Title1 Title2 Log K's extracted from Soltherm on 2018-Jul-23 CO,gas 1.0 CO + 0.25 SO4-- + 1.0 H2O = 1.0 HCO3- + 0.75 H+ + 0.25 HS- mol.wt. = 28.01 mol.vol.(cc/mol) = 0.00 rho(g/cc) = 0.00 Ref = H&P2011 T(°C) P(bar) Log(K) 7.00 0.990 4.895 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 7.00 1.000 4.895 7.00 100.000 4.884 25.00 0.990 4.114 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 25.00 1.000 4.114 25.00 100.000 4.100 100.00 0.990 1.521 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.000 1.521 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.014 1.521 100.00 500.000 1.464 200.00 5.000 99999.999 ERROR: Specified P and/or T are outside the P-T range of the data. 200.00 1000.000 -0.972 250.00 500.000 -1.932 250.10 500.000 -1.934 300.00 1000.000 -2.761 349.90 500.000 -3.723 350.00 500.000 -3.725 350.10 500.000 -3.727 373.00 500.000 -4.150 377.00 500.000 -4.224 400.00 500.000 -4.659 CO,gas 1.0 CO + 0.5 O2 aq. + 1.0 H2O = 1.0 HCO3- + 1.0 H+ mol.wt. = 28.01 mol.vol.(cc/mol) = 0.00 rho(g/cc) = 0.00 Ref = H&P2011 T(°C) P(bar) Log(K) 7.00 0.990 41.908 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 7.00 1.000 41.908 7.00 100.000 41.927 25.00 0.990 38.693 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 25.00 1.000 38.693 25.00 100.000 38.708 100.00 0.990 28.283 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.000 28.283 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.014 28.283 100.00 500.000 28.352 200.00 5.000 99999.999 ERROR: Specified P and/or T are outside the P-T range of the data. 200.00 1000.000 19.136 250.00 500.000 15.501 250.10 500.000 15.494 300.00 1000.000 12.618 349.90 500.000 9.578 350.00 500.000 9.572 350.10 500.000 9.566 373.00 500.000 8.309 377.00 500.000 8.092 400.00 500.000 6.857 quartz 1.0 SiO2 + 2.0 H2O = 1.0 H4SiO4 mol.wt. = 60.08 mol.vol.(cc/mol) = 22.69 rho(g/cc) = 2.65 Ref = H&P2011 T(°C) P(bar) Log(K) 7.00 0.990 -4.039 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 7.00 1.000 -4.039 7.00 100.000 -4.034 25.00 0.990 -3.750 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 25.00 1.000 -3.750 25.00 100.000 -3.740 100.00 0.990 -2.998 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.000 -2.998 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.014 -2.998 100.00 500.000 -2.935 200.00 5.000 99999.999 ERROR: Specified P and/or T are outside the P-T range of the data. 200.00 1000.000 -2.267 250.00 500.000 -2.090 250.10 500.000 -2.090 300.00 1000.000 -1.831 349.90 500.000 -1.766 350.00 500.000 -1.766 350.10 500.000 -1.766 373.00 500.000 -1.721 377.00 500.000 -1.714 400.00 500.000 -1.684 1.0 AlF++ = 1.0 Al+++ + 1.0 F- Ref = WO82 T(°C) P(bar) Log(K) 7.00 0.990 -6.964 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 7.00 1.000 -6.964 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 7.00 100.000 -6.964 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 25.00 0.990 -7.000 Data for L-V sat only, pressure ignored. 25.00 1.000 -7.000 Data for L-V sat only, pressure ignored. 25.00 100.000 -7.000 Data for L-V sat only, pressure ignored. 100.00 0.990 -7.540 Data for L-V sat only, pressure ignored. 100.00 1.000 -7.540 Data for L-V sat only, pressure ignored. 100.00 1.014 -7.540 Data for L-V sat only, pressure ignored. 100.00 500.000 -7.540 Data for L-V sat only, pressure ignored. 200.00 5.000 -9.170 Data for L-V sat only, pressure ignored. 200.00 1000.000 -9.170 Data for L-V sat only, pressure ignored. 250.00 500.000 -10.590 Data for L-V sat only, pressure ignored. 250.10 500.000 -10.594 Data for L-V sat only, pressure ignored. 300.00 1000.000 -13.000 Data for L-V sat only, pressure ignored. 349.90 500.000 -16.392 Data for L-V sat only, pressure ignored. 350.00 500.000 -16.400 Data for L-V sat only, pressure ignored. 350.10 500.000 99999.999 ERROR: Data extend to 300 °C only. Max extrapolation is 50 °C 373.00 500.000 99999.999 ERROR: Data extend to 300 °C only. Max extrapolation is 50 °C 377.00 500.000 99999.999 ERROR: Data extend to 300 °C only. Max extrapolation is 50 °C 400.00 500.000 99999.999 ERROR: Data extend to 300 °C only. Max extrapolation is 50 °C Entry 'bogus entry test ' not found in SOLTHERM. andradite 1.0 Ca3Fe2Si3O12 + 1.0 H2O + 0.25 HS- + 9.75 H+ = 3.0 Ca++ + 3.0 H4SiO4 + 0.25 SO4-- + 2.0 Fe++ mol.wt. = 508.18 mol.vol.(cc/mol) = 132.04 rho(g/cc) = 3.85 Ref = H&P2011 T(°C) P(bar) Log(K) 7.00 0.990 55.837 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 7.00 1.000 55.837 7.00 100.000 55.992 25.00 0.990 51.854 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 25.00 1.000 51.854 25.00 100.000 52.013 100.00 0.990 38.929 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.000 38.929 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.014 38.929 100.00 500.000 39.625 200.00 5.000 99999.999 ERROR: Specified P and/or T are outside the P-T range of the data. 200.00 1000.000 29.171 250.00 500.000 24.413 250.10 500.000 24.405 300.00 1000.000 21.801 349.90 500.000 17.407 350.00 500.000 17.400 350.10 500.000 17.395 373.00 500.000 16.446 377.00 500.000 16.341 400.00 500.000 16.085 andradite 1.0 Ca3Fe2Si3O12 + 1.0 H2O + 10.0 H+ = 3.0 Ca++ + 3.0 H4SiO4 + 2.0 Fe++ + 0.5 O2 aq. mol.wt. = 508.18 mol.vol.(cc/mol) = 132.04 rho(g/cc) = 3.85 Ref = H&P2011 T(°C) P(bar) Log(K) 7.00 0.990 18.824 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 7.00 1.000 18.824 7.00 100.000 18.949 25.00 0.990 17.275 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 25.00 1.000 17.275 25.00 100.000 17.404 100.00 0.990 12.166 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.000 12.166 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.014 12.166 100.00 500.000 12.737 200.00 5.000 99999.999 ERROR: Specified P and/or T are outside the P-T range of the data. 200.00 1000.000 9.063 250.00 500.000 6.980 250.10 500.000 6.977 300.00 1000.000 6.423 349.90 500.000 4.106 350.00 500.000 4.103 350.10 500.000 4.101 373.00 500.000 3.987 377.00 500.000 4.024 400.00 500.000 4.569 polydymite 1.0 Ni3S4 + 1.0 H2O + 1.75 H+ = 3.0 Ni++ + 3.75 HS- + 0.25 SO4-- mol.wt. = 304.33 mol.vol.(cc/mol) = 0.00 rho(g/cc) = 0.00 Ref = PH88 T(°C) P(bar) Log(K) 7.00 0.990 -45.500 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 7.00 1.000 -45.500 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 7.00 100.000 -45.500 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 25.00 0.990 -43.991 Data for L-V sat only, pressure ignored. 25.00 1.000 -43.991 Data for L-V sat only, pressure ignored. 25.00 100.000 -43.991 Data for L-V sat only, pressure ignored. 100.00 0.990 -40.046 Data for L-V sat only, pressure ignored. 100.00 1.000 -40.046 Data for L-V sat only, pressure ignored. 100.00 1.014 -40.046 Data for L-V sat only, pressure ignored. 100.00 500.000 -40.046 Data for L-V sat only, pressure ignored. 200.00 5.000 -38.882 Data for L-V sat only, pressure ignored. 200.00 1000.000 -38.882 Data for L-V sat only, pressure ignored. 250.00 500.000 -39.541 Data for L-V sat only, pressure ignored. 250.10 500.000 -39.543 Data for L-V sat only, pressure ignored. 300.00 1000.000 -41.189 Data for L-V sat only, pressure ignored. 349.90 500.000 -44.408 Data for L-V sat only, pressure ignored. 350.00 500.000 -44.416 Data for L-V sat only, pressure ignored. 350.10 500.000 -44.424 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 373.00 500.000 -46.431 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 377.00 500.000 -46.815 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 400.00 500.000 -49.222 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. polydymite 1.0 Ni3S4 + 1.0 H2O + 7.5 O2 aq. = 3.0 Ni++ + 2.0 H+ + 4.0 SO4-- mol.wt. = 304.33 mol.vol.(cc/mol) = 0.00 rho(g/cc) = 0.00 Ref = PH88 T(°C) P(bar) Log(K) 7.00 0.990 508.764 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 7.00 1.000 508.764 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 7.00 100.000 508.764 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 25.00 0.990 474.784 Data for L-V sat only, pressure ignored. 25.00 1.000 474.784 Data for L-V sat only, pressure ignored. 25.00 100.000 474.784 Data for L-V sat only, pressure ignored. 100.00 0.990 361.129 Data for L-V sat only, pressure ignored. 100.00 1.000 361.129 Data for L-V sat only, pressure ignored. 100.00 1.014 361.129 Data for L-V sat only, pressure ignored. 100.00 500.000 361.129 Data for L-V sat only, pressure ignored. 200.00 5.000 259.018 Data for L-V sat only, pressure ignored. 200.00 1000.000 259.018 Data for L-V sat only, pressure ignored. 250.00 500.000 219.509 Data for L-V sat only, pressure ignored. 250.10 500.000 219.434 Data for L-V sat only, pressure ignored. 300.00 1000.000 184.036 Data for L-V sat only, pressure ignored. 349.90 500.000 152.658 Data for L-V sat only, pressure ignored. 350.00 500.000 152.599 Data for L-V sat only, pressure ignored. 350.10 500.000 99999.999 ERROR: Data extend to 300 °C only. Max extrapolation is 50 °C 373.00 500.000 99999.999 ERROR: Data extend to 300 °C only. Max extrapolation is 50 °C 377.00 500.000 99999.999 ERROR: Data extend to 300 °C only. Max extrapolation is 50 °C 400.00 500.000 99999.999 ERROR: Data extend to 300 °C only. Max extrapolation is 50 °C 1.0 CuCl3(-1) + 0.5 H2O + 0.125 HS- = 1.125 H+ + 0.125 SO4-- + 1.0 Cu+ + 3.0 Cl- Ref = Shock07 T(°C) P(bar) Log(K) 7.00 0.990 0.172 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 7.00 1.000 0.172 7.00 100.000 0.207 25.00 0.990 0.809 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 25.00 1.000 0.809 25.00 100.000 0.841 100.00 0.990 1.811 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.000 1.811 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.014 1.811 100.00 500.000 1.955 200.00 5.000 99999.999 ERROR: Specified P and/or T are outside the P-T range of the data. 200.00 1000.000 1.644 250.00 500.000 0.772 250.10 500.000 0.770 300.00 1000.000 0.267 349.90 500.000 -1.422 350.00 500.000 -1.425 350.10 500.000 -1.428 373.00 500.000 -2.093 377.00 500.000 -2.212 400.00 500.000 -2.915 1.0 CuCl3(-1) + 0.5 H2O = 1.0 H+ + 0.25 O2 aq. + 1.0 Cu+ + 3.0 Cl- Ref = Shock07 T(°C) P(bar) Log(K) 7.00 0.990 -18.334 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 7.00 1.000 -18.334 7.00 100.000 -18.315 25.00 0.990 -16.480 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 25.00 1.000 -16.480 25.00 100.000 -16.464 100.00 0.990 -11.571 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.000 -11.571 WARNING: P and/or T are in a grid block at the limit of the P-T range of data. 100.00 1.014 -11.571 100.00 500.000 -11.489 200.00 5.000 99999.999 ERROR: Specified P and/or T are outside the P-T range of the data. 200.00 1000.000 -8.411 250.00 500.000 -7.944 250.10 500.000 -7.943 300.00 1000.000 -7.422 349.90 500.000 -8.073 350.00 500.000 -8.074 350.10 500.000 -8.075 373.00 500.000 -8.323 377.00 500.000 -8.371 400.00 500.000 -8.673 1.0 UO2SO4,aq = 1.0 UO2++ + 1.0 SO4-- Ref = WO90 T(°C) P(bar) Log(K) 7.00 0.990 -2.949 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 7.00 1.000 -2.949 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 7.00 100.000 -2.949 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 25.00 0.990 -3.138 Data for L-V sat only, pressure ignored. 25.00 1.000 -3.138 Data for L-V sat only, pressure ignored. 25.00 100.000 -3.138 Data for L-V sat only, pressure ignored. 100.00 0.990 -4.040 Data for L-V sat only, pressure ignored. 100.00 1.000 -4.040 Data for L-V sat only, pressure ignored. 100.00 1.014 -4.040 Data for L-V sat only, pressure ignored. 100.00 500.000 -4.040 Data for L-V sat only, pressure ignored. 200.00 5.000 -5.740 Data for L-V sat only, pressure ignored. 200.00 1000.000 -5.740 Data for L-V sat only, pressure ignored. 250.00 500.000 -6.896 Data for L-V sat only, pressure ignored. 250.10 500.000 99999.999 ERROR: Data extend to 200 °C only. Max extrapolation is 50 °C 300.00 1000.000 99999.999 ERROR: Data extend to 200 °C only. Max extrapolation is 50 °C 349.90 500.000 99999.999 ERROR: Data extend to 200 °C only. Max extrapolation is 50 °C 350.00 500.000 99999.999 ERROR: Data extend to 200 °C only. Max extrapolation is 50 °C 350.10 500.000 99999.999 ERROR: Data extend to 200 °C only. Max extrapolation is 50 °C 373.00 500.000 99999.999 ERROR: Data extend to 200 °C only. Max extrapolation is 50 °C 377.00 500.000 99999.999 ERROR: Data extend to 200 °C only. Max extrapolation is 50 °C 400.00 500.000 99999.999 ERROR: Data extend to 200 °C only. Max extrapolation is 50 °C 1.0 SnCl2 = 1.0 Sn++ + 2.0 Cl- Ref = JH85 FTA T(°C) P(bar) Log(K) 7.00 0.990 -1.615 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 7.00 1.000 -1.615 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 7.00 100.000 -1.615 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 25.00 0.990 -1.710 Data for L-V sat only, pressure ignored. 25.00 1.000 -1.710 Data for L-V sat only, pressure ignored. 25.00 100.000 -1.710 Data for L-V sat only, pressure ignored. 100.00 0.990 -2.290 Data for L-V sat only, pressure ignored. 100.00 1.000 -2.290 Data for L-V sat only, pressure ignored. 100.00 1.014 -2.290 Data for L-V sat only, pressure ignored. 100.00 500.000 -2.290 Data for L-V sat only, pressure ignored. 200.00 5.000 -3.590 Data for L-V sat only, pressure ignored. 200.00 1000.000 -3.590 Data for L-V sat only, pressure ignored. 250.00 500.000 -4.490 Data for L-V sat only, pressure ignored. 250.10 500.000 -4.492 Data for L-V sat only, pressure ignored. 300.00 1000.000 -5.870 Data for L-V sat only, pressure ignored. 349.90 500.000 -9.022 Data for L-V sat only, pressure ignored. 350.00 500.000 -9.030 Data for L-V sat only, pressure ignored. 350.10 500.000 -9.038 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 373.00 500.000 -11.081 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 377.00 500.000 -11.477 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C. 400.00 500.000 -13.970 WARNING: LogK extrapolated. Data limited to L-V saturation where 25 °C <= T <= 350 °C.