File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. S2,gas is suppressed in THIS RUN. S2,gas is suppressed in THIS RUN. SO2,gas is suppressed in THIS RUN. SO2,gas is suppressed in THIS RUN. spessartine is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. cordierite is suppressed in THIS RUN. osumilite(1) is suppressed in THIS RUN. pyroxmangite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. tridymite is suppressed in THIS RUN. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. silica-amorphous is suppressed in THIS RUN. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. 0.42624E+01 0.29489E-02 0.0050 0.00000000E+00 H2O 2 0. 0.51965E+02 0.10000E+01 1.0024 0.00000000E+00 Cl- 3 -1. 0.65146E+00 0.33068-233 0.0762 0.00000000E+00 SO4-- 4 -2. 0.25172E+00 0.62091E+01 0.0000 0.00000000E+00 HCO3- 5 -1. 0.26561E+01 0.35642-237 0.2030 0.00000000E+00 HS- 6 -1. 0.11601E+01 0.42409E-03 0.0855 0.00000000E+00 H4SiO4 7 0. 0.14359E+00 0.14520E+00 1.0000 0.00000000E+00 Al+++ 8 3. 0.69454E-03 0.11743E+01 0.0000 0.00000000E+00 Ca++ 9 2. 0.52791E-03 0.88536E+01 0.0000 0.00000000E+00 Mg++ 10 2. 0.20677E-04 0.49435E+00 0.0000 0.00000000E+00 Fe++ 11 2. 0.87668E-02 0.86340E+01 0.0000 0.00000000E+00 K+ 12 1. 0.12541E+00 0.18310E+00 0.3129 0.00000000E+00 Na+ 13 1. 0.55460E+00 0.19781E+01 0.1061 0.00000000E+00 Mn++ 14 2. 0.11495E-02 0.51638E+01 0.0000 0.00000000E+00 Zn++ 15 2. 0.22993E-02 0.12386-235 0.0000 0.00000000E+00 Cu+ 16 1. 0.39961E-03 0.74782E-06 0.1024 0.00000000E+00 Pb++ 17 2. 0.34017E-03 0.18224-236 0.0000 0.00000000E+00 Ag+ 18 1. 0.87008E-05 0.17581E-14 0.2602 0.00000000E+00 Ba++ 19 2. 0.55372E-04 0.33449E+01 0.0000 0.00000000E+00 HPO4-- 20 -2. 0.85675E-05 0.82178E-03 0.0000 0.00000000E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 2500.0000 SLIM = 0.535000E+03 TEMP = 600.0000 SINC = -.1000E+01 TEMPC = 0.0000 TOTMIX = 0.000000E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.1000E-08 RM = 0.0000 AQGRM = 1200.0089 SUPRNT = 0.1000E-10 VBOX-1 = 0.0000 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 1 NLOOP = 500 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 0 INCREM = 0 INCP = 0 MINSOL = 0 NEUT = 0 AWAT = 0 CHGF = 0 Given pressure grid: 66 T-P points read Of the derived species, only those with molality > 0.10E-10 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 21 -1. 10.2110 Mg(HCO3)+ 90 1. -5.4330 Ca(HSiO3)+ 22 1. 5.0410 MgCl+ 91 1. -3.7130 Mg(HSiO3)+ 23 1. 5.6620 MgOH+ 92 1. 3.9600 NaHSiO3,aq 24 0. 9.0790 Mn+3 93 3. 14.2490 Ag(CO3)- 25 -1. 9.0940 MnO,aq 94 0. 9.8110 Ag(CO3)2-3 26 -3. 19.7650 MnOH+ 95 1. 4.1730 Ag+2 27 2. 13.8900 MnO2-2 96 -2. 28.2870 AgCl,aq 28 0. -3.5280 HMnO2- 97 -1. 18.3980 AgCl2- 29 -1. -5.9530 MnO4- 98 -1. 31.5260 AgCl3-2 30 -2. -5.4110 MnO4-2 99 -2. 40.4650 AgCl4-3 31 -3. -3.5960 MnCl+ 100 1. -5.9020 Ag(OH),aq 32 0. 10.9200 MnSO4,aq 101 0. -5.8650 AgO- 33 -1. 14.9360 NaCl,aq 102 0. -1.6000 Ag(HS),aq 34 0. -4.5230 NaOH,aq 103 0. 9.9770 Ag(HS)2- 35 -1. -9.0630 O2,aq 104 0. 14.5760 AlO+ 36 1. 0.3070 OH- 105 -1. 10.5260 AlOH+2 37 2. -1.7510 HO2- 106 -1. 25.6170 HAlO2,aq 38 0. 2.5650 H2O2,aq 107 0. 14.6940 AlO2- 39 -1. 4.4590 H3PO2,aq 108 0. 1.9250 BaCO3,aq 40 0. 4.2110 H2PO2- 109 -1. 5.8610 Ba(HCO3)+ 41 1. -6.8110 HPO3-2 110 -2. 3.3160 BaCl+ 42 1. -4.6200 H3PO3,aq 111 0. -9.4930 CH4,aq 43 0. 5.1480 H2PO3- 112 -1. -5.6950 C2H6,aq 44 0. 9.3390 H3PO4,aq 113 0. -14.8210 C3H8,aq 45 0. 14.2890 H2PO4- 114 -1. -9.7600 C4H10,aq 46 0. 19.6850 PO4-3 115 -3. 14.4500 ethanol,aq 47 0. 10.0660 H4P2O7,aq 116 0. -31.5400 CO,aq 48 0. -5.2100 H3P2O7- 117 -1. -27.5180 CO2,aq 49 0. -10.3090 H2P2O7-2 118 -2. -23.5370 CO3-2 50 -2. 12.1860 HP2O7-3 119 -3. -14.2960 CaCO3,aq 51 0. 3.7520 P2O7-4 120 -4. 1.3100 Ca(HCO3)+ 52 1. -5.7790 PbCl+ 121 1. -5.1200 CaCl+ 53 1. -4.4520 PbCl2,aq 122 0. -7.9420 CaCl2,aq 54 0. -5.4680 PbCl3- 123 -1. -8.5360 CaOH+ 55 1. 4.5740 PbCl4-2 124 -2. -7.6860 CaSO4,aq 56 0. -5.7620 PbO,aq 125 0. 8.9420 HCl,aq 57 0. -3.0560 HPbO2- 126 -1. 19.0060 HClO,aq 58 0. 7.5990 Pb(HS)2,aq 127 0. -14.2370 ClO- 59 -1. 15.8040 Pb(HS)3- 128 -1. -16.7810 HClO2,aq 60 0. 20.5980 H2S,aq 129 0. -9.4110 Cu+2 61 2. 2.5750 S2-2 130 -2. -0.4700 CuCl+ 62 1. -1.8910 S3-2 131 -2. -10.4550 CuCl2,aq 63 0. -4.1910 S3- 132 -1. -24.8520 CuCl3- 64 -1. -4.1130 S4-2 133 -2. -20.3540 CuCl4-2 65 -2. -1.4530 S5-2 134 -2. -30.1740 CuCl,aq 66 0. -4.1270 SO2,aq 135 0. -13.5370 CuCl2- 67 -1. -5.2610 SO3-2 136 -2. 6.7820 CuCl3-2 68 -2. -3.4310 HSO3- 137 -1. -5.3140 CuO,aq 69 0. 10.1020 HSO4- 138 -1. -8.4160 CuOH+ 70 1. 5.6030 HSO5- 139 -1. 4.3260 CuO2-2 71 -2. 27.8180 S2O3-2 140 -2. -6.8200 HCuO2- 72 -1. 17.7790 HS2O3- 141 -1. -13.5390 Fe+3 73 3. 7.0480 H2S2O3,aq 142 0. -17.4620 FeCl+ 74 1. -4.0060 S2O4-2 143 -2. -2.4030 FeCl2,aq 75 0. -9.5160 HS2O4- 144 -1. -9.3740 FeCl+2 76 2. 1.5880 H2S2O4,aq 145 0. -13.2580 FeO,aq 77 0. 7.9760 S2O5-2 146 -2. -3.8310 FeOH+ 78 1. 3.2750 S2O6-2 147 -2. -4.7260 HFeO2- 79 -1. 14.2500 S2O8-2 148 -2. 2.4290 FeO+ 80 1. 6.4740 S3O6-2 149 -2. -12.7710 FeOH+2 81 2. 5.1290 S4O6-2 150 -2. -30.7070 FeO2- 82 -1. 13.7830 S5O6-2 151 -2. -30.0370 HFeO2,aq 83 0. 9.8020 ZnCl+ 152 1. -8.6690 H2,aq 84 0. 3.9080 ZnCl2,aq 153 0. -10.2760 KCl,aq 85 0. -1.2830 ZnCl3- 154 -1. -10.1160 KHSO4,aq 86 0. -10.3330 ZnO,aq 155 0. 6.7180 KOH,aq 87 0. 9.6270 ZnOH+ 156 1. -0.1480 KSO4- 88 -1. -4.1640 ZnO2-2 157 -2. 24.2060 MgCO3,aq 89 0. 5.4870 HZnO2- 158 -1. 14.2050 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 0.296 0.0000E+00 phlogopite-Na 132 5.054 0.0000E+00 CO2,gas 2 -8.564 0.0000E+00 piemontite(ordered) 133 -0.830 0.0000E+00 CH4,gas 3 6.828 0.0000E+00 prehnite 134 -4.842 0.0000E+00 H2,gas 4 5.659 0.0000E+00 prehnite-Fe 135 1.264 0.0000E+00 H2S,gas 5 -7.090 0.0000E+00 pumpellyite-Fe 136 -12.520 0.0000E+00 CO,gas 6 -2.776 0.0000E+00 pumpellyite-Mg 137 -10.990 0.0000E+00 SO3,gas 7 -5.654 0.0000E+00 px-Mg-tschermaks 138 -8.086 0.0000E+00 O2,gas 8 13.140 0.0000E+00 px-Ca-tschermaks 139 -7.019 0.0000E+00 HCl,gas 9 -1.946 0.0000E+00 pyrite 140 -19.194 0.0000E+00 acmite 10 4.285 0.0000E+00 pyrrhotite 141 -7.701 0.0000E+00 akermanite 11 12.974 0.0000E+00 pyrrhotiteFe0.875 142 -8.391 0.0000E+00 akimotoite 12 5.922 0.0000E+00 pyrophyllite 143 -13.878 0.0000E+00 akimotoite-Fe 13 3.927 0.0000E+00 quartz 144 -0.832 0.0000E+00 albite-high 14 -3.935 0.0000E+00 rankinite 145 16.492 0.0000E+00 albite 15 -3.896 0.0000E+00 riebeckite 146 7.894 0.0000E+00 almandine 16 -9.917 0.0000E+00 ringwoodite-Fe 147 2.988 0.0000E+00 pyrope 17 -3.622 0.0000E+00 ringwoodite-Mg 148 8.843 0.0000E+00 analcite 18 -2.331 0.0000E+00 rhodochrosite 149 -4.404 0.0000E+00 andalusite 19 -12.178 0.0000E+00 rhodonite 150 2.614 0.0000E+00 andradite 20 11.907 0.0000E+00 sanidine 151 -3.985 0.0000E+00 grossular 21 -0.012 0.0000E+00 sapphirine(351) 152 -46.276 0.0000E+00 anhydrite 22 -12.532 0.0000E+00 siderite 153 -6.305 0.0000E+00 ankerite 23 -10.120 0.0000E+00 sillimanite 154 -12.160 0.0000E+00 annite 24 -0.186 0.0000E+00 sodalite 155 -7.476 0.0000E+00 phlogopite 25 4.166 0.0000E+00 spinel 156 -7.710 0.0000E+00 biotite-Mn 26 8.836 0.0000E+00 spurrite 157 20.284 0.0000E+00 anorthite 27 -9.600 0.0000E+00 staurolite-Fe 158 -102.666 0.0000E+00 anthophyllite 28 14.700 0.0000E+00 staurolite-Mg 159 -94.672 0.0000E+00 anthophyllite-Fe 29 2.808 0.0000E+00 staurolite-Mn 160 -93.649 0.0000E+00 apatite-OH 30 -46.710 0.0000E+00 stilbite 161 -8.016 0.0000E+00 apatite-OH-zs 31 -44.651 0.0000E+00 stilpnomelane-Fe 162 -7.335 0.0000E+00 apatite-Cl-zs 32 -49.894 0.0000E+00 stilpnomelane-Mg 163 -1.061 0.0000E+00 aragonite 33 -3.505 0.0000E+00 stishovite 164 1.974 0.0000E+00 brucite 34 4.890 0.0000E+00 sudoite-Fe 165 -20.447 0.0000E+00 calcite 35 -3.583 0.0000E+00 sudoite 166 -18.356 0.0000E+00 carnegieite-low 36 -0.652 0.0000E+00 sulfur 167 -9.447 0.0000E+00 carnegieite-high 37 -0.591 0.0000E+00 sylvite 168 0.121 0.0000E+00 carpholite-Mg 38 -8.882 0.0000E+00 talc 169 5.452 0.0000E+00 carpholite-Fe 39 -10.164 0.0000E+00 talc-Fe 170 2.814 0.0000E+00 celadonite 40 -0.682 0.0000E+00 talc-tschermaks 171 -7.207 0.0000E+00 celadonite-Fe 41 -2.024 0.0000E+00 tenorite 172 3.855 0.0000E+00 chrysotile 42 8.906 0.0000E+00 tephroite 173 6.347 0.0000E+00 chondrodite 43 17.112 0.0000E+00 tilleyite 174 8.985 0.0000E+00 clinochlore 44 0.804 0.0000E+00 titanite-CaSi 175 7.398 0.0000E+00 daphnite 45 -5.884 0.0000E+00 topaz-H 176 -10.225 0.0000E+00 chlorite-Mn 46 8.430 0.0000E+00 tremolite 177 15.910 0.0000E+00 chlorite-Al-free 47 18.035 0.0000E+00 ferroactinolite 178 9.620 0.0000E+00 chloritoid-Mg 48 -8.673 0.0000E+00 troilite-low 179 -7.601 0.0000E+00 chloritoid-Fe 49 -10.490 0.0000E+00 tschermakite 180 -10.921 0.0000E+00 chloritoid-Mn 50 -8.332 0.0000E+00 vesuvianite 181 16.842 0.0000E+00 clinohumite 51 28.307 0.0000E+00 wadeite-Si 182 16.255 0.0000E+00 coesite 52 -0.568 0.0000E+00 wadsleyite-Fe 183 2.837 0.0000E+00 cordierite-H 53 -21.446 0.0000E+00 wadsleyite-Mg 184 7.930 0.0000E+00 cordierite-Fe 54 -23.649 0.0000E+00 wairakite 185 -10.276 0.0000E+00 cordierite-Mn 55 -19.251 0.0000E+00 walstromite 186 4.742 0.0000E+00 corundum 56 -11.200 0.0000E+00 wollastonite 187 4.358 0.0000E+00 corundum-MgSi 57 6.905 0.0000E+00 pseudo-wollastonite 188 4.463 0.0000E+00 cristobalite 58 -0.761 0.0000E+00 zoisite 189 -11.495 0.0000E+00 cummingtonite 59 14.745 0.0000E+00 Ag2O 190 9.324 0.0000E+00 cuprite 60 3.907 0.0000E+00 argentite 191 -12.078 0.0000E+00 cymrite-K 61 -2.450 0.0000E+00 beidellite-Ca 192 -14.699 0.0000E+00 deerite 62 10.465 0.0000E+00 beidellite-H 193 -14.712 0.0000E+00 diaspore 63 -5.123 0.0000E+00 beidellite-K 194 -13.640 0.0000E+00 diamond 64 -1.074 0.0000E+00 beidellite-Mg 195 -15.037 0.0000E+00 diopside 65 5.532 0.0000E+00 beidellite-Na 196 -13.571 0.0000E+00 hedenbergite 66 4.190 0.0000E+00 bornite 197 -48.006 0.0000E+00 dolomite,ordered 67 -8.526 0.0000E+00 calcium 198 36.713 0.0000E+00 eastonite 68 -8.771 0.0000E+00 chalcocite 199 -12.389 0.0000E+00 enstatite 69 4.648 0.0000E+00 covellite 200 -10.987 0.0000E+00 clinoenstatite-HiP 70 5.114 0.0000E+00 dawsonite 201 -2.359 0.0000E+00 clinoenstatite 71 4.638 0.0000E+00 montmorillonite-Ca 202 -10.558 0.0000E+00 protoenstatite 72 4.784 0.0000E+00 montmorillonite-K 203 -9.798 0.0000E+00 epidote 73 -5.730 0.0000E+00 montmorillonite-Mg 204 -10.804 0.0000E+00 clinozoisite 74 -11.428 0.0000E+00 montmorillonite-Na 205 -9.406 0.0000E+00 epidote-Fe 75 1.614 0.0000E+00 nontronite-Ca 206 -2.784 0.0000E+00 fayalite 76 2.034 0.0000E+00 nontronite-H 207 -2.805 0.0000E+00 ferrosilite 77 1.274 0.0000E+00 nontronite-K 208 -1.727 0.0000E+00 forsterite 78 5.818 0.0000E+00 nontronite-Mg 209 -3.047 0.0000E+00 gedrite 79 -12.919 0.0000E+00 nontronite-Na 210 -1.655 0.0000E+00 gehlenite 80 -0.272 0.0000E+00 sepiolite 211 15.907 0.0000E+00 gibbsite 81 -3.608 0.0000E+00 alite 212 23.346 0.0000E+00 glaucophane 82 1.382 0.0000E+00 belite 213 12.099 0.0000E+00 glaucophane-Fe 83 -2.419 0.0000E+00 ettringite 214 5.363 0.0000E+00 goethite 84 0.969 0.0000E+00 gypsum 215 -10.526 0.0000E+00 graphite 85 -1.370 0.0000E+00 hemicarboaluminate 216 23.304 0.0000E+00 greenalite 86 4.363 0.0000E+00 hydrogarnet 217 16.441 0.0000E+00 grunerite 87 3.320 0.0000E+00 hydrogarnet-Si 218 11.110 0.0000E+00 halite 88 0.046 0.0000E+00 jennite 219 13.904 0.0000E+00 hematite 89 0.505 0.0000E+00 monosulfoaluminate 220 5.795 0.0000E+00 heulandite 90 -11.842 0.0000E+00 monocarboaluminate 221 17.573 0.0000E+00 hercynite 91 -9.779 0.0000E+00 portlandite 222 8.404 0.0000E+00 hollandite 92 8.307 0.0000E+00 stratlingite 223 6.949 0.0000E+00 iron 93 8.029 0.0000E+00 tricarboaluminate 224 35.182 0.0000E+00 jadeite 94 -1.685 0.0000E+00 tobermorite 225 7.388 0.0000E+00 julgoldite 95 22.005 0.0000E+00 C4AH13 226 31.340 0.0000E+00 kalsilite 96 -1.319 0.0000E+00 C2AH8 227 12.045 0.0000E+00 kaolinite 97 -10.841 0.0000E+00 C3A 228 20.019 0.0000E+00 kyanite 98 -12.062 0.0000E+00 C4AF 229 27.751 0.0000E+00 larnite-bredigite 99 12.293 0.0000E+00 CAH10 230 5.460 0.0000E+00 laumontite 100 -8.689 0.0000E+00 acanthite 231 -12.194 0.0000E+00 lawsonite 101 -7.117 0.0000E+00 alabandite 232 -5.430 0.0000E+00 leucite 102 -2.774 0.0000E+00 alunite 233 -36.681 0.0000E+00 lime 103 10.648 0.0000E+00 anglesite 234 -12.632 0.0000E+00 lizardite 104 9.104 0.0000E+00 artinite 235 5.459 0.0000E+00 magnesite 105 -4.579 0.0000E+00 azurite 236 0.697 0.0000E+00 magnetite 106 1.424 0.0000E+00 barite 237 -13.530 0.0000E+00 minnesotaite 107 1.508 0.0000E+00 boehmite 238 -4.848 0.0000E+00 minnesotaite-Mg 108 7.154 0.0000E+00 cerussite 239 -4.303 0.0000E+00 magnesioferrite 109 4.351 0.0000E+00 chalcopyrite 240 -20.669 0.0000E+00 majorite 110 17.612 0.0000E+00 chlorargyrite 241 -4.546 0.0000E+00 manganosite 111 5.019 0.0000E+00 copper,native 242 1.830 0.0000E+00 margarite 112 -20.413 0.0000E+00 dolomite,disordered 243 -8.621 0.0000E+00 meionite 113 -31.601 0.0000E+00 ferrous-oxide 244 1.753 0.0000E+00 merwinite 114 20.630 0.0000E+00 galena 245 -8.379 0.0000E+00 microcline 115 -4.502 0.0000E+00 silver,native 246 0.593 0.0000E+00 monticellite 116 8.492 0.0000E+00 huntite 247 -17.347 0.0000E+00 mullite-Al 117 123.042 0.0000E+00 litharge 248 5.277 0.0000E+00 mullite-Si 118 -11.487 0.0000E+00 hydromagnesite 249 -7.802 0.0000E+00 muscovite 119 -15.655 0.0000E+00 malachite 250 1.967 0.0000E+00 paragonite 120 -14.959 0.0000E+00 nesquehonite 251 3.093 0.0000E+00 nepheline 121 -0.942 0.0000E+00 potassium-oxide 252 35.112 0.0000E+00 osumilite(2) 122 -12.690 0.0000E+00 smithsonite 253 -5.097 0.0000E+00 osumilite-Fe 123 -29.537 0.0000E+00 sodium-oxide 254 29.096 0.0000E+00 pargasite 124 2.619 0.0000E+00 sphalerite 255 -9.794 0.0000E+00 periclase 125 5.115 0.0000E+00 wurtzite 256 -9.022 0.0000E+00 periclase-Fe 126 2.654 0.0000E+00 zincite 257 1.927 0.0000E+00 perovskite-Al 127 -9.536 0.0000E+00 an20ab80 258 -5.254 0.0000E+00 perovskite-Ca 128 10.148 0.0000E+00 an25ab75 259 -5.566 0.0000E+00 perovskite-Fe 129 7.349 0.0000E+00 an30ab70 260 -5.872 0.0000E+00 perovskite-Mg 130 8.614 0.0000E+00 tr.625ac.25prg.125 261 10.173 0.0000E+00 phase_A 131 27.363 0.0000E+00 262 0.000 0.0000E+00 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 CO,gas 6 SO3,gas 6 HCl,gas 6 almandine 16 pyrope 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 silver,native 10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 53 Loop limit = 500 Temperature = 600.00 C Pressure = 2500.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5496E+02 kg liquid = 0.9902E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9936 Stoichiometric ionic strength = .3318840E+01 Osmotic coef. = 0.0000 True ionic strength = .3306168E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.33067E-04 -4.4806 0.10684E-04 -4.9713 0.32309E+00 -0.4907 2 H2O 0.99356E+00 -0.0028 0.99356E+00 -0.0028 3 Cl- 0.28523E+00 -0.5448 0.91302E-01 -1.0395 0.32010E+00 -0.4947 4 SO4-- 0.12223E-03 -3.9128 0.18136E-05 -5.7415 0.14837E-01 -1.8286 5 HCO3- 0.44187E-04 -4.3547 0.15153E-04 -4.8195 0.34292E+00 -0.4648 6 HS- 0.14440E-03 -3.8404 0.46582E-04 -4.3318 0.32259E+00 -0.4914 7 H4SiO4 0.14502E+00 -0.8386 0.14502E+00 -0.8386 0.10000E+01 0.0000 8 Al+++ 0.13051E-14 -14.8844 0.75171E-19 -19.1240 0.57597E-04 -4.2396 9 Ca++ 0.43988E-05 -5.3567 0.54036E-07 -7.2673 0.12284E-01 -1.9106 10 Mg++ 0.13821E-05 -5.8595 0.14209E-07 -7.8474 0.10281E-01 -1.9880 11 Fe++ 0.30085E-07 -7.5216 0.32369E-09 -9.4899 0.10759E-01 -1.9682 12 K+ 0.70728E-01 -1.1504 0.24840E-01 -1.6048 0.35121E+00 -0.4544 13 Na+ 0.25711E+00 -0.5899 0.83361E-01 -1.0790 0.32422E+00 -0.4892 14 Mn++ 0.50696E-06 -6.2950 0.56379E-08 -8.2489 0.11121E-01 -1.9539 15 Zn++ 0.69812E-09 -9.1561 0.75112E-11 -11.1243 0.10759E-01 -1.9682 16 Cu+ 0.20376E-06 -6.6909 0.65899E-07 -7.1811 0.32341E+00 -0.4902 17 Pb++ 0.11391E-07 -7.9434 0.15494E-09 -9.8098 0.13601E-01 -1.8664 18 Ag+ 0.58542E-09 -9.2325 0.20268E-09 -9.6932 0.34622E+00 -0.4607 19 Ba++ 0.34791E-06 -6.4585 0.50438E-08 -8.2972 0.14497E-01 -1.8387 20 HPO4-- 0.14919E-08 -8.8263 0.22235E-10 -10.6530 0.14904E-01 -1.8267 21 HSiO3- 0.26256E-05 -5.5808 0.84045E-06 -6.0755 0.32010E+00 -0.4947 22 Ca(HSiO3)+ 0.18975E-07 -7.7218 0.67174E-08 -8.1728 0.35401E+00 -0.4510 23 Mg(HSiO3)+ 0.11942E-08 -8.9229 0.42275E-09 -9.3739 0.35401E+00 -0.4510 24 NaHSiO3,aq 0.94945E-06 -6.0225 0.94945E-06 -6.0225 0.10000E+01 0.0000 28 AgCl,aq 0.62416E-07 -7.2047 0.62416E-07 -7.2047 0.10000E+01 0.0000 29 AgCl2- 0.47368E-05 -5.3245 0.15163E-05 -5.8192 0.32010E+00 -0.4947 30 AgCl3-2 0.28696E-05 -5.5422 0.39743E-07 -7.4007 0.13849E-01 -1.8586 31 AgCl4-3 0.11160E-05 -5.9523 0.55557E-10 -10.2553 0.49783E-04 -4.3029 34 Ag(HS),aq 0.31480E-09 -9.5020 0.31480E-09 -9.5020 0.10000E+01 0.0000 35 Ag(HS)2- 0.15884E-08 -8.7990 0.50846E-09 -9.2937 0.32010E+00 -0.4947 36 AlO+ 0.91157E-09 -9.0402 0.32271E-09 -9.4912 0.35401E+00 -0.4510 37 AlOH+2 0.34125E-10 -10.4669 0.39403E-12 -12.4045 0.11547E-01 -1.9375 38 HAlO2,aq 0.16569E-06 -6.7807 0.16569E-06 -6.7807 0.10000E+01 0.0000 39 AlO2- 0.70128E-03 -3.1541 0.19795E-03 -3.7034 0.28228E+00 -0.5493 41 Ba(HCO3)+ 0.13481E-05 -5.8703 0.49459E-06 -6.3058 0.36689E+00 -0.4355 42 BaCl+ 0.54227E-04 -4.2658 0.19197E-04 -4.7168 0.35401E+00 -0.4510 43 CH4,aq 0.22218E-08 -8.6533 0.27502E-08 -8.5606 0.12378E+01 0.0926 48 CO,aq 0.10405E-02 -2.9827 0.10405E-02 -2.9827 0.10000E+01 0.0000 49 CO2,aq 0.26814E+01 0.4284 0.33191E+01 0.5210 0.12378E+01 0.0926 50 CO3-2 0.66733E-10 -10.1757 0.92422E-12 -12.0342 0.13849E-01 -1.8586 51 CaCO3,aq 0.13566E-10 -10.8675 0.13566E-10 -10.8675 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.13905E-05 -5.8568 0.49224E-06 -6.3078 0.35401E+00 -0.4510 53 CaCl+ 0.39459E-03 -3.4039 0.13969E-03 -3.8548 0.35401E+00 -0.4510 54 CaCl2,aq 0.13233E-03 -3.8784 0.13233E-03 -3.8784 0.10000E+01 0.0000 55 CaOH+ 0.37857E-06 -6.4219 0.13402E-06 -6.8728 0.35401E+00 -0.4510 56 CaSO4,aq 0.56654E-07 -7.2468 0.56654E-07 -7.2468 0.10000E+01 0.0000 57 HCl,aq 0.11097E-02 -2.9548 0.11097E-02 -2.9548 0.10000E+01 0.0000 63 CuCl2,aq 0.14566E-10 -10.8367 0.14566E-10 -10.8367 0.10000E+01 0.0000 66 CuCl,aq 0.80605E-04 -4.0936 0.80605E-04 -4.0936 0.10000E+01 0.0000 67 CuCl2- 0.31301E-03 -3.5044 0.10019E-03 -3.9992 0.32010E+00 -0.4947 68 CuCl3-2 0.97699E-05 -5.0101 0.13531E-06 -6.8687 0.13849E-01 -1.8586 74 FeCl+ 0.84643E-06 -6.0724 0.29965E-06 -6.5234 0.35401E+00 -0.4510 75 FeCl2,aq 0.88530E-02 -2.0529 0.88530E-02 -2.0529 0.10000E+01 0.0000 77 FeO,aq 0.29778E-07 -7.5261 0.29778E-07 -7.5261 0.10000E+01 0.0000 78 FeOH+ 0.45143E-07 -7.3454 0.15981E-07 -7.7964 0.35401E+00 -0.4510 79 HFeO2- 0.46034E-08 -8.3369 0.14736E-08 -8.8316 0.32010E+00 -0.4947 82 FeO2- 0.21571E-08 -8.6661 0.69048E-09 -9.1609 0.32010E+00 -0.4947 83 HFeO2,aq 0.70610E-10 -10.1511 0.70610E-10 -10.1511 0.10000E+01 0.0000 84 H2,aq 0.39065E-02 -2.4082 0.48354E-02 -2.3156 0.12378E+01 0.0926 85 KCl,aq 0.43515E-01 -1.3614 0.43515E-01 -1.3614 0.10000E+01 0.0000 86 KHSO4,aq 0.10361E-01 -1.9846 0.10361E-01 -1.9846 0.10000E+01 0.0000 87 KOH,aq 0.54530E-06 -6.2634 0.54530E-06 -6.2634 0.10000E+01 0.0000 88 KSO4- 0.20531E-02 -2.6876 0.65721E-03 -3.1823 0.32010E+00 -0.4947 90 Mg(HCO3)+ 0.16483E-06 -6.7830 0.58353E-07 -7.2339 0.35401E+00 -0.4510 91 MgCl+ 0.18925E-04 -4.7230 0.66996E-05 -5.1739 0.35401E+00 -0.4510 92 MgOH+ 0.40929E-06 -6.3880 0.14489E-06 -6.8390 0.35401E+00 -0.4510 94 MnO,aq 0.75836E-08 -8.1201 0.75836E-08 -8.1201 0.10000E+01 0.0000 95 MnOH+ 0.99442E-07 -7.0024 0.35204E-07 -7.4534 0.35401E+00 -0.4510 100 MnCl+ 0.11603E-02 -2.9354 0.41077E-03 -3.3864 0.35401E+00 -0.4510 101 MnSO4,aq 0.74931E-08 -8.1253 0.74931E-08 -8.1253 0.10000E+01 0.0000 102 NaCl,aq 0.30300E+00 -0.5186 0.30300E+00 -0.5186 0.10000E+01 0.0000 103 NaOH,aq 0.81741E-06 -6.0876 0.81741E-06 -6.0876 0.10000E+01 0.0000 105 OH- 0.98130E-05 -5.0082 0.27700E-05 -5.5575 0.28228E+00 -0.5493 110 HPO3-2 0.30538E-10 -10.5152 0.42293E-12 -12.3737 0.13849E-01 -1.8586 111 H3PO3,aq 0.31096E-09 -9.5073 0.31096E-09 -9.5073 0.10000E+01 0.0000 112 H2PO3- 0.14478E-07 -7.8393 0.46344E-08 -8.3340 0.32010E+00 -0.4947 113 H3PO4,aq 0.16806E-05 -5.7745 0.16806E-05 -5.7745 0.10000E+01 0.0000 114 H2PO4- 0.40763E-05 -5.3897 0.13669E-05 -5.8642 0.33534E+00 -0.4745 116 H4P2O7,aq 0.22477E-09 -9.6483 0.22477E-09 -9.6483 0.10000E+01 0.0000 117 H3P2O7- 0.62480E-08 -8.2043 0.20000E-08 -8.6990 0.32010E+00 -0.4947 118 H2P2O7-2 0.14121E-05 -5.8501 0.19557E-07 -7.7087 0.13849E-01 -1.8586 119 HP2O7-3 0.21111E-07 -7.6755 0.10510E-11 -11.9784 0.49783E-04 -4.3029 121 PbCl+ 0.52676E-05 -5.2784 0.18648E-05 -5.7294 0.35401E+00 -0.4510 122 PbCl2,aq 0.11301E-03 -3.9469 0.11301E-03 -3.9469 0.10000E+01 0.0000 123 PbCl3- 0.12656E-03 -3.8977 0.40513E-04 -4.3924 0.32010E+00 -0.4947 124 PbCl4-2 0.37726E-04 -4.4234 0.52249E-06 -6.2819 0.13849E-01 -1.8586 125 PbO,aq 0.15414E-08 -8.8121 0.15414E-08 -8.8121 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.58022E-04 -4.2364 0.58022E-04 -4.2364 0.10000E+01 0.0000 128 Pb(HS)3- 0.29548E-05 -5.5295 0.94582E-06 -6.0242 0.32010E+00 -0.4947 129 H2S,aq 0.10358E+01 0.0153 0.12821E+01 0.1079 0.12378E+01 0.0926 130 S2-2 0.11819E-07 -7.9274 0.16368E-09 -9.7860 0.13849E-01 -1.8586 131 S3-2 0.14524E-08 -8.8379 0.20114E-10 -10.6965 0.13849E-01 -1.8586 132 S3- 0.26775E-01 -1.5723 0.85706E-02 -2.0670 0.32010E+00 -0.4947 133 S4-2 0.14641E-09 -9.8344 0.20277E-11 -11.6930 0.13849E-01 -1.8586 134 S5-2 0.12305E-10 -10.9099 0.17042E-12 -12.7685 0.13849E-01 -1.8586 135 SO2,aq 0.28251E+00 -0.5490 0.28251E+00 -0.5490 0.10000E+01 0.0000 136 SO3-2 0.56905E-09 -9.2448 0.11797E-10 -10.9282 0.20732E-01 -1.6834 137 HSO3- 0.49115E-03 -3.3088 0.15722E-03 -3.8035 0.32010E+00 -0.4947 138 HSO4- 0.13943E-01 -1.8556 0.50497E-02 -2.2967 0.36216E+00 -0.4411 140 S2O3-2 0.43337E-06 -6.3631 0.60019E-08 -8.2217 0.13849E-01 -1.8586 141 HS2O3- 0.10489E-05 -5.9793 0.33574E-06 -6.4740 0.32010E+00 -0.4947 142 H2S2O3,aq 0.30042E-07 -7.5223 0.30042E-07 -7.5223 0.10000E+01 0.0000 150 S4O6-2 0.88543E-09 -9.0528 0.12263E-10 -10.9114 0.13849E-01 -1.8586 152 ZnCl+ 0.90400E-03 -3.0438 0.32003E-03 -3.4948 0.35401E+00 -0.4510 153 ZnCl2,aq 0.11821E-02 -2.9273 0.11821E-02 -2.9273 0.10000E+01 0.0000 154 ZnCl3- 0.23327E-03 -3.6321 0.74671E-04 -4.1268 0.32010E+00 -0.4947 155 ZnO,aq 0.12516E-07 -7.9025 0.12516E-07 -7.9025 0.10000E+01 0.0000 156 ZnOH+ 0.27744E-05 -5.5568 0.98217E-06 -6.0078 0.35401E+00 -0.4510 158 HZnO2- 0.11848E-09 -9.9263 0.37927E-10 -10.4211 0.32010E+00 -0.4947 Charge balance for all species = 0.2556E-05 Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 19 andalusite -12.18 -9.26 2.92 0.292 -0.11652E+05 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.30 0.00 -0.30 -0.299 0.11936E+04 3.099 2 CO2,gas -8.56 -9.79 -1.22 -0.408 0.48901E+04 2.174 3 CH4,gas 6.83 -3.41 -10.24 -2.560 0.40915E+05 -6.843 4 H2,gas 5.66 1.59 -4.07 -2.324 0.16247E+05 -0.669 5 H2S,gas -7.09 -9.30 -2.21 -1.107 0.88418E+04 1.185 6 CO,gas -2.78 -8.19 -5.42 -1.667 0.21642E+05 -2.019 7 SO3,gas -5.65 -15.68 -10.03 -2.507 0.40062E+05 -6.629 8 O2,gas 13.14 -3.19 -16.33 -10.887 0.65247E+05 -12.933 9 HCl,gas -1.95 -6.01 -4.06 -2.032 0.16240E+05 -4.065 10 acmite 4.29 1.88 -2.41 -0.250 0.96202E+04 12 akimotoite 5.92 1.26 -4.66 -0.933 0.18629E+05 13 akimotoite-Fe 3.93 -0.38 -4.31 -0.862 0.17220E+05 14 albite-high -3.94 -2.82 1.11 0.086 -0.44454E+04 15 albite -3.90 -2.82 1.07 0.083 -0.42896E+04 16 almandine -9.92 -9.58 0.34 0.017 -0.13550E+04 17 pyrope -3.62 -4.65 -1.03 -0.051 0.41094E+04 18 analcite -2.33 -1.99 0.34 0.038 -0.13536E+04 21 grossular -0.01 -2.91 -2.90 -0.145 0.11579E+05 22 anhydrite -12.53 -13.01 -0.48 -0.238 0.19049E+04 24 annite -0.19 -2.00 -1.82 -0.101 0.72529E+04 25 phlogopite 4.17 2.93 -1.24 -0.069 0.49542E+04 27 anorthite -9.60 -7.42 2.18 0.168 -0.87015E+04 30 apatite-OH -46.71 -48.41 -1.70 -0.131 0.68047E+04 31 apatite-OH-zs -44.65 -48.41 -3.76 -0.289 0.15031E+05 32 apatite-Cl-zs -49.89 -54.42 -4.53 -0.377 0.18088E+05 33 aragonite -3.50 -7.12 -3.61 -1.204 0.14426E+05 34 brucite 4.89 2.09 -2.80 -0.560 0.11189E+05 35 calcite -3.58 -7.12 -3.53 -1.178 0.14114E+05 36 carnegieite-low -0.65 -1.16 -0.50 -0.072 0.20154E+04 37 carnegieite-high -0.59 -1.16 -0.57 -0.081 0.22591E+04 38 carpholite-Mg -8.88 -8.01 0.87 0.058 -0.34926E+04 39 carpholite-Fe -10.16 -9.65 0.51 0.034 -0.20525E+04 40 celadonite -0.68 -2.09 -1.41 -0.083 0.56319E+04 41 celadonite-Fe -2.02 -3.73 -1.71 -0.101 0.68323E+04 42 chrysotile 8.91 4.61 -4.30 -0.358 0.17182E+05 44 clinochlore 0.80 -0.48 -1.28 -0.040 0.51184E+04 45 daphnite -5.88 -8.69 -2.81 -0.088 0.11208E+05 48 chloritoid-Mg -8.67 -7.17 1.50 0.100 -0.59968E+04 49 chloritoid-Fe -10.49 -8.81 1.68 0.112 -0.66942E+04 50 chloritoid-Mn -8.33 -7.57 0.76 0.051 -0.30304E+04 52 coesite -0.57 -0.83 -0.26 -0.088 0.10586E+04 53 cordierite-H -21.45 -16.84 4.61 0.164 -0.18402E+05 54 cordierite-Fe -23.65 -20.12 3.53 0.122 -0.14091E+05 55 cordierite-Mn -19.25 -17.64 1.61 0.056 -0.64353E+04 56 corundum -11.20 -8.43 2.77 0.252 -0.11073E+05 58 cristobalite -0.76 -0.83 -0.07 -0.024 0.28753E+03 61 cymrite-K -2.45 -3.35 -0.90 -0.075 0.35998E+04 63 diaspore -5.12 -4.22 0.91 0.151 -0.36250E+04 65 diopside 5.53 3.10 -2.43 -0.243 0.97214E+04 66 hedenbergite 4.19 1.46 -2.73 -0.273 0.10922E+05 68 eastonite -8.77 -6.76 2.01 0.077 -0.80268E+04 69 enstatite 4.65 2.52 -2.13 -0.213 0.85073E+04 70 clinoenstatite-HiP 5.11 2.52 -2.60 -0.260 0.10369E+05 71 clinoenstatite 4.64 2.52 -2.12 -0.212 0.84673E+04 72 protoenstatite 4.78 2.52 -2.27 -0.227 0.90506E+04 73 epidote -5.73 -5.93 -0.20 -0.010 0.80613E+03 74 clinozoisite -11.43 -9.80 1.63 0.074 -0.65111E+04 75 epidote-Fe 1.61 -2.07 -3.68 -0.191 0.14700E+05 76 fayalite 2.03 0.07 -1.97 -0.281 0.78597E+04 77 ferrosilite 1.27 -0.77 -2.04 -0.204 0.81512E+04 78 forsterite 5.82 3.35 -2.47 -0.352 0.98538E+04 79 gedrite -12.92 -11.40 1.52 0.041 -0.60842E+04 80 gehlenite -0.27 -3.92 -3.64 -0.202 0.14562E+05 81 gibbsite -3.61 -4.22 -0.61 -0.087 0.24393E+04 82 glaucophane 1.38 -1.04 -2.42 -0.065 0.96628E+04 83 glaucophane-Fe -2.42 -5.96 -3.54 -0.096 0.14163E+05 84 goethite 0.97 -0.35 -1.32 -0.285 0.52665E+04 86 greenalite 4.36 -0.32 -4.68 -0.390 0.18718E+05 88 halite 0.05 -2.12 -2.16 -1.082 0.86483E+04 89 hematite 0.51 -0.70 -1.20 -0.146 0.47963E+04 90 heulandite -11.84 -11.60 0.24 0.011 -0.95184E+03 91 hercynite -9.78 -7.98 1.80 0.120 -0.71927E+04 94 jadeite -1.69 -1.99 -0.30 -0.030 0.12162E+04 96 kalsilite -1.32 -1.68 -0.36 -0.052 0.14513E+04 97 kaolinite -10.84 -10.10 0.74 0.067 -0.29599E+04 98 kyanite -12.06 -9.26 2.80 0.280 -0.11189E+05 100 laumontite -8.69 -9.10 -0.41 -0.027 0.16392E+04 101 lawsonite -7.12 -7.43 -0.31 -0.021 0.12415E+04 102 leucite -2.77 -2.52 0.26 0.026 -0.10340E+04 104 lizardite 9.10 4.61 -4.50 -0.375 0.17973E+05 105 magnesite -4.58 -7.70 -3.12 -1.039 0.12452E+05 106 magnetite 1.42 -0.25 -1.67 -0.136 0.66706E+04 107 minnesotaite 1.51 -1.98 -3.49 -0.205 0.13956E+05 108 minnesotaite-Mg 7.15 2.94 -4.21 -0.248 0.16827E+05 109 magnesioferrite 4.35 1.40 -2.95 -0.241 0.11803E+05 111 manganosite 5.02 1.69 -3.33 -0.832 0.13297E+05 112 margarite -20.41 -15.85 4.56 0.182 -0.18217E+05 113 meionite -31.60 -29.38 2.22 0.053 -0.88663E+04 115 microcline -4.50 -3.35 1.15 0.089 -0.46100E+04 116 monticellite 8.49 3.93 -4.56 -0.651 0.18220E+05 118 mullite-Si -11.49 -9.26 2.23 0.223 -0.88914E+04 119 muscovite -15.65 -11.78 3.88 0.228 -0.15484E+05 120 paragonite -14.96 -11.25 3.71 0.218 -0.14804E+05 121 nepheline -0.94 -1.16 -0.21 -0.031 0.85676E+03 122 osumilite(2) -12.69 -12.16 0.53 0.011 -0.21035E+04 123 osumilite-Fe -29.54 -25.14 4.40 0.092 -0.17582E+05 124 pargasite 2.62 -0.04 -2.66 -0.070 0.10618E+05 125 periclase 5.12 2.09 -3.02 -0.756 0.12077E+05 126 periclase-Fe 2.65 0.45 -2.20 -0.551 0.88063E+04 127 perovskite-Al -9.54 -8.43 1.11 0.101 -0.44244E+04 132 phlogopite-Na 5.05 3.45 -1.60 -0.089 0.64013E+04 133 piemontite(ordered) -0.83 -4.69 -3.86 -0.187 0.15425E+05 134 prehnite -4.84 -5.59 -0.74 -0.044 0.29703E+04 135 prehnite-Fe 1.26 -1.72 -2.98 -0.179 0.11918E+05 136 pumpellyite-Fe -12.52 -14.94 -2.42 -0.054 0.96669E+04 137 pumpellyite-Mg -10.99 -13.30 -2.31 -0.051 0.92176E+04 138 px-Mg-tschermaks -8.09 -7.17 0.92 0.065 -0.36627E+04 139 px-Ca-tschermaks -7.02 -6.59 0.43 0.031 -0.17174E+04 140 pyrite -19.19 -19.75 -0.55 -0.130 0.22049E+04 141 pyrrhotite -7.70 -8.85 -1.15 -0.383 0.45922E+04 142 pyrrhotiteFe0.875 -8.39 -9.10 -0.71 -0.262 0.28504E+04 143 pyrophyllite -13.88 -11.76 2.11 0.132 -0.84491E+04 144 quartz -0.83 -0.83 0.00 0.000 0.38542E+01 147 ringwoodite-Fe 2.99 0.07 -2.92 -0.417 0.11671E+05 149 rhodochrosite -4.40 -8.10 -3.69 -1.231 0.14755E+05 150 rhodonite 2.61 0.86 -1.76 -0.351 0.70163E+04 151 sanidine -3.99 -3.35 0.64 0.049 -0.25444E+04 152 sapphirine(351) -46.28 -36.70 9.58 0.145 -0.38263E+05 153 siderite -6.30 -9.34 -3.03 -1.011 0.12118E+05 154 sillimanite -12.16 -9.26 2.90 0.290 -0.11580E+05 155 sodalite -7.48 -11.18 -3.70 -0.080 0.14782E+05 156 spinel -7.71 -6.34 1.37 0.092 -0.54885E+04 158 staurolite-Fe -102.67 -80.31 22.36 0.204 -0.89317E+05 159 staurolite-Mg -94.67 -73.74 20.93 0.191 -0.83627E+05 160 staurolite-Mn -93.65 -75.35 18.30 0.167 -0.73124E+05 161 stilbite -8.02 -11.61 -3.59 -0.171 0.14346E+05 162 stilpnomelane-Fe -7.33 -11.18 -3.84 -0.115 0.15354E+05 163 stilpnomelane-Mg -1.06 -2.97 -1.90 -0.057 0.76100E+04 164 stishovite 1.97 -0.83 -2.81 -0.936 0.11215E+05 165 sudoite-Fe -20.45 -18.47 1.98 0.064 -0.79085E+04 166 sudoite -18.36 -15.18 3.17 0.102 -0.12679E+05 167 sulfur -9.45 -10.90 -1.45 -0.446 0.57873E+04 168 sylvite 0.12 -2.64 -2.77 -1.383 0.11049E+05 169 talc 5.45 2.94 -2.51 -0.148 0.10027E+05 170 talc-Fe 2.81 -1.98 -4.80 -0.282 0.19174E+05 171 talc-tschermaks -7.21 -6.75 0.46 0.027 -0.18432E+04 173 tephroite 6.35 2.55 -3.80 -0.543 0.15175E+05 176 topaz-H -10.22 -9.26 0.96 0.087 -0.38380E+04 179 troilite-low -7.60 -8.85 -1.25 -0.416 0.49917E+04 180 tschermakite -10.92 -10.24 0.69 0.019 -0.27370E+04 183 wadsleyite-Fe 2.84 0.07 -2.77 -0.396 0.11068E+05 184 wadsleyite-Mg 7.93 3.35 -4.58 -0.654 0.18292E+05 185 wairakite -10.28 -9.09 1.18 0.070 -0.47239E+04 186 walstromite 4.74 1.84 -2.90 -0.581 0.11597E+05 187 wollastonite 4.36 1.84 -2.52 -0.504 0.10062E+05 188 pseudo-wollastonite 4.46 1.84 -2.62 -0.525 0.10482E+05 189 zoisite -11.49 -9.80 1.70 0.077 -0.67788E+04 192 beidellite-Ca -14.70 -12.44 2.26 0.140 -0.90329E+04 193 beidellite-H -14.71 -12.88 1.83 0.117 -0.73212E+04 194 beidellite-K -13.64 -11.77 1.87 0.115 -0.74767E+04 195 beidellite-Mg -15.04 -12.53 2.50 0.155 -0.10001E+05 196 beidellite-Na -13.57 -11.60 1.98 0.121 -0.78943E+04 197 bornite -48.01 -48.60 -0.60 -0.045 0.23931E+04 199 chalcocite -12.39 -13.72 -1.33 -0.333 0.53288E+04 200 covellite -10.99 -12.31 -1.32 -0.504 0.52824E+04 202 montmorillonite-Ca -10.56 -9.24 1.32 0.081 -0.52614E+04 203 montmorillonite-K -9.80 -8.57 1.23 0.075 -0.48998E+04 204 montmorillonite-Mg -10.80 -9.34 1.47 0.091 -0.58618E+04 205 montmorillonite-Na -9.41 -8.40 1.01 0.062 -0.40269E+04 206 nontronite-Ca -2.78 -4.71 -1.92 -0.125 0.76752E+04 207 nontronite-H -2.81 -5.15 -2.34 -0.157 0.93549E+04 208 nontronite-K -1.73 -4.04 -2.31 -0.148 0.92234E+04 209 nontronite-Mg -3.05 -4.80 -1.75 -0.114 0.70069E+04 210 nontronite-Na -1.66 -3.86 -2.21 -0.142 0.88178E+04 215 gypsum -10.53 -13.01 -2.49 -0.622 0.99420E+04 232 alabandite -5.43 -7.61 -2.18 -0.726 0.87075E+04 233 alunite -36.68 -40.65 -3.97 -0.220 0.15853E+05 234 anglesite -12.63 -15.55 -2.92 -1.460 0.11664E+05 237 barite -13.53 -14.04 -0.51 -0.254 0.20324E+04 238 boehmite -4.85 -4.22 0.63 0.105 -0.25262E+04 240 chalcopyrite -20.67 -21.16 -0.49 -0.091 0.19597E+04 242 copper,native 1.83 -1.41 -3.24 -1.128 0.12960E+05 244 ferrous-oxide 1.75 0.45 -1.30 -0.326 0.52064E+04 245 galena -8.38 -9.17 -0.79 -0.264 0.31617E+04 246 silver,native 0.59 -3.93 -4.52 -1.572 0.18054E+05 255 sphalerite -9.79 -10.48 -0.69 -0.230 0.27600E+04 256 wurtzite -9.02 -10.48 -1.46 -0.488 0.58444E+04 257 zincite 1.93 -1.18 -3.11 -0.778 0.12432E+05 258 an20ab80 -5.25 -3.74 1.51 0.116 -0.60398E+04 259 an25ab75 -5.57 -3.97 1.59 0.123 -0.63674E+04 260 an30ab70 -5.87 -4.20 1.67 0.128 -0.66711E+04 261 tr.625ac.25prg.125 10.17 5.94 -4.23 -0.114 0.16914E+05 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 17 Loop limit = 500 Temperature = 600.00 C Pressure = 2500.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5496E+02 kg liquid = 0.9902E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9936 Stoichiometric ionic strength = .3315640E+01 Osmotic coef. = 0.0000 True ionic strength = .3304564E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.32596E-04 -4.4868 0.10534E-04 -4.9774 0.32316E+00 -0.4906 2 H2O 0.99357E+00 -0.0028 0.99357E+00 -0.0028 3 Cl- 0.28524E+00 -0.5448 0.91321E-01 -1.0394 0.32016E+00 -0.4946 4 SO4-- 0.12529E-03 -3.9021 0.18603E-05 -5.7304 0.14847E-01 -1.8283 5 HCO3- 0.44803E-04 -4.3487 0.15366E-04 -4.8134 0.34297E+00 -0.4647 6 HS- 0.14634E-03 -3.8346 0.47214E-04 -4.3259 0.32264E+00 -0.4913 7 H4SiO4 0.14468E+00 -0.8396 0.14468E+00 -0.8396 0.10000E+01 0.0000 8 Al+++ 0.43532E-16 -16.3612 0.25115E-20 -20.6001 0.57692E-04 -4.2389 9 Ca++ 0.43945E-05 -5.3571 0.54024E-07 -7.2674 0.12294E-01 -1.9103 10 Mg++ 0.13804E-05 -5.8600 0.14203E-07 -7.8476 0.10289E-01 -1.9876 11 Fe++ 0.30048E-07 -7.5222 0.32355E-09 -9.4901 0.10768E-01 -1.9679 12 K+ 0.70622E-01 -1.1511 0.24807E-01 -1.6054 0.35126E+00 -0.4544 13 Na+ 0.25706E+00 -0.5900 0.83356E-01 -1.0791 0.32427E+00 -0.4891 14 Mn++ 0.50651E-06 -6.2954 0.56373E-08 -8.2489 0.11130E-01 -1.9535 15 Zn++ 0.69735E-09 -9.1566 0.75088E-11 -11.1244 0.10768E-01 -1.9679 16 Cu+ 0.20368E-06 -6.6911 0.65883E-07 -7.1812 0.32347E+00 -0.4902 17 Pb++ 0.11323E-07 -7.9460 0.15412E-09 -9.8121 0.13611E-01 -1.8661 18 Ag+ 0.58533E-09 -9.2326 0.20268E-09 -9.6932 0.34627E+00 -0.4606 19 Ba++ 0.34752E-06 -6.4590 0.50416E-08 -8.2974 0.14507E-01 -1.8384 20 HPO4-- 0.15155E-08 -8.8194 0.22602E-10 -10.6459 0.14914E-01 -1.8264 21 HSiO3- 0.26562E-05 -5.5757 0.85040E-06 -6.0704 0.32016E+00 -0.4946 22 Ca(HSiO3)+ 0.19193E-07 -7.7169 0.67954E-08 -8.1678 0.35406E+00 -0.4509 23 Mg(HSiO3)+ 0.12076E-08 -8.9181 0.42758E-09 -9.3690 0.35406E+00 -0.4509 24 NaHSiO3,aq 0.96064E-06 -6.0174 0.96064E-06 -6.0174 0.10000E+01 0.0000 28 AgCl,aq 0.62428E-07 -7.2046 0.62428E-07 -7.2046 0.10000E+01 0.0000 29 AgCl2- 0.47379E-05 -5.3244 0.15169E-05 -5.8190 0.32016E+00 -0.4946 30 AgCl3-2 0.28694E-05 -5.5422 0.39767E-07 -7.4005 0.13859E-01 -1.8583 31 AgCl4-3 0.11150E-05 -5.9527 0.55602E-10 -10.2549 0.49868E-04 -4.3022 34 Ag(HS),aq 0.31907E-09 -9.4961 0.31907E-09 -9.4961 0.10000E+01 0.0000 35 Ag(HS)2- 0.16315E-08 -8.7874 0.52234E-09 -9.2820 0.32016E+00 -0.4946 36 AlO+ 0.31325E-10 -10.5041 0.11091E-10 -10.9550 0.35406E+00 -0.4509 38 HAlO2,aq 0.57756E-08 -8.2384 0.57756E-08 -8.2384 0.10000E+01 0.0000 39 AlO2- 0.24789E-04 -4.6057 0.69988E-05 -5.1550 0.28234E+00 -0.5492 41 Ba(HCO3)+ 0.13663E-05 -5.8644 0.50135E-06 -6.2999 0.36693E+00 -0.4354 42 BaCl+ 0.54208E-04 -4.2659 0.19193E-04 -4.7169 0.35406E+00 -0.4509 43 CH4,aq 0.22268E-08 -8.6523 0.27559E-08 -8.5597 0.12376E+01 0.0926 48 CO,aq 0.10409E-02 -2.9826 0.10409E-02 -2.9826 0.10000E+01 0.0000 49 CO2,aq 0.26814E+01 0.4284 0.33185E+01 0.5209 0.12376E+01 0.0926 50 CO3-2 0.68588E-10 -10.1637 0.95058E-12 -12.0220 0.13859E-01 -1.8583 51 CaCO3,aq 0.13950E-10 -10.8554 0.13950E-10 -10.8554 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.14095E-05 -5.8509 0.49906E-06 -6.3018 0.35406E+00 -0.4509 53 CaCl+ 0.39453E-03 -3.4039 0.13969E-03 -3.8548 0.35406E+00 -0.4509 54 CaCl2,aq 0.13235E-03 -3.8783 0.13235E-03 -3.8783 0.10000E+01 0.0000 55 CaOH+ 0.38383E-06 -6.4159 0.13590E-06 -6.8668 0.35406E+00 -0.4509 56 CaSO4,aq 0.58098E-07 -7.2358 0.58098E-07 -7.2358 0.10000E+01 0.0000 57 HCl,aq 0.10943E-02 -2.9609 0.10943E-02 -2.9609 0.10000E+01 0.0000 63 CuCl2,aq 0.14360E-10 -10.8428 0.14360E-10 -10.8428 0.10000E+01 0.0000 66 CuCl,aq 0.80601E-04 -4.0937 0.80601E-04 -4.0937 0.10000E+01 0.0000 67 CuCl2- 0.31300E-03 -3.5044 0.10021E-03 -3.9991 0.32016E+00 -0.4946 68 CuCl3-2 0.97667E-05 -5.0103 0.13536E-06 -6.8685 0.13859E-01 -1.8583 74 FeCl+ 0.84612E-06 -6.0726 0.29958E-06 -6.5235 0.35406E+00 -0.4509 75 FeCl2,aq 0.88528E-02 -2.0529 0.88528E-02 -2.0529 0.10000E+01 0.0000 77 FeO,aq 0.30619E-07 -7.5140 0.30619E-07 -7.5140 0.10000E+01 0.0000 78 FeOH+ 0.45760E-07 -7.3395 0.16202E-07 -7.7904 0.35406E+00 -0.4509 79 HFeO2- 0.48001E-08 -8.3188 0.15368E-08 -8.8134 0.32016E+00 -0.4946 82 FeO2- 0.22486E-08 -8.6481 0.71989E-09 -9.1427 0.32016E+00 -0.4946 83 HFeO2,aq 0.72585E-10 -10.1392 0.72585E-10 -10.1392 0.10000E+01 0.0000 84 H2,aq 0.39093E-02 -2.4079 0.48382E-02 -2.3153 0.12376E+01 0.0926 85 KCl,aq 0.43465E-01 -1.3619 0.43465E-01 -1.3619 0.10000E+01 0.0000 86 KHSO4,aq 0.10464E-01 -1.9803 0.10464E-01 -1.9803 0.10000E+01 0.0000 87 KOH,aq 0.55232E-06 -6.2578 0.55232E-06 -6.2578 0.10000E+01 0.0000 88 KSO4- 0.21027E-02 -2.6772 0.67319E-03 -3.1719 0.32016E+00 -0.4946 90 Mg(HCO3)+ 0.16706E-06 -6.7771 0.59150E-07 -7.2280 0.35406E+00 -0.4509 91 MgCl+ 0.18918E-04 -4.7231 0.66982E-05 -5.1740 0.35406E+00 -0.4509 92 MgOH+ 0.41489E-06 -6.3821 0.14690E-06 -6.8330 0.35406E+00 -0.4509 94 MnO,aq 0.78004E-08 -8.1079 0.78004E-08 -8.1079 0.10000E+01 0.0000 95 MnOH+ 0.10084E-06 -6.9964 0.35702E-07 -7.4473 0.35406E+00 -0.4509 100 MnCl+ 0.11603E-02 -2.9354 0.41081E-03 -3.3864 0.35406E+00 -0.4509 101 MnSO4,aq 0.76850E-08 -8.1144 0.76850E-08 -8.1144 0.10000E+01 0.0000 102 NaCl,aq 0.30305E+00 -0.5185 0.30305E+00 -0.5185 0.10000E+01 0.0000 103 NaOH,aq 0.82901E-06 -6.0814 0.82901E-06 -6.0814 0.10000E+01 0.0000 105 OH- 0.99507E-05 -5.0021 0.28095E-05 -5.5514 0.28234E+00 -0.5492 110 HPO3-2 0.31038E-10 -10.5081 0.43016E-12 -12.3664 0.13859E-01 -1.8583 111 H3PO3,aq 0.30745E-09 -9.5122 0.30745E-09 -9.5122 0.10000E+01 0.0000 112 H2PO3- 0.14516E-07 -7.8382 0.46473E-08 -8.3328 0.32016E+00 -0.4946 113 H3PO4,aq 0.16607E-05 -5.7797 0.16607E-05 -5.7797 0.10000E+01 0.0000 114 H2PO4- 0.40848E-05 -5.3888 0.13700E-05 -5.8633 0.33539E+00 -0.4744 116 H4P2O7,aq 0.21948E-09 -9.6586 0.21948E-09 -9.6586 0.10000E+01 0.0000 117 H3P2O7- 0.61867E-08 -8.2085 0.19807E-08 -8.7032 0.32016E+00 -0.4946 118 H2P2O7-2 0.14174E-05 -5.8485 0.19645E-07 -7.7068 0.13859E-01 -1.8583 119 HP2O7-3 0.21471E-07 -7.6682 0.10707E-11 -11.9703 0.49868E-04 -4.3022 121 PbCl+ 0.52402E-05 -5.2807 0.18554E-05 -5.7316 0.35406E+00 -0.4509 122 PbCl2,aq 0.11246E-03 -3.9490 0.11246E-03 -3.9490 0.10000E+01 0.0000 123 PbCl3- 0.12595E-03 -3.8998 0.40324E-04 -4.3944 0.32016E+00 -0.4946 124 PbCl4-2 0.37532E-04 -4.4256 0.52016E-06 -6.2839 0.13859E-01 -1.8583 125 PbO,aq 0.15773E-08 -8.8021 0.15773E-08 -8.8021 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.59292E-04 -4.2270 0.59292E-04 -4.2270 0.10000E+01 0.0000 128 Pb(HS)3- 0.30599E-05 -5.5143 0.97965E-06 -6.0089 0.32016E+00 -0.4946 129 H2S,aq 0.10353E+01 0.0151 0.12813E+01 0.1076 0.12376E+01 0.0926 130 S2-2 0.12126E-07 -7.9163 0.16806E-09 -9.7745 0.13859E-01 -1.8583 131 S3-2 0.14883E-08 -8.8273 0.20627E-10 -10.6856 0.13859E-01 -1.8583 132 S3- 0.27059E-01 -1.5677 0.86630E-02 -2.0623 0.32016E+00 -0.4946 133 S4-2 0.14985E-09 -9.8243 0.20768E-11 -11.6826 0.13859E-01 -1.8583 134 S5-2 0.12578E-10 -10.9004 0.17433E-12 -12.7586 0.13859E-01 -1.8583 135 SO2,aq 0.28184E+00 -0.5500 0.28184E+00 -0.5500 0.10000E+01 0.0000 136 SO3-2 0.58367E-09 -9.2338 0.12107E-10 -10.9169 0.20744E-01 -1.6831 137 HSO3- 0.49690E-03 -3.3037 0.15908E-03 -3.7984 0.32016E+00 -0.4946 138 HSO4- 0.14099E-01 -1.8508 0.51068E-02 -2.2919 0.36220E+00 -0.4410 140 S2O3-2 0.44390E-06 -6.3527 0.61521E-08 -8.2110 0.13859E-01 -1.8583 141 HS2O3- 0.10598E-05 -5.9748 0.33931E-06 -6.4694 0.32016E+00 -0.4946 142 H2S2O3,aq 0.29935E-07 -7.5238 0.29935E-07 -7.5238 0.10000E+01 0.0000 150 S4O6-2 0.90318E-09 -9.0442 0.12517E-10 -10.9025 0.13859E-01 -1.8583 152 ZnCl+ 0.90378E-03 -3.0439 0.31999E-03 -3.4949 0.35406E+00 -0.4509 153 ZnCl2,aq 0.11823E-02 -2.9273 0.11823E-02 -2.9273 0.10000E+01 0.0000 154 ZnCl3- 0.23330E-03 -3.6321 0.74693E-04 -4.1267 0.32016E+00 -0.4946 155 ZnO,aq 0.12871E-07 -7.8904 0.12871E-07 -7.8904 0.10000E+01 0.0000 156 ZnOH+ 0.28126E-05 -5.5509 0.99584E-06 -6.0018 0.35406E+00 -0.4509 158 HZnO2- 0.12356E-09 -9.9081 0.39558E-10 -10.4028 0.32016E+00 -0.4946 Charge balance for all species = 0.2556E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3259590E-04 0.4306705E+01 0.3521924E+04 0.0000 2 H2O 0.1000000E+01 0.5248030E+02 0.7670754E+06 0.0000 3 Cl- 0.2852386E+00 0.6579277E+00 0.1892481E+05 3.9380 4 SO4-- 0.1252909E-03 0.2542216E+00 0.1981356E+05 4.2244 5 HCO3- 0.4480274E-04 0.2682480E+01 0.1327972E+06 0.1640 6 HS- 0.1463360E-03 0.1171661E+01 0.3143856E+05 0.6515 7 H4SiO4 0.1446778E+00 0.1446815E+00 0.1128252E+05 -0.8396 8 Al+++ 0.4353245E-16 0.2479436E-04 0.5427743E+00 -5.6678 9 Ca++ 0.4394506E-05 0.5331505E-03 0.1733629E+02 2.6874 10 Mg++ 0.1380436E-05 0.2088191E-04 0.4118994E+00 2.1072 11 Fe++ 0.3004827E-07 0.8853782E-02 0.4011704E+03 0.4648 12 K+ 0.7062241E-01 0.1266551E+00 0.4018110E+04 3.3720 13 Na+ 0.2570572E+00 0.5601049E+00 0.1044732E+05 3.8984 14 Mn++ 0.5065123E-06 0.1160911E-02 0.5174544E+02 1.7059 15 Zn++ 0.6973463E-09 0.2322160E-02 0.1231604E+03 -1.1696 16 Cu+ 0.2036755E-06 0.4035766E-03 0.2080528E+02 -2.2038 17 Pb++ 0.1132308E-07 0.3435495E-03 0.5775086E+02 0.1427 18 Ag+ 0.5853267E-09 0.8787215E-05 0.7690458E+00 -4.7158 19 Ba++ 0.3475228E-06 0.5592214E-04 0.6231334E+01 1.6574 20 HPO4-- 0.1515496E-08 0.8652550E-05 0.6737838E+00 -0.6910 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4264372E+01 -.2009967E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5196444E+02 0.3349944E-03 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517228E+00 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160144E+01 0.0000000E+00 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1432593E+00 0.3349944E-03 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2455065E-04 0.6699889E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.5279099E-03 0.0000000E+00 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8766754E-02 0.0000000E+00 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3996097E-03 0.0000000E+00 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.122042E+04 g Temperature = 600.00 C Pressure = 2500.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) andalusite 0.3350E-03 -3.475 0.5429E-01 -1.265 100.0 0.1726E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity andalusite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.054286 g Volume = 0.017261 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 19 andalusite -12.18 -12.18 0.00 0.000 0.14194E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.30 0.00 -0.30 -0.299 0.11936E+04 3.099 2 CO2,gas -8.56 -9.79 -1.22 -0.408 0.48903E+04 2.174 3 CH4,gas 6.83 -3.41 -10.24 -2.560 0.40911E+05 -6.842 4 H2,gas 5.66 1.59 -4.07 -2.324 0.16246E+05 -0.668 5 H2S,gas -7.09 -9.30 -2.21 -1.107 0.88430E+04 1.185 6 CO,gas -2.78 -8.19 -5.42 -1.667 0.21641E+05 -2.019 7 SO3,gas -5.65 -15.68 -10.03 -2.507 0.40067E+05 -6.630 8 O2,gas 13.14 -3.19 -16.33 -10.887 0.65249E+05 -12.933 9 HCl,gas -1.95 -6.02 -4.07 -2.035 0.16264E+05 -4.071 10 acmite 4.29 1.89 -2.39 -0.248 0.95561E+04 12 akimotoite 5.92 1.27 -4.65 -0.930 0.18585E+05 13 akimotoite-Fe 3.93 -0.37 -4.30 -0.860 0.17176E+05 14 albite-high -3.94 -4.28 -0.34 -0.026 0.13666E+04 15 albite -3.90 -4.28 -0.38 -0.029 0.15224E+04 16 almandine -9.92 -12.46 -2.54 -0.127 0.10160E+05 17 pyrope -3.62 -7.53 -3.91 -0.196 0.15625E+05 18 analcite -2.33 -3.45 -1.11 -0.124 0.44542E+04 22 anhydrite -12.53 -13.00 -0.47 -0.233 0.18612E+04 24 annite -0.19 -3.42 -3.23 -0.180 0.12922E+05 25 phlogopite 4.17 1.51 -2.66 -0.148 0.10623E+05 27 anorthite -9.60 -10.33 -0.73 -0.056 0.29061E+04 30 apatite-OH -46.71 -48.37 -1.66 -0.128 0.66232E+04 31 apatite-OH-zs -44.65 -48.37 -3.72 -0.286 0.14850E+05 32 apatite-Cl-zs -49.89 -54.38 -4.49 -0.374 0.17930E+05 33 aragonite -3.50 -7.10 -3.60 -1.199 0.14377E+05 34 brucite 4.89 2.10 -2.79 -0.558 0.11141E+05 35 calcite -3.58 -7.10 -3.52 -1.173 0.14065E+05 36 carnegieite-low -0.65 -2.61 -1.96 -0.280 0.78191E+04 37 carnegieite-high -0.59 -2.61 -2.02 -0.288 0.80629E+04 38 carpholite-Mg -8.88 -10.91 -2.03 -0.135 0.81153E+04 39 carpholite-Fe -10.16 -12.56 -2.39 -0.159 0.95554E+04 40 celadonite -0.68 -3.54 -2.85 -0.168 0.11402E+05 41 celadonite-Fe -2.02 -5.18 -3.15 -0.186 0.12602E+05 42 chrysotile 8.91 4.64 -4.27 -0.356 0.17045E+05 44 clinochlore 0.80 -3.34 -4.14 -0.129 0.16537E+05 48 chloritoid-Mg -8.67 -10.08 -1.40 -0.094 0.56070E+04 49 chloritoid-Fe -10.49 -11.72 -1.23 -0.082 0.49096E+04 50 chloritoid-Mn -8.33 -10.48 -2.15 -0.143 0.85728E+04 52 coesite -0.57 -0.83 -0.27 -0.089 0.10628E+04 53 cordierite-H -21.45 -22.65 -1.21 -0.043 0.48181E+04 54 cordierite-Fe -23.65 -25.93 -2.29 -0.079 0.91295E+04 55 cordierite-Mn -19.25 -23.45 -4.20 -0.145 0.16784E+05 56 corundum -11.20 -11.34 -0.14 -0.013 0.57535E+03 58 cristobalite -0.76 -0.83 -0.07 -0.024 0.29165E+03 61 cymrite-K -2.45 -4.81 -2.36 -0.196 0.94139E+04 63 diaspore -5.12 -5.67 -0.55 -0.092 0.21991E+04 65 diopside 5.53 3.12 -2.41 -0.241 0.96326E+04 66 hedenbergite 4.19 1.48 -2.71 -0.271 0.10833E+05 68 eastonite -8.77 -11.11 -2.34 -0.090 0.93346E+04 69 enstatite 4.65 2.54 -2.11 -0.211 0.84188E+04 70 clinoenstatite-HiP 5.11 2.54 -2.57 -0.257 0.10281E+05 71 clinoenstatite 4.64 2.54 -2.10 -0.210 0.83788E+04 72 protoenstatite 4.78 2.54 -2.24 -0.224 0.89622E+04 73 epidote -5.73 -8.81 -3.08 -0.150 0.12321E+05 74 clinozoisite -11.43 -14.15 -2.72 -0.124 0.10876E+05 76 fayalite 2.03 0.09 -1.94 -0.278 0.77671E+04 77 ferrosilite 1.27 -0.74 -2.02 -0.202 0.80628E+04 78 forsterite 5.82 3.37 -2.44 -0.349 0.97612E+04 79 gedrite -12.92 -17.17 -4.25 -0.115 0.16995E+05 81 gibbsite -3.61 -5.68 -2.07 -0.295 0.82633E+04 84 goethite 0.97 -0.34 -1.31 -0.282 0.52186E+04 86 greenalite 4.36 -0.29 -4.65 -0.388 0.18581E+05 88 halite 0.05 -2.12 -2.16 -1.082 0.86480E+04 89 hematite 0.51 -0.67 -1.18 -0.143 0.47006E+04 90 heulandite -11.84 -14.51 -2.67 -0.121 0.10676E+05 91 hercynite -9.78 -10.88 -1.10 -0.074 0.44070E+04 94 jadeite -1.69 -3.44 -1.76 -0.176 0.70240E+04 96 kalsilite -1.32 -3.14 -1.82 -0.259 0.72573E+04 97 kaolinite -10.84 -13.02 -2.18 -0.198 0.86964E+04 98 kyanite -12.06 -12.18 -0.12 -0.012 0.46347E+03 100 laumontite -8.69 -12.01 -3.32 -0.221 0.13255E+05 101 lawsonite -7.12 -10.33 -3.22 -0.214 0.12849E+05 102 leucite -2.77 -3.97 -1.20 -0.120 0.47761E+04 104 lizardite 9.10 4.64 -4.46 -0.372 0.17837E+05 105 magnesite -4.58 -7.68 -3.10 -1.035 0.12404E+05 106 magnetite 1.42 -0.21 -1.63 -0.133 0.65266E+04 107 minnesotaite 1.51 -1.95 -3.46 -0.204 0.13827E+05 108 minnesotaite-Mg 7.15 2.97 -4.18 -0.246 0.16699E+05 109 magnesioferrite 4.35 1.43 -2.92 -0.238 0.11659E+05 111 manganosite 5.02 1.70 -3.32 -0.829 0.13248E+05 112 margarite -20.41 -21.67 -1.26 -0.050 0.50388E+04 115 microcline -4.50 -4.80 -0.30 -0.023 0.12042E+04 116 monticellite 8.49 3.96 -4.54 -0.648 0.18127E+05 118 mullite-Si -11.49 -12.18 -0.69 -0.069 0.27608E+04 119 muscovite -15.65 -16.15 -0.50 -0.029 0.19785E+04 120 paragonite -14.96 -15.62 -0.66 -0.039 0.26563E+04 121 nepheline -0.94 -2.61 -1.67 -0.238 0.66605E+04 122 osumilite(2) -12.69 -16.51 -3.82 -0.080 0.15247E+05 123 osumilite-Fe -29.54 -32.41 -2.87 -0.060 0.11460E+05 125 periclase 5.12 2.10 -3.01 -0.753 0.12028E+05 126 periclase-Fe 2.65 0.46 -2.19 -0.548 0.87580E+04 127 perovskite-Al -9.54 -11.34 -1.81 -0.164 0.72237E+04 132 phlogopite-Na 5.05 2.03 -3.02 -0.168 0.12068E+05 134 prehnite -4.84 -8.48 -3.64 -0.214 0.14533E+05 135 prehnite-Fe 1.26 -3.14 -4.41 -0.265 0.17609E+05 138 px-Mg-tschermaks -8.09 -10.07 -1.99 -0.142 0.79411E+04 139 px-Ca-tschermaks -7.02 -9.49 -2.47 -0.177 0.98860E+04 140 pyrite -19.19 -19.73 -0.54 -0.127 0.21599E+04 141 pyrrhotite -7.70 -8.84 -1.14 -0.379 0.45450E+04 142 pyrrhotiteFe0.875 -8.39 -9.09 -0.70 -0.259 0.28094E+04 143 pyrophyllite -13.88 -14.68 -0.80 -0.050 0.32155E+04 144 quartz -0.83 -0.83 0.00 -0.001 0.79809E+01 147 ringwoodite-Fe 2.99 0.09 -2.90 -0.414 0.11579E+05 149 rhodochrosite -4.40 -8.08 -3.68 -1.227 0.14707E+05 150 rhodonite 2.61 0.87 -1.74 -0.349 0.69715E+04 151 sanidine -3.99 -4.80 -0.82 -0.063 0.32698E+04 152 sapphirine(351) -46.28 -51.24 -4.96 -0.075 0.19836E+05 153 siderite -6.30 -9.33 -3.02 -1.007 0.12070E+05 154 sillimanite -12.16 -12.18 -0.02 -0.002 0.71917E+02 156 spinel -7.71 -9.24 -1.53 -0.102 0.61112E+04 158 staurolite-Fe -102.67 -106.51 -3.84 -0.035 0.15353E+05 163 stilpnomelane-Mg -1.06 -5.83 -4.77 -0.142 0.19038E+05 164 stishovite 1.97 -0.83 -2.81 -0.936 0.11219E+05 165 sudoite-Fe -20.45 -24.28 -3.83 -0.124 0.15303E+05 166 sudoite -18.36 -20.99 -2.64 -0.085 0.10533E+05 167 sulfur -9.45 -10.90 -1.45 -0.446 0.57894E+04 168 sylvite 0.12 -2.64 -2.77 -1.383 0.11051E+05 169 talc 5.45 2.97 -2.48 -0.146 0.98985E+04 170 talc-Fe 2.81 -1.95 -4.77 -0.280 0.19045E+05 171 talc-tschermaks -7.21 -9.64 -2.43 -0.143 0.97205E+04 173 tephroite 6.35 2.57 -3.77 -0.539 0.15082E+05 176 topaz-H -10.22 -12.18 -1.96 -0.178 0.78142E+04 179 troilite-low -7.60 -8.84 -1.24 -0.413 0.49446E+04 183 wadsleyite-Fe 2.84 0.09 -2.75 -0.392 0.10975E+05 184 wadsleyite-Mg 7.93 3.37 -4.56 -0.651 0.18200E+05 185 wairakite -10.28 -12.00 -1.72 -0.101 0.68919E+04 186 walstromite 4.74 1.85 -2.89 -0.578 0.11552E+05 187 wollastonite 4.36 1.85 -2.51 -0.501 0.10018E+05 188 pseudo-wollastonite 4.46 1.85 -2.61 -0.522 0.10437E+05 189 zoisite -11.49 -14.15 -2.66 -0.121 0.10608E+05 192 beidellite-Ca -14.70 -15.84 -1.14 -0.070 0.45442E+04 193 beidellite-H -14.71 -16.28 -1.57 -0.100 0.62640E+04 194 beidellite-K -13.64 -15.17 -1.53 -0.094 0.61011E+04 195 beidellite-Mg -15.04 -15.93 -0.90 -0.055 0.35763E+04 196 beidellite-Na -13.57 -14.99 -1.42 -0.087 0.56828E+04 197 bornite -48.01 -48.56 -0.56 -0.042 0.22294E+04 199 chalcocite -12.39 -13.71 -1.32 -0.330 0.52818E+04 200 covellite -10.99 -12.30 -1.32 -0.502 0.52599E+04 202 montmorillonite-Ca -10.56 -11.67 -1.12 -0.069 0.44573E+04 203 montmorillonite-K -9.80 -11.00 -1.21 -0.074 0.48195E+04 204 montmorillonite-Mg -10.80 -11.77 -0.97 -0.060 0.38569E+04 205 montmorillonite-Na -9.41 -10.83 -1.42 -0.087 0.56917E+04 206 nontronite-Ca -2.78 -5.16 -2.38 -0.154 0.95085E+04 207 nontronite-H -2.81 -5.61 -2.80 -0.188 0.11196E+05 208 nontronite-K -1.73 -4.49 -2.77 -0.178 0.11057E+05 209 nontronite-Mg -3.05 -5.26 -2.21 -0.144 0.88402E+04 210 nontronite-Na -1.66 -4.32 -2.67 -0.171 0.10651E+05 215 gypsum -10.53 -13.00 -2.48 -0.619 0.98983E+04 232 alabandite -5.43 -7.60 -2.17 -0.722 0.86597E+04 234 anglesite -12.63 -15.54 -2.91 -1.455 0.11629E+05 237 barite -13.53 -14.03 -0.50 -0.249 0.19891E+04 238 boehmite -4.85 -5.67 -0.83 -0.138 0.32978E+04 240 chalcopyrite -20.67 -21.14 -0.47 -0.088 0.18901E+04 242 copper,native 1.83 -1.41 -3.24 -1.126 0.12935E+05 244 ferrous-oxide 1.75 0.46 -1.29 -0.323 0.51581E+04 245 galena -8.38 -9.16 -0.78 -0.261 0.31230E+04 246 silver,native 0.59 -3.92 -4.51 -1.570 0.18029E+05 255 sphalerite -9.79 -10.47 -0.68 -0.226 0.27126E+04 256 wurtzite -9.02 -10.47 -1.45 -0.484 0.57971E+04 257 zincite 1.93 -1.17 -3.10 -0.775 0.12383E+05 258 an20ab80 -5.25 -5.49 -0.23 -0.018 0.93132E+03 259 an25ab75 -5.57 -5.79 -0.22 -0.017 0.89343E+03 260 an30ab70 -5.87 -6.09 -0.22 -0.017 0.87951E+03 261 tr.625ac.25prg.125 10.17 5.47 -4.70 -0.127 0.18794E+05 Calculations done for 600.0000 Deg. C; 2500.0000 bar Temperature changed by -1.000 degrees to 599.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 19 Loop limit = 500 Temperature = 599.00 C Pressure = 2365.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5496E+02 kg liquid = 0.9901E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9939 Stoichiometric ionic strength = .3315640E+01 Osmotic coef. = 0.0000 True ionic strength = .3172161E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.27710E-04 -4.5574 0.87515E-05 -5.0579 0.31582E+00 -0.5006 2 H2O 0.99387E+00 -0.0027 0.99387E+00 -0.0027 3 Cl- 0.27262E+00 -0.5644 0.84264E-01 -1.0744 0.30909E+00 -0.5099 4 SO4-- 0.13091E-03 -3.8830 0.17610E-05 -5.7542 0.13452E-01 -1.8712 5 HCO3- 0.41876E-04 -4.3780 0.13872E-04 -4.8578 0.33127E+00 -0.4798 6 HS- 0.14827E-03 -3.8290 0.46185E-04 -4.3355 0.31150E+00 -0.5065 7 H4SiO4 0.14468E+00 -0.8396 0.14468E+00 -0.8396 0.10000E+01 0.0000 8 Al+++ 0.28131E-16 -16.5508 0.13085E-20 -20.8832 0.46514E-04 -4.3324 9 Ca++ 0.41320E-05 -5.3838 0.45923E-07 -7.3380 0.11114E-01 -1.9541 10 Mg++ 0.13281E-05 -5.8768 0.12337E-07 -7.9088 0.92887E-02 -2.0320 11 Fe++ 0.26863E-07 -7.5708 0.26122E-09 -9.5830 0.97241E-02 -2.0122 12 K+ 0.68233E-01 -1.1660 0.23152E-01 -1.6354 0.33930E+00 -0.4694 13 Na+ 0.24625E+00 -0.6086 0.77090E-01 -1.1130 0.31305E+00 -0.5044 14 Mn++ 0.48490E-06 -6.3143 0.48750E-08 -8.3120 0.10054E-01 -1.9977 15 Zn++ 0.63830E-09 -9.1950 0.62069E-11 -11.2071 0.97241E-02 -2.0122 16 Cu+ 0.18515E-06 -6.7325 0.57817E-07 -7.2379 0.31227E+00 -0.5055 17 Pb++ 0.95789E-08 -8.0187 0.11798E-09 -9.9282 0.12316E-01 -1.9095 18 Ag+ 0.54697E-09 -9.2620 0.18293E-09 -9.7377 0.33444E+00 -0.4757 19 Ba++ 0.33289E-06 -6.4777 0.43726E-08 -8.3593 0.13135E-01 -1.8816 20 HPO4-- 0.15590E-08 -8.8072 0.21066E-10 -10.6764 0.13513E-01 -1.8693 21 HSiO3- 0.27451E-05 -5.5614 0.84847E-06 -6.0714 0.30909E+00 -0.5099 22 Ca(HSiO3)+ 0.20306E-07 -7.6924 0.69453E-08 -8.1583 0.34203E+00 -0.4659 23 Mg(HSiO3)+ 0.13146E-08 -8.8812 0.44964E-09 -9.3471 0.34203E+00 -0.4659 24 NaHSiO3,aq 0.10834E-05 -5.9652 0.10834E-05 -5.9652 0.10000E+01 0.0000 28 AgCl,aq 0.62975E-07 -7.2008 0.62975E-07 -7.2008 0.10000E+01 0.0000 29 AgCl2- 0.47715E-05 -5.3213 0.14748E-05 -5.8313 0.30909E+00 -0.5099 30 AgCl3-2 0.28155E-05 -5.5504 0.35331E-07 -7.4518 0.12549E-01 -1.9014 31 AgCl4-3 0.11347E-05 -5.9451 0.45628E-10 -10.3408 0.40211E-04 -4.3957 34 Ag(HS),aq 0.34864E-09 -9.4576 0.34864E-09 -9.4576 0.10000E+01 0.0000 35 Ag(HS)2- 0.18806E-08 -8.7257 0.58127E-09 -9.2356 0.30909E+00 -0.5099 36 AlO+ 0.26071E-10 -10.5838 0.89172E-11 -11.0498 0.34203E+00 -0.4659 38 HAlO2,aq 0.55973E-08 -8.2520 0.55973E-08 -8.2520 0.10000E+01 0.0000 39 AlO2- 0.24744E-04 -4.6065 0.67405E-05 -5.1713 0.27241E+00 -0.5648 41 Ba(HCO3)+ 0.14040E-05 -5.8526 0.49784E-06 -6.3029 0.35458E+00 -0.4503 42 BaCl+ 0.54187E-04 -4.2661 0.18534E-04 -4.7320 0.34203E+00 -0.4659 43 CH4,aq 0.22119E-08 -8.6552 0.27278E-08 -8.5642 0.12333E+01 0.0911 48 CO,aq 0.10110E-02 -2.9953 0.10110E-02 -2.9953 0.10000E+01 0.0000 49 CO2,aq 0.26815E+01 0.4284 0.33070E+01 0.5194 0.12333E+01 0.0911 50 CO3-2 0.65588E-10 -10.1832 0.82304E-12 -12.0846 0.12549E-01 -1.9014 51 CaCO3,aq 0.15311E-10 -10.8150 0.15311E-10 -10.8150 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.13301E-05 -5.8761 0.45493E-06 -6.3421 0.34203E+00 -0.4659 53 CaCl+ 0.38590E-03 -3.4135 0.13199E-03 -3.8795 0.34203E+00 -0.4659 54 CaCl2,aq 0.14130E-03 -3.8498 0.14130E-03 -3.8498 0.10000E+01 0.0000 55 CaOH+ 0.40991E-06 -6.3873 0.14020E-06 -6.8532 0.34203E+00 -0.4659 56 CaSO4,aq 0.68331E-07 -7.1654 0.68331E-07 -7.1654 0.10000E+01 0.0000 57 HCl,aq 0.10691E-02 -2.9710 0.10691E-02 -2.9710 0.10000E+01 0.0000 63 CuCl2,aq 0.12618E-10 -10.8990 0.12618E-10 -10.8990 0.10000E+01 0.0000 66 CuCl,aq 0.79954E-04 -4.0972 0.79954E-04 -4.0972 0.10000E+01 0.0000 67 CuCl2- 0.31390E-03 -3.5032 0.97023E-04 -4.0131 0.30909E+00 -0.5099 68 CuCl3-2 0.95509E-05 -5.0200 0.11985E-06 -6.9214 0.12549E-01 -1.9014 74 FeCl+ 0.78653E-06 -6.1043 0.26902E-06 -6.5702 0.34203E+00 -0.4659 75 FeCl2,aq 0.88531E-02 -2.0529 0.88531E-02 -2.0529 0.10000E+01 0.0000 77 FeO,aq 0.36215E-07 -7.4411 0.36215E-07 -7.4411 0.10000E+01 0.0000 78 FeOH+ 0.45176E-07 -7.3451 0.15452E-07 -7.8110 0.34203E+00 -0.4659 79 HFeO2- 0.56503E-08 -8.2479 0.17465E-08 -8.7578 0.30909E+00 -0.5099 82 FeO2- 0.27856E-08 -8.5551 0.86100E-09 -9.0650 0.30909E+00 -0.5099 83 HFeO2,aq 0.87487E-10 -10.0581 0.87487E-10 -10.0581 0.10000E+01 0.0000 84 H2,aq 0.40473E-02 -2.3928 0.49913E-02 -2.3018 0.12333E+01 0.0911 85 KCl,aq 0.45279E-01 -1.3441 0.45279E-01 -1.3441 0.10000E+01 0.0000 86 KHSO4,aq 0.10835E-01 -1.9652 0.10835E-01 -1.9652 0.10000E+01 0.0000 87 KOH,aq 0.60672E-06 -6.2170 0.60672E-06 -6.2170 0.10000E+01 0.0000 88 KSO4- 0.23116E-02 -2.6361 0.71449E-03 -3.1460 0.30909E+00 -0.5099 90 Mg(HCO3)+ 0.16008E-06 -6.7957 0.54751E-07 -7.2616 0.34203E+00 -0.4659 91 MgCl+ 0.18941E-04 -4.7226 0.64786E-05 -5.1885 0.34203E+00 -0.4659 92 MgOH+ 0.45171E-06 -6.3451 0.15450E-06 -6.8111 0.34203E+00 -0.4659 94 MnO,aq 0.98872E-08 -8.0049 0.98872E-08 -8.0049 0.10000E+01 0.0000 95 MnOH+ 0.10674E-06 -6.9717 0.36510E-07 -7.4376 0.34203E+00 -0.4659 100 MnCl+ 0.11603E-02 -2.9354 0.39687E-03 -3.4013 0.34203E+00 -0.4659 101 MnSO4,aq 0.92373E-08 -8.0345 0.92373E-08 -8.0345 0.10000E+01 0.0000 102 NaCl,aq 0.31386E+00 -0.5033 0.31386E+00 -0.5033 0.10000E+01 0.0000 103 NaOH,aq 0.90776E-06 -6.0420 0.90776E-06 -6.0420 0.10000E+01 0.0000 105 OH- 0.99746E-05 -5.0011 0.27172E-05 -5.5659 0.27241E+00 -0.5648 110 HPO3-2 0.31851E-10 -10.4969 0.39968E-12 -12.3983 0.12549E-01 -1.9014 111 H3PO3,aq 0.29449E-09 -9.5309 0.29449E-09 -9.5309 0.10000E+01 0.0000 112 H2PO3- 0.14151E-07 -7.8492 0.43740E-08 -8.3591 0.30909E+00 -0.5099 113 H3PO4,aq 0.16369E-05 -5.7860 0.16369E-05 -5.7860 0.10000E+01 0.0000 114 H2PO4- 0.40552E-05 -5.3920 0.13135E-05 -5.8816 0.32390E+00 -0.4896 116 H4P2O7,aq 0.21388E-09 -9.6698 0.21388E-09 -9.6698 0.10000E+01 0.0000 117 H3P2O7- 0.60107E-08 -8.2211 0.18578E-08 -8.7310 0.30909E+00 -0.5099 118 H2P2O7-2 0.14419E-05 -5.8411 0.18093E-07 -7.7425 0.12549E-01 -1.9014 119 HP2O7-3 0.24253E-07 -7.6152 0.97526E-12 -12.0109 0.40211E-04 -4.3957 121 PbCl+ 0.47199E-05 -5.3261 0.16144E-05 -5.7920 0.34203E+00 -0.4659 122 PbCl2,aq 0.10878E-03 -3.9634 0.10878E-03 -3.9634 0.10000E+01 0.0000 123 PbCl3- 0.12478E-03 -3.9038 0.38569E-04 -4.4138 0.30909E+00 -0.5099 124 PbCl4-2 0.36531E-04 -4.4373 0.45842E-06 -6.3387 0.12549E-01 -1.9014 125 PbO,aq 0.18370E-08 -8.7359 0.18370E-08 -8.7359 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.65016E-04 -4.1870 0.65016E-04 -4.1870 0.10000E+01 0.0000 128 Pb(HS)3- 0.37154E-05 -5.4300 0.11484E-05 -5.9399 0.30909E+00 -0.5099 129 H2S,aq 0.10367E+01 0.0156 0.12785E+01 0.1067 0.12333E+01 0.0911 130 S2-2 0.12727E-07 -7.8953 0.15970E-09 -9.7967 0.12549E-01 -1.9014 131 S3-2 0.15180E-08 -8.8187 0.19050E-10 -10.7201 0.12549E-01 -1.9014 132 S3- 0.26469E-01 -1.5773 0.81815E-02 -2.0872 0.30909E+00 -0.5099 133 S4-2 0.14876E-09 -9.8275 0.18667E-11 -11.7289 0.12549E-01 -1.9014 134 S5-2 0.12172E-10 -10.9146 0.15274E-12 -12.8160 0.12549E-01 -1.9014 135 SO2,aq 0.28193E+00 -0.5499 0.28193E+00 -0.5499 0.10000E+01 0.0000 136 SO3-2 0.58544E-09 -9.2325 0.11042E-10 -10.9569 0.18861E-01 -1.7244 137 HSO3- 0.49468E-03 -3.3057 0.15290E-03 -3.8156 0.30909E+00 -0.5099 138 HSO4- 0.13850E-01 -1.8586 0.48474E-02 -2.3145 0.35000E+00 -0.4559 140 S2O3-2 0.45467E-06 -6.3423 0.57055E-08 -8.2437 0.12549E-01 -1.9014 141 HS2O3- 0.10006E-05 -5.9997 0.30929E-06 -6.5096 0.30909E+00 -0.5099 142 H2S2O3,aq 0.28165E-07 -7.5503 0.28165E-07 -7.5503 0.10000E+01 0.0000 150 S4O6-2 0.85506E-09 -9.0680 0.10730E-10 -10.9694 0.12549E-01 -1.9014 152 ZnCl+ 0.86711E-03 -3.0619 0.29658E-03 -3.5279 0.34203E+00 -0.4659 153 ZnCl2,aq 0.12196E-02 -2.9138 0.12196E-02 -2.9138 0.10000E+01 0.0000 154 ZnCl3- 0.23254E-03 -3.6335 0.71875E-04 -4.1434 0.30909E+00 -0.5099 155 ZnO,aq 0.15550E-07 -7.8083 0.15550E-07 -7.8083 0.10000E+01 0.0000 156 ZnOH+ 0.29163E-05 -5.5352 0.99747E-06 -6.0011 0.34203E+00 -0.4659 158 HZnO2- 0.14953E-09 -9.8253 0.46217E-10 -10.3352 0.30909E+00 -0.5099 Charge balance for all species = 0.2556E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2771012E-04 0.4306823E+01 0.3521924E+04 0.0000 2 H2O 0.1000000E+01 0.5248174E+02 0.7670754E+06 0.0000 3 Cl- 0.2726185E+00 0.6579458E+00 0.1892481E+05 3.9836 4 SO4-- 0.1309113E-03 0.2542286E+00 0.1981356E+05 4.3616 5 HCO3- 0.4187603E-04 0.2682554E+01 0.1327972E+06 0.2001 6 HS- 0.1482657E-03 0.1171693E+01 0.3143856E+05 0.7224 7 H4SiO4 0.1446816E+00 0.1446854E+00 0.1128252E+05 -0.8396 8 Al+++ 0.2813067E-16 0.2474959E-04 0.5417794E+00 -5.7095 9 Ca++ 0.4131983E-05 0.5331651E-03 0.1733629E+02 2.7779 10 Mg++ 0.1328134E-05 0.2088248E-04 0.4118994E+00 2.2070 11 Fe++ 0.2686346E-07 0.8854025E-02 0.4011704E+03 0.5328 12 K+ 0.6823283E-01 0.1266586E+00 0.4018110E+04 3.4225 13 Na+ 0.2462537E+00 0.5601203E+00 0.1044732E+05 3.9449 14 Mn++ 0.4849015E-06 0.1160943E-02 0.5174544E+02 1.8038 15 Zn++ 0.6383020E-09 0.2322224E-02 0.1231604E+03 -1.0913 16 Cu+ 0.1851510E-06 0.4035877E-03 0.2080528E+02 -2.1800 17 Pb++ 0.9578922E-08 0.3435590E-03 0.5775086E+02 0.1876 18 Ag+ 0.5469687E-09 0.8787457E-05 0.7690458E+00 -4.6798 19 Ba++ 0.3328867E-06 0.5592367E-04 0.6231334E+01 1.7566 20 HPO4-- 0.1558967E-08 0.8652788E-05 0.6737838E+00 -0.5606 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4264372E+01 -.2010102E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5196444E+02 0.3350169E-03 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517228E+00 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160144E+01 0.0000000E+00 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1432593E+00 0.3350169E-03 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2450564E-04 0.6700339E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.5279099E-03 0.0000000E+00 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8766754E-02 0.0000000E+00 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3996097E-03 0.0000000E+00 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.122042E+04 g Temperature = 599.00 C Pressure = 2365.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) andalusite 0.3350E-03 -3.475 0.5429E-01 -1.265 100.0 0.1726E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity andalusite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.054289 g Volume = 0.017262 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 19 andalusite -12.26 -12.26 0.00 0.000 0.00000E+00 144 quartz -0.85 -0.83 0.02 0.007 -0.82026E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.30 0.00 -0.30 -0.299 0.11920E+04 3.075 2 CO2,gas -8.65 -9.91 -1.26 -0.421 0.50406E+04 2.111 3 CH4,gas 6.85 -3.44 -10.29 -2.573 0.41071E+05 -6.917 4 H2,gas 5.68 1.62 -4.06 -2.320 0.16205E+05 -0.687 5 H2S,gas -7.17 -9.39 -2.23 -1.113 0.88838E+04 1.148 6 CO,gas -2.84 -8.29 -5.45 -1.678 0.21760E+05 -2.079 7 SO3,gas -5.80 -15.87 -10.07 -2.516 0.40169E+05 -6.691 8 O2,gas 16.51 -3.24 -19.75 -13.167 0.78818E+05 -16.376 9 HCl,gas -5.39 -6.13 -0.74 -0.370 0.29507E+04 -0.739 10 acmite 4.21 2.00 -2.21 -0.230 0.88354E+04 12 akimotoite 5.89 1.37 -4.52 -0.904 0.18043E+05 13 akimotoite-Fe 3.89 -0.30 -4.20 -0.840 0.16752E+05 14 albite-high -4.04 -4.27 -0.23 -0.018 0.91447E+03 15 albite -4.01 -4.27 -0.27 -0.021 0.10670E+04 16 almandine -10.09 -12.34 -2.25 -0.112 0.89737E+04 17 pyrope -3.79 -7.32 -3.53 -0.176 0.14084E+05 18 analcite -2.41 -3.44 -1.03 -0.115 0.41144E+04 22 anhydrite -12.72 -13.09 -0.37 -0.187 0.14905E+04 24 annite -0.34 -3.21 -2.87 -0.159 0.11447E+05 25 phlogopite 4.02 1.82 -2.20 -0.122 0.87978E+04 27 anorthite -9.73 -10.32 -0.59 -0.045 0.23430E+04 30 apatite-OH -47.37 -48.49 -1.12 -0.086 0.44696E+04 31 apatite-OH-zs -45.31 -48.49 -3.18 -0.245 0.12703E+05 32 apatite-Cl-zs -50.63 -54.62 -3.99 -0.332 0.15915E+05 33 aragonite -3.60 -7.14 -3.53 -1.178 0.14100E+05 34 brucite 4.88 2.20 -2.68 -0.536 0.10702E+05 35 calcite -3.69 -7.14 -3.45 -1.151 0.13780E+05 36 carnegieite-low -0.71 -2.60 -1.89 -0.270 0.75424E+04 37 carnegieite-high -0.65 -2.60 -1.95 -0.279 0.77858E+04 38 carpholite-Mg -8.98 -10.90 -1.91 -0.128 0.76367E+04 39 carpholite-Fe -10.27 -12.57 -2.30 -0.154 0.91951E+04 40 celadonite -0.81 -3.43 -2.62 -0.154 0.10463E+05 41 celadonite-Fe -2.15 -5.10 -2.95 -0.174 0.11783E+05 42 chrysotile 8.82 4.94 -3.88 -0.324 0.15503E+05 44 clinochlore 0.61 -2.92 -3.53 -0.110 0.14101E+05 48 chloritoid-Mg -8.76 -10.06 -1.30 -0.087 0.51868E+04 49 chloritoid-Fe -10.58 -11.73 -1.15 -0.077 0.46039E+04 50 chloritoid-Mn -8.42 -10.46 -2.04 -0.136 0.81512E+04 52 coesite -0.59 -0.83 -0.25 -0.082 0.97837E+03 53 cordierite-H -21.73 -22.62 -0.89 -0.032 0.35675E+04 54 cordierite-Fe -23.95 -25.96 -2.01 -0.069 0.80230E+04 55 cordierite-Mn -19.55 -23.42 -3.87 -0.133 0.15445E+05 56 corundum -11.26 -11.43 -0.17 -0.015 0.67620E+03 58 cristobalite -0.79 -0.83 -0.05 -0.016 0.18733E+03 61 cymrite-K -2.54 -4.80 -2.26 -0.188 0.90231E+04 63 diaspore -5.15 -5.71 -0.57 -0.095 0.22685E+04 65 diopside 5.45 3.31 -2.14 -0.214 0.85534E+04 66 hedenbergite 4.11 1.64 -2.47 -0.247 0.98702E+04 68 eastonite -8.94 -10.98 -2.04 -0.079 0.81555E+04 69 enstatite 4.57 2.74 -1.83 -0.183 0.73083E+04 70 clinoenstatite-HiP 5.04 2.74 -2.30 -0.230 0.91742E+04 71 clinoenstatite 4.56 2.74 -1.82 -0.182 0.72676E+04 72 protoenstatite 4.71 2.74 -1.97 -0.197 0.78448E+04 73 epidote -5.92 -8.66 -2.74 -0.133 0.10951E+05 74 clinozoisite -11.61 -14.09 -2.48 -0.113 0.99102E+04 75 epidote-Fe 1.43 -3.23 -4.65 -0.242 0.18567E+05 76 fayalite 1.97 0.23 -1.75 -0.249 0.69688E+04 77 ferrosilite 1.19 -0.61 -1.80 -0.180 0.71836E+04 78 forsterite 5.76 3.57 -2.19 -0.312 0.87280E+04 79 gedrite -13.25 -16.84 -3.59 -0.097 0.14325E+05 81 gibbsite -3.62 -5.72 -2.10 -0.300 0.83693E+04 82 glaucophane 1.10 -3.60 -4.70 -0.127 0.18760E+05 84 goethite 0.94 -0.28 -1.22 -0.265 0.48865E+04 86 greenalite 4.27 -0.08 -4.35 -0.363 0.17366E+05 88 halite -0.04 -2.19 -2.15 -1.075 0.85813E+04 89 hematite 0.44 -0.56 -1.00 -0.121 0.39956E+04 90 heulandite -12.04 -14.51 -2.46 -0.112 0.98369E+04 91 hercynite -9.86 -10.90 -1.04 -0.069 0.41442E+04 94 jadeite -1.76 -3.44 -1.68 -0.168 0.67080E+04 96 kalsilite -1.37 -3.13 -1.75 -0.250 0.69912E+04 97 kaolinite -10.93 -13.10 -2.17 -0.197 0.86683E+04 98 kyanite -12.14 -12.26 -0.12 -0.012 0.48488E+03 100 laumontite -8.83 -12.00 -3.17 -0.211 0.12647E+05 101 lawsonite -7.21 -10.33 -3.11 -0.208 0.12428E+05 102 leucite -2.86 -3.96 -1.10 -0.110 0.44065E+04 104 lizardite 9.02 4.94 -4.08 -0.340 0.16294E+05 105 magnesite -4.68 -7.71 -3.03 -1.011 0.12099E+05 106 magnetite 1.34 -0.03 -1.37 -0.112 0.54604E+04 107 minnesotaite 1.36 -1.75 -3.11 -0.183 0.12406E+05 108 minnesotaite-Mg 7.01 3.27 -3.74 -0.220 0.14930E+05 109 magnesioferrite 4.27 1.65 -2.62 -0.214 0.10471E+05 111 manganosite 5.00 1.80 -3.20 -0.800 0.12778E+05 112 margarite -20.59 -21.75 -1.16 -0.046 0.46372E+04 115 microcline -4.61 -4.80 -0.19 -0.014 0.74647E+03 116 monticellite 8.43 4.15 -4.29 -0.613 0.17114E+05 118 mullite-Si -11.57 -12.26 -0.69 -0.069 0.27682E+04 119 muscovite -15.80 -16.22 -0.42 -0.025 0.16773E+04 120 paragonite -15.11 -15.70 -0.59 -0.035 0.23576E+04 121 nepheline -1.00 -2.60 -1.60 -0.229 0.63882E+04 122 osumilite(2) -13.11 -16.28 -3.17 -0.066 0.12649E+05 123 osumilite-Fe -29.99 -32.43 -2.44 -0.051 0.97421E+04 125 periclase 5.10 2.20 -2.90 -0.724 0.11555E+05 126 periclase-Fe 2.64 0.53 -2.11 -0.526 0.84035E+04 127 perovskite-Al -9.59 -11.43 -1.84 -0.167 0.73254E+04 132 phlogopite-Na 4.90 2.34 -2.56 -0.142 0.10235E+05 134 prehnite -5.00 -8.38 -3.38 -0.199 0.13505E+05 135 prehnite-Fe 1.10 -2.95 -4.05 -0.244 0.16162E+05 138 px-Mg-tschermaks -8.18 -10.06 -1.87 -0.134 0.74777E+04 139 px-Ca-tschermaks -7.12 -9.49 -2.37 -0.169 0.94555E+04 140 pyrite -19.40 -19.87 -0.47 -0.110 0.18724E+04 141 pyrrhotite -7.81 -8.86 -1.06 -0.352 0.42103E+04 142 pyrrhotiteFe0.875 -8.50 -9.13 -0.63 -0.232 0.25226E+04 143 pyrophyllite -14.02 -14.77 -0.75 -0.047 0.29913E+04 147 ringwoodite-Fe 2.93 0.23 -2.70 -0.386 0.10790E+05 149 rhodochrosite -4.50 -8.11 -3.61 -1.203 0.14401E+05 150 rhodonite 2.57 0.97 -1.61 -0.322 0.64153E+04 151 sanidine -4.09 -4.80 -0.70 -0.054 0.28117E+04 152 sapphirine(351) -46.65 -51.36 -4.71 -0.071 0.18796E+05 153 siderite -6.41 -9.38 -2.98 -0.992 0.11882E+05 154 sillimanite -12.24 -12.26 -0.02 -0.002 0.77927E+02 156 spinel -7.79 -9.22 -1.44 -0.096 0.57294E+04 158 staurolite-Fe -103.40 -106.98 -3.58 -0.033 0.14298E+05 159 staurolite-Mg -95.39 -100.29 -4.89 -0.045 0.19527E+05 163 stilpnomelane-Mg -1.34 -5.39 -4.05 -0.121 0.16149E+05 164 stishovite 1.96 -0.83 -2.79 -0.932 0.11153E+05 165 sudoite-Fe -20.63 -24.31 -3.67 -0.118 0.14658E+05 166 sudoite -18.54 -20.96 -2.42 -0.078 0.96475E+04 167 sulfur -9.55 -11.01 -1.46 -0.448 0.58164E+04 168 sylvite 0.04 -2.71 -2.75 -1.375 0.10974E+05 169 talc 5.32 3.27 -2.04 -0.120 0.81482E+04 170 talc-Fe 2.67 -1.75 -4.42 -0.260 0.17643E+05 171 talc-tschermaks -7.36 -9.52 -2.16 -0.127 0.86167E+04 173 tephroite 6.29 2.77 -3.52 -0.503 0.14050E+05 176 topaz-H -10.29 -12.26 -1.97 -0.179 0.78786E+04 179 troilite-low -7.71 -8.86 -1.15 -0.385 0.46088E+04 180 tschermakite -11.26 -15.70 -4.44 -0.120 0.17717E+05 183 wadsleyite-Fe 2.78 0.23 -2.55 -0.365 0.10185E+05 184 wadsleyite-Mg 7.88 3.57 -4.30 -0.615 0.17176E+05 185 wairakite -10.45 -11.99 -1.55 -0.091 0.61679E+04 186 walstromite 4.70 1.94 -2.76 -0.552 0.11022E+05 187 wollastonite 4.32 1.94 -2.38 -0.475 0.94798E+04 188 pseudo-wollastonite 4.42 1.94 -2.48 -0.496 0.99002E+04 189 zoisite -11.68 -14.09 -2.42 -0.110 0.96456E+04 192 beidellite-Ca -14.84 -15.92 -1.07 -0.066 0.42861E+04 193 beidellite-H -14.85 -16.38 -1.52 -0.097 0.60814E+04 194 beidellite-K -13.78 -15.25 -1.46 -0.090 0.58463E+04 195 beidellite-Mg -15.18 -16.01 -0.83 -0.052 0.33316E+04 196 beidellite-Na -13.71 -15.08 -1.36 -0.083 0.54295E+04 197 bornite -48.46 -48.75 -0.28 -0.021 0.11351E+04 199 chalcocite -12.51 -13.75 -1.25 -0.312 0.49758E+04 200 covellite -11.10 -12.38 -1.28 -0.489 0.51190E+04 202 montmorillonite-Ca -10.70 -11.70 -1.00 -0.062 0.39768E+04 203 montmorillonite-K -9.94 -11.02 -1.09 -0.067 0.43458E+04 204 montmorillonite-Mg -10.95 -11.79 -0.84 -0.052 0.33707E+04 205 montmorillonite-Na -9.55 -10.85 -1.30 -0.080 0.52057E+04 206 nontronite-Ca -2.93 -5.05 -2.12 -0.137 0.84566E+04 207 nontronite-H -2.95 -5.51 -2.56 -0.172 0.10219E+05 208 nontronite-K -1.87 -4.38 -2.51 -0.161 0.10009E+05 209 nontronite-Mg -3.19 -5.14 -1.95 -0.127 0.77856E+04 210 nontronite-Na -1.80 -4.21 -2.41 -0.154 0.96028E+04 215 gypsum -10.69 -13.10 -2.41 -0.601 0.96011E+04 232 alabandite -5.53 -7.59 -2.06 -0.686 0.82077E+04 234 anglesite -12.82 -15.68 -2.86 -1.431 0.11420E+05 237 barite -13.71 -14.11 -0.40 -0.200 0.15926E+04 238 boehmite -4.87 -5.71 -0.84 -0.140 0.33633E+04 240 chalcopyrite -20.89 -21.24 -0.35 -0.066 0.14063E+04 242 copper,native 1.83 -1.37 -3.20 -1.112 0.12759E+05 244 ferrous-oxide 1.73 0.53 -1.20 -0.301 0.48059E+04 245 galena -8.49 -9.21 -0.71 -0.237 0.28378E+04 246 silver,native 0.59 -3.87 -4.46 -1.553 0.17818E+05 255 sphalerite -9.91 -10.48 -0.58 -0.193 0.23050E+04 256 wurtzite -9.13 -10.48 -1.35 -0.450 0.53894E+04 257 zincite 1.90 -1.09 -3.00 -0.749 0.11964E+05 258 an20ab80 -5.37 -5.48 -0.11 -0.009 0.45511E+03 259 an25ab75 -5.68 -5.78 -0.10 -0.008 0.41227E+03 260 an30ab70 -5.99 -6.09 -0.10 -0.008 0.39288E+03 261 tr.625ac.25prg.125 9.87 6.09 -3.78 -0.102 0.15105E+05 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 16 Loop limit = 500 Temperature = 599.00 C Pressure = 2365.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5497E+02 kg liquid = 0.9904E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9939 Stoichiometric ionic strength = .3314802E+01 Osmotic coef. = 0.0000 True ionic strength = .3171162E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.27694E-04 -4.5576 0.87484E-05 -5.0581 0.31590E+00 -0.5005 2 H2O 0.99387E+00 -0.0027 0.99387E+00 -0.0027 3 Cl- 0.27253E+00 -0.5646 0.84256E-01 -1.0744 0.30916E+00 -0.5098 4 SO4-- 0.13090E-03 -3.8831 0.17618E-05 -5.7540 0.13460E-01 -1.8710 5 HCO3- 0.41873E-04 -4.3781 0.13874E-04 -4.8578 0.33134E+00 -0.4797 6 HS- 0.14826E-03 -3.8290 0.46193E-04 -4.3354 0.31157E+00 -0.5064 7 H4SiO4 0.13799E+00 -0.8601 0.13799E+00 -0.8601 0.10000E+01 0.0000 8 Al+++ 0.28739E-16 -16.5415 0.13384E-20 -20.8734 0.46570E-04 -4.3319 9 Ca++ 0.41296E-05 -5.3841 0.45924E-07 -7.3380 0.11121E-01 -1.9539 10 Mg++ 0.13274E-05 -5.8770 0.12337E-07 -7.9088 0.92947E-02 -2.0318 11 Fe++ 0.26845E-07 -7.5711 0.26121E-09 -9.5830 0.97303E-02 -2.0119 12 K+ 0.68211E-01 -1.1661 0.23149E-01 -1.6355 0.33937E+00 -0.4693 13 Na+ 0.24618E+00 -0.6088 0.77083E-01 -1.1130 0.31312E+00 -0.5043 14 Mn++ 0.48462E-06 -6.3146 0.48753E-08 -8.3120 0.10060E-01 -1.9974 15 Zn++ 0.63790E-09 -9.1952 0.62069E-11 -11.2071 0.97303E-02 -2.0119 16 Cu+ 0.18513E-06 -6.7325 0.57824E-07 -7.2379 0.31234E+00 -0.5054 17 Pb++ 0.95737E-08 -8.0189 0.11798E-09 -9.9282 0.12323E-01 -1.9093 18 Ag+ 0.54710E-09 -9.2619 0.18301E-09 -9.7375 0.33451E+00 -0.4756 19 Ba++ 0.33271E-06 -6.4779 0.43728E-08 -8.3592 0.13143E-01 -1.8813 20 HPO4-- 0.15588E-08 -8.8072 0.21076E-10 -10.6762 0.13520E-01 -1.8690 21 HSiO3- 0.26185E-05 -5.5819 0.80954E-06 -6.0918 0.30916E+00 -0.5098 22 Ca(HSiO3)+ 0.19371E-07 -7.7129 0.66268E-08 -8.1787 0.34210E+00 -0.4658 23 Mg(HSiO3)+ 0.12541E-08 -8.9017 0.42904E-09 -9.3675 0.34210E+00 -0.4658 24 NaHSiO3,aq 0.10336E-05 -5.9856 0.10336E-05 -5.9856 0.10000E+01 0.0000 28 AgCl,aq 0.62998E-07 -7.2007 0.62998E-07 -7.2007 0.10000E+01 0.0000 29 AgCl2- 0.47718E-05 -5.3213 0.14752E-05 -5.8311 0.30916E+00 -0.5098 30 AgCl3-2 0.28144E-05 -5.5506 0.35338E-07 -7.4518 0.12556E-01 -1.9011 31 AgCl4-3 0.11334E-05 -5.9456 0.45632E-10 -10.3407 0.40262E-04 -4.3951 34 Ag(HS),aq 0.34885E-09 -9.4574 0.34885E-09 -9.4574 0.10000E+01 0.0000 35 Ag(HS)2- 0.18816E-08 -8.7255 0.58172E-09 -9.2353 0.30916E+00 -0.5098 36 AlO+ 0.26680E-10 -10.5738 0.91275E-11 -11.0396 0.34210E+00 -0.4658 38 HAlO2,aq 0.57314E-08 -8.2417 0.57314E-08 -8.2417 0.10000E+01 0.0000 39 AlO2- 0.25339E-04 -4.5962 0.69044E-05 -5.1609 0.27248E+00 -0.5647 41 Ba(HCO3)+ 0.14040E-05 -5.8526 0.49794E-06 -6.3028 0.35465E+00 -0.4502 42 BaCl+ 0.54174E-04 -4.2662 0.18533E-04 -4.7321 0.34210E+00 -0.4658 43 CH4,aq 0.22115E-08 -8.6553 0.27274E-08 -8.5642 0.12333E+01 0.0911 48 CO,aq 0.10108E-02 -2.9953 0.10108E-02 -2.9953 0.10000E+01 0.0000 49 CO2,aq 0.26809E+01 0.4283 0.33063E+01 0.5193 0.12333E+01 0.0911 50 CO3-2 0.65582E-10 -10.1832 0.82345E-12 -12.0844 0.12556E-01 -1.9011 51 CaCO3,aq 0.15319E-10 -10.8148 0.15319E-10 -10.8148 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.13300E-05 -5.8761 0.45500E-06 -6.3420 0.34210E+00 -0.4658 53 CaCl+ 0.38580E-03 -3.4136 0.13198E-03 -3.8795 0.34210E+00 -0.4658 54 CaCl2,aq 0.14128E-03 -3.8499 0.14128E-03 -3.8499 0.10000E+01 0.0000 55 CaOH+ 0.40998E-06 -6.3872 0.14026E-06 -6.8531 0.34210E+00 -0.4658 56 CaSO4,aq 0.68364E-07 -7.1652 0.68364E-07 -7.1652 0.10000E+01 0.0000 57 HCl,aq 0.10686E-02 -2.9712 0.10686E-02 -2.9712 0.10000E+01 0.0000 63 CuCl2,aq 0.12613E-10 -10.8992 0.12613E-10 -10.8992 0.10000E+01 0.0000 66 CuCl,aq 0.79956E-04 -4.0971 0.79956E-04 -4.0971 0.10000E+01 0.0000 67 CuCl2- 0.31381E-03 -3.5033 0.97016E-04 -4.0132 0.30916E+00 -0.5098 68 CuCl3-2 0.95439E-05 -5.0203 0.11983E-06 -6.9214 0.12556E-01 -1.9011 74 FeCl+ 0.78625E-06 -6.1044 0.26898E-06 -6.5703 0.34210E+00 -0.4658 75 FeCl2,aq 0.88510E-02 -2.0530 0.88510E-02 -2.0530 0.10000E+01 0.0000 77 FeO,aq 0.36239E-07 -7.4408 0.36239E-07 -7.4408 0.10000E+01 0.0000 78 FeOH+ 0.45180E-07 -7.3450 0.15456E-07 -7.8109 0.34210E+00 -0.4658 79 HFeO2- 0.56547E-08 -8.2476 0.17482E-08 -8.7574 0.30916E+00 -0.5098 82 FeO2- 0.27877E-08 -8.5548 0.86185E-09 -9.0646 0.30916E+00 -0.5098 83 HFeO2,aq 0.87543E-10 -10.0578 0.87543E-10 -10.0578 0.10000E+01 0.0000 84 H2,aq 0.40472E-02 -2.3928 0.49914E-02 -2.3018 0.12333E+01 0.0911 85 KCl,aq 0.45270E-01 -1.3442 0.45270E-01 -1.3442 0.10000E+01 0.0000 86 KHSO4,aq 0.10834E-01 -1.9652 0.10834E-01 -1.9652 0.10000E+01 0.0000 87 KOH,aq 0.60687E-06 -6.2169 0.60687E-06 -6.2169 0.10000E+01 0.0000 88 KSO4- 0.23119E-02 -2.6360 0.71474E-03 -3.1459 0.30916E+00 -0.5098 90 Mg(HCO3)+ 0.16008E-06 -6.7957 0.54763E-07 -7.2615 0.34210E+00 -0.4658 91 MgCl+ 0.18937E-04 -4.7227 0.64784E-05 -5.1885 0.34210E+00 -0.4658 92 MgOH+ 0.45181E-06 -6.3450 0.15457E-06 -6.8109 0.34210E+00 -0.4658 94 MnO,aq 0.98948E-08 -8.0046 0.98948E-08 -8.0046 0.10000E+01 0.0000 95 MnOH+ 0.10676E-06 -6.9716 0.36525E-07 -7.4374 0.34210E+00 -0.4658 100 MnCl+ 0.11601E-02 -2.9355 0.39686E-03 -3.4014 0.34210E+00 -0.4658 101 MnSO4,aq 0.92420E-08 -8.0342 0.92420E-08 -8.0342 0.10000E+01 0.0000 102 NaCl,aq 0.31381E+00 -0.5033 0.31381E+00 -0.5033 0.10000E+01 0.0000 103 NaOH,aq 0.90800E-06 -6.0419 0.90800E-06 -6.0419 0.10000E+01 0.0000 105 OH- 0.99756E-05 -5.0011 0.27182E-05 -5.5657 0.27248E+00 -0.5647 110 HPO3-2 0.31847E-10 -10.4969 0.39987E-12 -12.3981 0.12556E-01 -1.9011 111 H3PO3,aq 0.29442E-09 -9.5310 0.29442E-09 -9.5310 0.10000E+01 0.0000 112 H2PO3- 0.14150E-07 -7.8493 0.43745E-08 -8.3591 0.30916E+00 -0.5098 113 H3PO4,aq 0.16365E-05 -5.7861 0.16365E-05 -5.7861 0.10000E+01 0.0000 114 H2PO4- 0.40547E-05 -5.3920 0.13136E-05 -5.8815 0.32397E+00 -0.4895 116 H4P2O7,aq 0.21377E-09 -9.6701 0.21377E-09 -9.6701 0.10000E+01 0.0000 117 H3P2O7- 0.60083E-08 -8.2212 0.18575E-08 -8.7311 0.30916E+00 -0.5098 118 H2P2O7-2 0.14413E-05 -5.8412 0.18097E-07 -7.7424 0.12556E-01 -1.9011 119 HP2O7-3 0.24236E-07 -7.6155 0.97579E-12 -12.0106 0.40262E-04 -4.3951 121 PbCl+ 0.47187E-05 -5.3262 0.16143E-05 -5.7920 0.34210E+00 -0.4658 122 PbCl2,aq 0.10877E-03 -3.9635 0.10877E-03 -3.9635 0.10000E+01 0.0000 123 PbCl3- 0.12473E-03 -3.9040 0.38560E-04 -4.4139 0.30916E+00 -0.5098 124 PbCl4-2 0.36498E-04 -4.4377 0.45827E-06 -6.3389 0.12556E-01 -1.9011 125 PbO,aq 0.18384E-08 -8.7356 0.18384E-08 -8.7356 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.65039E-04 -4.1868 0.65039E-04 -4.1868 0.10000E+01 0.0000 128 Pb(HS)3- 0.37164E-05 -5.4299 0.11490E-05 -5.9397 0.30916E+00 -0.5098 129 H2S,aq 0.10364E+01 0.0155 0.12782E+01 0.1066 0.12333E+01 0.0911 130 S2-2 0.12723E-07 -7.8954 0.15975E-09 -9.7966 0.12556E-01 -1.9011 131 S3-2 0.15173E-08 -8.8189 0.19051E-10 -10.7201 0.12556E-01 -1.9011 132 S3- 0.26456E-01 -1.5775 0.81792E-02 -2.0873 0.30916E+00 -0.5098 133 S4-2 0.14865E-09 -9.8278 0.18665E-11 -11.7290 0.12556E-01 -1.9011 134 S5-2 0.12161E-10 -10.9150 0.15269E-12 -12.8162 0.12556E-01 -1.9011 135 SO2,aq 0.28187E+00 -0.5500 0.28187E+00 -0.5500 0.10000E+01 0.0000 136 SO3-2 0.58542E-09 -9.2325 0.11047E-10 -10.9567 0.18871E-01 -1.7242 137 HSO3- 0.49463E-03 -3.3057 0.15292E-03 -3.8155 0.30916E+00 -0.5098 138 HSO4- 0.13848E-01 -1.8586 0.48479E-02 -2.3144 0.35007E+00 -0.4558 140 S2O3-2 0.45452E-06 -6.3424 0.57070E-08 -8.2436 0.12556E-01 -1.9011 141 HS2O3- 0.10003E-05 -5.9999 0.30926E-06 -6.5097 0.30916E+00 -0.5098 142 H2S2O3,aq 0.28153E-07 -7.5505 0.28153E-07 -7.5505 0.10000E+01 0.0000 150 S4O6-2 0.85438E-09 -9.0683 0.10728E-10 -10.9695 0.12556E-01 -1.9011 152 ZnCl+ 0.86687E-03 -3.0620 0.29656E-03 -3.5279 0.34210E+00 -0.4658 153 ZnCl2,aq 0.12194E-02 -2.9138 0.12194E-02 -2.9138 0.10000E+01 0.0000 154 ZnCl3- 0.23242E-03 -3.6337 0.71856E-04 -4.1435 0.30916E+00 -0.5098 155 ZnO,aq 0.15561E-07 -7.8080 0.15561E-07 -7.8080 0.10000E+01 0.0000 156 ZnOH+ 0.29168E-05 -5.5351 0.99784E-06 -6.0009 0.34210E+00 -0.4658 158 HZnO2- 0.14965E-09 -9.8249 0.46267E-10 -10.3347 0.30916E+00 -0.5098 Charge balance for all species = 0.2555E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2769360E-04 0.4305791E+01 0.3523066E+04 0.0000 2 H2O 0.1000000E+01 0.5248248E+02 0.7675189E+06 0.0000 3 Cl- 0.2725330E+00 0.6577883E+00 0.1893095E+05 3.9837 4 SO4-- 0.1308967E-03 0.2541678E+00 0.1981999E+05 4.3621 5 HCO3- 0.4187329E-04 0.2681912E+01 0.1328403E+06 0.2003 6 HS- 0.1482559E-03 0.1171413E+01 0.3144876E+05 0.7226 7 H4SiO4 0.1379942E+00 0.1379979E+00 0.1076710E+05 -0.8601 8 Al+++ 0.2873888E-16 0.2534470E-04 0.5551194E+00 -5.6992 9 Ca++ 0.4129577E-05 0.5330375E-03 0.1734191E+02 2.7782 10 Mg++ 0.1327361E-05 0.2087748E-04 0.4120330E+00 2.2074 11 Fe++ 0.2684463E-07 0.8851906E-02 0.4013006E+03 0.5331 12 K+ 0.6821133E-01 0.1266282E+00 0.4019414E+04 3.4226 13 Na+ 0.2461760E+00 0.5599862E+00 0.1045071E+05 3.9450 14 Mn++ 0.4846214E-06 0.1160665E-02 0.5176223E+02 1.8041 15 Zn++ 0.6379020E-09 0.2321668E-02 0.1232003E+03 -1.0910 16 Cu+ 0.1851299E-06 0.4034911E-03 0.2081203E+02 -2.1798 17 Pb++ 0.9573658E-08 0.3434768E-03 0.5776959E+02 0.1880 18 Ag+ 0.5471037E-09 0.8785354E-05 0.7692953E+00 -4.6794 19 Ba++ 0.3327128E-06 0.5591029E-04 0.6233356E+01 1.7569 20 HPO4-- 0.1558791E-08 0.8650717E-05 0.6740025E+00 -0.5601 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4264370E+01 -.2008316E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5197762E+02 -.1284367E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517228E+00 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160144E+01 0.0000000E+00 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1366704E+00 0.6923915E-02 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2510089E-04 0.6694386E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.5279099E-03 0.0000000E+00 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8766754E-02 0.0000000E+00 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3996097E-03 0.0000000E+00 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.122003E+04 g Temperature = 599.00 C Pressure = 2365.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) andalusite 0.3347E-03 -3.475 0.5424E-01 -1.266 12.05 0.1725E-01 quartz 0.6589E-02 -2.181 0.3959 -0.402 87.95 0.1495 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity andalusite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.450120 g Volume = 0.166748 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 19 andalusite -12.26 -12.26 0.00 0.000 -0.14178E-10 144 quartz -0.85 -0.85 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.30 0.00 -0.30 -0.299 0.11920E+04 3.075 2 CO2,gas -8.65 -9.91 -1.26 -0.421 0.50410E+04 2.111 3 CH4,gas 6.85 -3.44 -10.29 -2.573 0.41071E+05 -6.918 4 H2,gas 5.68 1.62 -4.06 -2.320 0.16205E+05 -0.687 5 H2S,gas -7.17 -9.39 -2.23 -1.113 0.88842E+04 1.148 6 CO,gas -2.84 -8.29 -5.45 -1.678 0.21760E+05 -2.079 7 SO3,gas -5.80 -15.87 -10.07 -2.516 0.40169E+05 -6.692 8 O2,gas 16.51 -3.24 -19.75 -13.167 0.78818E+05 -16.376 9 HCl,gas -5.39 -6.13 -0.74 -0.370 0.29515E+04 -0.740 10 acmite 4.21 1.95 -2.25 -0.234 0.89979E+04 12 akimotoite 5.89 1.35 -4.54 -0.908 0.18124E+05 13 akimotoite-Fe 3.89 -0.32 -4.22 -0.844 0.16833E+05 14 albite-high -4.04 -4.32 -0.28 -0.022 0.11191E+04 15 albite -4.01 -4.32 -0.32 -0.025 0.12716E+04 16 almandine -10.09 -12.38 -2.29 -0.114 0.91343E+04 17 pyrope -3.79 -7.36 -3.57 -0.178 0.14244E+05 18 analcite -2.41 -3.47 -1.06 -0.118 0.42370E+04 22 anhydrite -12.72 -13.09 -0.37 -0.187 0.14896E+04 24 annite -0.34 -3.26 -2.92 -0.162 0.11648E+05 25 phlogopite 4.02 1.77 -2.25 -0.125 0.89983E+04 27 anorthite -9.73 -10.34 -0.61 -0.047 0.24237E+04 30 apatite-OH -47.37 -48.49 -1.12 -0.086 0.44646E+04 31 apatite-OH-zs -45.31 -48.49 -3.18 -0.245 0.12698E+05 32 apatite-Cl-zs -50.63 -54.62 -3.99 -0.332 0.15911E+05 33 aragonite -3.60 -7.14 -3.53 -1.178 0.14099E+05 34 brucite 4.88 2.20 -2.68 -0.536 0.10701E+05 35 calcite -3.69 -7.14 -3.45 -1.151 0.13779E+05 36 carnegieite-low -0.71 -2.61 -1.90 -0.271 0.75830E+04 37 carnegieite-high -0.65 -2.61 -1.96 -0.280 0.78264E+04 38 carpholite-Mg -8.98 -10.92 -1.93 -0.129 0.77174E+04 39 carpholite-Fe -10.27 -12.59 -2.32 -0.155 0.92760E+04 40 celadonite -0.81 -3.50 -2.69 -0.158 0.10748E+05 41 celadonite-Fe -2.15 -5.17 -3.02 -0.178 0.12069E+05 42 chrysotile 8.82 4.90 -3.92 -0.327 0.15663E+05 44 clinochlore 0.61 -2.96 -3.57 -0.112 0.14258E+05 48 chloritoid-Mg -8.76 -10.06 -1.30 -0.087 0.51855E+04 49 chloritoid-Fe -10.58 -11.73 -1.15 -0.077 0.46028E+04 50 chloritoid-Mn -8.42 -10.46 -2.04 -0.136 0.81498E+04 52 coesite -0.59 -0.85 -0.27 -0.089 0.10604E+04 53 cordierite-H -21.73 -22.68 -0.95 -0.034 0.38109E+04 54 cordierite-Fe -23.95 -26.03 -2.07 -0.071 0.82668E+04 55 cordierite-Mn -19.55 -23.48 -3.93 -0.136 0.15688E+05 56 corundum -11.26 -11.41 -0.15 -0.014 0.59417E+03 58 cristobalite -0.79 -0.85 -0.07 -0.022 0.26936E+03 61 cymrite-K -2.54 -4.85 -2.31 -0.193 0.92277E+04 63 diaspore -5.15 -5.70 -0.56 -0.093 0.22275E+04 65 diopside 5.45 3.27 -2.18 -0.218 0.87149E+04 66 hedenbergite 4.11 1.60 -2.51 -0.251 0.10032E+05 68 eastonite -8.94 -10.99 -2.05 -0.079 0.81934E+04 69 enstatite 4.57 2.70 -1.87 -0.187 0.74696E+04 70 clinoenstatite-HiP 5.04 2.70 -2.34 -0.234 0.93356E+04 71 clinoenstatite 4.56 2.70 -1.86 -0.186 0.74289E+04 72 protoenstatite 4.71 2.70 -2.01 -0.201 0.80061E+04 73 epidote -5.92 -8.70 -2.78 -0.135 0.11112E+05 74 clinozoisite -11.61 -14.12 -2.51 -0.114 0.10031E+05 75 epidote-Fe 1.43 -3.28 -4.70 -0.244 0.18767E+05 76 fayalite 1.97 0.21 -1.77 -0.252 0.70486E+04 77 ferrosilite 1.19 -0.65 -1.84 -0.184 0.73454E+04 78 forsterite 5.76 3.55 -2.21 -0.315 0.88073E+04 79 gedrite -13.25 -16.92 -3.67 -0.099 0.14647E+05 81 gibbsite -3.62 -5.71 -2.09 -0.298 0.83283E+04 82 glaucophane 1.10 -3.75 -4.84 -0.131 0.19330E+05 84 goethite 0.94 -0.28 -1.22 -0.265 0.48854E+04 86 greenalite 4.27 -0.12 -4.39 -0.366 0.17527E+05 88 halite -0.04 -2.19 -2.15 -1.075 0.85816E+04 89 hematite 0.44 -0.56 -1.00 -0.121 0.39934E+04 90 heulandite -12.04 -14.63 -2.59 -0.118 0.10328E+05 91 hercynite -9.86 -10.88 -1.02 -0.068 0.40611E+04 94 jadeite -1.76 -3.47 -1.71 -0.171 0.68306E+04 96 kalsilite -1.37 -3.14 -1.76 -0.252 0.70317E+04 97 kaolinite -10.93 -13.12 -2.19 -0.199 0.87503E+04 98 kyanite -12.14 -12.26 -0.12 -0.012 0.48488E+03 100 laumontite -8.83 -12.06 -3.23 -0.215 0.12892E+05 101 lawsonite -7.21 -10.35 -3.13 -0.209 0.12509E+05 102 leucite -2.86 -3.99 -1.13 -0.113 0.45291E+04 104 lizardite 9.02 4.90 -4.12 -0.344 0.16454E+05 105 magnesite -4.68 -7.71 -3.03 -1.010 0.12098E+05 106 magnetite 1.34 -0.03 -1.37 -0.112 0.54571E+04 107 minnesotaite 1.36 -1.83 -3.19 -0.188 0.12731E+05 108 minnesotaite-Mg 7.01 3.19 -3.82 -0.225 0.15254E+05 109 magnesioferrite 4.27 1.65 -2.62 -0.214 0.10468E+05 111 manganosite 5.00 1.80 -3.20 -0.800 0.12777E+05 112 margarite -20.59 -21.75 -1.16 -0.046 0.46359E+04 115 microcline -4.61 -4.85 -0.24 -0.018 0.95110E+03 116 monticellite 8.43 4.13 -4.31 -0.615 0.17194E+05 118 mullite-Si -11.57 -12.26 -0.69 -0.069 0.27682E+04 119 muscovite -15.80 -16.26 -0.45 -0.027 0.17999E+04 120 paragonite -15.11 -15.73 -0.62 -0.037 0.24801E+04 121 nepheline -1.00 -2.61 -1.61 -0.230 0.64287E+04 122 osumilite(2) -13.11 -16.48 -3.36 -0.070 0.13423E+05 123 osumilite-Fe -29.99 -32.58 -2.59 -0.054 0.10355E+05 125 periclase 5.10 2.20 -2.89 -0.724 0.11553E+05 126 periclase-Fe 2.64 0.53 -2.11 -0.526 0.84024E+04 127 perovskite-Al -9.59 -11.41 -1.82 -0.165 0.72433E+04 132 phlogopite-Na 4.90 2.29 -2.61 -0.145 0.10436E+05 134 prehnite -5.00 -8.42 -3.42 -0.201 0.13666E+05 135 prehnite-Fe 1.10 -3.00 -4.10 -0.247 0.16363E+05 138 px-Mg-tschermaks -8.18 -10.06 -1.87 -0.134 0.74763E+04 139 px-Ca-tschermaks -7.12 -9.49 -2.37 -0.169 0.94543E+04 140 pyrite -19.40 -19.87 -0.47 -0.110 0.18719E+04 141 pyrrhotite -7.81 -8.86 -1.05 -0.352 0.42096E+04 142 pyrrhotiteFe0.875 -8.50 -9.13 -0.63 -0.232 0.25219E+04 143 pyrophyllite -14.02 -14.83 -0.81 -0.051 0.32374E+04 147 ringwoodite-Fe 2.93 0.21 -2.72 -0.389 0.10870E+05 149 rhodochrosite -4.50 -8.11 -3.61 -1.203 0.14400E+05 150 rhodonite 2.57 0.95 -1.63 -0.326 0.64960E+04 151 sanidine -4.09 -4.85 -0.76 -0.058 0.30163E+04 152 sapphirine(351) -46.65 -51.27 -4.63 -0.070 0.18464E+05 153 siderite -6.41 -9.38 -2.98 -0.992 0.11881E+05 154 sillimanite -12.24 -12.26 -0.02 -0.002 0.77927E+02 156 spinel -7.79 -9.20 -1.41 -0.094 0.56460E+04 158 staurolite-Fe -103.40 -106.95 -3.55 -0.032 0.14171E+05 159 staurolite-Mg -95.39 -100.26 -4.86 -0.044 0.19398E+05 163 stilpnomelane-Mg -1.34 -5.53 -4.19 -0.125 0.16716E+05 164 stishovite 1.96 -0.85 -2.82 -0.938 0.11235E+05 165 sudoite-Fe -20.63 -24.33 -3.69 -0.119 0.14738E+05 166 sudoite -18.54 -20.98 -2.44 -0.079 0.97269E+04 167 sulfur -9.55 -11.01 -1.46 -0.448 0.58168E+04 168 sylvite 0.04 -2.71 -2.75 -1.375 0.10975E+05 169 talc 5.32 3.19 -2.12 -0.125 0.84723E+04 170 talc-Fe 2.67 -1.83 -4.50 -0.265 0.17968E+05 171 talc-tschermaks -7.36 -9.56 -2.20 -0.129 0.87781E+04 173 tephroite 6.29 2.75 -3.54 -0.506 0.14129E+05 176 topaz-H -10.29 -12.26 -1.97 -0.179 0.78786E+04 179 troilite-low -7.71 -8.86 -1.15 -0.385 0.46080E+04 180 tschermakite -11.26 -15.78 -4.52 -0.122 0.18038E+05 183 wadsleyite-Fe 2.78 0.21 -2.57 -0.367 0.10265E+05 184 wadsleyite-Mg 7.88 3.55 -4.32 -0.618 0.17255E+05 185 wairakite -10.45 -12.06 -1.61 -0.095 0.64127E+04 186 walstromite 4.70 1.92 -2.78 -0.556 0.11103E+05 187 wollastonite 4.32 1.92 -2.40 -0.479 0.95606E+04 188 pseudo-wollastonite 4.42 1.92 -2.50 -0.500 0.99809E+04 189 zoisite -11.68 -14.12 -2.45 -0.111 0.97661E+04 192 beidellite-Ca -14.84 -15.97 -1.13 -0.070 0.44914E+04 193 beidellite-H -14.85 -16.43 -1.58 -0.101 0.62868E+04 194 beidellite-K -13.78 -15.30 -1.52 -0.093 0.60516E+04 195 beidellite-Mg -15.18 -16.06 -0.89 -0.055 0.35368E+04 196 beidellite-Na -13.71 -15.13 -1.41 -0.086 0.56349E+04 197 bornite -48.46 -48.75 -0.28 -0.021 0.11314E+04 199 chalcocite -12.51 -13.75 -1.25 -0.312 0.49745E+04 200 covellite -11.10 -12.38 -1.28 -0.489 0.51185E+04 202 montmorillonite-Ca -10.70 -11.76 -1.06 -0.066 0.42357E+04 203 montmorillonite-K -9.94 -11.09 -1.15 -0.071 0.46048E+04 204 montmorillonite-Mg -10.95 -11.85 -0.91 -0.056 0.36296E+04 205 montmorillonite-Na -9.55 -10.92 -1.37 -0.084 0.54647E+04 206 nontronite-Ca -2.93 -5.12 -2.19 -0.142 0.87417E+04 207 nontronite-H -2.95 -5.58 -2.63 -0.176 0.10505E+05 208 nontronite-K -1.87 -4.45 -2.58 -0.166 0.10294E+05 209 nontronite-Mg -3.19 -5.22 -2.02 -0.131 0.80707E+04 210 nontronite-Na -1.80 -4.28 -2.48 -0.159 0.98880E+04 215 gypsum -10.69 -13.10 -2.41 -0.601 0.96003E+04 232 alabandite -5.53 -7.59 -2.06 -0.685 0.82067E+04 234 anglesite -12.82 -15.68 -2.86 -1.431 0.11419E+05 237 barite -13.71 -14.11 -0.40 -0.199 0.15917E+04 238 boehmite -4.87 -5.70 -0.83 -0.139 0.33223E+04 240 chalcopyrite -20.89 -21.24 -0.35 -0.066 0.14051E+04 242 copper,native 1.83 -1.37 -3.20 -1.112 0.12759E+05 244 ferrous-oxide 1.73 0.53 -1.20 -0.301 0.48047E+04 245 galena -8.49 -9.21 -0.71 -0.237 0.28369E+04 246 silver,native 0.59 -3.87 -4.46 -1.553 0.17817E+05 255 sphalerite -9.91 -10.48 -0.58 -0.192 0.23041E+04 256 wurtzite -9.13 -10.48 -1.35 -0.450 0.53885E+04 257 zincite 1.90 -1.09 -3.00 -0.749 0.11962E+05 258 an20ab80 -5.37 -5.53 -0.16 -0.012 0.63495E+03 259 an25ab75 -5.68 -5.83 -0.15 -0.011 0.58592E+03 260 an30ab70 -5.99 -6.13 -0.14 -0.011 0.56033E+03 261 tr.625ac.25prg.125 9.87 5.93 -3.94 -0.106 0.15717E+05 Calculations done for 599.0000 Deg. C; 2365.0000 bar Temperature changed by -1.000 degrees to 598.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 20 Loop limit = 500 Temperature = 598.00 C Pressure = 2245.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5499E+02 kg liquid = 0.9906E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9941 Stoichiometric ionic strength = .3313957E+01 Osmotic coef. = 0.0000 True ionic strength = .3041741E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.23716E-04 -4.6250 0.73462E-05 -5.1339 0.30975E+00 -0.5090 2 H2O 0.99414E+00 -0.0026 0.99414E+00 -0.0026 3 Cl- 0.26024E+00 -0.5846 0.78034E-01 -1.1077 0.29986E+00 -0.5231 4 SO4-- 0.13567E-03 -3.8675 0.16768E-05 -5.7755 0.12360E-01 -1.9080 5 HCO3- 0.39249E-04 -4.4062 0.12616E-04 -4.8991 0.32143E+00 -0.4929 6 HS- 0.14968E-03 -3.8248 0.45235E-04 -4.3445 0.30220E+00 -0.5197 7 H4SiO4 0.13125E+00 -0.8819 0.13125E+00 -0.8819 0.10000E+01 0.0000 8 Al+++ 0.19486E-16 -16.7103 0.75408E-21 -21.1226 0.38699E-04 -4.4123 9 Ca++ 0.38754E-05 -5.4117 0.39519E-07 -7.4032 0.10197E-01 -1.9915 10 Mg++ 0.12741E-05 -5.8948 0.10852E-07 -7.9645 0.85169E-02 -2.0697 11 Fe++ 0.24084E-07 -7.6183 0.21477E-09 -9.6680 0.89174E-02 -2.0498 12 K+ 0.65834E-01 -1.1816 0.21674E-01 -1.6641 0.32922E+00 -0.4825 13 Na+ 0.23566E+00 -0.6277 0.71562E-01 -1.1453 0.30367E+00 -0.5176 14 Mn++ 0.46416E-06 -6.3333 0.42799E-08 -8.3686 0.92207E-02 -2.0352 15 Zn++ 0.58497E-09 -9.2329 0.52164E-11 -11.2826 0.89174E-02 -2.0498 16 Cu+ 0.16941E-06 -6.7711 0.51317E-07 -7.2897 0.30291E+00 -0.5187 17 Pb++ 0.81369E-08 -8.0895 0.91993E-10 -10.0362 0.11306E-01 -1.9467 18 Ag+ 0.51686E-09 -9.2866 0.16771E-09 -9.7754 0.32448E+00 -0.4888 19 Ba++ 0.31816E-06 -6.4974 0.38374E-08 -8.4160 0.12062E-01 -1.9186 20 HPO4-- 0.15981E-08 -8.7964 0.19842E-10 -10.7024 0.12416E-01 -1.9060 21 HSiO3- 0.25709E-05 -5.5899 0.77091E-06 -6.1130 0.29986E+00 -0.5231 22 Ca(HSiO3)+ 0.19484E-07 -7.7103 0.64661E-08 -8.1894 0.33188E+00 -0.4790 23 Mg(HSiO3)+ 0.12984E-08 -8.8866 0.43092E-09 -9.3656 0.33188E+00 -0.4790 24 NaHSiO3,aq 0.11051E-05 -5.9566 0.11051E-05 -5.9566 0.10000E+01 0.0000 28 AgCl,aq 0.64148E-07 -7.1928 0.64148E-07 -7.1928 0.10000E+01 0.0000 29 AgCl2- 0.48252E-05 -5.3165 0.14469E-05 -5.8396 0.29986E+00 -0.5231 30 AgCl3-2 0.27560E-05 -5.5597 0.31765E-07 -7.4981 0.11526E-01 -1.9383 31 AgCl4-3 0.11351E-05 -5.9450 0.38005E-10 -10.4202 0.33483E-04 -4.4752 34 Ag(HS),aq 0.38334E-09 -9.4164 0.38334E-09 -9.4164 0.10000E+01 0.0000 35 Ag(HS)2- 0.21620E-08 -8.6651 0.64830E-09 -9.1882 0.29986E+00 -0.5231 36 AlO+ 0.23066E-10 -10.6370 0.76551E-11 -11.1161 0.33188E+00 -0.4790 38 HAlO2,aq 0.57117E-08 -8.2432 0.57117E-08 -8.2432 0.10000E+01 0.0000 39 AlO2- 0.25865E-04 -4.5873 0.68351E-05 -5.1653 0.26426E+00 -0.5780 41 Ba(HCO3)+ 0.14425E-05 -5.8409 0.49637E-06 -6.3042 0.34410E+00 -0.4633 42 BaCl+ 0.54138E-04 -4.2665 0.17967E-04 -4.7455 0.33188E+00 -0.4790 43 CH4,aq 0.21961E-08 -8.6584 0.26994E-08 -8.5687 0.12292E+01 0.0896 48 CO,aq 0.98384E-03 -3.0071 0.98384E-03 -3.0071 0.10000E+01 0.0000 49 CO2,aq 0.26803E+01 0.4282 0.32946E+01 0.5178 0.12292E+01 0.0896 50 CO3-2 0.62739E-10 -10.2025 0.72309E-12 -12.1408 0.11526E-01 -1.9383 51 CaCO3,aq 0.16814E-10 -10.7743 0.16814E-10 -10.7743 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.12598E-05 -5.8997 0.41810E-06 -6.3787 0.33188E+00 -0.4790 53 CaCl+ 0.37712E-03 -3.4235 0.12516E-03 -3.9025 0.33188E+00 -0.4790 54 CaCl2,aq 0.15014E-03 -3.8235 0.15014E-03 -3.8235 0.10000E+01 0.0000 55 CaOH+ 0.43492E-06 -6.3616 0.14434E-06 -6.8406 0.33188E+00 -0.4790 56 CaSO4,aq 0.79988E-07 -7.0970 0.79988E-07 -7.0970 0.10000E+01 0.0000 57 HCl,aq 0.10504E-02 -2.9786 0.10504E-02 -2.9786 0.10000E+01 0.0000 63 CuCl2,aq 0.11211E-10 -10.9504 0.11211E-10 -10.9504 0.10000E+01 0.0000 66 CuCl,aq 0.79645E-04 -4.0988 0.79645E-04 -4.0988 0.10000E+01 0.0000 67 CuCl2- 0.31433E-03 -3.5026 0.94254E-04 -4.0257 0.29986E+00 -0.5231 68 CuCl3-2 0.92636E-05 -5.0332 0.10677E-06 -6.9716 0.11526E-01 -1.9383 74 FeCl+ 0.73449E-06 -6.1340 0.24376E-06 -6.6130 0.33188E+00 -0.4790 75 FeCl2,aq 0.88492E-02 -2.0531 0.88492E-02 -2.0531 0.10000E+01 0.0000 77 FeO,aq 0.42505E-07 -7.3716 0.42505E-07 -7.3716 0.10000E+01 0.0000 78 FeOH+ 0.44719E-07 -7.3495 0.14841E-07 -7.8285 0.33188E+00 -0.4790 79 HFeO2- 0.65982E-08 -8.1806 0.19785E-08 -8.7037 0.29986E+00 -0.5231 82 FeO2- 0.34007E-08 -8.4684 0.10197E-08 -8.9915 0.29986E+00 -0.5231 83 HFeO2,aq 0.10458E-09 -9.9806 0.10458E-09 -9.9806 0.10000E+01 0.0000 84 H2,aq 0.41771E-02 -2.3791 0.51345E-02 -2.2895 0.12292E+01 0.0896 85 KCl,aq 0.47025E-01 -1.3277 0.47025E-01 -1.3277 0.10000E+01 0.0000 86 KHSO4,aq 0.11215E-01 -1.9502 0.11215E-01 -1.9502 0.10000E+01 0.0000 87 KOH,aq 0.66359E-06 -6.1781 0.66359E-06 -6.1781 0.10000E+01 0.0000 88 KSO4- 0.25265E-02 -2.5975 0.75759E-03 -3.1206 0.29986E+00 -0.5231 90 Mg(HCO3)+ 0.15394E-06 -6.8126 0.51089E-07 -7.2917 0.33188E+00 -0.4790 91 MgCl+ 0.18955E-04 -4.7223 0.62906E-05 -5.2013 0.33188E+00 -0.4790 92 MgOH+ 0.48914E-06 -6.3106 0.16233E-06 -6.7896 0.33188E+00 -0.4790 94 MnO,aq 0.12402E-07 -7.9065 0.12402E-07 -7.9065 0.10000E+01 0.0000 95 MnOH+ 0.11286E-06 -6.9475 0.37454E-07 -7.4265 0.33188E+00 -0.4790 100 MnCl+ 0.11598E-02 -2.9356 0.38492E-03 -3.4146 0.33188E+00 -0.4790 101 MnSO4,aq 0.11068E-07 -7.9559 0.11068E-07 -7.9559 0.10000E+01 0.0000 102 NaCl,aq 0.32421E+00 -0.4892 0.32421E+00 -0.4892 0.10000E+01 0.0000 103 NaOH,aq 0.98979E-06 -6.0045 0.98979E-06 -6.0045 0.10000E+01 0.0000 105 OH- 0.99816E-05 -5.0008 0.26377E-05 -5.5788 0.26426E+00 -0.5780 110 HPO3-2 0.32457E-10 -10.4887 0.37408E-12 -12.4270 0.11526E-01 -1.9383 111 H3PO3,aq 0.28415E-09 -9.5465 0.28415E-09 -9.5465 0.10000E+01 0.0000 112 H2PO3- 0.13797E-07 -7.8602 0.41372E-08 -8.3833 0.29986E+00 -0.5231 113 H3PO4,aq 0.16218E-05 -5.7900 0.16218E-05 -5.7900 0.10000E+01 0.0000 114 H2PO4- 0.40284E-05 -5.3949 0.12659E-05 -5.8976 0.31425E+00 -0.5027 116 H4P2O7,aq 0.21089E-09 -9.6760 0.21089E-09 -9.6760 0.10000E+01 0.0000 117 H3P2O7- 0.58652E-08 -8.2317 0.17587E-08 -8.7548 0.29986E+00 -0.5231 118 H2P2O7-2 0.14586E-05 -5.8361 0.16811E-07 -7.7744 0.11526E-01 -1.9383 119 HP2O7-3 0.26840E-07 -7.5712 0.89868E-12 -12.0464 0.33483E-04 -4.4752 121 PbCl+ 0.42671E-05 -5.3699 0.14161E-05 -5.8489 0.33188E+00 -0.4790 122 PbCl2,aq 0.10547E-03 -3.9769 0.10547E-03 -3.9769 0.10000E+01 0.0000 123 PbCl3- 0.12307E-03 -3.9098 0.36904E-04 -4.4329 0.29986E+00 -0.5231 124 PbCl4-2 0.35133E-04 -4.4543 0.40493E-06 -6.3926 0.11526E-01 -1.9383 125 PbO,aq 0.21230E-08 -8.6731 0.21230E-08 -8.6731 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.71008E-04 -4.1487 0.71008E-04 -4.1487 0.10000E+01 0.0000 128 Pb(HS)3- 0.44462E-05 -5.3520 0.13332E-05 -5.8751 0.29986E+00 -0.5231 129 H2S,aq 0.10376E+01 0.0160 0.12754E+01 0.1056 0.12292E+01 0.0896 130 S2-2 0.13206E-07 -7.8792 0.15221E-09 -9.8176 0.11526E-01 -1.9383 131 S3-2 0.15333E-08 -8.8144 0.17672E-10 -10.7527 0.11526E-01 -1.9383 132 S3- 0.25842E-01 -1.5877 0.77491E-02 -2.1108 0.29986E+00 -0.5231 133 S4-2 0.14650E-09 -9.8342 0.16884E-11 -11.7725 0.11526E-01 -1.9383 134 S5-2 0.11708E-10 -10.9315 0.13494E-12 -12.8699 0.11526E-01 -1.9383 135 SO2,aq 0.28188E+00 -0.5499 0.28188E+00 -0.5499 0.10000E+01 0.0000 136 SO3-2 0.58570E-09 -9.2323 0.10172E-10 -10.9926 0.17367E-01 -1.7603 137 HSO3- 0.49096E-03 -3.3090 0.14722E-03 -3.8320 0.29986E+00 -0.5231 138 HSO4- 0.13598E-01 -1.8665 0.46190E-02 -2.3355 0.33967E+00 -0.4689 140 S2O3-2 0.46190E-06 -6.3355 0.53236E-08 -8.2738 0.11526E-01 -1.9383 141 HS2O3- 0.94656E-06 -6.0239 0.28383E-06 -6.5469 0.29986E+00 -0.5231 142 H2S2O3,aq 0.26709E-07 -7.5733 0.26709E-07 -7.5733 0.10000E+01 0.0000 150 S4O6-2 0.80744E-09 -9.0929 0.93062E-11 -11.0312 0.11526E-01 -1.9383 152 ZnCl+ 0.83171E-03 -3.0800 0.27602E-03 -3.5591 0.33188E+00 -0.4790 153 ZnCl2,aq 0.12559E-02 -2.9010 0.12559E-02 -2.9010 0.10000E+01 0.0000 154 ZnCl3- 0.23054E-03 -3.6373 0.69129E-04 -4.1603 0.29986E+00 -0.5231 155 ZnO,aq 0.18618E-07 -7.7301 0.18618E-07 -7.7301 0.10000E+01 0.0000 156 ZnOH+ 0.30129E-05 -5.5210 0.99991E-06 -6.0000 0.33188E+00 -0.4790 158 HZnO2- 0.17918E-09 -9.7467 0.53728E-10 -10.2698 0.29986E+00 -0.5231 Charge balance for all species = 0.2555E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2371620E-04 0.4304870E+01 0.3524219E+04 0.0000 2 H2O 0.1000000E+01 0.5248471E+02 0.7679669E+06 0.0000 3 Cl- 0.2602378E+00 0.6576479E+00 0.1893715E+05 4.0262 4 SO4-- 0.1356675E-03 0.2541135E+00 0.1982649E+05 4.4924 5 HCO3- 0.3924941E-04 0.2681339E+01 0.1328839E+06 0.2349 6 HS- 0.1496842E-03 0.1171163E+01 0.3145907E+05 0.7894 7 H4SiO4 0.1312494E+00 0.1312531E+00 0.1024638E+05 -0.8819 8 Al+++ 0.1948567E-16 0.2587076E-04 0.5669483E+00 -5.7208 9 Ca++ 0.3875440E-05 0.5329237E-03 0.1734759E+02 2.8647 10 Mg++ 0.1274131E-05 0.2087303E-04 0.4121681E+00 2.3034 11 Fe++ 0.2408443E-07 0.8850016E-02 0.4014321E+03 0.5999 12 K+ 0.6583383E-01 0.1266012E+00 0.4020731E+04 3.4699 13 Na+ 0.2356578E+00 0.5598666E+00 0.1045413E+05 3.9886 14 Mn++ 0.4641602E-06 0.1160417E-02 0.5177919E+02 1.8993 15 Zn++ 0.5849710E-09 0.2321172E-02 0.1232407E+03 -1.0148 16 Cu+ 0.1694112E-06 0.4034050E-03 0.2081885E+02 -2.1558 17 Pb++ 0.8136890E-08 0.3434034E-03 0.5778853E+02 0.2316 18 Ag+ 0.5168619E-09 0.8783478E-05 0.7695474E+00 -4.6415 19 Ba++ 0.3181558E-06 0.5589835E-04 0.6235399E+01 1.8519 20 HPO4-- 0.1598126E-08 0.8648870E-05 0.6742233E+00 -0.4345 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4264369E+01 -.2006736E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5199093E+02 -.2614884E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517228E+00 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160144E+01 0.0000000E+00 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1300182E+00 0.1357610E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2562736E-04 0.6689122E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.5279099E-03 0.0000000E+00 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8766754E-02 0.0000000E+00 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3996097E-03 0.0000000E+00 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.121963E+04 g Temperature = 598.00 C Pressure = 2245.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) andalusite 0.3345E-03 -3.476 0.5420E-01 -1.266 6.378 0.1723E-01 quartz 0.1324E-01 -1.878 0.7956 -0.099 93.62 0.3004 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity andalusite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.849757 g Volume = 0.317671 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 19 andalusite -12.33 -12.33 0.00 0.000 0.21243E-10 144 quartz -0.88 -0.88 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.30 0.00 -0.30 -0.298 0.11879E+04 3.053 2 CO2,gas -8.73 -10.03 -1.30 -0.433 0.51754E+04 2.053 3 CH4,gas 6.87 -3.47 -10.34 -2.585 0.41211E+05 -6.987 4 H2,gas 5.69 1.64 -4.05 -2.317 0.16164E+05 -0.704 5 H2S,gas -7.24 -9.48 -2.24 -1.119 0.89184E+04 1.114 6 CO,gas -2.90 -8.39 -5.49 -1.688 0.21866E+05 -2.134 7 SO3,gas -5.94 -16.04 -10.10 -2.525 0.40259E+05 -6.748 8 O2,gas 16.49 -3.28 -19.77 -13.180 0.78810E+05 -16.419 9 HCl,gas -5.44 -6.24 -0.80 -0.401 0.31961E+04 -0.802 10 acmite 4.14 2.01 -2.13 -0.221 0.84891E+04 12 akimotoite 5.86 1.42 -4.44 -0.888 0.17702E+05 13 akimotoite-Fe 3.86 -0.28 -4.14 -0.829 0.16519E+05 14 albite-high -4.14 -4.37 -0.23 -0.017 0.90676E+03 15 albite -4.10 -4.37 -0.27 -0.020 0.10564E+04 16 almandine -10.23 -12.29 -2.05 -0.103 0.81874E+04 17 pyrope -3.92 -7.18 -3.26 -0.163 0.12975E+05 18 analcite -2.48 -3.49 -1.01 -0.113 0.40460E+04 22 anhydrite -12.89 -13.18 -0.29 -0.143 0.11417E+04 24 annite -0.47 -3.10 -2.63 -0.146 0.10474E+05 25 phlogopite 3.90 2.01 -1.88 -0.105 0.75062E+04 27 anorthite -9.84 -10.34 -0.50 -0.038 0.19843E+04 30 apatite-OH -47.98 -48.59 -0.61 -0.047 0.24461E+04 31 apatite-OH-zs -45.91 -48.59 -2.68 -0.206 0.10687E+05 32 apatite-Cl-zs -51.31 -54.83 -3.52 -0.293 0.14023E+05 33 aragonite -3.70 -7.17 -3.47 -1.157 0.13837E+05 34 brucite 4.88 2.30 -2.58 -0.516 0.10292E+05 35 calcite -3.78 -7.17 -3.39 -1.130 0.13509E+05 36 carnegieite-low -0.77 -2.61 -1.85 -0.264 0.73672E+04 37 carnegieite-high -0.70 -2.61 -1.91 -0.273 0.76106E+04 38 carpholite-Mg -9.06 -10.91 -1.84 -0.123 0.73516E+04 39 carpholite-Fe -10.35 -12.61 -2.26 -0.151 0.90173E+04 40 celadonite -0.92 -3.46 -2.55 -0.150 0.10161E+05 41 celadonite-Fe -2.26 -5.17 -2.91 -0.171 0.11592E+05 42 chrysotile 8.75 5.14 -3.61 -0.301 0.14394E+05 44 clinochlore 0.46 -2.59 -3.05 -0.095 0.12154E+05 45 daphnite -6.24 -11.10 -4.86 -0.152 0.19379E+05 48 chloritoid-Mg -8.83 -10.03 -1.20 -0.080 0.47918E+04 49 chloritoid-Fe -10.65 -11.73 -1.08 -0.072 0.43128E+04 50 chloritoid-Mn -8.49 -10.43 -1.94 -0.130 0.77483E+04 52 coesite -0.61 -0.88 -0.27 -0.089 0.10651E+04 53 cordierite-H -21.96 -22.68 -0.73 -0.026 0.29014E+04 54 cordierite-Fe -24.21 -26.09 -1.88 -0.065 0.74886E+04 55 cordierite-Mn -19.80 -23.49 -3.68 -0.127 0.14687E+05 56 corundum -11.30 -11.45 -0.15 -0.014 0.60392E+03 58 cristobalite -0.81 -0.88 -0.06 -0.021 0.25651E+03 61 cymrite-K -2.61 -4.89 -2.28 -0.190 0.90698E+04 63 diaspore -5.16 -5.73 -0.56 -0.094 0.22490E+04 65 diopside 5.39 3.41 -1.98 -0.198 0.78765E+04 66 hedenbergite 4.04 1.71 -2.33 -0.233 0.92994E+04 68 eastonite -9.07 -10.86 -1.79 -0.069 0.71356E+04 69 enstatite 4.50 2.85 -1.66 -0.166 0.66033E+04 70 clinoenstatite-HiP 4.97 2.85 -2.13 -0.213 0.84727E+04 71 clinoenstatite 4.49 2.85 -1.65 -0.165 0.65618E+04 72 protoenstatite 4.64 2.85 -1.79 -0.179 0.71337E+04 73 epidote -6.07 -8.58 -2.51 -0.122 0.99972E+04 74 clinozoisite -11.76 -14.08 -2.32 -0.106 0.92530E+04 75 epidote-Fe 1.26 -3.08 -4.34 -0.226 0.17314E+05 76 fayalite 1.92 0.32 -1.60 -0.229 0.63845E+04 77 ferrosilite 1.12 -0.56 -1.68 -0.168 0.66892E+04 78 forsterite 5.71 3.72 -1.99 -0.284 0.79299E+04 79 gedrite -13.52 -16.66 -3.13 -0.085 0.12495E+05 81 gibbsite -3.63 -5.73 -2.10 -0.300 0.83825E+04 82 glaucophane 0.85 -3.59 -4.44 -0.120 0.17684E+05 84 goethite 0.92 -0.22 -1.15 -0.248 0.45726E+04 86 greenalite 4.19 0.03 -4.15 -0.346 0.16554E+05 88 halite -0.12 -2.25 -2.14 -1.069 0.85201E+04 89 hematite 0.39 -0.45 -0.84 -0.101 0.33318E+04 90 heulandite -12.22 -14.74 -2.52 -0.115 0.10045E+05 91 hercynite -9.92 -10.85 -0.94 -0.062 0.37304E+04 94 jadeite -1.82 -3.49 -1.67 -0.167 0.66589E+04 96 kalsilite -1.42 -3.13 -1.71 -0.245 0.68247E+04 97 kaolinite -11.00 -13.21 -2.21 -0.201 0.88033E+04 98 kyanite -12.20 -12.33 -0.13 -0.013 0.50357E+03 100 laumontite -8.95 -12.10 -3.15 -0.210 0.12574E+05 101 lawsonite -7.29 -10.35 -3.06 -0.204 0.12194E+05 102 leucite -2.93 -4.01 -1.08 -0.108 0.43105E+04 104 lizardite 8.95 5.14 -3.81 -0.317 0.15183E+05 105 magnesite -4.77 -7.73 -2.96 -0.988 0.11810E+05 106 magnetite 1.27 0.15 -1.12 -0.091 0.44578E+04 107 minnesotaite 1.23 -1.72 -2.94 -0.173 0.11734E+05 108 minnesotaite-Mg 6.89 3.39 -3.50 -0.206 0.13941E+05 109 magnesioferrite 4.20 1.85 -2.35 -0.192 0.93581E+04 111 manganosite 4.99 1.90 -3.09 -0.773 0.12333E+05 112 margarite -20.72 -21.79 -1.07 -0.043 0.42587E+04 115 microcline -4.70 -4.89 -0.18 -0.014 0.73277E+03 116 monticellite 8.38 4.29 -4.10 -0.585 0.16335E+05 118 mullite-Si -11.63 -12.33 -0.70 -0.070 0.27750E+04 119 muscovite -15.93 -16.34 -0.41 -0.024 0.16409E+04 120 paragonite -15.24 -15.82 -0.58 -0.034 0.23236E+04 121 nepheline -1.05 -2.61 -1.56 -0.223 0.62167E+04 122 osumilite(2) -13.49 -16.45 -2.96 -0.062 0.11804E+05 123 osumilite-Fe -30.37 -32.73 -2.35 -0.049 0.93811E+04 125 periclase 5.09 2.30 -2.79 -0.697 0.11113E+05 126 periclase-Fe 2.62 0.60 -2.02 -0.506 0.80706E+04 127 perovskite-Al -9.63 -11.45 -1.82 -0.165 0.72536E+04 132 phlogopite-Na 4.77 2.53 -2.24 -0.125 0.89378E+04 134 prehnite -5.13 -8.36 -3.23 -0.190 0.12872E+05 135 prehnite-Fe 0.96 -2.86 -3.82 -0.230 0.15220E+05 138 px-Mg-tschermaks -8.26 -10.03 -1.77 -0.126 0.70454E+04 139 px-Ca-tschermaks -7.19 -9.46 -2.27 -0.162 0.90523E+04 140 pyrite -19.59 -20.00 -0.40 -0.094 0.15995E+04 141 pyrrhotite -7.90 -8.88 -0.98 -0.326 0.38955E+04 142 pyrrhotiteFe0.875 -8.59 -9.16 -0.57 -0.208 0.22526E+04 143 pyrophyllite -14.14 -14.96 -0.82 -0.051 0.32764E+04 147 ringwoodite-Fe 2.88 0.32 -2.56 -0.366 0.10215E+05 149 rhodochrosite -4.59 -8.13 -3.54 -1.180 0.14106E+05 150 rhodonite 2.54 1.02 -1.52 -0.304 0.60555E+04 151 sanidine -4.18 -4.89 -0.70 -0.054 0.27978E+04 152 sapphirine(351) -46.91 -51.22 -4.31 -0.065 0.17163E+05 153 siderite -6.50 -9.43 -2.93 -0.978 0.11698E+05 154 sillimanite -12.31 -12.33 -0.02 -0.002 0.82950E+02 156 spinel -7.84 -9.15 -1.31 -0.087 0.52073E+04 158 staurolite-Fe -103.96 -107.23 -3.27 -0.030 0.13040E+05 159 staurolite-Mg -95.94 -100.42 -4.48 -0.041 0.17849E+05 163 stilpnomelane-Mg -1.58 -5.24 -3.66 -0.109 0.14606E+05 164 stishovite 1.95 -0.88 -2.82 -0.941 0.11256E+05 165 sudoite-Fe -20.78 -24.34 -3.57 -0.115 0.14211E+05 166 sudoite -18.68 -20.94 -2.25 -0.073 0.89822E+04 167 sulfur -9.65 -11.12 -1.47 -0.451 0.58417E+04 168 sylvite -0.04 -2.77 -2.74 -1.368 0.10904E+05 169 talc 5.19 3.39 -1.80 -0.106 0.71762E+04 170 talc-Fe 2.54 -1.72 -4.26 -0.251 0.16988E+05 171 talc-tschermaks -7.49 -9.48 -1.99 -0.117 0.79169E+04 173 tephroite 6.24 2.92 -3.32 -0.475 0.13241E+05 176 topaz-H -10.34 -12.33 -1.99 -0.181 0.79346E+04 179 troilite-low -7.80 -8.88 -1.08 -0.359 0.42929E+04 180 tschermakite -11.54 -15.54 -4.00 -0.108 0.15926E+05 183 wadsleyite-Fe 2.73 0.32 -2.41 -0.344 0.96080E+04 184 wadsleyite-Mg 7.84 3.72 -4.11 -0.587 0.16386E+05 185 wairakite -10.60 -12.10 -1.50 -0.088 0.59904E+04 186 walstromite 4.67 1.99 -2.68 -0.536 0.10692E+05 187 wollastonite 4.28 1.99 -2.29 -0.459 0.91430E+04 188 pseudo-wollastonite 4.38 1.99 -2.40 -0.480 0.95642E+04 189 zoisite -11.83 -14.08 -2.26 -0.103 0.89910E+04 192 beidellite-Ca -14.97 -16.09 -1.12 -0.069 0.44579E+04 193 beidellite-H -14.97 -16.56 -1.59 -0.101 0.63234E+04 194 beidellite-K -13.90 -15.41 -1.51 -0.092 0.60209E+04 195 beidellite-Mg -15.30 -16.18 -0.88 -0.055 0.35146E+04 196 beidellite-Na -13.84 -15.24 -1.41 -0.086 0.56053E+04 197 bornite -48.89 -48.91 -0.02 -0.001 0.70768E+02 199 chalcocite -12.62 -13.79 -1.17 -0.293 0.46737E+04 200 covellite -11.20 -12.45 -1.25 -0.476 0.49785E+04 202 montmorillonite-Ca -10.82 -11.84 -1.02 -0.063 0.40505E+04 203 montmorillonite-K -10.06 -11.17 -1.11 -0.068 0.44260E+04 204 montmorillonite-Mg -11.07 -11.93 -0.86 -0.053 0.34392E+04 205 montmorillonite-Na -9.67 -10.99 -1.32 -0.081 0.52746E+04 206 nontronite-Ca -3.07 -5.08 -2.02 -0.131 0.80474E+04 207 nontronite-H -3.08 -5.56 -2.48 -0.166 0.98804E+04 208 nontronite-K -2.00 -4.41 -2.41 -0.155 0.96022E+04 209 nontronite-Mg -3.33 -5.18 -1.85 -0.120 0.73741E+04 210 nontronite-Na -1.93 -4.24 -2.31 -0.148 0.91972E+04 215 gypsum -10.85 -13.18 -2.34 -0.584 0.93194E+04 232 alabandite -5.63 -7.58 -1.95 -0.651 0.77804E+04 234 anglesite -13.00 -15.81 -2.81 -1.407 0.11221E+05 237 barite -13.89 -14.19 -0.30 -0.152 0.12144E+04 238 boehmite -4.89 -5.73 -0.84 -0.140 0.33404E+04 240 chalcopyrite -21.10 -21.33 -0.24 -0.044 0.94444E+03 242 copper,native 1.82 -1.34 -3.16 -1.098 0.12587E+05 244 ferrous-oxide 1.72 0.60 -1.12 -0.281 0.44750E+04 245 galena -8.60 -9.25 -0.64 -0.215 0.25701E+04 246 silver,native 0.59 -3.82 -4.42 -1.536 0.17600E+05 255 sphalerite -10.01 -10.49 -0.48 -0.161 0.19224E+04 256 wurtzite -9.24 -10.49 -1.26 -0.419 0.50070E+04 257 zincite 1.89 -1.02 -2.90 -0.726 0.11570E+05 258 an20ab80 -5.47 -5.56 -0.09 -0.007 0.37578E+03 259 an25ab75 -5.78 -5.86 -0.08 -0.006 0.31561E+03 260 an30ab70 -6.09 -6.16 -0.07 -0.005 0.27902E+03 261 tr.625ac.25prg.125 9.60 6.37 -3.24 -0.087 0.12910E+05 Calculations done for 598.0000 Deg. C; 2245.0000 bar Temperature changed by -1.000 degrees to 597.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 20 Loop limit = 500 Temperature = 597.00 C Pressure = 2140.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5500E+02 kg liquid = 0.9908E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9944 Stoichiometric ionic strength = .3313200E+01 Osmotic coef. = 0.0000 True ionic strength = .2921090E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20575E-04 -4.6867 0.62690E-05 -5.2028 0.30469E+00 -0.5161 2 H2O 0.99439E+00 -0.0024 0.99439E+00 -0.0024 3 Cl- 0.24880E+00 -0.6041 0.72697E-01 -1.1385 0.29219E+00 -0.5343 4 SO4-- 0.13950E-03 -3.8554 0.16046E-05 -5.7946 0.11502E-01 -1.9392 5 HCO3- 0.36940E-04 -4.4325 0.11570E-04 -4.9367 0.31320E+00 -0.5042 6 HS- 0.15060E-03 -3.8222 0.44346E-04 -4.3531 0.29447E+00 -0.5310 7 H4SiO4 0.12521E+00 -0.9023 0.12521E+00 -0.9023 0.10000E+01 0.0000 8 Al+++ 0.13679E-16 -16.8639 0.45324E-21 -21.3437 0.33133E-04 -4.4797 9 Ca++ 0.36423E-05 -5.4386 0.34536E-07 -7.4617 0.94820E-02 -2.0231 10 Mg++ 0.12234E-05 -5.9124 0.96877E-08 -8.0138 0.79185E-02 -2.1014 11 Fe++ 0.21784E-07 -7.6619 0.18061E-09 -9.7433 0.82910E-02 -2.0814 12 K+ 0.63588E-01 -1.1966 0.20397E-01 -1.6904 0.32076E+00 -0.4938 13 Na+ 0.22588E+00 -0.6461 0.66831E-01 -1.1750 0.29587E+00 -0.5289 14 Mn++ 0.44567E-06 -6.3510 0.38207E-08 -8.4179 0.85731E-02 -2.0669 15 Zn++ 0.53928E-09 -9.2682 0.44712E-11 -11.3496 0.82910E-02 -2.0814 16 Cu+ 0.15633E-06 -6.8060 0.46137E-07 -7.3359 0.29513E+00 -0.5300 17 Pb++ 0.69867E-08 -8.1557 0.73461E-10 -10.1339 0.10514E-01 -1.9782 18 Ag+ 0.49348E-09 -9.3067 0.15601E-09 -9.8068 0.31614E+00 -0.5001 19 Ba++ 0.30459E-06 -6.5163 0.34172E-08 -8.4663 0.11219E-01 -1.9500 20 HPO4-- 0.16311E-08 -8.7875 0.18846E-10 -10.7248 0.11554E-01 -1.9373 21 HSiO3- 0.25237E-05 -5.5980 0.73739E-06 -6.1323 0.29219E+00 -0.5343 22 Ca(HSiO3)+ 0.19584E-07 -7.7081 0.63326E-08 -8.1984 0.32335E+00 -0.4903 23 Mg(HSiO3)+ 0.13424E-08 -8.8721 0.43407E-09 -9.3624 0.32335E+00 -0.4903 24 NaHSiO3,aq 0.11753E-05 -5.9298 0.11753E-05 -5.9298 0.10000E+01 0.0000 28 AgCl,aq 0.65729E-07 -7.1822 0.65729E-07 -7.1822 0.10000E+01 0.0000 29 AgCl2- 0.48924E-05 -5.3105 0.14295E-05 -5.8448 0.29219E+00 -0.5343 30 AgCl3-2 0.26972E-05 -5.5691 0.28926E-07 -7.5387 0.10724E-01 -1.9696 31 AgCl4-3 0.11231E-05 -5.9496 0.32235E-10 -10.4917 0.28702E-04 -4.5421 34 Ag(HS),aq 0.42151E-09 -9.3752 0.42151E-09 -9.3752 0.10000E+01 0.0000 35 Ag(HS)2- 0.24637E-08 -8.6084 0.71987E-09 -9.1427 0.29219E+00 -0.5343 36 AlO+ 0.20261E-10 -10.6933 0.65513E-11 -11.1837 0.32335E+00 -0.4903 38 HAlO2,aq 0.57032E-08 -8.2439 0.57032E-08 -8.2439 0.10000E+01 0.0000 39 AlO2- 0.26271E-04 -4.5805 0.67668E-05 -5.1696 0.25758E+00 -0.5891 41 Ba(HCO3)+ 0.14797E-05 -5.8298 0.49612E-06 -6.3044 0.33529E+00 -0.4746 42 BaCl+ 0.54104E-04 -4.2668 0.17495E-04 -4.7571 0.32335E+00 -0.4903 43 CH4,aq 0.21788E-08 -8.6618 0.26700E-08 -8.5735 0.12254E+01 0.0883 48 CO,aq 0.95931E-03 -3.0180 0.95931E-03 -3.0180 0.10000E+01 0.0000 49 CO2,aq 0.26798E+01 0.4281 0.32839E+01 0.5164 0.12254E+01 0.0883 50 CO3-2 0.60031E-10 -10.2216 0.64380E-12 -12.1913 0.10724E-01 -1.9696 51 CaCO3,aq 0.18357E-10 -10.7362 0.18357E-10 -10.7362 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.11985E-05 -5.9213 0.38756E-06 -6.4117 0.32335E+00 -0.4903 53 CaCl+ 0.36882E-03 -3.4332 0.11926E-03 -3.9235 0.32335E+00 -0.4903 54 CaCl2,aq 0.15860E-03 -3.7997 0.15860E-03 -3.7997 0.10000E+01 0.0000 55 CaOH+ 0.45758E-06 -6.3395 0.14796E-06 -6.8299 0.32335E+00 -0.4903 56 CaSO4,aq 0.92624E-07 -7.0333 0.92624E-07 -7.0333 0.10000E+01 0.0000 57 HCl,aq 0.10382E-02 -2.9837 0.10382E-02 -2.9837 0.10000E+01 0.0000 63 CuCl2,aq 0.10103E-10 -10.9956 0.10103E-10 -10.9956 0.10000E+01 0.0000 66 CuCl,aq 0.79592E-04 -4.0991 0.79592E-04 -4.0991 0.10000E+01 0.0000 67 CuCl2- 0.31462E-03 -3.5022 0.91930E-04 -4.0365 0.29219E+00 -0.5343 68 CuCl3-2 0.89556E-05 -5.0479 0.96043E-07 -7.0175 0.10724E-01 -1.9696 74 FeCl+ 0.69112E-06 -6.1604 0.22348E-06 -6.6508 0.32335E+00 -0.4903 75 FeCl2,aq 0.88475E-02 -2.0532 0.88475E-02 -2.0532 0.10000E+01 0.0000 77 FeO,aq 0.49160E-07 -7.3084 0.49160E-07 -7.3084 0.10000E+01 0.0000 78 FeOH+ 0.44355E-07 -7.3531 0.14343E-07 -7.8434 0.32335E+00 -0.4903 79 HFeO2- 0.75778E-08 -8.1205 0.22142E-08 -8.6548 0.29219E+00 -0.5343 82 FeO2- 0.40599E-08 -8.3915 0.11863E-08 -8.9258 0.29219E+00 -0.5343 83 HFeO2,aq 0.12314E-09 -9.9096 0.12314E-09 -9.9096 0.10000E+01 0.0000 84 H2,aq 0.42920E-02 -2.3673 0.52594E-02 -2.2791 0.12254E+01 0.0883 85 KCl,aq 0.48664E-01 -1.3128 0.48664E-01 -1.3128 0.10000E+01 0.0000 86 KHSO4,aq 0.11587E-01 -1.9360 0.11587E-01 -1.9360 0.10000E+01 0.0000 87 KOH,aq 0.71960E-06 -6.1429 0.71960E-06 -6.1429 0.10000E+01 0.0000 88 KSO4- 0.27371E-02 -2.5627 0.79975E-03 -3.0970 0.29219E+00 -0.5343 90 Mg(HCO3)+ 0.14860E-06 -6.8280 0.48050E-07 -7.3183 0.32335E+00 -0.4903 91 MgCl+ 0.18971E-04 -4.7219 0.61342E-05 -5.2122 0.32335E+00 -0.4903 92 MgOH+ 0.52509E-06 -6.2798 0.16979E-06 -6.7701 0.32335E+00 -0.4903 94 MnO,aq 0.15245E-07 -7.8169 0.15245E-07 -7.8169 0.10000E+01 0.0000 95 MnOH+ 0.11881E-06 -6.9252 0.38417E-07 -7.4155 0.32335E+00 -0.4903 97 HMnO2- 0.11370E-10 -10.9442 0.33222E-11 -11.4786 0.29219E+00 -0.5343 100 MnCl+ 0.11596E-02 -2.9357 0.37496E-03 -3.4260 0.32335E+00 -0.4903 101 MnSO4,aq 0.13126E-07 -7.8819 0.13126E-07 -7.8819 0.10000E+01 0.0000 102 NaCl,aq 0.33388E+00 -0.4764 0.33388E+00 -0.4764 0.10000E+01 0.0000 103 NaOH,aq 0.10703E-05 -5.9705 0.10703E-05 -5.9705 0.10000E+01 0.0000 105 OH- 0.99605E-05 -5.0017 0.25656E-05 -5.5908 0.25758E+00 -0.5891 110 HPO3-2 0.32821E-10 -10.4839 0.35198E-12 -12.4535 0.10724E-01 -1.9696 111 H3PO3,aq 0.27612E-09 -9.5589 0.27612E-09 -9.5589 0.10000E+01 0.0000 112 H2PO3- 0.13458E-07 -7.8710 0.39323E-08 -8.4053 0.29219E+00 -0.5343 113 H3PO4,aq 0.16158E-05 -5.7916 0.16158E-05 -5.7916 0.10000E+01 0.0000 114 H2PO4- 0.40066E-05 -5.3972 0.12269E-05 -5.9112 0.30621E+00 -0.5140 116 H4P2O7,aq 0.21038E-09 -9.6770 0.21038E-09 -9.6770 0.10000E+01 0.0000 117 H3P2O7- 0.57562E-08 -8.2399 0.16819E-08 -8.7742 0.29219E+00 -0.5343 118 H2P2O7-2 0.14696E-05 -5.8328 0.15760E-07 -7.8024 0.10724E-01 -1.9696 119 HP2O7-3 0.29133E-07 -7.5356 0.83617E-12 -12.0777 0.28702E-04 -4.5421 121 PbCl+ 0.38860E-05 -5.4105 0.12566E-05 -5.9008 0.32335E+00 -0.4903 122 PbCl2,aq 0.10256E-03 -3.9890 0.10256E-03 -3.9890 0.10000E+01 0.0000 123 PbCl3- 0.12114E-03 -3.9167 0.35396E-04 -4.4510 0.29219E+00 -0.5343 124 PbCl4-2 0.33601E-04 -4.4736 0.36035E-06 -6.4433 0.10724E-01 -1.9696 125 PbO,aq 0.24172E-08 -8.6167 0.24172E-08 -8.6167 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.76923E-04 -4.1139 0.76923E-04 -4.1139 0.10000E+01 0.0000 128 Pb(HS)3- 0.52157E-05 -5.2827 0.15240E-05 -5.8170 0.29219E+00 -0.5343 129 H2S,aq 0.10388E+01 0.0165 0.12729E+01 0.1048 0.12254E+01 0.0883 130 S2-2 0.13561E-07 -7.8677 0.14544E-09 -9.8373 0.10724E-01 -1.9696 131 S3-2 0.15379E-08 -8.8131 0.16493E-10 -10.7827 0.10724E-01 -1.9696 132 S3- 0.25244E-01 -1.5978 0.73760E-02 -2.1322 0.29219E+00 -0.5343 133 S4-2 0.14380E-09 -9.8423 0.15421E-11 -11.8119 0.10724E-01 -1.9696 134 S5-2 0.11263E-10 -10.9483 0.12079E-12 -12.9180 0.10724E-01 -1.9696 135 SO2,aq 0.28188E+00 -0.5499 0.28188E+00 -0.5499 0.10000E+01 0.0000 136 SO3-2 0.58409E-09 -9.2335 0.94516E-11 -11.0245 0.16182E-01 -1.7910 137 HSO3- 0.48625E-03 -3.3131 0.14208E-03 -3.8475 0.29219E+00 -0.5343 138 HSO4- 0.13361E-01 -1.8741 0.44225E-02 -2.3543 0.33099E+00 -0.4802 140 S2O3-2 0.46632E-06 -6.3313 0.50010E-08 -8.3009 0.10724E-01 -1.9696 141 HS2O3- 0.89965E-06 -6.0459 0.26287E-06 -6.5803 0.29219E+00 -0.5343 142 H2S2O3,aq 0.25583E-07 -7.5921 0.25583E-07 -7.5921 0.10000E+01 0.0000 150 S4O6-2 0.76519E-09 -9.1162 0.82062E-11 -11.0859 0.10724E-01 -1.9696 152 ZnCl+ 0.79946E-03 -3.0972 0.25851E-03 -3.5875 0.32335E+00 -0.4903 153 ZnCl2,aq 0.12902E-02 -2.8893 0.12902E-02 -2.8893 0.10000E+01 0.0000 154 ZnCl3- 0.22791E-03 -3.6422 0.66592E-04 -4.1766 0.29219E+00 -0.5343 155 ZnO,aq 0.21914E-07 -7.6593 0.21914E-07 -7.6593 0.10000E+01 0.0000 156 ZnOH+ 0.30976E-05 -5.5090 0.10016E-05 -5.9993 0.32335E+00 -0.4903 158 HZnO2- 0.21053E-09 -9.6767 0.61515E-10 -10.2110 0.29219E+00 -0.5343 Charge balance for all species = 0.2554E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2057500E-04 0.4304056E+01 0.3525252E+04 0.0000 2 H2O 0.1000000E+01 0.5248682E+02 0.7683682E+06 0.0000 3 Cl- 0.2488015E+00 0.6575237E+00 0.1894271E+05 4.0643 4 SO4-- 0.1395036E-03 0.2540655E+00 0.1983230E+05 4.6110 5 HCO3- 0.3694039E-04 0.2680833E+01 0.1329229E+06 0.2661 6 HS- 0.1505958E-03 0.1170941E+01 0.3146830E+05 0.8497 7 H4SiO4 0.1252149E+00 0.1252186E+00 0.9780015E+04 -0.9023 8 Al+++ 0.1367911E-16 0.2627636E-04 0.5761146E+00 -5.7353 9 Ca++ 0.3642304E-05 0.5328231E-03 0.1735268E+02 2.9439 10 Mg++ 0.1223429E-05 0.2086909E-04 0.4122890E+00 2.3918 11 Fe++ 0.2178372E-07 0.8848345E-02 0.4015499E+03 0.6623 12 K+ 0.6358848E-01 0.1265773E+00 0.4021911E+04 3.5124 13 Na+ 0.2258814E+00 0.5597609E+00 0.1045720E+05 4.0278 14 Mn++ 0.4456678E-06 0.1160198E-02 0.5179438E+02 1.9878 15 Zn++ 0.5392815E-09 0.2320734E-02 0.1232768E+03 -0.9440 16 Cu+ 0.1563288E-06 0.4033288E-03 0.2082496E+02 -2.1331 17 Pb++ 0.6986689E-08 0.3433386E-03 0.5780548E+02 0.2717 18 Ag+ 0.4934835E-09 0.8781820E-05 0.7697732E+00 -4.6040 19 Ba++ 0.3045886E-06 0.5588780E-04 0.6237228E+01 1.9393 20 HPO4-- 0.1631110E-08 0.8647237E-05 0.6744212E+00 -0.3192 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4264368E+01 -.2005516E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5200284E+02 -.3805794E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517228E+00 0.0000000E+00 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160144E+01 0.0000000E+00 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1240640E+00 0.1953035E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2603406E-04 0.6685055E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.5279099E-03 0.0000000E+00 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8766754E-02 0.0000000E+00 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3996097E-03 0.0000000E+00 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.121927E+04 g Temperature = 597.00 C Pressure = 2140.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) andalusite 0.3343E-03 -3.476 0.5417E-01 -1.266 4.486 0.1722E-01 quartz 0.1920E-01 -1.717 1.153 0.062 95.51 0.4355 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity andalusite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.207467 g Volume = 0.452760 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 19 andalusite -12.38 -12.38 0.00 0.000 0.00000E+00 144 quartz -0.90 -0.90 0.00 0.000 0.00000E+00 197 bornite -49.29 -49.06 0.23 0.017 -0.92083E+03 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.30 -0.297 0.11817E+04 3.034 2 CO2,gas -8.81 -10.14 -1.33 -0.443 0.52920E+04 2.001 3 CH4,gas 6.88 -3.50 -10.38 -2.595 0.41330E+05 -7.050 4 H2,gas 5.71 1.66 -4.05 -2.314 0.16125E+05 -0.719 5 H2S,gas -7.31 -9.56 -2.25 -1.123 0.89450E+04 1.084 6 CO,gas -2.96 -8.48 -5.51 -1.697 0.21958E+05 -2.184 7 SO3,gas -6.07 -16.20 -10.13 -2.532 0.40334E+05 -6.799 8 O2,gas 16.47 -3.32 -19.79 -13.194 0.78802E+05 -16.461 9 HCl,gas -5.48 -6.34 -0.86 -0.429 0.34172E+04 -0.858 10 acmite 4.08 2.06 -2.02 -0.209 0.80281E+04 12 akimotoite 5.84 1.49 -4.35 -0.870 0.17323E+05 13 akimotoite-Fe 3.84 -0.24 -4.08 -0.815 0.16234E+05 14 albite-high -4.22 -4.40 -0.18 -0.014 0.71593E+03 15 albite -4.19 -4.40 -0.22 -0.017 0.86294E+03 16 almandine -10.35 -12.19 -1.84 -0.092 0.73296E+04 17 pyrope -4.03 -7.00 -2.97 -0.149 0.11837E+05 18 analcite -2.54 -3.51 -0.97 -0.108 0.38746E+04 21 grossular -0.44 -5.35 -4.90 -0.245 0.19517E+05 22 anhydrite -13.05 -13.26 -0.21 -0.104 0.82556E+03 24 annite -0.58 -2.94 -2.36 -0.131 0.94121E+04 25 phlogopite 3.79 2.25 -1.55 -0.086 0.61657E+04 27 anorthite -9.93 -10.33 -0.40 -0.031 0.15914E+04 28 anthophyllite 13.93 9.54 -4.38 -0.118 0.17454E+05 29 anthophyllite-Fe 1.97 -2.56 -4.53 -0.122 0.18045E+05 30 apatite-OH -48.52 -48.67 -0.16 -0.012 0.61913E+03 31 apatite-OH-zs -46.45 -48.67 -2.23 -0.171 0.88665E+04 32 apatite-Cl-zs -51.92 -55.01 -3.09 -0.258 0.12313E+05 33 aragonite -3.78 -7.20 -3.42 -1.138 0.13598E+05 34 brucite 4.88 2.39 -2.49 -0.498 0.99242E+04 35 calcite -3.86 -7.20 -3.33 -1.110 0.13263E+05 36 carnegieite-low -0.81 -2.61 -1.80 -0.257 0.71737E+04 37 carnegieite-high -0.75 -2.61 -1.86 -0.266 0.74174E+04 38 carpholite-Mg -9.13 -10.89 -1.76 -0.118 0.70202E+04 39 carpholite-Fe -10.41 -12.62 -2.20 -0.147 0.87794E+04 40 celadonite -1.01 -3.43 -2.42 -0.142 0.96318E+04 41 celadonite-Fe -2.36 -5.16 -2.80 -0.165 0.11159E+05 42 chrysotile 8.70 5.37 -3.33 -0.277 0.13252E+05 44 clinochlore 0.34 -2.23 -2.58 -0.081 0.10262E+05 45 daphnite -6.37 -10.88 -4.51 -0.141 0.17959E+05 48 chloritoid-Mg -8.87 -9.99 -1.11 -0.074 0.44364E+04 49 chloritoid-Fe -10.70 -11.72 -1.02 -0.068 0.40477E+04 50 chloritoid-Mn -8.54 -10.39 -1.85 -0.124 0.73808E+04 52 coesite -0.63 -0.90 -0.27 -0.089 0.10691E+04 53 cordierite-H -22.14 -22.67 -0.52 -0.019 0.20879E+04 54 cordierite-Fe -24.42 -26.12 -1.71 -0.059 0.67888E+04 55 cordierite-Mn -20.01 -23.47 -3.46 -0.119 0.13781E+05 56 corundum -11.32 -11.48 -0.15 -0.014 0.61241E+03 58 cristobalite -0.84 -0.90 -0.06 -0.021 0.24549E+03 59 cummingtonite 13.98 9.54 -4.43 -0.120 0.17652E+05 61 cymrite-K -2.68 -4.92 -2.24 -0.187 0.89263E+04 63 diaspore -5.17 -5.74 -0.57 -0.095 0.22674E+04 65 diopside 5.33 3.54 -1.79 -0.179 0.71239E+04 66 hedenbergite 3.98 1.81 -2.17 -0.217 0.86397E+04 68 eastonite -9.17 -10.72 -1.55 -0.060 0.61848E+04 69 enstatite 4.45 2.98 -1.46 -0.146 0.58261E+04 70 clinoenstatite-HiP 4.92 2.98 -1.93 -0.193 0.76985E+04 71 clinoenstatite 4.44 2.98 -1.45 -0.145 0.57839E+04 72 protoenstatite 4.58 2.98 -1.60 -0.160 0.63515E+04 73 epidote -6.20 -8.46 -2.26 -0.109 0.89922E+04 74 clinozoisite -11.88 -14.03 -2.15 -0.098 0.85533E+04 75 epidote-Fe 1.13 -2.89 -4.02 -0.209 0.16002E+05 76 fayalite 1.88 0.42 -1.45 -0.208 0.57840E+04 77 ferrosilite 1.06 -0.48 -1.53 -0.153 0.60954E+04 78 forsterite 5.68 3.88 -1.79 -0.256 0.71431E+04 79 gedrite -13.74 -16.40 -2.65 -0.072 0.10563E+05 81 gibbsite -3.63 -5.74 -2.12 -0.302 0.84293E+04 82 glaucophane 0.63 -3.44 -4.07 -0.110 0.16202E+05 84 goethite 0.91 -0.17 -1.08 -0.233 0.42884E+04 86 greenalite 4.12 0.18 -3.94 -0.328 0.15672E+05 88 halite -0.19 -2.31 -2.13 -1.063 0.84643E+04 89 hematite 0.34 -0.34 -0.69 -0.083 0.27323E+04 90 heulandite -12.37 -14.83 -2.46 -0.112 0.97897E+04 91 hercynite -9.96 -10.82 -0.86 -0.057 0.34315E+04 94 jadeite -1.87 -3.51 -1.63 -0.163 0.65030E+04 96 kalsilite -1.46 -3.13 -1.67 -0.238 0.66382E+04 97 kaolinite -11.06 -13.28 -2.22 -0.202 0.88466E+04 98 kyanite -12.24 -12.38 -0.13 -0.013 0.51975E+03 100 laumontite -9.05 -12.14 -3.09 -0.206 0.12285E+05 101 lawsonite -7.35 -10.34 -2.99 -0.199 0.11907E+05 102 leucite -2.99 -4.02 -1.03 -0.103 0.41144E+04 104 lizardite 8.89 5.37 -3.53 -0.294 0.14039E+05 105 magnesite -4.85 -7.75 -2.90 -0.967 0.11547E+05 106 magnetite 1.21 0.32 -0.89 -0.073 0.35536E+04 107 minnesotaite 1.11 -1.61 -2.72 -0.160 0.10831E+05 108 minnesotaite-Mg 6.78 3.58 -3.21 -0.189 0.12763E+05 109 magnesioferrite 4.15 2.05 -2.10 -0.171 0.83579E+04 111 manganosite 4.98 1.99 -3.00 -0.749 0.11930E+05 112 margarite -20.83 -21.81 -0.98 -0.039 0.39182E+04 115 microcline -4.79 -4.92 -0.13 -0.010 0.53573E+03 116 monticellite 8.34 4.43 -3.91 -0.558 0.15566E+05 118 mullite-Si -11.68 -12.38 -0.70 -0.070 0.27812E+04 119 muscovite -16.02 -16.40 -0.38 -0.022 0.14954E+04 120 paragonite -15.34 -15.89 -0.55 -0.032 0.21803E+04 121 nepheline -1.10 -2.61 -1.51 -0.216 0.60262E+04 122 osumilite(2) -13.81 -16.41 -2.60 -0.054 0.10353E+05 123 osumilite-Fe -30.70 -32.84 -2.14 -0.045 0.85049E+04 124 pargasite 1.80 -3.14 -4.94 -0.130 0.19671E+05 125 periclase 5.08 2.39 -2.69 -0.673 0.10719E+05 126 periclase-Fe 2.61 0.66 -1.95 -0.488 0.77709E+04 127 perovskite-Al -9.65 -11.48 -1.82 -0.166 0.72624E+04 132 phlogopite-Na 4.67 2.76 -1.91 -0.106 0.75928E+04 134 prehnite -5.24 -8.29 -3.05 -0.180 0.12158E+05 135 prehnite-Fe 0.84 -2.72 -3.56 -0.214 0.14190E+05 138 px-Mg-tschermaks -8.31 -9.99 -1.67 -0.119 0.66594E+04 139 px-Ca-tschermaks -7.25 -9.43 -2.18 -0.156 0.86912E+04 140 pyrite -19.77 -20.11 -0.34 -0.080 0.13478E+04 141 pyrrhotite -7.99 -8.89 -0.91 -0.302 0.36099E+04 142 pyrrhotiteFe0.875 -8.68 -9.18 -0.50 -0.185 0.20072E+04 143 pyrophyllite -14.24 -15.07 -0.83 -0.052 0.33087E+04 146 riebeckite 7.08 2.51 -4.57 -0.126 0.18183E+05 147 ringwoodite-Fe 2.84 0.42 -2.42 -0.345 0.96220E+04 148 ringwoodite-Mg 8.72 3.88 -4.84 -0.691 0.19258E+05 149 rhodochrosite -4.68 -8.15 -3.47 -1.158 0.13834E+05 150 rhodonite 2.51 1.09 -1.42 -0.284 0.56550E+04 151 sanidine -4.27 -4.92 -0.65 -0.050 0.26008E+04 152 sapphirine(351) -47.10 -51.12 -4.02 -0.061 0.15997E+05 153 siderite -6.58 -9.48 -2.90 -0.965 0.11528E+05 154 sillimanite -12.35 -12.38 -0.02 -0.002 0.87178E+02 156 spinel -7.88 -9.09 -1.21 -0.081 0.48140E+04 158 staurolite-Fe -104.38 -107.40 -3.02 -0.028 0.12008E+05 159 staurolite-Mg -96.35 -100.48 -4.13 -0.038 0.16451E+05 163 stilpnomelane-Mg -1.78 -4.97 -3.19 -0.095 0.12707E+05 164 stishovite 1.93 -0.90 -2.83 -0.944 0.11273E+05 165 sudoite-Fe -20.89 -24.34 -3.45 -0.111 0.13730E+05 166 sudoite -18.79 -20.88 -2.09 -0.067 0.83113E+04 167 sulfur -9.74 -11.21 -1.47 -0.453 0.58622E+04 168 sylvite -0.11 -2.83 -2.72 -1.361 0.10839E+05 169 talc 5.09 3.58 -1.51 -0.089 0.60117E+04 170 talc-Fe 2.43 -1.61 -4.04 -0.238 0.16100E+05 171 talc-tschermaks -7.60 -9.39 -1.79 -0.106 0.71429E+04 173 tephroite 6.20 3.07 -3.12 -0.446 0.12434E+05 176 topaz-H -10.37 -12.38 -2.00 -0.182 0.79818E+04 177 tremolite 15.12 10.65 -4.47 -0.121 0.17814E+05 179 troilite-low -7.89 -8.89 -1.01 -0.335 0.40062E+04 180 tschermakite -11.77 -15.29 -3.52 -0.095 0.14029E+05 183 wadsleyite-Fe 2.69 0.42 -2.26 -0.323 0.90132E+04 184 wadsleyite-Mg 7.80 3.88 -3.92 -0.560 0.15607E+05 185 wairakite -10.72 -12.13 -1.41 -0.083 0.56115E+04 186 walstromite 4.64 2.04 -2.59 -0.519 0.10324E+05 187 wollastonite 4.25 2.04 -2.20 -0.440 0.87685E+04 188 pseudo-wollastonite 4.35 2.04 -2.31 -0.462 0.91903E+04 189 zoisite -11.94 -14.03 -2.08 -0.095 0.82935E+04 192 beidellite-Ca -15.07 -16.18 -1.11 -0.069 0.44257E+04 193 beidellite-H -15.07 -16.67 -1.60 -0.102 0.63537E+04 194 beidellite-K -14.00 -15.51 -1.50 -0.092 0.59907E+04 195 beidellite-Mg -15.40 -16.27 -0.88 -0.054 0.34918E+04 196 beidellite-Na -13.94 -15.34 -1.40 -0.086 0.55762E+04 199 chalcocite -12.72 -13.82 -1.10 -0.276 0.43895E+04 200 covellite -11.30 -12.52 -1.22 -0.463 0.48441E+04 202 montmorillonite-Ca -10.93 -11.90 -0.98 -0.060 0.38823E+04 203 montmorillonite-K -10.16 -11.23 -1.07 -0.066 0.42637E+04 204 montmorillonite-Mg -11.17 -11.99 -0.82 -0.051 0.32657E+04 205 montmorillonite-Na -9.78 -11.06 -1.28 -0.078 0.51019E+04 206 nontronite-Ca -3.18 -5.05 -1.86 -0.121 0.74163E+04 207 nontronite-H -3.19 -5.53 -2.34 -0.157 0.93119E+04 208 nontronite-K -2.12 -4.37 -2.25 -0.145 0.89729E+04 209 nontronite-Mg -3.44 -5.14 -1.69 -0.110 0.67410E+04 210 nontronite-Na -2.05 -4.20 -2.15 -0.138 0.85694E+04 215 gypsum -10.99 -13.26 -2.28 -0.569 0.90625E+04 232 alabandite -5.71 -7.57 -1.86 -0.619 0.73918E+04 234 anglesite -13.16 -15.93 -2.77 -1.386 0.11038E+05 237 barite -14.04 -14.26 -0.22 -0.109 0.86655E+03 238 boehmite -4.90 -5.74 -0.84 -0.140 0.33559E+04 240 chalcopyrite -21.28 -21.41 -0.13 -0.024 0.51936E+03 242 copper,native 1.82 -1.30 -3.12 -1.086 0.12426E+05 244 ferrous-oxide 1.71 0.66 -1.05 -0.262 0.41771E+04 245 galena -8.70 -9.28 -0.58 -0.195 0.23291E+04 246 silver,native 0.59 -3.77 -4.37 -1.519 0.17387E+05 248 litharge 5.21 0.27 -4.94 -1.236 0.19680E+05 255 sphalerite -10.10 -10.50 -0.40 -0.132 0.15759E+04 256 wurtzite -9.33 -10.50 -1.17 -0.390 0.46612E+04 257 zincite 1.87 -0.95 -2.82 -0.704 0.11215E+05 258 an20ab80 -5.55 -5.59 -0.04 -0.003 0.14342E+03 259 an25ab75 -5.87 -5.89 -0.02 -0.001 0.72973E+02 260 an30ab70 -6.18 -6.18 -0.01 -0.001 0.26905E+02 261 tr.625ac.25prg.125 9.37 6.76 -2.61 -0.070 0.10388E+05 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 16 Loop limit = 500 Temperature = 597.00 C Pressure = 2140.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5500E+02 kg liquid = 0.9908E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9944 Stoichiometric ionic strength = .3313143E+01 Osmotic coef. = 0.0000 True ionic strength = .2920763E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20596E-04 -4.6862 0.62755E-05 -5.2023 0.30470E+00 -0.5161 2 H2O 0.99439E+00 -0.0024 0.99439E+00 -0.0024 3 Cl- 0.24884E+00 -0.6041 0.72712E-01 -1.1384 0.29220E+00 -0.5343 4 SO4-- 0.13922E-03 -3.8563 0.16016E-05 -5.7954 0.11504E-01 -1.9392 5 HCO3- 0.36900E-04 -4.4330 0.11558E-04 -4.9371 0.31321E+00 -0.5042 6 HS- 0.15043E-03 -3.8227 0.44300E-04 -4.3536 0.29448E+00 -0.5309 7 H4SiO4 0.12521E+00 -0.9023 0.12521E+00 -0.9023 0.10000E+01 0.0000 8 Al+++ 0.13717E-16 -16.8627 0.45466E-21 -21.3423 0.33146E-04 -4.4796 9 Ca++ 0.36408E-05 -5.4388 0.34528E-07 -7.4618 0.94837E-02 -2.0230 10 Mg++ 0.12231E-05 -5.9126 0.96866E-08 -8.0138 0.79200E-02 -2.1013 11 Fe++ 0.21751E-07 -7.6625 0.18037E-09 -9.7438 0.82925E-02 -2.0813 12 K+ 0.63590E-01 -1.1966 0.20398E-01 -1.6904 0.32077E+00 -0.4938 13 Na+ 0.22585E+00 -0.6462 0.66823E-01 -1.1751 0.29588E+00 -0.5289 14 Mn++ 0.44551E-06 -6.3511 0.38201E-08 -8.4179 0.85746E-02 -2.0668 15 Zn++ 0.53899E-09 -9.2684 0.44696E-11 -11.3497 0.82925E-02 -2.0813 16 Cu+ 0.14077E-06 -6.8515 0.41547E-07 -7.3815 0.29514E+00 -0.5300 17 Pb++ 0.69864E-08 -8.1557 0.73470E-10 -10.1339 0.10516E-01 -1.9781 18 Ag+ 0.49327E-09 -9.3069 0.15595E-09 -9.8070 0.31615E+00 -0.5001 19 Ba++ 0.30450E-06 -6.5164 0.34167E-08 -8.4664 0.11221E-01 -1.9500 20 HPO4-- 0.16290E-08 -8.7881 0.18825E-10 -10.7253 0.11556E-01 -1.9372 21 HSiO3- 0.25209E-05 -5.5984 0.73662E-06 -6.1328 0.29220E+00 -0.5343 22 Ca(HSiO3)+ 0.19558E-07 -7.7087 0.63245E-08 -8.1990 0.32336E+00 -0.4903 23 Mg(HSiO3)+ 0.13408E-08 -8.8726 0.43357E-09 -9.3629 0.32336E+00 -0.4903 24 NaHSiO3,aq 0.11740E-05 -5.9303 0.11740E-05 -5.9303 0.10000E+01 0.0000 28 AgCl,aq 0.65716E-07 -7.1823 0.65716E-07 -7.1823 0.10000E+01 0.0000 29 AgCl2- 0.48922E-05 -5.3105 0.14295E-05 -5.8448 0.29220E+00 -0.5343 30 AgCl3-2 0.26974E-05 -5.5691 0.28932E-07 -7.5386 0.10726E-01 -1.9696 31 AgCl4-3 0.11231E-05 -5.9496 0.32249E-10 -10.4915 0.28714E-04 -4.5419 34 Ag(HS),aq 0.42090E-09 -9.3758 0.42090E-09 -9.3758 0.10000E+01 0.0000 35 Ag(HS)2- 0.24575E-08 -8.6095 0.71809E-09 -9.1438 0.29220E+00 -0.5343 36 AlO+ 0.20281E-10 -10.6929 0.65582E-11 -11.1832 0.32336E+00 -0.4903 38 HAlO2,aq 0.57032E-08 -8.2439 0.57032E-08 -8.2439 0.10000E+01 0.0000 39 AlO2- 0.26242E-04 -4.5810 0.67597E-05 -5.1701 0.25759E+00 -0.5891 41 Ba(HCO3)+ 0.14779E-05 -5.8304 0.49553E-06 -6.3049 0.33530E+00 -0.4746 42 BaCl+ 0.54105E-04 -4.2668 0.17496E-04 -4.7571 0.32336E+00 -0.4903 43 CH4,aq 0.21783E-08 -8.6619 0.26693E-08 -8.5736 0.12254E+01 0.0883 48 CO,aq 0.95925E-03 -3.0181 0.95925E-03 -3.0181 0.10000E+01 0.0000 49 CO2,aq 0.26798E+01 0.4281 0.32839E+01 0.5164 0.12254E+01 0.0883 50 CO3-2 0.59895E-10 -10.2226 0.64245E-12 -12.1922 0.10726E-01 -1.9696 51 CaCO3,aq 0.18314E-10 -10.7372 0.18314E-10 -10.7372 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.11970E-05 -5.9219 0.38706E-06 -6.4122 0.32336E+00 -0.4903 53 CaCl+ 0.36879E-03 -3.4332 0.11925E-03 -3.9235 0.32336E+00 -0.4903 54 CaCl2,aq 0.15862E-03 -3.7996 0.15862E-03 -3.7996 0.10000E+01 0.0000 55 CaOH+ 0.45698E-06 -6.3401 0.14777E-06 -6.8304 0.32336E+00 -0.4903 56 CaSO4,aq 0.92430E-07 -7.0342 0.92430E-07 -7.0342 0.10000E+01 0.0000 57 HCl,aq 0.10395E-02 -2.9832 0.10395E-02 -2.9832 0.10000E+01 0.0000 66 CuCl,aq 0.71689E-04 -4.1445 0.71689E-04 -4.1445 0.10000E+01 0.0000 67 CuCl2- 0.28343E-03 -3.5476 0.82819E-04 -4.0819 0.29220E+00 -0.5343 68 CuCl3-2 0.80683E-05 -5.0932 0.86542E-07 -7.0628 0.10726E-01 -1.9696 74 FeCl+ 0.69033E-06 -6.1609 0.22323E-06 -6.6513 0.32336E+00 -0.4903 75 FeCl2,aq 0.88395E-02 -2.0536 0.88395E-02 -2.0536 0.10000E+01 0.0000 77 FeO,aq 0.48993E-07 -7.3099 0.48993E-07 -7.3099 0.10000E+01 0.0000 78 FeOH+ 0.44249E-07 -7.3541 0.14309E-07 -7.8444 0.32336E+00 -0.4903 79 HFeO2- 0.75438E-08 -8.1224 0.22043E-08 -8.6567 0.29220E+00 -0.5343 82 FeO2- 0.40418E-08 -8.3934 0.11810E-08 -8.9277 0.29220E+00 -0.5343 83 HFeO2,aq 0.12273E-09 -9.9111 0.12273E-09 -9.9111 0.10000E+01 0.0000 84 H2,aq 0.42917E-02 -2.3674 0.52591E-02 -2.2791 0.12254E+01 0.0883 85 KCl,aq 0.48676E-01 -1.3127 0.48676E-01 -1.3127 0.10000E+01 0.0000 86 KHSO4,aq 0.11579E-01 -1.9363 0.11579E-01 -1.9363 0.10000E+01 0.0000 87 KOH,aq 0.71889E-06 -6.1433 0.71889E-06 -6.1433 0.10000E+01 0.0000 88 KSO4- 0.27321E-02 -2.5635 0.79831E-03 -3.0978 0.29220E+00 -0.5343 90 Mg(HCO3)+ 0.14842E-06 -6.8285 0.47994E-07 -7.3188 0.32336E+00 -0.4903 91 MgCl+ 0.18972E-04 -4.7219 0.61348E-05 -5.2122 0.32336E+00 -0.4903 92 MgOH+ 0.52447E-06 -6.2803 0.16959E-06 -6.7706 0.32336E+00 -0.4903 94 MnO,aq 0.15210E-07 -7.8179 0.15210E-07 -7.8179 0.10000E+01 0.0000 95 MnOH+ 0.11866E-06 -6.9257 0.38370E-07 -7.4160 0.32336E+00 -0.4903 97 HMnO2- 0.11332E-10 -10.9457 0.33112E-11 -11.4800 0.29220E+00 -0.5343 100 MnCl+ 0.11596E-02 -2.9357 0.37497E-03 -3.4260 0.32336E+00 -0.4903 101 MnSO4,aq 0.13100E-07 -7.8827 0.13100E-07 -7.8827 0.10000E+01 0.0000 102 NaCl,aq 0.33391E+00 -0.4764 0.33391E+00 -0.4764 0.10000E+01 0.0000 103 NaOH,aq 0.10691E-05 -5.9710 0.10691E-05 -5.9710 0.10000E+01 0.0000 105 OH- 0.99496E-05 -5.0022 0.25630E-05 -5.5913 0.25759E+00 -0.5891 110 HPO3-2 0.32776E-10 -10.4844 0.35156E-12 -12.4540 0.10726E-01 -1.9696 111 H3PO3,aq 0.27637E-09 -9.5585 0.27637E-09 -9.5585 0.10000E+01 0.0000 112 H2PO3- 0.13456E-07 -7.8711 0.39318E-08 -8.4054 0.29220E+00 -0.5343 113 H3PO4,aq 0.16174E-05 -5.7912 0.16174E-05 -5.7912 0.10000E+01 0.0000 114 H2PO4- 0.40061E-05 -5.3973 0.12268E-05 -5.9112 0.30622E+00 -0.5140 116 H4P2O7,aq 0.21079E-09 -9.6762 0.21079E-09 -9.6762 0.10000E+01 0.0000 117 H3P2O7- 0.57610E-08 -8.2395 0.16834E-08 -8.7738 0.29220E+00 -0.5343 118 H2P2O7-2 0.14691E-05 -5.8330 0.15758E-07 -7.8025 0.10726E-01 -1.9696 119 HP2O7-3 0.29086E-07 -7.5363 0.83515E-12 -12.0782 0.28714E-04 -4.5419 121 PbCl+ 0.38872E-05 -5.4104 0.12570E-05 -5.9007 0.32336E+00 -0.4903 122 PbCl2,aq 0.10262E-03 -3.9888 0.10262E-03 -3.9888 0.10000E+01 0.0000 123 PbCl3- 0.12123E-03 -3.9164 0.35423E-04 -4.4507 0.29220E+00 -0.5343 124 PbCl4-2 0.33627E-04 -4.4733 0.36069E-06 -6.4429 0.10726E-01 -1.9696 125 PbO,aq 0.24124E-08 -8.6175 0.24124E-08 -8.6175 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.76772E-04 -4.1148 0.76772E-04 -4.1148 0.10000E+01 0.0000 128 Pb(HS)3- 0.51998E-05 -5.2840 0.15194E-05 -5.8183 0.29220E+00 -0.5343 129 H2S,aq 0.10388E+01 0.0165 0.12729E+01 0.1048 0.12254E+01 0.0883 130 S2-2 0.13532E-07 -7.8686 0.14514E-09 -9.8382 0.10726E-01 -1.9696 131 S3-2 0.15346E-08 -8.8140 0.16461E-10 -10.7836 0.10726E-01 -1.9696 132 S3- 0.25221E-01 -1.5982 0.73695E-02 -2.1326 0.29220E+00 -0.5343 133 S4-2 0.14350E-09 -9.8431 0.15392E-11 -11.8127 0.10726E-01 -1.9696 134 S5-2 0.11241E-10 -10.9492 0.12057E-12 -12.9188 0.10726E-01 -1.9696 135 SO2,aq 0.28193E+00 -0.5499 0.28193E+00 -0.5499 0.10000E+01 0.0000 136 SO3-2 0.58289E-09 -9.2344 0.94335E-11 -11.0253 0.16184E-01 -1.7909 137 HSO3- 0.48581E-03 -3.3135 0.14196E-03 -3.8478 0.29220E+00 -0.5343 138 HSO4- 0.13350E-01 -1.8745 0.44189E-02 -2.3547 0.33100E+00 -0.4802 140 S2O3-2 0.46539E-06 -6.3322 0.49918E-08 -8.3017 0.10726E-01 -1.9696 141 HS2O3- 0.89890E-06 -6.0463 0.26266E-06 -6.5806 0.29220E+00 -0.5343 142 H2S2O3,aq 0.25589E-07 -7.5919 0.25589E-07 -7.5919 0.10000E+01 0.0000 150 S4O6-2 0.76389E-09 -9.1170 0.81936E-11 -11.0865 0.10726E-01 -1.9696 152 ZnCl+ 0.79932E-03 -3.0973 0.25847E-03 -3.5876 0.32336E+00 -0.4903 153 ZnCl2,aq 0.12903E-02 -2.8893 0.12903E-02 -2.8893 0.10000E+01 0.0000 154 ZnCl3- 0.22796E-03 -3.6421 0.66610E-04 -4.1765 0.29220E+00 -0.5343 155 ZnO,aq 0.21860E-07 -7.6603 0.21860E-07 -7.6603 0.10000E+01 0.0000 156 ZnOH+ 0.30932E-05 -5.5096 0.10002E-05 -5.9999 0.32336E+00 -0.4903 158 HZnO2- 0.20979E-09 -9.6782 0.61300E-10 -10.2125 0.29220E+00 -0.5343 Charge balance for all species = 0.2554E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2059575E-04 0.4304079E+01 0.3525282E+04 0.0000 2 H2O 0.1000000E+01 0.5248683E+02 0.7683708E+06 0.0000 3 Cl- 0.2488432E+00 0.6575238E+00 0.1894277E+05 4.0640 4 SO4-- 0.1392226E-03 0.2540645E+00 0.1983229E+05 4.6093 5 HCO3- 0.3690039E-04 0.2680833E+01 0.1329233E+06 0.2652 6 HS- 0.1504335E-03 0.1170911E+01 0.3146757E+05 0.8488 7 H4SiO4 0.1252149E+00 0.1252187E+00 0.9780049E+04 -0.9023 8 Al+++ 0.1371680E-16 0.2624752E-04 0.5754842E+00 -5.7353 9 Ca++ 0.3640792E-05 0.5328231E-03 0.1735274E+02 2.9429 10 Mg++ 0.1223057E-05 0.2086909E-04 0.4122903E+00 2.3909 11 Fe++ 0.2175101E-07 0.8840345E-02 0.4011881E+03 0.6609 12 K+ 0.6358978E-01 0.1265773E+00 0.4021924E+04 3.5119 13 Na+ 0.2258487E+00 0.5597610E+00 0.1045723E+05 4.0273 14 Mn++ 0.4455075E-06 0.1160198E-02 0.5179455E+02 1.9868 15 Zn++ 0.5389948E-09 0.2320734E-02 0.1232772E+03 -0.9450 16 Cu+ 0.1407719E-06 0.3633296E-03 0.1875975E+02 -2.1791 17 Pb++ 0.6986355E-08 0.3433386E-03 0.5780567E+02 0.2708 18 Ag+ 0.4932704E-09 0.8781820E-05 0.7697757E+00 -4.6047 19 Ba++ 0.3044961E-06 0.5588780E-04 0.6237249E+01 1.9383 20 HPO4-- 0.1628999E-08 0.8647237E-05 0.6744234E+00 -0.3206 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4264391E+01 -.2028390E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5200284E+02 -.3806179E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517218E+00 0.9907601E-06 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160113E+01 0.3071356E-04 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1240640E+00 0.1953031E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2600549E-04 0.6685340E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.5279099E-03 0.0000000E+00 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8758828E-02 0.7926081E-05 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3599793E-03 0.3963041E-04 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.6776E-19 Mass of aqueous solution: 0.121926E+04 g Temperature = 597.00 C Pressure = 2140.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) andalusite 0.3343E-03 -3.476 0.5417E-01 -1.266 4.471 0.1722E-01 quartz 0.1920E-01 -1.717 1.153 0.062 95.20 0.4355 bornite 0.7926E-05 -5.101 0.3977E-02 -2.400 0.3283 0.7825E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity andalusite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.211444 g Volume = 0.453542 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 19 andalusite -12.38 -12.38 0.00 0.000 -0.28291E-10 144 quartz -0.90 -0.90 0.00 0.000 0.00000E+00 197 bornite -49.29 -49.29 0.00 0.000 0.28291E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.30 -0.297 0.11817E+04 3.034 2 CO2,gas -8.81 -10.14 -1.33 -0.443 0.52920E+04 2.001 3 CH4,gas 6.88 -3.50 -10.38 -2.595 0.41331E+05 -7.050 4 H2,gas 5.71 1.66 -4.05 -2.314 0.16125E+05 -0.719 5 H2S,gas -7.31 -9.56 -2.25 -1.123 0.89450E+04 1.084 6 CO,gas -2.96 -8.48 -5.51 -1.697 0.21958E+05 -2.184 7 SO3,gas -6.07 -16.20 -10.13 -2.532 0.40333E+05 -6.799 8 O2,gas 16.47 -3.32 -19.79 -13.194 0.78802E+05 -16.461 9 HCl,gas -5.48 -6.34 -0.86 -0.429 0.34150E+04 -0.858 10 acmite 4.08 2.06 -2.02 -0.210 0.80359E+04 12 akimotoite 5.84 1.49 -4.35 -0.870 0.17327E+05 13 akimotoite-Fe 3.84 -0.24 -4.08 -0.816 0.16240E+05 14 albite-high -4.22 -4.41 -0.18 -0.014 0.71793E+03 15 albite -4.19 -4.41 -0.22 -0.017 0.86494E+03 16 almandine -10.35 -12.19 -1.85 -0.092 0.73473E+04 17 pyrope -4.03 -7.00 -2.98 -0.149 0.11849E+05 18 analcite -2.54 -3.51 -0.97 -0.108 0.38766E+04 21 grossular -0.44 -5.35 -4.90 -0.245 0.19529E+05 22 anhydrite -13.05 -13.26 -0.21 -0.104 0.82918E+03 24 annite -0.58 -2.95 -2.37 -0.132 0.94315E+04 25 phlogopite 3.79 2.24 -1.55 -0.086 0.61789E+04 27 anorthite -9.93 -10.33 -0.40 -0.031 0.15954E+04 28 anthophyllite 13.93 9.54 -4.39 -0.119 0.17480E+05 29 anthophyllite-Fe 1.97 -2.57 -4.54 -0.123 0.18086E+05 30 apatite-OH -48.52 -48.68 -0.16 -0.012 0.63434E+03 31 apatite-OH-zs -46.45 -48.68 -2.23 -0.172 0.88817E+04 32 apatite-Cl-zs -51.92 -55.02 -3.10 -0.258 0.12326E+05 33 aragonite -3.78 -7.20 -3.42 -1.139 0.13602E+05 34 brucite 4.88 2.39 -2.49 -0.499 0.99281E+04 35 calcite -3.86 -7.20 -3.33 -1.111 0.13267E+05 36 carnegieite-low -0.81 -2.61 -1.80 -0.257 0.71757E+04 37 carnegieite-high -0.75 -2.61 -1.86 -0.266 0.74194E+04 38 carpholite-Mg -9.13 -10.89 -1.76 -0.118 0.70240E+04 39 carpholite-Fe -10.41 -12.62 -2.21 -0.147 0.87853E+04 40 celadonite -1.01 -3.43 -2.42 -0.142 0.96374E+04 41 celadonite-Fe -2.36 -5.16 -2.80 -0.165 0.11166E+05 42 chrysotile 8.70 5.37 -3.33 -0.278 0.13264E+05 44 clinochlore 0.34 -2.24 -2.58 -0.081 0.10281E+05 45 daphnite -6.37 -10.89 -4.52 -0.141 0.17988E+05 48 chloritoid-Mg -8.87 -9.99 -1.12 -0.074 0.44402E+04 49 chloritoid-Fe -10.70 -11.72 -1.02 -0.068 0.40536E+04 50 chloritoid-Mn -8.54 -10.39 -1.85 -0.124 0.73847E+04 52 coesite -0.63 -0.90 -0.27 -0.089 0.10691E+04 53 cordierite-H -22.14 -22.67 -0.53 -0.019 0.20956E+04 54 cordierite-Fe -24.42 -26.13 -1.71 -0.059 0.68006E+04 55 cordierite-Mn -20.01 -23.47 -3.46 -0.119 0.13789E+05 56 corundum -11.32 -11.48 -0.15 -0.014 0.61241E+03 58 cristobalite -0.84 -0.90 -0.06 -0.021 0.24549E+03 59 cummingtonite 13.98 9.54 -4.44 -0.120 0.17679E+05 61 cymrite-K -2.68 -4.92 -2.24 -0.187 0.89280E+04 63 diaspore -5.17 -5.74 -0.57 -0.095 0.22674E+04 65 diopside 5.33 3.53 -1.79 -0.179 0.71318E+04 66 hedenbergite 3.98 1.80 -2.17 -0.217 0.86497E+04 68 eastonite -9.17 -10.73 -1.56 -0.060 0.61942E+04 69 enstatite 4.45 2.98 -1.47 -0.147 0.58337E+04 70 clinoenstatite-HiP 4.92 2.98 -1.94 -0.194 0.77061E+04 71 clinoenstatite 4.44 2.98 -1.45 -0.145 0.57915E+04 72 protoenstatite 4.58 2.98 -1.60 -0.160 0.63591E+04 73 epidote -6.20 -8.46 -2.26 -0.110 0.90061E+04 74 clinozoisite -11.88 -14.03 -2.15 -0.098 0.85614E+04 75 epidote-Fe 1.13 -2.90 -4.02 -0.209 0.16022E+05 76 fayalite 1.88 0.42 -1.46 -0.208 0.57958E+04 77 ferrosilite 1.06 -0.48 -1.53 -0.153 0.61072E+04 78 forsterite 5.68 3.88 -1.80 -0.257 0.71508E+04 79 gedrite -13.74 -16.40 -2.66 -0.072 0.10582E+05 81 gibbsite -3.63 -5.74 -2.12 -0.302 0.84293E+04 82 glaucophane 0.63 -3.44 -4.07 -0.110 0.16217E+05 84 goethite 0.91 -0.17 -1.08 -0.233 0.42943E+04 86 greenalite 4.12 0.18 -3.94 -0.328 0.15690E+05 88 halite -0.19 -2.31 -2.13 -1.063 0.84641E+04 89 hematite 0.34 -0.34 -0.69 -0.084 0.27440E+04 90 heulandite -12.37 -14.83 -2.46 -0.112 0.97938E+04 91 hercynite -9.96 -10.82 -0.86 -0.058 0.34375E+04 94 jadeite -1.87 -3.51 -1.63 -0.163 0.65050E+04 96 kalsilite -1.46 -3.13 -1.67 -0.238 0.66399E+04 97 kaolinite -11.06 -13.28 -2.22 -0.202 0.88466E+04 98 kyanite -12.24 -12.38 -0.13 -0.013 0.51975E+03 100 laumontite -9.05 -12.14 -3.09 -0.206 0.12289E+05 101 lawsonite -7.35 -10.34 -2.99 -0.199 0.11911E+05 102 leucite -2.99 -4.02 -1.03 -0.103 0.41161E+04 104 lizardite 8.89 5.37 -3.53 -0.294 0.14051E+05 105 magnesite -4.85 -7.75 -2.90 -0.967 0.11551E+05 106 magnetite 1.21 0.31 -0.90 -0.073 0.35712E+04 107 minnesotaite 1.11 -1.62 -2.72 -0.160 0.10849E+05 108 minnesotaite-Mg 6.78 3.57 -3.21 -0.189 0.12774E+05 109 magnesioferrite 4.15 2.04 -2.10 -0.172 0.83735E+04 111 manganosite 4.98 1.98 -3.00 -0.749 0.11934E+05 112 margarite -20.83 -21.81 -0.99 -0.039 0.39222E+04 115 microcline -4.79 -4.92 -0.13 -0.010 0.53746E+03 116 monticellite 8.34 4.43 -3.91 -0.559 0.15574E+05 118 mullite-Si -11.68 -12.38 -0.70 -0.070 0.27812E+04 119 muscovite -16.02 -16.40 -0.38 -0.022 0.14971E+04 120 paragonite -15.34 -15.89 -0.55 -0.032 0.21823E+04 121 nepheline -1.10 -2.61 -1.51 -0.216 0.60282E+04 122 osumilite(2) -13.81 -16.41 -2.60 -0.054 0.10366E+05 123 osumilite-Fe -30.70 -32.84 -2.14 -0.045 0.85184E+04 124 pargasite 1.80 -3.14 -4.95 -0.130 0.19696E+05 125 periclase 5.08 2.39 -2.69 -0.673 0.10723E+05 126 periclase-Fe 2.61 0.66 -1.95 -0.488 0.77768E+04 127 perovskite-Al -9.65 -11.48 -1.82 -0.166 0.72624E+04 132 phlogopite-Na 4.67 2.76 -1.91 -0.106 0.76063E+04 134 prehnite -5.24 -8.29 -3.06 -0.180 0.12166E+05 135 prehnite-Fe 0.84 -2.72 -3.57 -0.215 0.14204E+05 138 px-Mg-tschermaks -8.31 -9.99 -1.67 -0.120 0.66632E+04 139 px-Ca-tschermaks -7.25 -9.43 -2.18 -0.156 0.86953E+04 140 pyrite -19.77 -20.11 -0.34 -0.080 0.13535E+04 141 pyrrhotite -7.99 -8.90 -0.91 -0.303 0.36158E+04 142 pyrrhotiteFe0.875 -8.68 -9.18 -0.51 -0.186 0.20123E+04 143 pyrophyllite -14.24 -15.07 -0.83 -0.052 0.33087E+04 146 riebeckite 7.08 2.50 -4.58 -0.126 0.18217E+05 147 ringwoodite-Fe 2.84 0.42 -2.42 -0.346 0.96338E+04 148 ringwoodite-Mg 8.72 3.88 -4.84 -0.691 0.19266E+05 149 rhodochrosite -4.68 -8.15 -3.48 -1.158 0.13838E+05 150 rhodonite 2.51 1.09 -1.42 -0.284 0.56589E+04 151 sanidine -4.27 -4.92 -0.65 -0.050 0.26025E+04 152 sapphirine(351) -47.10 -51.12 -4.02 -0.061 0.16008E+05 153 siderite -6.58 -9.48 -2.90 -0.966 0.11534E+05 154 sillimanite -12.35 -12.38 -0.02 -0.002 0.87178E+02 156 spinel -7.88 -9.09 -1.21 -0.081 0.48178E+04 158 staurolite-Fe -104.38 -107.40 -3.02 -0.028 0.12031E+05 159 staurolite-Mg -96.35 -100.48 -4.14 -0.038 0.16467E+05 163 stilpnomelane-Mg -1.78 -4.98 -3.20 -0.095 0.12727E+05 164 stishovite 1.93 -0.90 -2.83 -0.944 0.11273E+05 165 sudoite-Fe -20.89 -24.34 -3.45 -0.111 0.13742E+05 166 sudoite -18.79 -20.88 -2.09 -0.067 0.83189E+04 167 sulfur -9.74 -11.21 -1.47 -0.453 0.58621E+04 168 sylvite -0.11 -2.83 -2.72 -1.361 0.10839E+05 169 talc 5.09 3.57 -1.51 -0.089 0.60231E+04 170 talc-Fe 2.43 -1.62 -4.05 -0.238 0.16117E+05 171 talc-tschermaks -7.60 -9.40 -1.80 -0.106 0.71506E+04 173 tephroite 6.20 3.07 -3.12 -0.446 0.12442E+05 176 topaz-H -10.37 -12.38 -2.00 -0.182 0.79818E+04 177 tremolite 15.12 10.64 -4.48 -0.121 0.17841E+05 179 troilite-low -7.89 -8.90 -1.01 -0.336 0.40120E+04 180 tschermakite -11.77 -15.30 -3.53 -0.095 0.14049E+05 183 wadsleyite-Fe 2.69 0.42 -2.27 -0.324 0.90250E+04 184 wadsleyite-Mg 7.80 3.88 -3.92 -0.560 0.15615E+05 185 wairakite -10.72 -12.13 -1.41 -0.083 0.56155E+04 186 walstromite 4.64 2.04 -2.59 -0.519 0.10328E+05 187 wollastonite 4.25 2.04 -2.20 -0.441 0.87726E+04 188 pseudo-wollastonite 4.35 2.04 -2.31 -0.462 0.91944E+04 189 zoisite -11.94 -14.03 -2.08 -0.095 0.83016E+04 192 beidellite-Ca -15.07 -16.18 -1.11 -0.069 0.44264E+04 193 beidellite-H -15.07 -16.67 -1.60 -0.102 0.63537E+04 194 beidellite-K -14.00 -15.51 -1.50 -0.092 0.59913E+04 195 beidellite-Mg -15.40 -16.27 -0.88 -0.054 0.34925E+04 196 beidellite-Na -13.94 -15.34 -1.40 -0.086 0.55768E+04 199 chalcocite -12.72 -13.91 -1.19 -0.299 0.47555E+04 200 covellite -11.30 -12.56 -1.26 -0.481 0.50270E+04 202 montmorillonite-Ca -10.93 -11.90 -0.98 -0.060 0.38842E+04 203 montmorillonite-K -10.16 -11.23 -1.07 -0.066 0.42655E+04 204 montmorillonite-Mg -11.17 -11.99 -0.82 -0.051 0.32676E+04 205 montmorillonite-Na -9.78 -11.06 -1.28 -0.078 0.51038E+04 206 nontronite-Ca -3.18 -5.05 -1.87 -0.121 0.74287E+04 207 nontronite-H -3.19 -5.53 -2.34 -0.157 0.93237E+04 208 nontronite-K -2.12 -4.38 -2.26 -0.145 0.89852E+04 209 nontronite-Mg -3.44 -5.14 -1.70 -0.110 0.67533E+04 210 nontronite-Na -2.05 -4.21 -2.16 -0.138 0.85817E+04 215 gypsum -10.99 -13.26 -2.28 -0.569 0.90661E+04 232 alabandite -5.71 -7.57 -1.86 -0.619 0.73958E+04 234 anglesite -13.16 -15.93 -2.77 -1.386 0.11041E+05 237 barite -14.04 -14.26 -0.22 -0.109 0.87000E+03 238 boehmite -4.90 -5.74 -0.84 -0.140 0.33559E+04 240 chalcopyrite -21.28 -21.46 -0.18 -0.033 0.70819E+03 242 copper,native 1.82 -1.35 -3.17 -1.102 0.12609E+05 244 ferrous-oxide 1.71 0.66 -1.05 -0.263 0.41830E+04 245 galena -8.70 -9.29 -0.59 -0.195 0.23325E+04 246 silver,native 0.59 -3.78 -4.37 -1.519 0.17390E+05 248 litharge 5.21 0.27 -4.94 -1.236 0.19684E+05 255 sphalerite -10.10 -10.50 -0.40 -0.132 0.15802E+04 256 wurtzite -9.33 -10.50 -1.17 -0.391 0.46654E+04 257 zincite 1.87 -0.95 -2.82 -0.704 0.11220E+05 258 an20ab80 -5.55 -5.59 -0.04 -0.003 0.14582E+03 259 an25ab75 -5.87 -5.89 -0.02 -0.001 0.75484E+02 260 an30ab70 -6.18 -6.18 -0.01 -0.001 0.29517E+02 261 tr.625ac.25prg.125 9.37 6.76 -2.62 -0.070 0.10418E+05 Calculations done for 597.0000 Deg. C; 2140.0000 bar Temperature changed by -1.000 degrees to 596.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 500 Temperature = 596.00 C Pressure = 2060.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5500E+02 kg liquid = 0.9909E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9946 Stoichiometric ionic strength = .3312504E+01 Osmotic coef. = 0.0000 True ionic strength = .2827278E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18536E-04 -4.7320 0.55796E-05 -5.2534 0.30102E+00 -0.5214 2 H2O 0.99457E+00 -0.0024 0.99457E+00 -0.0024 3 Cl- 0.24004E+00 -0.6197 0.68812E-01 -1.1623 0.28667E+00 -0.5426 4 SO4-- 0.14168E-03 -3.8487 0.15455E-05 -5.8109 0.10908E-01 -1.9622 5 HCO3- 0.35103E-04 -4.4547 0.10785E-04 -4.9672 0.30724E+00 -0.5125 6 HS- 0.15058E-03 -3.8222 0.43502E-04 -4.3615 0.28890E+00 -0.5393 7 H4SiO4 0.12048E+00 -0.9191 0.12048E+00 -0.9191 0.10000E+01 0.0000 8 Al+++ 0.10638E-16 -16.9731 0.31449E-21 -21.5024 0.29561E-04 -4.5293 9 Ca++ 0.34711E-05 -5.4595 0.31202E-07 -7.5058 0.89891E-02 -2.0463 10 Mg++ 0.11856E-05 -5.9261 0.89016E-08 -8.0505 0.75080E-02 -2.1245 11 Fe++ 0.20215E-07 -7.6943 0.15890E-09 -9.7989 0.78608E-02 -2.1045 12 K+ 0.61848E-01 -1.2087 0.19459E-01 -1.7109 0.31462E+00 -0.5022 13 Na+ 0.21828E+00 -0.6610 0.63351E-01 -1.1982 0.29023E+00 -0.5373 14 Mn++ 0.43261E-06 -6.3639 0.35162E-08 -8.4539 0.81280E-02 -2.0900 15 Zn++ 0.50733E-09 -9.2947 0.39880E-11 -11.3992 0.78608E-02 -2.1045 16 Cu+ 0.12100E-06 -6.9172 0.35031E-07 -7.4555 0.28951E+00 -0.5383 17 Pb++ 0.62149E-08 -8.2066 0.61949E-10 -10.2080 0.99678E-02 -2.0014 18 Ag+ 0.47758E-09 -9.3210 0.14809E-09 -9.8295 0.31010E+00 -0.5085 19 Ba++ 0.29469E-06 -6.5306 0.31343E-08 -8.5039 0.10636E-01 -1.9732 20 HPO4-- 0.16481E-08 -8.7830 0.18060E-10 -10.7433 0.10958E-01 -1.9603 21 HSiO3- 0.24712E-05 -5.6071 0.70841E-06 -6.1497 0.28667E+00 -0.5426 22 Ca(HSiO3)+ 0.19545E-07 -7.7090 0.61988E-08 -8.2077 0.31716E+00 -0.4987 23 Mg(HSiO3)+ 0.13707E-08 -8.8631 0.43473E-09 -9.3618 0.31716E+00 -0.4987 24 NaHSiO3,aq 0.12263E-05 -5.9114 0.12263E-05 -5.9114 0.10000E+01 0.0000 28 AgCl,aq 0.67274E-07 -7.1722 0.67274E-07 -7.1722 0.10000E+01 0.0000 29 AgCl2- 0.49541E-05 -5.3050 0.14202E-05 -5.8477 0.28667E+00 -0.5426 30 AgCl3-2 0.26486E-05 -5.5770 0.26938E-07 -7.5696 0.10171E-01 -1.9926 31 AgCl4-3 0.11069E-05 -5.9559 0.28379E-10 -10.5470 0.25639E-04 -4.5911 34 Ag(HS),aq 0.45555E-09 -9.3415 0.45555E-09 -9.3415 0.10000E+01 0.0000 35 Ag(HS)2- 0.27162E-08 -8.5660 0.77865E-09 -9.1087 0.28667E+00 -0.5426 36 AlO+ 0.18497E-10 -10.7329 0.58666E-11 -11.2316 0.31716E+00 -0.4987 38 HAlO2,aq 0.57141E-08 -8.2430 0.57141E-08 -8.2430 0.10000E+01 0.0000 39 AlO2- 0.26374E-04 -4.5788 0.66679E-05 -5.1760 0.25282E+00 -0.5972 41 Ba(HCO3)+ 0.15044E-05 -5.8226 0.49473E-06 -6.3056 0.32886E+00 -0.4830 42 BaCl+ 0.54080E-04 -4.2670 0.17152E-04 -4.7657 0.31716E+00 -0.4987 43 CH4,aq 0.21557E-08 -8.6664 0.26358E-08 -8.5791 0.12228E+01 0.0873 48 CO,aq 0.93706E-03 -3.0282 0.93706E-03 -3.0282 0.10000E+01 0.0000 49 CO2,aq 0.26795E+01 0.4280 0.32763E+01 0.5154 0.12228E+01 0.0873 50 CO3-2 0.57478E-10 -10.2405 0.58459E-12 -12.2332 0.10171E-01 -1.9926 51 CaCO3,aq 0.19536E-10 -10.7092 0.19536E-10 -10.7092 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.11483E-05 -5.9399 0.36420E-06 -6.4387 0.31716E+00 -0.4987 53 CaCl+ 0.36221E-03 -3.4410 0.11488E-03 -3.9398 0.31716E+00 -0.4987 54 CaCl2,aq 0.16531E-03 -3.7817 0.16531E-03 -3.7817 0.10000E+01 0.0000 55 CaOH+ 0.47234E-06 -6.3257 0.14981E-06 -6.8245 0.31716E+00 -0.4987 56 CaSO4,aq 0.10364E-06 -6.9845 0.10364E-06 -6.9845 0.10000E+01 0.0000 57 HCl,aq 0.10355E-02 -2.9849 0.10355E-02 -2.9849 0.10000E+01 0.0000 66 CuCl,aq 0.65647E-04 -4.1828 0.65647E-04 -4.1828 0.10000E+01 0.0000 67 CuCl2- 0.25953E-03 -3.5858 0.74397E-04 -4.1284 0.28667E+00 -0.5426 68 CuCl3-2 0.71725E-05 -5.1443 0.72950E-07 -7.1370 0.10171E-01 -1.9926 74 FeCl+ 0.66092E-06 -6.1799 0.20962E-06 -6.6786 0.31716E+00 -0.4987 75 FeCl2,aq 0.88321E-02 -2.0539 0.88321E-02 -2.0539 0.10000E+01 0.0000 77 FeO,aq 0.54420E-07 -7.2642 0.54420E-07 -7.2642 0.10000E+01 0.0000 78 FeOH+ 0.43928E-07 -7.3573 0.13932E-07 -7.8560 0.31716E+00 -0.4987 79 HFeO2- 0.82737E-08 -8.0823 0.23718E-08 -8.6249 0.28667E+00 -0.5426 82 FeO2- 0.45735E-08 -8.3398 0.13111E-08 -8.8824 0.28667E+00 -0.5426 83 HFeO2,aq 0.13879E-09 -9.8576 0.13879E-09 -9.8576 0.10000E+01 0.0000 84 H2,aq 0.43614E-02 -2.3604 0.53329E-02 -2.2730 0.12228E+01 0.0873 85 KCl,aq 0.49950E-01 -1.3015 0.49950E-01 -1.3015 0.10000E+01 0.0000 86 KHSO4,aq 0.11862E-01 -1.9258 0.11862E-01 -1.9258 0.10000E+01 0.0000 87 KOH,aq 0.76166E-06 -6.1182 0.76166E-06 -6.1182 0.10000E+01 0.0000 88 KSO4- 0.28966E-02 -2.5381 0.83037E-03 -3.0807 0.28667E+00 -0.5426 90 Mg(HCO3)+ 0.14403E-06 -6.8415 0.45681E-07 -7.3403 0.31716E+00 -0.4987 91 MgCl+ 0.18984E-04 -4.7216 0.60211E-05 -5.2203 0.31716E+00 -0.4987 92 MgOH+ 0.55068E-06 -6.2591 0.17465E-06 -6.7578 0.31716E+00 -0.4987 94 MnO,aq 0.17679E-07 -7.7526 0.17679E-07 -7.7526 0.10000E+01 0.0000 95 MnOH+ 0.12305E-06 -6.9099 0.39026E-07 -7.4086 0.31716E+00 -0.4987 97 HMnO2- 0.12975E-10 -10.8869 0.37195E-11 -11.4295 0.28667E+00 -0.5426 100 MnCl+ 0.11594E-02 -2.9358 0.36773E-03 -3.4345 0.31716E+00 -0.4987 101 MnSO4,aq 0.14989E-07 -7.8242 0.14989E-07 -7.8242 0.10000E+01 0.0000 102 NaCl,aq 0.34140E+00 -0.4667 0.34140E+00 -0.4667 0.10000E+01 0.0000 103 NaOH,aq 0.11301E-05 -5.9469 0.11301E-05 -5.9469 0.10000E+01 0.0000 105 OH- 0.98695E-05 -5.0057 0.24952E-05 -5.6029 0.25282E+00 -0.5972 110 HPO3-2 0.32697E-10 -10.4855 0.33255E-12 -12.4781 0.10171E-01 -1.9926 111 H3PO3,aq 0.27079E-09 -9.5674 0.27079E-09 -9.5674 0.10000E+01 0.0000 112 H2PO3- 0.13125E-07 -7.8819 0.37625E-08 -8.4245 0.28667E+00 -0.5426 113 H3PO4,aq 0.16232E-05 -5.7896 0.16232E-05 -5.7896 0.10000E+01 0.0000 114 H2PO4- 0.39910E-05 -5.3989 0.11989E-05 -5.9212 0.30039E+00 -0.5223 116 H4P2O7,aq 0.21284E-09 -9.6719 0.21284E-09 -9.6719 0.10000E+01 0.0000 117 H3P2O7- 0.56984E-08 -8.2442 0.16335E-08 -8.7869 0.28667E+00 -0.5426 118 H2P2O7-2 0.14717E-05 -5.8322 0.14969E-07 -7.8248 0.10171E-01 -1.9926 119 HP2O7-3 0.30655E-07 -7.5135 0.78595E-12 -12.1046 0.25639E-04 -4.5911 121 PbCl+ 0.36171E-05 -5.4416 0.11472E-05 -5.9404 0.31716E+00 -0.4987 122 PbCl2,aq 0.10051E-03 -3.9978 0.10051E-03 -3.9978 0.10000E+01 0.0000 123 PbCl3- 0.11960E-03 -3.9223 0.34284E-04 -4.4649 0.28667E+00 -0.5426 124 PbCl4-2 0.32360E-04 -4.4900 0.32913E-06 -6.4826 0.10171E-01 -1.9926 125 PbO,aq 0.26457E-08 -8.5775 0.26457E-08 -8.5775 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.81366E-04 -4.0896 0.81366E-04 -4.0896 0.10000E+01 0.0000 128 Pb(HS)3- 0.58300E-05 -5.2343 0.16713E-05 -5.7770 0.28667E+00 -0.5426 129 H2S,aq 0.10397E+01 0.0169 0.12713E+01 0.1043 0.12228E+01 0.0873 130 S2-2 0.13702E-07 -7.8632 0.13936E-09 -9.8559 0.10171E-01 -1.9926 131 S3-2 0.15313E-08 -8.8150 0.15574E-10 -10.8076 0.10171E-01 -1.9926 132 S3- 0.24726E-01 -1.6068 0.70882E-02 -2.1495 0.28667E+00 -0.5426 133 S4-2 0.14135E-09 -9.8497 0.14376E-11 -11.8424 0.10171E-01 -1.9926 134 S5-2 0.10941E-10 -10.9610 0.11128E-12 -12.9536 0.10171E-01 -1.9926 135 SO2,aq 0.28196E+00 -0.5498 0.28196E+00 -0.5498 0.10000E+01 0.0000 136 SO3-2 0.57835E-09 -9.2378 0.88799E-11 -11.0516 0.15354E-01 -1.8138 137 HSO3- 0.48054E-03 -3.3183 0.13775E-03 -3.8609 0.28667E+00 -0.5426 138 HSO4- 0.13165E-01 -1.8806 0.42742E-02 -2.3691 0.32467E+00 -0.4886 140 S2O3-2 0.46734E-06 -6.3304 0.47532E-08 -8.3230 0.10171E-01 -1.9926 141 HS2O3- 0.86539E-06 -6.0628 0.24808E-06 -6.6054 0.28667E+00 -0.5426 142 H2S2O3,aq 0.24956E-07 -7.6028 0.24956E-07 -7.6028 0.10000E+01 0.0000 150 S4O6-2 0.73611E-09 -9.1331 0.74868E-11 -11.1257 0.10171E-01 -1.9926 152 ZnCl+ 0.77483E-03 -3.1108 0.24575E-03 -3.6095 0.31716E+00 -0.4987 153 ZnCl2,aq 0.13172E-02 -2.8804 0.13172E-02 -2.8804 0.10000E+01 0.0000 154 ZnCl3- 0.22521E-03 -3.6474 0.64560E-04 -4.1900 0.28667E+00 -0.5426 155 ZnO,aq 0.24582E-07 -7.6094 0.24582E-07 -7.6094 0.10000E+01 0.0000 156 ZnOH+ 0.31467E-05 -5.5021 0.99801E-06 -6.0009 0.31716E+00 -0.4987 158 HZnO2- 0.23386E-09 -9.6310 0.67039E-10 -10.1737 0.28667E+00 -0.5426 Charge balance for all species = 0.2554E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1853564E-04 0.4303460E+01 0.3526117E+04 0.0000 2 H2O 0.1000000E+01 0.5248850E+02 0.7686878E+06 0.0000 3 Cl- 0.2400440E+00 0.6574265E+00 0.1894718E+05 4.0911 4 SO4-- 0.1416841E-03 0.2540262E+00 0.1983685E+05 4.6959 5 HCO3- 0.3510252E-04 0.2680437E+01 0.1329542E+06 0.2862 6 HS- 0.1505768E-03 0.1170714E+01 0.3147425E+05 0.8919 7 H4SiO4 0.1204817E+00 0.1204854E+00 0.9413950E+04 -0.9191 8 Al+++ 0.1063849E-16 0.2637967E-04 0.5786017E+00 -5.7422 9 Ca++ 0.3471123E-05 0.5327443E-03 0.1735678E+02 3.0010 10 Mg++ 0.1185608E-05 0.2086600E-04 0.4123863E+00 2.4563 11 Fe++ 0.2021473E-07 0.8832876E-02 0.4010018E+03 0.7079 12 K+ 0.6184841E-01 0.1265586E+00 0.4022860E+04 3.5425 13 Na+ 0.2182755E+00 0.5596782E+00 0.1045967E+05 4.0551 14 Mn++ 0.4326067E-06 0.1160027E-02 0.5180661E+02 2.0529 15 Zn++ 0.5073269E-09 0.2320391E-02 0.1233059E+03 -0.8925 16 Cu+ 0.1209994E-06 0.3324661E-03 0.1717271E+02 -2.2022 17 Pb++ 0.6214919E-08 0.3432878E-03 0.5781913E+02 0.2988 18 Ag+ 0.4775754E-09 0.8780522E-05 0.7699549E+00 -4.5761 19 Ba++ 0.2946898E-06 0.5587954E-04 0.6238701E+01 2.0029 20 HPO4-- 0.1648072E-08 0.8645959E-05 0.6745804E+00 -0.2365 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4264408E+01 -.2045540E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5201219E+02 -.4740888E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517210E+00 0.1754015E-05 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160090E+01 0.5437446E-04 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1193921E+00 0.2420223E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2614028E-04 0.6683992E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.5279099E-03 0.0000000E+00 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8752722E-02 0.1403212E-04 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3294491E-03 0.7016059E-04 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4337E-18 Mass of aqueous solution: 0.121898E+04 g Temperature = 596.00 C Pressure = 2060.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) andalusite 0.3342E-03 -3.476 0.5416E-01 -1.266 3.622 0.1722E-01 quartz 0.2387E-01 -1.622 1.434 0.157 95.91 0.5415 bornite 0.1403E-04 -4.853 0.7041E-02 -2.152 0.4709 0.1385E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity andalusite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.495190 g Volume = 0.560143 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 19 andalusite -12.41 -12.41 0.00 0.000 0.00000E+00 144 quartz -0.91 -0.91 0.00 0.000 0.00000E+00 197 bornite -49.60 -49.60 0.00 0.000 -0.28259E-10 30 apatite-OH -48.93 -48.75 0.18 0.014 -0.71433E+03 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.30 -0.296 0.11757E+04 3.018 2 CO2,gas -8.87 -10.22 -1.35 -0.451 0.53751E+04 1.962 3 CH4,gas 6.89 -3.52 -10.41 -2.603 0.41413E+05 -7.099 4 H2,gas 5.72 1.67 -4.05 -2.312 0.16094E+05 -0.733 5 H2S,gas -7.36 -9.61 -2.25 -1.126 0.89583E+04 1.061 6 CO,gas -3.00 -8.54 -5.54 -1.704 0.22023E+05 -2.224 7 SO3,gas -6.16 -16.32 -10.15 -2.538 0.40382E+05 -6.840 8 O2,gas 16.46 -3.35 -19.81 -13.208 0.78797E+05 -16.499 9 HCl,gas -5.52 -6.42 -0.90 -0.450 0.35819E+04 -0.901 10 acmite 4.03 2.09 -1.94 -0.201 0.76988E+04 12 akimotoite 5.83 1.54 -4.29 -0.858 0.17055E+05 13 akimotoite-Fe 3.82 -0.21 -4.03 -0.806 0.16033E+05 14 albite-high -4.29 -4.43 -0.15 -0.011 0.57998E+03 15 albite -4.25 -4.43 -0.18 -0.014 0.72432E+03 16 almandine -10.43 -12.12 -1.69 -0.085 0.67235E+04 17 pyrope -4.10 -6.87 -2.77 -0.139 0.11033E+05 18 analcite -2.58 -3.52 -0.94 -0.105 0.37528E+04 21 grossular -0.52 -5.24 -4.72 -0.236 0.18752E+05 22 anhydrite -13.17 -13.32 -0.15 -0.074 0.59137E+03 24 annite -0.66 -2.83 -2.18 -0.121 0.86552E+04 25 phlogopite 3.72 2.41 -1.31 -0.073 0.52112E+04 27 anorthite -9.99 -10.32 -0.33 -0.025 0.13129E+04 28 anthophyllite 13.76 9.86 -3.90 -0.105 0.15521E+05 29 anthophyllite-Fe 1.79 -2.38 -4.16 -0.113 0.16560E+05 31 apatite-OH-zs -46.85 -48.75 -1.90 -0.146 0.75383E+04 32 apatite-Cl-zs -52.38 -55.16 -2.78 -0.232 0.11060E+05 33 aragonite -3.84 -7.22 -3.38 -1.125 0.13426E+05 34 brucite 4.88 2.45 -2.43 -0.486 0.96630E+04 35 calcite -3.93 -7.22 -3.29 -1.097 0.13087E+05 36 carnegieite-low -0.84 -2.61 -1.77 -0.253 0.70353E+04 37 carnegieite-high -0.78 -2.61 -1.83 -0.261 0.72799E+04 38 carpholite-Mg -9.17 -10.87 -1.71 -0.114 0.67823E+04 39 carpholite-Fe -10.45 -12.62 -2.16 -0.144 0.86079E+04 40 celadonite -1.08 -3.41 -2.33 -0.137 0.92531E+04 41 celadonite-Fe -2.43 -5.16 -2.73 -0.160 0.10849E+05 42 chrysotile 8.66 5.53 -3.13 -0.261 0.12439E+05 44 clinochlore 0.27 -1.97 -2.24 -0.070 0.89123E+04 45 daphnite -6.46 -10.72 -4.26 -0.133 0.16944E+05 48 chloritoid-Mg -8.90 -9.95 -1.05 -0.070 0.41825E+04 49 chloritoid-Fe -10.73 -11.70 -0.97 -0.065 0.38569E+04 50 chloritoid-Mn -8.57 -10.36 -1.79 -0.119 0.71122E+04 52 coesite -0.64 -0.91 -0.27 -0.090 0.10722E+04 53 cordierite-H -22.27 -22.65 -0.38 -0.014 0.15116E+04 54 cordierite-Fe -24.56 -26.14 -1.58 -0.055 0.62895E+04 55 cordierite-Mn -20.15 -23.45 -3.30 -0.114 0.13125E+05 56 corundum -11.34 -11.49 -0.16 -0.014 0.61870E+03 58 cristobalite -0.85 -0.91 -0.06 -0.020 0.23765E+03 59 cummingtonite 13.81 9.86 -3.95 -0.107 0.15724E+05 61 cymrite-K -2.73 -4.95 -2.22 -0.185 0.88238E+04 63 diaspore -5.17 -5.75 -0.57 -0.096 0.22795E+04 65 diopside 5.28 3.62 -1.66 -0.166 0.65906E+04 66 hedenbergite 3.93 1.88 -2.05 -0.205 0.81724E+04 68 eastonite -9.23 -10.62 -1.38 -0.053 0.55068E+04 69 enstatite 4.41 3.08 -1.33 -0.133 0.52754E+04 70 clinoenstatite-HiP 4.88 3.08 -1.80 -0.180 0.71501E+04 71 clinoenstatite 4.39 3.08 -1.32 -0.132 0.52324E+04 72 protoenstatite 4.54 3.08 -1.46 -0.146 0.57974E+04 73 epidote -6.29 -8.37 -2.08 -0.101 0.82775E+04 74 clinozoisite -11.96 -13.98 -2.03 -0.092 0.80570E+04 75 epidote-Fe 1.03 -2.76 -3.79 -0.197 0.15067E+05 76 fayalite 1.84 0.50 -1.35 -0.192 0.53580E+04 77 ferrosilite 1.01 -0.42 -1.43 -0.143 0.56744E+04 78 forsterite 5.65 3.99 -1.66 -0.237 0.65852E+04 79 gedrite -13.89 -16.20 -2.31 -0.062 0.91925E+04 81 gibbsite -3.62 -5.75 -2.13 -0.304 0.84613E+04 82 glaucophane 0.47 -3.34 -3.81 -0.103 0.15145E+05 84 goethite 0.89 -0.13 -1.03 -0.222 0.40849E+04 86 greenalite 4.07 0.28 -3.78 -0.315 0.15042E+05 87 grunerite 2.30 -2.38 -4.68 -0.127 0.18618E+05 88 halite -0.24 -2.36 -2.12 -1.059 0.84198E+04 89 hematite 0.31 -0.26 -0.58 -0.070 0.23036E+04 90 heulandite -12.49 -14.91 -2.42 -0.110 0.96103E+04 91 hercynite -9.98 -10.79 -0.81 -0.054 0.32200E+04 94 jadeite -1.91 -3.52 -1.61 -0.161 0.63914E+04 96 kalsilite -1.48 -3.12 -1.64 -0.234 0.65039E+04 97 kaolinite -11.09 -13.32 -2.23 -0.203 0.88714E+04 98 kyanite -12.27 -12.41 -0.13 -0.013 0.53169E+03 100 laumontite -9.12 -12.16 -3.04 -0.202 0.12078E+05 101 lawsonite -7.38 -10.33 -2.94 -0.196 0.11702E+05 102 leucite -3.03 -4.03 -1.00 -0.100 0.39737E+04 104 lizardite 8.85 5.53 -3.32 -0.277 0.13223E+05 105 magnesite -4.91 -7.76 -2.86 -0.952 0.11359E+05 106 magnetite 1.17 0.44 -0.73 -0.060 0.29092E+04 107 minnesotaite 1.02 -1.54 -2.56 -0.151 0.10187E+05 108 minnesotaite-Mg 6.70 3.70 -3.00 -0.176 0.11923E+05 109 magnesioferrite 4.11 2.19 -1.92 -0.157 0.76458E+04 111 manganosite 4.98 2.05 -2.93 -0.732 0.11639E+05 112 margarite -20.89 -21.82 -0.92 -0.037 0.36753E+04 115 microcline -4.85 -4.95 -0.10 -0.008 0.39297E+03 116 monticellite 8.31 4.54 -3.78 -0.539 0.15019E+05 118 mullite-Si -11.71 -12.41 -0.70 -0.070 0.27863E+04 119 muscovite -16.09 -16.44 -0.35 -0.021 0.13895E+04 120 paragonite -15.41 -15.93 -0.52 -0.031 0.20764E+04 121 nepheline -1.13 -2.61 -1.48 -0.212 0.58895E+04 122 osumilite(2) -14.05 -16.39 -2.34 -0.049 0.93205E+04 123 osumilite-Fe -30.94 -32.92 -1.98 -0.041 0.78798E+04 124 pargasite 1.65 -2.86 -4.51 -0.119 0.17940E+05 125 periclase 5.08 2.45 -2.62 -0.656 0.10439E+05 126 periclase-Fe 2.61 0.71 -1.90 -0.475 0.75588E+04 127 perovskite-Al -9.66 -11.49 -1.83 -0.166 0.72687E+04 132 phlogopite-Na 4.59 2.92 -1.67 -0.093 0.66363E+04 134 prehnite -5.31 -8.24 -2.93 -0.172 0.11649E+05 135 prehnite-Fe 0.76 -2.63 -3.38 -0.204 0.13456E+05 138 px-Mg-tschermaks -8.35 -9.95 -1.61 -0.115 0.63866E+04 139 px-Ca-tschermaks -7.29 -9.41 -2.12 -0.152 0.84355E+04 140 pyrite -19.90 -20.20 -0.29 -0.068 0.11552E+04 141 pyrrhotite -8.05 -8.91 -0.86 -0.285 0.34019E+04 142 pyrrhotiteFe0.875 -8.74 -9.20 -0.46 -0.169 0.18275E+04 143 pyrophyllite -14.31 -15.15 -0.84 -0.052 0.33299E+04 146 riebeckite 6.89 2.64 -4.25 -0.117 0.16886E+05 147 ringwoodite-Fe 2.81 0.50 -2.31 -0.331 0.92013E+04 148 ringwoodite-Mg 8.70 3.99 -4.70 -0.672 0.18706E+05 149 rhodochrosite -4.74 -8.17 -3.43 -1.143 0.13633E+05 150 rhodonite 2.49 1.14 -1.35 -0.270 0.53651E+04 151 sanidine -4.33 -4.95 -0.62 -0.048 0.24581E+04 152 sapphirine(351) -47.20 -51.01 -3.82 -0.058 0.15173E+05 153 siderite -6.64 -9.51 -2.87 -0.956 0.11405E+05 154 sillimanite -12.38 -12.41 -0.02 -0.002 0.90384E+02 156 spinel -7.90 -9.04 -1.14 -0.076 0.45352E+04 158 staurolite-Fe -104.63 -107.46 -2.83 -0.026 0.11273E+05 159 staurolite-Mg -96.58 -100.47 -3.89 -0.036 0.15461E+05 163 stilpnomelane-Mg -1.93 -4.78 -2.86 -0.085 0.11357E+05 164 stishovite 1.92 -0.91 -2.84 -0.946 0.11286E+05 165 sudoite-Fe -20.96 -24.32 -3.37 -0.109 0.13390E+05 166 sudoite -18.86 -20.83 -1.97 -0.064 0.78360E+04 167 sulfur -9.81 -11.29 -1.48 -0.454 0.58705E+04 168 sylvite -0.16 -2.87 -2.71 -1.356 0.10787E+05 169 talc 5.01 3.70 -1.30 -0.077 0.51827E+04 170 talc-Fe 2.35 -1.54 -3.89 -0.229 0.15467E+05 171 talc-tschermaks -7.67 -9.33 -1.66 -0.097 0.65916E+04 173 tephroite 6.17 3.19 -2.98 -0.426 0.11851E+05 176 topaz-H -10.39 -12.41 -2.01 -0.183 0.80133E+04 177 tremolite 14.95 10.95 -4.00 -0.108 0.15913E+05 179 troilite-low -7.95 -8.91 -0.95 -0.318 0.37969E+04 180 tschermakite -11.92 -15.11 -3.19 -0.086 0.12681E+05 183 wadsleyite-Fe 2.66 0.50 -2.16 -0.309 0.85912E+04 184 wadsleyite-Mg 7.78 3.99 -3.79 -0.541 0.15055E+05 185 wairakite -10.81 -12.16 -1.34 -0.079 0.53401E+04 186 walstromite 4.61 2.08 -2.53 -0.506 0.10062E+05 187 wollastonite 4.22 2.08 -2.14 -0.428 0.85027E+04 188 pseudo-wollastonite 4.33 2.08 -2.24 -0.449 0.89249E+04 189 zoisite -12.02 -13.98 -1.96 -0.089 0.77991E+04 192 beidellite-Ca -15.14 -16.25 -1.11 -0.068 0.44013E+04 193 beidellite-H -15.14 -16.75 -1.60 -0.102 0.63731E+04 194 beidellite-K -14.08 -15.58 -1.50 -0.092 0.59668E+04 195 beidellite-Mg -15.47 -16.34 -0.87 -0.054 0.34744E+04 196 beidellite-Na -14.01 -15.41 -1.40 -0.086 0.55533E+04 199 chalcocite -12.80 -14.02 -1.22 -0.304 0.48407E+04 200 covellite -11.38 -12.65 -1.27 -0.486 0.50706E+04 202 montmorillonite-Ca -11.00 -11.95 -0.95 -0.058 0.37609E+04 203 montmorillonite-K -10.23 -11.28 -1.04 -0.064 0.41469E+04 204 montmorillonite-Mg -11.25 -12.04 -0.79 -0.049 0.31401E+04 205 montmorillonite-Na -9.86 -11.11 -1.25 -0.077 0.49766E+04 206 nontronite-Ca -3.27 -5.02 -1.75 -0.114 0.69638E+04 207 nontronite-H -3.28 -5.52 -2.24 -0.150 0.89036E+04 208 nontronite-K -2.21 -4.35 -2.14 -0.138 0.85209E+04 209 nontronite-Mg -3.53 -5.11 -1.58 -0.103 0.62872E+04 210 nontronite-Na -2.14 -4.18 -2.04 -0.131 0.81191E+04 215 gypsum -11.09 -13.32 -2.23 -0.558 0.88716E+04 232 alabandite -5.78 -7.56 -1.79 -0.596 0.71056E+04 234 anglesite -13.28 -16.02 -2.74 -1.370 0.10900E+05 237 barite -14.16 -14.31 -0.15 -0.076 0.60335E+03 238 boehmite -4.90 -5.75 -0.85 -0.141 0.33664E+04 240 chalcopyrite -21.43 -21.56 -0.13 -0.025 0.53516E+03 242 copper,native 1.81 -1.37 -3.18 -1.105 0.12640E+05 244 ferrous-oxide 1.70 0.71 -1.00 -0.249 0.39665E+04 245 galena -8.77 -9.32 -0.54 -0.180 0.21533E+04 246 silver,native 0.59 -3.74 -4.33 -1.506 0.17217E+05 248 litharge 5.20 0.30 -4.90 -1.226 0.19499E+05 255 sphalerite -10.18 -10.51 -0.33 -0.111 0.13198E+04 256 wurtzite -9.40 -10.51 -1.11 -0.369 0.44059E+04 257 zincite 1.86 -0.89 -2.76 -0.689 0.10960E+05 258 an20ab80 -5.62 -5.61 0.01 0.000 -0.22070E+02 259 an25ab75 -5.93 -5.91 0.03 0.002 -0.10002E+03 260 an30ab70 -6.24 -6.20 0.04 0.003 -0.15244E+03 261 tr.625ac.25prg.125 9.20 7.04 -2.16 -0.058 0.86008E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 14 Loop limit = 500 Temperature = 596.00 C Pressure = 2060.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5500E+02 kg liquid = 0.9909E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9946 Stoichiometric ionic strength = .3312497E+01 Osmotic coef. = 0.0000 True ionic strength = .2827245E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18537E-04 -4.7320 0.55800E-05 -5.2534 0.30102E+00 -0.5214 2 H2O 0.99457E+00 -0.0024 0.99457E+00 -0.0024 3 Cl- 0.24004E+00 -0.6197 0.68813E-01 -1.1623 0.28667E+00 -0.5426 4 SO4-- 0.14167E-03 -3.8487 0.15454E-05 -5.8110 0.10909E-01 -1.9622 5 HCO3- 0.35100E-04 -4.4547 0.10784E-04 -4.9672 0.30724E+00 -0.5125 6 HS- 0.15057E-03 -3.8223 0.43499E-04 -4.3615 0.28890E+00 -0.5393 7 H4SiO4 0.12048E+00 -0.9191 0.12048E+00 -0.9191 0.10000E+01 0.0000 8 Al+++ 0.10640E-16 -16.9731 0.31455E-21 -21.5023 0.29563E-04 -4.5293 9 Ca++ 0.34560E-05 -5.4614 0.31067E-07 -7.5077 0.89893E-02 -2.0463 10 Mg++ 0.11856E-05 -5.9261 0.89016E-08 -8.0505 0.75082E-02 -2.1245 11 Fe++ 0.20214E-07 -7.6943 0.15890E-09 -9.7989 0.78609E-02 -2.1045 12 K+ 0.61849E-01 -1.2087 0.19459E-01 -1.7109 0.31462E+00 -0.5022 13 Na+ 0.21827E+00 -0.6610 0.63351E-01 -1.1982 0.29024E+00 -0.5372 14 Mn++ 0.43260E-06 -6.3639 0.35162E-08 -8.4539 0.81281E-02 -2.0900 15 Zn++ 0.50731E-09 -9.2947 0.39879E-11 -11.3993 0.78609E-02 -2.1045 16 Cu+ 0.12101E-06 -6.9172 0.35034E-07 -7.4555 0.28951E+00 -0.5383 17 Pb++ 0.62149E-08 -8.2066 0.61950E-10 -10.2080 0.99679E-02 -2.0014 18 Ag+ 0.47757E-09 -9.3210 0.14809E-09 -9.8295 0.31010E+00 -0.5085 19 Ba++ 0.29468E-06 -6.5306 0.31343E-08 -8.5039 0.10636E-01 -1.9732 20 HPO4-- 0.14464E-08 -8.8397 0.15849E-10 -10.8000 0.10958E-01 -1.9603 21 HSiO3- 0.24710E-05 -5.6071 0.70837E-06 -6.1497 0.28667E+00 -0.5426 22 Ca(HSiO3)+ 0.19459E-07 -7.7109 0.61716E-08 -8.2096 0.31716E+00 -0.4987 23 Mg(HSiO3)+ 0.13706E-08 -8.8631 0.43470E-09 -9.3618 0.31716E+00 -0.4987 24 NaHSiO3,aq 0.12262E-05 -5.9114 0.12262E-05 -5.9114 0.10000E+01 0.0000 28 AgCl,aq 0.67274E-07 -7.1721 0.67274E-07 -7.1721 0.10000E+01 0.0000 29 AgCl2- 0.49541E-05 -5.3050 0.14202E-05 -5.8477 0.28667E+00 -0.5426 30 AgCl3-2 0.26486E-05 -5.5770 0.26939E-07 -7.5696 0.10171E-01 -1.9926 31 AgCl4-3 0.11068E-05 -5.9559 0.28380E-10 -10.5470 0.25640E-04 -4.5911 34 Ag(HS),aq 0.45552E-09 -9.3415 0.45552E-09 -9.3415 0.10000E+01 0.0000 35 Ag(HS)2- 0.27159E-08 -8.5661 0.77855E-09 -9.1087 0.28667E+00 -0.5426 36 AlO+ 0.18498E-10 -10.7329 0.58669E-11 -11.2316 0.31716E+00 -0.4987 38 HAlO2,aq 0.57141E-08 -8.2430 0.57141E-08 -8.2430 0.10000E+01 0.0000 39 AlO2- 0.26372E-04 -4.5789 0.66675E-05 -5.1760 0.25282E+00 -0.5972 41 Ba(HCO3)+ 0.15043E-05 -5.8227 0.49470E-06 -6.3057 0.32886E+00 -0.4830 42 BaCl+ 0.54081E-04 -4.2670 0.17152E-04 -4.7657 0.31716E+00 -0.4987 43 CH4,aq 0.21556E-08 -8.6664 0.26358E-08 -8.5791 0.12228E+01 0.0873 48 CO,aq 0.93705E-03 -3.0282 0.93705E-03 -3.0282 0.10000E+01 0.0000 49 CO2,aq 0.26795E+01 0.4280 0.32763E+01 0.5154 0.12228E+01 0.0873 50 CO3-2 0.57469E-10 -10.2406 0.58451E-12 -12.2332 0.10171E-01 -1.9926 51 CaCO3,aq 0.19449E-10 -10.7111 0.19449E-10 -10.7111 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.11433E-05 -5.9419 0.36260E-06 -6.4406 0.31716E+00 -0.4987 53 CaCl+ 0.36065E-03 -3.4429 0.11438E-03 -3.9416 0.31716E+00 -0.4987 54 CaCl2,aq 0.16460E-03 -3.7836 0.16460E-03 -3.7836 0.10000E+01 0.0000 55 CaOH+ 0.47026E-06 -6.3277 0.14915E-06 -6.8264 0.31716E+00 -0.4987 56 CaSO4,aq 0.10318E-06 -6.9864 0.10318E-06 -6.9864 0.10000E+01 0.0000 57 HCl,aq 0.10355E-02 -2.9848 0.10355E-02 -2.9848 0.10000E+01 0.0000 66 CuCl,aq 0.65654E-04 -4.1827 0.65654E-04 -4.1827 0.10000E+01 0.0000 67 CuCl2- 0.25955E-03 -3.5858 0.74405E-04 -4.1284 0.28667E+00 -0.5426 68 CuCl3-2 0.71732E-05 -5.1443 0.72958E-07 -7.1369 0.10171E-01 -1.9926 74 FeCl+ 0.66091E-06 -6.1799 0.20962E-06 -6.6786 0.31716E+00 -0.4987 75 FeCl2,aq 0.88321E-02 -2.0539 0.88321E-02 -2.0539 0.10000E+01 0.0000 77 FeO,aq 0.54412E-07 -7.2643 0.54412E-07 -7.2643 0.10000E+01 0.0000 78 FeOH+ 0.43925E-07 -7.3573 0.13931E-07 -7.8560 0.31716E+00 -0.4987 79 HFeO2- 0.82719E-08 -8.0824 0.23713E-08 -8.6250 0.28667E+00 -0.5426 82 FeO2- 0.45726E-08 -8.3398 0.13108E-08 -8.8825 0.28667E+00 -0.5426 83 HFeO2,aq 0.13877E-09 -9.8577 0.13877E-09 -9.8577 0.10000E+01 0.0000 84 H2,aq 0.43613E-02 -2.3604 0.53328E-02 -2.2730 0.12228E+01 0.0873 85 KCl,aq 0.49951E-01 -1.3015 0.49951E-01 -1.3015 0.10000E+01 0.0000 86 KHSO4,aq 0.11862E-01 -1.9258 0.11862E-01 -1.9258 0.10000E+01 0.0000 87 KOH,aq 0.76162E-06 -6.1183 0.76162E-06 -6.1183 0.10000E+01 0.0000 88 KSO4- 0.28963E-02 -2.5382 0.83028E-03 -3.0808 0.28667E+00 -0.5426 90 Mg(HCO3)+ 0.14402E-06 -6.8416 0.45679E-07 -7.3403 0.31716E+00 -0.4987 91 MgCl+ 0.18984E-04 -4.7216 0.60211E-05 -5.2203 0.31716E+00 -0.4987 92 MgOH+ 0.55064E-06 -6.2591 0.17464E-06 -6.7578 0.31716E+00 -0.4987 94 MnO,aq 0.17676E-07 -7.7526 0.17676E-07 -7.7526 0.10000E+01 0.0000 95 MnOH+ 0.12304E-06 -6.9100 0.39023E-07 -7.4087 0.31716E+00 -0.4987 97 HMnO2- 0.12972E-10 -10.8870 0.37188E-11 -11.4296 0.28667E+00 -0.5426 100 MnCl+ 0.11594E-02 -2.9358 0.36773E-03 -3.4345 0.31716E+00 -0.4987 101 MnSO4,aq 0.14988E-07 -7.8243 0.14988E-07 -7.8243 0.10000E+01 0.0000 102 NaCl,aq 0.34140E+00 -0.4667 0.34140E+00 -0.4667 0.10000E+01 0.0000 103 NaOH,aq 0.11301E-05 -5.9469 0.11301E-05 -5.9469 0.10000E+01 0.0000 105 OH- 0.98688E-05 -5.0057 0.24951E-05 -5.6029 0.25282E+00 -0.5972 110 HPO3-2 0.28695E-10 -10.5422 0.29185E-12 -12.5348 0.10171E-01 -1.9926 111 H3PO3,aq 0.23768E-09 -9.6240 0.23768E-09 -9.6240 0.10000E+01 0.0000 112 H2PO3- 0.11519E-07 -7.9386 0.33022E-08 -8.4812 0.28667E+00 -0.5426 113 H3PO4,aq 0.14248E-05 -5.8463 0.14248E-05 -5.8463 0.10000E+01 0.0000 114 H2PO4- 0.35028E-05 -5.4556 0.10522E-05 -5.9779 0.30039E+00 -0.5223 116 H4P2O7,aq 0.16398E-09 -9.7852 0.16398E-09 -9.7852 0.10000E+01 0.0000 117 H3P2O7- 0.43898E-08 -8.3576 0.12584E-08 -8.9002 0.28667E+00 -0.5426 118 H2P2O7-2 0.11337E-05 -5.9455 0.11531E-07 -7.9382 0.10171E-01 -1.9926 119 HP2O7-3 0.23611E-07 -7.6269 0.60539E-12 -12.2180 0.25640E-04 -4.5911 121 PbCl+ 0.36172E-05 -5.4416 0.11473E-05 -5.9403 0.31716E+00 -0.4987 122 PbCl2,aq 0.10051E-03 -3.9978 0.10051E-03 -3.9978 0.10000E+01 0.0000 123 PbCl3- 0.11960E-03 -3.9223 0.34286E-04 -4.4649 0.28667E+00 -0.5426 124 PbCl4-2 0.32361E-04 -4.4900 0.32914E-06 -6.4826 0.10171E-01 -1.9926 125 PbO,aq 0.26454E-08 -8.5775 0.26454E-08 -8.5775 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.81358E-04 -4.0896 0.81358E-04 -4.0896 0.10000E+01 0.0000 128 Pb(HS)3- 0.58291E-05 -5.2344 0.16710E-05 -5.7770 0.28667E+00 -0.5426 129 H2S,aq 0.10397E+01 0.0169 0.12713E+01 0.1043 0.12228E+01 0.0873 130 S2-2 0.13700E-07 -7.8633 0.13934E-09 -9.8559 0.10171E-01 -1.9926 131 S3-2 0.15311E-08 -8.8150 0.15572E-10 -10.8077 0.10171E-01 -1.9926 132 S3- 0.24725E-01 -1.6069 0.70879E-02 -2.1495 0.28667E+00 -0.5426 133 S4-2 0.14133E-09 -9.8498 0.14374E-11 -11.8424 0.10171E-01 -1.9926 134 S5-2 0.10939E-10 -10.9610 0.11126E-12 -12.9536 0.10171E-01 -1.9926 135 SO2,aq 0.28196E+00 -0.5498 0.28196E+00 -0.5498 0.10000E+01 0.0000 136 SO3-2 0.57828E-09 -9.2379 0.88788E-11 -11.0516 0.15354E-01 -1.8138 137 HSO3- 0.48051E-03 -3.3183 0.13775E-03 -3.8609 0.28667E+00 -0.5426 138 HSO4- 0.13164E-01 -1.8806 0.42740E-02 -2.3692 0.32467E+00 -0.4886 140 S2O3-2 0.46728E-06 -6.3304 0.47527E-08 -8.3231 0.10171E-01 -1.9926 141 HS2O3- 0.86535E-06 -6.0628 0.24807E-06 -6.6054 0.28667E+00 -0.5426 142 H2S2O3,aq 0.24957E-07 -7.6028 0.24957E-07 -7.6028 0.10000E+01 0.0000 150 S4O6-2 0.73603E-09 -9.1331 0.74861E-11 -11.1257 0.10171E-01 -1.9926 152 ZnCl+ 0.77482E-03 -3.1108 0.24574E-03 -3.6095 0.31716E+00 -0.4987 153 ZnCl2,aq 0.13172E-02 -2.8804 0.13172E-02 -2.8804 0.10000E+01 0.0000 154 ZnCl3- 0.22521E-03 -3.6474 0.64560E-04 -4.1900 0.28667E+00 -0.5426 155 ZnO,aq 0.24578E-07 -7.6094 0.24578E-07 -7.6094 0.10000E+01 0.0000 156 ZnOH+ 0.31464E-05 -5.5022 0.99793E-06 -6.0009 0.31716E+00 -0.4987 158 HZnO2- 0.23381E-09 -9.6311 0.67025E-10 -10.1738 0.28667E+00 -0.5426 Charge balance for all species = 0.2554E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1853674E-04 0.4303462E+01 0.3526119E+04 0.0000 2 H2O 0.1000000E+01 0.5248850E+02 0.7686879E+06 0.0000 3 Cl- 0.2400447E+00 0.6574265E+00 0.1894718E+05 4.0910 4 SO4-- 0.1416657E-03 0.2540262E+00 0.1983685E+05 4.6958 5 HCO3- 0.3510015E-04 0.2680437E+01 0.1329543E+06 0.2862 6 HS- 0.1505669E-03 0.1170714E+01 0.3147426E+05 0.8918 7 H4SiO4 0.1204817E+00 0.1204855E+00 0.9413952E+04 -0.9191 8 Al+++ 0.1064009E-16 0.2637785E-04 0.5785618E+00 -5.7422 9 Ca++ 0.3456035E-05 0.5304419E-03 0.1728177E+02 2.9990 10 Mg++ 0.1185585E-05 0.2086600E-04 0.4123864E+00 2.4562 11 Fe++ 0.2021407E-07 0.8832883E-02 0.4010022E+03 0.7079 12 K+ 0.6184859E-01 0.1265586E+00 0.4022861E+04 3.5425 13 Na+ 0.2182741E+00 0.5596782E+00 0.1045967E+05 4.0551 14 Mn++ 0.4325968E-06 0.1160027E-02 0.5180662E+02 2.0528 15 Zn++ 0.5073115E-09 0.2320391E-02 0.1233060E+03 -0.8925 16 Cu+ 0.1210098E-06 0.3324992E-03 0.1717442E+02 -2.2021 17 Pb++ 0.6214944E-08 0.3432878E-03 0.5781914E+02 0.2988 18 Ag+ 0.4775715E-09 0.8780522E-05 0.7699551E+00 -4.5761 19 Ba++ 0.2946843E-06 0.5587954E-04 0.6238702E+01 2.0029 20 HPO4-- 0.1446355E-08 0.7264507E-05 0.5667959E+00 -0.2932 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4264410E+01 -.2047352E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5201219E+02 -.4740841E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517210E+00 0.1753196E-05 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160090E+01 0.5434909E-04 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1193921E+00 0.2420223E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2613848E-04 0.6684010E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.5256284E-03 0.2281527E-05 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8752728E-02 0.1402557E-04 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3294819E-03 0.7012786E-04 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.7198584E-05 0.1368916E-05 0.0000000E+00 Chg. balance for solid moles: -.3007E-18 Mass of aqueous solution: 0.121898E+04 g Temperature = 596.00 C Pressure = 2060.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) andalusite 0.3342E-03 -3.476 0.5416E-01 -1.266 3.622 0.1722E-01 quartz 0.2387E-01 -1.622 1.434 0.157 95.89 0.5415 bornite 0.1403E-04 -4.853 0.7038E-02 -2.153 0.4706 0.1385E-02 apatite-OH 0.4563E-06 -6.341 0.2292E-03 -3.640 0.1533E-01 0.7283E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity andalusite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.495416 g Volume = 0.560215 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 19 andalusite -12.41 -12.41 0.00 0.000 -0.14129E-10 30 apatite-OH -48.93 -48.93 0.00 0.000 -0.28259E-10 144 quartz -0.91 -0.91 0.00 0.000 0.00000E+00 197 bornite -49.60 -49.60 0.00 0.000 0.28259E-10 260 an30ab70 -6.24 -6.20 0.04 0.003 -0.15005E+03 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.30 -0.296 0.11757E+04 3.018 2 CO2,gas -8.87 -10.22 -1.35 -0.451 0.53751E+04 1.962 3 CH4,gas 6.89 -3.52 -10.41 -2.603 0.41413E+05 -7.099 4 H2,gas 5.72 1.67 -4.05 -2.312 0.16094E+05 -0.733 5 H2S,gas -7.36 -9.61 -2.25 -1.126 0.89583E+04 1.061 6 CO,gas -3.00 -8.54 -5.54 -1.704 0.22023E+05 -2.224 7 SO3,gas -6.16 -16.32 -10.15 -2.538 0.40382E+05 -6.840 8 O2,gas 16.46 -3.35 -19.81 -13.208 0.78797E+05 -16.499 9 HCl,gas -5.52 -6.42 -0.90 -0.450 0.35818E+04 -0.901 10 acmite 4.03 2.09 -1.94 -0.201 0.76992E+04 12 akimotoite 5.83 1.54 -4.29 -0.858 0.17055E+05 13 akimotoite-Fe 3.82 -0.21 -4.03 -0.806 0.16033E+05 14 albite-high -4.29 -4.43 -0.15 -0.011 0.58010E+03 15 albite -4.25 -4.43 -0.18 -0.014 0.72443E+03 16 almandine -10.43 -12.12 -1.69 -0.085 0.67242E+04 17 pyrope -4.10 -6.87 -2.77 -0.139 0.11034E+05 18 analcite -2.58 -3.52 -0.94 -0.105 0.37529E+04 21 grossular -0.52 -5.24 -4.72 -0.236 0.18775E+05 22 anhydrite -13.17 -13.32 -0.15 -0.075 0.59906E+03 24 annite -0.66 -2.83 -2.18 -0.121 0.86561E+04 25 phlogopite 3.72 2.41 -1.31 -0.073 0.52120E+04 27 anorthite -9.99 -10.32 -0.33 -0.026 0.13206E+04 28 anthophyllite 13.76 9.86 -3.90 -0.105 0.15522E+05 29 anthophyllite-Fe 1.79 -2.38 -4.16 -0.113 0.16562E+05 31 apatite-OH-zs -46.85 -48.93 -2.08 -0.160 0.82526E+04 32 apatite-Cl-zs -52.38 -55.34 -2.96 -0.247 0.11774E+05 33 aragonite -3.84 -7.22 -3.38 -1.126 0.13434E+05 34 brucite 4.88 2.45 -2.43 -0.486 0.96632E+04 35 calcite -3.93 -7.22 -3.29 -1.098 0.13095E+05 36 carnegieite-low -0.84 -2.61 -1.77 -0.253 0.70354E+04 37 carnegieite-high -0.78 -2.61 -1.83 -0.261 0.72800E+04 38 carpholite-Mg -9.17 -10.87 -1.71 -0.114 0.67825E+04 39 carpholite-Fe -10.45 -12.62 -2.16 -0.144 0.86082E+04 40 celadonite -1.08 -3.41 -2.33 -0.137 0.92534E+04 41 celadonite-Fe -2.43 -5.16 -2.73 -0.160 0.10849E+05 42 chrysotile 8.66 5.53 -3.13 -0.261 0.12440E+05 44 clinochlore 0.27 -1.97 -2.24 -0.070 0.89134E+04 45 daphnite -6.46 -10.72 -4.26 -0.133 0.16945E+05 48 chloritoid-Mg -8.90 -9.95 -1.05 -0.070 0.41827E+04 49 chloritoid-Fe -10.73 -11.70 -0.97 -0.065 0.38572E+04 50 chloritoid-Mn -8.57 -10.36 -1.79 -0.119 0.71124E+04 52 coesite -0.64 -0.91 -0.27 -0.090 0.10722E+04 53 cordierite-H -22.27 -22.65 -0.38 -0.014 0.15121E+04 54 cordierite-Fe -24.56 -26.14 -1.58 -0.055 0.62900E+04 55 cordierite-Mn -20.15 -23.45 -3.30 -0.114 0.13125E+05 56 corundum -11.34 -11.49 -0.16 -0.014 0.61870E+03 58 cristobalite -0.85 -0.91 -0.06 -0.020 0.23765E+03 59 cummingtonite 13.81 9.86 -3.95 -0.107 0.15725E+05 61 cymrite-K -2.73 -4.95 -2.22 -0.185 0.88239E+04 63 diaspore -5.17 -5.75 -0.57 -0.096 0.22795E+04 65 diopside 5.28 3.62 -1.66 -0.166 0.65985E+04 66 hedenbergite 3.93 1.87 -2.06 -0.206 0.81803E+04 68 eastonite -9.23 -10.62 -1.38 -0.053 0.55073E+04 69 enstatite 4.41 3.08 -1.33 -0.133 0.52758E+04 70 clinoenstatite-HiP 4.88 3.08 -1.80 -0.180 0.71506E+04 71 clinoenstatite 4.39 3.08 -1.32 -0.132 0.52329E+04 72 protoenstatite 4.54 3.08 -1.46 -0.146 0.57978E+04 73 epidote -6.29 -8.37 -2.09 -0.101 0.82932E+04 74 clinozoisite -11.96 -13.99 -2.03 -0.092 0.80724E+04 75 epidote-Fe 1.03 -2.76 -3.79 -0.197 0.15083E+05 76 fayalite 1.84 0.50 -1.35 -0.192 0.53584E+04 77 ferrosilite 1.01 -0.42 -1.43 -0.143 0.56749E+04 78 forsterite 5.65 3.99 -1.66 -0.237 0.65857E+04 79 gedrite -13.89 -16.20 -2.31 -0.062 0.91936E+04 81 gibbsite -3.62 -5.75 -2.13 -0.304 0.84613E+04 82 glaucophane 0.47 -3.34 -3.81 -0.103 0.15146E+05 84 goethite 0.89 -0.13 -1.03 -0.222 0.40851E+04 86 greenalite 4.07 0.28 -3.78 -0.315 0.15043E+05 87 grunerite 2.30 -2.38 -4.68 -0.127 0.18620E+05 88 halite -0.24 -2.36 -2.12 -1.059 0.84198E+04 89 hematite 0.31 -0.26 -0.58 -0.070 0.23041E+04 90 heulandite -12.49 -14.91 -2.42 -0.110 0.96180E+04 91 hercynite -9.98 -10.79 -0.81 -0.054 0.32202E+04 94 jadeite -1.91 -3.52 -1.61 -0.161 0.63915E+04 96 kalsilite -1.48 -3.12 -1.64 -0.234 0.65040E+04 97 kaolinite -11.09 -13.32 -2.23 -0.203 0.88714E+04 98 kyanite -12.27 -12.41 -0.13 -0.013 0.53169E+03 100 laumontite -9.12 -12.16 -3.04 -0.203 0.12086E+05 101 lawsonite -7.38 -10.33 -2.94 -0.196 0.11709E+05 102 leucite -3.03 -4.03 -1.00 -0.100 0.39738E+04 104 lizardite 8.85 5.53 -3.32 -0.277 0.13224E+05 105 magnesite -4.91 -7.76 -2.86 -0.952 0.11359E+05 106 magnetite 1.17 0.44 -0.73 -0.060 0.29099E+04 107 minnesotaite 1.02 -1.54 -2.56 -0.151 0.10188E+05 108 minnesotaite-Mg 6.70 3.70 -3.00 -0.176 0.11924E+05 109 magnesioferrite 4.11 2.19 -1.92 -0.157 0.76465E+04 111 manganosite 4.98 2.05 -2.93 -0.732 0.11639E+05 112 margarite -20.89 -21.82 -0.93 -0.037 0.36830E+04 115 microcline -4.85 -4.95 -0.10 -0.008 0.39307E+03 116 monticellite 8.31 4.54 -3.78 -0.540 0.15027E+05 118 mullite-Si -11.71 -12.41 -0.70 -0.070 0.27863E+04 119 muscovite -16.09 -16.44 -0.35 -0.021 0.13896E+04 120 paragonite -15.41 -15.93 -0.52 -0.031 0.20765E+04 121 nepheline -1.13 -2.61 -1.48 -0.212 0.58896E+04 122 osumilite(2) -14.05 -16.39 -2.34 -0.049 0.93213E+04 123 osumilite-Fe -30.94 -32.92 -1.98 -0.041 0.78804E+04 124 pargasite 1.65 -2.86 -4.52 -0.119 0.17957E+05 125 periclase 5.08 2.45 -2.62 -0.656 0.10439E+05 126 periclase-Fe 2.61 0.71 -1.90 -0.475 0.75591E+04 127 perovskite-Al -9.66 -11.49 -1.83 -0.166 0.72687E+04 132 phlogopite-Na 4.59 2.92 -1.67 -0.093 0.66370E+04 134 prehnite -5.31 -8.24 -2.93 -0.173 0.11665E+05 135 prehnite-Fe 0.76 -2.63 -3.39 -0.204 0.13472E+05 138 px-Mg-tschermaks -8.35 -9.95 -1.61 -0.115 0.63869E+04 139 px-Ca-tschermaks -7.29 -9.41 -2.12 -0.152 0.84432E+04 140 pyrite -19.90 -20.20 -0.29 -0.068 0.11555E+04 141 pyrrhotite -8.05 -8.91 -0.86 -0.285 0.34021E+04 142 pyrrhotiteFe0.875 -8.74 -9.20 -0.46 -0.169 0.18277E+04 143 pyrophyllite -14.31 -15.15 -0.84 -0.052 0.33299E+04 146 riebeckite 6.89 2.64 -4.25 -0.117 0.16887E+05 147 ringwoodite-Fe 2.81 0.50 -2.31 -0.331 0.92018E+04 148 ringwoodite-Mg 8.70 3.99 -4.70 -0.672 0.18706E+05 149 rhodochrosite -4.74 -8.17 -3.43 -1.143 0.13633E+05 150 rhodonite 2.49 1.14 -1.35 -0.270 0.53653E+04 151 sanidine -4.33 -4.95 -0.62 -0.048 0.24582E+04 152 sapphirine(351) -47.20 -51.01 -3.82 -0.058 0.15173E+05 153 siderite -6.64 -9.51 -2.87 -0.956 0.11405E+05 154 sillimanite -12.38 -12.41 -0.02 -0.002 0.90384E+02 156 spinel -7.90 -9.04 -1.14 -0.076 0.45354E+04 158 staurolite-Fe -104.63 -107.46 -2.83 -0.026 0.11274E+05 159 staurolite-Mg -96.58 -100.47 -3.89 -0.036 0.15462E+05 163 stilpnomelane-Mg -1.93 -4.78 -2.86 -0.085 0.11358E+05 164 stishovite 1.92 -0.91 -2.84 -0.946 0.11286E+05 165 sudoite-Fe -20.96 -24.32 -3.37 -0.109 0.13390E+05 166 sudoite -18.86 -20.83 -1.97 -0.064 0.78364E+04 167 sulfur -9.81 -11.29 -1.48 -0.454 0.58705E+04 168 sylvite -0.16 -2.87 -2.71 -1.356 0.10787E+05 169 talc 5.01 3.70 -1.30 -0.077 0.51834E+04 170 talc-Fe 2.35 -1.54 -3.89 -0.229 0.15467E+05 171 talc-tschermaks -7.67 -9.33 -1.66 -0.097 0.65920E+04 173 tephroite 6.17 3.19 -2.98 -0.426 0.11851E+05 176 topaz-H -10.39 -12.41 -2.01 -0.183 0.80133E+04 177 tremolite 14.95 10.95 -4.01 -0.108 0.15930E+05 179 troilite-low -7.95 -8.91 -0.95 -0.318 0.37972E+04 180 tschermakite -11.92 -15.12 -3.19 -0.086 0.12697E+05 183 wadsleyite-Fe 2.66 0.50 -2.16 -0.309 0.85917E+04 184 wadsleyite-Mg 7.78 3.99 -3.79 -0.541 0.15055E+05 185 wairakite -10.81 -12.16 -1.34 -0.079 0.53478E+04 186 walstromite 4.61 2.08 -2.53 -0.506 0.10070E+05 187 wollastonite 4.22 2.08 -2.14 -0.428 0.85104E+04 188 pseudo-wollastonite 4.33 2.08 -2.25 -0.449 0.89326E+04 189 zoisite -12.02 -13.99 -1.96 -0.089 0.78145E+04 192 beidellite-Ca -15.14 -16.25 -1.11 -0.068 0.44026E+04 193 beidellite-H -15.14 -16.75 -1.60 -0.102 0.63731E+04 194 beidellite-K -14.08 -15.58 -1.50 -0.092 0.59668E+04 195 beidellite-Mg -15.47 -16.34 -0.87 -0.054 0.34744E+04 196 beidellite-Na -14.01 -15.41 -1.40 -0.086 0.55534E+04 199 chalcocite -12.80 -14.02 -1.22 -0.304 0.48406E+04 200 covellite -11.38 -12.65 -1.27 -0.486 0.50706E+04 202 montmorillonite-Ca -11.00 -11.95 -0.95 -0.059 0.37623E+04 203 montmorillonite-K -10.23 -11.28 -1.04 -0.064 0.41470E+04 204 montmorillonite-Mg -11.25 -12.04 -0.79 -0.049 0.31402E+04 205 montmorillonite-Na -9.86 -11.11 -1.25 -0.077 0.49767E+04 206 nontronite-Ca -3.27 -5.02 -1.75 -0.114 0.69656E+04 207 nontronite-H -3.28 -5.52 -2.24 -0.150 0.89041E+04 208 nontronite-K -2.21 -4.35 -2.14 -0.138 0.85214E+04 209 nontronite-Mg -3.53 -5.11 -1.58 -0.103 0.62877E+04 210 nontronite-Na -2.14 -4.18 -2.04 -0.131 0.81196E+04 215 gypsum -11.09 -13.32 -2.23 -0.558 0.88793E+04 232 alabandite -5.78 -7.56 -1.79 -0.596 0.71059E+04 234 anglesite -13.28 -16.02 -2.74 -1.370 0.10900E+05 237 barite -14.16 -14.31 -0.15 -0.076 0.60354E+03 238 boehmite -4.90 -5.75 -0.85 -0.141 0.33664E+04 240 chalcopyrite -21.43 -21.56 -0.13 -0.025 0.53535E+03 242 copper,native 1.81 -1.37 -3.18 -1.105 0.12640E+05 244 ferrous-oxide 1.70 0.71 -1.00 -0.249 0.39668E+04 245 galena -8.77 -9.32 -0.54 -0.180 0.21534E+04 246 silver,native 0.59 -3.74 -4.33 -1.506 0.17217E+05 248 litharge 5.20 0.30 -4.90 -1.226 0.19500E+05 255 sphalerite -10.18 -10.51 -0.33 -0.111 0.13200E+04 256 wurtzite -9.40 -10.51 -1.11 -0.369 0.44061E+04 257 zincite 1.86 -0.89 -2.76 -0.689 0.10960E+05 258 an20ab80 -5.62 -5.61 0.01 0.000 -0.20436E+02 259 an25ab75 -5.93 -5.91 0.02 0.002 -0.98005E+02 261 tr.625ac.25prg.125 9.20 7.03 -2.17 -0.058 0.86174E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 18 Loop limit = 500 Temperature = 596.00 C Pressure = 2060.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5500E+02 kg liquid = 0.9909E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9946 Stoichiometric ionic strength = .3312136E+01 Osmotic coef. = 0.0000 True ionic strength = .2824407E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18718E-04 -4.7277 0.56366E-05 -5.2490 0.30113E+00 -0.5212 2 H2O 0.99457E+00 -0.0024 0.99457E+00 -0.0024 3 Cl- 0.24012E+00 -0.6196 0.68860E-01 -1.1620 0.28677E+00 -0.5425 4 SO4-- 0.13894E-03 -3.8572 0.15178E-05 -5.8188 0.10925E-01 -1.9616 5 HCO3- 0.34737E-04 -4.4592 0.10676E-04 -4.9716 0.30733E+00 -0.5124 6 HS- 0.14905E-03 -3.8267 0.43077E-04 -4.3658 0.28900E+00 -0.5391 7 H4SiO4 0.12048E+00 -0.9191 0.12048E+00 -0.9191 0.10000E+01 0.0000 8 Al+++ 0.10928E-16 -16.9614 0.32422E-21 -21.4892 0.29668E-04 -4.5277 9 Ca++ 0.27036E-05 -5.5681 0.24342E-07 -7.6136 0.90036E-02 -2.0456 10 Mg++ 0.11836E-05 -5.9268 0.89023E-08 -8.0505 0.75211E-02 -2.1237 11 Fe++ 0.20155E-07 -7.6956 0.15870E-09 -9.7994 0.78742E-02 -2.1038 12 K+ 0.61895E-01 -1.2083 0.19479E-01 -1.7104 0.31471E+00 -0.5021 13 Na+ 0.21803E+00 -0.6615 0.63300E-01 -1.1986 0.29033E+00 -0.5371 14 Mn++ 0.43171E-06 -6.3648 0.35148E-08 -8.4541 0.81416E-02 -2.0893 15 Zn++ 0.50592E-09 -9.2959 0.39837E-11 -11.3997 0.78742E-02 -2.1038 16 Cu+ 0.12268E-06 -6.9112 0.35530E-07 -7.4494 0.28961E+00 -0.5382 17 Pb++ 0.62303E-08 -8.2055 0.62197E-10 -10.2062 0.99831E-02 -2.0007 18 Ag+ 0.47715E-09 -9.3213 0.14800E-09 -9.8297 0.31019E+00 -0.5084 19 Ba++ 0.29422E-06 -6.5313 0.31340E-08 -8.5039 0.10652E-01 -1.9726 20 HPO4-- 0.21982E-08 -8.6579 0.24124E-10 -10.6176 0.10974E-01 -1.9596 21 HSiO3- 0.24454E-05 -5.6117 0.70125E-06 -6.1541 0.28677E+00 -0.5425 22 Ca(HSiO3)+ 0.15089E-07 -7.8213 0.47870E-08 -8.3199 0.31725E+00 -0.4986 23 Mg(HSiO3)+ 0.13566E-08 -8.8676 0.43037E-09 -9.3662 0.31725E+00 -0.4986 24 NaHSiO3,aq 0.12129E-05 -5.9162 0.12129E-05 -5.9162 0.10000E+01 0.0000 28 AgCl,aq 0.67280E-07 -7.1721 0.67280E-07 -7.1721 0.10000E+01 0.0000 29 AgCl2- 0.49562E-05 -5.3049 0.14213E-05 -5.8473 0.28677E+00 -0.5425 30 AgCl3-2 0.26484E-05 -5.5770 0.26978E-07 -7.5690 0.10186E-01 -1.9920 31 AgCl4-3 0.11051E-05 -5.9566 0.28440E-10 -10.5461 0.25735E-04 -4.5895 34 Ag(HS),aq 0.45082E-09 -9.3460 0.45082E-09 -9.3460 0.10000E+01 0.0000 35 Ag(HS)2- 0.26609E-08 -8.5750 0.76305E-09 -9.1174 0.28677E+00 -0.5425 36 AlO+ 0.18681E-10 -10.7286 0.59265E-11 -11.2272 0.31725E+00 -0.4986 38 HAlO2,aq 0.57141E-08 -8.2430 0.57141E-08 -8.2430 0.10000E+01 0.0000 39 AlO2- 0.26095E-04 -4.5834 0.66005E-05 -5.1804 0.25294E+00 -0.5970 41 Ba(HCO3)+ 0.14886E-05 -5.8272 0.48967E-06 -6.3101 0.32895E+00 -0.4829 42 BaCl+ 0.54097E-04 -4.2668 0.17162E-04 -4.7654 0.31725E+00 -0.4986 43 CH4,aq 0.21516E-08 -8.6672 0.26308E-08 -8.5799 0.12227E+01 0.0873 48 CO,aq 0.93660E-03 -3.0284 0.93660E-03 -3.0284 0.10000E+01 0.0000 49 CO2,aq 0.26795E+01 0.4280 0.32763E+01 0.5154 0.12227E+01 0.0873 50 CO3-2 0.56234E-10 -10.2500 0.57282E-12 -12.2420 0.10186E-01 -1.9920 51 CaCO3,aq 0.14934E-10 -10.8258 0.14934E-10 -10.8258 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.88651E-06 -6.0523 0.28125E-06 -6.5509 0.31725E+00 -0.4986 53 CaCl+ 0.28269E-03 -3.5487 0.89683E-04 -4.0473 0.31725E+00 -0.4986 54 CaCl2,aq 0.12914E-03 -3.8889 0.12914E-03 -3.8889 0.10000E+01 0.0000 55 CaOH+ 0.36466E-06 -6.4381 0.11569E-06 -6.9367 0.31725E+00 -0.4986 56 CaSO4,aq 0.79406E-07 -7.1001 0.79406E-07 -7.1001 0.10000E+01 0.0000 57 HCl,aq 0.10468E-02 -2.9801 0.10468E-02 -2.9801 0.10000E+01 0.0000 66 CuCl,aq 0.66629E-04 -4.1763 0.66629E-04 -4.1763 0.10000E+01 0.0000 67 CuCl2- 0.26349E-03 -3.5792 0.75561E-04 -4.1217 0.28677E+00 -0.5425 68 CuCl3-2 0.72787E-05 -5.1379 0.74143E-07 -7.1299 0.10186E-01 -1.9920 74 FeCl+ 0.66036E-06 -6.1802 0.20950E-06 -6.6788 0.31725E+00 -0.4986 75 FeCl2,aq 0.88331E-02 -2.0539 0.88331E-02 -2.0539 0.10000E+01 0.0000 77 FeO,aq 0.53258E-07 -7.2736 0.53258E-07 -7.2736 0.10000E+01 0.0000 78 FeOH+ 0.43417E-07 -7.3623 0.13774E-07 -7.8609 0.31725E+00 -0.4986 79 HFeO2- 0.80123E-08 -8.0962 0.22977E-08 -8.6387 0.28677E+00 -0.5425 82 FeO2- 0.44301E-08 -8.3536 0.12704E-08 -8.8961 0.28677E+00 -0.5425 83 HFeO2,aq 0.13586E-09 -9.8669 0.13586E-09 -9.8669 0.10000E+01 0.0000 84 H2,aq 0.43594E-02 -2.3606 0.53303E-02 -2.2732 0.12227E+01 0.0873 85 KCl,aq 0.50036E-01 -1.3007 0.50036E-01 -1.3007 0.10000E+01 0.0000 86 KHSO4,aq 0.11781E-01 -1.9288 0.11781E-01 -1.9288 0.10000E+01 0.0000 87 KOH,aq 0.75474E-06 -6.1222 0.75474E-06 -6.1222 0.10000E+01 0.0000 88 KSO4- 0.28466E-02 -2.5457 0.81633E-03 -3.0881 0.28677E+00 -0.5425 90 Mg(HCO3)+ 0.14255E-06 -6.8460 0.45223E-07 -7.3446 0.31725E+00 -0.4986 91 MgCl+ 0.18994E-04 -4.7214 0.60257E-05 -5.2200 0.31725E+00 -0.4986 92 MgOH+ 0.54500E-06 -6.2636 0.17290E-06 -6.7622 0.31725E+00 -0.4986 94 MnO,aq 0.17316E-07 -7.7616 0.17316E-07 -7.7616 0.10000E+01 0.0000 95 MnOH+ 0.12172E-06 -6.9146 0.38616E-07 -7.4132 0.31725E+00 -0.4986 97 HMnO2- 0.12576E-10 -10.9005 0.36064E-11 -11.4429 0.28677E+00 -0.5425 100 MnCl+ 0.11594E-02 -2.9357 0.36783E-03 -3.4343 0.31725E+00 -0.4986 101 MnSO4,aq 0.14715E-07 -7.8322 0.14715E-07 -7.8322 0.10000E+01 0.0000 102 NaCl,aq 0.34136E+00 -0.4668 0.34136E+00 -0.4668 0.10000E+01 0.0000 103 NaOH,aq 0.11178E-05 -5.9516 0.11178E-05 -5.9516 0.10000E+01 0.0000 105 OH- 0.97652E-05 -5.0103 0.24700E-05 -5.6073 0.25294E+00 -0.5970 110 HPO3-2 0.43588E-10 -10.3606 0.44400E-12 -12.3526 0.10186E-01 -1.9920 111 H3PO3,aq 0.36897E-09 -9.4330 0.36897E-09 -9.4330 0.10000E+01 0.0000 112 H2PO3- 0.17697E-07 -7.7521 0.50748E-08 -8.2946 0.28677E+00 -0.5425 113 H3PO4,aq 0.22128E-05 -5.6551 0.22128E-05 -5.6551 0.10000E+01 0.0000 114 H2PO4- 0.53839E-05 -5.2689 0.16178E-05 -5.7911 0.30048E+00 -0.5222 116 H4P2O7,aq 0.39553E-09 -9.4028 0.39553E-09 -9.4028 0.10000E+01 0.0000 117 H3P2O7- 0.10479E-07 -7.9797 0.30049E-08 -8.5222 0.28677E+00 -0.5425 118 H2P2O7-2 0.26759E-05 -5.5725 0.27257E-07 -7.5645 0.10186E-01 -1.9920 119 HP2O7-3 0.55050E-07 -7.2592 0.14167E-11 -11.8487 0.25735E-04 -4.5895 121 PbCl+ 0.36331E-05 -5.4397 0.11526E-05 -5.9383 0.31725E+00 -0.4986 122 PbCl2,aq 0.10105E-03 -3.9955 0.10105E-03 -3.9955 0.10000E+01 0.0000 123 PbCl3- 0.12028E-03 -3.9198 0.34493E-04 -4.4623 0.28677E+00 -0.5425 124 PbCl4-2 0.32530E-04 -4.4877 0.33136E-06 -6.4797 0.10186E-01 -1.9920 125 PbO,aq 0.26028E-08 -8.5846 0.26028E-08 -8.5846 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.80104E-04 -4.0963 0.80104E-04 -4.0963 0.10000E+01 0.0000 128 Pb(HS)3- 0.56815E-05 -5.2455 0.16293E-05 -5.7880 0.28677E+00 -0.5425 129 H2S,aq 0.10401E+01 0.0171 0.12718E+01 0.1044 0.12227E+01 0.0873 130 S2-2 0.13421E-07 -7.8722 0.13671E-09 -9.8642 0.10186E-01 -1.9920 131 S3-2 0.15011E-08 -8.8236 0.15291E-10 -10.8156 0.10186E-01 -1.9920 132 S3- 0.24522E-01 -1.6104 0.70321E-02 -2.1529 0.28677E+00 -0.5425 133 S4-2 0.13868E-09 -9.8580 0.14126E-11 -11.8500 0.10186E-01 -1.9920 134 S5-2 0.10743E-10 -10.9689 0.10943E-12 -12.9609 0.10186E-01 -1.9920 135 SO2,aq 0.28246E+00 -0.5490 0.28246E+00 -0.5490 0.10000E+01 0.0000 136 SO3-2 0.56701E-09 -9.2464 0.87166E-11 -11.0597 0.15373E-01 -1.8132 137 HSO3- 0.47635E-03 -3.3221 0.13660E-03 -3.8645 0.28677E+00 -0.5425 138 HSO4- 0.13057E-01 -1.8841 0.42405E-02 -2.3726 0.32476E+00 -0.4884 140 S2O3-2 0.45842E-06 -6.3387 0.46696E-08 -8.3307 0.10186E-01 -1.9920 141 HS2O3- 0.85855E-06 -6.0662 0.24621E-06 -6.6087 0.28677E+00 -0.5425 142 H2S2O3,aq 0.25021E-07 -7.6017 0.25021E-07 -7.6017 0.10000E+01 0.0000 150 S4O6-2 0.72427E-09 -9.1401 0.73776E-11 -11.1321 0.10186E-01 -1.9920 152 ZnCl+ 0.77432E-03 -3.1111 0.24565E-03 -3.6097 0.31725E+00 -0.4986 153 ZnCl2,aq 0.13176E-02 -2.8802 0.13176E-02 -2.8802 0.10000E+01 0.0000 154 ZnCl3- 0.22535E-03 -3.6471 0.64624E-04 -4.1896 0.28677E+00 -0.5425 155 ZnO,aq 0.24062E-07 -7.6187 0.24062E-07 -7.6187 0.10000E+01 0.0000 156 ZnOH+ 0.31107E-05 -5.5071 0.98687E-06 -6.0057 0.31725E+00 -0.4986 158 HZnO2- 0.22651E-09 -9.6449 0.64957E-10 -10.1874 0.28677E+00 -0.5425 Charge balance for all species = 0.2554E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1871796E-04 0.4304012E+01 0.3526594E+04 0.0000 2 H2O 0.1000000E+01 0.5248849E+02 0.7686930E+06 0.0000 3 Cl- 0.2401236E+00 0.6574298E+00 0.1894740E+05 4.0869 4 SO4-- 0.1389388E-03 0.2540276E+00 0.1983709E+05 4.6792 5 HCO3- 0.3473668E-04 0.2680450E+01 0.1329558E+06 0.2774 6 HS- 0.1490535E-03 0.1170723E+01 0.3147473E+05 0.8832 7 H4SiO4 0.1204820E+00 0.1204857E+00 0.9414034E+04 -0.9191 8 Al+++ 0.1092824E-16 0.2610104E-04 0.5724944E+00 -5.7422 9 Ca++ 0.2703566E-05 0.4158836E-03 0.1354956E+02 2.8843 10 Mg++ 0.1183635E-05 0.2086611E-04 0.4123913E+00 2.4475 11 Fe++ 0.2015487E-07 0.8833932E-02 0.4010525E+03 0.6986 12 K+ 0.6189460E-01 0.1265592E+00 0.4022908E+04 3.5385 13 Na+ 0.2180260E+00 0.5593910E+00 0.1045437E+05 4.0504 14 Mn++ 0.4317051E-06 0.1160033E-02 0.5180723E+02 2.0439 15 Zn++ 0.5059217E-09 0.2320403E-02 0.1233074E+03 -0.9017 16 Cu+ 0.1226817E-06 0.3375239E-03 0.1743408E+02 -2.2004 17 Pb++ 0.6230262E-08 0.3432896E-03 0.5781982E+02 0.2917 18 Ag+ 0.4771456E-09 0.8780566E-05 0.7699642E+00 -4.5807 19 Ba++ 0.2942200E-06 0.5587982E-04 0.6238775E+01 1.9941 20 HPO4-- 0.2198216E-08 0.1310058E-04 0.1022149E+01 -0.1196 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4264933E+01 -.2571292E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5201192E+02 -.4714333E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517212E+00 0.1628758E-05 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160094E+01 0.5049151E-04 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1193917E+00 0.2420260E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2586405E-04 0.6686755E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.4121075E-03 0.1158024E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8753724E-02 0.1303007E-04 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5543120E+00 0.2873716E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3344594E-03 0.6515034E-04 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.1298164E-04 -.4414137E-05 0.0000000E+00 Chg. balance for solid moles: 0.1016E-18 Mass of aqueous solution: 0.121897E+04 g Temperature = 596.00 C Pressure = 2060.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) andalusite 0.6749E-04 -4.171 0.1094E-01 -1.961 0.7244 0.3478E-02 apatite-OH -.1471E-05 1.000 -.7391E-03 1.000 -.4895E-01 -.2349E-03 quartz 0.2303E-01 -1.638 1.383 0.141 91.63 0.5224 bornite 0.1303E-04 -4.885 0.6538E-02 -2.185 0.4331 0.1286E-02 an30ab70 0.4105E-03 -3.387 0.1096 -0.960 7.261 0.4116E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity andalusite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.509798 g Volume = 0.568141 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 19 andalusite -12.41 -12.41 0.00 0.000 0.00000E+00 144 quartz -0.91 -0.91 0.00 0.000 0.00000E+00 197 bornite -49.60 -49.60 0.00 0.000 0.28259E-10 260 an30ab70 -6.24 -6.24 0.00 0.000 -0.21194E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.30 -0.296 0.11757E+04 3.018 2 CO2,gas -8.87 -10.22 -1.35 -0.451 0.53751E+04 1.962 3 CH4,gas 6.89 -3.52 -10.41 -2.603 0.41416E+05 -7.100 4 H2,gas 5.72 1.67 -4.05 -2.312 0.16095E+05 -0.733 5 H2S,gas -7.36 -9.61 -2.25 -1.126 0.89577E+04 1.062 6 CO,gas -3.00 -8.54 -5.54 -1.704 0.22024E+05 -2.224 7 SO3,gas -6.16 -16.31 -10.15 -2.538 0.40378E+05 -6.839 8 O2,gas 16.46 -3.35 -19.81 -13.208 0.78795E+05 -16.498 9 HCl,gas -5.52 -6.41 -0.90 -0.448 0.35632E+04 -0.896 10 acmite 4.03 2.08 -1.95 -0.203 0.77546E+04 12 akimotoite 5.83 1.53 -4.30 -0.859 0.17090E+05 13 akimotoite-Fe 3.82 -0.22 -4.04 -0.808 0.16070E+05 14 albite-high -4.29 -4.44 -0.15 -0.012 0.59891E+03 15 albite -4.25 -4.44 -0.19 -0.014 0.74325E+03 16 almandine -10.43 -12.15 -1.72 -0.086 0.68353E+04 17 pyrope -4.10 -6.90 -2.80 -0.140 0.11138E+05 18 analcite -2.58 -3.53 -0.95 -0.105 0.37717E+04 22 anhydrite -13.17 -13.43 -0.26 -0.132 0.10515E+04 24 annite -0.66 -2.87 -2.21 -0.123 0.87828E+04 25 phlogopite 3.72 2.38 -1.34 -0.074 0.53319E+04 27 anorthite -9.99 -10.44 -0.45 -0.034 0.17768E+04 28 anthophyllite 13.76 9.80 -3.96 -0.107 0.15765E+05 29 anthophyllite-Fe 1.79 -2.44 -4.23 -0.114 0.16821E+05 30 apatite-OH -48.93 -48.93 0.00 0.000 0.56518E-10 31 apatite-OH-zs -46.85 -48.93 -2.08 -0.160 0.82526E+04 32 apatite-Cl-zs -52.38 -55.34 -2.96 -0.246 0.11756E+05 33 aragonite -3.84 -7.34 -3.49 -1.164 0.13890E+05 34 brucite 4.88 2.44 -2.44 -0.488 0.96979E+04 35 calcite -3.93 -7.34 -3.41 -1.136 0.13551E+05 36 carnegieite-low -0.84 -2.61 -1.77 -0.253 0.70542E+04 37 carnegieite-high -0.78 -2.61 -1.84 -0.262 0.72988E+04 38 carpholite-Mg -9.17 -10.88 -1.71 -0.114 0.68172E+04 39 carpholite-Fe -10.45 -12.63 -2.17 -0.145 0.86452E+04 40 celadonite -1.08 -3.42 -2.34 -0.138 0.93038E+04 41 celadonite-Fe -2.43 -5.17 -2.74 -0.161 0.10902E+05 42 chrysotile 8.66 5.50 -3.15 -0.263 0.12544E+05 44 clinochlore 0.27 -2.02 -2.28 -0.071 0.90871E+04 45 daphnite -6.46 -10.76 -4.31 -0.135 0.17130E+05 48 chloritoid-Mg -8.90 -9.96 -1.06 -0.071 0.42175E+04 49 chloritoid-Fe -10.73 -11.71 -0.98 -0.065 0.38942E+04 50 chloritoid-Mn -8.57 -10.37 -1.80 -0.120 0.71480E+04 52 coesite -0.64 -0.91 -0.27 -0.090 0.10722E+04 53 cordierite-H -22.27 -22.67 -0.40 -0.014 0.15816E+04 54 cordierite-Fe -24.56 -26.16 -1.60 -0.055 0.63640E+04 55 cordierite-Mn -20.15 -23.47 -3.32 -0.114 0.13196E+05 56 corundum -11.34 -11.49 -0.16 -0.014 0.61870E+03 58 cristobalite -0.85 -0.91 -0.06 -0.020 0.23765E+03 59 cummingtonite 13.81 9.80 -4.02 -0.109 0.15969E+05 61 cymrite-K -2.73 -4.95 -2.22 -0.185 0.88395E+04 63 diaspore -5.17 -5.75 -0.57 -0.096 0.22795E+04 65 diopside 5.28 3.50 -1.78 -0.178 0.70895E+04 66 hedenbergite 3.93 1.75 -2.18 -0.218 0.86736E+04 68 eastonite -9.23 -10.64 -1.41 -0.054 0.55925E+04 69 enstatite 4.41 3.06 -1.34 -0.134 0.53453E+04 70 clinoenstatite-HiP 4.88 3.06 -1.82 -0.182 0.72200E+04 71 clinoenstatite 4.39 3.06 -1.33 -0.133 0.53024E+04 72 protoenstatite 4.54 3.06 -1.48 -0.148 0.58673E+04 73 epidote -6.29 -8.61 -2.32 -0.113 0.92423E+04 74 clinozoisite -11.96 -14.22 -2.26 -0.103 0.89849E+04 75 epidote-Fe 1.03 -3.01 -4.04 -0.210 0.16068E+05 76 fayalite 1.84 0.48 -1.37 -0.195 0.54325E+04 77 ferrosilite 1.01 -0.44 -1.45 -0.145 0.57490E+04 78 forsterite 5.65 3.98 -1.67 -0.239 0.66552E+04 79 gedrite -13.89 -16.25 -2.36 -0.064 0.93673E+04 81 gibbsite -3.62 -5.75 -2.13 -0.304 0.84613E+04 82 glaucophane 0.47 -3.37 -3.84 -0.104 0.15288E+05 84 goethite 0.89 -0.14 -1.04 -0.224 0.41217E+04 86 greenalite 4.07 0.26 -3.81 -0.318 0.15154E+05 87 grunerite 2.30 -2.44 -4.75 -0.128 0.18879E+05 88 halite -0.24 -2.36 -2.12 -1.059 0.84200E+04 89 hematite 0.31 -0.28 -0.60 -0.072 0.23773E+04 90 heulandite -12.49 -15.02 -2.53 -0.115 0.10074E+05 91 hercynite -9.98 -10.80 -0.82 -0.055 0.32572E+04 94 jadeite -1.91 -3.53 -1.61 -0.161 0.64103E+04 96 kalsilite -1.48 -3.12 -1.64 -0.234 0.65197E+04 97 kaolinite -11.09 -13.32 -2.23 -0.203 0.88714E+04 98 kyanite -12.27 -12.41 -0.13 -0.013 0.53169E+03 100 laumontite -9.12 -12.28 -3.15 -0.210 0.12542E+05 101 lawsonite -7.38 -10.44 -3.06 -0.204 0.12165E+05 102 leucite -3.03 -4.04 -1.00 -0.100 0.39895E+04 104 lizardite 8.85 5.50 -3.35 -0.279 0.13328E+05 105 magnesite -4.91 -7.77 -2.86 -0.955 0.11394E+05 106 magnetite 1.17 0.41 -0.76 -0.062 0.30202E+04 107 minnesotaite 1.02 -1.57 -2.59 -0.152 0.10299E+05 108 minnesotaite-Mg 6.70 3.68 -3.02 -0.178 0.12028E+05 109 magnesioferrite 4.11 2.16 -1.95 -0.159 0.77545E+04 111 manganosite 4.98 2.04 -2.94 -0.734 0.11675E+05 112 margarite -20.89 -21.93 -1.04 -0.042 0.41392E+04 115 microcline -4.85 -4.95 -0.10 -0.008 0.40874E+03 116 monticellite 8.31 4.41 -3.90 -0.557 0.15518E+05 118 mullite-Si -11.71 -12.41 -0.70 -0.070 0.27863E+04 119 muscovite -16.09 -16.45 -0.35 -0.021 0.14053E+04 120 paragonite -15.41 -15.93 -0.53 -0.031 0.20954E+04 121 nepheline -1.13 -2.61 -1.49 -0.212 0.59084E+04 122 osumilite(2) -14.05 -16.42 -2.37 -0.049 0.94412E+04 123 osumilite-Fe -30.94 -32.94 -2.00 -0.042 0.79701E+04 124 pargasite 1.65 -3.13 -4.78 -0.126 0.19027E+05 125 periclase 5.08 2.45 -2.63 -0.658 0.10474E+05 126 periclase-Fe 2.61 0.70 -1.91 -0.477 0.75961E+04 127 perovskite-Al -9.66 -11.49 -1.83 -0.166 0.72687E+04 132 phlogopite-Na 4.59 2.89 -1.70 -0.094 0.67601E+04 134 prehnite -5.31 -8.47 -3.16 -0.186 0.12577E+05 135 prehnite-Fe 0.76 -2.87 -3.63 -0.218 0.14421E+05 138 px-Mg-tschermaks -8.35 -9.96 -1.61 -0.115 0.64216E+04 139 px-Ca-tschermaks -7.29 -9.52 -2.24 -0.160 0.88995E+04 140 pyrite -19.90 -20.20 -0.30 -0.070 0.11905E+04 141 pyrrhotite -8.05 -8.92 -0.86 -0.288 0.34386E+04 142 pyrrhotiteFe0.875 -8.74 -9.21 -0.47 -0.172 0.18594E+04 143 pyrophyllite -14.31 -15.15 -0.84 -0.052 0.33299E+04 146 riebeckite 6.89 2.59 -4.30 -0.119 0.17109E+05 147 ringwoodite-Fe 2.81 0.48 -2.33 -0.333 0.92758E+04 148 ringwoodite-Mg 8.70 3.98 -4.72 -0.674 0.18776E+05 149 rhodochrosite -4.74 -8.18 -3.44 -1.146 0.13669E+05 150 rhodonite 2.49 1.13 -1.36 -0.272 0.54009E+04 151 sanidine -4.33 -4.95 -0.62 -0.048 0.24738E+04 152 sapphirine(351) -47.20 -51.04 -3.84 -0.058 0.15278E+05 153 siderite -6.64 -9.52 -2.88 -0.959 0.11442E+05 154 sillimanite -12.38 -12.41 -0.02 -0.002 0.90384E+02 156 spinel -7.90 -9.05 -1.15 -0.077 0.45701E+04 158 staurolite-Fe -104.63 -107.50 -2.87 -0.026 0.11422E+05 159 staurolite-Mg -96.58 -100.51 -3.92 -0.036 0.15601E+05 163 stilpnomelane-Mg -1.93 -4.83 -2.90 -0.087 0.11540E+05 164 stishovite 1.92 -0.91 -2.84 -0.946 0.11286E+05 165 sudoite-Fe -20.96 -24.34 -3.39 -0.109 0.13464E+05 166 sudoite -18.86 -20.85 -1.99 -0.064 0.79059E+04 167 sulfur -9.81 -11.29 -1.48 -0.454 0.58691E+04 168 sylvite -0.16 -2.87 -2.71 -1.356 0.10784E+05 169 talc 5.01 3.68 -1.33 -0.078 0.52876E+04 170 talc-Fe 2.35 -1.57 -3.92 -0.230 0.15578E+05 171 talc-tschermaks -7.67 -9.35 -1.67 -0.099 0.66615E+04 173 tephroite 6.17 3.17 -3.00 -0.428 0.11922E+05 176 topaz-H -10.39 -12.41 -2.01 -0.183 0.80133E+04 177 tremolite 14.95 10.67 -4.28 -0.116 0.17016E+05 179 troilite-low -7.95 -8.92 -0.96 -0.321 0.38336E+04 180 tschermakite -11.92 -15.37 -3.45 -0.093 0.13714E+05 183 wadsleyite-Fe 2.66 0.48 -2.18 -0.311 0.86658E+04 184 wadsleyite-Mg 7.78 3.98 -3.80 -0.543 0.15125E+05 185 wairakite -10.81 -12.27 -1.46 -0.086 0.58040E+04 186 walstromite 4.61 1.97 -2.65 -0.529 0.10526E+05 187 wollastonite 4.22 1.97 -2.25 -0.451 0.89666E+04 188 pseudo-wollastonite 4.33 1.97 -2.36 -0.472 0.93889E+04 189 zoisite -12.02 -14.22 -2.19 -0.100 0.87270E+04 192 beidellite-Ca -15.14 -16.27 -1.13 -0.070 0.44779E+04 193 beidellite-H -15.14 -16.75 -1.60 -0.102 0.63731E+04 194 beidellite-K -14.08 -15.58 -1.50 -0.092 0.59720E+04 195 beidellite-Mg -15.47 -16.34 -0.88 -0.054 0.34801E+04 196 beidellite-Na -14.01 -15.41 -1.40 -0.086 0.55596E+04 199 chalcocite -12.80 -14.02 -1.21 -0.303 0.48263E+04 200 covellite -11.38 -12.65 -1.27 -0.485 0.50627E+04 202 montmorillonite-Ca -11.00 -11.97 -0.97 -0.060 0.38490E+04 203 montmorillonite-K -10.23 -11.28 -1.05 -0.064 0.41637E+04 204 montmorillonite-Mg -11.25 -12.04 -0.79 -0.049 0.31574E+04 205 montmorillonite-Na -9.86 -11.11 -1.26 -0.077 0.49944E+04 206 nontronite-Ca -3.27 -5.06 -1.79 -0.116 0.71141E+04 207 nontronite-H -3.28 -5.54 -2.26 -0.151 0.89773E+04 208 nontronite-K -2.21 -4.37 -2.16 -0.139 0.85998E+04 209 nontronite-Mg -3.53 -5.13 -1.60 -0.104 0.63667E+04 210 nontronite-Na -2.14 -4.20 -2.06 -0.132 0.81991E+04 215 gypsum -11.09 -13.44 -2.35 -0.587 0.93317E+04 232 alabandite -5.78 -7.57 -1.80 -0.598 0.71408E+04 234 anglesite -13.28 -16.03 -2.75 -1.373 0.10925E+05 237 barite -14.16 -14.32 -0.16 -0.080 0.63476E+03 238 boehmite -4.90 -5.75 -0.85 -0.141 0.33664E+04 240 chalcopyrite -21.43 -21.57 -0.14 -0.026 0.56394E+03 242 copper,native 1.81 -1.36 -3.18 -1.105 0.12633E+05 244 ferrous-oxide 1.70 0.70 -1.01 -0.252 0.40038E+04 245 galena -8.77 -9.32 -0.55 -0.183 0.21809E+04 246 silver,native 0.59 -3.74 -4.33 -1.507 0.17236E+05 248 litharge 5.20 0.29 -4.91 -1.228 0.19528E+05 255 sphalerite -10.18 -10.52 -0.34 -0.114 0.13561E+04 256 wurtzite -9.40 -10.52 -1.12 -0.372 0.44423E+04 257 zincite 1.86 -0.90 -2.77 -0.691 0.10997E+05 258 an20ab80 -5.62 -5.64 -0.02 -0.002 0.85867E+02 259 an25ab75 -5.93 -5.94 -0.01 -0.001 0.30169E+02 261 tr.625ac.25prg.125 9.20 6.76 -2.44 -0.066 0.97045E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 15 Loop limit = 500 Temperature = 596.00 C Pressure = 2060.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5500E+02 kg liquid = 0.9909E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9946 Stoichiometric ionic strength = .3312132E+01 Osmotic coef. = 0.0000 True ionic strength = .2824461E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18711E-04 -4.7279 0.56346E-05 -5.2491 0.30113E+00 -0.5212 2 H2O 0.99457E+00 -0.0024 0.99457E+00 -0.0024 3 Cl- 0.24012E+00 -0.6196 0.68859E-01 -1.1620 0.28677E+00 -0.5425 4 SO4-- 0.13903E-03 -3.8569 0.15188E-05 -5.8185 0.10924E-01 -1.9616 5 HCO3- 0.34749E-04 -4.4591 0.10679E-04 -4.9715 0.30733E+00 -0.5124 6 HS- 0.14911E-03 -3.8265 0.43092E-04 -4.3656 0.28900E+00 -0.5391 7 H4SiO4 0.12048E+00 -0.9191 0.12048E+00 -0.9191 0.10000E+01 0.0000 8 Al+++ 0.10917E-16 -16.9619 0.32387E-21 -21.4896 0.29666E-04 -4.5277 9 Ca++ 0.26992E-05 -5.5688 0.24302E-07 -7.6144 0.90033E-02 -2.0456 10 Mg++ 0.11837E-05 -5.9268 0.89022E-08 -8.0505 0.75209E-02 -2.1237 11 Fe++ 0.20156E-07 -7.6956 0.15871E-09 -9.7994 0.78740E-02 -2.1038 12 K+ 0.61893E-01 -1.2084 0.19478E-01 -1.7105 0.31471E+00 -0.5021 13 Na+ 0.21804E+00 -0.6615 0.63303E-01 -1.1986 0.29033E+00 -0.5371 14 Mn++ 0.43172E-06 -6.3648 0.35148E-08 -8.4541 0.81414E-02 -2.0893 15 Zn++ 0.50595E-09 -9.2959 0.39838E-11 -11.3997 0.78740E-02 -2.1038 16 Cu+ 0.12262E-06 -6.9114 0.35513E-07 -7.4496 0.28961E+00 -0.5382 17 Pb++ 0.62295E-08 -8.2055 0.62188E-10 -10.2063 0.99828E-02 -2.0007 18 Ag+ 0.47716E-09 -9.3213 0.14801E-09 -9.8297 0.31018E+00 -0.5084 19 Ba++ 0.29423E-06 -6.5313 0.31340E-08 -8.5039 0.10652E-01 -1.9726 20 HPO4-- 0.16283E-08 -8.7883 0.17869E-10 -10.7479 0.10974E-01 -1.9596 21 HSiO3- 0.24462E-05 -5.6115 0.70150E-06 -6.1540 0.28677E+00 -0.5425 22 Ca(HSiO3)+ 0.15070E-07 -7.8219 0.47809E-08 -8.3205 0.31725E+00 -0.4986 23 Mg(HSiO3)+ 0.13571E-08 -8.8674 0.43052E-09 -9.3660 0.31725E+00 -0.4986 24 NaHSiO3,aq 0.12134E-05 -5.9160 0.12134E-05 -5.9160 0.10000E+01 0.0000 28 AgCl,aq 0.67280E-07 -7.1721 0.67280E-07 -7.1721 0.10000E+01 0.0000 29 AgCl2- 0.49561E-05 -5.3049 0.14212E-05 -5.8473 0.28677E+00 -0.5425 30 AgCl3-2 0.26484E-05 -5.5770 0.26977E-07 -7.5690 0.10186E-01 -1.9920 31 AgCl4-3 0.11051E-05 -5.9566 0.28439E-10 -10.5461 0.25733E-04 -4.5895 34 Ag(HS),aq 0.45099E-09 -9.3458 0.45099E-09 -9.3458 0.10000E+01 0.0000 35 Ag(HS)2- 0.26628E-08 -8.5747 0.76359E-09 -9.1171 0.28677E+00 -0.5425 36 AlO+ 0.18674E-10 -10.7288 0.59243E-11 -11.2274 0.31725E+00 -0.4986 38 HAlO2,aq 0.57141E-08 -8.2430 0.57141E-08 -8.2430 0.10000E+01 0.0000 39 AlO2- 0.26105E-04 -4.5833 0.66029E-05 -5.1803 0.25294E+00 -0.5970 41 Ba(HCO3)+ 0.14892E-05 -5.8271 0.48985E-06 -6.3099 0.32894E+00 -0.4829 42 BaCl+ 0.54096E-04 -4.2668 0.17162E-04 -4.7654 0.31725E+00 -0.4986 43 CH4,aq 0.21517E-08 -8.6672 0.26310E-08 -8.5799 0.12227E+01 0.0873 48 CO,aq 0.93661E-03 -3.0284 0.93661E-03 -3.0284 0.10000E+01 0.0000 49 CO2,aq 0.26795E+01 0.4280 0.32763E+01 0.5154 0.12227E+01 0.0873 50 CO3-2 0.56276E-10 -10.2497 0.57323E-12 -12.2417 0.10186E-01 -1.9920 51 CaCO3,aq 0.14920E-10 -10.8262 0.14920E-10 -10.8262 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.88539E-06 -6.0529 0.28089E-06 -6.5515 0.31725E+00 -0.4986 53 CaCl+ 0.28223E-03 -3.5494 0.89536E-04 -4.0480 0.31725E+00 -0.4986 54 CaCl2,aq 0.12893E-03 -3.8896 0.12893E-03 -3.8896 0.10000E+01 0.0000 55 CaOH+ 0.36420E-06 -6.4387 0.11554E-06 -6.9373 0.31725E+00 -0.4986 56 CaSO4,aq 0.79327E-07 -7.1006 0.79327E-07 -7.1006 0.10000E+01 0.0000 57 HCl,aq 0.10464E-02 -2.9803 0.10464E-02 -2.9803 0.10000E+01 0.0000 66 CuCl,aq 0.66595E-04 -4.1766 0.66595E-04 -4.1766 0.10000E+01 0.0000 67 CuCl2- 0.26336E-03 -3.5795 0.75522E-04 -4.1219 0.28677E+00 -0.5425 68 CuCl3-2 0.72749E-05 -5.1382 0.74102E-07 -7.1302 0.10186E-01 -1.9920 74 FeCl+ 0.66037E-06 -6.1802 0.20950E-06 -6.6788 0.31725E+00 -0.4986 75 FeCl2,aq 0.88331E-02 -2.0539 0.88331E-02 -2.0539 0.10000E+01 0.0000 77 FeO,aq 0.53298E-07 -7.2733 0.53298E-07 -7.2733 0.10000E+01 0.0000 78 FeOH+ 0.43434E-07 -7.3622 0.13779E-07 -7.8608 0.31725E+00 -0.4986 79 HFeO2- 0.80212E-08 -8.0958 0.23002E-08 -8.6382 0.28677E+00 -0.5425 82 FeO2- 0.44350E-08 -8.3531 0.12718E-08 -8.8956 0.28677E+00 -0.5425 83 HFeO2,aq 0.13596E-09 -9.8666 0.13596E-09 -9.8666 0.10000E+01 0.0000 84 H2,aq 0.43594E-02 -2.3606 0.53304E-02 -2.2732 0.12227E+01 0.0873 85 KCl,aq 0.50034E-01 -1.3007 0.50034E-01 -1.3007 0.10000E+01 0.0000 86 KHSO4,aq 0.11784E-01 -1.9287 0.11784E-01 -1.9287 0.10000E+01 0.0000 87 KOH,aq 0.75498E-06 -6.1221 0.75498E-06 -6.1221 0.10000E+01 0.0000 88 KSO4- 0.28484E-02 -2.5454 0.81682E-03 -3.0879 0.28677E+00 -0.5425 90 Mg(HCO3)+ 0.14260E-06 -6.8459 0.45239E-07 -7.3445 0.31725E+00 -0.4986 91 MgCl+ 0.18993E-04 -4.7214 0.60256E-05 -5.2200 0.31725E+00 -0.4986 92 MgOH+ 0.54520E-06 -6.2634 0.17296E-06 -6.7620 0.31725E+00 -0.4986 94 MnO,aq 0.17329E-07 -7.7612 0.17329E-07 -7.7612 0.10000E+01 0.0000 95 MnOH+ 0.12177E-06 -6.9145 0.38630E-07 -7.4131 0.31725E+00 -0.4986 97 HMnO2- 0.12590E-10 -10.9000 0.36103E-11 -11.4425 0.28677E+00 -0.5425 100 MnCl+ 0.11594E-02 -2.9357 0.36783E-03 -3.4344 0.31725E+00 -0.4986 101 MnSO4,aq 0.14724E-07 -7.8320 0.14724E-07 -7.8320 0.10000E+01 0.0000 102 NaCl,aq 0.34137E+00 -0.4668 0.34137E+00 -0.4668 0.10000E+01 0.0000 103 NaOH,aq 0.11183E-05 -5.9515 0.11183E-05 -5.9515 0.10000E+01 0.0000 105 OH- 0.97688E-05 -5.0102 0.24709E-05 -5.6071 0.25294E+00 -0.5970 110 HPO3-2 0.32288E-10 -10.4910 0.32889E-12 -12.4830 0.10186E-01 -1.9920 111 H3PO3,aq 0.27311E-09 -9.5637 0.27311E-09 -9.5637 0.10000E+01 0.0000 112 H2PO3- 0.13104E-07 -7.8826 0.37577E-08 -8.4251 0.28677E+00 -0.5425 113 H3PO4,aq 0.16379E-05 -5.7857 0.16379E-05 -5.7857 0.10000E+01 0.0000 114 H2PO4- 0.39865E-05 -5.3994 0.11979E-05 -5.9216 0.30048E+00 -0.5222 116 H4P2O7,aq 0.21670E-09 -9.6641 0.21670E-09 -9.6641 0.10000E+01 0.0000 117 H3P2O7- 0.57431E-08 -8.2409 0.16469E-08 -8.7833 0.28677E+00 -0.5425 118 H2P2O7-2 0.14671E-05 -5.8335 0.14944E-07 -7.8255 0.10186E-01 -1.9920 119 HP2O7-3 0.30195E-07 -7.5201 0.77701E-12 -12.1096 0.25733E-04 -4.5895 121 PbCl+ 0.36325E-05 -5.4398 0.11524E-05 -5.9384 0.31725E+00 -0.4986 122 PbCl2,aq 0.10103E-03 -3.9955 0.10103E-03 -3.9955 0.10000E+01 0.0000 123 PbCl3- 0.12026E-03 -3.9199 0.34486E-04 -4.4624 0.28677E+00 -0.5425 124 PbCl4-2 0.32524E-04 -4.4878 0.33129E-06 -6.4798 0.10186E-01 -1.9920 125 PbO,aq 0.26043E-08 -8.5843 0.26043E-08 -8.5843 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.80147E-04 -4.0961 0.80147E-04 -4.0961 0.10000E+01 0.0000 128 Pb(HS)3- 0.56866E-05 -5.2451 0.16307E-05 -5.7876 0.28677E+00 -0.5425 129 H2S,aq 0.10401E+01 0.0171 0.12717E+01 0.1044 0.12227E+01 0.0873 130 S2-2 0.13431E-07 -7.8719 0.13681E-09 -9.8639 0.10186E-01 -1.9920 131 S3-2 0.15021E-08 -8.8233 0.15301E-10 -10.8153 0.10186E-01 -1.9920 132 S3- 0.24529E-01 -1.6103 0.70341E-02 -2.1528 0.28677E+00 -0.5425 133 S4-2 0.13877E-09 -9.8577 0.14135E-11 -11.8497 0.10186E-01 -1.9920 134 S5-2 0.10750E-10 -10.9686 0.10950E-12 -12.9606 0.10186E-01 -1.9920 135 SO2,aq 0.28244E+00 -0.5491 0.28244E+00 -0.5491 0.10000E+01 0.0000 136 SO3-2 0.56739E-09 -9.2461 0.87223E-11 -11.0594 0.15373E-01 -1.8133 137 HSO3- 0.47650E-03 -3.3219 0.13664E-03 -3.8644 0.28677E+00 -0.5425 138 HSO4- 0.13061E-01 -1.8840 0.42417E-02 -2.3725 0.32476E+00 -0.4884 140 S2O3-2 0.45872E-06 -6.3384 0.46726E-08 -8.3304 0.10186E-01 -1.9920 141 HS2O3- 0.85879E-06 -6.0661 0.24627E-06 -6.6086 0.28677E+00 -0.5425 142 H2S2O3,aq 0.25018E-07 -7.6017 0.25018E-07 -7.6017 0.10000E+01 0.0000 150 S4O6-2 0.72467E-09 -9.1399 0.73815E-11 -11.1319 0.10186E-01 -1.9920 152 ZnCl+ 0.77433E-03 -3.1111 0.24565E-03 -3.6097 0.31725E+00 -0.4986 153 ZnCl2,aq 0.13176E-02 -2.8802 0.13176E-02 -2.8802 0.10000E+01 0.0000 154 ZnCl3- 0.22535E-03 -3.6471 0.64623E-04 -4.1896 0.28677E+00 -0.5425 155 ZnO,aq 0.24079E-07 -7.6184 0.24079E-07 -7.6184 0.10000E+01 0.0000 156 ZnOH+ 0.31119E-05 -5.5070 0.98724E-06 -6.0056 0.31725E+00 -0.4986 158 HZnO2- 0.22676E-09 -9.6444 0.65028E-10 -10.1869 0.28677E+00 -0.5425 Charge balance for all species = 0.2554E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1871139E-04 0.4303988E+01 0.3526575E+04 0.0000 2 H2O 0.1000000E+01 0.5248850E+02 0.7686932E+06 0.0000 3 Cl- 0.2401213E+00 0.6574297E+00 0.1894740E+05 4.0871 4 SO4-- 0.1390314E-03 0.2540275E+00 0.1983709E+05 4.6798 5 HCO3- 0.3474930E-04 0.2680450E+01 0.1329558E+06 0.2777 6 HS- 0.1491060E-03 0.1170723E+01 0.3147473E+05 0.8835 7 H4SiO4 0.1204820E+00 0.1204857E+00 0.9414035E+04 -0.9191 8 Al+++ 0.1091725E-16 0.2611061E-04 0.5727043E+00 -5.7422 9 Ca++ 0.2699235E-05 0.4151983E-03 0.1352723E+02 2.8839 10 Mg++ 0.1183669E-05 0.2086610E-04 0.4123912E+00 2.4478 11 Fe++ 0.2015607E-07 0.8833895E-02 0.4010509E+03 0.6989 12 K+ 0.6189262E-01 0.1265592E+00 0.4022908E+04 3.5387 13 Na+ 0.2180350E+00 0.5594066E+00 0.1045467E+05 4.0506 14 Mn++ 0.4317232E-06 0.1160032E-02 0.5180722E+02 2.0442 15 Zn++ 0.5059505E-09 0.2320402E-02 0.1233074E+03 -0.9014 16 Cu+ 0.1226218E-06 0.3373491E-03 0.1742505E+02 -2.2005 17 Pb++ 0.6229496E-08 0.3432895E-03 0.5781981E+02 0.2920 18 Ag+ 0.4771572E-09 0.8780564E-05 0.7699641E+00 -4.5806 19 Ba++ 0.2942283E-06 0.5587980E-04 0.6238775E+01 1.9944 20 HPO4-- 0.1628295E-08 0.8646000E-05 0.6745884E+00 -0.2496 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4264910E+01 -.2548311E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5201194E+02 -.4715629E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517211E+00 0.1633089E-05 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160094E+01 0.5062575E-04 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1193918E+00 0.2420257E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2587354E-04 0.6686660E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.4114286E-03 0.1164813E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8753689E-02 0.1306471E-04 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5543276E+00 0.2717898E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3342862E-03 0.6532355E-04 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5150E-18 Mass of aqueous solution: 0.121897E+04 g Temperature = 596.00 C Pressure = 2060.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) andalusite 0.8196E-04 -4.086 0.1328E-01 -1.877 0.8797 0.4223E-02 quartz 0.2307E-01 -1.637 1.386 0.142 91.82 0.5235 bornite 0.1306E-04 -4.884 0.6556E-02 -2.183 0.4343 0.1290E-02 an30ab70 0.3883E-03 -3.411 0.1037 -0.984 6.867 0.3893E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity andalusite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.509695 g Volume = 0.567927 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 19 andalusite -12.41 -12.41 0.00 0.000 -0.14129E-10 144 quartz -0.91 -0.91 0.00 0.000 0.00000E+00 197 bornite -49.60 -49.60 0.00 0.000 0.28259E-10 260 an30ab70 -6.24 -6.24 0.00 0.000 0.70647E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.30 -0.296 0.11757E+04 3.018 2 CO2,gas -8.87 -10.22 -1.35 -0.451 0.53751E+04 1.962 3 CH4,gas 6.89 -3.52 -10.41 -2.603 0.41416E+05 -7.100 4 H2,gas 5.72 1.67 -4.05 -2.312 0.16095E+05 -0.733 5 H2S,gas -7.36 -9.61 -2.25 -1.126 0.89577E+04 1.062 6 CO,gas -3.00 -8.54 -5.54 -1.704 0.22024E+05 -2.224 7 SO3,gas -6.16 -16.31 -10.15 -2.538 0.40379E+05 -6.839 8 O2,gas 16.46 -3.35 -19.81 -13.208 0.78795E+05 -16.498 9 HCl,gas -5.52 -6.41 -0.90 -0.448 0.35638E+04 -0.896 10 acmite 4.03 2.08 -1.95 -0.203 0.77526E+04 12 akimotoite 5.83 1.53 -4.30 -0.859 0.17088E+05 13 akimotoite-Fe 3.82 -0.22 -4.04 -0.808 0.16069E+05 14 albite-high -4.29 -4.44 -0.15 -0.012 0.59823E+03 15 albite -4.25 -4.44 -0.19 -0.014 0.74257E+03 16 almandine -10.43 -12.15 -1.72 -0.086 0.68315E+04 17 pyrope -4.10 -6.90 -2.80 -0.140 0.11134E+05 18 analcite -2.58 -3.53 -0.95 -0.105 0.37710E+04 22 anhydrite -13.17 -13.43 -0.26 -0.132 0.10532E+04 24 annite -0.66 -2.86 -2.21 -0.123 0.87784E+04 25 phlogopite 3.72 2.38 -1.34 -0.074 0.53276E+04 27 anorthite -9.99 -10.44 -0.45 -0.034 0.17784E+04 28 anthophyllite 13.76 9.80 -3.96 -0.107 0.15757E+05 29 anthophyllite-Fe 1.79 -2.44 -4.23 -0.114 0.16812E+05 30 apatite-OH -48.93 -49.32 -0.39 -0.030 0.15669E+04 31 apatite-OH-zs -46.85 -49.32 -2.47 -0.190 0.98195E+04 32 apatite-Cl-zs -52.38 -55.73 -3.35 -0.279 0.13323E+05 33 aragonite -3.84 -7.34 -3.49 -1.164 0.13892E+05 34 brucite 4.88 2.44 -2.44 -0.488 0.96967E+04 35 calcite -3.93 -7.34 -3.41 -1.136 0.13552E+05 36 carnegieite-low -0.84 -2.61 -1.77 -0.253 0.70535E+04 37 carnegieite-high -0.78 -2.61 -1.84 -0.262 0.72981E+04 38 carpholite-Mg -9.17 -10.88 -1.71 -0.114 0.68160E+04 39 carpholite-Fe -10.45 -12.63 -2.17 -0.145 0.86439E+04 40 celadonite -1.08 -3.42 -2.34 -0.138 0.93020E+04 41 celadonite-Fe -2.43 -5.17 -2.74 -0.161 0.10900E+05 42 chrysotile 8.66 5.50 -3.15 -0.263 0.12540E+05 44 clinochlore 0.27 -2.02 -2.28 -0.071 0.90810E+04 45 daphnite -6.46 -10.76 -4.31 -0.135 0.17124E+05 48 chloritoid-Mg -8.90 -9.96 -1.06 -0.071 0.42162E+04 49 chloritoid-Fe -10.73 -11.71 -0.98 -0.065 0.38929E+04 50 chloritoid-Mn -8.57 -10.37 -1.80 -0.120 0.71467E+04 52 coesite -0.64 -0.91 -0.27 -0.090 0.10722E+04 53 cordierite-H -22.27 -22.67 -0.40 -0.014 0.15791E+04 54 cordierite-Fe -24.56 -26.16 -1.60 -0.055 0.63615E+04 55 cordierite-Mn -20.15 -23.47 -3.32 -0.114 0.13194E+05 56 corundum -11.34 -11.49 -0.16 -0.014 0.61870E+03 58 cristobalite -0.85 -0.91 -0.06 -0.020 0.23765E+03 59 cummingtonite 13.81 9.80 -4.01 -0.108 0.15960E+05 61 cymrite-K -2.73 -4.95 -2.22 -0.185 0.88390E+04 63 diaspore -5.17 -5.75 -0.57 -0.096 0.22795E+04 65 diopside 5.28 3.50 -1.78 -0.178 0.70899E+04 66 hedenbergite 3.93 1.75 -2.18 -0.218 0.86739E+04 68 eastonite -9.23 -10.64 -1.41 -0.054 0.55894E+04 69 enstatite 4.41 3.06 -1.34 -0.134 0.53429E+04 70 clinoenstatite-HiP 4.88 3.06 -1.81 -0.181 0.72176E+04 71 clinoenstatite 4.39 3.06 -1.33 -0.133 0.52999E+04 72 protoenstatite 4.54 3.06 -1.47 -0.147 0.58649E+04 73 epidote -6.29 -8.61 -2.32 -0.113 0.92442E+04 74 clinozoisite -11.96 -14.22 -2.26 -0.103 0.89881E+04 75 epidote-Fe 1.03 -3.01 -4.04 -0.210 0.16069E+05 76 fayalite 1.84 0.48 -1.37 -0.195 0.54299E+04 77 ferrosilite 1.01 -0.44 -1.44 -0.144 0.57464E+04 78 forsterite 5.65 3.98 -1.67 -0.239 0.66527E+04 79 gedrite -13.89 -16.24 -2.35 -0.064 0.93611E+04 81 gibbsite -3.62 -5.75 -2.13 -0.304 0.84613E+04 82 glaucophane 0.47 -3.37 -3.84 -0.104 0.15283E+05 84 goethite 0.89 -0.14 -1.04 -0.224 0.41204E+04 86 greenalite 4.07 0.26 -3.81 -0.317 0.15150E+05 87 grunerite 2.30 -2.44 -4.74 -0.128 0.18870E+05 88 halite -0.24 -2.36 -2.12 -1.059 0.84200E+04 89 hematite 0.31 -0.28 -0.60 -0.072 0.23748E+04 90 heulandite -12.49 -15.02 -2.53 -0.115 0.10076E+05 91 hercynite -9.98 -10.79 -0.82 -0.055 0.32560E+04 94 jadeite -1.91 -3.53 -1.61 -0.161 0.64097E+04 96 kalsilite -1.48 -3.12 -1.64 -0.234 0.65191E+04 97 kaolinite -11.09 -13.32 -2.23 -0.203 0.88714E+04 98 kyanite -12.27 -12.41 -0.13 -0.013 0.53169E+03 100 laumontite -9.12 -12.28 -3.15 -0.210 0.12544E+05 101 lawsonite -7.38 -10.44 -3.06 -0.204 0.12167E+05 102 leucite -3.03 -4.04 -1.00 -0.100 0.39889E+04 104 lizardite 8.85 5.50 -3.35 -0.279 0.13324E+05 105 magnesite -4.91 -7.77 -2.86 -0.955 0.11393E+05 106 magnetite 1.17 0.41 -0.76 -0.062 0.30163E+04 107 minnesotaite 1.02 -1.57 -2.59 -0.152 0.10295E+05 108 minnesotaite-Mg 6.70 3.68 -3.02 -0.178 0.12024E+05 109 magnesioferrite 4.11 2.16 -1.95 -0.159 0.77507E+04 111 manganosite 4.98 2.04 -2.94 -0.734 0.11674E+05 112 margarite -20.89 -21.93 -1.04 -0.042 0.41408E+04 115 microcline -4.85 -4.95 -0.10 -0.008 0.40818E+03 116 monticellite 8.31 4.41 -3.90 -0.557 0.15519E+05 118 mullite-Si -11.71 -12.41 -0.70 -0.070 0.27863E+04 119 muscovite -16.09 -16.45 -0.35 -0.021 0.14047E+04 120 paragonite -15.41 -15.93 -0.53 -0.031 0.20947E+04 121 nepheline -1.13 -2.61 -1.49 -0.212 0.59078E+04 122 osumilite(2) -14.05 -16.42 -2.37 -0.049 0.94370E+04 123 osumilite-Fe -30.94 -32.94 -2.00 -0.042 0.79670E+04 124 pargasite 1.65 -3.13 -4.78 -0.126 0.19025E+05 125 periclase 5.08 2.45 -2.63 -0.658 0.10473E+05 126 periclase-Fe 2.61 0.70 -1.91 -0.477 0.75948E+04 127 perovskite-Al -9.66 -11.49 -1.83 -0.166 0.72687E+04 132 phlogopite-Na 4.59 2.89 -1.70 -0.094 0.67557E+04 134 prehnite -5.31 -8.47 -3.16 -0.186 0.12581E+05 135 prehnite-Fe 0.76 -2.87 -3.63 -0.218 0.14423E+05 138 px-Mg-tschermaks -8.35 -9.96 -1.61 -0.115 0.64204E+04 139 px-Ca-tschermaks -7.29 -9.52 -2.24 -0.160 0.89011E+04 140 pyrite -19.90 -20.20 -0.30 -0.070 0.11893E+04 141 pyrrhotite -8.05 -8.92 -0.86 -0.288 0.34373E+04 142 pyrrhotiteFe0.875 -8.74 -9.21 -0.47 -0.172 0.18583E+04 143 pyrophyllite -14.31 -15.15 -0.84 -0.052 0.33299E+04 146 riebeckite 6.89 2.59 -4.30 -0.119 0.17102E+05 147 ringwoodite-Fe 2.81 0.48 -2.33 -0.333 0.92733E+04 148 ringwoodite-Mg 8.70 3.98 -4.72 -0.674 0.18773E+05 149 rhodochrosite -4.74 -8.18 -3.44 -1.146 0.13668E+05 150 rhodonite 2.49 1.13 -1.36 -0.272 0.53996E+04 151 sanidine -4.33 -4.95 -0.62 -0.048 0.24733E+04 152 sapphirine(351) -47.20 -51.04 -3.84 -0.058 0.15274E+05 153 siderite -6.64 -9.52 -2.88 -0.959 0.11441E+05 154 sillimanite -12.38 -12.41 -0.02 -0.002 0.90384E+02 156 spinel -7.90 -9.05 -1.15 -0.077 0.45689E+04 158 staurolite-Fe -104.63 -107.50 -2.87 -0.026 0.11417E+05 159 staurolite-Mg -96.58 -100.50 -3.92 -0.036 0.15596E+05 163 stilpnomelane-Mg -1.93 -4.83 -2.90 -0.087 0.11533E+05 164 stishovite 1.92 -0.91 -2.84 -0.946 0.11286E+05 165 sudoite-Fe -20.96 -24.34 -3.38 -0.109 0.13462E+05 166 sudoite -18.86 -20.84 -1.99 -0.064 0.79034E+04 167 sulfur -9.81 -11.29 -1.48 -0.454 0.58692E+04 168 sylvite -0.16 -2.87 -2.71 -1.356 0.10784E+05 169 talc 5.01 3.68 -1.33 -0.078 0.52839E+04 170 talc-Fe 2.35 -1.57 -3.92 -0.230 0.15575E+05 171 talc-tschermaks -7.67 -9.35 -1.67 -0.098 0.66590E+04 173 tephroite 6.17 3.17 -3.00 -0.428 0.11920E+05 176 topaz-H -10.39 -12.41 -2.01 -0.183 0.80133E+04 177 tremolite 14.95 10.67 -4.28 -0.116 0.17013E+05 179 troilite-low -7.95 -8.92 -0.96 -0.321 0.38323E+04 180 tschermakite -11.92 -15.37 -3.45 -0.093 0.13714E+05 183 wadsleyite-Fe 2.66 0.48 -2.18 -0.311 0.86632E+04 184 wadsleyite-Mg 7.78 3.98 -3.80 -0.543 0.15122E+05 185 wairakite -10.81 -12.27 -1.46 -0.086 0.58056E+04 186 walstromite 4.61 1.97 -2.65 -0.529 0.10528E+05 187 wollastonite 4.22 1.97 -2.25 -0.451 0.89682E+04 188 pseudo-wollastonite 4.33 1.97 -2.36 -0.472 0.93905E+04 189 zoisite -12.02 -14.22 -2.20 -0.100 0.87302E+04 192 beidellite-Ca -15.14 -16.27 -1.13 -0.070 0.44781E+04 193 beidellite-H -15.14 -16.75 -1.60 -0.102 0.63731E+04 194 beidellite-K -14.08 -15.58 -1.50 -0.092 0.59718E+04 195 beidellite-Mg -15.47 -16.34 -0.87 -0.054 0.34799E+04 196 beidellite-Na -14.01 -15.41 -1.40 -0.086 0.55594E+04 199 chalcocite -12.80 -14.02 -1.21 -0.303 0.48268E+04 200 covellite -11.38 -12.65 -1.27 -0.485 0.50630E+04 202 montmorillonite-Ca -11.00 -11.97 -0.97 -0.060 0.38489E+04 203 montmorillonite-K -10.23 -11.28 -1.05 -0.064 0.41631E+04 204 montmorillonite-Mg -11.25 -12.04 -0.79 -0.049 0.31568E+04 205 montmorillonite-Na -9.86 -11.11 -1.26 -0.077 0.49937E+04 206 nontronite-Ca -3.27 -5.06 -1.79 -0.116 0.71118E+04 207 nontronite-H -3.28 -5.54 -2.26 -0.151 0.89748E+04 208 nontronite-K -2.21 -4.37 -2.16 -0.139 0.85971E+04 209 nontronite-Mg -3.53 -5.13 -1.60 -0.104 0.63639E+04 210 nontronite-Na -2.14 -4.20 -2.06 -0.132 0.81963E+04 215 gypsum -11.09 -13.44 -2.35 -0.587 0.93334E+04 232 alabandite -5.78 -7.57 -1.80 -0.598 0.71396E+04 234 anglesite -13.28 -16.02 -2.75 -1.373 0.10924E+05 237 barite -14.16 -14.32 -0.16 -0.080 0.63366E+03 238 boehmite -4.90 -5.75 -0.85 -0.141 0.33664E+04 240 chalcopyrite -21.43 -21.57 -0.14 -0.026 0.56295E+03 242 copper,native 1.81 -1.36 -3.18 -1.105 0.12634E+05 244 ferrous-oxide 1.70 0.70 -1.01 -0.252 0.40025E+04 245 galena -8.77 -9.32 -0.55 -0.183 0.21799E+04 246 silver,native 0.59 -3.74 -4.33 -1.507 0.17236E+05 248 litharge 5.20 0.29 -4.91 -1.227 0.19527E+05 255 sphalerite -10.18 -10.52 -0.34 -0.114 0.13549E+04 256 wurtzite -9.40 -10.52 -1.12 -0.372 0.44410E+04 257 zincite 1.86 -0.90 -2.76 -0.691 0.10995E+05 258 an20ab80 -5.62 -5.64 -0.02 -0.002 0.85640E+02 259 an25ab75 -5.93 -5.94 -0.01 -0.001 0.30056E+02 261 tr.625ac.25prg.125 9.20 6.76 -2.44 -0.066 0.97015E+04 Calculations done for 596.0000 Deg. C; 2060.0000 bar Temperature changed by -1.000 degrees to 595.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 500 Temperature = 595.00 C Pressure = 2000.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5501E+02 kg liquid = 0.9910E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9947 Stoichiometric ionic strength = .3311393E+01 Osmotic coef. = 0.0000 True ionic strength = .2754216E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17497E-04 -4.7570 0.52232E-05 -5.2821 0.29851E+00 -0.5250 2 H2O 0.99471E+00 -0.0023 0.99471E+00 -0.0023 3 Cl- 0.23373E+00 -0.6313 0.66107E-01 -1.1798 0.28284E+00 -0.5485 4 SO4-- 0.13898E-03 -3.8570 0.14612E-05 -5.8353 0.10513E-01 -1.9783 5 HCO3- 0.33188E-04 -4.4790 0.10058E-04 -4.9975 0.30307E+00 -0.5185 6 HS- 0.14787E-03 -3.8301 0.42149E-04 -4.3752 0.28503E+00 -0.5451 7 H4SiO4 0.11682E+00 -0.9325 0.11682E+00 -0.9325 0.10000E+01 0.0000 8 Al+++ 0.94002E-17 -17.0269 0.25683E-21 -21.5904 0.27322E-04 -4.5635 9 Ca++ 0.21172E-05 -5.6742 0.18342E-07 -7.7366 0.86633E-02 -2.0623 10 Mg++ 0.11579E-05 -5.9363 0.83821E-08 -8.0766 0.72388E-02 -2.1403 11 Fe++ 0.19201E-07 -7.7167 0.14551E-09 -9.8371 0.75780E-02 -2.1204 12 K+ 0.60652E-01 -1.2172 0.18821E-01 -1.7254 0.31031E+00 -0.5082 13 Na+ 0.21233E+00 -0.6730 0.60795E-01 -1.2161 0.28632E+00 -0.5431 14 Mn++ 0.42336E-06 -6.3733 0.33170E-08 -8.4793 0.78350E-02 -2.1060 15 Zn++ 0.48505E-09 -9.3142 0.36758E-11 -11.4347 0.75780E-02 -2.1204 16 Cu+ 0.11039E-06 -6.9571 0.31529E-07 -7.5013 0.28561E+00 -0.5442 17 Pb++ 0.57387E-08 -8.2412 0.55119E-10 -10.2587 0.96049E-02 -2.0175 18 Ag+ 0.46657E-09 -9.3311 0.14271E-09 -9.8456 0.30586E+00 -0.5145 19 Ba++ 0.28767E-06 -6.5411 0.29480E-08 -8.5305 0.10248E-01 -1.9894 20 HPO4-- 0.16245E-08 -8.7893 0.17156E-10 -10.7656 0.10561E-01 -1.9763 21 HSiO3- 0.23815E-05 -5.6232 0.67357E-06 -6.1716 0.28284E+00 -0.5485 22 Ca(HSiO3)+ 0.12083E-07 -7.9178 0.37797E-08 -8.4225 0.31282E+00 -0.5047 23 Mg(HSiO3)+ 0.13644E-08 -8.8650 0.42681E-09 -9.3698 0.31282E+00 -0.5047 24 NaHSiO3,aq 0.12392E-05 -5.9069 0.12392E-05 -5.9069 0.10000E+01 0.0000 28 AgCl,aq 0.68638E-07 -7.1634 0.68638E-07 -7.1634 0.10000E+01 0.0000 29 AgCl2- 0.50078E-05 -5.3004 0.14164E-05 -5.8488 0.28284E+00 -0.5485 30 AgCl3-2 0.26102E-05 -5.5833 0.25589E-07 -7.5919 0.98034E-02 -2.0086 31 AgCl4-3 0.10891E-05 -5.9629 0.25840E-10 -10.5877 0.23726E-04 -4.6248 34 Ag(HS),aq 0.47737E-09 -9.3211 0.47737E-09 -9.3211 0.10000E+01 0.0000 35 Ag(HS)2- 0.28296E-08 -8.5483 0.80031E-09 -9.0967 0.28284E+00 -0.5485 36 AlO+ 0.17693E-10 -10.7522 0.55346E-11 -11.2569 0.31282E+00 -0.5047 38 HAlO2,aq 0.57408E-08 -8.2410 0.57408E-08 -8.2410 0.10000E+01 0.0000 39 AlO2- 0.25856E-04 -4.5874 0.64534E-05 -5.1902 0.24958E+00 -0.6028 41 Ba(HCO3)+ 0.14964E-05 -5.8249 0.48535E-06 -6.3139 0.32434E+00 -0.4890 42 BaCl+ 0.54089E-04 -4.2669 0.16920E-04 -4.7716 0.31282E+00 -0.5047 43 CH4,aq 0.21222E-08 -8.6732 0.25915E-08 -8.5864 0.12211E+01 0.0868 48 CO,aq 0.91580E-03 -3.0382 0.91580E-03 -3.0382 0.10000E+01 0.0000 49 CO2,aq 0.26792E+01 0.4280 0.32716E+01 0.5148 0.12211E+01 0.0868 50 CO3-2 0.53544E-10 -10.2713 0.52491E-12 -12.2799 0.98034E-02 -2.0086 51 CaCO3,aq 0.12496E-10 -10.9032 0.12496E-10 -10.9032 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.69033E-06 -6.1609 0.21595E-06 -6.6657 0.31282E+00 -0.5047 53 CaCl+ 0.22596E-03 -3.6460 0.70683E-04 -4.1507 0.31282E+00 -0.5047 54 CaCl2,aq 0.10785E-03 -3.9672 0.10785E-03 -3.9672 0.10000E+01 0.0000 55 CaOH+ 0.29925E-06 -6.5240 0.93611E-07 -7.0287 0.31282E+00 -0.5047 56 CaSO4,aq 0.69426E-07 -7.1585 0.69426E-07 -7.1585 0.10000E+01 0.0000 57 HCl,aq 0.10545E-02 -2.9769 0.10545E-02 -2.9769 0.10000E+01 0.0000 66 CuCl,aq 0.62944E-04 -4.2010 0.62944E-04 -4.2010 0.10000E+01 0.0000 67 CuCl2- 0.24891E-03 -3.6040 0.70400E-04 -4.1524 0.28284E+00 -0.5485 68 CuCl3-2 0.67192E-05 -5.1727 0.65871E-07 -7.1813 0.98034E-02 -2.0086 74 FeCl+ 0.64228E-06 -6.1923 0.20091E-06 -6.6970 0.31282E+00 -0.5047 75 FeCl2,aq 0.88284E-02 -2.0541 0.88284E-02 -2.0541 0.10000E+01 0.0000 77 FeO,aq 0.56489E-07 -7.2480 0.56489E-07 -7.2480 0.10000E+01 0.0000 78 FeOH+ 0.42903E-07 -7.3675 0.13421E-07 -7.8722 0.31282E+00 -0.5047 79 HFeO2- 0.83044E-08 -8.0807 0.23488E-08 -8.6292 0.28284E+00 -0.5485 82 FeO2- 0.47119E-08 -8.3268 0.13327E-08 -8.8753 0.28284E+00 -0.5485 83 HFeO2,aq 0.14674E-09 -9.8335 0.14674E-09 -9.8335 0.10000E+01 0.0000 84 H2,aq 0.43863E-02 -2.3579 0.53562E-02 -2.2711 0.12211E+01 0.0868 85 KCl,aq 0.51022E-01 -1.2922 0.51022E-01 -1.2922 0.10000E+01 0.0000 86 KHSO4,aq 0.11934E-01 -1.9232 0.11934E-01 -1.9232 0.10000E+01 0.0000 87 KOH,aq 0.77965E-06 -6.1081 0.77965E-06 -6.1081 0.10000E+01 0.0000 88 KSO4- 0.29363E-02 -2.5322 0.83051E-03 -3.0807 0.28284E+00 -0.5485 90 Mg(HCO3)+ 0.13819E-06 -6.8595 0.43227E-07 -7.3642 0.31282E+00 -0.5047 91 MgCl+ 0.19008E-04 -4.7211 0.59460E-05 -5.2258 0.31282E+00 -0.5047 92 MgOH+ 0.55825E-06 -6.2532 0.17463E-06 -6.7579 0.31282E+00 -0.5047 94 MnO,aq 0.18937E-07 -7.7227 0.18937E-07 -7.7227 0.10000E+01 0.0000 95 MnOH+ 0.12380E-06 -6.9073 0.38726E-07 -7.4120 0.31282E+00 -0.5047 97 HMnO2- 0.13413E-10 -10.8725 0.37938E-11 -11.4209 0.28284E+00 -0.5485 100 MnCl+ 0.11593E-02 -2.9358 0.36265E-03 -3.4405 0.31282E+00 -0.5047 101 MnSO4,aq 0.16137E-07 -7.7922 0.16137E-07 -7.7922 0.10000E+01 0.0000 102 NaCl,aq 0.34683E+00 -0.4599 0.34683E+00 -0.4599 0.10000E+01 0.0000 103 NaOH,aq 0.11515E-05 -5.9387 0.11515E-05 -5.9387 0.10000E+01 0.0000 105 OH- 0.95867E-05 -5.0183 0.23927E-05 -5.6211 0.24958E+00 -0.6028 110 HPO3-2 0.31638E-10 -10.4998 0.31016E-12 -12.5084 0.98034E-02 -2.0086 111 H3PO3,aq 0.27037E-09 -9.5680 0.27037E-09 -9.5680 0.10000E+01 0.0000 112 H2PO3- 0.12768E-07 -7.8939 0.36112E-08 -8.4423 0.28284E+00 -0.5485 113 H3PO4,aq 0.16607E-05 -5.7797 0.16607E-05 -5.7797 0.10000E+01 0.0000 114 H2PO4- 0.39739E-05 -5.4008 0.11776E-05 -5.9290 0.29633E+00 -0.5282 116 H4P2O7,aq 0.22273E-09 -9.6522 0.22273E-09 -9.6522 0.10000E+01 0.0000 117 H3P2O7- 0.57387E-08 -8.2412 0.16231E-08 -8.7897 0.28284E+00 -0.5485 118 H2P2O7-2 0.14610E-05 -5.8353 0.14323E-07 -7.8440 0.98034E-02 -2.0086 119 HP2O7-3 0.30859E-07 -7.5106 0.73215E-12 -12.1354 0.23726E-04 -4.6248 121 PbCl+ 0.34575E-05 -5.4612 0.10816E-05 -5.9660 0.31282E+00 -0.5047 122 PbCl2,aq 0.99924E-04 -4.0003 0.99924E-04 -4.0003 0.10000E+01 0.0000 123 PbCl3- 0.11947E-03 -3.9227 0.33790E-04 -4.4712 0.28284E+00 -0.5485 124 PbCl4-2 0.31689E-04 -4.4991 0.31066E-06 -6.5077 0.98034E-02 -2.0086 125 PbO,aq 0.27400E-08 -8.5622 0.27400E-08 -8.5622 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.82651E-04 -4.0828 0.82651E-04 -4.0828 0.10000E+01 0.0000 128 Pb(HS)3- 0.60516E-05 -5.2181 0.17116E-05 -5.7666 0.28284E+00 -0.5485 129 H2S,aq 0.10410E+01 0.0175 0.12712E+01 0.1042 0.12211E+01 0.0868 130 S2-2 0.13315E-07 -7.8757 0.13053E-09 -9.8843 0.98034E-02 -2.0086 131 S3-2 0.14798E-08 -8.8298 0.14507E-10 -10.8384 0.98034E-02 -2.0086 132 S3- 0.24036E-01 -1.6191 0.67983E-02 -2.1676 0.28284E+00 -0.5485 133 S4-2 0.13605E-09 -9.8663 0.13337E-11 -11.8749 0.98034E-02 -2.0086 134 S5-2 0.10494E-10 -10.9791 0.10287E-12 -12.9877 0.98034E-02 -2.0086 135 SO2,aq 0.28276E+00 -0.5486 0.28276E+00 -0.5486 0.10000E+01 0.0000 136 SO3-2 0.55491E-09 -9.2558 0.82104E-11 -11.0856 0.14796E-01 -1.8299 137 HSO3- 0.46897E-03 -3.3289 0.13264E-03 -3.8773 0.28284E+00 -0.5485 138 HSO4- 0.12869E-01 -1.8904 0.41211E-02 -2.3850 0.32023E+00 -0.4945 140 S2O3-2 0.45470E-06 -6.3423 0.44576E-08 -8.3509 0.98034E-02 -2.0086 141 HS2O3- 0.83297E-06 -6.0794 0.23560E-06 -6.6278 0.28284E+00 -0.5485 142 H2S2O3,aq 0.24802E-07 -7.6055 0.24802E-07 -7.6055 0.10000E+01 0.0000 150 S4O6-2 0.70384E-09 -9.1525 0.69000E-11 -11.1611 0.98034E-02 -2.0086 152 ZnCl+ 0.75649E-03 -3.1212 0.23664E-03 -3.6259 0.31282E+00 -0.5047 153 ZnCl2,aq 0.13376E-02 -2.8737 0.13376E-02 -2.8737 0.10000E+01 0.0000 154 ZnCl3- 0.22287E-03 -3.6520 0.63035E-04 -4.2004 0.28284E+00 -0.5485 155 ZnO,aq 0.25699E-07 -7.5901 0.25699E-07 -7.5901 0.10000E+01 0.0000 156 ZnOH+ 0.31185E-05 -5.5061 0.97551E-06 -6.0108 0.31282E+00 -0.5047 158 HZnO2- 0.23708E-09 -9.6251 0.67054E-10 -10.1736 0.28284E+00 -0.5485 Charge balance for all species = 0.2554E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1749747E-04 0.4303855E+01 0.3527525E+04 0.0000 2 H2O 0.1000000E+01 0.5248973E+02 0.7689421E+06 0.0000 3 Cl- 0.2337273E+00 0.6573559E+00 0.1895096E+05 4.1023 4 SO4-- 0.1389829E-03 0.2539986E+00 0.1984078E+05 4.7288 5 HCO3- 0.3318803E-04 0.2680149E+01 0.1329808E+06 0.2846 6 HS- 0.1478727E-03 0.1170577E+01 0.3148025E+05 0.9068 7 H4SiO4 0.1168204E+00 0.1168240E+00 0.9130673E+04 -0.9325 8 Al+++ 0.9400168E-17 0.2586220E-04 0.5674261E+00 -5.7442 9 Ca++ 0.2117196E-05 0.3369940E-03 0.1098262E+02 2.8276 10 Mg++ 0.1157937E-05 0.2086376E-04 0.4124687E+00 2.4875 11 Fe++ 0.1920146E-07 0.8829177E-02 0.4009570E+03 0.7270 12 K+ 0.6065156E-01 0.1265450E+00 0.4023664E+04 3.5567 13 Na+ 0.2123309E+00 0.5591614E+00 0.1045322E+05 4.0659 14 Mn++ 0.4233573E-06 0.1159902E-02 0.5181696E+02 2.0849 15 Zn++ 0.4850542E-09 0.2320142E-02 0.1233306E+03 -0.8705 16 Cu+ 0.1103894E-06 0.3186792E-03 0.1646564E+02 -2.2192 17 Pb++ 0.5738655E-08 0.3432510E-03 0.5783068E+02 0.3054 18 Ag+ 0.4665719E-09 0.8779578E-05 0.7701088E+00 -4.5635 19 Ba++ 0.2876660E-06 0.5587353E-04 0.6239947E+01 2.0337 20 HPO4-- 0.1624484E-08 0.8645030E-05 0.6747152E+00 -0.2014 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265257E+01 -.2895305E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5201900E+02 -.5422084E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517207E+00 0.2094712E-05 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160079E+01 0.6493607E-04 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1157763E+00 0.2781801E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2563026E-04 0.6689093E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3339718E-03 0.1939381E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8749996E-02 0.1675770E-04 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5541468E+00 0.4525223E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3158212E-03 0.8378848E-04 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.7589E-18 Mass of aqueous solution: 0.121874E+04 g Temperature = 595.00 C Pressure = 2000.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) andalusite -.8574E-04 1.000 -.1389E-01 1.000 -.7991 -.4418E-02 quartz 0.2616E-01 -1.582 1.572 0.196 90.39 0.5935 bornite 0.1676E-04 -4.776 0.8409E-02 -2.075 0.4836 0.1654E-02 an30ab70 0.6465E-03 -3.189 0.1726 -0.763 9.928 0.6482E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity andalusite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.738722 g Volume = 0.655558 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 144 quartz -0.93 -0.93 0.00 0.000 0.00000E+00 197 bornite -49.84 -49.84 0.00 0.000 -0.28226E-10 260 an30ab70 -6.28 -6.28 0.00 0.000 -0.28226E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.295 0.11707E+04 3.006 2 CO2,gas -8.91 -10.28 -1.37 -0.456 0.54305E+04 1.934 3 CH4,gas 6.90 -3.54 -10.44 -2.610 0.41468E+05 -7.138 4 H2,gas 5.73 1.68 -4.05 -2.312 0.16071E+05 -0.745 5 H2S,gas -7.40 -9.66 -2.26 -1.128 0.89597E+04 1.046 6 CO,gas -3.04 -8.59 -5.56 -1.709 0.22068E+05 -2.254 7 SO3,gas -6.23 -16.40 -10.17 -2.543 0.40404E+05 -6.870 8 O2,gas 16.46 -3.37 -19.83 -13.223 0.78792E+05 -16.533 9 HCl,gas -5.54 -6.46 -0.92 -0.462 0.36738E+04 -0.925 10 acmite 3.99 2.09 -1.90 -0.198 0.75533E+04 12 akimotoite 5.82 1.56 -4.26 -0.852 0.16928E+05 13 akimotoite-Fe 3.81 -0.20 -4.01 -0.803 0.15948E+05 14 albite-high -4.34 -4.47 -0.13 -0.010 0.51681E+03 15 albite -4.30 -4.47 -0.17 -0.013 0.65833E+03 16 almandine -10.48 -12.10 -1.63 -0.081 0.64697E+04 17 pyrope -4.14 -6.82 -2.68 -0.134 0.10658E+05 18 analcite -2.61 -3.54 -0.93 -0.103 0.36990E+04 19 andalusite -12.42 -12.42 0.00 0.000 -0.21170E-10 22 anhydrite -13.25 -13.57 -0.32 -0.159 0.12607E+04 24 annite -0.71 -2.80 -2.09 -0.116 0.83174E+04 25 phlogopite 3.67 2.48 -1.20 -0.066 0.47515E+04 27 anorthite -10.03 -10.53 -0.50 -0.038 0.19708E+04 28 anthophyllite 13.65 9.97 -3.67 -0.099 0.14598E+05 29 anthophyllite-Fe 1.65 -2.35 -4.01 -0.108 0.15910E+05 30 apatite-OH -49.22 -49.85 -0.63 -0.049 0.25068E+04 31 apatite-OH-zs -47.14 -49.85 -2.71 -0.208 0.10764E+05 32 apatite-Cl-zs -52.71 -56.31 -3.60 -0.300 0.14305E+05 33 aragonite -3.89 -7.45 -3.56 -1.187 0.14152E+05 34 brucite 4.88 2.48 -2.40 -0.480 0.95400E+04 35 calcite -3.98 -7.45 -3.48 -1.159 0.13809E+05 36 carnegieite-low -0.86 -2.61 -1.75 -0.251 0.69697E+04 37 carnegieite-high -0.79 -2.61 -1.82 -0.259 0.72155E+04 38 carpholite-Mg -9.19 -10.87 -1.68 -0.112 0.66726E+04 39 carpholite-Fe -10.48 -12.63 -2.15 -0.143 0.85395E+04 40 celadonite -1.14 -3.42 -2.28 -0.134 0.90730E+04 41 celadonite-Fe -2.48 -5.18 -2.70 -0.159 0.10712E+05 42 chrysotile 8.63 5.60 -3.03 -0.253 0.12050E+05 44 clinochlore 0.22 -1.86 -2.08 -0.065 0.82647E+04 45 daphnite -6.51 -10.66 -4.15 -0.130 0.16503E+05 48 chloritoid-Mg -8.92 -9.94 -1.02 -0.068 0.40634E+04 49 chloritoid-Fe -10.75 -11.70 -0.95 -0.063 0.37757E+04 50 chloritoid-Mn -8.59 -10.34 -1.76 -0.117 0.69787E+04 52 coesite -0.66 -0.93 -0.27 -0.090 0.10746E+04 53 cordierite-H -22.35 -22.66 -0.31 -0.011 0.12328E+04 54 cordierite-Fe -24.66 -26.18 -1.52 -0.053 0.60514E+04 55 cordierite-Mn -20.25 -23.46 -3.22 -0.111 0.12780E+05 56 corundum -11.34 -11.50 -0.16 -0.014 0.62319E+03 58 cristobalite -0.87 -0.93 -0.06 -0.020 0.23239E+03 59 cummingtonite 13.70 9.97 -3.73 -0.101 0.14805E+05 61 cymrite-K -2.77 -4.98 -2.21 -0.184 0.87783E+04 63 diaspore -5.17 -5.75 -0.58 -0.096 0.22863E+04 65 diopside 5.25 3.45 -1.80 -0.180 0.71314E+04 66 hedenbergite 3.90 1.69 -2.20 -0.220 0.87540E+04 68 eastonite -9.27 -10.58 -1.30 -0.050 0.51788E+04 69 enstatite 4.38 3.11 -1.26 -0.126 0.50139E+04 70 clinoenstatite-HiP 4.85 3.11 -1.73 -0.173 0.68904E+04 71 clinoenstatite 4.37 3.11 -1.25 -0.125 0.49702E+04 72 protoenstatite 4.51 3.11 -1.39 -0.139 0.55338E+04 73 epidote -6.35 -8.75 -2.40 -0.116 0.95342E+04 74 clinozoisite -12.01 -14.38 -2.37 -0.108 0.94128E+04 75 epidote-Fe 0.97 -3.12 -4.08 -0.212 0.16222E+05 76 fayalite 1.82 0.52 -1.30 -0.186 0.51720E+04 77 ferrosilite 0.98 -0.41 -1.38 -0.138 0.54923E+04 78 forsterite 5.63 4.04 -1.59 -0.227 0.63184E+04 79 gedrite -13.98 -16.13 -2.15 -0.058 0.85401E+04 81 gibbsite -3.62 -5.75 -2.13 -0.305 0.84811E+04 82 glaucophane 0.35 -3.34 -3.69 -0.100 0.14648E+05 84 goethite 0.89 -0.12 -1.01 -0.217 0.39952E+04 86 greenalite 4.03 0.31 -3.72 -0.310 0.14763E+05 87 grunerite 2.17 -2.35 -4.52 -0.122 0.17971E+05 88 halite -0.29 -2.40 -2.11 -1.055 0.83855E+04 89 hematite 0.30 -0.24 -0.53 -0.064 0.21108E+04 90 heulandite -12.58 -15.18 -2.60 -0.118 0.10335E+05 91 hercynite -9.98 -10.77 -0.79 -0.053 0.31285E+04 94 jadeite -1.94 -3.54 -1.60 -0.160 0.63440E+04 96 kalsilite -1.50 -3.12 -1.62 -0.231 0.64358E+04 97 kaolinite -11.12 -13.36 -2.24 -0.203 0.88810E+04 98 kyanite -12.29 -12.42 -0.14 -0.014 0.54026E+03 100 laumontite -9.17 -12.39 -3.22 -0.214 0.12781E+05 101 lawsonite -7.41 -10.53 -3.12 -0.208 0.12405E+05 102 leucite -3.07 -4.05 -0.98 -0.098 0.39018E+04 104 lizardite 8.82 5.60 -3.23 -0.269 0.12830E+05 105 magnesite -4.95 -7.79 -2.84 -0.947 0.11282E+05 106 magnetite 1.15 0.49 -0.66 -0.054 0.26220E+04 107 minnesotaite 0.95 -1.54 -2.49 -0.147 0.99002E+04 108 minnesotaite-Mg 6.64 3.74 -2.90 -0.171 0.11517E+05 109 magnesioferrite 4.09 2.25 -1.84 -0.150 0.73171E+04 111 manganosite 4.98 2.08 -2.89 -0.723 0.11493E+05 112 margarite -20.93 -22.02 -1.10 -0.044 0.43550E+04 115 microcline -4.90 -4.98 -0.08 -0.006 0.31810E+03 116 monticellite 8.30 4.38 -3.91 -0.559 0.15551E+05 118 mullite-Si -11.72 -12.42 -0.70 -0.070 0.27907E+04 119 muscovite -16.14 -16.47 -0.34 -0.020 0.13392E+04 120 paragonite -15.45 -15.96 -0.51 -0.030 0.20325E+04 121 nepheline -1.14 -2.61 -1.47 -0.209 0.58246E+04 122 osumilite(2) -14.22 -16.44 -2.22 -0.046 0.88097E+04 123 osumilite-Fe -31.10 -33.01 -1.91 -0.040 0.75811E+04 124 pargasite 1.55 -3.16 -4.71 -0.124 0.18713E+05 125 periclase 5.08 2.49 -2.59 -0.649 0.10305E+05 126 periclase-Fe 2.60 0.72 -1.88 -0.470 0.74670E+04 127 perovskite-Al -9.66 -11.50 -1.83 -0.166 0.72732E+04 132 phlogopite-Na 4.54 2.99 -1.56 -0.086 0.61807E+04 134 prehnite -5.36 -8.63 -3.27 -0.192 0.12995E+05 135 prehnite-Fe 0.70 -3.00 -3.70 -0.223 0.14698E+05 138 px-Mg-tschermaks -8.36 -9.94 -1.58 -0.113 0.62585E+04 139 px-Ca-tschermaks -7.30 -9.60 -2.29 -0.164 0.91089E+04 140 pyrite -20.01 -20.27 -0.27 -0.063 0.10553E+04 141 pyrrhotite -8.10 -8.93 -0.83 -0.277 0.33042E+04 142 pyrrhotiteFe0.875 -8.79 -9.23 -0.44 -0.161 0.17424E+04 143 pyrophyllite -14.37 -15.21 -0.84 -0.053 0.33421E+04 146 riebeckite 6.75 2.64 -4.11 -0.113 0.16313E+05 147 ringwoodite-Fe 2.79 0.52 -2.27 -0.324 0.90189E+04 148 ringwoodite-Mg 8.68 4.04 -4.64 -0.663 0.18442E+05 149 rhodochrosite -4.79 -8.19 -3.41 -1.136 0.13543E+05 150 rhodonite 2.47 1.15 -1.31 -0.263 0.52201E+04 151 sanidine -4.38 -4.98 -0.60 -0.046 0.23833E+04 152 sapphirine(351) -47.23 -50.95 -3.72 -0.056 0.14784E+05 153 siderite -6.69 -9.55 -2.86 -0.954 0.11367E+05 154 sillimanite -12.40 -12.42 -0.02 -0.002 0.92857E+02 156 spinel -7.90 -9.01 -1.11 -0.074 0.44018E+04 158 staurolite-Fe -104.76 -107.52 -2.76 -0.025 0.10979E+05 159 staurolite-Mg -96.70 -100.48 -3.78 -0.035 0.15011E+05 163 stilpnomelane-Mg -2.03 -4.73 -2.70 -0.081 0.10726E+05 164 stishovite 1.92 -0.93 -2.84 -0.948 0.11294E+05 165 sudoite-Fe -21.00 -24.33 -3.34 -0.108 0.13260E+05 166 sudoite -18.89 -20.81 -1.92 -0.062 0.76237E+04 167 sulfur -9.86 -11.34 -1.48 -0.454 0.58660E+04 168 sylvite -0.20 -2.91 -2.70 -1.352 0.10742E+05 169 talc 4.95 3.74 -1.20 -0.071 0.47840E+04 170 talc-Fe 2.28 -1.54 -3.82 -0.225 0.15188E+05 171 talc-tschermaks -7.72 -9.31 -1.59 -0.094 0.63260E+04 173 tephroite 6.15 3.24 -2.91 -0.416 0.11558E+05 176 topaz-H -10.40 -12.43 -2.02 -0.184 0.80321E+04 177 tremolite 14.83 10.65 -4.18 -0.113 0.16593E+05 179 troilite-low -8.00 -8.93 -0.93 -0.310 0.36980E+04 180 tschermakite -12.02 -15.45 -3.43 -0.093 0.13624E+05 183 wadsleyite-Fe 2.64 0.52 -2.12 -0.302 0.84081E+04 184 wadsleyite-Mg 7.77 4.04 -3.72 -0.532 0.14792E+05 185 wairakite -10.88 -12.39 -1.51 -0.089 0.59989E+04 186 walstromite 4.60 1.90 -2.70 -0.540 0.10732E+05 187 wollastonite 4.21 1.90 -2.31 -0.462 0.91685E+04 188 pseudo-wollastonite 4.31 1.90 -2.41 -0.483 0.95911E+04 189 zoisite -12.07 -14.38 -2.30 -0.105 0.91566E+04 192 beidellite-Ca -15.20 -16.33 -1.14 -0.070 0.45223E+04 193 beidellite-H -15.19 -16.80 -1.61 -0.103 0.63836E+04 194 beidellite-K -14.13 -15.63 -1.50 -0.092 0.59557E+04 195 beidellite-Mg -15.52 -16.39 -0.87 -0.054 0.34701E+04 196 beidellite-Na -14.06 -15.46 -1.40 -0.085 0.55449E+04 199 chalcocite -12.87 -14.10 -1.23 -0.307 0.48812E+04 200 covellite -11.44 -12.72 -1.28 -0.488 0.50848E+04 202 montmorillonite-Ca -11.06 -12.03 -0.97 -0.060 0.38342E+04 203 montmorillonite-K -10.29 -11.32 -1.03 -0.063 0.40923E+04 204 montmorillonite-Mg -11.31 -12.08 -0.78 -0.048 0.30794E+04 205 montmorillonite-Na -9.91 -11.15 -1.24 -0.076 0.49164E+04 206 nontronite-Ca -3.34 -5.07 -1.74 -0.113 0.68929E+04 207 nontronite-H -3.35 -5.54 -2.20 -0.147 0.87224E+04 208 nontronite-K -2.27 -4.37 -2.09 -0.134 0.83178E+04 209 nontronite-Mg -3.60 -5.13 -1.53 -0.099 0.60849E+04 210 nontronite-Na -2.21 -4.20 -1.99 -0.128 0.79194E+04 215 gypsum -11.17 -13.58 -2.41 -0.602 0.95706E+04 232 alabandite -5.82 -7.57 -1.75 -0.584 0.69555E+04 234 anglesite -13.37 -16.09 -2.73 -1.363 0.10832E+05 237 barite -14.25 -14.37 -0.11 -0.057 0.45641E+03 238 boehmite -4.90 -5.75 -0.85 -0.142 0.33728E+04 240 chalcopyrite -21.53 -21.65 -0.11 -0.021 0.45094E+03 242 copper,native 1.81 -1.38 -3.19 -1.108 0.12655E+05 244 ferrous-oxide 1.70 0.72 -0.98 -0.244 0.38758E+04 245 galena -8.83 -9.35 -0.52 -0.174 0.20681E+04 246 silver,native 0.59 -3.72 -4.31 -1.498 0.17113E+05 248 litharge 5.19 0.30 -4.89 -1.222 0.19419E+05 255 sphalerite -10.23 -10.53 -0.30 -0.100 0.11890E+04 256 wurtzite -9.45 -10.53 -1.08 -0.359 0.42761E+04 257 zincite 1.86 -0.87 -2.73 -0.682 0.10838E+05 258 an20ab80 -5.66 -5.68 -0.01 -0.001 0.57894E+02 259 an25ab75 -5.98 -5.98 0.00 0.000 0.15540E+02 261 tr.625ac.25prg.125 9.08 6.72 -2.35 -0.063 0.93524E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 18 Loop limit = 500 Temperature = 595.00 C Pressure = 2000.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5501E+02 kg liquid = 0.9910E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9947 Stoichiometric ionic strength = .3311516E+01 Osmotic coef. = 0.0000 True ionic strength = .2755167E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17441E-04 -4.7584 0.52058E-05 -5.2835 0.29847E+00 -0.5251 2 H2O 0.99471E+00 -0.0023 0.99471E+00 -0.0023 3 Cl- 0.23370E+00 -0.6313 0.66091E-01 -1.1799 0.28280E+00 -0.5485 4 SO4-- 0.13988E-03 -3.8542 0.14699E-05 -5.8327 0.10508E-01 -1.9785 5 HCO3- 0.33303E-04 -4.4775 0.10092E-04 -4.9960 0.30304E+00 -0.5185 6 HS- 0.14837E-03 -3.8287 0.42285E-04 -4.3738 0.28500E+00 -0.5452 7 H4SiO4 0.11682E+00 -0.9325 0.11682E+00 -0.9325 0.10000E+01 0.0000 8 Al+++ 0.90489E-17 -17.0434 0.24693E-21 -21.6074 0.27288E-04 -4.5640 9 Ca++ 0.23690E-05 -5.6254 0.20512E-07 -7.6880 0.86585E-02 -2.0626 10 Mg++ 0.11586E-05 -5.9361 0.83819E-08 -8.0767 0.72345E-02 -2.1406 11 Fe++ 0.19221E-07 -7.7162 0.14557E-09 -9.8369 0.75736E-02 -2.1207 12 K+ 0.60637E-01 -1.2173 0.18814E-01 -1.7255 0.31028E+00 -0.5082 13 Na+ 0.21241E+00 -0.6728 0.60811E-01 -1.2160 0.28629E+00 -0.5432 14 Mn++ 0.42366E-06 -6.3730 0.33174E-08 -8.4792 0.78305E-02 -2.1062 15 Zn++ 0.48551E-09 -9.3138 0.36771E-11 -11.4345 0.75736E-02 -2.1207 16 Cu+ 0.10989E-06 -6.9590 0.31382E-07 -7.5033 0.28558E+00 -0.5443 17 Pb++ 0.57339E-08 -8.2416 0.55044E-10 -10.2593 0.95999E-02 -2.0177 18 Ag+ 0.46671E-09 -9.3309 0.14273E-09 -9.8455 0.30583E+00 -0.5145 19 Ba++ 0.28782E-06 -6.5409 0.29481E-08 -8.5305 0.10243E-01 -1.9896 20 HPO4-- 0.16312E-08 -8.7875 0.17219E-10 -10.7640 0.10556E-01 -1.9765 21 HSiO3- 0.23898E-05 -5.6216 0.67583E-06 -6.1702 0.28280E+00 -0.5485 22 Ca(HSiO3)+ 0.13559E-07 -7.8678 0.42409E-08 -8.3725 0.31278E+00 -0.5048 23 Mg(HSiO3)+ 0.13691E-08 -8.8636 0.42823E-09 -9.3683 0.31278E+00 -0.5048 24 NaHSiO3,aq 0.12436E-05 -5.9053 0.12436E-05 -5.9053 0.10000E+01 0.0000 28 AgCl,aq 0.68635E-07 -7.1635 0.68635E-07 -7.1635 0.10000E+01 0.0000 29 AgCl2- 0.50071E-05 -5.3004 0.14160E-05 -5.8489 0.28280E+00 -0.5485 30 AgCl3-2 0.26103E-05 -5.5833 0.25576E-07 -7.5922 0.97982E-02 -2.0089 31 AgCl4-3 0.10897E-05 -5.9627 0.25822E-10 -10.5880 0.23695E-04 -4.6253 34 Ag(HS),aq 0.47901E-09 -9.3197 0.47901E-09 -9.3197 0.10000E+01 0.0000 35 Ag(HS)2- 0.28489E-08 -8.5453 0.80567E-09 -9.0938 0.28280E+00 -0.5485 36 AlO+ 0.17127E-10 -10.7663 0.53569E-11 -11.2711 0.31278E+00 -0.5048 38 HAlO2,aq 0.55751E-08 -8.2537 0.55751E-08 -8.2537 0.10000E+01 0.0000 39 AlO2- 0.25198E-04 -4.5986 0.62881E-05 -5.2015 0.24954E+00 -0.6029 41 Ba(HCO3)+ 0.15016E-05 -5.8234 0.48699E-06 -6.3125 0.32431E+00 -0.4890 42 BaCl+ 0.54084E-04 -4.2669 0.16917E-04 -4.7717 0.31278E+00 -0.5048 43 CH4,aq 0.21235E-08 -8.6729 0.25931E-08 -8.5862 0.12211E+01 0.0868 48 CO,aq 0.91595E-03 -3.0381 0.91595E-03 -3.0381 0.10000E+01 0.0000 49 CO2,aq 0.26792E+01 0.4280 0.32717E+01 0.5148 0.12211E+01 0.0868 50 CO3-2 0.53932E-10 -10.2682 0.52844E-12 -12.2770 0.97982E-02 -2.0089 51 CaCO3,aq 0.14068E-10 -10.8518 0.14068E-10 -10.8518 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.77466E-06 -6.1109 0.24230E-06 -6.6156 0.31278E+00 -0.5048 53 CaCl+ 0.25265E-03 -3.5975 0.79026E-04 -4.1022 0.31278E+00 -0.5048 54 CaCl2,aq 0.12055E-03 -3.9188 0.12055E-03 -3.9188 0.10000E+01 0.0000 55 CaOH+ 0.33581E-06 -6.4739 0.10504E-06 -6.9787 0.31278E+00 -0.5048 56 CaSO4,aq 0.78103E-07 -7.1073 0.78103E-07 -7.1073 0.10000E+01 0.0000 57 HCl,aq 0.10508E-02 -2.9785 0.10508E-02 -2.9785 0.10000E+01 0.0000 66 CuCl,aq 0.62636E-04 -4.2032 0.62636E-04 -4.2032 0.10000E+01 0.0000 67 CuCl2- 0.24766E-03 -3.6061 0.70040E-04 -4.1547 0.28280E+00 -0.5485 68 CuCl3-2 0.66868E-05 -5.1748 0.65518E-07 -7.1836 0.97982E-02 -2.0089 74 FeCl+ 0.64247E-06 -6.1921 0.20095E-06 -6.6969 0.31278E+00 -0.5048 75 FeCl2,aq 0.88281E-02 -2.0541 0.88281E-02 -2.0541 0.10000E+01 0.0000 77 FeO,aq 0.56892E-07 -7.2449 0.56892E-07 -7.2449 0.10000E+01 0.0000 78 FeOH+ 0.43069E-07 -7.3658 0.13471E-07 -7.8706 0.31278E+00 -0.5048 79 HFeO2- 0.83928E-08 -8.0761 0.23735E-08 -8.6246 0.28280E+00 -0.5485 82 FeO2- 0.47616E-08 -8.3222 0.13466E-08 -8.8708 0.28280E+00 -0.5485 83 HFeO2,aq 0.14777E-09 -9.8304 0.14777E-09 -9.8304 0.10000E+01 0.0000 84 H2,aq 0.43869E-02 -2.3578 0.53570E-02 -2.2711 0.12211E+01 0.0868 85 KCl,aq 0.50993E-01 -1.2925 0.50993E-01 -1.2925 0.10000E+01 0.0000 86 KHSO4,aq 0.11961E-01 -1.9222 0.11961E-01 -1.9222 0.10000E+01 0.0000 87 KOH,aq 0.78199E-06 -6.1068 0.78199E-06 -6.1068 0.10000E+01 0.0000 88 KSO4- 0.29532E-02 -2.5297 0.83518E-03 -3.0782 0.28280E+00 -0.5485 90 Mg(HCO3)+ 0.13866E-06 -6.8580 0.43371E-07 -7.3628 0.31278E+00 -0.5048 91 MgCl+ 0.19005E-04 -4.7211 0.59445E-05 -5.2259 0.31278E+00 -0.5048 92 MgOH+ 0.56016E-06 -6.2517 0.17521E-06 -6.7564 0.31278E+00 -0.5048 94 MnO,aq 0.19067E-07 -7.7197 0.19067E-07 -7.7197 0.10000E+01 0.0000 95 MnOH+ 0.12424E-06 -6.9057 0.38861E-07 -7.4105 0.31278E+00 -0.5048 97 HMnO2- 0.13552E-10 -10.8680 0.38326E-11 -11.4165 0.28280E+00 -0.5485 100 MnCl+ 0.11593E-02 -2.9358 0.36262E-03 -3.4406 0.31278E+00 -0.5048 101 MnSO4,aq 0.16236E-07 -7.7895 0.16236E-07 -7.7895 0.10000E+01 0.0000 102 NaCl,aq 0.34684E+00 -0.4599 0.34684E+00 -0.4599 0.10000E+01 0.0000 103 NaOH,aq 0.11556E-05 -5.9372 0.11556E-05 -5.9372 0.10000E+01 0.0000 105 OH- 0.96203E-05 -5.0168 0.24007E-05 -5.6197 0.24954E+00 -0.6029 110 HPO3-2 0.31775E-10 -10.4979 0.31134E-12 -12.5068 0.97982E-02 -2.0089 111 H3PO3,aq 0.26959E-09 -9.5693 0.26959E-09 -9.5693 0.10000E+01 0.0000 112 H2PO3- 0.12775E-07 -7.8936 0.36128E-08 -8.4422 0.28280E+00 -0.5485 113 H3PO4,aq 0.16557E-05 -5.7810 0.16557E-05 -5.7810 0.10000E+01 0.0000 114 H2PO4- 0.39754E-05 -5.4006 0.11779E-05 -5.9289 0.29630E+00 -0.5283 116 H4P2O7,aq 0.22137E-09 -9.6549 0.22137E-09 -9.6549 0.10000E+01 0.0000 117 H3P2O7- 0.57235E-08 -8.2423 0.16186E-08 -8.7909 0.28280E+00 -0.5485 118 H2P2O7-2 0.14626E-05 -5.8349 0.14331E-07 -7.8437 0.97982E-02 -2.0089 119 HP2O7-3 0.31020E-07 -7.5084 0.73502E-12 -12.1337 0.23695E-04 -4.6253 121 PbCl+ 0.34523E-05 -5.4619 0.10798E-05 -5.9666 0.31278E+00 -0.5048 122 PbCl2,aq 0.99742E-04 -4.0011 0.99742E-04 -4.0011 0.10000E+01 0.0000 123 PbCl3- 0.11924E-03 -3.9236 0.33721E-04 -4.4721 0.28280E+00 -0.5485 124 PbCl4-2 0.31633E-04 -4.4999 0.30995E-06 -6.5087 0.97982E-02 -2.0089 125 PbO,aq 0.27546E-08 -8.5599 0.27546E-08 -8.5599 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.83074E-04 -4.0805 0.83074E-04 -4.0805 0.10000E+01 0.0000 128 Pb(HS)3- 0.61031E-05 -5.2145 0.17260E-05 -5.7630 0.28280E+00 -0.5485 129 H2S,aq 0.10409E+01 0.0174 0.12711E+01 0.1042 0.12211E+01 0.0868 130 S2-2 0.13406E-07 -7.8727 0.13136E-09 -9.8815 0.97982E-02 -2.0089 131 S3-2 0.14896E-08 -8.8269 0.14595E-10 -10.8358 0.97982E-02 -2.0089 132 S3- 0.24102E-01 -1.6179 0.68161E-02 -2.1665 0.28280E+00 -0.5485 133 S4-2 0.13691E-09 -9.8636 0.13415E-11 -11.8724 0.97982E-02 -2.0089 134 S5-2 0.10557E-10 -10.9764 0.10344E-12 -12.9853 0.97982E-02 -2.0089 135 SO2,aq 0.28260E+00 -0.5488 0.28260E+00 -0.5488 0.10000E+01 0.0000 136 SO3-2 0.55855E-09 -9.2529 0.82607E-11 -11.0830 0.14790E-01 -1.8300 137 HSO3- 0.47032E-03 -3.3276 0.13301E-03 -3.8761 0.28280E+00 -0.5485 138 HSO4- 0.12904E-01 -1.8893 0.41319E-02 -2.3838 0.32020E+00 -0.4946 140 S2O3-2 0.45761E-06 -6.3395 0.44838E-08 -8.3484 0.97982E-02 -2.0089 141 HS2O3- 0.83516E-06 -6.0782 0.23619E-06 -6.6267 0.28280E+00 -0.5485 142 H2S2O3,aq 0.24781E-07 -7.6059 0.24781E-07 -7.6059 0.10000E+01 0.0000 150 S4O6-2 0.70764E-09 -9.1502 0.69336E-11 -11.1590 0.97982E-02 -2.0089 152 ZnCl+ 0.75666E-03 -3.1211 0.23667E-03 -3.6259 0.31278E+00 -0.5048 153 ZnCl2,aq 0.13375E-02 -2.8737 0.13375E-02 -2.8737 0.10000E+01 0.0000 154 ZnCl3- 0.22282E-03 -3.6520 0.63014E-04 -4.2006 0.28280E+00 -0.5485 155 ZnO,aq 0.25881E-07 -7.5870 0.25881E-07 -7.5870 0.10000E+01 0.0000 156 ZnOH+ 0.31304E-05 -5.5044 0.97913E-06 -6.0092 0.31278E+00 -0.5048 158 HZnO2- 0.23958E-09 -9.6205 0.67755E-10 -10.1691 0.28280E+00 -0.5485 Charge balance for all species = 0.2554E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1744127E-04 0.4303679E+01 0.3527372E+04 0.0000 2 H2O 0.1000000E+01 0.5248974E+02 0.7689402E+06 0.0000 3 Cl- 0.2337018E+00 0.6573549E+00 0.1895089E+05 4.1037 4 SO4-- 0.1398844E-03 0.2539981E+00 0.1984070E+05 4.7343 5 HCO3- 0.3330290E-04 0.2680145E+01 0.1329803E+06 0.2875 6 HS- 0.1483698E-03 0.1170574E+01 0.3148009E+05 0.9097 7 H4SiO4 0.1168203E+00 0.1168239E+00 0.9130646E+04 -0.9325 8 Al+++ 0.9048867E-17 0.2520387E-04 0.5529807E+00 -5.7569 9 Ca++ 0.2368956E-05 0.3767740E-03 0.1227902E+02 2.8790 10 Mg++ 0.1158597E-05 0.2086373E-04 0.4124671E+00 2.4904 11 Fe++ 0.1922092E-07 0.8828847E-02 0.4009410E+03 0.7301 12 K+ 0.6063676E-01 0.1265448E+00 0.4023648E+04 3.5580 13 Na+ 0.2124123E+00 0.5592534E+00 0.1045492E+05 4.0675 14 Mn++ 0.4236578E-06 0.1159900E-02 0.5181675E+02 2.0878 15 Zn++ 0.4855135E-09 0.2320138E-02 0.1233301E+03 -0.8675 16 Cu+ 0.1098889E-06 0.3170957E-03 0.1638378E+02 -2.2198 17 Pb++ 0.5733854E-08 0.3432504E-03 0.5783045E+02 0.3077 18 Ag+ 0.4667136E-09 0.8779564E-05 0.7701057E+00 -4.5620 19 Ba++ 0.2878230E-06 0.5587344E-04 0.6239922E+01 2.0366 20 HPO4-- 0.1631216E-08 0.8645016E-05 0.6747125E+00 -0.1970 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265090E+01 -.2727327E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5201908E+02 -.5430521E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517206E+00 0.2133932E-05 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160078E+01 0.6615190E-04 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1157764E+00 0.2781790E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2497788E-04 0.6695616E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3733957E-03 0.1545142E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8749682E-02 0.1707146E-04 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542388E+00 0.3605332E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3142524E-03 0.8535729E-04 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1355E-18 Mass of aqueous solution: 0.121874E+04 g Temperature = 595.00 C Pressure = 2000.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) quartz 0.2643E-01 -1.578 1.588 0.201 91.57 0.5996 bornite 0.1707E-04 -4.768 0.8566E-02 -2.067 0.4941 0.1685E-02 an30ab70 0.5150E-03 -3.288 0.1375 -0.862 7.932 0.5164E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.733844 g Volume = 0.652933 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 144 quartz -0.93 -0.93 0.00 0.000 0.00000E+00 197 bornite -49.84 -49.84 0.00 0.000 0.00000E+00 260 an30ab70 -6.28 -6.28 0.00 0.000 -0.14113E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.295 0.11707E+04 3.006 2 CO2,gas -8.91 -10.28 -1.37 -0.456 0.54305E+04 1.934 3 CH4,gas 6.90 -3.54 -10.44 -2.610 0.41467E+05 -7.138 4 H2,gas 5.73 1.68 -4.05 -2.312 0.16071E+05 -0.744 5 H2S,gas -7.40 -9.66 -2.26 -1.128 0.89599E+04 1.046 6 CO,gas -3.04 -8.59 -5.56 -1.709 0.22068E+05 -2.254 7 SO3,gas -6.23 -16.40 -10.17 -2.543 0.40405E+05 -6.870 8 O2,gas 16.46 -3.37 -19.83 -13.223 0.78792E+05 -16.533 9 HCl,gas -5.54 -6.46 -0.93 -0.463 0.36800E+04 -0.926 10 acmite 3.99 2.10 -1.90 -0.197 0.75350E+04 12 akimotoite 5.82 1.56 -4.26 -0.852 0.16917E+05 13 akimotoite-Fe 3.81 -0.20 -4.01 -0.802 0.15936E+05 14 albite-high -4.34 -4.48 -0.14 -0.011 0.56111E+03 15 albite -4.30 -4.48 -0.18 -0.014 0.70263E+03 16 almandine -10.48 -12.12 -1.64 -0.082 0.65339E+04 17 pyrope -4.14 -6.84 -2.70 -0.135 0.10725E+05 18 analcite -2.61 -3.55 -0.94 -0.105 0.37433E+04 19 andalusite -12.42 -12.45 -0.03 -0.003 0.10106E+03 22 anhydrite -13.25 -13.52 -0.27 -0.133 0.10575E+04 24 annite -0.71 -2.81 -2.10 -0.116 0.83259E+04 25 phlogopite 3.67 2.47 -1.20 -0.067 0.47624E+04 27 anorthite -10.03 -10.50 -0.47 -0.036 0.18674E+04 28 anthophyllite 13.65 9.99 -3.65 -0.099 0.14518E+05 29 anthophyllite-Fe 1.65 -2.33 -3.98 -0.108 0.15824E+05 30 apatite-OH -49.22 -49.60 -0.38 -0.029 0.15005E+04 31 apatite-OH-zs -47.14 -49.60 -2.46 -0.189 0.97574E+04 32 apatite-Cl-zs -52.71 -56.06 -3.35 -0.279 0.13305E+05 33 aragonite -3.89 -7.40 -3.51 -1.170 0.13948E+05 34 brucite 4.88 2.49 -2.40 -0.480 0.95285E+04 35 calcite -3.98 -7.40 -3.42 -1.142 0.13604E+05 36 carnegieite-low -0.86 -2.62 -1.77 -0.252 0.70140E+04 37 carnegieite-high -0.79 -2.62 -1.83 -0.261 0.72598E+04 38 carpholite-Mg -9.19 -10.89 -1.70 -0.113 0.67621E+04 39 carpholite-Fe -10.48 -12.65 -2.17 -0.145 0.86283E+04 40 celadonite -1.14 -3.43 -2.29 -0.135 0.91069E+04 41 celadonite-Fe -2.48 -5.19 -2.70 -0.159 0.10745E+05 42 chrysotile 8.63 5.60 -3.02 -0.252 0.12015E+05 44 clinochlore 0.22 -1.87 -2.09 -0.065 0.83082E+04 45 daphnite -6.51 -10.67 -4.16 -0.130 0.16543E+05 48 chloritoid-Mg -8.92 -9.96 -1.05 -0.070 0.41530E+04 49 chloritoid-Fe -10.75 -11.72 -0.97 -0.065 0.38645E+04 50 chloritoid-Mn -8.59 -10.37 -1.78 -0.119 0.70679E+04 52 coesite -0.66 -0.93 -0.27 -0.090 0.10746E+04 53 cordierite-H -22.35 -22.71 -0.36 -0.013 0.14119E+04 54 cordierite-Fe -24.66 -26.23 -1.57 -0.054 0.62290E+04 55 cordierite-Mn -20.25 -23.51 -3.26 -0.112 0.12959E+05 56 corundum -11.34 -11.52 -0.18 -0.017 0.72425E+03 58 cristobalite -0.87 -0.93 -0.06 -0.020 0.23239E+03 59 cummingtonite 13.70 9.99 -3.71 -0.100 0.14725E+05 61 cymrite-K -2.77 -4.99 -2.22 -0.185 0.88236E+04 63 diaspore -5.17 -5.76 -0.59 -0.098 0.23368E+04 65 diopside 5.25 3.51 -1.74 -0.174 0.69155E+04 66 hedenbergite 3.90 1.75 -2.15 -0.215 0.85373E+04 68 eastonite -9.27 -10.61 -1.33 -0.051 0.53022E+04 69 enstatite 4.38 3.12 -1.26 -0.126 0.49909E+04 70 clinoenstatite-HiP 4.85 3.12 -1.73 -0.173 0.68674E+04 71 clinoenstatite 4.37 3.12 -1.25 -0.125 0.49472E+04 72 protoenstatite 4.51 3.12 -1.39 -0.139 0.55108E+04 73 epidote -6.35 -8.67 -2.32 -0.112 0.92143E+04 74 clinozoisite -12.01 -14.31 -2.30 -0.105 0.91556E+04 75 epidote-Fe 0.97 -3.02 -3.99 -0.207 0.15840E+05 76 fayalite 1.82 0.53 -1.30 -0.185 0.51475E+04 77 ferrosilite 0.98 -0.40 -1.38 -0.138 0.54677E+04 78 forsterite 5.63 4.05 -1.58 -0.226 0.62954E+04 79 gedrite -13.98 -16.17 -2.19 -0.059 0.86848E+04 81 gibbsite -3.62 -5.76 -2.15 -0.307 0.85317E+04 82 glaucophane 0.35 -3.35 -3.70 -0.100 0.14702E+05 84 goethite 0.89 -0.12 -1.00 -0.217 0.39830E+04 86 greenalite 4.03 0.32 -3.71 -0.309 0.14726E+05 87 grunerite 2.17 -2.33 -4.50 -0.122 0.17885E+05 88 halite -0.29 -2.40 -2.11 -1.055 0.83855E+04 89 hematite 0.30 -0.23 -0.53 -0.064 0.20866E+04 90 heulandite -12.58 -15.15 -2.58 -0.117 0.10231E+05 91 hercynite -9.98 -10.79 -0.81 -0.054 0.32173E+04 94 jadeite -1.94 -3.55 -1.61 -0.161 0.63883E+04 96 kalsilite -1.50 -3.13 -1.63 -0.233 0.64811E+04 97 kaolinite -11.12 -13.38 -2.26 -0.206 0.89820E+04 98 kyanite -12.29 -12.45 -0.16 -0.016 0.64132E+03 100 laumontite -9.17 -12.36 -3.19 -0.213 0.12677E+05 101 lawsonite -7.41 -10.50 -3.10 -0.206 0.12302E+05 102 leucite -3.07 -4.06 -0.99 -0.099 0.39471E+04 104 lizardite 8.82 5.60 -3.22 -0.268 0.12796E+05 105 magnesite -4.95 -7.79 -2.84 -0.946 0.11271E+05 106 magnetite 1.15 0.50 -0.65 -0.053 0.25854E+04 107 minnesotaite 0.95 -1.53 -2.48 -0.146 0.98633E+04 108 minnesotaite-Mg 6.64 3.75 -2.89 -0.170 0.11482E+05 109 magnesioferrite 4.09 2.26 -1.83 -0.150 0.72813E+04 111 manganosite 4.98 2.09 -2.89 -0.723 0.11481E+05 112 margarite -20.93 -22.02 -1.10 -0.044 0.43527E+04 115 microcline -4.90 -4.99 -0.09 -0.007 0.36345E+03 116 monticellite 8.30 4.44 -3.86 -0.551 0.15335E+05 118 mullite-Si -11.72 -12.45 -0.73 -0.073 0.28917E+04 119 muscovite -16.14 -16.51 -0.37 -0.022 0.14857E+04 120 paragonite -15.45 -16.00 -0.55 -0.032 0.21779E+04 121 nepheline -1.14 -2.62 -1.48 -0.211 0.58689E+04 122 osumilite(2) -14.22 -16.47 -2.25 -0.047 0.89217E+04 123 osumilite-Fe -31.10 -33.07 -1.96 -0.041 0.78040E+04 124 pargasite 1.55 -3.08 -4.63 -0.122 0.18403E+05 125 periclase 5.08 2.49 -2.59 -0.648 0.10293E+05 126 periclase-Fe 2.60 0.73 -1.88 -0.469 0.74547E+04 127 perovskite-Al -9.66 -11.52 -1.86 -0.169 0.73742E+04 132 phlogopite-Na 4.54 2.98 -1.56 -0.087 0.61905E+04 134 prehnite -5.36 -8.55 -3.19 -0.188 0.12687E+05 135 prehnite-Fe 0.70 -2.91 -3.61 -0.217 0.14328E+05 138 px-Mg-tschermaks -8.36 -9.96 -1.60 -0.114 0.63481E+04 139 px-Ca-tschermaks -7.30 -9.57 -2.27 -0.162 0.90055E+04 140 pyrite -20.01 -20.27 -0.26 -0.062 0.10437E+04 141 pyrrhotite -8.10 -8.93 -0.83 -0.276 0.32921E+04 142 pyrrhotiteFe0.875 -8.79 -9.23 -0.44 -0.160 0.17319E+04 143 pyrophyllite -14.37 -15.23 -0.87 -0.054 0.34431E+04 146 riebeckite 6.75 2.66 -4.09 -0.113 0.16239E+05 147 ringwoodite-Fe 2.79 0.53 -2.26 -0.323 0.89943E+04 148 ringwoodite-Mg 8.68 4.05 -4.64 -0.662 0.18419E+05 149 rhodochrosite -4.79 -8.19 -3.41 -1.135 0.13531E+05 150 rhodonite 2.47 1.16 -1.31 -0.262 0.52083E+04 151 sanidine -4.38 -4.99 -0.61 -0.047 0.24287E+04 152 sapphirine(351) -47.23 -51.07 -3.84 -0.058 0.15255E+05 153 siderite -6.69 -9.55 -2.86 -0.953 0.11355E+05 154 sillimanite -12.40 -12.45 -0.05 -0.005 0.19392E+03 156 spinel -7.90 -9.03 -1.13 -0.075 0.44914E+04 158 staurolite-Fe -104.76 -107.74 -2.98 -0.027 0.11839E+05 159 staurolite-Mg -96.70 -100.70 -4.00 -0.036 0.15875E+05 163 stilpnomelane-Mg -2.03 -4.74 -2.71 -0.081 0.10767E+05 164 stishovite 1.92 -0.93 -2.84 -0.948 0.11294E+05 165 sudoite-Fe -21.00 -24.38 -3.38 -0.109 0.13438E+05 166 sudoite -18.89 -20.86 -1.96 -0.063 0.78028E+04 167 sulfur -9.86 -11.34 -1.48 -0.454 0.58664E+04 168 sylvite -0.20 -2.91 -2.70 -1.352 0.10743E+05 169 talc 4.95 3.75 -1.20 -0.070 0.47495E+04 170 talc-Fe 2.28 -1.53 -3.81 -0.224 0.15151E+05 171 talc-tschermaks -7.72 -9.33 -1.61 -0.095 0.64041E+04 173 tephroite 6.15 3.24 -2.90 -0.415 0.11534E+05 176 topaz-H -10.40 -12.45 -2.05 -0.186 0.81332E+04 177 tremolite 14.83 10.77 -4.06 -0.110 0.16126E+05 179 troilite-low -8.00 -8.93 -0.93 -0.309 0.36859E+04 180 tschermakite -12.02 -15.39 -3.37 -0.091 0.13382E+05 183 wadsleyite-Fe 2.64 0.53 -2.11 -0.301 0.83836E+04 184 wadsleyite-Mg 7.77 4.05 -3.72 -0.531 0.14769E+05 185 wairakite -10.88 -12.36 -1.48 -0.087 0.58955E+04 186 walstromite 4.60 1.95 -2.65 -0.530 0.10527E+05 187 wollastonite 4.21 1.95 -2.26 -0.451 0.89641E+04 188 pseudo-wollastonite 4.31 1.95 -2.36 -0.473 0.93866E+04 189 zoisite -12.07 -14.31 -2.24 -0.102 0.88993E+04 192 beidellite-Ca -15.20 -16.35 -1.16 -0.072 0.46063E+04 193 beidellite-H -15.19 -16.83 -1.64 -0.104 0.65014E+04 194 beidellite-K -14.13 -15.66 -1.53 -0.094 0.60718E+04 195 beidellite-Mg -15.52 -16.42 -0.90 -0.056 0.35859E+04 196 beidellite-Na -14.06 -15.49 -1.42 -0.087 0.56606E+04 199 chalcocite -12.87 -14.10 -1.23 -0.307 0.48859E+04 200 covellite -11.44 -12.72 -1.28 -0.488 0.50874E+04 202 montmorillonite-Ca -11.06 -12.04 -0.98 -0.060 0.38811E+04 203 montmorillonite-K -10.29 -11.34 -1.05 -0.064 0.41712E+04 204 montmorillonite-Mg -11.31 -12.10 -0.79 -0.049 0.31581E+04 205 montmorillonite-Na -9.91 -11.17 -1.26 -0.077 0.49949E+04 206 nontronite-Ca -3.34 -5.06 -1.72 -0.112 0.68515E+04 207 nontronite-H -3.35 -5.54 -2.19 -0.147 0.87148E+04 208 nontronite-K -2.27 -4.36 -2.09 -0.134 0.83085E+04 209 nontronite-Mg -3.60 -5.13 -1.53 -0.099 0.60754E+04 210 nontronite-Na -2.21 -4.20 -1.99 -0.128 0.79098E+04 215 gypsum -11.17 -13.53 -2.36 -0.590 0.93674E+04 232 alabandite -5.82 -7.57 -1.75 -0.583 0.69439E+04 234 anglesite -13.37 -16.09 -2.72 -1.362 0.10824E+05 237 barite -14.25 -14.36 -0.11 -0.056 0.44607E+03 238 boehmite -4.90 -5.76 -0.86 -0.144 0.34233E+04 240 chalcopyrite -21.53 -21.65 -0.11 -0.021 0.44145E+03 242 copper,native 1.81 -1.38 -3.19 -1.108 0.12658E+05 244 ferrous-oxide 1.70 0.73 -0.97 -0.243 0.38636E+04 245 galena -8.83 -9.35 -0.52 -0.173 0.20591E+04 246 silver,native 0.59 -3.72 -4.31 -1.498 0.17107E+05 248 litharge 5.19 0.31 -4.89 -1.221 0.19409E+05 255 sphalerite -10.23 -10.52 -0.30 -0.099 0.11770E+04 256 wurtzite -9.45 -10.52 -1.07 -0.358 0.42642E+04 257 zincite 1.86 -0.87 -2.73 -0.681 0.10826E+05 258 an20ab80 -5.66 -5.68 -0.02 -0.001 0.72662E+02 259 an25ab75 -5.98 -5.98 -0.01 0.000 0.22924E+02 261 tr.625ac.25prg.125 9.08 6.84 -2.24 -0.060 0.89047E+04 Calculations done for 595.0000 Deg. C; 2000.0000 bar Temperature changed by -1.000 degrees to 594.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 22 Loop limit = 500 Temperature = 594.00 C Pressure = 1950.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5502E+02 kg liquid = 0.9911E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9948 Stoichiometric ionic strength = .3311049E+01 Osmotic coef. = 0.0000 True ionic strength = .2704133E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16395E-04 -4.7853 0.48215E-05 -5.3168 0.29409E+00 -0.5315 2 H2O 0.99482E+00 -0.0023 0.99482E+00 -0.0023 3 Cl- 0.22890E+00 -0.6403 0.63416E-01 -1.1978 0.27704E+00 -0.5575 4 SO4-- 0.14472E-03 -3.8395 0.14293E-05 -5.8449 0.98766E-02 -2.0054 5 HCO3- 0.32211E-04 -4.4920 0.95682E-05 -5.0192 0.29705E+00 -0.5272 6 HS- 0.14894E-03 -3.8270 0.41587E-04 -4.3810 0.27921E+00 -0.5541 7 H4SiO4 0.11335E+00 -0.9456 0.11335E+00 -0.9456 0.10000E+01 0.0000 8 Al+++ 0.81425E-17 -17.0892 0.19356E-21 -21.7132 0.23772E-04 -4.6239 9 Ca++ 0.23662E-05 -5.6260 0.19220E-07 -7.7163 0.81227E-02 -2.0903 10 Mg++ 0.11670E-05 -5.9329 0.79069E-08 -8.1020 0.67755E-02 -2.1691 11 Fe++ 0.19199E-07 -7.7167 0.13623E-09 -9.8657 0.70961E-02 -2.1490 12 K+ 0.59651E-01 -1.2244 0.18147E-01 -1.7412 0.30421E+00 -0.5168 13 Na+ 0.20831E+00 -0.6813 0.58426E-01 -1.2334 0.28048E+00 -0.5521 14 Mn++ 0.43049E-06 -6.3660 0.31594E-08 -8.5004 0.73390E-02 -2.1344 15 Zn++ 0.48630E-09 -9.3131 0.34508E-11 -11.4621 0.70961E-02 -2.1490 16 Cu+ 0.99727E-07 -7.0012 0.27901E-07 -7.5544 0.27978E+00 -0.5532 17 Pb++ 0.54651E-08 -8.2624 0.49265E-10 -10.3075 0.90146E-02 -2.0451 18 Ag+ 0.45482E-09 -9.3422 0.13636E-09 -9.8653 0.29981E+00 -0.5232 19 Ba++ 0.28905E-06 -6.5390 0.27819E-08 -8.5557 0.96243E-02 -2.0166 20 HPO4-- 0.16735E-08 -8.7764 0.16605E-10 -10.7798 0.99220E-02 -2.0034 21 HSiO3- 0.23629E-05 -5.6266 0.65461E-06 -6.1840 0.27704E+00 -0.5575 22 Ca(HSiO3)+ 0.13561E-07 -7.8677 0.41589E-08 -8.3810 0.30669E+00 -0.5133 23 Mg(HSiO3)+ 0.13873E-08 -8.8578 0.42547E-09 -9.3711 0.30669E+00 -0.5133 24 NaHSiO3,aq 0.12754E-05 -5.8944 0.12754E-05 -5.8944 0.10000E+01 0.0000 28 AgCl,aq 0.69108E-07 -7.1605 0.69108E-07 -7.1605 0.10000E+01 0.0000 29 AgCl2- 0.50052E-05 -5.3006 0.13866E-05 -5.8580 0.27704E+00 -0.5575 30 AgCl3-2 0.25842E-05 -5.5877 0.23783E-07 -7.6237 0.92033E-02 -2.0361 31 AgCl4-3 0.11161E-05 -5.9523 0.23013E-10 -10.6380 0.20619E-04 -4.6857 34 Ag(HS),aq 0.50245E-09 -9.2989 0.50245E-09 -9.2989 0.10000E+01 0.0000 35 Ag(HS)2- 0.30168E-08 -8.5205 0.83578E-09 -9.0779 0.27704E+00 -0.5575 36 AlO+ 0.15769E-10 -10.8022 0.48360E-11 -11.3155 0.30669E+00 -0.5133 38 HAlO2,aq 0.53588E-08 -8.2709 0.53588E-08 -8.2709 0.10000E+01 0.0000 39 AlO2- 0.24227E-04 -4.6157 0.59160E-05 -5.2280 0.24420E+00 -0.6123 41 Ba(HCO3)+ 0.15162E-05 -5.8192 0.48230E-06 -6.3167 0.31809E+00 -0.4974 42 BaCl+ 0.54062E-04 -4.2671 0.16580E-04 -4.7804 0.30669E+00 -0.5133 43 CH4,aq 0.21038E-08 -8.6770 0.25668E-08 -8.5906 0.12201E+01 0.0864 48 CO,aq 0.89885E-03 -3.0463 0.89885E-03 -3.0463 0.10000E+01 0.0000 49 CO2,aq 0.26789E+01 0.4280 0.32684E+01 0.5143 0.12201E+01 0.0864 50 CO3-2 0.53704E-10 -10.2700 0.49426E-12 -12.3060 0.92033E-02 -2.0361 51 CaCO3,aq 0.14624E-10 -10.8349 0.14624E-10 -10.8349 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.75203E-06 -6.1238 0.23064E-06 -6.6371 0.30669E+00 -0.5133 53 CaCl+ 0.24986E-03 -3.6023 0.76629E-04 -4.1156 0.30669E+00 -0.5133 54 CaCl2,aq 0.12309E-03 -3.9098 0.12309E-03 -3.9098 0.10000E+01 0.0000 55 CaOH+ 0.34227E-06 -6.4656 0.10497E-06 -6.9789 0.30669E+00 -0.5133 56 CaSO4,aq 0.84332E-07 -7.0740 0.84332E-07 -7.0740 0.10000E+01 0.0000 57 HCl,aq 0.10620E-02 -2.9739 0.10620E-02 -2.9739 0.10000E+01 0.0000 66 CuCl,aq 0.58963E-04 -4.2294 0.58963E-04 -4.2294 0.10000E+01 0.0000 67 CuCl2- 0.23363E-03 -3.6315 0.64724E-04 -4.1889 0.27704E+00 -0.5575 68 CuCl3-2 0.62571E-05 -5.2036 0.57586E-07 -7.2397 0.92033E-02 -2.0361 74 FeCl+ 0.63470E-06 -6.1974 0.19466E-06 -6.7107 0.30669E+00 -0.5133 75 FeCl2,aq 0.88235E-02 -2.0544 0.88235E-02 -2.0544 0.10000E+01 0.0000 77 FeO,aq 0.60868E-07 -7.2156 0.60868E-07 -7.2156 0.10000E+01 0.0000 78 FeOH+ 0.43466E-07 -7.3618 0.13331E-07 -7.8751 0.30669E+00 -0.5133 79 HFeO2- 0.89346E-08 -8.0489 0.24753E-08 -8.6064 0.27704E+00 -0.5575 82 FeO2- 0.51565E-08 -8.2876 0.14286E-08 -8.8451 0.27704E+00 -0.5575 83 HFeO2,aq 0.16092E-09 -9.7934 0.16092E-09 -9.7934 0.10000E+01 0.0000 84 H2,aq 0.44135E-02 -2.3552 0.53847E-02 -2.2688 0.12201E+01 0.0864 85 KCl,aq 0.51703E-01 -1.2865 0.51703E-01 -1.2865 0.10000E+01 0.0000 86 KHSO4,aq 0.12104E-01 -1.9171 0.12104E-01 -1.9171 0.10000E+01 0.0000 87 KOH,aq 0.80841E-06 -6.0924 0.80841E-06 -6.0924 0.10000E+01 0.0000 88 KSO4- 0.30721E-02 -2.5126 0.85110E-03 -3.0700 0.27704E+00 -0.5575 90 Mg(HCO3)+ 0.13478E-06 -6.8704 0.41335E-07 -7.3837 0.30669E+00 -0.5133 91 MgCl+ 0.18984E-04 -4.7216 0.58221E-05 -5.2349 0.30669E+00 -0.5133 92 MgOH+ 0.57459E-06 -6.2406 0.17622E-06 -6.7539 0.30669E+00 -0.5133 94 MnO,aq 0.20816E-07 -7.6816 0.20816E-07 -7.6816 0.10000E+01 0.0000 95 MnOH+ 0.12740E-06 -6.8948 0.39072E-07 -7.4081 0.30669E+00 -0.5133 97 HMnO2- 0.14670E-10 -10.8336 0.40641E-11 -11.3910 0.27704E+00 -0.5575 100 MnCl+ 0.11592E-02 -2.9359 0.35551E-03 -3.4492 0.30669E+00 -0.5133 101 MnSO4,aq 0.17799E-07 -7.7496 0.17799E-07 -7.7496 0.10000E+01 0.0000 102 NaCl,aq 0.35088E+00 -0.4548 0.35088E+00 -0.4548 0.10000E+01 0.0000 103 NaOH,aq 0.11925E-05 -5.9235 0.11925E-05 -5.9235 0.10000E+01 0.0000 105 OH- 0.96108E-05 -5.0172 0.23469E-05 -5.6295 0.24420E+00 -0.6123 110 HPO3-2 0.31942E-10 -10.4956 0.29397E-12 -12.5317 0.92033E-02 -2.0361 111 H3PO3,aq 0.26509E-09 -9.5766 0.26509E-09 -9.5766 0.10000E+01 0.0000 112 H2PO3- 0.12432E-07 -7.9055 0.34442E-08 -8.4629 0.27704E+00 -0.5575 113 H3PO4,aq 0.16621E-05 -5.7794 0.16621E-05 -5.7794 0.10000E+01 0.0000 114 H2PO4- 0.39545E-05 -5.4029 0.11483E-05 -5.9399 0.29038E+00 -0.5370 116 H4P2O7,aq 0.22367E-09 -9.6504 0.22367E-09 -9.6504 0.10000E+01 0.0000 117 H3P2O7- 0.56411E-08 -8.2486 0.15628E-08 -8.8061 0.27704E+00 -0.5575 118 H2P2O7-2 0.14673E-05 -5.8335 0.13504E-07 -7.8695 0.92033E-02 -2.0361 119 HP2O7-3 0.33344E-07 -7.4770 0.68752E-12 -12.1627 0.20619E-04 -4.6857 121 PbCl+ 0.32988E-05 -5.4816 0.10117E-05 -5.9949 0.30669E+00 -0.5133 122 PbCl2,aq 0.98149E-04 -4.0081 0.98149E-04 -4.0081 0.10000E+01 0.0000 123 PbCl3- 0.11816E-03 -3.9275 0.32735E-04 -4.4850 0.27704E+00 -0.5575 124 PbCl4-2 0.31142E-04 -4.5067 0.28661E-06 -6.5427 0.92033E-02 -2.0361 125 PbO,aq 0.29051E-08 -8.5368 0.29051E-08 -8.5368 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.85899E-04 -4.0660 0.85899E-04 -4.0660 0.10000E+01 0.0000 128 Pb(HS)3- 0.65570E-05 -5.1833 0.18165E-05 -5.7408 0.27704E+00 -0.5575 129 H2S,aq 0.10415E+01 0.0177 0.12707E+01 0.1040 0.12201E+01 0.0864 130 S2-2 0.13740E-07 -7.8620 0.12645E-09 -9.8981 0.92033E-02 -2.0361 131 S3-2 0.15153E-08 -8.8195 0.13946E-10 -10.8556 0.92033E-02 -2.0361 132 S3- 0.23783E-01 -1.6237 0.65890E-02 -2.1812 0.27704E+00 -0.5575 133 S4-2 0.13835E-09 -9.8590 0.12733E-11 -11.8951 0.92033E-02 -2.0361 134 S5-2 0.10606E-10 -10.9745 0.97608E-13 -13.0105 0.92033E-02 -2.0361 135 SO2,aq 0.28260E+00 -0.5488 0.28260E+00 -0.5488 0.10000E+01 0.0000 136 SO3-2 0.56628E-09 -9.2470 0.78985E-11 -11.1025 0.13948E-01 -1.8555 137 HSO3- 0.46662E-03 -3.3310 0.12927E-03 -3.8885 0.27704E+00 -0.5575 138 HSO4- 0.12808E-01 -1.8925 0.40222E-02 -2.3955 0.31403E+00 -0.5030 140 S2O3-2 0.46860E-06 -6.3292 0.43127E-08 -8.3653 0.92033E-02 -2.0361 141 HS2O3- 0.81783E-06 -6.0873 0.22657E-06 -6.6448 0.27704E+00 -0.5575 142 H2S2O3,aq 0.24640E-07 -7.6084 0.24640E-07 -7.6084 0.10000E+01 0.0000 150 S4O6-2 0.70672E-09 -9.1508 0.65041E-11 -11.1868 0.92033E-02 -2.0361 152 ZnCl+ 0.74338E-03 -3.1288 0.22799E-03 -3.6421 0.30669E+00 -0.5133 153 ZnCl2,aq 0.13530E-02 -2.8687 0.13530E-02 -2.8687 0.10000E+01 0.0000 154 ZnCl3- 0.22031E-03 -3.6570 0.61034E-04 -4.2144 0.27704E+00 -0.5575 155 ZnO,aq 0.27792E-07 -7.5561 0.27792E-07 -7.5561 0.10000E+01 0.0000 156 ZnOH+ 0.31714E-05 -5.4988 0.97262E-06 -6.0121 0.30669E+00 -0.5133 158 HZnO2- 0.25655E-09 -9.5908 0.71075E-10 -10.1483 0.27704E+00 -0.5575 Charge balance for all species = 0.2553E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1639452E-04 0.4303217E+01 0.3527985E+04 0.0000 2 H2O 0.1000000E+01 0.5249085E+02 0.7691727E+06 0.0000 3 Cl- 0.2289046E+00 0.6572821E+00 0.1895412E+05 4.1190 4 SO4-- 0.1447166E-03 0.2539696E+00 0.1984405E+05 4.7888 5 HCO3- 0.3221099E-04 0.2679848E+01 0.1330029E+06 0.2976 6 HS- 0.1489443E-03 0.1170430E+01 0.3148509E+05 0.9358 7 H4SiO4 0.1133494E+00 0.1133530E+00 0.8861860E+04 -0.9456 8 Al+++ 0.8142498E-17 0.2423200E-04 0.5318070E+00 -5.7627 9 Ca++ 0.2366151E-05 0.3765087E-03 0.1227382E+02 2.9174 10 Mg++ 0.1166986E-05 0.2086142E-04 0.4125374E+00 2.5316 11 Fe++ 0.1919860E-07 0.8824247E-02 0.4008448E+03 0.7679 12 K+ 0.5965117E-01 0.1265308E+00 0.4024334E+04 3.5756 13 Na+ 0.2083079E+00 0.5591910E+00 0.1045669E+05 4.0834 14 Mn++ 0.4304901E-06 0.1159772E-02 0.5182559E+02 2.1332 15 Zn++ 0.4863013E-09 0.2319882E-02 0.1233511E+03 -0.8284 16 Cu+ 0.9972656E-07 0.2989457E-03 0.1545035E+02 -2.2376 17 Pb++ 0.5465053E-08 0.3432124E-03 0.5784031E+02 0.3262 18 Ag+ 0.4548210E-09 0.8778593E-05 0.7702370E+00 -4.5485 19 Ba++ 0.2890456E-06 0.5586726E-04 0.6240986E+01 2.0780 20 HPO4-- 0.1673532E-08 0.8644060E-05 0.6748275E+00 -0.1461 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265104E+01 -.2741493E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5202594E+02 -.6115981E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517202E+00 0.2582793E-05 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160064E+01 0.8006657E-04 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1123491E+00 0.3124526E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2401738E-04 0.6705222E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3731740E-03 0.1547359E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8746091E-02 0.2066234E-04 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542383E+00 0.3610504E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.2962980E-03 0.1033117E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1762E-18 Mass of aqueous solution: 0.121853E+04 g Temperature = 594.00 C Pressure = 1950.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) quartz 0.2985E-01 -1.525 1.794 0.254 92.37 0.6773 bornite 0.2066E-04 -4.685 0.1037E-01 -1.984 0.5340 0.2040E-02 an30ab70 0.5158E-03 -3.288 0.1377 -0.861 7.093 0.5172E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.941639 g Volume = 0.731079 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 144 quartz -0.94 -0.94 0.00 0.000 0.00000E+00 197 bornite -50.06 -50.06 0.00 0.000 0.00000E+00 260 an30ab70 -6.30 -6.30 0.00 0.000 -0.10573E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.294 0.11674E+04 2.996 2 CO2,gas -8.95 -10.33 -1.38 -0.460 0.54815E+04 1.909 3 CH4,gas 6.90 -3.56 -10.46 -2.615 0.41509E+05 -7.171 4 H2,gas 5.74 1.69 -4.04 -2.311 0.16050E+05 -0.755 5 H2S,gas -7.44 -9.70 -2.26 -1.129 0.89629E+04 1.031 6 CO,gas -3.07 -8.64 -5.57 -1.714 0.22110E+05 -2.282 7 SO3,gas -6.29 -16.48 -10.19 -2.547 0.40432E+05 -6.900 8 O2,gas 16.47 -3.39 -19.86 -13.238 0.78794E+05 -16.568 9 HCl,gas -5.56 -6.51 -0.96 -0.478 0.37904E+04 -0.955 10 acmite 3.96 2.12 -1.85 -0.192 0.73246E+04 12 akimotoite 5.82 1.59 -4.23 -0.846 0.16779E+05 13 akimotoite-Fe 3.81 -0.18 -3.98 -0.796 0.15802E+05 14 albite-high -4.37 -4.51 -0.14 -0.011 0.56297E+03 15 albite -4.33 -4.51 -0.18 -0.014 0.70133E+03 16 almandine -10.47 -12.06 -1.59 -0.079 0.62946E+04 17 pyrope -4.13 -6.77 -2.64 -0.132 0.10477E+05 18 analcite -2.62 -3.57 -0.95 -0.105 0.37520E+04 19 andalusite -12.41 -12.47 -0.07 -0.007 0.25998E+03 22 anhydrite -13.33 -13.56 -0.23 -0.115 0.91179E+03 24 annite -0.73 -2.72 -1.99 -0.111 0.79124E+04 25 phlogopite 3.66 2.57 -1.09 -0.061 0.43394E+04 27 anorthite -10.03 -10.50 -0.47 -0.036 0.18666E+04 28 anthophyllite 13.58 10.17 -3.41 -0.092 0.13528E+05 29 anthophyllite-Fe 1.57 -2.17 -3.74 -0.101 0.14846E+05 30 apatite-OH -49.47 -49.66 -0.18 -0.014 0.73303E+03 31 apatite-OH-zs -47.39 -49.66 -2.27 -0.174 0.89935E+04 32 apatite-Cl-zs -53.00 -56.17 -3.17 -0.264 0.12586E+05 33 aragonite -3.93 -7.42 -3.49 -1.163 0.13846E+05 34 brucite 4.89 2.53 -2.37 -0.473 0.93926E+04 35 calcite -4.02 -7.42 -3.40 -1.134 0.13499E+05 36 carnegieite-low -0.86 -2.62 -1.77 -0.252 0.70121E+04 37 carnegieite-high -0.80 -2.62 -1.83 -0.261 0.72592E+04 38 carpholite-Mg -9.18 -10.89 -1.71 -0.114 0.67952E+04 39 carpholite-Fe -10.47 -12.65 -2.18 -0.146 0.86655E+04 40 celadonite -1.17 -3.43 -2.26 -0.133 0.89804E+04 41 celadonite-Fe -2.52 -5.19 -2.68 -0.157 0.10624E+05 42 chrysotile 8.62 5.70 -2.92 -0.243 0.11594E+05 44 clinochlore 0.24 -1.72 -1.96 -0.061 0.77630E+04 45 daphnite -6.50 -10.54 -4.04 -0.126 0.16018E+05 48 chloritoid-Mg -8.89 -9.95 -1.05 -0.070 0.41790E+04 49 chloritoid-Fe -10.73 -11.71 -0.98 -0.065 0.38913E+04 50 chloritoid-Mn -8.56 -10.34 -1.78 -0.119 0.70615E+04 52 coesite -0.67 -0.94 -0.27 -0.090 0.10768E+04 53 cordierite-H -22.35 -22.71 -0.36 -0.013 0.14369E+04 54 cordierite-Fe -24.67 -26.24 -1.57 -0.054 0.62268E+04 55 cordierite-Mn -20.26 -23.51 -3.25 -0.112 0.12889E+05 56 corundum -11.31 -11.53 -0.22 -0.020 0.88641E+03 58 cristobalite -0.88 -0.94 -0.06 -0.019 0.22835E+03 59 cummingtonite 13.64 10.17 -3.46 -0.094 0.13738E+05 61 cymrite-K -2.79 -5.02 -2.23 -0.186 0.88428E+04 63 diaspore -5.16 -5.77 -0.61 -0.102 0.24206E+04 65 diopside 5.23 3.56 -1.67 -0.167 0.66255E+04 66 hedenbergite 3.88 1.80 -2.08 -0.208 0.82506E+04 68 eastonite -9.24 -10.55 -1.31 -0.050 0.51792E+04 69 enstatite 4.36 3.18 -1.19 -0.119 0.47099E+04 70 clinoenstatite-HiP 4.84 3.18 -1.66 -0.166 0.65882E+04 71 clinoenstatite 4.35 3.18 -1.18 -0.118 0.46654E+04 72 protoenstatite 4.49 3.18 -1.32 -0.132 0.52284E+04 73 epidote -6.36 -8.61 -2.25 -0.109 0.89392E+04 74 clinozoisite -12.00 -14.29 -2.29 -0.104 0.91042E+04 75 epidote-Fe 0.94 -2.92 -3.87 -0.201 0.15338E+05 76 fayalite 1.82 0.59 -1.23 -0.175 0.48677E+04 77 ferrosilite 0.96 -0.35 -1.31 -0.131 0.51916E+04 78 forsterite 5.63 4.12 -1.51 -0.216 0.60097E+04 79 gedrite -13.97 -16.07 -2.09 -0.057 0.83006E+04 81 gibbsite -3.60 -5.77 -2.17 -0.311 0.86250E+04 82 glaucophane 0.29 -3.31 -3.60 -0.097 0.14295E+05 84 goethite 0.89 -0.08 -0.97 -0.210 0.38452E+04 86 greenalite 4.02 0.41 -3.61 -0.300 0.14305E+05 87 grunerite 2.09 -2.17 -4.26 -0.115 0.16910E+05 88 halite -0.32 -2.43 -2.11 -1.053 0.83591E+04 89 hematite 0.29 -0.16 -0.45 -0.055 0.18010E+04 90 heulandite -12.63 -15.22 -2.59 -0.118 0.10288E+05 91 hercynite -9.95 -10.77 -0.82 -0.054 0.32376E+04 94 jadeite -1.95 -3.57 -1.61 -0.161 0.64005E+04 96 kalsilite -1.50 -3.13 -1.63 -0.233 0.64810E+04 97 kaolinite -11.11 -13.42 -2.30 -0.210 0.91452E+04 98 kyanite -12.27 -12.47 -0.20 -0.020 0.80687E+03 100 laumontite -9.19 -12.39 -3.20 -0.214 0.12712E+05 101 lawsonite -7.40 -10.50 -3.11 -0.207 0.12335E+05 102 leucite -3.08 -4.07 -0.99 -0.099 0.39446E+04 104 lizardite 8.82 5.70 -3.12 -0.260 0.12370E+05 105 magnesite -4.99 -7.80 -2.82 -0.939 0.11177E+05 106 magnetite 1.15 0.60 -0.54 -0.044 0.21583E+04 107 minnesotaite 0.91 -1.47 -2.38 -0.140 0.94367E+04 108 minnesotaite-Mg 6.61 3.82 -2.78 -0.164 0.11048E+05 109 magnesioferrite 4.09 2.37 -1.73 -0.141 0.68506E+04 111 manganosite 4.98 2.13 -2.85 -0.712 0.11308E+05 112 margarite -20.89 -22.03 -1.14 -0.046 0.45272E+04 115 microcline -4.92 -5.01 -0.09 -0.007 0.35810E+03 116 monticellite 8.29 4.50 -3.79 -0.541 0.15036E+05 118 mullite-Si -11.70 -12.47 -0.77 -0.077 0.30546E+04 119 muscovite -16.13 -16.55 -0.42 -0.025 0.16577E+04 120 paragonite -15.45 -16.04 -0.59 -0.035 0.23519E+04 121 nepheline -1.15 -2.62 -1.48 -0.211 0.58674E+04 122 osumilite(2) -14.31 -16.49 -2.17 -0.045 0.86220E+04 123 osumilite-Fe -31.17 -33.14 -1.97 -0.041 0.78101E+04 124 pargasite 1.55 -2.92 -4.46 -0.117 0.17714E+05 125 periclase 5.09 2.53 -2.56 -0.639 0.10150E+05 126 periclase-Fe 2.61 0.77 -1.84 -0.461 0.73157E+04 127 perovskite-Al -9.63 -11.53 -1.90 -0.173 0.75369E+04 132 phlogopite-Na 4.53 3.08 -1.45 -0.081 0.57675E+04 134 prehnite -5.36 -8.53 -3.16 -0.186 0.12549E+05 135 prehnite-Fe 0.68 -2.84 -3.52 -0.212 0.13961E+05 138 px-Mg-tschermaks -8.34 -9.94 -1.61 -0.115 0.63686E+04 139 px-Ca-tschermaks -7.29 -9.56 -2.27 -0.162 0.90163E+04 140 pyrite -20.09 -20.32 -0.23 -0.053 0.89875E+03 141 pyrrhotite -8.14 -8.93 -0.79 -0.265 0.31487E+04 142 pyrrhotiteFe0.875 -8.83 -9.24 -0.41 -0.149 0.16071E+04 143 pyrophyllite -14.39 -15.30 -0.91 -0.057 0.36118E+04 146 riebeckite 6.65 2.77 -3.88 -0.107 0.15395E+05 147 ringwoodite-Fe 2.79 0.59 -2.20 -0.314 0.87168E+04 148 ringwoodite-Mg 8.69 4.12 -4.57 -0.653 0.18136E+05 149 rhodochrosite -4.82 -8.20 -3.38 -1.126 0.13406E+05 150 rhodonite 2.46 1.19 -1.27 -0.254 0.50363E+04 151 sanidine -4.40 -5.01 -0.61 -0.047 0.24235E+04 152 sapphirine(351) -47.07 -51.01 -3.94 -0.060 0.15632E+05 153 siderite -6.73 -9.57 -2.84 -0.946 0.11263E+05 154 sillimanite -12.38 -12.47 -0.09 -0.009 0.35511E+03 156 spinel -7.87 -9.00 -1.14 -0.076 0.45073E+04 158 staurolite-Fe -104.57 -107.79 -3.22 -0.029 0.12770E+05 159 staurolite-Mg -96.50 -100.74 -4.23 -0.039 0.16799E+05 163 stilpnomelane-Mg -2.06 -4.64 -2.58 -0.077 0.10228E+05 164 stishovite 1.91 -0.94 -2.85 -0.949 0.11301E+05 165 sudoite-Fe -20.96 -24.37 -3.41 -0.110 0.13523E+05 166 sudoite -18.85 -20.84 -1.99 -0.064 0.78791E+04 167 sulfur -9.91 -11.39 -1.48 -0.455 0.58654E+04 168 sylvite -0.24 -2.94 -2.70 -1.350 0.10712E+05 169 talc 4.91 3.82 -1.09 -0.064 0.43215E+04 170 talc-Fe 2.24 -1.47 -3.71 -0.218 0.14732E+05 171 talc-tschermaks -7.72 -9.30 -1.58 -0.093 0.62778E+04 173 tephroite 6.14 3.32 -2.82 -0.403 0.11187E+05 176 topaz-H -10.38 -12.48 -2.09 -0.190 0.83055E+04 177 tremolite 14.76 10.95 -3.81 -0.103 0.15116E+05 179 troilite-low -8.04 -8.93 -0.89 -0.297 0.35411E+04 180 tschermakite -12.03 -15.29 -3.27 -0.088 0.12972E+05 183 wadsleyite-Fe 2.63 0.59 -2.04 -0.292 0.81064E+04 184 wadsleyite-Mg 7.77 4.12 -3.65 -0.522 0.14486E+05 185 wairakite -10.90 -12.39 -1.49 -0.087 0.58948E+04 186 walstromite 4.59 1.97 -2.61 -0.523 0.10376E+05 187 wollastonite 4.19 1.97 -2.22 -0.444 0.88095E+04 188 pseudo-wollastonite 4.30 1.97 -2.33 -0.465 0.92327E+04 189 zoisite -12.06 -14.29 -2.23 -0.101 0.88501E+04 192 beidellite-Ca -15.21 -16.41 -1.20 -0.074 0.47748E+04 193 beidellite-H -15.20 -16.89 -1.69 -0.108 0.66946E+04 194 beidellite-K -14.14 -15.71 -1.57 -0.096 0.62392E+04 195 beidellite-Mg -15.53 -16.47 -0.95 -0.059 0.37621E+04 196 beidellite-Na -14.07 -15.54 -1.47 -0.090 0.58291E+04 199 chalcocite -12.93 -14.17 -1.25 -0.311 0.49431E+04 200 covellite -11.49 -12.78 -1.29 -0.491 0.51117E+04 202 montmorillonite-Ca -11.09 -12.08 -0.99 -0.062 0.39474E+04 203 montmorillonite-K -10.31 -11.38 -1.07 -0.065 0.42401E+04 204 montmorillonite-Mg -11.33 -12.14 -0.81 -0.050 0.32244E+04 205 montmorillonite-Na -9.94 -11.21 -1.27 -0.078 0.50576E+04 206 nontronite-Ca -3.38 -5.04 -1.66 -0.108 0.65768E+04 207 nontronite-H -3.39 -5.52 -2.13 -0.143 0.84649E+04 208 nontronite-K -2.32 -4.34 -2.02 -0.130 0.80328E+04 209 nontronite-Mg -3.64 -5.11 -1.46 -0.095 0.58028E+04 210 nontronite-Na -2.25 -4.18 -1.92 -0.124 0.76354E+04 215 gypsum -11.24 -13.57 -2.33 -0.583 0.92458E+04 232 alabandite -5.86 -7.56 -1.71 -0.569 0.67678E+04 234 anglesite -13.45 -16.15 -2.70 -1.352 0.10732E+05 237 barite -14.33 -14.40 -0.07 -0.035 0.27652E+03 238 boehmite -4.88 -5.77 -0.88 -0.147 0.35074E+04 240 chalcopyrite -21.63 -21.71 -0.08 -0.015 0.32270E+03 242 copper,native 1.80 -1.39 -3.20 -1.112 0.12680E+05 244 ferrous-oxide 1.70 0.77 -0.94 -0.235 0.37255E+04 245 galena -8.88 -9.37 -0.49 -0.164 0.19473E+04 246 silver,native 0.58 -3.70 -4.28 -1.490 0.17001E+05 248 litharge 5.19 0.32 -4.86 -1.216 0.19300E+05 255 sphalerite -10.27 -10.53 -0.25 -0.085 0.10097E+04 256 wurtzite -9.49 -10.53 -1.03 -0.344 0.40974E+04 257 zincite 1.86 -0.83 -2.69 -0.672 0.10664E+05 258 an20ab80 -5.69 -5.71 -0.02 -0.001 0.72488E+02 259 an25ab75 -6.00 -6.01 -0.01 0.000 0.22707E+02 261 tr.625ac.25prg.125 9.01 7.01 -2.00 -0.054 0.79485E+04 Calculations done for 594.0000 Deg. C; 1950.0000 bar Temperature changed by -1.000 degrees to 593.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 22 Loop limit = 500 Temperature = 593.00 C Pressure = 1903.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5502E+02 kg liquid = 0.9912E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9949 Stoichiometric ionic strength = .3310606E+01 Osmotic coef. = 0.0000 True ionic strength = .2656083E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15461E-04 -4.8108 0.44808E-05 -5.3486 0.28982E+00 -0.5379 2 H2O 0.99493E+00 -0.0022 0.99493E+00 -0.0022 3 Cl- 0.22439E+00 -0.6490 0.60922E-01 -1.2152 0.27150E+00 -0.5662 4 SO4-- 0.14975E-03 -3.8246 0.13912E-05 -5.8566 0.92905E-02 -2.0320 5 HCO3- 0.31192E-04 -4.5060 0.90861E-05 -5.0416 0.29129E+00 -0.5357 6 HS- 0.14950E-03 -3.8254 0.40909E-04 -4.3882 0.27364E+00 -0.5628 7 H4SiO4 0.11005E+00 -0.9584 0.11005E+00 -0.9584 0.10000E+01 0.0000 8 Al+++ 0.74450E-17 -17.1281 0.15442E-21 -21.8113 0.20741E-04 -4.6832 9 Ca++ 0.23697E-05 -5.6253 0.18071E-07 -7.7430 0.76259E-02 -2.1177 10 Mg++ 0.11778E-05 -5.9289 0.74797E-08 -8.1261 0.63503E-02 -2.1972 11 Fe++ 0.19263E-07 -7.7153 0.12817E-09 -9.8922 0.66536E-02 -2.1769 12 K+ 0.58715E-01 -1.2313 0.17519E-01 -1.7565 0.29838E+00 -0.5252 13 Na+ 0.20445E+00 -0.6894 0.56203E-01 -1.2502 0.27490E+00 -0.5608 14 Mn++ 0.43859E-06 -6.3579 0.30191E-08 -8.5201 0.68836E-02 -2.1622 15 Zn++ 0.48892E-09 -9.3108 0.32531E-11 -11.4877 0.66536E-02 -2.1769 16 Cu+ 0.90872E-07 -7.0416 0.24917E-07 -7.6035 0.27420E+00 -0.5619 17 Pb++ 0.52312E-08 -8.2814 0.44317E-10 -10.3534 0.84717E-02 -2.0720 18 Ag+ 0.44377E-09 -9.3528 0.13048E-09 -9.8845 0.29402E+00 -0.5316 19 Ba++ 0.29087E-06 -6.5363 0.26325E-08 -8.5796 0.90504E-02 -2.0433 20 HPO4-- 0.17177E-08 -8.7650 0.16033E-10 -10.7950 0.93336E-02 -2.0299 21 HSiO3- 0.23375E-05 -5.6313 0.63462E-06 -6.1975 0.27150E+00 -0.5662 22 Ca(HSiO3)+ 0.13565E-07 -7.8676 0.40808E-08 -8.3893 0.30083E+00 -0.5217 23 Mg(HSiO3)+ 0.14051E-08 -8.8523 0.42271E-09 -9.3740 0.30083E+00 -0.5217 24 NaHSiO3,aq 0.13064E-05 -5.8839 0.13064E-05 -5.8839 0.10000E+01 0.0000 28 AgCl,aq 0.69565E-07 -7.1576 0.69565E-07 -7.1576 0.10000E+01 0.0000 29 AgCl2- 0.50010E-05 -5.3009 0.13578E-05 -5.8672 0.27150E+00 -0.5662 30 AgCl3-2 0.25590E-05 -5.5919 0.22138E-07 -7.6549 0.86513E-02 -2.0629 31 AgCl4-3 0.11440E-05 -5.9416 0.20556E-10 -10.6871 0.17969E-04 -4.7455 34 Ag(HS),aq 0.52627E-09 -9.2788 0.52627E-09 -9.2788 0.10000E+01 0.0000 35 Ag(HS)2- 0.31852E-08 -8.4969 0.86478E-09 -9.0631 0.27150E+00 -0.5662 36 AlO+ 0.14623E-10 -10.8350 0.43989E-11 -11.3567 0.30083E+00 -0.5217 38 HAlO2,aq 0.51679E-08 -8.2867 0.51679E-08 -8.2867 0.10000E+01 0.0000 39 AlO2- 0.23351E-04 -4.6317 0.55820E-05 -5.2532 0.23904E+00 -0.6215 41 Ba(HCO3)+ 0.15302E-05 -5.8152 0.47763E-06 -6.3209 0.31213E+00 -0.5057 42 BaCl+ 0.54040E-04 -4.2673 0.16257E-04 -4.7890 0.30083E+00 -0.5217 43 CH4,aq 0.20845E-08 -8.6810 0.25411E-08 -8.5950 0.12190E+01 0.0860 48 CO,aq 0.88247E-03 -3.0543 0.88247E-03 -3.0543 0.10000E+01 0.0000 49 CO2,aq 0.26787E+01 0.4279 0.32654E+01 0.5139 0.12190E+01 0.0860 50 CO3-2 0.53589E-10 -10.2709 0.46361E-12 -12.3338 0.86513E-02 -2.0629 51 CaCO3,aq 0.15181E-10 -10.8187 0.15181E-10 -10.8187 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.73093E-06 -6.1361 0.21988E-06 -6.6578 0.30083E+00 -0.5217 53 CaCl+ 0.24721E-03 -3.6069 0.74368E-04 -4.1286 0.30083E+00 -0.5217 54 CaCl2,aq 0.12551E-03 -3.9013 0.12551E-03 -3.9013 0.10000E+01 0.0000 55 CaOH+ 0.34842E-06 -6.4579 0.10481E-06 -6.9796 0.30083E+00 -0.5217 56 CaSO4,aq 0.90823E-07 -7.0418 0.90823E-07 -7.0418 0.10000E+01 0.0000 57 HCl,aq 0.10749E-02 -2.9686 0.10749E-02 -2.9686 0.10000E+01 0.0000 66 CuCl,aq 0.55630E-04 -4.2547 0.55630E-04 -4.2547 0.10000E+01 0.0000 67 CuCl2- 0.22081E-03 -3.6560 0.59950E-04 -4.2222 0.27150E+00 -0.5662 68 CuCl3-2 0.58710E-05 -5.2313 0.50791E-07 -7.2942 0.86513E-02 -2.0629 74 FeCl+ 0.62849E-06 -6.2017 0.18907E-06 -6.7234 0.30083E+00 -0.5217 75 FeCl2,aq 0.88192E-02 -2.0546 0.88192E-02 -2.0546 0.10000E+01 0.0000 77 FeO,aq 0.64926E-07 -7.1876 0.64926E-07 -7.1876 0.10000E+01 0.0000 78 FeOH+ 0.43917E-07 -7.3574 0.13212E-07 -7.8790 0.30083E+00 -0.5217 79 HFeO2- 0.94864E-08 -8.0229 0.25755E-08 -8.5891 0.27150E+00 -0.5662 82 FeO2- 0.55618E-08 -8.2548 0.15100E-08 -8.8210 0.27150E+00 -0.5662 83 HFeO2,aq 0.17470E-09 -9.7577 0.17470E-09 -9.7577 0.10000E+01 0.0000 84 H2,aq 0.44365E-02 -2.3530 0.54082E-02 -2.2669 0.12190E+01 0.0860 85 KCl,aq 0.52372E-01 -1.2809 0.52372E-01 -1.2809 0.10000E+01 0.0000 86 KHSO4,aq 0.12239E-01 -1.9123 0.12239E-01 -1.9123 0.10000E+01 0.0000 87 KOH,aq 0.83414E-06 -6.0788 0.83414E-06 -6.0788 0.10000E+01 0.0000 88 KSO4- 0.31903E-02 -2.4962 0.86615E-03 -3.0624 0.27150E+00 -0.5662 90 Mg(HCO3)+ 0.13107E-06 -6.8825 0.39430E-07 -7.4042 0.30083E+00 -0.5217 91 MgCl+ 0.18961E-04 -4.7221 0.57039E-05 -5.2438 0.30083E+00 -0.5217 92 MgOH+ 0.58834E-06 -6.2304 0.17699E-06 -6.7520 0.30083E+00 -0.5217 94 MnO,aq 0.22618E-07 -7.6456 0.22618E-07 -7.6456 0.10000E+01 0.0000 95 MnOH+ 0.13053E-06 -6.8843 0.39269E-07 -7.4060 0.30083E+00 -0.5217 97 HMnO2- 0.15809E-10 -10.8011 0.42921E-11 -11.3673 0.27150E+00 -0.5662 100 MnCl+ 0.11590E-02 -2.9359 0.34867E-03 -3.4576 0.30083E+00 -0.5217 101 MnSO4,aq 0.19457E-07 -7.7109 0.19457E-07 -7.7109 0.10000E+01 0.0000 102 NaCl,aq 0.35468E+00 -0.4502 0.35468E+00 -0.4502 0.10000E+01 0.0000 103 NaOH,aq 0.12283E-05 -5.9107 0.12283E-05 -5.9107 0.10000E+01 0.0000 105 OH- 0.96032E-05 -5.0176 0.22956E-05 -5.6391 0.23904E+00 -0.6215 110 HPO3-2 0.32104E-10 -10.4934 0.27774E-12 -12.5564 0.86513E-02 -2.0629 111 H3PO3,aq 0.26087E-09 -9.5836 0.26087E-09 -9.5836 0.10000E+01 0.0000 112 H2PO3- 0.12096E-07 -7.9174 0.32840E-08 -8.4836 0.27150E+00 -0.5662 113 H3PO4,aq 0.16693E-05 -5.7775 0.16693E-05 -5.7775 0.10000E+01 0.0000 114 H2PO4- 0.39335E-05 -5.4052 0.11198E-05 -5.9508 0.28469E+00 -0.5456 116 H4P2O7,aq 0.22624E-09 -9.6454 0.22624E-09 -9.6454 0.10000E+01 0.0000 117 H3P2O7- 0.55613E-08 -8.2548 0.15099E-08 -8.8211 0.27150E+00 -0.5662 118 H2P2O7-2 0.14715E-05 -5.8322 0.12730E-07 -7.8952 0.86513E-02 -2.0629 119 HP2O7-3 0.35816E-07 -7.4459 0.64358E-12 -12.1914 0.17969E-04 -4.7455 121 PbCl+ 0.31577E-05 -5.5006 0.94992E-06 -6.0223 0.30083E+00 -0.5217 122 PbCl2,aq 0.96620E-04 -4.0149 0.96620E-04 -4.0149 0.10000E+01 0.0000 123 PbCl3- 0.11707E-03 -3.9315 0.31785E-04 -4.4978 0.27150E+00 -0.5662 124 PbCl4-2 0.30665E-04 -4.5134 0.26529E-06 -6.5763 0.86513E-02 -2.0629 125 PbO,aq 0.30539E-08 -8.5151 0.30539E-08 -8.5151 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.88637E-04 -4.0524 0.88637E-04 -4.0524 0.10000E+01 0.0000 128 Pb(HS)3- 0.70163E-05 -5.1539 0.19049E-05 -5.7201 0.27150E+00 -0.5662 129 H2S,aq 0.10421E+01 0.0179 0.12704E+01 0.1039 0.12190E+01 0.0860 130 S2-2 0.14076E-07 -7.8515 0.12178E-09 -9.9144 0.86513E-02 -2.0629 131 S3-2 0.15418E-08 -8.8120 0.13339E-10 -10.8749 0.86513E-02 -2.0629 132 S3- 0.23473E-01 -1.6294 0.63727E-02 -2.1957 0.27150E+00 -0.5662 133 S4-2 0.13991E-09 -9.8541 0.12104E-11 -11.9171 0.86513E-02 -2.0629 134 S5-2 0.10668E-10 -10.9719 0.92291E-13 -13.0348 0.86513E-02 -2.0629 135 SO2,aq 0.28261E+00 -0.5488 0.28261E+00 -0.5488 0.10000E+01 0.0000 136 SO3-2 0.57464E-09 -9.2406 0.75654E-11 -11.1212 0.13165E-01 -1.8806 137 HSO3- 0.46292E-03 -3.3345 0.12568E-03 -3.9007 0.27150E+00 -0.5662 138 HSO4- 0.12718E-01 -1.8956 0.39185E-02 -2.4069 0.30811E+00 -0.5113 140 S2O3-2 0.48005E-06 -6.3187 0.41530E-08 -8.3816 0.86513E-02 -2.0629 141 HS2O3- 0.80173E-06 -6.0960 0.21767E-06 -6.6622 0.27150E+00 -0.5662 142 H2S2O3,aq 0.24544E-07 -7.6100 0.24544E-07 -7.6100 0.10000E+01 0.0000 150 S4O6-2 0.70711E-09 -9.1505 0.61174E-11 -11.2134 0.86513E-02 -2.0629 152 ZnCl+ 0.73092E-03 -3.1361 0.21988E-03 -3.6578 0.30083E+00 -0.5217 153 ZnCl2,aq 0.13677E-02 -2.8640 0.13677E-02 -2.8640 0.10000E+01 0.0000 154 ZnCl3- 0.21775E-03 -3.6620 0.59117E-04 -4.2283 0.27150E+00 -0.5662 155 ZnO,aq 0.29734E-07 -7.5267 0.29734E-07 -7.5267 0.10000E+01 0.0000 156 ZnOH+ 0.32111E-05 -5.4934 0.96598E-06 -6.0150 0.30083E+00 -0.5217 158 HZnO2- 0.27377E-09 -9.5626 0.74327E-10 -10.1289 0.27150E+00 -0.5662 Charge balance for all species = 0.2553E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1546054E-04 0.4302779E+01 0.3528567E+04 0.0000 2 H2O 0.1000000E+01 0.5249192E+02 0.7693935E+06 0.0000 3 Cl- 0.2243912E+00 0.6572134E+00 0.1895719E+05 4.1334 4 SO4-- 0.1497454E-03 0.2539426E+00 0.1984723E+05 4.8407 5 HCO3- 0.3119240E-04 0.2679568E+01 0.1330245E+06 0.3070 6 HS- 0.1494954E-03 0.1170295E+01 0.3148984E+05 0.9605 7 H4SiO4 0.1100538E+00 0.1100574E+00 0.8606507E+04 -0.9584 8 Al+++ 0.7445003E-17 0.2335659E-04 0.5127316E+00 -5.7654 9 Ca++ 0.2369675E-05 0.3762679E-03 0.1226924E+02 2.9543 10 Mg++ 0.1177842E-05 0.2085924E-04 0.4126042E+00 2.5712 11 Fe++ 0.1926258E-07 0.8820021E-02 0.4007597E+03 0.8051 12 K+ 0.5871502E-01 0.1265176E+00 0.4024986E+04 3.5922 13 Na+ 0.2044511E+00 0.5591320E+00 0.1045837E+05 4.0984 14 Mn++ 0.4385948E-06 0.1159651E-02 0.5183398E+02 2.1772 15 Zn++ 0.4889193E-09 0.2319639E-02 0.1233711E+03 -0.7904 16 Cu+ 0.9087197E-07 0.2824034E-03 0.1459929E+02 -2.2549 17 Pb++ 0.5231228E-08 0.3431765E-03 0.5784968E+02 0.3439 18 Ag+ 0.4437701E-09 0.8777674E-05 0.7703618E+00 -4.5358 19 Ba++ 0.2908718E-06 0.5586142E-04 0.6241997E+01 2.1177 20 HPO4-- 0.1717724E-08 0.8643155E-05 0.6749368E+00 -0.0977 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265117E+01 -.2754365E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5203245E+02 -.6766967E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517198E+00 0.2991957E-05 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160051E+01 0.9275066E-04 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1090941E+00 0.3450024E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2315215E-04 0.6713874E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3729743E-03 0.1549355E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8742818E-02 0.2393565E-04 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542378E+00 0.3615163E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.2799314E-03 0.1196783E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4066E-18 Mass of aqueous solution: 0.121834E+04 g Temperature = 593.00 C Pressure = 1903.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) quartz 0.3311E-01 -1.480 1.989 0.299 92.99 0.7511 bornite 0.2394E-04 -4.621 0.1201E-01 -1.920 0.5615 0.2363E-02 an30ab70 0.5165E-03 -3.287 0.1379 -0.860 6.447 0.5178E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.138910 g Volume = 0.805279 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 144 quartz -0.95 -0.95 0.00 0.000 0.00000E+00 197 bornite -50.27 -50.27 0.00 0.000 0.28161E-10 260 an30ab70 -6.32 -6.32 0.00 0.000 0.70403E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.294 0.11638E+04 2.986 2 CO2,gas -8.99 -10.39 -1.39 -0.465 0.55288E+04 1.884 3 CH4,gas 6.91 -3.58 -10.48 -2.621 0.41545E+05 -7.203 4 H2,gas 5.75 1.70 -4.04 -2.311 0.16030E+05 -0.765 5 H2S,gas -7.47 -9.74 -2.26 -1.131 0.89646E+04 1.018 6 CO,gas -3.10 -8.68 -5.59 -1.719 0.22149E+05 -2.309 7 SO3,gas -6.34 -16.55 -10.21 -2.552 0.40456E+05 -6.928 8 O2,gas 16.47 -3.41 -19.88 -13.254 0.78796E+05 -16.602 9 HCl,gas -5.58 -6.56 -0.98 -0.491 0.38958E+04 -0.983 10 acmite 3.94 2.14 -1.80 -0.187 0.71248E+04 12 akimotoite 5.82 1.61 -4.20 -0.840 0.16653E+05 13 akimotoite-Fe 3.80 -0.15 -3.96 -0.791 0.15675E+05 14 albite-high -4.39 -4.53 -0.14 -0.011 0.56497E+03 15 albite -4.36 -4.53 -0.18 -0.014 0.70006E+03 16 almandine -10.46 -11.99 -1.53 -0.077 0.60645E+04 17 pyrope -4.11 -6.69 -2.59 -0.129 0.10253E+05 18 analcite -2.63 -3.58 -0.95 -0.105 0.37600E+04 19 andalusite -12.39 -12.49 -0.10 -0.010 0.40893E+03 21 grossular -0.57 -5.54 -4.97 -0.249 0.19699E+05 22 anhydrite -13.40 -13.60 -0.20 -0.098 0.77343E+03 24 annite -0.74 -2.63 -1.90 -0.105 0.75182E+04 25 phlogopite 3.66 2.67 -1.00 -0.055 0.39487E+04 27 anorthite -10.02 -10.49 -0.47 -0.036 0.18660E+04 28 anthophyllite 13.53 10.35 -3.18 -0.086 0.12615E+05 29 anthophyllite-Fe 1.50 -2.01 -3.51 -0.095 0.13915E+05 30 apatite-OH -49.70 -49.71 0.00 0.000 0.11125E+02 31 apatite-OH-zs -47.62 -49.71 -2.09 -0.161 0.82750E+04 32 apatite-Cl-zs -53.26 -56.27 -3.01 -0.250 0.11911E+05 33 aragonite -3.97 -7.44 -3.47 -1.156 0.13749E+05 34 brucite 4.90 2.57 -2.34 -0.468 0.92669E+04 35 calcite -4.06 -7.44 -3.38 -1.127 0.13399E+05 36 carnegieite-low -0.86 -2.63 -1.77 -0.253 0.70101E+04 37 carnegieite-high -0.79 -2.63 -1.83 -0.262 0.72586E+04 38 carpholite-Mg -9.16 -10.88 -1.72 -0.115 0.68273E+04 39 carpholite-Fe -10.45 -12.65 -2.19 -0.146 0.86973E+04 40 celadonite -1.19 -3.43 -2.24 -0.132 0.88631E+04 41 celadonite-Fe -2.54 -5.19 -2.65 -0.156 0.10508E+05 42 chrysotile 8.62 5.79 -2.83 -0.236 0.11204E+05 44 clinochlore 0.27 -1.56 -1.83 -0.057 0.72605E+04 45 daphnite -6.48 -10.39 -3.91 -0.122 0.15514E+05 48 chloritoid-Mg -8.86 -9.92 -1.06 -0.071 0.42048E+04 49 chloritoid-Fe -10.70 -11.69 -0.99 -0.066 0.39134E+04 50 chloritoid-Mn -8.54 -10.32 -1.78 -0.119 0.70533E+04 52 coesite -0.68 -0.95 -0.27 -0.091 0.10790E+04 53 cordierite-H -22.34 -22.71 -0.37 -0.013 0.14655E+04 54 cordierite-Fe -24.67 -26.24 -1.57 -0.054 0.62215E+04 55 cordierite-Mn -20.26 -23.49 -3.24 -0.112 0.12822E+05 56 corundum -11.28 -11.54 -0.26 -0.024 0.10384E+04 58 cristobalite -0.90 -0.95 -0.06 -0.019 0.22463E+03 59 cummingtonite 13.59 10.35 -3.24 -0.087 0.12828E+05 61 cymrite-K -2.81 -5.04 -2.24 -0.186 0.88604E+04 63 diaspore -5.14 -5.77 -0.63 -0.105 0.24987E+04 65 diopside 5.22 3.61 -1.60 -0.160 0.63557E+04 66 hedenbergite 3.86 1.85 -2.01 -0.201 0.79798E+04 68 eastonite -9.21 -10.49 -1.28 -0.049 0.50675E+04 69 enstatite 4.35 3.23 -1.12 -0.112 0.44511E+04 70 clinoenstatite-HiP 4.83 3.23 -1.60 -0.160 0.63311E+04 71 clinoenstatite 4.34 3.23 -1.11 -0.111 0.44058E+04 72 protoenstatite 4.48 3.23 -1.25 -0.125 0.49683E+04 73 epidote -6.36 -8.55 -2.19 -0.106 0.86783E+04 74 clinozoisite -11.98 -14.27 -2.28 -0.104 0.90553E+04 75 epidote-Fe 0.92 -2.83 -3.75 -0.195 0.14862E+05 76 fayalite 1.81 0.65 -1.16 -0.166 0.46017E+04 77 ferrosilite 0.94 -0.30 -1.24 -0.124 0.49288E+04 78 forsterite 5.63 4.18 -1.45 -0.207 0.57465E+04 79 gedrite -13.95 -15.96 -2.01 -0.054 0.79515E+04 81 gibbsite -3.57 -5.77 -2.20 -0.314 0.87116E+04 82 glaucophane 0.24 -3.27 -3.51 -0.095 0.13918E+05 83 glaucophane-Fe -3.61 -8.57 -4.96 -0.134 0.19668E+05 84 goethite 0.89 -0.05 -0.94 -0.203 0.37134E+04 86 greenalite 4.00 0.50 -3.51 -0.292 0.13903E+05 87 grunerite 2.02 -2.01 -4.03 -0.109 0.15982E+05 88 halite -0.36 -2.47 -2.10 -1.051 0.83341E+04 89 hematite 0.29 -0.10 -0.39 -0.047 0.15287E+04 90 heulandite -12.67 -15.28 -2.61 -0.119 0.10340E+05 91 hercynite -9.91 -10.73 -0.82 -0.055 0.32549E+04 94 jadeite -1.96 -3.58 -1.62 -0.162 0.64114E+04 96 kalsilite -1.50 -3.13 -1.64 -0.234 0.64807E+04 97 kaolinite -11.10 -13.45 -2.35 -0.213 0.92963E+04 98 kyanite -12.25 -12.49 -0.24 -0.024 0.96189E+03 100 laumontite -9.20 -12.41 -3.22 -0.214 0.12742E+05 101 lawsonite -7.38 -10.50 -3.12 -0.208 0.12365E+05 102 leucite -3.09 -4.09 -0.99 -0.099 0.39422E+04 104 lizardite 8.82 5.79 -3.02 -0.252 0.11976E+05 105 magnesite -5.02 -7.82 -2.80 -0.933 0.11091E+05 106 magnetite 1.15 0.70 -0.44 -0.036 0.17514E+04 107 minnesotaite 0.87 -1.41 -2.28 -0.134 0.90305E+04 108 minnesotaite-Mg 6.58 3.89 -2.69 -0.158 0.10647E+05 109 magnesioferrite 4.10 2.47 -1.63 -0.133 0.64446E+04 111 manganosite 4.99 2.17 -2.81 -0.703 0.11145E+05 112 margarite -20.85 -22.03 -1.18 -0.047 0.46902E+04 115 microcline -4.95 -5.04 -0.09 -0.007 0.35277E+03 116 monticellite 8.29 4.57 -3.72 -0.532 0.14759E+05 118 mullite-Si -11.68 -12.49 -0.81 -0.081 0.32073E+04 119 muscovite -16.12 -16.58 -0.46 -0.027 0.18180E+04 120 paragonite -15.44 -16.07 -0.63 -0.037 0.25141E+04 121 nepheline -1.15 -2.63 -1.48 -0.211 0.58657E+04 122 osumilite(2) -14.40 -16.50 -2.11 -0.044 0.83488E+04 123 osumilite-Fe -31.22 -33.19 -1.97 -0.041 0.78126E+04 124 pargasite 1.55 -2.75 -4.31 -0.113 0.17076E+05 125 periclase 5.10 2.57 -2.53 -0.632 0.10017E+05 126 periclase-Fe 2.62 0.80 -1.81 -0.453 0.71835E+04 127 perovskite-Al -9.60 -11.54 -1.94 -0.176 0.76894E+04 132 phlogopite-Na 4.53 3.17 -1.36 -0.075 0.53770E+04 134 prehnite -5.36 -8.50 -3.13 -0.184 0.12418E+05 135 prehnite-Fe 0.66 -2.78 -3.43 -0.207 0.13614E+05 138 px-Mg-tschermaks -8.31 -9.92 -1.61 -0.115 0.63903E+04 139 px-Ca-tschermaks -7.26 -9.54 -2.28 -0.163 0.90262E+04 140 pyrite -20.18 -20.37 -0.19 -0.045 0.75850E+03 141 pyrrhotite -8.17 -8.93 -0.76 -0.253 0.30114E+04 142 pyrrhotiteFe0.875 -8.87 -9.24 -0.38 -0.138 0.14875E+04 143 pyrophyllite -14.40 -15.36 -0.95 -0.059 0.37693E+04 146 riebeckite 6.55 2.87 -3.68 -0.102 0.14592E+05 147 ringwoodite-Fe 2.78 0.65 -2.13 -0.305 0.84525E+04 148 ringwoodite-Mg 8.69 4.18 -4.51 -0.644 0.17874E+05 149 rhodochrosite -4.86 -8.21 -3.35 -1.117 0.13286E+05 150 rhodonite 2.45 1.22 -1.23 -0.246 0.48740E+04 151 sanidine -4.43 -5.04 -0.61 -0.047 0.24184E+04 152 sapphirine(351) -46.90 -50.93 -4.03 -0.061 0.15992E+05 153 siderite -6.77 -9.59 -2.82 -0.940 0.11174E+05 154 sillimanite -12.36 -12.49 -0.13 -0.013 0.50626E+03 156 spinel -7.83 -8.97 -1.14 -0.076 0.45245E+04 158 staurolite-Fe -104.34 -107.78 -3.44 -0.031 0.13633E+05 159 staurolite-Mg -96.26 -100.72 -4.46 -0.041 0.17673E+05 162 stilpnomelane-Fe -8.46 -13.37 -4.92 -0.147 0.19487E+05 163 stilpnomelane-Mg -2.09 -4.54 -2.46 -0.073 0.97318E+04 164 stishovite 1.90 -0.95 -2.85 -0.951 0.11307E+05 165 sudoite-Fe -20.91 -24.34 -3.43 -0.111 0.13597E+05 166 sudoite -18.80 -20.81 -2.01 -0.065 0.79542E+04 167 sulfur -9.96 -11.44 -1.48 -0.455 0.58637E+04 168 sylvite -0.28 -2.97 -2.70 -1.348 0.10682E+05 169 talc 4.88 3.89 -0.99 -0.058 0.39264E+04 170 talc-Fe 2.21 -1.41 -3.62 -0.213 0.14332E+05 171 talc-tschermaks -7.71 -9.26 -1.56 -0.091 0.61632E+04 173 tephroite 6.14 3.40 -2.74 -0.391 0.10859E+05 176 topaz-H -10.36 -12.49 -2.14 -0.194 0.84661E+04 177 tremolite 14.69 11.11 -3.58 -0.097 0.14179E+05 179 troilite-low -8.07 -8.93 -0.86 -0.286 0.34025E+04 180 tschermakite -12.01 -15.19 -3.18 -0.086 0.12592E+05 183 wadsleyite-Fe 2.63 0.65 -1.98 -0.283 0.78427E+04 184 wadsleyite-Mg 7.77 4.18 -3.59 -0.513 0.14225E+05 185 wairakite -10.92 -12.41 -1.49 -0.087 0.58938E+04 186 walstromite 4.58 2.00 -2.58 -0.516 0.10234E+05 187 wollastonite 4.18 2.00 -2.19 -0.437 0.86645E+04 188 pseudo-wollastonite 4.29 2.00 -2.29 -0.459 0.90882E+04 189 zoisite -12.04 -14.27 -2.22 -0.101 0.88032E+04 192 beidellite-Ca -15.21 -16.46 -1.24 -0.077 0.49321E+04 193 beidellite-H -15.21 -16.94 -1.73 -0.111 0.68751E+04 194 beidellite-K -14.15 -15.76 -1.61 -0.099 0.63954E+04 195 beidellite-Mg -15.53 -16.52 -0.99 -0.061 0.39271E+04 196 beidellite-Na -14.08 -15.59 -1.51 -0.092 0.59863E+04 199 chalcocite -12.99 -14.25 -1.26 -0.315 0.49979E+04 200 covellite -11.55 -12.84 -1.30 -0.494 0.51343E+04 202 montmorillonite-Ca -11.11 -12.12 -1.01 -0.063 0.40097E+04 203 montmorillonite-K -10.33 -11.42 -1.09 -0.067 0.43049E+04 204 montmorillonite-Mg -11.35 -12.18 -0.83 -0.051 0.32871E+04 205 montmorillonite-Na -9.96 -11.25 -1.29 -0.079 0.51164E+04 206 nontronite-Ca -3.43 -5.02 -1.59 -0.103 0.63142E+04 207 nontronite-H -3.43 -5.51 -2.08 -0.139 0.82255E+04 208 nontronite-K -2.36 -4.32 -1.96 -0.126 0.77692E+04 209 nontronite-Mg -3.68 -5.08 -1.40 -0.091 0.55427E+04 210 nontronite-Na -2.29 -4.15 -1.86 -0.119 0.73731E+04 215 gypsum -11.30 -13.60 -2.30 -0.576 0.91296E+04 232 alabandite -5.89 -7.56 -1.67 -0.555 0.66008E+04 234 anglesite -13.52 -16.21 -2.69 -1.343 0.10643E+05 237 barite -14.41 -14.44 -0.03 -0.014 0.11443E+03 238 boehmite -4.87 -5.77 -0.90 -0.151 0.35859E+04 240 chalcopyrite -21.72 -21.77 -0.05 -0.010 0.20866E+03 242 copper,native 1.80 -1.40 -3.20 -1.115 0.12702E+05 244 ferrous-oxide 1.71 0.80 -0.91 -0.227 0.35943E+04 245 galena -8.93 -9.39 -0.46 -0.155 0.18414E+04 246 silver,native 0.58 -3.68 -4.26 -1.483 0.16898E+05 248 litharge 5.19 0.34 -4.84 -1.211 0.19197E+05 255 sphalerite -10.31 -10.53 -0.21 -0.072 0.85036E+03 256 wurtzite -9.53 -10.53 -0.99 -0.331 0.39385E+04 257 zincite 1.86 -0.79 -2.65 -0.663 0.10511E+05 258 an20ab80 -5.71 -5.73 -0.02 -0.001 0.72353E+02 259 an25ab75 -6.02 -6.02 -0.01 0.000 0.22619E+02 261 tr.625ac.25prg.125 8.95 7.17 -1.78 -0.048 0.70577E+04 Calculations done for 593.0000 Deg. C; 1903.0000 bar Temperature changed by -1.000 degrees to 592.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 23 Loop limit = 500 Temperature = 592.00 C Pressure = 1856.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5503E+02 kg liquid = 0.9913E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9950 Stoichiometric ionic strength = .3310165E+01 Osmotic coef. = 0.0000 True ionic strength = .2606715E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14540E-04 -4.8374 0.41506E-05 -5.3819 0.28547E+00 -0.5444 2 H2O 0.99503E+00 -0.0022 0.99503E+00 -0.0022 3 Cl- 0.21976E+00 -0.6580 0.58434E-01 -1.2333 0.26590E+00 -0.5753 4 SO4-- 0.15519E-03 -3.8091 0.13535E-05 -5.8686 0.87211E-02 -2.0594 5 HCO3- 0.30183E-04 -4.5202 0.86163E-05 -5.0647 0.28547E+00 -0.5444 6 HS- 0.15010E-03 -3.8236 0.40230E-04 -4.3955 0.26802E+00 -0.5718 7 H4SiO4 0.10676E+00 -0.9716 0.10676E+00 -0.9716 0.10000E+01 0.0000 8 Al+++ 0.67932E-17 -17.1679 0.12236E-21 -21.9124 0.18012E-04 -4.7444 9 Ca++ 0.23743E-05 -5.6245 0.16963E-07 -7.7705 0.71442E-02 -2.1460 10 Mg++ 0.11897E-05 -5.9246 0.70652E-08 -8.1509 0.59387E-02 -2.2263 11 Fe++ 0.19341E-07 -7.7135 0.12040E-09 -9.9194 0.62251E-02 -2.2059 12 K+ 0.57742E-01 -1.2385 0.16888E-01 -1.7724 0.29248E+00 -0.5339 13 Na+ 0.20050E+00 -0.6979 0.53985E-01 -1.2677 0.26925E+00 -0.5698 14 Mn++ 0.44757E-06 -6.3491 0.28834E-08 -8.5401 0.64423E-02 -2.1910 15 Zn++ 0.49209E-09 -9.3080 0.30633E-11 -11.5138 0.62251E-02 -2.2059 16 Cu+ 0.82579E-07 -7.0831 0.22178E-07 -7.6541 0.26857E+00 -0.5709 17 Pb++ 0.50011E-08 -8.3009 0.39732E-10 -10.4009 0.79447E-02 -2.0999 18 Ag+ 0.43280E-09 -9.3637 0.12472E-09 -9.9041 0.28816E+00 -0.5404 19 Ba++ 0.29287E-06 -6.5333 0.24873E-08 -8.6043 0.84930E-02 -2.0709 20 HPO4-- 0.17670E-08 -8.7528 0.15482E-10 -10.8102 0.87619E-02 -2.0574 21 HSiO3- 0.23143E-05 -5.6356 0.61536E-06 -6.2109 0.26590E+00 -0.5753 22 Ca(HSiO3)+ 0.13588E-07 -7.8668 0.40072E-08 -8.3972 0.29491E+00 -0.5303 23 Mg(HSiO3)+ 0.14259E-08 -8.8459 0.42050E-09 -9.3762 0.29491E+00 -0.5303 24 NaHSiO3,aq 0.13405E-05 -5.8727 0.13405E-05 -5.8727 0.10000E+01 0.0000 28 AgCl,aq 0.70067E-07 -7.1545 0.70067E-07 -7.1545 0.10000E+01 0.0000 29 AgCl2- 0.49967E-05 -5.3013 0.13286E-05 -5.8766 0.26590E+00 -0.5753 30 AgCl3-2 0.25324E-05 -5.5965 0.20551E-07 -7.6872 0.81152E-02 -2.0907 31 AgCl4-3 0.11733E-05 -5.9306 0.18286E-10 -10.7379 0.15585E-04 -4.8073 34 Ag(HS),aq 0.55217E-09 -9.2579 0.55217E-09 -9.2579 0.10000E+01 0.0000 35 Ag(HS)2- 0.33692E-08 -8.4725 0.89586E-09 -9.0478 0.26590E+00 -0.5753 36 AlO+ 0.13525E-10 -10.8689 0.39885E-11 -11.3992 0.29491E+00 -0.5303 38 HAlO2,aq 0.49751E-08 -8.3032 0.49751E-08 -8.3032 0.10000E+01 0.0000 39 AlO2- 0.22500E-04 -4.6478 0.52614E-05 -5.2789 0.23384E+00 -0.6311 41 Ba(HCO3)+ 0.15456E-05 -5.8109 0.47310E-06 -6.3250 0.30609E+00 -0.5141 42 BaCl+ 0.54017E-04 -4.2675 0.15930E-04 -4.7978 0.29491E+00 -0.5303 43 CH4,aq 0.20668E-08 -8.6847 0.25171E-08 -8.5991 0.12179E+01 0.0856 48 CO,aq 0.86674E-03 -3.0621 0.86674E-03 -3.0621 0.10000E+01 0.0000 49 CO2,aq 0.26784E+01 0.4279 0.32619E+01 0.5135 0.12179E+01 0.0856 50 CO3-2 0.53582E-10 -10.2710 0.43483E-12 -12.3617 0.81152E-02 -2.0907 51 CaCO3,aq 0.15799E-10 -10.8014 0.15799E-10 -10.8014 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.71019E-06 -6.1486 0.20944E-06 -6.6789 0.29491E+00 -0.5303 53 CaCl+ 0.24446E-03 -3.6118 0.72093E-04 -4.1421 0.29491E+00 -0.5303 54 CaCl2,aq 0.12802E-03 -3.8927 0.12802E-03 -3.8927 0.10000E+01 0.0000 55 CaOH+ 0.35511E-06 -6.4496 0.10472E-06 -6.9800 0.29491E+00 -0.5303 56 CaSO4,aq 0.98059E-07 -7.0085 0.98059E-07 -7.0085 0.10000E+01 0.0000 57 HCl,aq 0.10890E-02 -2.9630 0.10890E-02 -2.9630 0.10000E+01 0.0000 66 CuCl,aq 0.52390E-04 -4.2808 0.52390E-04 -4.2808 0.10000E+01 0.0000 67 CuCl2- 0.20820E-03 -3.6815 0.55359E-04 -4.2568 0.26590E+00 -0.5753 68 CuCl3-2 0.54921E-05 -5.2603 0.44569E-07 -7.3510 0.81152E-02 -2.0907 74 FeCl+ 0.62218E-06 -6.2061 0.18348E-06 -6.7364 0.29491E+00 -0.5303 75 FeCl2,aq 0.88151E-02 -2.0548 0.88151E-02 -2.0548 0.10000E+01 0.0000 77 FeO,aq 0.69492E-07 -7.1581 0.69492E-07 -7.1581 0.10000E+01 0.0000 78 FeOH+ 0.44434E-07 -7.3523 0.13104E-07 -7.8826 0.29491E+00 -0.5303 79 HFeO2- 0.10123E-07 -7.9947 0.26917E-08 -8.5700 0.26590E+00 -0.5753 82 FeO2- 0.60242E-08 -8.2201 0.16018E-08 -8.7954 0.26590E+00 -0.5753 83 HFeO2,aq 0.19030E-09 -9.7206 0.19030E-09 -9.7206 0.10000E+01 0.0000 84 H2,aq 0.44641E-02 -2.3503 0.54367E-02 -2.2647 0.12179E+01 0.0856 85 KCl,aq 0.53062E-01 -1.2752 0.53062E-01 -1.2752 0.10000E+01 0.0000 86 KHSO4,aq 0.12382E-01 -1.9072 0.12382E-01 -1.9072 0.10000E+01 0.0000 87 KOH,aq 0.86229E-06 -6.0643 0.86229E-06 -6.0643 0.10000E+01 0.0000 88 KSO4- 0.33176E-02 -2.4792 0.88214E-03 -3.0545 0.26590E+00 -0.5753 90 Mg(HCO3)+ 0.12739E-06 -6.8948 0.37570E-07 -7.4252 0.29491E+00 -0.5303 91 MgCl+ 0.18935E-04 -4.7227 0.55841E-05 -5.2530 0.29491E+00 -0.5303 92 MgOH+ 0.60341E-06 -6.2194 0.17795E-06 -6.7497 0.29491E+00 -0.5303 94 MnO,aq 0.24684E-07 -7.6076 0.24684E-07 -7.6076 0.10000E+01 0.0000 95 MnOH+ 0.13402E-06 -6.8728 0.39522E-07 -7.4032 0.29491E+00 -0.5303 97 HMnO2- 0.17135E-10 -10.7661 0.45562E-11 -11.3414 0.26590E+00 -0.5753 100 MnCl+ 0.11589E-02 -2.9360 0.34177E-03 -3.4663 0.29491E+00 -0.5303 101 MnSO4,aq 0.21339E-07 -7.6708 0.21339E-07 -7.6708 0.10000E+01 0.0000 102 NaCl,aq 0.35857E+00 -0.4454 0.35857E+00 -0.4454 0.10000E+01 0.0000 103 NaOH,aq 0.12675E-05 -5.8971 0.12675E-05 -5.8971 0.10000E+01 0.0000 105 OH- 0.96084E-05 -5.0173 0.22468E-05 -5.6484 0.23384E+00 -0.6311 110 HPO3-2 0.32330E-10 -10.4904 0.26236E-12 -12.5811 0.81152E-02 -2.0907 111 H3PO3,aq 0.25678E-09 -9.5904 0.25678E-09 -9.5904 0.10000E+01 0.0000 112 H2PO3- 0.11766E-07 -7.9294 0.31284E-08 -8.5047 0.26590E+00 -0.5753 113 H3PO4,aq 0.16763E-05 -5.7757 0.16763E-05 -5.7757 0.10000E+01 0.0000 114 H2PO4- 0.39110E-05 -5.4077 0.10910E-05 -5.9622 0.27895E+00 -0.5545 116 H4P2O7,aq 0.22895E-09 -9.6403 0.22895E-09 -9.6403 0.10000E+01 0.0000 117 H3P2O7- 0.54782E-08 -8.2614 0.14566E-08 -8.8367 0.26590E+00 -0.5753 118 H2P2O7-2 0.14762E-05 -5.8308 0.11980E-07 -7.9215 0.81152E-02 -2.0907 119 HP2O7-3 0.38621E-07 -7.4132 0.60191E-12 -12.2205 0.15585E-04 -4.8073 121 PbCl+ 0.30165E-05 -5.5205 0.88959E-06 -6.0508 0.29491E+00 -0.5303 122 PbCl2,aq 0.95032E-04 -4.0221 0.95032E-04 -4.0221 0.10000E+01 0.0000 123 PbCl3- 0.11587E-03 -3.9360 0.30808E-04 -4.5113 0.26590E+00 -0.5753 124 PbCl4-2 0.30133E-04 -4.5210 0.24453E-06 -6.6117 0.81152E-02 -2.0907 125 PbO,aq 0.32186E-08 -8.4923 0.32186E-08 -8.4923 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.91561E-04 -4.0383 0.91561E-04 -4.0383 0.10000E+01 0.0000 128 Pb(HS)3- 0.75252E-05 -5.1235 0.20009E-05 -5.6988 0.26590E+00 -0.5753 129 H2S,aq 0.10427E+01 0.0182 0.12699E+01 0.1038 0.12179E+01 0.0856 130 S2-2 0.14440E-07 -7.8404 0.11718E-09 -9.9311 0.81152E-02 -2.0907 131 S3-2 0.15692E-08 -8.8043 0.12734E-10 -10.8950 0.81152E-02 -2.0907 132 S3- 0.23142E-01 -1.6356 0.61534E-02 -2.2109 0.26590E+00 -0.5753 133 S4-2 0.14137E-09 -9.8496 0.11473E-11 -11.9403 0.81152E-02 -2.0907 134 S5-2 0.10712E-10 -10.9701 0.86929E-13 -13.0608 0.81152E-02 -2.0907 135 SO2,aq 0.28262E+00 -0.5488 0.28262E+00 -0.5488 0.10000E+01 0.0000 136 SO3-2 0.58425E-09 -9.2334 0.72460E-11 -11.1399 0.12402E-01 -1.9065 137 HSO3- 0.45910E-03 -3.3381 0.12207E-03 -3.9134 0.26590E+00 -0.5753 138 HSO4- 0.12621E-01 -1.8989 0.38131E-02 -2.4187 0.30211E+00 -0.5198 140 S2O3-2 0.49211E-06 -6.3079 0.39936E-08 -8.3986 0.81152E-02 -2.0907 141 HS2O3- 0.78490E-06 -6.1052 0.20870E-06 -6.6805 0.26590E+00 -0.5753 142 H2S2O3,aq 0.24433E-07 -7.6120 0.24433E-07 -7.6120 0.10000E+01 0.0000 150 S4O6-2 0.70636E-09 -9.1510 0.57322E-11 -11.2417 0.81152E-02 -2.0907 152 ZnCl+ 0.71809E-03 -3.1438 0.21177E-03 -3.6741 0.29491E+00 -0.5303 153 ZnCl2,aq 0.13830E-02 -2.8592 0.13830E-02 -2.8592 0.10000E+01 0.0000 154 ZnCl3- 0.21503E-03 -3.6675 0.57176E-04 -4.2428 0.26590E+00 -0.5753 155 ZnO,aq 0.31931E-07 -7.4958 0.31931E-07 -7.4958 0.10000E+01 0.0000 156 ZnOH+ 0.32543E-05 -5.4875 0.95973E-06 -6.0179 0.29491E+00 -0.5303 158 HZnO2- 0.29370E-09 -9.5321 0.78093E-10 -10.1074 0.26590E+00 -0.5753 Charge balance for all species = 0.2553E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1453983E-04 0.4302346E+01 0.3529148E+04 0.0000 2 H2O 0.1000000E+01 0.5249304E+02 0.7696141E+06 0.0000 3 Cl- 0.2197616E+00 0.6571453E+00 0.1896026E+05 4.1485 4 SO4-- 0.1551945E-03 0.2539159E+00 0.1985041E+05 4.8952 5 HCO3- 0.3018286E-04 0.2679290E+01 0.1330460E+06 0.3172 6 HS- 0.1501010E-03 0.1170161E+01 0.3149460E+05 0.9864 7 H4SiO4 0.1067628E+00 0.1067664E+00 0.8351366E+04 -0.9716 8 Al+++ 0.6793238E-17 0.2250494E-04 0.4941670E+00 -5.7667 9 Ca++ 0.2374303E-05 0.3760329E-03 0.1226484E+02 2.9933 10 Mg++ 0.1189695E-05 0.2085707E-04 0.4126710E+00 2.6129 11 Fe++ 0.1934097E-07 0.8815865E-02 0.4006772E+03 0.8444 12 K+ 0.5774168E-01 0.1265045E+00 0.4025637E+04 3.6095 13 Na+ 0.2004996E+00 0.5590736E+00 0.1046006E+05 4.1142 14 Mn++ 0.4475656E-06 0.1159530E-02 0.5184237E+02 2.2237 15 Zn++ 0.4920875E-09 0.2319399E-02 0.1233911E+03 -0.7500 16 Cu+ 0.8257922E-07 0.2661639E-03 0.1376342E+02 -2.2722 17 Pb++ 0.5001081E-08 0.3431410E-03 0.5785903E+02 0.3629 18 Ag+ 0.4327987E-09 0.8776765E-05 0.7704864E+00 -4.5222 19 Ba++ 0.2928665E-06 0.5585563E-04 0.6243007E+01 2.1595 20 HPO4-- 0.1767011E-08 0.8642260E-05 0.6750460E+00 -0.0464 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265129E+01 -.2766972E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5203895E+02 -.7417206E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517194E+00 0.3393705E-05 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160039E+01 0.1052049E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1058429E+00 0.3775147E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2231026E-04 0.6722293E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3727801E-03 0.1551298E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8739604E-02 0.2714964E-04 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542374E+00 0.3619696E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.2638615E-03 0.1357482E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.8132E-19 Mass of aqueous solution: 0.121814E+04 g Temperature = 592.00 C Pressure = 1856.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) quartz 0.3636E-01 -1.439 2.184 0.339 93.51 0.8249 bornite 0.2715E-04 -4.566 0.1362E-01 -1.866 0.5832 0.2680E-02 an30ab70 0.5171E-03 -3.286 0.1381 -0.860 5.911 0.5185E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.335925 g Volume = 0.879389 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 144 quartz -0.97 -0.97 0.00 0.000 0.00000E+00 197 bornite -50.48 -50.48 0.00 0.000 0.00000E+00 260 an30ab70 -6.34 -6.34 0.00 0.000 -0.35161E-11 30 apatite-OH -49.94 -49.76 0.19 0.014 -0.73696E+03 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.293 0.11595E+04 2.976 2 CO2,gas -9.04 -10.44 -1.41 -0.470 0.55774E+04 1.860 3 CH4,gas 6.91 -3.59 -10.50 -2.626 0.41583E+05 -7.235 4 H2,gas 5.76 1.71 -4.04 -2.311 0.16009E+05 -0.775 5 H2S,gas -7.51 -9.78 -2.27 -1.133 0.89667E+04 1.004 6 CO,gas -3.13 -8.73 -5.60 -1.725 0.22188E+05 -2.336 7 SO3,gas -6.40 -16.63 -10.23 -2.556 0.40482E+05 -6.957 8 O2,gas 16.48 -3.43 -19.90 -13.270 0.78797E+05 -16.636 9 HCl,gas -5.60 -6.62 -1.01 -0.506 0.40042E+04 -1.011 10 acmite 3.91 2.16 -1.75 -0.182 0.69168E+04 12 akimotoite 5.82 1.64 -4.17 -0.835 0.16521E+05 13 akimotoite-Fe 3.80 -0.13 -3.93 -0.785 0.15543E+05 14 albite-high -4.42 -4.56 -0.14 -0.011 0.56725E+03 15 albite -4.38 -4.56 -0.18 -0.014 0.69900E+03 16 almandine -10.44 -11.91 -1.47 -0.074 0.58238E+04 17 pyrope -4.08 -6.61 -2.53 -0.127 0.10019E+05 18 analcite -2.64 -3.59 -0.95 -0.106 0.37684E+04 19 andalusite -12.36 -12.51 -0.14 -0.014 0.56385E+03 21 grossular -0.56 -5.47 -4.90 -0.245 0.19415E+05 22 anhydrite -13.48 -13.64 -0.16 -0.080 0.63097E+03 24 annite -0.74 -2.54 -1.80 -0.100 0.71075E+04 25 phlogopite 3.66 2.77 -0.90 -0.050 0.35436E+04 27 anorthite -10.01 -10.48 -0.47 -0.036 0.18650E+04 28 anthophyllite 13.48 10.53 -2.95 -0.080 0.11669E+05 29 anthophyllite-Fe 1.43 -1.84 -3.27 -0.088 0.12946E+05 31 apatite-OH-zs -47.86 -49.76 -1.90 -0.146 0.75304E+04 32 apatite-Cl-zs -53.54 -56.37 -2.83 -0.236 0.11212E+05 33 aragonite -4.01 -7.45 -3.45 -1.149 0.13649E+05 34 brucite 4.92 2.61 -2.31 -0.462 0.91364E+04 35 calcite -4.09 -7.45 -3.36 -1.120 0.13296E+05 36 carnegieite-low -0.85 -2.62 -1.77 -0.253 0.70082E+04 37 carnegieite-high -0.79 -2.62 -1.83 -0.262 0.72581E+04 38 carpholite-Mg -9.13 -10.87 -1.73 -0.116 0.68609E+04 39 carpholite-Fe -10.43 -12.64 -2.21 -0.147 0.87302E+04 40 celadonite -1.21 -3.42 -2.21 -0.130 0.87413E+04 41 celadonite-Fe -2.57 -5.19 -2.62 -0.154 0.10386E+05 42 chrysotile 8.62 5.89 -2.73 -0.227 0.10800E+05 44 clinochlore 0.31 -1.40 -1.70 -0.053 0.67403E+04 45 daphnite -6.45 -10.24 -3.79 -0.118 0.14989E+05 48 chloritoid-Mg -8.83 -9.90 -1.07 -0.071 0.42320E+04 49 chloritoid-Fe -10.67 -11.67 -0.99 -0.066 0.39362E+04 50 chloritoid-Mn -8.51 -10.29 -1.78 -0.119 0.70442E+04 52 coesite -0.69 -0.97 -0.27 -0.091 0.10812E+04 53 cordierite-H -22.32 -22.70 -0.38 -0.014 0.14965E+04 54 cordierite-Fe -24.66 -26.23 -1.57 -0.054 0.62172E+04 55 cordierite-Mn -20.25 -23.47 -3.22 -0.111 0.12753E+05 56 corundum -11.24 -11.54 -0.30 -0.027 0.11964E+04 58 cristobalite -0.91 -0.97 -0.06 -0.019 0.22087E+03 59 cummingtonite 13.54 10.53 -3.00 -0.081 0.11884E+05 61 cymrite-K -2.82 -5.07 -2.24 -0.187 0.88785E+04 63 diaspore -5.12 -5.77 -0.65 -0.109 0.25799E+04 65 diopside 5.20 3.67 -1.53 -0.153 0.60747E+04 66 hedenbergite 3.84 1.90 -1.94 -0.194 0.76971E+04 68 eastonite -9.17 -10.42 -1.25 -0.048 0.49522E+04 69 enstatite 4.34 3.29 -1.06 -0.106 0.41823E+04 70 clinoenstatite-HiP 4.82 3.29 -1.53 -0.153 0.60641E+04 71 clinoenstatite 4.33 3.29 -1.04 -0.104 0.41363E+04 72 protoenstatite 4.47 3.29 -1.19 -0.119 0.46984E+04 73 epidote -6.35 -8.48 -2.12 -0.103 0.84058E+04 74 clinozoisite -11.96 -14.23 -2.27 -0.103 0.90030E+04 75 epidote-Fe 0.91 -2.72 -3.63 -0.189 0.14366E+05 76 fayalite 1.81 0.72 -1.09 -0.156 0.43246E+04 77 ferrosilite 0.93 -0.25 -1.18 -0.118 0.46550E+04 78 forsterite 5.64 4.25 -1.38 -0.198 0.54734E+04 79 gedrite -13.91 -15.83 -1.92 -0.052 0.75902E+04 81 gibbsite -3.55 -5.77 -2.22 -0.318 0.88013E+04 82 glaucophane 0.20 -3.22 -3.42 -0.092 0.13528E+05 83 glaucophane-Fe -3.66 -8.53 -4.87 -0.132 0.19271E+05 84 goethite 0.89 -0.02 -0.90 -0.195 0.35762E+04 86 greenalite 3.99 0.59 -3.41 -0.284 0.13484E+05 87 grunerite 1.95 -1.84 -3.79 -0.103 0.15015E+05 88 halite -0.40 -2.50 -2.10 -1.049 0.83093E+04 89 hematite 0.29 -0.03 -0.31 -0.038 0.12455E+04 90 heulandite -12.71 -15.33 -2.63 -0.119 0.10394E+05 91 hercynite -9.87 -10.70 -0.83 -0.055 0.32725E+04 94 jadeite -1.97 -3.59 -1.62 -0.162 0.64222E+04 96 kalsilite -1.49 -3.13 -1.64 -0.234 0.64805E+04 97 kaolinite -11.09 -13.48 -2.39 -0.217 0.94540E+04 98 kyanite -12.22 -12.51 -0.28 -0.028 0.11229E+04 100 laumontite -9.20 -12.43 -3.23 -0.215 0.12774E+05 101 lawsonite -7.36 -10.49 -3.13 -0.209 0.12396E+05 102 leucite -3.10 -4.10 -1.00 -0.100 0.39397E+04 104 lizardite 8.82 5.89 -2.92 -0.244 0.11568E+05 105 magnesite -5.05 -7.83 -2.78 -0.926 0.11003E+05 106 magnetite 1.15 0.81 -0.34 -0.027 0.13279E+04 107 minnesotaite 0.83 -1.34 -2.17 -0.128 0.86080E+04 108 minnesotaite-Mg 6.55 3.96 -2.58 -0.152 0.10231E+05 109 magnesioferrite 4.10 2.58 -1.52 -0.124 0.60226E+04 111 manganosite 4.99 2.22 -2.77 -0.693 0.10974E+05 112 margarite -20.80 -22.03 -1.23 -0.049 0.48592E+04 115 microcline -4.98 -5.06 -0.09 -0.007 0.34759E+03 116 monticellite 8.29 4.63 -3.66 -0.522 0.14470E+05 118 mullite-Si -11.66 -12.51 -0.85 -0.085 0.33660E+04 119 muscovite -16.10 -16.61 -0.50 -0.029 0.19846E+04 120 paragonite -15.42 -16.10 -0.68 -0.040 0.26828E+04 121 nepheline -1.14 -2.62 -1.48 -0.212 0.58643E+04 122 osumilite(2) -14.47 -16.51 -2.04 -0.042 0.80673E+04 123 osumilite-Fe -31.26 -33.23 -1.97 -0.041 0.78163E+04 124 pargasite 1.57 -2.58 -4.15 -0.109 0.16413E+05 125 periclase 5.11 2.61 -2.50 -0.624 0.98796E+04 126 periclase-Fe 2.62 0.84 -1.78 -0.445 0.70456E+04 127 perovskite-Al -9.56 -11.54 -1.98 -0.180 0.78479E+04 132 phlogopite-Na 4.53 3.27 -1.26 -0.070 0.49721E+04 134 prehnite -5.36 -8.46 -3.10 -0.182 0.12281E+05 135 prehnite-Fe 0.64 -2.71 -3.35 -0.201 0.13252E+05 138 px-Mg-tschermaks -8.28 -9.90 -1.62 -0.116 0.64130E+04 139 px-Ca-tschermaks -7.23 -9.52 -2.28 -0.163 0.90358E+04 140 pyrite -20.27 -20.42 -0.16 -0.037 0.61530E+03 141 pyrrhotite -8.21 -8.93 -0.72 -0.242 0.28697E+04 142 pyrrhotiteFe0.875 -8.91 -9.25 -0.34 -0.127 0.13642E+04 143 pyrophyllite -14.42 -15.41 -0.99 -0.062 0.39331E+04 146 riebeckite 6.46 2.98 -3.47 -0.096 0.13756E+05 147 ringwoodite-Fe 2.78 0.72 -2.07 -0.295 0.81769E+04 148 ringwoodite-Mg 8.70 4.25 -4.45 -0.635 0.17603E+05 149 rhodochrosite -4.90 -8.22 -3.32 -1.108 0.13162E+05 150 rhodonite 2.44 1.25 -1.19 -0.238 0.47046E+04 151 sanidine -4.45 -5.06 -0.61 -0.047 0.24136E+04 152 sapphirine(351) -46.70 -50.83 -4.13 -0.063 0.16367E+05 153 siderite -6.80 -9.60 -2.80 -0.933 0.11082E+05 154 sillimanite -12.34 -12.51 -0.17 -0.017 0.66342E+03 156 spinel -7.78 -8.93 -1.15 -0.076 0.45426E+04 158 staurolite-Fe -104.08 -107.75 -3.67 -0.034 0.14527E+05 159 staurolite-Mg -95.98 -100.67 -4.69 -0.043 0.18581E+05 162 stilpnomelane-Fe -8.49 -13.28 -4.79 -0.143 0.18947E+05 163 stilpnomelane-Mg -2.11 -4.43 -2.33 -0.070 0.92174E+04 164 stishovite 1.89 -0.97 -2.86 -0.953 0.11313E+05 165 sudoite-Fe -20.85 -24.31 -3.45 -0.111 0.13673E+05 166 sudoite -18.74 -20.77 -2.03 -0.065 0.80323E+04 167 sulfur -10.01 -11.49 -1.48 -0.456 0.58634E+04 168 sylvite -0.32 -3.01 -2.69 -1.345 0.10652E+05 169 talc 4.85 3.96 -0.89 -0.052 0.35170E+04 170 talc-Fe 2.17 -1.34 -3.52 -0.207 0.13916E+05 171 talc-tschermaks -7.70 -9.22 -1.53 -0.090 0.60450E+04 173 tephroite 6.13 3.48 -2.66 -0.379 0.10516E+05 176 topaz-H -10.33 -12.51 -2.18 -0.198 0.86328E+04 177 tremolite 14.63 11.30 -3.34 -0.090 0.13205E+05 179 troilite-low -8.11 -8.93 -0.82 -0.274 0.32595E+04 180 tschermakite -11.99 -15.07 -3.08 -0.083 0.12198E+05 183 wadsleyite-Fe 2.63 0.72 -1.91 -0.273 0.75679E+04 184 wadsleyite-Mg 7.78 4.25 -3.52 -0.504 0.13954E+05 185 wairakite -10.93 -12.42 -1.49 -0.088 0.58931E+04 186 walstromite 4.57 2.02 -2.55 -0.510 0.10086E+05 187 wollastonite 4.17 2.02 -2.15 -0.430 0.85132E+04 188 pseudo-wollastonite 4.28 2.02 -2.26 -0.452 0.89376E+04 189 zoisite -12.02 -14.23 -2.21 -0.101 0.87530E+04 192 beidellite-Ca -15.22 -16.50 -1.29 -0.080 0.50957E+04 193 beidellite-H -15.21 -17.00 -1.78 -0.114 0.70629E+04 194 beidellite-K -14.15 -15.81 -1.66 -0.101 0.65579E+04 195 beidellite-Mg -15.53 -16.57 -1.04 -0.064 0.40986E+04 196 beidellite-Na -14.09 -15.64 -1.55 -0.095 0.61497E+04 199 chalcocite -13.05 -14.32 -1.28 -0.319 0.50542E+04 200 covellite -11.60 -12.91 -1.30 -0.496 0.51584E+04 202 montmorillonite-Ca -11.12 -12.15 -1.03 -0.064 0.40748E+04 203 montmorillonite-K -10.35 -11.45 -1.10 -0.068 0.43725E+04 204 montmorillonite-Mg -11.37 -12.21 -0.85 -0.052 0.33528E+04 205 montmorillonite-Na -9.98 -11.29 -1.31 -0.080 0.51780E+04 206 nontronite-Ca -3.47 -4.99 -1.53 -0.099 0.60410E+04 207 nontronite-H -3.47 -5.49 -2.01 -0.135 0.79767E+04 208 nontronite-K -2.40 -4.29 -1.89 -0.122 0.74951E+04 209 nontronite-Mg -3.72 -5.05 -1.33 -0.086 0.52721E+04 210 nontronite-Na -2.33 -4.13 -1.79 -0.115 0.71002E+04 215 gypsum -11.37 -13.64 -2.28 -0.569 0.90097E+04 232 alabandite -5.93 -7.55 -1.62 -0.541 0.64278E+04 234 anglesite -13.60 -16.27 -2.67 -1.333 0.10553E+05 237 barite -14.49 -14.47 0.01 0.007 -0.52937E+02 238 boehmite -4.84 -5.77 -0.93 -0.154 0.36675E+04 240 chalcopyrite -21.82 -21.84 -0.02 -0.004 0.91643E+02 242 copper,native 1.80 -1.42 -3.21 -1.118 0.12724E+05 244 ferrous-oxide 1.72 0.84 -0.87 -0.218 0.34573E+04 245 galena -8.98 -9.41 -0.44 -0.146 0.17325E+04 246 silver,native 0.58 -3.67 -4.24 -1.475 0.16792E+05 248 litharge 5.18 0.36 -4.82 -1.205 0.19089E+05 255 sphalerite -10.35 -10.53 -0.17 -0.058 0.68625E+03 256 wurtzite -9.57 -10.53 -0.95 -0.318 0.37748E+04 257 zincite 1.86 -0.75 -2.61 -0.654 0.10352E+05 258 an20ab80 -5.73 -5.74 -0.02 -0.001 0.72315E+02 259 an25ab75 -6.03 -6.04 -0.01 0.000 0.22696E+02 261 tr.625ac.25prg.125 8.90 7.35 -1.55 -0.042 0.61309E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 16 Loop limit = 500 Temperature = 592.00 C Pressure = 1856.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5503E+02 kg liquid = 0.9913E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9950 Stoichiometric ionic strength = .3310157E+01 Osmotic coef. = 0.0000 True ionic strength = .2606680E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14541E-04 -4.8374 0.41509E-05 -5.3819 0.28547E+00 -0.5444 2 H2O 0.99503E+00 -0.0022 0.99503E+00 -0.0022 3 Cl- 0.21976E+00 -0.6580 0.58434E-01 -1.2333 0.26590E+00 -0.5753 4 SO4-- 0.15517E-03 -3.8092 0.13533E-05 -5.8686 0.87212E-02 -2.0594 5 HCO3- 0.30181E-04 -4.5203 0.86158E-05 -5.0647 0.28547E+00 -0.5444 6 HS- 0.15009E-03 -3.8236 0.40227E-04 -4.3955 0.26802E+00 -0.5718 7 H4SiO4 0.10676E+00 -0.9716 0.10676E+00 -0.9716 0.10000E+01 0.0000 8 Al+++ 0.68044E-17 -17.1672 0.12257E-21 -21.9116 0.18013E-04 -4.7444 9 Ca++ 0.23595E-05 -5.6272 0.16857E-07 -7.7732 0.71444E-02 -2.1460 10 Mg++ 0.11897E-05 -5.9246 0.70652E-08 -8.1509 0.59388E-02 -2.2263 11 Fe++ 0.19340E-07 -7.7135 0.12040E-09 -9.9194 0.62252E-02 -2.2058 12 K+ 0.57742E-01 -1.2385 0.16888E-01 -1.7724 0.29248E+00 -0.5339 13 Na+ 0.20050E+00 -0.6979 0.53985E-01 -1.2677 0.26926E+00 -0.5698 14 Mn++ 0.44755E-06 -6.3492 0.28834E-08 -8.5401 0.64425E-02 -2.1909 15 Zn++ 0.49207E-09 -9.3080 0.30633E-11 -11.5138 0.62252E-02 -2.2058 16 Cu+ 0.82586E-07 -7.0831 0.22180E-07 -7.6540 0.26857E+00 -0.5709 17 Pb++ 0.50011E-08 -8.3009 0.39733E-10 -10.4008 0.79449E-02 -2.0999 18 Ag+ 0.43280E-09 -9.3637 0.12472E-09 -9.9041 0.28817E+00 -0.5404 19 Ba++ 0.29286E-06 -6.5333 0.24873E-08 -8.6043 0.84932E-02 -2.0709 20 HPO4-- 0.15478E-08 -8.8103 0.13562E-10 -10.8677 0.87621E-02 -2.0574 21 HSiO3- 0.23141E-05 -5.6356 0.61532E-06 -6.2109 0.26590E+00 -0.5753 22 Ca(HSiO3)+ 0.13503E-07 -7.8696 0.39821E-08 -8.3999 0.29491E+00 -0.5303 23 Mg(HSiO3)+ 0.14258E-08 -8.8460 0.42047E-09 -9.3763 0.29491E+00 -0.5303 24 NaHSiO3,aq 0.13404E-05 -5.8728 0.13404E-05 -5.8728 0.10000E+01 0.0000 28 AgCl,aq 0.70067E-07 -7.1545 0.70067E-07 -7.1545 0.10000E+01 0.0000 29 AgCl2- 0.49967E-05 -5.3013 0.13286E-05 -5.8766 0.26590E+00 -0.5753 30 AgCl3-2 0.25324E-05 -5.5965 0.20551E-07 -7.6872 0.81154E-02 -2.0907 31 AgCl4-3 0.11733E-05 -5.9306 0.18286E-10 -10.7379 0.15586E-04 -4.8073 34 Ag(HS),aq 0.55213E-09 -9.2580 0.55213E-09 -9.2580 0.10000E+01 0.0000 35 Ag(HS)2- 0.33688E-08 -8.4725 0.89574E-09 -9.0478 0.26590E+00 -0.5753 36 AlO+ 0.13546E-10 -10.8682 0.39947E-11 -11.3985 0.29491E+00 -0.5303 38 HAlO2,aq 0.49826E-08 -8.3025 0.49826E-08 -8.3025 0.10000E+01 0.0000 39 AlO2- 0.22532E-04 -4.6472 0.52689E-05 -5.2783 0.23384E+00 -0.6311 41 Ba(HCO3)+ 0.15455E-05 -5.8109 0.47307E-06 -6.3251 0.30609E+00 -0.5141 42 BaCl+ 0.54017E-04 -4.2675 0.15930E-04 -4.7978 0.29491E+00 -0.5303 43 CH4,aq 0.20668E-08 -8.6847 0.25170E-08 -8.5991 0.12179E+01 0.0856 48 CO,aq 0.86673E-03 -3.0621 0.86673E-03 -3.0621 0.10000E+01 0.0000 49 CO2,aq 0.26784E+01 0.4279 0.32619E+01 0.5135 0.12179E+01 0.0856 50 CO3-2 0.53574E-10 -10.2710 0.43477E-12 -12.3617 0.81154E-02 -2.0907 51 CaCO3,aq 0.15699E-10 -10.8041 0.15699E-10 -10.8041 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.70574E-06 -6.1514 0.20813E-06 -6.6817 0.29491E+00 -0.5303 53 CaCl+ 0.24295E-03 -3.6145 0.71647E-04 -4.1448 0.29491E+00 -0.5303 54 CaCl2,aq 0.12723E-03 -3.8954 0.12723E-03 -3.8954 0.10000E+01 0.0000 55 CaOH+ 0.35288E-06 -6.4524 0.10407E-06 -6.9827 0.29491E+00 -0.5303 56 CaSO4,aq 0.97440E-07 -7.0113 0.97440E-07 -7.0113 0.10000E+01 0.0000 57 HCl,aq 0.10891E-02 -2.9629 0.10891E-02 -2.9629 0.10000E+01 0.0000 66 CuCl,aq 0.52395E-04 -4.2807 0.52395E-04 -4.2807 0.10000E+01 0.0000 67 CuCl2- 0.20822E-03 -3.6815 0.55365E-04 -4.2568 0.26590E+00 -0.5753 68 CuCl3-2 0.54926E-05 -5.2602 0.44574E-07 -7.3509 0.81154E-02 -2.0907 74 FeCl+ 0.62217E-06 -6.2061 0.18348E-06 -6.7364 0.29491E+00 -0.5303 75 FeCl2,aq 0.88151E-02 -2.0548 0.88151E-02 -2.0548 0.10000E+01 0.0000 77 FeO,aq 0.69482E-07 -7.1581 0.69482E-07 -7.1581 0.10000E+01 0.0000 78 FeOH+ 0.44430E-07 -7.3523 0.13103E-07 -7.8826 0.29491E+00 -0.5303 79 HFeO2- 0.10121E-07 -7.9948 0.26912E-08 -8.5701 0.26590E+00 -0.5753 82 FeO2- 0.60229E-08 -8.2202 0.16015E-08 -8.7955 0.26590E+00 -0.5753 83 HFeO2,aq 0.19027E-09 -9.7206 0.19027E-09 -9.7206 0.10000E+01 0.0000 84 H2,aq 0.44641E-02 -2.3503 0.54367E-02 -2.2647 0.12179E+01 0.0856 85 KCl,aq 0.53063E-01 -1.2752 0.53063E-01 -1.2752 0.10000E+01 0.0000 86 KHSO4,aq 0.12382E-01 -1.9072 0.12382E-01 -1.9072 0.10000E+01 0.0000 87 KOH,aq 0.86224E-06 -6.0644 0.86224E-06 -6.0644 0.10000E+01 0.0000 88 KSO4- 0.33172E-02 -2.4792 0.88204E-03 -3.0545 0.26590E+00 -0.5753 90 Mg(HCO3)+ 0.12739E-06 -6.8949 0.37567E-07 -7.4252 0.29491E+00 -0.5303 91 MgCl+ 0.18935E-04 -4.7227 0.55842E-05 -5.2530 0.29491E+00 -0.5303 92 MgOH+ 0.60337E-06 -6.2194 0.17794E-06 -6.7497 0.29491E+00 -0.5303 94 MnO,aq 0.24681E-07 -7.6076 0.24681E-07 -7.6076 0.10000E+01 0.0000 95 MnOH+ 0.13401E-06 -6.8729 0.39519E-07 -7.4032 0.29491E+00 -0.5303 97 HMnO2- 0.17132E-10 -10.7662 0.45554E-11 -11.3415 0.26590E+00 -0.5753 100 MnCl+ 0.11589E-02 -2.9360 0.34177E-03 -3.4663 0.29491E+00 -0.5303 101 MnSO4,aq 0.21337E-07 -7.6709 0.21337E-07 -7.6709 0.10000E+01 0.0000 102 NaCl,aq 0.35857E+00 -0.4454 0.35857E+00 -0.4454 0.10000E+01 0.0000 103 NaOH,aq 0.12674E-05 -5.8971 0.12674E-05 -5.8971 0.10000E+01 0.0000 105 OH- 0.96077E-05 -5.0174 0.22467E-05 -5.6485 0.23384E+00 -0.6311 110 HPO3-2 0.28319E-10 -10.5479 0.22982E-12 -12.6386 0.81154E-02 -2.0907 111 H3PO3,aq 0.22496E-09 -9.6479 0.22496E-09 -9.6479 0.10000E+01 0.0000 112 H2PO3- 0.10307E-07 -7.9869 0.27406E-08 -8.5622 0.26590E+00 -0.5753 113 H3PO4,aq 0.14686E-05 -5.8331 0.14686E-05 -5.8331 0.10000E+01 0.0000 114 H2PO4- 0.34261E-05 -5.4652 0.95570E-06 -6.0197 0.27895E+00 -0.5545 116 H4P2O7,aq 0.17572E-09 -9.7552 0.17572E-09 -9.7552 0.10000E+01 0.0000 117 H3P2O7- 0.42042E-08 -8.3763 0.11179E-08 -8.9516 0.26590E+00 -0.5753 118 H2P2O7-2 0.11329E-05 -5.9458 0.91936E-08 -8.0365 0.81154E-02 -2.0907 119 HP2O7-3 0.29635E-07 -7.5282 0.46188E-12 -12.3355 0.15586E-04 -4.8073 121 PbCl+ 0.30166E-05 -5.5205 0.88962E-06 -6.0508 0.29491E+00 -0.5303 122 PbCl2,aq 0.95036E-04 -4.0221 0.95036E-04 -4.0221 0.10000E+01 0.0000 123 PbCl3- 0.11587E-03 -3.9360 0.30810E-04 -4.5113 0.26590E+00 -0.5753 124 PbCl4-2 0.30134E-04 -4.5209 0.24455E-06 -6.6116 0.81154E-02 -2.0907 125 PbO,aq 0.32183E-08 -8.4924 0.32183E-08 -8.4924 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.91552E-04 -4.0383 0.91552E-04 -4.0383 0.10000E+01 0.0000 128 Pb(HS)3- 0.75240E-05 -5.1236 0.20006E-05 -5.6988 0.26590E+00 -0.5753 129 H2S,aq 0.10427E+01 0.0182 0.12699E+01 0.1038 0.12179E+01 0.0856 130 S2-2 0.14438E-07 -7.8405 0.11717E-09 -9.9312 0.81154E-02 -2.0907 131 S3-2 0.15689E-08 -8.8044 0.12733E-10 -10.8951 0.81154E-02 -2.0907 132 S3- 0.23141E-01 -1.6356 0.61530E-02 -2.2109 0.26590E+00 -0.5753 133 S4-2 0.14136E-09 -9.8497 0.11472E-11 -11.9404 0.81154E-02 -2.0907 134 S5-2 0.10710E-10 -10.9702 0.86919E-13 -13.0609 0.81154E-02 -2.0907 135 SO2,aq 0.28262E+00 -0.5488 0.28262E+00 -0.5488 0.10000E+01 0.0000 136 SO3-2 0.58417E-09 -9.2335 0.72452E-11 -11.1400 0.12403E-01 -1.9065 137 HSO3- 0.45907E-03 -3.3381 0.12207E-03 -3.9134 0.26590E+00 -0.5753 138 HSO4- 0.12621E-01 -1.8989 0.38129E-02 -2.4187 0.30212E+00 -0.5198 140 S2O3-2 0.49205E-06 -6.3080 0.39932E-08 -8.3987 0.81154E-02 -2.0907 141 HS2O3- 0.78486E-06 -6.1052 0.20869E-06 -6.6805 0.26590E+00 -0.5753 142 H2S2O3,aq 0.24433E-07 -7.6120 0.24433E-07 -7.6120 0.10000E+01 0.0000 150 S4O6-2 0.70628E-09 -9.1510 0.57317E-11 -11.2417 0.81154E-02 -2.0907 152 ZnCl+ 0.71809E-03 -3.1438 0.21177E-03 -3.6741 0.29491E+00 -0.5303 153 ZnCl2,aq 0.13830E-02 -2.8592 0.13830E-02 -2.8592 0.10000E+01 0.0000 154 ZnCl3- 0.21503E-03 -3.6675 0.57176E-04 -4.2428 0.26590E+00 -0.5753 155 ZnO,aq 0.31926E-07 -7.4958 0.31926E-07 -7.4958 0.10000E+01 0.0000 156 ZnOH+ 0.32541E-05 -5.4876 0.95965E-06 -6.0179 0.29491E+00 -0.5303 158 HZnO2- 0.29363E-09 -9.5322 0.78077E-10 -10.1075 0.26590E+00 -0.5753 Charge balance for all species = 0.2553E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1454069E-04 0.4302348E+01 0.3529150E+04 0.0000 2 H2O 0.1000000E+01 0.5249304E+02 0.7696143E+06 0.0000 3 Cl- 0.2197621E+00 0.6571453E+00 0.1896026E+05 4.1485 4 SO4-- 0.1551737E-03 0.2539159E+00 0.1985041E+05 4.8951 5 HCO3- 0.3018077E-04 0.2679290E+01 0.1330460E+06 0.3172 6 HS- 0.1500909E-03 0.1170161E+01 0.3149460E+05 0.9864 7 H4SiO4 0.1067628E+00 0.1067664E+00 0.8351368E+04 -0.9716 8 Al+++ 0.6804419E-17 0.2253715E-04 0.4948744E+00 -5.7660 9 Ca++ 0.2359530E-05 0.3737041E-03 0.1218888E+02 2.9905 10 Mg++ 0.1189668E-05 0.2085708E-04 0.4126710E+00 2.6128 11 Fe++ 0.1934023E-07 0.8815871E-02 0.4006775E+03 0.8443 12 K+ 0.5774182E-01 0.1265045E+00 0.4025638E+04 3.6094 13 Na+ 0.2004980E+00 0.5590736E+00 0.1046006E+05 4.1141 14 Mn++ 0.4475537E-06 0.1159530E-02 0.5184238E+02 2.2236 15 Zn++ 0.4920703E-09 0.2319399E-02 0.1233911E+03 -0.7501 16 Cu+ 0.8258632E-07 0.2661906E-03 0.1376480E+02 -2.2722 17 Pb++ 0.5001108E-08 0.3431410E-03 0.5785905E+02 0.3629 18 Ag+ 0.4327953E-09 0.8776765E-05 0.7704865E+00 -4.5222 19 Ba++ 0.2928601E-06 0.5585563E-04 0.6243008E+01 2.1594 20 HPO4-- 0.1547805E-08 0.7240520E-05 0.5655563E+00 -0.1040 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265131E+01 -.2768682E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5203895E+02 -.7417165E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517194E+00 0.3393043E-05 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160039E+01 0.1051843E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1058429E+00 0.3775147E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2234219E-04 0.6721973E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3704714E-03 0.1574385E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8739609E-02 0.2714435E-04 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542374E+00 0.3619524E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.2638880E-03 0.1357217E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5537245E-04 0.0000000E+00 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.7177886E-05 0.1389614E-05 0.0000000E+00 Chg. balance for solid moles: -.5218E-18 Mass of aqueous solution: 0.121814E+04 g Temperature = 592.00 C Pressure = 1856.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) quartz 0.3636E-01 -1.439 2.184 0.339 93.50 0.8249 bornite 0.2714E-04 -4.566 0.1362E-01 -1.866 0.5831 0.2680E-02 an30ab70 0.5171E-03 -3.286 0.1381 -0.860 5.910 0.5185E-01 apatite-OH 0.4632E-06 -6.334 0.2327E-03 -3.633 0.9960E-02 0.7394E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.336152 g Volume = 0.879461 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 30 apatite-OH -49.94 -49.94 0.00 0.000 0.28129E-10 144 quartz -0.97 -0.97 0.00 0.000 0.00000E+00 197 bornite -50.48 -50.48 0.00 0.000 -0.28129E-10 260 an30ab70 -6.34 -6.34 0.00 0.000 0.10548E-10 237 barite -14.49 -14.47 0.01 0.007 -0.52739E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.293 0.11595E+04 2.976 2 CO2,gas -9.04 -10.44 -1.41 -0.470 0.55774E+04 1.860 3 CH4,gas 6.91 -3.59 -10.50 -2.626 0.41583E+05 -7.235 4 H2,gas 5.76 1.71 -4.04 -2.311 0.16009E+05 -0.775 5 H2S,gas -7.51 -9.78 -2.27 -1.133 0.89667E+04 1.004 6 CO,gas -3.13 -8.73 -5.60 -1.725 0.22189E+05 -2.336 7 SO3,gas -6.40 -16.63 -10.23 -2.556 0.40482E+05 -6.957 8 O2,gas 16.48 -3.43 -19.90 -13.270 0.78797E+05 -16.636 9 HCl,gas -5.60 -6.62 -1.01 -0.506 0.40041E+04 -1.011 10 acmite 3.91 2.16 -1.75 -0.182 0.69172E+04 12 akimotoite 5.82 1.64 -4.17 -0.835 0.16522E+05 13 akimotoite-Fe 3.80 -0.13 -3.93 -0.785 0.15543E+05 14 albite-high -4.42 -4.56 -0.14 -0.011 0.56479E+03 15 albite -4.38 -4.56 -0.18 -0.014 0.69654E+03 16 almandine -10.44 -11.91 -1.47 -0.073 0.58194E+04 17 pyrope -4.08 -6.61 -2.53 -0.126 0.10015E+05 18 analcite -2.64 -3.59 -0.95 -0.106 0.37660E+04 19 andalusite -12.36 -12.51 -0.14 -0.014 0.55869E+03 21 grossular -0.56 -5.48 -4.91 -0.246 0.19443E+05 22 anhydrite -13.48 -13.64 -0.16 -0.081 0.64185E+03 24 annite -0.74 -2.54 -1.79 -0.100 0.71058E+04 25 phlogopite 3.66 2.77 -0.89 -0.050 0.35418E+04 27 anorthite -10.01 -10.48 -0.47 -0.036 0.18708E+04 28 anthophyllite 13.48 10.53 -2.95 -0.080 0.11670E+05 29 anthophyllite-Fe 1.43 -1.85 -3.27 -0.088 0.12947E+05 31 apatite-OH-zs -47.86 -49.94 -2.09 -0.161 0.82673E+04 32 apatite-Cl-zs -53.54 -56.56 -3.02 -0.252 0.11949E+05 33 aragonite -4.01 -7.46 -3.45 -1.150 0.13660E+05 34 brucite 4.92 2.61 -2.31 -0.462 0.91366E+04 35 calcite -4.09 -7.46 -3.36 -1.120 0.13307E+05 36 carnegieite-low -0.85 -2.62 -1.77 -0.253 0.70057E+04 37 carnegieite-high -0.79 -2.62 -1.83 -0.262 0.72556E+04 38 carpholite-Mg -9.13 -10.87 -1.73 -0.115 0.68560E+04 39 carpholite-Fe -10.43 -12.64 -2.20 -0.147 0.87253E+04 40 celadonite -1.21 -3.42 -2.21 -0.130 0.87390E+04 41 celadonite-Fe -2.57 -5.19 -2.62 -0.154 0.10384E+05 42 chrysotile 8.62 5.89 -2.73 -0.227 0.10801E+05 44 clinochlore 0.31 -1.40 -1.70 -0.053 0.67362E+04 45 daphnite -6.45 -10.24 -3.79 -0.118 0.14985E+05 48 chloritoid-Mg -8.83 -9.90 -1.07 -0.071 0.42271E+04 49 chloritoid-Fe -10.67 -11.67 -0.99 -0.066 0.39313E+04 50 chloritoid-Mn -8.51 -10.29 -1.78 -0.119 0.70392E+04 52 coesite -0.69 -0.97 -0.27 -0.091 0.10812E+04 53 cordierite-H -22.32 -22.69 -0.38 -0.013 0.14867E+04 54 cordierite-Fe -24.66 -26.23 -1.57 -0.054 0.62074E+04 55 cordierite-Mn -20.25 -23.47 -3.22 -0.111 0.12743E+05 56 corundum -11.24 -11.54 -0.30 -0.027 0.11912E+04 58 cristobalite -0.91 -0.97 -0.06 -0.019 0.22087E+03 59 cummingtonite 13.54 10.53 -3.00 -0.081 0.11886E+05 61 cymrite-K -2.82 -5.06 -2.24 -0.187 0.88760E+04 63 diaspore -5.12 -5.77 -0.65 -0.109 0.25773E+04 65 diopside 5.20 3.66 -1.54 -0.154 0.60858E+04 66 hedenbergite 3.84 1.90 -1.95 -0.195 0.77083E+04 68 eastonite -9.17 -10.41 -1.25 -0.048 0.49450E+04 69 enstatite 4.34 3.29 -1.06 -0.106 0.41827E+04 70 clinoenstatite-HiP 4.82 3.29 -1.53 -0.153 0.60646E+04 71 clinoenstatite 4.33 3.29 -1.04 -0.104 0.41367E+04 72 protoenstatite 4.47 3.29 -1.19 -0.119 0.46989E+04 73 epidote -6.35 -8.48 -2.13 -0.103 0.84227E+04 74 clinozoisite -11.96 -14.23 -2.28 -0.104 0.90171E+04 75 epidote-Fe 0.91 -2.72 -3.63 -0.189 0.14386E+05 76 fayalite 1.81 0.72 -1.09 -0.156 0.43251E+04 77 ferrosilite 0.93 -0.25 -1.18 -0.118 0.46555E+04 78 forsterite 5.64 4.25 -1.38 -0.198 0.54739E+04 79 gedrite -13.91 -15.83 -1.91 -0.052 0.75809E+04 81 gibbsite -3.55 -5.77 -2.22 -0.318 0.87987E+04 82 glaucophane 0.20 -3.22 -3.42 -0.092 0.13524E+05 83 glaucophane-Fe -3.66 -8.53 -4.87 -0.132 0.19266E+05 84 goethite 0.89 -0.02 -0.90 -0.195 0.35765E+04 86 greenalite 3.99 0.59 -3.41 -0.284 0.13485E+05 87 grunerite 1.95 -1.85 -3.79 -0.103 0.15017E+05 88 halite -0.40 -2.50 -2.10 -1.049 0.83093E+04 89 hematite 0.29 -0.03 -0.31 -0.038 0.12460E+04 90 heulandite -12.71 -15.33 -2.63 -0.119 0.10400E+05 91 hercynite -9.87 -10.70 -0.83 -0.055 0.32676E+04 94 jadeite -1.97 -3.59 -1.62 -0.162 0.64198E+04 96 kalsilite -1.49 -3.13 -1.64 -0.234 0.64780E+04 97 kaolinite -11.09 -13.48 -2.39 -0.217 0.94488E+04 98 kyanite -12.22 -12.51 -0.28 -0.028 0.11177E+04 100 laumontite -9.20 -12.43 -3.23 -0.215 0.12780E+05 101 lawsonite -7.36 -10.49 -3.13 -0.209 0.12402E+05 102 leucite -3.10 -4.10 -0.99 -0.099 0.39373E+04 104 lizardite 8.82 5.89 -2.92 -0.244 0.11568E+05 105 magnesite -5.05 -7.83 -2.78 -0.926 0.11003E+05 106 magnetite 1.15 0.81 -0.34 -0.027 0.13286E+04 107 minnesotaite 0.83 -1.34 -2.17 -0.128 0.86088E+04 108 minnesotaite-Mg 6.55 3.96 -2.58 -0.152 0.10232E+05 109 magnesioferrite 4.10 2.58 -1.52 -0.124 0.60233E+04 111 manganosite 4.99 2.22 -2.77 -0.693 0.10974E+05 112 margarite -20.80 -22.03 -1.23 -0.049 0.48598E+04 115 microcline -4.98 -5.06 -0.09 -0.007 0.34511E+03 116 monticellite 8.29 4.63 -3.66 -0.523 0.14481E+05 118 mullite-Si -11.66 -12.51 -0.85 -0.085 0.33608E+04 119 muscovite -16.10 -16.60 -0.50 -0.029 0.19770E+04 120 paragonite -15.42 -16.10 -0.68 -0.040 0.26751E+04 121 nepheline -1.14 -2.62 -1.48 -0.212 0.58618E+04 122 osumilite(2) -14.47 -16.51 -2.04 -0.042 0.80603E+04 123 osumilite-Fe -31.26 -33.23 -1.97 -0.041 0.78040E+04 124 pargasite 1.57 -2.58 -4.15 -0.109 0.16428E+05 125 periclase 5.11 2.61 -2.50 -0.624 0.98798E+04 126 periclase-Fe 2.62 0.84 -1.78 -0.445 0.70458E+04 127 perovskite-Al -9.56 -11.54 -1.98 -0.180 0.78427E+04 132 phlogopite-Na 4.53 3.27 -1.26 -0.070 0.49703E+04 134 prehnite -5.36 -8.47 -3.11 -0.183 0.12298E+05 135 prehnite-Fe 0.64 -2.71 -3.35 -0.202 0.13272E+05 138 px-Mg-tschermaks -8.28 -9.90 -1.62 -0.116 0.64080E+04 139 px-Ca-tschermaks -7.23 -9.52 -2.28 -0.163 0.90416E+04 140 pyrite -20.27 -20.42 -0.16 -0.037 0.61554E+03 141 pyrrhotite -8.21 -8.93 -0.72 -0.242 0.28700E+04 142 pyrrhotiteFe0.875 -8.91 -9.25 -0.34 -0.127 0.13644E+04 143 pyrophyllite -14.42 -15.41 -0.99 -0.062 0.39280E+04 146 riebeckite 6.46 2.98 -3.48 -0.096 0.13757E+05 147 ringwoodite-Fe 2.78 0.72 -2.07 -0.295 0.81774E+04 148 ringwoodite-Mg 8.70 4.25 -4.45 -0.635 0.17603E+05 149 rhodochrosite -4.90 -8.22 -3.32 -1.108 0.13162E+05 150 rhodonite 2.44 1.25 -1.19 -0.238 0.47048E+04 151 sanidine -4.45 -5.06 -0.61 -0.047 0.24112E+04 152 sapphirine(351) -46.70 -50.83 -4.13 -0.063 0.16342E+05 153 siderite -6.80 -9.60 -2.80 -0.933 0.11082E+05 154 sillimanite -12.34 -12.51 -0.17 -0.017 0.65826E+03 156 spinel -7.78 -8.93 -1.15 -0.076 0.45377E+04 158 staurolite-Fe -104.08 -107.74 -3.66 -0.033 0.14482E+05 159 staurolite-Mg -95.98 -100.66 -4.68 -0.043 0.18535E+05 162 stilpnomelane-Fe -8.49 -13.28 -4.79 -0.143 0.18944E+05 163 stilpnomelane-Mg -2.11 -4.43 -2.33 -0.069 0.92134E+04 164 stishovite 1.89 -0.97 -2.86 -0.953 0.11313E+05 165 sudoite-Fe -20.85 -24.30 -3.45 -0.111 0.13663E+05 166 sudoite -18.74 -20.77 -2.03 -0.065 0.80224E+04 167 sulfur -10.01 -11.49 -1.48 -0.456 0.58634E+04 168 sylvite -0.32 -3.01 -2.69 -1.345 0.10652E+05 169 talc 4.85 3.96 -0.89 -0.052 0.35177E+04 170 talc-Fe 2.17 -1.34 -3.52 -0.207 0.13916E+05 171 talc-tschermaks -7.70 -9.22 -1.53 -0.090 0.60403E+04 173 tephroite 6.13 3.48 -2.66 -0.380 0.10517E+05 176 topaz-H -10.33 -12.51 -2.18 -0.198 0.86277E+04 177 tremolite 14.63 11.29 -3.34 -0.090 0.13228E+05 179 troilite-low -8.11 -8.93 -0.82 -0.274 0.32598E+04 180 tschermakite -11.99 -15.07 -3.08 -0.083 0.12210E+05 183 wadsleyite-Fe 2.63 0.72 -1.91 -0.273 0.75684E+04 184 wadsleyite-Mg 7.78 4.25 -3.53 -0.504 0.13955E+05 185 wairakite -10.93 -12.42 -1.49 -0.088 0.58988E+04 186 walstromite 4.57 2.02 -2.55 -0.510 0.10096E+05 187 wollastonite 4.17 2.02 -2.15 -0.431 0.85241E+04 188 pseudo-wollastonite 4.28 2.02 -2.26 -0.452 0.89486E+04 189 zoisite -12.02 -14.23 -2.21 -0.101 0.87671E+04 192 beidellite-Ca -15.22 -16.50 -1.29 -0.080 0.50915E+04 193 beidellite-H -15.21 -16.99 -1.78 -0.114 0.70569E+04 194 beidellite-K -14.15 -15.80 -1.66 -0.101 0.65519E+04 195 beidellite-Mg -15.53 -16.56 -1.03 -0.064 0.40927E+04 196 beidellite-Na -14.09 -15.64 -1.55 -0.095 0.61438E+04 199 chalcocite -13.05 -14.32 -1.28 -0.319 0.50541E+04 200 covellite -11.60 -12.91 -1.30 -0.496 0.51583E+04 202 montmorillonite-Ca -11.12 -12.15 -1.03 -0.064 0.40724E+04 203 montmorillonite-K -10.35 -11.45 -1.10 -0.068 0.43683E+04 204 montmorillonite-Mg -11.37 -12.21 -0.85 -0.052 0.33486E+04 205 montmorillonite-Na -9.98 -11.29 -1.31 -0.080 0.51738E+04 206 nontronite-Ca -3.47 -4.99 -1.53 -0.099 0.60425E+04 207 nontronite-H -3.47 -5.49 -2.01 -0.135 0.79763E+04 208 nontronite-K -2.40 -4.29 -1.89 -0.122 0.74948E+04 209 nontronite-Mg -3.72 -5.05 -1.33 -0.086 0.52718E+04 210 nontronite-Na -2.33 -4.13 -1.79 -0.115 0.70999E+04 215 gypsum -11.37 -13.65 -2.28 -0.570 0.90206E+04 232 alabandite -5.93 -7.55 -1.62 -0.541 0.64280E+04 234 anglesite -13.60 -16.27 -2.67 -1.333 0.10553E+05 238 boehmite -4.84 -5.77 -0.93 -0.154 0.36649E+04 240 chalcopyrite -21.82 -21.84 -0.02 -0.004 0.91834E+02 242 copper,native 1.80 -1.42 -3.21 -1.118 0.12724E+05 244 ferrous-oxide 1.72 0.84 -0.87 -0.218 0.34576E+04 245 galena -8.98 -9.41 -0.44 -0.146 0.17327E+04 246 silver,native 0.58 -3.67 -4.24 -1.475 0.16792E+05 248 litharge 5.18 0.36 -4.82 -1.206 0.19089E+05 255 sphalerite -10.35 -10.53 -0.17 -0.058 0.68648E+03 256 wurtzite -9.57 -10.53 -0.95 -0.318 0.37750E+04 257 zincite 1.86 -0.75 -2.62 -0.654 0.10352E+05 258 an20ab80 -5.73 -5.74 -0.02 -0.001 0.71493E+02 259 an25ab75 -6.03 -6.04 -0.01 0.000 0.22285E+02 261 tr.625ac.25prg.125 8.90 7.35 -1.55 -0.042 0.61529E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 16 Loop limit = 500 Temperature = 592.00 C Pressure = 1856.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5503E+02 kg liquid = 0.9913E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9950 Stoichiometric ionic strength = .3310150E+01 Osmotic coef. = 0.0000 True ionic strength = .2606657E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14541E-04 -4.8374 0.41511E-05 -5.3818 0.28547E+00 -0.5444 2 H2O 0.99503E+00 -0.0022 0.99503E+00 -0.0022 3 Cl- 0.21976E+00 -0.6580 0.58434E-01 -1.2333 0.26590E+00 -0.5753 4 SO4-- 0.15515E-03 -3.8092 0.13532E-05 -5.8687 0.87214E-02 -2.0594 5 HCO3- 0.30179E-04 -4.5203 0.86153E-05 -5.0647 0.28547E+00 -0.5444 6 HS- 0.15008E-03 -3.8237 0.40225E-04 -4.3955 0.26802E+00 -0.5718 7 H4SiO4 0.10676E+00 -0.9716 0.10676E+00 -0.9716 0.10000E+01 0.0000 8 Al+++ 0.68057E-17 -17.1671 0.12260E-21 -21.9115 0.18014E-04 -4.7444 9 Ca++ 0.23595E-05 -5.6272 0.16857E-07 -7.7732 0.71445E-02 -2.1460 10 Mg++ 0.11897E-05 -5.9246 0.70652E-08 -8.1509 0.59389E-02 -2.2263 11 Fe++ 0.19340E-07 -7.7135 0.12040E-09 -9.9194 0.62253E-02 -2.2058 12 K+ 0.57742E-01 -1.2385 0.16889E-01 -1.7724 0.29248E+00 -0.5339 13 Na+ 0.20050E+00 -0.6979 0.53985E-01 -1.2677 0.26926E+00 -0.5698 14 Mn++ 0.44755E-06 -6.3492 0.28834E-08 -8.5401 0.64426E-02 -2.1909 15 Zn++ 0.49206E-09 -9.3080 0.30632E-11 -11.5138 0.62253E-02 -2.2058 16 Cu+ 0.82592E-07 -7.0831 0.22182E-07 -7.6540 0.26857E+00 -0.5709 17 Pb++ 0.50012E-08 -8.3009 0.39734E-10 -10.4008 0.79450E-02 -2.0999 18 Ag+ 0.43279E-09 -9.3637 0.12472E-09 -9.9041 0.28817E+00 -0.5404 19 Ba++ 0.28404E-06 -6.5466 0.24124E-08 -8.6175 0.84933E-02 -2.0709 20 HPO4-- 0.15479E-08 -8.8103 0.13563E-10 -10.8676 0.87622E-02 -2.0574 21 HSiO3- 0.23140E-05 -5.6356 0.61529E-06 -6.2109 0.26590E+00 -0.5753 22 Ca(HSiO3)+ 0.13502E-07 -7.8696 0.39818E-08 -8.3999 0.29491E+00 -0.5303 23 Mg(HSiO3)+ 0.14257E-08 -8.8460 0.42045E-09 -9.3763 0.29491E+00 -0.5303 24 NaHSiO3,aq 0.13404E-05 -5.8728 0.13404E-05 -5.8728 0.10000E+01 0.0000 28 AgCl,aq 0.70068E-07 -7.1545 0.70068E-07 -7.1545 0.10000E+01 0.0000 29 AgCl2- 0.49968E-05 -5.3013 0.13286E-05 -5.8766 0.26590E+00 -0.5753 30 AgCl3-2 0.25323E-05 -5.5965 0.20551E-07 -7.6872 0.81155E-02 -2.0907 31 AgCl4-3 0.11732E-05 -5.9306 0.18287E-10 -10.7379 0.15586E-04 -4.8073 34 Ag(HS),aq 0.55211E-09 -9.2580 0.55211E-09 -9.2580 0.10000E+01 0.0000 35 Ag(HS)2- 0.33684E-08 -8.4726 0.89565E-09 -9.0479 0.26590E+00 -0.5753 36 AlO+ 0.13547E-10 -10.8682 0.39952E-11 -11.3985 0.29491E+00 -0.5303 38 HAlO2,aq 0.49829E-08 -8.3025 0.49829E-08 -8.3025 0.10000E+01 0.0000 39 AlO2- 0.22532E-04 -4.6472 0.52689E-05 -5.2783 0.23384E+00 -0.6311 41 Ba(HCO3)+ 0.14989E-05 -5.8242 0.45880E-06 -6.3384 0.30609E+00 -0.5141 42 BaCl+ 0.52391E-04 -4.2807 0.15451E-04 -4.8111 0.29491E+00 -0.5303 43 CH4,aq 0.20668E-08 -8.6847 0.25170E-08 -8.5991 0.12179E+01 0.0856 48 CO,aq 0.86673E-03 -3.0621 0.86673E-03 -3.0621 0.10000E+01 0.0000 49 CO2,aq 0.26784E+01 0.4279 0.32619E+01 0.5135 0.12179E+01 0.0856 50 CO3-2 0.53567E-10 -10.2711 0.43472E-12 -12.3618 0.81155E-02 -2.0907 51 CaCO3,aq 0.15697E-10 -10.8042 0.15697E-10 -10.8042 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.70570E-06 -6.1514 0.20812E-06 -6.6817 0.29491E+00 -0.5303 53 CaCl+ 0.24295E-03 -3.6145 0.71647E-04 -4.1448 0.29491E+00 -0.5303 54 CaCl2,aq 0.12723E-03 -3.8954 0.12723E-03 -3.8954 0.10000E+01 0.0000 55 CaOH+ 0.35286E-06 -6.4524 0.10406E-06 -6.9827 0.29491E+00 -0.5303 56 CaSO4,aq 0.97430E-07 -7.0113 0.97430E-07 -7.0113 0.10000E+01 0.0000 57 HCl,aq 0.10891E-02 -2.9629 0.10891E-02 -2.9629 0.10000E+01 0.0000 66 CuCl,aq 0.52399E-04 -4.2807 0.52399E-04 -4.2807 0.10000E+01 0.0000 67 CuCl2- 0.20824E-03 -3.6814 0.55370E-04 -4.2567 0.26590E+00 -0.5753 68 CuCl3-2 0.54930E-05 -5.2602 0.44578E-07 -7.3509 0.81155E-02 -2.0907 74 FeCl+ 0.62217E-06 -6.2061 0.18348E-06 -6.7364 0.29491E+00 -0.5303 75 FeCl2,aq 0.88151E-02 -2.0548 0.88151E-02 -2.0548 0.10000E+01 0.0000 77 FeO,aq 0.69474E-07 -7.1582 0.69474E-07 -7.1582 0.10000E+01 0.0000 78 FeOH+ 0.44428E-07 -7.3523 0.13102E-07 -7.8827 0.29491E+00 -0.5303 79 HFeO2- 0.10119E-07 -7.9948 0.26907E-08 -8.5701 0.26590E+00 -0.5753 82 FeO2- 0.60218E-08 -8.2203 0.16012E-08 -8.7956 0.26590E+00 -0.5753 83 HFeO2,aq 0.19025E-09 -9.7207 0.19025E-09 -9.7207 0.10000E+01 0.0000 84 H2,aq 0.44641E-02 -2.3503 0.54367E-02 -2.2647 0.12179E+01 0.0856 85 KCl,aq 0.53064E-01 -1.2752 0.53064E-01 -1.2752 0.10000E+01 0.0000 86 KHSO4,aq 0.12381E-01 -1.9072 0.12381E-01 -1.9072 0.10000E+01 0.0000 87 KOH,aq 0.86219E-06 -6.0644 0.86219E-06 -6.0644 0.10000E+01 0.0000 88 KSO4- 0.33169E-02 -2.4793 0.88195E-03 -3.0546 0.26590E+00 -0.5753 90 Mg(HCO3)+ 0.12738E-06 -6.8949 0.37565E-07 -7.4252 0.29491E+00 -0.5303 91 MgCl+ 0.18935E-04 -4.7227 0.55842E-05 -5.2530 0.29491E+00 -0.5303 92 MgOH+ 0.60334E-06 -6.2194 0.17793E-06 -6.7498 0.29491E+00 -0.5303 94 MnO,aq 0.24678E-07 -7.6077 0.24678E-07 -7.6077 0.10000E+01 0.0000 95 MnOH+ 0.13400E-06 -6.8729 0.39517E-07 -7.4032 0.29491E+00 -0.5303 97 HMnO2- 0.17129E-10 -10.7663 0.45546E-11 -11.3416 0.26590E+00 -0.5753 100 MnCl+ 0.11589E-02 -2.9360 0.34177E-03 -3.4663 0.29491E+00 -0.5303 101 MnSO4,aq 0.21335E-07 -7.6709 0.21335E-07 -7.6709 0.10000E+01 0.0000 102 NaCl,aq 0.35857E+00 -0.4454 0.35857E+00 -0.4454 0.10000E+01 0.0000 103 NaOH,aq 0.12673E-05 -5.8971 0.12673E-05 -5.8971 0.10000E+01 0.0000 105 OH- 0.96071E-05 -5.0174 0.22465E-05 -5.6485 0.23384E+00 -0.6311 110 HPO3-2 0.28320E-10 -10.5479 0.22983E-12 -12.6386 0.81155E-02 -2.0907 111 H3PO3,aq 0.22500E-09 -9.6478 0.22500E-09 -9.6478 0.10000E+01 0.0000 112 H2PO3- 0.10308E-07 -7.9868 0.27409E-08 -8.5621 0.26590E+00 -0.5753 113 H3PO4,aq 0.14688E-05 -5.8330 0.14688E-05 -5.8330 0.10000E+01 0.0000 114 H2PO4- 0.34265E-05 -5.4651 0.95582E-06 -6.0196 0.27895E+00 -0.5545 116 H4P2O7,aq 0.17578E-09 -9.7550 0.17578E-09 -9.7550 0.10000E+01 0.0000 117 H3P2O7- 0.42055E-08 -8.3762 0.11182E-08 -8.9515 0.26590E+00 -0.5753 118 H2P2O7-2 0.11331E-05 -5.9457 0.91959E-08 -8.0364 0.81155E-02 -2.0907 119 HP2O7-3 0.29639E-07 -7.5281 0.46197E-12 -12.3354 0.15586E-04 -4.8073 121 PbCl+ 0.30167E-05 -5.5205 0.88965E-06 -6.0508 0.29491E+00 -0.5303 122 PbCl2,aq 0.95039E-04 -4.0221 0.95039E-04 -4.0221 0.10000E+01 0.0000 123 PbCl3- 0.11587E-03 -3.9360 0.30811E-04 -4.5113 0.26590E+00 -0.5753 124 PbCl4-2 0.30135E-04 -4.5209 0.24456E-06 -6.6116 0.81155E-02 -2.0907 125 PbO,aq 0.32180E-08 -8.4924 0.32180E-08 -8.4924 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.91544E-04 -4.0384 0.91544E-04 -4.0384 0.10000E+01 0.0000 128 Pb(HS)3- 0.75229E-05 -5.1236 0.20003E-05 -5.6989 0.26590E+00 -0.5753 129 H2S,aq 0.10427E+01 0.0182 0.12699E+01 0.1038 0.12179E+01 0.0856 130 S2-2 0.14436E-07 -7.8406 0.11716E-09 -9.9312 0.81155E-02 -2.0907 131 S3-2 0.15688E-08 -8.8044 0.12731E-10 -10.8951 0.81155E-02 -2.0907 132 S3- 0.23139E-01 -1.6356 0.61527E-02 -2.2109 0.26590E+00 -0.5753 133 S4-2 0.14134E-09 -9.8497 0.11470E-11 -11.9404 0.81155E-02 -2.0907 134 S5-2 0.10709E-10 -10.9702 0.86911E-13 -13.0609 0.81155E-02 -2.0907 135 SO2,aq 0.28262E+00 -0.5488 0.28262E+00 -0.5488 0.10000E+01 0.0000 136 SO3-2 0.58410E-09 -9.2335 0.72444E-11 -11.1400 0.12403E-01 -1.9065 137 HSO3- 0.45904E-03 -3.3381 0.12206E-03 -3.9134 0.26590E+00 -0.5753 138 HSO4- 0.12620E-01 -1.8989 0.38127E-02 -2.4188 0.30212E+00 -0.5198 140 S2O3-2 0.49199E-06 -6.3080 0.39927E-08 -8.3987 0.81155E-02 -2.0907 141 HS2O3- 0.78482E-06 -6.1052 0.20868E-06 -6.6805 0.26590E+00 -0.5753 142 H2S2O3,aq 0.24433E-07 -7.6120 0.24433E-07 -7.6120 0.10000E+01 0.0000 150 S4O6-2 0.70620E-09 -9.1511 0.57311E-11 -11.2418 0.81155E-02 -2.0907 152 ZnCl+ 0.71808E-03 -3.1438 0.21177E-03 -3.6741 0.29491E+00 -0.5303 153 ZnCl2,aq 0.13830E-02 -2.8592 0.13830E-02 -2.8592 0.10000E+01 0.0000 154 ZnCl3- 0.21503E-03 -3.6675 0.57177E-04 -4.2428 0.26590E+00 -0.5753 155 ZnO,aq 0.31923E-07 -7.4959 0.31923E-07 -7.4959 0.10000E+01 0.0000 156 ZnOH+ 0.32539E-05 -5.4876 0.95960E-06 -6.0179 0.29491E+00 -0.5303 158 HZnO2- 0.29358E-09 -9.5323 0.78063E-10 -10.1076 0.26590E+00 -0.5753 Charge balance for all species = 0.2553E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1454145E-04 0.4302348E+01 0.3529151E+04 0.0000 2 H2O 0.1000000E+01 0.5249304E+02 0.7696145E+06 0.0000 3 Cl- 0.2197621E+00 0.6571453E+00 0.1896027E+05 4.1485 4 SO4-- 0.1551548E-03 0.2539142E+00 0.1985029E+05 4.8950 5 HCO3- 0.3017899E-04 0.2679290E+01 0.1330461E+06 0.3171 6 HS- 0.1500824E-03 0.1170161E+01 0.3149461E+05 0.9863 7 H4SiO4 0.1067628E+00 0.1067664E+00 0.8351370E+04 -0.9716 8 Al+++ 0.6805712E-17 0.2253705E-04 0.4948723E+00 -5.7660 9 Ca++ 0.2359502E-05 0.3737062E-03 0.1218895E+02 2.9905 10 Mg++ 0.1189652E-05 0.2085708E-04 0.4126712E+00 2.6128 11 Fe++ 0.1933981E-07 0.8815875E-02 0.4006778E+03 0.8443 12 K+ 0.5774211E-01 0.1265045E+00 0.4025639E+04 3.6094 13 Na+ 0.2004971E+00 0.5590737E+00 0.1046006E+05 4.1141 14 Mn++ 0.4475465E-06 0.1159531E-02 0.5184239E+02 2.2236 15 Zn++ 0.4920601E-09 0.2319399E-02 0.1233911E+03 -0.7502 16 Cu+ 0.8259245E-07 0.2662122E-03 0.1376592E+02 -2.2722 17 Pb++ 0.5001176E-08 0.3431410E-03 0.5785906E+02 0.3628 18 Ag+ 0.4327948E-09 0.8776765E-05 0.7704868E+00 -4.5222 19 Ba++ 0.2840397E-06 0.5417405E-04 0.6055059E+01 2.1461 20 HPO4-- 0.1547892E-08 0.7241754E-05 0.5656529E+00 -0.1040 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265131E+01 -.2768669E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5203895E+02 -.7417165E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517177E+00 0.5059543E-05 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160039E+01 0.1051678E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1058429E+00 0.3775147E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2234209E-04 0.6721974E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3704734E-03 0.1574365E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8739614E-02 0.2714008E-04 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542374E+00 0.3619525E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.2639093E-03 0.1357004E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.5370542E-04 0.1667034E-05 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.7179109E-05 0.1388391E-05 0.0000000E+00 Chg. balance for solid moles: 0.2058E-18 Mass of aqueous solution: 0.121814E+04 g Temperature = 592.00 C Pressure = 1856.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4628E-06 -6.335 0.2325E-03 -3.634 0.9949E-02 0.7387E-04 quartz 0.3636E-01 -1.439 2.184 0.339 93.48 0.8249 bornite 0.2714E-04 -4.566 0.1362E-01 -1.866 0.5829 0.2679E-02 an30ab70 0.5171E-03 -3.286 0.1381 -0.860 5.909 0.5185E-01 barite 0.1667E-05 -5.778 0.3891E-03 -3.410 0.1665E-01 0.8685E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.336539 g Volume = 0.879547 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 30 apatite-OH -49.94 -49.94 0.00 0.000 0.00000E+00 144 quartz -0.97 -0.97 0.00 0.000 0.00000E+00 197 bornite -50.48 -50.48 0.00 0.000 -0.28129E-10 237 barite -14.49 -14.49 0.00 0.000 -0.70322E-11 260 an30ab70 -6.34 -6.34 0.00 0.000 -0.17581E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.293 0.11595E+04 2.976 2 CO2,gas -9.04 -10.44 -1.41 -0.470 0.55774E+04 1.860 3 CH4,gas 6.91 -3.59 -10.50 -2.626 0.41583E+05 -7.235 4 H2,gas 5.76 1.71 -4.04 -2.311 0.16009E+05 -0.775 5 H2S,gas -7.51 -9.78 -2.27 -1.133 0.89667E+04 1.004 6 CO,gas -3.13 -8.73 -5.60 -1.725 0.22189E+05 -2.336 7 SO3,gas -6.40 -16.63 -10.23 -2.556 0.40482E+05 -6.957 8 O2,gas 16.48 -3.43 -19.90 -13.270 0.78797E+05 -16.636 9 HCl,gas -5.60 -6.62 -1.01 -0.506 0.40040E+04 -1.011 10 acmite 3.91 2.16 -1.75 -0.182 0.69175E+04 12 akimotoite 5.82 1.64 -4.17 -0.835 0.16522E+05 13 akimotoite-Fe 3.80 -0.13 -3.93 -0.785 0.15543E+05 14 albite-high -4.42 -4.56 -0.14 -0.011 0.56479E+03 15 albite -4.38 -4.56 -0.18 -0.014 0.69654E+03 16 almandine -10.44 -11.91 -1.47 -0.074 0.58198E+04 17 pyrope -4.08 -6.61 -2.53 -0.126 0.10015E+05 18 analcite -2.64 -3.59 -0.95 -0.106 0.37660E+04 19 andalusite -12.36 -12.51 -0.14 -0.014 0.55849E+03 21 grossular -0.56 -5.48 -4.91 -0.246 0.19443E+05 22 anhydrite -13.48 -13.64 -0.16 -0.081 0.64203E+03 24 annite -0.74 -2.54 -1.80 -0.100 0.71064E+04 25 phlogopite 3.66 2.77 -0.89 -0.050 0.35424E+04 27 anorthite -10.01 -10.48 -0.47 -0.036 0.18708E+04 28 anthophyllite 13.48 10.53 -2.95 -0.080 0.11671E+05 29 anthophyllite-Fe 1.43 -1.85 -3.27 -0.088 0.12949E+05 31 apatite-OH-zs -47.86 -49.94 -2.09 -0.161 0.82673E+04 32 apatite-Cl-zs -53.54 -56.56 -3.02 -0.252 0.11949E+05 33 aragonite -4.01 -7.46 -3.45 -1.150 0.13660E+05 34 brucite 4.92 2.61 -2.31 -0.462 0.91368E+04 35 calcite -4.09 -7.46 -3.36 -1.120 0.13307E+05 36 carnegieite-low -0.85 -2.62 -1.77 -0.253 0.70057E+04 37 carnegieite-high -0.79 -2.62 -1.83 -0.262 0.72556E+04 38 carpholite-Mg -9.13 -10.87 -1.73 -0.115 0.68560E+04 39 carpholite-Fe -10.43 -12.64 -2.20 -0.147 0.87253E+04 40 celadonite -1.21 -3.42 -2.21 -0.130 0.87392E+04 41 celadonite-Fe -2.57 -5.19 -2.62 -0.154 0.10384E+05 42 chrysotile 8.62 5.89 -2.73 -0.227 0.10801E+05 44 clinochlore 0.31 -1.40 -1.70 -0.053 0.67369E+04 45 daphnite -6.45 -10.24 -3.79 -0.118 0.14986E+05 48 chloritoid-Mg -8.83 -9.90 -1.07 -0.071 0.42271E+04 49 chloritoid-Fe -10.67 -11.67 -0.99 -0.066 0.39313E+04 50 chloritoid-Mn -8.51 -10.29 -1.78 -0.119 0.70392E+04 52 coesite -0.69 -0.97 -0.27 -0.091 0.10812E+04 53 cordierite-H -22.32 -22.69 -0.38 -0.013 0.14866E+04 54 cordierite-Fe -24.66 -26.23 -1.57 -0.054 0.62074E+04 55 cordierite-Mn -20.25 -23.47 -3.22 -0.111 0.12743E+05 56 corundum -11.24 -11.54 -0.30 -0.027 0.11910E+04 58 cristobalite -0.91 -0.97 -0.06 -0.019 0.22087E+03 59 cummingtonite 13.54 10.53 -3.00 -0.081 0.11887E+05 61 cymrite-K -2.82 -5.06 -2.24 -0.187 0.88760E+04 63 diaspore -5.12 -5.77 -0.65 -0.109 0.25772E+04 65 diopside 5.20 3.66 -1.54 -0.154 0.60862E+04 66 hedenbergite 3.84 1.90 -1.95 -0.195 0.77087E+04 68 eastonite -9.17 -10.41 -1.25 -0.048 0.49452E+04 69 enstatite 4.34 3.29 -1.06 -0.106 0.41831E+04 70 clinoenstatite-HiP 4.82 3.29 -1.53 -0.153 0.60649E+04 71 clinoenstatite 4.33 3.29 -1.05 -0.105 0.41371E+04 72 protoenstatite 4.47 3.29 -1.19 -0.119 0.46992E+04 73 epidote -6.35 -8.48 -2.13 -0.103 0.84231E+04 74 clinozoisite -11.96 -14.23 -2.28 -0.104 0.90171E+04 75 epidote-Fe 0.91 -2.73 -3.63 -0.189 0.14387E+05 76 fayalite 1.81 0.72 -1.09 -0.156 0.43255E+04 77 ferrosilite 0.93 -0.25 -1.18 -0.118 0.46559E+04 78 forsterite 5.64 4.25 -1.38 -0.198 0.54743E+04 79 gedrite -13.91 -15.83 -1.92 -0.052 0.75815E+04 81 gibbsite -3.55 -5.77 -2.22 -0.318 0.87986E+04 82 glaucophane 0.20 -3.22 -3.42 -0.092 0.13524E+05 83 glaucophane-Fe -3.66 -8.53 -4.87 -0.132 0.19267E+05 84 goethite 0.89 -0.02 -0.90 -0.195 0.35767E+04 86 greenalite 3.99 0.59 -3.41 -0.284 0.13486E+05 87 grunerite 1.95 -1.85 -3.79 -0.103 0.15019E+05 88 halite -0.40 -2.50 -2.10 -1.049 0.83093E+04 89 hematite 0.29 -0.03 -0.31 -0.038 0.12464E+04 90 heulandite -12.71 -15.33 -2.63 -0.119 0.10400E+05 91 hercynite -9.87 -10.70 -0.83 -0.055 0.32676E+04 94 jadeite -1.97 -3.59 -1.62 -0.162 0.64198E+04 96 kalsilite -1.49 -3.13 -1.64 -0.234 0.64780E+04 97 kaolinite -11.09 -13.48 -2.39 -0.217 0.94487E+04 98 kyanite -12.22 -12.51 -0.28 -0.028 0.11175E+04 100 laumontite -9.20 -12.43 -3.23 -0.215 0.12780E+05 101 lawsonite -7.36 -10.49 -3.13 -0.209 0.12402E+05 102 leucite -3.10 -4.10 -0.99 -0.099 0.39372E+04 104 lizardite 8.82 5.89 -2.92 -0.244 0.11569E+05 105 magnesite -5.05 -7.83 -2.78 -0.926 0.11003E+05 106 magnetite 1.15 0.81 -0.34 -0.027 0.13292E+04 107 minnesotaite 0.83 -1.34 -2.17 -0.128 0.86094E+04 108 minnesotaite-Mg 6.55 3.96 -2.58 -0.152 0.10233E+05 109 magnesioferrite 4.10 2.58 -1.52 -0.124 0.60239E+04 111 manganosite 4.99 2.22 -2.77 -0.693 0.10975E+05 112 margarite -20.80 -22.03 -1.23 -0.049 0.48596E+04 115 microcline -4.98 -5.06 -0.09 -0.007 0.34509E+03 116 monticellite 8.29 4.63 -3.66 -0.523 0.14481E+05 118 mullite-Si -11.66 -12.51 -0.85 -0.085 0.33606E+04 119 muscovite -16.10 -16.60 -0.50 -0.029 0.19768E+04 120 paragonite -15.42 -16.10 -0.68 -0.040 0.26750E+04 121 nepheline -1.14 -2.62 -1.48 -0.212 0.58618E+04 122 osumilite(2) -14.47 -16.51 -2.04 -0.042 0.80607E+04 123 osumilite-Fe -31.26 -33.23 -1.97 -0.041 0.78040E+04 124 pargasite 1.57 -2.58 -4.15 -0.109 0.16429E+05 125 periclase 5.11 2.61 -2.50 -0.624 0.98800E+04 126 periclase-Fe 2.62 0.84 -1.78 -0.445 0.70460E+04 127 perovskite-Al -9.56 -11.54 -1.98 -0.180 0.78425E+04 132 phlogopite-Na 4.53 3.27 -1.26 -0.070 0.49709E+04 134 prehnite -5.36 -8.47 -3.11 -0.183 0.12298E+05 135 prehnite-Fe 0.64 -2.71 -3.35 -0.202 0.13272E+05 138 px-Mg-tschermaks -8.28 -9.90 -1.62 -0.116 0.64080E+04 139 px-Ca-tschermaks -7.23 -9.52 -2.28 -0.163 0.90416E+04 140 pyrite -20.27 -20.42 -0.16 -0.037 0.61573E+03 141 pyrrhotite -8.21 -8.93 -0.73 -0.242 0.28702E+04 142 pyrrhotiteFe0.875 -8.91 -9.25 -0.34 -0.127 0.13645E+04 143 pyrophyllite -14.42 -15.41 -0.99 -0.062 0.39278E+04 146 riebeckite 6.46 2.98 -3.48 -0.096 0.13758E+05 147 ringwoodite-Fe 2.78 0.72 -2.07 -0.295 0.81778E+04 148 ringwoodite-Mg 8.70 4.25 -4.45 -0.635 0.17604E+05 149 rhodochrosite -4.90 -8.22 -3.32 -1.108 0.13162E+05 150 rhodonite 2.44 1.25 -1.19 -0.238 0.47050E+04 151 sanidine -4.45 -5.06 -0.61 -0.047 0.24111E+04 152 sapphirine(351) -46.70 -50.83 -4.13 -0.063 0.16342E+05 153 siderite -6.80 -9.60 -2.80 -0.933 0.11083E+05 154 sillimanite -12.34 -12.51 -0.17 -0.017 0.65807E+03 156 spinel -7.78 -8.93 -1.15 -0.076 0.45377E+04 158 staurolite-Fe -104.08 -107.74 -3.66 -0.033 0.14481E+05 159 staurolite-Mg -95.98 -100.66 -4.68 -0.043 0.18534E+05 162 stilpnomelane-Fe -8.49 -13.28 -4.79 -0.143 0.18944E+05 163 stilpnomelane-Mg -2.11 -4.43 -2.33 -0.069 0.92142E+04 164 stishovite 1.89 -0.97 -2.86 -0.953 0.11313E+05 165 sudoite-Fe -20.85 -24.30 -3.45 -0.111 0.13663E+05 166 sudoite -18.74 -20.77 -2.03 -0.065 0.80224E+04 167 sulfur -10.01 -11.49 -1.48 -0.456 0.58634E+04 168 sylvite -0.32 -3.01 -2.69 -1.345 0.10652E+05 169 talc 4.85 3.96 -0.89 -0.052 0.35183E+04 170 talc-Fe 2.17 -1.34 -3.52 -0.207 0.13917E+05 171 talc-tschermaks -7.70 -9.22 -1.53 -0.090 0.60405E+04 173 tephroite 6.13 3.48 -2.66 -0.380 0.10517E+05 176 topaz-H -10.33 -12.51 -2.18 -0.198 0.86275E+04 177 tremolite 14.63 11.29 -3.34 -0.090 0.13229E+05 179 troilite-low -8.11 -8.93 -0.82 -0.274 0.32600E+04 180 tschermakite -11.99 -15.07 -3.08 -0.083 0.12210E+05 183 wadsleyite-Fe 2.63 0.72 -1.91 -0.273 0.75688E+04 184 wadsleyite-Mg 7.78 4.25 -3.53 -0.504 0.13955E+05 185 wairakite -10.93 -12.42 -1.49 -0.088 0.58988E+04 186 walstromite 4.57 2.02 -2.55 -0.510 0.10097E+05 187 wollastonite 4.17 2.02 -2.15 -0.431 0.85243E+04 188 pseudo-wollastonite 4.28 2.02 -2.26 -0.452 0.89487E+04 189 zoisite -12.02 -14.23 -2.21 -0.101 0.87672E+04 192 beidellite-Ca -15.22 -16.50 -1.29 -0.080 0.50913E+04 193 beidellite-H -15.21 -16.99 -1.78 -0.114 0.70567E+04 194 beidellite-K -14.15 -15.80 -1.65 -0.101 0.65517E+04 195 beidellite-Mg -15.53 -16.56 -1.03 -0.064 0.40925E+04 196 beidellite-Na -14.09 -15.64 -1.55 -0.095 0.61436E+04 199 chalcocite -13.05 -14.32 -1.28 -0.319 0.50540E+04 200 covellite -11.60 -12.91 -1.30 -0.496 0.51583E+04 202 montmorillonite-Ca -11.12 -12.15 -1.03 -0.064 0.40723E+04 203 montmorillonite-K -10.35 -11.45 -1.10 -0.068 0.43682E+04 204 montmorillonite-Mg -11.37 -12.21 -0.85 -0.052 0.33486E+04 205 montmorillonite-Na -9.98 -11.29 -1.31 -0.080 0.51737E+04 206 nontronite-Ca -3.47 -4.99 -1.53 -0.099 0.60429E+04 207 nontronite-H -3.47 -5.49 -2.01 -0.135 0.79767E+04 208 nontronite-K -2.40 -4.29 -1.89 -0.122 0.74952E+04 209 nontronite-Mg -3.72 -5.05 -1.33 -0.086 0.52722E+04 210 nontronite-Na -2.33 -4.13 -1.79 -0.115 0.71003E+04 215 gypsum -11.37 -13.65 -2.28 -0.570 0.90208E+04 232 alabandite -5.93 -7.55 -1.62 -0.541 0.64282E+04 234 anglesite -13.60 -16.27 -2.67 -1.333 0.10553E+05 238 boehmite -4.84 -5.77 -0.93 -0.154 0.36648E+04 240 chalcopyrite -21.82 -21.84 -0.02 -0.004 0.91991E+02 242 copper,native 1.80 -1.42 -3.21 -1.118 0.12724E+05 244 ferrous-oxide 1.72 0.84 -0.87 -0.218 0.34578E+04 245 galena -8.98 -9.41 -0.44 -0.146 0.17328E+04 246 silver,native 0.58 -3.67 -4.24 -1.475 0.16792E+05 248 litharge 5.18 0.36 -4.82 -1.206 0.19089E+05 255 sphalerite -10.35 -10.53 -0.17 -0.058 0.68668E+03 256 wurtzite -9.57 -10.53 -0.95 -0.318 0.37752E+04 257 zincite 1.86 -0.75 -2.62 -0.654 0.10352E+05 258 an20ab80 -5.73 -5.74 -0.02 -0.001 0.71494E+02 259 an25ab75 -6.03 -6.04 -0.01 0.000 0.22286E+02 261 tr.625ac.25prg.125 8.90 7.35 -1.55 -0.042 0.61542E+04 Calculations done for 592.0000 Deg. C; 1856.0000 bar Temperature changed by -1.000 degrees to 591.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 23 Loop limit = 500 Temperature = 591.00 C Pressure = 1811.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5503E+02 kg liquid = 0.9914E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9951 Stoichiometric ionic strength = .3309701E+01 Osmotic coef. = 0.0000 True ionic strength = .2558874E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13702E-04 -4.8632 0.38534E-05 -5.4142 0.28123E+00 -0.5509 2 H2O 0.99514E+00 -0.0021 0.99514E+00 -0.0021 3 Cl- 0.21529E+00 -0.6670 0.56086E-01 -1.2511 0.26051E+00 -0.5842 4 SO4-- 0.16070E-03 -3.7940 0.13168E-05 -5.8805 0.81938E-02 -2.0865 5 HCO3- 0.29213E-04 -4.5344 0.81759E-05 -5.0875 0.27987E+00 -0.5530 6 HS- 0.15062E-03 -3.8221 0.39554E-04 -4.4028 0.26261E+00 -0.5807 7 H4SiO4 0.10361E+00 -0.9846 0.10361E+00 -0.9846 0.10000E+01 0.0000 8 Al+++ 0.62778E-17 -17.2022 0.98387E-22 -22.0071 0.15672E-04 -4.8049 9 Ca++ 0.23550E-05 -5.6280 0.15776E-07 -7.8020 0.66991E-02 -2.1740 10 Mg++ 0.12028E-05 -5.9198 0.66860E-08 -8.1748 0.55589E-02 -2.2550 11 Fe++ 0.19464E-07 -7.7108 0.11347E-09 -9.9451 0.58296E-02 -2.2344 12 K+ 0.56795E-01 -1.2457 0.16289E-01 -1.7881 0.28680E+00 -0.5424 13 Na+ 0.19668E+00 -0.7062 0.51890E-01 -1.2849 0.26382E+00 -0.5787 14 Mn++ 0.45733E-06 -6.3398 0.27600E-08 -8.5591 0.60350E-02 -2.2193 15 Zn++ 0.49619E-09 -9.3044 0.28926E-11 -11.5387 0.58296E-02 -2.2344 16 Cu+ 0.75243E-07 -7.1235 0.19800E-07 -7.7033 0.26315E+00 -0.5798 17 Pb++ 0.47916E-08 -8.3195 0.35733E-10 -10.4469 0.74574E-02 -2.1274 18 Ag+ 0.42248E-09 -9.3742 0.11936E-09 -9.9231 0.28253E+00 -0.5489 19 Ba++ 0.26041E-06 -6.5843 0.20773E-08 -8.6825 0.79772E-02 -2.0981 20 HPO4-- 0.13964E-08 -8.8550 0.11496E-10 -10.9395 0.82326E-02 -2.0845 21 HSiO3- 0.22912E-05 -5.6399 0.59687E-06 -6.2241 0.26051E+00 -0.5842 22 Ca(HSiO3)+ 0.13455E-07 -7.8711 0.38912E-08 -8.4099 0.28921E+00 -0.5388 23 Mg(HSiO3)+ 0.14463E-08 -8.8397 0.41828E-09 -9.3785 0.28921E+00 -0.5388 24 NaHSiO3,aq 0.13743E-05 -5.8619 0.13743E-05 -5.8619 0.10000E+01 0.0000 28 AgCl,aq 0.70589E-07 -7.1513 0.70589E-07 -7.1513 0.10000E+01 0.0000 29 AgCl2- 0.49920E-05 -5.3017 0.13005E-05 -5.8859 0.26051E+00 -0.5842 30 AgCl3-2 0.25058E-05 -5.6010 0.19093E-07 -7.7191 0.76193E-02 -2.1181 31 AgCl4-3 0.12029E-05 -5.9198 0.16291E-10 -10.7880 0.13543E-04 -4.8683 34 Ag(HS),aq 0.57890E-09 -9.2374 0.57890E-09 -9.2374 0.10000E+01 0.0000 35 Ag(HS)2- 0.35558E-08 -8.4491 0.92631E-09 -9.0332 0.26051E+00 -0.5842 36 AlO+ 0.12603E-10 -10.8995 0.36449E-11 -11.4383 0.28921E+00 -0.5388 38 HAlO2,aq 0.48132E-08 -8.3176 0.48132E-08 -8.3176 0.10000E+01 0.0000 39 AlO2- 0.21766E-04 -4.6622 0.49809E-05 -5.3027 0.22883E+00 -0.6405 41 Ba(HCO3)+ 0.13766E-05 -5.8612 0.41337E-06 -6.3837 0.30028E+00 -0.5225 42 BaCl+ 0.47639E-04 -4.3220 0.13777E-04 -4.8608 0.28921E+00 -0.5388 43 CH4,aq 0.20494E-08 -8.6884 0.24934E-08 -8.6032 0.12167E+01 0.0852 48 CO,aq 0.85155E-03 -3.0698 0.85155E-03 -3.0698 0.10000E+01 0.0000 49 CO2,aq 0.26781E+01 0.4278 0.32584E+01 0.5130 0.12167E+01 0.0852 50 CO3-2 0.53591E-10 -10.2709 0.40833E-12 -12.3890 0.76193E-02 -2.1181 51 CaCO3,aq 0.16236E-10 -10.7895 0.16236E-10 -10.7895 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.68250E-06 -6.1659 0.19738E-06 -6.7047 0.28921E+00 -0.5388 53 CaCl+ 0.23906E-03 -3.6215 0.69137E-04 -4.1603 0.28921E+00 -0.5388 54 CaCl2,aq 0.12902E-03 -3.8894 0.12902E-03 -3.8894 0.10000E+01 0.0000 55 CaOH+ 0.35744E-06 -6.4468 0.10337E-06 -6.9856 0.28921E+00 -0.5388 56 CaSO4,aq 0.10447E-06 -6.9810 0.10447E-06 -6.9810 0.10000E+01 0.0000 57 HCl,aq 0.11048E-02 -2.9567 0.11048E-02 -2.9567 0.10000E+01 0.0000 66 CuCl,aq 0.49426E-04 -4.3060 0.49426E-04 -4.3060 0.10000E+01 0.0000 67 CuCl2- 0.19658E-03 -3.7065 0.51209E-04 -4.2907 0.26051E+00 -0.5842 68 CuCl3-2 0.51452E-05 -5.2886 0.39202E-07 -7.4067 0.76193E-02 -2.1181 74 FeCl+ 0.61674E-06 -6.2099 0.17836E-06 -6.7487 0.28921E+00 -0.5388 75 FeCl2,aq 0.88112E-02 -2.0550 0.88112E-02 -2.0550 0.10000E+01 0.0000 77 FeO,aq 0.74204E-07 -7.1296 0.74204E-07 -7.1296 0.10000E+01 0.0000 78 FeOH+ 0.44972E-07 -7.3471 0.13006E-07 -7.8858 0.28921E+00 -0.5388 79 HFeO2- 0.10776E-07 -7.9675 0.28073E-08 -8.5517 0.26051E+00 -0.5842 82 FeO2- 0.65027E-08 -8.1869 0.16940E-08 -8.7711 0.26051E+00 -0.5842 83 HFeO2,aq 0.20680E-09 -9.6844 0.20680E-09 -9.6844 0.10000E+01 0.0000 84 H2,aq 0.44899E-02 -2.3478 0.54627E-02 -2.2626 0.12167E+01 0.0852 85 KCl,aq 0.53733E-01 -1.2698 0.53733E-01 -1.2698 0.10000E+01 0.0000 86 KHSO4,aq 0.12519E-01 -1.9024 0.12519E-01 -1.9024 0.10000E+01 0.0000 87 KOH,aq 0.89022E-06 -6.0505 0.89022E-06 -6.0505 0.10000E+01 0.0000 88 KSO4- 0.34442E-02 -2.4629 0.89724E-03 -3.0471 0.26051E+00 -0.5842 90 Mg(HCO3)+ 0.12382E-06 -6.9072 0.35810E-07 -7.4460 0.28921E+00 -0.5388 91 MgCl+ 0.18909E-04 -4.7233 0.54686E-05 -5.2621 0.28921E+00 -0.5388 92 MgOH+ 0.61806E-06 -6.2090 0.17875E-06 -6.7478 0.28921E+00 -0.5388 94 MnO,aq 0.26853E-07 -7.5710 0.26853E-07 -7.5710 0.10000E+01 0.0000 95 MnOH+ 0.13750E-06 -6.8617 0.39765E-07 -7.4005 0.28921E+00 -0.5388 97 HMnO2- 0.18511E-10 -10.7326 0.48221E-11 -11.3168 0.26051E+00 -0.5842 100 MnCl+ 0.11588E-02 -2.9360 0.33512E-03 -3.4748 0.28921E+00 -0.5388 101 MnSO4,aq 0.23357E-07 -7.6316 0.23357E-07 -7.6316 0.10000E+01 0.0000 102 NaCl,aq 0.36233E+00 -0.4409 0.36233E+00 -0.4409 0.10000E+01 0.0000 103 NaOH,aq 0.13061E-05 -5.8840 0.13061E-05 -5.8840 0.10000E+01 0.0000 105 OH- 0.96109E-05 -5.0172 0.21993E-05 -5.6577 0.22883E+00 -0.6405 110 HPO3-2 0.24998E-10 -10.6021 0.19047E-12 -12.7202 0.76193E-02 -2.1181 111 H3PO3,aq 0.19440E-09 -9.7113 0.19440E-09 -9.7113 0.10000E+01 0.0000 112 H2PO3- 0.87918E-08 -8.0559 0.22903E-08 -8.6401 0.26051E+00 -0.5842 113 H3PO4,aq 0.12944E-05 -5.8879 0.12944E-05 -5.8879 0.10000E+01 0.0000 114 H2PO4- 0.29877E-05 -5.5247 0.81688E-06 -6.0878 0.27341E+00 -0.5632 116 H4P2O7,aq 0.13702E-09 -9.8632 0.13702E-09 -9.8632 0.10000E+01 0.0000 117 H3P2O7- 0.31877E-08 -8.4965 0.83042E-09 -9.0807 0.26051E+00 -0.5842 118 H2P2O7-2 0.87398E-06 -6.0585 0.66591E-08 -8.1766 0.76193E-02 -2.1181 119 HP2O7-3 0.24551E-07 -7.6099 0.33251E-12 -12.4782 0.13543E-04 -4.8683 121 PbCl+ 0.28844E-05 -5.5399 0.83418E-06 -6.0787 0.28921E+00 -0.5388 122 PbCl2,aq 0.93504E-04 -4.0292 0.93504E-04 -4.0292 0.10000E+01 0.0000 123 PbCl3- 0.11465E-03 -3.9406 0.29868E-04 -4.5248 0.26051E+00 -0.5842 124 PbCl4-2 0.29599E-04 -4.5287 0.22552E-06 -6.6468 0.76193E-02 -2.1181 125 PbO,aq 0.33840E-08 -8.4706 0.33840E-08 -8.4706 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.94414E-04 -4.0250 0.94414E-04 -4.0250 0.10000E+01 0.0000 128 Pb(HS)3- 0.80433E-05 -5.0946 0.20953E-05 -5.6787 0.26051E+00 -0.5842 129 H2S,aq 0.10434E+01 0.0185 0.12695E+01 0.1036 0.12167E+01 0.0852 130 S2-2 0.14793E-07 -7.8299 0.11272E-09 -9.9480 0.76193E-02 -2.1181 131 S3-2 0.15954E-08 -8.7971 0.12155E-10 -10.9152 0.76193E-02 -2.1181 132 S3- 0.22806E-01 -1.6420 0.59410E-02 -2.2261 0.26051E+00 -0.5842 133 S4-2 0.14274E-09 -9.8455 0.10876E-11 -11.9635 0.76193E-02 -2.1181 134 S5-2 0.10751E-10 -10.9686 0.81914E-13 -13.0866 0.76193E-02 -2.1181 135 SO2,aq 0.28263E+00 -0.5488 0.28263E+00 -0.5488 0.10000E+01 0.0000 136 SO3-2 0.59382E-09 -9.2263 0.69438E-11 -11.1584 0.11693E-01 -1.9321 137 HSO3- 0.45507E-03 -3.3419 0.11855E-03 -3.9261 0.26051E+00 -0.5842 138 HSO4- 0.12523E-01 -1.9023 0.37112E-02 -2.4305 0.29634E+00 -0.5282 140 S2O3-2 0.50407E-06 -6.2975 0.38406E-08 -8.4156 0.76193E-02 -2.1181 141 HS2O3- 0.76855E-06 -6.1143 0.20021E-06 -6.6985 0.26051E+00 -0.5842 142 H2S2O3,aq 0.24350E-07 -7.6135 0.24350E-07 -7.6135 0.10000E+01 0.0000 150 S4O6-2 0.70560E-09 -9.1514 0.53761E-11 -11.2695 0.76193E-02 -2.1181 152 ZnCl+ 0.70572E-03 -3.1514 0.20410E-03 -3.6902 0.28921E+00 -0.5388 153 ZnCl2,aq 0.13979E-02 -2.8545 0.13979E-02 -2.8545 0.10000E+01 0.0000 154 ZnCl3- 0.21226E-03 -3.6731 0.55295E-04 -4.2573 0.26051E+00 -0.5842 155 ZnO,aq 0.34197E-07 -7.4660 0.34197E-07 -7.4660 0.10000E+01 0.0000 156 ZnOH+ 0.32956E-05 -5.4821 0.95311E-06 -6.0209 0.28921E+00 -0.5388 158 HZnO2- 0.31415E-09 -9.5029 0.81837E-10 -10.0871 0.26051E+00 -0.5842 Charge balance for all species = 0.2553E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1370188E-04 0.4301937E+01 0.3529713E+04 0.0000 2 H2O 0.1000000E+01 0.5249415E+02 0.7698270E+06 0.0000 3 Cl- 0.2152946E+00 0.6570804E+00 0.1896323E+05 4.1630 4 SO4-- 0.1607037E-03 0.2538839E+00 0.1985298E+05 4.9478 5 HCO3- 0.2921335E-04 0.2679026E+01 0.1330669E+06 0.3267 6 HS- 0.1506222E-03 0.1170034E+01 0.3149922E+05 1.0114 7 H4SiO4 0.1036059E+00 0.1036095E+00 0.8106501E+04 -0.9846 8 Al+++ 0.6277838E-17 0.2177127E-04 0.4781792E+00 -5.7646 9 Ca++ 0.2354958E-05 0.3715851E-03 0.1212286E+02 3.0263 10 Mg++ 0.1202751E-05 0.2085502E-04 0.4127356E+00 2.6535 11 Fe++ 0.1946372E-07 0.8812012E-02 0.4006044E+03 0.8832 12 K+ 0.5679519E-01 0.1264920E+00 0.4026268E+04 3.6261 13 Na+ 0.1966835E+00 0.5590180E+00 0.1046169E+05 4.1292 14 Mn++ 0.4573296E-06 0.1159416E-02 0.5185049E+02 2.2692 15 Zn++ 0.4961910E-09 0.2319170E-02 0.1234104E+03 -0.7104 16 Cu+ 0.7524340E-07 0.2512223E-03 0.1299410E+02 -2.2892 17 Pb++ 0.4791575E-08 0.3431071E-03 0.5786810E+02 0.3814 18 Ag+ 0.4224834E-09 0.8775899E-05 0.7706071E+00 -4.5090 19 Ba++ 0.2604085E-06 0.4927583E-04 0.5508987E+01 2.1458 20 HPO4-- 0.1396374E-08 0.6096280E-05 0.4763014E+00 -0.1111 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265144E+01 -.2781740E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5204519E+02 -.8041014E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517125E+00 0.1028145E-04 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1160027E+01 0.1166654E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1027234E+00 0.4087092E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2158507E-04 0.6729545E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3684071E-03 0.1595028E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8736647E-02 0.3010720E-04 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542370E+00 0.3623601E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.2490737E-03 0.1505360E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.4885440E-04 0.6518055E-05 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.6044141E-05 0.2523360E-05 0.0000000E+00 Chg. balance for solid moles: 0.1694E-19 Mass of aqueous solution: 0.121795E+04 g Temperature = 591.00 C Pressure = 1811.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8411E-06 -6.075 0.4225E-03 -3.374 0.1672E-01 0.1343E-03 quartz 0.3947E-01 -1.404 2.372 0.375 93.85 0.8956 bornite 0.3011E-04 -4.521 0.1511E-01 -1.821 0.5979 0.2972E-02 barite 0.6518E-05 -5.186 0.1521E-02 -2.818 0.6021E-01 0.3396E-03 an30ab70 0.5177E-03 -3.286 0.1382 -0.859 5.470 0.5191E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.526828 g Volume = 0.950953 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 30 apatite-OH -50.17 -50.17 0.00 0.000 0.00000E+00 144 quartz -0.98 -0.98 0.00 0.000 -0.43901E-12 197 bornite -50.69 -50.69 0.00 0.000 -0.28096E-10 237 barite -14.56 -14.56 0.00 0.000 0.00000E+00 260 an30ab70 -6.35 -6.35 0.00 0.000 -0.21072E-10 240 chalcopyrite -21.91 -21.90 0.01 0.001 -0.21578E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.292 0.11550E+04 2.966 2 CO2,gas -9.08 -10.50 -1.42 -0.474 0.56235E+04 1.836 3 CH4,gas 6.91 -3.61 -10.53 -2.631 0.41618E+05 -7.267 4 H2,gas 5.76 1.72 -4.04 -2.310 0.15988E+05 -0.785 5 H2S,gas -7.55 -9.82 -2.27 -1.134 0.89679E+04 0.990 6 CO,gas -3.16 -8.78 -5.62 -1.730 0.22227E+05 -2.363 7 SO3,gas -6.46 -16.71 -10.24 -2.561 0.40506E+05 -6.986 8 O2,gas 16.48 -3.45 -19.93 -13.285 0.78799E+05 -16.670 9 HCl,gas -5.63 -6.67 -1.04 -0.520 0.41089E+04 -1.039 10 acmite 3.89 2.19 -1.70 -0.176 0.67168E+04 12 akimotoite 5.82 1.67 -4.15 -0.829 0.16397E+05 13 akimotoite-Fe 3.80 -0.10 -3.90 -0.780 0.15415E+05 14 albite-high -4.44 -4.58 -0.14 -0.011 0.56520E+03 15 albite -4.41 -4.58 -0.18 -0.013 0.69350E+03 16 almandine -10.42 -11.83 -1.41 -0.071 0.55818E+04 17 pyrope -4.05 -6.52 -2.48 -0.124 0.97923E+04 18 analcite -2.65 -3.60 -0.95 -0.106 0.37719E+04 19 andalusite -12.34 -12.52 -0.18 -0.018 0.70272E+03 20 andradite 11.15 6.17 -4.98 -0.259 0.19690E+05 21 grossular -0.55 -5.40 -4.85 -0.243 0.19192E+05 22 anhydrite -13.55 -13.68 -0.13 -0.065 0.51337E+03 24 annite -0.75 -2.44 -1.70 -0.094 0.67072E+04 25 phlogopite 3.67 2.87 -0.80 -0.044 0.31562E+04 27 anorthite -10.00 -10.47 -0.47 -0.036 0.18746E+04 28 anthophyllite 13.44 10.71 -2.73 -0.074 0.10775E+05 29 anthophyllite-Fe 1.36 -1.68 -3.04 -0.082 0.12012E+05 31 apatite-OH-zs -48.08 -50.17 -2.09 -0.161 0.82706E+04 32 apatite-Cl-zs -53.80 -56.84 -3.03 -0.253 0.11997E+05 33 aragonite -4.04 -7.48 -3.43 -1.144 0.13572E+05 34 brucite 4.93 2.65 -2.28 -0.456 0.90129E+04 35 calcite -4.13 -7.48 -3.34 -1.114 0.13216E+05 36 carnegieite-low -0.85 -2.62 -1.77 -0.253 0.70016E+04 37 carnegieite-high -0.79 -2.62 -1.83 -0.262 0.72531E+04 38 carpholite-Mg -9.11 -10.85 -1.74 -0.116 0.68848E+04 39 carpholite-Fe -10.41 -12.62 -2.21 -0.148 0.87507E+04 40 celadonite -1.23 -3.42 -2.18 -0.128 0.86212E+04 41 celadonite-Fe -2.59 -5.19 -2.60 -0.153 0.10264E+05 42 chrysotile 8.62 5.99 -2.63 -0.220 0.10418E+05 44 clinochlore 0.35 -1.23 -1.58 -0.049 0.62403E+04 45 daphnite -6.42 -10.08 -3.66 -0.114 0.14471E+05 48 chloritoid-Mg -8.79 -9.87 -1.07 -0.072 0.42500E+04 49 chloritoid-Fe -10.64 -11.64 -1.00 -0.067 0.39473E+04 50 chloritoid-Mn -8.47 -10.25 -1.78 -0.118 0.70247E+04 52 coesite -0.71 -0.98 -0.27 -0.091 0.10833E+04 53 cordierite-H -22.29 -22.67 -0.38 -0.014 0.15116E+04 54 cordierite-Fe -24.64 -26.21 -1.57 -0.054 0.61934E+04 55 cordierite-Mn -20.24 -23.44 -3.20 -0.110 0.12667E+05 56 corundum -11.20 -11.54 -0.34 -0.031 0.13382E+04 58 cristobalite -0.93 -0.98 -0.05 -0.018 0.21731E+03 59 cummingtonite 13.49 10.71 -2.78 -0.075 0.10994E+05 61 cymrite-K -2.84 -5.09 -2.25 -0.187 0.88911E+04 63 diaspore -5.10 -5.77 -0.67 -0.112 0.26525E+04 65 diopside 5.19 3.71 -1.47 -0.147 0.58273E+04 66 hedenbergite 3.83 1.94 -1.88 -0.188 0.74455E+04 68 eastonite -9.12 -10.34 -1.22 -0.047 0.48310E+04 69 enstatite 4.34 3.34 -0.99 -0.099 0.39288E+04 70 clinoenstatite-HiP 4.81 3.34 -1.47 -0.147 0.58123E+04 71 clinoenstatite 4.32 3.34 -0.98 -0.098 0.38820E+04 72 protoenstatite 4.47 3.34 -1.12 -0.112 0.44439E+04 73 epidote -6.34 -8.41 -2.07 -0.100 0.81739E+04 74 clinozoisite -11.93 -14.20 -2.27 -0.103 0.89779E+04 75 epidote-Fe 0.90 -2.62 -3.52 -0.183 0.13924E+05 76 fayalite 1.81 0.78 -1.03 -0.147 0.40580E+04 77 ferrosilite 0.91 -0.20 -1.11 -0.111 0.43915E+04 78 forsterite 5.64 4.32 -1.32 -0.188 0.52158E+04 79 gedrite -13.87 -15.70 -1.83 -0.049 0.72345E+04 81 gibbsite -3.52 -5.77 -2.25 -0.321 0.88817E+04 82 glaucophane 0.16 -3.17 -3.33 -0.090 0.13149E+05 83 glaucophane-Fe -3.71 -8.48 -4.77 -0.129 0.18878E+05 84 goethite 0.89 0.02 -0.87 -0.188 0.34437E+04 86 greenalite 3.99 0.68 -3.31 -0.276 0.13081E+05 87 grunerite 1.88 -1.68 -3.56 -0.096 0.14085E+05 88 halite -0.44 -2.54 -2.10 -1.048 0.82855E+04 89 hematite 0.29 0.04 -0.25 -0.030 0.97246E+03 90 heulandite -12.74 -15.39 -2.64 -0.120 0.10457E+05 91 hercynite -9.83 -10.65 -0.83 -0.055 0.32794E+04 94 jadeite -1.97 -3.60 -1.63 -0.163 0.64277E+04 96 kalsilite -1.49 -3.12 -1.64 -0.234 0.64756E+04 97 kaolinite -11.07 -13.50 -2.43 -0.221 0.95944E+04 98 kyanite -12.20 -12.52 -0.32 -0.032 0.12674E+04 100 laumontite -9.20 -12.44 -3.24 -0.216 0.12814E+05 101 lawsonite -7.33 -10.48 -3.14 -0.210 0.12434E+05 102 leucite -3.11 -4.10 -0.99 -0.099 0.39328E+04 104 lizardite 8.82 5.99 -2.83 -0.236 0.11182E+05 105 magnesite -5.09 -7.85 -2.76 -0.920 0.10919E+05 106 magnetite 1.15 0.92 -0.23 -0.019 0.91985E+03 107 minnesotaite 0.79 -1.28 -2.07 -0.122 0.82012E+04 108 minnesotaite-Mg 6.52 4.03 -2.49 -0.146 0.98390E+04 109 magnesioferrite 4.11 2.69 -1.42 -0.116 0.56185E+04 111 manganosite 5.00 2.27 -2.73 -0.683 0.10810E+05 112 margarite -20.74 -22.01 -1.27 -0.051 0.50215E+04 115 microcline -5.00 -5.08 -0.09 -0.007 0.33787E+03 116 monticellite 8.29 4.70 -3.59 -0.514 0.14215E+05 118 mullite-Si -11.63 -12.52 -0.89 -0.089 0.35085E+04 119 muscovite -16.08 -16.62 -0.54 -0.032 0.21294E+04 120 paragonite -15.40 -16.12 -0.72 -0.042 0.28298E+04 121 nepheline -1.14 -2.62 -1.48 -0.212 0.58583E+04 122 osumilite(2) -14.54 -16.51 -1.97 -0.041 0.77902E+04 123 osumilite-Fe -31.28 -33.26 -1.97 -0.041 0.77956E+04 124 pargasite 1.59 -2.41 -4.00 -0.105 0.15811E+05 125 periclase 5.12 2.65 -2.47 -0.616 0.97496E+04 126 periclase-Fe 2.63 0.88 -1.75 -0.437 0.69129E+04 127 perovskite-Al -9.51 -11.54 -2.02 -0.184 0.79903E+04 132 phlogopite-Na 4.53 3.37 -1.16 -0.064 0.45852E+04 134 prehnite -5.35 -8.43 -3.08 -0.181 0.12180E+05 135 prehnite-Fe 0.63 -2.64 -3.27 -0.197 0.12940E+05 138 px-Mg-tschermaks -8.24 -9.86 -1.63 -0.116 0.64273E+04 139 px-Ca-tschermaks -7.20 -9.49 -2.29 -0.164 0.90553E+04 140 pyrite -20.35 -20.47 -0.12 -0.028 0.47609E+03 141 pyrrhotite -8.24 -8.93 -0.69 -0.230 0.27330E+04 142 pyrrhotiteFe0.875 -8.94 -9.26 -0.31 -0.116 0.12450E+04 143 pyrophyllite -14.43 -15.46 -1.03 -0.064 0.40802E+04 146 riebeckite 6.37 3.09 -3.28 -0.090 0.12951E+05 147 ringwoodite-Fe 2.78 0.78 -2.00 -0.286 0.79114E+04 148 ringwoodite-Mg 8.71 4.32 -4.39 -0.627 0.17347E+05 149 rhodochrosite -4.93 -8.23 -3.30 -1.099 0.13041E+05 150 rhodonite 2.44 1.29 -1.15 -0.230 0.45420E+04 151 sanidine -4.48 -5.08 -0.61 -0.047 0.24044E+04 152 sapphirine(351) -46.48 -50.70 -4.22 -0.064 0.16686E+05 153 siderite -6.84 -9.62 -2.78 -0.927 0.10993E+05 154 sillimanite -12.31 -12.52 -0.20 -0.020 0.80450E+03 156 spinel -7.73 -8.88 -1.15 -0.077 0.45525E+04 158 staurolite-Fe -103.78 -107.65 -3.87 -0.035 0.15295E+05 159 staurolite-Mg -95.67 -100.57 -4.90 -0.045 0.19371E+05 162 stilpnomelane-Fe -8.52 -13.17 -4.66 -0.139 0.18416E+05 163 stilpnomelane-Mg -2.12 -4.32 -2.21 -0.066 0.87236E+04 164 stishovite 1.88 -0.98 -2.86 -0.954 0.11319E+05 165 sudoite-Fe -20.79 -24.26 -3.47 -0.112 0.13725E+05 166 sudoite -18.67 -20.72 -2.05 -0.066 0.80912E+04 167 sulfur -10.06 -11.54 -1.48 -0.456 0.58629E+04 168 sylvite -0.35 -3.04 -2.69 -1.343 0.10623E+05 169 talc 4.82 4.03 -0.79 -0.047 0.31303E+04 170 talc-Fe 2.14 -1.28 -3.42 -0.201 0.13515E+05 171 talc-tschermaks -7.68 -9.18 -1.50 -0.088 0.59258E+04 173 tephroite 6.13 3.55 -2.58 -0.368 0.10187E+05 176 topaz-H -10.30 -12.52 -2.22 -0.202 0.87823E+04 177 tremolite 14.58 11.46 -3.12 -0.084 0.12321E+05 179 troilite-low -8.14 -8.93 -0.79 -0.263 0.31214E+04 180 tschermakite -11.96 -14.95 -3.00 -0.081 0.11846E+05 183 wadsleyite-Fe 2.63 0.78 -1.85 -0.264 0.73034E+04 184 wadsleyite-Mg 7.79 4.32 -3.46 -0.495 0.13699E+05 185 wairakite -10.94 -12.44 -1.49 -0.088 0.59026E+04 186 walstromite 4.56 2.04 -2.52 -0.504 0.99634E+04 187 wollastonite 4.17 2.04 -2.12 -0.424 0.83880E+04 188 pseudo-wollastonite 4.27 2.04 -2.23 -0.446 0.88133E+04 189 zoisite -11.99 -14.20 -2.21 -0.100 0.87301E+04 192 beidellite-Ca -15.21 -16.54 -1.33 -0.082 0.52441E+04 193 beidellite-H -15.21 -17.04 -1.83 -0.117 0.72313E+04 194 beidellite-K -14.15 -15.84 -1.69 -0.104 0.67021E+04 195 beidellite-Mg -15.53 -16.60 -1.08 -0.067 0.42518E+04 196 beidellite-Na -14.08 -15.68 -1.59 -0.097 0.62948E+04 199 chalcocite -13.10 -14.40 -1.29 -0.323 0.51085E+04 200 covellite -11.66 -12.97 -1.31 -0.499 0.51812E+04 202 montmorillonite-Ca -11.14 -12.18 -1.05 -0.065 0.41328E+04 203 montmorillonite-K -10.36 -11.48 -1.12 -0.069 0.44295E+04 204 montmorillonite-Mg -11.38 -12.24 -0.86 -0.053 0.34085E+04 205 montmorillonite-Na -10.00 -11.32 -1.32 -0.081 0.52293E+04 206 nontronite-Ca -3.50 -4.97 -1.46 -0.095 0.57791E+04 207 nontronite-H -3.51 -5.46 -1.96 -0.131 0.77347E+04 208 nontronite-K -2.44 -4.27 -1.83 -0.117 0.72291E+04 209 nontronite-Mg -3.76 -5.03 -1.27 -0.082 0.50097E+04 210 nontronite-Na -2.37 -4.10 -1.73 -0.111 0.68352E+04 215 gypsum -11.43 -13.69 -2.25 -0.564 0.89134E+04 232 alabandite -5.96 -7.55 -1.58 -0.528 0.62612E+04 234 anglesite -13.68 -16.33 -2.65 -1.323 0.10466E+05 238 boehmite -4.82 -5.77 -0.95 -0.158 0.37407E+04 242 copper,native 1.79 -1.43 -3.22 -1.121 0.12746E+05 244 ferrous-oxide 1.72 0.88 -0.84 -0.210 0.33256E+04 245 galena -9.02 -9.44 -0.41 -0.137 0.16282E+04 246 silver,native 0.57 -3.65 -4.22 -1.468 0.16688E+05 248 litharge 5.18 0.38 -4.80 -1.200 0.18986E+05 255 sphalerite -10.39 -10.53 -0.13 -0.045 0.52815E+03 256 wurtzite -9.61 -10.53 -0.91 -0.305 0.36170E+04 257 zincite 1.87 -0.71 -2.58 -0.645 0.10199E+05 258 an20ab80 -5.74 -5.76 -0.02 -0.001 0.70816E+02 259 an25ab75 -6.05 -6.05 -0.01 0.000 0.22147E+02 261 tr.625ac.25prg.125 8.85 7.51 -1.34 -0.036 0.52875E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 19 Loop limit = 500 Temperature = 591.00 C Pressure = 1811.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5503E+02 kg liquid = 0.9914E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9951 Stoichiometric ionic strength = .3309452E+01 Osmotic coef. = 0.0000 True ionic strength = .2558414E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13741E-04 -4.8620 0.38647E-05 -5.4129 0.28125E+00 -0.5509 2 H2O 0.99514E+00 -0.0021 0.99514E+00 -0.0021 3 Cl- 0.21536E+00 -0.6668 0.56106E-01 -1.2510 0.26053E+00 -0.5842 4 SO4-- 0.15982E-03 -3.7964 0.13099E-05 -5.8828 0.81961E-02 -2.0864 5 HCO3- 0.29125E-04 -4.5357 0.81518E-05 -5.0887 0.27989E+00 -0.5530 6 HS- 0.15017E-03 -3.8234 0.39438E-04 -4.4041 0.26262E+00 -0.5807 7 H4SiO4 0.10361E+00 -0.9846 0.10361E+00 -0.9846 0.10000E+01 0.0000 8 Al+++ 0.63488E-17 -17.1973 0.99566E-22 -22.0019 0.15683E-04 -4.8046 9 Ca++ 0.23538E-05 -5.6282 0.15773E-07 -7.8021 0.67012E-02 -2.1739 10 Mg++ 0.12022E-05 -5.9200 0.66850E-08 -8.1749 0.55608E-02 -2.2549 11 Fe++ 0.19266E-07 -7.7152 0.11235E-09 -9.9494 0.58315E-02 -2.2342 12 K+ 0.56806E-01 -1.2456 0.16293E-01 -1.7880 0.28682E+00 -0.5424 13 Na+ 0.19663E+00 -0.7064 0.51879E-01 -1.2850 0.26384E+00 -0.5787 14 Mn++ 0.45704E-06 -6.3400 0.27592E-08 -8.5592 0.60370E-02 -2.2192 15 Zn++ 0.49572E-09 -9.3048 0.28908E-11 -11.5390 0.58315E-02 -2.2342 16 Cu+ 0.75697E-07 -7.1209 0.19921E-07 -7.7007 0.26316E+00 -0.5798 17 Pb++ 0.47958E-08 -8.3191 0.35775E-10 -10.4464 0.74596E-02 -2.1273 18 Ag+ 0.42216E-09 -9.3745 0.11928E-09 -9.9234 0.28255E+00 -0.5489 19 Ba++ 0.26170E-06 -6.5822 0.20882E-08 -8.6802 0.79795E-02 -2.0980 20 HPO4-- 0.14019E-08 -8.8533 0.11544E-10 -10.9376 0.82349E-02 -2.0843 21 HSiO3- 0.22843E-05 -5.6412 0.59511E-06 -6.2254 0.26053E+00 -0.5842 22 Ca(HSiO3)+ 0.13412E-07 -7.8725 0.38791E-08 -8.4113 0.28922E+00 -0.5388 23 Mg(HSiO3)+ 0.14418E-08 -8.8411 0.41699E-09 -9.3799 0.28922E+00 -0.5388 24 NaHSiO3,aq 0.13700E-05 -5.8633 0.13700E-05 -5.8633 0.10000E+01 0.0000 28 AgCl,aq 0.70565E-07 -7.1514 0.70565E-07 -7.1514 0.10000E+01 0.0000 29 AgCl2- 0.49918E-05 -5.3017 0.13005E-05 -5.8859 0.26053E+00 -0.5842 30 AgCl3-2 0.25061E-05 -5.6010 0.19100E-07 -7.7190 0.76215E-02 -2.1180 31 AgCl4-3 0.12030E-05 -5.9198 0.16304E-10 -10.7877 0.13553E-04 -4.8680 34 Ag(HS),aq 0.57678E-09 -9.2390 0.57678E-09 -9.2390 0.10000E+01 0.0000 35 Ag(HS)2- 0.35321E-08 -8.4520 0.92020E-09 -9.0361 0.26053E+00 -0.5842 36 AlO+ 0.12679E-10 -10.8969 0.36669E-11 -11.4357 0.28922E+00 -0.5388 38 HAlO2,aq 0.48281E-08 -8.3162 0.48281E-08 -8.3162 0.10000E+01 0.0000 39 AlO2- 0.21768E-04 -4.6622 0.49817E-05 -5.3026 0.22885E+00 -0.6404 41 Ba(HCO3)+ 0.13797E-05 -5.8602 0.41432E-06 -6.3827 0.30030E+00 -0.5225 42 BaCl+ 0.47904E-04 -4.3196 0.13855E-04 -4.8584 0.28922E+00 -0.5388 43 CH4,aq 0.20481E-08 -8.6887 0.24918E-08 -8.6035 0.12167E+01 0.0852 48 CO,aq 0.85140E-03 -3.0699 0.85140E-03 -3.0699 0.10000E+01 0.0000 49 CO2,aq 0.26781E+01 0.4278 0.32584E+01 0.5130 0.12167E+01 0.0852 50 CO3-2 0.53261E-10 -10.2736 0.40593E-12 -12.3916 0.76215E-02 -2.1180 51 CaCO3,aq 0.16138E-10 -10.7921 0.16138E-10 -10.7921 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.68033E-06 -6.1673 0.19677E-06 -6.7060 0.28922E+00 -0.5388 53 CaCl+ 0.23909E-03 -3.6214 0.69150E-04 -4.1602 0.28922E+00 -0.5388 54 CaCl2,aq 0.12909E-03 -3.8891 0.12909E-03 -3.8891 0.10000E+01 0.0000 55 CaOH+ 0.35631E-06 -6.4482 0.10305E-06 -6.9869 0.28922E+00 -0.5388 56 CaSO4,aq 0.10391E-06 -6.9833 0.10391E-06 -6.9833 0.10000E+01 0.0000 57 HCl,aq 0.11084E-02 -2.9553 0.11084E-02 -2.9553 0.10000E+01 0.0000 66 CuCl,aq 0.49746E-04 -4.3032 0.49746E-04 -4.3032 0.10000E+01 0.0000 67 CuCl2- 0.19791E-03 -3.7035 0.51560E-04 -4.2877 0.26053E+00 -0.5842 68 CuCl3-2 0.51808E-05 -5.2856 0.39485E-07 -7.4036 0.76215E-02 -2.1180 74 FeCl+ 0.61086E-06 -6.2141 0.17667E-06 -6.7528 0.28922E+00 -0.5388 75 FeCl2,aq 0.87309E-02 -2.0589 0.87309E-02 -2.0589 0.10000E+01 0.0000 77 FeO,aq 0.73043E-07 -7.1364 0.73043E-07 -7.1364 0.10000E+01 0.0000 78 FeOH+ 0.44396E-07 -7.3527 0.12840E-07 -7.8914 0.28922E+00 -0.5388 79 HFeO2- 0.10576E-07 -7.9757 0.27553E-08 -8.5598 0.26053E+00 -0.5842 82 FeO2- 0.63823E-08 -8.1950 0.16627E-08 -8.7792 0.26053E+00 -0.5842 83 HFeO2,aq 0.20358E-09 -9.6913 0.20358E-09 -9.6913 0.10000E+01 0.0000 84 H2,aq 0.44892E-02 -2.3478 0.54618E-02 -2.2627 0.12167E+01 0.0852 85 KCl,aq 0.53766E-01 -1.2695 0.53766E-01 -1.2695 0.10000E+01 0.0000 86 KHSO4,aq 0.12493E-01 -1.9033 0.12493E-01 -1.9033 0.10000E+01 0.0000 87 KOH,aq 0.88782E-06 -6.0517 0.88782E-06 -6.0517 0.10000E+01 0.0000 88 KSO4- 0.34268E-02 -2.4651 0.89277E-03 -3.0493 0.26053E+00 -0.5842 90 Mg(HCO3)+ 0.12343E-06 -6.9086 0.35699E-07 -7.4473 0.28922E+00 -0.5388 91 MgCl+ 0.18912E-04 -4.7233 0.54697E-05 -5.2620 0.28922E+00 -0.5388 92 MgOH+ 0.61611E-06 -6.2103 0.17819E-06 -6.7491 0.28922E+00 -0.5388 94 MnO,aq 0.26687E-07 -7.5737 0.26687E-07 -7.5737 0.10000E+01 0.0000 95 MnOH+ 0.13704E-06 -6.8631 0.39636E-07 -7.4019 0.28922E+00 -0.5388 97 HMnO2- 0.18341E-10 -10.7366 0.47783E-11 -11.3207 0.26053E+00 -0.5842 100 MnCl+ 0.11588E-02 -2.9360 0.33514E-03 -3.4748 0.28922E+00 -0.5388 101 MnSO4,aq 0.23228E-07 -7.6340 0.23228E-07 -7.6340 0.10000E+01 0.0000 102 NaCl,aq 0.36239E+00 -0.4408 0.36239E+00 -0.4408 0.10000E+01 0.0000 103 NaOH,aq 0.13020E-05 -5.8854 0.13020E-05 -5.8854 0.10000E+01 0.0000 105 OH- 0.95818E-05 -5.0186 0.21928E-05 -5.6590 0.22885E+00 -0.6404 110 HPO3-2 0.25092E-10 -10.6005 0.19124E-12 -12.7184 0.76215E-02 -2.1180 111 H3PO3,aq 0.19634E-09 -9.7070 0.19634E-09 -9.7070 0.10000E+01 0.0000 112 H2PO3- 0.88528E-08 -8.0529 0.23064E-08 -8.6371 0.26053E+00 -0.5842 113 H3PO4,aq 0.13075E-05 -5.8835 0.13075E-05 -5.8835 0.10000E+01 0.0000 114 H2PO4- 0.30090E-05 -5.5216 0.82275E-06 -6.0847 0.27343E+00 -0.5632 116 H4P2O7,aq 0.13981E-09 -9.8545 0.13981E-09 -9.8545 0.10000E+01 0.0000 117 H3P2O7- 0.32429E-08 -8.4891 0.84485E-09 -9.0732 0.26053E+00 -0.5842 118 H2P2O7-2 0.88631E-06 -6.0524 0.67550E-08 -8.1704 0.76215E-02 -2.1180 119 HP2O7-3 0.24814E-07 -7.6053 0.33630E-12 -12.4733 0.13553E-04 -4.8680 121 PbCl+ 0.28887E-05 -5.5393 0.83547E-06 -6.0781 0.28922E+00 -0.5388 122 PbCl2,aq 0.93683E-04 -4.0283 0.93683E-04 -4.0283 0.10000E+01 0.0000 123 PbCl3- 0.11491E-03 -3.9397 0.29936E-04 -4.5238 0.26053E+00 -0.5842 124 PbCl4-2 0.29669E-04 -4.5277 0.22612E-06 -6.6457 0.76215E-02 -2.1180 125 PbO,aq 0.33682E-08 -8.4726 0.33682E-08 -8.4726 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.93969E-04 -4.0270 0.93969E-04 -4.0270 0.10000E+01 0.0000 128 Pb(HS)3- 0.79813E-05 -5.0979 0.20793E-05 -5.6821 0.26053E+00 -0.5842 129 H2S,aq 0.10434E+01 0.0185 0.12695E+01 0.1036 0.12167E+01 0.0852 130 S2-2 0.14704E-07 -7.8326 0.11207E-09 -9.9505 0.76215E-02 -2.1180 131 S3-2 0.15860E-08 -8.7997 0.12088E-10 -10.9177 0.76215E-02 -2.1180 132 S3- 0.22746E-01 -1.6431 0.59258E-02 -2.2273 0.26053E+00 -0.5842 133 S4-2 0.14193E-09 -9.8479 0.10817E-11 -11.9659 0.76215E-02 -2.1180 134 S5-2 0.10691E-10 -10.9710 0.81482E-13 -13.0889 0.76215E-02 -2.1180 135 SO2,aq 0.28277E+00 -0.5486 0.28277E+00 -0.5486 0.10000E+01 0.0000 136 SO3-2 0.59048E-09 -9.2288 0.69064E-11 -11.1607 0.11696E-01 -1.9320 137 HSO3- 0.45392E-03 -3.3430 0.11826E-03 -3.9272 0.26053E+00 -0.5842 138 HSO4- 0.12494E-01 -1.9033 0.37026E-02 -2.4315 0.29636E+00 -0.5282 140 S2O3-2 0.50128E-06 -6.2999 0.38205E-08 -8.4179 0.76215E-02 -2.1180 141 HS2O3- 0.76672E-06 -6.1154 0.19975E-06 -6.6995 0.26053E+00 -0.5842 142 H2S2O3,aq 0.24365E-07 -7.6132 0.24365E-07 -7.6132 0.10000E+01 0.0000 150 S4O6-2 0.70226E-09 -9.1535 0.53523E-11 -11.2715 0.76215E-02 -2.1180 152 ZnCl+ 0.70549E-03 -3.1515 0.20404E-03 -3.6903 0.28922E+00 -0.5388 153 ZnCl2,aq 0.13980E-02 -2.8545 0.13980E-02 -2.8545 0.10000E+01 0.0000 154 ZnCl3- 0.21235E-03 -3.6730 0.55321E-04 -4.2571 0.26053E+00 -0.5842 155 ZnO,aq 0.33975E-07 -7.4688 0.33975E-07 -7.4688 0.10000E+01 0.0000 156 ZnOH+ 0.32837E-05 -5.4836 0.94971E-06 -6.0224 0.28922E+00 -0.5388 158 HZnO2- 0.31117E-09 -9.5070 0.81067E-10 -10.0912 0.26053E+00 -0.5842 Charge balance for all species = 0.2553E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1374126E-04 0.4301964E+01 0.3529761E+04 0.0000 2 H2O 0.1000000E+01 0.5249417E+02 0.7698327E+06 0.0000 3 Cl- 0.2153578E+00 0.6570801E+00 0.1896335E+05 4.1619 4 SO4-- 0.1598193E-03 0.2538740E+00 0.1985235E+05 4.9430 5 HCO3- 0.2912543E-04 0.2679024E+01 0.1330677E+06 0.3241 6 HS- 0.1501676E-03 0.1169924E+01 0.3149648E+05 1.0088 7 H4SiO4 0.1036060E+00 0.1036097E+00 0.8106568E+04 -0.9846 8 Al+++ 0.6348769E-17 0.2177267E-04 0.4782132E+00 -5.7632 9 Ca++ 0.2353832E-05 0.3716848E-03 0.1212620E+02 3.0237 10 Mg++ 0.1202168E-05 0.2085501E-04 0.4127384E+00 2.6509 11 Fe++ 0.1926593E-07 0.8731677E-02 0.3969550E+03 0.8763 12 K+ 0.5680556E-01 0.1264919E+00 0.4026295E+04 3.6249 13 Na+ 0.1966278E+00 0.5590178E+00 0.1046176E+05 4.1279 14 Mn++ 0.4570429E-06 0.1159415E-02 0.5185084E+02 2.2665 15 Zn++ 0.4957203E-09 0.2319169E-02 0.1234112E+03 -0.7132 16 Cu+ 0.7569747E-07 0.2529092E-03 0.1308144E+02 -2.2878 17 Pb++ 0.4795839E-08 0.3431069E-03 0.5786849E+02 0.3793 18 Ag+ 0.4221573E-09 0.8775895E-05 0.7706123E+00 -4.5106 19 Ba++ 0.2617017E-06 0.4954511E-04 0.5539131E+01 2.1455 20 HPO4-- 0.1401868E-08 0.6156006E-05 0.4809712E+00 -0.1119 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265173E+01 -.2810686E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5204523E+02 -.8044964E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2517028E+00 0.1997001E-04 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159919E+01 0.2253401E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.1027236E+00 0.4087075E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2158647E-04 0.6729531E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3685061E-03 0.1594038E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8657002E-02 0.1097516E-03 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542370E+00 0.3623593E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.2507463E-03 0.1488634E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.4912139E-04 0.6251059E-05 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.6103359E-05 0.2464141E-05 0.0000000E+00 Chg. balance for solid moles: 0.8301E-19 Mass of aqueous solution: 0.121794E+04 g Temperature = 591.00 C Pressure = 1811.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8214E-06 -6.085 0.4126E-03 -3.384 0.1628E-01 0.1311E-03 quartz 0.3947E-01 -1.404 2.372 0.375 93.56 0.8956 bornite 0.9778E-05 -5.010 0.4907E-02 -2.309 0.1936 0.9653E-03 barite 0.6251E-05 -5.204 0.1459E-02 -2.836 0.5756E-01 0.3257E-03 an30ab70 0.5177E-03 -3.286 0.1382 -0.859 5.453 0.5191E-01 chalcopyrite 0.9997E-04 -4.000 0.1835E-01 -1.736 0.7237 0.4282E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.534889 g Volume = 0.953207 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 30 apatite-OH -50.17 -50.17 0.00 0.000 0.00000E+00 144 quartz -0.98 -0.98 0.00 0.000 0.00000E+00 197 bornite -50.69 -50.69 0.00 0.000 0.00000E+00 237 barite -14.56 -14.56 0.00 0.000 0.00000E+00 240 chalcopyrite -21.91 -21.91 0.00 0.000 0.00000E+00 260 an30ab70 -6.35 -6.35 0.00 0.000 0.35120E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.292 0.11550E+04 2.966 2 CO2,gas -9.08 -10.50 -1.42 -0.474 0.56235E+04 1.836 3 CH4,gas 6.91 -3.61 -10.53 -2.631 0.41619E+05 -7.267 4 H2,gas 5.76 1.72 -4.04 -2.311 0.15988E+05 -0.785 5 H2S,gas -7.55 -9.82 -2.27 -1.134 0.89679E+04 0.990 6 CO,gas -3.16 -8.78 -5.62 -1.730 0.22227E+05 -2.363 7 SO3,gas -6.46 -16.71 -10.24 -2.561 0.40505E+05 -6.986 8 O2,gas 16.48 -3.45 -19.93 -13.285 0.78798E+05 -16.670 9 HCl,gas -5.63 -6.66 -1.04 -0.519 0.41032E+04 -1.038 10 acmite 3.89 2.18 -1.71 -0.177 0.67492E+04 12 akimotoite 5.82 1.67 -4.15 -0.830 0.16408E+05 13 akimotoite-Fe 3.80 -0.11 -3.91 -0.781 0.15442E+05 14 albite-high -4.44 -4.58 -0.14 -0.011 0.56530E+03 15 albite -4.41 -4.58 -0.18 -0.013 0.69361E+03 16 almandine -10.42 -11.85 -1.43 -0.071 0.56525E+04 17 pyrope -4.05 -6.53 -2.48 -0.124 0.98128E+04 18 analcite -2.65 -3.60 -0.95 -0.106 0.37720E+04 19 andalusite -12.34 -12.51 -0.18 -0.018 0.69209E+03 21 grossular -0.55 -5.41 -4.86 -0.243 0.19213E+05 22 anhydrite -13.55 -13.68 -0.13 -0.066 0.52266E+03 24 annite -0.75 -2.46 -1.72 -0.095 0.67877E+04 25 phlogopite 3.67 2.86 -0.81 -0.045 0.31867E+04 27 anorthite -10.00 -10.47 -0.47 -0.036 0.18744E+04 28 anthophyllite 13.44 10.70 -2.74 -0.074 0.10848E+05 29 anthophyllite-Fe 1.36 -1.73 -3.09 -0.083 0.12202E+05 31 apatite-OH-zs -48.08 -50.17 -2.09 -0.161 0.82706E+04 32 apatite-Cl-zs -53.80 -56.84 -3.03 -0.253 0.11991E+05 33 aragonite -4.04 -7.48 -3.44 -1.145 0.13583E+05 34 brucite 4.93 2.65 -2.28 -0.456 0.90233E+04 35 calcite -4.13 -7.48 -3.34 -1.115 0.13226E+05 36 carnegieite-low -0.85 -2.62 -1.77 -0.253 0.70017E+04 37 carnegieite-high -0.79 -2.62 -1.83 -0.262 0.72532E+04 38 carpholite-Mg -9.11 -10.85 -1.74 -0.116 0.68845E+04 39 carpholite-Fe -10.41 -12.62 -2.22 -0.148 0.87671E+04 40 celadonite -1.23 -3.42 -2.18 -0.128 0.86309E+04 41 celadonite-Fe -2.59 -5.19 -2.60 -0.153 0.10290E+05 42 chrysotile 8.62 5.98 -2.64 -0.220 0.10449E+05 44 clinochlore 0.35 -1.24 -1.59 -0.050 0.62815E+04 45 daphnite -6.42 -10.11 -3.69 -0.115 0.14596E+05 48 chloritoid-Mg -8.79 -9.87 -1.07 -0.072 0.42497E+04 49 chloritoid-Fe -10.64 -11.64 -1.00 -0.067 0.39637E+04 50 chloritoid-Mn -8.47 -10.25 -1.78 -0.118 0.70246E+04 52 coesite -0.71 -0.98 -0.27 -0.091 0.10833E+04 53 cordierite-H -22.29 -22.67 -0.38 -0.014 0.15111E+04 54 cordierite-Fe -24.64 -26.22 -1.57 -0.054 0.62263E+04 55 cordierite-Mn -20.24 -23.44 -3.20 -0.110 0.12667E+05 56 corundum -11.20 -11.53 -0.34 -0.031 0.13276E+04 58 cristobalite -0.93 -0.98 -0.05 -0.018 0.21731E+03 59 cummingtonite 13.49 10.70 -2.80 -0.076 0.11066E+05 61 cymrite-K -2.84 -5.09 -2.25 -0.187 0.88904E+04 63 diaspore -5.10 -5.77 -0.67 -0.112 0.26471E+04 65 diopside 5.19 3.71 -1.48 -0.148 0.58480E+04 66 hedenbergite 3.83 1.94 -1.89 -0.189 0.74830E+04 68 eastonite -9.12 -10.34 -1.22 -0.047 0.48404E+04 69 enstatite 4.34 3.34 -1.00 -0.100 0.39495E+04 70 clinoenstatite-HiP 4.81 3.34 -1.48 -0.148 0.58330E+04 71 clinoenstatite 4.32 3.34 -0.99 -0.099 0.39028E+04 72 protoenstatite 4.47 3.34 -1.13 -0.113 0.44646E+04 73 epidote -6.34 -8.42 -2.08 -0.101 0.82110E+04 74 clinozoisite -11.93 -14.20 -2.27 -0.103 0.89827E+04 75 epidote-Fe 0.90 -2.64 -3.54 -0.184 0.13994E+05 76 fayalite 1.81 0.77 -1.04 -0.149 0.41122E+04 77 ferrosilite 0.91 -0.21 -1.12 -0.112 0.44457E+04 78 forsterite 5.64 4.32 -1.32 -0.189 0.52366E+04 79 gedrite -13.87 -15.71 -1.84 -0.050 0.72651E+04 81 gibbsite -3.52 -5.77 -2.24 -0.321 0.88764E+04 82 glaucophane 0.16 -3.18 -3.33 -0.090 0.13180E+05 83 glaucophane-Fe -3.71 -8.50 -4.79 -0.130 0.18959E+05 84 goethite 0.89 0.01 -0.88 -0.190 0.34706E+04 86 greenalite 3.99 0.66 -3.33 -0.277 0.13162E+05 87 grunerite 1.88 -1.73 -3.61 -0.098 0.14275E+05 88 halite -0.44 -2.54 -2.10 -1.048 0.82852E+04 89 hematite 0.29 0.03 -0.26 -0.031 0.10263E+04 90 heulandite -12.74 -15.39 -2.64 -0.120 0.10457E+05 91 hercynite -9.83 -10.66 -0.83 -0.056 0.32959E+04 94 jadeite -1.97 -3.60 -1.63 -0.163 0.64278E+04 96 kalsilite -1.49 -3.12 -1.64 -0.234 0.64749E+04 97 kaolinite -11.07 -13.50 -2.42 -0.220 0.95837E+04 98 kyanite -12.20 -12.51 -0.32 -0.032 0.12568E+04 100 laumontite -9.20 -12.44 -3.24 -0.216 0.12813E+05 101 lawsonite -7.33 -10.48 -3.14 -0.210 0.12434E+05 102 leucite -3.11 -4.10 -0.99 -0.099 0.39321E+04 104 lizardite 8.82 5.98 -2.84 -0.236 0.11213E+05 105 magnesite -5.09 -7.85 -2.76 -0.921 0.10930E+05 106 magnetite 1.15 0.90 -0.25 -0.021 0.10008E+04 107 minnesotaite 0.79 -1.30 -2.09 -0.123 0.82825E+04 108 minnesotaite-Mg 6.52 4.02 -2.50 -0.147 0.98700E+04 109 magnesioferrite 4.11 2.67 -1.44 -0.117 0.56828E+04 111 manganosite 5.00 2.26 -2.74 -0.684 0.10821E+05 112 margarite -20.74 -22.01 -1.27 -0.051 0.50106E+04 115 microcline -5.00 -5.08 -0.09 -0.007 0.33719E+03 116 monticellite 8.29 4.69 -3.60 -0.514 0.14236E+05 118 mullite-Si -11.63 -12.51 -0.88 -0.088 0.34979E+04 119 muscovite -16.08 -16.62 -0.54 -0.032 0.21181E+04 120 paragonite -15.40 -16.12 -0.71 -0.042 0.28193E+04 121 nepheline -1.14 -2.62 -1.48 -0.212 0.58584E+04 122 osumilite(2) -14.54 -16.51 -1.98 -0.041 0.78100E+04 123 osumilite-Fe -31.28 -33.26 -1.98 -0.041 0.78278E+04 124 pargasite 1.59 -2.42 -4.01 -0.106 0.15862E+05 125 periclase 5.12 2.65 -2.47 -0.617 0.97600E+04 126 periclase-Fe 2.63 0.87 -1.76 -0.439 0.69400E+04 127 perovskite-Al -9.51 -11.53 -2.02 -0.183 0.79796E+04 132 phlogopite-Na 4.53 3.36 -1.17 -0.065 0.46163E+04 134 prehnite -5.35 -8.43 -3.08 -0.181 0.12190E+05 135 prehnite-Fe 0.63 -2.65 -3.28 -0.197 0.12982E+05 138 px-Mg-tschermaks -8.24 -9.86 -1.63 -0.116 0.64270E+04 139 px-Ca-tschermaks -7.20 -9.49 -2.29 -0.164 0.90551E+04 140 pyrite -20.35 -20.48 -0.13 -0.030 0.50294E+03 141 pyrrhotite -8.24 -8.94 -0.70 -0.233 0.27601E+04 142 pyrrhotiteFe0.875 -8.94 -9.26 -0.32 -0.118 0.12687E+04 143 pyrophyllite -14.43 -15.46 -1.03 -0.064 0.40695E+04 146 riebeckite 6.37 3.06 -3.31 -0.091 0.13097E+05 147 ringwoodite-Fe 2.78 0.77 -2.01 -0.288 0.79656E+04 148 ringwoodite-Mg 8.71 4.32 -4.39 -0.627 0.17367E+05 149 rhodochrosite -4.93 -8.24 -3.30 -1.100 0.13052E+05 150 rhodonite 2.44 1.28 -1.15 -0.230 0.45526E+04 151 sanidine -4.48 -5.08 -0.61 -0.047 0.24037E+04 152 sapphirine(351) -46.48 -50.70 -4.21 -0.064 0.16663E+05 153 siderite -6.84 -9.63 -2.79 -0.929 0.11020E+05 154 sillimanite -12.31 -12.51 -0.20 -0.020 0.79387E+03 156 spinel -7.73 -8.88 -1.15 -0.077 0.45522E+04 158 staurolite-Fe -103.78 -107.66 -3.87 -0.035 0.15307E+05 159 staurolite-Mg -95.67 -100.56 -4.89 -0.045 0.19317E+05 162 stilpnomelane-Fe -8.52 -13.21 -4.69 -0.140 0.18543E+05 163 stilpnomelane-Mg -2.12 -4.33 -2.22 -0.066 0.87671E+04 164 stishovite 1.88 -0.98 -2.86 -0.954 0.11319E+05 165 sudoite-Fe -20.79 -24.27 -3.48 -0.112 0.13758E+05 166 sudoite -18.67 -20.72 -2.05 -0.066 0.80907E+04 167 sulfur -10.06 -11.54 -1.48 -0.456 0.58626E+04 168 sylvite -0.35 -3.04 -2.69 -1.343 0.10622E+05 169 talc 4.82 4.02 -0.80 -0.047 0.31614E+04 170 talc-Fe 2.14 -1.30 -3.44 -0.202 0.13596E+05 171 talc-tschermaks -7.68 -9.18 -1.50 -0.088 0.59359E+04 173 tephroite 6.13 3.55 -2.58 -0.369 0.10208E+05 176 topaz-H -10.30 -12.52 -2.22 -0.202 0.87717E+04 177 tremolite 14.58 11.44 -3.13 -0.085 0.12394E+05 179 troilite-low -8.14 -8.94 -0.80 -0.265 0.31485E+04 180 tschermakite -11.96 -14.96 -3.00 -0.081 0.11876E+05 183 wadsleyite-Fe 2.63 0.77 -1.86 -0.266 0.73576E+04 184 wadsleyite-Mg 7.79 4.32 -3.47 -0.496 0.13720E+05 185 wairakite -10.94 -12.44 -1.49 -0.088 0.59023E+04 186 walstromite 4.56 2.04 -2.52 -0.504 0.99738E+04 187 wollastonite 4.17 2.04 -2.12 -0.425 0.83984E+04 188 pseudo-wollastonite 4.27 2.04 -2.23 -0.446 0.88237E+04 189 zoisite -11.99 -14.20 -2.21 -0.100 0.87349E+04 192 beidellite-Ca -15.21 -16.54 -1.32 -0.082 0.52335E+04 193 beidellite-H -15.21 -17.04 -1.83 -0.117 0.72189E+04 194 beidellite-K -14.15 -15.84 -1.69 -0.104 0.66913E+04 195 beidellite-Mg -15.53 -16.60 -1.07 -0.066 0.42411E+04 196 beidellite-Na -14.08 -15.67 -1.59 -0.097 0.62842E+04 199 chalcocite -13.10 -14.39 -1.29 -0.322 0.50977E+04 200 covellite -11.66 -12.97 -1.31 -0.499 0.51757E+04 202 montmorillonite-Ca -11.14 -12.18 -1.04 -0.065 0.41291E+04 203 montmorillonite-K -10.36 -11.48 -1.12 -0.069 0.44256E+04 204 montmorillonite-Mg -11.38 -12.24 -0.86 -0.053 0.34048E+04 205 montmorillonite-Na -10.00 -11.32 -1.32 -0.081 0.52256E+04 206 nontronite-Ca -3.50 -4.98 -1.48 -0.096 0.58329E+04 207 nontronite-H -3.51 -5.48 -1.97 -0.132 0.77868E+04 208 nontronite-K -2.44 -4.28 -1.84 -0.118 0.72827E+04 209 nontronite-Mg -3.76 -5.04 -1.28 -0.083 0.50635E+04 210 nontronite-Na -2.37 -4.12 -1.74 -0.112 0.68891E+04 215 gypsum -11.43 -13.69 -2.26 -0.564 0.89227E+04 232 alabandite -5.96 -7.55 -1.59 -0.529 0.62718E+04 234 anglesite -13.68 -16.33 -2.65 -1.324 0.10473E+05 238 boehmite -4.82 -5.77 -0.94 -0.157 0.37354E+04 242 copper,native 1.79 -1.43 -3.22 -1.121 0.12740E+05 244 ferrous-oxide 1.72 0.87 -0.85 -0.212 0.33527E+04 245 galena -9.02 -9.44 -0.41 -0.138 0.16363E+04 246 silver,native 0.57 -3.65 -4.22 -1.468 0.16694E+05 248 litharge 5.18 0.38 -4.80 -1.201 0.18995E+05 255 sphalerite -10.39 -10.53 -0.14 -0.045 0.53934E+03 256 wurtzite -9.61 -10.53 -0.92 -0.306 0.36282E+04 257 zincite 1.87 -0.72 -2.58 -0.646 0.10210E+05 258 an20ab80 -5.74 -5.76 -0.02 -0.001 0.70849E+02 259 an25ab75 -6.05 -6.05 -0.01 0.000 0.22164E+02 261 tr.625ac.25prg.125 8.85 7.49 -1.36 -0.037 0.53784E+04 Calculations done for 591.0000 Deg. C; 1811.0000 bar Temperature changed by -1.000 degrees to 590.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 24 Loop limit = 500 Temperature = 590.00 C Pressure = 1769.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5504E+02 kg liquid = 0.9915E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9952 Stoichiometric ionic strength = .3307814E+01 Osmotic coef. = 0.0000 True ionic strength = .2511741E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13189E-04 -4.8798 0.36579E-05 -5.4368 0.27734E+00 -0.5570 2 H2O 0.99524E+00 -0.0021 0.99524E+00 -0.0021 3 Cl- 0.21151E+00 -0.6747 0.54058E-01 -1.2671 0.25558E+00 -0.5925 4 SO4-- 0.16091E-03 -3.7934 0.12441E-05 -5.9052 0.77317E-02 -2.1117 5 HCO3- 0.27819E-04 -4.5557 0.76428E-05 -5.1167 0.27473E+00 -0.5611 6 HS- 0.14840E-03 -3.8286 0.38236E-04 -4.4175 0.25765E+00 -0.5890 7 H4SiO4 0.10065E+00 -0.9972 0.10065E+00 -0.9972 0.10000E+01 0.0000 8 Al+++ 0.62773E-17 -17.2022 0.86440E-22 -22.0633 0.13770E-04 -4.8611 9 Ca++ 0.23496E-05 -5.6290 0.14826E-07 -7.8290 0.63102E-02 -2.2000 10 Mg++ 0.12136E-05 -5.9159 0.63450E-08 -8.1976 0.52281E-02 -2.2817 11 Fe++ 0.18476E-07 -7.7334 0.10134E-09 -9.9942 0.54848E-02 -2.2608 12 K+ 0.55971E-01 -1.2520 0.15761E-01 -1.8024 0.28159E+00 -0.5504 13 Na+ 0.19281E+00 -0.7149 0.49911E-01 -1.3018 0.25886E+00 -0.5869 14 Mn++ 0.46607E-06 -6.3315 0.26472E-08 -8.5772 0.56797E-02 -2.2457 15 Zn++ 0.49862E-09 -9.3022 0.27349E-11 -11.5631 0.54848E-02 -2.2608 16 Cu+ 0.71406E-07 -7.1463 0.18436E-07 -7.7343 0.25819E+00 -0.5881 17 Pb++ 0.46343E-08 -8.3340 0.32583E-10 -10.4870 0.70308E-02 -2.1530 18 Ag+ 0.41123E-09 -9.3859 0.11406E-09 -9.9429 0.27736E+00 -0.5569 19 Ba++ 0.24744E-06 -6.6065 0.18620E-08 -8.7300 0.75252E-02 -2.1235 20 HPO4-- 0.12995E-08 -8.8862 0.10095E-10 -10.9959 0.77686E-02 -2.1097 21 HSiO3- 0.22283E-05 -5.6520 0.56951E-06 -6.2445 0.25558E+00 -0.5925 22 Ca(HSiO3)+ 0.13163E-07 -7.8807 0.37378E-08 -8.4274 0.28397E+00 -0.5467 23 Mg(HSiO3)+ 0.14383E-08 -8.8422 0.40844E-09 -9.3889 0.28397E+00 -0.5467 24 NaHSiO3,aq 0.13803E-05 -5.8600 0.13803E-05 -5.8600 0.10000E+01 0.0000 28 AgCl,aq 0.70963E-07 -7.1490 0.70963E-07 -7.1490 0.10000E+01 0.0000 29 AgCl2- 0.49853E-05 -5.3023 0.12741E-05 -5.8948 0.25558E+00 -0.5925 30 AgCl3-2 0.24818E-05 -5.6052 0.17832E-07 -7.7488 0.71851E-02 -2.1436 31 AgCl4-3 0.12325E-05 -5.9092 0.14650E-10 -10.8342 0.11887E-04 -4.9249 34 Ag(HS),aq 0.59295E-09 -9.2270 0.59295E-09 -9.2270 0.10000E+01 0.0000 35 Ag(HS)2- 0.35955E-08 -8.4442 0.91893E-09 -9.0367 0.25558E+00 -0.5925 36 AlO+ 0.12241E-10 -10.9122 0.34761E-11 -11.4589 0.28397E+00 -0.5467 38 HAlO2,aq 0.47534E-08 -8.3230 0.47534E-08 -8.3230 0.10000E+01 0.0000 39 AlO2- 0.21079E-04 -4.6761 0.47276E-05 -5.3254 0.22428E+00 -0.6492 41 Ba(HCO3)+ 0.12870E-05 -5.8904 0.37960E-06 -6.4207 0.29494E+00 -0.5303 42 BaCl+ 0.45004E-04 -4.3468 0.12780E-04 -4.8935 0.28397E+00 -0.5467 43 CH4,aq 0.20238E-08 -8.6938 0.24599E-08 -8.6091 0.12155E+01 0.0848 48 CO,aq 0.83592E-03 -3.0778 0.83592E-03 -3.0778 0.10000E+01 0.0000 49 CO2,aq 0.26779E+01 0.4278 0.32550E+01 0.5125 0.12155E+01 0.0848 50 CO3-2 0.51706E-10 -10.2865 0.37151E-12 -12.4300 0.71851E-02 -2.1436 51 CaCO3,aq 0.16177E-10 -10.7911 0.16177E-10 -10.7911 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.64917E-06 -6.1876 0.18435E-06 -6.7344 0.28397E+00 -0.5467 53 CaCl+ 0.23576E-03 -3.6275 0.66950E-04 -4.1743 0.28397E+00 -0.5467 54 CaCl2,aq 0.13119E-03 -3.8821 0.13119E-03 -3.8821 0.10000E+01 0.0000 55 CaOH+ 0.35498E-06 -6.4498 0.10080E-06 -6.9965 0.28397E+00 -0.5467 56 CaSO4,aq 0.10821E-06 -6.9657 0.10821E-06 -6.9657 0.10000E+01 0.0000 57 HCl,aq 0.11436E-02 -2.9417 0.11436E-02 -2.9417 0.10000E+01 0.0000 66 CuCl,aq 0.48595E-04 -4.3134 0.48595E-04 -4.3134 0.10000E+01 0.0000 67 CuCl2- 0.19371E-03 -3.7128 0.49509E-04 -4.3053 0.25558E+00 -0.5925 68 CuCl3-2 0.50384E-05 -5.2977 0.36201E-07 -7.4413 0.71851E-02 -2.1436 74 FeCl+ 0.57829E-06 -6.2379 0.16422E-06 -6.7846 0.28397E+00 -0.5467 75 FeCl2,aq 0.83342E-02 -2.0791 0.83342E-02 -2.0791 0.10000E+01 0.0000 77 FeO,aq 0.71783E-07 -7.1440 0.71783E-07 -7.1440 0.10000E+01 0.0000 78 FeOH+ 0.42145E-07 -7.3753 0.11968E-07 -7.9220 0.28397E+00 -0.5467 79 HFeO2- 0.10203E-07 -7.9913 0.26077E-08 -8.5837 0.25558E+00 -0.5925 82 FeO2- 0.62412E-08 -8.2047 0.15951E-08 -8.7972 0.25558E+00 -0.5925 83 HFeO2,aq 0.20371E-09 -9.6910 0.20371E-09 -9.6910 0.10000E+01 0.0000 84 H2,aq 0.45056E-02 -2.3462 0.54766E-02 -2.2615 0.12155E+01 0.0848 85 KCl,aq 0.54552E-01 -1.2632 0.54552E-01 -1.2632 0.10000E+01 0.0000 86 KHSO4,aq 0.12494E-01 -1.9033 0.12494E-01 -1.9033 0.10000E+01 0.0000 87 KOH,aq 0.90218E-06 -6.0447 0.90218E-06 -6.0447 0.10000E+01 0.0000 88 KSO4- 0.34625E-02 -2.4606 0.88493E-03 -3.0531 0.25558E+00 -0.5925 90 Mg(HCO3)+ 0.11824E-06 -6.9272 0.33578E-07 -7.4739 0.28397E+00 -0.5467 91 MgCl+ 0.18900E-04 -4.7235 0.53670E-05 -5.2703 0.28397E+00 -0.5467 92 MgOH+ 0.61990E-06 -6.2077 0.17603E-06 -6.7544 0.28397E+00 -0.5467 94 MnO,aq 0.27983E-07 -7.5531 0.27983E-07 -7.5531 0.10000E+01 0.0000 95 MnOH+ 0.13811E-06 -6.8598 0.39219E-07 -7.4065 0.28397E+00 -0.5467 97 HMnO2- 0.18808E-10 -10.7257 0.48069E-11 -11.3181 0.25558E+00 -0.5925 100 MnCl+ 0.11586E-02 -2.9360 0.32902E-03 -3.4828 0.28397E+00 -0.5467 101 MnSO4,aq 0.24643E-07 -7.6083 0.24643E-07 -7.6083 0.10000E+01 0.0000 102 NaCl,aq 0.36615E+00 -0.4363 0.36615E+00 -0.4363 0.10000E+01 0.0000 103 NaOH,aq 0.13178E-05 -5.8802 0.13178E-05 -5.8802 0.10000E+01 0.0000 105 OH- 0.94368E-05 -5.0252 0.21165E-05 -5.6744 0.22428E+00 -0.6492 110 HPO3-2 0.22727E-10 -10.6435 0.16330E-12 -12.7870 0.71851E-02 -2.1436 111 H3PO3,aq 0.17988E-09 -9.7450 0.17988E-09 -9.7450 0.10000E+01 0.0000 112 H2PO3- 0.78821E-08 -8.1034 0.20145E-08 -8.6958 0.25558E+00 -0.5925 113 H3PO4,aq 0.12228E-05 -5.9126 0.12228E-05 -5.9126 0.10000E+01 0.0000 114 H2PO4- 0.27419E-05 -5.5619 0.73577E-06 -6.1333 0.26834E+00 -0.5713 116 H4P2O7,aq 0.12268E-09 -9.9112 0.12268E-09 -9.9112 0.10000E+01 0.0000 117 H3P2O7- 0.27257E-08 -8.5645 0.69664E-09 -9.1570 0.25558E+00 -0.5925 118 H2P2O7-2 0.74516E-06 -6.1278 0.53540E-08 -8.2713 0.71851E-02 -2.1436 119 HP2O7-3 0.21967E-07 -7.6582 0.26112E-12 -12.5832 0.11887E-04 -4.9249 121 PbCl+ 0.27899E-05 -5.5544 0.79226E-06 -6.1011 0.28397E+00 -0.5467 122 PbCl2,aq 0.93140E-04 -4.0309 0.93140E-04 -4.0309 0.10000E+01 0.0000 123 PbCl3- 0.11499E-03 -3.9393 0.29388E-04 -4.5318 0.25558E+00 -0.5925 124 PbCl4-2 0.29503E-04 -4.5301 0.21198E-06 -6.6737 0.71851E-02 -2.1436 125 PbO,aq 0.34465E-08 -8.4626 0.34465E-08 -8.4626 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.94473E-04 -4.0247 0.94473E-04 -4.0247 0.10000E+01 0.0000 128 Pb(HS)3- 0.81726E-05 -5.0876 0.20887E-05 -5.6801 0.25558E+00 -0.5925 129 H2S,aq 0.10440E+01 0.0187 0.12690E+01 0.1035 0.12155E+01 0.0848 130 S2-2 0.14604E-07 -7.8355 0.10493E-09 -9.9791 0.71851E-02 -2.1436 131 S3-2 0.15660E-08 -8.8052 0.11252E-10 -10.9488 0.71851E-02 -2.1436 132 S3- 0.22138E-01 -1.6549 0.56580E-02 -2.2473 0.25558E+00 -0.5925 133 S4-2 0.13941E-09 -9.8557 0.10017E-11 -11.9993 0.71851E-02 -2.1436 134 S5-2 0.10458E-10 -10.9806 0.75139E-13 -13.1241 0.71851E-02 -2.1436 135 SO2,aq 0.28344E+00 -0.5475 0.28344E+00 -0.5475 0.10000E+01 0.0000 136 SO3-2 0.58352E-09 -9.2339 0.64586E-11 -11.1899 0.11068E-01 -1.9559 137 HSO3- 0.44442E-03 -3.3522 0.11358E-03 -3.9447 0.25558E+00 -0.5925 138 HSO4- 0.12263E-01 -1.9114 0.35689E-02 -2.4475 0.29104E+00 -0.5360 140 S2O3-2 0.49948E-06 -6.3015 0.35888E-08 -8.4450 0.71851E-02 -2.1436 141 HS2O3- 0.74329E-06 -6.1288 0.18997E-06 -6.7213 0.25558E+00 -0.5925 142 H2S2O3,aq 0.24407E-07 -7.6125 0.24407E-07 -7.6125 0.10000E+01 0.0000 150 S4O6-2 0.68687E-09 -9.1631 0.49352E-11 -11.3067 0.71851E-02 -2.1436 152 ZnCl+ 0.69298E-03 -3.1593 0.19679E-03 -3.7060 0.28397E+00 -0.5467 153 ZnCl2,aq 0.14127E-02 -2.8500 0.14127E-02 -2.8500 0.10000E+01 0.0000 154 ZnCl3- 0.21001E-03 -3.6778 0.53674E-04 -4.2702 0.25558E+00 -0.5925 155 ZnO,aq 0.35062E-07 -7.4552 0.35062E-07 -7.4552 0.10000E+01 0.0000 156 ZnOH+ 0.32632E-05 -5.4864 0.92664E-06 -6.0331 0.28397E+00 -0.5467 158 HZnO2- 0.31576E-09 -9.5006 0.80701E-10 -10.0931 0.25558E+00 -0.5925 Charge balance for all species = 0.2552E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1318899E-04 0.4301711E+01 0.3530518E+04 0.0000 2 H2O 0.1000000E+01 0.5249528E+02 0.7700595E+06 0.0000 3 Cl- 0.2115115E+00 0.6570179E+00 0.1896674E+05 4.1696 4 SO4-- 0.1609057E-03 0.2537974E+00 0.1985179E+05 4.9684 5 HCO3- 0.2781935E-04 0.2678771E+01 0.1330915E+06 0.3200 6 HS- 0.1484012E-03 0.1169266E+01 0.3148737E+05 1.0192 7 H4SiO4 0.1006517E+00 0.1006553E+00 0.7877571E+04 -0.9972 8 Al+++ 0.6277319E-17 0.2108404E-04 0.4632147E+00 -5.7530 9 Ca++ 0.2349562E-05 0.3704222E-03 0.1208831E+02 3.0446 10 Mg++ 0.1213637E-05 0.2085303E-04 0.4128121E+00 2.6760 11 Fe++ 0.1847559E-07 0.8334881E-02 0.3790197E+03 0.8793 12 K+ 0.5597100E-01 0.1264799E+00 0.4027014E+04 3.6344 13 Na+ 0.1928141E+00 0.5589645E+00 0.1046362E+05 4.1350 14 Mn++ 0.4660735E-06 0.1159306E-02 0.5186010E+02 2.2963 15 Zn++ 0.4986224E-09 0.2318949E-02 0.1234333E+03 -0.6895 16 Cu+ 0.7140583E-07 0.2474182E-03 0.1280092E+02 -2.2976 17 Pb++ 0.4634309E-08 0.3430744E-03 0.5787882E+02 0.3865 18 Ag+ 0.4112263E-09 0.8775063E-05 0.7707499E+00 -4.5061 19 Ba++ 0.2474412E-06 0.4653836E-04 0.5204400E+01 2.1435 20 HPO4-- 0.1299509E-08 0.5514038E-05 0.4309318E+00 -0.1223 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265326E+01 -.2964200E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5205126E+02 -.8648358E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2516508E+00 0.7202413E-04 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159376E+01 0.7679026E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.9980397E-01 0.4379035E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2090570E-04 0.6736338E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3672891E-03 0.1606208E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8264383E-02 0.5023713E-03 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542366E+00 0.3627259E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.2453255E-03 0.1542843E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.4614473E-04 0.9227723E-05 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.5467399E-05 0.3100101E-05 0.0000000E+00 Chg. balance for solid moles: 0.1525E-19 Mass of aqueous solution: 0.121772E+04 g Temperature = 590.00 C Pressure = 1769.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1033E-05 -5.986 0.5191E-03 -3.285 0.1886E-01 0.1649E-03 quartz 0.4239E-01 -1.373 2.547 0.406 92.53 0.9618 bornite -.8702E-04 1.000 -.4367E-01 1.000 -1.587 -.8591E-02 barite 0.9228E-05 -5.035 0.2154E-02 -2.667 0.7825E-01 0.4807E-03 chalcopyrite 0.5894E-03 -3.230 0.1082 -0.966 3.929 0.2525E-01 an30ab70 0.5182E-03 -3.286 0.1384 -0.859 5.027 0.5196E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.752389 g Volume = 1.031066 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 30 apatite-OH -50.39 -50.39 0.00 0.000 0.00000E+00 144 quartz -0.99 -0.99 0.00 0.000 0.00000E+00 237 barite -14.64 -14.64 0.00 0.000 -0.70160E-11 240 chalcopyrite -21.99 -21.99 0.00 0.000 -0.14032E-10 260 an30ab70 -6.36 -6.36 0.00 0.000 0.10524E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.291 0.11503E+04 2.956 2 CO2,gas -9.12 -10.55 -1.43 -0.478 0.56653E+04 1.813 3 CH4,gas 6.92 -3.63 -10.55 -2.637 0.41655E+05 -7.299 4 H2,gas 5.77 1.73 -4.04 -2.311 0.15970E+05 -0.796 5 H2S,gas -7.58 -9.85 -2.27 -1.135 0.89673E+04 0.977 6 CO,gas -3.18 -8.82 -5.64 -1.734 0.22263E+05 -2.389 7 SO3,gas -6.52 -16.78 -10.26 -2.565 0.40520E+05 -7.011 8 O2,gas 16.49 -3.46 -19.95 -13.300 0.78797E+05 -16.703 9 HCl,gas -5.65 -6.70 -1.06 -0.528 0.41736E+04 -1.057 10 acmite 3.86 2.16 -1.70 -0.177 0.67238E+04 12 akimotoite 5.82 1.68 -4.14 -0.828 0.16347E+05 13 akimotoite-Fe 3.80 -0.12 -3.91 -0.783 0.15457E+05 14 albite-high -4.46 -4.60 -0.14 -0.011 0.56661E+03 15 albite -4.43 -4.60 -0.18 -0.013 0.69137E+03 16 almandine -10.40 -11.86 -1.46 -0.073 0.57821E+04 17 pyrope -4.01 -6.47 -2.46 -0.123 0.97159E+04 18 analcite -2.65 -3.61 -0.96 -0.106 0.37780E+04 19 andalusite -12.31 -12.51 -0.20 -0.020 0.77219E+03 20 andradite 11.13 6.17 -4.96 -0.257 0.19577E+05 21 grossular -0.53 -5.36 -4.83 -0.242 0.19081E+05 22 anhydrite -13.62 -13.73 -0.11 -0.057 0.44705E+03 24 annite -0.75 -2.47 -1.73 -0.096 0.68171E+04 25 phlogopite 3.67 2.92 -0.76 -0.042 0.29873E+04 27 anorthite -9.98 -10.46 -0.48 -0.037 0.18764E+04 28 anthophyllite 13.40 10.77 -2.63 -0.071 0.10397E+05 29 anthophyllite-Fe 1.30 -1.81 -3.11 -0.084 0.12275E+05 31 apatite-OH-zs -48.29 -50.39 -2.09 -0.161 0.82739E+04 32 apatite-Cl-zs -54.05 -57.09 -3.04 -0.253 0.12007E+05 33 aragonite -4.08 -7.51 -3.43 -1.144 0.13552E+05 34 brucite 4.94 2.67 -2.27 -0.454 0.89620E+04 35 calcite -4.17 -7.51 -3.34 -1.113 0.13192E+05 36 carnegieite-low -0.84 -2.62 -1.77 -0.253 0.69984E+04 37 carnegieite-high -0.78 -2.62 -1.84 -0.262 0.72515E+04 38 carpholite-Mg -9.08 -10.83 -1.75 -0.117 0.69103E+04 39 carpholite-Fe -10.38 -12.63 -2.25 -0.150 0.88702E+04 40 celadonite -1.25 -3.42 -2.17 -0.128 0.85714E+04 41 celadonite-Fe -2.61 -5.22 -2.61 -0.154 0.10309E+05 42 chrysotile 8.63 6.03 -2.60 -0.216 0.10255E+05 44 clinochlore 0.40 -1.13 -1.53 -0.048 0.60355E+04 45 daphnite -6.38 -10.11 -3.73 -0.117 0.14735E+05 48 chloritoid-Mg -8.75 -9.83 -1.08 -0.072 0.42707E+04 49 chloritoid-Fe -10.60 -11.63 -1.03 -0.069 0.40583E+04 50 chloritoid-Mn -8.44 -10.21 -1.77 -0.118 0.70094E+04 52 coesite -0.72 -0.99 -0.27 -0.092 0.10852E+04 53 cordierite-H -22.25 -22.64 -0.39 -0.014 0.15362E+04 54 cordierite-Fe -24.62 -26.23 -1.61 -0.056 0.63758E+04 55 cordierite-Mn -20.21 -23.40 -3.19 -0.110 0.12596E+05 56 corundum -11.16 -11.51 -0.36 -0.032 0.14105E+04 58 cristobalite -0.94 -0.99 -0.05 -0.018 0.21405E+03 59 cummingtonite 13.46 10.77 -2.69 -0.073 0.10617E+05 61 cymrite-K -2.85 -5.10 -2.25 -0.188 0.89008E+04 63 diaspore -5.08 -5.76 -0.68 -0.113 0.26895E+04 65 diopside 5.18 3.73 -1.45 -0.145 0.57140E+04 66 hedenbergite 3.81 1.93 -1.88 -0.188 0.74254E+04 68 eastonite -9.06 -10.28 -1.21 -0.047 0.47853E+04 69 enstatite 4.33 3.36 -0.97 -0.097 0.38223E+04 70 clinoenstatite-HiP 4.81 3.36 -1.45 -0.145 0.57075E+04 71 clinoenstatite 4.32 3.36 -0.96 -0.096 0.37749E+04 72 protoenstatite 4.46 3.36 -1.10 -0.110 0.43367E+04 73 epidote -6.33 -8.40 -2.07 -0.100 0.81629E+04 74 clinozoisite -11.89 -14.16 -2.27 -0.103 0.89690E+04 75 epidote-Fe 0.89 -2.63 -3.52 -0.183 0.13908E+05 76 fayalite 1.81 0.76 -1.05 -0.150 0.41334E+04 77 ferrosilite 0.90 -0.23 -1.13 -0.113 0.44697E+04 78 forsterite 5.65 4.35 -1.29 -0.185 0.51056E+04 79 gedrite -13.82 -15.62 -1.80 -0.049 0.71073E+04 81 gibbsite -3.50 -5.76 -2.26 -0.323 0.89256E+04 82 glaucophane 0.12 -3.17 -3.29 -0.089 0.12995E+05 83 glaucophane-Fe -3.75 -8.56 -4.81 -0.130 0.19001E+05 84 goethite 0.89 0.01 -0.88 -0.191 0.34804E+04 86 greenalite 3.98 0.64 -3.34 -0.278 0.13190E+05 87 grunerite 1.83 -1.81 -3.63 -0.098 0.14350E+05 88 halite -0.48 -2.57 -2.09 -1.046 0.82615E+04 89 hematite 0.29 0.02 -0.26 -0.032 0.10392E+04 90 heulandite -12.77 -15.43 -2.66 -0.121 0.10506E+05 91 hercynite -9.78 -10.63 -0.86 -0.057 0.33879E+04 94 jadeite -1.98 -3.61 -1.63 -0.163 0.64352E+04 96 kalsilite -1.48 -3.12 -1.64 -0.234 0.64692E+04 97 kaolinite -11.06 -13.50 -2.45 -0.222 0.96630E+04 98 kyanite -12.17 -12.51 -0.34 -0.034 0.13421E+04 100 laumontite -9.20 -12.45 -3.25 -0.217 0.12842E+05 101 lawsonite -7.30 -10.46 -3.16 -0.210 0.12461E+05 102 leucite -3.12 -4.11 -0.99 -0.099 0.39246E+04 104 lizardite 8.82 6.03 -2.79 -0.232 0.11015E+05 105 magnesite -5.12 -7.88 -2.76 -0.920 0.10905E+05 106 magnetite 1.16 0.90 -0.26 -0.021 0.10227E+04 107 minnesotaite 0.76 -1.34 -2.10 -0.124 0.83069E+04 108 minnesotaite-Mg 6.50 4.05 -2.45 -0.144 0.96672E+04 109 magnesioferrite 4.12 2.70 -1.42 -0.116 0.56282E+04 111 manganosite 5.01 2.29 -2.71 -0.679 0.10722E+05 112 margarite -20.68 -21.97 -1.29 -0.052 0.51047E+04 115 microcline -5.02 -5.10 -0.08 -0.006 0.32694E+03 116 monticellite 8.29 4.72 -3.57 -0.510 0.14095E+05 118 mullite-Si -11.60 -12.51 -0.91 -0.091 0.35816E+04 119 muscovite -16.06 -16.62 -0.56 -0.033 0.22017E+04 120 paragonite -15.38 -16.12 -0.74 -0.043 0.29089E+04 121 nepheline -1.13 -2.62 -1.48 -0.212 0.58556E+04 122 osumilite(2) -14.60 -16.54 -1.94 -0.040 0.76662E+04 123 osumilite-Fe -31.30 -33.32 -2.02 -0.042 0.79794E+04 124 pargasite 1.62 -2.31 -3.94 -0.104 0.15557E+05 125 periclase 5.13 2.67 -2.45 -0.614 0.96934E+04 126 periclase-Fe 2.64 0.88 -1.76 -0.440 0.69510E+04 127 perovskite-Al -9.47 -11.51 -2.04 -0.186 0.80630E+04 132 phlogopite-Na 4.54 3.42 -1.12 -0.062 0.44214E+04 134 prehnite -5.34 -8.41 -3.07 -0.181 0.12130E+05 135 prehnite-Fe 0.62 -2.64 -3.26 -0.196 0.12884E+05 138 px-Mg-tschermaks -8.20 -9.83 -1.63 -0.117 0.64458E+04 139 px-Ca-tschermaks -7.17 -9.46 -2.30 -0.164 0.90660E+04 140 pyrite -20.43 -20.56 -0.13 -0.030 0.50301E+03 141 pyrrhotite -8.27 -8.97 -0.70 -0.233 0.27660E+04 142 pyrrhotiteFe0.875 -8.98 -9.30 -0.32 -0.119 0.12740E+04 143 pyrophyllite -14.43 -15.49 -1.05 -0.066 0.41564E+04 146 riebeckite 6.29 2.98 -3.31 -0.091 0.13072E+05 147 ringwoodite-Fe 2.78 0.76 -2.02 -0.289 0.79874E+04 148 ringwoodite-Mg 8.72 4.35 -4.36 -0.623 0.17238E+05 149 rhodochrosite -4.97 -8.26 -3.29 -1.096 0.12991E+05 150 rhodonite 2.43 1.30 -1.13 -0.226 0.44545E+04 151 sanidine -4.50 -5.10 -0.61 -0.047 0.23939E+04 152 sapphirine(351) -46.26 -50.53 -4.27 -0.065 0.16878E+05 153 siderite -6.87 -9.67 -2.80 -0.934 0.11069E+05 154 sillimanite -12.28 -12.51 -0.22 -0.022 0.87610E+03 156 spinel -7.68 -8.84 -1.16 -0.077 0.45666E+04 158 staurolite-Fe -103.47 -107.55 -4.08 -0.037 0.16115E+05 162 stilpnomelane-Fe -8.54 -13.27 -4.73 -0.141 0.18680E+05 163 stilpnomelane-Mg -2.12 -4.28 -2.16 -0.065 0.85393E+04 164 stishovite 1.87 -0.99 -2.87 -0.956 0.11324E+05 165 sudoite-Fe -20.72 -24.26 -3.54 -0.114 0.13976E+05 166 sudoite -18.60 -20.66 -2.06 -0.067 0.81545E+04 167 sulfur -10.10 -11.58 -1.48 -0.456 0.58593E+04 168 sylvite -0.39 -3.07 -2.68 -1.341 0.10590E+05 169 talc 4.80 4.05 -0.75 -0.044 0.29638E+04 170 talc-Fe 2.11 -1.34 -3.45 -0.203 0.13626E+05 171 talc-tschermaks -7.66 -9.15 -1.49 -0.088 0.58837E+04 173 tephroite 6.13 3.60 -2.53 -0.362 0.10008E+05 176 topaz-H -10.26 -12.51 -2.24 -0.204 0.88605E+04 177 tremolite 14.53 11.51 -3.02 -0.082 0.11926E+05 179 troilite-low -8.18 -8.97 -0.80 -0.266 0.31531E+04 180 tschermakite -11.92 -14.88 -2.96 -0.080 0.11697E+05 183 wadsleyite-Fe 2.63 0.76 -1.87 -0.267 0.73806E+04 184 wadsleyite-Mg 7.80 4.35 -3.44 -0.492 0.13591E+05 185 wairakite -10.95 -12.45 -1.49 -0.088 0.59034E+04 186 walstromite 4.56 2.05 -2.51 -0.501 0.99021E+04 187 wollastonite 4.16 2.05 -2.11 -0.422 0.83239E+04 188 pseudo-wollastonite 4.26 2.05 -2.22 -0.443 0.87500E+04 189 zoisite -11.95 -14.16 -2.21 -0.100 0.87233E+04 192 beidellite-Ca -15.21 -16.56 -1.35 -0.083 0.53205E+04 193 beidellite-H -15.21 -17.06 -1.85 -0.118 0.73175E+04 194 beidellite-K -14.14 -15.86 -1.72 -0.105 0.67752E+04 195 beidellite-Mg -15.52 -16.62 -1.10 -0.068 0.43346E+04 196 beidellite-Na -14.08 -15.69 -1.61 -0.099 0.63700E+04 197 bornite -50.89 -50.89 0.00 0.000 0.00000E+00 199 chalcocite -13.16 -14.45 -1.29 -0.323 0.50954E+04 200 covellite -11.71 -13.02 -1.31 -0.499 0.51688E+04 202 montmorillonite-Ca -11.15 -12.20 -1.05 -0.065 0.41661E+04 203 montmorillonite-K -10.38 -11.51 -1.13 -0.069 0.44627E+04 204 montmorillonite-Mg -11.39 -12.26 -0.87 -0.054 0.34418E+04 205 montmorillonite-Na -10.01 -11.34 -1.33 -0.082 0.52585E+04 206 nontronite-Ca -3.54 -5.02 -1.48 -0.096 0.58542E+04 207 nontronite-H -3.54 -5.52 -1.98 -0.133 0.78197E+04 208 nontronite-K -2.48 -4.32 -1.85 -0.119 0.73010E+04 209 nontronite-Mg -3.79 -5.08 -1.29 -0.084 0.50864E+04 210 nontronite-Na -2.41 -4.16 -1.75 -0.112 0.69095E+04 215 gypsum -11.49 -13.74 -2.24 -0.561 0.88662E+04 232 alabandite -6.00 -7.56 -1.56 -0.521 0.61688E+04 234 anglesite -13.75 -16.39 -2.64 -1.320 0.10424E+05 238 boehmite -4.80 -5.76 -0.96 -0.159 0.37784E+04 242 copper,native 1.79 -1.43 -3.22 -1.121 0.12735E+05 244 ferrous-oxide 1.73 0.88 -0.85 -0.213 0.33648E+04 245 galena -9.07 -9.47 -0.40 -0.133 0.15783E+04 246 silver,native 0.57 -3.64 -4.21 -1.464 0.16626E+05 248 litharge 5.18 0.38 -4.80 -1.199 0.18939E+05 255 sphalerite -10.43 -10.54 -0.11 -0.038 0.44604E+03 256 wurtzite -9.65 -10.54 -0.90 -0.298 0.35351E+04 257 zincite 1.87 -0.69 -2.56 -0.641 0.10123E+05 258 an20ab80 -5.75 -5.77 -0.02 -0.001 0.70446E+02 259 an25ab75 -6.06 -6.06 -0.01 0.000 0.22242E+02 261 tr.625ac.25prg.125 8.81 7.53 -1.28 -0.034 0.50370E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 20 Loop limit = 500 Temperature = 590.00 C Pressure = 1769.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5504E+02 kg liquid = 0.9915E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9952 Stoichiometric ionic strength = .3308834E+01 Osmotic coef. = 0.0000 True ionic strength = .2513575E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13036E-04 -4.8849 0.36143E-05 -5.4420 0.27726E+00 -0.5571 2 H2O 0.99523E+00 -0.0021 0.99523E+00 -0.0021 3 Cl- 0.21126E+00 -0.6752 0.53978E-01 -1.2678 0.25550E+00 -0.5926 4 SO4-- 0.16457E-03 -3.7836 0.12709E-05 -5.8959 0.77227E-02 -2.1122 5 HCO3- 0.28163E-04 -4.5503 0.77353E-05 -5.1115 0.27466E+00 -0.5612 6 HS- 0.15024E-03 -3.8232 0.38699E-04 -4.4123 0.25758E+00 -0.5891 7 H4SiO4 0.10065E+00 -0.9972 0.10065E+00 -0.9972 0.10000E+01 0.0000 8 Al+++ 0.59964E-17 -17.2221 0.82342E-22 -22.0844 0.13732E-04 -4.8623 9 Ca++ 0.23544E-05 -5.6281 0.14838E-07 -7.8286 0.63022E-02 -2.2005 10 Mg++ 0.12160E-05 -5.9151 0.63488E-08 -8.1973 0.52210E-02 -2.2822 11 Fe++ 0.19294E-07 -7.7146 0.10568E-09 -9.9760 0.54775E-02 -2.2614 12 K+ 0.55929E-01 -1.2524 0.15745E-01 -1.8029 0.28152E+00 -0.5505 13 Na+ 0.19304E+00 -0.7144 0.49954E-01 -1.3014 0.25878E+00 -0.5871 14 Mn++ 0.46726E-06 -6.3304 0.26504E-08 -8.5767 0.56723E-02 -2.2462 15 Zn++ 0.50054E-09 -9.3006 0.27417E-11 -11.5620 0.54775E-02 -2.2614 16 Cu+ 0.66086E-07 -7.1799 0.17057E-07 -7.7681 0.25811E+00 -0.5882 17 Pb++ 0.46168E-08 -8.3357 0.32420E-10 -10.4892 0.70223E-02 -2.1535 18 Ag+ 0.41250E-09 -9.3846 0.11438E-09 -9.9416 0.27729E+00 -0.5571 19 Ba++ 0.24249E-06 -6.6153 0.18227E-08 -8.7393 0.75164E-02 -2.1240 20 HPO4-- 0.12787E-08 -8.8932 0.99219E-11 -11.0034 0.77596E-02 -2.1102 21 HSiO3- 0.22559E-05 -5.6467 0.57637E-06 -6.2393 0.25550E+00 -0.5926 22 Ca(HSiO3)+ 0.13335E-07 -7.8750 0.37859E-08 -8.4218 0.28390E+00 -0.5468 23 Mg(HSiO3)+ 0.14569E-08 -8.8366 0.41361E-09 -9.3834 0.28390E+00 -0.5468 24 NaHSiO3,aq 0.13982E-05 -5.8544 0.13982E-05 -5.8544 0.10000E+01 0.0000 28 AgCl,aq 0.71060E-07 -7.1484 0.71060E-07 -7.1484 0.10000E+01 0.0000 29 AgCl2- 0.49862E-05 -5.3022 0.12740E-05 -5.8948 0.25550E+00 -0.5926 30 AgCl3-2 0.24808E-05 -5.6054 0.17804E-07 -7.7495 0.71765E-02 -2.1441 31 AgCl4-3 0.12323E-05 -5.9093 0.14606E-10 -10.8355 0.11853E-04 -4.9262 34 Ag(HS),aq 0.60183E-09 -9.2205 0.60183E-09 -9.2205 0.10000E+01 0.0000 35 Ag(HS)2- 0.36946E-08 -8.4324 0.94398E-09 -9.0250 0.25550E+00 -0.5926 36 AlO+ 0.11946E-10 -10.9228 0.33916E-11 -11.4696 0.28390E+00 -0.5468 38 HAlO2,aq 0.46938E-08 -8.3285 0.46938E-08 -8.3285 0.10000E+01 0.0000 39 AlO2- 0.21073E-04 -4.6763 0.47245E-05 -5.3256 0.22419E+00 -0.6494 41 Ba(HCO3)+ 0.12754E-05 -5.8944 0.37607E-06 -6.4247 0.29487E+00 -0.5304 42 BaCl+ 0.43999E-04 -4.3566 0.12491E-04 -4.9034 0.28390E+00 -0.5468 43 CH4,aq 0.20292E-08 -8.6927 0.24666E-08 -8.6079 0.12156E+01 0.0848 48 CO,aq 0.83652E-03 -3.0775 0.83652E-03 -3.0775 0.10000E+01 0.0000 49 CO2,aq 0.26779E+01 0.4278 0.32551E+01 0.5126 0.12156E+01 0.0848 50 CO3-2 0.53026E-10 -10.2755 0.38054E-12 -12.4196 0.71765E-02 -2.1441 51 CaCO3,aq 0.16584E-10 -10.7803 0.16584E-10 -10.7803 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.65772E-06 -6.1820 0.18673E-06 -6.7288 0.28390E+00 -0.5468 53 CaCl+ 0.23566E-03 -3.6277 0.66906E-04 -4.1745 0.28390E+00 -0.5468 54 CaCl2,aq 0.13091E-03 -3.8830 0.13091E-03 -3.8830 0.10000E+01 0.0000 55 CaOH+ 0.35963E-06 -6.4441 0.10210E-06 -6.9910 0.28390E+00 -0.5468 56 CaSO4,aq 0.11064E-06 -6.9561 0.11064E-06 -6.9561 0.10000E+01 0.0000 57 HCl,aq 0.11283E-02 -2.9476 0.11283E-02 -2.9476 0.10000E+01 0.0000 66 CuCl,aq 0.44895E-04 -4.3478 0.44895E-04 -4.3478 0.10000E+01 0.0000 67 CuCl2- 0.17876E-03 -3.7477 0.45672E-04 -4.3403 0.25550E+00 -0.5926 68 CuCl3-2 0.46467E-05 -5.3329 0.33347E-07 -7.4769 0.71765E-02 -2.1441 74 FeCl+ 0.60236E-06 -6.2201 0.17101E-06 -6.7670 0.28390E+00 -0.5468 75 FeCl2,aq 0.86661E-02 -2.0622 0.86661E-02 -2.0622 0.10000E+01 0.0000 77 FeO,aq 0.76677E-07 -7.1153 0.76677E-07 -7.1153 0.10000E+01 0.0000 78 FeOH+ 0.44493E-07 -7.3517 0.12632E-07 -7.8985 0.28390E+00 -0.5468 79 HFeO2- 0.11034E-07 -7.9573 0.28191E-08 -8.5499 0.25550E+00 -0.5926 82 FeO2- 0.67469E-08 -8.1709 0.17238E-08 -8.7635 0.25550E+00 -0.5926 83 HFeO2,aq 0.21753E-09 -9.6625 0.21753E-09 -9.6625 0.10000E+01 0.0000 84 H2,aq 0.45084E-02 -2.3460 0.54802E-02 -2.2612 0.12156E+01 0.0848 85 KCl,aq 0.54417E-01 -1.2643 0.54417E-01 -1.2643 0.10000E+01 0.0000 86 KHSO4,aq 0.12599E-01 -1.8997 0.12599E-01 -1.8997 0.10000E+01 0.0000 87 KOH,aq 0.91213E-06 -6.0399 0.91213E-06 -6.0399 0.10000E+01 0.0000 88 KSO4- 0.35347E-02 -2.4516 0.90313E-03 -3.0443 0.25550E+00 -0.5926 90 Mg(HCO3)+ 0.11978E-06 -6.9216 0.34005E-07 -7.4685 0.28390E+00 -0.5468 91 MgCl+ 0.18888E-04 -4.7238 0.53623E-05 -5.2706 0.28390E+00 -0.5468 92 MgOH+ 0.62790E-06 -6.2021 0.17826E-06 -6.7489 0.28390E+00 -0.5468 94 MnO,aq 0.28697E-07 -7.5422 0.28697E-07 -7.5422 0.10000E+01 0.0000 95 MnOH+ 0.13998E-06 -6.8539 0.39741E-07 -7.4008 0.28390E+00 -0.5468 97 HMnO2- 0.19526E-10 -10.7094 0.49889E-11 -11.3020 0.25550E+00 -0.5926 100 MnCl+ 0.11586E-02 -2.9360 0.32894E-03 -3.4829 0.28390E+00 -0.5468 101 MnSO4,aq 0.25206E-07 -7.5985 0.25206E-07 -7.5985 0.10000E+01 0.0000 102 NaCl,aq 0.36593E+00 -0.4366 0.36593E+00 -0.4366 0.10000E+01 0.0000 103 NaOH,aq 0.13348E-05 -5.8746 0.13348E-05 -5.8746 0.10000E+01 0.0000 105 OH- 0.95541E-05 -5.0198 0.21420E-05 -5.6692 0.22419E+00 -0.6494 110 HPO3-2 0.22378E-10 -10.6502 0.16060E-12 -12.7943 0.71765E-02 -2.1441 111 H3PO3,aq 0.17272E-09 -9.7627 0.17272E-09 -9.7627 0.10000E+01 0.0000 112 H2PO3- 0.76619E-08 -8.1157 0.19576E-08 -8.7083 0.25550E+00 -0.5926 113 H3PO4,aq 0.11734E-05 -5.9306 0.11734E-05 -5.9306 0.10000E+01 0.0000 114 H2PO4- 0.26634E-05 -5.5746 0.71452E-06 -6.1460 0.26827E+00 -0.5714 116 H4P2O7,aq 0.11296E-09 -9.9471 0.11296E-09 -9.9471 0.10000E+01 0.0000 117 H3P2O7- 0.25407E-08 -8.5950 0.64915E-09 -9.1877 0.25550E+00 -0.5926 118 H2P2O7-2 0.70358E-06 -6.1527 0.50492E-08 -8.2968 0.71765E-02 -2.1441 119 HP2O7-3 0.21027E-07 -7.6772 0.24922E-12 -12.6034 0.11853E-04 -4.9262 121 PbCl+ 0.27726E-05 -5.5571 0.78716E-06 -6.1039 0.28390E+00 -0.5468 122 PbCl2,aq 0.92404E-04 -4.0343 0.92404E-04 -4.0343 0.10000E+01 0.0000 123 PbCl3- 0.11395E-03 -3.9433 0.29113E-04 -4.5359 0.25550E+00 -0.5926 124 PbCl4-2 0.29219E-04 -4.5343 0.20969E-06 -6.6784 0.71765E-02 -2.1441 125 PbO,aq 0.35125E-08 -8.4544 0.35125E-08 -8.4544 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.96292E-04 -4.0164 0.96292E-04 -4.0164 0.10000E+01 0.0000 128 Pb(HS)3- 0.84334E-05 -5.0740 0.21547E-05 -5.6666 0.25550E+00 -0.5926 129 H2S,aq 0.10440E+01 0.0187 0.12691E+01 0.1035 0.12156E+01 0.0848 130 S2-2 0.14967E-07 -7.8249 0.10741E-09 -9.9689 0.71765E-02 -2.1441 131 S3-2 0.16040E-08 -8.7948 0.11511E-10 -10.9389 0.71765E-02 -2.1441 132 S3- 0.22378E-01 -1.6502 0.57177E-02 -2.2428 0.25550E+00 -0.5926 133 S4-2 0.14271E-09 -9.8455 0.10242E-11 -11.9896 0.71765E-02 -2.1441 134 S5-2 0.10699E-10 -10.9707 0.76778E-13 -13.1148 0.71765E-02 -2.1441 135 SO2,aq 0.28289E+00 -0.5484 0.28289E+00 -0.5484 0.10000E+01 0.0000 136 SO3-2 0.59710E-09 -9.2240 0.66024E-11 -11.1803 0.11058E-01 -1.9563 137 HSO3- 0.44904E-03 -3.3477 0.11473E-03 -3.9403 0.25550E+00 -0.5926 138 HSO4- 0.12381E-01 -1.9072 0.36025E-02 -2.4434 0.29098E+00 -0.5361 140 S2O3-2 0.51091E-06 -6.2917 0.36665E-08 -8.4357 0.71765E-02 -2.1441 141 HS2O3- 0.75056E-06 -6.1246 0.19177E-06 -6.7172 0.25550E+00 -0.5926 142 H2S2O3,aq 0.24345E-07 -7.6136 0.24345E-07 -7.6136 0.10000E+01 0.0000 150 S4O6-2 0.70033E-09 -9.1547 0.50259E-11 -11.2988 0.71765E-02 -2.1441 152 ZnCl+ 0.69388E-03 -3.1587 0.19699E-03 -3.7055 0.28390E+00 -0.5468 153 ZnCl2,aq 0.14121E-02 -2.8501 0.14121E-02 -2.8501 0.10000E+01 0.0000 154 ZnCl3- 0.20968E-03 -3.6785 0.53572E-04 -4.2711 0.25550E+00 -0.5926 155 ZnO,aq 0.36003E-07 -7.4437 0.36003E-07 -7.4437 0.10000E+01 0.0000 156 ZnOH+ 0.33116E-05 -5.4800 0.94017E-06 -6.0268 0.28390E+00 -0.5468 158 HZnO2- 0.32824E-09 -9.4838 0.83865E-10 -10.0764 0.25550E+00 -0.5926 Charge balance for all species = 0.2552E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1303570E-04 0.4301606E+01 0.3530330E+04 0.0000 2 H2O 0.1000000E+01 0.5249523E+02 0.7700366E+06 0.0000 3 Cl- 0.2112644E+00 0.6570192E+00 0.1896624E+05 4.1742 4 SO4-- 0.1645703E-03 0.2538384E+00 0.1985442E+05 4.9881 5 HCO3- 0.2816328E-04 0.2678776E+01 0.1330880E+06 0.3305 6 HS- 0.1502425E-03 0.1169716E+01 0.3149857E+05 1.0297 7 H4SiO4 0.1006512E+00 0.1006549E+00 0.7877307E+04 -0.9972 8 Al+++ 0.5996435E-17 0.2107820E-04 0.4630732E+00 -5.7584 9 Ca++ 0.2354426E-05 0.3700656E-03 0.1207633E+02 3.0553 10 Mg++ 0.1216013E-05 0.2085308E-04 0.4128011E+00 2.6866 11 Fe++ 0.1929379E-07 0.8666900E-02 0.3941066E+03 0.9080 12 K+ 0.5592866E-01 0.1264802E+00 0.4026907E+04 3.6391 13 Na+ 0.1930371E+00 0.5589656E+00 0.1046334E+05 4.1405 14 Mn++ 0.4672583E-06 0.1159308E-02 0.5185872E+02 2.3073 15 Zn++ 0.5005435E-09 0.2318954E-02 0.1234300E+03 -0.6780 16 Cu+ 0.6608566E-07 0.2283633E-03 0.1181473E+02 -2.3261 17 Pb++ 0.4616763E-08 0.3430752E-03 0.5787728E+02 0.3948 18 Ag+ 0.4124970E-09 0.8775082E-05 0.7707294E+00 -4.4997 19 Ba++ 0.2424946E-06 0.4551658E-04 0.5089988E+01 2.1447 20 HPO4-- 0.1278666E-08 0.5300440E-05 0.4142268E+00 -0.1195 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265213E+01 -.2850506E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5205110E+02 -.8632028E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2516909E+00 0.3188825E-04 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159819E+01 0.3247095E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.9980329E-01 0.4379103E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2089987E-04 0.6736397E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3669347E-03 0.1609751E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8593575E-02 0.1731784E-03 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542366E+00 0.3627290E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.2264313E-03 0.1731784E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.4513150E-04 0.1024095E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.5255597E-05 0.3311904E-05 0.0000000E+00 Chg. balance for solid moles: -.1508E-18 Mass of aqueous solution: 0.121776E+04 g Temperature = 590.00 C Pressure = 1769.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1104E-05 -5.957 0.5545E-03 -3.256 0.2039E-01 0.1762E-03 quartz 0.4239E-01 -1.373 2.547 0.406 93.64 0.9618 barite 0.1024E-04 -4.990 0.2390E-02 -2.622 0.8788E-01 0.5335E-03 chalcopyrite 0.1732E-03 -3.762 0.3178E-01 -1.498 1.168 0.7418E-02 an30ab70 0.5182E-03 -3.286 0.1384 -0.859 5.087 0.5196E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.719995 g Volume = 1.021909 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 30 apatite-OH -50.39 -50.39 0.00 0.000 0.28064E-10 144 quartz -0.99 -0.99 0.00 0.000 0.00000E+00 237 barite -14.64 -14.64 0.00 0.000 0.70160E-11 240 chalcopyrite -21.99 -21.99 0.00 0.000 -0.14032E-10 260 an30ab70 -6.36 -6.36 0.00 0.000 -0.17540E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.291 0.11503E+04 2.956 2 CO2,gas -9.12 -10.55 -1.43 -0.478 0.56652E+04 1.813 3 CH4,gas 6.92 -3.63 -10.55 -2.636 0.41650E+05 -7.298 4 H2,gas 5.77 1.73 -4.04 -2.310 0.15969E+05 -0.795 5 H2S,gas -7.58 -9.85 -2.27 -1.135 0.89672E+04 0.977 6 CO,gas -3.18 -8.82 -5.64 -1.734 0.22262E+05 -2.389 7 SO3,gas -6.52 -16.78 -10.26 -2.565 0.40524E+05 -7.013 8 O2,gas 16.49 -3.46 -19.95 -13.301 0.78799E+05 -16.703 9 HCl,gas -5.65 -6.71 -1.06 -0.531 0.41967E+04 -1.063 10 acmite 3.86 2.19 -1.67 -0.173 0.65892E+04 12 akimotoite 5.82 1.69 -4.13 -0.826 0.16304E+05 13 akimotoite-Fe 3.80 -0.09 -3.88 -0.777 0.15344E+05 14 albite-high -4.46 -4.60 -0.14 -0.011 0.56625E+03 15 albite -4.43 -4.60 -0.17 -0.013 0.69101E+03 16 almandine -10.40 -11.78 -1.39 -0.069 0.54861E+04 17 pyrope -4.01 -6.45 -2.44 -0.122 0.96329E+04 18 analcite -2.65 -3.61 -0.96 -0.106 0.37777E+04 19 andalusite -12.31 -12.52 -0.21 -0.021 0.81552E+03 20 andradite 11.13 6.26 -4.87 -0.253 0.19224E+05 21 grossular -0.53 -5.34 -4.81 -0.240 0.18997E+05 22 anhydrite -13.62 -13.72 -0.10 -0.052 0.40902E+03 24 annite -0.75 -2.39 -1.64 -0.091 0.64805E+04 25 phlogopite 3.67 2.95 -0.73 -0.040 0.28638E+04 27 anorthite -9.98 -10.46 -0.48 -0.037 0.18773E+04 28 anthophyllite 13.40 10.85 -2.56 -0.069 0.10102E+05 29 anthophyllite-Fe 1.30 -1.61 -2.91 -0.079 0.11483E+05 31 apatite-OH-zs -48.29 -50.39 -2.09 -0.161 0.82739E+04 32 apatite-Cl-zs -54.05 -57.10 -3.05 -0.254 0.12030E+05 33 aragonite -4.08 -7.50 -3.42 -1.140 0.13509E+05 34 brucite 4.94 2.68 -2.26 -0.452 0.89199E+04 35 calcite -4.17 -7.50 -3.33 -1.110 0.13150E+05 36 carnegieite-low -0.84 -2.62 -1.77 -0.253 0.69980E+04 37 carnegieite-high -0.78 -2.62 -1.84 -0.262 0.72511E+04 38 carpholite-Mg -9.08 -10.83 -1.75 -0.117 0.69116E+04 39 carpholite-Fe -10.38 -12.61 -2.23 -0.149 0.88004E+04 40 celadonite -1.25 -3.41 -2.16 -0.127 0.85321E+04 41 celadonite-Fe -2.61 -5.19 -2.58 -0.152 0.10198E+05 42 chrysotile 8.63 6.06 -2.56 -0.214 0.10129E+05 44 clinochlore 0.40 -1.09 -1.49 -0.046 0.58682E+04 45 daphnite -6.38 -9.98 -3.60 -0.112 0.14213E+05 48 chloritoid-Mg -8.75 -9.83 -1.08 -0.072 0.42720E+04 49 chloritoid-Fe -10.60 -11.61 -1.01 -0.067 0.39885E+04 50 chloritoid-Mn -8.44 -10.21 -1.77 -0.118 0.70095E+04 52 coesite -0.72 -0.99 -0.27 -0.092 0.10852E+04 53 cordierite-H -22.25 -22.64 -0.39 -0.014 0.15386E+04 54 cordierite-Fe -24.62 -26.20 -1.58 -0.054 0.62362E+04 55 cordierite-Mn -20.21 -23.40 -3.19 -0.110 0.12596E+05 56 corundum -11.16 -11.52 -0.37 -0.033 0.14539E+04 58 cristobalite -0.94 -0.99 -0.05 -0.018 0.21405E+03 59 cummingtonite 13.46 10.85 -2.61 -0.071 0.10323E+05 61 cymrite-K -2.85 -5.10 -2.25 -0.188 0.89036E+04 63 diaspore -5.08 -5.76 -0.69 -0.114 0.27112E+04 65 diopside 5.18 3.75 -1.43 -0.143 0.56294E+04 66 hedenbergite 3.81 1.97 -1.84 -0.184 0.72697E+04 68 eastonite -9.06 -10.27 -1.20 -0.046 0.47472E+04 69 enstatite 4.33 3.38 -0.95 -0.095 0.37381E+04 70 clinoenstatite-HiP 4.81 3.38 -1.42 -0.142 0.56233E+04 71 clinoenstatite 4.32 3.38 -0.93 -0.093 0.36907E+04 72 protoenstatite 4.46 3.38 -1.08 -0.108 0.42524E+04 73 epidote -6.33 -8.36 -2.03 -0.098 0.80087E+04 74 clinozoisite -11.89 -14.16 -2.27 -0.103 0.89490E+04 75 epidote-Fe 0.89 -2.55 -3.45 -0.179 0.13619E+05 76 fayalite 1.81 0.82 -0.99 -0.141 0.39071E+04 77 ferrosilite 0.90 -0.17 -1.07 -0.107 0.42434E+04 78 forsterite 5.65 4.38 -1.27 -0.182 0.50214E+04 79 gedrite -13.82 -15.58 -1.77 -0.048 0.69834E+04 81 gibbsite -3.50 -5.76 -2.27 -0.324 0.89472E+04 82 glaucophane 0.12 -3.14 -3.26 -0.088 0.12868E+05 83 glaucophane-Fe -3.75 -8.47 -4.72 -0.128 0.18661E+05 84 goethite 0.89 0.04 -0.85 -0.184 0.33678E+04 86 greenalite 3.98 0.73 -3.25 -0.271 0.12850E+05 87 grunerite 1.83 -1.61 -3.43 -0.093 0.13558E+05 88 halite -0.48 -2.57 -2.09 -1.046 0.82625E+04 89 hematite 0.29 0.08 -0.21 -0.025 0.81406E+03 90 heulandite -12.77 -15.43 -2.66 -0.121 0.10507E+05 91 hercynite -9.78 -10.62 -0.84 -0.056 0.33181E+04 94 jadeite -1.98 -3.61 -1.63 -0.163 0.64348E+04 96 kalsilite -1.48 -3.12 -1.64 -0.234 0.64721E+04 97 kaolinite -11.06 -13.51 -2.46 -0.223 0.97064E+04 98 kyanite -12.17 -12.52 -0.35 -0.035 0.13854E+04 100 laumontite -9.20 -12.45 -3.25 -0.217 0.12843E+05 101 lawsonite -7.30 -10.46 -3.16 -0.210 0.12462E+05 102 leucite -3.12 -4.11 -0.99 -0.099 0.39275E+04 104 lizardite 8.82 6.06 -2.76 -0.230 0.10888E+05 105 magnesite -5.12 -7.87 -2.75 -0.917 0.10862E+05 106 magnetite 1.16 0.99 -0.17 -0.014 0.68438E+03 107 minnesotaite 0.76 -1.26 -2.02 -0.119 0.79675E+04 108 minnesotaite-Mg 6.50 4.08 -2.42 -0.142 0.95408E+04 109 magnesioferrite 4.12 2.76 -1.36 -0.111 0.53609E+04 111 manganosite 5.01 2.31 -2.70 -0.676 0.10678E+05 112 margarite -20.68 -21.98 -1.30 -0.052 0.51489E+04 115 microcline -5.02 -5.10 -0.08 -0.006 0.32978E+03 116 monticellite 8.29 4.74 -3.55 -0.507 0.14010E+05 118 mullite-Si -11.60 -12.52 -0.92 -0.092 0.36249E+04 119 muscovite -16.06 -16.63 -0.57 -0.033 0.22478E+04 120 paragonite -15.38 -16.13 -0.75 -0.044 0.29519E+04 121 nepheline -1.13 -2.62 -1.48 -0.212 0.58552E+04 122 osumilite(2) -14.60 -16.52 -1.92 -0.040 0.75860E+04 123 osumilite-Fe -31.30 -33.29 -1.99 -0.041 0.78426E+04 124 pargasite 1.62 -2.26 -3.89 -0.102 0.15346E+05 125 periclase 5.13 2.68 -2.44 -0.611 0.96513E+04 126 periclase-Fe 2.64 0.91 -1.73 -0.433 0.68379E+04 127 perovskite-Al -9.47 -11.52 -2.05 -0.187 0.81064E+04 132 phlogopite-Na 4.54 3.45 -1.09 -0.060 0.42947E+04 134 prehnite -5.34 -8.40 -3.06 -0.180 0.12089E+05 135 prehnite-Fe 0.62 -2.60 -3.22 -0.194 0.12708E+05 138 px-Mg-tschermaks -8.20 -9.83 -1.63 -0.117 0.64470E+04 139 px-Ca-tschermaks -7.17 -9.46 -2.30 -0.164 0.90669E+04 140 pyrite -20.43 -20.53 -0.10 -0.023 0.39081E+03 141 pyrrhotite -8.27 -8.95 -0.67 -0.224 0.26528E+04 142 pyrrhotiteFe0.875 -8.98 -9.27 -0.30 -0.109 0.11750E+04 143 pyrophyllite -14.43 -15.50 -1.06 -0.066 0.41998E+04 146 riebeckite 6.29 3.13 -3.16 -0.087 0.12464E+05 147 ringwoodite-Fe 2.78 0.82 -1.97 -0.281 0.77611E+04 148 ringwoodite-Mg 8.72 4.38 -4.34 -0.620 0.17153E+05 149 rhodochrosite -4.97 -8.25 -3.28 -1.093 0.12948E+05 150 rhodonite 2.43 1.31 -1.12 -0.223 0.44113E+04 151 sanidine -4.50 -5.10 -0.61 -0.047 0.23968E+04 152 sapphirine(351) -46.26 -50.55 -4.30 -0.065 0.16968E+05 153 siderite -6.87 -9.65 -2.77 -0.925 0.10956E+05 154 sillimanite -12.28 -12.52 -0.23 -0.023 0.91944E+03 156 spinel -7.68 -8.84 -1.16 -0.077 0.45679E+04 158 staurolite-Fe -103.47 -107.54 -4.06 -0.037 0.16053E+05 162 stilpnomelane-Fe -8.54 -13.13 -4.60 -0.137 0.18149E+05 163 stilpnomelane-Mg -2.12 -4.24 -2.12 -0.063 0.83626E+04 164 stishovite 1.87 -0.99 -2.87 -0.956 0.11324E+05 165 sudoite-Fe -20.72 -24.22 -3.50 -0.113 0.13837E+05 166 sudoite -18.60 -20.66 -2.07 -0.067 0.81569E+04 167 sulfur -10.10 -11.58 -1.48 -0.457 0.58604E+04 168 sylvite -0.39 -3.07 -2.68 -1.341 0.10594E+05 169 talc 4.80 4.08 -0.72 -0.042 0.28374E+04 170 talc-Fe 2.11 -1.26 -3.36 -0.198 0.13287E+05 171 talc-tschermaks -7.66 -9.14 -1.48 -0.087 0.58428E+04 173 tephroite 6.13 3.62 -2.51 -0.359 0.99217E+04 176 topaz-H -10.26 -12.52 -2.25 -0.205 0.89039E+04 177 tremolite 14.53 11.58 -2.94 -0.080 0.11631E+05 179 troilite-low -8.18 -8.95 -0.77 -0.257 0.30398E+04 180 tschermakite -11.92 -14.85 -2.93 -0.079 0.11572E+05 183 wadsleyite-Fe 2.63 0.82 -1.81 -0.259 0.71543E+04 184 wadsleyite-Mg 7.80 4.38 -3.42 -0.489 0.13506E+05 185 wairakite -10.95 -12.45 -1.49 -0.088 0.59043E+04 186 walstromite 4.56 2.06 -2.50 -0.499 0.98596E+04 187 wollastonite 4.16 2.06 -2.10 -0.419 0.82814E+04 188 pseudo-wollastonite 4.26 2.06 -2.20 -0.441 0.87075E+04 189 zoisite -11.95 -14.16 -2.20 -0.100 0.87034E+04 192 beidellite-Ca -15.21 -16.57 -1.36 -0.084 0.53640E+04 193 beidellite-H -15.21 -17.07 -1.87 -0.119 0.73680E+04 194 beidellite-K -14.14 -15.87 -1.73 -0.106 0.68194E+04 195 beidellite-Mg -15.52 -16.63 -1.11 -0.069 0.43781E+04 196 beidellite-Na -14.08 -15.70 -1.62 -0.099 0.64132E+04 197 bornite -50.89 -51.00 -0.11 -0.009 0.45088E+03 199 chalcocite -13.16 -14.51 -1.35 -0.337 0.53208E+04 200 covellite -11.71 -13.05 -1.34 -0.509 0.52821E+04 202 montmorillonite-Ca -11.15 -12.21 -1.06 -0.065 0.41814E+04 203 montmorillonite-K -10.38 -11.51 -1.13 -0.069 0.44788E+04 204 montmorillonite-Mg -11.39 -12.27 -0.88 -0.054 0.34571E+04 205 montmorillonite-Na -10.01 -11.34 -1.34 -0.082 0.52735E+04 206 nontronite-Ca -3.54 -4.96 -1.43 -0.092 0.56292E+04 207 nontronite-H -3.54 -5.47 -1.92 -0.129 0.76017E+04 208 nontronite-K -2.48 -4.27 -1.79 -0.115 0.70768E+04 209 nontronite-Mg -3.79 -5.02 -1.23 -0.080 0.48614E+04 210 nontronite-Na -2.41 -4.10 -1.69 -0.109 0.66843E+04 215 gypsum -11.49 -13.73 -2.24 -0.559 0.88282E+04 232 alabandite -6.00 -7.55 -1.55 -0.517 0.61255E+04 234 anglesite -13.75 -16.39 -2.63 -1.316 0.10396E+05 238 boehmite -4.80 -5.76 -0.96 -0.160 0.38001E+04 242 copper,native 1.79 -1.46 -3.25 -1.131 0.12847E+05 244 ferrous-oxide 1.73 0.91 -0.82 -0.206 0.32516E+04 245 galena -9.07 -9.46 -0.39 -0.130 0.15457E+04 246 silver,native 0.57 -3.64 -4.20 -1.462 0.16600E+05 248 litharge 5.18 0.39 -4.79 -1.197 0.18907E+05 255 sphalerite -10.43 -10.53 -0.10 -0.034 0.40053E+03 256 wurtzite -9.65 -10.53 -0.88 -0.295 0.34896E+04 257 zincite 1.87 -0.68 -2.55 -0.638 0.10077E+05 258 an20ab80 -5.75 -5.77 -0.02 -0.001 0.70325E+02 259 an25ab75 -6.06 -6.06 -0.01 0.000 0.22182E+02 261 tr.625ac.25prg.125 8.81 7.63 -1.18 -0.032 0.46633E+04 Calculations done for 590.0000 Deg. C; 1769.0000 bar Temperature changed by -1.000 degrees to 589.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 24 Loop limit = 500 Temperature = 589.00 C Pressure = 1729.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5504E+02 kg liquid = 0.9916E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9953 Stoichiometric ionic strength = .3308365E+01 Osmotic coef. = 0.0000 True ionic strength = .2471190E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12381E-04 -4.9072 0.33854E-05 -5.4704 0.27342E+00 -0.5632 2 H2O 0.99533E+00 -0.0020 0.99533E+00 -0.0020 3 Cl- 0.20734E+00 -0.6833 0.51984E-01 -1.2841 0.25072E+00 -0.6008 4 SO4-- 0.16977E-03 -3.7701 0.12373E-05 -5.9075 0.72877E-02 -2.1374 5 HCO3- 0.27296E-04 -4.5639 0.73614E-05 -5.1330 0.26968E+00 -0.5691 6 HS- 0.15050E-03 -3.8225 0.38043E-04 -4.4197 0.25277E+00 -0.5973 7 H4SiO4 0.97832E-01 -1.0095 0.97832E-01 -1.0095 0.10000E+01 0.0000 8 Al+++ 0.56845E-17 -17.2453 0.68571E-22 -22.1639 0.12063E-04 -4.9185 9 Ca++ 0.23598E-05 -5.6271 0.14009E-07 -7.8536 0.59363E-02 -2.2265 10 Mg++ 0.12313E-05 -5.9096 0.60453E-08 -8.2186 0.49098E-02 -2.3089 11 Fe++ 0.19459E-07 -7.7109 0.10027E-09 -9.9988 0.51532E-02 -2.2879 12 K+ 0.55083E-01 -1.2590 0.15229E-01 -1.8173 0.27648E+00 -0.5583 13 Na+ 0.18966E+00 -0.7220 0.48166E-01 -1.3173 0.25396E+00 -0.5952 14 Mn++ 0.47824E-06 -6.3204 0.25528E-08 -8.5930 0.53380E-02 -2.2726 15 Zn++ 0.50635E-09 -9.2956 0.26093E-11 -11.5835 0.51532E-02 -2.2879 16 Cu+ 0.57448E-07 -7.2407 0.14551E-07 -7.8371 0.25330E+00 -0.5964 17 Pb++ 0.44529E-08 -8.3514 0.29482E-10 -10.5304 0.66209E-02 -2.1791 18 Ag+ 0.40364E-09 -9.3940 0.10991E-09 -9.9590 0.27229E+00 -0.5650 19 Ba++ 0.22507E-06 -6.6477 0.15959E-08 -8.7970 0.70910E-02 -2.1493 20 HPO4-- 0.11692E-08 -8.9321 0.85620E-11 -11.0674 0.73228E-02 -2.1353 21 HSiO3- 0.22310E-05 -5.6515 0.55935E-06 -6.2523 0.25072E+00 -0.6008 22 Ca(HSiO3)+ 0.13283E-07 -7.8767 0.37039E-08 -8.4313 0.27884E+00 -0.5546 23 Mg(HSiO3)+ 0.14735E-08 -8.8316 0.41088E-09 -9.3863 0.27884E+00 -0.5546 24 NaHSiO3,aq 0.14277E-05 -5.8454 0.14277E-05 -5.8454 0.10000E+01 0.0000 28 AgCl,aq 0.71576E-07 -7.1452 0.71576E-07 -7.1452 0.10000E+01 0.0000 29 AgCl2- 0.49807E-05 -5.3027 0.12487E-05 -5.9035 0.25072E+00 -0.6008 30 AgCl3-2 0.24558E-05 -5.6098 0.16620E-07 -7.7794 0.67678E-02 -2.1696 31 AgCl4-3 0.12613E-05 -5.8992 0.13117E-10 -10.8822 0.10400E-04 -4.9830 34 Ag(HS),aq 0.62859E-09 -9.2016 0.62859E-09 -9.2016 0.10000E+01 0.0000 35 Ag(HS)2- 0.38700E-08 -8.4123 0.97026E-09 -9.0131 0.25072E+00 -0.6008 36 AlO+ 0.11280E-10 -10.9477 0.31454E-11 -11.5023 0.27884E+00 -0.5546 38 HAlO2,aq 0.45679E-08 -8.3403 0.45679E-08 -8.3403 0.10000E+01 0.0000 39 AlO2- 0.20432E-04 -4.6897 0.44901E-05 -5.3477 0.21976E+00 -0.6581 41 Ba(HCO3)+ 0.11811E-05 -5.9277 0.34219E-06 -6.4657 0.28971E+00 -0.5380 42 BaCl+ 0.40431E-04 -4.3933 0.11274E-04 -4.9479 0.27884E+00 -0.5546 43 CH4,aq 0.20119E-08 -8.6964 0.24434E-08 -8.6120 0.12145E+01 0.0844 48 CO,aq 0.82222E-03 -3.0850 0.82222E-03 -3.0850 0.10000E+01 0.0000 49 CO2,aq 0.26777E+01 0.4278 0.32520E+01 0.5121 0.12145E+01 0.0844 50 CO3-2 0.52964E-10 -10.2760 0.35845E-12 -12.4456 0.67678E-02 -2.1696 51 CaCO3,aq 0.17086E-10 -10.7674 0.17086E-10 -10.7674 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.63794E-06 -6.1952 0.17788E-06 -6.7499 0.27884E+00 -0.5546 53 CaCl+ 0.23249E-03 -3.6336 0.64826E-04 -4.1883 0.27884E+00 -0.5546 54 CaCl2,aq 0.13271E-03 -3.8771 0.13271E-03 -3.8771 0.10000E+01 0.0000 55 CaOH+ 0.36344E-06 -6.4396 0.10134E-06 -6.9942 0.27884E+00 -0.5546 56 CaSO4,aq 0.11795E-06 -6.9283 0.11795E-06 -6.9283 0.10000E+01 0.0000 57 HCl,aq 0.11471E-02 -2.9404 0.11471E-02 -2.9404 0.10000E+01 0.0000 66 CuCl,aq 0.40286E-04 -4.3948 0.40286E-04 -4.3948 0.10000E+01 0.0000 67 CuCl2- 0.16049E-03 -3.7946 0.40236E-04 -4.3954 0.25072E+00 -0.6008 68 CuCl3-2 0.41441E-05 -5.3826 0.28047E-07 -7.5521 0.67678E-02 -2.1696 74 FeCl+ 0.59768E-06 -6.2235 0.16666E-06 -6.7782 0.27884E+00 -0.5546 75 FeCl2,aq 0.86420E-02 -2.0634 0.86420E-02 -2.0634 0.10000E+01 0.0000 77 FeO,aq 0.80901E-07 -7.0920 0.80901E-07 -7.0920 0.10000E+01 0.0000 78 FeOH+ 0.44888E-07 -7.3479 0.12516E-07 -7.9025 0.27884E+00 -0.5546 79 HFeO2- 0.11581E-07 -7.9363 0.29035E-08 -8.5371 0.25072E+00 -0.6008 82 FeO2- 0.71713E-08 -8.1444 0.17980E-08 -8.7452 0.25072E+00 -0.6008 83 HFeO2,aq 0.23359E-09 -9.6316 0.23359E-09 -9.6316 0.10000E+01 0.0000 84 H2,aq 0.45250E-02 -2.3444 0.54955E-02 -2.2600 0.12145E+01 0.0844 85 KCl,aq 0.55027E-01 -1.2594 0.55027E-01 -1.2594 0.10000E+01 0.0000 86 KHSO4,aq 0.12710E-01 -1.8959 0.12710E-01 -1.8959 0.10000E+01 0.0000 87 KOH,aq 0.93696E-06 -6.0283 0.93696E-06 -6.0283 0.10000E+01 0.0000 88 KSO4- 0.36481E-02 -2.4379 0.91465E-03 -3.0387 0.25072E+00 -0.6008 90 Mg(HCO3)+ 0.11651E-06 -6.9337 0.32486E-07 -7.4883 0.27884E+00 -0.5546 91 MgCl+ 0.18862E-04 -4.7244 0.52594E-05 -5.2791 0.27884E+00 -0.5546 92 MgOH+ 0.64020E-06 -6.1937 0.17851E-06 -6.7483 0.27884E+00 -0.5546 94 MnO,aq 0.30830E-07 -7.5110 0.30830E-07 -7.5110 0.10000E+01 0.0000 95 MnOH+ 0.14309E-06 -6.8444 0.39899E-07 -7.3990 0.27884E+00 -0.5546 97 HMnO2- 0.20797E-10 -10.6820 0.52142E-11 -11.2828 0.25072E+00 -0.6008 100 MnCl+ 0.11585E-02 -2.9361 0.32304E-03 -3.4907 0.27884E+00 -0.5546 101 MnSO4,aq 0.27359E-07 -7.5629 0.27359E-07 -7.5629 0.10000E+01 0.0000 102 NaCl,aq 0.36925E+00 -0.4327 0.36925E+00 -0.4327 0.10000E+01 0.0000 103 NaOH,aq 0.13683E-05 -5.8638 0.13683E-05 -5.8638 0.10000E+01 0.0000 105 OH- 0.95360E-05 -5.0206 0.20956E-05 -5.6787 0.21976E+00 -0.6581 110 HPO3-2 0.20003E-10 -10.6989 0.13538E-12 -12.8685 0.67678E-02 -2.1696 111 H3PO3,aq 0.15207E-09 -9.8180 0.15207E-09 -9.8180 0.10000E+01 0.0000 112 H2PO3- 0.66416E-08 -8.1777 0.16652E-08 -8.7785 0.25072E+00 -0.6008 113 H3PO4,aq 0.10535E-05 -5.9774 0.10535E-05 -5.9774 0.10000E+01 0.0000 114 H2PO4- 0.23612E-05 -5.6269 0.62184E-06 -6.2063 0.26336E+00 -0.5795 116 H4P2O7,aq 0.91358E-10 -10.0393 0.91358E-10 -10.0393 0.10000E+01 0.0000 117 H3P2O7- 0.19952E-08 -8.7000 0.50023E-09 -9.3008 0.25072E+00 -0.6008 118 H2P2O7-2 0.56005E-06 -6.2518 0.37903E-08 -8.4213 0.67678E-02 -2.1696 119 HP2O7-3 0.17865E-07 -7.7480 0.18578E-12 -12.7310 0.10400E-04 -4.9830 121 PbCl+ 0.26631E-05 -5.5746 0.74258E-06 -6.1293 0.27884E+00 -0.5546 122 PbCl2,aq 0.91094E-04 -4.0405 0.91094E-04 -4.0405 0.10000E+01 0.0000 123 PbCl3- 0.11288E-03 -3.9474 0.28300E-04 -4.5482 0.25072E+00 -0.6008 124 PbCl4-2 0.28742E-04 -4.5415 0.19452E-06 -6.7110 0.67678E-02 -2.1696 125 PbO,aq 0.36612E-08 -8.4364 0.36612E-08 -8.4364 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.98743E-04 -4.0055 0.98743E-04 -4.0055 0.10000E+01 0.0000 128 Pb(HS)3- 0.89167E-05 -5.0498 0.22356E-05 -5.6506 0.25072E+00 -0.6008 129 H2S,aq 0.10446E+01 0.0190 0.12687E+01 0.1033 0.12145E+01 0.0844 130 S2-2 0.15268E-07 -7.8162 0.10333E-09 -9.9858 0.67678E-02 -2.1696 131 S3-2 0.16267E-08 -8.7887 0.11009E-10 -10.9582 0.67678E-02 -2.1696 132 S3- 0.22057E-01 -1.6565 0.55300E-02 -2.2573 0.25072E+00 -0.6008 133 S4-2 0.14396E-09 -9.8418 0.97426E-12 -12.0113 0.67678E-02 -2.1696 134 S5-2 0.10748E-10 -10.9687 0.72737E-13 -13.1382 0.67678E-02 -2.1696 135 SO2,aq 0.28295E+00 -0.5483 0.28295E+00 -0.5483 0.10000E+01 0.0000 136 SO3-2 0.60518E-09 -9.2181 0.63355E-11 -11.1982 0.10469E-01 -1.9801 137 HSO3- 0.44472E-03 -3.3519 0.11150E-03 -3.9527 0.25072E+00 -0.6008 138 HSO4- 0.12287E-01 -1.9105 0.35123E-02 -2.4544 0.28585E+00 -0.5439 140 S2O3-2 0.52196E-06 -6.2824 0.35325E-08 -8.4519 0.67678E-02 -2.1696 141 HS2O3- 0.73623E-06 -6.1330 0.18458E-06 -6.7338 0.25072E+00 -0.6008 142 H2S2O3,aq 0.24347E-07 -7.6136 0.24347E-07 -7.6136 0.10000E+01 0.0000 150 S4O6-2 0.70082E-09 -9.1544 0.47430E-11 -11.3239 0.67678E-02 -2.1696 152 ZnCl+ 0.68297E-03 -3.1656 0.19044E-03 -3.7202 0.27884E+00 -0.5546 153 ZnCl2,aq 0.14254E-02 -2.8461 0.14254E-02 -2.8461 0.10000E+01 0.0000 154 ZnCl3- 0.20697E-03 -3.6841 0.51890E-04 -4.2849 0.25072E+00 -0.6008 155 ZnO,aq 0.38145E-07 -7.4186 0.38145E-07 -7.4186 0.10000E+01 0.0000 156 ZnOH+ 0.33427E-05 -5.4759 0.93206E-06 -6.0306 0.27884E+00 -0.5546 158 HZnO2- 0.34648E-09 -9.4603 0.86867E-10 -10.0611 0.25072E+00 -0.6008 Charge balance for all species = 0.2552E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1238148E-04 0.4301250E+01 0.3530851E+04 0.0000 2 H2O 0.1000000E+01 0.5249623E+02 0.7702285E+06 0.0000 3 Cl- 0.2073430E+00 0.6569613E+00 0.1896893E+05 4.1863 4 SO4-- 0.1697730E-03 0.2538095E+00 0.1985672E+05 5.0332 5 HCO3- 0.2729645E-04 0.2678540E+01 0.1331068E+06 0.3374 6 HS- 0.1505017E-03 0.1169569E+01 0.3150186E+05 1.0507 7 H4SiO4 0.9783170E-01 0.9783538E-01 0.7658415E+04 -1.0095 8 Al+++ 0.5684502E-17 0.2043655E-04 0.4490800E+00 -5.7527 9 Ca++ 0.2359843E-05 0.3686899E-03 0.1203420E+02 3.0872 10 Mg++ 0.1231275E-05 0.2085124E-04 0.4128597E+00 2.7222 11 Fe++ 0.1945880E-07 0.8642765E-02 0.3930995E+03 0.9420 12 K+ 0.5508345E-01 0.1264690E+00 0.4027478E+04 3.6531 13 Na+ 0.1896584E+00 0.5589160E+00 0.1046482E+05 4.1531 14 Mn++ 0.4782373E-06 0.1159206E-02 0.5186608E+02 2.3478 15 Zn++ 0.5063484E-09 0.2318749E-02 0.1234475E+03 -0.6427 16 Cu+ 0.5744790E-07 0.2049724E-03 0.1060700E+02 -2.3667 17 Pb++ 0.4452928E-08 0.3430449E-03 0.5788550E+02 0.4103 18 Ag+ 0.4036379E-09 0.8774308E-05 0.7708387E+00 -4.4886 19 Ba++ 0.2250662E-06 0.4183724E-04 0.4679614E+01 2.1438 20 HPO4-- 0.1169227E-08 0.4582696E-05 0.3582179E+00 -0.1266 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265236E+01 -.2874270E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5205668E+02 -.9190450E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2516844E+00 0.3842970E-04 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159776E+01 0.3681628E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.9701621E-01 0.4657811E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.2026544E-04 0.6742741E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3656029E-03 0.1623070E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8570400E-02 0.1963535E-03 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542363E+00 0.3630707E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.2032562E-03 0.1963535E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.4148694E-04 0.1388551E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.4544326E-05 0.4023175E-05 0.0000000E+00 Chg. balance for solid moles: -.6607E-19 Mass of aqueous solution: 0.121758E+04 g Temperature = 589.00 C Pressure = 1729.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1341E-05 -5.873 0.6736E-03 -3.172 0.2329E-01 0.2141E-03 quartz 0.4518E-01 -1.345 2.714 0.434 93.83 1.025 barite 0.1389E-04 -4.857 0.3241E-02 -2.489 0.1120 0.7234E-03 chalcopyrite 0.1964E-03 -3.707 0.3603E-01 -1.443 1.246 0.8411E-02 an30ab70 0.5187E-03 -3.285 0.1385 -0.859 4.788 0.5201E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.892716 g Volume = 1.086384 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 30 apatite-OH -50.59 -50.59 0.00 0.000 0.28031E-10 144 quartz -1.01 -1.01 0.00 0.000 0.00000E+00 237 barite -14.70 -14.70 0.00 0.000 0.00000E+00 240 chalcopyrite -22.07 -22.07 0.00 0.000 0.14016E-10 260 an30ab70 -6.37 -6.37 0.00 0.000 0.70078E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.290 0.11457E+04 2.947 2 CO2,gas -9.16 -10.60 -1.45 -0.482 0.57035E+04 1.792 3 CH4,gas 6.92 -3.65 -10.56 -2.641 0.41677E+05 -7.326 4 H2,gas 5.78 1.74 -4.04 -2.310 0.15949E+05 -0.805 5 H2S,gas -7.62 -9.89 -2.27 -1.136 0.89649E+04 0.965 6 CO,gas -3.21 -8.86 -5.65 -1.739 0.22294E+05 -2.413 7 SO3,gas -6.57 -16.85 -10.28 -2.569 0.40543E+05 -7.039 8 O2,gas 16.50 -3.48 -19.97 -13.316 0.78800E+05 -16.737 9 HCl,gas -5.67 -6.75 -1.09 -0.544 0.42887E+04 -1.087 10 acmite 3.84 2.21 -1.63 -0.169 0.64224E+04 12 akimotoite 5.82 1.71 -4.11 -0.821 0.16204E+05 13 akimotoite-Fe 3.80 -0.07 -3.86 -0.773 0.15239E+05 14 albite-high -4.48 -4.62 -0.14 -0.011 0.56799E+03 15 albite -4.45 -4.62 -0.17 -0.013 0.68899E+03 16 almandine -10.37 -11.71 -1.34 -0.067 0.52940E+04 17 pyrope -3.97 -6.37 -2.40 -0.120 0.94585E+04 18 analcite -2.66 -3.62 -0.96 -0.107 0.37829E+04 19 andalusite -12.28 -12.52 -0.24 -0.024 0.93624E+03 20 andradite 11.11 6.38 -4.73 -0.246 0.18661E+05 21 grossular -0.51 -5.27 -4.76 -0.238 0.18781E+05 22 anhydrite -13.69 -13.76 -0.07 -0.037 0.29536E+03 24 annite -0.74 -2.30 -1.56 -0.087 0.61504E+04 25 phlogopite 3.68 3.04 -0.65 -0.036 0.25492E+04 27 anorthite -9.96 -10.44 -0.48 -0.037 0.18792E+04 28 anthophyllite 13.37 11.00 -2.38 -0.064 0.93756E+04 29 anthophyllite-Fe 1.25 -1.47 -2.72 -0.073 0.10712E+05 31 apatite-OH-zs -48.49 -50.59 -2.10 -0.161 0.82771E+04 32 apatite-Cl-zs -54.28 -57.34 -3.06 -0.255 0.12069E+05 33 aragonite -4.11 -7.52 -3.41 -1.135 0.13434E+05 34 brucite 4.95 2.72 -2.24 -0.447 0.88184E+04 35 calcite -4.20 -7.52 -3.31 -1.104 0.13071E+05 36 carnegieite-low -0.84 -2.61 -1.77 -0.253 0.69941E+04 37 carnegieite-high -0.77 -2.61 -1.84 -0.263 0.72490E+04 38 carpholite-Mg -9.05 -10.81 -1.76 -0.117 0.69375E+04 39 carpholite-Fe -10.35 -12.59 -2.24 -0.149 0.88223E+04 40 celadonite -1.27 -3.41 -2.14 -0.126 0.84354E+04 41 celadonite-Fe -2.63 -5.19 -2.56 -0.151 0.10099E+05 42 chrysotile 8.63 6.15 -2.49 -0.207 0.98161E+04 44 clinochlore 0.45 -0.94 -1.38 -0.043 0.54638E+04 45 daphnite -6.34 -9.84 -3.49 -0.109 0.13787E+05 48 chloritoid-Mg -8.71 -9.80 -1.09 -0.073 0.42934E+04 49 chloritoid-Fe -10.56 -11.58 -1.01 -0.068 0.40021E+04 50 chloritoid-Mn -8.40 -10.17 -1.77 -0.118 0.69933E+04 52 coesite -0.73 -1.01 -0.28 -0.092 0.10871E+04 53 cordierite-H -22.21 -22.61 -0.40 -0.014 0.15674E+04 54 cordierite-Fe -24.59 -26.17 -1.58 -0.054 0.62287E+04 55 cordierite-Mn -20.18 -23.36 -3.18 -0.110 0.12528E+05 56 corundum -11.11 -11.51 -0.40 -0.036 0.15777E+04 58 cristobalite -0.95 -1.01 -0.05 -0.018 0.21124E+03 59 cummingtonite 13.43 11.00 -2.43 -0.066 0.95983E+04 61 cymrite-K -2.86 -5.12 -2.26 -0.188 0.89168E+04 63 diaspore -5.05 -5.76 -0.70 -0.117 0.27731E+04 65 diopside 5.17 3.79 -1.37 -0.137 0.54144E+04 66 hedenbergite 3.80 2.01 -1.79 -0.179 0.70497E+04 68 eastonite -9.01 -10.19 -1.18 -0.045 0.46567E+04 69 enstatite 4.32 3.43 -0.90 -0.090 0.35321E+04 70 clinoenstatite-HiP 4.80 3.43 -1.37 -0.137 0.54191E+04 71 clinoenstatite 4.31 3.43 -0.88 -0.088 0.34838E+04 72 protoenstatite 4.45 3.43 -1.03 -0.103 0.40459E+04 73 epidote -6.31 -8.29 -1.98 -0.096 0.77980E+04 74 clinozoisite -11.86 -14.11 -2.26 -0.103 0.89128E+04 75 epidote-Fe 0.89 -2.46 -3.35 -0.174 0.13231E+05 76 fayalite 1.81 0.87 -0.93 -0.134 0.36872E+04 77 ferrosilite 0.89 -0.13 -1.02 -0.102 0.40262E+04 78 forsterite 5.65 4.43 -1.22 -0.174 0.48120E+04 79 gedrite -13.76 -15.46 -1.70 -0.046 0.67104E+04 81 gibbsite -3.47 -5.76 -2.29 -0.326 0.90151E+04 82 glaucophane 0.09 -3.09 -3.18 -0.086 0.12562E+05 83 glaucophane-Fe -3.78 -8.43 -4.65 -0.126 0.18339E+05 84 goethite 0.89 0.07 -0.83 -0.178 0.32567E+04 86 greenalite 3.98 0.80 -3.17 -0.264 0.12514E+05 87 grunerite 1.78 -1.47 -3.24 -0.088 0.12790E+05 88 halite -0.51 -2.60 -2.09 -1.044 0.82411E+04 89 hematite 0.29 0.14 -0.15 -0.018 0.58636E+03 90 heulandite -12.80 -15.48 -2.68 -0.122 0.10555E+05 91 hercynite -9.73 -10.57 -0.84 -0.056 0.33301E+04 94 jadeite -1.98 -3.61 -1.63 -0.163 0.64411E+04 96 kalsilite -1.47 -3.11 -1.64 -0.234 0.64697E+04 97 kaolinite -11.04 -13.53 -2.49 -0.226 0.98253E+04 98 kyanite -12.13 -12.52 -0.38 -0.038 0.15113E+04 100 laumontite -9.19 -12.46 -3.26 -0.217 0.12868E+05 101 lawsonite -7.28 -10.44 -3.17 -0.211 0.12486E+05 102 leucite -3.12 -4.11 -0.99 -0.099 0.39234E+04 104 lizardite 8.83 6.15 -2.68 -0.223 0.10571E+05 105 magnesite -5.15 -7.88 -2.74 -0.912 0.10794E+05 106 magnetite 1.17 1.08 -0.09 -0.007 0.34498E+03 107 minnesotaite 0.73 -1.20 -1.93 -0.114 0.76306E+04 108 minnesotaite-Mg 6.47 4.14 -2.34 -0.137 0.92207E+04 109 magnesioferrite 4.13 2.86 -1.27 -0.104 0.50267E+04 111 manganosite 5.02 2.35 -2.67 -0.668 0.10538E+05 112 margarite -20.61 -21.95 -1.34 -0.054 0.52827E+04 115 microcline -5.04 -5.12 -0.08 -0.006 0.32314E+03 116 monticellite 8.30 4.80 -3.50 -0.499 0.13789E+05 118 mullite-Si -11.57 -12.52 -0.95 -0.095 0.37494E+04 119 muscovite -16.03 -16.63 -0.60 -0.035 0.23743E+04 120 paragonite -15.35 -16.13 -0.78 -0.046 0.30812E+04 121 nepheline -1.13 -2.61 -1.48 -0.212 0.58522E+04 122 osumilite(2) -14.65 -16.51 -1.87 -0.039 0.73715E+04 123 osumilite-Fe -31.31 -33.30 -1.99 -0.041 0.78408E+04 124 pargasite 1.66 -2.10 -3.76 -0.099 0.14840E+05 125 periclase 5.14 2.72 -2.42 -0.605 0.95451E+04 126 periclase-Fe 2.65 0.94 -1.71 -0.426 0.67278E+04 127 perovskite-Al -9.43 -11.51 -2.09 -0.190 0.82305E+04 132 phlogopite-Na 4.55 3.54 -1.01 -0.056 0.39807E+04 134 prehnite -5.32 -8.36 -3.04 -0.179 0.11986E+05 135 prehnite-Fe 0.62 -2.53 -3.15 -0.189 0.12427E+05 138 px-Mg-tschermaks -8.16 -9.80 -1.64 -0.117 0.64672E+04 139 px-Ca-tschermaks -7.13 -9.43 -2.30 -0.164 0.90771E+04 140 pyrite -20.51 -20.58 -0.07 -0.016 0.26873E+03 141 pyrrhotite -8.31 -8.95 -0.64 -0.214 0.25370E+04 142 pyrrhotiteFe0.875 -9.01 -9.28 -0.27 -0.100 0.10733E+04 143 pyrophyllite -14.44 -15.54 -1.10 -0.069 0.43268E+04 146 riebeckite 6.21 3.22 -2.99 -0.082 0.11795E+05 147 ringwoodite-Fe 2.79 0.87 -1.91 -0.273 0.75411E+04 148 ringwoodite-Mg 8.73 4.43 -4.30 -0.614 0.16945E+05 149 rhodochrosite -5.00 -8.26 -3.26 -1.085 0.12844E+05 150 rhodonite 2.42 1.34 -1.08 -0.217 0.42731E+04 151 sanidine -4.51 -5.12 -0.61 -0.047 0.23910E+04 152 sapphirine(351) -46.03 -50.40 -4.38 -0.066 0.17268E+05 153 siderite -6.90 -9.66 -2.76 -0.919 0.10882E+05 154 sillimanite -12.25 -12.52 -0.26 -0.026 0.10427E+04 156 spinel -7.63 -8.79 -1.16 -0.077 0.45838E+04 158 staurolite-Fe -103.14 -107.39 -4.24 -0.039 0.16741E+05 162 stilpnomelane-Fe -8.55 -13.04 -4.49 -0.134 0.17712E+05 163 stilpnomelane-Mg -2.12 -4.14 -2.02 -0.060 0.79670E+04 164 stishovite 1.87 -1.01 -2.87 -0.957 0.11328E+05 165 sudoite-Fe -20.65 -24.17 -3.52 -0.114 0.13892E+05 166 sudoite -18.52 -20.61 -2.08 -0.067 0.82210E+04 167 sulfur -10.14 -11.63 -1.48 -0.457 0.58572E+04 168 sylvite -0.42 -3.10 -2.68 -1.339 0.10568E+05 169 talc 4.78 4.14 -0.64 -0.038 0.25221E+04 170 talc-Fe 2.08 -1.20 -3.28 -0.193 0.12955E+05 171 talc-tschermaks -7.63 -9.09 -1.46 -0.086 0.57525E+04 173 tephroite 6.13 3.69 -2.44 -0.349 0.96405E+04 176 topaz-H -10.23 -12.52 -2.29 -0.208 0.90322E+04 177 tremolite 14.48 11.73 -2.76 -0.075 0.10884E+05 179 troilite-low -8.21 -8.95 -0.74 -0.247 0.29226E+04 180 tschermakite -11.87 -14.73 -2.86 -0.077 0.11273E+05 183 wadsleyite-Fe 2.63 0.87 -1.76 -0.251 0.69359E+04 184 wadsleyite-Mg 7.81 4.43 -3.37 -0.482 0.13299E+05 185 wairakite -10.96 -12.45 -1.50 -0.088 0.59052E+04 186 walstromite 4.55 2.08 -2.47 -0.494 0.97465E+04 187 wollastonite 4.15 2.08 -2.07 -0.414 0.81656E+04 188 pseudo-wollastonite 4.26 2.08 -2.18 -0.436 0.85930E+04 189 zoisite -11.92 -14.11 -2.20 -0.100 0.86693E+04 192 beidellite-Ca -15.20 -16.59 -1.39 -0.086 0.54911E+04 193 beidellite-H -15.20 -17.10 -1.90 -0.122 0.75138E+04 194 beidellite-K -14.14 -15.90 -1.76 -0.108 0.69446E+04 195 beidellite-Mg -15.51 -16.65 -1.14 -0.071 0.45121E+04 196 beidellite-Na -14.08 -15.73 -1.66 -0.102 0.65391E+04 197 bornite -51.08 -51.32 -0.24 -0.018 0.93716E+03 199 chalcocite -13.21 -14.62 -1.41 -0.352 0.55616E+04 200 covellite -11.76 -13.13 -1.37 -0.521 0.53968E+04 202 montmorillonite-Ca -11.16 -12.23 -1.07 -0.066 0.42327E+04 203 montmorillonite-K -10.38 -11.53 -1.15 -0.070 0.45311E+04 204 montmorillonite-Mg -11.40 -12.29 -0.89 -0.055 0.35092E+04 205 montmorillonite-Na -10.02 -11.37 -1.35 -0.083 0.53203E+04 206 nontronite-Ca -3.57 -4.94 -1.37 -0.089 0.54100E+04 207 nontronite-H -3.58 -5.45 -1.88 -0.126 0.74008E+04 208 nontronite-K -2.51 -4.25 -1.74 -0.112 0.68558E+04 209 nontronite-Mg -3.83 -5.00 -1.18 -0.076 0.46438E+04 210 nontronite-Na -2.44 -4.08 -1.64 -0.105 0.64636E+04 215 gypsum -11.55 -13.77 -2.21 -0.553 0.87319E+04 232 alabandite -6.03 -7.54 -1.52 -0.505 0.59810E+04 234 anglesite -13.82 -16.44 -2.62 -1.308 0.10319E+05 238 boehmite -4.78 -5.76 -0.98 -0.163 0.38627E+04 242 copper,native 1.79 -1.50 -3.29 -1.143 0.12963E+05 244 ferrous-oxide 1.74 0.94 -0.80 -0.199 0.31429E+04 245 galena -9.11 -9.48 -0.37 -0.123 0.14554E+04 246 silver,native 0.56 -3.62 -4.18 -1.455 0.16506E+05 248 litharge 5.18 0.41 -4.77 -1.193 0.18820E+05 255 sphalerite -10.47 -10.53 -0.07 -0.022 0.26293E+03 256 wurtzite -9.68 -10.53 -0.85 -0.283 0.33518E+04 257 zincite 1.88 -0.64 -2.52 -0.630 0.99459E+04 258 an20ab80 -5.77 -5.78 -0.02 -0.001 0.69976E+02 259 an25ab75 -6.07 -6.07 -0.01 0.000 0.22468E+02 261 tr.625ac.25prg.125 8.77 7.77 -1.00 -0.027 0.39511E+04 Calculations done for 589.0000 Deg. C; 1729.0000 bar Temperature changed by -1.000 degrees to 588.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 24 Loop limit = 500 Temperature = 588.00 C Pressure = 1691.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5505E+02 kg liquid = 0.9917E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9954 Stoichiometric ionic strength = .3307930E+01 Osmotic coef. = 0.0000 True ionic strength = .2430998E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11793E-04 -4.9284 0.31814E-05 -5.4974 0.26977E+00 -0.5690 2 H2O 0.99542E+00 -0.0020 0.99542E+00 -0.0020 3 Cl- 0.20362E+00 -0.6912 0.50133E-01 -1.2999 0.24621E+00 -0.6087 4 SO4-- 0.17501E-03 -3.7569 0.12061E-05 -5.9186 0.68916E-02 -2.1617 5 HCO3- 0.26482E-04 -4.5770 0.70175E-05 -5.1538 0.26499E+00 -0.5768 6 HS- 0.15070E-03 -3.8219 0.37410E-04 -4.4270 0.24824E+00 -0.6051 7 H4SiO4 0.95163E-01 -1.0215 0.95163E-01 -1.0215 0.10000E+01 0.0000 8 Al+++ 0.54332E-17 -17.2649 0.57842E-22 -22.2378 0.10646E-04 -4.9728 9 Ca++ 0.23683E-05 -5.6256 0.13271E-07 -7.8771 0.56038E-02 -2.2515 10 Mg++ 0.12471E-05 -5.9041 0.57711E-08 -8.2387 0.46275E-02 -2.3347 11 Fe++ 0.19666E-07 -7.7063 0.95555E-10 -10.0197 0.48588E-02 -2.3135 12 K+ 0.54278E-01 -1.2654 0.14748E-01 -1.8313 0.27172E+00 -0.5659 13 Na+ 0.18646E+00 -0.7294 0.46505E-01 -1.3325 0.24942E+00 -0.6031 14 Mn++ 0.48967E-06 -6.3101 0.24653E-08 -8.6081 0.50345E-02 -2.2980 15 Zn++ 0.51280E-09 -9.2901 0.24916E-11 -11.6035 0.48588E-02 -2.3135 16 Cu+ 0.50186E-07 -7.2994 0.12484E-07 -7.9036 0.24876E+00 -0.6042 17 Pb++ 0.43050E-08 -8.3660 0.26931E-10 -10.5697 0.62558E-02 -2.2037 18 Ag+ 0.39549E-09 -9.4029 0.10582E-09 -9.9754 0.26757E+00 -0.5726 19 Ba++ 0.20966E-06 -6.6785 0.14055E-08 -8.8522 0.67039E-02 -2.1737 20 HPO4-- 0.10744E-08 -8.9688 0.74403E-11 -11.1284 0.69251E-02 -2.1596 21 HSiO3- 0.22063E-05 -5.6563 0.54321E-06 -6.2650 0.24621E+00 -0.6087 22 Ca(HSiO3)+ 0.13235E-07 -7.8783 0.36273E-08 -8.4404 0.27406E+00 -0.5622 23 Mg(HSiO3)+ 0.14893E-08 -8.8270 0.40815E-09 -9.3892 0.27406E+00 -0.5622 24 NaHSiO3,aq 0.14561E-05 -5.8368 0.14561E-05 -5.8368 0.10000E+01 0.0000 28 AgCl,aq 0.72109E-07 -7.1420 0.72109E-07 -7.1420 0.10000E+01 0.0000 29 AgCl2- 0.49754E-05 -5.3032 0.12250E-05 -5.9119 0.24621E+00 -0.6087 30 AgCl3-2 0.24314E-05 -5.6141 0.15551E-07 -7.8082 0.63960E-02 -2.1941 31 AgCl4-3 0.12896E-05 -5.8896 0.11822E-10 -10.9273 0.91677E-05 -5.0377 34 Ag(HS),aq 0.65595E-09 -9.1831 0.65595E-09 -9.1831 0.10000E+01 0.0000 35 Ag(HS)2- 0.40455E-08 -8.3930 0.99602E-09 -9.0017 0.24621E+00 -0.6087 36 AlO+ 0.10702E-10 -10.9705 0.29330E-11 -11.5327 0.27406E+00 -0.5622 38 HAlO2,aq 0.44566E-08 -8.3510 0.44566E-08 -8.3510 0.10000E+01 0.0000 39 AlO2- 0.19835E-04 -4.7026 0.42761E-05 -5.3690 0.21558E+00 -0.6664 41 Ba(HCO3)+ 0.10968E-05 -5.9599 0.31242E-06 -6.5053 0.28483E+00 -0.5454 42 BaCl+ 0.37273E-04 -4.4286 0.10215E-04 -4.9908 0.27406E+00 -0.5622 43 CH4,aq 0.19937E-08 -8.7003 0.24192E-08 -8.6163 0.12134E+01 0.0840 48 CO,aq 0.80813E-03 -3.0925 0.80813E-03 -3.0925 0.10000E+01 0.0000 49 CO2,aq 0.26775E+01 0.4277 0.32489E+01 0.5117 0.12134E+01 0.0840 50 CO3-2 0.52903E-10 -10.2765 0.33837E-12 -12.4706 0.63960E-02 -2.1941 51 CaCO3,aq 0.17586E-10 -10.7548 0.17586E-10 -10.7548 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.61964E-06 -6.2079 0.16982E-06 -6.7700 0.27406E+00 -0.5622 53 CaCl+ 0.22957E-03 -3.6391 0.62915E-04 -4.2012 0.27406E+00 -0.5622 54 CaCl2,aq 0.13449E-03 -3.8713 0.13449E-03 -3.8713 0.10000E+01 0.0000 55 CaOH+ 0.36701E-06 -6.4353 0.10058E-06 -6.9975 0.27406E+00 -0.5622 56 CaSO4,aq 0.12556E-06 -6.9011 0.12556E-06 -6.9011 0.10000E+01 0.0000 57 HCl,aq 0.11665E-02 -2.9331 0.11665E-02 -2.9331 0.10000E+01 0.0000 66 CuCl,aq 0.36285E-04 -4.4403 0.36285E-04 -4.4403 0.10000E+01 0.0000 67 CuCl2- 0.14458E-03 -3.8399 0.35595E-04 -4.4486 0.24621E+00 -0.6087 68 CuCl3-2 0.37094E-05 -5.4307 0.23725E-07 -7.6248 0.63960E-02 -2.1941 74 FeCl+ 0.59407E-06 -6.2262 0.16281E-06 -6.7883 0.27406E+00 -0.5622 75 FeCl2,aq 0.86209E-02 -2.0644 0.86209E-02 -2.0644 0.10000E+01 0.0000 77 FeO,aq 0.85143E-07 -7.0699 0.85143E-07 -7.0699 0.10000E+01 0.0000 78 FeOH+ 0.45315E-07 -7.3438 0.12419E-07 -7.9059 0.27406E+00 -0.5622 79 HFeO2- 0.12119E-07 -7.9165 0.29838E-08 -8.5252 0.24621E+00 -0.6087 82 FeO2- 0.75958E-08 -8.1194 0.18701E-08 -8.7281 0.24621E+00 -0.6087 83 HFeO2,aq 0.25024E-09 -9.6016 0.25024E-09 -9.6016 0.10000E+01 0.0000 84 H2,aq 0.45372E-02 -2.3432 0.55055E-02 -2.2592 0.12134E+01 0.0840 85 KCl,aq 0.55602E-01 -1.2549 0.55602E-01 -1.2549 0.10000E+01 0.0000 86 KHSO4,aq 0.12817E-01 -1.8922 0.12817E-01 -1.8922 0.10000E+01 0.0000 87 KOH,aq 0.96078E-06 -6.0174 0.96078E-06 -6.0174 0.10000E+01 0.0000 88 KSO4- 0.37602E-02 -2.4248 0.92579E-03 -3.0335 0.24621E+00 -0.6087 90 Mg(HCO3)+ 0.11340E-06 -6.9454 0.31079E-07 -7.5075 0.27406E+00 -0.5622 91 MgCl+ 0.18836E-04 -4.7250 0.51621E-05 -5.2872 0.27406E+00 -0.5622 92 MgOH+ 0.65168E-06 -6.1860 0.17860E-06 -6.7481 0.27406E+00 -0.5622 94 MnO,aq 0.32985E-07 -7.4817 0.32985E-07 -7.4817 0.10000E+01 0.0000 95 MnOH+ 0.14610E-06 -6.8353 0.40040E-07 -7.3975 0.27406E+00 -0.5622 97 HMnO2- 0.22049E-10 -10.6566 0.54286E-11 -11.2653 0.24621E+00 -0.6087 100 MnCl+ 0.11584E-02 -2.9361 0.31747E-03 -3.4983 0.27406E+00 -0.5622 101 MnSO4,aq 0.29628E-07 -7.5283 0.29628E-07 -7.5283 0.10000E+01 0.0000 102 NaCl,aq 0.37241E+00 -0.4290 0.37241E+00 -0.4290 0.10000E+01 0.0000 103 NaOH,aq 0.14004E-05 -5.8538 0.14004E-05 -5.8538 0.10000E+01 0.0000 105 OH- 0.95130E-05 -5.0217 0.20508E-05 -5.6881 0.21558E+00 -0.6664 110 HPO3-2 0.17959E-10 -10.7457 0.11487E-12 -12.9398 0.63960E-02 -2.1941 111 H3PO3,aq 0.13473E-09 -9.8706 0.13473E-09 -9.8706 0.10000E+01 0.0000 112 H2PO3- 0.57904E-08 -8.2373 0.14256E-08 -8.8460 0.24621E+00 -0.6087 113 H3PO4,aq 0.95186E-06 -6.0214 0.95186E-06 -6.0214 0.10000E+01 0.0000 114 H2PO4- 0.21061E-05 -5.6765 0.54488E-06 -6.2637 0.25872E+00 -0.5872 116 H4P2O7,aq 0.74800E-10 -10.1261 0.74800E-10 -10.1261 0.10000E+01 0.0000 117 H3P2O7- 0.15860E-08 -8.7997 0.39047E-09 -9.4084 0.24621E+00 -0.6087 118 H2P2O7-2 0.45074E-06 -6.3461 0.28829E-08 -8.5402 0.63960E-02 -2.1941 119 HP2O7-3 0.15306E-07 -7.8151 0.14033E-12 -12.8529 0.91677E-05 -5.0377 121 PbCl+ 0.25623E-05 -5.5914 0.70220E-06 -6.1535 0.27406E+00 -0.5622 122 PbCl2,aq 0.89852E-04 -4.0465 0.89852E-04 -4.0465 0.10000E+01 0.0000 123 PbCl3- 0.11181E-03 -3.9515 0.27530E-04 -4.5602 0.24621E+00 -0.6087 124 PbCl4-2 0.28277E-04 -4.5486 0.18086E-06 -6.7427 0.63960E-02 -2.1941 125 PbO,aq 0.38055E-08 -8.4196 0.38055E-08 -8.4196 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10111E-03 -3.9952 0.10111E-03 -3.9952 0.10000E+01 0.0000 128 Pb(HS)3- 0.93952E-05 -5.0271 0.23132E-05 -5.6358 0.24621E+00 -0.6087 129 H2S,aq 0.10452E+01 0.0192 0.12683E+01 0.1032 0.12134E+01 0.0840 130 S2-2 0.15553E-07 -7.8082 0.99480E-10 -10.0023 0.63960E-02 -2.1941 131 S3-2 0.16488E-08 -8.7828 0.10545E-10 -10.9769 0.63960E-02 -2.1941 132 S3- 0.21745E-01 -1.6626 0.53537E-02 -2.2713 0.24621E+00 -0.6087 133 S4-2 0.14524E-09 -9.8379 0.92896E-12 -12.0320 0.63960E-02 -2.1941 134 S5-2 0.10806E-10 -10.9663 0.69118E-13 -13.1604 0.63960E-02 -2.1941 135 SO2,aq 0.28299E+00 -0.5482 0.28299E+00 -0.5482 0.10000E+01 0.0000 136 SO3-2 0.61309E-09 -9.2125 0.60887E-11 -11.2155 0.99311E-02 -2.0030 137 HSO3- 0.44047E-03 -3.3561 0.10845E-03 -3.9648 0.24621E+00 -0.6087 138 HSO4- 0.12201E-01 -1.9136 0.34286E-02 -2.4649 0.28101E+00 -0.5513 140 S2O3-2 0.53305E-06 -6.2732 0.34094E-08 -8.4673 0.63960E-02 -2.1941 141 HS2O3- 0.72308E-06 -6.1408 0.17803E-06 -6.7495 0.24621E+00 -0.6087 142 H2S2O3,aq 0.24384E-07 -7.6129 0.24384E-07 -7.6129 0.10000E+01 0.0000 150 S4O6-2 0.70236E-09 -9.1534 0.44923E-11 -11.3475 0.63960E-02 -2.1941 152 ZnCl+ 0.67271E-03 -3.1722 0.18436E-03 -3.7343 0.27406E+00 -0.5622 153 ZnCl2,aq 0.14382E-02 -2.8422 0.14382E-02 -2.8422 0.10000E+01 0.0000 154 ZnCl3- 0.20427E-03 -3.6898 0.50292E-04 -4.2985 0.24621E+00 -0.6087 155 ZnO,aq 0.40282E-07 -7.3949 0.40282E-07 -7.3949 0.10000E+01 0.0000 156 ZnOH+ 0.33717E-05 -5.4721 0.92404E-06 -6.0343 0.27406E+00 -0.5622 158 HZnO2- 0.36433E-09 -9.4385 0.89699E-10 -10.0472 0.24621E+00 -0.6087 Charge balance for all species = 0.2552E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1179274E-04 0.4300914E+01 0.3531341E+04 0.0000 2 H2O 0.1000000E+01 0.5249720E+02 0.7704099E+06 0.0000 3 Cl- 0.2036219E+00 0.6569067E+00 0.1897147E+05 4.1975 4 SO4-- 0.1750051E-03 0.2537826E+00 0.1985893E+05 5.0761 5 HCO3- 0.2648249E-04 0.2678318E+01 0.1331247E+06 0.3436 6 HS- 0.1506991E-03 0.1169433E+01 0.3150505E+05 1.0704 7 H4SiO4 0.9516328E-01 0.9516695E-01 0.7451151E+04 -1.0215 8 Al+++ 0.5433158E-17 0.1983997E-04 0.4360650E+00 -5.7456 9 Ca++ 0.2368299E-05 0.3675520E-03 0.1199966E+02 3.1177 10 Mg++ 0.1247137E-05 0.2084950E-04 0.4129150E+00 2.7560 11 Fe++ 0.1966620E-07 0.8621713E-02 0.3922271E+03 0.9750 12 K+ 0.5427819E-01 0.1264585E+00 0.4028018E+04 3.6661 13 Na+ 0.1864573E+00 0.5588693E+00 0.1046621E+05 4.1649 14 Mn++ 0.4896745E-06 0.1159110E-02 0.5187303E+02 2.3866 15 Zn++ 0.5127955E-09 0.2318557E-02 0.1234640E+03 -0.6088 16 Cu+ 0.5018612E-07 0.1846209E-03 0.9555917E+01 -2.4063 17 Pb++ 0.4305039E-08 0.3430164E-03 0.5789325E+02 0.4250 18 Ag+ 0.3954938E-09 0.8773579E-05 0.7709420E+00 -4.4780 19 Ba++ 0.2096564E-06 0.3857956E-04 0.4316170E+01 2.1426 20 HPO4-- 0.1074393E-08 0.4000357E-05 0.3127658E+00 -0.1336 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265257E+01 -.2895044E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5206197E+02 -.9718970E-01 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2516786E+00 0.4417766E-04 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159738E+01 0.4059739E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.9437797E-01 0.4921635E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1967548E-04 0.6748640E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3645049E-03 0.1634050E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8550234E-02 0.2165194E-03 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542360E+00 0.3633883E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1830903E-03 0.2165194E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.3825971E-04 0.1711274E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3967192E-05 0.4600308E-05 0.0000000E+00 Chg. balance for solid moles: 0.3574E-18 Mass of aqueous solution: 0.121742E+04 g Temperature = 588.00 C Pressure = 1691.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1533E-05 -5.814 0.7703E-03 -3.113 0.2521E-01 0.2448E-03 quartz 0.4781E-01 -1.320 2.873 0.458 94.01 1.085 barite 0.1711E-04 -4.767 0.3994E-02 -2.399 0.1307 0.8915E-03 chalcopyrite 0.2165E-03 -3.665 0.3973E-01 -1.401 1.300 0.9274E-02 an30ab70 0.5191E-03 -3.285 0.1386 -0.858 4.536 0.5205E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.055819 g Volume = 1.147323 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 30 apatite-OH -50.78 -50.78 0.00 0.000 0.00000E+00 144 quartz -1.02 -1.02 0.00 0.000 0.00000E+00 237 barite -14.77 -14.77 0.00 0.000 0.00000E+00 240 chalcopyrite -22.15 -22.15 0.00 0.000 0.13999E-10 260 an30ab70 -6.37 -6.37 0.00 0.000 0.20999E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.290 0.11410E+04 2.939 2 CO2,gas -9.19 -10.65 -1.46 -0.485 0.57390E+04 1.772 3 CH4,gas 6.92 -3.66 -10.58 -2.646 0.41700E+05 -7.354 4 H2,gas 5.79 1.75 -4.04 -2.310 0.15930E+05 -0.815 5 H2S,gas -7.65 -9.92 -2.27 -1.137 0.89614E+04 0.954 6 CO,gas -3.24 -8.90 -5.67 -1.743 0.22324E+05 -2.437 7 SO3,gas -6.62 -16.91 -10.29 -2.573 0.40559E+05 -7.065 8 O2,gas 16.50 -3.49 -20.00 -13.332 0.78802E+05 -16.770 9 HCl,gas -5.69 -6.80 -1.11 -0.555 0.43765E+04 -1.111 10 acmite 3.82 2.23 -1.59 -0.165 0.62640E+04 12 akimotoite 5.83 1.74 -4.09 -0.818 0.16111E+05 13 akimotoite-Fe 3.80 -0.04 -3.84 -0.768 0.15139E+05 14 albite-high -4.49 -4.64 -0.14 -0.011 0.56971E+03 15 albite -4.46 -4.64 -0.17 -0.013 0.68693E+03 16 almandine -10.33 -11.63 -1.30 -0.065 0.51091E+04 17 pyrope -3.93 -6.29 -2.36 -0.118 0.92998E+04 18 analcite -2.66 -3.62 -0.96 -0.107 0.37876E+04 19 andalusite -12.25 -12.51 -0.27 -0.027 0.10492E+04 20 andradite 11.09 6.49 -4.60 -0.239 0.18129E+05 21 grossular -0.49 -5.20 -4.71 -0.236 0.18577E+05 22 anhydrite -13.75 -13.80 -0.05 -0.024 0.18618E+03 24 annite -0.74 -2.22 -1.48 -0.082 0.58354E+04 25 phlogopite 3.70 3.12 -0.57 -0.032 0.22578E+04 27 anorthite -9.94 -10.42 -0.48 -0.037 0.18809E+04 28 anthophyllite 13.35 11.14 -2.21 -0.060 0.87050E+04 29 anthophyllite-Fe 1.20 -1.33 -2.53 -0.068 0.99767E+04 31 apatite-OH-zs -48.68 -50.78 -2.10 -0.162 0.82804E+04 32 apatite-Cl-zs -54.51 -57.58 -3.07 -0.256 0.12106E+05 33 aragonite -4.14 -7.53 -3.39 -1.130 0.13361E+05 34 brucite 4.97 2.75 -2.21 -0.443 0.87244E+04 35 calcite -4.24 -7.53 -3.30 -1.099 0.12995E+05 36 carnegieite-low -0.83 -2.60 -1.77 -0.253 0.69901E+04 37 carnegieite-high -0.76 -2.60 -1.84 -0.263 0.72471E+04 38 carpholite-Mg -9.02 -10.78 -1.77 -0.118 0.69618E+04 39 carpholite-Fe -10.32 -12.56 -2.24 -0.150 0.88398E+04 40 celadonite -1.28 -3.40 -2.12 -0.125 0.83453E+04 41 celadonite-Fe -2.64 -5.18 -2.54 -0.149 0.10003E+05 42 chrysotile 8.64 6.22 -2.42 -0.201 0.95262E+04 44 clinochlore 0.50 -0.79 -1.29 -0.040 0.50894E+04 45 daphnite -6.30 -9.69 -3.39 -0.106 0.13378E+05 48 chloritoid-Mg -8.67 -9.76 -1.09 -0.073 0.43140E+04 49 chloritoid-Fe -10.53 -11.54 -1.02 -0.068 0.40121E+04 50 chloritoid-Mn -8.36 -10.13 -1.77 -0.118 0.69765E+04 52 coesite -0.74 -1.02 -0.28 -0.092 0.10888E+04 53 cordierite-H -22.17 -22.58 -0.41 -0.014 0.15975E+04 54 cordierite-Fe -24.56 -26.14 -1.58 -0.054 0.62182E+04 55 cordierite-Mn -20.15 -23.31 -3.16 -0.109 0.12463E+05 56 corundum -11.07 -11.50 -0.43 -0.039 0.16935E+04 58 cristobalite -0.96 -1.02 -0.05 -0.018 0.20860E+03 59 cummingtonite 13.40 11.14 -2.27 -0.061 0.89294E+04 61 cymrite-K -2.87 -5.14 -2.27 -0.189 0.89290E+04 63 diaspore -5.03 -5.75 -0.72 -0.120 0.28306E+04 65 diopside 5.16 3.83 -1.32 -0.132 0.52140E+04 66 hedenbergite 3.79 2.05 -1.74 -0.174 0.68416E+04 68 eastonite -8.95 -10.11 -1.16 -0.045 0.45740E+04 69 enstatite 4.32 3.47 -0.85 -0.085 0.33423E+04 70 clinoenstatite-HiP 4.80 3.47 -1.33 -0.133 0.52307E+04 71 clinoenstatite 4.31 3.47 -0.84 -0.084 0.32931E+04 72 protoenstatite 4.45 3.47 -0.98 -0.098 0.38553E+04 73 epidote -6.29 -8.22 -1.93 -0.093 0.75974E+04 74 clinozoisite -11.82 -14.07 -2.25 -0.102 0.88777E+04 75 epidote-Fe 0.89 -2.37 -3.26 -0.170 0.12861E+05 76 fayalite 1.81 0.93 -0.88 -0.126 0.34779E+04 77 ferrosilite 0.88 -0.09 -0.97 -0.097 0.38194E+04 78 forsterite 5.66 4.49 -1.17 -0.167 0.46186E+04 79 gedrite -13.69 -15.33 -1.64 -0.044 0.64613E+04 81 gibbsite -3.45 -5.75 -2.30 -0.329 0.90778E+04 82 glaucophane 0.07 -3.05 -3.12 -0.084 0.12278E+05 83 glaucophane-Fe -3.82 -8.39 -4.58 -0.124 0.18031E+05 84 goethite 0.90 0.10 -0.80 -0.173 0.31503E+04 86 greenalite 3.97 0.88 -3.09 -0.258 0.12194E+05 87 grunerite 1.73 -1.33 -3.06 -0.083 0.12058E+05 88 halite -0.55 -2.63 -2.09 -1.043 0.82206E+04 89 hematite 0.29 0.20 -0.09 -0.011 0.36884E+03 90 heulandite -12.83 -15.52 -2.69 -0.122 0.10600E+05 91 hercynite -9.68 -10.52 -0.85 -0.057 0.33397E+04 94 jadeite -1.98 -3.62 -1.64 -0.164 0.64467E+04 96 kalsilite -1.46 -3.10 -1.64 -0.234 0.64673E+04 97 kaolinite -11.02 -13.54 -2.52 -0.229 0.99349E+04 98 kyanite -12.10 -12.51 -0.41 -0.041 0.16290E+04 100 laumontite -9.19 -12.46 -3.27 -0.218 0.12891E+05 101 lawsonite -7.25 -10.42 -3.17 -0.212 0.12507E+05 102 leucite -3.12 -4.12 -0.99 -0.099 0.39195E+04 104 lizardite 8.83 6.22 -2.61 -0.217 0.10277E+05 105 magnesite -5.17 -7.90 -2.72 -0.908 0.10731E+05 106 magnetite 1.18 1.17 -0.01 0.000 0.21270E+02 107 minnesotaite 0.70 -1.15 -1.85 -0.109 0.73090E+04 108 minnesotaite-Mg 6.45 4.19 -2.26 -0.133 0.89243E+04 109 magnesioferrite 4.15 2.95 -1.20 -0.098 0.47111E+04 111 manganosite 5.03 2.38 -2.64 -0.660 0.10407E+05 112 margarite -20.54 -21.92 -1.37 -0.055 0.54069E+04 115 microcline -5.06 -5.14 -0.08 -0.006 0.31663E+03 116 monticellite 8.30 4.85 -3.45 -0.492 0.13582E+05 118 mullite-Si -11.53 -12.51 -0.98 -0.098 0.38662E+04 119 muscovite -16.00 -16.64 -0.63 -0.037 0.24920E+04 120 paragonite -15.32 -16.14 -0.81 -0.048 0.32014E+04 121 nepheline -1.12 -2.60 -1.48 -0.212 0.58490E+04 122 osumilite(2) -14.69 -16.51 -1.82 -0.038 0.71750E+04 123 osumilite-Fe -31.32 -33.31 -1.99 -0.041 0.78356E+04 124 pargasite 1.71 -1.94 -3.65 -0.096 0.14371E+05 125 periclase 5.15 2.75 -2.40 -0.599 0.94471E+04 126 periclase-Fe 2.65 0.97 -1.68 -0.420 0.66231E+04 127 perovskite-Al -9.38 -11.50 -2.12 -0.193 0.83467E+04 132 phlogopite-Na 4.56 3.62 -0.94 -0.052 0.36902E+04 134 prehnite -5.30 -8.32 -3.02 -0.177 0.11889E+05 135 prehnite-Fe 0.61 -2.47 -3.09 -0.186 0.12160E+05 138 px-Mg-tschermaks -8.11 -9.76 -1.65 -0.118 0.64876E+04 139 px-Ca-tschermaks -7.09 -9.40 -2.31 -0.165 0.90862E+04 140 pyrite -20.58 -20.62 -0.04 -0.009 0.14973E+03 141 pyrrhotite -8.33 -8.95 -0.62 -0.205 0.24258E+04 142 pyrrhotiteFe0.875 -9.04 -9.29 -0.25 -0.091 0.97545E+03 143 pyrophyllite -14.44 -15.57 -1.13 -0.071 0.44452E+04 146 riebeckite 6.13 3.30 -2.83 -0.078 0.11158E+05 147 ringwoodite-Fe 2.79 0.93 -1.86 -0.266 0.73316E+04 148 ringwoodite-Mg 8.74 4.49 -4.25 -0.607 0.16752E+05 149 rhodochrosite -5.03 -8.26 -3.23 -1.078 0.12744E+05 150 rhodonite 2.42 1.37 -1.05 -0.210 0.41428E+04 151 sanidine -4.53 -5.14 -0.61 -0.047 0.23851E+04 152 sapphirine(351) -45.79 -50.24 -4.45 -0.067 0.17553E+05 153 siderite -6.93 -9.68 -2.74 -0.914 0.10809E+05 154 sillimanite -12.22 -12.51 -0.29 -0.029 0.11580E+04 156 spinel -7.58 -8.74 -1.17 -0.078 0.46001E+04 158 staurolite-Fe -102.81 -107.22 -4.41 -0.040 0.17376E+05 162 stilpnomelane-Fe -8.56 -12.95 -4.39 -0.131 0.17291E+05 163 stilpnomelane-Mg -2.12 -4.05 -1.93 -0.058 0.76015E+04 164 stishovite 1.86 -1.02 -2.88 -0.959 0.11332E+05 165 sudoite-Fe -20.57 -24.11 -3.54 -0.114 0.13940E+05 166 sudoite -18.44 -20.55 -2.10 -0.068 0.82829E+04 167 sulfur -10.18 -11.67 -1.49 -0.457 0.58531E+04 168 sylvite -0.46 -3.13 -2.68 -1.338 0.10543E+05 169 talc 4.76 4.19 -0.57 -0.033 0.22302E+04 170 talc-Fe 2.05 -1.15 -3.21 -0.189 0.12638E+05 171 talc-tschermaks -7.60 -9.04 -1.44 -0.085 0.56700E+04 173 tephroite 6.13 3.75 -2.38 -0.340 0.93756E+04 176 topaz-H -10.19 -12.52 -2.32 -0.211 0.91516E+04 177 tremolite 14.45 11.86 -2.59 -0.070 0.10191E+05 179 troilite-low -8.24 -8.95 -0.71 -0.238 0.28100E+04 180 tschermakite -11.82 -14.61 -2.79 -0.075 0.10996E+05 183 wadsleyite-Fe 2.64 0.93 -1.71 -0.244 0.67280E+04 184 wadsleyite-Mg 7.82 4.49 -3.33 -0.475 0.13107E+05 185 wairakite -10.96 -12.46 -1.50 -0.088 0.59049E+04 186 walstromite 4.54 2.10 -2.45 -0.489 0.96402E+04 187 wollastonite 4.14 2.10 -2.04 -0.409 0.80568E+04 188 pseudo-wollastonite 4.25 2.10 -2.15 -0.431 0.84854E+04 189 zoisite -11.88 -14.07 -2.19 -0.100 0.86363E+04 192 beidellite-Ca -15.19 -16.62 -1.42 -0.088 0.56093E+04 193 beidellite-H -15.19 -17.13 -1.94 -0.124 0.76494E+04 194 beidellite-K -14.13 -15.92 -1.79 -0.110 0.70611E+04 195 beidellite-Mg -15.50 -16.68 -1.18 -0.073 0.46373E+04 196 beidellite-Na -14.07 -15.76 -1.69 -0.103 0.66562E+04 197 bornite -51.27 -51.63 -0.36 -0.027 0.14065E+04 199 chalcocite -13.27 -14.74 -1.47 -0.368 0.57939E+04 200 covellite -11.81 -13.20 -1.40 -0.532 0.55067E+04 202 montmorillonite-Ca -11.16 -12.25 -1.09 -0.067 0.42805E+04 203 montmorillonite-K -10.39 -11.55 -1.16 -0.071 0.45800E+04 204 montmorillonite-Mg -11.41 -12.31 -0.90 -0.056 0.35578E+04 205 montmorillonite-Na -10.03 -11.39 -1.36 -0.083 0.53639E+04 206 nontronite-Ca -3.60 -4.92 -1.32 -0.086 0.51999E+04 207 nontronite-H -3.61 -5.43 -1.83 -0.123 0.72079E+04 208 nontronite-K -2.54 -4.23 -1.69 -0.108 0.66439E+04 209 nontronite-Mg -3.85 -4.98 -1.13 -0.073 0.44355E+04 210 nontronite-Na -2.47 -4.06 -1.59 -0.102 0.62521E+04 215 gypsum -11.61 -13.80 -2.19 -0.548 0.86387E+04 232 alabandite -6.05 -7.54 -1.48 -0.494 0.58438E+04 234 anglesite -13.89 -16.49 -2.60 -1.300 0.10244E+05 238 boehmite -4.75 -5.75 -1.00 -0.166 0.39211E+04 242 copper,native 1.78 -1.53 -3.32 -1.154 0.13075E+05 244 ferrous-oxide 1.74 0.97 -0.77 -0.193 0.30395E+04 245 galena -9.15 -9.50 -0.35 -0.116 0.13698E+04 246 silver,native 0.56 -3.61 -4.17 -1.449 0.16415E+05 248 litharge 5.18 0.42 -4.76 -1.189 0.18739E+05 255 sphalerite -10.50 -10.53 -0.03 -0.011 0.13178E+03 256 wurtzite -9.72 -10.53 -0.82 -0.272 0.32203E+04 257 zincite 1.88 -0.61 -2.49 -0.623 0.98217E+04 258 an20ab80 -5.78 -5.79 -0.02 -0.001 0.69606E+02 259 an25ab75 -6.08 -6.08 -0.01 0.000 0.22665E+02 261 tr.625ac.25prg.125 8.74 7.91 -0.83 -0.022 0.32863E+04 Calculations done for 588.0000 Deg. C; 1691.0000 bar Temperature changed by -1.000 degrees to 587.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 25 Loop limit = 500 Temperature = 587.00 C Pressure = 1655.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5505E+02 kg liquid = 0.9918E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9955 Stoichiometric ionic strength = .3307527E+01 Osmotic coef. = 0.0000 True ionic strength = .2393152E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11267E-04 -4.9482 0.30007E-05 -5.5228 0.26632E+00 -0.5746 2 H2O 0.99550E+00 -0.0020 0.99550E+00 -0.0020 3 Cl- 0.20012E+00 -0.6987 0.48423E-01 -1.3150 0.24197E+00 -0.6162 4 SO4-- 0.18022E-03 -3.7442 0.11773E-05 -5.9291 0.65325E-02 -2.1849 5 HCO3- 0.25720E-04 -4.5897 0.67021E-05 -5.1738 0.26058E+00 -0.5841 6 HS- 0.15082E-03 -3.8215 0.36799E-04 -4.4342 0.24399E+00 -0.6126 7 H4SiO4 0.92647E-01 -1.0332 0.92647E-01 -1.0332 0.10000E+01 0.0000 8 Al+++ 0.52373E-17 -17.2809 0.49466E-22 -22.3057 0.94449E-05 -5.0248 9 Ca++ 0.23794E-05 -5.6235 0.12618E-07 -7.8990 0.53028E-02 -2.2755 10 Mg++ 0.12635E-05 -5.8984 0.55245E-08 -8.2577 0.43724E-02 -2.3593 11 Fe++ 0.19914E-07 -7.7008 0.91461E-10 -10.0388 0.45927E-02 -2.3379 12 K+ 0.53517E-01 -1.2715 0.14303E-01 -1.8446 0.26725E+00 -0.5731 13 Na+ 0.18344E+00 -0.7365 0.44972E-01 -1.3471 0.24515E+00 -0.6106 14 Mn++ 0.50148E-06 -6.2997 0.23871E-08 -8.6221 0.47601E-02 -2.3224 15 Zn++ 0.51983E-09 -9.2841 0.23874E-11 -11.6221 0.45927E-02 -2.3379 16 Cu+ 0.44088E-07 -7.3557 0.10779E-07 -7.9674 0.24450E+00 -0.6117 17 Pb++ 0.41725E-08 -8.3796 0.24722E-10 -10.6069 0.59250E-02 -2.2273 18 Ag+ 0.38804E-09 -9.4111 0.10211E-09 -9.9909 0.26314E+00 -0.5798 19 Ba++ 0.19609E-06 -6.7075 0.12457E-08 -8.9046 0.63529E-02 -2.1970 20 HPO4-- 0.99265E-09 -9.0032 0.65163E-11 -11.1860 0.65645E-02 -2.1828 21 HSiO3- 0.21815E-05 -5.6612 0.52787E-06 -6.2775 0.24197E+00 -0.6162 22 Ca(HSiO3)+ 0.13188E-07 -7.8798 0.35550E-08 -8.4492 0.26957E+00 -0.5693 23 Mg(HSiO3)+ 0.15037E-08 -8.8228 0.40535E-09 -9.3922 0.26957E+00 -0.5693 24 NaHSiO3,aq 0.14829E-05 -5.8289 0.14829E-05 -5.8289 0.10000E+01 0.0000 28 AgCl,aq 0.72654E-07 -7.1387 0.72654E-07 -7.1387 0.10000E+01 0.0000 29 AgCl2- 0.49704E-05 -5.3036 0.12027E-05 -5.9198 0.24197E+00 -0.6162 30 AgCl3-2 0.24077E-05 -5.6184 0.14589E-07 -7.8360 0.60591E-02 -2.2176 31 AgCl4-3 0.13168E-05 -5.8805 0.10699E-10 -10.9707 0.81245E-05 -5.0902 34 Ag(HS),aq 0.68373E-09 -9.1651 0.68373E-09 -9.1651 0.10000E+01 0.0000 35 Ag(HS)2- 0.42193E-08 -8.3748 0.10210E-08 -8.9910 0.24197E+00 -0.6162 36 AlO+ 0.10206E-10 -10.9911 0.27512E-11 -11.5605 0.26957E+00 -0.5693 38 HAlO2,aq 0.43599E-08 -8.3605 0.43599E-08 -8.3605 0.10000E+01 0.0000 39 AlO2- 0.19282E-04 -4.7148 0.40813E-05 -5.3892 0.21166E+00 -0.6744 41 Ba(HCO3)+ 0.10216E-05 -5.9907 0.28632E-06 -6.5432 0.28025E+00 -0.5525 42 BaCl+ 0.34488E-04 -4.4623 0.92969E-05 -5.0317 0.26957E+00 -0.5693 43 CH4,aq 0.19745E-08 -8.7045 0.23939E-08 -8.6209 0.12124E+01 0.0837 48 CO,aq 0.79420E-03 -3.1001 0.79420E-03 -3.1001 0.10000E+01 0.0000 49 CO2,aq 0.26773E+01 0.4277 0.32460E+01 0.5113 0.12124E+01 0.0837 50 CO3-2 0.52827E-10 -10.2771 0.32008E-12 -12.4947 0.60591E-02 -2.2176 51 CaCO3,aq 0.18075E-10 -10.7429 0.18075E-10 -10.7429 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.60267E-06 -6.2199 0.16246E-06 -6.7893 0.26957E+00 -0.5693 53 CaCl+ 0.22690E-03 -3.6442 0.61165E-04 -4.2135 0.26957E+00 -0.5693 54 CaCl2,aq 0.13621E-03 -3.8658 0.13621E-03 -3.8658 0.10000E+01 0.0000 55 CaOH+ 0.37024E-06 -6.4315 0.99804E-07 -7.0009 0.26957E+00 -0.5693 56 CaSO4,aq 0.13341E-06 -6.8748 0.13341E-06 -6.8748 0.10000E+01 0.0000 57 HCl,aq 0.11863E-02 -2.9258 0.11863E-02 -2.9258 0.10000E+01 0.0000 66 CuCl,aq 0.32823E-04 -4.4838 0.32823E-04 -4.4838 0.10000E+01 0.0000 67 CuCl2- 0.13077E-03 -3.8835 0.31643E-04 -4.4997 0.24197E+00 -0.6162 68 CuCl3-2 0.33346E-05 -5.4770 0.20204E-07 -7.6946 0.60591E-02 -2.2176 74 FeCl+ 0.59150E-06 -6.2280 0.15945E-06 -6.7974 0.26957E+00 -0.5693 75 FeCl2,aq 0.86026E-02 -2.0654 0.86026E-02 -2.0654 0.10000E+01 0.0000 77 FeO,aq 0.89335E-07 -7.0490 0.89335E-07 -7.0490 0.10000E+01 0.0000 78 FeOH+ 0.45764E-07 -7.3395 0.12337E-07 -7.9088 0.26957E+00 -0.5693 79 HFeO2- 0.12635E-07 -7.8984 0.30574E-08 -8.5146 0.24197E+00 -0.6162 82 FeO2- 0.80127E-08 -8.0962 0.19389E-08 -8.7125 0.24197E+00 -0.6162 83 HFeO2,aq 0.26731E-09 -9.5730 0.26731E-09 -9.5730 0.10000E+01 0.0000 84 H2,aq 0.45443E-02 -2.3425 0.55096E-02 -2.2589 0.12124E+01 0.0837 85 KCl,aq 0.56141E-01 -1.2507 0.56141E-01 -1.2507 0.10000E+01 0.0000 86 KHSO4,aq 0.12920E-01 -1.8888 0.12920E-01 -1.8888 0.10000E+01 0.0000 87 KOH,aq 0.98325E-06 -6.0073 0.98325E-06 -6.0073 0.10000E+01 0.0000 88 KSO4- 0.38699E-02 -2.4123 0.93642E-03 -3.0285 0.24197E+00 -0.6162 90 Mg(HCO3)+ 0.11047E-06 -6.9568 0.29779E-07 -7.5261 0.26957E+00 -0.5693 91 MgCl+ 0.18810E-04 -4.7256 0.50706E-05 -5.2949 0.26957E+00 -0.5693 92 MgOH+ 0.66215E-06 -6.1790 0.17850E-06 -6.7484 0.26957E+00 -0.5693 94 MnO,aq 0.35122E-07 -7.4544 0.35122E-07 -7.4544 0.10000E+01 0.0000 95 MnOH+ 0.14896E-06 -6.8269 0.40156E-07 -7.3963 0.26957E+00 -0.5693 97 HMnO2- 0.23250E-10 -10.6336 0.56260E-11 -11.2498 0.24197E+00 -0.6162 100 MnCl+ 0.11583E-02 -2.9362 0.31224E-03 -3.5055 0.26957E+00 -0.5693 101 MnSO4,aq 0.31997E-07 -7.4949 0.31997E-07 -7.4949 0.10000E+01 0.0000 102 NaCl,aq 0.37538E+00 -0.4255 0.37538E+00 -0.4255 0.10000E+01 0.0000 103 NaOH,aq 0.14306E-05 -5.8445 0.14306E-05 -5.8445 0.10000E+01 0.0000 105 OH- 0.94834E-05 -5.0230 0.20073E-05 -5.6974 0.21166E+00 -0.6744 110 HPO3-2 0.16206E-10 -10.7903 0.98191E-13 -13.0079 0.60591E-02 -2.2176 111 H3PO3,aq 0.12020E-09 -9.9201 0.12020E-09 -9.9201 0.10000E+01 0.0000 112 H2PO3- 0.50820E-08 -8.2940 0.12297E-08 -8.9102 0.24197E+00 -0.6162 113 H3PO4,aq 0.86627E-06 -6.0623 0.86627E-06 -6.0623 0.10000E+01 0.0000 114 H2PO4- 0.18916E-05 -5.7232 0.48118E-06 -6.3177 0.25437E+00 -0.5945 116 H4P2O7,aq 0.62107E-10 -10.2069 0.62107E-10 -10.2069 0.10000E+01 0.0000 117 H3P2O7- 0.12785E-08 -8.8933 0.30935E-09 -9.5095 0.24197E+00 -0.6162 118 H2P2O7-2 0.36741E-06 -6.4349 0.22262E-08 -8.6524 0.60591E-02 -2.2176 119 HP2O7-3 0.13242E-07 -7.8780 0.10759E-12 -12.9682 0.81245E-05 -5.0902 121 PbCl+ 0.24700E-05 -5.6073 0.66583E-06 -6.1766 0.26957E+00 -0.5693 122 PbCl2,aq 0.88686E-04 -4.0521 0.88686E-04 -4.0521 0.10000E+01 0.0000 123 PbCl3- 0.11078E-03 -3.9556 0.26805E-04 -4.5718 0.24197E+00 -0.6162 124 PbCl4-2 0.27831E-04 -4.5555 0.16863E-06 -6.7731 0.60591E-02 -2.2176 125 PbO,aq 0.39430E-08 -8.4042 0.39430E-08 -8.4042 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10336E-03 -3.9857 0.10336E-03 -3.9857 0.10000E+01 0.0000 128 Pb(HS)3- 0.98618E-05 -5.0060 0.23863E-05 -5.6223 0.24197E+00 -0.6162 129 H2S,aq 0.10458E+01 0.0194 0.12679E+01 0.1031 0.12124E+01 0.0837 130 S2-2 0.15820E-07 -7.8008 0.95854E-10 -10.0184 0.60591E-02 -2.2176 131 S3-2 0.16700E-08 -8.7773 0.10119E-10 -10.9949 0.60591E-02 -2.2176 132 S3- 0.21445E-01 -1.6687 0.51890E-02 -2.2849 0.24197E+00 -0.6162 133 S4-2 0.14658E-09 -9.8339 0.88813E-12 -12.0515 0.60591E-02 -2.2176 134 S5-2 0.10877E-10 -10.9635 0.65905E-13 -13.1811 0.60591E-02 -2.2176 135 SO2,aq 0.28302E+00 -0.5482 0.28302E+00 -0.5482 0.10000E+01 0.0000 136 SO3-2 0.62066E-09 -9.2071 0.58602E-11 -11.2321 0.94420E-02 -2.0249 137 HSO3- 0.43629E-03 -3.3602 0.10557E-03 -3.9765 0.24197E+00 -0.6162 138 HSO4- 0.12123E-01 -1.9164 0.33516E-02 -2.4747 0.27646E+00 -0.5584 140 S2O3-2 0.54409E-06 -6.2643 0.32967E-08 -8.4819 0.60591E-02 -2.2176 141 HS2O3- 0.71115E-06 -6.1480 0.17208E-06 -6.7643 0.24197E+00 -0.6162 142 H2S2O3,aq 0.24457E-07 -7.6116 0.24457E-07 -7.6116 0.10000E+01 0.0000 150 S4O6-2 0.70508E-09 -9.1518 0.42721E-11 -11.3694 0.60591E-02 -2.2176 152 ZnCl+ 0.66312E-03 -3.1784 0.17876E-03 -3.7477 0.26957E+00 -0.5693 153 ZnCl2,aq 0.14502E-02 -2.8386 0.14502E-02 -2.8386 0.10000E+01 0.0000 154 ZnCl3- 0.20161E-03 -3.6955 0.48783E-04 -4.3117 0.24197E+00 -0.6162 155 ZnO,aq 0.42377E-07 -7.3729 0.42377E-07 -7.3729 0.10000E+01 0.0000 156 ZnOH+ 0.33982E-05 -5.4688 0.91604E-06 -6.0381 0.26957E+00 -0.5693 158 HZnO2- 0.38135E-09 -9.4187 0.92277E-10 -10.0349 0.24197E+00 -0.6162 Charge balance for all species = 0.2552E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1126716E-04 0.4300597E+01 0.3531801E+04 0.0000 2 H2O 0.1000000E+01 0.5249813E+02 0.7705808E+06 0.0000 3 Cl- 0.2001154E+00 0.6568555E+00 0.1897386E+05 4.2078 4 SO4-- 0.1802160E-03 0.2537577E+00 0.1986104E+05 5.1164 5 HCO3- 0.2571999E-04 0.2678109E+01 0.1331415E+06 0.3490 6 HS- 0.1508240E-03 0.1169309E+01 0.3150813E+05 1.0886 7 H4SiO4 0.9264711E-01 0.9265079E-01 0.7255627E+04 -1.0332 8 Al+++ 0.5237326E-17 0.1928654E-04 0.4239877E+00 -5.7374 9 Ca++ 0.2379430E-05 0.3666095E-03 0.1197133E+02 3.1465 10 Mg++ 0.1263493E-05 0.2084788E-04 0.4129671E+00 2.7878 11 Fe++ 0.1991446E-07 0.8603406E-02 0.3914742E+03 1.0068 12 K+ 0.5351739E-01 0.1264487E+00 0.4028525E+04 3.6782 13 Na+ 0.1834449E+00 0.5588254E+00 0.1046753E+05 4.1757 14 Mn++ 0.5014840E-06 0.1159019E-02 0.5187957E+02 2.4234 15 Zn++ 0.5198315E-09 0.2318376E-02 0.1234796E+03 -0.5765 16 Cu+ 0.4408756E-07 0.1669724E-03 0.8644199E+01 -2.4446 17 Pb++ 0.4172541E-08 0.3429897E-03 0.5790055E+02 0.4386 18 Ag+ 0.3880444E-09 0.8772895E-05 0.7710392E+00 -4.4682 19 Ba++ 0.1960896E-06 0.3570580E-04 0.3995477E+01 2.1410 20 HPO4-- 0.9926497E-09 0.3528104E-05 0.2758992E+00 -0.1404 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265275E+01 -.2913161E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5206695E+02 -.1021735E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2516736E+00 0.4921100E-04 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159705E+01 0.4387663E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.9188983E-01 0.5170449E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1912813E-04 0.6754114E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3635984E-03 0.1643115E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8532745E-02 0.2340087E-03 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542357E+00 0.3636831E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1656010E-03 0.2340087E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.3541254E-04 0.1995991E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3499127E-05 0.5068373E-05 0.0000000E+00 Chg. balance for solid moles: 0.1847E-18 Mass of aqueous solution: 0.121727E+04 g Temperature = 587.00 C Pressure = 1655.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1689E-05 -5.772 0.8486E-03 -3.071 0.2644E-01 0.2697E-03 quartz 0.5030E-01 -1.298 3.022 0.480 94.17 1.141 barite 0.1996E-04 -4.700 0.4659E-02 -2.332 0.1452 0.1040E-02 chalcopyrite 0.2340E-03 -3.631 0.4294E-01 -1.367 1.338 0.1002E-01 an30ab70 0.5195E-03 -3.284 0.1387 -0.858 4.323 0.5209E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.209303 g Volume = 1.204714 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 30 apatite-OH -50.96 -50.96 0.00 0.000 -0.27966E-10 144 quartz -1.03 -1.03 0.00 0.000 0.00000E+00 237 barite -14.83 -14.83 0.00 0.000 0.00000E+00 240 chalcopyrite -22.23 -22.23 0.00 0.000 0.00000E+00 260 an30ab70 -6.38 -6.38 0.00 0.000 -0.13983E-10 106 magnetite 1.19 1.26 0.07 0.006 -0.28427E+03 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.289 0.11362E+04 2.930 2 CO2,gas -9.23 -10.69 -1.47 -0.489 0.57715E+04 1.752 3 CH4,gas 6.92 -3.68 -10.60 -2.650 0.41720E+05 -7.381 4 H2,gas 5.80 1.75 -4.04 -2.310 0.15912E+05 -0.824 5 H2S,gas -7.68 -9.96 -2.28 -1.138 0.89564E+04 0.943 6 CO,gas -3.26 -8.94 -5.68 -1.747 0.22351E+05 -2.460 7 SO3,gas -6.66 -16.97 -10.31 -2.577 0.40572E+05 -7.089 8 O2,gas 16.51 -3.51 -20.02 -13.348 0.78803E+05 -16.803 9 HCl,gas -5.70 -6.84 -1.13 -0.567 0.44596E+04 -1.133 10 acmite 3.80 2.24 -1.55 -0.161 0.61152E+04 12 akimotoite 5.83 1.76 -4.07 -0.814 0.16027E+05 13 akimotoite-Fe 3.80 -0.02 -3.82 -0.764 0.15044E+05 14 albite-high -4.51 -4.65 -0.15 -0.011 0.57138E+03 15 albite -4.48 -4.65 -0.17 -0.013 0.68476E+03 16 almandine -10.30 -11.55 -1.25 -0.063 0.49331E+04 17 pyrope -3.88 -6.21 -2.33 -0.116 0.91579E+04 18 analcite -2.66 -3.63 -0.96 -0.107 0.37916E+04 19 andalusite -12.22 -12.51 -0.29 -0.029 0.11536E+04 20 andradite 11.08 6.60 -4.48 -0.233 0.17631E+05 21 grossular -0.46 -5.13 -4.67 -0.234 0.18387E+05 22 anhydrite -13.81 -13.83 -0.02 -0.010 0.82235E+02 24 annite -0.73 -2.14 -1.41 -0.078 0.55379E+04 25 phlogopite 3.71 3.20 -0.51 -0.028 0.19917E+04 27 anorthite -9.92 -10.39 -0.48 -0.037 0.18823E+04 28 anthophyllite 13.32 11.27 -2.06 -0.056 0.80944E+04 29 anthophyllite-Fe 1.16 -1.20 -2.36 -0.064 0.92836E+04 31 apatite-OH-zs -48.86 -50.96 -2.10 -0.162 0.82837E+04 32 apatite-Cl-zs -54.72 -57.80 -3.08 -0.257 0.12140E+05 33 aragonite -4.17 -7.55 -3.38 -1.126 0.13293E+05 34 brucite 4.98 2.78 -2.19 -0.439 0.86386E+04 35 calcite -4.27 -7.55 -3.28 -1.095 0.12925E+05 36 carnegieite-low -0.82 -2.59 -1.77 -0.254 0.69861E+04 37 carnegieite-high -0.75 -2.59 -1.84 -0.263 0.72453E+04 38 carpholite-Mg -8.98 -10.76 -1.77 -0.118 0.69845E+04 39 carpholite-Fe -10.29 -12.54 -2.25 -0.150 0.88528E+04 40 celadonite -1.30 -3.40 -2.10 -0.123 0.82623E+04 41 celadonite-Fe -2.66 -5.18 -2.52 -0.148 0.99114E+04 42 chrysotile 8.65 6.30 -2.35 -0.196 0.92610E+04 44 clinochlore 0.56 -0.65 -1.21 -0.038 0.47473E+04 45 daphnite -6.25 -9.55 -3.30 -0.103 0.12987E+05 47 chlorite-Al-free 17.50 12.59 -4.91 -0.205 0.19329E+05 48 chloritoid-Mg -8.62 -9.73 -1.10 -0.073 0.43336E+04 49 chloritoid-Fe -10.49 -11.51 -1.02 -0.068 0.40183E+04 50 chloritoid-Mn -8.32 -10.09 -1.77 -0.118 0.69591E+04 52 coesite -0.75 -1.03 -0.28 -0.092 0.10904E+04 53 cordierite-H -22.12 -22.54 -0.41 -0.015 0.16283E+04 54 cordierite-Fe -24.52 -26.10 -1.58 -0.054 0.62046E+04 55 cordierite-Mn -20.11 -23.26 -3.15 -0.109 0.12401E+05 56 corundum -11.02 -11.48 -0.46 -0.042 0.18005E+04 58 cristobalite -0.98 -1.03 -0.05 -0.017 0.20614E+03 59 cummingtonite 13.38 11.27 -2.11 -0.057 0.83205E+04 61 cymrite-K -2.88 -5.15 -2.27 -0.189 0.89399E+04 63 diaspore -5.01 -5.74 -0.73 -0.122 0.28834E+04 65 diopside 5.15 3.87 -1.28 -0.128 0.50300E+04 66 hedenbergite 3.78 2.09 -1.69 -0.169 0.66473E+04 68 eastonite -8.89 -10.03 -1.14 -0.044 0.44994E+04 69 enstatite 4.32 3.51 -0.81 -0.081 0.31698E+04 70 clinoenstatite-HiP 4.80 3.51 -1.29 -0.129 0.50595E+04 71 clinoenstatite 4.31 3.51 -0.79 -0.079 0.31198E+04 72 protoenstatite 4.45 3.51 -0.94 -0.094 0.36822E+04 73 epidote -6.27 -8.15 -1.88 -0.091 0.74089E+04 74 clinozoisite -11.77 -14.02 -2.25 -0.102 0.88443E+04 75 epidote-Fe 0.89 -2.28 -3.18 -0.165 0.12514E+05 76 fayalite 1.81 0.98 -0.83 -0.119 0.32806E+04 77 ferrosilite 0.87 -0.05 -0.92 -0.092 0.36248E+04 78 forsterite 5.67 4.54 -1.13 -0.161 0.44428E+04 79 gedrite -13.62 -15.21 -1.58 -0.043 0.62374E+04 81 gibbsite -3.42 -5.74 -2.32 -0.332 0.91350E+04 82 glaucophane 0.04 -3.01 -3.05 -0.083 0.12018E+05 83 glaucophane-Fe -3.85 -8.35 -4.51 -0.122 0.17739E+05 84 goethite 0.90 0.13 -0.77 -0.168 0.30495E+04 86 greenalite 3.97 0.95 -3.02 -0.252 0.11890E+05 87 grunerite 1.69 -1.20 -2.89 -0.078 0.11367E+05 88 halite -0.58 -2.66 -2.08 -1.042 0.82010E+04 89 hematite 0.30 0.26 -0.04 -0.005 0.16316E+03 90 heulandite -12.85 -15.55 -2.70 -0.123 0.10640E+05 91 hercynite -9.63 -10.48 -0.85 -0.057 0.33468E+04 94 jadeite -1.98 -3.62 -1.64 -0.164 0.64514E+04 96 kalsilite -1.45 -3.09 -1.64 -0.235 0.64648E+04 97 kaolinite -10.99 -13.54 -2.55 -0.232 0.10034E+05 98 kyanite -12.07 -12.51 -0.44 -0.044 0.17378E+04 100 laumontite -9.18 -12.46 -3.28 -0.219 0.12910E+05 101 lawsonite -7.22 -10.40 -3.18 -0.212 0.12525E+05 102 leucite -3.13 -4.12 -0.99 -0.099 0.39158E+04 104 lizardite 8.84 6.30 -2.54 -0.212 0.10008E+05 105 magnesite -5.20 -7.91 -2.71 -0.904 0.10673E+05 107 minnesotaite 0.68 -1.10 -1.78 -0.105 0.70051E+04 108 minnesotaite-Mg 6.44 4.24 -2.20 -0.129 0.86535E+04 109 magnesioferrite 4.16 3.04 -1.12 -0.092 0.44162E+04 111 manganosite 5.03 2.42 -2.61 -0.653 0.10284E+05 112 margarite -20.47 -21.88 -1.40 -0.056 0.55206E+04 115 microcline -5.07 -5.15 -0.08 -0.006 0.31018E+03 116 monticellite 8.30 4.90 -3.40 -0.486 0.13393E+05 118 mullite-Si -11.50 -12.51 -1.01 -0.101 0.39743E+04 119 muscovite -15.97 -16.63 -0.66 -0.039 0.25999E+04 120 paragonite -15.29 -16.14 -0.84 -0.049 0.33116E+04 121 nepheline -1.11 -2.59 -1.49 -0.212 0.58458E+04 122 osumilite(2) -14.73 -16.51 -1.78 -0.037 0.69976E+04 123 osumilite-Fe -31.32 -33.31 -1.99 -0.041 0.78270E+04 124 pargasite 1.75 -1.79 -3.54 -0.093 0.13942E+05 125 periclase 5.16 2.79 -2.38 -0.594 0.93580E+04 126 periclase-Fe 2.66 1.00 -1.66 -0.414 0.65245E+04 127 perovskite-Al -9.33 -11.48 -2.15 -0.195 0.84541E+04 132 phlogopite-Na 4.57 3.70 -0.87 -0.048 0.34251E+04 134 prehnite -5.28 -8.28 -3.00 -0.176 0.11798E+05 135 prehnite-Fe 0.61 -2.41 -3.03 -0.182 0.11910E+05 138 px-Mg-tschermaks -8.07 -9.72 -1.65 -0.118 0.65082E+04 139 px-Ca-tschermaks -7.05 -9.37 -2.31 -0.165 0.90943E+04 140 pyrite -20.65 -20.66 -0.01 -0.002 0.34358E+02 141 pyrrhotite -8.36 -8.95 -0.59 -0.196 0.23197E+04 142 pyrrhotiteFe0.875 -9.07 -9.29 -0.22 -0.082 0.88205E+03 143 pyrophyllite -14.44 -15.60 -1.16 -0.072 0.45539E+04 146 riebeckite 6.07 3.38 -2.68 -0.074 0.10558E+05 147 ringwoodite-Fe 2.79 0.98 -1.81 -0.259 0.71341E+04 148 ringwoodite-Mg 8.75 4.54 -4.21 -0.602 0.16576E+05 149 rhodochrosite -5.06 -8.27 -3.21 -1.071 0.12650E+05 150 rhodonite 2.41 1.39 -1.02 -0.204 0.40214E+04 151 sanidine -4.55 -5.15 -0.60 -0.046 0.23791E+04 152 sapphirine(351) -45.55 -50.07 -4.53 -0.069 0.17821E+05 153 siderite -6.96 -9.69 -2.73 -0.910 0.10739E+05 154 sillimanite -12.19 -12.51 -0.32 -0.032 0.12646E+04 156 spinel -7.52 -8.69 -1.17 -0.078 0.46165E+04 158 staurolite-Fe -102.47 -107.03 -4.56 -0.042 0.17954E+05 162 stilpnomelane-Fe -8.57 -12.86 -4.29 -0.128 0.16890E+05 163 stilpnomelane-Mg -2.11 -3.96 -1.85 -0.055 0.72687E+04 164 stishovite 1.85 -1.03 -2.88 -0.960 0.11336E+05 165 sudoite-Fe -20.50 -24.05 -3.55 -0.115 0.13980E+05 166 sudoite -18.37 -20.49 -2.12 -0.068 0.83420E+04 167 sulfur -10.22 -11.71 -1.49 -0.457 0.58478E+04 168 sylvite -0.49 -3.16 -2.67 -1.336 0.10519E+05 169 talc 4.74 4.24 -0.50 -0.029 0.19637E+04 170 talc-Fe 2.03 -1.10 -3.13 -0.184 0.12339E+05 171 talc-tschermaks -7.58 -9.00 -1.42 -0.084 0.55957E+04 173 tephroite 6.13 3.81 -2.32 -0.331 0.91289E+04 176 topaz-H -10.16 -12.51 -2.35 -0.214 0.92610E+04 177 tremolite 14.41 11.98 -2.43 -0.066 0.95556E+04 178 ferroactinolite 7.97 3.08 -4.89 -0.132 0.19244E+05 179 troilite-low -8.26 -8.95 -0.69 -0.229 0.27027E+04 180 tschermakite -11.76 -14.49 -2.73 -0.074 0.10742E+05 183 wadsleyite-Fe 2.64 0.98 -1.66 -0.237 0.65322E+04 184 wadsleyite-Mg 7.83 4.54 -3.29 -0.469 0.12933E+05 185 wairakite -10.96 -12.46 -1.50 -0.088 0.59036E+04 186 walstromite 4.54 2.12 -2.42 -0.485 0.95418E+04 187 wollastonite 4.14 2.12 -2.02 -0.404 0.79559E+04 188 pseudo-wollastonite 4.25 2.12 -2.13 -0.426 0.83857E+04 189 zoisite -11.83 -14.02 -2.19 -0.099 0.86050E+04 192 beidellite-Ca -15.18 -16.64 -1.45 -0.090 0.57177E+04 193 beidellite-H -15.18 -17.15 -1.98 -0.126 0.77739E+04 194 beidellite-K -14.12 -15.94 -1.82 -0.112 0.71679E+04 195 beidellite-Mg -15.49 -16.69 -1.21 -0.075 0.47526E+04 196 beidellite-Na -14.06 -15.78 -1.72 -0.105 0.67635E+04 197 bornite -51.45 -51.92 -0.47 -0.035 0.18564E+04 199 chalcocite -13.32 -14.85 -1.53 -0.382 0.60166E+04 200 covellite -11.85 -13.28 -1.43 -0.543 0.56112E+04 202 montmorillonite-Ca -11.17 -12.27 -1.10 -0.068 0.43243E+04 203 montmorillonite-K -10.40 -11.57 -1.18 -0.072 0.46249E+04 204 montmorillonite-Mg -11.41 -12.33 -0.92 -0.057 0.36026E+04 205 montmorillonite-Na -10.04 -11.41 -1.37 -0.084 0.54037E+04 206 nontronite-Ca -3.63 -4.90 -1.27 -0.082 0.50004E+04 207 nontronite-H -3.63 -5.42 -1.78 -0.120 0.70244E+04 208 nontronite-K -2.57 -4.20 -1.64 -0.105 0.64426E+04 209 nontronite-Mg -3.88 -4.96 -1.08 -0.070 0.42379E+04 210 nontronite-Na -2.50 -4.04 -1.54 -0.099 0.60513E+04 215 gypsum -11.66 -13.83 -2.17 -0.543 0.85494E+04 232 alabandite -6.08 -7.53 -1.45 -0.484 0.57150E+04 234 anglesite -13.95 -16.54 -2.58 -1.292 0.10173E+05 238 boehmite -4.73 -5.74 -1.01 -0.168 0.39746E+04 242 copper,native 1.78 -1.57 -3.35 -1.165 0.13183E+05 244 ferrous-oxide 1.75 1.00 -0.75 -0.187 0.29424E+04 245 galena -9.19 -9.52 -0.33 -0.109 0.12891E+04 246 silver,native 0.56 -3.59 -4.15 -1.443 0.16327E+05 248 litharge 5.18 0.44 -4.74 -1.185 0.18663E+05 255 sphalerite -10.53 -10.53 0.00 -0.001 0.77511E+01 256 wurtzite -9.75 -10.53 -0.79 -0.262 0.30961E+04 257 zincite 1.89 -0.58 -2.47 -0.616 0.97055E+04 258 an20ab80 -5.78 -5.80 -0.02 -0.001 0.69194E+02 259 an25ab75 -6.08 -6.09 -0.01 0.000 0.22756E+02 261 tr.625ac.25prg.125 8.71 8.03 -0.68 -0.018 0.26742E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 500 Temperature = 587.00 C Pressure = 1655.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5505E+02 kg liquid = 0.9918E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9955 Stoichiometric ionic strength = .3306948E+01 Osmotic coef. = 0.0000 True ionic strength = .2391613E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11380E-04 -4.9439 0.30316E-05 -5.5183 0.26639E+00 -0.5745 2 H2O 0.99550E+00 -0.0020 0.99550E+00 -0.0020 3 Cl- 0.20031E+00 -0.6983 0.48484E-01 -1.3144 0.24204E+00 -0.6161 4 SO4-- 0.17676E-03 -3.7526 0.11559E-05 -5.9371 0.65394E-02 -2.1845 5 HCO3- 0.25451E-04 -4.5943 0.66338E-05 -5.1782 0.26064E+00 -0.5840 6 HS- 0.14930E-03 -3.8260 0.36436E-04 -4.4385 0.24406E+00 -0.6125 7 H4SiO4 0.92647E-01 -1.0332 0.92647E-01 -1.0332 0.10000E+01 0.0000 8 Al+++ 0.54457E-17 -17.2639 0.51566E-22 -22.2876 0.94690E-05 -5.0237 9 Ca++ 0.23743E-05 -5.6245 0.12605E-07 -7.8995 0.53089E-02 -2.2750 10 Mg++ 0.12613E-05 -5.8992 0.55219E-08 -8.2579 0.43778E-02 -2.3587 11 Fe++ 0.19204E-07 -7.7166 0.88305E-10 -10.0540 0.45983E-02 -2.3374 12 K+ 0.53555E-01 -1.2712 0.14316E-01 -1.8442 0.26731E+00 -0.5730 13 Na+ 0.18326E+00 -0.7369 0.44938E-01 -1.3474 0.24522E+00 -0.6104 14 Mn++ 0.50037E-06 -6.3007 0.23847E-08 -8.6226 0.47658E-02 -2.3219 15 Zn++ 0.51808E-09 -9.2856 0.23823E-11 -11.6230 0.45983E-02 -2.3374 16 Cu+ 0.47033E-07 -7.3276 0.11503E-07 -7.9392 0.24457E+00 -0.6116 17 Pb++ 0.41874E-08 -8.3781 0.24838E-10 -10.6049 0.59315E-02 -2.2268 18 Ag+ 0.38703E-09 -9.4123 0.10187E-09 -9.9920 0.26320E+00 -0.5797 19 Ba++ 0.19950E-06 -6.7000 0.12688E-08 -8.8966 0.63597E-02 -2.1966 20 HPO4-- 0.10069E-08 -8.9970 0.66168E-11 -11.1794 0.65714E-02 -2.1823 21 HSiO3- 0.21587E-05 -5.6658 0.52250E-06 -6.2819 0.24204E+00 -0.6161 22 Ca(HSiO3)+ 0.13038E-07 -7.8848 0.35153E-08 -8.4540 0.26963E+00 -0.5692 23 Mg(HSiO3)+ 0.14873E-08 -8.8276 0.40103E-09 -9.3968 0.26963E+00 -0.5692 24 NaHSiO3,aq 0.14667E-05 -5.8337 0.14667E-05 -5.8337 0.10000E+01 0.0000 28 AgCl,aq 0.72573E-07 -7.1392 0.72573E-07 -7.1392 0.10000E+01 0.0000 29 AgCl2- 0.49698E-05 -5.3037 0.12029E-05 -5.9198 0.24204E+00 -0.6161 30 AgCl3-2 0.24085E-05 -5.6182 0.14609E-07 -7.8354 0.60657E-02 -2.2171 31 AgCl4-3 0.13169E-05 -5.8804 0.10727E-10 -10.9695 0.81459E-05 -5.0891 34 Ag(HS),aq 0.67538E-09 -9.1705 0.67538E-09 -9.1705 0.10000E+01 0.0000 35 Ag(HS)2- 0.41255E-08 -8.3845 0.99854E-09 -9.0006 0.24204E+00 -0.6161 36 AlO+ 0.10421E-10 -10.9821 0.28099E-11 -11.5513 0.26963E+00 -0.5692 38 HAlO2,aq 0.44076E-08 -8.3558 0.44076E-08 -8.3558 0.10000E+01 0.0000 39 AlO2- 0.19288E-04 -4.7147 0.40839E-05 -5.3889 0.21173E+00 -0.6742 41 Ba(HCO3)+ 0.10297E-05 -5.9873 0.28864E-06 -6.5396 0.28031E+00 -0.5524 42 BaCl+ 0.35163E-04 -4.4539 0.94808E-05 -5.0232 0.26963E+00 -0.5692 43 CH4,aq 0.19709E-08 -8.7053 0.23895E-08 -8.6217 0.12124E+01 0.0836 48 CO,aq 0.79383E-03 -3.1003 0.79383E-03 -3.1003 0.10000E+01 0.0000 49 CO2,aq 0.26773E+01 0.4277 0.32459E+01 0.5113 0.12124E+01 0.0836 50 CO3-2 0.51699E-10 -10.2865 0.31359E-12 -12.5036 0.60657E-02 -2.2171 51 CaCO3,aq 0.17691E-10 -10.7523 0.17691E-10 -10.7523 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.59580E-06 -6.2249 0.16064E-06 -6.7941 0.26963E+00 -0.5692 53 CaCl+ 0.22691E-03 -3.6441 0.61182E-04 -4.2134 0.26963E+00 -0.5692 54 CaCl2,aq 0.13642E-03 -3.8651 0.13642E-03 -3.8651 0.10000E+01 0.0000 55 CaOH+ 0.36602E-06 -6.4365 0.98690E-07 -7.0057 0.26963E+00 -0.5692 56 CaSO4,aq 0.13086E-06 -6.8832 0.13086E-06 -6.8832 0.10000E+01 0.0000 57 HCl,aq 0.12001E-02 -2.9208 0.12001E-02 -2.9208 0.10000E+01 0.0000 66 CuCl,aq 0.35070E-04 -4.4551 0.35070E-04 -4.4551 0.10000E+01 0.0000 67 CuCl2- 0.13986E-03 -3.8543 0.33852E-04 -4.4704 0.24204E+00 -0.6161 68 CuCl3-2 0.35680E-05 -5.4476 0.21642E-07 -7.6647 0.60657E-02 -2.2171 74 FeCl+ 0.57169E-06 -6.2428 0.15414E-06 -6.8121 0.26963E+00 -0.5692 75 FeCl2,aq 0.83268E-02 -2.0795 0.83268E-02 -2.0795 0.10000E+01 0.0000 77 FeO,aq 0.84505E-07 -7.0731 0.84505E-07 -7.0731 0.10000E+01 0.0000 78 FeOH+ 0.43726E-07 -7.3593 0.11790E-07 -7.9285 0.26963E+00 -0.5692 79 HFeO2- 0.11827E-07 -7.9271 0.28626E-08 -8.5432 0.24204E+00 -0.6161 82 FeO2- 0.75019E-08 -8.1248 0.18158E-08 -8.7409 0.24204E+00 -0.6161 83 HFeO2,aq 0.25292E-09 -9.5970 0.25292E-09 -9.5970 0.10000E+01 0.0000 84 H2,aq 0.45424E-02 -2.3427 0.55071E-02 -2.2591 0.12124E+01 0.0836 85 KCl,aq 0.56264E-01 -1.2498 0.56264E-01 -1.2498 0.10000E+01 0.0000 86 KHSO4,aq 0.12827E-01 -1.8919 0.12827E-01 -1.8919 0.10000E+01 0.0000 87 KOH,aq 0.97414E-06 -6.0114 0.97414E-06 -6.0114 0.10000E+01 0.0000 88 KSO4- 0.38021E-02 -2.4200 0.92027E-03 -3.0361 0.24204E+00 -0.6161 90 Mg(HCO3)+ 0.10927E-06 -6.9615 0.29462E-07 -7.5307 0.26963E+00 -0.5692 91 MgCl+ 0.18821E-04 -4.7254 0.50746E-05 -5.2946 0.26963E+00 -0.5692 92 MgOH+ 0.65496E-06 -6.1838 0.17659E-06 -6.7530 0.26963E+00 -0.5692 94 MnO,aq 0.34375E-07 -7.4638 0.34375E-07 -7.4638 0.10000E+01 0.0000 95 MnOH+ 0.14726E-06 -6.8319 0.39706E-07 -7.4011 0.26963E+00 -0.5692 97 HMnO2- 0.22518E-10 -10.6475 0.54503E-11 -11.2636 0.24204E+00 -0.6161 100 MnCl+ 0.11583E-02 -2.9362 0.31231E-03 -3.5054 0.26963E+00 -0.5692 101 MnSO4,aq 0.31383E-07 -7.5033 0.31383E-07 -7.5033 0.10000E+01 0.0000 102 NaCl,aq 0.37557E+00 -0.4253 0.37557E+00 -0.4253 0.10000E+01 0.0000 103 NaOH,aq 0.14149E-05 -5.8493 0.14149E-05 -5.8493 0.10000E+01 0.0000 105 OH- 0.93836E-05 -5.0276 0.19868E-05 -5.7018 0.21173E+00 -0.6742 110 HPO3-2 0.16430E-10 -10.7844 0.99660E-13 -13.0015 0.60657E-02 -2.2171 111 H3PO3,aq 0.12452E-09 -9.9048 0.12452E-09 -9.9048 0.10000E+01 0.0000 112 H2PO3- 0.52096E-08 -8.2832 0.12609E-08 -8.8993 0.24204E+00 -0.6161 113 H3PO4,aq 0.89782E-06 -6.0468 0.89782E-06 -6.0468 0.10000E+01 0.0000 114 H2PO4- 0.19401E-05 -5.7122 0.49362E-06 -6.3066 0.25443E+00 -0.5944 116 H4P2O7,aq 0.66713E-10 -10.1758 0.66713E-10 -10.1758 0.10000E+01 0.0000 117 H3P2O7- 0.13589E-08 -8.8668 0.32891E-09 -9.4829 0.24204E+00 -0.6161 118 H2P2O7-2 0.38624E-06 -6.4131 0.23428E-08 -8.6303 0.60657E-02 -2.2171 119 HP2O7-3 0.13758E-07 -7.8614 0.11207E-12 -12.9505 0.81459E-05 -5.0891 121 PbCl+ 0.24841E-05 -5.6048 0.66979E-06 -6.1741 0.26963E+00 -0.5692 122 PbCl2,aq 0.89326E-04 -4.0490 0.89326E-04 -4.0490 0.10000E+01 0.0000 123 PbCl3- 0.11169E-03 -3.9520 0.27032E-04 -4.5681 0.24204E+00 -0.6161 124 PbCl4-2 0.28073E-04 -4.5517 0.17028E-06 -6.7688 0.60657E-02 -2.2171 125 PbO,aq 0.38811E-08 -8.4110 0.38811E-08 -8.4110 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10180E-03 -3.9923 0.10180E-03 -3.9923 0.10000E+01 0.0000 128 Pb(HS)3- 0.96148E-05 -5.0171 0.23272E-05 -5.6332 0.24204E+00 -0.6161 129 H2S,aq 0.10462E+01 0.0196 0.12683E+01 0.1032 0.12124E+01 0.0836 130 S2-2 0.15499E-07 -7.8097 0.94015E-10 -10.0268 0.60657E-02 -2.2171 131 S3-2 0.16374E-08 -8.7858 0.99321E-11 -11.0030 0.60657E-02 -2.2171 132 S3- 0.21265E-01 -1.6723 0.51470E-02 -2.2884 0.24204E+00 -0.6161 133 S4-2 0.14383E-09 -9.8421 0.87244E-12 -12.0593 0.60657E-02 -2.2171 134 S5-2 0.10682E-10 -10.9714 0.64792E-13 -13.1885 0.60657E-02 -2.2171 135 SO2,aq 0.28350E+00 -0.5474 0.28350E+00 -0.5474 0.10000E+01 0.0000 136 SO3-2 0.60856E-09 -9.2157 0.57512E-11 -11.2402 0.94504E-02 -2.0245 137 HSO3- 0.43246E-03 -3.3641 0.10467E-03 -3.9802 0.24204E+00 -0.6161 138 HSO4- 0.12023E-01 -1.9200 0.33246E-02 -2.4783 0.27652E+00 -0.5583 140 S2O3-2 0.53380E-06 -6.2726 0.32379E-08 -8.4897 0.60657E-02 -2.2171 141 HS2O3- 0.70545E-06 -6.1515 0.17075E-06 -6.7676 0.24204E+00 -0.6161 142 H2S2O3,aq 0.24517E-07 -7.6105 0.24517E-07 -7.6105 0.10000E+01 0.0000 150 S4O6-2 0.69376E-09 -9.1588 0.42081E-11 -11.3759 0.60657E-02 -2.2171 152 ZnCl+ 0.66237E-03 -3.1789 0.17859E-03 -3.7481 0.26963E+00 -0.5692 153 ZnCl2,aq 0.14507E-02 -2.8384 0.14507E-02 -2.8384 0.10000E+01 0.0000 154 ZnCl3- 0.20188E-03 -3.6949 0.48863E-04 -4.3110 0.24204E+00 -0.6161 155 ZnO,aq 0.41428E-07 -7.3827 0.41428E-07 -7.3827 0.10000E+01 0.0000 156 ZnOH+ 0.33556E-05 -5.4742 0.90475E-06 -6.0435 0.26963E+00 -0.5692 158 HZnO2- 0.36892E-09 -9.4331 0.89294E-10 -10.0492 0.24204E+00 -0.6161 Charge balance for all species = 0.2552E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1138010E-04 0.4301158E+01 0.3532303E+04 0.0000 2 H2O 0.1000000E+01 0.5249809E+02 0.7705890E+06 0.0000 3 Cl- 0.2003138E+00 0.6568586E+00 0.1897417E+05 4.2039 4 SO4-- 0.1767568E-03 0.2537371E+00 0.1985965E+05 5.0996 5 HCO3- 0.2545149E-04 0.2678121E+01 0.1331436E+06 0.3401 6 HS- 0.1492959E-03 0.1169360E+01 0.3150987E+05 1.0799 7 H4SiO4 0.9264736E-01 0.9265100E-01 0.7255727E+04 -1.0332 8 Al+++ 0.5445743E-17 0.1929223E-04 0.4241176E+00 -5.7326 9 Ca++ 0.2374340E-05 0.3668108E-03 0.1197805E+02 3.1372 10 Mg++ 0.1261332E-05 0.2084798E-04 0.4129738E+00 2.7788 11 Fe++ 0.1920389E-07 0.8327560E-02 0.3789269E+03 0.9826 12 K+ 0.5355480E-01 0.1264493E+00 0.4028591E+04 3.6741 13 Na+ 0.1832566E+00 0.5588280E+00 0.1046770E+05 4.1709 14 Mn++ 0.5003668E-06 0.1159025E-02 0.5188041E+02 2.4141 15 Zn++ 0.5180763E-09 0.2318387E-02 0.1234816E+03 -0.5863 16 Cu+ 0.4703341E-07 0.1785468E-03 0.9243514E+01 -2.4209 17 Pb++ 0.4187418E-08 0.3429913E-03 0.5790149E+02 0.4318 18 Ag+ 0.3870294E-09 0.8772937E-05 0.7710517E+00 -4.4736 19 Ba++ 0.1995043E-06 0.3639183E-04 0.4072290E+01 2.1401 20 HPO4-- 0.1006898E-08 0.3647107E-05 0.2852086E+00 -0.1427 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265812E+01 -.3449377E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5206666E+02 -.1018831E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2516519E+00 0.7085419E-04 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159751E+01 0.3934859E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.9188961E-01 0.5170471E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1913369E-04 0.6754058E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3637964E-03 0.1641135E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.8259125E-02 0.5076289E-03 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542357E+00 0.3636801E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1770795E-03 0.2225302E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.3609276E-04 0.1927969E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3617136E-05 0.4950364E-05 0.0000000E+00 Chg. balance for solid moles: -.4066E-19 Mass of aqueous solution: 0.121725E+04 g Temperature = 587.00 C Pressure = 1655.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1650E-05 -5.782 0.8289E-03 -3.082 0.2567E-01 0.2634E-03 quartz 0.5030E-01 -1.298 3.022 0.480 93.59 1.141 barite 0.1928E-04 -4.715 0.4500E-02 -2.347 0.1394 0.1004E-02 chalcopyrite 0.2225E-03 -3.653 0.4083E-01 -1.389 1.265 0.9532E-02 an30ab70 0.5195E-03 -3.284 0.1387 -0.858 4.296 0.5209E-01 magnetite 0.9503E-04 -4.022 0.2200E-01 -1.658 0.6813 0.4231E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.229032 g Volume = 1.208417 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 30 apatite-OH -50.96 -50.96 0.00 0.000 0.00000E+00 106 magnetite 1.19 1.19 0.00 0.000 0.18353E-10 144 quartz -1.03 -1.03 0.00 0.000 0.00000E+00 237 barite -14.83 -14.83 0.00 0.000 0.69916E-11 240 chalcopyrite -22.23 -22.23 0.00 0.000 0.00000E+00 260 an30ab70 -6.38 -6.38 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.289 0.11362E+04 2.930 2 CO2,gas -9.23 -10.69 -1.47 -0.489 0.57715E+04 1.752 3 CH4,gas 6.92 -3.68 -10.60 -2.650 0.41723E+05 -7.382 4 H2,gas 5.80 1.75 -4.04 -2.310 0.15913E+05 -0.824 5 H2S,gas -7.68 -9.96 -2.28 -1.138 0.89559E+04 0.943 6 CO,gas -3.26 -8.94 -5.68 -1.747 0.22352E+05 -2.460 7 SO3,gas -6.66 -16.97 -10.31 -2.577 0.40568E+05 -7.088 8 O2,gas 16.51 -3.51 -20.02 -13.347 0.78801E+05 -16.802 9 HCl,gas -5.70 -6.83 -1.13 -0.564 0.44400E+04 -1.128 10 acmite 3.80 2.22 -1.58 -0.164 0.62286E+04 12 akimotoite 5.83 1.75 -4.08 -0.816 0.16062E+05 13 akimotoite-Fe 3.80 -0.05 -3.85 -0.769 0.15139E+05 14 albite-high -4.51 -4.65 -0.15 -0.011 0.57158E+03 15 albite -4.48 -4.65 -0.17 -0.013 0.68497E+03 16 almandine -10.30 -11.62 -1.32 -0.066 0.51810E+04 17 pyrope -3.88 -6.23 -2.34 -0.117 0.92281E+04 18 analcite -2.66 -3.63 -0.96 -0.107 0.37918E+04 19 andalusite -12.22 -12.50 -0.28 -0.028 0.11164E+04 20 andradite 11.08 6.53 -4.56 -0.237 0.17930E+05 21 grossular -0.46 -5.15 -4.69 -0.235 0.18460E+05 22 anhydrite -13.81 -13.84 -0.03 -0.015 0.11526E+03 24 annite -0.73 -2.21 -1.48 -0.082 0.58203E+04 25 phlogopite 3.71 3.18 -0.53 -0.030 0.20964E+04 27 anorthite -9.92 -10.39 -0.48 -0.037 0.18818E+04 28 anthophyllite 13.32 11.20 -2.12 -0.057 0.83450E+04 29 anthophyllite-Fe 1.16 -1.37 -2.53 -0.068 0.99487E+04 31 apatite-OH-zs -48.86 -50.96 -2.10 -0.162 0.82837E+04 32 apatite-Cl-zs -54.72 -57.79 -3.08 -0.257 0.12121E+05 33 aragonite -4.17 -7.56 -3.39 -1.129 0.13330E+05 34 brucite 4.98 2.77 -2.20 -0.441 0.86744E+04 35 calcite -4.27 -7.56 -3.29 -1.098 0.12961E+05 36 carnegieite-low -0.82 -2.59 -1.78 -0.254 0.69863E+04 37 carnegieite-high -0.75 -2.59 -1.84 -0.263 0.72455E+04 38 carpholite-Mg -8.98 -10.76 -1.77 -0.118 0.69831E+04 39 carpholite-Fe -10.29 -12.55 -2.26 -0.151 0.89107E+04 40 celadonite -1.30 -3.40 -2.11 -0.124 0.82954E+04 41 celadonite-Fe -2.66 -5.20 -2.54 -0.150 0.10004E+05 42 chrysotile 8.65 6.27 -2.38 -0.198 0.93683E+04 44 clinochlore 0.56 -0.68 -1.24 -0.039 0.48891E+04 45 daphnite -6.25 -9.66 -3.41 -0.107 0.13425E+05 47 chlorite-Al-free 17.50 12.54 -4.97 -0.207 0.19544E+05 48 chloritoid-Mg -8.62 -9.73 -1.10 -0.073 0.43322E+04 49 chloritoid-Fe -10.49 -11.52 -1.04 -0.069 0.40762E+04 50 chloritoid-Mn -8.32 -10.09 -1.77 -0.118 0.69587E+04 52 coesite -0.75 -1.03 -0.28 -0.092 0.10904E+04 53 cordierite-H -22.12 -22.54 -0.41 -0.015 0.16255E+04 54 cordierite-Fe -24.52 -26.13 -1.61 -0.055 0.63203E+04 55 cordierite-Mn -20.11 -23.26 -3.15 -0.109 0.12400E+05 56 corundum -11.02 -11.47 -0.45 -0.041 0.17633E+04 58 cristobalite -0.98 -1.03 -0.05 -0.017 0.20614E+03 59 cummingtonite 13.38 11.20 -2.18 -0.059 0.85711E+04 61 cymrite-K -2.88 -5.15 -2.27 -0.189 0.89373E+04 63 diaspore -5.01 -5.74 -0.73 -0.121 0.28648E+04 65 diopside 5.15 3.85 -1.30 -0.130 0.51025E+04 66 hedenbergite 3.78 2.06 -1.72 -0.172 0.67790E+04 68 eastonite -8.89 -10.04 -1.15 -0.044 0.45311E+04 69 enstatite 4.32 3.50 -0.82 -0.082 0.32414E+04 70 clinoenstatite-HiP 4.80 3.50 -1.30 -0.130 0.51311E+04 71 clinoenstatite 4.31 3.50 -0.81 -0.081 0.31914E+04 72 protoenstatite 4.45 3.50 -0.95 -0.095 0.37538E+04 73 epidote -6.27 -8.19 -1.92 -0.093 0.75397E+04 74 clinozoisite -11.77 -14.02 -2.25 -0.102 0.88619E+04 75 epidote-Fe 0.89 -2.35 -3.24 -0.168 0.12758E+05 76 fayalite 1.81 0.93 -0.88 -0.126 0.34706E+04 77 ferrosilite 0.87 -0.10 -0.97 -0.097 0.38148E+04 78 forsterite 5.67 4.52 -1.15 -0.164 0.45144E+04 79 gedrite -13.62 -15.24 -1.61 -0.044 0.63421E+04 81 gibbsite -3.42 -5.74 -2.32 -0.331 0.91165E+04 82 glaucophane 0.04 -3.04 -3.08 -0.083 0.12126E+05 83 glaucophane-Fe -3.85 -8.43 -4.58 -0.124 0.18024E+05 84 goethite 0.90 0.10 -0.80 -0.173 0.31442E+04 86 greenalite 3.97 0.88 -3.09 -0.258 0.12175E+05 87 grunerite 1.69 -1.37 -3.06 -0.083 0.12032E+05 88 halite -0.58 -2.66 -2.08 -1.042 0.82001E+04 89 hematite 0.30 0.21 -0.09 -0.011 0.35241E+03 90 heulandite -12.85 -15.55 -2.70 -0.123 0.10639E+05 91 hercynite -9.63 -10.49 -0.87 -0.058 0.34047E+04 94 jadeite -1.98 -3.62 -1.64 -0.164 0.64516E+04 96 kalsilite -1.45 -3.09 -1.64 -0.235 0.64621E+04 97 kaolinite -10.99 -13.53 -2.54 -0.231 0.99968E+04 98 kyanite -12.07 -12.50 -0.43 -0.043 0.17007E+04 100 laumontite -9.18 -12.46 -3.28 -0.219 0.12909E+05 101 lawsonite -7.22 -10.40 -3.18 -0.212 0.12525E+05 102 leucite -3.13 -4.12 -0.99 -0.099 0.39131E+04 104 lizardite 8.84 6.27 -2.57 -0.214 0.10116E+05 105 magnesite -5.20 -7.92 -2.72 -0.907 0.10709E+05 107 minnesotaite 0.68 -1.18 -1.85 -0.109 0.72901E+04 108 minnesotaite-Mg 6.44 4.21 -2.23 -0.131 0.87609E+04 109 magnesioferrite 4.16 2.98 -1.18 -0.096 0.46413E+04 111 manganosite 5.03 2.41 -2.62 -0.656 0.10321E+05 112 margarite -20.47 -21.87 -1.39 -0.056 0.54829E+04 115 microcline -5.07 -5.15 -0.08 -0.006 0.30751E+03 116 monticellite 8.30 4.88 -3.42 -0.489 0.13465E+05 118 mullite-Si -11.50 -12.50 -1.00 -0.100 0.39371E+04 119 muscovite -15.97 -16.62 -0.65 -0.038 0.25601E+04 120 paragonite -15.29 -16.13 -0.83 -0.049 0.32746E+04 121 nepheline -1.11 -2.59 -1.49 -0.212 0.58460E+04 122 osumilite(2) -14.73 -16.52 -1.80 -0.037 0.70652E+04 123 osumilite-Fe -31.32 -33.34 -2.02 -0.042 0.79401E+04 124 pargasite 1.75 -1.84 -3.59 -0.094 0.14121E+05 125 periclase 5.16 2.78 -2.39 -0.597 0.93938E+04 126 periclase-Fe 2.66 0.98 -1.68 -0.420 0.66195E+04 127 perovskite-Al -9.33 -11.47 -2.14 -0.194 0.84169E+04 132 phlogopite-Na 4.57 3.68 -0.90 -0.050 0.35327E+04 134 prehnite -5.28 -8.29 -3.01 -0.177 0.11834E+05 135 prehnite-Fe 0.61 -2.45 -3.06 -0.184 0.12059E+05 138 px-Mg-tschermaks -8.07 -9.72 -1.65 -0.118 0.65068E+04 139 px-Ca-tschermaks -7.05 -9.37 -2.31 -0.165 0.90939E+04 140 pyrite -20.65 -20.68 -0.03 -0.008 0.12750E+03 141 pyrrhotite -8.36 -8.97 -0.61 -0.204 0.24142E+04 142 pyrrhotiteFe0.875 -9.07 -9.31 -0.25 -0.090 0.96454E+03 143 pyrophyllite -14.44 -15.59 -1.15 -0.072 0.45167E+04 146 riebeckite 6.07 3.25 -2.81 -0.078 0.11070E+05 147 ringwoodite-Fe 2.79 0.93 -1.86 -0.266 0.73242E+04 148 ringwoodite-Mg 8.75 4.52 -4.23 -0.604 0.16648E+05 149 rhodochrosite -5.06 -8.28 -3.22 -1.074 0.12687E+05 150 rhodonite 2.41 1.38 -1.03 -0.206 0.40581E+04 151 sanidine -4.55 -5.15 -0.60 -0.046 0.23765E+04 152 sapphirine(351) -45.55 -50.05 -4.51 -0.068 0.17743E+05 153 siderite -6.96 -9.71 -2.75 -0.918 0.10834E+05 154 sillimanite -12.19 -12.50 -0.31 -0.031 0.12275E+04 156 spinel -7.52 -8.69 -1.17 -0.078 0.46151E+04 158 staurolite-Fe -102.47 -107.04 -4.57 -0.042 0.18000E+05 162 stilpnomelane-Fe -8.57 -12.98 -4.40 -0.131 0.17336E+05 163 stilpnomelane-Mg -2.11 -4.00 -1.88 -0.056 0.74185E+04 164 stishovite 1.85 -1.03 -2.88 -0.960 0.11336E+05 165 sudoite-Fe -20.50 -24.08 -3.58 -0.116 0.14095E+05 166 sudoite -18.37 -20.48 -2.12 -0.068 0.83392E+04 167 sulfur -10.22 -11.71 -1.49 -0.457 0.58465E+04 168 sylvite -0.49 -3.16 -2.67 -1.336 0.10515E+05 169 talc 4.74 4.21 -0.53 -0.031 0.20711E+04 170 talc-Fe 2.03 -1.18 -3.21 -0.189 0.12624E+05 171 talc-tschermaks -7.58 -9.01 -1.43 -0.084 0.56302E+04 173 tephroite 6.13 3.80 -2.34 -0.334 0.92024E+04 176 topaz-H -10.16 -12.50 -2.34 -0.213 0.92238E+04 177 tremolite 14.41 11.92 -2.49 -0.067 0.98080E+04 179 troilite-low -8.26 -8.97 -0.71 -0.237 0.27971E+04 180 tschermakite -11.76 -14.52 -2.76 -0.074 0.10848E+05 183 wadsleyite-Fe 2.64 0.93 -1.71 -0.244 0.67222E+04 184 wadsleyite-Mg 7.83 4.52 -3.30 -0.472 0.13004E+05 185 wairakite -10.96 -12.46 -1.50 -0.088 0.59031E+04 186 walstromite 4.54 2.11 -2.43 -0.487 0.95785E+04 187 wollastonite 4.14 2.11 -2.03 -0.406 0.79926E+04 188 pseudo-wollastonite 4.25 2.11 -2.14 -0.428 0.84224E+04 189 zoisite -11.83 -14.02 -2.19 -0.100 0.86226E+04 192 beidellite-Ca -15.18 -16.63 -1.44 -0.089 0.56804E+04 193 beidellite-H -15.18 -17.14 -1.96 -0.125 0.77306E+04 194 beidellite-K -14.12 -15.93 -1.81 -0.111 0.71299E+04 195 beidellite-Mg -15.49 -16.69 -1.20 -0.074 0.47152E+04 196 beidellite-Na -14.06 -15.77 -1.71 -0.105 0.67264E+04 197 bornite -51.45 -51.82 -0.38 -0.028 0.14812E+04 199 chalcocite -13.32 -14.80 -1.48 -0.370 0.58289E+04 200 covellite -11.85 -13.25 -1.40 -0.534 0.55167E+04 202 montmorillonite-Ca -11.17 -12.26 -1.10 -0.068 0.43112E+04 203 montmorillonite-K -10.40 -11.57 -1.17 -0.072 0.46109E+04 204 montmorillonite-Mg -11.41 -12.32 -0.91 -0.056 0.35892E+04 205 montmorillonite-Na -10.04 -11.40 -1.37 -0.084 0.53907E+04 206 nontronite-Ca -3.63 -4.95 -1.32 -0.086 0.51895E+04 207 nontronite-H -3.63 -5.47 -1.83 -0.123 0.72076E+04 208 nontronite-K -2.57 -4.25 -1.68 -0.108 0.66310E+04 209 nontronite-Mg -3.88 -5.01 -1.12 -0.073 0.44269E+04 210 nontronite-Na -2.50 -4.09 -1.59 -0.102 0.62407E+04 215 gypsum -11.66 -13.84 -2.18 -0.545 0.85824E+04 232 alabandite -6.08 -7.54 -1.46 -0.487 0.57512E+04 234 anglesite -13.95 -16.54 -2.59 -1.295 0.10196E+05 238 boehmite -4.73 -5.74 -1.01 -0.168 0.39560E+04 242 copper,native 1.78 -1.54 -3.33 -1.157 0.13090E+05 244 ferrous-oxide 1.75 0.98 -0.77 -0.193 0.30374E+04 245 galena -9.19 -9.53 -0.33 -0.111 0.13156E+04 246 silver,native 0.56 -3.60 -4.15 -1.445 0.16349E+05 248 litharge 5.18 0.43 -4.75 -1.187 0.18690E+05 255 sphalerite -10.53 -10.54 -0.01 -0.004 0.45894E+02 256 wurtzite -9.75 -10.54 -0.80 -0.265 0.31342E+04 257 zincite 1.89 -0.59 -2.48 -0.619 0.97442E+04 258 an20ab80 -5.78 -5.80 -0.02 -0.001 0.69263E+02 259 an25ab75 -6.08 -6.09 -0.01 0.000 0.22790E+02 261 tr.625ac.25prg.125 8.71 7.95 -0.76 -0.020 0.29914E+04 Calculations done for 587.0000 Deg. C; 1655.0000 bar Temperature changed by -1.000 degrees to 586.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 25 Loop limit = 500 Temperature = 586.00 C Pressure = 1621.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5506E+02 kg liquid = 0.9919E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9956 Stoichiometric ionic strength = .3306005E+01 Osmotic coef. = 0.0000 True ionic strength = .2354706E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11018E-04 -4.9579 0.29001E-05 -5.5376 0.26322E+00 -0.5797 2 H2O 0.99558E+00 -0.0019 0.99558E+00 -0.0019 3 Cl- 0.19722E+00 -0.7050 0.46971E-01 -1.3282 0.23816E+00 -0.6231 4 SO4-- 0.17835E-03 -3.7487 0.11096E-05 -5.9548 0.62216E-02 -2.2061 5 HCO3- 0.24492E-04 -4.6110 0.62845E-05 -5.2017 0.25659E+00 -0.5908 6 HS- 0.14785E-03 -3.8302 0.35506E-04 -4.4497 0.24016E+00 -0.6195 7 H4SiO4 0.90284E-01 -1.0444 0.90284E-01 -1.0444 0.10000E+01 0.0000 8 Al+++ 0.55029E-17 -17.2594 0.46616E-22 -22.3315 0.84712E-05 -5.0721 9 Ca++ 0.23824E-05 -5.6230 0.12015E-07 -7.9203 0.50432E-02 -2.2973 10 Mg++ 0.12758E-05 -5.8942 0.52988E-08 -8.2758 0.41532E-02 -2.3816 11 Fe++ 0.18774E-07 -7.7264 0.81928E-10 -10.0866 0.43638E-02 -2.3601 12 K+ 0.52878E-01 -1.2767 0.13918E-01 -1.8564 0.26320E+00 -0.5797 13 Na+ 0.18026E+00 -0.7441 0.43497E-01 -1.3615 0.24131E+00 -0.6174 14 Mn++ 0.51128E-06 -6.2913 0.23130E-08 -8.6358 0.45239E-02 -2.3445 15 Zn++ 0.52383E-09 -9.2808 0.22859E-11 -11.6409 0.43638E-02 -2.3601 16 Cu+ 0.44358E-07 -7.3530 0.10675E-07 -7.9716 0.24066E+00 -0.6186 17 Pb++ 0.40844E-08 -8.3889 0.23032E-10 -10.6377 0.56390E-02 -2.2488 18 Ag+ 0.37928E-09 -9.4210 0.98282E-10 -10.0075 0.25912E+00 -0.5865 19 Ba++ 0.19062E-06 -6.7198 0.11531E-08 -8.9381 0.60491E-02 -2.2183 20 HPO4-- 0.94924E-09 -9.0226 0.59348E-11 -11.2266 0.62522E-02 -2.2040 21 HSiO3- 0.21119E-05 -5.6753 0.50297E-06 -6.2985 0.23816E+00 -0.6231 22 Ca(HSiO3)+ 0.12839E-07 -7.8915 0.34088E-08 -8.4674 0.26550E+00 -0.5759 23 Mg(HSiO3)+ 0.14838E-08 -8.8286 0.39395E-09 -9.4046 0.26550E+00 -0.5759 24 NaHSiO3,aq 0.14751E-05 -5.8312 0.14751E-05 -5.8312 0.10000E+01 0.0000 28 AgCl,aq 0.73043E-07 -7.1364 0.73043E-07 -7.1364 0.10000E+01 0.0000 29 AgCl2- 0.49645E-05 -5.3041 0.11823E-05 -5.9273 0.23816E+00 -0.6231 30 AgCl3-2 0.23866E-05 -5.6222 0.13765E-07 -7.8612 0.57677E-02 -2.2390 31 AgCl4-3 0.13430E-05 -5.8719 0.97780E-11 -11.0098 0.72807E-05 -5.1378 34 Ag(HS),aq 0.69457E-09 -9.1583 0.69457E-09 -9.1583 0.10000E+01 0.0000 35 Ag(HS)2- 0.41977E-08 -8.3770 0.99973E-09 -9.0001 0.23816E+00 -0.6231 36 AlO+ 0.10201E-10 -10.9914 0.27082E-11 -11.5673 0.26550E+00 -0.5759 38 HAlO2,aq 0.43714E-08 -8.3594 0.43714E-08 -8.3594 0.10000E+01 0.0000 39 AlO2- 0.18781E-04 -4.7263 0.39095E-05 -5.4079 0.20816E+00 -0.6816 41 Ba(HCO3)+ 0.96978E-06 -6.0133 0.26775E-06 -6.5723 0.27609E+00 -0.5589 42 BaCl+ 0.33297E-04 -4.4776 0.88404E-05 -5.0535 0.26550E+00 -0.5759 43 CH4,aq 0.19471E-08 -8.7106 0.23588E-08 -8.6273 0.12114E+01 0.0833 48 CO,aq 0.77967E-03 -3.1081 0.77967E-03 -3.1081 0.10000E+01 0.0000 49 CO2,aq 0.26771E+01 0.4277 0.32431E+01 0.5110 0.12114E+01 0.0833 50 CO3-2 0.50510E-10 -10.2966 0.29133E-12 -12.5356 0.57677E-02 -2.2390 51 CaCO3,aq 0.17768E-10 -10.7504 0.17768E-10 -10.7504 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.57363E-06 -6.2414 0.15230E-06 -6.8173 0.26550E+00 -0.5759 53 CaCl+ 0.22446E-03 -3.6489 0.59592E-04 -4.2248 0.26550E+00 -0.5759 54 CaCl2,aq 0.13826E-03 -3.8593 0.13826E-03 -3.8593 0.10000E+01 0.0000 55 CaOH+ 0.36459E-06 -6.4382 0.96798E-07 -7.0141 0.26550E+00 -0.5759 56 CaSO4,aq 0.13609E-06 -6.8662 0.13609E-06 -6.8662 0.10000E+01 0.0000 57 HCl,aq 0.12344E-02 -2.9085 0.12344E-02 -2.9085 0.10000E+01 0.0000 66 CuCl,aq 0.34063E-04 -4.4677 0.34063E-04 -4.4677 0.10000E+01 0.0000 67 CuCl2- 0.13595E-03 -3.8666 0.32377E-04 -4.4898 0.23816E+00 -0.6231 68 CuCl3-2 0.34496E-05 -5.4622 0.19896E-07 -7.7012 0.57677E-02 -2.2390 74 FeCl+ 0.55074E-06 -6.2591 0.14622E-06 -6.8350 0.26550E+00 -0.5759 75 FeCl2,aq 0.80401E-02 -2.0947 0.80401E-02 -2.0947 0.10000E+01 0.0000 77 FeO,aq 0.83555E-07 -7.0780 0.83555E-07 -7.0780 0.10000E+01 0.0000 78 FeOH+ 0.42180E-07 -7.3749 0.11199E-07 -7.9508 0.26550E+00 -0.5759 79 HFeO2- 0.11490E-07 -7.9397 0.27365E-08 -8.5628 0.23816E+00 -0.6231 82 FeO2- 0.73737E-08 -8.1323 0.17561E-08 -8.7554 0.23816E+00 -0.6231 83 HFeO2,aq 0.25470E-09 -9.5940 0.25470E-09 -9.5940 0.10000E+01 0.0000 84 H2,aq 0.45420E-02 -2.3427 0.55023E-02 -2.2595 0.12114E+01 0.0833 85 KCl,aq 0.56890E-01 -1.2450 0.56890E-01 -1.2450 0.10000E+01 0.0000 86 KHSO4,aq 0.12832E-01 -1.8917 0.12832E-01 -1.8917 0.10000E+01 0.0000 87 KOH,aq 0.98566E-06 -6.0063 0.98566E-06 -6.0063 0.10000E+01 0.0000 88 KSO4- 0.38389E-02 -2.4158 0.91428E-03 -3.0389 0.23816E+00 -0.6231 90 Mg(HCO3)+ 0.10538E-06 -6.9772 0.27979E-07 -7.5532 0.26550E+00 -0.5759 91 MgCl+ 0.18807E-04 -4.7257 0.49932E-05 -5.3016 0.26550E+00 -0.5759 92 MgOH+ 0.65701E-06 -6.1824 0.17443E-06 -6.7584 0.26550E+00 -0.5759 94 MnO,aq 0.35647E-07 -7.4480 0.35647E-07 -7.4480 0.10000E+01 0.0000 95 MnOH+ 0.14821E-06 -6.8291 0.39349E-07 -7.4051 0.26550E+00 -0.5759 97 HMnO2- 0.22867E-10 -10.6408 0.54462E-11 -11.2639 0.23816E+00 -0.6231 100 MnCl+ 0.11582E-02 -2.9362 0.30750E-03 -3.5121 0.26550E+00 -0.5759 101 MnSO4,aq 0.33147E-07 -7.4796 0.33147E-07 -7.4796 0.10000E+01 0.0000 102 NaCl,aq 0.37853E+00 -0.4219 0.37853E+00 -0.4219 0.10000E+01 0.0000 103 NaOH,aq 0.14269E-05 -5.8456 0.14269E-05 -5.8456 0.10000E+01 0.0000 105 OH- 0.92493E-05 -5.0339 0.19253E-05 -5.7155 0.20816E+00 -0.6816 110 HPO3-2 0.15114E-10 -10.8206 0.87175E-13 -13.0596 0.57677E-02 -2.2390 111 H3PO3,aq 0.11595E-09 -9.9357 0.11595E-09 -9.9357 0.10000E+01 0.0000 112 H2PO3- 0.47213E-08 -8.3259 0.11244E-08 -8.9491 0.23816E+00 -0.6231 113 H3PO4,aq 0.85340E-06 -6.0688 0.85340E-06 -6.0688 0.10000E+01 0.0000 114 H2PO4- 0.18008E-05 -5.7445 0.45100E-06 -6.3458 0.25044E+00 -0.6013 116 H4P2O7,aq 0.60391E-10 -10.2190 0.60391E-10 -10.2190 0.10000E+01 0.0000 117 H3P2O7- 0.11821E-08 -8.9273 0.28154E-09 -9.5505 0.23816E+00 -0.6231 118 H2P2O7-2 0.33558E-06 -6.4742 0.19355E-08 -8.7132 0.57677E-02 -2.2390 119 HP2O7-3 0.12497E-07 -7.9032 0.90987E-13 -13.0410 0.72807E-05 -5.1378 121 PbCl+ 0.24140E-05 -5.6173 0.64090E-06 -6.1932 0.26550E+00 -0.5759 122 PbCl2,aq 0.88885E-04 -4.0512 0.88885E-04 -4.0512 0.10000E+01 0.0000 123 PbCl3- 0.11160E-03 -3.9523 0.26579E-04 -4.5755 0.23816E+00 -0.6231 124 PbCl4-2 0.27891E-04 -4.5545 0.16087E-06 -6.7935 0.57677E-02 -2.2390 125 PbO,aq 0.39465E-08 -8.4038 0.39465E-08 -8.4038 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10236E-03 -3.9899 0.10236E-03 -3.9899 0.10000E+01 0.0000 128 Pb(HS)3- 0.98050E-05 -5.0086 0.23352E-05 -5.6317 0.23816E+00 -0.6231 129 H2S,aq 0.10471E+01 0.0200 0.12684E+01 0.1033 0.12114E+01 0.0833 130 S2-2 0.15423E-07 -7.8118 0.88955E-10 -10.0508 0.57677E-02 -2.2390 131 S3-2 0.16254E-08 -8.7890 0.93747E-11 -11.0280 0.57677E-02 -2.2390 132 S3- 0.20807E-01 -1.6818 0.49553E-02 -2.3049 0.23816E+00 -0.6231 133 S4-2 0.14251E-09 -9.8461 0.82197E-12 -12.0851 0.57677E-02 -2.2390 134 S5-2 0.10573E-10 -10.9758 0.60983E-13 -13.2148 0.57677E-02 -2.2390 135 SO2,aq 0.28399E+00 -0.5467 0.28399E+00 -0.5467 0.10000E+01 0.0000 136 SO3-2 0.60363E-09 -9.2192 0.54419E-11 -11.2642 0.90153E-02 -2.0450 137 HSO3- 0.42468E-03 -3.3719 0.10114E-03 -3.9951 0.23816E+00 -0.6231 138 HSO4- 0.11856E-01 -1.9260 0.32289E-02 -2.4909 0.27233E+00 -0.5649 140 S2O3-2 0.53434E-06 -6.2722 0.30820E-08 -8.5112 0.57677E-02 -2.2390 141 HS2O3- 0.68935E-06 -6.1616 0.16418E-06 -6.7847 0.23816E+00 -0.6231 142 H2S2O3,aq 0.24689E-07 -7.6075 0.24689E-07 -7.6075 0.10000E+01 0.0000 150 S4O6-2 0.68661E-09 -9.1633 0.39602E-11 -11.4023 0.57677E-02 -2.2390 152 ZnCl+ 0.65275E-03 -3.1852 0.17331E-03 -3.7612 0.26550E+00 -0.5759 153 ZnCl2,aq 0.14626E-02 -2.8349 0.14626E-02 -2.8349 0.10000E+01 0.0000 154 ZnCl3- 0.19954E-03 -3.7000 0.47522E-04 -4.3231 0.23816E+00 -0.6231 155 ZnO,aq 0.42440E-07 -7.3722 0.42440E-07 -7.3722 0.10000E+01 0.0000 156 ZnOH+ 0.33368E-05 -5.4767 0.88592E-06 -6.0526 0.26550E+00 -0.5759 158 HZnO2- 0.37179E-09 -9.4297 0.88546E-10 -10.0528 0.23816E+00 -0.6231 Charge balance for all species = 0.2552E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1101800E-04 0.4301409E+01 0.3533225E+04 0.0000 2 H2O 0.1000000E+01 0.5249892E+02 0.7707576E+06 0.0000 3 Cl- 0.1972245E+00 0.6568136E+00 0.1897672E+05 4.2094 4 SO4-- 0.1783508E-03 0.2536937E+00 0.1986028E+05 5.1203 5 HCO3- 0.2449190E-04 0.2677938E+01 0.1331615E+06 0.3359 6 HS- 0.1478454E-03 0.1169294E+01 0.3151448E+05 1.0879 7 H4SiO4 0.9028372E-01 0.9028732E-01 0.7072056E+04 -1.0444 8 Al+++ 0.5502873E-17 0.1878587E-04 0.4130697E+00 -5.7187 9 Ca++ 0.2382356E-05 0.3661888E-03 0.1196016E+02 3.1549 10 Mg++ 0.1275835E-05 0.2084655E-04 0.4130292E+00 2.7993 11 Fe++ 0.1877435E-07 0.8040805E-02 0.3659530E+03 0.9886 12 K+ 0.5287827E-01 0.1264406E+00 0.4029132E+04 3.6812 13 Na+ 0.1802557E+00 0.5587895E+00 0.1046910E+05 4.1760 14 Mn++ 0.5112812E-06 0.1158945E-02 0.5188738E+02 2.4393 15 Zn++ 0.5238317E-09 0.2318228E-02 0.1234982E+03 -0.5658 16 Cu+ 0.4435839E-07 0.1735040E-03 0.8984267E+01 -2.4340 17 Pb++ 0.4084374E-08 0.3429678E-03 0.5790927E+02 0.4375 18 Ag+ 0.3792834E-09 0.8772335E-05 0.7711553E+00 -4.4699 19 Ba++ 0.1906165E-06 0.3445780E-04 0.3856653E+01 2.1370 20 HPO4-- 0.9492389E-09 0.3358656E-05 0.2627046E+00 -0.1514 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4266353E+01 -.3990613E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5207106E+02 -.1062819E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2516261E+00 0.9663215E-04 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159765E+01 0.3796028E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.8955149E-01 0.5404283E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1863277E-04 0.6759068E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3632044E-03 0.1647055E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.7975274E-02 0.7914802E-03 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542354E+00 0.3639498E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2299335E-02 0.0000000E+00 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1720900E-03 0.2275197E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.3417697E-04 0.2119548E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3331283E-05 0.5236217E-05 0.0000000E+00 Chg. balance for solid moles: 0.9046E-18 Mass of aqueous solution: 0.121708E+04 g Temperature = 586.00 C Pressure = 1621.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1745E-05 -5.758 0.8768E-03 -3.057 0.2584E-01 0.2786E-03 magnetite 0.1880E-03 -3.726 0.4352E-01 -1.361 1.283 0.8369E-02 quartz 0.5264E-01 -1.279 3.163 0.500 93.22 1.194 barite 0.2120E-04 -4.674 0.4947E-02 -2.306 0.1458 0.1104E-02 chalcopyrite 0.2275E-03 -3.643 0.4175E-01 -1.379 1.231 0.9746E-02 an30ab70 0.5199E-03 -3.284 0.1388 -0.858 4.092 0.5213E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.392475 g Volume = 1.265948 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 30 apatite-OH -51.13 -51.13 0.00 0.000 0.27934E-10 106 magnetite 1.20 1.20 0.00 0.000 0.31425E-10 144 quartz -1.04 -1.04 0.00 0.000 0.00000E+00 237 barite -14.89 -14.89 0.00 0.000 0.69834E-11 240 chalcopyrite -22.30 -22.30 0.00 0.000 0.00000E+00 260 an30ab70 -6.38 -6.38 0.00 0.000 0.00000E+00 255 sphalerite -10.56 -10.55 0.01 0.003 -0.32860E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.288 0.11314E+04 2.922 2 CO2,gas -9.26 -10.74 -1.48 -0.492 0.58008E+04 1.734 3 CH4,gas 6.92 -3.70 -10.62 -2.655 0.41743E+05 -7.408 4 H2,gas 5.80 1.76 -4.04 -2.310 0.15896E+05 -0.834 5 H2S,gas -7.71 -9.99 -2.28 -1.138 0.89490E+04 0.933 6 CO,gas -3.28 -8.98 -5.69 -1.751 0.22378E+05 -2.482 7 SO3,gas -6.71 -17.03 -10.32 -2.580 0.40575E+05 -7.111 8 O2,gas 16.52 -3.52 -20.04 -13.363 0.78801E+05 -16.835 9 HCl,gas -5.72 -6.87 -1.14 -0.572 0.44988E+04 -1.144 10 acmite 3.78 2.20 -1.58 -0.164 0.62037E+04 12 akimotoite 5.83 1.76 -4.08 -0.815 0.16022E+05 13 akimotoite-Fe 3.80 -0.05 -3.85 -0.771 0.15146E+05 14 albite-high -4.52 -4.67 -0.15 -0.011 0.57331E+03 15 albite -4.49 -4.67 -0.17 -0.013 0.68284E+03 16 almandine -10.27 -11.60 -1.34 -0.067 0.52646E+04 17 pyrope -3.84 -6.17 -2.33 -0.117 0.91728E+04 18 analcite -2.66 -3.63 -0.97 -0.107 0.37954E+04 19 andalusite -12.18 -12.48 -0.30 -0.030 0.11748E+04 20 andradite 11.07 6.55 -4.52 -0.235 0.17769E+05 21 grossular -0.44 -5.11 -4.67 -0.233 0.18358E+05 22 anhydrite -13.86 -13.88 -0.01 -0.006 0.49912E+02 24 annite -0.72 -2.20 -1.48 -0.082 0.58256E+04 25 phlogopite 3.73 3.23 -0.50 -0.028 0.19600E+04 27 anorthite -9.89 -10.37 -0.48 -0.037 0.18827E+04 28 anthophyllite 13.30 11.26 -2.05 -0.055 0.80448E+04 29 anthophyllite-Fe 1.12 -1.42 -2.54 -0.069 0.99698E+04 31 apatite-OH-zs -49.02 -51.13 -2.11 -0.162 0.82870E+04 32 apatite-Cl-zs -54.91 -58.00 -3.09 -0.257 0.12132E+05 33 aragonite -4.20 -7.58 -3.38 -1.128 0.13303E+05 34 brucite 4.99 2.80 -2.20 -0.439 0.86325E+04 35 calcite -4.30 -7.58 -3.29 -1.096 0.12932E+05 36 carnegieite-low -0.81 -2.59 -1.78 -0.254 0.69824E+04 37 carnegieite-high -0.74 -2.59 -1.84 -0.263 0.72439E+04 38 carpholite-Mg -8.95 -10.73 -1.78 -0.119 0.70023E+04 39 carpholite-Fe -10.26 -12.54 -2.28 -0.152 0.89778E+04 40 celadonite -1.31 -3.41 -2.10 -0.123 0.82526E+04 41 celadonite-Fe -2.67 -5.22 -2.55 -0.150 0.10010E+05 42 chrysotile 8.66 6.31 -2.35 -0.196 0.92351E+04 44 clinochlore 0.62 -0.59 -1.20 -0.038 0.47208E+04 45 daphnite -6.21 -9.64 -3.43 -0.107 0.13497E+05 47 chlorite-Al-free 17.52 12.61 -4.90 -0.204 0.19272E+05 48 chloritoid-Mg -8.58 -9.69 -1.11 -0.074 0.43491E+04 49 chloritoid-Fe -10.45 -11.50 -1.05 -0.070 0.41373E+04 50 chloritoid-Mn -8.28 -10.05 -1.77 -0.118 0.69403E+04 52 coesite -0.76 -1.04 -0.28 -0.093 0.10919E+04 53 cordierite-H -22.08 -22.50 -0.42 -0.015 0.16538E+04 54 cordierite-Fe -24.48 -26.12 -1.63 -0.056 0.64210E+04 55 cordierite-Mn -20.08 -23.21 -3.14 -0.108 0.12340E+05 56 corundum -10.98 -11.44 -0.46 -0.042 0.18241E+04 58 cristobalite -0.99 -1.04 -0.05 -0.017 0.20385E+03 59 cummingtonite 13.36 11.26 -2.10 -0.057 0.82725E+04 61 cymrite-K -2.89 -5.16 -2.28 -0.190 0.89443E+04 63 diaspore -4.99 -5.72 -0.74 -0.123 0.28940E+04 65 diopside 5.14 3.87 -1.27 -0.127 0.50078E+04 66 hedenbergite 3.77 2.06 -1.71 -0.171 0.67316E+04 68 eastonite -8.83 -9.97 -1.14 -0.044 0.44960E+04 69 enstatite 4.32 3.51 -0.80 -0.080 0.31578E+04 70 clinoenstatite-HiP 4.80 3.51 -1.28 -0.128 0.50485E+04 71 clinoenstatite 4.30 3.51 -0.79 -0.079 0.31070E+04 72 protoenstatite 4.45 3.51 -0.93 -0.093 0.36695E+04 73 epidote -6.25 -8.15 -1.91 -0.092 0.74957E+04 74 clinozoisite -11.73 -13.98 -2.25 -0.102 0.88484E+04 75 epidote-Fe 0.90 -2.33 -3.23 -0.168 0.12680E+05 76 fayalite 1.82 0.93 -0.88 -0.126 0.34776E+04 77 ferrosilite 0.87 -0.11 -0.97 -0.097 0.38243E+04 78 forsterite 5.68 4.55 -1.13 -0.161 0.44275E+04 79 gedrite -13.56 -15.14 -1.59 -0.043 0.62476E+04 81 gibbsite -3.40 -5.72 -2.33 -0.332 0.91495E+04 82 glaucophane 0.02 -3.03 -3.05 -0.082 0.11997E+05 83 glaucophane-Fe -3.87 -8.46 -4.59 -0.124 0.18037E+05 84 goethite 0.91 0.11 -0.80 -0.173 0.31446E+04 86 greenalite 3.97 0.88 -3.10 -0.258 0.12177E+05 87 grunerite 1.65 -1.42 -3.07 -0.083 0.12056E+05 88 halite -0.61 -2.69 -2.08 -1.040 0.81805E+04 89 hematite 0.30 0.21 -0.09 -0.011 0.34988E+03 90 heulandite -12.87 -15.59 -2.72 -0.123 0.10675E+05 91 hercynite -9.57 -10.46 -0.88 -0.059 0.34679E+04 94 jadeite -1.99 -3.63 -1.64 -0.164 0.64557E+04 96 kalsilite -1.44 -3.08 -1.64 -0.235 0.64567E+04 97 kaolinite -10.97 -13.53 -2.56 -0.232 0.10048E+05 98 kyanite -12.04 -12.48 -0.45 -0.045 0.17631E+04 100 laumontite -9.17 -12.46 -3.29 -0.219 0.12925E+05 101 lawsonite -7.19 -10.38 -3.19 -0.213 0.12539E+05 102 leucite -3.13 -4.12 -0.99 -0.099 0.39067E+04 104 lizardite 8.85 6.31 -2.54 -0.212 0.99783E+04 105 magnesite -5.22 -7.94 -2.72 -0.906 0.10691E+05 107 minnesotaite 0.65 -1.20 -1.85 -0.109 0.72921E+04 108 minnesotaite-Mg 6.42 4.23 -2.19 -0.129 0.86231E+04 109 magnesioferrite 4.18 3.01 -1.17 -0.095 0.45944E+04 111 manganosite 5.04 2.44 -2.61 -0.651 0.10244E+05 112 margarite -20.41 -21.82 -1.41 -0.056 0.55485E+04 115 microcline -5.09 -5.16 -0.08 -0.006 0.29838E+03 116 monticellite 8.31 4.91 -3.40 -0.486 0.13365E+05 118 mullite-Si -11.47 -12.48 -1.02 -0.102 0.39992E+04 119 muscovite -15.94 -16.61 -0.67 -0.039 0.26181E+04 120 paragonite -15.26 -16.11 -0.85 -0.050 0.33374E+04 121 nepheline -1.10 -2.59 -1.49 -0.212 0.58428E+04 122 osumilite(2) -14.76 -16.54 -1.77 -0.037 0.69739E+04 123 osumilite-Fe -31.31 -33.36 -2.05 -0.043 0.80425E+04 124 pargasite 1.80 -1.74 -3.54 -0.093 0.13913E+05 125 periclase 5.18 2.80 -2.38 -0.595 0.93493E+04 126 periclase-Fe 2.67 0.99 -1.68 -0.421 0.66232E+04 127 perovskite-Al -9.29 -11.44 -2.16 -0.196 0.84781E+04 132 phlogopite-Na 4.59 3.72 -0.86 -0.048 0.34004E+04 134 prehnite -5.26 -8.26 -3.00 -0.176 0.11786E+05 135 prehnite-Fe 0.61 -2.43 -3.05 -0.183 0.11977E+05 138 px-Mg-tschermaks -8.03 -9.69 -1.66 -0.119 0.65259E+04 139 px-Ca-tschermaks -7.02 -9.33 -2.31 -0.165 0.91008E+04 140 pyrite -20.72 -20.74 -0.03 -0.007 0.10972E+03 141 pyrrhotite -8.39 -9.00 -0.61 -0.204 0.24088E+04 142 pyrrhotiteFe0.875 -9.10 -9.34 -0.24 -0.090 0.95889E+03 143 pyrophyllite -14.44 -15.61 -1.16 -0.073 0.45783E+04 146 riebeckite 6.00 3.20 -2.80 -0.077 0.11024E+05 147 ringwoodite-Fe 2.80 0.93 -1.86 -0.266 0.73310E+04 148 ringwoodite-Mg 8.77 4.55 -4.21 -0.602 0.16562E+05 149 rhodochrosite -5.09 -8.30 -3.21 -1.071 0.12635E+05 150 rhodonite 2.41 1.40 -1.01 -0.203 0.39826E+04 151 sanidine -4.56 -5.16 -0.60 -0.046 0.23676E+04 152 sapphirine(351) -45.31 -49.86 -4.56 -0.069 0.17914E+05 153 siderite -6.99 -9.75 -2.76 -0.921 0.10863E+05 154 sillimanite -12.16 -12.48 -0.33 -0.033 0.12879E+04 156 spinel -7.47 -8.65 -1.18 -0.079 0.46300E+04 158 staurolite-Fe -102.13 -106.85 -4.72 -0.043 0.18567E+05 162 stilpnomelane-Fe -8.58 -13.01 -4.43 -0.132 0.17405E+05 163 stilpnomelane-Mg -2.10 -3.95 -1.85 -0.055 0.72674E+04 164 stishovite 1.84 -1.04 -2.88 -0.961 0.11339E+05 165 sudoite-Fe -20.42 -24.04 -3.62 -0.117 0.14244E+05 166 sudoite -18.29 -20.42 -2.13 -0.069 0.83921E+04 167 sulfur -10.26 -11.75 -1.49 -0.457 0.58385E+04 168 sylvite -0.52 -3.18 -2.67 -1.334 0.10488E+05 169 talc 4.72 4.23 -0.49 -0.029 0.19372E+04 170 talc-Fe 2.01 -1.20 -3.21 -0.189 0.12630E+05 171 talc-tschermaks -7.55 -8.97 -1.42 -0.084 0.55983E+04 173 tephroite 6.14 3.83 -2.30 -0.329 0.90480E+04 176 topaz-H -10.12 -12.49 -2.36 -0.215 0.92859E+04 177 tremolite 14.38 11.97 -2.41 -0.065 0.94839E+04 179 troilite-low -8.29 -9.00 -0.71 -0.237 0.27906E+04 180 tschermakite -11.71 -14.43 -2.73 -0.074 0.10725E+05 183 wadsleyite-Fe 2.64 0.93 -1.71 -0.245 0.67307E+04 184 wadsleyite-Mg 7.84 4.55 -3.29 -0.469 0.12919E+05 185 wairakite -10.96 -12.46 -1.50 -0.088 0.59003E+04 186 walstromite 4.54 2.11 -2.42 -0.485 0.95250E+04 187 wollastonite 4.13 2.11 -2.02 -0.404 0.79368E+04 188 pseudo-wollastonite 4.24 2.11 -2.13 -0.426 0.83677E+04 189 zoisite -11.79 -13.98 -2.19 -0.100 0.86112E+04 192 beidellite-Ca -15.17 -16.63 -1.46 -0.090 0.57415E+04 193 beidellite-H -15.17 -17.15 -1.98 -0.127 0.78002E+04 194 beidellite-K -14.11 -15.94 -1.83 -0.112 0.71887E+04 195 beidellite-Mg -15.47 -16.69 -1.22 -0.075 0.47830E+04 196 beidellite-Na -14.05 -15.77 -1.73 -0.106 0.67866E+04 197 bornite -51.62 -52.01 -0.39 -0.029 0.15331E+04 199 chalcocite -13.37 -14.86 -1.49 -0.372 0.58526E+04 200 covellite -11.90 -13.30 -1.40 -0.535 0.55203E+04 202 montmorillonite-Ca -11.17 -12.28 -1.10 -0.068 0.43377E+04 203 montmorillonite-K -10.40 -11.58 -1.18 -0.072 0.46377E+04 204 montmorillonite-Mg -11.41 -12.33 -0.92 -0.057 0.36166E+04 205 montmorillonite-Na -10.04 -11.42 -1.38 -0.084 0.54135E+04 206 nontronite-Ca -3.66 -4.98 -1.32 -0.086 0.51920E+04 207 nontronite-H -3.66 -5.50 -1.84 -0.123 0.72185E+04 208 nontronite-K -2.60 -4.28 -1.69 -0.108 0.66307E+04 209 nontronite-Mg -3.91 -5.03 -1.13 -0.073 0.44311E+04 210 nontronite-Na -2.53 -4.12 -1.59 -0.102 0.62420E+04 215 gypsum -11.71 -13.88 -2.17 -0.542 0.85302E+04 232 alabandite -6.11 -7.55 -1.44 -0.480 0.56669E+04 234 anglesite -14.01 -16.59 -2.58 -1.291 0.10151E+05 238 boehmite -4.71 -5.72 -1.01 -0.169 0.39862E+04 242 copper,native 1.78 -1.55 -3.33 -1.159 0.13100E+05 244 ferrous-oxide 1.76 0.99 -0.77 -0.193 0.30426E+04 245 galena -9.23 -9.55 -0.32 -0.107 0.12659E+04 246 silver,native 0.55 -3.59 -4.14 -1.441 0.16286E+05 248 litharge 5.18 0.44 -4.74 -1.186 0.18647E+05 256 wurtzite -9.78 -10.55 -0.78 -0.259 0.30553E+04 257 zincite 1.89 -0.57 -2.46 -0.615 0.96747E+04 258 an20ab80 -5.79 -5.81 -0.02 -0.001 0.68852E+02 259 an25ab75 -6.09 -6.09 -0.01 0.000 0.22794E+02 261 tr.625ac.25prg.125 8.69 7.99 -0.70 -0.019 0.27513E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 20 Loop limit = 500 Temperature = 586.00 C Pressure = 1621.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5506E+02 kg liquid = 0.9919E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9956 Stoichiometric ionic strength = .3305934E+01 Osmotic coef. = 0.0000 True ionic strength = .2354434E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11027E-04 -4.9575 0.29027E-05 -5.5372 0.26323E+00 -0.5797 2 H2O 0.99558E+00 -0.0019 0.99558E+00 -0.0019 3 Cl- 0.19723E+00 -0.7050 0.46976E-01 -1.3281 0.23817E+00 -0.6231 4 SO4-- 0.17804E-03 -3.7495 0.11079E-05 -5.9555 0.62228E-02 -2.2060 5 HCO3- 0.24469E-04 -4.6114 0.62789E-05 -5.2021 0.25661E+00 -0.5907 6 HS- 0.14770E-03 -3.8306 0.35474E-04 -4.4501 0.24017E+00 -0.6195 7 H4SiO4 0.90284E-01 -1.0444 0.90284E-01 -1.0444 0.10000E+01 0.0000 8 Al+++ 0.55202E-17 -17.2580 0.46784E-22 -22.3299 0.84751E-05 -5.0719 9 Ca++ 0.23817E-05 -5.6231 0.12014E-07 -7.9203 0.50443E-02 -2.2972 10 Mg++ 0.12755E-05 -5.8943 0.52988E-08 -8.2758 0.41541E-02 -2.3815 11 Fe++ 0.18803E-07 -7.7258 0.82072E-10 -10.0858 0.43648E-02 -2.3600 12 K+ 0.52881E-01 -1.2767 0.13919E-01 -1.8564 0.26321E+00 -0.5797 13 Na+ 0.18024E+00 -0.7442 0.43495E-01 -1.3616 0.24132E+00 -0.6174 14 Mn++ 0.51114E-06 -6.2915 0.23129E-08 -8.6358 0.45249E-02 -2.3444 15 Zn++ 0.51465E-09 -9.2885 0.22464E-11 -11.6485 0.43648E-02 -2.3600 16 Cu+ 0.44396E-07 -7.3527 0.10685E-07 -7.9712 0.24067E+00 -0.6186 17 Pb++ 0.40855E-08 -8.3888 0.23043E-10 -10.6375 0.56402E-02 -2.2487 18 Ag+ 0.37923E-09 -9.4211 0.98273E-10 -10.0076 0.25914E+00 -0.5865 19 Ba++ 0.19088E-06 -6.7192 0.11549E-08 -8.9375 0.60503E-02 -2.2182 20 HPO4-- 0.95028E-09 -9.0221 0.59425E-11 -11.2260 0.62534E-02 -2.2039 21 HSiO3- 0.21099E-05 -5.6757 0.50252E-06 -6.2988 0.23817E+00 -0.6231 22 Ca(HSiO3)+ 0.12827E-07 -7.8919 0.34056E-08 -8.4678 0.26551E+00 -0.5759 23 Mg(HSiO3)+ 0.14824E-08 -8.8290 0.39360E-09 -9.4049 0.26551E+00 -0.5759 24 NaHSiO3,aq 0.14737E-05 -5.8316 0.14737E-05 -5.8316 0.10000E+01 0.0000 28 AgCl,aq 0.73043E-07 -7.1364 0.73043E-07 -7.1364 0.10000E+01 0.0000 29 AgCl2- 0.49647E-05 -5.3041 0.11825E-05 -5.9272 0.23817E+00 -0.6231 30 AgCl3-2 0.23866E-05 -5.6222 0.13768E-07 -7.8611 0.57689E-02 -2.2389 31 AgCl4-3 0.13427E-05 -5.8720 0.97809E-11 -11.0096 0.72842E-05 -5.1376 34 Ag(HS),aq 0.69388E-09 -9.1587 0.69388E-09 -9.1587 0.10000E+01 0.0000 35 Ag(HS)2- 0.41895E-08 -8.3778 0.99784E-09 -9.0009 0.23817E+00 -0.6231 36 AlO+ 0.10219E-10 -10.9906 0.27132E-11 -11.5665 0.26551E+00 -0.5759 38 HAlO2,aq 0.43755E-08 -8.3590 0.43755E-08 -8.3590 0.10000E+01 0.0000 39 AlO2- 0.18781E-04 -4.7263 0.39097E-05 -5.4079 0.20817E+00 -0.6816 41 Ba(HCO3)+ 0.97039E-06 -6.0131 0.26793E-06 -6.5720 0.27610E+00 -0.5589 42 BaCl+ 0.33351E-04 -4.4769 0.88551E-05 -5.0528 0.26551E+00 -0.5759 43 CH4,aq 0.19467E-08 -8.7107 0.23582E-08 -8.6274 0.12114E+01 0.0833 48 CO,aq 0.77962E-03 -3.1081 0.77962E-03 -3.1081 0.10000E+01 0.0000 49 CO2,aq 0.26771E+01 0.4277 0.32431E+01 0.5110 0.12114E+01 0.0833 50 CO3-2 0.50410E-10 -10.2975 0.29081E-12 -12.5364 0.57689E-02 -2.2389 51 CaCO3,aq 0.17735E-10 -10.7512 0.17735E-10 -10.7512 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.57306E-06 -6.2418 0.15215E-06 -6.8177 0.26551E+00 -0.5759 53 CaCl+ 0.22445E-03 -3.6489 0.59595E-04 -4.2248 0.26551E+00 -0.5759 54 CaCl2,aq 0.13828E-03 -3.8592 0.13828E-03 -3.8592 0.10000E+01 0.0000 55 CaOH+ 0.36423E-06 -6.4386 0.96706E-07 -7.0145 0.26551E+00 -0.5759 56 CaSO4,aq 0.13587E-06 -6.8669 0.13587E-06 -6.8669 0.10000E+01 0.0000 57 HCl,aq 0.12356E-02 -2.9081 0.12356E-02 -2.9081 0.10000E+01 0.0000 66 CuCl,aq 0.34097E-04 -4.4673 0.34097E-04 -4.4673 0.10000E+01 0.0000 67 CuCl2- 0.13609E-03 -3.8662 0.32413E-04 -4.4893 0.23817E+00 -0.6231 68 CuCl3-2 0.34530E-05 -5.4618 0.19920E-07 -7.7007 0.57689E-02 -2.2389 74 FeCl+ 0.55174E-06 -6.2583 0.14649E-06 -6.8342 0.26551E+00 -0.5759 75 FeCl2,aq 0.80558E-02 -2.0939 0.80558E-02 -2.0939 0.10000E+01 0.0000 77 FeO,aq 0.83553E-07 -7.0780 0.83553E-07 -7.0780 0.10000E+01 0.0000 78 FeOH+ 0.42215E-07 -7.3745 0.11208E-07 -7.9505 0.26551E+00 -0.5759 79 HFeO2- 0.11479E-07 -7.9401 0.27340E-08 -8.5632 0.23817E+00 -0.6231 82 FeO2- 0.73668E-08 -8.1327 0.17546E-08 -8.7558 0.23817E+00 -0.6231 83 HFeO2,aq 0.25470E-09 -9.5940 0.25470E-09 -9.5940 0.10000E+01 0.0000 84 H2,aq 0.45418E-02 -2.3428 0.55020E-02 -2.2595 0.12114E+01 0.0833 85 KCl,aq 0.56901E-01 -1.2449 0.56901E-01 -1.2449 0.10000E+01 0.0000 86 KHSO4,aq 0.12825E-01 -1.8919 0.12825E-01 -1.8919 0.10000E+01 0.0000 87 KOH,aq 0.98487E-06 -6.0066 0.98487E-06 -6.0066 0.10000E+01 0.0000 88 KSO4- 0.38331E-02 -2.4165 0.91294E-03 -3.0396 0.23817E+00 -0.6231 90 Mg(HCO3)+ 0.10528E-06 -6.9776 0.27954E-07 -7.5536 0.26551E+00 -0.5759 91 MgCl+ 0.18808E-04 -4.7257 0.49937E-05 -5.3016 0.26551E+00 -0.5759 92 MgOH+ 0.65640E-06 -6.1828 0.17428E-06 -6.7588 0.26551E+00 -0.5759 94 MnO,aq 0.35582E-07 -7.4488 0.35582E-07 -7.4488 0.10000E+01 0.0000 95 MnOH+ 0.14806E-06 -6.8296 0.39312E-07 -7.4055 0.26551E+00 -0.5759 97 HMnO2- 0.22804E-10 -10.6420 0.54313E-11 -11.2651 0.23817E+00 -0.6231 100 MnCl+ 0.11582E-02 -2.9362 0.30752E-03 -3.5121 0.26551E+00 -0.5759 101 MnSO4,aq 0.33094E-07 -7.4803 0.33094E-07 -7.4803 0.10000E+01 0.0000 102 NaCl,aq 0.37855E+00 -0.4219 0.37855E+00 -0.4219 0.10000E+01 0.0000 103 NaOH,aq 0.14255E-05 -5.8460 0.14255E-05 -5.8460 0.10000E+01 0.0000 105 OH- 0.92404E-05 -5.0343 0.19236E-05 -5.7159 0.20817E+00 -0.6816 110 HPO3-2 0.15130E-10 -10.8202 0.87282E-13 -13.0591 0.57689E-02 -2.2389 111 H3PO3,aq 0.11630E-09 -9.9344 0.11630E-09 -9.9344 0.10000E+01 0.0000 112 H2PO3- 0.47311E-08 -8.3250 0.11268E-08 -8.9481 0.23817E+00 -0.6231 113 H3PO4,aq 0.85602E-06 -6.0675 0.85602E-06 -6.0675 0.10000E+01 0.0000 114 H2PO4- 0.18047E-05 -5.7436 0.45198E-06 -6.3449 0.25045E+00 -0.6013 116 H4P2O7,aq 0.60763E-10 -10.2164 0.60763E-10 -10.2164 0.10000E+01 0.0000 117 H3P2O7- 0.11883E-08 -8.9251 0.28302E-09 -9.5482 0.23817E+00 -0.6231 118 H2P2O7-2 0.33698E-06 -6.4724 0.19440E-08 -8.7113 0.57689E-02 -2.2389 119 HP2O7-3 0.12534E-07 -7.9019 0.91303E-13 -13.0395 0.72842E-05 -5.1376 121 PbCl+ 0.24152E-05 -5.6170 0.64126E-06 -6.1930 0.26551E+00 -0.5759 122 PbCl2,aq 0.88945E-04 -4.0509 0.88945E-04 -4.0509 0.10000E+01 0.0000 123 PbCl3- 0.11168E-03 -3.9520 0.26600E-04 -4.5751 0.23817E+00 -0.6231 124 PbCl4-2 0.27910E-04 -4.5542 0.16101E-06 -6.7931 0.57689E-02 -2.2389 125 PbO,aq 0.39413E-08 -8.4044 0.39413E-08 -8.4044 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10222E-03 -3.9904 0.10222E-03 -3.9904 0.10000E+01 0.0000 128 Pb(HS)3- 0.97826E-05 -5.0095 0.23300E-05 -5.6327 0.23817E+00 -0.6231 129 H2S,aq 0.10471E+01 0.0200 0.12684E+01 0.1033 0.12114E+01 0.0833 130 S2-2 0.15393E-07 -7.8127 0.88800E-10 -10.0516 0.57689E-02 -2.2389 131 S3-2 0.16223E-08 -8.7899 0.93588E-11 -11.0288 0.57689E-02 -2.2389 132 S3- 0.20789E-01 -1.6822 0.49515E-02 -2.3053 0.23817E+00 -0.6231 133 S4-2 0.14225E-09 -9.8470 0.82061E-12 -12.0859 0.57689E-02 -2.2389 134 S5-2 0.10554E-10 -10.9766 0.60884E-13 -13.2155 0.57689E-02 -2.2389 135 SO2,aq 0.28404E+00 -0.5466 0.28404E+00 -0.5466 0.10000E+01 0.0000 136 SO3-2 0.60256E-09 -9.2200 0.54331E-11 -11.2649 0.90168E-02 -2.0449 137 HSO3- 0.42435E-03 -3.3723 0.10107E-03 -3.9954 0.23817E+00 -0.6231 138 HSO4- 0.11848E-01 -1.9264 0.32267E-02 -2.4912 0.27234E+00 -0.5649 140 S2O3-2 0.53340E-06 -6.2730 0.30771E-08 -8.5119 0.57689E-02 -2.2389 141 HS2O3- 0.68885E-06 -6.1619 0.16407E-06 -6.7850 0.23817E+00 -0.6231 142 H2S2O3,aq 0.24694E-07 -7.6074 0.24694E-07 -7.6074 0.10000E+01 0.0000 150 S4O6-2 0.68557E-09 -9.1639 0.39550E-11 -11.4029 0.57689E-02 -2.2389 152 ZnCl+ 0.64150E-03 -3.1928 0.17032E-03 -3.7687 0.26551E+00 -0.5759 153 ZnCl2,aq 0.14375E-02 -2.8424 0.14375E-02 -2.8424 0.10000E+01 0.0000 154 ZnCl3- 0.19613E-03 -3.7075 0.46713E-04 -4.3306 0.23817E+00 -0.6231 155 ZnO,aq 0.41632E-07 -7.3806 0.41632E-07 -7.3806 0.10000E+01 0.0000 156 ZnOH+ 0.32760E-05 -5.4847 0.86981E-06 -6.0606 0.26551E+00 -0.5759 158 HZnO2- 0.36436E-09 -9.4385 0.86782E-10 -10.0616 0.23817E+00 -0.6231 Charge balance for all species = 0.2552E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1102727E-04 0.4301417E+01 0.3533241E+04 0.0000 2 H2O 0.1000000E+01 0.5249892E+02 0.7707595E+06 0.0000 3 Cl- 0.1972334E+00 0.6568134E+00 0.1897676E+05 4.2091 4 SO4-- 0.1780383E-03 0.2536950E+00 0.1986043E+05 5.1189 5 HCO3- 0.2446892E-04 0.2677937E+01 0.1331618E+06 0.3351 6 HS- 0.1477044E-03 0.1169253E+01 0.3151345E+05 1.0871 7 H4SiO4 0.9028375E-01 0.9028735E-01 0.7072075E+04 -1.0444 8 Al+++ 0.5520158E-17 0.1878543E-04 0.4130610E+00 -5.7183 9 Ca++ 0.2381710E-05 0.3662042E-03 0.1196069E+02 3.1541 10 Mg++ 0.1275544E-05 0.2084654E-04 0.4130301E+00 2.7986 11 Fe++ 0.1880325E-07 0.8056547E-02 0.3666704E+03 0.9886 12 K+ 0.5288077E-01 0.1264406E+00 0.4029140E+04 3.6808 13 Na+ 0.1802375E+00 0.5587893E+00 0.1046912E+05 4.1756 14 Mn++ 0.5111410E-06 0.1158945E-02 0.5188749E+02 2.4385 15 Zn++ 0.5146543E-09 0.2278480E-02 0.1213810E+03 -0.5741 16 Cu+ 0.4439636E-07 0.1736846E-03 0.8993640E+01 -2.4340 17 Pb++ 0.4085483E-08 0.3429677E-03 0.5790939E+02 0.4369 18 Ag+ 0.3792311E-09 0.8772333E-05 0.7711569E+00 -4.4704 19 Ba++ 0.1908769E-06 0.3451250E-04 0.3862784E+01 2.1369 20 HPO4-- 0.9502792E-09 0.3368015E-05 0.2634373E+00 -0.1516 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4266362E+01 -.4000280E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5207108E+02 -.1062971E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2516275E+00 0.9526904E-04 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159724E+01 0.4199768E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.8955155E-01 0.5404278E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1863234E-04 0.6759072E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3632198E-03 0.1646901E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.7990890E-02 0.7758636E-03 0.0000000E+00 12 K+ 0.1254101E+00 0.1254101E+00 0.0000000E+00 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542354E+00 0.3639500E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2259911E-02 0.3942342E-04 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1722691E-03 0.2273406E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.3423124E-04 0.2114121E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3340567E-05 0.5226933E-05 0.0000000E+00 Chg. balance for solid moles: -.8301E-18 Mass of aqueous solution: 0.121708E+04 g Temperature = 586.00 C Pressure = 1621.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1742E-05 -5.759 0.8752E-03 -3.058 0.2578E-01 0.2781E-03 magnetite 0.1828E-03 -3.738 0.4233E-01 -1.373 1.247 0.8140E-02 quartz 0.5264E-01 -1.279 3.163 0.500 93.15 1.194 barite 0.2114E-04 -4.675 0.4934E-02 -2.307 0.1453 0.1101E-02 chalcopyrite 0.2273E-03 -3.643 0.4172E-01 -1.380 1.229 0.9738E-02 an30ab70 0.5199E-03 -3.284 0.1388 -0.858 4.089 0.5213E-01 sphalerite 0.3942E-04 -4.404 0.3841E-02 -2.416 0.1131 0.9394E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.395075 g Volume = 1.266646 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 30 apatite-OH -51.13 -51.13 0.00 0.000 0.00000E+00 106 magnetite 1.20 1.20 0.00 0.000 0.34917E-11 144 quartz -1.04 -1.04 0.00 0.000 0.00000E+00 237 barite -14.89 -14.89 0.00 0.000 0.69834E-11 240 chalcopyrite -22.30 -22.30 0.00 0.000 0.00000E+00 255 sphalerite -10.56 -10.56 0.00 0.000 -0.69834E-11 260 an30ab70 -6.38 -6.38 0.00 0.000 -0.13967E-10 24 annite -0.72 -2.20 -1.48 -0.082 0.58255E+04 25 phlogopite 3.73 3.23 -0.50 -0.028 0.19689E+04 26 biotite-Mn 8.39 2.14 -6.24 -0.347 0.24543E+05 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.288 0.11314E+04 2.922 2 CO2,gas -9.26 -10.74 -1.48 -0.492 0.58008E+04 1.734 3 CH4,gas 6.92 -3.70 -10.62 -2.655 0.41744E+05 -7.408 4 H2,gas 5.80 1.76 -4.04 -2.311 0.15896E+05 -0.834 5 H2S,gas -7.71 -9.99 -2.28 -1.138 0.89490E+04 0.933 6 CO,gas -3.28 -8.98 -5.69 -1.751 0.22378E+05 -2.482 7 SO3,gas -6.71 -17.03 -10.32 -2.580 0.40575E+05 -7.111 8 O2,gas 16.52 -3.52 -20.04 -13.363 0.78801E+05 -16.835 9 HCl,gas -5.72 -6.87 -1.14 -0.572 0.44971E+04 -1.144 10 acmite 3.78 2.20 -1.58 -0.164 0.62053E+04 12 akimotoite 5.83 1.76 -4.08 -0.815 0.16025E+05 13 akimotoite-Fe 3.80 -0.05 -3.85 -0.771 0.15146E+05 14 albite-high -4.52 -4.67 -0.15 -0.011 0.57333E+03 15 albite -4.49 -4.67 -0.17 -0.013 0.68286E+03 16 almandine -10.27 -11.60 -1.34 -0.067 0.52615E+04 17 pyrope -3.84 -6.17 -2.33 -0.117 0.91787E+04 18 analcite -2.66 -3.63 -0.97 -0.107 0.37954E+04 19 andalusite -12.18 -12.48 -0.30 -0.030 0.11717E+04 20 andradite 11.07 6.55 -4.52 -0.235 0.17779E+05 21 grossular -0.44 -5.11 -4.67 -0.234 0.18365E+05 22 anhydrite -13.86 -13.88 -0.01 -0.007 0.52681E+02 27 anorthite -9.89 -10.37 -0.48 -0.037 0.18827E+04 28 anthophyllite 13.30 11.25 -2.05 -0.055 0.80661E+04 29 anthophyllite-Fe 1.12 -1.42 -2.54 -0.069 0.99700E+04 31 apatite-OH-zs -49.02 -51.13 -2.11 -0.162 0.82870E+04 32 apatite-Cl-zs -54.91 -58.00 -3.09 -0.257 0.12130E+05 33 aragonite -4.20 -7.59 -3.38 -1.128 0.13306E+05 34 brucite 4.99 2.79 -2.20 -0.439 0.86355E+04 35 calcite -4.30 -7.59 -3.29 -1.097 0.12935E+05 36 carnegieite-low -0.81 -2.59 -1.78 -0.254 0.69824E+04 37 carnegieite-high -0.74 -2.59 -1.84 -0.263 0.72439E+04 38 carpholite-Mg -8.95 -10.73 -1.78 -0.119 0.70021E+04 39 carpholite-Fe -10.26 -12.54 -2.28 -0.152 0.89746E+04 40 celadonite -1.31 -3.41 -2.10 -0.124 0.82555E+04 41 celadonite-Fe -2.67 -5.22 -2.55 -0.150 0.10010E+05 42 chrysotile 8.66 6.31 -2.35 -0.196 0.92442E+04 44 clinochlore 0.62 -0.59 -1.20 -0.038 0.47328E+04 45 daphnite -6.21 -9.64 -3.43 -0.107 0.13494E+05 47 chlorite-Al-free 17.52 12.61 -4.91 -0.204 0.19290E+05 48 chloritoid-Mg -8.58 -9.69 -1.11 -0.074 0.43490E+04 49 chloritoid-Fe -10.45 -11.50 -1.05 -0.070 0.41342E+04 50 chloritoid-Mn -8.28 -10.05 -1.77 -0.118 0.69403E+04 52 coesite -0.76 -1.04 -0.28 -0.093 0.10919E+04 53 cordierite-H -22.08 -22.50 -0.42 -0.015 0.16535E+04 54 cordierite-Fe -24.48 -26.11 -1.63 -0.056 0.64147E+04 55 cordierite-Mn -20.08 -23.21 -3.14 -0.108 0.12340E+05 56 corundum -10.98 -11.44 -0.46 -0.042 0.18210E+04 58 cristobalite -0.99 -1.04 -0.05 -0.017 0.20385E+03 59 cummingtonite 13.36 11.25 -2.11 -0.057 0.82938E+04 61 cymrite-K -2.89 -5.16 -2.28 -0.190 0.89441E+04 63 diaspore -4.99 -5.72 -0.74 -0.123 0.28924E+04 65 diopside 5.14 3.87 -1.28 -0.128 0.50140E+04 66 hedenbergite 3.77 2.06 -1.71 -0.171 0.67348E+04 68 eastonite -8.83 -9.97 -1.14 -0.044 0.44986E+04 69 enstatite 4.32 3.51 -0.80 -0.080 0.31639E+04 70 clinoenstatite-HiP 4.80 3.51 -1.29 -0.129 0.50546E+04 71 clinoenstatite 4.30 3.51 -0.79 -0.079 0.31131E+04 72 protoenstatite 4.45 3.51 -0.93 -0.093 0.36756E+04 73 epidote -6.25 -8.15 -1.91 -0.092 0.74988E+04 74 clinozoisite -11.73 -13.98 -2.25 -0.102 0.88499E+04 75 epidote-Fe 0.90 -2.33 -3.23 -0.168 0.12685E+05 76 fayalite 1.82 0.93 -0.88 -0.126 0.34777E+04 77 ferrosilite 0.87 -0.11 -0.97 -0.097 0.38244E+04 78 forsterite 5.68 4.55 -1.13 -0.161 0.44336E+04 79 gedrite -13.56 -15.15 -1.59 -0.043 0.62564E+04 81 gibbsite -3.40 -5.72 -2.33 -0.332 0.91479E+04 82 glaucophane 0.02 -3.03 -3.05 -0.083 0.12006E+05 83 glaucophane-Fe -3.87 -8.46 -4.59 -0.124 0.18037E+05 84 goethite 0.91 0.11 -0.80 -0.173 0.31446E+04 86 greenalite 3.97 0.88 -3.10 -0.258 0.12177E+05 87 grunerite 1.65 -1.42 -3.07 -0.083 0.12056E+05 88 halite -0.61 -2.69 -2.08 -1.040 0.81805E+04 89 hematite 0.30 0.21 -0.09 -0.011 0.34985E+03 90 heulandite -12.87 -15.59 -2.72 -0.123 0.10675E+05 91 hercynite -9.57 -10.46 -0.88 -0.059 0.34648E+04 94 jadeite -1.99 -3.63 -1.64 -0.164 0.64558E+04 96 kalsilite -1.44 -3.08 -1.64 -0.235 0.64565E+04 97 kaolinite -10.97 -13.53 -2.56 -0.232 0.10045E+05 98 kyanite -12.04 -12.48 -0.45 -0.045 0.17600E+04 100 laumontite -9.17 -12.46 -3.29 -0.219 0.12925E+05 101 lawsonite -7.19 -10.38 -3.19 -0.213 0.12539E+05 102 leucite -3.13 -4.12 -0.99 -0.099 0.39065E+04 104 lizardite 8.85 6.31 -2.54 -0.212 0.99874E+04 105 magnesite -5.22 -7.94 -2.72 -0.907 0.10694E+05 107 minnesotaite 0.65 -1.20 -1.85 -0.109 0.72922E+04 108 minnesotaite-Mg 6.42 4.23 -2.20 -0.129 0.86322E+04 109 magnesioferrite 4.18 3.01 -1.17 -0.095 0.45974E+04 111 manganosite 5.04 2.44 -2.61 -0.652 0.10247E+05 112 margarite -20.41 -21.82 -1.41 -0.056 0.55453E+04 115 microcline -5.09 -5.16 -0.08 -0.006 0.29815E+03 116 monticellite 8.31 4.91 -3.40 -0.486 0.13371E+05 118 mullite-Si -11.47 -12.48 -1.02 -0.102 0.39960E+04 119 muscovite -15.94 -16.61 -0.67 -0.039 0.26147E+04 120 paragonite -15.26 -16.11 -0.85 -0.050 0.33342E+04 121 nepheline -1.10 -2.59 -1.49 -0.212 0.58428E+04 122 osumilite(2) -14.76 -16.54 -1.78 -0.037 0.69796E+04 123 osumilite-Fe -31.31 -33.36 -2.04 -0.043 0.80360E+04 124 pargasite 1.80 -1.74 -3.54 -0.093 0.13929E+05 125 periclase 5.18 2.80 -2.38 -0.595 0.93523E+04 126 periclase-Fe 2.67 0.99 -1.68 -0.421 0.66232E+04 127 perovskite-Al -9.29 -11.44 -2.16 -0.196 0.84749E+04 132 phlogopite-Na 4.59 3.72 -0.87 -0.048 0.34096E+04 134 prehnite -5.26 -8.26 -3.00 -0.176 0.11789E+05 135 prehnite-Fe 0.61 -2.43 -3.05 -0.183 0.11982E+05 138 px-Mg-tschermaks -8.03 -9.69 -1.66 -0.119 0.65257E+04 139 px-Ca-tschermaks -7.02 -9.33 -2.31 -0.165 0.91008E+04 140 pyrite -20.72 -20.74 -0.03 -0.007 0.10970E+03 141 pyrrhotite -8.39 -9.00 -0.61 -0.204 0.24089E+04 142 pyrrhotiteFe0.875 -9.10 -9.34 -0.24 -0.090 0.95893E+03 143 pyrophyllite -14.44 -15.61 -1.16 -0.073 0.45751E+04 146 riebeckite 6.00 3.20 -2.80 -0.077 0.11027E+05 147 ringwoodite-Fe 2.80 0.93 -1.86 -0.266 0.73310E+04 148 ringwoodite-Mg 8.77 4.55 -4.21 -0.602 0.16568E+05 149 rhodochrosite -5.09 -8.30 -3.21 -1.072 0.12638E+05 150 rhodonite 2.41 1.40 -1.01 -0.203 0.39857E+04 151 sanidine -4.56 -5.16 -0.60 -0.046 0.23674E+04 152 sapphirine(351) -45.31 -49.86 -4.56 -0.069 0.17907E+05 153 siderite -6.99 -9.75 -2.76 -0.921 0.10863E+05 154 sillimanite -12.16 -12.48 -0.33 -0.033 0.12848E+04 156 spinel -7.47 -8.65 -1.18 -0.079 0.46299E+04 158 staurolite-Fe -102.13 -106.84 -4.72 -0.043 0.18539E+05 162 stilpnomelane-Fe -8.58 -13.01 -4.43 -0.132 0.17402E+05 163 stilpnomelane-Mg -2.10 -3.96 -1.85 -0.055 0.72801E+04 164 stishovite 1.84 -1.04 -2.88 -0.961 0.11339E+05 165 sudoite-Fe -20.42 -24.04 -3.62 -0.117 0.14238E+05 166 sudoite -18.29 -20.42 -2.13 -0.069 0.83919E+04 167 sulfur -10.26 -11.75 -1.49 -0.457 0.58385E+04 168 sylvite -0.52 -3.18 -2.67 -1.334 0.10488E+05 169 talc 4.72 4.23 -0.50 -0.029 0.19463E+04 170 talc-Fe 2.01 -1.20 -3.21 -0.189 0.12630E+05 171 talc-tschermaks -7.55 -8.97 -1.42 -0.084 0.56012E+04 173 tephroite 6.14 3.83 -2.30 -0.329 0.90542E+04 176 topaz-H -10.12 -12.48 -2.36 -0.215 0.92828E+04 177 tremolite 14.38 11.96 -2.42 -0.065 0.95054E+04 179 troilite-low -8.29 -9.00 -0.71 -0.237 0.27906E+04 180 tschermakite -11.71 -14.44 -2.73 -0.074 0.10734E+05 183 wadsleyite-Fe 2.64 0.93 -1.71 -0.245 0.67307E+04 184 wadsleyite-Mg 7.84 4.55 -3.29 -0.470 0.12925E+05 185 wairakite -10.96 -12.46 -1.50 -0.088 0.59003E+04 186 walstromite 4.54 2.11 -2.42 -0.485 0.95282E+04 187 wollastonite 4.13 2.11 -2.02 -0.404 0.79400E+04 188 pseudo-wollastonite 4.24 2.11 -2.13 -0.426 0.83709E+04 189 zoisite -11.79 -13.98 -2.19 -0.100 0.86127E+04 192 beidellite-Ca -15.17 -16.63 -1.46 -0.090 0.57383E+04 193 beidellite-H -15.17 -17.15 -1.98 -0.127 0.77965E+04 194 beidellite-K -14.11 -15.94 -1.83 -0.112 0.71855E+04 195 beidellite-Mg -15.47 -16.69 -1.22 -0.075 0.47798E+04 196 beidellite-Na -14.05 -15.77 -1.73 -0.106 0.67835E+04 197 bornite -51.62 -52.01 -0.39 -0.029 0.15331E+04 199 chalcocite -13.37 -14.86 -1.49 -0.372 0.58525E+04 200 covellite -11.90 -13.30 -1.40 -0.535 0.55202E+04 202 montmorillonite-Ca -11.17 -12.28 -1.10 -0.068 0.43366E+04 203 montmorillonite-K -10.40 -11.58 -1.18 -0.072 0.46365E+04 204 montmorillonite-Mg -11.41 -12.33 -0.92 -0.057 0.36155E+04 205 montmorillonite-Na -10.04 -11.42 -1.38 -0.084 0.54124E+04 206 nontronite-Ca -3.66 -4.98 -1.32 -0.086 0.51919E+04 207 nontronite-H -3.66 -5.50 -1.84 -0.123 0.72180E+04 208 nontronite-K -2.60 -4.28 -1.69 -0.108 0.66306E+04 209 nontronite-Mg -3.91 -5.03 -1.13 -0.073 0.44310E+04 210 nontronite-Na -2.53 -4.12 -1.59 -0.102 0.62420E+04 215 gypsum -11.71 -13.88 -2.17 -0.543 0.85329E+04 232 alabandite -6.11 -7.55 -1.44 -0.481 0.56701E+04 234 anglesite -14.01 -16.59 -2.58 -1.291 0.10152E+05 238 boehmite -4.71 -5.72 -1.01 -0.169 0.39846E+04 242 copper,native 1.78 -1.55 -3.33 -1.159 0.13100E+05 244 ferrous-oxide 1.76 0.99 -0.77 -0.193 0.30427E+04 245 galena -9.23 -9.55 -0.32 -0.108 0.12682E+04 246 silver,native 0.55 -3.59 -4.14 -1.441 0.16287E+05 248 litharge 5.18 0.44 -4.74 -1.186 0.18649E+05 256 wurtzite -9.78 -10.56 -0.79 -0.262 0.30882E+04 257 zincite 1.89 -0.58 -2.47 -0.617 0.97076E+04 258 an20ab80 -5.79 -5.81 -0.02 -0.001 0.68857E+02 259 an25ab75 -6.09 -6.09 -0.01 0.000 0.22797E+02 261 tr.625ac.25prg.125 8.69 7.99 -0.70 -0.019 0.27683E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 16 Loop limit = 500 Temperature = 586.00 C Pressure = 1621.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5506E+02 kg liquid = 0.9919E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9956 Stoichiometric ionic strength = .3305934E+01 Osmotic coef. = 0.0000 True ionic strength = .2354430E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11027E-04 -4.9575 0.29027E-05 -5.5372 0.26323E+00 -0.5797 2 H2O 0.99558E+00 -0.0019 0.99558E+00 -0.0019 3 Cl- 0.19723E+00 -0.7050 0.46976E-01 -1.3281 0.23817E+00 -0.6231 4 SO4-- 0.17804E-03 -3.7495 0.11079E-05 -5.9555 0.62228E-02 -2.2060 5 HCO3- 0.24469E-04 -4.6114 0.62788E-05 -5.2021 0.25661E+00 -0.5907 6 HS- 0.14770E-03 -3.8306 0.35474E-04 -4.4501 0.24017E+00 -0.6195 7 H4SiO4 0.90284E-01 -1.0444 0.90284E-01 -1.0444 0.10000E+01 0.0000 8 Al+++ 0.55201E-17 -17.2581 0.46784E-22 -22.3299 0.84752E-05 -5.0719 9 Ca++ 0.23819E-05 -5.6231 0.12015E-07 -7.9203 0.50443E-02 -2.2972 10 Mg++ 0.12571E-05 -5.9006 0.52223E-08 -8.2821 0.41541E-02 -2.3815 11 Fe++ 0.18803E-07 -7.7258 0.82073E-10 -10.0858 0.43648E-02 -2.3600 12 K+ 0.52881E-01 -1.2767 0.13919E-01 -1.8564 0.26321E+00 -0.5797 13 Na+ 0.18024E+00 -0.7442 0.43495E-01 -1.3616 0.24132E+00 -0.6174 14 Mn++ 0.51114E-06 -6.2915 0.23129E-08 -8.6359 0.45249E-02 -2.3444 15 Zn++ 0.51466E-09 -9.2885 0.22464E-11 -11.6485 0.43648E-02 -2.3600 16 Cu+ 0.44397E-07 -7.3527 0.10685E-07 -7.9712 0.24067E+00 -0.6186 17 Pb++ 0.40855E-08 -8.3888 0.23043E-10 -10.6375 0.56402E-02 -2.2487 18 Ag+ 0.37923E-09 -9.4211 0.98273E-10 -10.0076 0.25914E+00 -0.5865 19 Ba++ 0.19088E-06 -6.7192 0.11549E-08 -8.9375 0.60503E-02 -2.2182 20 HPO4-- 0.95014E-09 -9.0222 0.59416E-11 -11.2261 0.62534E-02 -2.2039 21 HSiO3- 0.21099E-05 -5.6757 0.50252E-06 -6.2988 0.23817E+00 -0.6231 22 Ca(HSiO3)+ 0.12828E-07 -7.8918 0.34059E-08 -8.4678 0.26551E+00 -0.5759 23 Mg(HSiO3)+ 0.14610E-08 -8.8353 0.38792E-09 -9.4113 0.26551E+00 -0.5759 24 NaHSiO3,aq 0.14737E-05 -5.8316 0.14737E-05 -5.8316 0.10000E+01 0.0000 28 AgCl,aq 0.73044E-07 -7.1364 0.73044E-07 -7.1364 0.10000E+01 0.0000 29 AgCl2- 0.49647E-05 -5.3041 0.11825E-05 -5.9272 0.23817E+00 -0.6231 30 AgCl3-2 0.23866E-05 -5.6222 0.13768E-07 -7.8611 0.57689E-02 -2.2389 31 AgCl4-3 0.13427E-05 -5.8720 0.97809E-11 -11.0096 0.72843E-05 -5.1376 34 Ag(HS),aq 0.69388E-09 -9.1587 0.69388E-09 -9.1587 0.10000E+01 0.0000 35 Ag(HS)2- 0.41895E-08 -8.3778 0.99783E-09 -9.0009 0.23817E+00 -0.6231 36 AlO+ 0.10219E-10 -10.9906 0.27132E-11 -11.5665 0.26551E+00 -0.5759 38 HAlO2,aq 0.43754E-08 -8.3590 0.43754E-08 -8.3590 0.10000E+01 0.0000 39 AlO2- 0.18781E-04 -4.7263 0.39096E-05 -5.4079 0.20817E+00 -0.6816 41 Ba(HCO3)+ 0.97040E-06 -6.0131 0.26793E-06 -6.5720 0.27610E+00 -0.5589 42 BaCl+ 0.33352E-04 -4.4769 0.88552E-05 -5.0528 0.26551E+00 -0.5759 43 CH4,aq 0.19467E-08 -8.7107 0.23582E-08 -8.6274 0.12114E+01 0.0833 48 CO,aq 0.77962E-03 -3.1081 0.77962E-03 -3.1081 0.10000E+01 0.0000 49 CO2,aq 0.26771E+01 0.4277 0.32431E+01 0.5110 0.12114E+01 0.0833 50 CO3-2 0.50409E-10 -10.2975 0.29081E-12 -12.5364 0.57689E-02 -2.2389 51 CaCO3,aq 0.17736E-10 -10.7511 0.17736E-10 -10.7511 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.57311E-06 -6.2418 0.15217E-06 -6.8177 0.26551E+00 -0.5759 53 CaCl+ 0.22447E-03 -3.6488 0.59600E-04 -4.2248 0.26551E+00 -0.5759 54 CaCl2,aq 0.13830E-03 -3.8592 0.13830E-03 -3.8592 0.10000E+01 0.0000 55 CaOH+ 0.36426E-06 -6.4386 0.96714E-07 -7.0145 0.26551E+00 -0.5759 56 CaSO4,aq 0.13588E-06 -6.8668 0.13588E-06 -6.8668 0.10000E+01 0.0000 57 HCl,aq 0.12356E-02 -2.9081 0.12356E-02 -2.9081 0.10000E+01 0.0000 66 CuCl,aq 0.34097E-04 -4.4673 0.34097E-04 -4.4673 0.10000E+01 0.0000 67 CuCl2- 0.13609E-03 -3.8662 0.32413E-04 -4.4893 0.23817E+00 -0.6231 68 CuCl3-2 0.34530E-05 -5.4618 0.19920E-07 -7.7007 0.57689E-02 -2.2389 74 FeCl+ 0.55175E-06 -6.2583 0.14649E-06 -6.8342 0.26551E+00 -0.5759 75 FeCl2,aq 0.80559E-02 -2.0939 0.80559E-02 -2.0939 0.10000E+01 0.0000 77 FeO,aq 0.83553E-07 -7.0780 0.83553E-07 -7.0780 0.10000E+01 0.0000 78 FeOH+ 0.42215E-07 -7.3745 0.11209E-07 -7.9504 0.26551E+00 -0.5759 79 HFeO2- 0.11479E-07 -7.9401 0.27340E-08 -8.5632 0.23817E+00 -0.6231 82 FeO2- 0.73668E-08 -8.1327 0.17546E-08 -8.7558 0.23817E+00 -0.6231 83 HFeO2,aq 0.25470E-09 -9.5940 0.25470E-09 -9.5940 0.10000E+01 0.0000 84 H2,aq 0.45418E-02 -2.3428 0.55020E-02 -2.2595 0.12114E+01 0.0833 85 KCl,aq 0.56901E-01 -1.2449 0.56901E-01 -1.2449 0.10000E+01 0.0000 86 KHSO4,aq 0.12825E-01 -1.8919 0.12825E-01 -1.8919 0.10000E+01 0.0000 87 KOH,aq 0.98487E-06 -6.0066 0.98487E-06 -6.0066 0.10000E+01 0.0000 88 KSO4- 0.38330E-02 -2.4165 0.91293E-03 -3.0396 0.23817E+00 -0.6231 90 Mg(HCO3)+ 0.10376E-06 -6.9840 0.27550E-07 -7.5599 0.26551E+00 -0.5759 91 MgCl+ 0.18536E-04 -4.7320 0.49216E-05 -5.3079 0.26551E+00 -0.5759 92 MgOH+ 0.64692E-06 -6.1891 0.17176E-06 -6.7651 0.26551E+00 -0.5759 94 MnO,aq 0.35582E-07 -7.4488 0.35582E-07 -7.4488 0.10000E+01 0.0000 95 MnOH+ 0.14806E-06 -6.8296 0.39312E-07 -7.4055 0.26551E+00 -0.5759 97 HMnO2- 0.22804E-10 -10.6420 0.54312E-11 -11.2651 0.23817E+00 -0.6231 100 MnCl+ 0.11582E-02 -2.9362 0.30752E-03 -3.5121 0.26551E+00 -0.5759 101 MnSO4,aq 0.33093E-07 -7.4803 0.33093E-07 -7.4803 0.10000E+01 0.0000 102 NaCl,aq 0.37855E+00 -0.4219 0.37855E+00 -0.4219 0.10000E+01 0.0000 103 NaOH,aq 0.14255E-05 -5.8460 0.14255E-05 -5.8460 0.10000E+01 0.0000 105 OH- 0.92404E-05 -5.0343 0.19236E-05 -5.7159 0.20817E+00 -0.6816 110 HPO3-2 0.15128E-10 -10.8202 0.87270E-13 -13.0591 0.57689E-02 -2.2389 111 H3PO3,aq 0.11629E-09 -9.9345 0.11629E-09 -9.9345 0.10000E+01 0.0000 112 H2PO3- 0.47305E-08 -8.3251 0.11267E-08 -8.9482 0.23817E+00 -0.6231 113 H3PO4,aq 0.85591E-06 -6.0676 0.85591E-06 -6.0676 0.10000E+01 0.0000 114 H2PO4- 0.18044E-05 -5.7437 0.45192E-06 -6.3449 0.25045E+00 -0.6013 116 H4P2O7,aq 0.60747E-10 -10.2165 0.60747E-10 -10.2165 0.10000E+01 0.0000 117 H3P2O7- 0.11880E-08 -8.9252 0.28295E-09 -9.5483 0.23817E+00 -0.6231 118 H2P2O7-2 0.33688E-06 -6.4725 0.19435E-08 -8.7114 0.57689E-02 -2.2389 119 HP2O7-3 0.12531E-07 -7.9020 0.91277E-13 -13.0396 0.72843E-05 -5.1376 121 PbCl+ 0.24152E-05 -5.6170 0.64127E-06 -6.1930 0.26551E+00 -0.5759 122 PbCl2,aq 0.88945E-04 -4.0509 0.88945E-04 -4.0509 0.10000E+01 0.0000 123 PbCl3- 0.11168E-03 -3.9520 0.26600E-04 -4.5751 0.23817E+00 -0.6231 124 PbCl4-2 0.27910E-04 -4.5542 0.16101E-06 -6.7931 0.57689E-02 -2.2389 125 PbO,aq 0.39413E-08 -8.4044 0.39413E-08 -8.4044 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10222E-03 -3.9904 0.10222E-03 -3.9904 0.10000E+01 0.0000 128 Pb(HS)3- 0.97824E-05 -5.0096 0.23299E-05 -5.6327 0.23817E+00 -0.6231 129 H2S,aq 0.10471E+01 0.0200 0.12684E+01 0.1033 0.12114E+01 0.0833 130 S2-2 0.15393E-07 -7.8127 0.88799E-10 -10.0516 0.57689E-02 -2.2389 131 S3-2 0.16223E-08 -8.7899 0.93587E-11 -11.0288 0.57689E-02 -2.2389 132 S3- 0.20789E-01 -1.6822 0.49514E-02 -2.3053 0.23817E+00 -0.6231 133 S4-2 0.14225E-09 -9.8470 0.82060E-12 -12.0859 0.57689E-02 -2.2389 134 S5-2 0.10554E-10 -10.9766 0.60884E-13 -13.2155 0.57689E-02 -2.2389 135 SO2,aq 0.28404E+00 -0.5466 0.28404E+00 -0.5466 0.10000E+01 0.0000 136 SO3-2 0.60255E-09 -9.2200 0.54331E-11 -11.2650 0.90168E-02 -2.0449 137 HSO3- 0.42435E-03 -3.3723 0.10107E-03 -3.9954 0.23817E+00 -0.6231 138 HSO4- 0.11848E-01 -1.9264 0.32267E-02 -2.4912 0.27234E+00 -0.5649 140 S2O3-2 0.53339E-06 -6.2730 0.30771E-08 -8.5119 0.57689E-02 -2.2389 141 HS2O3- 0.68884E-06 -6.1619 0.16406E-06 -6.7850 0.23817E+00 -0.6231 142 H2S2O3,aq 0.24694E-07 -7.6074 0.24694E-07 -7.6074 0.10000E+01 0.0000 150 S4O6-2 0.68556E-09 -9.1640 0.39550E-11 -11.4029 0.57689E-02 -2.2389 152 ZnCl+ 0.64150E-03 -3.1928 0.17033E-03 -3.7687 0.26551E+00 -0.5759 153 ZnCl2,aq 0.14376E-02 -2.8424 0.14376E-02 -2.8424 0.10000E+01 0.0000 154 ZnCl3- 0.19613E-03 -3.7075 0.46714E-04 -4.3306 0.23817E+00 -0.6231 155 ZnO,aq 0.41632E-07 -7.3806 0.41632E-07 -7.3806 0.10000E+01 0.0000 156 ZnOH+ 0.32760E-05 -5.4847 0.86982E-06 -6.0606 0.26551E+00 -0.5759 158 HZnO2- 0.36436E-09 -9.4385 0.86782E-10 -10.0616 0.23817E+00 -0.6231 Charge balance for all species = 0.2552E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1102733E-04 0.4301418E+01 0.3533241E+04 0.0000 2 H2O 0.1000000E+01 0.5249892E+02 0.7707595E+06 0.0000 3 Cl- 0.1972333E+00 0.6568134E+00 0.1897676E+05 4.2091 4 SO4-- 0.1780358E-03 0.2536950E+00 0.1986044E+05 5.1189 5 HCO3- 0.2446875E-04 0.2677937E+01 0.1331618E+06 0.3351 6 HS- 0.1477034E-03 0.1169253E+01 0.3151345E+05 1.0871 7 H4SiO4 0.9028375E-01 0.9028735E-01 0.7072075E+04 -1.0444 8 Al+++ 0.5520139E-17 0.1878501E-04 0.4130517E+00 -5.7183 9 Ca++ 0.2381922E-05 0.3662376E-03 0.1196178E+02 3.1541 10 Mg++ 0.1257137E-05 0.2054576E-04 0.4070707E+00 2.7923 11 Fe++ 0.1880342E-07 0.8056646E-02 0.3666749E+03 0.9886 12 K+ 0.5288074E-01 0.1264404E+00 0.4029136E+04 3.6808 13 Na+ 0.1802374E+00 0.5587894E+00 0.1046912E+05 4.1756 14 Mn++ 0.5111380E-06 0.1158941E-02 0.5188732E+02 2.4385 15 Zn++ 0.5146589E-09 0.2278507E-02 0.1213824E+03 -0.5741 16 Cu+ 0.4439659E-07 0.1736855E-03 0.8993685E+01 -2.4340 17 Pb++ 0.4085490E-08 0.3429677E-03 0.5790939E+02 0.4369 18 Ag+ 0.3792318E-09 0.8772333E-05 0.7711569E+00 -4.4704 19 Ba++ 0.1908784E-06 0.3451284E-04 0.3862823E+01 2.1369 20 HPO4-- 0.9501389E-09 0.3367453E-05 0.2633933E+00 -0.1517 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4266363E+01 -.4000685E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5207108E+02 -.1062968E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2516275E+00 0.9524863E-04 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159724E+01 0.4199681E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.8955155E-01 0.5404278E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1863192E-04 0.6759076E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3632529E-03 0.1646570E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2037832E-04 0.2983354E-06 0.0000000E+00 11 Fe++ 0.8766754E-02 0.7990988E-02 0.7757658E-03 0.0000000E+00 12 K+ 0.1254101E+00 0.1254100E+00 0.1481978E-06 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542355E+00 0.3638705E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149496E-02 0.3689930E-08 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2259938E-02 0.3939648E-04 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1722700E-03 0.2273397E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.3423158E-04 0.2114087E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3340009E-05 0.5227491E-05 0.0000000E+00 Chg. balance for solid moles: -.4201E-18 Mass of aqueous solution: 0.121708E+04 g Temperature = 586.00 C Pressure = 1621.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1742E-05 -5.759 0.8753E-03 -3.058 0.2578E-01 0.2781E-03 magnetite 0.1828E-03 -3.738 0.4231E-01 -1.374 1.246 0.8136E-02 quartz 0.5264E-01 -1.279 3.163 0.500 93.15 1.194 barite 0.2114E-04 -4.675 0.4934E-02 -2.307 0.1453 0.1101E-02 chalcopyrite 0.2273E-03 -3.643 0.4172E-01 -1.380 1.229 0.9738E-02 sphalerite 0.3940E-04 -4.405 0.3838E-02 -2.416 0.1131 0.9387E-03 an30ab70 0.5198E-03 -3.284 0.1388 -0.858 4.088 0.5212E-01 annite 0.4752E-07 -7.323 0.2433E-04 -4.614 0.7165E-03 0.7334E-05 phlogopite 0.9945E-07 -7.002 0.4150E-04 -4.382 0.1222E-02 0.1488E-04 biotite-Mn 0.1230E-08 -8.910 0.6263E-06 -6.203 0.1845E-04 0.1877E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3207E+00 0.3207E+00 1.0000 -0.494 phlogopite 0.6710E+00 0.6710E+00 1.0000 -0.173 biotite-Mn 0.8300E-02 0.8300E-02 1.0000 -2.081 Solid products produced: Mass = 3.395081 g Volume = 1.266650 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 24 annite -0.72 -0.72 0.00 0.000 0.17459E-11 25 phlogopite 3.73 3.73 0.00 0.000 0.36663E-10 26 biotite-Mn 8.39 8.39 0.00 0.000 0.27934E-10 30 apatite-OH -51.13 -51.13 0.00 0.000 0.00000E+00 106 magnetite 1.20 1.20 0.00 0.000 0.17459E-10 144 quartz -1.04 -1.04 0.00 0.000 0.00000E+00 237 barite -14.89 -14.89 0.00 0.000 -0.69834E-11 240 chalcopyrite -22.30 -22.30 0.00 0.000 0.00000E+00 255 sphalerite -10.56 -10.56 0.00 0.000 0.00000E+00 260 an30ab70 -6.38 -6.38 0.00 0.000 0.13967E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.288 0.11314E+04 2.922 2 CO2,gas -9.26 -10.74 -1.48 -0.492 0.58008E+04 1.734 3 CH4,gas 6.92 -3.70 -10.62 -2.655 0.41744E+05 -7.408 4 H2,gas 5.80 1.76 -4.04 -2.311 0.15896E+05 -0.834 5 H2S,gas -7.71 -9.99 -2.28 -1.138 0.89490E+04 0.933 6 CO,gas -3.28 -8.98 -5.69 -1.751 0.22378E+05 -2.482 7 SO3,gas -6.71 -17.03 -10.32 -2.580 0.40575E+05 -7.111 8 O2,gas 16.52 -3.52 -20.04 -13.363 0.78801E+05 -16.835 9 HCl,gas -5.72 -6.87 -1.14 -0.572 0.44971E+04 -1.144 10 acmite 3.78 2.20 -1.58 -0.164 0.62053E+04 12 akimotoite 5.83 1.75 -4.08 -0.817 0.16050E+05 13 akimotoite-Fe 3.80 -0.05 -3.85 -0.771 0.15146E+05 14 albite-high -4.52 -4.67 -0.15 -0.011 0.57336E+03 15 albite -4.49 -4.67 -0.17 -0.013 0.68289E+03 16 almandine -10.27 -11.60 -1.34 -0.067 0.52615E+04 17 pyrope -3.84 -6.19 -2.35 -0.118 0.92533E+04 18 analcite -2.66 -3.63 -0.97 -0.107 0.37954E+04 19 andalusite -12.18 -12.48 -0.30 -0.030 0.11717E+04 20 andradite 11.07 6.55 -4.52 -0.235 0.17778E+05 21 grossular -0.44 -5.11 -4.67 -0.234 0.18364E+05 22 anhydrite -13.86 -13.88 -0.01 -0.007 0.52543E+02 27 anorthite -9.89 -10.37 -0.48 -0.037 0.18826E+04 28 anthophyllite 13.30 11.21 -2.10 -0.057 0.82400E+04 29 anthophyllite-Fe 1.12 -1.42 -2.54 -0.069 0.99700E+04 31 apatite-OH-zs -49.02 -51.13 -2.11 -0.162 0.82870E+04 32 apatite-Cl-zs -54.91 -58.00 -3.09 -0.257 0.12130E+05 33 aragonite -4.20 -7.59 -3.38 -1.128 0.13306E+05 34 brucite 4.99 2.79 -2.20 -0.441 0.86604E+04 35 calcite -4.30 -7.59 -3.29 -1.097 0.12935E+05 36 carnegieite-low -0.81 -2.59 -1.78 -0.254 0.69824E+04 37 carnegieite-high -0.74 -2.59 -1.84 -0.263 0.72440E+04 38 carpholite-Mg -8.95 -10.74 -1.79 -0.119 0.70270E+04 39 carpholite-Fe -10.26 -12.54 -2.28 -0.152 0.89747E+04 40 celadonite -1.31 -3.42 -2.11 -0.124 0.82803E+04 41 celadonite-Fe -2.67 -5.22 -2.55 -0.150 0.10010E+05 42 chrysotile 8.66 6.29 -2.37 -0.198 0.93187E+04 44 clinochlore 0.62 -0.62 -1.24 -0.039 0.48570E+04 45 daphnite -6.21 -9.64 -3.43 -0.107 0.13494E+05 47 chlorite-Al-free 17.52 12.57 -4.94 -0.206 0.19439E+05 48 chloritoid-Mg -8.58 -9.69 -1.11 -0.074 0.43739E+04 49 chloritoid-Fe -10.45 -11.50 -1.05 -0.070 0.41342E+04 50 chloritoid-Mn -8.28 -10.05 -1.77 -0.118 0.69404E+04 52 coesite -0.76 -1.04 -0.28 -0.093 0.10919E+04 53 cordierite-H -22.08 -22.51 -0.43 -0.015 0.17033E+04 54 cordierite-Fe -24.48 -26.11 -1.63 -0.056 0.64148E+04 55 cordierite-Mn -20.08 -23.21 -3.14 -0.108 0.12340E+05 56 corundum -10.98 -11.44 -0.46 -0.042 0.18210E+04 58 cristobalite -0.99 -1.04 -0.05 -0.017 0.20385E+03 59 cummingtonite 13.36 11.21 -2.15 -0.058 0.84676E+04 61 cymrite-K -2.89 -5.16 -2.28 -0.190 0.89441E+04 63 diaspore -4.99 -5.72 -0.74 -0.123 0.28924E+04 65 diopside 5.14 3.86 -1.28 -0.128 0.50387E+04 66 hedenbergite 3.77 2.06 -1.71 -0.171 0.67346E+04 68 eastonite -8.83 -9.99 -1.16 -0.044 0.45484E+04 69 enstatite 4.32 3.50 -0.82 -0.082 0.32136E+04 70 clinoenstatite-HiP 4.80 3.50 -1.30 -0.130 0.51043E+04 71 clinoenstatite 4.30 3.50 -0.80 -0.080 0.31628E+04 72 protoenstatite 4.45 3.50 -0.95 -0.095 0.37252E+04 73 epidote -6.25 -8.15 -1.91 -0.092 0.74986E+04 74 clinozoisite -11.73 -13.98 -2.25 -0.102 0.88497E+04 75 epidote-Fe 0.90 -2.33 -3.23 -0.168 0.12685E+05 76 fayalite 1.82 0.93 -0.88 -0.126 0.34777E+04 77 ferrosilite 0.87 -0.11 -0.97 -0.097 0.38244E+04 78 forsterite 5.68 4.54 -1.14 -0.163 0.44832E+04 79 gedrite -13.56 -15.18 -1.62 -0.044 0.63807E+04 81 gibbsite -3.40 -5.72 -2.33 -0.332 0.91479E+04 82 glaucophane 0.02 -3.05 -3.07 -0.083 0.12081E+05 83 glaucophane-Fe -3.87 -8.46 -4.59 -0.124 0.18037E+05 84 goethite 0.91 0.11 -0.80 -0.173 0.31446E+04 86 greenalite 3.97 0.88 -3.10 -0.258 0.12177E+05 87 grunerite 1.65 -1.42 -3.07 -0.083 0.12056E+05 88 halite -0.61 -2.69 -2.08 -1.040 0.81805E+04 89 hematite 0.30 0.21 -0.09 -0.011 0.34985E+03 90 heulandite -12.87 -15.59 -2.72 -0.123 0.10675E+05 91 hercynite -9.57 -10.46 -0.88 -0.059 0.34648E+04 94 jadeite -1.99 -3.63 -1.64 -0.164 0.64558E+04 96 kalsilite -1.44 -3.08 -1.64 -0.235 0.64565E+04 97 kaolinite -10.97 -13.53 -2.56 -0.232 0.10045E+05 98 kyanite -12.04 -12.48 -0.45 -0.045 0.17600E+04 100 laumontite -9.17 -12.46 -3.29 -0.219 0.12925E+05 101 lawsonite -7.19 -10.38 -3.19 -0.213 0.12539E+05 102 leucite -3.13 -4.12 -0.99 -0.099 0.39066E+04 104 lizardite 8.85 6.29 -2.56 -0.213 0.10062E+05 105 magnesite -5.22 -7.95 -2.73 -0.909 0.10719E+05 107 minnesotaite 0.65 -1.20 -1.85 -0.109 0.72922E+04 108 minnesotaite-Mg 6.42 4.21 -2.21 -0.130 0.87067E+04 109 magnesioferrite 4.18 3.00 -1.18 -0.096 0.46223E+04 111 manganosite 5.04 2.44 -2.61 -0.652 0.10247E+05 112 margarite -20.41 -21.82 -1.41 -0.056 0.55453E+04 115 microcline -5.09 -5.16 -0.08 -0.006 0.29819E+03 116 monticellite 8.31 4.90 -3.41 -0.487 0.13396E+05 118 mullite-Si -11.47 -12.48 -1.02 -0.102 0.39961E+04 119 muscovite -15.94 -16.61 -0.67 -0.039 0.26147E+04 120 paragonite -15.26 -16.11 -0.85 -0.050 0.33343E+04 121 nepheline -1.10 -2.59 -1.49 -0.212 0.58428E+04 122 osumilite(2) -14.76 -16.56 -1.79 -0.037 0.70542E+04 123 osumilite-Fe -31.31 -33.36 -2.04 -0.043 0.80362E+04 124 pargasite 1.80 -1.77 -3.57 -0.094 0.14028E+05 125 periclase 5.18 2.79 -2.39 -0.596 0.93772E+04 126 periclase-Fe 2.67 0.99 -1.68 -0.421 0.66232E+04 127 perovskite-Al -9.29 -11.44 -2.16 -0.196 0.84750E+04 132 phlogopite-Na 4.59 3.70 -0.89 -0.049 0.34841E+04 134 prehnite -5.26 -8.26 -3.00 -0.176 0.11789E+05 135 prehnite-Fe 0.61 -2.43 -3.05 -0.183 0.11982E+05 138 px-Mg-tschermaks -8.03 -9.69 -1.67 -0.119 0.65506E+04 139 px-Ca-tschermaks -7.02 -9.33 -2.31 -0.165 0.91007E+04 140 pyrite -20.72 -20.74 -0.03 -0.007 0.10970E+03 141 pyrrhotite -8.39 -9.00 -0.61 -0.204 0.24089E+04 142 pyrrhotiteFe0.875 -9.10 -9.34 -0.24 -0.090 0.95893E+03 143 pyrophyllite -14.44 -15.61 -1.16 -0.073 0.45752E+04 146 riebeckite 6.00 3.20 -2.80 -0.077 0.11027E+05 147 ringwoodite-Fe 2.80 0.93 -1.86 -0.266 0.73310E+04 148 ringwoodite-Mg 8.77 4.54 -4.23 -0.604 0.16617E+05 149 rhodochrosite -5.09 -8.30 -3.21 -1.072 0.12638E+05 150 rhodonite 2.41 1.40 -1.01 -0.203 0.39858E+04 151 sanidine -4.56 -5.16 -0.60 -0.046 0.23674E+04 152 sapphirine(351) -45.31 -49.88 -4.57 -0.069 0.17982E+05 153 siderite -6.99 -9.75 -2.76 -0.921 0.10863E+05 154 sillimanite -12.16 -12.48 -0.33 -0.033 0.12848E+04 156 spinel -7.47 -8.65 -1.18 -0.079 0.46548E+04 158 staurolite-Fe -102.13 -106.84 -4.72 -0.043 0.18539E+05 162 stilpnomelane-Fe -8.58 -13.01 -4.43 -0.132 0.17402E+05 163 stilpnomelane-Mg -2.10 -3.99 -1.88 -0.056 0.74044E+04 164 stishovite 1.84 -1.04 -2.88 -0.961 0.11339E+05 165 sudoite-Fe -20.42 -24.04 -3.62 -0.117 0.14238E+05 166 sudoite -18.29 -20.43 -2.15 -0.069 0.84416E+04 167 sulfur -10.26 -11.75 -1.49 -0.457 0.58385E+04 168 sylvite -0.52 -3.18 -2.67 -1.334 0.10488E+05 169 talc 4.72 4.21 -0.51 -0.030 0.20208E+04 170 talc-Fe 2.01 -1.20 -3.21 -0.189 0.12630E+05 171 talc-tschermaks -7.55 -8.99 -1.44 -0.085 0.56509E+04 173 tephroite 6.14 3.83 -2.30 -0.329 0.90543E+04 176 topaz-H -10.12 -12.48 -2.36 -0.215 0.92828E+04 177 tremolite 14.38 11.93 -2.45 -0.066 0.96293E+04 179 troilite-low -8.29 -9.00 -0.71 -0.237 0.27906E+04 180 tschermakite -11.71 -14.45 -2.75 -0.074 0.10808E+05 183 wadsleyite-Fe 2.64 0.93 -1.71 -0.245 0.67307E+04 184 wadsleyite-Mg 7.84 4.54 -3.30 -0.471 0.12975E+05 185 wairakite -10.96 -12.46 -1.50 -0.088 0.59002E+04 186 walstromite 4.54 2.11 -2.42 -0.485 0.95280E+04 187 wollastonite 4.13 2.11 -2.02 -0.404 0.79398E+04 188 pseudo-wollastonite 4.24 2.11 -2.13 -0.426 0.83707E+04 189 zoisite -11.79 -13.98 -2.19 -0.100 0.86125E+04 192 beidellite-Ca -15.17 -16.63 -1.46 -0.090 0.57384E+04 193 beidellite-H -15.17 -17.15 -1.98 -0.127 0.77966E+04 194 beidellite-K -14.11 -15.94 -1.83 -0.112 0.71855E+04 195 beidellite-Mg -15.47 -16.69 -1.22 -0.075 0.47839E+04 196 beidellite-Na -14.05 -15.77 -1.73 -0.106 0.67835E+04 197 bornite -51.62 -52.01 -0.39 -0.029 0.15331E+04 199 chalcocite -13.37 -14.86 -1.49 -0.372 0.58525E+04 200 covellite -11.90 -13.30 -1.40 -0.535 0.55202E+04 202 montmorillonite-Ca -11.17 -12.28 -1.11 -0.068 0.43448E+04 203 montmorillonite-K -10.40 -11.58 -1.18 -0.072 0.46448E+04 204 montmorillonite-Mg -11.41 -12.34 -0.92 -0.057 0.36278E+04 205 montmorillonite-Na -10.04 -11.42 -1.38 -0.084 0.54206E+04 206 nontronite-Ca -3.66 -4.98 -1.32 -0.086 0.51919E+04 207 nontronite-H -3.66 -5.50 -1.84 -0.123 0.72180E+04 208 nontronite-K -2.60 -4.28 -1.69 -0.108 0.66306E+04 209 nontronite-Mg -3.91 -5.04 -1.13 -0.073 0.44351E+04 210 nontronite-Na -2.53 -4.12 -1.59 -0.102 0.62420E+04 215 gypsum -11.71 -13.88 -2.17 -0.543 0.85328E+04 232 alabandite -6.11 -7.55 -1.44 -0.481 0.56701E+04 234 anglesite -14.01 -16.59 -2.58 -1.291 0.10152E+05 238 boehmite -4.71 -5.72 -1.01 -0.169 0.39846E+04 242 copper,native 1.78 -1.55 -3.33 -1.159 0.13100E+05 244 ferrous-oxide 1.76 0.99 -0.77 -0.193 0.30427E+04 245 galena -9.23 -9.55 -0.32 -0.108 0.12682E+04 246 silver,native 0.55 -3.59 -4.14 -1.441 0.16288E+05 248 litharge 5.18 0.44 -4.74 -1.186 0.18649E+05 256 wurtzite -9.78 -10.56 -0.79 -0.262 0.30882E+04 257 zincite 1.89 -0.58 -2.47 -0.617 0.97076E+04 258 an20ab80 -5.79 -5.81 -0.02 -0.001 0.68869E+02 259 an25ab75 -6.09 -6.09 -0.01 0.000 0.22803E+02 261 tr.625ac.25prg.125 8.69 7.96 -0.73 -0.020 0.28580E+04 Calculations done for 586.0000 Deg. C; 1621.0000 bar Temperature changed by -1.000 degrees to 585.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 26 Loop limit = 500 Temperature = 585.00 C Pressure = 1589.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5506E+02 kg liquid = 0.9919E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9957 Stoichiometric ionic strength = .3304918E+01 Osmotic coef. = 0.0000 True ionic strength = .2319674E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10727E-04 -4.9695 0.27921E-05 -5.5541 0.26029E+00 -0.5845 2 H2O 0.99566E+00 -0.0019 0.99566E+00 -0.0019 3 Cl- 0.19438E+00 -0.7113 0.45602E-01 -1.3410 0.23460E+00 -0.6297 4 SO4-- 0.17901E-03 -3.7471 0.10631E-05 -5.9734 0.59387E-02 -2.2263 5 HCO3- 0.23548E-04 -4.6280 0.59546E-05 -5.2251 0.25287E+00 -0.5971 6 HS- 0.14601E-03 -3.8356 0.34542E-04 -4.4616 0.23658E+00 -0.6260 7 H4SiO4 0.88072E-01 -1.0552 0.88072E-01 -1.0552 0.10000E+01 0.0000 8 Al+++ 0.56485E-17 -17.2481 0.43127E-22 -22.3653 0.76350E-05 -5.1172 9 Ca++ 0.23912E-05 -5.6214 0.11495E-07 -7.9395 0.48073E-02 -2.3181 10 Mg++ 0.12486E-05 -5.9036 0.49370E-08 -8.3065 0.39542E-02 -2.4029 11 Fe++ 0.18524E-07 -7.7323 0.76987E-10 -10.1136 0.41560E-02 -2.3813 12 K+ 0.52258E-01 -1.2818 0.13557E-01 -1.8678 0.25942E+00 -0.5860 13 Na+ 0.17742E+00 -0.7510 0.42176E-01 -1.3749 0.23771E+00 -0.6239 14 Mn++ 0.52199E-06 -6.2823 0.22495E-08 -8.6479 0.43094E-02 -2.3656 15 Zn++ 0.50054E-09 -9.3006 0.20802E-11 -11.6819 0.41560E-02 -2.3813 16 Cu+ 0.42019E-07 -7.3766 0.99617E-08 -8.0017 0.23708E+00 -0.6251 17 Pb++ 0.39982E-08 -8.3981 0.21507E-10 -10.6674 0.53791E-02 -2.2693 18 Ag+ 0.37213E-09 -9.4293 0.95034E-10 -10.0221 0.25538E+00 -0.5928 19 Ba++ 0.18351E-06 -6.7363 0.10594E-08 -8.9750 0.57728E-02 -2.2386 20 HPO4-- 0.90252E-09 -9.0445 0.53864E-11 -11.2687 0.59682E-02 -2.2242 21 HSiO3- 0.20610E-05 -5.6859 0.48351E-06 -6.3156 0.23460E+00 -0.6297 22 Ca(HSiO3)+ 0.12612E-07 -7.8992 0.33005E-08 -8.4814 0.26170E+00 -0.5822 23 Mg(HSiO3)+ 0.14280E-08 -8.8453 0.37369E-09 -9.4275 0.26170E+00 -0.5822 24 NaHSiO3,aq 0.14777E-05 -5.8304 0.14777E-05 -5.8304 0.10000E+01 0.0000 28 AgCl,aq 0.73518E-07 -7.1336 0.73518E-07 -7.1336 0.10000E+01 0.0000 29 AgCl2- 0.49603E-05 -5.3045 0.11637E-05 -5.9342 0.23460E+00 -0.6297 30 AgCl3-2 0.23656E-05 -5.6261 0.13018E-07 -7.8855 0.55029E-02 -2.2594 31 AgCl4-3 0.13670E-05 -5.8642 0.89632E-11 -11.0475 0.65567E-05 -5.1833 34 Ag(HS),aq 0.71168E-09 -9.1477 0.71168E-09 -9.1477 0.10000E+01 0.0000 35 Ag(HS)2- 0.42411E-08 -8.3725 0.99497E-09 -9.0022 0.23460E+00 -0.6297 36 AlO+ 0.10081E-10 -10.9965 0.26381E-11 -11.5787 0.26170E+00 -0.5822 38 HAlO2,aq 0.43579E-08 -8.3607 0.43579E-08 -8.3607 0.10000E+01 0.0000 39 AlO2- 0.18312E-04 -4.7373 0.37520E-05 -5.4257 0.20489E+00 -0.6885 41 Ba(HCO3)+ 0.91786E-06 -6.0372 0.24985E-06 -6.6023 0.27221E+00 -0.5651 42 BaCl+ 0.31782E-04 -4.4978 0.83172E-05 -5.0800 0.26170E+00 -0.5822 43 CH4,aq 0.19212E-08 -8.7164 0.23256E-08 -8.6335 0.12105E+01 0.0830 48 CO,aq 0.76550E-03 -3.1161 0.76550E-03 -3.1161 0.10000E+01 0.0000 49 CO2,aq 0.26770E+01 0.4276 0.32405E+01 0.5106 0.12105E+01 0.0830 50 CO3-2 0.49094E-10 -10.3090 0.27016E-12 -12.5684 0.55029E-02 -2.2594 51 CaCO3,aq 0.17737E-10 -10.7511 0.17737E-10 -10.7511 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.55184E-06 -6.2582 0.14441E-06 -6.8404 0.26170E+00 -0.5822 53 CaCl+ 0.22224E-03 -3.6532 0.58159E-04 -4.2354 0.26170E+00 -0.5822 54 CaCl2,aq 0.14008E-03 -3.8536 0.14008E-03 -3.8536 0.10000E+01 0.0000 55 CaOH+ 0.36189E-06 -6.4414 0.94706E-07 -7.0236 0.26170E+00 -0.5822 56 CaSO4,aq 0.14069E-06 -6.8518 0.14069E-06 -6.8518 0.10000E+01 0.0000 57 HCl,aq 0.12724E-02 -2.8954 0.12724E-02 -2.8954 0.10000E+01 0.0000 66 CuCl,aq 0.33191E-04 -4.4790 0.33191E-04 -4.4790 0.10000E+01 0.0000 67 CuCl2- 0.13257E-03 -3.8776 0.31101E-04 -4.5072 0.23460E+00 -0.6297 68 CuCl3-2 0.33466E-05 -5.4754 0.18416E-07 -7.7348 0.55029E-02 -2.2594 74 FeCl+ 0.53585E-06 -6.2710 0.14023E-06 -6.8532 0.26170E+00 -0.5822 75 FeCl2,aq 0.78317E-02 -2.1061 0.78317E-02 -2.1061 0.10000E+01 0.0000 77 FeO,aq 0.82641E-07 -7.0828 0.82641E-07 -7.0828 0.10000E+01 0.0000 78 FeOH+ 0.40935E-07 -7.3879 0.10713E-07 -7.9701 0.26170E+00 -0.5822 79 HFeO2- 0.11131E-07 -7.9535 0.26112E-08 -8.5832 0.23460E+00 -0.6297 82 FeO2- 0.72264E-08 -8.1411 0.16953E-08 -8.7707 0.23460E+00 -0.6297 83 HFeO2,aq 0.25664E-09 -9.5907 0.25664E-09 -9.5907 0.10000E+01 0.0000 84 H2,aq 0.45351E-02 -2.3434 0.54897E-02 -2.2604 0.12105E+01 0.0830 85 KCl,aq 0.57503E-01 -1.2403 0.57503E-01 -1.2403 0.10000E+01 0.0000 86 KHSO4,aq 0.12814E-01 -1.8923 0.12814E-01 -1.8923 0.10000E+01 0.0000 87 KOH,aq 0.99320E-06 -6.0030 0.99320E-06 -6.0030 0.10000E+01 0.0000 88 KSO4- 0.38560E-02 -2.4139 0.90463E-03 -3.0435 0.23460E+00 -0.6297 90 Mg(HCO3)+ 0.98266E-07 -7.0076 0.25716E-07 -7.5898 0.26170E+00 -0.5822 91 MgCl+ 0.18194E-04 -4.7401 0.47614E-05 -5.3223 0.26170E+00 -0.5822 92 MgOH+ 0.63526E-06 -6.1970 0.16625E-06 -6.7792 0.26170E+00 -0.5822 94 MnO,aq 0.36607E-07 -7.4364 0.36607E-07 -7.4364 0.10000E+01 0.0000 95 MnOH+ 0.14856E-06 -6.8281 0.38878E-07 -7.4103 0.26170E+00 -0.5822 97 HMnO2- 0.22926E-10 -10.6397 0.53786E-11 -11.2693 0.23460E+00 -0.6297 100 MnCl+ 0.11581E-02 -2.9362 0.30308E-03 -3.5184 0.26170E+00 -0.5822 101 MnSO4,aq 0.34765E-07 -7.4589 0.34765E-07 -7.4589 0.10000E+01 0.0000 102 NaCl,aq 0.38133E+00 -0.4187 0.38133E+00 -0.4187 0.10000E+01 0.0000 103 NaOH,aq 0.14327E-05 -5.8438 0.14327E-05 -5.8438 0.10000E+01 0.0000 105 OH- 0.90883E-05 -5.0415 0.18621E-05 -5.7300 0.20489E+00 -0.6885 110 HPO3-2 0.14015E-10 -10.8534 0.77122E-13 -13.1128 0.55029E-02 -2.2594 111 H3PO3,aq 0.10958E-09 -9.9602 0.10958E-09 -9.9602 0.10000E+01 0.0000 112 H2PO3- 0.43323E-08 -8.3633 0.10164E-08 -8.9930 0.23460E+00 -0.6297 113 H3PO4,aq 0.82363E-06 -6.0843 0.82363E-06 -6.0843 0.10000E+01 0.0000 114 H2PO4- 0.16933E-05 -5.7713 0.41785E-06 -6.3790 0.24677E+00 -0.6077 116 H4P2O7,aq 0.56322E-10 -10.2493 0.56322E-10 -10.2493 0.10000E+01 0.0000 117 H3P2O7- 0.10576E-08 -8.9757 0.24811E-09 -9.6054 0.23460E+00 -0.6297 118 H2P2O7-2 0.29868E-06 -6.5248 0.16436E-08 -8.7842 0.55029E-02 -2.2594 119 HP2O7-3 0.11553E-07 -7.9373 0.75752E-13 -13.1206 0.65567E-05 -5.1833 121 PbCl+ 0.23547E-05 -5.6281 0.61621E-06 -6.2103 0.26170E+00 -0.5822 122 PbCl2,aq 0.88678E-04 -4.0522 0.88678E-04 -4.0522 0.10000E+01 0.0000 123 PbCl3- 0.11177E-03 -3.9517 0.26221E-04 -4.5814 0.23460E+00 -0.6297 124 PbCl4-2 0.27781E-04 -4.5562 0.15288E-06 -6.8157 0.55029E-02 -2.2594 125 PbO,aq 0.39877E-08 -8.3993 0.39877E-08 -8.3993 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10245E-03 -3.9895 0.10245E-03 -3.9895 0.10000E+01 0.0000 128 Pb(HS)3- 0.99068E-05 -5.0041 0.23241E-05 -5.6337 0.23460E+00 -0.6297 129 H2S,aq 0.10479E+01 0.0203 0.12684E+01 0.1033 0.12105E+01 0.0830 130 S2-2 0.15251E-07 -7.8167 0.83922E-10 -10.0761 0.55029E-02 -2.2594 131 S3-2 0.16052E-08 -8.7945 0.88332E-11 -11.0539 0.55029E-02 -2.2594 132 S3- 0.20330E-01 -1.6919 0.47693E-02 -2.3215 0.23460E+00 -0.6297 133 S4-2 0.14065E-09 -9.8519 0.77399E-12 -12.1113 0.55029E-02 -2.2594 134 S5-2 0.10436E-10 -10.9815 0.57427E-13 -13.2409 0.55029E-02 -2.2594 135 SO2,aq 0.28458E+00 -0.5458 0.28458E+00 -0.5458 0.10000E+01 0.0000 136 SO3-2 0.59567E-09 -9.2250 0.51386E-11 -11.2892 0.86266E-02 -2.0642 137 HSO3- 0.41638E-03 -3.3805 0.97684E-04 -4.0102 0.23460E+00 -0.6297 138 HSO4- 0.11682E-01 -1.9325 0.31364E-02 -2.5036 0.26848E+00 -0.5711 140 S2O3-2 0.53237E-06 -6.2738 0.29296E-08 -8.5332 0.55029E-02 -2.2594 141 HS2O3- 0.67360E-06 -6.1716 0.15803E-06 -6.8013 0.23460E+00 -0.6297 142 H2S2O3,aq 0.24913E-07 -7.6036 0.24913E-07 -7.6036 0.10000E+01 0.0000 150 S4O6-2 0.67852E-09 -9.1684 0.37338E-11 -11.4278 0.55029E-02 -2.2594 152 ZnCl+ 0.60846E-03 -3.2158 0.15923E-03 -3.7980 0.26170E+00 -0.5822 153 ZnCl2,aq 0.13930E-02 -2.8561 0.13930E-02 -2.8561 0.10000E+01 0.0000 154 ZnCl3- 0.18648E-03 -3.7294 0.43749E-04 -4.3590 0.23460E+00 -0.6297 155 ZnO,aq 0.40730E-07 -7.3901 0.40730E-07 -7.3901 0.10000E+01 0.0000 156 ZnOH+ 0.31256E-05 -5.5051 0.81795E-06 -6.0873 0.26170E+00 -0.5822 158 HZnO2- 0.34988E-09 -9.4561 0.82082E-10 -10.0858 0.23460E+00 -0.6297 Charge balance for all species = 0.2551E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1072683E-04 0.4301652E+01 0.3534123E+04 0.0000 2 H2O 0.1000000E+01 0.5249970E+02 0.7709211E+06 0.0000 3 Cl- 0.1943822E+00 0.6567706E+00 0.1897922E+05 4.2131 4 SO4-- 0.1790074E-03 0.2536581E+00 0.1986141E+05 5.1347 5 HCO3- 0.2354801E-04 0.2677763E+01 0.1331791E+06 0.3289 6 HS- 0.1460085E-03 0.1169099E+01 0.3151545E+05 1.0924 7 H4SiO4 0.8807153E-01 0.8807509E-01 0.6900137E+04 -1.0552 8 Al+++ 0.5648504E-17 0.1831679E-04 0.4028350E+00 -5.7030 9 Ca++ 0.2391151E-05 0.3657775E-03 0.1194909E+02 3.1687 10 Mg++ 0.1248559E-05 0.2017780E-04 0.3998584E+00 2.8016 11 Fe++ 0.1852435E-07 0.7832354E-02 0.3565364E+03 0.9946 12 K+ 0.5225800E-01 0.1264320E+00 0.4029653E+04 3.6862 13 Na+ 0.1774218E+00 0.5587528E+00 0.1047048E+05 4.1791 14 Mn++ 0.5219908E-06 0.1158861E-02 0.5189384E+02 2.4602 15 Zn++ 0.5005379E-09 0.2191085E-02 0.1167480E+03 -0.5737 16 Cu+ 0.4201913E-07 0.1691487E-03 0.8760474E+01 -2.4476 17 Pb++ 0.3998176E-08 0.3429454E-03 0.5791691E+02 0.4407 18 Ag+ 0.3721305E-09 0.8771761E-05 0.7712571E+00 -4.4680 19 Ba++ 0.1835076E-06 0.3288319E-04 0.3681143E+01 2.1332 20 HPO4-- 0.9025210E-09 0.3144945E-05 0.2460373E+00 -0.1605 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4266873E+01 -.4510895E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5207524E+02 -.1104571E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2516072E+00 0.1155320E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159647E+01 0.4968446E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.8736300E-01 0.5623132E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1816870E-04 0.6763708E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3628202E-03 0.1650897E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2001467E-04 0.6619851E-06 0.0000000E+00 11 Fe++ 0.8766754E-02 0.7769030E-02 0.9977239E-03 0.0000000E+00 12 K+ 0.1254101E+00 0.1254098E+00 0.3286238E-06 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542353E+00 0.3640227E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149492E-02 0.8442321E-08 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2173370E-02 0.1259643E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1677812E-03 0.2318286E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.3261733E-04 0.2275512E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3119518E-05 0.5447983E-05 0.0000000E+00 Chg. balance for solid moles: 0.1355E-18 Mass of aqueous solution: 0.121692E+04 g Temperature = 585.00 C Pressure = 1589.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) annite 0.1051E-06 -6.978 0.5382E-04 -4.269 0.1515E-02 0.1623E-04 phlogopite 0.2207E-06 -6.656 0.9208E-04 -4.036 0.2592E-02 0.3302E-04 biotite-Mn 0.2814E-08 -8.551 0.1433E-05 -5.844 0.4033E-04 0.4295E-06 apatite-OH 0.1816E-05 -5.741 0.9122E-03 -3.040 0.2567E-01 0.2899E-03 magnetite 0.2552E-03 -3.593 0.5908E-01 -1.229 1.663 0.1136E-01 quartz 0.5483E-01 -1.261 3.294 0.518 92.71 1.244 barite 0.2276E-04 -4.643 0.5311E-02 -2.275 0.1495 0.1186E-02 chalcopyrite 0.2318E-03 -3.635 0.4254E-01 -1.371 1.197 0.9930E-02 sphalerite 0.1260E-03 -3.900 0.1227E-01 -1.911 0.3454 0.3001E-02 an30ab70 0.5200E-03 -3.284 0.1389 -0.857 3.908 0.5214E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity annite 0.3200E+00 0.3200E+00 1.0000 -0.495 phlogopite 0.6715E+00 0.6715E+00 1.0000 -0.173 biotite-Mn 0.8563E-02 0.8563E-02 1.0000 -2.067 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.553080 g Volume = 1.321904 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 24 annite -0.71 -0.71 0.00 0.000 -0.43596E-10 25 phlogopite 3.74 3.74 0.00 0.000 -0.17438E-10 26 biotite-Mn 8.40 8.40 0.00 0.000 -0.13951E-10 30 apatite-OH -51.29 -51.29 0.00 0.000 -0.27901E-10 106 magnetite 1.21 1.21 0.00 0.000 -0.11335E-10 144 quartz -1.05 -1.05 0.00 0.000 0.00000E+00 237 barite -14.95 -14.95 0.00 0.000 0.00000E+00 240 chalcopyrite -22.37 -22.37 0.00 0.000 -0.13951E-10 255 sphalerite -10.59 -10.59 0.00 0.000 0.69753E-11 260 an30ab70 -6.38 -6.38 0.00 0.000 0.13951E-10 22 anhydrite -13.91 -13.91 0.00 0.000 -0.32425E+01 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.287 0.11266E+04 2.914 2 CO2,gas -9.29 -10.78 -1.48 -0.495 0.58268E+04 1.717 3 CH4,gas 6.92 -3.72 -10.64 -2.659 0.41761E+05 -7.434 4 H2,gas 5.81 1.76 -4.04 -2.311 0.15880E+05 -0.843 5 H2S,gas -7.74 -10.02 -2.28 -1.138 0.89407E+04 0.924 6 CO,gas -3.31 -9.01 -5.70 -1.755 0.22401E+05 -2.504 7 SO3,gas -6.75 -17.08 -10.33 -2.583 0.40578E+05 -7.133 8 O2,gas 16.53 -3.53 -20.07 -13.378 0.78800E+05 -16.866 9 HCl,gas -5.74 -6.90 -1.16 -0.579 0.45486E+04 -1.158 10 acmite 3.76 2.18 -1.58 -0.164 0.61864E+04 12 akimotoite 5.84 1.75 -4.09 -0.818 0.16054E+05 13 akimotoite-Fe 3.80 -0.06 -3.86 -0.772 0.15154E+05 14 albite-high -4.54 -4.68 -0.15 -0.011 0.57501E+03 15 albite -4.51 -4.68 -0.17 -0.013 0.68065E+03 16 almandine -10.23 -11.59 -1.36 -0.068 0.53309E+04 17 pyrope -3.79 -6.17 -2.37 -0.119 0.93156E+04 18 analcite -2.67 -3.63 -0.97 -0.107 0.37983E+04 19 andalusite -12.15 -12.46 -0.31 -0.031 0.12165E+04 20 andradite 11.06 6.57 -4.50 -0.234 0.17656E+05 21 grossular -0.41 -5.07 -4.66 -0.233 0.18287E+05 27 anorthite -9.87 -10.35 -0.48 -0.037 0.18835E+04 28 anthophyllite 13.29 11.19 -2.10 -0.057 0.82468E+04 29 anthophyllite-Fe 1.08 -1.46 -2.54 -0.069 0.99910E+04 31 apatite-OH-zs -49.18 -51.29 -2.11 -0.162 0.82903E+04 32 apatite-Cl-zs -55.09 -58.18 -3.09 -0.258 0.12136E+05 33 aragonite -4.23 -7.61 -3.38 -1.128 0.13288E+05 34 brucite 5.00 2.80 -2.21 -0.441 0.86618E+04 35 calcite -4.32 -7.61 -3.29 -1.096 0.12915E+05 36 carnegieite-low -0.80 -2.58 -1.78 -0.254 0.69785E+04 37 carnegieite-high -0.73 -2.58 -1.84 -0.263 0.72425E+04 38 carpholite-Mg -8.92 -10.72 -1.80 -0.120 0.70745E+04 39 carpholite-Fe -10.23 -12.53 -2.30 -0.153 0.90262E+04 40 celadonite -1.32 -3.43 -2.11 -0.124 0.82796E+04 41 celadonite-Fe -2.68 -5.24 -2.55 -0.150 0.10015E+05 42 chrysotile 8.67 6.29 -2.37 -0.198 0.93160E+04 44 clinochlore 0.67 -0.57 -1.25 -0.039 0.48921E+04 45 daphnite -6.16 -9.61 -3.45 -0.108 0.13549E+05 47 chlorite-Al-free 17.53 12.59 -4.95 -0.206 0.19428E+05 48 chloritoid-Mg -8.54 -9.67 -1.13 -0.075 0.44200E+04 49 chloritoid-Fe -10.41 -11.47 -1.06 -0.071 0.41806E+04 50 chloritoid-Mn -8.24 -10.01 -1.76 -0.118 0.69216E+04 52 coesite -0.77 -1.05 -0.28 -0.093 0.10933E+04 53 cordierite-H -22.03 -22.48 -0.46 -0.016 0.17927E+04 54 cordierite-Fe -24.44 -26.10 -1.65 -0.057 0.64903E+04 55 cordierite-Mn -20.04 -23.16 -3.13 -0.108 0.12283E+05 56 corundum -10.94 -11.41 -0.48 -0.043 0.18680E+04 58 cristobalite -1.00 -1.05 -0.05 -0.017 0.20175E+03 59 cummingtonite 13.34 11.19 -2.16 -0.058 0.84760E+04 61 cymrite-K -2.90 -5.18 -2.28 -0.190 0.89496E+04 63 diaspore -4.96 -5.71 -0.74 -0.124 0.29142E+04 65 diopside 5.14 3.86 -1.27 -0.127 0.50008E+04 66 hedenbergite 3.76 2.06 -1.71 -0.171 0.67002E+04 68 eastonite -8.77 -9.94 -1.17 -0.045 0.45865E+04 69 enstatite 4.32 3.50 -0.82 -0.082 0.32179E+04 70 clinoenstatite-HiP 4.80 3.50 -1.30 -0.130 0.51095E+04 71 clinoenstatite 4.30 3.50 -0.81 -0.081 0.31663E+04 72 protoenstatite 4.45 3.50 -0.95 -0.095 0.37289E+04 73 epidote -6.22 -8.12 -1.90 -0.092 0.74659E+04 74 clinozoisite -11.69 -13.94 -2.25 -0.102 0.88408E+04 75 epidote-Fe 0.91 -2.31 -3.22 -0.167 0.12625E+05 76 fayalite 1.82 0.93 -0.89 -0.127 0.34849E+04 77 ferrosilite 0.86 -0.12 -0.98 -0.098 0.38340E+04 78 forsterite 5.69 4.55 -1.14 -0.163 0.44844E+04 79 gedrite -13.49 -15.13 -1.65 -0.045 0.64778E+04 81 gibbsite -3.37 -5.71 -2.34 -0.334 0.91728E+04 82 glaucophane 0.01 -3.07 -3.08 -0.083 0.12081E+05 83 glaucophane-Fe -3.89 -8.49 -4.60 -0.124 0.18047E+05 84 goethite 0.91 0.11 -0.80 -0.173 0.31446E+04 86 greenalite 3.97 0.87 -3.10 -0.258 0.12178E+05 87 grunerite 1.61 -1.46 -3.08 -0.083 0.12080E+05 88 halite -0.64 -2.72 -2.08 -1.039 0.81617E+04 89 hematite 0.31 0.22 -0.09 -0.011 0.34699E+03 90 heulandite -12.89 -15.62 -2.73 -0.124 0.10706E+05 91 hercynite -9.52 -10.42 -0.90 -0.060 0.35146E+04 94 jadeite -1.99 -3.63 -1.64 -0.164 0.64591E+04 96 kalsilite -1.43 -3.07 -1.64 -0.235 0.64507E+04 97 kaolinite -10.95 -13.52 -2.57 -0.233 0.10081E+05 98 kyanite -12.00 -12.46 -0.46 -0.046 0.18085E+04 100 laumontite -9.16 -12.46 -3.29 -0.220 0.12937E+05 101 lawsonite -7.16 -10.35 -3.20 -0.213 0.12550E+05 102 leucite -3.13 -4.12 -0.99 -0.099 0.39000E+04 104 lizardite 8.85 6.29 -2.56 -0.213 0.10055E+05 105 magnesite -5.24 -7.98 -2.74 -0.912 0.10741E+05 107 minnesotaite 0.63 -1.23 -1.86 -0.109 0.72939E+04 108 minnesotaite-Mg 6.41 4.19 -2.22 -0.130 0.87004E+04 109 magnesioferrite 4.19 3.02 -1.18 -0.096 0.46193E+04 111 manganosite 5.05 2.46 -2.59 -0.648 0.10185E+05 112 margarite -20.34 -21.76 -1.42 -0.057 0.55956E+04 115 microcline -5.10 -5.17 -0.07 -0.006 0.28878E+03 116 monticellite 8.32 4.92 -3.40 -0.486 0.13353E+05 118 mullite-Si -11.43 -12.46 -1.03 -0.103 0.40445E+04 119 muscovite -15.91 -16.59 -0.68 -0.040 0.26575E+04 120 paragonite -15.23 -16.10 -0.86 -0.051 0.33819E+04 121 nepheline -1.09 -2.58 -1.49 -0.212 0.58395E+04 122 osumilite(2) -14.79 -16.60 -1.80 -0.038 0.70824E+04 123 osumilite-Fe -31.31 -33.37 -2.07 -0.043 0.81128E+04 124 pargasite 1.85 -1.72 -3.57 -0.094 0.14007E+05 125 periclase 5.19 2.80 -2.39 -0.597 0.93768E+04 126 periclase-Fe 2.68 0.99 -1.69 -0.422 0.66271E+04 127 perovskite-Al -9.24 -11.41 -2.17 -0.197 0.85223E+04 132 phlogopite-Na 4.60 3.72 -0.89 -0.049 0.34830E+04 134 prehnite -5.24 -8.23 -2.99 -0.176 0.11752E+05 135 prehnite-Fe 0.62 -2.42 -3.04 -0.183 0.11918E+05 138 px-Mg-tschermaks -7.98 -9.66 -1.68 -0.120 0.65999E+04 139 px-Ca-tschermaks -6.98 -9.30 -2.32 -0.166 0.91069E+04 140 pyrite -20.78 -20.80 -0.02 -0.005 0.89086E+02 141 pyrrhotite -8.41 -9.02 -0.61 -0.204 0.24025E+04 142 pyrrhotiteFe0.875 -9.12 -9.36 -0.24 -0.089 0.95234E+03 143 pyrophyllite -14.44 -15.62 -1.18 -0.074 0.46220E+04 146 riebeckite 5.94 3.14 -2.80 -0.077 0.10993E+05 147 ringwoodite-Fe 2.80 0.93 -1.87 -0.267 0.73380E+04 148 ringwoodite-Mg 8.78 4.55 -4.23 -0.605 0.16619E+05 149 rhodochrosite -5.11 -8.32 -3.21 -1.069 0.12597E+05 150 rhodonite 2.41 1.41 -1.00 -0.200 0.39244E+04 151 sanidine -4.57 -5.17 -0.60 -0.046 0.23582E+04 152 sapphirine(351) -45.07 -49.71 -4.64 -0.070 0.18217E+05 153 siderite -7.01 -9.78 -2.77 -0.924 0.10887E+05 154 sillimanite -12.12 -12.46 -0.34 -0.034 0.13315E+04 156 spinel -7.42 -8.61 -1.20 -0.080 0.47000E+04 158 staurolite-Fe -101.79 -106.62 -4.83 -0.044 0.18981E+05 162 stilpnomelane-Fe -8.58 -13.03 -4.45 -0.133 0.17456E+05 163 stilpnomelane-Mg -2.09 -3.99 -1.90 -0.057 0.74580E+04 164 stishovite 1.84 -1.05 -2.89 -0.963 0.11342E+05 165 sudoite-Fe -20.34 -24.00 -3.66 -0.118 0.14356E+05 166 sudoite -18.21 -20.39 -2.18 -0.070 0.85520E+04 167 sulfur -10.30 -11.78 -1.48 -0.457 0.58290E+04 168 sylvite -0.54 -3.21 -2.66 -1.332 0.10462E+05 169 talc 4.71 4.19 -0.51 -0.030 0.20181E+04 170 talc-Fe 1.99 -1.23 -3.22 -0.189 0.12636E+05 171 talc-tschermaks -7.52 -8.97 -1.45 -0.085 0.56927E+04 173 tephroite 6.14 3.87 -2.27 -0.325 0.89285E+04 176 topaz-H -10.09 -12.46 -2.38 -0.216 0.93299E+04 177 tremolite 14.35 11.92 -2.43 -0.066 0.95501E+04 179 troilite-low -8.31 -9.02 -0.71 -0.236 0.27832E+04 180 tschermakite -11.65 -14.40 -2.75 -0.074 0.10815E+05 183 wadsleyite-Fe 2.65 0.93 -1.72 -0.245 0.67393E+04 184 wadsleyite-Mg 7.85 4.55 -3.30 -0.472 0.12977E+05 185 wairakite -10.95 -12.45 -1.50 -0.088 0.58965E+04 186 walstromite 4.53 2.12 -2.42 -0.483 0.94876E+04 187 wollastonite 4.13 2.12 -2.01 -0.402 0.78972E+04 188 pseudo-wollastonite 4.24 2.12 -2.12 -0.424 0.83292E+04 189 zoisite -11.75 -13.94 -2.19 -0.100 0.86056E+04 192 beidellite-Ca -15.16 -16.63 -1.47 -0.091 0.57845E+04 193 beidellite-H -15.16 -17.16 -2.00 -0.128 0.78492E+04 194 beidellite-K -14.10 -15.94 -1.84 -0.113 0.72296E+04 195 beidellite-Mg -15.46 -16.69 -1.23 -0.076 0.48417E+04 196 beidellite-Na -14.04 -15.78 -1.74 -0.106 0.68289E+04 197 bornite -51.78 -52.19 -0.41 -0.030 0.15909E+04 199 chalcocite -13.41 -14.91 -1.50 -0.374 0.58791E+04 200 covellite -11.94 -13.35 -1.41 -0.536 0.55244E+04 202 montmorillonite-Ca -11.18 -12.29 -1.11 -0.069 0.43757E+04 203 montmorillonite-K -10.41 -11.60 -1.19 -0.073 0.46758E+04 204 montmorillonite-Mg -11.42 -12.35 -0.93 -0.058 0.36646E+04 205 montmorillonite-Na -10.05 -11.43 -1.39 -0.085 0.54479E+04 206 nontronite-Ca -3.68 -5.00 -1.32 -0.086 0.51928E+04 207 nontronite-H -3.68 -5.52 -1.84 -0.123 0.72253E+04 208 nontronite-K -2.62 -4.31 -1.69 -0.108 0.66287E+04 209 nontronite-Mg -3.93 -5.06 -1.13 -0.073 0.44429E+04 210 nontronite-Na -2.56 -4.15 -1.59 -0.102 0.62419E+04 215 gypsum -11.75 -13.92 -2.16 -0.540 0.84887E+04 232 alabandite -6.13 -7.56 -1.43 -0.475 0.55992E+04 234 anglesite -14.07 -16.64 -2.58 -1.288 0.10112E+05 238 boehmite -4.69 -5.71 -1.02 -0.170 0.40074E+04 242 copper,native 1.77 -1.57 -3.34 -1.161 0.13113E+05 244 ferrous-oxide 1.77 0.99 -0.78 -0.194 0.30481E+04 245 galena -9.26 -9.58 -0.31 -0.104 0.12264E+04 246 silver,native 0.55 -3.59 -4.13 -1.438 0.16230E+05 248 litharge 5.18 0.44 -4.74 -1.185 0.18615E+05 256 wurtzite -9.80 -10.59 -0.79 -0.262 0.30880E+04 257 zincite 1.90 -0.58 -2.47 -0.619 0.97179E+04 258 an20ab80 -5.80 -5.81 -0.02 -0.001 0.68407E+02 259 an25ab75 -6.09 -6.10 -0.01 0.000 0.22700E+02 261 tr.625ac.25prg.125 8.67 7.96 -0.71 -0.019 0.28007E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 17 Loop limit = 500 Temperature = 585.00 C Pressure = 1589.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5506E+02 kg liquid = 0.9919E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9957 Stoichiometric ionic strength = .3304916E+01 Osmotic coef. = 0.0000 True ionic strength = .2319668E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10727E-04 -4.9695 0.27921E-05 -5.5541 0.26029E+00 -0.5845 2 H2O 0.99566E+00 -0.0019 0.99566E+00 -0.0019 3 Cl- 0.19438E+00 -0.7113 0.45602E-01 -1.3410 0.23460E+00 -0.6297 4 SO4-- 0.17900E-03 -3.7471 0.10631E-05 -5.9734 0.59388E-02 -2.2263 5 HCO3- 0.23548E-04 -4.6281 0.59545E-05 -5.2252 0.25287E+00 -0.5971 6 HS- 0.14601E-03 -3.8356 0.34542E-04 -4.4617 0.23658E+00 -0.6260 7 H4SiO4 0.88072E-01 -1.0552 0.88072E-01 -1.0552 0.10000E+01 0.0000 8 Al+++ 0.56512E-17 -17.2479 0.43148E-22 -22.3650 0.76351E-05 -5.1172 9 Ca++ 0.23867E-05 -5.6222 0.11474E-07 -7.9403 0.48074E-02 -2.3181 10 Mg++ 0.12483E-05 -5.9037 0.49361E-08 -8.3066 0.39542E-02 -2.4029 11 Fe++ 0.18525E-07 -7.7322 0.76989E-10 -10.1136 0.41560E-02 -2.3813 12 K+ 0.52258E-01 -1.2818 0.13557E-01 -1.8678 0.25942E+00 -0.5860 13 Na+ 0.17742E+00 -0.7510 0.42176E-01 -1.3749 0.23771E+00 -0.6239 14 Mn++ 0.52199E-06 -6.2823 0.22495E-08 -8.6479 0.43094E-02 -2.3656 15 Zn++ 0.50055E-09 -9.3006 0.20803E-11 -11.6819 0.41560E-02 -2.3813 16 Cu+ 0.42020E-07 -7.3765 0.99618E-08 -8.0017 0.23708E+00 -0.6251 17 Pb++ 0.39982E-08 -8.3981 0.21507E-10 -10.6674 0.53791E-02 -2.2693 18 Ag+ 0.37213E-09 -9.4293 0.95034E-10 -10.0221 0.25538E+00 -0.5928 19 Ba++ 0.18351E-06 -6.7363 0.10594E-08 -8.9749 0.57729E-02 -2.2386 20 HPO4-- 0.90536E-09 -9.0432 0.54034E-11 -11.2673 0.59682E-02 -2.2242 21 HSiO3- 0.20609E-05 -5.6859 0.48350E-06 -6.3156 0.23460E+00 -0.6297 22 Ca(HSiO3)+ 0.12588E-07 -7.9000 0.32943E-08 -8.4822 0.26170E+00 -0.5822 23 Mg(HSiO3)+ 0.14277E-08 -8.8454 0.37362E-09 -9.4276 0.26170E+00 -0.5822 24 NaHSiO3,aq 0.14777E-05 -5.8304 0.14777E-05 -5.8304 0.10000E+01 0.0000 28 AgCl,aq 0.73518E-07 -7.1336 0.73518E-07 -7.1336 0.10000E+01 0.0000 29 AgCl2- 0.49603E-05 -5.3045 0.11637E-05 -5.9342 0.23460E+00 -0.6297 30 AgCl3-2 0.23656E-05 -5.6261 0.13018E-07 -7.8855 0.55029E-02 -2.2594 31 AgCl4-3 0.13670E-05 -5.8642 0.89633E-11 -11.0475 0.65568E-05 -5.1833 34 Ag(HS),aq 0.71168E-09 -9.1477 0.71168E-09 -9.1477 0.10000E+01 0.0000 35 Ag(HS)2- 0.42410E-08 -8.3725 0.99494E-09 -9.0022 0.23460E+00 -0.6297 36 AlO+ 0.10085E-10 -10.9963 0.26393E-11 -11.5785 0.26170E+00 -0.5822 38 HAlO2,aq 0.43599E-08 -8.3605 0.43599E-08 -8.3605 0.10000E+01 0.0000 39 AlO2- 0.18320E-04 -4.7371 0.37536E-05 -5.4256 0.20489E+00 -0.6885 41 Ba(HCO3)+ 0.91788E-06 -6.0372 0.24985E-06 -6.6023 0.27221E+00 -0.5651 42 BaCl+ 0.31783E-04 -4.4978 0.83175E-05 -5.0800 0.26170E+00 -0.5822 43 CH4,aq 0.19212E-08 -8.7164 0.23256E-08 -8.6335 0.12105E+01 0.0830 48 CO,aq 0.76550E-03 -3.1161 0.76550E-03 -3.1161 0.10000E+01 0.0000 49 CO2,aq 0.26770E+01 0.4276 0.32405E+01 0.5106 0.12105E+01 0.0830 50 CO3-2 0.49092E-10 -10.3090 0.27015E-12 -12.5684 0.55029E-02 -2.2594 51 CaCO3,aq 0.17704E-10 -10.7519 0.17704E-10 -10.7519 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.55079E-06 -6.2590 0.14414E-06 -6.8412 0.26170E+00 -0.5822 53 CaCl+ 0.22182E-03 -3.6540 0.58051E-04 -4.2362 0.26170E+00 -0.5822 54 CaCl2,aq 0.13982E-03 -3.8544 0.13982E-03 -3.8544 0.10000E+01 0.0000 55 CaOH+ 0.36121E-06 -6.4422 0.94527E-07 -7.0244 0.26170E+00 -0.5822 56 CaSO4,aq 0.14042E-06 -6.8526 0.14042E-06 -6.8526 0.10000E+01 0.0000 57 HCl,aq 0.12724E-02 -2.8954 0.12724E-02 -2.8954 0.10000E+01 0.0000 66 CuCl,aq 0.33192E-04 -4.4790 0.33192E-04 -4.4790 0.10000E+01 0.0000 67 CuCl2- 0.13257E-03 -3.8776 0.31101E-04 -4.5072 0.23460E+00 -0.6297 68 CuCl3-2 0.33467E-05 -5.4754 0.18416E-07 -7.7348 0.55029E-02 -2.2594 74 FeCl+ 0.53586E-06 -6.2709 0.14023E-06 -6.8531 0.26170E+00 -0.5822 75 FeCl2,aq 0.78319E-02 -2.1061 0.78319E-02 -2.1061 0.10000E+01 0.0000 77 FeO,aq 0.82641E-07 -7.0828 0.82641E-07 -7.0828 0.10000E+01 0.0000 78 FeOH+ 0.40935E-07 -7.3879 0.10713E-07 -7.9701 0.26170E+00 -0.5822 79 HFeO2- 0.11130E-07 -7.9535 0.26112E-08 -8.5832 0.23460E+00 -0.6297 82 FeO2- 0.72263E-08 -8.1411 0.16953E-08 -8.7708 0.23460E+00 -0.6297 83 HFeO2,aq 0.25664E-09 -9.5907 0.25664E-09 -9.5907 0.10000E+01 0.0000 84 H2,aq 0.45351E-02 -2.3434 0.54897E-02 -2.2604 0.12105E+01 0.0830 85 KCl,aq 0.57503E-01 -1.2403 0.57503E-01 -1.2403 0.10000E+01 0.0000 86 KHSO4,aq 0.12814E-01 -1.8923 0.12814E-01 -1.8923 0.10000E+01 0.0000 87 KOH,aq 0.99319E-06 -6.0030 0.99319E-06 -6.0030 0.10000E+01 0.0000 88 KSO4- 0.38559E-02 -2.4139 0.90461E-03 -3.0435 0.23460E+00 -0.6297 90 Mg(HCO3)+ 0.98246E-07 -7.0077 0.25711E-07 -7.5899 0.26170E+00 -0.5822 91 MgCl+ 0.18191E-04 -4.7401 0.47605E-05 -5.3223 0.26170E+00 -0.5822 92 MgOH+ 0.63513E-06 -6.1971 0.16621E-06 -6.7793 0.26170E+00 -0.5822 94 MnO,aq 0.36606E-07 -7.4364 0.36606E-07 -7.4364 0.10000E+01 0.0000 95 MnOH+ 0.14856E-06 -6.8281 0.38877E-07 -7.4103 0.26170E+00 -0.5822 97 HMnO2- 0.22926E-10 -10.6397 0.53784E-11 -11.2694 0.23460E+00 -0.6297 100 MnCl+ 0.11581E-02 -2.9362 0.30308E-03 -3.5184 0.26170E+00 -0.5822 101 MnSO4,aq 0.34764E-07 -7.4589 0.34764E-07 -7.4589 0.10000E+01 0.0000 102 NaCl,aq 0.38133E+00 -0.4187 0.38133E+00 -0.4187 0.10000E+01 0.0000 103 NaOH,aq 0.14327E-05 -5.8438 0.14327E-05 -5.8438 0.10000E+01 0.0000 105 OH- 0.90882E-05 -5.0415 0.18620E-05 -5.7300 0.20489E+00 -0.6885 110 HPO3-2 0.14059E-10 -10.8520 0.77365E-13 -13.1115 0.55029E-02 -2.2594 111 H3PO3,aq 0.10993E-09 -9.9589 0.10993E-09 -9.9589 0.10000E+01 0.0000 112 H2PO3- 0.43460E-08 -8.3619 0.10196E-08 -8.9916 0.23460E+00 -0.6297 113 H3PO4,aq 0.82624E-06 -6.0829 0.82624E-06 -6.0829 0.10000E+01 0.0000 114 H2PO4- 0.16986E-05 -5.7699 0.41917E-06 -6.3776 0.24677E+00 -0.6077 116 H4P2O7,aq 0.56680E-10 -10.2466 0.56680E-10 -10.2466 0.10000E+01 0.0000 117 H3P2O7- 0.10643E-08 -8.9729 0.24968E-09 -9.6026 0.23460E+00 -0.6297 118 H2P2O7-2 0.30057E-06 -6.5221 0.16540E-08 -8.7815 0.55029E-02 -2.2594 119 HP2O7-3 0.11626E-07 -7.9346 0.76231E-13 -13.1179 0.65568E-05 -5.1833 121 PbCl+ 0.23547E-05 -5.6281 0.61622E-06 -6.2103 0.26170E+00 -0.5822 122 PbCl2,aq 0.88679E-04 -4.0522 0.88679E-04 -4.0522 0.10000E+01 0.0000 123 PbCl3- 0.11177E-03 -3.9517 0.26221E-04 -4.5813 0.23460E+00 -0.6297 124 PbCl4-2 0.27782E-04 -4.5562 0.15288E-06 -6.8156 0.55029E-02 -2.2594 125 PbO,aq 0.39877E-08 -8.3993 0.39877E-08 -8.3993 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10245E-03 -3.9895 0.10245E-03 -3.9895 0.10000E+01 0.0000 128 Pb(HS)3- 0.99065E-05 -5.0041 0.23241E-05 -5.6337 0.23460E+00 -0.6297 129 H2S,aq 0.10479E+01 0.0203 0.12684E+01 0.1033 0.12105E+01 0.0830 130 S2-2 0.15250E-07 -7.8167 0.83920E-10 -10.0761 0.55029E-02 -2.2594 131 S3-2 0.16051E-08 -8.7945 0.88329E-11 -11.0539 0.55029E-02 -2.2594 132 S3- 0.20329E-01 -1.6919 0.47693E-02 -2.3215 0.23460E+00 -0.6297 133 S4-2 0.14065E-09 -9.8519 0.77397E-12 -12.1113 0.55029E-02 -2.2594 134 S5-2 0.10435E-10 -10.9815 0.57425E-13 -13.2409 0.55029E-02 -2.2594 135 SO2,aq 0.28458E+00 -0.5458 0.28458E+00 -0.5458 0.10000E+01 0.0000 136 SO3-2 0.59565E-09 -9.2250 0.51384E-11 -11.2892 0.86266E-02 -2.0642 137 HSO3- 0.41638E-03 -3.3805 0.97683E-04 -4.0102 0.23460E+00 -0.6297 138 HSO4- 0.11682E-01 -1.9325 0.31364E-02 -2.5036 0.26848E+00 -0.5711 140 S2O3-2 0.53235E-06 -6.2738 0.29295E-08 -8.5332 0.55029E-02 -2.2594 141 HS2O3- 0.67359E-06 -6.1716 0.15803E-06 -6.8013 0.23460E+00 -0.6297 142 H2S2O3,aq 0.24913E-07 -7.6036 0.24913E-07 -7.6036 0.10000E+01 0.0000 150 S4O6-2 0.67850E-09 -9.1685 0.37337E-11 -11.4279 0.55029E-02 -2.2594 152 ZnCl+ 0.60848E-03 -3.2158 0.15924E-03 -3.7980 0.26170E+00 -0.5822 153 ZnCl2,aq 0.13930E-02 -2.8560 0.13930E-02 -2.8560 0.10000E+01 0.0000 154 ZnCl3- 0.18649E-03 -3.7294 0.43750E-04 -4.3590 0.23460E+00 -0.6297 155 ZnO,aq 0.40730E-07 -7.3901 0.40730E-07 -7.3901 0.10000E+01 0.0000 156 ZnOH+ 0.31256E-05 -5.5051 0.81796E-06 -6.0873 0.26170E+00 -0.5822 158 HZnO2- 0.34988E-09 -9.4561 0.82081E-10 -10.0858 0.23460E+00 -0.6297 Charge balance for all species = 0.2551E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1072696E-04 0.4301651E+01 0.3534122E+04 0.0000 2 H2O 0.1000000E+01 0.5249970E+02 0.7709212E+06 0.0000 3 Cl- 0.1943821E+00 0.6567706E+00 0.1897922E+05 4.2131 4 SO4-- 0.1790019E-03 0.2536574E+00 0.1986136E+05 5.1347 5 HCO3- 0.2354767E-04 0.2677763E+01 0.1331791E+06 0.3289 6 HS- 0.1460065E-03 0.1169099E+01 0.3151546E+05 1.0924 7 H4SiO4 0.8807154E-01 0.8807509E-01 0.6900138E+04 -1.0552 8 Al+++ 0.5651183E-17 0.1832469E-04 0.4030088E+00 -5.7028 9 Ca++ 0.2386662E-05 0.3650927E-03 0.1192671E+02 3.1678 10 Mg++ 0.1248316E-05 0.2017396E-04 0.3997823E+00 2.8015 11 Fe++ 0.1852474E-07 0.7832573E-02 0.3565464E+03 0.9946 12 K+ 0.5225807E-01 0.1264320E+00 0.4029653E+04 3.6862 13 Na+ 0.1774215E+00 0.5587528E+00 0.1047048E+05 4.1791 14 Mn++ 0.5219883E-06 0.1158861E-02 0.5189384E+02 2.4602 15 Zn++ 0.5005482E-09 0.2191144E-02 0.1167511E+03 -0.5737 16 Cu+ 0.4201958E-07 0.1691508E-03 0.8760584E+01 -2.4476 17 Pb++ 0.3998188E-08 0.3429454E-03 0.5791691E+02 0.4407 18 Ag+ 0.3721306E-09 0.8771762E-05 0.7712571E+00 -4.4681 19 Ba++ 0.1835117E-06 0.3288406E-04 0.3681240E+01 2.1332 20 HPO4-- 0.9053568E-09 0.3156861E-05 0.2469695E+00 -0.1592 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4266873E+01 -.4510384E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5207524E+02 -.1104573E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2516066E+00 0.1162141E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159647E+01 0.4968007E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.8736300E-01 0.5623132E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1817654E-04 0.6763630E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3621409E-03 0.1657690E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2001085E-04 0.6657977E-06 0.0000000E+00 11 Fe++ 0.8766754E-02 0.7769247E-02 0.9975068E-03 0.0000000E+00 12 K+ 0.1254101E+00 0.1254098E+00 0.3305398E-06 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542353E+00 0.3640175E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149492E-02 0.8492553E-08 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2173428E-02 0.1259064E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1677833E-03 0.2318265E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.3261819E-04 0.2275426E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3131338E-05 0.5436163E-05 0.0000000E+00 Chg. balance for solid moles: -.4303E-18 Mass of aqueous solution: 0.121692E+04 g Temperature = 585.00 C Pressure = 1589.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) annite 0.1058E-06 -6.976 0.5415E-04 -4.266 0.1524E-02 0.1632E-04 phlogopite 0.2219E-06 -6.654 0.9261E-04 -4.033 0.2606E-02 0.3321E-04 biotite-Mn 0.2831E-08 -8.548 0.1441E-05 -5.841 0.4057E-04 0.4321E-06 apatite-OH 0.1812E-05 -5.742 0.9102E-03 -3.041 0.2562E-01 0.2892E-03 magnetite 0.2551E-03 -3.593 0.5906E-01 -1.229 1.662 0.1136E-01 quartz 0.5483E-01 -1.261 3.294 0.518 92.71 1.244 barite 0.2275E-04 -4.643 0.5311E-02 -2.275 0.1495 0.1185E-02 chalcopyrite 0.2318E-03 -3.635 0.4254E-01 -1.371 1.197 0.9930E-02 sphalerite 0.1259E-03 -3.900 0.1227E-01 -1.911 0.3452 0.3000E-02 an30ab70 0.5200E-03 -3.284 0.1389 -0.857 3.908 0.5214E-01 anhydrite 0.7012E-06 -6.154 0.9547E-04 -4.020 0.2687E-02 0.3222E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity annite 0.3200E+00 0.3200E+00 1.0000 -0.495 phlogopite 0.6714E+00 0.6714E+00 1.0000 -0.173 biotite-Mn 0.8564E-02 0.8564E-02 1.0000 -2.067 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.553150 g Volume = 1.321931 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -13.91 -13.91 0.00 0.000 -0.69753E-11 24 annite -0.71 -0.71 0.00 0.000 0.35748E-10 25 phlogopite 3.74 3.74 0.00 0.000 -0.52315E-11 26 biotite-Mn 8.40 8.40 0.00 0.000 -0.69753E-11 30 apatite-OH -51.29 -51.29 0.00 0.000 0.00000E+00 106 magnetite 1.21 1.21 0.00 0.000 0.16566E-10 144 quartz -1.05 -1.05 0.00 0.000 0.00000E+00 237 barite -14.95 -14.95 0.00 0.000 0.00000E+00 240 chalcopyrite -22.37 -22.37 0.00 0.000 -0.13951E-10 255 sphalerite -10.59 -10.59 0.00 0.000 0.20926E-10 260 an30ab70 -6.38 -6.38 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.29 0.00 -0.29 -0.287 0.11266E+04 2.914 2 CO2,gas -9.29 -10.78 -1.48 -0.495 0.58268E+04 1.717 3 CH4,gas 6.92 -3.72 -10.64 -2.659 0.41761E+05 -7.434 4 H2,gas 5.81 1.76 -4.04 -2.311 0.15880E+05 -0.843 5 H2S,gas -7.74 -10.02 -2.28 -1.138 0.89407E+04 0.924 6 CO,gas -3.31 -9.01 -5.70 -1.755 0.22401E+05 -2.504 7 SO3,gas -6.75 -17.08 -10.33 -2.583 0.40578E+05 -7.133 8 O2,gas 16.53 -3.53 -20.07 -13.378 0.78800E+05 -16.866 9 HCl,gas -5.74 -6.90 -1.16 -0.579 0.45486E+04 -1.158 10 acmite 3.76 2.18 -1.58 -0.164 0.61865E+04 12 akimotoite 5.84 1.75 -4.09 -0.818 0.16054E+05 13 akimotoite-Fe 3.80 -0.06 -3.86 -0.772 0.15154E+05 14 albite-high -4.54 -4.68 -0.15 -0.011 0.57427E+03 15 albite -4.51 -4.68 -0.17 -0.013 0.67991E+03 16 almandine -10.23 -11.59 -1.36 -0.068 0.53294E+04 17 pyrope -3.79 -6.17 -2.37 -0.119 0.93152E+04 18 analcite -2.67 -3.63 -0.97 -0.107 0.37976E+04 19 andalusite -12.15 -12.46 -0.31 -0.031 0.12150E+04 20 andradite 11.06 6.56 -4.50 -0.234 0.17665E+05 21 grossular -0.41 -5.07 -4.66 -0.233 0.18295E+05 27 anorthite -9.87 -10.35 -0.48 -0.037 0.18852E+04 28 anthophyllite 13.29 11.18 -2.10 -0.057 0.82494E+04 29 anthophyllite-Fe 1.08 -1.46 -2.54 -0.069 0.99910E+04 31 apatite-OH-zs -49.18 -51.29 -2.11 -0.162 0.82903E+04 32 apatite-Cl-zs -55.09 -58.18 -3.09 -0.258 0.12136E+05 33 aragonite -4.23 -7.61 -3.38 -1.128 0.13291E+05 34 brucite 5.00 2.80 -2.21 -0.441 0.86622E+04 35 calcite -4.32 -7.61 -3.29 -1.097 0.12918E+05 36 carnegieite-low -0.80 -2.58 -1.78 -0.254 0.69778E+04 37 carnegieite-high -0.73 -2.58 -1.84 -0.263 0.72418E+04 38 carpholite-Mg -8.92 -10.72 -1.80 -0.120 0.70734E+04 39 carpholite-Fe -10.23 -12.53 -2.30 -0.153 0.90246E+04 40 celadonite -1.32 -3.43 -2.11 -0.124 0.82792E+04 41 celadonite-Fe -2.68 -5.24 -2.55 -0.150 0.10015E+05 42 chrysotile 8.67 6.29 -2.37 -0.198 0.93171E+04 44 clinochlore 0.67 -0.57 -1.25 -0.039 0.48924E+04 45 daphnite -6.16 -9.61 -3.45 -0.108 0.13548E+05 47 chlorite-Al-free 17.53 12.58 -4.95 -0.206 0.19430E+05 48 chloritoid-Mg -8.54 -9.66 -1.13 -0.075 0.44188E+04 49 chloritoid-Fe -10.41 -11.47 -1.06 -0.071 0.41791E+04 50 chloritoid-Mn -8.24 -10.01 -1.76 -0.117 0.69201E+04 52 coesite -0.77 -1.05 -0.28 -0.093 0.10933E+04 53 cordierite-H -22.03 -22.48 -0.46 -0.016 0.17904E+04 54 cordierite-Fe -24.44 -26.09 -1.65 -0.057 0.64872E+04 55 cordierite-Mn -20.04 -23.16 -3.13 -0.108 0.12280E+05 56 corundum -10.94 -11.41 -0.48 -0.043 0.18664E+04 58 cristobalite -1.00 -1.05 -0.05 -0.017 0.20175E+03 59 cummingtonite 13.34 11.18 -2.16 -0.058 0.84786E+04 61 cymrite-K -2.90 -5.18 -2.28 -0.190 0.89488E+04 63 diaspore -4.96 -5.71 -0.74 -0.124 0.29135E+04 65 diopside 5.14 3.86 -1.27 -0.127 0.50044E+04 66 hedenbergite 3.76 2.06 -1.71 -0.171 0.67034E+04 68 eastonite -8.77 -9.94 -1.17 -0.045 0.45850E+04 69 enstatite 4.32 3.50 -0.82 -0.082 0.32186E+04 70 clinoenstatite-HiP 4.80 3.50 -1.30 -0.130 0.51102E+04 71 clinoenstatite 4.30 3.50 -0.81 -0.081 0.31671E+04 72 protoenstatite 4.45 3.50 -0.95 -0.095 0.37296E+04 73 epidote -6.22 -8.13 -1.90 -0.092 0.74708E+04 74 clinozoisite -11.69 -13.94 -2.25 -0.102 0.88450E+04 75 epidote-Fe 0.91 -2.31 -3.22 -0.167 0.12631E+05 76 fayalite 1.82 0.93 -0.89 -0.127 0.34849E+04 77 ferrosilite 0.86 -0.12 -0.98 -0.098 0.38340E+04 78 forsterite 5.69 4.55 -1.14 -0.163 0.44851E+04 79 gedrite -13.49 -15.13 -1.65 -0.045 0.64766E+04 81 gibbsite -3.37 -5.71 -2.34 -0.334 0.91721E+04 82 glaucophane 0.01 -3.07 -3.08 -0.083 0.12081E+05 83 glaucophane-Fe -3.89 -8.49 -4.60 -0.124 0.18045E+05 84 goethite 0.91 0.11 -0.80 -0.173 0.31446E+04 86 greenalite 3.97 0.87 -3.10 -0.258 0.12178E+05 87 grunerite 1.61 -1.46 -3.08 -0.083 0.12080E+05 88 halite -0.64 -2.72 -2.08 -1.039 0.81617E+04 89 hematite 0.31 0.22 -0.09 -0.011 0.34699E+03 90 heulandite -12.89 -15.62 -2.73 -0.124 0.10708E+05 91 hercynite -9.52 -10.42 -0.89 -0.060 0.35130E+04 94 jadeite -1.99 -3.63 -1.64 -0.164 0.64583E+04 96 kalsilite -1.43 -3.07 -1.64 -0.235 0.64500E+04 97 kaolinite -10.95 -13.52 -2.57 -0.233 0.10079E+05 98 kyanite -12.00 -12.46 -0.46 -0.046 0.18070E+04 100 laumontite -9.16 -12.46 -3.30 -0.220 0.12939E+05 101 lawsonite -7.16 -10.35 -3.20 -0.213 0.12552E+05 102 leucite -3.13 -4.12 -0.99 -0.099 0.38993E+04 104 lizardite 8.85 6.29 -2.56 -0.213 0.10056E+05 105 magnesite -5.24 -7.98 -2.74 -0.912 0.10742E+05 107 minnesotaite 0.63 -1.23 -1.86 -0.109 0.72939E+04 108 minnesotaite-Mg 6.41 4.19 -2.22 -0.130 0.87015E+04 109 magnesioferrite 4.19 3.02 -1.18 -0.096 0.46197E+04 111 manganosite 5.05 2.46 -2.59 -0.648 0.10185E+05 112 margarite -20.34 -21.76 -1.43 -0.057 0.55958E+04 115 microcline -5.10 -5.17 -0.07 -0.006 0.28804E+03 116 monticellite 8.32 4.91 -3.40 -0.486 0.13357E+05 118 mullite-Si -11.43 -12.46 -1.03 -0.103 0.40430E+04 119 muscovite -15.91 -16.59 -0.68 -0.040 0.26553E+04 120 paragonite -15.23 -16.09 -0.86 -0.051 0.33797E+04 121 nepheline -1.09 -2.58 -1.49 -0.212 0.58388E+04 122 osumilite(2) -14.79 -16.60 -1.80 -0.038 0.70813E+04 123 osumilite-Fe -31.31 -33.37 -2.07 -0.043 0.81090E+04 124 pargasite 1.85 -1.72 -3.57 -0.094 0.14012E+05 125 periclase 5.19 2.80 -2.39 -0.597 0.93772E+04 126 periclase-Fe 2.68 0.99 -1.69 -0.422 0.66271E+04 127 perovskite-Al -9.24 -11.41 -2.17 -0.197 0.85208E+04 132 phlogopite-Na 4.60 3.72 -0.89 -0.049 0.34833E+04 134 prehnite -5.24 -8.24 -2.99 -0.176 0.11757E+05 135 prehnite-Fe 0.62 -2.42 -3.04 -0.183 0.11924E+05 138 px-Mg-tschermaks -7.98 -9.66 -1.68 -0.120 0.65988E+04 139 px-Ca-tschermaks -6.98 -9.30 -2.32 -0.166 0.91086E+04 140 pyrite -20.78 -20.80 -0.02 -0.005 0.89084E+02 141 pyrrhotite -8.41 -9.02 -0.61 -0.204 0.24025E+04 142 pyrrhotiteFe0.875 -9.12 -9.36 -0.24 -0.089 0.95234E+03 143 pyrophyllite -14.44 -15.62 -1.18 -0.074 0.46205E+04 146 riebeckite 5.94 3.14 -2.80 -0.077 0.10993E+05 147 ringwoodite-Fe 2.80 0.93 -1.87 -0.267 0.73380E+04 148 ringwoodite-Mg 8.78 4.55 -4.23 -0.605 0.16619E+05 149 rhodochrosite -5.11 -8.32 -3.21 -1.069 0.12597E+05 150 rhodonite 2.41 1.41 -1.00 -0.200 0.39244E+04 151 sanidine -4.57 -5.17 -0.60 -0.046 0.23574E+04 152 sapphirine(351) -45.07 -49.71 -4.64 -0.070 0.18211E+05 153 siderite -7.01 -9.78 -2.77 -0.924 0.10887E+05 154 sillimanite -12.12 -12.46 -0.34 -0.034 0.13300E+04 156 spinel -7.42 -8.61 -1.20 -0.080 0.46989E+04 158 staurolite-Fe -101.79 -106.62 -4.83 -0.044 0.18967E+05 162 stilpnomelane-Fe -8.58 -13.03 -4.45 -0.133 0.17455E+05 163 stilpnomelane-Mg -2.09 -3.99 -1.90 -0.057 0.74584E+04 164 stishovite 1.84 -1.05 -2.89 -0.963 0.11342E+05 165 sudoite-Fe -20.34 -24.00 -3.66 -0.118 0.14353E+05 166 sudoite -18.21 -20.39 -2.18 -0.070 0.85497E+04 167 sulfur -10.30 -11.78 -1.48 -0.457 0.58290E+04 168 sylvite -0.54 -3.21 -2.66 -1.332 0.10462E+05 169 talc 4.71 4.19 -0.51 -0.030 0.20192E+04 170 talc-Fe 1.99 -1.23 -3.22 -0.189 0.12636E+05 171 talc-tschermaks -7.52 -8.97 -1.45 -0.085 0.56920E+04 173 tephroite 6.14 3.87 -2.27 -0.325 0.89286E+04 176 topaz-H -10.09 -12.46 -2.38 -0.216 0.93284E+04 177 tremolite 14.35 11.92 -2.43 -0.066 0.95584E+04 179 troilite-low -8.31 -9.02 -0.71 -0.236 0.27832E+04 180 tschermakite -11.65 -14.40 -2.76 -0.074 0.10820E+05 183 wadsleyite-Fe 2.65 0.93 -1.72 -0.245 0.67393E+04 184 wadsleyite-Mg 7.85 4.55 -3.31 -0.472 0.12978E+05 185 wairakite -10.95 -12.45 -1.50 -0.088 0.58982E+04 186 walstromite 4.53 2.11 -2.42 -0.483 0.94908E+04 187 wollastonite 4.13 2.11 -2.01 -0.402 0.79005E+04 188 pseudo-wollastonite 4.24 2.11 -2.12 -0.424 0.83325E+04 189 zoisite -11.75 -13.94 -2.19 -0.100 0.86098E+04 192 beidellite-Ca -15.16 -16.63 -1.47 -0.091 0.57833E+04 193 beidellite-H -15.16 -17.15 -2.00 -0.128 0.78474E+04 194 beidellite-K -14.10 -15.94 -1.84 -0.113 0.72278E+04 195 beidellite-Mg -15.46 -16.69 -1.23 -0.076 0.48400E+04 196 beidellite-Na -14.04 -15.78 -1.74 -0.106 0.68272E+04 197 bornite -51.78 -52.19 -0.41 -0.030 0.15909E+04 199 chalcocite -13.41 -14.91 -1.50 -0.374 0.58791E+04 200 covellite -11.94 -13.35 -1.41 -0.536 0.55244E+04 202 montmorillonite-Ca -11.18 -12.29 -1.11 -0.069 0.43751E+04 203 montmorillonite-K -10.41 -11.60 -1.19 -0.073 0.46747E+04 204 montmorillonite-Mg -11.42 -12.35 -0.93 -0.058 0.36635E+04 205 montmorillonite-Na -10.05 -11.43 -1.39 -0.085 0.54468E+04 206 nontronite-Ca -3.68 -5.00 -1.32 -0.086 0.51930E+04 207 nontronite-H -3.68 -5.52 -1.84 -0.123 0.72250E+04 208 nontronite-K -2.62 -4.31 -1.69 -0.108 0.66284E+04 209 nontronite-Mg -3.93 -5.06 -1.13 -0.073 0.44427E+04 210 nontronite-Na -2.56 -4.15 -1.59 -0.102 0.62417E+04 215 gypsum -11.75 -13.92 -2.16 -0.541 0.84919E+04 232 alabandite -6.13 -7.56 -1.43 -0.475 0.55992E+04 234 anglesite -14.07 -16.64 -2.58 -1.288 0.10112E+05 238 boehmite -4.69 -5.71 -1.02 -0.170 0.40067E+04 242 copper,native 1.77 -1.57 -3.34 -1.161 0.13113E+05 244 ferrous-oxide 1.77 0.99 -0.78 -0.194 0.30481E+04 245 galena -9.26 -9.58 -0.31 -0.104 0.12265E+04 246 silver,native 0.55 -3.59 -4.13 -1.438 0.16230E+05 248 litharge 5.18 0.44 -4.74 -1.185 0.18615E+05 256 wurtzite -9.80 -10.59 -0.79 -0.262 0.30880E+04 257 zincite 1.90 -0.58 -2.47 -0.619 0.97179E+04 258 an20ab80 -5.80 -5.81 -0.02 -0.001 0.68161E+02 259 an25ab75 -6.09 -6.10 -0.01 0.000 0.22577E+02 261 tr.625ac.25prg.125 8.67 7.95 -0.72 -0.019 0.28082E+04 Calculations done for 585.0000 Deg. C; 1589.0000 bar Temperature changed by -1.000 degrees to 584.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 26 Loop limit = 500 Temperature = 584.00 C Pressure = 1558.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5506E+02 kg liquid = 0.9920E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9957 Stoichiometric ionic strength = .3303911E+01 Osmotic coef. = 0.0000 True ionic strength = .2285923E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10446E-04 -4.9810 0.26897E-05 -5.5703 0.25748E+00 -0.5893 2 H2O 0.99573E+00 -0.0019 0.99573E+00 -0.0019 3 Cl- 0.19161E+00 -0.7176 0.44302E-01 -1.3536 0.23121E+00 -0.6360 4 SO4-- 0.17991E-03 -3.7449 0.10213E-05 -5.9908 0.56768E-02 -2.2459 5 HCO3- 0.22677E-04 -4.6444 0.56539E-05 -5.2477 0.24932E+00 -0.6032 6 HS- 0.14431E-03 -3.8407 0.33649E-04 -4.4730 0.23316E+00 -0.6323 7 H4SiO4 0.85950E-01 -1.0658 0.85950E-01 -1.0658 0.10000E+01 0.0000 8 Al+++ 0.58352E-17 -17.2339 0.40280E-22 -22.3949 0.69030E-05 -5.1610 9 Ca++ 0.23210E-05 -5.6343 0.10652E-07 -7.9726 0.45892E-02 -2.3383 10 Mg++ 0.12368E-05 -5.9077 0.46634E-08 -8.3313 0.37704E-02 -2.4236 11 Fe++ 0.18276E-07 -7.7381 0.72448E-10 -10.1400 0.39640E-02 -2.4019 12 K+ 0.51653E-01 -1.2869 0.13213E-01 -1.8790 0.25581E+00 -0.5921 13 Na+ 0.17469E+00 -0.7577 0.40929E-01 -1.3880 0.23429E+00 -0.6302 14 Mn++ 0.53291E-06 -6.2733 0.21909E-08 -8.6594 0.41112E-02 -2.3860 15 Zn++ 0.48744E-09 -9.3121 0.19322E-11 -11.7139 0.39640E-02 -2.4019 16 Cu+ 0.39796E-07 -7.4002 0.92986E-08 -8.0316 0.23366E+00 -0.6314 17 Pb++ 0.39161E-08 -8.4071 0.20123E-10 -10.6963 0.51385E-02 -2.2892 18 Ag+ 0.36551E-09 -9.4371 0.92036E-10 -10.0360 0.25180E+00 -0.5989 19 Ba++ 0.17659E-06 -6.7530 0.97428E-09 -9.0113 0.55170E-02 -2.2583 20 HPO4-- 0.90845E-09 -9.0417 0.51828E-11 -11.2854 0.57051E-02 -2.2437 21 HSiO3- 0.20134E-05 -5.6961 0.46551E-06 -6.3321 0.23121E+00 -0.6360 22 Ca(HSiO3)+ 0.11991E-07 -7.9211 0.30947E-08 -8.5094 0.25807E+00 -0.5883 23 Mg(HSiO3)+ 0.13921E-08 -8.8563 0.35927E-09 -9.4446 0.25807E+00 -0.5883 24 NaHSiO3,aq 0.14812E-05 -5.8294 0.14812E-05 -5.8294 0.10000E+01 0.0000 28 AgCl,aq 0.74027E-07 -7.1306 0.74027E-07 -7.1306 0.10000E+01 0.0000 29 AgCl2- 0.49570E-05 -5.3048 0.11461E-05 -5.9408 0.23121E+00 -0.6360 30 AgCl3-2 0.23449E-05 -5.6299 0.12329E-07 -7.9091 0.52577E-02 -2.2792 31 AgCl4-3 0.13899E-05 -5.8570 0.82330E-11 -11.0844 0.59235E-05 -5.2274 34 Ag(HS),aq 0.73003E-09 -9.1367 0.73003E-09 -9.1367 0.10000E+01 0.0000 35 Ag(HS)2- 0.42920E-08 -8.3673 0.99234E-09 -9.0033 0.23121E+00 -0.6360 36 AlO+ 0.10040E-10 -10.9983 0.25909E-11 -11.5865 0.25807E+00 -0.5883 38 HAlO2,aq 0.43787E-08 -8.3587 0.43787E-08 -8.3587 0.10000E+01 0.0000 39 AlO2- 0.18003E-04 -4.7447 0.36325E-05 -5.4398 0.20177E+00 -0.6951 41 Ba(HCO3)+ 0.86914E-06 -6.0609 0.23336E-06 -6.6320 0.26850E+00 -0.5711 42 BaCl+ 0.30320E-04 -4.5183 0.78248E-05 -5.1065 0.25807E+00 -0.5883 43 CH4,aq 0.18954E-08 -8.7223 0.22926E-08 -8.6397 0.12096E+01 0.0826 48 CO,aq 0.75156E-03 -3.1240 0.75156E-03 -3.1240 0.10000E+01 0.0000 49 CO2,aq 0.26768E+01 0.4276 0.32378E+01 0.5102 0.12096E+01 0.0826 50 CO3-2 0.47811E-10 -10.3205 0.25138E-12 -12.5997 0.52577E-02 -2.2792 51 CaCO3,aq 0.17148E-10 -10.7658 0.17148E-10 -10.7658 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.51418E-06 -6.2889 0.13269E-06 -6.8771 0.25807E+00 -0.5883 53 CaCl+ 0.21281E-03 -3.6720 0.54919E-04 -4.2603 0.25807E+00 -0.5883 54 CaCl2,aq 0.13714E-03 -3.8628 0.13714E-03 -3.8628 0.10000E+01 0.0000 55 CaOH+ 0.34751E-06 -6.4590 0.89682E-07 -7.0473 0.25807E+00 -0.5883 56 CaSO4,aq 0.14077E-06 -6.8515 0.14077E-06 -6.8515 0.10000E+01 0.0000 57 HCl,aq 0.13097E-02 -2.8828 0.13097E-02 -2.8828 0.10000E+01 0.0000 66 CuCl,aq 0.32315E-04 -4.4906 0.32315E-04 -4.4906 0.10000E+01 0.0000 67 CuCl2- 0.12912E-03 -3.8890 0.29854E-04 -4.5250 0.23121E+00 -0.6360 68 CuCl3-2 0.32425E-05 -5.4891 0.17048E-07 -7.7683 0.52577E-02 -2.2792 74 FeCl+ 0.52131E-06 -6.2829 0.13453E-06 -6.8712 0.25807E+00 -0.5883 75 FeCl2,aq 0.76224E-02 -2.1179 0.76224E-02 -2.1179 0.10000E+01 0.0000 77 FeO,aq 0.81752E-07 -7.0875 0.81752E-07 -7.0875 0.10000E+01 0.0000 78 FeOH+ 0.39750E-07 -7.4007 0.10258E-07 -7.9889 0.25807E+00 -0.5883 79 HFeO2- 0.10792E-07 -7.9669 0.24953E-08 -8.6029 0.23121E+00 -0.6360 82 FeO2- 0.70873E-08 -8.1495 0.16386E-08 -8.7855 0.23121E+00 -0.6360 83 HFeO2,aq 0.25865E-09 -9.5873 0.25865E-09 -9.5873 0.10000E+01 0.0000 84 H2,aq 0.45261E-02 -2.3443 0.54746E-02 -2.2616 0.12096E+01 0.0826 85 KCl,aq 0.58088E-01 -1.2359 0.58088E-01 -1.2359 0.10000E+01 0.0000 86 KHSO4,aq 0.12804E-01 -1.8927 0.12804E-01 -1.8927 0.10000E+01 0.0000 87 KOH,aq 0.10009E-05 -5.9996 0.10009E-05 -5.9996 0.10000E+01 0.0000 88 KSO4- 0.38780E-02 -2.4114 0.89662E-03 -3.0474 0.23121E+00 -0.6360 90 Mg(HCO3)+ 0.92908E-07 -7.0319 0.23977E-07 -7.6202 0.25807E+00 -0.5883 91 MgCl+ 0.17817E-04 -4.7492 0.45982E-05 -5.3374 0.25807E+00 -0.5883 92 MgOH+ 0.62199E-06 -6.2062 0.16052E-06 -6.7945 0.25807E+00 -0.5883 94 MnO,aq 0.37602E-07 -7.4248 0.37602E-07 -7.4248 0.10000E+01 0.0000 95 MnOH+ 0.14900E-06 -6.8268 0.38452E-07 -7.4151 0.25807E+00 -0.5883 97 HMnO2- 0.23008E-10 -10.6381 0.53196E-11 -11.2741 0.23121E+00 -0.6360 100 MnCl+ 0.11580E-02 -2.9363 0.29885E-03 -3.5245 0.25807E+00 -0.5883 101 MnSO4,aq 0.36496E-07 -7.4378 0.36496E-07 -7.4378 0.10000E+01 0.0000 102 NaCl,aq 0.38402E+00 -0.4156 0.38402E+00 -0.4156 0.10000E+01 0.0000 103 NaOH,aq 0.14391E-05 -5.8419 0.14391E-05 -5.8419 0.10000E+01 0.0000 105 OH- 0.89367E-05 -5.0488 0.18032E-05 -5.7440 0.20177E+00 -0.6951 110 HPO3-2 0.13756E-10 -10.8615 0.72324E-13 -13.1407 0.52577E-02 -2.2792 111 H3PO3,aq 0.10950E-09 -9.9606 0.10950E-09 -9.9606 0.10000E+01 0.0000 112 H2PO3- 0.42071E-08 -8.3760 0.97270E-09 -9.0120 0.23121E+00 -0.6360 113 H3PO4,aq 0.84048E-06 -6.0755 0.84048E-06 -6.0755 0.10000E+01 0.0000 114 H2PO4- 0.16851E-05 -5.7734 0.40994E-06 -6.3873 0.24327E+00 -0.6139 116 H4P2O7,aq 0.58710E-10 -10.2313 0.58710E-10 -10.2313 0.10000E+01 0.0000 117 H3P2O7- 0.10587E-08 -8.9752 0.24478E-09 -9.6112 0.23121E+00 -0.6360 118 H2P2O7-2 0.29758E-06 -6.5264 0.15646E-08 -8.8056 0.52577E-02 -2.2792 119 HP2O7-3 0.11949E-07 -7.9227 0.70779E-13 -13.1501 0.59235E-05 -5.2274 121 PbCl+ 0.22978E-05 -5.6387 0.59299E-06 -6.2270 0.25807E+00 -0.5883 122 PbCl2,aq 0.88444E-04 -4.0533 0.88444E-04 -4.0533 0.10000E+01 0.0000 123 PbCl3- 0.11185E-03 -3.9514 0.25860E-04 -4.5874 0.23121E+00 -0.6360 124 PbCl4-2 0.27648E-04 -4.5583 0.14537E-06 -6.8375 0.52577E-02 -2.2792 125 PbO,aq 0.40313E-08 -8.3946 0.40313E-08 -8.3946 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10266E-03 -3.9886 0.10266E-03 -3.9886 0.10000E+01 0.0000 128 Pb(HS)3- 0.10022E-04 -4.9991 0.23171E-05 -5.6351 0.23121E+00 -0.6360 129 H2S,aq 0.10487E+01 0.0206 0.12684E+01 0.1033 0.12096E+01 0.0826 130 S2-2 0.15099E-07 -7.8211 0.79385E-10 -10.1003 0.52577E-02 -2.2792 131 S3-2 0.15878E-08 -8.7992 0.83480E-11 -11.0784 0.52577E-02 -2.2792 132 S3- 0.19884E-01 -1.7015 0.45972E-02 -2.3375 0.23121E+00 -0.6360 133 S4-2 0.13909E-09 -9.8567 0.73130E-12 -12.1359 0.52577E-02 -2.2792 134 S5-2 0.10324E-10 -10.9862 0.54279E-13 -13.2654 0.52577E-02 -2.2792 135 SO2,aq 0.28508E+00 -0.5450 0.28508E+00 -0.5450 0.10000E+01 0.0000 136 SO3-2 0.58873E-09 -9.2301 0.48661E-11 -11.3128 0.82655E-02 -2.0827 137 HSO3- 0.40863E-03 -3.3887 0.94477E-04 -4.0247 0.23121E+00 -0.6360 138 HSO4- 0.11524E-01 -1.9384 0.30515E-02 -2.5155 0.26480E+00 -0.5771 140 S2O3-2 0.53123E-06 -6.2747 0.27931E-08 -8.5539 0.52577E-02 -2.2792 141 HS2O3- 0.65918E-06 -6.1810 0.15241E-06 -6.8170 0.23121E+00 -0.6360 142 H2S2O3,aq 0.25149E-07 -7.5995 0.25149E-07 -7.5995 0.10000E+01 0.0000 150 S4O6-2 0.67204E-09 -9.1726 0.35334E-11 -11.4518 0.52577E-02 -2.2792 152 ZnCl+ 0.57805E-03 -3.2380 0.14918E-03 -3.8263 0.25807E+00 -0.5883 153 ZnCl2,aq 0.13512E-02 -2.8693 0.13512E-02 -2.8693 0.10000E+01 0.0000 154 ZnCl3- 0.17751E-03 -3.7508 0.41041E-04 -4.3868 0.23121E+00 -0.6360 155 ZnO,aq 0.39853E-07 -7.3995 0.39853E-07 -7.3995 0.10000E+01 0.0000 156 ZnOH+ 0.29855E-05 -5.5250 0.77047E-06 -6.1132 0.25807E+00 -0.5883 158 HZnO2- 0.33593E-09 -9.4737 0.77669E-10 -10.1098 0.23121E+00 -0.6360 Charge balance for all species = 0.2551E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1044642E-04 0.4301864E+01 0.3534959E+04 0.0000 2 H2O 0.1000000E+01 0.5250046E+02 0.7710769E+06 0.0000 3 Cl- 0.1916107E+00 0.6567298E+00 0.1898160E+05 4.2167 4 SO4-- 0.1799102E-03 0.2536108E+00 0.1986143E+05 5.1498 5 HCO3- 0.2267742E-04 0.2677596E+01 0.1331958E+06 0.3226 6 HS- 0.1443144E-03 0.1168954E+01 0.3151745E+05 1.0973 7 H4SiO4 0.8595020E-01 0.8595371E-01 0.6735202E+04 -1.0658 8 Al+++ 0.5835185E-17 0.1800719E-04 0.3961003E+00 -5.6840 9 Ca++ 0.2321006E-05 0.3532826E-03 0.1154307E+02 3.1680 10 Mg++ 0.1236826E-05 0.1977048E-04 0.3918600E+00 2.8093 11 Fe++ 0.1827649E-07 0.7623029E-02 0.3470727E+03 1.0006 12 K+ 0.5165288E-01 0.1264239E+00 0.4030152E+04 3.6913 13 Na+ 0.1746937E+00 0.5587181E+00 0.1047179E+05 4.1823 14 Mn++ 0.5329117E-06 0.1158783E-02 0.5190009E+02 2.4812 15 Zn++ 0.4874385E-09 0.2109758E-02 0.1124357E+03 -0.5734 16 Cu+ 0.3979610E-07 0.1647201E-03 0.8532706E+01 -2.4613 17 Pb++ 0.3916140E-08 0.3429240E-03 0.5792417E+02 0.4443 18 Ag+ 0.3655092E-09 0.8771217E-05 0.7713537E+00 -4.4657 19 Ba++ 0.1765950E-06 0.3136600E-04 0.3511958E+01 2.1293 20 HPO4-- 0.9084459E-09 0.3152159E-05 0.2466479E+00 -0.1448 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4267348E+01 -.4985978E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5207923E+02 -.1144532E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2515760E+00 0.1468251E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159575E+01 0.5687190E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.8526407E-01 0.5833025E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1786271E-04 0.6766768E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3504481E-03 0.1774618E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1961185E-04 0.1064797E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.7561867E-02 0.1204887E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254096E+00 0.5289248E-06 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542353E+00 0.3640796E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149486E-02 0.1403256E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2092831E-02 0.2065036E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1633985E-03 0.2362113E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.3111434E-04 0.2425811E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3126868E-05 0.5440632E-05 0.0000000E+00 Chg. balance for solid moles: -.2372E-19 Mass of aqueous solution: 0.121677E+04 g Temperature = 584.00 C Pressure = 1558.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.1236E-04 -4.908 0.1683E-02 -2.774 0.4541E-01 0.5679E-03 annite 0.1693E-06 -6.771 0.8667E-04 -4.062 0.2339E-02 0.2613E-04 phlogopite 0.3549E-06 -6.450 0.1481E-03 -3.829 0.3997E-02 0.5310E-04 biotite-Mn 0.4678E-08 -8.330 0.2382E-05 -5.623 0.6427E-04 0.7139E-06 apatite-OH 0.1814E-05 -5.741 0.9110E-03 -3.040 0.2458E-01 0.2895E-03 magnetite 0.3227E-03 -3.491 0.7471E-01 -1.127 2.016 0.1437E-01 quartz 0.5692E-01 -1.245 3.420 0.534 92.29 1.292 barite 0.2426E-04 -4.615 0.5662E-02 -2.247 0.1528 0.1264E-02 chalcopyrite 0.2362E-03 -3.627 0.4334E-01 -1.363 1.170 0.1012E-01 sphalerite 0.2065E-03 -3.685 0.2012E-01 -1.696 0.5430 0.4920E-02 an30ab70 0.5201E-03 -3.284 0.1389 -0.857 3.748 0.5215E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3201E+00 0.3201E+00 1.0000 -0.495 phlogopite 0.6710E+00 0.6710E+00 1.0000 -0.173 biotite-Mn 0.8843E-02 0.8843E-02 1.0000 -2.053 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.705563 g Volume = 1.375305 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -13.96 -13.96 0.00 0.000 -0.69672E-11 24 annite -0.70 -0.70 0.00 0.000 0.13499E-10 25 phlogopite 3.76 3.76 0.00 0.000 0.31352E-10 26 biotite-Mn 8.41 8.41 0.00 0.000 0.13934E-10 30 apatite-OH -51.44 -51.44 0.00 0.000 -0.27869E-10 106 magnetite 1.22 1.22 0.00 0.000 -0.87090E-11 144 quartz -1.06 -1.06 0.00 0.000 0.00000E+00 237 barite -15.00 -15.00 0.00 0.000 -0.69672E-11 240 chalcopyrite -22.43 -22.43 0.00 0.000 -0.13934E-10 255 sphalerite -10.62 -10.62 0.00 0.000 0.00000E+00 260 an30ab70 -6.38 -6.38 0.00 0.000 0.13934E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.29 -0.286 0.11217E+04 2.907 2 CO2,gas -9.32 -10.82 -1.49 -0.497 0.58511E+04 1.701 3 CH4,gas 6.92 -3.73 -10.65 -2.663 0.41776E+05 -7.459 4 H2,gas 5.81 1.77 -4.04 -2.311 0.15864E+05 -0.852 5 H2S,gas -7.77 -10.04 -2.28 -1.139 0.89317E+04 0.915 6 CO,gas -3.33 -9.04 -5.72 -1.759 0.22423E+05 -2.524 7 SO3,gas -6.78 -17.13 -10.35 -2.587 0.40580E+05 -7.154 8 O2,gas 16.55 -3.54 -20.09 -13.394 0.78799E+05 -16.898 9 HCl,gas -5.75 -6.92 -1.17 -0.586 0.45985E+04 -1.172 10 acmite 3.74 2.17 -1.57 -0.163 0.61686E+04 12 akimotoite 5.84 1.75 -4.10 -0.819 0.16064E+05 13 akimotoite-Fe 3.80 -0.06 -3.87 -0.773 0.15161E+05 14 albite-high -4.55 -4.69 -0.14 -0.011 0.56331E+03 15 albite -4.52 -4.69 -0.17 -0.013 0.66506E+03 16 almandine -10.19 -11.56 -1.37 -0.068 0.53703E+04 17 pyrope -3.75 -6.14 -2.39 -0.119 0.93683E+04 18 analcite -2.67 -3.63 -0.97 -0.107 0.37876E+04 19 andalusite -12.12 -12.44 -0.31 -0.031 0.12318E+04 20 andradite 11.05 6.54 -4.52 -0.235 0.17713E+05 21 grossular -0.38 -5.06 -4.68 -0.234 0.18360E+05 27 anorthite -9.84 -10.33 -0.49 -0.038 0.19153E+04 28 anthophyllite 13.27 11.15 -2.12 -0.057 0.83005E+04 29 anthophyllite-Fe 1.05 -1.51 -2.55 -0.069 0.10011E+05 31 apatite-OH-zs -49.33 -51.44 -2.11 -0.163 0.82935E+04 32 apatite-Cl-zs -55.27 -58.36 -3.10 -0.258 0.12141E+05 33 aragonite -4.25 -7.65 -3.40 -1.133 0.13328E+05 34 brucite 5.02 2.81 -2.21 -0.442 0.86698E+04 35 calcite -4.35 -7.65 -3.30 -1.101 0.12953E+05 36 carnegieite-low -0.79 -2.57 -1.77 -0.254 0.69613E+04 37 carnegieite-high -0.72 -2.57 -1.84 -0.263 0.72279E+04 38 carpholite-Mg -8.88 -10.69 -1.81 -0.121 0.70984E+04 39 carpholite-Fe -10.20 -12.50 -2.31 -0.154 0.90471E+04 40 celadonite -1.33 -3.44 -2.11 -0.124 0.82716E+04 41 celadonite-Fe -2.70 -5.25 -2.55 -0.150 0.10006E+05 42 chrysotile 8.67 6.29 -2.38 -0.198 0.93329E+04 44 clinochlore 0.73 -0.53 -1.26 -0.039 0.49303E+04 45 daphnite -6.11 -9.57 -3.46 -0.108 0.13574E+05 47 chlorite-Al-free 17.55 12.59 -4.96 -0.207 0.19456E+05 48 chloritoid-Mg -8.50 -9.63 -1.13 -0.076 0.44427E+04 49 chloritoid-Fe -10.37 -11.44 -1.07 -0.071 0.41968E+04 50 chloritoid-Mn -8.21 -9.96 -1.75 -0.117 0.68759E+04 52 coesite -0.78 -1.06 -0.28 -0.093 0.10947E+04 53 cordierite-H -21.98 -22.44 -0.47 -0.017 0.18369E+04 54 cordierite-Fe -24.40 -26.06 -1.66 -0.057 0.65076E+04 55 cordierite-Mn -19.99 -23.10 -3.10 -0.107 0.12174E+05 56 corundum -10.89 -11.37 -0.48 -0.044 0.18853E+04 58 cristobalite -1.01 -1.06 -0.05 -0.017 0.19971E+03 59 cummingtonite 13.33 11.15 -2.18 -0.059 0.85312E+04 61 cymrite-K -2.90 -5.18 -2.28 -0.190 0.89412E+04 63 diaspore -4.94 -5.69 -0.74 -0.124 0.29211E+04 65 diopside 5.13 3.85 -1.28 -0.128 0.50298E+04 66 hedenbergite 3.76 2.04 -1.71 -0.171 0.67258E+04 68 eastonite -8.71 -9.88 -1.17 -0.045 0.45952E+04 69 enstatite 4.32 3.49 -0.82 -0.082 0.32357E+04 70 clinoenstatite-HiP 4.80 3.49 -1.31 -0.131 0.51281E+04 71 clinoenstatite 4.30 3.49 -0.81 -0.081 0.31834E+04 72 protoenstatite 4.45 3.49 -0.96 -0.096 0.37461E+04 73 epidote -6.20 -8.12 -1.92 -0.093 0.75234E+04 74 clinozoisite -11.64 -13.92 -2.27 -0.103 0.89073E+04 75 epidote-Fe 0.91 -2.32 -3.23 -0.168 0.12671E+05 76 fayalite 1.83 0.94 -0.89 -0.127 0.34920E+04 77 ferrosilite 0.85 -0.13 -0.98 -0.098 0.38435E+04 78 forsterite 5.70 4.55 -1.15 -0.164 0.44990E+04 79 gedrite -13.41 -15.08 -1.67 -0.045 0.65491E+04 81 gibbsite -3.35 -5.69 -2.34 -0.334 0.91824E+04 82 glaucophane -0.01 -3.09 -3.08 -0.083 0.12075E+05 83 glaucophane-Fe -3.92 -8.51 -4.60 -0.124 0.18029E+05 84 goethite 0.91 0.11 -0.80 -0.173 0.31443E+04 86 greenalite 3.97 0.87 -3.11 -0.259 0.12179E+05 87 grunerite 1.58 -1.51 -3.09 -0.083 0.12102E+05 88 halite -0.67 -2.74 -2.08 -1.038 0.81433E+04 89 hematite 0.31 0.23 -0.09 -0.011 0.34399E+03 90 heulandite -12.91 -15.65 -2.74 -0.125 0.10766E+05 91 hercynite -9.47 -10.37 -0.90 -0.060 0.35348E+04 94 jadeite -1.99 -3.63 -1.64 -0.164 0.64487E+04 96 kalsilite -1.42 -3.06 -1.64 -0.234 0.64317E+04 97 kaolinite -10.93 -13.50 -2.57 -0.234 0.10086E+05 98 kyanite -11.97 -12.44 -0.47 -0.047 0.18273E+04 100 laumontite -9.15 -12.46 -3.31 -0.221 0.12979E+05 101 lawsonite -7.13 -10.34 -3.21 -0.214 0.12591E+05 102 leucite -3.13 -4.12 -0.99 -0.099 0.38803E+04 104 lizardite 8.86 6.29 -2.57 -0.214 0.10068E+05 105 magnesite -5.26 -8.01 -2.75 -0.915 0.10768E+05 107 minnesotaite 0.61 -1.25 -1.86 -0.109 0.72952E+04 108 minnesotaite-Mg 6.39 4.17 -2.22 -0.131 0.87140E+04 109 magnesioferrite 4.21 3.03 -1.18 -0.096 0.46232E+04 111 manganosite 5.06 2.48 -2.58 -0.645 0.10126E+05 112 margarite -20.27 -21.71 -1.44 -0.058 0.56464E+04 115 microcline -5.11 -5.18 -0.07 -0.005 0.26616E+03 116 monticellite 8.32 4.91 -3.41 -0.487 0.13378E+05 118 mullite-Si -11.40 -12.44 -1.04 -0.104 0.40633E+04 119 muscovite -15.88 -16.56 -0.68 -0.040 0.26570E+04 120 paragonite -15.20 -16.07 -0.86 -0.051 0.33860E+04 121 nepheline -1.08 -2.57 -1.48 -0.212 0.58229E+04 122 osumilite(2) -14.82 -16.63 -1.81 -0.038 0.70888E+04 123 osumilite-Fe -31.30 -33.37 -2.07 -0.043 0.81178E+04 124 pargasite 1.90 -1.69 -3.59 -0.095 0.14090E+05 125 periclase 5.20 2.81 -2.39 -0.598 0.93833E+04 126 periclase-Fe 2.69 1.00 -1.69 -0.423 0.66310E+04 127 perovskite-Al -9.20 -11.37 -2.18 -0.198 0.85401E+04 132 phlogopite-Na 4.62 3.73 -0.89 -0.049 0.34886E+04 134 prehnite -5.22 -8.23 -3.01 -0.177 0.11806E+05 135 prehnite-Fe 0.62 -2.43 -3.05 -0.183 0.11960E+05 138 px-Mg-tschermaks -7.94 -9.63 -1.69 -0.121 0.66265E+04 139 px-Ca-tschermaks -6.94 -9.27 -2.33 -0.167 0.91436E+04 140 pyrite -20.84 -20.86 -0.02 -0.004 0.67459E+02 141 pyrrhotite -8.43 -9.04 -0.61 -0.204 0.23959E+04 142 pyrrhotiteFe0.875 -9.15 -9.39 -0.24 -0.089 0.94544E+03 143 pyrophyllite -14.44 -15.62 -1.18 -0.074 0.46387E+04 146 riebeckite 5.88 3.09 -2.79 -0.077 0.10960E+05 147 ringwoodite-Fe 2.81 0.94 -1.87 -0.268 0.73449E+04 148 ringwoodite-Mg 8.79 4.55 -4.24 -0.606 0.16634E+05 149 rhodochrosite -5.14 -8.34 -3.20 -1.067 0.12557E+05 150 rhodonite 2.40 1.42 -0.99 -0.197 0.38661E+04 151 sanidine -4.59 -5.18 -0.60 -0.046 0.23356E+04 152 sapphirine(351) -44.84 -49.51 -4.67 -0.071 0.18325E+05 153 siderite -7.04 -9.82 -2.78 -0.927 0.10909E+05 154 sillimanite -12.09 -12.44 -0.34 -0.034 0.13486E+04 156 spinel -7.36 -8.57 -1.20 -0.080 0.47226E+04 158 staurolite-Fe -101.45 -106.34 -4.88 -0.045 0.19154E+05 162 stilpnomelane-Fe -8.59 -13.04 -4.46 -0.133 0.17478E+05 163 stilpnomelane-Mg -2.08 -4.00 -1.92 -0.057 0.75145E+04 164 stishovite 1.83 -1.06 -2.89 -0.964 0.11345E+05 165 sudoite-Fe -20.27 -23.94 -3.67 -0.119 0.14413E+05 166 sudoite -18.13 -20.33 -2.20 -0.071 0.86153E+04 167 sulfur -10.33 -11.81 -1.48 -0.457 0.58191E+04 168 sylvite -0.57 -3.23 -2.66 -1.330 0.10436E+05 169 talc 4.69 4.17 -0.52 -0.031 0.20351E+04 170 talc-Fe 1.97 -1.25 -3.22 -0.190 0.12641E+05 171 talc-tschermaks -7.49 -8.95 -1.46 -0.086 0.57183E+04 173 tephroite 6.14 3.90 -2.25 -0.321 0.88092E+04 176 topaz-H -10.05 -12.44 -2.38 -0.217 0.93469E+04 177 tremolite 14.33 11.87 -2.45 -0.066 0.96244E+04 179 troilite-low -8.34 -9.04 -0.71 -0.236 0.27754E+04 180 tschermakite -11.59 -14.37 -2.78 -0.075 0.10903E+05 183 wadsleyite-Fe 2.66 0.94 -1.72 -0.246 0.67478E+04 184 wadsleyite-Mg 7.87 4.55 -3.31 -0.473 0.12993E+05 185 wairakite -10.95 -12.46 -1.51 -0.089 0.59231E+04 186 walstromite 4.53 2.10 -2.42 -0.485 0.95073E+04 187 wollastonite 4.12 2.10 -2.02 -0.404 0.79148E+04 188 pseudo-wollastonite 4.23 2.10 -2.13 -0.426 0.83479E+04 189 zoisite -11.70 -13.92 -2.21 -0.101 0.86742E+04 192 beidellite-Ca -15.15 -16.63 -1.48 -0.092 0.58056E+04 193 beidellite-H -15.14 -17.15 -2.01 -0.128 0.78667E+04 194 beidellite-K -14.09 -15.93 -1.85 -0.113 0.72392E+04 195 beidellite-Mg -15.45 -16.69 -1.24 -0.077 0.48655E+04 196 beidellite-Na -14.03 -15.77 -1.74 -0.107 0.68398E+04 197 bornite -51.94 -52.36 -0.42 -0.031 0.16507E+04 199 chalcocite -13.46 -14.97 -1.51 -0.376 0.59067E+04 200 covellite -11.98 -13.39 -1.41 -0.537 0.55289E+04 202 montmorillonite-Ca -11.18 -12.30 -1.12 -0.069 0.43935E+04 203 montmorillonite-K -10.41 -11.60 -1.19 -0.073 0.46844E+04 204 montmorillonite-Mg -11.42 -12.36 -0.94 -0.058 0.36795E+04 205 montmorillonite-Na -10.05 -11.44 -1.39 -0.085 0.54528E+04 206 nontronite-Ca -3.70 -5.03 -1.33 -0.086 0.51979E+04 207 nontronite-H -3.71 -5.55 -1.84 -0.123 0.72269E+04 208 nontronite-K -2.64 -4.33 -1.69 -0.108 0.66215E+04 209 nontronite-Mg -3.95 -5.09 -1.13 -0.074 0.44461E+04 210 nontronite-Na -2.58 -4.17 -1.59 -0.102 0.62367E+04 215 gypsum -11.80 -13.97 -2.17 -0.542 0.85029E+04 232 alabandite -6.15 -7.56 -1.41 -0.470 0.55312E+04 234 anglesite -14.12 -16.69 -2.57 -1.284 0.10072E+05 238 boehmite -4.66 -5.69 -1.02 -0.171 0.40153E+04 242 copper,native 1.77 -1.58 -3.35 -1.164 0.13126E+05 244 ferrous-oxide 1.78 1.00 -0.78 -0.195 0.30536E+04 245 galena -9.30 -9.60 -0.30 -0.101 0.11859E+04 246 silver,native 0.54 -3.58 -4.12 -1.434 0.16174E+05 248 litharge 5.18 0.44 -4.74 -1.184 0.18583E+05 256 wurtzite -9.83 -10.62 -0.79 -0.262 0.30879E+04 257 zincite 1.91 -0.58 -2.48 -0.620 0.97286E+04 258 an20ab80 -5.80 -5.82 -0.02 -0.001 0.63480E+02 259 an25ab75 -6.10 -6.10 -0.01 0.000 0.20294E+02 261 tr.625ac.25prg.125 8.65 7.92 -0.73 -0.020 0.28822E+04 Calculations done for 584.0000 Deg. C; 1558.0000 bar Temperature changed by -1.000 degrees to 583.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 27 Loop limit = 500 Temperature = 583.00 C Pressure = 1528.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5507E+02 kg liquid = 0.9920E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9958 Stoichiometric ionic strength = .3302959E+01 Osmotic coef. = 0.0000 True ionic strength = .2253373E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10184E-04 -4.9921 0.25948E-05 -5.5859 0.25479E+00 -0.5938 2 H2O 0.99580E+00 -0.0018 0.99580E+00 -0.0018 3 Cl- 0.18893E+00 -0.7237 0.43073E-01 -1.3658 0.22798E+00 -0.6421 4 SO4-- 0.18085E-03 -3.7427 0.98292E-06 -6.0075 0.54351E-02 -2.2648 5 HCO3- 0.21861E-04 -4.6603 0.53767E-05 -5.2695 0.24594E+00 -0.6092 6 HS- 0.14266E-03 -3.8457 0.32802E-04 -4.4841 0.22993E+00 -0.6384 7 H4SiO4 0.83919E-01 -1.0761 0.83919E-01 -1.0761 0.10000E+01 0.0000 8 Al+++ 0.60310E-17 -17.2196 0.37774E-22 -22.4228 0.62634E-05 -5.2032 9 Ca++ 0.22586E-05 -5.6462 0.99114E-08 -8.0039 0.43883E-02 -2.3577 10 Mg++ 0.12268E-05 -5.9112 0.44181E-08 -8.3548 0.36014E-02 -2.4435 11 Fe++ 0.18054E-07 -7.7434 0.68375E-10 -10.1651 0.37873E-02 -2.4217 12 K+ 0.51066E-01 -1.2919 0.12888E-01 -1.8898 0.25238E+00 -0.5979 13 Na+ 0.17206E+00 -0.7643 0.39754E-01 -1.4006 0.23104E+00 -0.6363 14 Mn++ 0.54392E-06 -6.2645 0.21369E-08 -8.6702 0.39288E-02 -2.4057 15 Zn++ 0.47516E-09 -9.3232 0.17996E-11 -11.7448 0.37873E-02 -2.4217 16 Cu+ 0.37710E-07 -7.4235 0.86888E-08 -8.0610 0.23041E+00 -0.6375 17 Pb++ 0.38392E-08 -8.4158 0.18876E-10 -10.7241 0.49166E-02 -2.3083 18 Ag+ 0.35935E-09 -9.4445 0.89265E-10 -10.0493 0.24841E+00 -0.6048 19 Ba++ 0.17006E-06 -6.7694 0.89809E-09 -9.0467 0.52810E-02 -2.2773 20 HPO4-- 0.91237E-09 -9.0398 0.49837E-11 -11.3025 0.54623E-02 -2.2626 21 HSiO3- 0.19676E-05 -5.7061 0.44858E-06 -6.3482 0.22798E+00 -0.6421 22 Ca(HSiO3)+ 0.11433E-07 -7.9418 0.29112E-08 -8.5359 0.25462E+00 -0.5941 23 Mg(HSiO3)+ 0.13592E-08 -8.8667 0.34609E-09 -9.4608 0.25462E+00 -0.5941 24 NaHSiO3,aq 0.14843E-05 -5.8285 0.14843E-05 -5.8285 0.10000E+01 0.0000 28 AgCl,aq 0.74564E-07 -7.1275 0.74564E-07 -7.1275 0.10000E+01 0.0000 29 AgCl2- 0.49547E-05 -5.3050 0.11296E-05 -5.9471 0.22798E+00 -0.6421 30 AgCl3-2 0.23245E-05 -5.6337 0.11696E-07 -7.9320 0.50316E-02 -2.2983 31 AgCl4-3 0.14114E-05 -5.8503 0.75805E-11 -11.1203 0.53707E-05 -5.2700 34 Ag(HS),aq 0.74905E-09 -9.1255 0.74905E-09 -9.1255 0.10000E+01 0.0000 35 Ag(HS)2- 0.43440E-08 -8.3621 0.99036E-09 -9.0042 0.22798E+00 -0.6421 36 AlO+ 0.10006E-10 -10.9997 0.25477E-11 -11.5938 0.25462E+00 -0.5941 38 HAlO2,aq 0.44007E-08 -8.3565 0.44007E-08 -8.3565 0.10000E+01 0.0000 39 AlO2- 0.17697E-04 -4.7521 0.35185E-05 -5.4536 0.19882E+00 -0.7015 41 Ba(HCO3)+ 0.82383E-06 -6.0842 0.21829E-06 -6.6610 0.26497E+00 -0.5768 42 BaCl+ 0.28948E-04 -4.5384 0.73708E-05 -5.1325 0.25462E+00 -0.5941 43 CH4,aq 0.18694E-08 -8.7283 0.22593E-08 -8.6460 0.12086E+01 0.0823 48 CO,aq 0.73778E-03 -3.1321 0.73778E-03 -3.1321 0.10000E+01 0.0000 49 CO2,aq 0.26767E+01 0.4276 0.32351E+01 0.5099 0.12086E+01 0.0823 50 CO3-2 0.46586E-10 -10.3317 0.23441E-12 -12.6300 0.50316E-02 -2.2983 51 CaCO3,aq 0.16623E-10 -10.7793 0.16623E-10 -10.7793 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.48078E-06 -6.3181 0.12242E-06 -6.9122 0.25462E+00 -0.5941 53 CaCl+ 0.20433E-03 -3.6897 0.52028E-04 -4.2838 0.25462E+00 -0.5941 54 CaCl2,aq 0.13452E-03 -3.8712 0.13452E-03 -3.8712 0.10000E+01 0.0000 55 CaOH+ 0.33446E-06 -6.4757 0.85162E-07 -7.0698 0.25462E+00 -0.5941 56 CaSO4,aq 0.14120E-06 -6.8502 0.14120E-06 -6.8502 0.10000E+01 0.0000 57 HCl,aq 0.13473E-02 -2.8705 0.13473E-02 -2.8705 0.10000E+01 0.0000 66 CuCl,aq 0.31459E-04 -4.5023 0.31459E-04 -4.5023 0.10000E+01 0.0000 67 CuCl2- 0.12572E-03 -3.9006 0.28663E-04 -4.5427 0.22798E+00 -0.6421 68 CuCl3-2 0.31403E-05 -5.5030 0.15801E-07 -7.8013 0.50316E-02 -2.2983 74 FeCl+ 0.50786E-06 -6.2943 0.12931E-06 -6.8884 0.25462E+00 -0.5941 75 FeCl2,aq 0.74241E-02 -2.1294 0.74241E-02 -2.1294 0.10000E+01 0.0000 77 FeO,aq 0.80886E-07 -7.0921 0.80886E-07 -7.0921 0.10000E+01 0.0000 78 FeOH+ 0.38648E-07 -7.4129 0.98406E-08 -8.0070 0.25462E+00 -0.5941 79 HFeO2- 0.10466E-07 -7.9802 0.23862E-08 -8.6223 0.22798E+00 -0.6421 82 FeO2- 0.69514E-08 -8.1579 0.15848E-08 -8.8000 0.22798E+00 -0.6421 83 HFeO2,aq 0.26074E-09 -9.5838 0.26074E-09 -9.5838 0.10000E+01 0.0000 84 H2,aq 0.45145E-02 -2.3454 0.54563E-02 -2.2631 0.12086E+01 0.0823 85 KCl,aq 0.58652E-01 -1.2317 0.58652E-01 -1.2317 0.10000E+01 0.0000 86 KHSO4,aq 0.12796E-01 -1.8929 0.12796E-01 -1.8929 0.10000E+01 0.0000 87 KOH,aq 0.10081E-05 -5.9965 0.10081E-05 -5.9965 0.10000E+01 0.0000 88 KSO4- 0.39007E-02 -2.4089 0.88931E-03 -3.0509 0.22798E+00 -0.6421 90 Mg(HCO3)+ 0.88059E-07 -7.0552 0.22422E-07 -7.6493 0.25462E+00 -0.5941 91 MgCl+ 0.17474E-04 -4.7576 0.44493E-05 -5.3517 0.25462E+00 -0.5941 92 MgOH+ 0.60964E-06 -6.2149 0.15523E-06 -6.8090 0.25462E+00 -0.5941 94 MnO,aq 0.38573E-07 -7.4137 0.38573E-07 -7.4137 0.10000E+01 0.0000 95 MnOH+ 0.14940E-06 -6.8256 0.38042E-07 -7.4197 0.25462E+00 -0.5941 97 HMnO2- 0.23061E-10 -10.6371 0.52576E-11 -11.2792 0.22798E+00 -0.6421 100 MnCl+ 0.11579E-02 -2.9363 0.29484E-03 -3.5304 0.25462E+00 -0.5941 101 MnSO4,aq 0.38302E-07 -7.4168 0.38302E-07 -7.4168 0.10000E+01 0.0000 102 NaCl,aq 0.38662E+00 -0.4127 0.38662E+00 -0.4127 0.10000E+01 0.0000 103 NaOH,aq 0.14449E-05 -5.8402 0.14449E-05 -5.8402 0.10000E+01 0.0000 105 OH- 0.87877E-05 -5.0561 0.17472E-05 -5.7577 0.19882E+00 -0.7015 110 HPO3-2 0.13468E-10 -10.8707 0.67767E-13 -13.1690 0.50316E-02 -2.2983 111 H3PO3,aq 0.10917E-09 -9.9619 0.10917E-09 -9.9619 0.10000E+01 0.0000 112 H2PO3- 0.40779E-08 -8.3896 0.92969E-09 -9.0317 0.22798E+00 -0.6421 113 H3PO4,aq 0.85594E-06 -6.0676 0.85594E-06 -6.0676 0.10000E+01 0.0000 114 H2PO4- 0.16743E-05 -5.7762 0.40173E-06 -6.3961 0.23994E+00 -0.6199 116 H4P2O7,aq 0.60931E-10 -10.2152 0.60931E-10 -10.2152 0.10000E+01 0.0000 117 H3P2O7- 0.10558E-08 -8.9764 0.24070E-09 -9.6185 0.22798E+00 -0.6421 118 H2P2O7-2 0.29525E-06 -6.5298 0.14856E-08 -8.8281 0.50316E-02 -2.2983 119 HP2O7-3 0.12288E-07 -7.9105 0.65994E-13 -13.1805 0.53707E-05 -5.2700 121 PbCl+ 0.22441E-05 -5.6489 0.57142E-06 -6.2430 0.25462E+00 -0.5941 122 PbCl2,aq 0.88227E-04 -4.0544 0.88227E-04 -4.0544 0.10000E+01 0.0000 123 PbCl3- 0.11191E-03 -3.9511 0.25513E-04 -4.5932 0.22798E+00 -0.6421 124 PbCl4-2 0.27509E-04 -4.5605 0.13841E-06 -6.8588 0.50316E-02 -2.2983 125 PbO,aq 0.40730E-08 -8.3901 0.40730E-08 -8.3901 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10288E-03 -3.9877 0.10288E-03 -3.9877 0.10000E+01 0.0000 128 Pb(HS)3- 0.10132E-04 -4.9943 0.23099E-05 -5.6364 0.22798E+00 -0.6421 129 H2S,aq 0.10494E+01 0.0210 0.12684E+01 0.1032 0.12086E+01 0.0823 130 S2-2 0.14946E-07 -7.8255 0.75204E-10 -10.1238 0.50316E-02 -2.2983 131 S3-2 0.15710E-08 -8.8038 0.79046E-11 -11.1021 0.50316E-02 -2.2983 132 S3- 0.19457E-01 -1.7109 0.44360E-02 -2.3530 0.22798E+00 -0.6421 133 S4-2 0.13765E-09 -9.8612 0.69262E-12 -12.1595 0.50316E-02 -2.2983 134 S5-2 0.10224E-10 -10.9904 0.51445E-13 -13.2887 0.50316E-02 -2.2983 135 SO2,aq 0.28555E+00 -0.5443 0.28555E+00 -0.5443 0.10000E+01 0.0000 136 SO3-2 0.58206E-09 -9.2350 0.46164E-11 -11.3357 0.79312E-02 -2.1007 137 HSO3- 0.40120E-03 -3.3966 0.91467E-04 -4.0387 0.22798E+00 -0.6421 138 HSO4- 0.11375E-01 -1.9440 0.29725E-02 -2.5269 0.26131E+00 -0.5829 140 S2O3-2 0.53031E-06 -6.2755 0.26683E-08 -8.5738 0.50316E-02 -2.2983 141 HS2O3- 0.64578E-06 -6.1899 0.14723E-06 -6.8320 0.22798E+00 -0.6421 142 H2S2O3,aq 0.25402E-07 -7.5951 0.25402E-07 -7.5951 0.10000E+01 0.0000 150 S4O6-2 0.66660E-09 -9.1761 0.33541E-11 -11.4744 0.50316E-02 -2.2983 152 ZnCl+ 0.54984E-03 -3.2598 0.14000E-03 -3.8539 0.25462E+00 -0.5941 153 ZnCl2,aq 0.13114E-02 -2.8823 0.13114E-02 -2.8823 0.10000E+01 0.0000 154 ZnCl3- 0.16910E-03 -3.7719 0.38553E-04 -4.4139 0.22798E+00 -0.6421 155 ZnO,aq 0.38996E-07 -7.4090 0.38996E-07 -7.4090 0.10000E+01 0.0000 156 ZnOH+ 0.28546E-05 -5.5445 0.72685E-06 -6.1386 0.25462E+00 -0.5941 158 HZnO2- 0.32255E-09 -9.4914 0.73537E-10 -10.1335 0.22798E+00 -0.6421 Charge balance for all species = 0.2551E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1018385E-04 0.4302061E+01 0.3535754E+04 0.0000 2 H2O 0.1000000E+01 0.5250120E+02 0.7712259E+06 0.0000 3 Cl- 0.1889274E+00 0.6566908E+00 0.1898387E+05 4.2201 4 SO4-- 0.1808474E-03 0.2535665E+00 0.1986152E+05 5.1643 5 HCO3- 0.2186137E-04 0.2677437E+01 0.1332117E+06 0.3164 6 HS- 0.1426610E-03 0.1168816E+01 0.3151938E+05 1.1018 7 H4SiO4 0.8391913E-01 0.8392259E-01 0.6577225E+04 -1.0761 8 Al+++ 0.6030965E-17 0.1770123E-04 0.3894399E+00 -5.6651 9 Ca++ 0.2258611E-05 0.3420808E-03 0.1117907E+02 3.1679 10 Mg++ 0.1226764E-05 0.1939995E-04 0.3845849E+00 2.8170 11 Fe++ 0.1805366E-07 0.7424732E-02 0.3381049E+03 1.0067 12 K+ 0.5106616E-01 0.1264162E+00 0.4030628E+04 3.6961 13 Na+ 0.1720640E+00 0.5586848E+00 0.1047304E+05 4.1853 14 Mn++ 0.5439183E-06 0.1158709E-02 0.5190606E+02 2.5016 15 Zn++ 0.4751557E-09 0.2033259E-02 0.1083782E+03 -0.5730 16 Cu+ 0.3770994E-07 0.1603596E-03 0.8308315E+01 -2.4751 17 Pb++ 0.3839155E-08 0.3429037E-03 0.5793110E+02 0.4477 18 Ag+ 0.3593503E-09 0.8770695E-05 0.7714461E+00 -4.4634 19 Ba++ 0.1700620E-06 0.2994163E-04 0.3353076E+01 2.1251 20 HPO4-- 0.9123680E-09 0.3152634E-05 0.2467293E+00 -0.1306 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4267798E+01 -.5435396E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5208306E+02 -.1182820E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2515470E+00 0.1758223E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159508E+01 0.6365958E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.8325420E-01 0.6034013E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1756025E-04 0.6769793E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3393563E-03 0.1885536E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1924544E-04 0.1431208E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.7365599E-02 0.1401155E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254094E+00 0.7113368E-06 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542352E+00 0.3641443E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149481E-02 0.1945882E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.2017066E-02 0.2822691E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1590824E-03 0.2405273E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.2970316E-04 0.2566929E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3127525E-05 0.5439975E-05 0.0000000E+00 Chg. balance for solid moles: 0.4710E-18 Mass of aqueous solution: 0.121662E+04 g Temperature = 583.00 C Pressure = 1528.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.2343E-04 -4.630 0.3189E-02 -2.496 0.8281E-01 0.1076E-02 annite 0.2278E-06 -6.642 0.1166E-03 -3.933 0.3028E-02 0.3515E-04 phlogopite 0.4771E-06 -6.321 0.1991E-03 -3.701 0.5169E-02 0.7138E-04 biotite-Mn 0.6486E-08 -8.188 0.3303E-05 -5.481 0.8575E-04 0.9900E-06 apatite-OH 0.1813E-05 -5.742 0.9109E-03 -3.041 0.2365E-01 0.2894E-03 magnetite 0.3866E-03 -3.413 0.8951E-01 -1.048 2.324 0.1721E-01 quartz 0.5893E-01 -1.230 3.541 0.549 91.94 1.337 barite 0.2567E-04 -4.591 0.5991E-02 -2.222 0.1556 0.1337E-02 chalcopyrite 0.2405E-03 -3.619 0.4414E-01 -1.355 1.146 0.1030E-01 sphalerite 0.2823E-03 -3.549 0.2750E-01 -1.561 0.7141 0.6726E-02 an30ab70 0.5202E-03 -3.284 0.1389 -0.857 3.607 0.5216E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3202E+00 0.3202E+00 1.0000 -0.495 phlogopite 0.6707E+00 0.6707E+00 1.0000 -0.173 biotite-Mn 0.9118E-02 0.9118E-02 1.0000 -2.040 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.851183 g Volume = 1.426343 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.01 -14.01 0.00 0.000 -0.69591E-11 24 annite -0.69 -0.69 0.00 0.000 -0.33925E-10 25 phlogopite 3.77 3.77 0.00 0.000 -0.20877E-10 26 biotite-Mn 8.43 8.43 0.00 0.000 -0.13918E-10 30 apatite-OH -51.58 -51.58 0.00 0.000 -0.27836E-10 106 magnetite 1.24 1.24 0.00 0.000 0.12178E-10 144 quartz -1.07 -1.07 0.00 0.000 0.00000E+00 237 barite -15.05 -15.05 0.00 0.000 0.00000E+00 240 chalcopyrite -22.50 -22.50 0.00 0.000 0.00000E+00 255 sphalerite -10.64 -10.64 0.00 0.000 0.00000E+00 260 an30ab70 -6.39 -6.39 0.00 0.000 0.48713E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.29 -0.285 0.11166E+04 2.899 2 CO2,gas -9.35 -10.85 -1.50 -0.500 0.58738E+04 1.685 3 CH4,gas 6.92 -3.75 -10.67 -2.667 0.41790E+05 -7.483 4 H2,gas 5.82 1.78 -4.05 -2.312 0.15848E+05 -0.861 5 H2S,gas -7.79 -10.07 -2.28 -1.139 0.89220E+04 0.907 6 CO,gas -3.35 -9.08 -5.73 -1.763 0.22443E+05 -2.545 7 SO3,gas -6.82 -17.18 -10.36 -2.590 0.40580E+05 -7.174 8 O2,gas 16.56 -3.55 -20.11 -13.409 0.78798E+05 -16.930 9 HCl,gas -5.77 -6.95 -1.19 -0.593 0.46470E+04 -1.186 10 acmite 3.73 2.16 -1.57 -0.163 0.61515E+04 12 akimotoite 5.85 1.74 -4.10 -0.821 0.16074E+05 13 akimotoite-Fe 3.80 -0.07 -3.87 -0.774 0.15168E+05 14 albite-high -4.56 -4.70 -0.14 -0.011 0.55250E+03 15 albite -4.53 -4.70 -0.17 -0.013 0.65033E+03 16 almandine -10.16 -11.54 -1.38 -0.069 0.54089E+04 17 pyrope -3.70 -6.11 -2.40 -0.120 0.94192E+04 18 analcite -2.67 -3.63 -0.96 -0.107 0.37775E+04 19 andalusite -12.09 -12.41 -0.32 -0.032 0.12467E+04 20 andradite 11.05 6.51 -4.53 -0.236 0.17764E+05 21 grossular -0.35 -5.05 -4.70 -0.235 0.18427E+05 27 anorthite -9.82 -10.31 -0.50 -0.038 0.19448E+04 28 anthophyllite 13.26 11.12 -2.13 -0.058 0.83513E+04 29 anthophyllite-Fe 1.01 -1.55 -2.56 -0.069 0.10031E+05 31 apatite-OH-zs -49.47 -51.58 -2.12 -0.163 0.82967E+04 32 apatite-Cl-zs -55.43 -58.53 -3.10 -0.258 0.12145E+05 33 aragonite -4.28 -7.69 -3.41 -1.137 0.13365E+05 34 brucite 5.03 2.81 -2.21 -0.443 0.86772E+04 35 calcite -4.37 -7.69 -3.32 -1.105 0.12987E+05 36 carnegieite-low -0.78 -2.56 -1.77 -0.253 0.69452E+04 37 carnegieite-high -0.71 -2.56 -1.84 -0.263 0.72144E+04 38 carpholite-Mg -8.85 -10.67 -1.82 -0.121 0.71204E+04 39 carpholite-Fe -10.17 -12.48 -2.31 -0.154 0.90665E+04 40 celadonite -1.34 -3.45 -2.11 -0.124 0.82635E+04 41 celadonite-Fe -2.71 -5.26 -2.55 -0.150 0.99977E+04 42 chrysotile 8.68 6.30 -2.39 -0.199 0.93480E+04 44 clinochlore 0.78 -0.48 -1.27 -0.040 0.49650E+04 45 daphnite -6.07 -9.54 -3.47 -0.108 0.13596E+05 47 chlorite-Al-free 17.57 12.59 -4.97 -0.207 0.19481E+05 48 chloritoid-Mg -8.46 -9.59 -1.14 -0.076 0.44642E+04 49 chloritoid-Fe -10.33 -11.41 -1.08 -0.072 0.42120E+04 50 chloritoid-Mn -8.17 -9.91 -1.74 -0.116 0.68320E+04 52 coesite -0.79 -1.07 -0.28 -0.093 0.10960E+04 53 cordierite-H -21.93 -22.41 -0.48 -0.017 0.18797E+04 54 cordierite-Fe -24.36 -26.02 -1.67 -0.057 0.65250E+04 55 cordierite-Mn -19.95 -23.03 -3.08 -0.106 0.12070E+05 56 corundum -10.85 -11.34 -0.49 -0.044 0.19020E+04 58 cristobalite -1.02 -1.07 -0.05 -0.017 0.19774E+03 59 cummingtonite 13.32 11.12 -2.19 -0.059 0.85835E+04 61 cymrite-K -2.91 -5.19 -2.28 -0.190 0.89333E+04 63 diaspore -4.92 -5.67 -0.75 -0.125 0.29274E+04 65 diopside 5.13 3.84 -1.29 -0.129 0.50564E+04 66 hedenbergite 3.75 2.03 -1.72 -0.172 0.67493E+04 68 eastonite -8.65 -9.82 -1.18 -0.045 0.46035E+04 69 enstatite 4.32 3.49 -0.83 -0.083 0.32528E+04 70 clinoenstatite-HiP 4.80 3.49 -1.31 -0.131 0.51458E+04 71 clinoenstatite 4.30 3.49 -0.82 -0.082 0.31999E+04 72 protoenstatite 4.45 3.49 -0.96 -0.096 0.37625E+04 73 epidote -6.17 -8.11 -1.93 -0.094 0.75758E+04 74 clinozoisite -11.60 -13.89 -2.29 -0.104 0.89687E+04 75 epidote-Fe 0.92 -2.32 -3.24 -0.169 0.12711E+05 76 fayalite 1.83 0.94 -0.89 -0.128 0.34991E+04 77 ferrosilite 0.85 -0.14 -0.98 -0.098 0.38530E+04 78 forsterite 5.71 4.56 -1.15 -0.165 0.45131E+04 79 gedrite -13.34 -15.03 -1.69 -0.046 0.66174E+04 81 gibbsite -3.32 -5.67 -2.35 -0.335 0.91913E+04 82 glaucophane -0.02 -3.10 -3.08 -0.083 0.12068E+05 83 glaucophane-Fe -3.94 -8.53 -4.60 -0.124 0.18012E+05 84 goethite 0.92 0.12 -0.80 -0.174 0.31438E+04 86 greenalite 3.97 0.87 -3.11 -0.259 0.12179E+05 87 grunerite 1.55 -1.55 -3.09 -0.084 0.12125E+05 88 halite -0.69 -2.77 -2.07 -1.037 0.81254E+04 89 hematite 0.32 0.23 -0.09 -0.011 0.34084E+03 90 heulandite -12.93 -15.69 -2.76 -0.126 0.10822E+05 91 hercynite -9.42 -10.33 -0.91 -0.060 0.35546E+04 94 jadeite -1.98 -3.63 -1.64 -0.164 0.64390E+04 96 kalsilite -1.41 -3.05 -1.64 -0.234 0.64137E+04 97 kaolinite -10.91 -13.48 -2.58 -0.234 0.10090E+05 98 kyanite -11.94 -12.41 -0.47 -0.047 0.18455E+04 100 laumontite -9.14 -12.47 -3.32 -0.222 0.13017E+05 101 lawsonite -7.09 -10.32 -3.22 -0.215 0.12628E+05 102 leucite -3.13 -4.12 -0.99 -0.099 0.38619E+04 104 lizardite 8.87 6.30 -2.57 -0.214 0.10079E+05 105 magnesite -5.28 -8.04 -2.76 -0.918 0.10793E+05 107 minnesotaite 0.59 -1.28 -1.86 -0.110 0.72962E+04 108 minnesotaite-Mg 6.38 4.15 -2.23 -0.131 0.87264E+04 109 magnesioferrite 4.23 3.05 -1.18 -0.096 0.46268E+04 111 manganosite 5.07 2.50 -2.57 -0.643 0.10069E+05 112 margarite -20.20 -21.65 -1.45 -0.058 0.56938E+04 115 microcline -5.13 -5.19 -0.06 -0.005 0.24461E+03 116 monticellite 8.33 4.91 -3.42 -0.489 0.13400E+05 118 mullite-Si -11.37 -12.41 -1.04 -0.104 0.40817E+04 119 muscovite -15.85 -16.53 -0.68 -0.040 0.26564E+04 120 paragonite -15.17 -16.04 -0.87 -0.051 0.33899E+04 121 nepheline -1.07 -2.56 -1.48 -0.212 0.58072E+04 122 osumilite(2) -14.85 -16.66 -1.81 -0.038 0.70954E+04 123 osumilite-Fe -31.29 -33.36 -2.07 -0.043 0.81236E+04 124 pargasite 1.95 -1.66 -3.62 -0.095 0.14167E+05 125 periclase 5.21 2.82 -2.40 -0.599 0.93897E+04 126 periclase-Fe 2.70 1.00 -1.69 -0.423 0.66351E+04 127 perovskite-Al -9.15 -11.34 -2.18 -0.199 0.85573E+04 132 phlogopite-Na 4.63 3.74 -0.89 -0.050 0.34938E+04 134 prehnite -5.20 -8.22 -3.03 -0.178 0.11854E+05 135 prehnite-Fe 0.62 -2.44 -3.06 -0.184 0.11996E+05 138 px-Mg-tschermaks -7.89 -9.59 -1.70 -0.121 0.66523E+04 139 px-Ca-tschermaks -6.90 -9.24 -2.34 -0.167 0.91778E+04 140 pyrite -20.90 -20.91 -0.01 -0.003 0.44725E+02 141 pyrrhotite -8.45 -9.06 -0.61 -0.203 0.23888E+04 142 pyrrhotiteFe0.875 -9.17 -9.41 -0.24 -0.088 0.93819E+03 143 pyrophyllite -14.44 -15.63 -1.19 -0.074 0.46544E+04 146 riebeckite 5.82 3.03 -2.79 -0.077 0.10928E+05 147 ringwoodite-Fe 2.81 0.94 -1.88 -0.268 0.73518E+04 148 ringwoodite-Mg 8.81 4.56 -4.25 -0.607 0.16648E+05 149 rhodochrosite -5.16 -8.35 -3.20 -1.065 0.12518E+05 150 rhodonite 2.40 1.43 -0.97 -0.195 0.38103E+04 151 sanidine -4.60 -5.19 -0.59 -0.045 0.23140E+04 152 sapphirine(351) -44.60 -49.31 -4.70 -0.071 0.18430E+05 153 siderite -7.06 -9.85 -2.79 -0.930 0.10930E+05 154 sillimanite -12.06 -12.41 -0.35 -0.035 0.13652E+04 156 spinel -7.31 -8.52 -1.21 -0.081 0.47443E+04 158 staurolite-Fe -101.12 -106.05 -4.93 -0.045 0.19321E+05 162 stilpnomelane-Fe -8.59 -13.06 -4.47 -0.133 0.17498E+05 163 stilpnomelane-Mg -2.07 -4.00 -1.93 -0.058 0.75670E+04 164 stishovite 1.82 -1.07 -2.90 -0.965 0.11347E+05 165 sudoite-Fe -20.19 -23.89 -3.69 -0.119 0.14468E+05 166 sudoite -18.05 -20.27 -2.21 -0.071 0.86755E+04 167 sulfur -10.36 -11.85 -1.48 -0.456 0.58087E+04 168 sylvite -0.60 -3.26 -2.66 -1.329 0.10411E+05 169 talc 4.68 4.15 -0.52 -0.031 0.20506E+04 170 talc-Fe 1.95 -1.28 -3.23 -0.190 0.12646E+05 171 talc-tschermaks -7.46 -8.92 -1.47 -0.086 0.57425E+04 173 tephroite 6.15 3.93 -2.22 -0.317 0.86952E+04 176 topaz-H -10.02 -12.41 -2.39 -0.217 0.93627E+04 177 tremolite 14.30 11.83 -2.47 -0.067 0.96924E+04 179 troilite-low -8.36 -9.06 -0.71 -0.235 0.27673E+04 180 tschermakite -11.53 -14.33 -2.80 -0.076 0.10984E+05 183 wadsleyite-Fe 2.66 0.94 -1.72 -0.246 0.67563E+04 184 wadsleyite-Mg 7.88 4.56 -3.32 -0.474 0.13009E+05 185 wairakite -10.95 -12.46 -1.52 -0.089 0.59470E+04 186 walstromite 4.52 2.09 -2.43 -0.486 0.95251E+04 187 wollastonite 4.12 2.09 -2.02 -0.405 0.79305E+04 188 pseudo-wollastonite 4.23 2.09 -2.14 -0.427 0.83646E+04 189 zoisite -11.66 -13.89 -2.23 -0.101 0.87375E+04 192 beidellite-Ca -15.13 -16.62 -1.49 -0.092 0.58253E+04 193 beidellite-H -15.13 -17.14 -2.01 -0.128 0.78830E+04 194 beidellite-K -14.07 -15.92 -1.85 -0.113 0.72481E+04 195 beidellite-Mg -15.43 -16.68 -1.25 -0.077 0.48880E+04 196 beidellite-Na -14.01 -15.76 -1.75 -0.107 0.68500E+04 197 bornite -52.10 -52.54 -0.44 -0.033 0.17128E+04 199 chalcocite -13.51 -15.02 -1.52 -0.379 0.59353E+04 200 covellite -12.02 -13.43 -1.41 -0.538 0.55335E+04 202 montmorillonite-Ca -11.18 -12.31 -1.13 -0.070 0.44099E+04 203 montmorillonite-K -10.41 -11.61 -1.20 -0.073 0.46923E+04 204 montmorillonite-Mg -11.42 -12.36 -0.94 -0.058 0.36933E+04 205 montmorillonite-Na -10.05 -11.45 -1.39 -0.085 0.54571E+04 206 nontronite-Ca -3.73 -5.05 -1.33 -0.086 0.52018E+04 207 nontronite-H -3.73 -5.58 -1.84 -0.124 0.72277E+04 208 nontronite-K -2.67 -4.36 -1.69 -0.108 0.66139E+04 209 nontronite-Mg -3.98 -5.11 -1.14 -0.074 0.44485E+04 210 nontronite-Na -2.60 -4.19 -1.59 -0.102 0.62310E+04 215 gypsum -11.84 -14.02 -2.17 -0.543 0.85131E+04 232 alabandite -6.17 -7.57 -1.40 -0.465 0.54654E+04 234 anglesite -14.17 -16.73 -2.56 -1.280 0.10031E+05 238 boehmite -4.64 -5.67 -1.03 -0.171 0.40227E+04 242 copper,native 1.77 -1.59 -3.35 -1.167 0.13140E+05 244 ferrous-oxide 1.79 1.00 -0.78 -0.195 0.30592E+04 245 galena -9.33 -9.62 -0.29 -0.098 0.11463E+04 246 silver,native 0.54 -3.58 -4.11 -1.431 0.16117E+05 248 litharge 5.18 0.45 -4.74 -1.184 0.18551E+05 256 wurtzite -9.85 -10.64 -0.79 -0.263 0.30879E+04 257 zincite 1.91 -0.57 -2.49 -0.622 0.97398E+04 258 an20ab80 -5.81 -5.82 -0.02 -0.001 0.58823E+02 259 an25ab75 -6.10 -6.10 0.00 0.000 0.17963E+02 261 tr.625ac.25prg.125 8.63 7.88 -0.76 -0.020 0.29579E+04 Calculations done for 583.0000 Deg. C; 1528.0000 bar Temperature changed by -1.000 degrees to 582.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 27 Loop limit = 500 Temperature = 582.00 C Pressure = 1500.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5507E+02 kg liquid = 0.9921E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9959 Stoichiometric ionic strength = .3302107E+01 Osmotic coef. = 0.0000 True ionic strength = .2224036E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.99604E-05 -5.0017 0.25131E-05 -5.5998 0.25230E+00 -0.5981 2 H2O 0.99586E+00 -0.0018 0.99586E+00 -0.0018 3 Cl- 0.18650E+00 -0.7293 0.41965E-01 -1.3771 0.22502E+00 -0.6478 4 SO4-- 0.18193E-03 -3.7401 0.94930E-06 -6.0226 0.52180E-02 -2.2825 5 HCO3- 0.21131E-04 -4.6751 0.51314E-05 -5.2898 0.24284E+00 -0.6147 6 HS- 0.14112E-03 -3.8504 0.32026E-04 -4.4945 0.22695E+00 -0.6441 7 H4SiO4 0.82035E-01 -1.0860 0.82035E-01 -1.0860 0.10000E+01 0.0000 8 Al+++ 0.62672E-17 -17.2029 0.35835E-22 -22.4457 0.57178E-05 -5.2428 9 Ca++ 0.22056E-05 -5.6565 0.92810E-08 -8.0324 0.42080E-02 -2.3759 10 Mg++ 0.12224E-05 -5.9128 0.42171E-08 -8.3750 0.34499E-02 -2.4622 11 Fe++ 0.17919E-07 -7.7467 0.65027E-10 -10.1869 0.36290E-02 -2.4402 12 K+ 0.50537E-01 -1.2964 0.12595E-01 -1.8998 0.24923E+00 -0.6034 13 Na+ 0.16969E+00 -0.7703 0.38698E-01 -1.4123 0.22805E+00 -0.6420 14 Mn++ 0.55517E-06 -6.2556 0.20904E-08 -8.6798 0.37652E-02 -2.4242 15 Zn++ 0.46507E-09 -9.3325 0.16877E-11 -11.7727 0.36290E-02 -2.4402 16 Cu+ 0.35793E-07 -7.4462 0.81403E-08 -8.0894 0.22743E+00 -0.6432 17 Pb++ 0.37754E-08 -8.4230 0.17811E-10 -10.7493 0.47176E-02 -2.3263 18 Ag+ 0.35386E-09 -9.4512 0.86795E-10 -10.0615 0.24528E+00 -0.6103 19 Ba++ 0.16439E-06 -6.7841 0.83329E-09 -9.0792 0.50691E-02 -2.2951 20 HPO4-- 0.91846E-09 -9.0369 0.48168E-11 -11.3172 0.52444E-02 -2.2803 21 HSiO3- 0.19242E-05 -5.7157 0.43299E-06 -6.3635 0.22502E+00 -0.6478 22 Ca(HSiO3)+ 0.10930E-07 -7.9614 0.27484E-08 -8.5609 0.25145E+00 -0.5995 23 Mg(HSiO3)+ 0.13318E-08 -8.8756 0.33488E-09 -9.4751 0.25145E+00 -0.5995 24 NaHSiO3,aq 0.14858E-05 -5.8280 0.14858E-05 -5.8280 0.10000E+01 0.0000 28 AgCl,aq 0.75077E-07 -7.1245 0.75077E-07 -7.1245 0.10000E+01 0.0000 29 AgCl2- 0.49520E-05 -5.3052 0.11143E-05 -5.9530 0.22502E+00 -0.6478 30 AgCl3-2 0.23056E-05 -5.6372 0.11133E-07 -7.9534 0.48287E-02 -2.3162 31 AgCl4-3 0.14320E-05 -5.8440 0.70163E-11 -11.1539 0.48995E-05 -5.3098 34 Ag(HS),aq 0.76799E-09 -9.1146 0.76799E-09 -9.1146 0.10000E+01 0.0000 35 Ag(HS)2- 0.43933E-08 -8.3572 0.98859E-09 -9.0050 0.22502E+00 -0.6478 36 AlO+ 0.10008E-10 -10.9996 0.25166E-11 -11.5992 0.25145E+00 -0.5995 38 HAlO2,aq 0.44305E-08 -8.3535 0.44305E-08 -8.3535 0.10000E+01 0.0000 39 AlO2- 0.17415E-04 -4.7591 0.34152E-05 -5.4666 0.19611E+00 -0.7075 41 Ba(HCO3)+ 0.78356E-06 -6.1059 0.20508E-06 -6.6881 0.26172E+00 -0.5822 42 BaCl+ 0.27722E-04 -4.5572 0.69709E-05 -5.1567 0.25145E+00 -0.5995 43 CH4,aq 0.18427E-08 -8.7345 0.22256E-08 -8.6525 0.12078E+01 0.0820 48 CO,aq 0.72413E-03 -3.1402 0.72413E-03 -3.1402 0.10000E+01 0.0000 49 CO2,aq 0.26765E+01 0.4276 0.32327E+01 0.5096 0.12078E+01 0.0820 50 CO3-2 0.45470E-10 -10.3423 0.21956E-12 -12.6584 0.48287E-02 -2.3162 51 CaCO3,aq 0.16145E-10 -10.7920 0.16145E-10 -10.7920 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.45171E-06 -6.3451 0.11358E-06 -6.9447 0.25145E+00 -0.5995 53 CaCl+ 0.19680E-03 -3.7060 0.49487E-04 -4.3055 0.25145E+00 -0.5995 54 CaCl2,aq 0.13209E-03 -3.8791 0.13209E-03 -3.8791 0.10000E+01 0.0000 55 CaOH+ 0.32247E-06 -6.4915 0.81087E-07 -7.0910 0.25145E+00 -0.5995 56 CaSO4,aq 0.14178E-06 -6.8484 0.14178E-06 -6.8484 0.10000E+01 0.0000 57 HCl,aq 0.13837E-02 -2.8589 0.13837E-02 -2.8589 0.10000E+01 0.0000 66 CuCl,aq 0.30615E-04 -4.5141 0.30615E-04 -4.5141 0.10000E+01 0.0000 67 CuCl2- 0.12238E-03 -3.9123 0.27539E-04 -4.5601 0.22502E+00 -0.6478 68 CuCl3-2 0.30429E-05 -5.5167 0.14693E-07 -7.8329 0.48287E-02 -2.3162 74 FeCl+ 0.49697E-06 -6.3037 0.12496E-06 -6.9032 0.25145E+00 -0.5995 75 FeCl2,aq 0.72503E-02 -2.1396 0.72503E-02 -2.1396 0.10000E+01 0.0000 77 FeO,aq 0.80058E-07 -7.0966 0.80058E-07 -7.0966 0.10000E+01 0.0000 78 FeOH+ 0.37711E-07 -7.4235 0.94826E-08 -8.0231 0.25145E+00 -0.5995 79 HFeO2- 0.10153E-07 -7.9934 0.22846E-08 -8.6412 0.22502E+00 -0.6478 82 FeO2- 0.68198E-08 -8.1662 0.15346E-08 -8.8140 0.22502E+00 -0.6478 83 HFeO2,aq 0.26298E-09 -9.5801 0.26298E-09 -9.5801 0.10000E+01 0.0000 84 H2,aq 0.44964E-02 -2.3471 0.54307E-02 -2.2651 0.12078E+01 0.0820 85 KCl,aq 0.59159E-01 -1.2280 0.59159E-01 -1.2280 0.10000E+01 0.0000 86 KHSO4,aq 0.12788E-01 -1.8932 0.12788E-01 -1.8932 0.10000E+01 0.0000 87 KOH,aq 0.10136E-05 -5.9941 0.10136E-05 -5.9941 0.10000E+01 0.0000 88 KSO4- 0.39231E-02 -2.4064 0.88278E-03 -3.0541 0.22502E+00 -0.6478 90 Mg(HCO3)+ 0.83999E-07 -7.0757 0.21122E-07 -7.6753 0.25145E+00 -0.5995 91 MgCl+ 0.17210E-04 -4.7642 0.43274E-05 -5.3638 0.25145E+00 -0.5995 92 MgOH+ 0.59923E-06 -6.2224 0.15068E-06 -6.8219 0.25145E+00 -0.5995 94 MnO,aq 0.39396E-07 -7.4045 0.39396E-07 -7.4045 0.10000E+01 0.0000 95 MnOH+ 0.14966E-06 -6.8249 0.37634E-07 -7.4244 0.25145E+00 -0.5995 97 HMnO2- 0.23014E-10 -10.6380 0.51786E-11 -11.2858 0.22502E+00 -0.6478 100 MnCl+ 0.11579E-02 -2.9363 0.29115E-03 -3.5359 0.25145E+00 -0.5995 101 MnSO4,aq 0.40107E-07 -7.3968 0.40107E-07 -7.3968 0.10000E+01 0.0000 102 NaCl,aq 0.38896E+00 -0.4101 0.38896E+00 -0.4101 0.10000E+01 0.0000 103 NaOH,aq 0.14487E-05 -5.8390 0.14487E-05 -5.8390 0.10000E+01 0.0000 105 OH- 0.86414E-05 -5.0634 0.16946E-05 -5.7709 0.19611E+00 -0.7075 110 HPO3-2 0.13215E-10 -10.8789 0.63810E-13 -13.1951 0.48287E-02 -2.3162 111 H3PO3,aq 0.10908E-09 -9.9623 0.10908E-09 -9.9623 0.10000E+01 0.0000 112 H2PO3- 0.39653E-08 -8.4017 0.89227E-09 -9.0495 0.22502E+00 -0.6478 113 H3PO4,aq 0.87378E-06 -6.0586 0.87378E-06 -6.0586 0.10000E+01 0.0000 114 H2PO4- 0.16692E-05 -5.7775 0.39540E-06 -6.4030 0.23689E+00 -0.6255 116 H4P2O7,aq 0.63488E-10 -10.1973 0.63488E-10 -10.1973 0.10000E+01 0.0000 117 H3P2O7- 0.10590E-08 -8.9751 0.23830E-09 -9.6229 0.22502E+00 -0.6478 118 H2P2O7-2 0.29456E-06 -6.5308 0.14223E-08 -8.8470 0.48287E-02 -2.3162 119 HP2O7-3 0.12672E-07 -7.8972 0.62087E-13 -13.2070 0.48995E-05 -5.3098 121 PbCl+ 0.21968E-05 -5.6582 0.55240E-06 -6.2577 0.25145E+00 -0.5995 122 PbCl2,aq 0.88037E-04 -4.0553 0.88037E-04 -4.0553 0.10000E+01 0.0000 123 PbCl3- 0.11196E-03 -3.9509 0.25193E-04 -4.5987 0.22502E+00 -0.6478 124 PbCl4-2 0.27392E-04 -4.5624 0.13227E-06 -6.8785 0.48287E-02 -2.3162 125 PbO,aq 0.41054E-08 -8.3866 0.41054E-08 -8.3866 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10307E-03 -3.9869 0.10307E-03 -3.9869 0.10000E+01 0.0000 128 Pb(HS)3- 0.10225E-04 -4.9903 0.23009E-05 -5.6381 0.22502E+00 -0.6478 129 H2S,aq 0.10501E+01 0.0212 0.12683E+01 0.1032 0.12078E+01 0.0820 130 S2-2 0.14804E-07 -7.8296 0.71487E-10 -10.1458 0.48287E-02 -2.3162 131 S3-2 0.15573E-08 -8.8076 0.75196E-11 -11.1238 0.48287E-02 -2.3162 132 S3- 0.19076E-01 -1.7195 0.42925E-02 -2.3673 0.22502E+00 -0.6478 133 S4-2 0.13665E-09 -9.8644 0.65985E-12 -12.1806 0.48287E-02 -2.3162 134 S5-2 0.10169E-10 -10.9927 0.49101E-13 -13.3089 0.48287E-02 -2.3162 135 SO2,aq 0.28596E+00 -0.5437 0.28596E+00 -0.5437 0.10000E+01 0.0000 136 SO3-2 0.57599E-09 -9.2396 0.43952E-11 -11.3570 0.76306E-02 -2.1174 137 HSO3- 0.39442E-03 -3.4040 0.88752E-04 -4.0518 0.22502E+00 -0.6478 138 HSO4- 0.11249E-01 -1.9489 0.29033E-02 -2.5371 0.25809E+00 -0.5882 140 S2O3-2 0.53024E-06 -6.2755 0.25604E-08 -8.5917 0.48287E-02 -2.3162 141 HS2O3- 0.63447E-06 -6.1976 0.14277E-06 -6.8454 0.22502E+00 -0.6478 142 H2S2O3,aq 0.25696E-07 -7.5901 0.25696E-07 -7.5901 0.10000E+01 0.0000 150 S4O6-2 0.66413E-09 -9.1777 0.32069E-11 -11.4939 0.48287E-02 -2.3162 152 ZnCl+ 0.52517E-03 -3.2797 0.13206E-03 -3.8792 0.25145E+00 -0.5995 153 ZnCl2,aq 0.12755E-02 -2.8943 0.12755E-02 -2.8943 0.10000E+01 0.0000 154 ZnCl3- 0.16160E-03 -3.7916 0.36363E-04 -4.4393 0.22502E+00 -0.6478 155 ZnO,aq 0.38154E-07 -7.4185 0.38154E-07 -7.4185 0.10000E+01 0.0000 156 ZnOH+ 0.27378E-05 -5.5626 0.68843E-06 -6.1621 0.25145E+00 -0.5995 158 HZnO2- 0.30959E-09 -9.5092 0.69665E-10 -10.1570 0.22502E+00 -0.6478 Charge balance for all species = 0.2551E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9960443E-05 0.4302220E+01 0.3536471E+04 0.0000 2 H2O 0.1000000E+01 0.5250188E+02 0.7713636E+06 0.0000 3 Cl- 0.1864965E+00 0.6566543E+00 0.1898596E+05 4.2227 4 SO4-- 0.1819262E-03 0.2535265E+00 0.1986168E+05 5.1770 5 HCO3- 0.2113093E-04 0.2677288E+01 0.1332264E+06 0.3100 6 HS- 0.1411156E-03 0.1168690E+01 0.3152118E+05 1.1053 7 H4SiO4 0.8203517E-01 0.8203859E-01 0.6430637E+04 -1.0860 8 Al+++ 0.6267215E-17 0.1741929E-04 0.3833005E+00 -5.6463 9 Ca++ 0.2205556E-05 0.3320225E-03 0.1085216E+02 3.1672 10 Mg++ 0.1222387E-05 0.1911655E-04 0.3790296E+00 2.8246 11 Fe++ 0.1791882E-07 0.7250957E-02 0.3302463E+03 1.0127 12 K+ 0.5053720E-01 0.1264091E+00 0.4031068E+04 3.7000 13 Na+ 0.1696927E+00 0.5586537E+00 0.1047420E+05 4.1875 14 Mn++ 0.5551733E-06 0.1158640E-02 0.5191158E+02 2.5198 15 Zn++ 0.4650744E-09 0.1965072E-02 0.1047610E+03 -0.5731 16 Cu+ 0.3579322E-07 0.1560773E-03 0.8087791E+01 -2.4896 17 Pb++ 0.3775415E-08 0.3428846E-03 0.5793748E+02 0.4503 18 Ag+ 0.3538620E-09 0.8770208E-05 0.7715311E+00 -4.4617 19 Ba++ 0.1643862E-06 0.2867035E-04 0.3211240E+01 2.1204 20 HPO4-- 0.9184647E-09 0.3164673E-05 0.2477125E+00 -0.1177 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4268192E+01 -.5829846E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5208662E+02 -.1218443E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2515213E+00 0.2015280E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159446E+01 0.6981128E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.8138972E-01 0.6220460E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1728152E-04 0.6772580E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3293964E-03 0.1985135E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1896535E-04 0.1711298E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.7193607E-02 0.1573147E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254093E+00 0.8509578E-06 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542351E+00 0.3642192E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149476E-02 0.2388815E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1949530E-02 0.3498052E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1548429E-03 0.2447668E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.2844358E-04 0.2692887E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3139643E-05 0.5427858E-05 0.0000000E+00 Chg. balance for solid moles: -.1262E-17 Mass of aqueous solution: 0.121649E+04 g Temperature = 582.00 C Pressure = 1500.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3337E-04 -4.477 0.4543E-02 -2.343 0.1140 0.1533E-02 annite 0.2726E-06 -6.565 0.1395E-03 -3.855 0.3501E-02 0.4206E-04 phlogopite 0.5704E-06 -6.244 0.2380E-03 -3.623 0.5973E-02 0.8535E-04 biotite-Mn 0.7963E-08 -8.099 0.4054E-05 -5.392 0.1017E-03 0.1215E-05 apatite-OH 0.1809E-05 -5.742 0.9088E-03 -3.042 0.2281E-01 0.2888E-03 magnetite 0.4425E-03 -3.354 0.1024 -0.990 2.571 0.1970E-01 quartz 0.6080E-01 -1.216 3.653 0.563 91.66 1.379 barite 0.2693E-04 -4.570 0.6285E-02 -2.202 0.1577 0.1403E-02 chalcopyrite 0.2448E-03 -3.611 0.4491E-01 -1.348 1.127 0.1048E-01 sphalerite 0.3498E-03 -3.456 0.3408E-01 -1.467 0.8552 0.8335E-02 an30ab70 0.5203E-03 -3.284 0.1389 -0.857 3.486 0.5217E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3203E+00 0.3203E+00 1.0000 -0.494 phlogopite 0.6703E+00 0.6703E+00 1.0000 -0.174 biotite-Mn 0.9357E-02 0.9357E-02 1.0000 -2.029 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.985188 g Volume = 1.473462 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.05 -14.05 0.00 0.000 0.00000E+00 24 annite -0.68 -0.68 0.00 0.000 -0.25632E-10 25 phlogopite 3.79 3.79 0.00 0.000 0.00000E+00 26 biotite-Mn 8.44 8.44 0.00 0.000 -0.13902E-10 30 apatite-OH -51.72 -51.72 0.00 0.000 0.00000E+00 106 magnetite 1.25 1.25 0.00 0.000 -0.10426E-10 144 quartz -1.08 -1.08 0.00 0.000 0.00000E+00 237 barite -15.10 -15.10 0.00 0.000 0.00000E+00 240 chalcopyrite -22.56 -22.56 0.00 0.000 0.00000E+00 255 sphalerite -10.67 -10.67 0.00 0.000 0.13902E-10 260 an30ab70 -6.39 -6.39 0.00 0.000 0.17377E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.28 -0.284 0.11117E+04 2.892 2 CO2,gas -9.38 -10.89 -1.51 -0.502 0.58927E+04 1.670 3 CH4,gas 6.92 -3.76 -10.68 -2.671 0.41800E+05 -7.506 4 H2,gas 5.83 1.78 -4.05 -2.312 0.15833E+05 -0.870 5 H2S,gas -7.82 -10.09 -2.28 -1.139 0.89107E+04 0.899 6 CO,gas -3.37 -9.11 -5.74 -1.766 0.22460E+05 -2.564 7 SO3,gas -6.85 -17.22 -10.37 -2.593 0.40578E+05 -7.194 8 O2,gas 16.57 -3.56 -20.14 -13.425 0.78798E+05 -16.961 9 HCl,gas -5.78 -6.98 -1.20 -0.600 0.46918E+04 -1.199 10 acmite 3.71 2.14 -1.57 -0.163 0.61370E+04 12 akimotoite 5.85 1.74 -4.11 -0.822 0.16083E+05 13 akimotoite-Fe 3.81 -0.07 -3.88 -0.776 0.15174E+05 14 albite-high -4.57 -4.71 -0.14 -0.011 0.54242E+03 15 albite -4.55 -4.71 -0.16 -0.013 0.63633E+03 16 almandine -10.12 -11.51 -1.39 -0.070 0.54414E+04 17 pyrope -3.66 -6.08 -2.42 -0.121 0.94635E+04 18 analcite -2.67 -3.63 -0.96 -0.107 0.37677E+04 19 andalusite -12.06 -12.38 -0.32 -0.032 0.12564E+04 20 andradite 11.04 6.49 -4.55 -0.237 0.17822E+05 21 grossular -0.32 -5.05 -4.73 -0.236 0.18495E+05 27 anorthite -9.79 -10.30 -0.50 -0.039 0.19726E+04 28 anthophyllite 13.25 11.10 -2.15 -0.058 0.83996E+04 29 anthophyllite-Fe 0.98 -1.58 -2.57 -0.069 0.10050E+05 31 apatite-OH-zs -49.60 -51.72 -2.12 -0.163 0.82998E+04 32 apatite-Cl-zs -55.59 -58.69 -3.10 -0.259 0.12147E+05 33 aragonite -4.30 -7.72 -3.42 -1.141 0.13399E+05 34 brucite 5.04 2.82 -2.22 -0.444 0.86836E+04 35 calcite -4.39 -7.72 -3.33 -1.109 0.13021E+05 36 carnegieite-low -0.77 -2.54 -1.77 -0.253 0.69299E+04 37 carnegieite-high -0.70 -2.54 -1.84 -0.263 0.72018E+04 38 carpholite-Mg -8.82 -10.64 -1.82 -0.122 0.71350E+04 39 carpholite-Fe -10.14 -12.46 -2.32 -0.155 0.90787E+04 40 celadonite -1.35 -3.46 -2.11 -0.124 0.82548E+04 41 celadonite-Fe -2.72 -5.27 -2.55 -0.150 0.99886E+04 42 chrysotile 8.69 6.30 -2.39 -0.199 0.93609E+04 44 clinochlore 0.84 -0.44 -1.28 -0.040 0.49904E+04 45 daphnite -6.02 -9.50 -3.48 -0.109 0.13610E+05 47 chlorite-Al-free 17.58 12.60 -4.98 -0.208 0.19501E+05 48 chloritoid-Mg -8.41 -9.56 -1.14 -0.076 0.44790E+04 49 chloritoid-Fe -10.29 -11.37 -1.08 -0.072 0.42208E+04 50 chloritoid-Mn -8.13 -9.86 -1.74 -0.116 0.67899E+04 52 coesite -0.80 -1.08 -0.28 -0.093 0.10972E+04 53 cordierite-H -21.88 -22.36 -0.49 -0.017 0.19121E+04 54 cordierite-Fe -24.32 -25.99 -1.67 -0.058 0.65339E+04 55 cordierite-Mn -19.91 -22.97 -3.06 -0.106 0.11974E+05 56 corundum -10.81 -11.30 -0.49 -0.044 0.19134E+04 58 cristobalite -1.03 -1.08 -0.05 -0.017 0.19596E+03 59 cummingtonite 13.30 11.10 -2.21 -0.060 0.86333E+04 61 cymrite-K -2.92 -5.20 -2.28 -0.190 0.89252E+04 63 diaspore -4.90 -5.65 -0.75 -0.125 0.29306E+04 65 diopside 5.12 3.82 -1.30 -0.130 0.50854E+04 66 hedenbergite 3.74 2.01 -1.73 -0.173 0.67755E+04 68 eastonite -8.59 -9.77 -1.18 -0.045 0.46065E+04 69 enstatite 4.32 3.48 -0.84 -0.084 0.32693E+04 70 clinoenstatite-HiP 4.80 3.48 -1.32 -0.132 0.51629E+04 71 clinoenstatite 4.30 3.48 -0.82 -0.082 0.32158E+04 72 protoenstatite 4.45 3.48 -0.97 -0.097 0.37785E+04 73 epidote -6.15 -8.10 -1.95 -0.095 0.76277E+04 74 clinozoisite -11.56 -13.86 -2.31 -0.105 0.90270E+04 75 epidote-Fe 0.93 -2.33 -3.26 -0.169 0.12754E+05 76 fayalite 1.84 0.94 -0.90 -0.128 0.35063E+04 77 ferrosilite 0.84 -0.14 -0.99 -0.099 0.38623E+04 78 forsterite 5.72 4.56 -1.16 -0.165 0.45267E+04 79 gedrite -13.27 -14.98 -1.71 -0.046 0.66730E+04 81 gibbsite -3.30 -5.65 -2.35 -0.336 0.91962E+04 82 glaucophane -0.04 -3.12 -3.08 -0.083 0.12059E+05 83 glaucophane-Fe -3.95 -8.55 -4.60 -0.124 0.17995E+05 84 goethite 0.92 0.12 -0.80 -0.174 0.31428E+04 86 greenalite 3.98 0.86 -3.11 -0.259 0.12177E+05 87 grunerite 1.52 -1.58 -3.10 -0.084 0.12146E+05 88 halite -0.72 -2.79 -2.07 -1.036 0.81085E+04 89 hematite 0.33 0.24 -0.09 -0.010 0.33748E+03 90 heulandite -12.94 -15.72 -2.78 -0.126 0.10871E+05 91 hercynite -9.37 -10.29 -0.91 -0.061 0.35693E+04 94 jadeite -1.98 -3.63 -1.64 -0.164 0.64292E+04 96 kalsilite -1.40 -3.03 -1.63 -0.234 0.63968E+04 97 kaolinite -10.89 -13.47 -2.58 -0.234 0.10087E+05 98 kyanite -11.91 -12.38 -0.47 -0.047 0.18581E+04 100 laumontite -9.13 -12.47 -3.33 -0.222 0.13049E+05 101 lawsonite -7.07 -10.30 -3.24 -0.216 0.12660E+05 102 leucite -3.13 -4.11 -0.98 -0.098 0.38447E+04 104 lizardite 8.88 6.30 -2.58 -0.215 0.10088E+05 105 magnesite -5.30 -8.06 -2.76 -0.921 0.10814E+05 107 minnesotaite 0.57 -1.30 -1.86 -0.110 0.72966E+04 108 minnesotaite-Mg 6.37 4.14 -2.23 -0.131 0.87375E+04 109 magnesioferrite 4.25 3.06 -1.18 -0.097 0.46302E+04 111 manganosite 5.08 2.52 -2.56 -0.640 0.10021E+05 112 margarite -20.13 -21.60 -1.46 -0.059 0.57326E+04 115 microcline -5.14 -5.20 -0.06 -0.004 0.22421E+03 116 monticellite 8.34 4.91 -3.43 -0.490 0.13425E+05 118 mullite-Si -11.33 -12.38 -1.05 -0.105 0.40948E+04 119 muscovite -15.82 -16.50 -0.68 -0.040 0.26505E+04 120 paragonite -15.14 -16.01 -0.87 -0.051 0.33879E+04 121 nepheline -1.06 -2.54 -1.48 -0.211 0.57923E+04 122 osumilite(2) -14.87 -16.69 -1.81 -0.038 0.70987E+04 123 osumilite-Fe -31.27 -33.35 -2.08 -0.043 0.81217E+04 124 pargasite 2.01 -1.63 -3.64 -0.096 0.14244E+05 125 periclase 5.22 2.82 -2.40 -0.600 0.93959E+04 126 periclase-Fe 2.71 1.01 -1.70 -0.424 0.66393E+04 127 perovskite-Al -9.11 -11.30 -2.19 -0.199 0.85691E+04 132 phlogopite-Na 4.65 3.76 -0.89 -0.050 0.34984E+04 134 prehnite -5.17 -8.22 -3.04 -0.179 0.11902E+05 135 prehnite-Fe 0.63 -2.45 -3.08 -0.185 0.12036E+05 138 px-Mg-tschermaks -7.85 -9.56 -1.71 -0.122 0.66727E+04 139 px-Ca-tschermaks -6.86 -9.22 -2.35 -0.168 0.92095E+04 140 pyrite -20.95 -20.96 0.00 -0.001 0.18640E+02 141 pyrrhotite -8.47 -9.08 -0.61 -0.203 0.23804E+04 142 pyrrhotiteFe0.875 -9.19 -9.43 -0.24 -0.087 0.92965E+03 143 pyrophyllite -14.44 -15.63 -1.19 -0.074 0.46636E+04 146 riebeckite 5.77 2.98 -2.79 -0.077 0.10902E+05 147 ringwoodite-Fe 2.82 0.94 -1.88 -0.269 0.73586E+04 148 ringwoodite-Mg 8.82 4.56 -4.26 -0.608 0.16661E+05 149 rhodochrosite -5.18 -8.37 -3.19 -1.063 0.12482E+05 150 rhodonite 2.40 1.44 -0.96 -0.192 0.37626E+04 151 sanidine -4.61 -5.20 -0.59 -0.045 0.22934E+04 152 sapphirine(351) -44.37 -49.10 -4.73 -0.072 0.18508E+05 153 siderite -7.08 -9.88 -2.80 -0.932 0.10946E+05 154 sillimanite -12.03 -12.38 -0.35 -0.035 0.13765E+04 156 spinel -7.26 -8.48 -1.22 -0.081 0.47608E+04 158 staurolite-Fe -100.79 -105.76 -4.97 -0.045 0.19436E+05 162 stilpnomelane-Fe -8.59 -13.06 -4.47 -0.134 0.17510E+05 163 stilpnomelane-Mg -2.06 -4.00 -1.94 -0.058 0.76100E+04 164 stishovite 1.82 -1.08 -2.90 -0.967 0.11349E+05 165 sudoite-Fe -20.12 -23.83 -3.71 -0.120 0.14509E+05 166 sudoite -17.98 -20.20 -2.23 -0.072 0.87214E+04 167 sulfur -10.39 -11.87 -1.48 -0.456 0.57966E+04 168 sylvite -0.62 -3.28 -2.65 -1.327 0.10387E+05 169 talc 4.66 4.14 -0.53 -0.031 0.20646E+04 170 talc-Fe 1.93 -1.30 -3.23 -0.190 0.12650E+05 171 talc-tschermaks -7.43 -8.90 -1.47 -0.087 0.57603E+04 173 tephroite 6.15 3.95 -2.20 -0.314 0.85976E+04 176 topaz-H -9.99 -12.38 -2.40 -0.218 0.93719E+04 177 tremolite 14.28 11.78 -2.50 -0.067 0.97638E+04 179 troilite-low -8.38 -9.08 -0.70 -0.235 0.27580E+04 180 tschermakite -11.47 -14.29 -2.83 -0.076 0.11059E+05 183 wadsleyite-Fe 2.67 0.94 -1.73 -0.247 0.67646E+04 184 wadsleyite-Mg 7.89 4.56 -3.33 -0.475 0.13023E+05 185 wairakite -10.94 -12.47 -1.53 -0.090 0.59681E+04 186 walstromite 4.52 2.08 -2.44 -0.488 0.95456E+04 187 wollastonite 4.11 2.08 -2.03 -0.406 0.79491E+04 188 pseudo-wollastonite 4.23 2.08 -2.14 -0.429 0.83842E+04 189 zoisite -11.62 -13.86 -2.25 -0.102 0.87976E+04 192 beidellite-Ca -15.12 -16.61 -1.49 -0.092 0.58382E+04 193 beidellite-H -15.12 -17.14 -2.02 -0.129 0.78920E+04 194 beidellite-K -14.06 -15.92 -1.85 -0.113 0.72510E+04 195 beidellite-Mg -15.42 -16.67 -1.25 -0.078 0.49030E+04 196 beidellite-Na -14.00 -15.75 -1.75 -0.107 0.68540E+04 197 bornite -52.25 -52.70 -0.46 -0.034 0.17828E+04 199 chalcocite -13.55 -15.07 -1.53 -0.381 0.59679E+04 200 covellite -12.06 -13.47 -1.42 -0.539 0.55392E+04 202 montmorillonite-Ca -11.18 -12.31 -1.13 -0.070 0.44213E+04 203 montmorillonite-K -10.41 -11.61 -1.20 -0.073 0.46960E+04 204 montmorillonite-Mg -11.42 -12.37 -0.95 -0.059 0.37015E+04 205 montmorillonite-Na -10.06 -11.45 -1.39 -0.085 0.54572E+04 206 nontronite-Ca -3.75 -5.08 -1.33 -0.086 0.52039E+04 207 nontronite-H -3.75 -5.60 -1.85 -0.124 0.72261E+04 208 nontronite-K -2.69 -4.38 -1.69 -0.108 0.66052E+04 209 nontronite-Mg -4.00 -5.13 -1.14 -0.074 0.44486E+04 210 nontronite-Na -2.63 -4.22 -1.59 -0.102 0.62241E+04 215 gypsum -11.88 -14.06 -2.18 -0.544 0.85218E+04 232 alabandite -6.19 -7.57 -1.38 -0.461 0.54067E+04 234 anglesite -14.22 -16.77 -2.55 -1.277 0.99923E+04 238 boehmite -4.62 -5.65 -1.03 -0.172 0.40271E+04 242 copper,native 1.76 -1.60 -3.36 -1.169 0.13156E+05 244 ferrous-oxide 1.79 1.01 -0.78 -0.196 0.30650E+04 245 galena -9.36 -9.64 -0.28 -0.095 0.11098E+04 246 silver,native 0.53 -3.57 -4.10 -1.428 0.16063E+05 248 litharge 5.18 0.45 -4.73 -1.184 0.18525E+05 256 wurtzite -9.88 -10.67 -0.79 -0.263 0.30878E+04 257 zincite 1.92 -0.57 -2.49 -0.623 0.97523E+04 258 an20ab80 -5.81 -5.83 -0.01 -0.001 0.54390E+02 259 an25ab75 -6.10 -6.11 0.00 0.000 0.15691E+02 261 tr.625ac.25prg.125 8.62 7.84 -0.78 -0.021 0.30369E+04 Calculations done for 582.0000 Deg. C; 1500.0000 bar Temperature changed by -1.000 degrees to 581.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 28 Loop limit = 500 Temperature = 581.00 C Pressure = 1473.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5507E+02 kg liquid = 0.9921E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9959 Stoichiometric ionic strength = .3300858E+01 Osmotic coef. = 0.0000 True ionic strength = .2179357E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95428E-05 -5.0203 0.23755E-05 -5.6242 0.24893E+00 -0.6039 2 H2O 0.99593E+00 -0.0018 0.99593E+00 -0.0018 3 Cl- 0.18287E+00 -0.7379 0.40451E-01 -1.3931 0.22120E+00 -0.6552 4 SO4-- 0.18482E-03 -3.7332 0.91172E-06 -6.0401 0.49329E-02 -2.3069 5 HCO3- 0.20198E-04 -4.6947 0.48224E-05 -5.3167 0.23875E+00 -0.6221 6 HS- 0.13982E-03 -3.8544 0.31194E-04 -4.5059 0.22310E+00 -0.6515 7 H4SiO4 0.79811E-01 -1.0979 0.79811E-01 -1.0979 0.10000E+01 0.0000 8 Al+++ 0.67143E-17 -17.1730 0.33838E-22 -22.4706 0.50398E-05 -5.2976 9 Ca++ 0.21446E-05 -5.6687 0.85223E-08 -8.0694 0.39739E-02 -2.4008 10 Mg++ 0.12140E-05 -5.9158 0.39531E-08 -8.4031 0.32563E-02 -2.4873 11 Fe++ 0.17689E-07 -7.7523 0.60599E-10 -10.2175 0.34257E-02 -2.4652 12 K+ 0.49669E-01 -1.3039 0.12171E-01 -1.9147 0.24503E+00 -0.6108 13 Na+ 0.16614E+00 -0.7795 0.37242E-01 -1.4290 0.22416E+00 -0.6494 14 Mn++ 0.57813E-06 -6.2380 0.20551E-08 -8.6872 0.35547E-02 -2.4492 15 Zn++ 0.45580E-09 -9.3412 0.15615E-11 -11.8065 0.34257E-02 -2.4652 16 Cu+ 0.33802E-07 -7.4711 0.75564E-08 -8.1217 0.22355E+00 -0.6506 17 Pb++ 0.37059E-08 -8.4311 0.16516E-10 -10.7821 0.44567E-02 -2.3510 18 Ag+ 0.34734E-09 -9.4592 0.83758E-10 -10.0770 0.24114E+00 -0.6177 19 Ba++ 0.15691E-06 -6.8043 0.75161E-09 -9.1240 0.47901E-02 -2.3197 20 HPO4-- 0.93350E-09 -9.0299 0.46282E-11 -11.3346 0.49579E-02 -2.3047 21 HSiO3- 0.18923E-05 -5.7230 0.41859E-06 -6.3782 0.22120E+00 -0.6552 22 Ca(HSiO3)+ 0.10432E-07 -7.9816 0.25792E-08 -8.5885 0.24722E+00 -0.6069 23 Mg(HSiO3)+ 0.13092E-08 -8.8830 0.32367E-09 -9.4899 0.24722E+00 -0.6069 24 NaHSiO3,aq 0.15067E-05 -5.8220 0.15067E-05 -5.8220 0.10000E+01 0.0000 28 AgCl,aq 0.76190E-07 -7.1181 0.76190E-07 -7.1181 0.10000E+01 0.0000 29 AgCl2- 0.49485E-05 -5.3055 0.10946E-05 -5.9607 0.22120E+00 -0.6552 30 AgCl3-2 0.22771E-05 -5.6426 0.10392E-07 -7.9833 0.45637E-02 -2.3407 31 AgCl4-3 0.14623E-05 -5.8350 0.63187E-11 -11.1994 0.43210E-05 -5.3644 34 Ag(HS),aq 0.79690E-09 -9.0986 0.79690E-09 -9.0986 0.10000E+01 0.0000 35 Ag(HS)2- 0.44717E-08 -8.3495 0.98914E-09 -9.0047 0.22120E+00 -0.6552 36 AlO+ 0.10010E-10 -10.9996 0.24747E-11 -11.6065 0.24722E+00 -0.6069 38 HAlO2,aq 0.44269E-08 -8.3539 0.44269E-08 -8.3539 0.10000E+01 0.0000 39 AlO2- 0.17194E-04 -4.7646 0.33143E-05 -5.4796 0.19276E+00 -0.7150 41 Ba(HCO3)+ 0.73065E-06 -6.1363 0.18804E-06 -6.7258 0.25735E+00 -0.5895 42 BaCl+ 0.26031E-04 -4.5845 0.64356E-05 -5.1914 0.24722E+00 -0.6069 43 CH4,aq 0.18287E-08 -8.7379 0.22071E-08 -8.6562 0.12069E+01 0.0817 48 CO,aq 0.71336E-03 -3.1467 0.71336E-03 -3.1467 0.10000E+01 0.0000 49 CO2,aq 0.26764E+01 0.4276 0.32302E+01 0.5092 0.12069E+01 0.0817 50 CO3-2 0.45106E-10 -10.3458 0.20585E-12 -12.6865 0.45637E-02 -2.3407 51 CaCO3,aq 0.15680E-10 -10.8047 0.15680E-10 -10.8047 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.41561E-06 -6.3813 0.10275E-06 -6.9882 0.24722E+00 -0.6069 53 CaCl+ 0.18679E-03 -3.7287 0.46178E-04 -4.3356 0.24722E+00 -0.6069 54 CaCl2,aq 0.12862E-03 -3.8907 0.12862E-03 -3.8907 0.10000E+01 0.0000 55 CaOH+ 0.30906E-06 -6.5100 0.76407E-07 -7.1169 0.24722E+00 -0.6069 56 CaSO4,aq 0.14243E-06 -6.8464 0.14243E-06 -6.8464 0.10000E+01 0.0000 57 HCl,aq 0.14476E-02 -2.8394 0.14476E-02 -2.8394 0.10000E+01 0.0000 66 CuCl,aq 0.29901E-04 -4.5243 0.29901E-04 -4.5243 0.10000E+01 0.0000 67 CuCl2- 0.11881E-03 -3.9251 0.26281E-04 -4.5804 0.22120E+00 -0.6552 68 CuCl3-2 0.29218E-05 -5.5343 0.13334E-07 -7.8750 0.45637E-02 -2.3407 74 FeCl+ 0.47845E-06 -6.3202 0.11828E-06 -6.9271 0.24722E+00 -0.6069 75 FeCl2,aq 0.69555E-02 -2.1577 0.69555E-02 -2.1577 0.10000E+01 0.0000 77 FeO,aq 0.79384E-07 -7.1003 0.79384E-07 -7.1003 0.10000E+01 0.0000 78 FeOH+ 0.36552E-07 -7.4371 0.90365E-08 -8.0440 0.24722E+00 -0.6069 79 HFeO2- 0.10031E-07 -7.9986 0.22189E-08 -8.6539 0.22120E+00 -0.6552 82 FeO2- 0.67137E-08 -8.1730 0.14851E-08 -8.8283 0.22120E+00 -0.6552 83 HFeO2,aq 0.26544E-09 -9.5760 0.26544E-09 -9.5760 0.10000E+01 0.0000 84 H2,aq 0.45177E-02 -2.3451 0.54525E-02 -2.2634 0.12069E+01 0.0817 85 KCl,aq 0.59949E-01 -1.2222 0.59949E-01 -1.2222 0.10000E+01 0.0000 86 KHSO4,aq 0.12819E-01 -1.8922 0.12819E-01 -1.8922 0.10000E+01 0.0000 87 KOH,aq 0.10337E-05 -5.9856 0.10337E-05 -5.9856 0.10000E+01 0.0000 88 KSO4- 0.39633E-02 -2.4019 0.87670E-03 -3.0572 0.22120E+00 -0.6552 90 Mg(HCO3)+ 0.78075E-07 -7.1075 0.19302E-07 -7.7144 0.24722E+00 -0.6069 91 MgCl+ 0.16758E-04 -4.7758 0.41430E-05 -5.3827 0.24722E+00 -0.6069 92 MgOH+ 0.58795E-06 -6.2307 0.14536E-06 -6.8376 0.24722E+00 -0.6069 94 MnO,aq 0.41422E-07 -7.3828 0.41422E-07 -7.3828 0.10000E+01 0.0000 95 MnOH+ 0.15211E-06 -6.8178 0.37605E-07 -7.4247 0.24722E+00 -0.6069 97 HMnO2- 0.23932E-10 -10.6210 0.52938E-11 -11.2762 0.22120E+00 -0.6552 100 MnCl+ 0.11577E-02 -2.9364 0.28622E-03 -3.5433 0.24722E+00 -0.6069 101 MnSO4,aq 0.42824E-07 -7.3683 0.42824E-07 -7.3683 0.10000E+01 0.0000 102 NaCl,aq 0.39248E+00 -0.4062 0.39248E+00 -0.4062 0.10000E+01 0.0000 103 NaOH,aq 0.14704E-05 -5.8326 0.14704E-05 -5.8326 0.10000E+01 0.0000 105 OH- 0.85904E-05 -5.0660 0.16559E-05 -5.7810 0.19276E+00 -0.7150 110 HPO3-2 0.13019E-10 -10.8854 0.59416E-13 -13.2261 0.45637E-02 -2.3407 111 H3PO3,aq 0.10865E-09 -9.9640 0.10865E-09 -9.9640 0.10000E+01 0.0000 112 H2PO3- 0.37977E-08 -8.4205 0.84005E-09 -9.0757 0.22120E+00 -0.6552 113 H3PO4,aq 0.88456E-06 -6.0533 0.88456E-06 -6.0533 0.10000E+01 0.0000 114 H2PO4- 0.16381E-05 -5.7857 0.38148E-06 -6.4185 0.23288E+00 -0.6329 116 H4P2O7,aq 0.65607E-10 -10.1830 0.65607E-10 -10.1830 0.10000E+01 0.0000 117 H3P2O7- 0.10318E-08 -8.9864 0.22824E-09 -9.6416 0.22120E+00 -0.6552 118 H2P2O7-2 0.28694E-06 -6.5422 0.13095E-08 -8.8829 0.45637E-02 -2.3407 119 HP2O7-3 0.13135E-07 -7.8816 0.56758E-13 -13.2460 0.43210E-05 -5.3644 121 PbCl+ 0.21246E-05 -5.6727 0.52526E-06 -6.2796 0.24722E+00 -0.6069 122 PbCl2,aq 0.87818E-04 -4.0564 0.87818E-04 -4.0564 0.10000E+01 0.0000 123 PbCl3- 0.11155E-03 -3.9525 0.24676E-04 -4.6077 0.22120E+00 -0.6552 124 PbCl4-2 0.26929E-04 -4.5698 0.12290E-06 -6.9105 0.45637E-02 -2.3407 125 PbO,aq 0.42192E-08 -8.3748 0.42192E-08 -8.3748 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10399E-03 -3.9830 0.10399E-03 -3.9830 0.10000E+01 0.0000 128 Pb(HS)3- 0.10438E-04 -4.9814 0.23089E-05 -5.6366 0.22120E+00 -0.6552 129 H2S,aq 0.10513E+01 0.0217 0.12688E+01 0.1034 0.12069E+01 0.0817 130 S2-2 0.14746E-07 -7.8313 0.67296E-10 -10.1720 0.45637E-02 -2.3407 131 S3-2 0.15365E-08 -8.8135 0.70121E-11 -11.1542 0.45637E-02 -2.3407 132 S3- 0.18439E-01 -1.7343 0.40787E-02 -2.3895 0.22120E+00 -0.6552 133 S4-2 0.13372E-09 -9.8738 0.61027E-12 -12.2145 0.45637E-02 -2.3407 135 SO2,aq 0.28663E+00 -0.5427 0.28663E+00 -0.5427 0.10000E+01 0.0000 136 SO3-2 0.57997E-09 -9.2366 0.41905E-11 -11.3777 0.72253E-02 -2.1411 137 HSO3- 0.38459E-03 -3.4150 0.85072E-04 -4.0702 0.22120E+00 -0.6552 138 HSO4- 0.11024E-01 -1.9577 0.27977E-02 -2.5532 0.25378E+00 -0.5955 140 S2O3-2 0.52971E-06 -6.2760 0.24174E-08 -8.6166 0.45637E-02 -2.3407 141 HS2O3- 0.61397E-06 -6.2119 0.13581E-06 -6.8671 0.22120E+00 -0.6552 142 H2S2O3,aq 0.25931E-07 -7.5862 0.25931E-07 -7.5862 0.10000E+01 0.0000 150 S4O6-2 0.64628E-09 -9.1896 0.29494E-11 -11.5303 0.45637E-02 -2.3407 152 ZnCl+ 0.48989E-03 -3.3099 0.12111E-03 -3.9168 0.24722E+00 -0.6069 153 ZnCl2,aq 0.12258E-02 -2.9116 0.12258E-02 -2.9116 0.10000E+01 0.0000 154 ZnCl3- 0.15094E-03 -3.8212 0.33388E-04 -4.4764 0.22120E+00 -0.6552 155 ZnO,aq 0.37611E-07 -7.4247 0.37611E-07 -7.4247 0.10000E+01 0.0000 156 ZnOH+ 0.25931E-05 -5.5862 0.64107E-06 -6.1931 0.24722E+00 -0.6069 158 HZnO2- 0.30458E-09 -9.5163 0.67372E-10 -10.1715 0.22120E+00 -0.6552 Charge balance for all species = 0.2551E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9542780E-05 0.4302627E+01 0.3537496E+04 0.0000 2 H2O 0.1000000E+01 0.5250297E+02 0.7715304E+06 0.0000 3 Cl- 0.1828707E+00 0.6566161E+00 0.1898857E+05 4.2312 4 SO4-- 0.1848237E-03 0.2534717E+00 0.1986127E+05 5.2084 5 HCO3- 0.2019841E-04 0.2677133E+01 0.1332447E+06 0.3075 6 HS- 0.1398220E-03 0.1168542E+01 0.3152335E+05 1.1183 7 H4SiO4 0.7981101E-01 0.7981442E-01 0.6257517E+04 -1.0979 8 Al+++ 0.6714275E-17 0.1719821E-04 0.3785097E+00 -5.5978 9 Ca++ 0.2144552E-05 0.3184313E-03 0.1040997E+02 3.1791 10 Mg++ 0.1213985E-05 0.1863929E-04 0.3696389E+00 2.8454 11 Fe++ 0.1768930E-07 0.6956114E-02 0.3168795E+03 1.0310 12 K+ 0.4966947E-01 0.1264015E+00 0.4031613E+04 3.7096 13 Na+ 0.1661387E+00 0.5586212E+00 0.1047563E+05 4.1953 14 Mn++ 0.5781348E-06 0.1158564E-02 0.5191832E+02 2.5613 15 Zn++ 0.4558031E-09 0.1869243E-02 0.9967170E+02 -0.5580 16 Cu+ 0.3380215E-07 0.1516674E-03 0.7860809E+01 -2.4974 17 Pb++ 0.3705915E-08 0.3428647E-03 0.5794543E+02 0.4664 18 Ag+ 0.3473423E-09 0.8769698E-05 0.7716369E+00 -4.4527 19 Ba++ 0.1569104E-06 0.2691906E-04 0.3015676E+01 2.1245 20 HPO4-- 0.9335025E-09 0.3129825E-05 0.2450327E+00 -0.0861 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4268844E+01 -.6482037E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5209074E+02 -.1259615E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2514816E+00 0.2411814E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159367E+01 0.7773033E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.7918775E-01 0.6440657E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1706318E-04 0.6774763E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3159311E-03 0.2119788E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1849294E-04 0.2183712E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.6901497E-02 0.1865256E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254090E+00 0.1087738E-05 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542351E+00 0.3642093E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149468E-02 0.3225254E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1854566E-02 0.4447684E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1504766E-03 0.2491331E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.2670770E-04 0.2866475E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3105251E-05 0.5462249E-05 0.0000000E+00 Chg. balance for solid moles: -.3388E-18 Mass of aqueous solution: 0.121632E+04 g Temperature = 581.00 C Pressure = 1473.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.4679E-04 -4.330 0.6369E-02 -2.196 0.1534 0.2150E-02 annite 0.3491E-06 -6.457 0.1787E-03 -3.748 0.4304E-02 0.5387E-04 phlogopite 0.7279E-06 -6.138 0.3037E-03 -3.517 0.7316E-02 0.1089E-03 biotite-Mn 0.1075E-07 -7.969 0.5474E-05 -5.262 0.1318E-03 0.1641E-05 apatite-OH 0.1821E-05 -5.740 0.9146E-03 -3.039 0.2203E-01 0.2906E-03 magnetite 0.5384E-03 -3.269 0.1246 -0.904 3.002 0.2397E-01 quartz 0.6300E-01 -1.201 3.785 0.578 91.16 1.429 barite 0.2866E-04 -4.543 0.6690E-02 -2.175 0.1611 0.1493E-02 chalcopyrite 0.2491E-03 -3.604 0.4572E-01 -1.340 1.101 0.1067E-01 sphalerite 0.4448E-03 -3.352 0.4333E-01 -1.363 1.044 0.1060E-01 an30ab70 0.5203E-03 -3.284 0.1389 -0.857 3.346 0.5217E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3209E+00 0.3209E+00 1.0000 -0.494 phlogopite 0.6692E+00 0.6692E+00 1.0000 -0.174 biotite-Mn 0.9884E-02 0.9884E-02 1.0000 -2.005 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.152021 g Volume = 1.530866 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.11 -14.11 0.00 0.000 0.69428E-11 24 annite -0.61 -0.61 0.00 0.000 0.55976E-10 25 phlogopite 3.88 3.88 0.00 0.000 0.41657E-10 26 biotite-Mn 8.52 8.52 0.00 0.000 0.27771E-10 30 apatite-OH -51.86 -51.86 0.00 0.000 0.00000E+00 106 magnetite 1.30 1.30 0.00 0.000 -0.23432E-10 144 quartz -1.09 -1.09 0.00 0.000 0.00000E+00 237 barite -15.16 -15.16 0.00 0.000 0.00000E+00 240 chalcopyrite -22.62 -22.62 0.00 0.000 0.00000E+00 255 sphalerite -10.69 -10.69 0.00 0.000 -0.13886E-10 260 an30ab70 -6.35 -6.35 0.00 0.000 0.10414E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.28 -0.283 0.11076E+04 2.885 2 CO2,gas -9.42 -10.94 -1.52 -0.506 0.59323E+04 1.650 3 CH4,gas 6.92 -3.78 -10.70 -2.675 0.41824E+05 -7.533 4 H2,gas 5.83 1.79 -4.05 -2.313 0.15817E+05 -0.879 5 H2S,gas -7.85 -10.13 -2.28 -1.140 0.89108E+04 0.888 6 CO,gas -3.39 -9.15 -5.76 -1.771 0.22496E+05 -2.588 7 SO3,gas -6.90 -17.29 -10.39 -2.596 0.40593E+05 -7.218 8 O2,gas 16.58 -3.58 -20.16 -13.441 0.78801E+05 -16.993 9 HCl,gas -5.80 -7.02 -1.22 -0.608 0.47538E+04 -1.216 10 acmite 3.70 2.14 -1.56 -0.162 0.61032E+04 12 akimotoite 5.87 1.75 -4.12 -0.824 0.16097E+05 13 akimotoite-Fe 3.82 -0.07 -3.88 -0.777 0.15180E+05 14 albite-high -4.55 -4.69 -0.13 -0.010 0.52735E+03 15 albite -4.53 -4.69 -0.16 -0.012 0.61745E+03 16 almandine -9.99 -11.40 -1.41 -0.070 0.55010E+04 17 pyrope -3.51 -5.95 -2.44 -0.122 0.95491E+04 18 analcite -2.64 -3.60 -0.96 -0.107 0.37543E+04 19 andalusite -11.96 -12.30 -0.33 -0.033 0.12950E+04 20 andradite 11.08 6.52 -4.56 -0.237 0.17830E+05 21 grossular -0.21 -4.95 -4.74 -0.237 0.18542E+05 27 anorthite -9.70 -10.21 -0.51 -0.040 0.20121E+04 28 anthophyllite 13.32 11.15 -2.17 -0.059 0.84784E+04 29 anthophyllite-Fe 1.02 -1.55 -2.58 -0.070 0.10066E+05 31 apatite-OH-zs -49.73 -51.86 -2.12 -0.163 0.83027E+04 32 apatite-Cl-zs -55.76 -58.87 -3.11 -0.259 0.12165E+05 33 aragonite -4.32 -7.76 -3.44 -1.146 0.13437E+05 34 brucite 5.07 2.84 -2.22 -0.445 0.86950E+04 35 calcite -4.42 -7.76 -3.34 -1.114 0.13057E+05 36 carnegieite-low -0.73 -2.50 -1.77 -0.253 0.69102E+04 37 carnegieite-high -0.66 -2.50 -1.84 -0.263 0.71844E+04 38 carpholite-Mg -8.71 -10.55 -1.84 -0.123 0.71841E+04 39 carpholite-Fe -10.03 -12.36 -2.33 -0.156 0.91209E+04 40 celadonite -1.32 -3.43 -2.11 -0.124 0.82434E+04 41 celadonite-Fe -2.69 -5.24 -2.55 -0.150 0.99718E+04 42 chrysotile 8.74 6.34 -2.40 -0.200 0.93884E+04 44 clinochlore 1.02 -0.27 -1.30 -0.041 0.50693E+04 45 daphnite -5.85 -9.35 -3.49 -0.109 0.13654E+05 48 chloritoid-Mg -8.30 -9.45 -1.16 -0.077 0.45276E+04 49 chloritoid-Fe -10.18 -11.27 -1.09 -0.073 0.42586E+04 50 chloritoid-Mn -8.02 -9.74 -1.72 -0.115 0.67307E+04 52 coesite -0.81 -1.09 -0.28 -0.094 0.10985E+04 53 cordierite-H -21.67 -22.19 -0.51 -0.018 0.20119E+04 54 cordierite-Fe -24.13 -25.82 -1.69 -0.058 0.66002E+04 55 cordierite-Mn -19.72 -22.75 -3.03 -0.104 0.11844E+05 56 corundum -10.70 -11.20 -0.50 -0.045 0.19535E+04 58 cristobalite -1.04 -1.09 -0.05 -0.017 0.19439E+03 59 cummingtonite 13.38 11.15 -2.23 -0.060 0.87137E+04 61 cymrite-K -2.90 -5.18 -2.28 -0.190 0.89103E+04 63 diaspore -4.85 -5.60 -0.75 -0.126 0.29485E+04 65 diopside 5.14 3.83 -1.31 -0.131 0.51012E+04 66 hedenbergite 3.75 2.02 -1.74 -0.174 0.67839E+04 68 eastonite -8.41 -9.60 -1.19 -0.046 0.46400E+04 69 enstatite 4.34 3.50 -0.84 -0.084 0.32941E+04 70 clinoenstatite-HiP 4.83 3.50 -1.33 -0.133 0.51885E+04 71 clinoenstatite 4.33 3.50 -0.83 -0.083 0.32400E+04 72 protoenstatite 4.47 3.50 -0.97 -0.097 0.38029E+04 73 epidote -6.03 -8.00 -1.96 -0.095 0.76745E+04 74 clinozoisite -11.40 -13.73 -2.33 -0.106 0.90944E+04 75 epidote-Fe 1.01 -2.26 -3.27 -0.170 0.12777E+05 76 fayalite 1.86 0.96 -0.90 -0.128 0.35126E+04 77 ferrosilite 0.86 -0.13 -0.99 -0.099 0.38703E+04 78 forsterite 5.76 4.59 -1.16 -0.166 0.45487E+04 79 gedrite -13.01 -14.75 -1.74 -0.047 0.68085E+04 81 gibbsite -3.25 -5.60 -2.36 -0.337 0.92152E+04 82 glaucophane 0.05 -3.04 -3.08 -0.083 0.12054E+05 83 glaucophane-Fe -3.88 -8.48 -4.60 -0.124 0.17966E+05 84 goethite 0.94 0.13 -0.80 -0.174 0.31425E+04 86 greenalite 4.01 0.90 -3.12 -0.260 0.12177E+05 87 grunerite 1.56 -1.55 -3.11 -0.084 0.12164E+05 88 halite -0.75 -2.82 -2.07 -1.035 0.80889E+04 89 hematite 0.35 0.27 -0.09 -0.010 0.33480E+03 90 heulandite -12.90 -15.70 -2.80 -0.127 0.10938E+05 91 hercynite -9.25 -10.17 -0.92 -0.062 0.36122E+04 94 jadeite -1.95 -3.59 -1.64 -0.164 0.64141E+04 96 kalsilite -1.36 -2.99 -1.63 -0.233 0.63723E+04 97 kaolinite -10.81 -13.39 -2.59 -0.235 0.10115E+05 98 kyanite -11.81 -12.30 -0.49 -0.049 0.18993E+04 100 laumontite -9.06 -12.41 -3.35 -0.223 0.13097E+05 101 lawsonite -6.97 -10.22 -3.25 -0.217 0.12705E+05 102 leucite -3.10 -4.08 -0.98 -0.098 0.38203E+04 104 lizardite 8.93 6.34 -2.59 -0.216 0.10112E+05 105 magnesite -5.32 -8.10 -2.78 -0.926 0.10859E+05 107 minnesotaite 0.58 -1.29 -1.87 -0.110 0.72967E+04 108 minnesotaite-Mg 6.39 4.15 -2.24 -0.132 0.87623E+04 109 magnesioferrite 4.30 3.11 -1.19 -0.097 0.46384E+04 111 manganosite 5.10 2.56 -2.54 -0.635 0.99260E+04 112 margarite -19.93 -21.42 -1.49 -0.059 0.58128E+04 115 microcline -5.12 -5.18 -0.05 -0.004 0.19631E+03 116 monticellite 8.36 4.93 -3.44 -0.491 0.13437E+05 118 mullite-Si -11.24 -12.30 -1.06 -0.106 0.41364E+04 119 muscovite -15.70 -16.38 -0.68 -0.040 0.26663E+04 120 paragonite -15.02 -15.89 -0.87 -0.051 0.34106E+04 121 nepheline -1.02 -2.50 -1.48 -0.211 0.57727E+04 122 osumilite(2) -14.77 -16.60 -1.83 -0.038 0.71368E+04 123 osumilite-Fe -31.09 -33.18 -2.09 -0.044 0.81697E+04 124 pargasite 2.22 -1.45 -3.67 -0.096 0.14328E+05 125 periclase 5.25 2.84 -2.41 -0.602 0.94065E+04 126 periclase-Fe 2.73 1.03 -1.70 -0.425 0.66430E+04 127 perovskite-Al -9.00 -11.20 -2.20 -0.200 0.86095E+04 132 phlogopite-Na 4.74 3.84 -0.90 -0.050 0.35116E+04 134 prehnite -5.07 -8.13 -3.06 -0.180 0.11946E+05 135 prehnite-Fe 0.69 -2.40 -3.08 -0.186 0.12056E+05 138 px-Mg-tschermaks -7.73 -9.45 -1.72 -0.123 0.67260E+04 139 px-Ca-tschermaks -6.75 -9.12 -2.37 -0.169 0.92530E+04 140 pyrite -21.01 -21.02 0.00 -0.001 0.14048E+02 141 pyrrhotite -8.49 -9.10 -0.61 -0.203 0.23818E+04 142 pyrrhotiteFe0.875 -9.21 -9.45 -0.24 -0.088 0.93116E+03 143 pyrophyllite -14.38 -15.58 -1.20 -0.075 0.47020E+04 146 riebeckite 5.76 2.99 -2.77 -0.076 0.10835E+05 147 ringwoodite-Fe 2.85 0.96 -1.88 -0.269 0.73642E+04 148 ringwoodite-Mg 8.86 4.59 -4.27 -0.610 0.16684E+05 149 rhodochrosite -5.20 -8.38 -3.18 -1.059 0.12421E+05 150 rhodonite 2.40 1.47 -0.94 -0.188 0.36683E+04 151 sanidine -4.60 -5.18 -0.58 -0.045 0.22653E+04 152 sapphirine(351) -43.77 -48.57 -4.80 -0.073 0.18744E+05 153 siderite -7.10 -9.91 -2.81 -0.937 0.10982E+05 154 sillimanite -11.93 -12.30 -0.36 -0.036 0.14166E+04 156 spinel -7.13 -8.36 -1.23 -0.082 0.48103E+04 162 stilpnomelane-Fe -8.48 -12.97 -4.49 -0.134 0.17541E+05 163 stilpnomelane-Mg -1.93 -3.89 -1.97 -0.059 0.76974E+04 164 stishovite 1.81 -1.09 -2.90 -0.968 0.11350E+05 165 sudoite-Fe -19.90 -23.63 -3.74 -0.121 0.14610E+05 166 sudoite -17.74 -20.00 -2.26 -0.073 0.88366E+04 167 sulfur -10.44 -11.92 -1.48 -0.456 0.57963E+04 168 sylvite -0.66 -3.31 -2.65 -1.325 0.10358E+05 169 talc 4.69 4.15 -0.54 -0.031 0.20921E+04 170 talc-Fe 1.95 -1.29 -3.24 -0.190 0.12654E+05 171 talc-tschermaks -7.31 -8.80 -1.49 -0.088 0.58162E+04 173 tephroite 6.18 4.02 -2.15 -0.307 0.84067E+04 176 topaz-H -9.89 -12.30 -2.41 -0.219 0.94104E+04 177 tremolite 14.33 11.82 -2.51 -0.068 0.98228E+04 179 troilite-low -8.39 -9.10 -0.71 -0.235 0.27580E+04 180 tschermakite -11.23 -14.08 -2.86 -0.077 0.11171E+05 183 wadsleyite-Fe 2.70 0.96 -1.73 -0.248 0.67717E+04 184 wadsleyite-Mg 7.93 4.59 -3.34 -0.477 0.13047E+05 185 wairakite -10.87 -12.40 -1.54 -0.090 0.60032E+04 186 walstromite 4.53 2.08 -2.44 -0.489 0.95488E+04 187 wollastonite 4.12 2.08 -2.03 -0.407 0.79507E+04 188 pseudo-wollastonite 4.23 2.08 -2.15 -0.429 0.83869E+04 189 zoisite -11.46 -13.73 -2.27 -0.103 0.88669E+04 192 beidellite-Ca -15.04 -16.54 -1.51 -0.093 0.58827E+04 193 beidellite-H -15.04 -17.07 -2.03 -0.130 0.79355E+04 194 beidellite-K -13.98 -15.84 -1.86 -0.114 0.72806E+04 195 beidellite-Mg -15.33 -16.60 -1.27 -0.078 0.49527E+04 196 beidellite-Na -13.92 -15.68 -1.76 -0.108 0.68859E+04 197 bornite -52.41 -52.87 -0.46 -0.034 0.17903E+04 199 chalcocite -13.60 -15.13 -1.53 -0.382 0.59693E+04 200 covellite -12.11 -13.52 -1.42 -0.540 0.55353E+04 202 montmorillonite-Ca -11.13 -12.27 -1.14 -0.071 0.44560E+04 203 montmorillonite-K -10.36 -11.57 -1.21 -0.074 0.47186E+04 204 montmorillonite-Mg -11.37 -12.32 -0.96 -0.059 0.37367E+04 205 montmorillonite-Na -10.01 -11.41 -1.40 -0.086 0.54769E+04 206 nontronite-Ca -3.74 -5.07 -1.33 -0.086 0.52092E+04 207 nontronite-H -3.75 -5.60 -1.85 -0.124 0.72307E+04 208 nontronite-K -2.69 -4.37 -1.69 -0.108 0.65954E+04 209 nontronite-Mg -3.99 -5.13 -1.14 -0.074 0.44555E+04 210 nontronite-Na -2.62 -4.21 -1.59 -0.102 0.62166E+04 215 gypsum -11.93 -14.11 -2.18 -0.546 0.85322E+04 232 alabandite -6.21 -7.57 -1.36 -0.453 0.53120E+04 234 anglesite -14.28 -16.82 -2.54 -1.272 0.99395E+04 238 boehmite -4.57 -5.60 -1.04 -0.173 0.40461E+04 242 copper,native 1.76 -1.60 -3.36 -1.170 0.13151E+05 244 ferrous-oxide 1.81 1.03 -0.79 -0.196 0.30700E+04 245 galena -9.39 -9.66 -0.27 -0.090 0.10535E+04 246 silver,native 0.53 -3.56 -4.09 -1.422 0.15980E+05 248 litharge 5.19 0.46 -4.73 -1.181 0.18468E+05 256 wurtzite -9.90 -10.69 -0.79 -0.263 0.30879E+04 257 zincite 1.94 -0.56 -2.50 -0.624 0.97544E+04 258 an20ab80 -5.78 -5.79 -0.01 -0.001 0.48229E+02 259 an25ab75 -6.07 -6.07 0.00 0.000 0.12499E+02 261 tr.625ac.25prg.125 8.68 7.89 -0.79 -0.021 0.31002E+04 Calculations done for 581.0000 Deg. C; 1473.0000 bar Temperature changed by -1.000 degrees to 580.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 28 Loop limit = 500 Temperature = 580.00 C Pressure = 1447.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5508E+02 kg liquid = 0.9922E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9960 Stoichiometric ionic strength = .3299658E+01 Osmotic coef. = 0.0000 True ionic strength = .2135344E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91430E-05 -5.0389 0.22465E-05 -5.6485 0.24571E+00 -0.6096 2 H2O 0.99599E+00 -0.0017 0.99599E+00 -0.0017 3 Cl- 0.17928E+00 -0.7465 0.39009E-01 -1.4088 0.21759E+00 -0.6624 4 SO4-- 0.18776E-03 -3.7264 0.87723E-06 -6.0569 0.46720E-02 -2.3305 5 HCO3- 0.19320E-04 -4.7140 0.45377E-05 -5.3432 0.23487E+00 -0.6292 6 HS- 0.13856E-03 -3.8583 0.30409E-04 -4.5170 0.21945E+00 -0.6587 7 H4SiO4 0.77673E-01 -1.1097 0.77673E-01 -1.1097 0.10000E+01 0.0000 8 Al+++ 0.71901E-17 -17.1433 0.32073E-22 -22.4939 0.44607E-05 -5.3506 9 Ca++ 0.20843E-05 -5.6810 0.78376E-08 -8.1058 0.37603E-02 -2.4248 10 Mg++ 0.12054E-05 -5.9189 0.37128E-08 -8.4303 0.30800E-02 -2.5114 11 Fe++ 0.17462E-07 -7.7579 0.56585E-10 -10.2473 0.32405E-02 -2.4894 12 K+ 0.48807E-01 -1.3115 0.11765E-01 -1.9294 0.24104E+00 -0.6179 13 Na+ 0.16264E+00 -0.7888 0.35860E-01 -1.4454 0.22048E+00 -0.6566 14 Mn++ 0.60193E-06 -6.2205 0.20241E-08 -8.6938 0.33628E-02 -2.4733 15 Zn++ 0.44669E-09 -9.3500 0.14475E-11 -11.8394 0.32405E-02 -2.4894 16 Cu+ 0.31920E-07 -7.4959 0.70185E-08 -8.1538 0.21988E+00 -0.6578 17 Pb++ 0.36381E-08 -8.4391 0.15347E-10 -10.8140 0.42184E-02 -2.3749 18 Ag+ 0.34138E-09 -9.4668 0.80978E-10 -10.0916 0.23721E+00 -0.6249 19 Ba++ 0.14969E-06 -6.8248 0.67882E-09 -9.1682 0.45348E-02 -2.3434 20 HPO4-- 0.94940E-09 -9.0226 0.44581E-11 -11.3508 0.46957E-02 -2.3283 21 HSiO3- 0.18618E-05 -5.7301 0.40511E-06 -6.3924 0.21759E+00 -0.6624 22 Ca(HSiO3)+ 0.99633E-08 -8.0016 0.24231E-08 -8.6156 0.24321E+00 -0.6140 23 Mg(HSiO3)+ 0.12883E-08 -8.8900 0.31332E-09 -9.5040 0.24321E+00 -0.6140 24 NaHSiO3,aq 0.15283E-05 -5.8158 0.15283E-05 -5.8158 0.10000E+01 0.0000 28 AgCl,aq 0.77410E-07 -7.1112 0.77410E-07 -7.1112 0.10000E+01 0.0000 29 AgCl2- 0.49476E-05 -5.3056 0.10765E-05 -5.9680 0.21759E+00 -0.6624 30 AgCl3-2 0.22485E-05 -5.6481 0.97166E-08 -8.0125 0.43214E-02 -2.3644 31 AgCl4-3 0.14900E-05 -5.8268 0.57026E-11 -11.2439 0.38272E-05 -5.4171 34 Ag(HS),aq 0.82811E-09 -9.0819 0.82811E-09 -9.0819 0.10000E+01 0.0000 35 Ag(HS)2- 0.45562E-08 -8.3414 0.99136E-09 -9.0038 0.21759E+00 -0.6624 36 AlO+ 0.10019E-10 -10.9992 0.24366E-11 -11.6132 0.24321E+00 -0.6140 38 HAlO2,aq 0.44244E-08 -8.3541 0.44244E-08 -8.3541 0.10000E+01 0.0000 39 AlO2- 0.16979E-04 -4.7701 0.32194E-05 -5.4922 0.18961E+00 -0.7221 41 Ba(HCO3)+ 0.68146E-06 -6.1666 0.17254E-06 -6.7631 0.25320E+00 -0.5965 42 BaCl+ 0.24437E-04 -4.6120 0.59432E-05 -5.2260 0.24321E+00 -0.6140 43 CH4,aq 0.18150E-08 -8.7411 0.21890E-08 -8.6597 0.12061E+01 0.0814 48 CO,aq 0.70282E-03 -3.1532 0.70282E-03 -3.1532 0.10000E+01 0.0000 49 CO2,aq 0.26763E+01 0.4275 0.32278E+01 0.5089 0.12061E+01 0.0814 50 CO3-2 0.44776E-10 -10.3489 0.19350E-12 -12.7133 0.43214E-02 -2.3644 51 CaCO3,aq 0.15243E-10 -10.8169 0.15243E-10 -10.8169 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.38268E-06 -6.4172 0.93070E-07 -7.0312 0.24321E+00 -0.6140 53 CaCl+ 0.17727E-03 -3.7514 0.43112E-04 -4.3654 0.24321E+00 -0.6140 54 CaCl2,aq 0.12519E-03 -3.9024 0.12519E-03 -3.9024 0.10000E+01 0.0000 55 CaOH+ 0.29621E-06 -6.5284 0.72039E-07 -7.1424 0.24321E+00 -0.6140 56 CaSO4,aq 0.14316E-06 -6.8442 0.14316E-06 -6.8442 0.10000E+01 0.0000 57 HCl,aq 0.15140E-02 -2.8199 0.15140E-02 -2.8199 0.10000E+01 0.0000 66 CuCl,aq 0.29196E-04 -4.5347 0.29196E-04 -4.5347 0.10000E+01 0.0000 67 CuCl2- 0.11524E-03 -3.9384 0.25074E-04 -4.6008 0.21759E+00 -0.6624 68 CuCl3-2 0.28007E-05 -5.5527 0.12103E-07 -7.9171 0.43214E-02 -2.3644 74 FeCl+ 0.46080E-06 -6.3365 0.11207E-06 -6.9505 0.24321E+00 -0.6140 75 FeCl2,aq 0.66716E-02 -2.1758 0.66716E-02 -2.1758 0.10000E+01 0.0000 77 FeO,aq 0.78735E-07 -7.1038 0.78735E-07 -7.1038 0.10000E+01 0.0000 78 FeOH+ 0.35452E-07 -7.4504 0.86221E-08 -8.0644 0.24321E+00 -0.6140 79 HFeO2- 0.99187E-08 -8.0035 0.21582E-08 -8.6659 0.21759E+00 -0.6624 82 FeO2- 0.66101E-08 -8.1798 0.14383E-08 -8.8422 0.21759E+00 -0.6624 83 HFeO2,aq 0.26799E-09 -9.5719 0.26799E-09 -9.5719 0.10000E+01 0.0000 84 H2,aq 0.45380E-02 -2.3431 0.54731E-02 -2.2618 0.12061E+01 0.0814 85 KCl,aq 0.60729E-01 -1.2166 0.60729E-01 -1.2166 0.10000E+01 0.0000 86 KHSO4,aq 0.12853E-01 -1.8910 0.12853E-01 -1.8910 0.10000E+01 0.0000 87 KOH,aq 0.10541E-05 -5.9771 0.10541E-05 -5.9771 0.10000E+01 0.0000 88 KSO4- 0.40049E-02 -2.3974 0.87142E-03 -3.0598 0.21759E+00 -0.6624 90 Mg(HCO3)+ 0.72649E-07 -7.1388 0.17669E-07 -7.7528 0.24321E+00 -0.6140 91 MgCl+ 0.16324E-04 -4.7872 0.39701E-05 -5.4012 0.24321E+00 -0.6140 92 MgOH+ 0.57714E-06 -6.2387 0.14036E-06 -6.8527 0.24321E+00 -0.6140 94 MnO,aq 0.43559E-07 -7.3609 0.43559E-07 -7.3609 0.10000E+01 0.0000 95 MnOH+ 0.15467E-06 -6.8106 0.37616E-07 -7.4246 0.24321E+00 -0.6140 97 HMnO2- 0.24900E-10 -10.6038 0.54179E-11 -11.2662 0.21759E+00 -0.6624 100 MnCl+ 0.11576E-02 -2.9364 0.28155E-03 -3.5505 0.24321E+00 -0.6140 101 MnSO4,aq 0.45755E-07 -7.3396 0.45755E-07 -7.3396 0.10000E+01 0.0000 102 NaCl,aq 0.39594E+00 -0.4024 0.39594E+00 -0.4024 0.10000E+01 0.0000 103 NaOH,aq 0.14927E-05 -5.8260 0.14927E-05 -5.8260 0.10000E+01 0.0000 105 OH- 0.85420E-05 -5.0684 0.16197E-05 -5.7906 0.18961E+00 -0.7221 110 HPO3-2 0.12830E-10 -10.8918 0.55444E-13 -13.2561 0.43214E-02 -2.3644 111 H3PO3,aq 0.10830E-09 -9.9654 0.10830E-09 -9.9654 0.10000E+01 0.0000 112 H2PO3- 0.36393E-08 -8.4390 0.79186E-09 -9.1014 0.21759E+00 -0.6624 113 H3PO4,aq 0.89605E-06 -6.0477 0.89605E-06 -6.0477 0.10000E+01 0.0000 114 H2PO4- 0.16086E-05 -5.7936 0.36852E-06 -6.4335 0.22909E+00 -0.6400 116 H4P2O7,aq 0.67883E-10 -10.1682 0.67883E-10 -10.1682 0.10000E+01 0.0000 117 H3P2O7- 0.10064E-08 -8.9972 0.21899E-09 -9.6596 0.21759E+00 -0.6624 118 H2P2O7-2 0.27967E-06 -6.5534 0.12085E-08 -8.9177 0.43214E-02 -2.3644 119 HP2O7-3 0.13604E-07 -7.8663 0.52065E-13 -13.2835 0.38272E-05 -5.4171 121 PbCl+ 0.20552E-05 -5.6871 0.49985E-06 -6.3012 0.24321E+00 -0.6140 122 PbCl2,aq 0.87609E-04 -4.0575 0.87609E-04 -4.0575 0.10000E+01 0.0000 123 PbCl3- 0.11108E-03 -3.9544 0.24170E-04 -4.6167 0.21759E+00 -0.6624 124 PbCl4-2 0.26434E-04 -4.5778 0.11423E-06 -6.9422 0.43214E-02 -2.3644 125 PbO,aq 0.43379E-08 -8.3627 0.43379E-08 -8.3627 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10500E-03 -3.9788 0.10500E-03 -3.9788 0.10000E+01 0.0000 128 Pb(HS)3- 0.10656E-04 -4.9724 0.23187E-05 -5.6348 0.21759E+00 -0.6624 129 H2S,aq 0.10525E+01 0.0222 0.12694E+01 0.1036 0.12061E+01 0.0814 130 S2-2 0.14683E-07 -7.8332 0.63450E-10 -10.1976 0.43214E-02 -2.3644 131 S3-2 0.15157E-08 -8.8194 0.65498E-11 -11.1838 0.43214E-02 -2.3644 132 S3- 0.17822E-01 -1.7490 0.38779E-02 -2.4114 0.21759E+00 -0.6624 133 S4-2 0.13084E-09 -9.8833 0.56540E-12 -12.2476 0.43214E-02 -2.3644 135 SO2,aq 0.28727E+00 -0.5417 0.28727E+00 -0.5417 0.10000E+01 0.0000 136 SO3-2 0.58427E-09 -9.2334 0.40038E-11 -11.3975 0.68527E-02 -2.1641 137 HSO3- 0.37504E-03 -3.4259 0.81604E-04 -4.0883 0.21759E+00 -0.6624 138 HSO4- 0.10806E-01 -1.9663 0.26983E-02 -2.5689 0.24969E+00 -0.6026 140 S2O3-2 0.52910E-06 -6.2765 0.22864E-08 -8.6408 0.43214E-02 -2.3644 141 HS2O3- 0.59439E-06 -6.2259 0.12933E-06 -6.8883 0.21759E+00 -0.6624 142 H2S2O3,aq 0.26179E-07 -7.5821 0.26179E-07 -7.5821 0.10000E+01 0.0000 150 S4O6-2 0.62892E-09 -9.2014 0.27178E-11 -11.5658 0.43214E-02 -2.3644 152 ZnCl+ 0.45697E-03 -3.3401 0.11114E-03 -3.9541 0.24321E+00 -0.6140 153 ZnCl2,aq 0.11779E-02 -2.9289 0.11779E-02 -2.9289 0.10000E+01 0.0000 154 ZnCl3- 0.14090E-03 -3.8511 0.30659E-04 -4.5134 0.21759E+00 -0.6624 155 ZnO,aq 0.37087E-07 -7.4308 0.37087E-07 -7.4308 0.10000E+01 0.0000 156 ZnOH+ 0.24567E-05 -5.6096 0.59749E-06 -6.2237 0.24321E+00 -0.6140 158 HZnO2- 0.29985E-09 -9.5231 0.65244E-10 -10.1855 0.21759E+00 -0.6624 Charge balance for all species = 0.2551E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9143028E-05 0.4303019E+01 0.3538482E+04 0.0000 2 H2O 0.1000000E+01 0.5250404E+02 0.7716907E+06 0.0000 3 Cl- 0.1792809E+00 0.6565796E+00 0.1899107E+05 4.2397 4 SO4-- 0.1877629E-03 0.2534192E+00 0.1986088E+05 5.2401 5 HCO3- 0.1931979E-04 0.2676984E+01 0.1332622E+06 0.3053 6 HS- 0.1385640E-03 0.1168401E+01 0.3152546E+05 1.1315 7 H4SiO4 0.7767333E-01 0.7767673E-01 0.6091062E+04 -1.1097 8 Al+++ 0.7190076E-17 0.1698329E-04 0.3738496E+00 -5.5484 9 Ca++ 0.2084322E-05 0.3053669E-03 0.9984746E+01 3.1912 10 Mg++ 0.1205434E-05 0.1818054E-04 0.3606090E+00 2.8667 11 Fe++ 0.1746159E-07 0.6672246E-02 0.3040052E+03 1.0497 12 K+ 0.4880666E-01 0.1263942E+00 0.4032137E+04 3.7191 13 Na+ 0.1626432E+00 0.5585901E+00 0.1047701E+05 4.2031 14 Mn++ 0.6019282E-06 0.1158491E-02 0.5192476E+02 2.6032 15 Zn++ 0.4466933E-09 0.1778217E-02 0.9483581E+02 -0.5424 16 Cu+ 0.3192011E-07 0.1472665E-03 0.7634143E+01 -2.5053 17 Pb++ 0.3638143E-08 0.3428456E-03 0.5795307E+02 0.4830 18 Ag+ 0.3413809E-09 0.8769210E-05 0.7717386E+00 -4.4431 19 Ba++ 0.1496917E-06 0.2526784E-04 0.2831224E+01 2.1287 20 HPO4-- 0.9493959E-09 0.3098047E-05 0.2425902E+00 -0.0539 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4269471E+01 -.7108647E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5209470E+02 -.1299189E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2514435E+00 0.2793170E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159292E+01 0.8526302E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.7707114E-01 0.6652319E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1685088E-04 0.6776886E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.3029861E-03 0.2249238E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1803880E-04 0.2637852E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.6620227E-02 0.2146527E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254088E+00 0.1316318E-05 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542351E+00 0.3642005E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149459E-02 0.4122555E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1764354E-02 0.5349811E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1461184E-03 0.2534914E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.2507084E-04 0.3030161E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3073894E-05 0.5493607E-05 0.0000000E+00 Chg. balance for solid moles: 0.1423E-18 Mass of aqueous solution: 0.121616E+04 g Temperature = 580.00 C Pressure = 1447.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.5968E-04 -4.224 0.8125E-02 -2.090 0.1884 0.2742E-02 annite 0.4233E-06 -6.373 0.2167E-03 -3.664 0.5025E-02 0.6532E-04 phlogopite 0.8793E-06 -6.056 0.3669E-03 -3.435 0.8509E-02 0.1316E-03 biotite-Mn 0.1374E-07 -7.862 0.6997E-05 -5.155 0.1623E-03 0.2097E-05 apatite-OH 0.1831E-05 -5.737 0.9198E-03 -3.036 0.2133E-01 0.2923E-03 magnetite 0.6306E-03 -3.200 0.1460 -0.836 3.385 0.2807E-01 quartz 0.6511E-01 -1.186 3.912 0.592 90.72 1.477 barite 0.3030E-04 -4.519 0.7072E-02 -2.150 0.1640 0.1579E-02 chalcopyrite 0.2535E-03 -3.596 0.4652E-01 -1.332 1.079 0.1086E-01 sphalerite 0.5350E-03 -3.272 0.5212E-01 -1.283 1.209 0.1275E-01 an30ab70 0.5203E-03 -3.284 0.1389 -0.857 3.222 0.5217E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3216E+00 0.3216E+00 1.0000 -0.493 phlogopite 0.6680E+00 0.6680E+00 1.0000 -0.175 biotite-Mn 0.1044E-01 0.1044E-01 1.0000 -1.981 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.312331 g Volume = 1.586030 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.16 -14.16 0.00 0.000 0.00000E+00 24 annite -0.53 -0.53 0.00 0.000 0.39008E-11 25 phlogopite 3.97 3.97 0.00 0.000 -0.10402E-10 26 biotite-Mn 8.60 8.60 0.00 0.000 -0.13869E-10 30 apatite-OH -51.99 -51.99 0.00 0.000 0.00000E+00 106 magnetite 1.35 1.35 0.00 0.000 -0.18204E-10 144 quartz -1.11 -1.11 0.00 0.000 0.00000E+00 237 barite -15.23 -15.23 0.00 0.000 0.00000E+00 240 chalcopyrite -22.68 -22.68 0.00 0.000 0.13869E-10 255 sphalerite -10.71 -10.71 0.00 0.000 0.00000E+00 260 an30ab70 -6.30 -6.30 0.00 0.000 0.34673E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.28 -0.283 0.11035E+04 2.878 2 CO2,gas -9.46 -10.99 -1.53 -0.510 0.59708E+04 1.631 3 CH4,gas 6.91 -3.81 -10.72 -2.680 0.41848E+05 -7.559 4 H2,gas 5.84 1.80 -4.05 -2.313 0.15802E+05 -0.887 5 H2S,gas -7.88 -10.17 -2.28 -1.141 0.89107E+04 0.878 6 CO,gas -3.42 -9.19 -5.77 -1.776 0.22532E+05 -2.611 7 SO3,gas -6.95 -17.35 -10.40 -2.600 0.40607E+05 -7.241 8 O2,gas 16.59 -3.59 -20.19 -13.457 0.78804E+05 -17.026 9 HCl,gas -5.82 -7.06 -1.23 -0.617 0.48152E+04 -1.233 10 acmite 3.69 2.14 -1.55 -0.162 0.60694E+04 12 akimotoite 5.89 1.76 -4.13 -0.825 0.16110E+05 13 akimotoite-Fe 3.83 -0.06 -3.89 -0.778 0.15186E+05 14 albite-high -4.54 -4.67 -0.13 -0.010 0.51226E+03 15 albite -4.51 -4.67 -0.15 -0.012 0.59856E+03 16 almandine -9.85 -11.28 -1.42 -0.071 0.55596E+04 17 pyrope -3.36 -5.83 -2.47 -0.123 0.96344E+04 18 analcite -2.60 -3.56 -0.96 -0.106 0.37408E+04 19 andalusite -11.87 -12.21 -0.34 -0.034 0.13331E+04 20 andradite 11.12 6.55 -4.57 -0.237 0.17838E+05 21 grossular -0.09 -4.85 -4.76 -0.238 0.18589E+05 27 anorthite -9.60 -10.13 -0.53 -0.040 0.20518E+04 28 anthophyllite 13.40 11.20 -2.19 -0.059 0.85581E+04 29 anthophyllite-Fe 1.07 -1.52 -2.58 -0.070 0.10081E+05 31 apatite-OH-zs -49.86 -51.99 -2.13 -0.164 0.83054E+04 32 apatite-Cl-zs -55.92 -59.04 -3.12 -0.260 0.12183E+05 33 aragonite -4.35 -7.80 -3.45 -1.151 0.13475E+05 34 brucite 5.09 2.86 -2.23 -0.446 0.87062E+04 35 calcite -4.45 -7.80 -3.35 -1.118 0.13093E+05 36 carnegieite-low -0.69 -2.46 -1.77 -0.252 0.68906E+04 37 carnegieite-high -0.62 -2.46 -1.84 -0.262 0.71671E+04 38 carpholite-Mg -8.60 -10.45 -1.85 -0.124 0.72319E+04 39 carpholite-Fe -9.92 -12.27 -2.35 -0.156 0.91616E+04 40 celadonite -1.29 -3.39 -2.11 -0.124 0.82316E+04 41 celadonite-Fe -2.66 -5.21 -2.55 -0.150 0.99543E+04 42 chrysotile 8.79 6.38 -2.41 -0.201 0.94157E+04 44 clinochlore 1.22 -0.10 -1.32 -0.041 0.51474E+04 45 daphnite -5.68 -9.19 -3.51 -0.110 0.13695E+05 48 chloritoid-Mg -8.17 -9.35 -1.17 -0.078 0.45754E+04 49 chloritoid-Fe -10.06 -11.16 -1.10 -0.073 0.42954E+04 50 chloritoid-Mn -7.90 -9.61 -1.71 -0.114 0.66708E+04 52 coesite -0.82 -1.11 -0.28 -0.094 0.10997E+04 53 cordierite-H -21.47 -22.01 -0.54 -0.019 0.21112E+04 54 cordierite-Fe -23.93 -25.64 -1.71 -0.059 0.66664E+04 55 cordierite-Mn -19.53 -22.53 -3.00 -0.103 0.11715E+05 56 corundum -10.59 -11.10 -0.51 -0.046 0.19931E+04 58 cristobalite -1.06 -1.11 -0.05 -0.016 0.19289E+03 59 cummingtonite 13.46 11.20 -2.25 -0.061 0.87950E+04 61 cymrite-K -2.87 -5.15 -2.28 -0.190 0.88949E+04 63 diaspore -4.79 -5.55 -0.76 -0.127 0.29659E+04 65 diopside 5.15 3.84 -1.31 -0.131 0.51176E+04 66 hedenbergite 3.76 2.02 -1.74 -0.174 0.67927E+04 68 eastonite -8.22 -9.42 -1.20 -0.046 0.46733E+04 69 enstatite 4.37 3.52 -0.85 -0.085 0.33191E+04 70 clinoenstatite-HiP 4.85 3.52 -1.34 -0.134 0.52144E+04 71 clinoenstatite 4.35 3.52 -0.84 -0.084 0.32645E+04 72 protoenstatite 4.50 3.52 -0.98 -0.098 0.38276E+04 73 epidote -5.92 -7.89 -1.98 -0.096 0.77213E+04 74 clinozoisite -11.25 -13.59 -2.35 -0.107 0.91615E+04 75 epidote-Fe 1.09 -2.19 -3.28 -0.170 0.12801E+05 76 fayalite 1.89 0.99 -0.90 -0.129 0.35190E+04 77 ferrosilite 0.88 -0.12 -0.99 -0.099 0.38781E+04 78 forsterite 5.79 4.62 -1.17 -0.167 0.45712E+04 79 gedrite -12.74 -14.52 -1.78 -0.048 0.69434E+04 81 gibbsite -3.19 -5.55 -2.37 -0.338 0.92333E+04 82 glaucophane 0.13 -2.95 -3.09 -0.083 0.12049E+05 83 glaucophane-Fe -3.81 -8.41 -4.59 -0.124 0.17935E+05 84 goethite 0.95 0.15 -0.80 -0.174 0.31419E+04 86 greenalite 4.05 0.93 -3.12 -0.260 0.12175E+05 87 grunerite 1.60 -1.52 -3.12 -0.084 0.12182E+05 88 halite -0.79 -2.85 -2.07 -1.034 0.80698E+04 89 hematite 0.38 0.30 -0.09 -0.010 0.33212E+03 90 heulandite -12.85 -15.67 -2.82 -0.128 0.11003E+05 91 hercynite -9.12 -10.05 -0.94 -0.062 0.36546E+04 94 jadeite -1.92 -3.56 -1.64 -0.164 0.63986E+04 96 kalsilite -1.31 -2.94 -1.63 -0.232 0.63480E+04 97 kaolinite -10.72 -13.32 -2.60 -0.236 0.10141E+05 98 kyanite -11.71 -12.21 -0.50 -0.050 0.19397E+04 100 laumontite -8.98 -12.34 -3.37 -0.224 0.13143E+05 101 lawsonite -6.86 -10.13 -3.27 -0.218 0.12749E+05 102 leucite -3.07 -4.05 -0.97 -0.097 0.37963E+04 104 lizardite 8.98 6.38 -2.60 -0.216 0.10135E+05 105 magnesite -5.33 -8.12 -2.79 -0.931 0.10903E+05 107 minnesotaite 0.59 -1.28 -1.87 -0.110 0.72964E+04 108 minnesotaite-Mg 6.42 4.17 -2.25 -0.132 0.87873E+04 109 magnesioferrite 4.35 3.16 -1.19 -0.097 0.46467E+04 111 manganosite 5.12 2.60 -2.52 -0.630 0.98313E+04 112 margarite -19.72 -21.23 -1.51 -0.060 0.58921E+04 115 microcline -5.11 -5.15 -0.04 -0.003 0.16856E+03 116 monticellite 8.39 4.95 -3.45 -0.492 0.13450E+05 118 mullite-Si -11.14 -12.21 -1.07 -0.107 0.41774E+04 119 muscovite -15.57 -16.26 -0.69 -0.040 0.26812E+04 120 paragonite -14.89 -15.77 -0.88 -0.052 0.34322E+04 121 nepheline -0.98 -2.46 -1.47 -0.211 0.57531E+04 122 osumilite(2) -14.67 -16.51 -1.84 -0.038 0.71758E+04 123 osumilite-Fe -30.90 -33.00 -2.10 -0.044 0.82174E+04 124 pargasite 2.44 -1.25 -3.69 -0.097 0.14413E+05 125 periclase 5.28 2.86 -2.41 -0.603 0.94173E+04 126 periclase-Fe 2.75 1.05 -1.70 -0.426 0.66468E+04 127 perovskite-Al -8.89 -11.10 -2.22 -0.201 0.86494E+04 132 phlogopite-Na 4.83 3.93 -0.90 -0.050 0.35252E+04 134 prehnite -4.97 -8.04 -3.07 -0.181 0.11989E+05 135 prehnite-Fe 0.75 -2.34 -3.09 -0.186 0.12077E+05 138 px-Mg-tschermaks -7.61 -9.34 -1.74 -0.124 0.67789E+04 139 px-Ca-tschermaks -6.64 -9.02 -2.38 -0.170 0.92963E+04 140 pyrite -21.07 -21.08 0.00 -0.001 0.89946E+01 141 pyrrhotite -8.51 -9.12 -0.61 -0.203 0.23832E+04 142 pyrrhotiteFe0.875 -9.23 -9.47 -0.24 -0.088 0.93262E+03 143 pyrophyllite -14.31 -15.53 -1.21 -0.076 0.47392E+04 146 riebeckite 5.75 3.00 -2.76 -0.076 0.10768E+05 147 ringwoodite-Fe 2.88 0.99 -1.89 -0.270 0.73696E+04 148 ringwoodite-Mg 8.90 4.62 -4.28 -0.611 0.16706E+05 149 rhodochrosite -5.22 -8.39 -3.17 -1.055 0.12358E+05 150 rhodonite 2.41 1.50 -0.92 -0.183 0.35745E+04 151 sanidine -4.58 -5.15 -0.57 -0.044 0.22374E+04 152 sapphirine(351) -43.16 -48.02 -4.86 -0.074 0.18977E+05 153 siderite -7.12 -9.94 -2.82 -0.941 0.11016E+05 154 sillimanite -11.84 -12.21 -0.37 -0.037 0.14562E+04 156 spinel -6.99 -8.24 -1.24 -0.083 0.48596E+04 162 stilpnomelane-Fe -8.36 -12.86 -4.50 -0.134 0.17570E+05 163 stilpnomelane-Mg -1.79 -3.78 -1.99 -0.060 0.77832E+04 164 stishovite 1.80 -1.11 -2.91 -0.969 0.11352E+05 165 sudoite-Fe -19.67 -23.43 -3.77 -0.122 0.14708E+05 166 sudoite -17.51 -19.80 -2.29 -0.074 0.89496E+04 167 sulfur -10.48 -11.96 -1.48 -0.457 0.57959E+04 168 sylvite -0.69 -3.34 -2.65 -1.323 0.10330E+05 169 talc 4.71 4.17 -0.54 -0.032 0.21197E+04 170 talc-Fe 1.96 -1.28 -3.24 -0.191 0.12657E+05 171 talc-tschermaks -7.19 -8.69 -1.50 -0.088 0.58717E+04 173 tephroite 6.20 4.10 -2.10 -0.301 0.82165E+04 176 topaz-H -9.79 -12.21 -2.42 -0.220 0.94478E+04 177 tremolite 14.38 11.85 -2.53 -0.068 0.98830E+04 179 troilite-low -8.41 -9.12 -0.71 -0.235 0.27579E+04 180 tschermakite -10.98 -13.87 -2.89 -0.078 0.11284E+05 183 wadsleyite-Fe 2.73 0.99 -1.74 -0.248 0.67787E+04 184 wadsleyite-Mg 7.97 4.62 -3.35 -0.478 0.13070E+05 185 wairakite -10.79 -12.34 -1.55 -0.091 0.60381E+04 186 walstromite 4.53 2.08 -2.45 -0.489 0.95525E+04 187 wollastonite 4.12 2.08 -2.04 -0.407 0.79527E+04 188 pseudo-wollastonite 4.23 2.08 -2.15 -0.430 0.83899E+04 189 zoisite -11.30 -13.59 -2.29 -0.104 0.89357E+04 192 beidellite-Ca -14.95 -16.47 -1.52 -0.094 0.59262E+04 193 beidellite-H -14.95 -17.00 -2.04 -0.130 0.79778E+04 194 beidellite-K -13.90 -15.77 -1.87 -0.115 0.73092E+04 195 beidellite-Mg -15.24 -16.52 -1.28 -0.079 0.50011E+04 196 beidellite-Na -13.84 -15.61 -1.77 -0.108 0.69167E+04 197 bornite -52.58 -53.04 -0.46 -0.034 0.17984E+04 199 chalcocite -13.65 -15.18 -1.53 -0.382 0.59710E+04 200 covellite -12.15 -13.57 -1.42 -0.540 0.55315E+04 202 montmorillonite-Ca -11.08 -12.23 -1.15 -0.071 0.44897E+04 203 montmorillonite-K -10.31 -11.52 -1.21 -0.074 0.47405E+04 204 montmorillonite-Mg -11.31 -12.28 -0.97 -0.060 0.37711E+04 205 montmorillonite-Na -9.96 -11.36 -1.41 -0.086 0.54959E+04 206 nontronite-Ca -3.73 -5.07 -1.34 -0.087 0.52138E+04 207 nontronite-H -3.74 -5.59 -1.85 -0.124 0.72345E+04 208 nontronite-K -2.68 -4.37 -1.69 -0.108 0.65850E+04 209 nontronite-Mg -3.98 -5.12 -1.14 -0.074 0.44617E+04 210 nontronite-Na -2.62 -4.21 -1.59 -0.102 0.62083E+04 215 gypsum -11.98 -14.17 -2.19 -0.547 0.85418E+04 232 alabandite -6.23 -7.56 -1.34 -0.446 0.52175E+04 234 anglesite -14.34 -16.87 -2.53 -1.266 0.98859E+04 238 boehmite -4.51 -5.55 -1.04 -0.174 0.40647E+04 242 copper,native 1.76 -1.61 -3.37 -1.171 0.13147E+05 244 ferrous-oxide 1.84 1.05 -0.79 -0.197 0.30750E+04 245 galena -9.43 -9.68 -0.26 -0.085 0.99682E+03 246 silver,native 0.53 -3.55 -4.07 -1.416 0.15895E+05 248 litharge 5.20 0.48 -4.72 -1.179 0.18410E+05 256 wurtzite -9.92 -10.71 -0.79 -0.264 0.30880E+04 257 zincite 1.96 -0.54 -2.50 -0.625 0.97566E+04 258 an20ab80 -5.75 -5.76 -0.01 -0.001 0.42050E+02 259 an25ab75 -6.03 -6.03 0.00 0.000 0.93133E+01 261 tr.625ac.25prg.125 8.75 7.94 -0.81 -0.022 0.31645E+04 Calculations done for 580.0000 Deg. C; 1447.0000 bar Temperature changed by -1.000 degrees to 579.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 29 Loop limit = 500 Temperature = 579.00 C Pressure = 1421.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5508E+02 kg liquid = 0.9923E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9960 Stoichiometric ionic strength = .3298448E+01 Osmotic coef. = 0.0000 True ionic strength = .2089605E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.87342E-05 -5.0588 0.21185E-05 -5.6740 0.24255E+00 -0.6152 2 H2O 0.99605E+00 -0.0017 0.99605E+00 -0.0017 3 Cl- 0.17554E+00 -0.7556 0.37577E-01 -1.4251 0.21407E+00 -0.6694 4 SO4-- 0.19068E-03 -3.7197 0.84403E-06 -6.0736 0.44264E-02 -2.3540 5 HCO3- 0.18458E-04 -4.7338 0.42653E-05 -5.3700 0.23108E+00 -0.6362 6 HS- 0.13729E-03 -3.8623 0.29643E-04 -4.5281 0.21591E+00 -0.6657 7 H4SiO4 0.75561E-01 -1.1217 0.75561E-01 -1.1217 0.10000E+01 0.0000 8 Al+++ 0.76605E-17 -17.1157 0.30271E-22 -22.5190 0.39516E-05 -5.4032 9 Ca++ 0.20184E-05 -5.6950 0.71851E-08 -8.1436 0.35597E-02 -2.4486 10 Mg++ 0.11921E-05 -5.9237 0.34750E-08 -8.4590 0.29151E-02 -2.5353 11 Fe++ 0.17166E-07 -7.7653 0.52649E-10 -10.2786 0.30671E-02 -2.5133 12 K+ 0.47899E-01 -1.3197 0.11359E-01 -1.9447 0.23714E+00 -0.6250 13 Na+ 0.15902E+00 -0.7985 0.34491E-01 -1.4623 0.21690E+00 -0.6637 14 Mn++ 0.62656E-06 -6.2030 0.19943E-08 -8.7002 0.31829E-02 -2.4972 15 Zn++ 0.43623E-09 -9.3603 0.13380E-11 -11.8736 0.30671E-02 -2.5133 16 Cu+ 0.30094E-07 -7.5215 0.65094E-08 -8.1865 0.21630E+00 -0.6649 17 Pb++ 0.35631E-08 -8.4482 0.14232E-10 -10.8467 0.39942E-02 -2.3986 18 Ag+ 0.33570E-09 -9.4740 0.78340E-10 -10.1060 0.23336E+00 -0.6320 19 Ba++ 0.14225E-06 -6.8469 0.61091E-09 -9.2140 0.42946E-02 -2.3671 20 HPO4-- 0.96508E-09 -9.0154 0.42936E-11 -11.3672 0.44489E-02 -2.3517 21 HSiO3- 0.18326E-05 -5.7369 0.39231E-06 -6.4064 0.21407E+00 -0.6694 22 Ca(HSiO3)+ 0.95048E-08 -8.0221 0.22742E-08 -8.6432 0.23927E+00 -0.6211 23 Mg(HSiO3)+ 0.12662E-08 -8.8975 0.30296E-09 -9.5186 0.23927E+00 -0.6211 24 NaHSiO3,aq 0.15527E-05 -5.8089 0.15527E-05 -5.8089 0.10000E+01 0.0000 28 AgCl,aq 0.78820E-07 -7.1034 0.78820E-07 -7.1034 0.10000E+01 0.0000 29 AgCl2- 0.49506E-05 -5.3053 0.10598E-05 -5.9748 0.21407E+00 -0.6694 30 AgCl3-2 0.22187E-05 -5.6539 0.90821E-08 -8.0418 0.40935E-02 -2.3879 31 AgCl4-3 0.15148E-05 -5.8196 0.51405E-11 -11.2890 0.33935E-05 -5.4694 34 Ag(HS),aq 0.86321E-09 -9.0639 0.86321E-09 -9.0639 0.10000E+01 0.0000 35 Ag(HS)2- 0.46521E-08 -8.3323 0.99588E-09 -9.0018 0.21407E+00 -0.6694 36 AlO+ 0.10006E-10 -10.9997 0.23941E-11 -11.6208 0.23927E+00 -0.6211 38 HAlO2,aq 0.44153E-08 -8.3550 0.44153E-08 -8.3550 0.10000E+01 0.0000 39 AlO2- 0.16752E-04 -4.7759 0.31254E-05 -5.5051 0.18657E+00 -0.7291 41 Ba(HCO3)+ 0.63389E-06 -6.1980 0.15792E-06 -6.8016 0.24912E+00 -0.6036 42 BaCl+ 0.22870E-04 -4.6407 0.54723E-05 -5.2618 0.23927E+00 -0.6211 43 CH4,aq 0.18027E-08 -8.7441 0.21725E-08 -8.6630 0.12051E+01 0.0810 48 CO,aq 0.69259E-03 -3.1595 0.69259E-03 -3.1595 0.10000E+01 0.0000 49 CO2,aq 0.26761E+01 0.4275 0.32250E+01 0.5085 0.12051E+01 0.0810 50 CO3-2 0.44469E-10 -10.3519 0.18204E-12 -12.7398 0.40935E-02 -2.3879 51 CaCO3,aq 0.14820E-10 -10.8291 0.14820E-10 -10.8291 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.35127E-06 -6.4544 0.84049E-07 -7.0755 0.23927E+00 -0.6211 53 CaCl+ 0.16773E-03 -3.7754 0.40133E-04 -4.3965 0.23927E+00 -0.6211 54 CaCl2,aq 0.12158E-03 -3.9151 0.12158E-03 -3.9151 0.10000E+01 0.0000 55 CaOH+ 0.28345E-06 -6.5475 0.67821E-07 -7.1686 0.23927E+00 -0.6211 56 CaSO4,aq 0.14387E-06 -6.8420 0.14387E-06 -6.8420 0.10000E+01 0.0000 57 HCl,aq 0.15854E-02 -2.7999 0.15854E-02 -2.7999 0.10000E+01 0.0000 66 CuCl,aq 0.28497E-04 -4.5452 0.28497E-04 -4.5452 0.10000E+01 0.0000 67 CuCl2- 0.11162E-03 -3.9523 0.23894E-04 -4.6217 0.21407E+00 -0.6694 68 CuCl3-2 0.26754E-05 -5.5726 0.10952E-07 -7.9605 0.40935E-02 -2.3879 74 FeCl+ 0.44226E-06 -6.3543 0.10582E-06 -6.9754 0.23927E+00 -0.6211 75 FeCl2,aq 0.63817E-02 -2.1951 0.63817E-02 -2.1951 0.10000E+01 0.0000 77 FeO,aq 0.78089E-07 -7.1074 0.78089E-07 -7.1074 0.10000E+01 0.0000 78 FeOH+ 0.34307E-07 -7.4646 0.82088E-08 -8.0857 0.23927E+00 -0.6211 79 HFeO2- 0.98195E-08 -8.0079 0.21021E-08 -8.6774 0.21407E+00 -0.6694 82 FeO2- 0.65091E-08 -8.1865 0.13934E-08 -8.8559 0.21407E+00 -0.6694 83 HFeO2,aq 0.27054E-09 -9.5678 0.27054E-09 -9.5678 0.10000E+01 0.0000 84 H2,aq 0.45632E-02 -2.3407 0.54991E-02 -2.2597 0.12051E+01 0.0810 85 KCl,aq 0.61544E-01 -1.2108 0.61544E-01 -1.2108 0.10000E+01 0.0000 86 KHSO4,aq 0.12892E-01 -1.8897 0.12892E-01 -1.8897 0.10000E+01 0.0000 87 KOH,aq 0.10769E-05 -5.9678 0.10769E-05 -5.9678 0.10000E+01 0.0000 88 KSO4- 0.40506E-02 -2.3925 0.86712E-03 -3.0619 0.21407E+00 -0.6694 90 Mg(HCO3)+ 0.67338E-07 -7.1717 0.16112E-07 -7.7928 0.23927E+00 -0.6211 91 MgCl+ 0.15855E-04 -4.7998 0.37937E-05 -5.4209 0.23927E+00 -0.6211 92 MgOH+ 0.56546E-06 -6.2476 0.13530E-06 -6.8687 0.23927E+00 -0.6211 94 MnO,aq 0.46000E-07 -7.3372 0.46000E-07 -7.3372 0.10000E+01 0.0000 95 MnOH+ 0.15751E-06 -6.8027 0.37688E-07 -7.4238 0.23927E+00 -0.6211 97 HMnO2- 0.26035E-10 -10.5844 0.55732E-11 -11.2539 0.21407E+00 -0.6694 100 MnCl+ 0.11575E-02 -2.9365 0.27697E-03 -3.5576 0.23927E+00 -0.6211 101 MnSO4,aq 0.49036E-07 -7.3095 0.49036E-07 -7.3095 0.10000E+01 0.0000 102 NaCl,aq 0.39954E+00 -0.3984 0.39954E+00 -0.3984 0.10000E+01 0.0000 103 NaOH,aq 0.15177E-05 -5.8188 0.15177E-05 -5.8188 0.10000E+01 0.0000 105 OH- 0.84992E-05 -5.0706 0.15857E-05 -5.7998 0.18657E+00 -0.7291 110 HPO3-2 0.12632E-10 -10.8985 0.51710E-13 -13.2864 0.40935E-02 -2.3879 111 H3PO3,aq 0.10789E-09 -9.9670 0.10789E-09 -9.9670 0.10000E+01 0.0000 112 H2PO3- 0.34814E-08 -8.4582 0.74526E-09 -9.1277 0.21407E+00 -0.6694 113 H3PO4,aq 0.90677E-06 -6.0425 0.90677E-06 -6.0425 0.10000E+01 0.0000 114 H2PO4- 0.15765E-05 -5.8023 0.35533E-06 -6.4494 0.22539E+00 -0.6471 116 H4P2O7,aq 0.70148E-10 -10.1540 0.70148E-10 -10.1540 0.10000E+01 0.0000 117 H3P2O7- 0.97829E-09 -9.0095 0.20942E-09 -9.6790 0.21407E+00 -0.6694 118 H2P2O7-2 0.27160E-06 -6.5661 0.11118E-08 -8.9540 0.40935E-02 -2.3879 119 HP2O7-3 0.14046E-07 -7.8524 0.47666E-13 -13.3218 0.33935E-05 -5.4694 121 PbCl+ 0.19843E-05 -5.7024 0.47479E-06 -6.3235 0.23927E+00 -0.6211 122 PbCl2,aq 0.87369E-04 -4.0586 0.87369E-04 -4.0586 0.10000E+01 0.0000 123 PbCl3- 0.11051E-03 -3.9566 0.23658E-04 -4.6260 0.21407E+00 -0.6694 124 PbCl4-2 0.25868E-04 -4.5872 0.10589E-06 -6.9751 0.40935E-02 -2.3879 125 PbO,aq 0.44738E-08 -8.3493 0.44738E-08 -8.3493 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10619E-03 -3.9739 0.10619E-03 -3.9739 0.10000E+01 0.0000 128 Pb(HS)3- 0.10897E-04 -4.9627 0.23327E-05 -5.6321 0.21407E+00 -0.6694 129 H2S,aq 0.10537E+01 0.0227 0.12698E+01 0.1037 0.12051E+01 0.0810 130 S2-2 0.14609E-07 -7.8354 0.59801E-10 -10.2233 0.40935E-02 -2.3879 131 S3-2 0.14923E-08 -8.8261 0.61089E-11 -11.2140 0.40935E-02 -2.3879 132 S3- 0.17194E-01 -1.7646 0.36807E-02 -2.4341 0.21407E+00 -0.6694 133 S4-2 0.12765E-09 -9.8940 0.52254E-12 -12.2819 0.40935E-02 -2.3879 135 SO2,aq 0.28793E+00 -0.5407 0.28793E+00 -0.5407 0.10000E+01 0.0000 136 SO3-2 0.58892E-09 -9.2299 0.38280E-11 -11.4170 0.65000E-02 -2.1871 137 HSO3- 0.36539E-03 -3.4372 0.78219E-04 -4.1067 0.21407E+00 -0.6694 138 HSO4- 0.10579E-01 -1.9755 0.25992E-02 -2.5852 0.24568E+00 -0.6096 140 S2O3-2 0.52767E-06 -6.2776 0.21600E-08 -8.6655 0.40935E-02 -2.3879 141 HS2O3- 0.57429E-06 -6.2409 0.12294E-06 -6.9103 0.21407E+00 -0.6694 142 H2S2O3,aq 0.26414E-07 -7.5782 0.26414E-07 -7.5782 0.10000E+01 0.0000 150 S4O6-2 0.60957E-09 -9.2150 0.24953E-11 -11.6029 0.40935E-02 -2.3879 152 ZnCl+ 0.42455E-03 -3.3721 0.10158E-03 -3.9932 0.23927E+00 -0.6211 153 ZnCl2,aq 0.11293E-02 -2.9472 0.11293E-02 -2.9472 0.10000E+01 0.0000 154 ZnCl3- 0.13102E-03 -3.8827 0.28048E-04 -4.5521 0.21407E+00 -0.6694 155 ZnO,aq 0.36597E-07 -7.4366 0.36597E-07 -7.4366 0.10000E+01 0.0000 156 ZnOH+ 0.23225E-05 -5.6340 0.55572E-06 -6.2551 0.23927E+00 -0.6211 158 HZnO2- 0.29577E-09 -9.5290 0.63315E-10 -10.1985 0.21407E+00 -0.6694 Charge balance for all species = 0.2551E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8734223E-05 0.4303429E+01 0.3539475E+04 0.0000 2 H2O 0.1000000E+01 0.5250512E+02 0.7718497E+06 0.0000 3 Cl- 0.1755360E+00 0.6565440E+00 0.1899356E+05 4.2489 4 SO4-- 0.1906813E-03 0.2533664E+00 0.1986042E+05 5.2743 5 HCO3- 0.1845795E-04 0.2676839E+01 0.1332797E+06 0.3039 6 HS- 0.1372945E-03 0.1168262E+01 0.3152755E+05 1.1459 7 H4SiO4 0.7556109E-01 0.7556449E-01 0.5926527E+04 -1.1217 8 Al+++ 0.7660503E-17 0.1675595E-04 0.3689137E+00 -5.4971 9 Ca++ 0.2018443E-05 0.2921201E-03 0.9553379E+01 3.2044 10 Mg++ 0.1192073E-05 0.1768119E-04 0.3507695E+00 2.8889 11 Fe++ 0.1716559E-07 0.6382293E-02 0.2908480E+03 1.0693 12 K+ 0.4789892E-01 0.1263871E+00 0.4032657E+04 3.7293 13 Na+ 0.1590199E+00 0.5585599E+00 0.1047839E+05 4.2117 14 Mn++ 0.6265587E-06 0.1158417E-02 0.5193108E+02 2.6477 15 Zn++ 0.4362255E-09 0.1687234E-02 0.9000019E+02 -0.5256 16 Cu+ 0.3009392E-07 0.1428212E-03 0.7405073E+01 -2.5125 17 Pb++ 0.3563087E-08 0.3428270E-03 0.5796066E+02 0.5012 18 Ag+ 0.3357014E-09 0.8768735E-05 0.7718397E+00 -4.4320 19 Ba++ 0.1422515E-06 0.2364653E-04 0.2650050E+01 2.1339 20 HPO4-- 0.9650758E-09 0.3061224E-05 0.2397512E+00 -0.0192 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4270109E+01 -.7746974E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5209860E+02 -.1338203E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2514047E+00 0.3181063E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159217E+01 0.9275100E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.7497942E-01 0.6861490E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1662622E-04 0.6779133E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2898583E-03 0.2380516E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1754430E-04 0.3132355E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.6332878E-02 0.2433876E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254086E+00 0.1566266E-05 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542352E+00 0.3641869E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149448E-02 0.5203326E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1674171E-02 0.6251637E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1417154E-03 0.2578943E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.2346345E-04 0.3190901E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3037522E-05 0.5529978E-05 0.0000000E+00 Chg. balance for solid moles: 0.9588E-18 Mass of aqueous solution: 0.121600E+04 g Temperature = 579.00 C Pressure = 1421.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.7275E-04 -4.138 0.9905E-02 -2.004 0.2215 0.3343E-02 annite 0.5048E-06 -6.297 0.2584E-03 -3.588 0.5779E-02 0.7790E-04 phlogopite 0.1044E-05 -5.981 0.4357E-03 -3.361 0.9744E-02 0.1562E-03 biotite-Mn 0.1734E-07 -7.761 0.8831E-05 -5.054 0.1975E-03 0.2647E-05 apatite-OH 0.1843E-05 -5.734 0.9259E-03 -3.033 0.2071E-01 0.2942E-03 magnetite 0.7248E-03 -3.140 0.1678 -0.775 3.752 0.3227E-01 quartz 0.6721E-01 -1.173 4.038 0.606 90.30 1.525 barite 0.3191E-04 -4.496 0.7448E-02 -2.128 0.1666 0.1662E-02 chalcopyrite 0.2579E-03 -3.589 0.4732E-01 -1.325 1.058 0.1105E-01 sphalerite 0.6252E-03 -3.204 0.6091E-01 -1.215 1.362 0.1490E-01 an30ab70 0.5203E-03 -3.284 0.1389 -0.857 3.107 0.5217E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3223E+00 0.3223E+00 1.0000 -0.492 phlogopite 0.6666E+00 0.6666E+00 1.0000 -0.176 biotite-Mn 0.1107E-01 0.1107E-01 1.0000 -1.956 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.471637 g Volume = 1.640727 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.22 -14.22 0.00 0.000 0.00000E+00 24 annite -0.45 -0.45 0.00 0.000 0.20347E-10 25 phlogopite 4.06 4.06 0.00 0.000 -0.27706E-10 26 biotite-Mn 8.68 8.68 0.00 0.000 0.00000E+00 30 apatite-OH -52.13 -52.13 0.00 0.000 0.00000E+00 106 magnetite 1.40 1.40 0.00 0.000 -0.41559E-10 144 quartz -1.12 -1.12 0.00 0.000 0.00000E+00 237 barite -15.29 -15.29 0.00 0.000 0.69265E-11 240 chalcopyrite -22.75 -22.75 0.00 0.000 -0.13853E-10 255 sphalerite -10.73 -10.73 0.00 0.000 -0.13853E-10 260 an30ab70 -6.26 -6.26 0.00 0.000 0.34633E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.28 -0.282 0.10990E+04 2.871 2 CO2,gas -9.50 -11.04 -1.54 -0.514 0.60108E+04 1.611 3 CH4,gas 6.91 -3.83 -10.74 -2.685 0.41872E+05 -7.586 4 H2,gas 5.85 1.80 -4.05 -2.314 0.15787E+05 -0.896 5 H2S,gas -7.92 -10.20 -2.29 -1.143 0.89116E+04 0.867 6 CO,gas -3.45 -9.24 -5.79 -1.781 0.22568E+05 -2.635 7 SO3,gas -7.00 -17.42 -10.42 -2.604 0.40622E+05 -7.265 8 O2,gas 16.60 -3.61 -20.21 -13.474 0.78808E+05 -17.058 9 HCl,gas -5.85 -7.10 -1.25 -0.626 0.48794E+04 -1.251 10 acmite 3.69 2.14 -1.55 -0.161 0.60324E+04 12 akimotoite 5.90 1.77 -4.14 -0.827 0.16124E+05 13 akimotoite-Fe 3.85 -0.05 -3.90 -0.779 0.15191E+05 14 albite-high -4.52 -4.64 -0.13 -0.010 0.49634E+03 15 albite -4.50 -4.64 -0.15 -0.011 0.57883E+03 16 almandine -9.71 -11.15 -1.44 -0.072 0.56227E+04 17 pyrope -3.20 -5.69 -2.49 -0.125 0.97255E+04 18 analcite -2.57 -3.53 -0.96 -0.106 0.37272E+04 19 andalusite -11.76 -12.12 -0.35 -0.035 0.13765E+04 20 andradite 11.16 6.58 -4.58 -0.238 0.17841E+05 21 grossular 0.03 -4.75 -4.78 -0.239 0.18634E+05 27 anorthite -9.50 -10.03 -0.54 -0.041 0.20939E+04 28 anthophyllite 13.48 11.26 -2.22 -0.060 0.86394E+04 29 anthophyllite-Fe 1.11 -1.47 -2.59 -0.070 0.10094E+05 31 apatite-OH-zs -49.99 -52.13 -2.13 -0.164 0.83075E+04 32 apatite-Cl-zs -56.09 -59.22 -3.13 -0.261 0.12203E+05 33 aragonite -4.37 -7.84 -3.47 -1.155 0.13512E+05 34 brucite 5.12 2.89 -2.24 -0.447 0.87177E+04 35 calcite -4.47 -7.84 -3.37 -1.122 0.13128E+05 36 carnegieite-low -0.64 -2.41 -1.76 -0.252 0.68711E+04 37 carnegieite-high -0.57 -2.41 -1.83 -0.262 0.71495E+04 38 carpholite-Mg -8.48 -10.35 -1.87 -0.125 0.72852E+04 39 carpholite-Fe -9.81 -12.17 -2.36 -0.157 0.92075E+04 40 celadonite -1.25 -3.36 -2.11 -0.124 0.82198E+04 41 celadonite-Fe -2.63 -5.18 -2.55 -0.150 0.99357E+04 42 chrysotile 8.84 6.42 -2.42 -0.202 0.94440E+04 44 clinochlore 1.42 0.07 -1.34 -0.042 0.52326E+04 45 daphnite -5.50 -9.02 -3.52 -0.110 0.13742E+05 48 chloritoid-Mg -8.04 -9.23 -1.19 -0.079 0.46288E+04 49 chloritoid-Fe -9.94 -11.05 -1.11 -0.074 0.43372E+04 50 chloritoid-Mn -7.78 -9.47 -1.69 -0.113 0.66092E+04 52 coesite -0.84 -1.12 -0.28 -0.094 0.11009E+04 53 cordierite-H -21.25 -21.82 -0.57 -0.020 0.22206E+04 54 cordierite-Fe -23.73 -25.45 -1.73 -0.060 0.67415E+04 55 cordierite-Mn -19.33 -22.30 -2.97 -0.102 0.11581E+05 56 corundum -10.48 -11.00 -0.52 -0.048 0.20376E+04 58 cristobalite -1.07 -1.12 -0.05 -0.016 0.19099E+03 59 cummingtonite 13.54 11.26 -2.28 -0.062 0.88783E+04 61 cymrite-K -2.85 -5.13 -2.28 -0.190 0.88788E+04 63 diaspore -4.73 -5.50 -0.77 -0.128 0.29861E+04 65 diopside 5.17 3.85 -1.32 -0.132 0.51320E+04 66 hedenbergite 3.78 2.03 -1.74 -0.174 0.67991E+04 68 eastonite -8.03 -9.23 -1.21 -0.046 0.47119E+04 69 enstatite 4.40 3.54 -0.86 -0.086 0.33442E+04 70 clinoenstatite-HiP 4.88 3.54 -1.34 -0.134 0.52407E+04 71 clinoenstatite 4.38 3.54 -0.84 -0.084 0.32895E+04 72 protoenstatite 4.53 3.54 -0.99 -0.099 0.38530E+04 73 epidote -5.79 -7.78 -1.99 -0.097 0.77685E+04 74 clinozoisite -11.08 -13.45 -2.37 -0.108 0.92316E+04 75 epidote-Fe 1.17 -2.12 -3.29 -0.171 0.12822E+05 76 fayalite 1.92 1.02 -0.90 -0.129 0.35253E+04 77 ferrosilite 0.90 -0.10 -1.00 -0.100 0.38854E+04 78 forsterite 5.83 4.66 -1.18 -0.168 0.45942E+04 79 gedrite -12.46 -14.27 -1.82 -0.049 0.70900E+04 81 gibbsite -3.13 -5.50 -2.37 -0.339 0.92545E+04 82 glaucophane 0.22 -2.86 -3.09 -0.083 0.12042E+05 83 glaucophane-Fe -3.73 -8.32 -4.59 -0.124 0.17903E+05 84 goethite 0.97 0.16 -0.81 -0.174 0.31416E+04 86 greenalite 4.09 0.96 -3.12 -0.260 0.12174E+05 87 grunerite 1.65 -1.47 -3.13 -0.085 0.12197E+05 88 halite -0.82 -2.89 -2.06 -1.032 0.80499E+04 89 hematite 0.41 0.33 -0.08 -0.010 0.32989E+03 90 heulandite -12.80 -15.63 -2.84 -0.129 0.11070E+05 91 hercynite -8.98 -9.93 -0.95 -0.063 0.37023E+04 94 jadeite -1.89 -3.53 -1.64 -0.164 0.63823E+04 96 kalsilite -1.27 -2.89 -1.62 -0.232 0.63234E+04 97 kaolinite -10.63 -13.24 -2.61 -0.237 0.10173E+05 98 kyanite -11.61 -12.12 -0.51 -0.051 0.19848E+04 100 laumontite -8.89 -12.28 -3.38 -0.226 0.13193E+05 101 lawsonite -6.75 -10.04 -3.28 -0.219 0.12797E+05 102 leucite -3.04 -4.01 -0.97 -0.097 0.37719E+04 104 lizardite 9.03 6.42 -2.61 -0.217 0.10160E+05 105 magnesite -5.35 -8.16 -2.81 -0.936 0.10949E+05 107 minnesotaite 0.60 -1.27 -1.87 -0.110 0.72957E+04 108 minnesotaite-Mg 6.45 4.19 -2.26 -0.133 0.88129E+04 109 magnesioferrite 4.41 3.22 -1.19 -0.097 0.46553E+04 111 manganosite 5.14 2.65 -2.50 -0.624 0.97296E+04 112 margarite -19.50 -21.03 -1.53 -0.061 0.59795E+04 115 microcline -5.09 -5.13 -0.04 -0.003 0.13982E+03 116 monticellite 8.42 4.97 -3.45 -0.493 0.13461E+05 118 mullite-Si -11.03 -12.12 -1.08 -0.108 0.42229E+04 119 muscovite -15.43 -16.13 -0.69 -0.041 0.27001E+04 120 paragonite -14.76 -15.64 -0.89 -0.052 0.34582E+04 121 nepheline -0.94 -2.41 -1.47 -0.210 0.57334E+04 122 osumilite(2) -14.56 -16.41 -1.85 -0.039 0.72189E+04 123 osumilite-Fe -30.70 -32.82 -2.12 -0.044 0.82728E+04 124 pargasite 2.67 -1.05 -3.72 -0.098 0.14500E+05 125 periclase 5.31 2.89 -2.42 -0.605 0.94287E+04 126 periclase-Fe 2.77 1.07 -1.71 -0.426 0.66509E+04 127 perovskite-Al -8.77 -11.00 -2.23 -0.203 0.86944E+04 132 phlogopite-Na 4.92 4.02 -0.91 -0.050 0.35396E+04 134 prehnite -4.86 -7.95 -3.09 -0.182 0.12033E+05 135 prehnite-Fe 0.82 -2.29 -3.10 -0.187 0.12096E+05 138 px-Mg-tschermaks -7.48 -9.23 -1.75 -0.125 0.68371E+04 139 px-Ca-tschermaks -6.52 -8.91 -2.40 -0.171 0.93428E+04 140 pyrite -21.14 -21.14 0.00 0.000 0.66937E+01 141 pyrrhotite -8.52 -9.13 -0.61 -0.204 0.23856E+04 142 pyrrhotiteFe0.875 -9.25 -9.49 -0.24 -0.088 0.93554E+03 143 pyrophyllite -14.25 -15.47 -1.23 -0.077 0.47806E+04 146 riebeckite 5.75 3.01 -2.74 -0.076 0.10694E+05 147 ringwoodite-Fe 2.91 1.02 -1.89 -0.270 0.73747E+04 148 ringwoodite-Mg 8.95 4.66 -4.29 -0.613 0.16729E+05 149 rhodochrosite -5.24 -8.40 -3.15 -1.051 0.12290E+05 150 rhodonite 2.42 1.53 -0.89 -0.178 0.34739E+04 151 sanidine -4.56 -5.13 -0.57 -0.044 0.22085E+04 152 sapphirine(351) -42.52 -47.45 -4.93 -0.075 0.19238E+05 153 siderite -7.14 -9.97 -2.83 -0.945 0.11053E+05 154 sillimanite -11.73 -12.12 -0.38 -0.038 0.15008E+04 156 spinel -6.85 -8.11 -1.26 -0.084 0.49143E+04 162 stilpnomelane-Fe -8.24 -12.75 -4.51 -0.135 0.17602E+05 163 stilpnomelane-Mg -1.64 -3.66 -2.02 -0.060 0.78744E+04 164 stishovite 1.79 -1.12 -2.91 -0.971 0.11353E+05 165 sudoite-Fe -19.43 -23.22 -3.80 -0.123 0.14816E+05 166 sudoite -17.26 -19.59 -2.33 -0.075 0.90734E+04 167 sulfur -10.52 -12.01 -1.49 -0.457 0.57971E+04 168 sylvite -0.73 -3.37 -2.64 -1.321 0.10301E+05 169 talc 4.74 4.19 -0.55 -0.032 0.21476E+04 170 talc-Fe 1.97 -1.27 -3.25 -0.191 0.12659E+05 171 talc-tschermaks -7.06 -8.58 -1.52 -0.089 0.59326E+04 173 tephroite 6.23 4.17 -2.05 -0.294 0.80125E+04 176 topaz-H -9.69 -12.12 -2.43 -0.221 0.94901E+04 177 tremolite 14.44 11.89 -2.55 -0.069 0.99393E+04 179 troilite-low -8.43 -9.13 -0.71 -0.236 0.27585E+04 180 tschermakite -10.72 -13.64 -2.92 -0.079 0.11402E+05 183 wadsleyite-Fe 2.76 1.02 -1.74 -0.249 0.67852E+04 184 wadsleyite-Mg 8.01 4.66 -3.36 -0.480 0.13094E+05 185 wairakite -10.72 -12.27 -1.56 -0.092 0.60754E+04 186 walstromite 4.53 2.08 -2.45 -0.490 0.95538E+04 187 wollastonite 4.12 2.08 -2.04 -0.408 0.79524E+04 188 pseudo-wollastonite 4.24 2.08 -2.15 -0.430 0.83908E+04 189 zoisite -11.14 -13.45 -2.31 -0.105 0.90076E+04 192 beidellite-Ca -14.86 -16.39 -1.53 -0.095 0.59748E+04 193 beidellite-H -14.86 -16.92 -2.06 -0.131 0.80254E+04 194 beidellite-K -13.81 -15.69 -1.88 -0.115 0.73422E+04 195 beidellite-Mg -15.15 -16.44 -1.30 -0.080 0.50547E+04 196 beidellite-Na -13.75 -15.53 -1.78 -0.109 0.69521E+04 197 bornite -52.74 -53.20 -0.46 -0.035 0.18008E+04 199 chalcocite -13.70 -15.23 -1.53 -0.383 0.59695E+04 200 covellite -12.20 -13.62 -1.42 -0.540 0.55267E+04 202 montmorillonite-Ca -11.02 -12.18 -1.16 -0.072 0.45266E+04 203 montmorillonite-K -10.25 -11.48 -1.22 -0.075 0.47649E+04 204 montmorillonite-Mg -11.25 -12.23 -0.98 -0.060 0.38094E+04 205 montmorillonite-Na -9.90 -11.32 -1.41 -0.087 0.55174E+04 206 nontronite-Ca -3.72 -5.06 -1.34 -0.087 0.52181E+04 207 nontronite-H -3.73 -5.59 -1.86 -0.124 0.72385E+04 208 nontronite-K -2.67 -4.36 -1.69 -0.108 0.65743E+04 209 nontronite-Mg -3.97 -5.11 -1.15 -0.074 0.44689E+04 210 nontronite-Na -2.61 -4.20 -1.59 -0.102 0.61994E+04 215 gypsum -12.03 -14.22 -2.19 -0.548 0.85520E+04 232 alabandite -6.24 -7.55 -1.31 -0.438 0.51180E+04 234 anglesite -14.40 -16.92 -2.52 -1.260 0.98295E+04 238 boehmite -4.45 -5.50 -1.05 -0.175 0.40859E+04 242 copper,native 1.76 -1.61 -3.37 -1.172 0.13139E+05 244 ferrous-oxide 1.86 1.07 -0.79 -0.197 0.30797E+04 245 galena -9.46 -9.70 -0.24 -0.080 0.93726E+03 246 silver,native 0.52 -3.53 -4.05 -1.410 0.15804E+05 248 litharge 5.21 0.50 -4.71 -1.176 0.18349E+05 256 wurtzite -9.94 -10.73 -0.79 -0.264 0.30884E+04 257 zincite 1.98 -0.53 -2.50 -0.626 0.97579E+04 258 an20ab80 -5.71 -5.72 -0.01 -0.001 0.35368E+02 259 an25ab75 -5.99 -5.99 0.00 0.000 0.59559E+01 261 tr.625ac.25prg.125 8.83 8.00 -0.83 -0.022 0.32257E+04 Calculations done for 579.0000 Deg. C; 1421.0000 bar Temperature changed by -1.000 degrees to 578.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 29 Loop limit = 500 Temperature = 578.00 C Pressure = 1396.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5508E+02 kg liquid = 0.9923E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9961 Stoichiometric ionic strength = .3297298E+01 Osmotic coef. = 0.0000 True ionic strength = .2044955E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.83484E-05 -5.0784 0.20000E-05 -5.6990 0.23957E+00 -0.6206 2 H2O 0.99611E+00 -0.0017 0.99611E+00 -0.0017 3 Cl- 0.17186E+00 -0.7648 0.36224E-01 -1.4410 0.21077E+00 -0.6762 4 SO4-- 0.19359E-03 -3.7131 0.81373E-06 -6.0895 0.42033E-02 -2.3764 5 HCO3- 0.17650E-04 -4.7533 0.40158E-05 -5.3962 0.22752E+00 -0.6430 6 HS- 0.13605E-03 -3.8663 0.28923E-04 -4.5388 0.21258E+00 -0.6725 7 H4SiO4 0.73540E-01 -1.1335 0.73540E-01 -1.1335 0.10000E+01 0.0000 8 Al+++ 0.81541E-17 -17.0886 0.28693E-22 -22.5422 0.35189E-05 -5.4536 9 Ca++ 0.19540E-05 -5.7091 0.66009E-08 -8.1804 0.33781E-02 -2.4713 10 Mg++ 0.11788E-05 -5.9286 0.32605E-08 -8.4867 0.27660E-02 -2.5582 11 Fe++ 0.16877E-07 -7.7727 0.49116E-10 -10.3088 0.29103E-02 -2.5361 12 K+ 0.47006E-01 -1.3278 0.10974E-01 -1.9596 0.23347E+00 -0.6318 13 Na+ 0.15549E+00 -0.8083 0.33202E-01 -1.4788 0.21353E+00 -0.6705 14 Mn++ 0.65182E-06 -6.1859 0.19686E-08 -8.7058 0.30202E-02 -2.5200 15 Zn++ 0.42602E-09 -9.3706 0.12398E-11 -11.9066 0.29103E-02 -2.5361 16 Cu+ 0.28376E-07 -7.5471 0.60425E-08 -8.2188 0.21295E+00 -0.6717 17 Pb++ 0.34902E-08 -8.4572 0.13231E-10 -10.8784 0.37910E-02 -2.4213 18 Ag+ 0.33060E-09 -9.4807 0.75955E-10 -10.1194 0.22975E+00 -0.6388 19 Ba++ 0.13514E-06 -6.8692 0.55088E-09 -9.2589 0.40765E-02 -2.3897 20 HPO4-- 0.98141E-09 -9.0081 0.41462E-11 -11.3823 0.42248E-02 -2.3742 21 HSiO3- 0.18044E-05 -5.7437 0.38031E-06 -6.4199 0.21077E+00 -0.6762 22 Ca(HSiO3)+ 0.90725E-08 -8.0423 0.21372E-08 -8.6702 0.23557E+00 -0.6279 23 Mg(HSiO3)+ 0.12456E-08 -8.9046 0.29342E-09 -9.5325 0.23557E+00 -0.6279 24 NaHSiO3,aq 0.15776E-05 -5.8020 0.15776E-05 -5.8020 0.10000E+01 0.0000 28 AgCl,aq 0.80342E-07 -7.0951 0.80342E-07 -7.0951 0.10000E+01 0.0000 29 AgCl2- 0.49568E-05 -5.3048 0.10448E-05 -5.9810 0.21077E+00 -0.6762 30 AgCl3-2 0.21889E-05 -5.6598 0.85077E-08 -8.0702 0.38868E-02 -2.4104 31 AgCl4-3 0.15363E-05 -5.8135 0.46471E-11 -11.3328 0.30249E-05 -5.5193 34 Ag(HS),aq 0.90093E-09 -9.0453 0.90093E-09 -9.0453 0.10000E+01 0.0000 35 Ag(HS)2- 0.47549E-08 -8.3229 0.10022E-08 -8.9990 0.21077E+00 -0.6762 36 AlO+ 0.10002E-10 -10.9999 0.23562E-11 -11.6278 0.23557E+00 -0.6279 38 HAlO2,aq 0.44087E-08 -8.3557 0.44087E-08 -8.3557 0.10000E+01 0.0000 39 AlO2- 0.16531E-04 -4.7817 0.30375E-05 -5.5175 0.18374E+00 -0.7358 41 Ba(HCO3)+ 0.58999E-06 -6.2292 0.14471E-06 -6.8395 0.24528E+00 -0.6103 42 BaCl+ 0.21406E-04 -4.6695 0.50426E-05 -5.2973 0.23557E+00 -0.6279 43 CH4,aq 0.17904E-08 -8.7471 0.21559E-08 -8.6664 0.12041E+01 0.0807 48 CO,aq 0.68249E-03 -3.1659 0.68249E-03 -3.1659 0.10000E+01 0.0000 49 CO2,aq 0.26760E+01 0.4275 0.32223E+01 0.5082 0.12041E+01 0.0807 50 CO3-2 0.44174E-10 -10.3548 0.17169E-12 -12.7652 0.38868E-02 -2.4104 51 CaCO3,aq 0.14422E-10 -10.8410 0.14422E-10 -10.8410 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.32284E-06 -6.4910 0.76053E-07 -7.1189 0.23557E+00 -0.6279 53 CaCl+ 0.15875E-03 -3.7993 0.37396E-04 -4.4272 0.23557E+00 -0.6279 54 CaCl2,aq 0.11806E-03 -3.9279 0.11806E-03 -3.9279 0.10000E+01 0.0000 55 CaOH+ 0.27128E-06 -6.5666 0.63905E-07 -7.1945 0.23557E+00 -0.6279 56 CaSO4,aq 0.14466E-06 -6.8397 0.14466E-06 -6.8397 0.10000E+01 0.0000 57 HCl,aq 0.16591E-02 -2.7801 0.16591E-02 -2.7801 0.10000E+01 0.0000 66 CuCl,aq 0.27807E-04 -4.5558 0.27807E-04 -4.5558 0.10000E+01 0.0000 67 CuCl2- 0.10802E-03 -3.9665 0.22768E-04 -4.6427 0.21077E+00 -0.6762 68 CuCl3-2 0.25518E-05 -5.5932 0.99183E-08 -8.0036 0.38868E-02 -2.4104 74 FeCl+ 0.42483E-06 -6.3718 0.10008E-06 -6.9997 0.23557E+00 -0.6279 75 FeCl2,aq 0.61061E-02 -2.2142 0.61061E-02 -2.2142 0.10000E+01 0.0000 77 FeO,aq 0.77463E-07 -7.1109 0.77463E-07 -7.1109 0.10000E+01 0.0000 78 FeOH+ 0.33231E-07 -7.4785 0.78281E-08 -8.1063 0.23557E+00 -0.6279 79 HFeO2- 0.97243E-08 -8.0121 0.20496E-08 -8.6883 0.21077E+00 -0.6762 82 FeO2- 0.64099E-08 -8.1931 0.13510E-08 -8.8693 0.21077E+00 -0.6762 83 HFeO2,aq 0.27318E-09 -9.5636 0.27318E-09 -9.5636 0.10000E+01 0.0000 84 H2,aq 0.45863E-02 -2.3385 0.55226E-02 -2.2579 0.12041E+01 0.0807 85 KCl,aq 0.62341E-01 -1.2052 0.62341E-01 -1.2052 0.10000E+01 0.0000 86 KHSO4,aq 0.12935E-01 -1.8882 0.12935E-01 -1.8882 0.10000E+01 0.0000 87 KOH,aq 0.10998E-05 -5.9587 0.10998E-05 -5.9587 0.10000E+01 0.0000 88 KSO4- 0.40968E-02 -2.3876 0.86351E-03 -3.0637 0.21077E+00 -0.6762 90 Mg(HCO3)+ 0.62526E-07 -7.2039 0.14729E-07 -7.8318 0.23557E+00 -0.6279 91 MgCl+ 0.15410E-04 -4.8122 0.36301E-05 -5.4401 0.23557E+00 -0.6279 92 MgOH+ 0.55435E-06 -6.2562 0.13059E-06 -6.8841 0.23557E+00 -0.6279 94 MnO,aq 0.48550E-07 -7.3138 0.48550E-07 -7.3138 0.10000E+01 0.0000 95 MnOH+ 0.16044E-06 -6.7947 0.37794E-07 -7.4226 0.23557E+00 -0.6279 97 HMnO2- 0.27209E-10 -10.5653 0.57350E-11 -11.2415 0.21077E+00 -0.6762 100 MnCl+ 0.11574E-02 -2.9365 0.27266E-03 -3.5644 0.23557E+00 -0.6279 101 MnSO4,aq 0.52567E-07 -7.2793 0.52567E-07 -7.2793 0.10000E+01 0.0000 102 NaCl,aq 0.40304E+00 -0.3947 0.40304E+00 -0.3947 0.10000E+01 0.0000 103 NaOH,aq 0.15429E-05 -5.8117 0.15429E-05 -5.8117 0.10000E+01 0.0000 105 OH- 0.84566E-05 -5.0728 0.15538E-05 -5.8086 0.18374E+00 -0.7358 110 HPO3-2 0.12439E-10 -10.9052 0.48347E-13 -13.3156 0.38868E-02 -2.4104 111 H3PO3,aq 0.10758E-09 -9.9683 0.10758E-09 -9.9683 0.10000E+01 0.0000 112 H2PO3- 0.33334E-08 -8.4771 0.70260E-09 -9.1533 0.21077E+00 -0.6762 113 H3PO4,aq 0.91840E-06 -6.0370 0.91840E-06 -6.0370 0.10000E+01 0.0000 114 H2PO4- 0.15467E-05 -5.8106 0.34325E-06 -6.4644 0.22192E+00 -0.6538 116 H4P2O7,aq 0.72597E-10 -10.1391 0.72597E-10 -10.1391 0.10000E+01 0.0000 117 H3P2O7- 0.95266E-09 -9.0211 0.20080E-09 -9.6972 0.21077E+00 -0.6762 118 H2P2O7-2 0.26404E-06 -6.5783 0.10263E-08 -8.9887 0.38868E-02 -2.4104 119 HP2O7-3 0.14488E-07 -7.8390 0.43823E-13 -13.3583 0.30249E-05 -5.5193 121 PbCl+ 0.19168E-05 -5.7174 0.45155E-06 -6.3453 0.23557E+00 -0.6279 122 PbCl2,aq 0.87144E-04 -4.0598 0.87144E-04 -4.0598 0.10000E+01 0.0000 123 PbCl3- 0.10988E-03 -3.9591 0.23161E-04 -4.6353 0.21077E+00 -0.6762 124 PbCl4-2 0.25279E-04 -4.5972 0.98255E-07 -7.0076 0.38868E-02 -2.4104 125 PbO,aq 0.46132E-08 -8.3360 0.46132E-08 -8.3360 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10744E-03 -3.9688 0.10744E-03 -3.9688 0.10000E+01 0.0000 128 Pb(HS)3- 0.11141E-04 -4.9531 0.23482E-05 -5.6293 0.21077E+00 -0.6762 129 H2S,aq 0.10548E+01 0.0232 0.12701E+01 0.1038 0.12041E+01 0.0807 130 S2-2 0.14528E-07 -7.8378 0.56466E-10 -10.2482 0.38868E-02 -2.4104 131 S3-2 0.14692E-08 -8.8329 0.57103E-11 -11.2433 0.38868E-02 -2.4104 132 S3- 0.16594E-01 -1.7801 0.34975E-02 -2.4562 0.21077E+00 -0.6762 133 S4-2 0.12456E-09 -9.9046 0.48415E-12 -12.3150 0.38868E-02 -2.4104 135 SO2,aq 0.28854E+00 -0.5398 0.28854E+00 -0.5398 0.10000E+01 0.0000 136 SO3-2 0.59365E-09 -9.2265 0.36677E-11 -11.4356 0.61782E-02 -2.2091 137 HSO3- 0.35607E-03 -3.4485 0.75051E-04 -4.1246 0.21077E+00 -0.6762 138 HSO4- 0.10363E-01 -1.9845 0.25068E-02 -2.6009 0.24191E+00 -0.6164 140 S2O3-2 0.52618E-06 -6.2789 0.20451E-08 -8.6893 0.38868E-02 -2.4104 141 HS2O3- 0.55533E-06 -6.2554 0.11705E-06 -6.9316 0.21077E+00 -0.6762 142 H2S2O3,aq 0.26666E-07 -7.5740 0.26666E-07 -7.5740 0.10000E+01 0.0000 150 S4O6-2 0.59121E-09 -9.2283 0.22979E-11 -11.6387 0.38868E-02 -2.4104 152 ZnCl+ 0.39468E-03 -3.4038 0.92975E-04 -4.0316 0.23557E+00 -0.6279 153 ZnCl2,aq 0.10830E-02 -2.9654 0.10830E-02 -2.9654 0.10000E+01 0.0000 154 ZnCl3- 0.12184E-03 -3.9142 0.25681E-04 -4.5904 0.21077E+00 -0.6762 155 ZnO,aq 0.36118E-07 -7.4423 0.36118E-07 -7.4423 0.10000E+01 0.0000 156 ZnOH+ 0.21970E-05 -5.6582 0.51754E-06 -6.2861 0.23557E+00 -0.6279 158 HZnO2- 0.29178E-09 -9.5349 0.61500E-10 -10.2111 0.21077E+00 -0.6762 Charge balance for all species = 0.2550E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8348358E-05 0.4303816E+01 0.3540420E+04 0.0000 2 H2O 0.1000000E+01 0.5250617E+02 0.7720016E+06 0.0000 3 Cl- 0.1718602E+00 0.6565100E+00 0.1899594E+05 4.2580 4 SO4-- 0.1935921E-03 0.2533161E+00 0.1985999E+05 5.3084 5 HCO3- 0.1765009E-04 0.2676700E+01 0.1332964E+06 0.3027 6 HS- 0.1360547E-03 0.1168130E+01 0.3152958E+05 1.1602 7 H4SiO4 0.7353960E-01 0.7354299E-01 0.5769001E+04 -1.1335 8 Al+++ 0.8154080E-17 0.1653562E-04 0.3641271E+00 -5.4453 9 Ca++ 0.1954046E-05 0.2795077E-03 0.9142527E+01 3.2175 10 Mg++ 0.1178804E-05 0.1720660E-04 0.3414146E+00 2.9112 11 Fe++ 0.1687684E-07 0.6106647E-02 0.2783358E+03 1.0892 12 K+ 0.4700582E-01 0.1263803E+00 0.4033155E+04 3.7394 13 Na+ 0.1554875E+00 0.5585310E+00 0.1047970E+05 4.2201 14 Mn++ 0.6518179E-06 0.1158346E-02 0.5193706E+02 2.6921 15 Zn++ 0.4260152E-09 0.1601745E-02 0.8545513E+02 -0.5087 16 Cu+ 0.2837552E-07 0.1384093E-03 0.7177595E+01 -2.5198 17 Pb++ 0.3490181E-08 0.3428093E-03 0.5796792E+02 0.5195 18 Ag+ 0.3306045E-09 0.8768281E-05 0.7719363E+00 -4.4205 19 Ba++ 0.1351364E-06 0.2213114E-04 0.2480660E+01 2.1390 20 HPO4-- 0.9814092E-09 0.3028677E-05 0.2372441E+00 0.0156 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4270715E+01 -.8352695E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5210234E+02 -.1375567E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2513678E+00 0.3549895E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159146E+01 0.9980676E-03 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.7297735E-01 0.7061697E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1640844E-04 0.6781311E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2773580E-03 0.2505519E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1707426E-04 0.3602392E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.6059679E-02 0.2707075E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254083E+00 0.1805083E-05 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542352E+00 0.3641755E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149436E-02 0.6356710E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1589425E-02 0.7099093E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1373448E-03 0.2622649E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.2196093E-04 0.3341153E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3005382E-05 0.5562118E-05 0.0000000E+00 Chg. balance for solid moles: 0.1342E-17 Mass of aqueous solution: 0.121585E+04 g Temperature = 578.00 C Pressure = 1396.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.8521E-04 -4.070 0.1160E-01 -1.936 0.2509 0.3915E-02 annite 0.5831E-06 -6.234 0.2985E-03 -3.525 0.6455E-02 0.8999E-04 phlogopite 0.1201E-05 -5.921 0.5011E-03 -3.300 0.1084E-01 0.1797E-03 biotite-Mn 0.2119E-07 -7.674 0.1079E-04 -4.967 0.2333E-03 0.3234E-05 apatite-OH 0.1854E-05 -5.732 0.9313E-03 -3.031 0.2014E-01 0.2959E-03 magnetite 0.8144E-03 -3.089 0.1885 -0.725 4.077 0.3625E-01 quartz 0.6921E-01 -1.160 4.158 0.619 89.92 1.570 barite 0.3341E-04 -4.476 0.7798E-02 -2.108 0.1687 0.1741E-02 chalcopyrite 0.2623E-03 -3.581 0.4813E-01 -1.318 1.041 0.1123E-01 sphalerite 0.7099E-03 -3.149 0.6917E-01 -1.160 1.496 0.1692E-01 an30ab70 0.5203E-03 -3.284 0.1389 -0.857 3.004 0.5217E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3230E+00 0.3230E+00 1.0000 -0.491 phlogopite 0.6652E+00 0.6652E+00 1.0000 -0.177 biotite-Mn 0.1174E-01 0.1174E-01 1.0000 -1.930 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.623820 g Volume = 1.693016 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.27 -14.27 0.00 0.000 0.69184E-11 24 annite -0.37 -0.37 0.00 0.000 -0.38916E-11 25 phlogopite 4.16 4.16 0.00 0.000 0.00000E+00 26 biotite-Mn 8.76 8.76 0.00 0.000 0.27674E-10 30 apatite-OH -52.25 -52.25 0.00 0.000 0.00000E+00 106 magnetite 1.45 1.45 0.00 0.000 -0.77832E-11 144 quartz -1.13 -1.13 0.00 0.000 0.00000E+00 237 barite -15.35 -15.35 0.00 0.000 0.00000E+00 240 chalcopyrite -22.81 -22.81 0.00 0.000 0.13837E-10 255 sphalerite -10.75 -10.75 0.00 0.000 0.69184E-11 260 an30ab70 -6.22 -6.22 0.00 0.000 -0.17296E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.28 -0.281 0.10944E+04 2.864 2 CO2,gas -9.54 -11.09 -1.55 -0.518 0.60494E+04 1.592 3 CH4,gas 6.91 -3.85 -10.76 -2.689 0.41894E+05 -7.612 4 H2,gas 5.86 1.81 -4.05 -2.314 0.15772E+05 -0.905 5 H2S,gas -7.95 -10.24 -2.29 -1.144 0.89119E+04 0.857 6 CO,gas -3.48 -9.28 -5.80 -1.786 0.22603E+05 -2.659 7 SO3,gas -7.05 -17.49 -10.43 -2.608 0.40636E+05 -7.289 8 O2,gas 16.61 -3.62 -20.24 -13.490 0.78811E+05 -17.090 9 HCl,gas -5.87 -7.14 -1.27 -0.635 0.49426E+04 -1.269 10 acmite 3.68 2.14 -1.54 -0.160 0.59959E+04 12 akimotoite 5.92 1.78 -4.14 -0.829 0.16138E+05 13 akimotoite-Fe 3.86 -0.04 -3.90 -0.780 0.15197E+05 14 albite-high -4.50 -4.62 -0.12 -0.009 0.48054E+03 15 albite -4.48 -4.62 -0.14 -0.011 0.55922E+03 16 almandine -9.56 -11.02 -1.46 -0.073 0.56839E+04 17 pyrope -3.04 -5.56 -2.52 -0.126 0.98153E+04 18 analcite -2.54 -3.49 -0.95 -0.106 0.37134E+04 19 andalusite -11.66 -12.03 -0.36 -0.036 0.14183E+04 20 andradite 11.20 6.62 -4.58 -0.238 0.17846E+05 21 grossular 0.16 -4.64 -4.80 -0.240 0.18681E+05 27 anorthite -9.39 -9.94 -0.55 -0.042 0.21358E+04 28 anthophyllite 13.56 11.32 -2.24 -0.061 0.87215E+04 29 anthophyllite-Fe 1.16 -1.43 -2.60 -0.070 0.10107E+05 31 apatite-OH-zs -50.12 -52.25 -2.13 -0.164 0.83097E+04 32 apatite-Cl-zs -56.25 -59.39 -3.14 -0.262 0.12223E+05 33 aragonite -4.40 -7.88 -3.48 -1.160 0.13549E+05 34 brucite 5.15 2.91 -2.24 -0.448 0.87290E+04 35 calcite -4.50 -7.88 -3.38 -1.127 0.13163E+05 36 carnegieite-low -0.60 -2.36 -1.76 -0.251 0.68517E+04 37 carnegieite-high -0.53 -2.36 -1.83 -0.262 0.71320E+04 38 carpholite-Mg -8.37 -10.25 -1.88 -0.126 0.73361E+04 39 carpholite-Fe -9.70 -12.07 -2.38 -0.158 0.92508E+04 40 celadonite -1.21 -3.32 -2.11 -0.124 0.82076E+04 41 celadonite-Fe -2.60 -5.14 -2.55 -0.150 0.99166E+04 42 chrysotile 8.90 6.47 -2.43 -0.203 0.94721E+04 44 clinochlore 1.62 0.25 -1.36 -0.043 0.53158E+04 45 daphnite -5.32 -8.86 -3.54 -0.111 0.13785E+05 48 chloritoid-Mg -7.92 -9.12 -1.20 -0.080 0.46804E+04 49 chloritoid-Fe -9.82 -10.94 -1.12 -0.075 0.43770E+04 50 chloritoid-Mn -7.66 -9.34 -1.68 -0.112 0.65470E+04 52 coesite -0.85 -1.13 -0.28 -0.094 0.11019E+04 53 cordierite-H -21.03 -21.62 -0.60 -0.021 0.23275E+04 54 cordierite-Fe -23.52 -25.27 -1.75 -0.060 0.68147E+04 55 cordierite-Mn -19.12 -22.06 -2.94 -0.101 0.11448E+05 56 corundum -10.36 -10.90 -0.53 -0.049 0.20806E+04 58 cristobalite -1.08 -1.13 -0.05 -0.016 0.18924E+03 59 cummingtonite 13.63 11.32 -2.30 -0.062 0.89623E+04 61 cymrite-K -2.83 -5.10 -2.28 -0.190 0.88624E+04 63 diaspore -4.68 -5.45 -0.77 -0.129 0.30052E+04 65 diopside 5.19 3.87 -1.32 -0.132 0.51475E+04 66 hedenbergite 3.79 2.04 -1.75 -0.175 0.68064E+04 68 eastonite -7.83 -9.05 -1.22 -0.047 0.47492E+04 69 enstatite 4.42 3.56 -0.87 -0.087 0.33696E+04 70 clinoenstatite-HiP 4.91 3.56 -1.35 -0.135 0.52674E+04 71 clinoenstatite 4.41 3.56 -0.85 -0.085 0.33147E+04 72 protoenstatite 4.55 3.56 -1.00 -0.100 0.38788E+04 73 epidote -5.67 -7.67 -2.01 -0.097 0.78157E+04 74 clinozoisite -10.91 -13.30 -2.39 -0.109 0.93008E+04 75 epidote-Fe 1.25 -2.04 -3.30 -0.171 0.12845E+05 76 fayalite 1.95 1.04 -0.91 -0.130 0.35317E+04 77 ferrosilite 0.91 -0.09 -1.00 -0.100 0.38925E+04 78 forsterite 5.87 4.69 -1.19 -0.169 0.46177E+04 79 gedrite -12.17 -14.03 -1.86 -0.050 0.72339E+04 81 gibbsite -3.07 -5.45 -2.38 -0.340 0.92741E+04 82 glaucophane 0.32 -2.77 -3.09 -0.084 0.12036E+05 83 glaucophane-Fe -3.65 -8.24 -4.59 -0.124 0.17869E+05 84 goethite 0.99 0.18 -0.81 -0.174 0.31410E+04 86 greenalite 4.12 1.00 -3.13 -0.260 0.12173E+05 87 grunerite 1.71 -1.43 -3.14 -0.085 0.12213E+05 88 halite -0.86 -2.92 -2.06 -1.031 0.80306E+04 89 hematite 0.45 0.36 -0.08 -0.010 0.32753E+03 90 heulandite -12.74 -15.60 -2.86 -0.130 0.11135E+05 91 hercynite -8.85 -9.81 -0.96 -0.064 0.37484E+04 94 jadeite -1.85 -3.49 -1.63 -0.163 0.63657E+04 96 kalsilite -1.22 -2.84 -1.62 -0.231 0.62990E+04 97 kaolinite -10.54 -13.16 -2.62 -0.238 0.10202E+05 98 kyanite -11.51 -12.03 -0.52 -0.052 0.20282E+04 100 laumontite -8.81 -12.21 -3.40 -0.227 0.13240E+05 101 lawsonite -6.65 -9.94 -3.30 -0.220 0.12842E+05 102 leucite -3.01 -3.97 -0.96 -0.096 0.37478E+04 104 lizardite 9.08 6.47 -2.62 -0.218 0.10185E+05 105 magnesite -5.36 -8.18 -2.82 -0.941 0.10995E+05 107 minnesotaite 0.61 -1.26 -1.87 -0.110 0.72948E+04 108 minnesotaite-Mg 6.48 4.21 -2.27 -0.133 0.88388E+04 109 magnesioferrite 4.47 3.27 -1.20 -0.098 0.46642E+04 111 manganosite 5.16 2.69 -2.47 -0.618 0.96294E+04 112 margarite -19.28 -20.84 -1.56 -0.062 0.60644E+04 115 microcline -5.07 -5.10 -0.03 -0.002 0.11136E+03 116 monticellite 8.45 5.00 -3.46 -0.494 0.13473E+05 118 mullite-Si -10.93 -12.03 -1.10 -0.110 0.42668E+04 119 muscovite -15.30 -16.00 -0.70 -0.041 0.27171E+04 120 paragonite -14.62 -15.52 -0.89 -0.053 0.34822E+04 121 nepheline -0.89 -2.36 -1.47 -0.210 0.57136E+04 122 osumilite(2) -14.44 -16.31 -1.86 -0.039 0.72620E+04 123 osumilite-Fe -30.49 -32.63 -2.14 -0.045 0.83263E+04 124 pargasite 2.91 -0.84 -3.75 -0.099 0.14587E+05 125 periclase 5.33 2.91 -2.42 -0.606 0.94403E+04 126 periclase-Fe 2.80 1.09 -1.71 -0.427 0.66551E+04 127 perovskite-Al -8.65 -10.90 -2.24 -0.204 0.87378E+04 132 phlogopite-Na 5.02 4.11 -0.91 -0.051 0.35542E+04 134 prehnite -4.75 -7.86 -3.10 -0.182 0.12077E+05 135 prehnite-Fe 0.88 -2.23 -3.11 -0.187 0.12116E+05 138 px-Mg-tschermaks -7.35 -9.12 -1.77 -0.126 0.68940E+04 139 px-Ca-tschermaks -6.40 -8.81 -2.41 -0.172 0.93886E+04 140 pyrite -21.20 -21.20 0.00 0.000 0.32759E+01 141 pyrrhotite -8.54 -9.15 -0.61 -0.204 0.23877E+04 142 pyrrhotiteFe0.875 -9.27 -9.51 -0.24 -0.089 0.93802E+03 143 pyrophyllite -14.18 -15.42 -1.24 -0.077 0.48198E+04 146 riebeckite 5.75 3.02 -2.73 -0.075 0.10621E+05 147 ringwoodite-Fe 2.94 1.04 -1.89 -0.271 0.73798E+04 148 ringwoodite-Mg 8.99 4.69 -4.30 -0.614 0.16753E+05 149 rhodochrosite -5.26 -8.40 -3.14 -1.046 0.12222E+05 150 rhodonite 2.43 1.56 -0.87 -0.173 0.33748E+04 151 sanidine -4.54 -5.10 -0.56 -0.043 0.21800E+04 153 siderite -7.16 -10.01 -2.85 -0.949 0.11087E+05 154 sillimanite -11.63 -12.03 -0.40 -0.040 0.15439E+04 156 spinel -6.71 -7.99 -1.28 -0.085 0.49676E+04 162 stilpnomelane-Fe -8.11 -12.64 -4.53 -0.135 0.17630E+05 163 stilpnomelane-Mg -1.49 -3.53 -2.04 -0.061 0.79629E+04 164 stishovite 1.79 -1.13 -2.92 -0.972 0.11354E+05 165 sudoite-Fe -19.18 -23.01 -3.83 -0.124 0.14919E+05 166 sudoite -17.01 -19.37 -2.36 -0.076 0.91928E+04 167 sulfur -10.56 -12.05 -1.49 -0.458 0.57978E+04 168 sylvite -0.76 -3.40 -2.64 -1.319 0.10273E+05 169 talc 4.77 4.21 -0.56 -0.033 0.21756E+04 170 talc-Fe 1.99 -1.26 -3.25 -0.191 0.12661E+05 171 talc-tschermaks -6.93 -8.47 -1.54 -0.091 0.59920E+04 173 tephroite 6.26 4.25 -2.01 -0.287 0.78115E+04 176 topaz-H -9.58 -12.03 -2.45 -0.222 0.95302E+04 177 tremolite 14.50 11.94 -2.57 -0.069 0.99980E+04 179 troilite-low -8.44 -9.15 -0.71 -0.236 0.27588E+04 180 tschermakite -10.46 -13.41 -2.96 -0.080 0.11520E+05 183 wadsleyite-Fe 2.79 1.04 -1.74 -0.249 0.67917E+04 184 wadsleyite-Mg 8.06 4.69 -3.37 -0.481 0.13118E+05 185 wairakite -10.63 -12.20 -1.57 -0.092 0.61119E+04 186 walstromite 4.54 2.09 -2.45 -0.491 0.95561E+04 187 wollastonite 4.13 2.09 -2.04 -0.408 0.79532E+04 188 pseudo-wollastonite 4.24 2.09 -2.15 -0.431 0.83927E+04 189 zoisite -10.97 -13.30 -2.33 -0.106 0.90786E+04 192 beidellite-Ca -14.77 -16.31 -1.55 -0.096 0.60212E+04 193 beidellite-H -14.77 -16.84 -2.07 -0.132 0.80707E+04 194 beidellite-K -13.72 -15.61 -1.89 -0.116 0.73731E+04 195 beidellite-Mg -15.05 -16.36 -1.31 -0.081 0.51060E+04 196 beidellite-Na -13.66 -15.45 -1.79 -0.110 0.69854E+04 197 bornite -52.90 -53.37 -0.46 -0.035 0.18050E+04 199 chalcocite -13.74 -15.28 -1.53 -0.383 0.59690E+04 200 covellite -12.25 -13.66 -1.42 -0.540 0.55222E+04 202 montmorillonite-Ca -10.96 -12.13 -1.17 -0.072 0.45619E+04 203 montmorillonite-K -10.20 -11.43 -1.23 -0.075 0.47880E+04 204 montmorillonite-Mg -11.19 -12.18 -0.99 -0.061 0.38460E+04 205 montmorillonite-Na -9.85 -11.27 -1.42 -0.087 0.55376E+04 206 nontronite-Ca -3.71 -5.05 -1.34 -0.087 0.52218E+04 207 nontronite-H -3.73 -5.58 -1.86 -0.125 0.72416E+04 208 nontronite-K -2.67 -4.35 -1.69 -0.108 0.65630E+04 209 nontronite-Mg -3.96 -5.10 -1.15 -0.075 0.44751E+04 210 nontronite-Na -2.60 -4.19 -1.59 -0.102 0.61899E+04 215 gypsum -12.08 -14.27 -2.20 -0.550 0.85613E+04 232 alabandite -6.26 -7.55 -1.29 -0.430 0.50196E+04 234 anglesite -14.46 -16.97 -2.51 -1.255 0.97725E+04 238 boehmite -4.39 -5.45 -1.05 -0.176 0.41061E+04 242 copper,native 1.76 -1.61 -3.37 -1.173 0.13133E+05 244 ferrous-oxide 1.88 1.09 -0.79 -0.198 0.30845E+04 245 galena -9.49 -9.72 -0.23 -0.075 0.87778E+03 246 silver,native 0.52 -3.52 -4.03 -1.403 0.15711E+05 248 litharge 5.21 0.52 -4.70 -1.174 0.18288E+05 256 wurtzite -9.95 -10.75 -0.79 -0.264 0.30886E+04 257 zincite 2.00 -0.51 -2.51 -0.626 0.97594E+04 258 an20ab80 -5.68 -5.68 -0.01 -0.001 0.28787E+02 259 an25ab75 -5.95 -5.95 0.00 0.000 0.26276E+01 261 tr.625ac.25prg.125 8.91 8.06 -0.84 -0.023 0.32889E+04 Calculations done for 578.0000 Deg. C; 1396.0000 bar Temperature changed by -1.000 degrees to 577.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 30 Loop limit = 500 Temperature = 577.00 C Pressure = 1372.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5508E+02 kg liquid = 0.9924E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9962 Stoichiometric ionic strength = .3296212E+01 Osmotic coef. = 0.0000 True ionic strength = .2001675E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.79871E-05 -5.0976 0.18910E-05 -5.7233 0.23676E+00 -0.6257 2 H2O 0.99616E+00 -0.0017 0.99616E+00 -0.0017 3 Cl- 0.16828E+00 -0.7740 0.34951E-01 -1.4565 0.20770E+00 -0.6826 4 SO4-- 0.19649E-03 -3.7067 0.78617E-06 -6.1045 0.40012E-02 -2.3978 5 HCO3- 0.16896E-04 -4.7722 0.37878E-05 -5.4216 0.22419E+00 -0.6494 6 HS- 0.13484E-03 -3.8702 0.28247E-04 -4.5490 0.20947E+00 -0.6789 7 H4SiO4 0.71610E-01 -1.1450 0.71610E-01 -1.1450 0.10000E+01 0.0000 8 Al+++ 0.86724E-17 -17.0619 0.27324E-22 -22.5635 0.31507E-05 -5.5016 9 Ca++ 0.18917E-05 -5.7231 0.60795E-08 -8.2161 0.32138E-02 -2.4930 10 Mg++ 0.11660E-05 -5.9333 0.30683E-08 -8.5131 0.26314E-02 -2.5798 11 Fe++ 0.16601E-07 -7.7799 0.45963E-10 -10.3376 0.27687E-02 -2.5577 12 K+ 0.46134E-01 -1.3360 0.10612E-01 -1.9742 0.23003E+00 -0.6382 13 Na+ 0.15207E+00 -0.8180 0.31994E-01 -1.4949 0.21039E+00 -0.6770 14 Mn++ 0.67759E-06 -6.1690 0.19469E-08 -8.7107 0.28732E-02 -2.5416 15 Zn++ 0.41616E-09 -9.3807 0.11522E-11 -11.9385 0.27687E-02 -2.5577 16 Cu+ 0.26762E-07 -7.5725 0.56151E-08 -8.2506 0.20982E+00 -0.6782 17 Pb++ 0.34200E-08 -8.4660 0.12336E-10 -10.9088 0.36069E-02 -2.4429 18 Ag+ 0.32607E-09 -9.4867 0.73808E-10 -10.1319 0.22636E+00 -0.6452 19 Ba++ 0.12839E-06 -6.8915 0.49800E-09 -9.3028 0.38789E-02 -2.4113 20 HPO4-- 0.99841E-09 -9.0007 0.40152E-11 -11.3963 0.40216E-02 -2.3956 21 HSiO3- 0.17770E-05 -5.7503 0.36907E-06 -6.4329 0.20770E+00 -0.6826 22 Ca(HSiO3)+ 0.86658E-08 -8.0622 0.20113E-08 -8.6965 0.23210E+00 -0.6343 23 Mg(HSiO3)+ 0.12266E-08 -8.9113 0.28468E-09 -9.5456 0.23210E+00 -0.6343 24 NaHSiO3,aq 0.16026E-05 -5.7952 0.16026E-05 -5.7952 0.10000E+01 0.0000 28 AgCl,aq 0.81965E-07 -7.0864 0.81965E-07 -7.0864 0.10000E+01 0.0000 29 AgCl2- 0.49658E-05 -5.3040 0.10314E-05 -5.9866 0.20770E+00 -0.6826 30 AgCl3-2 0.21594E-05 -5.6657 0.79890E-08 -8.0975 0.36996E-02 -2.4318 31 AgCl4-3 0.15545E-05 -5.8084 0.42147E-11 -11.3752 0.27113E-05 -5.5668 34 Ag(HS),aq 0.94121E-09 -9.0263 0.94121E-09 -9.0263 0.10000E+01 0.0000 35 Ag(HS)2- 0.48639E-08 -8.3130 0.10102E-08 -8.9956 0.20770E+00 -0.6826 36 AlO+ 0.10008E-10 -10.9996 0.23229E-11 -11.6340 0.23210E+00 -0.6343 38 HAlO2,aq 0.44052E-08 -8.3560 0.44052E-08 -8.3560 0.10000E+01 0.0000 39 AlO2- 0.16318E-04 -4.7873 0.29554E-05 -5.5294 0.18111E+00 -0.7421 41 Ba(HCO3)+ 0.54965E-06 -6.2599 0.13283E-06 -6.8767 0.24167E+00 -0.6168 42 BaCl+ 0.20045E-04 -4.6980 0.46524E-05 -5.3323 0.23210E+00 -0.6343 43 CH4,aq 0.17778E-08 -8.7501 0.21391E-08 -8.6698 0.12032E+01 0.0803 48 CO,aq 0.67249E-03 -3.1723 0.67249E-03 -3.1723 0.10000E+01 0.0000 49 CO2,aq 0.26759E+01 0.4275 0.32197E+01 0.5078 0.12032E+01 0.0803 50 CO3-2 0.43885E-10 -10.3577 0.16236E-12 -12.7895 0.36996E-02 -2.4318 51 CaCO3,aq 0.14048E-10 -10.8524 0.14048E-10 -10.8524 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.29721E-06 -6.5269 0.68982E-07 -7.1613 0.23210E+00 -0.6343 53 CaCl+ 0.15033E-03 -3.8230 0.34892E-04 -4.4573 0.23210E+00 -0.6343 54 CaCl2,aq 0.11463E-03 -3.9407 0.11463E-03 -3.9407 0.10000E+01 0.0000 55 CaOH+ 0.25972E-06 -6.5855 0.60281E-07 -7.2198 0.23210E+00 -0.6343 56 CaSO4,aq 0.14553E-06 -6.8371 0.14553E-06 -6.8371 0.10000E+01 0.0000 57 HCl,aq 0.17345E-02 -2.7608 0.17345E-02 -2.7608 0.10000E+01 0.0000 66 CuCl,aq 0.27125E-04 -4.5666 0.27125E-04 -4.5666 0.10000E+01 0.0000 67 CuCl2- 0.10446E-03 -3.9810 0.21697E-04 -4.6636 0.20770E+00 -0.6826 68 CuCl3-2 0.24308E-05 -5.6142 0.89930E-08 -8.0461 0.36996E-02 -2.4318 74 FeCl+ 0.40859E-06 -6.3887 0.94832E-07 -7.0230 0.23210E+00 -0.6343 75 FeCl2,aq 0.58460E-02 -2.2331 0.58460E-02 -2.2331 0.10000E+01 0.0000 77 FeO,aq 0.76858E-07 -7.1143 0.76858E-07 -7.1143 0.10000E+01 0.0000 78 FeOH+ 0.32224E-07 -7.4918 0.74792E-08 -8.1261 0.23210E+00 -0.6343 79 HFeO2- 0.96307E-08 -8.0163 0.20003E-08 -8.6989 0.20770E+00 -0.6826 82 FeO2- 0.63123E-08 -8.1998 0.13110E-08 -8.8824 0.20770E+00 -0.6826 83 HFeO2,aq 0.27591E-09 -9.5592 0.27591E-09 -9.5592 0.10000E+01 0.0000 84 H2,aq 0.46066E-02 -2.3366 0.55428E-02 -2.2563 0.12032E+01 0.0803 85 KCl,aq 0.63115E-01 -1.1999 0.63115E-01 -1.1999 0.10000E+01 0.0000 86 KHSO4,aq 0.12981E-01 -1.8867 0.12981E-01 -1.8867 0.10000E+01 0.0000 87 KOH,aq 0.11226E-05 -5.9498 0.11226E-05 -5.9498 0.10000E+01 0.0000 88 KSO4- 0.41433E-02 -2.3826 0.86056E-03 -3.0652 0.20770E+00 -0.6826 90 Mg(HCO3)+ 0.58190E-07 -7.2351 0.13506E-07 -7.8695 0.23210E+00 -0.6343 91 MgCl+ 0.14992E-04 -4.8242 0.34795E-05 -5.4585 0.23210E+00 -0.6343 92 MgOH+ 0.54384E-06 -6.2645 0.12622E-06 -6.8989 0.23210E+00 -0.6343 94 MnO,aq 0.51186E-07 -7.2909 0.51186E-07 -7.2909 0.10000E+01 0.0000 95 MnOH+ 0.16341E-06 -6.7867 0.37927E-07 -7.4211 0.23210E+00 -0.6343 97 HMnO2- 0.28405E-10 -10.5466 0.58995E-11 -11.2292 0.20770E+00 -0.6826 100 MnCl+ 0.11573E-02 -2.9365 0.26861E-03 -3.5709 0.23210E+00 -0.6343 101 MnSO4,aq 0.56346E-07 -7.2491 0.56346E-07 -7.2491 0.10000E+01 0.0000 102 NaCl,aq 0.40643E+00 -0.3910 0.40643E+00 -0.3910 0.10000E+01 0.0000 103 NaOH,aq 0.15680E-05 -5.8047 0.15680E-05 -5.8047 0.10000E+01 0.0000 105 OH- 0.84133E-05 -5.0750 0.15237E-05 -5.8171 0.18111E+00 -0.7421 110 HPO3-2 0.12251E-10 -10.9118 0.45324E-13 -13.3437 0.36996E-02 -2.4318 111 H3PO3,aq 0.10735E-09 -9.9692 0.10735E-09 -9.9692 0.10000E+01 0.0000 112 H2PO3- 0.31955E-08 -8.4955 0.66369E-09 -9.1780 0.20770E+00 -0.6826 113 H3PO4,aq 0.93112E-06 -6.0310 0.93112E-06 -6.0310 0.10000E+01 0.0000 114 H2PO4- 0.15196E-05 -5.8183 0.33229E-06 -6.4785 0.21867E+00 -0.6602 116 H4P2O7,aq 0.75256E-10 -10.1235 0.75256E-10 -10.1235 0.10000E+01 0.0000 117 H3P2O7- 0.92986E-09 -9.0316 0.19313E-09 -9.7142 0.20770E+00 -0.6826 118 H2P2O7-2 0.25709E-06 -6.5899 0.95111E-09 -9.0218 0.36996E-02 -2.4318 119 HP2O7-3 0.14929E-07 -7.8260 0.40478E-13 -13.3928 0.27113E-05 -5.5668 121 PbCl+ 0.18530E-05 -5.7321 0.43008E-06 -6.3665 0.23210E+00 -0.6343 122 PbCl2,aq 0.86934E-04 -4.0608 0.86934E-04 -4.0608 0.10000E+01 0.0000 123 PbCl3- 0.10920E-03 -3.9618 0.22681E-04 -4.6443 0.20770E+00 -0.6826 124 PbCl4-2 0.24677E-04 -4.6077 0.91293E-07 -7.0396 0.36996E-02 -2.4318 125 PbO,aq 0.47545E-08 -8.3229 0.47545E-08 -8.3229 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10873E-03 -3.9636 0.10873E-03 -3.9636 0.10000E+01 0.0000 128 Pb(HS)3- 0.11384E-04 -4.9437 0.23645E-05 -5.6263 0.20770E+00 -0.6826 129 H2S,aq 0.10559E+01 0.0236 0.12704E+01 0.1040 0.12032E+01 0.0803 130 S2-2 0.14440E-07 -7.8404 0.53423E-10 -10.2723 0.36996E-02 -2.4318 131 S3-2 0.14464E-08 -8.8397 0.53510E-11 -11.2716 0.36996E-02 -2.4318 132 S3- 0.16023E-01 -1.7952 0.33280E-02 -2.4778 0.20770E+00 -0.6826 133 S4-2 0.12161E-09 -9.9150 0.44990E-12 -12.3469 0.36996E-02 -2.4318 135 SO2,aq 0.28911E+00 -0.5389 0.28911E+00 -0.5389 0.10000E+01 0.0000 136 SO3-2 0.59838E-09 -9.2230 0.35217E-11 -11.4532 0.58854E-02 -2.2302 137 HSO3- 0.34713E-03 -3.4595 0.72096E-04 -4.1421 0.20770E+00 -0.6826 138 HSO4- 0.10158E-01 -1.9932 0.24212E-02 -2.6160 0.23836E+00 -0.6228 140 S2O3-2 0.52467E-06 -6.2801 0.19411E-08 -8.7120 0.36996E-02 -2.4318 141 HS2O3- 0.53758E-06 -6.2696 0.11165E-06 -6.9521 0.20770E+00 -0.6826 142 H2S2O3,aq 0.26939E-07 -7.5696 0.26939E-07 -7.5696 0.10000E+01 0.0000 150 S4O6-2 0.57404E-09 -9.2411 0.21237E-11 -11.6729 0.36996E-02 -2.4318 152 ZnCl+ 0.36731E-03 -3.4350 0.85252E-04 -4.0693 0.23210E+00 -0.6343 153 ZnCl2,aq 0.10391E-02 -2.9834 0.10391E-02 -2.9834 0.10000E+01 0.0000 154 ZnCl3- 0.11336E-03 -3.9456 0.23544E-04 -4.6281 0.20770E+00 -0.6826 155 ZnO,aq 0.35645E-07 -7.4480 0.35645E-07 -7.4480 0.10000E+01 0.0000 156 ZnOH+ 0.20800E-05 -5.6819 0.48277E-06 -6.3163 0.23210E+00 -0.6343 158 HZnO2- 0.28779E-09 -9.5409 0.59772E-10 -10.2235 0.20770E+00 -0.6826 Charge balance for all species = 0.2550E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7987055E-05 0.4304179E+01 0.3541315E+04 0.0000 2 H2O 0.1000000E+01 0.5250718E+02 0.7721465E+06 0.0000 3 Cl- 0.1682781E+00 0.6564776E+00 0.1899820E+05 4.2668 4 SO4-- 0.1964857E-03 0.2532685E+00 0.1985960E+05 5.3421 5 HCO3- 0.1689571E-04 0.2676568E+01 0.1333123E+06 0.3017 6 HS- 0.1348450E-03 0.1168006E+01 0.3153153E+05 1.1743 7 H4SiO4 0.7161048E-01 0.7161387E-01 0.5618620E+04 -1.1450 8 Al+++ 0.8672354E-17 0.1632241E-04 0.3594927E+00 -5.3935 9 Ca++ 0.1891697E-05 0.2675685E-03 0.8753476E+01 3.2305 10 Mg++ 0.1166019E-05 0.1676081E-04 0.3326253E+00 2.9335 11 Fe++ 0.1660105E-07 0.5846550E-02 0.2665257E+03 1.1090 12 K+ 0.4613386E-01 0.1263739E+00 0.4033628E+04 3.7491 13 Na+ 0.1520678E+00 0.5585034E+00 0.1048095E+05 4.2284 14 Mn++ 0.6775949E-06 0.1158276E-02 0.5194270E+02 2.7360 15 Zn++ 0.4161570E-09 0.1521848E-02 0.8120622E+02 -0.4919 16 Cu+ 0.2676230E-07 0.1340467E-03 0.6952528E+01 -2.5273 17 Pb++ 0.3419978E-08 0.3427924E-03 0.5797483E+02 0.5378 18 Ag+ 0.3260671E-09 0.8767848E-05 0.7720283E+00 -4.4086 19 Ba++ 0.1283868E-06 0.2072292E-04 0.2323205E+01 2.1438 20 HPO4-- 0.9984082E-09 0.3001095E-05 0.2351232E+00 0.0503 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4271286E+01 -.8923341E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5210591E+02 -.1411258E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2513330E+00 0.3898239E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1159080E+01 0.1064275E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.7106658E-01 0.7252774E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1619767E-04 0.6783419E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2655237E-03 0.2623862E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1663272E-04 0.4043929E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.5801869E-02 0.2964885E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254081E+00 0.2030670E-05 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542352E+00 0.3641676E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149424E-02 0.7571138E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1510218E-02 0.7891170E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1330222E-03 0.2665875E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.2056455E-04 0.3480790E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2978160E-05 0.5589340E-05 0.0000000E+00 Chg. balance for solid moles: 0.7606E-18 Mass of aqueous solution: 0.121571E+04 g Temperature = 577.00 C Pressure = 1372.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.9700E-04 -4.013 0.1321E-01 -1.879 0.2769 0.4457E-02 annite 0.6575E-06 -6.182 0.3365E-03 -3.473 0.7057E-02 0.1015E-03 phlogopite 0.1348E-05 -5.870 0.5625E-03 -3.250 0.1180E-01 0.2017E-03 biotite-Mn 0.2524E-07 -7.598 0.1285E-04 -4.891 0.2695E-03 0.3852E-05 apatite-OH 0.1863E-05 -5.730 0.9359E-03 -3.029 0.1963E-01 0.2974E-03 magnetite 0.8988E-03 -3.046 0.2081 -0.682 4.363 0.4001E-01 quartz 0.7112E-01 -1.148 4.273 0.631 89.60 1.614 barite 0.3481E-04 -4.458 0.8124E-02 -2.090 0.1704 0.1813E-02 chalcopyrite 0.2666E-03 -3.574 0.4892E-01 -1.311 1.026 0.1142E-01 sphalerite 0.7891E-03 -3.103 0.7688E-01 -1.114 1.612 0.1880E-01 an30ab70 0.5202E-03 -3.284 0.1389 -0.857 2.913 0.5216E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3238E+00 0.3238E+00 1.0000 -0.490 phlogopite 0.6638E+00 0.6638E+00 1.0000 -0.178 biotite-Mn 0.1243E-01 0.1243E-01 1.0000 -1.906 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.768669 g Volume = 1.742834 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.32 -14.32 0.00 0.000 0.00000E+00 24 annite -0.28 -0.28 0.00 0.000 -0.12957E-10 25 phlogopite 4.25 4.25 0.00 0.000 0.17276E-10 26 biotite-Mn 8.85 8.85 0.00 0.000 0.27641E-10 30 apatite-OH -52.38 -52.38 0.00 0.000 -0.27641E-10 106 magnetite 1.50 1.50 0.00 0.000 0.34551E-11 144 quartz -1.14 -1.14 0.00 0.000 0.00000E+00 237 barite -15.41 -15.41 0.00 0.000 -0.69103E-11 240 chalcopyrite -22.87 -22.87 0.00 0.000 0.13821E-10 255 sphalerite -10.76 -10.76 0.00 0.000 0.00000E+00 260 an30ab70 -6.17 -6.17 0.00 0.000 0.13821E-10 140 pyrite -21.25 -21.25 0.00 0.000 -0.16137E+01 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.28 -0.280 0.10897E+04 2.857 2 CO2,gas -9.58 -11.14 -1.56 -0.521 0.60860E+04 1.573 3 CH4,gas 6.91 -3.87 -10.77 -2.694 0.41915E+05 -7.637 4 H2,gas 5.87 1.82 -4.05 -2.315 0.15757E+05 -0.913 5 H2S,gas -7.98 -10.27 -2.29 -1.145 0.89115E+04 0.847 6 CO,gas -3.50 -9.32 -5.82 -1.790 0.22637E+05 -2.682 7 SO3,gas -7.10 -17.55 -10.45 -2.612 0.40649E+05 -7.312 8 O2,gas 16.62 -3.64 -20.26 -13.507 0.78814E+05 -17.123 9 HCl,gas -5.89 -7.18 -1.29 -0.643 0.50046E+04 -1.286 10 acmite 3.67 2.14 -1.53 -0.159 0.59603E+04 12 akimotoite 5.94 1.79 -4.15 -0.830 0.16152E+05 13 akimotoite-Fe 3.87 -0.03 -3.91 -0.782 0.15202E+05 14 albite-high -4.47 -4.59 -0.12 -0.009 0.46496E+03 15 albite -4.45 -4.59 -0.14 -0.011 0.53983E+03 16 almandine -9.42 -10.90 -1.48 -0.074 0.57428E+04 17 pyrope -2.88 -5.42 -2.55 -0.127 0.99030E+04 18 analcite -2.50 -3.45 -0.95 -0.106 0.36994E+04 19 andalusite -11.56 -11.93 -0.37 -0.037 0.14581E+04 20 andradite 11.25 6.66 -4.59 -0.238 0.17854E+05 21 grossular 0.28 -4.53 -4.81 -0.241 0.18729E+05 27 anorthite -9.29 -9.85 -0.56 -0.043 0.21771E+04 28 anthophyllite 13.65 11.39 -2.26 -0.061 0.88039E+04 29 anthophyllite-Fe 1.22 -1.38 -2.60 -0.070 0.10120E+05 31 apatite-OH-zs -50.24 -52.38 -2.14 -0.164 0.83119E+04 32 apatite-Cl-zs -56.41 -59.56 -3.15 -0.262 0.12243E+05 33 aragonite -4.42 -7.91 -3.49 -1.164 0.13585E+05 34 brucite 5.18 2.93 -2.25 -0.449 0.87400E+04 35 calcite -4.52 -7.91 -3.39 -1.131 0.13198E+05 36 carnegieite-low -0.55 -2.31 -1.76 -0.251 0.68326E+04 37 carnegieite-high -0.48 -2.31 -1.83 -0.261 0.71148E+04 38 carpholite-Mg -8.25 -10.15 -1.90 -0.127 0.73842E+04 39 carpholite-Fe -9.58 -11.97 -2.39 -0.159 0.92911E+04 40 celadonite -1.18 -3.28 -2.11 -0.124 0.81951E+04 41 celadonite-Fe -2.56 -5.11 -2.54 -0.150 0.98972E+04 42 chrysotile 8.95 6.51 -2.44 -0.204 0.94999E+04 44 clinochlore 1.82 0.44 -1.39 -0.043 0.53960E+04 45 daphnite -5.13 -8.69 -3.55 -0.111 0.13825E+05 48 chloritoid-Mg -7.79 -9.00 -1.22 -0.081 0.47293E+04 49 chloritoid-Fe -9.69 -10.83 -1.13 -0.076 0.44142E+04 50 chloritoid-Mn -7.53 -9.20 -1.67 -0.111 0.64845E+04 52 coesite -0.86 -1.14 -0.28 -0.095 0.11029E+04 53 cordierite-H -20.81 -21.43 -0.62 -0.022 0.24309E+04 54 cordierite-Fe -23.31 -25.08 -1.77 -0.061 0.68848E+04 55 cordierite-Mn -18.91 -21.82 -2.91 -0.100 0.11317E+05 56 corundum -10.25 -10.79 -0.55 -0.050 0.21215E+04 58 cristobalite -1.09 -1.14 -0.05 -0.016 0.18765E+03 59 cummingtonite 13.71 11.39 -2.33 -0.063 0.90465E+04 61 cymrite-K -2.80 -5.07 -2.27 -0.189 0.88458E+04 63 diaspore -4.62 -5.40 -0.78 -0.130 0.30229E+04 65 diopside 5.20 3.88 -1.33 -0.133 0.51641E+04 66 hedenbergite 3.80 2.05 -1.75 -0.175 0.68147E+04 68 eastonite -7.63 -8.86 -1.23 -0.047 0.47846E+04 69 enstatite 4.45 3.58 -0.87 -0.087 0.33952E+04 70 clinoenstatite-HiP 4.94 3.58 -1.36 -0.136 0.52941E+04 71 clinoenstatite 4.44 3.58 -0.86 -0.086 0.33401E+04 72 protoenstatite 4.58 3.58 -1.00 -0.100 0.39047E+04 73 epidote -5.54 -7.56 -2.02 -0.098 0.78628E+04 74 clinozoisite -10.75 -13.16 -2.41 -0.109 0.93689E+04 75 epidote-Fe 1.34 -1.97 -3.31 -0.172 0.12868E+05 76 fayalite 1.98 1.07 -0.91 -0.130 0.35382E+04 77 ferrosilite 0.93 -0.07 -1.00 -0.100 0.38997E+04 78 forsterite 5.92 4.72 -1.19 -0.170 0.46415E+04 79 gedrite -11.88 -13.78 -1.90 -0.051 0.73738E+04 81 gibbsite -3.01 -5.40 -2.39 -0.341 0.92918E+04 82 glaucophane 0.42 -2.68 -3.09 -0.084 0.12029E+05 83 glaucophane-Fe -3.57 -8.15 -4.58 -0.124 0.17835E+05 84 goethite 1.00 0.20 -0.81 -0.175 0.31401E+04 86 greenalite 4.16 1.04 -3.13 -0.261 0.12170E+05 87 grunerite 1.76 -1.38 -3.14 -0.085 0.12229E+05 88 halite -0.89 -2.95 -2.06 -1.030 0.80119E+04 89 hematite 0.48 0.40 -0.08 -0.010 0.32505E+03 90 heulandite -12.69 -15.57 -2.88 -0.131 0.11197E+05 91 hercynite -8.71 -9.68 -0.97 -0.065 0.37925E+04 94 jadeite -1.82 -3.45 -1.63 -0.163 0.63488E+04 96 kalsilite -1.18 -2.79 -1.61 -0.230 0.62750E+04 97 kaolinite -10.45 -13.08 -2.63 -0.239 0.10228E+05 98 kyanite -11.40 -11.93 -0.53 -0.053 0.20695E+04 100 laumontite -8.72 -12.14 -3.42 -0.228 0.13285E+05 101 lawsonite -6.54 -9.85 -3.31 -0.221 0.12886E+05 102 leucite -2.97 -3.93 -0.96 -0.096 0.37241E+04 104 lizardite 9.13 6.51 -2.62 -0.219 0.10209E+05 105 magnesite -5.37 -8.21 -2.84 -0.946 0.11038E+05 107 minnesotaite 0.63 -1.25 -1.87 -0.110 0.72939E+04 108 minnesotaite-Mg 6.51 4.23 -2.28 -0.134 0.88648E+04 109 magnesioferrite 4.53 3.33 -1.20 -0.098 0.46733E+04 111 manganosite 5.18 2.73 -2.45 -0.613 0.95317E+04 112 margarite -19.06 -20.64 -1.58 -0.063 0.61458E+04 115 microcline -5.05 -5.07 -0.02 -0.002 0.83318E+02 116 monticellite 8.49 5.02 -3.47 -0.495 0.13487E+05 118 mullite-Si -10.83 -11.93 -1.11 -0.111 0.43088E+04 119 muscovite -15.16 -15.87 -0.70 -0.041 0.27318E+04 120 paragonite -14.49 -15.39 -0.90 -0.053 0.35036E+04 121 nepheline -0.85 -2.31 -1.46 -0.209 0.56940E+04 122 osumilite(2) -14.33 -16.20 -1.88 -0.039 0.73046E+04 123 osumilite-Fe -30.28 -32.43 -2.15 -0.045 0.83771E+04 124 pargasite 3.14 -0.63 -3.77 -0.099 0.14675E+05 125 periclase 5.36 2.93 -2.43 -0.607 0.94519E+04 126 periclase-Fe 2.82 1.11 -1.71 -0.428 0.66592E+04 127 perovskite-Al -8.54 -10.79 -2.26 -0.205 0.87790E+04 132 phlogopite-Na 5.12 4.20 -0.92 -0.051 0.35689E+04 134 prehnite -4.65 -7.76 -3.12 -0.183 0.12121E+05 135 prehnite-Fe 0.95 -2.17 -3.12 -0.188 0.12137E+05 138 px-Mg-tschermaks -7.22 -9.00 -1.79 -0.128 0.69488E+04 139 px-Ca-tschermaks -6.28 -8.70 -2.42 -0.173 0.94335E+04 141 pyrrhotite -8.55 -9.16 -0.61 -0.205 0.23892E+04 142 pyrrhotiteFe0.875 -9.29 -9.53 -0.24 -0.089 0.93991E+03 143 pyrophyllite -14.11 -15.36 -1.25 -0.078 0.48564E+04 146 riebeckite 5.75 3.04 -2.71 -0.075 0.10549E+05 147 ringwoodite-Fe 2.97 1.07 -1.90 -0.271 0.73850E+04 148 ringwoodite-Mg 9.03 4.72 -4.31 -0.616 0.16776E+05 149 rhodochrosite -5.28 -8.41 -3.12 -1.041 0.12154E+05 150 rhodonite 2.44 1.59 -0.84 -0.169 0.32780E+04 151 sanidine -4.52 -5.07 -0.55 -0.043 0.21519E+04 153 siderite -7.18 -10.04 -2.86 -0.953 0.11120E+05 154 sillimanite -11.53 -11.93 -0.41 -0.041 0.15848E+04 156 spinel -6.57 -7.86 -1.29 -0.086 0.50190E+04 162 stilpnomelane-Fe -7.99 -12.53 -4.54 -0.135 0.17654E+05 163 stilpnomelane-Mg -1.33 -3.40 -2.07 -0.062 0.80480E+04 164 stishovite 1.78 -1.14 -2.92 -0.973 0.11355E+05 165 sudoite-Fe -18.94 -22.80 -3.86 -0.125 0.15016E+05 166 sudoite -16.76 -19.15 -2.39 -0.077 0.93066E+04 167 sulfur -10.60 -12.09 -1.49 -0.459 0.57978E+04 168 sylvite -0.80 -3.43 -2.63 -1.317 0.10246E+05 169 talc 4.79 4.23 -0.57 -0.033 0.22036E+04 170 talc-Fe 2.01 -1.25 -3.26 -0.191 0.12663E+05 171 talc-tschermaks -6.80 -8.36 -1.56 -0.091 0.60493E+04 173 tephroite 6.28 4.33 -1.96 -0.280 0.76153E+04 176 topaz-H -9.48 -11.94 -2.46 -0.224 0.95675E+04 177 tremolite 14.57 11.98 -2.59 -0.070 0.10059E+05 179 troilite-low -8.45 -9.16 -0.71 -0.236 0.27586E+04 180 tschermakite -10.19 -13.18 -2.99 -0.081 0.11637E+05 183 wadsleyite-Fe 2.82 1.07 -1.75 -0.250 0.67983E+04 184 wadsleyite-Mg 8.10 4.72 -3.38 -0.483 0.13143E+05 185 wairakite -10.55 -12.13 -1.58 -0.093 0.61475E+04 186 walstromite 4.54 2.09 -2.46 -0.491 0.95597E+04 187 wollastonite 4.13 2.09 -2.05 -0.409 0.79554E+04 188 pseudo-wollastonite 4.25 2.09 -2.16 -0.432 0.83958E+04 189 zoisite -10.80 -13.16 -2.35 -0.107 0.91485E+04 192 beidellite-Ca -14.67 -16.23 -1.56 -0.096 0.60650E+04 193 beidellite-H -14.68 -16.76 -2.09 -0.133 0.81131E+04 194 beidellite-K -13.62 -15.53 -1.90 -0.117 0.74015E+04 195 beidellite-Mg -14.96 -16.28 -1.32 -0.082 0.51542E+04 196 beidellite-Na -13.57 -15.37 -1.80 -0.110 0.70161E+04 197 bornite -53.06 -53.53 -0.47 -0.035 0.18122E+04 199 chalcocite -13.79 -15.33 -1.53 -0.384 0.59699E+04 200 covellite -12.29 -13.71 -1.42 -0.540 0.55180E+04 202 montmorillonite-Ca -10.90 -12.08 -1.18 -0.073 0.45953E+04 203 montmorillonite-K -10.14 -11.38 -1.24 -0.076 0.48094E+04 204 montmorillonite-Mg -11.13 -12.13 -1.00 -0.062 0.38805E+04 205 montmorillonite-Na -9.79 -11.22 -1.43 -0.087 0.55562E+04 206 nontronite-Ca -3.70 -5.04 -1.34 -0.087 0.52247E+04 207 nontronite-H -3.72 -5.58 -1.86 -0.125 0.72437E+04 208 nontronite-K -2.66 -4.34 -1.68 -0.108 0.65511E+04 209 nontronite-Mg -3.94 -5.09 -1.15 -0.075 0.44804E+04 210 nontronite-Na -2.59 -4.18 -1.59 -0.102 0.61798E+04 215 gypsum -12.12 -14.32 -2.20 -0.551 0.85697E+04 232 alabandite -6.27 -7.54 -1.27 -0.422 0.49230E+04 234 anglesite -14.52 -17.01 -2.50 -1.249 0.97153E+04 238 boehmite -4.34 -5.40 -1.06 -0.177 0.41250E+04 242 copper,native 1.76 -1.62 -3.37 -1.174 0.13128E+05 244 ferrous-oxide 1.90 1.11 -0.79 -0.199 0.30893E+04 245 galena -9.52 -9.73 -0.21 -0.070 0.81883E+03 246 silver,native 0.52 -3.50 -4.01 -1.396 0.15617E+05 248 litharge 5.22 0.54 -4.69 -1.171 0.18228E+05 256 wurtzite -9.97 -10.76 -0.79 -0.265 0.30889E+04 257 zincite 2.02 -0.49 -2.51 -0.627 0.97614E+04 258 an20ab80 -5.64 -5.64 -0.01 0.000 0.22338E+02 259 an25ab75 -5.91 -5.91 0.00 0.000 -0.65463E+00 261 tr.625ac.25prg.125 8.99 8.12 -0.86 -0.023 0.33542E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 23 Loop limit = 500 Temperature = 577.00 C Pressure = 1372.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5508E+02 kg liquid = 0.9924E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9962 Stoichiometric ionic strength = .3295760E+01 Osmotic coef. = 0.0000 True ionic strength = .2001529E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.79840E-05 -5.0978 0.18904E-05 -5.7235 0.23677E+00 -0.6257 2 H2O 0.99616E+00 -0.0017 0.99616E+00 -0.0017 3 Cl- 0.16828E+00 -0.7740 0.34952E-01 -1.4565 0.20771E+00 -0.6826 4 SO4-- 0.19656E-03 -3.7065 0.78660E-06 -6.1042 0.40018E-02 -2.3977 5 HCO3- 0.16900E-04 -4.7721 0.37889E-05 -5.4215 0.22420E+00 -0.6494 6 HS- 0.13482E-03 -3.8703 0.28242E-04 -4.5491 0.20948E+00 -0.6788 7 H4SiO4 0.71611E-01 -1.1450 0.71611E-01 -1.1450 0.10000E+01 0.0000 8 Al+++ 0.86591E-17 -17.0625 0.27291E-22 -22.5640 0.31518E-05 -5.5014 9 Ca++ 0.18904E-05 -5.7234 0.60762E-08 -8.2164 0.32143E-02 -2.4929 10 Mg++ 0.11650E-05 -5.9337 0.30661E-08 -8.5134 0.26318E-02 -2.5797 11 Fe++ 0.16587E-07 -7.7802 0.45931E-10 -10.3379 0.27691E-02 -2.5577 12 K+ 0.46130E-01 -1.3360 0.10612E-01 -1.9742 0.23004E+00 -0.6382 13 Na+ 0.15206E+00 -0.8180 0.31993E-01 -1.4949 0.21040E+00 -0.6770 14 Mn++ 0.67749E-06 -6.1691 0.19469E-08 -8.7107 0.28737E-02 -2.5416 15 Zn++ 0.41602E-09 -9.3809 0.11520E-11 -11.9385 0.27691E-02 -2.5577 16 Cu+ 0.26779E-07 -7.5722 0.56189E-08 -8.2503 0.20983E+00 -0.6781 17 Pb++ 0.34198E-08 -8.4660 0.12337E-10 -10.9088 0.36074E-02 -2.4428 18 Ag+ 0.32606E-09 -9.4867 0.73810E-10 -10.1319 0.22637E+00 -0.6452 19 Ba++ 0.12830E-06 -6.8918 0.49774E-09 -9.3030 0.38795E-02 -2.4112 20 HPO4-- 0.99871E-09 -9.0006 0.40170E-11 -11.3961 0.40222E-02 -2.3955 21 HSiO3- 0.17775E-05 -5.7502 0.36919E-06 -6.4327 0.20771E+00 -0.6826 22 Ca(HSiO3)+ 0.86637E-08 -8.0623 0.20109E-08 -8.6966 0.23211E+00 -0.6343 23 Mg(HSiO3)+ 0.12261E-08 -8.9115 0.28458E-09 -9.5458 0.23211E+00 -0.6343 24 NaHSiO3,aq 0.16031E-05 -5.7950 0.16031E-05 -5.7950 0.10000E+01 0.0000 28 AgCl,aq 0.81970E-07 -7.0863 0.81970E-07 -7.0863 0.10000E+01 0.0000 29 AgCl2- 0.49661E-05 -5.3040 0.10315E-05 -5.9865 0.20771E+00 -0.6826 30 AgCl3-2 0.21594E-05 -5.6657 0.79900E-08 -8.0975 0.37001E-02 -2.4318 31 AgCl4-3 0.15542E-05 -5.8085 0.42154E-11 -11.3752 0.27122E-05 -5.5667 34 Ag(HS),aq 0.94107E-09 -9.0264 0.94107E-09 -9.0264 0.10000E+01 0.0000 35 Ag(HS)2- 0.48621E-08 -8.3132 0.10099E-08 -8.9957 0.20771E+00 -0.6826 36 AlO+ 0.10003E-10 -10.9999 0.23217E-11 -11.6342 0.23211E+00 -0.6343 38 HAlO2,aq 0.44043E-08 -8.3561 0.44043E-08 -8.3561 0.10000E+01 0.0000 39 AlO2- 0.16319E-04 -4.7873 0.29558E-05 -5.5293 0.18112E+00 -0.7420 41 Ba(HCO3)+ 0.54950E-06 -6.2600 0.13280E-06 -6.8768 0.24168E+00 -0.6168 42 BaCl+ 0.20034E-04 -4.6982 0.46500E-05 -5.3325 0.23211E+00 -0.6343 43 CH4,aq 0.17771E-08 -8.7503 0.21382E-08 -8.6699 0.12032E+01 0.0803 48 CO,aq 0.67241E-03 -3.1724 0.67241E-03 -3.1724 0.10000E+01 0.0000 49 CO2,aq 0.26759E+01 0.4275 0.32196E+01 0.5078 0.12032E+01 0.0803 50 CO3-2 0.43907E-10 -10.3575 0.16246E-12 -12.7893 0.37001E-02 -2.4318 51 CaCO3,aq 0.14050E-10 -10.8523 0.14050E-10 -10.8523 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.29713E-06 -6.5271 0.68967E-07 -7.1614 0.23211E+00 -0.6343 53 CaCl+ 0.15025E-03 -3.8232 0.34874E-04 -4.4575 0.23211E+00 -0.6343 54 CaCl2,aq 0.11458E-03 -3.9409 0.11458E-03 -3.9409 0.10000E+01 0.0000 55 CaOH+ 0.25966E-06 -6.5856 0.60269E-07 -7.2199 0.23211E+00 -0.6343 56 CaSO4,aq 0.14553E-06 -6.8371 0.14553E-06 -6.8371 0.10000E+01 0.0000 57 HCl,aq 0.17340E-02 -2.7610 0.17340E-02 -2.7610 0.10000E+01 0.0000 66 CuCl,aq 0.27144E-04 -4.5663 0.27144E-04 -4.5663 0.10000E+01 0.0000 67 CuCl2- 0.10454E-03 -3.9807 0.21713E-04 -4.6633 0.20771E+00 -0.6826 68 CuCl3-2 0.24323E-05 -5.6140 0.90000E-08 -8.0458 0.37001E-02 -2.4318 74 FeCl+ 0.40830E-06 -6.3890 0.94769E-07 -7.0233 0.23211E+00 -0.6343 75 FeCl2,aq 0.58423E-02 -2.2334 0.58423E-02 -2.2334 0.10000E+01 0.0000 77 FeO,aq 0.76855E-07 -7.1143 0.76855E-07 -7.1143 0.10000E+01 0.0000 78 FeOH+ 0.32211E-07 -7.4920 0.74765E-08 -8.1263 0.23211E+00 -0.6343 79 HFeO2- 0.96331E-08 -8.0162 0.20009E-08 -8.6988 0.20771E+00 -0.6826 82 FeO2- 0.63142E-08 -8.1997 0.13115E-08 -8.8822 0.20771E+00 -0.6826 83 HFeO2,aq 0.27591E-09 -9.5592 0.27591E-09 -9.5592 0.10000E+01 0.0000 84 H2,aq 0.46063E-02 -2.3366 0.55422E-02 -2.2563 0.12032E+01 0.0803 85 KCl,aq 0.63114E-01 -1.1999 0.63114E-01 -1.1999 0.10000E+01 0.0000 86 KHSO4,aq 0.12983E-01 -1.8866 0.12983E-01 -1.8866 0.10000E+01 0.0000 87 KOH,aq 0.11229E-05 -5.9496 0.11229E-05 -5.9496 0.10000E+01 0.0000 88 KSO4- 0.41452E-02 -2.3825 0.86098E-03 -3.0650 0.20771E+00 -0.6826 90 Mg(HCO3)+ 0.58164E-07 -7.2353 0.13500E-07 -7.8697 0.23211E+00 -0.6343 91 MgCl+ 0.14981E-04 -4.8245 0.34772E-05 -5.4588 0.23211E+00 -0.6343 92 MgOH+ 0.54361E-06 -6.2647 0.12618E-06 -6.8990 0.23211E+00 -0.6343 94 MnO,aq 0.51220E-07 -7.2906 0.51220E-07 -7.2906 0.10000E+01 0.0000 95 MnOH+ 0.16346E-06 -6.7866 0.37939E-07 -7.4209 0.23211E+00 -0.6343 97 HMnO2- 0.28432E-10 -10.5462 0.59054E-11 -11.2287 0.20771E+00 -0.6826 100 MnCl+ 0.11573E-02 -2.9365 0.26862E-03 -3.5709 0.23211E+00 -0.6343 101 MnSO4,aq 0.56376E-07 -7.2489 0.56376E-07 -7.2489 0.10000E+01 0.0000 102 NaCl,aq 0.40644E+00 -0.3910 0.40644E+00 -0.3910 0.10000E+01 0.0000 103 NaOH,aq 0.15684E-05 -5.8045 0.15684E-05 -5.8045 0.10000E+01 0.0000 105 OH- 0.84156E-05 -5.0749 0.15242E-05 -5.8169 0.18112E+00 -0.7420 110 HPO3-2 0.12254E-10 -10.9117 0.45340E-13 -13.3435 0.37001E-02 -2.4318 111 H3PO3,aq 0.10732E-09 -9.9693 0.10732E-09 -9.9693 0.10000E+01 0.0000 112 H2PO3- 0.31954E-08 -8.4955 0.66370E-09 -9.1780 0.20771E+00 -0.6826 113 H3PO4,aq 0.93092E-06 -6.0311 0.93092E-06 -6.0311 0.10000E+01 0.0000 114 H2PO4- 0.15197E-05 -5.8182 0.33233E-06 -6.4784 0.21868E+00 -0.6602 116 H4P2O7,aq 0.75223E-10 -10.1237 0.75223E-10 -10.1237 0.10000E+01 0.0000 117 H3P2O7- 0.92972E-09 -9.0316 0.19311E-09 -9.7142 0.20771E+00 -0.6826 118 H2P2O7-2 0.25711E-06 -6.5899 0.95132E-09 -9.0217 0.37001E-02 -2.4318 119 HP2O7-3 0.14933E-07 -7.8259 0.40501E-13 -13.3925 0.27122E-05 -5.5667 121 PbCl+ 0.18531E-05 -5.7321 0.43013E-06 -6.3664 0.23211E+00 -0.6343 122 PbCl2,aq 0.86948E-04 -4.0607 0.86948E-04 -4.0607 0.10000E+01 0.0000 123 PbCl3- 0.10922E-03 -3.9617 0.22685E-04 -4.6443 0.20771E+00 -0.6826 124 PbCl4-2 0.24679E-04 -4.6077 0.91314E-07 -7.0395 0.37001E-02 -2.4318 125 PbO,aq 0.47580E-08 -8.3226 0.47580E-08 -8.3226 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10871E-03 -3.9637 0.10871E-03 -3.9637 0.10000E+01 0.0000 128 Pb(HS)3- 0.11379E-04 -4.9439 0.23634E-05 -5.6265 0.20771E+00 -0.6826 129 H2S,aq 0.10554E+01 0.0234 0.12698E+01 0.1037 0.12032E+01 0.0803 130 S2-2 0.14435E-07 -7.8406 0.53410E-10 -10.2724 0.37001E-02 -2.4318 131 S3-2 0.14452E-08 -8.8401 0.53474E-11 -11.2719 0.37001E-02 -2.4318 132 S3- 0.16007E-01 -1.7957 0.33248E-02 -2.4782 0.20771E+00 -0.6826 133 S4-2 0.12146E-09 -9.9156 0.44942E-12 -12.3474 0.37001E-02 -2.4318 135 SO2,aq 0.28905E+00 -0.5390 0.28905E+00 -0.5390 0.10000E+01 0.0000 136 SO3-2 0.59857E-09 -9.2229 0.35233E-11 -11.4531 0.58862E-02 -2.2302 137 HSO3- 0.34715E-03 -3.4595 0.72104E-04 -4.1420 0.20771E+00 -0.6826 138 HSO4- 0.10159E-01 -1.9931 0.24217E-02 -2.6159 0.23837E+00 -0.6227 140 S2O3-2 0.52461E-06 -6.2802 0.19411E-08 -8.7119 0.37001E-02 -2.4318 141 HS2O3- 0.53739E-06 -6.2697 0.11162E-06 -6.9523 0.20771E+00 -0.6826 142 H2S2O3,aq 0.26922E-07 -7.5699 0.26922E-07 -7.5699 0.10000E+01 0.0000 150 S4O6-2 0.57365E-09 -9.2414 0.21226E-11 -11.6731 0.37001E-02 -2.4318 152 ZnCl+ 0.36725E-03 -3.4350 0.85242E-04 -4.0693 0.23211E+00 -0.6343 153 ZnCl2,aq 0.10390E-02 -2.9834 0.10390E-02 -2.9834 0.10000E+01 0.0000 154 ZnCl3- 0.11334E-03 -3.9456 0.23542E-04 -4.6282 0.20771E+00 -0.6826 155 ZnO,aq 0.35663E-07 -7.4478 0.35663E-07 -7.4478 0.10000E+01 0.0000 156 ZnOH+ 0.20803E-05 -5.6819 0.48285E-06 -6.3162 0.23211E+00 -0.6343 158 HZnO2- 0.28802E-09 -9.5406 0.59823E-10 -10.2231 0.20771E+00 -0.6826 Charge balance for all species = 0.2550E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7984040E-05 0.4303484E+01 0.3540814E+04 0.0000 2 H2O 0.1000000E+01 0.5250731E+02 0.7721639E+06 0.0000 3 Cl- 0.1682758E+00 0.6564717E+00 0.1899841E+05 4.2669 4 SO4-- 0.1965627E-03 0.2532147E+00 0.1985578E+05 5.3427 5 HCO3- 0.1690017E-04 0.2676544E+01 0.1333137E+06 0.3020 6 HS- 0.1348152E-03 0.1167434E+01 0.3151673E+05 1.1743 7 H4SiO4 0.7161058E-01 0.7161397E-01 0.5618740E+04 -1.1450 8 Al+++ 0.8659100E-17 0.1632370E-04 0.3595282E+00 -5.3936 9 Ca++ 0.1890395E-05 0.2674321E-03 0.8749189E+01 3.2305 10 Mg++ 0.1164999E-05 0.1674878E-04 0.3323933E+00 2.9335 11 Fe++ 0.1658674E-07 0.5842858E-02 0.2663627E+03 1.1090 12 K+ 0.4612973E-01 0.1263727E+00 0.4033672E+04 3.7492 13 Na+ 0.1520574E+00 0.5584983E+00 0.1048106E+05 4.2285 14 Mn++ 0.6774852E-06 0.1158265E-02 0.5194325E+02 2.7362 15 Zn++ 0.4160230E-09 0.1521680E-02 0.8119887E+02 -0.4916 16 Cu+ 0.2677891E-07 0.1341392E-03 0.6957465E+01 -2.5269 17 Pb++ 0.3419766E-08 0.3427892E-03 0.5797546E+02 0.5381 18 Ag+ 0.3260614E-09 0.8767769E-05 0.7720367E+00 -4.4084 19 Ba++ 0.1282997E-06 0.2071182E-04 0.2322007E+01 2.1439 20 HPO4-- 0.9987107E-09 0.3001035E-05 0.2351232E+00 0.0508 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4270634E+01 -.8271917E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5210651E+02 -.1417285E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2512819E+00 0.4409284E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1158523E+01 0.1621234E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.7106733E-01 0.7252700E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1619910E-04 0.6783404E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2653907E-03 0.2625192E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1662094E-04 0.4055715E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.5798258E-02 0.2968495E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254081E+00 0.2036613E-05 0.0000000E+00 13 Na+ 0.5545993E+00 0.5542352E+00 0.3641636E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149424E-02 0.7598585E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1510064E-02 0.7892703E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1331153E-03 0.2664945E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.2055372E-04 0.3481873E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2978127E-05 0.5589373E-05 0.0000000E+00 Chg. balance for solid moles: 0.1838E-17 Mass of aqueous solution: 0.121569E+04 g Temperature = 577.00 C Pressure = 1372.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.9713E-04 -4.013 0.1322E-01 -1.879 0.2765 0.4463E-02 annite 0.6594E-06 -6.181 0.3375E-03 -3.472 0.7058E-02 0.1018E-03 phlogopite 0.1352E-05 -5.869 0.5641E-03 -3.249 0.1180E-01 0.2023E-03 biotite-Mn 0.2533E-07 -7.596 0.1290E-04 -4.890 0.2697E-03 0.3866E-05 apatite-OH 0.1863E-05 -5.730 0.9359E-03 -3.029 0.1957E-01 0.2974E-03 magnetite 0.7987E-03 -3.098 0.1849 -0.733 3.867 0.3556E-01 quartz 0.7112E-01 -1.148 4.273 0.631 89.35 1.614 barite 0.3482E-04 -4.458 0.8127E-02 -2.090 0.1699 0.1814E-02 chalcopyrite 0.2665E-03 -3.574 0.4890E-01 -1.311 1.023 0.1141E-01 sphalerite 0.7893E-03 -3.103 0.7690E-01 -1.114 1.608 0.1881E-01 an30ab70 0.5202E-03 -3.284 0.1389 -0.857 2.905 0.5216E-01 pyrite 0.3040E-03 -3.517 0.3647E-01 -1.438 0.7627 0.7277E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3238E+00 0.3238E+00 1.0000 -0.490 phlogopite 0.6638E+00 0.6638E+00 1.0000 -0.178 biotite-Mn 0.1244E-01 0.1244E-01 1.0000 -1.905 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.781944 g Volume = 1.745645 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.32 -14.32 0.00 0.000 0.00000E+00 24 annite -0.28 -0.28 0.00 0.000 0.19867E-10 25 phlogopite 4.25 4.25 0.00 0.000 0.38007E-10 26 biotite-Mn 8.85 8.85 0.00 0.000 0.00000E+00 30 apatite-OH -52.38 -52.38 0.00 0.000 0.27641E-10 106 magnetite 1.50 1.50 0.00 0.000 0.31096E-10 140 pyrite -21.25 -21.25 0.00 0.000 0.00000E+00 144 quartz -1.14 -1.14 0.00 0.000 0.86379E-12 237 barite -15.41 -15.41 0.00 0.000 0.00000E+00 240 chalcopyrite -22.87 -22.87 0.00 0.000 0.00000E+00 255 sphalerite -10.76 -10.76 0.00 0.000 0.20731E-10 260 an30ab70 -6.17 -6.17 0.00 0.000 -0.27641E-10 259 an25ab75 -5.91 -5.91 0.00 0.000 -0.68662E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.28 -0.280 0.10897E+04 2.857 2 CO2,gas -9.58 -11.14 -1.56 -0.521 0.60861E+04 1.573 3 CH4,gas 6.91 -3.87 -10.77 -2.694 0.41915E+05 -7.637 4 H2,gas 5.87 1.82 -4.05 -2.315 0.15757E+05 -0.913 5 H2S,gas -7.98 -10.27 -2.29 -1.146 0.89123E+04 0.846 6 CO,gas -3.50 -9.32 -5.82 -1.790 0.22637E+05 -2.682 7 SO3,gas -7.10 -17.55 -10.45 -2.612 0.40649E+05 -7.312 8 O2,gas 16.62 -3.64 -20.26 -13.507 0.78814E+05 -17.123 9 HCl,gas -5.89 -7.18 -1.29 -0.643 0.50051E+04 -1.287 10 acmite 3.67 2.14 -1.53 -0.159 0.59597E+04 12 akimotoite 5.94 1.79 -4.15 -0.830 0.16152E+05 13 akimotoite-Fe 3.87 -0.03 -3.91 -0.782 0.15202E+05 14 albite-high -4.47 -4.59 -0.12 -0.009 0.46477E+03 15 albite -4.45 -4.59 -0.14 -0.011 0.53964E+03 16 almandine -9.42 -10.90 -1.48 -0.074 0.57437E+04 17 pyrope -2.88 -5.42 -2.55 -0.127 0.99039E+04 18 analcite -2.50 -3.45 -0.95 -0.106 0.36992E+04 19 andalusite -11.56 -11.93 -0.37 -0.037 0.14587E+04 20 andradite 11.25 6.66 -4.59 -0.238 0.17854E+05 21 grossular 0.28 -4.53 -4.81 -0.241 0.18729E+05 27 anorthite -9.29 -9.85 -0.56 -0.043 0.21776E+04 28 anthophyllite 13.65 11.39 -2.26 -0.061 0.88044E+04 29 anthophyllite-Fe 1.22 -1.38 -2.60 -0.070 0.10120E+05 31 apatite-OH-zs -50.24 -52.38 -2.14 -0.164 0.83119E+04 32 apatite-Cl-zs -56.41 -59.56 -3.15 -0.262 0.12244E+05 33 aragonite -4.42 -7.91 -3.49 -1.164 0.13584E+05 34 brucite 5.18 2.93 -2.25 -0.449 0.87400E+04 35 calcite -4.52 -7.91 -3.39 -1.131 0.13197E+05 36 carnegieite-low -0.55 -2.31 -1.76 -0.251 0.68324E+04 37 carnegieite-high -0.48 -2.31 -1.83 -0.261 0.71146E+04 38 carpholite-Mg -8.25 -10.15 -1.90 -0.127 0.73849E+04 39 carpholite-Fe -9.58 -11.97 -2.39 -0.159 0.92918E+04 40 celadonite -1.18 -3.28 -2.11 -0.124 0.81950E+04 41 celadonite-Fe -2.56 -5.11 -2.54 -0.150 0.98971E+04 42 chrysotile 8.95 6.51 -2.44 -0.204 0.95001E+04 44 clinochlore 1.82 0.44 -1.39 -0.043 0.53971E+04 45 daphnite -5.13 -8.69 -3.55 -0.111 0.13826E+05 48 chloritoid-Mg -7.79 -9.00 -1.22 -0.081 0.47300E+04 49 chloritoid-Fe -9.69 -10.83 -1.13 -0.076 0.44149E+04 50 chloritoid-Mn -7.53 -9.20 -1.67 -0.111 0.64841E+04 52 coesite -0.86 -1.14 -0.28 -0.095 0.11029E+04 53 cordierite-H -20.81 -21.43 -0.63 -0.022 0.24324E+04 54 cordierite-Fe -23.31 -25.08 -1.77 -0.061 0.68862E+04 55 cordierite-Mn -18.91 -21.82 -2.91 -0.100 0.11316E+05 56 corundum -10.25 -10.79 -0.55 -0.050 0.21222E+04 58 cristobalite -1.09 -1.14 -0.05 -0.016 0.18765E+03 59 cummingtonite 13.71 11.39 -2.33 -0.063 0.90470E+04 61 cymrite-K -2.80 -5.07 -2.27 -0.189 0.88457E+04 63 diaspore -4.62 -5.40 -0.78 -0.130 0.30232E+04 65 diopside 5.20 3.88 -1.33 -0.133 0.51640E+04 66 hedenbergite 3.80 2.05 -1.75 -0.175 0.68146E+04 68 eastonite -7.63 -8.86 -1.23 -0.047 0.47852E+04 69 enstatite 4.45 3.58 -0.87 -0.087 0.33954E+04 70 clinoenstatite-HiP 4.94 3.58 -1.36 -0.136 0.52943E+04 71 clinoenstatite 4.44 3.58 -0.86 -0.086 0.33402E+04 72 protoenstatite 4.58 3.58 -1.00 -0.100 0.39048E+04 73 epidote -5.54 -7.56 -2.02 -0.098 0.78630E+04 74 clinozoisite -10.75 -13.16 -2.41 -0.109 0.93695E+04 75 epidote-Fe 1.34 -1.97 -3.31 -0.172 0.12868E+05 76 fayalite 1.98 1.07 -0.91 -0.130 0.35383E+04 77 ferrosilite 0.93 -0.07 -1.00 -0.100 0.38998E+04 78 forsterite 5.92 4.72 -1.19 -0.170 0.46417E+04 79 gedrite -11.88 -13.78 -1.90 -0.051 0.73755E+04 81 gibbsite -3.01 -5.40 -2.39 -0.341 0.92922E+04 82 glaucophane 0.42 -2.68 -3.09 -0.084 0.12029E+05 83 glaucophane-Fe -3.57 -8.15 -4.58 -0.124 0.17835E+05 84 goethite 1.00 0.20 -0.81 -0.175 0.31401E+04 86 greenalite 4.16 1.04 -3.13 -0.261 0.12171E+05 87 grunerite 1.76 -1.38 -3.14 -0.085 0.12229E+05 88 halite -0.89 -2.95 -2.06 -1.030 0.80119E+04 89 hematite 0.48 0.40 -0.08 -0.010 0.32499E+03 90 heulandite -12.69 -15.57 -2.88 -0.131 0.11197E+05 91 hercynite -8.71 -9.68 -0.98 -0.065 0.37932E+04 94 jadeite -1.82 -3.45 -1.63 -0.163 0.63486E+04 96 kalsilite -1.18 -2.79 -1.61 -0.230 0.62748E+04 97 kaolinite -10.45 -13.08 -2.63 -0.239 0.10228E+05 98 kyanite -11.40 -11.93 -0.53 -0.053 0.20701E+04 100 laumontite -8.72 -12.14 -3.42 -0.228 0.13286E+05 101 lawsonite -6.54 -9.85 -3.31 -0.221 0.12886E+05 102 leucite -2.97 -3.93 -0.96 -0.096 0.37240E+04 104 lizardite 9.13 6.51 -2.62 -0.219 0.10210E+05 105 magnesite -5.37 -8.21 -2.84 -0.946 0.11038E+05 107 minnesotaite 0.63 -1.25 -1.87 -0.110 0.72940E+04 108 minnesotaite-Mg 6.51 4.23 -2.28 -0.134 0.88650E+04 109 magnesioferrite 4.53 3.33 -1.20 -0.098 0.46734E+04 111 manganosite 5.18 2.73 -2.45 -0.612 0.95305E+04 112 margarite -19.06 -20.64 -1.58 -0.063 0.61470E+04 115 microcline -5.05 -5.07 -0.02 -0.002 0.83171E+02 116 monticellite 8.49 5.02 -3.47 -0.495 0.13486E+05 118 mullite-Si -10.83 -11.93 -1.11 -0.111 0.43094E+04 119 muscovite -15.16 -15.87 -0.70 -0.041 0.27323E+04 120 paragonite -14.49 -15.39 -0.90 -0.053 0.35041E+04 121 nepheline -0.85 -2.31 -1.46 -0.209 0.56938E+04 122 osumilite(2) -14.33 -16.20 -1.88 -0.039 0.73053E+04 123 osumilite-Fe -30.28 -32.43 -2.15 -0.045 0.83784E+04 124 pargasite 3.14 -0.63 -3.77 -0.099 0.14675E+05 125 periclase 5.36 2.93 -2.43 -0.607 0.94520E+04 126 periclase-Fe 2.82 1.11 -1.71 -0.428 0.66592E+04 127 perovskite-Al -8.54 -10.79 -2.26 -0.205 0.87797E+04 132 phlogopite-Na 5.12 4.20 -0.92 -0.051 0.35689E+04 134 prehnite -4.65 -7.76 -3.12 -0.183 0.12122E+05 135 prehnite-Fe 0.95 -2.17 -3.12 -0.188 0.12136E+05 138 px-Mg-tschermaks -7.22 -9.00 -1.79 -0.128 0.69496E+04 139 px-Ca-tschermaks -6.28 -8.71 -2.43 -0.173 0.94339E+04 141 pyrrhotite -8.55 -9.16 -0.61 -0.205 0.23901E+04 142 pyrrhotiteFe0.875 -9.29 -9.53 -0.24 -0.089 0.94080E+03 143 pyrophyllite -14.11 -15.36 -1.25 -0.078 0.48571E+04 146 riebeckite 5.75 3.04 -2.71 -0.075 0.10548E+05 147 ringwoodite-Fe 2.97 1.07 -1.90 -0.271 0.73851E+04 148 ringwoodite-Mg 9.03 4.72 -4.31 -0.616 0.16776E+05 149 rhodochrosite -5.28 -8.41 -3.12 -1.041 0.12153E+05 150 rhodonite 2.44 1.59 -0.84 -0.168 0.32769E+04 151 sanidine -4.52 -5.07 -0.55 -0.043 0.21518E+04 153 siderite -7.18 -10.04 -2.86 -0.953 0.11120E+05 154 sillimanite -11.53 -11.93 -0.41 -0.041 0.15854E+04 156 spinel -6.57 -7.86 -1.29 -0.086 0.50198E+04 162 stilpnomelane-Fe -7.99 -12.53 -4.54 -0.135 0.17655E+05 163 stilpnomelane-Mg -1.33 -3.40 -2.07 -0.062 0.80488E+04 164 stishovite 1.78 -1.14 -2.92 -0.973 0.11355E+05 165 sudoite-Fe -18.94 -22.80 -3.86 -0.125 0.15018E+05 166 sudoite -16.76 -19.15 -2.39 -0.077 0.93080E+04 167 sulfur -10.60 -12.09 -1.49 -0.459 0.57985E+04 168 sylvite -0.80 -3.43 -2.63 -1.317 0.10246E+05 169 talc 4.79 4.23 -0.57 -0.033 0.22039E+04 170 talc-Fe 2.01 -1.25 -3.26 -0.191 0.12663E+05 171 talc-tschermaks -6.80 -8.36 -1.56 -0.091 0.60501E+04 173 tephroite 6.28 4.33 -1.96 -0.280 0.76130E+04 176 topaz-H -9.48 -11.94 -2.46 -0.224 0.95682E+04 177 tremolite 14.57 11.98 -2.59 -0.070 0.10059E+05 179 troilite-low -8.45 -9.16 -0.71 -0.236 0.27595E+04 180 tschermakite -10.19 -13.18 -2.99 -0.081 0.11638E+05 183 wadsleyite-Fe 2.82 1.07 -1.75 -0.250 0.67984E+04 184 wadsleyite-Mg 8.10 4.72 -3.38 -0.483 0.13143E+05 185 wairakite -10.55 -12.13 -1.58 -0.093 0.61479E+04 186 walstromite 4.54 2.09 -2.46 -0.491 0.95594E+04 187 wollastonite 4.13 2.09 -2.04 -0.409 0.79552E+04 188 pseudo-wollastonite 4.25 2.09 -2.16 -0.432 0.83955E+04 189 zoisite -10.80 -13.16 -2.35 -0.107 0.91491E+04 192 beidellite-Ca -14.67 -16.23 -1.56 -0.096 0.60657E+04 193 beidellite-H -14.68 -16.76 -2.09 -0.133 0.81139E+04 194 beidellite-K -13.62 -15.53 -1.90 -0.117 0.74021E+04 195 beidellite-Mg -14.96 -16.28 -1.33 -0.082 0.51550E+04 196 beidellite-Na -13.57 -15.37 -1.80 -0.110 0.70167E+04 197 bornite -53.06 -53.52 -0.46 -0.035 0.18071E+04 199 chalcocite -13.79 -15.33 -1.53 -0.383 0.59674E+04 200 covellite -12.29 -13.71 -1.42 -0.540 0.55171E+04 202 montmorillonite-Ca -10.90 -12.08 -1.18 -0.073 0.45958E+04 203 montmorillonite-K -10.14 -11.38 -1.24 -0.076 0.48099E+04 204 montmorillonite-Mg -11.13 -12.13 -1.00 -0.062 0.38811E+04 205 montmorillonite-Na -9.79 -11.22 -1.43 -0.087 0.55566E+04 206 nontronite-Ca -3.70 -5.04 -1.34 -0.087 0.52247E+04 207 nontronite-H -3.72 -5.58 -1.86 -0.125 0.72438E+04 208 nontronite-K -2.66 -4.34 -1.68 -0.108 0.65510E+04 209 nontronite-Mg -3.94 -5.09 -1.15 -0.075 0.44805E+04 210 nontronite-Na -2.59 -4.18 -1.59 -0.102 0.61797E+04 215 gypsum -12.12 -14.32 -2.20 -0.551 0.85697E+04 232 alabandite -6.27 -7.54 -1.27 -0.422 0.49227E+04 234 anglesite -14.52 -17.01 -2.50 -1.249 0.97142E+04 238 boehmite -4.34 -5.40 -1.06 -0.177 0.41254E+04 242 copper,native 1.76 -1.62 -3.37 -1.174 0.13126E+05 244 ferrous-oxide 1.90 1.11 -0.79 -0.199 0.30894E+04 245 galena -9.52 -9.73 -0.21 -0.070 0.81841E+03 246 silver,native 0.52 -3.50 -4.01 -1.396 0.15617E+05 248 litharge 5.22 0.54 -4.69 -1.171 0.18227E+05 256 wurtzite -9.97 -10.76 -0.79 -0.265 0.30889E+04 257 zincite 2.02 -0.49 -2.51 -0.627 0.97605E+04 258 an20ab80 -5.64 -5.64 -0.01 0.000 0.22274E+02 261 tr.625ac.25prg.125 8.99 8.12 -0.86 -0.023 0.33541E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 28 Loop limit = 500 Temperature = 577.00 C Pressure = 1372.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5508E+02 kg liquid = 0.9924E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9962 Stoichiometric ionic strength = .3295156E+01 Osmotic coef. = 0.0000 True ionic strength = .1999641E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.80152E-05 -5.0961 0.18986E-05 -5.7216 0.23687E+00 -0.6255 2 H2O 0.99617E+00 -0.0017 0.99617E+00 -0.0017 3 Cl- 0.16826E+00 -0.7740 0.34965E-01 -1.4564 0.20781E+00 -0.6823 4 SO4-- 0.19450E-03 -3.7111 0.77969E-06 -6.1081 0.40087E-02 -2.3970 5 HCO3- 0.16819E-04 -4.7742 0.37725E-05 -5.4234 0.22429E+00 -0.6492 6 HS- 0.13417E-03 -3.8723 0.28120E-04 -4.5510 0.20959E+00 -0.6786 7 H4SiO4 0.71611E-01 -1.1450 0.71611E-01 -1.1450 0.10000E+01 0.0000 8 Al+++ 0.87605E-17 -17.0575 0.27724E-22 -22.5571 0.31647E-05 -5.4997 9 Ca++ 0.19036E-05 -5.7204 0.61300E-08 -8.2125 0.32203E-02 -2.4921 10 Mg++ 0.11734E-05 -5.9305 0.30945E-08 -8.5094 0.26371E-02 -2.5789 11 Fe++ 0.16698E-07 -7.7773 0.46330E-10 -10.3341 0.27746E-02 -2.5568 12 K+ 0.46144E-01 -1.3359 0.10619E-01 -1.9739 0.23013E+00 -0.6380 13 Na+ 0.15185E+00 -0.8186 0.31965E-01 -1.4953 0.21050E+00 -0.6767 14 Mn++ 0.67620E-06 -6.1699 0.19470E-08 -8.7106 0.28793E-02 -2.5407 15 Zn++ 0.41881E-09 -9.3780 0.11620E-11 -11.9348 0.27746E-02 -2.5568 16 Cu+ 0.26881E-07 -7.5705 0.56431E-08 -8.2485 0.20993E+00 -0.6779 17 Pb++ 0.34232E-08 -8.4656 0.12371E-10 -10.9076 0.36139E-02 -2.4420 18 Ag+ 0.32608E-09 -9.4867 0.73846E-10 -10.1317 0.22647E+00 -0.6450 19 Ba++ 0.12921E-06 -6.8887 0.50214E-09 -9.2992 0.38862E-02 -2.4105 20 HPO4-- 0.98814E-09 -9.0052 0.39813E-11 -11.4000 0.40291E-02 -2.3948 21 HSiO3- 0.17689E-05 -5.7523 0.36760E-06 -6.4346 0.20781E+00 -0.6823 22 Ca(HSiO3)+ 0.86991E-08 -8.0605 0.20200E-08 -8.6947 0.23220E+00 -0.6341 23 Mg(HSiO3)+ 0.12316E-08 -8.9095 0.28597E-09 -9.5437 0.23220E+00 -0.6341 24 NaHSiO3,aq 0.15948E-05 -5.7973 0.15948E-05 -5.7973 0.10000E+01 0.0000 28 AgCl,aq 0.82041E-07 -7.0860 0.82041E-07 -7.0860 0.10000E+01 0.0000 29 AgCl2- 0.49698E-05 -5.3037 0.10328E-05 -5.9860 0.20781E+00 -0.6823 30 AgCl3-2 0.21591E-05 -5.6657 0.80030E-08 -8.0967 0.37067E-02 -2.4310 31 AgCl4-3 0.15508E-05 -5.8095 0.42239E-11 -11.3743 0.27237E-05 -5.5648 34 Ag(HS),aq 0.93748E-09 -9.0280 0.93748E-09 -9.0280 0.10000E+01 0.0000 35 Ag(HS)2- 0.48204E-08 -8.3169 0.10017E-08 -8.9993 0.20781E+00 -0.6823 36 AlO+ 0.10070E-10 -10.9970 0.23382E-11 -11.6311 0.23220E+00 -0.6341 38 HAlO2,aq 0.44165E-08 -8.3549 0.44165E-08 -8.3549 0.10000E+01 0.0000 39 AlO2- 0.16284E-04 -4.7882 0.29511E-05 -5.5300 0.18123E+00 -0.7418 41 Ba(HCO3)+ 0.55175E-06 -6.2583 0.13340E-06 -6.8749 0.24177E+00 -0.6166 42 BaCl+ 0.20211E-04 -4.6944 0.46930E-05 -5.3286 0.23220E+00 -0.6341 43 CH4,aq 0.17774E-08 -8.7502 0.21385E-08 -8.6699 0.12032E+01 0.0803 48 CO,aq 0.67242E-03 -3.1724 0.67242E-03 -3.1724 0.10000E+01 0.0000 49 CO2,aq 0.26759E+01 0.4275 0.32195E+01 0.5078 0.12032E+01 0.0803 50 CO3-2 0.43450E-10 -10.3620 0.16106E-12 -12.7930 0.37067E-02 -2.4310 51 CaCO3,aq 0.14051E-10 -10.8523 0.14051E-10 -10.8523 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.29834E-06 -6.5253 0.69275E-07 -7.1594 0.23220E+00 -0.6341 53 CaCl+ 0.15157E-03 -3.8194 0.35196E-04 -4.4535 0.23220E+00 -0.6341 54 CaCl2,aq 0.11568E-03 -3.9367 0.11568E-03 -3.9367 0.10000E+01 0.0000 55 CaOH+ 0.26072E-06 -6.5838 0.60540E-07 -7.2180 0.23220E+00 -0.6341 56 CaSO4,aq 0.14553E-06 -6.8371 0.14553E-06 -6.8371 0.10000E+01 0.0000 57 HCl,aq 0.17422E-02 -2.7589 0.17422E-02 -2.7589 0.10000E+01 0.0000 66 CuCl,aq 0.27271E-04 -4.5643 0.27271E-04 -4.5643 0.10000E+01 0.0000 67 CuCl2- 0.10501E-03 -3.9787 0.21823E-04 -4.6611 0.20781E+00 -0.6823 68 CuCl3-2 0.24413E-05 -5.6124 0.90490E-08 -8.0434 0.37067E-02 -2.4310 74 FeCl+ 0.41184E-06 -6.3853 0.95630E-07 -7.0194 0.23220E+00 -0.6341 75 FeCl2,aq 0.58976E-02 -2.2293 0.58976E-02 -2.2293 0.10000E+01 0.0000 77 FeO,aq 0.76856E-07 -7.1143 0.76856E-07 -7.1143 0.10000E+01 0.0000 78 FeOH+ 0.32338E-07 -7.4903 0.75090E-08 -8.1244 0.23220E+00 -0.6341 79 HFeO2- 0.95870E-08 -8.0183 0.19923E-08 -8.7007 0.20781E+00 -0.6823 82 FeO2- 0.62838E-08 -8.2018 0.13058E-08 -8.8841 0.20781E+00 -0.6823 83 HFeO2,aq 0.27591E-09 -9.5592 0.27591E-09 -9.5592 0.10000E+01 0.0000 84 H2,aq 0.46066E-02 -2.3366 0.55425E-02 -2.2563 0.12032E+01 0.0803 85 KCl,aq 0.63184E-01 -1.1994 0.63184E-01 -1.1994 0.10000E+01 0.0000 86 KHSO4,aq 0.12934E-01 -1.8883 0.12934E-01 -1.8883 0.10000E+01 0.0000 87 KOH,aq 0.11189E-05 -5.9512 0.11189E-05 -5.9512 0.10000E+01 0.0000 88 KSO4- 0.41098E-02 -2.3862 0.85404E-03 -3.0685 0.20781E+00 -0.6823 90 Mg(HCO3)+ 0.58424E-07 -7.2334 0.13566E-07 -7.8675 0.23220E+00 -0.6341 91 MgCl+ 0.15119E-04 -4.8205 0.35107E-05 -5.4546 0.23220E+00 -0.6341 92 MgOH+ 0.54606E-06 -6.2628 0.12680E-06 -6.8969 0.23220E+00 -0.6341 94 MnO,aq 0.50781E-07 -7.2943 0.50781E-07 -7.2943 0.10000E+01 0.0000 95 MnOH+ 0.16269E-06 -6.7886 0.37777E-07 -7.4228 0.23220E+00 -0.6341 97 HMnO2- 0.28052E-10 -10.5520 0.58295E-11 -11.2344 0.20781E+00 -0.6823 100 MnCl+ 0.11573E-02 -2.9365 0.26873E-03 -3.5707 0.23220E+00 -0.6341 101 MnSO4,aq 0.55883E-07 -7.2527 0.55883E-07 -7.2527 0.10000E+01 0.0000 102 NaCl,aq 0.40624E+00 -0.3912 0.40624E+00 -0.3912 0.10000E+01 0.0000 103 NaOH,aq 0.15603E-05 -5.8068 0.15603E-05 -5.8068 0.10000E+01 0.0000 105 OH- 0.83743E-05 -5.0771 0.15177E-05 -5.8188 0.18123E+00 -0.7418 110 HPO3-2 0.12124E-10 -10.9164 0.44940E-13 -13.3474 0.37067E-02 -2.4310 111 H3PO3,aq 0.10730E-09 -9.9694 0.10730E-09 -9.9694 0.10000E+01 0.0000 112 H2PO3- 0.31793E-08 -8.4977 0.66069E-09 -9.1800 0.20781E+00 -0.6823 113 H3PO4,aq 0.93067E-06 -6.0312 0.93067E-06 -6.0312 0.10000E+01 0.0000 114 H2PO4- 0.15121E-05 -5.8204 0.33080E-06 -6.4804 0.21878E+00 -0.6600 116 H4P2O7,aq 0.75182E-10 -10.1239 0.75182E-10 -10.1239 0.10000E+01 0.0000 117 H3P2O7- 0.92475E-09 -9.0340 0.19217E-09 -9.7163 0.20781E+00 -0.6823 118 H2P2O7-2 0.25430E-06 -6.5947 0.94262E-09 -9.0257 0.37067E-02 -2.4310 119 HP2O7-3 0.14670E-07 -7.8336 0.39957E-13 -13.3984 0.27237E-05 -5.5648 121 PbCl+ 0.18583E-05 -5.7309 0.43149E-06 -6.3650 0.23220E+00 -0.6341 122 PbCl2,aq 0.87257E-04 -4.0592 0.87257E-04 -4.0592 0.10000E+01 0.0000 123 PbCl3- 0.10959E-03 -3.9602 0.22774E-04 -4.6426 0.20781E+00 -0.6823 124 PbCl4-2 0.24741E-04 -4.6066 0.91708E-07 -7.0376 0.37067E-02 -2.4310 125 PbO,aq 0.47302E-08 -8.3251 0.47302E-08 -8.3251 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10807E-03 -3.9663 0.10807E-03 -3.9663 0.10000E+01 0.0000 128 Pb(HS)3- 0.11258E-04 -4.9485 0.23396E-05 -5.6309 0.20781E+00 -0.6823 129 H2S,aq 0.10554E+01 0.0234 0.12698E+01 0.1037 0.12032E+01 0.0803 130 S2-2 0.14285E-07 -7.8451 0.52949E-10 -10.2761 0.37067E-02 -2.4310 131 S3-2 0.14301E-08 -8.8446 0.53011E-11 -11.2756 0.37067E-02 -2.4310 132 S3- 0.15929E-01 -1.7978 0.33102E-02 -2.4801 0.20781E+00 -0.6823 133 S4-2 0.12019E-09 -9.9201 0.44551E-12 -12.3511 0.37067E-02 -2.4310 135 SO2,aq 0.28901E+00 -0.5391 0.28901E+00 -0.5391 0.10000E+01 0.0000 136 SO3-2 0.59246E-09 -9.2273 0.34925E-11 -11.4569 0.58949E-02 -2.2295 137 HSO3- 0.34544E-03 -3.4616 0.71784E-04 -4.1440 0.20781E+00 -0.6823 138 HSO4- 0.10110E-01 -1.9953 0.24109E-02 -2.6178 0.23847E+00 -0.6226 140 S2O3-2 0.51909E-06 -6.2848 0.19241E-08 -8.7158 0.37067E-02 -2.4310 141 HS2O3- 0.53473E-06 -6.2719 0.11112E-06 -6.9542 0.20781E+00 -0.6823 142 H2S2O3,aq 0.26918E-07 -7.5700 0.26918E-07 -7.5700 0.10000E+01 0.0000 150 S4O6-2 0.56751E-09 -9.2460 0.21036E-11 -11.6770 0.37067E-02 -2.4310 152 ZnCl+ 0.37042E-03 -3.4313 0.86014E-04 -4.0654 0.23220E+00 -0.6341 153 ZnCl2,aq 0.10488E-02 -2.9793 0.10488E-02 -2.9793 0.10000E+01 0.0000 154 ZnCl3- 0.11440E-03 -3.9416 0.23774E-04 -4.6239 0.20781E+00 -0.6823 155 ZnO,aq 0.35663E-07 -7.4478 0.35663E-07 -7.4478 0.10000E+01 0.0000 156 ZnOH+ 0.20884E-05 -5.6802 0.48494E-06 -6.3143 0.23220E+00 -0.6341 158 HZnO2- 0.28663E-09 -9.5427 0.59564E-10 -10.2250 0.20781E+00 -0.6823 Charge balance for all species = 0.2550E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8015167E-05 0.4303174E+01 0.3540636E+04 0.0000 2 H2O 0.1000000E+01 0.5250754E+02 0.7721841E+06 0.0000 3 Cl- 0.1682566E+00 0.6564717E+00 0.1899882E+05 4.2652 4 SO4-- 0.1945017E-03 0.2530032E+00 0.1983962E+05 5.3351 5 HCO3- 0.1681941E-04 0.2676544E+01 0.1333166E+06 0.2982 6 HS- 0.1341701E-03 0.1167284E+01 0.3151336E+05 1.1706 7 H4SiO4 0.7161073E-01 0.7161410E-01 0.5618873E+04 -1.1450 8 Al+++ 0.8760540E-17 0.1628852E-04 0.3587611E+00 -5.3924 9 Ca++ 0.1903584E-05 0.2698747E-03 0.8829293E+01 3.2306 10 Mg++ 0.1173444E-05 0.1689825E-04 0.3353668E+00 2.9337 11 Fe++ 0.1669828E-07 0.5898171E-02 0.2688901E+03 1.1090 12 K+ 0.4614408E-01 0.1263728E+00 0.4033762E+04 3.7477 13 Na+ 0.1518513E+00 0.5580898E+00 0.1047362E+05 4.2262 14 Mn++ 0.6761991E-06 0.1158269E-02 0.5194454E+02 2.7325 15 Zn++ 0.4188080E-09 0.1535723E-02 0.8194999E+02 -0.4916 16 Cu+ 0.2688143E-07 0.1347541E-03 0.6989513E+01 -2.5269 17 Pb++ 0.3423212E-08 0.3427892E-03 0.5797672E+02 0.5356 18 Ag+ 0.3260820E-09 0.8767768E-05 0.7720536E+00 -4.4101 19 Ba++ 0.1292110E-06 0.2089168E-04 0.2342222E+01 2.1440 20 HPO4-- 0.9881351E-09 0.2986952E-05 0.2340249E+00 0.0432 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4270327E+01 -.7964712E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5210674E+02 -.1419564E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2510719E+00 0.6508440E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1158374E+01 0.1770211E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.7106746E-01 0.7252687E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1616418E-04 0.6783753E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2678147E-03 0.2600952E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1676926E-04 0.3907390E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.5853149E-02 0.2913605E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254082E+00 0.1961554E-05 0.0000000E+00 13 Na+ 0.5545993E+00 0.5538298E+00 0.7695360E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149427E-02 0.7253761E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1524000E-02 0.7753347E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1337255E-03 0.2658842E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.2073221E-04 0.3464024E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2964152E-05 0.5603349E-05 0.0000000E+00 Chg. balance for solid moles: -.1831E-17 Mass of aqueous solution: 0.121567E+04 g Temperature = 577.00 C Pressure = 1372.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.2973E-03 -3.527 0.4048E-01 -1.393 0.8418 0.1366E-01 annite 0.6349E-06 -6.197 0.3250E-03 -3.488 0.6759E-02 0.9798E-04 phlogopite 0.1302E-05 -5.885 0.5435E-03 -3.265 0.1130E-01 0.1949E-03 biotite-Mn 0.2418E-07 -7.617 0.1231E-04 -4.910 0.2560E-03 0.3690E-05 apatite-OH 0.1868E-05 -5.729 0.9382E-03 -3.028 0.1951E-01 0.2981E-03 magnetite 0.7516E-03 -3.124 0.1740 -0.759 3.619 0.3346E-01 pyrite 0.3910E-03 -3.408 0.4691E-01 -1.329 0.9756 0.9360E-02 quartz 0.7031E-01 -1.153 4.224 0.626 87.85 1.595 barite 0.3464E-04 -4.460 0.8085E-02 -2.092 0.1681 0.1805E-02 chalcopyrite 0.2659E-03 -3.575 0.4879E-01 -1.312 1.015 0.1139E-01 sphalerite 0.7753E-03 -3.111 0.7554E-01 -1.122 1.571 0.1847E-01 an30ab70 -.4546E-02 1.000 -1.214 1.000 -25.25 -.4558 an25ab75 0.5269E-02 -2.278 1.403 0.147 29.17 0.5281 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3237E+00 0.3237E+00 1.0000 -0.490 phlogopite 0.6640E+00 0.6640E+00 1.0000 -0.178 biotite-Mn 0.1233E-01 0.1233E-01 1.0000 -1.909 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an30ab70 0.1000E+01 0.1000E+01 1.0000 0.000 an25ab75 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.808412 g Volume = 1.756193 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.32 -14.32 0.00 0.000 -0.69103E-11 24 annite -0.28 -0.28 0.00 0.000 0.27641E-10 25 phlogopite 4.25 4.25 0.00 0.000 0.00000E+00 26 biotite-Mn 8.85 8.85 0.00 0.000 0.20731E-10 30 apatite-OH -52.38 -52.38 0.00 0.000 0.00000E+00 106 magnetite 1.50 1.50 0.00 0.000 -0.24186E-10 140 pyrite -21.25 -21.25 0.00 0.000 0.00000E+00 144 quartz -1.14 -1.14 0.00 0.000 0.00000E+00 237 barite -15.41 -15.41 0.00 0.000 -0.69103E-11 240 chalcopyrite -22.87 -22.87 0.00 0.000 0.00000E+00 255 sphalerite -10.76 -10.76 0.00 0.000 0.69103E-11 259 an25ab75 -5.91 -5.91 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.28 -0.280 0.10897E+04 2.857 2 CO2,gas -9.58 -11.14 -1.56 -0.521 0.60861E+04 1.573 3 CH4,gas 6.91 -3.87 -10.77 -2.694 0.41915E+05 -7.637 4 H2,gas 5.87 1.82 -4.05 -2.315 0.15757E+05 -0.913 5 H2S,gas -7.98 -10.27 -2.29 -1.145 0.89123E+04 0.846 6 CO,gas -3.50 -9.32 -5.82 -1.790 0.22637E+05 -2.682 7 SO3,gas -7.10 -17.55 -10.45 -2.612 0.40650E+05 -7.312 8 O2,gas 16.62 -3.64 -20.26 -13.507 0.78814E+05 -17.123 9 HCl,gas -5.89 -7.18 -1.28 -0.642 0.49971E+04 -1.285 10 acmite 3.67 2.14 -1.53 -0.159 0.59685E+04 12 akimotoite 5.94 1.79 -4.15 -0.830 0.16151E+05 13 akimotoite-Fe 3.87 -0.03 -3.91 -0.782 0.15202E+05 14 albite-high -4.47 -4.59 -0.12 -0.009 0.46889E+03 15 albite -4.45 -4.59 -0.14 -0.011 0.54376E+03 16 almandine -9.42 -10.89 -1.47 -0.074 0.57342E+04 17 pyrope -2.88 -5.42 -2.54 -0.127 0.98916E+04 18 analcite -2.50 -3.45 -0.95 -0.106 0.37033E+04 19 andalusite -11.56 -11.93 -0.37 -0.037 0.14494E+04 20 andradite 11.25 6.66 -4.59 -0.238 0.17853E+05 21 grossular 0.28 -4.53 -4.81 -0.241 0.18718E+05 27 anorthite -9.29 -9.84 -0.56 -0.043 0.21680E+04 28 anthophyllite 13.65 11.39 -2.26 -0.061 0.87976E+04 29 anthophyllite-Fe 1.22 -1.38 -2.60 -0.070 0.10120E+05 31 apatite-OH-zs -50.24 -52.38 -2.14 -0.164 0.83119E+04 32 apatite-Cl-zs -56.41 -59.55 -3.15 -0.262 0.12236E+05 33 aragonite -4.42 -7.91 -3.49 -1.164 0.13584E+05 34 brucite 5.18 2.93 -2.25 -0.449 0.87391E+04 35 calcite -4.52 -7.91 -3.39 -1.131 0.13197E+05 36 carnegieite-low -0.55 -2.31 -1.76 -0.251 0.68365E+04 37 carnegieite-high -0.48 -2.31 -1.83 -0.261 0.71188E+04 38 carpholite-Mg -8.25 -10.14 -1.90 -0.126 0.73746E+04 39 carpholite-Fe -9.58 -11.97 -2.39 -0.159 0.92824E+04 40 celadonite -1.18 -3.28 -2.11 -0.124 0.81955E+04 41 celadonite-Fe -2.56 -5.11 -2.54 -0.150 0.98985E+04 42 chrysotile 8.95 6.51 -2.44 -0.203 0.94972E+04 44 clinochlore 1.82 0.44 -1.38 -0.043 0.53829E+04 45 daphnite -5.13 -8.68 -3.55 -0.111 0.13816E+05 48 chloritoid-Mg -7.79 -9.00 -1.21 -0.081 0.47197E+04 49 chloritoid-Fe -9.69 -10.83 -1.13 -0.075 0.44055E+04 50 chloritoid-Mn -7.53 -9.20 -1.67 -0.111 0.64893E+04 52 coesite -0.86 -1.14 -0.28 -0.095 0.11029E+04 53 cordierite-H -20.81 -21.43 -0.62 -0.022 0.24118E+04 54 cordierite-Fe -23.31 -25.07 -1.77 -0.061 0.68675E+04 55 cordierite-Mn -18.91 -21.83 -2.91 -0.100 0.11326E+05 56 corundum -10.25 -10.79 -0.54 -0.049 0.21128E+04 58 cristobalite -1.09 -1.14 -0.05 -0.016 0.18765E+03 59 cummingtonite 13.71 11.39 -2.32 -0.063 0.90403E+04 61 cymrite-K -2.80 -5.07 -2.27 -0.190 0.88471E+04 63 diaspore -4.62 -5.40 -0.78 -0.129 0.30186E+04 65 diopside 5.20 3.88 -1.33 -0.133 0.51627E+04 66 hedenbergite 3.80 2.05 -1.75 -0.175 0.68143E+04 68 eastonite -7.63 -8.86 -1.23 -0.047 0.47754E+04 69 enstatite 4.45 3.58 -0.87 -0.087 0.33934E+04 70 clinoenstatite-HiP 4.94 3.58 -1.36 -0.136 0.52923E+04 71 clinoenstatite 4.44 3.58 -0.86 -0.086 0.33383E+04 72 protoenstatite 4.58 3.58 -1.00 -0.100 0.39029E+04 73 epidote -5.54 -7.56 -2.02 -0.098 0.78531E+04 74 clinozoisite -10.75 -13.15 -2.40 -0.109 0.93549E+04 75 epidote-Fe 1.34 -1.97 -3.31 -0.172 0.12863E+05 76 fayalite 1.98 1.07 -0.91 -0.130 0.35382E+04 77 ferrosilite 0.93 -0.07 -1.00 -0.100 0.38998E+04 78 forsterite 5.92 4.72 -1.19 -0.170 0.46397E+04 79 gedrite -11.88 -13.77 -1.89 -0.051 0.73519E+04 81 gibbsite -3.01 -5.40 -2.39 -0.341 0.92875E+04 82 glaucophane 0.42 -2.68 -3.09 -0.084 0.12034E+05 83 glaucophane-Fe -3.57 -8.15 -4.59 -0.124 0.17843E+05 84 goethite 1.00 0.20 -0.81 -0.175 0.31401E+04 86 greenalite 4.16 1.04 -3.13 -0.261 0.12171E+05 87 grunerite 1.76 -1.38 -3.14 -0.085 0.12229E+05 88 halite -0.89 -2.95 -2.06 -1.030 0.80128E+04 89 hematite 0.48 0.40 -0.08 -0.010 0.32502E+03 90 heulandite -12.69 -15.56 -2.88 -0.131 0.11187E+05 91 hercynite -8.71 -9.68 -0.97 -0.065 0.37839E+04 94 jadeite -1.82 -3.45 -1.63 -0.163 0.63528E+04 96 kalsilite -1.18 -2.79 -1.61 -0.230 0.62762E+04 97 kaolinite -10.45 -13.08 -2.63 -0.239 0.10219E+05 98 kyanite -11.40 -11.93 -0.53 -0.053 0.20608E+04 100 laumontite -8.72 -12.13 -3.41 -0.228 0.13276E+05 101 lawsonite -6.54 -9.85 -3.31 -0.221 0.12877E+05 102 leucite -2.97 -3.93 -0.96 -0.096 0.37254E+04 104 lizardite 9.13 6.51 -2.62 -0.219 0.10207E+05 105 magnesite -5.37 -8.21 -2.84 -0.946 0.11037E+05 107 minnesotaite 0.63 -1.25 -1.87 -0.110 0.72939E+04 108 minnesotaite-Mg 6.51 4.23 -2.28 -0.134 0.88621E+04 109 magnesioferrite 4.53 3.33 -1.20 -0.098 0.46724E+04 111 manganosite 5.18 2.73 -2.45 -0.613 0.95451E+04 112 margarite -19.06 -20.64 -1.58 -0.063 0.61280E+04 115 microcline -5.05 -5.07 -0.02 -0.002 0.84580E+02 116 monticellite 8.49 5.02 -3.47 -0.495 0.13485E+05 118 mullite-Si -10.83 -11.93 -1.11 -0.111 0.43001E+04 119 muscovite -15.16 -15.86 -0.70 -0.041 0.27244E+04 120 paragonite -14.49 -15.39 -0.90 -0.053 0.34989E+04 121 nepheline -0.85 -2.31 -1.46 -0.209 0.56979E+04 122 osumilite(2) -14.33 -16.20 -1.88 -0.039 0.72945E+04 123 osumilite-Fe -30.28 -32.43 -2.15 -0.045 0.83611E+04 124 pargasite 3.14 -0.62 -3.77 -0.099 0.14665E+05 125 periclase 5.36 2.93 -2.43 -0.607 0.94511E+04 126 periclase-Fe 2.82 1.11 -1.71 -0.428 0.66592E+04 127 perovskite-Al -8.54 -10.79 -2.25 -0.205 0.87704E+04 132 phlogopite-Na 5.12 4.20 -0.92 -0.051 0.35701E+04 134 prehnite -4.65 -7.76 -3.11 -0.183 0.12112E+05 135 prehnite-Fe 0.95 -2.17 -3.12 -0.188 0.12131E+05 138 px-Mg-tschermaks -7.22 -9.00 -1.78 -0.127 0.69392E+04 139 px-Ca-tschermaks -6.28 -8.70 -2.42 -0.173 0.94243E+04 141 pyrrhotite -8.55 -9.16 -0.61 -0.205 0.23901E+04 142 pyrrhotiteFe0.875 -9.29 -9.53 -0.24 -0.089 0.94076E+03 143 pyrophyllite -14.11 -15.36 -1.25 -0.078 0.48477E+04 146 riebeckite 5.75 3.03 -2.72 -0.075 0.10566E+05 147 ringwoodite-Fe 2.97 1.07 -1.90 -0.271 0.73850E+04 148 ringwoodite-Mg 9.03 4.72 -4.31 -0.616 0.16774E+05 149 rhodochrosite -5.28 -8.41 -3.13 -1.043 0.12168E+05 150 rhodonite 2.44 1.59 -0.85 -0.169 0.32914E+04 151 sanidine -4.52 -5.07 -0.55 -0.043 0.21532E+04 153 siderite -7.18 -10.04 -2.86 -0.953 0.11120E+05 154 sillimanite -11.53 -11.93 -0.41 -0.041 0.15761E+04 156 spinel -6.57 -7.86 -1.29 -0.086 0.50095E+04 162 stilpnomelane-Fe -7.99 -12.52 -4.54 -0.135 0.17649E+05 163 stilpnomelane-Mg -1.33 -3.40 -2.07 -0.062 0.80377E+04 164 stishovite 1.78 -1.14 -2.92 -0.973 0.11355E+05 165 sudoite-Fe -18.94 -22.80 -3.86 -0.124 0.14999E+05 166 sudoite -16.76 -19.15 -2.39 -0.077 0.92874E+04 167 sulfur -10.60 -12.09 -1.49 -0.459 0.57985E+04 168 sylvite -0.80 -3.43 -2.63 -1.317 0.10244E+05 169 talc 4.79 4.23 -0.57 -0.033 0.22010E+04 170 talc-Fe 2.01 -1.25 -3.26 -0.191 0.12663E+05 171 talc-tschermaks -6.80 -8.35 -1.55 -0.091 0.60388E+04 173 tephroite 6.28 4.32 -1.96 -0.281 0.76421E+04 176 topaz-H -9.48 -11.93 -2.46 -0.223 0.95588E+04 177 tremolite 14.57 11.98 -2.58 -0.070 0.10054E+05 179 troilite-low -8.45 -9.16 -0.71 -0.236 0.27595E+04 180 tschermakite -10.19 -13.18 -2.99 -0.081 0.11616E+05 183 wadsleyite-Fe 2.82 1.07 -1.75 -0.250 0.67984E+04 184 wadsleyite-Mg 8.10 4.72 -3.38 -0.483 0.13141E+05 185 wairakite -10.55 -12.13 -1.58 -0.093 0.61383E+04 186 walstromite 4.54 2.09 -2.46 -0.491 0.95592E+04 187 wollastonite 4.13 2.09 -2.04 -0.409 0.79549E+04 188 pseudo-wollastonite 4.25 2.09 -2.16 -0.432 0.83953E+04 189 zoisite -10.80 -13.15 -2.35 -0.107 0.91345E+04 192 beidellite-Ca -14.67 -16.23 -1.56 -0.096 0.60548E+04 193 beidellite-H -14.68 -16.76 -2.08 -0.133 0.81030E+04 194 beidellite-K -13.62 -15.53 -1.90 -0.116 0.73933E+04 195 beidellite-Mg -14.96 -16.28 -1.32 -0.082 0.51439E+04 196 beidellite-Na -13.57 -15.37 -1.80 -0.110 0.70087E+04 197 bornite -53.06 -53.52 -0.46 -0.035 0.18072E+04 199 chalcocite -13.79 -15.33 -1.53 -0.383 0.59674E+04 200 covellite -12.29 -13.71 -1.42 -0.540 0.55171E+04 202 montmorillonite-Ca -10.90 -12.08 -1.18 -0.073 0.45877E+04 203 montmorillonite-K -10.14 -11.37 -1.23 -0.076 0.48038E+04 204 montmorillonite-Mg -11.13 -12.13 -1.00 -0.062 0.38728E+04 205 montmorillonite-Na -9.79 -11.22 -1.43 -0.087 0.55513E+04 206 nontronite-Ca -3.70 -5.04 -1.34 -0.087 0.52231E+04 207 nontronite-H -3.72 -5.58 -1.86 -0.125 0.72423E+04 208 nontronite-K -2.66 -4.34 -1.68 -0.108 0.65515E+04 209 nontronite-Mg -3.94 -5.09 -1.15 -0.075 0.44788E+04 210 nontronite-Na -2.59 -4.18 -1.59 -0.102 0.61811E+04 215 gypsum -12.12 -14.32 -2.20 -0.551 0.85697E+04 232 alabandite -6.27 -7.54 -1.27 -0.423 0.49373E+04 234 anglesite -14.52 -17.02 -2.50 -1.250 0.97244E+04 238 boehmite -4.34 -5.40 -1.06 -0.177 0.41207E+04 242 copper,native 1.76 -1.62 -3.37 -1.174 0.13126E+05 244 ferrous-oxide 1.90 1.11 -0.79 -0.199 0.30894E+04 245 galena -9.52 -9.74 -0.21 -0.071 0.82829E+03 246 silver,native 0.52 -3.50 -4.02 -1.397 0.15623E+05 248 litharge 5.22 0.53 -4.69 -1.172 0.18237E+05 256 wurtzite -9.97 -10.76 -0.79 -0.265 0.30889E+04 257 zincite 2.02 -0.49 -2.51 -0.627 0.97605E+04 258 an20ab80 -5.64 -5.64 -0.01 0.000 0.23648E+02 260 an30ab70 -6.17 -6.17 0.00 0.000 0.13821E-10 261 tr.625ac.25prg.125 8.99 8.13 -0.86 -0.023 0.33494E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 23 Loop limit = 500 Temperature = 577.00 C Pressure = 1372.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5508E+02 kg liquid = 0.9924E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9962 Stoichiometric ionic strength = .3295698E+01 Osmotic coef. = 0.0000 True ionic strength = .2001335E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.79872E-05 -5.0976 0.18912E-05 -5.7233 0.23678E+00 -0.6257 2 H2O 0.99616E+00 -0.0017 0.99616E+00 -0.0017 3 Cl- 0.16827E+00 -0.7740 0.34953E-01 -1.4565 0.20772E+00 -0.6825 4 SO4-- 0.19635E-03 -3.7070 0.78588E-06 -6.1046 0.40025E-02 -2.3977 5 HCO3- 0.16892E-04 -4.7723 0.37872E-05 -5.4217 0.22421E+00 -0.6494 6 HS- 0.13475E-03 -3.8705 0.28229E-04 -4.5493 0.20949E+00 -0.6788 7 H4SiO4 0.71611E-01 -1.1450 0.71611E-01 -1.1450 0.10000E+01 0.0000 8 Al+++ 0.86669E-17 -17.0621 0.27328E-22 -22.5634 0.31531E-05 -5.5013 9 Ca++ 0.18917E-05 -5.7231 0.60817E-08 -8.2160 0.32149E-02 -2.4928 10 Mg++ 0.11660E-05 -5.9333 0.30694E-08 -8.5129 0.26324E-02 -2.5797 11 Fe++ 0.16598E-07 -7.7799 0.45971E-10 -10.3375 0.27697E-02 -2.5576 12 K+ 0.46131E-01 -1.3360 0.10612E-01 -1.9742 0.23005E+00 -0.6382 13 Na+ 0.15204E+00 -0.8181 0.31990E-01 -1.4950 0.21041E+00 -0.6769 14 Mn++ 0.67735E-06 -6.1692 0.19469E-08 -8.7107 0.28743E-02 -2.5415 15 Zn++ 0.41631E-09 -9.3806 0.11530E-11 -11.9382 0.27697E-02 -2.5576 16 Cu+ 0.26789E-07 -7.5720 0.56214E-08 -8.2502 0.20984E+00 -0.6781 17 Pb++ 0.34201E-08 -8.4660 0.12340E-10 -10.9087 0.36081E-02 -2.4427 18 Ag+ 0.32606E-09 -9.4867 0.73814E-10 -10.1319 0.22638E+00 -0.6452 19 Ba++ 0.12839E-06 -6.8915 0.49819E-09 -9.3026 0.38802E-02 -2.4111 20 HPO4-- 0.99762E-09 -9.0010 0.40133E-11 -11.3965 0.40229E-02 -2.3955 21 HSiO3- 0.17766E-05 -5.7504 0.36903E-06 -6.4329 0.20772E+00 -0.6825 22 Ca(HSiO3)+ 0.86674E-08 -8.0621 0.20118E-08 -8.6964 0.23212E+00 -0.6343 23 Mg(HSiO3)+ 0.12268E-08 -8.9112 0.28476E-09 -9.5455 0.23212E+00 -0.6343 24 NaHSiO3,aq 0.16022E-05 -5.7953 0.16022E-05 -5.7953 0.10000E+01 0.0000 28 AgCl,aq 0.81977E-07 -7.0863 0.81977E-07 -7.0863 0.10000E+01 0.0000 29 AgCl2- 0.49664E-05 -5.3040 0.10316E-05 -5.9865 0.20772E+00 -0.6825 30 AgCl3-2 0.21594E-05 -5.6657 0.79913E-08 -8.0974 0.37008E-02 -2.4317 31 AgCl4-3 0.15539E-05 -5.8086 0.42163E-11 -11.3751 0.27134E-05 -5.5665 34 Ag(HS),aq 0.94070E-09 -9.0265 0.94070E-09 -9.0265 0.10000E+01 0.0000 35 Ag(HS)2- 0.48578E-08 -8.3136 0.10091E-08 -8.9961 0.20772E+00 -0.6825 36 AlO+ 0.10007E-10 -10.9997 0.23227E-11 -11.6340 0.23212E+00 -0.6343 38 HAlO2,aq 0.44043E-08 -8.3561 0.44043E-08 -8.3561 0.10000E+01 0.0000 39 AlO2- 0.16311E-04 -4.7875 0.29544E-05 -5.5295 0.18113E+00 -0.7420 41 Ba(HCO3)+ 0.54973E-06 -6.2598 0.13286E-06 -6.8766 0.24169E+00 -0.6167 42 BaCl+ 0.20052E-04 -4.6978 0.46544E-05 -5.3321 0.23212E+00 -0.6343 43 CH4,aq 0.17772E-08 -8.7503 0.21383E-08 -8.6699 0.12032E+01 0.0803 48 CO,aq 0.67241E-03 -3.1724 0.67241E-03 -3.1724 0.10000E+01 0.0000 49 CO2,aq 0.26759E+01 0.4275 0.32196E+01 0.5078 0.12032E+01 0.0803 50 CO3-2 0.43860E-10 -10.3579 0.16232E-12 -12.7896 0.37008E-02 -2.4317 51 CaCO3,aq 0.14050E-10 -10.8523 0.14050E-10 -10.8523 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.29725E-06 -6.5269 0.68998E-07 -7.1612 0.23212E+00 -0.6343 53 CaCl+ 0.15038E-03 -3.8228 0.34907E-04 -4.4571 0.23212E+00 -0.6343 54 CaCl2,aq 0.11469E-03 -3.9405 0.11469E-03 -3.9405 0.10000E+01 0.0000 55 CaOH+ 0.25977E-06 -6.5854 0.60297E-07 -7.2197 0.23212E+00 -0.6343 56 CaSO4,aq 0.14553E-06 -6.8371 0.14553E-06 -6.8371 0.10000E+01 0.0000 57 HCl,aq 0.17348E-02 -2.7607 0.17348E-02 -2.7607 0.10000E+01 0.0000 66 CuCl,aq 0.27157E-04 -4.5661 0.27157E-04 -4.5661 0.10000E+01 0.0000 67 CuCl2- 0.10459E-03 -3.9805 0.21724E-04 -4.6631 0.20772E+00 -0.6825 68 CuCl3-2 0.24333E-05 -5.6138 0.90050E-08 -8.0455 0.37008E-02 -2.4317 74 FeCl+ 0.40866E-06 -6.3886 0.94857E-07 -7.0229 0.23212E+00 -0.6343 75 FeCl2,aq 0.58480E-02 -2.2330 0.58480E-02 -2.2330 0.10000E+01 0.0000 77 FeO,aq 0.76855E-07 -7.1143 0.76855E-07 -7.1143 0.10000E+01 0.0000 78 FeOH+ 0.32224E-07 -7.4918 0.74798E-08 -8.1261 0.23212E+00 -0.6343 79 HFeO2- 0.96284E-08 -8.0164 0.20000E-08 -8.6990 0.20772E+00 -0.6825 82 FeO2- 0.63111E-08 -8.1999 0.13109E-08 -8.8824 0.20772E+00 -0.6825 83 HFeO2,aq 0.27591E-09 -9.5592 0.27591E-09 -9.5592 0.10000E+01 0.0000 84 H2,aq 0.46063E-02 -2.3366 0.55423E-02 -2.2563 0.12032E+01 0.0803 85 KCl,aq 0.63121E-01 -1.1998 0.63121E-01 -1.1998 0.10000E+01 0.0000 86 KHSO4,aq 0.12978E-01 -1.8868 0.12978E-01 -1.8868 0.10000E+01 0.0000 87 KOH,aq 0.11225E-05 -5.9498 0.11225E-05 -5.9498 0.10000E+01 0.0000 88 KSO4- 0.41415E-02 -2.3828 0.86026E-03 -3.0654 0.20772E+00 -0.6825 90 Mg(HCO3)+ 0.58200E-07 -7.2351 0.13509E-07 -7.8694 0.23212E+00 -0.6343 91 MgCl+ 0.14997E-04 -4.8240 0.34811E-05 -5.4583 0.23212E+00 -0.6343 92 MgOH+ 0.54394E-06 -6.2644 0.12626E-06 -6.8987 0.23212E+00 -0.6343 94 MnO,aq 0.51175E-07 -7.2909 0.51175E-07 -7.2909 0.10000E+01 0.0000 95 MnOH+ 0.16338E-06 -6.7868 0.37923E-07 -7.4211 0.23212E+00 -0.6343 97 HMnO2- 0.28392E-10 -10.5468 0.58976E-11 -11.2293 0.20772E+00 -0.6825 100 MnCl+ 0.11573E-02 -2.9365 0.26863E-03 -3.5708 0.23212E+00 -0.6343 101 MnSO4,aq 0.56325E-07 -7.2493 0.56325E-07 -7.2493 0.10000E+01 0.0000 102 NaCl,aq 0.40642E+00 -0.3910 0.40642E+00 -0.3910 0.10000E+01 0.0000 103 NaOH,aq 0.15676E-05 -5.8048 0.15676E-05 -5.8048 0.10000E+01 0.0000 105 OH- 0.84114E-05 -5.0751 0.15236E-05 -5.8171 0.18113E+00 -0.7420 110 HPO3-2 0.12240E-10 -10.9122 0.45299E-13 -13.3439 0.37008E-02 -2.4317 111 H3PO3,aq 0.10732E-09 -9.9693 0.10732E-09 -9.9693 0.10000E+01 0.0000 112 H2PO3- 0.31937E-08 -8.4957 0.66339E-09 -9.1782 0.20772E+00 -0.6825 113 H3PO4,aq 0.93089E-06 -6.0311 0.93089E-06 -6.0311 0.10000E+01 0.0000 114 H2PO4- 0.15189E-05 -5.8185 0.33217E-06 -6.4786 0.21869E+00 -0.6602 116 H4P2O7,aq 0.75219E-10 -10.1237 0.75219E-10 -10.1237 0.10000E+01 0.0000 117 H3P2O7- 0.92921E-09 -9.0319 0.19301E-09 -9.7144 0.20772E+00 -0.6825 118 H2P2O7-2 0.25682E-06 -6.5904 0.95043E-09 -9.0221 0.37008E-02 -2.4317 119 HP2O7-3 0.14905E-07 -7.8267 0.40444E-13 -13.3931 0.27134E-05 -5.5665 121 PbCl+ 0.18537E-05 -5.7320 0.43027E-06 -6.3663 0.23212E+00 -0.6343 122 PbCl2,aq 0.86980E-04 -4.0606 0.86980E-04 -4.0606 0.10000E+01 0.0000 123 PbCl3- 0.10926E-03 -3.9616 0.22694E-04 -4.6441 0.20772E+00 -0.6825 124 PbCl4-2 0.24685E-04 -4.6076 0.91354E-07 -7.0393 0.37008E-02 -2.4317 125 PbO,aq 0.47552E-08 -8.3228 0.47552E-08 -8.3228 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10864E-03 -3.9640 0.10864E-03 -3.9640 0.10000E+01 0.0000 128 Pb(HS)3- 0.11366E-04 -4.9444 0.23610E-05 -5.6269 0.20772E+00 -0.6825 129 H2S,aq 0.10554E+01 0.0234 0.12698E+01 0.1037 0.12032E+01 0.0803 130 S2-2 0.14419E-07 -7.8411 0.53362E-10 -10.2728 0.37008E-02 -2.4317 131 S3-2 0.14436E-08 -8.8405 0.53426E-11 -11.2722 0.37008E-02 -2.4317 132 S3- 0.15999E-01 -1.7959 0.33233E-02 -2.4784 0.20772E+00 -0.6825 133 S4-2 0.12133E-09 -9.9160 0.44901E-12 -12.3477 0.37008E-02 -2.4317 135 SO2,aq 0.28904E+00 -0.5390 0.28904E+00 -0.5390 0.10000E+01 0.0000 136 SO3-2 0.59794E-09 -9.2233 0.35201E-11 -11.4534 0.58871E-02 -2.2301 137 HSO3- 0.34697E-03 -3.4597 0.72071E-04 -4.1422 0.20772E+00 -0.6825 138 HSO4- 0.10154E-01 -1.9934 0.24206E-02 -2.6161 0.23838E+00 -0.6227 140 S2O3-2 0.52404E-06 -6.2806 0.19394E-08 -8.7123 0.37008E-02 -2.4317 141 HS2O3- 0.53712E-06 -6.2699 0.11157E-06 -6.9525 0.20772E+00 -0.6825 142 H2S2O3,aq 0.26921E-07 -7.5699 0.26921E-07 -7.5699 0.10000E+01 0.0000 150 S4O6-2 0.57302E-09 -9.2418 0.21206E-11 -11.6735 0.37008E-02 -2.4317 152 ZnCl+ 0.36757E-03 -3.4347 0.85321E-04 -4.0689 0.23212E+00 -0.6343 153 ZnCl2,aq 0.10400E-02 -2.9830 0.10400E-02 -2.9830 0.10000E+01 0.0000 154 ZnCl3- 0.11345E-03 -3.9452 0.23566E-04 -4.6277 0.20772E+00 -0.6825 155 ZnO,aq 0.35663E-07 -7.4478 0.35663E-07 -7.4478 0.10000E+01 0.0000 156 ZnOH+ 0.20811E-05 -5.6817 0.48307E-06 -6.3160 0.23212E+00 -0.6343 158 HZnO2- 0.28787E-09 -9.5408 0.59796E-10 -10.2233 0.20772E+00 -0.6825 Charge balance for all species = 0.2550E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7987230E-05 0.4303452E+01 0.3540795E+04 0.0000 2 H2O 0.1000000E+01 0.5250733E+02 0.7721659E+06 0.0000 3 Cl- 0.1682738E+00 0.6564717E+00 0.1899845E+05 4.2667 4 SO4-- 0.1963501E-03 0.2531930E+00 0.1985412E+05 5.3419 5 HCO3- 0.1689186E-04 0.2676544E+01 0.1333140E+06 0.3016 6 HS- 0.1347488E-03 0.1167419E+01 0.3151638E+05 1.1740 7 H4SiO4 0.7161060E-01 0.7161399E-01 0.5618754E+04 -1.1450 8 Al+++ 0.8666926E-17 0.1631533E-04 0.3593446E+00 -5.3936 9 Ca++ 0.1891744E-05 0.2676819E-03 0.8757379E+01 3.2305 10 Mg++ 0.1166033E-05 0.1676652E-04 0.3327461E+00 2.9336 11 Fe++ 0.1659815E-07 0.5848515E-02 0.2666212E+03 1.1090 12 K+ 0.4613121E-01 0.1263727E+00 0.4033681E+04 3.7491 13 Na+ 0.1520362E+00 0.5584564E+00 0.1048030E+05 4.2283 14 Mn++ 0.6773529E-06 0.1158266E-02 0.5194339E+02 2.7359 15 Zn++ 0.4163080E-09 0.1523116E-02 0.8127569E+02 -0.4916 16 Cu+ 0.2678942E-07 0.1342022E-03 0.6960751E+01 -2.5269 17 Pb++ 0.3420122E-08 0.3427892E-03 0.5797559E+02 0.5378 18 Ag+ 0.3260634E-09 0.8767769E-05 0.7720385E+00 -4.4086 19 Ba++ 0.1283929E-06 0.2073021E-04 0.2324074E+01 2.1439 20 HPO4-- 0.9976198E-09 0.2999585E-05 0.2350101E+00 0.0500 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4270603E+01 -.8240393E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5210653E+02 -.1417519E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2512603E+00 0.4624888E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1158508E+01 0.1636572E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.7106734E-01 0.7252698E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1619079E-04 0.6783487E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2656386E-03 0.2622713E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1663854E-04 0.4038111E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.5803872E-02 0.2962882E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254081E+00 0.2027612E-05 0.0000000E+00 13 Na+ 0.5545993E+00 0.5541936E+00 0.4057927E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149424E-02 0.7557365E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1511490E-02 0.7878451E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1331778E-03 0.2664319E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.2057197E-04 0.3480048E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2976688E-05 0.5590812E-05 0.0000000E+00 Chg. balance for solid moles: 0.2067E-18 Mass of aqueous solution: 0.121569E+04 g Temperature = 577.00 C Pressure = 1372.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.1177E-03 -3.929 0.1602E-01 -1.795 0.3349 0.5407E-02 annite 0.6564E-06 -6.183 0.3360E-03 -3.474 0.7022E-02 0.1013E-03 phlogopite 0.1346E-05 -5.871 0.5617E-03 -3.251 0.1174E-01 0.2014E-03 biotite-Mn 0.2519E-07 -7.599 0.1283E-04 -4.892 0.2681E-03 0.3845E-05 apatite-OH 0.1864E-05 -5.730 0.9361E-03 -3.029 0.1957E-01 0.2975E-03 magnetite 0.7938E-03 -3.100 0.1838 -0.736 3.841 0.3534E-01 pyrite 0.3129E-03 -3.505 0.3755E-01 -1.425 0.7847 0.7491E-02 quartz 0.7103E-01 -1.149 4.268 0.630 89.19 1.612 barite 0.3480E-04 -4.458 0.8122E-02 -2.090 0.1698 0.1813E-02 chalcopyrite 0.2664E-03 -3.574 0.4889E-01 -1.311 1.022 0.1141E-01 sphalerite 0.7878E-03 -3.104 0.7676E-01 -1.115 1.604 0.1877E-01 an25ab75 0.5411E-03 -3.267 0.1440 -0.842 3.010 0.5423E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3237E+00 0.3237E+00 1.0000 -0.490 phlogopite 0.6639E+00 0.6639E+00 1.0000 -0.178 biotite-Mn 0.1242E-01 0.1242E-01 1.0000 -1.906 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an25ab75 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.784665 g Volume = 1.746728 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.32 -14.32 0.00 0.000 -0.69103E-11 24 annite -0.28 -0.28 0.00 0.000 -0.32824E-10 25 phlogopite 4.25 4.25 0.00 0.000 0.00000E+00 26 biotite-Mn 8.85 8.85 0.00 0.000 -0.69103E-11 30 apatite-OH -52.38 -52.38 0.00 0.000 0.00000E+00 106 magnetite 1.50 1.50 0.00 0.000 -0.24186E-10 140 pyrite -21.25 -21.25 0.00 0.000 -0.13821E-10 144 quartz -1.14 -1.14 0.00 0.000 -0.86379E-12 237 barite -15.41 -15.41 0.00 0.000 0.00000E+00 240 chalcopyrite -22.87 -22.87 0.00 0.000 -0.13821E-10 255 sphalerite -10.76 -10.76 0.00 0.000 0.69103E-11 259 an25ab75 -5.91 -5.91 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.28 -0.280 0.10897E+04 2.857 2 CO2,gas -9.58 -11.14 -1.56 -0.521 0.60861E+04 1.573 3 CH4,gas 6.91 -3.87 -10.77 -2.694 0.41915E+05 -7.637 4 H2,gas 5.87 1.82 -4.05 -2.315 0.15757E+05 -0.913 5 H2S,gas -7.98 -10.27 -2.29 -1.146 0.89123E+04 0.846 6 CO,gas -3.50 -9.32 -5.82 -1.790 0.22637E+05 -2.682 7 SO3,gas -7.10 -17.55 -10.45 -2.612 0.40649E+05 -7.312 8 O2,gas 16.62 -3.64 -20.26 -13.507 0.78814E+05 -17.123 9 HCl,gas -5.89 -7.18 -1.29 -0.643 0.50043E+04 -1.286 10 acmite 3.67 2.14 -1.53 -0.159 0.59606E+04 12 akimotoite 5.94 1.79 -4.15 -0.830 0.16152E+05 13 akimotoite-Fe 3.87 -0.03 -3.91 -0.782 0.15202E+05 14 albite-high -4.47 -4.59 -0.12 -0.009 0.46568E+03 15 albite -4.45 -4.59 -0.14 -0.011 0.54055E+03 16 almandine -9.42 -10.90 -1.48 -0.074 0.57437E+04 17 pyrope -2.88 -5.42 -2.55 -0.127 0.99028E+04 18 analcite -2.50 -3.45 -0.95 -0.106 0.37001E+04 19 andalusite -11.56 -11.93 -0.37 -0.037 0.14588E+04 20 andradite 11.25 6.66 -4.59 -0.238 0.17854E+05 21 grossular 0.28 -4.53 -4.81 -0.241 0.18728E+05 27 anorthite -9.29 -9.85 -0.56 -0.043 0.21776E+04 28 anthophyllite 13.65 11.39 -2.26 -0.061 0.88020E+04 29 anthophyllite-Fe 1.22 -1.38 -2.60 -0.070 0.10120E+05 31 apatite-OH-zs -50.24 -52.38 -2.14 -0.164 0.83119E+04 32 apatite-Cl-zs -56.41 -59.56 -3.15 -0.262 0.12243E+05 33 aragonite -4.42 -7.91 -3.49 -1.164 0.13584E+05 34 brucite 5.18 2.93 -2.25 -0.449 0.87397E+04 35 calcite -4.52 -7.91 -3.39 -1.131 0.13197E+05 36 carnegieite-low -0.55 -2.31 -1.76 -0.251 0.68333E+04 37 carnegieite-high -0.48 -2.31 -1.83 -0.261 0.71156E+04 38 carpholite-Mg -8.25 -10.15 -1.90 -0.127 0.73846E+04 39 carpholite-Fe -9.58 -11.97 -2.39 -0.159 0.92918E+04 40 celadonite -1.18 -3.28 -2.11 -0.124 0.81953E+04 41 celadonite-Fe -2.56 -5.11 -2.54 -0.150 0.98978E+04 42 chrysotile 8.95 6.51 -2.44 -0.203 0.94991E+04 44 clinochlore 1.82 0.44 -1.39 -0.043 0.53954E+04 45 daphnite -5.13 -8.69 -3.55 -0.111 0.13826E+05 48 chloritoid-Mg -7.79 -9.00 -1.22 -0.081 0.47297E+04 49 chloritoid-Fe -9.69 -10.83 -1.13 -0.076 0.44149E+04 50 chloritoid-Mn -7.53 -9.20 -1.67 -0.111 0.64856E+04 52 coesite -0.86 -1.14 -0.28 -0.095 0.11029E+04 53 cordierite-H -20.81 -21.43 -0.63 -0.022 0.24317E+04 54 cordierite-Fe -23.31 -25.08 -1.77 -0.061 0.68863E+04 55 cordierite-Mn -18.91 -21.82 -2.91 -0.100 0.11319E+05 56 corundum -10.25 -10.79 -0.55 -0.050 0.21222E+04 58 cristobalite -1.09 -1.14 -0.05 -0.016 0.18765E+03 59 cummingtonite 13.71 11.39 -2.33 -0.063 0.90446E+04 61 cymrite-K -2.80 -5.07 -2.27 -0.190 0.88463E+04 63 diaspore -4.62 -5.40 -0.78 -0.130 0.30233E+04 65 diopside 5.20 3.88 -1.33 -0.133 0.51636E+04 66 hedenbergite 3.80 2.05 -1.75 -0.175 0.68145E+04 68 eastonite -7.63 -8.86 -1.23 -0.047 0.47852E+04 69 enstatite 4.45 3.58 -0.87 -0.087 0.33947E+04 70 clinoenstatite-HiP 4.94 3.58 -1.36 -0.136 0.52936E+04 71 clinoenstatite 4.44 3.58 -0.86 -0.086 0.33395E+04 72 protoenstatite 4.58 3.58 -1.00 -0.100 0.39041E+04 73 epidote -5.54 -7.56 -2.02 -0.098 0.78630E+04 74 clinozoisite -10.75 -13.16 -2.41 -0.109 0.93695E+04 75 epidote-Fe 1.34 -1.97 -3.31 -0.172 0.12868E+05 76 fayalite 1.98 1.07 -0.91 -0.130 0.35383E+04 77 ferrosilite 0.93 -0.07 -1.00 -0.100 0.38998E+04 78 forsterite 5.92 4.72 -1.19 -0.170 0.46410E+04 79 gedrite -11.88 -13.78 -1.90 -0.051 0.73738E+04 81 gibbsite -3.01 -5.40 -2.39 -0.341 0.92922E+04 82 glaucophane 0.42 -2.68 -3.09 -0.084 0.12030E+05 83 glaucophane-Fe -3.57 -8.15 -4.59 -0.124 0.17837E+05 84 goethite 1.00 0.20 -0.81 -0.175 0.31401E+04 86 greenalite 4.16 1.04 -3.13 -0.261 0.12171E+05 87 grunerite 1.76 -1.38 -3.14 -0.085 0.12229E+05 88 halite -0.89 -2.95 -2.06 -1.030 0.80120E+04 89 hematite 0.48 0.40 -0.08 -0.010 0.32499E+03 90 heulandite -12.69 -15.57 -2.88 -0.131 0.11197E+05 91 hercynite -8.71 -9.68 -0.98 -0.065 0.37932E+04 94 jadeite -1.82 -3.45 -1.63 -0.163 0.63496E+04 96 kalsilite -1.18 -2.79 -1.61 -0.230 0.62755E+04 97 kaolinite -10.45 -13.08 -2.63 -0.239 0.10229E+05 98 kyanite -11.40 -11.93 -0.53 -0.053 0.20702E+04 100 laumontite -8.72 -12.14 -3.42 -0.228 0.13286E+05 101 lawsonite -6.54 -9.85 -3.31 -0.221 0.12886E+05 102 leucite -2.97 -3.93 -0.96 -0.096 0.37246E+04 104 lizardite 9.13 6.51 -2.62 -0.219 0.10209E+05 105 magnesite -5.37 -8.21 -2.84 -0.946 0.11037E+05 107 minnesotaite 0.63 -1.25 -1.87 -0.110 0.72940E+04 108 minnesotaite-Mg 6.51 4.23 -2.28 -0.134 0.88640E+04 109 magnesioferrite 4.53 3.33 -1.20 -0.098 0.46730E+04 111 manganosite 5.18 2.73 -2.45 -0.613 0.95320E+04 112 margarite -19.06 -20.64 -1.58 -0.063 0.61470E+04 115 microcline -5.05 -5.07 -0.02 -0.002 0.83808E+02 116 monticellite 8.49 5.02 -3.47 -0.495 0.13486E+05 118 mullite-Si -10.83 -11.93 -1.11 -0.111 0.43095E+04 119 muscovite -15.16 -15.87 -0.70 -0.041 0.27330E+04 120 paragonite -14.49 -15.39 -0.90 -0.053 0.35050E+04 121 nepheline -0.85 -2.31 -1.46 -0.209 0.56947E+04 122 osumilite(2) -14.33 -16.20 -1.88 -0.039 0.73050E+04 123 osumilite-Fe -30.28 -32.43 -2.15 -0.045 0.83791E+04 124 pargasite 3.14 -0.63 -3.77 -0.099 0.14674E+05 125 periclase 5.36 2.93 -2.43 -0.607 0.94517E+04 126 periclase-Fe 2.82 1.11 -1.71 -0.428 0.66592E+04 127 perovskite-Al -8.54 -10.79 -2.26 -0.205 0.87797E+04 132 phlogopite-Na 5.12 4.20 -0.92 -0.051 0.35688E+04 134 prehnite -4.65 -7.76 -3.12 -0.183 0.12122E+05 135 prehnite-Fe 0.95 -2.17 -3.12 -0.188 0.12136E+05 138 px-Mg-tschermaks -7.22 -9.00 -1.79 -0.128 0.69492E+04 139 px-Ca-tschermaks -6.28 -8.71 -2.43 -0.173 0.94339E+04 141 pyrrhotite -8.55 -9.16 -0.61 -0.205 0.23901E+04 142 pyrrhotiteFe0.875 -9.29 -9.53 -0.24 -0.089 0.94080E+03 143 pyrophyllite -14.11 -15.36 -1.25 -0.078 0.48571E+04 146 riebeckite 5.75 3.04 -2.71 -0.075 0.10550E+05 147 ringwoodite-Fe 2.97 1.07 -1.90 -0.271 0.73851E+04 148 ringwoodite-Mg 9.03 4.72 -4.31 -0.616 0.16776E+05 149 rhodochrosite -5.28 -8.41 -3.12 -1.042 0.12155E+05 150 rhodonite 2.44 1.59 -0.84 -0.169 0.32784E+04 151 sanidine -4.52 -5.07 -0.55 -0.043 0.21524E+04 153 siderite -7.18 -10.04 -2.86 -0.953 0.11120E+05 154 sillimanite -11.53 -11.93 -0.41 -0.041 0.15855E+04 156 spinel -6.57 -7.86 -1.29 -0.086 0.50194E+04 162 stilpnomelane-Fe -7.99 -12.53 -4.54 -0.135 0.17655E+05 163 stilpnomelane-Mg -1.33 -3.40 -2.07 -0.062 0.80474E+04 164 stishovite 1.78 -1.14 -2.92 -0.973 0.11355E+05 165 sudoite-Fe -18.94 -22.80 -3.86 -0.125 0.15018E+05 166 sudoite -16.76 -19.15 -2.39 -0.077 0.93074E+04 167 sulfur -10.60 -12.09 -1.49 -0.459 0.57985E+04 168 sylvite -0.80 -3.43 -2.63 -1.317 0.10246E+05 169 talc 4.79 4.23 -0.57 -0.033 0.22028E+04 170 talc-Fe 2.01 -1.25 -3.26 -0.191 0.12663E+05 171 talc-tschermaks -6.80 -8.36 -1.56 -0.091 0.60494E+04 173 tephroite 6.28 4.33 -1.96 -0.280 0.76160E+04 176 topaz-H -9.48 -11.94 -2.46 -0.224 0.95682E+04 177 tremolite 14.57 11.98 -2.59 -0.070 0.10057E+05 179 troilite-low -8.45 -9.16 -0.71 -0.236 0.27595E+04 180 tschermakite -10.19 -13.18 -2.99 -0.081 0.11637E+05 183 wadsleyite-Fe 2.82 1.07 -1.75 -0.250 0.67984E+04 184 wadsleyite-Mg 8.10 4.72 -3.38 -0.483 0.13142E+05 185 wairakite -10.55 -12.13 -1.58 -0.093 0.61479E+04 186 walstromite 4.54 2.09 -2.46 -0.491 0.95594E+04 187 wollastonite 4.13 2.09 -2.04 -0.409 0.79551E+04 188 pseudo-wollastonite 4.25 2.09 -2.16 -0.432 0.83955E+04 189 zoisite -10.80 -13.16 -2.35 -0.107 0.91490E+04 192 beidellite-Ca -14.67 -16.23 -1.56 -0.096 0.60657E+04 193 beidellite-H -14.68 -16.76 -2.09 -0.133 0.81139E+04 194 beidellite-K -13.62 -15.53 -1.90 -0.117 0.74024E+04 195 beidellite-Mg -14.96 -16.28 -1.33 -0.082 0.51549E+04 196 beidellite-Na -13.57 -15.37 -1.80 -0.110 0.70170E+04 197 bornite -53.06 -53.52 -0.46 -0.035 0.18071E+04 199 chalcocite -13.79 -15.33 -1.53 -0.383 0.59674E+04 200 covellite -12.29 -13.71 -1.42 -0.540 0.55171E+04 202 montmorillonite-Ca -10.90 -12.08 -1.18 -0.073 0.45957E+04 203 montmorillonite-K -10.14 -11.38 -1.24 -0.076 0.48100E+04 204 montmorillonite-Mg -11.13 -12.13 -1.00 -0.062 0.38809E+04 205 montmorillonite-Na -9.79 -11.22 -1.43 -0.087 0.55568E+04 206 nontronite-Ca -3.70 -5.04 -1.34 -0.087 0.52247E+04 207 nontronite-H -3.72 -5.58 -1.86 -0.125 0.72438E+04 208 nontronite-K -2.66 -4.34 -1.68 -0.108 0.65512E+04 209 nontronite-Mg -3.94 -5.09 -1.15 -0.075 0.44805E+04 210 nontronite-Na -2.59 -4.18 -1.59 -0.102 0.61800E+04 215 gypsum -12.12 -14.32 -2.20 -0.551 0.85697E+04 232 alabandite -6.27 -7.54 -1.27 -0.422 0.49242E+04 234 anglesite -14.52 -17.01 -2.50 -1.249 0.97153E+04 238 boehmite -4.34 -5.40 -1.06 -0.177 0.41254E+04 242 copper,native 1.76 -1.62 -3.37 -1.174 0.13126E+05 244 ferrous-oxide 1.90 1.11 -0.79 -0.199 0.30894E+04 245 galena -9.52 -9.73 -0.21 -0.070 0.81942E+03 246 silver,native 0.52 -3.50 -4.01 -1.396 0.15618E+05 248 litharge 5.22 0.54 -4.69 -1.171 0.18228E+05 256 wurtzite -9.97 -10.76 -0.79 -0.265 0.30889E+04 257 zincite 2.02 -0.49 -2.51 -0.627 0.97605E+04 258 an20ab80 -5.64 -5.64 -0.01 0.000 0.23007E+02 260 an30ab70 -6.17 -6.17 0.00 0.000 0.64078E+00 261 tr.625ac.25prg.125 8.99 8.13 -0.86 -0.023 0.33529E+04 Calculations done for 577.0000 Deg. C; 1372.0000 bar Temperature changed by -1.000 degrees to 576.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 30 Loop limit = 500 Temperature = 576.00 C Pressure = 1348.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5509E+02 kg liquid = 0.9924E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9962 Stoichiometric ionic strength = .3293738E+01 Osmotic coef. = 0.0000 True ionic strength = .1956432E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.76179E-05 -5.1182 0.17832E-05 -5.7488 0.23408E+00 -0.6306 2 H2O 0.99622E+00 -0.0016 0.99622E+00 -0.0016 3 Cl- 0.16456E+00 -0.7837 0.33697E-01 -1.4724 0.20477E+00 -0.6887 4 SO4-- 0.19927E-03 -3.7006 0.76015E-06 -6.1191 0.38147E-02 -2.4185 5 HCO3- 0.16159E-04 -4.7916 0.35713E-05 -5.4472 0.22100E+00 -0.6556 6 HS- 0.13344E-03 -3.8747 0.27559E-04 -4.5597 0.20652E+00 -0.6850 7 H4SiO4 0.69702E-01 -1.1568 0.69702E-01 -1.1568 0.10000E+01 0.0000 8 Al+++ 0.91268E-17 -17.0397 0.25843E-22 -22.5877 0.28315E-05 -5.5480 9 Ca++ 0.18223E-05 -5.7394 0.55815E-08 -8.2533 0.30628E-02 -2.5139 10 Mg++ 0.11477E-05 -5.9402 0.28787E-08 -8.5408 0.25083E-02 -2.6006 11 Fe++ 0.16235E-07 -7.7895 0.42844E-10 -10.3681 0.26389E-02 -2.5786 12 K+ 0.45217E-01 -1.3447 0.10252E-01 -1.9892 0.22674E+00 -0.6445 13 Na+ 0.14850E+00 -0.8283 0.30798E-01 -1.5115 0.20740E+00 -0.6832 14 Mn++ 0.70354E-06 -6.1527 0.19267E-08 -8.7152 0.27385E-02 -2.5625 15 Zn++ 0.40505E-09 -9.3925 0.10689E-11 -11.9711 0.26389E-02 -2.5786 16 Cu+ 0.25264E-07 -7.5975 0.52255E-08 -8.2819 0.20684E+00 -0.6844 17 Pb++ 0.33429E-08 -8.4759 0.11491E-10 -10.9396 0.34374E-02 -2.4638 18 Ag+ 0.32188E-09 -9.4923 0.71819E-10 -10.1438 0.22312E+00 -0.6515 19 Ba++ 0.12133E-06 -6.9160 0.44851E-09 -9.3482 0.36967E-02 -2.4322 20 HPO4-- 0.10145E-08 -8.9938 0.38896E-11 -11.4101 0.38342E-02 -2.4163 21 HSiO3- 0.17506E-05 -5.7568 0.35847E-06 -6.4455 0.20477E+00 -0.6887 22 Ca(HSiO3)+ 0.82638E-08 -8.0828 0.18905E-08 -8.7234 0.22877E+00 -0.6406 23 Mg(HSiO3)+ 0.12064E-08 -8.9185 0.27598E-09 -9.5591 0.22877E+00 -0.6406 24 NaHSiO3,aq 0.16307E-05 -5.7876 0.16307E-05 -5.7876 0.10000E+01 0.0000 28 AgCl,aq 0.83835E-07 -7.0766 0.83835E-07 -7.0766 0.10000E+01 0.0000 29 AgCl2- 0.49814E-05 -5.3027 0.10201E-05 -5.9914 0.20477E+00 -0.6887 30 AgCl3-2 0.21286E-05 -5.6719 0.75078E-08 -8.1245 0.35272E-02 -2.4526 31 AgCl4-3 0.15671E-05 -5.8049 0.38234E-11 -11.4176 0.24397E-05 -5.6127 34 Ag(HS),aq 0.98536E-09 -9.0064 0.98536E-09 -9.0064 0.10000E+01 0.0000 35 Ag(HS)2- 0.49770E-08 -8.3030 0.10192E-08 -8.9918 0.20477E+00 -0.6887 38 HAlO2,aq 0.43885E-08 -8.3577 0.43885E-08 -8.3577 0.10000E+01 0.0000 39 AlO2- 0.16069E-04 -4.7940 0.28706E-05 -5.5420 0.17864E+00 -0.7480 41 Ba(HCO3)+ 0.51061E-06 -6.2919 0.12163E-06 -6.9150 0.23821E+00 -0.6230 42 BaCl+ 0.18702E-04 -4.7281 0.42786E-05 -5.3687 0.22877E+00 -0.6406 43 CH4,aq 0.17639E-08 -8.7535 0.21203E-08 -8.6736 0.12021E+01 0.0799 48 CO,aq 0.66247E-03 -3.1788 0.66247E-03 -3.1788 0.10000E+01 0.0000 49 CO2,aq 0.26757E+01 0.4274 0.32164E+01 0.5074 0.12021E+01 0.0799 50 CO3-2 0.43584E-10 -10.3607 0.15373E-12 -12.8133 0.35272E-02 -2.4526 51 CaCO3,aq 0.13685E-10 -10.8638 0.13685E-10 -10.8638 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.27279E-06 -6.5642 0.62408E-07 -7.2048 0.22877E+00 -0.6406 53 CaCl+ 0.14189E-03 -3.8480 0.32462E-04 -4.4886 0.22877E+00 -0.6406 54 CaCl2,aq 0.11111E-03 -3.9543 0.11111E-03 -3.9543 0.10000E+01 0.0000 55 CaOH+ 0.24821E-06 -6.6052 0.56785E-07 -7.2458 0.22877E+00 -0.6406 56 CaSO4,aq 0.14640E-06 -6.8344 0.14640E-06 -6.8344 0.10000E+01 0.0000 57 HCl,aq 0.18140E-02 -2.7414 0.18140E-02 -2.7414 0.10000E+01 0.0000 66 CuCl,aq 0.26526E-04 -4.5763 0.26526E-04 -4.5763 0.10000E+01 0.0000 67 CuCl2- 0.10116E-03 -3.9950 0.20715E-04 -4.6837 0.20477E+00 -0.6887 68 CuCl3-2 0.23135E-05 -5.6357 0.81602E-08 -8.0883 0.35272E-02 -2.4526 74 FeCl+ 0.39140E-06 -6.4074 0.89542E-07 -7.0480 0.22877E+00 -0.6406 75 FeCl2,aq 0.55795E-02 -2.2534 0.55795E-02 -2.2534 0.10000E+01 0.0000 77 FeO,aq 0.76254E-07 -7.1177 0.76254E-07 -7.1177 0.10000E+01 0.0000 78 FeOH+ 0.31170E-07 -7.5063 0.71310E-08 -8.1469 0.22877E+00 -0.6406 79 HFeO2- 0.95469E-08 -8.0201 0.19549E-08 -8.7089 0.20477E+00 -0.6887 82 FeO2- 0.62180E-08 -8.2064 0.12733E-08 -8.8951 0.20477E+00 -0.6887 83 HFeO2,aq 0.27868E-09 -9.5549 0.27868E-09 -9.5549 0.10000E+01 0.0000 84 H2,aq 0.46291E-02 -2.3345 0.55646E-02 -2.2546 0.12021E+01 0.0799 85 KCl,aq 0.63918E-01 -1.1944 0.63918E-01 -1.1944 0.10000E+01 0.0000 86 KHSO4,aq 0.13035E-01 -1.8849 0.13035E-01 -1.8849 0.10000E+01 0.0000 87 KOH,aq 0.11480E-05 -5.9401 0.11480E-05 -5.9401 0.10000E+01 0.0000 88 KSO4- 0.41935E-02 -2.3774 0.85871E-03 -3.0662 0.20477E+00 -0.6887 90 Mg(HCO3)+ 0.53984E-07 -7.2677 0.12350E-07 -7.9083 0.22877E+00 -0.6406 91 MgCl+ 0.14542E-04 -4.8374 0.33267E-05 -5.4780 0.22877E+00 -0.6406 92 MgOH+ 0.53278E-06 -6.2734 0.12189E-06 -6.9140 0.22877E+00 -0.6406 94 MnO,aq 0.54212E-07 -7.2659 0.54212E-07 -7.2659 0.10000E+01 0.0000 95 MnOH+ 0.16673E-06 -6.7780 0.38144E-07 -7.4186 0.22877E+00 -0.6406 97 HMnO2- 0.29810E-10 -10.5256 0.61044E-11 -11.2144 0.20477E+00 -0.6887 100 MnCl+ 0.11572E-02 -2.9366 0.26474E-03 -3.5772 0.22877E+00 -0.6406 101 MnSO4,aq 0.60610E-07 -7.2175 0.60610E-07 -7.2175 0.10000E+01 0.0000 102 NaCl,aq 0.40992E+00 -0.3873 0.40992E+00 -0.3873 0.10000E+01 0.0000 103 NaOH,aq 0.15960E-05 -5.7970 0.15960E-05 -5.7970 0.10000E+01 0.0000 105 OH- 0.83746E-05 -5.0770 0.14960E-05 -5.8251 0.17864E+00 -0.7480 110 HPO3-2 0.12044E-10 -10.9192 0.42479E-13 -13.3718 0.35272E-02 -2.4526 111 H3PO3,aq 0.10699E-09 -9.9707 0.10699E-09 -9.9707 0.10000E+01 0.0000 112 H2PO3- 0.30568E-08 -8.5147 0.62596E-09 -9.2035 0.20477E+00 -0.6887 113 H3PO4,aq 0.94272E-06 -6.0256 0.94272E-06 -6.0256 0.10000E+01 0.0000 114 H2PO4- 0.14904E-05 -5.8267 0.32128E-06 -6.4931 0.21557E+00 -0.6664 116 H4P2O7,aq 0.77840E-10 -10.1088 0.77840E-10 -10.1088 0.10000E+01 0.0000 117 H3P2O7- 0.90445E-09 -9.0436 0.18521E-09 -9.7323 0.20477E+00 -0.6887 118 H2P2O7-2 0.24928E-06 -6.6033 0.87924E-09 -9.0559 0.35272E-02 -2.4526 119 HP2O7-3 0.15308E-07 -7.8151 0.37348E-13 -13.4277 0.24397E-05 -5.6127 121 PbCl+ 0.17898E-05 -5.7472 0.40945E-06 -6.3878 0.22877E+00 -0.6406 122 PbCl2,aq 0.86798E-04 -4.0615 0.86798E-04 -4.0615 0.10000E+01 0.0000 123 PbCl3- 0.10850E-03 -3.9646 0.22218E-04 -4.6533 0.20477E+00 -0.6887 124 PbCl4-2 0.24025E-04 -4.6193 0.84740E-07 -7.0719 0.35272E-02 -2.4526 125 PbO,aq 0.49189E-08 -8.3081 0.49189E-08 -8.3081 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11003E-03 -3.9585 0.11003E-03 -3.9585 0.10000E+01 0.0000 128 Pb(HS)3- 0.11618E-04 -4.9349 0.23790E-05 -5.6236 0.20477E+00 -0.6887 129 H2S,aq 0.10555E+01 0.0234 0.12688E+01 0.1034 0.12021E+01 0.0799 130 S2-2 0.14302E-07 -7.8446 0.50446E-10 -10.2972 0.35272E-02 -2.4526 131 S3-2 0.14160E-08 -8.8489 0.49945E-11 -11.3015 0.35272E-02 -2.4526 132 S3- 0.15396E-01 -1.8126 0.31526E-02 -2.5013 0.20477E+00 -0.6887 133 S4-2 0.11783E-09 -9.9287 0.41562E-12 -12.3813 0.35272E-02 -2.4526 135 SO2,aq 0.28948E+00 -0.5384 0.28948E+00 -0.5384 0.10000E+01 0.0000 136 SO3-2 0.60291E-09 -9.2197 0.33844E-11 -11.4705 0.56134E-02 -2.2508 137 HSO3- 0.33798E-03 -3.4711 0.69209E-04 -4.1598 0.20477E+00 -0.6887 138 HSO4- 0.99483E-02 -2.0022 0.23375E-02 -2.6312 0.23497E+00 -0.6290 140 S2O3-2 0.52155E-06 -6.2827 0.18396E-08 -8.7353 0.35272E-02 -2.4526 141 HS2O3- 0.51882E-06 -6.2850 0.10624E-06 -6.9737 0.20477E+00 -0.6887 142 H2S2O3,aq 0.27152E-07 -7.5662 0.27152E-07 -7.5662 0.10000E+01 0.0000 150 S4O6-2 0.55383E-09 -9.2566 0.19535E-11 -11.7092 0.35272E-02 -2.4526 152 ZnCl+ 0.34093E-03 -3.4673 0.77997E-04 -4.1079 0.22877E+00 -0.6406 153 ZnCl2,aq 0.99592E-03 -3.0018 0.99592E-03 -3.0018 0.10000E+01 0.0000 154 ZnCl3- 0.10520E-03 -3.9780 0.21542E-04 -4.6667 0.20477E+00 -0.6887 155 ZnO,aq 0.35250E-07 -7.4528 0.35250E-07 -7.4528 0.10000E+01 0.0000 156 ZnOH+ 0.19671E-05 -5.7062 0.45003E-06 -6.3468 0.22877E+00 -0.6406 158 HZnO2- 0.28471E-09 -9.5456 0.58302E-10 -10.2343 0.20477E+00 -0.6887 Charge balance for all species = 0.2550E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7617891E-05 0.4302470E+01 0.3540714E+04 0.0000 2 H2O 0.1000000E+01 0.5250860E+02 0.7723432E+06 0.0000 3 Cl- 0.1645582E+00 0.6564283E+00 0.1900110E+05 4.2764 4 SO4-- 0.1992691E-03 0.2530412E+00 0.1984629E+05 5.3785 5 HCO3- 0.1615945E-04 0.2676367E+01 0.1333326E+06 0.3016 6 HS- 0.1334432E-03 0.1166187E+01 0.3148959E+05 1.1891 7 H4SiO4 0.6970247E-01 0.6970586E-01 0.5470167E+04 -1.1568 8 Al+++ 0.9126779E-17 0.1607326E-04 0.3540856E+00 -5.3413 9 Ca++ 0.1822326E-05 0.2554986E-03 0.8360514E+01 3.2444 10 Mg++ 0.1147691E-05 0.1627719E-04 0.3231011E+00 2.9568 11 Fe++ 0.1623526E-07 0.5580065E-02 0.2544353E+03 1.1295 12 K+ 0.4521701E-01 0.1263641E+00 0.4034235E+04 3.7596 13 Na+ 0.1484959E+00 0.5584195E+00 0.1048176E+05 4.2373 14 Mn++ 0.7035402E-06 0.1158175E-02 0.5194996E+02 2.7824 15 Zn++ 0.4050493E-09 0.1444059E-02 0.7707292E+02 -0.4735 16 Cu+ 0.2526397E-07 0.1300262E-03 0.6745537E+01 -2.5331 17 Pb++ 0.3342881E-08 0.3427666E-03 0.5798367E+02 0.5580 18 Ag+ 0.3218832E-09 0.8767190E-05 0.7721461E+00 -4.3950 19 Ba++ 0.1213268E-06 0.1933438E-04 0.2168032E+01 2.1494 20 HPO4-- 0.1014453E-08 0.2968424E-05 0.2326165E+00 0.0875 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4269910E+01 -.7547927E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5211123E+02 -.1464489E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2511262E+00 0.5965594E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1157362E+01 0.2782632E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.6917834E-01 0.7441598E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1595162E-04 0.6785879E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2535651E-03 0.2743448E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1615401E-04 0.4522645E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.5537836E-02 0.3228918E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254079E+00 0.2275674E-05 0.0000000E+00 13 Na+ 0.5545993E+00 0.5541936E+00 0.4057873E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149410E-02 0.9019958E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1433131E-02 0.8662039E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1290422E-03 0.2705675E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1918806E-04 0.3618439E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2945960E-05 0.5621541E-05 0.0000000E+00 Chg. balance for solid moles: 0.2412E-17 Mass of aqueous solution: 0.121552E+04 g Temperature = 576.00 C Pressure = 1348.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.1297E-03 -3.887 0.1766E-01 -1.753 0.3565 0.5960E-02 annite 0.7381E-06 -6.132 0.3778E-03 -3.423 0.7626E-02 0.1139E-03 phlogopite 0.1508E-05 -5.822 0.6291E-03 -3.201 0.1270E-01 0.2256E-03 biotite-Mn 0.3007E-07 -7.522 0.1531E-04 -4.815 0.3090E-03 0.4589E-05 apatite-OH 0.1874E-05 -5.727 0.9413E-03 -3.026 0.1900E-01 0.2991E-03 magnetite 0.6844E-03 -3.165 0.1584 -0.800 3.198 0.3047E-01 pyrite 0.9030E-03 -3.044 0.1083 -0.965 2.187 0.2162E-01 quartz 0.7292E-01 -1.137 4.381 0.642 88.44 1.654 barite 0.3618E-04 -4.441 0.8445E-02 -2.073 0.1705 0.1885E-02 chalcopyrite 0.2706E-03 -3.568 0.4965E-01 -1.304 1.002 0.1159E-01 sphalerite 0.8662E-03 -3.062 0.8439E-01 -1.074 1.704 0.2064E-01 an25ab75 0.5410E-03 -3.267 0.1440 -0.842 2.907 0.5423E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3243E+00 0.3243E+00 1.0000 -0.489 phlogopite 0.6625E+00 0.6625E+00 1.0000 -0.179 biotite-Mn 0.1321E-01 0.1321E-01 1.0000 -1.879 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an25ab75 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.954034 g Volume = 1.801530 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.37 -14.37 0.00 0.000 0.00000E+00 24 annite -0.20 -0.20 0.00 0.000 -0.23510E-10 25 phlogopite 4.36 4.36 0.00 0.000 -0.24158E-10 26 biotite-Mn 8.93 8.93 0.00 0.000 -0.13804E-10 30 apatite-OH -52.50 -52.50 0.00 0.000 -0.55217E-10 106 magnetite 1.56 1.56 0.00 0.000 0.12942E-10 140 pyrite -21.31 -21.31 0.00 0.000 0.00000E+00 144 quartz -1.15 -1.15 0.00 0.000 0.00000E+00 237 barite -15.47 -15.47 0.00 0.000 0.00000E+00 240 chalcopyrite -22.93 -22.93 0.00 0.000 -0.13804E-10 255 sphalerite -10.78 -10.78 0.00 0.000 0.00000E+00 259 an25ab75 -5.86 -5.86 0.00 0.000 -0.10353E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.28 -0.279 0.10847E+04 2.851 2 CO2,gas -9.62 -11.19 -1.58 -0.525 0.61239E+04 1.554 3 CH4,gas 6.90 -3.89 -10.79 -2.698 0.41938E+05 -7.664 4 H2,gas 5.88 1.83 -4.05 -2.315 0.15742E+05 -0.922 5 H2S,gas -8.01 -10.31 -2.29 -1.147 0.89141E+04 0.836 6 CO,gas -3.53 -9.37 -5.83 -1.795 0.22672E+05 -2.705 7 SO3,gas -7.15 -17.62 -10.47 -2.616 0.40664E+05 -7.336 8 O2,gas 16.63 -3.65 -20.28 -13.523 0.78817E+05 -17.155 9 HCl,gas -5.92 -7.22 -1.30 -0.652 0.50691E+04 -1.305 10 acmite 3.67 2.14 -1.52 -0.158 0.59220E+04 12 akimotoite 5.96 1.80 -4.16 -0.832 0.16165E+05 13 akimotoite-Fe 3.89 -0.03 -3.91 -0.783 0.15207E+05 14 albite-high -4.45 -4.57 -0.12 -0.009 0.45185E+03 15 albite -4.43 -4.57 -0.13 -0.010 0.52292E+03 16 almandine -9.27 -10.76 -1.50 -0.075 0.58122E+04 17 pyrope -2.71 -5.28 -2.57 -0.129 0.99980E+04 18 analcite -2.47 -3.42 -0.95 -0.105 0.36879E+04 19 andalusite -11.45 -11.84 -0.39 -0.039 0.15079E+04 20 andradite 11.29 6.70 -4.60 -0.239 0.17857E+05 21 grossular 0.41 -4.42 -4.83 -0.242 0.18781E+05 27 anorthite -9.18 -9.75 -0.57 -0.044 0.22268E+04 28 anthophyllite 13.74 11.46 -2.29 -0.062 0.88799E+04 29 anthophyllite-Fe 1.27 -1.33 -2.61 -0.070 0.10134E+05 31 apatite-OH-zs -50.36 -52.50 -2.14 -0.165 0.83141E+04 32 apatite-Cl-zs -56.57 -59.72 -3.16 -0.263 0.12266E+05 33 aragonite -4.45 -7.95 -3.51 -1.168 0.13620E+05 34 brucite 5.21 2.95 -2.25 -0.450 0.87500E+04 35 calcite -4.55 -7.95 -3.41 -1.135 0.13232E+05 36 carnegieite-low -0.51 -2.26 -1.75 -0.251 0.68159E+04 37 carnegieite-high -0.43 -2.26 -1.83 -0.261 0.71001E+04 38 carpholite-Mg -8.13 -10.04 -1.92 -0.128 0.74416E+04 39 carpholite-Fe -9.47 -11.87 -2.40 -0.160 0.93416E+04 40 celadonite -1.14 -3.25 -2.11 -0.124 0.81839E+04 41 celadonite-Fe -2.53 -5.07 -2.54 -0.150 0.98803E+04 42 chrysotile 9.01 6.56 -2.45 -0.204 0.95250E+04 44 clinochlore 2.03 0.62 -1.41 -0.044 0.54822E+04 45 daphnite -4.94 -8.52 -3.57 -0.112 0.13876E+05 48 chloritoid-Mg -7.66 -8.89 -1.23 -0.082 0.47875E+04 49 chloritoid-Fe -9.57 -10.71 -1.15 -0.077 0.44617E+04 50 chloritoid-Mn -7.41 -9.06 -1.65 -0.110 0.64247E+04 52 coesite -0.87 -1.15 -0.28 -0.095 0.11039E+04 53 cordierite-H -20.58 -21.23 -0.66 -0.023 0.25528E+04 54 cordierite-Fe -23.09 -24.89 -1.80 -0.062 0.69754E+04 55 cordierite-Mn -18.70 -21.58 -2.88 -0.099 0.11191E+05 56 corundum -10.13 -10.69 -0.56 -0.051 0.21725E+04 58 cristobalite -1.11 -1.15 -0.05 -0.016 0.18610E+03 59 cummingtonite 13.81 11.46 -2.35 -0.063 0.91243E+04 61 cymrite-K -2.77 -5.05 -2.27 -0.189 0.88315E+04 63 diaspore -4.56 -5.34 -0.78 -0.131 0.30457E+04 65 diopside 5.22 3.89 -1.33 -0.133 0.51779E+04 66 hedenbergite 3.82 2.06 -1.76 -0.176 0.68213E+04 68 eastonite -7.43 -8.67 -1.24 -0.048 0.48304E+04 69 enstatite 4.48 3.60 -0.88 -0.088 0.34191E+04 70 clinoenstatite-HiP 4.97 3.60 -1.37 -0.137 0.53191E+04 71 clinoenstatite 4.47 3.60 -0.87 -0.087 0.33635E+04 72 protoenstatite 4.61 3.60 -1.01 -0.101 0.39287E+04 73 epidote -5.41 -7.45 -2.04 -0.099 0.79163E+04 74 clinozoisite -10.58 -13.01 -2.43 -0.111 0.94485E+04 75 epidote-Fe 1.43 -1.89 -3.32 -0.172 0.12893E+05 76 fayalite 2.01 1.10 -0.91 -0.130 0.35448E+04 77 ferrosilite 0.95 -0.05 -1.01 -0.101 0.39072E+04 78 forsterite 5.96 4.76 -1.20 -0.171 0.46635E+04 79 gedrite -11.58 -13.52 -1.94 -0.052 0.75293E+04 81 gibbsite -2.95 -5.35 -2.40 -0.342 0.93146E+04 82 glaucophane 0.52 -2.58 -3.09 -0.084 0.12024E+05 83 glaucophane-Fe -3.48 -8.06 -4.58 -0.124 0.17807E+05 84 goethite 1.02 0.21 -0.81 -0.175 0.31391E+04 86 greenalite 4.21 1.07 -3.13 -0.261 0.12169E+05 87 grunerite 1.82 -1.33 -3.15 -0.085 0.12245E+05 88 halite -0.93 -2.98 -2.06 -1.029 0.79933E+04 89 hematite 0.51 0.43 -0.08 -0.010 0.32239E+03 90 heulandite -12.63 -15.53 -2.90 -0.132 0.11267E+05 91 hercynite -8.57 -9.56 -0.99 -0.066 0.38468E+04 94 jadeite -1.78 -3.41 -1.63 -0.163 0.63345E+04 96 kalsilite -1.13 -2.74 -1.61 -0.230 0.62531E+04 97 kaolinite -10.36 -13.00 -2.64 -0.240 0.10264E+05 98 kyanite -11.30 -11.84 -0.55 -0.055 0.21208E+04 100 laumontite -8.63 -12.07 -3.43 -0.229 0.13339E+05 101 lawsonite -6.43 -9.75 -3.33 -0.222 0.12938E+05 102 leucite -2.94 -3.89 -0.95 -0.095 0.37026E+04 104 lizardite 9.19 6.56 -2.63 -0.219 0.10231E+05 105 magnesite -5.39 -8.24 -2.85 -0.951 0.11082E+05 107 minnesotaite 0.65 -1.23 -1.88 -0.110 0.72934E+04 108 minnesotaite-Mg 6.54 4.25 -2.29 -0.135 0.88881E+04 109 magnesioferrite 4.59 3.38 -1.20 -0.098 0.46815E+04 111 manganosite 5.21 2.78 -2.43 -0.607 0.94265E+04 112 margarite -18.83 -20.44 -1.61 -0.064 0.62457E+04 115 microcline -5.03 -5.05 -0.01 -0.001 0.57484E+02 116 monticellite 8.52 5.04 -3.47 -0.496 0.13497E+05 118 mullite-Si -10.72 -11.84 -1.12 -0.112 0.43609E+04 119 muscovite -15.02 -15.73 -0.71 -0.042 0.27589E+04 120 paragonite -14.35 -15.26 -0.91 -0.054 0.35377E+04 121 nepheline -0.80 -2.26 -1.46 -0.209 0.56768E+04 122 osumilite(2) -14.20 -16.09 -1.89 -0.039 0.73567E+04 123 osumilite-Fe -30.06 -32.24 -2.17 -0.045 0.84507E+04 124 pargasite 3.39 -0.41 -3.80 -0.100 0.14767E+05 125 periclase 5.39 2.96 -2.44 -0.609 0.94626E+04 126 periclase-Fe 2.84 1.13 -1.71 -0.429 0.66634E+04 127 perovskite-Al -8.41 -10.69 -2.27 -0.207 0.88304E+04 132 phlogopite-Na 5.22 4.30 -0.92 -0.051 0.35833E+04 134 prehnite -4.53 -7.66 -3.13 -0.184 0.12172E+05 135 prehnite-Fe 1.02 -2.11 -3.13 -0.188 0.12159E+05 138 px-Mg-tschermaks -7.08 -8.89 -1.80 -0.129 0.70128E+04 139 px-Ca-tschermaks -6.16 -8.60 -2.44 -0.174 0.94867E+04 141 pyrrhotite -8.56 -9.18 -0.62 -0.205 0.23944E+04 142 pyrrhotiteFe0.875 -9.30 -9.55 -0.24 -0.089 0.94522E+03 143 pyrophyllite -14.04 -15.30 -1.26 -0.079 0.49032E+04 146 riebeckite 5.75 3.06 -2.70 -0.074 0.10473E+05 147 ringwoodite-Fe 3.00 1.10 -1.90 -0.272 0.73904E+04 148 ringwoodite-Mg 9.08 4.76 -4.32 -0.618 0.16798E+05 149 rhodochrosite -5.30 -8.41 -3.11 -1.036 0.12081E+05 150 rhodonite 2.44 1.63 -0.82 -0.163 0.31737E+04 151 sanidine -4.50 -5.05 -0.55 -0.042 0.21261E+04 153 siderite -7.20 -10.07 -2.87 -0.957 0.11154E+05 154 sillimanite -11.42 -11.84 -0.42 -0.042 0.16358E+04 156 spinel -6.42 -7.73 -1.31 -0.087 0.50796E+04 162 stilpnomelane-Fe -7.85 -12.41 -4.55 -0.136 0.17689E+05 163 stilpnomelane-Mg -1.18 -3.27 -2.09 -0.063 0.81376E+04 164 stishovite 1.77 -1.15 -2.92 -0.974 0.11356E+05 165 sudoite-Fe -18.69 -22.59 -3.90 -0.126 0.15134E+05 166 sudoite -16.50 -18.93 -2.43 -0.078 0.94391E+04 167 sulfur -10.64 -12.13 -1.49 -0.459 0.58008E+04 168 sylvite -0.83 -3.46 -2.63 -1.315 0.10218E+05 169 talc 4.82 4.25 -0.57 -0.034 0.22290E+04 170 talc-Fe 2.03 -1.23 -3.26 -0.192 0.12665E+05 171 talc-tschermaks -6.67 -8.24 -1.57 -0.093 0.61149E+04 173 tephroite 6.31 4.41 -1.91 -0.272 0.74041E+04 176 topaz-H -9.37 -11.84 -2.47 -0.225 0.96150E+04 177 tremolite 14.63 12.03 -2.60 -0.070 0.10112E+05 179 troilite-low -8.47 -9.18 -0.71 -0.237 0.27621E+04 180 tschermakite -9.92 -12.95 -3.03 -0.082 0.11766E+05 183 wadsleyite-Fe 2.85 1.10 -1.75 -0.250 0.68053E+04 184 wadsleyite-Mg 8.15 4.76 -3.39 -0.484 0.13165E+05 185 wairakite -10.47 -12.06 -1.59 -0.094 0.61915E+04 186 walstromite 4.55 2.09 -2.46 -0.492 0.95613E+04 187 wollastonite 4.14 2.09 -2.05 -0.409 0.79557E+04 188 pseudo-wollastonite 4.25 2.09 -2.16 -0.432 0.83969E+04 189 zoisite -10.63 -13.01 -2.38 -0.108 0.92298E+04 192 beidellite-Ca -14.58 -16.15 -1.58 -0.097 0.61203E+04 193 beidellite-H -14.58 -16.69 -2.10 -0.134 0.81674E+04 194 beidellite-K -13.53 -15.45 -1.91 -0.117 0.74408E+04 195 beidellite-Mg -14.86 -16.20 -1.34 -0.083 0.52141E+04 196 beidellite-Na -13.47 -15.29 -1.82 -0.111 0.70578E+04 197 bornite -53.22 -53.68 -0.46 -0.035 0.17989E+04 199 chalcocite -13.84 -15.37 -1.53 -0.384 0.59606E+04 200 covellite -12.34 -13.75 -1.42 -0.540 0.55102E+04 202 montmorillonite-Ca -10.84 -12.03 -1.19 -0.074 0.46366E+04 203 montmorillonite-K -10.08 -11.32 -1.25 -0.076 0.48382E+04 204 montmorillonite-Mg -11.07 -12.08 -1.01 -0.062 0.39230E+04 205 montmorillonite-Na -9.73 -11.17 -1.44 -0.088 0.55821E+04 206 nontronite-Ca -3.69 -5.03 -1.35 -0.087 0.52290E+04 207 nontronite-H -3.70 -5.57 -1.87 -0.125 0.72475E+04 208 nontronite-K -2.65 -4.33 -1.68 -0.108 0.65399E+04 209 nontronite-Mg -3.93 -5.08 -1.15 -0.075 0.44872E+04 210 nontronite-Na -2.58 -4.17 -1.59 -0.102 0.61706E+04 215 gypsum -12.17 -14.38 -2.21 -0.552 0.85781E+04 232 alabandite -6.29 -7.53 -1.24 -0.414 0.48223E+04 234 anglesite -14.57 -17.06 -2.48 -1.242 0.96536E+04 238 boehmite -4.28 -5.34 -1.07 -0.178 0.41491E+04 242 copper,native 1.76 -1.62 -3.38 -1.174 0.13116E+05 244 ferrous-oxide 1.92 1.13 -0.80 -0.199 0.30943E+04 245 galena -9.56 -9.75 -0.19 -0.065 0.75684E+03 246 silver,native 0.51 -3.48 -3.99 -1.389 0.15517E+05 248 litharge 5.23 0.56 -4.67 -1.169 0.18162E+05 256 wurtzite -9.99 -10.78 -0.79 -0.265 0.30890E+04 257 zincite 2.04 -0.48 -2.51 -0.628 0.97599E+04 258 an20ab80 -5.60 -5.60 -0.01 0.000 0.19583E+02 260 an30ab70 -6.12 -6.12 0.00 0.000 0.42169E+01 261 tr.625ac.25prg.125 9.07 8.19 -0.88 -0.024 0.34142E+04 Calculations done for 576.0000 Deg. C; 1348.0000 bar Temperature changed by -1.000 degrees to 575.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 31 Loop limit = 500 Temperature = 575.00 C Pressure = 1325.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5509E+02 kg liquid = 0.9925E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9963 Stoichiometric ionic strength = .3291309E+01 Osmotic coef. = 0.0000 True ionic strength = .1913132E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.72729E-05 -5.1383 0.16842E-05 -5.7736 0.23157E+00 -0.6353 2 H2O 0.99628E+00 -0.0016 0.99628E+00 -0.0016 3 Cl- 0.16097E+00 -0.7933 0.32525E-01 -1.4878 0.20206E+00 -0.6945 4 SO4-- 0.20224E-03 -3.6941 0.73736E-06 -6.1323 0.36460E-02 -2.4382 5 HCO3- 0.15484E-04 -4.8101 0.33760E-05 -5.4716 0.21803E+00 -0.6615 6 HS- 0.13213E-03 -3.8790 0.26925E-04 -4.5698 0.20378E+00 -0.6908 7 H4SiO4 0.67889E-01 -1.1682 0.67889E-01 -1.1682 0.10000E+01 0.0000 8 Al+++ 0.95862E-17 -17.0184 0.24531E-22 -22.6103 0.25590E-05 -5.5919 9 Ca++ 0.17546E-05 -5.7558 0.51350E-08 -8.2895 0.29265E-02 -2.5336 10 Mg++ 0.11292E-05 -5.9472 0.27070E-08 -8.5675 0.23972E-02 -2.6203 11 Fe++ 0.15878E-07 -7.7992 0.40044E-10 -10.3975 0.25219E-02 -2.5983 12 K+ 0.44328E-01 -1.3533 0.99147E-02 -2.0037 0.22367E+00 -0.6504 13 Na+ 0.14509E+00 -0.8384 0.29688E-01 -1.5274 0.20462E+00 -0.6890 14 Mn++ 0.72988E-06 -6.1368 0.19101E-08 -8.7190 0.26170E-02 -2.5822 15 Zn++ 0.39416E-09 -9.4043 0.99405E-12 -12.0026 0.25219E-02 -2.5983 16 Cu+ 0.23854E-07 -7.6224 0.48678E-08 -8.3127 0.20407E+00 -0.6902 17 Pb++ 0.32690E-08 -8.4856 0.10736E-10 -10.9691 0.32842E-02 -2.4836 18 Ag+ 0.31824E-09 -9.4973 0.70045E-10 -10.1546 0.22010E+00 -0.6574 19 Ba++ 0.11462E-06 -6.9407 0.40484E-09 -9.3927 0.35319E-02 -2.4520 20 HPO4-- 0.10323E-08 -8.9862 0.37828E-11 -11.4222 0.36646E-02 -2.4360 21 HSiO3- 0.17257E-05 -5.7630 0.34870E-06 -6.4576 0.20206E+00 -0.6945 22 Ca(HSiO3)+ 0.78832E-08 -8.1033 0.17790E-08 -8.7498 0.22567E+00 -0.6465 23 Mg(HSiO3)+ 0.11870E-08 -8.9256 0.26787E-09 -9.5721 0.22567E+00 -0.6465 24 NaHSiO3,aq 0.16594E-05 -5.7801 0.16594E-05 -5.7801 0.10000E+01 0.0000 28 AgCl,aq 0.85795E-07 -7.0665 0.85795E-07 -7.0665 0.10000E+01 0.0000 29 AgCl2- 0.49993E-05 -5.3011 0.10101E-05 -5.9956 0.20206E+00 -0.6945 30 AgCl3-2 0.20983E-05 -5.6781 0.70740E-08 -8.1503 0.33713E-02 -2.4722 31 AgCl4-3 0.15766E-05 -5.8023 0.34809E-11 -11.4583 0.22078E-05 -5.6560 34 Ag(HS),aq 0.10326E-08 -8.9861 0.10326E-08 -8.9861 0.10000E+01 0.0000 35 Ag(HS)2- 0.50996E-08 -8.2925 0.10304E-08 -8.9870 0.20206E+00 -0.6945 38 HAlO2,aq 0.43759E-08 -8.3589 0.43759E-08 -8.3589 0.10000E+01 0.0000 39 AlO2- 0.15836E-04 -4.8003 0.27928E-05 -5.5540 0.17636E+00 -0.7536 41 Ba(HCO3)+ 0.47479E-06 -6.3235 0.11156E-06 -6.9525 0.23497E+00 -0.6290 42 BaCl+ 0.17450E-04 -4.7582 0.39380E-05 -5.4047 0.22567E+00 -0.6465 43 CH4,aq 0.17493E-08 -8.7571 0.21009E-08 -8.6776 0.12010E+01 0.0795 48 CO,aq 0.65248E-03 -3.1854 0.65248E-03 -3.1854 0.10000E+01 0.0000 49 CO2,aq 0.26755E+01 0.4274 0.32133E+01 0.5069 0.12010E+01 0.0795 50 CO3-2 0.43329E-10 -10.3632 0.14607E-12 -12.8354 0.33713E-02 -2.4722 51 CaCO3,aq 0.13343E-10 -10.8747 0.13343E-10 -10.8747 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.25081E-06 -6.6007 0.56601E-07 -7.2472 0.22567E+00 -0.6465 53 CaCl+ 0.13393E-03 -3.8731 0.30226E-04 -4.5196 0.22567E+00 -0.6465 54 CaCl2,aq 0.10760E-03 -3.9682 0.10760E-03 -3.9682 0.10000E+01 0.0000 55 CaOH+ 0.23724E-06 -6.6248 0.53538E-07 -7.2713 0.22567E+00 -0.6465 56 CaSO4,aq 0.14736E-06 -6.8316 0.14736E-06 -6.8316 0.10000E+01 0.0000 57 HCl,aq 0.18937E-02 -2.7227 0.18937E-02 -2.7227 0.10000E+01 0.0000 66 CuCl,aq 0.25923E-04 -4.5863 0.25923E-04 -4.5863 0.10000E+01 0.0000 67 CuCl2- 0.97869E-04 -4.0094 0.19775E-04 -4.7039 0.20206E+00 -0.6945 68 CuCl3-2 0.21993E-05 -5.6577 0.74144E-08 -8.1299 0.33713E-02 -2.4722 74 FeCl+ 0.37521E-06 -6.4257 0.84674E-07 -7.0722 0.22567E+00 -0.6465 75 FeCl2,aq 0.53252E-02 -2.2737 0.53252E-02 -2.2737 0.10000E+01 0.0000 77 FeO,aq 0.75667E-07 -7.1211 0.75667E-07 -7.1211 0.10000E+01 0.0000 78 FeOH+ 0.30179E-07 -7.5203 0.68106E-08 -8.1668 0.22567E+00 -0.6465 79 HFeO2- 0.94664E-08 -8.0238 0.19128E-08 -8.7183 0.20206E+00 -0.6945 82 FeO2- 0.61281E-08 -8.2127 0.12382E-08 -8.9072 0.20206E+00 -0.6945 83 HFeO2,aq 0.28155E-09 -9.5504 0.28155E-09 -9.5504 0.10000E+01 0.0000 84 H2,aq 0.46478E-02 -2.3328 0.55819E-02 -2.2532 0.12010E+01 0.0795 85 KCl,aq 0.64682E-01 -1.1892 0.64682E-01 -1.1892 0.10000E+01 0.0000 86 KHSO4,aq 0.13095E-01 -1.8829 0.13095E-01 -1.8829 0.10000E+01 0.0000 87 KOH,aq 0.11734E-05 -5.9306 0.11734E-05 -5.9306 0.10000E+01 0.0000 88 KSO4- 0.42475E-02 -2.3719 0.85824E-03 -3.0664 0.20206E+00 -0.6945 90 Mg(HCO3)+ 0.50195E-07 -7.2993 0.11328E-07 -7.9459 0.22567E+00 -0.6465 91 MgCl+ 0.14107E-04 -4.8506 0.31837E-05 -5.4971 0.22567E+00 -0.6465 92 MgOH+ 0.52206E-06 -6.2823 0.11782E-06 -6.9288 0.22567E+00 -0.6465 94 MnO,aq 0.57370E-07 -7.2413 0.57370E-07 -7.2413 0.10000E+01 0.0000 95 MnOH+ 0.17015E-06 -6.7692 0.38398E-07 -7.4157 0.22567E+00 -0.6465 97 HMnO2- 0.31270E-10 -10.5049 0.63183E-11 -11.1994 0.20206E+00 -0.6945 100 MnCl+ 0.11570E-02 -2.9366 0.26112E-03 -3.5832 0.22567E+00 -0.6465 101 MnSO4,aq 0.65221E-07 -7.1856 0.65221E-07 -7.1856 0.10000E+01 0.0000 102 NaCl,aq 0.41329E+00 -0.3837 0.41329E+00 -0.3837 0.10000E+01 0.0000 103 NaOH,aq 0.16244E-05 -5.7893 0.16244E-05 -5.7893 0.10000E+01 0.0000 105 OH- 0.83381E-05 -5.0789 0.14705E-05 -5.8325 0.17636E+00 -0.7536 110 HPO3-2 0.11855E-10 -10.9261 0.39967E-13 -13.3983 0.33713E-02 -2.4722 111 H3PO3,aq 0.10672E-09 -9.9718 0.10672E-09 -9.9718 0.10000E+01 0.0000 112 H2PO3- 0.29301E-08 -8.5331 0.59205E-09 -9.2276 0.20206E+00 -0.6945 113 H3PO4,aq 0.95561E-06 -6.0197 0.95561E-06 -6.0197 0.10000E+01 0.0000 114 H2PO4- 0.14650E-05 -5.8342 0.31158E-06 -6.5064 0.21268E+00 -0.6723 116 H4P2O7,aq 0.80664E-10 -10.0933 0.80664E-10 -10.0933 0.10000E+01 0.0000 117 H3P2O7- 0.88281E-09 -9.0541 0.17838E-09 -9.7487 0.20206E+00 -0.6945 118 H2P2O7-2 0.24250E-06 -6.6153 0.81753E-09 -9.0875 0.33713E-02 -2.4722 119 HP2O7-3 0.15714E-07 -7.8037 0.34692E-13 -13.4598 0.22078E-05 -5.6560 121 PbCl+ 0.17300E-05 -5.7620 0.39042E-06 -6.4085 0.22567E+00 -0.6465 122 PbCl2,aq 0.86647E-04 -4.0622 0.86647E-04 -4.0622 0.10000E+01 0.0000 123 PbCl3- 0.10773E-03 -3.9677 0.21767E-04 -4.6622 0.20206E+00 -0.6945 124 PbCl4-2 0.23367E-04 -4.6314 0.78778E-07 -7.1036 0.33713E-02 -2.4722 125 PbO,aq 0.50876E-08 -8.2935 0.50876E-08 -8.2935 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11140E-03 -3.9531 0.11140E-03 -3.9531 0.10000E+01 0.0000 128 Pb(HS)3- 0.11858E-04 -4.9260 0.23961E-05 -5.6205 0.20206E+00 -0.6945 129 H2S,aq 0.10549E+01 0.0232 0.12669E+01 0.1027 0.12010E+01 0.0795 130 S2-2 0.14172E-07 -7.8486 0.47777E-10 -10.3208 0.33713E-02 -2.4722 131 S3-2 0.13878E-08 -8.8577 0.46786E-11 -11.3299 0.33713E-02 -2.4722 132 S3- 0.14810E-01 -1.8294 0.29924E-02 -2.5240 0.20206E+00 -0.6945 133 S4-2 0.11437E-09 -9.9417 0.38556E-12 -12.4139 0.33713E-02 -2.4722 135 SO2,aq 0.28979E+00 -0.5379 0.28979E+00 -0.5379 0.10000E+01 0.0000 136 SO3-2 0.60794E-09 -9.2161 0.32625E-11 -11.4864 0.53666E-02 -2.2703 137 HSO3- 0.32943E-03 -3.4822 0.66563E-04 -4.1768 0.20206E+00 -0.6945 138 HSO4- 0.97574E-02 -2.0107 0.22617E-02 -2.6456 0.23180E+00 -0.6349 140 S2O3-2 0.51904E-06 -6.2848 0.17498E-08 -8.7570 0.33713E-02 -2.4722 141 HS2O3- 0.50164E-06 -6.2996 0.10136E-06 -6.9941 0.20206E+00 -0.6945 142 H2S2O3,aq 0.27384E-07 -7.5625 0.27384E-07 -7.5625 0.10000E+01 0.0000 150 S4O6-2 0.53575E-09 -9.2710 0.18062E-11 -11.7432 0.33713E-02 -2.4722 152 ZnCl+ 0.31670E-03 -3.4994 0.71471E-04 -4.1459 0.22567E+00 -0.6465 153 ZnCl2,aq 0.95440E-03 -3.0203 0.95440E-03 -3.0203 0.10000E+01 0.0000 154 ZnCl3- 0.97643E-04 -4.0104 0.19730E-04 -4.7049 0.20206E+00 -0.6945 155 ZnO,aq 0.34858E-07 -7.4577 0.34858E-07 -7.4577 0.10000E+01 0.0000 156 ZnOH+ 0.18620E-05 -5.7300 0.42020E-06 -6.3765 0.22567E+00 -0.6465 158 HZnO2- 0.28167E-09 -9.5503 0.56914E-10 -10.2448 0.20206E+00 -0.6945 Charge balance for all species = 0.2550E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7272892E-05 0.4300624E+01 0.3539976E+04 0.0000 2 H2O 0.1000000E+01 0.5250997E+02 0.7725338E+06 0.0000 3 Cl- 0.1609668E+00 0.6563793E+00 0.1900387E+05 4.2858 4 SO4-- 0.2022362E-03 0.2528279E+00 0.1983395E+05 5.4149 5 HCO3- 0.1548389E-04 0.2676167E+01 0.1333521E+06 0.3020 6 HS- 0.1321306E-03 0.1164277E+01 0.3144497E+05 1.2038 7 H4SiO4 0.6788890E-01 0.6789230E-01 0.5329025E+04 -1.1682 8 Al+++ 0.9586152E-17 0.1584064E-04 0.3490382E+00 -5.2894 9 Ca++ 0.1754641E-05 0.2439275E-03 0.7983643E+01 3.2578 10 Mg++ 0.1129224E-05 0.1580998E-04 0.3138964E+00 2.9797 11 Fe++ 0.1587849E-07 0.5325694E-02 0.2428904E+03 1.1498 12 K+ 0.4432835E-01 0.1263545E+00 0.4034817E+04 3.7699 13 Na+ 0.1450872E+00 0.5583778E+00 0.1048329E+05 4.2462 14 Mn++ 0.7298752E-06 0.1158072E-02 0.5195684E+02 2.8283 15 Zn++ 0.3941627E-09 0.1370639E-02 0.7317047E+02 -0.4554 16 Cu+ 0.2385424E-07 0.1260153E-03 0.6538900E+01 -2.5390 17 Pb++ 0.3269005E-08 0.3427410E-03 0.5799214E+02 0.5781 18 Ag+ 0.3182363E-09 0.8766535E-05 0.7722589E+00 -4.3810 19 Ba++ 0.1146235E-06 0.1803937E-04 0.2023265E+01 2.1545 20 HPO4-- 0.1032251E-08 0.2943030E-05 0.2306774E+00 0.1250 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4268397E+01 -.6034327E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5211648E+02 -.1516995E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2509333E+00 0.7894380E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1155553E+01 0.4591400E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.6738354E-01 0.7621078E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1572194E-04 0.6788176E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2420996E-03 0.2858103E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1569151E-04 0.4985141E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.5285786E-02 0.3480968E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254076E+00 0.2513748E-05 0.0000000E+00 13 Na+ 0.5545993E+00 0.5541936E+00 0.4057823E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149394E-02 0.1058352E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1360368E-02 0.9389666E-03 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1250710E-03 0.2745387E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1790419E-04 0.3746826E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2920976E-05 0.5646525E-05 0.0000000E+00 Chg. balance for solid moles: 0.7674E-18 Mass of aqueous solution: 0.121534E+04 g Temperature = 575.00 C Pressure = 1325.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.1411E-03 -3.850 0.1921E-01 -1.716 0.3744 0.6485E-02 annite 0.8168E-06 -6.088 0.4181E-03 -3.379 0.8147E-02 0.1260E-03 phlogopite 0.1662E-05 -5.779 0.6934E-03 -3.159 0.1351E-01 0.2486E-03 biotite-Mn 0.3528E-07 -7.452 0.1796E-04 -4.746 0.3500E-03 0.5384E-05 apatite-OH 0.1882E-05 -5.725 0.9455E-03 -3.024 0.1842E-01 0.3004E-03 magnetite 0.4490E-03 -3.348 0.1039 -0.983 2.025 0.1999E-01 pyrite 0.1857E-02 -2.731 0.2228 -0.652 4.342 0.4446E-01 quartz 0.7472E-01 -1.127 4.489 0.652 87.48 1.695 barite 0.3747E-04 -4.426 0.8745E-02 -2.058 0.1704 0.1952E-02 chalcopyrite 0.2745E-03 -3.561 0.5038E-01 -1.298 0.9817 0.1176E-01 sphalerite 0.9390E-03 -3.027 0.9148E-01 -1.039 1.783 0.2237E-01 an25ab75 0.5410E-03 -3.267 0.1440 -0.842 2.807 0.5423E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3249E+00 0.3249E+00 1.0000 -0.488 phlogopite 0.6611E+00 0.6611E+00 1.0000 -0.180 biotite-Mn 0.1403E-01 0.1403E-01 1.0000 -1.853 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an25ab75 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.131580 g Volume = 1.857128 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.42 -14.42 0.00 0.000 0.00000E+00 24 annite -0.11 -0.11 0.00 0.000 -0.15296E-10 25 phlogopite 4.45 4.45 0.00 0.000 0.34470E-11 26 biotite-Mn 9.02 9.02 0.00 0.000 0.00000E+00 30 apatite-OH -52.62 -52.62 0.00 0.000 -0.27576E-10 106 magnetite 1.61 1.61 0.00 0.000 0.43088E-11 140 pyrite -21.37 -21.37 0.00 0.000 0.13788E-10 144 quartz -1.16 -1.16 0.00 0.000 0.00000E+00 237 barite -15.53 -15.53 0.00 0.000 0.00000E+00 240 chalcopyrite -22.99 -22.99 0.00 0.000 -0.13788E-10 255 sphalerite -10.80 -10.80 0.00 0.000 0.00000E+00 259 an25ab75 -5.82 -5.82 0.00 0.000 -0.68940E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.28 -0.278 0.10796E+04 2.844 2 CO2,gas -9.66 -11.24 -1.59 -0.529 0.61596E+04 1.535 3 CH4,gas 6.90 -3.91 -10.81 -2.703 0.41959E+05 -7.689 4 H2,gas 5.88 1.83 -4.05 -2.316 0.15728E+05 -0.930 5 H2S,gas -8.05 -10.34 -2.30 -1.149 0.89160E+04 0.825 6 CO,gas -3.56 -9.41 -5.85 -1.800 0.22706E+05 -2.728 7 SO3,gas -7.20 -17.68 -10.48 -2.620 0.40677E+05 -7.359 8 O2,gas 16.64 -3.67 -20.31 -13.539 0.78819E+05 -17.187 9 HCl,gas -5.94 -7.26 -1.32 -0.661 0.51329E+04 -1.323 10 acmite 3.66 2.15 -1.52 -0.158 0.58841E+04 12 akimotoite 5.98 1.81 -4.17 -0.834 0.16178E+05 13 akimotoite-Fe 3.90 -0.02 -3.92 -0.784 0.15212E+05 14 albite-high -4.43 -4.54 -0.11 -0.009 0.43812E+03 15 albite -4.41 -4.54 -0.13 -0.010 0.50540E+03 16 almandine -9.12 -10.63 -1.51 -0.076 0.58787E+04 17 pyrope -2.54 -5.14 -2.60 -0.130 0.10091E+05 18 analcite -2.43 -3.38 -0.95 -0.105 0.36754E+04 19 andalusite -11.35 -11.75 -0.40 -0.040 0.15549E+04 20 andradite 11.34 6.74 -4.60 -0.239 0.17864E+05 21 grossular 0.54 -4.31 -4.85 -0.243 0.18834E+05 27 anorthite -9.07 -9.66 -0.59 -0.045 0.22756E+04 28 anthophyllite 13.83 11.53 -2.31 -0.062 0.89583E+04 29 anthophyllite-Fe 1.33 -1.28 -2.61 -0.071 0.10148E+05 31 apatite-OH-zs -50.48 -52.62 -2.14 -0.165 0.83164E+04 32 apatite-Cl-zs -56.71 -59.88 -3.17 -0.264 0.12288E+05 33 aragonite -4.47 -7.99 -3.52 -1.173 0.13655E+05 34 brucite 5.23 2.98 -2.26 -0.451 0.87600E+04 35 calcite -4.57 -7.99 -3.42 -1.139 0.13265E+05 36 carnegieite-low -0.46 -2.21 -1.75 -0.250 0.67985E+04 37 carnegieite-high -0.39 -2.21 -1.83 -0.261 0.70847E+04 38 carpholite-Mg -8.01 -9.94 -1.93 -0.129 0.74956E+04 39 carpholite-Fe -9.35 -11.77 -2.42 -0.161 0.93884E+04 40 celadonite -1.10 -3.21 -2.11 -0.124 0.81721E+04 41 celadonite-Fe -2.49 -5.04 -2.54 -0.149 0.98625E+04 42 chrysotile 9.06 6.60 -2.46 -0.205 0.95506E+04 44 clinochlore 2.24 0.81 -1.43 -0.045 0.55659E+04 45 daphnite -4.76 -8.34 -3.59 -0.112 0.13923E+05 48 chloritoid-Mg -7.52 -8.77 -1.25 -0.083 0.48427E+04 49 chloritoid-Fe -9.44 -10.60 -1.16 -0.077 0.45059E+04 50 chloritoid-Mn -7.28 -8.92 -1.64 -0.109 0.63634E+04 52 coesite -0.88 -1.16 -0.28 -0.095 0.11048E+04 53 cordierite-H -20.35 -21.04 -0.69 -0.025 0.26703E+04 54 cordierite-Fe -22.88 -24.70 -1.82 -0.063 0.70617E+04 55 cordierite-Mn -18.49 -21.34 -2.85 -0.098 0.11065E+05 56 corundum -10.01 -10.58 -0.57 -0.052 0.22208E+04 58 cristobalite -1.12 -1.16 -0.05 -0.016 0.18472E+03 59 cummingtonite 13.90 11.53 -2.37 -0.064 0.92043E+04 61 cymrite-K -2.75 -5.02 -2.27 -0.189 0.88163E+04 63 diaspore -4.50 -5.29 -0.79 -0.132 0.30668E+04 65 diopside 5.24 3.90 -1.34 -0.134 0.51936E+04 66 hedenbergite 3.83 2.07 -1.76 -0.176 0.68294E+04 68 eastonite -7.23 -8.48 -1.26 -0.048 0.48737E+04 69 enstatite 4.51 3.63 -0.89 -0.089 0.34437E+04 70 clinoenstatite-HiP 5.00 3.63 -1.38 -0.138 0.53448E+04 71 clinoenstatite 4.50 3.63 -0.87 -0.087 0.33877E+04 72 protoenstatite 4.64 3.63 -1.02 -0.102 0.39536E+04 73 epidote -5.28 -7.34 -2.05 -0.100 0.79696E+04 74 clinozoisite -10.40 -12.86 -2.45 -0.112 0.95265E+04 75 epidote-Fe 1.52 -1.81 -3.33 -0.173 0.12919E+05 76 fayalite 2.05 1.13 -0.92 -0.131 0.35515E+04 77 ferrosilite 0.98 -0.03 -1.01 -0.101 0.39147E+04 78 forsterite 6.00 4.79 -1.21 -0.173 0.46864E+04 79 gedrite -11.29 -13.27 -1.98 -0.053 0.76807E+04 81 gibbsite -2.89 -5.29 -2.41 -0.344 0.93353E+04 82 glaucophane 0.62 -2.48 -3.10 -0.084 0.12018E+05 83 glaucophane-Fe -3.39 -7.97 -4.58 -0.124 0.17776E+05 84 goethite 1.04 0.23 -0.81 -0.175 0.31378E+04 86 greenalite 4.25 1.11 -3.13 -0.261 0.12167E+05 87 grunerite 1.88 -1.28 -3.16 -0.085 0.12262E+05 88 halite -0.96 -3.02 -2.05 -1.027 0.79752E+04 89 hematite 0.54 0.46 -0.08 -0.010 0.31959E+03 90 heulandite -12.57 -15.49 -2.92 -0.133 0.11335E+05 91 hercynite -8.43 -9.44 -1.00 -0.067 0.38983E+04 94 jadeite -1.75 -3.38 -1.63 -0.163 0.63190E+04 96 kalsilite -1.08 -2.69 -1.61 -0.229 0.62310E+04 97 kaolinite -10.26 -12.92 -2.65 -0.241 0.10297E+05 98 kyanite -11.19 -11.75 -0.56 -0.056 0.21693E+04 100 laumontite -8.54 -11.99 -3.45 -0.230 0.13390E+05 101 lawsonite -6.31 -9.66 -3.35 -0.223 0.12987E+05 102 leucite -2.90 -3.85 -0.95 -0.095 0.36811E+04 104 lizardite 9.24 6.60 -2.64 -0.220 0.10253E+05 105 magnesite -5.40 -8.27 -2.87 -0.955 0.11123E+05 107 minnesotaite 0.66 -1.22 -1.88 -0.111 0.72929E+04 108 minnesotaite-Mg 6.57 4.27 -2.30 -0.135 0.89124E+04 109 magnesioferrite 4.65 3.44 -1.21 -0.099 0.46900E+04 111 manganosite 5.23 2.83 -2.40 -0.601 0.93233E+04 112 margarite -18.61 -20.24 -1.63 -0.065 0.63410E+04 115 microcline -5.01 -5.02 -0.01 -0.001 0.31580E+02 116 monticellite 8.55 5.07 -3.48 -0.497 0.13510E+05 118 mullite-Si -10.61 -11.75 -1.14 -0.114 0.44102E+04 119 muscovite -14.89 -15.60 -0.72 -0.042 0.27825E+04 120 paragonite -14.21 -15.13 -0.92 -0.054 0.35677E+04 121 nepheline -0.75 -2.21 -1.46 -0.208 0.56589E+04 122 osumilite(2) -14.08 -15.99 -1.91 -0.040 0.74081E+04 123 osumilite-Fe -29.85 -32.04 -2.20 -0.046 0.85198E+04 124 pargasite 3.63 -0.20 -3.83 -0.101 0.14860E+05 125 periclase 5.42 2.98 -2.44 -0.610 0.94737E+04 126 periclase-Fe 2.87 1.15 -1.72 -0.430 0.66676E+04 127 perovskite-Al -8.30 -10.58 -2.29 -0.208 0.88789E+04 132 phlogopite-Na 5.32 4.39 -0.93 -0.052 0.35979E+04 134 prehnite -4.42 -7.57 -3.15 -0.185 0.12222E+05 135 prehnite-Fe 1.09 -2.04 -3.14 -0.189 0.12182E+05 138 px-Mg-tschermaks -6.95 -8.77 -1.82 -0.130 0.70744E+04 139 px-Ca-tschermaks -6.03 -8.49 -2.46 -0.176 0.95386E+04 141 pyrrhotite -8.58 -9.19 -0.62 -0.206 0.23989E+04 142 pyrrhotiteFe0.875 -9.32 -9.56 -0.24 -0.090 0.94990E+03 143 pyrophyllite -13.97 -15.25 -1.27 -0.080 0.49468E+04 146 riebeckite 5.76 3.08 -2.68 -0.074 0.10397E+05 147 ringwoodite-Fe 3.04 1.13 -1.91 -0.272 0.73958E+04 148 ringwoodite-Mg 9.13 4.79 -4.33 -0.619 0.16820E+05 149 rhodochrosite -5.32 -8.42 -3.09 -1.031 0.12007E+05 150 rhodonite 2.45 1.66 -0.79 -0.158 0.30712E+04 151 sanidine -4.48 -5.02 -0.54 -0.042 0.21001E+04 153 siderite -7.21 -10.10 -2.88 -0.961 0.11186E+05 154 sillimanite -11.31 -11.75 -0.43 -0.043 0.16839E+04 156 spinel -6.28 -7.61 -1.32 -0.088 0.51379E+04 162 stilpnomelane-Fe -7.72 -12.29 -4.57 -0.136 0.17718E+05 163 stilpnomelane-Mg -1.02 -3.14 -2.12 -0.063 0.82243E+04 164 stishovite 1.76 -1.16 -2.93 -0.975 0.11356E+05 165 sudoite-Fe -18.44 -22.37 -3.93 -0.127 0.15245E+05 166 sudoite -16.25 -18.71 -2.46 -0.080 0.95650E+04 167 sulfur -10.68 -12.18 -1.50 -0.460 0.58031E+04 168 sylvite -0.87 -3.49 -2.63 -1.313 0.10192E+05 169 talc 4.85 4.27 -0.58 -0.034 0.22553E+04 170 talc-Fe 2.05 -1.22 -3.26 -0.192 0.12667E+05 171 talc-tschermaks -6.53 -8.12 -1.59 -0.094 0.61783E+04 173 tephroite 6.34 4.49 -1.85 -0.265 0.71967E+04 176 topaz-H -9.26 -11.75 -2.49 -0.226 0.96589E+04 177 tremolite 14.70 12.08 -2.62 -0.071 0.10170E+05 179 troilite-low -8.48 -9.19 -0.71 -0.237 0.27650E+04 180 tschermakite -9.65 -12.71 -3.06 -0.083 0.11895E+05 183 wadsleyite-Fe 2.89 1.13 -1.76 -0.251 0.68123E+04 184 wadsleyite-Mg 8.19 4.79 -3.40 -0.485 0.13188E+05 185 wairakite -10.38 -11.99 -1.61 -0.094 0.62341E+04 186 walstromite 4.56 2.09 -2.46 -0.493 0.95647E+04 187 wollastonite 4.14 2.09 -2.05 -0.410 0.79577E+04 188 pseudo-wollastonite 4.26 2.09 -2.16 -0.433 0.83996E+04 189 zoisite -10.46 -12.86 -2.40 -0.109 0.93098E+04 192 beidellite-Ca -14.48 -16.07 -1.59 -0.098 0.61721E+04 193 beidellite-H -14.49 -16.61 -2.12 -0.135 0.82180E+04 194 beidellite-K -13.44 -15.36 -1.93 -0.118 0.74767E+04 195 beidellite-Mg -14.76 -16.12 -1.36 -0.084 0.52702E+04 196 beidellite-Na -13.38 -15.21 -1.83 -0.112 0.70959E+04 197 bornite -53.37 -53.84 -0.46 -0.034 0.17890E+04 199 chalcocite -13.89 -15.42 -1.53 -0.383 0.59530E+04 200 covellite -12.38 -13.80 -1.42 -0.540 0.55029E+04 202 montmorillonite-Ca -10.77 -11.98 -1.20 -0.075 0.46756E+04 203 montmorillonite-K -10.02 -11.27 -1.25 -0.077 0.48648E+04 204 montmorillonite-Mg -11.00 -12.02 -1.02 -0.063 0.39630E+04 205 montmorillonite-Na -9.67 -11.12 -1.44 -0.088 0.56057E+04 206 nontronite-Ca -3.68 -5.02 -1.35 -0.087 0.52325E+04 207 nontronite-H -3.69 -5.56 -1.87 -0.125 0.72502E+04 208 nontronite-K -2.64 -4.32 -1.68 -0.108 0.65280E+04 209 nontronite-Mg -3.91 -5.07 -1.16 -0.075 0.44928E+04 210 nontronite-Na -2.57 -4.16 -1.59 -0.102 0.61605E+04 215 gypsum -12.21 -14.43 -2.21 -0.553 0.85855E+04 232 alabandite -6.30 -7.52 -1.22 -0.406 0.47228E+04 234 anglesite -14.63 -17.10 -2.47 -1.236 0.95908E+04 238 boehmite -4.22 -5.29 -1.07 -0.179 0.41715E+04 242 copper,native 1.75 -1.62 -3.38 -1.175 0.13106E+05 244 ferrous-oxide 1.95 1.15 -0.80 -0.200 0.30994E+04 245 galena -9.59 -9.77 -0.18 -0.060 0.69486E+03 246 silver,native 0.51 -3.46 -3.97 -1.382 0.15417E+05 248 litharge 5.24 0.58 -4.66 -1.166 0.18096E+05 256 wurtzite -10.00 -10.80 -0.80 -0.265 0.30891E+04 257 zincite 2.06 -0.46 -2.51 -0.629 0.97589E+04 258 an20ab80 -5.56 -5.56 0.00 0.000 0.16220E+02 260 an30ab70 -6.07 -6.08 0.00 0.000 0.77577E+01 261 tr.625ac.25prg.125 9.16 8.26 -0.90 -0.024 0.34779E+04 Calculations done for 575.0000 Deg. C; 1325.0000 bar Temperature changed by -1.000 degrees to 574.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 33 Loop limit = 500 Temperature = 574.00 C Pressure = 1302.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5510E+02 kg liquid = 0.9926E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9963 Stoichiometric ionic strength = .3289307E+01 Osmotic coef. = 0.0000 True ionic strength = .1868886E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.69311E-05 -5.1592 0.15882E-05 -5.7991 0.22914E+00 -0.6399 2 H2O 0.99633E+00 -0.0016 0.99633E+00 -0.0016 3 Cl- 0.15727E+00 -0.8034 0.31368E-01 -1.5035 0.19945E+00 -0.7002 4 SO4-- 0.20497E-03 -3.6883 0.71508E-06 -6.1456 0.34886E-02 -2.4573 5 HCO3- 0.14818E-04 -4.8292 0.31885E-05 -5.4964 0.21518E+00 -0.6672 6 HS- 0.13081E-03 -3.8834 0.26311E-04 -4.5799 0.20115E+00 -0.6965 7 H4SiO4 0.66098E-01 -1.1798 0.66098E-01 -1.1798 0.10000E+01 0.0000 8 Al+++ 0.10024E-16 -16.9989 0.23244E-22 -22.6337 0.23188E-05 -5.6347 9 Ca++ 0.16844E-05 -5.7736 0.47159E-08 -8.3264 0.27998E-02 -2.5529 10 Mg++ 0.11074E-05 -5.9557 0.25407E-08 -8.5950 0.22943E-02 -2.6394 11 Fe++ 0.15481E-07 -7.8102 0.37360E-10 -10.4276 0.24133E-02 -2.6174 12 K+ 0.43415E-01 -1.3624 0.95818E-02 -2.0186 0.22070E+00 -0.6562 13 Na+ 0.14161E+00 -0.8489 0.28599E-01 -1.5437 0.20196E+00 -0.6947 14 Mn++ 0.75670E-06 -6.1211 0.18948E-08 -8.7224 0.25041E-02 -2.6014 15 Zn++ 0.38236E-09 -9.4175 0.92276E-12 -12.0349 0.24133E-02 -2.6174 16 Cu+ 0.22482E-07 -7.6482 0.45280E-08 -8.3441 0.20141E+00 -0.6959 17 Pb++ 0.31891E-08 -8.4963 0.10019E-10 -10.9992 0.31415E-02 -2.5029 18 Ag+ 0.31497E-09 -9.5017 0.68411E-10 -10.1649 0.21720E+00 -0.6631 19 Ba++ 0.10793E-06 -6.9669 0.36461E-09 -9.4382 0.33783E-02 -2.4713 20 HPO4-- 0.10489E-08 -8.9793 0.36778E-11 -11.4344 0.35064E-02 -2.4551 21 HSiO3- 0.17006E-05 -5.7694 0.33920E-06 -6.4695 0.19945E+00 -0.7002 22 Ca(HSiO3)+ 0.75119E-08 -8.1243 0.16728E-08 -8.7766 0.22268E+00 -0.6523 23 Mg(HSiO3)+ 0.11667E-08 -8.9331 0.25979E-09 -9.5854 0.22268E+00 -0.6523 24 NaHSiO3,aq 0.16900E-05 -5.7721 0.16900E-05 -5.7721 0.10000E+01 0.0000 28 AgCl,aq 0.87996E-07 -7.0555 0.87996E-07 -7.0555 0.10000E+01 0.0000 29 AgCl2- 0.50228E-05 -5.2991 0.10018E-05 -5.9992 0.19945E+00 -0.7002 30 AgCl3-2 0.20671E-05 -5.6846 0.66683E-08 -8.1760 0.32260E-02 -2.4913 31 AgCl4-3 0.15815E-05 -5.8009 0.31684E-11 -11.4992 0.20035E-05 -5.6982 34 Ag(HS),aq 0.10854E-08 -8.9644 0.10854E-08 -8.9644 0.10000E+01 0.0000 35 Ag(HS)2- 0.52389E-08 -8.2808 0.10449E-08 -8.9809 0.19945E+00 -0.7002 38 HAlO2,aq 0.43611E-08 -8.3604 0.43611E-08 -8.3604 0.10000E+01 0.0000 39 AlO2- 0.15597E-04 -4.8069 0.27169E-05 -5.5659 0.17419E+00 -0.7590 41 Ba(HCO3)+ 0.44059E-06 -6.3560 0.10215E-06 -6.9908 0.23185E+00 -0.6348 42 BaCl+ 0.16245E-04 -4.7893 0.36175E-05 -5.4416 0.22268E+00 -0.6523 43 CH4,aq 0.17358E-08 -8.7605 0.20826E-08 -8.6814 0.11998E+01 0.0791 48 CO,aq 0.64276E-03 -3.1920 0.64276E-03 -3.1920 0.10000E+01 0.0000 49 CO2,aq 0.26753E+01 0.4274 0.32099E+01 0.5065 0.11998E+01 0.0791 50 CO3-2 0.43017E-10 -10.3664 0.13877E-12 -12.8577 0.32260E-02 -2.4913 51 CaCO3,aq 0.13007E-10 -10.8858 0.13007E-10 -10.8858 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.23010E-06 -6.6381 0.51239E-07 -7.2904 0.22268E+00 -0.6523 53 CaCl+ 0.12617E-03 -3.8990 0.28097E-04 -4.5513 0.22268E+00 -0.6523 54 CaCl2,aq 0.10410E-03 -3.9826 0.10410E-03 -3.9826 0.10000E+01 0.0000 55 CaOH+ 0.22646E-06 -6.6450 0.50430E-07 -7.2973 0.22268E+00 -0.6523 56 CaSO4,aq 0.14833E-06 -6.8288 0.14833E-06 -6.8288 0.10000E+01 0.0000 57 HCl,aq 0.19784E-02 -2.7037 0.19784E-02 -2.7037 0.10000E+01 0.0000 66 CuCl,aq 0.25315E-04 -4.5966 0.25315E-04 -4.5966 0.10000E+01 0.0000 67 CuCl2- 0.94514E-04 -4.0245 0.18851E-04 -4.7247 0.19945E+00 -0.7002 68 CuCl3-2 0.20830E-05 -5.6813 0.67197E-08 -8.1726 0.32260E-02 -2.4913 74 FeCl+ 0.35896E-06 -6.4449 0.79935E-07 -7.0973 0.22268E+00 -0.6523 75 FeCl2,aq 0.50749E-02 -2.2946 0.50749E-02 -2.2946 0.10000E+01 0.0000 77 FeO,aq 0.75089E-07 -7.1244 0.75089E-07 -7.1244 0.10000E+01 0.0000 78 FeOH+ 0.29182E-07 -7.5349 0.64985E-08 -8.1872 0.22268E+00 -0.6523 79 HFeO2- 0.93889E-08 -8.0274 0.18727E-08 -8.7275 0.19945E+00 -0.7002 82 FeO2- 0.60370E-08 -8.2192 0.12041E-08 -8.9193 0.19945E+00 -0.7002 83 HFeO2,aq 0.28446E-09 -9.5460 0.28446E-09 -9.5460 0.10000E+01 0.0000 84 H2,aq 0.46693E-02 -2.3307 0.56022E-02 -2.2516 0.11998E+01 0.0791 85 KCl,aq 0.65467E-01 -1.1840 0.65467E-01 -1.1840 0.10000E+01 0.0000 86 KHSO4,aq 0.13162E-01 -1.8807 0.13162E-01 -1.8807 0.10000E+01 0.0000 87 KOH,aq 0.12004E-05 -5.9207 0.12004E-05 -5.9207 0.10000E+01 0.0000 88 KSO4- 0.43017E-02 -2.3664 0.85800E-03 -3.0665 0.19945E+00 -0.7002 90 Mg(HCO3)+ 0.46553E-07 -7.3321 0.10367E-07 -7.9844 0.22268E+00 -0.6523 91 MgCl+ 0.13659E-04 -4.8646 0.30416E-05 -5.5169 0.22268E+00 -0.6523 92 MgOH+ 0.51093E-06 -6.2916 0.11378E-06 -6.9440 0.22268E+00 -0.6523 94 MnO,aq 0.60870E-07 -7.2156 0.60870E-07 -7.2156 0.10000E+01 0.0000 95 MnOH+ 0.17381E-06 -6.7599 0.38705E-07 -7.4122 0.22268E+00 -0.6523 97 HMnO2- 0.32884E-10 -10.4830 0.65589E-11 -11.1832 0.19945E+00 -0.7002 100 MnCl+ 0.11569E-02 -2.9367 0.25763E-03 -3.5890 0.22268E+00 -0.6523 101 MnSO4,aq 0.70335E-07 -7.1528 0.70335E-07 -7.1528 0.10000E+01 0.0000 102 NaCl,aq 0.41673E+00 -0.3801 0.41673E+00 -0.3801 0.10000E+01 0.0000 103 NaOH,aq 0.16547E-05 -5.7813 0.16547E-05 -5.7813 0.10000E+01 0.0000 105 OH- 0.83005E-05 -5.0809 0.14459E-05 -5.8399 0.17419E+00 -0.7590 110 HPO3-2 0.11651E-10 -10.9336 0.37585E-13 -13.4250 0.32260E-02 -2.4913 111 H3PO3,aq 0.10645E-09 -9.9729 0.10645E-09 -9.9729 0.10000E+01 0.0000 112 H2PO3- 0.28051E-08 -8.5521 0.55948E-09 -9.2522 0.19945E+00 -0.7002 113 H3PO4,aq 0.96832E-06 -6.0140 0.96832E-06 -6.0140 0.10000E+01 0.0000 114 H2PO4- 0.14382E-05 -5.8422 0.30189E-06 -6.5201 0.20991E+00 -0.6780 116 H4P2O7,aq 0.83565E-10 -10.0780 0.83565E-10 -10.0780 0.10000E+01 0.0000 117 H3P2O7- 0.86002E-09 -9.0655 0.17153E-09 -9.7656 0.19945E+00 -0.7002 118 H2P2O7-2 0.23519E-06 -6.6286 0.75871E-09 -9.1199 0.32260E-02 -2.4913 119 HP2O7-3 0.16063E-07 -7.7942 0.32181E-13 -13.4924 0.20035E-05 -5.6982 121 PbCl+ 0.16700E-05 -5.7773 0.37188E-06 -6.4296 0.22268E+00 -0.6523 122 PbCl2,aq 0.86481E-04 -4.0631 0.86481E-04 -4.0631 0.10000E+01 0.0000 123 PbCl3- 0.10683E-03 -3.9713 0.21308E-04 -4.6714 0.19945E+00 -0.7002 124 PbCl4-2 0.22656E-04 -4.6448 0.73087E-07 -7.1362 0.32260E-02 -2.4913 125 PbO,aq 0.52689E-08 -8.2783 0.52689E-08 -8.2783 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11295E-03 -3.9471 0.11295E-03 -3.9471 0.10000E+01 0.0000 128 Pb(HS)3- 0.12122E-04 -4.9164 0.24177E-05 -5.6166 0.19945E+00 -0.7002 129 H2S,aq 0.10547E+01 0.0231 0.12655E+01 0.1023 0.11998E+01 0.0791 130 S2-2 0.14028E-07 -7.8530 0.45254E-10 -10.3443 0.32260E-02 -2.4913 131 S3-2 0.13584E-08 -8.8670 0.43820E-11 -11.3583 0.32260E-02 -2.4913 132 S3- 0.14240E-01 -1.8465 0.28402E-02 -2.5466 0.19945E+00 -0.7002 133 S4-2 0.11083E-09 -9.9553 0.35754E-12 -12.4467 0.32260E-02 -2.4913 135 SO2,aq 0.29016E+00 -0.5374 0.29016E+00 -0.5374 0.10000E+01 0.0000 136 SO3-2 0.61254E-09 -9.2129 0.31454E-11 -11.5023 0.51350E-02 -2.2895 137 HSO3- 0.32081E-03 -3.4938 0.63987E-04 -4.1939 0.19945E+00 -0.7002 138 HSO4- 0.95619E-02 -2.0195 0.21871E-02 -2.6601 0.22873E+00 -0.6407 140 S2O3-2 0.51572E-06 -6.2876 0.16637E-08 -8.7789 0.32260E-02 -2.4913 141 HS2O3- 0.48456E-06 -6.3147 0.96647E-07 -7.0148 0.19945E+00 -0.7002 142 H2S2O3,aq 0.27625E-07 -7.5587 0.27625E-07 -7.5587 0.10000E+01 0.0000 150 S4O6-2 0.51702E-09 -9.2865 0.16679E-11 -11.7778 0.32260E-02 -2.4913 152 ZnCl+ 0.29341E-03 -3.5325 0.65337E-04 -4.1848 0.22268E+00 -0.6523 153 ZnCl2,aq 0.91322E-03 -3.0394 0.91322E-03 -3.0394 0.10000E+01 0.0000 154 ZnCl3- 0.90371E-04 -4.0440 0.18025E-04 -4.7441 0.19945E+00 -0.7002 155 ZnO,aq 0.34470E-07 -7.4626 0.34470E-07 -7.4626 0.10000E+01 0.0000 156 ZnOH+ 0.17591E-05 -5.7547 0.39173E-06 -6.4070 0.22268E+00 -0.6523 158 HZnO2- 0.27871E-09 -9.5548 0.55590E-10 -10.2550 0.19945E+00 -0.7002 Charge balance for all species = 0.2550E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6931085E-05 0.4299423E+01 0.3539696E+04 0.0000 2 H2O 0.1000000E+01 0.5251122E+02 0.7727068E+06 0.0000 3 Cl- 0.1572699E+00 0.6563365E+00 0.1900643E+05 4.2956 4 SO4-- 0.2049743E-03 0.2526650E+00 0.1982513E+05 5.4525 5 HCO3- 0.1481789E-04 0.2675992E+01 0.1333700E+06 0.3027 6 HS- 0.1308065E-03 0.1162900E+01 0.3141406E+05 1.2192 7 H4SiO4 0.6609820E-01 0.6610160E-01 0.5189506E+04 -1.1798 8 Al+++ 0.1002432E-16 0.1560175E-04 0.3438433E+00 -5.2364 9 Ca++ 0.1684401E-05 0.2325660E-03 0.7613307E+01 3.2717 10 Mg++ 0.1107411E-05 0.1532470E-04 0.3043223E+00 3.0031 11 Fe++ 0.1548072E-07 0.5075405E-02 0.2315217E+03 1.1706 12 K+ 0.4341476E-01 0.1263460E+00 0.4035352E+04 3.7805 13 Na+ 0.1416079E+00 0.5583414E+00 0.1048470E+05 4.2554 14 Mn++ 0.7567026E-06 0.1157979E-02 0.5196303E+02 2.8758 15 Zn++ 0.3823582E-09 0.1298793E-02 0.6934888E+02 -0.4367 16 Cu+ 0.2248187E-07 0.1219349E-03 0.6328434E+01 -2.5450 17 Pb++ 0.3189099E-08 0.3427186E-03 0.5799995E+02 0.5990 18 Ag+ 0.3149717E-09 0.8765963E-05 0.7723629E+00 -4.3658 19 Ba++ 0.1079289E-06 0.1679354E-04 0.1883911E+01 2.1600 20 HPO4-- 0.1048872E-08 0.2914882E-05 0.2285169E+00 0.1638 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4267484E+01 -.5121648E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5212113E+02 -.1563473E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2507880E+00 0.9348040E-03 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1154261E+01 0.5882891E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.6561054E-01 0.7798378E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1548585E-04 0.6790537E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2308383E-03 0.2970716E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1521085E-04 0.5465797E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.5037700E-02 0.3729053E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254074E+00 0.2762558E-05 0.0000000E+00 13 Na+ 0.5545993E+00 0.5541936E+00 0.4057747E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149376E-02 0.1238757E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1289144E-02 0.1010190E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1210290E-03 0.2785807E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1666878E-04 0.3870367E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2893228E-05 0.5674272E-05 0.0000000E+00 Chg. balance for solid moles: -.9063E-18 Mass of aqueous solution: 0.121518E+04 g Temperature = 574.00 C Pressure = 1302.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.1524E-03 -3.817 0.2074E-01 -1.683 0.3917 0.7000E-02 annite 0.8993E-06 -6.046 0.4604E-03 -3.337 0.8694E-02 0.1388E-03 phlogopite 0.1822E-05 -5.739 0.7603E-03 -3.119 0.1436E-01 0.2726E-03 biotite-Mn 0.4129E-07 -7.384 0.2102E-04 -4.677 0.3970E-03 0.6302E-05 apatite-OH 0.1891E-05 -5.723 0.9501E-03 -3.022 0.1794E-01 0.3019E-03 magnetite 0.3060E-03 -3.514 0.7085E-01 -1.150 1.338 0.1362E-01 pyrite 0.2530E-02 -2.597 0.3035 -0.518 5.732 0.6056E-01 quartz 0.7649E-01 -1.116 4.595 0.662 86.78 1.735 barite 0.3870E-04 -4.412 0.9033E-02 -2.044 0.1706 0.2016E-02 chalcopyrite 0.2786E-03 -3.555 0.5112E-01 -1.291 0.9654 0.1193E-01 sphalerite 0.1010E-02 -2.996 0.9842E-01 -1.007 1.859 0.2407E-01 an25ab75 0.5410E-03 -3.267 0.1440 -0.842 2.720 0.5423E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3255E+00 0.3255E+00 1.0000 -0.487 phlogopite 0.6595E+00 0.6595E+00 1.0000 -0.181 biotite-Mn 0.1495E-01 0.1495E-01 1.0000 -1.825 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an25ab75 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.295276 g Volume = 1.909564 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.47 -14.47 0.00 0.000 -0.68859E-11 24 annite -0.02 -0.02 0.00 0.000 -0.78004E-12 25 phlogopite 4.56 4.56 0.00 0.000 0.20658E-10 26 biotite-Mn 9.11 9.11 0.00 0.000 -0.68859E-11 30 apatite-OH -52.74 -52.74 0.00 0.000 0.27544E-10 106 magnetite 1.67 1.67 0.00 0.000 0.17215E-11 140 pyrite -21.43 -21.43 0.00 0.000 0.00000E+00 144 quartz -1.18 -1.18 0.00 0.000 0.00000E+00 237 barite -15.58 -15.58 0.00 0.000 0.00000E+00 240 chalcopyrite -23.05 -23.05 0.00 0.000 0.00000E+00 255 sphalerite -10.82 -10.82 0.00 0.000 0.00000E+00 259 an25ab75 -5.78 -5.78 0.00 0.000 0.10329E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.28 0.00 -0.28 -0.277 0.10742E+04 2.838 2 CO2,gas -9.70 -11.29 -1.60 -0.533 0.61960E+04 1.516 3 CH4,gas 6.90 -3.93 -10.83 -2.707 0.41980E+05 -7.715 4 H2,gas 5.89 1.84 -4.05 -2.316 0.15713E+05 -0.939 5 H2S,gas -8.08 -10.38 -2.30 -1.150 0.89175E+04 0.814 6 CO,gas -3.59 -9.45 -5.87 -1.805 0.22740E+05 -2.752 7 SO3,gas -7.25 -17.74 -10.50 -2.624 0.40690E+05 -7.382 8 O2,gas 16.65 -3.68 -20.33 -13.556 0.78821E+05 -17.219 9 HCl,gas -5.96 -7.30 -1.34 -0.670 0.51979E+04 -1.341 10 acmite 3.66 2.15 -1.51 -0.157 0.58451E+04 12 akimotoite 6.00 1.82 -4.18 -0.835 0.16192E+05 13 akimotoite-Fe 3.92 -0.01 -3.93 -0.785 0.15217E+05 14 albite-high -4.40 -4.51 -0.11 -0.008 0.42402E+03 15 albite -4.39 -4.51 -0.13 -0.010 0.48752E+03 16 almandine -8.97 -10.50 -1.53 -0.077 0.59467E+04 17 pyrope -2.37 -5.00 -2.63 -0.131 0.10188E+05 18 analcite -2.39 -3.34 -0.94 -0.105 0.36625E+04 19 andalusite -11.24 -11.65 -0.41 -0.041 0.16036E+04 20 andradite 11.39 6.78 -4.61 -0.239 0.17868E+05 21 grossular 0.68 -4.20 -4.87 -0.244 0.18887E+05 27 anorthite -8.96 -9.56 -0.60 -0.046 0.23254E+04 28 anthophyllite 13.93 11.60 -2.33 -0.063 0.90403E+04 29 anthophyllite-Fe 1.39 -1.23 -2.62 -0.071 0.10161E+05 31 apatite-OH-zs -50.59 -52.74 -2.15 -0.165 0.83188E+04 32 apatite-Cl-zs -56.87 -60.04 -3.18 -0.265 0.12312E+05 33 aragonite -4.49 -8.02 -3.53 -1.177 0.13690E+05 34 brucite 5.26 3.00 -2.26 -0.453 0.87706E+04 35 calcite -4.59 -8.02 -3.43 -1.143 0.13298E+05 36 carnegieite-low -0.41 -2.16 -1.75 -0.250 0.67807E+04 37 carnegieite-high -0.34 -2.16 -1.82 -0.261 0.70689E+04 38 carpholite-Mg -7.88 -9.83 -1.95 -0.130 0.75519E+04 39 carpholite-Fe -9.23 -11.67 -2.43 -0.162 0.94368E+04 40 celadonite -1.06 -3.17 -2.11 -0.124 0.81603E+04 41 celadonite-Fe -2.46 -5.00 -2.54 -0.149 0.98443E+04 42 chrysotile 9.12 6.65 -2.47 -0.206 0.95778E+04 44 clinochlore 2.45 0.99 -1.46 -0.046 0.56542E+04 45 daphnite -4.56 -8.17 -3.60 -0.113 0.13971E+05 48 chloritoid-Mg -7.39 -8.65 -1.26 -0.084 0.49001E+04 49 chloritoid-Fe -9.31 -10.49 -1.17 -0.078 0.45519E+04 50 chloritoid-Mn -7.16 -8.78 -1.63 -0.108 0.62997E+04 52 coesite -0.89 -1.18 -0.29 -0.095 0.11056E+04 53 cordierite-H -20.12 -20.84 -0.72 -0.026 0.27924E+04 54 cordierite-Fe -22.66 -24.50 -1.84 -0.064 0.71514E+04 55 cordierite-Mn -18.27 -21.09 -2.82 -0.097 0.10934E+05 56 corundum -9.89 -10.48 -0.59 -0.053 0.22707E+04 58 cristobalite -1.13 -1.18 -0.05 -0.016 0.18338E+03 59 cummingtonite 13.99 11.60 -2.40 -0.065 0.92879E+04 61 cymrite-K -2.72 -4.99 -2.27 -0.189 0.88008E+04 63 diaspore -4.44 -5.24 -0.80 -0.133 0.30888E+04 65 diopside 5.26 3.92 -1.34 -0.134 0.52090E+04 66 hedenbergite 3.85 2.09 -1.76 -0.176 0.68366E+04 68 eastonite -7.02 -8.29 -1.27 -0.049 0.49191E+04 69 enstatite 4.54 3.65 -0.90 -0.090 0.34694E+04 70 clinoenstatite-HiP 5.04 3.65 -1.39 -0.139 0.53714E+04 71 clinoenstatite 4.53 3.65 -0.88 -0.088 0.34128E+04 72 protoenstatite 4.68 3.65 -1.03 -0.103 0.39794E+04 73 epidote -5.15 -7.22 -2.07 -0.100 0.80232E+04 74 clinozoisite -10.23 -12.71 -2.48 -0.113 0.96057E+04 75 epidote-Fe 1.61 -1.73 -3.34 -0.173 0.12944E+05 76 fayalite 2.08 1.16 -0.92 -0.131 0.35581E+04 77 ferrosilite 1.00 -0.02 -1.01 -0.101 0.39222E+04 78 forsterite 6.04 4.83 -1.22 -0.174 0.47103E+04 79 gedrite -10.99 -13.01 -2.02 -0.055 0.78381E+04 81 gibbsite -2.83 -5.24 -2.41 -0.345 0.93567E+04 82 glaucophane 0.72 -2.38 -3.10 -0.084 0.12013E+05 83 glaucophane-Fe -3.30 -7.88 -4.58 -0.124 0.17745E+05 84 goethite 1.06 0.25 -0.81 -0.175 0.31365E+04 86 greenalite 4.29 1.15 -3.14 -0.262 0.12165E+05 87 grunerite 1.94 -1.23 -3.17 -0.086 0.12279E+05 88 halite -0.99 -3.05 -2.05 -1.026 0.79572E+04 89 hematite 0.58 0.50 -0.08 -0.010 0.31681E+03 90 heulandite -12.51 -15.45 -2.94 -0.134 0.11404E+05 91 hercynite -8.29 -9.31 -1.02 -0.068 0.39514E+04 94 jadeite -1.71 -3.34 -1.63 -0.163 0.63032E+04 96 kalsilite -1.03 -2.64 -1.60 -0.229 0.62084E+04 97 kaolinite -10.17 -12.83 -2.67 -0.242 0.10331E+05 98 kyanite -11.08 -11.65 -0.57 -0.057 0.22195E+04 100 laumontite -8.45 -11.92 -3.47 -0.231 0.13443E+05 101 lawsonite -6.20 -9.56 -3.36 -0.224 0.13037E+05 102 leucite -2.87 -3.81 -0.94 -0.094 0.36589E+04 104 lizardite 9.30 6.65 -2.65 -0.221 0.10276E+05 105 magnesite -5.41 -8.29 -2.88 -0.960 0.11166E+05 107 minnesotaite 0.68 -1.20 -1.88 -0.111 0.72923E+04 108 minnesotaite-Mg 6.60 4.30 -2.31 -0.136 0.89382E+04 109 magnesioferrite 4.71 3.50 -1.21 -0.099 0.46992E+04 111 manganosite 5.25 2.87 -2.38 -0.594 0.92160E+04 112 margarite -18.38 -20.04 -1.66 -0.066 0.64390E+04 115 microcline -4.99 -4.99 0.00 0.000 0.52222E+01 116 monticellite 8.58 5.10 -3.49 -0.498 0.13523E+05 118 mullite-Si -10.50 -11.65 -1.15 -0.115 0.44613E+04 119 muscovite -14.74 -15.47 -0.72 -0.043 0.28074E+04 120 paragonite -14.06 -14.99 -0.93 -0.055 0.35991E+04 121 nepheline -0.71 -2.16 -1.46 -0.208 0.56405E+04 122 osumilite(2) -13.95 -15.87 -1.93 -0.040 0.74623E+04 123 osumilite-Fe -29.63 -31.84 -2.22 -0.046 0.85918E+04 124 pargasite 3.88 0.02 -3.86 -0.102 0.14955E+05 125 periclase 5.45 3.00 -2.45 -0.612 0.94852E+04 126 periclase-Fe 2.89 1.17 -1.72 -0.430 0.66718E+04 127 perovskite-Al -8.17 -10.48 -2.30 -0.209 0.89292E+04 132 phlogopite-Na 5.42 4.49 -0.93 -0.052 0.36135E+04 134 prehnite -4.30 -7.47 -3.17 -0.186 0.12272E+05 135 prehnite-Fe 1.17 -1.98 -3.15 -0.189 0.12206E+05 138 px-Mg-tschermaks -6.81 -8.65 -1.84 -0.132 0.71382E+04 139 px-Ca-tschermaks -5.91 -8.38 -2.47 -0.177 0.95914E+04 141 pyrrhotite -8.59 -9.21 -0.62 -0.207 0.24034E+04 142 pyrrhotiteFe0.875 -9.34 -9.58 -0.25 -0.091 0.95445E+03 143 pyrophyllite -13.90 -15.19 -1.29 -0.080 0.49923E+04 146 riebeckite 5.76 3.10 -2.66 -0.073 0.10319E+05 147 ringwoodite-Fe 3.07 1.16 -1.91 -0.273 0.74012E+04 148 ringwoodite-Mg 9.17 4.83 -4.35 -0.621 0.16843E+05 149 rhodochrosite -5.34 -8.42 -3.08 -1.026 0.11929E+05 150 rhodonite 2.46 1.70 -0.76 -0.153 0.29647E+04 151 sanidine -4.45 -4.99 -0.53 -0.041 0.20738E+04 153 siderite -7.23 -10.12 -2.89 -0.965 0.11219E+05 154 sillimanite -11.21 -11.65 -0.45 -0.045 0.17337E+04 156 spinel -6.14 -7.48 -1.34 -0.089 0.51983E+04 162 stilpnomelane-Fe -7.59 -12.17 -4.58 -0.137 0.17749E+05 163 stilpnomelane-Mg -0.86 -3.00 -2.15 -0.064 0.83149E+04 164 stishovite 1.75 -1.18 -2.93 -0.977 0.11357E+05 165 sudoite-Fe -18.19 -22.15 -3.96 -0.128 0.15360E+05 166 sudoite -15.99 -18.49 -2.50 -0.081 0.96956E+04 167 sulfur -10.72 -12.22 -1.50 -0.461 0.58055E+04 168 sylvite -0.90 -3.52 -2.62 -1.311 0.10166E+05 169 talc 4.89 4.30 -0.59 -0.035 0.22832E+04 170 talc-Fe 2.07 -1.20 -3.27 -0.192 0.12669E+05 171 talc-tschermaks -6.40 -8.01 -1.61 -0.095 0.62444E+04 173 tephroite 6.37 4.57 -1.80 -0.257 0.69811E+04 176 topaz-H -9.15 -11.66 -2.50 -0.228 0.97046E+04 177 tremolite 14.77 12.13 -2.64 -0.071 0.10229E+05 179 troilite-low -8.49 -9.21 -0.71 -0.238 0.27680E+04 180 tschermakite -9.37 -12.47 -3.10 -0.084 0.12026E+05 183 wadsleyite-Fe 2.92 1.16 -1.76 -0.251 0.68193E+04 184 wadsleyite-Mg 8.23 4.83 -3.41 -0.487 0.13213E+05 185 wairakite -10.30 -11.92 -1.62 -0.095 0.62779E+04 186 walstromite 4.56 2.09 -2.47 -0.494 0.95672E+04 187 wollastonite 4.15 2.09 -2.05 -0.411 0.79589E+04 188 pseudo-wollastonite 4.26 2.09 -2.17 -0.433 0.84015E+04 189 zoisite -10.28 -12.71 -2.42 -0.110 0.93907E+04 192 beidellite-Ca -14.38 -15.99 -1.61 -0.099 0.62258E+04 193 beidellite-H -14.39 -16.53 -2.13 -0.136 0.82706E+04 194 beidellite-K -13.34 -15.28 -1.94 -0.119 0.75143E+04 195 beidellite-Mg -14.66 -16.03 -1.37 -0.085 0.53285E+04 196 beidellite-Na -13.28 -15.12 -1.84 -0.113 0.71356E+04 197 bornite -53.53 -53.99 -0.46 -0.034 0.17789E+04 199 chalcocite -13.94 -15.47 -1.53 -0.383 0.59454E+04 200 covellite -12.43 -13.84 -1.42 -0.540 0.54956E+04 202 montmorillonite-Ca -10.71 -11.93 -1.22 -0.075 0.47162E+04 203 montmorillonite-K -9.96 -11.22 -1.26 -0.077 0.48927E+04 204 montmorillonite-Mg -10.94 -11.97 -1.03 -0.064 0.40047E+04 205 montmorillonite-Na -9.61 -11.06 -1.45 -0.089 0.56306E+04 206 nontronite-Ca -3.66 -5.01 -1.35 -0.088 0.52364E+04 207 nontronite-H -3.68 -5.55 -1.87 -0.125 0.72534E+04 208 nontronite-K -2.62 -4.30 -1.68 -0.108 0.65161E+04 209 nontronite-Mg -3.90 -5.06 -1.16 -0.075 0.44990E+04 210 nontronite-Na -2.56 -4.15 -1.59 -0.102 0.61505E+04 215 gypsum -12.26 -14.48 -2.22 -0.554 0.85929E+04 232 alabandite -6.31 -7.50 -1.19 -0.397 0.46191E+04 234 anglesite -14.69 -17.14 -2.46 -1.229 0.95268E+04 238 boehmite -4.16 -5.24 -1.08 -0.180 0.41947E+04 242 copper,native 1.75 -1.63 -3.38 -1.175 0.13095E+05 244 ferrous-oxide 1.97 1.17 -0.80 -0.200 0.31045E+04 245 galena -9.62 -9.78 -0.16 -0.054 0.63072E+03 246 silver,native 0.50 -3.45 -3.95 -1.374 0.15311E+05 248 litharge 5.25 0.60 -4.65 -1.163 0.18028E+05 256 wurtzite -10.02 -10.82 -0.80 -0.266 0.30891E+04 257 zincite 2.08 -0.44 -2.52 -0.629 0.97580E+04 258 an20ab80 -5.52 -5.52 0.00 0.000 0.12822E+02 260 an30ab70 -6.03 -6.03 0.00 0.000 0.11353E+02 261 tr.625ac.25prg.125 9.24 8.33 -0.91 -0.025 0.35421E+04 Calculations done for 574.0000 Deg. C; 1302.0000 bar Temperature changed by -1.000 degrees to 573.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 32 Loop limit = 500 Temperature = 573.00 C Pressure = 1280.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5510E+02 kg liquid = 0.9926E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9964 Stoichiometric ionic strength = .3286721E+01 Osmotic coef. = 0.0000 True ionic strength = .1826582E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.66147E-05 -5.1795 0.15009E-05 -5.8236 0.22691E+00 -0.6442 2 H2O 0.99639E+00 -0.0016 0.99639E+00 -0.0016 3 Cl- 0.15373E+00 -0.8132 0.30295E-01 -1.5186 0.19707E+00 -0.7054 4 SO4-- 0.20777E-03 -3.6824 0.69557E-06 -6.1577 0.33478E-02 -2.4752 5 HCO3- 0.14208E-04 -4.8475 0.30199E-05 -5.5200 0.21255E+00 -0.6725 6 HS- 0.12947E-03 -3.8878 0.25730E-04 -4.5896 0.19874E+00 -0.7017 7 H4SiO4 0.64403E-01 -1.1911 0.64403E-01 -1.1911 0.10000E+01 0.0000 8 Al+++ 0.10456E-16 -16.9806 0.22114E-22 -22.6553 0.21150E-05 -5.6747 9 Ca++ 0.16167E-05 -5.7914 0.43436E-08 -8.3622 0.26866E-02 -2.5708 10 Mg++ 0.10860E-05 -5.9642 0.23920E-08 -8.6212 0.22026E-02 -2.6571 11 Fe++ 0.15096E-07 -7.8211 0.34972E-10 -10.4563 0.23166E-02 -2.6352 12 K+ 0.42535E-01 -1.3713 0.92717E-02 -2.0328 0.21798E+00 -0.6616 13 Na+ 0.13829E+00 -0.8592 0.27590E-01 -1.5593 0.19951E+00 -0.7000 14 Mn++ 0.78345E-06 -6.1060 0.18830E-08 -8.7252 0.24035E-02 -2.6192 15 Zn++ 0.37110E-09 -9.4305 0.85969E-12 -12.0657 0.23166E-02 -2.6352 16 Cu+ 0.21223E-07 -7.6732 0.42227E-08 -8.3744 0.19897E+00 -0.7012 17 Pb++ 0.31136E-08 -8.5067 0.93844E-11 -11.0276 0.30140E-02 -2.5209 18 Ag+ 0.31219E-09 -9.5056 0.66973E-10 -10.1741 0.21452E+00 -0.6685 19 Ba++ 0.10165E-06 -6.9929 0.32942E-09 -9.4822 0.32408E-02 -2.4893 20 HPO4-- 0.10666E-08 -8.9720 0.35889E-11 -11.4450 0.33649E-02 -2.4730 21 HSiO3- 0.16767E-05 -5.7756 0.33042E-06 -6.4809 0.19707E+00 -0.7054 22 Ca(HSiO3)+ 0.71628E-08 -8.1449 0.15753E-08 -8.8026 0.21993E+00 -0.6577 23 Mg(HSiO3)+ 0.11474E-08 -8.9403 0.25235E-09 -9.5980 0.21993E+00 -0.6577 24 NaHSiO3,aq 0.17207E-05 -5.7643 0.17207E-05 -5.7643 0.10000E+01 0.0000 28 AgCl,aq 0.90289E-07 -7.0444 0.90289E-07 -7.0444 0.10000E+01 0.0000 29 AgCl2- 0.50488E-05 -5.2968 0.99496E-06 -6.0022 0.19707E+00 -0.7054 30 AgCl3-2 0.20366E-05 -5.6911 0.63056E-08 -8.2003 0.30961E-02 -2.5092 31 AgCl4-3 0.15828E-05 -5.8006 0.28967E-11 -11.5381 0.18301E-05 -5.7375 34 Ag(HS),aq 0.11407E-08 -8.9428 0.11407E-08 -8.9428 0.10000E+01 0.0000 35 Ag(HS)2- 0.53801E-08 -8.2692 0.10603E-08 -8.9746 0.19707E+00 -0.7054 38 HAlO2,aq 0.43501E-08 -8.3615 0.43501E-08 -8.3615 0.10000E+01 0.0000 39 AlO2- 0.15369E-04 -4.8134 0.26468E-05 -5.5773 0.17222E+00 -0.7639 41 Ba(HCO3)+ 0.40949E-06 -6.3878 0.93758E-07 -7.0280 0.22897E+00 -0.6402 42 BaCl+ 0.15135E-04 -4.8200 0.33287E-05 -5.4777 0.21993E+00 -0.6577 43 CH4,aq 0.17208E-08 -8.7643 0.20625E-08 -8.6856 0.11986E+01 0.0787 48 CO,aq 0.63293E-03 -3.1986 0.63293E-03 -3.1986 0.10000E+01 0.0000 49 CO2,aq 0.26751E+01 0.4273 0.32064E+01 0.5060 0.11986E+01 0.0787 50 CO3-2 0.42727E-10 -10.3693 0.13229E-12 -12.8785 0.30961E-02 -2.5092 51 CaCO3,aq 0.12692E-10 -10.8965 0.12692E-10 -10.8965 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.21160E-06 -6.6745 0.46536E-07 -7.3322 0.21993E+00 -0.6577 53 CaCl+ 0.11895E-03 -3.9246 0.26161E-04 -4.5824 0.21993E+00 -0.6577 54 CaCl2,aq 0.10069E-03 -3.9970 0.10069E-03 -3.9970 0.10000E+01 0.0000 55 CaOH+ 0.21628E-06 -6.6650 0.47566E-07 -7.3227 0.21993E+00 -0.6577 56 CaSO4,aq 0.14939E-06 -6.8257 0.14939E-06 -6.8257 0.10000E+01 0.0000 57 HCl,aq 0.20630E-02 -2.6855 0.20630E-02 -2.6855 0.10000E+01 0.0000 66 CuCl,aq 0.24738E-04 -4.6066 0.24738E-04 -4.6066 0.10000E+01 0.0000 67 CuCl2- 0.91325E-04 -4.0394 0.17997E-04 -4.7448 0.19707E+00 -0.7054 68 CuCl3-2 0.19737E-05 -5.7047 0.61108E-08 -8.2139 0.30961E-02 -2.5092 74 FeCl+ 0.34386E-06 -6.4636 0.75625E-07 -7.1213 0.21993E+00 -0.6577 75 FeCl2,aq 0.48395E-02 -2.3152 0.48395E-02 -2.3152 0.10000E+01 0.0000 77 FeO,aq 0.74523E-07 -7.1277 0.74523E-07 -7.1277 0.10000E+01 0.0000 78 FeOH+ 0.28251E-07 -7.5490 0.62133E-08 -8.2067 0.21993E+00 -0.6577 79 HFeO2- 0.93104E-08 -8.0310 0.18348E-08 -8.7364 0.19707E+00 -0.7054 82 FeO2- 0.59492E-08 -8.2255 0.11724E-08 -8.9309 0.19707E+00 -0.7054 83 HFeO2,aq 0.28746E-09 -9.5414 0.28746E-09 -9.5414 0.10000E+01 0.0000 84 H2,aq 0.46858E-02 -2.3292 0.56164E-02 -2.2505 0.11986E+01 0.0787 85 KCl,aq 0.66211E-01 -1.1791 0.66211E-01 -1.1791 0.10000E+01 0.0000 86 KHSO4,aq 0.13231E-01 -1.8784 0.13231E-01 -1.8784 0.10000E+01 0.0000 87 KOH,aq 0.12271E-05 -5.9111 0.12271E-05 -5.9111 0.10000E+01 0.0000 88 KSO4- 0.43581E-02 -2.3607 0.85886E-03 -3.0661 0.19707E+00 -0.7054 90 Mg(HCO3)+ 0.43303E-07 -7.3635 0.95237E-08 -8.0212 0.21993E+00 -0.6577 91 MgCl+ 0.13235E-04 -4.8783 0.29108E-05 -5.5360 0.21993E+00 -0.6577 92 MgOH+ 0.50029E-06 -6.3008 0.11003E-06 -6.9585 0.21993E+00 -0.6577 94 MnO,aq 0.64478E-07 -7.1906 0.64478E-07 -7.1906 0.10000E+01 0.0000 95 MnOH+ 0.17750E-06 -6.7508 0.39038E-07 -7.4085 0.21993E+00 -0.6577 97 HMnO2- 0.34526E-10 -10.4619 0.68040E-11 -11.1672 0.19707E+00 -0.7054 100 MnCl+ 0.11568E-02 -2.9368 0.25441E-03 -3.5945 0.21993E+00 -0.6577 101 MnSO4,aq 0.75819E-07 -7.1202 0.75819E-07 -7.1202 0.10000E+01 0.0000 102 NaCl,aq 0.42001E+00 -0.3767 0.42001E+00 -0.3767 0.10000E+01 0.0000 103 NaOH,aq 0.16848E-05 -5.7735 0.16848E-05 -5.7735 0.10000E+01 0.0000 105 OH- 0.82626E-05 -5.0829 0.14230E-05 -5.8468 0.17222E+00 -0.7639 110 HPO3-2 0.11457E-10 -10.9409 0.35471E-13 -13.4501 0.30961E-02 -2.5092 111 H3PO3,aq 0.10624E-09 -9.9737 0.10624E-09 -9.9737 0.10000E+01 0.0000 112 H2PO3- 0.26901E-08 -8.5702 0.53014E-09 -9.2756 0.19707E+00 -0.7054 113 H3PO4,aq 0.98228E-06 -6.0078 0.98228E-06 -6.0078 0.10000E+01 0.0000 114 H2PO4- 0.14149E-05 -5.8493 0.29341E-06 -6.5325 0.20737E+00 -0.6833 116 H4P2O7,aq 0.86701E-10 -10.0620 0.86701E-10 -10.0620 0.10000E+01 0.0000 117 H3P2O7- 0.84064E-09 -9.0754 0.16566E-09 -9.7808 0.19707E+00 -0.7054 118 H2P2O7-2 0.22875E-06 -6.6406 0.70825E-09 -9.1498 0.30961E-02 -2.5092 119 HP2O7-3 0.16418E-07 -7.7847 0.30048E-13 -13.5222 0.18301E-05 -5.7375 121 PbCl+ 0.16144E-05 -5.7920 0.35505E-06 -6.4497 0.21993E+00 -0.6577 122 PbCl2,aq 0.86349E-04 -4.0637 0.86349E-04 -4.0637 0.10000E+01 0.0000 123 PbCl3- 0.10594E-03 -3.9749 0.20878E-04 -4.6803 0.19707E+00 -0.7054 124 PbCl4-2 0.21962E-04 -4.6583 0.67997E-07 -7.1675 0.30961E-02 -2.5092 125 PbO,aq 0.54542E-08 -8.2633 0.54542E-08 -8.2633 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11445E-03 -3.9414 0.11445E-03 -3.9414 0.10000E+01 0.0000 128 Pb(HS)3- 0.12368E-04 -4.9077 0.24373E-05 -5.6131 0.19707E+00 -0.7054 129 H2S,aq 0.10538E+01 0.0228 0.12631E+01 0.1014 0.11986E+01 0.0787 130 S2-2 0.13870E-07 -7.8579 0.42944E-10 -10.3671 0.30961E-02 -2.5092 131 S3-2 0.13285E-08 -8.8766 0.41132E-11 -11.3858 0.30961E-02 -2.5092 132 S3- 0.13688E-01 -1.8637 0.26974E-02 -2.5691 0.19707E+00 -0.7054 133 S4-2 0.10735E-09 -9.9692 0.33235E-12 -12.4784 0.30961E-02 -2.5092 135 SO2,aq 0.29038E+00 -0.5370 0.29038E+00 -0.5370 0.10000E+01 0.0000 136 SO3-2 0.61713E-09 -9.2096 0.30406E-11 -11.5170 0.49270E-02 -2.3074 137 HSO3- 0.31267E-03 -3.5049 0.61618E-04 -4.2103 0.19707E+00 -0.7054 138 HSO4- 0.93828E-02 -2.0277 0.21197E-02 -2.6737 0.22591E+00 -0.6461 140 S2O3-2 0.51246E-06 -6.2903 0.15866E-08 -8.7995 0.30961E-02 -2.5092 141 HS2O3- 0.46863E-06 -6.3292 0.92352E-07 -7.0346 0.19707E+00 -0.7054 142 H2S2O3,aq 0.27864E-07 -7.5550 0.27864E-07 -7.5550 0.10000E+01 0.0000 150 S4O6-2 0.49958E-09 -9.3014 0.15468E-11 -11.8106 0.30961E-02 -2.5092 152 ZnCl+ 0.27240E-03 -3.5648 0.59910E-04 -4.2225 0.21993E+00 -0.6577 153 ZnCl2,aq 0.87471E-03 -3.0581 0.87471E-03 -3.0581 0.10000E+01 0.0000 154 ZnCl3- 0.83771E-04 -4.0769 0.16509E-04 -4.7823 0.19707E+00 -0.7054 155 ZnO,aq 0.34102E-07 -7.4672 0.34102E-07 -7.4672 0.10000E+01 0.0000 156 ZnOH+ 0.16649E-05 -5.7786 0.36617E-06 -6.4363 0.21993E+00 -0.6577 158 HZnO2- 0.27581E-09 -9.5594 0.54353E-10 -10.2648 0.19707E+00 -0.7054 Charge balance for all species = 0.2550E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6614702E-05 0.4297172E+01 0.3538624E+04 0.0000 2 H2O 0.1000000E+01 0.5251260E+02 0.7728977E+06 0.0000 3 Cl- 0.1537297E+00 0.6562862E+00 0.1900917E+05 4.3050 4 SO4-- 0.2077682E-03 0.2524267E+00 0.1981080E+05 5.4896 5 HCO3- 0.1420781E-04 0.2675788E+01 0.1333893E+06 0.3036 6 HS- 0.1294687E-03 0.1160695E+01 0.3136141E+05 1.2341 7 H4SiO4 0.6440260E-01 0.6440601E-01 0.5057505E+04 -1.1911 8 Al+++ 0.1045567E-16 0.1537322E-04 0.3388814E+00 -5.1844 9 Ca++ 0.1616743E-05 0.2218423E-03 0.7263858E+01 3.2851 10 Mg++ 0.1085978E-05 0.1486582E-04 0.2952749E+00 3.0260 11 Fe++ 0.1509650E-07 0.4839990E-02 0.2208316E+03 1.1910 12 K+ 0.4253461E-01 0.1263361E+00 0.4035926E+04 3.7908 13 Na+ 0.1382864E+00 0.5582987E+00 0.1048621E+05 4.2644 14 Mn++ 0.7834479E-06 0.1157871E-02 0.5196966E+02 2.9221 15 Zn++ 0.3711022E-09 0.1232586E-02 0.6582830E+02 -0.4184 16 Cu+ 0.2122256E-07 0.1180578E-03 0.6128567E+01 -2.5508 17 Pb++ 0.3113614E-08 0.3426924E-03 0.5800831E+02 0.6197 18 Ag+ 0.3121941E-09 0.8765292E-05 0.7724742E+00 -4.3505 19 Ba++ 0.1016485E-06 0.1564643E-04 0.1755615E+01 2.1650 20 HPO4-- 0.1066559E-08 0.2893297E-05 0.2268747E+00 0.2022 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265576E+01 -.3213620E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5212649E+02 -.1617075E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2505706E+00 0.1152171E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1152161E+01 0.7983205E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.6393244E-01 0.7966188E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1526018E-04 0.6792793E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2202111E-03 0.3076988E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1475652E-04 0.5920134E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.4804402E-02 0.3962352E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1254071E+00 0.2999233E-05 0.0000000E+00 13 Na+ 0.5545993E+00 0.5541936E+00 0.4057681E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149357E-02 0.1429883E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1223523E-02 0.1075812E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1171898E-03 0.2824200E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1553138E-04 0.3984107E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2872023E-05 0.5695478E-05 0.0000000E+00 Chg. balance for solid moles: 0.1121E-17 Mass of aqueous solution: 0.121500E+04 g Temperature = 573.00 C Pressure = 1280.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.1630E-03 -3.788 0.2218E-01 -1.654 0.4055 0.7487E-02 annite 0.9782E-06 -6.010 0.5007E-03 -3.300 0.9153E-02 0.1510E-03 phlogopite 0.1973E-05 -5.705 0.8235E-03 -3.084 0.1505E-01 0.2953E-03 biotite-Mn 0.4766E-07 -7.322 0.2427E-04 -4.615 0.4436E-03 0.7275E-05 apatite-OH 0.1898E-05 -5.722 0.9537E-03 -3.021 0.1743E-01 0.3030E-03 magnetite 0.1034E-04 -4.985 0.2395E-02 -2.621 0.4377E-01 0.4605E-03 pyrite 0.3646E-02 -2.438 0.4374 -0.359 7.996 0.8728E-01 quartz 0.7817E-01 -1.107 4.696 0.672 85.85 1.773 barite 0.3984E-04 -4.400 0.9299E-02 -2.032 0.1700 0.2076E-02 chalcopyrite 0.2824E-03 -3.549 0.5182E-01 -1.285 0.9473 0.1210E-01 sphalerite 0.1076E-02 -2.968 0.1048 -0.980 1.916 0.2563E-01 an25ab75 0.5410E-03 -3.267 0.1440 -0.842 2.633 0.5423E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3261E+00 0.3261E+00 1.0000 -0.487 phlogopite 0.6580E+00 0.6580E+00 1.0000 -0.182 biotite-Mn 0.1589E-01 0.1589E-01 1.0000 -1.799 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an25ab75 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.470451 g Volume = 1.963492 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.52 -14.52 0.00 0.000 0.00000E+00 24 annite 0.07 0.07 0.00 0.000 0.18591E-10 25 phlogopite 4.66 4.66 0.00 0.000 0.00000E+00 26 biotite-Mn 9.20 9.20 0.00 0.000 0.20633E-10 30 apatite-OH -52.85 -52.85 0.00 0.000 -0.27511E-10 106 magnetite 1.72 1.72 0.00 0.000 0.29231E-10 140 pyrite -21.48 -21.48 0.00 0.000 -0.13756E-10 144 quartz -1.19 -1.19 0.00 0.000 0.85972E-12 237 barite -15.64 -15.64 0.00 0.000 0.68778E-11 240 chalcopyrite -23.11 -23.11 0.00 0.000 0.00000E+00 255 sphalerite -10.83 -10.83 0.00 0.000 0.00000E+00 259 an25ab75 -5.73 -5.73 0.00 0.000 0.68778E-11 115 microcline -4.97 -4.96 0.01 0.000 -0.20572E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.28 -0.276 0.10688E+04 2.831 2 CO2,gas -9.73 -11.34 -1.61 -0.536 0.62300E+04 1.498 3 CH4,gas 6.89 -3.95 -10.85 -2.712 0.41999E+05 -7.740 4 H2,gas 5.90 1.85 -4.05 -2.317 0.15698E+05 -0.947 5 H2S,gas -8.11 -10.41 -2.30 -1.152 0.89191E+04 0.804 6 CO,gas -3.61 -9.49 -5.88 -1.810 0.22773E+05 -2.774 7 SO3,gas -7.29 -17.80 -10.51 -2.628 0.40702E+05 -7.405 8 O2,gas 16.66 -3.70 -20.36 -13.572 0.78823E+05 -17.251 9 HCl,gas -5.98 -7.34 -1.36 -0.679 0.52615E+04 -1.359 10 acmite 3.65 2.15 -1.50 -0.156 0.58071E+04 12 akimotoite 6.02 1.84 -4.19 -0.837 0.16205E+05 13 akimotoite-Fe 3.93 0.00 -3.93 -0.786 0.15222E+05 14 albite-high -4.38 -4.49 -0.11 -0.008 0.41010E+03 15 albite -4.37 -4.49 -0.12 -0.009 0.46983E+03 16 almandine -8.82 -10.37 -1.55 -0.078 0.60121E+04 17 pyrope -2.21 -4.86 -2.66 -0.133 0.10281E+05 18 analcite -2.36 -3.30 -0.94 -0.105 0.36494E+04 19 andalusite -11.14 -11.56 -0.43 -0.043 0.16496E+04 20 andradite 11.43 6.82 -4.62 -0.240 0.17877E+05 21 grossular 0.81 -4.09 -4.89 -0.245 0.18942E+05 27 anorthite -8.85 -9.47 -0.61 -0.047 0.23745E+04 28 anthophyllite 14.02 11.67 -2.36 -0.064 0.91223E+04 29 anthophyllite-Fe 1.45 -1.18 -2.63 -0.071 0.10176E+05 31 apatite-OH-zs -50.70 -52.85 -2.15 -0.165 0.83211E+04 32 apatite-Cl-zs -57.01 -60.19 -3.19 -0.265 0.12336E+05 33 aragonite -4.51 -8.06 -3.54 -1.181 0.13724E+05 34 brucite 5.29 3.02 -2.27 -0.454 0.87807E+04 35 calcite -4.62 -8.06 -3.44 -1.148 0.13330E+05 36 carnegieite-low -0.36 -2.11 -1.75 -0.250 0.67630E+04 37 carnegieite-high -0.29 -2.11 -1.82 -0.260 0.70532E+04 38 carpholite-Mg -7.76 -9.73 -1.96 -0.131 0.76046E+04 39 carpholite-Fe -9.11 -11.56 -2.45 -0.163 0.94816E+04 40 celadonite -1.02 -3.13 -2.10 -0.124 0.81482E+04 41 celadonite-Fe -2.42 -4.96 -2.54 -0.149 0.98259E+04 42 chrysotile 9.17 6.69 -2.48 -0.207 0.96044E+04 44 clinochlore 2.66 1.18 -1.48 -0.046 0.57384E+04 45 daphnite -4.38 -8.00 -3.62 -0.113 0.14016E+05 48 chloritoid-Mg -7.26 -8.54 -1.28 -0.085 0.49542E+04 49 chloritoid-Fe -9.19 -10.37 -1.19 -0.079 0.45947E+04 50 chloritoid-Mn -7.03 -8.64 -1.61 -0.107 0.62360E+04 52 coesite -0.90 -1.19 -0.29 -0.095 0.11065E+04 53 cordierite-H -19.89 -20.64 -0.75 -0.027 0.29096E+04 54 cordierite-Fe -22.44 -24.31 -1.87 -0.064 0.72371E+04 55 cordierite-Mn -18.06 -20.85 -2.79 -0.096 0.10805E+05 56 corundum -9.77 -10.37 -0.60 -0.054 0.23179E+04 58 cristobalite -1.14 -1.19 -0.05 -0.016 0.18222E+03 59 cummingtonite 14.09 11.67 -2.42 -0.065 0.93713E+04 61 cymrite-K -2.69 -4.96 -2.27 -0.189 0.87851E+04 63 diaspore -4.38 -5.19 -0.80 -0.134 0.31091E+04 65 diopside 5.28 3.93 -1.35 -0.135 0.52260E+04 66 hedenbergite 3.87 2.10 -1.77 -0.177 0.68455E+04 68 eastonite -6.82 -8.10 -1.28 -0.049 0.49620E+04 69 enstatite 4.58 3.67 -0.90 -0.090 0.34952E+04 70 clinoenstatite-HiP 5.07 3.67 -1.39 -0.139 0.53982E+04 71 clinoenstatite 4.56 3.67 -0.89 -0.089 0.34379E+04 72 protoenstatite 4.71 3.67 -1.03 -0.103 0.40053E+04 73 epidote -5.02 -7.11 -2.09 -0.101 0.80769E+04 74 clinozoisite -10.06 -12.56 -2.50 -0.114 0.96836E+04 75 epidote-Fe 1.70 -1.65 -3.35 -0.174 0.12971E+05 76 fayalite 2.11 1.19 -0.92 -0.132 0.35649E+04 77 ferrosilite 1.02 0.00 -1.01 -0.101 0.39299E+04 78 forsterite 6.08 4.86 -1.22 -0.175 0.47344E+04 79 gedrite -10.69 -12.75 -2.06 -0.056 0.79899E+04 81 gibbsite -2.77 -5.19 -2.42 -0.346 0.93759E+04 82 glaucophane 0.82 -2.28 -3.10 -0.084 0.12008E+05 83 glaucophane-Fe -3.21 -7.78 -4.57 -0.124 0.17713E+05 84 goethite 1.07 0.26 -0.81 -0.175 0.31348E+04 86 greenalite 4.33 1.19 -3.14 -0.262 0.12162E+05 87 grunerite 2.00 -1.18 -3.18 -0.086 0.12296E+05 88 halite -1.03 -3.08 -2.05 -1.025 0.79399E+04 89 hematite 0.61 0.53 -0.08 -0.010 0.31381E+03 90 heulandite -12.45 -15.42 -2.96 -0.135 0.11470E+05 91 hercynite -8.15 -9.18 -1.03 -0.069 0.40020E+04 94 jadeite -1.68 -3.30 -1.62 -0.162 0.62871E+04 96 kalsilite -0.99 -2.58 -1.60 -0.228 0.61862E+04 97 kaolinite -10.08 -12.75 -2.68 -0.243 0.10362E+05 98 kyanite -10.98 -11.56 -0.59 -0.059 0.22669E+04 100 laumontite -8.36 -11.85 -3.48 -0.232 0.13493E+05 101 lawsonite -6.09 -9.47 -3.38 -0.225 0.13085E+05 102 leucite -2.83 -3.77 -0.94 -0.094 0.36373E+04 104 lizardite 9.35 6.69 -2.66 -0.222 0.10299E+05 105 magnesite -5.42 -8.32 -2.89 -0.965 0.11207E+05 107 minnesotaite 0.70 -1.19 -1.88 -0.111 0.72919E+04 108 minnesotaite-Mg 6.64 4.32 -2.32 -0.136 0.89640E+04 109 magnesioferrite 4.77 3.56 -1.22 -0.099 0.47084E+04 111 manganosite 5.27 2.92 -2.35 -0.588 0.91120E+04 112 margarite -18.15 -19.84 -1.69 -0.067 0.65328E+04 116 monticellite 8.62 5.12 -3.50 -0.499 0.13537E+05 118 mullite-Si -10.40 -11.56 -1.16 -0.116 0.45097E+04 119 muscovite -14.60 -15.34 -0.73 -0.043 0.28294E+04 120 paragonite -13.93 -14.86 -0.94 -0.055 0.36273E+04 121 nepheline -0.66 -2.11 -1.45 -0.207 0.56222E+04 122 osumilite(2) -13.82 -15.76 -1.94 -0.040 0.75155E+04 123 osumilite-Fe -29.41 -31.64 -2.24 -0.047 0.86603E+04 124 pargasite 4.13 0.24 -3.89 -0.102 0.15051E+05 125 periclase 5.48 3.02 -2.45 -0.613 0.94968E+04 126 periclase-Fe 2.91 1.19 -1.72 -0.431 0.66760E+04 127 perovskite-Al -8.06 -10.37 -2.32 -0.211 0.89766E+04 132 phlogopite-Na 5.52 4.58 -0.94 -0.052 0.36290E+04 134 prehnite -4.19 -7.37 -3.18 -0.187 0.12323E+05 135 prehnite-Fe 1.24 -1.92 -3.16 -0.190 0.12230E+05 138 px-Mg-tschermaks -6.68 -8.54 -1.86 -0.133 0.71994E+04 139 px-Ca-tschermaks -5.79 -8.28 -2.49 -0.178 0.96432E+04 141 pyrrhotite -8.60 -9.22 -0.62 -0.207 0.24083E+04 142 pyrrhotiteFe0.875 -9.35 -9.60 -0.25 -0.091 0.95930E+03 143 pyrophyllite -13.83 -15.13 -1.30 -0.081 0.50346E+04 146 riebeckite 5.77 3.12 -2.65 -0.073 0.10243E+05 147 ringwoodite-Fe 3.10 1.19 -1.91 -0.273 0.74067E+04 148 ringwoodite-Mg 9.22 4.86 -4.36 -0.622 0.16867E+05 149 rhodochrosite -5.36 -8.42 -3.06 -1.020 0.11853E+05 150 rhodonite 2.47 1.73 -0.74 -0.148 0.28613E+04 151 sanidine -4.43 -4.96 -0.53 -0.041 0.20480E+04 153 siderite -7.25 -10.15 -2.91 -0.968 0.11249E+05 154 sillimanite -11.10 -11.56 -0.46 -0.046 0.17808E+04 156 spinel -5.99 -7.35 -1.36 -0.091 0.52561E+04 162 stilpnomelane-Fe -7.45 -12.04 -4.59 -0.137 0.17777E+05 163 stilpnomelane-Mg -0.70 -2.87 -2.17 -0.065 0.84012E+04 164 stishovite 1.75 -1.19 -2.93 -0.978 0.11358E+05 165 sudoite-Fe -17.94 -21.94 -3.99 -0.129 0.15468E+05 166 sudoite -15.73 -18.27 -2.54 -0.082 0.98191E+04 167 sulfur -10.76 -12.26 -1.50 -0.462 0.58078E+04 168 sylvite -0.93 -3.55 -2.62 -1.310 0.10141E+05 169 talc 4.92 4.32 -0.60 -0.035 0.23109E+04 170 talc-Fe 2.09 -1.19 -3.27 -0.193 0.12671E+05 171 talc-tschermaks -6.26 -7.89 -1.63 -0.096 0.63076E+04 173 tephroite 6.40 4.65 -1.75 -0.250 0.67720E+04 176 topaz-H -9.05 -11.56 -2.52 -0.229 0.97469E+04 177 tremolite 14.84 12.18 -2.66 -0.072 0.10291E+05 179 troilite-low -8.51 -9.22 -0.72 -0.239 0.27713E+04 180 tschermakite -9.10 -12.24 -3.14 -0.085 0.12156E+05 183 wadsleyite-Fe 2.95 1.19 -1.76 -0.252 0.68266E+04 184 wadsleyite-Mg 8.28 4.86 -3.42 -0.488 0.13237E+05 185 wairakite -10.21 -11.84 -1.63 -0.096 0.63205E+04 186 walstromite 4.57 2.10 -2.47 -0.494 0.95715E+04 187 wollastonite 4.15 2.10 -2.06 -0.411 0.79620E+04 188 pseudo-wollastonite 4.27 2.10 -2.17 -0.434 0.84051E+04 189 zoisite -10.11 -12.56 -2.45 -0.111 0.94705E+04 192 beidellite-Ca -14.28 -15.90 -1.62 -0.100 0.62763E+04 193 beidellite-H -14.30 -16.45 -2.15 -0.137 0.83197E+04 194 beidellite-K -13.25 -15.20 -1.95 -0.119 0.75487E+04 195 beidellite-Mg -14.56 -15.95 -1.39 -0.086 0.53830E+04 196 beidellite-Na -13.19 -15.04 -1.85 -0.113 0.71721E+04 197 bornite -53.68 -54.14 -0.46 -0.034 0.17671E+04 199 chalcocite -13.98 -15.51 -1.53 -0.383 0.59368E+04 200 covellite -12.47 -13.89 -1.42 -0.540 0.54877E+04 202 montmorillonite-Ca -10.65 -11.88 -1.23 -0.076 0.47544E+04 203 montmorillonite-K -9.90 -11.17 -1.27 -0.078 0.49185E+04 204 montmorillonite-Mg -10.87 -11.92 -1.04 -0.065 0.40438E+04 205 montmorillonite-Na -9.55 -11.01 -1.46 -0.089 0.56535E+04 206 nontronite-Ca -3.65 -5.00 -1.35 -0.088 0.52395E+04 207 nontronite-H -3.67 -5.54 -1.87 -0.126 0.72554E+04 208 nontronite-K -2.61 -4.29 -1.68 -0.108 0.65035E+04 209 nontronite-Mg -3.88 -5.04 -1.16 -0.075 0.45039E+04 210 nontronite-Na -2.55 -4.14 -1.59 -0.102 0.61399E+04 215 gypsum -12.30 -14.52 -2.22 -0.555 0.85993E+04 232 alabandite -6.32 -7.49 -1.17 -0.389 0.45189E+04 234 anglesite -14.74 -17.19 -2.44 -1.222 0.94619E+04 238 boehmite -4.10 -5.19 -1.09 -0.181 0.42164E+04 242 copper,native 1.75 -1.63 -3.38 -1.175 0.13084E+05 244 ferrous-oxide 1.99 1.19 -0.80 -0.201 0.31097E+04 245 galena -9.65 -9.79 -0.15 -0.049 0.56769E+03 246 silver,native 0.50 -3.43 -3.93 -1.366 0.15205E+05 248 litharge 5.26 0.62 -4.64 -1.160 0.17961E+05 256 wurtzite -10.03 -10.83 -0.80 -0.266 0.30890E+04 257 zincite 2.10 -0.42 -2.52 -0.630 0.97566E+04 258 an20ab80 -5.48 -5.48 0.00 0.000 0.94833E+01 260 an30ab70 -5.98 -5.98 0.00 0.000 0.14893E+02 261 tr.625ac.25prg.125 9.33 8.40 -0.93 -0.025 0.36092E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 30 Loop limit = 500 Temperature = 573.00 C Pressure = 1280.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5510E+02 kg liquid = 0.9926E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9964 Stoichiometric ionic strength = .3285872E+01 Osmotic coef. = 0.0000 True ionic strength = .1823032E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.66333E-05 -5.1783 0.15065E-05 -5.8220 0.22712E+00 -0.6438 2 H2O 0.99639E+00 -0.0016 0.99639E+00 -0.0016 3 Cl- 0.15356E+00 -0.8137 0.30295E-01 -1.5186 0.19728E+00 -0.7049 4 SO4-- 0.20554E-03 -3.6871 0.69065E-06 -6.1607 0.33601E-02 -2.4736 5 HCO3- 0.14141E-04 -4.8495 0.30086E-05 -5.5216 0.21275E+00 -0.6721 6 HS- 0.12885E-03 -3.8899 0.25634E-04 -4.5912 0.19894E+00 -0.7013 7 H4SiO4 0.64403E-01 -1.1911 0.64403E-01 -1.1911 0.10000E+01 0.0000 8 Al+++ 0.10495E-16 -16.9790 0.22391E-22 -22.6499 0.21334E-05 -5.6709 9 Ca++ 0.16219E-05 -5.7900 0.43745E-08 -8.3591 0.26972E-02 -2.5691 10 Mg++ 0.10964E-05 -5.9600 0.24253E-08 -8.6152 0.22119E-02 -2.6552 11 Fe++ 0.15146E-07 -7.8197 0.35233E-10 -10.4531 0.23262E-02 -2.6334 12 K+ 0.42083E-01 -1.3759 0.91815E-02 -2.0371 0.21818E+00 -0.6612 13 Na+ 0.13838E+00 -0.8589 0.27637E-01 -1.5585 0.19972E+00 -0.6996 14 Mn++ 0.78097E-06 -6.1074 0.18847E-08 -8.7248 0.24133E-02 -2.6174 15 Zn++ 0.37234E-09 -9.4291 0.86615E-12 -12.0624 0.23262E-02 -2.6334 16 Cu+ 0.21281E-07 -7.6720 0.42387E-08 -8.3728 0.19918E+00 -0.7008 17 Pb++ 0.31130E-08 -8.5068 0.94180E-11 -11.0260 0.30254E-02 -2.5192 18 Ag+ 0.31290E-09 -9.5046 0.67186E-10 -10.1727 0.21472E+00 -0.6681 19 Ba++ 0.10200E-06 -6.9914 0.33177E-09 -9.4792 0.32528E-02 -2.4877 20 HPO4-- 0.10554E-08 -8.9766 0.35643E-11 -11.4480 0.33772E-02 -2.4714 21 HSiO3- 0.16687E-05 -5.7776 0.32919E-06 -6.4826 0.19728E+00 -0.7049 22 Ca(HSiO3)+ 0.71806E-08 -8.1438 0.15806E-08 -8.8012 0.22013E+00 -0.6573 23 Mg(HSiO3)+ 0.11580E-08 -8.9363 0.25491E-09 -9.5936 0.22013E+00 -0.6573 24 NaHSiO3,aq 0.17172E-05 -5.7652 0.17172E-05 -5.7652 0.10000E+01 0.0000 28 AgCl,aq 0.90574E-07 -7.0430 0.90574E-07 -7.0430 0.10000E+01 0.0000 29 AgCl2- 0.50592E-05 -5.2959 0.99806E-06 -6.0008 0.19728E+00 -0.7049 30 AgCl3-2 0.20352E-05 -5.6914 0.63251E-08 -8.1989 0.31078E-02 -2.5075 31 AgCl4-3 0.15735E-05 -5.8031 0.29055E-11 -11.5368 0.18465E-05 -5.7336 34 Ag(HS),aq 0.11401E-08 -8.9431 0.11401E-08 -8.9431 0.10000E+01 0.0000 35 Ag(HS)2- 0.53511E-08 -8.2716 0.10557E-08 -8.9765 0.19728E+00 -0.7049 38 HAlO2,aq 0.43556E-08 -8.3610 0.43556E-08 -8.3610 0.10000E+01 0.0000 39 AlO2- 0.15312E-04 -4.8150 0.26403E-05 -5.5783 0.17243E+00 -0.7634 41 Ba(HCO3)+ 0.41051E-06 -6.3867 0.94072E-07 -7.0265 0.22916E+00 -0.6399 42 BaCl+ 0.15229E-04 -4.8173 0.33523E-05 -5.4747 0.22013E+00 -0.6573 43 CH4,aq 0.17201E-08 -8.7644 0.20616E-08 -8.6858 0.11986E+01 0.0787 48 CO,aq 0.63284E-03 -3.1987 0.63284E-03 -3.1987 0.10000E+01 0.0000 49 CO2,aq 0.26751E+01 0.4273 0.32063E+01 0.5060 0.11986E+01 0.0787 50 CO3-2 0.42248E-10 -10.3742 0.13130E-12 -12.8817 0.31078E-02 -2.5075 51 CaCO3,aq 0.12687E-10 -10.8966 0.12687E-10 -10.8966 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.21211E-06 -6.6734 0.46692E-07 -7.3308 0.22013E+00 -0.6573 53 CaCl+ 0.11969E-03 -3.9220 0.26346E-04 -4.5793 0.22013E+00 -0.6573 54 CaCl2,aq 0.10140E-03 -3.9939 0.10140E-03 -3.9939 0.10000E+01 0.0000 55 CaOH+ 0.21682E-06 -6.6639 0.47727E-07 -7.3212 0.22013E+00 -0.6573 56 CaSO4,aq 0.14939E-06 -6.8257 0.14939E-06 -6.8257 0.10000E+01 0.0000 57 HCl,aq 0.20706E-02 -2.6839 0.20706E-02 -2.6839 0.10000E+01 0.0000 66 CuCl,aq 0.24831E-04 -4.6050 0.24831E-04 -4.6050 0.10000E+01 0.0000 67 CuCl2- 0.91568E-04 -4.0383 0.18064E-04 -4.7432 0.19728E+00 -0.7049 68 CuCl3-2 0.19735E-05 -5.7048 0.61333E-08 -8.2123 0.31078E-02 -2.5075 74 FeCl+ 0.34610E-06 -6.4608 0.76186E-07 -7.1181 0.22013E+00 -0.6573 75 FeCl2,aq 0.48753E-02 -2.3120 0.48753E-02 -2.3120 0.10000E+01 0.0000 77 FeO,aq 0.74521E-07 -7.1277 0.74521E-07 -7.1277 0.10000E+01 0.0000 78 FeOH+ 0.28331E-07 -7.5477 0.62363E-08 -8.2051 0.22013E+00 -0.6573 79 HFeO2- 0.92658E-08 -8.0331 0.18279E-08 -8.7380 0.19728E+00 -0.7049 82 FeO2- 0.59209E-08 -8.2276 0.11681E-08 -8.9325 0.19728E+00 -0.7049 83 HFeO2,aq 0.28747E-09 -9.5414 0.28747E-09 -9.5414 0.10000E+01 0.0000 84 H2,aq 0.46855E-02 -2.3292 0.56158E-02 -2.2506 0.11986E+01 0.0787 85 KCl,aq 0.65564E-01 -1.1833 0.65564E-01 -1.1833 0.10000E+01 0.0000 86 KHSO4,aq 0.13058E-01 -1.8841 0.13058E-01 -1.8841 0.10000E+01 0.0000 87 KOH,aq 0.12106E-05 -5.9170 0.12106E-05 -5.9170 0.10000E+01 0.0000 88 KSO4- 0.42807E-02 -2.3685 0.84448E-03 -3.0734 0.19728E+00 -0.7049 90 Mg(HCO3)+ 0.43702E-07 -7.3595 0.96199E-08 -8.0168 0.22013E+00 -0.6573 91 MgCl+ 0.13407E-04 -4.8727 0.29512E-05 -5.5300 0.22013E+00 -0.6573 92 MgOH+ 0.50492E-06 -6.2968 0.11115E-06 -6.9541 0.22013E+00 -0.6573 94 MnO,aq 0.64058E-07 -7.1934 0.64058E-07 -7.1934 0.10000E+01 0.0000 95 MnOH+ 0.17685E-06 -6.7524 0.38929E-07 -7.4097 0.22013E+00 -0.6573 97 HMnO2- 0.34138E-10 -10.4668 0.67346E-11 -11.1717 0.19728E+00 -0.7049 100 MnCl+ 0.11568E-02 -2.9368 0.25464E-03 -3.5941 0.22013E+00 -0.6573 101 MnSO4,aq 0.75352E-07 -7.1229 0.75352E-07 -7.1229 0.10000E+01 0.0000 102 NaCl,aq 0.42072E+00 -0.3760 0.42072E+00 -0.3760 0.10000E+01 0.0000 103 NaOH,aq 0.16814E-05 -5.7743 0.16814E-05 -5.7743 0.10000E+01 0.0000 105 OH- 0.82214E-05 -5.0851 0.14177E-05 -5.8484 0.17243E+00 -0.7634 110 HPO3-2 0.11334E-10 -10.9456 0.35225E-13 -13.4532 0.31078E-02 -2.5075 111 H3PO3,aq 0.10629E-09 -9.9735 0.10629E-09 -9.9735 0.10000E+01 0.0000 112 H2PO3- 0.26786E-08 -8.5721 0.52843E-09 -9.2770 0.19728E+00 -0.7049 113 H3PO4,aq 0.98286E-06 -6.0075 0.98286E-06 -6.0075 0.10000E+01 0.0000 114 H2PO4- 0.14091E-05 -5.8511 0.29249E-06 -6.5339 0.20757E+00 -0.6828 116 H4P2O7,aq 0.86802E-10 -10.0615 0.86802E-10 -10.0615 0.10000E+01 0.0000 117 H3P2O7- 0.83761E-09 -9.0770 0.16524E-09 -9.7819 0.19728E+00 -0.7049 118 H2P2O7-2 0.22647E-06 -6.6450 0.70382E-09 -9.1525 0.31078E-02 -2.5075 119 HP2O7-3 0.16110E-07 -7.7929 0.29749E-13 -13.5265 0.18465E-05 -5.7336 121 PbCl+ 0.16186E-05 -5.7909 0.35630E-06 -6.4482 0.22013E+00 -0.6573 122 PbCl2,aq 0.86653E-04 -4.0622 0.86653E-04 -4.0622 0.10000E+01 0.0000 123 PbCl3- 0.10620E-03 -3.9739 0.20951E-04 -4.6788 0.19728E+00 -0.7049 124 PbCl4-2 0.21955E-04 -4.6585 0.68231E-07 -7.1660 0.31078E-02 -2.5075 125 PbO,aq 0.54331E-08 -8.2650 0.54331E-08 -8.2650 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11400E-03 -3.9431 0.11400E-03 -3.9431 0.10000E+01 0.0000 128 Pb(HS)3- 0.12260E-04 -4.9115 0.24186E-05 -5.6164 0.19728E+00 -0.7049 129 H2S,aq 0.10538E+01 0.0228 0.12630E+01 0.1014 0.11986E+01 0.0787 130 S2-2 0.13716E-07 -7.8628 0.42626E-10 -10.3703 0.31078E-02 -2.5075 131 S3-2 0.13138E-08 -8.8815 0.40831E-11 -11.3890 0.31078E-02 -2.5075 132 S3- 0.13624E-01 -1.8657 0.26877E-02 -2.5706 0.19728E+00 -0.7049 133 S4-2 0.10616E-09 -9.9740 0.32994E-12 -12.4816 0.31078E-02 -2.5075 135 SO2,aq 0.29046E+00 -0.5369 0.29046E+00 -0.5369 0.10000E+01 0.0000 136 SO3-2 0.61077E-09 -9.2141 0.30188E-11 -11.5202 0.49426E-02 -2.3060 137 HSO3- 0.31126E-03 -3.5069 0.61404E-04 -4.2118 0.19728E+00 -0.7049 138 HSO4- 0.93432E-02 -2.0295 0.21125E-02 -2.6752 0.22611E+00 -0.6457 140 S2O3-2 0.50690E-06 -6.2951 0.15754E-08 -8.8026 0.31078E-02 -2.5075 141 HS2O3- 0.46654E-06 -6.3311 0.92038E-07 -7.0360 0.19728E+00 -0.7049 142 H2S2O3,aq 0.27873E-07 -7.5548 0.27873E-07 -7.5548 0.10000E+01 0.0000 150 S4O6-2 0.49437E-09 -9.3060 0.15364E-11 -11.8135 0.31078E-02 -2.5075 152 ZnCl+ 0.27420E-03 -3.5619 0.60358E-04 -4.2193 0.22013E+00 -0.6573 153 ZnCl2,aq 0.88123E-03 -3.0549 0.88123E-03 -3.0549 0.10000E+01 0.0000 154 ZnCl3- 0.84304E-04 -4.0742 0.16631E-04 -4.7791 0.19728E+00 -0.7049 155 ZnO,aq 0.34103E-07 -7.4672 0.34103E-07 -7.4672 0.10000E+01 0.0000 156 ZnOH+ 0.16697E-05 -5.7774 0.36755E-06 -6.4347 0.22013E+00 -0.6573 158 HZnO2- 0.27450E-09 -9.5615 0.54153E-10 -10.2664 0.19728E+00 -0.7049 Charge balance for all species = 0.2550E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6633336E-05 0.4296935E+01 0.3538605E+04 0.0000 2 H2O 0.1000000E+01 0.5251269E+02 0.7729376E+06 0.0000 3 Cl- 0.1535632E+00 0.6562851E+00 0.1901009E+05 4.3034 4 SO4-- 0.2055439E-03 0.2521494E+00 0.1979002E+05 5.4833 5 HCO3- 0.1414107E-04 0.2675783E+01 0.1333957E+06 0.3004 6 HS- 0.1288489E-03 0.1160570E+01 0.3135961E+05 1.2308 7 H4SiO4 0.6440275E-01 0.6440615E-01 0.5057769E+04 -1.1911 8 Al+++ 0.1049539E-16 0.1531616E-04 0.3376405E+00 -5.1839 9 Ca++ 0.1621869E-05 0.2232983E-03 0.7311897E+01 3.2850 10 Mg++ 0.1096450E-05 0.1505316E-04 0.2990109E+00 3.0288 11 Fe++ 0.1514601E-07 0.4875747E-02 0.2224742E+03 1.1910 12 K+ 0.4208282E-01 0.1249875E+00 0.3993046E+04 3.7849 13 Na+ 0.1383826E+00 0.5591067E+00 0.1050192E+05 4.2635 14 Mn++ 0.7809679E-06 0.1157875E-02 0.5197245E+02 2.9193 15 Zn++ 0.3723430E-09 0.1241437E-02 0.6630434E+02 -0.4184 16 Cu+ 0.2128084E-07 0.1183938E-03 0.6146316E+01 -2.5507 17 Pb++ 0.3112962E-08 0.3426918E-03 0.5801111E+02 0.6180 18 Ag+ 0.3128974E-09 0.8765277E-05 0.7725116E+00 -4.3507 19 Ba++ 0.1019969E-06 0.1574173E-04 0.1766396E+01 2.1649 20 HPO4-- 0.1055395E-08 0.2882835E-05 0.2260657E+00 0.1960 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265347E+01 -.2984935E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5212666E+02 -.1618825E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2502958E+00 0.1427018E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1152039E+01 0.8105364E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.6393269E-01 0.7966163E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1520356E-04 0.6793360E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2216568E-03 0.3062531E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1494250E-04 0.5734150E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.4839905E-02 0.3926849E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1240687E+00 0.1341417E-02 0.0000000E+00 13 Na+ 0.5545993E+00 0.5549966E+00 -.3972487E-03 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149363E-02 0.1367222E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1232311E-02 0.1067023E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1175235E-03 0.2820862E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1562601E-04 0.3974645E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2861642E-05 0.5705858E-05 0.0000000E+00 Chg. balance for solid moles: -.1287E-17 Mass of aqueous solution: 0.121495E+04 g Temperature = 573.00 C Pressure = 1280.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.4292E-03 -3.367 0.5843E-01 -1.233 1.057 0.1972E-01 annite 0.9414E-06 -6.026 0.4819E-03 -3.317 0.8716E-02 0.1453E-03 phlogopite 0.1911E-05 -5.719 0.7976E-03 -3.098 0.1443E-01 0.2860E-03 biotite-Mn 0.4557E-07 -7.341 0.2320E-04 -4.634 0.4197E-03 0.6956E-05 apatite-OH 0.1902E-05 -5.721 0.9554E-03 -3.020 0.1728E-01 0.3036E-03 magnetite -.2473E-04 1.000 -.5726E-02 1.000 -.1036 -.1101E-02 pyrite 0.3716E-02 -2.430 0.4459 -0.351 8.064 0.8896E-01 quartz 0.7709E-01 -1.113 4.632 0.666 83.77 1.749 barite 0.3975E-04 -4.401 0.9277E-02 -2.033 0.1678 0.2071E-02 chalcopyrite 0.2821E-03 -3.550 0.5176E-01 -1.286 0.9362 0.1208E-01 sphalerite 0.1067E-02 -2.972 0.1040 -0.983 1.880 0.2542E-01 an25ab75 -.5297E-03 1.000 -.1410 1.000 -2.550 -.5309E-01 microcline 0.1339E-02 -2.873 0.3726 -0.429 6.738 0.1455 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3248E+00 0.3248E+00 1.0000 -0.488 phlogopite 0.6595E+00 0.6595E+00 1.0000 -0.181 biotite-Mn 0.1572E-01 0.1572E-01 1.0000 -1.803 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 magnetite 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 an25ab75 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.529182 g Volume = 1.989510 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.52 -14.52 0.00 0.000 0.00000E+00 24 annite 0.07 0.07 0.00 0.000 -0.35571E-10 25 phlogopite 4.66 4.66 0.00 0.000 -0.34389E-11 26 biotite-Mn 9.20 9.20 0.00 0.000 0.68778E-11 30 apatite-OH -52.85 -52.85 0.00 0.000 0.00000E+00 115 microcline -4.97 -4.97 0.00 0.000 0.00000E+00 140 pyrite -21.48 -21.48 0.00 0.000 0.00000E+00 144 quartz -1.19 -1.19 0.00 0.000 0.00000E+00 237 barite -15.64 -15.64 0.00 0.000 0.00000E+00 240 chalcopyrite -23.11 -23.11 0.00 0.000 0.00000E+00 255 sphalerite -10.83 -10.83 0.00 0.000 -0.13756E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.28 -0.276 0.10688E+04 2.831 2 CO2,gas -9.73 -11.34 -1.61 -0.536 0.62300E+04 1.498 3 CH4,gas 6.89 -3.95 -10.85 -2.712 0.42000E+05 -7.740 4 H2,gas 5.90 1.85 -4.05 -2.317 0.15698E+05 -0.947 5 H2S,gas -8.11 -10.41 -2.30 -1.152 0.89192E+04 0.804 6 CO,gas -3.61 -9.49 -5.88 -1.810 0.22773E+05 -2.774 7 SO3,gas -7.29 -17.80 -10.51 -2.628 0.40701E+05 -7.405 8 O2,gas 16.66 -3.70 -20.36 -13.572 0.78823E+05 -17.251 9 HCl,gas -5.98 -7.34 -1.36 -0.679 0.52553E+04 -1.357 10 acmite 3.65 2.15 -1.50 -0.156 0.58104E+04 12 akimotoite 6.02 1.84 -4.18 -0.837 0.16194E+05 13 akimotoite-Fe 3.93 0.00 -3.93 -0.786 0.15222E+05 14 albite-high -4.38 -4.49 -0.11 -0.008 0.41133E+03 15 albite -4.37 -4.49 -0.12 -0.009 0.47106E+03 16 almandine -8.82 -10.37 -1.55 -0.078 0.60080E+04 17 pyrope -2.21 -4.85 -2.65 -0.132 0.10245E+05 18 analcite -2.36 -3.30 -0.94 -0.105 0.36506E+04 19 andalusite -11.14 -11.56 -0.42 -0.042 0.16453E+04 20 andradite 11.43 6.82 -4.62 -0.240 0.17879E+05 21 grossular 0.81 -4.09 -4.89 -0.245 0.18940E+05 27 anorthite -8.85 -9.46 -0.61 -0.047 0.23709E+04 28 anthophyllite 14.02 11.69 -2.34 -0.063 0.90474E+04 29 anthophyllite-Fe 1.45 -1.18 -2.63 -0.071 0.10176E+05 31 apatite-OH-zs -50.70 -52.85 -2.15 -0.165 0.83211E+04 32 apatite-Cl-zs -57.01 -60.19 -3.18 -0.265 0.12329E+05 33 aragonite -4.51 -8.06 -3.54 -1.182 0.13724E+05 34 brucite 5.29 3.03 -2.27 -0.453 0.87700E+04 35 calcite -4.62 -8.06 -3.44 -1.148 0.13331E+05 36 carnegieite-low -0.36 -2.11 -1.75 -0.250 0.67642E+04 37 carnegieite-high -0.29 -2.11 -1.82 -0.260 0.70545E+04 38 carpholite-Mg -7.76 -9.72 -1.96 -0.131 0.75896E+04 39 carpholite-Fe -9.11 -11.56 -2.45 -0.163 0.94774E+04 40 celadonite -1.02 -3.13 -2.11 -0.124 0.81581E+04 41 celadonite-Fe -2.42 -4.97 -2.54 -0.150 0.98465E+04 42 chrysotile 9.17 6.70 -2.47 -0.206 0.95723E+04 44 clinochlore 2.66 1.19 -1.47 -0.046 0.56806E+04 45 daphnite -4.38 -8.00 -3.62 -0.113 0.14012E+05 48 chloritoid-Mg -7.26 -8.53 -1.28 -0.085 0.49392E+04 49 chloritoid-Fe -9.19 -10.37 -1.19 -0.079 0.45904E+04 50 chloritoid-Mn -7.03 -8.64 -1.61 -0.107 0.62427E+04 52 coesite -0.90 -1.19 -0.29 -0.095 0.11065E+04 53 cordierite-H -19.89 -20.63 -0.74 -0.027 0.28796E+04 54 cordierite-Fe -22.44 -24.31 -1.87 -0.064 0.72286E+04 55 cordierite-Mn -18.06 -20.85 -2.79 -0.096 0.10818E+05 56 corundum -9.77 -10.37 -0.60 -0.054 0.23136E+04 58 cristobalite -1.14 -1.19 -0.05 -0.016 0.18222E+03 59 cummingtonite 14.09 11.69 -2.40 -0.065 0.92964E+04 61 cymrite-K -2.69 -4.97 -2.27 -0.190 0.88056E+04 63 diaspore -4.38 -5.19 -0.80 -0.134 0.31069E+04 65 diopside 5.28 3.93 -1.35 -0.135 0.52159E+04 66 hedenbergite 3.87 2.10 -1.77 -0.177 0.68462E+04 68 eastonite -6.82 -8.10 -1.28 -0.049 0.49569E+04 69 enstatite 4.58 3.68 -0.90 -0.090 0.34738E+04 70 clinoenstatite-HiP 5.07 3.68 -1.39 -0.139 0.53768E+04 71 clinoenstatite 4.56 3.68 -0.88 -0.088 0.34166E+04 72 protoenstatite 4.71 3.68 -1.03 -0.103 0.39839E+04 73 epidote -5.02 -7.10 -2.09 -0.101 0.80738E+04 74 clinozoisite -10.06 -12.56 -2.50 -0.114 0.96784E+04 75 epidote-Fe 1.70 -1.65 -3.35 -0.174 0.12970E+05 76 fayalite 2.11 1.19 -0.92 -0.132 0.35650E+04 77 ferrosilite 1.02 0.00 -1.02 -0.102 0.39300E+04 78 forsterite 6.08 4.87 -1.22 -0.174 0.47130E+04 79 gedrite -10.69 -12.74 -2.05 -0.055 0.79279E+04 81 gibbsite -2.77 -5.19 -2.42 -0.346 0.93738E+04 82 glaucophane 0.82 -2.27 -3.09 -0.084 0.11978E+05 83 glaucophane-Fe -3.21 -7.78 -4.58 -0.124 0.17716E+05 84 goethite 1.07 0.26 -0.81 -0.175 0.31347E+04 86 greenalite 4.33 1.19 -3.14 -0.262 0.12163E+05 87 grunerite 2.00 -1.18 -3.18 -0.086 0.12296E+05 88 halite -1.03 -3.08 -2.05 -1.025 0.79370E+04 89 hematite 0.61 0.53 -0.08 -0.010 0.31375E+03 90 heulandite -12.45 -15.41 -2.96 -0.135 0.11466E+05 91 hercynite -8.15 -9.18 -1.03 -0.069 0.39977E+04 94 jadeite -1.68 -3.30 -1.62 -0.162 0.62883E+04 96 kalsilite -0.99 -2.59 -1.60 -0.229 0.62068E+04 97 kaolinite -10.08 -12.75 -2.68 -0.243 0.10358E+05 98 kyanite -10.98 -11.56 -0.58 -0.058 0.22626E+04 100 laumontite -8.36 -11.85 -3.48 -0.232 0.13489E+05 101 lawsonite -6.09 -9.47 -3.38 -0.225 0.13082E+05 102 leucite -2.83 -3.78 -0.94 -0.094 0.36579E+04 104 lizardite 9.35 6.70 -2.65 -0.221 0.10267E+05 105 magnesite -5.42 -8.31 -2.89 -0.964 0.11196E+05 106 magnetite 1.72 1.72 0.00 0.000 0.17194E-11 107 minnesotaite 0.70 -1.19 -1.88 -0.111 0.72921E+04 108 minnesotaite-Mg 6.64 4.33 -2.31 -0.136 0.89319E+04 109 magnesioferrite 4.77 3.56 -1.21 -0.099 0.46976E+04 111 manganosite 5.27 2.92 -2.36 -0.589 0.91230E+04 112 margarite -18.15 -19.84 -1.69 -0.067 0.65248E+04 116 monticellite 8.62 5.12 -3.49 -0.499 0.13527E+05 118 mullite-Si -10.40 -11.56 -1.16 -0.116 0.45054E+04 119 muscovite -14.60 -15.34 -0.73 -0.043 0.28457E+04 120 paragonite -13.93 -14.86 -0.94 -0.055 0.36243E+04 121 nepheline -0.66 -2.11 -1.45 -0.207 0.56234E+04 122 osumilite(2) -13.82 -15.76 -1.94 -0.040 0.74997E+04 123 osumilite-Fe -29.41 -31.65 -2.24 -0.047 0.86725E+04 124 pargasite 4.13 0.25 -3.88 -0.102 0.15006E+05 125 periclase 5.48 3.03 -2.45 -0.613 0.94861E+04 126 periclase-Fe 2.91 1.19 -1.72 -0.431 0.66761E+04 127 perovskite-Al -8.06 -10.37 -2.32 -0.211 0.89724E+04 132 phlogopite-Na 5.52 4.59 -0.93 -0.052 0.35981E+04 134 prehnite -4.19 -7.37 -3.18 -0.187 0.12319E+05 135 prehnite-Fe 1.24 -1.92 -3.16 -0.190 0.12229E+05 138 px-Mg-tschermaks -6.68 -8.53 -1.86 -0.133 0.71844E+04 139 px-Ca-tschermaks -5.79 -8.28 -2.49 -0.178 0.96395E+04 141 pyrrhotite -8.60 -9.22 -0.62 -0.207 0.24084E+04 142 pyrrhotiteFe0.875 -9.35 -9.60 -0.25 -0.091 0.95938E+03 143 pyrophyllite -13.83 -15.13 -1.30 -0.081 0.50303E+04 146 riebeckite 5.77 3.12 -2.65 -0.073 0.10250E+05 147 ringwoodite-Fe 3.10 1.19 -1.91 -0.273 0.74068E+04 148 ringwoodite-Mg 9.22 4.87 -4.35 -0.622 0.16845E+05 149 rhodochrosite -5.36 -8.42 -3.06 -1.021 0.11864E+05 150 rhodonite 2.47 1.73 -0.74 -0.148 0.28723E+04 151 sanidine -4.43 -4.97 -0.53 -0.041 0.20685E+04 153 siderite -7.25 -10.15 -2.91 -0.968 0.11250E+05 154 sillimanite -11.10 -11.56 -0.46 -0.046 0.17765E+04 156 spinel -5.99 -7.35 -1.35 -0.090 0.52411E+04 162 stilpnomelane-Fe -7.45 -12.05 -4.59 -0.137 0.17784E+05 163 stilpnomelane-Mg -0.70 -2.86 -2.16 -0.064 0.83548E+04 164 stishovite 1.75 -1.19 -2.93 -0.978 0.11358E+05 165 sudoite-Fe -17.94 -21.94 -3.99 -0.129 0.15459E+05 166 sudoite -15.73 -18.26 -2.53 -0.082 0.97892E+04 167 sulfur -10.76 -12.26 -1.50 -0.462 0.58077E+04 168 sylvite -0.93 -3.56 -2.62 -1.312 0.10157E+05 169 talc 4.92 4.33 -0.59 -0.035 0.22788E+04 170 talc-Fe 2.09 -1.19 -3.27 -0.193 0.12671E+05 171 talc-tschermaks -6.26 -7.88 -1.62 -0.095 0.62819E+04 173 tephroite 6.40 4.65 -1.75 -0.251 0.67939E+04 176 topaz-H -9.05 -11.56 -2.52 -0.229 0.97426E+04 177 tremolite 14.84 12.20 -2.64 -0.071 0.10239E+05 179 troilite-low -8.51 -9.22 -0.72 -0.239 0.27715E+04 180 tschermakite -9.10 -12.23 -3.13 -0.085 0.12116E+05 183 wadsleyite-Fe 2.95 1.19 -1.76 -0.252 0.68267E+04 184 wadsleyite-Mg 8.28 4.87 -3.41 -0.488 0.13216E+05 185 wairakite -10.21 -11.84 -1.63 -0.096 0.63168E+04 186 walstromite 4.57 2.10 -2.47 -0.494 0.95721E+04 187 wollastonite 4.15 2.10 -2.06 -0.411 0.79626E+04 188 pseudo-wollastonite 4.27 2.10 -2.17 -0.434 0.84057E+04 189 zoisite -10.11 -12.56 -2.44 -0.111 0.94652E+04 192 beidellite-Ca -14.28 -15.90 -1.62 -0.100 0.62714E+04 193 beidellite-H -14.30 -16.45 -2.15 -0.137 0.83147E+04 194 beidellite-K -13.25 -15.20 -1.95 -0.119 0.75512E+04 195 beidellite-Mg -14.56 -15.95 -1.39 -0.086 0.53763E+04 196 beidellite-Na -13.19 -15.04 -1.85 -0.113 0.71683E+04 197 bornite -53.68 -54.14 -0.46 -0.034 0.17669E+04 199 chalcocite -13.98 -15.51 -1.53 -0.383 0.59367E+04 200 covellite -12.47 -13.89 -1.42 -0.540 0.54876E+04 202 montmorillonite-Ca -10.65 -11.87 -1.23 -0.076 0.47474E+04 203 montmorillonite-K -9.90 -11.17 -1.27 -0.078 0.49188E+04 204 montmorillonite-Mg -10.87 -11.92 -1.04 -0.064 0.40349E+04 205 montmorillonite-Na -9.55 -11.01 -1.46 -0.089 0.56475E+04 206 nontronite-Ca -3.65 -5.00 -1.35 -0.088 0.52388E+04 207 nontronite-H -3.67 -5.54 -1.87 -0.126 0.72547E+04 208 nontronite-K -2.61 -4.29 -1.68 -0.108 0.65102E+04 209 nontronite-Mg -3.88 -5.04 -1.16 -0.075 0.45014E+04 210 nontronite-Na -2.55 -4.14 -1.59 -0.102 0.61402E+04 215 gypsum -12.30 -14.52 -2.22 -0.555 0.85993E+04 232 alabandite -6.32 -7.49 -1.17 -0.390 0.45299E+04 234 anglesite -14.74 -17.19 -2.45 -1.223 0.94679E+04 238 boehmite -4.10 -5.19 -1.09 -0.181 0.42143E+04 242 copper,native 1.75 -1.63 -3.38 -1.175 0.13084E+05 244 ferrous-oxide 1.99 1.19 -0.80 -0.201 0.31097E+04 245 galena -9.65 -9.80 -0.15 -0.049 0.57427E+03 246 silver,native 0.50 -3.43 -3.93 -1.366 0.15206E+05 248 litharge 5.26 0.62 -4.64 -1.160 0.17968E+05 256 wurtzite -10.03 -10.83 -0.80 -0.266 0.30890E+04 257 zincite 2.10 -0.42 -2.52 -0.630 0.97566E+04 258 an20ab80 -5.48 -5.48 0.00 0.000 0.97292E+01 259 an25ab75 -5.73 -5.73 0.00 0.000 -0.68778E-11 260 an30ab70 -5.98 -5.98 0.00 0.000 0.14647E+02 261 tr.625ac.25prg.125 9.33 8.41 -0.92 -0.025 0.35713E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 28 Loop limit = 500 Temperature = 573.00 C Pressure = 1280.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5510E+02 kg liquid = 0.9926E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9964 Stoichiometric ionic strength = .3286324E+01 Osmotic coef. = 0.0000 True ionic strength = .1824797E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.66243E-05 -5.1789 0.15038E-05 -5.8228 0.22701E+00 -0.6440 2 H2O 0.99639E+00 -0.0016 0.99639E+00 -0.0016 3 Cl- 0.15365E+00 -0.8135 0.30295E-01 -1.5186 0.19717E+00 -0.7052 4 SO4-- 0.20663E-03 -3.6848 0.69305E-06 -6.1592 0.33540E-02 -2.4744 5 HCO3- 0.14174E-04 -4.8485 0.30141E-05 -5.5208 0.21265E+00 -0.6723 6 HS- 0.12916E-03 -3.8889 0.25682E-04 -4.5904 0.19884E+00 -0.7015 7 H4SiO4 0.64403E-01 -1.1911 0.64403E-01 -1.1911 0.10000E+01 0.0000 8 Al+++ 0.10414E-16 -16.9824 0.22121E-22 -22.6552 0.21243E-05 -5.6728 9 Ca++ 0.16194E-05 -5.7906 0.43594E-08 -8.3606 0.26919E-02 -2.5699 10 Mg++ 0.10947E-05 -5.9607 0.24163E-08 -8.6168 0.22073E-02 -2.6561 11 Fe++ 0.15121E-07 -7.8204 0.35103E-10 -10.4547 0.23214E-02 -2.6342 12 K+ 0.42307E-01 -1.3736 0.92262E-02 -2.0350 0.21808E+00 -0.6614 13 Na+ 0.13834E+00 -0.8591 0.27614E-01 -1.5589 0.19962E+00 -0.6998 14 Mn++ 0.78220E-06 -6.1067 0.18839E-08 -8.7250 0.24084E-02 -2.6183 15 Zn++ 0.37174E-09 -9.4298 0.86296E-12 -12.0640 0.23214E-02 -2.6342 16 Cu+ 0.21253E-07 -7.6726 0.42309E-08 -8.3736 0.19908E+00 -0.7010 17 Pb++ 0.31133E-08 -8.5068 0.94013E-11 -11.0268 0.30197E-02 -2.5200 18 Ag+ 0.31255E-09 -9.5051 0.67080E-10 -10.1734 0.21462E+00 -0.6683 19 Ba++ 0.10183E-06 -6.9921 0.33062E-09 -9.4807 0.32468E-02 -2.4885 20 HPO4-- 0.10609E-08 -8.9743 0.35763E-11 -11.4466 0.33711E-02 -2.4722 21 HSiO3- 0.16726E-05 -5.7766 0.32979E-06 -6.4818 0.19717E+00 -0.7052 22 Ca(HSiO3)+ 0.71719E-08 -8.1444 0.15780E-08 -8.8019 0.22003E+00 -0.6575 23 Mg(HSiO3)+ 0.11564E-08 -8.9369 0.25444E-09 -9.5944 0.22003E+00 -0.6575 24 NaHSiO3,aq 0.17189E-05 -5.7648 0.17189E-05 -5.7648 0.10000E+01 0.0000 28 AgCl,aq 0.90432E-07 -7.0437 0.90432E-07 -7.0437 0.10000E+01 0.0000 29 AgCl2- 0.50540E-05 -5.2964 0.99652E-06 -6.0015 0.19717E+00 -0.7052 30 AgCl3-2 0.20359E-05 -5.6912 0.63154E-08 -8.1996 0.31020E-02 -2.5084 31 AgCl4-3 0.15781E-05 -5.8019 0.29011E-11 -11.5374 0.18384E-05 -5.7356 34 Ag(HS),aq 0.11404E-08 -8.9429 0.11404E-08 -8.9429 0.10000E+01 0.0000 35 Ag(HS)2- 0.53655E-08 -8.2704 0.10579E-08 -8.9755 0.19717E+00 -0.7052 38 HAlO2,aq 0.43266E-08 -8.3638 0.43266E-08 -8.3638 0.10000E+01 0.0000 39 AlO2- 0.15247E-04 -4.8168 0.26275E-05 -5.5805 0.17233E+00 -0.7636 41 Ba(HCO3)+ 0.41001E-06 -6.3872 0.93918E-07 -7.0273 0.22906E+00 -0.6400 42 BaCl+ 0.15183E-04 -4.8186 0.33408E-05 -5.4762 0.22003E+00 -0.6575 43 CH4,aq 0.17205E-08 -8.7644 0.20621E-08 -8.6857 0.11986E+01 0.0787 48 CO,aq 0.63289E-03 -3.1987 0.63289E-03 -3.1987 0.10000E+01 0.0000 49 CO2,aq 0.26751E+01 0.4273 0.32064E+01 0.5060 0.11986E+01 0.0787 50 CO3-2 0.42483E-10 -10.3718 0.13178E-12 -12.8801 0.31020E-02 -2.5084 51 CaCO3,aq 0.12690E-10 -10.8966 0.12690E-10 -10.8966 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.21186E-06 -6.6739 0.46616E-07 -7.3315 0.22003E+00 -0.6575 53 CaCl+ 0.11933E-03 -3.9233 0.26255E-04 -4.5808 0.22003E+00 -0.6575 54 CaCl2,aq 0.10106E-03 -3.9954 0.10106E-03 -3.9954 0.10000E+01 0.0000 55 CaOH+ 0.21655E-06 -6.6644 0.47648E-07 -7.3220 0.22003E+00 -0.6575 56 CaSO4,aq 0.14939E-06 -6.8257 0.14939E-06 -6.8257 0.10000E+01 0.0000 57 HCl,aq 0.20669E-02 -2.6847 0.20669E-02 -2.6847 0.10000E+01 0.0000 66 CuCl,aq 0.24785E-04 -4.6058 0.24785E-04 -4.6058 0.10000E+01 0.0000 67 CuCl2- 0.91450E-04 -4.0388 0.18032E-04 -4.7440 0.19717E+00 -0.7052 68 CuCl3-2 0.19737E-05 -5.7047 0.61223E-08 -8.2131 0.31020E-02 -2.5084 74 FeCl+ 0.34499E-06 -6.4622 0.75907E-07 -7.1197 0.22003E+00 -0.6575 75 FeCl2,aq 0.48575E-02 -2.3136 0.48575E-02 -2.3136 0.10000E+01 0.0000 77 FeO,aq 0.74517E-07 -7.1277 0.74517E-07 -7.1277 0.10000E+01 0.0000 78 FeOH+ 0.28290E-07 -7.5484 0.62246E-08 -8.2059 0.22003E+00 -0.6575 79 HFeO2- 0.92870E-08 -8.0321 0.18311E-08 -8.7373 0.19717E+00 -0.7052 82 FeO2- 0.59343E-08 -8.2266 0.11701E-08 -8.9318 0.19717E+00 -0.7052 83 HFeO2,aq 0.28745E-09 -9.5414 0.28745E-09 -9.5414 0.10000E+01 0.0000 84 H2,aq 0.46857E-02 -2.3292 0.56161E-02 -2.2506 0.11986E+01 0.0787 85 KCl,aq 0.65884E-01 -1.1812 0.65884E-01 -1.1812 0.10000E+01 0.0000 86 KHSO4,aq 0.13144E-01 -1.8813 0.13144E-01 -1.8813 0.10000E+01 0.0000 87 KOH,aq 0.12187E-05 -5.9141 0.12187E-05 -5.9141 0.10000E+01 0.0000 88 KSO4- 0.43187E-02 -2.3646 0.85154E-03 -3.0698 0.19717E+00 -0.7052 90 Mg(HCO3)+ 0.43641E-07 -7.3601 0.96022E-08 -8.0176 0.22003E+00 -0.6575 91 MgCl+ 0.13364E-04 -4.8741 0.29404E-05 -5.5316 0.22003E+00 -0.6575 92 MgOH+ 0.50420E-06 -6.2974 0.11094E-06 -6.9549 0.22003E+00 -0.6575 94 MnO,aq 0.64262E-07 -7.1920 0.64262E-07 -7.1920 0.10000E+01 0.0000 95 MnOH+ 0.17717E-06 -6.7516 0.38982E-07 -7.4091 0.22003E+00 -0.6575 97 HMnO2- 0.34327E-10 -10.4644 0.67683E-11 -11.1695 0.19717E+00 -0.7052 100 MnCl+ 0.11568E-02 -2.9368 0.25452E-03 -3.5943 0.22003E+00 -0.6575 101 MnSO4,aq 0.75580E-07 -7.1216 0.75580E-07 -7.1216 0.10000E+01 0.0000 102 NaCl,aq 0.42037E+00 -0.3764 0.42037E+00 -0.3764 0.10000E+01 0.0000 103 NaOH,aq 0.16830E-05 -5.7739 0.16830E-05 -5.7739 0.10000E+01 0.0000 105 OH- 0.82416E-05 -5.0840 0.14202E-05 -5.8476 0.17233E+00 -0.7636 110 HPO3-2 0.11394E-10 -10.9433 0.35345E-13 -13.4517 0.31020E-02 -2.5084 111 H3PO3,aq 0.10627E-09 -9.9736 0.10627E-09 -9.9736 0.10000E+01 0.0000 112 H2PO3- 0.26843E-08 -8.5712 0.52927E-09 -9.2763 0.19717E+00 -0.7052 113 H3PO4,aq 0.98259E-06 -6.0076 0.98259E-06 -6.0076 0.10000E+01 0.0000 114 H2PO4- 0.14120E-05 -5.8502 0.29294E-06 -6.5332 0.20747E+00 -0.6831 116 H4P2O7,aq 0.86756E-10 -10.0617 0.86756E-10 -10.0617 0.10000E+01 0.0000 117 H3P2O7- 0.83912E-09 -9.0762 0.16545E-09 -9.7813 0.19717E+00 -0.7052 118 H2P2O7-2 0.22759E-06 -6.6428 0.70600E-09 -9.1512 0.31020E-02 -2.5084 119 HP2O7-3 0.16262E-07 -7.7888 0.29895E-13 -13.5244 0.18384E-05 -5.7356 121 PbCl+ 0.16165E-05 -5.7914 0.35568E-06 -6.4489 0.22003E+00 -0.6575 122 PbCl2,aq 0.86502E-04 -4.0630 0.86502E-04 -4.0630 0.10000E+01 0.0000 123 PbCl3- 0.10607E-03 -3.9744 0.20915E-04 -4.6796 0.19717E+00 -0.7052 124 PbCl4-2 0.21958E-04 -4.6584 0.68115E-07 -7.1668 0.31020E-02 -2.5084 125 PbO,aq 0.54432E-08 -8.2641 0.54432E-08 -8.2641 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11422E-03 -3.9422 0.11422E-03 -3.9422 0.10000E+01 0.0000 128 Pb(HS)3- 0.12313E-04 -4.9096 0.24279E-05 -5.6148 0.19717E+00 -0.7052 129 H2S,aq 0.10538E+01 0.0228 0.12631E+01 0.1014 0.11986E+01 0.0787 130 S2-2 0.13792E-07 -7.8604 0.42784E-10 -10.3687 0.31020E-02 -2.5084 131 S3-2 0.13211E-08 -8.8791 0.40981E-11 -11.3874 0.31020E-02 -2.5084 132 S3- 0.13657E-01 -1.8647 0.26927E-02 -2.5698 0.19717E+00 -0.7052 133 S4-2 0.10676E-09 -9.9716 0.33116E-12 -12.4800 0.31020E-02 -2.5084 135 SO2,aq 0.29042E+00 -0.5370 0.29042E+00 -0.5370 0.10000E+01 0.0000 136 SO3-2 0.61390E-09 -9.2119 0.30295E-11 -11.5186 0.49348E-02 -2.3067 137 HSO3- 0.31195E-03 -3.5059 0.61509E-04 -4.2111 0.19717E+00 -0.7052 138 HSO4- 0.93626E-02 -2.0286 0.21160E-02 -2.6745 0.22601E+00 -0.6459 140 S2O3-2 0.50964E-06 -6.2927 0.15809E-08 -8.8011 0.31020E-02 -2.5084 141 HS2O3- 0.46758E-06 -6.3301 0.92195E-07 -7.0353 0.19717E+00 -0.7052 142 H2S2O3,aq 0.27870E-07 -7.5549 0.27870E-07 -7.5549 0.10000E+01 0.0000 150 S4O6-2 0.49696E-09 -9.3037 0.15416E-11 -11.8120 0.31020E-02 -2.5084 152 ZnCl+ 0.27332E-03 -3.5633 0.60137E-04 -4.2209 0.22003E+00 -0.6575 153 ZnCl2,aq 0.87801E-03 -3.0565 0.87801E-03 -3.0565 0.10000E+01 0.0000 154 ZnCl3- 0.84041E-04 -4.0755 0.16571E-04 -4.7807 0.19717E+00 -0.7052 155 ZnO,aq 0.34101E-07 -7.4672 0.34101E-07 -7.4672 0.10000E+01 0.0000 156 ZnOH+ 0.16674E-05 -5.7780 0.36687E-06 -6.4355 0.22003E+00 -0.6575 158 HZnO2- 0.27513E-09 -9.5605 0.54248E-10 -10.2656 0.19717E+00 -0.7052 Charge balance for all species = 0.2550E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6624310E-05 0.4297103E+01 0.3538652E+04 0.0000 2 H2O 0.1000000E+01 0.5251264E+02 0.7729166E+06 0.0000 3 Cl- 0.1536460E+00 0.6562861E+00 0.1900962E+05 4.3042 4 SO4-- 0.2066346E-03 0.2522904E+00 0.1980058E+05 5.4864 5 HCO3- 0.1417374E-04 0.2675787E+01 0.1333924E+06 0.3020 6 HS- 0.1291569E-03 0.1160674E+01 0.3136158E+05 1.2324 7 H4SiO4 0.6440267E-01 0.6440607E-01 0.5057631E+04 -1.1911 8 Al+++ 0.1041369E-16 0.1525157E-04 0.3362079E+00 -5.1868 9 Ca++ 0.1619416E-05 0.2225864E-03 0.7288395E+01 3.2850 10 Mg++ 0.1094714E-05 0.1500745E-04 0.2980951E+00 3.0288 11 Fe++ 0.1512145E-07 0.4857950E-02 0.2216564E+03 1.1910 12 K+ 0.4230656E-01 0.1256546E+00 0.4014253E+04 3.7878 13 Na+ 0.1383356E+00 0.5587073E+00 0.1049414E+05 4.2639 14 Mn++ 0.7822021E-06 0.1157875E-02 0.5197110E+02 2.9207 15 Zn++ 0.3717390E-09 0.1237071E-02 0.6606941E+02 -0.4184 16 Cu+ 0.2125256E-07 0.1182305E-03 0.6137676E+01 -2.5508 17 Pb++ 0.3113296E-08 0.3426923E-03 0.5800968E+02 0.6188 18 Ag+ 0.3125487E-09 0.8765290E-05 0.7724925E+00 -4.3506 19 Ba++ 0.1018297E-06 0.1569520E-04 0.1761129E+01 2.1650 20 HPO4-- 0.1060877E-08 0.2888010E-05 0.2264656E+00 0.1991 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265508E+01 -.3146200E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5212653E+02 -.1617518E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2504354E+00 0.1287389E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1152140E+01 0.8004573E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.6393252E-01 0.7966181E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1513943E-04 0.6794001E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2209498E-03 0.3069601E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1489710E-04 0.5779549E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.4822232E-02 0.3944522E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247307E+00 0.6794001E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149362E-02 0.1382498E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1227975E-02 0.1071359E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1173612E-03 0.2822485E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1557980E-04 0.3979265E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2866776E-05 0.5700724E-05 0.0000000E+00 Chg. balance for solid moles: -.3829E-18 Mass of aqueous solution: 0.121498E+04 g Temperature = 573.00 C Pressure = 1280.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.2975E-03 -3.527 0.4050E-01 -1.393 0.7364 0.1367E-01 annite 0.9489E-06 -6.023 0.4857E-03 -3.314 0.8833E-02 0.1464E-03 phlogopite 0.1927E-05 -5.715 0.8039E-03 -3.095 0.1462E-01 0.2882E-03 biotite-Mn 0.4608E-07 -7.336 0.2346E-04 -4.630 0.4267E-03 0.7034E-05 apatite-OH 0.1900E-05 -5.721 0.9545E-03 -3.020 0.1736E-01 0.3033E-03 microcline 0.6765E-03 -3.170 0.1883 -0.725 3.424 0.7355E-01 pyrite 0.3659E-02 -2.437 0.4391 -0.357 7.984 0.8760E-01 quartz 0.7762E-01 -1.110 4.664 0.669 84.81 1.761 barite 0.3979E-04 -4.400 0.9288E-02 -2.032 0.1689 0.2073E-02 chalcopyrite 0.2822E-03 -3.549 0.5179E-01 -1.286 0.9418 0.1209E-01 sphalerite 0.1071E-02 -2.970 0.1044 -0.981 1.898 0.2553E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3248E+00 0.3248E+00 1.0000 -0.488 phlogopite 0.6594E+00 0.6594E+00 1.0000 -0.181 biotite-Mn 0.1577E-01 0.1577E-01 1.0000 -1.802 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.499202 g Volume = 1.976444 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.52 -14.52 0.00 0.000 0.00000E+00 24 annite 0.07 0.07 0.00 0.000 -0.42449E-10 25 phlogopite 4.66 4.66 0.00 0.000 -0.58461E-10 26 biotite-Mn 9.20 9.20 0.00 0.000 -0.27511E-10 30 apatite-OH -52.85 -52.85 0.00 0.000 -0.27511E-10 115 microcline -4.97 -4.97 0.00 0.000 0.00000E+00 140 pyrite -21.48 -21.48 0.00 0.000 0.00000E+00 144 quartz -1.19 -1.19 0.00 0.000 0.00000E+00 237 barite -15.64 -15.64 0.00 0.000 0.68778E-11 240 chalcopyrite -23.11 -23.11 0.00 0.000 0.13756E-10 255 sphalerite -10.83 -10.83 0.00 0.000 0.13756E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.28 -0.276 0.10688E+04 2.831 2 CO2,gas -9.73 -11.34 -1.61 -0.536 0.62300E+04 1.498 3 CH4,gas 6.89 -3.95 -10.85 -2.712 0.42000E+05 -7.740 4 H2,gas 5.90 1.85 -4.05 -2.317 0.15698E+05 -0.947 5 H2S,gas -8.11 -10.41 -2.30 -1.152 0.89191E+04 0.804 6 CO,gas -3.61 -9.49 -5.88 -1.810 0.22773E+05 -2.774 7 SO3,gas -7.29 -17.80 -10.51 -2.628 0.40702E+05 -7.405 8 O2,gas 16.66 -3.70 -20.36 -13.572 0.78823E+05 -17.251 9 HCl,gas -5.98 -7.34 -1.36 -0.679 0.52583E+04 -1.358 10 acmite 3.65 2.15 -1.50 -0.156 0.58089E+04 12 akimotoite 6.02 1.84 -4.18 -0.837 0.16194E+05 13 akimotoite-Fe 3.93 0.00 -3.93 -0.786 0.15222E+05 14 albite-high -4.38 -4.49 -0.11 -0.008 0.42093E+03 15 albite -4.37 -4.49 -0.12 -0.010 0.48066E+03 16 almandine -8.82 -10.37 -1.56 -0.078 0.60307E+04 17 pyrope -2.21 -4.86 -2.65 -0.133 0.10267E+05 18 analcite -2.36 -3.30 -0.95 -0.105 0.36602E+04 19 andalusite -11.14 -11.57 -0.43 -0.043 0.16678E+04 20 andradite 11.43 6.82 -4.62 -0.240 0.17878E+05 21 grossular 0.81 -4.09 -4.90 -0.245 0.18961E+05 27 anorthite -8.85 -9.47 -0.62 -0.048 0.23930E+04 28 anthophyllite 14.02 11.69 -2.34 -0.063 0.90480E+04 29 anthophyllite-Fe 1.45 -1.18 -2.63 -0.071 0.10177E+05 31 apatite-OH-zs -50.70 -52.85 -2.15 -0.165 0.83211E+04 32 apatite-Cl-zs -57.01 -60.19 -3.19 -0.265 0.12332E+05 33 aragonite -4.51 -8.06 -3.54 -1.182 0.13724E+05 34 brucite 5.29 3.03 -2.27 -0.453 0.87700E+04 35 calcite -4.62 -8.06 -3.44 -1.148 0.13331E+05 36 carnegieite-low -0.36 -2.11 -1.75 -0.250 0.67738E+04 37 carnegieite-high -0.29 -2.11 -1.82 -0.261 0.70641E+04 38 carpholite-Mg -7.76 -9.73 -1.97 -0.131 0.76121E+04 39 carpholite-Fe -9.11 -11.57 -2.45 -0.164 0.94999E+04 40 celadonite -1.02 -3.13 -2.11 -0.124 0.81582E+04 41 celadonite-Fe -2.42 -4.97 -2.54 -0.150 0.98466E+04 42 chrysotile 9.17 6.70 -2.47 -0.206 0.95726E+04 44 clinochlore 2.66 1.19 -1.47 -0.046 0.57035E+04 45 daphnite -4.38 -8.00 -3.62 -0.113 0.14035E+05 48 chloritoid-Mg -7.26 -8.54 -1.28 -0.085 0.49617E+04 49 chloritoid-Fe -9.19 -10.38 -1.19 -0.079 0.46130E+04 50 chloritoid-Mn -7.03 -8.65 -1.62 -0.108 0.62598E+04 52 coesite -0.90 -1.19 -0.29 -0.095 0.11065E+04 53 cordierite-H -19.89 -20.64 -0.76 -0.027 0.29246E+04 54 cordierite-Fe -22.44 -24.32 -1.88 -0.065 0.72737E+04 55 cordierite-Mn -18.06 -20.86 -2.80 -0.097 0.10852E+05 56 corundum -9.77 -10.38 -0.60 -0.055 0.23360E+04 58 cristobalite -1.14 -1.19 -0.05 -0.016 0.18222E+03 59 cummingtonite 14.09 11.69 -2.40 -0.065 0.92970E+04 61 cymrite-K -2.69 -4.97 -2.27 -0.190 0.88056E+04 63 diaspore -4.38 -5.19 -0.81 -0.134 0.31182E+04 65 diopside 5.28 3.93 -1.35 -0.135 0.52157E+04 66 hedenbergite 3.87 2.10 -1.77 -0.177 0.68460E+04 68 eastonite -6.82 -8.10 -1.29 -0.049 0.49795E+04 69 enstatite 4.58 3.68 -0.90 -0.090 0.34740E+04 70 clinoenstatite-HiP 5.07 3.68 -1.39 -0.139 0.53770E+04 71 clinoenstatite 4.56 3.68 -0.88 -0.088 0.34167E+04 72 protoenstatite 4.71 3.68 -1.03 -0.103 0.39840E+04 73 epidote -5.02 -7.11 -2.09 -0.101 0.80958E+04 74 clinozoisite -10.06 -12.57 -2.51 -0.114 0.97115E+04 75 epidote-Fe 1.70 -1.66 -3.35 -0.174 0.12981E+05 76 fayalite 2.11 1.19 -0.92 -0.132 0.35651E+04 77 ferrosilite 1.02 0.00 -1.02 -0.102 0.39302E+04 78 forsterite 6.08 4.87 -1.22 -0.174 0.47132E+04 79 gedrite -10.69 -12.75 -2.06 -0.056 0.79732E+04 81 gibbsite -2.77 -5.19 -2.42 -0.346 0.93850E+04 82 glaucophane 0.82 -2.28 -3.10 -0.084 0.11997E+05 83 glaucophane-Fe -3.21 -7.79 -4.58 -0.124 0.17735E+05 84 goethite 1.07 0.26 -0.81 -0.175 0.31349E+04 86 greenalite 4.33 1.19 -3.14 -0.262 0.12163E+05 87 grunerite 2.00 -1.18 -3.18 -0.086 0.12297E+05 88 halite -1.03 -3.08 -2.05 -1.025 0.79385E+04 89 hematite 0.61 0.53 -0.08 -0.010 0.31402E+03 90 heulandite -12.45 -15.42 -2.97 -0.135 0.11489E+05 91 hercynite -8.15 -9.19 -1.04 -0.069 0.40203E+04 94 jadeite -1.68 -3.30 -1.63 -0.163 0.62979E+04 96 kalsilite -0.99 -2.59 -1.60 -0.229 0.62068E+04 97 kaolinite -10.08 -12.76 -2.68 -0.244 0.10380E+05 98 kyanite -10.98 -11.57 -0.59 -0.059 0.22850E+04 100 laumontite -8.36 -11.85 -3.49 -0.233 0.13511E+05 101 lawsonite -6.09 -9.47 -3.38 -0.226 0.13104E+05 102 leucite -2.83 -3.78 -0.94 -0.094 0.36579E+04 104 lizardite 9.35 6.70 -2.65 -0.221 0.10267E+05 105 magnesite -5.42 -8.31 -2.89 -0.964 0.11196E+05 106 magnetite 1.72 1.72 0.00 0.000 0.35435E+00 107 minnesotaite 0.70 -1.19 -1.88 -0.111 0.72924E+04 108 minnesotaite-Mg 6.64 4.33 -2.31 -0.136 0.89322E+04 109 magnesioferrite 4.77 3.56 -1.21 -0.099 0.46980E+04 111 manganosite 5.27 2.92 -2.35 -0.589 0.91177E+04 112 margarite -18.15 -19.85 -1.70 -0.068 0.65694E+04 116 monticellite 8.62 5.12 -3.49 -0.499 0.13527E+05 118 mullite-Si -10.40 -11.57 -1.17 -0.117 0.45278E+04 119 muscovite -14.60 -15.35 -0.74 -0.044 0.28682E+04 120 paragonite -13.93 -14.87 -0.94 -0.056 0.36563E+04 121 nepheline -0.66 -2.11 -1.45 -0.208 0.56330E+04 122 osumilite(2) -13.82 -15.77 -1.94 -0.040 0.75224E+04 123 osumilite-Fe -29.41 -31.66 -2.25 -0.047 0.87175E+04 124 pargasite 4.13 0.24 -3.88 -0.102 0.15038E+05 125 periclase 5.48 3.03 -2.45 -0.613 0.94861E+04 126 periclase-Fe 2.91 1.19 -1.72 -0.431 0.66761E+04 127 perovskite-Al -8.06 -10.38 -2.32 -0.211 0.89948E+04 132 phlogopite-Na 5.52 4.59 -0.93 -0.052 0.36080E+04 134 prehnite -4.19 -7.38 -3.19 -0.187 0.12341E+05 135 prehnite-Fe 1.24 -1.92 -3.16 -0.190 0.12240E+05 138 px-Mg-tschermaks -6.68 -8.54 -1.86 -0.133 0.72069E+04 139 px-Ca-tschermaks -5.79 -8.28 -2.50 -0.178 0.96617E+04 141 pyrrhotite -8.60 -9.22 -0.62 -0.207 0.24084E+04 142 pyrrhotiteFe0.875 -9.35 -9.60 -0.25 -0.091 0.95938E+03 143 pyrophyllite -13.83 -15.13 -1.30 -0.082 0.50527E+04 146 riebeckite 5.77 3.12 -2.65 -0.073 0.10247E+05 147 ringwoodite-Fe 3.10 1.19 -1.91 -0.273 0.74070E+04 148 ringwoodite-Mg 9.22 4.87 -4.35 -0.622 0.16845E+05 149 rhodochrosite -5.36 -8.42 -3.06 -1.021 0.11858E+05 150 rhodonite 2.47 1.73 -0.74 -0.148 0.28670E+04 151 sanidine -4.43 -4.97 -0.53 -0.041 0.20685E+04 153 siderite -7.25 -10.15 -2.91 -0.968 0.11250E+05 154 sillimanite -11.10 -11.57 -0.46 -0.046 0.17990E+04 156 spinel -5.99 -7.35 -1.36 -0.091 0.52636E+04 162 stilpnomelane-Fe -7.45 -12.05 -4.60 -0.137 0.17801E+05 163 stilpnomelane-Mg -0.70 -2.86 -2.16 -0.065 0.83720E+04 164 stishovite 1.75 -1.19 -2.93 -0.978 0.11358E+05 165 sudoite-Fe -17.94 -21.95 -4.00 -0.129 0.15504E+05 166 sudoite -15.73 -18.27 -2.54 -0.082 0.98342E+04 167 sulfur -10.76 -12.26 -1.50 -0.462 0.58077E+04 168 sylvite -0.93 -3.55 -2.62 -1.311 0.10149E+05 169 talc 4.92 4.33 -0.59 -0.035 0.22791E+04 170 talc-Fe 2.09 -1.19 -3.27 -0.193 0.12672E+05 171 talc-tschermaks -6.26 -7.89 -1.63 -0.096 0.63045E+04 173 tephroite 6.40 4.65 -1.75 -0.250 0.67833E+04 176 topaz-H -9.05 -11.57 -2.52 -0.229 0.97650E+04 177 tremolite 14.84 12.20 -2.64 -0.071 0.10239E+05 179 troilite-low -8.51 -9.22 -0.72 -0.239 0.27715E+04 180 tschermakite -9.10 -12.24 -3.14 -0.085 0.12161E+05 183 wadsleyite-Fe 2.95 1.19 -1.76 -0.252 0.68269E+04 184 wadsleyite-Mg 8.28 4.87 -3.41 -0.488 0.13216E+05 185 wairakite -10.21 -11.85 -1.64 -0.096 0.63390E+04 186 walstromite 4.57 2.10 -2.47 -0.494 0.95718E+04 187 wollastonite 4.15 2.10 -2.06 -0.411 0.79623E+04 188 pseudo-wollastonite 4.27 2.10 -2.17 -0.434 0.84054E+04 189 zoisite -10.11 -12.57 -2.45 -0.112 0.94984E+04 192 beidellite-Ca -14.28 -15.91 -1.63 -0.101 0.62975E+04 193 beidellite-H -14.30 -16.45 -2.15 -0.137 0.83409E+04 194 beidellite-K -13.25 -15.20 -1.96 -0.120 0.75737E+04 195 beidellite-Mg -14.56 -15.95 -1.40 -0.086 0.54024E+04 196 beidellite-Na -13.19 -15.05 -1.86 -0.114 0.71939E+04 197 bornite -53.68 -54.14 -0.46 -0.034 0.17669E+04 199 chalcocite -13.98 -15.51 -1.53 -0.383 0.59367E+04 200 covellite -12.47 -13.89 -1.42 -0.540 0.54876E+04 202 montmorillonite-Ca -10.65 -11.88 -1.23 -0.076 0.47661E+04 203 montmorillonite-K -9.90 -11.17 -1.27 -0.078 0.49339E+04 204 montmorillonite-Mg -10.87 -11.92 -1.05 -0.065 0.40537E+04 205 montmorillonite-Na -9.55 -11.01 -1.46 -0.090 0.56657E+04 206 nontronite-Ca -3.65 -5.00 -1.35 -0.088 0.52427E+04 207 nontronite-H -3.67 -5.54 -1.87 -0.126 0.72586E+04 208 nontronite-K -2.61 -4.29 -1.68 -0.108 0.65105E+04 209 nontronite-Mg -3.88 -5.04 -1.16 -0.075 0.45054E+04 210 nontronite-Na -2.55 -4.14 -1.59 -0.102 0.61436E+04 215 gypsum -12.30 -14.52 -2.22 -0.555 0.85993E+04 232 alabandite -6.32 -7.49 -1.17 -0.390 0.45245E+04 234 anglesite -14.74 -17.19 -2.44 -1.222 0.94650E+04 238 boehmite -4.10 -5.19 -1.09 -0.182 0.42255E+04 242 copper,native 1.75 -1.63 -3.38 -1.175 0.13084E+05 244 ferrous-oxide 1.99 1.19 -0.80 -0.201 0.31098E+04 245 galena -9.65 -9.79 -0.15 -0.049 0.57106E+03 246 silver,native 0.50 -3.43 -3.93 -1.366 0.15206E+05 248 litharge 5.26 0.62 -4.64 -1.160 0.17965E+05 256 wurtzite -10.03 -10.83 -0.80 -0.266 0.30890E+04 257 zincite 2.10 -0.42 -2.52 -0.630 0.97566E+04 258 an20ab80 -5.48 -5.49 -0.01 0.000 0.21839E+02 259 an25ab75 -5.73 -5.74 0.00 0.000 0.12738E+02 260 an30ab70 -5.98 -5.98 -0.01 -0.001 0.28013E+02 261 tr.625ac.25prg.125 9.33 8.41 -0.92 -0.025 0.35752E+04 Calculations done for 573.0000 Deg. C; 1280.0000 bar Temperature changed by -1.000 degrees to 572.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 32 Loop limit = 500 Temperature = 572.00 C Pressure = 1258.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5510E+02 kg liquid = 0.9927E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9964 Stoichiometric ionic strength = .3285052E+01 Osmotic coef. = 0.0000 True ionic strength = .1782021E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.63183E-05 -5.1994 0.14207E-05 -5.8475 0.22485E+00 -0.6481 2 H2O 0.99644E+00 -0.0015 0.99644E+00 -0.0015 3 Cl- 0.15003E+00 -0.8238 0.29239E-01 -1.5340 0.19489E+00 -0.7102 4 SO4-- 0.20889E-03 -3.6801 0.67305E-06 -6.1720 0.32221E-02 -2.4919 5 HCO3- 0.13564E-04 -4.8676 0.28502E-05 -5.5451 0.21013E+00 -0.6775 6 HS- 0.12784E-03 -3.8933 0.25123E-04 -4.5999 0.19653E+00 -0.7066 7 H4SiO4 0.62731E-01 -1.2025 0.62731E-01 -1.2025 0.10000E+01 0.0000 8 Al+++ 0.10688E-16 -16.9711 0.20761E-22 -22.6827 0.19426E-05 -5.7116 9 Ca++ 0.15525E-05 -5.8090 0.40151E-08 -8.3963 0.25862E-02 -2.5873 10 Mg++ 0.10820E-05 -5.9658 0.22957E-08 -8.6391 0.21218E-02 -2.6733 11 Fe++ 0.14702E-07 -7.8326 0.32803E-10 -10.4841 0.22312E-02 -2.6515 12 K+ 0.41419E-01 -1.3828 0.89238E-02 -2.0495 0.21545E+00 -0.6667 13 Na+ 0.13497E+00 -0.8698 0.26626E-01 -1.5747 0.19727E+00 -0.7049 14 Mn++ 0.80935E-06 -6.0919 0.18732E-08 -8.7274 0.23145E-02 -2.6355 15 Zn++ 0.36004E-09 -9.4436 0.80332E-12 -12.0951 0.22312E-02 -2.6515 16 Cu+ 0.20048E-07 -7.6979 0.39441E-08 -8.4041 0.19674E+00 -0.7061 17 Pb++ 0.30329E-08 -8.5181 0.87964E-11 -11.0557 0.29004E-02 -2.5375 18 Ag+ 0.31013E-09 -9.5085 0.65760E-10 -10.1820 0.21204E+00 -0.6736 19 Ba++ 0.95765E-07 -7.0188 0.29861E-09 -9.5249 0.31181E-02 -2.5061 20 HPO4-- 0.10760E-08 -8.9682 0.34846E-11 -11.4578 0.32385E-02 -2.4897 21 HSiO3- 0.16469E-05 -5.7833 0.32097E-06 -6.4935 0.19489E+00 -0.7102 22 Ca(HSiO3)+ 0.68358E-08 -8.1652 0.14859E-08 -8.8280 0.21737E+00 -0.6628 23 Mg(HSiO3)+ 0.11474E-08 -8.9403 0.24942E-09 -9.6031 0.21737E+00 -0.6628 24 NaHSiO3,aq 0.17497E-05 -5.7570 0.17497E-05 -5.7570 0.10000E+01 0.0000 28 AgCl,aq 0.92973E-07 -7.0316 0.92973E-07 -7.0316 0.10000E+01 0.0000 29 AgCl2- 0.50852E-05 -5.2937 0.99103E-06 -6.0039 0.19489E+00 -0.7102 30 AgCl3-2 0.20046E-05 -5.6980 0.59747E-08 -8.2237 0.29804E-02 -2.5257 31 AgCl4-3 0.15750E-05 -5.8027 0.26521E-11 -11.5764 0.16838E-05 -5.7737 34 Ag(HS),aq 0.12021E-08 -8.9201 0.12021E-08 -8.9201 0.10000E+01 0.0000 35 Ag(HS)2- 0.55253E-08 -8.2576 0.10768E-08 -8.9679 0.19489E+00 -0.7102 38 HAlO2,aq 0.42507E-08 -8.3715 0.42507E-08 -8.3715 0.10000E+01 0.0000 39 AlO2- 0.14782E-04 -4.8303 0.25196E-05 -5.5987 0.17045E+00 -0.7684 41 Ba(HCO3)+ 0.38065E-06 -6.4195 0.86131E-07 -7.0648 0.22627E+00 -0.6454 42 BaCl+ 0.14140E-04 -4.8496 0.30736E-05 -5.5124 0.21737E+00 -0.6628 43 CH4,aq 0.17076E-08 -8.7676 0.20445E-08 -8.6894 0.11973E+01 0.0782 48 CO,aq 0.62343E-03 -3.2052 0.62343E-03 -3.2052 0.10000E+01 0.0000 49 CO2,aq 0.26750E+01 0.4273 0.32028E+01 0.5055 0.11973E+01 0.0782 50 CO3-2 0.42067E-10 -10.3761 0.12538E-12 -12.9018 0.29804E-02 -2.5257 51 CaCO3,aq 0.12376E-10 -10.9074 0.12376E-10 -10.9074 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.19459E-06 -6.7109 0.42299E-07 -7.3737 0.21737E+00 -0.6628 53 CaCl+ 0.11247E-03 -3.9490 0.24447E-04 -4.6118 0.21737E+00 -0.6628 54 CaCl2,aq 0.97808E-04 -4.0096 0.97808E-04 -4.0096 0.10000E+01 0.0000 55 CaOH+ 0.20671E-06 -6.6846 0.44933E-07 -7.3474 0.21737E+00 -0.6628 56 CaSO4,aq 0.15045E-06 -6.8226 0.15045E-06 -6.8226 0.10000E+01 0.0000 57 HCl,aq 0.21583E-02 -2.6659 0.21583E-02 -2.6659 0.10000E+01 0.0000 66 CuCl,aq 0.24224E-04 -4.6157 0.24224E-04 -4.6157 0.10000E+01 0.0000 67 CuCl2- 0.88295E-04 -4.0541 0.17208E-04 -4.7643 0.19489E+00 -0.7102 68 CuCl3-2 0.18655E-05 -5.7292 0.55599E-08 -8.2549 0.29804E-02 -2.5257 74 FeCl+ 0.32983E-06 -6.4817 0.71695E-07 -7.1445 0.21737E+00 -0.6628 75 FeCl2,aq 0.46251E-02 -2.3349 0.46251E-02 -2.3349 0.10000E+01 0.0000 77 FeO,aq 0.73809E-07 -7.1319 0.73809E-07 -7.1319 0.10000E+01 0.0000 78 FeOH+ 0.27327E-07 -7.5634 0.59401E-08 -8.2262 0.21737E+00 -0.6628 79 HFeO2- 0.91835E-08 -8.0370 0.17897E-08 -8.7472 0.19489E+00 -0.7102 82 FeO2- 0.58281E-08 -8.2345 0.11358E-08 -8.9447 0.19489E+00 -0.7102 83 HFeO2,aq 0.28987E-09 -9.5378 0.28987E-09 -9.5378 0.10000E+01 0.0000 84 H2,aq 0.47053E-02 -2.3274 0.56337E-02 -2.2492 0.11973E+01 0.0782 85 KCl,aq 0.66647E-01 -1.1762 0.66647E-01 -1.1762 0.10000E+01 0.0000 86 KHSO4,aq 0.13212E-01 -1.8790 0.13212E-01 -1.8790 0.10000E+01 0.0000 87 KOH,aq 0.12458E-05 -5.9046 0.12458E-05 -5.9046 0.10000E+01 0.0000 88 KSO4- 0.43689E-02 -2.3596 0.85145E-03 -3.0698 0.19489E+00 -0.7102 90 Mg(HCO3)+ 0.40909E-07 -7.3882 0.88925E-08 -8.0510 0.21737E+00 -0.6628 91 MgCl+ 0.13066E-04 -4.8839 0.28401E-05 -5.5467 0.21737E+00 -0.6628 92 MgOH+ 0.49804E-06 -6.3027 0.10826E-06 -6.9655 0.21737E+00 -0.6628 94 MnO,aq 0.68099E-07 -7.1669 0.68099E-07 -7.1669 0.10000E+01 0.0000 95 MnOH+ 0.18093E-06 -6.7425 0.39328E-07 -7.4053 0.21737E+00 -0.6628 97 HMnO2- 0.36019E-10 -10.4435 0.70196E-11 -11.1537 0.19489E+00 -0.7102 100 MnCl+ 0.11567E-02 -2.9368 0.25143E-03 -3.5996 0.21737E+00 -0.6628 101 MnSO4,aq 0.81508E-07 -7.0888 0.81508E-07 -7.0888 0.10000E+01 0.0000 102 NaCl,aq 0.42370E+00 -0.3729 0.42370E+00 -0.3729 0.10000E+01 0.0000 103 NaOH,aq 0.17132E-05 -5.7662 0.17132E-05 -5.7662 0.10000E+01 0.0000 105 OH- 0.81949E-05 -5.0865 0.13968E-05 -5.8549 0.17045E+00 -0.7684 110 HPO3-2 0.11176E-10 -10.9517 0.33309E-13 -13.4774 0.29804E-02 -2.5257 111 H3PO3,aq 0.10613E-09 -9.9741 0.10613E-09 -9.9741 0.10000E+01 0.0000 112 H2PO3- 0.25712E-08 -8.5899 0.50109E-09 -9.3001 0.19489E+00 -0.7102 113 H3PO4,aq 0.99705E-06 -6.0013 0.99705E-06 -6.0013 0.10000E+01 0.0000 114 H2PO4- 0.13872E-05 -5.8578 0.28441E-06 -6.5461 0.20502E+00 -0.6882 116 H4P2O7,aq 0.90094E-10 -10.0453 0.90094E-10 -10.0453 0.10000E+01 0.0000 117 H3P2O7- 0.81911E-09 -9.0867 0.15963E-09 -9.7969 0.19489E+00 -0.7102 118 H2P2O7-2 0.22065E-06 -6.6563 0.65764E-09 -9.1820 0.29804E-02 -2.5257 119 HP2O7-3 0.16534E-07 -7.7816 0.27840E-13 -13.5553 0.16838E-05 -5.7737 121 PbCl+ 0.15607E-05 -5.8067 0.33925E-06 -6.4695 0.21737E+00 -0.6628 122 PbCl2,aq 0.86342E-04 -4.0638 0.86342E-04 -4.0638 0.10000E+01 0.0000 123 PbCl3- 0.10506E-03 -3.9786 0.20474E-04 -4.6888 0.19489E+00 -0.7102 124 PbCl4-2 0.21222E-04 -4.6732 0.63250E-07 -7.1989 0.29804E-02 -2.5257 125 PbO,aq 0.56298E-08 -8.2495 0.56298E-08 -8.2495 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11590E-03 -3.9359 0.11590E-03 -3.9359 0.10000E+01 0.0000 128 Pb(HS)3- 0.12584E-04 -4.9002 0.24525E-05 -5.6104 0.19489E+00 -0.7102 129 H2S,aq 0.10544E+01 0.0230 0.12625E+01 0.1012 0.11973E+01 0.0782 130 S2-2 0.13626E-07 -7.8656 0.40612E-10 -10.3913 0.29804E-02 -2.5257 131 S3-2 0.12919E-08 -8.8888 0.38506E-11 -11.4145 0.29804E-02 -2.5257 132 S3- 0.13147E-01 -1.8812 0.25621E-02 -2.5914 0.19489E+00 -0.7102 133 S4-2 0.10346E-09 -9.9852 0.30836E-12 -12.5109 0.29804E-02 -2.5257 135 SO2,aq 0.29084E+00 -0.5363 0.29084E+00 -0.5363 0.10000E+01 0.0000 136 SO3-2 0.61722E-09 -9.2096 0.29251E-11 -11.5339 0.47391E-02 -2.3243 137 HSO3- 0.30370E-03 -3.5176 0.59186E-04 -4.2278 0.19489E+00 -0.7102 138 HSO4- 0.91756E-02 -2.0374 0.20488E-02 -2.6885 0.22328E+00 -0.6511 140 S2O3-2 0.50552E-06 -6.2963 0.15067E-08 -8.8220 0.29804E-02 -2.5257 141 HS2O3- 0.45208E-06 -6.3448 0.88105E-07 -7.0550 0.19489E+00 -0.7102 142 H2S2O3,aq 0.28157E-07 -7.5504 0.28157E-07 -7.5504 0.10000E+01 0.0000 150 S4O6-2 0.47963E-09 -9.3191 0.14295E-11 -11.8448 0.29804E-02 -2.5257 152 ZnCl+ 0.25336E-03 -3.5963 0.55073E-04 -4.2591 0.21737E+00 -0.6628 153 ZnCl2,aq 0.84045E-03 -3.0755 0.84045E-03 -3.0755 0.10000E+01 0.0000 154 ZnCl3- 0.77763E-04 -4.1092 0.15155E-04 -4.8194 0.19489E+00 -0.7102 155 ZnO,aq 0.33699E-07 -7.4724 0.33699E-07 -7.4724 0.10000E+01 0.0000 156 ZnOH+ 0.15753E-05 -5.8026 0.34243E-06 -6.4654 0.21737E+00 -0.6628 158 HZnO2- 0.27173E-09 -9.5659 0.52957E-10 -10.2761 0.19489E+00 -0.7102 Charge balance for all species = 0.2549E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6318334E-05 0.4296907E+01 0.3539056E+04 0.0000 2 H2O 0.1000000E+01 0.5251364E+02 0.7730552E+06 0.0000 3 Cl- 0.1500318E+00 0.6562541E+00 0.1901174E+05 4.3135 4 SO4-- 0.2088857E-03 0.2522093E+00 0.1979738E+05 5.5231 5 HCO3- 0.1356414E-04 0.2675657E+01 0.1334073E+06 0.3024 6 HS- 0.1278359E-03 0.1160147E+01 0.3135236E+05 1.2476 7 H4SiO4 0.6273084E-01 0.6273424E-01 0.4927135E+04 -1.2025 8 Al+++ 0.1068752E-16 0.1478625E-04 0.3260025E+00 -5.1402 9 Ca++ 0.1552526E-05 0.2123871E-03 0.6955542E+01 3.2987 10 Mg++ 0.1081960E-05 0.1468783E-04 0.2917932E+00 3.0559 11 Fe++ 0.1470213E-07 0.4625553E-02 0.2110864E+03 1.2109 12 K+ 0.4141922E-01 0.1256480E+00 0.4014685E+04 3.7981 13 Na+ 0.1349729E+00 0.5586801E+00 0.1049531E+05 4.2728 14 Mn++ 0.8093450E-06 0.1157803E-02 0.5197617E+02 2.9676 15 Zn++ 0.3600433E-09 0.1173177E-02 0.6266701E+02 -0.4001 16 Cu+ 0.2004750E-07 0.1144053E-03 0.5940051E+01 -2.5565 17 Pb++ 0.3032852E-08 0.3426756E-03 0.5801614E+02 0.6393 18 Ag+ 0.3101253E-09 0.8764863E-05 0.7725785E+00 -4.3345 19 Ba++ 0.9576526E-07 0.1461618E-04 0.1640317E+01 2.1701 20 HPO4-- 0.1076020E-08 0.2864242E-05 0.2246378E+00 0.2372 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265521E+01 -.3159065E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5213007E+02 -.1652917E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2503671E+00 0.1355643E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1151673E+01 0.8471488E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.6227601E-01 0.8131831E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1467825E-04 0.6798613E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2108357E-03 0.3170741E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1458054E-04 0.6096107E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.4591767E-02 0.4174987E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247303E+00 0.6798613E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149346E-02 0.1541211E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1164608E-02 0.1134727E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1135696E-03 0.2860401E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1450942E-04 0.4086303E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2843321E-05 0.5724179E-05 0.0000000E+00 Chg. balance for solid moles: -.4472E-18 Mass of aqueous solution: 0.121484E+04 g Temperature = 572.00 C Pressure = 1258.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3075E-03 -3.512 0.4187E-01 -1.378 0.7431 0.1413E-01 annite 0.9944E-06 -6.002 0.5090E-03 -3.293 0.9034E-02 0.1535E-03 phlogopite 0.2032E-05 -5.692 0.8479E-03 -3.072 0.1505E-01 0.3040E-03 biotite-Mn 0.5137E-07 -7.289 0.2616E-04 -4.582 0.4642E-03 0.7841E-05 apatite-OH 0.1908E-05 -5.719 0.9585E-03 -3.018 0.1701E-01 0.3046E-03 microcline 0.6768E-03 -3.170 0.1884 -0.725 3.343 0.7358E-01 pyrite 0.3886E-02 -2.411 0.4662 -0.331 8.275 0.9302E-01 quartz 0.7928E-01 -1.101 4.763 0.678 84.53 1.799 barite 0.4086E-04 -4.389 0.9537E-02 -2.021 0.1693 0.2129E-02 chalcopyrite 0.2860E-03 -3.544 0.5249E-01 -1.280 0.9316 0.1225E-01 sphalerite 0.1135E-02 -2.945 0.1106 -0.956 1.962 0.2704E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3231E+00 0.3231E+00 1.0000 -0.491 phlogopite 0.6602E+00 0.6602E+00 1.0000 -0.180 biotite-Mn 0.1669E-01 0.1669E-01 1.0000 -1.777 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.634471 g Volume = 2.021668 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.57 -14.57 0.00 0.000 0.00000E+00 24 annite 0.16 0.16 0.00 0.000 0.12129E-10 25 phlogopite 4.76 4.76 0.00 0.000 0.68696E-11 26 biotite-Mn 9.29 9.29 0.00 0.000 0.00000E+00 30 apatite-OH -52.97 -52.97 0.00 0.000 0.00000E+00 115 microcline -4.94 -4.94 0.00 0.000 -0.13739E-10 140 pyrite -21.54 -21.54 0.00 0.000 0.00000E+00 144 quartz -1.20 -1.20 0.00 0.000 0.00000E+00 237 barite -15.70 -15.70 0.00 0.000 0.00000E+00 240 chalcopyrite -23.17 -23.17 0.00 0.000 0.00000E+00 255 sphalerite -10.85 -10.85 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.27 -0.275 0.10629E+04 2.825 2 CO2,gas -9.77 -11.39 -1.62 -0.540 0.62644E+04 1.480 3 CH4,gas 6.89 -3.97 -10.86 -2.716 0.42018E+05 -7.765 4 H2,gas 5.91 1.85 -4.06 -2.317 0.15683E+05 -0.956 5 H2S,gas -8.14 -10.45 -2.31 -1.153 0.89184E+04 0.794 6 CO,gas -3.64 -9.54 -5.90 -1.814 0.22805E+05 -2.797 7 SO3,gas -7.34 -17.87 -10.53 -2.632 0.40713E+05 -7.428 8 O2,gas 16.67 -3.71 -20.38 -13.588 0.78825E+05 -17.283 9 HCl,gas -6.01 -7.38 -1.38 -0.688 0.53215E+04 -1.376 10 acmite 3.65 2.16 -1.49 -0.155 0.57751E+04 12 akimotoite 6.04 1.85 -4.19 -0.837 0.16193E+05 13 akimotoite-Fe 3.95 0.01 -3.94 -0.788 0.15230E+05 14 albite-high -4.36 -4.47 -0.11 -0.009 0.43303E+03 15 albite -4.34 -4.47 -0.13 -0.010 0.48900E+03 16 almandine -8.66 -10.26 -1.59 -0.080 0.61571E+04 17 pyrope -2.04 -4.72 -2.68 -0.134 0.10368E+05 18 analcite -2.32 -3.27 -0.95 -0.106 0.36731E+04 19 andalusite -11.03 -11.48 -0.46 -0.046 0.17647E+04 20 andradite 11.48 6.86 -4.63 -0.240 0.17894E+05 21 grossular 0.94 -3.99 -4.93 -0.247 0.19067E+05 27 anorthite -8.74 -9.39 -0.64 -0.050 0.24932E+04 28 anthophyllite 14.12 11.78 -2.33 -0.063 0.90284E+04 29 anthophyllite-Fe 1.51 -1.13 -2.64 -0.071 0.10215E+05 31 apatite-OH-zs -50.81 -52.97 -2.15 -0.166 0.83236E+04 32 apatite-Cl-zs -57.15 -60.35 -3.19 -0.266 0.12356E+05 33 aragonite -4.54 -8.09 -3.56 -1.186 0.13759E+05 34 brucite 5.32 3.05 -2.27 -0.453 0.87656E+04 35 calcite -4.64 -8.09 -3.46 -1.152 0.13364E+05 36 carnegieite-low -0.32 -2.07 -1.75 -0.251 0.67820E+04 37 carnegieite-high -0.24 -2.07 -1.83 -0.261 0.70744E+04 38 carpholite-Mg -7.64 -9.63 -1.99 -0.133 0.77014E+04 39 carpholite-Fe -9.00 -11.48 -2.48 -0.165 0.95991E+04 40 celadonite -0.98 -3.09 -2.11 -0.124 0.81574E+04 41 celadonite-Fe -2.39 -4.94 -2.55 -0.150 0.98575E+04 42 chrysotile 9.23 6.76 -2.47 -0.206 0.95557E+04 44 clinochlore 2.87 1.38 -1.49 -0.047 0.57662E+04 45 daphnite -4.18 -7.84 -3.66 -0.114 0.14148E+05 48 chloritoid-Mg -7.13 -8.43 -1.31 -0.087 0.50523E+04 49 chloritoid-Fe -9.06 -10.28 -1.22 -0.081 0.47102E+04 50 chloritoid-Mn -6.90 -8.52 -1.62 -0.108 0.62466E+04 52 coesite -0.91 -1.20 -0.29 -0.095 0.11073E+04 53 cordierite-H -19.65 -20.46 -0.81 -0.029 0.31148E+04 54 cordierite-Fe -22.22 -24.15 -1.93 -0.067 0.74681E+04 55 cordierite-Mn -17.84 -20.64 -2.80 -0.097 0.10825E+05 56 corundum -9.66 -10.29 -0.63 -0.057 0.24342E+04 58 cristobalite -1.15 -1.20 -0.05 -0.016 0.18111E+03 59 cummingtonite 14.18 11.78 -2.40 -0.065 0.92788E+04 61 cymrite-K -2.67 -4.95 -2.28 -0.190 0.88157E+04 63 diaspore -4.33 -5.14 -0.82 -0.136 0.31639E+04 65 diopside 5.30 3.95 -1.35 -0.135 0.52181E+04 66 hedenbergite 3.88 2.11 -1.77 -0.177 0.68582E+04 68 eastonite -6.61 -7.92 -1.31 -0.050 0.50700E+04 69 enstatite 4.61 3.71 -0.90 -0.090 0.34708E+04 70 clinoenstatite-HiP 5.10 3.71 -1.39 -0.139 0.53746E+04 71 clinoenstatite 4.59 3.71 -0.88 -0.088 0.34128E+04 72 protoenstatite 4.74 3.71 -1.03 -0.103 0.39808E+04 73 epidote -4.89 -7.01 -2.12 -0.103 0.82041E+04 74 clinozoisite -9.88 -12.43 -2.55 -0.116 0.98659E+04 75 epidote-Fe 1.79 -1.58 -3.37 -0.175 0.13040E+05 76 fayalite 2.14 1.22 -0.93 -0.132 0.35786E+04 77 ferrosilite 1.04 0.02 -1.02 -0.102 0.39446E+04 78 forsterite 6.13 4.91 -1.22 -0.174 0.47082E+04 79 gedrite -10.39 -12.50 -2.11 -0.057 0.81543E+04 81 gibbsite -2.71 -5.14 -2.44 -0.348 0.94297E+04 82 glaucophane 0.93 -2.17 -3.10 -0.084 0.12000E+05 83 glaucophane-Fe -3.12 -7.71 -4.59 -0.124 0.17766E+05 84 goethite 1.09 0.28 -0.81 -0.175 0.31367E+04 86 greenalite 4.37 1.23 -3.15 -0.262 0.12171E+05 87 grunerite 2.06 -1.13 -3.19 -0.086 0.12338E+05 88 halite -1.06 -3.11 -2.05 -1.024 0.79212E+04 89 hematite 0.65 0.56 -0.08 -0.010 0.31816E+03 90 heulandite -12.39 -15.39 -3.00 -0.136 0.11606E+05 91 hercynite -8.01 -9.08 -1.07 -0.071 0.41250E+04 94 jadeite -1.64 -3.27 -1.63 -0.163 0.63079E+04 96 kalsilite -0.94 -2.54 -1.61 -0.229 0.62103E+04 97 kaolinite -9.98 -12.69 -2.71 -0.246 0.10462E+05 98 kyanite -10.87 -11.48 -0.62 -0.062 0.23834E+04 100 laumontite -8.27 -11.79 -3.52 -0.235 0.13612E+05 101 lawsonite -5.98 -9.39 -3.41 -0.228 0.13203E+05 102 leucite -2.80 -3.74 -0.95 -0.095 0.36620E+04 104 lizardite 9.41 6.76 -2.65 -0.221 0.10246E+05 105 magnesite -5.43 -8.34 -2.90 -0.967 0.11222E+05 106 magnetite 1.78 1.77 0.00 0.000 0.10885E+02 107 minnesotaite 0.72 -1.17 -1.89 -0.111 0.73022E+04 108 minnesotaite-Mg 6.67 4.36 -2.31 -0.136 0.89144E+04 109 magnesioferrite 4.83 3.62 -1.22 -0.099 0.46998E+04 111 manganosite 5.30 2.97 -2.33 -0.583 0.90133E+04 112 margarite -17.92 -19.67 -1.75 -0.070 0.67651E+04 116 monticellite 8.65 5.15 -3.50 -0.500 0.13527E+05 118 mullite-Si -10.29 -11.48 -1.20 -0.120 0.46273E+04 119 muscovite -14.46 -15.23 -0.77 -0.045 0.29670E+04 120 paragonite -13.78 -14.76 -0.97 -0.057 0.37615E+04 121 nepheline -0.61 -2.07 -1.46 -0.208 0.56407E+04 122 osumilite(2) -13.69 -15.66 -1.97 -0.041 0.76088E+04 123 osumilite-Fe -29.18 -31.49 -2.31 -0.048 0.89206E+04 124 pargasite 4.38 0.46 -3.92 -0.103 0.15152E+05 125 periclase 5.51 3.05 -2.45 -0.613 0.94831E+04 126 periclase-Fe 2.94 1.21 -1.73 -0.432 0.66837E+04 127 perovskite-Al -7.93 -10.29 -2.35 -0.214 0.90932E+04 132 phlogopite-Na 5.63 4.69 -0.93 -0.052 0.36059E+04 134 prehnite -4.07 -7.29 -3.22 -0.189 0.12443E+05 135 prehnite-Fe 1.31 -1.87 -3.18 -0.191 0.12294E+05 138 px-Mg-tschermaks -6.54 -8.43 -1.89 -0.135 0.73045E+04 139 px-Ca-tschermaks -5.66 -8.19 -2.52 -0.180 0.97644E+04 141 pyrrhotite -8.61 -9.24 -0.62 -0.208 0.24148E+04 142 pyrrhotiteFe0.875 -9.37 -9.62 -0.25 -0.092 0.96528E+03 143 pyrophyllite -13.75 -15.08 -1.33 -0.083 0.51462E+04 146 riebeckite 5.77 3.14 -2.63 -0.073 0.10190E+05 147 ringwoodite-Fe 3.14 1.22 -1.92 -0.274 0.74193E+04 148 ringwoodite-Mg 9.26 4.91 -4.35 -0.622 0.16840E+05 149 rhodochrosite -5.38 -8.43 -3.05 -1.016 0.11782E+05 150 rhodonite 2.48 1.77 -0.71 -0.143 0.27632E+04 151 sanidine -4.41 -4.94 -0.53 -0.041 0.20685E+04 153 siderite -7.26 -10.18 -2.92 -0.973 0.11284E+05 154 sillimanite -10.99 -11.48 -0.49 -0.049 0.18970E+04 156 spinel -5.85 -7.23 -1.39 -0.092 0.53579E+04 162 stilpnomelane-Fe -7.32 -11.94 -4.63 -0.138 0.17897E+05 163 stilpnomelane-Mg -0.54 -2.72 -2.18 -0.065 0.84370E+04 164 stishovite 1.74 -1.20 -2.94 -0.979 0.11358E+05 165 sudoite-Fe -17.69 -21.76 -4.07 -0.131 0.15721E+05 166 sudoite -15.47 -18.07 -2.59 -0.084 0.10031E+05 167 sulfur -10.80 -12.30 -1.50 -0.462 0.58085E+04 168 sylvite -0.97 -3.58 -2.62 -1.309 0.10123E+05 169 talc 4.95 4.36 -0.59 -0.034 0.22634E+04 170 talc-Fe 2.11 -1.17 -3.28 -0.193 0.12684E+05 171 talc-tschermaks -6.12 -7.78 -1.65 -0.097 0.63897E+04 173 tephroite 6.43 4.73 -1.70 -0.243 0.65733E+04 176 topaz-H -8.94 -11.49 -2.55 -0.232 0.98583E+04 177 tremolite 14.91 12.27 -2.64 -0.071 0.10228E+05 179 troilite-low -8.52 -9.24 -0.72 -0.239 0.27763E+04 180 tschermakite -8.82 -12.01 -3.19 -0.086 0.12349E+05 183 wadsleyite-Fe 2.99 1.22 -1.77 -0.253 0.68409E+04 184 wadsleyite-Mg 8.33 4.91 -3.42 -0.488 0.13212E+05 185 wairakite -10.13 -11.79 -1.66 -0.098 0.64327E+04 186 walstromite 4.57 2.10 -2.48 -0.495 0.95760E+04 187 wollastonite 4.16 2.10 -2.06 -0.412 0.79653E+04 188 pseudo-wollastonite 4.27 2.10 -2.17 -0.435 0.84090E+04 189 zoisite -9.94 -12.43 -2.50 -0.113 0.96546E+04 192 beidellite-Ca -14.18 -15.84 -1.66 -0.102 0.64074E+04 193 beidellite-H -14.20 -16.39 -2.18 -0.139 0.84495E+04 194 beidellite-K -13.15 -15.13 -1.98 -0.121 0.76677E+04 195 beidellite-Mg -14.46 -15.88 -1.43 -0.088 0.55141E+04 196 beidellite-Na -13.09 -14.98 -1.89 -0.115 0.72900E+04 197 bornite -53.84 -54.29 -0.45 -0.034 0.17518E+04 199 chalcocite -14.03 -15.56 -1.53 -0.383 0.59266E+04 200 covellite -12.51 -13.93 -1.42 -0.540 0.54783E+04 202 montmorillonite-Ca -10.58 -11.84 -1.25 -0.077 0.48423E+04 203 montmorillonite-K -9.83 -11.13 -1.29 -0.079 0.49977E+04 204 montmorillonite-Mg -10.81 -11.88 -1.07 -0.066 0.41282E+04 205 montmorillonite-Na -9.49 -10.97 -1.48 -0.091 0.57266E+04 206 nontronite-Ca -3.63 -4.99 -1.36 -0.088 0.52616E+04 207 nontronite-H -3.66 -5.54 -1.88 -0.126 0.72764E+04 208 nontronite-K -2.60 -4.28 -1.68 -0.108 0.65137E+04 209 nontronite-Mg -3.86 -5.03 -1.17 -0.076 0.45236E+04 210 nontronite-Na -2.54 -4.13 -1.59 -0.102 0.61489E+04 215 gypsum -12.35 -14.57 -2.23 -0.556 0.86057E+04 232 alabandite -6.34 -7.48 -1.14 -0.381 0.44219E+04 234 anglesite -14.80 -17.23 -2.43 -1.216 0.94017E+04 238 boehmite -4.04 -5.14 -1.10 -0.184 0.42727E+04 242 copper,native 1.75 -1.63 -3.38 -1.176 0.13073E+05 244 ferrous-oxide 2.02 1.21 -0.81 -0.202 0.31184E+04 245 galena -9.68 -9.81 -0.13 -0.044 0.50762E+03 246 silver,native 0.50 -3.41 -3.90 -1.358 0.15097E+05 248 litharge 5.27 0.64 -4.63 -1.157 0.17899E+05 256 wurtzite -10.05 -10.85 -0.80 -0.266 0.30889E+04 257 zincite 2.12 -0.40 -2.52 -0.631 0.97572E+04 258 an20ab80 -5.44 -5.45 -0.01 -0.001 0.49565E+02 259 an25ab75 -5.69 -5.70 -0.01 -0.001 0.45041E+02 260 an30ab70 -5.93 -5.94 -0.02 -0.001 0.65088E+02 261 tr.625ac.25prg.125 9.42 8.49 -0.93 -0.025 0.36034E+04 Calculations done for 572.0000 Deg. C; 1258.0000 bar Temperature changed by -1.000 degrees to 571.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 32 Loop limit = 500 Temperature = 571.00 C Pressure = 1238.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5511E+02 kg liquid = 0.9927E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9965 Stoichiometric ionic strength = .3283923E+01 Osmotic coef. = 0.0000 True ionic strength = .1744887E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.60705E-05 -5.2168 0.13532E-05 -5.8686 0.22291E+00 -0.6519 2 H2O 0.99649E+00 -0.0015 0.99649E+00 -0.0015 3 Cl- 0.14689E+00 -0.8330 0.28328E-01 -1.5478 0.19285E+00 -0.7148 4 SO4-- 0.21106E-03 -3.6756 0.65580E-06 -6.1832 0.31072E-02 -2.5076 5 HCO3- 0.13032E-04 -4.8850 0.27092E-05 -5.5672 0.20788E+00 -0.6822 6 HS- 0.12657E-03 -3.8977 0.24614E-04 -4.6088 0.19447E+00 -0.7111 7 H4SiO4 0.61223E-01 -1.2131 0.61223E-01 -1.2131 0.10000E+01 0.0000 8 Al+++ 0.11081E-16 -16.9554 0.19852E-22 -22.7022 0.17915E-05 -5.7468 9 Ca++ 0.14994E-05 -5.8241 0.37397E-08 -8.4272 0.24941E-02 -2.6031 10 Mg++ 0.10803E-05 -5.9664 0.22118E-08 -8.6553 0.20473E-02 -2.6888 11 Fe++ 0.14367E-07 -7.8426 0.30924E-10 -10.5097 0.21525E-02 -2.6671 12 K+ 0.40649E-01 -1.3909 0.86629E-02 -2.0623 0.21312E+00 -0.6714 13 Na+ 0.13205E+00 -0.8793 0.25774E-01 -1.5888 0.19518E+00 -0.7096 14 Mn++ 0.83634E-06 -6.0776 0.18673E-08 -8.7288 0.22327E-02 -2.6512 15 Zn++ 0.35132E-09 -9.4543 0.75622E-12 -12.1213 0.21525E-02 -2.6671 16 Cu+ 0.19054E-07 -7.7200 0.37090E-08 -8.4307 0.19466E+00 -0.7107 17 Pb++ 0.29700E-08 -8.5272 0.83055E-11 -11.0806 0.27965E-02 -2.5534 18 Ag+ 0.30814E-09 -9.5113 0.64633E-10 -10.1895 0.20976E+00 -0.6783 19 Ba++ 0.90834E-07 -7.0418 0.27306E-09 -9.5637 0.30061E-02 -2.5220 20 HPO4-- 0.10929E-08 -8.9614 0.34131E-11 -11.4669 0.31230E-02 -2.5054 21 HSiO3- 0.16212E-05 -5.7902 0.31266E-06 -6.5049 0.19285E+00 -0.7148 22 Ca(HSiO3)+ 0.65425E-08 -8.1843 0.14067E-08 -8.8518 0.21501E+00 -0.6675 23 Mg(HSiO3)+ 0.11457E-08 -8.9409 0.24634E-09 -9.6085 0.21501E+00 -0.6675 24 NaHSiO3,aq 0.17745E-05 -5.7509 0.17745E-05 -5.7509 0.10000E+01 0.0000 28 AgCl,aq 0.95343E-07 -7.0207 0.95343E-07 -7.0207 0.10000E+01 0.0000 29 AgCl2- 0.51129E-05 -5.2913 0.98603E-06 -6.0061 0.19285E+00 -0.7148 30 AgCl3-2 0.19767E-05 -5.7041 0.56821E-08 -8.2455 0.28746E-02 -2.5414 31 AgCl4-3 0.15724E-05 -5.8034 0.24452E-11 -11.6117 0.15551E-05 -5.8082 34 Ag(HS),aq 0.12618E-08 -8.8990 0.12618E-08 -8.8990 0.10000E+01 0.0000 35 Ag(HS)2- 0.56687E-08 -8.2465 0.10932E-08 -8.9613 0.19285E+00 -0.7148 38 HAlO2,aq 0.41971E-08 -8.3771 0.41971E-08 -8.3771 0.10000E+01 0.0000 39 AlO2- 0.14370E-04 -4.8426 0.24253E-05 -5.6152 0.16878E+00 -0.7727 41 Ba(HCO3)+ 0.35596E-06 -6.4486 0.79665E-07 -7.0987 0.22380E+00 -0.6501 42 BaCl+ 0.13270E-04 -4.8771 0.28532E-05 -5.5447 0.21501E+00 -0.6675 43 CH4,aq 0.16927E-08 -8.7714 0.20249E-08 -8.6936 0.11963E+01 0.0778 48 CO,aq 0.61378E-03 -3.2120 0.61378E-03 -3.2120 0.10000E+01 0.0000 49 CO2,aq 0.26749E+01 0.4273 0.31999E+01 0.5051 0.11963E+01 0.0778 50 CO3-2 0.41643E-10 -10.3805 0.11971E-12 -12.9219 0.28746E-02 -2.5414 51 CaCO3,aq 0.12094E-10 -10.9174 0.12094E-10 -10.9174 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.18035E-06 -6.7439 0.38777E-07 -7.4114 0.21501E+00 -0.6675 53 CaCl+ 0.10677E-03 -3.9715 0.22957E-04 -4.6391 0.21501E+00 -0.6675 54 CaCl2,aq 0.95030E-04 -4.0221 0.95030E-04 -4.0221 0.10000E+01 0.0000 55 CaOH+ 0.19808E-06 -6.7032 0.42589E-07 -7.3707 0.21501E+00 -0.6675 56 CaSO4,aq 0.15168E-06 -6.8191 0.15168E-06 -6.8191 0.10000E+01 0.0000 57 HCl,aq 0.22468E-02 -2.6484 0.22468E-02 -2.6484 0.10000E+01 0.0000 66 CuCl,aq 0.23768E-04 -4.6240 0.23768E-04 -4.6240 0.10000E+01 0.0000 67 CuCl2- 0.85701E-04 -4.0670 0.16528E-04 -4.7818 0.19285E+00 -0.7148 68 CuCl3-2 0.17771E-05 -5.7503 0.51085E-08 -8.2917 0.28746E-02 -2.5414 74 FeCl+ 0.31691E-06 -6.4991 0.68140E-07 -7.1666 0.21501E+00 -0.6675 75 FeCl2,aq 0.44164E-02 -2.3549 0.44164E-02 -2.3549 0.10000E+01 0.0000 77 FeO,aq 0.72824E-07 -7.1377 0.72824E-07 -7.1377 0.10000E+01 0.0000 78 FeOH+ 0.26449E-07 -7.5776 0.56869E-08 -8.2451 0.21501E+00 -0.6675 79 HFeO2- 0.90236E-08 -8.0446 0.17402E-08 -8.7594 0.19285E+00 -0.7148 82 FeO2- 0.56972E-08 -8.2443 0.10987E-08 -8.9591 0.19285E+00 -0.7148 83 HFeO2,aq 0.29123E-09 -9.5358 0.29123E-09 -9.5358 0.10000E+01 0.0000 84 H2,aq 0.47119E-02 -2.3268 0.56367E-02 -2.2490 0.11963E+01 0.0778 85 KCl,aq 0.67312E-01 -1.1719 0.67312E-01 -1.1719 0.10000E+01 0.0000 86 KHSO4,aq 0.13268E-01 -1.8772 0.13268E-01 -1.8772 0.10000E+01 0.0000 87 KOH,aq 0.12678E-05 -5.8969 0.12678E-05 -5.8969 0.10000E+01 0.0000 88 KSO4- 0.44120E-02 -2.3554 0.85086E-03 -3.0701 0.19285E+00 -0.7148 90 Mg(HCO3)+ 0.38853E-07 -7.4106 0.83538E-08 -8.0781 0.21501E+00 -0.6675 91 MgCl+ 0.12899E-04 -4.8895 0.27734E-05 -5.5570 0.21501E+00 -0.6675 92 MgOH+ 0.49503E-06 -6.3054 0.10644E-06 -6.9729 0.21501E+00 -0.6675 94 MnO,aq 0.71410E-07 -7.1462 0.71410E-07 -7.1462 0.10000E+01 0.0000 95 MnOH+ 0.18409E-06 -6.7350 0.39582E-07 -7.4025 0.21501E+00 -0.6675 97 HMnO2- 0.37337E-10 -10.4279 0.72004E-11 -11.1426 0.19285E+00 -0.7148 100 MnCl+ 0.11566E-02 -2.9368 0.24867E-03 -3.6044 0.21501E+00 -0.6675 101 MnSO4,aq 0.87300E-07 -7.0590 0.87300E-07 -7.0590 0.10000E+01 0.0000 102 NaCl,aq 0.42660E+00 -0.3700 0.42660E+00 -0.3700 0.10000E+01 0.0000 103 NaOH,aq 0.17370E-05 -5.7602 0.17370E-05 -5.7602 0.10000E+01 0.0000 105 OH- 0.81359E-05 -5.0896 0.13732E-05 -5.8623 0.16878E+00 -0.7727 110 HPO3-2 0.10981E-10 -10.9593 0.31567E-13 -13.5008 0.28746E-02 -2.5414 111 H3PO3,aq 0.10631E-09 -9.9734 0.10631E-09 -9.9734 0.10000E+01 0.0000 112 H2PO3- 0.24755E-08 -8.6063 0.47740E-09 -9.3211 0.19285E+00 -0.7148 113 H3PO4,aq 0.10156E-05 -5.9933 0.10156E-05 -5.9933 0.10000E+01 0.0000 114 H2PO4- 0.13704E-05 -5.8631 0.27798E-06 -6.5560 0.20284E+00 -0.6928 116 H4P2O7,aq 0.94097E-10 -10.0264 0.94097E-10 -10.0264 0.10000E+01 0.0000 117 H3P2O7- 0.80760E-09 -9.0928 0.15575E-09 -9.8076 0.19285E+00 -0.7148 118 H2P2O7-2 0.21585E-06 -6.6658 0.62049E-09 -9.2073 0.28746E-02 -2.5414 119 HP2O7-3 0.16867E-07 -7.7730 0.26230E-13 -13.5812 0.15551E-05 -5.8082 121 PbCl+ 0.15138E-05 -5.8199 0.32548E-06 -6.4875 0.21501E+00 -0.6675 122 PbCl2,aq 0.86246E-04 -4.0643 0.86246E-04 -4.0643 0.10000E+01 0.0000 123 PbCl3- 0.10418E-03 -3.9822 0.20092E-04 -4.6970 0.19285E+00 -0.7148 124 PbCl4-2 0.20593E-04 -4.6863 0.59198E-07 -7.2277 0.28746E-02 -2.5414 125 PbO,aq 0.57849E-08 -8.2377 0.57849E-08 -8.2377 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11731E-03 -3.9307 0.11731E-03 -3.9307 0.10000E+01 0.0000 128 Pb(HS)3- 0.12800E-04 -4.8928 0.24685E-05 -5.6076 0.19285E+00 -0.7148 129 H2S,aq 0.10549E+01 0.0232 0.12619E+01 0.1010 0.11963E+01 0.0778 130 S2-2 0.13463E-07 -7.8709 0.38701E-10 -10.4123 0.28746E-02 -2.5414 131 S3-2 0.12670E-08 -8.8972 0.36422E-11 -11.4386 0.28746E-02 -2.5414 132 S3- 0.12705E-01 -1.8960 0.24502E-02 -2.6108 0.19285E+00 -0.7148 133 S4-2 0.10082E-09 -9.9965 0.28981E-12 -12.5379 0.28746E-02 -2.5414 135 SO2,aq 0.29119E+00 -0.5358 0.29119E+00 -0.5358 0.10000E+01 0.0000 136 SO3-2 0.61974E-09 -9.2078 0.28315E-11 -11.5480 0.45688E-02 -2.3402 137 HSO3- 0.29631E-03 -3.5283 0.57143E-04 -4.2430 0.19285E+00 -0.7148 138 HSO4- 0.90176E-02 -2.0449 0.19917E-02 -2.7008 0.22086E+00 -0.6559 140 S2O3-2 0.50238E-06 -6.2990 0.14442E-08 -8.8404 0.28746E-02 -2.5414 141 HS2O3- 0.43926E-06 -6.3573 0.84713E-07 -7.0720 0.19285E+00 -0.7148 142 H2S2O3,aq 0.28511E-07 -7.5450 0.28511E-07 -7.5450 0.10000E+01 0.0000 150 S4O6-2 0.46662E-09 -9.3310 0.13414E-11 -11.8725 0.28746E-02 -2.5414 152 ZnCl+ 0.23709E-03 -3.6251 0.50976E-04 -4.2926 0.21501E+00 -0.6675 153 ZnCl2,aq 0.80891E-03 -3.0921 0.80891E-03 -3.0921 0.10000E+01 0.0000 154 ZnCl3- 0.72568E-04 -4.1393 0.13995E-04 -4.8540 0.19285E+00 -0.7148 155 ZnO,aq 0.33259E-07 -7.4781 0.33259E-07 -7.4781 0.10000E+01 0.0000 156 ZnOH+ 0.14972E-05 -5.8247 0.32192E-06 -6.4923 0.21501E+00 -0.6675 158 HZnO2- 0.26733E-09 -9.5730 0.51555E-10 -10.2877 0.19285E+00 -0.7148 Charge balance for all species = 0.2549E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6070543E-05 0.4296722E+01 0.3539415E+04 0.0000 2 H2O 0.1000000E+01 0.5251452E+02 0.7731798E+06 0.0000 3 Cl- 0.1468891E+00 0.6562248E+00 0.1901364E+05 4.3209 4 SO4-- 0.2110557E-03 0.2521369E+00 0.1979456E+05 5.5541 5 HCO3- 0.1303235E-04 0.2675537E+01 0.1334206E+06 0.3015 6 HS- 0.1265711E-03 0.1159677E+01 0.3134418E+05 1.2598 7 H4SiO4 0.6122271E-01 0.6122611E-01 0.4809382E+04 -1.2131 8 Al+++ 0.1108107E-16 0.1437381E-04 0.3169550E+00 -5.0963 9 Ca++ 0.1499418E-05 0.2038371E-03 0.6676501E+01 3.3101 10 Mg++ 0.1080339E-05 0.1451415E-04 0.2883844E+00 3.0820 11 Fe++ 0.1436662E-07 0.4416826E-02 0.2015904E+03 1.2276 12 K+ 0.4064902E-01 0.1256420E+00 0.4015073E+04 3.8063 13 Na+ 0.1320519E+00 0.5586552E+00 0.1049636E+05 4.2798 14 Mn++ 0.8363384E-06 0.1157740E-02 0.5198085E+02 3.0085 15 Zn++ 0.3513209E-09 0.1120093E-02 0.5984008E+02 -0.3841 16 Cu+ 0.1905418E-07 0.1112648E-03 0.5777827E+01 -2.5621 17 Pb++ 0.2969977E-08 0.3426604E-03 0.5802194E+02 0.6567 18 Ag+ 0.3081371E-09 0.8764472E-05 0.7726557E+00 -4.3209 19 Ba++ 0.9083413E-07 0.1371669E-04 0.1539593E+01 2.1735 20 HPO4-- 0.1092882E-08 0.2856958E-05 0.2240989E+00 0.2704 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265528E+01 -.3165575E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5213326E+02 -.1684847E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2503064E+00 0.1416353E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1151257E+01 0.8886706E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.6078161E-01 0.8281271E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1426946E-04 0.6802701E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.2023573E-03 0.3255526E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1440877E-04 0.6267879E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.4384760E-02 0.4381994E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247299E+00 0.6802701E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149335E-02 0.1653861E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1111961E-02 0.1187374E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1104570E-03 0.2891527E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1361711E-04 0.4175535E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2836216E-05 0.5731284E-05 0.0000000E+00 Chg. balance for solid moles: -.1833E-17 Mass of aqueous solution: 0.121472E+04 g Temperature = 571.00 C Pressure = 1238.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3160E-03 -3.500 0.4302E-01 -1.366 0.7474 0.1452E-01 annite 0.1010E-05 -5.996 0.5168E-03 -3.287 0.8979E-02 0.1558E-03 phlogopite 0.2089E-05 -5.680 0.8718E-03 -3.060 0.1515E-01 0.3126E-03 biotite-Mn 0.5513E-07 -7.259 0.2807E-04 -4.552 0.4877E-03 0.8414E-05 apatite-OH 0.1910E-05 -5.719 0.9596E-03 -3.018 0.1667E-01 0.3049E-03 microcline 0.6771E-03 -3.169 0.1885 -0.725 3.274 0.7362E-01 pyrite 0.4090E-02 -2.388 0.4907 -0.309 8.525 0.9790E-01 quartz 0.8077E-01 -1.093 4.853 0.686 84.31 1.833 barite 0.4176E-04 -4.379 0.9746E-02 -2.011 0.1693 0.2175E-02 chalcopyrite 0.2892E-03 -3.539 0.5306E-01 -1.275 0.9218 0.1239E-01 sphalerite 0.1187E-02 -2.925 0.1157 -0.937 2.010 0.2829E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3201E+00 0.3201E+00 1.0000 -0.495 phlogopite 0.6624E+00 0.6624E+00 1.0000 -0.179 biotite-Mn 0.1748E-01 0.1748E-01 1.0000 -1.757 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.755828 g Volume = 2.062298 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.61 -14.61 0.00 0.000 0.68615E-11 24 annite 0.24 0.24 0.00 0.000 0.40740E-11 25 phlogopite 4.85 4.85 0.00 0.000 0.20585E-10 26 biotite-Mn 9.37 9.37 0.00 0.000 0.34308E-10 30 apatite-OH -53.06 -53.06 0.00 0.000 0.00000E+00 115 microcline -4.92 -4.92 0.00 0.000 -0.13723E-10 140 pyrite -21.59 -21.59 0.00 0.000 0.00000E+00 144 quartz -1.21 -1.21 0.00 0.000 0.00000E+00 237 barite -15.75 -15.75 0.00 0.000 0.00000E+00 240 chalcopyrite -23.22 -23.22 0.00 0.000 -0.13723E-10 255 sphalerite -10.86 -10.86 0.00 0.000 -0.13723E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.27 -0.274 0.10577E+04 2.819 2 CO2,gas -9.81 -11.43 -1.63 -0.543 0.62925E+04 1.464 3 CH4,gas 6.89 -3.99 -10.88 -2.720 0.42030E+05 -7.788 4 H2,gas 5.92 1.86 -4.06 -2.318 0.15669E+05 -0.964 5 H2S,gas -8.17 -10.48 -2.31 -1.154 0.89150E+04 0.785 6 CO,gas -3.66 -9.57 -5.91 -1.819 0.22832E+05 -2.818 7 SO3,gas -7.38 -17.92 -10.54 -2.635 0.40720E+05 -7.449 8 O2,gas 16.69 -3.72 -20.41 -13.605 0.78828E+05 -17.315 9 HCl,gas -6.02 -7.42 -1.39 -0.696 0.53770E+04 -1.392 10 acmite 3.64 2.15 -1.49 -0.155 0.57550E+04 12 akimotoite 6.06 1.87 -4.19 -0.838 0.16188E+05 13 akimotoite-Fe 3.96 0.02 -3.95 -0.789 0.15245E+05 14 albite-high -4.33 -4.45 -0.12 -0.009 0.44455E+03 15 albite -4.32 -4.45 -0.13 -0.010 0.49677E+03 16 almandine -8.52 -10.15 -1.63 -0.081 0.62875E+04 17 pyrope -1.88 -4.59 -2.70 -0.135 0.10443E+05 18 analcite -2.29 -3.24 -0.95 -0.106 0.36846E+04 19 andalusite -10.93 -11.41 -0.48 -0.048 0.18451E+04 20 andradite 11.53 6.89 -4.64 -0.241 0.17940E+05 21 grossular 1.06 -3.90 -4.96 -0.248 0.19172E+05 27 anorthite -8.64 -9.31 -0.67 -0.051 0.25829E+04 28 anthophyllite 14.21 11.88 -2.33 -0.063 0.89862E+04 29 anthophyllite-Fe 1.57 -1.10 -2.67 -0.072 0.10302E+05 31 apatite-OH-zs -50.91 -53.06 -2.16 -0.166 0.83260E+04 32 apatite-Cl-zs -57.27 -60.48 -3.20 -0.267 0.12373E+05 33 aragonite -4.56 -8.13 -3.57 -1.190 0.13791E+05 34 brucite 5.35 3.08 -2.27 -0.453 0.87571E+04 35 calcite -4.66 -8.13 -3.47 -1.156 0.13395E+05 36 carnegieite-low -0.27 -2.03 -1.76 -0.251 0.67896E+04 37 carnegieite-high -0.20 -2.03 -1.83 -0.262 0.70841E+04 38 carpholite-Mg -7.53 -9.54 -2.01 -0.134 0.77685E+04 39 carpholite-Fe -8.89 -11.39 -2.51 -0.167 0.96863E+04 40 celadonite -0.94 -3.05 -2.11 -0.124 0.81516E+04 41 celadonite-Fe -2.35 -4.91 -2.56 -0.150 0.98736E+04 42 chrysotile 9.28 6.82 -2.47 -0.206 0.95276E+04 44 clinochlore 3.07 1.57 -1.50 -0.047 0.57931E+04 45 daphnite -4.01 -7.70 -3.70 -0.115 0.14276E+05 48 chloritoid-Mg -7.00 -8.33 -1.33 -0.088 0.51219E+04 49 chloritoid-Fe -8.94 -10.18 -1.24 -0.083 0.47965E+04 50 chloritoid-Mn -6.79 -8.40 -1.61 -0.108 0.62338E+04 52 coesite -0.92 -1.21 -0.29 -0.096 0.11080E+04 53 cordierite-H -19.44 -20.28 -0.85 -0.030 0.32661E+04 54 cordierite-Fe -22.01 -23.99 -1.98 -0.068 0.76458E+04 55 cordierite-Mn -17.63 -20.43 -2.80 -0.096 0.10803E+05 56 corundum -9.55 -10.20 -0.65 -0.059 0.25156E+04 58 cristobalite -1.16 -1.21 -0.05 -0.016 0.18030E+03 59 cummingtonite 14.27 11.88 -2.39 -0.065 0.92378E+04 61 cymrite-K -2.64 -4.92 -2.28 -0.190 0.88243E+04 63 diaspore -4.27 -5.10 -0.83 -0.138 0.32007E+04 65 diopside 5.32 3.97 -1.35 -0.135 0.52228E+04 66 hedenbergite 3.90 2.11 -1.78 -0.178 0.68829E+04 68 eastonite -6.42 -7.75 -1.33 -0.051 0.51366E+04 69 enstatite 4.64 3.74 -0.90 -0.090 0.34614E+04 70 clinoenstatite-HiP 5.13 3.74 -1.39 -0.139 0.53660E+04 71 clinoenstatite 4.62 3.74 -0.88 -0.088 0.34026E+04 72 protoenstatite 4.77 3.74 -1.03 -0.103 0.39714E+04 73 epidote -4.76 -6.92 -2.15 -0.104 0.83126E+04 74 clinozoisite -9.72 -12.31 -2.59 -0.118 0.10005E+05 75 epidote-Fe 1.87 -1.52 -3.40 -0.176 0.13115E+05 76 fayalite 2.18 1.24 -0.93 -0.133 0.36062E+04 77 ferrosilite 1.06 0.03 -1.03 -0.103 0.39732E+04 78 forsterite 6.17 4.95 -1.22 -0.174 0.46970E+04 79 gedrite -10.11 -12.25 -2.15 -0.058 0.82857E+04 81 gibbsite -2.65 -5.10 -2.45 -0.350 0.94645E+04 82 glaucophane 1.02 -2.08 -3.10 -0.084 0.11990E+05 83 glaucophane-Fe -3.03 -7.64 -4.61 -0.125 0.17814E+05 84 goethite 1.11 0.29 -0.81 -0.176 0.31448E+04 86 greenalite 4.41 1.26 -3.16 -0.263 0.12198E+05 87 grunerite 2.12 -1.10 -3.22 -0.087 0.12428E+05 88 halite -1.09 -3.14 -2.05 -1.023 0.79053E+04 89 hematite 0.68 0.59 -0.09 -0.011 0.33585E+03 90 heulandite -12.34 -15.37 -3.03 -0.138 0.11708E+05 91 hercynite -7.88 -8.97 -1.09 -0.073 0.42203E+04 94 jadeite -1.60 -3.24 -1.64 -0.164 0.63164E+04 96 kalsilite -0.89 -2.50 -1.61 -0.230 0.62135E+04 97 kaolinite -9.90 -12.62 -2.72 -0.248 0.10525E+05 98 kyanite -10.77 -11.41 -0.64 -0.064 0.24649E+04 100 laumontite -8.19 -11.73 -3.55 -0.236 0.13699E+05 101 lawsonite -5.87 -9.31 -3.44 -0.229 0.13288E+05 102 leucite -2.76 -3.71 -0.95 -0.095 0.36662E+04 104 lizardite 9.46 6.82 -2.64 -0.220 0.10214E+05 105 magnesite -5.44 -8.35 -2.91 -0.970 0.11238E+05 106 magnetite 1.83 1.82 -0.01 -0.001 0.42190E+02 107 minnesotaite 0.73 -1.16 -1.90 -0.112 0.73327E+04 108 minnesotaite-Mg 6.70 4.40 -2.30 -0.135 0.88868E+04 109 magnesioferrite 4.89 3.67 -1.22 -0.100 0.47123E+04 111 manganosite 5.32 3.01 -2.31 -0.578 0.89274E+04 112 margarite -17.71 -19.51 -1.79 -0.072 0.69320E+04 116 monticellite 8.68 5.18 -3.50 -0.500 0.13529E+05 118 mullite-Si -10.19 -11.41 -1.22 -0.122 0.47101E+04 119 muscovite -14.33 -15.12 -0.79 -0.046 0.30478E+04 120 paragonite -13.65 -14.65 -1.00 -0.059 0.38480E+04 121 nepheline -0.57 -2.03 -1.46 -0.209 0.56476E+04 122 osumilite(2) -13.57 -15.56 -1.99 -0.041 0.76713E+04 123 osumilite-Fe -28.98 -31.34 -2.36 -0.049 0.91067E+04 124 pargasite 4.61 0.66 -3.95 -0.104 0.15246E+05 125 periclase 5.53 3.08 -2.45 -0.613 0.94770E+04 126 periclase-Fe 2.96 1.23 -1.73 -0.434 0.66983E+04 127 perovskite-Al -7.82 -10.20 -2.38 -0.216 0.91749E+04 132 phlogopite-Na 5.72 4.79 -0.93 -0.052 0.35928E+04 134 prehnite -3.97 -7.21 -3.25 -0.191 0.12538E+05 135 prehnite-Fe 1.38 -1.82 -3.20 -0.192 0.12357E+05 138 px-Mg-tschermaks -6.42 -8.33 -1.91 -0.137 0.73824E+04 139 px-Ca-tschermaks -5.55 -8.10 -2.55 -0.182 0.98558E+04 141 pyrrhotite -8.62 -9.25 -0.63 -0.209 0.24251E+04 142 pyrrhotiteFe0.875 -9.38 -9.63 -0.25 -0.093 0.97421E+03 143 pyrophyllite -13.69 -15.04 -1.35 -0.084 0.52219E+04 146 riebeckite 5.78 3.15 -2.64 -0.073 0.10180E+05 147 ringwoodite-Fe 3.17 1.24 -1.93 -0.275 0.74455E+04 148 ringwoodite-Mg 9.31 4.95 -4.36 -0.622 0.16828E+05 149 rhodochrosite -5.39 -8.43 -3.03 -1.011 0.11716E+05 150 rhodonite 2.49 1.80 -0.69 -0.139 0.26777E+04 151 sanidine -4.39 -4.92 -0.54 -0.041 0.20685E+04 153 siderite -7.28 -10.21 -2.93 -0.977 0.11318E+05 154 sillimanite -10.89 -11.41 -0.51 -0.051 0.19784E+04 156 spinel -5.71 -7.12 -1.41 -0.094 0.54325E+04 162 stilpnomelane-Fe -7.19 -11.85 -4.66 -0.139 0.18009E+05 163 stilpnomelane-Mg -0.39 -2.58 -2.19 -0.065 0.84678E+04 164 stishovite 1.73 -1.21 -2.94 -0.980 0.11358E+05 165 sudoite-Fe -17.46 -21.58 -4.12 -0.133 0.15914E+05 166 sudoite -15.23 -17.87 -2.64 -0.085 0.10184E+05 167 sulfur -10.83 -12.34 -1.50 -0.462 0.58058E+04 168 sylvite -1.00 -3.61 -2.61 -1.307 0.10100E+05 169 talc 4.98 4.40 -0.58 -0.034 0.22375E+04 170 talc-Fe 2.13 -1.16 -3.29 -0.194 0.12717E+05 171 talc-tschermaks -6.00 -7.67 -1.67 -0.098 0.64514E+04 173 tephroite 6.46 4.80 -1.66 -0.237 0.64001E+04 176 topaz-H -8.84 -11.41 -2.57 -0.234 0.99334E+04 177 tremolite 14.98 12.34 -2.64 -0.071 0.10212E+05 179 troilite-low -8.53 -9.25 -0.72 -0.240 0.27853E+04 180 tschermakite -8.56 -11.80 -3.24 -0.087 0.12504E+05 183 wadsleyite-Fe 3.02 1.24 -1.78 -0.254 0.68690E+04 184 wadsleyite-Mg 8.37 4.95 -3.42 -0.488 0.13201E+05 185 wairakite -10.05 -11.73 -1.69 -0.099 0.65147E+04 186 walstromite 4.58 2.10 -2.48 -0.496 0.95858E+04 187 wollastonite 4.16 2.10 -2.06 -0.413 0.79740E+04 188 pseudo-wollastonite 4.28 2.10 -2.18 -0.436 0.84181E+04 189 zoisite -9.77 -12.31 -2.54 -0.115 0.97959E+04 192 beidellite-Ca -14.09 -15.78 -1.68 -0.104 0.64978E+04 193 beidellite-H -14.11 -16.32 -2.21 -0.141 0.85376E+04 194 beidellite-K -13.06 -15.07 -2.00 -0.123 0.77439E+04 195 beidellite-Mg -14.36 -15.81 -1.45 -0.090 0.56046E+04 196 beidellite-Na -13.00 -14.91 -1.91 -0.117 0.73681E+04 197 bornite -53.98 -54.42 -0.45 -0.033 0.17271E+04 199 chalcocite -14.07 -15.60 -1.53 -0.383 0.59117E+04 200 covellite -12.55 -13.97 -1.41 -0.539 0.54648E+04 202 montmorillonite-Ca -10.52 -11.79 -1.27 -0.079 0.49035E+04 203 montmorillonite-K -9.78 -11.08 -1.31 -0.080 0.50482E+04 204 montmorillonite-Mg -10.75 -11.83 -1.08 -0.067 0.41864E+04 205 montmorillonite-Na -9.43 -10.93 -1.49 -0.092 0.57743E+04 206 nontronite-Ca -3.62 -4.99 -1.37 -0.089 0.52911E+04 207 nontronite-H -3.64 -5.53 -1.89 -0.127 0.73038E+04 208 nontronite-K -2.59 -4.28 -1.69 -0.108 0.65292E+04 209 nontronite-Mg -3.85 -5.03 -1.18 -0.076 0.45510E+04 210 nontronite-Na -2.53 -4.12 -1.60 -0.102 0.61663E+04 215 gypsum -12.38 -14.61 -2.23 -0.557 0.86100E+04 232 alabandite -6.35 -7.47 -1.12 -0.374 0.43345E+04 234 anglesite -14.84 -17.26 -2.42 -1.209 0.93436E+04 238 boehmite -3.98 -5.10 -1.12 -0.186 0.43109E+04 242 copper,native 1.75 -1.63 -3.38 -1.176 0.13062E+05 244 ferrous-oxide 2.04 1.23 -0.81 -0.203 0.31340E+04 245 galena -9.70 -9.82 -0.12 -0.039 0.45216E+03 246 silver,native 0.49 -3.39 -3.88 -1.351 0.14999E+05 248 litharge 5.27 0.66 -4.62 -1.155 0.17845E+05 256 wurtzite -10.06 -10.86 -0.80 -0.267 0.30888E+04 257 zincite 2.14 -0.39 -2.53 -0.632 0.97606E+04 258 an20ab80 -5.40 -5.42 -0.02 -0.001 0.74774E+02 259 an25ab75 -5.65 -5.66 -0.02 -0.001 0.74348E+02 260 an30ab70 -5.88 -5.91 -0.03 -0.002 0.98651E+02 261 tr.625ac.25prg.125 9.50 8.56 -0.94 -0.025 0.36370E+04 Calculations done for 571.0000 Deg. C; 1238.0000 bar Temperature changed by -1.000 degrees to 570.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 32 Loop limit = 500 Temperature = 570.00 C Pressure = 1220.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5511E+02 kg liquid = 0.9928E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9965 Stoichiometric ionic strength = .3282934E+01 Osmotic coef. = 0.0000 True ionic strength = .1713685E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.58792E-05 -5.2307 0.13003E-05 -5.8860 0.22117E+00 -0.6553 2 H2O 0.99652E+00 -0.0015 0.99652E+00 -0.0015 3 Cl- 0.14425E+00 -0.8409 0.27557E-01 -1.5598 0.19104E+00 -0.7189 4 SO4-- 0.21321E-03 -3.6712 0.64107E-06 -6.1931 0.30067E-02 -2.5219 5 HCO3- 0.12575E-04 -4.9005 0.25889E-05 -5.5869 0.20588E+00 -0.6864 6 HS- 0.12537E-03 -3.9018 0.24151E-04 -4.6171 0.19264E+00 -0.7153 7 H4SiO4 0.59875E-01 -1.2228 0.59875E-01 -1.2228 0.10000E+01 0.0000 8 Al+++ 0.11631E-16 -16.9344 0.19360E-22 -22.7131 0.16645E-05 -5.7787 9 Ca++ 0.14606E-05 -5.8355 0.35250E-08 -8.4528 0.24134E-02 -2.6174 10 Mg++ 0.10913E-05 -5.9621 0.21628E-08 -8.6650 0.19819E-02 -2.7029 11 Fe++ 0.14124E-07 -7.8500 0.29426E-10 -10.5313 0.20834E-02 -2.6812 12 K+ 0.40004E-01 -1.3979 0.84425E-02 -2.0735 0.21104E+00 -0.6756 13 Na+ 0.12959E+00 -0.8874 0.25053E-01 -1.6011 0.19332E+00 -0.7137 14 Mn++ 0.86334E-06 -6.0638 0.18656E-08 -8.7292 0.21609E-02 -2.6654 15 Zn++ 0.34577E-09 -9.4612 0.72039E-12 -12.1424 0.20834E-02 -2.6812 16 Cu+ 0.18260E-07 -7.7385 0.35206E-08 -8.4534 0.19280E+00 -0.7149 17 Pb++ 0.29261E-08 -8.5337 0.79168E-11 -11.1015 0.27055E-02 -2.5677 18 Ag+ 0.30646E-09 -9.5136 0.63659E-10 -10.1961 0.20772E+00 -0.6825 19 Ba++ 0.87007E-07 -7.0604 0.25302E-09 -9.5968 0.29081E-02 -2.5364 20 HPO4-- 0.11120E-08 -8.9539 0.33603E-11 -11.4736 0.30220E-02 -2.5197 21 HSiO3- 0.15954E-05 -5.7971 0.30479E-06 -6.5160 0.19104E+00 -0.7189 22 Ca(HSiO3)+ 0.62904E-08 -8.2013 0.13393E-08 -8.8731 0.21292E+00 -0.6718 23 Mg(HSiO3)+ 0.11518E-08 -8.9386 0.24524E-09 -9.6104 0.21292E+00 -0.6718 24 NaHSiO3,aq 0.17924E-05 -5.7466 0.17924E-05 -5.7466 0.10000E+01 0.0000 28 AgCl,aq 0.97455E-07 -7.0112 0.97455E-07 -7.0112 0.10000E+01 0.0000 29 AgCl2- 0.51351E-05 -5.2895 0.98100E-06 -6.0083 0.19104E+00 -0.7189 30 AgCl3-2 0.19524E-05 -5.7094 0.54314E-08 -8.2651 0.27819E-02 -2.5557 31 AgCl4-3 0.15718E-05 -5.8036 0.22738E-11 -11.6433 0.14466E-05 -5.8396 34 Ag(HS),aq 0.13177E-08 -8.8802 0.13177E-08 -8.8802 0.10000E+01 0.0000 35 Ag(HS)2- 0.57897E-08 -8.2373 0.11061E-08 -8.9562 0.19104E+00 -0.7189 38 HAlO2,aq 0.41664E-08 -8.3802 0.41664E-08 -8.3802 0.10000E+01 0.0000 39 AlO2- 0.14011E-04 -4.8535 0.23437E-05 -5.6301 0.16728E+00 -0.7766 41 Ba(HCO3)+ 0.33554E-06 -6.4743 0.74357E-07 -7.1287 0.22160E+00 -0.6544 42 BaCl+ 0.12561E-04 -4.9010 0.26744E-05 -5.5728 0.21292E+00 -0.6718 43 CH4,aq 0.16757E-08 -8.7758 0.20033E-08 -8.6983 0.11955E+01 0.0775 48 CO,aq 0.60390E-03 -3.2190 0.60390E-03 -3.2190 0.10000E+01 0.0000 49 CO2,aq 0.26748E+01 0.4273 0.31977E+01 0.5048 0.11955E+01 0.0775 50 CO3-2 0.41223E-10 -10.3849 0.11468E-12 -12.9405 0.27819E-02 -2.5557 51 CaCO3,aq 0.11843E-10 -10.9265 0.11843E-10 -10.9265 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.16879E-06 -6.7727 0.35937E-07 -7.4445 0.21292E+00 -0.6718 53 CaCl+ 0.10218E-03 -3.9906 0.21756E-04 -4.6624 0.21292E+00 -0.6718 54 CaCl2,aq 0.92730E-04 -4.0328 0.92730E-04 -4.0328 0.10000E+01 0.0000 55 CaOH+ 0.19062E-06 -6.7198 0.40587E-07 -7.3916 0.21292E+00 -0.6718 56 CaSO4,aq 0.15308E-06 -6.8151 0.15308E-06 -6.8151 0.10000E+01 0.0000 57 HCl,aq 0.23311E-02 -2.6324 0.23311E-02 -2.6324 0.10000E+01 0.0000 66 CuCl,aq 0.23419E-04 -4.6304 0.23419E-04 -4.6304 0.10000E+01 0.0000 67 CuCl2- 0.83680E-04 -4.0774 0.15986E-04 -4.7963 0.19104E+00 -0.7189 68 CuCl3-2 0.17086E-05 -5.7674 0.47532E-08 -8.3230 0.27819E-02 -2.5557 74 FeCl+ 0.30622E-06 -6.5140 0.65199E-07 -7.1858 0.21292E+00 -0.6718 75 FeCl2,aq 0.42308E-02 -2.3736 0.42308E-02 -2.3736 0.10000E+01 0.0000 77 FeO,aq 0.71549E-07 -7.1454 0.71549E-07 -7.1454 0.10000E+01 0.0000 78 FeOH+ 0.25657E-07 -7.5908 0.54628E-08 -8.2626 0.21292E+00 -0.6718 79 HFeO2- 0.88061E-08 -8.0552 0.16823E-08 -8.7741 0.19104E+00 -0.7189 82 FeO2- 0.55420E-08 -8.2563 0.10587E-08 -8.9752 0.19104E+00 -0.7189 83 HFeO2,aq 0.29141E-09 -9.5355 0.29141E-09 -9.5355 0.10000E+01 0.0000 84 H2,aq 0.47047E-02 -2.3275 0.56243E-02 -2.2499 0.11955E+01 0.0775 85 KCl,aq 0.67874E-01 -1.1683 0.67874E-01 -1.1683 0.10000E+01 0.0000 86 KHSO4,aq 0.13310E-01 -1.8758 0.13310E-01 -1.8758 0.10000E+01 0.0000 87 KOH,aq 0.12842E-05 -5.8914 0.12842E-05 -5.8914 0.10000E+01 0.0000 88 KSO4- 0.44471E-02 -2.3519 0.84957E-03 -3.0708 0.19104E+00 -0.7189 90 Mg(HCO3)+ 0.37421E-07 -7.4269 0.79676E-08 -8.0987 0.21292E+00 -0.6718 91 MgCl+ 0.12869E-04 -4.8904 0.27401E-05 -5.5622 0.21292E+00 -0.6718 92 MgOH+ 0.49536E-06 -6.3051 0.10547E-06 -6.9769 0.21292E+00 -0.6718 94 MnO,aq 0.74019E-07 -7.1307 0.74019E-07 -7.1307 0.10000E+01 0.0000 95 MnOH+ 0.18656E-06 -6.7292 0.39721E-07 -7.4010 0.21292E+00 -0.6718 97 HMnO2- 0.38188E-10 -10.4181 0.72954E-11 -11.1370 0.19104E+00 -0.7189 100 MnCl+ 0.11565E-02 -2.9369 0.24623E-03 -3.6087 0.21292E+00 -0.6718 101 MnSO4,aq 0.92785E-07 -7.0325 0.92785E-07 -7.0325 0.10000E+01 0.0000 102 NaCl,aq 0.42904E+00 -0.3675 0.42904E+00 -0.3675 0.10000E+01 0.0000 103 NaOH,aq 0.17534E-05 -5.7561 0.17534E-05 -5.7561 0.10000E+01 0.0000 105 OH- 0.80644E-05 -5.0934 0.13490E-05 -5.8700 0.16728E+00 -0.7766 110 HPO3-2 0.10815E-10 -10.9660 0.30086E-13 -13.5216 0.27819E-02 -2.5557 111 H3PO3,aq 0.10680E-09 -9.9714 0.10680E-09 -9.9714 0.10000E+01 0.0000 112 H2PO3- 0.23965E-08 -8.6204 0.45783E-09 -9.3393 0.19104E+00 -0.7189 113 H3PO4,aq 0.10388E-05 -5.9835 0.10388E-05 -5.9835 0.10000E+01 0.0000 114 H2PO4- 0.13618E-05 -5.8659 0.27359E-06 -6.5629 0.20090E+00 -0.6970 116 H4P2O7,aq 0.98868E-10 -10.0049 0.98868E-10 -10.0049 0.10000E+01 0.0000 117 H3P2O7- 0.80482E-09 -9.0943 0.15375E-09 -9.8132 0.19104E+00 -0.7189 118 H2P2O7-2 0.21327E-06 -6.6711 0.59330E-09 -9.2267 0.27819E-02 -2.5557 119 HP2O7-3 0.17289E-07 -7.7622 0.25011E-13 -13.6019 0.14466E-05 -5.8396 121 PbCl+ 0.14758E-05 -5.8310 0.31422E-06 -6.5028 0.21292E+00 -0.6718 122 PbCl2,aq 0.86222E-04 -4.0644 0.86222E-04 -4.0644 0.10000E+01 0.0000 123 PbCl3- 0.10349E-03 -3.9851 0.19770E-04 -4.7040 0.19104E+00 -0.7189 124 PbCl4-2 0.20087E-04 -4.6971 0.55881E-07 -7.2527 0.27819E-02 -2.5557 125 PbO,aq 0.59019E-08 -8.2290 0.59019E-08 -8.2290 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11841E-03 -3.9266 0.11841E-03 -3.9266 0.10000E+01 0.0000 128 Pb(HS)3- 0.12953E-04 -4.8876 0.24745E-05 -5.6065 0.19104E+00 -0.7189 129 H2S,aq 0.10553E+01 0.0234 0.12616E+01 0.1009 0.11955E+01 0.0775 130 S2-2 0.13309E-07 -7.8759 0.37023E-10 -10.4315 0.27819E-02 -2.5557 131 S3-2 0.12469E-08 -8.9042 0.34688E-11 -11.4598 0.27819E-02 -2.5557 132 S3- 0.12331E-01 -1.9090 0.23556E-02 -2.6279 0.19104E+00 -0.7189 133 S4-2 0.98860E-10 -10.0050 0.27502E-12 -12.5606 0.27819E-02 -2.5557 135 SO2,aq 0.29149E+00 -0.5354 0.29149E+00 -0.5354 0.10000E+01 0.0000 136 SO3-2 0.62152E-09 -9.2065 0.27473E-11 -11.5611 0.44203E-02 -2.3545 137 HSO3- 0.28980E-03 -3.5379 0.55363E-04 -4.2568 0.19104E+00 -0.7189 138 HSO4- 0.88893E-02 -2.0511 0.19442E-02 -2.7113 0.21871E+00 -0.6601 140 S2O3-2 0.50049E-06 -6.3006 0.13923E-08 -8.8563 0.27819E-02 -2.5557 141 HS2O3- 0.42909E-06 -6.3674 0.81974E-07 -7.0863 0.19104E+00 -0.7189 142 H2S2O3,aq 0.28936E-07 -7.5386 0.28936E-07 -7.5386 0.10000E+01 0.0000 150 S4O6-2 0.45806E-09 -9.3391 0.12743E-11 -11.8947 0.27819E-02 -2.5557 152 ZnCl+ 0.22417E-03 -3.6494 0.47730E-04 -4.3212 0.21292E+00 -0.6718 153 ZnCl2,aq 0.78326E-03 -3.1061 0.78326E-03 -3.1061 0.10000E+01 0.0000 154 ZnCl3- 0.68364E-04 -4.1652 0.13060E-04 -4.8840 0.19104E+00 -0.7189 155 ZnO,aq 0.32780E-07 -7.4844 0.32780E-07 -7.4844 0.10000E+01 0.0000 156 ZnOH+ 0.14323E-05 -5.8440 0.30497E-06 -6.5157 0.21292E+00 -0.6718 158 HZnO2- 0.26189E-09 -9.5819 0.50031E-10 -10.3008 0.19104E+00 -0.7189 Charge balance for all species = 0.2549E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5879197E-05 0.4296548E+01 0.3539730E+04 0.0000 2 H2O 0.1000000E+01 0.5251526E+02 0.7732907E+06 0.0000 3 Cl- 0.1442472E+00 0.6561982E+00 0.1901533E+05 4.3262 4 SO4-- 0.2132098E-03 0.2520730E+00 0.1979210E+05 5.5788 5 HCO3- 0.1257488E-04 0.2675429E+01 0.1334324E+06 0.2991 6 HS- 0.1253739E-03 0.1159262E+01 0.3133703E+05 1.2689 7 H4SiO4 0.5987462E-01 0.5987802E-01 0.4704096E+04 -1.2228 8 Al+++ 0.1163108E-16 0.1401474E-04 0.3090772E+00 -5.0552 9 Ca++ 0.1460576E-05 0.1968887E-03 0.6449744E+01 3.3191 10 Mg++ 0.1091281E-05 0.1449459E-04 0.2880330E+00 3.1069 11 Fe++ 0.1412396E-07 0.4231242E-02 0.1931450E+03 1.2407 12 K+ 0.4000422E-01 0.1256366E+00 0.4015418E+04 3.8124 13 Na+ 0.1295938E+00 0.5586325E+00 0.1049729E+05 4.2848 14 Mn++ 0.8633357E-06 0.1157687E-02 0.5198522E+02 3.0427 15 Zn++ 0.3457667E-09 0.1077266E-02 0.5755952E+02 -0.3705 16 Cu+ 0.1826024E-07 0.1088259E-03 0.5651909E+01 -2.5674 17 Pb++ 0.2926147E-08 0.3426465E-03 0.5802709E+02 0.6705 18 Ag+ 0.3064644E-09 0.8764116E-05 0.7727243E+00 -4.3102 19 Ba++ 0.8700688E-07 0.1298351E-04 0.1457488E+01 2.1751 20 HPO4-- 0.1111959E-08 0.2867084E-05 0.2249222E+00 0.2983 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265528E+01 -.3166100E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5213612E+02 -.1713388E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2502531E+00 0.1469714E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1150892E+01 0.9251681E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.5944572E-01 0.8414860E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1391356E-04 0.6806260E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1954672E-03 0.3324427E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1438994E-04 0.6286713E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.4200694E-02 0.4566060E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247295E+00 0.6806260E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149329E-02 0.1707626E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1069488E-02 0.1229846E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1080402E-03 0.2915695E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1288978E-04 0.4248268E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2846384E-05 0.5721116E-05 0.0000000E+00 Chg. balance for solid moles: 0.3607E-17 Mass of aqueous solution: 0.121461E+04 g Temperature = 570.00 C Pressure = 1220.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3229E-03 -3.491 0.4396E-01 -1.357 0.7497 0.1484E-01 annite 0.9935E-06 -6.003 0.5086E-03 -3.294 0.8673E-02 0.1533E-03 phlogopite 0.2096E-05 -5.679 0.8745E-03 -3.058 0.1491E-01 0.3135E-03 biotite-Mn 0.5692E-07 -7.245 0.2898E-04 -4.538 0.4943E-03 0.8688E-05 apatite-OH 0.1907E-05 -5.720 0.9579E-03 -3.019 0.1634E-01 0.3044E-03 microcline 0.6775E-03 -3.169 0.1886 -0.725 3.216 0.7366E-01 pyrite 0.4272E-02 -2.369 0.5125 -0.290 8.740 0.1023 quartz 0.8211E-01 -1.086 4.933 0.693 84.13 1.863 barite 0.4248E-04 -4.372 0.9915E-02 -2.004 0.1691 0.2213E-02 chalcopyrite 0.2916E-03 -3.535 0.5350E-01 -1.272 0.9125 0.1249E-01 sphalerite 0.1230E-02 -2.910 0.1198 -0.921 2.044 0.2930E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3158E+00 0.3158E+00 1.0000 -0.501 phlogopite 0.6661E+00 0.6661E+00 1.0000 -0.176 biotite-Mn 0.1809E-01 0.1809E-01 1.0000 -1.742 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.863611 g Volume = 2.098441 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.65 -14.65 0.00 0.000 0.00000E+00 24 annite 0.31 0.31 0.00 0.000 0.23344E-10 25 phlogopite 4.94 4.94 0.00 0.000 -0.10280E-10 26 biotite-Mn 9.44 9.44 0.00 0.000 -0.68534E-11 30 apatite-OH -53.14 -53.14 0.00 0.000 0.27414E-10 115 microcline -4.90 -4.90 0.00 0.000 -0.68534E-11 140 pyrite -21.63 -21.63 0.00 0.000 0.13707E-10 144 quartz -1.22 -1.22 0.00 0.000 0.00000E+00 237 barite -15.79 -15.79 0.00 0.000 0.00000E+00 240 chalcopyrite -23.26 -23.26 0.00 0.000 0.13707E-10 255 sphalerite -10.87 -10.87 0.00 0.000 0.68534E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.27 -0.273 0.10530E+04 2.813 2 CO2,gas -9.83 -11.47 -1.64 -0.546 0.63140E+04 1.450 3 CH4,gas 6.88 -4.01 -10.90 -2.724 0.42035E+05 -7.809 4 H2,gas 5.92 1.86 -4.06 -2.319 0.15656E+05 -0.972 5 H2S,gas -8.19 -10.50 -2.31 -1.155 0.89085E+04 0.777 6 CO,gas -3.68 -9.61 -5.92 -1.823 0.22854E+05 -2.837 7 SO3,gas -7.41 -17.96 -10.55 -2.639 0.40722E+05 -7.469 8 O2,gas 16.70 -3.73 -20.43 -13.622 0.78831E+05 -17.346 9 HCl,gas -6.04 -7.45 -1.41 -0.703 0.54243E+04 -1.406 10 acmite 3.64 2.15 -1.49 -0.155 0.57498E+04 12 akimotoite 6.08 1.89 -4.19 -0.839 0.16180E+05 13 akimotoite-Fe 3.98 0.02 -3.96 -0.791 0.15267E+05 14 albite-high -4.31 -4.43 -0.12 -0.009 0.45550E+03 15 albite -4.30 -4.43 -0.13 -0.010 0.50395E+03 16 almandine -8.39 -10.06 -1.66 -0.083 0.64221E+04 17 pyrope -1.74 -4.46 -2.72 -0.136 0.10489E+05 18 analcite -2.26 -3.21 -0.96 -0.106 0.36945E+04 19 andalusite -10.84 -11.33 -0.49 -0.049 0.19077E+04 20 andradite 11.58 6.91 -4.67 -0.243 0.18017E+05 21 grossular 1.17 -3.82 -5.00 -0.250 0.19275E+05 27 anorthite -8.55 -9.24 -0.69 -0.053 0.26614E+04 28 anthophyllite 14.29 11.98 -2.31 -0.062 0.89202E+04 29 anthophyllite-Fe 1.62 -1.09 -2.71 -0.073 0.10442E+05 31 apatite-OH-zs -50.98 -53.14 -2.16 -0.166 0.83284E+04 32 apatite-Cl-zs -57.38 -60.59 -3.21 -0.267 0.12384E+05 33 aragonite -4.57 -8.15 -3.58 -1.194 0.13821E+05 34 brucite 5.37 3.10 -2.27 -0.453 0.87441E+04 35 calcite -4.67 -8.15 -3.48 -1.160 0.13424E+05 36 carnegieite-low -0.23 -1.99 -1.76 -0.252 0.67966E+04 37 carnegieite-high -0.15 -1.99 -1.84 -0.263 0.70932E+04 38 carpholite-Mg -7.43 -9.45 -2.02 -0.135 0.78123E+04 39 carpholite-Fe -8.79 -11.32 -2.53 -0.169 0.97609E+04 40 celadonite -0.91 -3.02 -2.11 -0.124 0.81406E+04 41 celadonite-Fe -2.32 -4.89 -2.56 -0.151 0.98954E+04 42 chrysotile 9.33 6.87 -2.46 -0.205 0.94878E+04 44 clinochlore 3.25 1.75 -1.50 -0.047 0.57819E+04 45 daphnite -3.85 -7.58 -3.74 -0.117 0.14419E+05 48 chloritoid-Mg -6.89 -8.23 -1.34 -0.089 0.51690E+04 49 chloritoid-Fe -8.83 -10.10 -1.26 -0.084 0.48713E+04 50 chloritoid-Mn -6.68 -8.29 -1.61 -0.108 0.62219E+04 52 coesite -0.93 -1.22 -0.29 -0.096 0.11087E+04 53 cordierite-H -19.24 -20.12 -0.87 -0.031 0.33758E+04 54 cordierite-Fe -21.83 -23.85 -2.02 -0.070 0.78054E+04 55 cordierite-Mn -17.45 -20.25 -2.80 -0.096 0.10788E+05 56 corundum -9.45 -10.11 -0.67 -0.061 0.25792E+04 58 cristobalite -1.17 -1.22 -0.05 -0.016 0.17979E+03 59 cummingtonite 14.36 11.98 -2.38 -0.064 0.91728E+04 61 cymrite-K -2.62 -4.91 -2.29 -0.191 0.88314E+04 63 diaspore -4.22 -5.06 -0.84 -0.139 0.32278E+04 65 diopside 5.34 3.98 -1.36 -0.136 0.52298E+04 66 hedenbergite 3.91 2.12 -1.79 -0.179 0.69208E+04 68 eastonite -6.25 -7.59 -1.34 -0.052 0.51775E+04 69 enstatite 4.66 3.77 -0.89 -0.089 0.34454E+04 70 clinoenstatite-HiP 5.16 3.77 -1.39 -0.139 0.53505E+04 71 clinoenstatite 4.65 3.77 -0.88 -0.088 0.33858E+04 72 protoenstatite 4.80 3.77 -1.03 -0.103 0.39554E+04 73 epidote -4.65 -6.83 -2.18 -0.106 0.84214E+04 74 clinozoisite -9.57 -12.20 -2.63 -0.119 0.10129E+05 75 epidote-Fe 1.95 -1.47 -3.42 -0.178 0.13206E+05 76 fayalite 2.20 1.26 -0.95 -0.135 0.36489E+04 77 ferrosilite 1.08 0.04 -1.04 -0.104 0.40168E+04 78 forsterite 6.20 4.99 -1.21 -0.173 0.46794E+04 79 gedrite -9.85 -12.02 -2.17 -0.059 0.83641E+04 81 gibbsite -2.60 -5.06 -2.46 -0.351 0.94889E+04 82 glaucophane 1.11 -1.99 -3.10 -0.084 0.11966E+05 83 glaucophane-Fe -2.95 -7.59 -4.63 -0.125 0.17881E+05 84 goethite 1.12 0.31 -0.82 -0.177 0.31594E+04 86 greenalite 4.45 1.27 -3.17 -0.265 0.12247E+05 87 grunerite 2.17 -1.09 -3.26 -0.088 0.12570E+05 88 halite -1.12 -3.16 -2.05 -1.023 0.78906E+04 89 hematite 0.71 0.61 -0.10 -0.012 0.36798E+03 90 heulandite -12.29 -15.34 -3.06 -0.139 0.11793E+05 91 hercynite -7.76 -8.88 -1.12 -0.074 0.43053E+04 94 jadeite -1.57 -3.21 -1.64 -0.164 0.63234E+04 96 kalsilite -0.85 -2.47 -1.61 -0.230 0.62165E+04 97 kaolinite -9.82 -12.56 -2.74 -0.249 0.10568E+05 98 kyanite -10.68 -11.33 -0.66 -0.066 0.25284E+04 100 laumontite -8.11 -11.68 -3.57 -0.238 0.13770E+05 101 lawsonite -5.78 -9.24 -3.46 -0.231 0.13358E+05 102 leucite -2.73 -3.69 -0.95 -0.095 0.36703E+04 104 lizardite 9.51 6.87 -2.64 -0.220 0.10169E+05 105 magnesite -5.45 -8.37 -2.91 -0.971 0.11243E+05 106 magnetite 1.88 1.85 -0.02 -0.002 0.95630E+02 107 minnesotaite 0.75 -1.16 -1.91 -0.113 0.73853E+04 108 minnesotaite-Mg 6.73 4.44 -2.29 -0.135 0.88487E+04 109 magnesioferrite 4.95 3.72 -1.23 -0.100 0.47362E+04 111 manganosite 5.34 3.04 -2.30 -0.574 0.88614E+04 112 margarite -17.52 -19.35 -1.83 -0.073 0.70680E+04 116 monticellite 8.71 5.20 -3.51 -0.501 0.13534E+05 118 mullite-Si -10.10 -11.33 -1.24 -0.124 0.47752E+04 119 muscovite -14.22 -15.02 -0.81 -0.047 0.31092E+04 120 paragonite -13.53 -14.55 -1.01 -0.060 0.39145E+04 121 nepheline -0.53 -1.99 -1.47 -0.209 0.56538E+04 122 osumilite(2) -13.46 -15.46 -2.00 -0.042 0.77081E+04 123 osumilite-Fe -28.79 -31.19 -2.40 -0.050 0.92744E+04 124 pargasite 4.82 0.85 -3.97 -0.104 0.15318E+05 125 periclase 5.56 3.11 -2.45 -0.613 0.94676E+04 126 periclase-Fe 2.98 1.24 -1.74 -0.435 0.67204E+04 127 perovskite-Al -7.72 -10.11 -2.39 -0.218 0.92387E+04 132 phlogopite-Na 5.81 4.88 -0.92 -0.051 0.35681E+04 134 prehnite -3.87 -7.14 -3.27 -0.192 0.12625E+05 135 prehnite-Fe 1.44 -1.78 -3.22 -0.194 0.12429E+05 138 px-Mg-tschermaks -6.30 -8.23 -1.93 -0.138 0.74392E+04 139 px-Ca-tschermaks -5.44 -8.02 -2.58 -0.184 0.99352E+04 141 pyrrhotite -8.63 -9.26 -0.63 -0.211 0.24397E+04 142 pyrrhotiteFe0.875 -9.39 -9.65 -0.26 -0.094 0.98637E+03 143 pyrophyllite -13.63 -15.00 -1.37 -0.086 0.52788E+04 146 riebeckite 5.79 3.14 -2.65 -0.073 0.10222E+05 147 ringwoodite-Fe 3.20 1.26 -1.94 -0.277 0.74867E+04 148 ringwoodite-Mg 9.35 4.99 -4.36 -0.622 0.16809E+05 149 rhodochrosite -5.41 -8.43 -3.02 -1.008 0.11662E+05 150 rhodonite 2.50 1.82 -0.68 -0.135 0.26122E+04 151 sanidine -4.37 -4.90 -0.54 -0.041 0.20684E+04 153 siderite -7.29 -10.23 -2.94 -0.981 0.11352E+05 154 sillimanite -10.81 -11.33 -0.53 -0.053 0.20420E+04 156 spinel -5.59 -7.01 -1.42 -0.095 0.54861E+04 162 stilpnomelane-Fe -7.08 -11.78 -4.70 -0.140 0.18139E+05 163 stilpnomelane-Mg -0.26 -2.45 -2.19 -0.065 0.84623E+04 164 stishovite 1.72 -1.22 -2.94 -0.981 0.11358E+05 165 sudoite-Fe -17.25 -21.42 -4.17 -0.134 0.16082E+05 166 sudoite -15.02 -17.68 -2.67 -0.086 0.10291E+05 167 sulfur -10.86 -12.37 -1.50 -0.463 0.57993E+04 168 sylvite -1.02 -3.63 -2.61 -1.306 0.10078E+05 169 talc 5.01 4.44 -0.57 -0.034 0.22010E+04 170 talc-Fe 2.15 -1.16 -3.31 -0.195 0.12772E+05 171 talc-tschermaks -5.88 -7.56 -1.68 -0.099 0.64880E+04 173 tephroite 6.49 4.86 -1.62 -0.232 0.62669E+04 176 topaz-H -8.75 -11.34 -2.59 -0.235 0.99891E+04 177 tremolite 15.04 12.40 -2.64 -0.071 0.10190E+05 179 troilite-low -8.54 -9.26 -0.73 -0.242 0.27985E+04 180 tschermakite -8.33 -11.60 -3.27 -0.088 0.12624E+05 183 wadsleyite-Fe 3.05 1.26 -1.79 -0.256 0.69121E+04 184 wadsleyite-Mg 8.41 4.99 -3.42 -0.488 0.13183E+05 185 wairakite -9.97 -11.68 -1.71 -0.100 0.65841E+04 186 walstromite 4.59 2.10 -2.49 -0.498 0.96015E+04 187 wollastonite 4.17 2.10 -2.07 -0.414 0.79886E+04 188 pseudo-wollastonite 4.28 2.10 -2.19 -0.437 0.84333E+04 189 zoisite -9.63 -12.20 -2.57 -0.117 0.99212E+04 192 beidellite-Ca -14.01 -15.71 -1.70 -0.105 0.65674E+04 193 beidellite-H -14.03 -16.26 -2.23 -0.142 0.86038E+04 194 beidellite-K -12.98 -15.00 -2.02 -0.124 0.78010E+04 195 beidellite-Mg -14.28 -15.75 -1.47 -0.091 0.56724E+04 196 beidellite-Na -12.92 -14.85 -1.93 -0.118 0.74270E+04 197 bornite -54.10 -54.54 -0.44 -0.033 0.16922E+04 199 chalcocite -14.11 -15.64 -1.53 -0.382 0.58916E+04 200 covellite -12.59 -14.00 -1.41 -0.538 0.54469E+04 202 montmorillonite-Ca -10.47 -11.75 -1.28 -0.079 0.49488E+04 203 montmorillonite-K -9.73 -11.04 -1.32 -0.081 0.50846E+04 204 montmorillonite-Mg -10.69 -11.79 -1.10 -0.068 0.42272E+04 205 montmorillonite-Na -9.38 -10.89 -1.51 -0.092 0.58078E+04 206 nontronite-Ca -3.60 -4.99 -1.38 -0.090 0.53320E+04 207 nontronite-H -3.63 -5.53 -1.90 -0.128 0.73414E+04 208 nontronite-K -2.58 -4.28 -1.70 -0.109 0.65579E+04 209 nontronite-Mg -3.83 -5.02 -1.19 -0.077 0.45881E+04 210 nontronite-Na -2.51 -4.12 -1.61 -0.103 0.61966E+04 215 gypsum -12.42 -14.65 -2.23 -0.558 0.86120E+04 232 alabandite -6.36 -7.46 -1.11 -0.368 0.42639E+04 234 anglesite -14.89 -17.29 -2.41 -1.204 0.92914E+04 238 boehmite -3.93 -5.06 -1.12 -0.187 0.43398E+04 242 copper,native 1.75 -1.64 -3.38 -1.176 0.13049E+05 244 ferrous-oxide 2.06 1.24 -0.82 -0.205 0.31572E+04 245 galena -9.73 -9.83 -0.11 -0.035 0.40545E+03 246 silver,native 0.49 -3.38 -3.87 -1.344 0.14913E+05 248 litharge 5.28 0.67 -4.61 -1.154 0.17802E+05 256 wurtzite -10.07 -10.87 -0.80 -0.267 0.30887E+04 257 zincite 2.16 -0.37 -2.53 -0.633 0.97671E+04 258 an20ab80 -5.37 -5.39 -0.03 -0.002 0.97276E+02 259 an25ab75 -5.61 -5.63 -0.03 -0.002 0.10044E+03 260 an30ab70 -5.84 -5.87 -0.03 -0.003 0.12844E+03 261 tr.625ac.25prg.125 9.58 8.63 -0.95 -0.026 0.36765E+04 Calculations done for 570.0000 Deg. C; 1220.0000 bar Temperature changed by -1.000 degrees to 569.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 33 Loop limit = 500 Temperature = 569.00 C Pressure = 1203.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5511E+02 kg liquid = 0.9928E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9966 Stoichiometric ionic strength = .3282022E+01 Osmotic coef. = 0.0000 True ionic strength = .1685448E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.57166E-05 -5.2429 0.12550E-05 -5.9014 0.21954E+00 -0.6585 2 H2O 0.99656E+00 -0.0015 0.99656E+00 -0.0015 3 Cl- 0.14185E+00 -0.8482 0.26860E-01 -1.5709 0.18935E+00 -0.7227 4 SO4-- 0.21532E-03 -3.6669 0.62770E-06 -6.2022 0.29151E-02 -2.5353 5 HCO3- 0.12158E-04 -4.9151 0.24807E-05 -5.6054 0.20403E+00 -0.6903 6 HS- 0.12421E-03 -3.9058 0.23715E-04 -4.6250 0.19093E+00 -0.7191 7 H4SiO4 0.58607E-01 -1.2320 0.58607E-01 -1.2320 0.10000E+01 0.0000 8 Al+++ 0.12286E-16 -16.9106 0.19081E-22 -22.7194 0.15531E-05 -5.8088 9 Ca++ 0.14287E-05 -5.8451 0.33428E-08 -8.4759 0.23398E-02 -2.6308 10 Mg++ 0.11084E-05 -5.9553 0.21305E-08 -8.6715 0.19221E-02 -2.7162 11 Fe++ 0.13922E-07 -7.8563 0.28128E-10 -10.5509 0.20204E-02 -2.6946 12 K+ 0.39423E-01 -1.4043 0.82440E-02 -2.0839 0.20912E+00 -0.6796 13 Na+ 0.12737E+00 -0.8949 0.24403E-01 -1.6126 0.19159E+00 -0.7176 14 Mn++ 0.89064E-06 -6.0503 0.18662E-08 -8.7290 0.20954E-02 -2.6787 15 Zn++ 0.34168E-09 -9.4664 0.69034E-12 -12.1609 0.20204E-02 -2.6946 16 Cu+ 0.17585E-07 -7.7548 0.33603E-08 -8.4736 0.19108E+00 -0.7188 17 Pb++ 0.28915E-08 -8.5389 0.75833E-11 -11.1201 0.26226E-02 -2.5813 18 Ag+ 0.30502E-09 -9.5157 0.62782E-10 -10.2022 0.20583E+00 -0.6865 19 Ba++ 0.83724E-07 -7.0771 0.23600E-09 -9.6271 0.28188E-02 -2.5499 20 HPO4-- 0.11319E-08 -8.9462 0.33165E-11 -11.4793 0.29299E-02 -2.5331 21 HSiO3- 0.15694E-05 -5.8043 0.29717E-06 -6.5270 0.18935E+00 -0.7227 22 Ca(HSiO3)+ 0.60611E-08 -8.2174 0.12787E-08 -8.8932 0.21097E+00 -0.6758 23 Mg(HSiO3)+ 0.11616E-08 -8.9350 0.24505E-09 -9.6107 0.21097E+00 -0.6758 24 NaHSiO3,aq 0.18066E-05 -5.7431 0.18066E-05 -5.7431 0.10000E+01 0.0000 28 AgCl,aq 0.99453E-07 -7.0024 0.99453E-07 -7.0024 0.10000E+01 0.0000 29 AgCl2- 0.51553E-05 -5.2877 0.97617E-06 -6.0105 0.18935E+00 -0.7227 30 AgCl3-2 0.19300E-05 -5.7144 0.52059E-08 -8.2835 0.26974E-02 -2.5691 31 AgCl4-3 0.15715E-05 -5.8037 0.21236E-11 -11.6729 0.13514E-05 -5.8692 34 Ag(HS),aq 0.13729E-08 -8.8624 0.13729E-08 -8.8624 0.10000E+01 0.0000 35 Ag(HS)2- 0.59015E-08 -8.2290 0.11175E-08 -8.9518 0.18935E+00 -0.7227 38 HAlO2,aq 0.41494E-08 -8.3820 0.41494E-08 -8.3820 0.10000E+01 0.0000 39 AlO2- 0.13686E-04 -4.8637 0.22704E-05 -5.6439 0.16589E+00 -0.7802 41 Ba(HCO3)+ 0.31750E-06 -6.4983 0.69713E-07 -7.1567 0.21957E+00 -0.6584 42 BaCl+ 0.11938E-04 -4.9231 0.25187E-05 -5.5988 0.21097E+00 -0.6758 43 CH4,aq 0.16578E-08 -8.7805 0.19807E-08 -8.7032 0.11947E+01 0.0773 48 CO,aq 0.59407E-03 -3.2262 0.59407E-03 -3.2262 0.10000E+01 0.0000 49 CO2,aq 0.26747E+01 0.4273 0.31956E+01 0.5046 0.11947E+01 0.0773 50 CO3-2 0.40793E-10 -10.3894 0.11003E-12 -12.9585 0.26974E-02 -2.5691 51 CaCO3,aq 0.11608E-10 -10.9352 0.11608E-10 -10.9352 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.15873E-06 -6.7993 0.33487E-07 -7.4751 0.21097E+00 -0.6758 53 CaCl+ 0.98182E-04 -4.0080 0.20714E-04 -4.6837 0.21097E+00 -0.6758 54 CaCl2,aq 0.90710E-04 -4.0423 0.90710E-04 -4.0423 0.10000E+01 0.0000 55 CaOH+ 0.18385E-06 -6.7355 0.38786E-07 -7.4113 0.21097E+00 -0.6758 56 CaSO4,aq 0.15459E-06 -6.8108 0.15459E-06 -6.8108 0.10000E+01 0.0000 57 HCl,aq 0.24146E-02 -2.6172 0.24146E-02 -2.6172 0.10000E+01 0.0000 66 CuCl,aq 0.23144E-04 -4.6356 0.23144E-04 -4.6356 0.10000E+01 0.0000 67 CuCl2- 0.82017E-04 -4.0861 0.15530E-04 -4.8088 0.18935E+00 -0.7227 68 CuCl3-2 0.16513E-05 -5.7822 0.44542E-08 -8.3512 0.26974E-02 -2.5691 74 FeCl+ 0.29666E-06 -6.5277 0.62587E-07 -7.2035 0.21097E+00 -0.6758 75 FeCl2,aq 0.40587E-02 -2.3916 0.40587E-02 -2.3916 0.10000E+01 0.0000 77 FeO,aq 0.70143E-07 -7.1540 0.70143E-07 -7.1540 0.10000E+01 0.0000 78 FeOH+ 0.24912E-07 -7.6036 0.52557E-08 -8.2794 0.21097E+00 -0.6758 79 HFeO2- 0.85616E-08 -8.0674 0.16212E-08 -8.7902 0.18935E+00 -0.7227 82 FeO2- 0.53761E-08 -8.2695 0.10180E-08 -8.9923 0.18935E+00 -0.7227 83 HFeO2,aq 0.29094E-09 -9.5362 0.29094E-09 -9.5362 0.10000E+01 0.0000 84 H2,aq 0.46897E-02 -2.3289 0.56030E-02 -2.2516 0.11947E+01 0.0773 85 KCl,aq 0.68384E-01 -1.1650 0.68384E-01 -1.1650 0.10000E+01 0.0000 86 KHSO4,aq 0.13346E-01 -1.8747 0.13346E-01 -1.8747 0.10000E+01 0.0000 87 KOH,aq 0.12975E-05 -5.8869 0.12975E-05 -5.8869 0.10000E+01 0.0000 88 KSO4- 0.44778E-02 -2.3489 0.84789E-03 -3.0717 0.18935E+00 -0.7227 90 Mg(HCO3)+ 0.36292E-07 -7.4402 0.76566E-08 -8.1160 0.21097E+00 -0.6758 91 MgCl+ 0.12904E-04 -4.8893 0.27225E-05 -5.5650 0.21097E+00 -0.6758 92 MgOH+ 0.49734E-06 -6.3033 0.10492E-06 -6.9791 0.21097E+00 -0.6758 94 MnO,aq 0.76286E-07 -7.1176 0.76286E-07 -7.1176 0.10000E+01 0.0000 95 MnOH+ 0.18869E-06 -6.7242 0.39808E-07 -7.4000 0.21097E+00 -0.6758 97 HMnO2- 0.38795E-10 -10.4112 0.73461E-11 -11.1339 0.18935E+00 -0.7227 100 MnCl+ 0.11564E-02 -2.9369 0.24396E-03 -3.6127 0.21097E+00 -0.6758 101 MnSO4,aq 0.98229E-07 -7.0078 0.98229E-07 -7.0078 0.10000E+01 0.0000 102 NaCl,aq 0.43124E+00 -0.3653 0.43124E+00 -0.3653 0.10000E+01 0.0000 103 NaOH,aq 0.17662E-05 -5.7529 0.17662E-05 -5.7529 0.10000E+01 0.0000 105 OH- 0.79870E-05 -5.0976 0.13249E-05 -5.8778 0.16589E+00 -0.7802 110 HPO3-2 0.10659E-10 -10.9723 0.28751E-13 -13.5413 0.26974E-02 -2.5691 111 H3PO3,aq 0.10745E-09 -9.9688 0.10745E-09 -9.9688 0.10000E+01 0.0000 112 H2PO3- 0.23257E-08 -8.6334 0.44039E-09 -9.3562 0.18935E+00 -0.7227 113 H3PO4,aq 0.10647E-05 -5.9728 0.10647E-05 -5.9728 0.10000E+01 0.0000 114 H2PO4- 0.13569E-05 -5.8675 0.27017E-06 -6.5684 0.19911E+00 -0.7009 116 H4P2O7,aq 0.10417E-09 -9.9823 0.10417E-09 -9.9823 0.10000E+01 0.0000 117 H3P2O7- 0.80611E-09 -9.0936 0.15264E-09 -9.8163 0.18935E+00 -0.7227 118 H2P2O7-2 0.21165E-06 -6.6744 0.57091E-09 -9.2434 0.26974E-02 -2.5691 119 HP2O7-3 0.17750E-07 -7.7508 0.23986E-13 -13.6200 0.13514E-05 -5.8692 121 PbCl+ 0.14427E-05 -5.8408 0.30436E-06 -6.5166 0.21097E+00 -0.6758 122 PbCl2,aq 0.86249E-04 -4.0642 0.86249E-04 -4.0642 0.10000E+01 0.0000 123 PbCl3- 0.10286E-03 -3.9877 0.19477E-04 -4.7105 0.18935E+00 -0.7227 124 PbCl4-2 0.19636E-04 -4.7069 0.52967E-07 -7.2760 0.26974E-02 -2.5691 125 PbO,aq 0.59993E-08 -8.2219 0.59993E-08 -8.2219 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11936E-03 -3.9231 0.11936E-03 -3.9231 0.10000E+01 0.0000 128 Pb(HS)3- 0.13075E-04 -4.8836 0.24758E-05 -5.6063 0.18935E+00 -0.7227 129 H2S,aq 0.10557E+01 0.0235 0.12612E+01 0.1008 0.11947E+01 0.0773 130 S2-2 0.13156E-07 -7.8809 0.35488E-10 -10.4499 0.26974E-02 -2.5691 131 S3-2 0.12293E-08 -8.9103 0.33160E-11 -11.4794 0.26974E-02 -2.5691 132 S3- 0.11994E-01 -1.9210 0.22711E-02 -2.6438 0.18935E+00 -0.7227 133 S4-2 0.97226E-10 -10.0122 0.26226E-12 -12.5813 0.26974E-02 -2.5691 135 SO2,aq 0.29174E+00 -0.5350 0.29174E+00 -0.5350 0.10000E+01 0.0000 136 SO3-2 0.62283E-09 -9.2056 0.26689E-11 -11.5737 0.42851E-02 -2.3680 137 HSO3- 0.28378E-03 -3.5470 0.53735E-04 -4.2697 0.18935E+00 -0.7227 138 HSO4- 0.87776E-02 -2.0566 0.19023E-02 -2.7207 0.21672E+00 -0.6641 140 S2O3-2 0.49916E-06 -6.3018 0.13464E-08 -8.8708 0.26974E-02 -2.5691 141 HS2O3- 0.42032E-06 -6.3764 0.79589E-07 -7.0991 0.18935E+00 -0.7227 142 H2S2O3,aq 0.29403E-07 -7.5316 0.29403E-07 -7.5316 0.10000E+01 0.0000 150 S4O6-2 0.45175E-09 -9.3451 0.12185E-11 -11.9142 0.26974E-02 -2.5691 152 ZnCl+ 0.21306E-03 -3.6715 0.44949E-04 -4.3473 0.21097E+00 -0.6758 153 ZnCl2,aq 0.76067E-03 -3.1188 0.76067E-03 -3.1188 0.10000E+01 0.0000 154 ZnCl3- 0.64702E-04 -4.1891 0.12252E-04 -4.9118 0.18935E+00 -0.7227 155 ZnO,aq 0.32281E-07 -7.4911 0.32281E-07 -7.4911 0.10000E+01 0.0000 156 ZnOH+ 0.13746E-05 -5.8618 0.28999E-06 -6.5376 0.21097E+00 -0.6758 158 HZnO2- 0.25594E-09 -9.5919 0.48463E-10 -10.3146 0.18935E+00 -0.7227 Charge balance for all species = 0.2549E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5716568E-05 0.4296380E+01 0.3540021E+04 0.0000 2 H2O 0.1000000E+01 0.5251594E+02 0.7733946E+06 0.0000 3 Cl- 0.1418506E+00 0.6561729E+00 0.1901690E+05 4.3305 4 SO4-- 0.2153228E-03 0.2520137E+00 0.1978985E+05 5.6005 5 HCO3- 0.1215841E-04 0.2675325E+01 0.1334435E+06 0.2959 6 HS- 0.1242088E-03 0.1158878E+01 0.3133047E+05 1.2764 7 H4SiO4 0.5860739E-01 0.5861077E-01 0.4605099E+04 -1.2320 8 Al+++ 0.1228552E-16 0.1369062E-04 0.3019659E+00 -5.0153 9 Ca++ 0.1428673E-05 0.1908245E-03 0.6251853E+01 3.3268 10 Mg++ 0.1108426E-05 0.1454765E-04 0.2891225E+00 3.1312 11 Fe++ 0.1392205E-07 0.4059089E-02 0.1853092E+03 1.2519 12 K+ 0.3942282E-01 0.1256314E+00 0.4015741E+04 3.8175 13 Na+ 0.1273659E+00 0.5586109E+00 0.1049816E+05 4.2888 14 Mn++ 0.8906388E-06 0.1157640E-02 0.5198942E+02 3.0737 15 Zn++ 0.3416815E-09 0.1039836E-02 0.5556635E+02 -0.3582 16 Cu+ 0.1758537E-07 0.1068295E-03 0.5548901E+01 -2.5723 17 Pb++ 0.2891506E-08 0.3426332E-03 0.5803190E+02 0.6826 18 Ag+ 0.3050165E-09 0.8763778E-05 0.7727883E+00 -4.3008 19 Ba++ 0.8372445E-07 0.1233969E-04 0.1385383E+01 2.1756 20 HPO4-- 0.1131948E-08 0.2885829E-05 0.2264203E+00 0.3234 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265526E+01 -.3163710E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5213880E+02 -.1740199E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2502039E+00 0.1518861E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1150556E+01 0.9588028E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.5818987E-01 0.8540445E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1359231E-04 0.6809472E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1894541E-03 0.3384557E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1444317E-04 0.6233478E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.4029939E-02 0.4736814E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247292E+00 0.6809472E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149327E-02 0.1731152E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1032369E-02 0.1266966E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1060623E-03 0.2935474E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1225107E-04 0.4312138E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2865105E-05 0.5702395E-05 0.0000000E+00 Chg. balance for solid moles: -.1086E-17 Mass of aqueous solution: 0.121451E+04 g Temperature = 569.00 C Pressure = 1203.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3290E-03 -3.483 0.4478E-01 -1.349 0.7509 0.1511E-01 annite 0.9631E-06 -6.016 0.4930E-03 -3.307 0.8266E-02 0.1486E-03 phlogopite 0.2078E-05 -5.682 0.8671E-03 -3.062 0.1454E-01 0.3109E-03 biotite-Mn 0.5771E-07 -7.239 0.2938E-04 -4.532 0.4926E-03 0.8807E-05 apatite-OH 0.1901E-05 -5.721 0.9548E-03 -3.020 0.1601E-01 0.3034E-03 microcline 0.6778E-03 -3.169 0.1887 -0.724 3.163 0.7370E-01 pyrite 0.4440E-02 -2.353 0.5328 -0.273 8.932 0.1063 quartz 0.8336E-01 -1.079 5.008 0.700 83.97 1.891 barite 0.4312E-04 -4.365 0.1006E-01 -1.997 0.1687 0.2247E-02 chalcopyrite 0.2935E-03 -3.532 0.5387E-01 -1.269 0.9031 0.1257E-01 sphalerite 0.1267E-02 -2.897 0.1234 -0.909 2.070 0.3019E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3108E+00 0.3108E+00 1.0000 -0.507 phlogopite 0.6706E+00 0.6706E+00 1.0000 -0.174 biotite-Mn 0.1862E-01 0.1862E-01 1.0000 -1.730 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.964293 g Volume = 2.132268 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.68 -14.68 0.00 0.000 0.00000E+00 24 annite 0.38 0.38 0.00 0.000 -0.38505E-11 25 phlogopite 5.02 5.02 0.00 0.000 -0.17113E-10 26 biotite-Mn 9.52 9.52 0.00 0.000 0.00000E+00 30 apatite-OH -53.21 -53.21 0.00 0.000 -0.27381E-10 115 microcline -4.89 -4.89 0.00 0.000 0.34226E-11 140 pyrite -21.67 -21.67 0.00 0.000 0.13691E-10 144 quartz -1.23 -1.23 0.00 0.000 0.00000E+00 237 barite -15.83 -15.83 0.00 0.000 0.00000E+00 240 chalcopyrite -23.31 -23.31 0.00 0.000 0.00000E+00 255 sphalerite -10.88 -10.88 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.27 -0.272 0.10484E+04 2.808 2 CO2,gas -9.86 -11.51 -1.64 -0.548 0.63319E+04 1.437 3 CH4,gas 6.88 -4.03 -10.91 -2.727 0.42037E+05 -7.829 4 H2,gas 5.93 1.87 -4.06 -2.320 0.15644E+05 -0.979 5 H2S,gas -8.22 -10.53 -2.31 -1.155 0.89005E+04 0.771 6 CO,gas -3.70 -9.64 -5.94 -1.826 0.22873E+05 -2.855 7 SO3,gas -7.44 -18.00 -10.57 -2.642 0.40722E+05 -7.487 8 O2,gas 16.72 -3.74 -20.46 -13.639 0.78835E+05 -17.378 9 HCl,gas -6.05 -7.47 -1.42 -0.709 0.54675E+04 -1.419 10 acmite 3.64 2.15 -1.49 -0.155 0.57528E+04 12 akimotoite 6.10 1.90 -4.20 -0.839 0.16170E+05 13 akimotoite-Fe 3.99 0.02 -3.97 -0.794 0.15294E+05 14 albite-high -4.30 -4.42 -0.12 -0.009 0.46561E+03 15 albite -4.28 -4.42 -0.13 -0.010 0.51055E+03 16 almandine -8.27 -9.97 -1.70 -0.085 0.65584E+04 17 pyrope -1.60 -4.33 -2.73 -0.137 0.10521E+05 18 analcite -2.23 -3.19 -0.96 -0.107 0.37031E+04 19 andalusite -10.76 -11.26 -0.51 -0.051 0.19596E+04 20 andradite 11.62 6.92 -4.70 -0.244 0.18111E+05 27 anorthite -8.46 -9.17 -0.71 -0.055 0.27328E+04 28 anthophyllite 14.37 12.07 -2.30 -0.062 0.88455E+04 29 anthophyllite-Fe 1.67 -1.08 -2.75 -0.074 0.10611E+05 31 apatite-OH-zs -51.05 -53.21 -2.16 -0.166 0.83309E+04 32 apatite-Cl-zs -57.47 -60.68 -3.22 -0.268 0.12393E+05 33 aragonite -4.59 -8.18 -3.59 -1.198 0.13850E+05 34 brucite 5.39 3.13 -2.27 -0.453 0.87293E+04 35 calcite -4.69 -8.18 -3.49 -1.164 0.13452E+05 36 carnegieite-low -0.19 -1.96 -1.77 -0.252 0.68023E+04 37 carnegieite-high -0.12 -1.96 -1.84 -0.263 0.71011E+04 38 carpholite-Mg -7.33 -9.37 -2.04 -0.136 0.78428E+04 39 carpholite-Fe -8.70 -11.25 -2.55 -0.170 0.98278E+04 40 celadonite -0.88 -2.99 -2.11 -0.124 0.81268E+04 41 celadonite-Fe -2.29 -4.87 -2.57 -0.151 0.99202E+04 42 chrysotile 9.38 6.93 -2.45 -0.204 0.94435E+04 44 clinochlore 3.41 1.92 -1.49 -0.047 0.57517E+04 45 daphnite -3.70 -7.48 -3.78 -0.118 0.14571E+05 48 chloritoid-Mg -6.79 -8.14 -1.35 -0.090 0.52035E+04 49 chloritoid-Fe -8.73 -10.02 -1.28 -0.085 0.49391E+04 50 chloritoid-Mn -6.58 -8.19 -1.61 -0.107 0.62086E+04 52 coesite -0.94 -1.23 -0.29 -0.096 0.11094E+04 53 cordierite-H -19.06 -19.96 -0.90 -0.032 0.34624E+04 54 cordierite-Fe -21.65 -23.71 -2.06 -0.071 0.79538E+04 55 cordierite-Mn -17.28 -20.07 -2.80 -0.096 0.10773E+05 56 corundum -9.35 -10.04 -0.68 -0.062 0.26315E+04 58 cristobalite -1.18 -1.23 -0.05 -0.016 0.17988E+03 59 cummingtonite 14.44 12.07 -2.36 -0.064 0.90989E+04 61 cymrite-K -2.60 -4.89 -2.29 -0.191 0.88372E+04 63 diaspore -4.18 -5.02 -0.84 -0.141 0.32491E+04 65 diopside 5.36 4.00 -1.36 -0.136 0.52385E+04 66 hedenbergite 3.93 2.12 -1.81 -0.181 0.69660E+04 68 eastonite -6.09 -7.44 -1.35 -0.052 0.52038E+04 69 enstatite 4.69 3.80 -0.89 -0.089 0.34273E+04 70 clinoenstatite-HiP 5.19 3.80 -1.38 -0.138 0.53326E+04 71 clinoenstatite 4.67 3.80 -0.87 -0.087 0.33667E+04 72 protoenstatite 4.82 3.80 -1.02 -0.102 0.39367E+04 73 epidote -4.54 -6.76 -2.21 -0.107 0.85293E+04 74 clinozoisite -9.43 -12.09 -2.66 -0.121 0.10243E+05 75 epidote-Fe 2.03 -1.42 -3.45 -0.179 0.13306E+05 76 fayalite 2.23 1.27 -0.96 -0.137 0.37000E+04 77 ferrosilite 1.10 0.04 -1.06 -0.106 0.40691E+04 78 forsterite 6.24 5.03 -1.21 -0.173 0.46589E+04 79 gedrite -9.61 -11.80 -2.18 -0.059 0.84142E+04 81 gibbsite -2.55 -5.02 -2.47 -0.352 0.95067E+04 82 glaucophane 1.19 -1.90 -3.10 -0.084 0.11936E+05 83 glaucophane-Fe -2.88 -7.54 -4.66 -0.126 0.17959E+05 84 goethite 1.14 0.31 -0.82 -0.178 0.31774E+04 86 greenalite 4.48 1.29 -3.19 -0.266 0.12307E+05 87 grunerite 2.23 -1.08 -3.31 -0.089 0.12742E+05 88 halite -1.14 -3.18 -2.04 -1.022 0.78769E+04 89 hematite 0.74 0.63 -0.11 -0.013 0.40801E+03 90 heulandite -12.24 -15.32 -3.08 -0.140 0.11870E+05 91 hercynite -7.65 -8.78 -1.14 -0.076 0.43832E+04 94 jadeite -1.55 -3.19 -1.64 -0.164 0.63294E+04 96 kalsilite -0.82 -2.43 -1.61 -0.231 0.62186E+04 97 kaolinite -9.75 -12.50 -2.75 -0.250 0.10600E+05 98 kyanite -10.59 -11.26 -0.67 -0.067 0.25811E+04 100 laumontite -8.04 -11.63 -3.59 -0.239 0.13832E+05 101 lawsonite -5.69 -9.17 -3.48 -0.232 0.13420E+05 102 leucite -2.71 -3.66 -0.95 -0.095 0.36740E+04 104 lizardite 9.55 6.93 -2.63 -0.219 0.10120E+05 105 magnesite -5.46 -8.38 -2.92 -0.972 0.11241E+05 106 magnetite 1.92 1.88 -0.04 -0.003 0.16130E+03 107 minnesotaite 0.77 -1.17 -1.93 -0.114 0.74509E+04 108 minnesotaite-Mg 6.76 4.47 -2.29 -0.134 0.88068E+04 109 magnesioferrite 5.00 3.76 -1.24 -0.101 0.47667E+04 111 manganosite 5.36 3.07 -2.29 -0.571 0.88059E+04 112 margarite -17.34 -19.20 -1.86 -0.075 0.71848E+04 116 monticellite 8.74 5.23 -3.51 -0.502 0.13541E+05 118 mullite-Si -10.01 -11.26 -1.25 -0.125 0.48296E+04 119 muscovite -14.10 -14.92 -0.82 -0.048 0.31588E+04 120 paragonite -13.42 -14.45 -1.03 -0.061 0.39689E+04 121 nepheline -0.49 -1.96 -1.47 -0.210 0.56588E+04 122 osumilite(2) -13.36 -15.37 -2.01 -0.042 0.77323E+04 123 osumilite-Fe -28.61 -31.06 -2.45 -0.051 0.94309E+04 124 pargasite 5.02 1.03 -3.99 -0.105 0.15380E+05 125 periclase 5.58 3.13 -2.45 -0.614 0.94567E+04 126 periclase-Fe 3.00 1.25 -1.75 -0.438 0.67466E+04 127 perovskite-Al -7.62 -10.04 -2.41 -0.219 0.92914E+04 132 phlogopite-Na 5.89 4.97 -0.92 -0.051 0.35382E+04 134 prehnite -3.78 -7.07 -3.30 -0.194 0.12708E+05 135 prehnite-Fe 1.51 -1.74 -3.25 -0.195 0.12506E+05 138 px-Mg-tschermaks -6.19 -8.13 -1.94 -0.139 0.74839E+04 139 px-Ca-tschermaks -5.34 -7.94 -2.60 -0.185 0.10007E+05 141 pyrrhotite -8.64 -9.27 -0.64 -0.212 0.24565E+04 142 pyrrhotiteFe0.875 -9.40 -9.66 -0.26 -0.095 0.10003E+04 143 pyrophyllite -13.57 -14.95 -1.38 -0.086 0.53256E+04 146 riebeckite 5.80 3.12 -2.67 -0.074 0.10294E+05 147 ringwoodite-Fe 3.23 1.27 -1.96 -0.279 0.75361E+04 148 ringwoodite-Mg 9.39 5.03 -4.36 -0.622 0.16787E+05 149 rhodochrosite -5.42 -8.43 -3.01 -1.005 0.11614E+05 150 rhodonite 2.51 1.84 -0.66 -0.133 0.25569E+04 151 sanidine -4.35 -4.89 -0.54 -0.041 0.20680E+04 153 siderite -7.30 -10.25 -2.95 -0.985 0.11385E+05 154 sillimanite -10.72 -11.26 -0.54 -0.054 0.20946E+04 156 spinel -5.47 -6.91 -1.43 -0.096 0.55276E+04 162 stilpnomelane-Fe -6.97 -11.72 -4.74 -0.142 0.18280E+05 163 stilpnomelane-Mg -0.13 -2.32 -2.19 -0.065 0.84393E+04 164 stishovite 1.72 -1.23 -2.95 -0.982 0.11358E+05 165 sudoite-Fe -17.05 -21.26 -4.21 -0.136 0.16236E+05 166 sudoite -14.81 -17.50 -2.69 -0.087 0.10371E+05 167 sulfur -10.89 -12.39 -1.50 -0.462 0.57906E+04 168 sylvite -1.04 -3.65 -2.61 -1.305 0.10058E+05 169 talc 5.03 4.47 -0.56 -0.033 0.21607E+04 170 talc-Fe 2.17 -1.17 -3.33 -0.196 0.12839E+05 171 talc-tschermaks -5.77 -7.46 -1.69 -0.099 0.65114E+04 173 tephroite 6.51 4.92 -1.60 -0.228 0.61541E+04 176 topaz-H -8.66 -11.27 -2.60 -0.237 0.10033E+05 177 tremolite 15.10 12.47 -2.64 -0.071 0.10169E+05 179 troilite-low -8.54 -9.27 -0.73 -0.243 0.28143E+04 180 tschermakite -8.10 -11.41 -3.30 -0.089 0.12726E+05 183 wadsleyite-Fe 3.08 1.27 -1.81 -0.258 0.69635E+04 184 wadsleyite-Mg 8.45 5.03 -3.42 -0.488 0.13164E+05 185 wairakite -9.90 -11.63 -1.72 -0.101 0.66464E+04 186 walstromite 4.59 2.10 -2.50 -0.499 0.96201E+04 187 wollastonite 4.17 2.10 -2.08 -0.416 0.80064E+04 188 pseudo-wollastonite 4.29 2.10 -2.19 -0.439 0.84518E+04 189 zoisite -9.49 -12.09 -2.60 -0.118 0.10036E+05 192 beidellite-Ca -13.94 -15.65 -1.72 -0.106 0.66251E+04 193 beidellite-H -13.96 -16.20 -2.25 -0.143 0.86577E+04 194 beidellite-K -12.91 -14.94 -2.04 -0.125 0.78472E+04 195 beidellite-Mg -14.20 -15.69 -1.49 -0.092 0.57276E+04 196 beidellite-Na -12.85 -14.79 -1.94 -0.119 0.74747E+04 197 bornite -54.22 -54.65 -0.43 -0.032 0.16455E+04 199 chalcocite -14.15 -15.67 -1.52 -0.381 0.58663E+04 200 covellite -12.62 -14.03 -1.41 -0.536 0.54254E+04 202 montmorillonite-Ca -10.42 -11.72 -1.29 -0.080 0.49856E+04 203 montmorillonite-K -9.68 -11.00 -1.33 -0.081 0.51133E+04 204 montmorillonite-Mg -10.64 -11.75 -1.11 -0.068 0.42582E+04 205 montmorillonite-Na -9.34 -10.85 -1.51 -0.093 0.58339E+04 206 nontronite-Ca -3.59 -4.99 -1.40 -0.091 0.53802E+04 207 nontronite-H -3.62 -5.54 -1.92 -0.128 0.73853E+04 208 nontronite-K -2.57 -4.28 -1.71 -0.110 0.65944E+04 209 nontronite-Mg -3.82 -5.02 -1.20 -0.078 0.46311E+04 210 nontronite-Na -2.50 -4.12 -1.62 -0.104 0.62347E+04 215 gypsum -12.45 -14.68 -2.23 -0.559 0.86125E+04 232 alabandite -6.36 -7.45 -1.09 -0.363 0.42011E+04 234 anglesite -14.92 -17.32 -2.40 -1.199 0.92419E+04 238 boehmite -3.89 -5.02 -1.13 -0.189 0.43630E+04 242 copper,native 1.74 -1.64 -3.38 -1.177 0.13035E+05 244 ferrous-oxide 2.08 1.25 -0.83 -0.207 0.31844E+04 245 galena -9.75 -9.84 -0.09 -0.031 0.36263E+03 246 silver,native 0.48 -3.37 -3.85 -1.339 0.14832E+05 248 litharge 5.29 0.68 -4.61 -1.153 0.17766E+05 256 wurtzite -10.08 -10.88 -0.80 -0.267 0.30882E+04 257 zincite 2.18 -0.36 -2.54 -0.634 0.97751E+04 258 an20ab80 -5.34 -5.37 -0.03 -0.002 0.11796E+03 259 an25ab75 -5.57 -5.60 -0.03 -0.002 0.12445E+03 260 an30ab70 -5.80 -5.84 -0.04 -0.003 0.15559E+03 261 tr.625ac.25prg.125 9.65 8.69 -0.97 -0.026 0.37212E+04 Calculations done for 569.0000 Deg. C; 1203.0000 bar Temperature changed by -1.000 degrees to 568.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 33 Loop limit = 500 Temperature = 568.00 C Pressure = 1187.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5511E+02 kg liquid = 0.9929E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9966 Stoichiometric ionic strength = .3281186E+01 Osmotic coef. = 0.0000 True ionic strength = .1660246E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.55809E-05 -5.2533 0.12167E-05 -5.9148 0.21801E+00 -0.6615 2 H2O 0.99658E+00 -0.0015 0.99658E+00 -0.0015 3 Cl- 0.13971E+00 -0.8548 0.26236E-01 -1.5811 0.18779E+00 -0.7263 4 SO4-- 0.21745E-03 -3.6626 0.61570E-06 -6.2106 0.28315E-02 -2.5480 5 HCO3- 0.11782E-04 -4.9288 0.23836E-05 -5.6228 0.20231E+00 -0.6940 6 HS- 0.12308E-03 -3.9098 0.23305E-04 -4.6325 0.18935E+00 -0.7227 7 H4SiO4 0.57427E-01 -1.2409 0.57427E-01 -1.2409 0.10000E+01 0.0000 8 Al+++ 0.13051E-16 -16.8844 0.18988E-22 -22.7215 0.14550E-05 -5.8371 9 Ca++ 0.14032E-05 -5.8529 0.31888E-08 -8.4964 0.22725E-02 -2.6435 10 Mg++ 0.11320E-05 -5.9461 0.21139E-08 -8.6749 0.18674E-02 -2.7288 11 Fe++ 0.13763E-07 -7.8613 0.27013E-10 -10.5684 0.19627E-02 -2.7071 12 K+ 0.38905E-01 -1.4100 0.80663E-02 -2.0933 0.20733E+00 -0.6833 13 Na+ 0.12538E+00 -0.9018 0.23820E-01 -1.6231 0.18999E+00 -0.7213 14 Mn++ 0.91818E-06 -6.0371 0.18689E-08 -8.7284 0.20354E-02 -2.6914 15 Zn++ 0.33904E-09 -9.4697 0.66544E-12 -12.1769 0.19627E-02 -2.7071 16 Cu+ 0.17002E-07 -7.7695 0.32217E-08 -8.4919 0.18948E+00 -0.7224 17 Pb++ 0.28659E-08 -8.5427 0.72991E-11 -11.1367 0.25469E-02 -2.5940 18 Ag+ 0.30373E-09 -9.5175 0.61985E-10 -10.2077 0.20408E+00 -0.6902 19 Ba++ 0.80959E-07 -7.0917 0.22160E-09 -9.6544 0.27372E-02 -2.5627 20 HPO4-- 0.11535E-08 -8.9380 0.32825E-11 -11.4838 0.28458E-02 -2.5458 21 HSiO3- 0.15435E-05 -5.8115 0.28986E-06 -6.5378 0.18779E+00 -0.7263 22 Ca(HSiO3)+ 0.58530E-08 -8.2326 0.12243E-08 -8.9121 0.20917E+00 -0.6795 23 Mg(HSiO3)+ 0.11751E-08 -8.9299 0.24579E-09 -9.6094 0.20917E+00 -0.6795 24 NaHSiO3,aq 0.18172E-05 -5.7406 0.18172E-05 -5.7406 0.10000E+01 0.0000 28 AgCl,aq 0.10133E-06 -6.9943 0.10133E-06 -6.9943 0.10000E+01 0.0000 29 AgCl2- 0.51727E-05 -5.2863 0.97138E-06 -6.0126 0.18779E+00 -0.7263 30 AgCl3-2 0.19095E-05 -5.7191 0.50031E-08 -8.3008 0.26201E-02 -2.5817 31 AgCl4-3 0.15722E-05 -5.8035 0.19923E-11 -11.7006 0.12672E-05 -5.8971 34 Ag(HS),aq 0.14267E-08 -8.8457 0.14267E-08 -8.8457 0.10000E+01 0.0000 35 Ag(HS)2- 0.60021E-08 -8.2217 0.11271E-08 -8.9480 0.18779E+00 -0.7263 38 HAlO2,aq 0.41435E-08 -8.3826 0.41435E-08 -8.3826 0.10000E+01 0.0000 39 AlO2- 0.13389E-04 -4.8732 0.22037E-05 -5.6568 0.16459E+00 -0.7836 41 Ba(HCO3)+ 0.30164E-06 -6.5205 0.65662E-07 -7.1827 0.21768E+00 -0.6622 42 BaCl+ 0.11396E-04 -4.9433 0.23837E-05 -5.6228 0.20917E+00 -0.6795 43 CH4,aq 0.16389E-08 -8.7854 0.19571E-08 -8.7084 0.11941E+01 0.0770 48 CO,aq 0.58417E-03 -3.2335 0.58417E-03 -3.2335 0.10000E+01 0.0000 49 CO2,aq 0.26746E+01 0.4273 0.31938E+01 0.5043 0.11941E+01 0.0770 50 CO3-2 0.40367E-10 -10.3940 0.10577E-12 -12.9756 0.26201E-02 -2.5817 51 CaCO3,aq 0.11389E-10 -10.9435 0.11389E-10 -10.9435 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.15000E-06 -6.8239 0.31375E-07 -7.5034 0.20917E+00 -0.6795 53 CaCl+ 0.94711E-04 -4.0236 0.19810E-04 -4.7031 0.20917E+00 -0.6795 54 CaCl2,aq 0.88910E-04 -4.0510 0.88910E-04 -4.0510 0.10000E+01 0.0000 55 CaOH+ 0.17768E-06 -6.7504 0.37164E-07 -7.4299 0.20917E+00 -0.6795 56 CaSO4,aq 0.15619E-06 -6.8064 0.15619E-06 -6.8064 0.10000E+01 0.0000 57 HCl,aq 0.24967E-02 -2.6026 0.24967E-02 -2.6026 0.10000E+01 0.0000 66 CuCl,aq 0.22915E-04 -4.6399 0.22915E-04 -4.6399 0.10000E+01 0.0000 67 CuCl2- 0.80612E-04 -4.0936 0.15138E-04 -4.8199 0.18779E+00 -0.7263 68 CuCl3-2 0.16030E-05 -5.7951 0.42000E-08 -8.3768 0.26201E-02 -2.5817 74 FeCl+ 0.28819E-06 -6.5403 0.60280E-07 -7.2198 0.20917E+00 -0.6795 75 FeCl2,aq 0.38997E-02 -2.4090 0.38997E-02 -2.4090 0.10000E+01 0.0000 77 FeO,aq 0.68618E-07 -7.1636 0.68618E-07 -7.1636 0.10000E+01 0.0000 78 FeOH+ 0.24215E-07 -7.6159 0.50650E-08 -8.2954 0.20917E+00 -0.6795 79 HFeO2- 0.82949E-08 -8.0812 0.15577E-08 -8.8075 0.18779E+00 -0.7263 82 FeO2- 0.52024E-08 -8.2838 0.97694E-09 -9.0101 0.18779E+00 -0.7263 83 HFeO2,aq 0.28989E-09 -9.5378 0.28989E-09 -9.5378 0.10000E+01 0.0000 84 H2,aq 0.46678E-02 -2.3309 0.55739E-02 -2.2538 0.11941E+01 0.0770 85 KCl,aq 0.68839E-01 -1.1622 0.68839E-01 -1.1622 0.10000E+01 0.0000 86 KHSO4,aq 0.13376E-01 -1.8737 0.13376E-01 -1.8737 0.10000E+01 0.0000 87 KOH,aq 0.13079E-05 -5.8834 0.13079E-05 -5.8834 0.10000E+01 0.0000 88 KSO4- 0.45052E-02 -2.3463 0.84601E-03 -3.0726 0.18779E+00 -0.7263 90 Mg(HCO3)+ 0.35441E-07 -7.4505 0.74130E-08 -8.1300 0.20917E+00 -0.6795 91 MgCl+ 0.13005E-04 -4.8859 0.27203E-05 -5.5654 0.20917E+00 -0.6795 92 MgOH+ 0.50088E-06 -6.3003 0.10477E-06 -6.9798 0.20917E+00 -0.6795 94 MnO,aq 0.78165E-07 -7.1070 0.78165E-07 -7.1070 0.10000E+01 0.0000 95 MnOH+ 0.19045E-06 -6.7202 0.39837E-07 -7.3997 0.20917E+00 -0.6795 97 HMnO2- 0.39146E-10 -10.4073 0.73511E-11 -11.1336 0.18779E+00 -0.7263 100 MnCl+ 0.11563E-02 -2.9369 0.24186E-03 -3.6164 0.20917E+00 -0.6795 101 MnSO4,aq 0.10359E-06 -6.9847 0.10359E-06 -6.9847 0.10000E+01 0.0000 102 NaCl,aq 0.43321E+00 -0.3633 0.43321E+00 -0.3633 0.10000E+01 0.0000 103 NaOH,aq 0.17752E-05 -5.7507 0.17752E-05 -5.7507 0.10000E+01 0.0000 105 OH- 0.79035E-05 -5.1022 0.13008E-05 -5.8858 0.16459E+00 -0.7836 110 HPO3-2 0.10518E-10 -10.9781 0.27559E-13 -13.5597 0.26201E-02 -2.5817 111 H3PO3,aq 0.10827E-09 -9.9655 0.10827E-09 -9.9655 0.10000E+01 0.0000 112 H2PO3- 0.22637E-08 -8.6452 0.42509E-09 -9.3715 0.18779E+00 -0.7263 113 H3PO4,aq 0.10937E-05 -5.9611 0.10937E-05 -5.9611 0.10000E+01 0.0000 114 H2PO4- 0.13563E-05 -5.8676 0.26778E-06 -6.5722 0.19744E+00 -0.7046 116 H4P2O7,aq 0.11011E-09 -9.9582 0.11011E-09 -9.9582 0.10000E+01 0.0000 117 H3P2O7- 0.81203E-09 -9.0904 0.15249E-09 -9.8168 0.18779E+00 -0.7263 118 H2P2O7-2 0.21119E-06 -6.6753 0.55335E-09 -9.2570 0.26201E-02 -2.5817 119 HP2O7-3 0.18271E-07 -7.7382 0.23153E-13 -13.6354 0.12672E-05 -5.8971 121 PbCl+ 0.14139E-05 -5.8496 0.29575E-06 -6.5291 0.20917E+00 -0.6795 122 PbCl2,aq 0.86308E-04 -4.0639 0.86308E-04 -4.0639 0.10000E+01 0.0000 123 PbCl3- 0.10233E-03 -3.9900 0.19216E-04 -4.7163 0.18779E+00 -0.7263 124 PbCl4-2 0.19248E-04 -4.7156 0.50432E-07 -7.2973 0.26201E-02 -2.5817 125 PbO,aq 0.60766E-08 -8.2163 0.60766E-08 -8.2163 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12015E-03 -3.9203 0.12015E-03 -3.9203 0.10000E+01 0.0000 128 Pb(HS)3- 0.13165E-04 -4.8806 0.24723E-05 -5.6069 0.18779E+00 -0.7263 129 H2S,aq 0.10560E+01 0.0237 0.12610E+01 0.1007 0.11941E+01 0.0770 130 S2-2 0.13009E-07 -7.8857 0.34087E-10 -10.4674 0.26201E-02 -2.5817 131 S3-2 0.12141E-08 -8.9157 0.31812E-11 -11.4974 0.26201E-02 -2.5817 132 S3- 0.11691E-01 -1.9321 0.21955E-02 -2.6585 0.18779E+00 -0.7263 133 S4-2 0.95929E-10 -10.0181 0.25135E-12 -12.5997 0.26201E-02 -2.5817 135 SO2,aq 0.29197E+00 -0.5347 0.29197E+00 -0.5347 0.10000E+01 0.0000 136 SO3-2 0.62376E-09 -9.2050 0.25960E-11 -11.5857 0.41618E-02 -2.3807 137 HSO3- 0.27824E-03 -3.5556 0.52250E-04 -4.2819 0.18779E+00 -0.7263 138 HSO4- 0.86811E-02 -2.0614 0.18654E-02 -2.7292 0.21488E+00 -0.6678 140 S2O3-2 0.49849E-06 -6.3023 0.13061E-08 -8.8840 0.26201E-02 -2.5817 141 HS2O3- 0.41285E-06 -6.3842 0.77528E-07 -7.1105 0.18779E+00 -0.7263 142 H2S2O3,aq 0.29912E-07 -7.5242 0.29912E-07 -7.5242 0.10000E+01 0.0000 150 S4O6-2 0.44760E-09 -9.3491 0.11728E-11 -11.9308 0.26201E-02 -2.5817 152 ZnCl+ 0.20355E-03 -3.6913 0.42575E-04 -4.3708 0.20917E+00 -0.6795 153 ZnCl2,aq 0.74091E-03 -3.1302 0.74091E-03 -3.1302 0.10000E+01 0.0000 154 ZnCl3- 0.61527E-04 -4.2109 0.11554E-04 -4.9373 0.18779E+00 -0.7263 155 ZnO,aq 0.31766E-07 -7.4980 0.31766E-07 -7.4980 0.10000E+01 0.0000 156 ZnOH+ 0.13235E-05 -5.8783 0.27682E-06 -6.5578 0.20917E+00 -0.6795 158 HZnO2- 0.24957E-09 -9.6028 0.46867E-10 -10.3291 0.18779E+00 -0.7263 Charge balance for all species = 0.2549E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5580900E-05 0.4296219E+01 0.3540289E+04 0.0000 2 H2O 0.1000000E+01 0.5251654E+02 0.7734910E+06 0.0000 3 Cl- 0.1397093E+00 0.6561490E+00 0.1901836E+05 4.3337 4 SO4-- 0.2174497E-03 0.2519591E+00 0.1978780E+05 5.6190 5 HCO3- 0.1178186E-04 0.2675228E+01 0.1334538E+06 0.2920 6 HS- 0.1230818E-03 0.1158526E+01 0.3132447E+05 1.2823 7 H4SiO4 0.5742742E-01 0.5743078E-01 0.4512897E+04 -1.2409 8 Al+++ 0.1305055E-16 0.1339352E-04 0.2954462E+00 -4.9771 9 Ca++ 0.1403216E-05 0.1855138E-03 0.6078551E+01 3.3332 10 Mg++ 0.1132049E-05 0.1467478E-04 0.2916821E+00 3.1547 11 Fe++ 0.1376305E-07 0.3900156E-02 0.1780736E+03 1.2612 12 K+ 0.3890513E-01 0.1256265E+00 0.4016040E+04 3.8215 13 Na+ 0.1253754E+00 0.5585907E+00 0.1049897E+05 4.2918 14 Mn++ 0.9181806E-06 0.1157599E-02 0.5199346E+02 3.1012 15 Zn++ 0.3390421E-09 0.1007333E-02 0.5383556E+02 -0.3473 16 Cu+ 0.1700233E-07 0.1051467E-03 0.5462110E+01 -2.5771 17 Pb++ 0.2865929E-08 0.3426208E-03 0.5803636E+02 0.6929 18 Ag+ 0.3037307E-09 0.8763460E-05 0.7728477E+00 -4.2929 19 Ba++ 0.8095863E-07 0.1177848E-04 0.1322525E+01 2.1752 20 HPO4-- 0.1153472E-08 0.2914303E-05 0.2286802E+00 0.3458 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265521E+01 -.3158996E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5214129E+02 -.1765155E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2501588E+00 0.1563968E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1150248E+01 0.9896589E-02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.5702042E-01 0.8657390E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1329781E-04 0.6812417E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1841883E-03 0.3437216E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1456992E-04 0.6106731E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.3872288E-02 0.4894466E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247289E+00 0.6812417E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149328E-02 0.1722287E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.1000135E-02 0.1299199E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1043954E-03 0.2952143E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1169432E-04 0.4367813E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2893480E-05 0.5674021E-05 0.0000000E+00 Chg. balance for solid moles: -.2477E-17 Mass of aqueous solution: 0.121442E+04 g Temperature = 568.00 C Pressure = 1187.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3343E-03 -3.476 0.4551E-01 -1.342 0.7512 0.1536E-01 annite 0.9196E-06 -6.036 0.4707E-03 -3.327 0.7771E-02 0.1419E-03 phlogopite 0.2036E-05 -5.691 0.8494E-03 -3.071 0.1402E-01 0.3046E-03 biotite-Mn 0.5741E-07 -7.241 0.2923E-04 -4.534 0.4825E-03 0.8762E-05 apatite-OH 0.1891E-05 -5.723 0.9501E-03 -3.022 0.1568E-01 0.3019E-03 microcline 0.6782E-03 -3.169 0.1888 -0.724 3.116 0.7374E-01 pyrite 0.4596E-02 -2.338 0.5515 -0.258 9.104 0.1100 quartz 0.8453E-01 -1.073 5.079 0.706 83.84 1.918 barite 0.4368E-04 -4.360 0.1019E-01 -1.992 0.1683 0.2276E-02 chalcopyrite 0.2952E-03 -3.530 0.5417E-01 -1.266 0.8943 0.1265E-01 sphalerite 0.1299E-02 -2.886 0.1266 -0.898 2.090 0.3096E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.3053E+00 0.3053E+00 1.0000 -0.515 phlogopite 0.6757E+00 0.6757E+00 1.0000 -0.170 biotite-Mn 0.1906E-01 0.1906E-01 1.0000 -1.720 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.057592 g Volume = 2.163658 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.71 -14.71 0.00 0.000 0.00000E+00 24 annite 0.45 0.45 0.00 0.000 0.00000E+00 25 phlogopite 5.10 5.10 0.00 0.000 -0.27349E-10 26 biotite-Mn 9.59 9.59 0.00 0.000 -0.13674E-10 30 apatite-OH -53.28 -53.28 0.00 0.000 0.27349E-10 115 microcline -4.87 -4.87 0.00 0.000 -0.68371E-11 140 pyrite -21.71 -21.71 0.00 0.000 0.00000E+00 144 quartz -1.24 -1.24 0.00 0.000 0.00000E+00 237 barite -15.87 -15.87 0.00 0.000 0.00000E+00 240 chalcopyrite -23.35 -23.35 0.00 0.000 0.00000E+00 255 sphalerite -10.89 -10.89 0.00 0.000 -0.13674E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.27 -0.271 0.10440E+04 2.803 2 CO2,gas -9.89 -11.54 -1.65 -0.550 0.63464E+04 1.426 3 CH4,gas 6.88 -4.05 -10.92 -2.730 0.42036E+05 -7.847 4 H2,gas 5.93 1.87 -4.06 -2.321 0.15632E+05 -0.987 5 H2S,gas -8.24 -10.55 -2.31 -1.155 0.88909E+04 0.764 6 CO,gas -3.72 -9.66 -5.95 -1.830 0.22889E+05 -2.872 7 SO3,gas -7.46 -18.04 -10.58 -2.645 0.40719E+05 -7.505 8 O2,gas 16.74 -3.75 -20.48 -13.655 0.78838E+05 -17.409 9 HCl,gas -6.07 -7.50 -1.43 -0.715 0.55066E+04 -1.431 10 acmite 3.64 2.14 -1.50 -0.156 0.57631E+04 12 akimotoite 6.11 1.92 -4.20 -0.840 0.16159E+05 13 akimotoite-Fe 4.00 0.02 -3.98 -0.796 0.15324E+05 14 albite-high -4.28 -4.40 -0.12 -0.010 0.47548E+03 15 albite -4.27 -4.40 -0.13 -0.010 0.51685E+03 16 almandine -8.15 -9.89 -1.74 -0.087 0.66967E+04 17 pyrope -1.47 -4.21 -2.74 -0.137 0.10539E+05 18 analcite -2.20 -3.17 -0.96 -0.107 0.37111E+04 19 andalusite -10.68 -11.20 -0.52 -0.052 0.20026E+04 20 andradite 11.66 6.93 -4.73 -0.246 0.18221E+05 27 anorthite -8.38 -9.10 -0.73 -0.056 0.27986E+04 28 anthophyllite 14.44 12.17 -2.28 -0.062 0.87608E+04 29 anthophyllite-Fe 1.72 -1.09 -2.81 -0.076 0.10807E+05 31 apatite-OH-zs -51.11 -53.28 -2.17 -0.167 0.83334E+04 32 apatite-Cl-zs -57.55 -60.77 -3.22 -0.268 0.12398E+05 33 aragonite -4.60 -8.20 -3.61 -1.202 0.13877E+05 34 brucite 5.42 3.15 -2.26 -0.453 0.87125E+04 35 calcite -4.70 -8.20 -3.50 -1.167 0.13478E+05 36 carnegieite-low -0.16 -1.93 -1.77 -0.253 0.68078E+04 37 carnegieite-high -0.08 -1.93 -1.85 -0.264 0.71088E+04 38 carpholite-Mg -7.24 -9.28 -2.04 -0.136 0.78619E+04 39 carpholite-Fe -8.61 -11.18 -2.57 -0.171 0.98885E+04 40 celadonite -0.85 -2.96 -2.11 -0.124 0.81108E+04 41 celadonite-Fe -2.27 -4.85 -2.58 -0.152 0.99479E+04 42 chrysotile 9.42 6.98 -2.44 -0.203 0.93940E+04 44 clinochlore 3.57 2.09 -1.48 -0.046 0.57038E+04 45 daphnite -3.55 -7.38 -3.83 -0.120 0.14731E+05 48 chloritoid-Mg -6.69 -8.04 -1.36 -0.091 0.52271E+04 49 chloritoid-Fe -8.64 -9.94 -1.30 -0.087 0.50011E+04 50 chloritoid-Mn -6.49 -8.10 -1.61 -0.107 0.61960E+04 52 coesite -0.95 -1.24 -0.29 -0.096 0.11101E+04 53 cordierite-H -18.89 -19.80 -0.92 -0.033 0.35287E+04 54 cordierite-Fe -21.48 -23.59 -2.10 -0.073 0.80932E+04 55 cordierite-Mn -17.11 -19.91 -2.80 -0.096 0.10763E+05 56 corundum -9.26 -9.96 -0.69 -0.063 0.26750E+04 58 cristobalite -1.19 -1.24 -0.05 -0.016 0.18011E+03 59 cummingtonite 14.51 12.17 -2.34 -0.063 0.90150E+04 61 cymrite-K -2.58 -4.87 -2.30 -0.191 0.88423E+04 63 diaspore -4.13 -4.98 -0.85 -0.141 0.32656E+04 65 diopside 5.37 4.01 -1.36 -0.136 0.52489E+04 66 hedenbergite 3.94 2.12 -1.82 -0.182 0.70179E+04 68 eastonite -5.93 -7.29 -1.36 -0.052 0.52179E+04 69 enstatite 4.72 3.83 -0.89 -0.089 0.34063E+04 70 clinoenstatite-HiP 5.21 3.83 -1.38 -0.138 0.53117E+04 71 clinoenstatite 4.70 3.83 -0.87 -0.087 0.33448E+04 72 protoenstatite 4.85 3.83 -1.02 -0.102 0.39153E+04 73 epidote -4.44 -6.69 -2.24 -0.109 0.86375E+04 74 clinozoisite -9.30 -11.99 -2.69 -0.122 0.10349E+05 75 epidote-Fe 2.10 -1.38 -3.49 -0.181 0.13414E+05 76 fayalite 2.26 1.28 -0.98 -0.140 0.37586E+04 77 ferrosilite 1.12 0.04 -1.07 -0.107 0.41289E+04 78 forsterite 6.27 5.07 -1.20 -0.172 0.46357E+04 79 gedrite -9.39 -11.58 -2.19 -0.059 0.84394E+04 81 gibbsite -2.51 -4.98 -2.47 -0.353 0.95193E+04 82 glaucophane 1.27 -1.82 -3.09 -0.084 0.11901E+05 83 glaucophane-Fe -2.81 -7.50 -4.69 -0.127 0.18046E+05 84 goethite 1.15 0.32 -0.83 -0.180 0.31986E+04 86 greenalite 4.52 1.30 -3.22 -0.268 0.12378E+05 87 grunerite 2.27 -1.09 -3.36 -0.091 0.12939E+05 88 halite -1.16 -3.20 -2.04 -1.022 0.78637E+04 89 hematite 0.76 0.65 -0.12 -0.014 0.45517E+03 90 heulandite -12.20 -15.30 -3.10 -0.141 0.11938E+05 91 hercynite -7.54 -8.70 -1.16 -0.077 0.44561E+04 94 jadeite -1.52 -3.16 -1.65 -0.165 0.63346E+04 96 kalsilite -0.78 -2.40 -1.62 -0.231 0.62206E+04 97 kaolinite -9.68 -12.44 -2.76 -0.251 0.10622E+05 98 kyanite -10.51 -11.20 -0.68 -0.068 0.26249E+04 100 laumontite -7.98 -11.58 -3.61 -0.241 0.13887E+05 101 lawsonite -5.61 -9.11 -3.50 -0.233 0.13474E+05 102 leucite -2.68 -3.63 -0.96 -0.096 0.36777E+04 104 lizardite 9.60 6.98 -2.62 -0.218 0.10066E+05 105 magnesite -5.46 -8.38 -2.92 -0.973 0.11234E+05 106 magnetite 1.97 1.91 -0.06 -0.005 0.23789E+03 107 minnesotaite 0.78 -1.17 -1.96 -0.115 0.75274E+04 108 minnesotaite-Mg 6.78 4.51 -2.28 -0.134 0.87605E+04 109 magnesioferrite 5.05 3.80 -1.25 -0.102 0.48029E+04 111 manganosite 5.38 3.10 -2.28 -0.569 0.87604E+04 112 margarite -17.17 -19.06 -1.89 -0.076 0.72865E+04 116 monticellite 8.77 5.25 -3.52 -0.503 0.13549E+05 118 mullite-Si -9.93 -11.20 -1.27 -0.127 0.48751E+04 119 muscovite -14.00 -14.83 -0.83 -0.049 0.31989E+04 120 paragonite -13.32 -14.36 -1.04 -0.061 0.40134E+04 121 nepheline -0.45 -1.93 -1.47 -0.210 0.56636E+04 122 osumilite(2) -13.26 -15.27 -2.01 -0.042 0.77446E+04 123 osumilite-Fe -28.45 -30.94 -2.49 -0.052 0.95783E+04 124 pargasite 5.21 1.20 -4.01 -0.106 0.15431E+05 125 periclase 5.61 3.15 -2.45 -0.613 0.94446E+04 126 periclase-Fe 3.02 1.26 -1.76 -0.440 0.67766E+04 127 perovskite-Al -7.53 -9.96 -2.43 -0.220 0.93353E+04 132 phlogopite-Na 5.97 5.06 -0.91 -0.051 0.35033E+04 134 prehnite -3.69 -7.01 -3.32 -0.195 0.12787E+05 135 prehnite-Fe 1.56 -1.71 -3.27 -0.197 0.12588E+05 138 px-Mg-tschermaks -6.09 -8.04 -1.95 -0.140 0.75185E+04 139 px-Ca-tschermaks -5.25 -7.86 -2.62 -0.187 0.10072E+05 141 pyrrhotite -8.64 -9.29 -0.64 -0.214 0.24753E+04 142 pyrrhotiteFe0.875 -9.41 -9.68 -0.26 -0.097 0.10159E+04 143 pyrophyllite -13.52 -14.91 -1.39 -0.087 0.53629E+04 146 riebeckite 5.80 3.10 -2.70 -0.074 0.10391E+05 147 ringwoodite-Fe 3.25 1.28 -1.97 -0.282 0.75929E+04 148 ringwoodite-Mg 9.42 5.07 -4.36 -0.622 0.16763E+05 149 rhodochrosite -5.43 -8.44 -3.01 -1.002 0.11572E+05 150 rhodonite 2.51 1.86 -0.65 -0.131 0.25117E+04 151 sanidine -4.34 -4.87 -0.54 -0.041 0.20677E+04 153 siderite -7.31 -10.28 -2.97 -0.989 0.11418E+05 154 sillimanite -10.64 -11.20 -0.56 -0.056 0.21384E+04 156 spinel -5.36 -6.81 -1.44 -0.096 0.55589E+04 162 stilpnomelane-Fe -6.87 -11.66 -4.79 -0.143 0.18429E+05 163 stilpnomelane-Mg -0.01 -2.19 -2.18 -0.065 0.83997E+04 164 stishovite 1.71 -1.24 -2.95 -0.984 0.11358E+05 165 sudoite-Fe -16.86 -21.12 -4.25 -0.137 0.16377E+05 166 sudoite -14.62 -17.33 -2.71 -0.087 0.10429E+05 167 sulfur -10.92 -12.42 -1.50 -0.462 0.57800E+04 168 sylvite -1.07 -3.67 -2.61 -1.304 0.10038E+05 169 talc 5.06 4.51 -0.55 -0.032 0.21158E+04 170 talc-Fe 2.18 -1.17 -3.36 -0.197 0.12917E+05 171 talc-tschermaks -5.67 -7.37 -1.69 -0.100 0.65228E+04 173 tephroite 6.54 4.96 -1.57 -0.225 0.60615E+04 176 topaz-H -8.58 -11.20 -2.62 -0.238 0.10068E+05 177 tremolite 15.16 12.52 -2.64 -0.071 0.10146E+05 179 troilite-low -8.55 -9.29 -0.74 -0.245 0.28320E+04 180 tschermakite -7.89 -11.22 -3.33 -0.090 0.12811E+05 183 wadsleyite-Fe 3.11 1.28 -1.82 -0.261 0.70223E+04 184 wadsleyite-Mg 8.48 5.07 -3.41 -0.488 0.13141E+05 185 wairakite -9.84 -11.58 -1.74 -0.102 0.67025E+04 186 walstromite 4.60 2.09 -2.51 -0.501 0.96419E+04 187 wollastonite 4.18 2.09 -2.09 -0.417 0.80273E+04 188 pseudo-wollastonite 4.30 2.09 -2.20 -0.440 0.84734E+04 189 zoisite -9.35 -11.99 -2.64 -0.120 0.10144E+05 192 beidellite-Ca -13.86 -15.60 -1.73 -0.107 0.66724E+04 193 beidellite-H -13.89 -16.15 -2.26 -0.144 0.87006E+04 194 beidellite-K -12.84 -14.89 -2.05 -0.125 0.78839E+04 195 beidellite-Mg -14.13 -15.63 -1.50 -0.093 0.57716E+04 196 beidellite-Na -12.78 -14.73 -1.95 -0.120 0.75128E+04 197 bornite -54.34 -54.75 -0.41 -0.031 0.15953E+04 199 chalcocite -14.18 -15.70 -1.52 -0.379 0.58392E+04 200 covellite -12.66 -14.06 -1.40 -0.535 0.54020E+04 202 montmorillonite-Ca -10.38 -11.68 -1.30 -0.081 0.50146E+04 203 montmorillonite-K -9.63 -10.97 -1.33 -0.082 0.51349E+04 204 montmorillonite-Mg -10.60 -11.71 -1.11 -0.069 0.42808E+04 205 montmorillonite-Na -9.29 -10.81 -1.52 -0.093 0.58530E+04 206 nontronite-Ca -3.58 -4.99 -1.41 -0.092 0.54339E+04 207 nontronite-H -3.61 -5.54 -1.93 -0.129 0.74343E+04 208 nontronite-K -2.56 -4.28 -1.72 -0.111 0.66373E+04 209 nontronite-Mg -3.81 -5.02 -1.22 -0.079 0.46790E+04 210 nontronite-Na -2.49 -4.13 -1.63 -0.105 0.62790E+04 215 gypsum -12.47 -14.71 -2.24 -0.559 0.86121E+04 232 alabandite -6.37 -7.45 -1.08 -0.359 0.41469E+04 234 anglesite -14.96 -17.35 -2.39 -1.195 0.91952E+04 238 boehmite -3.84 -4.98 -1.14 -0.190 0.43815E+04 242 copper,native 1.74 -1.64 -3.38 -1.177 0.13021E+05 244 ferrous-oxide 2.10 1.26 -0.84 -0.209 0.32154E+04 245 galena -9.77 -9.85 -0.08 -0.028 0.32423E+03 246 silver,native 0.48 -3.36 -3.83 -1.334 0.14758E+05 248 litharge 5.30 0.69 -4.61 -1.152 0.17735E+05 256 wurtzite -10.09 -10.89 -0.80 -0.267 0.30879E+04 257 zincite 2.19 -0.35 -2.54 -0.636 0.97846E+04 258 an20ab80 -5.31 -5.34 -0.04 -0.003 0.13725E+03 259 an25ab75 -5.54 -5.58 -0.04 -0.003 0.14693E+03 260 an30ab70 -5.77 -5.81 -0.05 -0.004 0.18095E+03 261 tr.625ac.25prg.125 9.72 8.74 -0.98 -0.026 0.37700E+04 Calculations done for 568.0000 Deg. C; 1187.0000 bar Temperature changed by -1.000 degrees to 567.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 33 Loop limit = 500 Temperature = 567.00 C Pressure = 1171.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5511E+02 kg liquid = 0.9929E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9966 Stoichiometric ionic strength = .3280367E+01 Osmotic coef. = 0.0000 True ionic strength = .1634875E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54447E-05 -5.2640 0.11790E-05 -5.9285 0.21654E+00 -0.6645 2 H2O 0.99661E+00 -0.0015 0.99661E+00 -0.0015 3 Cl- 0.13755E+00 -0.8616 0.25622E-01 -1.5914 0.18628E+00 -0.7298 4 SO4-- 0.21952E-03 -3.6585 0.60420E-06 -6.2188 0.27523E-02 -2.5603 5 HCO3- 0.11415E-04 -4.9425 0.22904E-05 -5.6401 0.20065E+00 -0.6976 6 HS- 0.12195E-03 -3.9138 0.22905E-04 -4.6401 0.18783E+00 -0.7262 7 H4SiO4 0.56266E-01 -1.2498 0.56266E-01 -1.2498 0.10000E+01 0.0000 8 Al+++ 0.13816E-16 -16.8596 0.18866E-22 -22.7243 0.13655E-05 -5.8647 9 Ca++ 0.13759E-05 -5.8614 0.30392E-08 -8.5172 0.22089E-02 -2.6558 10 Mg++ 0.11538E-05 -5.9379 0.20951E-08 -8.6788 0.18158E-02 -2.7409 11 Fe++ 0.13585E-07 -7.8669 0.25925E-10 -10.5863 0.19083E-02 -2.7193 12 K+ 0.38381E-01 -1.4159 0.78914E-02 -2.1028 0.20561E+00 -0.6870 13 Na+ 0.12337E+00 -0.9088 0.23249E-01 -1.6336 0.18844E+00 -0.7248 14 Mn++ 0.94595E-06 -6.0241 0.18719E-08 -8.7277 0.19789E-02 -2.7036 15 Zn++ 0.33586E-09 -9.4738 0.64094E-12 -12.1932 0.19083E-02 -2.7193 16 Cu+ 0.16423E-07 -7.7845 0.30866E-08 -8.5105 0.18794E+00 -0.7260 17 Pb++ 0.28376E-08 -8.5470 0.70239E-11 -11.1534 0.24753E-02 -2.6064 18 Ag+ 0.30260E-09 -9.5191 0.61243E-10 -10.2129 0.20239E+00 -0.6938 19 Ba++ 0.78156E-07 -7.1070 0.20790E-09 -9.6821 0.26601E-02 -2.5751 20 HPO4-- 0.11750E-08 -8.9299 0.32505E-11 -11.4881 0.27663E-02 -2.5581 21 HSiO3- 0.15180E-05 -5.8187 0.28278E-06 -6.5485 0.18628E+00 -0.7298 22 Ca(HSiO3)+ 0.56482E-08 -8.2481 0.11716E-08 -8.9312 0.20743E+00 -0.6831 23 Mg(HSiO3)+ 0.11876E-08 -8.9253 0.24634E-09 -9.6085 0.20743E+00 -0.6831 24 NaHSiO3,aq 0.18285E-05 -5.7379 0.18285E-05 -5.7379 0.10000E+01 0.0000 28 AgCl,aq 0.10332E-06 -6.9858 0.10332E-06 -6.9858 0.10000E+01 0.0000 29 AgCl2- 0.51926E-05 -5.2846 0.96728E-06 -6.0144 0.18628E+00 -0.7298 30 AgCl3-2 0.18887E-05 -5.7238 0.48108E-08 -8.3178 0.25472E-02 -2.5939 31 AgCl4-3 0.15707E-05 -5.8039 0.18700E-11 -11.7282 0.11906E-05 -5.9242 34 Ag(HS),aq 0.14843E-08 -8.8285 0.14843E-08 -8.8285 0.10000E+01 0.0000 35 Ag(HS)2- 0.61104E-08 -8.2139 0.11383E-08 -8.9438 0.18628E+00 -0.7298 38 HAlO2,aq 0.41360E-08 -8.3834 0.41360E-08 -8.3834 0.10000E+01 0.0000 39 AlO2- 0.13094E-04 -4.8829 0.21388E-05 -5.6698 0.16334E+00 -0.7869 41 Ba(HCO3)+ 0.28636E-06 -6.5431 0.61812E-07 -7.2089 0.21586E+00 -0.6658 42 BaCl+ 0.10867E-04 -4.9639 0.22541E-05 -5.6470 0.20743E+00 -0.6831 43 CH4,aq 0.16201E-08 -8.7905 0.19335E-08 -8.7137 0.11934E+01 0.0768 48 CO,aq 0.57437E-03 -3.2408 0.57437E-03 -3.2408 0.10000E+01 0.0000 49 CO2,aq 0.26745E+01 0.4273 0.31918E+01 0.5040 0.11934E+01 0.0768 50 CO3-2 0.39929E-10 -10.3987 0.10170E-12 -12.9927 0.25472E-02 -2.5939 51 CaCO3,aq 0.11173E-10 -10.9518 0.11173E-10 -10.9518 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.14163E-06 -6.8488 0.29378E-07 -7.5320 0.20743E+00 -0.6831 53 CaCl+ 0.91264E-04 -4.0397 0.18931E-04 -4.7228 0.20743E+00 -0.6831 54 CaCl2,aq 0.87077E-04 -4.0601 0.87077E-04 -4.0601 0.10000E+01 0.0000 55 CaOH+ 0.17160E-06 -6.7655 0.35593E-07 -7.4486 0.20743E+00 -0.6831 56 CaSO4,aq 0.15780E-06 -6.8019 0.15780E-06 -6.8019 0.10000E+01 0.0000 57 HCl,aq 0.25812E-02 -2.5882 0.25812E-02 -2.5882 0.10000E+01 0.0000 66 CuCl,aq 0.22676E-04 -4.6444 0.22676E-04 -4.6444 0.10000E+01 0.0000 67 CuCl2- 0.79154E-04 -4.1015 0.14745E-04 -4.8314 0.18628E+00 -0.7298 68 CuCl3-2 0.15534E-05 -5.8087 0.39568E-08 -8.4027 0.25472E-02 -2.5939 74 FeCl+ 0.27971E-06 -6.5533 0.58020E-07 -7.2364 0.20743E+00 -0.6831 75 FeCl2,aq 0.37449E-02 -2.4266 0.37449E-02 -2.4266 0.10000E+01 0.0000 77 FeO,aq 0.67143E-07 -7.1730 0.67143E-07 -7.1730 0.10000E+01 0.0000 78 FeOH+ 0.23528E-07 -7.6284 0.48803E-08 -8.3116 0.20743E+00 -0.6831 79 HFeO2- 0.80383E-08 -8.0948 0.14974E-08 -8.8247 0.18628E+00 -0.7298 82 FeO2- 0.50353E-08 -8.2980 0.93798E-09 -9.0278 0.18628E+00 -0.7298 83 HFeO2,aq 0.28891E-09 -9.5392 0.28891E-09 -9.5392 0.10000E+01 0.0000 84 H2,aq 0.46467E-02 -2.3329 0.55453E-02 -2.2561 0.11934E+01 0.0768 85 KCl,aq 0.69295E-01 -1.1593 0.69295E-01 -1.1593 0.10000E+01 0.0000 86 KHSO4,aq 0.13410E-01 -1.8726 0.13410E-01 -1.8726 0.10000E+01 0.0000 87 KOH,aq 0.13188E-05 -5.8798 0.13188E-05 -5.8798 0.10000E+01 0.0000 88 KSO4- 0.45341E-02 -2.3435 0.84462E-03 -3.0733 0.18628E+00 -0.7298 90 Mg(HCO3)+ 0.34568E-07 -7.4613 0.71703E-08 -8.1445 0.20743E+00 -0.6831 91 MgCl+ 0.13089E-04 -4.8831 0.27150E-05 -5.5662 0.20743E+00 -0.6831 92 MgOH+ 0.50394E-06 -6.2976 0.10453E-06 -6.9808 0.20743E+00 -0.6831 94 MnO,aq 0.80177E-07 -7.0960 0.80177E-07 -7.0960 0.10000E+01 0.0000 95 MnOH+ 0.19231E-06 -6.7160 0.39890E-07 -7.3991 0.20743E+00 -0.6831 97 HMnO2- 0.39541E-10 -10.4029 0.73658E-11 -11.1328 0.18628E+00 -0.7298 100 MnCl+ 0.11562E-02 -2.9370 0.23983E-03 -3.6201 0.20743E+00 -0.6831 101 MnSO4,aq 0.10936E-06 -6.9611 0.10936E-06 -6.9611 0.10000E+01 0.0000 102 NaCl,aq 0.43519E+00 -0.3613 0.43519E+00 -0.3613 0.10000E+01 0.0000 103 NaOH,aq 0.17849E-05 -5.7484 0.17849E-05 -5.7484 0.10000E+01 0.0000 105 OH- 0.78204E-05 -5.1068 0.12774E-05 -5.8937 0.16334E+00 -0.7869 110 HPO3-2 0.10375E-10 -10.9840 0.26427E-13 -13.5779 0.25472E-02 -2.5939 111 H3PO3,aq 0.10909E-09 -9.9622 0.10909E-09 -9.9622 0.10000E+01 0.0000 112 H2PO3- 0.22030E-08 -8.6570 0.41037E-09 -9.3868 0.18628E+00 -0.7298 113 H3PO4,aq 0.11234E-05 -5.9495 0.11234E-05 -5.9495 0.10000E+01 0.0000 114 H2PO4- 0.13556E-05 -5.8679 0.26546E-06 -6.5760 0.19583E+00 -0.7081 116 H4P2O7,aq 0.11640E-09 -9.9340 0.11640E-09 -9.9340 0.10000E+01 0.0000 117 H3P2O7- 0.81789E-09 -9.0873 0.15236E-09 -9.8171 0.18628E+00 -0.7298 118 H2P2O7-2 0.21063E-06 -6.6765 0.53652E-09 -9.2704 0.25472E-02 -2.5939 119 HP2O7-3 0.18783E-07 -7.7262 0.22363E-13 -13.6505 0.11906E-05 -5.9242 121 PbCl+ 0.13852E-05 -5.8585 0.28733E-06 -6.5416 0.20743E+00 -0.6831 122 PbCl2,aq 0.86357E-04 -4.0637 0.86357E-04 -4.0637 0.10000E+01 0.0000 123 PbCl3- 0.10175E-03 -3.9925 0.18954E-04 -4.7223 0.18628E+00 -0.7298 124 PbCl4-2 0.18846E-04 -4.7248 0.48002E-07 -7.3187 0.25472E-02 -2.5939 125 PbO,aq 0.61592E-08 -8.2105 0.61592E-08 -8.2105 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12100E-03 -3.9172 0.12100E-03 -3.9172 0.10000E+01 0.0000 128 Pb(HS)3- 0.13261E-04 -4.8774 0.24703E-05 -5.6073 0.18628E+00 -0.7298 129 H2S,aq 0.10563E+01 0.0238 0.12606E+01 0.1006 0.11934E+01 0.0768 130 S2-2 0.12857E-07 -7.8909 0.32748E-10 -10.4848 0.25472E-02 -2.5939 131 S3-2 0.11983E-08 -8.9214 0.30522E-11 -11.5154 0.25472E-02 -2.5939 132 S3- 0.11392E-01 -1.9434 0.21222E-02 -2.6732 0.18628E+00 -0.7298 133 S4-2 0.94572E-10 -10.0242 0.24089E-12 -12.6182 0.25472E-02 -2.5939 135 SO2,aq 0.29218E+00 -0.5343 0.29218E+00 -0.5343 0.10000E+01 0.0000 136 SO3-2 0.62453E-09 -9.2044 0.25261E-11 -11.5976 0.40448E-02 -2.3931 137 HSO3- 0.27277E-03 -3.5642 0.50811E-04 -4.2940 0.18628E+00 -0.7298 138 HSO4- 0.85851E-02 -2.0663 0.18294E-02 -2.7377 0.21309E+00 -0.6714 140 S2O3-2 0.49756E-06 -6.3032 0.12674E-08 -8.8971 0.25472E-02 -2.5939 141 HS2O3- 0.40541E-06 -6.3921 0.75519E-07 -7.1219 0.18628E+00 -0.7298 142 H2S2O3,aq 0.30426E-07 -7.5168 0.30426E-07 -7.5168 0.10000E+01 0.0000 150 S4O6-2 0.44313E-09 -9.3535 0.11287E-11 -11.9474 0.25472E-02 -2.5939 152 ZnCl+ 0.19426E-03 -3.7116 0.40294E-04 -4.3948 0.20743E+00 -0.6831 153 ZnCl2,aq 0.72113E-03 -3.1420 0.72113E-03 -3.1420 0.10000E+01 0.0000 154 ZnCl3- 0.58441E-04 -4.2333 0.10887E-04 -4.9631 0.18628E+00 -0.7298 155 ZnO,aq 0.31261E-07 -7.5050 0.31261E-07 -7.5050 0.10000E+01 0.0000 156 ZnOH+ 0.12735E-05 -5.8950 0.26415E-06 -6.5781 0.20743E+00 -0.6831 158 HZnO2- 0.24339E-09 -9.6137 0.45340E-10 -10.3435 0.18628E+00 -0.7298 Charge balance for all species = 0.2549E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5444737E-05 0.4296062E+01 0.3540553E+04 0.0000 2 H2O 0.1000000E+01 0.5251715E+02 0.7735858E+06 0.0000 3 Cl- 0.1375458E+00 0.6561257E+00 0.1901980E+05 4.3371 4 SO4-- 0.2195239E-03 0.2519058E+00 0.1978581E+05 5.6381 5 HCO3- 0.1141490E-04 0.2675133E+01 0.1334638E+06 0.2884 6 HS- 0.1219494E-03 0.1158181E+01 0.3131863E+05 1.2884 7 H4SiO4 0.5626630E-01 0.5626965E-01 0.4422146E+04 -1.2498 8 Al+++ 0.1381644E-16 0.1309789E-04 0.2889571E+00 -4.9389 9 Ca++ 0.1375860E-05 0.1801943E-03 0.5904906E+01 3.3397 10 Mg++ 0.1153789E-05 0.1478237E-04 0.2938534E+00 3.1782 11 Fe++ 0.1358547E-07 0.3745307E-02 0.1710225E+03 1.2707 12 K+ 0.3838100E-01 0.1256218E+00 0.4016333E+04 3.8256 13 Na+ 0.1233743E+00 0.5585708E+00 0.1049976E+05 4.2949 14 Mn++ 0.9459521E-06 0.1157558E-02 0.5199739E+02 3.1292 15 Zn++ 0.3358645E-09 0.9751363E-03 0.5212063E+02 -0.3362 16 Cu+ 0.1642317E-07 0.1033998E-03 0.5371960E+01 -2.5820 17 Pb++ 0.2837616E-08 0.3426086E-03 0.5804074E+02 0.7035 18 Ag+ 0.3026023E-09 0.8763148E-05 0.7729061E+00 -4.2845 19 Ba++ 0.7815586E-07 0.1123145E-04 0.1261243E+01 2.1748 20 HPO4-- 0.1175046E-08 0.2943227E-05 0.2309754E+00 0.3689 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265517E+01 -.3155132E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5214375E+02 -.1789698E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2501147E+00 0.1608049E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1149946E+01 0.1019776E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.5586957E-01 0.8772475E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1300477E-04 0.6815348E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1789131E-03 0.3489968E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1467727E-04 0.5999381E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.3718678E-02 0.5048076E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247286E+00 0.6815348E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149328E-02 0.1720722E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.9682031E-03 0.1331132E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1026646E-03 0.2969451E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1115160E-04 0.4422085E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2922300E-05 0.5645200E-05 0.0000000E+00 Chg. balance for solid moles: 0.2961E-17 Mass of aqueous solution: 0.121433E+04 g Temperature = 567.00 C Pressure = 1171.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3396E-03 -3.469 0.4623E-01 -1.335 0.7518 0.1560E-01 annite 0.8811E-06 -6.055 0.4510E-03 -3.346 0.7335E-02 0.1360E-03 phlogopite 0.2000E-05 -5.699 0.8345E-03 -3.079 0.1357E-01 0.2992E-03 biotite-Mn 0.5736E-07 -7.241 0.2920E-04 -4.535 0.4749E-03 0.8754E-05 apatite-OH 0.1882E-05 -5.725 0.9452E-03 -3.024 0.1537E-01 0.3004E-03 microcline 0.6786E-03 -3.168 0.1889 -0.724 3.072 0.7378E-01 pyrite 0.4748E-02 -2.323 0.5697 -0.244 9.265 0.1137 quartz 0.8568E-01 -1.067 5.148 0.712 83.71 1.944 barite 0.4422E-04 -4.354 0.1032E-01 -1.986 0.1678 0.2304E-02 chalcopyrite 0.2969E-03 -3.527 0.5449E-01 -1.264 0.8861 0.1272E-01 sphalerite 0.1331E-02 -2.876 0.1297 -0.887 2.109 0.3172E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2999E+00 0.2999E+00 1.0000 -0.523 phlogopite 0.6806E+00 0.6806E+00 1.0000 -0.167 biotite-Mn 0.1952E-01 0.1952E-01 1.0000 -1.709 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.149261 g Volume = 2.194523 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.74 -14.74 0.00 0.000 0.00000E+00 24 annite 0.52 0.52 0.00 0.000 0.45242E-10 25 phlogopite 5.17 5.17 0.00 0.000 0.34145E-11 26 biotite-Mn 9.65 9.65 0.00 0.000 0.20487E-10 30 apatite-OH -53.34 -53.34 0.00 0.000 0.00000E+00 115 microcline -4.86 -4.86 0.00 0.000 0.00000E+00 140 pyrite -21.74 -21.74 0.00 0.000 0.13658E-10 144 quartz -1.25 -1.25 0.00 0.000 0.00000E+00 237 barite -15.90 -15.90 0.00 0.000 0.00000E+00 240 chalcopyrite -23.39 -23.39 0.00 0.000 -0.13658E-10 255 sphalerite -10.90 -10.90 0.00 0.000 -0.13658E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.27 -0.270 0.10395E+04 2.798 2 CO2,gas -9.91 -11.57 -1.65 -0.552 0.63608E+04 1.414 3 CH4,gas 6.87 -4.06 -10.93 -2.734 0.42036E+05 -7.866 4 H2,gas 5.94 1.88 -4.06 -2.322 0.15621E+05 -0.995 5 H2S,gas -8.26 -10.57 -2.31 -1.155 0.88813E+04 0.758 6 CO,gas -3.73 -9.69 -5.96 -1.833 0.22904E+05 -2.889 7 SO3,gas -7.48 -18.07 -10.59 -2.648 0.40715E+05 -7.522 8 O2,gas 16.75 -3.75 -20.51 -13.672 0.78842E+05 -17.440 9 HCl,gas -6.08 -7.52 -1.44 -0.721 0.55463E+04 -1.443 10 acmite 3.63 2.13 -1.50 -0.156 0.57724E+04 12 akimotoite 6.13 1.93 -4.20 -0.840 0.16149E+05 13 akimotoite-Fe 4.02 0.02 -3.99 -0.799 0.15353E+05 14 albite-high -4.26 -4.39 -0.13 -0.010 0.48539E+03 15 albite -4.25 -4.39 -0.14 -0.010 0.52314E+03 16 almandine -8.04 -9.81 -1.78 -0.089 0.68347E+04 17 pyrope -1.35 -4.09 -2.75 -0.137 0.10560E+05 18 analcite -2.17 -3.14 -0.97 -0.107 0.37190E+04 19 andalusite -10.60 -11.13 -0.53 -0.053 0.20467E+04 20 andradite 11.70 6.94 -4.77 -0.248 0.18329E+05 27 anorthite -8.29 -9.04 -0.75 -0.057 0.28656E+04 28 anthophyllite 14.52 12.26 -2.26 -0.061 0.86804E+04 29 anthophyllite-Fe 1.77 -1.09 -2.86 -0.077 0.10999E+05 31 apatite-OH-zs -51.17 -53.34 -2.17 -0.167 0.83358E+04 32 apatite-Cl-zs -57.63 -60.86 -3.23 -0.269 0.12403E+05 33 aragonite -4.61 -8.23 -3.62 -1.206 0.13905E+05 34 brucite 5.44 3.18 -2.26 -0.452 0.86962E+04 35 calcite -4.72 -8.23 -3.51 -1.171 0.13506E+05 36 carnegieite-low -0.12 -1.89 -1.77 -0.253 0.68132E+04 37 carnegieite-high -0.04 -1.89 -1.85 -0.264 0.71164E+04 38 carpholite-Mg -7.15 -9.20 -2.05 -0.137 0.78827E+04 39 carpholite-Fe -8.52 -11.11 -2.59 -0.173 0.99499E+04 40 celadonite -0.82 -2.93 -2.11 -0.124 0.80954E+04 41 celadonite-Fe -2.24 -4.84 -2.59 -0.153 0.99752E+04 42 chrysotile 9.46 7.03 -2.43 -0.203 0.93464E+04 44 clinochlore 3.73 2.25 -1.47 -0.046 0.56599E+04 45 daphnite -3.41 -7.28 -3.87 -0.121 0.14890E+05 48 chloritoid-Mg -6.59 -7.95 -1.37 -0.091 0.52524E+04 49 chloritoid-Fe -8.54 -9.86 -1.32 -0.088 0.50637E+04 50 chloritoid-Mn -6.39 -8.00 -1.61 -0.107 0.61829E+04 52 coesite -0.96 -1.25 -0.29 -0.096 0.11109E+04 53 cordierite-H -18.71 -19.65 -0.94 -0.033 0.35985E+04 54 cordierite-Fe -21.32 -23.46 -2.14 -0.074 0.82340E+04 55 cordierite-Mn -16.95 -19.74 -2.80 -0.096 0.10751E+05 56 corundum -9.17 -9.88 -0.71 -0.064 0.27196E+04 58 cristobalite -1.20 -1.25 -0.05 -0.016 0.18033E+03 59 cummingtonite 14.59 12.26 -2.32 -0.063 0.89354E+04 61 cymrite-K -2.56 -4.86 -2.30 -0.192 0.88476E+04 63 diaspore -4.09 -4.94 -0.85 -0.142 0.32827E+04 65 diopside 5.39 4.02 -1.37 -0.137 0.52599E+04 66 hedenbergite 3.95 2.11 -1.84 -0.184 0.70695E+04 68 eastonite -5.78 -7.14 -1.36 -0.052 0.52344E+04 69 enstatite 4.74 3.86 -0.88 -0.088 0.33865E+04 70 clinoenstatite-HiP 5.24 3.86 -1.38 -0.138 0.52921E+04 71 clinoenstatite 4.72 3.86 -0.86 -0.086 0.33242E+04 72 protoenstatite 4.87 3.86 -1.01 -0.101 0.38952E+04 73 epidote -4.34 -6.62 -2.28 -0.110 0.87462E+04 74 clinozoisite -9.17 -11.89 -2.72 -0.124 0.10456E+05 75 epidote-Fe 2.17 -1.34 -3.52 -0.183 0.13522E+05 76 fayalite 2.28 1.29 -0.99 -0.142 0.38162E+04 77 ferrosilite 1.13 0.04 -1.09 -0.109 0.41877E+04 78 forsterite 6.31 5.11 -1.20 -0.171 0.46137E+04 79 gedrite -9.16 -11.36 -2.20 -0.060 0.84699E+04 81 gibbsite -2.46 -4.94 -2.48 -0.354 0.95326E+04 82 glaucophane 1.35 -1.74 -3.09 -0.083 0.11867E+05 83 glaucophane-Fe -2.75 -7.46 -4.72 -0.127 0.18132E+05 84 goethite 1.17 0.33 -0.84 -0.181 0.32195E+04 86 greenalite 4.55 1.31 -3.24 -0.270 0.12447E+05 87 grunerite 2.32 -1.09 -3.42 -0.092 0.13134E+05 88 halite -1.18 -3.22 -2.04 -1.021 0.78505E+04 89 hematite 0.79 0.66 -0.13 -0.016 0.50138E+03 90 heulandite -12.16 -15.28 -3.12 -0.142 0.12007E+05 91 hercynite -7.43 -8.61 -1.18 -0.079 0.45297E+04 94 jadeite -1.49 -3.14 -1.65 -0.165 0.63398E+04 96 kalsilite -0.74 -2.36 -1.62 -0.231 0.62226E+04 97 kaolinite -9.61 -12.38 -2.77 -0.252 0.10645E+05 98 kyanite -10.43 -11.13 -0.69 -0.069 0.26698E+04 100 laumontite -7.91 -11.54 -3.63 -0.242 0.13943E+05 101 lawsonite -5.52 -9.04 -3.52 -0.235 0.13529E+05 102 leucite -2.65 -3.61 -0.96 -0.096 0.36815E+04 104 lizardite 9.64 7.03 -2.60 -0.217 0.10014E+05 105 magnesite -5.47 -8.39 -2.92 -0.974 0.11228E+05 106 magnetite 2.01 1.93 -0.08 -0.007 0.31308E+03 107 minnesotaite 0.80 -1.18 -1.98 -0.116 0.76025E+04 108 minnesotaite-Mg 6.81 4.54 -2.27 -0.133 0.87161E+04 109 magnesioferrite 5.10 3.84 -1.26 -0.103 0.48388E+04 111 manganosite 5.39 3.13 -2.27 -0.567 0.87132E+04 112 margarite -17.00 -18.92 -1.92 -0.077 0.73904E+04 116 monticellite 8.79 5.27 -3.53 -0.504 0.13558E+05 118 mullite-Si -9.85 -11.13 -1.28 -0.128 0.49218E+04 119 muscovite -13.90 -14.74 -0.84 -0.050 0.32401E+04 120 paragonite -13.22 -14.27 -1.06 -0.062 0.40590E+04 121 nepheline -0.42 -1.89 -1.47 -0.211 0.56683E+04 122 osumilite(2) -13.16 -15.18 -2.02 -0.042 0.77600E+04 123 osumilite-Fe -28.28 -30.81 -2.53 -0.053 0.97271E+04 124 pargasite 5.40 1.37 -4.03 -0.106 0.15487E+05 125 periclase 5.63 3.18 -2.45 -0.613 0.94330E+04 126 periclase-Fe 3.04 1.27 -1.77 -0.443 0.68060E+04 127 perovskite-Al -7.44 -9.88 -2.44 -0.222 0.93803E+04 132 phlogopite-Na 6.04 5.14 -0.90 -0.050 0.34701E+04 134 prehnite -3.60 -6.95 -3.35 -0.197 0.12868E+05 135 prehnite-Fe 1.62 -1.68 -3.30 -0.198 0.12670E+05 138 px-Mg-tschermaks -5.99 -7.95 -1.97 -0.140 0.75549E+04 139 px-Ca-tschermaks -5.15 -7.79 -2.64 -0.188 0.10139E+05 141 pyrrhotite -8.65 -9.30 -0.65 -0.216 0.24939E+04 142 pyrrhotiteFe0.875 -9.42 -9.69 -0.27 -0.099 0.10313E+04 143 pyrophyllite -13.47 -14.87 -1.41 -0.088 0.54014E+04 146 riebeckite 5.81 3.08 -2.73 -0.075 0.10485E+05 147 ringwoodite-Fe 3.28 1.29 -1.99 -0.284 0.76486E+04 148 ringwoodite-Mg 9.46 5.11 -4.35 -0.622 0.16740E+05 149 rhodochrosite -5.44 -8.44 -3.00 -1.000 0.11528E+05 150 rhodonite 2.52 1.88 -0.64 -0.128 0.24649E+04 151 sanidine -4.32 -4.86 -0.54 -0.041 0.20674E+04 153 siderite -7.32 -10.30 -2.98 -0.993 0.11451E+05 154 sillimanite -10.56 -11.13 -0.57 -0.057 0.21835E+04 156 spinel -5.25 -6.71 -1.45 -0.097 0.55920E+04 162 stilpnomelane-Fe -6.78 -11.61 -4.83 -0.144 0.18577E+05 163 stilpnomelane-Mg 0.11 -2.07 -2.18 -0.065 0.83640E+04 164 stishovite 1.71 -1.25 -2.95 -0.985 0.11358E+05 165 sudoite-Fe -16.68 -20.97 -4.30 -0.139 0.16519E+05 166 sudoite -14.43 -17.16 -2.73 -0.088 0.10491E+05 167 sulfur -10.94 -12.44 -1.50 -0.462 0.57696E+04 168 sylvite -1.09 -3.69 -2.61 -1.303 0.10018E+05 169 talc 5.08 4.54 -0.54 -0.032 0.20728E+04 170 talc-Fe 2.20 -1.18 -3.38 -0.199 0.12994E+05 171 talc-tschermaks -5.57 -7.27 -1.70 -0.100 0.65365E+04 173 tephroite 6.56 5.01 -1.55 -0.222 0.59656E+04 176 topaz-H -8.50 -11.13 -2.63 -0.239 0.10104E+05 177 tremolite 15.22 12.58 -2.63 -0.071 0.10126E+05 179 troilite-low -8.56 -9.30 -0.74 -0.247 0.28495E+04 180 tschermakite -7.68 -11.04 -3.36 -0.091 0.12900E+05 183 wadsleyite-Fe 3.13 1.29 -1.84 -0.263 0.70801E+04 184 wadsleyite-Mg 8.52 5.11 -3.41 -0.488 0.13119E+05 185 wairakite -9.78 -11.53 -1.76 -0.103 0.67597E+04 186 walstromite 4.61 2.09 -2.51 -0.503 0.96635E+04 187 wollastonite 4.18 2.09 -2.09 -0.419 0.80480E+04 188 pseudo-wollastonite 4.30 2.09 -2.21 -0.442 0.84950E+04 189 zoisite -9.22 -11.89 -2.67 -0.121 0.10252E+05 192 beidellite-Ca -13.79 -15.54 -1.75 -0.108 0.67211E+04 193 beidellite-H -13.82 -16.09 -2.27 -0.145 0.87450E+04 194 beidellite-K -12.77 -14.83 -2.06 -0.126 0.79218E+04 195 beidellite-Mg -14.05 -15.57 -1.51 -0.094 0.58171E+04 196 beidellite-Na -12.71 -14.67 -1.96 -0.120 0.75521E+04 197 bornite -54.45 -54.85 -0.40 -0.030 0.15470E+04 199 chalcocite -14.22 -15.73 -1.51 -0.378 0.58129E+04 200 covellite -12.69 -14.09 -1.40 -0.533 0.53791E+04 202 montmorillonite-Ca -10.33 -11.64 -1.31 -0.081 0.50448E+04 203 montmorillonite-K -9.59 -10.93 -1.34 -0.082 0.51575E+04 204 montmorillonite-Mg -10.55 -11.67 -1.12 -0.069 0.43048E+04 205 montmorillonite-Na -9.25 -10.77 -1.53 -0.094 0.58730E+04 206 nontronite-Ca -3.57 -5.00 -1.43 -0.093 0.54868E+04 207 nontronite-H -3.60 -5.55 -1.95 -0.130 0.74825E+04 208 nontronite-K -2.55 -4.28 -1.74 -0.112 0.66794E+04 209 nontronite-Mg -3.79 -5.02 -1.23 -0.080 0.47263E+04 210 nontronite-Na -2.48 -4.13 -1.64 -0.106 0.63225E+04 215 gypsum -12.50 -14.74 -2.24 -0.560 0.86117E+04 232 alabandite -6.38 -7.44 -1.06 -0.355 0.40913E+04 234 anglesite -14.99 -17.37 -2.38 -1.190 0.91476E+04 238 boehmite -3.80 -4.94 -1.14 -0.191 0.44005E+04 242 copper,native 1.74 -1.64 -3.38 -1.177 0.13007E+05 244 ferrous-oxide 2.11 1.27 -0.84 -0.211 0.32458E+04 245 galena -9.79 -9.87 -0.07 -0.025 0.28497E+03 246 silver,native 0.47 -3.35 -3.82 -1.328 0.14681E+05 248 litharge 5.31 0.70 -4.60 -1.151 0.17703E+05 256 wurtzite -10.10 -10.90 -0.80 -0.268 0.30876E+04 257 zincite 2.21 -0.34 -2.55 -0.637 0.97940E+04 258 an20ab80 -5.28 -5.32 -0.04 -0.003 0.15669E+03 259 an25ab75 -5.51 -5.55 -0.04 -0.003 0.16969E+03 260 an30ab70 -5.73 -5.78 -0.05 -0.004 0.20665E+03 261 tr.625ac.25prg.125 9.79 8.80 -0.99 -0.027 0.38205E+04 Calculations done for 567.0000 Deg. C; 1171.0000 bar Temperature changed by -1.000 degrees to 566.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 34 Loop limit = 500 Temperature = 566.00 C Pressure = 1155.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5512E+02 kg liquid = 0.9929E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9966 Stoichiometric ionic strength = .3279568E+01 Osmotic coef. = 0.0000 True ionic strength = .1609359E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.53084E-05 -5.2750 0.11420E-05 -5.9424 0.21512E+00 -0.6673 2 H2O 0.99664E+00 -0.0015 0.99664E+00 -0.0015 3 Cl- 0.13536E+00 -0.8685 0.25020E-01 -1.6017 0.18484E+00 -0.7332 4 SO4-- 0.22154E-03 -3.6546 0.59319E-06 -6.2268 0.26776E-02 -2.5723 5 HCO3- 0.11057E-04 -4.9563 0.22010E-05 -5.6574 0.19905E+00 -0.7010 6 HS- 0.12081E-03 -3.9179 0.22515E-04 -4.6475 0.18636E+00 -0.7296 7 H4SiO4 0.55124E-01 -1.2587 0.55124E-01 -1.2587 0.10000E+01 0.0000 8 Al+++ 0.14577E-16 -16.8363 0.18716E-22 -22.7278 0.12840E-05 -5.8914 9 Ca++ 0.13467E-05 -5.8707 0.28942E-08 -8.5385 0.21491E-02 -2.6678 10 Mg++ 0.11735E-05 -5.9305 0.20740E-08 -8.6832 0.17673E-02 -2.7527 11 Fe++ 0.13390E-07 -7.8732 0.24867E-10 -10.6044 0.18572E-02 -2.7312 12 K+ 0.37851E-01 -1.4219 0.77196E-02 -2.1124 0.20395E+00 -0.6905 13 Na+ 0.12136E+00 -0.9159 0.22690E-01 -1.6442 0.18696E+00 -0.7283 14 Mn++ 0.97390E-06 -6.0115 0.18754E-08 -8.7269 0.19256E-02 -2.7154 15 Zn++ 0.33216E-09 -9.4787 0.61687E-12 -12.2098 0.18572E-02 -2.7312 16 Cu+ 0.15849E-07 -7.8000 0.29553E-08 -8.5294 0.18647E+00 -0.7294 17 Pb++ 0.28066E-08 -8.5518 0.67577E-11 -11.1702 0.24078E-02 -2.6184 18 Ag+ 0.30163E-09 -9.5205 0.60555E-10 -10.2178 0.20076E+00 -0.6973 19 Ba++ 0.75326E-07 -7.1231 0.19489E-09 -9.7102 0.25873E-02 -2.5872 20 HPO4-- 0.11966E-08 -8.9220 0.32203E-11 -11.4921 0.26911E-02 -2.5701 21 HSiO3- 0.14929E-05 -5.8260 0.27594E-06 -6.5592 0.18484E+00 -0.7332 22 Ca(HSiO3)+ 0.54471E-08 -8.2638 0.11207E-08 -8.9505 0.20575E+00 -0.6867 23 Mg(HSiO3)+ 0.11991E-08 -8.9211 0.24672E-09 -9.6078 0.20575E+00 -0.6867 24 NaHSiO3,aq 0.18405E-05 -5.7351 0.18405E-05 -5.7351 0.10000E+01 0.0000 28 AgCl,aq 0.10545E-06 -6.9770 0.10545E-06 -6.9770 0.10000E+01 0.0000 29 AgCl2- 0.52149E-05 -5.2828 0.96389E-06 -6.0160 0.18484E+00 -0.7332 30 AgCl3-2 0.18676E-05 -5.7287 0.46285E-08 -8.3346 0.24783E-02 -2.6059 31 AgCl4-3 0.15668E-05 -5.8050 0.17560E-11 -11.7555 0.11208E-05 -5.9505 34 Ag(HS),aq 0.15460E-08 -8.8108 0.15460E-08 -8.8108 0.10000E+01 0.0000 35 Ag(HS)2- 0.62269E-08 -8.2057 0.11509E-08 -8.9389 0.18484E+00 -0.7332 38 HAlO2,aq 0.41270E-08 -8.3844 0.41270E-08 -8.3844 0.10000E+01 0.0000 39 AlO2- 0.12800E-04 -4.8928 0.20756E-05 -5.6829 0.16216E+00 -0.7901 41 Ba(HCO3)+ 0.27164E-06 -6.5660 0.58157E-07 -7.2354 0.21410E+00 -0.6694 42 BaCl+ 0.10352E-04 -4.9850 0.21299E-05 -5.6716 0.20575E+00 -0.6867 43 CH4,aq 0.16014E-08 -8.7955 0.19099E-08 -8.7190 0.11926E+01 0.0765 48 CO,aq 0.56467E-03 -3.2482 0.56467E-03 -3.2482 0.10000E+01 0.0000 49 CO2,aq 0.26745E+01 0.4272 0.31896E+01 0.5037 0.11926E+01 0.0765 50 CO3-2 0.39477E-10 -10.4037 0.97834E-13 -13.0095 0.24783E-02 -2.6059 51 CaCO3,aq 0.10959E-10 -10.9602 0.10959E-10 -10.9602 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.13362E-06 -6.8741 0.27491E-07 -7.5608 0.20575E+00 -0.6867 53 CaCl+ 0.87851E-04 -4.0563 0.18075E-04 -4.7429 0.20575E+00 -0.6867 54 CaCl2,aq 0.85216E-04 -4.0695 0.85216E-04 -4.0695 0.10000E+01 0.0000 55 CaOH+ 0.16561E-06 -6.7809 0.34074E-07 -7.4676 0.20575E+00 -0.6867 56 CaSO4,aq 0.15942E-06 -6.7975 0.15942E-06 -6.7975 0.10000E+01 0.0000 57 HCl,aq 0.26682E-02 -2.5738 0.26682E-02 -2.5738 0.10000E+01 0.0000 66 CuCl,aq 0.22426E-04 -4.6492 0.22426E-04 -4.6492 0.10000E+01 0.0000 67 CuCl2- 0.77649E-04 -4.1099 0.14352E-04 -4.8431 0.18484E+00 -0.7332 68 CuCl3-2 0.15028E-05 -5.8231 0.37244E-08 -8.4289 0.24783E-02 -2.6059 74 FeCl+ 0.27126E-06 -6.5666 0.55810E-07 -7.2533 0.20575E+00 -0.6867 75 FeCl2,aq 0.35942E-02 -2.4444 0.35942E-02 -2.4444 0.10000E+01 0.0000 77 FeO,aq 0.65713E-07 -7.1823 0.65713E-07 -7.1823 0.10000E+01 0.0000 78 FeOH+ 0.22850E-07 -7.6411 0.47013E-08 -8.3278 0.20575E+00 -0.6867 79 HFeO2- 0.77912E-08 -8.1084 0.14401E-08 -8.8416 0.18484E+00 -0.7332 82 FeO2- 0.48745E-08 -8.3121 0.90097E-09 -9.0453 0.18484E+00 -0.7332 83 HFeO2,aq 0.28801E-09 -9.5406 0.28801E-09 -9.5406 0.10000E+01 0.0000 84 H2,aq 0.46263E-02 -2.3348 0.55173E-02 -2.2583 0.11926E+01 0.0765 85 KCl,aq 0.69752E-01 -1.1564 0.69752E-01 -1.1564 0.10000E+01 0.0000 86 KHSO4,aq 0.13448E-01 -1.8713 0.13448E-01 -1.8713 0.10000E+01 0.0000 87 KOH,aq 0.13304E-05 -5.8760 0.13304E-05 -5.8760 0.10000E+01 0.0000 88 KSO4- 0.45646E-02 -2.3406 0.84371E-03 -3.0738 0.18484E+00 -0.7332 90 Mg(HCO3)+ 0.33678E-07 -7.4727 0.69291E-08 -8.1593 0.20575E+00 -0.6867 91 MgCl+ 0.13155E-04 -4.8809 0.27067E-05 -5.5676 0.20575E+00 -0.6867 92 MgOH+ 0.50652E-06 -6.2954 0.10421E-06 -6.9821 0.20575E+00 -0.6867 94 MnO,aq 0.82327E-07 -7.0845 0.82327E-07 -7.0845 0.10000E+01 0.0000 95 MnOH+ 0.19425E-06 -6.7116 0.39967E-07 -7.3983 0.20575E+00 -0.6867 97 HMnO2- 0.39982E-10 -10.3981 0.73901E-11 -11.1314 0.18484E+00 -0.7332 100 MnCl+ 0.11562E-02 -2.9370 0.23787E-03 -3.6237 0.20575E+00 -0.6867 101 MnSO4,aq 0.11557E-06 -6.9371 0.11557E-06 -6.9371 0.10000E+01 0.0000 102 NaCl,aq 0.43718E+00 -0.3593 0.43718E+00 -0.3593 0.10000E+01 0.0000 103 NaOH,aq 0.17953E-05 -5.7459 0.17953E-05 -5.7459 0.10000E+01 0.0000 105 OH- 0.77376E-05 -5.1114 0.12547E-05 -5.9015 0.16216E+00 -0.7901 110 HPO3-2 0.10230E-10 -10.9901 0.25352E-13 -13.5960 0.24783E-02 -2.6059 111 H3PO3,aq 0.10991E-09 -9.9590 0.10991E-09 -9.9590 0.10000E+01 0.0000 112 H2PO3- 0.21436E-08 -8.6689 0.39621E-09 -9.4021 0.18484E+00 -0.7332 113 H3PO4,aq 0.11540E-05 -5.9378 0.11540E-05 -5.9378 0.10000E+01 0.0000 114 H2PO4- 0.13548E-05 -5.8681 0.26320E-06 -6.5797 0.19428E+00 -0.7116 116 H4P2O7,aq 0.12306E-09 -9.9099 0.12306E-09 -9.9099 0.10000E+01 0.0000 117 H3P2O7- 0.82370E-09 -9.0842 0.15225E-09 -9.8174 0.18484E+00 -0.7332 118 H2P2O7-2 0.20999E-06 -6.6778 0.52041E-09 -9.2837 0.24783E-02 -2.6059 119 HP2O7-3 0.19286E-07 -7.7148 0.21615E-13 -13.6653 0.11208E-05 -5.9505 121 PbCl+ 0.13565E-05 -5.8676 0.27909E-06 -6.5543 0.20575E+00 -0.6867 122 PbCl2,aq 0.86396E-04 -4.0635 0.86396E-04 -4.0635 0.10000E+01 0.0000 123 PbCl3- 0.10113E-03 -3.9951 0.18693E-04 -4.7283 0.18484E+00 -0.7332 124 PbCl4-2 0.18431E-04 -4.7345 0.45676E-07 -7.3403 0.24783E-02 -2.6059 125 PbO,aq 0.62472E-08 -8.2043 0.62472E-08 -8.2043 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12191E-03 -3.9140 0.12191E-03 -3.9140 0.10000E+01 0.0000 128 Pb(HS)3- 0.13362E-04 -4.8741 0.24698E-05 -5.6073 0.18484E+00 -0.7332 129 H2S,aq 0.10566E+01 0.0239 0.12601E+01 0.1004 0.11926E+01 0.0765 130 S2-2 0.12698E-07 -7.8963 0.31470E-10 -10.5021 0.24783E-02 -2.6059 131 S3-2 0.11817E-08 -8.9275 0.29286E-11 -11.5333 0.24783E-02 -2.6059 132 S3- 0.11097E-01 -1.9548 0.20511E-02 -2.6880 0.18484E+00 -0.7332 133 S4-2 0.93159E-10 -10.0308 0.23087E-12 -12.6366 0.24783E-02 -2.6059 135 SO2,aq 0.29239E+00 -0.5340 0.29239E+00 -0.5340 0.10000E+01 0.0000 136 SO3-2 0.62511E-09 -9.2040 0.24592E-11 -11.6092 0.39339E-02 -2.4052 137 HSO3- 0.26736E-03 -3.5729 0.49417E-04 -4.3061 0.18484E+00 -0.7332 138 HSO4- 0.84895E-02 -2.0711 0.17944E-02 -2.7461 0.21137E+00 -0.6750 140 S2O3-2 0.49637E-06 -6.3042 0.12301E-08 -8.9100 0.24783E-02 -2.6059 141 HS2O3- 0.39799E-06 -6.4001 0.73562E-07 -7.1333 0.18484E+00 -0.7332 142 H2S2O3,aq 0.30945E-07 -7.5094 0.30945E-07 -7.5094 0.10000E+01 0.0000 150 S4O6-2 0.43837E-09 -9.3582 0.10864E-11 -11.9640 0.24783E-02 -2.6059 152 ZnCl+ 0.18520E-03 -3.7324 0.38105E-04 -4.4190 0.20575E+00 -0.6867 153 ZnCl2,aq 0.70139E-03 -3.1540 0.70139E-03 -3.1540 0.10000E+01 0.0000 154 ZnCl3- 0.55450E-04 -4.2561 0.10249E-04 -4.9893 0.18484E+00 -0.7332 155 ZnO,aq 0.30766E-07 -7.5119 0.30766E-07 -7.5119 0.10000E+01 0.0000 156 ZnOH+ 0.12246E-05 -5.9120 0.25196E-06 -6.5987 0.20575E+00 -0.6867 158 HZnO2- 0.23739E-09 -9.6245 0.43878E-10 -10.3578 0.18484E+00 -0.7332 Charge balance for all species = 0.2549E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5308376E-05 0.4295910E+01 0.3540813E+04 0.0000 2 H2O 0.1000000E+01 0.5251775E+02 0.7736790E+06 0.0000 3 Cl- 0.1353625E+00 0.6561029E+00 0.1902121E+05 4.3406 4 SO4-- 0.2215388E-03 0.2518537E+00 0.1978387E+05 5.6579 5 HCO3- 0.1105741E-04 0.2675040E+01 0.1334737E+06 0.2850 6 HS- 0.1208109E-03 0.1157845E+01 0.3131296E+05 1.2948 7 H4SiO4 0.5512430E-01 0.5512764E-01 0.4332869E+04 -1.2587 8 Al+++ 0.1457693E-16 0.1280382E-04 0.2825003E+00 -4.9007 9 Ca++ 0.1346722E-05 0.1748775E-03 0.5731300E+01 3.3462 10 Mg++ 0.1173526E-05 0.1487034E-04 0.2956342E+00 3.2015 11 Fe++ 0.1338982E-07 0.3594570E-02 0.1641572E+03 1.2803 12 K+ 0.3785099E-01 0.1256171E+00 0.4016622E+04 3.8299 13 Na+ 0.1213644E+00 0.5585514E+00 0.1050054E+05 4.2982 14 Mn++ 0.9738969E-06 0.1157517E-02 0.5200122E+02 3.1578 15 Zn++ 0.3321608E-09 0.9433013E-03 0.5042456E+02 -0.3251 16 Cu+ 0.1584912E-07 0.1015940E-03 0.5278717E+01 -2.5870 17 Pb++ 0.2806618E-08 0.3425967E-03 0.5804504E+02 0.7145 18 Ag+ 0.3016324E-09 0.8762844E-05 0.7729634E+00 -4.2755 19 Ba++ 0.7532603E-07 0.1069912E-04 0.1201596E+01 2.1745 20 HPO4-- 0.1196631E-08 0.2972651E-05 0.2333100E+00 0.3926 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265514E+01 -.3152060E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5214616E+02 -.1813822E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2500717E+00 0.1651086E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1149653E+01 0.1049143E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.5473759E-01 0.8885674E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1271323E-04 0.6818263E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1736401E-03 0.3542698E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1476512E-04 0.5911528E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.3569137E-02 0.5197617E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247283E+00 0.6818263E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149327E-02 0.1726671E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.9366269E-03 0.1362708E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1008752E-03 0.2987346E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1062342E-04 0.4474903E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2951618E-05 0.5615882E-05 0.0000000E+00 Chg. balance for solid moles: -.1938E-17 Mass of aqueous solution: 0.121424E+04 g Temperature = 566.00 C Pressure = 1155.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3449E-03 -3.462 0.4696E-01 -1.328 0.7526 0.1585E-01 annite 0.8472E-06 -6.072 0.4337E-03 -3.363 0.6951E-02 0.1307E-03 phlogopite 0.1971E-05 -5.705 0.8223E-03 -3.085 0.1318E-01 0.2948E-03 biotite-Mn 0.5756E-07 -7.240 0.2931E-04 -4.533 0.4697E-03 0.8784E-05 apatite-OH 0.1872E-05 -5.728 0.9403E-03 -3.027 0.1507E-01 0.2988E-03 microcline 0.6790E-03 -3.168 0.1890 -0.724 3.029 0.7382E-01 pyrite 0.4896E-02 -2.310 0.5875 -0.231 9.416 0.1172 quartz 0.8681E-01 -1.061 5.216 0.717 83.59 1.970 barite 0.4475E-04 -4.349 0.1044E-01 -1.981 0.1674 0.2331E-02 chalcopyrite 0.2987E-03 -3.525 0.5482E-01 -1.261 0.8786 0.1280E-01 sphalerite 0.1363E-02 -2.866 0.1328 -0.877 2.128 0.3247E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2946E+00 0.2946E+00 1.0000 -0.531 phlogopite 0.6853E+00 0.6853E+00 1.0000 -0.164 biotite-Mn 0.2002E-01 0.2002E-01 1.0000 -1.699 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.239275 g Volume = 2.224854 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.77 -14.77 0.00 0.000 0.68209E-11 24 annite 0.59 0.59 0.00 0.000 -0.52862E-10 25 phlogopite 5.25 5.25 0.00 0.000 -0.37515E-10 26 biotite-Mn 9.72 9.72 0.00 0.000 -0.27284E-10 30 apatite-OH -53.40 -53.40 0.00 0.000 0.00000E+00 115 microcline -4.84 -4.84 0.00 0.000 0.00000E+00 140 pyrite -21.78 -21.78 0.00 0.000 0.13642E-10 144 quartz -1.26 -1.26 0.00 0.000 0.00000E+00 237 barite -15.94 -15.94 0.00 0.000 0.00000E+00 240 chalcopyrite -23.43 -23.43 0.00 0.000 0.00000E+00 255 sphalerite -10.91 -10.91 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.27 -0.270 0.10348E+04 2.793 2 CO2,gas -9.94 -11.60 -1.66 -0.553 0.63753E+04 1.402 3 CH4,gas 6.87 -4.08 -10.95 -2.737 0.42035E+05 -7.885 4 H2,gas 5.94 1.88 -4.06 -2.323 0.15609E+05 -1.002 5 H2S,gas -8.28 -10.59 -2.31 -1.155 0.88716E+04 0.752 6 CO,gas -3.75 -9.72 -5.97 -1.837 0.22920E+05 -2.906 7 SO3,gas -7.51 -18.11 -10.60 -2.651 0.40712E+05 -7.540 8 O2,gas 16.77 -3.76 -20.53 -13.689 0.78845E+05 -17.471 9 HCl,gas -6.09 -7.54 -1.45 -0.727 0.55866E+04 -1.455 10 acmite 3.63 2.12 -1.51 -0.156 0.57807E+04 12 akimotoite 6.15 1.94 -4.20 -0.841 0.16139E+05 13 akimotoite-Fe 4.03 0.02 -4.01 -0.801 0.15382E+05 14 albite-high -4.24 -4.37 -0.13 -0.010 0.49532E+03 15 albite -4.23 -4.37 -0.14 -0.011 0.52941E+03 16 almandine -7.92 -9.74 -1.82 -0.091 0.69726E+04 17 pyrope -1.22 -3.97 -2.76 -0.138 0.10585E+05 18 analcite -2.15 -3.12 -0.97 -0.108 0.37269E+04 19 andalusite -10.52 -11.06 -0.54 -0.054 0.20919E+04 20 andradite 11.75 6.94 -4.80 -0.249 0.18437E+05 27 anorthite -8.21 -8.97 -0.76 -0.059 0.29337E+04 28 anthophyllite 14.59 12.35 -2.24 -0.061 0.86041E+04 29 anthophyllite-Fe 1.82 -1.10 -2.91 -0.079 0.11188E+05 31 apatite-OH-zs -51.23 -53.40 -2.17 -0.167 0.83384E+04 32 apatite-Cl-zs -57.71 -60.94 -3.23 -0.269 0.12410E+05 33 aragonite -4.62 -8.25 -3.63 -1.210 0.13933E+05 34 brucite 5.46 3.20 -2.26 -0.452 0.86805E+04 35 calcite -4.73 -8.25 -3.52 -1.175 0.13533E+05 36 carnegieite-low -0.09 -1.86 -1.78 -0.254 0.68186E+04 37 carnegieite-high -0.01 -1.86 -1.86 -0.265 0.71239E+04 38 carpholite-Mg -7.06 -9.12 -2.06 -0.137 0.79053E+04 39 carpholite-Fe -8.43 -11.04 -2.61 -0.174 0.10012E+05 40 celadonite -0.79 -2.90 -2.10 -0.124 0.80808E+04 41 celadonite-Fe -2.21 -4.82 -2.60 -0.153 0.10002E+05 42 chrysotile 9.51 7.09 -2.42 -0.202 0.93004E+04 44 clinochlore 3.89 2.42 -1.46 -0.046 0.56200E+04 45 daphnite -3.27 -7.18 -3.92 -0.122 0.15047E+05 48 chloritoid-Mg -6.49 -7.86 -1.37 -0.092 0.52793E+04 49 chloritoid-Fe -8.45 -9.78 -1.34 -0.089 0.51270E+04 50 chloritoid-Mn -6.30 -7.91 -1.61 -0.107 0.61692E+04 52 coesite -0.97 -1.26 -0.29 -0.097 0.11117E+04 53 cordierite-H -18.54 -19.49 -0.96 -0.034 0.36717E+04 54 cordierite-Fe -21.15 -23.33 -2.18 -0.075 0.83762E+04 55 cordierite-Mn -16.78 -19.58 -2.80 -0.096 0.10738E+05 56 corundum -9.09 -9.81 -0.72 -0.065 0.27653E+04 58 cristobalite -1.21 -1.26 -0.05 -0.016 0.18056E+03 59 cummingtonite 14.66 12.35 -2.31 -0.062 0.88598E+04 61 cymrite-K -2.54 -4.84 -2.31 -0.192 0.88529E+04 63 diaspore -4.04 -4.90 -0.86 -0.143 0.33004E+04 65 diopside 5.41 4.03 -1.37 -0.137 0.52713E+04 66 hedenbergite 3.97 2.11 -1.85 -0.185 0.71205E+04 68 eastonite -5.62 -6.99 -1.37 -0.053 0.52532E+04 69 enstatite 4.77 3.89 -0.88 -0.088 0.33678E+04 70 clinoenstatite-HiP 5.26 3.89 -1.37 -0.137 0.52735E+04 71 clinoenstatite 4.75 3.89 -0.86 -0.086 0.33047E+04 72 protoenstatite 4.90 3.89 -1.01 -0.101 0.38762E+04 73 epidote -4.24 -6.55 -2.31 -0.112 0.88554E+04 74 clinozoisite -9.04 -11.79 -2.75 -0.125 0.10565E+05 75 epidote-Fe 2.25 -1.30 -3.55 -0.184 0.13629E+05 76 fayalite 2.31 1.30 -1.01 -0.144 0.38730E+04 77 ferrosilite 1.15 0.05 -1.11 -0.111 0.42457E+04 78 forsterite 6.34 5.14 -1.20 -0.171 0.45929E+04 79 gedrite -8.93 -11.15 -2.22 -0.060 0.85055E+04 81 gibbsite -2.42 -4.91 -2.49 -0.355 0.95465E+04 82 glaucophane 1.42 -1.66 -3.08 -0.083 0.11835E+05 83 glaucophane-Fe -2.68 -7.42 -4.74 -0.128 0.18216E+05 84 goethite 1.18 0.34 -0.84 -0.182 0.32400E+04 86 greenalite 4.58 1.32 -3.26 -0.272 0.12515E+05 87 grunerite 2.37 -1.10 -3.47 -0.094 0.13325E+05 88 halite -1.20 -3.25 -2.04 -1.021 0.78373E+04 89 hematite 0.82 0.68 -0.14 -0.017 0.54669E+03 90 heulandite -12.11 -15.26 -3.15 -0.143 0.12078E+05 91 hercynite -7.33 -8.53 -1.20 -0.080 0.46040E+04 94 jadeite -1.46 -3.12 -1.65 -0.165 0.63449E+04 96 kalsilite -0.71 -2.33 -1.62 -0.232 0.62246E+04 97 kaolinite -9.54 -12.32 -2.78 -0.253 0.10669E+05 98 kyanite -10.35 -11.06 -0.71 -0.071 0.27159E+04 100 laumontite -7.84 -11.49 -3.65 -0.243 0.14000E+05 101 lawsonite -5.44 -8.98 -3.54 -0.236 0.13585E+05 102 leucite -2.63 -3.59 -0.96 -0.096 0.36853E+04 104 lizardite 9.68 7.09 -2.59 -0.216 0.99629E+04 105 magnesite -5.48 -8.40 -2.92 -0.974 0.11223E+05 106 magnetite 2.06 1.96 -0.10 -0.008 0.38691E+03 107 minnesotaite 0.81 -1.19 -2.00 -0.118 0.76763E+04 108 minnesotaite-Mg 6.83 4.58 -2.26 -0.133 0.86734E+04 109 magnesioferrite 5.15 3.88 -1.27 -0.104 0.48742E+04 111 manganosite 5.41 3.16 -2.26 -0.564 0.86643E+04 112 margarite -16.83 -18.78 -1.95 -0.078 0.74965E+04 116 monticellite 8.82 5.29 -3.53 -0.505 0.13568E+05 118 mullite-Si -9.77 -11.06 -1.29 -0.129 0.49696E+04 119 muscovite -13.79 -14.65 -0.85 -0.050 0.32825E+04 120 paragonite -13.11 -14.18 -1.07 -0.063 0.41057E+04 121 nepheline -0.38 -1.86 -1.48 -0.211 0.56730E+04 122 osumilite(2) -13.07 -15.09 -2.03 -0.042 0.77783E+04 123 osumilite-Fe -28.11 -30.68 -2.57 -0.054 0.98774E+04 124 pargasite 5.59 1.54 -4.05 -0.107 0.15545E+05 125 periclase 5.65 3.20 -2.45 -0.613 0.94221E+04 126 periclase-Fe 3.06 1.28 -1.78 -0.445 0.68350E+04 127 perovskite-Al -7.35 -9.81 -2.45 -0.223 0.94265E+04 132 phlogopite-Na 6.12 5.23 -0.90 -0.050 0.34386E+04 134 prehnite -3.51 -6.88 -3.37 -0.198 0.12949E+05 135 prehnite-Fe 1.68 -1.64 -3.32 -0.200 0.12751E+05 138 px-Mg-tschermaks -5.88 -7.86 -1.98 -0.141 0.75931E+04 139 px-Ca-tschermaks -5.06 -7.72 -2.66 -0.190 0.10206E+05 141 pyrrhotite -8.66 -9.31 -0.65 -0.218 0.25122E+04 142 pyrrhotiteFe0.875 -9.43 -9.70 -0.27 -0.100 0.10465E+04 143 pyrophyllite -13.41 -14.83 -1.42 -0.089 0.54411E+04 146 riebeckite 5.82 3.06 -2.75 -0.076 0.10575E+05 147 ringwoodite-Fe 3.31 1.30 -2.01 -0.287 0.77035E+04 148 ringwoodite-Mg 9.50 5.14 -4.35 -0.622 0.16718E+05 149 rhodochrosite -5.45 -8.44 -2.99 -0.997 0.11483E+05 150 rhodonite 2.53 1.90 -0.63 -0.126 0.24165E+04 151 sanidine -4.30 -4.84 -0.54 -0.041 0.20671E+04 153 siderite -7.33 -10.32 -2.99 -0.997 0.11483E+05 154 sillimanite -10.48 -11.06 -0.58 -0.058 0.22298E+04 156 spinel -5.14 -6.61 -1.47 -0.098 0.56268E+04 162 stilpnomelane-Fe -6.68 -11.55 -4.88 -0.146 0.18724E+05 163 stilpnomelane-Mg 0.22 -1.95 -2.17 -0.065 0.83322E+04 164 stishovite 1.70 -1.26 -2.96 -0.986 0.11357E+05 165 sudoite-Fe -16.49 -20.83 -4.34 -0.140 0.16663E+05 166 sudoite -14.24 -16.98 -2.75 -0.089 0.10555E+05 167 sulfur -10.97 -12.47 -1.50 -0.462 0.57594E+04 168 sylvite -1.11 -3.71 -2.60 -1.302 0.99986E+04 169 talc 5.10 4.58 -0.53 -0.031 0.20315E+04 170 talc-Fe 2.22 -1.19 -3.40 -0.200 0.13069E+05 171 talc-tschermaks -5.47 -7.17 -1.71 -0.100 0.65525E+04 173 tephroite 6.58 5.06 -1.53 -0.218 0.58665E+04 176 topaz-H -8.42 -11.06 -2.64 -0.240 0.10140E+05 177 tremolite 15.28 12.64 -2.63 -0.071 0.10109E+05 179 troilite-low -8.56 -9.31 -0.75 -0.249 0.28668E+04 180 tschermakite -7.47 -10.86 -3.38 -0.091 0.12993E+05 183 wadsleyite-Fe 3.16 1.30 -1.86 -0.266 0.71370E+04 184 wadsleyite-Mg 8.56 5.14 -3.41 -0.487 0.13099E+05 185 wairakite -9.71 -11.49 -1.78 -0.104 0.68179E+04 186 walstromite 4.61 2.09 -2.52 -0.504 0.96852E+04 187 wollastonite 4.19 2.09 -2.10 -0.420 0.80686E+04 188 pseudo-wollastonite 4.31 2.09 -2.22 -0.444 0.85165E+04 189 zoisite -9.09 -11.79 -2.70 -0.123 0.10363E+05 192 beidellite-Ca -13.72 -15.48 -1.76 -0.109 0.67711E+04 193 beidellite-H -13.74 -16.03 -2.29 -0.146 0.87907E+04 194 beidellite-K -12.70 -14.77 -2.07 -0.127 0.79609E+04 195 beidellite-Mg -13.98 -15.51 -1.53 -0.094 0.58639E+04 196 beidellite-Na -12.64 -14.62 -1.98 -0.121 0.75926E+04 197 bornite -54.56 -54.95 -0.39 -0.029 0.15005E+04 199 chalcocite -14.26 -15.76 -1.51 -0.377 0.57874E+04 200 covellite -12.72 -14.12 -1.40 -0.531 0.53568E+04 202 montmorillonite-Ca -10.28 -11.60 -1.32 -0.082 0.50760E+04 203 montmorillonite-K -9.54 -10.89 -1.35 -0.083 0.51811E+04 204 montmorillonite-Mg -10.50 -11.63 -1.13 -0.070 0.43301E+04 205 montmorillonite-Na -9.20 -10.74 -1.53 -0.094 0.58939E+04 206 nontronite-Ca -3.56 -5.00 -1.44 -0.094 0.55390E+04 207 nontronite-H -3.59 -5.55 -1.96 -0.131 0.75300E+04 208 nontronite-K -2.54 -4.29 -1.75 -0.112 0.67206E+04 209 nontronite-Mg -3.78 -5.02 -1.24 -0.081 0.47730E+04 210 nontronite-Na -2.47 -4.13 -1.66 -0.106 0.63650E+04 215 gypsum -12.53 -14.77 -2.24 -0.561 0.86113E+04 232 alabandite -6.38 -7.43 -1.05 -0.350 0.40343E+04 234 anglesite -15.03 -17.40 -2.37 -1.185 0.90991E+04 238 boehmite -3.75 -4.90 -1.15 -0.192 0.44201E+04 242 copper,native 1.74 -1.65 -3.38 -1.177 0.12994E+05 244 ferrous-oxide 2.13 1.28 -0.85 -0.213 0.32758E+04 245 galena -9.81 -9.88 -0.06 -0.021 0.24488E+03 246 silver,native 0.47 -3.34 -3.80 -1.323 0.14602E+05 248 litharge 5.31 0.71 -4.60 -1.150 0.17670E+05 256 wurtzite -10.11 -10.91 -0.80 -0.268 0.30875E+04 257 zincite 2.23 -0.33 -2.55 -0.638 0.98033E+04 258 an20ab80 -5.25 -5.29 -0.05 -0.004 0.17626E+03 259 an25ab75 -5.47 -5.52 -0.05 -0.004 0.19273E+03 260 an30ab70 -5.69 -5.75 -0.06 -0.005 0.23269E+03 261 tr.625ac.25prg.125 9.86 8.85 -1.01 -0.027 0.38724E+04 Calculations done for 566.0000 Deg. C; 1155.0000 bar Temperature changed by -1.000 degrees to 565.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 34 Loop limit = 500 Temperature = 565.00 C Pressure = 1139.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5512E+02 kg liquid = 0.9930E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9967 Stoichiometric ionic strength = .3278786E+01 Osmotic coef. = 0.0000 True ionic strength = .1583725E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.51721E-05 -5.2863 0.11056E-05 -5.9564 0.21376E+00 -0.6701 2 H2O 0.99667E+00 -0.0014 0.99667E+00 -0.0014 3 Cl- 0.13316E+00 -0.8756 0.24428E-01 -1.6121 0.18345E+00 -0.7365 4 SO4-- 0.22349E-03 -3.6507 0.58266E-06 -6.2346 0.26071E-02 -2.5838 5 HCO3- 0.10709E-04 -4.9702 0.21152E-05 -5.6746 0.19751E+00 -0.7044 6 HS- 0.11967E-03 -3.9220 0.22133E-04 -4.6550 0.18496E+00 -0.7329 7 H4SiO4 0.54002E-01 -1.2676 0.54002E-01 -1.2676 0.10000E+01 0.0000 8 Al+++ 0.15325E-16 -16.8146 0.18539E-22 -22.7319 0.12097E-05 -5.9173 9 Ca++ 0.13159E-05 -5.8808 0.27539E-08 -8.5601 0.20927E-02 -2.6793 10 Mg++ 0.11912E-05 -5.9240 0.20509E-08 -8.6881 0.17218E-02 -2.7640 11 Fe++ 0.13177E-07 -7.8802 0.23838E-10 -10.6227 0.18091E-02 -2.7425 12 K+ 0.37316E-01 -1.4281 0.75507E-02 -2.1220 0.20235E+00 -0.6939 13 Na+ 0.11935E+00 -0.9232 0.22144E-01 -1.6548 0.18554E+00 -0.7316 14 Mn++ 0.10020E-05 -5.9992 0.18793E-08 -8.7260 0.18756E-02 -2.7269 15 Zn++ 0.32795E-09 -9.4842 0.59328E-12 -12.2267 0.18091E-02 -2.7425 16 Cu+ 0.15281E-07 -7.8158 0.28278E-08 -8.5486 0.18505E+00 -0.7327 17 Pb++ 0.27730E-08 -8.5571 0.65003E-11 -11.1871 0.23441E-02 -2.6300 18 Ag+ 0.30082E-09 -9.5217 0.59921E-10 -10.2224 0.19919E+00 -0.7007 19 Ba++ 0.72479E-07 -7.1398 0.18255E-09 -9.7386 0.25186E-02 -2.5988 20 HPO4-- 0.12182E-08 -8.9143 0.31920E-11 -11.4959 0.26203E-02 -2.5817 21 HSiO3- 0.14681E-05 -5.8333 0.26932E-06 -6.5697 0.18345E+00 -0.7365 22 Ca(HSiO3)+ 0.52496E-08 -8.2799 0.10716E-08 -8.9700 0.20413E+00 -0.6901 23 Mg(HSiO3)+ 0.12097E-08 -8.9173 0.24693E-09 -9.6074 0.20413E+00 -0.6901 24 NaHSiO3,aq 0.18532E-05 -5.7321 0.18532E-05 -5.7321 0.10000E+01 0.0000 28 AgCl,aq 0.10771E-06 -6.9678 0.10771E-06 -6.9678 0.10000E+01 0.0000 29 AgCl2- 0.52396E-05 -5.2807 0.96121E-06 -6.0172 0.18345E+00 -0.7365 30 AgCl3-2 0.18463E-05 -5.7337 0.44557E-08 -8.3511 0.24133E-02 -2.6174 31 AgCl4-3 0.15607E-05 -5.8067 0.16499E-11 -11.7825 0.10571E-05 -5.9759 34 Ag(HS),aq 0.16122E-08 -8.7926 0.16122E-08 -8.7926 0.10000E+01 0.0000 35 Ag(HS)2- 0.63517E-08 -8.1971 0.11652E-08 -8.9336 0.18345E+00 -0.7365 38 HAlO2,aq 0.41165E-08 -8.3855 0.41165E-08 -8.3855 0.10000E+01 0.0000 39 AlO2- 0.12507E-04 -4.9028 0.20141E-05 -5.6959 0.16103E+00 -0.7931 41 Ba(HCO3)+ 0.25749E-06 -6.5892 0.54690E-07 -7.2621 0.21240E+00 -0.6729 42 BaCl+ 0.98520E-05 -5.0065 0.20111E-05 -5.6966 0.20413E+00 -0.6901 43 CH4,aq 0.15828E-08 -8.8006 0.18862E-08 -8.7244 0.11917E+01 0.0762 48 CO,aq 0.55507E-03 -3.2557 0.55507E-03 -3.2557 0.10000E+01 0.0000 49 CO2,aq 0.26744E+01 0.4272 0.31870E+01 0.5034 0.11917E+01 0.0762 50 CO3-2 0.39010E-10 -10.4088 0.94145E-13 -13.0262 0.24133E-02 -2.6174 51 CaCO3,aq 0.10749E-10 -10.9686 0.10749E-10 -10.9686 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.12596E-06 -6.8998 0.25712E-07 -7.5899 0.20413E+00 -0.6901 53 CaCl+ 0.84477E-04 -4.0733 0.17244E-04 -4.7634 0.20413E+00 -0.6901 54 CaCl2,aq 0.83330E-04 -4.0792 0.83330E-04 -4.0792 0.10000E+01 0.0000 55 CaOH+ 0.15973E-06 -6.7966 0.32605E-07 -7.4867 0.20413E+00 -0.6901 56 CaSO4,aq 0.16105E-06 -6.7930 0.16105E-06 -6.7930 0.10000E+01 0.0000 57 HCl,aq 0.27576E-02 -2.5595 0.27576E-02 -2.5595 0.10000E+01 0.0000 66 CuCl,aq 0.22167E-04 -4.6543 0.22167E-04 -4.6543 0.10000E+01 0.0000 67 CuCl2- 0.76101E-04 -4.1186 0.13961E-04 -4.8551 0.18345E+00 -0.7365 68 CuCl3-2 0.14515E-05 -5.8382 0.35029E-08 -8.4556 0.24133E-02 -2.6174 74 FeCl+ 0.26283E-06 -6.5803 0.53651E-07 -7.2704 0.20413E+00 -0.6901 75 FeCl2,aq 0.34476E-02 -2.4625 0.34476E-02 -2.4625 0.10000E+01 0.0000 77 FeO,aq 0.64327E-07 -7.1916 0.64327E-07 -7.1916 0.10000E+01 0.0000 78 FeOH+ 0.22182E-07 -7.6540 0.45279E-08 -8.3441 0.20413E+00 -0.6901 79 HFeO2- 0.75530E-08 -8.1219 0.13856E-08 -8.8584 0.18345E+00 -0.7365 82 FeO2- 0.47195E-08 -8.3261 0.86580E-09 -9.0626 0.18345E+00 -0.7365 83 HFeO2,aq 0.28717E-09 -9.5419 0.28717E-09 -9.5419 0.10000E+01 0.0000 84 H2,aq 0.46065E-02 -2.3366 0.54895E-02 -2.2605 0.11917E+01 0.0762 85 KCl,aq 0.70209E-01 -1.1536 0.70209E-01 -1.1536 0.10000E+01 0.0000 86 KHSO4,aq 0.13490E-01 -1.8700 0.13490E-01 -1.8700 0.10000E+01 0.0000 87 KOH,aq 0.13425E-05 -5.8721 0.13425E-05 -5.8721 0.10000E+01 0.0000 88 KSO4- 0.45968E-02 -2.3375 0.84327E-03 -3.0740 0.18345E+00 -0.7365 90 Mg(HCO3)+ 0.32774E-07 -7.4845 0.66902E-08 -8.1746 0.20413E+00 -0.6901 91 MgCl+ 0.13205E-04 -4.8793 0.26955E-05 -5.5694 0.20413E+00 -0.6901 92 MgOH+ 0.50862E-06 -6.2936 0.10382E-06 -6.9837 0.20413E+00 -0.6901 94 MnO,aq 0.84622E-07 -7.0725 0.84622E-07 -7.0725 0.10000E+01 0.0000 95 MnOH+ 0.19629E-06 -6.7071 0.40068E-07 -7.3972 0.20413E+00 -0.6901 97 HMnO2- 0.40468E-10 -10.3929 0.74238E-11 -11.1294 0.18345E+00 -0.7365 100 MnCl+ 0.11561E-02 -2.9370 0.23599E-03 -3.6271 0.20413E+00 -0.6901 101 MnSO4,aq 0.12226E-06 -6.9127 0.12226E-06 -6.9127 0.10000E+01 0.0000 102 NaCl,aq 0.43918E+00 -0.3574 0.43918E+00 -0.3574 0.10000E+01 0.0000 103 NaOH,aq 0.18064E-05 -5.7432 0.18064E-05 -5.7432 0.10000E+01 0.0000 105 OH- 0.76550E-05 -5.1161 0.12327E-05 -5.9091 0.16103E+00 -0.7931 110 HPO3-2 0.10081E-10 -10.9965 0.24330E-13 -13.6139 0.24133E-02 -2.6174 111 H3PO3,aq 0.11074E-09 -9.9557 0.11074E-09 -9.9557 0.10000E+01 0.0000 112 H2PO3- 0.20855E-08 -8.6808 0.38258E-09 -9.4173 0.18345E+00 -0.7365 113 H3PO4,aq 0.11853E-05 -5.9262 0.11853E-05 -5.9262 0.10000E+01 0.0000 114 H2PO4- 0.13539E-05 -5.8684 0.26102E-06 -6.5833 0.19279E+00 -0.7149 116 H4P2O7,aq 0.13012E-09 -9.8857 0.13012E-09 -9.8857 0.10000E+01 0.0000 117 H3P2O7- 0.82948E-09 -9.0812 0.15217E-09 -9.8177 0.18345E+00 -0.7365 118 H2P2O7-2 0.20926E-06 -6.6793 0.50502E-09 -9.2967 0.24133E-02 -2.6174 119 HP2O7-3 0.19775E-07 -7.7039 0.20905E-13 -13.6797 0.10571E-05 -5.9759 121 PbCl+ 0.13278E-05 -5.8769 0.27104E-06 -6.5670 0.20413E+00 -0.6901 122 PbCl2,aq 0.86424E-04 -4.0634 0.86424E-04 -4.0634 0.10000E+01 0.0000 123 PbCl3- 0.10047E-03 -3.9980 0.18431E-04 -4.7344 0.18345E+00 -0.7365 124 PbCl4-2 0.18004E-04 -4.7446 0.43451E-07 -7.3620 0.24133E-02 -2.6174 125 PbO,aq 0.63406E-08 -8.1979 0.63406E-08 -8.1979 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12288E-03 -3.9105 0.12288E-03 -3.9105 0.10000E+01 0.0000 128 Pb(HS)3- 0.13469E-04 -4.8707 0.24708E-05 -5.6072 0.18345E+00 -0.7365 129 H2S,aq 0.10569E+01 0.0241 0.12596E+01 0.1002 0.11917E+01 0.0762 130 S2-2 0.12534E-07 -7.9019 0.30249E-10 -10.5193 0.24133E-02 -2.6174 131 S3-2 0.11645E-08 -8.9339 0.28104E-11 -11.5512 0.24133E-02 -2.6174 132 S3- 0.10805E-01 -1.9664 0.19822E-02 -2.7028 0.18345E+00 -0.7365 133 S4-2 0.91692E-10 -10.0377 0.22128E-12 -12.6551 0.24133E-02 -2.6174 135 SO2,aq 0.29258E+00 -0.5338 0.29258E+00 -0.5338 0.10000E+01 0.0000 136 SO3-2 0.62550E-09 -9.2038 0.23950E-11 -11.6207 0.38290E-02 -2.4169 137 HSO3- 0.26202E-03 -3.5817 0.48068E-04 -4.3181 0.18345E+00 -0.7365 138 HSO4- 0.83944E-02 -2.0760 0.17603E-02 -2.7544 0.20971E+00 -0.6784 140 S2O3-2 0.49493E-06 -6.3055 0.11944E-08 -8.9228 0.24133E-02 -2.6174 141 HS2O3- 0.39061E-06 -6.4083 0.71658E-07 -7.1447 0.18345E+00 -0.7365 142 H2S2O3,aq 0.31469E-07 -7.5021 0.31469E-07 -7.5021 0.10000E+01 0.0000 150 S4O6-2 0.43333E-09 -9.3632 0.10458E-11 -11.9806 0.24133E-02 -2.6174 152 ZnCl+ 0.17640E-03 -3.7535 0.36008E-04 -4.4436 0.20413E+00 -0.6901 153 ZnCl2,aq 0.68172E-03 -3.1664 0.68172E-03 -3.1664 0.10000E+01 0.0000 154 ZnCl3- 0.52555E-04 -4.2794 0.96413E-05 -5.0159 0.18345E+00 -0.7365 155 ZnO,aq 0.30282E-07 -7.5188 0.30282E-07 -7.5188 0.10000E+01 0.0000 156 ZnOH+ 0.11770E-05 -5.9292 0.24025E-06 -6.6193 0.20413E+00 -0.6901 158 HZnO2- 0.23155E-09 -9.6354 0.42478E-10 -10.3718 0.18345E+00 -0.7365 Charge balance for all species = 0.2549E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5172102E-05 0.4295762E+01 0.3541069E+04 0.0000 2 H2O 0.1000000E+01 0.5251836E+02 0.7737704E+06 0.0000 3 Cl- 0.1331615E+00 0.6560806E+00 0.1902259E+05 4.3443 4 SO4-- 0.2234875E-03 0.2518029E+00 0.1978199E+05 5.6782 5 HCO3- 0.1070929E-04 0.2674949E+01 0.1334834E+06 0.2818 6 HS- 0.1196659E-03 0.1157518E+01 0.3130744E+05 1.3015 7 H4SiO4 0.5400165E-01 0.5400498E-01 0.4245084E+04 -1.2676 8 Al+++ 0.1532540E-16 0.1251139E-04 0.2760775E+00 -4.8627 9 Ca++ 0.1315931E-05 0.1695748E-03 0.5558107E+01 3.3528 10 Mg++ 0.1191152E-05 0.1493867E-04 0.2970244E+00 3.2248 11 Fe++ 0.1317673E-07 0.3447964E-02 0.1574788E+03 1.2901 12 K+ 0.3731568E-01 0.1256126E+00 0.4016905E+04 3.8344 13 Na+ 0.1193478E+00 0.5585324E+00 0.1050130E+05 4.3017 14 Mn++ 0.1001956E-05 0.1157477E-02 0.5200494E+02 3.1868 15 Zn++ 0.3279474E-09 0.9118803E-03 0.4875014E+02 -0.3139 16 Cu+ 0.1528134E-07 0.9973461E-04 0.5182659E+01 -2.5921 17 Pb++ 0.2772997E-08 0.3425851E-03 0.5804927E+02 0.7258 18 Ag+ 0.3008217E-09 0.8762546E-05 0.7730196E+00 -4.2660 19 Ba++ 0.7247903E-07 0.1018193E-04 0.1143633E+01 2.1742 20 HPO4-- 0.1218182E-08 0.3002629E-05 0.2356880E+00 0.4169 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265512E+01 -.3149724E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5214853E+02 -.1837522E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2500297E+00 0.1693064E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1149367E+01 0.1077753E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.5362469E-01 0.8996964E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1242328E-04 0.6821162E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1683807E-03 0.3595292E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1483348E-04 0.5843175E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.3423684E-02 0.5343070E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247280E+00 0.6821162E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149326E-02 0.1740383E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.9054590E-03 0.1393876E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.9903230E-04 0.3005774E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.1011023E-04 0.4526222E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.2981485E-05 0.5586015E-05 0.0000000E+00 Chg. balance for solid moles: -.8504E-18 Mass of aqueous solution: 0.121415E+04 g Temperature = 565.00 C Pressure = 1139.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3502E-03 -3.456 0.4768E-01 -1.322 0.7535 0.1609E-01 annite 0.8176E-06 -6.087 0.4185E-03 -3.378 0.6614E-02 0.1262E-03 phlogopite 0.1948E-05 -5.710 0.8128E-03 -3.090 0.1284E-01 0.2914E-03 biotite-Mn 0.5801E-07 -7.236 0.2954E-04 -4.530 0.4668E-03 0.8854E-05 apatite-OH 0.1862E-05 -5.730 0.9353E-03 -3.029 0.1478E-01 0.2972E-03 microcline 0.6793E-03 -3.168 0.1891 -0.723 2.988 0.7386E-01 pyrite 0.5040E-02 -2.298 0.6047 -0.218 9.557 0.1207 quartz 0.8792E-01 -1.056 5.282 0.723 83.48 1.995 barite 0.4526E-04 -4.344 0.1056E-01 -1.976 0.1670 0.2358E-02 chalcopyrite 0.3006E-03 -3.522 0.5516E-01 -1.258 0.8717 0.1287E-01 sphalerite 0.1394E-02 -2.856 0.1358 -0.867 2.146 0.3321E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2896E+00 0.2896E+00 1.0000 -0.538 phlogopite 0.6899E+00 0.6899E+00 1.0000 -0.161 biotite-Mn 0.2055E-01 0.2055E-01 1.0000 -1.687 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.327610 g Volume = 2.254645 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.79 -14.79 0.00 0.000 0.00000E+00 24 annite 0.65 0.65 0.00 0.000 -0.10219E-10 25 phlogopite 5.33 5.33 0.00 0.000 -0.13625E-10 26 biotite-Mn 9.79 9.79 0.00 0.000 -0.27251E-10 30 apatite-OH -53.46 -53.46 0.00 0.000 -0.27251E-10 115 microcline -4.83 -4.83 0.00 0.000 -0.68127E-11 140 pyrite -21.82 -21.82 0.00 0.000 0.00000E+00 144 quartz -1.26 -1.26 0.00 0.000 0.00000E+00 237 barite -15.97 -15.97 0.00 0.000 -0.68127E-11 240 chalcopyrite -23.47 -23.47 0.00 0.000 0.13625E-10 255 sphalerite -10.93 -10.93 0.00 0.000 -0.20438E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.27 -0.269 0.10299E+04 2.788 2 CO2,gas -9.96 -11.63 -1.67 -0.555 0.63897E+04 1.390 3 CH4,gas 6.86 -4.10 -10.96 -2.740 0.42034E+05 -7.903 4 H2,gas 5.95 1.88 -4.07 -2.324 0.15597E+05 -1.010 5 H2S,gas -8.30 -10.61 -2.31 -1.155 0.88618E+04 0.746 6 CO,gas -3.77 -9.75 -5.98 -1.840 0.22935E+05 -2.924 7 SO3,gas -7.53 -18.15 -10.61 -2.654 0.40709E+05 -7.558 8 O2,gas 16.79 -3.77 -20.56 -13.706 0.78847E+05 -17.502 9 HCl,gas -6.10 -7.57 -1.47 -0.734 0.56276E+04 -1.467 10 acmite 3.63 2.12 -1.51 -0.157 0.57880E+04 12 akimotoite 6.16 1.96 -4.21 -0.841 0.16129E+05 13 akimotoite-Fe 4.04 0.02 -4.02 -0.804 0.15411E+05 14 albite-high -4.23 -4.36 -0.13 -0.010 0.50528E+03 15 albite -4.22 -4.36 -0.14 -0.011 0.53566E+03 16 almandine -7.80 -9.66 -1.85 -0.093 0.71102E+04 17 pyrope -1.09 -3.85 -2.77 -0.138 0.10612E+05 18 analcite -2.12 -3.09 -0.97 -0.108 0.37347E+04 19 andalusite -10.44 -10.99 -0.56 -0.056 0.21382E+04 20 andradite 11.79 6.95 -4.84 -0.251 0.18544E+05 27 anorthite -8.12 -8.91 -0.78 -0.060 0.30027E+04 28 anthophyllite 14.67 12.44 -2.22 -0.060 0.85315E+04 29 anthophyllite-Fe 1.87 -1.10 -2.97 -0.080 0.11374E+05 31 apatite-OH-zs -51.29 -53.46 -2.17 -0.167 0.83409E+04 32 apatite-Cl-zs -57.79 -61.03 -3.24 -0.270 0.12417E+05 33 aragonite -4.64 -8.28 -3.64 -1.213 0.13961E+05 34 brucite 5.48 3.22 -2.26 -0.452 0.86654E+04 35 calcite -4.74 -8.28 -3.54 -1.179 0.13560E+05 36 carnegieite-low -0.05 -1.83 -1.78 -0.254 0.68240E+04 37 carnegieite-high 0.03 -1.83 -1.86 -0.266 0.71314E+04 38 carpholite-Mg -6.97 -9.04 -2.07 -0.138 0.79295E+04 39 carpholite-Fe -8.35 -10.97 -2.63 -0.175 0.10075E+05 40 celadonite -0.76 -2.87 -2.10 -0.124 0.80667E+04 41 celadonite-Fe -2.19 -4.80 -2.61 -0.154 0.10029E+05 42 chrysotile 9.55 7.14 -2.41 -0.201 0.92560E+04 44 clinochlore 4.04 2.59 -1.46 -0.045 0.55838E+04 45 daphnite -3.12 -7.09 -3.96 -0.124 0.15204E+05 48 chloritoid-Mg -6.39 -7.77 -1.38 -0.092 0.53079E+04 49 chloritoid-Fe -8.35 -9.71 -1.35 -0.090 0.51909E+04 50 chloritoid-Mn -6.21 -7.81 -1.60 -0.107 0.61551E+04 52 coesite -0.97 -1.26 -0.29 -0.097 0.11126E+04 53 cordierite-H -18.36 -19.34 -0.98 -0.035 0.37481E+04 54 cordierite-Fe -20.98 -23.21 -2.22 -0.077 0.85198E+04 55 cordierite-Mn -16.62 -19.41 -2.80 -0.096 0.10725E+05 56 corundum -9.00 -9.73 -0.73 -0.067 0.28122E+04 58 cristobalite -1.22 -1.26 -0.05 -0.016 0.18078E+03 59 cummingtonite 14.74 12.44 -2.29 -0.062 0.87879E+04 61 cymrite-K -2.52 -4.83 -2.31 -0.192 0.88582E+04 63 diaspore -4.00 -4.87 -0.87 -0.144 0.33186E+04 65 diopside 5.42 4.05 -1.38 -0.138 0.52834E+04 66 hedenbergite 3.98 2.11 -1.87 -0.187 0.71712E+04 68 eastonite -5.47 -6.85 -1.38 -0.053 0.52742E+04 69 enstatite 4.79 3.92 -0.87 -0.087 0.33500E+04 70 clinoenstatite-HiP 5.29 3.92 -1.37 -0.137 0.52560E+04 71 clinoenstatite 4.77 3.92 -0.86 -0.086 0.32864E+04 72 protoenstatite 4.92 3.92 -1.01 -0.101 0.38584E+04 73 epidote -4.14 -6.48 -2.34 -0.113 0.89652E+04 74 clinozoisite -8.90 -11.69 -2.78 -0.127 0.10676E+05 75 epidote-Fe 2.32 -1.26 -3.58 -0.186 0.13735E+05 76 fayalite 2.34 1.31 -1.02 -0.146 0.39290E+04 77 ferrosilite 1.17 0.05 -1.12 -0.112 0.43029E+04 78 forsterite 6.37 5.18 -1.19 -0.170 0.45730E+04 79 gedrite -8.70 -10.93 -2.23 -0.060 0.85459E+04 81 gibbsite -2.37 -4.87 -2.49 -0.356 0.95610E+04 82 glaucophane 1.50 -1.58 -3.08 -0.083 0.11804E+05 83 glaucophane-Fe -2.61 -7.38 -4.77 -0.129 0.18299E+05 84 goethite 1.20 0.35 -0.85 -0.184 0.32601E+04 86 greenalite 4.61 1.33 -3.28 -0.273 0.12582E+05 87 grunerite 2.42 -1.10 -3.52 -0.095 0.13513E+05 88 halite -1.23 -3.27 -2.04 -1.020 0.78240E+04 89 hematite 0.85 0.69 -0.15 -0.019 0.59113E+03 90 heulandite -12.07 -15.24 -3.17 -0.144 0.12150E+05 91 hercynite -7.22 -8.44 -1.22 -0.081 0.46790E+04 94 jadeite -1.44 -3.09 -1.66 -0.166 0.63501E+04 96 kalsilite -0.67 -2.30 -1.62 -0.232 0.62267E+04 97 kaolinite -9.47 -12.26 -2.79 -0.253 0.10694E+05 98 kyanite -10.27 -10.99 -0.72 -0.072 0.27631E+04 100 laumontite -7.78 -11.44 -3.67 -0.244 0.14058E+05 101 lawsonite -5.35 -8.91 -3.56 -0.237 0.13642E+05 102 leucite -2.60 -3.56 -0.96 -0.096 0.36891E+04 104 lizardite 9.72 7.14 -2.58 -0.215 0.99139E+04 105 magnesite -5.48 -8.41 -2.93 -0.975 0.11218E+05 106 magnetite 2.10 1.98 -0.12 -0.010 0.45946E+03 107 minnesotaite 0.83 -1.19 -2.02 -0.119 0.77489E+04 108 minnesotaite-Mg 6.86 4.61 -2.25 -0.132 0.86324E+04 109 magnesioferrite 5.20 3.92 -1.28 -0.104 0.49093E+04 111 manganosite 5.43 3.19 -2.25 -0.561 0.86137E+04 112 margarite -16.66 -18.64 -1.98 -0.079 0.76048E+04 116 monticellite 8.85 5.31 -3.54 -0.506 0.13578E+05 118 mullite-Si -9.69 -10.99 -1.31 -0.131 0.50186E+04 119 muscovite -13.69 -14.56 -0.87 -0.051 0.33260E+04 120 paragonite -13.01 -14.09 -1.08 -0.064 0.41534E+04 121 nepheline -0.35 -1.83 -1.48 -0.211 0.56777E+04 122 osumilite(2) -12.97 -15.00 -2.03 -0.042 0.77994E+04 123 osumilite-Fe -27.95 -30.56 -2.61 -0.054 0.10029E+05 124 pargasite 5.78 1.71 -4.07 -0.107 0.15607E+05 125 periclase 5.68 3.22 -2.45 -0.613 0.94117E+04 126 periclase-Fe 3.08 1.29 -1.79 -0.447 0.68635E+04 127 perovskite-Al -7.26 -9.73 -2.47 -0.225 0.94738E+04 132 phlogopite-Na 6.20 5.31 -0.89 -0.049 0.34086E+04 134 prehnite -3.42 -6.82 -3.40 -0.200 0.13032E+05 135 prehnite-Fe 1.73 -1.61 -3.35 -0.201 0.12833E+05 138 px-Mg-tschermaks -5.78 -7.77 -1.99 -0.142 0.76329E+04 139 px-Ca-tschermaks -4.96 -7.64 -2.68 -0.191 0.10275E+05 141 pyrrhotite -8.66 -9.32 -0.66 -0.220 0.25304E+04 142 pyrrhotiteFe0.875 -9.44 -9.72 -0.28 -0.102 0.10616E+04 143 pyrophyllite -13.36 -14.79 -1.43 -0.089 0.54818E+04 146 riebeckite 5.82 3.04 -2.78 -0.077 0.10662E+05 147 ringwoodite-Fe 3.34 1.31 -2.02 -0.289 0.77575E+04 148 ringwoodite-Mg 9.54 5.18 -4.35 -0.622 0.16698E+05 149 rhodochrosite -5.46 -8.44 -2.98 -0.994 0.11437E+05 150 rhodonite 2.54 1.92 -0.62 -0.123 0.23666E+04 151 sanidine -4.29 -4.83 -0.54 -0.041 0.20669E+04 153 siderite -7.34 -10.34 -3.00 -1.001 0.11516E+05 154 sillimanite -10.40 -10.99 -0.59 -0.059 0.22772E+04 156 spinel -5.03 -6.51 -1.48 -0.098 0.56633E+04 162 stilpnomelane-Fe -6.58 -11.50 -4.92 -0.147 0.18869E+05 163 stilpnomelane-Mg 0.34 -1.82 -2.17 -0.065 0.83039E+04 164 stishovite 1.70 -1.26 -2.96 -0.987 0.11357E+05 165 sudoite-Fe -16.30 -20.68 -4.38 -0.141 0.16808E+05 166 sudoite -14.04 -16.81 -2.77 -0.089 0.10624E+05 167 sulfur -10.99 -12.49 -1.50 -0.461 0.57494E+04 168 sylvite -1.13 -3.73 -2.60 -1.301 0.99791E+04 169 talc 5.13 4.61 -0.52 -0.031 0.19918E+04 170 talc-Fe 2.23 -1.19 -3.43 -0.202 0.13143E+05 171 talc-tschermaks -5.37 -7.08 -1.71 -0.101 0.65706E+04 173 tephroite 6.61 5.11 -1.50 -0.215 0.57641E+04 176 topaz-H -8.34 -11.00 -2.65 -0.241 0.10179E+05 177 tremolite 15.33 12.70 -2.63 -0.071 0.10094E+05 179 troilite-low -8.57 -9.32 -0.75 -0.251 0.28838E+04 180 tschermakite -7.26 -10.68 -3.41 -0.092 0.13089E+05 183 wadsleyite-Fe 3.19 1.31 -1.88 -0.268 0.71929E+04 184 wadsleyite-Mg 8.59 5.18 -3.41 -0.487 0.13080E+05 185 wairakite -9.65 -11.44 -1.79 -0.105 0.68772E+04 186 walstromite 4.62 2.09 -2.53 -0.506 0.97068E+04 187 wollastonite 4.20 2.09 -2.11 -0.422 0.80892E+04 188 pseudo-wollastonite 4.31 2.09 -2.23 -0.445 0.85379E+04 189 zoisite -8.96 -11.69 -2.73 -0.124 0.10475E+05 192 beidellite-Ca -13.65 -15.43 -1.78 -0.110 0.68224E+04 193 beidellite-H -13.67 -15.98 -2.30 -0.147 0.88376E+04 194 beidellite-K -12.63 -14.71 -2.09 -0.128 0.80011E+04 195 beidellite-Mg -13.90 -15.45 -1.54 -0.095 0.59121E+04 196 beidellite-Na -12.57 -14.56 -1.99 -0.122 0.76343E+04 197 bornite -54.68 -55.06 -0.38 -0.028 0.14558E+04 199 chalcocite -14.29 -15.80 -1.50 -0.376 0.57627E+04 200 covellite -12.75 -14.14 -1.39 -0.530 0.53350E+04 202 montmorillonite-Ca -10.24 -11.57 -1.33 -0.082 0.51084E+04 203 montmorillonite-K -9.50 -10.86 -1.36 -0.083 0.52055E+04 204 montmorillonite-Mg -10.45 -11.59 -1.14 -0.070 0.43567E+04 205 montmorillonite-Na -9.16 -10.70 -1.54 -0.094 0.59157E+04 206 nontronite-Ca -3.54 -5.00 -1.46 -0.095 0.55904E+04 207 nontronite-H -3.58 -5.56 -1.98 -0.132 0.75768E+04 208 nontronite-K -2.53 -4.29 -1.76 -0.113 0.67610E+04 209 nontronite-Mg -3.77 -5.02 -1.26 -0.082 0.48191E+04 210 nontronite-Na -2.47 -4.14 -1.67 -0.107 0.64067E+04 215 gypsum -12.55 -14.80 -2.25 -0.561 0.86111E+04 232 alabandite -6.39 -7.42 -1.04 -0.346 0.39760E+04 234 anglesite -15.06 -17.42 -2.36 -1.180 0.90496E+04 238 boehmite -3.71 -4.87 -1.16 -0.193 0.44403E+04 242 copper,native 1.73 -1.65 -3.38 -1.177 0.12981E+05 244 ferrous-oxide 2.15 1.29 -0.86 -0.215 0.33053E+04 245 galena -9.83 -9.89 -0.05 -0.018 0.20399E+03 246 silver,native 0.46 -3.32 -3.79 -1.317 0.14522E+05 248 litharge 5.32 0.72 -4.60 -1.150 0.17636E+05 256 wurtzite -10.12 -10.93 -0.81 -0.268 0.30874E+04 257 zincite 2.24 -0.32 -2.56 -0.640 0.98123E+04 258 an20ab80 -5.22 -5.27 -0.05 -0.004 0.19599E+03 259 an25ab75 -5.44 -5.50 -0.06 -0.004 0.21604E+03 260 an30ab70 -5.66 -5.72 -0.07 -0.005 0.25906E+03 261 tr.625ac.25prg.125 9.93 8.91 -1.02 -0.028 0.39258E+04 Calculations done for 565.0000 Deg. C; 1139.0000 bar Temperature changed by -1.000 degrees to 564.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 34 Loop limit = 500 Temperature = 564.00 C Pressure = 1123.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5512E+02 kg liquid = 0.9930E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9967 Stoichiometric ionic strength = .3278024E+01 Osmotic coef. = 0.0000 True ionic strength = .1557999E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.50362E-05 -5.2979 0.10699E-05 -5.9707 0.21244E+00 -0.6728 2 H2O 0.99670E+00 -0.0014 0.99670E+00 -0.0014 3 Cl- 0.13095E+00 -0.8829 0.23849E-01 -1.6225 0.18213E+00 -0.7396 4 SO4-- 0.22536E-03 -3.6471 0.57258E-06 -6.2422 0.25407E-02 -2.5950 5 HCO3- 0.10370E-04 -4.9842 0.20330E-05 -5.6919 0.19604E+00 -0.7077 6 HS- 0.11851E-03 -3.9262 0.21762E-04 -4.6623 0.18362E+00 -0.7361 7 H4SiO4 0.52899E-01 -1.2766 0.52899E-01 -1.2766 0.10000E+01 0.0000 8 Al+++ 0.16055E-16 -16.7944 0.18336E-22 -22.7367 0.11420E-05 -5.9423 9 Ca++ 0.12836E-05 -5.8916 0.26183E-08 -8.5820 0.20398E-02 -2.6904 10 Mg++ 0.12066E-05 -5.9184 0.20260E-08 -8.6934 0.16791E-02 -2.7749 11 Fe++ 0.12947E-07 -7.8878 0.22838E-10 -10.6413 0.17640E-02 -2.7535 12 K+ 0.36776E-01 -1.4344 0.73849E-02 -2.1317 0.20081E+00 -0.6972 13 Na+ 0.11733E+00 -0.9306 0.21609E-01 -1.6654 0.18418E+00 -0.7348 14 Mn++ 0.10301E-05 -5.9871 0.18836E-08 -8.7250 0.18287E-02 -2.7379 15 Zn++ 0.32324E-09 -9.4905 0.57019E-12 -12.2440 0.17640E-02 -2.7535 16 Cu+ 0.14721E-07 -7.8321 0.27041E-08 -8.5680 0.18369E+00 -0.7359 17 Pb++ 0.27368E-08 -8.5628 0.62516E-11 -11.2040 0.22842E-02 -2.6413 18 Ag+ 0.30017E-09 -9.5226 0.59340E-10 -10.2267 0.19769E+00 -0.7040 19 Ba++ 0.69625E-07 -7.1572 0.17085E-09 -9.7674 0.24539E-02 -2.6101 20 HPO4-- 0.12397E-08 -8.9067 0.31655E-11 -11.4996 0.25535E-02 -2.5929 21 HSiO3- 0.14436E-05 -5.8406 0.26291E-06 -6.5802 0.18213E+00 -0.7396 22 Ca(HSiO3)+ 0.50559E-08 -8.2962 0.10242E-08 -8.9896 0.20257E+00 -0.6934 23 Mg(HSiO3)+ 0.12191E-08 -8.9140 0.24696E-09 -9.6074 0.20257E+00 -0.6934 24 NaHSiO3,aq 0.18666E-05 -5.7289 0.18666E-05 -5.7289 0.10000E+01 0.0000 28 AgCl,aq 0.11011E-06 -6.9582 0.11011E-06 -6.9582 0.10000E+01 0.0000 29 AgCl2- 0.52669E-05 -5.2784 0.95923E-06 -6.0181 0.18213E+00 -0.7396 30 AgCl3-2 0.18246E-05 -5.7388 0.42919E-08 -8.3673 0.23522E-02 -2.6285 31 AgCl4-3 0.15522E-05 -5.8091 0.15510E-11 -11.8094 0.99923E-06 -6.0003 34 Ag(HS),aq 0.16830E-08 -8.7739 0.16830E-08 -8.7739 0.10000E+01 0.0000 35 Ag(HS)2- 0.64853E-08 -8.1881 0.11811E-08 -8.9277 0.18213E+00 -0.7396 38 HAlO2,aq 0.41046E-08 -8.3867 0.41046E-08 -8.3867 0.10000E+01 0.0000 39 AlO2- 0.12217E-04 -4.9131 0.19542E-05 -5.7090 0.15996E+00 -0.7960 41 Ba(HCO3)+ 0.24390E-06 -6.6128 0.51404E-07 -7.2890 0.21076E+00 -0.6762 42 BaCl+ 0.93667E-05 -5.0284 0.18975E-05 -5.7218 0.20257E+00 -0.6934 43 CH4,aq 0.15643E-08 -8.8057 0.18625E-08 -8.7299 0.11907E+01 0.0758 48 CO,aq 0.54556E-03 -3.2632 0.54556E-03 -3.2632 0.10000E+01 0.0000 49 CO2,aq 0.26743E+01 0.4272 0.31843E+01 0.5030 0.11907E+01 0.0758 50 CO3-2 0.38529E-10 -10.4142 0.90629E-13 -13.0427 0.23522E-02 -2.6285 51 CaCO3,aq 0.10541E-10 -10.9771 0.10541E-10 -10.9771 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.11864E-06 -6.9258 0.24034E-07 -7.6192 0.20257E+00 -0.6934 53 CaCl+ 0.81149E-04 -4.0907 0.16439E-04 -4.7841 0.20257E+00 -0.6934 54 CaCl2,aq 0.81424E-04 -4.0892 0.81424E-04 -4.0892 0.10000E+01 0.0000 55 CaOH+ 0.15395E-06 -6.8126 0.31186E-07 -7.5060 0.20257E+00 -0.6934 56 CaSO4,aq 0.16270E-06 -6.7886 0.16270E-06 -6.7886 0.10000E+01 0.0000 57 HCl,aq 0.28493E-02 -2.5453 0.28493E-02 -2.5453 0.10000E+01 0.0000 66 CuCl,aq 0.21898E-04 -4.6596 0.21898E-04 -4.6596 0.10000E+01 0.0000 67 CuCl2- 0.74515E-04 -4.1278 0.13571E-04 -4.8674 0.18213E+00 -0.7396 68 CuCl3-2 0.13995E-05 -5.8540 0.32920E-08 -8.4825 0.23522E-02 -2.6285 74 FeCl+ 0.25445E-06 -6.5944 0.51546E-07 -7.2878 0.20257E+00 -0.6934 75 FeCl2,aq 0.33051E-02 -2.4808 0.33051E-02 -2.4808 0.10000E+01 0.0000 77 FeO,aq 0.62981E-07 -7.2008 0.62981E-07 -7.2008 0.10000E+01 0.0000 78 FeOH+ 0.21524E-07 -7.6671 0.43601E-08 -8.3605 0.20257E+00 -0.6934 79 HFeO2- 0.73232E-08 -8.1353 0.13337E-08 -8.8749 0.18213E+00 -0.7396 82 FeO2- 0.45702E-08 -8.3401 0.83235E-09 -9.0797 0.18213E+00 -0.7396 83 HFeO2,aq 0.28639E-09 -9.5430 0.28639E-09 -9.5430 0.10000E+01 0.0000 84 H2,aq 0.45873E-02 -2.3384 0.54621E-02 -2.2626 0.11907E+01 0.0758 85 KCl,aq 0.70665E-01 -1.1508 0.70665E-01 -1.1508 0.10000E+01 0.0000 86 KHSO4,aq 0.13536E-01 -1.8685 0.13536E-01 -1.8685 0.10000E+01 0.0000 87 KOH,aq 0.13551E-05 -5.8680 0.13551E-05 -5.8680 0.10000E+01 0.0000 88 KSO4- 0.46304E-02 -2.3344 0.84332E-03 -3.0740 0.18213E+00 -0.7396 90 Mg(HCO3)+ 0.31861E-07 -7.4967 0.64542E-08 -8.1902 0.20257E+00 -0.6934 91 MgCl+ 0.13238E-04 -4.8782 0.26816E-05 -5.5716 0.20257E+00 -0.6934 92 MgOH+ 0.51024E-06 -6.2922 0.10336E-06 -6.9856 0.20257E+00 -0.6934 94 MnO,aq 0.87067E-07 -7.0601 0.87067E-07 -7.0601 0.10000E+01 0.0000 95 MnOH+ 0.19842E-06 -6.7024 0.40195E-07 -7.3958 0.20257E+00 -0.6934 97 HMnO2- 0.40998E-10 -10.3872 0.74668E-11 -11.1269 0.18213E+00 -0.7396 100 MnCl+ 0.11560E-02 -2.9370 0.23417E-03 -3.6305 0.20257E+00 -0.6934 101 MnSO4,aq 0.12946E-06 -6.8879 0.12946E-06 -6.8879 0.10000E+01 0.0000 102 NaCl,aq 0.44118E+00 -0.3554 0.44118E+00 -0.3554 0.10000E+01 0.0000 103 NaOH,aq 0.18181E-05 -5.7404 0.18181E-05 -5.7404 0.10000E+01 0.0000 105 OH- 0.75725E-05 -5.1208 0.12113E-05 -5.9167 0.15996E+00 -0.7960 111 H3PO3,aq 0.11156E-09 -9.9525 0.11156E-09 -9.9525 0.10000E+01 0.0000 112 H2PO3- 0.20287E-08 -8.6928 0.36948E-09 -9.4324 0.18213E+00 -0.7396 113 H3PO4,aq 0.12176E-05 -5.9145 0.12176E-05 -5.9145 0.10000E+01 0.0000 114 H2PO4- 0.13529E-05 -5.8687 0.25890E-06 -6.5869 0.19137E+00 -0.7181 116 H4P2O7,aq 0.13760E-09 -9.8614 0.13760E-09 -9.8614 0.10000E+01 0.0000 117 H3P2O7- 0.83525E-09 -9.0782 0.15212E-09 -9.8178 0.18213E+00 -0.7396 118 H2P2O7-2 0.20845E-06 -6.6810 0.49031E-09 -9.3095 0.23522E-02 -2.6285 119 HP2O7-3 0.20249E-07 -7.6936 0.20234E-13 -13.6939 0.99923E-06 -6.0003 121 PbCl+ 0.12992E-05 -5.8863 0.26319E-06 -6.5797 0.20257E+00 -0.6934 122 PbCl2,aq 0.86441E-04 -4.0633 0.86441E-04 -4.0633 0.10000E+01 0.0000 123 PbCl3- 0.99771E-04 -4.0010 0.18171E-04 -4.7406 0.18213E+00 -0.7396 124 PbCl4-2 0.17568E-04 -4.7553 0.41323E-07 -7.3838 0.23522E-02 -2.6285 125 PbO,aq 0.64394E-08 -8.1912 0.64394E-08 -8.1912 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12391E-03 -3.9069 0.12391E-03 -3.9069 0.10000E+01 0.0000 128 Pb(HS)3- 0.13580E-04 -4.8671 0.24733E-05 -5.6067 0.18213E+00 -0.7396 129 H2S,aq 0.10573E+01 0.0242 0.12589E+01 0.1000 0.11907E+01 0.0758 130 S2-2 0.12364E-07 -7.9078 0.29084E-10 -10.5363 0.23522E-02 -2.6285 131 S3-2 0.11467E-08 -8.9406 0.26973E-11 -11.5691 0.23522E-02 -2.6285 132 S3- 0.10518E-01 -1.9781 0.19156E-02 -2.7177 0.18213E+00 -0.7396 133 S4-2 0.90172E-10 -10.0449 0.21211E-12 -12.6734 0.23522E-02 -2.6285 135 SO2,aq 0.29277E+00 -0.5335 0.29277E+00 -0.5335 0.10000E+01 0.0000 136 SO3-2 0.62566E-09 -9.2037 0.23335E-11 -11.6320 0.37297E-02 -2.4283 137 HSO3- 0.25676E-03 -3.5905 0.46762E-04 -4.3301 0.18213E+00 -0.7396 138 HSO4- 0.82998E-02 -2.0809 0.17273E-02 -2.7626 0.20811E+00 -0.6817 140 S2O3-2 0.49321E-06 -6.3070 0.11602E-08 -8.9355 0.23522E-02 -2.6285 141 HS2O3- 0.38328E-06 -6.4165 0.69806E-07 -7.1561 0.18213E+00 -0.7396 142 H2S2O3,aq 0.31997E-07 -7.4949 0.31997E-07 -7.4949 0.10000E+01 0.0000 150 S4O6-2 0.42802E-09 -9.3685 0.10068E-11 -11.9970 0.23522E-02 -2.6285 152 ZnCl+ 0.16785E-03 -3.7751 0.34002E-04 -4.4685 0.20257E+00 -0.6934 153 ZnCl2,aq 0.66215E-03 -3.1790 0.66215E-03 -3.1790 0.10000E+01 0.0000 154 ZnCl3- 0.49759E-04 -4.3031 0.90624E-05 -5.0428 0.18213E+00 -0.7396 155 ZnO,aq 0.29806E-07 -7.5257 0.29806E-07 -7.5257 0.10000E+01 0.0000 156 ZnOH+ 0.11305E-05 -5.9467 0.22902E-06 -6.6401 0.20257E+00 -0.6934 158 HZnO2- 0.22586E-09 -9.6462 0.41136E-10 -10.3858 0.18213E+00 -0.7396 Charge balance for all species = 0.2549E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5036192E-05 0.4295618E+01 0.3541320E+04 0.0000 2 H2O 0.1000000E+01 0.5251896E+02 0.7738602E+06 0.0000 3 Cl- 0.1309454E+00 0.6560589E+00 0.1902395E+05 4.3481 4 SO4-- 0.2253637E-03 0.2517533E+00 0.1978017E+05 5.6992 5 HCO3- 0.1037038E-04 0.2674861E+01 0.1334930E+06 0.2788 6 HS- 0.1185138E-03 0.1157199E+01 0.3130209E+05 1.3083 7 H4SiO4 0.5289853E-01 0.5290185E-01 0.4158807E+04 -1.2766 8 Al+++ 0.1605501E-16 0.1222068E-04 0.2696909E+00 -4.8247 9 Ca++ 0.1283628E-05 0.1642974E-03 0.5385693E+01 3.3593 10 Mg++ 0.1206574E-05 0.1498747E-04 0.2980258E+00 3.2479 11 Fe++ 0.1294697E-07 0.3305499E-02 0.1509878E+03 1.3000 12 K+ 0.3677566E-01 0.1256081E+00 0.4017182E+04 3.8390 13 Na+ 0.1173265E+00 0.5585139E+00 0.1050205E+05 4.3053 14 Mn++ 0.1030068E-05 0.1157436E-02 0.5200855E+02 3.2163 15 Zn++ 0.3232442E-09 0.8809224E-03 0.4710001E+02 -0.3027 16 Cu+ 0.1472095E-07 0.9782717E-04 0.5084071E+01 -2.5973 17 Pb++ 0.2736832E-08 0.3425737E-03 0.5805341E+02 0.7373 18 Ag+ 0.3001702E-09 0.8762255E-05 0.7730748E+00 -4.2560 19 Ba++ 0.6962469E-07 0.9680266E-05 0.1087400E+01 2.1739 20 HPO4-- 0.1239655E-08 0.3033212E-05 0.2381135E+00 0.4417 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265510E+01 -.3148070E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5215086E+02 -.1860795E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2499888E+00 0.1733968E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1149088E+01 0.1105598E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.5253107E-01 0.9106325E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1213502E-04 0.6824045E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1631458E-03 0.3647641E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1488242E-04 0.5794227E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.3282331E-02 0.5484423E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247277E+00 0.6824045E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149324E-02 0.1762140E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.8747481E-03 0.1424587E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.9714151E-04 0.3024682E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.9612419E-05 0.4576003E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3011953E-05 0.5555547E-05 0.0000000E+00 Chg. balance for solid moles: -.9046E-18 Mass of aqueous solution: 0.121406E+04 g Temperature = 564.00 C Pressure = 1123.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3555E-03 -3.449 0.4840E-01 -1.315 0.7545 0.1633E-01 annite 0.7919E-06 -6.101 0.4054E-03 -3.392 0.6320E-02 0.1222E-03 phlogopite 0.1931E-05 -5.714 0.8060E-03 -3.094 0.1257E-01 0.2890E-03 biotite-Mn 0.5874E-07 -7.231 0.2991E-04 -4.524 0.4663E-03 0.8965E-05 apatite-OH 0.1852E-05 -5.732 0.9302E-03 -3.031 0.1450E-01 0.2956E-03 microcline 0.6796E-03 -3.168 0.1892 -0.723 2.949 0.7389E-01 pyrite 0.5180E-02 -2.286 0.6214 -0.207 9.689 0.1240 quartz 0.8902E-01 -1.051 5.348 0.728 83.38 2.020 barite 0.4576E-04 -4.340 0.1068E-01 -1.971 0.1665 0.2384E-02 chalcopyrite 0.3025E-03 -3.519 0.5550E-01 -1.256 0.8653 0.1296E-01 sphalerite 0.1425E-02 -2.846 0.1388 -0.858 2.164 0.3394E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2847E+00 0.2847E+00 1.0000 -0.546 phlogopite 0.6942E+00 0.6942E+00 1.0000 -0.158 biotite-Mn 0.2111E-01 0.2111E-01 1.0000 -1.675 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.414246 g Volume = 2.283888 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.82 -14.82 0.00 0.000 0.00000E+00 24 annite 0.72 0.72 0.00 0.000 0.17012E-10 25 phlogopite 5.40 5.40 0.00 0.000 0.34023E-11 26 biotite-Mn 9.86 9.86 0.00 0.000 -0.13609E-10 30 apatite-OH -53.53 -53.53 0.00 0.000 0.27218E-10 115 microcline -4.81 -4.81 0.00 0.000 0.68046E-11 140 pyrite -21.85 -21.85 0.00 0.000 0.00000E+00 144 quartz -1.27 -1.27 0.00 0.000 0.00000E+00 237 barite -16.01 -16.01 0.00 0.000 0.00000E+00 240 chalcopyrite -23.51 -23.51 0.00 0.000 0.00000E+00 255 sphalerite -10.94 -10.94 0.00 0.000 -0.68046E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.27 -0.268 0.10248E+04 2.783 2 CO2,gas -9.99 -11.66 -1.67 -0.557 0.64040E+04 1.379 3 CH4,gas 6.86 -4.11 -10.97 -2.743 0.42034E+05 -7.923 4 H2,gas 5.95 1.89 -4.07 -2.325 0.15584E+05 -1.018 5 H2S,gas -8.32 -10.63 -2.31 -1.155 0.88520E+04 0.740 6 CO,gas -3.78 -9.77 -5.99 -1.843 0.22951E+05 -2.941 7 SO3,gas -7.56 -18.18 -10.63 -2.657 0.40705E+05 -7.576 8 O2,gas 16.81 -3.78 -20.58 -13.723 0.78850E+05 -17.533 9 HCl,gas -6.11 -7.59 -1.48 -0.740 0.56691E+04 -1.480 10 acmite 3.62 2.11 -1.51 -0.157 0.57944E+04 12 akimotoite 6.18 1.97 -4.21 -0.842 0.16120E+05 13 akimotoite-Fe 4.06 0.02 -4.03 -0.806 0.15439E+05 14 albite-high -4.21 -4.34 -0.13 -0.010 0.51527E+03 15 albite -4.20 -4.34 -0.14 -0.011 0.54190E+03 16 almandine -7.69 -9.58 -1.89 -0.095 0.72477E+04 17 pyrope -0.96 -3.74 -2.78 -0.139 0.10641E+05 18 analcite -2.09 -3.07 -0.98 -0.109 0.37426E+04 19 andalusite -10.36 -10.93 -0.57 -0.057 0.21855E+04 20 andradite 11.83 6.96 -4.87 -0.253 0.18650E+05 27 anorthite -8.04 -8.84 -0.80 -0.062 0.30728E+04 28 anthophyllite 14.74 12.53 -2.21 -0.060 0.84625E+04 29 anthophyllite-Fe 1.92 -1.10 -3.02 -0.082 0.11558E+05 31 apatite-OH-zs -51.35 -53.53 -2.18 -0.168 0.83435E+04 32 apatite-Cl-zs -57.88 -61.12 -3.24 -0.270 0.12424E+05 33 aragonite -4.65 -8.30 -3.65 -1.217 0.13989E+05 34 brucite 5.50 3.25 -2.26 -0.452 0.86507E+04 35 calcite -4.76 -8.30 -3.55 -1.182 0.13588E+05 36 carnegieite-low -0.01 -1.80 -1.78 -0.255 0.68294E+04 37 carnegieite-high 0.07 -1.80 -1.86 -0.266 0.71389E+04 38 carpholite-Mg -6.88 -8.96 -2.08 -0.138 0.79554E+04 39 carpholite-Fe -8.26 -10.91 -2.65 -0.176 0.10139E+05 40 celadonite -0.74 -2.84 -2.10 -0.124 0.80532E+04 41 celadonite-Fe -2.16 -4.79 -2.62 -0.154 0.10055E+05 42 chrysotile 9.59 7.19 -2.41 -0.200 0.92130E+04 44 clinochlore 4.20 2.75 -1.45 -0.045 0.55512E+04 45 daphnite -2.98 -6.99 -4.01 -0.125 0.15359E+05 47 chlorite-Al-free 19.37 14.38 -4.99 -0.208 0.19103E+05 48 chloritoid-Mg -6.29 -7.68 -1.39 -0.093 0.53380E+04 49 chloritoid-Fe -8.26 -9.63 -1.37 -0.091 0.52555E+04 50 chloritoid-Mn -6.11 -7.71 -1.60 -0.107 0.61404E+04 52 coesite -0.98 -1.27 -0.29 -0.097 0.11135E+04 53 cordierite-H -18.19 -19.18 -1.00 -0.036 0.38276E+04 54 cordierite-Fe -20.82 -23.08 -2.26 -0.078 0.86647E+04 55 cordierite-Mn -16.45 -19.25 -2.80 -0.096 0.10710E+05 56 corundum -8.91 -9.65 -0.75 -0.068 0.28601E+04 58 cristobalite -1.23 -1.27 -0.05 -0.016 0.18098E+03 59 cummingtonite 14.81 12.53 -2.28 -0.062 0.87197E+04 61 cymrite-K -2.50 -4.81 -2.31 -0.193 0.88637E+04 63 diaspore -3.96 -4.83 -0.87 -0.145 0.33374E+04 65 diopside 5.44 4.06 -1.38 -0.138 0.52959E+04 66 hedenbergite 3.99 2.11 -1.89 -0.189 0.72214E+04 68 eastonite -5.32 -6.70 -1.38 -0.053 0.52974E+04 69 enstatite 4.82 3.95 -0.87 -0.087 0.33332E+04 70 clinoenstatite-HiP 5.31 3.95 -1.37 -0.137 0.52395E+04 71 clinoenstatite 4.80 3.95 -0.85 -0.085 0.32690E+04 72 protoenstatite 4.95 3.95 -1.00 -0.100 0.38416E+04 73 epidote -4.04 -6.41 -2.37 -0.115 0.90754E+04 74 clinozoisite -8.77 -11.59 -2.82 -0.128 0.10788E+05 75 epidote-Fe 2.39 -1.22 -3.61 -0.188 0.13842E+05 76 fayalite 2.36 1.32 -1.04 -0.149 0.39842E+04 77 ferrosilite 1.19 0.05 -1.14 -0.114 0.43593E+04 78 forsterite 6.41 5.22 -1.19 -0.170 0.45542E+04 79 gedrite -8.48 -10.72 -2.24 -0.061 0.85911E+04 81 gibbsite -2.33 -4.83 -2.50 -0.357 0.95761E+04 82 glaucophane 1.58 -1.50 -3.07 -0.083 0.11775E+05 83 glaucophane-Fe -2.54 -7.34 -4.80 -0.130 0.18381E+05 84 goethite 1.21 0.35 -0.86 -0.185 0.32798E+04 86 greenalite 4.65 1.35 -3.30 -0.275 0.12648E+05 87 grunerite 2.47 -1.10 -3.58 -0.097 0.13699E+05 88 halite -1.25 -3.29 -2.04 -1.020 0.78108E+04 89 hematite 0.88 0.71 -0.17 -0.020 0.63473E+03 90 heulandite -12.03 -15.22 -3.19 -0.145 0.12222E+05 91 hercynite -7.11 -8.36 -1.24 -0.083 0.47548E+04 94 jadeite -1.41 -3.07 -1.66 -0.166 0.63552E+04 96 kalsilite -0.64 -2.26 -1.63 -0.232 0.62288E+04 97 kaolinite -9.41 -12.20 -2.80 -0.254 0.10721E+05 98 kyanite -10.19 -10.93 -0.73 -0.073 0.28113E+04 100 laumontite -7.71 -11.40 -3.69 -0.246 0.14117E+05 101 lawsonite -5.27 -8.85 -3.58 -0.238 0.13700E+05 102 leucite -2.57 -3.54 -0.96 -0.096 0.36930E+04 104 lizardite 9.76 7.19 -2.58 -0.215 0.98663E+04 105 magnesite -5.49 -8.41 -2.93 -0.976 0.11215E+05 106 magnetite 2.15 2.01 -0.14 -0.011 0.53077E+03 107 minnesotaite 0.84 -1.20 -2.04 -0.120 0.78201E+04 108 minnesotaite-Mg 6.89 4.64 -2.24 -0.132 0.85930E+04 109 magnesioferrite 5.25 3.96 -1.29 -0.105 0.49440E+04 111 manganosite 5.45 3.21 -2.24 -0.559 0.85615E+04 112 margarite -16.48 -18.50 -2.01 -0.081 0.77151E+04 116 monticellite 8.88 5.33 -3.55 -0.507 0.13588E+05 118 mullite-Si -9.60 -10.93 -1.32 -0.132 0.50686E+04 119 muscovite -13.58 -14.46 -0.88 -0.052 0.33706E+04 120 paragonite -12.90 -14.00 -1.10 -0.065 0.42022E+04 121 nepheline -0.31 -1.80 -1.48 -0.212 0.56823E+04 122 osumilite(2) -12.87 -14.91 -2.04 -0.043 0.78231E+04 123 osumilite-Fe -27.78 -30.44 -2.66 -0.055 0.10182E+05 124 pargasite 5.97 1.88 -4.09 -0.108 0.15671E+05 125 periclase 5.70 3.25 -2.45 -0.614 0.94018E+04 126 periclase-Fe 3.10 1.30 -1.80 -0.450 0.68916E+04 127 perovskite-Al -7.17 -9.65 -2.49 -0.226 0.95221E+04 132 phlogopite-Na 6.28 5.39 -0.88 -0.049 0.33801E+04 134 prehnite -3.34 -6.76 -3.42 -0.201 0.13115E+05 135 prehnite-Fe 1.79 -1.58 -3.37 -0.203 0.12914E+05 138 px-Mg-tschermaks -5.68 -7.68 -2.00 -0.143 0.76743E+04 139 px-Ca-tschermaks -4.87 -7.57 -2.70 -0.193 0.10345E+05 141 pyrrhotite -8.67 -9.33 -0.67 -0.222 0.25484E+04 142 pyrrhotiteFe0.875 -9.45 -9.73 -0.28 -0.103 0.10765E+04 143 pyrophyllite -13.31 -14.75 -1.44 -0.090 0.55235E+04 146 riebeckite 5.83 3.02 -2.81 -0.077 0.10746E+05 147 ringwoodite-Fe 3.36 1.32 -2.04 -0.291 0.78106E+04 148 ringwoodite-Mg 9.57 5.22 -4.35 -0.622 0.16678E+05 149 rhodochrosite -5.47 -8.45 -2.97 -0.991 0.11390E+05 150 rhodonite 2.55 1.94 -0.60 -0.121 0.23151E+04 151 sanidine -4.27 -4.81 -0.54 -0.042 0.20667E+04 153 siderite -7.35 -10.36 -3.01 -1.005 0.11548E+05 154 sillimanite -10.32 -10.93 -0.61 -0.061 0.23257E+04 156 spinel -4.92 -6.41 -1.49 -0.099 0.57013E+04 162 stilpnomelane-Fe -6.48 -11.44 -4.96 -0.148 0.19013E+05 163 stilpnomelane-Mg 0.46 -1.70 -2.16 -0.065 0.82790E+04 164 stishovite 1.69 -1.27 -2.96 -0.988 0.11357E+05 165 sudoite-Fe -16.11 -20.54 -4.43 -0.143 0.16954E+05 166 sudoite -13.85 -16.64 -2.79 -0.090 0.10695E+05 167 sulfur -11.02 -12.52 -1.50 -0.461 0.57396E+04 168 sylvite -1.15 -3.75 -2.60 -1.300 0.99596E+04 169 talc 5.15 4.64 -0.51 -0.030 0.19536E+04 170 talc-Fe 2.25 -1.20 -3.45 -0.203 0.13216E+05 171 talc-tschermaks -5.26 -6.98 -1.72 -0.101 0.65908E+04 173 tephroite 6.63 5.16 -1.48 -0.211 0.56586E+04 176 topaz-H -8.26 -10.93 -2.67 -0.242 0.10218E+05 177 tremolite 15.39 12.76 -2.63 -0.071 0.10082E+05 179 troilite-low -8.58 -9.33 -0.76 -0.252 0.29005E+04 180 tschermakite -7.05 -10.50 -3.44 -0.093 0.13190E+05 183 wadsleyite-Fe 3.22 1.32 -1.89 -0.270 0.72480E+04 184 wadsleyite-Mg 8.63 5.22 -3.41 -0.487 0.13061E+05 185 wairakite -9.58 -11.39 -1.81 -0.107 0.69374E+04 186 walstromite 4.62 2.08 -2.54 -0.508 0.97284E+04 187 wollastonite 4.20 2.08 -2.12 -0.423 0.81096E+04 188 pseudo-wollastonite 4.32 2.08 -2.23 -0.447 0.85593E+04 189 zoisite -8.82 -11.59 -2.76 -0.126 0.10588E+05 192 beidellite-Ca -13.57 -15.37 -1.79 -0.111 0.68749E+04 193 beidellite-H -13.60 -15.92 -2.32 -0.148 0.88858E+04 194 beidellite-K -12.56 -14.66 -2.10 -0.129 0.80425E+04 195 beidellite-Mg -13.83 -15.39 -1.56 -0.096 0.59617E+04 196 beidellite-Na -12.50 -14.50 -2.00 -0.123 0.76770E+04 197 bornite -54.79 -55.16 -0.37 -0.028 0.14128E+04 199 chalcocite -14.33 -15.83 -1.50 -0.375 0.57388E+04 200 covellite -12.79 -14.17 -1.39 -0.528 0.53136E+04 202 montmorillonite-Ca -10.19 -11.53 -1.34 -0.083 0.51418E+04 203 montmorillonite-K -9.45 -10.82 -1.37 -0.084 0.52308E+04 204 montmorillonite-Mg -10.41 -11.55 -1.14 -0.071 0.43845E+04 205 montmorillonite-Na -9.12 -10.67 -1.55 -0.095 0.59383E+04 206 nontronite-Ca -3.53 -5.01 -1.47 -0.096 0.56411E+04 207 nontronite-H -3.57 -5.56 -1.99 -0.133 0.76230E+04 208 nontronite-K -2.52 -4.29 -1.78 -0.114 0.68006E+04 209 nontronite-Mg -3.75 -5.02 -1.27 -0.082 0.48647E+04 210 nontronite-Na -2.46 -4.14 -1.68 -0.108 0.64475E+04 215 gypsum -12.58 -14.83 -2.25 -0.562 0.86109E+04 232 alabandite -6.39 -7.42 -1.02 -0.341 0.39164E+04 234 anglesite -15.10 -17.45 -2.35 -1.175 0.89992E+04 238 boehmite -3.66 -4.83 -1.16 -0.194 0.44609E+04 242 copper,native 1.73 -1.65 -3.39 -1.177 0.12968E+05 244 ferrous-oxide 2.17 1.30 -0.87 -0.218 0.33344E+04 245 galena -9.85 -9.90 -0.04 -0.014 0.16233E+03 246 silver,native 0.46 -3.31 -3.77 -1.311 0.14440E+05 248 litharge 5.33 0.74 -4.59 -1.149 0.17601E+05 256 wurtzite -10.13 -10.94 -0.81 -0.269 0.30874E+04 257 zincite 2.26 -0.30 -2.56 -0.641 0.98212E+04 258 an20ab80 -5.19 -5.24 -0.06 -0.004 0.21587E+03 259 an25ab75 -5.41 -5.47 -0.06 -0.005 0.23960E+03 260 an30ab70 -5.62 -5.69 -0.07 -0.006 0.28574E+03 261 tr.625ac.25prg.125 10.00 8.96 -1.04 -0.028 0.39805E+04 Calculations done for 564.0000 Deg. C; 1123.0000 bar Temperature changed by -1.000 degrees to 563.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 34 Loop limit = 500 Temperature = 563.00 C Pressure = 1107.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5512E+02 kg liquid = 0.9930E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9967 Stoichiometric ionic strength = .3277280E+01 Osmotic coef. = 0.0000 True ionic strength = .1532206E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.49009E-05 -5.3097 0.10350E-05 -5.9851 0.21118E+00 -0.6753 2 H2O 0.99674E+00 -0.0014 0.99674E+00 -0.0014 3 Cl- 0.12872E+00 -0.8904 0.23280E-01 -1.6330 0.18086E+00 -0.7427 4 SO4-- 0.22716E-03 -3.6437 0.56296E-06 -6.2495 0.24782E-02 -2.6059 5 HCO3- 0.10041E-04 -4.9982 0.19542E-05 -5.7090 0.19463E+00 -0.7108 6 HS- 0.11735E-03 -3.9305 0.21398E-04 -4.6696 0.18234E+00 -0.7391 7 H4SiO4 0.51815E-01 -1.2855 0.51815E-01 -1.2855 0.10000E+01 0.0000 8 Al+++ 0.16759E-16 -16.7758 0.18107E-22 -22.7421 0.10805E-05 -5.9664 9 Ca++ 0.12500E-05 -5.9031 0.24875E-08 -8.6042 0.19901E-02 -2.7011 10 Mg++ 0.12197E-05 -5.9137 0.19993E-08 -8.6991 0.16391E-02 -2.7854 11 Fe++ 0.12701E-07 -7.8961 0.21868E-10 -10.6602 0.17217E-02 -2.7640 12 K+ 0.36232E-01 -1.4409 0.72223E-02 -2.1413 0.19934E+00 -0.7004 13 Na+ 0.11530E+00 -0.9382 0.21086E-01 -1.6760 0.18288E+00 -0.7378 14 Mn++ 0.10582E-05 -5.9754 0.18885E-08 -8.7239 0.17847E-02 -2.7484 15 Zn++ 0.31807E-09 -9.4975 0.54763E-12 -12.2615 0.17217E-02 -2.7640 16 Cu+ 0.14169E-07 -7.8487 0.25844E-08 -8.5876 0.18240E+00 -0.7390 17 Pb++ 0.26982E-08 -8.5689 0.60116E-11 -11.2210 0.22280E-02 -2.6521 18 Ag+ 0.29968E-09 -9.5233 0.58810E-10 -10.2305 0.19625E+00 -0.7072 19 Ba++ 0.66773E-07 -7.1754 0.15979E-09 -9.7964 0.23931E-02 -2.6210 20 HPO4-- 0.12610E-08 -8.8993 0.31408E-11 -11.5030 0.24907E-02 -2.6037 21 HSiO3- 0.14194E-05 -5.8479 0.25672E-06 -6.5905 0.18086E+00 -0.7427 22 Ca(HSiO3)+ 0.48662E-08 -8.3128 0.97852E-09 -9.0094 0.20108E+00 -0.6966 23 Mg(HSiO3)+ 0.12275E-08 -8.9110 0.24684E-09 -9.6076 0.20108E+00 -0.6966 24 NaHSiO3,aq 0.18807E-05 -5.7257 0.18807E-05 -5.7257 0.10000E+01 0.0000 28 AgCl,aq 0.11266E-06 -6.9482 0.11266E-06 -6.9482 0.10000E+01 0.0000 29 AgCl2- 0.52966E-05 -5.2760 0.95796E-06 -6.0187 0.18086E+00 -0.7427 30 AgCl3-2 0.18027E-05 -5.7441 0.41368E-08 -8.3833 0.22948E-02 -2.6393 31 AgCl4-3 0.15413E-05 -5.8121 0.14589E-11 -11.8360 0.94652E-06 -6.0239 34 Ag(HS),aq 0.17589E-08 -8.7548 0.17589E-08 -8.7548 0.10000E+01 0.0000 35 Ag(HS)2- 0.66279E-08 -8.1786 0.11987E-08 -8.9213 0.18086E+00 -0.7427 38 HAlO2,aq 0.40913E-08 -8.3881 0.40913E-08 -8.3881 0.10000E+01 0.0000 39 AlO2- 0.11928E-04 -4.9234 0.18959E-05 -5.7222 0.15895E+00 -0.7987 41 Ba(HCO3)+ 0.23085E-06 -6.6367 0.48292E-07 -7.3161 0.20919E+00 -0.6795 42 BaCl+ 0.88968E-05 -5.0508 0.17890E-05 -5.7474 0.20108E+00 -0.6966 43 CH4,aq 0.15457E-08 -8.8109 0.18388E-08 -8.7355 0.11896E+01 0.0754 48 CO,aq 0.53614E-03 -3.2707 0.53614E-03 -3.2707 0.10000E+01 0.0000 49 CO2,aq 0.26742E+01 0.4272 0.31812E+01 0.5026 0.11896E+01 0.0754 50 CO3-2 0.38032E-10 -10.4199 0.87275E-13 -13.0591 0.22948E-02 -2.6393 51 CaCO3,aq 0.10335E-10 -10.9857 0.10335E-10 -10.9857 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.11167E-06 -6.9521 0.22455E-07 -7.6487 0.20108E+00 -0.6966 53 CaCl+ 0.77874E-04 -4.1086 0.15659E-04 -4.8052 0.20108E+00 -0.6966 54 CaCl2,aq 0.79502E-04 -4.0996 0.79502E-04 -4.0996 0.10000E+01 0.0000 55 CaOH+ 0.14828E-06 -6.8289 0.29817E-07 -7.5255 0.20108E+00 -0.6966 56 CaSO4,aq 0.16436E-06 -6.7842 0.16436E-06 -6.7842 0.10000E+01 0.0000 57 HCl,aq 0.29435E-02 -2.5311 0.29435E-02 -2.5311 0.10000E+01 0.0000 66 CuCl,aq 0.21622E-04 -4.6651 0.21622E-04 -4.6651 0.10000E+01 0.0000 67 CuCl2- 0.72894E-04 -4.1373 0.13184E-04 -4.8800 0.18086E+00 -0.7427 68 CuCl3-2 0.13472E-05 -5.8706 0.30916E-08 -8.5098 0.22948E-02 -2.6393 74 FeCl+ 0.24614E-06 -6.6088 0.49495E-07 -7.3054 0.20108E+00 -0.6966 75 FeCl2,aq 0.31668E-02 -2.4994 0.31668E-02 -2.4994 0.10000E+01 0.0000 77 FeO,aq 0.61674E-07 -7.2099 0.61674E-07 -7.2099 0.10000E+01 0.0000 78 FeOH+ 0.20875E-07 -7.6804 0.41977E-08 -8.3770 0.20108E+00 -0.6966 79 HFeO2- 0.71011E-08 -8.1487 0.12843E-08 -8.8913 0.18086E+00 -0.7427 82 FeO2- 0.44261E-08 -8.3540 0.80053E-09 -9.0966 0.18086E+00 -0.7427 83 HFeO2,aq 0.28567E-09 -9.5441 0.28567E-09 -9.5441 0.10000E+01 0.0000 84 H2,aq 0.45687E-02 -2.3402 0.54349E-02 -2.2648 0.11896E+01 0.0754 85 KCl,aq 0.71119E-01 -1.1480 0.71119E-01 -1.1480 0.10000E+01 0.0000 86 KHSO4,aq 0.13586E-01 -1.8669 0.13586E-01 -1.8669 0.10000E+01 0.0000 87 KOH,aq 0.13683E-05 -5.8638 0.13683E-05 -5.8638 0.10000E+01 0.0000 88 KSO4- 0.46656E-02 -2.3311 0.84383E-03 -3.0737 0.18086E+00 -0.7427 90 Mg(HCO3)+ 0.30940E-07 -7.5095 0.62216E-08 -8.2061 0.20108E+00 -0.6966 91 MgCl+ 0.13254E-04 -4.8777 0.26651E-05 -5.5743 0.20108E+00 -0.6966 92 MgOH+ 0.51140E-06 -6.2912 0.10283E-06 -6.9879 0.20108E+00 -0.6966 94 MnO,aq 0.89669E-07 -7.0474 0.89669E-07 -7.0474 0.10000E+01 0.0000 95 MnOH+ 0.20064E-06 -6.6976 0.40345E-07 -7.3942 0.20108E+00 -0.6966 97 HMnO2- 0.41574E-10 -10.3812 0.75191E-11 -11.1238 0.18086E+00 -0.7427 100 MnCl+ 0.11559E-02 -2.9371 0.23243E-03 -3.6337 0.20108E+00 -0.6966 101 MnSO4,aq 0.13723E-06 -6.8626 0.13723E-06 -6.8626 0.10000E+01 0.0000 102 NaCl,aq 0.44319E+00 -0.3534 0.44319E+00 -0.3534 0.10000E+01 0.0000 103 NaOH,aq 0.18304E-05 -5.7375 0.18304E-05 -5.7375 0.10000E+01 0.0000 105 OH- 0.74901E-05 -5.1255 0.11906E-05 -5.9242 0.15895E+00 -0.7987 111 H3PO3,aq 0.11239E-09 -9.9493 0.11239E-09 -9.9493 0.10000E+01 0.0000 112 H2PO3- 0.19733E-08 -8.7048 0.35690E-09 -9.4475 0.18086E+00 -0.7427 113 H3PO4,aq 0.12507E-05 -5.9029 0.12507E-05 -5.9029 0.10000E+01 0.0000 114 H2PO4- 0.13519E-05 -5.8690 0.25687E-06 -6.5903 0.19000E+00 -0.7212 116 H4P2O7,aq 0.14551E-09 -9.8371 0.14551E-09 -9.8371 0.10000E+01 0.0000 117 H3P2O7- 0.84103E-09 -9.0752 0.15211E-09 -9.8178 0.18086E+00 -0.7427 118 H2P2O7-2 0.20755E-06 -6.6829 0.47629E-09 -9.3221 0.22948E-02 -2.6393 119 HP2O7-3 0.20706E-07 -7.6839 0.19599E-13 -13.7078 0.94652E-06 -6.0239 121 PbCl+ 0.12707E-05 -5.8959 0.25553E-06 -6.5926 0.20108E+00 -0.6966 122 PbCl2,aq 0.86448E-04 -4.0632 0.86448E-04 -4.0632 0.10000E+01 0.0000 123 PbCl3- 0.99030E-04 -4.0042 0.17911E-04 -4.7469 0.18086E+00 -0.7427 124 PbCl4-2 0.17121E-04 -4.7665 0.39290E-07 -7.4057 0.22948E-02 -2.6393 125 PbO,aq 0.65439E-08 -8.1842 0.65439E-08 -8.1842 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12499E-03 -3.9031 0.12499E-03 -3.9031 0.10000E+01 0.0000 128 Pb(HS)3- 0.13696E-04 -4.8634 0.24771E-05 -5.6061 0.18086E+00 -0.7427 129 H2S,aq 0.10576E+01 0.0243 0.12581E+01 0.0997 0.11896E+01 0.0754 130 S2-2 0.12189E-07 -7.9140 0.27971E-10 -10.5533 0.22948E-02 -2.6393 131 S3-2 0.11283E-08 -8.9476 0.25892E-11 -11.5868 0.22948E-02 -2.6393 132 S3- 0.10234E-01 -1.9899 0.18510E-02 -2.7326 0.18086E+00 -0.7427 133 S4-2 0.88604E-10 -10.0525 0.20333E-12 -12.6918 0.22948E-02 -2.6393 135 SO2,aq 0.29295E+00 -0.5332 0.29295E+00 -0.5332 0.10000E+01 0.0000 136 SO3-2 0.62559E-09 -9.2037 0.22746E-11 -11.6431 0.36359E-02 -2.4394 137 HSO3- 0.25156E-03 -3.5994 0.45499E-04 -4.3420 0.18086E+00 -0.7427 138 HSO4- 0.82060E-02 -2.0859 0.16951E-02 -2.7708 0.20657E+00 -0.6849 140 S2O3-2 0.49123E-06 -6.3087 0.11273E-08 -8.9480 0.22948E-02 -2.6393 141 HS2O3- 0.37601E-06 -6.4248 0.68006E-07 -7.1675 0.18086E+00 -0.7427 142 H2S2O3,aq 0.32531E-07 -7.4877 0.32531E-07 -7.4877 0.10000E+01 0.0000 150 S4O6-2 0.42247E-09 -9.3742 0.96949E-12 -12.0135 0.22948E-02 -2.6393 152 ZnCl+ 0.15957E-03 -3.7970 0.32087E-04 -4.4937 0.20108E+00 -0.6966 153 ZnCl2,aq 0.64272E-03 -3.1920 0.64272E-03 -3.1920 0.10000E+01 0.0000 154 ZnCl3- 0.47064E-04 -4.3273 0.85121E-05 -5.0700 0.18086E+00 -0.7427 155 ZnO,aq 0.29341E-07 -7.5325 0.29341E-07 -7.5325 0.10000E+01 0.0000 156 ZnOH+ 0.10853E-05 -5.9644 0.21824E-06 -6.6611 0.20108E+00 -0.6966 158 HZnO2- 0.22032E-09 -9.6569 0.39848E-10 -10.3996 0.18086E+00 -0.7427 Charge balance for all species = 0.2549E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4900911E-05 0.4295477E+01 0.3541567E+04 0.0000 2 H2O 0.1000000E+01 0.5251955E+02 0.7739482E+06 0.0000 3 Cl- 0.1287166E+00 0.6560376E+00 0.1902528E+05 4.3520 4 SO4-- 0.2271611E-03 0.2517051E+00 0.1977840E+05 5.7206 5 HCO3- 0.1004057E-04 0.2674774E+01 0.1335023E+06 0.2760 6 HS- 0.1173541E-03 0.1156889E+01 0.3129690E+05 1.3154 7 H4SiO4 0.5181510E-01 0.5181841E-01 0.4074051E+04 -1.2855 8 Al+++ 0.1675879E-16 0.1193180E-04 0.2633429E+00 -4.7870 9 Ca++ 0.1249963E-05 0.1590560E-03 0.5214412E+01 3.3659 10 Mg++ 0.1219716E-05 0.1501693E-04 0.2986422E+00 3.2710 11 Fe++ 0.1270141E-07 0.3167180E-02 0.1446845E+03 1.3099 12 K+ 0.3623153E-01 0.1256037E+00 0.4017454E+04 3.8437 13 Na+ 0.1153024E+00 0.5584958E+00 0.1050278E+05 4.3091 14 Mn++ 0.1058172E-05 0.1157396E-02 0.5201206E+02 3.2462 15 Zn++ 0.3180745E-09 0.8504729E-03 0.4547664E+02 -0.2914 16 Cu+ 0.1416898E-07 0.9587727E-04 0.4983245E+01 -2.6026 17 Pb++ 0.2698213E-08 0.3425626E-03 0.5805747E+02 0.7491 18 Ag+ 0.2996771E-09 0.8761971E-05 0.7731289E+00 -4.2455 19 Ba++ 0.6677268E-07 0.9194430E-05 0.1032931E+01 2.1737 20 HPO4-- 0.1261004E-08 0.3064454E-05 0.2405906E+00 0.4672 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265509E+01 -.3147044E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5215314E+02 -.1883638E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2499490E+00 0.1773788E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1148817E+01 0.1132673E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.5145689E-01 0.9213743E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1184856E-04 0.6826910E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1579463E-03 0.3699636E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1491216E-04 0.5764491E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.3145084E-02 0.5621670E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247274E+00 0.6826910E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149321E-02 0.1792257E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.8445395E-03 0.1454795E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.9520837E-04 0.3044013E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.9130284E-05 0.4624217E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3043075E-05 0.5524426E-05 0.0000000E+00 Chg. balance for solid moles: 0.2404E-17 Mass of aqueous solution: 0.121398E+04 g Temperature = 563.00 C Pressure = 1107.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3608E-03 -3.443 0.4911E-01 -1.309 0.7557 0.1658E-01 annite 0.7700E-06 -6.114 0.3942E-03 -3.404 0.6065E-02 0.1188E-03 phlogopite 0.1921E-05 -5.716 0.8018E-03 -3.096 0.1234E-01 0.2875E-03 biotite-Mn 0.5974E-07 -7.224 0.3042E-04 -4.517 0.4680E-03 0.9118E-05 apatite-OH 0.1841E-05 -5.735 0.9250E-03 -3.034 0.1423E-01 0.2939E-03 microcline 0.6799E-03 -3.168 0.1893 -0.723 2.912 0.7393E-01 pyrite 0.5315E-02 -2.275 0.6377 -0.195 9.812 0.1272 quartz 0.9009E-01 -1.045 5.413 0.733 83.28 2.044 barite 0.4624E-04 -4.335 0.1079E-01 -1.967 0.1661 0.2409E-02 chalcopyrite 0.3044E-03 -3.517 0.5586E-01 -1.253 0.8595 0.1304E-01 sphalerite 0.1455E-02 -2.837 0.1417 -0.849 2.181 0.3466E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2799E+00 0.2799E+00 1.0000 -0.553 phlogopite 0.6984E+00 0.6984E+00 1.0000 -0.156 biotite-Mn 0.2171E-01 0.2171E-01 1.0000 -1.663 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.499168 g Volume = 2.312578 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.85 -14.85 0.00 0.000 0.67965E-11 24 annite 0.79 0.79 0.00 0.000 -0.24637E-10 25 phlogopite 5.48 5.48 0.00 0.000 0.16991E-10 26 biotite-Mn 9.93 9.93 0.00 0.000 -0.27186E-10 30 apatite-OH -53.59 -53.59 0.00 0.000 0.00000E+00 115 microcline -4.79 -4.79 0.00 0.000 0.67965E-11 140 pyrite -21.89 -21.89 0.00 0.000 0.00000E+00 144 quartz -1.28 -1.28 0.00 0.000 0.00000E+00 237 barite -16.05 -16.05 0.00 0.000 0.00000E+00 240 chalcopyrite -23.55 -23.55 0.00 0.000 0.00000E+00 255 sphalerite -10.95 -10.95 0.00 0.000 -0.13593E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.27 0.00 -0.27 -0.266 0.10195E+04 2.778 2 CO2,gas -10.02 -11.69 -1.68 -0.559 0.64182E+04 1.367 3 CH4,gas 6.86 -4.13 -10.99 -2.746 0.42033E+05 -7.942 4 H2,gas 5.96 1.89 -4.07 -2.326 0.15572E+05 -1.026 5 H2S,gas -8.34 -10.65 -2.31 -1.155 0.88420E+04 0.733 6 CO,gas -3.80 -9.80 -6.00 -1.847 0.22966E+05 -2.958 7 SO3,gas -7.58 -18.22 -10.64 -2.659 0.40701E+05 -7.594 8 O2,gas 16.83 -3.78 -20.61 -13.739 0.78852E+05 -17.565 9 HCl,gas -6.13 -7.62 -1.49 -0.746 0.57112E+04 -1.493 10 acmite 3.62 2.11 -1.52 -0.157 0.57998E+04 12 akimotoite 6.20 1.99 -4.21 -0.842 0.16112E+05 13 akimotoite-Fe 4.07 0.03 -4.04 -0.808 0.15467E+05 14 albite-high -4.19 -4.33 -0.14 -0.011 0.52529E+03 15 albite -4.19 -4.33 -0.14 -0.011 0.54813E+03 16 almandine -7.57 -9.50 -1.93 -0.097 0.73850E+04 17 pyrope -0.83 -3.62 -2.79 -0.139 0.10673E+05 18 analcite -2.07 -3.05 -0.98 -0.109 0.37505E+04 19 andalusite -10.28 -10.86 -0.58 -0.058 0.22338E+04 20 andradite 11.87 6.97 -4.90 -0.255 0.18754E+05 27 anorthite -7.96 -8.78 -0.82 -0.063 0.31440E+04 28 anthophyllite 14.82 12.62 -2.19 -0.059 0.83967E+04 29 anthophyllite-Fe 1.96 -1.10 -3.07 -0.083 0.11738E+05 31 apatite-OH-zs -51.41 -53.59 -2.18 -0.168 0.83461E+04 32 apatite-Cl-zs -57.96 -61.21 -3.25 -0.271 0.12433E+05 33 aragonite -4.66 -8.33 -3.66 -1.221 0.14018E+05 34 brucite 5.53 3.27 -2.26 -0.451 0.86366E+04 35 calcite -4.77 -8.33 -3.56 -1.186 0.13615E+05 36 carnegieite-low 0.02 -1.76 -1.79 -0.255 0.68348E+04 37 carnegieite-high 0.10 -1.76 -1.87 -0.267 0.71464E+04 38 carpholite-Mg -6.79 -8.88 -2.09 -0.139 0.79827E+04 39 carpholite-Fe -8.17 -10.84 -2.67 -0.178 0.10203E+05 40 celadonite -0.71 -2.81 -2.10 -0.124 0.80403E+04 41 celadonite-Fe -2.14 -4.77 -2.63 -0.155 0.10080E+05 42 chrysotile 9.64 7.24 -2.40 -0.200 0.91715E+04 44 clinochlore 4.36 2.92 -1.44 -0.045 0.55219E+04 45 daphnite -2.83 -6.89 -4.05 -0.127 0.15514E+05 47 chlorite-Al-free 19.45 14.48 -4.97 -0.207 0.19014E+05 48 chloritoid-Mg -6.19 -7.59 -1.40 -0.094 0.53696E+04 49 chloritoid-Fe -8.16 -9.55 -1.39 -0.093 0.53206E+04 50 chloritoid-Mn -6.02 -7.62 -1.60 -0.107 0.61253E+04 52 coesite -0.99 -1.28 -0.29 -0.097 0.11144E+04 53 cordierite-H -18.01 -19.03 -1.02 -0.036 0.39102E+04 54 cordierite-Fe -20.65 -22.95 -2.30 -0.079 0.88109E+04 55 cordierite-Mn -16.29 -19.08 -2.80 -0.096 0.10694E+05 56 corundum -8.82 -9.58 -0.76 -0.069 0.29091E+04 58 cristobalite -1.24 -1.28 -0.05 -0.016 0.18116E+03 59 cummingtonite 14.89 12.62 -2.26 -0.061 0.86548E+04 61 cymrite-K -2.48 -4.80 -2.32 -0.193 0.88692E+04 63 diaspore -3.91 -4.79 -0.88 -0.146 0.33568E+04 65 diopside 5.46 4.07 -1.39 -0.139 0.53088E+04 66 hedenbergite 4.01 2.11 -1.90 -0.190 0.72712E+04 68 eastonite -5.16 -6.55 -1.39 -0.054 0.53226E+04 69 enstatite 4.84 3.97 -0.87 -0.087 0.33173E+04 70 clinoenstatite-HiP 5.34 3.97 -1.37 -0.137 0.52239E+04 71 clinoenstatite 4.82 3.97 -0.85 -0.085 0.32527E+04 72 protoenstatite 4.97 3.97 -1.00 -0.100 0.38257E+04 73 epidote -3.93 -6.34 -2.40 -0.116 0.91863E+04 74 clinozoisite -8.64 -11.49 -2.85 -0.130 0.10901E+05 75 epidote-Fe 2.46 -1.18 -3.65 -0.189 0.13947E+05 76 fayalite 2.39 1.33 -1.06 -0.151 0.40386E+04 77 ferrosilite 1.21 0.05 -1.15 -0.115 0.44149E+04 78 forsterite 6.44 5.26 -1.19 -0.169 0.45364E+04 79 gedrite -8.25 -10.51 -2.26 -0.061 0.86406E+04 81 gibbsite -2.28 -4.79 -2.51 -0.358 0.95917E+04 82 glaucophane 1.65 -1.42 -3.07 -0.083 0.11747E+05 83 glaucophane-Fe -2.47 -7.30 -4.83 -0.130 0.18462E+05 84 goethite 1.22 0.36 -0.86 -0.186 0.32991E+04 86 greenalite 4.68 1.36 -3.32 -0.277 0.12712E+05 87 grunerite 2.52 -1.10 -3.63 -0.098 0.13882E+05 88 halite -1.27 -3.31 -2.04 -1.019 0.77975E+04 89 hematite 0.90 0.73 -0.18 -0.021 0.67753E+03 90 heulandite -11.99 -15.20 -3.21 -0.146 0.12296E+05 91 hercynite -7.01 -8.27 -1.26 -0.084 0.48312E+04 94 jadeite -1.38 -3.05 -1.66 -0.166 0.63602E+04 96 kalsilite -0.60 -2.23 -1.63 -0.233 0.62309E+04 97 kaolinite -9.34 -12.15 -2.81 -0.255 0.10748E+05 98 kyanite -10.11 -10.86 -0.75 -0.075 0.28605E+04 100 laumontite -7.64 -11.35 -3.71 -0.247 0.14177E+05 101 lawsonite -5.19 -8.78 -3.60 -0.240 0.13760E+05 102 leucite -2.55 -3.51 -0.97 -0.097 0.36969E+04 104 lizardite 9.81 7.24 -2.57 -0.214 0.98202E+04 105 magnesite -5.49 -8.42 -2.93 -0.977 0.11212E+05 106 magnetite 2.19 2.03 -0.16 -0.013 0.60089E+03 107 minnesotaite 0.86 -1.21 -2.06 -0.121 0.78902E+04 108 minnesotaite-Mg 6.91 4.68 -2.24 -0.132 0.85549E+04 109 magnesioferrite 5.30 4.00 -1.30 -0.106 0.49783E+04 111 manganosite 5.47 3.24 -2.22 -0.556 0.85078E+04 112 margarite -16.31 -18.36 -2.05 -0.082 0.78275E+04 116 monticellite 8.91 5.35 -3.55 -0.508 0.13599E+05 118 mullite-Si -9.52 -10.86 -1.34 -0.134 0.51196E+04 119 muscovite -13.48 -14.37 -0.89 -0.053 0.34162E+04 120 paragonite -12.80 -13.91 -1.11 -0.065 0.42519E+04 121 nepheline -0.28 -1.76 -1.49 -0.212 0.56870E+04 122 osumilite(2) -12.77 -14.83 -2.05 -0.043 0.78493E+04 123 osumilite-Fe -27.61 -30.31 -2.70 -0.056 0.10336E+05 124 pargasite 6.16 2.05 -4.11 -0.108 0.15739E+05 125 periclase 5.72 3.27 -2.45 -0.614 0.93924E+04 126 periclase-Fe 3.12 1.31 -1.81 -0.452 0.69194E+04 127 perovskite-Al -7.08 -9.58 -2.50 -0.227 0.95716E+04 132 phlogopite-Na 6.35 5.48 -0.88 -0.049 0.33530E+04 134 prehnite -3.25 -6.70 -3.45 -0.203 0.13200E+05 135 prehnite-Fe 1.85 -1.55 -3.40 -0.204 0.12996E+05 138 px-Mg-tschermaks -5.57 -7.59 -2.02 -0.144 0.77173E+04 139 px-Ca-tschermaks -4.77 -7.50 -2.72 -0.194 0.10415E+05 141 pyrrhotite -8.67 -9.34 -0.67 -0.224 0.25662E+04 142 pyrrhotiteFe0.875 -9.46 -9.74 -0.29 -0.105 0.10912E+04 143 pyrophyllite -13.26 -14.71 -1.45 -0.091 0.55662E+04 146 riebeckite 5.83 3.00 -2.83 -0.078 0.10826E+05 147 ringwoodite-Fe 3.39 1.33 -2.06 -0.294 0.78630E+04 148 ringwoodite-Mg 9.61 5.26 -4.35 -0.622 0.16659E+05 149 rhodochrosite -5.48 -8.45 -2.96 -0.988 0.11341E+05 150 rhodonite 2.55 1.96 -0.59 -0.118 0.22621E+04 151 sanidine -4.25 -4.79 -0.54 -0.042 0.20665E+04 153 siderite -7.36 -10.38 -3.03 -1.009 0.11580E+05 154 sillimanite -10.24 -10.86 -0.62 -0.062 0.23753E+04 156 spinel -4.81 -6.31 -1.50 -0.100 0.57409E+04 163 stilpnomelane-Mg 0.58 -1.58 -2.16 -0.064 0.82573E+04 164 stishovite 1.69 -1.28 -2.97 -0.989 0.11356E+05 165 sudoite-Fe -15.92 -20.39 -4.47 -0.144 0.17102E+05 166 sudoite -13.66 -16.47 -2.81 -0.091 0.10769E+05 167 sulfur -11.05 -12.54 -1.50 -0.461 0.57300E+04 168 sylvite -1.18 -3.77 -2.60 -1.299 0.99401E+04 169 talc 5.18 4.68 -0.50 -0.029 0.19169E+04 170 talc-Fe 2.27 -1.21 -3.47 -0.204 0.13287E+05 171 talc-tschermaks -5.16 -6.89 -1.73 -0.102 0.66130E+04 173 tephroite 6.66 5.21 -1.45 -0.207 0.55502E+04 176 topaz-H -8.18 -10.86 -2.68 -0.244 0.10258E+05 177 tremolite 15.45 12.81 -2.63 -0.071 0.10072E+05 179 troilite-low -8.58 -9.34 -0.76 -0.254 0.29171E+04 180 tschermakite -6.84 -10.32 -3.47 -0.094 0.13293E+05 183 wadsleyite-Fe 3.24 1.33 -1.91 -0.273 0.73023E+04 184 wadsleyite-Mg 8.67 5.26 -3.41 -0.487 0.13044E+05 185 wairakite -9.52 -11.35 -1.83 -0.108 0.69986E+04 186 walstromite 4.63 2.08 -2.55 -0.510 0.97500E+04 187 wollastonite 4.21 2.08 -2.12 -0.425 0.81300E+04 188 pseudo-wollastonite 4.32 2.08 -2.24 -0.449 0.85807E+04 189 zoisite -8.69 -11.49 -2.80 -0.127 0.10703E+05 192 beidellite-Ca -13.50 -15.31 -1.81 -0.112 0.69285E+04 193 beidellite-H -13.53 -15.87 -2.34 -0.149 0.89353E+04 194 beidellite-K -12.49 -14.60 -2.11 -0.129 0.80848E+04 195 beidellite-Mg -13.76 -15.33 -1.57 -0.097 0.60124E+04 196 beidellite-Na -12.43 -14.45 -2.02 -0.124 0.77207E+04 197 bornite -54.91 -55.27 -0.36 -0.027 0.13715E+04 199 chalcocite -14.37 -15.86 -1.49 -0.373 0.57156E+04 200 covellite -12.82 -14.20 -1.38 -0.527 0.52927E+04 202 montmorillonite-Ca -10.14 -11.50 -1.35 -0.084 0.51762E+04 203 montmorillonite-K -9.41 -10.78 -1.37 -0.084 0.52569E+04 204 montmorillonite-Mg -10.36 -11.51 -1.15 -0.071 0.44135E+04 205 montmorillonite-Na -9.07 -10.63 -1.56 -0.095 0.59616E+04 206 nontronite-Ca -3.52 -5.01 -1.49 -0.096 0.56911E+04 207 nontronite-H -3.56 -5.56 -2.00 -0.134 0.76685E+04 208 nontronite-K -2.51 -4.30 -1.79 -0.115 0.68393E+04 209 nontronite-Mg -3.74 -5.02 -1.28 -0.083 0.49098E+04 210 nontronite-Na -2.45 -4.14 -1.70 -0.109 0.64874E+04 215 gypsum -12.61 -14.86 -2.25 -0.563 0.86107E+04 232 alabandite -6.40 -7.41 -1.01 -0.336 0.38555E+04 234 anglesite -15.13 -17.47 -2.34 -1.169 0.89480E+04 238 boehmite -3.62 -4.79 -1.17 -0.195 0.44821E+04 242 copper,native 1.73 -1.66 -3.39 -1.178 0.12955E+05 244 ferrous-oxide 2.19 1.31 -0.88 -0.220 0.33632E+04 245 galena -9.87 -9.91 -0.03 -0.010 0.11994E+03 246 silver,native 0.45 -3.30 -3.75 -1.305 0.14356E+05 248 litharge 5.34 0.75 -4.59 -1.148 0.17565E+05 256 wurtzite -10.14 -10.95 -0.81 -0.269 0.30874E+04 257 zincite 2.28 -0.29 -2.57 -0.642 0.98299E+04 258 an20ab80 -5.16 -5.22 -0.06 -0.005 0.23590E+03 259 an25ab75 -5.37 -5.44 -0.07 -0.005 0.26341E+03 260 an30ab70 -5.58 -5.66 -0.08 -0.006 0.31273E+03 261 tr.625ac.25prg.125 10.07 9.02 -1.05 -0.028 0.40365E+04 Calculations done for 563.0000 Deg. C; 1107.0000 bar Temperature changed by -1.000 degrees to 562.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 35 Loop limit = 500 Temperature = 562.00 C Pressure = 1091.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5512E+02 kg liquid = 0.9931E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9968 Stoichiometric ionic strength = .3276556E+01 Osmotic coef. = 0.0000 True ionic strength = .1506373E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.47665E-05 -5.3218 0.10009E-05 -5.9996 0.20998E+00 -0.6778 2 H2O 0.99677E+00 -0.0014 0.99677E+00 -0.0014 3 Cl- 0.12648E+00 -0.8980 0.22723E-01 -1.6435 0.17966E+00 -0.7455 4 SO4-- 0.22887E-03 -3.6404 0.55378E-06 -6.2567 0.24196E-02 -2.6163 5 HCO3- 0.97197E-05 -5.0123 0.18786E-05 -5.7262 0.19328E+00 -0.7138 6 HS- 0.11619E-03 -3.9348 0.21044E-04 -4.6769 0.18112E+00 -0.7420 7 H4SiO4 0.50751E-01 -1.2946 0.50751E-01 -1.2946 0.10000E+01 0.0000 8 Al+++ 0.17430E-16 -16.7587 0.17855E-22 -22.7482 0.10244E-05 -5.9895 9 Ca++ 0.12151E-05 -5.9154 0.23615E-08 -8.6268 0.19435E-02 -2.7114 10 Mg++ 0.12305E-05 -5.9099 0.19710E-08 -8.7053 0.16018E-02 -2.7954 11 Fe++ 0.12441E-07 -7.9051 0.20928E-10 -10.6793 0.16822E-02 -2.7741 12 K+ 0.35684E-01 -1.4475 0.70628E-02 -2.1510 0.19793E+00 -0.7035 13 Na+ 0.11328E+00 -0.9459 0.20576E-01 -1.6866 0.18164E+00 -0.7408 14 Mn++ 0.10862E-05 -5.9641 0.18938E-08 -8.7227 0.17435E-02 -2.7586 15 Zn++ 0.31247E-09 -9.5052 0.52562E-12 -12.2793 0.16822E-02 -2.7741 16 Cu+ 0.13626E-07 -7.8656 0.24686E-08 -8.6075 0.18117E+00 -0.7419 17 Pb++ 0.26572E-08 -8.5756 0.57800E-11 -11.2381 0.21752E-02 -2.6625 18 Ag+ 0.29934E-09 -9.5238 0.58332E-10 -10.2341 0.19487E+00 -0.7103 19 Ba++ 0.63932E-07 -7.1943 0.14935E-09 -9.8258 0.23360E-02 -2.6315 20 HPO4-- 0.12822E-08 -8.8921 0.31179E-11 -11.5061 0.24317E-02 -2.6141 21 HSiO3- 0.13955E-05 -5.8553 0.25072E-06 -6.6008 0.17966E+00 -0.7455 22 Ca(HSiO3)+ 0.46806E-08 -8.3297 0.93451E-09 -9.0294 0.19966E+00 -0.6997 23 Mg(HSiO3)+ 0.12349E-08 -8.9084 0.24655E-09 -9.6081 0.19966E+00 -0.6997 24 NaHSiO3,aq 0.18955E-05 -5.7223 0.18955E-05 -5.7223 0.10000E+01 0.0000 28 AgCl,aq 0.11537E-06 -6.9379 0.11537E-06 -6.9379 0.10000E+01 0.0000 29 AgCl2- 0.53289E-05 -5.2734 0.95740E-06 -6.0189 0.17966E+00 -0.7455 30 AgCl3-2 0.17804E-05 -5.7495 0.39898E-08 -8.3990 0.22409E-02 -2.6496 31 AgCl4-3 0.15281E-05 -5.8159 0.13731E-11 -11.8623 0.89856E-06 -6.0465 34 Ag(HS),aq 0.18402E-08 -8.7351 0.18402E-08 -8.7351 0.10000E+01 0.0000 35 Ag(HS)2- 0.67799E-08 -8.1688 0.12181E-08 -8.9143 0.17966E+00 -0.7455 38 HAlO2,aq 0.40767E-08 -8.3897 0.40767E-08 -8.3897 0.10000E+01 0.0000 39 AlO2- 0.11641E-04 -4.9340 0.18393E-05 -5.7354 0.15800E+00 -0.8013 41 Ba(HCO3)+ 0.21835E-06 -6.6608 0.45347E-07 -7.3435 0.20768E+00 -0.6826 42 BaCl+ 0.84424E-05 -5.0735 0.16856E-05 -5.7733 0.19966E+00 -0.6997 43 CH4,aq 0.15272E-08 -8.8161 0.18149E-08 -8.7411 0.11884E+01 0.0750 48 CO,aq 0.52680E-03 -3.2784 0.52680E-03 -3.2784 0.10000E+01 0.0000 49 CO2,aq 0.26742E+01 0.4272 0.31779E+01 0.5021 0.11884E+01 0.0750 50 CO3-2 0.37518E-10 -10.4258 0.84075E-13 -13.0753 0.22409E-02 -2.6496 51 CaCO3,aq 0.10132E-10 -10.9943 0.10132E-10 -10.9943 0.10000E+01 0.0000 52 Ca(HCO3)+ 0.10503E-06 -6.9787 0.20969E-07 -7.6784 0.19966E+00 -0.6997 53 CaCl+ 0.74658E-04 -4.1269 0.14906E-04 -4.8266 0.19966E+00 -0.6997 54 CaCl2,aq 0.77569E-04 -4.1103 0.77569E-04 -4.1103 0.10000E+01 0.0000 55 CaOH+ 0.14273E-06 -6.8455 0.28497E-07 -7.5452 0.19966E+00 -0.6997 56 CaSO4,aq 0.16604E-06 -6.7798 0.16604E-06 -6.7798 0.10000E+01 0.0000 57 HCl,aq 0.30400E-02 -2.5171 0.30400E-02 -2.5171 0.10000E+01 0.0000 66 CuCl,aq 0.21337E-04 -4.6709 0.21337E-04 -4.6709 0.10000E+01 0.0000 67 CuCl2- 0.71245E-04 -4.1472 0.12800E-04 -4.8928 0.17966E+00 -0.7455 68 CuCl3-2 0.12947E-05 -5.8878 0.29013E-08 -8.5374 0.22409E-02 -2.6496 74 FeCl+ 0.23790E-06 -6.6236 0.47499E-07 -7.3233 0.19966E+00 -0.6997 75 FeCl2,aq 0.30327E-02 -2.5182 0.30327E-02 -2.5182 0.10000E+01 0.0000 77 FeO,aq 0.60403E-07 -7.2189 0.60403E-07 -7.2189 0.10000E+01 0.0000 78 FeOH+ 0.20237E-07 -7.6938 0.40405E-08 -8.3936 0.19966E+00 -0.6997 79 HFeO2- 0.68863E-08 -8.1620 0.12372E-08 -8.9076 0.17966E+00 -0.7455 82 FeO2- 0.42871E-08 -8.3678 0.77022E-09 -9.1134 0.17966E+00 -0.7455 83 HFeO2,aq 0.28501E-09 -9.5451 0.28501E-09 -9.5451 0.10000E+01 0.0000 84 H2,aq 0.45506E-02 -2.3419 0.54078E-02 -2.2670 0.11884E+01 0.0750 85 KCl,aq 0.71572E-01 -1.1453 0.71572E-01 -1.1453 0.10000E+01 0.0000 86 KHSO4,aq 0.13640E-01 -1.8652 0.13640E-01 -1.8652 0.10000E+01 0.0000 87 KOH,aq 0.13820E-05 -5.8595 0.13820E-05 -5.8595 0.10000E+01 0.0000 88 KSO4- 0.47022E-02 -2.3277 0.84481E-03 -3.0732 0.17966E+00 -0.7455 90 Mg(HCO3)+ 0.30016E-07 -7.5226 0.59929E-08 -8.2224 0.19966E+00 -0.6997 91 MgCl+ 0.13253E-04 -4.8777 0.26461E-05 -5.5774 0.19966E+00 -0.6997 92 MgOH+ 0.51209E-06 -6.2907 0.10224E-06 -6.9904 0.19966E+00 -0.6997 94 MnO,aq 0.92436E-07 -7.0342 0.92436E-07 -7.0342 0.10000E+01 0.0000 95 MnOH+ 0.20295E-06 -6.6926 0.40521E-07 -7.3923 0.19966E+00 -0.6997 97 HMnO2- 0.42194E-10 -10.3747 0.75806E-11 -11.1203 0.17966E+00 -0.7455 100 MnCl+ 0.11558E-02 -2.9371 0.23077E-03 -3.6368 0.19966E+00 -0.6997 101 MnSO4,aq 0.14560E-06 -6.8368 0.14560E-06 -6.8368 0.10000E+01 0.0000 102 NaCl,aq 0.44520E+00 -0.3514 0.44520E+00 -0.3514 0.10000E+01 0.0000 103 NaOH,aq 0.18434E-05 -5.7344 0.18434E-05 -5.7344 0.10000E+01 0.0000 105 OH- 0.74078E-05 -5.1303 0.11704E-05 -5.9317 0.15800E+00 -0.8013 111 H3PO3,aq 0.11323E-09 -9.9461 0.11323E-09 -9.9461 0.10000E+01 0.0000 112 H2PO3- 0.19192E-08 -8.7169 0.34481E-09 -9.4624 0.17966E+00 -0.7455 113 H3PO4,aq 0.12847E-05 -5.8912 0.12847E-05 -5.8912 0.10000E+01 0.0000 114 H2PO4- 0.13509E-05 -5.8694 0.25493E-06 -6.5936 0.18870E+00 -0.7242 116 H4P2O7,aq 0.15390E-09 -9.8127 0.15390E-09 -9.8127 0.10000E+01 0.0000 117 H3P2O7- 0.84683E-09 -9.0722 0.15214E-09 -9.8177 0.17966E+00 -0.7455 118 H2P2O7-2 0.20658E-06 -6.6849 0.46292E-09 -9.3345 0.22409E-02 -2.6496 119 HP2O7-3 0.21142E-07 -7.6748 0.18998E-13 -13.7213 0.89856E-06 -6.0465 121 PbCl+ 0.12424E-05 -5.9057 0.24805E-06 -6.6055 0.19966E+00 -0.6997 122 PbCl2,aq 0.86443E-04 -4.0633 0.86443E-04 -4.0633 0.10000E+01 0.0000 123 PbCl3- 0.98249E-04 -4.0077 0.17652E-04 -4.7532 0.17966E+00 -0.7455 124 PbCl4-2 0.16667E-04 -4.7781 0.37349E-07 -7.4277 0.22409E-02 -2.6496 125 PbO,aq 0.66539E-08 -8.1769 0.66539E-08 -8.1769 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12612E-03 -3.8992 0.12612E-03 -3.8992 0.10000E+01 0.0000 128 Pb(HS)3- 0.13816E-04 -4.8596 0.24823E-05 -5.6051 0.17966E+00 -0.7455 129 H2S,aq 0.10579E+01 0.0245 0.12572E+01 0.0994 0.11884E+01 0.0750 130 S2-2 0.12008E-07 -7.9205 0.26909E-10 -10.5701 0.22409E-02 -2.6496 131 S3-2 0.11093E-08 -8.9550 0.24858E-11 -11.6045 0.22409E-02 -2.6496 132 S3- 0.99550E-02 -2.0020 0.17885E-02 -2.7475 0.17966E+00 -0.7455 133 S4-2 0.86991E-10 -10.0605 0.19494E-12 -12.7101 0.22409E-02 -2.6496 135 SO2,aq 0.29311E+00 -0.5330 0.29311E+00 -0.5330 0.10000E+01 0.0000 136 SO3-2 0.62527E-09 -9.2039 0.22181E-11 -11.6540 0.35474E-02 -2.4501 137 HSO3- 0.24645E-03 -3.6083 0.44278E-04 -4.3538 0.17966E+00 -0.7455 138 HSO4- 0.81128E-02 -2.0908 0.16640E-02 -2.7789 0.20510E+00 -0.6880 140 S2O3-2 0.48898E-06 -6.3107 0.10957E-08 -8.9603 0.22409E-02 -2.6496 141 HS2O3- 0.36880E-06 -6.4332 0.66258E-07 -7.1788 0.17966E+00 -0.7455 142 H2S2O3,aq 0.33069E-07 -7.4806 0.33069E-07 -7.4806 0.10000E+01 0.0000 150 S4O6-2 0.41669E-09 -9.3802 0.93377E-12 -12.0298 0.22409E-02 -2.6496 152 ZnCl+ 0.15156E-03 -3.8194 0.30260E-04 -4.5191 0.19966E+00 -0.6997 153 ZnCl2,aq 0.62347E-03 -3.2052 0.62347E-03 -3.2052 0.10000E+01 0.0000 154 ZnCl3- 0.44469E-04 -4.3519 0.79895E-05 -5.0975 0.17966E+00 -0.7455 155 ZnO,aq 0.28884E-07 -7.5393 0.28884E-07 -7.5393 0.10000E+01 0.0000 156 ZnOH+ 0.10414E-05 -5.9824 0.20791E-06 -6.6821 0.19966E+00 -0.6997 158 HZnO2- 0.21492E-09 -9.6677 0.38613E-10 -10.4133 0.17966E+00 -0.7455 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4766512E-05 0.4295341E+01 0.3541810E+04 0.0000 2 H2O 0.1000000E+01 0.5252015E+02 0.7740345E+06 0.0000 3 Cl- 0.1264775E+00 0.6560169E+00 0.1902659E+05 4.3561 4 SO4-- 0.2288736E-03 0.2516581E+00 0.1977669E+05 5.7426 5 HCO3- 0.9719700E-05 0.2674689E+01 0.1335114E+06 0.2735 6 HS- 0.1161866E-03 0.1156587E+01 0.3129188E+05 1.3228 7 H4SiO4 0.5075149E-01 0.5075478E-01 0.3990826E+04 -1.2946 8 Al+++ 0.1742980E-16 0.1164489E-04 0.2570362E+00 -4.7494 9 Ca++ 0.1215093E-05 0.1538610E-03 0.5044607E+01 3.3724 10 Mg++ 0.1230516E-05 0.1502735E-04 0.2988793E+00 3.2939 11 Fe++ 0.1244102E-07 0.3033005E-02 0.1385689E+03 1.3200 12 K+ 0.3568389E-01 0.1255995E+00 0.4017720E+04 3.8486 13 Na+ 0.1132776E+00 0.5584781E+00 0.1050350E+05 4.3130 14 Mn++ 0.1086203E-05 0.1157355E-02 0.5201545E+02 3.2766 15 Zn++ 0.3124650E-09 0.8205740E-03 0.4388227E+02 -0.2801 16 Cu+ 0.1362641E-07 0.9389061E-04 0.4880477E+01 -2.6079 17 Pb++ 0.2657247E-08 0.3425518E-03 0.5806145E+02 0.7612 18 Ag+ 0.2993410E-09 0.8761694E-05 0.7731818E+00 -4.2345 19 Ba++ 0.6393246E-07 0.8724667E-05 0.9802544E+00 2.1734 20 HPO4-- 0.1282181E-08 0.3096409E-05 0.2431237E+00 0.4931 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265509E+01 -.3146595E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5215538E+02 -.1906048E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2499103E+00 0.1812515E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1148554E+01 0.1158974E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.5040228E-01 0.9319204E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1156401E-04 0.6829755E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1527924E-03 0.3751175E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1492298E-04 0.5753675E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.3011940E-02 0.5754814E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247272E+00 0.6829755E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149317E-02 0.1831077E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.8148749E-03 0.1484460E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.9323852E-04 0.3063712E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.8664072E-05 0.4670838E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3074903E-05 0.5492597E-05 0.0000000E+00 Chg. balance for solid moles: 0.1345E-17 Mass of aqueous solution: 0.121389E+04 g Temperature = 562.00 C Pressure = 1091.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3660E-03 -3.437 0.4982E-01 -1.303 0.7569 0.1681E-01 annite 0.7514E-06 -6.124 0.3847E-03 -3.415 0.5844E-02 0.1160E-03 phlogopite 0.1918E-05 -5.717 0.8003E-03 -3.097 0.1216E-01 0.2870E-03 biotite-Mn 0.6104E-07 -7.214 0.3108E-04 -4.508 0.4721E-03 0.9316E-05 apatite-OH 0.1831E-05 -5.737 0.9197E-03 -3.036 0.1397E-01 0.2922E-03 microcline 0.6802E-03 -3.167 0.1893 -0.723 2.876 0.7396E-01 pyrite 0.5446E-02 -2.264 0.6534 -0.185 9.927 0.1304 quartz 0.9114E-01 -1.040 5.476 0.738 83.19 2.068 barite 0.4671E-04 -4.331 0.1090E-01 -1.963 0.1656 0.2433E-02 chalcopyrite 0.3064E-03 -3.514 0.5622E-01 -1.250 0.8541 0.1312E-01 sphalerite 0.1484E-02 -2.828 0.1446 -0.840 2.197 0.3537E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2752E+00 0.2752E+00 1.0000 -0.560 phlogopite 0.7024E+00 0.7024E+00 1.0000 -0.153 biotite-Mn 0.2235E-01 0.2235E-01 1.0000 -1.651 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.582361 g Volume = 2.340711 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.88 -14.88 0.00 0.000 0.00000E+00 24 annite 0.86 0.86 0.00 0.000 -0.16971E-10 25 phlogopite 5.56 5.56 0.00 0.000 -0.33942E-11 26 biotite-Mn 10.00 10.00 0.00 0.000 0.13577E-10 30 apatite-OH -53.66 -53.66 0.00 0.000 0.00000E+00 115 microcline -4.78 -4.78 0.00 0.000 0.23759E-10 140 pyrite -21.93 -21.93 0.00 0.000 -0.13577E-10 144 quartz -1.29 -1.29 0.00 0.000 0.00000E+00 237 barite -16.08 -16.08 0.00 0.000 0.00000E+00 240 chalcopyrite -23.59 -23.59 0.00 0.000 0.00000E+00 255 sphalerite -10.96 -10.96 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 0.00 -0.27 -0.265 0.10139E+04 2.772 2 CO2,gas -10.04 -11.72 -1.68 -0.561 0.64323E+04 1.355 3 CH4,gas 6.85 -4.15 -11.00 -2.750 0.42033E+05 -7.961 4 H2,gas 5.96 1.89 -4.07 -2.327 0.15559E+05 -1.034 5 H2S,gas -8.37 -10.68 -2.31 -1.156 0.88320E+04 0.727 6 CO,gas -3.82 -9.83 -6.01 -1.850 0.22981E+05 -2.976 7 SO3,gas -7.61 -18.25 -10.65 -2.662 0.40697E+05 -7.612 8 O2,gas 16.84 -3.79 -20.63 -13.756 0.78853E+05 -17.596 9 HCl,gas -6.14 -7.64 -1.51 -0.753 0.57538E+04 -1.506 10 acmite 3.62 2.10 -1.52 -0.158 0.58043E+04 12 akimotoite 6.21 2.00 -4.21 -0.843 0.16103E+05 13 akimotoite-Fe 4.08 0.03 -4.05 -0.811 0.15494E+05 14 albite-high -4.17 -4.31 -0.14 -0.011 0.53535E+03 15 albite -4.17 -4.31 -0.15 -0.011 0.55434E+03 16 almandine -7.45 -9.42 -1.97 -0.098 0.75222E+04 17 pyrope -0.70 -3.50 -2.80 -0.140 0.10707E+05 18 analcite -2.04 -3.02 -0.98 -0.109 0.37583E+04 19 andalusite -10.20 -10.79 -0.60 -0.060 0.22831E+04 20 andradite 11.91 6.98 -4.93 -0.256 0.18859E+05 27 anorthite -7.87 -8.72 -0.84 -0.065 0.32160E+04 28 anthophyllite 14.89 12.71 -2.18 -0.059 0.83342E+04 29 anthophyllite-Fe 2.01 -1.11 -3.12 -0.084 0.11916E+05 31 apatite-OH-zs -51.47 -53.66 -2.18 -0.168 0.83487E+04 32 apatite-Cl-zs -58.04 -61.30 -3.26 -0.271 0.12441E+05 33 aragonite -4.68 -8.35 -3.68 -1.225 0.14046E+05 34 brucite 5.55 3.29 -2.26 -0.451 0.86229E+04 35 calcite -4.78 -8.35 -3.57 -1.190 0.13643E+05 36 carnegieite-low 0.06 -1.73 -1.79 -0.256 0.68401E+04 37 carnegieite-high 0.14 -1.73 -1.87 -0.267 0.71539E+04 38 carpholite-Mg -6.70 -8.80 -2.10 -0.140 0.80114E+04 39 carpholite-Fe -8.08 -10.77 -2.69 -0.179 0.10268E+05 40 celadonite -0.68 -2.78 -2.10 -0.124 0.80279E+04 41 celadonite-Fe -2.11 -4.75 -2.64 -0.156 0.10106E+05 42 chrysotile 9.68 7.29 -2.39 -0.199 0.91313E+04 44 clinochlore 4.52 3.08 -1.44 -0.045 0.54959E+04 45 daphnite -2.69 -6.79 -4.10 -0.128 0.15667E+05 47 chlorite-Al-free 19.54 14.58 -4.95 -0.206 0.18927E+05 48 chloritoid-Mg -6.09 -7.50 -1.41 -0.094 0.54027E+04 49 chloritoid-Fe -8.07 -9.48 -1.41 -0.094 0.53864E+04 50 chloritoid-Mn -5.92 -7.52 -1.60 -0.107 0.61097E+04 52 coesite -1.00 -1.29 -0.29 -0.097 0.11154E+04 53 cordierite-H -17.84 -18.88 -1.05 -0.037 0.39956E+04 54 cordierite-Fe -20.48 -22.83 -2.34 -0.081 0.89583E+04 55 cordierite-Mn -16.12 -18.91 -2.79 -0.096 0.10678E+05 56 corundum -8.73 -9.50 -0.77 -0.070 0.29592E+04 58 cristobalite -1.24 -1.29 -0.05 -0.016 0.18131E+03 59 cummingtonite 14.96 12.71 -2.25 -0.061 0.85930E+04 61 cymrite-K -2.46 -4.78 -2.32 -0.194 0.88748E+04 63 diaspore -3.87 -4.75 -0.88 -0.147 0.33766E+04 65 diopside 5.47 4.08 -1.39 -0.139 0.53222E+04 66 hedenbergite 4.02 2.11 -1.92 -0.192 0.73207E+04 68 eastonite -5.01 -6.41 -1.40 -0.054 0.53498E+04 69 enstatite 4.87 4.00 -0.86 -0.086 0.33022E+04 70 clinoenstatite-HiP 5.36 4.00 -1.36 -0.136 0.52091E+04 71 clinoenstatite 4.85 4.00 -0.85 -0.085 0.32372E+04 72 protoenstatite 5.00 4.00 -1.00 -0.100 0.38109E+04 73 epidote -3.83 -6.27 -2.43 -0.118 0.92976E+04 74 clinozoisite -8.51 -11.39 -2.88 -0.131 0.11016E+05 75 epidote-Fe 2.53 -1.14 -3.68 -0.191 0.14053E+05 76 fayalite 2.42 1.35 -1.07 -0.153 0.40922E+04 77 ferrosilite 1.22 0.05 -1.17 -0.117 0.44698E+04 78 forsterite 6.48 5.29 -1.18 -0.169 0.45194E+04 79 gedrite -8.02 -10.30 -2.28 -0.061 0.86944E+04 81 gibbsite -2.24 -4.75 -2.51 -0.359 0.96078E+04 82 glaucophane 1.73 -1.34 -3.07 -0.083 0.11720E+05 83 glaucophane-Fe -2.41 -7.26 -4.85 -0.131 0.18541E+05 84 goethite 1.24 0.37 -0.87 -0.188 0.33181E+04 86 greenalite 4.71 1.37 -3.34 -0.279 0.12776E+05 87 grunerite 2.57 -1.11 -3.68 -0.099 0.14062E+05 88 halite -1.29 -3.33 -2.04 -1.018 0.77843E+04 89 hematite 0.93 0.74 -0.19 -0.023 0.71957E+03 90 heulandite -11.95 -15.18 -3.24 -0.147 0.12370E+05 91 hercynite -6.90 -8.18 -1.28 -0.086 0.49084E+04 94 jadeite -1.36 -3.02 -1.67 -0.167 0.63653E+04 96 kalsilite -0.56 -2.20 -1.63 -0.233 0.62330E+04 97 kaolinite -9.27 -12.09 -2.82 -0.256 0.10777E+05 98 kyanite -10.03 -10.79 -0.76 -0.076 0.29107E+04 100 laumontite -7.58 -11.30 -3.73 -0.248 0.14238E+05 101 lawsonite -5.10 -8.72 -3.62 -0.241 0.13820E+05 102 leucite -2.52 -3.49 -0.97 -0.097 0.37008E+04 104 lizardite 9.85 7.29 -2.56 -0.213 0.97755E+04 105 magnesite -5.50 -8.43 -2.93 -0.978 0.11209E+05 106 magnetite 2.24 2.06 -0.18 -0.014 0.66990E+03 107 minnesotaite 0.87 -1.21 -2.08 -0.123 0.79592E+04 108 minnesotaite-Mg 6.94 4.71 -2.23 -0.131 0.85183E+04 109 magnesioferrite 5.35 4.03 -1.31 -0.107 0.50123E+04 111 manganosite 5.49 3.28 -2.21 -0.553 0.84526E+04 112 margarite -16.14 -18.22 -2.08 -0.083 0.79419E+04 116 monticellite 8.93 5.37 -3.56 -0.509 0.13611E+05 118 mullite-Si -9.44 -10.79 -1.35 -0.135 0.51717E+04 119 muscovite -13.38 -14.28 -0.91 -0.053 0.34628E+04 120 paragonite -12.69 -13.82 -1.13 -0.066 0.43026E+04 121 nepheline -0.24 -1.73 -1.49 -0.213 0.56918E+04 122 osumilite(2) -12.68 -14.74 -2.06 -0.043 0.78778E+04 123 osumilite-Fe -27.44 -30.19 -2.75 -0.057 0.10492E+05 124 pargasite 6.36 2.22 -4.14 -0.109 0.15809E+05 125 periclase 5.75 3.29 -2.46 -0.614 0.93834E+04 126 periclase-Fe 3.14 1.32 -1.82 -0.454 0.69467E+04 127 perovskite-Al -6.99 -9.50 -2.52 -0.229 0.96220E+04 132 phlogopite-Na 6.43 5.56 -0.87 -0.048 0.33272E+04 134 prehnite -3.16 -6.64 -3.48 -0.204 0.13285E+05 135 prehnite-Fe 1.91 -1.51 -3.42 -0.206 0.13077E+05 138 px-Mg-tschermaks -5.47 -7.50 -2.03 -0.145 0.77617E+04 139 px-Ca-tschermaks -4.68 -7.42 -2.74 -0.196 0.10487E+05 141 pyrrhotite -8.68 -9.36 -0.68 -0.225 0.25838E+04 142 pyrrhotiteFe0.875 -9.47 -9.76 -0.29 -0.106 0.11059E+04 143 pyrophyllite -13.20 -14.67 -1.47 -0.092 0.56099E+04 146 riebeckite 5.84 2.99 -2.85 -0.079 0.10904E+05 147 ringwoodite-Fe 3.42 1.35 -2.07 -0.296 0.79146E+04 148 ringwoodite-Mg 9.65 5.29 -4.35 -0.622 0.16642E+05 149 rhodochrosite -5.49 -8.45 -2.95 -0.985 0.11290E+05 150 rhodonite 2.56 1.98 -0.58 -0.116 0.22078E+04 151 sanidine -4.24 -4.78 -0.54 -0.042 0.20664E+04 153 siderite -7.37 -10.41 -3.04 -1.013 0.11611E+05 154 sillimanite -10.16 -10.79 -0.63 -0.063 0.24259E+04 156 spinel -4.70 -6.21 -1.51 -0.101 0.57819E+04 163 stilpnomelane-Mg 0.70 -1.46 -2.16 -0.064 0.82386E+04 164 stishovite 1.68 -1.29 -2.97 -0.991 0.11356E+05 165 sudoite-Fe -15.74 -20.25 -4.51 -0.146 0.17251E+05 166 sudoite -13.46 -16.30 -2.84 -0.092 0.10846E+05 167 sulfur -11.07 -12.57 -1.50 -0.461 0.57206E+04 168 sylvite -1.20 -3.79 -2.60 -1.298 0.99208E+04 169 talc 5.20 4.71 -0.49 -0.029 0.18815E+04 170 talc-Fe 2.28 -1.21 -3.50 -0.206 0.13358E+05 171 talc-tschermaks -5.06 -6.79 -1.74 -0.102 0.66370E+04 173 tephroite 6.68 5.26 -1.42 -0.203 0.54387E+04 176 topaz-H -8.10 -10.80 -2.70 -0.245 0.10299E+05 177 tremolite 15.50 12.87 -2.63 -0.071 0.10064E+05 179 troilite-low -8.59 -9.36 -0.77 -0.256 0.29335E+04 180 tschermakite -6.63 -10.14 -3.51 -0.095 0.13400E+05 183 wadsleyite-Fe 3.27 1.35 -1.92 -0.275 0.73559E+04 184 wadsleyite-Mg 8.70 5.29 -3.41 -0.487 0.13027E+05 185 wairakite -9.45 -11.30 -1.85 -0.109 0.70606E+04 186 walstromite 4.64 2.08 -2.56 -0.511 0.97716E+04 187 wollastonite 4.21 2.08 -2.13 -0.427 0.81504E+04 188 pseudo-wollastonite 4.33 2.08 -2.25 -0.450 0.86019E+04 189 zoisite -8.56 -11.39 -2.83 -0.129 0.10819E+05 192 beidellite-Ca -13.43 -15.26 -1.83 -0.113 0.69833E+04 193 beidellite-H -13.46 -15.81 -2.35 -0.150 0.89858E+04 194 beidellite-K -12.42 -14.54 -2.13 -0.130 0.81282E+04 195 beidellite-Mg -13.68 -15.27 -1.59 -0.098 0.60644E+04 196 beidellite-Na -12.36 -14.39 -2.03 -0.124 0.77654E+04 197 bornite -55.02 -55.37 -0.35 -0.026 0.13319E+04 199 chalcocite -14.40 -15.89 -1.49 -0.372 0.56932E+04 200 covellite -12.85 -14.23 -1.38 -0.526 0.52723E+04 202 montmorillonite-Ca -10.10 -11.46 -1.36 -0.084 0.52116E+04 203 montmorillonite-K -9.36 -10.75 -1.38 -0.085 0.52839E+04 204 montmorillonite-Mg -10.31 -11.47 -1.16 -0.072 0.44435E+04 205 montmorillonite-Na -9.03 -10.59 -1.57 -0.096 0.59857E+04 206 nontronite-Ca -3.51 -5.01 -1.50 -0.097 0.57404E+04 207 nontronite-H -3.55 -5.57 -2.02 -0.135 0.77133E+04 208 nontronite-K -2.50 -4.30 -1.80 -0.116 0.68773E+04 209 nontronite-Mg -3.73 -5.02 -1.30 -0.084 0.49543E+04 210 nontronite-Na -2.44 -4.14 -1.71 -0.110 0.65265E+04 215 gypsum -12.63 -14.89 -2.25 -0.563 0.86106E+04 232 alabandite -6.41 -7.40 -0.99 -0.331 0.37934E+04 234 anglesite -15.17 -17.49 -2.33 -1.164 0.88959E+04 238 boehmite -3.57 -4.75 -1.18 -0.196 0.45037E+04 242 copper,native 1.73 -1.66 -3.39 -1.178 0.12943E+05 244 ferrous-oxide 2.21 1.32 -0.89 -0.222 0.33915E+04 245 galena -9.90 -9.92 -0.02 -0.007 0.76861E+02 246 silver,native 0.45 -3.29 -3.73 -1.299 0.14270E+05 248 litharge 5.35 0.76 -4.59 -1.147 0.17529E+05 256 wurtzite -10.15 -10.96 -0.81 -0.269 0.30876E+04 257 zincite 2.29 -0.28 -2.57 -0.644 0.98384E+04 258 an20ab80 -5.13 -5.19 -0.07 -0.005 0.25609E+03 259 an25ab75 -5.34 -5.41 -0.08 -0.006 0.28744E+03 260 an30ab70 -5.55 -5.63 -0.09 -0.007 0.34000E+03 261 tr.625ac.25prg.125 10.14 9.07 -1.07 -0.029 0.40937E+04 Calculations done for 562.0000 Deg. C; 1091.0000 bar Temperature changed by -1.000 degrees to 561.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 35 Loop limit = 500 Temperature = 561.00 C Pressure = 1077.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5512E+02 kg liquid = 0.9931E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9968 Stoichiometric ionic strength = .3275950E+01 Osmotic coef. = 0.0000 True ionic strength = .1487310E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.46841E-05 -5.3294 0.97832E-06 -6.0095 0.20886E+00 -0.6801 2 H2O 0.99679E+00 -0.0014 0.99679E+00 -0.0014 3 Cl- 0.12483E+00 -0.9037 0.22288E-01 -1.6519 0.17855E+00 -0.7482 4 SO4-- 0.23086E-03 -3.6366 0.54625E-06 -6.2626 0.23661E-02 -2.6260 5 HCO3- 0.94587E-05 -5.0242 0.18165E-05 -5.7408 0.19205E+00 -0.7166 6 HS- 0.11513E-03 -3.9388 0.20723E-04 -4.6836 0.18000E+00 -0.7447 7 H4SiO4 0.49831E-01 -1.3025 0.49831E-01 -1.3025 0.10000E+01 0.0000 8 Al+++ 0.18496E-16 -16.7329 0.18023E-22 -22.7442 0.97443E-06 -6.0113 9 Ca++ 0.11966E-05 -5.9221 0.22743E-08 -8.6431 0.19007E-02 -2.7211 10 Mg++ 0.12618E-05 -5.8990 0.19772E-08 -8.7039 0.15671E-02 -2.8049 11 Fe++ 0.12308E-07 -7.9098 0.20252E-10 -10.6935 0.16455E-02 -2.7837 12 K+ 0.35287E-01 -1.4524 0.69390E-02 -2.1587 0.19665E+00 -0.7063 13 Na+ 0.11178E+00 -0.9517 0.20175E-01 -1.6952 0.18050E+00 -0.7435 14 Mn++ 0.11152E-05 -5.9527 0.19018E-08 -8.7208 0.17054E-02 -2.7682 15 Zn++ 0.31094E-09 -9.5073 0.51167E-12 -12.2910 0.16455E-02 -2.7837 16 Cu+ 0.13243E-07 -7.8780 0.23842E-08 -8.6227 0.18003E+00 -0.7447 17 Pb++ 0.26413E-08 -8.5782 0.56177E-11 -11.2504 0.21269E-02 -2.6722 18 Ag+ 0.29889E-09 -9.5245 0.57868E-10 -10.2376 0.19361E+00 -0.7131 19 Ba++ 0.62106E-07 -7.2069 0.14185E-09 -9.8482 0.22840E-02 -2.6413 20 HPO4-- 0.13080E-08 -8.8834 0.31104E-11 -11.5072 0.23780E-02 -2.6238 21 HSiO3- 0.13719E-05 -5.8627 0.24495E-06 -6.6109 0.17855E+00 -0.7482 22 Ca(HSiO3)+ 0.45295E-08 -8.3440 0.89848E-09 -9.0465 0.19836E+00 -0.7025 23 Mg(HSiO3)+ 0.12526E-08 -8.9022 0.24846E-09 -9.6047 0.19836E+00 -0.7025 24 NaHSiO3,aq 0.19002E-05 -5.7212 0.19002E-05 -5.7212 0.10000E+01 0.0000 28 AgCl,aq 0.11745E-06 -6.9302 0.11745E-06 -6.9302 0.10000E+01 0.0000 29 AgCl2- 0.53485E-05 -5.2718 0.95495E-06 -6.0200 0.17855E+00 -0.7482 30 AgCl3-2 0.17632E-05 -5.7537 0.38643E-08 -8.4129 0.21916E-02 -2.6592 31 AgCl4-3 0.15232E-05 -5.8172 0.13031E-11 -11.8850 0.85550E-06 -6.0678 34 Ag(HS),aq 0.19088E-08 -8.7192 0.19088E-08 -8.7192 0.10000E+01 0.0000 35 Ag(HS)2- 0.68846E-08 -8.1621 0.12292E-08 -8.9104 0.17855E+00 -0.7482 38 HAlO2,aq 0.40882E-08 -8.3885 0.40882E-08 -8.3885 0.10000E+01 0.0000 39 AlO2- 0.11406E-04 -4.9429 0.17917E-05 -5.7467 0.15709E+00 -0.8039 41 Ba(HCO3)+ 0.20867E-06 -6.6805 0.43054E-07 -7.3660 0.20632E+00 -0.6855 42 BaCl+ 0.81051E-05 -5.0912 0.16077E-05 -5.7938 0.19836E+00 -0.7025 43 CH4,aq 0.15065E-08 -8.8220 0.17889E-08 -8.7474 0.11875E+01 0.0746 48 CO,aq 0.51724E-03 -3.2863 0.51724E-03 -3.2863 0.10000E+01 0.0000 49 CO2,aq 0.26741E+01 0.4272 0.31755E+01 0.5018 0.11875E+01 0.0746 50 CO3-2 0.37054E-10 -10.4312 0.81208E-13 -13.0904 0.21916E-02 -2.6592 52 Ca(HCO3)+ 0.10000E-06 -7.0000 0.19837E-07 -7.7025 0.19836E+00 -0.7025 53 CaCl+ 0.72357E-04 -4.1405 0.14353E-04 -4.8431 0.19836E+00 -0.7025 54 CaCl2,aq 0.76136E-04 -4.1184 0.76136E-04 -4.1184 0.10000E+01 0.0000 55 CaOH+ 0.13821E-06 -6.8595 0.27415E-07 -7.5620 0.19836E+00 -0.7025 56 CaSO4,aq 0.16791E-06 -6.7749 0.16791E-06 -6.7749 0.10000E+01 0.0000 57 HCl,aq 0.31283E-02 -2.5047 0.31283E-02 -2.5047 0.10000E+01 0.0000 66 CuCl,aq 0.21166E-04 -4.6744 0.21166E-04 -4.6744 0.10000E+01 0.0000 67 CuCl2- 0.70210E-04 -4.1536 0.12536E-04 -4.9018 0.17855E+00 -0.7482 68 CuCl3-2 0.12617E-05 -5.8991 0.27651E-08 -8.5583 0.21916E-02 -2.6592 74 FeCl+ 0.23175E-06 -6.6350 0.45970E-07 -7.3375 0.19836E+00 -0.7025 75 FeCl2,aq 0.29179E-02 -2.5349 0.29179E-02 -2.5349 0.10000E+01 0.0000 77 FeO,aq 0.58850E-07 -7.2303 0.58850E-07 -7.2303 0.10000E+01 0.0000 78 FeOH+ 0.19682E-07 -7.7059 0.39042E-08 -8.4085 0.19836E+00 -0.7025 79 HFeO2- 0.66235E-08 -8.1789 0.11826E-08 -8.9272 0.17855E+00 -0.7482 82 FeO2- 0.41289E-08 -8.3842 0.73721E-09 -9.1324 0.17855E+00 -0.7482 83 HFeO2,aq 0.28293E-09 -9.5483 0.28293E-09 -9.5483 0.10000E+01 0.0000 84 H2,aq 0.45168E-02 -2.3452 0.53637E-02 -2.2705 0.11875E+01 0.0746 85 KCl,aq 0.71908E-01 -1.1432 0.71908E-01 -1.1432 0.10000E+01 0.0000 86 KHSO4,aq 0.13671E-01 -1.8642 0.13671E-01 -1.8642 0.10000E+01 0.0000 87 KOH,aq 0.13875E-05 -5.8578 0.13875E-05 -5.8578 0.10000E+01 0.0000 88 KSO4- 0.47290E-02 -2.3252 0.84435E-03 -3.0735 0.17855E+00 -0.7482 90 Mg(HCO3)+ 0.29618E-07 -7.5284 0.58751E-08 -8.2310 0.19836E+00 -0.7025 91 MgCl+ 0.13433E-04 -4.8718 0.26647E-05 -5.5744 0.19836E+00 -0.7025 92 MgOH+ 0.51709E-06 -6.2864 0.10257E-06 -6.9890 0.19836E+00 -0.7025 94 MnO,aq 0.93844E-07 -7.0276 0.93844E-07 -7.0276 0.10000E+01 0.0000 95 MnOH+ 0.20417E-06 -6.6900 0.40499E-07 -7.3926 0.19836E+00 -0.7025 97 HMnO2- 0.42092E-10 -10.3758 0.75155E-11 -11.1240 0.17855E+00 -0.7482 100 MnCl+ 0.11558E-02 -2.9371 0.22926E-03 -3.6397 0.19836E+00 -0.7025 101 MnSO4,aq 0.15284E-06 -6.8158 0.15284E-06 -6.8158 0.10000E+01 0.0000 102 NaCl,aq 0.44668E+00 -0.3500 0.44668E+00 -0.3500 0.10000E+01 0.0000 103 NaOH,aq 0.18461E-05 -5.7338 0.18461E-05 -5.7338 0.10000E+01 0.0000 105 OH- 0.73141E-05 -5.1358 0.11490E-05 -5.9397 0.15709E+00 -0.8039 111 H3PO3,aq 0.11446E-09 -9.9413 0.11446E-09 -9.9413 0.10000E+01 0.0000 112 H2PO3- 0.18796E-08 -8.7259 0.33559E-09 -9.4742 0.17855E+00 -0.7482 113 H3PO4,aq 0.13259E-05 -5.8775 0.13259E-05 -5.8775 0.10000E+01 0.0000 114 H2PO4- 0.13598E-05 -5.8665 0.25497E-06 -6.5935 0.18751E+00 -0.7270 116 H4P2O7,aq 0.16391E-09 -9.7854 0.16391E-09 -9.7854 0.10000E+01 0.0000 117 H3P2O7- 0.86386E-09 -9.0636 0.15424E-09 -9.8118 0.17855E+00 -0.7482 118 H2P2O7-2 0.20839E-06 -6.6811 0.45671E-09 -9.3404 0.21916E-02 -2.6592 119 HP2O7-3 0.21798E-07 -7.6616 0.18648E-13 -13.7294 0.85550E-06 -6.0678 121 PbCl+ 0.12229E-05 -5.9126 0.24258E-06 -6.6151 0.19836E+00 -0.7025 122 PbCl2,aq 0.86537E-04 -4.0628 0.86537E-04 -4.0628 0.10000E+01 0.0000 123 PbCl3- 0.97783E-04 -4.0097 0.17459E-04 -4.7580 0.17855E+00 -0.7482 124 PbCl4-2 0.16374E-04 -4.7858 0.35886E-07 -7.4451 0.21916E-02 -2.6592 125 PbO,aq 0.67038E-08 -8.1737 0.67038E-08 -8.1737 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12676E-03 -3.8970 0.12676E-03 -3.8970 0.10000E+01 0.0000 128 Pb(HS)3- 0.13852E-04 -4.8585 0.24732E-05 -5.6067 0.17855E+00 -0.7482 129 H2S,aq 0.10582E+01 0.0246 0.12566E+01 0.0992 0.11875E+01 0.0746 130 S2-2 0.11856E-07 -7.9261 0.25984E-10 -10.5853 0.21916E-02 -2.6592 131 S3-2 0.10970E-08 -8.9598 0.24042E-11 -11.6190 0.21916E-02 -2.6592 132 S3- 0.97382E-02 -2.0115 0.17387E-02 -2.7598 0.17855E+00 -0.7482 133 S4-2 0.86201E-10 -10.0645 0.18892E-12 -12.7237 0.21916E-02 -2.6592 135 SO2,aq 0.29323E+00 -0.5328 0.29323E+00 -0.5328 0.10000E+01 0.0000 136 SO3-2 0.62464E-09 -9.2044 0.21664E-11 -11.6643 0.34682E-02 -2.4599 137 HSO3- 0.24224E-03 -3.6158 0.43252E-04 -4.3640 0.17855E+00 -0.7482 138 HSO4- 0.80511E-02 -2.0941 0.16406E-02 -2.7850 0.20377E+00 -0.6908 140 S2O3-2 0.48889E-06 -6.3108 0.10715E-08 -8.9700 0.21916E-02 -2.6592 141 HS2O3- 0.36416E-06 -6.4387 0.65020E-07 -7.1870 0.17855E+00 -0.7482 142 H2S2O3,aq 0.33706E-07 -7.4723 0.33706E-07 -7.4723 0.10000E+01 0.0000 150 S4O6-2 0.41609E-09 -9.3808 0.91192E-12 -12.0400 0.21916E-02 -2.6592 152 ZnCl+ 0.14593E-03 -3.8358 0.28948E-04 -4.5384 0.19836E+00 -0.7025 153 ZnCl2,aq 0.60965E-03 -3.2149 0.60965E-03 -3.2149 0.10000E+01 0.0000 154 ZnCl3- 0.42568E-04 -4.3709 0.76004E-05 -5.1192 0.17855E+00 -0.7482 155 ZnO,aq 0.28381E-07 -7.5470 0.28381E-07 -7.5470 0.10000E+01 0.0000 156 ZnOH+ 0.10077E-05 -5.9967 0.19989E-06 -6.6992 0.19836E+00 -0.7025 158 HZnO2- 0.20858E-09 -9.6807 0.37242E-10 -10.4290 0.17855E+00 -0.7482 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4684077E-05 0.4295214E+01 0.3542013E+04 0.0000 2 H2O 0.1000000E+01 0.5252061E+02 0.7741087E+06 0.0000 3 Cl- 0.1248272E+00 0.6559983E+00 0.1902770E+05 4.3576 4 SO4-- 0.2308640E-03 0.2516182E+00 0.1977528E+05 5.7564 5 HCO3- 0.9458692E-05 0.2674614E+01 0.1335193E+06 0.2688 6 HS- 0.1151276E-03 0.1156332E+01 0.3128770E+05 1.3260 7 H4SiO4 0.4983129E-01 0.4983457E-01 0.3918811E+04 -1.3025 8 Al+++ 0.1849648E-16 0.1140968E-04 0.2518664E+00 -4.7156 9 Ca++ 0.1196599E-05 0.1501005E-03 0.4921743E+01 3.3759 10 Mg++ 0.1261761E-05 0.1524315E-04 0.3031978E+00 3.3151 11 Fe++ 0.1230755E-07 0.2918251E-02 0.1333378E+03 1.3255 12 K+ 0.3528671E-01 0.1255957E+00 0.4017948E+04 3.8508 13 Na+ 0.1117750E+00 0.5584623E+00 0.1050412E+05 4.3143 14 Mn++ 0.1115185E-05 0.1157328E-02 0.5201876E+02 3.2982 15 Zn++ 0.3109429E-09 0.7991877E-03 0.4274230E+02 -0.2720 16 Cu+ 0.1324345E-07 0.9265077E-04 0.4816448E+01 -2.6131 17 Pb++ 0.2641263E-08 0.3425421E-03 0.5806486E+02 0.7686 18 Ag+ 0.2988874E-09 0.8761446E-05 0.7732272E+00 -4.2280 19 Ba++ 0.6210607E-07 0.8375908E-05 0.9411516E+00 2.1709 20 HPO4-- 0.1308012E-08 0.3151410E-05 0.2474638E+00 0.5119 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265503E+01 -.3140810E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5215732E+02 -.1925431E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2498777E+00 0.1845035E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1148333E+01 0.1181064E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4948985E-01 0.9410447E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1133076E-04 0.6832088E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1490623E-03 0.3788476E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1513771E-04 0.5538944E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2898065E-02 0.5868689E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247269E+00 0.6832088E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149323E-02 0.1773122E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7936596E-03 0.1505675E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.9200989E-04 0.3075998E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.8317971E-05 0.4705448E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3129611E-05 0.5437889E-05 0.0000000E+00 Chg. balance for solid moles: -.2285E-17 Mass of aqueous solution: 0.121382E+04 g Temperature = 561.00 C Pressure = 1077.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3698E-03 -3.432 0.5034E-01 -1.298 0.7566 0.1699E-01 annite 0.7020E-06 -6.154 0.3594E-03 -3.444 0.5401E-02 0.1083E-03 phlogopite 0.1846E-05 -5.734 0.7704E-03 -3.113 0.1158E-01 0.2762E-03 biotite-Mn 0.5910E-07 -7.228 0.3009E-04 -4.522 0.4523E-03 0.9021E-05 apatite-OH 0.1813E-05 -5.742 0.9105E-03 -3.041 0.1368E-01 0.2893E-03 microcline 0.6806E-03 -3.167 0.1894 -0.723 2.847 0.7400E-01 pyrite 0.5559E-02 -2.255 0.6670 -0.176 10.02 0.1331 quartz 0.9205E-01 -1.036 5.531 0.743 83.12 2.089 barite 0.4705E-04 -4.327 0.1098E-01 -1.959 0.1651 0.2451E-02 chalcopyrite 0.3076E-03 -3.512 0.5644E-01 -1.248 0.8483 0.1318E-01 sphalerite 0.1506E-02 -2.822 0.1467 -0.834 2.205 0.3588E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2692E+00 0.2692E+00 1.0000 -0.570 phlogopite 0.7081E+00 0.7081E+00 1.0000 -0.150 biotite-Mn 0.2267E-01 0.2267E-01 1.0000 -1.645 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.653598 g Volume = 2.364866 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.91 -14.91 0.00 0.000 0.00000E+00 24 annite 0.91 0.91 0.00 0.000 0.43648E-10 25 phlogopite 5.62 5.62 0.00 0.000 0.67802E-11 26 biotite-Mn 10.06 10.06 0.00 0.000 0.20341E-10 30 apatite-OH -53.70 -53.70 0.00 0.000 0.27121E-10 115 microcline -4.77 -4.77 0.00 0.000 0.33901E-11 140 pyrite -21.96 -21.96 0.00 0.000 0.00000E+00 144 quartz -1.30 -1.30 0.00 0.000 0.00000E+00 237 barite -16.11 -16.11 0.00 0.000 0.00000E+00 240 chalcopyrite -23.62 -23.62 0.00 0.000 0.00000E+00 255 sphalerite -10.97 -10.97 0.00 0.000 0.67802E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 0.00 -0.26 -0.264 0.10094E+04 2.768 2 CO2,gas -10.06 -11.75 -1.69 -0.562 0.64390E+04 1.345 3 CH4,gas 6.85 -4.16 -11.01 -2.753 0.42025E+05 -7.978 4 H2,gas 5.97 1.90 -4.07 -2.328 0.15548E+05 -1.041 5 H2S,gas -8.38 -10.69 -2.31 -1.155 0.88186E+04 0.722 6 CO,gas -3.83 -9.85 -6.02 -1.853 0.22990E+05 -2.991 7 SO3,gas -7.62 -18.28 -10.66 -2.665 0.40687E+05 -7.627 8 O2,gas 16.87 -3.79 -20.66 -13.773 0.78856E+05 -17.627 9 HCl,gas -6.15 -7.66 -1.52 -0.758 0.57861E+04 -1.516 10 acmite 3.62 2.09 -1.53 -0.159 0.58268E+04 12 akimotoite 6.23 2.01 -4.22 -0.843 0.16092E+05 13 akimotoite-Fe 4.09 0.02 -4.07 -0.814 0.15531E+05 14 albite-high -4.16 -4.30 -0.14 -0.011 0.54496E+03 15 albite -4.16 -4.30 -0.15 -0.011 0.56006E+03 16 almandine -7.35 -9.36 -2.01 -0.100 0.76644E+04 17 pyrope -0.59 -3.39 -2.81 -0.140 0.10710E+05 18 analcite -2.02 -3.00 -0.99 -0.110 0.37649E+04 19 andalusite -10.13 -10.74 -0.61 -0.061 0.23113E+04 20 andradite 11.95 6.98 -4.98 -0.259 0.19000E+05 27 anorthite -7.80 -8.66 -0.86 -0.066 0.32744E+04 28 anthophyllite 14.96 12.80 -2.16 -0.058 0.82467E+04 29 anthophyllite-Fe 2.05 -1.13 -3.18 -0.086 0.12155E+05 31 apatite-OH-zs -51.51 -53.70 -2.19 -0.168 0.83513E+04 32 apatite-Cl-zs -58.10 -61.36 -3.26 -0.272 0.12442E+05 33 aragonite -4.69 -8.37 -3.69 -1.229 0.14072E+05 34 brucite 5.57 3.31 -2.25 -0.451 0.86048E+04 35 calcite -4.79 -8.37 -3.58 -1.194 0.13669E+05 36 carnegieite-low 0.09 -1.70 -1.79 -0.256 0.68451E+04 37 carnegieite-high 0.17 -1.70 -1.88 -0.268 0.71610E+04 38 carpholite-Mg -6.62 -8.72 -2.10 -0.140 0.80132E+04 39 carpholite-Fe -8.01 -10.71 -2.70 -0.180 0.10318E+05 40 celadonite -0.66 -2.75 -2.10 -0.123 0.80103E+04 41 celadonite-Fe -2.09 -4.74 -2.66 -0.156 0.10138E+05 42 chrysotile 9.72 7.34 -2.38 -0.198 0.90787E+04 44 clinochlore 4.65 3.23 -1.42 -0.044 0.54276E+04 45 daphnite -2.57 -6.72 -4.15 -0.130 0.15840E+05 47 chlorite-Al-free 19.61 14.68 -4.93 -0.205 0.18817E+05 48 chloritoid-Mg -6.01 -7.42 -1.42 -0.094 0.54099E+04 49 chloritoid-Fe -7.99 -9.41 -1.42 -0.095 0.54385E+04 50 chloritoid-Mn -5.84 -7.44 -1.60 -0.106 0.60973E+04 52 coesite -1.01 -1.30 -0.29 -0.097 0.11163E+04 53 cordierite-H -17.69 -18.74 -1.06 -0.038 0.40323E+04 54 cordierite-Fe -20.34 -22.72 -2.38 -0.082 0.90836E+04 55 cordierite-Mn -15.98 -18.78 -2.80 -0.096 0.10672E+05 56 corundum -8.65 -9.44 -0.78 -0.071 0.29880E+04 58 cristobalite -1.25 -1.30 -0.05 -0.016 0.18162E+03 59 cummingtonite 15.03 12.80 -2.23 -0.060 0.85062E+04 61 cymrite-K -2.44 -4.77 -2.33 -0.194 0.88789E+04 63 diaspore -3.83 -4.72 -0.89 -0.148 0.33852E+04 65 diopside 5.49 4.09 -1.40 -0.140 0.53389E+04 66 hedenbergite 4.03 2.10 -1.93 -0.193 0.73857E+04 68 eastonite -4.88 -6.28 -1.40 -0.054 0.53480E+04 69 enstatite 4.89 4.03 -0.86 -0.086 0.32802E+04 70 clinoenstatite-HiP 5.39 4.03 -1.36 -0.136 0.51874E+04 71 clinoenstatite 4.87 4.03 -0.84 -0.084 0.32148E+04 72 protoenstatite 5.02 4.03 -0.99 -0.099 0.37892E+04 73 epidote -3.75 -6.21 -2.47 -0.120 0.94092E+04 74 clinozoisite -8.39 -11.30 -2.91 -0.132 0.11112E+05 75 epidote-Fe 2.60 -1.12 -3.71 -0.193 0.14178E+05 76 fayalite 2.44 1.35 -1.09 -0.156 0.41638E+04 77 ferrosilite 1.24 0.05 -1.19 -0.119 0.45424E+04 78 forsterite 6.51 5.33 -1.18 -0.168 0.44958E+04 79 gedrite -7.83 -10.10 -2.28 -0.062 0.86880E+04 81 gibbsite -2.20 -4.72 -2.52 -0.360 0.96119E+04 82 glaucophane 1.79 -1.27 -3.06 -0.083 0.11680E+05 83 glaucophane-Fe -2.35 -7.23 -4.88 -0.132 0.18644E+05 84 goethite 1.25 0.37 -0.88 -0.189 0.33451E+04 86 greenalite 4.74 1.37 -3.37 -0.281 0.12864E+05 87 grunerite 2.62 -1.13 -3.75 -0.101 0.14303E+05 88 halite -1.31 -3.35 -2.04 -1.018 0.77722E+04 89 hematite 0.96 0.75 -0.20 -0.025 0.77884E+03 90 heulandite -11.91 -15.17 -3.26 -0.148 0.12425E+05 91 hercynite -6.81 -8.11 -1.30 -0.087 0.49735E+04 94 jadeite -1.33 -3.00 -1.67 -0.167 0.63691E+04 96 kalsilite -0.53 -2.17 -1.63 -0.233 0.62351E+04 97 kaolinite -9.21 -12.04 -2.82 -0.257 0.10782E+05 98 kyanite -9.96 -10.74 -0.77 -0.077 0.29395E+04 100 laumontite -7.52 -11.27 -3.74 -0.249 0.14280E+05 101 lawsonite -5.03 -8.66 -3.63 -0.242 0.13863E+05 102 leucite -2.50 -3.47 -0.97 -0.097 0.37049E+04 104 lizardite 9.89 7.34 -2.55 -0.212 0.97184E+04 105 magnesite -5.50 -8.44 -2.93 -0.978 0.11195E+05 106 magnetite 2.28 2.08 -0.20 -0.016 0.76520E+03 107 minnesotaite 0.88 -1.23 -2.11 -0.124 0.80541E+04 108 minnesotaite-Mg 6.96 4.74 -2.22 -0.131 0.84706E+04 109 magnesioferrite 5.39 4.06 -1.33 -0.108 0.50604E+04 111 manganosite 5.50 3.30 -2.21 -0.552 0.84231E+04 112 margarite -16.00 -18.10 -2.10 -0.084 0.80198E+04 116 monticellite 8.96 5.39 -3.57 -0.510 0.13626E+05 118 mullite-Si -9.37 -10.74 -1.36 -0.136 0.52027E+04 119 muscovite -13.29 -14.20 -0.91 -0.054 0.34867E+04 120 paragonite -12.61 -13.74 -1.13 -0.067 0.43301E+04 121 nepheline -0.21 -1.70 -1.49 -0.213 0.56960E+04 122 osumilite(2) -12.59 -14.66 -2.06 -0.043 0.78769E+04 123 osumilite-Fe -27.30 -30.09 -2.78 -0.058 0.10625E+05 124 pargasite 6.52 2.36 -4.15 -0.109 0.15856E+05 125 periclase 5.77 3.31 -2.46 -0.614 0.93711E+04 126 periclase-Fe 3.15 1.32 -1.83 -0.457 0.69831E+04 127 perovskite-Al -6.91 -9.44 -2.53 -0.230 0.96512E+04 132 phlogopite-Na 6.50 5.64 -0.86 -0.048 0.32897E+04 134 prehnite -3.09 -6.59 -3.50 -0.206 0.13362E+05 135 prehnite-Fe 1.96 -1.49 -3.45 -0.208 0.13170E+05 138 px-Mg-tschermaks -5.38 -7.42 -2.04 -0.146 0.77817E+04 139 px-Ca-tschermaks -4.60 -7.36 -2.76 -0.197 0.10544E+05 141 pyrrhotite -8.68 -9.37 -0.68 -0.228 0.26065E+04 142 pyrrhotiteFe0.875 -9.47 -9.77 -0.29 -0.108 0.11244E+04 143 pyrophyllite -13.16 -14.64 -1.48 -0.092 0.56310E+04 146 riebeckite 5.84 2.95 -2.89 -0.080 0.11044E+05 147 ringwoodite-Fe 3.44 1.35 -2.09 -0.299 0.79839E+04 148 ringwoodite-Mg 9.68 5.33 -4.35 -0.622 0.16617E+05 149 rhodochrosite -5.50 -8.45 -2.95 -0.983 0.11257E+05 150 rhodonite 2.57 2.00 -0.57 -0.114 0.21790E+04 151 sanidine -4.23 -4.77 -0.54 -0.042 0.20663E+04 153 siderite -7.37 -10.42 -3.05 -1.017 0.11643E+05 154 sillimanite -10.09 -10.74 -0.64 -0.064 0.24554E+04 156 spinel -4.60 -6.12 -1.52 -0.101 0.57986E+04 163 stilpnomelane-Mg 0.79 -1.35 -2.14 -0.064 0.81803E+04 164 stishovite 1.68 -1.30 -2.98 -0.992 0.11355E+05 165 sudoite-Fe -15.58 -20.13 -4.55 -0.147 0.17370E+05 166 sudoite -13.30 -16.15 -2.85 -0.092 0.10870E+05 167 sulfur -11.09 -12.59 -1.50 -0.460 0.57067E+04 168 sylvite -1.22 -3.81 -2.59 -1.297 0.99033E+04 169 talc 5.22 4.74 -0.48 -0.028 0.18348E+04 170 talc-Fe 2.30 -1.23 -3.52 -0.207 0.13454E+05 171 talc-tschermaks -4.97 -6.71 -1.74 -0.102 0.66322E+04 173 tephroite 6.70 5.29 -1.41 -0.201 0.53787E+04 176 topaz-H -8.03 -10.74 -2.70 -0.246 0.10318E+05 177 tremolite 15.55 12.92 -2.63 -0.071 0.10051E+05 179 troilite-low -8.59 -9.37 -0.77 -0.258 0.29548E+04 180 tschermakite -6.45 -9.98 -3.53 -0.095 0.13467E+05 183 wadsleyite-Fe 3.29 1.35 -1.95 -0.278 0.74272E+04 184 wadsleyite-Mg 8.73 5.33 -3.41 -0.487 0.13004E+05 185 wairakite -9.40 -11.26 -1.86 -0.110 0.71074E+04 186 walstromite 4.64 2.07 -2.57 -0.514 0.98000E+04 187 wollastonite 4.22 2.07 -2.14 -0.428 0.81776E+04 188 pseudo-wollastonite 4.34 2.07 -2.26 -0.452 0.86301E+04 189 zoisite -8.44 -11.30 -2.86 -0.130 0.10916E+05 192 beidellite-Ca -13.37 -15.21 -1.84 -0.114 0.70133E+04 193 beidellite-H -13.40 -15.76 -2.36 -0.151 0.90103E+04 194 beidellite-K -12.36 -14.49 -2.13 -0.131 0.81491E+04 195 beidellite-Mg -13.62 -15.22 -1.60 -0.099 0.60896E+04 196 beidellite-Na -12.30 -14.34 -2.04 -0.125 0.77874E+04 197 bornite -55.12 -55.46 -0.34 -0.025 0.12820E+04 199 chalcocite -14.44 -15.92 -1.48 -0.371 0.56655E+04 200 covellite -12.88 -14.25 -1.37 -0.524 0.52468E+04 202 montmorillonite-Ca -10.06 -11.43 -1.37 -0.085 0.52281E+04 203 montmorillonite-K -9.33 -10.71 -1.39 -0.085 0.52942E+04 204 montmorillonite-Mg -10.27 -11.44 -1.17 -0.072 0.44531E+04 205 montmorillonite-Na -8.99 -10.56 -1.57 -0.096 0.59932E+04 206 nontronite-Ca -3.50 -5.02 -1.52 -0.099 0.58032E+04 207 nontronite-H -3.54 -5.58 -2.04 -0.136 0.77704E+04 208 nontronite-K -2.49 -4.31 -1.82 -0.117 0.69310E+04 209 nontronite-Mg -3.72 -5.03 -1.31 -0.085 0.50105E+04 210 nontronite-Na -2.43 -4.15 -1.72 -0.111 0.65812E+04 215 gypsum -12.65 -14.91 -2.26 -0.564 0.86082E+04 231 acanthite -14.17 -19.15 -4.98 -1.244 0.18994E+05 232 alabandite -6.41 -7.39 -0.98 -0.328 0.37532E+04 234 anglesite -15.19 -17.51 -2.32 -1.160 0.88519E+04 238 boehmite -3.54 -4.72 -1.18 -0.197 0.45142E+04 242 copper,native 1.72 -1.67 -3.39 -1.178 0.12930E+05 244 ferrous-oxide 2.22 1.32 -0.90 -0.225 0.34289E+04 245 galena -9.91 -9.92 -0.01 -0.004 0.45154E+02 246 silver,native 0.44 -3.28 -3.72 -1.294 0.14202E+05 248 litharge 5.35 0.77 -4.59 -1.147 0.17507E+05 256 wurtzite -10.16 -10.97 -0.81 -0.270 0.30878E+04 257 zincite 2.31 -0.27 -2.58 -0.645 0.98507E+04 258 an20ab80 -5.10 -5.17 -0.07 -0.006 0.27315E+03 259 an25ab75 -5.31 -5.39 -0.08 -0.006 0.30765E+03 260 an30ab70 -5.52 -5.61 -0.10 -0.007 0.36282E+03 261 tr.625ac.25prg.125 10.20 9.11 -1.09 -0.029 0.41595E+04 Calculations done for 561.0000 Deg. C; 1077.0000 bar Temperature changed by -1.000 degrees to 560.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 35 Loop limit = 500 Temperature = 560.00 C Pressure = 1063.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5513E+02 kg liquid = 0.9931E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9968 Stoichiometric ionic strength = .3275359E+01 Osmotic coef. = 0.0000 True ionic strength = .1468291E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.46019E-05 -5.3371 0.95619E-06 -6.0195 0.20778E+00 -0.6824 2 H2O 0.99681E+00 -0.0014 0.99681E+00 -0.0014 3 Cl- 0.12318E+00 -0.9095 0.21861E-01 -1.6603 0.17748E+00 -0.7509 4 SO4-- 0.23282E-03 -3.6330 0.53906E-06 -6.2684 0.23153E-02 -2.6354 5 HCO3- 0.92044E-05 -5.0360 0.17567E-05 -5.7553 0.19086E+00 -0.7193 6 HS- 0.11407E-03 -3.9428 0.20408E-04 -4.6902 0.17891E+00 -0.7474 7 H4SiO4 0.48928E-01 -1.3104 0.48928E-01 -1.3104 0.10000E+01 0.0000 8 Al+++ 0.19581E-16 -16.7082 0.18176E-22 -22.7405 0.92824E-06 -6.0323 9 Ca++ 0.11772E-05 -5.9292 0.21896E-08 -8.6596 0.18600E-02 -2.7305 10 Mg++ 0.12921E-05 -5.8887 0.19822E-08 -8.7028 0.15341E-02 -2.8141 11 Fe++ 0.12164E-07 -7.9149 0.19593E-10 -10.7079 0.16108E-02 -2.7930 12 K+ 0.34889E-01 -1.4573 0.68177E-02 -2.1664 0.19541E+00 -0.7091 13 Na+ 0.11028E+00 -0.9575 0.19783E-01 -1.7037 0.17940E+00 -0.7462 14 Mn++ 0.11443E-05 -5.9415 0.19102E-08 -8.7189 0.16693E-02 -2.7775 15 Zn++ 0.30912E-09 -9.5099 0.49793E-12 -12.3028 0.16108E-02 -2.7930 16 Cu+ 0.12865E-07 -7.8906 0.23020E-08 -8.6379 0.17893E+00 -0.7473 17 Pb++ 0.26238E-08 -8.5811 0.54603E-11 -11.2628 0.20811E-02 -2.6817 18 Ag+ 0.29853E-09 -9.5250 0.57437E-10 -10.2408 0.19240E+00 -0.7158 19 Ba++ 0.60273E-07 -7.2199 0.13468E-09 -9.8707 0.22346E-02 -2.6508 20 HPO4-- 0.13341E-08 -8.8748 0.31043E-11 -11.5080 0.23269E-02 -2.6332 21 HSiO3- 0.13486E-05 -5.8701 0.23934E-06 -6.6210 0.17748E+00 -0.7509 22 Ca(HSiO3)+ 0.43814E-08 -8.3584 0.86363E-09 -9.0637 0.19711E+00 -0.7053 23 Mg(HSiO3)+ 0.12696E-08 -8.8963 0.25026E-09 -9.6016 0.19711E+00 -0.7053 24 NaHSiO3,aq 0.19052E-05 -5.7200 0.19052E-05 -5.7200 0.10000E+01 0.0000 28 AgCl,aq 0.11962E-06 -6.9222 0.11962E-06 -6.9222 0.10000E+01 0.0000 29 AgCl2- 0.53695E-05 -5.2701 0.95295E-06 -6.0209 0.17748E+00 -0.7509 30 AgCl3-2 0.17459E-05 -5.7580 0.37445E-08 -8.4266 0.21448E-02 -2.6686 31 AgCl4-3 0.15170E-05 -5.8190 0.12374E-11 -11.9075 0.81572E-06 -6.0885 34 Ag(HS),aq 0.19810E-08 -8.7031 0.19810E-08 -8.7031 0.10000E+01 0.0000 35 Ag(HS)2- 0.69946E-08 -8.1552 0.12414E-08 -8.9061 0.17748E+00 -0.7509 38 HAlO2,aq 0.40989E-08 -8.3873 0.40989E-08 -8.3873 0.10000E+01 0.0000 39 AlO2- 0.11172E-04 -4.9519 0.17452E-05 -5.7581 0.15621E+00 -0.8063 41 Ba(HCO3)+ 0.19934E-06 -6.7004 0.40867E-07 -7.3886 0.20501E+00 -0.6882 42 BaCl+ 0.77772E-05 -5.1092 0.15330E-05 -5.8145 0.19711E+00 -0.7053 43 CH4,aq 0.14858E-08 -8.8281 0.17629E-08 -8.7538 0.11865E+01 0.0743 48 CO,aq 0.50777E-03 -3.2943 0.50777E-03 -3.2943 0.10000E+01 0.0000 49 CO2,aq 0.26740E+01 0.4272 0.31728E+01 0.5014 0.11865E+01 0.0743 50 CO3-2 0.36580E-10 -10.4368 0.78457E-13 -13.1054 0.21448E-02 -2.6686 52 Ca(HCO3)+ 0.95188E-07 -7.0214 0.18763E-07 -7.7267 0.19711E+00 -0.7053 53 CaCl+ 0.70088E-04 -4.1544 0.13815E-04 -4.8596 0.19711E+00 -0.7053 54 CaCl2,aq 0.74695E-04 -4.1267 0.74695E-04 -4.1267 0.10000E+01 0.0000 55 CaOH+ 0.13377E-06 -6.8736 0.26368E-07 -7.5789 0.19711E+00 -0.7053 56 CaSO4,aq 0.16979E-06 -6.7701 0.16979E-06 -6.7701 0.10000E+01 0.0000 57 HCl,aq 0.32183E-02 -2.4924 0.32183E-02 -2.4924 0.10000E+01 0.0000 66 CuCl,aq 0.20988E-04 -4.6780 0.20988E-04 -4.6780 0.10000E+01 0.0000 67 CuCl2- 0.69153E-04 -4.1602 0.12273E-04 -4.9111 0.17748E+00 -0.7509 68 CuCl3-2 0.12283E-05 -5.9107 0.26346E-08 -8.5793 0.21448E-02 -2.6686 74 FeCl+ 0.22565E-06 -6.6466 0.44478E-07 -7.3519 0.19711E+00 -0.7053 75 FeCl2,aq 0.28066E-02 -2.5518 0.28066E-02 -2.5518 0.10000E+01 0.0000 77 FeO,aq 0.57337E-07 -7.2416 0.57337E-07 -7.2416 0.10000E+01 0.0000 78 FeOH+ 0.19136E-07 -7.7182 0.37719E-08 -8.4234 0.19711E+00 -0.7053 79 HFeO2- 0.63702E-08 -8.1958 0.11306E-08 -8.9467 0.17748E+00 -0.7509 82 FeO2- 0.39766E-08 -8.4005 0.70574E-09 -9.1514 0.17748E+00 -0.7509 83 HFeO2,aq 0.28087E-09 -9.5515 0.28087E-09 -9.5515 0.10000E+01 0.0000 84 H2,aq 0.44833E-02 -2.3484 0.53195E-02 -2.2741 0.11865E+01 0.0743 85 KCl,aq 0.72240E-01 -1.1412 0.72240E-01 -1.1412 0.10000E+01 0.0000 86 KHSO4,aq 0.13705E-01 -1.8631 0.13705E-01 -1.8631 0.10000E+01 0.0000 87 KOH,aq 0.13931E-05 -5.8560 0.13931E-05 -5.8560 0.10000E+01 0.0000 88 KSO4- 0.47569E-02 -2.3227 0.84423E-03 -3.0735 0.17748E+00 -0.7509 90 Mg(HCO3)+ 0.29208E-07 -7.5345 0.57572E-08 -8.2398 0.19711E+00 -0.7053 91 MgCl+ 0.13605E-04 -4.8663 0.26816E-05 -5.5716 0.19711E+00 -0.7053 92 MgOH+ 0.52180E-06 -6.2825 0.10285E-06 -6.9878 0.19711E+00 -0.7053 94 MnO,aq 0.95313E-07 -7.0208 0.95313E-07 -7.0208 0.10000E+01 0.0000 95 MnOH+ 0.20542E-06 -6.6874 0.40490E-07 -7.3926 0.19711E+00 -0.7053 97 HMnO2- 0.42006E-10 -10.3767 0.74550E-11 -11.1276 0.17748E+00 -0.7509 100 MnCl+ 0.11557E-02 -2.9372 0.22780E-03 -3.6424 0.19711E+00 -0.7053 101 MnSO4,aq 0.16053E-06 -6.7945 0.16053E-06 -6.7945 0.10000E+01 0.0000 102 NaCl,aq 0.44817E+00 -0.3486 0.44817E+00 -0.3486 0.10000E+01 0.0000 103 NaOH,aq 0.18490E-05 -5.7331 0.18490E-05 -5.7331 0.10000E+01 0.0000 105 OH- 0.72209E-05 -5.1414 0.11280E-05 -5.9477 0.15621E+00 -0.8063 111 H3PO3,aq 0.11571E-09 -9.9366 0.11571E-09 -9.9366 0.10000E+01 0.0000 112 H2PO3- 0.18409E-08 -8.7350 0.32671E-09 -9.4858 0.17748E+00 -0.7509 113 H3PO4,aq 0.13685E-05 -5.8637 0.13685E-05 -5.8637 0.10000E+01 0.0000 114 H2PO4- 0.13689E-05 -5.8636 0.25510E-06 -6.5933 0.18636E+00 -0.7296 116 H4P2O7,aq 0.17459E-09 -9.7580 0.17459E-09 -9.7580 0.10000E+01 0.0000 117 H3P2O7- 0.88145E-09 -9.0548 0.15643E-09 -9.8057 0.17748E+00 -0.7509 118 H2P2O7-2 0.21022E-06 -6.6773 0.45088E-09 -9.3459 0.21448E-02 -2.6686 119 HP2O7-3 0.22458E-07 -7.6486 0.18320E-13 -13.7371 0.81572E-06 -6.0885 121 PbCl+ 0.12035E-05 -5.9195 0.23723E-06 -6.6248 0.19711E+00 -0.7053 122 PbCl2,aq 0.86626E-04 -4.0624 0.86626E-04 -4.0624 0.10000E+01 0.0000 123 PbCl3- 0.97297E-04 -4.0119 0.17268E-04 -4.7628 0.17748E+00 -0.7509 124 PbCl4-2 0.16077E-04 -4.7938 0.34481E-07 -7.4624 0.21448E-02 -2.6686 125 PbO,aq 0.67560E-08 -8.1703 0.67560E-08 -8.1703 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12743E-03 -3.8947 0.12743E-03 -3.8947 0.10000E+01 0.0000 128 Pb(HS)3- 0.13889E-04 -4.8573 0.24649E-05 -5.6082 0.17748E+00 -0.7509 129 H2S,aq 0.10584E+01 0.0247 0.12558E+01 0.0989 0.11865E+01 0.0743 130 S2-2 0.11701E-07 -7.9318 0.25097E-10 -10.6004 0.21448E-02 -2.6686 131 S3-2 0.10844E-08 -8.9648 0.23257E-11 -11.6334 0.21448E-02 -2.6686 132 S3- 0.95246E-02 -2.0212 0.16904E-02 -2.7720 0.17748E+00 -0.7509 133 S4-2 0.85383E-10 -10.0686 0.18313E-12 -12.7372 0.21448E-02 -2.6686 135 SO2,aq 0.29335E+00 -0.5326 0.29335E+00 -0.5326 0.10000E+01 0.0000 136 SO3-2 0.62385E-09 -9.2049 0.21165E-11 -11.6744 0.33927E-02 -2.4695 137 HSO3- 0.23811E-03 -3.6232 0.42258E-04 -4.3741 0.17748E+00 -0.7509 138 HSO4- 0.79904E-02 -2.0974 0.16180E-02 -2.7910 0.20249E+00 -0.6936 140 S2O3-2 0.48867E-06 -6.3110 0.10481E-08 -8.9796 0.21448E-02 -2.6686 141 HS2O3- 0.35958E-06 -6.4442 0.63816E-07 -7.1951 0.17748E+00 -0.7509 142 H2S2O3,aq 0.34354E-07 -7.4640 0.34354E-07 -7.4640 0.10000E+01 0.0000 150 S4O6-2 0.41539E-09 -9.3815 0.89094E-12 -12.0502 0.21448E-02 -2.6686 152 ZnCl+ 0.14045E-03 -3.8525 0.27685E-04 -4.5578 0.19711E+00 -0.7053 153 ZnCl2,aq 0.59593E-03 -3.2248 0.59593E-03 -3.2248 0.10000E+01 0.0000 154 ZnCl3- 0.40727E-04 -4.3901 0.72281E-05 -5.1410 0.17748E+00 -0.7509 155 ZnO,aq 0.27887E-07 -7.5546 0.27887E-07 -7.5546 0.10000E+01 0.0000 156 ZnOH+ 0.97495E-06 -6.0110 0.19217E-06 -6.7163 0.19711E+00 -0.7053 158 HZnO2- 0.20242E-09 -9.6938 0.35924E-10 -10.4446 0.17748E+00 -0.7509 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4601927E-05 0.4295089E+01 0.3542212E+04 0.0000 2 H2O 0.1000000E+01 0.5252108E+02 0.7741815E+06 0.0000 3 Cl- 0.1231759E+00 0.6559801E+00 0.1902880E+05 4.3591 4 SO4-- 0.2328200E-03 0.2515794E+00 0.1977391E+05 5.7705 5 HCO3- 0.9204399E-05 0.2674540E+01 0.1335270E+06 0.2642 6 HS- 0.1140667E-03 0.1156084E+01 0.3128365E+05 1.3293 7 H4SiO4 0.4892782E-01 0.4893108E-01 0.3848092E+04 -1.3104 8 Al+++ 0.1958137E-16 0.1117613E-04 0.2467318E+00 -4.6821 9 Ca++ 0.1177155E-05 0.1463632E-03 0.4799606E+01 3.3793 10 Mg++ 0.1292079E-05 0.1544911E-04 0.3073208E+00 3.3361 11 Fe++ 0.1216356E-07 0.2806883E-02 0.1282602E+03 1.3310 12 K+ 0.3488892E-01 0.1255920E+00 0.4018172E+04 3.8531 13 Na+ 0.1102773E+00 0.5584469E+00 0.1050473E+05 4.3158 14 Mn++ 0.1144315E-05 0.1157302E-02 0.5202200E+02 3.3200 15 Zn++ 0.3091165E-09 0.7781140E-03 0.4161878E+02 -0.2639 16 Cu+ 0.1286521E-07 0.9138262E-04 0.4750928E+01 -2.6184 17 Pb++ 0.2623795E-08 0.3425326E-03 0.5806820E+02 0.7761 18 Ag+ 0.2985304E-09 0.8761204E-05 0.7732717E+00 -4.2214 19 Ba++ 0.6027346E-07 0.8036810E-05 0.9031262E+00 2.1682 20 HPO4-- 0.1334093E-08 0.3208180E-05 0.2519432E+00 0.5309 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265498E+01 -.3135622E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5215922E+02 -.1944449E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2498461E+00 0.1876680E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1148119E+01 0.1202536E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4859396E-01 0.9500037E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1109913E-04 0.6834404E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1453548E-03 0.3825551E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1534267E-04 0.5333978E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2787545E-02 0.5979209E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247267E+00 0.6834404E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149328E-02 0.1718811E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7727530E-03 0.1526582E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.9075302E-04 0.3088567E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7981440E-05 0.4739101E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3186077E-05 0.5381424E-05 0.0000000E+00 Chg. balance for solid moles: -.5607E-18 Mass of aqueous solution: 0.121375E+04 g Temperature = 560.00 C Pressure = 1063.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3736E-03 -3.428 0.5086E-01 -1.294 0.7565 0.1717E-01 annite 0.6563E-06 -6.183 0.3360E-03 -3.474 0.4997E-02 0.1013E-03 phlogopite 0.1778E-05 -5.750 0.7419E-03 -3.130 0.1104E-01 0.2660E-03 biotite-Mn 0.5729E-07 -7.242 0.2917E-04 -4.535 0.4339E-03 0.8745E-05 apatite-OH 0.1794E-05 -5.746 0.9011E-03 -3.045 0.1340E-01 0.2863E-03 microcline 0.6809E-03 -3.167 0.1895 -0.722 2.819 0.7404E-01 pyrite 0.5668E-02 -2.247 0.6801 -0.167 10.12 0.1357 quartz 0.9295E-01 -1.032 5.584 0.747 83.06 2.109 barite 0.4739E-04 -4.324 0.1106E-01 -1.956 0.1645 0.2469E-02 chalcopyrite 0.3089E-03 -3.510 0.5668E-01 -1.247 0.8430 0.1323E-01 sphalerite 0.1527E-02 -2.816 0.1487 -0.828 2.212 0.3637E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2634E+00 0.2634E+00 1.0000 -0.579 phlogopite 0.7136E+00 0.7136E+00 1.0000 -0.147 biotite-Mn 0.2299E-01 0.2299E-01 1.0000 -1.638 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.723406 g Volume = 2.388557 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.93 -14.93 0.00 0.000 0.00000E+00 24 annite 0.97 0.97 0.00 0.000 -0.14391E-10 25 phlogopite 5.69 5.69 0.00 0.000 0.16930E-10 26 biotite-Mn 10.11 10.11 0.00 0.000 0.00000E+00 30 apatite-OH -53.75 -53.75 0.00 0.000 0.00000E+00 115 microcline -4.75 -4.75 0.00 0.000 -0.16930E-10 140 pyrite -21.99 -21.99 0.00 0.000 0.00000E+00 144 quartz -1.31 -1.31 0.00 0.000 0.00000E+00 237 barite -16.14 -16.14 0.00 0.000 0.00000E+00 240 chalcopyrite -23.66 -23.66 0.00 0.000 0.00000E+00 255 sphalerite -10.97 -10.97 0.00 0.000 0.13544E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 0.00 -0.26 -0.264 0.10046E+04 2.763 2 CO2,gas -10.08 -11.77 -1.69 -0.564 0.64456E+04 1.336 3 CH4,gas 6.84 -4.18 -11.02 -2.755 0.42018E+05 -7.995 4 H2,gas 5.97 1.90 -4.08 -2.329 0.15537E+05 -1.049 5 H2S,gas -8.40 -10.71 -2.31 -1.155 0.88051E+04 0.717 6 CO,gas -3.84 -9.87 -6.03 -1.856 0.22999E+05 -3.006 7 SO3,gas -7.64 -18.31 -10.67 -2.667 0.40677E+05 -7.643 8 O2,gas 16.89 -3.80 -20.68 -13.790 0.78858E+05 -17.658 9 HCl,gas -6.15 -7.68 -1.53 -0.763 0.58187E+04 -1.526 10 acmite 3.61 2.08 -1.53 -0.159 0.58488E+04 12 akimotoite 6.24 2.03 -4.22 -0.844 0.16080E+05 13 akimotoite-Fe 4.11 0.02 -4.08 -0.817 0.15567E+05 14 albite-high -4.15 -4.29 -0.15 -0.011 0.55462E+03 15 albite -4.14 -4.29 -0.15 -0.011 0.56579E+03 16 almandine -7.25 -9.30 -2.05 -0.102 0.78066E+04 17 pyrope -0.48 -3.29 -2.81 -0.141 0.10715E+05 18 analcite -2.00 -2.99 -0.99 -0.110 0.37714E+04 19 andalusite -10.06 -10.68 -0.61 -0.061 0.23401E+04 27 anorthite -7.73 -8.61 -0.87 -0.067 0.33335E+04 28 anthophyllite 15.02 12.88 -2.14 -0.058 0.81624E+04 29 anthophyllite-Fe 2.10 -1.16 -3.25 -0.088 0.12393E+05 31 apatite-OH-zs -51.55 -53.75 -2.19 -0.169 0.83539E+04 32 apatite-Cl-zs -58.16 -61.42 -3.26 -0.272 0.12443E+05 33 aragonite -4.70 -8.40 -3.70 -1.233 0.14099E+05 34 brucite 5.59 3.33 -2.25 -0.450 0.85871E+04 35 calcite -4.80 -8.40 -3.59 -1.197 0.13695E+05 36 carnegieite-low 0.12 -1.68 -1.80 -0.257 0.68500E+04 37 carnegieite-high 0.20 -1.68 -1.88 -0.269 0.71681E+04 38 carpholite-Mg -6.55 -8.65 -2.10 -0.140 0.80159E+04 39 carpholite-Fe -7.94 -10.66 -2.72 -0.181 0.10369E+05 40 celadonite -0.63 -2.73 -2.10 -0.123 0.79932E+04 41 celadonite-Fe -2.07 -4.73 -2.67 -0.157 0.10171E+05 42 chrysotile 9.75 7.39 -2.37 -0.197 0.90276E+04 44 clinochlore 4.78 3.38 -1.41 -0.044 0.53623E+04 45 daphnite -2.45 -6.65 -4.20 -0.131 0.16013E+05 47 chlorite-Al-free 19.68 14.77 -4.91 -0.204 0.18709E+05 48 chloritoid-Mg -5.92 -7.34 -1.42 -0.095 0.54181E+04 49 chloritoid-Fe -7.91 -9.35 -1.44 -0.096 0.54910E+04 50 chloritoid-Mn -5.76 -7.36 -1.60 -0.106 0.60847E+04 52 coesite -1.01 -1.31 -0.29 -0.098 0.11173E+04 53 cordierite-H -17.54 -18.61 -1.07 -0.038 0.40710E+04 54 cordierite-Fe -20.20 -22.62 -2.42 -0.083 0.92095E+04 55 cordierite-Mn -15.84 -18.64 -2.80 -0.096 0.10667E+05 56 corundum -8.58 -9.37 -0.79 -0.072 0.30175E+04 58 cristobalite -1.26 -1.31 -0.05 -0.016 0.18188E+03 59 cummingtonite 15.09 12.88 -2.21 -0.060 0.84227E+04 61 cymrite-K -2.43 -4.76 -2.33 -0.194 0.88830E+04 63 diaspore -3.79 -4.68 -0.89 -0.148 0.33941E+04 65 diopside 5.50 4.10 -1.40 -0.140 0.53561E+04 66 hedenbergite 4.05 2.09 -1.95 -0.195 0.74505E+04 68 eastonite -4.74 -6.15 -1.40 -0.054 0.53479E+04 69 enstatite 4.91 4.05 -0.85 -0.085 0.32590E+04 70 clinoenstatite-HiP 5.41 4.05 -1.36 -0.136 0.51666E+04 71 clinoenstatite 4.89 4.05 -0.84 -0.084 0.31933E+04 72 protoenstatite 5.04 4.05 -0.99 -0.099 0.37685E+04 73 epidote -3.66 -6.16 -2.50 -0.121 0.95213E+04 74 clinozoisite -8.28 -11.22 -2.94 -0.134 0.11208E+05 75 epidote-Fe 2.66 -1.09 -3.75 -0.195 0.14303E+05 76 fayalite 2.46 1.35 -1.11 -0.159 0.42351E+04 77 ferrosilite 1.25 0.04 -1.21 -0.121 0.46146E+04 78 forsterite 6.54 5.36 -1.17 -0.168 0.44731E+04 79 gedrite -7.63 -9.91 -2.28 -0.062 0.86850E+04 81 gibbsite -2.16 -4.69 -2.52 -0.360 0.96163E+04 82 glaucophane 1.86 -1.20 -3.05 -0.083 0.11641E+05 83 glaucophane-Fe -2.30 -7.21 -4.92 -0.133 0.18746E+05 84 goethite 1.26 0.38 -0.88 -0.191 0.33720E+04 86 greenalite 4.77 1.37 -3.40 -0.283 0.12952E+05 87 grunerite 2.66 -1.16 -3.81 -0.103 0.14544E+05 88 halite -1.33 -3.36 -2.04 -1.018 0.77600E+04 89 hematite 0.98 0.76 -0.22 -0.027 0.83775E+03 90 heulandite -11.88 -15.15 -3.27 -0.149 0.12480E+05 91 hercynite -6.72 -8.04 -1.32 -0.088 0.50391E+04 94 jadeite -1.31 -2.98 -1.67 -0.167 0.63730E+04 96 kalsilite -0.50 -2.14 -1.64 -0.234 0.62372E+04 97 kaolinite -9.16 -11.99 -2.83 -0.257 0.10787E+05 98 kyanite -9.90 -10.68 -0.78 -0.078 0.29689E+04 100 laumontite -7.47 -11.23 -3.76 -0.250 0.14323E+05 101 lawsonite -4.96 -8.61 -3.65 -0.243 0.13906E+05 102 leucite -2.47 -3.45 -0.97 -0.097 0.37090E+04 104 lizardite 9.92 7.39 -2.53 -0.211 0.96628E+04 105 magnesite -5.51 -8.44 -2.93 -0.978 0.11180E+05 106 magnetite 2.32 2.09 -0.23 -0.018 0.85997E+03 107 minnesotaite 0.89 -1.24 -2.14 -0.126 0.81484E+04 108 minnesotaite-Mg 6.98 4.77 -2.21 -0.130 0.84243E+04 109 magnesioferrite 5.43 4.09 -1.34 -0.109 0.51086E+04 111 manganosite 5.52 3.32 -2.20 -0.550 0.83928E+04 112 margarite -15.85 -17.98 -2.12 -0.085 0.80988E+04 116 monticellite 8.98 5.40 -3.58 -0.511 0.13642E+05 118 mullite-Si -9.30 -10.68 -1.37 -0.137 0.52342E+04 119 muscovite -13.20 -14.12 -0.92 -0.054 0.35112E+04 120 paragonite -12.52 -13.66 -1.14 -0.067 0.43582E+04 121 nepheline -0.18 -1.68 -1.50 -0.214 0.57003E+04 122 osumilite(2) -12.51 -14.58 -2.07 -0.043 0.78778E+04 123 osumilite-Fe -27.16 -29.99 -2.82 -0.059 0.10758E+05 124 pargasite 6.68 2.51 -4.17 -0.110 0.15906E+05 125 periclase 5.79 3.33 -2.45 -0.614 0.93593E+04 126 periclase-Fe 3.17 1.33 -1.84 -0.460 0.70192E+04 127 perovskite-Al -6.83 -9.37 -2.54 -0.231 0.96810E+04 132 phlogopite-Na 6.56 5.71 -0.85 -0.047 0.32535E+04 134 prehnite -3.01 -6.54 -3.53 -0.207 0.13440E+05 135 prehnite-Fe 2.01 -1.47 -3.48 -0.209 0.13262E+05 138 px-Mg-tschermaks -5.29 -7.34 -2.05 -0.146 0.78028E+04 139 px-Ca-tschermaks -4.52 -7.30 -2.78 -0.199 0.10602E+05 141 pyrrhotite -8.69 -9.38 -0.69 -0.230 0.26291E+04 142 pyrrhotiteFe0.875 -9.48 -9.78 -0.30 -0.110 0.11428E+04 143 pyrophyllite -13.12 -14.60 -1.48 -0.093 0.56526E+04 146 riebeckite 5.85 2.92 -2.93 -0.081 0.11182E+05 147 ringwoodite-Fe 3.46 1.35 -2.11 -0.302 0.80528E+04 148 ringwoodite-Mg 9.71 5.36 -4.35 -0.622 0.16593E+05 149 rhodochrosite -5.51 -8.45 -2.94 -0.981 0.11222E+05 150 rhodonite 2.57 2.01 -0.56 -0.113 0.21496E+04 151 sanidine -4.21 -4.75 -0.54 -0.042 0.20663E+04 153 siderite -7.38 -10.44 -3.06 -1.021 0.11674E+05 154 sillimanite -10.02 -10.68 -0.65 -0.065 0.24855E+04 156 spinel -4.51 -6.03 -1.53 -0.102 0.58163E+04 163 stilpnomelane-Mg 0.89 -1.24 -2.13 -0.064 0.81247E+04 164 stishovite 1.67 -1.31 -2.98 -0.993 0.11355E+05 165 sudoite-Fe -15.42 -20.01 -4.59 -0.148 0.17491E+05 166 sudoite -13.14 -16.00 -2.86 -0.092 0.10896E+05 167 sulfur -11.11 -12.61 -1.49 -0.459 0.56929E+04 168 sylvite -1.23 -3.83 -2.59 -1.297 0.98858E+04 169 talc 5.24 4.77 -0.47 -0.028 0.17895E+04 170 talc-Fe 2.31 -1.24 -3.55 -0.209 0.13549E+05 171 talc-tschermaks -4.88 -6.62 -1.74 -0.102 0.66289E+04 173 tephroite 6.72 5.33 -1.39 -0.199 0.53173E+04 176 topaz-H -7.97 -10.68 -2.71 -0.246 0.10337E+05 177 tremolite 15.60 12.97 -2.63 -0.071 0.10041E+05 179 troilite-low -8.60 -9.38 -0.78 -0.260 0.29761E+04 180 tschermakite -6.27 -9.82 -3.55 -0.096 0.13537E+05 183 wadsleyite-Fe 3.32 1.35 -1.97 -0.281 0.74981E+04 184 wadsleyite-Mg 8.77 5.36 -3.41 -0.486 0.12981E+05 185 wairakite -9.35 -11.22 -1.88 -0.110 0.71547E+04 186 walstromite 4.65 2.07 -2.58 -0.516 0.98285E+04 187 wollastonite 4.22 2.07 -2.15 -0.430 0.82049E+04 188 pseudo-wollastonite 4.34 2.07 -2.27 -0.454 0.86584E+04 189 zoisite -8.33 -11.22 -2.89 -0.131 0.11014E+05 192 beidellite-Ca -13.31 -15.16 -1.85 -0.114 0.70439E+04 193 beidellite-H -13.34 -15.71 -2.37 -0.151 0.90353E+04 194 beidellite-K -12.30 -14.44 -2.14 -0.131 0.81704E+04 195 beidellite-Mg -13.56 -15.16 -1.60 -0.099 0.61154E+04 196 beidellite-Na -12.24 -14.29 -2.05 -0.125 0.78099E+04 197 bornite -55.23 -55.55 -0.32 -0.024 0.12334E+04 199 chalcocite -14.47 -15.95 -1.48 -0.370 0.56383E+04 200 covellite -12.91 -14.28 -1.37 -0.522 0.52217E+04 202 montmorillonite-Ca -10.02 -11.40 -1.38 -0.085 0.52453E+04 203 montmorillonite-K -9.29 -10.68 -1.39 -0.085 0.53051E+04 204 montmorillonite-Mg -10.23 -11.40 -1.17 -0.072 0.44634E+04 205 montmorillonite-Na -8.96 -10.53 -1.57 -0.096 0.60011E+04 206 nontronite-Ca -3.49 -5.03 -1.54 -0.100 0.58655E+04 207 nontronite-H -3.53 -5.59 -2.05 -0.138 0.78272E+04 208 nontronite-K -2.48 -4.32 -1.83 -0.118 0.69843E+04 209 nontronite-Mg -3.71 -5.04 -1.33 -0.086 0.50665E+04 210 nontronite-Na -2.42 -4.16 -1.74 -0.112 0.66354E+04 215 gypsum -12.67 -14.93 -2.26 -0.564 0.86059E+04 231 acanthite -14.21 -19.15 -4.95 -1.237 0.18858E+05 232 alabandite -6.42 -7.39 -0.97 -0.325 0.37125E+04 234 anglesite -15.22 -17.53 -2.31 -1.155 0.88073E+04 238 boehmite -3.50 -4.68 -1.19 -0.198 0.45250E+04 242 copper,native 1.72 -1.67 -3.39 -1.179 0.12918E+05 244 ferrous-oxide 2.24 1.33 -0.91 -0.227 0.34661E+04 245 galena -9.93 -9.93 0.00 -0.001 0.13082E+02 246 silver,native 0.44 -3.27 -3.71 -1.290 0.14134E+05 248 litharge 5.36 0.77 -4.59 -1.147 0.17485E+05 256 wurtzite -10.16 -10.97 -0.81 -0.270 0.30880E+04 257 zincite 2.32 -0.27 -2.59 -0.647 0.98630E+04 258 an20ab80 -5.08 -5.15 -0.08 -0.006 0.29034E+03 259 an25ab75 -5.28 -5.37 -0.09 -0.007 0.32800E+03 260 an30ab70 -5.49 -5.59 -0.10 -0.008 0.38583E+03 261 tr.625ac.25prg.125 10.26 9.15 -1.11 -0.030 0.42270E+04 Calculations done for 560.0000 Deg. C; 1063.0000 bar Temperature changed by -1.000 degrees to 559.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 35 Loop limit = 500 Temperature = 559.00 C Pressure = 1050.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5513E+02 kg liquid = 0.9931E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9968 Stoichiometric ionic strength = .3274838E+01 Osmotic coef. = 0.0000 True ionic strength = .1454045E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.45516E-05 -5.3418 0.94017E-06 -6.0268 0.20656E+00 -0.6850 2 H2O 0.99683E+00 -0.0014 0.99683E+00 -0.0014 3 Cl- 0.12194E+00 -0.9138 0.21494E-01 -1.6677 0.17626E+00 -0.7538 4 SO4-- 0.23565E-03 -3.6277 0.53237E-06 -6.2738 0.22592E-02 -2.6461 5 HCO3- 0.89863E-05 -5.0464 0.17033E-05 -5.7687 0.18954E+00 -0.7223 6 HS- 0.11315E-03 -3.9463 0.20105E-04 -4.6967 0.17769E+00 -0.7503 7 H4SiO4 0.48105E-01 -1.3178 0.48105E-01 -1.3178 0.10000E+01 0.0000 8 Al+++ 0.21153E-16 -16.6746 0.18574E-22 -22.7311 0.87808E-06 -6.0565 9 Ca++ 0.11712E-05 -5.9314 0.21252E-08 -8.6726 0.18145E-02 -2.7412 10 Mg++ 0.13407E-05 -5.8727 0.20066E-08 -8.6975 0.14967E-02 -2.8249 11 Fe++ 0.12139E-07 -7.9158 0.19076E-10 -10.7195 0.15714E-02 -2.8037 12 K+ 0.34598E-01 -1.4609 0.67139E-02 -2.1730 0.19405E+00 -0.7121 13 Na+ 0.10915E+00 -0.9620 0.19445E-01 -1.7112 0.17816E+00 -0.7492 14 Mn++ 0.11783E-05 -5.9288 0.19187E-08 -8.7170 0.16284E-02 -2.7882 15 Zn++ 0.31083E-09 -9.5075 0.48844E-12 -12.3112 0.15714E-02 -2.8037 16 Cu+ 0.12579E-07 -7.9004 0.22352E-08 -8.6507 0.17770E+00 -0.7503 17 Pb++ 0.26291E-08 -8.5802 0.53375E-11 -11.2727 0.20301E-02 -2.6925 18 Ag+ 0.29764E-09 -9.5263 0.56868E-10 -10.2451 0.19107E+00 -0.7188 19 Ba++ 0.59199E-07 -7.2277 0.12905E-09 -9.8893 0.21799E-02 -2.6616 20 HPO4-- 0.13672E-08 -8.8642 0.31042E-11 -11.5080 0.22705E-02 -2.6439 21 HSiO3- 0.13268E-05 -5.8772 0.23386E-06 -6.6310 0.17626E+00 -0.7538 22 Ca(HSiO3)+ 0.42569E-08 -8.3709 0.83326E-09 -9.0792 0.19574E+00 -0.7083 23 Mg(HSiO3)+ 0.12939E-08 -8.8881 0.25327E-09 -9.5964 0.19574E+00 -0.7083 24 NaHSiO3,aq 0.19039E-05 -5.7204 0.19039E-05 -5.7204 0.10000E+01 0.0000 28 AgCl,aq 0.12115E-06 -6.9167 0.12115E-06 -6.9167 0.10000E+01 0.0000 29 AgCl2- 0.53742E-05 -5.2697 0.94728E-06 -6.0235 0.17626E+00 -0.7538 30 AgCl3-2 0.17324E-05 -5.7614 0.36254E-08 -8.4406 0.20928E-02 -2.6793 31 AgCl4-3 0.15238E-05 -5.8171 0.11766E-11 -11.9294 0.77215E-06 -6.1123 34 Ag(HS),aq 0.20407E-08 -8.6902 0.20407E-08 -8.6902 0.10000E+01 0.0000 35 Ag(HS)2- 0.70643E-08 -8.1509 0.12452E-08 -8.9048 0.17626E+00 -0.7538 36 AlO+ 0.10070E-10 -10.9970 0.19712E-11 -11.7053 0.19574E+00 -0.7083 38 HAlO2,aq 0.41238E-08 -8.3847 0.41238E-08 -8.3847 0.10000E+01 0.0000 39 AlO2- 0.10977E-04 -4.9595 0.17035E-05 -5.7687 0.15518E+00 -0.8092 41 Ba(HCO3)+ 0.19166E-06 -6.7175 0.39019E-07 -7.4087 0.20359E+00 -0.6913 42 BaCl+ 0.75200E-05 -5.1238 0.14720E-05 -5.8321 0.19574E+00 -0.7083 43 CH4,aq 0.14639E-08 -8.8345 0.17358E-08 -8.7605 0.11857E+01 0.0740 48 CO,aq 0.49819E-03 -3.3026 0.49819E-03 -3.3026 0.10000E+01 0.0000 49 CO2,aq 0.26740E+01 0.4272 0.31705E+01 0.5011 0.11857E+01 0.0740 50 CO3-2 0.36233E-10 -10.4409 0.75827E-13 -13.1202 0.20928E-02 -2.6793 52 Ca(HCO3)+ 0.91312E-07 -7.0395 0.17874E-07 -7.7478 0.19574E+00 -0.7083 53 CaCl+ 0.68390E-04 -4.1650 0.13387E-04 -4.8733 0.19574E+00 -0.7083 54 CaCl2,aq 0.73526E-04 -4.1336 0.73526E-04 -4.1336 0.10000E+01 0.0000 55 CaOH+ 0.13005E-06 -6.8859 0.25456E-07 -7.5942 0.19574E+00 -0.7083 56 CaSO4,aq 0.17181E-06 -6.7650 0.17181E-06 -6.7650 0.10000E+01 0.0000 57 HCl,aq 0.33049E-02 -2.4808 0.33049E-02 -2.4808 0.10000E+01 0.0000 66 CuCl,aq 0.20860E-04 -4.6807 0.20860E-04 -4.6807 0.10000E+01 0.0000 67 CuCl2- 0.68443E-04 -4.1647 0.12064E-04 -4.9185 0.17626E+00 -0.7538 68 CuCl3-2 0.12086E-05 -5.9177 0.25293E-08 -8.5970 0.20928E-02 -2.6793 74 FeCl+ 0.22091E-06 -6.6558 0.43242E-07 -7.3641 0.19574E+00 -0.7083 75 FeCl2,aq 0.27067E-02 -2.5676 0.27067E-02 -2.5676 0.10000E+01 0.0000 77 FeO,aq 0.55689E-07 -7.2542 0.55689E-07 -7.2542 0.10000E+01 0.0000 78 FeOH+ 0.18656E-07 -7.7292 0.36517E-08 -8.4375 0.19574E+00 -0.7083 79 HFeO2- 0.61045E-08 -8.2143 0.10760E-08 -8.9682 0.17626E+00 -0.7538 82 FeO2- 0.38202E-08 -8.4179 0.67337E-09 -9.1717 0.17626E+00 -0.7538 83 HFeO2,aq 0.27804E-09 -9.5559 0.27804E-09 -9.5559 0.10000E+01 0.0000 84 H2,aq 0.44417E-02 -2.3525 0.52665E-02 -2.2785 0.11857E+01 0.0740 85 KCl,aq 0.72490E-01 -1.1397 0.72490E-01 -1.1397 0.10000E+01 0.0000 86 KHSO4,aq 0.13718E-01 -1.8627 0.13718E-01 -1.8627 0.10000E+01 0.0000 87 KOH,aq 0.13937E-05 -5.8558 0.13937E-05 -5.8558 0.10000E+01 0.0000 88 KSO4- 0.47808E-02 -2.3205 0.84269E-03 -3.0743 0.17626E+00 -0.7538 90 Mg(HCO3)+ 0.29091E-07 -7.5362 0.56944E-08 -8.2445 0.19574E+00 -0.7083 91 MgCl+ 0.13898E-04 -4.8570 0.27204E-05 -5.5654 0.19574E+00 -0.7083 92 MgOH+ 0.52952E-06 -6.2761 0.10365E-06 -6.9844 0.19574E+00 -0.7083 94 MnO,aq 0.95885E-07 -7.0183 0.95885E-07 -7.0183 0.10000E+01 0.0000 95 MnOH+ 0.20608E-06 -6.6860 0.40338E-07 -7.3943 0.19574E+00 -0.7083 97 HMnO2- 0.41524E-10 -10.3817 0.73191E-11 -11.1355 0.17626E+00 -0.7538 100 MnCl+ 0.11556E-02 -2.9372 0.22621E-03 -3.6455 0.19574E+00 -0.7083 101 MnSO4,aq 0.16748E-06 -6.7760 0.16748E-06 -6.7760 0.10000E+01 0.0000 102 NaCl,aq 0.44928E+00 -0.3475 0.44928E+00 -0.3475 0.10000E+01 0.0000 103 NaOH,aq 0.18454E-05 -5.7339 0.18454E-05 -5.7339 0.10000E+01 0.0000 105 OH- 0.71288E-05 -5.1470 0.11063E-05 -5.9561 0.15518E+00 -0.8092 111 H3PO3,aq 0.11719E-09 -9.9311 0.11719E-09 -9.9311 0.10000E+01 0.0000 112 H2PO3- 0.18112E-08 -8.7420 0.31924E-09 -9.4959 0.17626E+00 -0.7538 113 H3PO4,aq 0.14158E-05 -5.8490 0.14158E-05 -5.8490 0.10000E+01 0.0000 114 H2PO4- 0.13847E-05 -5.8586 0.25628E-06 -6.5913 0.18508E+00 -0.7326 116 H4P2O7,aq 0.18664E-09 -9.7290 0.18664E-09 -9.7290 0.10000E+01 0.0000 117 H3P2O7- 0.90649E-09 -9.0426 0.15978E-09 -9.7965 0.17626E+00 -0.7538 118 H2P2O7-2 0.21430E-06 -6.6690 0.44848E-09 -9.3483 0.20928E-02 -2.6793 119 HP2O7-3 0.23435E-07 -7.6301 0.18096E-13 -13.7424 0.77215E-06 -6.1123 121 PbCl+ 0.11897E-05 -5.9246 0.23287E-06 -6.6329 0.19574E+00 -0.7083 122 PbCl2,aq 0.86741E-04 -4.0618 0.86741E-04 -4.0618 0.10000E+01 0.0000 123 PbCl3- 0.97032E-04 -4.0131 0.17103E-04 -4.7669 0.17626E+00 -0.7538 124 PbCl4-2 0.15913E-04 -4.7983 0.33302E-07 -7.4775 0.20928E-02 -2.6793 125 PbO,aq 0.67724E-08 -8.1693 0.67724E-08 -8.1693 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12776E-03 -3.8936 0.12776E-03 -3.8936 0.10000E+01 0.0000 128 Pb(HS)3- 0.13883E-04 -4.8575 0.24471E-05 -5.6113 0.17626E+00 -0.7538 129 H2S,aq 0.10586E+01 0.0247 0.12552E+01 0.0987 0.11857E+01 0.0740 130 S2-2 0.11599E-07 -7.9356 0.24275E-10 -10.6148 0.20928E-02 -2.6793 131 S3-2 0.10785E-08 -8.9672 0.22571E-11 -11.6465 0.20928E-02 -2.6793 132 S3- 0.93499E-02 -2.0292 0.16480E-02 -2.7830 0.17626E+00 -0.7538 133 S4-2 0.85262E-10 -10.0692 0.17843E-12 -12.7485 0.20928E-02 -2.6793 135 SO2,aq 0.29343E+00 -0.5325 0.29343E+00 -0.5325 0.10000E+01 0.0000 136 SO3-2 0.62450E-09 -9.2045 0.20678E-11 -11.6845 0.33112E-02 -2.4800 137 HSO3- 0.23460E-03 -3.6297 0.41352E-04 -4.3835 0.17626E+00 -0.7538 138 HSO4- 0.79493E-02 -2.0997 0.15985E-02 -2.7963 0.20109E+00 -0.6966 140 S2O3-2 0.49114E-06 -6.3088 0.10278E-08 -8.9881 0.20928E-02 -2.6793 141 HS2O3- 0.35661E-06 -6.4478 0.62857E-07 -7.2016 0.17626E+00 -0.7538 142 H2S2O3,aq 0.35062E-07 -7.4552 0.35062E-07 -7.4552 0.10000E+01 0.0000 150 S4O6-2 0.41868E-09 -9.3781 0.87619E-12 -12.0574 0.20928E-02 -2.6793 152 ZnCl+ 0.13636E-03 -3.8653 0.26691E-04 -4.5736 0.19574E+00 -0.7083 153 ZnCl2,aq 0.58515E-03 -3.2327 0.58515E-03 -3.2327 0.10000E+01 0.0000 154 ZnCl3- 0.39279E-04 -4.4058 0.69234E-05 -5.1597 0.17626E+00 -0.7538 155 ZnO,aq 0.27376E-07 -7.5626 0.27376E-07 -7.5626 0.10000E+01 0.0000 156 ZnOH+ 0.94863E-06 -6.0229 0.18569E-06 -6.7312 0.19574E+00 -0.7083 158 HZnO2- 0.19607E-09 -9.7076 0.34559E-10 -10.4614 0.17626E+00 -0.7538 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4551623E-05 0.4294970E+01 0.3542389E+04 0.0000 2 H2O 0.1000000E+01 0.5252145E+02 0.7742473E+06 0.0000 3 Cl- 0.1219425E+00 0.6559631E+00 0.1902978E+05 4.3591 4 SO4-- 0.2356499E-03 0.2515447E+00 0.1977272E+05 5.7798 5 HCO3- 0.8986285E-05 0.2674470E+01 0.1335339E+06 0.2581 6 HS- 0.1131498E-03 0.1155862E+01 0.3128010E+05 1.3301 7 H4SiO4 0.4810528E-01 0.4810852E-01 0.3783698E+04 -1.3178 8 Al+++ 0.2115279E-16 0.1098134E-04 0.2424503E+00 -4.6507 9 Ca++ 0.1171221E-05 0.1434854E-03 0.4705603E+01 3.3810 10 Mg++ 0.1340692E-05 0.1579869E-04 0.3142991E+00 3.3560 11 Fe++ 0.1213903E-07 0.2707056E-02 0.1237082E+03 1.3341 12 K+ 0.3459818E-01 0.1255885E+00 0.4018374E+04 3.8538 13 Na+ 0.1091465E+00 0.5584323E+00 0.1050527E+05 4.3156 14 Mn++ 0.1178267E-05 0.1157283E-02 0.5202523E+02 3.3366 15 Zn++ 0.3108257E-09 0.7617648E-03 0.4074749E+02 -0.2576 16 Cu+ 0.1257865E-07 0.9052385E-04 0.4706648E+01 -2.6239 17 Pb++ 0.2629130E-08 0.3425237E-03 0.5807121E+02 0.7809 18 Ag+ 0.2976358E-09 0.8760976E-05 0.7733118E+00 -4.2183 19 Ba++ 0.5919882E-07 0.7770808E-05 0.8733025E+00 2.1643 20 HPO4-- 0.1367229E-08 0.3281432E-05 0.2577159E+00 0.5455 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265490E+01 -.3127559E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5216095E+02 -.1961754E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2498182E+00 0.1904628E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1147929E+01 0.1221539E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4777831E-01 0.9581601E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1090596E-04 0.6836336E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1425006E-03 0.3854093E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1569025E-04 0.4986405E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2688475E-02 0.6078279E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247265E+00 0.6836336E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149340E-02 0.1600695E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7565362E-03 0.1542799E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.8990251E-04 0.3097072E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7717470E-05 0.4765498E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3258909E-05 0.5308591E-05 0.0000000E+00 Chg. balance for solid moles: -.3046E-17 Mass of aqueous solution: 0.121369E+04 g Temperature = 559.00 C Pressure = 1050.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3766E-03 -3.424 0.5127E-01 -1.290 0.7554 0.1730E-01 annite 0.5932E-06 -6.227 0.3037E-03 -3.518 0.4475E-02 0.9155E-04 phlogopite 0.1662E-05 -5.779 0.6936E-03 -3.159 0.1022E-01 0.2487E-03 biotite-Mn 0.5336E-07 -7.273 0.2717E-04 -4.566 0.4003E-03 0.8144E-05 apatite-OH 0.1770E-05 -5.752 0.8889E-03 -3.051 0.1310E-01 0.2825E-03 microcline 0.6813E-03 -3.167 0.1896 -0.722 2.794 0.7408E-01 pyrite 0.5767E-02 -2.239 0.6919 -0.160 10.20 0.1380 quartz 0.9377E-01 -1.028 5.633 0.751 83.01 2.127 barite 0.4765E-04 -4.322 0.1112E-01 -1.954 0.1639 0.2483E-02 chalcopyrite 0.3097E-03 -3.509 0.5683E-01 -1.245 0.8374 0.1327E-01 sphalerite 0.1543E-02 -2.812 0.1503 -0.823 2.215 0.3676E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2569E+00 0.2569E+00 1.0000 -0.590 phlogopite 0.7199E+00 0.7199E+00 1.0000 -0.143 biotite-Mn 0.2311E-01 0.2311E-01 1.0000 -1.636 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.786395 g Volume = 2.409989 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.95 -14.95 0.00 0.000 0.00000E+00 24 annite 1.02 1.02 0.00 0.000 -0.14373E-10 25 phlogopite 5.75 5.75 0.00 0.000 0.10146E-10 26 biotite-Mn 10.17 10.17 0.00 0.000 0.00000E+00 30 apatite-OH -53.78 -53.78 0.00 0.000 0.00000E+00 115 microcline -4.74 -4.74 0.00 0.000 -0.20292E-10 140 pyrite -22.01 -22.01 0.00 0.000 0.13528E-10 144 quartz -1.32 -1.32 0.00 0.000 0.00000E+00 237 barite -16.16 -16.16 0.00 0.000 0.00000E+00 240 chalcopyrite -23.69 -23.69 0.00 0.000 0.13528E-10 255 sphalerite -10.98 -10.98 0.00 0.000 -0.67640E-11 245 galena -9.95 -9.94 0.00 0.001 -0.11952E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 0.00 -0.26 -0.263 0.10005E+04 2.758 2 CO2,gas -10.10 -11.79 -1.69 -0.565 0.64485E+04 1.328 3 CH4,gas 6.84 -4.19 -11.03 -2.758 0.42007E+05 -8.011 4 H2,gas 5.98 1.90 -4.08 -2.330 0.15528E+05 -1.057 5 H2S,gas -8.42 -10.72 -2.31 -1.154 0.87899E+04 0.713 6 CO,gas -3.85 -9.89 -6.04 -1.859 0.23005E+05 -3.020 7 SO3,gas -7.65 -18.33 -10.68 -2.670 0.40664E+05 -7.658 8 O2,gas 16.91 -3.80 -20.71 -13.807 0.78860E+05 -17.689 9 HCl,gas -6.16 -7.69 -1.54 -0.768 0.58455E+04 -1.535 10 acmite 3.61 2.07 -1.54 -0.160 0.58811E+04 12 akimotoite 6.26 2.04 -4.22 -0.844 0.16067E+05 13 akimotoite-Fe 4.12 0.02 -4.10 -0.820 0.15607E+05 14 albite-high -4.13 -4.28 -0.15 -0.011 0.56477E+03 15 albite -4.13 -4.28 -0.15 -0.012 0.57181E+03 16 almandine -7.16 -9.25 -2.09 -0.104 0.79512E+04 17 pyrope -0.38 -3.19 -2.81 -0.141 0.10702E+05 18 analcite -1.98 -2.97 -0.99 -0.110 0.37781E+04 19 andalusite -10.00 -10.62 -0.62 -0.062 0.23574E+04 27 anorthite -7.67 -8.56 -0.89 -0.068 0.33848E+04 28 anthophyllite 15.08 12.96 -2.12 -0.057 0.80647E+04 29 anthophyllite-Fe 2.13 -1.19 -3.33 -0.090 0.12663E+05 31 apatite-OH-zs -51.59 -53.78 -2.19 -0.169 0.83566E+04 32 apatite-Cl-zs -58.21 -61.47 -3.27 -0.272 0.12439E+05 33 aragonite -4.71 -8.41 -3.71 -1.236 0.14125E+05 34 brucite 5.60 3.35 -2.25 -0.450 0.85676E+04 35 calcite -4.81 -8.41 -3.60 -1.201 0.13719E+05 36 carnegieite-low 0.15 -1.65 -1.80 -0.257 0.68552E+04 37 carnegieite-high 0.23 -1.65 -1.88 -0.269 0.71755E+04 38 carpholite-Mg -6.48 -8.58 -2.10 -0.140 0.80041E+04 39 carpholite-Fe -7.87 -10.61 -2.73 -0.182 0.10411E+05 40 celadonite -0.61 -2.71 -2.09 -0.123 0.79740E+04 41 celadonite-Fe -2.05 -4.73 -2.68 -0.158 0.10207E+05 42 chrysotile 9.79 7.43 -2.36 -0.196 0.89699E+04 44 clinochlore 4.90 3.52 -1.39 -0.043 0.52746E+04 45 daphnite -2.34 -6.59 -4.25 -0.133 0.16196E+05 47 chlorite-Al-free 19.74 14.86 -4.88 -0.203 0.18588E+05 48 chloritoid-Mg -5.85 -7.27 -1.42 -0.095 0.54125E+04 49 chloritoid-Fe -7.84 -9.29 -1.45 -0.097 0.55362E+04 50 chloritoid-Mn -5.69 -7.29 -1.60 -0.106 0.60757E+04 52 coesite -1.02 -1.32 -0.29 -0.098 0.11183E+04 53 cordierite-H -17.41 -18.48 -1.07 -0.038 0.40832E+04 54 cordierite-Fe -20.07 -22.52 -2.45 -0.084 0.93226E+04 55 cordierite-Mn -15.71 -18.52 -2.80 -0.097 0.10670E+05 56 corundum -8.51 -9.31 -0.80 -0.072 0.30360E+04 58 cristobalite -1.27 -1.32 -0.05 -0.016 0.18193E+03 59 cummingtonite 15.15 12.96 -2.19 -0.059 0.83260E+04 61 cymrite-K -2.41 -4.75 -2.33 -0.194 0.88868E+04 63 diaspore -3.76 -4.65 -0.89 -0.149 0.33970E+04 65 diopside 5.52 4.10 -1.41 -0.141 0.53749E+04 66 hedenbergite 4.06 2.08 -1.98 -0.198 0.75235E+04 68 eastonite -4.63 -6.03 -1.40 -0.054 0.53330E+04 69 enstatite 4.93 4.08 -0.85 -0.085 0.32340E+04 70 clinoenstatite-HiP 5.43 4.08 -1.35 -0.135 0.51422E+04 71 clinoenstatite 4.91 4.08 -0.83 -0.083 0.31679E+04 72 protoenstatite 5.06 4.08 -0.98 -0.098 0.37445E+04 73 epidote -3.58 -6.11 -2.53 -0.123 0.96331E+04 74 clinozoisite -8.18 -11.14 -2.97 -0.135 0.11294E+05 75 epidote-Fe 2.72 -1.08 -3.79 -0.197 0.14438E+05 76 fayalite 2.48 1.35 -1.13 -0.162 0.43158E+04 77 ferrosilite 1.27 0.04 -1.23 -0.123 0.46961E+04 78 forsterite 6.56 5.39 -1.17 -0.167 0.44471E+04 79 gedrite -7.46 -9.73 -2.27 -0.061 0.86496E+04 81 gibbsite -2.13 -4.65 -2.52 -0.361 0.96144E+04 82 glaucophane 1.91 -1.13 -3.04 -0.082 0.11595E+05 83 glaucophane-Fe -2.25 -7.20 -4.95 -0.134 0.18861E+05 84 goethite 1.28 0.38 -0.89 -0.193 0.34033E+04 86 greenalite 4.79 1.37 -3.43 -0.286 0.13053E+05 87 grunerite 2.70 -1.19 -3.89 -0.105 0.14816E+05 88 halite -1.34 -3.38 -2.04 -1.018 0.77490E+04 89 hematite 1.00 0.76 -0.24 -0.029 0.90612E+03 90 heulandite -11.85 -15.14 -3.29 -0.149 0.12523E+05 91 hercynite -6.63 -7.97 -1.34 -0.089 0.50985E+04 94 jadeite -1.29 -2.97 -1.67 -0.167 0.63769E+04 96 kalsilite -0.48 -2.11 -1.64 -0.234 0.62395E+04 97 kaolinite -9.11 -11.94 -2.83 -0.257 0.10780E+05 98 kyanite -9.84 -10.62 -0.78 -0.078 0.29864E+04 100 laumontite -7.42 -11.19 -3.77 -0.251 0.14356E+05 101 lawsonite -4.90 -8.56 -3.66 -0.244 0.13940E+05 102 leucite -2.45 -3.43 -0.98 -0.098 0.37132E+04 104 lizardite 9.95 7.43 -2.52 -0.210 0.96010E+04 105 magnesite -5.51 -8.44 -2.93 -0.977 0.11160E+05 106 magnetite 2.35 2.10 -0.25 -0.021 0.96903E+03 107 minnesotaite 0.90 -1.26 -2.17 -0.128 0.82561E+04 108 minnesotaite-Mg 7.00 4.80 -2.20 -0.129 0.83719E+04 109 magnesioferrite 5.48 4.12 -1.36 -0.111 0.51647E+04 111 manganosite 5.54 3.34 -2.20 -0.550 0.83778E+04 112 margarite -15.72 -17.86 -2.14 -0.086 0.81580E+04 116 monticellite 9.01 5.42 -3.59 -0.512 0.13660E+05 118 mullite-Si -9.24 -10.62 -1.38 -0.138 0.52546E+04 119 muscovite -13.13 -14.05 -0.93 -0.054 0.35237E+04 120 paragonite -12.44 -13.59 -1.15 -0.068 0.43741E+04 121 nepheline -0.15 -1.65 -1.50 -0.214 0.57050E+04 122 osumilite(2) -12.44 -14.51 -2.06 -0.043 0.78629E+04 123 osumilite-Fe -27.04 -29.90 -2.86 -0.060 0.10879E+05 124 pargasite 6.83 2.64 -4.19 -0.110 0.15944E+05 125 periclase 5.81 3.35 -2.45 -0.614 0.93458E+04 126 periclase-Fe 3.19 1.33 -1.85 -0.464 0.70603E+04 127 perovskite-Al -6.76 -9.31 -2.55 -0.232 0.96993E+04 132 phlogopite-Na 6.62 5.78 -0.84 -0.047 0.32119E+04 134 prehnite -2.94 -6.49 -3.55 -0.209 0.13513E+05 135 prehnite-Fe 2.05 -1.46 -3.51 -0.211 0.13361E+05 138 px-Mg-tschermaks -5.21 -7.27 -2.05 -0.147 0.78109E+04 139 px-Ca-tschermaks -4.44 -7.24 -2.80 -0.200 0.10652E+05 141 pyrrhotite -8.69 -9.39 -0.70 -0.232 0.26548E+04 142 pyrrhotiteFe0.875 -9.49 -9.79 -0.31 -0.112 0.11635E+04 143 pyrophyllite -13.08 -14.57 -1.49 -0.093 0.56616E+04 146 riebeckite 5.85 2.87 -2.98 -0.082 0.11354E+05 147 ringwoodite-Fe 3.49 1.35 -2.14 -0.305 0.81313E+04 148 ringwoodite-Mg 9.74 5.39 -4.35 -0.622 0.16566E+05 149 rhodochrosite -5.52 -8.46 -2.94 -0.980 0.11199E+05 150 rhodonite 2.58 2.02 -0.56 -0.112 0.21357E+04 151 sanidine -4.20 -4.74 -0.54 -0.042 0.20667E+04 153 siderite -7.39 -10.46 -3.07 -1.025 0.11705E+05 154 sillimanite -9.96 -10.62 -0.66 -0.066 0.25042E+04 156 spinel -4.42 -5.95 -1.53 -0.102 0.58210E+04 163 stilpnomelane-Mg 0.98 -1.13 -2.11 -0.063 0.80482E+04 164 stishovite 1.67 -1.32 -2.98 -0.994 0.11354E+05 165 sudoite-Fe -15.28 -19.90 -4.62 -0.149 0.17596E+05 166 sudoite -12.99 -15.85 -2.86 -0.092 0.10893E+05 167 sulfur -11.13 -12.62 -1.49 -0.459 0.56769E+04 168 sylvite -1.25 -3.84 -2.59 -1.296 0.98697E+04 169 talc 5.26 4.80 -0.46 -0.027 0.17385E+04 170 talc-Fe 2.32 -1.26 -3.59 -0.211 0.13658E+05 171 talc-tschermaks -4.81 -6.54 -1.74 -0.102 0.66101E+04 173 tephroite 6.74 5.36 -1.39 -0.198 0.52870E+04 176 topaz-H -7.91 -10.62 -2.72 -0.247 0.10343E+05 177 tremolite 15.64 13.01 -2.63 -0.071 0.10029E+05 179 troilite-low -8.60 -9.39 -0.79 -0.263 0.29999E+04 180 tschermakite -6.11 -9.68 -3.57 -0.096 0.13585E+05 183 wadsleyite-Fe 3.34 1.35 -1.99 -0.284 0.75790E+04 184 wadsleyite-Mg 8.80 5.39 -3.40 -0.486 0.12955E+05 185 wairakite -9.30 -11.19 -1.89 -0.111 0.71930E+04 186 walstromite 4.65 2.06 -2.59 -0.518 0.98607E+04 187 wollastonite 4.23 2.06 -2.16 -0.433 0.82359E+04 188 pseudo-wollastonite 4.35 2.06 -2.28 -0.456 0.86897E+04 189 zoisite -8.23 -11.14 -2.92 -0.133 0.11101E+05 192 beidellite-Ca -13.26 -15.11 -1.85 -0.115 0.70606E+04 193 beidellite-H -13.29 -15.67 -2.38 -0.152 0.90459E+04 194 beidellite-K -12.25 -14.40 -2.15 -0.132 0.81795E+04 195 beidellite-Mg -13.51 -15.12 -1.61 -0.100 0.61262E+04 196 beidellite-Na -12.19 -14.24 -2.05 -0.126 0.78198E+04 197 bornite -55.32 -55.63 -0.31 -0.023 0.11834E+04 199 chalcocite -14.50 -15.97 -1.47 -0.368 0.56099E+04 200 covellite -12.93 -14.30 -1.36 -0.520 0.51945E+04 202 montmorillonite-Ca -9.99 -11.37 -1.38 -0.085 0.52519E+04 203 montmorillonite-K -9.26 -10.65 -1.39 -0.085 0.53071E+04 204 montmorillonite-Mg -10.20 -11.37 -1.17 -0.073 0.44629E+04 205 montmorillonite-Na -8.93 -10.50 -1.58 -0.096 0.59994E+04 206 nontronite-Ca -3.48 -5.04 -1.56 -0.101 0.59346E+04 207 nontronite-H -3.53 -5.60 -2.07 -0.139 0.78905E+04 208 nontronite-K -2.48 -4.33 -1.85 -0.119 0.70458E+04 209 nontronite-Mg -3.70 -5.05 -1.35 -0.087 0.51287E+04 210 nontronite-Na -2.42 -4.17 -1.76 -0.113 0.66979E+04 215 gypsum -12.69 -14.95 -2.26 -0.565 0.86028E+04 231 acanthite -14.24 -19.16 -4.92 -1.231 0.18748E+05 232 alabandite -6.42 -7.39 -0.97 -0.323 0.36856E+04 234 anglesite -15.24 -17.55 -2.30 -1.151 0.87686E+04 238 boehmite -3.46 -4.65 -1.19 -0.198 0.45297E+04 242 copper,native 1.72 -1.67 -3.39 -1.179 0.12906E+05 244 ferrous-oxide 2.25 1.33 -0.92 -0.230 0.35084E+04 246 silver,native 0.43 -3.27 -3.70 -1.286 0.14080E+05 248 litharge 5.37 0.78 -4.59 -1.147 0.17473E+05 256 wurtzite -10.17 -10.98 -0.81 -0.270 0.30887E+04 257 zincite 2.33 -0.26 -2.59 -0.648 0.98771E+04 258 an20ab80 -5.06 -5.14 -0.08 -0.006 0.30624E+03 259 an25ab75 -5.26 -5.35 -0.09 -0.007 0.34631E+03 260 an30ab70 -5.46 -5.56 -0.11 -0.008 0.40674E+03 261 tr.625ac.25prg.125 10.32 9.19 -1.13 -0.030 0.42992E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 26 Loop limit = 500 Temperature = 559.00 C Pressure = 1050.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5513E+02 kg liquid = 0.9931E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9968 Stoichiometric ionic strength = .3274832E+01 Osmotic coef. = 0.0000 True ionic strength = .1454026E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.45518E-05 -5.3418 0.94021E-06 -6.0268 0.20656E+00 -0.6850 2 H2O 0.99683E+00 -0.0014 0.99683E+00 -0.0014 3 Cl- 0.12194E+00 -0.9138 0.21494E-01 -1.6677 0.17627E+00 -0.7538 4 SO4-- 0.23563E-03 -3.6278 0.53233E-06 -6.2738 0.22592E-02 -2.6460 5 HCO3- 0.89859E-05 -5.0464 0.17032E-05 -5.7687 0.18954E+00 -0.7223 6 HS- 0.11314E-03 -3.9464 0.20105E-04 -4.6967 0.17769E+00 -0.7503 7 H4SiO4 0.48105E-01 -1.3178 0.48105E-01 -1.3178 0.10000E+01 0.0000 8 Al+++ 0.21155E-16 -16.6746 0.18577E-22 -22.7310 0.87814E-06 -6.0564 9 Ca++ 0.11713E-05 -5.9313 0.21253E-08 -8.6726 0.18145E-02 -2.7412 10 Mg++ 0.13408E-05 -5.8726 0.20068E-08 -8.6975 0.14967E-02 -2.8249 11 Fe++ 0.12140E-07 -7.9158 0.19077E-10 -10.7195 0.15715E-02 -2.8037 12 K+ 0.34598E-01 -1.4609 0.67139E-02 -2.1730 0.19406E+00 -0.7121 13 Na+ 0.10914E+00 -0.9620 0.19445E-01 -1.7112 0.17816E+00 -0.7492 14 Mn++ 0.11782E-05 -5.9288 0.19187E-08 -8.7170 0.16285E-02 -2.7882 15 Zn++ 0.31084E-09 -9.5075 0.48848E-12 -12.3112 0.15715E-02 -2.8037 16 Cu+ 0.12579E-07 -7.9004 0.22353E-08 -8.6507 0.17770E+00 -0.7503 17 Pb++ 0.26103E-08 -8.5833 0.52995E-11 -11.2758 0.20302E-02 -2.6925 18 Ag+ 0.29763E-09 -9.5263 0.56868E-10 -10.2451 0.19107E+00 -0.7188 19 Ba++ 0.59202E-07 -7.2277 0.12906E-09 -9.8892 0.21800E-02 -2.6616 20 HPO4-- 0.13671E-08 -8.8642 0.31040E-11 -11.5081 0.22705E-02 -2.6439 21 HSiO3- 0.13267E-05 -5.8772 0.23385E-06 -6.6311 0.17627E+00 -0.7538 22 Ca(HSiO3)+ 0.42570E-08 -8.3709 0.83328E-09 -9.0792 0.19574E+00 -0.7083 23 Mg(HSiO3)+ 0.12940E-08 -8.8881 0.25328E-09 -9.5964 0.19574E+00 -0.7083 24 NaHSiO3,aq 0.19038E-05 -5.7204 0.19038E-05 -5.7204 0.10000E+01 0.0000 28 AgCl,aq 0.12115E-06 -6.9167 0.12115E-06 -6.9167 0.10000E+01 0.0000 29 AgCl2- 0.53743E-05 -5.2697 0.94730E-06 -6.0235 0.17627E+00 -0.7538 30 AgCl3-2 0.17324E-05 -5.7614 0.36255E-08 -8.4406 0.20928E-02 -2.6793 31 AgCl4-3 0.15238E-05 -5.8171 0.11767E-11 -11.9294 0.77220E-06 -6.1123 34 Ag(HS),aq 0.20406E-08 -8.6902 0.20406E-08 -8.6902 0.10000E+01 0.0000 35 Ag(HS)2- 0.70636E-08 -8.1510 0.12451E-08 -8.9048 0.17627E+00 -0.7538 36 AlO+ 0.10071E-10 -10.9969 0.19713E-11 -11.7052 0.19574E+00 -0.7083 38 HAlO2,aq 0.41239E-08 -8.3847 0.41239E-08 -8.3847 0.10000E+01 0.0000 39 AlO2- 0.10977E-04 -4.9595 0.17034E-05 -5.7687 0.15518E+00 -0.8092 41 Ba(HCO3)+ 0.19166E-06 -6.7175 0.39020E-07 -7.4087 0.20359E+00 -0.6912 42 BaCl+ 0.75205E-05 -5.1238 0.14721E-05 -5.8321 0.19574E+00 -0.7083 43 CH4,aq 0.14639E-08 -8.8345 0.17358E-08 -8.7605 0.11857E+01 0.0740 48 CO,aq 0.49819E-03 -3.3026 0.49819E-03 -3.3026 0.10000E+01 0.0000 49 CO2,aq 0.26740E+01 0.4272 0.31705E+01 0.5011 0.11857E+01 0.0740 50 CO3-2 0.36229E-10 -10.4409 0.75821E-13 -13.1202 0.20928E-02 -2.6793 52 Ca(HCO3)+ 0.91314E-07 -7.0395 0.17874E-07 -7.7478 0.19574E+00 -0.7083 53 CaCl+ 0.68396E-04 -4.1650 0.13388E-04 -4.8733 0.19574E+00 -0.7083 54 CaCl2,aq 0.73533E-04 -4.1335 0.73533E-04 -4.1335 0.10000E+01 0.0000 55 CaOH+ 0.13005E-06 -6.8859 0.25457E-07 -7.5942 0.19574E+00 -0.7083 56 CaSO4,aq 0.17181E-06 -6.7650 0.17181E-06 -6.7650 0.10000E+01 0.0000 57 HCl,aq 0.33050E-02 -2.4808 0.33050E-02 -2.4808 0.10000E+01 0.0000 66 CuCl,aq 0.20861E-04 -4.6807 0.20861E-04 -4.6807 0.10000E+01 0.0000 67 CuCl2- 0.68446E-04 -4.1646 0.12065E-04 -4.9185 0.17627E+00 -0.7538 68 CuCl3-2 0.12087E-05 -5.9177 0.25295E-08 -8.5970 0.20928E-02 -2.6793 74 FeCl+ 0.22093E-06 -6.6557 0.43246E-07 -7.3641 0.19574E+00 -0.7083 75 FeCl2,aq 0.27070E-02 -2.5675 0.27070E-02 -2.5675 0.10000E+01 0.0000 77 FeO,aq 0.55689E-07 -7.2542 0.55689E-07 -7.2542 0.10000E+01 0.0000 78 FeOH+ 0.18656E-07 -7.7292 0.36518E-08 -8.4375 0.19574E+00 -0.7083 79 HFeO2- 0.61042E-08 -8.2144 0.10760E-08 -8.9682 0.17627E+00 -0.7538 82 FeO2- 0.38201E-08 -8.4179 0.67334E-09 -9.1718 0.17627E+00 -0.7538 83 HFeO2,aq 0.27804E-09 -9.5559 0.27804E-09 -9.5559 0.10000E+01 0.0000 84 H2,aq 0.44417E-02 -2.3525 0.52665E-02 -2.2785 0.11857E+01 0.0740 85 KCl,aq 0.72491E-01 -1.1397 0.72491E-01 -1.1397 0.10000E+01 0.0000 86 KHSO4,aq 0.13718E-01 -1.8627 0.13718E-01 -1.8627 0.10000E+01 0.0000 87 KOH,aq 0.13936E-05 -5.8559 0.13936E-05 -5.8559 0.10000E+01 0.0000 88 KSO4- 0.47805E-02 -2.3205 0.84263E-03 -3.0744 0.17627E+00 -0.7538 90 Mg(HCO3)+ 0.29092E-07 -7.5362 0.56947E-08 -8.2445 0.19574E+00 -0.7083 91 MgCl+ 0.13899E-04 -4.8570 0.27207E-05 -5.5653 0.19574E+00 -0.7083 92 MgOH+ 0.52954E-06 -6.2761 0.10365E-06 -6.9844 0.19574E+00 -0.7083 94 MnO,aq 0.95877E-07 -7.0183 0.95877E-07 -7.0183 0.10000E+01 0.0000 95 MnOH+ 0.20607E-06 -6.6860 0.40336E-07 -7.3943 0.19574E+00 -0.7083 97 HMnO2- 0.41518E-10 -10.3818 0.73182E-11 -11.1356 0.17627E+00 -0.7538 100 MnCl+ 0.11556E-02 -2.9372 0.22621E-03 -3.6455 0.19574E+00 -0.7083 101 MnSO4,aq 0.16747E-06 -6.7761 0.16747E-06 -6.7761 0.10000E+01 0.0000 102 NaCl,aq 0.44928E+00 -0.3475 0.44928E+00 -0.3475 0.10000E+01 0.0000 103 NaOH,aq 0.18453E-05 -5.7339 0.18453E-05 -5.7339 0.10000E+01 0.0000 105 OH- 0.71285E-05 -5.1470 0.11062E-05 -5.9562 0.15518E+00 -0.8092 111 H3PO3,aq 0.11719E-09 -9.9311 0.11719E-09 -9.9311 0.10000E+01 0.0000 112 H2PO3- 0.18111E-08 -8.7421 0.31923E-09 -9.4959 0.17627E+00 -0.7538 113 H3PO4,aq 0.14158E-05 -5.8490 0.14158E-05 -5.8490 0.10000E+01 0.0000 114 H2PO4- 0.13847E-05 -5.8587 0.25627E-06 -6.5913 0.18508E+00 -0.7326 116 H4P2O7,aq 0.18664E-09 -9.7290 0.18664E-09 -9.7290 0.10000E+01 0.0000 117 H3P2O7- 0.90647E-09 -9.0426 0.15978E-09 -9.7965 0.17627E+00 -0.7538 118 H2P2O7-2 0.21428E-06 -6.6690 0.44845E-09 -9.3483 0.20928E-02 -2.6793 119 HP2O7-3 0.23432E-07 -7.6302 0.18094E-13 -13.7425 0.77220E-06 -6.1123 121 PbCl+ 0.11812E-05 -5.9277 0.23121E-06 -6.6360 0.19574E+00 -0.7083 122 PbCl2,aq 0.86125E-04 -4.0649 0.86125E-04 -4.0649 0.10000E+01 0.0000 123 PbCl3- 0.96343E-04 -4.0162 0.16982E-04 -4.7700 0.17627E+00 -0.7538 124 PbCl4-2 0.15800E-04 -4.8013 0.33066E-07 -7.4806 0.20928E-02 -2.6793 125 PbO,aq 0.67237E-08 -8.1724 0.67237E-08 -8.1724 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12684E-03 -3.8968 0.12684E-03 -3.8968 0.10000E+01 0.0000 128 Pb(HS)3- 0.13783E-04 -4.8607 0.24294E-05 -5.6145 0.17627E+00 -0.7538 129 H2S,aq 0.10586E+01 0.0247 0.12552E+01 0.0987 0.11857E+01 0.0740 130 S2-2 0.11598E-07 -7.9356 0.24273E-10 -10.6149 0.20928E-02 -2.6793 131 S3-2 0.10784E-08 -8.9672 0.22569E-11 -11.6465 0.20928E-02 -2.6793 132 S3- 0.93495E-02 -2.0292 0.16480E-02 -2.7830 0.17627E+00 -0.7538 133 S4-2 0.85253E-10 -10.0693 0.17842E-12 -12.7486 0.20928E-02 -2.6793 135 SO2,aq 0.29344E+00 -0.5325 0.29344E+00 -0.5325 0.10000E+01 0.0000 136 SO3-2 0.62444E-09 -9.2045 0.20677E-11 -11.6845 0.33113E-02 -2.4800 137 HSO3- 0.23459E-03 -3.6297 0.41351E-04 -4.3835 0.17627E+00 -0.7538 138 HSO4- 0.79490E-02 -2.0997 0.15985E-02 -2.7963 0.20109E+00 -0.6966 140 S2O3-2 0.49109E-06 -6.3088 0.10278E-08 -8.9881 0.20928E-02 -2.6793 141 HS2O3- 0.35659E-06 -6.4478 0.62855E-07 -7.2017 0.17627E+00 -0.7538 142 H2S2O3,aq 0.35062E-07 -7.4552 0.35062E-07 -7.4552 0.10000E+01 0.0000 150 S4O6-2 0.41864E-09 -9.3782 0.87614E-12 -12.0574 0.20928E-02 -2.6793 152 ZnCl+ 0.13637E-03 -3.8653 0.26693E-04 -4.5736 0.19574E+00 -0.7083 153 ZnCl2,aq 0.58521E-03 -3.2327 0.58521E-03 -3.2327 0.10000E+01 0.0000 154 ZnCl3- 0.39283E-04 -4.4058 0.69242E-05 -5.1596 0.17627E+00 -0.7538 155 ZnO,aq 0.27376E-07 -7.5626 0.27376E-07 -7.5626 0.10000E+01 0.0000 156 ZnOH+ 0.94866E-06 -6.0229 0.18569E-06 -6.7312 0.19574E+00 -0.7083 158 HZnO2- 0.19606E-09 -9.7076 0.34558E-10 -10.4615 0.17627E+00 -0.7538 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4551776E-05 0.4294972E+01 0.3542393E+04 0.0000 2 H2O 0.1000000E+01 0.5252145E+02 0.7742477E+06 0.0000 3 Cl- 0.1219429E+00 0.6559631E+00 0.1902979E+05 4.3591 4 SO4-- 0.2356272E-03 0.2515448E+00 0.1977274E+05 5.7797 5 HCO3- 0.8985865E-05 0.2674470E+01 0.1335340E+06 0.2580 6 HS- 0.1131445E-03 0.1155860E+01 0.3128006E+05 1.3301 7 H4SiO4 0.4810528E-01 0.4810852E-01 0.3783700E+04 -1.3178 8 Al+++ 0.2115484E-16 0.1098122E-04 0.2424478E+00 -4.6507 9 Ca++ 0.1171272E-05 0.1434974E-03 0.4705999E+01 3.3810 10 Mg++ 0.1340765E-05 0.1579999E-04 0.3143253E+00 3.3560 11 Fe++ 0.1213961E-07 0.2707321E-02 0.1237204E+03 1.3341 12 K+ 0.3459803E-01 0.1255885E+00 0.4018376E+04 3.8538 13 Na+ 0.1091449E+00 0.5584323E+00 0.1050528E+05 4.3156 14 Mn++ 0.1178229E-05 0.1157283E-02 0.5202526E+02 3.3366 15 Zn++ 0.3108413E-09 0.7618390E-03 0.4075148E+02 -0.2576 16 Cu+ 0.1257907E-07 0.9052872E-04 0.4706903E+01 -2.6239 17 Pb++ 0.2610335E-08 0.3400767E-03 0.5765638E+02 0.7778 18 Ag+ 0.2976319E-09 0.8760976E-05 0.7733122E+00 -4.2184 19 Ba++ 0.5920150E-07 0.7771381E-05 0.8733674E+00 2.1643 20 HPO4-- 0.1367105E-08 0.3281366E-05 0.2577108E+00 0.5455 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265492E+01 -.3129973E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5216095E+02 -.1961751E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2498182E+00 0.1904550E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1147927E+01 0.1221728E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4777831E-01 0.9581601E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1090585E-04 0.6836337E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1425125E-03 0.3853974E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1569154E-04 0.4985107E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2688738E-02 0.6078015E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247265E+00 0.6836337E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149340E-02 0.1600138E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7566098E-03 0.1542725E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.8990735E-04 0.3097024E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3377425E-03 0.2430155E-05 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7718040E-05 0.4765441E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3258844E-05 0.5308657E-05 0.0000000E+00 Chg. balance for solid moles: 0.1638E-17 Mass of aqueous solution: 0.121369E+04 g Temperature = 559.00 C Pressure = 1050.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3765E-03 -3.424 0.5126E-01 -1.290 0.7553 0.1730E-01 annite 0.5931E-06 -6.227 0.3036E-03 -3.518 0.4473E-02 0.9152E-04 phlogopite 0.1662E-05 -5.779 0.6934E-03 -3.159 0.1022E-01 0.2486E-03 biotite-Mn 0.5334E-07 -7.273 0.2716E-04 -4.566 0.4001E-03 0.8141E-05 apatite-OH 0.1770E-05 -5.752 0.8889E-03 -3.051 0.1310E-01 0.2825E-03 microcline 0.6813E-03 -3.167 0.1896 -0.722 2.794 0.7408E-01 pyrite 0.5767E-02 -2.239 0.6919 -0.160 10.19 0.1380 quartz 0.9377E-01 -1.028 5.633 0.751 83.00 2.127 barite 0.4765E-04 -4.322 0.1112E-01 -1.954 0.1639 0.2483E-02 chalcopyrite 0.3097E-03 -3.509 0.5683E-01 -1.245 0.8373 0.1327E-01 sphalerite 0.1543E-02 -2.812 0.1503 -0.823 2.215 0.3676E-01 galena 0.2430E-05 -5.614 0.5814E-03 -3.236 0.8567E-02 0.7652E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2569E+00 0.2569E+00 1.0000 -0.590 phlogopite 0.7199E+00 0.7199E+00 1.0000 -0.143 biotite-Mn 0.2311E-01 0.2311E-01 1.0000 -1.636 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.786935 g Volume = 2.410056 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.95 -14.95 0.00 0.000 0.00000E+00 24 annite 1.02 1.02 0.00 0.000 -0.36356E-10 25 phlogopite 5.75 5.75 0.00 0.000 -0.16910E-10 26 biotite-Mn 10.17 10.17 0.00 0.000 -0.27056E-10 30 apatite-OH -53.78 -53.78 0.00 0.000 -0.27056E-10 115 microcline -4.74 -4.74 0.00 0.000 0.67640E-11 140 pyrite -22.01 -22.01 0.00 0.000 -0.13528E-10 144 quartz -1.32 -1.32 0.00 0.000 0.84550E-12 237 barite -16.16 -16.16 0.00 0.000 0.00000E+00 240 chalcopyrite -23.69 -23.69 0.00 0.000 -0.27056E-10 245 galena -9.95 -9.95 0.00 0.000 0.00000E+00 255 sphalerite -10.98 -10.98 0.00 0.000 -0.67640E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 0.00 -0.26 -0.263 0.10005E+04 2.758 2 CO2,gas -10.10 -11.79 -1.69 -0.565 0.64485E+04 1.328 3 CH4,gas 6.84 -4.19 -11.03 -2.758 0.42007E+05 -8.011 4 H2,gas 5.98 1.90 -4.08 -2.330 0.15528E+05 -1.057 5 H2S,gas -8.42 -10.72 -2.31 -1.154 0.87899E+04 0.713 6 CO,gas -3.85 -9.89 -6.04 -1.859 0.23005E+05 -3.020 7 SO3,gas -7.65 -18.33 -10.68 -2.670 0.40664E+05 -7.658 8 O2,gas 16.91 -3.80 -20.71 -13.807 0.78860E+05 -17.689 9 HCl,gas -6.16 -7.69 -1.54 -0.768 0.58454E+04 -1.535 10 acmite 3.61 2.07 -1.54 -0.160 0.58811E+04 12 akimotoite 6.26 2.04 -4.22 -0.844 0.16067E+05 13 akimotoite-Fe 4.12 0.02 -4.10 -0.820 0.15607E+05 14 albite-high -4.13 -4.28 -0.15 -0.011 0.56479E+03 15 albite -4.13 -4.28 -0.15 -0.012 0.57182E+03 16 almandine -7.16 -9.25 -2.09 -0.104 0.79511E+04 17 pyrope -0.38 -3.19 -2.81 -0.141 0.10702E+05 18 analcite -1.98 -2.97 -0.99 -0.110 0.37781E+04 19 andalusite -10.00 -10.62 -0.62 -0.062 0.23572E+04 27 anorthite -7.67 -8.56 -0.89 -0.068 0.33847E+04 28 anthophyllite 15.08 12.96 -2.12 -0.057 0.80647E+04 29 anthophyllite-Fe 2.13 -1.19 -3.33 -0.090 0.12663E+05 31 apatite-OH-zs -51.59 -53.78 -2.19 -0.169 0.83566E+04 32 apatite-Cl-zs -58.21 -61.47 -3.27 -0.272 0.12439E+05 33 aragonite -4.71 -8.41 -3.71 -1.236 0.14125E+05 34 brucite 5.60 3.35 -2.25 -0.450 0.85676E+04 35 calcite -4.81 -8.41 -3.60 -1.201 0.13719E+05 36 carnegieite-low 0.15 -1.65 -1.80 -0.257 0.68553E+04 37 carnegieite-high 0.23 -1.65 -1.88 -0.269 0.71755E+04 38 carpholite-Mg -6.48 -8.58 -2.10 -0.140 0.80039E+04 39 carpholite-Fe -7.87 -10.61 -2.73 -0.182 0.10411E+05 40 celadonite -0.61 -2.71 -2.09 -0.123 0.79740E+04 41 celadonite-Fe -2.05 -4.73 -2.68 -0.158 0.10207E+05 42 chrysotile 9.79 7.43 -2.36 -0.196 0.89699E+04 44 clinochlore 4.90 3.52 -1.39 -0.043 0.52744E+04 45 daphnite -2.34 -6.59 -4.25 -0.133 0.16196E+05 47 chlorite-Al-free 19.74 14.86 -4.88 -0.203 0.18588E+05 48 chloritoid-Mg -5.85 -7.27 -1.42 -0.095 0.54123E+04 49 chloritoid-Fe -7.84 -9.29 -1.45 -0.097 0.55361E+04 50 chloritoid-Mn -5.69 -7.29 -1.60 -0.106 0.60757E+04 52 coesite -1.02 -1.32 -0.29 -0.098 0.11183E+04 53 cordierite-H -17.41 -18.48 -1.07 -0.038 0.40830E+04 54 cordierite-Fe -20.07 -22.52 -2.45 -0.084 0.93224E+04 55 cordierite-Mn -15.71 -18.52 -2.80 -0.097 0.10670E+05 56 corundum -8.51 -9.31 -0.80 -0.072 0.30358E+04 58 cristobalite -1.27 -1.32 -0.05 -0.016 0.18193E+03 59 cummingtonite 15.15 12.96 -2.19 -0.059 0.83260E+04 61 cymrite-K -2.41 -4.75 -2.33 -0.194 0.88868E+04 63 diaspore -3.76 -4.65 -0.89 -0.149 0.33969E+04 65 diopside 5.52 4.10 -1.41 -0.141 0.53749E+04 66 hedenbergite 4.06 2.08 -1.98 -0.198 0.75235E+04 68 eastonite -4.63 -6.03 -1.40 -0.054 0.53329E+04 69 enstatite 4.93 4.08 -0.85 -0.085 0.32340E+04 70 clinoenstatite-HiP 5.43 4.08 -1.35 -0.135 0.51422E+04 71 clinoenstatite 4.91 4.08 -0.83 -0.083 0.31679E+04 72 protoenstatite 5.06 4.08 -0.98 -0.098 0.37445E+04 73 epidote -3.58 -6.11 -2.53 -0.123 0.96330E+04 74 clinozoisite -8.18 -11.14 -2.97 -0.135 0.11294E+05 75 epidote-Fe 2.72 -1.08 -3.79 -0.197 0.14438E+05 76 fayalite 2.48 1.35 -1.13 -0.162 0.43159E+04 77 ferrosilite 1.27 0.04 -1.23 -0.123 0.46962E+04 78 forsterite 6.56 5.39 -1.17 -0.167 0.44471E+04 79 gedrite -7.46 -9.73 -2.27 -0.061 0.86493E+04 81 gibbsite -2.13 -4.65 -2.52 -0.361 0.96143E+04 82 glaucophane 1.91 -1.13 -3.04 -0.082 0.11595E+05 83 glaucophane-Fe -2.25 -7.20 -4.95 -0.134 0.18861E+05 84 goethite 1.28 0.38 -0.89 -0.193 0.34033E+04 86 greenalite 4.79 1.37 -3.43 -0.286 0.13053E+05 87 grunerite 2.70 -1.19 -3.89 -0.105 0.14816E+05 88 halite -1.34 -3.38 -2.04 -1.018 0.77489E+04 89 hematite 1.00 0.76 -0.24 -0.029 0.90612E+03 90 heulandite -11.85 -15.14 -3.29 -0.149 0.12523E+05 91 hercynite -6.63 -7.97 -1.34 -0.089 0.50984E+04 94 jadeite -1.29 -2.97 -1.67 -0.167 0.63770E+04 96 kalsilite -0.48 -2.11 -1.64 -0.234 0.62395E+04 97 kaolinite -9.11 -11.94 -2.83 -0.257 0.10780E+05 98 kyanite -9.84 -10.62 -0.78 -0.078 0.29862E+04 100 laumontite -7.42 -11.19 -3.77 -0.251 0.14356E+05 101 lawsonite -4.90 -8.56 -3.66 -0.244 0.13940E+05 102 leucite -2.45 -3.43 -0.98 -0.098 0.37132E+04 104 lizardite 9.95 7.43 -2.52 -0.210 0.96010E+04 105 magnesite -5.51 -8.44 -2.93 -0.977 0.11160E+05 106 magnetite 2.35 2.10 -0.25 -0.021 0.96904E+03 107 minnesotaite 0.90 -1.26 -2.17 -0.128 0.82561E+04 108 minnesotaite-Mg 7.00 4.80 -2.20 -0.129 0.83719E+04 109 magnesioferrite 5.48 4.12 -1.36 -0.111 0.51647E+04 111 manganosite 5.54 3.34 -2.20 -0.550 0.83780E+04 112 margarite -15.72 -17.86 -2.14 -0.086 0.81577E+04 116 monticellite 9.01 5.42 -3.59 -0.512 0.13660E+05 118 mullite-Si -9.24 -10.62 -1.38 -0.138 0.52544E+04 119 muscovite -13.13 -14.05 -0.93 -0.054 0.35236E+04 120 paragonite -12.44 -13.59 -1.15 -0.068 0.43740E+04 121 nepheline -0.15 -1.65 -1.50 -0.214 0.57050E+04 122 osumilite(2) -12.44 -14.51 -2.06 -0.043 0.78627E+04 123 osumilite-Fe -27.04 -29.90 -2.86 -0.060 0.10879E+05 124 pargasite 6.83 2.64 -4.19 -0.110 0.15944E+05 125 periclase 5.81 3.35 -2.45 -0.614 0.93458E+04 126 periclase-Fe 3.19 1.33 -1.85 -0.464 0.70603E+04 127 perovskite-Al -6.76 -9.31 -2.55 -0.232 0.96992E+04 132 phlogopite-Na 6.62 5.78 -0.84 -0.047 0.32119E+04 134 prehnite -2.94 -6.49 -3.55 -0.209 0.13513E+05 135 prehnite-Fe 2.05 -1.46 -3.51 -0.211 0.13361E+05 138 px-Mg-tschermaks -5.21 -7.27 -2.05 -0.147 0.78108E+04 139 px-Ca-tschermaks -4.44 -7.24 -2.80 -0.200 0.10652E+05 141 pyrrhotite -8.69 -9.39 -0.70 -0.232 0.26548E+04 142 pyrrhotiteFe0.875 -9.49 -9.79 -0.31 -0.112 0.11635E+04 143 pyrophyllite -13.08 -14.57 -1.49 -0.093 0.56615E+04 146 riebeckite 5.85 2.87 -2.98 -0.082 0.11354E+05 147 ringwoodite-Fe 3.49 1.35 -2.14 -0.305 0.81313E+04 148 ringwoodite-Mg 9.74 5.39 -4.35 -0.622 0.16566E+05 149 rhodochrosite -5.52 -8.46 -2.94 -0.980 0.11199E+05 150 rhodonite 2.58 2.02 -0.56 -0.112 0.21359E+04 151 sanidine -4.20 -4.74 -0.54 -0.042 0.20667E+04 153 siderite -7.39 -10.46 -3.07 -1.025 0.11705E+05 154 sillimanite -9.96 -10.62 -0.66 -0.066 0.25040E+04 156 spinel -4.42 -5.95 -1.53 -0.102 0.58209E+04 163 stilpnomelane-Mg 0.98 -1.13 -2.11 -0.063 0.80481E+04 164 stishovite 1.67 -1.32 -2.98 -0.994 0.11354E+05 165 sudoite-Fe -15.28 -19.90 -4.62 -0.149 0.17595E+05 166 sudoite -12.99 -15.85 -2.86 -0.092 0.10893E+05 167 sulfur -11.13 -12.62 -1.49 -0.459 0.56769E+04 168 sylvite -1.25 -3.84 -2.59 -1.296 0.98697E+04 169 talc 5.26 4.80 -0.46 -0.027 0.17384E+04 170 talc-Fe 2.32 -1.26 -3.59 -0.211 0.13658E+05 171 talc-tschermaks -4.81 -6.54 -1.74 -0.102 0.66099E+04 173 tephroite 6.74 5.36 -1.39 -0.198 0.52872E+04 176 topaz-H -7.91 -10.62 -2.72 -0.247 0.10343E+05 177 tremolite 15.64 13.01 -2.63 -0.071 0.10029E+05 179 troilite-low -8.60 -9.39 -0.79 -0.263 0.29999E+04 180 tschermakite -6.11 -9.68 -3.57 -0.096 0.13585E+05 183 wadsleyite-Fe 3.34 1.35 -1.99 -0.284 0.75790E+04 184 wadsleyite-Mg 8.80 5.39 -3.40 -0.486 0.12955E+05 185 wairakite -9.30 -11.19 -1.89 -0.111 0.71929E+04 186 walstromite 4.65 2.06 -2.59 -0.518 0.98607E+04 187 wollastonite 4.23 2.06 -2.16 -0.433 0.82359E+04 188 pseudo-wollastonite 4.35 2.06 -2.28 -0.456 0.86897E+04 189 zoisite -8.23 -11.14 -2.92 -0.133 0.11101E+05 192 beidellite-Ca -13.26 -15.11 -1.85 -0.115 0.70605E+04 193 beidellite-H -13.29 -15.67 -2.38 -0.152 0.90457E+04 194 beidellite-K -12.25 -14.40 -2.15 -0.132 0.81793E+04 195 beidellite-Mg -13.51 -15.12 -1.61 -0.100 0.61261E+04 196 beidellite-Na -12.19 -14.24 -2.05 -0.126 0.78197E+04 197 bornite -55.32 -55.63 -0.31 -0.023 0.11834E+04 199 chalcocite -14.50 -15.97 -1.47 -0.368 0.56099E+04 200 covellite -12.93 -14.30 -1.36 -0.520 0.51945E+04 202 montmorillonite-Ca -9.99 -11.37 -1.38 -0.085 0.52518E+04 203 montmorillonite-K -9.26 -10.65 -1.39 -0.085 0.53070E+04 204 montmorillonite-Mg -10.20 -11.37 -1.17 -0.073 0.44628E+04 205 montmorillonite-Na -8.93 -10.50 -1.58 -0.096 0.59993E+04 206 nontronite-Ca -3.48 -5.04 -1.56 -0.101 0.59346E+04 207 nontronite-H -3.53 -5.60 -2.07 -0.139 0.78905E+04 208 nontronite-K -2.48 -4.33 -1.85 -0.119 0.70458E+04 209 nontronite-Mg -3.70 -5.05 -1.35 -0.087 0.51287E+04 210 nontronite-Na -2.42 -4.17 -1.76 -0.113 0.66979E+04 215 gypsum -12.69 -14.95 -2.26 -0.565 0.86028E+04 231 acanthite -14.24 -19.16 -4.92 -1.231 0.18748E+05 232 alabandite -6.42 -7.39 -0.97 -0.323 0.36857E+04 234 anglesite -15.24 -17.55 -2.31 -1.153 0.87805E+04 238 boehmite -3.46 -4.65 -1.19 -0.198 0.45296E+04 242 copper,native 1.72 -1.67 -3.39 -1.179 0.12906E+05 244 ferrous-oxide 2.25 1.33 -0.92 -0.230 0.35084E+04 246 silver,native 0.43 -3.27 -3.70 -1.286 0.14080E+05 248 litharge 5.37 0.78 -4.59 -1.148 0.17485E+05 256 wurtzite -10.17 -10.98 -0.81 -0.270 0.30887E+04 257 zincite 2.33 -0.26 -2.59 -0.648 0.98771E+04 258 an20ab80 -5.06 -5.14 -0.08 -0.006 0.30623E+03 259 an25ab75 -5.26 -5.35 -0.09 -0.007 0.34629E+03 260 an30ab70 -5.46 -5.56 -0.11 -0.008 0.40671E+03 261 tr.625ac.25prg.125 10.32 9.19 -1.13 -0.030 0.42992E+04 Calculations done for 559.0000 Deg. C; 1050.0000 bar Temperature changed by -1.000 degrees to 558.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 36 Loop limit = 500 Temperature = 558.00 C Pressure = 1037.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5513E+02 kg liquid = 0.9932E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9968 Stoichiometric ionic strength = .3274311E+01 Osmotic coef. = 0.0000 True ionic strength = .1439574E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.45008E-05 -5.3467 0.92448E-06 -6.0341 0.20540E+00 -0.6874 2 H2O 0.99685E+00 -0.0014 0.99685E+00 -0.0014 3 Cl- 0.12069E+00 -0.9183 0.21136E-01 -1.6750 0.17513E+00 -0.7567 4 SO4-- 0.23828E-03 -3.6229 0.52592E-06 -6.2791 0.22071E-02 -2.6562 5 HCO3- 0.87713E-05 -5.0569 0.16517E-05 -5.7821 0.18830E+00 -0.7251 6 HS- 0.11220E-03 -3.9500 0.19808E-04 -4.7032 0.17654E+00 -0.7532 7 H4SiO4 0.47297E-01 -1.3252 0.47297E-01 -1.3252 0.10000E+01 0.0000 8 Al+++ 0.22773E-16 -16.6426 0.18971E-22 -22.7219 0.83307E-06 -6.0793 9 Ca++ 0.11636E-05 -5.9342 0.20625E-08 -8.6856 0.17724E-02 -2.7514 10 Mg++ 0.13887E-05 -5.8574 0.20305E-08 -8.6924 0.14622E-02 -2.8350 11 Fe++ 0.12097E-07 -7.9173 0.18570E-10 -10.7312 0.15351E-02 -2.8139 12 K+ 0.34302E-01 -1.4647 0.66125E-02 -2.1796 0.19277E+00 -0.7150 13 Na+ 0.10800E+00 -0.9666 0.19115E-01 -1.7186 0.17699E+00 -0.7520 14 Mn++ 0.12118E-05 -5.9166 0.19277E-08 -8.7150 0.15908E-02 -2.7984 15 Zn++ 0.31210E-09 -9.5057 0.47912E-12 -12.3196 0.15351E-02 -2.8139 16 Cu+ 0.12294E-07 -7.9103 0.21704E-08 -8.6635 0.17654E+00 -0.7532 17 Pb++ 0.25731E-08 -8.5896 0.51024E-11 -11.2922 0.19830E-02 -2.7027 18 Ag+ 0.29688E-09 -9.5274 0.56350E-10 -10.2491 0.18981E+00 -0.7217 19 Ba++ 0.58063E-07 -7.2361 0.12363E-09 -9.9079 0.21293E-02 -2.6718 20 HPO4-- 0.13998E-08 -8.8539 0.31050E-11 -11.5079 0.22181E-02 -2.6540 21 HSiO3- 0.13049E-05 -5.8844 0.22852E-06 -6.6411 0.17513E+00 -0.7567 22 Ca(HSiO3)+ 0.41340E-08 -8.3836 0.80386E-09 -9.0948 0.19445E+00 -0.7112 23 Mg(HSiO3)+ 0.13176E-08 -8.8802 0.25621E-09 -9.5914 0.19445E+00 -0.7112 24 NaHSiO3,aq 0.19026E-05 -5.7206 0.19026E-05 -5.7206 0.10000E+01 0.0000 28 AgCl,aq 0.12280E-06 -6.9108 0.12280E-06 -6.9108 0.10000E+01 0.0000 29 AgCl2- 0.53818E-05 -5.2691 0.94249E-06 -6.0257 0.17513E+00 -0.7567 30 AgCl3-2 0.17186E-05 -5.7648 0.35139E-08 -8.4542 0.20446E-02 -2.6894 31 AgCl4-3 0.15279E-05 -5.8159 0.11201E-11 -11.9507 0.73307E-06 -6.1349 34 Ag(HS),aq 0.21038E-08 -8.6770 0.21038E-08 -8.6770 0.10000E+01 0.0000 35 Ag(HS)2- 0.71377E-08 -8.1464 0.12500E-08 -8.9031 0.17513E+00 -0.7567 36 AlO+ 0.10234E-10 -10.9900 0.19900E-11 -11.7012 0.19445E+00 -0.7112 38 HAlO2,aq 0.41485E-08 -8.3821 0.41485E-08 -8.3821 0.10000E+01 0.0000 39 AlO2- 0.10781E-04 -4.9674 0.16625E-05 -5.7792 0.15422E+00 -0.8119 41 Ba(HCO3)+ 0.18418E-06 -6.7347 0.37249E-07 -7.4289 0.20224E+00 -0.6941 42 BaCl+ 0.72680E-05 -5.1386 0.14132E-05 -5.8498 0.19445E+00 -0.7112 43 CH4,aq 0.14421E-08 -8.8410 0.17086E-08 -8.7674 0.11848E+01 0.0736 48 CO,aq 0.48872E-03 -3.3109 0.48872E-03 -3.3109 0.10000E+01 0.0000 49 CO2,aq 0.26739E+01 0.4271 0.31680E+01 0.5008 0.11848E+01 0.0736 50 CO3-2 0.35846E-10 -10.4456 0.73290E-13 -13.1350 0.20446E-02 -2.6894 52 Ca(HCO3)+ 0.87558E-07 -7.0577 0.17026E-07 -7.7689 0.19445E+00 -0.7112 53 CaCl+ 0.66706E-04 -4.1758 0.12971E-04 -4.8870 0.19445E+00 -0.7112 54 CaCl2,aq 0.72372E-04 -4.1404 0.72372E-04 -4.1404 0.10000E+01 0.0000 55 CaOH+ 0.12637E-06 -6.8983 0.24573E-07 -7.6095 0.19445E+00 -0.7112 56 CaSO4,aq 0.17385E-06 -6.7598 0.17385E-06 -6.7598 0.10000E+01 0.0000 57 HCl,aq 0.33931E-02 -2.4694 0.33931E-02 -2.4694 0.10000E+01 0.0000 66 CuCl,aq 0.20732E-04 -4.6834 0.20732E-04 -4.6834 0.10000E+01 0.0000 67 CuCl2- 0.67722E-04 -4.1693 0.11860E-04 -4.9259 0.17513E+00 -0.7567 68 CuCl3-2 0.11880E-05 -5.9252 0.24290E-08 -8.6146 0.20446E-02 -2.6894 74 FeCl+ 0.21621E-06 -6.6651 0.42041E-07 -7.3763 0.19445E+00 -0.7112 75 FeCl2,aq 0.26104E-02 -2.5833 0.26104E-02 -2.5833 0.10000E+01 0.0000 77 FeO,aq 0.54085E-07 -7.2669 0.54085E-07 -7.2669 0.10000E+01 0.0000 78 FeOH+ 0.18180E-07 -7.7404 0.35351E-08 -8.4516 0.19445E+00 -0.7112 79 HFeO2- 0.58472E-08 -8.2331 0.10240E-08 -8.9897 0.17513E+00 -0.7567 82 FeO2- 0.36689E-08 -8.4355 0.64251E-09 -9.1921 0.17513E+00 -0.7567 83 HFeO2,aq 0.27522E-09 -9.5603 0.27522E-09 -9.5603 0.10000E+01 0.0000 84 H2,aq 0.44003E-02 -2.3565 0.52134E-02 -2.2829 0.11848E+01 0.0736 85 KCl,aq 0.72744E-01 -1.1382 0.72744E-01 -1.1382 0.10000E+01 0.0000 86 KHSO4,aq 0.13733E-01 -1.8622 0.13733E-01 -1.8622 0.10000E+01 0.0000 87 KOH,aq 0.13943E-05 -5.8557 0.13943E-05 -5.8557 0.10000E+01 0.0000 88 KSO4- 0.48044E-02 -2.3184 0.84138E-03 -3.0750 0.17513E+00 -0.7567 90 Mg(HCO3)+ 0.28958E-07 -7.5382 0.56309E-08 -8.2494 0.19445E+00 -0.7112 91 MgCl+ 0.14188E-04 -4.8481 0.27589E-05 -5.5593 0.19445E+00 -0.7112 92 MgOH+ 0.53698E-06 -6.2700 0.10441E-06 -6.9812 0.19445E+00 -0.7112 94 MnO,aq 0.96480E-07 -7.0156 0.96480E-07 -7.0156 0.10000E+01 0.0000 95 MnOH+ 0.20672E-06 -6.6846 0.40196E-07 -7.3958 0.19445E+00 -0.7112 97 HMnO2- 0.41040E-10 -10.3868 0.71871E-11 -11.1434 0.17513E+00 -0.7567 100 MnCl+ 0.11556E-02 -2.9372 0.22470E-03 -3.6484 0.19445E+00 -0.7112 101 MnSO4,aq 0.17481E-06 -6.7574 0.17481E-06 -6.7574 0.10000E+01 0.0000 102 NaCl,aq 0.45042E+00 -0.3464 0.45042E+00 -0.3464 0.10000E+01 0.0000 103 NaOH,aq 0.18419E-05 -5.7347 0.18419E-05 -5.7347 0.10000E+01 0.0000 105 OH- 0.70353E-05 -5.1527 0.10850E-05 -5.9646 0.15422E+00 -0.8119 111 H3PO3,aq 0.11870E-09 -9.9256 0.11870E-09 -9.9256 0.10000E+01 0.0000 112 H2PO3- 0.17817E-08 -8.7492 0.31201E-09 -9.5058 0.17513E+00 -0.7567 113 H3PO4,aq 0.14649E-05 -5.8342 0.14649E-05 -5.8342 0.10000E+01 0.0000 114 H2PO4- 0.14006E-05 -5.8537 0.25754E-06 -6.5892 0.18387E+00 -0.7355 116 H4P2O7,aq 0.19956E-09 -9.6999 0.19956E-09 -9.6999 0.10000E+01 0.0000 117 H3P2O7- 0.93229E-09 -9.0304 0.16327E-09 -9.7871 0.17513E+00 -0.7567 118 H2P2O7-2 0.21830E-06 -6.6609 0.44634E-09 -9.3503 0.20446E-02 -2.6894 119 HP2O7-3 0.24398E-07 -7.6127 0.17885E-13 -13.7475 0.73307E-06 -6.1349 121 PbCl+ 0.11497E-05 -5.9394 0.22355E-06 -6.6506 0.19445E+00 -0.7112 122 PbCl2,aq 0.84940E-04 -4.0709 0.84940E-04 -4.0709 0.10000E+01 0.0000 123 PbCl3- 0.94609E-04 -4.0241 0.16568E-04 -4.7807 0.17513E+00 -0.7567 124 PbCl4-2 0.15387E-04 -4.8128 0.31461E-07 -7.5022 0.20446E-02 -2.6894 125 PbO,aq 0.66387E-08 -8.1779 0.66387E-08 -8.1779 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12524E-03 -3.9023 0.12524E-03 -3.9023 0.10000E+01 0.0000 128 Pb(HS)3- 0.13565E-04 -4.8676 0.23756E-05 -5.6242 0.17513E+00 -0.7567 129 H2S,aq 0.10588E+01 0.0248 0.12544E+01 0.0984 0.11848E+01 0.0736 130 S2-2 0.11485E-07 -7.9399 0.23482E-10 -10.6293 0.20446E-02 -2.6894 131 S3-2 0.10715E-08 -8.9700 0.21908E-11 -11.6594 0.20446E-02 -2.6894 132 S3- 0.91755E-02 -2.0374 0.16069E-02 -2.7940 0.17513E+00 -0.7567 133 S4-2 0.85045E-10 -10.0703 0.17388E-12 -12.7597 0.20446E-02 -2.6894 135 SO2,aq 0.29352E+00 -0.5324 0.29352E+00 -0.5324 0.10000E+01 0.0000 136 SO3-2 0.62454E-09 -9.2044 0.20206E-11 -11.6945 0.32354E-02 -2.4901 137 HSO3- 0.23112E-03 -3.6362 0.40475E-04 -4.3928 0.17513E+00 -0.7567 138 HSO4- 0.79077E-02 -2.1019 0.15797E-02 -2.8014 0.19977E+00 -0.6995 140 S2O3-2 0.49312E-06 -6.3070 0.10082E-08 -8.9964 0.20446E-02 -2.6894 141 HS2O3- 0.35360E-06 -6.4515 0.61924E-07 -7.2081 0.17513E+00 -0.7567 142 H2S2O3,aq 0.35783E-07 -7.4463 0.35783E-07 -7.4463 0.10000E+01 0.0000 150 S4O6-2 0.42164E-09 -9.3751 0.86208E-12 -12.0645 0.20446E-02 -2.6894 152 ZnCl+ 0.13235E-03 -3.8783 0.25736E-04 -4.5895 0.19445E+00 -0.7112 153 ZnCl2,aq 0.57460E-03 -3.2406 0.57460E-03 -3.2406 0.10000E+01 0.0000 154 ZnCl3- 0.37876E-04 -4.4216 0.66331E-05 -5.1783 0.17513E+00 -0.7567 155 ZnO,aq 0.26872E-07 -7.5707 0.26872E-07 -7.5707 0.10000E+01 0.0000 156 ZnOH+ 0.92278E-06 -6.0349 0.17943E-06 -6.7461 0.19445E+00 -0.7112 158 HZnO2- 0.18983E-09 -9.7216 0.33245E-10 -10.4783 0.17513E+00 -0.7567 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4500808E-05 0.4294861E+01 0.3542575E+04 0.0000 2 H2O 0.1000000E+01 0.5252183E+02 0.7743130E+06 0.0000 3 Cl- 0.1206912E+00 0.6559464E+00 0.1903078E+05 4.3591 4 SO4-- 0.2382845E-03 0.2515111E+00 0.1977162E+05 5.7891 5 HCO3- 0.8771335E-05 0.2674402E+01 0.1335409E+06 0.2520 6 HS- 0.1122010E-03 0.1155641E+01 0.3127652E+05 1.3309 7 H4SiO4 0.4729736E-01 0.4730057E-01 0.3720443E+04 -1.3252 8 Al+++ 0.2277272E-16 0.1078467E-04 0.2381268E+00 -4.6196 9 Ca++ 0.1163644E-05 0.1406335E-03 0.4612433E+01 3.3826 10 Mg++ 0.1388667E-05 0.1614403E-04 0.3211943E+00 3.3758 11 Fe++ 0.1209694E-07 0.2610713E-02 0.1193148E+03 1.3370 12 K+ 0.3430206E-01 0.1255851E+00 0.4018578E+04 3.8545 13 Na+ 0.1079990E+00 0.5584181E+00 0.1050582E+05 4.3155 14 Mn++ 0.1211820E-05 0.1157266E-02 0.5202848E+02 3.3532 15 Zn++ 0.3121035E-09 0.7457739E-03 0.3989522E+02 -0.2514 16 Cu+ 0.1229435E-07 0.8965420E-04 0.4661794E+01 -2.6294 17 Pb++ 0.2573056E-08 0.3348998E-03 0.5678308E+02 0.7760 18 Ag+ 0.2968845E-09 0.8760753E-05 0.7733523E+00 -4.2150 19 Ba++ 0.5806319E-07 0.7510204E-05 0.8440808E+00 2.1603 20 HPO4-- 0.1399816E-08 0.3356477E-05 0.2636302E+00 0.5603 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265490E+01 -.3127622E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5216265E+02 -.1978735E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2497911E+00 0.1931680E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1147738E+01 0.1240656E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4697711E-01 0.9661722E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1071092E-04 0.6838286E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1396718E-03 0.3882381E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1603363E-04 0.4643025E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2592859E-02 0.6173894E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247263E+00 0.6838286E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149351E-02 0.1485574E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7406738E-03 0.1558661E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.8904109E-04 0.3105686E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3326096E-03 0.7563059E-05 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7458845E-05 0.4791361E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3333523E-05 0.5233977E-05 0.0000000E+00 Chg. balance for solid moles: -.2072E-17 Mass of aqueous solution: 0.121363E+04 g Temperature = 558.00 C Pressure = 1037.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3795E-03 -3.421 0.5167E-01 -1.287 0.7543 0.1744E-01 annite 0.5342E-06 -6.272 0.2735E-03 -3.563 0.3992E-02 0.8244E-04 phlogopite 0.1548E-05 -5.810 0.6458E-03 -3.190 0.9428E-02 0.2316E-03 biotite-Mn 0.4952E-07 -7.305 0.2521E-04 -4.598 0.3681E-03 0.7558E-05 apatite-OH 0.1745E-05 -5.758 0.8764E-03 -3.057 0.1279E-01 0.2785E-03 microcline 0.6817E-03 -3.166 0.1897 -0.722 2.770 0.7412E-01 pyrite 0.5862E-02 -2.232 0.7033 -0.153 10.27 0.1403 quartz 0.9457E-01 -1.024 5.682 0.754 82.94 2.146 barite 0.4791E-04 -4.320 0.1118E-01 -1.951 0.1633 0.2496E-02 chalcopyrite 0.3106E-03 -3.508 0.5699E-01 -1.244 0.8320 0.1330E-01 galena 0.7563E-05 -5.121 0.1809E-02 -2.742 0.2642E-01 0.2381E-03 sphalerite 0.1559E-02 -2.807 0.1519 -0.819 2.217 0.3714E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2506E+00 0.2506E+00 1.0000 -0.601 phlogopite 0.7261E+00 0.7261E+00 1.0000 -0.139 biotite-Mn 0.2323E-01 0.2323E-01 1.0000 -1.634 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.849873 g Volume = 2.431238 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.96 -14.96 0.00 0.000 -0.67558E-11 24 annite 1.07 1.07 0.00 0.000 -0.37157E-10 25 phlogopite 5.80 5.80 0.00 0.000 0.00000E+00 26 biotite-Mn 10.22 10.22 0.00 0.000 -0.13512E-10 30 apatite-OH -53.82 -53.82 0.00 0.000 0.00000E+00 115 microcline -4.74 -4.74 0.00 0.000 -0.33779E-11 140 pyrite -22.04 -22.04 0.00 0.000 0.00000E+00 144 quartz -1.32 -1.32 0.00 0.000 0.00000E+00 237 barite -16.19 -16.19 0.00 0.000 0.00000E+00 240 chalcopyrite -23.72 -23.72 0.00 0.000 0.13512E-10 245 galena -9.96 -9.96 0.00 0.000 -0.67558E-11 255 sphalerite -10.99 -10.99 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 0.00 -0.26 -0.262 0.99609E+03 2.754 2 CO2,gas -10.12 -11.81 -1.70 -0.565 0.64512E+04 1.320 3 CH4,gas 6.83 -4.21 -11.04 -2.761 0.41995E+05 -8.026 4 H2,gas 5.98 1.90 -4.08 -2.332 0.15518E+05 -1.064 5 H2S,gas -8.43 -10.74 -2.31 -1.154 0.87745E+04 0.709 6 CO,gas -3.86 -9.91 -6.05 -1.862 0.23010E+05 -3.034 7 SO3,gas -7.66 -18.35 -10.69 -2.672 0.40651E+05 -7.673 8 O2,gas 16.93 -3.81 -20.74 -13.824 0.78862E+05 -17.720 9 HCl,gas -6.17 -7.71 -1.54 -0.772 0.58722E+04 -1.544 10 acmite 3.61 2.05 -1.55 -0.162 0.59130E+04 12 akimotoite 6.27 2.05 -4.22 -0.844 0.16054E+05 13 akimotoite-Fe 4.13 0.01 -4.11 -0.823 0.15648E+05 14 albite-high -4.12 -4.27 -0.15 -0.012 0.57490E+03 15 albite -4.12 -4.27 -0.15 -0.012 0.57780E+03 16 almandine -7.07 -9.20 -2.13 -0.106 0.80958E+04 17 pyrope -0.28 -3.09 -2.81 -0.141 0.10691E+05 18 analcite -1.96 -2.95 -1.00 -0.111 0.37847E+04 19 andalusite -9.94 -10.57 -0.62 -0.062 0.23748E+04 27 anorthite -7.60 -8.51 -0.90 -0.070 0.34364E+04 28 anthophyllite 15.14 13.04 -2.10 -0.057 0.79706E+04 29 anthophyllite-Fe 2.17 -1.23 -3.40 -0.092 0.12933E+05 31 apatite-OH-zs -51.62 -53.82 -2.20 -0.169 0.83593E+04 32 apatite-Cl-zs -58.25 -61.52 -3.27 -0.272 0.12435E+05 33 aragonite -4.71 -8.43 -3.72 -1.240 0.14151E+05 34 brucite 5.62 3.37 -2.25 -0.450 0.85487E+04 35 calcite -4.82 -8.43 -3.61 -1.205 0.13744E+05 36 carnegieite-low 0.17 -1.63 -1.80 -0.258 0.68605E+04 37 carnegieite-high 0.26 -1.63 -1.89 -0.270 0.71830E+04 38 carpholite-Mg -6.41 -8.52 -2.10 -0.140 0.79929E+04 39 carpholite-Fe -7.81 -10.56 -2.75 -0.183 0.10454E+05 40 celadonite -0.59 -2.68 -2.09 -0.123 0.79552E+04 41 celadonite-Fe -2.03 -4.72 -2.69 -0.158 0.10243E+05 42 chrysotile 9.82 7.48 -2.34 -0.195 0.89137E+04 44 clinochlore 5.02 3.66 -1.36 -0.043 0.51897E+04 45 daphnite -2.23 -6.54 -4.31 -0.135 0.16379E+05 47 chlorite-Al-free 19.81 14.95 -4.86 -0.202 0.18471E+05 48 chloritoid-Mg -5.77 -7.19 -1.42 -0.095 0.54076E+04 49 chloritoid-Fe -7.76 -9.23 -1.47 -0.098 0.55814E+04 50 chloritoid-Mn -5.62 -7.22 -1.60 -0.106 0.60665E+04 52 coesite -1.03 -1.32 -0.29 -0.098 0.11194E+04 53 cordierite-H -17.27 -18.35 -1.08 -0.038 0.40969E+04 54 cordierite-Fe -19.95 -22.43 -2.48 -0.086 0.94360E+04 55 cordierite-Mn -15.59 -18.39 -2.81 -0.097 0.10673E+05 56 corundum -8.44 -9.24 -0.80 -0.073 0.30546E+04 58 cristobalite -1.27 -1.32 -0.05 -0.016 0.18193E+03 59 cummingtonite 15.20 13.04 -2.16 -0.059 0.82328E+04 61 cymrite-K -2.40 -4.74 -2.34 -0.195 0.88904E+04 63 diaspore -3.73 -4.62 -0.89 -0.149 0.33999E+04 65 diopside 5.53 4.11 -1.42 -0.142 0.53942E+04 66 hedenbergite 4.07 2.07 -2.00 -0.200 0.75964E+04 68 eastonite -4.51 -5.91 -1.40 -0.054 0.53193E+04 69 enstatite 4.95 4.10 -0.84 -0.084 0.32101E+04 70 clinoenstatite-HiP 5.45 4.10 -1.35 -0.135 0.51188E+04 71 clinoenstatite 4.93 4.10 -0.83 -0.083 0.31436E+04 72 protoenstatite 5.08 4.10 -0.98 -0.098 0.37215E+04 73 epidote -3.50 -6.06 -2.56 -0.124 0.97453E+04 74 clinozoisite -8.08 -11.07 -2.99 -0.136 0.11381E+05 75 epidote-Fe 2.77 -1.06 -3.83 -0.199 0.14573E+05 76 fayalite 2.50 1.35 -1.16 -0.165 0.43965E+04 77 ferrosilite 1.28 0.03 -1.26 -0.126 0.47775E+04 78 forsterite 6.59 5.43 -1.16 -0.166 0.44221E+04 79 gedrite -7.28 -9.55 -2.27 -0.061 0.86172E+04 81 gibbsite -2.10 -4.62 -2.53 -0.361 0.96125E+04 82 glaucophane 1.97 -1.07 -3.04 -0.082 0.11550E+05 83 glaucophane-Fe -2.20 -7.19 -4.99 -0.135 0.18976E+05 84 goethite 1.29 0.38 -0.90 -0.195 0.34345E+04 86 greenalite 4.82 1.36 -3.46 -0.288 0.13154E+05 87 grunerite 2.74 -1.23 -3.97 -0.107 0.15089E+05 88 halite -1.36 -3.39 -2.03 -1.017 0.77378E+04 89 hematite 1.02 0.77 -0.26 -0.031 0.97429E+03 90 heulandite -11.82 -15.13 -3.30 -0.150 0.12567E+05 91 hercynite -6.55 -7.91 -1.36 -0.090 0.51580E+04 94 jadeite -1.27 -2.95 -1.68 -0.168 0.63809E+04 96 kalsilite -0.45 -2.09 -1.64 -0.234 0.62417E+04 97 kaolinite -9.06 -11.89 -2.83 -0.258 0.10773E+05 98 kyanite -9.78 -10.57 -0.79 -0.079 0.30040E+04 100 laumontite -7.37 -11.16 -3.78 -0.252 0.14389E+05 101 lawsonite -4.84 -8.51 -3.67 -0.245 0.13974E+05 102 leucite -2.44 -3.41 -0.98 -0.098 0.37174E+04 104 lizardite 9.98 7.48 -2.51 -0.209 0.95407E+04 105 magnesite -5.51 -8.44 -2.93 -0.976 0.11140E+05 106 magnetite 2.39 2.10 -0.28 -0.023 0.10778E+04 107 minnesotaite 0.91 -1.28 -2.20 -0.129 0.83636E+04 108 minnesotaite-Mg 7.02 4.83 -2.19 -0.129 0.83210E+04 109 magnesioferrite 5.52 4.14 -1.37 -0.112 0.52212E+04 111 manganosite 5.55 3.35 -2.20 -0.550 0.83625E+04 112 margarite -15.59 -17.75 -2.16 -0.086 0.82176E+04 116 monticellite 9.03 5.43 -3.60 -0.514 0.13678E+05 118 mullite-Si -9.18 -10.57 -1.39 -0.139 0.52751E+04 119 muscovite -13.05 -13.98 -0.93 -0.055 0.35363E+04 120 paragonite -12.36 -13.52 -1.15 -0.068 0.43902E+04 121 nepheline -0.13 -1.63 -1.50 -0.214 0.57098E+04 122 osumilite(2) -12.37 -14.43 -2.06 -0.043 0.78496E+04 123 osumilite-Fe -26.92 -29.81 -2.89 -0.060 0.11000E+05 124 pargasite 6.98 2.77 -4.20 -0.111 0.15984E+05 125 periclase 5.83 3.37 -2.45 -0.613 0.93328E+04 126 periclase-Fe 3.20 1.34 -1.87 -0.467 0.71013E+04 127 perovskite-Al -6.69 -9.24 -2.56 -0.232 0.97178E+04 132 phlogopite-Na 6.68 5.85 -0.83 -0.046 0.31719E+04 134 prehnite -2.88 -6.45 -3.57 -0.210 0.13587E+05 135 prehnite-Fe 2.10 -1.44 -3.54 -0.213 0.13459E+05 138 px-Mg-tschermaks -5.14 -7.19 -2.06 -0.147 0.78198E+04 139 px-Ca-tschermaks -4.37 -7.18 -2.81 -0.201 0.10703E+05 141 pyrrhotite -8.70 -9.40 -0.70 -0.235 0.26804E+04 142 pyrrhotiteFe0.875 -9.49 -9.80 -0.31 -0.115 0.11842E+04 143 pyrophyllite -13.04 -14.53 -1.49 -0.093 0.56708E+04 146 riebeckite 5.86 2.82 -3.03 -0.084 0.11525E+05 147 ringwoodite-Fe 3.51 1.35 -2.16 -0.308 0.82097E+04 148 ringwoodite-Mg 9.78 5.43 -4.35 -0.621 0.16540E+05 149 rhodochrosite -5.52 -8.46 -2.94 -0.979 0.11175E+05 150 rhodonite 2.59 2.03 -0.56 -0.112 0.21214E+04 151 sanidine -4.19 -4.74 -0.54 -0.042 0.20670E+04 153 siderite -7.39 -10.48 -3.09 -1.029 0.11737E+05 154 sillimanite -9.90 -10.57 -0.66 -0.066 0.25230E+04 156 spinel -4.34 -5.87 -1.53 -0.102 0.58264E+04 163 stilpnomelane-Mg 1.06 -1.03 -2.10 -0.063 0.79744E+04 164 stishovite 1.66 -1.32 -2.99 -0.995 0.11353E+05 165 sudoite-Fe -15.13 -19.79 -4.65 -0.150 0.17700E+05 166 sudoite -12.85 -15.71 -2.86 -0.092 0.10892E+05 167 sulfur -11.15 -12.64 -1.49 -0.458 0.56610E+04 168 sylvite -1.26 -3.85 -2.59 -1.295 0.98535E+04 169 talc 5.28 4.83 -0.44 -0.026 0.16889E+04 170 talc-Fe 2.34 -1.28 -3.62 -0.213 0.13767E+05 171 talc-tschermaks -4.73 -6.46 -1.73 -0.102 0.65925E+04 173 tephroite 6.76 5.38 -1.38 -0.197 0.52558E+04 176 topaz-H -7.85 -10.57 -2.72 -0.247 0.10350E+05 177 tremolite 15.69 13.05 -2.63 -0.071 0.10019E+05 179 troilite-low -8.61 -9.40 -0.80 -0.265 0.30238E+04 180 tschermakite -5.95 -9.54 -3.59 -0.097 0.13635E+05 183 wadsleyite-Fe 3.36 1.35 -2.01 -0.288 0.76597E+04 184 wadsleyite-Mg 8.83 5.43 -3.40 -0.486 0.12930E+05 185 wairakite -9.25 -11.15 -1.90 -0.112 0.72315E+04 186 walstromite 4.66 2.06 -2.60 -0.520 0.98930E+04 187 wollastonite 4.23 2.06 -2.17 -0.435 0.82669E+04 188 pseudo-wollastonite 4.35 2.06 -2.29 -0.459 0.87211E+04 189 zoisite -8.13 -11.07 -2.94 -0.134 0.11189E+05 191 argentite -14.18 -19.17 -4.98 -1.246 0.18958E+05 192 beidellite-Ca -13.20 -15.07 -1.86 -0.115 0.70775E+04 193 beidellite-H -13.24 -15.62 -2.38 -0.152 0.90565E+04 194 beidellite-K -12.20 -14.35 -2.15 -0.132 0.81886E+04 195 beidellite-Mg -13.45 -15.07 -1.61 -0.100 0.61373E+04 196 beidellite-Na -12.14 -14.20 -2.06 -0.126 0.78299E+04 197 bornite -55.41 -55.71 -0.30 -0.022 0.11335E+04 199 chalcocite -14.53 -16.00 -1.47 -0.367 0.55815E+04 200 covellite -12.96 -14.32 -1.36 -0.518 0.51673E+04 202 montmorillonite-Ca -9.95 -11.34 -1.38 -0.086 0.52589E+04 203 montmorillonite-K -9.23 -10.62 -1.40 -0.085 0.53094E+04 204 montmorillonite-Mg -10.17 -11.34 -1.17 -0.073 0.44627E+04 205 montmorillonite-Na -8.89 -10.47 -1.58 -0.097 0.59980E+04 206 nontronite-Ca -3.47 -5.05 -1.58 -0.102 0.60036E+04 207 nontronite-H -3.52 -5.61 -2.09 -0.140 0.79536E+04 208 nontronite-K -2.47 -4.34 -1.87 -0.120 0.71071E+04 209 nontronite-Mg -3.69 -5.05 -1.36 -0.089 0.51907E+04 210 nontronite-Na -2.41 -4.19 -1.78 -0.114 0.67601E+04 215 gypsum -12.71 -14.97 -2.26 -0.565 0.85996E+04 231 acanthite -14.27 -19.17 -4.90 -1.225 0.18635E+05 232 alabandite -6.42 -7.38 -0.96 -0.321 0.36584E+04 234 anglesite -15.27 -17.57 -2.31 -1.153 0.87664E+04 238 boehmite -3.43 -4.62 -1.19 -0.199 0.45345E+04 242 copper,native 1.71 -1.68 -3.39 -1.179 0.12895E+05 244 ferrous-oxide 2.27 1.34 -0.93 -0.233 0.35507E+04 246 silver,native 0.42 -3.26 -3.69 -1.283 0.14025E+05 248 litharge 5.38 0.77 -4.60 -1.150 0.17497E+05 256 wurtzite -10.18 -10.99 -0.81 -0.271 0.30893E+04 257 zincite 2.35 -0.25 -2.60 -0.650 0.98912E+04 258 an20ab80 -5.04 -5.12 -0.08 -0.007 0.32224E+03 259 an25ab75 -5.24 -5.33 -0.10 -0.007 0.36464E+03 260 an30ab70 -5.43 -5.54 -0.11 -0.009 0.42767E+03 261 tr.625ac.25prg.125 10.37 9.22 -1.15 -0.031 0.43735E+04 Calculations done for 558.0000 Deg. C; 1037.0000 bar Temperature changed by -1.000 degrees to 557.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 36 Loop limit = 500 Temperature = 557.00 C Pressure = 1024.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5513E+02 kg liquid = 0.9932E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9969 Stoichiometric ionic strength = .3273802E+01 Osmotic coef. = 0.0000 True ionic strength = .1424952E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.44489E-05 -5.3517 0.90899E-06 -6.0414 0.20432E+00 -0.6897 2 H2O 0.99687E+00 -0.0014 0.99687E+00 -0.0014 3 Cl- 0.11942E+00 -0.9229 0.20786E-01 -1.6822 0.17406E+00 -0.7593 4 SO4-- 0.24080E-03 -3.6183 0.51986E-06 -6.2841 0.21589E-02 -2.6658 5 HCO3- 0.85612E-05 -5.0675 0.16021E-05 -5.7953 0.18713E+00 -0.7278 6 HS- 0.11124E-03 -3.9537 0.19518E-04 -4.7096 0.17546E+00 -0.7558 7 H4SiO4 0.46504E-01 -1.3325 0.46504E-01 -1.3325 0.10000E+01 0.0000 8 Al+++ 0.24421E-16 -16.6122 0.19356E-22 -22.7132 0.79260E-06 -6.1009 9 Ca++ 0.11542E-05 -5.9377 0.20008E-08 -8.6988 0.17335E-02 -2.7611 10 Mg++ 0.14354E-05 -5.8430 0.20531E-08 -8.6876 0.14303E-02 -2.8446 11 Fe++ 0.12035E-07 -7.9196 0.18071E-10 -10.7430 0.15016E-02 -2.8234 12 K+ 0.34001E-01 -1.4685 0.65133E-02 -2.1862 0.19156E+00 -0.7177 13 Na+ 0.10684E+00 -0.9713 0.18793E-01 -1.7260 0.17590E+00 -0.7547 14 Mn++ 0.12450E-05 -5.9048 0.19372E-08 -8.7128 0.15560E-02 -2.8080 15 Zn++ 0.31286E-09 -9.5046 0.46980E-12 -12.3281 0.15016E-02 -2.8234 16 Cu+ 0.12011E-07 -7.9204 0.21072E-08 -8.6763 0.17545E+00 -0.7559 17 Pb++ 0.25327E-08 -8.5964 0.49118E-11 -11.3088 0.19394E-02 -2.7123 18 Ag+ 0.29630E-09 -9.5283 0.55887E-10 -10.2527 0.18862E+00 -0.7244 19 Ba++ 0.56858E-07 -7.2452 0.11840E-09 -9.9267 0.20824E-02 -2.6814 20 HPO4-- 0.14322E-08 -8.8440 0.31075E-11 -11.5076 0.21697E-02 -2.6636 21 HSiO3- 0.12832E-05 -5.8917 0.22335E-06 -6.6510 0.17406E+00 -0.7593 22 Ca(HSiO3)+ 0.40123E-08 -8.3966 0.77529E-09 -9.1105 0.19323E+00 -0.7139 23 Mg(HSiO3)+ 0.13406E-08 -8.8727 0.25904E-09 -9.5866 0.19323E+00 -0.7139 24 NaHSiO3,aq 0.19018E-05 -5.7208 0.19018E-05 -5.7208 0.10000E+01 0.0000 28 AgCl,aq 0.12457E-06 -6.9046 0.12457E-06 -6.9046 0.10000E+01 0.0000 29 AgCl2- 0.53923E-05 -5.2682 0.93855E-06 -6.0275 0.17406E+00 -0.7593 30 AgCl3-2 0.17047E-05 -5.7684 0.34092E-08 -8.4673 0.20000E-02 -2.6990 31 AgCl4-3 0.15294E-05 -5.8155 0.10674E-11 -11.9717 0.69796E-06 -6.1562 34 Ag(HS),aq 0.21708E-08 -8.6634 0.21708E-08 -8.6634 0.10000E+01 0.0000 35 Ag(HS)2- 0.72179E-08 -8.1416 0.12563E-08 -8.9009 0.17406E+00 -0.7593 36 AlO+ 0.10391E-10 -10.9833 0.20079E-11 -11.6973 0.19323E+00 -0.7139 38 HAlO2,aq 0.41726E-08 -8.3796 0.41726E-08 -8.3796 0.10000E+01 0.0000 39 AlO2- 0.10583E-04 -4.9754 0.16225E-05 -5.7898 0.15332E+00 -0.8144 41 Ba(HCO3)+ 0.17690E-06 -6.7523 0.35551E-07 -7.4491 0.20096E+00 -0.6969 42 BaCl+ 0.70191E-05 -5.1537 0.13563E-05 -5.8677 0.19323E+00 -0.7139 43 CH4,aq 0.14203E-08 -8.8476 0.16813E-08 -8.7743 0.11838E+01 0.0733 48 CO,aq 0.47934E-03 -3.3194 0.47934E-03 -3.3194 0.10000E+01 0.0000 49 CO2,aq 0.26738E+01 0.4271 0.31652E+01 0.5004 0.11838E+01 0.0733 50 CO3-2 0.35434E-10 -10.4506 0.70867E-13 -13.1496 0.20000E-02 -2.6990 52 Ca(HCO3)+ 0.83917E-07 -7.0762 0.16215E-07 -7.7901 0.19323E+00 -0.7139 53 CaCl+ 0.65016E-04 -4.1870 0.12563E-04 -4.9009 0.19323E+00 -0.7139 54 CaCl2,aq 0.71204E-04 -4.1475 0.71204E-04 -4.1475 0.10000E+01 0.0000 55 CaOH+ 0.12273E-06 -6.9110 0.23716E-07 -7.6250 0.19323E+00 -0.7139 56 CaSO4,aq 0.17591E-06 -6.7547 0.17591E-06 -6.7547 0.10000E+01 0.0000 57 HCl,aq 0.34823E-02 -2.4581 0.34823E-02 -2.4581 0.10000E+01 0.0000 66 CuCl,aq 0.20600E-04 -4.6861 0.20600E-04 -4.6861 0.10000E+01 0.0000 67 CuCl2- 0.66976E-04 -4.1741 0.11657E-04 -4.9334 0.17406E+00 -0.7593 68 CuCl3-2 0.11664E-05 -5.9332 0.23328E-08 -8.6321 0.20000E-02 -2.6990 74 FeCl+ 0.21146E-06 -6.6748 0.40859E-07 -7.3887 0.19323E+00 -0.7139 75 FeCl2,aq 0.25164E-02 -2.5992 0.25164E-02 -2.5992 0.10000E+01 0.0000 77 FeO,aq 0.52525E-07 -7.2796 0.52525E-07 -7.2796 0.10000E+01 0.0000 78 FeOH+ 0.17706E-07 -7.7519 0.34214E-08 -8.4658 0.19323E+00 -0.7139 79 HFeO2- 0.55991E-08 -8.2519 0.97456E-09 -9.0112 0.17406E+00 -0.7593 82 FeO2- 0.35230E-08 -8.4531 0.61320E-09 -9.2124 0.17406E+00 -0.7593 83 HFeO2,aq 0.27243E-09 -9.5648 0.27243E-09 -9.5648 0.10000E+01 0.0000 84 H2,aq 0.43591E-02 -2.3606 0.51601E-02 -2.2873 0.11838E+01 0.0733 85 KCl,aq 0.72998E-01 -1.1367 0.72998E-01 -1.1367 0.10000E+01 0.0000 86 KHSO4,aq 0.13753E-01 -1.8616 0.13753E-01 -1.8616 0.10000E+01 0.0000 87 KOH,aq 0.13951E-05 -5.8554 0.13951E-05 -5.8554 0.10000E+01 0.0000 88 KSO4- 0.48291E-02 -2.3161 0.84054E-03 -3.0754 0.17406E+00 -0.7593 90 Mg(HCO3)+ 0.28804E-07 -7.5405 0.55658E-08 -8.2545 0.19323E+00 -0.7139 91 MgCl+ 0.14469E-04 -4.8396 0.27958E-05 -5.5535 0.19323E+00 -0.7139 92 MgOH+ 0.54407E-06 -6.2643 0.10513E-06 -6.9783 0.19323E+00 -0.7139 94 MnO,aq 0.97132E-07 -7.0126 0.97132E-07 -7.0126 0.10000E+01 0.0000 95 MnOH+ 0.20738E-06 -6.6832 0.40072E-07 -7.3972 0.19323E+00 -0.7139 97 HMnO2- 0.40576E-10 -10.3917 0.70624E-11 -11.1510 0.17406E+00 -0.7593 100 MnCl+ 0.11555E-02 -2.9372 0.22328E-03 -3.6512 0.19323E+00 -0.7139 101 MnSO4,aq 0.18258E-06 -6.7385 0.18258E-06 -6.7385 0.10000E+01 0.0000 102 NaCl,aq 0.45156E+00 -0.3453 0.45156E+00 -0.3453 0.10000E+01 0.0000 103 NaOH,aq 0.18388E-05 -5.7355 0.18388E-05 -5.7355 0.10000E+01 0.0000 105 OH- 0.69416E-05 -5.1585 0.10643E-05 -5.9729 0.15332E+00 -0.8144 111 H3PO3,aq 0.12022E-09 -9.9200 0.12022E-09 -9.9200 0.10000E+01 0.0000 112 H2PO3- 0.17526E-08 -8.7563 0.30505E-09 -9.5156 0.17406E+00 -0.7593 113 H3PO4,aq 0.15159E-05 -5.8193 0.15159E-05 -5.8193 0.10000E+01 0.0000 114 H2PO4- 0.14168E-05 -5.8487 0.25891E-06 -6.5869 0.18274E+00 -0.7382 116 H4P2O7,aq 0.21340E-09 -9.6708 0.21340E-09 -9.6708 0.10000E+01 0.0000 117 H3P2O7- 0.95898E-09 -9.0182 0.16692E-09 -9.7775 0.17406E+00 -0.7593 118 H2P2O7-2 0.22229E-06 -6.6531 0.44458E-09 -9.3520 0.20000E-02 -2.6990 119 HP2O7-3 0.25353E-07 -7.5960 0.17695E-13 -13.7521 0.69796E-06 -6.1562 121 PbCl+ 0.11184E-05 -5.9514 0.21611E-06 -6.6653 0.19323E+00 -0.7139 122 PbCl2,aq 0.83750E-04 -4.0770 0.83750E-04 -4.0770 0.10000E+01 0.0000 123 PbCl3- 0.92856E-04 -4.0322 0.16162E-04 -4.7915 0.17406E+00 -0.7593 124 PbCl4-2 0.14966E-04 -4.8249 0.29932E-07 -7.5239 0.20000E-02 -2.6990 125 PbO,aq 0.65546E-08 -8.1835 0.65546E-08 -8.1835 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12366E-03 -3.9078 0.12366E-03 -3.9078 0.10000E+01 0.0000 128 Pb(HS)3- 0.13347E-04 -4.8746 0.23231E-05 -5.6339 0.17406E+00 -0.7593 129 H2S,aq 0.10590E+01 0.0249 0.12536E+01 0.0982 0.11838E+01 0.0733 130 S2-2 0.11362E-07 -7.9445 0.22724E-10 -10.6435 0.20000E-02 -2.6990 131 S3-2 0.10637E-08 -8.9732 0.21274E-11 -11.6722 0.20000E-02 -2.6990 132 S3- 0.90031E-02 -2.0456 0.15670E-02 -2.8049 0.17406E+00 -0.7593 133 S4-2 0.84765E-10 -10.0718 0.16953E-12 -12.7708 0.20000E-02 -2.6990 135 SO2,aq 0.29360E+00 -0.5322 0.29360E+00 -0.5322 0.10000E+01 0.0000 136 SO3-2 0.62418E-09 -9.2047 0.19754E-11 -11.7043 0.31648E-02 -2.4997 137 HSO3- 0.22770E-03 -3.6426 0.39632E-04 -4.4020 0.17406E+00 -0.7593 138 HSO4- 0.78669E-02 -2.1042 0.15617E-02 -2.8064 0.19852E+00 -0.7022 140 S2O3-2 0.49479E-06 -6.3056 0.98956E-09 -9.0046 0.20000E-02 -2.6990 141 HS2O3- 0.35061E-06 -6.4552 0.61025E-07 -7.2145 0.17406E+00 -0.7593 142 H2S2O3,aq 0.36518E-07 -7.4375 0.36518E-07 -7.4375 0.10000E+01 0.0000 150 S4O6-2 0.42442E-09 -9.3722 0.84882E-12 -12.0712 0.20000E-02 -2.6990 152 ZnCl+ 0.12839E-03 -3.8915 0.24808E-04 -4.6054 0.19323E+00 -0.7139 153 ZnCl2,aq 0.56403E-03 -3.2487 0.56403E-03 -3.2487 0.10000E+01 0.0000 154 ZnCl3- 0.36503E-04 -4.4377 0.63535E-05 -5.1970 0.17406E+00 -0.7593 155 ZnO,aq 0.26377E-07 -7.5788 0.26377E-07 -7.5788 0.10000E+01 0.0000 156 ZnOH+ 0.89728E-06 -6.0471 0.17338E-06 -6.7610 0.19323E+00 -0.7139 158 HZnO2- 0.18375E-09 -9.7358 0.31983E-10 -10.4951 0.17406E+00 -0.7593 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4448896E-05 0.4294752E+01 0.3542753E+04 0.0000 2 H2O 0.1000000E+01 0.5252220E+02 0.7743772E+06 0.0000 3 Cl- 0.1194202E+00 0.6559301E+00 0.1903175E+05 4.3592 4 SO4-- 0.2408003E-03 0.2514782E+00 0.1977053E+05 5.7988 5 HCO3- 0.8561190E-05 0.2674336E+01 0.1335477E+06 0.2461 6 HS- 0.1112406E-03 0.1155426E+01 0.3127309E+05 1.3319 7 H4SiO4 0.4650388E-01 0.4650707E-01 0.3658306E+04 -1.3325 8 Al+++ 0.2442072E-16 0.1058675E-04 0.2337743E+00 -4.5889 9 Ca++ 0.1154188E-05 0.1377603E-03 0.4518541E+01 3.3841 10 Mg++ 0.1435425E-05 0.1647881E-04 0.3278797E+00 3.3953 11 Fe++ 0.1203455E-07 0.2516752E-02 0.1150293E+03 1.3399 12 K+ 0.3400110E-01 0.1255818E+00 0.4018776E+04 3.8552 13 Na+ 0.1068413E+00 0.5584043E+00 0.1050635E+05 4.3154 14 Mn++ 0.1244982E-05 0.1157248E-02 0.5203162E+02 3.3701 15 Zn++ 0.3128643E-09 0.7298481E-03 0.3904623E+02 -0.2452 16 Cu+ 0.1201070E-07 0.8875427E-04 0.4615350E+01 -2.6348 17 Pb++ 0.2532669E-08 0.3297018E-03 0.5590598E+02 0.7741 18 Ag+ 0.2962986E-09 0.8760536E-05 0.7733916E+00 -4.2112 19 Ba++ 0.5685789E-07 0.7252840E-05 0.8152171E+00 2.1562 20 HPO4-- 0.1432250E-08 0.3433650E-05 0.2697121E+00 0.5753 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265488E+01 -.3125892E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5216432E+02 -.1995407E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2497646E+00 0.1958157E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1147553E+01 0.1259111E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4619017E-01 0.9740415E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1051461E-04 0.6840249E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1368216E-03 0.3910883E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1636652E-04 0.4310131E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2499603E-02 0.6267151E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247261E+00 0.6840249E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149362E-02 0.1375733E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7248750E-03 0.1574460E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.8814950E-04 0.3114602E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3274553E-03 0.1271738E-04 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7203420E-05 0.4816903E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3410254E-05 0.5157247E-05 0.0000000E+00 Chg. balance for solid moles: -.2700E-17 Mass of aqueous solution: 0.121356E+04 g Temperature = 557.00 C Pressure = 1024.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3825E-03 -3.417 0.5207E-01 -1.283 0.7534 0.1757E-01 annite 0.4798E-06 -6.319 0.2456E-03 -3.610 0.3553E-02 0.7404E-04 phlogopite 0.1437E-05 -5.843 0.5995E-03 -3.222 0.8674E-02 0.2150E-03 biotite-Mn 0.4586E-07 -7.339 0.2335E-04 -4.632 0.3378E-03 0.6999E-05 apatite-OH 0.1719E-05 -5.765 0.8635E-03 -3.064 0.1249E-01 0.2744E-03 microcline 0.6821E-03 -3.166 0.1898 -0.722 2.747 0.7416E-01 pyrite 0.5954E-02 -2.225 0.7144 -0.146 10.34 0.1425 quartz 0.9535E-01 -1.021 5.729 0.758 82.89 2.163 barite 0.4817E-04 -4.317 0.1124E-01 -1.949 0.1627 0.2510E-02 chalcopyrite 0.3115E-03 -3.507 0.5715E-01 -1.243 0.8269 0.1334E-01 galena 0.1272E-04 -4.896 0.3043E-02 -2.517 0.4402E-01 0.4005E-03 sphalerite 0.1574E-02 -2.803 0.1534 -0.814 2.219 0.3752E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2445E+00 0.2445E+00 1.0000 -0.612 phlogopite 0.7321E+00 0.7321E+00 1.0000 -0.135 biotite-Mn 0.2337E-01 0.2337E-01 1.0000 -1.631 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.911632 g Volume = 2.452032 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -14.98 -14.98 0.00 0.000 0.00000E+00 24 annite 1.12 1.12 0.00 0.000 0.59043E-11 25 phlogopite 5.86 5.86 0.00 0.000 0.33739E-10 26 biotite-Mn 10.27 10.27 0.00 0.000 -0.26991E-10 30 apatite-OH -53.85 -53.85 0.00 0.000 0.00000E+00 115 microcline -4.73 -4.73 0.00 0.000 0.13495E-10 140 pyrite -22.06 -22.06 0.00 0.000 0.00000E+00 144 quartz -1.33 -1.33 0.00 0.000 0.00000E+00 237 barite -16.21 -16.21 0.00 0.000 0.00000E+00 240 chalcopyrite -23.75 -23.75 0.00 0.000 0.00000E+00 245 galena -9.98 -9.98 0.00 0.000 0.00000E+00 255 sphalerite -11.00 -11.00 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 0.00 -0.26 -0.261 0.99145E+03 2.749 2 CO2,gas -10.14 -11.84 -1.70 -0.566 0.64536E+04 1.311 3 CH4,gas 6.83 -4.22 -11.05 -2.763 0.41984E+05 -8.042 4 H2,gas 5.99 1.90 -4.08 -2.333 0.15508E+05 -1.072 5 H2S,gas -8.45 -10.75 -2.31 -1.153 0.87590E+04 0.704 6 CO,gas -3.87 -9.93 -6.06 -1.864 0.23015E+05 -3.049 7 SO3,gas -7.67 -18.37 -10.70 -2.674 0.40637E+05 -7.687 8 O2,gas 16.95 -3.81 -20.76 -13.841 0.78863E+05 -17.751 9 HCl,gas -6.17 -7.72 -1.55 -0.776 0.58993E+04 -1.553 10 acmite 3.61 2.04 -1.56 -0.163 0.59445E+04 12 akimotoite 6.29 2.06 -4.22 -0.845 0.16042E+05 13 akimotoite-Fe 4.14 0.01 -4.13 -0.826 0.15689E+05 14 albite-high -4.11 -4.27 -0.15 -0.012 0.58493E+03 15 albite -4.11 -4.27 -0.15 -0.012 0.58370E+03 16 almandine -6.99 -9.16 -2.17 -0.108 0.82408E+04 17 pyrope -0.18 -2.99 -2.81 -0.141 0.10683E+05 18 analcite -1.94 -2.94 -1.00 -0.111 0.37912E+04 19 andalusite -9.88 -10.51 -0.63 -0.063 0.23930E+04 27 anorthite -7.54 -8.46 -0.92 -0.071 0.34886E+04 28 anthophyllite 15.19 13.12 -2.07 -0.056 0.78801E+04 29 anthophyllite-Fe 2.21 -1.27 -3.48 -0.094 0.13201E+05 31 apatite-OH-zs -51.65 -53.85 -2.20 -0.169 0.83620E+04 32 apatite-Cl-zs -58.30 -61.57 -3.27 -0.273 0.12432E+05 33 aragonite -4.72 -8.45 -3.73 -1.244 0.14177E+05 34 brucite 5.64 3.39 -2.25 -0.449 0.85303E+04 35 calcite -4.83 -8.45 -3.62 -1.208 0.13769E+05 36 carnegieite-low 0.20 -1.61 -1.81 -0.258 0.68657E+04 37 carnegieite-high 0.29 -1.61 -1.89 -0.270 0.71904E+04 38 carpholite-Mg -6.35 -8.45 -2.10 -0.140 0.79828E+04 39 carpholite-Fe -7.74 -10.51 -2.76 -0.184 0.10497E+05 40 celadonite -0.57 -2.66 -2.09 -0.123 0.79369E+04 41 celadonite-Fe -2.01 -4.72 -2.71 -0.159 0.10279E+05 42 chrysotile 9.85 7.52 -2.33 -0.194 0.88591E+04 44 clinochlore 5.14 3.79 -1.34 -0.042 0.51080E+04 45 daphnite -2.12 -6.48 -4.36 -0.136 0.16561E+05 47 chlorite-Al-free 19.87 15.04 -4.83 -0.201 0.18356E+05 48 chloritoid-Mg -5.70 -7.12 -1.42 -0.095 0.54039E+04 49 chloritoid-Fe -7.69 -9.17 -1.48 -0.099 0.56272E+04 50 chloritoid-Mn -5.55 -7.14 -1.59 -0.106 0.60570E+04 52 coesite -1.03 -1.33 -0.29 -0.098 0.11204E+04 53 cordierite-H -17.14 -18.23 -1.08 -0.039 0.41129E+04 54 cordierite-Fe -19.82 -22.34 -2.51 -0.087 0.95504E+04 55 cordierite-Mn -15.46 -18.28 -2.81 -0.097 0.10675E+05 56 corundum -8.37 -9.18 -0.81 -0.074 0.30738E+04 58 cristobalite -1.28 -1.33 -0.05 -0.016 0.18188E+03 59 cummingtonite 15.26 13.12 -2.14 -0.058 0.81434E+04 61 cymrite-K -2.39 -4.73 -2.34 -0.195 0.88940E+04 63 diaspore -3.70 -4.59 -0.90 -0.149 0.34031E+04 65 diopside 5.54 4.12 -1.43 -0.143 0.54141E+04 66 hedenbergite 4.08 2.06 -2.02 -0.202 0.76692E+04 68 eastonite -4.39 -5.79 -1.40 -0.054 0.53074E+04 69 enstatite 4.97 4.13 -0.84 -0.084 0.31873E+04 70 clinoenstatite-HiP 5.47 4.13 -1.34 -0.134 0.50965E+04 71 clinoenstatite 4.95 4.13 -0.82 -0.082 0.31203E+04 72 protoenstatite 5.10 4.13 -0.97 -0.097 0.36996E+04 73 epidote -3.42 -6.02 -2.60 -0.126 0.98582E+04 74 clinozoisite -7.98 -11.00 -3.02 -0.137 0.11468E+05 75 epidote-Fe 2.83 -1.04 -3.87 -0.201 0.14709E+05 76 fayalite 2.53 1.35 -1.18 -0.168 0.44770E+04 77 ferrosilite 1.30 0.02 -1.28 -0.128 0.48587E+04 78 forsterite 6.62 5.46 -1.16 -0.165 0.43983E+04 79 gedrite -7.11 -9.37 -2.26 -0.061 0.85887E+04 81 gibbsite -2.06 -4.59 -2.53 -0.361 0.96108E+04 82 glaucophane 2.02 -1.01 -3.03 -0.082 0.11507E+05 84 goethite 1.30 0.39 -0.91 -0.197 0.34654E+04 86 greenalite 4.84 1.35 -3.49 -0.291 0.13254E+05 87 grunerite 2.77 -1.27 -4.04 -0.109 0.15360E+05 88 halite -1.37 -3.41 -2.03 -1.017 0.77265E+04 89 hematite 1.05 0.77 -0.27 -0.033 0.10422E+04 90 heulandite -11.80 -15.12 -3.32 -0.151 0.12611E+05 91 hercynite -6.47 -7.84 -1.37 -0.092 0.52181E+04 94 jadeite -1.25 -2.94 -1.68 -0.168 0.63849E+04 96 kalsilite -0.42 -2.07 -1.64 -0.235 0.62440E+04 97 kaolinite -9.01 -11.84 -2.83 -0.258 0.10767E+05 98 kyanite -9.72 -10.51 -0.80 -0.080 0.30224E+04 100 laumontite -7.33 -11.12 -3.80 -0.253 0.14422E+05 101 lawsonite -4.77 -8.46 -3.69 -0.246 0.14009E+05 102 leucite -2.42 -3.40 -0.98 -0.098 0.37216E+04 104 lizardite 10.02 7.52 -2.50 -0.208 0.94820E+04 105 magnesite -5.51 -8.44 -2.93 -0.976 0.11120E+05 106 magnetite 2.42 2.11 -0.31 -0.025 0.11863E+04 107 minnesotaite 0.92 -1.30 -2.23 -0.131 0.84708E+04 108 minnesotaite-Mg 7.04 4.86 -2.18 -0.128 0.82716E+04 109 magnesioferrite 5.56 4.17 -1.39 -0.113 0.52780E+04 111 manganosite 5.57 3.37 -2.20 -0.549 0.83463E+04 112 margarite -15.46 -17.64 -2.18 -0.087 0.82785E+04 116 monticellite 9.05 5.45 -3.61 -0.515 0.13698E+05 118 mullite-Si -9.12 -10.51 -1.39 -0.139 0.52962E+04 119 muscovite -12.97 -13.91 -0.93 -0.055 0.35496E+04 120 paragonite -12.29 -13.45 -1.16 -0.068 0.44068E+04 121 nepheline -0.10 -1.61 -1.50 -0.215 0.57145E+04 122 osumilite(2) -12.30 -14.36 -2.06 -0.043 0.78385E+04 123 osumilite-Fe -26.79 -29.72 -2.93 -0.061 0.11122E+05 124 pargasite 7.12 2.90 -4.22 -0.111 0.16027E+05 125 periclase 5.85 3.39 -2.45 -0.613 0.93204E+04 126 periclase-Fe 3.22 1.34 -1.88 -0.470 0.71423E+04 127 perovskite-Al -6.62 -9.18 -2.56 -0.233 0.97369E+04 132 phlogopite-Na 6.74 5.91 -0.82 -0.046 0.31334E+04 134 prehnite -2.81 -6.41 -3.60 -0.212 0.13661E+05 135 prehnite-Fe 2.14 -1.43 -3.57 -0.215 0.13558E+05 138 px-Mg-tschermaks -5.06 -7.12 -2.06 -0.147 0.78297E+04 139 px-Ca-tschermaks -4.30 -7.13 -2.83 -0.202 0.10754E+05 141 pyrrhotite -8.70 -9.41 -0.71 -0.237 0.27059E+04 142 pyrrhotiteFe0.875 -9.50 -9.81 -0.32 -0.117 0.12049E+04 143 pyrophyllite -13.01 -14.50 -1.50 -0.093 0.56805E+04 146 riebeckite 5.86 2.78 -3.08 -0.085 0.11696E+05 147 ringwoodite-Fe 3.53 1.35 -2.18 -0.312 0.82880E+04 148 ringwoodite-Mg 9.81 5.46 -4.35 -0.621 0.16514E+05 149 rhodochrosite -5.53 -8.47 -2.94 -0.978 0.11151E+05 150 rhodonite 2.59 2.04 -0.55 -0.111 0.21062E+04 151 sanidine -4.18 -4.73 -0.54 -0.042 0.20672E+04 153 siderite -7.40 -10.50 -3.10 -1.033 0.11768E+05 154 sillimanite -9.84 -10.51 -0.67 -0.067 0.25424E+04 156 spinel -4.25 -5.79 -1.54 -0.102 0.58330E+04 163 stilpnomelane-Mg 1.15 -0.93 -2.08 -0.062 0.79035E+04 164 stishovite 1.66 -1.33 -2.99 -0.996 0.11352E+05 165 sudoite-Fe -14.99 -19.68 -4.69 -0.151 0.17806E+05 166 sudoite -12.70 -15.57 -2.87 -0.093 0.10893E+05 167 sulfur -11.17 -12.65 -1.49 -0.457 0.56452E+04 168 sylvite -1.28 -3.87 -2.59 -1.295 0.98374E+04 169 talc 5.29 4.86 -0.43 -0.025 0.16408E+04 170 talc-Fe 2.35 -1.30 -3.65 -0.215 0.13876E+05 171 talc-tschermaks -4.65 -6.38 -1.73 -0.102 0.65765E+04 173 tephroite 6.78 5.41 -1.37 -0.196 0.52228E+04 176 topaz-H -7.79 -10.51 -2.73 -0.248 0.10357E+05 177 tremolite 15.73 13.10 -2.64 -0.071 0.10012E+05 179 troilite-low -8.61 -9.41 -0.80 -0.267 0.30478E+04 180 tschermakite -5.79 -9.40 -3.60 -0.097 0.13688E+05 183 wadsleyite-Fe 3.38 1.35 -2.04 -0.291 0.77403E+04 184 wadsleyite-Mg 8.86 5.46 -3.40 -0.485 0.12906E+05 185 wairakite -9.21 -11.12 -1.91 -0.113 0.72707E+04 186 walstromite 4.67 2.05 -2.61 -0.523 0.99253E+04 187 wollastonite 4.24 2.05 -2.18 -0.437 0.82981E+04 188 pseudo-wollastonite 4.36 2.05 -2.30 -0.461 0.87527E+04 189 zoisite -8.03 -11.00 -2.97 -0.135 0.11278E+05 191 argentite -14.21 -19.17 -4.96 -1.240 0.18839E+05 192 beidellite-Ca -13.15 -15.02 -1.87 -0.116 0.70952E+04 193 beidellite-H -13.19 -15.58 -2.39 -0.152 0.90679E+04 194 beidellite-K -12.15 -14.31 -2.16 -0.132 0.81984E+04 195 beidellite-Mg -13.40 -15.02 -1.62 -0.100 0.61492E+04 196 beidellite-Na -12.09 -14.15 -2.06 -0.126 0.78406E+04 197 bornite -55.50 -55.79 -0.29 -0.021 0.10837E+04 199 chalcocite -14.56 -16.02 -1.46 -0.365 0.55531E+04 200 covellite -12.98 -14.34 -1.35 -0.515 0.51402E+04 202 montmorillonite-Ca -9.92 -11.31 -1.39 -0.086 0.52666E+04 203 montmorillonite-K -9.20 -10.60 -1.40 -0.086 0.53122E+04 204 montmorillonite-Mg -10.13 -11.31 -1.17 -0.073 0.44632E+04 205 montmorillonite-Na -8.86 -10.44 -1.58 -0.097 0.59973E+04 206 nontronite-Ca -3.47 -5.07 -1.60 -0.104 0.60724E+04 207 nontronite-H -3.51 -5.62 -2.11 -0.141 0.80166E+04 208 nontronite-K -2.46 -4.35 -1.89 -0.121 0.71681E+04 209 nontronite-Mg -3.68 -5.06 -1.38 -0.090 0.52526E+04 210 nontronite-Na -2.40 -4.20 -1.80 -0.115 0.68221E+04 215 gypsum -12.72 -14.99 -2.26 -0.566 0.85962E+04 231 acanthite -14.30 -19.17 -4.88 -1.219 0.18519E+05 232 alabandite -6.43 -7.38 -0.96 -0.319 0.36303E+04 234 anglesite -15.29 -17.59 -2.30 -1.152 0.87521E+04 238 boehmite -3.40 -4.59 -1.20 -0.199 0.45397E+04 242 copper,native 1.71 -1.68 -3.39 -1.180 0.12883E+05 244 ferrous-oxide 2.28 1.34 -0.95 -0.236 0.35929E+04 246 silver,native 0.42 -3.26 -3.68 -1.279 0.13968E+05 248 litharge 5.38 0.77 -4.61 -1.152 0.17509E+05 256 wurtzite -10.18 -11.00 -0.81 -0.271 0.30899E+04 257 zincite 2.36 -0.25 -2.61 -0.652 0.99053E+04 258 an20ab80 -5.02 -5.10 -0.09 -0.007 0.33836E+03 259 an25ab75 -5.21 -5.31 -0.10 -0.008 0.38305E+03 260 an30ab70 -5.41 -5.52 -0.12 -0.009 0.44872E+03 261 tr.625ac.25prg.125 10.42 9.25 -1.17 -0.032 0.44497E+04 Calculations done for 557.0000 Deg. C; 1024.0000 bar Temperature changed by -1.000 degrees to 556.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 36 Loop limit = 500 Temperature = 556.00 C Pressure = 1012.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5513E+02 kg liquid = 0.9932E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9969 Stoichiometric ionic strength = .3273352E+01 Osmotic coef. = 0.0000 True ionic strength = .1413588E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.44212E-05 -5.3545 0.89882E-06 -6.0463 0.20330E+00 -0.6919 2 H2O 0.99688E+00 -0.0014 0.99688E+00 -0.0014 3 Cl- 0.11843E+00 -0.9265 0.20495E-01 -1.6884 0.17305E+00 -0.7618 4 SO4-- 0.24341E-03 -3.6137 0.51469E-06 -6.2885 0.21145E-02 -2.6748 5 HCO3- 0.83790E-05 -5.0768 0.15589E-05 -5.8072 0.18605E+00 -0.7304 6 HS- 0.11033E-03 -3.9573 0.19246E-04 -4.7157 0.17445E+00 -0.7583 7 H4SiO4 0.45783E-01 -1.3393 0.45783E-01 -1.3393 0.10000E+01 0.0000 8 Al+++ 0.26428E-16 -16.5779 0.19984E-22 -22.6993 0.75618E-06 -6.1214 9 Ca++ 0.11520E-05 -5.9386 0.19555E-08 -8.7087 0.16975E-02 -2.7702 10 Mg++ 0.14950E-05 -5.8253 0.20941E-08 -8.6790 0.14007E-02 -2.8537 11 Fe++ 0.12027E-07 -7.9198 0.17686E-10 -10.7524 0.14705E-02 -2.8325 12 K+ 0.33773E-01 -1.4714 0.64319E-02 -2.1917 0.19044E+00 -0.7202 13 Na+ 0.10593E+00 -0.9750 0.18525E-01 -1.7322 0.17488E+00 -0.7573 14 Mn++ 0.12785E-05 -5.8933 0.19481E-08 -8.7104 0.15237E-02 -2.8171 15 Zn++ 0.31557E-09 -9.5009 0.46404E-12 -12.3334 0.14705E-02 -2.8325 16 Cu+ 0.11798E-07 -7.9282 0.20578E-08 -8.6866 0.17442E+00 -0.7584 17 Pb++ 0.25127E-08 -8.5999 0.47718E-11 -11.3213 0.18991E-02 -2.7215 18 Ag+ 0.29569E-09 -9.5292 0.55446E-10 -10.2561 0.18751E+00 -0.7270 19 Ba++ 0.56070E-07 -7.2513 0.11434E-09 -9.9418 0.20392E-02 -2.6905 20 HPO4-- 0.14674E-08 -8.8334 0.31183E-11 -11.5061 0.21251E-02 -2.6726 21 HSiO3- 0.12617E-05 -5.8991 0.21834E-06 -6.6609 0.17305E+00 -0.7618 22 Ca(HSiO3)+ 0.39058E-08 -8.4083 0.75030E-09 -9.1248 0.19210E+00 -0.7165 23 Mg(HSiO3)+ 0.13691E-08 -8.8636 0.26300E-09 -9.5800 0.19210E+00 -0.7165 24 NaHSiO3,aq 0.18957E-05 -5.7222 0.18957E-05 -5.7222 0.10000E+01 0.0000 28 AgCl,aq 0.12600E-06 -6.8996 0.12600E-06 -6.8996 0.10000E+01 0.0000 29 AgCl2- 0.53971E-05 -5.2678 0.93398E-06 -6.0297 0.17305E+00 -0.7618 30 AgCl3-2 0.16932E-05 -5.7713 0.33166E-08 -8.4793 0.19588E-02 -2.7080 31 AgCl4-3 0.15343E-05 -5.8141 0.10222E-11 -11.9904 0.66625E-06 -6.1764 34 Ag(HS),aq 0.22303E-08 -8.6516 0.22303E-08 -8.6516 0.10000E+01 0.0000 35 Ag(HS)2- 0.72724E-08 -8.1383 0.12585E-08 -8.9001 0.17305E+00 -0.7618 36 AlO+ 0.10606E-10 -10.9744 0.20374E-11 -11.6909 0.19210E+00 -0.7165 38 HAlO2,aq 0.42107E-08 -8.3756 0.42107E-08 -8.3756 0.10000E+01 0.0000 39 AlO2- 0.10408E-04 -4.9827 0.15867E-05 -5.7995 0.15246E+00 -0.8168 41 Ba(HCO3)+ 0.17081E-06 -6.7675 0.34126E-07 -7.4669 0.19979E+00 -0.6994 42 BaCl+ 0.68191E-05 -5.1663 0.13099E-05 -5.8828 0.19210E+00 -0.7165 43 CH4,aq 0.13976E-08 -8.8546 0.16532E-08 -8.7817 0.11829E+01 0.0730 48 CO,aq 0.46994E-03 -3.3280 0.46994E-03 -3.3280 0.10000E+01 0.0000 49 CO2,aq 0.26738E+01 0.4271 0.31629E+01 0.5001 0.11829E+01 0.0730 50 CO3-2 0.35033E-10 -10.4555 0.68623E-13 -13.1635 0.19588E-02 -2.7080 52 Ca(HCO3)+ 0.80937E-07 -7.0919 0.15548E-07 -7.8083 0.19210E+00 -0.7165 53 CaCl+ 0.63721E-04 -4.1957 0.12241E-04 -4.9122 0.19210E+00 -0.7165 54 CaCl2,aq 0.70277E-04 -4.1532 0.70277E-04 -4.1532 0.10000E+01 0.0000 55 CaOH+ 0.11955E-06 -6.9224 0.22965E-07 -7.6389 0.19210E+00 -0.7165 56 CaSO4,aq 0.17809E-06 -6.7494 0.17809E-06 -6.7494 0.10000E+01 0.0000 57 HCl,aq 0.35667E-02 -2.4477 0.35667E-02 -2.4477 0.10000E+01 0.0000 66 CuCl,aq 0.20526E-04 -4.6877 0.20526E-04 -4.6877 0.10000E+01 0.0000 67 CuCl2- 0.66529E-04 -4.1770 0.11513E-04 -4.9388 0.17305E+00 -0.7618 68 CuCl3-2 0.11533E-05 -5.9380 0.22591E-08 -8.6461 0.19588E-02 -2.7080 74 FeCl+ 0.20763E-06 -6.6827 0.39885E-07 -7.3992 0.19210E+00 -0.7165 75 FeCl2,aq 0.24318E-02 -2.6141 0.24318E-02 -2.6141 0.10000E+01 0.0000 77 FeO,aq 0.50866E-07 -7.2936 0.50866E-07 -7.2936 0.10000E+01 0.0000 78 FeOH+ 0.17270E-07 -7.7627 0.33176E-08 -8.4792 0.19210E+00 -0.7165 79 HFeO2- 0.53373E-08 -8.2727 0.92363E-09 -9.0345 0.17305E+00 -0.7618 82 FeO2- 0.33725E-08 -8.4721 0.58361E-09 -9.2339 0.17305E+00 -0.7618 83 HFeO2,aq 0.26893E-09 -9.5704 0.26893E-09 -9.5704 0.10000E+01 0.0000 84 H2,aq 0.43102E-02 -2.3655 0.50985E-02 -2.2926 0.11829E+01 0.0730 85 KCl,aq 0.73194E-01 -1.1355 0.73194E-01 -1.1355 0.10000E+01 0.0000 86 KHSO4,aq 0.13761E-01 -1.8613 0.13761E-01 -1.8613 0.10000E+01 0.0000 87 KOH,aq 0.13915E-05 -5.8565 0.13915E-05 -5.8565 0.10000E+01 0.0000 88 KSO4- 0.48486E-02 -2.3144 0.83907E-03 -3.0762 0.17305E+00 -0.7618 90 Mg(HCO3)+ 0.28895E-07 -7.5392 0.55507E-08 -8.2557 0.19210E+00 -0.7165 91 MgCl+ 0.14853E-04 -4.8282 0.28533E-05 -5.5447 0.19210E+00 -0.7165 92 MgOH+ 0.55340E-06 -6.2570 0.10631E-06 -6.9734 0.19210E+00 -0.7165 94 MnO,aq 0.97012E-07 -7.0132 0.97012E-07 -7.0132 0.10000E+01 0.0000 95 MnOH+ 0.20744E-06 -6.6831 0.39848E-07 -7.3996 0.19210E+00 -0.7165 97 HMnO2- 0.39751E-10 -10.4007 0.68790E-11 -11.1625 0.17305E+00 -0.7618 100 MnCl+ 0.11555E-02 -2.9372 0.22196E-03 -3.6537 0.19210E+00 -0.7165 101 MnSO4,aq 0.18966E-06 -6.7220 0.18966E-06 -6.7220 0.10000E+01 0.0000 102 NaCl,aq 0.45245E+00 -0.3444 0.45245E+00 -0.3444 0.10000E+01 0.0000 103 NaOH,aq 0.18303E-05 -5.7375 0.18303E-05 -5.7375 0.10000E+01 0.0000 105 OH- 0.68423E-05 -5.1648 0.10432E-05 -5.9816 0.15246E+00 -0.8168 111 H3PO3,aq 0.12197E-09 -9.9137 0.12197E-09 -9.9137 0.10000E+01 0.0000 112 H2PO3- 0.17303E-08 -8.7619 0.29943E-09 -9.5237 0.17305E+00 -0.7618 113 H3PO4,aq 0.15726E-05 -5.8034 0.15726E-05 -5.8034 0.10000E+01 0.0000 114 H2PO4- 0.14387E-05 -5.8420 0.26138E-06 -6.5827 0.18168E+00 -0.7407 116 H4P2O7,aq 0.22902E-09 -9.6401 0.22902E-09 -9.6401 0.10000E+01 0.0000 117 H3P2O7- 0.99321E-09 -9.0030 0.17188E-09 -9.7648 0.17305E+00 -0.7618 118 H2P2O7-2 0.22790E-06 -6.6423 0.44641E-09 -9.3503 0.19588E-02 -2.7080 119 HP2O7-3 0.26458E-07 -7.5774 0.17628E-13 -13.7538 0.66625E-06 -6.1764 121 PbCl+ 0.10957E-05 -5.9603 0.21048E-06 -6.6768 0.19210E+00 -0.7165 122 PbCl2,aq 0.82923E-04 -4.0813 0.82923E-04 -4.0813 0.10000E+01 0.0000 123 PbCl3- 0.91613E-04 -4.0380 0.15854E-04 -4.7999 0.17305E+00 -0.7618 124 PbCl4-2 0.14676E-04 -4.8334 0.28747E-07 -7.5414 0.19588E-02 -2.7080 125 PbO,aq 0.64628E-08 -8.1896 0.64628E-08 -8.1896 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12227E-03 -3.9127 0.12227E-03 -3.9127 0.10000E+01 0.0000 128 Pb(HS)3- 0.13135E-04 -4.8816 0.22731E-05 -5.6434 0.17305E+00 -0.7618 129 H2S,aq 0.10591E+01 0.0250 0.12529E+01 0.0979 0.11829E+01 0.0730 130 S2-2 0.11250E-07 -7.9488 0.22037E-10 -10.6569 0.19588E-02 -2.7080 131 S3-2 0.10589E-08 -8.9751 0.20742E-11 -11.6831 0.19588E-02 -2.7080 132 S3- 0.88602E-02 -2.0526 0.15333E-02 -2.8144 0.17305E+00 -0.7618 133 S4-2 0.84873E-10 -10.0712 0.16625E-12 -12.7792 0.19588E-02 -2.7080 135 SO2,aq 0.29365E+00 -0.5322 0.29365E+00 -0.5322 0.10000E+01 0.0000 136 SO3-2 0.62345E-09 -9.2052 0.19329E-11 -11.7138 0.31004E-02 -2.5086 137 HSO3- 0.22472E-03 -3.6484 0.38889E-04 -4.4102 0.17305E+00 -0.7618 138 HSO4- 0.78423E-02 -2.1056 0.15478E-02 -2.8103 0.19737E+00 -0.7047 140 S2O3-2 0.49745E-06 -6.3032 0.97442E-09 -9.0113 0.19588E-02 -2.7080 141 HS2O3- 0.34887E-06 -6.4573 0.60373E-07 -7.2192 0.17305E+00 -0.7618 142 H2S2O3,aq 0.37321E-07 -7.4281 0.37321E-07 -7.4281 0.10000E+01 0.0000 150 S4O6-2 0.42991E-09 -9.3666 0.84211E-12 -12.0746 0.19588E-02 -2.7080 152 ZnCl+ 0.12543E-03 -3.9016 0.24094E-04 -4.6181 0.19210E+00 -0.7165 153 ZnCl2,aq 0.55601E-03 -3.2549 0.55601E-03 -3.2549 0.10000E+01 0.0000 154 ZnCl3- 0.35421E-04 -4.4507 0.61297E-05 -5.2126 0.17305E+00 -0.7618 155 ZnO,aq 0.25865E-07 -7.5873 0.25865E-07 -7.5873 0.10000E+01 0.0000 156 ZnOH+ 0.87628E-06 -6.0574 0.16833E-06 -6.7738 0.19210E+00 -0.7165 158 HZnO2- 0.17735E-09 -9.7512 0.30692E-10 -10.5130 0.17305E+00 -0.7618 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4421152E-05 0.4294648E+01 0.3542911E+04 0.0000 2 H2O 0.1000000E+01 0.5252252E+02 0.7744352E+06 0.0000 3 Cl- 0.1184322E+00 0.6559150E+00 0.1903262E+05 4.3580 4 SO4-- 0.2434112E-03 0.2514487E+00 0.1976957E+05 5.8042 5 HCO3- 0.8379001E-05 0.2674274E+01 0.1335538E+06 0.2391 6 HS- 0.1103280E-03 0.1155235E+01 0.3127007E+05 1.3307 7 H4SiO4 0.4578257E-01 0.4578573E-01 0.3601813E+04 -1.3393 8 Al+++ 0.2642807E-16 0.1041180E-04 0.2299270E+00 -4.5603 9 Ca++ 0.1151950E-05 0.1355322E-03 0.4445764E+01 3.3839 10 Mg++ 0.1495047E-05 0.1693199E-04 0.3369200E+00 3.4137 11 Fe++ 0.1202723E-07 0.2432111E-02 0.1111684E+03 1.3403 12 K+ 0.3377337E-01 0.1255787E+00 0.4018955E+04 3.8547 13 Na+ 0.1059342E+00 0.5583914E+00 0.1050684E+05 4.3141 14 Mn++ 0.1278514E-05 0.1157237E-02 0.5203472E+02 3.3823 15 Zn++ 0.3155693E-09 0.7177628E-03 0.3840232E+02 -0.2408 16 Cu+ 0.1179778E-07 0.8821982E-04 0.4587873E+01 -2.6403 17 Pb++ 0.2512674E-08 0.3257172E-03 0.5523412E+02 0.7713 18 Ag+ 0.2956888E-09 0.8760334E-05 0.7734270E+00 -4.2098 19 Ba++ 0.5607033E-07 0.7045946E-05 0.7920168E+00 2.1508 20 HPO4-- 0.1467416E-08 0.3525764E-05 0.2769667E+00 0.5866 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265483E+01 -.3120617E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5216584E+02 -.2010559E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2497411E+00 0.1981710E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1147390E+01 0.1275447E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4547480E-01 0.9811952E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1034109E-04 0.6841984E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1346117E-03 0.3932981E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1681701E-04 0.3859647E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2415594E-02 0.6351160E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247259E+00 0.6841984E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149378E-02 0.1218247E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7128884E-03 0.1586446E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.8762072E-04 0.3119890E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3235052E-03 0.1666745E-04 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.6998097E-05 0.4837436E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3501821E-05 0.5065680E-05 0.0000000E+00 Chg. balance for solid moles: 0.3093E-17 Mass of aqueous solution: 0.121351E+04 g Temperature = 556.00 C Pressure = 1012.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3849E-03 -3.415 0.5239E-01 -1.281 0.7520 0.1768E-01 annite 0.4141E-06 -6.383 0.2120E-03 -3.674 0.3042E-02 0.6390E-04 phlogopite 0.1287E-05 -5.891 0.5369E-03 -3.270 0.7706E-02 0.1925E-03 biotite-Mn 0.4061E-07 -7.391 0.2068E-04 -4.685 0.2968E-03 0.6198E-05 apatite-OH 0.1689E-05 -5.772 0.8482E-03 -3.072 0.1217E-01 0.2695E-03 microcline 0.6825E-03 -3.166 0.1900 -0.721 2.726 0.7420E-01 pyrite 0.6038E-02 -2.219 0.7244 -0.140 10.40 0.1445 quartz 0.9607E-01 -1.017 5.772 0.761 82.84 2.180 barite 0.4837E-04 -4.315 0.1129E-01 -1.947 0.1621 0.2520E-02 chalcopyrite 0.3120E-03 -3.506 0.5725E-01 -1.242 0.8217 0.1336E-01 galena 0.1667E-04 -4.778 0.3988E-02 -2.399 0.5724E-01 0.5248E-03 sphalerite 0.1586E-02 -2.800 0.1546 -0.811 2.219 0.3780E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2378E+00 0.2378E+00 1.0000 -0.624 phlogopite 0.7389E+00 0.7389E+00 1.0000 -0.131 biotite-Mn 0.2332E-01 0.2332E-01 1.0000 -1.632 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.967194 g Volume = 2.470810 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.00 -15.00 0.00 0.000 0.00000E+00 24 annite 1.17 1.17 0.00 0.000 0.84245E-11 25 phlogopite 5.91 5.91 0.00 0.000 0.13479E-10 26 biotite-Mn 10.32 10.32 0.00 0.000 -0.13479E-10 30 apatite-OH -53.88 -53.88 0.00 0.000 0.00000E+00 115 microcline -4.72 -4.72 0.00 0.000 0.00000E+00 140 pyrite -22.09 -22.09 0.00 0.000 0.13479E-10 144 quartz -1.34 -1.34 0.00 0.000 0.00000E+00 237 barite -16.23 -16.23 0.00 0.000 0.00000E+00 240 chalcopyrite -23.78 -23.78 0.00 0.000 -0.13479E-10 245 galena -9.99 -9.99 0.00 0.000 -0.67396E-11 255 sphalerite -11.00 -11.00 0.00 0.000 0.67396E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 0.00 -0.26 -0.260 0.98724E+03 2.745 2 CO2,gas -10.15 -11.85 -1.70 -0.567 0.64521E+04 1.305 3 CH4,gas 6.83 -4.24 -11.06 -2.765 0.41970E+05 -8.057 4 H2,gas 5.99 1.90 -4.09 -2.334 0.15499E+05 -1.080 5 H2S,gas -8.46 -10.76 -2.30 -1.152 0.87417E+04 0.701 6 CO,gas -3.88 -9.95 -6.07 -1.867 0.23017E+05 -3.062 7 SO3,gas -7.67 -18.38 -10.71 -2.677 0.40620E+05 -7.701 8 O2,gas 16.98 -3.81 -20.79 -13.858 0.78865E+05 -17.781 9 HCl,gas -6.17 -7.73 -1.56 -0.780 0.59209E+04 -1.561 10 acmite 3.60 2.03 -1.58 -0.164 0.59852E+04 12 akimotoite 6.30 2.08 -4.22 -0.845 0.16029E+05 13 akimotoite-Fe 4.15 0.00 -4.15 -0.829 0.15734E+05 14 albite-high -4.10 -4.26 -0.16 -0.012 0.59464E+03 15 albite -4.10 -4.26 -0.16 -0.012 0.58928E+03 16 almandine -6.91 -9.12 -2.21 -0.111 0.83887E+04 17 pyrope -0.09 -2.90 -2.81 -0.140 0.10660E+05 18 analcite -1.92 -2.92 -1.00 -0.111 0.37969E+04 19 andalusite -9.83 -10.46 -0.63 -0.063 0.24005E+04 27 anorthite -7.48 -8.42 -0.93 -0.072 0.35340E+04 28 anthophyllite 15.24 13.19 -2.05 -0.055 0.77807E+04 29 anthophyllite-Fe 2.24 -1.32 -3.56 -0.096 0.13502E+05 31 apatite-OH-zs -51.67 -53.88 -2.20 -0.170 0.83646E+04 32 apatite-Cl-zs -58.34 -61.61 -3.27 -0.273 0.12424E+05 33 aragonite -4.73 -8.47 -3.74 -1.248 0.14202E+05 34 brucite 5.65 3.41 -2.24 -0.449 0.85102E+04 35 calcite -4.83 -8.47 -3.64 -1.212 0.13793E+05 36 carnegieite-low 0.23 -1.59 -1.81 -0.259 0.68705E+04 37 carnegieite-high 0.31 -1.59 -1.90 -0.271 0.71975E+04 38 carpholite-Mg -6.29 -8.39 -2.10 -0.140 0.79595E+04 39 carpholite-Fe -7.69 -10.46 -2.78 -0.185 0.10533E+05 40 celadonite -0.56 -2.64 -2.09 -0.123 0.79163E+04 41 celadonite-Fe -2.00 -4.72 -2.72 -0.160 0.10319E+05 42 chrysotile 9.88 7.56 -2.32 -0.193 0.88000E+04 44 clinochlore 5.24 3.92 -1.32 -0.041 0.50076E+04 45 daphnite -2.03 -6.45 -4.42 -0.138 0.16755E+05 47 chlorite-Al-free 19.93 15.12 -4.81 -0.200 0.18233E+05 48 chloritoid-Mg -5.63 -7.05 -1.42 -0.095 0.53875E+04 49 chloritoid-Fe -7.63 -9.12 -1.49 -0.100 0.56661E+04 50 chloritoid-Mn -5.49 -7.08 -1.59 -0.106 0.60493E+04 52 coesite -1.04 -1.34 -0.30 -0.099 0.11213E+04 53 cordierite-H -17.03 -18.11 -1.08 -0.039 0.41049E+04 54 cordierite-Fe -19.71 -22.25 -2.54 -0.088 0.96537E+04 55 cordierite-Mn -15.35 -18.17 -2.82 -0.097 0.10683E+05 56 corundum -8.31 -9.12 -0.81 -0.074 0.30822E+04 58 cristobalite -1.29 -1.34 -0.05 -0.016 0.18190E+03 59 cummingtonite 15.31 13.19 -2.12 -0.057 0.80449E+04 61 cymrite-K -2.37 -4.72 -2.34 -0.195 0.88968E+04 63 diaspore -3.67 -4.56 -0.90 -0.149 0.34006E+04 65 diopside 5.55 4.12 -1.43 -0.143 0.54363E+04 66 hedenbergite 4.09 2.05 -2.04 -0.204 0.77502E+04 68 eastonite -4.29 -5.68 -1.39 -0.054 0.52817E+04 69 enstatite 4.98 4.15 -0.83 -0.083 0.31621E+04 70 clinoenstatite-HiP 5.49 4.15 -1.34 -0.134 0.50717E+04 71 clinoenstatite 4.97 4.15 -0.82 -0.082 0.30945E+04 72 protoenstatite 5.12 4.15 -0.97 -0.097 0.36753E+04 73 epidote -3.36 -5.98 -2.63 -0.127 0.99715E+04 74 clinozoisite -7.89 -10.93 -3.04 -0.138 0.11546E+05 75 epidote-Fe 2.88 -1.03 -3.92 -0.203 0.14855E+05 76 fayalite 2.54 1.34 -1.20 -0.172 0.45669E+04 77 ferrosilite 1.31 0.00 -1.30 -0.130 0.49491E+04 78 forsterite 6.64 5.49 -1.15 -0.165 0.43720E+04 79 gedrite -6.96 -9.21 -2.25 -0.061 0.85320E+04 81 gibbsite -2.03 -4.56 -2.53 -0.362 0.96030E+04 82 glaucophane 2.07 -0.96 -3.02 -0.082 0.11459E+05 84 goethite 1.31 0.39 -0.92 -0.199 0.35005E+04 86 greenalite 4.86 1.34 -3.52 -0.294 0.13368E+05 87 grunerite 2.81 -1.32 -4.13 -0.112 0.15664E+05 88 halite -1.39 -3.42 -2.03 -1.017 0.77157E+04 89 hematite 1.07 0.77 -0.29 -0.036 0.11192E+04 90 heulandite -11.77 -15.11 -3.33 -0.151 0.12645E+05 91 hercynite -6.40 -7.79 -1.39 -0.093 0.52721E+04 94 jadeite -1.24 -2.92 -1.68 -0.168 0.63881E+04 96 kalsilite -0.40 -2.04 -1.65 -0.235 0.62462E+04 97 kaolinite -8.97 -11.80 -2.83 -0.258 0.10748E+05 98 kyanite -9.66 -10.46 -0.80 -0.080 0.30297E+04 100 laumontite -7.29 -11.09 -3.81 -0.254 0.14447E+05 101 lawsonite -4.72 -8.42 -3.70 -0.247 0.14034E+05 102 leucite -2.40 -3.38 -0.98 -0.098 0.37259E+04 104 lizardite 10.04 7.56 -2.48 -0.207 0.94186E+04 105 magnesite -5.52 -8.44 -2.92 -0.975 0.11094E+05 106 magnetite 2.46 2.11 -0.34 -0.028 0.13086E+04 107 minnesotaite 0.93 -1.33 -2.26 -0.133 0.85917E+04 108 minnesotaite-Mg 7.06 4.89 -2.17 -0.127 0.82183E+04 109 magnesioferrite 5.59 4.19 -1.41 -0.115 0.53428E+04 111 manganosite 5.58 3.38 -2.20 -0.550 0.83434E+04 112 margarite -15.35 -17.54 -2.19 -0.088 0.83209E+04 116 monticellite 9.07 5.46 -3.62 -0.517 0.13719E+05 118 mullite-Si -9.06 -10.46 -1.40 -0.140 0.53066E+04 119 muscovite -12.91 -13.84 -0.94 -0.055 0.35512E+04 120 paragonite -12.22 -13.38 -1.16 -0.068 0.44115E+04 121 nepheline -0.08 -1.59 -1.51 -0.215 0.57189E+04 122 osumilite(2) -12.24 -14.30 -2.06 -0.043 0.78139E+04 123 osumilite-Fe -26.69 -29.65 -2.96 -0.062 0.11233E+05 124 pargasite 7.25 3.02 -4.23 -0.111 0.16061E+05 125 periclase 5.87 3.41 -2.45 -0.613 0.93067E+04 126 periclase-Fe 3.23 1.34 -1.89 -0.474 0.71881E+04 127 perovskite-Al -6.56 -9.12 -2.57 -0.234 0.97452E+04 132 phlogopite-Na 6.79 5.98 -0.81 -0.045 0.30905E+04 134 prehnite -2.75 -6.37 -3.62 -0.213 0.13730E+05 135 prehnite-Fe 2.18 -1.42 -3.60 -0.217 0.13662E+05 138 px-Mg-tschermaks -4.99 -7.05 -2.06 -0.147 0.78276E+04 139 px-Ca-tschermaks -4.23 -7.08 -2.85 -0.203 0.10798E+05 141 pyrrhotite -8.70 -9.42 -0.72 -0.240 0.27341E+04 142 pyrrhotiteFe0.875 -9.50 -9.83 -0.32 -0.119 0.12275E+04 143 pyrophyllite -12.98 -14.47 -1.50 -0.094 0.56787E+04 146 riebeckite 5.86 2.72 -3.14 -0.087 0.11898E+05 147 ringwoodite-Fe 3.55 1.34 -2.21 -0.315 0.83756E+04 148 ringwoodite-Mg 9.83 5.49 -4.35 -0.621 0.16486E+05 149 rhodochrosite -5.54 -8.47 -2.93 -0.978 0.11135E+05 150 rhodonite 2.60 2.04 -0.55 -0.111 0.21042E+04 151 sanidine -4.17 -4.72 -0.54 -0.042 0.20675E+04 153 siderite -7.40 -10.51 -3.11 -1.037 0.11799E+05 154 sillimanite -9.79 -10.46 -0.67 -0.067 0.25510E+04 156 spinel -4.18 -5.71 -1.54 -0.102 0.58276E+04 163 stilpnomelane-Mg 1.22 -0.84 -2.06 -0.061 0.78150E+04 164 stishovite 1.66 -1.34 -2.99 -0.997 0.11350E+05 165 sudoite-Fe -14.87 -19.59 -4.72 -0.152 0.17898E+05 166 sudoite -12.58 -15.44 -2.86 -0.092 0.10868E+05 167 sulfur -11.18 -12.67 -1.48 -0.456 0.56269E+04 168 sylvite -1.29 -3.88 -2.59 -1.294 0.98220E+04 169 talc 5.31 4.89 -0.42 -0.025 0.15885E+04 170 talc-Fe 2.36 -1.33 -3.69 -0.217 0.13998E+05 171 talc-tschermaks -4.59 -6.31 -1.73 -0.102 0.65469E+04 173 tephroite 6.80 5.43 -1.37 -0.196 0.52164E+04 176 topaz-H -7.73 -10.46 -2.73 -0.248 0.10353E+05 177 tremolite 15.77 13.13 -2.64 -0.071 0.10005E+05 179 troilite-low -8.61 -9.42 -0.81 -0.270 0.30744E+04 180 tschermakite -5.65 -9.27 -3.62 -0.098 0.13723E+05 183 wadsleyite-Fe 3.41 1.34 -2.06 -0.295 0.78301E+04 184 wadsleyite-Mg 8.88 5.49 -3.39 -0.485 0.12879E+05 185 wairakite -9.17 -11.09 -1.92 -0.113 0.73021E+04 186 walstromite 4.67 2.05 -2.63 -0.525 0.99612E+04 187 wollastonite 4.24 2.05 -2.20 -0.439 0.83328E+04 188 pseudo-wollastonite 4.36 2.05 -2.32 -0.463 0.87879E+04 189 zoisite -7.94 -10.93 -2.99 -0.136 0.11357E+05 191 argentite -14.24 -19.18 -4.94 -1.235 0.18737E+05 192 beidellite-Ca -13.11 -14.98 -1.87 -0.116 0.71001E+04 193 beidellite-H -13.15 -15.54 -2.39 -0.152 0.90659E+04 194 beidellite-K -12.10 -14.27 -2.16 -0.132 0.81966E+04 195 beidellite-Mg -13.35 -14.97 -1.62 -0.100 0.61476E+04 196 beidellite-Na -12.05 -14.11 -2.07 -0.127 0.78396E+04 197 bornite -55.59 -55.86 -0.27 -0.020 0.10282E+04 199 chalcocite -14.59 -16.04 -1.46 -0.364 0.55219E+04 200 covellite -13.01 -14.35 -1.35 -0.513 0.51103E+04 202 montmorillonite-Ca -9.90 -11.28 -1.39 -0.086 0.52649E+04 203 montmorillonite-K -9.17 -10.57 -1.40 -0.086 0.53068E+04 204 montmorillonite-Mg -10.10 -11.28 -1.17 -0.073 0.44533E+04 205 montmorillonite-Na -8.84 -10.42 -1.58 -0.097 0.59882E+04 206 nontronite-Ca -3.46 -5.08 -1.62 -0.105 0.61483E+04 207 nontronite-H -3.51 -5.64 -2.13 -0.143 0.80859E+04 208 nontronite-K -2.46 -4.37 -1.91 -0.122 0.72373E+04 209 nontronite-Mg -3.67 -5.08 -1.40 -0.091 0.53207E+04 210 nontronite-Na -2.40 -4.22 -1.82 -0.117 0.68921E+04 215 gypsum -12.74 -15.00 -2.26 -0.566 0.85915E+04 231 acanthite -14.33 -19.18 -4.85 -1.214 0.18419E+05 232 alabandite -6.43 -7.38 -0.95 -0.317 0.36135E+04 234 anglesite -15.31 -17.61 -2.30 -1.151 0.87359E+04 238 boehmite -3.37 -4.56 -1.20 -0.199 0.45392E+04 242 copper,native 1.70 -1.69 -3.39 -1.180 0.12872E+05 244 ferrous-oxide 2.30 1.34 -0.96 -0.240 0.36399E+04 246 silver,native 0.41 -3.26 -3.67 -1.276 0.13920E+05 248 litharge 5.39 0.77 -4.62 -1.155 0.17523E+05 256 wurtzite -10.19 -11.00 -0.81 -0.272 0.30904E+04 257 zincite 2.37 -0.24 -2.61 -0.654 0.99213E+04 258 an20ab80 -5.00 -5.09 -0.09 -0.007 0.35288E+03 259 an25ab75 -5.19 -5.30 -0.11 -0.008 0.39946E+03 260 an30ab70 -5.38 -5.51 -0.12 -0.009 0.46741E+03 261 tr.625ac.25prg.125 10.47 9.28 -1.19 -0.032 0.45326E+04 Calculations done for 556.0000 Deg. C; 1012.0000 bar Temperature changed by -1.000 degrees to 555.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 36 Loop limit = 500 Temperature = 555.00 C Pressure = 1000.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5513E+02 kg liquid = 0.9932E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9969 Stoichiometric ionic strength = .3272912E+01 Osmotic coef. = 0.0000 True ionic strength = .1402056E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.43925E-05 -5.3573 0.88881E-06 -6.0512 0.20235E+00 -0.6939 2 H2O 0.99690E+00 -0.0014 0.99690E+00 -0.0014 3 Cl- 0.11743E+00 -0.9302 0.20211E-01 -1.6944 0.17212E+00 -0.7642 4 SO4-- 0.24587E-03 -3.6093 0.50983E-06 -6.2926 0.20736E-02 -2.6833 5 HCO3- 0.82002E-05 -5.0862 0.15173E-05 -5.8189 0.18503E+00 -0.7328 6 HS- 0.10940E-03 -3.9610 0.18981E-04 -4.7217 0.17350E+00 -0.7607 7 H4SiO4 0.45074E-01 -1.3461 0.45074E-01 -1.3461 0.10000E+01 0.0000 8 Al+++ 0.28498E-16 -16.5452 0.20618E-22 -22.6857 0.72351E-06 -6.1406 9 Ca++ 0.11480E-05 -5.9401 0.19107E-08 -8.7188 0.16644E-02 -2.7787 10 Mg++ 0.15542E-05 -5.8085 0.21348E-08 -8.6707 0.13735E-02 -2.8622 11 Fe++ 0.12001E-07 -7.9208 0.17305E-10 -10.7618 0.14419E-02 -2.8411 12 K+ 0.33541E-01 -1.4744 0.63523E-02 -2.1971 0.18939E+00 -0.7226 13 Na+ 0.10502E+00 -0.9787 0.18264E-01 -1.7384 0.17392E+00 -0.7596 14 Mn++ 0.13115E-05 -5.8822 0.19595E-08 -8.7079 0.14941E-02 -2.8256 15 Zn++ 0.31782E-09 -9.4978 0.45827E-12 -12.3389 0.14419E-02 -2.8411 16 Cu+ 0.11584E-07 -7.9361 0.20095E-08 -8.6969 0.17347E+00 -0.7608 17 Pb++ 0.24896E-08 -8.6039 0.46358E-11 -11.3339 0.18620E-02 -2.7300 18 Ag+ 0.29523E-09 -9.5298 0.55054E-10 -10.2592 0.18648E+00 -0.7294 19 Ba++ 0.55215E-07 -7.2579 0.11040E-09 -9.9570 0.19994E-02 -2.6991 20 HPO4-- 0.15023E-08 -8.8232 0.31307E-11 -11.5044 0.20839E-02 -2.6811 21 HSiO3- 0.12403E-05 -5.9065 0.21347E-06 -6.6707 0.17212E+00 -0.7642 22 Ca(HSiO3)+ 0.38002E-08 -8.4202 0.72597E-09 -9.1391 0.19103E+00 -0.7189 23 Mg(HSiO3)+ 0.13970E-08 -8.8548 0.26688E-09 -9.5737 0.19103E+00 -0.7189 24 NaHSiO3,aq 0.18899E-05 -5.7236 0.18899E-05 -5.7236 0.10000E+01 0.0000 28 AgCl,aq 0.12754E-06 -6.8944 0.12754E-06 -6.8944 0.10000E+01 0.0000 29 AgCl2- 0.54047E-05 -5.2672 0.93024E-06 -6.0314 0.17212E+00 -0.7642 30 AgCl3-2 0.16814E-05 -5.7743 0.32298E-08 -8.4908 0.19209E-02 -2.7165 31 AgCl4-3 0.15366E-05 -5.8134 0.98010E-12 -12.0087 0.63784E-06 -6.1953 34 Ag(HS),aq 0.22934E-08 -8.6395 0.22934E-08 -8.6395 0.10000E+01 0.0000 35 Ag(HS)2- 0.73319E-08 -8.1348 0.12619E-08 -8.8990 0.17212E+00 -0.7642 36 AlO+ 0.10819E-10 -10.9658 0.20667E-11 -11.6847 0.19103E+00 -0.7189 38 HAlO2,aq 0.42487E-08 -8.3717 0.42487E-08 -8.3717 0.10000E+01 0.0000 39 AlO2- 0.10231E-04 -4.9901 0.15517E-05 -5.8092 0.15167E+00 -0.8191 41 Ba(HCO3)+ 0.16486E-06 -6.7829 0.32754E-07 -7.4847 0.19868E+00 -0.7018 42 BaCl+ 0.66211E-05 -5.1791 0.12649E-05 -5.8980 0.19103E+00 -0.7189 43 CH4,aq 0.13748E-08 -8.8617 0.16250E-08 -8.7891 0.11820E+01 0.0726 48 CO,aq 0.46065E-03 -3.3366 0.46065E-03 -3.3366 0.10000E+01 0.0000 49 CO2,aq 0.26737E+01 0.4271 0.31603E+01 0.4997 0.11820E+01 0.0726 50 CO3-2 0.34604E-10 -10.4609 0.66471E-13 -13.1774 0.19209E-02 -2.7165 52 Ca(HCO3)+ 0.78034E-07 -7.1077 0.14907E-07 -7.8266 0.19103E+00 -0.7189 53 CaCl+ 0.62417E-04 -4.2047 0.11924E-04 -4.9236 0.19103E+00 -0.7189 54 CaCl2,aq 0.69343E-04 -4.1590 0.69343E-04 -4.1590 0.10000E+01 0.0000 55 CaOH+ 0.11639E-06 -6.9341 0.22235E-07 -7.6530 0.19103E+00 -0.7189 56 CaSO4,aq 0.18030E-06 -6.7440 0.18030E-06 -6.7440 0.10000E+01 0.0000 57 HCl,aq 0.36519E-02 -2.4375 0.36519E-02 -2.4375 0.10000E+01 0.0000 66 CuCl,aq 0.20450E-04 -4.6893 0.20450E-04 -4.6893 0.10000E+01 0.0000 67 CuCl2- 0.66062E-04 -4.1800 0.11370E-04 -4.9442 0.17212E+00 -0.7642 68 CuCl3-2 0.11392E-05 -5.9434 0.21883E-08 -8.6599 0.19209E-02 -2.7165 74 FeCl+ 0.20377E-06 -6.6909 0.38928E-07 -7.4097 0.19103E+00 -0.7189 75 FeCl2,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 77 FeO,aq 0.49255E-07 -7.3075 0.49255E-07 -7.3075 0.10000E+01 0.0000 78 FeOH+ 0.16837E-07 -7.7737 0.32165E-08 -8.4926 0.19103E+00 -0.7189 79 HFeO2- 0.50856E-08 -8.2937 0.87533E-09 -9.0578 0.17212E+00 -0.7642 82 FeO2- 0.32276E-08 -8.4911 0.55553E-09 -9.2553 0.17212E+00 -0.7642 83 HFeO2,aq 0.26547E-09 -9.5760 0.26547E-09 -9.5760 0.10000E+01 0.0000 84 H2,aq 0.42615E-02 -2.3704 0.50370E-02 -2.2978 0.11820E+01 0.0726 85 KCl,aq 0.73391E-01 -1.1344 0.73391E-01 -1.1344 0.10000E+01 0.0000 86 KHSO4,aq 0.13773E-01 -1.8610 0.13773E-01 -1.8610 0.10000E+01 0.0000 87 KOH,aq 0.13880E-05 -5.8576 0.13880E-05 -5.8576 0.10000E+01 0.0000 88 KSO4- 0.48686E-02 -2.3126 0.83797E-03 -3.0768 0.17212E+00 -0.7642 90 Mg(HCO3)+ 0.28969E-07 -7.5381 0.55340E-08 -8.2570 0.19103E+00 -0.7189 91 MgCl+ 0.15234E-04 -4.8172 0.29103E-05 -5.5361 0.19103E+00 -0.7189 92 MgOH+ 0.56244E-06 -6.2499 0.10745E-06 -6.9688 0.19103E+00 -0.7189 94 MnO,aq 0.96921E-07 -7.0136 0.96921E-07 -7.0136 0.10000E+01 0.0000 95 MnOH+ 0.20749E-06 -6.6830 0.39637E-07 -7.4019 0.19103E+00 -0.7189 97 HMnO2- 0.38944E-10 -10.4096 0.67029E-11 -11.1737 0.17212E+00 -0.7642 100 MnCl+ 0.11554E-02 -2.9373 0.22072E-03 -3.6562 0.19103E+00 -0.7189 101 MnSO4,aq 0.19710E-06 -6.7053 0.19710E-06 -6.7053 0.10000E+01 0.0000 102 NaCl,aq 0.45336E+00 -0.3436 0.45336E+00 -0.3436 0.10000E+01 0.0000 103 NaOH,aq 0.18221E-05 -5.7394 0.18221E-05 -5.7394 0.10000E+01 0.0000 105 OH- 0.67425E-05 -5.1712 0.10226E-05 -5.9903 0.15167E+00 -0.8191 111 H3PO3,aq 0.12375E-09 -9.9075 0.12375E-09 -9.9075 0.10000E+01 0.0000 112 H2PO3- 0.17082E-08 -8.7675 0.29400E-09 -9.5316 0.17212E+00 -0.7642 113 H3PO4,aq 0.16317E-05 -5.7874 0.16317E-05 -5.7874 0.10000E+01 0.0000 114 H2PO4- 0.14610E-05 -5.8353 0.26399E-06 -6.5784 0.18069E+00 -0.7431 116 H4P2O7,aq 0.24583E-09 -9.6094 0.24583E-09 -9.6094 0.10000E+01 0.0000 117 H3P2O7- 0.10289E-08 -8.9876 0.17709E-09 -9.7518 0.17212E+00 -0.7642 118 H2P2O7-2 0.23355E-06 -6.6316 0.44863E-09 -9.3481 0.19209E-02 -2.7165 119 HP2O7-3 0.27558E-07 -7.5598 0.17577E-13 -13.7550 0.63784E-06 -6.1953 121 PbCl+ 0.10730E-05 -5.9694 0.20498E-06 -6.6883 0.19103E+00 -0.7189 122 PbCl2,aq 0.82091E-04 -4.0857 0.82091E-04 -4.0857 0.10000E+01 0.0000 123 PbCl3- 0.90352E-04 -4.0441 0.15551E-04 -4.8082 0.17212E+00 -0.7642 124 PbCl4-2 0.14374E-04 -4.8424 0.27612E-07 -7.5589 0.19209E-02 -2.7165 125 PbO,aq 0.63720E-08 -8.1957 0.63720E-08 -8.1957 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.12088E-03 -3.9176 0.12088E-03 -3.9176 0.10000E+01 0.0000 128 Pb(HS)3- 0.12923E-04 -4.8886 0.22242E-05 -5.6528 0.17212E+00 -0.7642 129 H2S,aq 0.10593E+01 0.0250 0.12520E+01 0.0976 0.11820E+01 0.0726 130 S2-2 0.11129E-07 -7.9536 0.21377E-10 -10.6700 0.19209E-02 -2.7165 131 S3-2 0.10532E-08 -8.9775 0.20232E-11 -11.6940 0.19209E-02 -2.7165 132 S3- 0.87182E-02 -2.0596 0.15006E-02 -2.8237 0.17212E+00 -0.7642 133 S4-2 0.84913E-10 -10.0710 0.16311E-12 -12.7875 0.19209E-02 -2.7165 135 SO2,aq 0.29370E+00 -0.5321 0.29370E+00 -0.5321 0.10000E+01 0.0000 136 SO3-2 0.62225E-09 -9.2060 0.18921E-11 -11.7231 0.30407E-02 -2.5170 137 HSO3- 0.22178E-03 -3.6541 0.38173E-04 -4.4182 0.17212E+00 -0.7642 138 HSO4- 0.78182E-02 -2.1069 0.15345E-02 -2.8140 0.19628E+00 -0.7071 140 S2O3-2 0.49976E-06 -6.3012 0.95999E-09 -9.0177 0.19209E-02 -2.7165 141 HS2O3- 0.34714E-06 -6.4595 0.59748E-07 -7.2237 0.17212E+00 -0.7642 142 H2S2O3,aq 0.38140E-07 -7.4186 0.38140E-07 -7.4186 0.10000E+01 0.0000 150 S4O6-2 0.43524E-09 -9.3613 0.83605E-12 -12.0778 0.19209E-02 -2.7165 152 ZnCl+ 0.12249E-03 -3.9119 0.23400E-04 -4.6308 0.19103E+00 -0.7189 153 ZnCl2,aq 0.54802E-03 -3.2612 0.54802E-03 -3.2612 0.10000E+01 0.0000 154 ZnCl3- 0.34361E-04 -4.4639 0.59141E-05 -5.2281 0.17212E+00 -0.7642 155 ZnO,aq 0.25360E-07 -7.5958 0.25360E-07 -7.5958 0.10000E+01 0.0000 156 ZnOH+ 0.85551E-06 -6.0678 0.16343E-06 -6.7867 0.19103E+00 -0.7189 158 HZnO2- 0.17112E-09 -9.7667 0.29452E-10 -10.5309 0.17212E+00 -0.7642 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4392467E-05 0.4294547E+01 0.3543067E+04 0.0000 2 H2O 0.1000000E+01 0.5252283E+02 0.7744921E+06 0.0000 3 Cl- 0.1174258E+00 0.6559003E+00 0.1903348E+05 4.3568 4 SO4-- 0.2458698E-03 0.2514199E+00 0.1976864E+05 5.8098 5 HCO3- 0.8200223E-05 0.2674214E+01 0.1335598E+06 0.2323 6 HS- 0.1093980E-03 0.1155049E+01 0.3126713E+05 1.3295 7 H4SiO4 0.4507385E-01 0.4507698E-01 0.3546297E+04 -1.3461 8 Al+++ 0.2849755E-16 0.1023543E-04 0.2260473E+00 -4.5322 9 Ca++ 0.1147982E-05 0.1332870E-03 0.4372412E+01 3.3836 10 Mg++ 0.1554212E-05 0.1738137E-04 0.3458852E+00 3.4317 11 Fe++ 0.1200141E-07 0.2349773E-02 0.1074121E+03 1.3406 12 K+ 0.3354098E-01 0.1255757E+00 0.4019130E+04 3.8541 13 Na+ 0.1050152E+00 0.5583788E+00 0.1050731E+05 4.3128 14 Mn++ 0.1311478E-05 0.1157226E-02 0.5203774E+02 3.3945 15 Zn++ 0.3178213E-09 0.7057529E-03 0.3776230E+02 -0.2365 16 Cu+ 0.1158429E-07 0.8766230E-04 0.4559187E+01 -2.6457 17 Pb++ 0.2489607E-08 0.3217070E-03 0.5455777E+02 0.7685 18 Ag+ 0.2952312E-09 0.8760137E-05 0.7734618E+00 -4.2080 19 Ba++ 0.5521511E-07 0.6841153E-05 0.7690483E+00 2.1453 20 HPO4-- 0.1502334E-08 0.3620822E-05 0.2844531E+00 0.5980 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265478E+01 -.3115933E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5216732E+02 -.2025440E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2497181E+00 0.2004706E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1147230E+01 0.1291377E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4477187E-01 0.9882245E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1016615E-04 0.6843734E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1323848E-03 0.3955251E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1726372E-04 0.3412934E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2333868E-02 0.6432886E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247258E+00 0.6843734E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149393E-02 0.1065982E-06 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7009758E-03 0.1598359E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.8706894E-04 0.3125408E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3195294E-03 0.2064320E-04 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.6794847E-05 0.4857761E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3596313E-05 0.4971187E-05 0.0000000E+00 Chg. balance for solid moles: -.1103E-17 Mass of aqueous solution: 0.121345E+04 g Temperature = 555.00 C Pressure = 1000.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3872E-03 -3.412 0.5272E-01 -1.278 0.7508 0.1779E-01 annite 0.3530E-06 -6.452 0.1807E-03 -3.743 0.2574E-02 0.5448E-04 phlogopite 0.1138E-05 -5.944 0.4747E-03 -3.324 0.6761E-02 0.1702E-03 biotite-Mn 0.3553E-07 -7.449 0.1809E-04 -4.743 0.2577E-03 0.5423E-05 apatite-OH 0.1657E-05 -5.781 0.8324E-03 -3.080 0.1185E-01 0.2645E-03 microcline 0.6828E-03 -3.166 0.1901 -0.721 2.707 0.7424E-01 pyrite 0.6119E-02 -2.213 0.7342 -0.134 10.46 0.1465 quartz 0.9677E-01 -1.014 5.814 0.764 82.80 2.196 barite 0.4858E-04 -4.314 0.1134E-01 -1.945 0.1615 0.2531E-02 chalcopyrite 0.3125E-03 -3.505 0.5735E-01 -1.241 0.8168 0.1339E-01 galena 0.2064E-04 -4.685 0.4939E-02 -2.306 0.7034E-01 0.6500E-03 sphalerite 0.1598E-02 -2.796 0.1557 -0.808 2.218 0.3808E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2313E+00 0.2313E+00 1.0000 -0.636 phlogopite 0.7454E+00 0.7454E+00 1.0000 -0.128 biotite-Mn 0.2328E-01 0.2328E-01 1.0000 -1.633 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.021738 g Volume = 2.489252 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.01 -15.01 0.00 0.000 0.00000E+00 24 annite 1.21 1.21 0.00 0.000 -0.27767E-10 25 phlogopite 5.96 5.96 0.00 0.000 -0.10097E-10 26 biotite-Mn 10.37 10.37 0.00 0.000 0.13463E-10 30 apatite-OH -53.90 -53.90 0.00 0.000 0.26926E-10 115 microcline -4.71 -4.71 0.00 0.000 0.33657E-10 140 pyrite -22.11 -22.11 0.00 0.000 0.13463E-10 144 quartz -1.34 -1.34 0.00 0.000 0.00000E+00 237 barite -16.25 -16.25 0.00 0.000 0.00000E+00 240 chalcopyrite -23.80 -23.80 0.00 0.000 0.00000E+00 245 galena -10.00 -10.00 0.00 0.000 0.67315E-11 255 sphalerite -11.01 -11.01 0.00 0.000 -0.67315E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 0.00 -0.26 -0.259 0.98280E+03 2.741 2 CO2,gas -10.17 -11.87 -1.70 -0.567 0.64503E+04 1.298 3 CH4,gas 6.82 -4.25 -11.07 -2.768 0.41955E+05 -8.071 4 H2,gas 5.99 1.90 -4.09 -2.336 0.15490E+05 -1.088 5 H2S,gas -8.47 -10.77 -2.30 -1.151 0.87243E+04 0.698 6 CO,gas -3.89 -9.96 -6.07 -1.869 0.23019E+05 -3.075 7 SO3,gas -7.68 -18.39 -10.71 -2.679 0.40603E+05 -7.715 8 O2,gas 17.00 -3.81 -20.81 -13.875 0.78867E+05 -17.812 9 HCl,gas -6.18 -7.75 -1.57 -0.784 0.59428E+04 -1.568 10 acmite 3.60 2.01 -1.59 -0.165 0.60255E+04 12 akimotoite 6.31 2.09 -4.23 -0.845 0.16016E+05 13 akimotoite-Fe 4.16 0.00 -4.16 -0.833 0.15779E+05 14 albite-high -4.09 -4.25 -0.16 -0.012 0.60424E+03 15 albite -4.10 -4.25 -0.16 -0.012 0.59477E+03 16 almandine -6.83 -9.08 -2.25 -0.113 0.85369E+04 17 pyrope 0.00 -2.81 -2.81 -0.140 0.10639E+05 18 analcite -1.91 -2.91 -1.00 -0.111 0.38025E+04 19 andalusite -9.78 -10.41 -0.64 -0.064 0.24083E+04 27 anorthite -7.43 -8.37 -0.94 -0.073 0.35798E+04 28 anthophyllite 15.29 13.26 -2.03 -0.055 0.76853E+04 29 anthophyllite-Fe 2.27 -1.37 -3.64 -0.098 0.13803E+05 31 apatite-OH-zs -51.70 -53.90 -2.21 -0.170 0.83672E+04 32 apatite-Cl-zs -58.37 -61.65 -3.28 -0.273 0.12416E+05 33 aragonite -4.73 -8.49 -3.75 -1.251 0.14226E+05 34 brucite 5.67 3.43 -2.24 -0.448 0.84907E+04 35 calcite -4.84 -8.49 -3.65 -1.215 0.13817E+05 36 carnegieite-low 0.25 -1.57 -1.81 -0.259 0.68754E+04 37 carnegieite-high 0.34 -1.57 -1.90 -0.272 0.72046E+04 38 carpholite-Mg -6.23 -8.33 -2.09 -0.140 0.79369E+04 39 carpholite-Fe -7.63 -10.42 -2.79 -0.186 0.10568E+05 40 celadonite -0.54 -2.63 -2.08 -0.123 0.78962E+04 41 celadonite-Fe -1.98 -4.72 -2.73 -0.161 0.10358E+05 42 chrysotile 9.91 7.60 -2.31 -0.192 0.87425E+04 44 clinochlore 5.34 4.05 -1.30 -0.040 0.49103E+04 45 daphnite -1.94 -6.41 -4.47 -0.140 0.16948E+05 47 chlorite-Al-free 19.98 15.20 -4.78 -0.199 0.18113E+05 48 chloritoid-Mg -5.57 -6.98 -1.42 -0.095 0.53720E+04 49 chloritoid-Fe -7.57 -9.07 -1.51 -0.100 0.57052E+04 50 chloritoid-Mn -5.43 -7.02 -1.59 -0.106 0.60412E+04 52 coesite -1.05 -1.34 -0.30 -0.099 0.11222E+04 53 cordierite-H -16.91 -17.99 -1.08 -0.039 0.40988E+04 54 cordierite-Fe -19.60 -22.18 -2.57 -0.089 0.97575E+04 55 cordierite-Mn -15.25 -18.07 -2.82 -0.097 0.10691E+05 56 corundum -8.25 -9.07 -0.82 -0.074 0.30909E+04 58 cristobalite -1.30 -1.34 -0.05 -0.016 0.18189E+03 59 cummingtonite 15.36 13.26 -2.10 -0.057 0.79506E+04 61 cymrite-K -2.36 -4.71 -2.35 -0.196 0.88995E+04 63 diaspore -3.64 -4.53 -0.90 -0.149 0.33982E+04 65 diopside 5.57 4.13 -1.44 -0.144 0.54592E+04 66 hedenbergite 4.10 2.03 -2.07 -0.207 0.78312E+04 68 eastonite -4.19 -5.58 -1.39 -0.053 0.52574E+04 69 enstatite 5.00 4.17 -0.83 -0.083 0.31381E+04 70 clinoenstatite-HiP 5.51 4.17 -1.33 -0.133 0.50480E+04 71 clinoenstatite 4.98 4.17 -0.81 -0.081 0.30699E+04 72 protoenstatite 5.14 4.17 -0.96 -0.096 0.36521E+04 73 epidote -3.29 -5.95 -2.66 -0.129 0.10085E+05 74 clinozoisite -7.80 -10.87 -3.07 -0.139 0.11624E+05 75 epidote-Fe 2.93 -1.03 -3.96 -0.206 0.15001E+05 76 fayalite 2.56 1.34 -1.23 -0.176 0.46567E+04 77 ferrosilite 1.32 -0.01 -1.33 -0.133 0.50394E+04 78 forsterite 6.66 5.52 -1.15 -0.164 0.43470E+04 79 gedrite -6.81 -9.05 -2.24 -0.060 0.84789E+04 81 gibbsite -2.00 -4.54 -2.53 -0.362 0.95953E+04 82 glaucophane 2.11 -0.90 -3.01 -0.081 0.11412E+05 84 goethite 1.32 0.39 -0.93 -0.202 0.35355E+04 86 greenalite 4.89 1.33 -3.56 -0.296 0.13481E+05 87 grunerite 2.84 -1.37 -4.21 -0.114 0.15967E+05 88 halite -1.40 -3.43 -2.03 -1.017 0.77047E+04 89 hematite 1.09 0.77 -0.32 -0.038 0.11960E+04 90 heulandite -11.75 -15.10 -3.35 -0.152 0.12680E+05 91 hercynite -6.32 -7.73 -1.41 -0.094 0.53264E+04 94 jadeite -1.22 -2.91 -1.69 -0.169 0.63912E+04 96 kalsilite -0.38 -2.02 -1.65 -0.236 0.62484E+04 97 kaolinite -8.93 -11.76 -2.83 -0.257 0.10730E+05 98 kyanite -9.61 -10.41 -0.80 -0.080 0.30374E+04 100 laumontite -7.25 -11.07 -3.82 -0.255 0.14471E+05 101 lawsonite -4.67 -8.38 -3.71 -0.247 0.14061E+05 102 leucite -2.38 -3.37 -0.98 -0.098 0.37303E+04 104 lizardite 10.07 7.60 -2.47 -0.206 0.93569E+04 105 magnesite -5.52 -8.44 -2.92 -0.974 0.11069E+05 106 magnetite 2.49 2.11 -0.38 -0.031 0.14307E+04 107 minnesotaite 0.94 -1.36 -2.30 -0.135 0.87124E+04 108 minnesotaite-Mg 7.07 4.92 -2.16 -0.127 0.81666E+04 109 magnesioferrite 5.63 4.20 -1.43 -0.116 0.54080E+04 111 manganosite 5.59 3.39 -2.20 -0.550 0.83400E+04 112 margarite -15.24 -17.44 -2.21 -0.088 0.83640E+04 116 monticellite 9.10 5.47 -3.63 -0.518 0.13742E+05 118 mullite-Si -9.01 -10.41 -1.40 -0.140 0.53172E+04 119 muscovite -12.84 -13.78 -0.94 -0.055 0.35531E+04 120 paragonite -12.16 -13.32 -1.17 -0.069 0.44164E+04 121 nepheline -0.06 -1.57 -1.51 -0.216 0.57234E+04 122 osumilite(2) -12.18 -14.24 -2.06 -0.043 0.77912E+04 123 osumilite-Fe -26.58 -29.57 -2.99 -0.062 0.11344E+05 124 pargasite 7.38 3.13 -4.25 -0.112 0.16097E+05 125 periclase 5.88 3.43 -2.45 -0.613 0.92937E+04 126 periclase-Fe 3.25 1.34 -1.91 -0.477 0.72338E+04 127 perovskite-Al -6.49 -9.07 -2.57 -0.234 0.97537E+04 132 phlogopite-Na 6.84 6.04 -0.80 -0.045 0.30492E+04 134 prehnite -2.69 -6.34 -3.64 -0.214 0.13801E+05 135 prehnite-Fe 2.22 -1.41 -3.63 -0.219 0.13767E+05 138 px-Mg-tschermaks -4.92 -6.98 -2.07 -0.148 0.78263E+04 139 px-Ca-tschermaks -4.17 -7.03 -2.86 -0.204 0.10842E+05 141 pyrrhotite -8.70 -9.43 -0.73 -0.243 0.27623E+04 142 pyrrhotiteFe0.875 -9.51 -9.84 -0.33 -0.121 0.12501E+04 143 pyrophyllite -12.95 -14.44 -1.50 -0.094 0.56771E+04 146 riebeckite 5.86 2.67 -3.19 -0.088 0.12100E+05 147 ringwoodite-Fe 3.57 1.34 -2.23 -0.319 0.84632E+04 148 ringwoodite-Mg 9.86 5.52 -4.34 -0.620 0.16460E+05 149 rhodochrosite -5.54 -8.48 -2.93 -0.978 0.11118E+05 150 rhodonite 2.60 2.05 -0.55 -0.111 0.21016E+04 151 sanidine -4.17 -4.71 -0.55 -0.042 0.20676E+04 153 siderite -7.41 -10.53 -3.12 -1.041 0.11830E+05 154 sillimanite -9.74 -10.41 -0.68 -0.068 0.25599E+04 156 spinel -4.10 -5.64 -1.54 -0.102 0.58231E+04 163 stilpnomelane-Mg 1.29 -0.75 -2.04 -0.061 0.77294E+04 164 stishovite 1.65 -1.34 -2.99 -0.998 0.11349E+05 165 sudoite-Fe -14.75 -19.49 -4.75 -0.153 0.17989E+05 166 sudoite -12.45 -15.31 -2.86 -0.092 0.10844E+05 167 sulfur -11.20 -12.68 -1.48 -0.455 0.56086E+04 168 sylvite -1.30 -3.89 -2.59 -1.294 0.98066E+04 169 talc 5.32 4.92 -0.41 -0.024 0.15379E+04 170 talc-Fe 2.37 -1.36 -3.73 -0.219 0.14121E+05 171 talc-tschermaks -4.52 -6.24 -1.72 -0.101 0.65188E+04 173 tephroite 6.82 5.44 -1.37 -0.196 0.52088E+04 176 topaz-H -7.68 -10.41 -2.73 -0.248 0.10349E+05 177 tremolite 15.81 13.17 -2.64 -0.071 0.10002E+05 179 troilite-low -8.61 -9.43 -0.82 -0.273 0.31010E+04 180 tschermakite -5.51 -9.14 -3.63 -0.098 0.13761E+05 183 wadsleyite-Fe 3.42 1.34 -2.09 -0.299 0.79199E+04 184 wadsleyite-Mg 8.91 5.52 -3.39 -0.485 0.12854E+05 185 wairakite -9.13 -11.06 -1.94 -0.114 0.73340E+04 186 walstromite 4.68 2.04 -2.64 -0.528 0.99972E+04 187 wollastonite 4.25 2.04 -2.21 -0.442 0.83677E+04 188 pseudo-wollastonite 4.37 2.04 -2.33 -0.466 0.88234E+04 189 zoisite -7.85 -10.87 -3.02 -0.137 0.11437E+05 191 argentite -14.27 -19.19 -4.92 -1.229 0.18632E+05 192 beidellite-Ca -13.06 -14.94 -1.88 -0.116 0.71054E+04 193 beidellite-H -13.10 -15.50 -2.39 -0.153 0.90642E+04 194 beidellite-K -12.06 -14.22 -2.16 -0.132 0.81951E+04 195 beidellite-Mg -13.31 -14.93 -1.62 -0.100 0.61464E+04 196 beidellite-Na -12.00 -14.07 -2.07 -0.127 0.78389E+04 197 bornite -55.67 -55.93 -0.26 -0.019 0.97285E+03 199 chalcocite -14.62 -16.06 -1.45 -0.362 0.54907E+04 200 covellite -13.03 -14.37 -1.34 -0.511 0.50805E+04 202 montmorillonite-Ca -9.87 -11.26 -1.39 -0.086 0.52636E+04 203 montmorillonite-K -9.14 -10.54 -1.40 -0.086 0.53017E+04 204 montmorillonite-Mg -10.08 -11.25 -1.17 -0.073 0.44438E+04 205 montmorillonite-Na -8.81 -10.39 -1.58 -0.097 0.59796E+04 206 nontronite-Ca -3.45 -5.10 -1.64 -0.107 0.62242E+04 207 nontronite-H -3.50 -5.66 -2.15 -0.144 0.81551E+04 208 nontronite-K -2.46 -4.38 -1.93 -0.124 0.73063E+04 209 nontronite-Mg -3.67 -5.09 -1.42 -0.092 0.53888E+04 210 nontronite-Na -2.39 -4.23 -1.84 -0.118 0.69620E+04 215 gypsum -12.75 -15.01 -2.27 -0.566 0.85868E+04 231 acanthite -14.36 -19.19 -4.83 -1.208 0.18317E+05 232 alabandite -6.43 -7.38 -0.95 -0.316 0.35962E+04 234 anglesite -15.33 -17.63 -2.30 -1.150 0.87194E+04 238 boehmite -3.34 -4.53 -1.20 -0.200 0.45388E+04 242 copper,native 1.70 -1.69 -3.39 -1.180 0.12860E+05 244 ferrous-oxide 2.31 1.34 -0.97 -0.243 0.36869E+04 246 silver,native 0.40 -3.26 -3.66 -1.273 0.13872E+05 248 litharge 5.40 0.77 -4.63 -1.157 0.17538E+05 256 wurtzite -10.19 -11.01 -0.82 -0.272 0.30908E+04 257 zincite 2.38 -0.24 -2.62 -0.656 0.99373E+04 258 an20ab80 -4.98 -5.08 -0.10 -0.007 0.36746E+03 259 an25ab75 -5.17 -5.28 -0.11 -0.008 0.41591E+03 260 an30ab70 -5.36 -5.49 -0.13 -0.010 0.48615E+03 261 tr.625ac.25prg.125 10.52 9.30 -1.22 -0.033 0.46178E+04 Calculations done for 555.0000 Deg. C; 1000.0000 bar Temperature changed by -1.000 degrees to 554.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 40 Loop limit = 500 Temperature = 554.00 C Pressure = 989.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5513E+02 kg liquid = 0.9933E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9969 Stoichiometric ionic strength = .3272665E+01 Osmotic coef. = 0.0000 True ionic strength = .1434667E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.45251E-05 -5.3444 0.87561E-06 -6.0577 0.19350E+00 -0.7133 2 H2O 0.99690E+00 -0.0013 0.99690E+00 -0.0013 3 Cl- 0.12035E+00 -0.9195 0.19678E-01 -1.7060 0.16350E+00 -0.7865 4 SO4-- 0.28314E-03 -3.5480 0.48907E-06 -6.3106 0.17273E-02 -2.7626 5 HCO3- 0.81833E-05 -5.0871 0.14419E-05 -5.8411 0.17620E+00 -0.7540 6 HS- 0.11175E-03 -3.9517 0.18423E-04 -4.7346 0.16486E+00 -0.7829 7 H4SiO4 0.44270E-01 -1.3539 0.44270E-01 -1.3539 0.10000E+01 0.0000 8 Al+++ 0.47501E-16 -16.3233 0.22493E-22 -22.6480 0.47352E-06 -6.3247 9 Ca++ 0.13760E-05 -5.8614 0.18929E-08 -8.7229 0.13757E-02 -2.8615 10 Mg++ 0.19566E-05 -5.7085 0.22066E-08 -8.6563 0.11278E-02 -2.9478 11 Fe++ 0.14609E-07 -7.8354 0.17325E-10 -10.7613 0.11859E-02 -2.9260 12 K+ 0.34211E-01 -1.4658 0.61746E-02 -2.2094 0.18049E+00 -0.7436 13 Na+ 0.10756E+00 -0.9684 0.17775E-01 -1.7502 0.16526E+00 -0.7818 14 Mn++ 0.15533E-05 -5.8087 0.19111E-08 -8.7187 0.12303E-02 -2.9100 15 Zn++ 0.38863E-09 -9.4105 0.46088E-12 -12.3364 0.11859E-02 -2.9260 16 Cu+ 0.11877E-07 -7.9253 0.19575E-08 -8.7083 0.16482E+00 -0.7830 17 Pb++ 0.29339E-08 -8.5326 0.45328E-11 -11.3436 0.15450E-02 -2.8111 18 Ag+ 0.27310E-09 -9.5637 0.48508E-10 -10.3142 0.17762E+00 -0.7505 19 Ba++ 0.64561E-07 -7.1900 0.10737E-09 -9.9691 0.16630E-02 -2.7791 20 HPO4-- 0.17521E-08 -8.7564 0.30421E-11 -11.5168 0.17362E-02 -2.7604 21 HSiO3- 0.12615E-05 -5.8991 0.20626E-06 -6.6856 0.16350E+00 -0.7865 22 Ca(HSiO3)+ 0.38984E-08 -8.4091 0.70995E-09 -9.1488 0.18211E+00 -0.7397 23 Mg(HSiO3)+ 0.15078E-08 -8.8217 0.27458E-09 -9.5613 0.18211E+00 -0.7397 24 NaHSiO3,aq 0.18692E-05 -5.7284 0.18692E-05 -5.7284 0.10000E+01 0.0000 28 AgCl,aq 0.11526E-06 -6.9383 0.11526E-06 -6.9383 0.10000E+01 0.0000 29 AgCl2- 0.49908E-05 -5.3018 0.81600E-06 -6.0883 0.16350E+00 -0.7865 30 AgCl3-2 0.17083E-05 -5.7674 0.27264E-08 -8.5644 0.15959E-02 -2.7970 31 AgCl4-3 0.19363E-05 -5.7130 0.80544E-12 -12.0940 0.41596E-06 -6.3809 34 Ag(HS),aq 0.20930E-08 -8.6792 0.20930E-08 -8.6792 0.10000E+01 0.0000 35 Ag(HS)2- 0.67262E-08 -8.1722 0.10997E-08 -8.9587 0.16350E+00 -0.7865 36 AlO+ 0.11834E-10 -10.9269 0.21551E-11 -11.6665 0.18211E+00 -0.7397 38 HAlO2,aq 0.43383E-08 -8.3627 0.43383E-08 -8.3627 0.10000E+01 0.0000 39 AlO2- 0.10613E-04 -4.9741 0.15226E-05 -5.8174 0.14346E+00 -0.8433 41 Ba(HCO3)+ 0.16539E-06 -6.7815 0.31369E-07 -7.5035 0.18966E+00 -0.7220 42 BaCl+ 0.67417E-05 -5.1712 0.12277E-05 -5.9109 0.18211E+00 -0.7397 43 CH4,aq 0.13599E-08 -8.8665 0.16064E-08 -8.7941 0.11812E+01 0.0723 48 CO,aq 0.45288E-03 -3.3440 0.45288E-03 -3.3440 0.10000E+01 0.0000 49 CO2,aq 0.26737E+01 0.4271 0.31582E+01 0.4994 0.11812E+01 0.0723 50 CO3-2 0.39315E-10 -10.4054 0.62743E-13 -13.2024 0.15959E-02 -2.7970 52 Ca(HCO3)+ 0.78233E-07 -7.1066 0.14247E-07 -7.8463 0.18211E+00 -0.7397 53 CaCl+ 0.64361E-04 -4.1914 0.11721E-04 -4.9310 0.18211E+00 -0.7397 54 CaCl2,aq 0.69282E-04 -4.1594 0.69282E-04 -4.1594 0.10000E+01 0.0000 55 CaOH+ 0.11903E-06 -6.9243 0.21677E-07 -7.6640 0.18211E+00 -0.7397 56 CaSO4,aq 0.18263E-06 -6.7384 0.18263E-06 -6.7384 0.10000E+01 0.0000 57 HCl,aq 0.38214E-02 -2.4178 0.38214E-02 -2.4178 0.10000E+01 0.0000 66 CuCl,aq 0.20415E-04 -4.6901 0.20415E-04 -4.6901 0.10000E+01 0.0000 67 CuCl2- 0.67979E-04 -4.1676 0.11115E-04 -4.9541 0.16350E+00 -0.7865 68 CuCl3-2 0.12912E-05 -5.8890 0.20607E-08 -8.6860 0.15959E-02 -2.7970 74 FeCl+ 0.21239E-06 -6.6729 0.38678E-07 -7.4125 0.18211E+00 -0.7397 75 FeCl2,aq 0.23028E-02 -2.6378 0.23028E-02 -2.6378 0.10000E+01 0.0000 77 FeO,aq 0.48265E-07 -7.3164 0.48265E-07 -7.3164 0.10000E+01 0.0000 78 FeOH+ 0.17410E-07 -7.7592 0.31705E-08 -8.4989 0.18211E+00 -0.7397 79 HFeO2- 0.51107E-08 -8.2915 0.83561E-09 -9.0780 0.16350E+00 -0.7865 82 FeO2- 0.32231E-08 -8.4917 0.52698E-09 -9.2782 0.16350E+00 -0.7865 83 HFeO2,aq 0.26495E-09 -9.5768 0.26495E-09 -9.5768 0.10000E+01 0.0000 84 H2,aq 0.42403E-02 -2.3726 0.50088E-02 -2.3003 0.11812E+01 0.0723 85 KCl,aq 0.72904E-01 -1.1372 0.72904E-01 -1.1372 0.10000E+01 0.0000 86 KHSO4,aq 0.13515E-01 -1.8692 0.13515E-01 -1.8692 0.10000E+01 0.0000 87 KOH,aq 0.13694E-05 -5.8635 0.13694E-05 -5.8635 0.10000E+01 0.0000 88 KSO4- 0.49406E-02 -2.3062 0.80779E-03 -3.0927 0.16350E+00 -0.7865 90 Mg(HCO3)+ 0.30057E-07 -7.5221 0.54737E-08 -8.2617 0.18211E+00 -0.7397 91 MgCl+ 0.16474E-04 -4.7832 0.30000E-05 -5.5229 0.18211E+00 -0.7397 92 MgOH+ 0.60160E-06 -6.2207 0.10956E-06 -6.9604 0.18211E+00 -0.7397 94 MnO,aq 0.92983E-07 -7.0316 0.92983E-07 -7.0316 0.10000E+01 0.0000 95 MnOH+ 0.20781E-06 -6.6823 0.37844E-07 -7.4220 0.18211E+00 -0.7397 97 HMnO2- 0.38060E-10 -10.4195 0.62228E-11 -11.2060 0.16350E+00 -0.7865 100 MnCl+ 0.11552E-02 -2.9373 0.21037E-03 -3.6770 0.18211E+00 -0.7397 101 MnSO4,aq 0.19516E-06 -6.7096 0.19516E-06 -6.7096 0.10000E+01 0.0000 102 NaCl,aq 0.45080E+00 -0.3460 0.45080E+00 -0.3460 0.10000E+01 0.0000 103 NaOH,aq 0.17981E-05 -5.7452 0.17981E-05 -5.7452 0.10000E+01 0.0000 105 OH- 0.69309E-05 -5.1592 0.99434E-06 -6.0025 0.14346E+00 -0.8433 110 HPO3-2 0.10212E-10 -10.9909 0.16297E-13 -13.7879 0.15959E-02 -2.7970 111 H3PO3,aq 0.12513E-09 -9.9026 0.12513E-09 -9.9026 0.10000E+01 0.0000 112 H2PO3- 0.17164E-08 -8.7654 0.28064E-09 -9.5519 0.16350E+00 -0.7865 113 H3PO4,aq 0.16803E-05 -5.7746 0.16803E-05 -5.7746 0.10000E+01 0.0000 114 H2PO4- 0.15064E-05 -5.8221 0.25899E-06 -6.5867 0.17193E+00 -0.7647 116 H4P2O7,aq 0.26162E-09 -9.5823 0.26162E-09 -9.5823 0.10000E+01 0.0000 117 H3P2O7- 0.10725E-08 -8.9696 0.17535E-09 -9.7561 0.16350E+00 -0.7865 118 H2P2O7-2 0.26664E-06 -6.5741 0.42554E-09 -9.3711 0.15959E-02 -2.7970 119 HP2O7-3 0.39511E-07 -7.4033 0.16435E-13 -13.7842 0.41596E-06 -6.3809 121 PbCl+ 0.10986E-05 -5.9591 0.20007E-06 -6.6988 0.18211E+00 -0.7397 122 PbCl2,aq 0.82038E-04 -4.0860 0.82038E-04 -4.0860 0.10000E+01 0.0000 123 PbCl3- 0.93176E-04 -4.0307 0.15234E-04 -4.8172 0.16350E+00 -0.7865 124 PbCl4-2 0.16277E-04 -4.7884 0.25977E-07 -7.5854 0.15959E-02 -2.7970 125 PbO,aq 0.63180E-08 -8.1994 0.63180E-08 -8.1994 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11905E-03 -3.9243 0.11905E-03 -3.9243 0.10000E+01 0.0000 128 Pb(HS)3- 0.13077E-04 -4.8835 0.21381E-05 -5.6700 0.16350E+00 -0.7865 129 H2S,aq 0.10591E+01 0.0250 0.12511E+01 0.0973 0.11812E+01 0.0723 130 S2-2 0.12541E-07 -7.9017 0.20015E-10 -10.6986 0.15959E-02 -2.7970 131 S3-2 0.11839E-08 -8.9267 0.18894E-11 -11.7237 0.15959E-02 -2.7970 132 S3- 0.87328E-02 -2.0588 0.14278E-02 -2.8453 0.16350E+00 -0.7865 133 S4-2 0.95294E-10 -10.0209 0.15208E-12 -12.8179 0.15959E-02 -2.7970 135 SO2,aq 0.29370E+00 -0.5321 0.29370E+00 -0.5321 0.10000E+01 0.0000 136 SO3-2 0.70267E-09 -9.1532 0.18036E-11 -11.7439 0.25667E-02 -2.5906 137 HSO3- 0.22399E-03 -3.6498 0.36622E-04 -4.4363 0.16350E+00 -0.7865 138 HSO4- 0.79327E-02 -2.1006 0.14858E-02 -2.8280 0.18730E+00 -0.7275 140 S2O3-2 0.56903E-06 -6.2449 0.90814E-09 -9.0418 0.15959E-02 -2.7970 141 HS2O3- 0.35146E-06 -6.4541 0.57463E-07 -7.2406 0.16350E+00 -0.7865 142 H2S2O3,aq 0.38874E-07 -7.4103 0.38874E-07 -7.4103 0.10000E+01 0.0000 150 S4O6-2 0.49102E-09 -9.3089 0.78363E-12 -12.1059 0.15959E-02 -2.7970 152 ZnCl+ 0.12514E-03 -3.9026 0.22789E-04 -4.6423 0.18211E+00 -0.7397 153 ZnCl2,aq 0.54518E-03 -3.2635 0.54518E-03 -3.2635 0.10000E+01 0.0000 154 ZnCl3- 0.34686E-04 -4.4598 0.56712E-05 -5.2463 0.16350E+00 -0.7865 155 ZnO,aq 0.25021E-07 -7.6017 0.25021E-07 -7.6017 0.10000E+01 0.0000 156 ZnOH+ 0.87300E-06 -6.0590 0.15898E-06 -6.7986 0.18211E+00 -0.7397 158 HZnO2- 0.17324E-09 -9.7614 0.28325E-10 -10.5478 0.16350E+00 -0.7865 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4525062E-05 0.4294390E+01 0.3543200E+04 0.0000 2 H2O 0.1000000E+01 0.5252286E+02 0.7745498E+06 0.0000 3 Cl- 0.1203542E+00 0.6558799E+00 0.1903429E+05 4.3517 4 SO4-- 0.2831404E-03 0.2514020E+00 0.1976869E+05 5.8047 5 HCO3- 0.8183301E-05 0.2674131E+01 0.1335655E+06 0.2166 6 HS- 0.1117513E-03 0.1154934E+01 0.3126633E+05 1.3231 7 H4SiO4 0.4426950E-01 0.4427264E-01 0.3483276E+04 -1.3539 8 Al+++ 0.4750065E-16 0.1061770E-04 0.2345072E+00 -4.4749 9 Ca++ 0.1375994E-05 0.1354023E-03 0.4442132E+01 3.3925 10 Mg++ 0.1956562E-05 0.1906336E-04 0.3793845E+00 3.4591 11 Fe++ 0.1460883E-07 0.2303059E-02 0.1052845E+03 1.3540 12 K+ 0.3421072E-01 0.1255722E+00 0.4019315E+04 3.8483 13 Na+ 0.1075573E+00 0.5583615E+00 0.1050776E+05 4.3075 14 Mn++ 0.1553341E-05 0.1157246E-02 0.5204247E+02 3.3967 15 Zn++ 0.3886310E-09 0.7059051E-03 0.3777325E+02 -0.2210 16 Cu+ 0.1187674E-07 0.8969687E-04 0.4665347E+01 -2.6506 17 Pb++ 0.2933880E-08 0.3247277E-03 0.5507412E+02 0.7717 18 Ag+ 0.2731029E-09 0.8759865E-05 0.7734951E+00 -4.2565 19 Ba++ 0.6456139E-07 0.6971621E-05 0.7837730E+00 2.1463 20 HPO4-- 0.1752125E-08 0.3805273E-05 0.2989658E+00 0.5986 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265455E+01 -.3092479E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5216897E+02 -.2041907E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2497080E+00 0.2014745E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1147152E+01 0.1299233E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4397433E-01 0.9961999E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1054616E-04 0.6839934E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1344899E-03 0.3934200E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.1893491E-04 0.1741738E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2287541E-02 0.6479213E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247261E+00 0.6839934E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149448E-02 0.5174489E-07 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7011488E-03 0.1598186E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.8909251E-04 0.3105172E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3225397E-03 0.1763293E-04 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.6924647E-05 0.4844780E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3779634E-05 0.4787866E-05 0.0000000E+00 Chg. balance for solid moles: 0.1338E-18 Mass of aqueous solution: 0.121340E+04 g Temperature = 554.00 C Pressure = 989.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3854E-03 -3.414 0.5247E-01 -1.280 0.7418 0.1771E-01 annite 0.1760E-06 -6.755 0.9007E-04 -4.045 0.1273E-02 0.2715E-04 phlogopite 0.5806E-06 -6.236 0.2423E-03 -3.616 0.3425E-02 0.8687E-04 biotite-Mn 0.1725E-07 -7.763 0.8782E-05 -5.056 0.1241E-03 0.2633E-05 apatite-OH 0.1596E-05 -5.797 0.8017E-03 -3.096 0.1133E-01 0.2547E-03 microcline 0.6832E-03 -3.165 0.1902 -0.721 2.688 0.7428E-01 pyrite 0.6168E-02 -2.210 0.7401 -0.131 10.46 0.1477 quartz 0.9757E-01 -1.011 5.862 0.768 82.87 2.214 barite 0.4845E-04 -4.315 0.1131E-01 -1.947 0.1599 0.2524E-02 chalcopyrite 0.3105E-03 -3.508 0.5698E-01 -1.244 0.8055 0.1330E-01 galena 0.1763E-04 -4.754 0.4219E-02 -2.375 0.5964E-01 0.5552E-03 sphalerite 0.1598E-02 -2.796 0.1557 -0.808 2.201 0.3808E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.2274E+00 0.2274E+00 1.0000 -0.643 phlogopite 0.7503E+00 0.7503E+00 1.0000 -0.125 biotite-Mn 0.2229E-01 0.2229E-01 1.0000 -1.652 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.073944 g Volume = 2.508186 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.03 -15.03 0.00 0.000 0.00000E+00 24 annite 1.30 1.30 0.00 0.000 -0.75638E-11 25 phlogopite 6.06 6.06 0.00 0.000 0.00000E+00 26 biotite-Mn 10.46 10.46 0.00 0.000 -0.67233E-11 30 apatite-OH -53.94 -53.94 0.00 0.000 0.00000E+00 115 microcline -4.68 -4.68 0.00 0.000 0.13447E-10 140 pyrite -22.14 -22.14 0.00 0.000 0.00000E+00 144 quartz -1.35 -1.35 0.00 0.000 0.00000E+00 237 barite -16.28 -16.28 0.00 0.000 0.00000E+00 240 chalcopyrite -23.83 -23.83 0.00 0.000 -0.26893E-10 245 galena -10.02 -10.02 0.00 0.000 0.00000E+00 255 sphalerite -11.01 -11.01 0.00 0.000 -0.13447E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 0.00 -0.26 -0.259 0.97944E+03 2.736 2 CO2,gas -10.19 -11.90 -1.71 -0.569 0.64628E+04 1.288 3 CH4,gas 6.82 -4.27 -11.08 -2.771 0.41950E+05 -8.088 4 H2,gas 6.00 1.91 -4.09 -2.337 0.15481E+05 -1.095 5 H2S,gas -8.49 -10.79 -2.30 -1.151 0.87158E+04 0.692 6 CO,gas -3.90 -9.99 -6.09 -1.873 0.23034E+05 -3.091 7 SO3,gas -7.70 -18.42 -10.73 -2.682 0.40600E+05 -7.732 8 O2,gas 17.02 -3.82 -20.84 -13.892 0.78873E+05 -17.844 9 HCl,gas -6.19 -7.76 -1.58 -0.788 0.59625E+04 -1.575 10 acmite 3.61 2.00 -1.60 -0.166 0.60638E+04 12 akimotoite 6.34 2.11 -4.23 -0.846 0.16006E+05 13 akimotoite-Fe 4.18 0.00 -4.18 -0.835 0.15806E+05 14 albite-high -4.06 -4.22 -0.16 -0.012 0.61013E+03 15 albite -4.07 -4.22 -0.16 -0.012 0.59651E+03 16 almandine -6.68 -8.95 -2.27 -0.114 0.85950E+04 17 pyrope 0.16 -2.63 -2.80 -0.140 0.10590E+05 18 analcite -1.87 -2.87 -1.01 -0.112 0.38053E+04 19 andalusite -9.68 -10.31 -0.63 -0.063 0.23800E+04 27 anorthite -7.32 -8.27 -0.94 -0.073 0.35754E+04 28 anthophyllite 15.40 13.39 -2.01 -0.054 0.76111E+04 29 anthophyllite-Fe 2.35 -1.34 -3.69 -0.100 0.13977E+05 31 apatite-OH-zs -51.72 -53.94 -2.21 -0.170 0.83694E+04 32 apatite-Cl-zs -58.42 -61.70 -3.28 -0.273 0.12406E+05 33 aragonite -4.74 -8.51 -3.77 -1.255 0.14251E+05 34 brucite 5.70 3.46 -2.24 -0.448 0.84751E+04 35 calcite -4.85 -8.51 -3.66 -1.219 0.13840E+05 36 carnegieite-low 0.30 -1.52 -1.82 -0.260 0.68779E+04 37 carnegieite-high 0.38 -1.52 -1.90 -0.272 0.72101E+04 38 carpholite-Mg -6.12 -8.20 -2.08 -0.139 0.78808E+04 39 carpholite-Fe -7.52 -10.31 -2.79 -0.186 0.10549E+05 40 celadonite -0.50 -2.58 -2.08 -0.122 0.78786E+04 41 celadonite-Fe -1.94 -4.68 -2.74 -0.161 0.10379E+05 42 chrysotile 9.97 7.67 -2.30 -0.191 0.86952E+04 44 clinochlore 5.54 4.28 -1.27 -0.040 0.47947E+04 45 daphnite -1.75 -6.25 -4.50 -0.141 0.17018E+05 47 chlorite-Al-free 20.10 15.34 -4.76 -0.198 0.18014E+05 48 chloritoid-Mg -5.44 -6.85 -1.41 -0.094 0.53241E+04 49 chloritoid-Fe -7.45 -8.95 -1.50 -0.100 0.56898E+04 50 chloritoid-Mn -5.31 -6.91 -1.60 -0.107 0.60652E+04 52 coesite -1.05 -1.35 -0.30 -0.099 0.11219E+04 53 cordierite-H -16.69 -17.75 -1.06 -0.038 0.40262E+04 54 cordierite-Fe -19.38 -21.96 -2.58 -0.089 0.97529E+04 55 cordierite-Mn -15.03 -17.87 -2.84 -0.098 0.10761E+05 56 corundum -8.14 -8.95 -0.81 -0.074 0.30636E+04 58 cristobalite -1.30 -1.35 -0.05 -0.016 0.18146E+03 59 cummingtonite 15.47 13.39 -2.08 -0.056 0.78777E+04 61 cymrite-K -2.33 -4.68 -2.35 -0.196 0.89016E+04 63 diaspore -3.59 -4.48 -0.89 -0.149 0.33783E+04 65 diopside 5.59 4.15 -1.45 -0.145 0.54717E+04 66 hedenbergite 4.12 2.04 -2.08 -0.208 0.78804E+04 68 eastonite -4.00 -5.37 -1.38 -0.053 0.52051E+04 69 enstatite 5.04 4.21 -0.82 -0.082 0.31206E+04 70 clinoenstatite-HiP 5.54 4.21 -1.33 -0.133 0.50307E+04 71 clinoenstatite 5.02 4.21 -0.81 -0.081 0.30515E+04 72 protoenstatite 5.17 4.21 -0.96 -0.096 0.36352E+04 73 epidote -3.15 -5.83 -2.67 -0.130 0.10118E+05 74 clinozoisite -7.63 -10.70 -3.07 -0.140 0.11620E+05 75 epidote-Fe 3.03 -0.95 -3.98 -0.207 0.15067E+05 76 fayalite 2.60 1.35 -1.24 -0.178 0.47109E+04 77 ferrosilite 1.35 0.00 -1.35 -0.135 0.50932E+04 78 forsterite 6.71 5.56 -1.14 -0.163 0.43293E+04 79 gedrite -6.52 -8.73 -2.21 -0.060 0.83693E+04 81 gibbsite -1.95 -4.48 -2.53 -0.361 0.95691E+04 82 glaucophane 2.23 -0.78 -3.00 -0.081 0.11368E+05 84 goethite 1.34 0.40 -0.94 -0.203 0.35537E+04 86 greenalite 4.93 1.35 -3.58 -0.298 0.13542E+05 87 grunerite 2.92 -1.34 -4.27 -0.115 0.16144E+05 88 halite -1.42 -3.46 -2.04 -1.018 0.77077E+04 89 hematite 1.12 0.80 -0.33 -0.040 0.12395E+04 90 heulandite -11.68 -15.03 -3.35 -0.152 0.12661E+05 91 hercynite -6.19 -7.60 -1.41 -0.094 0.53268E+04 94 jadeite -1.18 -2.87 -1.69 -0.169 0.63906E+04 96 kalsilite -0.33 -1.98 -1.65 -0.236 0.62520E+04 97 kaolinite -8.84 -11.66 -2.82 -0.256 0.10674E+05 98 kyanite -9.51 -10.31 -0.79 -0.079 0.30085E+04 100 laumontite -7.16 -10.97 -3.82 -0.254 0.14445E+05 101 lawsonite -4.56 -8.27 -3.71 -0.247 0.14037E+05 102 leucite -2.34 -3.33 -0.99 -0.099 0.37351E+04 104 lizardite 10.13 7.67 -2.46 -0.205 0.93056E+04 105 magnesite -5.52 -8.44 -2.92 -0.974 0.11060E+05 106 magnetite 2.55 2.15 -0.40 -0.032 0.15013E+04 107 minnesotaite 0.97 -1.35 -2.32 -0.136 0.87793E+04 108 minnesotaite-Mg 7.11 4.97 -2.15 -0.126 0.81242E+04 109 magnesioferrite 5.69 4.25 -1.44 -0.117 0.54436E+04 111 manganosite 5.62 3.40 -2.22 -0.555 0.84052E+04 112 margarite -15.02 -17.22 -2.20 -0.088 0.83209E+04 116 monticellite 9.13 5.50 -3.63 -0.519 0.13754E+05 118 mullite-Si -8.91 -10.31 -1.40 -0.140 0.52907E+04 119 muscovite -12.71 -13.64 -0.93 -0.055 0.35187E+04 120 paragonite -12.02 -13.18 -1.16 -0.068 0.43813E+04 121 nepheline -0.01 -1.52 -1.51 -0.216 0.57262E+04 122 osumilite(2) -12.03 -14.07 -2.04 -0.043 0.77393E+04 123 osumilite-Fe -26.35 -29.34 -3.00 -0.062 0.11345E+05 124 pargasite 7.63 3.38 -4.25 -0.112 0.16082E+05 125 periclase 5.91 3.46 -2.45 -0.613 0.92843E+04 126 periclase-Fe 3.27 1.35 -1.92 -0.480 0.72625E+04 127 perovskite-Al -6.38 -8.95 -2.57 -0.234 0.97264E+04 132 phlogopite-Na 6.95 6.15 -0.80 -0.044 0.30158E+04 134 prehnite -2.58 -6.23 -3.65 -0.215 0.13807E+05 135 prehnite-Fe 2.30 -1.35 -3.65 -0.219 0.13809E+05 138 px-Mg-tschermaks -4.79 -6.85 -2.06 -0.147 0.77920E+04 139 px-Ca-tschermaks -4.05 -6.91 -2.86 -0.205 0.10837E+05 141 pyrrhotite -8.70 -9.44 -0.73 -0.245 0.27816E+04 142 pyrrhotiteFe0.875 -9.51 -9.84 -0.33 -0.123 0.12652E+04 143 pyrophyllite -12.87 -14.36 -1.49 -0.093 0.56369E+04 146 riebeckite 5.89 2.66 -3.23 -0.089 0.12243E+05 147 ringwoodite-Fe 3.60 1.35 -2.25 -0.321 0.85154E+04 148 ringwoodite-Mg 9.91 5.56 -4.34 -0.621 0.16440E+05 149 rhodochrosite -5.55 -8.50 -2.95 -0.985 0.11183E+05 150 rhodonite 2.62 2.04 -0.57 -0.114 0.21665E+04 151 sanidine -4.14 -4.68 -0.55 -0.042 0.20678E+04 153 siderite -7.41 -10.54 -3.13 -1.044 0.11856E+05 154 sillimanite -9.64 -10.31 -0.67 -0.067 0.25324E+04 156 spinel -3.97 -5.50 -1.53 -0.102 0.57862E+04 163 stilpnomelane-Mg 1.46 -0.56 -2.02 -0.060 0.76327E+04 164 stishovite 1.65 -1.35 -3.00 -0.999 0.11347E+05 165 sudoite-Fe -14.51 -19.26 -4.75 -0.153 0.17973E+05 166 sudoite -12.21 -15.05 -2.84 -0.092 0.10755E+05 167 sulfur -11.22 -12.70 -1.48 -0.455 0.55998E+04 168 sylvite -1.32 -3.92 -2.59 -1.296 0.98089E+04 169 talc 5.36 4.97 -0.40 -0.023 0.14964E+04 170 talc-Fe 2.40 -1.35 -3.75 -0.221 0.14188E+05 171 talc-tschermaks -4.39 -6.09 -1.71 -0.100 0.64605E+04 173 tephroite 6.85 5.44 -1.41 -0.201 0.53376E+04 176 topaz-H -7.58 -10.31 -2.72 -0.248 0.10308E+05 177 tremolite 15.90 13.26 -2.64 -0.071 0.99858E+04 179 troilite-low -8.61 -9.44 -0.82 -0.275 0.31187E+04 180 tschermakite -5.24 -8.86 -3.62 -0.098 0.13707E+05 183 wadsleyite-Fe 3.46 1.35 -2.11 -0.301 0.79740E+04 184 wadsleyite-Mg 8.96 5.56 -3.39 -0.484 0.12836E+05 185 wairakite -9.04 -10.97 -1.93 -0.114 0.73154E+04 186 walstromite 4.69 2.04 -2.65 -0.529 0.10019E+05 187 wollastonite 4.26 2.04 -2.22 -0.443 0.83889E+04 188 pseudo-wollastonite 4.38 2.04 -2.34 -0.467 0.88451E+04 189 zoisite -7.68 -10.70 -3.02 -0.137 0.11434E+05 191 argentite -14.31 -19.31 -5.00 -1.249 0.18915E+05 192 beidellite-Ca -12.97 -14.83 -1.87 -0.115 0.70644E+04 193 beidellite-H -13.01 -15.39 -2.38 -0.152 0.90184E+04 194 beidellite-K -11.97 -14.12 -2.15 -0.132 0.81558E+04 195 beidellite-Mg -13.21 -14.82 -1.61 -0.100 0.61018E+04 196 beidellite-Na -11.91 -13.97 -2.06 -0.126 0.77997E+04 197 bornite -55.77 -56.02 -0.25 -0.019 0.93768E+03 199 chalcocite -14.65 -16.09 -1.45 -0.361 0.54695E+04 200 covellite -13.06 -14.40 -1.34 -0.509 0.50606E+04 202 montmorillonite-Ca -9.80 -11.18 -1.38 -0.085 0.52286E+04 203 montmorillonite-K -9.08 -10.47 -1.39 -0.085 0.52715E+04 204 montmorillonite-Mg -10.01 -11.17 -1.16 -0.072 0.44032E+04 205 montmorillonite-Na -8.75 -10.32 -1.57 -0.096 0.59451E+04 206 nontronite-Ca -3.43 -5.08 -1.65 -0.107 0.62564E+04 207 nontronite-H -3.48 -5.64 -2.16 -0.145 0.81823E+04 208 nontronite-K -2.43 -4.37 -1.94 -0.124 0.73400E+04 209 nontronite-Mg -3.64 -5.07 -1.43 -0.093 0.54161E+04 210 nontronite-Na -2.37 -4.22 -1.85 -0.119 0.69958E+04 215 gypsum -12.77 -15.04 -2.27 -0.567 0.85822E+04 231 acanthite -14.39 -19.31 -4.91 -1.229 0.18603E+05 232 alabandite -6.43 -7.40 -0.97 -0.322 0.36559E+04 234 anglesite -15.35 -17.65 -2.30 -1.150 0.87078E+04 238 boehmite -3.28 -4.48 -1.19 -0.199 0.45199E+04 242 copper,native 1.70 -1.70 -3.39 -1.181 0.12849E+05 244 ferrous-oxide 2.33 1.35 -0.98 -0.246 0.37169E+04 246 silver,native 0.40 -3.30 -3.70 -1.288 0.14013E+05 248 litharge 5.41 0.77 -4.64 -1.159 0.17544E+05 256 wurtzite -10.20 -11.01 -0.82 -0.272 0.30906E+04 257 zincite 2.41 -0.22 -2.63 -0.657 0.99453E+04 258 an20ab80 -4.93 -5.03 -0.10 -0.007 0.36894E+03 259 an25ab75 -5.12 -5.23 -0.11 -0.008 0.41725E+03 260 an30ab70 -5.31 -5.44 -0.13 -0.010 0.48701E+03 261 tr.625ac.25prg.125 10.62 9.39 -1.23 -0.033 0.46592E+04 Calculations done for 554.0000 Deg. C; 989.0000 bar Temperature changed by -1.000 degrees to 553.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 500 Loop limit = 500 Temperature = 553.00 C Pressure = 978.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5146E+02 kg liquid = 0.9270E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9977 Stoichiometric ionic strength = .2415060E+01 Osmotic coef. = 0.0000 True ionic strength = .4240640E+01 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.35121E-04 -4.4544 0.62052E-07 -7.2072 0.17668E-02 -2.7528 2 H2O 0.99767E+00 -0.0010 0.99767E+00 -0.0010 3 Cl- 0.70079E+00 -0.1544 0.72957E-03 -3.1369 0.10411E-02 -2.9825 4 SO4-- 0.90282E+01 0.9556 0.25743E-09 -9.5893 0.28514E-10 -10.5449 5 HCO3- 0.49421E-02 -2.3061 0.14314E-04 -4.8442 0.28963E-02 -2.5382 6 HS- 0.41432E+00 -0.3827 0.48591E-03 -3.3134 0.11728E-02 -2.9308 7 H4SiO4 0.43545E-01 -1.3611 0.43545E-01 -1.3611 0.10000E+01 0.0000 8 Al+++ 0.17677E-01 -1.7526 0.39866E-26 -26.3994 0.22553E-24 -24.6468 9 Ca++ 0.24430E+01 0.3879 0.93613E-11 -11.0287 0.38318E-11 -11.4166 10 Mg++ 0.16653E-04 -4.7785 0.53509E-17 -17.2716 0.32131E-12 -12.4931 11 Fe++ 0.65147E+00 -0.1861 0.40123E-12 -12.3966 0.61588E-12 -12.2105 12 K+ 0.22131E+00 -0.6550 0.98844E-03 -3.0050 0.44663E-02 -2.3500 13 Na+ 0.59744E+00 -0.2237 0.85438E-03 -3.0684 0.14301E-02 -2.8446 14 Mn++ 0.11971E-02 -2.9219 0.11745E-14 -14.9301 0.98116E-12 -12.0083 15 Zn++ 0.19927E-02 -2.7006 0.12273E-14 -14.9111 0.61588E-12 -12.2105 16 Cu+ 0.24084E-07 -7.6183 0.33189E-10 -10.4790 0.13781E-02 -2.8607 17 Pb++ 0.80551E-03 -3.0939 0.11733E-13 -13.9306 0.14566E-10 -10.8367 18 Ag+ 0.63077E-21 -21.2001 0.23168E-23 -23.6351 0.36730E-02 -2.4350 19 Ba++ 0.67753E+01 0.8309 0.22109E-09 -9.6554 0.32632E-10 -10.4864 20 HPO4-- 0.35282E-06 -6.4524 0.10649E-16 -16.9727 0.30181E-10 -10.5203 21 HSiO3- 0.26628E-02 -2.5747 0.27722E-05 -5.5572 0.10411E-02 -2.9825 22 Ca(HSiO3)+ 0.96978E-08 -8.0133 0.48208E-10 -10.3169 0.49710E-02 -2.3036 24 NaHSiO3,aq 0.12702E-05 -5.8961 0.12702E-05 -5.8961 0.10000E+01 0.0000 31 AgCl4-3 0.93862E-05 -5.0275 0.75458E-31 -31.1223 0.80393E-26 -26.0948 36 AlO+ 0.14196E-10 -10.8478 0.70567E-13 -13.1514 0.49710E-02 -2.3036 37 AlOH+2 0.37184E-06 -6.4296 0.61421E-18 -18.2117 0.16518E-11 -11.7820 38 HAlO2,aq 0.19348E-08 -8.7134 0.19348E-08 -8.7134 0.10000E+01 0.0000 39 AlO2- 0.69760E-01 -1.1564 0.90699E-05 -5.0424 0.13002E-03 -3.8860 40 BaCO3,aq 0.65453E-10 -10.1841 0.65453E-10 -10.1841 0.10000E+01 0.0000 41 Ba(HCO3)+ 0.83779E-04 -4.0769 0.66451E-06 -6.1775 0.79317E-02 -2.1006 42 BaCl+ 0.19328E-04 -4.7138 0.96081E-07 -7.0174 0.49710E-02 -2.3036 43 CH4,aq 0.73558E-03 -3.1334 0.82225E-03 -3.0850 0.11178E+01 0.0484 44 C2H6,aq 0.10192E-09 -9.9917 0.11393E-09 -9.9434 0.11178E+01 0.0484 48 CO,aq 0.96329E-02 -2.0162 0.96329E-02 -2.0162 0.10000E+01 0.0000 49 CO2,aq 0.21207E+01 0.3265 0.23706E+01 0.3749 0.11178E+01 0.0484 50 CO3-2 0.73539E+00 -0.1335 0.86002E-11 -11.0655 0.11695E-10 -10.9320 52 Ca(HCO3)+ 0.14283E-06 -6.8452 0.71000E-09 -9.1487 0.49710E-02 -2.3036 53 CaCl+ 0.44053E-06 -6.3560 0.21899E-08 -8.6596 0.49710E-02 -2.3036 54 CaCl2,aq 0.50119E-09 -9.3000 0.50119E-09 -9.3000 0.10000E+01 0.0000 55 CaOH+ 0.29517E-06 -6.5299 0.14673E-08 -8.8335 0.49710E-02 -2.3036 57 HCl,aq 0.10961E-04 -4.9601 0.10961E-04 -4.9601 0.10000E+01 0.0000 61 Cu+2 0.32230E-09 -9.4917 0.53239E-21 -21.2738 0.16518E-11 -11.7820 66 CuCl,aq 0.13511E-07 -7.8693 0.13511E-07 -7.8693 0.10000E+01 0.0000 67 CuCl2- 0.26345E-06 -6.5793 0.27427E-09 -9.5618 0.10411E-02 -2.9825 68 CuCl3-2 0.15951E-03 -3.7972 0.18654E-14 -14.7292 0.11695E-10 -10.9320 71 CuO2-2 0.58608E-10 -10.2320 0.68541E-21 -21.1640 0.11695E-10 -10.9320 73 Fe+3 0.30194E-03 -3.5201 0.28120E-27 -27.5510 0.93132E-24 -24.0309 74 FeCl+ 0.68102E-08 -8.1668 0.33854E-10 -10.4704 0.49710E-02 -2.3036 75 FeCl2,aq 0.75716E-07 -7.1208 0.75716E-07 -7.1208 0.10000E+01 0.0000 77 FeO,aq 0.21152E-06 -6.6746 0.21152E-06 -6.6746 0.10000E+01 0.0000 78 FeOH+ 0.20229E-06 -6.6940 0.10056E-08 -8.9976 0.49710E-02 -2.3036 79 HFeO2- 0.47664E-04 -4.3218 0.49622E-07 -7.3043 0.10411E-02 -2.9825 81 FeOH+2 0.28728E-07 -7.5417 0.47453E-19 -19.3237 0.16518E-11 -11.7820 82 FeO2- 0.55632E-05 -5.2547 0.57917E-08 -8.2372 0.10411E-02 -2.9825 83 HFeO2,aq 0.22043E-09 -9.6567 0.22043E-09 -9.6567 0.10000E+01 0.0000 84 H2,aq 0.12845E+00 -0.8913 0.14359E+00 -0.8429 0.11178E+01 0.0484 85 KCl,aq 0.45428E-03 -3.3427 0.45428E-03 -3.3427 0.10000E+01 0.0000 86 KHSO4,aq 0.86250E-07 -7.0642 0.86250E-07 -7.0642 0.10000E+01 0.0000 87 KOH,aq 0.30952E-05 -5.5093 0.30952E-05 -5.5093 0.10000E+01 0.0000 88 KSO4- 0.67594E-04 -4.1701 0.70370E-07 -7.1526 0.10411E-02 -2.9825 94 MnO,aq 0.10867E-10 -10.9639 0.10867E-10 -10.9639 0.10000E+01 0.0000 95 MnOH+ 0.63701E-10 -10.1959 0.31666E-12 -12.4994 0.49710E-02 -2.3036 96 MnO2-2 0.86571E-07 -7.0626 0.10124E-17 -17.9946 0.11695E-10 -10.9320 100 MnCl+ 0.96792E-09 -9.0142 0.48116E-11 -11.3177 0.49710E-02 -2.3036 102 NaCl,aq 0.84320E-03 -3.0741 0.84320E-03 -3.0741 0.10000E+01 0.0000 103 NaOH,aq 0.12192E-05 -5.9139 0.12192E-05 -5.9139 0.10000E+01 0.0000 105 OH- 0.10343E+00 -0.9853 0.13448E-04 -4.8714 0.13002E-03 -3.8860 110 HPO3-2 0.13565E-06 -6.8676 0.15864E-17 -17.7996 0.11695E-10 -10.9320 114 H2PO4- 0.31401E-10 -10.5031 0.65845E-13 -13.1815 0.20969E-02 -2.6784 115 PO4-3 0.43502E-06 -6.3615 0.10183E-24 -24.9921 0.23409E-18 -18.6306 119 HP2O7-3 0.17832E+01 0.2512 0.14335E-25 -25.8436 0.80393E-26 -26.0948 120 P2O7-4 0.10000E+02 1.0000 0.39325E-38 -38.4053 0.39325E-39 -39.4053 121 PbCl+ 0.39602E-08 -8.4023 0.19686E-10 -10.7058 0.49710E-02 -2.3036 122 PbCl2,aq 0.31481E-09 -9.5020 0.31481E-09 -9.5020 0.10000E+01 0.0000 123 PbCl3- 0.20960E-08 -8.6786 0.21821E-11 -11.6611 0.10411E-02 -2.9825 124 PbCl4-2 0.11634E-04 -4.9343 0.13606E-15 -15.8663 0.11695E-10 -10.9320 125 PbO,aq 0.32062E-08 -8.4940 0.32062E-08 -8.4940 0.10000E+01 0.0000 126 HPbO2- 0.10318E-09 -9.9864 0.10742E-12 -12.9689 0.10411E-02 -2.9825 127 Pb(HS)2,aq 0.22923E-03 -3.6397 0.22923E-03 -3.6397 0.10000E+01 0.0000 128 Pb(HS)3- 0.10487E+00 -0.9794 0.10918E-03 -3.9619 0.10411E-02 -2.9825 129 H2S,aq 0.21867E+01 0.3398 0.24443E+01 0.3882 0.11178E+01 0.0484 130 S2-2 0.10000E+02 1.0000 0.11695E-09 -9.9320 0.11695E-10 -10.9320 131 S3-2 0.26212E+00 -0.5815 0.30654E-11 -11.5135 0.11695E-10 -10.9320 132 S3- 0.30383E-01 -1.5174 0.31631E-04 -4.4999 0.10411E-02 -2.9825 133 S4-2 0.14286E-02 -2.8451 0.16707E-13 -13.7771 0.11695E-10 -10.9320 134 S5-2 0.67956E-05 -5.1678 0.79473E-16 -16.0998 0.11695E-10 -10.9320 135 SO2,aq 0.24014E-04 -4.6195 0.24014E-04 -4.6195 0.10000E+01 0.0000 136 SO3-2 0.18412E-04 -4.7349 0.27173E-13 -13.5659 0.14759E-08 -8.8310 137 HSO3- 0.38371E-04 -4.4160 0.39947E-07 -7.3985 0.10411E-02 -2.9825 138 HSO4- 0.92590E-05 -5.0334 0.56792E-07 -7.2457 0.61337E-02 -2.2123 140 S2O3-2 0.78732E-01 -1.1038 0.92076E-12 -12.0359 0.11695E-10 -10.9320 141 HS2O3- 0.40937E-08 -8.3879 0.42619E-11 -11.3704 0.10411E-02 -2.9825 143 S2O4-2 0.88055E-09 -9.0552 0.10298E-19 -19.9873 0.11695E-10 -10.9320 146 S2O5-2 0.21801E-10 -10.6615 0.25496E-21 -21.5935 0.11695E-10 -10.9320 150 S4O6-2 0.12959E-10 -10.8874 0.15155E-21 -21.8194 0.11695E-10 -10.9320 152 ZnCl+ 0.45014E-06 -6.3467 0.22377E-08 -8.6502 0.49710E-02 -2.3036 153 ZnCl2,aq 0.20827E-08 -8.6814 0.20827E-08 -8.6814 0.10000E+01 0.0000 154 ZnCl3- 0.76388E-09 -9.1170 0.79525E-12 -12.0995 0.10411E-02 -2.9825 155 ZnO,aq 0.12636E-07 -7.8984 0.12636E-07 -7.8984 0.10000E+01 0.0000 156 ZnOH+ 0.11457E-05 -5.9409 0.56952E-08 -8.2445 0.49710E-02 -2.3036 157 ZnO2-2 0.19253E-02 -2.7155 0.22516E-13 -13.6475 0.11695E-10 -10.9320 158 HZnO2- 0.18628E-06 -6.7298 0.19394E-09 -9.7123 0.10411E-02 -2.9825 Charge balance for all species = -.6638E+02 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3512123E-04 0.5047821E+01 0.3960848E+04 0.0000 2 H2O 0.1000000E+01 0.5614748E+02 0.7874470E+06 0.0000 3 Cl- 0.7007861E+00 0.7027730E+00 0.1939624E+05 4.0703 4 SO4-- 0.9028183E+01 0.1414842E+00 0.1058053E+05 4.8251 5 HCO3- 0.4942135E-02 0.2865322E+01 0.1361054E+06 2.3630 6 HS- 0.4143248E+00 0.1189466E+01 0.3062400E+05 3.8938 7 H4SiO4 0.4354461E-01 0.9956945E-03 0.7450213E+02 -1.3611 8 Al+++ 0.1767692E-01 -.1364663E+00 -.2866428E+04 -4.7777 9 Ca++ 0.2443019E+01 0.1487465E-05 0.4640901E-01 3.3858 10 Mg++ 0.1665343E-04 0.2230525E-04 0.4221603E+00 -2.8571 11 Fe++ 0.6514746E+00 -.2259640E-01 -.9824008E+03 2.0179 12 K+ 0.2213092E+00 -.1927465E-02 -.5867255E+02 4.2022 13 Na+ 0.5974367E+00 0.5982824E+00 0.1070757E+05 4.1389 14 Mn++ 0.1197051E-02 0.1240040E-02 0.5303447E+02 -0.5157 15 Zn++ 0.1992730E-02 0.3862171E-04 0.1965439E+01 -0.4966 16 Cu+ 0.2408398E-07 0.3637557E-03 0.1799313E+02 -3.2718 17 Pb++ 0.8055064E-03 -.3146244E-02 -.5074704E+03 0.4839 18 Ag+ 0.6307716E-21 0.9386164E-05 0.7882036E+00 -16.4279 19 Ba++ 0.6775317E+01 -.5041418E-07 -.5390132E-02 4.7591 20 HPO4-- 0.3528248E-06 0.7286886E-01 0.5444623E+04 -2.5582 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4679259E+01 -.5009018E+01 0.0000000E+00 2 H2O 0.5196478E+02 0.5204792E+02 0.2863388E+02 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.1311539E+00 -.2966828E+02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1102618E+01 -.2790305E+02 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.9229948E-03 0.1007594E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 -.1265023E+00 -.8035839E-01 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1378859E-05 -.2652894E+02 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.5239156E-05 0.0000000E+00 11 Fe++ 0.8766754E-02 -.2094654E-01 -.5955453E+00 0.0000000E+00 12 K+ 0.1254101E+00 -.1786732E-02 -.8035839E-01 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.3976898E-04 0.0000000E+00 15 Zn++ 0.2299335E-02 0.3580178E-04 -.1334311E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.3371964E-03 0.2514708E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 -.2916524E-02 -.9784163E-01 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 -.4673324E-07 -.3557673E+02 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.6754841E-01 -.2184565E+02 0.0000000E+00 Chg. balance for solid moles: 0.7105E-14 Mass of aqueous solution: 0.119076E+04 g Temperature = 553.00 C Pressure = 978.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 9.880 0.995 1345. 3.129 -11.84 454.0 annite 5.097 0.707 2609. 3.417 -22.97 786.7 phlogopite 0.1746E-05 -5.758 0.7287E-03 -3.137 -.6417E-05 0.2613E-03 biotite-Mn 0.1326E-04 -4.878 0.6750E-02 -2.171 -.5943E-04 0.2023E-02 apatite-OH -7.282 1.000 -3658. 1.000 32.21 -1162. microcline -5.178 1.000 -1441. 1.000 12.69 -563.0 pyrite -15.89 1.000 -1906. 1.000 16.78 -380.3 quartz 0.3418 -0.466 20.54 1.313 -.1808 7.756 barite -35.58 1.000 -8304. 1.000 73.11 -1853. chalcopyrite 0.2515E-03 -3.600 0.4614E-01 -1.336 -.4063E-03 0.1077E-01 galena -.9784E-01 1.000 -23.41 1.000 0.2061 -3.081 sphalerite -.1334E-02 1.000 -.1300 1.000 0.1145E-02 -.3179E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 annite 0.1000E+01 0.1000E+01 1.0000 0.000 phlogopite 0.3426E-06 0.3426E-06 1.0000 -6.465 biotite-Mn 0.2601E-05 0.2601E-05 1.0000 -5.585 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass =************ g Volume =-2713.829613 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases anhydrite does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.2103E+05 chalcopyrite does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.4296E+03 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 245 galena -10.04 -10.04 0.00 0.000 -0.67152E-11 255 sphalerite -11.02 -11.02 0.00 0.000 0.67152E-11 26 biotite-Mn 10.55 10.55 0.00 0.000 -0.20146E-10 144 quartz -1.36 -1.36 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 0.00 -0.26 -0.258 0.97469E+03 2.733 2 CO2,gas -10.21 -12.05 -1.84 -0.612 0.69453E+04 1.153 3 CH4,gas 6.81 1.43 -5.38 -1.345 0.20343E+05 -2.391 4 H2,gas 6.00 3.37 -2.63 -1.505 0.99535E+04 0.357 5 H2S,gas -8.51 -10.52 -2.01 -1.006 0.76064E+04 0.978 6 CO,gas -3.92 -8.68 -4.76 -1.465 0.18002E+05 -1.772 7 SO3,gas -7.72 -24.00 -16.29 -4.071 0.61565E+05 -13.295 8 O2,gas 17.04 -6.74 -23.78 -15.856 0.89913E+05 -20.794 9 HCl,gas -6.20 -10.34 -4.14 -2.072 0.15669E+05 -4.145 10 acmite 3.61 1.75 -1.86 -0.193 0.70179E+04 13 akimotoite-Fe 4.20 0.66 -3.54 -0.708 0.13373E+05 14 albite-high -4.03 -4.72 -0.69 -0.053 0.25931E+04 15 albite -4.04 -4.72 -0.68 -0.052 0.25754E+04 16 almandine -6.53 -7.58 -1.06 -0.053 0.39966E+04 18 analcite -1.83 -3.36 -1.53 -0.170 0.57840E+04 19 andalusite -9.58 -10.92 -1.34 -0.134 0.50732E+04 24 annite 1.39 1.39 0.00 0.000 -0.17627E-10 25 phlogopite 6.17 6.17 0.00 0.000 -0.20146E-10 27 anorthite -7.21 -8.89 -1.68 -0.129 0.63506E+04 29 anthophyllite-Fe 2.43 3.24 0.81 0.022 -0.30655E+04 33 aragonite -4.75 -8.67 -3.92 -1.305 0.14803E+05 35 calcite -4.86 -8.67 -3.81 -1.269 0.14392E+05 36 carnegieite-low 0.34 -2.00 -2.34 -0.335 0.88579E+04 37 carnegieite-high 0.43 -2.00 -2.43 -0.347 0.91929E+04 39 carpholite-Fe -7.41 -10.26 -2.85 -0.190 0.10790E+05 41 celadonite-Fe -1.90 -4.00 -2.10 -0.124 0.79402E+04 45 daphnite -1.57 -3.56 -1.99 -0.062 0.75074E+04 49 chloritoid-Fe -7.33 -8.90 -1.57 -0.105 0.59351E+04 52 coesite -1.06 -1.36 -0.30 -0.099 0.11213E+04 54 cordierite-Fe -19.16 -21.88 -2.72 -0.094 0.10272E+05 56 corundum -8.04 -9.56 -1.52 -0.138 0.57576E+04 58 cristobalite -1.31 -1.36 -0.05 -0.016 0.18103E+03 61 cymrite-K -2.30 -4.66 -2.35 -0.196 0.89024E+04 62 deerite 13.28 9.88 -3.40 -0.050 0.12870E+05 63 diaspore -3.53 -4.78 -1.25 -0.208 0.47185E+04 64 diamond -1.91 -5.31 -3.40 -0.971 0.12843E+05 66 hedenbergite 4.15 2.68 -1.46 -0.146 0.55286E+04 73 epidote -3.02 -6.53 -3.51 -0.170 0.13287E+05 74 clinozoisite -7.46 -11.65 -4.18 -0.190 0.15814E+05 75 epidote-Fe 3.13 -1.42 -4.55 -0.236 0.17208E+05 76 fayalite 2.63 2.67 0.04 0.006 -0.15353E+03 77 ferrosilite 1.38 1.32 -0.06 -0.006 0.22837E+03 81 gibbsite -1.90 -4.78 -2.88 -0.412 0.10902E+05 83 glaucophane-Fe -1.86 -6.10 -4.25 -0.115 0.16049E+05 84 goethite 1.35 0.33 -1.02 -0.221 0.38706E+04 85 graphite -2.23 -5.31 -3.08 -0.880 0.11643E+05 86 greenalite 4.98 3.33 -1.65 -0.137 0.62228E+04 87 grunerite 3.01 3.24 0.24 0.006 -0.89563E+03 88 halite -1.44 -6.21 -4.77 -2.383 0.18014E+05 89 hematite 1.16 0.66 -0.50 -0.060 0.18817E+04 90 heulandite -11.62 -15.69 -4.08 -0.185 0.15414E+05 91 hercynite -6.06 -7.54 -1.48 -0.099 0.55893E+04 93 iron 9.13 5.39 -3.74 -0.787 0.14130E+05 94 jadeite -1.15 -3.36 -2.21 -0.221 0.83670E+04 96 kalsilite -0.28 -1.94 -1.65 -0.236 0.62559E+04 97 kaolinite -8.75 -12.28 -3.53 -0.321 0.13337E+05 98 kyanite -9.41 -10.92 -1.51 -0.151 0.57011E+04 100 laumontite -7.07 -11.61 -4.55 -0.303 0.17192E+05 101 lawsonite -4.45 -8.89 -4.44 -0.296 0.16789E+05 102 leucite -2.31 -3.30 -0.99 -0.099 0.37400E+04 106 magnetite 2.60 2.68 0.08 0.006 -0.28860E+03 107 minnesotaite 1.00 0.61 -0.39 -0.023 0.14669E+04 112 margarite -14.81 -18.45 -3.64 -0.146 0.13777E+05 115 microcline -4.65 -4.65 0.00 0.000 -0.20146E-10 118 mullite-Si -8.81 -10.92 -2.11 -0.211 0.79853E+04 119 muscovite -12.57 -14.21 -1.64 -0.097 0.62045E+04 120 paragonite -11.89 -14.28 -2.39 -0.141 0.90433E+04 121 nepheline 0.04 -2.00 -2.04 -0.291 0.77062E+04 123 osumilite-Fe -26.11 -29.25 -3.14 -0.065 0.11869E+05 126 periclase-Fe 3.30 2.02 -1.28 -0.320 0.48320E+04 127 perovskite-Al -6.27 -9.56 -3.29 -0.299 0.12421E+05 134 prehnite -2.46 -6.87 -4.40 -0.259 0.16648E+05 135 prehnite-Fe 2.38 -1.76 -4.13 -0.249 0.15627E+05 139 px-Ca-tschermaks -3.93 -7.53 -3.60 -0.257 0.13611E+05 140 pyrite -22.17 -22.39 -0.23 -0.053 0.85911E+03 141 pyrrhotite -8.70 -8.50 0.20 0.067 -0.75787E+03 142 pyrrhotiteFe0.875 -9.51 -9.17 0.34 0.125 -0.12868E+04 143 pyrophyllite -12.80 -15.00 -2.20 -0.137 0.83165E+04 146 riebeckite 5.93 4.12 -1.81 -0.050 0.68396E+04 147 ringwoodite-Fe 3.64 2.67 -0.97 -0.138 0.36492E+04 150 rhodonite 2.63 -1.88 -4.50 -0.901 0.17028E+05 151 sanidine -4.11 -4.65 -0.55 -0.042 0.20679E+04 153 siderite -7.42 -10.03 -2.62 -0.872 0.98932E+04 154 sillimanite -9.53 -10.92 -1.38 -0.138 0.52263E+04 162 stilpnomelane-Fe -5.50 -8.25 -2.75 -0.082 0.10394E+05 164 stishovite 1.64 -1.36 -3.00 -1.000 0.11345E+05 165 sudoite-Fe -14.28 -19.16 -4.89 -0.158 0.18476E+05 167 sulfur -11.24 -13.89 -2.65 -0.815 0.10009E+05 168 sylvite -1.34 -6.14 -4.80 -2.399 0.18138E+05 170 talc-Fe 2.43 0.61 -1.82 -0.107 0.68773E+04 176 topaz-H -7.48 -10.92 -3.44 -0.312 0.12988E+05 178 ferroactinolite 9.02 5.98 -3.04 -0.082 0.11506E+05 179 troilite-low -8.61 -8.50 0.11 0.037 -0.42236E+03 183 wadsleyite-Fe 3.50 2.67 -0.82 -0.118 0.31094E+04 185 wairakite -8.95 -11.61 -2.66 -0.157 0.10074E+05 186 walstromite 4.70 2.03 -2.67 -0.534 0.10098E+05 187 wollastonite 4.27 2.03 -2.24 -0.448 0.84683E+04 188 pseudo-wollastonite 4.39 2.03 -2.36 -0.472 0.89252E+04 189 zoisite -7.51 -11.65 -4.13 -0.188 0.15629E+05 192 beidellite-Ca -12.87 -15.57 -2.70 -0.167 0.10202E+05 193 beidellite-H -12.91 -16.12 -3.21 -0.205 0.12141E+05 194 beidellite-K -11.87 -14.74 -2.87 -0.176 0.10836E+05 195 beidellite-Mg -13.11 -16.60 -3.49 -0.216 0.13183E+05 196 beidellite-Na -11.81 -14.76 -2.95 -0.180 0.11133E+05 197 bornite -55.87 -58.11 -2.24 -0.167 0.84494E+04 199 chalcocite -14.68 -17.06 -2.38 -0.596 0.90071E+04 200 covellite -13.09 -15.48 -2.39 -0.910 0.90290E+04 202 montmorillonite-Ca -9.73 -13.80 -4.07 -0.252 0.15387E+05 203 montmorillonite-K -9.01 -12.98 -3.96 -0.243 0.14976E+05 204 montmorillonite-Mg -9.94 -14.83 -4.89 -0.303 0.18503E+05 205 montmorillonite-Na -8.68 -13.00 -4.31 -0.264 0.16298E+05 206 nontronite-Ca -3.40 -5.34 -1.94 -0.126 0.73444E+04 207 nontronite-H -3.45 -5.90 -2.45 -0.164 0.92553E+04 208 nontronite-K -2.41 -4.52 -2.11 -0.135 0.79710E+04 209 nontronite-Mg -3.61 -6.37 -2.76 -0.179 0.10446E+05 210 nontronite-Na -2.35 -4.54 -2.19 -0.141 0.82794E+04 232 alabandite -6.43 -11.04 -4.61 -1.535 0.17413E+05 237 barite -16.31 -19.24 -2.93 -1.467 0.11094E+05 238 boehmite -3.23 -4.78 -1.55 -0.258 0.58609E+04 240 chalcopyrite -23.87 -23.98 -0.11 -0.021 0.42956E+03 242 copper,native 1.70 -1.59 -3.28 -1.142 0.12408E+05 244 ferrous-oxide 2.36 2.02 -0.34 -0.085 0.12877E+04 248 litharge 5.42 0.48 -4.93 -1.233 0.18649E+05 256 wurtzite -10.20 -11.02 -0.82 -0.272 0.30901E+04 257 zincite 2.43 -0.50 -2.92 -0.731 0.11053E+05 258 an20ab80 -4.89 -5.55 -0.66 -0.051 0.25079E+04 259 an25ab75 -5.07 -5.76 -0.69 -0.053 0.25963E+04 260 an30ab70 -5.25 -5.97 -0.72 -0.055 0.27057E+04 Number of iterations reached the given limit ( 500) Non-Convergence assumed. Execution aborted. Check "convergence problems" in manual. Cut step size to one tenth of previous value and try again.