File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. S2,gas is suppressed in THIS RUN. S2,gas is suppressed in THIS RUN. SO2,gas is suppressed in THIS RUN. SO2,gas is suppressed in THIS RUN. spessartine is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. annite is suppressed in THIS RUN. phlogopite is suppressed in THIS RUN. biotite-Mn is suppressed in THIS RUN. antigorite is suppressed in SOLTHERM data file. cordierite is suppressed in THIS RUN. osumilite(1) is suppressed in THIS RUN. pyroxmangite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. tridymite is suppressed in THIS RUN. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. silica-amorphous is suppressed in THIS RUN. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. 0.42624E+01 0.45251E-05 0.1935 0.00000000E+00 H2O 2 0. 0.51965E+02 0.10000E+01 0.9969 0.00000000E+00 Cl- 3 -1. 0.65146E+00 0.12035E+00 0.1635 0.00000000E+00 SO4-- 4 -2. 0.25172E+00 0.28314E-03 0.0017 0.00000000E+00 HCO3- 5 -1. 0.26561E+01 0.81833E-05 0.1762 0.00000000E+00 HS- 6 -1. 0.11601E+01 0.11175E-03 0.1649 0.00000000E+00 H4SiO4 7 0. 0.14359E+00 0.44270E-01 1.0000 0.00000000E+00 Al+++ 8 3. 0.69454E-03 0.47501E-16 0.0000 0.00000000E+00 Ca++ 9 2. 0.52791E-03 0.13760E-05 0.0014 0.00000000E+00 Mg++ 10 2. 0.20677E-04 0.19566E-05 0.0011 0.00000000E+00 Fe++ 11 2. 0.87668E-02 0.14609E-07 0.0012 0.00000000E+00 K+ 12 1. 0.12541E+00 0.34211E-01 0.1805 0.00000000E+00 Na+ 13 1. 0.55460E+00 0.10756E+00 0.1653 0.00000000E+00 Mn++ 14 2. 0.11495E-02 0.15533E-05 0.0012 0.00000000E+00 Zn++ 15 2. 0.22993E-02 0.38863E-09 0.0012 0.00000000E+00 Cu+ 16 1. 0.39961E-03 0.11877E-07 0.1648 0.00000000E+00 Pb++ 17 2. 0.34017E-03 0.29339E-08 0.0015 0.00000000E+00 Ag+ 18 1. 0.87008E-05 0.27310E-09 0.1776 0.00000000E+00 Ba++ 19 2. 0.55372E-04 0.64561E-07 0.0017 0.00000000E+00 HPO4-- 20 -2. 0.85675E-05 0.17521E-08 0.0017 0.00000000E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 989.0000 SLIM = 0.535000E+03 TEMP = 554.0000 SINC = -.1000E+01 TEMPC = 0.0000 TOTMIX = 0.000000E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.1000E-08 RM = 0.0000 AQGRM = 1200.0089 SUPRNT = 0.1000E-10 VBOX-1 = 0.0000 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 500 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 0 INCREM = 0 INCP = 0 MINSOL = 0 NEUT = 0 AWAT = 0 CHGF = 0 Given pressure grid: 66 T-P points read Of the derived species, only those with molality > 0.10E-10 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 21 -1. 11.3907 Mg(HCO3)+ 90 1. -6.2356 Ca(HSiO3)+ 22 1. 5.1311 MgCl+ 91 1. -4.8394 Mg(HSiO3)+ 23 1. 5.6102 MgOH+ 92 1. 4.3604 NaHSiO3,aq 24 0. 8.6833 Mn+3 93 3. 13.4600 Ag(CO3)- 25 -1. 9.0756 MnO,aq 94 0. 10.4269 Ag(CO3)2-3 26 -3. 21.1041 MnOH+ 95 1. 4.7596 Ag+2 27 2. 13.9650 MnO2-2 96 -2. 31.8331 AgCl,aq 28 0. -5.0819 HMnO2- 97 -1. 20.6577 AgCl2- 29 -1. -7.6379 MnO4- 98 -1. 34.1126 AgCl3-2 30 -2. -6.8678 MnO4-2 99 -2. 44.5331 AgCl4-3 31 -3. -5.0443 MnCl+ 100 1. -6.7477 Ag(OH),aq 32 0. 10.8304 MnSO4,aq 101 0. -8.3197 AgO- 33 -1. 16.6702 NaCl,aq 102 0. -3.1102 Ag(HS),aq 34 0. -6.3696 NaOH,aq 103 0. 10.0513 Ag(HS)2- 35 -1. -10.8247 O2,aq 104 0. 14.6906 AlO+ 36 1. 1.1326 OH- 105 -1. 12.0588 AlOH+2 37 2. -1.0066 HO2- 106 -1. 27.8309 HAlO2,aq 38 0. 3.8851 H2O2,aq 107 0. 15.0470 AlO2- 39 -1. 7.3975 H3PO2,aq 108 0. 0.3717 BaCO3,aq 40 0. 2.9100 H2PO2- 109 -1. 6.1380 Ba(HCO3)+ 41 1. -8.3067 HPO3-2 110 -2. 4.1795 BaCl+ 42 1. -5.7642 H3PO3,aq 111 0. -11.8211 CH4,aq 43 0. 4.5277 H2PO3- 112 -1. -6.1142 C2H6,aq 44 0. 9.4375 H3PO4,aq 113 0. -17.8576 C3H8,aq 45 0. 13.9628 H2PO4- 114 -1. -10.9878 C4H10,aq 46 0. 18.2258 PO4-3 115 -3. 15.2293 ethanol,aq 47 0. 9.6956 H4P2O7,aq 116 0. -37.6808 CO,aq 48 0. -6.6450 H3P2O7- 117 -1. -31.4493 CO2,aq 49 0. -12.3968 H2P2O7-2 118 -2. -25.7766 CO3-2 50 -2. 13.4191 HP2O7-3 119 -3. -15.3058 CaCO3,aq 51 0. 2.5468 P2O7-4 120 -4. 0.8703 Ca(HCO3)+ 52 1. -6.7177 PbCl+ 121 1. -6.3508 CaCl+ 53 1. -5.4978 PbCl2,aq 122 0. -10.6697 CaCl2,aq 54 0. -7.9755 PbCl3- 123 -1. -11.6445 CaOH+ 55 1. 4.9975 PbCl4-2 124 -2. -10.5823 CaSO4,aq 56 0. -8.2951 PbO,aq 125 0. 8.9698 HCl,aq 57 0. -5.3459 HPbO2- 126 -1. 20.6279 HClO,aq 58 0. 6.5360 Pb(HS)2,aq 127 0. -16.8886 ClO- 59 -1. 16.5826 Pb(HS)3- 128 -1. -19.8776 HClO2,aq 60 0. 19.8418 H2S,aq 129 0. -10.8896 Cu+2 61 2. 1.9236 S2-2 130 -2. -0.6777 CuCl+ 62 1. -3.5020 S3-2 131 -2. -12.3521 CuCl2,aq 63 0. -7.0592 S3- 132 -1. -28.2416 CuCl3- 64 -1. -6.8697 S4-2 133 -2. -23.9572 CuCl4-2 65 -2. -4.4006 S5-2 134 -2. -35.5029 CuCl,aq 66 0. -5.7243 SO2,aq 135 0. -15.9841 CuCl2- 67 -1. -7.1662 SO3-2 136 -2. 7.3417 CuCl3-2 68 -2. -5.1404 HSO3- 137 -1. -6.0236 CuO,aq 69 0. 11.4030 HSO4- 138 -1. -9.5403 CuOH+ 70 1. 5.4728 HSO5- 139 -1. 3.7764 CuO2-2 71 -2. 30.5853 S2O3-2 140 -2. -8.0598 HCuO2- 72 -1. 18.5915 HS2O3- 141 -1. -15.9187 Fe+3 73 3. 6.2863 H2S2O3,aq 142 0. -21.8066 FeCl+ 74 1. -5.0548 S2O4-2 143 -2. -3.4855 FeCl2,aq 75 0. -11.5356 HS2O4- 144 -1. -11.7763 FeCl+2 76 2. -0.0066 H2S2O4,aq 145 0. -17.7232 FeO,aq 77 0. 8.6691 S2O5-2 146 -2. -5.2459 FeOH+ 78 1. 3.7939 S2O6-2 147 -2. -6.4237 HFeO2- 79 -1. 16.4870 S2O8-2 148 -2. 0.6788 FeO+ 80 1. 6.7555 S3O6-2 149 -2. -16.1517 FeOH+2 81 2. 5.2397 S4O6-2 150 -2. -36.1198 FeO2- 82 -1. 15.7337 S5O6-2 151 -2. -36.8469 HFeO2,aq 83 0. 9.9747 ZnCl+ 152 1. -9.4002 H2,aq 84 0. 4.2073 ZnCl2,aq 153 0. -12.4850 KCl,aq 85 0. -2.7782 ZnCl3- 154 -1. -12.2082 KHSO4,aq 86 0. -12.7085 ZnO,aq 155 0. 7.3793 KOH,aq 87 0. 9.7104 ZnOH+ 156 1. 0.5186 KSO4- 88 -1. -5.4273 ZnO2-2 157 -2. 27.5140 MgCO3,aq 89 0. 4.4774 HZnO2- 158 -1. 16.3818 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 0.257 0.0000E+00 piemontite(ordered) 130 1.890 0.0000E+00 CO2,gas 2 -10.190 0.0000E+00 prehnite 131 -2.579 0.0000E+00 CH4,gas 3 6.817 0.0000E+00 prehnite-Fe 132 2.298 0.0000E+00 H2,gas 4 5.997 0.0000E+00 pumpellyite-Fe 133 -5.745 0.0000E+00 H2S,gas 5 -8.490 0.0000E+00 pumpellyite-Mg 134 -4.068 0.0000E+00 CO,gas 6 -3.903 0.0000E+00 px-Mg-tschermaks 135 -4.789 0.0000E+00 SO3,gas 7 -7.698 0.0000E+00 px-Ca-tschermaks 136 -4.051 0.0000E+00 O2,gas 8 14.027 0.0000E+00 pyrite 137 -22.138 0.6168E-02 HCl,gas 9 -3.193 0.0000E+00 pyrrhotite 138 -8.703 0.0000E+00 acmite 10 3.605 0.0000E+00 pyrrhotiteFe0.875 139 -9.510 0.0000E+00 akermanite 11 13.560 0.0000E+00 pyrophyllite 140 -12.871 0.0000E+00 akimotoite 12 6.335 0.0000E+00 quartz 141 -1.351 0.9757E-01 akimotoite-Fe 13 4.177 0.0000E+00 rankinite 142 16.863 0.0000E+00 albite-high 14 -4.062 0.0000E+00 riebeckite 143 5.893 0.0000E+00 albite 15 -4.066 0.0000E+00 ringwoodite-Fe 144 3.604 0.0000E+00 almandine 16 -6.678 0.0000E+00 ringwoodite-Mg 145 9.908 0.0000E+00 pyrope 17 0.164 0.0000E+00 rhodochrosite 146 -5.548 0.0000E+00 analcite 18 -1.868 0.0000E+00 rhodonite 147 2.617 0.0000E+00 andalusite 19 -9.676 0.0000E+00 sanidine 148 -4.137 0.0000E+00 andradite 20 12.224 0.0000E+00 sapphirine(351) 149 -29.381 0.0000E+00 grossular 21 2.684 0.0000E+00 siderite 150 -7.412 0.0000E+00 anhydrite 22 -15.033 0.3854E-03 sillimanite 151 -9.636 0.0000E+00 ankerite 23 -12.494 0.0000E+00 sodalite 152 -5.182 0.0000E+00 anorthite 24 -7.320 0.0000E+00 spinel 153 -3.967 0.0000E+00 anthophyllite 25 15.404 0.0000E+00 spurrite 154 19.936 0.0000E+00 anthophyllite-Fe 26 2.351 0.0000E+00 staurolite-Fe 155 -76.909 0.0000E+00 apatite-OH 27 -53.935 0.1596E-05 staurolite-Mg 156 -68.174 0.0000E+00 apatite-OH-zs 28 -51.724 0.0000E+00 staurolite-Mn 157 -67.937 0.0000E+00 apatite-Cl-zs 29 -58.420 0.0000E+00 stilbite 158 -7.927 0.0000E+00 aragonite 30 -4.741 0.0000E+00 stilpnomelane-Fe 159 -5.645 0.0000E+00 brucite 31 5.696 0.0000E+00 stilpnomelane-Mg 160 1.457 0.0000E+00 calcite 32 -4.850 0.0000E+00 stishovite 161 1.647 0.0000E+00 carnegieite-low 33 0.296 0.0000E+00 sudoite-Fe 162 -14.513 0.0000E+00 carnegieite-high 34 0.384 0.0000E+00 sudoite 163 -12.210 0.0000E+00 carpholite-Mg 35 -6.119 0.0000E+00 sulfur 164 -11.220 0.0000E+00 carpholite-Fe 36 -7.519 0.0000E+00 sylvite 165 -1.324 0.0000E+00 celadonite 37 -0.496 0.0000E+00 talc 166 5.362 0.0000E+00 celadonite-Fe 38 -1.940 0.0000E+00 talc-Fe 167 2.401 0.0000E+00 chrysotile 39 9.966 0.0000E+00 talc-tschermaks 168 -4.386 0.0000E+00 chondrodite 40 19.761 0.0000E+00 tenorite 169 3.617 0.0000E+00 clinochlore 41 5.543 0.0000E+00 tephroite 170 6.850 0.0000E+00 daphnite 42 -1.753 0.0000E+00 tilleyite 171 6.806 0.0000E+00 chlorite-Mn 43 12.554 0.0000E+00 titanite-CaSi 172 7.070 0.0000E+00 chlorite-Al-free 44 20.096 0.0000E+00 topaz-H 173 -7.583 0.0000E+00 chloritoid-Mg 45 -5.442 0.0000E+00 tremolite 174 15.898 0.0000E+00 chloritoid-Fe 46 -7.450 0.0000E+00 ferroactinolite 175 8.949 0.0000E+00 chloritoid-Mn 47 -5.309 0.0000E+00 troilite-low 176 -8.614 0.0000E+00 clinohumite 48 32.706 0.0000E+00 tschermakite 177 -5.239 0.0000E+00 coesite 49 -1.055 0.0000E+00 vesuvianite 178 33.627 0.0000E+00 cordierite-H 50 -16.686 0.0000E+00 wadeite-Si 179 14.818 0.0000E+00 cordierite-Fe 51 -19.381 0.0000E+00 wadsleyite-Fe 180 3.461 0.0000E+00 cordierite-Mn 52 -15.030 0.0000E+00 wadsleyite-Mg 181 8.956 0.0000E+00 corundum 53 -8.144 0.0000E+00 wairakite 182 -9.037 0.0000E+00 corundum-MgSi 54 7.373 0.0000E+00 walstromite 183 4.687 0.0000E+00 cristobalite 55 -1.303 0.0000E+00 wollastonite 184 4.256 0.0000E+00 cummingtonite 56 15.475 0.0000E+00 pseudo-wollastonite 185 4.377 0.0000E+00 cuprite 57 3.462 0.0000E+00 zoisite 186 -7.682 0.0000E+00 cymrite-K 58 -2.332 0.0000E+00 Ag2O 187 9.221 0.0000E+00 deerite 59 13.014 0.0000E+00 argentite 188 -14.308 0.0000E+00 diaspore 60 -3.585 0.0000E+00 beidellite-Ca 189 -12.965 0.0000E+00 diamond 61 -1.897 0.0000E+00 beidellite-H 190 -13.009 0.0000E+00 diopside 62 5.592 0.0000E+00 beidellite-K 191 -11.967 0.0000E+00 hedenbergite 63 4.124 0.0000E+00 beidellite-Mg 192 -13.209 0.0000E+00 dolomite,ordered 64 -10.750 0.0000E+00 beidellite-Na 193 -11.909 0.0000E+00 eastonite 65 -3.996 0.0000E+00 bornite 194 -55.774 0.0000E+00 enstatite 66 5.038 0.0000E+00 calcium 195 39.005 0.0000E+00 clinoenstatite-HiP 67 5.542 0.0000E+00 chalcocite 196 -14.648 0.0000E+00 clinoenstatite 68 5.019 0.0000E+00 covellite 197 -13.059 0.0000E+00 protoenstatite 69 5.174 0.0000E+00 dawsonite 198 -2.746 0.0000E+00 epidote 70 -3.154 0.0000E+00 montmorillonite-Ca 199 -9.801 0.0000E+00 clinozoisite 71 -7.632 0.0000E+00 montmorillonite-K 200 -9.079 0.0000E+00 epidote-Fe 72 3.029 0.0000E+00 montmorillonite-Mg 201 -10.008 0.0000E+00 fayalite 73 2.599 0.0000E+00 montmorillonite-Na 202 -8.750 0.0000E+00 ferrosilite 74 1.349 0.0000E+00 nontronite-Ca 203 -3.428 0.0000E+00 forsterite 75 6.708 0.0000E+00 nontronite-H 204 -3.479 0.0000E+00 gedrite 76 -6.516 0.0000E+00 nontronite-K 205 -2.432 0.0000E+00 gehlenite 77 3.154 0.0000E+00 nontronite-Mg 206 -3.639 0.0000E+00 gibbsite 78 -1.951 0.0000E+00 nontronite-Na 207 -2.371 0.0000E+00 glaucophane 79 2.226 0.0000E+00 sepiolite 208 15.924 0.0000E+00 glaucophane-Fe 80 -1.965 0.0000E+00 alite 209 24.594 0.0000E+00 goethite 81 1.337 0.0000E+00 belite 210 12.623 0.0000E+00 graphite 82 -2.215 0.0000E+00 ettringite 211 5.125 0.0000E+00 greenalite 83 4.931 0.0000E+00 gypsum 212 -12.769 0.0000E+00 grunerite 84 2.923 0.0000E+00 hemicarboaluminate 213 28.923 0.0000E+00 halite 85 -1.420 0.0000E+00 hydrogarnet 214 21.736 0.0000E+00 hematite 86 1.124 0.0000E+00 hydrogarnet-Si 215 15.662 0.0000E+00 heulandite 87 -11.684 0.0000E+00 jennite 216 14.365 0.0000E+00 hercynite 88 -6.194 0.0000E+00 monosulfoaluminate 217 9.268 0.0000E+00 hollandite 89 9.076 0.0000E+00 monocarboaluminate 218 22.293 0.0000E+00 iron 90 9.095 0.0000E+00 portlandite 219 9.016 0.0000E+00 jadeite 91 -1.184 0.0000E+00 stratlingite 220 11.260 0.0000E+00 julgoldite 92 23.300 0.0000E+00 tricarboaluminate 221 39.142 0.0000E+00 kalsilite 93 -0.329 0.0000E+00 tobermorite 222 7.293 0.0000E+00 kaolinite 94 -8.839 0.0000E+00 C4AH13 223 38.114 0.0000E+00 kyanite 95 -9.510 0.0000E+00 C2AH8 224 17.007 0.0000E+00 larnite-bredigite 96 12.820 0.0000E+00 C3A 225 25.160 0.0000E+00 laumontite 97 -7.156 0.0000E+00 C4AF 226 34.059 0.0000E+00 lawsonite 98 -4.559 0.0000E+00 CAH10 227 10.328 0.0000E+00 leucite 99 -2.345 0.0000E+00 acanthite 228 -14.390 0.0000E+00 lime 100 11.363 0.0000E+00 alabandite 229 -6.430 0.0000E+00 lizardite 101 10.127 0.0000E+00 alunite 230 -38.655 0.0000E+00 magnesite 102 -5.517 0.0000E+00 anglesite 231 -15.354 0.0000E+00 magnetite 103 2.546 0.0000E+00 artinite 232 5.574 0.0000E+00 minnesotaite 104 0.971 0.0000E+00 azurite 233 -2.909 0.0000E+00 minnesotaite-Mg 105 7.114 0.0000E+00 barite 234 -16.280 0.4845E-04 magnesioferrite 106 5.693 0.0000E+00 boehmite 235 -3.283 0.0000E+00 majorite 107 18.904 0.0000E+00 cerussite 236 -5.804 0.0000E+00 manganosite 108 5.616 0.0000E+00 chalcopyrite 237 -23.835 0.3105E-03 margarite 109 -15.022 0.0000E+00 chlorargyrite 238 -6.171 0.0000E+00 meionite 110 -25.812 0.0000E+00 copper,native 239 1.698 0.0000E+00 merwinite 111 21.873 0.0000E+00 dolomite,disordered 240 -10.806 0.0000E+00 microcline 112 -4.683 0.6832E-03 ferrous-oxide 241 2.335 0.0000E+00 monticellite 113 9.132 0.0000E+00 galena 242 -10.021 0.1763E-04 mullite-Al 114 138.304 0.0000E+00 silver,native 243 0.399 0.0000E+00 mullite-Si 115 -8.907 0.0000E+00 huntite 244 -21.394 0.0000E+00 muscovite 116 -12.708 0.0000E+00 litharge 245 5.406 0.0000E+00 paragonite 117 -12.021 0.0000E+00 hydromagnesite 246 -10.378 0.0000E+00 nepheline 118 -0.008 0.0000E+00 malachite 247 0.081 0.0000E+00 osumilite(2) 119 -12.028 0.0000E+00 nesquehonite 248 2.463 0.0000E+00 osumilite-Fe 120 -26.346 0.0000E+00 potassium-oxide 249 36.476 0.0000E+00 pargasite 121 7.630 0.0000E+00 smithsonite 250 -6.148 0.0000E+00 periclase 122 5.911 0.0000E+00 sodium-oxide 251 30.007 0.0000E+00 periclase-Fe 123 3.272 0.0000E+00 sphalerite 252 -11.013 0.1598E-02 perovskite-Al 124 -6.384 0.0000E+00 wurtzite 253 -10.197 0.0000E+00 perovskite-Ca 125 10.460 0.0000E+00 zincite 254 2.405 0.0000E+00 perovskite-Fe 126 7.815 0.0000E+00 an20ab80 255 -4.934 0.0000E+00 perovskite-Mg 127 9.203 0.0000E+00 an25ab75 256 -5.124 0.0000E+00 phase_A 128 31.592 0.0000E+00 an30ab70 257 -5.307 0.0000E+00 phlogopite-Na 129 6.945 0.0000E+00 tr.625ac.25prg.125 258 10.625 0.0000E+00 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 CO,gas 6 SO3,gas 6 HCl,gas 6 almandine 16 pyrope 16 andradite 8 grossular 8 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 silver,native 10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 43 Loop limit = 500 Temperature = 554.00 C Pressure = 989.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5513E+02 kg liquid = 0.9933E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9969 Stoichiometric ionic strength = .3272667E+01 Osmotic coef. = 0.0000 True ionic strength = .1434703E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.45249E-05 -5.3444 0.87556E-06 -6.0577 0.19350E+00 -0.7133 2 H2O 0.99690E+00 -0.0013 0.99690E+00 -0.0013 3 Cl- 0.12036E+00 -0.9195 0.19678E-01 -1.7060 0.16350E+00 -0.7865 4 SO4-- 0.28318E-03 -3.5479 0.48912E-06 -6.3106 0.17272E-02 -2.7627 5 HCO3- 0.81839E-05 -5.0870 0.14420E-05 -5.8410 0.17620E+00 -0.7540 6 HS- 0.11176E-03 -3.9517 0.18424E-04 -4.7346 0.16486E+00 -0.7829 7 H4SiO4 0.44270E-01 -1.3539 0.44270E-01 -1.3539 0.10000E+01 0.0000 8 Al+++ 0.47496E-16 -16.3233 0.22488E-22 -22.6481 0.47346E-06 -6.3247 9 Ca++ 0.13759E-05 -5.8614 0.18927E-08 -8.7229 0.13756E-02 -2.8615 10 Mg++ 0.21366E-05 -5.6703 0.24095E-08 -8.6181 0.11277E-02 -2.9478 11 Fe++ 0.14608E-07 -7.8354 0.17323E-10 -10.7614 0.11858E-02 -2.9260 12 K+ 0.34211E-01 -1.4658 0.61746E-02 -2.2094 0.18049E+00 -0.7436 13 Na+ 0.10756E+00 -0.9684 0.17775E-01 -1.7502 0.16526E+00 -0.7818 14 Mn++ 0.15535E-05 -5.8087 0.19112E-08 -8.7187 0.12302E-02 -2.9100 15 Zn++ 0.38861E-09 -9.4105 0.46083E-12 -12.3365 0.11858E-02 -2.9260 16 Cu+ 0.11876E-07 -7.9253 0.19574E-08 -8.7083 0.16482E+00 -0.7830 17 Pb++ 0.29337E-08 -8.5326 0.45323E-11 -11.3437 0.15449E-02 -2.8111 18 Ag+ 0.27309E-09 -9.5637 0.48506E-10 -10.3142 0.17762E+00 -0.7505 19 Ba++ 0.64558E-07 -7.1900 0.10736E-09 -9.9692 0.16629E-02 -2.7791 20 HPO4-- 0.17524E-08 -8.7564 0.30424E-11 -11.5168 0.17361E-02 -2.7604 21 HSiO3- 0.12616E-05 -5.8991 0.20628E-06 -6.6856 0.16350E+00 -0.7865 22 Ca(HSiO3)+ 0.38983E-08 -8.4091 0.70991E-09 -9.1488 0.18211E+00 -0.7397 23 Mg(HSiO3)+ 0.16465E-08 -8.7834 0.29985E-09 -9.5231 0.18211E+00 -0.7397 24 NaHSiO3,aq 0.18693E-05 -5.7283 0.18693E-05 -5.7283 0.10000E+01 0.0000 28 AgCl,aq 0.11525E-06 -6.9383 0.11525E-06 -6.9383 0.10000E+01 0.0000 29 AgCl2- 0.49907E-05 -5.3018 0.81596E-06 -6.0883 0.16350E+00 -0.7865 30 AgCl3-2 0.17084E-05 -5.7674 0.27263E-08 -8.5644 0.15958E-02 -2.7970 31 AgCl4-3 0.19365E-05 -5.7130 0.80540E-12 -12.0940 0.41591E-06 -6.3810 34 Ag(HS),aq 0.20930E-08 -8.6792 0.20930E-08 -8.6792 0.10000E+01 0.0000 35 Ag(HS)2- 0.67268E-08 -8.1722 0.10998E-08 -8.9587 0.16350E+00 -0.7865 36 AlO+ 0.11833E-10 -10.9269 0.21549E-11 -11.6666 0.18211E+00 -0.7397 38 HAlO2,aq 0.43381E-08 -8.3627 0.43381E-08 -8.3627 0.10000E+01 0.0000 39 AlO2- 0.10614E-04 -4.9741 0.15227E-05 -5.8174 0.14346E+00 -0.8433 41 Ba(HCO3)+ 0.16539E-06 -6.7815 0.31367E-07 -7.5035 0.18966E+00 -0.7220 42 BaCl+ 0.67411E-05 -5.1713 0.12276E-05 -5.9109 0.18211E+00 -0.7397 43 CH4,aq 0.13600E-08 -8.8665 0.16064E-08 -8.7941 0.11812E+01 0.0723 48 CO,aq 0.45288E-03 -3.3440 0.45288E-03 -3.3440 0.10000E+01 0.0000 49 CO2,aq 0.26737E+01 0.4271 0.31582E+01 0.4994 0.11812E+01 0.0723 50 CO3-2 0.39321E-10 -10.4054 0.62751E-13 -13.2024 0.15958E-02 -2.7970 52 Ca(HCO3)+ 0.78231E-07 -7.1066 0.14246E-07 -7.8463 0.18211E+00 -0.7397 53 CaCl+ 0.64355E-04 -4.1914 0.11720E-04 -4.9311 0.18211E+00 -0.7397 54 CaCl2,aq 0.69275E-04 -4.1594 0.69275E-04 -4.1594 0.10000E+01 0.0000 55 CaOH+ 0.11903E-06 -6.9244 0.21676E-07 -7.6640 0.18211E+00 -0.7397 56 CaSO4,aq 0.18263E-06 -6.7384 0.18263E-06 -6.7384 0.10000E+01 0.0000 57 HCl,aq 0.38212E-02 -2.4178 0.38212E-02 -2.4178 0.10000E+01 0.0000 66 CuCl,aq 0.20414E-04 -4.6901 0.20414E-04 -4.6901 0.10000E+01 0.0000 67 CuCl2- 0.67976E-04 -4.1676 0.11114E-04 -4.9541 0.16350E+00 -0.7865 68 CuCl3-2 0.12912E-05 -5.8890 0.20606E-08 -8.6860 0.15958E-02 -2.7970 74 FeCl+ 0.21237E-06 -6.6729 0.38674E-07 -7.4126 0.18211E+00 -0.7397 75 FeCl2,aq 0.23025E-02 -2.6378 0.23025E-02 -2.6378 0.10000E+01 0.0000 77 FeO,aq 0.48265E-07 -7.3164 0.48265E-07 -7.3164 0.10000E+01 0.0000 78 FeOH+ 0.17409E-07 -7.7592 0.31703E-08 -8.4989 0.18211E+00 -0.7397 79 HFeO2- 0.51111E-08 -8.2915 0.83566E-09 -9.0780 0.16350E+00 -0.7865 82 FeO2- 0.32233E-08 -8.4917 0.52701E-09 -9.2782 0.16350E+00 -0.7865 83 HFeO2,aq 0.26495E-09 -9.5768 0.26495E-09 -9.5768 0.10000E+01 0.0000 84 H2,aq 0.42403E-02 -2.3726 0.50088E-02 -2.3003 0.11812E+01 0.0723 85 KCl,aq 0.72903E-01 -1.1373 0.72903E-01 -1.1373 0.10000E+01 0.0000 86 KHSO4,aq 0.13516E-01 -1.8692 0.13516E-01 -1.8692 0.10000E+01 0.0000 87 KOH,aq 0.13695E-05 -5.8635 0.13695E-05 -5.8635 0.10000E+01 0.0000 88 KSO4- 0.49411E-02 -2.3062 0.80787E-03 -3.0927 0.16350E+00 -0.7865 90 Mg(HCO3)+ 0.32823E-07 -7.4838 0.59774E-08 -8.2235 0.18211E+00 -0.7397 91 MgCl+ 0.17989E-04 -4.7450 0.32759E-05 -5.4847 0.18211E+00 -0.7397 92 MgOH+ 0.65697E-06 -6.1825 0.11964E-06 -6.9221 0.18211E+00 -0.7397 94 MnO,aq 0.92997E-07 -7.0315 0.92997E-07 -7.0315 0.10000E+01 0.0000 95 MnOH+ 0.20783E-06 -6.6823 0.37847E-07 -7.4220 0.18211E+00 -0.7397 97 HMnO2- 0.38068E-10 -10.4194 0.62240E-11 -11.2059 0.16350E+00 -0.7865 100 MnCl+ 0.11552E-02 -2.9373 0.21038E-03 -3.6770 0.18211E+00 -0.7397 101 MnSO4,aq 0.19519E-06 -6.7095 0.19519E-06 -6.7095 0.10000E+01 0.0000 102 NaCl,aq 0.45080E+00 -0.3460 0.45080E+00 -0.3460 0.10000E+01 0.0000 103 NaOH,aq 0.17982E-05 -5.7452 0.17982E-05 -5.7452 0.10000E+01 0.0000 105 OH- 0.69314E-05 -5.1592 0.99439E-06 -6.0024 0.14346E+00 -0.8433 110 HPO3-2 0.10213E-10 -10.9908 0.16299E-13 -13.7878 0.15958E-02 -2.7970 111 H3PO3,aq 0.12513E-09 -9.9026 0.12513E-09 -9.9026 0.10000E+01 0.0000 112 H2PO3- 0.17165E-08 -8.7654 0.28065E-09 -9.5518 0.16350E+00 -0.7865 113 H3PO4,aq 0.16803E-05 -5.7746 0.16803E-05 -5.7746 0.10000E+01 0.0000 114 H2PO4- 0.15065E-05 -5.8220 0.25900E-06 -6.5867 0.17192E+00 -0.7647 116 H4P2O7,aq 0.26161E-09 -9.5823 0.26161E-09 -9.5823 0.10000E+01 0.0000 117 H3P2O7- 0.10725E-08 -8.9696 0.17536E-09 -9.7561 0.16350E+00 -0.7865 118 H2P2O7-2 0.26667E-06 -6.5740 0.42557E-09 -9.3710 0.15958E-02 -2.7970 119 HP2O7-3 0.39521E-07 -7.4032 0.16437E-13 -13.7842 0.41591E-06 -6.3810 121 PbCl+ 0.10985E-05 -5.9592 0.20005E-06 -6.6989 0.18211E+00 -0.7397 122 PbCl2,aq 0.82028E-04 -4.0860 0.82028E-04 -4.0860 0.10000E+01 0.0000 123 PbCl3- 0.93166E-04 -4.0307 0.15233E-04 -4.8172 0.16350E+00 -0.7865 124 PbCl4-2 0.16276E-04 -4.7885 0.25974E-07 -7.5855 0.15958E-02 -2.7970 125 PbO,aq 0.63180E-08 -8.1994 0.63180E-08 -8.1994 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11905E-03 -3.9243 0.11905E-03 -3.9243 0.10000E+01 0.0000 128 Pb(HS)3- 0.13078E-04 -4.8835 0.21382E-05 -5.6700 0.16350E+00 -0.7865 129 H2S,aq 0.10591E+01 0.0250 0.12511E+01 0.0973 0.11812E+01 0.0723 130 S2-2 0.12543E-07 -7.9016 0.20017E-10 -10.6986 0.15958E-02 -2.7970 131 S3-2 0.11841E-08 -8.9266 0.18896E-11 -11.7236 0.15958E-02 -2.7970 132 S3- 0.87333E-02 -2.0588 0.14279E-02 -2.8453 0.16350E+00 -0.7865 133 S4-2 0.95308E-10 -10.0209 0.15210E-12 -12.8179 0.15958E-02 -2.7970 135 SO2,aq 0.29370E+00 -0.5321 0.29370E+00 -0.5321 0.10000E+01 0.0000 136 SO3-2 0.70278E-09 -9.1532 0.18038E-11 -11.7438 0.25666E-02 -2.5906 137 HSO3- 0.22400E-03 -3.6497 0.36624E-04 -4.4362 0.16350E+00 -0.7865 138 HSO4- 0.79332E-02 -2.1006 0.14858E-02 -2.8280 0.18729E+00 -0.7275 140 S2O3-2 0.56912E-06 -6.2448 0.90823E-09 -9.0418 0.15958E-02 -2.7970 141 HS2O3- 0.35148E-06 -6.4541 0.57466E-07 -7.2406 0.16350E+00 -0.7865 142 H2S2O3,aq 0.38874E-07 -7.4103 0.38874E-07 -7.4103 0.10000E+01 0.0000 150 S4O6-2 0.49109E-09 -9.3088 0.78370E-12 -12.1059 0.15958E-02 -2.7970 152 ZnCl+ 0.12513E-03 -3.9026 0.22787E-04 -4.6423 0.18211E+00 -0.7397 153 ZnCl2,aq 0.54512E-03 -3.2635 0.54512E-03 -3.2635 0.10000E+01 0.0000 154 ZnCl3- 0.34683E-04 -4.4599 0.56706E-05 -5.2464 0.16350E+00 -0.7865 155 ZnO,aq 0.25021E-07 -7.6017 0.25021E-07 -7.6017 0.10000E+01 0.0000 156 ZnOH+ 0.87297E-06 -6.0590 0.15897E-06 -6.7987 0.18211E+00 -0.7397 158 HZnO2- 0.17325E-09 -9.7613 0.28326E-10 -10.5478 0.16350E+00 -0.7865 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4524859E-05 0.4294385E+01 0.3543196E+04 -0.0000 2 H2O 0.1000000E+01 0.5252287E+02 0.7745499E+06 0.0000 3 Cl- 0.1203559E+00 0.6558799E+00 0.1903429E+05 4.3517 4 SO4-- 0.2831841E-03 0.2514017E+00 0.1976868E+05 5.8048 5 HCO3- 0.8183883E-05 0.2674131E+01 0.1335655E+06 0.2167 6 HS- 0.1117591E-03 0.1154932E+01 0.3126629E+05 1.3231 7 H4SiO4 0.4426950E-01 0.4427264E-01 0.3483276E+04 -1.3539 8 Al+++ 0.4749604E-16 0.1061802E-04 0.2345143E+00 -4.4749 9 Ca++ 0.1375927E-05 0.1353891E-03 0.4441699E+01 3.3925 10 Mg++ 0.2136622E-05 0.2081691E-04 0.4142824E+00 3.4974 11 Fe++ 0.1460808E-07 0.2302805E-02 0.1052729E+03 1.3540 12 K+ 0.3421073E-01 0.1255722E+00 0.4019315E+04 3.8483 13 Na+ 0.1075587E+00 0.5583615E+00 0.1050776E+05 4.3075 14 Mn++ 0.1553480E-05 0.1157298E-02 0.5204481E+02 3.3967 15 Zn++ 0.3886093E-09 0.7058265E-03 0.3776904E+02 -0.2210 16 Cu+ 0.1187621E-07 0.8969256E-04 0.4665123E+01 -2.6506 17 Pb++ 0.2933702E-08 0.3247085E-03 0.5507086E+02 0.7718 18 Ag+ 0.2730945E-09 0.8759865E-05 0.7734951E+00 -4.2565 19 Ba++ 0.6455804E-07 0.6970997E-05 0.7837028E+00 2.1463 20 HPO4-- 0.1752382E-08 0.3805408E-05 0.2989764E+00 0.5986 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265450E+01 -.3087742E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5216897E+02 -.2041946E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2497078E+00 0.2014953E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1147150E+01 0.1299379E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4397434E-01 0.9961999E-01 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1054648E-04 0.6839930E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1344768E-03 0.3934331E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2287289E-02 0.6479465E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247261E+00 0.6839930E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7010708E-03 0.1598264E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.8908823E-04 0.3105215E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3225206E-03 0.1765203E-04 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.6924027E-05 0.4844842E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3779768E-05 0.4787732E-05 0.0000000E+00 Chg. balance for solid moles: 0.1084E-17 Mass of aqueous solution: 0.121340E+04 g Temperature = 554.00 C Pressure = 989.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3855E-03 -3.414 0.5248E-01 -1.280 0.7418 0.1771E-01 apatite-OH 0.1596E-05 -5.797 0.8017E-03 -3.096 0.1133E-01 0.2547E-03 microcline 0.6840E-03 -3.165 0.1904 -0.720 2.691 0.7437E-01 pyrite 0.6169E-02 -2.210 0.7401 -0.131 10.46 0.1477 quartz 0.9757E-01 -1.011 5.862 0.768 82.87 2.214 barite 0.4845E-04 -4.315 0.1131E-01 -1.947 0.1599 0.2524E-02 chalcopyrite 0.3105E-03 -3.508 0.5698E-01 -1.244 0.8055 0.1330E-01 galena 0.1765E-04 -4.753 0.4223E-02 -2.374 0.5970E-01 0.5558E-03 sphalerite 0.1598E-02 -2.796 0.1557 -0.808 2.201 0.3808E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.073926 g Volume = 2.508175 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.03 -15.03 0.00 0.000 0.00000E+00 27 apatite-OH -53.94 -53.94 0.00 0.000 -0.53787E-10 112 microcline -4.68 -4.68 0.00 0.000 -0.13447E-10 137 pyrite -22.14 -22.14 0.00 0.000 -0.13447E-10 141 quartz -1.35 -1.35 0.00 0.000 0.00000E+00 234 barite -16.28 -16.28 0.00 0.000 0.00000E+00 237 chalcopyrite -23.83 -23.83 0.00 0.000 -0.13447E-10 242 galena -10.02 -10.02 0.00 0.000 0.00000E+00 252 sphalerite -11.01 -11.01 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 -0.00 -0.26 -0.259 0.97944E+03 2.736 2 CO2,gas -10.19 -11.90 -1.71 -0.569 0.64628E+04 1.288 3 CH4,gas 6.82 -4.27 -11.08 -2.771 0.41950E+05 -8.088 4 H2,gas 6.00 1.91 -4.09 -2.337 0.15481E+05 -1.095 5 H2S,gas -8.49 -10.79 -2.30 -1.151 0.87158E+04 0.692 6 CO,gas -3.90 -9.99 -6.09 -1.873 0.23034E+05 -3.091 7 SO3,gas -7.70 -18.42 -10.73 -2.682 0.40600E+05 -7.732 8 O2,gas 14.03 -3.82 -17.84 -11.896 0.67536E+05 -14.848 9 HCl,gas -3.19 -7.76 -4.57 -2.285 0.17299E+05 -4.571 10 acmite 3.61 2.00 -1.60 -0.166 0.60637E+04 12 akimotoite 6.34 2.14 -4.19 -0.838 0.15861E+05 13 akimotoite-Fe 4.18 0.00 -4.18 -0.835 0.15806E+05 14 albite-high -4.06 -4.22 -0.16 -0.012 0.61012E+03 15 albite -4.07 -4.22 -0.16 -0.012 0.59650E+03 16 almandine -6.68 -8.95 -2.27 -0.114 0.85951E+04 17 pyrope 0.16 -2.52 -2.68 -0.134 0.10156E+05 18 analcite -1.87 -2.87 -1.01 -0.112 0.38053E+04 19 andalusite -9.68 -10.31 -0.63 -0.063 0.23802E+04 24 anorthite -7.32 -8.27 -0.94 -0.073 0.35756E+04 25 anthophyllite 15.40 13.66 -1.74 -0.047 0.65975E+04 26 anthophyllite-Fe 2.35 -1.34 -3.69 -0.100 0.13977E+05 28 apatite-OH-zs -51.72 -53.94 -2.21 -0.170 0.83694E+04 29 apatite-Cl-zs -58.42 -61.70 -3.28 -0.273 0.12406E+05 30 aragonite -4.74 -8.51 -3.77 -1.255 0.14251E+05 31 brucite 5.70 3.49 -2.20 -0.440 0.83303E+04 32 calcite -4.85 -8.51 -3.66 -1.219 0.13840E+05 33 carnegieite-low 0.30 -1.52 -1.82 -0.260 0.68779E+04 34 carnegieite-high 0.38 -1.52 -1.90 -0.272 0.72100E+04 35 carpholite-Mg -6.12 -8.16 -2.04 -0.136 0.77362E+04 36 carpholite-Fe -7.52 -10.31 -2.79 -0.186 0.10550E+05 37 celadonite -0.50 -2.54 -2.04 -0.120 0.77338E+04 38 celadonite-Fe -1.94 -4.68 -2.74 -0.161 0.10379E+05 39 chrysotile 9.97 7.78 -2.18 -0.182 0.82608E+04 40 chondrodite 19.76 14.78 -4.98 -0.262 0.18867E+05 41 clinochlore 5.54 4.47 -1.08 -0.034 0.40709E+04 42 daphnite -1.75 -6.25 -4.50 -0.141 0.17018E+05 44 chlorite-Al-free 20.10 15.57 -4.53 -0.189 0.17145E+05 45 chloritoid-Mg -5.44 -6.81 -1.37 -0.091 0.51794E+04 46 chloritoid-Fe -7.45 -8.95 -1.50 -0.100 0.56899E+04 47 chloritoid-Mn -5.31 -6.91 -1.60 -0.107 0.60651E+04 49 coesite -1.05 -1.35 -0.30 -0.099 0.11219E+04 50 cordierite-H -16.69 -17.67 -0.99 -0.035 0.37369E+04 51 cordierite-Fe -19.38 -21.96 -2.58 -0.089 0.97531E+04 52 cordierite-Mn -15.03 -17.87 -2.84 -0.098 0.10761E+05 53 corundum -8.14 -8.95 -0.81 -0.074 0.30637E+04 55 cristobalite -1.30 -1.35 -0.05 -0.016 0.18146E+03 56 cummingtonite 15.47 13.66 -1.81 -0.049 0.68641E+04 58 cymrite-K -2.33 -4.68 -2.35 -0.196 0.89016E+04 60 diaspore -3.59 -4.48 -0.89 -0.149 0.33784E+04 62 diopside 5.59 4.18 -1.41 -0.141 0.53269E+04 63 hedenbergite 4.12 2.04 -2.08 -0.208 0.78804E+04 65 eastonite -4.00 -5.29 -1.30 -0.050 0.49156E+04 66 enstatite 5.04 4.29 -0.75 -0.075 0.28310E+04 67 clinoenstatite-HiP 5.54 4.29 -1.25 -0.125 0.47411E+04 68 clinoenstatite 5.02 4.29 -0.73 -0.073 0.27619E+04 69 protoenstatite 5.17 4.29 -0.88 -0.088 0.33456E+04 70 epidote -3.15 -5.83 -2.67 -0.130 0.10118E+05 71 clinozoisite -7.63 -10.70 -3.07 -0.140 0.11620E+05 72 epidote-Fe 3.03 -0.95 -3.98 -0.207 0.15067E+05 73 fayalite 2.60 1.35 -1.24 -0.178 0.47108E+04 74 ferrosilite 1.35 0.00 -1.35 -0.135 0.50932E+04 75 forsterite 6.71 5.64 -1.07 -0.152 0.40397E+04 76 gedrite -6.52 -8.54 -2.02 -0.055 0.76456E+04 78 gibbsite -1.95 -4.48 -2.53 -0.361 0.95692E+04 79 glaucophane 2.23 -0.66 -2.89 -0.078 0.10933E+05 81 goethite 1.34 0.40 -0.94 -0.203 0.35537E+04 83 greenalite 4.93 1.35 -3.58 -0.298 0.13542E+05 84 grunerite 2.92 -1.34 -4.27 -0.115 0.16144E+05 85 halite -1.42 -3.46 -2.04 -1.018 0.77077E+04 86 hematite 1.12 0.80 -0.33 -0.040 0.12395E+04 87 heulandite -11.68 -15.03 -3.35 -0.152 0.12661E+05 88 hercynite -6.19 -7.60 -1.41 -0.094 0.53269E+04 91 jadeite -1.18 -2.87 -1.69 -0.169 0.63905E+04 93 kalsilite -0.33 -1.98 -1.65 -0.236 0.62520E+04 94 kaolinite -8.84 -11.66 -2.82 -0.256 0.10674E+05 95 kyanite -9.51 -10.31 -0.79 -0.079 0.30086E+04 97 laumontite -7.16 -10.97 -3.82 -0.254 0.14445E+05 98 lawsonite -4.56 -8.27 -3.71 -0.247 0.14037E+05 99 leucite -2.34 -3.33 -0.99 -0.099 0.37351E+04 101 lizardite 10.13 7.78 -2.34 -0.195 0.88712E+04 102 magnesite -5.52 -8.40 -2.88 -0.961 0.10915E+05 103 magnetite 2.55 2.15 -0.40 -0.032 0.15013E+04 104 minnesotaite 0.97 -1.35 -2.32 -0.136 0.87792E+04 105 minnesotaite-Mg 7.11 5.08 -2.03 -0.120 0.76898E+04 106 magnesioferrite 5.69 4.29 -1.40 -0.114 0.52988E+04 108 manganosite 5.62 3.40 -2.22 -0.555 0.84050E+04 109 margarite -15.02 -17.22 -2.20 -0.088 0.83211E+04 113 monticellite 9.13 5.54 -3.60 -0.514 0.13609E+05 115 mullite-Si -8.91 -10.31 -1.40 -0.140 0.52908E+04 116 muscovite -12.71 -13.64 -0.93 -0.055 0.35189E+04 117 paragonite -12.02 -13.18 -1.16 -0.068 0.43814E+04 118 nepheline -0.01 -1.52 -1.51 -0.216 0.57261E+04 119 osumilite(2) -12.03 -13.96 -1.93 -0.040 0.73050E+04 120 osumilite-Fe -26.35 -29.34 -3.00 -0.062 0.11345E+05 121 pargasite 7.63 3.53 -4.10 -0.108 0.15502E+05 122 periclase 5.91 3.50 -2.41 -0.604 0.91395E+04 123 periclase-Fe 3.27 1.35 -1.92 -0.480 0.72625E+04 124 perovskite-Al -6.38 -8.95 -2.57 -0.234 0.97266E+04 129 phlogopite-Na 6.95 6.26 -0.68 -0.038 0.25814E+04 131 prehnite -2.58 -6.23 -3.65 -0.215 0.13807E+05 132 prehnite-Fe 2.30 -1.35 -3.65 -0.219 0.13810E+05 135 px-Mg-tschermaks -4.79 -6.81 -2.02 -0.144 0.76473E+04 136 px-Ca-tschermaks -4.05 -6.91 -2.86 -0.205 0.10837E+05 138 pyrrhotite -8.70 -9.44 -0.73 -0.245 0.27816E+04 139 pyrrhotiteFe0.875 -9.51 -9.84 -0.33 -0.123 0.12652E+04 140 pyrophyllite -12.87 -14.36 -1.49 -0.093 0.56371E+04 143 riebeckite 5.89 2.66 -3.23 -0.089 0.12243E+05 144 ringwoodite-Fe 3.60 1.35 -2.25 -0.321 0.85154E+04 145 ringwoodite-Mg 9.91 5.64 -4.27 -0.610 0.16150E+05 146 rhodochrosite -5.55 -8.50 -2.95 -0.985 0.11182E+05 147 rhodonite 2.62 2.04 -0.57 -0.114 0.21662E+04 148 sanidine -4.14 -4.68 -0.55 -0.042 0.20678E+04 150 siderite -7.41 -10.54 -3.13 -1.044 0.11856E+05 151 sillimanite -9.64 -10.31 -0.67 -0.067 0.25326E+04 153 spinel -3.97 -5.46 -1.49 -0.099 0.56416E+04 160 stilpnomelane-Mg 1.46 -0.37 -1.83 -0.054 0.69088E+04 161 stishovite 1.65 -1.35 -3.00 -0.999 0.11347E+05 162 sudoite-Fe -14.51 -19.26 -4.75 -0.153 0.17973E+05 163 sudoite -12.21 -14.97 -2.77 -0.089 0.10466E+05 164 sulfur -11.22 -12.70 -1.48 -0.455 0.55998E+04 165 sylvite -1.32 -3.92 -2.59 -1.296 0.98089E+04 166 talc 5.36 5.08 -0.28 -0.017 0.10620E+04 167 talc-Fe 2.40 -1.35 -3.75 -0.221 0.14188E+05 168 talc-tschermaks -4.39 -6.02 -1.63 -0.096 0.61710E+04 170 tephroite 6.85 5.44 -1.41 -0.201 0.53372E+04 173 topaz-H -7.58 -10.31 -2.72 -0.248 0.10309E+05 174 tremolite 15.90 13.45 -2.45 -0.066 0.92618E+04 176 troilite-low -8.61 -9.44 -0.82 -0.275 0.31187E+04 177 tschermakite -5.24 -8.75 -3.51 -0.095 0.13273E+05 180 wadsleyite-Fe 3.46 1.35 -2.11 -0.301 0.79740E+04 181 wadsleyite-Mg 8.96 5.64 -3.31 -0.474 0.12546E+05 182 wairakite -9.04 -10.97 -1.93 -0.114 0.73156E+04 183 walstromite 4.69 2.04 -2.65 -0.529 0.10019E+05 184 wollastonite 4.26 2.04 -2.22 -0.443 0.83889E+04 185 pseudo-wollastonite 4.38 2.04 -2.34 -0.467 0.88451E+04 186 zoisite -7.68 -10.70 -3.02 -0.137 0.11434E+05 188 argentite -14.31 -19.31 -5.00 -1.249 0.18915E+05 189 beidellite-Ca -12.97 -14.83 -1.87 -0.115 0.70645E+04 190 beidellite-H -13.01 -15.39 -2.38 -0.152 0.90186E+04 191 beidellite-K -11.97 -14.12 -2.15 -0.132 0.81559E+04 192 beidellite-Mg -13.21 -14.81 -1.61 -0.099 0.60781E+04 193 beidellite-Na -11.91 -13.97 -2.06 -0.126 0.77999E+04 194 bornite -55.77 -56.02 -0.25 -0.019 0.93769E+03 196 chalcocite -14.65 -16.09 -1.45 -0.361 0.54695E+04 197 covellite -13.06 -14.40 -1.34 -0.509 0.50606E+04 199 montmorillonite-Ca -9.80 -11.17 -1.37 -0.085 0.51809E+04 200 montmorillonite-K -9.08 -10.46 -1.38 -0.085 0.52238E+04 201 montmorillonite-Mg -10.01 -11.15 -1.14 -0.071 0.43317E+04 202 montmorillonite-Na -8.75 -10.31 -1.56 -0.095 0.58974E+04 203 nontronite-Ca -3.43 -5.08 -1.65 -0.107 0.62564E+04 204 nontronite-H -3.48 -5.64 -2.16 -0.145 0.81823E+04 205 nontronite-K -2.43 -4.37 -1.94 -0.124 0.73400E+04 206 nontronite-Mg -3.64 -5.06 -1.42 -0.092 0.53922E+04 207 nontronite-Na -2.37 -4.22 -1.85 -0.119 0.69958E+04 212 gypsum -12.77 -15.04 -2.27 -0.567 0.85822E+04 228 acanthite -14.39 -19.31 -4.91 -1.229 0.18603E+05 229 alabandite -6.43 -7.40 -0.97 -0.322 0.36557E+04 231 anglesite -15.35 -17.65 -2.30 -1.150 0.87078E+04 235 boehmite -3.28 -4.48 -1.19 -0.199 0.45200E+04 239 copper,native 1.70 -1.70 -3.39 -1.181 0.12849E+05 241 ferrous-oxide 2.33 1.35 -0.98 -0.246 0.37169E+04 243 silver,native 0.40 -3.30 -3.70 -1.288 0.14012E+05 245 litharge 5.41 0.77 -4.64 -1.159 0.17544E+05 253 wurtzite -10.20 -11.01 -0.82 -0.272 0.30906E+04 254 zincite 2.41 -0.22 -2.63 -0.657 0.99453E+04 255 an20ab80 -4.93 -5.03 -0.10 -0.007 0.36895E+03 256 an25ab75 -5.12 -5.23 -0.11 -0.008 0.41727E+03 257 an30ab70 -5.31 -5.44 -0.13 -0.010 0.48704E+03 258 tr.625ac.25prg.125 10.62 9.53 -1.09 -0.029 0.41343E+04 Calculations done for 554.0000 Deg. C; 989.0000 bar Temperature changed by -1.000 degrees to 553.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 42 Loop limit = 500 Temperature = 553.00 C Pressure = 978.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5514E+02 kg liquid = 0.9933E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9969 Stoichiometric ionic strength = .3272427E+01 Osmotic coef. = 0.0000 True ionic strength = .1468394E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.46626E-05 -5.3314 0.86254E-06 -6.0642 0.18499E+00 -0.7328 2 H2O 0.99691E+00 -0.0013 0.99691E+00 -0.0013 3 Cl- 0.12337E+00 -0.9088 0.19154E-01 -1.7177 0.15525E+00 -0.8090 4 SO4-- 0.32631E-03 -3.4864 0.46898E-06 -6.3288 0.14372E-02 -2.8425 5 HCO3- 0.81665E-05 -5.0880 0.13698E-05 -5.8633 0.16774E+00 -0.7754 6 HS- 0.11417E-03 -3.9425 0.17877E-04 -4.7477 0.15659E+00 -0.8052 7 H4SiO4 0.43479E-01 -1.3617 0.43479E-01 -1.3617 0.10000E+01 0.0000 8 Al+++ 0.79453E-16 -16.0999 0.24555E-22 -22.6099 0.30905E-06 -6.5100 9 Ca++ 0.16518E-05 -5.7820 0.18757E-08 -8.7268 0.11356E-02 -2.9448 10 Mg++ 0.24498E-05 -5.6109 0.22653E-08 -8.6449 0.92467E-03 -3.0340 11 Fe++ 0.17818E-07 -7.7492 0.17354E-10 -10.7606 0.97398E-03 -3.0115 12 K+ 0.34896E-01 -1.4572 0.60003E-02 -2.2218 0.17195E+00 -0.7646 13 Na+ 0.11019E+00 -0.9579 0.17296E-01 -1.7621 0.15697E+00 -0.8042 14 Mn++ 0.18420E-05 -5.7347 0.18636E-08 -8.7297 0.10117E-02 -2.9949 15 Zn++ 0.47608E-09 -9.3223 0.46369E-12 -12.3338 0.97398E-03 -3.0115 16 Cu+ 0.12181E-07 -7.9143 0.19067E-08 -8.7197 0.15653E+00 -0.8054 17 Pb++ 0.34623E-08 -8.4606 0.44330E-11 -11.3533 0.12804E-02 -2.8927 18 Ag+ 0.24863E-09 -9.6045 0.42049E-10 -10.3762 0.16912E+00 -0.7718 19 Ba++ 0.75587E-07 -7.1216 0.10444E-09 -9.9811 0.13817E-02 -2.8596 20 HPO4-- 0.20450E-08 -8.6893 0.29549E-11 -11.5295 0.14449E-02 -2.8402 21 HSiO3- 0.12836E-05 -5.8916 0.19928E-06 -6.7005 0.15525E+00 -0.8090 22 Ca(HSiO3)+ 0.40012E-08 -8.3978 0.69439E-09 -9.1584 0.17355E+00 -0.7606 23 Mg(HSiO3)+ 0.16168E-08 -8.7913 0.28060E-09 -9.5519 0.17355E+00 -0.7606 24 NaHSiO3,aq 0.18485E-05 -5.7332 0.18485E-05 -5.7332 0.10000E+01 0.0000 28 AgCl,aq 0.10247E-06 -6.9894 0.10247E-06 -6.9894 0.10000E+01 0.0000 29 AgCl2- 0.45346E-05 -5.3435 0.70400E-06 -6.1524 0.15525E+00 -0.8090 30 AgCl3-2 0.17088E-05 -5.7673 0.22630E-08 -8.6453 0.13244E-02 -2.8780 31 AgCl4-3 0.24056E-05 -5.6188 0.65067E-12 -12.1866 0.27048E-06 -6.5679 34 Ag(HS),aq 0.18790E-08 -8.7261 0.18790E-08 -8.7261 0.10000E+01 0.0000 35 Ag(HS)2- 0.60701E-08 -8.2168 0.94239E-09 -9.0258 0.15525E+00 -0.8090 36 AlO+ 0.12952E-10 -10.8877 0.22478E-11 -11.6482 0.17355E+00 -0.7606 38 HAlO2,aq 0.44305E-08 -8.3535 0.44305E-08 -8.3535 0.10000E+01 0.0000 39 AlO2- 0.11016E-04 -4.9580 0.14941E-05 -5.8256 0.13563E+00 -0.8676 41 Ba(HCO3)+ 0.16597E-06 -6.7800 0.30039E-07 -7.5223 0.18099E+00 -0.7423 42 BaCl+ 0.68658E-05 -5.1633 0.11915E-05 -5.9239 0.17355E+00 -0.7606 43 CH4,aq 0.13452E-08 -8.8712 0.15879E-08 -8.7992 0.11804E+01 0.0720 48 CO,aq 0.44522E-03 -3.3514 0.44522E-03 -3.3514 0.10000E+01 0.0000 49 CO2,aq 0.26736E+01 0.4271 0.31559E+01 0.4991 0.11804E+01 0.0720 50 CO3-2 0.44708E-10 -10.3496 0.59209E-13 -13.2276 0.13244E-02 -2.8780 52 Ca(HCO3)+ 0.78448E-07 -7.1054 0.13615E-07 -7.8660 0.17355E+00 -0.7606 53 CaCl+ 0.66381E-04 -4.1780 0.11520E-04 -4.9385 0.17355E+00 -0.7606 54 CaCl2,aq 0.69220E-04 -4.1598 0.69220E-04 -4.1598 0.10000E+01 0.0000 55 CaOH+ 0.12178E-06 -6.9144 0.21135E-07 -7.6750 0.17355E+00 -0.7606 56 CaSO4,aq 0.18498E-06 -6.7329 0.18498E-06 -6.7329 0.10000E+01 0.0000 57 HCl,aq 0.40001E-02 -2.3979 0.40001E-02 -2.3979 0.10000E+01 0.0000 66 CuCl,aq 0.20378E-04 -4.6908 0.20378E-04 -4.6908 0.10000E+01 0.0000 67 CuCl2- 0.69955E-04 -4.1552 0.10861E-04 -4.9641 0.15525E+00 -0.8090 68 CuCl3-2 0.14643E-05 -5.8344 0.19393E-08 -8.7124 0.13244E-02 -2.8780 74 FeCl+ 0.22151E-06 -6.6546 0.38443E-07 -7.4152 0.17355E+00 -0.7606 75 FeCl2,aq 0.22573E-02 -2.6464 0.22573E-02 -2.6464 0.10000E+01 0.0000 77 FeO,aq 0.47313E-07 -7.3250 0.47313E-07 -7.3250 0.10000E+01 0.0000 78 FeOH+ 0.18015E-07 -7.7444 0.31265E-08 -8.5049 0.17355E+00 -0.7606 79 HFeO2- 0.51393E-08 -8.2891 0.79789E-09 -9.0981 0.15525E+00 -0.8090 82 FeO2- 0.32205E-08 -8.4921 0.49999E-09 -9.3010 0.15525E+00 -0.8090 83 HFeO2,aq 0.26451E-09 -9.5776 0.26451E-09 -9.5776 0.10000E+01 0.0000 84 H2,aq 0.42200E-02 -2.3747 0.49813E-02 -2.3027 0.11804E+01 0.0720 85 KCl,aq 0.72400E-01 -1.1403 0.72400E-01 -1.1403 0.10000E+01 0.0000 86 KHSO4,aq 0.13259E-01 -1.8775 0.13259E-01 -1.8775 0.10000E+01 0.0000 87 KOH,aq 0.13507E-05 -5.8694 0.13507E-05 -5.8694 0.10000E+01 0.0000 88 KSO4- 0.50127E-02 -2.2999 0.77823E-03 -3.1089 0.15525E+00 -0.8090 90 Mg(HCO3)+ 0.30973E-07 -7.5090 0.53753E-08 -8.2696 0.17355E+00 -0.7606 91 MgCl+ 0.17695E-04 -4.7522 0.30709E-05 -5.5127 0.17355E+00 -0.7606 92 MgOH+ 0.63921E-06 -6.1944 0.11093E-06 -6.9549 0.17355E+00 -0.7606 94 MnO,aq 0.89173E-07 -7.0498 0.89173E-07 -7.0498 0.10000E+01 0.0000 95 MnOH+ 0.20812E-06 -6.6817 0.36118E-07 -7.4423 0.17355E+00 -0.7606 97 HMnO2- 0.37186E-10 -10.4296 0.57733E-11 -11.2386 0.15525E+00 -0.8090 100 MnCl+ 0.11549E-02 -2.9374 0.20044E-03 -3.6980 0.17355E+00 -0.7606 101 MnSO4,aq 0.19312E-06 -6.7142 0.19312E-06 -6.7142 0.10000E+01 0.0000 102 NaCl,aq 0.44815E+00 -0.3486 0.44815E+00 -0.3486 0.10000E+01 0.0000 103 NaOH,aq 0.17742E-05 -5.7510 0.17742E-05 -5.7510 0.10000E+01 0.0000 105 OH- 0.71272E-05 -5.1471 0.96670E-06 -6.0147 0.13563E+00 -0.8676 110 HPO3-2 0.11540E-10 -10.9378 0.15283E-13 -13.8158 0.13244E-02 -2.8780 111 H3PO3,aq 0.12651E-09 -9.8979 0.12651E-09 -9.8979 0.10000E+01 0.0000 112 H2PO3- 0.17246E-08 -8.7633 0.26774E-09 -9.5723 0.15525E+00 -0.8090 113 H3PO4,aq 0.17304E-05 -5.7619 0.17304E-05 -5.7619 0.10000E+01 0.0000 114 H2PO4- 0.15531E-05 -5.8088 0.25398E-06 -6.5952 0.16353E+00 -0.7864 116 H4P2O7,aq 0.27844E-09 -9.5553 0.27844E-09 -9.5553 0.10000E+01 0.0000 117 H3P2O7- 0.11177E-08 -8.9517 0.17352E-09 -9.7607 0.15525E+00 -0.8090 118 H2P2O7-2 0.30454E-06 -6.5164 0.40332E-09 -9.3944 0.13244E-02 -2.8780 119 HP2O7-3 0.56771E-07 -7.2459 0.15356E-13 -13.8137 0.27048E-06 -6.5679 121 PbCl+ 0.11252E-05 -5.9488 0.19527E-06 -6.7094 0.17355E+00 -0.7606 122 PbCl2,aq 0.81984E-04 -4.0863 0.81984E-04 -4.0863 0.10000E+01 0.0000 123 PbCl3- 0.96098E-04 -4.0173 0.14919E-04 -4.8262 0.15525E+00 -0.8090 124 PbCl4-2 0.18442E-04 -4.7342 0.24424E-07 -7.6122 0.13244E-02 -2.8780 125 PbO,aq 0.62647E-08 -8.2031 0.62647E-08 -8.2031 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11723E-03 -3.9310 0.11723E-03 -3.9310 0.10000E+01 0.0000 128 Pb(HS)3- 0.13231E-04 -4.8784 0.20541E-05 -5.6874 0.15525E+00 -0.8090 129 H2S,aq 0.10590E+01 0.0249 0.12500E+01 0.0969 0.11804E+01 0.0720 130 S2-2 0.14142E-07 -7.8495 0.18729E-10 -10.7275 0.13244E-02 -2.8780 131 S3-2 0.13313E-08 -8.8757 0.17631E-11 -11.7537 0.13244E-02 -2.8780 132 S3- 0.87454E-02 -2.0582 0.13577E-02 -2.8672 0.15525E+00 -0.8090 133 S4-2 0.10696E-09 -9.9708 0.14166E-12 -12.8488 0.13244E-02 -2.8780 135 SO2,aq 0.29369E+00 -0.5321 0.29369E+00 -0.5321 0.10000E+01 0.0000 136 SO3-2 0.79394E-09 -9.1002 0.17186E-11 -11.7648 0.21647E-02 -2.6646 137 HSO3- 0.22621E-03 -3.6455 0.35120E-04 -4.4544 0.15525E+00 -0.8090 138 HSO4- 0.80492E-02 -2.0942 0.14382E-02 -2.8422 0.17867E+00 -0.7479 140 S2O3-2 0.64823E-06 -6.1883 0.85849E-09 -9.0663 0.13244E-02 -2.8780 141 HS2O3- 0.35578E-06 -6.4488 0.55235E-07 -7.2578 0.15525E+00 -0.8090 142 H2S2O3,aq 0.39618E-07 -7.4021 0.39618E-07 -7.4021 0.10000E+01 0.0000 150 S4O6-2 0.55407E-09 -9.2564 0.73378E-12 -12.1344 0.13244E-02 -2.8780 152 ZnCl+ 0.12790E-03 -3.8931 0.22196E-04 -4.6537 0.17355E+00 -0.7606 153 ZnCl2,aq 0.54239E-03 -3.2657 0.54239E-03 -3.2657 0.10000E+01 0.0000 154 ZnCl3- 0.35022E-04 -4.4557 0.54373E-05 -5.2646 0.15525E+00 -0.8090 155 ZnO,aq 0.24689E-07 -7.6075 0.24689E-07 -7.6075 0.10000E+01 0.0000 156 ZnOH+ 0.89129E-06 -6.0500 0.15468E-06 -6.8106 0.17355E+00 -0.7606 158 HZnO2- 0.17546E-09 -9.7558 0.27240E-10 -10.5648 0.15525E+00 -0.8090 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4662604E-05 0.4294236E+01 0.3543329E+04 -0.0000 2 H2O 0.1000000E+01 0.5252291E+02 0.7746065E+06 0.0000 3 Cl- 0.1233746E+00 0.6558601E+00 0.1903510E+05 4.3465 4 SO4-- 0.3263088E-03 0.2513846E+00 0.1976876E+05 5.7996 5 HCO3- 0.8166479E-05 0.2674050E+01 0.1335712E+06 0.2009 6 HS- 0.1141665E-03 0.1154822E+01 0.3126558E+05 1.3165 7 H4SiO4 0.4347859E-01 0.4348173E-01 0.3421296E+04 -1.3617 8 Al+++ 0.7945280E-16 0.1102008E-04 0.2434118E+00 -4.4172 9 Ca++ 0.1651817E-05 0.1376423E-03 0.4515949E+01 3.4016 10 Mg++ 0.2449838E-05 0.2081628E-04 0.4142999E+00 3.4836 11 Fe++ 0.1781763E-07 0.2257598E-02 0.1032137E+03 1.3678 12 K+ 0.3489566E-01 0.1255688E+00 0.4019497E+04 3.8424 13 Na+ 0.1101887E+00 0.5583446E+00 0.1050820E+05 4.3022 14 Mn++ 0.1841987E-05 0.1157263E-02 0.5204700E+02 3.3988 15 Zn++ 0.4760828E-09 0.7062255E-03 0.3779312E+02 -0.2053 16 Cu+ 0.1218062E-07 0.9181012E-04 0.4775608E+01 -2.6555 17 Pb++ 0.3462268E-08 0.3281217E-03 0.5565378E+02 0.7751 18 Ag+ 0.2486276E-09 0.8759600E-05 0.7735277E+00 -4.3120 19 Ba++ 0.7558718E-07 0.7107361E-05 0.7990911E+00 2.1473 20 HPO4-- 0.2045044E-08 0.4012815E-05 0.3152944E+00 0.5990 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265431E+01 -.3068473E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5217059E+02 -.2058099E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2496984E+00 0.2024390E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1147076E+01 0.1306817E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4319006E-01 0.1004043E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1094616E-04 0.6835934E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1367191E-03 0.3911908E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2242455E-02 0.6524299E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247265E+00 0.6835934E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7014882E-03 0.1597846E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.9119427E-04 0.3084154E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3259207E-03 0.1425193E-04 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7059686E-05 0.4831277E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.3985897E-05 0.4581603E-05 0.0000000E+00 Chg. balance for solid moles: 0.2224E-17 Mass of aqueous solution: 0.121335E+04 g Temperature = 553.00 C Pressure = 978.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3836E-03 -3.416 0.5222E-01 -1.282 0.7329 0.1762E-01 apatite-OH 0.1527E-05 -5.816 0.7671E-03 -3.115 0.1077E-01 0.2438E-03 microcline 0.6836E-03 -3.165 0.1903 -0.721 2.670 0.7432E-01 pyrite 0.6216E-02 -2.206 0.7458 -0.127 10.47 0.1488 quartz 0.9835E-01 -1.007 5.909 0.772 82.93 2.232 barite 0.4831E-04 -4.316 0.1128E-01 -1.948 0.1583 0.2517E-02 chalcopyrite 0.3084E-03 -3.511 0.5659E-01 -1.247 0.7943 0.1321E-01 galena 0.1425E-04 -4.846 0.3410E-02 -2.467 0.4786E-01 0.4488E-03 sphalerite 0.1598E-02 -2.796 0.1557 -0.808 2.185 0.3807E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.125073 g Volume = 2.526764 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.06 -15.06 0.00 0.000 0.00000E+00 27 apatite-OH -53.97 -53.97 -0.00 -0.000 0.53722E-10 112 microcline -4.65 -4.65 -0.00 -0.000 0.67152E-11 137 pyrite -22.17 -22.17 -0.00 -0.000 0.13430E-10 141 quartz -1.36 -1.36 -0.00 -0.000 0.83940E-12 234 barite -16.31 -16.31 0.00 0.000 0.00000E+00 237 chalcopyrite -23.87 -23.87 0.00 0.000 0.00000E+00 242 galena -10.04 -10.04 0.00 0.000 -0.67152E-11 252 sphalerite -11.02 -11.02 -0.00 -0.000 0.67152E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 -0.00 -0.26 -0.258 0.97594E+03 2.732 2 CO2,gas -10.21 -11.93 -1.71 -0.571 0.64755E+04 1.277 3 CH4,gas 6.81 -4.28 -11.10 -2.774 0.41945E+05 -8.105 4 H2,gas 6.00 1.91 -4.09 -2.339 0.15472E+05 -1.102 5 H2S,gas -8.51 -10.81 -2.30 -1.152 0.87074E+04 0.687 6 CO,gas -3.92 -10.01 -6.10 -1.876 0.23049E+05 -3.107 7 SO3,gas -7.72 -18.46 -10.74 -2.685 0.40596E+05 -7.748 8 O2,gas 17.04 -3.82 -20.87 -13.910 0.78878E+05 -17.875 9 HCl,gas -6.20 -7.78 -1.58 -0.791 0.59825E+04 -1.583 10 acmite 3.61 1.99 -1.61 -0.168 0.61014E+04 12 akimotoite 6.36 2.12 -4.23 -0.847 0.16008E+05 13 akimotoite-Fe 4.20 0.01 -4.19 -0.838 0.15832E+05 14 albite-high -4.03 -4.19 -0.16 -0.013 0.61572E+03 15 albite -4.04 -4.19 -0.16 -0.012 0.59796E+03 16 almandine -6.53 -8.82 -2.29 -0.114 0.86509E+04 17 pyrope 0.33 -2.47 -2.80 -0.140 0.10577E+05 18 analcite -1.83 -2.84 -1.01 -0.112 0.38078E+04 19 andalusite -9.58 -10.20 -0.62 -0.062 0.23516E+04 24 anorthite -7.21 -8.16 -0.94 -0.073 0.35706E+04 25 anthophyllite 15.52 13.50 -2.02 -0.054 0.76184E+04 26 anthophyllite-Fe 2.43 -1.31 -3.74 -0.101 0.14146E+05 28 apatite-OH-zs -51.75 -53.97 -2.21 -0.170 0.83715E+04 29 apatite-Cl-zs -58.47 -61.75 -3.28 -0.273 0.12395E+05 30 aragonite -4.75 -8.53 -3.78 -1.259 0.14275E+05 31 brucite 5.72 3.48 -2.24 -0.448 0.84711E+04 32 calcite -4.86 -8.53 -3.67 -1.222 0.13864E+05 33 carnegieite-low 0.34 -1.48 -1.82 -0.260 0.68805E+04 34 carnegieite-high 0.43 -1.48 -1.91 -0.273 0.72155E+04 35 carpholite-Mg -6.00 -8.08 -2.07 -0.138 0.78360E+04 36 carpholite-Fe -7.41 -10.19 -2.79 -0.186 0.10529E+05 37 celadonite -0.45 -2.53 -2.08 -0.122 0.78725E+04 38 celadonite-Fe -1.90 -4.65 -2.75 -0.162 0.10400E+05 39 chrysotile 10.02 7.73 -2.30 -0.191 0.86828E+04 41 clinochlore 5.74 4.49 -1.25 -0.039 0.47374E+04 42 daphnite -1.57 -6.09 -4.52 -0.141 0.17084E+05 44 chlorite-Al-free 20.21 15.45 -4.76 -0.198 0.17985E+05 45 chloritoid-Mg -5.32 -6.72 -1.40 -0.093 0.52875E+04 46 chloritoid-Fe -7.33 -8.83 -1.50 -0.100 0.56734E+04 47 chloritoid-Mn -5.19 -6.80 -1.61 -0.107 0.60893E+04 49 coesite -1.06 -1.36 -0.30 -0.099 0.11213E+04 50 cordierite-H -16.46 -17.51 -1.05 -0.038 0.39760E+04 51 cordierite-Fe -19.16 -21.74 -2.58 -0.089 0.97462E+04 52 cordierite-Mn -14.81 -17.68 -2.87 -0.099 0.10832E+05 53 corundum -8.04 -8.84 -0.80 -0.073 0.30360E+04 55 cristobalite -1.31 -1.36 -0.05 -0.016 0.18103E+03 56 cummingtonite 15.59 13.50 -2.09 -0.056 0.78863E+04 58 cymrite-K -2.30 -4.66 -2.36 -0.196 0.89036E+04 60 diaspore -3.53 -4.42 -0.89 -0.148 0.33584E+04 62 diopside 5.62 4.16 -1.45 -0.145 0.54955E+04 63 hedenbergite 4.15 2.05 -2.10 -0.210 0.79288E+04 65 eastonite -3.80 -5.17 -1.37 -0.053 0.51759E+04 66 enstatite 5.07 4.25 -0.83 -0.083 0.31265E+04 67 clinoenstatite-HiP 5.58 4.25 -1.33 -0.133 0.50366E+04 68 clinoenstatite 5.05 4.25 -0.81 -0.081 0.30566E+04 69 protoenstatite 5.21 4.25 -0.96 -0.096 0.36416E+04 70 epidote -3.02 -5.70 -2.68 -0.130 0.10149E+05 71 clinozoisite -7.46 -10.53 -3.07 -0.140 0.11615E+05 72 epidote-Fe 3.13 -0.87 -4.00 -0.208 0.15131E+05 73 fayalite 2.63 1.37 -1.26 -0.180 0.47637E+04 74 ferrosilite 1.38 0.01 -1.36 -0.136 0.51456E+04 75 forsterite 6.75 5.61 -1.15 -0.164 0.43352E+04 76 gedrite -6.22 -8.42 -2.20 -0.059 0.83173E+04 78 gibbsite -1.90 -4.42 -2.52 -0.361 0.95428E+04 79 glaucophane 2.34 -0.66 -3.00 -0.081 0.11358E+05 81 goethite 1.35 0.41 -0.94 -0.204 0.35712E+04 83 greenalite 4.98 1.38 -3.60 -0.300 0.13601E+05 84 grunerite 3.01 -1.31 -4.32 -0.117 0.16316E+05 85 halite -1.44 -3.48 -2.04 -1.020 0.77111E+04 86 hematite 1.16 0.82 -0.34 -0.041 0.12818E+04 87 heulandite -11.62 -14.96 -3.34 -0.152 0.12642E+05 88 hercynite -6.06 -7.47 -1.41 -0.094 0.53263E+04 91 jadeite -1.15 -2.84 -1.69 -0.169 0.63896E+04 93 kalsilite -0.28 -1.94 -1.65 -0.236 0.62559E+04 94 kaolinite -8.75 -11.56 -2.81 -0.255 0.10618E+05 95 kyanite -9.41 -10.20 -0.79 -0.079 0.29795E+04 97 laumontite -7.07 -10.88 -3.81 -0.254 0.14417E+05 98 lawsonite -4.45 -8.16 -3.71 -0.247 0.14012E+05 99 leucite -2.31 -3.30 -0.99 -0.099 0.37400E+04 101 lizardite 10.18 7.73 -2.46 -0.205 0.92893E+04 102 magnesite -5.52 -8.44 -2.93 -0.976 0.11063E+05 103 magnetite 2.60 2.19 -0.42 -0.034 0.15701E+04 104 minnesotaite 1.00 -1.34 -2.34 -0.138 0.88441E+04 105 minnesotaite-Mg 7.16 5.01 -2.15 -0.126 0.81166E+04 106 magnesioferrite 5.76 4.30 -1.45 -0.119 0.54897E+04 108 manganosite 5.64 3.40 -2.24 -0.560 0.84710E+04 109 margarite -14.81 -17.00 -2.19 -0.088 0.82770E+04 113 monticellite 9.17 5.52 -3.64 -0.521 0.13778E+05 115 mullite-Si -8.81 -10.20 -1.39 -0.139 0.52637E+04 116 muscovite -12.57 -13.49 -0.92 -0.054 0.34841E+04 117 paragonite -11.89 -13.03 -1.15 -0.068 0.43456E+04 118 nepheline 0.04 -1.48 -1.52 -0.216 0.57288E+04 119 osumilite(2) -11.88 -13.92 -2.04 -0.043 0.77215E+04 120 osumilite-Fe -26.11 -29.11 -3.00 -0.063 0.11343E+05 121 pargasite 7.88 3.62 -4.26 -0.112 0.16112E+05 122 periclase 5.94 3.48 -2.46 -0.614 0.92865E+04 123 periclase-Fe 3.30 1.37 -1.93 -0.482 0.72906E+04 124 perovskite-Al -6.27 -8.84 -2.57 -0.233 0.96989E+04 129 phlogopite-Na 7.05 6.25 -0.80 -0.044 0.30172E+04 131 prehnite -2.46 -6.12 -3.65 -0.215 0.13811E+05 132 prehnite-Fe 2.38 -1.29 -3.66 -0.220 0.13850E+05 135 px-Mg-tschermaks -4.66 -6.72 -2.06 -0.147 0.77690E+04 136 px-Ca-tschermaks -3.93 -6.80 -2.86 -0.205 0.10830E+05 138 pyrrhotite -8.70 -9.44 -0.74 -0.247 0.28005E+04 139 pyrrhotiteFe0.875 -9.51 -9.85 -0.34 -0.125 0.12801E+04 140 pyrophyllite -12.80 -14.28 -1.48 -0.093 0.55962E+04 143 riebeckite 5.93 2.65 -3.28 -0.090 0.12384E+05 144 ringwoodite-Fe 3.64 1.37 -2.27 -0.324 0.85665E+04 145 ringwoodite-Mg 9.96 5.61 -4.35 -0.621 0.16444E+05 146 rhodochrosite -5.55 -8.53 -2.98 -0.992 0.11248E+05 147 rhodonite 2.63 2.04 -0.59 -0.118 0.22318E+04 148 sanidine -4.11 -4.65 -0.55 -0.042 0.20679E+04 150 siderite -7.42 -10.56 -3.14 -1.048 0.11882E+05 151 sillimanite -9.53 -10.20 -0.66 -0.066 0.25047E+04 153 spinel -3.83 -5.36 -1.52 -0.102 0.57608E+04 160 stilpnomelane-Mg 1.62 -0.39 -2.01 -0.060 0.75938E+04 161 stishovite 1.64 -1.36 -3.00 -1.000 0.11345E+05 162 sudoite-Fe -14.28 -19.03 -4.75 -0.153 0.17955E+05 163 sudoite -11.97 -14.79 -2.83 -0.091 0.10688E+05 164 sulfur -11.24 -12.72 -1.48 -0.455 0.55911E+04 165 sylvite -1.34 -3.94 -2.60 -1.298 0.98118E+04 166 talc 5.40 5.01 -0.39 -0.023 0.14896E+04 167 talc-Fe 2.43 -1.34 -3.77 -0.222 0.14254E+05 168 talc-tschermaks -4.25 -5.95 -1.70 -0.100 0.64251E+04 170 tephroite 6.88 5.44 -1.45 -0.207 0.54674E+04 173 topaz-H -7.48 -10.20 -2.72 -0.247 0.10268E+05 174 tremolite 15.99 13.34 -2.65 -0.072 0.10027E+05 176 troilite-low -8.61 -9.44 -0.83 -0.277 0.31360E+04 177 tschermakite -4.96 -8.59 -3.62 -0.098 0.13687E+05 180 wadsleyite-Fe 3.50 1.37 -2.12 -0.303 0.80267E+04 181 wadsleyite-Mg 9.00 5.61 -3.40 -0.485 0.12841E+05 182 wairakite -8.95 -10.88 -1.93 -0.114 0.72963E+04 183 walstromite 4.70 2.04 -2.66 -0.531 0.10040E+05 184 wollastonite 4.27 2.04 -2.22 -0.445 0.84099E+04 185 pseudo-wollastonite 4.39 2.04 -2.35 -0.469 0.88668E+04 186 zoisite -7.51 -10.53 -3.02 -0.137 0.11431E+05 189 beidellite-Ca -12.87 -14.72 -1.86 -0.115 0.70228E+04 190 beidellite-H -12.91 -15.29 -2.37 -0.151 0.89721E+04 191 beidellite-K -11.87 -14.02 -2.15 -0.131 0.81160E+04 192 beidellite-Mg -13.11 -14.71 -1.60 -0.099 0.60588E+04 193 beidellite-Na -11.81 -13.87 -2.05 -0.126 0.77602E+04 194 bornite -55.87 -56.11 -0.24 -0.018 0.90311E+03 196 chalcocite -14.68 -16.12 -1.44 -0.360 0.54488E+04 197 covellite -13.09 -14.42 -1.33 -0.508 0.50411E+04 199 montmorillonite-Ca -9.73 -11.11 -1.37 -0.085 0.51967E+04 200 montmorillonite-K -9.01 -10.40 -1.39 -0.085 0.52445E+04 201 montmorillonite-Mg -9.94 -11.09 -1.16 -0.071 0.43677E+04 202 montmorillonite-Na -8.68 -10.25 -1.56 -0.096 0.59141E+04 203 nontronite-Ca -3.40 -5.06 -1.66 -0.108 0.62870E+04 204 nontronite-H -3.45 -5.63 -2.17 -0.146 0.82078E+04 205 nontronite-K -2.41 -4.36 -1.95 -0.125 0.73723E+04 206 nontronite-Mg -3.61 -5.05 -1.44 -0.093 0.54437E+04 207 nontronite-Na -2.35 -4.21 -1.86 -0.119 0.70282E+04 212 gypsum -12.79 -15.06 -2.27 -0.567 0.85775E+04 229 alabandite -6.43 -7.41 -0.98 -0.328 0.37165E+04 231 anglesite -15.38 -17.68 -2.30 -1.150 0.86959E+04 235 boehmite -3.23 -4.42 -1.19 -0.198 0.45007E+04 239 copper,native 1.70 -1.70 -3.40 -1.181 0.12838E+05 241 ferrous-oxide 2.36 1.37 -0.99 -0.248 0.37463E+04 243 silver,native 0.39 -3.36 -3.75 -1.305 0.14180E+05 245 litharge 5.42 0.77 -4.64 -1.161 0.17549E+05 253 wurtzite -10.20 -11.02 -0.82 -0.272 0.30901E+04 254 zincite 2.43 -0.21 -2.63 -0.658 0.99530E+04 255 an20ab80 -4.89 -4.99 -0.10 -0.008 0.36994E+03 256 an25ab75 -5.07 -5.19 -0.11 -0.009 0.41829E+03 257 an30ab70 -5.25 -5.38 -0.13 -0.010 0.48755E+03 258 tr.625ac.25prg.125 10.73 9.48 -1.25 -0.034 0.47411E+04 Calculations done for 553.0000 Deg. C; 978.0000 bar Temperature changed by -1.000 degrees to 552.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 43 Loop limit = 500 Temperature = 552.00 C Pressure = 967.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5514E+02 kg liquid = 0.9933E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9969 Stoichiometric ionic strength = .3272198E+01 Osmotic coef. = 0.0000 True ionic strength = .1503457E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.48068E-05 -5.3181 0.84978E-06 -6.0707 0.17679E+00 -0.7525 2 H2O 0.99692E+00 -0.0013 0.99692E+00 -0.0013 3 Cl- 0.12651E+00 -0.8979 0.18639E-01 -1.7296 0.14734E+00 -0.8317 4 SO4-- 0.37642E-03 -3.4243 0.44942E-06 -6.3473 0.11940E-02 -2.9230 5 HCO3- 0.81496E-05 -5.0889 0.13007E-05 -5.8858 0.15960E+00 -0.7970 6 HS- 0.11665E-03 -3.9331 0.17339E-04 -4.7610 0.14865E+00 -0.8278 7 H4SiO4 0.42701E-01 -1.3696 0.42701E-01 -1.3696 0.10000E+01 0.0000 8 Al+++ 0.13360E-15 -15.8742 0.26845E-22 -22.5711 0.20093E-06 -6.6970 9 Ca++ 0.19876E-05 -5.7017 0.18597E-08 -8.7306 0.93568E-03 -3.0289 10 Mg++ 0.28064E-05 -5.5518 0.21235E-08 -8.6729 0.75665E-03 -3.1211 11 Fe++ 0.21791E-07 -7.6617 0.17398E-10 -10.7595 0.79839E-03 -3.0978 12 K+ 0.35601E-01 -1.4485 0.58294E-02 -2.2344 0.16374E+00 -0.7858 13 Na+ 0.11293E+00 -0.9472 0.16828E-01 -1.7740 0.14901E+00 -0.8268 14 Mn++ 0.21877E-05 -5.6600 0.18166E-08 -8.7407 0.83038E-03 -3.0807 15 Zn++ 0.58476E-09 -9.2330 0.46687E-12 -12.3308 0.79839E-03 -3.0978 16 Cu+ 0.12501E-07 -7.9031 0.18574E-08 -8.7311 0.14859E+00 -0.8280 17 Pb++ 0.40950E-08 -8.3878 0.43378E-11 -11.3627 0.10593E-02 -2.9750 18 Ag+ 0.22217E-09 -9.6533 0.35760E-10 -10.4466 0.16096E+00 -0.7933 19 Ba++ 0.88682E-07 -7.0522 0.10163E-09 -9.9930 0.11461E-02 -2.9408 20 HPO4-- 0.23894E-08 -8.6217 0.28685E-11 -11.5423 0.12005E-02 -2.9206 21 HSiO3- 0.13064E-05 -5.8839 0.19248E-06 -6.7156 0.14734E+00 -0.8317 22 Ca(HSiO3)+ 0.41096E-08 -8.3862 0.67938E-09 -9.1679 0.16532E+00 -0.7817 23 Mg(HSiO3)+ 0.15835E-08 -8.8004 0.26179E-09 -9.5821 0.16532E+00 -0.7817 24 NaHSiO3,aq 0.18276E-05 -5.7381 0.18276E-05 -5.7381 0.10000E+01 0.0000 28 AgCl,aq 0.89356E-07 -7.0489 0.89356E-07 -7.0489 0.10000E+01 0.0000 29 AgCl2- 0.40428E-05 -5.3933 0.59567E-06 -6.2250 0.14734E+00 -0.8317 30 AgCl3-2 0.16787E-05 -5.7750 0.18417E-08 -8.7348 0.10972E-02 -2.9597 31 AgCl4-3 0.29412E-05 -5.5315 0.51525E-12 -12.2880 0.17518E-06 -6.7565 34 Ag(HS),aq 0.16546E-08 -8.7813 0.16546E-08 -8.7813 0.10000E+01 0.0000 35 Ag(HS)2- 0.53730E-08 -8.2698 0.79165E-09 -9.1015 0.14734E+00 -0.8317 36 AlO+ 0.14191E-10 -10.8480 0.23460E-11 -11.6297 0.16532E+00 -0.7817 38 HAlO2,aq 0.45263E-08 -8.3443 0.45263E-08 -8.3443 0.10000E+01 0.0000 39 AlO2- 0.11441E-04 -4.9415 0.14662E-05 -5.8338 0.12815E+00 -0.8923 41 Ba(HCO3)+ 0.16662E-06 -6.7783 0.28768E-07 -7.5411 0.17266E+00 -0.7628 42 BaCl+ 0.69968E-05 -5.1551 0.11567E-05 -5.9368 0.16532E+00 -0.7817 43 CH4,aq 0.13307E-08 -8.8759 0.15695E-08 -8.8042 0.11795E+01 0.0717 48 CO,aq 0.43764E-03 -3.3589 0.43764E-03 -3.3589 0.10000E+01 0.0000 49 CO2,aq 0.26735E+01 0.4271 0.31533E+01 0.4988 0.11795E+01 0.0717 50 CO3-2 0.50896E-10 -10.2933 0.55842E-13 -13.2530 0.10972E-02 -2.9597 52 Ca(HCO3)+ 0.78699E-07 -7.1040 0.13010E-07 -7.8857 0.16532E+00 -0.7817 53 CaCl+ 0.68510E-04 -4.1642 0.11326E-04 -4.9459 0.16532E+00 -0.7817 54 CaCl2,aq 0.69173E-04 -4.1601 0.69173E-04 -4.1601 0.10000E+01 0.0000 55 CaOH+ 0.12469E-06 -6.9042 0.20613E-07 -7.6859 0.16532E+00 -0.7817 56 CaSO4,aq 0.18736E-06 -6.7273 0.18736E-06 -6.7273 0.10000E+01 0.0000 57 HCl,aq 0.41889E-02 -2.3779 0.41889E-02 -2.3779 0.10000E+01 0.0000 66 CuCl,aq 0.20343E-04 -4.6916 0.20343E-04 -4.6916 0.10000E+01 0.0000 67 CuCl2- 0.72012E-04 -4.1426 0.10610E-04 -4.9743 0.14734E+00 -0.8317 68 CuCl3-2 0.16626E-05 -5.7792 0.18241E-08 -8.7389 0.10972E-02 -2.9597 74 FeCl+ 0.23126E-06 -6.6359 0.38231E-07 -7.4176 0.16532E+00 -0.7817 75 FeCl2,aq 0.22136E-02 -2.6549 0.22136E-02 -2.6549 0.10000E+01 0.0000 77 FeO,aq 0.46395E-07 -7.3335 0.46395E-07 -7.3335 0.10000E+01 0.0000 78 FeOH+ 0.18661E-07 -7.7291 0.30850E-08 -8.5107 0.16532E+00 -0.7817 79 HFeO2- 0.51709E-08 -8.2864 0.76188E-09 -9.1181 0.14734E+00 -0.8317 82 FeO2- 0.32196E-08 -8.4922 0.47437E-09 -9.3239 0.14734E+00 -0.8317 83 HFeO2,aq 0.26416E-09 -9.5781 0.26416E-09 -9.5781 0.10000E+01 0.0000 84 H2,aq 0.42005E-02 -2.3767 0.49543E-02 -2.3050 0.11795E+01 0.0717 85 KCl,aq 0.71878E-01 -1.1434 0.71878E-01 -1.1434 0.10000E+01 0.0000 86 KHSO4,aq 0.13002E-01 -1.8860 0.13002E-01 -1.8860 0.10000E+01 0.0000 87 KOH,aq 0.13316E-05 -5.8756 0.13316E-05 -5.8756 0.10000E+01 0.0000 88 KSO4- 0.50840E-02 -2.2938 0.74908E-03 -3.1255 0.14734E+00 -0.8317 90 Mg(HCO3)+ 0.29141E-07 -7.5355 0.48175E-08 -8.3172 0.16532E+00 -0.7817 91 MgCl+ 0.17358E-04 -4.7605 0.28696E-05 -5.5422 0.16532E+00 -0.7817 92 MgOH+ 0.62024E-06 -6.2074 0.10254E-06 -6.9891 0.16532E+00 -0.7817 94 MnO,aq 0.85446E-07 -7.0683 0.85446E-07 -7.0683 0.10000E+01 0.0000 95 MnOH+ 0.20838E-06 -6.6811 0.34449E-07 -7.4628 0.16532E+00 -0.7817 97 HMnO2- 0.36306E-10 -10.4400 0.53493E-11 -11.2717 0.14734E+00 -0.8317 100 MnCl+ 0.11546E-02 -2.9376 0.19087E-03 -3.7193 0.16532E+00 -0.7817 101 MnSO4,aq 0.19090E-06 -6.7192 0.19090E-06 -6.7192 0.10000E+01 0.0000 102 NaCl,aq 0.44540E+00 -0.3513 0.44540E+00 -0.3513 0.10000E+01 0.0000 103 NaOH,aq 0.17501E-05 -5.7569 0.17501E-05 -5.7569 0.10000E+01 0.0000 105 OH- 0.73320E-05 -5.1348 0.93956E-06 -6.0271 0.12815E+00 -0.8923 110 HPO3-2 0.13053E-10 -10.8843 0.14321E-13 -13.8440 0.10972E-02 -2.9597 111 H3PO3,aq 0.12790E-09 -9.8931 0.12790E-09 -9.8931 0.10000E+01 0.0000 112 H2PO3- 0.17327E-08 -8.7613 0.25530E-09 -9.5929 0.14734E+00 -0.8317 113 H3PO4,aq 0.17821E-05 -5.7491 0.17821E-05 -5.7491 0.10000E+01 0.0000 114 H2PO4- 0.16013E-05 -5.7955 0.24895E-06 -6.6039 0.15547E+00 -0.8084 116 H4P2O7,aq 0.29638E-09 -9.5281 0.29638E-09 -9.5281 0.10000E+01 0.0000 117 H3P2O7- 0.11647E-08 -8.9338 0.17160E-09 -9.7655 0.14734E+00 -0.8317 118 H2P2O7-2 0.34811E-06 -6.4583 0.38193E-09 -9.4180 0.10972E-02 -2.9597 119 HP2O7-3 0.81818E-07 -7.0872 0.14333E-13 -13.8437 0.17518E-06 -6.7565 121 PbCl+ 0.11532E-05 -5.9381 0.19065E-06 -6.7198 0.16532E+00 -0.7817 122 PbCl2,aq 0.81952E-04 -4.0864 0.81952E-04 -4.0864 0.10000E+01 0.0000 123 PbCl3- 0.99162E-04 -4.0037 0.14610E-04 -4.8353 0.14734E+00 -0.8317 124 PbCl4-2 0.20923E-04 -4.6794 0.22956E-07 -7.6391 0.10972E-02 -2.9597 125 PbO,aq 0.62123E-08 -8.2067 0.62123E-08 -8.2067 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11542E-03 -3.9377 0.11542E-03 -3.9377 0.10000E+01 0.0000 128 Pb(HS)3- 0.13385E-04 -4.8734 0.19722E-05 -5.7050 0.14734E+00 -0.8317 129 H2S,aq 0.10589E+01 0.0249 0.12489E+01 0.0965 0.11795E+01 0.0717 130 S2-2 0.15960E-07 -7.7970 0.17511E-10 -10.7567 0.10972E-02 -2.9597 131 S3-2 0.14981E-08 -8.8245 0.16436E-11 -11.7842 0.10972E-02 -2.9597 132 S3- 0.87563E-02 -2.0577 0.12902E-02 -2.8894 0.14734E+00 -0.8317 133 S4-2 0.12012E-09 -9.9204 0.13179E-12 -12.8801 0.10972E-02 -2.9597 135 SO2,aq 0.29367E+00 -0.5321 0.29367E+00 -0.5321 0.10000E+01 0.0000 136 SO3-2 0.89766E-09 -9.0469 0.16367E-11 -11.7860 0.18233E-02 -2.7391 137 HSO3- 0.22846E-03 -3.6412 0.33662E-04 -4.4729 0.14734E+00 -0.8317 138 HSO4- 0.81677E-02 -2.0879 0.13915E-02 -2.8565 0.17037E+00 -0.7686 140 S2O3-2 0.73903E-06 -6.1313 0.81083E-09 -9.0911 0.10972E-02 -2.9597 141 HS2O3- 0.36013E-06 -6.4435 0.53061E-07 -7.2752 0.14734E+00 -0.8317 142 H2S2O3,aq 0.40372E-07 -7.3939 0.40372E-07 -7.3939 0.10000E+01 0.0000 150 S4O6-2 0.62553E-09 -9.2038 0.68630E-12 -12.1635 0.10972E-02 -2.9597 152 ZnCl+ 0.13082E-03 -3.8833 0.21626E-04 -4.6650 0.16532E+00 -0.7817 153 ZnCl2,aq 0.53979E-03 -3.2678 0.53979E-03 -3.2678 0.10000E+01 0.0000 154 ZnCl3- 0.35383E-04 -4.4512 0.52133E-05 -5.2829 0.14734E+00 -0.8317 155 ZnO,aq 0.24366E-07 -7.6132 0.24366E-07 -7.6132 0.10000E+01 0.0000 156 ZnOH+ 0.91066E-06 -6.0406 0.15055E-06 -6.8223 0.16532E+00 -0.7817 158 HZnO2- 0.17776E-09 -9.7502 0.26192E-10 -10.5818 0.14734E+00 -0.8317 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4806797E-05 0.4294089E+01 0.3543459E+04 -0.0000 2 H2O 0.1000000E+01 0.5252296E+02 0.7746620E+06 0.0000 3 Cl- 0.1265065E+00 0.6558408E+00 0.1903588E+05 4.3411 4 SO4-- 0.3764182E-03 0.2513682E+00 0.1976887E+05 5.7940 5 HCO3- 0.8149593E-05 0.2673971E+01 0.1335767E+06 0.1849 6 HS- 0.1166451E-03 0.1154717E+01 0.3126494E+05 1.3097 7 H4SiO4 0.4270066E-01 0.4270380E-01 0.3360323E+04 -1.3696 8 Al+++ 0.1336024E-15 0.1144599E-04 0.2528373E+00 -4.3591 9 Ca++ 0.1987565E-05 0.1400659E-03 0.4595790E+01 3.4108 10 Mg++ 0.2806440E-05 0.2081567E-04 0.4143170E+00 3.4684 11 Fe++ 0.2179147E-07 0.2213891E-02 0.1012227E+03 1.3819 12 K+ 0.3560095E-01 0.1255656E+00 0.4019677E+04 3.8363 13 Na+ 0.1129273E+00 0.5583282E+00 0.1050864E+05 4.2967 14 Mn++ 0.2187681E-05 0.1157229E-02 0.5204915E+02 3.4006 15 Zn++ 0.5847632E-09 0.7069266E-03 0.3783331E+02 -0.1894 16 Cu+ 0.1250061E-07 0.9403075E-04 0.4891463E+01 -2.6604 17 Pb++ 0.4094955E-08 0.3320077E-03 0.5631687E+02 0.7787 18 Ag+ 0.2221662E-09 0.8759342E-05 0.7735596E+00 -4.3759 19 Ba++ 0.8868217E-07 0.7252060E-05 0.8154175E+00 2.1484 20 HPO4-- 0.2389352E-08 0.4250456E-05 0.3339899E+00 0.5990 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265411E+01 -.3048556E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5217218E+02 -.2073982E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2496894E+00 0.2033342E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1147005E+01 0.1313917E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4241860E-01 0.1011757E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1136955E-04 0.6831700E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1391305E-03 0.3887794E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2199105E-02 0.6567648E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247270E+00 0.6831700E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7022053E-03 0.1597129E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.9340276E-04 0.3062070E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3297903E-03 0.1038232E-04 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7203626E-05 0.4816883E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.4222069E-05 0.4345431E-05 0.0000000E+00 Chg. balance for solid moles: -.5573E-18 Mass of aqueous solution: 0.121330E+04 g Temperature = 552.00 C Pressure = 967.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3815E-03 -3.418 0.5194E-01 -1.284 0.7239 0.1753E-01 apatite-OH 0.1448E-05 -5.839 0.7276E-03 -3.138 0.1014E-01 0.2312E-03 microcline 0.6832E-03 -3.165 0.1902 -0.721 2.650 0.7428E-01 pyrite 0.6261E-02 -2.203 0.7512 -0.124 10.47 0.1499 quartz 0.9913E-01 -1.004 5.956 0.775 83.00 2.249 barite 0.4817E-04 -4.317 0.1124E-01 -1.949 0.1567 0.2510E-02 chalcopyrite 0.3062E-03 -3.514 0.5619E-01 -1.250 0.7831 0.1312E-01 galena 0.1038E-04 -4.984 0.2484E-02 -2.605 0.3462E-01 0.3269E-03 sphalerite 0.1597E-02 -2.797 0.1556 -0.808 2.169 0.3806E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.175098 g Volume = 2.544995 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.08 -15.08 -0.00 -0.000 0.67071E-11 27 apatite-OH -54.00 -54.00 0.00 0.000 0.00000E+00 112 microcline -4.63 -4.63 0.00 0.000 0.00000E+00 137 pyrite -22.19 -22.19 0.00 0.000 -0.13414E-10 141 quartz -1.37 -1.37 0.00 0.000 0.00000E+00 234 barite -16.34 -16.34 0.00 0.000 0.00000E+00 237 chalcopyrite -23.90 -23.90 0.00 0.000 0.00000E+00 242 galena -10.05 -10.05 0.00 0.000 0.00000E+00 252 sphalerite -11.02 -11.02 0.00 0.000 -0.67071E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 -0.00 -0.26 -0.258 0.97229E+03 2.728 2 CO2,gas -10.24 -11.96 -1.72 -0.573 0.64883E+04 1.267 3 CH4,gas 6.81 -4.30 -11.11 -2.777 0.41940E+05 -8.122 4 H2,gas 6.01 1.91 -4.10 -2.340 0.15462E+05 -1.110 5 H2S,gas -8.53 -10.83 -2.30 -1.152 0.86990E+04 0.682 6 CO,gas -3.93 -10.04 -6.11 -1.880 0.23064E+05 -3.123 7 SO3,gas -7.74 -18.49 -10.75 -2.688 0.40592E+05 -7.765 8 O2,gas 17.06 -3.83 -20.89 -13.928 0.78884E+05 -17.907 9 HCl,gas -6.21 -7.80 -1.59 -0.795 0.60025E+04 -1.590 10 acmite 3.61 1.99 -1.63 -0.169 0.61388E+04 12 akimotoite 6.38 2.10 -4.28 -0.856 0.16160E+05 13 akimotoite-Fe 4.21 0.01 -4.20 -0.840 0.15858E+05 14 albite-high -4.00 -4.17 -0.16 -0.013 0.62104E+03 15 albite -4.01 -4.17 -0.16 -0.012 0.59915E+03 16 almandine -6.38 -8.68 -2.31 -0.115 0.87042E+04 17 pyrope 0.50 -2.42 -2.92 -0.146 0.11012E+05 18 analcite -1.79 -2.80 -1.01 -0.112 0.38102E+04 19 andalusite -9.47 -10.09 -0.62 -0.062 0.23224E+04 24 anorthite -7.10 -8.05 -0.94 -0.073 0.35645E+04 25 anthophyllite 15.63 13.33 -2.30 -0.062 0.86759E+04 26 anthophyllite-Fe 2.52 -1.27 -3.79 -0.102 0.14312E+05 28 apatite-OH-zs -51.78 -54.00 -2.22 -0.171 0.83734E+04 29 apatite-Cl-zs -58.52 -61.80 -3.28 -0.273 0.12385E+05 30 aragonite -4.76 -8.55 -3.79 -1.262 0.14298E+05 31 brucite 5.75 3.47 -2.28 -0.456 0.86170E+04 32 calcite -4.87 -8.55 -3.68 -1.226 0.13888E+05 33 carnegieite-low 0.39 -1.43 -1.82 -0.260 0.68831E+04 34 carnegieite-high 0.48 -1.43 -1.91 -0.273 0.72208E+04 35 carpholite-Mg -5.89 -7.99 -2.10 -0.140 0.79403E+04 36 carpholite-Fe -7.30 -10.08 -2.78 -0.186 0.10508E+05 37 celadonite -0.40 -2.53 -2.12 -0.125 0.80162E+04 38 celadonite-Fe -1.85 -4.61 -2.76 -0.162 0.10420E+05 39 chrysotile 10.08 7.66 -2.42 -0.201 0.91204E+04 41 clinochlore 5.95 4.51 -1.44 -0.045 0.54294E+04 42 daphnite -1.38 -5.93 -4.54 -0.142 0.17146E+05 44 chlorite-Al-free 20.32 15.33 -4.99 -0.208 0.18856E+05 45 chloritoid-Mg -5.19 -6.62 -1.43 -0.095 0.54001E+04 46 chloritoid-Fe -7.21 -8.71 -1.50 -0.100 0.56555E+04 47 chloritoid-Mn -5.07 -6.69 -1.62 -0.108 0.61137E+04 49 coesite -1.07 -1.37 -0.30 -0.099 0.11205E+04 50 cordierite-H -16.23 -17.35 -1.12 -0.040 0.42239E+04 51 cordierite-Fe -18.94 -21.52 -2.58 -0.089 0.97364E+04 52 cordierite-Mn -14.59 -17.48 -2.89 -0.100 0.10903E+05 53 corundum -7.93 -8.72 -0.80 -0.072 0.30074E+04 55 cristobalite -1.32 -1.37 -0.05 -0.016 0.18063E+03 56 cummingtonite 15.70 13.33 -2.37 -0.064 0.89451E+04 58 cymrite-K -2.27 -4.63 -2.36 -0.197 0.89057E+04 60 diaspore -3.48 -4.36 -0.88 -0.147 0.33379E+04 62 diopside 5.64 4.14 -1.50 -0.150 0.56693E+04 63 hedenbergite 4.17 2.06 -2.11 -0.211 0.79765E+04 65 eastonite -3.61 -5.05 -1.44 -0.055 0.54460E+04 66 enstatite 5.11 4.20 -0.91 -0.091 0.34324E+04 67 clinoenstatite-HiP 5.62 4.20 -1.41 -0.141 0.53425E+04 68 clinoenstatite 5.09 4.20 -0.89 -0.089 0.33619E+04 69 protoenstatite 5.25 4.20 -1.05 -0.105 0.39478E+04 70 epidote -2.89 -5.58 -2.70 -0.131 0.10178E+05 71 clinozoisite -7.29 -10.37 -3.07 -0.140 0.11608E+05 72 epidote-Fe 3.23 -0.80 -4.02 -0.209 0.15192E+05 73 fayalite 2.67 1.39 -1.28 -0.182 0.48155E+04 74 ferrosilite 1.40 0.03 -1.38 -0.138 0.51970E+04 75 forsterite 6.80 5.57 -1.23 -0.176 0.46412E+04 76 gedrite -5.92 -8.31 -2.39 -0.065 0.90134E+04 78 gibbsite -1.84 -4.36 -2.52 -0.360 0.95160E+04 79 glaucophane 2.46 -0.67 -3.12 -0.084 0.11798E+05 81 goethite 1.37 0.42 -0.95 -0.205 0.35882E+04 83 greenalite 5.02 1.41 -3.62 -0.301 0.13658E+05 84 grunerite 3.09 -1.27 -4.37 -0.118 0.16484E+05 85 halite -1.46 -3.50 -2.04 -1.022 0.77151E+04 86 hematite 1.20 0.85 -0.35 -0.042 0.13230E+04 87 heulandite -11.55 -14.89 -3.34 -0.152 0.12620E+05 88 hercynite -5.93 -7.34 -1.41 -0.094 0.53244E+04 91 jadeite -1.11 -2.80 -1.69 -0.169 0.63882E+04 93 kalsilite -0.23 -1.89 -1.66 -0.237 0.62600E+04 94 kaolinite -8.66 -11.46 -2.80 -0.254 0.10561E+05 95 kyanite -9.31 -10.09 -0.78 -0.078 0.29497E+04 97 laumontite -6.97 -10.79 -3.81 -0.254 0.14388E+05 98 lawsonite -4.34 -8.05 -3.70 -0.247 0.13986E+05 99 leucite -2.27 -3.26 -0.99 -0.099 0.37451E+04 101 lizardite 10.24 7.66 -2.58 -0.215 0.97232E+04 102 magnesite -5.52 -8.49 -2.97 -0.990 0.11216E+05 103 magnetite 2.66 2.23 -0.43 -0.035 0.16374E+04 104 minnesotaite 1.03 -1.33 -2.36 -0.139 0.89072E+04 105 minnesotaite-Mg 7.20 4.93 -2.27 -0.133 0.85591E+04 106 magnesioferrite 5.82 4.31 -1.51 -0.123 0.56847E+04 108 manganosite 5.66 3.40 -2.26 -0.565 0.85382E+04 109 margarite -14.59 -16.77 -2.18 -0.087 0.82310E+04 113 monticellite 9.20 5.51 -3.70 -0.528 0.13952E+05 115 mullite-Si -8.70 -10.09 -1.39 -0.139 0.52356E+04 116 muscovite -12.44 -13.35 -0.91 -0.054 0.34486E+04 117 paragonite -11.75 -12.89 -1.14 -0.067 0.43087E+04 118 nepheline 0.09 -1.43 -1.52 -0.217 0.57314E+04 119 osumilite(2) -11.72 -13.88 -2.16 -0.045 0.81524E+04 120 osumilite-Fe -25.87 -28.88 -3.00 -0.063 0.11338E+05 121 pargasite 8.13 3.70 -4.43 -0.117 0.16741E+05 122 periclase 5.97 3.47 -2.50 -0.625 0.94388E+04 123 periclase-Fe 3.32 1.38 -1.94 -0.485 0.73182E+04 124 perovskite-Al -6.16 -8.72 -2.56 -0.233 0.96704E+04 129 phlogopite-Na 7.15 6.23 -0.92 -0.051 0.34686E+04 131 prehnite -2.35 -6.01 -3.66 -0.215 0.13814E+05 132 prehnite-Fe 2.46 -1.22 -3.68 -0.221 0.13890E+05 135 px-Mg-tschermaks -4.53 -6.62 -2.09 -0.149 0.78951E+04 136 px-Ca-tschermaks -3.81 -6.68 -2.87 -0.205 0.10823E+05 138 pyrrhotite -8.70 -9.45 -0.75 -0.249 0.28191E+04 139 pyrrhotiteFe0.875 -9.52 -9.86 -0.34 -0.126 0.12947E+04 140 pyrophyllite -12.72 -14.19 -1.47 -0.092 0.55542E+04 143 riebeckite 5.96 2.64 -3.32 -0.091 0.12522E+05 144 ringwoodite-Fe 3.68 1.39 -2.28 -0.326 0.86165E+04 145 ringwoodite-Mg 10.00 5.57 -4.44 -0.634 0.16748E+05 146 rhodochrosite -5.56 -8.56 -3.00 -0.999 0.11315E+05 147 rhodonite 2.64 2.03 -0.61 -0.122 0.22982E+04 148 sanidine -4.08 -4.63 -0.55 -0.042 0.20679E+04 150 siderite -7.42 -10.57 -3.15 -1.051 0.11907E+05 151 sillimanite -9.43 -10.09 -0.66 -0.066 0.24760E+04 153 spinel -3.70 -5.26 -1.56 -0.104 0.58845E+04 160 stilpnomelane-Mg 1.79 -0.41 -2.20 -0.066 0.83042E+04 161 stishovite 1.64 -1.37 -3.00 -1.001 0.11343E+05 162 sudoite-Fe -14.04 -18.79 -4.75 -0.153 0.17934E+05 163 sudoite -11.72 -14.62 -2.89 -0.093 0.10919E+05 164 sulfur -11.27 -12.74 -1.48 -0.455 0.55825E+04 165 sylvite -1.36 -3.96 -2.60 -1.300 0.98153E+04 166 talc 5.44 4.93 -0.51 -0.030 0.19330E+04 167 talc-Fe 2.47 -1.33 -3.79 -0.223 0.14319E+05 168 talc-tschermaks -4.12 -5.89 -1.77 -0.104 0.66887E+04 170 tephroite 6.91 5.43 -1.48 -0.212 0.55998E+04 173 topaz-H -7.38 -10.09 -2.71 -0.246 0.10226E+05 174 tremolite 16.08 13.22 -2.87 -0.077 0.10818E+05 176 troilite-low -8.61 -9.45 -0.84 -0.278 0.31531E+04 177 tschermakite -4.69 -8.43 -3.74 -0.101 0.14115E+05 180 wadsleyite-Fe 3.53 1.39 -2.14 -0.306 0.80783E+04 181 wadsleyite-Mg 9.05 5.57 -3.48 -0.497 0.13147E+05 182 wairakite -8.86 -10.78 -1.93 -0.113 0.72759E+04 183 walstromite 4.71 2.04 -2.66 -0.533 0.10061E+05 184 wollastonite 4.28 2.04 -2.23 -0.447 0.84307E+04 185 pseudo-wollastonite 4.40 2.04 -2.35 -0.471 0.88884E+04 186 zoisite -7.34 -10.37 -3.03 -0.138 0.11425E+05 189 beidellite-Ca -12.77 -14.62 -1.85 -0.114 0.69799E+04 190 beidellite-H -12.82 -15.18 -2.36 -0.151 0.89246E+04 191 beidellite-K -11.77 -13.91 -2.14 -0.131 0.80751E+04 192 beidellite-Mg -13.01 -14.61 -1.60 -0.099 0.60394E+04 193 beidellite-Na -11.72 -13.76 -2.04 -0.125 0.77196E+04 194 bornite -55.97 -56.20 -0.23 -0.017 0.86905E+03 196 chalcocite -14.71 -16.15 -1.44 -0.359 0.54284E+04 197 covellite -13.12 -14.45 -1.33 -0.507 0.50218E+04 199 montmorillonite-Ca -9.66 -11.05 -1.38 -0.085 0.52133E+04 200 montmorillonite-K -8.95 -10.34 -1.39 -0.085 0.52661E+04 201 montmorillonite-Mg -9.87 -11.04 -1.17 -0.072 0.44051E+04 202 montmorillonite-Na -8.62 -10.19 -1.57 -0.096 0.59318E+04 203 nontronite-Ca -3.37 -5.05 -1.67 -0.109 0.63161E+04 204 nontronite-H -3.43 -5.61 -2.18 -0.146 0.82317E+04 205 nontronite-K -2.38 -4.34 -1.96 -0.126 0.74033E+04 206 nontronite-Mg -3.58 -5.04 -1.46 -0.094 0.54947E+04 207 nontronite-Na -2.32 -4.19 -1.87 -0.120 0.70595E+04 212 gypsum -12.81 -15.08 -2.27 -0.568 0.85727E+04 229 alabandite -6.43 -7.43 -1.00 -0.334 0.37786E+04 231 anglesite -15.41 -17.71 -2.30 -1.150 0.86839E+04 235 boehmite -3.17 -4.36 -1.19 -0.198 0.44810E+04 239 copper,native 1.69 -1.70 -3.40 -1.182 0.12827E+05 241 ferrous-oxide 2.38 1.38 -1.00 -0.250 0.37753E+04 243 silver,native 0.39 -3.42 -3.81 -1.325 0.14378E+05 245 litharge 5.43 0.78 -4.65 -1.162 0.17555E+05 253 wurtzite -10.20 -11.02 -0.82 -0.273 0.30896E+04 254 zincite 2.45 -0.19 -2.64 -0.660 0.99605E+04 255 an20ab80 -4.84 -4.94 -0.10 -0.008 0.37041E+03 256 an25ab75 -5.02 -5.14 -0.11 -0.009 0.41891E+03 257 an30ab70 -5.20 -5.33 -0.13 -0.010 0.48761E+03 258 tr.625ac.25prg.125 10.84 9.42 -1.42 -0.038 0.53656E+04 Calculations done for 552.0000 Deg. C; 967.0000 bar Temperature changed by -1.000 degrees to 551.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 45 Loop limit = 500 Temperature = 551.00 C Pressure = 956.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5514E+02 kg liquid = 0.9933E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9969 Stoichiometric ionic strength = .3271980E+01 Osmotic coef. = 0.0000 True ionic strength = .1540237E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.49594E-05 -5.3046 0.83741E-06 -6.0771 0.16885E+00 -0.7725 2 H2O 0.99693E+00 -0.0013 0.99693E+00 -0.0013 3 Cl- 0.12978E+00 -0.8868 0.18134E-01 -1.7415 0.13973E+00 -0.8547 4 SO4-- 0.43491E-03 -3.3616 0.43036E-06 -6.3662 0.98954E-03 -3.0046 5 HCO3- 0.81338E-05 -5.0897 0.12344E-05 -5.9085 0.15176E+00 -0.8188 6 HS- 0.11921E-03 -3.9237 0.16810E-04 -4.7744 0.14101E+00 -0.8508 7 H4SiO4 0.41935E-01 -1.3774 0.41935E-01 -1.3774 0.10000E+01 0.0000 8 Al+++ 0.22633E-15 -15.6453 0.29402E-22 -22.5316 0.12991E-06 -6.8864 9 Ca++ 0.23994E-05 -5.6199 0.18451E-08 -8.7340 0.76900E-03 -3.1141 10 Mg++ 0.32125E-05 -5.4932 0.19835E-08 -8.7026 0.61743E-03 -3.2094 11 Fe++ 0.26751E-07 -7.5727 0.17459E-10 -10.7580 0.65267E-03 -3.1853 12 K+ 0.36333E-01 -1.4397 0.56617E-02 -2.2471 0.15583E+00 -0.8074 13 Na+ 0.11580E+00 -0.9363 0.16369E-01 -1.7860 0.14136E+00 -0.8497 14 Mn++ 0.26042E-05 -5.5843 0.17701E-08 -8.7520 0.67972E-03 -3.1677 15 Zn++ 0.72086E-09 -9.1422 0.47048E-12 -12.3275 0.65267E-03 -3.1853 16 Cu+ 0.12842E-07 -7.8914 0.18099E-08 -8.7423 0.14094E+00 -0.8510 17 Pb++ 0.48587E-08 -8.3135 0.42477E-11 -11.3718 0.87424E-03 -3.0584 18 Ag+ 0.19430E-09 -9.7115 0.29745E-10 -10.5266 0.15309E+00 -0.8151 19 Ba++ 0.10436E-06 -6.9815 0.98974E-10 -10.0045 0.94837E-03 -3.0230 20 HPO4-- 0.27963E-08 -8.5534 0.27828E-11 -11.5555 0.99519E-03 -3.0021 21 HSiO3- 0.13301E-05 -5.8761 0.18586E-06 -6.7308 0.13973E+00 -0.8547 22 Ca(HSiO3)+ 0.42250E-08 -8.3742 0.66491E-09 -9.1772 0.15738E+00 -0.8031 23 Mg(HSiO3)+ 0.15459E-08 -8.8108 0.24329E-09 -9.6139 0.15738E+00 -0.8031 24 NaHSiO3,aq 0.18063E-05 -5.7432 0.18063E-05 -5.7432 0.10000E+01 0.0000 28 AgCl,aq 0.76203E-07 -7.1180 0.76203E-07 -7.1180 0.10000E+01 0.0000 29 AgCl2- 0.35266E-05 -5.4526 0.49275E-06 -6.3074 0.13973E+00 -0.8547 30 AgCl3-2 0.16157E-05 -5.7916 0.14650E-08 -8.8342 0.90674E-03 -3.0425 31 AgCl4-3 0.35343E-05 -5.4517 0.39869E-12 -12.3994 0.11280E-06 -6.9477 34 Ag(HS),aq 0.14245E-08 -8.8463 0.14245E-08 -8.8463 0.10000E+01 0.0000 35 Ag(HS)2- 0.46509E-08 -8.3325 0.64985E-09 -9.1872 0.13973E+00 -0.8547 36 AlO+ 0.15573E-10 -10.8076 0.24508E-11 -11.6107 0.15738E+00 -0.8031 38 HAlO2,aq 0.46265E-08 -8.3347 0.46265E-08 -8.3347 0.10000E+01 0.0000 39 AlO2- 0.11896E-04 -4.9246 0.14390E-05 -5.8419 0.12096E+00 -0.9174 41 Ba(HCO3)+ 0.16740E-06 -6.7762 0.27555E-07 -7.5598 0.16461E+00 -0.7836 42 BaCl+ 0.71374E-05 -5.1465 0.11233E-05 -5.9495 0.15738E+00 -0.8031 43 CH4,aq 0.13162E-08 -8.8807 0.15511E-08 -8.8094 0.11785E+01 0.0713 48 CO,aq 0.43016E-03 -3.3664 0.43016E-03 -3.3664 0.10000E+01 0.0000 49 CO2,aq 0.26735E+01 0.4271 0.31506E+01 0.4984 0.11785E+01 0.0713 50 CO3-2 0.58039E-10 -10.2363 0.52626E-13 -13.2788 0.90674E-03 -3.0425 52 Ca(HCO3)+ 0.79009E-07 -7.1023 0.12434E-07 -7.9054 0.15738E+00 -0.8031 53 CaCl+ 0.70777E-04 -4.1501 0.11139E-04 -4.9532 0.15738E+00 -0.8031 54 CaCl2,aq 0.69144E-04 -4.1602 0.69144E-04 -4.1602 0.10000E+01 0.0000 55 CaOH+ 0.12778E-06 -6.8935 0.20110E-07 -7.6966 0.15738E+00 -0.8031 56 CaSO4,aq 0.18978E-06 -6.7218 0.18978E-06 -6.7218 0.10000E+01 0.0000 57 HCl,aq 0.43883E-02 -2.3577 0.43883E-02 -2.3577 0.10000E+01 0.0000 66 CuCl,aq 0.20310E-04 -4.6923 0.20310E-04 -4.6923 0.10000E+01 0.0000 67 CuCl2- 0.74172E-04 -4.1298 0.10364E-04 -4.9845 0.13973E+00 -0.8547 68 CuCl3-2 0.18914E-05 -5.7232 0.17150E-08 -8.7657 0.90674E-03 -3.0425 74 FeCl+ 0.24175E-06 -6.6166 0.38046E-07 -7.4197 0.15738E+00 -0.8031 75 FeCl2,aq 0.21717E-02 -2.6632 0.21717E-02 -2.6632 0.10000E+01 0.0000 77 FeO,aq 0.45506E-07 -7.3419 0.45506E-07 -7.3419 0.10000E+01 0.0000 78 FeOH+ 0.19354E-07 -7.7132 0.30458E-08 -8.5163 0.15738E+00 -0.8031 79 HFeO2- 0.52060E-08 -8.2835 0.72742E-09 -9.1382 0.13973E+00 -0.8547 82 FeO2- 0.32205E-08 -8.4921 0.44998E-09 -9.3468 0.13973E+00 -0.8547 83 HFeO2,aq 0.26387E-09 -9.5786 0.26387E-09 -9.5786 0.10000E+01 0.0000 84 H2,aq 0.41816E-02 -2.3787 0.49278E-02 -2.3073 0.11785E+01 0.0713 85 KCl,aq 0.71330E-01 -1.1467 0.71330E-01 -1.1467 0.10000E+01 0.0000 86 KHSO4,aq 0.12742E-01 -1.8947 0.12742E-01 -1.8947 0.10000E+01 0.0000 87 KOH,aq 0.13121E-05 -5.8820 0.13121E-05 -5.8820 0.10000E+01 0.0000 88 KSO4- 0.51548E-02 -2.2878 0.72026E-03 -3.1425 0.13973E+00 -0.8547 90 Mg(HCO3)+ 0.27322E-07 -7.5635 0.42998E-08 -8.3666 0.15738E+00 -0.8031 91 MgCl+ 0.16974E-04 -4.7702 0.26713E-05 -5.5733 0.15738E+00 -0.8031 92 MgOH+ 0.59984E-06 -6.2220 0.94400E-07 -7.0250 0.15738E+00 -0.8031 94 MnO,aq 0.81779E-07 -7.0874 0.81779E-07 -7.0874 0.10000E+01 0.0000 95 MnOH+ 0.20860E-06 -6.6807 0.32828E-07 -7.4838 0.15738E+00 -0.8031 97 HMnO2- 0.35415E-10 -10.4508 0.49484E-11 -11.3055 0.13973E+00 -0.8547 100 MnCl+ 0.11541E-02 -2.9378 0.18163E-03 -3.7408 0.15738E+00 -0.8031 101 MnSO4,aq 0.18846E-06 -6.7248 0.18846E-06 -6.7248 0.10000E+01 0.0000 102 NaCl,aq 0.44251E+00 -0.3541 0.44251E+00 -0.3541 0.10000E+01 0.0000 103 NaOH,aq 0.17257E-05 -5.7630 0.17257E-05 -5.7630 0.10000E+01 0.0000 105 OH- 0.75468E-05 -5.1222 0.91287E-06 -6.0396 0.12096E+00 -0.9174 110 HPO3-2 0.14789E-10 -10.8301 0.13410E-13 -13.8726 0.90674E-03 -3.0425 111 H3PO3,aq 0.12930E-09 -9.8884 0.12930E-09 -9.8884 0.10000E+01 0.0000 112 H2PO3- 0.17413E-08 -8.7591 0.24331E-09 -9.6138 0.13973E+00 -0.8547 113 H3PO4,aq 0.18356E-05 -5.7362 0.18356E-05 -5.7362 0.10000E+01 0.0000 114 H2PO4- 0.16514E-05 -5.7821 0.24392E-06 -6.6128 0.14770E+00 -0.8306 116 H4P2O7,aq 0.31555E-09 -9.5009 0.31555E-09 -9.5009 0.10000E+01 0.0000 117 H3P2O7- 0.12139E-08 -8.9158 0.16961E-09 -9.7705 0.13973E+00 -0.8547 118 H2P2O7-2 0.39852E-06 -6.3996 0.36135E-09 -9.4421 0.90674E-03 -3.0425 119 HP2O7-3 0.11847E-06 -6.9264 0.13364E-13 -13.8741 0.11280E-06 -6.9477 121 PbCl+ 0.11833E-05 -5.9269 0.18622E-06 -6.7300 0.15738E+00 -0.8031 122 PbCl2,aq 0.81947E-04 -4.0865 0.81947E-04 -4.0865 0.10000E+01 0.0000 123 PbCl3- 0.10240E-03 -3.9897 0.14308E-04 -4.8444 0.13973E+00 -0.8547 124 PbCl4-2 0.23788E-04 -4.6236 0.21569E-07 -7.6662 0.90674E-03 -3.0425 125 PbO,aq 0.61606E-08 -8.2104 0.61606E-08 -8.2104 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11363E-03 -3.9445 0.11363E-03 -3.9445 0.10000E+01 0.0000 128 Pb(HS)3- 0.13542E-04 -4.8683 0.18922E-05 -5.7230 0.13973E+00 -0.8547 129 H2S,aq 0.10588E+01 0.0248 0.12477E+01 0.0961 0.11785E+01 0.0713 130 S2-2 0.18038E-07 -7.7438 0.16356E-10 -10.7863 0.90674E-03 -3.0425 131 S3-2 0.16879E-08 -8.7726 0.15305E-11 -11.8152 0.90674E-03 -3.0425 132 S3- 0.87671E-02 -2.0571 0.12250E-02 -2.9119 0.13973E+00 -0.8547 133 S4-2 0.13505E-09 -9.8695 0.12245E-12 -12.9120 0.90674E-03 -3.0425 135 SO2,aq 0.29364E+00 -0.5322 0.29364E+00 -0.5322 0.10000E+01 0.0000 136 SO3-2 0.10162E-08 -8.9930 0.15576E-11 -11.8076 0.15328E-02 -2.8145 137 HSO3- 0.23078E-03 -3.6368 0.32246E-04 -4.4915 0.13973E+00 -0.8547 138 HSO4- 0.82892E-02 -2.0815 0.13458E-02 -2.8710 0.16236E+00 -0.7895 140 S2O3-2 0.84376E-06 -6.0738 0.76507E-09 -9.1163 0.90674E-03 -3.0425 141 HS2O3- 0.36458E-06 -6.4382 0.50942E-07 -7.2929 0.13973E+00 -0.8547 142 H2S2O3,aq 0.41139E-07 -7.3858 0.41139E-07 -7.3858 0.10000E+01 0.0000 150 S4O6-2 0.70706E-09 -9.1505 0.64111E-12 -12.1931 0.90674E-03 -3.0425 152 ZnCl+ 0.13396E-03 -3.8730 0.21081E-04 -4.6761 0.15738E+00 -0.8031 153 ZnCl2,aq 0.53741E-03 -3.2697 0.53741E-03 -3.2697 0.10000E+01 0.0000 154 ZnCl3- 0.35777E-04 -4.4464 0.49990E-05 -5.3011 0.13973E+00 -0.8547 155 ZnO,aq 0.24048E-07 -7.6189 0.24048E-07 -7.6189 0.10000E+01 0.0000 156 ZnOH+ 0.93142E-06 -6.0309 0.14658E-06 -6.8339 0.15738E+00 -0.8031 158 HZnO2- 0.18019E-09 -9.7443 0.25177E-10 -10.5990 0.13973E+00 -0.8547 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4959443E-05 0.4293945E+01 0.3543584E+04 0.0000 2 H2O 0.1000000E+01 0.5252302E+02 0.7747164E+06 0.0000 3 Cl- 0.1297802E+00 0.6558219E+00 0.1903665E+05 4.3356 4 SO4-- 0.4349093E-03 0.2513526E+00 0.1976900E+05 5.7880 5 HCO3- 0.8133786E-05 0.2673894E+01 0.1335821E+06 0.1685 6 HS- 0.1192080E-03 0.1154616E+01 0.3126438E+05 1.3026 7 H4SiO4 0.4193523E-01 0.4193837E-01 0.3300321E+04 -1.3774 8 Al+++ 0.2263282E-15 0.1190088E-04 0.2629037E+00 -4.3004 9 Ca++ 0.2399420E-05 0.1427209E-03 0.4683226E+01 3.4202 10 Mg++ 0.3212512E-05 0.2081507E-04 0.4143336E+00 3.4516 11 Fe++ 0.2675087E-07 0.2171993E-02 0.9931386E+02 1.3962 12 K+ 0.3633348E-01 0.1255624E+00 0.4019853E+04 3.8300 13 Na+ 0.1158004E+00 0.5583121E+00 0.1050906E+05 4.2911 14 Mn++ 0.2604153E-05 0.1157195E-02 0.5205124E+02 3.4021 15 Zn++ 0.7208580E-09 0.7080998E-03 0.3789872E+02 -0.1733 16 Cu+ 0.1284172E-07 0.9638684E-04 0.5014372E+01 -2.6653 17 Pb++ 0.4858693E-08 0.3364977E-03 0.5708243E+02 0.7823 18 Ag+ 0.1942986E-09 0.8759090E-05 0.7735907E+00 -4.4495 19 Ba++ 0.1043625E-06 0.7409137E-05 0.8331367E+00 2.1496 20 HPO4-- 0.2796265E-08 0.4528745E-05 0.3558817E+00 0.5986 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265390E+01 -.3027698E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5217374E+02 -.2089602E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2496811E+00 0.2041687E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1146938E+01 0.1320595E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4165948E-01 0.1019348E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1182174E-04 0.6827178E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1417718E-03 0.3861381E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2157549E-02 0.6609205E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247274E+00 0.6827178E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7033910E-03 0.1595944E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.9574587E-04 0.3038638E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3342600E-03 0.5912657E-05 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7359866E-05 0.4801259E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.4498629E-05 0.4068872E-05 0.0000000E+00 Chg. balance for solid moles: -.2914E-18 Mass of aqueous solution: 0.121325E+04 g Temperature = 551.00 C Pressure = 956.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3794E-03 -3.421 0.5165E-01 -1.287 0.7149 0.1743E-01 apatite-OH 0.1356E-05 -5.868 0.6813E-03 -3.167 0.9431E-02 0.2165E-03 microcline 0.6827E-03 -3.166 0.1900 -0.721 2.631 0.7423E-01 pyrite 0.6305E-02 -2.200 0.7565 -0.121 10.47 0.1509 quartz 0.9989E-01 -1.000 6.001 0.778 83.07 2.266 barite 0.4801E-04 -4.319 0.1121E-01 -1.951 0.1551 0.2501E-02 chalcopyrite 0.3039E-03 -3.517 0.5576E-01 -1.254 0.7719 0.1302E-01 galena 0.5913E-05 -5.228 0.1415E-02 -2.849 0.1958E-01 0.1862E-03 sphalerite 0.1596E-02 -2.797 0.1555 -0.808 2.152 0.3803E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.223934 g Volume = 2.562858 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.10 -15.10 -0.00 -0.000 0.66990E-11 27 apatite-OH -54.03 -54.03 0.00 0.000 0.00000E+00 112 microcline -4.60 -4.60 0.00 0.000 -0.10048E-10 137 pyrite -22.22 -22.22 0.00 0.000 0.00000E+00 141 quartz -1.37 -1.37 0.00 0.000 0.00000E+00 234 barite -16.37 -16.37 -0.00 -0.000 0.13398E-10 237 chalcopyrite -23.93 -23.93 0.00 0.000 -0.13398E-10 242 galena -10.07 -10.07 0.00 0.000 -0.66990E-11 252 sphalerite -11.02 -11.02 0.00 0.000 -0.66990E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.26 -0.00 -0.26 -0.257 0.96850E+03 2.724 2 CO2,gas -10.26 -11.98 -1.72 -0.575 0.65011E+04 1.257 3 CH4,gas 6.80 -4.32 -11.12 -2.780 0.41935E+05 -8.140 4 H2,gas 6.01 1.92 -4.10 -2.341 0.15453E+05 -1.117 5 H2S,gas -8.55 -10.85 -2.30 -1.152 0.86906E+04 0.676 6 CO,gas -3.95 -10.07 -6.12 -1.883 0.23079E+05 -3.139 7 SO3,gas -7.76 -18.52 -10.76 -2.691 0.40589E+05 -7.782 8 O2,gas 17.08 -3.83 -20.92 -13.946 0.78889E+05 -17.939 9 HCl,gas -6.22 -7.82 -1.60 -0.798 0.60225E+04 -1.597 10 acmite 3.61 1.98 -1.64 -0.170 0.61764E+04 12 akimotoite 6.40 2.08 -4.33 -0.865 0.16319E+05 13 akimotoite-Fe 4.23 0.02 -4.21 -0.842 0.15883E+05 14 albite-high -3.97 -4.14 -0.17 -0.013 0.62611E+03 15 albite -3.98 -4.14 -0.16 -0.012 0.60009E+03 16 almandine -6.22 -8.54 -2.32 -0.116 0.87546E+04 17 pyrope 0.66 -2.38 -3.04 -0.152 0.11467E+05 18 analcite -1.75 -2.76 -1.01 -0.112 0.38123E+04 19 andalusite -9.37 -9.98 -0.61 -0.061 0.22918E+04 24 anorthite -6.99 -7.94 -0.94 -0.073 0.35568E+04 25 anthophyllite 15.75 13.15 -2.59 -0.070 0.97805E+04 26 anthophyllite-Fe 2.60 -1.24 -3.84 -0.104 0.14474E+05 28 apatite-OH-zs -51.81 -54.03 -2.22 -0.171 0.83752E+04 29 apatite-Cl-zs -58.57 -61.85 -3.28 -0.273 0.12374E+05 30 aragonite -4.77 -8.57 -3.80 -1.266 0.14322E+05 31 brucite 5.77 3.45 -2.33 -0.465 0.87695E+04 32 calcite -4.88 -8.57 -3.69 -1.230 0.13911E+05 33 carnegieite-low 0.44 -1.39 -1.83 -0.261 0.68856E+04 34 carnegieite-high 0.53 -1.39 -1.92 -0.274 0.72260E+04 35 carpholite-Mg -5.77 -7.91 -2.13 -0.142 0.80498E+04 36 carpholite-Fe -7.18 -9.96 -2.78 -0.185 0.10484E+05 37 celadonite -0.36 -2.52 -2.17 -0.127 0.81666E+04 38 celadonite-Fe -1.81 -4.58 -2.77 -0.163 0.10440E+05 39 chrysotile 10.14 7.60 -2.54 -0.212 0.95784E+04 41 clinochlore 6.15 4.52 -1.63 -0.051 0.61538E+04 42 daphnite -1.20 -5.76 -4.56 -0.143 0.17205E+05 45 chloritoid-Mg -5.07 -6.53 -1.46 -0.098 0.55178E+04 46 chloritoid-Fe -7.09 -8.59 -1.49 -0.100 0.56356E+04 47 chloritoid-Mn -4.95 -6.58 -1.63 -0.109 0.61383E+04 49 coesite -1.08 -1.37 -0.30 -0.099 0.11194E+04 50 cordierite-H -16.00 -17.18 -1.19 -0.042 0.44821E+04 51 cordierite-Fe -18.72 -21.29 -2.58 -0.089 0.97226E+04 52 cordierite-Mn -14.37 -17.28 -2.91 -0.100 0.10975E+05 53 corundum -7.82 -8.60 -0.79 -0.072 0.29773E+04 55 cristobalite -1.33 -1.37 -0.05 -0.016 0.18028E+03 56 cummingtonite 15.82 13.15 -2.67 -0.072 0.10051E+05 58 cymrite-K -2.24 -4.60 -2.36 -0.197 0.89077E+04 60 diaspore -3.42 -4.30 -0.88 -0.147 0.33168E+04 62 diopside 5.67 4.12 -1.55 -0.155 0.58497E+04 63 hedenbergite 4.19 2.06 -2.13 -0.213 0.80237E+04 65 eastonite -3.41 -4.93 -1.52 -0.058 0.57281E+04 66 enstatite 5.15 4.15 -0.99 -0.099 0.37519E+04 67 clinoenstatite-HiP 5.65 4.15 -1.50 -0.150 0.56618E+04 68 clinoenstatite 5.13 4.15 -0.98 -0.098 0.36808E+04 69 protoenstatite 5.28 4.15 -1.13 -0.113 0.42675E+04 70 epidote -2.75 -5.46 -2.71 -0.131 0.10206E+05 71 clinozoisite -7.12 -10.19 -3.08 -0.140 0.11599E+05 72 epidote-Fe 3.33 -0.72 -4.04 -0.210 0.15252E+05 73 fayalite 2.71 1.41 -1.29 -0.184 0.48665E+04 74 ferrosilite 1.43 0.04 -1.39 -0.139 0.52474E+04 75 forsterite 6.84 5.53 -1.32 -0.188 0.49609E+04 76 gedrite -5.63 -8.21 -2.58 -0.070 0.97402E+04 78 gibbsite -1.79 -4.30 -2.52 -0.359 0.94884E+04 79 glaucophane 2.58 -0.67 -3.25 -0.088 0.12259E+05 81 goethite 1.39 0.44 -0.96 -0.207 0.36048E+04 83 greenalite 5.07 1.43 -3.64 -0.303 0.13714E+05 84 grunerite 3.18 -1.24 -4.41 -0.119 0.16649E+05 85 halite -1.48 -3.53 -2.05 -1.024 0.77197E+04 86 hematite 1.23 0.87 -0.36 -0.044 0.13632E+04 87 heulandite -11.48 -14.82 -3.34 -0.152 0.12597E+05 88 hercynite -5.80 -7.21 -1.41 -0.094 0.53207E+04 91 jadeite -1.07 -2.76 -1.69 -0.169 0.63867E+04 93 kalsilite -0.19 -1.85 -1.66 -0.237 0.62644E+04 94 kaolinite -8.57 -11.36 -2.78 -0.253 0.10502E+05 95 kyanite -9.21 -9.98 -0.77 -0.077 0.29184E+04 97 laumontite -6.88 -10.69 -3.81 -0.254 0.14358E+05 98 lawsonite -4.24 -7.94 -3.70 -0.247 0.13958E+05 99 leucite -2.23 -3.22 -0.99 -0.099 0.37502E+04 101 lizardite 10.30 7.60 -2.70 -0.225 0.10177E+05 102 magnesite -5.52 -8.53 -3.02 -1.006 0.11376E+05 103 magnetite 2.72 2.27 -0.45 -0.037 0.17034E+04 104 minnesotaite 1.06 -1.32 -2.38 -0.140 0.89691E+04 105 minnesotaite-Mg 7.24 4.85 -2.39 -0.141 0.90218E+04 106 magnesioferrite 5.88 4.32 -1.56 -0.127 0.58856E+04 108 manganosite 5.68 3.40 -2.28 -0.571 0.86072E+04 109 margarite -14.37 -16.54 -2.17 -0.087 0.81820E+04 113 monticellite 9.24 5.49 -3.75 -0.535 0.14132E+05 115 mullite-Si -8.60 -9.98 -1.38 -0.138 0.52059E+04 116 muscovite -12.30 -13.20 -0.90 -0.053 0.34115E+04 117 paragonite -11.61 -12.74 -1.13 -0.067 0.42701E+04 118 nepheline 0.13 -1.39 -1.52 -0.217 0.57338E+04 119 osumilite(2) -11.57 -13.85 -2.28 -0.048 0.86017E+04 120 osumilite-Fe -25.64 -28.64 -3.00 -0.063 0.11330E+05 121 pargasite 8.38 3.77 -4.61 -0.121 0.17396E+05 122 periclase 6.00 3.45 -2.55 -0.636 0.95979E+04 123 periclase-Fe 3.34 1.39 -1.95 -0.487 0.73454E+04 124 perovskite-Al -6.05 -8.60 -2.56 -0.232 0.96404E+04 129 phlogopite-Na 7.26 6.21 -1.04 -0.058 0.39402E+04 131 prehnite -2.23 -5.89 -3.66 -0.215 0.13815E+05 132 prehnite-Fe 2.54 -1.15 -3.69 -0.222 0.13927E+05 135 px-Mg-tschermaks -4.40 -6.53 -2.13 -0.152 0.80263E+04 136 px-Ca-tschermaks -3.69 -6.56 -2.87 -0.205 0.10814E+05 138 pyrrhotite -8.70 -9.46 -0.75 -0.251 0.28373E+04 139 pyrrhotiteFe0.875 -9.52 -9.87 -0.35 -0.128 0.13092E+04 140 pyrophyllite -12.64 -14.11 -1.46 -0.091 0.55105E+04 143 riebeckite 6.00 2.64 -3.36 -0.093 0.12659E+05 144 ringwoodite-Fe 3.71 1.41 -2.30 -0.328 0.86657E+04 145 ringwoodite-Mg 10.05 5.53 -4.53 -0.646 0.17065E+05 146 rhodochrosite -5.56 -8.58 -3.02 -1.006 0.11385E+05 147 rhodonite 2.65 2.03 -0.63 -0.126 0.23664E+04 148 sanidine -4.05 -4.60 -0.55 -0.042 0.20679E+04 150 siderite -7.43 -10.59 -3.16 -1.055 0.11932E+05 151 sillimanite -9.33 -9.98 -0.65 -0.065 0.24458E+04 153 spinel -3.56 -5.15 -1.59 -0.106 0.60134E+04 160 stilpnomelane-Mg 1.95 -0.45 -2.40 -0.072 0.90470E+04 161 stishovite 1.63 -1.37 -3.01 -1.002 0.11341E+05 162 sudoite-Fe -13.80 -18.55 -4.75 -0.153 0.17909E+05 163 sudoite -11.48 -14.44 -2.96 -0.095 0.11161E+05 164 sulfur -11.29 -12.77 -1.48 -0.455 0.55741E+04 165 sylvite -1.38 -3.99 -2.60 -1.302 0.98194E+04 166 talc 5.49 4.85 -0.64 -0.037 0.23964E+04 167 talc-Fe 2.50 -1.32 -3.81 -0.224 0.14382E+05 168 talc-tschermaks -3.98 -5.83 -1.85 -0.109 0.69643E+04 170 tephroite 6.95 5.43 -1.52 -0.217 0.57357E+04 173 topaz-H -7.28 -9.98 -2.70 -0.245 0.10182E+05 174 tremolite 16.18 13.09 -3.09 -0.083 0.11643E+05 176 troilite-low -8.61 -9.46 -0.84 -0.280 0.31700E+04 177 tschermakite -4.41 -8.27 -3.86 -0.104 0.14560E+05 180 wadsleyite-Fe 3.57 1.41 -2.16 -0.308 0.81290E+04 181 wadsleyite-Mg 9.10 5.53 -3.57 -0.510 0.13467E+05 182 wairakite -8.76 -10.69 -1.92 -0.113 0.72540E+04 183 walstromite 4.72 2.04 -2.67 -0.535 0.10082E+05 184 wollastonite 4.29 2.04 -2.24 -0.448 0.84515E+04 185 pseudo-wollastonite 4.41 2.04 -2.36 -0.473 0.89101E+04 186 zoisite -7.17 -10.19 -3.03 -0.138 0.11417E+05 189 beidellite-Ca -12.67 -14.51 -1.84 -0.114 0.69352E+04 190 beidellite-H -12.72 -15.07 -2.35 -0.150 0.88754E+04 191 beidellite-K -11.68 -13.81 -2.13 -0.130 0.80325E+04 192 beidellite-Mg -12.91 -14.50 -1.60 -0.099 0.60193E+04 193 beidellite-Na -11.62 -13.66 -2.04 -0.125 0.76774E+04 194 bornite -56.07 -56.29 -0.22 -0.017 0.83543E+03 196 chalcocite -14.75 -16.18 -1.43 -0.359 0.54082E+04 197 covellite -13.15 -14.47 -1.33 -0.505 0.50027E+04 199 montmorillonite-Ca -9.60 -10.98 -1.39 -0.086 0.52305E+04 200 montmorillonite-K -8.88 -10.28 -1.40 -0.086 0.52887E+04 201 montmorillonite-Mg -9.80 -10.98 -1.18 -0.073 0.44444E+04 202 montmorillonite-Na -8.55 -10.13 -1.58 -0.097 0.59506E+04 203 nontronite-Ca -3.35 -5.03 -1.68 -0.109 0.63440E+04 204 nontronite-H -3.41 -5.59 -2.19 -0.147 0.82543E+04 205 nontronite-K -2.36 -4.33 -1.97 -0.127 0.74334E+04 206 nontronite-Mg -3.55 -5.02 -1.47 -0.095 0.55456E+04 207 nontronite-Na -2.30 -4.18 -1.88 -0.121 0.70898E+04 212 gypsum -12.83 -15.10 -2.27 -0.568 0.85679E+04 229 alabandite -6.43 -7.45 -1.02 -0.340 0.38427E+04 231 anglesite -15.44 -17.74 -2.30 -1.150 0.86717E+04 235 boehmite -3.12 -4.30 -1.18 -0.197 0.44604E+04 239 copper,native 1.69 -1.71 -3.40 -1.182 0.12815E+05 241 ferrous-oxide 2.40 1.39 -1.01 -0.252 0.38037E+04 243 silver,native 0.38 -3.49 -3.87 -1.348 0.14613E+05 245 litharge 5.44 0.78 -4.66 -1.164 0.17560E+05 253 wurtzite -10.21 -11.02 -0.82 -0.273 0.30889E+04 254 zincite 2.47 -0.17 -2.64 -0.661 0.99679E+04 255 an20ab80 -4.80 -4.90 -0.10 -0.008 0.37028E+03 256 an25ab75 -4.97 -5.09 -0.11 -0.009 0.41899E+03 257 an30ab70 -5.15 -5.28 -0.13 -0.010 0.48704E+03 258 tr.625ac.25prg.125 10.95 9.36 -1.59 -0.043 0.60135E+04 Calculations done for 551.0000 Deg. C; 956.0000 bar Temperature changed by -1.000 degrees to 550.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 46 Loop limit = 500 Temperature = 550.00 C Pressure = 945.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5514E+02 kg liquid = 0.9934E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9969 Stoichiometric ionic strength = .3271739E+01 Osmotic coef. = 0.0000 True ionic strength = .1573146E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.50913E-05 -5.2932 0.82281E-06 -6.0847 0.16161E+00 -0.7915 2 H2O 0.99694E+00 -0.0013 0.99694E+00 -0.0013 3 Cl- 0.13269E+00 -0.8771 0.17625E-01 -1.7539 0.13282E+00 -0.8767 4 SO4-- 0.49884E-03 -3.3020 0.41262E-06 -6.3845 0.82715E-03 -3.0824 5 HCO3- 0.80955E-05 -5.0918 0.11709E-05 -5.9315 0.14463E+00 -0.8397 6 HS- 0.12159E-03 -3.9151 0.16304E-04 -4.7877 0.13408E+00 -0.8726 7 H4SiO4 0.41163E-01 -1.3855 0.41163E-01 -1.3855 0.10000E+01 0.0000 8 Al+++ 0.37385E-15 -15.4273 0.32031E-22 -22.4944 0.85679E-07 -7.0671 9 Ca++ 0.28588E-05 -5.5438 0.18231E-08 -8.7392 0.63771E-03 -3.1954 10 Mg++ 0.36422E-05 -5.4386 0.18524E-08 -8.7323 0.50859E-03 -3.2936 11 Fe++ 0.32445E-07 -7.4889 0.17472E-10 -10.7576 0.53853E-03 -3.2688 12 K+ 0.36978E-01 -1.4321 0.54955E-02 -2.2600 0.14862E+00 -0.8279 13 Na+ 0.11837E+00 -0.9268 0.15911E-01 -1.7983 0.13441E+00 -0.8716 14 Mn++ 0.30797E-05 -5.5115 0.17294E-08 -8.7621 0.56155E-03 -3.2506 15 Zn++ 0.87742E-09 -9.0568 0.47252E-12 -12.3256 0.53853E-03 -3.2688 16 Cu+ 0.13123E-07 -7.8820 0.17586E-08 -8.7548 0.13400E+00 -0.8729 17 Pb++ 0.56891E-08 -8.2450 0.41409E-11 -11.3829 0.72786E-03 -3.1380 18 Ag+ 0.16806E-09 -9.7745 0.24525E-10 -10.6104 0.14593E+00 -0.8359 19 Ba++ 0.12120E-06 -6.9165 0.95933E-10 -10.0180 0.79155E-03 -3.1015 20 HPO4-- 0.32494E-08 -8.4882 0.27035E-11 -11.5681 0.83202E-03 -3.0799 21 HSiO3- 0.13519E-05 -5.8691 0.17956E-06 -6.7458 0.13282E+00 -0.8767 22 Ca(HSiO3)+ 0.43254E-08 -8.3640 0.64943E-09 -9.1875 0.15014E+00 -0.8235 23 Mg(HSiO3)+ 0.15089E-08 -8.8213 0.22655E-09 -9.6448 0.15014E+00 -0.8235 24 NaHSiO3,aq 0.17888E-05 -5.7474 0.17888E-05 -5.7474 0.10000E+01 0.0000 28 AgCl,aq 0.64505E-07 -7.1904 0.64505E-07 -7.1904 0.10000E+01 0.0000 29 AgCl2- 0.30437E-05 -5.5166 0.40427E-06 -6.3933 0.13282E+00 -0.8767 30 AgCl3-2 0.15267E-05 -5.8163 0.11540E-08 -8.9378 0.75591E-03 -3.1215 31 AgCl4-3 0.41186E-05 -5.3852 0.30529E-12 -12.5153 0.74125E-07 -7.1300 34 Ag(HS),aq 0.12186E-08 -8.9141 0.12186E-08 -8.9141 0.10000E+01 0.0000 35 Ag(HS)2- 0.39917E-08 -8.3988 0.53019E-09 -9.2756 0.13282E+00 -0.8767 36 AlO+ 0.17005E-10 -10.7694 0.25531E-11 -11.5929 0.15014E+00 -0.8235 38 HAlO2,aq 0.47196E-08 -8.3261 0.47196E-08 -8.3261 0.10000E+01 0.0000 39 AlO2- 0.12327E-04 -4.9092 0.14112E-05 -5.8504 0.11449E+00 -0.9412 41 Ba(HCO3)+ 0.16730E-06 -6.7765 0.26310E-07 -7.5799 0.15726E+00 -0.8034 42 BaCl+ 0.72371E-05 -5.1404 0.10866E-05 -5.9639 0.15014E+00 -0.8235 43 CH4,aq 0.13021E-08 -8.8853 0.15331E-08 -8.8144 0.11774E+01 0.0709 48 CO,aq 0.42282E-03 -3.3738 0.42282E-03 -3.3738 0.10000E+01 0.0000 49 CO2,aq 0.26734E+01 0.4271 0.31475E+01 0.4980 0.11774E+01 0.0709 50 CO3-2 0.65701E-10 -10.1824 0.49664E-13 -13.3040 0.75591E-03 -3.1215 52 Ca(HCO3)+ 0.78878E-07 -7.1030 0.11843E-07 -7.9265 0.15014E+00 -0.8235 53 CaCl+ 0.72682E-04 -4.1386 0.10913E-04 -4.9621 0.15014E+00 -0.8235 54 CaCl2,aq 0.68911E-04 -4.1617 0.68911E-04 -4.1617 0.10000E+01 0.0000 55 CaOH+ 0.13038E-06 -6.8848 0.19575E-07 -7.7083 0.15014E+00 -0.8235 56 CaSO4,aq 0.19222E-06 -6.7162 0.19222E-06 -6.7162 0.10000E+01 0.0000 57 HCl,aq 0.45985E-02 -2.3374 0.45985E-02 -2.3374 0.10000E+01 0.0000 66 CuCl,aq 0.20246E-04 -4.6937 0.20246E-04 -4.6937 0.10000E+01 0.0000 67 CuCl2- 0.76033E-04 -4.1190 0.10099E-04 -4.9957 0.13282E+00 -0.8767 68 CuCl3-2 0.21247E-05 -5.6727 0.16061E-08 -8.7942 0.75591E-03 -3.1215 74 FeCl+ 0.25151E-06 -6.5994 0.37762E-07 -7.4229 0.15014E+00 -0.8235 75 FeCl2,aq 0.21264E-02 -2.6724 0.21264E-02 -2.6724 0.10000E+01 0.0000 77 FeO,aq 0.44689E-07 -7.3498 0.44689E-07 -7.3498 0.10000E+01 0.0000 78 FeOH+ 0.20008E-07 -7.6988 0.30040E-08 -8.5223 0.15014E+00 -0.8235 79 HFeO2- 0.52446E-08 -8.2803 0.69661E-09 -9.1570 0.13282E+00 -0.8767 82 FeO2- 0.32191E-08 -8.4923 0.42758E-09 -9.3690 0.13282E+00 -0.8767 83 HFeO2,aq 0.26392E-09 -9.5785 0.26392E-09 -9.5785 0.10000E+01 0.0000 84 H2,aq 0.41656E-02 -2.3803 0.49044E-02 -2.3094 0.11774E+01 0.0709 85 KCl,aq 0.70843E-01 -1.1497 0.70843E-01 -1.1497 0.10000E+01 0.0000 86 KHSO4,aq 0.12511E-01 -1.9027 0.12511E-01 -1.9027 0.10000E+01 0.0000 87 KOH,aq 0.12958E-05 -5.8875 0.12958E-05 -5.8875 0.10000E+01 0.0000 88 KSO4- 0.52270E-02 -2.2817 0.69427E-03 -3.1585 0.13282E+00 -0.8767 90 Mg(HCO3)+ 0.25558E-07 -7.5925 0.38374E-08 -8.4160 0.15014E+00 -0.8235 91 MgCl+ 0.16565E-04 -4.7808 0.24871E-05 -5.6043 0.15014E+00 -0.8235 92 MgOH+ 0.57995E-06 -6.2366 0.87075E-07 -7.0601 0.15014E+00 -0.8235 94 MnO,aq 0.78806E-07 -7.1034 0.78806E-07 -7.1034 0.10000E+01 0.0000 95 MnOH+ 0.20926E-06 -6.6793 0.31418E-07 -7.5028 0.15014E+00 -0.8235 97 HMnO2- 0.34750E-10 -10.4590 0.46156E-11 -11.3358 0.13282E+00 -0.8767 100 MnCl+ 0.11536E-02 -2.9379 0.17320E-03 -3.7614 0.15014E+00 -0.8235 101 MnSO4,aq 0.18725E-06 -6.7276 0.18725E-06 -6.7276 0.10000E+01 0.0000 102 NaCl,aq 0.43992E+00 -0.3566 0.43992E+00 -0.3566 0.10000E+01 0.0000 103 NaOH,aq 0.17051E-05 -5.7682 0.17051E-05 -5.7682 0.10000E+01 0.0000 105 OH- 0.77573E-05 -5.1103 0.88810E-06 -6.0515 0.11449E+00 -0.9412 110 HPO3-2 0.16625E-10 -10.7792 0.12567E-13 -13.9008 0.75591E-03 -3.1215 111 H3PO3,aq 0.13073E-09 -9.8836 0.13073E-09 -9.8836 0.10000E+01 0.0000 112 H2PO3- 0.17451E-08 -8.7582 0.23178E-09 -9.6349 0.13282E+00 -0.8767 113 H3PO4,aq 0.18907E-05 -5.7234 0.18907E-05 -5.7234 0.10000E+01 0.0000 114 H2PO4- 0.16986E-05 -5.7699 0.23890E-06 -6.6218 0.14064E+00 -0.8519 116 H4P2O7,aq 0.33597E-09 -9.4737 0.33597E-09 -9.4737 0.10000E+01 0.0000 117 H3P2O7- 0.12613E-08 -8.8992 0.16753E-09 -9.7759 0.13282E+00 -0.8767 118 H2P2O7-2 0.45200E-06 -6.3449 0.34167E-09 -9.4664 0.75591E-03 -3.1215 119 HP2O7-3 0.16827E-06 -6.7740 0.12473E-13 -13.9040 0.74125E-07 -7.1300 121 PbCl+ 0.12066E-05 -5.9184 0.18116E-06 -6.7419 0.15014E+00 -0.8235 122 PbCl2,aq 0.81715E-04 -4.0877 0.81715E-04 -4.0877 0.10000E+01 0.0000 123 PbCl3- 0.10516E-03 -3.9782 0.13967E-04 -4.8549 0.13282E+00 -0.8767 124 PbCl4-2 0.26682E-04 -4.5738 0.20169E-07 -7.6953 0.75591E-03 -3.1215 125 PbO,aq 0.61132E-08 -8.2137 0.61132E-08 -8.2137 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.11181E-03 -3.9515 0.11181E-03 -3.9515 0.10000E+01 0.0000 128 Pb(HS)3- 0.13676E-04 -4.8640 0.18165E-05 -5.7408 0.13282E+00 -0.8767 129 H2S,aq 0.10587E+01 0.0248 0.12465E+01 0.0957 0.11774E+01 0.0709 130 S2-2 0.20220E-07 -7.6942 0.15284E-10 -10.8158 0.75591E-03 -3.1215 131 S3-2 0.18848E-08 -8.7247 0.14248E-11 -11.8463 0.75591E-03 -3.1215 132 S3- 0.87497E-02 -2.0580 0.11622E-02 -2.9347 0.13282E+00 -0.8767 133 S4-2 0.15036E-09 -9.8229 0.11366E-12 -12.9444 0.75591E-03 -3.1215 134 S5-2 0.10505E-10 -10.9786 0.79408E-14 -14.1001 0.75591E-03 -3.1215 135 SO2,aq 0.29361E+00 -0.5322 0.29361E+00 -0.5322 0.10000E+01 0.0000 136 SO3-2 0.11431E-08 -8.9419 0.14844E-11 -11.8285 0.12986E-02 -2.8865 137 HSO3- 0.23255E-03 -3.6335 0.30888E-04 -4.5102 0.13282E+00 -0.8767 138 HSO4- 0.83951E-02 -2.0760 0.13017E-02 -2.8855 0.15505E+00 -0.8095 140 S2O3-2 0.95555E-06 -6.0197 0.72231E-09 -9.1413 0.75591E-03 -3.1215 141 HS2O3- 0.36802E-06 -6.4341 0.48882E-07 -7.3108 0.13282E+00 -0.8767 142 H2S2O3,aq 0.41906E-07 -7.3777 0.41906E-07 -7.3777 0.10000E+01 0.0000 150 S4O6-2 0.79129E-09 -9.1017 0.59814E-12 -12.2232 0.75591E-03 -3.1215 152 ZnCl+ 0.13630E-03 -3.8655 0.20465E-04 -4.6890 0.15014E+00 -0.8235 153 ZnCl2,aq 0.53358E-03 -3.2728 0.53358E-03 -3.2728 0.10000E+01 0.0000 154 ZnCl3- 0.35945E-04 -4.4444 0.47743E-05 -5.3211 0.13282E+00 -0.8767 155 ZnO,aq 0.23747E-07 -7.6244 0.23747E-07 -7.6244 0.10000E+01 0.0000 156 ZnOH+ 0.94832E-06 -6.0230 0.14238E-06 -6.8465 0.15014E+00 -0.8235 158 HZnO2- 0.18263E-09 -9.7384 0.24258E-10 -10.6151 0.13282E+00 -0.8767 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5091322E-05 0.4293808E+01 0.3543715E+04 0.0000 2 H2O 0.1000000E+01 0.5252315E+02 0.7747719E+06 0.0000 3 Cl- 0.1326946E+00 0.6558037E+00 0.1903744E+05 4.3308 4 SO4-- 0.4988416E-03 0.2513358E+00 0.1976905E+05 5.7849 5 HCO3- 0.8095487E-05 0.2673820E+01 0.1335876E+06 0.1532 6 HS- 0.1215942E-03 0.1154508E+01 0.3126360E+05 1.2970 7 H4SiO4 0.4116313E-01 0.4116628E-01 0.3239785E+04 -1.3855 8 Al+++ 0.3738537E-15 0.1233129E-04 0.2724307E+00 -4.2403 9 Ca++ 0.2858802E-05 0.1448577E-03 0.4753672E+01 3.4302 10 Mg++ 0.3642158E-05 0.2081450E-04 0.4143508E+00 3.4371 11 Fe++ 0.3244455E-07 0.2126749E-02 0.9725179E+02 1.4118 12 K+ 0.3697751E-01 0.1255594E+00 0.4020033E+04 3.8247 13 Na+ 0.1183705E+00 0.5582967E+00 0.1050949E+05 4.2864 14 Mn++ 0.3079736E-05 0.1157163E-02 0.5205340E+02 3.4073 15 Zn++ 0.8774238E-09 0.7068042E-03 0.3783199E+02 -0.1562 16 Cu+ 0.1312322E-07 0.9841689E-04 0.5120335E+01 -2.6701 17 Pb++ 0.5689124E-08 0.3402549E-03 0.5772378E+02 0.7865 18 Ag+ 0.1680605E-09 0.8758848E-05 0.7736227E+00 -4.5257 19 Ba++ 0.1211963E-06 0.7525578E-05 0.8462885E+00 2.1514 20 HPO4-- 0.3249369E-08 0.4838163E-05 0.3802229E+00 0.6013 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265372E+01 -.3009610E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5217532E+02 -.2105387E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2496713E+00 0.2051431E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1146862E+01 0.1328177E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4089366E-01 0.1027007E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1224962E-04 0.6822899E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1438984E-03 0.3840115E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2112664E-02 0.6654090E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247278E+00 0.6822899E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.7021233E-03 0.1597211E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.9776512E-04 0.3018446E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3380016E-03 0.2171057E-05 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7475739E-05 0.4789671E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.4806123E-05 0.3761378E-05 0.0000000E+00 Chg. balance for solid moles: 0.3913E-18 Mass of aqueous solution: 0.121320E+04 g Temperature = 550.00 C Pressure = 945.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3777E-03 -3.423 0.5143E-01 -1.289 0.7070 0.1736E-01 apatite-OH 0.1254E-05 -5.902 0.6298E-03 -3.201 0.8658E-02 0.2001E-03 microcline 0.6823E-03 -3.166 0.1899 -0.721 2.611 0.7418E-01 pyrite 0.6352E-02 -2.197 0.7621 -0.118 10.48 0.1521 quartz 0.1007 -0.997 6.047 0.782 83.13 2.284 barite 0.4790E-04 -4.320 0.1118E-01 -1.952 0.1537 0.2495E-02 chalcopyrite 0.3018E-03 -3.520 0.5539E-01 -1.257 0.7614 0.1293E-01 galena 0.2171E-05 -5.663 0.5194E-03 -3.284 0.7141E-02 0.6836E-04 sphalerite 0.1597E-02 -2.797 0.1556 -0.808 2.139 0.3806E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.274090 g Volume = 2.581069 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.12 -15.12 0.00 0.000 -0.66908E-11 27 apatite-OH -54.06 -54.06 0.00 0.000 0.00000E+00 112 microcline -4.57 -4.57 0.00 0.000 0.00000E+00 137 pyrite -22.25 -22.25 -0.00 -0.000 0.13382E-10 141 quartz -1.38 -1.38 -0.00 -0.000 0.83635E-12 234 barite -16.40 -16.40 0.00 0.000 0.00000E+00 237 chalcopyrite -23.96 -23.96 0.00 0.000 0.00000E+00 242 galena -10.09 -10.09 -0.00 -0.000 0.13382E-10 252 sphalerite -11.03 -11.03 -0.00 -0.000 0.13382E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.26 -0.256 0.96449E+03 2.719 2 CO2,gas -10.29 -12.01 -1.73 -0.577 0.65156E+04 1.246 3 CH4,gas 6.80 -4.34 -11.13 -2.783 0.41932E+05 -8.157 4 H2,gas 6.02 1.92 -4.10 -2.343 0.15443E+05 -1.125 5 H2S,gas -8.57 -10.87 -2.31 -1.153 0.86830E+04 0.670 6 CO,gas -3.96 -10.09 -6.13 -1.887 0.23095E+05 -3.156 7 SO3,gas -7.78 -18.55 -10.78 -2.694 0.40586E+05 -7.800 8 O2,gas 17.11 -3.84 -20.95 -13.964 0.78894E+05 -17.970 9 HCl,gas -6.23 -7.84 -1.60 -0.802 0.60449E+04 -1.605 10 acmite 3.62 1.97 -1.65 -0.171 0.62091E+04 12 akimotoite 6.43 2.05 -4.37 -0.875 0.16472E+05 13 akimotoite-Fe 4.25 0.03 -4.22 -0.845 0.15906E+05 14 albite-high -3.94 -4.11 -0.17 -0.013 0.63177E+03 15 albite -3.95 -4.11 -0.16 -0.012 0.60164E+03 16 almandine -6.06 -8.40 -2.34 -0.117 0.88059E+04 17 pyrope 0.84 -2.33 -3.16 -0.158 0.11910E+05 18 analcite -1.71 -2.72 -1.01 -0.113 0.38148E+04 19 andalusite -9.27 -9.87 -0.60 -0.060 0.22675E+04 24 anorthite -6.88 -7.82 -0.94 -0.073 0.35550E+04 25 anthophyllite 15.87 12.99 -2.88 -0.078 0.10846E+05 26 anthophyllite-Fe 2.69 -1.19 -3.88 -0.105 0.14624E+05 28 apatite-OH-zs -51.84 -54.06 -2.22 -0.171 0.83771E+04 29 apatite-Cl-zs -58.62 -61.90 -3.28 -0.274 0.12366E+05 30 aragonite -4.78 -8.59 -3.81 -1.270 0.14347E+05 31 brucite 5.80 3.43 -2.37 -0.473 0.89159E+04 32 calcite -4.89 -8.59 -3.70 -1.233 0.13936E+05 33 carnegieite-low 0.49 -1.34 -1.83 -0.261 0.68882E+04 34 carnegieite-high 0.58 -1.34 -1.92 -0.274 0.72310E+04 35 carpholite-Mg -5.65 -7.82 -2.17 -0.144 0.81607E+04 36 carpholite-Fe -7.06 -9.84 -2.78 -0.185 0.10465E+05 37 celadonite -0.31 -2.52 -2.21 -0.130 0.83114E+04 38 celadonite-Fe -1.76 -4.54 -2.78 -0.163 0.10458E+05 39 chrysotile 10.20 7.54 -2.66 -0.222 0.10019E+05 41 clinochlore 6.36 4.54 -1.82 -0.057 0.68561E+04 42 daphnite -1.00 -5.59 -4.58 -0.143 0.17261E+05 45 chloritoid-Mg -4.94 -6.43 -1.50 -0.100 0.56364E+04 46 chloritoid-Fe -6.97 -8.46 -1.49 -0.099 0.56207E+04 47 chloritoid-Mn -4.83 -6.46 -1.63 -0.109 0.61582E+04 49 coesite -1.09 -1.38 -0.30 -0.099 0.11187E+04 50 cordierite-H -15.75 -17.01 -1.26 -0.045 0.47427E+04 51 cordierite-Fe -18.48 -21.06 -2.58 -0.089 0.97186E+04 52 cordierite-Mn -14.14 -17.07 -2.93 -0.101 0.11038E+05 53 corundum -7.70 -8.48 -0.78 -0.071 0.29536E+04 55 cristobalite -1.34 -1.38 -0.05 -0.016 0.18004E+03 56 cummingtonite 15.94 12.99 -2.95 -0.080 0.11117E+05 58 cymrite-K -2.20 -4.57 -2.37 -0.197 0.89098E+04 60 diaspore -3.37 -4.24 -0.88 -0.146 0.32986E+04 62 diopside 5.70 4.10 -1.60 -0.160 0.60236E+04 63 hedenbergite 4.22 2.07 -2.14 -0.214 0.80685E+04 65 eastonite -3.20 -4.80 -1.59 -0.061 0.60047E+04 66 enstatite 5.18 4.11 -1.08 -0.108 0.40601E+04 67 clinoenstatite-HiP 5.69 4.11 -1.58 -0.158 0.59697E+04 68 clinoenstatite 5.16 4.11 -1.06 -0.106 0.39883E+04 69 protoenstatite 5.32 4.11 -1.21 -0.121 0.45757E+04 70 epidote -2.61 -5.33 -2.72 -0.132 0.10236E+05 71 clinozoisite -6.94 -10.02 -3.08 -0.140 0.11599E+05 72 epidote-Fe 3.43 -0.63 -4.06 -0.211 0.15310E+05 73 fayalite 2.74 1.44 -1.30 -0.186 0.49138E+04 74 ferrosilite 1.46 0.06 -1.41 -0.141 0.52944E+04 75 forsterite 6.89 5.49 -1.40 -0.200 0.52687E+04 76 gedrite -5.31 -8.09 -2.77 -0.075 0.10452E+05 78 gibbsite -1.73 -4.24 -2.51 -0.359 0.94641E+04 79 glaucophane 2.70 -0.67 -3.37 -0.091 0.12703E+05 81 goethite 1.41 0.45 -0.96 -0.208 0.36195E+04 83 greenalite 5.12 1.46 -3.65 -0.305 0.13765E+05 84 grunerite 3.27 -1.19 -4.46 -0.121 0.16801E+05 85 halite -1.50 -3.55 -2.05 -1.025 0.77235E+04 86 hematite 1.27 0.90 -0.37 -0.045 0.13994E+04 87 heulandite -11.40 -14.74 -3.34 -0.152 0.12582E+05 88 hercynite -5.66 -7.07 -1.41 -0.094 0.53217E+04 91 jadeite -1.03 -2.72 -1.70 -0.170 0.63856E+04 93 kalsilite -0.14 -1.80 -1.66 -0.238 0.62683E+04 94 kaolinite -8.48 -11.25 -2.77 -0.252 0.10451E+05 95 kyanite -9.10 -9.87 -0.77 -0.077 0.28937E+04 97 laumontite -6.79 -10.59 -3.81 -0.254 0.14334E+05 98 lawsonite -4.12 -7.82 -3.70 -0.247 0.13937E+05 99 leucite -2.19 -3.18 -1.00 -0.100 0.37551E+04 101 lizardite 10.36 7.54 -2.82 -0.235 0.10614E+05 102 magnesite -5.52 -8.58 -3.06 -1.021 0.11532E+05 103 magnetite 2.78 2.31 -0.47 -0.038 0.17637E+04 104 minnesotaite 1.09 -1.30 -2.40 -0.141 0.90257E+04 105 minnesotaite-Mg 7.29 4.77 -2.51 -0.148 0.94678E+04 106 magnesioferrite 5.95 4.34 -1.61 -0.132 0.60768E+04 108 manganosite 5.71 3.41 -2.30 -0.575 0.86650E+04 109 margarite -14.14 -16.31 -2.16 -0.087 0.81455E+04 113 monticellite 9.28 5.48 -3.80 -0.543 0.14305E+05 115 mullite-Si -8.49 -9.87 -1.38 -0.138 0.51831E+04 116 muscovite -12.16 -13.05 -0.90 -0.053 0.33811E+04 117 paragonite -11.47 -12.59 -1.13 -0.066 0.42389E+04 118 nepheline 0.18 -1.34 -1.52 -0.218 0.57358E+04 119 osumilite(2) -11.41 -13.81 -2.40 -0.050 0.90414E+04 120 osumilite-Fe -25.39 -28.40 -3.01 -0.063 0.11331E+05 121 pargasite 8.65 3.86 -4.79 -0.126 0.18032E+05 122 periclase 6.02 3.44 -2.59 -0.647 0.97514E+04 123 periclase-Fe 3.37 1.41 -1.96 -0.489 0.73705E+04 124 perovskite-Al -5.93 -8.48 -2.55 -0.232 0.96168E+04 129 phlogopite-Na 7.37 6.20 -1.17 -0.065 0.43946E+04 131 prehnite -2.11 -5.78 -3.67 -0.216 0.13822E+05 132 prehnite-Fe 2.62 -1.08 -3.71 -0.223 0.13965E+05 135 px-Mg-tschermaks -4.27 -6.43 -2.17 -0.155 0.81584E+04 136 px-Ca-tschermaks -3.57 -6.44 -2.87 -0.205 0.10811E+05 138 pyrrhotite -8.70 -9.46 -0.76 -0.253 0.28542E+04 139 pyrrhotiteFe0.875 -9.52 -9.88 -0.35 -0.129 0.13231E+04 140 pyrophyllite -12.56 -14.02 -1.45 -0.091 0.54741E+04 143 riebeckite 6.03 2.64 -3.39 -0.094 0.12781E+05 144 ringwoodite-Fe 3.75 1.44 -2.31 -0.330 0.87110E+04 145 ringwoodite-Mg 10.10 5.49 -4.61 -0.659 0.17371E+05 146 rhodochrosite -5.57 -8.61 -3.04 -1.013 0.11444E+05 147 rhodonite 2.67 2.02 -0.64 -0.129 0.24238E+04 148 sanidine -4.02 -4.57 -0.55 -0.042 0.20679E+04 150 siderite -7.43 -10.60 -3.17 -1.058 0.11957E+05 151 sillimanite -9.22 -9.87 -0.64 -0.064 0.24222E+04 153 spinel -3.42 -5.05 -1.63 -0.109 0.61432E+04 160 stilpnomelane-Mg 2.13 -0.46 -2.59 -0.077 0.97667E+04 161 stishovite 1.63 -1.38 -3.01 -1.003 0.11338E+05 162 sudoite-Fe -13.55 -18.30 -4.75 -0.153 0.17894E+05 163 sudoite -11.22 -14.25 -3.03 -0.098 0.11404E+05 164 sulfur -11.31 -12.79 -1.48 -0.455 0.55664E+04 165 sylvite -1.41 -4.01 -2.61 -1.304 0.98224E+04 166 talc 5.53 4.77 -0.75 -0.044 0.28431E+04 167 talc-Fe 2.53 -1.30 -3.83 -0.225 0.14439E+05 168 talc-tschermaks -3.84 -5.76 -1.92 -0.113 0.72351E+04 170 tephroite 6.98 5.43 -1.55 -0.222 0.58493E+04 173 topaz-H -7.18 -9.87 -2.69 -0.245 0.10146E+05 174 tremolite 16.27 12.97 -3.30 -0.089 0.12438E+05 176 troilite-low -8.61 -9.46 -0.85 -0.282 0.31858E+04 177 tschermakite -4.12 -8.10 -3.98 -0.108 0.15000E+05 180 wadsleyite-Fe 3.61 1.44 -2.17 -0.310 0.81760E+04 181 wadsleyite-Mg 9.15 5.49 -3.66 -0.522 0.13774E+05 182 wairakite -8.67 -10.59 -1.92 -0.113 0.72385E+04 183 walstromite 4.73 2.05 -2.68 -0.536 0.10103E+05 184 wollastonite 4.30 2.05 -2.25 -0.450 0.84715E+04 185 pseudo-wollastonite 4.42 2.05 -2.37 -0.474 0.89310E+04 186 zoisite -6.99 -10.02 -3.03 -0.138 0.11418E+05 189 beidellite-Ca -12.56 -14.40 -1.83 -0.113 0.68988E+04 190 beidellite-H -12.62 -14.96 -2.35 -0.150 0.88345E+04 191 beidellite-K -11.58 -13.70 -2.12 -0.130 0.79970E+04 192 beidellite-Mg -12.80 -14.39 -1.59 -0.099 0.60066E+04 193 beidellite-Na -11.52 -13.55 -2.03 -0.124 0.76422E+04 194 bornite -56.17 -56.39 -0.21 -0.016 0.80407E+03 196 chalcocite -14.78 -16.21 -1.43 -0.358 0.53890E+04 197 covellite -13.18 -14.50 -1.32 -0.504 0.49845E+04 199 montmorillonite-Ca -9.52 -10.92 -1.39 -0.086 0.52520E+04 200 montmorillonite-K -8.81 -10.22 -1.41 -0.086 0.53146E+04 201 montmorillonite-Mg -9.73 -10.92 -1.19 -0.074 0.44871E+04 202 montmorillonite-Na -8.48 -10.07 -1.59 -0.097 0.59728E+04 203 nontronite-Ca -3.32 -5.01 -1.69 -0.110 0.63695E+04 204 nontronite-H -3.38 -5.58 -2.20 -0.147 0.82749E+04 205 nontronite-K -2.33 -4.31 -1.98 -0.127 0.74601E+04 206 nontronite-Mg -3.52 -5.01 -1.49 -0.096 0.55934E+04 207 nontronite-Na -2.27 -4.16 -1.89 -0.121 0.71168E+04 212 gypsum -12.85 -15.13 -2.27 -0.568 0.85630E+04 229 alabandite -6.43 -7.47 -1.03 -0.345 0.38964E+04 231 anglesite -15.47 -17.77 -2.30 -1.150 0.86596E+04 235 boehmite -3.06 -4.24 -1.18 -0.197 0.44435E+04 239 copper,native 1.69 -1.71 -3.40 -1.182 0.12804E+05 241 ferrous-oxide 2.43 1.41 -1.02 -0.254 0.38299E+04 243 silver,native 0.38 -3.57 -3.94 -1.372 0.14856E+05 245 litharge 5.45 0.79 -4.66 -1.166 0.17564E+05 253 wurtzite -10.21 -11.03 -0.82 -0.273 0.30884E+04 254 zincite 2.49 -0.16 -2.65 -0.662 0.99743E+04 255 an20ab80 -4.75 -4.85 -0.10 -0.008 0.37192E+03 256 an25ab75 -4.92 -5.03 -0.11 -0.009 0.42102E+03 257 an30ab70 -5.09 -5.22 -0.13 -0.010 0.48879E+03 258 tr.625ac.25prg.125 11.06 9.30 -1.76 -0.047 0.66379E+04 Calculations done for 550.0000 Deg. C; 945.0000 bar Temperature changed by -1.000 degrees to 549.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 48 Loop limit = 500 Temperature = 549.00 C Pressure = 934.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5514E+02 kg liquid = 0.9934E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9970 Stoichiometric ionic strength = .3271451E+01 Osmotic coef. = 0.0000 True ionic strength = .1598651E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.51828E-05 -5.2854 0.80444E-06 -6.0945 0.15521E+00 -0.8091 2 H2O 0.99695E+00 -0.0013 0.99695E+00 -0.0013 3 Cl- 0.13493E+00 -0.8699 0.17106E-01 -1.7669 0.12677E+00 -0.8970 4 SO4-- 0.56557E-03 -3.2475 0.39655E-06 -6.4017 0.70115E-03 -3.1542 5 HCO3- 0.80205E-05 -5.0958 0.11097E-05 -5.9548 0.13835E+00 -0.8590 6 HS- 0.12366E-03 -3.9078 0.15829E-04 -4.8005 0.12801E+00 -0.8928 7 H4SiO4 0.40366E-01 -1.3940 0.40366E-01 -1.3940 0.10000E+01 0.0000 8 Al+++ 0.59244E-15 -15.2274 0.34596E-22 -22.4610 0.58396E-07 -7.2336 9 Ca++ 0.33313E-05 -5.4774 0.17882E-08 -8.7476 0.53677E-03 -3.2702 10 Mg++ 0.40730E-05 -5.3901 0.17333E-08 -8.7611 0.42557E-03 -3.3710 11 Fe++ 0.38543E-07 -7.4141 0.17394E-10 -10.7596 0.45129E-03 -3.3455 12 K+ 0.37460E-01 -1.4264 0.53290E-02 -2.2734 0.14226E+00 -0.8469 13 Na+ 0.12036E+00 -0.9195 0.15445E-01 -1.8112 0.12832E+00 -0.8917 14 Mn++ 0.36035E-05 -5.4433 0.16976E-08 -8.7702 0.47109E-03 -3.3269 15 Zn++ 0.10452E-08 -8.9808 0.47166E-12 -12.3264 0.45129E-03 -3.3455 16 Cu+ 0.13289E-07 -7.8765 0.16999E-08 -8.7696 0.12792E+00 -0.8931 17 Pb++ 0.65151E-08 -8.1861 0.40053E-11 -11.3974 0.61478E-03 -3.2113 18 Ag+ 0.14529E-09 -9.8378 0.20285E-10 -10.6928 0.13961E+00 -0.8551 19 Ba++ 0.13766E-06 -6.8612 0.92239E-10 -10.0351 0.67006E-03 -3.1739 20 HPO4-- 0.37338E-08 -8.4278 0.26338E-11 -11.5794 0.70539E-03 -3.1516 21 HSiO3- 0.13697E-05 -5.8634 0.17364E-06 -6.7604 0.12677E+00 -0.8970 22 Ca(HSiO3)+ 0.43952E-08 -8.3570 0.63182E-09 -9.1994 0.14375E+00 -0.8424 23 Mg(HSiO3)+ 0.14753E-08 -8.8311 0.21207E-09 -9.6735 0.14375E+00 -0.8424 24 NaHSiO3,aq 0.17776E-05 -5.7502 0.17776E-05 -5.7502 0.10000E+01 0.0000 28 AgCl,aq 0.54923E-07 -7.2602 0.54923E-07 -7.2602 0.10000E+01 0.0000 29 AgCl2- 0.26278E-05 -5.5804 0.33314E-06 -6.4774 0.12677E+00 -0.8970 30 AgCl3-2 0.14246E-05 -5.8463 0.91070E-09 -9.0406 0.63926E-03 -3.1943 31 AgCl4-3 0.46466E-05 -5.3329 0.23404E-12 -12.6307 0.50367E-07 -7.2979 34 Ag(HS),aq 0.10502E-08 -8.9787 0.10502E-08 -8.9787 0.10000E+01 0.0000 35 Ag(HS)2- 0.34406E-08 -8.4634 0.43618E-09 -9.3603 0.12677E+00 -0.8970 36 AlO+ 0.18424E-10 -10.7346 0.26485E-11 -11.5770 0.14375E+00 -0.8424 38 HAlO2,aq 0.48004E-08 -8.3187 0.48004E-08 -8.3187 0.10000E+01 0.0000 39 AlO2- 0.12703E-04 -4.8961 0.13829E-05 -5.8592 0.10886E+00 -0.9631 41 Ba(HCO3)+ 0.16574E-06 -6.7806 0.24985E-07 -7.6023 0.15075E+00 -0.8217 42 BaCl+ 0.72659E-05 -5.1387 0.10445E-05 -5.9811 0.14375E+00 -0.8424 43 CH4,aq 0.12884E-08 -8.8899 0.15154E-08 -8.8195 0.11762E+01 0.0705 48 CO,aq 0.41570E-03 -3.3812 0.41570E-03 -3.3812 0.10000E+01 0.0000 49 CO2,aq 0.26733E+01 0.4271 0.31443E+01 0.4975 0.11762E+01 0.0705 50 CO3-2 0.73495E-10 -10.1337 0.46982E-13 -13.3281 0.63926E-03 -3.1943 52 Ca(HCO3)+ 0.77996E-07 -7.1079 0.11212E-07 -7.9503 0.14375E+00 -0.8424 53 CaCl+ 0.73884E-04 -4.1314 0.10621E-04 -4.9738 0.14375E+00 -0.8424 54 CaCl2,aq 0.68318E-04 -4.1655 0.68318E-04 -4.1655 0.10000E+01 0.0000 55 CaOH+ 0.13201E-06 -6.8794 0.18977E-07 -7.7218 0.14375E+00 -0.8424 56 CaSO4,aq 0.19469E-06 -6.7106 0.19469E-06 -6.7106 0.10000E+01 0.0000 57 HCl,aq 0.48206E-02 -2.3169 0.48206E-02 -2.3169 0.10000E+01 0.0000 66 CuCl,aq 0.20126E-04 -4.6962 0.20126E-04 -4.6962 0.10000E+01 0.0000 67 CuCl2- 0.77318E-04 -4.1117 0.98020E-05 -5.0087 0.12677E+00 -0.8970 68 CuCl3-2 0.23375E-05 -5.6312 0.14943E-08 -8.8256 0.63926E-03 -3.1943 74 FeCl+ 0.25947E-06 -6.5859 0.37299E-07 -7.4283 0.14375E+00 -0.8424 75 FeCl2,aq 0.20752E-02 -2.6829 0.20752E-02 -2.6829 0.10000E+01 0.0000 77 FeO,aq 0.43961E-07 -7.3569 0.43961E-07 -7.3569 0.10000E+01 0.0000 78 FeOH+ 0.20563E-07 -7.6869 0.29559E-08 -8.5293 0.14375E+00 -0.8424 79 HFeO2- 0.52887E-08 -8.2767 0.67047E-09 -9.1736 0.12677E+00 -0.8970 82 FeO2- 0.32128E-08 -8.4931 0.40730E-09 -9.3901 0.12677E+00 -0.8970 83 HFeO2,aq 0.26449E-09 -9.5776 0.26449E-09 -9.5776 0.10000E+01 0.0000 84 H2,aq 0.41542E-02 -2.3815 0.48860E-02 -2.3110 0.11762E+01 0.0705 85 KCl,aq 0.70470E-01 -1.1520 0.70470E-01 -1.1520 0.10000E+01 0.0000 86 KHSO4,aq 0.12322E-01 -1.9093 0.12322E-01 -1.9093 0.10000E+01 0.0000 87 KOH,aq 0.12849E-05 -5.8911 0.12849E-05 -5.8911 0.10000E+01 0.0000 88 KSO4- 0.53031E-02 -2.2755 0.67229E-03 -3.1724 0.12677E+00 -0.8970 90 Mg(HCO3)+ 0.23879E-07 -7.6220 0.34326E-08 -8.4644 0.14375E+00 -0.8424 91 MgCl+ 0.16154E-04 -4.7917 0.23221E-05 -5.6341 0.14375E+00 -0.8424 92 MgOH+ 0.56198E-06 -6.2503 0.80787E-07 -7.0927 0.14375E+00 -0.8424 94 MnO,aq 0.76837E-07 -7.1144 0.76837E-07 -7.1144 0.10000E+01 0.0000 95 MnOH+ 0.21074E-06 -6.6762 0.30295E-07 -7.5186 0.14375E+00 -0.8424 97 HMnO2- 0.34461E-10 -10.4627 0.43688E-11 -11.3596 0.12677E+00 -0.8970 100 MnCl+ 0.11531E-02 -2.9382 0.16576E-03 -3.7805 0.14375E+00 -0.8424 101 MnSO4,aq 0.18822E-06 -6.7253 0.18822E-06 -6.7253 0.10000E+01 0.0000 102 NaCl,aq 0.43792E+00 -0.3586 0.43792E+00 -0.3586 0.10000E+01 0.0000 103 NaOH,aq 0.16911E-05 -5.7718 0.16911E-05 -5.7718 0.10000E+01 0.0000 105 OH- 0.79556E-05 -5.0993 0.86605E-06 -6.0625 0.10886E+00 -0.9631 110 HPO3-2 0.18458E-10 -10.7338 0.11799E-13 -13.9281 0.63926E-03 -3.1943 111 H3PO3,aq 0.13220E-09 -9.8788 0.13220E-09 -9.8788 0.10000E+01 0.0000 112 H2PO3- 0.17413E-08 -8.7591 0.22075E-09 -9.6561 0.12677E+00 -0.8970 113 H3PO4,aq 0.19476E-05 -5.7105 0.19476E-05 -5.7105 0.10000E+01 0.0000 114 H2PO4- 0.17398E-05 -5.7595 0.23390E-06 -6.6310 0.13444E+00 -0.8715 116 H4P2O7,aq 0.35782E-09 -9.4463 0.35782E-09 -9.4463 0.10000E+01 0.0000 117 H3P2O7- 0.13047E-08 -8.8845 0.16540E-09 -9.7815 0.12677E+00 -0.8970 118 H2P2O7-2 0.50511E-06 -6.2966 0.32289E-09 -9.4909 0.63926E-03 -3.1943 119 HP2O7-3 0.23169E-06 -6.6351 0.11669E-13 -13.9329 0.50367E-07 -7.2979 121 PbCl+ 0.12177E-05 -5.9145 0.17505E-06 -6.7568 0.14375E+00 -0.8424 122 PbCl2,aq 0.81105E-04 -4.0910 0.81105E-04 -4.0910 0.10000E+01 0.0000 123 PbCl3- 0.10701E-03 -3.9706 0.13566E-04 -4.8675 0.12677E+00 -0.8970 124 PbCl4-2 0.29272E-04 -4.5335 0.18712E-07 -7.7279 0.63926E-03 -3.1943 125 PbO,aq 0.60728E-08 -8.2166 0.60728E-08 -8.2166 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10993E-03 -3.9589 0.10993E-03 -3.9589 0.10000E+01 0.0000 128 Pb(HS)3- 0.13776E-04 -4.8609 0.17464E-05 -5.7578 0.12677E+00 -0.8970 129 H2S,aq 0.10588E+01 0.0248 0.12453E+01 0.0953 0.11762E+01 0.0705 130 S2-2 0.22370E-07 -7.6503 0.14300E-10 -10.8447 0.63926E-03 -3.1943 131 S3-2 0.20747E-08 -8.6830 0.13263E-11 -11.8774 0.63926E-03 -3.1943 132 S3- 0.86885E-02 -2.0611 0.11015E-02 -2.9580 0.12677E+00 -0.8970 133 S4-2 0.16485E-09 -9.7829 0.10538E-12 -12.9772 0.63926E-03 -3.1943 134 S5-2 0.11486E-10 -10.9398 0.73424E-14 -14.1342 0.63926E-03 -3.1943 135 SO2,aq 0.29358E+00 -0.5323 0.29358E+00 -0.5323 0.10000E+01 0.0000 136 SO3-2 0.12733E-08 -8.8951 0.14184E-11 -11.8482 0.11139E-02 -2.9531 137 HSO3- 0.23344E-03 -3.6318 0.29594E-04 -4.5288 0.12677E+00 -0.8970 138 HSO4- 0.84745E-02 -2.0719 0.12592E-02 -2.8999 0.14859E+00 -0.8280 140 S2O3-2 0.10686E-05 -5.9712 0.68310E-09 -9.1655 0.63926E-03 -3.1943 141 HS2O3- 0.36986E-06 -6.4320 0.46889E-07 -7.3289 0.12677E+00 -0.8970 142 H2S2O3,aq 0.42670E-07 -7.3699 0.42670E-07 -7.3699 0.10000E+01 0.0000 150 S4O6-2 0.87152E-09 -9.0597 0.55712E-12 -12.2540 0.63926E-03 -3.1943 152 ZnCl+ 0.13719E-03 -3.8627 0.19721E-04 -4.7051 0.14375E+00 -0.8424 153 ZnCl2,aq 0.52725E-03 -3.2780 0.52725E-03 -3.2780 0.10000E+01 0.0000 154 ZnCl3- 0.35722E-04 -4.4471 0.45287E-05 -5.3440 0.12677E+00 -0.8970 155 ZnO,aq 0.23463E-07 -7.6296 0.23463E-07 -7.6296 0.10000E+01 0.0000 156 ZnOH+ 0.95780E-06 -6.0187 0.13769E-06 -6.8611 0.14375E+00 -0.8424 158 HZnO2- 0.18513E-09 -9.7325 0.23470E-10 -10.6295 0.12677E+00 -0.8970 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5182776E-05 0.4293680E+01 0.3543861E+04 0.0000 2 H2O 0.1000000E+01 0.5252339E+02 0.7748303E+06 0.0000 3 Cl- 0.1349309E+00 0.6557862E+00 0.1903827E+05 4.3277 4 SO4-- 0.5655690E-03 0.2513167E+00 0.1976895E+05 5.7873 5 HCO3- 0.8020527E-05 0.2673749E+01 0.1335935E+06 0.1397 6 HS- 0.1236600E-03 0.1154384E+01 0.3126246E+05 1.2940 7 H4SiO4 0.4036555E-01 0.4036870E-01 0.3177240E+04 -1.3940 8 Al+++ 0.5924429E-15 0.1270824E-04 0.2807786E+00 -4.1775 9 Ca++ 0.3331346E-05 0.1459423E-03 0.4789605E+01 3.4414 10 Mg++ 0.4073031E-05 0.2081394E-04 0.4143690E+00 3.4279 11 Fe++ 0.3854329E-07 0.2075574E-02 0.9491840E+02 1.4294 12 K+ 0.3746040E-01 0.1255564E+00 0.4020222E+04 3.8211 13 Na+ 0.1203611E+00 0.5582817E+00 0.1050996E+05 4.2833 14 Mn++ 0.3603504E-05 0.1157132E-02 0.5205569E+02 3.4188 15 Zn++ 0.1045153E-08 0.7011393E-03 0.3753143E+02 -0.1374 16 Cu+ 0.1328895E-07 0.9979551E-04 0.5192429E+01 -2.6751 17 Pb++ 0.6515075E-08 0.3423165E-03 0.5807764E+02 0.7917 18 Ag+ 0.1452935E-09 0.8758613E-05 0.7736568E+00 -4.5983 19 Ba++ 0.1376593E-06 0.7569261E-05 0.8512612E+00 2.1539 20 HPO4-- 0.3733820E-08 0.5170000E-05 0.4063301E+00 0.6096 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265359E+01 -.2996984E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5217695E+02 -.2121734E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2496591E+00 0.2063722E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1146770E+01 0.1337402E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.4010243E-01 0.1034919E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1262442E-04 0.6819151E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1449797E-03 0.3829302E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2061884E-02 0.6704870E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247282E+00 0.6819151E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.6965147E-03 0.1602820E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.9913727E-04 0.3004724E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3400586E-03 0.1140220E-06 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7519335E-05 0.4785312E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.5135899E-05 0.3431602E-05 0.0000000E+00 Chg. balance for solid moles: -.1313E-17 Mass of aqueous solution: 0.121315E+04 g Temperature = 549.00 C Pressure = 934.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3772E-03 -3.423 0.5135E-01 -1.289 0.7008 0.1733E-01 apatite-OH 0.1144E-05 -5.942 0.5746E-03 -3.241 0.7842E-02 0.1826E-03 microcline 0.6819E-03 -3.166 0.1898 -0.722 2.590 0.7414E-01 pyrite 0.6404E-02 -2.194 0.7684 -0.114 10.49 0.1533 quartz 0.1014 -0.994 6.095 0.785 83.18 2.302 barite 0.4785E-04 -4.320 0.1117E-01 -1.952 0.1524 0.2493E-02 chalcopyrite 0.3005E-03 -3.522 0.5514E-01 -1.259 0.7525 0.1287E-01 galena 0.1140E-06 -6.943 0.2728E-04 -4.564 0.3723E-03 0.3590E-05 sphalerite 0.1603E-02 -2.795 0.1562 -0.806 2.131 0.3819E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.327512 g Volume = 2.600220 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.15 -15.15 0.00 0.000 -0.66827E-11 27 apatite-OH -54.10 -54.10 0.00 0.000 -0.26731E-10 112 microcline -4.53 -4.53 0.00 0.000 -0.13365E-10 137 pyrite -22.28 -22.28 -0.00 -0.000 0.26731E-10 141 quartz -1.39 -1.39 0.00 0.000 0.00000E+00 234 barite -16.44 -16.44 -0.00 -0.000 0.13365E-10 237 chalcopyrite -24.00 -24.00 -0.00 -0.000 0.13365E-10 242 galena -10.10 -10.10 0.00 0.000 -0.66827E-11 252 sphalerite -11.03 -11.03 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.26 -0.255 0.96002E+03 2.715 2 CO2,gas -10.31 -12.05 -1.74 -0.579 0.65328E+04 1.234 3 CH4,gas 6.79 -4.35 -11.15 -2.786 0.41931E+05 -8.176 4 H2,gas 6.02 1.92 -4.10 -2.344 0.15433E+05 -1.132 5 H2S,gas -8.59 -10.90 -2.31 -1.153 0.86766E+04 0.664 6 CO,gas -3.98 -10.12 -6.14 -1.891 0.23115E+05 -3.174 7 SO3,gas -7.80 -18.59 -10.79 -2.697 0.40585E+05 -7.818 8 O2,gas 17.12 -3.85 -20.97 -13.982 0.78899E+05 -18.002 9 HCl,gas -6.25 -7.86 -1.61 -0.807 0.60709E+04 -1.614 10 acmite 3.62 1.97 -1.66 -0.172 0.62348E+04 12 akimotoite 6.45 2.04 -4.42 -0.883 0.16612E+05 13 akimotoite-Fe 4.27 0.04 -4.23 -0.847 0.15928E+05 14 albite-high -3.90 -4.07 -0.17 -0.013 0.63829E+03 15 albite -3.91 -4.07 -0.16 -0.012 0.60421E+03 16 almandine -5.89 -8.25 -2.35 -0.118 0.88595E+04 17 pyrope 1.02 -2.25 -3.28 -0.164 0.12324E+05 18 analcite -1.67 -2.68 -1.01 -0.113 0.38175E+04 19 andalusite -9.15 -9.75 -0.60 -0.060 0.22525E+04 24 anorthite -6.75 -7.70 -0.95 -0.073 0.35619E+04 25 anthophyllite 16.00 12.85 -3.14 -0.085 0.11820E+05 26 anthophyllite-Fe 2.79 -1.14 -3.92 -0.106 0.14760E+05 28 apatite-OH-zs -51.87 -54.10 -2.23 -0.171 0.83794E+04 29 apatite-Cl-zs -58.67 -61.96 -3.29 -0.274 0.12364E+05 30 aragonite -4.79 -8.61 -3.82 -1.274 0.14374E+05 31 brucite 5.83 3.43 -2.41 -0.481 0.90483E+04 32 calcite -4.90 -8.61 -3.71 -1.237 0.13962E+05 33 carnegieite-low 0.54 -1.29 -1.83 -0.262 0.68899E+04 34 carnegieite-high 0.64 -1.29 -1.92 -0.275 0.72352E+04 35 carpholite-Mg -5.52 -7.72 -2.20 -0.147 0.82692E+04 36 carpholite-Fe -6.94 -9.72 -2.78 -0.185 0.10455E+05 37 celadonite -0.25 -2.50 -2.24 -0.132 0.84431E+04 38 celadonite-Fe -1.71 -4.50 -2.78 -0.164 0.10474E+05 39 chrysotile 10.26 7.49 -2.77 -0.231 0.10421E+05 41 clinochlore 6.59 4.59 -1.99 -0.062 0.75010E+04 42 daphnite -0.80 -5.40 -4.60 -0.144 0.17315E+05 45 chloritoid-Mg -4.80 -6.32 -1.53 -0.102 0.57509E+04 46 chloritoid-Fe -6.83 -8.32 -1.49 -0.099 0.56138E+04 47 chloritoid-Mn -4.69 -6.33 -1.64 -0.109 0.61684E+04 49 coesite -1.09 -1.39 -0.30 -0.099 0.11193E+04 50 cordierite-H -15.49 -16.82 -1.33 -0.047 0.49979E+04 51 cordierite-Fe -18.23 -20.82 -2.59 -0.089 0.97302E+04 52 cordierite-Mn -13.89 -16.84 -2.95 -0.102 0.11085E+05 53 corundum -7.58 -8.36 -0.78 -0.071 0.29394E+04 55 cristobalite -1.34 -1.39 -0.05 -0.016 0.18026E+03 56 cummingtonite 16.07 12.85 -3.21 -0.087 0.12091E+05 58 cymrite-K -2.17 -4.53 -2.37 -0.197 0.89118E+04 60 diaspore -3.31 -4.18 -0.87 -0.146 0.32847E+04 62 diopside 5.73 4.08 -1.64 -0.164 0.61835E+04 63 hedenbergite 4.24 2.09 -2.16 -0.216 0.81100E+04 65 eastonite -2.98 -4.65 -1.66 -0.064 0.62626E+04 66 enstatite 5.22 4.07 -1.15 -0.115 0.43422E+04 67 clinoenstatite-HiP 5.73 4.07 -1.66 -0.166 0.62517E+04 68 clinoenstatite 5.21 4.07 -1.13 -0.113 0.42691E+04 69 protoenstatite 5.36 4.07 -1.29 -0.129 0.48577E+04 70 epidote -2.46 -5.19 -2.73 -0.132 0.10272E+05 71 clinozoisite -6.75 -9.83 -3.09 -0.140 0.11612E+05 72 epidote-Fe 3.54 -0.54 -4.08 -0.212 0.15368E+05 73 fayalite 2.78 1.46 -1.32 -0.188 0.49569E+04 74 ferrosilite 1.49 0.07 -1.42 -0.142 0.53375E+04 75 forsterite 6.94 5.46 -1.48 -0.211 0.55492E+04 76 gedrite -4.98 -7.93 -2.96 -0.080 0.11117E+05 78 gibbsite -1.67 -4.18 -2.51 -0.359 0.94444E+04 79 glaucophane 2.84 -0.65 -3.48 -0.094 0.13108E+05 81 goethite 1.43 0.47 -0.97 -0.209 0.36319E+04 83 greenalite 5.17 1.50 -3.67 -0.306 0.13808E+05 84 grunerite 3.37 -1.14 -4.50 -0.122 0.16940E+05 85 halite -1.52 -3.58 -2.05 -1.027 0.77254E+04 86 hematite 1.31 0.93 -0.38 -0.046 0.14297E+04 87 heulandite -11.32 -14.67 -3.34 -0.152 0.12581E+05 88 hercynite -5.51 -6.93 -1.42 -0.094 0.53302E+04 91 jadeite -0.98 -2.68 -1.70 -0.170 0.63852E+04 93 kalsilite -0.08 -1.75 -1.67 -0.238 0.62708E+04 94 kaolinite -8.38 -11.14 -2.77 -0.252 0.10410E+05 95 kyanite -8.99 -9.75 -0.77 -0.077 0.28785E+04 97 laumontite -6.68 -10.49 -3.81 -0.254 0.14322E+05 98 lawsonite -4.00 -7.70 -3.70 -0.247 0.13925E+05 99 leucite -2.14 -3.14 -1.00 -0.100 0.37591E+04 101 lizardite 10.42 7.49 -2.93 -0.244 0.11011E+05 102 magnesite -5.52 -8.62 -3.10 -1.035 0.11678E+05 103 magnetite 2.84 2.36 -0.48 -0.039 0.18163E+04 104 minnesotaite 1.13 -1.28 -2.41 -0.142 0.90765E+04 105 minnesotaite-Mg 7.34 4.71 -2.62 -0.154 0.98752E+04 106 magnesioferrite 6.02 4.36 -1.66 -0.136 0.62492E+04 108 manganosite 5.73 3.42 -2.31 -0.578 0.87038E+04 109 margarite -13.90 -16.06 -2.16 -0.086 0.81278E+04 113 monticellite 9.32 5.48 -3.84 -0.549 0.14464E+05 115 mullite-Si -8.38 -9.75 -1.37 -0.137 0.51709E+04 116 muscovite -12.00 -12.89 -0.89 -0.053 0.33602E+04 117 paragonite -11.31 -12.43 -1.12 -0.066 0.42186E+04 118 nepheline 0.24 -1.29 -1.52 -0.218 0.57364E+04 119 osumilite(2) -11.23 -13.74 -2.51 -0.052 0.94535E+04 120 osumilite-Fe -25.12 -28.13 -3.02 -0.063 0.11350E+05 121 pargasite 8.93 3.98 -4.95 -0.130 0.18622E+05 122 periclase 6.06 3.43 -2.63 -0.657 0.98917E+04 123 periclase-Fe 3.39 1.43 -1.97 -0.491 0.73924E+04 124 perovskite-Al -5.81 -8.36 -2.55 -0.232 0.96024E+04 129 phlogopite-Na 7.49 6.21 -1.28 -0.071 0.48083E+04 131 prehnite -1.98 -5.65 -3.68 -0.216 0.13838E+05 132 prehnite-Fe 2.71 -1.01 -3.72 -0.224 0.14004E+05 135 px-Mg-tschermaks -4.12 -6.32 -2.20 -0.157 0.82864E+04 136 px-Ca-tschermaks -3.43 -6.31 -2.88 -0.205 0.10818E+05 138 pyrrhotite -8.70 -9.47 -0.76 -0.254 0.28687E+04 139 pyrrhotiteFe0.875 -9.53 -9.88 -0.36 -0.131 0.13363E+04 140 pyrophyllite -12.48 -13.93 -1.45 -0.091 0.54492E+04 143 riebeckite 6.07 2.65 -3.42 -0.094 0.12883E+05 144 ringwoodite-Fe 3.79 1.46 -2.33 -0.332 0.87510E+04 145 ringwoodite-Mg 10.15 5.46 -4.69 -0.670 0.17650E+05 146 rhodochrosite -5.58 -8.63 -3.05 -1.018 0.11487E+05 147 rhodonite 2.68 2.03 -0.65 -0.131 0.24630E+04 148 sanidine -3.98 -4.53 -0.55 -0.042 0.20674E+04 150 siderite -7.43 -10.62 -3.19 -1.062 0.11983E+05 151 sillimanite -9.11 -9.75 -0.64 -0.064 0.24082E+04 153 spinel -3.27 -4.93 -1.67 -0.111 0.62694E+04 160 stilpnomelane-Mg 2.32 -0.45 -2.77 -0.083 0.10429E+05 161 stishovite 1.62 -1.39 -3.01 -1.005 0.11337E+05 162 sudoite-Fe -13.28 -18.04 -4.76 -0.153 0.17893E+05 163 sudoite -10.95 -14.04 -3.09 -0.100 0.11640E+05 164 sulfur -11.34 -12.82 -1.48 -0.455 0.55599E+04 165 sylvite -1.43 -4.04 -2.61 -1.306 0.98227E+04 166 talc 5.58 4.71 -0.86 -0.051 0.32506E+04 167 talc-Fe 2.57 -1.28 -3.85 -0.227 0.14490E+05 168 talc-tschermaks -3.69 -5.68 -1.99 -0.117 0.74898E+04 170 tephroite 7.02 5.44 -1.58 -0.225 0.59252E+04 173 topaz-H -7.06 -9.75 -2.69 -0.245 0.10119E+05 174 tremolite 16.38 12.88 -3.50 -0.095 0.13166E+05 176 troilite-low -8.61 -9.47 -0.85 -0.284 0.32005E+04 177 tschermakite -3.81 -7.91 -4.10 -0.111 0.15418E+05 180 wadsleyite-Fe 3.65 1.46 -2.18 -0.312 0.82185E+04 181 wadsleyite-Mg 9.20 5.46 -3.74 -0.534 0.14054E+05 182 wairakite -8.56 -10.49 -1.92 -0.113 0.72330E+04 183 walstromite 4.74 2.05 -2.69 -0.538 0.10123E+05 184 wollastonite 4.31 2.05 -2.26 -0.451 0.84907E+04 185 pseudo-wollastonite 4.43 2.05 -2.38 -0.476 0.89511E+04 186 zoisite -6.79 -9.83 -3.04 -0.138 0.11433E+05 189 beidellite-Ca -12.45 -14.28 -1.83 -0.113 0.68758E+04 190 beidellite-H -12.50 -14.85 -2.34 -0.149 0.88068E+04 191 beidellite-K -11.47 -13.58 -2.12 -0.130 0.79728E+04 192 beidellite-Mg -12.68 -14.28 -1.60 -0.099 0.60043E+04 193 beidellite-Na -11.41 -13.43 -2.02 -0.124 0.76177E+04 194 bornite -56.28 -56.49 -0.21 -0.015 0.77815E+03 196 chalcocite -14.82 -16.25 -1.43 -0.357 0.53716E+04 197 covellite -13.21 -14.53 -1.32 -0.503 0.49676E+04 199 montmorillonite-Ca -9.44 -10.85 -1.40 -0.087 0.52793E+04 200 montmorillonite-K -8.73 -10.15 -1.42 -0.087 0.53448E+04 201 montmorillonite-Mg -9.64 -10.85 -1.21 -0.075 0.45340E+04 202 montmorillonite-Na -8.41 -10.00 -1.59 -0.098 0.59992E+04 203 nontronite-Ca -3.29 -4.99 -1.70 -0.110 0.63928E+04 204 nontronite-H -3.35 -5.55 -2.20 -0.148 0.82946E+04 205 nontronite-K -2.30 -4.29 -1.99 -0.128 0.74834E+04 206 nontronite-Mg -3.49 -4.99 -1.50 -0.097 0.56372E+04 207 nontronite-Na -2.24 -4.14 -1.90 -0.122 0.71397E+04 212 gypsum -12.88 -15.15 -2.27 -0.569 0.85582E+04 229 alabandite -6.43 -7.48 -1.05 -0.348 0.39318E+04 231 anglesite -15.50 -17.80 -2.30 -1.149 0.86476E+04 235 boehmite -3.00 -4.18 -1.18 -0.196 0.44323E+04 239 copper,native 1.69 -1.71 -3.40 -1.183 0.12793E+05 241 ferrous-oxide 2.45 1.43 -1.02 -0.256 0.38526E+04 243 silver,native 0.37 -3.64 -4.01 -1.395 0.15084E+05 245 litharge 5.46 0.79 -4.67 -1.167 0.17567E+05 253 wurtzite -10.21 -11.03 -0.82 -0.274 0.30887E+04 254 zincite 2.51 -0.14 -2.65 -0.663 0.99793E+04 255 an20ab80 -4.70 -4.80 -0.10 -0.008 0.37684E+03 256 an25ab75 -4.87 -4.98 -0.11 -0.009 0.42618E+03 257 an30ab70 -5.03 -5.16 -0.13 -0.010 0.49385E+03 258 tr.625ac.25prg.125 11.19 9.27 -1.92 -0.052 0.72118E+04 Calculations done for 549.0000 Deg. C; 934.0000 bar Temperature changed by -1.000 degrees to 548.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 49 Loop limit = 500 Temperature = 548.00 C Pressure = 923.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5514E+02 kg liquid = 0.9934E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9970 Stoichiometric ionic strength = .3271151E+01 Osmotic coef. = 0.0000 True ionic strength = .1622259E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.52612E-05 -5.2789 0.78485E-06 -6.1052 0.14918E+00 -0.8263 2 H2O 0.99696E+00 -0.0013 0.99696E+00 -0.0013 3 Cl- 0.13698E+00 -0.8633 0.16588E-01 -1.7802 0.12110E+00 -0.9169 4 SO4-- 0.63958E-03 -3.1941 0.38123E-06 -6.4188 0.59607E-03 -3.2247 5 HCO3- 0.79337E-05 -5.1005 0.10508E-05 -5.9785 0.13244E+00 -0.8780 6 HS- 0.12568E-03 -3.9007 0.15371E-04 -4.8133 0.12230E+00 -0.9126 7 H4SiO4 0.39568E-01 -1.4027 0.39568E-01 -1.4027 0.10000E+01 0.0000 8 Al+++ 0.92966E-15 -15.0317 0.37252E-22 -22.4289 0.40070E-07 -7.3972 9 Ca++ 0.38613E-05 -5.4133 0.17499E-08 -8.7570 0.45319E-03 -3.3437 10 Mg++ 0.45314E-05 -5.3438 0.16188E-08 -8.7908 0.35725E-03 -3.4470 11 Fe++ 0.45569E-07 -7.3413 0.17288E-10 -10.7623 0.37939E-03 -3.4209 12 K+ 0.37899E-01 -1.4214 0.51643E-02 -2.2870 0.13626E+00 -0.8656 13 Na+ 0.12220E+00 -0.9129 0.14982E-01 -1.8244 0.12260E+00 -0.9115 14 Mn++ 0.42088E-05 -5.3758 0.16686E-08 -8.7776 0.39645E-03 -3.4018 15 Zn++ 0.12384E-08 -8.9071 0.46983E-12 -12.3281 0.37939E-03 -3.4209 16 Cu+ 0.13421E-07 -7.8722 0.16402E-08 -8.7851 0.12221E+00 -0.9129 17 Pb++ 0.74158E-08 -8.1298 0.38622E-11 -11.4132 0.52080E-03 -3.2833 18 Ag+ 0.12437E-09 -9.9053 0.16624E-10 -10.7793 0.13367E+00 -0.8740 19 Ba++ 0.15543E-06 -6.8085 0.88417E-10 -10.0535 0.56886E-03 -3.2450 20 HPO4-- 0.42784E-08 -8.3687 0.25660E-11 -11.5907 0.59976E-03 -3.2220 21 HSiO3- 0.13868E-05 -5.8580 0.16794E-06 -6.7748 0.12110E+00 -0.9169 22 Ca(HSiO3)+ 0.44589E-08 -8.3508 0.61415E-09 -9.2117 0.13774E+00 -0.8610 23 Mg(HSiO3)+ 0.14407E-08 -8.8414 0.19843E-09 -9.7024 0.13774E+00 -0.8610 24 NaHSiO3,aq 0.17687E-05 -5.7523 0.17687E-05 -5.7523 0.10000E+01 0.0000 28 AgCl,aq 0.46376E-07 -7.3337 0.46376E-07 -7.3337 0.10000E+01 0.0000 29 AgCl2- 0.22466E-05 -5.6485 0.27207E-06 -6.5653 0.12110E+00 -0.9169 30 AgCl3-2 0.13121E-05 -5.8820 0.71140E-09 -9.1479 0.54221E-03 -3.2658 31 AgCl4-3 0.51494E-05 -5.2882 0.17746E-12 -12.7509 0.34462E-07 -7.4627 34 Ag(HS),aq 0.89839E-09 -9.0465 0.89839E-09 -9.0465 0.10000E+01 0.0000 35 Ag(HS)2- 0.29406E-08 -8.5316 0.35610E-09 -9.4484 0.12110E+00 -0.9169 36 AlO+ 0.19913E-10 -10.7009 0.27428E-11 -11.5618 0.13774E+00 -0.8610 38 HAlO2,aq 0.48755E-08 -8.3120 0.48755E-08 -8.3120 0.10000E+01 0.0000 39 AlO2- 0.13074E-04 -4.8836 0.13546E-05 -5.8682 0.10361E+00 -0.9846 41 Ba(HCO3)+ 0.16367E-06 -6.7860 0.23668E-07 -7.6258 0.14461E+00 -0.8398 42 BaCl+ 0.72695E-05 -5.1385 0.10013E-05 -5.9994 0.13774E+00 -0.8610 43 CH4,aq 0.12752E-08 -8.8944 0.14982E-08 -8.8244 0.11749E+01 0.0700 48 CO,aq 0.40866E-03 -3.3886 0.40866E-03 -3.3886 0.10000E+01 0.0000 49 CO2,aq 0.26733E+01 0.4270 0.31407E+01 0.4970 0.11749E+01 0.0700 50 CO3-2 0.82008E-10 -10.0861 0.44465E-13 -13.3520 0.54221E-03 -3.2658 52 Ca(HCO3)+ 0.76901E-07 -7.1141 0.10592E-07 -7.9750 0.13774E+00 -0.8610 53 CaCl+ 0.74899E-04 -4.1255 0.10316E-04 -4.9865 0.13774E+00 -0.8610 54 CaCl2,aq 0.67628E-04 -4.1699 0.67628E-04 -4.1699 0.10000E+01 0.0000 55 CaOH+ 0.13341E-06 -6.8748 0.18375E-07 -7.7358 0.13774E+00 -0.8610 56 CaSO4,aq 0.19719E-06 -6.7051 0.19719E-06 -6.7051 0.10000E+01 0.0000 57 HCl,aq 0.50565E-02 -2.2961 0.50565E-02 -2.2961 0.10000E+01 0.0000 66 CuCl,aq 0.19985E-04 -4.6993 0.19985E-04 -4.6993 0.10000E+01 0.0000 67 CuCl2- 0.78407E-04 -4.1056 0.94951E-05 -5.0225 0.12110E+00 -0.9169 68 CuCl3-2 0.25558E-05 -5.5925 0.13858E-08 -8.8583 0.54221E-03 -3.2658 74 FeCl+ 0.26708E-06 -6.5734 0.36787E-07 -7.4343 0.13774E+00 -0.8610 75 FeCl2,aq 0.20224E-02 -2.6941 0.20224E-02 -2.6941 0.10000E+01 0.0000 77 FeO,aq 0.43280E-07 -7.3637 0.43280E-07 -7.3637 0.10000E+01 0.0000 78 FeOH+ 0.21107E-07 -7.6756 0.29072E-08 -8.5365 0.13774E+00 -0.8610 79 HFeO2- 0.53398E-08 -8.2725 0.64664E-09 -9.1893 0.12110E+00 -0.9169 82 FeO2- 0.32077E-08 -8.4938 0.38845E-09 -9.4107 0.12110E+00 -0.9169 83 HFeO2,aq 0.26527E-09 -9.5763 0.26527E-09 -9.5763 0.10000E+01 0.0000 84 H2,aq 0.41448E-02 -2.3825 0.48696E-02 -2.3125 0.11749E+01 0.0700 85 KCl,aq 0.70127E-01 -1.1541 0.70127E-01 -1.1541 0.10000E+01 0.0000 86 KHSO4,aq 0.12145E-01 -1.9156 0.12145E-01 -1.9156 0.10000E+01 0.0000 87 KOH,aq 0.12761E-05 -5.8941 0.12761E-05 -5.8941 0.10000E+01 0.0000 88 KSO4- 0.53815E-02 -2.2691 0.65169E-03 -3.1860 0.12110E+00 -0.9169 90 Mg(HCO3)+ 0.22243E-07 -7.6528 0.30636E-08 -8.5138 0.13774E+00 -0.8610 91 MgCl+ 0.15714E-04 -4.8037 0.21644E-05 -5.6647 0.13774E+00 -0.8610 92 MgOH+ 0.54384E-06 -6.2645 0.74906E-07 -7.1255 0.13774E+00 -0.8610 94 MnO,aq 0.75228E-07 -7.1236 0.75228E-07 -7.1236 0.10000E+01 0.0000 95 MnOH+ 0.21258E-06 -6.6725 0.29280E-07 -7.5334 0.13774E+00 -0.8610 97 HMnO2- 0.34322E-10 -10.4644 0.41564E-11 -11.3813 0.12110E+00 -0.9169 100 MnCl+ 0.11524E-02 -2.9384 0.15873E-03 -3.7993 0.13774E+00 -0.8610 101 MnSO4,aq 0.18986E-06 -6.7216 0.18986E-06 -6.7216 0.10000E+01 0.0000 102 NaCl,aq 0.43606E+00 -0.3604 0.43606E+00 -0.3604 0.10000E+01 0.0000 103 NaOH,aq 0.16791E-05 -5.7749 0.16791E-05 -5.7749 0.10000E+01 0.0000 105 OH- 0.81570E-05 -5.0885 0.84515E-06 -6.0731 0.10361E+00 -0.9846 110 HPO3-2 0.20426E-10 -10.6898 0.11075E-13 -13.9556 0.54221E-03 -3.2658 111 H3PO3,aq 0.13362E-09 -9.8741 0.13362E-09 -9.8741 0.10000E+01 0.0000 112 H2PO3- 0.17341E-08 -8.7609 0.20999E-09 -9.6778 0.12110E+00 -0.9169 113 H3PO4,aq 0.20047E-05 -5.6979 0.20047E-05 -5.6979 0.10000E+01 0.0000 114 H2PO4- 0.17785E-05 -5.7500 0.22871E-06 -6.6407 0.12860E+00 -0.8907 116 H4P2O7,aq 0.38062E-09 -9.4195 0.38062E-09 -9.4195 0.10000E+01 0.0000 117 H3P2O7- 0.13456E-08 -8.8711 0.16295E-09 -9.7879 0.12110E+00 -0.9169 118 H2P2O7-2 0.56148E-06 -6.2507 0.30444E-09 -9.5165 0.54221E-03 -3.2658 119 HP2O7-3 0.31637E-06 -6.4998 0.10903E-13 -13.9625 0.34462E-07 -7.4627 121 PbCl+ 0.12242E-05 -5.9121 0.16862E-06 -6.7731 0.13774E+00 -0.8610 122 PbCl2,aq 0.80330E-04 -4.0951 0.80330E-04 -4.0951 0.10000E+01 0.0000 123 PbCl3- 0.10852E-03 -3.9645 0.13142E-04 -4.8813 0.12110E+00 -0.9169 124 PbCl4-2 0.31888E-04 -4.4964 0.17290E-07 -7.7622 0.54221E-03 -3.2658 125 PbO,aq 0.60353E-08 -8.2193 0.60353E-08 -8.2193 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10802E-03 -3.9665 0.10802E-03 -3.9665 0.10000E+01 0.0000 128 Pb(HS)3- 0.13866E-04 -4.8580 0.16792E-05 -5.7749 0.12110E+00 -0.9169 129 H2S,aq 0.10588E+01 0.0248 0.12440E+01 0.0948 0.11749E+01 0.0700 130 S2-2 0.24675E-07 -7.6077 0.13379E-10 -10.8736 0.54221E-03 -3.2658 131 S3-2 0.22752E-08 -8.6430 0.12336E-11 -11.9088 0.54221E-03 -3.2658 132 S3- 0.86115E-02 -2.0649 0.10428E-02 -2.9818 0.12110E+00 -0.9169 133 S4-2 0.17995E-09 -9.7448 0.97571E-13 -13.0107 0.54221E-03 -3.2658 134 S5-2 0.12496E-10 -10.9032 0.67755E-14 -14.1691 0.54221E-03 -3.2658 135 SO2,aq 0.29355E+00 -0.5323 0.29355E+00 -0.5323 0.10000E+01 0.0000 136 SO3-2 0.14158E-08 -8.8490 0.13563E-11 -11.8676 0.95801E-03 -3.0186 137 HSO3- 0.23407E-03 -3.6307 0.28345E-04 -4.5475 0.12110E+00 -0.9169 138 HSO4- 0.85454E-02 -2.0683 0.12177E-02 -2.9145 0.14249E+00 -0.8462 140 S2O3-2 0.11911E-05 -5.9240 0.64584E-09 -9.1899 0.54221E-03 -3.2658 141 HS2O3- 0.37102E-06 -6.4306 0.44930E-07 -7.3475 0.12110E+00 -0.9169 142 H2S2O3,aq 0.43433E-07 -7.3622 0.43433E-07 -7.3622 0.10000E+01 0.0000 150 S4O6-2 0.95512E-09 -9.0199 0.51787E-12 -12.2858 0.54221E-03 -3.2658 152 ZnCl+ 0.13756E-03 -3.8615 0.18947E-04 -4.7225 0.13774E+00 -0.8610 153 ZnCl2,aq 0.51998E-03 -3.2840 0.51998E-03 -3.2840 0.10000E+01 0.0000 154 ZnCl3- 0.35364E-04 -4.4514 0.42826E-05 -5.3683 0.12110E+00 -0.9169 155 ZnO,aq 0.23195E-07 -7.6346 0.23195E-07 -7.6346 0.10000E+01 0.0000 156 ZnOH+ 0.96502E-06 -6.0155 0.13292E-06 -6.8764 0.13774E+00 -0.8610 158 HZnO2- 0.18782E-09 -9.7263 0.22744E-10 -10.6431 0.12110E+00 -0.9169 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5261185E-05 0.4293558E+01 0.3544010E+04 -0.0000 2 H2O 0.1000000E+01 0.5252368E+02 0.7748891E+06 0.0000 3 Cl- 0.1369785E+00 0.6557691E+00 0.1903912E+05 4.3250 4 SO4-- 0.6395779E-03 0.2512971E+00 0.1976880E+05 5.7916 5 HCO3- 0.7933738E-05 0.2673679E+01 0.1335994E+06 0.1267 6 HS- 0.1256798E-03 0.1154257E+01 0.3126121E+05 1.2919 7 H4SiO4 0.3956786E-01 0.3957102E-01 0.3114678E+04 -1.4027 8 Al+++ 0.9296588E-15 0.1307876E-04 0.2889851E+00 -4.1132 9 Ca++ 0.3861275E-05 0.1468001E-03 0.4818094E+01 3.4534 10 Mg++ 0.4531413E-05 0.2081340E-04 0.4143874E+00 3.4196 11 Fe++ 0.4556865E-07 0.2022814E-02 0.9251212E+02 1.4482 12 K+ 0.3789911E-01 0.1255535E+00 0.4020413E+04 3.8182 13 Na+ 0.1221994E+00 0.5582672E+00 0.1051042E+05 4.2808 14 Mn++ 0.4208815E-05 0.1157102E-02 0.5205800E+02 3.4328 15 Zn++ 0.1238382E-08 0.6938910E-03 0.3714605E+02 -0.1176 16 Cu+ 0.1342060E-07 0.1009617E-03 0.5253478E+01 -2.6799 17 Pb++ 0.7415766E-08 0.3438684E-03 0.5834504E+02 0.7973 18 Ag+ 0.1243681E-09 0.8758386E-05 0.7736912E+00 -4.6740 19 Ba++ 0.1554294E-06 0.7588604E-05 0.8534967E+00 2.1570 20 HPO4-- 0.4278366E-08 0.5548524E-05 0.4361106E+00 0.6197 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265348E+01 -.2986245E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5217859E+02 -.2138100E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2496461E+00 0.2076709E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1146673E+01 0.1347113E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3931103E-01 0.1042833E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1299283E-04 0.6815467E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1458356E-03 0.3820743E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2009524E-02 0.6757230E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247286E+00 0.6815467E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.6893320E-03 0.1610003E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1002984E-03 0.2993113E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3416091E-03 -.1436464E-05 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7538746E-05 0.4783371E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.5512070E-05 0.3055431E-05 0.0000000E+00 Chg. balance for solid moles: -.9910E-18 Mass of aqueous solution: 0.121309E+04 g Temperature = 548.00 C Pressure = 923.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3770E-03 -3.424 0.5132E-01 -1.290 0.6953 0.1732E-01 apatite-OH 0.1018E-05 -5.992 0.5116E-03 -3.291 0.6931E-02 0.1626E-03 microcline 0.6815E-03 -3.167 0.1897 -0.722 2.570 0.7410E-01 pyrite 0.6458E-02 -2.190 0.7748 -0.111 10.50 0.1546 quartz 0.1022 -0.990 6.142 0.788 83.22 2.320 barite 0.4783E-04 -4.320 0.1116E-01 -1.952 0.1512 0.2492E-02 chalcopyrite 0.2993E-03 -3.524 0.5492E-01 -1.260 0.7441 0.1282E-01 galena -.1436E-05 1.000 -.3437E-03 1.000 -.4656E-02 -.4523E-04 sphalerite 0.1610E-02 -2.793 0.1569 -0.804 2.125 0.3836E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.381462 g Volume = 2.619483 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.18 -15.18 -0.00 -0.000 0.66746E-11 27 apatite-OH -54.14 -54.14 0.00 0.000 0.00000E+00 112 microcline -4.50 -4.50 0.00 0.000 -0.13349E-10 137 pyrite -22.32 -22.32 0.00 0.000 -0.26698E-10 141 quartz -1.40 -1.40 0.00 0.000 0.00000E+00 234 barite -16.47 -16.47 0.00 0.000 0.00000E+00 237 chalcopyrite -24.03 -24.03 0.00 0.000 0.00000E+00 252 sphalerite -11.04 -11.04 -0.00 -0.000 0.66746E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.254 0.95538E+03 2.711 2 CO2,gas -10.34 -12.08 -1.74 -0.581 0.65514E+04 1.222 3 CH4,gas 6.79 -4.37 -11.16 -2.790 0.41932E+05 -8.194 4 H2,gas 6.03 1.93 -4.10 -2.345 0.15422E+05 -1.139 5 H2S,gas -8.61 -10.92 -2.31 -1.154 0.86709E+04 0.658 6 CO,gas -4.00 -10.15 -6.16 -1.895 0.23135E+05 -3.192 7 SO3,gas -7.83 -18.63 -10.80 -2.700 0.40586E+05 -7.836 8 O2,gas 17.14 -3.86 -21.00 -13.999 0.78903E+05 -18.034 9 HCl,gas -6.26 -7.89 -1.62 -0.812 0.60990E+04 -1.623 10 acmite 3.63 1.96 -1.67 -0.173 0.62571E+04 12 akimotoite 6.48 2.02 -4.46 -0.892 0.16751E+05 13 akimotoite-Fe 4.29 0.05 -4.24 -0.849 0.15949E+05 14 albite-high -3.86 -4.04 -0.17 -0.013 0.64517E+03 15 albite -3.87 -4.04 -0.16 -0.012 0.60740E+03 16 almandine -5.72 -8.09 -2.37 -0.119 0.89134E+04 17 pyrope 1.21 -2.18 -3.39 -0.170 0.12740E+05 18 analcite -1.62 -2.64 -1.02 -0.113 0.38205E+04 19 andalusite -9.03 -9.63 -0.60 -0.060 0.22416E+04 24 anorthite -6.63 -7.58 -0.95 -0.073 0.35724E+04 25 anthophyllite 16.13 12.73 -3.40 -0.092 0.12789E+05 26 anthophyllite-Fe 2.89 -1.07 -3.96 -0.107 0.14887E+05 28 apatite-OH-zs -51.91 -54.14 -2.23 -0.172 0.83819E+04 29 apatite-Cl-zs -58.73 -62.02 -3.29 -0.274 0.12363E+05 30 aragonite -4.80 -8.63 -3.83 -1.278 0.14402E+05 31 brucite 5.86 3.42 -2.44 -0.489 0.91799E+04 32 calcite -4.91 -8.63 -3.72 -1.241 0.13988E+05 33 carnegieite-low 0.60 -1.24 -1.83 -0.262 0.68917E+04 34 carnegieite-high 0.69 -1.24 -1.93 -0.275 0.72398E+04 35 carpholite-Mg -5.38 -7.61 -2.23 -0.149 0.83816E+04 36 carpholite-Fe -6.81 -9.59 -2.78 -0.185 0.10448E+05 37 celadonite -0.20 -2.48 -2.28 -0.134 0.85744E+04 38 celadonite-Fe -1.66 -4.45 -2.79 -0.164 0.10488E+05 39 chrysotile 10.33 7.45 -2.88 -0.240 0.10821E+05 41 clinochlore 6.82 4.66 -2.17 -0.068 0.81467E+04 42 daphnite -0.58 -5.20 -4.62 -0.144 0.17366E+05 45 chloritoid-Mg -4.65 -6.21 -1.56 -0.104 0.58691E+04 46 chloritoid-Fe -6.69 -8.18 -1.49 -0.100 0.56098E+04 47 chloritoid-Mn -4.56 -6.20 -1.64 -0.110 0.61767E+04 49 coesite -1.10 -1.40 -0.30 -0.099 0.11203E+04 50 cordierite-H -15.23 -16.63 -1.40 -0.050 0.52608E+04 51 cordierite-Fe -17.97 -20.57 -2.59 -0.089 0.97482E+04 52 cordierite-Mn -13.64 -16.60 -2.96 -0.102 0.11127E+05 53 corundum -7.45 -8.23 -0.78 -0.071 0.29296E+04 55 cristobalite -1.35 -1.40 -0.05 -0.016 0.18040E+03 56 cummingtonite 16.20 12.73 -3.48 -0.094 0.13061E+05 58 cymrite-K -2.13 -4.50 -2.37 -0.198 0.89140E+04 60 diaspore -3.24 -4.12 -0.87 -0.145 0.32731E+04 62 diopside 5.76 4.07 -1.69 -0.169 0.63416E+04 63 hedenbergite 4.27 2.10 -2.17 -0.217 0.81488E+04 65 eastonite -2.76 -4.49 -1.74 -0.067 0.65235E+04 66 enstatite 5.27 4.04 -1.23 -0.123 0.46229E+04 67 clinoenstatite-HiP 5.78 4.04 -1.74 -0.174 0.65323E+04 68 clinoenstatite 5.25 4.04 -1.21 -0.121 0.45483E+04 69 protoenstatite 5.40 4.04 -1.37 -0.137 0.51382E+04 70 epidote -2.30 -5.04 -2.74 -0.133 0.10309E+05 71 clinozoisite -6.55 -9.64 -3.10 -0.141 0.11630E+05 72 epidote-Fe 3.66 -0.45 -4.10 -0.213 0.15422E+05 73 fayalite 2.82 1.49 -1.33 -0.190 0.49970E+04 74 ferrosilite 1.52 0.09 -1.43 -0.143 0.53777E+04 75 forsterite 6.99 5.44 -1.55 -0.222 0.58279E+04 76 gedrite -4.63 -7.77 -3.14 -0.085 0.11788E+05 78 gibbsite -1.61 -4.12 -2.51 -0.358 0.94269E+04 79 glaucophane 2.98 -0.62 -3.60 -0.097 0.13512E+05 81 goethite 1.45 0.48 -0.97 -0.210 0.36428E+04 83 greenalite 5.22 1.54 -3.69 -0.307 0.13848E+05 84 grunerite 3.47 -1.07 -4.54 -0.123 0.17068E+05 85 halite -1.55 -3.60 -2.06 -1.028 0.77270E+04 86 hematite 1.35 0.97 -0.39 -0.047 0.14571E+04 87 heulandite -11.24 -14.59 -3.35 -0.152 0.12585E+05 88 hercynite -5.36 -6.78 -1.42 -0.095 0.53413E+04 91 jadeite -0.94 -2.64 -1.70 -0.170 0.63855E+04 93 kalsilite -0.03 -1.70 -1.67 -0.238 0.62730E+04 94 kaolinite -8.27 -11.03 -2.76 -0.251 0.10375E+05 95 kyanite -8.87 -9.63 -0.76 -0.076 0.28677E+04 97 laumontite -6.57 -10.38 -3.81 -0.254 0.14313E+05 98 lawsonite -3.88 -7.58 -3.70 -0.247 0.13917E+05 99 leucite -2.10 -3.10 -1.00 -0.100 0.37632E+04 101 lizardite 10.49 7.45 -3.04 -0.253 0.11406E+05 102 magnesite -5.52 -8.66 -3.15 -1.049 0.11825E+05 103 magnetite 2.91 2.41 -0.50 -0.041 0.18645E+04 104 minnesotaite 1.17 -1.26 -2.43 -0.143 0.91231E+04 105 minnesotaite-Mg 7.39 4.65 -2.74 -0.161 0.10281E+05 106 magnesioferrite 6.09 4.38 -1.71 -0.139 0.64178E+04 108 manganosite 5.76 3.43 -2.32 -0.581 0.87358E+04 109 margarite -13.65 -15.81 -2.16 -0.086 0.81179E+04 113 monticellite 9.36 5.47 -3.89 -0.556 0.14621E+05 115 mullite-Si -8.26 -9.63 -1.37 -0.137 0.51633E+04 116 muscovite -11.84 -12.73 -0.89 -0.052 0.33438E+04 117 paragonite -11.15 -12.27 -1.12 -0.066 0.42033E+04 118 nepheline 0.29 -1.24 -1.53 -0.218 0.57372E+04 119 osumilite(2) -11.05 -13.67 -2.63 -0.055 0.98690E+04 120 osumilite-Fe -24.84 -27.86 -3.03 -0.063 0.11377E+05 122 periclase 6.09 3.42 -2.67 -0.667 0.10031E+05 123 periclase-Fe 3.42 1.45 -1.97 -0.493 0.74127E+04 124 perovskite-Al -5.68 -8.23 -2.55 -0.232 0.95926E+04 129 phlogopite-Na 7.61 6.22 -1.39 -0.077 0.52202E+04 131 prehnite -1.84 -5.53 -3.69 -0.217 0.13857E+05 132 prehnite-Fe 2.81 -0.93 -3.74 -0.225 0.14042E+05 135 px-Mg-tschermaks -3.97 -6.21 -2.24 -0.160 0.84185E+04 136 px-Ca-tschermaks -3.30 -6.18 -2.88 -0.206 0.10827E+05 138 pyrrhotite -8.70 -9.47 -0.77 -0.256 0.28826E+04 139 pyrrhotiteFe0.875 -9.53 -9.89 -0.36 -0.132 0.13488E+04 140 pyrophyllite -12.39 -13.83 -1.45 -0.090 0.54295E+04 143 riebeckite 6.12 2.67 -3.45 -0.095 0.12974E+05 144 ringwoodite-Fe 3.83 1.49 -2.34 -0.334 0.87877E+04 145 ringwoodite-Mg 10.21 5.44 -4.77 -0.682 0.17927E+05 146 rhodochrosite -5.58 -8.65 -3.07 -1.022 0.11526E+05 147 rhodonite 2.70 2.03 -0.66 -0.133 0.24957E+04 148 sanidine -3.95 -4.50 -0.55 -0.042 0.20673E+04 150 siderite -7.44 -10.64 -3.20 -1.065 0.12009E+05 151 sillimanite -8.99 -9.63 -0.64 -0.064 0.23987E+04 153 spinel -3.11 -4.81 -1.70 -0.114 0.63993E+04 160 stilpnomelane-Mg 2.51 -0.44 -2.95 -0.088 0.11091E+05 161 stishovite 1.62 -1.40 -3.02 -1.006 0.11336E+05 162 sudoite-Fe -13.01 -17.77 -4.76 -0.154 0.17899E+05 163 sudoite -10.67 -13.83 -3.16 -0.102 0.11884E+05 164 sulfur -11.37 -12.84 -1.48 -0.455 0.55541E+04 165 sylvite -1.45 -4.07 -2.61 -1.307 0.98226E+04 166 talc 5.63 4.65 -0.97 -0.057 0.36562E+04 167 talc-Fe 2.61 -1.26 -3.87 -0.228 0.14538E+05 168 talc-tschermaks -3.53 -5.60 -2.06 -0.121 0.77477E+04 170 tephroite 7.06 5.46 -1.59 -0.228 0.59879E+04 173 topaz-H -6.94 -9.63 -2.69 -0.244 0.10097E+05 174 tremolite 16.49 12.79 -3.70 -0.100 0.13889E+05 176 troilite-low -8.61 -9.47 -0.86 -0.285 0.32140E+04 177 tschermakite -3.49 -7.70 -4.22 -0.114 0.15841E+05 180 wadsleyite-Fe 3.69 1.49 -2.20 -0.314 0.82579E+04 181 wadsleyite-Mg 9.25 5.44 -3.81 -0.545 0.14333E+05 182 wairakite -8.46 -10.38 -1.92 -0.113 0.72315E+04 183 walstromite 4.75 2.05 -2.70 -0.540 0.10141E+05 184 wollastonite 4.32 2.05 -2.26 -0.453 0.85087E+04 185 pseudo-wollastonite 4.44 2.05 -2.39 -0.477 0.89698E+04 186 zoisite -6.59 -9.64 -3.05 -0.139 0.11452E+05 189 beidellite-Ca -12.33 -14.16 -1.83 -0.113 0.68581E+04 190 beidellite-H -12.39 -14.73 -2.34 -0.149 0.87846E+04 191 beidellite-K -11.35 -13.47 -2.12 -0.130 0.79536E+04 192 beidellite-Mg -12.56 -14.16 -1.60 -0.099 0.60073E+04 193 beidellite-Na -11.29 -13.32 -2.02 -0.124 0.75981E+04 194 bornite -56.39 -56.59 -0.20 -0.015 0.75299E+03 196 chalcocite -14.85 -16.28 -1.43 -0.356 0.53547E+04 197 covellite -13.24 -14.56 -1.32 -0.502 0.49516E+04 199 montmorillonite-Ca -9.36 -10.78 -1.41 -0.087 0.53106E+04 200 montmorillonite-K -8.65 -10.09 -1.43 -0.088 0.53784E+04 201 montmorillonite-Mg -9.56 -10.78 -1.22 -0.075 0.45852E+04 202 montmorillonite-Na -8.33 -9.93 -1.60 -0.098 0.60288E+04 203 nontronite-Ca -3.25 -4.96 -1.71 -0.111 0.64143E+04 204 nontronite-H -3.32 -5.53 -2.21 -0.148 0.83125E+04 205 nontronite-K -2.27 -4.27 -2.00 -0.128 0.75040E+04 206 nontronite-Mg -3.46 -4.97 -1.51 -0.098 0.56789E+04 207 nontronite-Na -2.21 -4.12 -1.91 -0.122 0.71600E+04 212 gypsum -12.90 -15.18 -2.28 -0.569 0.85534E+04 229 alabandite -6.43 -7.49 -1.05 -0.351 0.39611E+04 231 anglesite -15.53 -17.83 -2.30 -1.149 0.86361E+04 235 boehmite -2.94 -4.12 -1.18 -0.196 0.44233E+04 239 copper,native 1.69 -1.72 -3.40 -1.183 0.12782E+05 241 ferrous-oxide 2.48 1.45 -1.03 -0.258 0.38737E+04 242 galena -10.12 -10.12 0.00 0.000 -0.66746E-11 243 silver,native 0.37 -3.71 -4.08 -1.418 0.15323E+05 245 litharge 5.47 0.80 -4.68 -1.169 0.17569E+05 253 wurtzite -10.21 -11.04 -0.82 -0.274 0.30891E+04 254 zincite 2.54 -0.12 -2.66 -0.664 0.99835E+04 255 an20ab80 -4.64 -4.74 -0.10 -0.008 0.38281E+03 256 an25ab75 -4.81 -4.92 -0.12 -0.009 0.43258E+03 257 an30ab70 -4.96 -5.10 -0.13 -0.010 0.50063E+03 258 tr.625ac.25prg.125 11.32 9.24 -2.07 -0.056 0.77797E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 33 Loop limit = 500 Temperature = 548.00 C Pressure = 923.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5514E+02 kg liquid = 0.9934E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9970 Stoichiometric ionic strength = .3271148E+01 Osmotic coef. = 0.0000 True ionic strength = .1622241E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.52613E-05 -5.2789 0.78487E-06 -6.1052 0.14918E+00 -0.8263 2 H2O 0.99696E+00 -0.0013 0.99696E+00 -0.0013 3 Cl- 0.13698E+00 -0.8633 0.16588E-01 -1.7802 0.12110E+00 -0.9169 4 SO4-- 0.63953E-03 -3.1941 0.38122E-06 -6.4188 0.59608E-03 -3.2247 5 HCO3- 0.79335E-05 -5.1005 0.10507E-05 -5.9785 0.13244E+00 -0.8780 6 HS- 0.12568E-03 -3.9007 0.15371E-04 -4.8133 0.12231E+00 -0.9126 7 H4SiO4 0.39568E-01 -1.4027 0.39568E-01 -1.4027 0.10000E+01 0.0000 8 Al+++ 0.92969E-15 -15.0317 0.37255E-22 -22.4288 0.40073E-07 -7.3971 9 Ca++ 0.38613E-05 -5.4133 0.17500E-08 -8.7570 0.45320E-03 -3.3437 10 Mg++ 0.45313E-05 -5.3438 0.16189E-08 -8.7908 0.35726E-03 -3.4470 11 Fe++ 0.45569E-07 -7.3413 0.17289E-10 -10.7622 0.37940E-03 -3.4209 12 K+ 0.37899E-01 -1.4214 0.51643E-02 -2.2870 0.13627E+00 -0.8656 13 Na+ 0.12220E+00 -0.9129 0.14982E-01 -1.8244 0.12261E+00 -0.9115 14 Mn++ 0.42087E-05 -5.3759 0.16686E-08 -8.7776 0.39647E-03 -3.4018 15 Zn++ 0.12384E-08 -8.9071 0.46985E-12 -12.3280 0.37940E-03 -3.4209 16 Cu+ 0.13421E-07 -7.8722 0.16402E-08 -8.7851 0.12221E+00 -0.9129 17 Pb++ 0.73845E-08 -8.1317 0.38460E-11 -11.4150 0.52082E-03 -3.2833 18 Ag+ 0.12437E-09 -9.9053 0.16625E-10 -10.7792 0.13367E+00 -0.8740 19 Ba++ 0.15543E-06 -6.8085 0.88421E-10 -10.0534 0.56887E-03 -3.2450 20 HPO4-- 0.42781E-08 -8.3688 0.25659E-11 -11.5908 0.59978E-03 -3.2220 21 HSiO3- 0.13868E-05 -5.8580 0.16794E-06 -6.7749 0.12110E+00 -0.9169 22 Ca(HSiO3)+ 0.44590E-08 -8.3508 0.61417E-09 -9.2117 0.13774E+00 -0.8610 23 Mg(HSiO3)+ 0.14406E-08 -8.8415 0.19842E-09 -9.7024 0.13774E+00 -0.8610 24 NaHSiO3,aq 0.17687E-05 -5.7524 0.17687E-05 -5.7524 0.10000E+01 0.0000 28 AgCl,aq 0.46377E-07 -7.3337 0.46377E-07 -7.3337 0.10000E+01 0.0000 29 AgCl2- 0.22467E-05 -5.6485 0.27207E-06 -6.5653 0.12110E+00 -0.9169 30 AgCl3-2 0.13121E-05 -5.8820 0.71143E-09 -9.1479 0.54222E-03 -3.2658 31 AgCl4-3 0.51493E-05 -5.2883 0.17747E-12 -12.7509 0.34464E-07 -7.4626 34 Ag(HS),aq 0.89838E-09 -9.0465 0.89838E-09 -9.0465 0.10000E+01 0.0000 35 Ag(HS)2- 0.29404E-08 -8.5316 0.35609E-09 -9.4484 0.12110E+00 -0.9169 36 AlO+ 0.19914E-10 -10.7008 0.27429E-11 -11.5618 0.13774E+00 -0.8610 38 HAlO2,aq 0.48756E-08 -8.3120 0.48756E-08 -8.3120 0.10000E+01 0.0000 39 AlO2- 0.13074E-04 -4.8836 0.13546E-05 -5.8682 0.10361E+00 -0.9846 41 Ba(HCO3)+ 0.16367E-06 -6.7860 0.23669E-07 -7.6258 0.14461E+00 -0.8398 42 BaCl+ 0.72698E-05 -5.1385 0.10013E-05 -5.9994 0.13774E+00 -0.8610 43 CH4,aq 0.12752E-08 -8.8944 0.14982E-08 -8.8244 0.11749E+01 0.0700 48 CO,aq 0.40866E-03 -3.3886 0.40866E-03 -3.3886 0.10000E+01 0.0000 49 CO2,aq 0.26733E+01 0.4270 0.31407E+01 0.4970 0.11749E+01 0.0700 50 CO3-2 0.82001E-10 -10.0862 0.44463E-13 -13.3520 0.54222E-03 -3.2658 52 Ca(HCO3)+ 0.76901E-07 -7.1141 0.10592E-07 -7.9750 0.13774E+00 -0.8610 53 CaCl+ 0.74902E-04 -4.1255 0.10317E-04 -4.9865 0.13774E+00 -0.8610 54 CaCl2,aq 0.67632E-04 -4.1698 0.67632E-04 -4.1698 0.10000E+01 0.0000 55 CaOH+ 0.13341E-06 -6.8748 0.18376E-07 -7.7358 0.13774E+00 -0.8610 56 CaSO4,aq 0.19719E-06 -6.7051 0.19719E-06 -6.7051 0.10000E+01 0.0000 57 HCl,aq 0.50567E-02 -2.2961 0.50567E-02 -2.2961 0.10000E+01 0.0000 66 CuCl,aq 0.19986E-04 -4.6993 0.19986E-04 -4.6993 0.10000E+01 0.0000 67 CuCl2- 0.78410E-04 -4.1056 0.94955E-05 -5.0225 0.12110E+00 -0.9169 68 CuCl3-2 0.25559E-05 -5.5925 0.13858E-08 -8.8583 0.54222E-03 -3.2658 74 FeCl+ 0.26710E-06 -6.5733 0.36789E-07 -7.4343 0.13774E+00 -0.8610 75 FeCl2,aq 0.20226E-02 -2.6941 0.20226E-02 -2.6941 0.10000E+01 0.0000 77 FeO,aq 0.43280E-07 -7.3637 0.43280E-07 -7.3637 0.10000E+01 0.0000 78 FeOH+ 0.21108E-07 -7.6756 0.29073E-08 -8.5365 0.13774E+00 -0.8610 79 HFeO2- 0.53396E-08 -8.2725 0.64663E-09 -9.1893 0.12110E+00 -0.9169 82 FeO2- 0.32076E-08 -8.4938 0.38844E-09 -9.4107 0.12110E+00 -0.9169 83 HFeO2,aq 0.26527E-09 -9.5763 0.26527E-09 -9.5763 0.10000E+01 0.0000 84 H2,aq 0.41448E-02 -2.3825 0.48696E-02 -2.3125 0.11749E+01 0.0700 85 KCl,aq 0.70128E-01 -1.1541 0.70128E-01 -1.1541 0.10000E+01 0.0000 86 KHSO4,aq 0.12145E-01 -1.9156 0.12145E-01 -1.9156 0.10000E+01 0.0000 87 KOH,aq 0.12761E-05 -5.8941 0.12761E-05 -5.8941 0.10000E+01 0.0000 88 KSO4- 0.53812E-02 -2.2691 0.65167E-03 -3.1860 0.12110E+00 -0.9169 90 Mg(HCO3)+ 0.22242E-07 -7.6528 0.30636E-08 -8.5138 0.13774E+00 -0.8610 91 MgCl+ 0.15715E-04 -4.8037 0.21645E-05 -5.6646 0.13774E+00 -0.8610 92 MgOH+ 0.54383E-06 -6.2645 0.74905E-07 -7.1255 0.13774E+00 -0.8610 94 MnO,aq 0.75224E-07 -7.1236 0.75224E-07 -7.1236 0.10000E+01 0.0000 95 MnOH+ 0.21257E-06 -6.6725 0.29279E-07 -7.5334 0.13774E+00 -0.8610 97 HMnO2- 0.34319E-10 -10.4645 0.41561E-11 -11.3813 0.12110E+00 -0.9169 100 MnCl+ 0.11524E-02 -2.9384 0.15873E-03 -3.7993 0.13774E+00 -0.8610 101 MnSO4,aq 0.18985E-06 -6.7216 0.18985E-06 -6.7216 0.10000E+01 0.0000 102 NaCl,aq 0.43607E+00 -0.3604 0.43607E+00 -0.3604 0.10000E+01 0.0000 103 NaOH,aq 0.16790E-05 -5.7749 0.16790E-05 -5.7749 0.10000E+01 0.0000 105 OH- 0.81567E-05 -5.0885 0.84513E-06 -6.0731 0.10361E+00 -0.9846 110 HPO3-2 0.20425E-10 -10.6898 0.11075E-13 -13.9557 0.54222E-03 -3.2658 111 H3PO3,aq 0.13362E-09 -9.8741 0.13362E-09 -9.8741 0.10000E+01 0.0000 112 H2PO3- 0.17340E-08 -8.7609 0.20999E-09 -9.6778 0.12110E+00 -0.9169 113 H3PO4,aq 0.20048E-05 -5.6979 0.20048E-05 -5.6979 0.10000E+01 0.0000 114 H2PO4- 0.17784E-05 -5.7500 0.22871E-06 -6.6407 0.12860E+00 -0.8907 116 H4P2O7,aq 0.38062E-09 -9.4195 0.38062E-09 -9.4195 0.10000E+01 0.0000 117 H3P2O7- 0.13456E-08 -8.8711 0.16295E-09 -9.7879 0.12110E+00 -0.9169 118 H2P2O7-2 0.56145E-06 -6.2507 0.30443E-09 -9.5165 0.54222E-03 -3.2658 119 HP2O7-3 0.31633E-06 -6.4999 0.10902E-13 -13.9625 0.34464E-07 -7.4626 121 PbCl+ 0.12191E-05 -5.9140 0.16792E-06 -6.7749 0.13774E+00 -0.8610 122 PbCl2,aq 0.79994E-04 -4.0969 0.79994E-04 -4.0969 0.10000E+01 0.0000 123 PbCl3- 0.10807E-03 -3.9663 0.13087E-04 -4.8831 0.12110E+00 -0.9169 124 PbCl4-2 0.31754E-04 -4.4982 0.17218E-07 -7.7640 0.54222E-03 -3.2658 125 PbO,aq 0.60097E-08 -8.2211 0.60097E-08 -8.2211 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10756E-03 -3.9683 0.10756E-03 -3.9683 0.10000E+01 0.0000 128 Pb(HS)3- 0.13807E-04 -4.8599 0.16720E-05 -5.7768 0.12110E+00 -0.9169 129 H2S,aq 0.10588E+01 0.0248 0.12440E+01 0.0948 0.11749E+01 0.0700 130 S2-2 0.24674E-07 -7.6078 0.13379E-10 -10.8736 0.54222E-03 -3.2658 131 S3-2 0.22750E-08 -8.6430 0.12336E-11 -11.9088 0.54222E-03 -3.2658 132 S3- 0.86112E-02 -2.0649 0.10428E-02 -2.9818 0.12110E+00 -0.9169 133 S4-2 0.17994E-09 -9.7449 0.97567E-13 -13.0107 0.54222E-03 -3.2658 134 S5-2 0.12495E-10 -10.9033 0.67752E-14 -14.1691 0.54222E-03 -3.2658 135 SO2,aq 0.29355E+00 -0.5323 0.29355E+00 -0.5323 0.10000E+01 0.0000 136 SO3-2 0.14157E-08 -8.8490 0.13563E-11 -11.8677 0.95803E-03 -3.0186 137 HSO3- 0.23406E-03 -3.6307 0.28345E-04 -4.5475 0.12110E+00 -0.9169 138 HSO4- 0.85452E-02 -2.0683 0.12176E-02 -2.9145 0.14250E+00 -0.8462 140 S2O3-2 0.11911E-05 -5.9241 0.64581E-09 -9.1899 0.54222E-03 -3.2658 141 HS2O3- 0.37101E-06 -6.4306 0.44929E-07 -7.3475 0.12110E+00 -0.9169 142 H2S2O3,aq 0.43433E-07 -7.3622 0.43433E-07 -7.3622 0.10000E+01 0.0000 150 S4O6-2 0.95506E-09 -9.0200 0.51785E-12 -12.2858 0.54222E-03 -3.2658 152 ZnCl+ 0.13757E-03 -3.8615 0.18948E-04 -4.7224 0.13774E+00 -0.8610 153 ZnCl2,aq 0.52001E-03 -3.2840 0.52001E-03 -3.2840 0.10000E+01 0.0000 154 ZnCl3- 0.35366E-04 -4.4514 0.42829E-05 -5.3683 0.12110E+00 -0.9169 155 ZnO,aq 0.23195E-07 -7.6346 0.23195E-07 -7.6346 0.10000E+01 0.0000 156 ZnOH+ 0.96504E-06 -6.0155 0.13292E-06 -6.8764 0.13774E+00 -0.8610 158 HZnO2- 0.18781E-09 -9.7263 0.22744E-10 -10.6431 0.12110E+00 -0.9169 Charge balance for all species = 0.2548E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5261278E-05 0.4293559E+01 0.3544012E+04 -0.0000 2 H2O 0.1000000E+01 0.5252368E+02 0.7748893E+06 0.0000 3 Cl- 0.1369785E+00 0.6557691E+00 0.1903913E+05 4.3250 4 SO4-- 0.6395337E-03 0.2512972E+00 0.1976881E+05 5.7916 5 HCO3- 0.7933489E-05 0.2673679E+01 0.1335994E+06 0.1267 6 HS- 0.1256758E-03 0.1154255E+01 0.3126118E+05 1.2919 7 H4SiO4 0.3956786E-01 0.3957102E-01 0.3114679E+04 -1.4027 8 Al+++ 0.9296889E-15 0.1307861E-04 0.2889820E+00 -4.1132 9 Ca++ 0.3861330E-05 0.1468073E-03 0.4818332E+01 3.4534 10 Mg++ 0.4531307E-05 0.2081340E-04 0.4143876E+00 3.4196 11 Fe++ 0.4556943E-07 0.2022939E-02 0.9251787E+02 1.4482 12 K+ 0.3789892E-01 0.1255535E+00 0.4020414E+04 3.8182 13 Na+ 0.1221979E+00 0.5582672E+00 0.1051043E+05 4.2808 14 Mn++ 0.4208689E-05 0.1157102E-02 0.5205802E+02 3.4328 15 Zn++ 0.1238405E-08 0.6939328E-03 0.3714830E+02 -0.1176 16 Cu+ 0.1342083E-07 0.1009649E-03 0.5253647E+01 -2.6799 17 Pb++ 0.7384455E-08 0.3424224E-03 0.5809971E+02 0.7954 18 Ag+ 0.1243696E-09 0.8758386E-05 0.7736914E+00 -4.6740 19 Ba++ 0.1554319E-06 0.7588924E-05 0.8535330E+00 2.1570 20 HPO4-- 0.4278087E-08 0.5548365E-05 0.4360981E+00 0.6196 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265350E+01 -.2987668E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5217859E+02 -.2138099E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2496461E+00 0.2076671E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1146672E+01 0.1347231E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3931103E-01 0.1042833E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1299268E-04 0.6815468E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1458428E-03 0.3820671E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.2009648E-02 0.6757106E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247286E+00 0.6815468E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.6893736E-03 0.1609961E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1003016E-03 0.2993081E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7539064E-05 0.4783339E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.5511911E-05 0.3055589E-05 0.0000000E+00 Chg. balance for solid moles: 0.4520E-17 Mass of aqueous solution: 0.121309E+04 g Temperature = 548.00 C Pressure = 923.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3770E-03 -3.424 0.5132E-01 -1.290 0.6952 0.1732E-01 apatite-OH 0.1019E-05 -5.992 0.5116E-03 -3.291 0.6931E-02 0.1626E-03 microcline 0.6815E-03 -3.167 0.1897 -0.722 2.570 0.7410E-01 pyrite 0.6458E-02 -2.190 0.7748 -0.111 10.50 0.1546 quartz 0.1022 -0.990 6.142 0.788 83.21 2.320 barite 0.4783E-04 -4.320 0.1116E-01 -1.952 0.1512 0.2492E-02 chalcopyrite 0.2993E-03 -3.524 0.5492E-01 -1.260 0.7440 0.1282E-01 sphalerite 0.1610E-02 -2.793 0.1569 -0.804 2.125 0.3836E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.381785 g Volume = 2.619524 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.18 -15.18 0.00 0.000 0.00000E+00 27 apatite-OH -54.14 -54.14 -0.00 -0.000 0.53397E-10 112 microcline -4.50 -4.50 -0.00 -0.000 0.13349E-10 137 pyrite -22.32 -22.32 0.00 0.000 0.00000E+00 141 quartz -1.40 -1.40 -0.00 -0.000 0.83432E-12 234 barite -16.47 -16.47 0.00 0.000 0.00000E+00 237 chalcopyrite -24.03 -24.03 0.00 0.000 0.00000E+00 252 sphalerite -11.04 -11.04 -0.00 -0.000 0.66746E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.254 0.95538E+03 2.711 2 CO2,gas -10.34 -12.08 -1.74 -0.581 0.65514E+04 1.222 3 CH4,gas 6.79 -4.37 -11.16 -2.790 0.41932E+05 -8.194 4 H2,gas 6.03 1.93 -4.10 -2.345 0.15422E+05 -1.139 5 H2S,gas -8.61 -10.92 -2.31 -1.154 0.86709E+04 0.658 6 CO,gas -4.00 -10.15 -6.16 -1.895 0.23135E+05 -3.192 7 SO3,gas -7.83 -18.63 -10.80 -2.700 0.40586E+05 -7.836 8 O2,gas 17.14 -3.86 -21.00 -13.999 0.78903E+05 -18.034 9 HCl,gas -6.26 -7.89 -1.62 -0.812 0.60989E+04 -1.623 10 acmite 3.63 1.96 -1.67 -0.173 0.62572E+04 12 akimotoite 6.48 2.02 -4.46 -0.892 0.16751E+05 13 akimotoite-Fe 4.29 0.05 -4.24 -0.849 0.15949E+05 14 albite-high -3.86 -4.04 -0.17 -0.013 0.64518E+03 15 albite -3.87 -4.04 -0.16 -0.012 0.60741E+03 16 almandine -5.72 -8.09 -2.37 -0.119 0.89133E+04 17 pyrope 1.21 -2.18 -3.39 -0.170 0.12740E+05 18 analcite -1.62 -2.64 -1.02 -0.113 0.38205E+04 19 andalusite -9.03 -9.63 -0.60 -0.060 0.22415E+04 24 anorthite -6.63 -7.58 -0.95 -0.073 0.35723E+04 25 anthophyllite 16.13 12.73 -3.40 -0.092 0.12790E+05 26 anthophyllite-Fe 2.89 -1.07 -3.96 -0.107 0.14887E+05 28 apatite-OH-zs -51.91 -54.14 -2.23 -0.172 0.83819E+04 29 apatite-Cl-zs -58.73 -62.02 -3.29 -0.274 0.12363E+05 30 aragonite -4.80 -8.63 -3.83 -1.278 0.14402E+05 31 brucite 5.86 3.42 -2.44 -0.489 0.91800E+04 32 calcite -4.91 -8.63 -3.72 -1.241 0.13988E+05 33 carnegieite-low 0.60 -1.24 -1.83 -0.262 0.68917E+04 34 carnegieite-high 0.69 -1.24 -1.93 -0.275 0.72398E+04 35 carpholite-Mg -5.38 -7.61 -2.23 -0.149 0.83816E+04 36 carpholite-Fe -6.81 -9.59 -2.78 -0.185 0.10448E+05 37 celadonite -0.20 -2.48 -2.28 -0.134 0.85745E+04 38 celadonite-Fe -1.66 -4.45 -2.79 -0.164 0.10488E+05 39 chrysotile 10.33 7.45 -2.88 -0.240 0.10821E+05 41 clinochlore 6.82 4.66 -2.17 -0.068 0.81469E+04 42 daphnite -0.58 -5.20 -4.62 -0.144 0.17366E+05 45 chloritoid-Mg -4.65 -6.21 -1.56 -0.104 0.58691E+04 46 chloritoid-Fe -6.69 -8.18 -1.49 -0.100 0.56097E+04 47 chloritoid-Mn -4.56 -6.20 -1.64 -0.110 0.61767E+04 49 coesite -1.10 -1.40 -0.30 -0.099 0.11203E+04 50 cordierite-H -15.23 -16.63 -1.40 -0.050 0.52608E+04 51 cordierite-Fe -17.97 -20.57 -2.59 -0.089 0.97481E+04 52 cordierite-Mn -13.64 -16.60 -2.96 -0.102 0.11127E+05 53 corundum -7.45 -8.23 -0.78 -0.071 0.29295E+04 55 cristobalite -1.35 -1.40 -0.05 -0.016 0.18040E+03 56 cummingtonite 16.20 12.73 -3.48 -0.094 0.13062E+05 58 cymrite-K -2.13 -4.50 -2.37 -0.198 0.89140E+04 60 diaspore -3.24 -4.12 -0.87 -0.145 0.32730E+04 62 diopside 5.76 4.07 -1.69 -0.169 0.63417E+04 63 hedenbergite 4.27 2.10 -2.17 -0.217 0.81488E+04 65 eastonite -2.76 -4.49 -1.74 -0.067 0.65235E+04 66 enstatite 5.27 4.04 -1.23 -0.123 0.46231E+04 67 clinoenstatite-HiP 5.78 4.04 -1.74 -0.174 0.65324E+04 68 clinoenstatite 5.25 4.04 -1.21 -0.121 0.45485E+04 69 protoenstatite 5.40 4.04 -1.37 -0.137 0.51384E+04 70 epidote -2.30 -5.04 -2.74 -0.133 0.10309E+05 71 clinozoisite -6.55 -9.64 -3.10 -0.141 0.11630E+05 72 epidote-Fe 3.66 -0.45 -4.10 -0.213 0.15422E+05 73 fayalite 2.82 1.49 -1.33 -0.190 0.49970E+04 74 ferrosilite 1.52 0.09 -1.43 -0.143 0.53777E+04 75 forsterite 6.99 5.44 -1.55 -0.222 0.58280E+04 76 gedrite -4.63 -7.77 -3.14 -0.085 0.11788E+05 78 gibbsite -1.61 -4.12 -2.51 -0.358 0.94268E+04 79 glaucophane 2.98 -0.62 -3.60 -0.097 0.13512E+05 81 goethite 1.45 0.48 -0.97 -0.210 0.36428E+04 83 greenalite 5.22 1.54 -3.69 -0.307 0.13848E+05 84 grunerite 3.47 -1.07 -4.54 -0.123 0.17068E+05 85 halite -1.55 -3.60 -2.06 -1.028 0.77270E+04 86 hematite 1.35 0.97 -0.39 -0.047 0.14571E+04 87 heulandite -11.24 -14.59 -3.35 -0.152 0.12585E+05 88 hercynite -5.36 -6.78 -1.42 -0.095 0.53413E+04 91 jadeite -0.94 -2.64 -1.70 -0.170 0.63855E+04 93 kalsilite -0.03 -1.70 -1.67 -0.238 0.62730E+04 94 kaolinite -8.27 -11.03 -2.76 -0.251 0.10374E+05 95 kyanite -8.87 -9.63 -0.76 -0.076 0.28677E+04 97 laumontite -6.57 -10.38 -3.81 -0.254 0.14313E+05 98 lawsonite -3.88 -7.58 -3.70 -0.247 0.13917E+05 99 leucite -2.10 -3.10 -1.00 -0.100 0.37632E+04 101 lizardite 10.49 7.45 -3.04 -0.253 0.11406E+05 102 magnesite -5.52 -8.66 -3.15 -1.049 0.11825E+05 103 magnetite 2.91 2.41 -0.50 -0.041 0.18645E+04 104 minnesotaite 1.17 -1.26 -2.43 -0.143 0.91231E+04 105 minnesotaite-Mg 7.39 4.65 -2.74 -0.161 0.10281E+05 106 magnesioferrite 6.09 4.38 -1.71 -0.139 0.64179E+04 108 manganosite 5.76 3.43 -2.32 -0.581 0.87358E+04 109 margarite -13.65 -15.81 -2.16 -0.086 0.81178E+04 113 monticellite 9.36 5.47 -3.89 -0.556 0.14621E+05 115 mullite-Si -8.26 -9.63 -1.37 -0.137 0.51632E+04 116 muscovite -11.84 -12.73 -0.89 -0.052 0.33437E+04 117 paragonite -11.15 -12.27 -1.12 -0.066 0.42032E+04 118 nepheline 0.29 -1.24 -1.53 -0.218 0.57372E+04 119 osumilite(2) -11.05 -13.67 -2.63 -0.055 0.98691E+04 120 osumilite-Fe -24.84 -27.86 -3.03 -0.063 0.11376E+05 122 periclase 6.09 3.42 -2.67 -0.667 0.10031E+05 123 periclase-Fe 3.42 1.45 -1.97 -0.493 0.74127E+04 124 perovskite-Al -5.68 -8.23 -2.55 -0.232 0.95925E+04 129 phlogopite-Na 7.61 6.22 -1.39 -0.077 0.52205E+04 131 prehnite -1.84 -5.53 -3.69 -0.217 0.13857E+05 132 prehnite-Fe 2.81 -0.93 -3.74 -0.225 0.14042E+05 135 px-Mg-tschermaks -3.97 -6.21 -2.24 -0.160 0.84184E+04 136 px-Ca-tschermaks -3.30 -6.18 -2.88 -0.206 0.10827E+05 138 pyrrhotite -8.70 -9.47 -0.77 -0.256 0.28826E+04 139 pyrrhotiteFe0.875 -9.53 -9.89 -0.36 -0.132 0.13488E+04 140 pyrophyllite -12.39 -13.83 -1.44 -0.090 0.54295E+04 143 riebeckite 6.12 2.67 -3.45 -0.095 0.12974E+05 144 ringwoodite-Fe 3.83 1.49 -2.34 -0.334 0.87877E+04 145 ringwoodite-Mg 10.21 5.44 -4.77 -0.682 0.17927E+05 146 rhodochrosite -5.58 -8.65 -3.07 -1.023 0.11526E+05 147 rhodonite 2.70 2.03 -0.66 -0.133 0.24958E+04 148 sanidine -3.95 -4.50 -0.55 -0.042 0.20673E+04 150 siderite -7.44 -10.64 -3.20 -1.065 0.12009E+05 151 sillimanite -8.99 -9.63 -0.64 -0.064 0.23986E+04 153 spinel -3.11 -4.81 -1.70 -0.114 0.63993E+04 160 stilpnomelane-Mg 2.51 -0.44 -2.95 -0.088 0.11092E+05 161 stishovite 1.62 -1.40 -3.02 -1.006 0.11336E+05 162 sudoite-Fe -13.01 -17.77 -4.76 -0.154 0.17899E+05 163 sudoite -10.67 -13.83 -3.16 -0.102 0.11884E+05 164 sulfur -11.37 -12.84 -1.48 -0.455 0.55541E+04 165 sylvite -1.45 -4.07 -2.61 -1.307 0.98226E+04 166 talc 5.63 4.65 -0.97 -0.057 0.36564E+04 167 talc-Fe 2.61 -1.26 -3.87 -0.228 0.14538E+05 168 talc-tschermaks -3.53 -5.60 -2.06 -0.121 0.77478E+04 170 tephroite 7.06 5.46 -1.59 -0.228 0.59881E+04 173 topaz-H -6.94 -9.63 -2.69 -0.244 0.10097E+05 174 tremolite 16.49 12.79 -3.70 -0.100 0.13889E+05 176 troilite-low -8.61 -9.47 -0.86 -0.285 0.32140E+04 177 tschermakite -3.49 -7.70 -4.22 -0.114 0.15841E+05 180 wadsleyite-Fe 3.69 1.49 -2.20 -0.314 0.82579E+04 181 wadsleyite-Mg 9.25 5.44 -3.81 -0.545 0.14333E+05 182 wairakite -8.46 -10.38 -1.92 -0.113 0.72314E+04 183 walstromite 4.75 2.05 -2.70 -0.540 0.10141E+05 184 wollastonite 4.32 2.05 -2.26 -0.453 0.85087E+04 185 pseudo-wollastonite 4.44 2.05 -2.39 -0.477 0.89698E+04 186 zoisite -6.59 -9.64 -3.05 -0.139 0.11452E+05 189 beidellite-Ca -12.33 -14.16 -1.83 -0.113 0.68580E+04 190 beidellite-H -12.39 -14.73 -2.34 -0.149 0.87846E+04 191 beidellite-K -11.35 -13.47 -2.12 -0.130 0.79535E+04 192 beidellite-Mg -12.56 -14.16 -1.60 -0.099 0.60072E+04 193 beidellite-Na -11.29 -13.32 -2.02 -0.124 0.75980E+04 194 bornite -56.39 -56.59 -0.20 -0.015 0.75298E+03 196 chalcocite -14.85 -16.28 -1.43 -0.356 0.53547E+04 197 covellite -13.24 -14.56 -1.32 -0.502 0.49516E+04 199 montmorillonite-Ca -9.36 -10.78 -1.41 -0.087 0.53105E+04 200 montmorillonite-K -8.65 -10.09 -1.43 -0.088 0.53783E+04 201 montmorillonite-Mg -9.56 -10.78 -1.22 -0.075 0.45852E+04 202 montmorillonite-Na -8.33 -9.93 -1.60 -0.098 0.60288E+04 203 nontronite-Ca -3.25 -4.96 -1.71 -0.111 0.64143E+04 204 nontronite-H -3.32 -5.53 -2.21 -0.148 0.83125E+04 205 nontronite-K -2.27 -4.27 -2.00 -0.128 0.75040E+04 206 nontronite-Mg -3.46 -4.97 -1.51 -0.098 0.56789E+04 207 nontronite-Na -2.21 -4.12 -1.91 -0.122 0.71600E+04 212 gypsum -12.90 -15.18 -2.28 -0.569 0.85534E+04 229 alabandite -6.43 -7.49 -1.05 -0.351 0.39612E+04 231 anglesite -15.53 -17.83 -2.30 -1.150 0.86431E+04 235 boehmite -2.94 -4.12 -1.18 -0.196 0.44233E+04 239 copper,native 1.69 -1.72 -3.40 -1.183 0.12782E+05 241 ferrous-oxide 2.48 1.45 -1.03 -0.258 0.38737E+04 242 galena -10.12 -10.12 -0.00 -0.001 0.69388E+01 243 silver,native 0.37 -3.71 -4.08 -1.418 0.15323E+05 245 litharge 5.47 0.79 -4.68 -1.169 0.17576E+05 253 wurtzite -10.21 -11.04 -0.82 -0.274 0.30891E+04 254 zincite 2.54 -0.12 -2.66 -0.664 0.99835E+04 255 an20ab80 -4.64 -4.74 -0.10 -0.008 0.38281E+03 256 an25ab75 -4.81 -4.92 -0.12 -0.009 0.43257E+03 257 an30ab70 -4.96 -5.10 -0.13 -0.010 0.50061E+03 258 tr.625ac.25prg.125 11.32 9.24 -2.07 -0.056 0.77800E+04 Calculations done for 548.0000 Deg. C; 923.0000 bar Temperature changed by -1.000 degrees to 547.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 51 Loop limit = 500 Temperature = 547.00 C Pressure = 912.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5514E+02 kg liquid = 0.9935E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9970 Stoichiometric ionic strength = .3270834E+01 Osmotic coef. = 0.0000 True ionic strength = .1644021E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.53265E-05 -5.2736 0.76422E-06 -6.1168 0.14347E+00 -0.8432 2 H2O 0.99698E+00 -0.0013 0.99698E+00 -0.0013 3 Cl- 0.13884E+00 -0.8575 0.16074E-01 -1.7939 0.11577E+00 -0.9364 4 SO4-- 0.72148E-03 -3.1418 0.36661E-06 -6.4358 0.50814E-03 -3.2940 5 HCO3- 0.78361E-05 -5.1059 0.99421E-06 -6.0025 0.12688E+00 -0.8966 6 HS- 0.12765E-03 -3.8940 0.14929E-04 -4.8260 0.11695E+00 -0.9320 7 H4SiO4 0.38772E-01 -1.4115 0.38772E-01 -1.4115 0.10000E+01 0.0000 8 Al+++ 0.14451E-14 -14.8401 0.39991E-22 -22.3980 0.27674E-07 -7.5579 9 Ca++ 0.44534E-05 -5.3513 0.17090E-08 -8.7673 0.38374E-03 -3.4160 10 Mg++ 0.50155E-05 -5.2997 0.15088E-08 -8.8214 0.30083E-03 -3.5217 11 Fe++ 0.53632E-07 -7.2706 0.17158E-10 -10.7655 0.31992E-03 -3.4950 12 K+ 0.38295E-01 -1.4169 0.50020E-02 -2.3009 0.13062E+00 -0.8840 13 Na+ 0.12389E+00 -0.9070 0.14524E-01 -1.8379 0.11723E+00 -0.9310 14 Mn++ 0.49073E-05 -5.3092 0.16422E-08 -8.7846 0.33465E-03 -3.4754 15 Zn++ 0.14600E-08 -8.8356 0.46709E-12 -12.3306 0.31992E-03 -3.4950 16 Cu+ 0.13519E-07 -7.8691 0.15796E-08 -8.8015 0.11685E+00 -0.9324 17 Pb++ 0.83315E-08 -8.0793 0.36863E-11 -11.4334 0.44245E-03 -3.3541 18 Ag+ 0.10556E-09 -9.9765 0.13520E-10 -10.8690 0.12807E+00 -0.8925 19 Ba++ 0.17451E-06 -6.7582 0.84511E-10 -10.0731 0.48429E-03 -3.3149 20 HPO4-- 0.48881E-08 -8.3109 0.24996E-11 -11.6021 0.51136E-03 -3.2913 21 HSiO3- 0.14033E-05 -5.8529 0.16246E-06 -6.7893 0.11577E+00 -0.9364 22 Ca(HSiO3)+ 0.45176E-08 -8.3451 0.59659E-09 -9.2243 0.13206E+00 -0.8792 23 Mg(HSiO3)+ 0.14051E-08 -8.8523 0.18555E-09 -9.7315 0.13206E+00 -0.8792 24 NaHSiO3,aq 0.17620E-05 -5.7540 0.17620E-05 -5.7540 0.10000E+01 0.0000 28 AgCl,aq 0.38888E-07 -7.4102 0.38888E-07 -7.4102 0.10000E+01 0.0000 29 AgCl2- 0.19048E-05 -5.7201 0.22052E-06 -6.6565 0.11577E+00 -0.9364 30 AgCl3-2 0.11947E-05 -5.9227 0.55100E-09 -9.2588 0.46119E-03 -3.3361 31 AgCl4-3 0.56163E-05 -5.2505 0.13331E-12 -12.8751 0.23736E-07 -7.6246 34 Ag(HS),aq 0.76408E-09 -9.1169 0.76408E-09 -9.1169 0.10000E+01 0.0000 35 Ag(HS)2- 0.24955E-08 -8.6028 0.28890E-09 -9.5393 0.11577E+00 -0.9364 36 AlO+ 0.21470E-10 -10.6682 0.28353E-11 -11.5474 0.13206E+00 -0.8792 38 HAlO2,aq 0.49445E-08 -8.3059 0.49445E-08 -8.3059 0.10000E+01 0.0000 39 AlO2- 0.13437E-04 -4.8717 0.13263E-05 -5.8774 0.98702E-01 -1.0057 41 Ba(HCO3)+ 0.16114E-06 -6.7928 0.22369E-07 -7.6504 0.13881E+00 -0.8576 42 BaCl+ 0.72489E-05 -5.1397 0.95728E-06 -6.0190 0.13206E+00 -0.8792 43 CH4,aq 0.12626E-08 -8.8987 0.14817E-08 -8.8292 0.11735E+01 0.0695 48 CO,aq 0.40170E-03 -3.3961 0.40170E-03 -3.3961 0.10000E+01 0.0000 49 CO2,aq 0.26732E+01 0.4270 0.31369E+01 0.4965 0.11735E+01 0.0695 50 CO3-2 0.91294E-10 -10.0396 0.42104E-13 -13.3757 0.46119E-03 -3.3361 52 Ca(HCO3)+ 0.75619E-07 -7.1214 0.99863E-08 -8.0006 0.13206E+00 -0.8792 53 CaCl+ 0.75743E-04 -4.1207 0.10003E-04 -4.9999 0.13206E+00 -0.8792 54 CaCl2,aq 0.66865E-04 -4.1748 0.66865E-04 -4.1748 0.10000E+01 0.0000 55 CaOH+ 0.13459E-06 -6.8710 0.17774E-07 -7.7502 0.13206E+00 -0.8792 56 CaSO4,aq 0.19971E-06 -6.6996 0.19971E-06 -6.6996 0.10000E+01 0.0000 57 HCl,aq 0.53076E-02 -2.2751 0.53076E-02 -2.2751 0.10000E+01 0.0000 66 CuCl,aq 0.19823E-04 -4.7028 0.19823E-04 -4.7028 0.10000E+01 0.0000 67 CuCl2- 0.79298E-04 -4.1007 0.91803E-05 -5.0371 0.11577E+00 -0.9364 68 CuCl3-2 0.27781E-05 -5.5563 0.12812E-08 -8.8924 0.46119E-03 -3.3361 74 FeCl+ 0.27438E-06 -6.5616 0.36235E-07 -7.4409 0.13206E+00 -0.8792 75 FeCl2,aq 0.19685E-02 -2.7059 0.19685E-02 -2.7059 0.10000E+01 0.0000 77 FeO,aq 0.42648E-07 -7.3701 0.42648E-07 -7.3701 0.10000E+01 0.0000 78 FeOH+ 0.21645E-07 -7.6646 0.28584E-08 -8.5439 0.13206E+00 -0.8792 79 HFeO2- 0.53981E-08 -8.2678 0.62493E-09 -9.2042 0.11577E+00 -0.9364 82 FeO2- 0.32045E-08 -8.4942 0.37098E-09 -9.4306 0.11577E+00 -0.9364 83 HFeO2,aq 0.26628E-09 -9.5747 0.26628E-09 -9.5747 0.10000E+01 0.0000 84 H2,aq 0.41376E-02 -2.3833 0.48553E-02 -2.3138 0.11735E+01 0.0695 85 KCl,aq 0.69816E-01 -1.1560 0.69816E-01 -1.1560 0.10000E+01 0.0000 86 KHSO4,aq 0.11977E-01 -1.9217 0.11977E-01 -1.9217 0.10000E+01 0.0000 87 KOH,aq 0.12695E-05 -5.8964 0.12695E-05 -5.8964 0.10000E+01 0.0000 88 KSO4- 0.54618E-02 -2.2627 0.63231E-03 -3.1991 0.11577E+00 -0.9364 90 Mg(HCO3)+ 0.20656E-07 -7.6850 0.27278E-08 -8.5642 0.13206E+00 -0.8792 91 MgCl+ 0.15250E-04 -4.8167 0.20139E-05 -5.6960 0.13206E+00 -0.8792 92 MgOH+ 0.52548E-06 -6.2794 0.69395E-07 -7.1587 0.13206E+00 -0.8792 94 MnO,aq 0.73947E-07 -7.1311 0.73947E-07 -7.1311 0.10000E+01 0.0000 95 MnOH+ 0.21475E-06 -6.6681 0.28359E-07 -7.5473 0.13206E+00 -0.8792 97 HMnO2- 0.34324E-10 -10.4644 0.39736E-11 -11.4008 0.11577E+00 -0.9364 100 MnCl+ 0.11517E-02 -2.9387 0.15209E-03 -3.8179 0.13206E+00 -0.8792 101 MnSO4,aq 0.19212E-06 -6.7164 0.19212E-06 -6.7164 0.10000E+01 0.0000 102 NaCl,aq 0.43436E+00 -0.3621 0.43436E+00 -0.3621 0.10000E+01 0.0000 103 NaOH,aq 0.16689E-05 -5.7776 0.16689E-05 -5.7776 0.10000E+01 0.0000 105 OH- 0.83613E-05 -5.0777 0.82528E-06 -6.0834 0.98702E-01 -1.0057 110 HPO3-2 0.22528E-10 -10.6473 0.10390E-13 -13.9834 0.46119E-03 -3.3361 111 H3PO3,aq 0.13494E-09 -9.8699 0.13494E-09 -9.8699 0.10000E+01 0.0000 112 H2PO3- 0.17230E-08 -8.7637 0.19948E-09 -9.7001 0.11577E+00 -0.9364 113 H3PO4,aq 0.20614E-05 -5.6858 0.20614E-05 -5.6858 0.10000E+01 0.0000 114 H2PO4- 0.18139E-05 -5.7414 0.22331E-06 -6.6511 0.12311E+00 -0.9097 116 H4P2O7,aq 0.40415E-09 -9.3935 0.40415E-09 -9.3935 0.10000E+01 0.0000 117 H3P2O7- 0.13831E-08 -8.8592 0.16012E-09 -9.7956 0.11577E+00 -0.9364 118 H2P2O7-2 0.62068E-06 -6.2071 0.28625E-09 -9.5433 0.46119E-03 -3.3361 119 HP2O7-3 0.42838E-06 -6.3682 0.10168E-13 -13.9928 0.23736E-07 -7.6246 121 PbCl+ 0.12175E-05 -5.9145 0.16078E-06 -6.7938 0.13206E+00 -0.8792 122 PbCl2,aq 0.78830E-04 -4.1033 0.78830E-04 -4.1033 0.10000E+01 0.0000 123 PbCl3- 0.10892E-03 -3.9629 0.12610E-04 -4.8993 0.11577E+00 -0.9364 124 PbCl4-2 0.34256E-04 -4.4653 0.15798E-07 -7.8014 0.46119E-03 -3.3361 125 PbO,aq 0.59573E-08 -8.2250 0.59573E-08 -8.2250 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10533E-03 -3.9774 0.10533E-03 -3.9774 0.10000E+01 0.0000 128 Pb(HS)3- 0.13845E-04 -4.8587 0.16028E-05 -5.7951 0.11577E+00 -0.9364 129 H2S,aq 0.10589E+01 0.0249 0.12426E+01 0.0943 0.11735E+01 0.0695 130 S2-2 0.27142E-07 -7.5664 0.12518E-10 -10.9025 0.46119E-03 -3.3361 131 S3-2 0.24861E-08 -8.6045 0.11466E-11 -11.9406 0.46119E-03 -3.3361 132 S3- 0.85192E-02 -2.0696 0.98626E-03 -3.0060 0.11577E+00 -0.9364 133 S4-2 0.19560E-09 -9.7086 0.90211E-13 -13.0447 0.46119E-03 -3.3361 134 S5-2 0.13530E-10 -10.8687 0.62397E-14 -14.2048 0.46119E-03 -3.3361 135 SO2,aq 0.29352E+00 -0.5324 0.29352E+00 -0.5324 0.10000E+01 0.0000 136 SO3-2 0.15715E-08 -8.8037 0.12980E-11 -11.8867 0.82595E-03 -3.0830 137 HSO3- 0.23444E-03 -3.6300 0.27140E-04 -4.5664 0.11577E+00 -0.9364 138 HSO4- 0.86077E-02 -2.0651 0.11770E-02 -2.9292 0.13674E+00 -0.8641 140 S2O3-2 0.13235E-05 -5.8783 0.61038E-09 -9.2144 0.46119E-03 -3.3361 141 HS2O3- 0.37146E-06 -6.4301 0.43003E-07 -7.3665 0.11577E+00 -0.9364 142 H2S2O3,aq 0.44190E-07 -7.3547 0.44190E-07 -7.3547 0.10000E+01 0.0000 150 S4O6-2 0.10416E-08 -8.9823 0.48038E-12 -12.3184 0.46119E-03 -3.3361 152 ZnCl+ 0.13745E-03 -3.8618 0.18152E-04 -4.7411 0.13206E+00 -0.8792 153 ZnCl2,aq 0.51187E-03 -3.2908 0.51187E-03 -3.2908 0.10000E+01 0.0000 154 ZnCl3- 0.34884E-04 -4.4574 0.40384E-05 -5.3938 0.11577E+00 -0.9364 155 ZnO,aq 0.22944E-07 -7.6393 0.22944E-07 -7.6393 0.10000E+01 0.0000 156 ZnOH+ 0.97007E-06 -6.0132 0.12811E-06 -6.8924 0.13206E+00 -0.8792 158 HZnO2- 0.19069E-09 -9.7197 0.22076E-10 -10.6561 0.11577E+00 -0.9364 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5326524E-05 0.4293443E+01 0.3544165E+04 0.0000 2 H2O 0.1000000E+01 0.5252400E+02 0.7749484E+06 0.0000 3 Cl- 0.1388420E+00 0.6557526E+00 0.1903998E+05 4.3229 4 SO4-- 0.7214795E-03 0.2512771E+00 0.1976862E+05 5.7978 5 HCO3- 0.7836147E-05 0.2673612E+01 0.1336054E+06 0.1143 6 HS- 0.1276537E-03 0.1154123E+01 0.3125980E+05 1.2908 7 H4SiO4 0.3877199E-01 0.3877516E-01 0.3052250E+04 -1.4115 8 Al+++ 0.1445071E-14 0.1344234E-04 0.2970397E+00 -4.0477 9 Ca++ 0.4453434E-05 0.1474765E-03 0.4840634E+01 3.4663 10 Mg++ 0.5015521E-05 0.2081287E-04 0.4144062E+00 3.4122 11 Fe++ 0.5363233E-07 0.1968863E-02 0.9005107E+02 1.4680 12 K+ 0.3829487E-01 0.1255507E+00 0.4020606E+04 3.8159 13 Na+ 0.1238885E+00 0.5582532E+00 0.1051090E+05 4.2789 14 Mn++ 0.4907265E-05 0.1157073E-02 0.5206036E+02 3.4490 15 Zn++ 0.1460014E-08 0.6852017E-03 0.3668347E+02 -0.0970 16 Cu+ 0.1351853E-07 0.1019128E-03 0.5303342E+01 -2.6847 17 Pb++ 0.8331548E-08 0.3424138E-03 0.5810233E+02 0.8002 18 Ag+ 0.1055640E-09 0.8758165E-05 0.7737262E+00 -4.7522 19 Ba++ 0.1745068E-06 0.7584502E-05 0.8530954E+00 2.1605 20 HPO4-- 0.4888066E-08 0.5983742E-05 0.4703515E+00 0.6314 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265342E+01 -.2979821E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5218022E+02 -.2154442E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2496325E+00 0.2090263E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1146569E+01 0.1357477E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3852137E-01 0.1050729E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1335436E-04 0.6811852E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1465112E-03 0.3813987E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1955977E-02 0.6810777E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247289E+00 0.6811852E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.6807170E-03 0.1618618E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1012458E-03 0.2983639E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7534860E-05 0.4783759E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.5944578E-05 0.2622923E-05 0.0000000E+00 Chg. balance for solid moles: 0.1664E-17 Mass of aqueous solution: 0.121304E+04 g Temperature = 547.00 C Pressure = 912.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3770E-03 -3.424 0.5133E-01 -1.290 0.6902 0.1732E-01 apatite-OH 0.8743E-06 -6.058 0.4392E-03 -3.357 0.5906E-02 0.1396E-03 microcline 0.6812E-03 -3.167 0.1896 -0.722 2.550 0.7406E-01 pyrite 0.6512E-02 -2.186 0.7814 -0.107 10.51 0.1559 quartz 0.1030 -0.987 6.190 0.792 83.24 2.338 barite 0.4784E-04 -4.320 0.1117E-01 -1.952 0.1501 0.2492E-02 chalcopyrite 0.2984E-03 -3.525 0.5475E-01 -1.262 0.7362 0.1278E-01 sphalerite 0.1619E-02 -2.791 0.1577 -0.802 2.121 0.3857E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.436351 g Volume = 2.638879 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.20 -15.20 0.00 0.000 0.00000E+00 27 apatite-OH -54.18 -54.18 0.00 0.000 0.00000E+00 112 microcline -4.46 -4.46 -0.00 -0.000 0.16666E-10 137 pyrite -22.35 -22.35 0.00 0.000 -0.13333E-10 141 quartz -1.41 -1.41 0.00 0.000 0.00000E+00 234 barite -16.51 -16.51 0.00 0.000 0.00000E+00 237 chalcopyrite -24.07 -24.07 -0.00 -0.000 0.13333E-10 252 sphalerite -11.04 -11.04 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.253 0.95055E+03 2.707 2 CO2,gas -10.37 -12.12 -1.75 -0.584 0.65713E+04 1.209 3 CH4,gas 6.78 -4.39 -11.17 -2.793 0.41933E+05 -8.214 4 H2,gas 6.04 1.93 -4.11 -2.347 0.15412E+05 -1.147 5 H2S,gas -8.63 -10.94 -2.31 -1.155 0.86659E+04 0.651 6 CO,gas -4.02 -10.19 -6.17 -1.899 0.23157E+05 -3.210 7 SO3,gas -7.85 -18.67 -10.82 -2.704 0.40587E+05 -7.855 8 O2,gas 17.16 -3.86 -21.03 -14.017 0.78908E+05 -18.066 9 HCl,gas -6.28 -7.91 -1.63 -0.817 0.61290E+04 -1.633 10 acmite 3.63 1.96 -1.67 -0.174 0.62759E+04 12 akimotoite 6.50 2.00 -4.50 -0.900 0.16890E+05 13 akimotoite-Fe 4.31 0.06 -4.25 -0.851 0.15967E+05 14 albite-high -3.82 -4.00 -0.17 -0.013 0.65231E+03 15 albite -3.84 -4.00 -0.16 -0.013 0.61118E+03 16 almandine -5.54 -7.93 -2.39 -0.119 0.89675E+04 17 pyrope 1.41 -2.09 -3.51 -0.175 0.13159E+05 18 analcite -1.57 -2.59 -1.02 -0.113 0.38235E+04 19 andalusite -8.91 -9.51 -0.60 -0.060 0.22350E+04 24 anorthite -6.50 -7.45 -0.96 -0.074 0.35862E+04 25 anthophyllite 16.27 12.60 -3.67 -0.099 0.13757E+05 26 anthophyllite-Fe 2.99 -1.01 -4.00 -0.108 0.15003E+05 28 apatite-OH-zs -51.94 -54.18 -2.23 -0.172 0.83845E+04 29 apatite-Cl-zs -58.79 -62.09 -3.29 -0.275 0.12365E+05 30 aragonite -4.81 -8.65 -3.85 -1.282 0.14430E+05 31 brucite 5.89 3.41 -2.48 -0.496 0.93111E+04 32 calcite -4.92 -8.65 -3.73 -1.245 0.14014E+05 33 carnegieite-low 0.66 -1.18 -1.84 -0.262 0.68935E+04 34 carnegieite-high 0.75 -1.18 -1.93 -0.276 0.72448E+04 35 carpholite-Mg -5.24 -7.51 -2.26 -0.151 0.84979E+04 36 carpholite-Fe -6.67 -9.45 -2.78 -0.186 0.10444E+05 37 celadonite -0.14 -2.46 -2.32 -0.136 0.87057E+04 38 celadonite-Fe -1.61 -4.40 -2.80 -0.165 0.10500E+05 39 chrysotile 10.40 7.41 -2.99 -0.249 0.11219E+05 41 clinochlore 7.07 4.72 -2.34 -0.073 0.87949E+04 42 daphnite -0.36 -5.00 -4.64 -0.145 0.17414E+05 45 chloritoid-Mg -4.50 -6.10 -1.60 -0.106 0.59914E+04 46 chloritoid-Fe -6.55 -8.04 -1.49 -0.100 0.56085E+04 47 chloritoid-Mn -4.41 -6.06 -1.65 -0.110 0.61836E+04 49 coesite -1.11 -1.41 -0.30 -0.100 0.11216E+04 50 cordierite-H -14.95 -16.42 -1.47 -0.053 0.55320E+04 51 cordierite-Fe -17.71 -20.31 -2.60 -0.090 0.97727E+04 52 cordierite-Mn -13.37 -16.35 -2.98 -0.103 0.11167E+05 53 corundum -7.32 -8.10 -0.78 -0.071 0.29244E+04 55 cristobalite -1.36 -1.41 -0.05 -0.016 0.18037E+03 56 cummingtonite 16.34 12.60 -3.74 -0.101 0.14029E+05 58 cymrite-K -2.09 -4.46 -2.38 -0.198 0.89165E+04 60 diaspore -3.18 -4.05 -0.87 -0.145 0.32636E+04 62 diopside 5.79 4.06 -1.73 -0.173 0.64981E+04 63 hedenbergite 4.29 2.11 -2.18 -0.218 0.81845E+04 65 eastonite -2.52 -4.33 -1.81 -0.070 0.67883E+04 66 enstatite 5.31 4.00 -1.31 -0.131 0.49030E+04 67 clinoenstatite-HiP 5.82 4.00 -1.82 -0.182 0.68121E+04 68 clinoenstatite 5.29 4.00 -1.29 -0.129 0.48266E+04 69 protoenstatite 5.45 4.00 -1.44 -0.144 0.54181E+04 70 epidote -2.14 -4.90 -2.76 -0.134 0.10346E+05 71 clinozoisite -6.34 -9.45 -3.10 -0.141 0.11652E+05 72 epidote-Fe 3.78 -0.35 -4.12 -0.214 0.15474E+05 73 fayalite 2.87 1.52 -1.34 -0.192 0.50339E+04 74 ferrosilite 1.56 0.12 -1.44 -0.144 0.54150E+04 75 forsterite 7.04 5.41 -1.63 -0.232 0.61054E+04 76 gedrite -4.28 -7.60 -3.32 -0.090 0.12466E+05 78 gibbsite -1.54 -4.05 -2.51 -0.358 0.94113E+04 79 glaucophane 3.13 -0.58 -3.71 -0.100 0.13916E+05 81 goethite 1.47 0.50 -0.97 -0.210 0.36522E+04 83 greenalite 5.28 1.58 -3.70 -0.308 0.13882E+05 84 grunerite 3.57 -1.01 -4.58 -0.124 0.17187E+05 85 halite -1.57 -3.63 -2.06 -1.030 0.77282E+04 86 hematite 1.40 1.00 -0.39 -0.048 0.14814E+04 87 heulandite -11.15 -14.50 -3.36 -0.153 0.12592E+05 88 hercynite -5.21 -6.63 -1.43 -0.095 0.53550E+04 91 jadeite -0.89 -2.59 -1.70 -0.170 0.63863E+04 93 kalsilite 0.03 -1.64 -1.67 -0.239 0.62748E+04 94 kaolinite -8.16 -10.92 -2.76 -0.251 0.10344E+05 95 kyanite -8.75 -9.51 -0.76 -0.076 0.28616E+04 97 laumontite -6.46 -10.28 -3.81 -0.254 0.14308E+05 98 lawsonite -3.75 -7.45 -3.71 -0.247 0.13911E+05 99 leucite -2.05 -3.05 -1.00 -0.100 0.37676E+04 101 lizardite 10.56 7.41 -3.14 -0.262 0.11799E+05 102 magnesite -5.52 -8.71 -3.19 -1.063 0.11973E+05 103 magnetite 2.98 2.47 -0.51 -0.042 0.19080E+04 104 minnesotaite 1.21 -1.24 -2.44 -0.144 0.91651E+04 105 minnesotaite-Mg 7.44 4.60 -2.85 -0.167 0.10686E+05 106 magnesioferrite 6.17 4.41 -1.75 -0.143 0.65829E+04 108 manganosite 5.78 3.45 -2.33 -0.584 0.87611E+04 109 margarite -13.39 -15.55 -2.16 -0.087 0.81159E+04 113 monticellite 9.40 5.47 -3.94 -0.562 0.14776E+05 115 mullite-Si -8.13 -9.51 -1.38 -0.138 0.51603E+04 116 muscovite -11.67 -12.56 -0.89 -0.052 0.33317E+04 117 paragonite -10.98 -12.10 -1.12 -0.066 0.41930E+04 118 nepheline 0.35 -1.18 -1.53 -0.218 0.57383E+04 119 osumilite(2) -10.86 -13.60 -2.74 -0.057 0.10289E+05 120 osumilite-Fe -24.55 -27.59 -3.04 -0.063 0.11409E+05 122 periclase 6.12 3.41 -2.71 -0.677 0.10170E+05 123 periclase-Fe 3.45 1.47 -1.98 -0.495 0.74313E+04 124 perovskite-Al -5.54 -8.10 -2.55 -0.232 0.95875E+04 129 phlogopite-Na 7.73 6.23 -1.50 -0.083 0.56314E+04 131 prehnite -1.70 -5.40 -3.70 -0.218 0.13878E+05 132 prehnite-Fe 2.90 -0.85 -3.75 -0.226 0.14077E+05 135 px-Mg-tschermaks -3.82 -6.10 -2.28 -0.163 0.85549E+04 136 px-Ca-tschermaks -3.15 -6.04 -2.89 -0.206 0.10839E+05 138 pyrrhotite -8.70 -9.47 -0.77 -0.257 0.28959E+04 139 pyrrhotiteFe0.875 -9.54 -9.90 -0.36 -0.133 0.13606E+04 140 pyrophyllite -12.29 -13.74 -1.44 -0.090 0.54151E+04 143 riebeckite 6.16 2.69 -3.48 -0.096 0.13053E+05 144 ringwoodite-Fe 3.88 1.52 -2.35 -0.336 0.88213E+04 145 ringwoodite-Mg 10.26 5.41 -4.85 -0.693 0.18203E+05 146 rhodochrosite -5.59 -8.67 -3.08 -1.027 0.11560E+05 147 rhodonite 2.71 2.04 -0.67 -0.134 0.25223E+04 148 sanidine -3.91 -4.46 -0.55 -0.042 0.20676E+04 150 siderite -7.44 -10.65 -3.21 -1.069 0.12036E+05 151 sillimanite -8.87 -9.51 -0.64 -0.064 0.23936E+04 153 spinel -2.95 -4.69 -1.74 -0.116 0.65331E+04 160 stilpnomelane-Mg 2.72 -0.42 -3.13 -0.094 0.11756E+05 161 stishovite 1.61 -1.41 -3.02 -1.007 0.11335E+05 162 sudoite-Fe -12.72 -17.50 -4.77 -0.154 0.17911E+05 163 sudoite -10.37 -13.61 -3.23 -0.104 0.12137E+05 164 sulfur -11.39 -12.87 -1.48 -0.455 0.55493E+04 165 sylvite -1.48 -4.09 -2.62 -1.309 0.98221E+04 166 talc 5.68 4.60 -1.08 -0.064 0.40608E+04 167 talc-Fe 2.65 -1.24 -3.89 -0.229 0.14581E+05 168 talc-tschermaks -3.37 -5.51 -2.13 -0.126 0.80096E+04 170 tephroite 7.10 5.49 -1.61 -0.230 0.60380E+04 173 topaz-H -6.82 -9.51 -2.69 -0.244 0.10079E+05 174 tremolite 16.60 12.71 -3.89 -0.105 0.14607E+05 176 troilite-low -8.62 -9.47 -0.86 -0.287 0.32264E+04 177 tschermakite -3.16 -7.49 -4.33 -0.117 0.16269E+05 180 wadsleyite-Fe 3.73 1.52 -2.21 -0.316 0.82942E+04 181 wadsleyite-Mg 9.31 5.41 -3.89 -0.556 0.14610E+05 182 wairakite -8.34 -10.27 -1.93 -0.113 0.72336E+04 183 walstromite 4.76 2.06 -2.71 -0.541 0.10159E+05 184 wollastonite 4.33 2.06 -2.27 -0.454 0.85252E+04 185 pseudo-wollastonite 4.45 2.06 -2.39 -0.479 0.89871E+04 186 zoisite -6.39 -9.45 -3.06 -0.139 0.11475E+05 189 beidellite-Ca -12.21 -14.04 -1.82 -0.113 0.68454E+04 190 beidellite-H -12.27 -14.61 -2.34 -0.149 0.87679E+04 191 beidellite-K -11.23 -13.35 -2.12 -0.130 0.79393E+04 192 beidellite-Mg -12.44 -14.04 -1.60 -0.099 0.60157E+04 193 beidellite-Na -11.18 -13.20 -2.02 -0.124 0.75833E+04 194 bornite -56.50 -56.69 -0.19 -0.015 0.72866E+03 196 chalcocite -14.89 -16.31 -1.42 -0.356 0.53384E+04 197 covellite -13.28 -14.59 -1.32 -0.501 0.49366E+04 199 montmorillonite-Ca -9.28 -10.70 -1.42 -0.088 0.53458E+04 200 montmorillonite-K -8.57 -10.02 -1.44 -0.088 0.54154E+04 201 montmorillonite-Mg -9.47 -10.71 -1.24 -0.076 0.46409E+04 202 montmorillonite-Na -8.25 -9.86 -1.62 -0.099 0.60618E+04 203 nontronite-Ca -3.22 -4.93 -1.71 -0.111 0.64338E+04 204 nontronite-H -3.29 -5.51 -2.22 -0.149 0.83285E+04 205 nontronite-K -2.24 -4.25 -2.00 -0.129 0.75216E+04 206 nontronite-Mg -3.42 -4.94 -1.52 -0.099 0.57183E+04 207 nontronite-Na -2.18 -4.09 -1.91 -0.123 0.71775E+04 212 gypsum -12.93 -15.21 -2.28 -0.569 0.85484E+04 229 alabandite -6.43 -7.49 -1.06 -0.354 0.39847E+04 231 anglesite -15.57 -17.87 -2.30 -1.151 0.86371E+04 235 boehmite -2.87 -4.05 -1.18 -0.196 0.44165E+04 239 copper,native 1.68 -1.72 -3.40 -1.184 0.12771E+05 241 ferrous-oxide 2.50 1.47 -1.04 -0.259 0.38931E+04 242 galena -10.14 -10.14 -0.00 -0.001 0.11831E+02 243 silver,native 0.36 -3.79 -4.15 -1.443 0.15571E+05 245 litharge 5.48 0.80 -4.69 -1.171 0.17583E+05 253 wurtzite -10.22 -11.04 -0.82 -0.274 0.30898E+04 254 zincite 2.56 -0.10 -2.66 -0.665 0.99867E+04 255 an20ab80 -4.58 -4.69 -0.10 -0.008 0.38972E+03 256 an25ab75 -4.74 -4.86 -0.12 -0.009 0.44018E+03 257 an30ab70 -4.90 -5.03 -0.14 -0.010 0.50906E+03 258 tr.625ac.25prg.125 11.45 9.22 -2.22 -0.060 0.83423E+04 Calculations done for 547.0000 Deg. C; 912.0000 bar Temperature changed by -1.000 degrees to 546.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 52 Loop limit = 500 Temperature = 546.00 C Pressure = 901.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9935E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9970 Stoichiometric ionic strength = .3270512E+01 Osmotic coef. = 0.0000 True ionic strength = .1664108E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.53786E-05 -5.2693 0.74265E-06 -6.1292 0.13807E+00 -0.8599 2 H2O 0.99699E+00 -0.0013 0.99699E+00 -0.0013 3 Cl- 0.14053E+00 -0.8522 0.15564E-01 -1.8079 0.11075E+00 -0.9557 4 SO4-- 0.81222E-03 -3.0903 0.35270E-06 -6.4526 0.43425E-03 -3.3623 5 HCO3- 0.77299E-05 -5.1118 0.94012E-06 -6.0268 0.12162E+00 -0.9150 6 HS- 0.12960E-03 -3.8874 0.14503E-04 -4.8385 0.11190E+00 -0.9512 7 H4SiO4 0.37980E-01 -1.4204 0.37980E-01 -1.4204 0.10000E+01 0.0000 8 Al+++ 0.22260E-14 -14.6525 0.42792E-22 -22.3686 0.19224E-07 -7.7162 9 Ca++ 0.51131E-05 -5.2913 0.16658E-08 -8.7784 0.32579E-03 -3.4871 10 Mg++ 0.55239E-05 -5.2578 0.14032E-08 -8.8529 0.25402E-03 -3.5951 11 Fe++ 0.62859E-07 -7.2016 0.17004E-10 -10.7695 0.27051E-03 -3.5678 12 K+ 0.38650E-01 -1.4128 0.48421E-02 -2.3150 0.12528E+00 -0.9021 13 Na+ 0.12544E+00 -0.9016 0.14071E-01 -1.8517 0.11217E+00 -0.9501 14 Mn++ 0.57130E-05 -5.2431 0.16182E-08 -8.7910 0.28325E-03 -3.5478 15 Zn++ 0.17132E-08 -8.7662 0.46344E-12 -12.3340 0.27051E-03 -3.5678 16 Cu+ 0.13583E-07 -7.8670 0.15185E-08 -8.8186 0.11180E+00 -0.9516 17 Pb++ 0.93636E-08 -8.0286 0.35285E-11 -11.4524 0.37684E-03 -3.4238 18 Ag+ 0.88979E-10 -10.0507 0.10925E-10 -10.9616 0.12279E+00 -0.9109 19 Ba++ 0.19489E-06 -6.7102 0.80549E-10 -10.0939 0.41331E-03 -3.3837 20 HPO4-- 0.55701E-08 -8.2541 0.24345E-11 -11.6136 0.43706E-03 -3.3595 21 HSiO3- 0.14194E-05 -5.8479 0.15720E-06 -6.8036 0.11075E+00 -0.9557 22 Ca(HSiO3)+ 0.45718E-08 -8.3399 0.57923E-09 -9.2372 0.12670E+00 -0.8972 23 Mg(HSiO3)+ 0.13686E-08 -8.8637 0.17340E-09 -9.7610 0.12670E+00 -0.8972 24 NaHSiO3,aq 0.17577E-05 -5.7551 0.17577E-05 -5.7551 0.10000E+01 0.0000 28 AgCl,aq 0.32422E-07 -7.4892 0.32422E-07 -7.4892 0.10000E+01 0.0000 29 AgCl2- 0.16039E-05 -5.7948 0.17764E-06 -6.7505 0.11075E+00 -0.9557 30 AgCl3-2 0.10774E-05 -5.9676 0.42373E-09 -9.3729 0.39327E-03 -3.4053 31 AgCl4-3 0.60413E-05 -5.2189 0.99353E-13 -13.0028 0.16446E-07 -7.7840 34 Ag(HS),aq 0.64698E-09 -9.1891 0.64698E-09 -9.1891 0.10000E+01 0.0000 35 Ag(HS)2- 0.21059E-08 -8.6766 0.23323E-09 -9.6322 0.11075E+00 -0.9557 36 AlO+ 0.23089E-10 -10.6366 0.29252E-11 -11.5338 0.12670E+00 -0.8972 38 HAlO2,aq 0.50065E-08 -8.3005 0.50065E-08 -8.3005 0.10000E+01 0.0000 39 AlO2- 0.13795E-04 -4.8603 0.12981E-05 -5.8867 0.94102E-01 -1.0264 41 Ba(HCO3)+ 0.15821E-06 -6.8008 0.21093E-07 -7.6759 0.13333E+00 -0.8751 42 BaCl+ 0.72039E-05 -5.1424 0.91271E-06 -6.0397 0.12670E+00 -0.8972 43 CH4,aq 0.12507E-08 -8.9028 0.14658E-08 -8.8339 0.11720E+01 0.0689 48 CO,aq 0.39481E-03 -3.4036 0.39481E-03 -3.4036 0.10000E+01 0.0000 49 CO2,aq 0.26731E+01 0.4270 0.31328E+01 0.4959 0.11720E+01 0.0689 50 CO3-2 0.10145E-09 -9.9937 0.39897E-13 -13.3991 0.39327E-03 -3.4053 52 Ca(HCO3)+ 0.74178E-07 -7.1297 0.93980E-08 -8.0270 0.12670E+00 -0.8972 53 CaCl+ 0.76420E-04 -4.1168 0.96821E-05 -5.0140 0.12670E+00 -0.8972 54 CaCl2,aq 0.66034E-04 -4.1802 0.66034E-04 -4.1802 0.10000E+01 0.0000 55 CaOH+ 0.13557E-06 -6.8678 0.17176E-07 -7.7651 0.12670E+00 -0.8972 56 CaSO4,aq 0.20227E-06 -6.6941 0.20227E-06 -6.6941 0.10000E+01 0.0000 57 HCl,aq 0.55743E-02 -2.2538 0.55743E-02 -2.2538 0.10000E+01 0.0000 66 CuCl,aq 0.19639E-04 -4.7069 0.19639E-04 -4.7069 0.10000E+01 0.0000 67 CuCl2- 0.79981E-04 -4.0970 0.88579E-05 -5.0527 0.11075E+00 -0.9557 68 CuCl3-2 0.30027E-05 -5.5225 0.11809E-08 -8.9278 0.39327E-03 -3.4053 74 FeCl+ 0.28134E-06 -6.5508 0.35645E-07 -7.4480 0.12670E+00 -0.8972 75 FeCl2,aq 0.19132E-02 -2.7182 0.19132E-02 -2.7182 0.10000E+01 0.0000 77 FeO,aq 0.42064E-07 -7.3761 0.42064E-07 -7.3761 0.10000E+01 0.0000 78 FeOH+ 0.22177E-07 -7.6541 0.28097E-08 -8.5513 0.12670E+00 -0.8972 79 HFeO2- 0.54647E-08 -8.2624 0.60522E-09 -9.2181 0.11075E+00 -0.9557 82 FeO2- 0.32041E-08 -8.4943 0.35486E-09 -9.4499 0.11075E+00 -0.9557 83 HFeO2,aq 0.26752E-09 -9.5726 0.26752E-09 -9.5726 0.10000E+01 0.0000 84 H2,aq 0.41323E-02 -2.3838 0.48429E-02 -2.3149 0.11720E+01 0.0689 85 KCl,aq 0.69533E-01 -1.1578 0.69533E-01 -1.1578 0.10000E+01 0.0000 86 KHSO4,aq 0.11818E-01 -1.9274 0.11818E-01 -1.9274 0.10000E+01 0.0000 87 KOH,aq 0.12651E-05 -5.8979 0.12651E-05 -5.8979 0.10000E+01 0.0000 88 KSO4- 0.55449E-02 -2.2561 0.61410E-03 -3.2118 0.11075E+00 -0.9557 90 Mg(HCO3)+ 0.19124E-07 -7.7184 0.24229E-08 -8.6157 0.12670E+00 -0.8972 91 MgCl+ 0.14761E-04 -4.8309 0.18702E-05 -5.7281 0.12670E+00 -0.8972 92 MgOH+ 0.50693E-06 -6.2951 0.64226E-07 -7.1923 0.12670E+00 -0.8972 94 MnO,aq 0.72977E-07 -7.1368 0.72977E-07 -7.1368 0.10000E+01 0.0000 95 MnOH+ 0.21726E-06 -6.6630 0.27526E-07 -7.5603 0.12670E+00 -0.8972 97 HMnO2- 0.34470E-10 -10.4626 0.38176E-11 -11.4182 0.11075E+00 -0.9557 100 MnCl+ 0.11508E-02 -2.9390 0.14581E-03 -3.8362 0.12670E+00 -0.8972 101 MnSO4,aq 0.19500E-06 -6.7100 0.19500E-06 -6.7100 0.10000E+01 0.0000 102 NaCl,aq 0.43279E+00 -0.3637 0.43279E+00 -0.3637 0.10000E+01 0.0000 103 NaOH,aq 0.16608E-05 -5.7797 0.16608E-05 -5.7797 0.10000E+01 0.0000 105 OH- 0.85698E-05 -5.0670 0.80643E-06 -6.0934 0.94102E-01 -1.0264 110 HPO3-2 0.24771E-10 -10.6061 0.97416E-14 -14.0114 0.39327E-03 -3.4053 111 H3PO3,aq 0.13613E-09 -9.8660 0.13613E-09 -9.8660 0.10000E+01 0.0000 112 H2PO3- 0.17083E-08 -8.7674 0.18920E-09 -9.7231 0.11075E+00 -0.9557 113 H3PO4,aq 0.21170E-05 -5.6743 0.21170E-05 -5.6743 0.10000E+01 0.0000 114 H2PO4- 0.18458E-05 -5.7338 0.21769E-06 -6.6622 0.11794E+00 -0.9284 116 H4P2O7,aq 0.42822E-09 -9.3683 0.42822E-09 -9.3683 0.10000E+01 0.0000 117 H3P2O7- 0.14164E-08 -8.8488 0.15687E-09 -9.8045 0.11075E+00 -0.9557 118 H2P2O7-2 0.68239E-06 -6.1660 0.26837E-09 -9.5713 0.39327E-03 -3.4053 119 HP2O7-3 0.57553E-06 -6.2399 0.94649E-14 -14.0239 0.16446E-07 -7.7840 120 P2O7-4 0.14572E-10 -10.8365 0.92039E-24 -24.0360 0.63163E-13 -13.1995 121 PbCl+ 0.12133E-05 -5.9160 0.15372E-06 -6.8133 0.12670E+00 -0.8972 122 PbCl2,aq 0.77646E-04 -4.1099 0.77646E-04 -4.1099 0.10000E+01 0.0000 123 PbCl3- 0.10960E-03 -3.9602 0.12138E-04 -4.9158 0.11075E+00 -0.9557 124 PbCl4-2 0.36776E-04 -4.4344 0.14463E-07 -7.8397 0.39327E-03 -3.4053 125 PbO,aq 0.59171E-08 -8.2279 0.59171E-08 -8.2279 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10326E-03 -3.9861 0.10326E-03 -3.9861 0.10000E+01 0.0000 128 Pb(HS)3- 0.13895E-04 -4.8572 0.15388E-05 -5.8128 0.11075E+00 -0.9557 129 H2S,aq 0.10591E+01 0.0249 0.12412E+01 0.0938 0.11720E+01 0.0689 130 S2-2 0.29788E-07 -7.5260 0.11715E-10 -10.9313 0.39327E-03 -3.4053 131 S3-2 0.27081E-08 -8.5673 0.10650E-11 -11.9726 0.39327E-03 -3.4053 132 S3- 0.84134E-02 -2.0750 0.93179E-03 -3.0307 0.11075E+00 -0.9557 133 S4-2 0.21183E-09 -9.6740 0.83306E-13 -13.0793 0.39327E-03 -3.4053 134 S5-2 0.14584E-10 -10.8361 0.57354E-14 -14.2414 0.39327E-03 -3.4053 135 SO2,aq 0.29349E+00 -0.5324 0.29349E+00 -0.5324 0.10000E+01 0.0000 136 SO3-2 0.17421E-08 -8.7589 0.12433E-11 -11.9054 0.71365E-03 -3.1465 137 HSO3- 0.23459E-03 -3.6297 0.25981E-04 -4.5853 0.11075E+00 -0.9557 138 HSO4- 0.86624E-02 -2.0624 0.11373E-02 -2.9441 0.13130E+00 -0.8817 140 S2O3-2 0.14664E-05 -5.8337 0.57670E-09 -9.2391 0.39327E-03 -3.4053 141 HS2O3- 0.37121E-06 -6.4304 0.41111E-07 -7.3860 0.11075E+00 -0.9557 142 H2S2O3,aq 0.44939E-07 -7.3474 0.44939E-07 -7.3474 0.10000E+01 0.0000 150 S4O6-2 0.11308E-08 -8.9466 0.44471E-12 -12.3519 0.39327E-03 -3.4053 152 ZnCl+ 0.13686E-03 -3.8637 0.17340E-04 -4.7610 0.12670E+00 -0.8972 153 ZnCl2,aq 0.50291E-03 -3.2985 0.50291E-03 -3.2985 0.10000E+01 0.0000 154 ZnCl3- 0.34286E-04 -4.4649 0.37972E-05 -5.4205 0.11075E+00 -0.9557 155 ZnO,aq 0.22709E-07 -7.6438 0.22709E-07 -7.6438 0.10000E+01 0.0000 156 ZnOH+ 0.97299E-06 -6.0119 0.12327E-06 -6.9091 0.12670E+00 -0.8972 158 HZnO2- 0.19379E-09 -9.7127 0.21462E-10 -10.6683 0.11075E+00 -0.9557 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5378635E-05 0.4293332E+01 0.3544319E+04 0.0000 2 H2O 0.1000000E+01 0.5252436E+02 0.7750075E+06 0.0000 3 Cl- 0.1405294E+00 0.6557367E+00 0.1904084E+05 4.3213 4 SO4-- 0.8122176E-03 0.2512568E+00 0.1976839E+05 5.8058 5 HCO3- 0.7729942E-05 0.2673547E+01 0.1336115E+06 0.1024 6 HS- 0.1296010E-03 0.1153988E+01 0.3125832E+05 1.2907 7 H4SiO4 0.3797975E-01 0.3798293E-01 0.2990096E+04 -1.4204 8 Al+++ 0.2226008E-14 0.1379964E-04 0.3049563E+00 -3.9810 9 Ca++ 0.5113109E-05 0.1479831E-03 0.4857602E+01 3.4801 10 Mg++ 0.5523927E-05 0.2081237E-04 0.4144249E+00 3.4056 11 Fe++ 0.6285892E-07 0.1913598E-02 0.8752944E+02 1.4890 12 K+ 0.3865043E-01 0.1255480E+00 0.4020799E+04 3.8143 13 Na+ 0.1254416E+00 0.5582396E+00 0.1051137E+05 4.2775 14 Mn++ 0.5713024E-05 0.1157045E-02 0.5206271E+02 3.4675 15 Zn++ 0.1713238E-08 0.6750576E-03 0.3614290E+02 -0.0756 16 Cu+ 0.1358274E-07 0.1026360E-03 0.5341344E+01 -2.6894 17 Pb++ 0.9363600E-08 0.3424054E-03 0.5810495E+02 0.8060 18 Ag+ 0.8897899E-10 0.8757952E-05 0.7737611E+00 -4.8323 19 Ba++ 0.1948886E-06 0.7557031E-05 0.8500645E+00 2.1645 20 HPO4-- 0.5570104E-08 0.6489794E-05 0.5101651E+00 0.6448 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265335E+01 -.2973265E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5218185E+02 -.2170726E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2496184E+00 0.2104426E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1146463E+01 0.1368074E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3773525E-01 0.1058591E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1370966E-04 0.6808299E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1470181E-03 0.3808917E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1901119E-02 0.6865634E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247293E+00 0.6808299E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.6706556E-03 0.1628679E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1019667E-03 0.2976430E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7507752E-05 0.4786470E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.6447474E-05 0.2120026E-05 0.0000000E+00 Chg. balance for solid moles: -.1919E-17 Mass of aqueous solution: 0.121298E+04 g Temperature = 546.00 C Pressure = 901.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3774E-03 -3.423 0.5137E-01 -1.289 0.6858 0.1734E-01 apatite-OH 0.7067E-06 -6.151 0.3550E-03 -3.450 0.4739E-02 0.1128E-03 microcline 0.6808E-03 -3.167 0.1895 -0.722 2.530 0.7402E-01 pyrite 0.6568E-02 -2.183 0.7880 -0.103 10.52 0.1572 quartz 0.1038 -0.984 6.237 0.795 83.26 2.355 barite 0.4786E-04 -4.320 0.1117E-01 -1.952 0.1491 0.2494E-02 chalcopyrite 0.2976E-03 -3.526 0.5462E-01 -1.263 0.7291 0.1275E-01 sphalerite 0.1629E-02 -2.788 0.1587 -0.799 2.118 0.3881E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.491030 g Volume = 2.658230 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.23 -15.23 0.00 0.000 0.00000E+00 27 apatite-OH -54.22 -54.22 0.00 0.000 0.00000E+00 112 microcline -4.42 -4.42 0.00 0.000 -0.19975E-10 137 pyrite -22.38 -22.38 0.00 0.000 -0.13317E-10 141 quartz -1.42 -1.42 -0.00 -0.000 0.83229E-12 234 barite -16.55 -16.55 0.00 0.000 0.00000E+00 237 chalcopyrite -24.10 -24.10 0.00 0.000 0.00000E+00 252 sphalerite -11.04 -11.04 0.00 0.000 -0.66583E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.252 0.94552E+03 2.702 2 CO2,gas -10.40 -12.15 -1.76 -0.586 0.65925E+04 1.196 3 CH4,gas 6.77 -4.41 -11.19 -2.797 0.41935E+05 -8.233 4 H2,gas 6.04 1.93 -4.11 -2.348 0.15402E+05 -1.154 5 H2S,gas -8.66 -10.97 -2.31 -1.155 0.86616E+04 0.644 6 CO,gas -4.04 -10.22 -6.18 -1.903 0.23179E+05 -3.229 7 SO3,gas -7.88 -18.71 -10.83 -2.707 0.40591E+05 -7.874 8 O2,gas 17.18 -3.87 -21.05 -14.035 0.78912E+05 -18.098 9 HCl,gas -6.29 -7.94 -1.64 -0.822 0.61612E+04 -1.644 10 acmite 3.64 1.96 -1.68 -0.174 0.62907E+04 12 akimotoite 6.53 1.99 -4.54 -0.909 0.17029E+05 13 akimotoite-Fe 4.33 0.07 -4.26 -0.853 0.15984E+05 14 albite-high -3.78 -3.96 -0.18 -0.014 0.65959E+03 15 albite -3.80 -3.96 -0.16 -0.013 0.61544E+03 16 almandine -5.35 -7.76 -2.41 -0.120 0.90221E+04 17 pyrope 1.62 -2.01 -3.62 -0.181 0.13583E+05 18 analcite -1.52 -2.54 -1.02 -0.113 0.38265E+04 19 andalusite -8.79 -9.38 -0.60 -0.060 0.22331E+04 24 anorthite -6.36 -7.32 -0.96 -0.074 0.36035E+04 25 anthophyllite 16.41 12.49 -3.93 -0.106 0.14722E+05 26 anthophyllite-Fe 3.10 -0.93 -4.03 -0.109 0.15108E+05 28 apatite-OH-zs -51.98 -54.22 -2.24 -0.172 0.83874E+04 29 apatite-Cl-zs -58.85 -62.15 -3.30 -0.275 0.12369E+05 30 aragonite -4.82 -8.68 -3.86 -1.286 0.14458E+05 31 brucite 5.92 3.40 -2.52 -0.504 0.94421E+04 32 calcite -4.93 -8.68 -3.75 -1.249 0.14041E+05 33 carnegieite-low 0.72 -1.12 -1.84 -0.263 0.68954E+04 34 carnegieite-high 0.81 -1.12 -1.93 -0.276 0.72503E+04 35 carpholite-Mg -5.10 -7.40 -2.30 -0.153 0.86186E+04 36 carpholite-Fe -6.53 -9.32 -2.79 -0.186 0.10443E+05 37 celadonite -0.08 -2.44 -2.36 -0.139 0.88371E+04 38 celadonite-Fe -1.55 -4.35 -2.80 -0.165 0.10511E+05 39 chrysotile 10.47 7.37 -3.10 -0.258 0.11616E+05 41 clinochlore 7.32 4.80 -2.52 -0.079 0.94464E+04 42 daphnite -0.13 -4.79 -4.66 -0.146 0.17458E+05 45 chloritoid-Mg -4.35 -5.98 -1.63 -0.109 0.61181E+04 46 chloritoid-Fe -6.40 -7.90 -1.50 -0.100 0.56101E+04 47 chloritoid-Mn -4.27 -5.92 -1.65 -0.110 0.61895E+04 49 coesite -1.12 -1.42 -0.30 -0.100 0.11233E+04 50 cordierite-H -14.66 -16.21 -1.55 -0.055 0.58119E+04 51 cordierite-Fe -17.43 -20.05 -2.62 -0.090 0.98039E+04 52 cordierite-Mn -13.10 -16.09 -2.99 -0.103 0.11204E+05 53 corundum -7.19 -7.97 -0.78 -0.071 0.29240E+04 55 cristobalite -1.37 -1.42 -0.05 -0.016 0.18011E+03 56 cummingtonite 16.49 12.49 -4.00 -0.108 0.14995E+05 58 cymrite-K -2.04 -4.42 -2.38 -0.198 0.89192E+04 60 diaspore -3.11 -3.98 -0.87 -0.145 0.32565E+04 62 diopside 5.82 4.05 -1.77 -0.177 0.66529E+04 63 hedenbergite 4.32 2.13 -2.19 -0.219 0.82168E+04 65 eastonite -2.28 -4.16 -1.88 -0.072 0.70576E+04 66 enstatite 5.36 3.97 -1.38 -0.138 0.51824E+04 67 clinoenstatite-HiP 5.86 3.97 -1.89 -0.189 0.70914E+04 68 clinoenstatite 5.33 3.97 -1.36 -0.136 0.51041E+04 69 protoenstatite 5.49 3.97 -1.52 -0.152 0.56974E+04 70 epidote -1.97 -4.74 -2.77 -0.134 0.10383E+05 71 clinozoisite -6.13 -9.25 -3.12 -0.142 0.11678E+05 72 epidote-Fe 3.90 -0.24 -4.14 -0.215 0.15521E+05 73 fayalite 2.91 1.56 -1.35 -0.193 0.50673E+04 74 ferrosilite 1.59 0.14 -1.45 -0.145 0.54491E+04 75 forsterite 7.09 5.39 -1.70 -0.243 0.63820E+04 76 gedrite -3.91 -7.42 -3.51 -0.095 0.13153E+05 78 gibbsite -1.48 -3.98 -2.51 -0.358 0.93980E+04 79 glaucophane 3.28 -0.54 -3.82 -0.103 0.14320E+05 81 goethite 1.50 0.52 -0.98 -0.211 0.36597E+04 83 greenalite 5.34 1.62 -3.71 -0.309 0.13911E+05 84 grunerite 3.68 -0.93 -4.61 -0.125 0.17294E+05 85 halite -1.60 -3.66 -2.06 -1.031 0.77290E+04 86 hematite 1.44 1.04 -0.40 -0.049 0.15027E+04 87 heulandite -11.06 -14.42 -3.36 -0.153 0.12603E+05 88 hercynite -5.05 -6.48 -1.43 -0.096 0.53713E+04 91 jadeite -0.84 -2.54 -1.70 -0.170 0.63877E+04 93 kalsilite 0.09 -1.59 -1.67 -0.239 0.62764E+04 94 kaolinite -8.05 -10.80 -2.75 -0.250 0.10319E+05 95 kyanite -8.62 -9.38 -0.76 -0.076 0.28603E+04 97 laumontite -6.35 -10.16 -3.82 -0.254 0.14307E+05 98 lawsonite -3.61 -7.33 -3.71 -0.247 0.13909E+05 99 leucite -2.00 -3.01 -1.01 -0.101 0.37723E+04 101 lizardite 10.63 7.37 -3.25 -0.271 0.12192E+05 102 magnesite -5.52 -8.75 -3.23 -1.078 0.12122E+05 103 magnetite 3.05 2.53 -0.52 -0.042 0.19466E+04 104 minnesotaite 1.25 -1.21 -2.46 -0.144 0.92023E+04 105 minnesotaite-Mg 7.50 4.54 -2.96 -0.174 0.11090E+05 106 magnesioferrite 6.24 4.44 -1.80 -0.147 0.67445E+04 108 manganosite 5.81 3.47 -2.34 -0.586 0.87800E+04 109 margarite -13.12 -15.29 -2.17 -0.087 0.81220E+04 113 monticellite 9.45 5.47 -3.98 -0.569 0.14928E+05 115 mullite-Si -8.01 -9.38 -1.38 -0.138 0.51621E+04 116 muscovite -11.50 -12.39 -0.89 -0.052 0.33242E+04 117 paragonite -10.81 -11.93 -1.12 -0.066 0.41879E+04 118 nepheline 0.41 -1.12 -1.53 -0.219 0.57398E+04 119 osumilite(2) -10.66 -13.52 -2.86 -0.060 0.10713E+05 120 osumilite-Fe -24.25 -27.30 -3.05 -0.064 0.11450E+05 122 periclase 6.15 3.40 -2.75 -0.688 0.10309E+05 123 periclase-Fe 3.47 1.49 -1.99 -0.497 0.74482E+04 124 perovskite-Al -5.41 -7.97 -2.56 -0.233 0.95873E+04 129 phlogopite-Na 7.86 6.25 -1.61 -0.090 0.60421E+04 131 prehnite -1.55 -5.26 -3.71 -0.218 0.13901E+05 132 prehnite-Fe 3.00 -0.76 -3.76 -0.226 0.14111E+05 135 px-Mg-tschermaks -3.66 -5.98 -2.32 -0.166 0.86961E+04 136 px-Ca-tschermaks -3.01 -5.90 -2.90 -0.207 0.10855E+05 138 pyrrhotite -8.70 -9.48 -0.78 -0.259 0.29088E+04 139 pyrrhotiteFe0.875 -9.54 -9.90 -0.37 -0.135 0.13714E+04 140 pyrophyllite -12.20 -13.64 -1.44 -0.090 0.54061E+04 143 riebeckite 6.21 2.71 -3.50 -0.097 0.13120E+05 144 ringwoodite-Fe 3.92 1.56 -2.36 -0.337 0.88514E+04 145 ringwoodite-Mg 10.32 5.39 -4.93 -0.704 0.18479E+05 146 rhodochrosite -5.60 -8.69 -3.09 -1.031 0.11589E+05 147 rhodonite 2.73 2.05 -0.68 -0.136 0.25427E+04 148 sanidine -3.87 -4.42 -0.55 -0.042 0.20682E+04 150 siderite -7.45 -10.67 -3.22 -1.073 0.12062E+05 151 sillimanite -8.75 -9.38 -0.64 -0.064 0.23934E+04 153 spinel -2.78 -4.56 -1.78 -0.119 0.66713E+04 160 stilpnomelane-Mg 2.93 -0.39 -3.31 -0.099 0.12424E+05 161 stishovite 1.61 -1.42 -3.02 -1.008 0.11334E+05 162 sudoite-Fe -12.43 -17.22 -4.78 -0.154 0.17930E+05 163 sudoite -10.07 -13.38 -3.31 -0.107 0.12399E+05 164 sulfur -11.42 -12.90 -1.48 -0.455 0.55454E+04 165 sylvite -1.50 -4.12 -2.62 -1.310 0.98213E+04 166 talc 5.73 4.54 -1.19 -0.070 0.44645E+04 167 talc-Fe 2.69 -1.21 -3.90 -0.229 0.14620E+05 168 talc-tschermaks -3.20 -5.41 -2.21 -0.130 0.82759E+04 170 tephroite 7.14 5.51 -1.62 -0.232 0.60755E+04 173 topaz-H -6.70 -9.39 -2.69 -0.244 0.10066E+05 174 tremolite 16.72 12.63 -4.09 -0.110 0.15322E+05 176 troilite-low -8.62 -9.48 -0.86 -0.288 0.32375E+04 177 tschermakite -2.81 -7.27 -4.46 -0.120 0.16702E+05 180 wadsleyite-Fe 3.78 1.56 -2.22 -0.317 0.83270E+04 181 wadsleyite-Mg 9.36 5.39 -3.97 -0.567 0.14886E+05 182 wairakite -8.23 -10.16 -1.93 -0.114 0.72395E+04 183 walstromite 4.78 2.06 -2.71 -0.543 0.10175E+05 184 wollastonite 4.34 2.06 -2.28 -0.456 0.85399E+04 185 pseudo-wollastonite 4.46 2.06 -2.40 -0.480 0.90027E+04 186 zoisite -6.18 -9.25 -3.07 -0.139 0.11502E+05 189 beidellite-Ca -12.09 -13.91 -1.82 -0.113 0.68379E+04 190 beidellite-H -12.15 -14.49 -2.34 -0.149 0.87569E+04 191 beidellite-K -11.11 -13.23 -2.12 -0.130 0.79302E+04 192 beidellite-Mg -12.31 -13.92 -1.61 -0.100 0.60298E+04 193 beidellite-Na -11.05 -13.07 -2.02 -0.124 0.75737E+04 194 bornite -56.61 -56.80 -0.19 -0.014 0.70530E+03 196 chalcocite -14.93 -16.35 -1.42 -0.355 0.53227E+04 197 covellite -13.31 -14.62 -1.31 -0.500 0.49228E+04 199 montmorillonite-Ca -9.19 -10.63 -1.44 -0.089 0.53853E+04 200 montmorillonite-K -8.49 -9.94 -1.46 -0.089 0.54561E+04 201 montmorillonite-Mg -9.38 -10.64 -1.25 -0.078 0.47010E+04 202 montmorillonite-Na -8.16 -9.79 -1.63 -0.100 0.60981E+04 203 nontronite-Ca -3.18 -4.91 -1.72 -0.112 0.64510E+04 204 nontronite-H -3.25 -5.48 -2.23 -0.149 0.83421E+04 205 nontronite-K -2.21 -4.22 -2.01 -0.129 0.75360E+04 206 nontronite-Mg -3.38 -4.92 -1.54 -0.100 0.57551E+04 207 nontronite-Na -2.15 -4.07 -1.92 -0.123 0.71920E+04 212 gypsum -12.95 -15.23 -2.28 -0.570 0.85434E+04 229 alabandite -6.43 -7.50 -1.07 -0.356 0.40025E+04 231 anglesite -15.60 -17.90 -2.30 -1.151 0.86293E+04 235 boehmite -2.81 -3.98 -1.18 -0.196 0.44118E+04 239 copper,native 1.68 -1.72 -3.40 -1.184 0.12761E+05 241 ferrous-oxide 2.53 1.49 -1.04 -0.261 0.39109E+04 242 galena -10.16 -10.16 -0.00 -0.001 0.14126E+02 243 silver,native 0.36 -3.87 -4.22 -1.469 0.15825E+05 245 litharge 5.50 0.80 -4.69 -1.173 0.17587E+05 253 wurtzite -10.22 -11.04 -0.82 -0.275 0.30905E+04 254 zincite 2.59 -0.08 -2.66 -0.666 0.99891E+04 255 an20ab80 -4.53 -4.63 -0.11 -0.008 0.39746E+03 256 an25ab75 -4.68 -4.80 -0.12 -0.009 0.44893E+03 257 an30ab70 -4.83 -4.97 -0.14 -0.011 0.51911E+03 258 tr.625ac.25prg.125 11.58 9.21 -2.37 -0.064 0.88992E+04 Calculations done for 546.0000 Deg. C; 901.0000 bar Temperature changed by -1.000 degrees to 545.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 54 Loop limit = 500 Temperature = 545.00 C Pressure = 890.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9935E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9970 Stoichiometric ionic strength = .3270181E+01 Osmotic coef. = 0.0000 True ionic strength = .1682957E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54155E-05 -5.2664 0.71905E-06 -6.1432 0.13278E+00 -0.8769 2 H2O 0.99700E+00 -0.0013 0.99700E+00 -0.0013 3 Cl- 0.14207E+00 -0.8475 0.15040E-01 -1.8228 0.10586E+00 -0.9753 4 SO4-- 0.91597E-03 -3.0381 0.33887E-06 -6.4700 0.36995E-03 -3.4319 5 HCO3- 0.76169E-05 -5.1182 0.88725E-06 -6.0520 0.11649E+00 -0.9337 6 HS- 0.13157E-03 -3.8808 0.14077E-04 -4.8515 0.10699E+00 -0.9707 7 H4SiO4 0.37188E-01 -1.4296 0.37188E-01 -1.4296 0.10000E+01 0.0000 8 Al+++ 0.34382E-14 -14.4637 0.45587E-22 -22.3412 0.13259E-07 -7.8775 9 Ca++ 0.58630E-05 -5.2319 0.16166E-08 -8.7914 0.27573E-03 -3.5595 10 Mg++ 0.60703E-05 -5.2168 0.12980E-08 -8.8867 0.21382E-03 -3.6699 11 Fe++ 0.73717E-07 -7.1324 0.16808E-10 -10.7745 0.22801E-03 -3.6420 12 K+ 0.38969E-01 -1.4093 0.46786E-02 -2.3299 0.12006E+00 -0.9206 13 Na+ 0.12689E+00 -0.8966 0.13608E-01 -1.8662 0.10724E+00 -0.9697 14 Mn++ 0.66653E-05 -5.1762 0.15929E-08 -8.7978 0.23899E-03 -3.6216 15 Zn++ 0.20099E-08 -8.6968 0.45828E-12 -12.3389 0.22801E-03 -3.6420 16 Cu+ 0.13608E-07 -7.8662 0.14543E-08 -8.8373 0.10687E+00 -0.9711 17 Pb++ 0.10514E-07 -7.9782 0.33640E-11 -11.4731 0.31995E-03 -3.4949 18 Ag+ 0.74082E-10 -10.1303 0.87133E-11 -11.0598 0.11762E+00 -0.9295 19 Ba++ 0.21724E-06 -6.6631 0.76388E-10 -10.1170 0.35164E-03 -3.4539 20 HPO4-- 0.63596E-08 -8.1966 0.23683E-11 -11.6256 0.37241E-03 -3.4290 21 HSiO3- 0.14379E-05 -5.8423 0.15222E-06 -6.8175 0.10586E+00 -0.9753 22 Ca(HSiO3)+ 0.46227E-08 -8.3351 0.56141E-09 -9.2507 0.12145E+00 -0.9156 23 Mg(HSiO3)+ 0.13318E-08 -8.8756 0.16174E-09 -9.7912 0.12145E+00 -0.9156 24 NaHSiO3,aq 0.17569E-05 -5.7553 0.17569E-05 -5.7553 0.10000E+01 0.0000 28 AgCl,aq 0.26742E-07 -7.5728 0.26742E-07 -7.5728 0.10000E+01 0.0000 29 AgCl2- 0.13345E-05 -5.8747 0.14127E-06 -6.8500 0.10586E+00 -0.9753 30 AgCl3-2 0.95983E-06 -6.0178 0.32089E-09 -9.4936 0.33432E-03 -3.4758 31 AgCl4-3 0.64343E-05 -5.1915 0.72802E-13 -13.1379 0.11315E-07 -7.9464 34 Ag(HS),aq 0.54218E-09 -9.2659 0.54218E-09 -9.2659 0.10000E+01 0.0000 35 Ag(HS)2- 0.17578E-08 -8.7550 0.18608E-09 -9.7303 0.10586E+00 -0.9753 36 AlO+ 0.24789E-10 -10.6057 0.30105E-11 -11.5214 0.12145E+00 -0.9156 38 HAlO2,aq 0.50618E-08 -8.2957 0.50618E-08 -8.2957 0.10000E+01 0.0000 39 AlO2- 0.14154E-04 -4.8491 0.12688E-05 -5.8966 0.89643E-01 -1.0475 41 Ba(HCO3)+ 0.15493E-06 -6.8099 0.19823E-07 -7.7028 0.12795E+00 -0.8930 42 BaCl+ 0.71369E-05 -5.1465 0.86675E-06 -6.0621 0.12145E+00 -0.9156 43 CH4,aq 0.12402E-08 -8.9065 0.14515E-08 -8.8382 0.11704E+01 0.0683 48 CO,aq 0.38835E-03 -3.4108 0.38835E-03 -3.4108 0.10000E+01 0.0000 49 CO2,aq 0.26731E+01 0.4270 0.31285E+01 0.4953 0.11704E+01 0.0683 50 CO3-2 0.11303E-09 -9.9468 0.37787E-13 -13.4227 0.33432E-03 -3.4758 52 Ca(HCO3)+ 0.72507E-07 -7.1396 0.88056E-08 -8.0552 0.12145E+00 -0.9156 53 CaCl+ 0.76858E-04 -4.1143 0.93340E-05 -5.0299 0.12145E+00 -0.9156 54 CaCl2,aq 0.65108E-04 -4.1864 0.65108E-04 -4.1864 0.10000E+01 0.0000 55 CaOH+ 0.13640E-06 -6.8652 0.16566E-07 -7.7808 0.12145E+00 -0.9156 56 CaSO4,aq 0.20486E-06 -6.6885 0.20486E-06 -6.6885 0.10000E+01 0.0000 57 HCl,aq 0.58670E-02 -2.2316 0.58670E-02 -2.2316 0.10000E+01 0.0000 66 CuCl,aq 0.19426E-04 -4.7116 0.19426E-04 -4.7116 0.10000E+01 0.0000 67 CuCl2- 0.80473E-04 -4.0943 0.85189E-05 -5.0696 0.10586E+00 -0.9753 68 CuCl3-2 0.32362E-05 -5.4900 0.10819E-08 -8.9658 0.33432E-03 -3.4758 74 FeCl+ 0.28809E-06 -6.5405 0.34988E-07 -7.4561 0.12145E+00 -0.9156 75 FeCl2,aq 0.18569E-02 -2.7312 0.18569E-02 -2.7312 0.10000E+01 0.0000 77 FeO,aq 0.41576E-07 -7.3812 0.41576E-07 -7.3812 0.10000E+01 0.0000 78 FeOH+ 0.22736E-07 -7.6433 0.27612E-08 -8.5589 0.12145E+00 -0.9156 79 HFeO2- 0.55542E-08 -8.2554 0.58797E-09 -9.2306 0.10586E+00 -0.9753 82 FeO2- 0.32120E-08 -8.4932 0.34003E-09 -9.4685 0.10586E+00 -0.9753 83 HFeO2,aq 0.26938E-09 -9.5696 0.26938E-09 -9.5696 0.10000E+01 0.0000 84 H2,aq 0.41324E-02 -2.3838 0.48364E-02 -2.3155 0.11704E+01 0.0683 85 KCl,aq 0.69275E-01 -1.1594 0.69275E-01 -1.1594 0.10000E+01 0.0000 86 KHSO4,aq 0.11666E-01 -1.9331 0.11666E-01 -1.9331 0.10000E+01 0.0000 87 KOH,aq 0.12631E-05 -5.8986 0.12631E-05 -5.8986 0.10000E+01 0.0000 88 KSO4- 0.56348E-02 -2.2491 0.59651E-03 -3.2244 0.10586E+00 -0.9753 90 Mg(HCO3)+ 0.17614E-07 -7.7541 0.21392E-08 -8.6698 0.12145E+00 -0.9156 91 MgCl+ 0.14234E-04 -4.8467 0.17287E-05 -5.7623 0.12145E+00 -0.9156 92 MgOH+ 0.48817E-06 -6.3114 0.59286E-07 -7.2270 0.12145E+00 -0.9156 94 MnO,aq 0.72280E-07 -7.1410 0.72280E-07 -7.1410 0.10000E+01 0.0000 95 MnOH+ 0.22011E-06 -6.6574 0.26732E-07 -7.5730 0.12145E+00 -0.9156 97 HMnO2- 0.34786E-10 -10.4586 0.36825E-11 -11.4339 0.10586E+00 -0.9753 100 MnCl+ 0.11499E-02 -2.9394 0.13965E-03 -3.8550 0.12145E+00 -0.9156 101 MnSO4,aq 0.19840E-06 -6.7025 0.19840E-06 -6.7025 0.10000E+01 0.0000 102 NaCl,aq 0.43133E+00 -0.3652 0.43133E+00 -0.3652 0.10000E+01 0.0000 103 NaOH,aq 0.16563E-05 -5.7809 0.16563E-05 -5.7809 0.10000E+01 0.0000 105 OH- 0.87987E-05 -5.0556 0.78874E-06 -6.1031 0.89643E-01 -1.0475 110 HPO3-2 0.27277E-10 -10.5642 0.91193E-14 -14.0400 0.33432E-03 -3.4758 111 H3PO3,aq 0.13730E-09 -9.8623 0.13730E-09 -9.8623 0.10000E+01 0.0000 112 H2PO3- 0.16917E-08 -8.7717 0.17908E-09 -9.7469 0.10586E+00 -0.9753 113 H3PO4,aq 0.21715E-05 -5.6632 0.21715E-05 -5.6632 0.10000E+01 0.0000 114 H2PO4- 0.18762E-05 -5.7267 0.21179E-06 -6.6741 0.11288E+00 -0.9474 116 H4P2O7,aq 0.45355E-09 -9.3434 0.45355E-09 -9.3434 0.10000E+01 0.0000 117 H3P2O7- 0.14458E-08 -8.8399 0.15306E-09 -9.8151 0.10586E+00 -0.9753 118 H2P2O7-2 0.74933E-06 -6.1253 0.25051E-09 -9.6012 0.33432E-03 -3.4758 119 HP2O7-3 0.77550E-06 -6.1104 0.87745E-14 -14.0568 0.11315E-07 -7.9464 120 P2O7-4 0.26583E-10 -10.5754 0.88929E-24 -24.0510 0.33453E-13 -13.4756 121 PbCl+ 0.12068E-05 -5.9184 0.14656E-06 -6.8340 0.12145E+00 -0.9156 122 PbCl2,aq 0.76432E-04 -4.1167 0.76432E-04 -4.1167 0.10000E+01 0.0000 123 PbCl3- 0.11012E-03 -3.9581 0.11657E-04 -4.9334 0.10586E+00 -0.9753 124 PbCl4-2 0.39404E-04 -4.4045 0.13173E-07 -7.8803 0.33432E-03 -3.4758 125 PbO,aq 0.58923E-08 -8.2297 0.58923E-08 -8.2297 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.10126E-03 -3.9945 0.10126E-03 -3.9945 0.10000E+01 0.0000 128 Pb(HS)3- 0.13958E-04 -4.8552 0.14776E-05 -5.8305 0.10586E+00 -0.9753 129 H2S,aq 0.10592E+01 0.0250 0.12397E+01 0.0933 0.11704E+01 0.0683 130 S2-2 0.32723E-07 -7.4851 0.10940E-10 -10.9610 0.33432E-03 -3.4758 131 S3-2 0.29486E-08 -8.5304 0.98576E-12 -12.0062 0.33432E-03 -3.4758 132 S3- 0.82942E-02 -2.0812 0.87803E-03 -3.0565 0.10586E+00 -0.9753 133 S4-2 0.22897E-09 -9.6402 0.76549E-13 -13.1161 0.33432E-03 -3.4758 134 S5-2 0.15666E-10 -10.8050 0.52374E-14 -14.2809 0.33432E-03 -3.4758 135 SO2,aq 0.29344E+00 -0.5325 0.29344E+00 -0.5325 0.10000E+01 0.0000 136 SO3-2 0.19360E-08 -8.7131 0.11902E-11 -11.9244 0.61476E-03 -3.2113 137 HSO3- 0.23446E-03 -3.6299 0.24820E-04 -4.6052 0.10586E+00 -0.9753 138 HSO4- 0.87046E-02 -2.0603 0.10965E-02 -2.9600 0.12596E+00 -0.8998 140 S2O3-2 0.16242E-05 -5.7894 0.54300E-09 -9.2652 0.33432E-03 -3.4758 141 HS2O3- 0.37012E-06 -6.4317 0.39181E-07 -7.4069 0.10586E+00 -0.9753 142 H2S2O3,aq 0.45678E-07 -7.3403 0.45678E-07 -7.3403 0.10000E+01 0.0000 150 S4O6-2 0.12245E-08 -8.9120 0.40936E-12 -12.3879 0.33432E-03 -3.4758 152 ZnCl+ 0.13579E-03 -3.8671 0.16492E-04 -4.7827 0.12145E+00 -0.9156 153 ZnCl2,aq 0.49311E-03 -3.3071 0.49311E-03 -3.3071 0.10000E+01 0.0000 154 ZnCl3- 0.33578E-04 -4.4739 0.35546E-05 -5.4492 0.10586E+00 -0.9753 155 ZnO,aq 0.22504E-07 -7.6477 0.22504E-07 -7.6477 0.10000E+01 0.0000 156 ZnOH+ 0.97450E-06 -6.0112 0.11835E-06 -6.9268 0.12145E+00 -0.9156 158 HZnO2- 0.19761E-09 -9.7042 0.20919E-10 -10.6795 0.10586E+00 -0.9753 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5415451E-05 0.4293226E+01 0.3544475E+04 0.0000 2 H2O 0.1000000E+01 0.5252476E+02 0.7750668E+06 0.0000 3 Cl- 0.1420728E+00 0.6557212E+00 0.1904170E+05 4.3205 4 SO4-- 0.9159738E-03 0.2512359E+00 0.1976811E+05 5.8165 5 HCO3- 0.7616877E-05 0.2673484E+01 0.1336175E+06 0.0913 6 HS- 0.1315735E-03 0.1153851E+01 0.3125676E+05 1.2917 7 H4SiO4 0.3718769E-01 0.3719089E-01 0.2927946E+04 -1.4296 8 Al+++ 0.3438174E-14 0.1415916E-04 0.3129228E+00 -3.9114 9 Ca++ 0.5862966E-05 0.1482471E-03 0.4866602E+01 3.4951 10 Mg++ 0.6070315E-05 0.2081188E-04 0.4144437E+00 3.3997 11 Fe++ 0.7371671E-07 0.1857342E-02 0.8496212E+02 1.5120 12 K+ 0.3896877E-01 0.1255454E+00 0.4020993E+04 3.8134 13 Na+ 0.1268949E+00 0.5582264E+00 0.1051185E+05 4.2770 14 Mn++ 0.6665254E-05 0.1157018E-02 0.5206507E+02 3.4887 15 Zn++ 0.2009915E-08 0.6634854E-03 0.3552576E+02 -0.0524 16 Cu+ 0.1360810E-07 0.1031491E-03 0.5368414E+01 -2.6941 17 Pb++ 0.1051431E-07 0.3423974E-03 0.5810758E+02 0.8133 18 Ag+ 0.7408180E-10 0.8757746E-05 0.7737962E+00 -4.9166 19 Ba++ 0.2172352E-06 0.7509094E-05 0.8447304E+00 2.1695 20 HPO4-- 0.6359591E-08 0.7109444E-05 0.5589145E+00 0.6609 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265330E+01 -.2967958E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5218348E+02 -.2187016E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2496035E+00 0.2119260E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1146354E+01 0.1378989E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3694924E-01 0.1066451E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1406716E-04 0.6804724E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1472839E-03 0.3806260E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1845274E-02 0.6921480E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247297E+00 0.6804724E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.6591744E-03 0.1640160E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1024788E-03 0.2971309E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7460303E-05 0.4791215E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.7063250E-05 0.1504250E-05 0.0000000E+00 Chg. balance for solid moles: -.1608E-17 Mass of aqueous solution: 0.121293E+04 g Temperature = 545.00 C Pressure = 890.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3781E-03 -3.422 0.5148E-01 -1.288 0.6822 0.1737E-01 apatite-OH 0.5014E-06 -6.300 0.2519E-03 -3.599 0.3338E-02 0.8004E-04 microcline 0.6805E-03 -3.167 0.1894 -0.723 2.510 0.7399E-01 pyrite 0.6624E-02 -2.179 0.7948 -0.100 10.53 0.1586 quartz 0.1046 -0.980 6.285 0.798 83.28 2.373 barite 0.4791E-04 -4.320 0.1118E-01 -1.951 0.1482 0.2496E-02 chalcopyrite 0.2971E-03 -3.527 0.5452E-01 -1.263 0.7225 0.1273E-01 sphalerite 0.1640E-02 -2.785 0.1598 -0.796 2.118 0.3908E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.546016 g Volume = 2.677654 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.26 -15.26 0.00 0.000 0.00000E+00 27 apatite-OH -54.26 -54.26 0.00 0.000 0.00000E+00 112 microcline -4.38 -4.38 0.00 0.000 -0.66502E-11 137 pyrite -22.42 -22.42 0.00 0.000 0.00000E+00 141 quartz -1.43 -1.43 0.00 0.000 0.00000E+00 234 barite -16.59 -16.59 0.00 0.000 0.00000E+00 237 chalcopyrite -24.14 -24.14 -0.00 -0.000 0.13300E-10 252 sphalerite -11.05 -11.05 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.251 0.94098E+03 2.698 2 CO2,gas -10.43 -12.19 -1.77 -0.589 0.66155E+04 1.182 3 CH4,gas 6.77 -4.43 -11.20 -2.801 0.41939E+05 -8.253 4 H2,gas 6.05 1.94 -4.11 -2.349 0.15391E+05 -1.162 5 H2S,gas -8.68 -10.99 -2.31 -1.156 0.86591E+04 0.636 6 CO,gas -4.06 -10.25 -6.20 -1.907 0.23204E+05 -3.249 7 SO3,gas -7.91 -18.76 -10.84 -2.711 0.40595E+05 -7.894 8 O2,gas 17.20 -3.88 -21.08 -14.053 0.78917E+05 -18.131 9 HCl,gas -6.31 -7.97 -1.66 -0.828 0.61965E+04 -1.655 10 acmite 3.65 1.96 -1.68 -0.175 0.62991E+04 12 akimotoite 6.56 1.97 -4.59 -0.917 0.17169E+05 13 akimotoite-Fe 4.36 0.08 -4.27 -0.855 0.15997E+05 14 albite-high -3.74 -3.92 -0.18 -0.014 0.66680E+03 15 albite -3.75 -3.92 -0.17 -0.013 0.61896E+03 16 almandine -5.15 -7.58 -2.42 -0.121 0.90736E+04 17 pyrope 1.83 -1.91 -3.74 -0.187 0.14020E+05 18 analcite -1.47 -2.49 -1.02 -0.114 0.38300E+04 19 andalusite -8.66 -9.25 -0.60 -0.060 0.22392E+04 24 anorthite -6.22 -7.19 -0.97 -0.074 0.36257E+04 25 anthophyllite 16.57 12.37 -4.19 -0.113 0.15701E+05 26 anthophyllite-Fe 3.21 -0.84 -4.06 -0.110 0.15188E+05 28 apatite-OH-zs -52.02 -54.26 -2.24 -0.172 0.83897E+04 29 apatite-Cl-zs -58.92 -62.23 -3.31 -0.275 0.12374E+05 30 aragonite -4.83 -8.70 -3.87 -1.290 0.14485E+05 31 brucite 5.96 3.40 -2.56 -0.512 0.95761E+04 32 calcite -4.94 -8.70 -3.76 -1.253 0.14068E+05 33 carnegieite-low 0.78 -1.06 -1.84 -0.263 0.68981E+04 34 carnegieite-high 0.87 -1.06 -1.94 -0.277 0.72559E+04 35 carpholite-Mg -4.95 -7.28 -2.34 -0.156 0.87481E+04 36 carpholite-Fe -6.38 -9.17 -2.79 -0.186 0.10446E+05 37 celadonite -0.02 -2.41 -2.40 -0.141 0.89703E+04 38 celadonite-Fe -1.49 -4.30 -2.81 -0.165 0.10518E+05 39 chrysotile 10.55 7.34 -3.21 -0.268 0.12019E+05 41 clinochlore 7.58 4.88 -2.70 -0.084 0.10116E+05 42 daphnite 0.11 -4.56 -4.67 -0.146 0.17494E+05 45 chloritoid-Mg -4.19 -5.86 -1.67 -0.111 0.62539E+04 46 chloritoid-Fe -6.24 -7.74 -1.50 -0.100 0.56160E+04 47 chloritoid-Mn -4.11 -5.77 -1.66 -0.110 0.61968E+04 49 coesite -1.13 -1.43 -0.30 -0.100 0.11240E+04 50 cordierite-H -14.36 -15.99 -1.63 -0.058 0.61101E+04 51 cordierite-Fe -17.14 -19.77 -2.63 -0.091 0.98422E+04 52 cordierite-Mn -12.81 -15.81 -3.00 -0.104 0.11242E+05 53 corundum -7.04 -7.83 -0.78 -0.071 0.29307E+04 55 cristobalite -1.38 -1.43 -0.05 -0.016 0.18048E+03 56 cummingtonite 16.64 12.37 -4.27 -0.115 0.15975E+05 58 cymrite-K -2.00 -4.38 -2.38 -0.199 0.89219E+04 60 diaspore -3.04 -3.91 -0.87 -0.145 0.32535E+04 62 diopside 5.86 4.04 -1.82 -0.182 0.68074E+04 63 hedenbergite 4.35 2.15 -2.20 -0.220 0.82437E+04 65 eastonite -2.03 -3.99 -1.96 -0.075 0.73379E+04 66 enstatite 5.40 3.94 -1.46 -0.146 0.54650E+04 67 clinoenstatite-HiP 5.91 3.94 -1.97 -0.197 0.73743E+04 68 clinoenstatite 5.38 3.94 -1.44 -0.144 0.53861E+04 69 protoenstatite 5.54 3.94 -1.60 -0.160 0.59808E+04 70 epidote -1.80 -4.58 -2.78 -0.135 0.10419E+05 71 clinozoisite -5.91 -9.03 -3.13 -0.142 0.11709E+05 72 epidote-Fe 4.03 -0.13 -4.16 -0.216 0.15561E+05 73 fayalite 2.96 1.59 -1.36 -0.194 0.50940E+04 74 ferrosilite 1.63 0.17 -1.46 -0.146 0.54761E+04 75 forsterite 7.15 5.37 -1.78 -0.254 0.66632E+04 76 gedrite -3.52 -7.22 -3.70 -0.100 0.13863E+05 78 gibbsite -1.41 -3.92 -2.51 -0.358 0.93879E+04 79 glaucophane 3.44 -0.50 -3.93 -0.106 0.14729E+05 81 goethite 1.52 0.54 -0.98 -0.212 0.36640E+04 83 greenalite 5.40 1.68 -3.72 -0.310 0.13931E+05 84 grunerite 3.80 -0.84 -4.64 -0.125 0.17376E+05 85 halite -1.62 -3.69 -2.06 -1.032 0.77301E+04 86 hematite 1.49 1.08 -0.41 -0.049 0.15179E+04 87 heulandite -10.96 -14.33 -3.37 -0.153 0.12618E+05 88 hercynite -4.88 -6.32 -1.44 -0.096 0.53913E+04 91 jadeite -0.78 -2.49 -1.71 -0.171 0.63884E+04 93 kalsilite 0.15 -1.53 -1.68 -0.240 0.62782E+04 94 kaolinite -7.93 -10.68 -2.75 -0.250 0.10300E+05 95 kyanite -8.49 -9.25 -0.77 -0.077 0.28662E+04 97 laumontite -6.22 -10.05 -3.82 -0.255 0.14310E+05 98 lawsonite -3.47 -7.19 -3.72 -0.248 0.13912E+05 99 leucite -1.95 -2.95 -1.01 -0.101 0.37771E+04 101 lizardite 10.70 7.34 -3.36 -0.280 0.12591E+05 102 magnesite -5.52 -8.80 -3.28 -1.093 0.12276E+05 103 magnetite 3.12 2.59 -0.53 -0.043 0.19755E+04 104 minnesotaite 1.29 -1.18 -2.47 -0.145 0.92292E+04 105 minnesotaite-Mg 7.56 4.49 -3.07 -0.181 0.11500E+05 106 magnesioferrite 6.32 4.48 -1.84 -0.150 0.69016E+04 108 manganosite 5.84 3.49 -2.35 -0.587 0.87932E+04 109 margarite -12.84 -15.02 -2.17 -0.087 0.81401E+04 113 monticellite 9.49 5.47 -4.03 -0.575 0.15082E+05 115 mullite-Si -7.87 -9.25 -1.38 -0.138 0.51704E+04 116 muscovite -11.32 -12.21 -0.89 -0.052 0.33239E+04 117 paragonite -10.63 -11.75 -1.12 -0.066 0.41892E+04 118 nepheline 0.47 -1.06 -1.53 -0.219 0.57421E+04 119 osumilite(2) -10.45 -13.43 -2.98 -0.062 0.11149E+05 120 osumilite-Fe -23.93 -27.00 -3.07 -0.064 0.11495E+05 122 periclase 6.19 3.40 -2.79 -0.698 0.10449E+05 123 periclase-Fe 3.50 1.51 -1.99 -0.498 0.74622E+04 124 perovskite-Al -5.26 -7.83 -2.56 -0.233 0.95940E+04 129 phlogopite-Na 8.00 6.28 -1.73 -0.096 0.64592E+04 131 prehnite -1.40 -5.12 -3.72 -0.219 0.13926E+05 132 prehnite-Fe 3.11 -0.67 -3.78 -0.227 0.14140E+05 135 px-Mg-tschermaks -3.49 -5.86 -2.36 -0.169 0.88460E+04 136 px-Ca-tschermaks -2.86 -5.76 -2.90 -0.207 0.10875E+05 138 pyrrhotite -8.70 -9.48 -0.78 -0.260 0.29202E+04 139 pyrrhotiteFe0.875 -9.54 -9.91 -0.37 -0.136 0.13810E+04 140 pyrophyllite -12.09 -13.54 -1.44 -0.090 0.54034E+04 143 riebeckite 6.26 2.75 -3.52 -0.097 0.13163E+05 144 ringwoodite-Fe 3.97 1.59 -2.37 -0.339 0.88753E+04 146 rhodochrosite -5.60 -8.71 -3.10 -1.034 0.11614E+05 147 rhodonite 2.74 2.06 -0.68 -0.137 0.25564E+04 148 sanidine -3.83 -4.38 -0.55 -0.043 0.20686E+04 150 siderite -7.45 -10.68 -3.23 -1.076 0.12087E+05 151 sillimanite -8.61 -9.25 -0.64 -0.064 0.24006E+04 153 spinel -2.61 -4.43 -1.82 -0.121 0.68183E+04 160 stilpnomelane-Mg 3.15 -0.35 -3.50 -0.105 0.13107E+05 161 stishovite 1.60 -1.43 -3.03 -1.009 0.11333E+05 162 sudoite-Fe -12.12 -16.92 -4.80 -0.155 0.17956E+05 163 sudoite -9.76 -13.14 -3.39 -0.109 0.12679E+05 164 sulfur -11.45 -12.93 -1.48 -0.456 0.55436E+04 165 sylvite -1.53 -4.15 -2.62 -1.312 0.98199E+04 166 talc 5.79 4.49 -1.30 -0.077 0.48742E+04 167 talc-Fe 2.74 -1.18 -3.91 -0.230 0.14648E+05 168 talc-tschermaks -3.03 -5.31 -2.28 -0.134 0.85533E+04 170 tephroite 7.18 5.55 -1.63 -0.233 0.61009E+04 173 topaz-H -6.57 -9.26 -2.69 -0.244 0.10060E+05 174 tremolite 16.85 12.56 -4.28 -0.116 0.16041E+05 176 troilite-low -8.62 -9.48 -0.87 -0.289 0.32475E+04 177 tschermakite -2.45 -7.03 -4.58 -0.124 0.17152E+05 180 wadsleyite-Fe 3.83 1.59 -2.23 -0.319 0.83532E+04 181 wadsleyite-Mg 9.42 5.37 -4.05 -0.579 0.15167E+05 182 wairakite -8.11 -10.04 -1.94 -0.114 0.72495E+04 183 walstromite 4.79 2.07 -2.72 -0.544 0.10189E+05 184 wollastonite 4.35 2.07 -2.28 -0.457 0.85525E+04 185 pseudo-wollastonite 4.48 2.07 -2.41 -0.482 0.90165E+04 186 zoisite -5.95 -9.03 -3.08 -0.140 0.11536E+05 189 beidellite-Ca -11.95 -13.78 -1.83 -0.113 0.68377E+04 190 beidellite-H -12.02 -14.36 -2.34 -0.149 0.87534E+04 191 beidellite-K -10.98 -13.10 -2.12 -0.130 0.79274E+04 192 beidellite-Mg -12.18 -13.80 -1.62 -0.100 0.60523E+04 193 beidellite-Na -10.92 -12.95 -2.02 -0.124 0.75712E+04 194 bornite -56.72 -56.91 -0.18 -0.014 0.68642E+03 196 chalcocite -14.96 -16.38 -1.42 -0.355 0.53096E+04 197 covellite -13.35 -14.66 -1.31 -0.500 0.49108E+04 199 montmorillonite-Ca -9.10 -10.55 -1.45 -0.090 0.54302E+04 200 montmorillonite-K -8.40 -9.86 -1.47 -0.090 0.55008E+04 201 montmorillonite-Mg -9.29 -10.56 -1.27 -0.079 0.47664E+04 202 montmorillonite-Na -8.07 -9.71 -1.64 -0.100 0.61390E+04 203 nontronite-Ca -3.15 -4.87 -1.73 -0.112 0.64620E+04 204 nontronite-H -3.22 -5.45 -2.23 -0.149 0.83500E+04 205 nontronite-K -2.18 -4.19 -2.02 -0.129 0.75439E+04 206 nontronite-Mg -3.34 -4.89 -1.55 -0.100 0.57868E+04 207 nontronite-Na -2.11 -4.04 -1.92 -0.123 0.71999E+04 212 gypsum -12.98 -15.26 -2.28 -0.570 0.85388E+04 229 alabandite -6.43 -7.51 -1.07 -0.358 0.40164E+04 231 anglesite -15.64 -17.94 -2.30 -1.151 0.86198E+04 235 boehmite -2.74 -3.91 -1.18 -0.196 0.44106E+04 239 copper,native 1.68 -1.72 -3.41 -1.185 0.12750E+05 241 ferrous-oxide 2.56 1.51 -1.05 -0.262 0.39257E+04 242 galena -10.18 -10.18 -0.00 -0.001 0.14483E+02 243 silver,native 0.35 -3.95 -4.30 -1.495 0.16094E+05 245 litharge 5.51 0.81 -4.70 -1.174 0.17587E+05 253 wurtzite -10.22 -11.05 -0.83 -0.275 0.30909E+04 254 zincite 2.61 -0.05 -2.67 -0.667 0.99904E+04 255 an20ab80 -4.46 -4.57 -0.11 -0.008 0.40572E+03 256 an25ab75 -4.61 -4.74 -0.12 -0.009 0.45798E+03 257 an30ab70 -4.76 -4.90 -0.14 -0.011 0.52951E+03 258 tr.625ac.25prg.125 11.73 9.20 -2.53 -0.068 0.94557E+04 Calculations done for 545.0000 Deg. C; 890.0000 bar Temperature changed by -1.000 degrees to 544.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 56 Loop limit = 500 Temperature = 544.00 C Pressure = 879.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9935E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9970 Stoichiometric ionic strength = .3269847E+01 Osmotic coef. = 0.0000 True ionic strength = .1700305E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54388E-05 -5.2645 0.69448E-06 -6.1583 0.12769E+00 -0.8938 2 H2O 0.99702E+00 -0.0013 0.99702E+00 -0.0013 3 Cl- 0.14345E+00 -0.8433 0.14516E-01 -1.8382 0.10119E+00 -0.9949 4 SO4-- 0.10325E-02 -2.9861 0.32545E-06 -6.4875 0.31522E-03 -3.5014 5 HCO3- 0.74956E-05 -5.1252 0.83627E-06 -6.0777 0.11157E+00 -0.9525 6 HS- 0.13350E-03 -3.8745 0.13656E-04 -4.8647 0.10229E+00 -0.9902 7 H4SiO4 0.36398E-01 -1.4389 0.36398E-01 -1.4389 0.10000E+01 0.0000 8 Al+++ 0.52947E-14 -14.2762 0.48437E-22 -22.3148 0.91483E-08 -8.0387 9 Ca++ 0.67017E-05 -5.1738 0.15641E-08 -8.8057 0.23340E-03 -3.6319 10 Mg++ 0.66445E-05 -5.1775 0.11962E-08 -8.9222 0.18003E-03 -3.7446 11 Fe++ 0.86321E-07 -7.0639 0.16594E-10 -10.7801 0.19224E-03 -3.7162 12 K+ 0.39247E-01 -1.4062 0.45157E-02 -2.3453 0.11506E+00 -0.9391 13 Na+ 0.12822E+00 -0.8920 0.13146E-01 -1.8812 0.10253E+00 -0.9892 14 Mn++ 0.77763E-05 -5.1092 0.15684E-08 -8.8045 0.20169E-03 -3.6953 15 Zn++ 0.23527E-08 -8.6284 0.45228E-12 -12.3446 0.19224E-03 -3.7162 16 Cu+ 0.13598E-07 -7.8665 0.13893E-08 -8.8572 0.10217E+00 -0.9907 17 Pb++ 0.11780E-07 -7.9289 0.32003E-11 -11.4948 0.27169E-03 -3.5659 18 Ag+ 0.61227E-10 -10.2131 0.68983E-11 -11.1613 0.11267E+00 -0.9482 19 Ba++ 0.24128E-06 -6.6175 0.72191E-10 -10.1415 0.29920E-03 -3.5240 20 HPO4-- 0.72589E-08 -8.1391 0.23036E-11 -11.6376 0.31735E-03 -3.4985 21 HSiO3- 0.14573E-05 -5.8365 0.14747E-06 -6.8313 0.10119E+00 -0.9949 22 Ca(HSiO3)+ 0.46682E-08 -8.3308 0.54345E-09 -9.2648 0.11641E+00 -0.9340 23 Mg(HSiO3)+ 0.12939E-08 -8.8881 0.15063E-09 -9.8221 0.11641E+00 -0.9340 24 NaHSiO3,aq 0.17587E-05 -5.7548 0.17587E-05 -5.7548 0.10000E+01 0.0000 28 AgCl,aq 0.21930E-07 -7.6590 0.21930E-07 -7.6590 0.10000E+01 0.0000 29 AgCl2- 0.11024E-05 -5.9576 0.11156E-06 -6.9525 0.10119E+00 -0.9949 30 AgCl3-2 0.84744E-06 -6.0719 0.24088E-09 -9.6182 0.28424E-03 -3.5463 31 AgCl4-3 0.67838E-05 -5.1685 0.52833E-13 -13.2771 0.77881E-08 -8.1086 34 Ag(HS),aq 0.45180E-09 -9.3451 0.45180E-09 -9.3451 0.10000E+01 0.0000 35 Ag(HS)2- 0.14577E-08 -8.8363 0.14751E-09 -9.8312 0.10119E+00 -0.9949 36 AlO+ 0.26575E-10 -10.5755 0.30937E-11 -11.5095 0.11641E+00 -0.9340 38 HAlO2,aq 0.51122E-08 -8.2914 0.51122E-08 -8.2914 0.10000E+01 0.0000 39 AlO2- 0.14510E-04 -4.8383 0.12392E-05 -5.9069 0.85405E-01 -1.0685 41 Ba(HCO3)+ 0.15134E-06 -6.8200 0.18582E-07 -7.7309 0.12278E+00 -0.9109 42 BaCl+ 0.70503E-05 -5.1518 0.82075E-06 -6.0858 0.11641E+00 -0.9340 43 CH4,aq 0.12302E-08 -8.9100 0.14377E-08 -8.8423 0.11686E+01 0.0677 48 CO,aq 0.38210E-03 -3.4178 0.38210E-03 -3.4178 0.10000E+01 0.0000 49 CO2,aq 0.26730E+01 0.4270 0.31238E+01 0.4947 0.11686E+01 0.0677 50 CO3-2 0.12591E-09 -9.8999 0.35789E-13 -13.4462 0.28424E-03 -3.5463 52 Ca(HCO3)+ 0.70656E-07 -7.1509 0.82253E-08 -8.0848 0.11641E+00 -0.9340 53 CaCl+ 0.77081E-04 -4.1131 0.89733E-05 -5.0470 0.11641E+00 -0.9340 54 CaCl2,aq 0.64098E-04 -4.1932 0.64098E-04 -4.1932 0.10000E+01 0.0000 55 CaOH+ 0.13703E-06 -6.8632 0.15952E-07 -7.7972 0.11641E+00 -0.9340 56 CaSO4,aq 0.20750E-06 -6.6830 0.20750E-06 -6.6830 0.10000E+01 0.0000 57 HCl,aq 0.61827E-02 -2.2088 0.61827E-02 -2.2088 0.10000E+01 0.0000 66 CuCl,aq 0.19194E-04 -4.7168 0.19194E-04 -4.7168 0.10000E+01 0.0000 67 CuCl2- 0.80775E-04 -4.0927 0.81738E-05 -5.0876 0.10119E+00 -0.9949 68 CuCl3-2 0.34730E-05 -5.4593 0.98717E-09 -9.0056 0.28424E-03 -3.5463 74 FeCl+ 0.29464E-06 -6.5307 0.34300E-07 -7.4647 0.11641E+00 -0.9340 75 FeCl2,aq 0.18008E-02 -2.7445 0.18008E-02 -2.7445 0.10000E+01 0.0000 77 FeO,aq 0.41164E-07 -7.3855 0.41164E-07 -7.3855 0.10000E+01 0.0000 78 FeOH+ 0.23311E-07 -7.6324 0.27137E-08 -8.5664 0.11641E+00 -0.9340 79 HFeO2- 0.56599E-08 -8.2472 0.57274E-09 -9.2420 0.10119E+00 -0.9949 82 FeO2- 0.32248E-08 -8.4915 0.32633E-09 -9.4863 0.10119E+00 -0.9949 83 HFeO2,aq 0.27175E-09 -9.5658 0.27175E-09 -9.5658 0.10000E+01 0.0000 84 H2,aq 0.41359E-02 -2.3834 0.48334E-02 -2.3158 0.11686E+01 0.0677 85 KCl,aq 0.69042E-01 -1.1609 0.69042E-01 -1.1609 0.10000E+01 0.0000 86 KHSO4,aq 0.11523E-01 -1.9384 0.11523E-01 -1.9384 0.10000E+01 0.0000 87 KOH,aq 0.12628E-05 -5.8987 0.12628E-05 -5.8987 0.10000E+01 0.0000 88 KSO4- 0.57295E-02 -2.2419 0.57978E-03 -3.2367 0.10119E+00 -0.9949 90 Mg(HCO3)+ 0.16153E-07 -7.7918 0.18804E-08 -8.7257 0.11641E+00 -0.9340 91 MgCl+ 0.13680E-04 -4.8639 0.15926E-05 -5.7979 0.11641E+00 -0.9340 92 MgOH+ 0.46915E-06 -6.3287 0.54616E-07 -7.2627 0.11641E+00 -0.9340 94 MnO,aq 0.71821E-07 -7.1438 0.71821E-07 -7.1438 0.10000E+01 0.0000 95 MnOH+ 0.22327E-06 -6.6512 0.25991E-07 -7.5852 0.11641E+00 -0.9340 97 HMnO2- 0.35236E-10 -10.4530 0.35656E-11 -11.4479 0.10119E+00 -0.9949 100 MnCl+ 0.11487E-02 -2.9398 0.13373E-03 -3.8738 0.11641E+00 -0.9340 101 MnSO4,aq 0.20238E-06 -6.6938 0.20238E-06 -6.6938 0.10000E+01 0.0000 102 NaCl,aq 0.42999E+00 -0.3665 0.42999E+00 -0.3665 0.10000E+01 0.0000 103 NaOH,aq 0.16543E-05 -5.7814 0.16543E-05 -5.7814 0.10000E+01 0.0000 105 OH- 0.90400E-05 -5.0438 0.77206E-06 -6.1123 0.85405E-01 -1.0685 110 HPO3-2 0.30011E-10 -10.5227 0.85305E-14 -14.0690 0.28424E-03 -3.5463 111 H3PO3,aq 0.13848E-09 -9.8586 0.13848E-09 -9.8586 0.10000E+01 0.0000 112 H2PO3- 0.16730E-08 -8.7765 0.16929E-09 -9.7714 0.10119E+00 -0.9949 113 H3PO4,aq 0.22263E-05 -5.6524 0.22263E-05 -5.6524 0.10000E+01 0.0000 114 H2PO4- 0.19051E-05 -5.7201 0.20584E-06 -6.6865 0.10805E+00 -0.9664 116 H4P2O7,aq 0.48041E-09 -9.3184 0.48041E-09 -9.3184 0.10000E+01 0.0000 117 H3P2O7- 0.14726E-08 -8.8319 0.14901E-09 -9.8268 0.10119E+00 -0.9949 118 H2P2O7-2 0.82080E-06 -6.0858 0.23330E-09 -9.6321 0.28424E-03 -3.5463 119 HP2O7-3 0.10427E-05 -5.9818 0.81209E-14 -14.0904 0.77881E-08 -8.1086 120 P2O7-4 0.48514E-10 -10.3141 0.85976E-24 -24.0656 0.17722E-13 -13.7515 121 PbCl+ 0.11983E-05 -5.9214 0.13950E-06 -6.8554 0.11641E+00 -0.9340 122 PbCl2,aq 0.75215E-04 -4.1237 0.75215E-04 -4.1237 0.10000E+01 0.0000 123 PbCl3- 0.11050E-03 -3.9566 0.11182E-04 -4.9515 0.10119E+00 -0.9949 124 PbCl4-2 0.42084E-04 -4.3759 0.11962E-07 -7.9222 0.28424E-03 -3.5463 125 PbO,aq 0.58798E-08 -8.2306 0.58798E-08 -8.2306 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.99350E-04 -4.0028 0.99350E-04 -4.0028 0.10000E+01 0.0000 128 Pb(HS)3- 0.14025E-04 -4.8531 0.14192E-05 -5.8479 0.10119E+00 -0.9949 129 H2S,aq 0.10594E+01 0.0251 0.12381E+01 0.0927 0.11686E+01 0.0677 130 S2-2 0.35892E-07 -7.4450 0.10202E-10 -10.9913 0.28424E-03 -3.5463 131 S3-2 0.32027E-08 -8.4945 0.91035E-12 -12.0408 0.28424E-03 -3.5463 132 S3- 0.81609E-02 -2.0883 0.82582E-03 -3.0831 0.10119E+00 -0.9949 133 S4-2 0.24668E-09 -9.6079 0.70115E-13 -13.1542 0.28424E-03 -3.5463 134 S5-2 0.16752E-10 -10.7759 0.47617E-14 -14.3222 0.28424E-03 -3.5463 135 SO2,aq 0.29339E+00 -0.5326 0.29339E+00 -0.5326 0.10000E+01 0.0000 136 SO3-2 0.21514E-08 -8.6673 0.11393E-11 -11.9434 0.52957E-03 -3.2761 137 HSO3- 0.23403E-03 -3.6307 0.23682E-04 -4.6256 0.10119E+00 -0.9949 138 HSO4- 0.87368E-02 -2.0586 0.10558E-02 -2.9764 0.12085E+00 -0.9178 140 S2O3-2 0.17956E-05 -5.7458 0.51038E-09 -9.2921 0.28424E-03 -3.5463 141 HS2O3- 0.36834E-06 -6.4338 0.37273E-07 -7.4286 0.10119E+00 -0.9949 142 H2S2O3,aq 0.46410E-07 -7.3334 0.46410E-07 -7.3334 0.10000E+01 0.0000 150 S4O6-2 0.13212E-08 -8.8790 0.37553E-12 -12.4254 0.28424E-03 -3.5463 152 ZnCl+ 0.13434E-03 -3.8718 0.15639E-04 -4.8058 0.11641E+00 -0.9340 153 ZnCl2,aq 0.48277E-03 -3.3163 0.48277E-03 -3.3163 0.10000E+01 0.0000 154 ZnCl3- 0.32784E-04 -4.4843 0.33175E-05 -5.4792 0.10119E+00 -0.9949 155 ZnO,aq 0.22320E-07 -7.6513 0.22320E-07 -7.6513 0.10000E+01 0.0000 156 ZnOH+ 0.97456E-06 -6.0112 0.11345E-06 -6.9452 0.11641E+00 -0.9340 158 HZnO2- 0.20191E-09 -9.6948 0.20432E-10 -10.6897 0.10119E+00 -0.9949 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5438834E-05 0.4293124E+01 0.3544632E+04 -0.0000 2 H2O 0.1000000E+01 0.5252521E+02 0.7751261E+06 0.0000 3 Cl- 0.1434474E+00 0.6557064E+00 0.1904257E+05 4.3202 4 SO4-- 0.1032477E-02 0.2512149E+00 0.1976780E+05 5.8292 5 HCO3- 0.7495623E-05 0.2673424E+01 0.1336236E+06 0.0807 6 HS- 0.1335050E-03 0.1153715E+01 0.3125518E+05 1.2937 7 H4SiO4 0.3639779E-01 0.3640101E-01 0.2865956E+04 -1.4389 8 Al+++ 0.5294695E-14 0.1451489E-04 0.3208063E+00 -3.8398 9 Ca++ 0.6701715E-05 0.1483004E-03 0.4868683E+01 3.5110 10 Mg++ 0.6644523E-05 0.2081141E-04 0.4144625E+00 3.3945 11 Fe++ 0.8632085E-07 0.1801209E-02 0.8239998E+02 1.5366 12 K+ 0.3924744E-01 0.1255429E+00 0.4021187E+04 3.8131 13 Na+ 0.1282250E+00 0.5582138E+00 0.1051233E+05 4.2771 14 Mn++ 0.7776286E-05 0.1156992E-02 0.5206743E+02 3.5121 15 Zn++ 0.2352723E-08 0.6508915E-03 0.3485380E+02 -0.0279 16 Cu+ 0.1359846E-07 0.1034557E-03 0.5384738E+01 -2.6989 17 Pb++ 0.1177952E-07 0.3423897E-03 0.5811022E+02 0.8219 18 Ag+ 0.6122741E-10 0.8757548E-05 0.7738313E+00 -5.0029 19 Ba++ 0.2412803E-06 0.7442910E-05 0.8373420E+00 2.1752 20 HPO4-- 0.7258899E-08 0.7871593E-05 0.6188736E+00 0.6791 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265326E+01 -.2963753E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5218511E+02 -.2203263E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2495883E+00 0.2134502E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1146244E+01 0.1389987E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3616531E-01 0.1074290E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1442091E-04 0.6801186E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1473402E-03 0.3805697E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1789546E-02 0.6977207E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247300E+00 0.6801186E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.6466769E-03 0.1652658E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1027858E-03 0.2968239E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7394717E-05 0.4797774E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.7820624E-05 0.7468763E-06 0.0000000E+00 Chg. balance for solid moles: -.9887E-18 Mass of aqueous solution: 0.121287E+04 g Temperature = 544.00 C Pressure = 879.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3793E-03 -3.421 0.5164E-01 -1.287 0.6794 0.1743E-01 apatite-OH 0.2490E-06 -6.604 0.1251E-03 -3.903 0.1645E-02 0.3974E-04 microcline 0.6801E-03 -3.167 0.1893 -0.723 2.491 0.7395E-01 pyrite 0.6680E-02 -2.175 0.8015 -0.096 10.54 0.1599 quartz 0.1054 -0.977 6.332 0.802 83.30 2.391 barite 0.4798E-04 -4.319 0.1120E-01 -1.951 0.1473 0.2500E-02 chalcopyrite 0.2968E-03 -3.528 0.5447E-01 -1.264 0.7166 0.1271E-01 sphalerite 0.1653E-02 -2.782 0.1610 -0.793 2.118 0.3938E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.601017 g Volume = 2.697071 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.29 -15.29 0.00 0.000 -0.66421E-11 27 apatite-OH -54.31 -54.31 0.00 0.000 -0.26568E-10 112 microcline -4.34 -4.34 0.00 0.000 -0.23247E-10 137 pyrite -22.45 -22.45 0.00 0.000 0.00000E+00 141 quartz -1.44 -1.44 0.00 0.000 0.00000E+00 234 barite -16.63 -16.63 0.00 0.000 -0.13284E-10 237 chalcopyrite -24.18 -24.18 0.00 0.000 0.00000E+00 252 sphalerite -11.05 -11.05 0.00 0.000 -0.66421E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.250 0.93644E+03 2.694 2 CO2,gas -10.46 -12.23 -1.78 -0.592 0.66401E+04 1.168 3 CH4,gas 6.76 -4.46 -11.22 -2.804 0.41944E+05 -8.273 4 H2,gas 6.06 1.94 -4.11 -2.350 0.15380E+05 -1.169 5 H2S,gas -8.71 -11.02 -2.32 -1.158 0.86577E+04 0.629 6 CO,gas -4.08 -10.29 -6.21 -1.912 0.23230E+05 -3.269 7 SO3,gas -7.94 -18.80 -10.86 -2.715 0.40600E+05 -7.914 8 O2,gas 17.22 -3.89 -21.11 -14.071 0.78923E+05 -18.163 9 HCl,gas -6.33 -8.00 -1.67 -0.834 0.62336E+04 -1.667 10 acmite 3.65 1.97 -1.69 -0.175 0.63028E+04 12 akimotoite 6.59 1.96 -4.63 -0.926 0.17311E+05 13 akimotoite-Fe 4.38 0.10 -4.28 -0.856 0.16008E+05 14 albite-high -3.69 -3.87 -0.18 -0.014 0.67432E+03 15 albite -3.71 -3.87 -0.17 -0.013 0.62232E+03 16 almandine -4.95 -7.39 -2.44 -0.122 0.91216E+04 17 pyrope 2.06 -1.81 -3.87 -0.193 0.14466E+05 18 analcite -1.41 -2.44 -1.03 -0.114 0.38337E+04 19 andalusite -8.52 -9.12 -0.60 -0.060 0.22503E+04 24 anorthite -6.07 -7.05 -0.98 -0.075 0.36514E+04 25 anthophyllite 16.72 12.26 -4.46 -0.121 0.16692E+05 26 anthophyllite-Fe 3.33 -0.74 -4.08 -0.110 0.15250E+05 28 apatite-OH-zs -52.06 -54.31 -2.24 -0.173 0.83920E+04 29 apatite-Cl-zs -58.99 -62.30 -3.31 -0.276 0.12382E+05 30 aragonite -4.84 -8.73 -3.88 -1.294 0.14513E+05 31 brucite 5.99 3.39 -2.60 -0.519 0.97121E+04 32 calcite -4.96 -8.73 -3.77 -1.257 0.14095E+05 33 carnegieite-low 0.84 -1.00 -1.85 -0.264 0.69010E+04 34 carnegieite-high 0.94 -1.00 -1.94 -0.277 0.72614E+04 35 carpholite-Mg -4.79 -7.17 -2.38 -0.158 0.88839E+04 36 carpholite-Fe -6.23 -9.02 -2.80 -0.186 0.10452E+05 37 celadonite 0.05 -2.38 -2.44 -0.143 0.91052E+04 38 celadonite-Fe -1.43 -4.24 -2.81 -0.166 0.10523E+05 39 chrysotile 10.63 7.30 -3.32 -0.277 0.12428E+05 41 clinochlore 7.86 4.97 -2.89 -0.090 0.10799E+05 42 daphnite 0.36 -4.32 -4.69 -0.146 0.17521E+05 45 chloritoid-Mg -4.02 -5.73 -1.71 -0.114 0.63962E+04 46 chloritoid-Fe -6.08 -7.59 -1.50 -0.100 0.56243E+04 47 chloritoid-Mn -3.95 -5.61 -1.66 -0.111 0.62036E+04 49 coesite -1.14 -1.44 -0.30 -0.100 0.11244E+04 50 cordierite-H -14.05 -15.76 -1.72 -0.061 0.64213E+04 51 cordierite-Fe -16.83 -19.48 -2.64 -0.091 0.98845E+04 52 cordierite-Mn -12.51 -15.53 -3.02 -0.104 0.11280E+05 53 corundum -6.90 -7.68 -0.79 -0.072 0.29418E+04 55 cristobalite -1.39 -1.44 -0.05 -0.016 0.18114E+03 56 cummingtonite 16.80 12.26 -4.54 -0.123 0.16967E+05 58 cymrite-K -1.95 -4.34 -2.39 -0.199 0.89249E+04 60 diaspore -2.97 -3.84 -0.87 -0.145 0.32529E+04 62 diopside 5.89 4.03 -1.86 -0.186 0.69624E+04 63 hedenbergite 4.38 2.17 -2.21 -0.221 0.82672E+04 65 eastonite -1.76 -3.80 -2.04 -0.078 0.76259E+04 66 enstatite 5.45 3.91 -1.54 -0.154 0.57507E+04 67 clinoenstatite-HiP 5.96 3.91 -2.05 -0.205 0.76607E+04 68 clinoenstatite 5.43 3.91 -1.52 -0.152 0.56717E+04 69 protoenstatite 5.59 3.91 -1.68 -0.168 0.62679E+04 70 epidote -1.61 -4.41 -2.80 -0.136 0.10456E+05 71 clinozoisite -5.67 -8.82 -3.14 -0.143 0.11746E+05 72 epidote-Fe 4.16 -0.01 -4.17 -0.217 0.15595E+05 73 fayalite 3.00 1.63 -1.37 -0.195 0.51156E+04 74 ferrosilite 1.67 0.20 -1.47 -0.147 0.54980E+04 75 forsterite 7.21 5.35 -1.86 -0.265 0.69483E+04 76 gedrite -3.12 -7.02 -3.90 -0.105 0.14591E+05 78 gibbsite -1.34 -3.84 -2.51 -0.358 0.93799E+04 79 glaucophane 3.61 -0.44 -4.05 -0.109 0.15144E+05 81 goethite 1.54 0.56 -0.98 -0.212 0.36658E+04 83 greenalite 5.46 1.73 -3.73 -0.311 0.13943E+05 84 grunerite 3.92 -0.74 -4.66 -0.126 0.17441E+05 85 halite -1.65 -3.72 -2.07 -1.034 0.77313E+04 86 hematite 1.53 1.13 -0.41 -0.050 0.15280E+04 87 heulandite -10.86 -14.24 -3.38 -0.154 0.12635E+05 88 hercynite -4.70 -6.15 -1.45 -0.097 0.54134E+04 91 jadeite -0.73 -2.44 -1.71 -0.171 0.63890E+04 93 kalsilite 0.21 -1.47 -1.68 -0.240 0.62798E+04 94 kaolinite -7.81 -10.56 -2.75 -0.250 0.10286E+05 95 kyanite -8.35 -9.12 -0.77 -0.077 0.28769E+04 97 laumontite -6.10 -9.92 -3.83 -0.255 0.14317E+05 98 lawsonite -3.33 -7.05 -3.72 -0.248 0.13919E+05 99 leucite -1.89 -2.90 -1.01 -0.101 0.37816E+04 101 lizardite 10.78 7.30 -3.48 -0.290 0.12996E+05 102 magnesite -5.52 -8.84 -3.32 -1.108 0.12432E+05 103 magnetite 3.19 2.66 -0.53 -0.044 0.19967E+04 104 minnesotaite 1.33 -1.14 -2.47 -0.145 0.92482E+04 105 minnesotaite-Mg 7.62 4.43 -3.19 -0.187 0.11915E+05 106 magnesioferrite 6.41 4.52 -1.89 -0.154 0.70553E+04 108 manganosite 5.86 3.51 -2.35 -0.588 0.88013E+04 109 margarite -12.55 -14.73 -2.18 -0.087 0.81662E+04 113 monticellite 9.54 5.47 -4.07 -0.582 0.15235E+05 115 mullite-Si -7.73 -9.12 -1.39 -0.139 0.51833E+04 116 muscovite -11.13 -12.02 -0.89 -0.052 0.33281E+04 117 paragonite -10.44 -11.56 -1.12 -0.066 0.41948E+04 118 nepheline 0.53 -1.00 -1.54 -0.219 0.57444E+04 119 osumilite(2) -10.23 -13.33 -3.10 -0.065 0.11595E+05 120 osumilite-Fe -23.60 -26.69 -3.09 -0.064 0.11544E+05 122 periclase 6.23 3.39 -2.83 -0.708 0.10591E+05 123 periclase-Fe 3.53 1.54 -2.00 -0.500 0.74736E+04 124 perovskite-Al -5.11 -7.68 -2.57 -0.234 0.96051E+04 129 phlogopite-Na 8.14 6.30 -1.84 -0.102 0.68816E+04 131 prehnite -1.24 -4.97 -3.73 -0.220 0.13953E+05 132 prehnite-Fe 3.22 -0.57 -3.79 -0.228 0.14167E+05 135 px-Mg-tschermaks -3.32 -5.73 -2.41 -0.172 0.90021E+04 136 px-Ca-tschermaks -2.70 -5.61 -2.91 -0.208 0.10899E+05 138 pyrrhotite -8.70 -9.49 -0.78 -0.261 0.29302E+04 139 pyrrhotiteFe0.875 -9.55 -9.92 -0.37 -0.137 0.13896E+04 140 pyrophyllite -11.98 -13.43 -1.45 -0.090 0.54052E+04 143 riebeckite 6.32 2.79 -3.53 -0.097 0.13189E+05 144 ringwoodite-Fe 4.01 1.63 -2.38 -0.340 0.88943E+04 146 rhodochrosite -5.61 -8.72 -3.11 -1.037 0.11635E+05 147 rhodonite 2.76 2.07 -0.69 -0.137 0.25648E+04 148 sanidine -3.79 -4.34 -0.55 -0.043 0.20689E+04 150 siderite -7.46 -10.70 -3.24 -1.080 0.12111E+05 151 sillimanite -8.47 -9.12 -0.65 -0.065 0.24126E+04 153 spinel -2.43 -4.29 -1.86 -0.124 0.69715E+04 160 stilpnomelane-Mg 3.38 -0.31 -3.69 -0.110 0.13802E+05 161 stishovite 1.59 -1.44 -3.03 -1.010 0.11331E+05 162 sudoite-Fe -11.80 -16.61 -4.81 -0.155 0.17986E+05 163 sudoite -9.43 -12.89 -3.47 -0.112 0.12973E+05 164 sulfur -11.48 -12.97 -1.48 -0.456 0.55432E+04 165 sylvite -1.56 -4.18 -2.63 -1.313 0.98179E+04 166 talc 5.85 4.43 -1.41 -0.083 0.52894E+04 167 talc-Fe 2.78 -1.14 -3.92 -0.231 0.14668E+05 168 talc-tschermaks -2.84 -5.21 -2.36 -0.139 0.88387E+04 170 tephroite 7.22 5.59 -1.64 -0.234 0.61159E+04 173 topaz-H -6.43 -9.12 -2.69 -0.245 0.10059E+05 174 tremolite 16.98 12.49 -4.48 -0.121 0.16767E+05 176 troilite-low -8.62 -9.49 -0.87 -0.290 0.32564E+04 177 tschermakite -2.08 -6.79 -4.71 -0.127 0.17614E+05 180 wadsleyite-Fe 3.87 1.63 -2.24 -0.320 0.83742E+04 181 wadsleyite-Mg 9.48 5.35 -4.13 -0.590 0.15452E+05 182 wairakite -7.98 -9.92 -1.94 -0.114 0.72627E+04 183 walstromite 4.80 2.07 -2.73 -0.546 0.10202E+05 184 wollastonite 4.36 2.07 -2.29 -0.458 0.85640E+04 185 pseudo-wollastonite 4.49 2.07 -2.41 -0.483 0.90291E+04 186 zoisite -5.72 -8.82 -3.10 -0.141 0.11574E+05 189 beidellite-Ca -11.81 -13.64 -1.83 -0.113 0.68430E+04 190 beidellite-H -11.88 -14.22 -2.34 -0.149 0.87551E+04 191 beidellite-K -10.85 -12.97 -2.12 -0.130 0.79290E+04 192 beidellite-Mg -12.04 -13.66 -1.63 -0.101 0.60806E+04 193 beidellite-Na -10.79 -12.81 -2.03 -0.124 0.75732E+04 194 bornite -56.84 -57.02 -0.18 -0.013 0.67151E+03 196 chalcocite -15.00 -16.42 -1.42 -0.354 0.52984E+04 197 covellite -13.38 -14.69 -1.31 -0.499 0.49002E+04 199 montmorillonite-Ca -9.00 -10.46 -1.47 -0.091 0.54793E+04 200 montmorillonite-K -8.30 -9.78 -1.48 -0.091 0.55489E+04 201 montmorillonite-Mg -9.19 -10.48 -1.29 -0.080 0.48362E+04 202 montmorillonite-Na -7.98 -9.63 -1.65 -0.101 0.61837E+04 203 nontronite-Ca -3.11 -4.84 -1.73 -0.112 0.64685E+04 204 nontronite-H -3.18 -5.42 -2.23 -0.150 0.83534E+04 205 nontronite-K -2.14 -4.16 -2.02 -0.130 0.75467E+04 206 nontronite-Mg -3.30 -4.86 -1.56 -0.101 0.58145E+04 207 nontronite-Na -2.08 -4.00 -1.93 -0.124 0.72027E+04 212 gypsum -13.01 -15.30 -2.28 -0.571 0.85346E+04 229 alabandite -6.43 -7.51 -1.08 -0.359 0.40265E+04 231 anglesite -15.68 -17.98 -2.30 -1.151 0.86082E+04 235 boehmite -2.66 -3.84 -1.18 -0.197 0.44119E+04 239 copper,native 1.68 -1.73 -3.41 -1.185 0.12739E+05 241 ferrous-oxide 2.59 1.54 -1.05 -0.263 0.39381E+04 242 galena -10.20 -10.20 -0.00 -0.001 0.13211E+02 243 silver,native 0.35 -4.03 -4.38 -1.523 0.16371E+05 245 litharge 5.52 0.82 -4.70 -1.176 0.17584E+05 253 wurtzite -10.22 -11.05 -0.83 -0.276 0.30913E+04 254 zincite 2.64 -0.03 -2.67 -0.668 0.99906E+04 255 an20ab80 -4.40 -4.51 -0.11 -0.009 0.41471E+03 256 an25ab75 -4.54 -4.67 -0.13 -0.010 0.46766E+03 257 an30ab70 -4.68 -4.83 -0.14 -0.011 0.54060E+03 258 tr.625ac.25prg.125 11.88 9.20 -2.68 -0.072 0.10014E+05 Calculations done for 544.0000 Deg. C; 879.0000 bar Temperature changed by -1.000 degrees to 543.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 58 Loop limit = 500 Temperature = 543.00 C Pressure = 868.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9935E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9970 Stoichiometric ionic strength = .3269512E+01 Osmotic coef. = 0.0000 True ionic strength = .1716201E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54498E-05 -5.2636 0.66931E-06 -6.1744 0.12281E+00 -0.9108 2 H2O 0.99704E+00 -0.0013 0.99704E+00 -0.0013 3 Cl- 0.14465E+00 -0.8397 0.13995E-01 -1.8540 0.96747E-01 -1.0144 4 SO4-- 0.11628E-02 -2.9345 0.31249E-06 -6.5052 0.26874E-03 -3.5707 5 HCO3- 0.73664E-05 -5.1327 0.78728E-06 -6.1039 0.10687E+00 -0.9711 6 HS- 0.13538E-03 -3.8684 0.13242E-04 -4.8780 0.97817E-01 -1.0096 7 H4SiO4 0.35611E-01 -1.4484 0.35611E-01 -1.4484 0.10000E+01 0.0000 8 Al+++ 0.81263E-14 -14.0901 0.51365E-22 -22.2893 0.63209E-08 -8.1992 9 Ca++ 0.76361E-05 -5.1171 0.15096E-08 -8.8211 0.19770E-03 -3.7040 10 Mg++ 0.72424E-05 -5.1401 0.10987E-08 -8.9591 0.15170E-03 -3.8190 11 Fe++ 0.10092E-06 -6.9960 0.16369E-10 -10.7860 0.16219E-03 -3.7900 12 K+ 0.39488E-01 -1.4035 0.43546E-02 -2.3611 0.11028E+00 -0.9575 13 Na+ 0.12943E+00 -0.8880 0.12689E-01 -1.8966 0.98037E-01 -1.0086 14 Mn++ 0.90700E-05 -5.0424 0.15449E-08 -8.8111 0.17034E-03 -3.7687 15 Zn++ 0.27478E-08 -8.5610 0.44567E-12 -12.3510 0.16219E-03 -3.7900 16 Cu+ 0.13557E-07 -7.8679 0.13243E-08 -8.8780 0.97689E-01 -1.0102 17 Pb++ 0.13167E-07 -7.8805 0.30395E-11 -11.5172 0.23085E-03 -3.6367 18 Ag+ 0.50328E-10 -10.2982 0.54324E-11 -11.2650 0.10794E+00 -0.9668 19 Ba++ 0.26703E-06 -6.5734 0.68020E-10 -10.1674 0.25473E-03 -3.5939 20 HPO4-- 0.82805E-08 -8.0819 0.22407E-11 -11.6496 0.27059E-03 -3.5677 21 HSiO3- 0.14771E-05 -5.8306 0.14290E-06 -6.8450 0.96747E-01 -1.0144 22 Ca(HSiO3)+ 0.47083E-08 -8.3271 0.52546E-09 -9.2795 0.11160E+00 -0.9523 23 Mg(HSiO3)+ 0.12549E-08 -8.9014 0.14005E-09 -9.8537 0.11160E+00 -0.9523 24 NaHSiO3,aq 0.17628E-05 -5.7538 0.17628E-05 -5.7538 0.10000E+01 0.0000 28 AgCl,aq 0.17914E-07 -7.7468 0.17914E-07 -7.7468 0.10000E+01 0.0000 29 AgCl2- 0.90595E-06 -6.0429 0.87648E-07 -7.0573 0.96747E-01 -1.0144 30 AgCl3-2 0.74278E-06 -6.1291 0.17962E-09 -9.7457 0.24182E-03 -3.6165 31 AgCl4-3 0.70891E-05 -5.1494 0.38061E-13 -13.4195 0.53690E-08 -8.2701 34 Ag(HS),aq 0.37501E-09 -9.4260 0.37501E-09 -9.4260 0.10000E+01 0.0000 35 Ag(HS)2- 0.12029E-08 -8.9198 0.11638E-09 -9.9341 0.96747E-01 -1.0144 36 AlO+ 0.28455E-10 -10.5458 0.31757E-11 -11.4982 0.11160E+00 -0.9523 38 HAlO2,aq 0.51583E-08 -8.2875 0.51583E-08 -8.2875 0.10000E+01 0.0000 39 AlO2- 0.14861E-04 -4.8280 0.12095E-05 -5.9174 0.81390E-01 -1.0894 41 Ba(HCO3)+ 0.14749E-06 -6.8312 0.17380E-07 -7.7599 0.11784E+00 -0.9287 42 BaCl+ 0.69464E-05 -5.1582 0.77524E-06 -6.1106 0.11160E+00 -0.9523 43 CH4,aq 0.12206E-08 -8.9134 0.14242E-08 -8.8464 0.11668E+01 0.0670 48 CO,aq 0.37603E-03 -3.4248 0.37603E-03 -3.4248 0.10000E+01 0.0000 49 CO2,aq 0.26730E+01 0.4270 0.31188E+01 0.4940 0.11668E+01 0.0670 50 CO3-2 0.14018E-09 -9.8533 0.33898E-13 -13.4698 0.24182E-03 -3.6165 52 Ca(HCO3)+ 0.68656E-07 -7.1633 0.76623E-08 -8.1156 0.11160E+00 -0.9523 53 CaCl+ 0.77107E-04 -4.1129 0.86055E-05 -5.0652 0.11160E+00 -0.9523 54 CaCl2,aq 0.63012E-04 -4.2006 0.63012E-04 -4.2006 0.10000E+01 0.0000 55 CaOH+ 0.13745E-06 -6.8619 0.15340E-07 -7.8142 0.11160E+00 -0.9523 56 CaSO4,aq 0.21019E-06 -6.6774 0.21019E-06 -6.6774 0.10000E+01 0.0000 57 HCl,aq 0.65224E-02 -2.1856 0.65224E-02 -2.1856 0.10000E+01 0.0000 66 CuCl,aq 0.18946E-04 -4.7225 0.18946E-04 -4.7225 0.10000E+01 0.0000 67 CuCl2- 0.80898E-04 -4.0921 0.78266E-05 -5.1064 0.96747E-01 -1.0144 68 CuCl3-2 0.37113E-05 -5.4305 0.89746E-09 -9.0470 0.24182E-03 -3.6165 74 FeCl+ 0.30103E-06 -6.5214 0.33596E-07 -7.4737 0.11160E+00 -0.9523 75 FeCl2,aq 0.17452E-02 -2.7582 0.17452E-02 -2.7582 0.10000E+01 0.0000 77 FeO,aq 0.40820E-07 -7.3891 0.40820E-07 -7.3891 0.10000E+01 0.0000 78 FeOH+ 0.23901E-07 -7.6216 0.26675E-08 -8.5739 0.11160E+00 -0.9523 79 HFeO2- 0.57811E-08 -8.2380 0.55930E-09 -9.2524 0.96747E-01 -1.0144 82 FeO2- 0.32419E-08 -8.4892 0.31364E-09 -9.5036 0.96747E-01 -1.0144 83 HFeO2,aq 0.27462E-09 -9.5613 0.27462E-09 -9.5613 0.10000E+01 0.0000 84 H2,aq 0.41426E-02 -2.3827 0.48335E-02 -2.3157 0.11668E+01 0.0670 85 KCl,aq 0.68833E-01 -1.1622 0.68833E-01 -1.1622 0.10000E+01 0.0000 86 KHSO4,aq 0.11390E-01 -1.9435 0.11390E-01 -1.9435 0.10000E+01 0.0000 87 KOH,aq 0.12641E-05 -5.8982 0.12641E-05 -5.8982 0.10000E+01 0.0000 88 KSO4- 0.58285E-02 -2.2344 0.56389E-03 -3.2488 0.96747E-01 -1.0144 90 Mg(HCO3)+ 0.14748E-07 -7.8313 0.16459E-08 -8.7836 0.11160E+00 -0.9523 91 MgCl+ 0.13103E-04 -4.8826 0.14623E-05 -5.8350 0.11160E+00 -0.9523 92 MgOH+ 0.44987E-06 -6.3469 0.50208E-07 -7.2992 0.11160E+00 -0.9523 94 MnO,aq 0.71570E-07 -7.1453 0.71570E-07 -7.1453 0.10000E+01 0.0000 95 MnOH+ 0.22669E-06 -6.6446 0.25300E-07 -7.5969 0.11160E+00 -0.9523 97 HMnO2- 0.35807E-10 -10.4460 0.34642E-11 -11.4604 0.96747E-01 -1.0144 100 MnCl+ 0.11474E-02 -2.9403 0.12805E-03 -3.8926 0.11160E+00 -0.9523 101 MnSO4,aq 0.20692E-06 -6.6842 0.20692E-06 -6.6842 0.10000E+01 0.0000 102 NaCl,aq 0.42876E+00 -0.3678 0.42876E+00 -0.3678 0.10000E+01 0.0000 103 NaOH,aq 0.16545E-05 -5.7813 0.16545E-05 -5.7813 0.10000E+01 0.0000 105 OH- 0.92926E-05 -5.0319 0.75632E-06 -6.1213 0.81390E-01 -1.0894 110 HPO3-2 0.32979E-10 -10.4818 0.79749E-14 -14.0983 0.24182E-03 -3.6165 111 H3PO3,aq 0.13967E-09 -9.8549 0.13967E-09 -9.8549 0.10000E+01 0.0000 112 H2PO3- 0.16524E-08 -8.7819 0.15987E-09 -9.7962 0.96747E-01 -1.0144 113 H3PO4,aq 0.22820E-05 -5.6417 0.22820E-05 -5.6417 0.10000E+01 0.0000 114 H2PO4- 0.19324E-05 -5.7139 0.19987E-06 -6.6992 0.10343E+00 -0.9853 116 H4P2O7,aq 0.50900E-09 -9.2933 0.50900E-09 -9.2933 0.10000E+01 0.0000 117 H3P2O7- 0.14970E-08 -8.8248 0.14483E-09 -9.8391 0.96747E-01 -1.0144 118 H2P2O7-2 0.89687E-06 -6.0473 0.21688E-09 -9.6638 0.24182E-03 -3.6165 119 HP2O7-3 0.13983E-05 -5.8544 0.75072E-14 -14.1245 0.53690E-08 -8.2701 120 P2O7-4 0.88421E-10 -10.0534 0.83188E-24 -24.0799 0.94082E-14 -14.0265 121 PbCl+ 0.11880E-05 -5.9252 0.13259E-06 -6.8775 0.11160E+00 -0.9523 122 PbCl2,aq 0.74006E-04 -4.1307 0.74006E-04 -4.1307 0.10000E+01 0.0000 123 PbCl3- 0.11076E-03 -3.9556 0.10716E-04 -4.9700 0.96747E-01 -1.0144 124 PbCl4-2 0.44806E-04 -4.3487 0.10835E-07 -7.9652 0.24182E-03 -3.6165 125 PbO,aq 0.58783E-08 -8.2307 0.58783E-08 -8.2307 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.97507E-04 -4.0110 0.97507E-04 -4.0110 0.10000E+01 0.0000 128 Pb(HS)3- 0.14094E-04 -4.8510 0.13635E-05 -5.8653 0.96747E-01 -1.0144 129 H2S,aq 0.10597E+01 0.0252 0.12364E+01 0.0922 0.11668E+01 0.0670 130 S2-2 0.39290E-07 -7.4057 0.95011E-11 -11.0222 0.24182E-03 -3.6165 131 S3-2 0.34694E-08 -8.4597 0.83895E-12 -12.0763 0.24182E-03 -3.6165 132 S3- 0.80140E-02 -2.0961 0.77533E-03 -3.1105 0.96747E-01 -1.0144 133 S4-2 0.26481E-09 -9.5771 0.64036E-13 -13.1936 0.24182E-03 -3.6165 134 S5-2 0.17831E-10 -10.7488 0.43119E-14 -14.3653 0.24182E-03 -3.6165 135 SO2,aq 0.29333E+00 -0.5326 0.29333E+00 -0.5326 0.10000E+01 0.0000 136 SO3-2 0.23898E-08 -8.6216 0.10906E-11 -11.9623 0.45637E-03 -3.3407 137 HSO3- 0.23333E-03 -3.6320 0.22574E-04 -4.6464 0.96747E-01 -1.0144 138 HSO4- 0.87594E-02 -2.0575 0.10157E-02 -2.9933 0.11595E+00 -0.9357 140 S2O3-2 0.19809E-05 -5.7031 0.47901E-09 -9.3197 0.24182E-03 -3.6165 141 HS2O3- 0.36592E-06 -6.4366 0.35402E-07 -7.4510 0.96747E-01 -1.0144 142 H2S2O3,aq 0.47136E-07 -7.3266 0.47136E-07 -7.3266 0.10000E+01 0.0000 150 S4O6-2 0.14204E-08 -8.8476 0.34347E-12 -12.4641 0.24182E-03 -3.6165 152 ZnCl+ 0.13255E-03 -3.8776 0.14793E-04 -4.8299 0.11160E+00 -0.9523 153 ZnCl2,aq 0.47203E-03 -3.3260 0.47203E-03 -3.3260 0.10000E+01 0.0000 154 ZnCl3- 0.31920E-04 -4.4959 0.30881E-05 -5.5103 0.96747E-01 -1.0144 155 ZnO,aq 0.22153E-07 -7.6546 0.22153E-07 -7.6546 0.10000E+01 0.0000 156 ZnOH+ 0.97327E-06 -6.0118 0.10862E-06 -6.9641 0.11160E+00 -0.9523 158 HZnO2- 0.20668E-09 -9.6847 0.19995E-10 -10.6991 0.96747E-01 -1.0144 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5449765E-05 0.4293028E+01 0.3544790E+04 0.0000 2 H2O 0.1000000E+01 0.5252571E+02 0.7751852E+06 0.0000 3 Cl- 0.1446539E+00 0.6556923E+00 0.1904343E+05 4.3203 4 SO4-- 0.1162827E-02 0.2511938E+00 0.1976746E+05 5.8436 5 HCO3- 0.7366399E-05 0.2673366E+01 0.1336296E+06 0.0705 6 HS- 0.1353796E-03 0.1153579E+01 0.3125360E+05 1.2963 7 H4SiO4 0.3561095E-01 0.3561420E-01 0.2804195E+04 -1.4484 8 Al+++ 0.8126270E-14 0.1486595E-04 0.3285873E+00 -3.7662 9 Ca++ 0.7636056E-05 0.1481757E-03 0.4864913E+01 3.5276 10 Mg++ 0.7242416E-05 0.2081096E-04 0.4144812E+00 3.3896 11 Fe++ 0.1009231E-06 0.1745691E-02 0.7986551E+02 1.5628 12 K+ 0.3948787E-01 0.1255406E+00 0.4021380E+04 3.8133 13 Na+ 0.1294339E+00 0.5582018E+00 0.1051280E+05 4.2778 14 Mn++ 0.9070002E-05 0.1156967E-02 0.5206978E+02 3.5377 15 Zn++ 0.2747788E-08 0.6374996E-03 0.3413897E+02 -0.0022 16 Cu+ 0.1355651E-07 0.1035679E-03 0.5390942E+01 -2.7036 17 Pb++ 0.1316679E-07 0.3423823E-03 0.5811284E+02 0.8315 18 Ag+ 0.5032823E-10 0.8757359E-05 0.7738663E+00 -5.0906 19 Ba++ 0.2670312E-06 0.7360881E-05 0.8281689E+00 2.1814 20 HPO4-- 0.8280550E-08 0.8818978E-05 0.6934044E+00 0.6991 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265323E+01 -.2960485E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5218672E+02 -.2219444E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2495727E+00 0.2150067E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1146135E+01 0.1400961E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3538436E-01 0.1082100E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1477001E-04 0.6797695E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1472194E-03 0.3806905E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1734425E-02 0.7032329E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247304E+00 0.6797695E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.6333853E-03 0.1665949E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1028996E-03 0.2967102E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7313376E-05 0.4805908E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8762064E-05 -.1945633E-06 0.0000000E+00 Chg. balance for solid moles: 0.8566E-18 Mass of aqueous solution: 0.121282E+04 g Temperature = 543.00 C Pressure = 868.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3810E-03 -3.419 0.5187E-01 -1.285 0.6775 0.1751E-01 apatite-OH -.6485E-07 1.000 -.3258E-04 1.000 -.4255E-03 -.1035E-04 microcline 0.6798E-03 -3.168 0.1892 -0.723 2.471 0.7391E-01 pyrite 0.6736E-02 -2.172 0.8081 -0.093 10.56 0.1612 quartz 0.1062 -0.974 6.379 0.805 83.32 2.409 barite 0.4806E-04 -4.318 0.1122E-01 -1.950 0.1465 0.2504E-02 chalcopyrite 0.2967E-03 -3.528 0.5445E-01 -1.264 0.7112 0.1271E-01 sphalerite 0.1666E-02 -2.778 0.1623 -0.790 2.120 0.3970E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.655895 g Volume = 2.716441 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.33 -15.33 0.00 0.000 0.00000E+00 112 microcline -4.29 -4.29 -0.00 -0.000 0.66339E-11 137 pyrite -22.49 -22.49 0.00 0.000 0.00000E+00 141 quartz -1.45 -1.45 0.00 0.000 0.00000E+00 234 barite -16.67 -16.67 0.00 0.000 0.00000E+00 237 chalcopyrite -24.22 -24.22 -0.00 -0.000 0.13268E-10 252 sphalerite -11.05 -11.05 -0.00 -0.000 0.66339E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.250 0.93179E+03 2.689 2 CO2,gas -10.49 -12.28 -1.78 -0.595 0.66660E+04 1.154 3 CH4,gas 6.75 -4.48 -11.23 -2.808 0.41950E+05 -8.294 4 H2,gas 6.06 1.95 -4.12 -2.352 0.15368E+05 -1.177 5 H2S,gas -8.73 -11.05 -2.32 -1.159 0.86574E+04 0.620 6 CO,gas -4.10 -10.33 -6.23 -1.916 0.23258E+05 -3.289 7 SO3,gas -7.98 -18.85 -10.87 -2.718 0.40605E+05 -7.934 8 O2,gas 17.23 -3.90 -21.13 -14.090 0.78928E+05 -18.196 9 HCl,gas -6.35 -8.03 -1.68 -0.840 0.62723E+04 -1.680 10 acmite 3.66 1.97 -1.69 -0.175 0.63023E+04 12 akimotoite 6.62 1.94 -4.67 -0.935 0.17456E+05 13 akimotoite-Fe 4.40 0.12 -4.29 -0.858 0.16016E+05 14 albite-high -3.65 -3.83 -0.18 -0.014 0.68224E+03 15 albite -3.66 -3.83 -0.17 -0.013 0.62561E+03 16 almandine -4.74 -7.19 -2.45 -0.123 0.91658E+04 17 pyrope 2.29 -1.71 -4.00 -0.200 0.14923E+05 18 analcite -1.36 -2.38 -1.03 -0.114 0.38375E+04 19 andalusite -8.38 -8.98 -0.61 -0.061 0.22656E+04 24 anorthite -5.92 -6.90 -0.99 -0.076 0.36803E+04 25 anthophyllite 16.89 12.15 -4.74 -0.128 0.17697E+05 26 anthophyllite-Fe 3.46 -0.64 -4.10 -0.111 0.15294E+05 27 apatite-OH -54.36 -54.36 0.00 0.000 0.00000E+00 28 apatite-OH-zs -52.11 -54.36 -2.25 -0.173 0.83945E+04 29 apatite-Cl-zs -59.07 -62.39 -3.32 -0.276 0.12391E+05 30 aragonite -4.86 -8.75 -3.89 -1.298 0.14541E+05 31 brucite 6.02 3.39 -2.64 -0.528 0.98504E+04 32 calcite -4.97 -8.75 -3.78 -1.261 0.14124E+05 33 carnegieite-low 0.91 -0.94 -1.85 -0.264 0.69041E+04 34 carnegieite-high 1.01 -0.94 -1.95 -0.278 0.72664E+04 35 carpholite-Mg -4.63 -7.04 -2.42 -0.161 0.90261E+04 36 carpholite-Fe -6.07 -8.87 -2.80 -0.187 0.10459E+05 37 celadonite 0.12 -2.35 -2.47 -0.146 0.92421E+04 38 celadonite-Fe -1.36 -4.18 -2.82 -0.166 0.10526E+05 39 chrysotile 10.71 7.27 -3.44 -0.287 0.12843E+05 41 clinochlore 8.14 5.06 -3.08 -0.096 0.11497E+05 42 daphnite 0.62 -4.07 -4.70 -0.147 0.17540E+05 45 chloritoid-Mg -3.84 -5.60 -1.75 -0.117 0.65444E+04 46 chloritoid-Fe -5.91 -7.42 -1.51 -0.101 0.56344E+04 47 chloritoid-Mn -3.78 -5.45 -1.66 -0.111 0.62096E+04 49 coesite -1.14 -1.45 -0.30 -0.100 0.11244E+04 50 cordierite-H -13.72 -15.53 -1.81 -0.065 0.67448E+04 51 cordierite-Fe -16.52 -19.18 -2.66 -0.092 0.99295E+04 52 cordierite-Mn -12.20 -15.23 -3.03 -0.104 0.11315E+05 53 corundum -6.74 -7.54 -0.79 -0.072 0.29566E+04 55 cristobalite -1.40 -1.45 -0.05 -0.016 0.18200E+03 56 cummingtonite 16.96 12.15 -4.81 -0.130 0.17974E+05 58 cymrite-K -1.90 -4.29 -2.39 -0.199 0.89281E+04 60 diaspore -2.90 -3.77 -0.87 -0.145 0.32542E+04 62 diopside 5.93 4.02 -1.91 -0.191 0.71188E+04 63 hedenbergite 4.42 2.20 -2.22 -0.222 0.82877E+04 65 eastonite -1.49 -3.61 -2.12 -0.082 0.79217E+04 66 enstatite 5.50 3.88 -1.62 -0.162 0.60405E+04 67 clinoenstatite-HiP 6.01 3.88 -2.13 -0.213 0.79513E+04 68 clinoenstatite 5.48 3.88 -1.60 -0.160 0.59618E+04 69 protoenstatite 5.64 3.88 -1.76 -0.176 0.65596E+04 70 epidote -1.43 -4.24 -2.81 -0.136 0.10493E+05 71 clinozoisite -5.43 -8.59 -3.16 -0.143 0.11786E+05 72 epidote-Fe 4.30 0.12 -4.18 -0.217 0.15624E+05 73 fayalite 3.05 1.68 -1.37 -0.196 0.51323E+04 74 ferrosilite 1.71 0.23 -1.48 -0.148 0.55150E+04 75 forsterite 7.27 5.33 -1.94 -0.277 0.72379E+04 76 gedrite -2.70 -6.81 -4.11 -0.111 0.15337E+05 78 gibbsite -1.26 -3.77 -2.51 -0.359 0.93735E+04 79 glaucophane 3.78 -0.38 -4.17 -0.113 0.15565E+05 81 goethite 1.57 0.59 -0.98 -0.212 0.36650E+04 83 greenalite 5.52 1.79 -3.73 -0.311 0.13948E+05 84 grunerite 4.05 -0.64 -4.68 -0.127 0.17488E+05 85 halite -1.68 -3.75 -2.07 -1.035 0.77325E+04 86 hematite 1.58 1.17 -0.41 -0.050 0.15332E+04 87 heulandite -10.75 -14.14 -3.39 -0.154 0.12657E+05 88 hercynite -4.52 -5.97 -1.46 -0.097 0.54370E+04 91 jadeite -0.67 -2.38 -1.71 -0.171 0.63895E+04 93 kalsilite 0.28 -1.40 -1.68 -0.240 0.62812E+04 94 kaolinite -7.68 -10.43 -2.75 -0.250 0.10275E+05 95 kyanite -8.21 -8.98 -0.77 -0.077 0.28915E+04 97 laumontite -5.96 -9.80 -3.84 -0.256 0.14326E+05 98 lawsonite -3.17 -6.90 -3.73 -0.249 0.13929E+05 99 leucite -1.83 -2.85 -1.01 -0.101 0.37860E+04 101 lizardite 10.86 7.27 -3.59 -0.299 0.13407E+05 102 magnesite -5.52 -8.89 -3.37 -1.124 0.12592E+05 103 magnetite 3.27 2.73 -0.54 -0.044 0.20105E+04 104 minnesotaite 1.38 -1.10 -2.48 -0.146 0.92601E+04 105 minnesotaite-Mg 7.68 4.38 -3.30 -0.194 0.12336E+05 106 magnesioferrite 6.49 4.56 -1.93 -0.158 0.72062E+04 108 manganosite 5.89 3.54 -2.36 -0.589 0.88050E+04 109 margarite -12.24 -14.44 -2.20 -0.088 0.81992E+04 113 monticellite 9.59 5.47 -4.12 -0.589 0.15391E+05 115 mullite-Si -7.59 -8.98 -1.39 -0.139 0.52002E+04 116 muscovite -10.94 -11.83 -0.89 -0.053 0.33363E+04 117 paragonite -10.24 -11.37 -1.13 -0.066 0.42040E+04 118 nepheline 0.60 -0.94 -1.54 -0.220 0.57466E+04 119 osumilite(2) -10.00 -13.23 -3.23 -0.067 0.12052E+05 120 osumilite-Fe -23.26 -26.36 -3.11 -0.065 0.11596E+05 122 periclase 6.26 3.39 -2.87 -0.719 0.10735E+05 123 periclase-Fe 3.57 1.56 -2.00 -0.501 0.74827E+04 124 perovskite-Al -4.96 -7.54 -2.58 -0.234 0.96200E+04 129 phlogopite-Na 8.29 6.34 -1.96 -0.109 0.73105E+04 131 prehnite -1.08 -4.82 -3.74 -0.220 0.13982E+05 132 prehnite-Fe 3.33 -0.47 -3.80 -0.229 0.14192E+05 135 px-Mg-tschermaks -3.14 -5.59 -2.45 -0.175 0.91642E+04 136 px-Ca-tschermaks -2.53 -5.46 -2.93 -0.209 0.10925E+05 138 pyrrhotite -8.70 -9.49 -0.79 -0.262 0.29387E+04 139 pyrrhotiteFe0.875 -9.55 -9.93 -0.37 -0.138 0.13974E+04 140 pyrophyllite -11.87 -13.32 -1.45 -0.091 0.54108E+04 143 riebeckite 6.38 2.84 -3.53 -0.097 0.13199E+05 144 ringwoodite-Fe 4.06 1.68 -2.39 -0.341 0.89089E+04 146 rhodochrosite -5.62 -8.74 -3.12 -1.040 0.11653E+05 147 rhodonite 2.78 2.09 -0.69 -0.138 0.25686E+04 148 sanidine -3.74 -4.29 -0.55 -0.043 0.20690E+04 150 siderite -7.47 -10.72 -3.25 -1.083 0.12133E+05 151 sillimanite -8.33 -8.98 -0.65 -0.065 0.24285E+04 153 spinel -2.24 -4.15 -1.91 -0.127 0.71305E+04 160 stilpnomelane-Mg 3.62 -0.26 -3.89 -0.116 0.14511E+05 161 stishovite 1.59 -1.45 -3.03 -1.011 0.11330E+05 162 sudoite-Fe -11.47 -16.29 -4.82 -0.156 0.18019E+05 163 sudoite -9.08 -12.64 -3.56 -0.115 0.13279E+05 164 sulfur -11.52 -13.00 -1.48 -0.457 0.55439E+04 165 sylvite -1.59 -4.22 -2.63 -1.314 0.98154E+04 166 talc 5.91 4.38 -1.53 -0.090 0.57115E+04 167 talc-Fe 2.83 -1.10 -3.93 -0.231 0.14681E+05 168 talc-tschermaks -2.65 -5.10 -2.45 -0.144 0.91322E+04 170 tephroite 7.27 5.63 -1.64 -0.234 0.61215E+04 173 topaz-H -6.29 -8.98 -2.69 -0.245 0.10062E+05 174 tremolite 17.11 12.43 -4.69 -0.127 0.17502E+05 176 troilite-low -8.62 -9.49 -0.87 -0.291 0.32642E+04 177 tschermakite -1.69 -6.53 -4.84 -0.131 0.18089E+05 180 wadsleyite-Fe 3.92 1.68 -2.25 -0.321 0.83904E+04 181 wadsleyite-Mg 9.55 5.33 -4.22 -0.602 0.15742E+05 182 wairakite -7.85 -9.80 -1.95 -0.115 0.72787E+04 183 walstromite 4.82 2.08 -2.73 -0.547 0.10213E+05 184 wollastonite 4.38 2.08 -2.30 -0.459 0.85746E+04 185 pseudo-wollastonite 4.50 2.08 -2.42 -0.484 0.90408E+04 186 zoisite -5.48 -8.59 -3.11 -0.141 0.11617E+05 189 beidellite-Ca -11.67 -13.51 -1.83 -0.114 0.68528E+04 190 beidellite-H -11.74 -14.09 -2.35 -0.150 0.87615E+04 191 beidellite-K -10.70 -12.83 -2.12 -0.130 0.79344E+04 192 beidellite-Mg -11.89 -13.53 -1.64 -0.101 0.61140E+04 193 beidellite-Na -10.65 -12.68 -2.03 -0.124 0.75792E+04 194 bornite -56.96 -57.14 -0.18 -0.013 0.66054E+03 196 chalcocite -15.04 -16.46 -1.42 -0.354 0.52891E+04 197 covellite -13.42 -14.73 -1.31 -0.499 0.48910E+04 199 montmorillonite-Ca -8.90 -10.38 -1.48 -0.092 0.55323E+04 200 montmorillonite-K -8.20 -9.70 -1.50 -0.092 0.56001E+04 201 montmorillonite-Mg -9.09 -10.40 -1.31 -0.081 0.49099E+04 202 montmorillonite-Na -7.88 -9.55 -1.67 -0.102 0.62320E+04 203 nontronite-Ca -3.06 -4.80 -1.73 -0.112 0.64708E+04 204 nontronite-H -3.14 -5.38 -2.24 -0.150 0.83527E+04 205 nontronite-K -2.10 -4.12 -2.02 -0.130 0.75446E+04 206 nontronite-Mg -3.26 -4.82 -1.56 -0.101 0.58386E+04 207 nontronite-Na -2.04 -3.97 -1.93 -0.124 0.72008E+04 212 gypsum -13.04 -15.33 -2.28 -0.571 0.85305E+04 229 alabandite -6.43 -7.51 -1.08 -0.360 0.40332E+04 231 anglesite -15.72 -18.02 -2.30 -1.151 0.85946E+04 235 boehmite -2.59 -3.77 -1.18 -0.197 0.44153E+04 239 copper,native 1.68 -1.73 -3.41 -1.185 0.12729E+05 241 ferrous-oxide 2.62 1.56 -1.06 -0.264 0.39482E+04 242 galena -10.22 -10.22 -0.00 -0.001 0.10541E+02 243 silver,native 0.34 -4.12 -4.46 -1.551 0.16652E+05 245 litharge 5.54 0.83 -4.71 -1.177 0.17577E+05 253 wurtzite -10.23 -11.05 -0.83 -0.276 0.30915E+04 254 zincite 2.67 -0.00 -2.67 -0.669 0.99899E+04 255 an20ab80 -4.33 -4.44 -0.11 -0.009 0.42443E+03 256 an25ab75 -4.47 -4.60 -0.13 -0.010 0.47795E+03 257 an30ab70 -4.60 -4.75 -0.15 -0.011 0.55235E+03 258 tr.625ac.25prg.125 12.03 9.20 -2.83 -0.076 0.10576E+05 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 36 Loop limit = 500 Temperature = 543.00 C Pressure = 868.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9935E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9970 Stoichiometric ionic strength = .3269512E+01 Osmotic coef. = 0.0000 True ionic strength = .1716195E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54497E-05 -5.2636 0.66931E-06 -6.1744 0.12281E+00 -0.9107 2 H2O 0.99704E+00 -0.0013 0.99704E+00 -0.0013 3 Cl- 0.14465E+00 -0.8397 0.13995E-01 -1.8540 0.96747E-01 -1.0144 4 SO4-- 0.11628E-02 -2.9345 0.31250E-06 -6.5052 0.26874E-03 -3.5707 5 HCO3- 0.73664E-05 -5.1327 0.78728E-06 -6.1039 0.10687E+00 -0.9711 6 HS- 0.13538E-03 -3.8684 0.13242E-04 -4.8780 0.97817E-01 -1.0096 7 H4SiO4 0.35611E-01 -1.4484 0.35611E-01 -1.4484 0.10000E+01 0.0000 8 Al+++ 0.81260E-14 -14.0901 0.51365E-22 -22.2893 0.63210E-08 -8.1992 9 Ca++ 0.76359E-05 -5.1171 0.15096E-08 -8.8211 0.19770E-03 -3.7040 10 Mg++ 0.72424E-05 -5.1401 0.10987E-08 -8.9591 0.15170E-03 -3.8190 11 Fe++ 0.10092E-06 -6.9960 0.16369E-10 -10.7860 0.16220E-03 -3.7900 12 K+ 0.39488E-01 -1.4035 0.43546E-02 -2.3611 0.11028E+00 -0.9575 13 Na+ 0.12943E+00 -0.8880 0.12689E-01 -1.8966 0.98038E-01 -1.0086 14 Mn++ 0.90699E-05 -5.0424 0.15449E-08 -8.8111 0.17034E-03 -3.7687 15 Zn++ 0.27477E-08 -8.5610 0.44567E-12 -12.3510 0.16220E-03 -3.7900 16 Cu+ 0.13556E-07 -7.8679 0.13243E-08 -8.8780 0.97689E-01 -1.0102 17 Pb++ 0.13167E-07 -7.8805 0.30395E-11 -11.5172 0.23085E-03 -3.6367 18 Ag+ 0.50329E-10 -10.2982 0.54325E-11 -11.2650 0.10794E+00 -0.9668 19 Ba++ 0.26703E-06 -6.5734 0.68020E-10 -10.1674 0.25473E-03 -3.5939 20 HPO4-- 0.81591E-08 -8.0884 0.22078E-11 -11.6560 0.27059E-03 -3.5677 21 HSiO3- 0.14771E-05 -5.8306 0.14291E-06 -6.8450 0.96747E-01 -1.0144 22 Ca(HSiO3)+ 0.47082E-08 -8.3271 0.52546E-09 -9.2795 0.11160E+00 -0.9523 23 Mg(HSiO3)+ 0.12549E-08 -8.9014 0.14005E-09 -9.8537 0.11160E+00 -0.9523 24 NaHSiO3,aq 0.17628E-05 -5.7538 0.17628E-05 -5.7538 0.10000E+01 0.0000 28 AgCl,aq 0.17915E-07 -7.7468 0.17915E-07 -7.7468 0.10000E+01 0.0000 29 AgCl2- 0.90597E-06 -6.0429 0.87649E-07 -7.0573 0.96747E-01 -1.0144 30 AgCl3-2 0.74279E-06 -6.1291 0.17962E-09 -9.7456 0.24182E-03 -3.6165 31 AgCl4-3 0.70891E-05 -5.1494 0.38062E-13 -13.4195 0.53691E-08 -8.2701 34 Ag(HS),aq 0.37502E-09 -9.4259 0.37502E-09 -9.4259 0.10000E+01 0.0000 35 Ag(HS)2- 0.12030E-08 -8.9197 0.11638E-09 -9.9341 0.96747E-01 -1.0144 36 AlO+ 0.28455E-10 -10.5458 0.31757E-11 -11.4982 0.11160E+00 -0.9523 38 HAlO2,aq 0.51583E-08 -8.2875 0.51583E-08 -8.2875 0.10000E+01 0.0000 39 AlO2- 0.14861E-04 -4.8280 0.12095E-05 -5.9174 0.81390E-01 -1.0894 41 Ba(HCO3)+ 0.14749E-06 -6.8312 0.17380E-07 -7.7599 0.11784E+00 -0.9287 42 BaCl+ 0.69463E-05 -5.1582 0.77523E-06 -6.1106 0.11160E+00 -0.9523 43 CH4,aq 0.12206E-08 -8.9134 0.14242E-08 -8.8464 0.11668E+01 0.0670 48 CO,aq 0.37603E-03 -3.4248 0.37603E-03 -3.4248 0.10000E+01 0.0000 49 CO2,aq 0.26730E+01 0.4270 0.31188E+01 0.4940 0.11668E+01 0.0670 50 CO3-2 0.14018E-09 -9.8533 0.33898E-13 -13.4698 0.24182E-03 -3.6165 52 Ca(HCO3)+ 0.68655E-07 -7.1633 0.76622E-08 -8.1156 0.11160E+00 -0.9523 53 CaCl+ 0.77106E-04 -4.1129 0.86054E-05 -5.0652 0.11160E+00 -0.9523 54 CaCl2,aq 0.63011E-04 -4.2006 0.63011E-04 -4.2006 0.10000E+01 0.0000 55 CaOH+ 0.13745E-06 -6.8619 0.15340E-07 -7.8142 0.11160E+00 -0.9523 56 CaSO4,aq 0.21019E-06 -6.6774 0.21019E-06 -6.6774 0.10000E+01 0.0000 57 HCl,aq 0.65224E-02 -2.1856 0.65224E-02 -2.1856 0.10000E+01 0.0000 66 CuCl,aq 0.18945E-04 -4.7225 0.18945E-04 -4.7225 0.10000E+01 0.0000 67 CuCl2- 0.80897E-04 -4.0921 0.78265E-05 -5.1064 0.96747E-01 -1.0144 68 CuCl3-2 0.37113E-05 -5.4305 0.89746E-09 -9.0470 0.24182E-03 -3.6165 74 FeCl+ 0.30103E-06 -6.5214 0.33596E-07 -7.4737 0.11160E+00 -0.9523 75 FeCl2,aq 0.17452E-02 -2.7582 0.17452E-02 -2.7582 0.10000E+01 0.0000 77 FeO,aq 0.40820E-07 -7.3891 0.40820E-07 -7.3891 0.10000E+01 0.0000 78 FeOH+ 0.23901E-07 -7.6216 0.26675E-08 -8.5739 0.11160E+00 -0.9523 79 HFeO2- 0.57811E-08 -8.2380 0.55930E-09 -9.2524 0.96747E-01 -1.0144 82 FeO2- 0.32419E-08 -8.4892 0.31364E-09 -9.5036 0.96747E-01 -1.0144 83 HFeO2,aq 0.27462E-09 -9.5613 0.27462E-09 -9.5613 0.10000E+01 0.0000 84 H2,aq 0.41426E-02 -2.3827 0.48335E-02 -2.3157 0.11668E+01 0.0670 85 KCl,aq 0.68833E-01 -1.1622 0.68833E-01 -1.1622 0.10000E+01 0.0000 86 KHSO4,aq 0.11390E-01 -1.9435 0.11390E-01 -1.9435 0.10000E+01 0.0000 87 KOH,aq 0.12641E-05 -5.8982 0.12641E-05 -5.8982 0.10000E+01 0.0000 88 KSO4- 0.58285E-02 -2.2344 0.56389E-03 -3.2488 0.96747E-01 -1.0144 90 Mg(HCO3)+ 0.14748E-07 -7.8313 0.16459E-08 -8.7836 0.11160E+00 -0.9523 91 MgCl+ 0.13103E-04 -4.8826 0.14623E-05 -5.8350 0.11160E+00 -0.9523 92 MgOH+ 0.44988E-06 -6.3469 0.50208E-07 -7.2992 0.11160E+00 -0.9523 94 MnO,aq 0.71571E-07 -7.1453 0.71571E-07 -7.1453 0.10000E+01 0.0000 95 MnOH+ 0.22669E-06 -6.6446 0.25300E-07 -7.5969 0.11160E+00 -0.9523 97 HMnO2- 0.35807E-10 -10.4460 0.34642E-11 -11.4604 0.96747E-01 -1.0144 100 MnCl+ 0.11474E-02 -2.9403 0.12805E-03 -3.8926 0.11160E+00 -0.9523 101 MnSO4,aq 0.20692E-06 -6.6842 0.20692E-06 -6.6842 0.10000E+01 0.0000 102 NaCl,aq 0.42876E+00 -0.3678 0.42876E+00 -0.3678 0.10000E+01 0.0000 103 NaOH,aq 0.16545E-05 -5.7813 0.16545E-05 -5.7813 0.10000E+01 0.0000 105 OH- 0.92926E-05 -5.0319 0.75632E-06 -6.1213 0.81390E-01 -1.0894 110 HPO3-2 0.32495E-10 -10.4882 0.78580E-14 -14.1047 0.24182E-03 -3.6165 111 H3PO3,aq 0.13762E-09 -9.8613 0.13762E-09 -9.8613 0.10000E+01 0.0000 112 H2PO3- 0.16282E-08 -8.7883 0.15752E-09 -9.8027 0.96747E-01 -1.0144 113 H3PO4,aq 0.22486E-05 -5.6481 0.22486E-05 -5.6481 0.10000E+01 0.0000 114 H2PO4- 0.19041E-05 -5.7203 0.19694E-06 -6.7057 0.10343E+00 -0.9853 116 H4P2O7,aq 0.49418E-09 -9.3061 0.49418E-09 -9.3061 0.10000E+01 0.0000 117 H3P2O7- 0.14534E-08 -8.8376 0.14061E-09 -9.8520 0.96747E-01 -1.0144 118 H2P2O7-2 0.87074E-06 -6.0601 0.21056E-09 -9.6766 0.24182E-03 -3.6165 119 HP2O7-3 0.13575E-05 -5.8673 0.72886E-14 -14.1374 0.53691E-08 -8.2701 120 P2O7-4 0.85844E-10 -10.0663 0.80766E-24 -24.0928 0.94085E-14 -14.0265 121 PbCl+ 0.11880E-05 -5.9252 0.13259E-06 -6.8775 0.11160E+00 -0.9523 122 PbCl2,aq 0.74006E-04 -4.1307 0.74006E-04 -4.1307 0.10000E+01 0.0000 123 PbCl3- 0.11076E-03 -3.9556 0.10716E-04 -4.9700 0.96747E-01 -1.0144 124 PbCl4-2 0.44805E-04 -4.3487 0.10835E-07 -7.9652 0.24182E-03 -3.6165 125 PbO,aq 0.58784E-08 -8.2307 0.58784E-08 -8.2307 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.97508E-04 -4.0110 0.97508E-04 -4.0110 0.10000E+01 0.0000 128 Pb(HS)3- 0.14094E-04 -4.8510 0.13635E-05 -5.8653 0.96747E-01 -1.0144 129 H2S,aq 0.10597E+01 0.0252 0.12364E+01 0.0922 0.11668E+01 0.0670 130 S2-2 0.39290E-07 -7.4057 0.95011E-11 -11.0222 0.24182E-03 -3.6165 131 S3-2 0.34694E-08 -8.4597 0.83896E-12 -12.0763 0.24182E-03 -3.6165 132 S3- 0.80140E-02 -2.0961 0.77533E-03 -3.1105 0.96747E-01 -1.0144 133 S4-2 0.26481E-09 -9.5771 0.64036E-13 -13.1936 0.24182E-03 -3.6165 134 S5-2 0.17831E-10 -10.7488 0.43119E-14 -14.3653 0.24182E-03 -3.6165 135 SO2,aq 0.29333E+00 -0.5326 0.29333E+00 -0.5326 0.10000E+01 0.0000 136 SO3-2 0.23898E-08 -8.6216 0.10906E-11 -11.9623 0.45637E-03 -3.3407 137 HSO3- 0.23333E-03 -3.6320 0.22574E-04 -4.6464 0.96747E-01 -1.0144 138 HSO4- 0.87595E-02 -2.0575 0.10157E-02 -2.9933 0.11595E+00 -0.9357 140 S2O3-2 0.19809E-05 -5.7031 0.47902E-09 -9.3196 0.24182E-03 -3.6165 141 HS2O3- 0.36592E-06 -6.4366 0.35402E-07 -7.4510 0.96747E-01 -1.0144 142 H2S2O3,aq 0.47136E-07 -7.3266 0.47136E-07 -7.3266 0.10000E+01 0.0000 150 S4O6-2 0.14204E-08 -8.8476 0.34347E-12 -12.4641 0.24182E-03 -3.6165 152 ZnCl+ 0.13255E-03 -3.8776 0.14793E-04 -4.8299 0.11160E+00 -0.9523 153 ZnCl2,aq 0.47203E-03 -3.3260 0.47203E-03 -3.3260 0.10000E+01 0.0000 154 ZnCl3- 0.31920E-04 -4.4959 0.30881E-05 -5.5103 0.96747E-01 -1.0144 155 ZnO,aq 0.22153E-07 -7.6546 0.22153E-07 -7.6546 0.10000E+01 0.0000 156 ZnOH+ 0.97327E-06 -6.0118 0.10862E-06 -6.9641 0.11160E+00 -0.9523 158 HZnO2- 0.20668E-09 -9.6847 0.19995E-10 -10.6991 0.96747E-01 -1.0144 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5449735E-05 0.4293029E+01 0.3544790E+04 -0.0000 2 H2O 0.1000000E+01 0.5252571E+02 0.7751852E+06 0.0000 3 Cl- 0.1446537E+00 0.6556923E+00 0.1904343E+05 4.3203 4 SO4-- 0.1162827E-02 0.2511942E+00 0.1976749E+05 5.8436 5 HCO3- 0.7366408E-05 0.2673366E+01 0.1336296E+06 0.0705 6 HS- 0.1353797E-03 0.1153579E+01 0.3125360E+05 1.2963 7 H4SiO4 0.3561095E-01 0.3561420E-01 0.2804195E+04 -1.4484 8 Al+++ 0.8126000E-14 0.1486591E-04 0.3285865E+00 -3.7662 9 Ca++ 0.7635925E-05 0.1481743E-03 0.4864869E+01 3.5276 10 Mg++ 0.7242378E-05 0.2081096E-04 0.4144812E+00 3.3896 11 Fe++ 0.1009215E-06 0.1745681E-02 0.7986504E+02 1.5628 12 K+ 0.3948777E-01 0.1255406E+00 0.4021380E+04 3.8133 13 Na+ 0.1294336E+00 0.5582018E+00 0.1051280E+05 4.2778 14 Mn++ 0.9069932E-05 0.1156967E-02 0.5206978E+02 3.5377 15 Zn++ 0.2747743E-08 0.6374955E-03 0.3413876E+02 -0.0022 16 Cu+ 0.1355644E-07 0.1035675E-03 0.5390918E+01 -2.7036 17 Pb++ 0.1316665E-07 0.3423823E-03 0.5811284E+02 0.8315 18 Ag+ 0.5032887E-10 0.8757359E-05 0.7738663E+00 -5.0906 19 Ba++ 0.2670268E-06 0.7360807E-05 0.8281606E+00 2.1814 20 HPO4-- 0.8159054E-08 0.8623151E-05 0.6780072E+00 0.6927 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265323E+01 -.2960746E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5218672E+02 -.2219444E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2495730E+00 0.2149747E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1146135E+01 0.1400964E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3538436E-01 0.1082100E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1476997E-04 0.6797696E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1472181E-03 0.3806918E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1734415E-02 0.7032339E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247304E+00 0.6797696E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.6333813E-03 0.1665953E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1028991E-03 0.2967106E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7313303E-05 0.4805915E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1572E-17 Mass of aqueous solution: 0.121282E+04 g Temperature = 543.00 C Pressure = 868.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3807E-03 -3.419 0.5183E-01 -1.285 0.6770 0.1749E-01 microcline 0.6798E-03 -3.168 0.1892 -0.723 2.471 0.7391E-01 pyrite 0.6736E-02 -2.172 0.8081 -0.093 10.56 0.1612 quartz 0.1062 -0.974 6.379 0.805 83.32 2.409 barite 0.4806E-04 -4.318 0.1122E-01 -1.950 0.1465 0.2504E-02 chalcopyrite 0.2967E-03 -3.528 0.5445E-01 -1.264 0.7112 0.1271E-01 sphalerite 0.1666E-02 -2.778 0.1623 -0.790 2.120 0.3970E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.655886 g Volume = 2.716437 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.33 -15.33 0.00 0.000 0.00000E+00 112 microcline -4.29 -4.29 -0.00 -0.000 0.66339E-11 137 pyrite -22.49 -22.49 -0.00 -0.000 0.26536E-10 141 quartz -1.45 -1.45 0.00 0.000 0.00000E+00 234 barite -16.67 -16.67 -0.00 -0.000 0.13268E-10 237 chalcopyrite -24.22 -24.22 0.00 0.000 0.00000E+00 252 sphalerite -11.05 -11.05 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.250 0.93179E+03 2.689 2 CO2,gas -10.49 -12.28 -1.78 -0.595 0.66660E+04 1.154 3 CH4,gas 6.75 -4.48 -11.23 -2.808 0.41950E+05 -8.294 4 H2,gas 6.06 1.95 -4.12 -2.352 0.15368E+05 -1.177 5 H2S,gas -8.73 -11.05 -2.32 -1.159 0.86574E+04 0.620 6 CO,gas -4.10 -10.33 -6.23 -1.916 0.23258E+05 -3.289 7 SO3,gas -7.98 -18.85 -10.87 -2.718 0.40605E+05 -7.934 8 O2,gas 17.23 -3.90 -21.13 -14.090 0.78928E+05 -18.196 9 HCl,gas -6.35 -8.03 -1.68 -0.840 0.62723E+04 -1.680 10 acmite 3.66 1.97 -1.69 -0.175 0.63023E+04 12 akimotoite 6.62 1.94 -4.67 -0.935 0.17456E+05 13 akimotoite-Fe 4.40 0.12 -4.29 -0.858 0.16016E+05 14 albite-high -3.65 -3.83 -0.18 -0.014 0.68224E+03 15 albite -3.66 -3.83 -0.17 -0.013 0.62561E+03 16 almandine -4.74 -7.19 -2.45 -0.123 0.91658E+04 17 pyrope 2.29 -1.71 -4.00 -0.200 0.14923E+05 18 analcite -1.36 -2.38 -1.03 -0.114 0.38375E+04 19 andalusite -8.38 -8.98 -0.61 -0.061 0.22656E+04 24 anorthite -5.92 -6.90 -0.99 -0.076 0.36803E+04 25 anthophyllite 16.89 12.15 -4.74 -0.128 0.17697E+05 26 anthophyllite-Fe 3.46 -0.64 -4.10 -0.111 0.15294E+05 27 apatite-OH -54.36 -54.38 -0.02 -0.001 0.71925E+02 28 apatite-OH-zs -52.11 -54.38 -2.27 -0.174 0.84664E+04 29 apatite-Cl-zs -59.07 -62.40 -3.34 -0.278 0.12463E+05 30 aragonite -4.86 -8.75 -3.89 -1.298 0.14541E+05 31 brucite 6.02 3.39 -2.64 -0.528 0.98504E+04 32 calcite -4.97 -8.75 -3.78 -1.261 0.14124E+05 33 carnegieite-low 0.91 -0.94 -1.85 -0.264 0.69041E+04 34 carnegieite-high 1.01 -0.94 -1.95 -0.278 0.72664E+04 35 carpholite-Mg -4.63 -7.04 -2.42 -0.161 0.90260E+04 36 carpholite-Fe -6.07 -8.87 -2.80 -0.187 0.10459E+05 37 celadonite 0.12 -2.35 -2.47 -0.146 0.92421E+04 38 celadonite-Fe -1.36 -4.18 -2.82 -0.166 0.10526E+05 39 chrysotile 10.71 7.27 -3.44 -0.287 0.12843E+05 41 clinochlore 8.14 5.06 -3.08 -0.096 0.11496E+05 42 daphnite 0.62 -4.07 -4.70 -0.147 0.17540E+05 45 chloritoid-Mg -3.84 -5.60 -1.75 -0.117 0.65444E+04 46 chloritoid-Fe -5.91 -7.42 -1.51 -0.101 0.56344E+04 47 chloritoid-Mn -3.78 -5.45 -1.66 -0.111 0.62096E+04 49 coesite -1.14 -1.45 -0.30 -0.100 0.11244E+04 50 cordierite-H -13.72 -15.53 -1.81 -0.065 0.67448E+04 51 cordierite-Fe -16.52 -19.18 -2.66 -0.092 0.99295E+04 52 cordierite-Mn -12.20 -15.23 -3.03 -0.104 0.11315E+05 53 corundum -6.74 -7.54 -0.79 -0.072 0.29566E+04 55 cristobalite -1.40 -1.45 -0.05 -0.016 0.18200E+03 56 cummingtonite 16.96 12.15 -4.81 -0.130 0.17974E+05 58 cymrite-K -1.90 -4.29 -2.39 -0.199 0.89281E+04 60 diaspore -2.90 -3.77 -0.87 -0.145 0.32542E+04 62 diopside 5.93 4.02 -1.91 -0.191 0.71188E+04 63 hedenbergite 4.42 2.20 -2.22 -0.222 0.82877E+04 65 eastonite -1.49 -3.61 -2.12 -0.082 0.79217E+04 66 enstatite 5.50 3.88 -1.62 -0.162 0.60404E+04 67 clinoenstatite-HiP 6.01 3.88 -2.13 -0.213 0.79513E+04 68 clinoenstatite 5.48 3.88 -1.60 -0.160 0.59618E+04 69 protoenstatite 5.64 3.88 -1.76 -0.176 0.65595E+04 70 epidote -1.43 -4.24 -2.81 -0.136 0.10493E+05 71 clinozoisite -5.43 -8.59 -3.16 -0.143 0.11786E+05 72 epidote-Fe 4.30 0.12 -4.18 -0.217 0.15624E+05 73 fayalite 3.05 1.68 -1.37 -0.196 0.51323E+04 74 ferrosilite 1.71 0.23 -1.48 -0.148 0.55150E+04 75 forsterite 7.27 5.33 -1.94 -0.277 0.72379E+04 76 gedrite -2.70 -6.81 -4.11 -0.111 0.15337E+05 78 gibbsite -1.26 -3.77 -2.51 -0.359 0.93736E+04 79 glaucophane 3.78 -0.38 -4.17 -0.113 0.15565E+05 81 goethite 1.57 0.59 -0.98 -0.212 0.36650E+04 83 greenalite 5.52 1.79 -3.73 -0.311 0.13948E+05 84 grunerite 4.05 -0.64 -4.68 -0.127 0.17488E+05 85 halite -1.68 -3.75 -2.07 -1.035 0.77325E+04 86 hematite 1.58 1.17 -0.41 -0.050 0.15332E+04 87 heulandite -10.75 -14.14 -3.39 -0.154 0.12657E+05 88 hercynite -4.52 -5.97 -1.46 -0.097 0.54371E+04 91 jadeite -0.67 -2.38 -1.71 -0.171 0.63895E+04 93 kalsilite 0.28 -1.40 -1.68 -0.240 0.62812E+04 94 kaolinite -7.68 -10.43 -2.75 -0.250 0.10275E+05 95 kyanite -8.21 -8.98 -0.77 -0.077 0.28915E+04 97 laumontite -5.96 -9.80 -3.84 -0.256 0.14326E+05 98 lawsonite -3.17 -6.90 -3.73 -0.249 0.13929E+05 99 leucite -1.83 -2.85 -1.01 -0.101 0.37860E+04 101 lizardite 10.86 7.27 -3.59 -0.299 0.13407E+05 102 magnesite -5.52 -8.89 -3.37 -1.124 0.12592E+05 103 magnetite 3.27 2.73 -0.54 -0.044 0.20105E+04 104 minnesotaite 1.38 -1.10 -2.48 -0.146 0.92601E+04 105 minnesotaite-Mg 7.68 4.38 -3.30 -0.194 0.12336E+05 106 magnesioferrite 6.49 4.56 -1.93 -0.158 0.72062E+04 108 manganosite 5.89 3.54 -2.36 -0.589 0.88050E+04 109 margarite -12.24 -14.44 -2.20 -0.088 0.81992E+04 113 monticellite 9.59 5.47 -4.12 -0.589 0.15391E+05 115 mullite-Si -7.59 -8.98 -1.39 -0.139 0.52002E+04 116 muscovite -10.94 -11.83 -0.89 -0.053 0.33363E+04 117 paragonite -10.24 -11.37 -1.13 -0.066 0.42040E+04 118 nepheline 0.60 -0.94 -1.54 -0.220 0.57466E+04 119 osumilite(2) -10.00 -13.23 -3.23 -0.067 0.12052E+05 120 osumilite-Fe -23.26 -26.36 -3.11 -0.065 0.11596E+05 122 periclase 6.26 3.39 -2.87 -0.719 0.10735E+05 123 periclase-Fe 3.57 1.56 -2.00 -0.501 0.74827E+04 124 perovskite-Al -4.96 -7.54 -2.58 -0.234 0.96200E+04 129 phlogopite-Na 8.29 6.34 -1.96 -0.109 0.73105E+04 131 prehnite -1.08 -4.82 -3.74 -0.220 0.13982E+05 132 prehnite-Fe 3.33 -0.47 -3.80 -0.229 0.14192E+05 135 px-Mg-tschermaks -3.14 -5.59 -2.45 -0.175 0.91642E+04 136 px-Ca-tschermaks -2.53 -5.46 -2.93 -0.209 0.10925E+05 138 pyrrhotite -8.70 -9.49 -0.79 -0.262 0.29387E+04 139 pyrrhotiteFe0.875 -9.55 -9.93 -0.37 -0.138 0.13974E+04 140 pyrophyllite -11.87 -13.32 -1.45 -0.091 0.54109E+04 143 riebeckite 6.38 2.84 -3.53 -0.097 0.13199E+05 144 ringwoodite-Fe 4.06 1.68 -2.39 -0.341 0.89089E+04 146 rhodochrosite -5.62 -8.74 -3.12 -1.040 0.11653E+05 147 rhodonite 2.78 2.09 -0.69 -0.138 0.25685E+04 148 sanidine -3.74 -4.29 -0.55 -0.043 0.20690E+04 150 siderite -7.47 -10.72 -3.25 -1.083 0.12133E+05 151 sillimanite -8.33 -8.98 -0.65 -0.065 0.24285E+04 153 spinel -2.24 -4.15 -1.91 -0.127 0.71305E+04 160 stilpnomelane-Mg 3.62 -0.26 -3.89 -0.116 0.14511E+05 161 stishovite 1.59 -1.45 -3.03 -1.011 0.11330E+05 162 sudoite-Fe -11.47 -16.29 -4.82 -0.156 0.18019E+05 163 sudoite -9.08 -12.64 -3.56 -0.115 0.13279E+05 164 sulfur -11.52 -13.00 -1.48 -0.457 0.55439E+04 165 sylvite -1.59 -4.22 -2.63 -1.314 0.98154E+04 166 talc 5.91 4.38 -1.53 -0.090 0.57115E+04 167 talc-Fe 2.83 -1.10 -3.93 -0.231 0.14681E+05 168 talc-tschermaks -2.65 -5.10 -2.45 -0.144 0.91322E+04 170 tephroite 7.27 5.63 -1.64 -0.234 0.61215E+04 173 topaz-H -6.29 -8.98 -2.69 -0.245 0.10062E+05 174 tremolite 17.11 12.43 -4.69 -0.127 0.17502E+05 176 troilite-low -8.62 -9.49 -0.87 -0.291 0.32642E+04 177 tschermakite -1.69 -6.53 -4.84 -0.131 0.18089E+05 180 wadsleyite-Fe 3.92 1.68 -2.25 -0.321 0.83904E+04 181 wadsleyite-Mg 9.55 5.33 -4.22 -0.602 0.15742E+05 182 wairakite -7.85 -9.80 -1.95 -0.115 0.72787E+04 183 walstromite 4.82 2.08 -2.73 -0.547 0.10213E+05 184 wollastonite 4.38 2.08 -2.30 -0.459 0.85746E+04 185 pseudo-wollastonite 4.50 2.08 -2.42 -0.484 0.90408E+04 186 zoisite -5.48 -8.59 -3.11 -0.141 0.11617E+05 189 beidellite-Ca -11.67 -13.51 -1.83 -0.114 0.68528E+04 190 beidellite-H -11.74 -14.09 -2.35 -0.150 0.87615E+04 191 beidellite-K -10.70 -12.83 -2.12 -0.130 0.79344E+04 192 beidellite-Mg -11.89 -13.53 -1.64 -0.101 0.61140E+04 193 beidellite-Na -10.65 -12.68 -2.03 -0.124 0.75792E+04 194 bornite -56.96 -57.14 -0.18 -0.013 0.66054E+03 196 chalcocite -15.04 -16.46 -1.42 -0.354 0.52891E+04 197 covellite -13.42 -14.73 -1.31 -0.499 0.48910E+04 199 montmorillonite-Ca -8.90 -10.38 -1.48 -0.092 0.55323E+04 200 montmorillonite-K -8.20 -9.70 -1.50 -0.092 0.56001E+04 201 montmorillonite-Mg -9.09 -10.40 -1.31 -0.081 0.49099E+04 202 montmorillonite-Na -7.88 -9.55 -1.67 -0.102 0.62320E+04 203 nontronite-Ca -3.06 -4.80 -1.73 -0.112 0.64709E+04 204 nontronite-H -3.14 -5.38 -2.24 -0.150 0.83527E+04 205 nontronite-K -2.10 -4.12 -2.02 -0.130 0.75446E+04 206 nontronite-Mg -3.26 -4.82 -1.56 -0.101 0.58386E+04 207 nontronite-Na -2.04 -3.97 -1.93 -0.124 0.72008E+04 212 gypsum -13.04 -15.33 -2.28 -0.571 0.85305E+04 229 alabandite -6.43 -7.51 -1.08 -0.360 0.40332E+04 231 anglesite -15.72 -18.02 -2.30 -1.151 0.85946E+04 235 boehmite -2.59 -3.77 -1.18 -0.197 0.44153E+04 239 copper,native 1.68 -1.73 -3.41 -1.185 0.12729E+05 241 ferrous-oxide 2.62 1.56 -1.06 -0.264 0.39482E+04 242 galena -10.22 -10.22 -0.00 -0.001 0.10532E+02 243 silver,native 0.34 -4.12 -4.46 -1.551 0.16652E+05 245 litharge 5.54 0.83 -4.71 -1.177 0.17577E+05 253 wurtzite -10.23 -11.05 -0.83 -0.276 0.30915E+04 254 zincite 2.67 -0.00 -2.67 -0.669 0.99899E+04 255 an20ab80 -4.33 -4.44 -0.11 -0.009 0.42444E+03 256 an25ab75 -4.47 -4.60 -0.13 -0.010 0.47795E+03 257 an30ab70 -4.60 -4.75 -0.15 -0.011 0.55236E+03 258 tr.625ac.25prg.125 12.03 9.20 -2.83 -0.076 0.10576E+05 Calculations done for 543.0000 Deg. C; 868.0000 bar Temperature changed by -1.000 degrees to 542.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 60 Loop limit = 500 Temperature = 542.00 C Pressure = 858.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9936E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9970 Stoichiometric ionic strength = .3269223E+01 Osmotic coef. = 0.0000 True ionic strength = .1733013E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54842E-05 -5.2609 0.65008E-06 -6.1870 0.11854E+00 -0.9261 2 H2O 0.99705E+00 -0.0013 0.99705E+00 -0.0013 3 Cl- 0.14593E+00 -0.8359 0.13551E-01 -1.8680 0.92863E-01 -1.0322 4 SO4-- 0.12963E-02 -2.8873 0.30126E-06 -6.5211 0.23239E-03 -3.6338 5 HCO3- 0.72517E-05 -5.1396 0.74527E-06 -6.1277 0.10277E+00 -0.9881 6 HS- 0.13699E-03 -3.8633 0.12864E-04 -4.8906 0.93909E-01 -1.0273 7 H4SiO4 0.34902E-01 -1.4571 0.34902E-01 -1.4571 0.10000E+01 0.0000 8 Al+++ 0.12214E-13 -13.9132 0.55117E-22 -22.2587 0.45127E-08 -8.3456 9 Ca++ 0.86487E-05 -5.0630 0.14697E-08 -8.8328 0.16993E-03 -3.7697 10 Mg++ 0.78195E-05 -5.1068 0.10146E-08 -8.9937 0.12976E-03 -3.8869 11 Fe++ 0.11696E-06 -6.9320 0.16246E-10 -10.7893 0.13890E-03 -3.8573 12 K+ 0.39755E-01 -1.4006 0.42179E-02 -2.3749 0.10610E+00 -0.9743 13 Na+ 0.13070E+00 -0.8837 0.12301E-01 -1.9100 0.94117E-01 -1.0263 14 Mn++ 0.10454E-04 -4.9807 0.15264E-08 -8.8163 0.14601E-03 -3.8356 15 Zn++ 0.31884E-08 -8.4964 0.44287E-12 -12.3537 0.13890E-03 -3.8573 16 Cu+ 0.13566E-07 -7.8675 0.12722E-08 -8.8955 0.93776E-01 -1.0279 17 Pb++ 0.14625E-07 -7.8349 0.29105E-11 -11.5360 0.19900E-03 -3.7011 18 Ag+ 0.41800E-10 -10.3788 0.43391E-11 -11.3626 0.10381E+00 -0.9838 19 Ba++ 0.29442E-06 -6.5310 0.64773E-10 -10.1886 0.22000E-03 -3.6576 20 HPO4-- 0.85292E-08 -8.0691 0.19961E-11 -11.6998 0.23403E-03 -3.6307 21 HSiO3- 0.14926E-05 -5.8261 0.13861E-06 -6.8582 0.92863E-01 -1.0322 22 Ca(HSiO3)+ 0.47469E-08 -8.3236 0.50981E-09 -9.2926 0.10740E+00 -0.9690 23 Mg(HSiO3)+ 0.12119E-08 -8.9165 0.13015E-09 -9.8855 0.10740E+00 -0.9690 24 NaHSiO3,aq 0.17612E-05 -5.7542 0.17612E-05 -5.7542 0.10000E+01 0.0000 28 AgCl,aq 0.14778E-07 -7.8304 0.14778E-07 -7.8304 0.10000E+01 0.0000 29 AgCl2- 0.75165E-06 -6.1240 0.69801E-07 -7.1561 0.92863E-01 -1.0322 30 AgCl3-2 0.65410E-06 -6.1844 0.13651E-09 -9.8648 0.20870E-03 -3.6805 31 AgCl4-3 0.73353E-05 -5.1346 0.28056E-13 -13.5520 0.38248E-08 -8.4174 34 Ag(HS),aq 0.31371E-09 -9.5035 0.31371E-09 -9.5035 0.10000E+01 0.0000 35 Ag(HS)2- 0.99922E-09 -9.0003 0.92791E-10 -10.0325 0.92863E-01 -1.0322 36 AlO+ 0.30526E-10 -10.5153 0.32785E-11 -11.4843 0.10740E+00 -0.9690 38 HAlO2,aq 0.52242E-08 -8.2820 0.52242E-08 -8.2820 0.10000E+01 0.0000 39 AlO2- 0.15193E-04 -4.8183 0.11833E-05 -5.9269 0.77884E-01 -1.1085 41 Ba(HCO3)+ 0.14433E-06 -6.8407 0.16383E-07 -7.7856 0.11351E+00 -0.9449 42 BaCl+ 0.68746E-05 -5.1628 0.73833E-06 -6.1318 0.10740E+00 -0.9690 43 CH4,aq 0.12089E-08 -8.9176 0.14086E-08 -8.8512 0.11652E+01 0.0664 48 CO,aq 0.36980E-03 -3.4320 0.36980E-03 -3.4320 0.10000E+01 0.0000 49 CO2,aq 0.26729E+01 0.4270 0.31145E+01 0.4934 0.11652E+01 0.0664 50 CO3-2 0.15434E-09 -9.8115 0.32210E-13 -13.4920 0.20870E-03 -3.6805 52 Ca(HCO3)+ 0.67047E-07 -7.1736 0.72008E-08 -8.1426 0.10740E+00 -0.9690 53 CaCl+ 0.77396E-04 -4.1113 0.83123E-05 -5.0803 0.10740E+00 -0.9690 54 CaCl2,aq 0.62155E-04 -4.2065 0.62155E-04 -4.2065 0.10000E+01 0.0000 55 CaOH+ 0.13788E-06 -6.8605 0.14808E-07 -7.8295 0.10740E+00 -0.9690 56 CaSO4,aq 0.21303E-06 -6.6716 0.21303E-06 -6.6716 0.10000E+01 0.0000 57 HCl,aq 0.68532E-02 -2.1641 0.68532E-02 -2.1641 0.10000E+01 0.0000 66 CuCl,aq 0.18769E-04 -4.7266 0.18769E-04 -4.7266 0.10000E+01 0.0000 67 CuCl2- 0.81275E-04 -4.0900 0.75474E-05 -5.1222 0.92863E-01 -1.0322 68 CuCl3-2 0.39610E-05 -5.4022 0.82667E-09 -9.0827 0.20870E-03 -3.6805 74 FeCl+ 0.30784E-06 -6.5117 0.33061E-07 -7.4807 0.10740E+00 -0.9690 75 FeCl2,aq 0.16958E-02 -2.7706 0.16958E-02 -2.7706 0.10000E+01 0.0000 77 FeO,aq 0.40303E-07 -7.3947 0.40303E-07 -7.3947 0.10000E+01 0.0000 78 FeOH+ 0.24449E-07 -7.6117 0.26258E-08 -8.5807 0.10740E+00 -0.9690 79 HFeO2- 0.58451E-08 -8.2332 0.54279E-09 -9.2654 0.92863E-01 -1.0322 82 FeO2- 0.32350E-08 -8.4901 0.30042E-09 -9.5223 0.92863E-01 -1.0322 83 HFeO2,aq 0.27639E-09 -9.5585 0.27639E-09 -9.5585 0.10000E+01 0.0000 84 H2,aq 0.41374E-02 -2.3833 0.48208E-02 -2.3169 0.11652E+01 0.0664 85 KCl,aq 0.68605E-01 -1.1636 0.68605E-01 -1.1636 0.10000E+01 0.0000 86 KHSO4,aq 0.11264E-01 -1.9483 0.11264E-01 -1.9483 0.10000E+01 0.0000 87 KOH,aq 0.12608E-05 -5.8993 0.12608E-05 -5.8993 0.10000E+01 0.0000 88 KSO4- 0.59139E-02 -2.2281 0.54918E-03 -3.2603 0.92863E-01 -1.0322 90 Mg(HCO3)+ 0.13509E-07 -7.8694 0.14509E-08 -8.8384 0.10740E+00 -0.9690 91 MgCl+ 0.12547E-04 -4.9015 0.13475E-05 -5.8705 0.10740E+00 -0.9690 92 MgOH+ 0.42978E-06 -6.3668 0.46158E-07 -7.3358 0.10740E+00 -0.9690 94 MnO,aq 0.70756E-07 -7.1502 0.70756E-07 -7.1502 0.10000E+01 0.0000 95 MnOH+ 0.22914E-06 -6.6399 0.24610E-07 -7.6089 0.10740E+00 -0.9690 97 HMnO2- 0.35925E-10 -10.4446 0.33361E-11 -11.4768 0.92863E-01 -1.0322 100 MnCl+ 0.11460E-02 -2.9408 0.12308E-03 -3.9098 0.10740E+00 -0.9690 101 MnSO4,aq 0.21069E-06 -6.6763 0.21069E-06 -6.6763 0.10000E+01 0.0000 102 NaCl,aq 0.42748E+00 -0.3691 0.42748E+00 -0.3691 0.10000E+01 0.0000 103 NaOH,aq 0.16492E-05 -5.7827 0.16492E-05 -5.7827 0.10000E+01 0.0000 105 OH- 0.95075E-05 -5.0219 0.74049E-06 -6.1305 0.77884E-01 -1.1085 110 HPO3-2 0.32741E-10 -10.4849 0.68331E-14 -14.1654 0.20870E-03 -3.6805 111 H3PO3,aq 0.12867E-09 -9.8905 0.12867E-09 -9.8905 0.10000E+01 0.0000 112 H2PO3- 0.14913E-08 -8.8264 0.13848E-09 -9.8586 0.92863E-01 -1.0322 113 H3PO4,aq 0.21391E-05 -5.6698 0.21391E-05 -5.6698 0.10000E+01 0.0000 114 H2PO4- 0.17920E-05 -5.7467 0.17813E-06 -6.7493 0.99402E-01 -1.0026 116 H4P2O7,aq 0.45001E-09 -9.3468 0.45001E-09 -9.3468 0.10000E+01 0.0000 117 H3P2O7- 0.12732E-08 -8.8951 0.11823E-09 -9.9273 0.92863E-01 -1.0322 118 H2P2O7-2 0.81334E-06 -6.0897 0.16974E-09 -9.7702 0.20870E-03 -3.6805 119 HP2O7-3 0.15256E-05 -5.8165 0.58352E-14 -14.2339 0.38248E-08 -8.4174 120 P2O7-4 0.12740E-09 -9.8948 0.67338E-24 -24.1717 0.52857E-14 -14.2769 121 PbCl+ 0.11809E-05 -5.9278 0.12683E-06 -6.8968 0.10740E+00 -0.9690 122 PbCl2,aq 0.72943E-04 -4.1370 0.72943E-04 -4.1370 0.10000E+01 0.0000 123 PbCl3- 0.11106E-03 -3.9544 0.10314E-04 -4.9866 0.92863E-01 -1.0322 124 PbCl4-2 0.47537E-04 -4.3230 0.99209E-08 -8.0034 0.20870E-03 -3.6805 125 PbO,aq 0.58434E-08 -8.2333 0.58434E-08 -8.2333 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.95553E-04 -4.0198 0.95553E-04 -4.0198 0.10000E+01 0.0000 128 Pb(HS)3- 0.14079E-04 -4.8514 0.13075E-05 -5.8836 0.92863E-01 -1.0322 129 H2S,aq 0.10599E+01 0.0252 0.12349E+01 0.0916 0.11652E+01 0.0664 130 S2-2 0.42595E-07 -7.3706 0.88895E-11 -11.0511 0.20870E-03 -3.6805 131 S3-2 0.37342E-08 -8.4278 0.77932E-12 -12.1083 0.20870E-03 -3.6805 132 S3- 0.78874E-02 -2.1031 0.73245E-03 -3.1352 0.92863E-01 -1.0322 133 S4-2 0.28329E-09 -9.5478 0.59123E-13 -13.2282 0.20870E-03 -3.6805 134 S5-2 0.18962E-10 -10.7221 0.39575E-14 -14.4026 0.20870E-03 -3.6805 135 SO2,aq 0.29324E+00 -0.5328 0.29324E+00 -0.5328 0.10000E+01 0.0000 136 SO3-2 0.26255E-08 -8.5808 0.10466E-11 -11.9802 0.39864E-03 -3.3994 137 HSO3- 0.23266E-03 -3.6333 0.21605E-04 -4.6654 0.92863E-01 -1.0322 138 HSO4- 0.87905E-02 -2.0560 0.98162E-03 -3.0081 0.11167E+00 -0.9521 140 S2O3-2 0.21687E-05 -5.6638 0.45261E-09 -9.3443 0.20870E-03 -3.6805 141 HS2O3- 0.36461E-06 -6.4382 0.33859E-07 -7.4703 0.92863E-01 -1.0322 142 H2S2O3,aq 0.47971E-07 -7.3190 0.47971E-07 -7.3190 0.10000E+01 0.0000 150 S4O6-2 0.15261E-08 -8.8164 0.31849E-12 -12.4969 0.20870E-03 -3.6805 152 ZnCl+ 0.13160E-03 -3.8808 0.14133E-04 -4.8498 0.10740E+00 -0.9690 153 ZnCl2,aq 0.46396E-03 -3.3335 0.46396E-03 -3.3335 0.10000E+01 0.0000 154 ZnCl3- 0.31277E-04 -4.5048 0.29044E-05 -5.5369 0.92863E-01 -1.0322 155 ZnO,aq 0.21945E-07 -7.6587 0.21945E-07 -7.6587 0.10000E+01 0.0000 156 ZnOH+ 0.97441E-06 -6.0113 0.10465E-06 -6.9803 0.10740E+00 -0.9690 158 HZnO2- 0.20995E-09 -9.6779 0.19496E-10 -10.7100 0.92863E-01 -1.0322 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5484201E-05 0.4292941E+01 0.3544930E+04 0.0000 2 H2O 0.1000000E+01 0.5252616E+02 0.7752382E+06 0.0000 3 Cl- 0.1459295E+00 0.6556796E+00 0.1904420E+05 4.3190 4 SO4-- 0.1296324E-02 0.2511773E+00 0.1976734E+05 5.8530 5 HCO3- 0.7251725E-05 0.2673314E+01 0.1336350E+06 0.0593 6 HS- 0.1369873E-03 0.1153461E+01 0.3125226E+05 1.2964 7 H4SiO4 0.3490209E-01 0.3490535E-01 0.2748546E+04 -1.4571 8 Al+++ 0.1221369E-13 0.1519849E-04 0.3359578E+00 -3.6976 9 Ca++ 0.8648727E-05 0.1486224E-03 0.4879872E+01 3.5413 10 Mg++ 0.7819462E-05 0.2081056E-04 0.4144980E+00 3.3804 11 Fe++ 0.1169579E-06 0.1696316E-02 0.7761125E+02 1.5848 12 K+ 0.3975489E-01 0.1255385E+00 0.4021553E+04 3.8121 13 Na+ 0.1307042E+00 0.5581910E+00 0.1051323E+05 4.2770 14 Mn++ 0.1045434E-04 0.1156944E-02 0.5207189E+02 3.5577 15 Zn++ 0.3188354E-08 0.6278298E-03 0.3362315E+02 0.0203 16 Cu+ 0.1356599E-07 0.1040185E-03 0.5414716E+01 -2.7084 17 Pb++ 0.1462532E-07 0.3423756E-03 0.5811519E+02 0.8380 18 Ag+ 0.4179960E-10 0.8757189E-05 0.7738975E+00 -5.1756 19 Ba++ 0.2944220E-06 0.7313368E-05 0.8228724E+00 2.1855 20 HPO4-- 0.8529209E-08 0.8622984E-05 0.6780346E+00 0.6742 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265318E+01 -.2956255E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5218818E+02 -.2234015E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2495611E+00 0.2161655E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1146039E+01 0.1410494E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3468076E-01 0.1089136E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1510070E-04 0.6794388E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1476661E-03 0.3802438E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1685401E-02 0.7081352E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247307E+00 0.6794388E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.6237901E-03 0.1675545E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1033492E-03 0.2962605E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7266311E-05 0.4810614E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.5014E-18 Mass of aqueous solution: 0.121277E+04 g Temperature = 542.00 C Pressure = 858.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3802E-03 -3.420 0.5177E-01 -1.286 0.6719 0.1747E-01 microcline 0.6794E-03 -3.168 0.1891 -0.723 2.454 0.7387E-01 pyrite 0.6785E-02 -2.168 0.8141 -0.089 10.57 0.1624 quartz 0.1069 -0.971 6.421 0.808 83.34 2.425 barite 0.4811E-04 -4.318 0.1123E-01 -1.950 0.1457 0.2506E-02 chalcopyrite 0.2963E-03 -3.528 0.5436E-01 -1.265 0.7056 0.1269E-01 sphalerite 0.1676E-02 -2.776 0.1632 -0.787 2.119 0.3992E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.704862 g Volume = 2.733763 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.35 -15.35 -0.00 -0.000 0.13252E-10 112 microcline -4.25 -4.25 0.00 0.000 -0.66258E-11 137 pyrite -22.52 -22.52 0.00 0.000 0.00000E+00 141 quartz -1.45 -1.45 -0.00 -0.000 0.82822E-12 234 barite -16.71 -16.71 0.00 0.000 0.00000E+00 237 chalcopyrite -24.26 -24.26 0.00 0.000 0.00000E+00 252 sphalerite -11.06 -11.06 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.249 0.92779E+03 2.685 2 CO2,gas -10.52 -12.31 -1.79 -0.597 0.66859E+04 1.141 3 CH4,gas 6.75 -4.50 -11.25 -2.812 0.41952E+05 -8.314 4 H2,gas 6.07 1.95 -4.12 -2.353 0.15359E+05 -1.184 5 H2S,gas -8.76 -11.08 -2.32 -1.160 0.86544E+04 0.613 6 CO,gas -4.12 -10.36 -6.24 -1.920 0.23281E+05 -3.308 7 SO3,gas -8.01 -18.89 -10.89 -2.722 0.40606E+05 -7.953 8 O2,gas 17.25 -3.91 -21.16 -14.108 0.78933E+05 -18.228 9 HCl,gas -6.37 -8.06 -1.69 -0.845 0.63038E+04 -1.690 10 acmite 3.67 1.97 -1.69 -0.176 0.63141E+04 12 akimotoite 6.64 1.92 -4.72 -0.944 0.17607E+05 13 akimotoite-Fe 4.43 0.13 -4.30 -0.860 0.16031E+05 14 albite-high -3.60 -3.79 -0.19 -0.014 0.69029E+03 15 albite -3.62 -3.79 -0.17 -0.013 0.62868E+03 16 almandine -4.54 -7.01 -2.47 -0.124 0.92190E+04 17 pyrope 2.50 -1.63 -4.12 -0.206 0.15385E+05 18 analcite -1.30 -2.33 -1.03 -0.114 0.38408E+04 19 andalusite -8.25 -8.85 -0.61 -0.061 0.22692E+04 24 anorthite -5.78 -6.77 -0.99 -0.076 0.37036E+04 26 anthophyllite-Fe 3.57 -0.55 -4.13 -0.112 0.15388E+05 27 apatite-OH -54.39 -54.52 -0.12 -0.009 0.45450E+03 28 apatite-OH-zs -52.14 -54.52 -2.37 -0.183 0.88516E+04 29 apatite-Cl-zs -59.13 -62.57 -3.44 -0.287 0.12849E+05 30 aragonite -4.87 -8.77 -3.91 -1.302 0.14568E+05 31 brucite 6.06 3.38 -2.68 -0.536 0.99939E+04 32 calcite -4.98 -8.77 -3.79 -1.265 0.14151E+05 33 carnegieite-low 0.97 -0.88 -1.85 -0.265 0.69069E+04 34 carnegieite-high 1.07 -0.88 -1.95 -0.278 0.72710E+04 35 carpholite-Mg -4.48 -6.93 -2.46 -0.164 0.91609E+04 36 carpholite-Fe -5.92 -8.73 -2.80 -0.187 0.10460E+05 37 celadonite 0.19 -2.33 -2.52 -0.148 0.93838E+04 38 celadonite-Fe -1.30 -4.12 -2.82 -0.166 0.10534E+05 39 chrysotile 10.78 7.23 -3.56 -0.297 0.13275E+05 41 clinochlore 8.40 5.13 -3.27 -0.102 0.12210E+05 42 daphnite 0.86 -3.85 -4.71 -0.147 0.17580E+05 45 chloritoid-Mg -3.68 -5.48 -1.79 -0.119 0.66858E+04 46 chloritoid-Fe -5.76 -7.27 -1.51 -0.101 0.56392E+04 47 chloritoid-Mn -3.63 -5.30 -1.67 -0.111 0.62154E+04 49 coesite -1.15 -1.45 -0.30 -0.100 0.11242E+04 50 cordierite-H -13.42 -15.31 -1.89 -0.068 0.70568E+04 51 cordierite-Fe -16.23 -18.90 -2.67 -0.092 0.99661E+04 52 cordierite-Mn -11.91 -14.96 -3.04 -0.105 0.11354E+05 53 corundum -6.61 -7.40 -0.79 -0.072 0.29593E+04 55 cristobalite -1.41 -1.45 -0.05 -0.016 0.18310E+03 58 cymrite-K -1.86 -4.25 -2.39 -0.200 0.89305E+04 60 diaspore -2.83 -3.70 -0.87 -0.145 0.32490E+04 62 diopside 5.96 4.01 -1.95 -0.195 0.72870E+04 63 hedenbergite 4.45 2.21 -2.23 -0.223 0.83216E+04 65 eastonite -1.24 -3.44 -2.20 -0.085 0.82164E+04 66 enstatite 5.55 3.85 -1.70 -0.170 0.63419E+04 67 clinoenstatite-HiP 6.06 3.85 -2.21 -0.221 0.82537E+04 68 clinoenstatite 5.53 3.85 -1.68 -0.168 0.62639E+04 69 protoenstatite 5.69 3.85 -1.84 -0.184 0.68632E+04 70 epidote -1.25 -4.08 -2.82 -0.137 0.10537E+05 71 clinozoisite -5.21 -8.38 -3.17 -0.144 0.11820E+05 72 epidote-Fe 4.43 0.23 -4.20 -0.218 0.15673E+05 73 fayalite 3.10 1.71 -1.38 -0.198 0.51633E+04 74 ferrosilite 1.74 0.26 -1.49 -0.149 0.55464E+04 75 forsterite 7.32 5.30 -2.02 -0.289 0.75397E+04 76 gedrite -2.32 -6.63 -4.31 -0.117 0.16089E+05 78 gibbsite -1.19 -3.70 -2.51 -0.358 0.93604E+04 79 glaucophane 3.94 -0.35 -4.29 -0.116 0.16003E+05 81 goethite 1.59 0.61 -0.98 -0.213 0.36706E+04 83 greenalite 5.58 1.84 -3.75 -0.312 0.13973E+05 84 grunerite 4.16 -0.55 -4.71 -0.127 0.17585E+05 85 halite -1.70 -3.78 -2.07 -1.037 0.77333E+04 86 hematite 1.63 1.21 -0.42 -0.050 0.15521E+04 87 heulandite -10.65 -14.05 -3.40 -0.154 0.12668E+05 88 hercynite -4.35 -5.82 -1.46 -0.098 0.54561E+04 91 jadeite -0.62 -2.33 -1.71 -0.171 0.63894E+04 93 kalsilite 0.34 -1.34 -1.68 -0.241 0.62824E+04 94 kaolinite -7.56 -10.31 -2.75 -0.250 0.10251E+05 95 kyanite -8.08 -8.85 -0.78 -0.078 0.28941E+04 97 laumontite -5.84 -9.68 -3.84 -0.256 0.14327E+05 98 lawsonite -3.04 -6.77 -3.73 -0.249 0.13931E+05 99 leucite -1.78 -2.80 -1.02 -0.102 0.37901E+04 101 lizardite 10.93 7.23 -3.71 -0.309 0.13834E+05 102 magnesite -5.52 -8.93 -3.42 -1.139 0.12751E+05 103 magnetite 3.34 2.80 -0.55 -0.045 0.20452E+04 104 minnesotaite 1.42 -1.07 -2.49 -0.147 0.92931E+04 105 minnesotaite-Mg 7.74 4.32 -3.42 -0.201 0.12774E+05 106 magnesioferrite 6.57 4.59 -1.98 -0.161 0.73768E+04 108 manganosite 5.92 3.56 -2.37 -0.591 0.88216E+04 109 margarite -11.97 -14.17 -2.20 -0.088 0.82135E+04 113 monticellite 9.64 5.46 -4.17 -0.596 0.15558E+05 115 mullite-Si -7.46 -8.85 -1.40 -0.140 0.52052E+04 116 muscovite -10.76 -11.65 -0.89 -0.053 0.33316E+04 117 paragonite -10.06 -11.19 -1.13 -0.066 0.42000E+04 118 nepheline 0.66 -0.88 -1.54 -0.220 0.57483E+04 119 osumilite(2) -9.80 -13.15 -3.36 -0.070 0.12515E+05 120 osumilite-Fe -22.94 -26.07 -3.12 -0.065 0.11639E+05 122 periclase 6.30 3.38 -2.92 -0.730 0.10885E+05 123 periclase-Fe 3.59 1.58 -2.01 -0.503 0.74989E+04 124 perovskite-Al -4.82 -7.40 -2.58 -0.235 0.96228E+04 129 phlogopite-Na 8.43 6.35 -2.08 -0.116 0.77563E+04 131 prehnite -0.93 -4.68 -3.76 -0.221 0.14010E+05 132 prehnite-Fe 3.44 -0.38 -3.82 -0.229 0.14230E+05 135 px-Mg-tschermaks -2.98 -5.47 -2.50 -0.178 0.93203E+04 136 px-Ca-tschermaks -2.38 -5.31 -2.93 -0.210 0.10946E+05 138 pyrrhotite -8.70 -9.49 -0.79 -0.264 0.29509E+04 139 pyrrhotiteFe0.875 -9.56 -9.93 -0.38 -0.139 0.14083E+04 140 pyrophyllite -11.77 -13.22 -1.45 -0.091 0.54039E+04 143 riebeckite 6.43 2.88 -3.55 -0.098 0.13254E+05 144 ringwoodite-Fe 4.11 1.71 -2.40 -0.342 0.89379E+04 146 rhodochrosite -5.63 -8.76 -3.13 -1.043 0.11676E+05 147 rhodonite 2.79 2.10 -0.69 -0.139 0.25851E+04 148 sanidine -3.70 -4.25 -0.55 -0.043 0.20689E+04 150 siderite -7.47 -10.73 -3.26 -1.086 0.12156E+05 151 sillimanite -8.20 -8.85 -0.65 -0.065 0.24324E+04 153 spinel -2.07 -4.02 -1.95 -0.130 0.72834E+04 160 stilpnomelane-Mg 3.84 -0.24 -4.08 -0.122 0.15237E+05 161 stishovite 1.58 -1.45 -3.04 -1.012 0.11328E+05 162 sudoite-Fe -11.16 -16.00 -4.84 -0.156 0.18039E+05 163 sudoite -8.77 -12.41 -3.64 -0.117 0.13569E+05 164 sulfur -11.55 -13.03 -1.49 -0.457 0.55409E+04 165 sylvite -1.61 -4.24 -2.63 -1.315 0.98125E+04 166 talc 5.97 4.32 -1.65 -0.097 0.61510E+04 167 talc-Fe 2.88 -1.07 -3.95 -0.232 0.14715E+05 168 talc-tschermaks -2.48 -5.01 -2.53 -0.149 0.94250E+04 170 tephroite 7.31 5.66 -1.65 -0.236 0.61527E+04 173 topaz-H -6.16 -8.85 -2.69 -0.245 0.10052E+05 174 tremolite 17.24 12.34 -4.90 -0.132 0.18278E+05 176 troilite-low -8.61 -9.49 -0.88 -0.293 0.32761E+04 177 tschermakite -1.33 -6.31 -4.98 -0.135 0.18570E+05 180 wadsleyite-Fe 3.97 1.71 -2.26 -0.323 0.84209E+04 181 wadsleyite-Mg 9.60 5.30 -4.30 -0.614 0.16043E+05 182 wairakite -7.73 -9.68 -1.95 -0.115 0.72880E+04 183 walstromite 4.83 2.09 -2.74 -0.549 0.10231E+05 184 wollastonite 4.39 2.09 -2.30 -0.461 0.85913E+04 185 pseudo-wollastonite 4.51 2.09 -2.43 -0.486 0.90585E+04 186 zoisite -5.26 -8.38 -3.12 -0.142 0.11653E+05 189 beidellite-Ca -11.54 -13.38 -1.84 -0.114 0.68494E+04 190 beidellite-H -11.61 -13.96 -2.35 -0.150 0.87534E+04 191 beidellite-K -10.58 -12.70 -2.13 -0.130 0.79271E+04 192 beidellite-Mg -11.76 -13.40 -1.64 -0.102 0.61338E+04 193 beidellite-Na -10.52 -12.55 -2.03 -0.124 0.75724E+04 194 bornite -57.07 -57.24 -0.17 -0.013 0.64205E+03 196 chalcocite -15.08 -16.49 -1.41 -0.354 0.52759E+04 197 covellite -13.45 -14.76 -1.31 -0.498 0.48776E+04 199 montmorillonite-Ca -8.80 -10.30 -1.50 -0.093 0.55777E+04 200 montmorillonite-K -8.11 -9.62 -1.51 -0.093 0.56445E+04 201 montmorillonite-Mg -8.99 -10.33 -1.33 -0.083 0.49758E+04 202 montmorillonite-Na -7.79 -9.47 -1.68 -0.103 0.62739E+04 203 nontronite-Ca -3.02 -4.76 -1.74 -0.113 0.64854E+04 204 nontronite-H -3.11 -5.35 -2.24 -0.150 0.83630E+04 205 nontronite-K -2.06 -4.09 -2.03 -0.130 0.75555E+04 206 nontronite-Mg -3.22 -4.79 -1.58 -0.102 0.58749E+04 207 nontronite-Na -2.00 -3.94 -1.93 -0.124 0.72119E+04 212 gypsum -13.07 -15.36 -2.29 -0.571 0.85251E+04 229 alabandite -6.43 -7.52 -1.09 -0.362 0.40496E+04 231 anglesite -15.76 -18.06 -2.30 -1.151 0.85839E+04 235 boehmite -2.52 -3.70 -1.18 -0.197 0.44125E+04 239 copper,native 1.68 -1.73 -3.41 -1.186 0.12718E+05 241 ferrous-oxide 2.65 1.58 -1.06 -0.266 0.39656E+04 242 galena -10.24 -10.24 -0.00 -0.001 0.13898E+02 243 silver,native 0.34 -4.20 -4.54 -1.578 0.16922E+05 245 litharge 5.55 0.84 -4.71 -1.178 0.17579E+05 253 wurtzite -10.23 -11.06 -0.83 -0.276 0.30917E+04 254 zincite 2.70 0.02 -2.68 -0.670 0.99924E+04 255 an20ab80 -4.27 -4.38 -0.12 -0.009 0.43301E+03 256 an25ab75 -4.40 -4.53 -0.13 -0.010 0.48669E+03 257 an30ab70 -4.53 -4.68 -0.15 -0.012 0.56215E+03 258 tr.625ac.25prg.125 12.18 9.18 -3.00 -0.081 0.11179E+05 Calculations done for 542.0000 Deg. C; 858.0000 bar Temperature changed by -1.000 degrees to 541.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 62 Loop limit = 500 Temperature = 541.00 C Pressure = 848.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9936E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9971 Stoichiometric ionic strength = .3268929E+01 Osmotic coef. = 0.0000 True ionic strength = .1747856E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.55039E-05 -5.2593 0.63001E-06 -6.2006 0.11447E+00 -0.9413 2 H2O 0.99706E+00 -0.0013 0.99706E+00 -0.0013 3 Cl- 0.14699E+00 -0.8327 0.13110E-01 -1.8824 0.89190E-01 -1.0497 4 SO4-- 0.14422E-02 -2.8410 0.29042E-06 -6.5370 0.20137E-03 -3.6960 5 HCO3- 0.71283E-05 -5.1470 0.70484E-06 -6.1519 0.98879E-01 -1.0049 6 HS- 0.13852E-03 -3.8585 0.12496E-04 -4.9032 0.90212E-01 -1.0447 7 H4SiO4 0.34195E-01 -1.4660 0.34195E-01 -1.4660 0.10000E+01 0.0000 8 Al+++ 0.18213E-13 -13.7396 0.58962E-22 -22.2294 0.32374E-08 -8.4898 9 Ca++ 0.97480E-05 -5.0111 0.14270E-08 -8.8456 0.14639E-03 -3.8345 10 Mg++ 0.84028E-05 -5.0756 0.93483E-09 -9.0293 0.11125E-03 -3.9537 11 Fe++ 0.13501E-06 -6.8696 0.16098E-10 -10.7932 0.11924E-03 -3.9236 12 K+ 0.39974E-01 -1.3982 0.40825E-02 -2.3891 0.10213E+00 -0.9908 13 Na+ 0.13181E+00 -0.8800 0.11917E-01 -1.9238 0.90406E-01 -1.0438 14 Mn++ 0.12031E-04 -4.9197 0.15092E-08 -8.8212 0.12544E-03 -3.9015 15 Zn++ 0.36833E-08 -8.4338 0.43919E-12 -12.3574 0.11924E-03 -3.9236 16 Cu+ 0.13537E-07 -7.8685 0.12194E-08 -8.9139 0.90073E-01 -1.0454 17 Pb++ 0.16185E-07 -7.7909 0.27824E-11 -11.5556 0.17192E-03 -3.7647 18 Ag+ 0.34723E-10 -10.4594 0.34684E-11 -11.4599 0.99887E-01 -1.0005 19 Ba++ 0.32292E-06 -6.4909 0.61483E-10 -10.2112 0.19040E-03 -3.7203 20 HPO4-- 0.88785E-08 -8.0517 0.18007E-11 -11.7446 0.20282E-03 -3.6929 21 HSiO3- 0.15077E-05 -5.8217 0.13447E-06 -6.8714 0.89190E-01 -1.0497 22 Ca(HSiO3)+ 0.47776E-08 -8.3208 0.49403E-09 -9.3062 0.10340E+00 -0.9855 23 Mg(HSiO3)+ 0.11691E-08 -8.9322 0.12089E-09 -9.9176 0.10340E+00 -0.9855 24 NaHSiO3,aq 0.17624E-05 -5.7539 0.17624E-05 -5.7539 0.10000E+01 0.0000 28 AgCl,aq 0.12216E-07 -7.9131 0.12216E-07 -7.9131 0.10000E+01 0.0000 29 AgCl2- 0.62392E-06 -6.2049 0.55647E-07 -7.2546 0.89190E-01 -1.0497 30 AgCl3-2 0.57466E-06 -6.2406 0.10372E-09 -9.9841 0.18050E-03 -3.7435 31 AgCl4-3 0.75451E-05 -5.1223 0.20661E-13 -13.6848 0.27384E-08 -8.5625 34 Ag(HS),aq 0.26309E-09 -9.5799 0.26309E-09 -9.5799 0.10000E+01 0.0000 35 Ag(HS)2- 0.83126E-09 -9.0803 0.74140E-10 -10.1299 0.89190E-01 -1.0497 36 AlO+ 0.32672E-10 -10.4858 0.33785E-11 -11.4713 0.10340E+00 -0.9855 38 HAlO2,aq 0.52833E-08 -8.2771 0.52833E-08 -8.2771 0.10000E+01 0.0000 39 AlO2- 0.15509E-04 -4.8094 0.11568E-05 -5.9368 0.74585E-01 -1.1273 41 Ba(HCO3)+ 0.14085E-06 -6.8512 0.15410E-07 -7.8122 0.10940E+00 -0.9610 42 BaCl+ 0.67823E-05 -5.1686 0.70132E-06 -6.1541 0.10340E+00 -0.9855 43 CH4,aq 0.11978E-08 -8.9216 0.13936E-08 -8.8558 0.11635E+01 0.0658 48 CO,aq 0.36373E-03 -3.4392 0.36373E-03 -3.4392 0.10000E+01 0.0000 49 CO2,aq 0.26729E+01 0.4270 0.31098E+01 0.4927 0.11635E+01 0.0658 50 CO3-2 0.16962E-09 -9.7705 0.30616E-13 -13.5140 0.18050E-03 -3.7435 52 Ca(HCO3)+ 0.65277E-07 -7.1852 0.67500E-08 -8.1707 0.10340E+00 -0.9855 53 CaCl+ 0.77457E-04 -4.1109 0.80095E-05 -5.0964 0.10340E+00 -0.9855 54 CaCl2,aq 0.61222E-04 -4.2131 0.61222E-04 -4.2131 0.10000E+01 0.0000 55 CaOH+ 0.13804E-06 -6.8600 0.14274E-07 -7.8454 0.10340E+00 -0.9855 56 CaSO4,aq 0.21591E-06 -6.6657 0.21591E-06 -6.6657 0.10000E+01 0.0000 57 HCl,aq 0.72075E-02 -2.1422 0.72075E-02 -2.1422 0.10000E+01 0.0000 66 CuCl,aq 0.18576E-04 -4.7311 0.18576E-04 -4.7311 0.10000E+01 0.0000 67 CuCl2- 0.81459E-04 -4.0891 0.72653E-05 -5.1387 0.89190E-01 -1.0497 68 CuCl3-2 0.42050E-05 -5.3762 0.75899E-09 -9.1198 0.18050E-03 -3.7435 74 FeCl+ 0.31416E-06 -6.5028 0.32486E-07 -7.4883 0.10340E+00 -0.9855 75 FeCl2,aq 0.16461E-02 -2.7835 0.16461E-02 -2.7835 0.10000E+01 0.0000 77 FeO,aq 0.39841E-07 -7.3997 0.39841E-07 -7.3997 0.10000E+01 0.0000 78 FeOH+ 0.24987E-07 -7.6023 0.25838E-08 -8.5877 0.10340E+00 -0.9855 79 HFeO2- 0.59196E-08 -8.2277 0.52797E-09 -9.2774 0.89190E-01 -1.0497 82 FeO2- 0.32301E-08 -8.4908 0.28809E-09 -9.5405 0.89190E-01 -1.0497 83 HFeO2,aq 0.27850E-09 -9.5552 0.27850E-09 -9.5552 0.10000E+01 0.0000 84 H2,aq 0.41353E-02 -2.3835 0.48113E-02 -2.3177 0.11635E+01 0.0658 85 KCl,aq 0.68410E-01 -1.1649 0.68410E-01 -1.1649 0.10000E+01 0.0000 86 KHSO4,aq 0.11148E-01 -1.9528 0.11148E-01 -1.9528 0.10000E+01 0.0000 87 KOH,aq 0.12595E-05 -5.8998 0.12595E-05 -5.8998 0.10000E+01 0.0000 88 KSO4- 0.60027E-02 -2.2217 0.53537E-03 -3.2713 0.89190E-01 -1.0497 90 Mg(HCO3)+ 0.12335E-07 -7.9089 0.12755E-08 -8.8943 0.10340E+00 -0.9855 91 MgCl+ 0.11984E-04 -4.9214 0.12392E-05 -5.9069 0.10340E+00 -0.9855 92 MgOH+ 0.41000E-06 -6.3872 0.42396E-07 -7.3727 0.10340E+00 -0.9855 94 MnO,aq 0.70202E-07 -7.1537 0.70202E-07 -7.1537 0.10000E+01 0.0000 95 MnOH+ 0.23190E-06 -6.6347 0.23979E-07 -7.6202 0.10340E+00 -0.9855 97 HMnO2- 0.36178E-10 -10.4416 0.32267E-11 -11.4912 0.89190E-01 -1.0497 100 MnCl+ 0.11444E-02 -2.9414 0.11833E-03 -3.9269 0.10340E+00 -0.9855 101 MnSO4,aq 0.21517E-06 -6.6672 0.21517E-06 -6.6672 0.10000E+01 0.0000 102 NaCl,aq 0.42636E+00 -0.3702 0.42636E+00 -0.3702 0.10000E+01 0.0000 103 NaOH,aq 0.16465E-05 -5.7834 0.16465E-05 -5.7834 0.10000E+01 0.0000 105 OH- 0.97269E-05 -5.0120 0.72549E-06 -6.1394 0.74585E-01 -1.1273 110 HPO3-2 0.32833E-10 -10.4837 0.59264E-14 -14.2272 0.18050E-03 -3.7435 111 H3PO3,aq 0.12001E-09 -9.9208 0.12001E-09 -9.9208 0.10000E+01 0.0000 112 H2PO3- 0.13605E-08 -8.8663 0.12135E-09 -9.9160 0.89190E-01 -1.0497 113 H3PO4,aq 0.20295E-05 -5.6926 0.20295E-05 -5.6926 0.10000E+01 0.0000 114 H2PO4- 0.16802E-05 -5.7746 0.16060E-06 -6.7943 0.95582E-01 -1.0196 116 H4P2O7,aq 0.40783E-09 -9.3895 0.40783E-09 -9.3895 0.10000E+01 0.0000 117 H3P2O7- 0.11077E-08 -8.9556 0.98796E-10 -10.0053 0.89190E-01 -1.0497 118 H2P2O7-2 0.75320E-06 -6.1231 0.13595E-09 -9.8666 0.18050E-03 -3.7435 119 HP2O7-3 0.16964E-05 -5.7705 0.46454E-14 -14.3330 0.27384E-08 -8.5625 120 P2O7-4 0.18690E-09 -9.7284 0.55939E-24 -24.2523 0.29930E-14 -14.5239 121 PbCl+ 0.11718E-05 -5.9311 0.12117E-06 -6.9166 0.10340E+00 -0.9855 122 PbCl2,aq 0.71897E-04 -4.1433 0.71897E-04 -4.1433 0.10000E+01 0.0000 123 PbCl3- 0.11124E-03 -3.9538 0.99211E-05 -5.0034 0.89190E-01 -1.0497 124 PbCl4-2 0.50227E-04 -4.2991 0.90659E-08 -8.0426 0.18050E-03 -3.7435 125 PbO,aq 0.58212E-08 -8.2350 0.58212E-08 -8.2350 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.93740E-04 -4.0281 0.93740E-04 -4.0281 0.10000E+01 0.0000 128 Pb(HS)3- 0.14075E-04 -4.8515 0.12554E-05 -5.9012 0.89190E-01 -1.0497 129 H2S,aq 0.10601E+01 0.0253 0.12334E+01 0.0911 0.11635E+01 0.0658 130 S2-2 0.46053E-07 -7.3367 0.83125E-11 -11.0803 0.18050E-03 -3.7435 131 S3-2 0.40057E-08 -8.3973 0.72302E-12 -12.1409 0.18050E-03 -3.7435 132 S3- 0.77486E-02 -2.1108 0.69110E-03 -3.1605 0.89190E-01 -1.0497 133 S4-2 0.30181E-09 -9.5203 0.54476E-13 -13.2638 0.18050E-03 -3.7435 134 S5-2 0.20068E-10 -10.6975 0.36222E-14 -14.4410 0.18050E-03 -3.7435 135 SO2,aq 0.29315E+00 -0.5329 0.29315E+00 -0.5329 0.10000E+01 0.0000 136 SO3-2 0.28807E-08 -8.5405 0.10048E-11 -11.9979 0.34881E-03 -3.4574 137 HSO3- 0.23168E-03 -3.6351 0.20664E-04 -4.6848 0.89190E-01 -1.0497 138 HSO4- 0.88112E-02 -2.0550 0.94806E-03 -3.0232 0.10760E+00 -0.9682 140 S2O3-2 0.23673E-05 -5.6257 0.42730E-09 -9.3693 0.18050E-03 -3.7435 141 HS2O3- 0.36266E-06 -6.4405 0.32345E-07 -7.4902 0.89190E-01 -1.0497 142 H2S2O3,aq 0.48802E-07 -7.3116 0.48802E-07 -7.3116 0.10000E+01 0.0000 150 S4O6-2 0.16323E-08 -8.7872 0.29463E-12 -12.5307 0.18050E-03 -3.7435 152 ZnCl+ 0.13023E-03 -3.8853 0.13466E-04 -4.8707 0.10340E+00 -0.9855 153 ZnCl2,aq 0.45532E-03 -3.3417 0.45532E-03 -3.3417 0.10000E+01 0.0000 154 ZnCl3- 0.30547E-04 -4.5150 0.27244E-05 -5.5647 0.89190E-01 -1.0497 155 ZnO,aq 0.21751E-07 -7.6625 0.21751E-07 -7.6625 0.10000E+01 0.0000 156 ZnOH+ 0.97346E-06 -6.0117 0.10066E-06 -6.9971 0.10340E+00 -0.9855 158 HZnO2- 0.21352E-09 -9.6706 0.19044E-10 -10.7203 0.89190E-01 -1.0497 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5503886E-05 0.4292858E+01 0.3545070E+04 0.0000 2 H2O 0.1000000E+01 0.5252665E+02 0.7752911E+06 0.0000 3 Cl- 0.1469904E+00 0.6556674E+00 0.1904497E+05 4.3183 4 SO4-- 0.1442212E-02 0.2511604E+00 0.1976717E+05 5.8643 5 HCO3- 0.7128266E-05 0.2673265E+01 0.1336404E+06 0.0487 6 HS- 0.1385177E-03 0.1153342E+01 0.3125088E+05 1.2974 7 H4SiO4 0.3419539E-01 0.3419866E-01 0.2693058E+04 -1.4660 8 Al+++ 0.1821302E-13 0.1551465E-04 0.3429665E+00 -3.6275 9 Ca++ 0.9747959E-05 0.1488516E-03 0.4887685E+01 3.5557 10 Mg++ 0.8402801E-05 0.2081017E-04 0.4145147E+00 3.3720 11 Fe++ 0.1350101E-06 0.1646673E-02 0.7534438E+02 1.6081 12 K+ 0.3997395E-01 0.1255365E+00 0.4021726E+04 3.8116 13 Na+ 0.1318130E+00 0.5581806E+00 0.1051365E+05 4.2768 14 Mn++ 0.1203097E-04 0.1156923E-02 0.5207399E+02 3.5800 15 Zn++ 0.3683337E-08 0.6170937E-03 0.3305013E+02 0.0439 16 Cu+ 0.1353737E-07 0.1042533E-03 0.5427258E+01 -2.7132 17 Pb++ 0.1618473E-07 0.3423693E-03 0.5811754E+02 0.8457 18 Ag+ 0.3472350E-10 0.8757027E-05 0.7739288E+00 -5.2592 19 Ba++ 0.3229225E-06 0.7246035E-05 0.8153445E+00 2.1901 20 HPO4-- 0.8878536E-08 0.8622825E-05 0.6780620E+00 0.6567 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265315E+01 -.2953065E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5218963E+02 -.2248545E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2495489E+00 0.2173844E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1145942E+01 0.1420183E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3397924E-01 0.1096151E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1541511E-04 0.6791244E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1478966E-03 0.3800133E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1636108E-02 0.7130646E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247310E+00 0.6791244E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.6131344E-03 0.1686200E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1035844E-03 0.2960253E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7199545E-05 0.4817291E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1057E-17 Mass of aqueous solution: 0.121272E+04 g Temperature = 541.00 C Pressure = 848.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3800E-03 -3.420 0.5174E-01 -1.286 0.6672 0.1746E-01 microcline 0.6791E-03 -3.168 0.1890 -0.723 2.438 0.7384E-01 pyrite 0.6835E-02 -2.165 0.8200 -0.086 10.58 0.1636 quartz 0.1076 -0.968 6.463 0.810 83.36 2.441 barite 0.4817E-04 -4.317 0.1124E-01 -1.949 0.1450 0.2510E-02 chalcopyrite 0.2960E-03 -3.529 0.5432E-01 -1.265 0.7006 0.1268E-01 sphalerite 0.1686E-02 -2.773 0.1643 -0.784 2.119 0.4018E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.753900 g Volume = 2.751089 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.38 -15.38 -0.00 -0.000 0.66177E-11 112 microcline -4.21 -4.21 -0.00 -0.000 0.66177E-11 137 pyrite -22.56 -22.56 0.00 0.000 0.00000E+00 141 quartz -1.46 -1.46 0.00 0.000 0.00000E+00 234 barite -16.75 -16.75 0.00 0.000 0.00000E+00 237 chalcopyrite -24.29 -24.29 -0.00 -0.000 0.13235E-10 252 sphalerite -11.06 -11.06 -0.00 -0.000 0.13235E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.248 0.92358E+03 2.680 2 CO2,gas -10.55 -12.35 -1.80 -0.600 0.67072E+04 1.128 3 CH4,gas 6.74 -4.52 -11.26 -2.815 0.41955E+05 -8.333 4 H2,gas 6.08 1.96 -4.12 -2.354 0.15349E+05 -1.192 5 H2S,gas -8.78 -11.10 -2.32 -1.161 0.86520E+04 0.606 6 CO,gas -4.14 -10.39 -6.26 -1.925 0.23305E+05 -3.327 7 SO3,gas -8.04 -18.94 -10.90 -2.725 0.40608E+05 -7.972 8 O2,gas 17.27 -3.92 -21.19 -14.126 0.78938E+05 -18.261 9 HCl,gas -6.38 -8.08 -1.70 -0.851 0.63370E+04 -1.701 10 acmite 3.67 1.98 -1.70 -0.176 0.63219E+04 12 akimotoite 6.67 1.91 -4.77 -0.953 0.17757E+05 13 akimotoite-Fe 4.45 0.14 -4.31 -0.861 0.16044E+05 14 albite-high -3.56 -3.74 -0.19 -0.014 0.69857E+03 15 albite -3.57 -3.74 -0.17 -0.013 0.63189E+03 16 almandine -4.34 -6.83 -2.49 -0.124 0.92712E+04 17 pyrope 2.72 -1.54 -4.25 -0.213 0.15851E+05 18 analcite -1.25 -2.28 -1.03 -0.115 0.38442E+04 19 andalusite -8.11 -8.72 -0.61 -0.061 0.22775E+04 24 anorthite -5.63 -6.63 -1.00 -0.077 0.37307E+04 26 anthophyllite-Fe 3.69 -0.46 -4.15 -0.112 0.15470E+05 27 apatite-OH -54.43 -54.66 -0.23 -0.017 0.84692E+03 28 apatite-OH-zs -52.18 -54.66 -2.48 -0.191 0.92466E+04 29 apatite-Cl-zs -59.19 -62.74 -3.56 -0.296 0.13248E+05 30 aragonite -4.88 -8.80 -3.92 -1.306 0.14595E+05 31 brucite 6.09 3.37 -2.72 -0.544 0.10137E+05 32 calcite -4.99 -8.80 -3.81 -1.269 0.14179E+05 33 carnegieite-low 1.04 -0.82 -1.85 -0.265 0.69098E+04 34 carnegieite-high 1.14 -0.82 -1.95 -0.279 0.72754E+04 35 carpholite-Mg -4.32 -6.82 -2.50 -0.166 0.93004E+04 36 carpholite-Fe -5.77 -8.58 -2.81 -0.187 0.10464E+05 37 celadonite 0.25 -2.30 -2.56 -0.150 0.95251E+04 38 celadonite-Fe -1.24 -4.07 -2.83 -0.166 0.10542E+05 39 chrysotile 10.86 7.18 -3.68 -0.307 0.13705E+05 41 clinochlore 8.67 5.20 -3.47 -0.108 0.12926E+05 42 daphnite 1.11 -3.62 -4.73 -0.148 0.17616E+05 45 chloritoid-Mg -3.52 -5.35 -1.83 -0.122 0.68317E+04 46 chloritoid-Fe -5.60 -7.12 -1.52 -0.101 0.56471E+04 47 chloritoid-Mn -3.48 -5.14 -1.67 -0.111 0.62201E+04 49 coesite -1.16 -1.46 -0.30 -0.101 0.11239E+04 50 cordierite-H -13.11 -15.09 -1.98 -0.071 0.73779E+04 51 cordierite-Fe -15.93 -18.62 -2.69 -0.093 0.10009E+05 52 cordierite-Mn -11.62 -14.68 -3.06 -0.105 0.11391E+05 53 corundum -6.46 -7.26 -0.80 -0.072 0.29666E+04 55 cristobalite -1.41 -1.46 -0.05 -0.016 0.18418E+03 58 cymrite-K -1.81 -4.21 -2.40 -0.200 0.89330E+04 60 diaspore -2.76 -3.63 -0.87 -0.145 0.32461E+04 62 diopside 6.00 4.00 -2.00 -0.200 0.74537E+04 63 hedenbergite 4.48 2.23 -2.24 -0.224 0.83529E+04 65 eastonite -0.98 -3.26 -2.29 -0.088 0.85150E+04 66 enstatite 5.60 3.81 -1.78 -0.178 0.66427E+04 67 clinoenstatite-HiP 6.11 3.81 -2.30 -0.230 0.85555E+04 68 clinoenstatite 5.58 3.81 -1.76 -0.176 0.65653E+04 69 protoenstatite 5.74 3.81 -1.92 -0.192 0.71663E+04 70 epidote -1.07 -3.91 -2.84 -0.138 0.10582E+05 71 clinozoisite -4.99 -8.17 -3.18 -0.145 0.11859E+05 72 epidote-Fe 4.56 0.34 -4.22 -0.219 0.15718E+05 73 fayalite 3.14 1.75 -1.39 -0.199 0.51906E+04 74 ferrosilite 1.78 0.29 -1.50 -0.150 0.55742E+04 75 forsterite 7.38 5.28 -2.10 -0.301 0.78409E+04 76 gedrite -1.92 -6.45 -4.52 -0.122 0.16849E+05 78 gibbsite -1.12 -3.63 -2.51 -0.359 0.93495E+04 79 glaucophane 4.11 -0.30 -4.41 -0.119 0.16440E+05 81 goethite 1.61 0.63 -0.99 -0.213 0.36745E+04 83 greenalite 5.65 1.89 -3.76 -0.313 0.13992E+05 84 grunerite 4.28 -0.46 -4.74 -0.128 0.17670E+05 85 halite -1.73 -3.81 -2.08 -1.038 0.77336E+04 86 hematite 1.68 1.25 -0.42 -0.051 0.15675E+04 87 heulandite -10.55 -13.96 -3.40 -0.155 0.12684E+05 88 hercynite -4.18 -5.65 -1.47 -0.098 0.54783E+04 91 jadeite -0.57 -2.28 -1.72 -0.172 0.63892E+04 93 kalsilite 0.40 -1.28 -1.69 -0.241 0.62835E+04 94 kaolinite -7.44 -10.19 -2.75 -0.250 0.10231E+05 95 kyanite -7.94 -8.72 -0.78 -0.078 0.29015E+04 97 laumontite -5.72 -9.56 -3.85 -0.256 0.14332E+05 98 lawsonite -2.89 -6.63 -3.74 -0.249 0.13937E+05 99 leucite -1.73 -2.75 -1.02 -0.102 0.37941E+04 101 lizardite 11.01 7.18 -3.83 -0.319 0.14261E+05 102 magnesite -5.52 -8.98 -3.47 -1.155 0.12910E+05 103 magnetite 3.42 2.86 -0.56 -0.045 0.20744E+04 104 minnesotaite 1.47 -1.03 -2.50 -0.147 0.93209E+04 105 minnesotaite-Mg 7.80 4.26 -3.55 -0.209 0.13211E+05 106 magnesioferrite 6.65 4.63 -2.02 -0.165 0.75434E+04 108 manganosite 5.95 3.58 -2.37 -0.593 0.88326E+04 109 margarite -11.68 -13.89 -2.21 -0.088 0.82364E+04 113 monticellite 9.68 5.46 -4.22 -0.603 0.15724E+05 115 mullite-Si -7.32 -8.72 -1.40 -0.140 0.52151E+04 116 muscovite -10.57 -11.47 -0.89 -0.053 0.33320E+04 117 paragonite -9.88 -11.00 -1.13 -0.066 0.42009E+04 118 nepheline 0.73 -0.82 -1.54 -0.220 0.57500E+04 119 osumilite(2) -9.58 -13.06 -3.48 -0.073 0.12982E+05 120 osumilite-Fe -22.62 -25.76 -3.14 -0.065 0.11689E+05 122 periclase 6.33 3.37 -2.96 -0.741 0.11035E+05 123 periclase-Fe 3.62 1.61 -2.02 -0.504 0.75134E+04 124 perovskite-Al -4.67 -7.26 -2.59 -0.235 0.96304E+04 129 phlogopite-Na 8.57 6.37 -2.20 -0.122 0.82012E+04 131 prehnite -0.77 -4.54 -3.77 -0.222 0.14041E+05 132 prehnite-Fe 3.54 -0.28 -3.83 -0.230 0.14266E+05 135 px-Mg-tschermaks -2.81 -5.35 -2.54 -0.182 0.94809E+04 136 px-Ca-tschermaks -2.22 -5.17 -2.94 -0.210 0.10970E+05 138 pyrrhotite -8.70 -9.50 -0.80 -0.265 0.29620E+04 139 pyrrhotiteFe0.875 -9.56 -9.94 -0.38 -0.140 0.14187E+04 140 pyrophyllite -11.66 -13.11 -1.45 -0.091 0.54017E+04 143 riebeckite 6.49 2.92 -3.57 -0.098 0.13296E+05 144 ringwoodite-Fe 4.16 1.75 -2.41 -0.344 0.89634E+04 146 rhodochrosite -5.63 -8.77 -3.14 -1.046 0.11695E+05 147 rhodonite 2.81 2.12 -0.70 -0.139 0.25961E+04 148 sanidine -3.65 -4.21 -0.56 -0.043 0.20687E+04 150 siderite -7.48 -10.74 -3.27 -1.090 0.12178E+05 151 sillimanite -8.07 -8.72 -0.66 -0.066 0.24409E+04 153 spinel -1.89 -3.89 -2.00 -0.133 0.74408E+04 160 stilpnomelane-Mg 4.07 -0.22 -4.29 -0.128 0.15965E+05 161 stishovite 1.58 -1.46 -3.04 -1.013 0.11327E+05 162 sudoite-Fe -10.85 -15.70 -4.85 -0.156 0.18065E+05 163 sudoite -8.45 -12.17 -3.72 -0.120 0.13869E+05 164 sulfur -11.57 -13.06 -1.49 -0.457 0.55388E+04 165 sylvite -1.64 -4.27 -2.63 -1.316 0.98088E+04 166 talc 6.03 4.26 -1.77 -0.104 0.65897E+04 167 talc-Fe 2.92 -1.03 -3.96 -0.233 0.14743E+05 168 talc-tschermaks -2.30 -4.91 -2.61 -0.154 0.97218E+04 170 tephroite 7.35 5.69 -1.66 -0.237 0.61724E+04 173 topaz-H -6.03 -8.72 -2.70 -0.245 0.10047E+05 176 troilite-low -8.61 -9.50 -0.88 -0.294 0.32871E+04 180 wadsleyite-Fe 4.02 1.75 -2.27 -0.324 0.84477E+04 181 wadsleyite-Mg 9.67 5.28 -4.39 -0.627 0.16344E+05 182 wairakite -7.60 -9.56 -1.96 -0.115 0.73010E+04 183 walstromite 4.84 2.09 -2.75 -0.550 0.10248E+05 184 wollastonite 4.40 2.09 -2.31 -0.462 0.86069E+04 185 pseudo-wollastonite 4.53 2.09 -2.44 -0.487 0.90751E+04 186 zoisite -5.03 -8.17 -3.14 -0.143 0.11694E+05 189 beidellite-Ca -11.40 -13.24 -1.84 -0.114 0.68517E+04 190 beidellite-H -11.48 -13.83 -2.35 -0.150 0.87512E+04 191 beidellite-K -10.44 -12.57 -2.13 -0.130 0.79246E+04 192 beidellite-Mg -11.62 -13.27 -1.65 -0.102 0.61591E+04 193 beidellite-Na -10.39 -12.42 -2.03 -0.124 0.75704E+04 194 bornite -57.18 -57.35 -0.17 -0.013 0.62596E+03 196 chalcocite -15.12 -16.53 -1.41 -0.353 0.52638E+04 197 covellite -13.49 -14.80 -1.31 -0.497 0.48651E+04 199 montmorillonite-Ca -8.71 -10.22 -1.51 -0.093 0.56268E+04 200 montmorillonite-K -8.02 -9.55 -1.53 -0.094 0.56920E+04 201 montmorillonite-Mg -8.89 -10.25 -1.35 -0.084 0.50455E+04 202 montmorillonite-Na -7.70 -9.39 -1.70 -0.104 0.63191E+04 203 nontronite-Ca -2.98 -4.73 -1.74 -0.113 0.64972E+04 204 nontronite-H -3.07 -5.32 -2.25 -0.151 0.83706E+04 205 nontronite-K -2.03 -4.06 -2.03 -0.130 0.75629E+04 206 nontronite-Mg -3.17 -4.76 -1.59 -0.103 0.59085E+04 207 nontronite-Na -1.97 -3.90 -1.94 -0.124 0.72196E+04 212 gypsum -13.10 -15.39 -2.29 -0.572 0.85199E+04 229 alabandite -6.43 -7.52 -1.09 -0.363 0.40612E+04 231 anglesite -15.79 -18.09 -2.30 -1.150 0.85708E+04 235 boehmite -2.45 -3.63 -1.18 -0.197 0.44122E+04 239 copper,native 1.68 -1.73 -3.41 -1.186 0.12707E+05 241 ferrous-oxide 2.68 1.61 -1.07 -0.267 0.39812E+04 242 galena -10.25 -10.26 -0.00 -0.001 0.14813E+02 243 silver,native 0.33 -4.28 -4.61 -1.605 0.17187E+05 245 litharge 5.56 0.84 -4.72 -1.180 0.17578E+05 253 wurtzite -10.23 -11.06 -0.83 -0.277 0.30918E+04 254 zincite 2.73 0.04 -2.68 -0.671 0.99940E+04 255 an20ab80 -4.20 -4.32 -0.12 -0.009 0.44248E+03 256 an25ab75 -4.33 -4.47 -0.13 -0.010 0.49653E+03 257 an30ab70 -4.46 -4.61 -0.15 -0.012 0.57318E+03 258 tr.625ac.25prg.125 12.33 9.17 -3.16 -0.085 0.11777E+05 Calculations done for 541.0000 Deg. C; 848.0000 bar Temperature changed by -1.000 degrees to 540.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 64 Loop limit = 500 Temperature = 540.00 C Pressure = 838.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9936E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9971 Stoichiometric ionic strength = .3268595E+01 Osmotic coef. = 0.0000 True ionic strength = .1755244E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54756E-05 -5.2616 0.60682E-06 -6.2169 0.11082E+00 -0.9554 2 H2O 0.99707E+00 -0.0013 0.99707E+00 -0.0013 3 Cl- 0.14734E+00 -0.8317 0.12661E-01 -1.8975 0.85931E-01 -1.0658 4 SO4-- 0.15906E-02 -2.7985 0.28048E-06 -6.5521 0.17634E-03 -3.7536 5 HCO3- 0.69840E-05 -5.1559 0.66630E-06 -6.1763 0.95404E-01 -1.0204 6 HS- 0.13986E-03 -3.8543 0.12158E-04 -4.9151 0.86929E-01 -1.0608 7 H4SiO4 0.33485E-01 -1.4751 0.33485E-01 -1.4751 0.10000E+01 0.0000 8 Al+++ 0.26097E-13 -13.5834 0.62138E-22 -22.2066 0.23810E-08 -8.6232 9 Ca++ 0.10774E-04 -4.9676 0.13742E-08 -8.8619 0.12755E-03 -3.8943 10 Mg++ 0.89424E-05 -5.0485 0.86339E-09 -9.0638 0.96550E-04 -4.0152 11 Fe++ 0.15274E-06 -6.8160 0.15821E-10 -10.8008 0.10358E-03 -3.9847 12 K+ 0.40033E-01 -1.3976 0.39464E-02 -2.4038 0.98579E-01 -1.0062 13 Na+ 0.13234E+00 -0.8783 0.11528E-01 -1.9382 0.87110E-01 -1.0599 14 Mn++ 0.13720E-04 -4.8626 0.14962E-08 -8.8250 0.10905E-03 -3.9624 15 Zn++ 0.41686E-08 -8.3800 0.43179E-12 -12.3647 0.10358E-03 -3.9847 16 Cu+ 0.13386E-07 -7.8733 0.11617E-08 -8.9349 0.86785E-01 -1.0616 17 Pb++ 0.17651E-07 -7.7532 0.26501E-11 -11.5767 0.15014E-03 -3.8235 18 Ag+ 0.29386E-10 -10.5319 0.28323E-11 -11.5479 0.96382E-01 -1.0160 19 Ba++ 0.34713E-06 -6.4595 0.57809E-10 -10.2380 0.16654E-03 -3.7785 20 HPO4-- 0.92068E-08 -8.0359 0.16353E-11 -11.7864 0.17762E-03 -3.7505 21 HSiO3- 0.15201E-05 -5.8181 0.13063E-06 -6.8840 0.85931E-01 -1.0658 22 Ca(HSiO3)+ 0.47804E-08 -8.3205 0.47721E-09 -9.3213 0.99827E-01 -1.0007 23 Mg(HSiO3)+ 0.11334E-08 -8.9456 0.11315E-09 -9.9464 0.99827E-01 -1.0007 24 NaHSiO3,aq 0.17728E-05 -5.7513 0.17728E-05 -5.7513 0.10000E+01 0.0000 28 AgCl,aq 0.10345E-07 -7.9853 0.10345E-07 -7.9853 0.10000E+01 0.0000 29 AgCl2- 0.52816E-06 -6.2772 0.45385E-07 -7.3431 0.85931E-01 -1.0658 30 AgCl3-2 0.50980E-06 -6.2926 0.80450E-10 -10.0945 0.15781E-03 -3.8019 31 AgCl4-3 0.77076E-05 -5.1131 0.15502E-13 -13.8096 0.20113E-08 -8.6965 34 Ag(HS),aq 0.22685E-09 -9.6443 0.22685E-09 -9.6443 0.10000E+01 0.0000 35 Ag(HS)2- 0.70940E-09 -9.1491 0.60960E-10 -10.2150 0.85931E-01 -1.0658 36 AlO+ 0.34577E-10 -10.4612 0.34517E-11 -11.4620 0.99827E-01 -1.0007 38 HAlO2,aq 0.53110E-08 -8.2748 0.53110E-08 -8.2748 0.10000E+01 0.0000 39 AlO2- 0.15734E-04 -4.8032 0.11280E-05 -5.9477 0.71692E-01 -1.1445 41 Ba(HCO3)+ 0.13638E-06 -6.8652 0.14416E-07 -7.8411 0.10570E+00 -0.9759 42 BaCl+ 0.66222E-05 -5.1790 0.66108E-06 -6.1797 0.99827E-01 -1.0007 43 CH4,aq 0.11890E-08 -8.9248 0.13811E-08 -8.8598 0.11616E+01 0.0651 48 CO,aq 0.35797E-03 -3.4462 0.35797E-03 -3.4462 0.10000E+01 0.0000 49 CO2,aq 0.26729E+01 0.4270 0.31049E+01 0.4920 0.11616E+01 0.0651 50 CO3-2 0.18499E-09 -9.7329 0.29192E-13 -13.5347 0.15781E-03 -3.8019 52 Ca(HCO3)+ 0.63025E-07 -7.2005 0.62917E-08 -8.2012 0.99827E-01 -1.0007 53 CaCl+ 0.76783E-04 -4.1147 0.76651E-05 -5.1155 0.99827E-01 -1.0007 54 CaCl2,aq 0.60065E-04 -4.2214 0.60065E-04 -4.2214 0.10000E+01 0.0000 55 CaOH+ 0.13735E-06 -6.8622 0.13712E-07 -7.8629 0.99827E-01 -1.0007 56 CaSO4,aq 0.21884E-06 -6.6599 0.21884E-06 -6.6599 0.10000E+01 0.0000 57 HCl,aq 0.75879E-02 -2.1199 0.75879E-02 -2.1199 0.10000E+01 0.0000 66 CuCl,aq 0.18323E-04 -4.7370 0.18323E-04 -4.7370 0.10000E+01 0.0000 67 CuCl2- 0.81058E-04 -4.0912 0.69654E-05 -5.1571 0.85931E-01 -1.0658 68 CuCl3-2 0.43864E-05 -5.3579 0.69220E-09 -9.1598 0.15781E-03 -3.8019 74 FeCl+ 0.31758E-06 -6.4981 0.31703E-07 -7.4989 0.99827E-01 -1.0007 75 FeCl2,aq 0.15899E-02 -2.7986 0.15899E-02 -2.7986 0.10000E+01 0.0000 77 FeO,aq 0.39442E-07 -7.4040 0.39442E-07 -7.4040 0.10000E+01 0.0000 78 FeOH+ 0.25376E-07 -7.5956 0.25332E-08 -8.5963 0.99827E-01 -1.0007 79 HFeO2- 0.60062E-08 -8.2214 0.51612E-09 -9.2873 0.85931E-01 -1.0658 82 FeO2- 0.32234E-08 -8.4917 0.27699E-09 -9.5575 0.85931E-01 -1.0658 83 HFeO2,aq 0.28081E-09 -9.5516 0.28081E-09 -9.5516 0.10000E+01 0.0000 84 H2,aq 0.41396E-02 -2.3830 0.48087E-02 -2.3180 0.11616E+01 0.0651 85 KCl,aq 0.68338E-01 -1.1653 0.68338E-01 -1.1653 0.10000E+01 0.0000 86 KHSO4,aq 0.11063E-01 -1.9561 0.11063E-01 -1.9561 0.10000E+01 0.0000 87 KOH,aq 0.12653E-05 -5.8978 0.12653E-05 -5.8978 0.10000E+01 0.0000 88 KSO4- 0.60995E-02 -2.2147 0.52413E-03 -3.2806 0.85931E-01 -1.0658 90 Mg(HCO3)+ 0.11281E-07 -7.9477 0.11261E-08 -8.9484 0.99827E-01 -1.0007 91 MgCl+ 0.11462E-04 -4.9407 0.11442E-05 -5.9415 0.99827E-01 -1.0007 92 MgOH+ 0.39289E-06 -6.4057 0.39221E-07 -7.4065 0.99827E-01 -1.0007 94 MnO,aq 0.70536E-07 -7.1516 0.70536E-07 -7.1516 0.10000E+01 0.0000 95 MnOH+ 0.23566E-06 -6.6277 0.23525E-07 -7.6285 0.99827E-01 -1.0007 97 HMnO2- 0.36891E-10 -10.4331 0.31701E-11 -11.4989 0.85931E-01 -1.0658 100 MnCl+ 0.11427E-02 -2.9421 0.11407E-03 -3.9428 0.99827E-01 -1.0007 101 MnSO4,aq 0.22203E-06 -6.6536 0.22203E-06 -6.6536 0.10000E+01 0.0000 102 NaCl,aq 0.42583E+00 -0.3708 0.42583E+00 -0.3708 0.10000E+01 0.0000 103 NaOH,aq 0.16525E-05 -5.7819 0.16525E-05 -5.7819 0.10000E+01 0.0000 105 OH- 0.99338E-05 -5.0029 0.71217E-06 -6.1474 0.71692E-01 -1.1445 110 HPO3-2 0.32789E-10 -10.4843 0.51743E-14 -14.2861 0.15781E-03 -3.8019 111 H3PO3,aq 0.11240E-09 -9.9492 0.11240E-09 -9.9492 0.10000E+01 0.0000 112 H2PO3- 0.12423E-08 -8.9058 0.10675E-09 -9.9716 0.85931E-01 -1.0658 113 H3PO4,aq 0.19319E-05 -5.7140 0.19319E-05 -5.7140 0.10000E+01 0.0000 114 H2PO4- 0.15757E-05 -5.8025 0.14525E-06 -6.8379 0.92179E-01 -1.0354 116 H4P2O7,aq 0.37241E-09 -9.4290 0.37241E-09 -9.4290 0.10000E+01 0.0000 117 H3P2O7- 0.96691E-09 -9.0146 0.83087E-10 -10.0805 0.85931E-01 -1.0658 118 H2P2O7-2 0.69449E-06 -6.1583 0.10959E-09 -9.9602 0.15781E-03 -3.8019 119 HP2O7-3 0.18561E-05 -5.7314 0.37332E-14 -14.4279 0.20113E-08 -8.6965 120 P2O7-4 0.26709E-09 -9.5733 0.47154E-24 -24.3265 0.17655E-14 -14.7531 121 PbCl+ 0.11574E-05 -5.9365 0.11554E-06 -6.9373 0.99827E-01 -1.0007 122 PbCl2,aq 0.70948E-04 -4.1491 0.70948E-04 -4.1491 0.10000E+01 0.0000 123 PbCl3- 0.11109E-03 -3.9543 0.95465E-05 -5.0202 0.85931E-01 -1.0658 124 PbCl4-2 0.52369E-04 -4.2809 0.82641E-08 -8.0828 0.15781E-03 -3.8019 125 PbO,aq 0.58441E-08 -8.2333 0.58441E-08 -8.2333 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.92610E-04 -4.0333 0.92610E-04 -4.0333 0.10000E+01 0.0000 128 Pb(HS)3- 0.14161E-04 -4.8489 0.12169E-05 -5.9148 0.85931E-01 -1.0658 129 H2S,aq 0.10604E+01 0.0255 0.12318E+01 0.0905 0.11616E+01 0.0651 130 S2-2 0.49389E-07 -7.3064 0.77939E-11 -11.1082 0.15781E-03 -3.8019 131 S3-2 0.42552E-08 -8.3711 0.67150E-12 -12.1730 0.15781E-03 -3.8019 132 S3- 0.75859E-02 -2.1200 0.65187E-03 -3.1858 0.85931E-01 -1.0658 133 S4-2 0.31792E-09 -9.4977 0.50170E-13 -13.2996 0.15781E-03 -3.8019 134 S5-2 0.20991E-10 -10.6780 0.33125E-14 -14.4798 0.15781E-03 -3.8019 135 SO2,aq 0.29305E+00 -0.5331 0.29305E+00 -0.5331 0.10000E+01 0.0000 136 SO3-2 0.31425E-08 -8.5027 0.96792E-12 -12.0142 0.30800E-03 -3.5114 137 HSO3- 0.23000E-03 -3.6383 0.19764E-04 -4.7041 0.85931E-01 -1.0658 138 HSO4- 0.88059E-02 -2.0552 0.91530E-03 -3.0384 0.10394E+00 -0.9832 140 S2O3-2 0.25590E-05 -5.5919 0.40383E-09 -9.3938 0.15781E-03 -3.8019 141 HS2O3- 0.35913E-06 -6.4447 0.30861E-07 -7.5106 0.85931E-01 -1.0658 142 H2S2O3,aq 0.49602E-07 -7.3045 0.49602E-07 -7.3045 0.10000E+01 0.0000 150 S4O6-2 0.17225E-08 -8.7638 0.27183E-12 -12.5657 0.15781E-03 -3.8019 152 ZnCl+ 0.12741E-03 -3.8948 0.12719E-04 -4.8955 0.99827E-01 -1.0007 153 ZnCl2,aq 0.44431E-03 -3.3523 0.44431E-03 -3.3523 0.10000E+01 0.0000 154 ZnCl3- 0.29509E-04 -4.5300 0.25357E-05 -5.5959 0.85931E-01 -1.0658 155 ZnO,aq 0.21578E-07 -7.6660 0.21578E-07 -7.6660 0.10000E+01 0.0000 156 ZnOH+ 0.96423E-06 -6.0158 0.96257E-07 -7.0166 0.99827E-01 -1.0007 158 HZnO2- 0.21732E-09 -9.6629 0.18674E-10 -10.7288 0.85931E-01 -1.0658 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5475577E-05 0.4292783E+01 0.3545219E+04 0.0000 2 H2O 0.1000000E+01 0.5252720E+02 0.7753453E+06 0.0000 3 Cl- 0.1473448E+00 0.6556559E+00 0.1904576E+05 4.3194 4 SO4-- 0.1590556E-02 0.2511411E+00 0.1976683E+05 5.8818 5 HCO3- 0.6983995E-05 0.2673218E+01 0.1336460E+06 0.0406 6 HS- 0.1398593E-03 0.1153209E+01 0.3124912E+05 1.3018 7 H4SiO4 0.3348510E-01 0.3348840E-01 0.2637283E+04 -1.4751 8 Al+++ 0.2609727E-13 0.1573930E-04 0.3479532E+00 -3.5558 9 Ca++ 0.1077447E-04 0.1480473E-03 0.4861562E+01 3.5719 10 Mg++ 0.8942438E-05 0.2080980E-04 0.4145320E+00 3.3701 11 Fe++ 0.1527396E-06 0.1590491E-02 0.7277807E+02 1.6331 12 K+ 0.4003286E-01 0.1255345E+00 0.4021901E+04 3.8131 13 Na+ 0.1323373E+00 0.5581708E+00 0.1051409E+05 4.2787 14 Mn++ 0.1371994E-04 0.1156903E-02 0.5207617E+02 3.6089 15 Zn++ 0.4168597E-08 0.6022185E-03 0.3225536E+02 0.0692 16 Cu+ 0.1338650E-07 0.1037808E-03 0.5402985E+01 -2.7179 17 Pb++ 0.1765074E-07 0.3423633E-03 0.5811997E+02 0.8571 18 Ag+ 0.2938602E-10 0.8756873E-05 0.7739611E+00 -5.3309 19 Ba++ 0.3471271E-06 0.7105726E-05 0.7996039E+00 2.1959 20 HPO4-- 0.9206784E-08 0.8622673E-05 0.6780903E+00 0.6475 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265316E+01 -.2953518E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5219110E+02 -.2263208E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2495341E+00 0.2188670E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1145830E+01 0.1431430E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3327412E-01 0.1103202E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1563859E-04 0.6789009E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1471000E-03 0.3808099E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1580314E-02 0.7186439E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247312E+00 0.6789009E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.5983651E-03 0.1700970E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1031168E-03 0.2964929E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.7060259E-05 0.4831219E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1355E-18 Mass of aqueous solution: 0.121267E+04 g Temperature = 540.00 C Pressure = 838.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3808E-03 -3.419 0.5184E-01 -1.285 0.6643 0.1750E-01 microcline 0.6789E-03 -3.168 0.1890 -0.724 2.421 0.7381E-01 pyrite 0.6890E-02 -2.162 0.8267 -0.083 10.59 0.1649 quartz 0.1083 -0.965 6.506 0.813 83.36 2.457 barite 0.4831E-04 -4.316 0.1128E-01 -1.948 0.1445 0.2517E-02 chalcopyrite 0.2965E-03 -3.528 0.5441E-01 -1.264 0.6971 0.1270E-01 sphalerite 0.1701E-02 -2.769 0.1657 -0.781 2.123 0.4053E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.804545 g Volume = 2.768818 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.41 -15.41 0.00 0.000 0.00000E+00 112 microcline -4.16 -4.16 0.00 0.000 -0.66095E-11 137 pyrite -22.59 -22.59 -0.00 -0.000 0.13219E-10 141 quartz -1.47 -1.47 0.00 0.000 0.00000E+00 234 barite -16.79 -16.79 0.00 0.000 0.00000E+00 237 chalcopyrite -24.33 -24.33 -0.00 -0.000 0.13219E-10 252 sphalerite -11.06 -11.06 0.00 0.000 -0.66095E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.247 0.91915E+03 2.676 2 CO2,gas -10.58 -12.39 -1.81 -0.603 0.67313E+04 1.114 3 CH4,gas 6.74 -4.54 -11.28 -2.819 0.41958E+05 -8.353 4 H2,gas 6.08 1.96 -4.12 -2.356 0.15338E+05 -1.199 5 H2S,gas -8.81 -11.13 -2.32 -1.162 0.86502E+04 0.598 6 CO,gas -4.16 -10.43 -6.27 -1.929 0.23331E+05 -3.347 7 SO3,gas -8.07 -18.98 -10.92 -2.729 0.40614E+05 -7.992 8 O2,gas 17.29 -3.93 -21.22 -14.145 0.78945E+05 -18.294 9 HCl,gas -6.40 -8.11 -1.71 -0.857 0.63759E+04 -1.714 10 acmite 3.68 1.98 -1.70 -0.176 0.63190E+04 12 akimotoite 6.70 1.90 -4.81 -0.962 0.17888E+05 13 akimotoite-Fe 4.47 0.16 -4.32 -0.863 0.16056E+05 14 albite-high -3.51 -3.70 -0.19 -0.015 0.70654E+03 15 albite -3.53 -3.70 -0.17 -0.013 0.63606E+03 16 almandine -4.13 -6.64 -2.51 -0.125 0.93352E+04 17 pyrope 2.95 -1.43 -4.38 -0.219 0.16279E+05 18 analcite -1.19 -2.23 -1.03 -0.115 0.38484E+04 19 andalusite -7.97 -8.59 -0.62 -0.062 0.23029E+04 24 anorthite -5.48 -6.49 -1.01 -0.078 0.37712E+04 26 anthophyllite-Fe 3.82 -0.36 -4.18 -0.113 0.15536E+05 27 apatite-OH -54.48 -54.80 -0.32 -0.025 0.12090E+04 28 apatite-OH-zs -52.22 -54.80 -2.58 -0.199 0.96110E+04 29 apatite-Cl-zs -59.26 -62.92 -3.66 -0.305 0.13620E+05 30 aragonite -4.89 -8.82 -3.93 -1.310 0.14623E+05 31 brucite 6.13 3.37 -2.76 -0.552 0.10261E+05 32 calcite -5.00 -8.82 -3.82 -1.273 0.14205E+05 33 carnegieite-low 1.11 -0.75 -1.86 -0.265 0.69131E+04 34 carnegieite-high 1.20 -0.75 -1.96 -0.280 0.72811E+04 35 carpholite-Mg -4.16 -6.69 -2.54 -0.169 0.94390E+04 36 carpholite-Fe -5.61 -8.43 -2.82 -0.188 0.10483E+05 37 celadonite 0.32 -2.27 -2.59 -0.153 0.96482E+04 38 celadonite-Fe -1.17 -4.01 -2.83 -0.167 0.10547E+05 39 chrysotile 10.94 7.16 -3.78 -0.315 0.14081E+05 41 clinochlore 8.95 5.31 -3.65 -0.114 0.13567E+05 42 daphnite 1.37 -3.38 -4.75 -0.148 0.17660E+05 45 chloritoid-Mg -3.35 -5.22 -1.88 -0.125 0.69770E+04 46 chloritoid-Fe -5.43 -6.96 -1.52 -0.102 0.56698E+04 47 chloritoid-Mn -3.31 -4.98 -1.67 -0.111 0.62219E+04 49 coesite -1.17 -1.47 -0.30 -0.101 0.11242E+04 50 cordierite-H -12.79 -14.86 -2.07 -0.074 0.76959E+04 51 cordierite-Fe -15.62 -18.33 -2.71 -0.093 0.10082E+05 52 cordierite-Mn -11.31 -14.38 -3.07 -0.106 0.11422E+05 53 corundum -6.31 -7.12 -0.80 -0.073 0.29918E+04 55 cristobalite -1.42 -1.47 -0.05 -0.017 0.18460E+03 58 cymrite-K -1.76 -4.16 -2.40 -0.200 0.89352E+04 60 diaspore -2.68 -3.56 -0.87 -0.146 0.32520E+04 62 diopside 6.04 3.99 -2.04 -0.204 0.75976E+04 63 hedenbergite 4.51 2.26 -2.25 -0.225 0.83774E+04 65 eastonite -0.71 -3.07 -2.36 -0.091 0.87958E+04 66 enstatite 5.65 3.79 -1.86 -0.186 0.69067E+04 67 clinoenstatite-HiP 6.16 3.79 -2.37 -0.237 0.88201E+04 68 clinoenstatite 5.63 3.79 -1.84 -0.184 0.68289E+04 69 protoenstatite 5.79 3.79 -2.00 -0.200 0.74312E+04 70 epidote -0.88 -3.74 -2.86 -0.139 0.10633E+05 71 clinozoisite -4.75 -7.95 -3.20 -0.146 0.11917E+05 72 epidote-Fe 4.70 0.47 -4.24 -0.220 0.15761E+05 73 fayalite 3.19 1.79 -1.40 -0.200 0.52129E+04 74 ferrosilite 1.82 0.32 -1.50 -0.150 0.55976E+04 75 forsterite 7.44 5.27 -2.18 -0.311 0.81043E+04 76 gedrite -1.51 -6.22 -4.72 -0.127 0.17551E+05 78 gibbsite -1.05 -3.56 -2.51 -0.359 0.93481E+04 79 glaucophane 4.29 -0.24 -4.52 -0.122 0.16822E+05 81 goethite 1.64 0.65 -0.99 -0.214 0.36768E+04 83 greenalite 5.71 1.95 -3.76 -0.314 0.14006E+05 84 grunerite 4.41 -0.36 -4.77 -0.129 0.17739E+05 85 halite -1.76 -3.84 -2.08 -1.039 0.77306E+04 86 hematite 1.72 1.30 -0.42 -0.051 0.15790E+04 87 heulandite -10.44 -13.86 -3.42 -0.155 0.12714E+05 88 hercynite -4.00 -5.48 -1.48 -0.099 0.55163E+04 91 jadeite -0.51 -2.22 -1.72 -0.172 0.63896E+04 93 kalsilite 0.47 -1.22 -1.69 -0.241 0.62856E+04 94 kaolinite -7.31 -10.06 -2.75 -0.250 0.10230E+05 95 kyanite -7.80 -8.59 -0.79 -0.079 0.29260E+04 97 laumontite -5.58 -9.44 -3.86 -0.257 0.14352E+05 98 lawsonite -2.74 -6.49 -3.75 -0.250 0.13957E+05 99 leucite -1.67 -2.69 -1.02 -0.102 0.37986E+04 101 lizardite 11.09 7.16 -3.93 -0.328 0.14631E+05 102 magnesite -5.51 -9.02 -3.51 -1.170 0.13055E+05 103 magnetite 3.50 2.93 -0.56 -0.046 0.20975E+04 104 minnesotaite 1.51 -1.00 -2.51 -0.148 0.93419E+04 105 minnesotaite-Mg 7.87 4.21 -3.65 -0.215 0.13593E+05 106 magnesioferrite 6.74 4.67 -2.07 -0.169 0.76877E+04 108 manganosite 5.98 3.61 -2.37 -0.593 0.88229E+04 109 margarite -11.38 -13.61 -2.23 -0.089 0.82905E+04 113 monticellite 9.73 5.47 -4.26 -0.609 0.15867E+05 115 mullite-Si -7.18 -8.59 -1.41 -0.141 0.52429E+04 116 muscovite -10.38 -11.28 -0.90 -0.053 0.33506E+04 117 paragonite -9.68 -10.81 -1.13 -0.067 0.42211E+04 118 nepheline 0.79 -0.75 -1.55 -0.221 0.57528E+04 119 osumilite(2) -9.35 -12.95 -3.60 -0.075 0.13411E+05 120 osumilite-Fe -22.28 -25.44 -3.16 -0.066 0.11769E+05 122 periclase 6.37 3.37 -3.00 -0.750 0.11166E+05 123 periclase-Fe 3.65 1.63 -2.02 -0.506 0.75251E+04 124 perovskite-Al -4.52 -7.12 -2.60 -0.236 0.96563E+04 129 phlogopite-Na 8.72 6.41 -2.31 -0.128 0.85914E+04 131 prehnite -0.61 -4.39 -3.78 -0.223 0.14082E+05 132 prehnite-Fe 3.66 -0.19 -3.84 -0.231 0.14301E+05 135 px-Mg-tschermaks -2.63 -5.22 -2.59 -0.185 0.96409E+04 136 px-Ca-tschermaks -2.06 -5.02 -2.96 -0.211 0.11009E+05 138 pyrrhotite -8.70 -9.50 -0.80 -0.266 0.29727E+04 139 pyrrhotiteFe0.875 -9.56 -9.95 -0.38 -0.141 0.14281E+04 140 pyrophyllite -11.55 -13.01 -1.46 -0.091 0.54169E+04 143 riebeckite 6.55 2.97 -3.58 -0.099 0.13311E+05 144 ringwoodite-Fe 4.21 1.79 -2.41 -0.345 0.89839E+04 146 rhodochrosite -5.64 -8.78 -3.14 -1.048 0.11697E+05 147 rhodonite 2.83 2.13 -0.70 -0.139 0.25868E+04 148 sanidine -3.61 -4.16 -0.56 -0.043 0.20688E+04 150 siderite -7.48 -10.76 -3.28 -1.093 0.12201E+05 151 sillimanite -7.93 -8.59 -0.66 -0.066 0.24666E+04 153 spinel -1.70 -3.75 -2.04 -0.136 0.75978E+04 160 stilpnomelane-Mg 4.31 -0.15 -4.46 -0.133 0.16612E+05 161 stishovite 1.57 -1.47 -3.04 -1.015 0.11325E+05 162 sudoite-Fe -10.52 -15.39 -4.87 -0.157 0.18123E+05 163 sudoite -8.11 -11.92 -3.81 -0.123 0.14167E+05 164 sulfur -11.61 -13.09 -1.49 -0.458 0.55381E+04 165 sylvite -1.67 -4.30 -2.63 -1.317 0.98026E+04 166 talc 6.09 4.21 -1.87 -0.110 0.69719E+04 167 talc-Fe 2.97 -1.00 -3.97 -0.233 0.14764E+05 168 talc-tschermaks -2.11 -4.80 -2.69 -0.158 0.99993E+04 170 tephroite 7.40 5.74 -1.65 -0.236 0.61518E+04 173 topaz-H -5.89 -8.59 -2.70 -0.246 0.10059E+05 176 troilite-low -8.61 -9.50 -0.89 -0.295 0.32962E+04 180 wadsleyite-Fe 4.07 1.79 -2.28 -0.325 0.84696E+04 181 wadsleyite-Mg 9.73 5.27 -4.46 -0.638 0.16607E+05 182 wairakite -7.47 -9.44 -1.97 -0.116 0.73282E+04 183 walstromite 4.86 2.10 -2.76 -0.552 0.10261E+05 184 wollastonite 4.41 2.10 -2.32 -0.463 0.86187E+04 185 pseudo-wollastonite 4.54 2.10 -2.44 -0.488 0.90876E+04 186 zoisite -4.79 -7.95 -3.16 -0.144 0.11753E+05 189 beidellite-Ca -11.26 -13.11 -1.85 -0.114 0.68732E+04 190 beidellite-H -11.34 -13.70 -2.36 -0.150 0.87698E+04 191 beidellite-K -10.30 -12.44 -2.13 -0.131 0.79401E+04 192 beidellite-Mg -11.47 -13.14 -1.67 -0.103 0.62016E+04 193 beidellite-Na -10.24 -12.28 -2.04 -0.125 0.75866E+04 194 bornite -57.30 -57.47 -0.16 -0.012 0.60974E+03 196 chalcocite -15.16 -16.57 -1.41 -0.353 0.52520E+04 197 covellite -13.53 -14.83 -1.30 -0.497 0.48537E+04 199 montmorillonite-Ca -8.60 -10.13 -1.53 -0.094 0.56831E+04 200 montmorillonite-K -7.92 -9.46 -1.54 -0.095 0.57455E+04 201 montmorillonite-Mg -8.79 -10.17 -1.38 -0.085 0.51216E+04 202 montmorillonite-Na -7.60 -9.31 -1.71 -0.105 0.63694E+04 203 nontronite-Ca -2.94 -4.69 -1.75 -0.113 0.65069E+04 204 nontronite-H -3.03 -5.28 -2.25 -0.151 0.83769E+04 205 nontronite-K -1.99 -4.02 -2.03 -0.131 0.75664E+04 206 nontronite-Mg -3.13 -4.72 -1.60 -0.104 0.59377E+04 207 nontronite-Na -1.93 -3.87 -1.94 -0.125 0.72235E+04 212 gypsum -13.13 -15.42 -2.29 -0.572 0.85148E+04 229 alabandite -6.43 -7.52 -1.09 -0.363 0.40530E+04 231 anglesite -15.83 -18.13 -2.30 -1.149 0.85493E+04 235 boehmite -2.37 -3.56 -1.19 -0.198 0.44203E+04 239 copper,native 1.68 -1.74 -3.41 -1.187 0.12695E+05 241 ferrous-oxide 2.71 1.63 -1.07 -0.268 0.39946E+04 242 galena -10.27 -10.27 -0.00 -0.000 0.34445E+01 243 silver,native 0.33 -4.35 -4.68 -1.627 0.17405E+05 245 litharge 5.58 0.86 -4.72 -1.180 0.17565E+05 253 wurtzite -10.23 -11.06 -0.83 -0.277 0.30915E+04 254 zincite 2.75 0.07 -2.69 -0.671 0.99938E+04 255 an20ab80 -4.13 -4.26 -0.12 -0.009 0.45483E+03 256 an25ab75 -4.26 -4.40 -0.14 -0.011 0.51085E+03 257 an30ab70 -4.38 -4.54 -0.16 -0.012 0.58954E+03 258 tr.625ac.25prg.125 12.48 9.18 -3.31 -0.089 0.12298E+05 Calculations done for 540.0000 Deg. C; 838.0000 bar Temperature changed by -1.000 degrees to 539.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 66 Loop limit = 500 Temperature = 539.00 C Pressure = 829.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9936E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9971 Stoichiometric ionic strength = .3268304E+01 Osmotic coef. = 0.0000 True ionic strength = .1764677E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54768E-05 -5.2615 0.58960E-06 -6.2294 0.10765E+00 -0.9680 2 H2O 0.99708E+00 -0.0013 0.99708E+00 -0.0013 3 Cl- 0.14788E+00 -0.8301 0.12290E-01 -1.9105 0.83105E-01 -1.0804 4 SO4-- 0.17373E-02 -2.7601 0.27198E-06 -6.5655 0.15655E-03 -3.8053 5 HCO3- 0.68599E-05 -5.1637 0.63380E-06 -6.1980 0.92393E-01 -1.0344 6 HS- 0.14104E-03 -3.8507 0.11859E-04 -4.9260 0.84083E-01 -1.0753 7 H4SiO4 0.32854E-01 -1.4834 0.32854E-01 -1.4834 0.10000E+01 0.0000 8 Al+++ 0.36682E-13 -13.4355 0.66294E-22 -22.1785 0.18073E-08 -8.7430 9 Ca++ 0.11867E-04 -4.9257 0.13374E-08 -8.8737 0.11270E-03 -3.9481 10 Mg++ 0.94457E-05 -5.0248 0.80289E-09 -9.0953 0.85001E-04 -4.0706 11 Fe++ 0.17132E-06 -6.7662 0.15637E-10 -10.8058 0.91275E-04 -4.0396 12 K+ 0.40148E-01 -1.3963 0.38343E-02 -2.4163 0.95502E-01 -1.0200 13 Na+ 0.13301E+00 -0.8761 0.11206E-01 -1.9505 0.84253E-01 -1.0744 14 Mn++ 0.15468E-04 -4.8106 0.14875E-08 -8.8276 0.96162E-04 -4.0170 15 Zn++ 0.46922E-08 -8.3286 0.42828E-12 -12.3683 0.91275E-04 -4.0396 16 Cu+ 0.13306E-07 -7.8759 0.11169E-08 -8.9520 0.83934E-01 -1.0761 17 Pb++ 0.19147E-07 -7.7179 0.25459E-11 -11.5942 0.13297E-03 -3.8763 18 Ag+ 0.25204E-10 -10.5985 0.23527E-11 -11.6284 0.93346E-01 -1.0299 19 Ba++ 0.37262E-06 -6.4287 0.55034E-10 -10.2594 0.14769E-03 -3.8306 20 HPO4-- 0.94737E-08 -8.0235 0.14941E-11 -11.8256 0.15771E-03 -3.8021 21 HSiO3- 0.15279E-05 -5.8159 0.12698E-06 -6.8963 0.83105E-01 -1.0804 22 Ca(HSiO3)+ 0.47872E-08 -8.3199 0.46306E-09 -9.3344 0.96729E-01 -1.0144 23 Mg(HSiO3)+ 0.10948E-08 -8.9607 0.10589E-09 -9.9751 0.96729E-01 -1.0144 24 NaHSiO3,aq 0.17768E-05 -5.7504 0.17768E-05 -5.7504 0.10000E+01 0.0000 28 AgCl,aq 0.88639E-08 -8.0524 0.88639E-08 -8.0524 0.10000E+01 0.0000 29 AgCl2- 0.45273E-06 -6.3442 0.37624E-07 -7.4245 0.83105E-01 -1.0804 30 AgCl3-2 0.45642E-06 -6.3406 0.63849E-10 -10.1948 0.13989E-03 -3.8542 31 AgCl4-3 0.78379E-05 -5.1058 0.11949E-13 -13.9227 0.15245E-08 -8.8169 34 Ag(HS),aq 0.19772E-09 -9.7039 0.19772E-09 -9.7039 0.10000E+01 0.0000 35 Ag(HS)2- 0.61168E-09 -9.2135 0.50834E-10 -10.2938 0.83105E-01 -1.0804 36 AlO+ 0.36666E-10 -10.4357 0.35467E-11 -11.4502 0.96729E-01 -1.0144 38 HAlO2,aq 0.53579E-08 -8.2710 0.53579E-08 -8.2710 0.10000E+01 0.0000 39 AlO2- 0.15942E-04 -4.7975 0.11029E-05 -5.9575 0.69179E-01 -1.1600 41 Ba(HCO3)+ 0.13282E-06 -6.8767 0.13615E-07 -7.8660 0.10250E+00 -0.9893 42 BaCl+ 0.65052E-05 -5.1867 0.62924E-06 -6.2012 0.96729E-01 -1.0144 43 CH4,aq 0.11785E-08 -8.9287 0.13671E-08 -8.8642 0.11601E+01 0.0645 48 CO,aq 0.35212E-03 -3.4533 0.35212E-03 -3.4533 0.10000E+01 0.0000 49 CO2,aq 0.26728E+01 0.4270 0.31007E+01 0.4915 0.11601E+01 0.0645 50 CO3-2 0.19966E-09 -9.6997 0.27930E-13 -13.5539 0.13989E-03 -3.8542 52 Ca(HCO3)+ 0.61283E-07 -7.2127 0.59279E-08 -8.2271 0.96729E-01 -1.0144 53 CaCl+ 0.76525E-04 -4.1162 0.74021E-05 -5.1306 0.96729E-01 -1.0144 54 CaCl2,aq 0.59221E-04 -4.2275 0.59221E-04 -4.2275 0.10000E+01 0.0000 55 CaOH+ 0.13688E-06 -6.8637 0.13240E-07 -7.8781 0.96729E-01 -1.0144 56 CaSO4,aq 0.22198E-06 -6.6537 0.22198E-06 -6.6537 0.10000E+01 0.0000 57 HCl,aq 0.79529E-02 -2.0995 0.79529E-02 -2.0995 0.10000E+01 0.0000 66 CuCl,aq 0.18152E-04 -4.7411 0.18152E-04 -4.7411 0.10000E+01 0.0000 67 CuCl2- 0.81041E-04 -4.0913 0.67349E-05 -5.1717 0.83105E-01 -1.0804 68 CuCl3-2 0.45824E-05 -5.3389 0.64102E-09 -9.1931 0.13989E-03 -3.8542 74 FeCl+ 0.32129E-06 -6.4931 0.31078E-07 -7.5075 0.96729E-01 -1.0144 75 FeCl2,aq 0.15392E-02 -2.8127 0.15392E-02 -2.8127 0.10000E+01 0.0000 77 FeO,aq 0.38819E-07 -7.4110 0.38819E-07 -7.4110 0.10000E+01 0.0000 78 FeOH+ 0.25693E-07 -7.5902 0.24853E-08 -8.6046 0.96729E-01 -1.0144 79 HFeO2- 0.60232E-08 -8.2202 0.50056E-09 -9.3005 0.83105E-01 -1.0804 82 FeO2- 0.31892E-08 -8.4963 0.26504E-09 -9.5767 0.83105E-01 -1.0804 83 HFeO2,aq 0.28149E-09 -9.5505 0.28149E-09 -9.5505 0.10000E+01 0.0000 84 H2,aq 0.41310E-02 -2.3839 0.47923E-02 -2.3195 0.11601E+01 0.0645 85 KCl,aq 0.68228E-01 -1.1660 0.68228E-01 -1.1660 0.10000E+01 0.0000 86 KHSO4,aq 0.10975E-01 -1.9596 0.10975E-01 -1.9596 0.10000E+01 0.0000 87 KOH,aq 0.12665E-05 -5.8974 0.12665E-05 -5.8974 0.10000E+01 0.0000 88 KSO4- 0.61809E-02 -2.2090 0.51366E-03 -3.2893 0.83105E-01 -1.0804 90 Mg(HCO3)+ 0.10373E-07 -7.9841 0.10033E-08 -8.9986 0.96729E-01 -1.0144 91 MgCl+ 0.10977E-04 -4.9595 0.10618E-05 -5.9740 0.96729E-01 -1.0144 92 MgOH+ 0.37535E-06 -6.4256 0.36307E-07 -7.4400 0.96729E-01 -1.0144 94 MnO,aq 0.70225E-07 -7.1535 0.70225E-07 -7.1535 0.10000E+01 0.0000 95 MnOH+ 0.23836E-06 -6.6228 0.23056E-07 -7.6372 0.96729E-01 -1.0144 97 HMnO2- 0.37100E-10 -10.4306 0.30832E-11 -11.5110 0.83105E-01 -1.0804 100 MnCl+ 0.11409E-02 -2.9428 0.11036E-03 -3.9572 0.96729E-01 -1.0144 101 MnSO4,aq 0.22783E-06 -6.6424 0.22783E-06 -6.6424 0.10000E+01 0.0000 102 NaCl,aq 0.42515E+00 -0.3715 0.42515E+00 -0.3715 0.10000E+01 0.0000 103 NaOH,aq 0.16524E-05 -5.7819 0.16524E-05 -5.7819 0.10000E+01 0.0000 105 OH- 0.10095E-04 -4.9959 0.69837E-06 -6.1559 0.69179E-01 -1.1600 110 HPO3-2 0.32530E-10 -10.4877 0.45506E-14 -14.3419 0.13989E-03 -3.8542 111 H3PO3,aq 0.10560E-09 -9.9763 0.10560E-09 -9.9763 0.10000E+01 0.0000 112 H2PO3- 0.11393E-08 -8.9434 0.94680E-10 -10.0237 0.83105E-01 -1.0804 113 H3PO4,aq 0.18469E-05 -5.7335 0.18469E-05 -5.7335 0.10000E+01 0.0000 114 H2PO4- 0.14846E-05 -5.8284 0.13247E-06 -6.8779 0.89229E-01 -1.0495 116 H4P2O7,aq 0.34206E-09 -9.4659 0.34206E-09 -9.4659 0.10000E+01 0.0000 117 H3P2O7- 0.85242E-09 -9.0693 0.70840E-10 -10.1497 0.83105E-01 -1.0804 118 H2P2O7-2 0.64177E-06 -6.1926 0.89776E-10 -10.0468 0.13989E-03 -3.8542 119 HP2O7-3 0.19968E-05 -5.6997 0.30442E-14 -14.5165 0.15245E-08 -8.8169 120 P2O7-4 0.36458E-09 -9.4382 0.40107E-24 -24.3968 0.11001E-14 -14.9586 121 PbCl+ 0.11466E-05 -5.9406 0.11091E-06 -6.9550 0.96729E-01 -1.0144 122 PbCl2,aq 0.70113E-04 -4.1542 0.70113E-04 -4.1542 0.10000E+01 0.0000 123 PbCl3- 0.11103E-03 -3.9546 0.92270E-05 -5.0349 0.83105E-01 -1.0804 124 PbCl4-2 0.54497E-04 -4.2636 0.76235E-08 -8.1178 0.13989E-03 -3.8542 125 PbO,aq 0.58264E-08 -8.2346 0.58264E-08 -8.2346 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.91375E-04 -4.0392 0.91375E-04 -4.0392 0.10000E+01 0.0000 128 Pb(HS)3- 0.14173E-04 -4.8485 0.11778E-05 -5.9289 0.83105E-01 -1.0804 129 H2S,aq 0.10606E+01 0.0256 0.12304E+01 0.0900 0.11601E+01 0.0645 130 S2-2 0.52575E-07 -7.2792 0.73546E-11 -11.1334 0.13989E-03 -3.8542 131 S3-2 0.45016E-08 -8.3466 0.62972E-12 -12.2009 0.13989E-03 -3.8542 132 S3- 0.74542E-02 -2.1276 0.61948E-03 -3.2080 0.83105E-01 -1.0804 133 S4-2 0.33464E-09 -9.4754 0.46812E-13 -13.3296 0.13989E-03 -3.8542 134 S5-2 0.22020E-10 -10.6572 0.30803E-14 -14.5114 0.13989E-03 -3.8542 135 SO2,aq 0.29294E+00 -0.5332 0.29294E+00 -0.5332 0.10000E+01 0.0000 136 SO3-2 0.33928E-08 -8.4694 0.93495E-12 -12.0292 0.27557E-03 -3.5598 137 HSO3- 0.22855E-03 -3.6410 0.18994E-04 -4.7214 0.83105E-01 -1.0804 138 HSO4- 0.88130E-02 -2.0549 0.88814E-03 -3.0515 0.10078E+00 -0.9966 140 S2O3-2 0.27495E-05 -5.5607 0.38463E-09 -9.4150 0.13989E-03 -3.8542 141 HS2O3- 0.35707E-06 -6.4472 0.29674E-07 -7.5276 0.83105E-01 -1.0804 142 H2S2O3,aq 0.50525E-07 -7.2965 0.50525E-07 -7.2965 0.10000E+01 0.0000 150 S4O6-2 0.18197E-08 -8.7400 0.25455E-12 -12.5942 0.13989E-03 -3.8542 152 ZnCl+ 0.12558E-03 -3.9011 0.12147E-04 -4.9155 0.96729E-01 -1.0144 153 ZnCl2,aq 0.43608E-03 -3.3604 0.43608E-03 -3.3604 0.10000E+01 0.0000 154 ZnCl3- 0.28721E-04 -4.5418 0.23869E-05 -5.6222 0.83105E-01 -1.0804 155 ZnO,aq 0.21358E-07 -7.6704 0.21358E-07 -7.6704 0.10000E+01 0.0000 156 ZnOH+ 0.95784E-06 -6.0187 0.92650E-07 -7.0332 0.96729E-01 -1.0144 158 HZnO2- 0.21923E-09 -9.6591 0.18219E-10 -10.7395 0.83105E-01 -1.0804 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5476795E-05 0.4292712E+01 0.3545347E+04 0.0000 2 H2O 0.1000000E+01 0.5252767E+02 0.7753932E+06 0.0000 3 Cl- 0.1478799E+00 0.6556455E+00 0.1904647E+05 4.3190 4 SO4-- 0.1737293E-02 0.2511243E+00 0.1976655E+05 5.8934 5 HCO3- 0.6859856E-05 0.2673175E+01 0.1336509E+06 0.0314 6 HS- 0.1410351E-03 0.1153091E+01 0.3124757E+05 1.3035 7 H4SiO4 0.3285419E-01 0.3285750E-01 0.2587735E+04 -1.4834 8 Al+++ 0.3668223E-13 0.1594753E-04 0.3525753E+00 -3.4902 9 Ca++ 0.1186683E-04 0.1480373E-03 0.4861493E+01 3.5852 10 Mg++ 0.9445676E-05 0.2080947E-04 0.4145473E+00 3.3635 11 Fe++ 0.1713221E-06 0.1539767E-02 0.7046072E+02 1.6530 12 K+ 0.4014834E-01 0.1255327E+00 0.4022056E+04 3.8131 13 Na+ 0.1330094E+00 0.5581620E+00 0.1051448E+05 4.2789 14 Mn++ 0.1546821E-04 0.1156884E-02 0.5207809E+02 3.6313 15 Zn++ 0.4692235E-08 0.5913577E-03 0.3167532E+02 0.0906 16 Cu+ 0.1330639E-07 0.1037882E-03 0.5403656E+01 -2.7226 17 Pb++ 0.1914683E-07 0.3423578E-03 0.5812211E+02 0.8647 18 Ag+ 0.2520355E-10 0.8756734E-05 0.7739897E+00 -5.3990 19 Ba++ 0.3726247E-06 0.7010683E-05 0.7889504E+00 2.1995 20 HPO4-- 0.9473682E-08 0.8622536E-05 0.6781153E+00 0.6333 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265313E+01 -.2950867E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5219240E+02 -.2276243E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2495214E+00 0.2201367E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1145731E+01 0.1441324E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3264778E-01 0.1109465E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1584574E-04 0.6786938E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1470925E-03 0.3808174E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1529939E-02 0.7236815E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247314E+00 0.6786938E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.5875832E-03 0.1711752E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1031258E-03 0.2964839E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3401726E-03 0.0000000E+00 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.6965935E-05 0.4840652E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.9080E-18 Mass of aqueous solution: 0.121263E+04 g Temperature = 539.00 C Pressure = 829.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3808E-03 -3.419 0.5184E-01 -1.285 0.6605 0.1750E-01 microcline 0.6787E-03 -3.168 0.1889 -0.724 2.407 0.7379E-01 pyrite 0.6940E-02 -2.159 0.8327 -0.080 10.61 0.1661 quartz 0.1089 -0.963 6.543 0.816 83.36 2.471 barite 0.4841E-04 -4.315 0.1130E-01 -1.947 0.1439 0.2522E-02 chalcopyrite 0.2965E-03 -3.528 0.5440E-01 -1.264 0.6931 0.1270E-01 sphalerite 0.1712E-02 -2.767 0.1668 -0.778 2.125 0.4079E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.849273 g Volume = 2.784489 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.44 -15.44 0.00 0.000 0.00000E+00 112 microcline -4.12 -4.12 -0.00 -0.000 0.19804E-10 137 pyrite -22.62 -22.62 0.00 0.000 0.00000E+00 141 quartz -1.48 -1.48 -0.00 -0.000 0.82518E-12 234 barite -16.82 -16.82 0.00 0.000 0.00000E+00 237 chalcopyrite -24.36 -24.36 0.00 0.000 0.00000E+00 252 sphalerite -11.06 -11.06 0.00 0.000 -0.66014E-11 242 galena -10.29 -10.29 0.00 0.000 -0.18312E+01 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.246 0.91552E+03 2.672 2 CO2,gas -10.61 -12.43 -1.82 -0.605 0.67488E+04 1.103 3 CH4,gas 6.73 -4.56 -11.29 -2.822 0.41955E+05 -8.371 4 H2,gas 6.09 1.97 -4.12 -2.357 0.15328E+05 -1.206 5 H2S,gas -8.83 -11.16 -2.33 -1.163 0.86446E+04 0.592 6 CO,gas -4.18 -10.46 -6.28 -1.933 0.23350E+05 -3.365 7 SO3,gas -8.09 -19.02 -10.93 -2.732 0.40615E+05 -8.011 8 O2,gas 17.31 -3.93 -21.24 -14.163 0.78951E+05 -18.326 9 HCl,gas -6.42 -8.14 -1.72 -0.862 0.64071E+04 -1.724 10 acmite 3.69 1.98 -1.70 -0.177 0.63311E+04 12 akimotoite 6.73 1.88 -4.85 -0.970 0.18024E+05 13 akimotoite-Fe 4.50 0.17 -4.33 -0.865 0.16077E+05 14 albite-high -3.46 -3.66 -0.19 -0.015 0.71415E+03 15 albite -3.48 -3.66 -0.17 -0.013 0.64007E+03 16 almandine -3.94 -6.47 -2.53 -0.127 0.94148E+04 17 pyrope 3.16 -1.34 -4.50 -0.225 0.16709E+05 18 analcite -1.14 -2.18 -1.04 -0.115 0.38521E+04 19 andalusite -7.84 -8.47 -0.62 -0.062 0.23151E+04 24 anorthite -5.34 -6.36 -1.02 -0.079 0.38043E+04 26 anthophyllite-Fe 3.93 -0.29 -4.22 -0.114 0.15667E+05 27 apatite-OH -54.51 -54.93 -0.42 -0.032 0.15648E+04 28 apatite-OH-zs -52.25 -54.93 -2.68 -0.206 0.99683E+04 29 apatite-Cl-zs -59.31 -63.07 -3.76 -0.313 0.13979E+05 30 aragonite -4.90 -8.84 -3.94 -1.314 0.14647E+05 31 brucite 6.16 3.36 -2.80 -0.559 0.10389E+05 32 calcite -5.01 -8.84 -3.83 -1.276 0.14229E+05 33 carnegieite-low 1.17 -0.69 -1.86 -0.266 0.69162E+04 34 carnegieite-high 1.27 -0.69 -1.96 -0.280 0.72870E+04 35 carpholite-Mg -4.01 -6.59 -2.57 -0.172 0.95687E+04 36 carpholite-Fe -5.47 -8.30 -2.82 -0.188 0.10497E+05 37 celadonite 0.39 -2.24 -2.63 -0.155 0.97754E+04 38 celadonite-Fe -1.11 -3.95 -2.84 -0.167 0.10560E+05 39 chrysotile 11.02 7.12 -3.89 -0.324 0.14470E+05 41 clinochlore 9.21 5.38 -3.83 -0.120 0.14218E+05 42 daphnite 1.60 -3.17 -4.77 -0.149 0.17734E+05 45 chloritoid-Mg -3.19 -5.10 -1.91 -0.128 0.71140E+04 46 chloritoid-Fe -5.28 -6.81 -1.53 -0.102 0.56877E+04 47 chloritoid-Mn -3.16 -4.84 -1.68 -0.112 0.62250E+04 49 coesite -1.18 -1.48 -0.30 -0.101 0.11250E+04 50 cordierite-H -12.50 -14.65 -2.15 -0.077 0.79989E+04 51 cordierite-Fe -15.34 -18.07 -2.73 -0.094 0.10150E+05 52 cordierite-Mn -11.03 -14.11 -3.08 -0.106 0.11458E+05 53 corundum -6.18 -6.98 -0.81 -0.073 0.30039E+04 55 cristobalite -1.43 -1.48 -0.05 -0.017 0.18498E+03 58 cymrite-K -1.72 -4.12 -2.40 -0.200 0.89357E+04 60 diaspore -2.62 -3.49 -0.87 -0.146 0.32511E+04 62 diopside 6.07 3.98 -2.09 -0.209 0.77517E+04 63 hedenbergite 4.54 2.27 -2.26 -0.226 0.84161E+04 65 eastonite -0.46 -2.90 -2.44 -0.094 0.90736E+04 66 enstatite 5.70 3.76 -1.93 -0.193 0.71813E+04 67 clinoenstatite-HiP 6.21 3.76 -2.45 -0.245 0.90950E+04 68 clinoenstatite 5.67 3.76 -1.91 -0.191 0.71029E+04 69 protoenstatite 5.84 3.76 -2.07 -0.207 0.77060E+04 70 epidote -0.71 -3.59 -2.88 -0.139 0.10690E+05 71 clinozoisite -4.53 -7.75 -3.22 -0.146 0.11965E+05 72 epidote-Fe 4.83 0.57 -4.26 -0.221 0.15825E+05 73 fayalite 3.24 1.82 -1.41 -0.202 0.52535E+04 74 ferrosilite 1.86 0.34 -1.52 -0.152 0.56399E+04 75 forsterite 7.50 5.24 -2.25 -0.322 0.83777E+04 76 gedrite -1.13 -6.04 -4.91 -0.133 0.18253E+05 78 gibbsite -0.98 -3.49 -2.51 -0.359 0.93400E+04 79 glaucophane 4.44 -0.19 -4.63 -0.125 0.17218E+05 81 goethite 1.66 0.67 -0.99 -0.215 0.36884E+04 83 greenalite 5.77 1.99 -3.78 -0.315 0.14047E+05 84 grunerite 4.52 -0.29 -4.81 -0.130 0.17872E+05 85 halite -1.78 -3.86 -2.08 -1.040 0.77264E+04 86 hematite 1.77 1.34 -0.43 -0.052 0.16091E+04 87 heulandite -10.35 -13.77 -3.43 -0.156 0.12733E+05 88 hercynite -3.84 -5.33 -1.49 -0.100 0.55511E+04 91 jadeite -0.46 -2.18 -1.72 -0.172 0.63893E+04 93 kalsilite 0.53 -1.16 -1.69 -0.242 0.62880E+04 94 kaolinite -7.20 -9.95 -2.75 -0.250 0.10215E+05 95 kyanite -7.67 -8.47 -0.79 -0.079 0.29373E+04 97 laumontite -5.46 -9.33 -3.86 -0.258 0.14361E+05 98 lawsonite -2.61 -6.36 -3.76 -0.251 0.13968E+05 99 leucite -1.62 -2.64 -1.02 -0.102 0.38032E+04 101 lizardite 11.16 7.12 -4.04 -0.337 0.15016E+05 102 magnesite -5.51 -9.06 -3.55 -1.184 0.13197E+05 103 magnetite 3.57 2.99 -0.58 -0.047 0.21482E+04 104 minnesotaite 1.56 -0.97 -2.53 -0.149 0.93907E+04 105 minnesotaite-Mg 7.93 4.16 -3.76 -0.221 0.13989E+05 106 magnesioferrite 6.81 4.70 -2.11 -0.173 0.78555E+04 108 manganosite 6.01 3.63 -2.38 -0.594 0.88277E+04 109 margarite -11.11 -13.35 -2.24 -0.090 0.83237E+04 113 monticellite 9.78 5.47 -4.31 -0.616 0.16021E+05 115 mullite-Si -7.05 -8.47 -1.41 -0.141 0.52580E+04 116 muscovite -10.20 -11.11 -0.90 -0.053 0.33561E+04 117 paragonite -9.50 -10.64 -1.14 -0.067 0.42277E+04 118 nepheline 0.85 -0.69 -1.55 -0.221 0.57556E+04 119 osumilite(2) -9.14 -12.87 -3.72 -0.078 0.13842E+05 120 osumilite-Fe -21.97 -25.15 -3.19 -0.066 0.11844E+05 122 periclase 6.40 3.36 -3.04 -0.760 0.11303E+05 123 periclase-Fe 3.68 1.65 -2.03 -0.508 0.75460E+04 124 perovskite-Al -4.38 -6.98 -2.60 -0.237 0.96699E+04 129 phlogopite-Na 8.85 6.43 -2.42 -0.134 0.89961E+04 131 prehnite -0.46 -4.26 -3.80 -0.223 0.14120E+05 132 prehnite-Fe 3.76 -0.10 -3.86 -0.232 0.14348E+05 135 px-Mg-tschermaks -2.47 -5.10 -2.64 -0.188 0.97933E+04 136 px-Ca-tschermaks -1.91 -4.88 -2.97 -0.212 0.11039E+05 138 pyrrhotite -8.70 -9.50 -0.80 -0.268 0.29887E+04 139 pyrrhotiteFe0.875 -9.56 -9.95 -0.39 -0.143 0.14412E+04 140 pyrophyllite -11.45 -12.91 -1.46 -0.091 0.54185E+04 143 riebeckite 6.60 3.00 -3.60 -0.099 0.13384E+05 144 ringwoodite-Fe 4.25 1.82 -2.43 -0.347 0.90228E+04 146 rhodochrosite -5.65 -8.80 -3.15 -1.050 0.11707E+05 147 rhodonite 2.85 2.15 -0.70 -0.140 0.25924E+04 148 sanidine -3.57 -4.12 -0.56 -0.043 0.20686E+04 150 siderite -7.48 -10.77 -3.29 -1.097 0.12225E+05 151 sillimanite -7.80 -8.47 -0.67 -0.067 0.24793E+04 153 spinel -1.54 -3.62 -2.08 -0.139 0.77474E+04 160 stilpnomelane-Mg 4.53 -0.12 -4.65 -0.139 0.17271E+05 161 stishovite 1.57 -1.48 -3.05 -1.016 0.11323E+05 162 sudoite-Fe -10.22 -15.11 -4.89 -0.158 0.18172E+05 163 sudoite -7.80 -11.69 -3.89 -0.125 0.14447E+05 164 sulfur -11.63 -13.12 -1.49 -0.458 0.55329E+04 165 sylvite -1.69 -4.33 -2.64 -1.318 0.97957E+04 166 talc 6.14 4.16 -1.98 -0.117 0.73685E+04 167 talc-Fe 3.02 -0.97 -3.99 -0.234 0.14813E+05 168 talc-tschermaks -1.94 -4.70 -2.76 -0.163 0.10274E+05 170 tephroite 7.44 5.78 -1.66 -0.237 0.61610E+04 173 topaz-H -5.76 -8.47 -2.71 -0.246 0.10058E+05 176 troilite-low -8.61 -9.50 -0.89 -0.297 0.33102E+04 180 wadsleyite-Fe 4.11 1.82 -2.29 -0.327 0.85098E+04 181 wadsleyite-Mg 9.79 5.24 -4.54 -0.649 0.16881E+05 182 wairakite -7.35 -9.33 -1.98 -0.116 0.73476E+04 183 walstromite 4.87 2.10 -2.77 -0.553 0.10278E+05 184 wollastonite 4.43 2.10 -2.32 -0.465 0.86359E+04 185 pseudo-wollastonite 4.55 2.10 -2.45 -0.490 0.91055E+04 186 zoisite -4.58 -7.75 -3.18 -0.144 0.11802E+05 189 beidellite-Ca -11.13 -12.98 -1.85 -0.115 0.68803E+04 190 beidellite-H -11.21 -13.57 -2.36 -0.151 0.87733E+04 191 beidellite-K -10.18 -12.31 -2.14 -0.131 0.79424E+04 192 beidellite-Mg -11.34 -13.02 -1.68 -0.104 0.62294E+04 193 beidellite-Na -10.12 -12.16 -2.04 -0.125 0.75897E+04 194 bornite -57.41 -57.56 -0.16 -0.012 0.58087E+03 196 chalcocite -15.19 -16.60 -1.41 -0.352 0.52340E+04 197 covellite -13.56 -14.86 -1.30 -0.496 0.48370E+04 199 montmorillonite-Ca -8.51 -10.06 -1.54 -0.095 0.57306E+04 200 montmorillonite-K -7.83 -9.39 -1.56 -0.095 0.57914E+04 201 montmorillonite-Mg -8.70 -10.09 -1.40 -0.086 0.51891E+04 202 montmorillonite-Na -7.51 -9.24 -1.73 -0.106 0.64120E+04 203 nontronite-Ca -2.90 -4.66 -1.76 -0.114 0.65327E+04 204 nontronite-H -2.99 -5.25 -2.26 -0.151 0.83987E+04 205 nontronite-K -1.95 -3.99 -2.04 -0.131 0.75874E+04 206 nontronite-Mg -3.09 -4.70 -1.61 -0.104 0.59832E+04 207 nontronite-Na -1.89 -3.84 -1.95 -0.125 0.72448E+04 212 gypsum -13.15 -15.44 -2.29 -0.572 0.85081E+04 229 alabandite -6.43 -7.52 -1.09 -0.364 0.40554E+04 231 anglesite -15.86 -18.16 -2.30 -1.148 0.85332E+04 235 boehmite -2.30 -3.49 -1.19 -0.198 0.44213E+04 239 copper,native 1.67 -1.74 -3.41 -1.187 0.12684E+05 241 ferrous-oxide 2.73 1.65 -1.08 -0.270 0.40174E+04 243 silver,native 0.32 -4.42 -4.74 -1.648 0.17609E+05 245 litharge 5.59 0.86 -4.73 -1.181 0.17562E+05 253 wurtzite -10.23 -11.06 -0.83 -0.277 0.30910E+04 254 zincite 2.78 0.09 -2.69 -0.673 0.99970E+04 255 an20ab80 -4.07 -4.20 -0.13 -0.010 0.46551E+03 256 an25ab75 -4.19 -4.33 -0.14 -0.011 0.52348E+03 257 an30ab70 -4.31 -4.47 -0.16 -0.013 0.60391E+03 258 tr.625ac.25prg.125 12.63 9.17 -3.46 -0.093 0.12857E+05 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 43 Loop limit = 500 Temperature = 539.00 C Pressure = 829.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9936E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9971 Stoichiometric ionic strength = .3268304E+01 Osmotic coef. = 0.0000 True ionic strength = .1764669E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54768E-05 -5.2615 0.58961E-06 -6.2294 0.10766E+00 -0.9680 2 H2O 0.99708E+00 -0.0013 0.99708E+00 -0.0013 3 Cl- 0.14788E+00 -0.8301 0.12290E-01 -1.9105 0.83106E-01 -1.0804 4 SO4-- 0.17373E-02 -2.7601 0.27198E-06 -6.5655 0.15656E-03 -3.8053 5 HCO3- 0.68598E-05 -5.1637 0.63380E-06 -6.1980 0.92393E-01 -1.0344 6 HS- 0.14103E-03 -3.8507 0.11859E-04 -4.9260 0.84083E-01 -1.0753 7 H4SiO4 0.32854E-01 -1.4834 0.32854E-01 -1.4834 0.10000E+01 0.0000 8 Al+++ 0.36682E-13 -13.4355 0.66296E-22 -22.1785 0.18073E-08 -8.7430 9 Ca++ 0.11867E-04 -4.9257 0.13375E-08 -8.8737 0.11271E-03 -3.9481 10 Mg++ 0.94456E-05 -5.0248 0.80289E-09 -9.0953 0.85002E-04 -4.0706 11 Fe++ 0.17132E-06 -6.7662 0.15638E-10 -10.8058 0.91276E-04 -4.0396 12 K+ 0.40148E-01 -1.3963 0.38343E-02 -2.4163 0.95503E-01 -1.0200 13 Na+ 0.13301E+00 -0.8761 0.11206E-01 -1.9505 0.84254E-01 -1.0744 14 Mn++ 0.15468E-04 -4.8106 0.14875E-08 -8.8276 0.96164E-04 -4.0170 15 Zn++ 0.46922E-08 -8.3286 0.42829E-12 -12.3683 0.91276E-04 -4.0396 16 Cu+ 0.13306E-07 -7.8759 0.11169E-08 -8.9520 0.83935E-01 -1.0761 17 Pb++ 0.19125E-07 -7.7184 0.25430E-11 -11.5947 0.13297E-03 -3.8763 18 Ag+ 0.25204E-10 -10.5985 0.23527E-11 -11.6284 0.93346E-01 -1.0299 19 Ba++ 0.37262E-06 -6.4287 0.55035E-10 -10.2594 0.14770E-03 -3.8306 20 HPO4-- 0.94736E-08 -8.0235 0.14941E-11 -11.8256 0.15771E-03 -3.8021 21 HSiO3- 0.15279E-05 -5.8159 0.12697E-06 -6.8963 0.83106E-01 -1.0804 22 Ca(HSiO3)+ 0.47872E-08 -8.3199 0.46306E-09 -9.3344 0.96729E-01 -1.0144 23 Mg(HSiO3)+ 0.10948E-08 -8.9607 0.10589E-09 -9.9751 0.96729E-01 -1.0144 24 NaHSiO3,aq 0.17768E-05 -5.7504 0.17768E-05 -5.7504 0.10000E+01 0.0000 28 AgCl,aq 0.88641E-08 -8.0524 0.88641E-08 -8.0524 0.10000E+01 0.0000 29 AgCl2- 0.45274E-06 -6.3441 0.37625E-07 -7.4245 0.83106E-01 -1.0804 30 AgCl3-2 0.45643E-06 -6.3406 0.63850E-10 -10.1948 0.13989E-03 -3.8542 31 AgCl4-3 0.78379E-05 -5.1058 0.11949E-13 -13.9227 0.15246E-08 -8.8169 34 Ag(HS),aq 0.19772E-09 -9.7039 0.19772E-09 -9.7039 0.10000E+01 0.0000 35 Ag(HS)2- 0.61169E-09 -9.2135 0.50835E-10 -10.2938 0.83106E-01 -1.0804 36 AlO+ 0.36667E-10 -10.4357 0.35467E-11 -11.4502 0.96729E-01 -1.0144 38 HAlO2,aq 0.53579E-08 -8.2710 0.53579E-08 -8.2710 0.10000E+01 0.0000 39 AlO2- 0.15942E-04 -4.7975 0.11029E-05 -5.9575 0.69180E-01 -1.1600 41 Ba(HCO3)+ 0.13282E-06 -6.8767 0.13615E-07 -7.8660 0.10250E+00 -0.9893 42 BaCl+ 0.65053E-05 -5.1867 0.62925E-06 -6.2012 0.96729E-01 -1.0144 43 CH4,aq 0.11785E-08 -8.9287 0.13671E-08 -8.8642 0.11601E+01 0.0645 48 CO,aq 0.35212E-03 -3.4533 0.35212E-03 -3.4533 0.10000E+01 0.0000 49 CO2,aq 0.26728E+01 0.4270 0.31007E+01 0.4915 0.11601E+01 0.0645 50 CO3-2 0.19966E-09 -9.6997 0.27930E-13 -13.5539 0.13989E-03 -3.8542 52 Ca(HCO3)+ 0.61283E-07 -7.2127 0.59279E-08 -8.2271 0.96729E-01 -1.0144 53 CaCl+ 0.76525E-04 -4.1162 0.74022E-05 -5.1306 0.96729E-01 -1.0144 54 CaCl2,aq 0.59222E-04 -4.2275 0.59222E-04 -4.2275 0.10000E+01 0.0000 55 CaOH+ 0.13688E-06 -6.8637 0.13240E-07 -7.8781 0.96729E-01 -1.0144 56 CaSO4,aq 0.22198E-06 -6.6537 0.22198E-06 -6.6537 0.10000E+01 0.0000 57 HCl,aq 0.79530E-02 -2.0995 0.79530E-02 -2.0995 0.10000E+01 0.0000 66 CuCl,aq 0.18152E-04 -4.7411 0.18152E-04 -4.7411 0.10000E+01 0.0000 67 CuCl2- 0.81042E-04 -4.0913 0.67350E-05 -5.1717 0.83106E-01 -1.0804 68 CuCl3-2 0.45824E-05 -5.3389 0.64103E-09 -9.1931 0.13989E-03 -3.8542 74 FeCl+ 0.32129E-06 -6.4931 0.31078E-07 -7.5075 0.96729E-01 -1.0144 75 FeCl2,aq 0.15392E-02 -2.8127 0.15392E-02 -2.8127 0.10000E+01 0.0000 77 FeO,aq 0.38819E-07 -7.4110 0.38819E-07 -7.4110 0.10000E+01 0.0000 78 FeOH+ 0.25693E-07 -7.5902 0.24853E-08 -8.6046 0.96729E-01 -1.0144 79 HFeO2- 0.60232E-08 -8.2202 0.50056E-09 -9.3005 0.83106E-01 -1.0804 82 FeO2- 0.31892E-08 -8.4963 0.26504E-09 -9.5767 0.83106E-01 -1.0804 83 HFeO2,aq 0.28149E-09 -9.5505 0.28149E-09 -9.5505 0.10000E+01 0.0000 84 H2,aq 0.41310E-02 -2.3839 0.47923E-02 -2.3195 0.11601E+01 0.0645 85 KCl,aq 0.68228E-01 -1.1660 0.68228E-01 -1.1660 0.10000E+01 0.0000 86 KHSO4,aq 0.10975E-01 -1.9596 0.10975E-01 -1.9596 0.10000E+01 0.0000 87 KOH,aq 0.12665E-05 -5.8974 0.12665E-05 -5.8974 0.10000E+01 0.0000 88 KSO4- 0.61808E-02 -2.2090 0.51366E-03 -3.2893 0.83106E-01 -1.0804 90 Mg(HCO3)+ 0.10373E-07 -7.9841 0.10033E-08 -8.9986 0.96729E-01 -1.0144 91 MgCl+ 0.10977E-04 -4.9595 0.10618E-05 -5.9740 0.96729E-01 -1.0144 92 MgOH+ 0.37535E-06 -6.4256 0.36308E-07 -7.4400 0.96729E-01 -1.0144 94 MnO,aq 0.70224E-07 -7.1535 0.70224E-07 -7.1535 0.10000E+01 0.0000 95 MnOH+ 0.23836E-06 -6.6228 0.23056E-07 -7.6372 0.96729E-01 -1.0144 97 HMnO2- 0.37099E-10 -10.4306 0.30831E-11 -11.5110 0.83106E-01 -1.0804 100 MnCl+ 0.11409E-02 -2.9428 0.11036E-03 -3.9572 0.96729E-01 -1.0144 101 MnSO4,aq 0.22783E-06 -6.6424 0.22783E-06 -6.6424 0.10000E+01 0.0000 102 NaCl,aq 0.42515E+00 -0.3715 0.42515E+00 -0.3715 0.10000E+01 0.0000 103 NaOH,aq 0.16524E-05 -5.7819 0.16524E-05 -5.7819 0.10000E+01 0.0000 105 OH- 0.10095E-04 -4.9959 0.69836E-06 -6.1559 0.69180E-01 -1.1600 110 HPO3-2 0.32530E-10 -10.4877 0.45506E-14 -14.3419 0.13989E-03 -3.8542 111 H3PO3,aq 0.10560E-09 -9.9763 0.10560E-09 -9.9763 0.10000E+01 0.0000 112 H2PO3- 0.11393E-08 -8.9434 0.94681E-10 -10.0237 0.83106E-01 -1.0804 113 H3PO4,aq 0.18470E-05 -5.7335 0.18470E-05 -5.7335 0.10000E+01 0.0000 114 H2PO4- 0.14846E-05 -5.8284 0.13247E-06 -6.8779 0.89229E-01 -1.0495 116 H4P2O7,aq 0.34207E-09 -9.4659 0.34207E-09 -9.4659 0.10000E+01 0.0000 117 H3P2O7- 0.85244E-09 -9.0693 0.70842E-10 -10.1497 0.83106E-01 -1.0804 118 H2P2O7-2 0.64178E-06 -6.1926 0.89779E-10 -10.0468 0.13989E-03 -3.8542 119 HP2O7-3 0.19968E-05 -5.6997 0.30442E-14 -14.5165 0.15246E-08 -8.8169 120 P2O7-4 0.36456E-09 -9.4382 0.40108E-24 -24.3968 0.11002E-14 -14.9585 121 PbCl+ 0.11453E-05 -5.9411 0.11078E-06 -6.9555 0.96729E-01 -1.0144 122 PbCl2,aq 0.70034E-04 -4.1547 0.70034E-04 -4.1547 0.10000E+01 0.0000 123 PbCl3- 0.11090E-03 -3.9551 0.92167E-05 -5.0354 0.83106E-01 -1.0804 124 PbCl4-2 0.54435E-04 -4.2641 0.76150E-08 -8.1183 0.13989E-03 -3.8542 125 PbO,aq 0.58198E-08 -8.2351 0.58198E-08 -8.2351 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.91272E-04 -4.0397 0.91272E-04 -4.0397 0.10000E+01 0.0000 128 Pb(HS)3- 0.14157E-04 -4.8490 0.11765E-05 -5.9294 0.83106E-01 -1.0804 129 H2S,aq 0.10606E+01 0.0256 0.12304E+01 0.0900 0.11601E+01 0.0645 130 S2-2 0.52573E-07 -7.2792 0.73545E-11 -11.1334 0.13989E-03 -3.8542 131 S3-2 0.45015E-08 -8.3466 0.62971E-12 -12.2009 0.13989E-03 -3.8542 132 S3- 0.74541E-02 -2.1276 0.61948E-03 -3.2080 0.83106E-01 -1.0804 133 S4-2 0.33463E-09 -9.4754 0.46811E-13 -13.3296 0.13989E-03 -3.8542 134 S5-2 0.22019E-10 -10.6572 0.30803E-14 -14.5114 0.13989E-03 -3.8542 135 SO2,aq 0.29294E+00 -0.5332 0.29294E+00 -0.5332 0.10000E+01 0.0000 136 SO3-2 0.33927E-08 -8.4694 0.93495E-12 -12.0292 0.27557E-03 -3.5598 137 HSO3- 0.22855E-03 -3.6410 0.18994E-04 -4.7214 0.83106E-01 -1.0804 138 HSO4- 0.88129E-02 -2.0549 0.88814E-03 -3.0515 0.10078E+00 -0.9966 140 S2O3-2 0.27495E-05 -5.5608 0.38462E-09 -9.4150 0.13989E-03 -3.8542 141 HS2O3- 0.35707E-06 -6.4472 0.29674E-07 -7.5276 0.83106E-01 -1.0804 142 H2S2O3,aq 0.50525E-07 -7.2965 0.50525E-07 -7.2965 0.10000E+01 0.0000 150 S4O6-2 0.18197E-08 -8.7400 0.25455E-12 -12.5942 0.13989E-03 -3.8542 152 ZnCl+ 0.12558E-03 -3.9011 0.12147E-04 -4.9155 0.96729E-01 -1.0144 153 ZnCl2,aq 0.43608E-03 -3.3604 0.43608E-03 -3.3604 0.10000E+01 0.0000 154 ZnCl3- 0.28722E-04 -4.5418 0.23869E-05 -5.6222 0.83106E-01 -1.0804 155 ZnO,aq 0.21358E-07 -7.6704 0.21358E-07 -7.6704 0.10000E+01 0.0000 156 ZnOH+ 0.95784E-06 -6.0187 0.92651E-07 -7.0332 0.96729E-01 -1.0144 158 HZnO2- 0.21923E-09 -9.6591 0.18219E-10 -10.7395 0.83106E-01 -1.0804 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5476806E-05 0.4292713E+01 0.3545348E+04 0.0000 2 H2O 0.1000000E+01 0.5252767E+02 0.7753933E+06 0.0000 3 Cl- 0.1478797E+00 0.6556455E+00 0.1904647E+05 4.3190 4 SO4-- 0.1737255E-02 0.2511243E+00 0.1976655E+05 5.8934 5 HCO3- 0.6859796E-05 0.2673175E+01 0.1336510E+06 0.0314 6 HS- 0.1410339E-03 0.1153090E+01 0.3124757E+05 1.3035 7 H4SiO4 0.3285419E-01 0.3285750E-01 0.2587735E+04 -1.4834 8 Al+++ 0.3668184E-13 0.1594745E-04 0.3525734E+00 -3.4902 9 Ca++ 0.1186677E-04 0.1480387E-03 0.4861538E+01 3.5852 10 Mg++ 0.9445604E-05 0.2080947E-04 0.4145474E+00 3.3635 11 Fe++ 0.1713213E-06 0.1539790E-02 0.7046180E+02 1.6530 12 K+ 0.4014823E-01 0.1255327E+00 0.4022056E+04 3.8131 13 Na+ 0.1330088E+00 0.5581620E+00 0.1051448E+05 4.2789 14 Mn++ 0.1546800E-04 0.1156884E-02 0.5207809E+02 3.6313 15 Zn++ 0.4692215E-08 0.5913661E-03 0.3167577E+02 0.0906 16 Cu+ 0.1330641E-07 0.1037889E-03 0.5403691E+01 -2.7226 17 Pb++ 0.1912506E-07 0.3419725E-03 0.5805670E+02 0.8642 18 Ag+ 0.2520397E-10 0.8756734E-05 0.7739897E+00 -5.3990 19 Ba++ 0.3726231E-06 0.7010734E-05 0.7889562E+00 2.1995 20 HPO4-- 0.9473618E-08 0.8622536E-05 0.6781154E+00 0.6333 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265313E+01 -.2951247E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5219240E+02 -.2276243E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2495214E+00 0.2201360E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1145731E+01 0.1441357E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3264778E-01 0.1109465E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1584566E-04 0.6786939E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1470938E-03 0.3808161E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1529962E-02 0.7236792E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247314E+00 0.6786939E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.5875915E-03 0.1711743E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1031265E-03 0.2964833E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3397898E-03 0.3828630E-06 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.6965986E-05 0.4840647E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1924E-17 Mass of aqueous solution: 0.121263E+04 g Temperature = 539.00 C Pressure = 829.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3808E-03 -3.419 0.5184E-01 -1.285 0.6605 0.1750E-01 microcline 0.6787E-03 -3.168 0.1889 -0.724 2.407 0.7379E-01 pyrite 0.6940E-02 -2.159 0.8327 -0.080 10.61 0.1661 quartz 0.1089 -0.963 6.543 0.816 83.36 2.471 barite 0.4841E-04 -4.315 0.1130E-01 -1.947 0.1439 0.2522E-02 chalcopyrite 0.2965E-03 -3.528 0.5440E-01 -1.264 0.6931 0.1270E-01 sphalerite 0.1712E-02 -2.767 0.1668 -0.778 2.125 0.4079E-01 galena 0.3829E-06 -6.417 0.9160E-04 -4.038 0.1167E-02 0.1206E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.849360 g Volume = 2.784500 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.44 -15.44 0.00 0.000 0.00000E+00 112 microcline -4.12 -4.12 0.00 0.000 -0.66014E-11 137 pyrite -22.62 -22.62 -0.00 -0.000 0.13203E-10 141 quartz -1.48 -1.48 0.00 0.000 0.00000E+00 234 barite -16.82 -16.82 0.00 0.000 0.00000E+00 237 chalcopyrite -24.36 -24.36 0.00 0.000 -0.13203E-10 242 galena -10.29 -10.29 -0.00 -0.000 0.66014E-11 252 sphalerite -11.06 -11.06 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.25 -0.00 -0.25 -0.246 0.91552E+03 2.672 2 CO2,gas -10.61 -12.43 -1.82 -0.605 0.67488E+04 1.103 3 CH4,gas 6.73 -4.56 -11.29 -2.822 0.41955E+05 -8.371 4 H2,gas 6.09 1.97 -4.12 -2.357 0.15328E+05 -1.206 5 H2S,gas -8.83 -11.16 -2.33 -1.163 0.86446E+04 0.592 6 CO,gas -4.18 -10.46 -6.28 -1.933 0.23350E+05 -3.365 7 SO3,gas -8.09 -19.02 -10.93 -2.732 0.40615E+05 -8.011 8 O2,gas 17.31 -3.93 -21.24 -14.163 0.78951E+05 -18.326 9 HCl,gas -6.42 -8.14 -1.72 -0.862 0.64071E+04 -1.724 10 acmite 3.69 1.98 -1.70 -0.177 0.63312E+04 12 akimotoite 6.73 1.88 -4.85 -0.970 0.18024E+05 13 akimotoite-Fe 4.50 0.17 -4.33 -0.865 0.16077E+05 14 albite-high -3.46 -3.66 -0.19 -0.015 0.71415E+03 15 albite -3.48 -3.66 -0.17 -0.013 0.64007E+03 16 almandine -3.94 -6.47 -2.53 -0.127 0.94147E+04 17 pyrope 3.16 -1.34 -4.50 -0.225 0.16709E+05 18 analcite -1.14 -2.18 -1.04 -0.115 0.38521E+04 19 andalusite -7.84 -8.47 -0.62 -0.062 0.23151E+04 24 anorthite -5.34 -6.36 -1.02 -0.079 0.38043E+04 26 anthophyllite-Fe 3.93 -0.29 -4.22 -0.114 0.15667E+05 27 apatite-OH -54.51 -54.93 -0.42 -0.032 0.15648E+04 28 apatite-OH-zs -52.25 -54.93 -2.68 -0.206 0.99682E+04 29 apatite-Cl-zs -59.31 -63.07 -3.76 -0.313 0.13979E+05 30 aragonite -4.90 -8.84 -3.94 -1.314 0.14647E+05 31 brucite 6.16 3.36 -2.80 -0.559 0.10389E+05 32 calcite -5.01 -8.84 -3.83 -1.276 0.14229E+05 33 carnegieite-low 1.17 -0.69 -1.86 -0.266 0.69162E+04 34 carnegieite-high 1.27 -0.69 -1.96 -0.280 0.72870E+04 35 carpholite-Mg -4.01 -6.59 -2.57 -0.172 0.95687E+04 36 carpholite-Fe -5.47 -8.30 -2.82 -0.188 0.10497E+05 37 celadonite 0.39 -2.24 -2.63 -0.155 0.97755E+04 38 celadonite-Fe -1.11 -3.95 -2.84 -0.167 0.10560E+05 39 chrysotile 11.02 7.12 -3.89 -0.324 0.14470E+05 41 clinochlore 9.21 5.38 -3.83 -0.120 0.14218E+05 42 daphnite 1.60 -3.17 -4.77 -0.149 0.17734E+05 45 chloritoid-Mg -3.19 -5.10 -1.91 -0.128 0.71140E+04 46 chloritoid-Fe -5.28 -6.81 -1.53 -0.102 0.56877E+04 47 chloritoid-Mn -3.16 -4.84 -1.68 -0.112 0.62250E+04 49 coesite -1.18 -1.48 -0.30 -0.101 0.11250E+04 50 cordierite-H -12.50 -14.65 -2.15 -0.077 0.79988E+04 51 cordierite-Fe -15.34 -18.07 -2.73 -0.094 0.10150E+05 52 cordierite-Mn -11.03 -14.11 -3.08 -0.106 0.11458E+05 53 corundum -6.18 -6.98 -0.81 -0.073 0.30039E+04 55 cristobalite -1.43 -1.48 -0.05 -0.017 0.18498E+03 58 cymrite-K -1.72 -4.12 -2.40 -0.200 0.89357E+04 60 diaspore -2.62 -3.49 -0.87 -0.146 0.32511E+04 62 diopside 6.07 3.98 -2.09 -0.209 0.77517E+04 63 hedenbergite 4.54 2.27 -2.26 -0.226 0.84161E+04 65 eastonite -0.46 -2.90 -2.44 -0.094 0.90736E+04 66 enstatite 5.70 3.76 -1.93 -0.193 0.71813E+04 67 clinoenstatite-HiP 6.21 3.76 -2.45 -0.245 0.90950E+04 68 clinoenstatite 5.67 3.76 -1.91 -0.191 0.71029E+04 69 protoenstatite 5.84 3.76 -2.07 -0.207 0.77060E+04 70 epidote -0.71 -3.59 -2.88 -0.139 0.10690E+05 71 clinozoisite -4.53 -7.75 -3.22 -0.146 0.11965E+05 72 epidote-Fe 4.83 0.57 -4.26 -0.221 0.15825E+05 73 fayalite 3.24 1.82 -1.41 -0.202 0.52535E+04 74 ferrosilite 1.86 0.34 -1.52 -0.152 0.56399E+04 75 forsterite 7.50 5.24 -2.25 -0.322 0.83777E+04 76 gedrite -1.13 -6.04 -4.91 -0.133 0.18253E+05 78 gibbsite -0.98 -3.49 -2.51 -0.359 0.93400E+04 79 glaucophane 4.44 -0.19 -4.63 -0.125 0.17218E+05 81 goethite 1.66 0.67 -0.99 -0.215 0.36884E+04 83 greenalite 5.77 1.99 -3.78 -0.315 0.14047E+05 84 grunerite 4.52 -0.29 -4.81 -0.130 0.17872E+05 85 halite -1.78 -3.86 -2.08 -1.040 0.77264E+04 86 hematite 1.77 1.34 -0.43 -0.052 0.16091E+04 87 heulandite -10.35 -13.77 -3.43 -0.156 0.12733E+05 88 hercynite -3.84 -5.33 -1.49 -0.100 0.55511E+04 91 jadeite -0.46 -2.18 -1.72 -0.172 0.63893E+04 93 kalsilite 0.53 -1.16 -1.69 -0.242 0.62880E+04 94 kaolinite -7.20 -9.95 -2.75 -0.250 0.10215E+05 95 kyanite -7.67 -8.47 -0.79 -0.079 0.29373E+04 97 laumontite -5.46 -9.33 -3.86 -0.258 0.14361E+05 98 lawsonite -2.61 -6.36 -3.76 -0.251 0.13968E+05 99 leucite -1.62 -2.64 -1.02 -0.102 0.38032E+04 101 lizardite 11.16 7.12 -4.04 -0.337 0.15016E+05 102 magnesite -5.51 -9.06 -3.55 -1.184 0.13197E+05 103 magnetite 3.57 2.99 -0.58 -0.047 0.21482E+04 104 minnesotaite 1.56 -0.97 -2.53 -0.149 0.93907E+04 105 minnesotaite-Mg 7.93 4.16 -3.76 -0.221 0.13989E+05 106 magnesioferrite 6.81 4.70 -2.11 -0.173 0.78555E+04 108 manganosite 6.01 3.63 -2.38 -0.594 0.88277E+04 109 margarite -11.11 -13.35 -2.24 -0.090 0.83236E+04 113 monticellite 9.78 5.47 -4.31 -0.616 0.16021E+05 115 mullite-Si -7.05 -8.47 -1.41 -0.141 0.52580E+04 116 muscovite -10.20 -11.11 -0.90 -0.053 0.33561E+04 117 paragonite -9.50 -10.64 -1.14 -0.067 0.42277E+04 118 nepheline 0.85 -0.69 -1.55 -0.221 0.57556E+04 119 osumilite(2) -9.14 -12.87 -3.72 -0.078 0.13842E+05 120 osumilite-Fe -21.97 -25.15 -3.19 -0.066 0.11844E+05 122 periclase 6.40 3.36 -3.04 -0.760 0.11303E+05 123 periclase-Fe 3.68 1.65 -2.03 -0.508 0.75460E+04 124 perovskite-Al -4.38 -6.98 -2.60 -0.237 0.96698E+04 129 phlogopite-Na 8.85 6.43 -2.42 -0.134 0.89961E+04 131 prehnite -0.46 -4.26 -3.80 -0.223 0.14120E+05 132 prehnite-Fe 3.76 -0.10 -3.86 -0.232 0.14348E+05 135 px-Mg-tschermaks -2.47 -5.10 -2.64 -0.188 0.97933E+04 136 px-Ca-tschermaks -1.91 -4.88 -2.97 -0.212 0.11039E+05 138 pyrrhotite -8.70 -9.50 -0.80 -0.268 0.29887E+04 139 pyrrhotiteFe0.875 -9.56 -9.95 -0.39 -0.143 0.14412E+04 140 pyrophyllite -11.45 -12.91 -1.46 -0.091 0.54185E+04 143 riebeckite 6.60 3.00 -3.60 -0.099 0.13384E+05 144 ringwoodite-Fe 4.25 1.82 -2.43 -0.347 0.90228E+04 146 rhodochrosite -5.65 -8.80 -3.15 -1.050 0.11707E+05 147 rhodonite 2.85 2.15 -0.70 -0.140 0.25924E+04 148 sanidine -3.57 -4.12 -0.56 -0.043 0.20686E+04 150 siderite -7.48 -10.77 -3.29 -1.097 0.12225E+05 151 sillimanite -7.80 -8.47 -0.67 -0.067 0.24793E+04 153 spinel -1.54 -3.62 -2.08 -0.139 0.77474E+04 160 stilpnomelane-Mg 4.53 -0.12 -4.65 -0.139 0.17271E+05 161 stishovite 1.57 -1.48 -3.05 -1.016 0.11323E+05 162 sudoite-Fe -10.22 -15.11 -4.89 -0.158 0.18172E+05 163 sudoite -7.80 -11.69 -3.89 -0.125 0.14447E+05 164 sulfur -11.63 -13.12 -1.49 -0.458 0.55329E+04 165 sylvite -1.69 -4.33 -2.64 -1.318 0.97957E+04 166 talc 6.14 4.16 -1.98 -0.117 0.73685E+04 167 talc-Fe 3.02 -0.97 -3.99 -0.234 0.14813E+05 168 talc-tschermaks -1.94 -4.70 -2.76 -0.163 0.10274E+05 170 tephroite 7.44 5.78 -1.66 -0.237 0.61610E+04 173 topaz-H -5.76 -8.47 -2.71 -0.246 0.10058E+05 176 troilite-low -8.61 -9.50 -0.89 -0.297 0.33102E+04 180 wadsleyite-Fe 4.11 1.82 -2.29 -0.327 0.85098E+04 181 wadsleyite-Mg 9.79 5.24 -4.54 -0.649 0.16881E+05 182 wairakite -7.35 -9.33 -1.98 -0.116 0.73476E+04 183 walstromite 4.87 2.10 -2.77 -0.553 0.10278E+05 184 wollastonite 4.43 2.10 -2.32 -0.465 0.86359E+04 185 pseudo-wollastonite 4.55 2.10 -2.45 -0.490 0.91055E+04 186 zoisite -4.58 -7.75 -3.18 -0.144 0.11802E+05 189 beidellite-Ca -11.13 -12.98 -1.85 -0.115 0.68803E+04 190 beidellite-H -11.21 -13.57 -2.36 -0.151 0.87733E+04 191 beidellite-K -10.18 -12.31 -2.14 -0.131 0.79424E+04 192 beidellite-Mg -11.34 -13.02 -1.68 -0.104 0.62293E+04 193 beidellite-Na -10.12 -12.16 -2.04 -0.125 0.75897E+04 194 bornite -57.41 -57.56 -0.16 -0.012 0.58087E+03 196 chalcocite -15.19 -16.60 -1.41 -0.352 0.52340E+04 197 covellite -13.56 -14.86 -1.30 -0.496 0.48370E+04 199 montmorillonite-Ca -8.51 -10.06 -1.54 -0.095 0.57306E+04 200 montmorillonite-K -7.83 -9.39 -1.56 -0.095 0.57914E+04 201 montmorillonite-Mg -8.70 -10.09 -1.40 -0.086 0.51891E+04 202 montmorillonite-Na -7.51 -9.24 -1.73 -0.106 0.64120E+04 203 nontronite-Ca -2.90 -4.66 -1.76 -0.114 0.65327E+04 204 nontronite-H -2.99 -5.25 -2.26 -0.151 0.83987E+04 205 nontronite-K -1.95 -3.99 -2.04 -0.131 0.75874E+04 206 nontronite-Mg -3.09 -4.70 -1.61 -0.104 0.59832E+04 207 nontronite-Na -1.89 -3.84 -1.95 -0.125 0.72448E+04 212 gypsum -13.15 -15.44 -2.29 -0.572 0.85081E+04 229 alabandite -6.43 -7.52 -1.09 -0.364 0.40554E+04 231 anglesite -15.86 -18.16 -2.30 -1.148 0.85351E+04 235 boehmite -2.30 -3.49 -1.19 -0.198 0.44212E+04 239 copper,native 1.67 -1.74 -3.41 -1.187 0.12684E+05 241 ferrous-oxide 2.73 1.65 -1.08 -0.270 0.40174E+04 243 silver,native 0.32 -4.42 -4.74 -1.648 0.17609E+05 245 litharge 5.59 0.86 -4.73 -1.182 0.17563E+05 253 wurtzite -10.23 -11.06 -0.83 -0.277 0.30910E+04 254 zincite 2.78 0.09 -2.69 -0.673 0.99970E+04 255 an20ab80 -4.07 -4.20 -0.13 -0.010 0.46551E+03 256 an25ab75 -4.19 -4.33 -0.14 -0.011 0.52348E+03 257 an30ab70 -4.31 -4.47 -0.16 -0.013 0.60391E+03 258 tr.625ac.25prg.125 12.63 9.17 -3.46 -0.093 0.12857E+05 Calculations done for 539.0000 Deg. C; 829.0000 bar Temperature changed by -1.000 degrees to 538.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 68 Loop limit = 500 Temperature = 538.00 C Pressure = 820.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9936E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9971 Stoichiometric ionic strength = .3267999E+01 Osmotic coef. = 0.0000 True ionic strength = .1771322E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54600E-05 -5.2628 0.57157E-06 -6.2429 0.10468E+00 -0.9801 2 H2O 0.99708E+00 -0.0013 0.99708E+00 -0.0013 3 Cl- 0.14814E+00 -0.8293 0.11921E-01 -1.9237 0.80471E-01 -1.0944 4 SO4-- 0.18914E-02 -2.7232 0.26398E-06 -6.5784 0.13956E-03 -3.8552 5 HCO3- 0.67291E-05 -5.1720 0.60277E-06 -6.2198 0.89576E-01 -1.0478 6 HS- 0.14211E-03 -3.8474 0.11572E-04 -4.9366 0.81429E-01 -1.0892 7 H4SiO4 0.32228E-01 -1.4918 0.32228E-01 -1.4918 0.10000E+01 0.0000 8 Al+++ 0.50829E-13 -13.2939 0.70410E-22 -22.1524 0.13852E-08 -8.8585 9 Ca++ 0.12975E-04 -4.8869 0.12980E-08 -8.8867 0.10003E-03 -3.9998 10 Mg++ 0.99328E-05 -5.0029 0.74683E-09 -9.1268 0.75189E-04 -4.1238 11 Fe++ 0.19086E-06 -6.7193 0.15423E-10 -10.8118 0.80807E-04 -4.0925 12 K+ 0.40203E-01 -1.3957 0.37237E-02 -2.4290 0.92621E-01 -1.0333 13 Na+ 0.13346E+00 -0.8747 0.10889E-01 -1.9630 0.81588E-01 -1.0884 14 Mn++ 0.17382E-04 -4.7599 0.14807E-08 -8.8295 0.85188E-04 -4.0696 15 Zn++ 0.52427E-08 -8.2804 0.42365E-12 -12.3730 0.80807E-04 -4.0925 16 Cu+ 0.13182E-07 -7.8800 0.10714E-08 -8.9700 0.81276E-01 -1.0900 17 Pb++ 0.20518E-07 -7.6879 0.24264E-11 -11.6150 0.11826E-03 -3.9272 18 Ag+ 0.21768E-10 -10.6622 0.19701E-11 -11.7055 0.90505E-01 -1.0433 19 Ba++ 0.39705E-06 -6.4012 0.52224E-10 -10.2821 0.13153E-03 -3.8810 20 HPO4-- 0.97263E-08 -8.0121 0.13676E-11 -11.8641 0.14061E-03 -3.8520 21 HSiO3- 0.15351E-05 -5.8139 0.12353E-06 -6.9082 0.80471E-01 -1.0944 22 Ca(HSiO3)+ 0.47838E-08 -8.3202 0.44884E-09 -9.3479 0.93825E-01 -1.0277 23 Mg(HSiO3)+ 0.10586E-08 -8.9753 0.99322E-10 -10.0030 0.93825E-01 -1.0277 24 NaHSiO3,aq 0.17841E-05 -5.7486 0.17841E-05 -5.7486 0.10000E+01 0.0000 28 AgCl,aq 0.76653E-08 -8.1155 0.76653E-08 -8.1155 0.10000E+01 0.0000 29 AgCl2- 0.39092E-06 -6.4079 0.31458E-07 -7.5023 0.80471E-01 -1.0944 30 AgCl3-2 0.40997E-06 -6.3872 0.51055E-10 -10.2920 0.12453E-03 -3.9047 31 AgCl4-3 0.79473E-05 -5.0998 0.92762E-14 -14.0326 0.11672E-08 -8.9329 34 Ag(HS),aq 0.17409E-09 -9.7592 0.17409E-09 -9.7592 0.10000E+01 0.0000 35 Ag(HS)2- 0.53220E-09 -9.2739 0.42827E-10 -10.3683 0.80471E-01 -1.0944 36 AlO+ 0.38734E-10 -10.4119 0.36343E-11 -11.4396 0.93825E-01 -1.0277 38 HAlO2,aq 0.53952E-08 -8.2680 0.53952E-08 -8.2680 0.10000E+01 0.0000 39 AlO2- 0.16114E-04 -4.7928 0.10773E-05 -5.9677 0.66852E-01 -1.1749 41 Ba(HCO3)+ 0.12896E-06 -6.8896 0.12831E-07 -7.8917 0.99498E-01 -1.0022 42 BaCl+ 0.63662E-05 -5.1961 0.59731E-06 -6.2238 0.93825E-01 -1.0277 43 CH4,aq 0.11688E-08 -8.9323 0.13540E-08 -8.8684 0.11584E+01 0.0639 48 CO,aq 0.34642E-03 -3.4604 0.34642E-03 -3.4604 0.10000E+01 0.0000 49 CO2,aq 0.26728E+01 0.4270 0.30962E+01 0.4908 0.11584E+01 0.0639 50 CO3-2 0.21490E-09 -9.6678 0.26762E-13 -13.5725 0.12453E-03 -3.9047 52 Ca(HCO3)+ 0.59397E-07 -7.2262 0.55729E-08 -8.2539 0.93825E-01 -1.0277 53 CaCl+ 0.75977E-04 -4.1193 0.71286E-05 -5.1470 0.93825E-01 -1.0277 54 CaCl2,aq 0.58273E-04 -4.2345 0.58273E-04 -4.2345 0.10000E+01 0.0000 55 CaOH+ 0.13605E-06 -6.8663 0.12765E-07 -7.8940 0.93825E-01 -1.0277 56 CaSO4,aq 0.22515E-06 -6.6475 0.22515E-06 -6.6475 0.10000E+01 0.0000 57 HCl,aq 0.83383E-02 -2.0789 0.83383E-02 -2.0789 0.10000E+01 0.0000 66 CuCl,aq 0.17956E-04 -4.7458 0.17956E-04 -4.7458 0.10000E+01 0.0000 67 CuCl2- 0.80781E-04 -4.0927 0.65006E-05 -5.1870 0.80471E-01 -1.0944 68 CuCl3-2 0.47536E-05 -5.3230 0.59199E-09 -9.2277 0.12453E-03 -3.9047 74 FeCl+ 0.32410E-06 -6.4893 0.30408E-07 -7.5170 0.93825E-01 -1.0277 75 FeCl2,aq 0.14875E-02 -2.8275 0.14875E-02 -2.8275 0.10000E+01 0.0000 77 FeO,aq 0.38243E-07 -7.4174 0.38243E-07 -7.4174 0.10000E+01 0.0000 78 FeOH+ 0.25967E-07 -7.5856 0.24364E-08 -8.6133 0.93825E-01 -1.0277 79 HFeO2- 0.60478E-08 -8.2184 0.48667E-09 -9.3128 0.80471E-01 -1.0944 82 FeO2- 0.31562E-08 -8.5008 0.25399E-09 -9.5952 0.80471E-01 -1.0944 83 HFeO2,aq 0.28238E-09 -9.5492 0.28238E-09 -9.5492 0.10000E+01 0.0000 84 H2,aq 0.41249E-02 -2.3846 0.47784E-02 -2.3207 0.11584E+01 0.0639 85 KCl,aq 0.68162E-01 -1.1665 0.68162E-01 -1.1665 0.10000E+01 0.0000 86 KHSO4,aq 0.10899E-01 -1.9626 0.10899E-01 -1.9626 0.10000E+01 0.0000 87 KOH,aq 0.12701E-05 -5.8962 0.12701E-05 -5.8962 0.10000E+01 0.0000 88 KSO4- 0.62656E-02 -2.2030 0.50420E-03 -3.2974 0.80471E-01 -1.0944 90 Mg(HCO3)+ 0.95318E-08 -8.0208 0.89433E-09 -9.0485 0.93825E-01 -1.0277 91 MgCl+ 0.10507E-04 -4.9785 0.98582E-06 -6.0062 0.93825E-01 -1.0277 92 MgOH+ 0.35886E-06 -6.4451 0.33670E-07 -7.4728 0.93825E-01 -1.0277 94 MnO,aq 0.70231E-07 -7.1535 0.70231E-07 -7.1535 0.10000E+01 0.0000 95 MnOH+ 0.24142E-06 -6.6172 0.22652E-07 -7.6449 0.93825E-01 -1.0277 97 HMnO2- 0.37474E-10 -10.4263 0.30156E-11 -11.5206 0.80471E-01 -1.0944 100 MnCl+ 0.11389E-02 -2.9435 0.10686E-03 -3.9712 0.93825E-01 -1.0277 101 MnSO4,aq 0.23467E-06 -6.6295 0.23467E-06 -6.6295 0.10000E+01 0.0000 102 NaCl,aq 0.42469E+00 -0.3719 0.42469E+00 -0.3719 0.10000E+01 0.0000 103 NaOH,aq 0.16553E-05 -5.7811 0.16553E-05 -5.7811 0.10000E+01 0.0000 105 OH- 0.10256E-04 -4.9890 0.68561E-06 -6.1639 0.66852E-01 -1.1749 110 HPO3-2 0.32189E-10 -10.4923 0.40086E-14 -14.3970 0.12453E-03 -3.9047 111 H3PO3,aq 0.99276E-10 -10.0032 0.99276E-10 -10.0032 0.10000E+01 0.0000 112 H2PO3- 0.10440E-08 -8.9813 0.84013E-10 -10.0757 0.80471E-01 -1.0944 113 H3PO4,aq 0.17662E-05 -5.7530 0.17662E-05 -5.7530 0.10000E+01 0.0000 114 H2PO4- 0.13977E-05 -5.8546 0.12086E-06 -6.9177 0.86472E-01 -1.0631 116 H4P2O7,aq 0.31458E-09 -9.5023 0.31458E-09 -9.5023 0.10000E+01 0.0000 117 H3P2O7- 0.75091E-09 -9.1244 0.60427E-10 -10.2188 0.80471E-01 -1.0944 118 H2P2O7-2 0.59100E-06 -6.2284 0.73599E-10 -10.1331 0.12453E-03 -3.9047 119 HP2O7-3 0.21312E-05 -5.6714 0.24876E-14 -14.6042 0.11672E-08 -8.9329 120 P2O7-4 0.49176E-09 -9.3083 0.34257E-24 -24.4653 0.69662E-15 -15.1570 121 PbCl+ 0.11258E-05 -5.9485 0.10563E-06 -6.9762 0.93825E-01 -1.0277 122 PbCl2,aq 0.68831E-04 -4.1622 0.68831E-04 -4.1622 0.10000E+01 0.0000 123 PbCl3- 0.11006E-03 -3.9584 0.88566E-05 -5.0527 0.80471E-01 -1.0944 124 PbCl4-2 0.56013E-04 -4.2517 0.69755E-08 -8.1564 0.12453E-03 -3.9047 125 PbO,aq 0.57849E-08 -8.2377 0.57849E-08 -8.2377 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.89728E-04 -4.0471 0.89728E-04 -4.0471 0.10000E+01 0.0000 128 Pb(HS)3- 0.14109E-04 -4.8505 0.11354E-05 -5.9449 0.80471E-01 -1.0944 129 H2S,aq 0.10609E+01 0.0257 0.12289E+01 0.0895 0.11584E+01 0.0639 130 S2-2 0.55765E-07 -7.2536 0.69446E-11 -11.1584 0.12453E-03 -3.9047 131 S3-2 0.47413E-08 -8.3241 0.59045E-12 -12.2288 0.12453E-03 -3.9047 132 S3- 0.73101E-02 -2.1361 0.58826E-03 -3.2304 0.80471E-01 -1.0944 133 S4-2 0.35043E-09 -9.4554 0.43641E-13 -13.3601 0.12453E-03 -3.9047 134 S5-2 0.22970E-10 -10.6388 0.28605E-14 -14.5436 0.12453E-03 -3.9047 135 SO2,aq 0.29282E+00 -0.5334 0.29282E+00 -0.5334 0.10000E+01 0.0000 136 SO3-2 0.36548E-08 -8.4371 0.90433E-12 -12.0437 0.24744E-03 -3.6065 137 HSO3- 0.22679E-03 -3.6444 0.18250E-04 -4.7387 0.80471E-01 -1.0944 138 HSO4- 0.88090E-02 -2.0551 0.86160E-03 -3.0647 0.97808E-01 -1.0096 140 S2O3-2 0.29426E-05 -5.5313 0.36645E-09 -9.4360 0.12453E-03 -3.9047 141 HS2O3- 0.35435E-06 -6.4506 0.28515E-07 -7.5449 0.80471E-01 -1.0944 142 H2S2O3,aq 0.51453E-07 -7.2886 0.51453E-07 -7.2886 0.10000E+01 0.0000 150 S4O6-2 0.19116E-08 -8.7186 0.23806E-12 -12.6233 0.12453E-03 -3.9047 152 ZnCl+ 0.12321E-03 -3.9093 0.11561E-04 -4.9370 0.93825E-01 -1.0277 153 ZnCl2,aq 0.42697E-03 -3.3696 0.42697E-03 -3.3696 0.10000E+01 0.0000 154 ZnCl3- 0.27829E-04 -4.5555 0.22395E-05 -5.6499 0.80471E-01 -1.0944 155 ZnO,aq 0.21146E-07 -7.6748 0.21146E-07 -7.6748 0.10000E+01 0.0000 156 ZnOH+ 0.94858E-06 -6.0229 0.89001E-07 -7.0506 0.93825E-01 -1.0277 158 HZnO2- 0.22127E-09 -9.6551 0.17806E-10 -10.7494 0.80471E-01 -1.0944 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5460013E-05 0.4292649E+01 0.3545481E+04 0.0000 2 H2O 0.1000000E+01 0.5252819E+02 0.7754415E+06 0.0000 3 Cl- 0.1481377E+00 0.6556356E+00 0.1904718E+05 4.3192 4 SO4-- 0.1891432E-02 0.2511071E+00 0.1976624E+05 5.9074 5 HCO3- 0.6729141E-05 0.2673135E+01 0.1336559E+06 0.0231 6 HS- 0.1421139E-03 0.1152968E+01 0.3124589E+05 1.3063 7 H4SiO4 0.3222837E-01 0.3223169E-01 0.2538582E+04 -1.4918 8 Al+++ 0.5082909E-13 0.1611988E-04 0.3564043E+00 -3.4236 9 Ca++ 0.1297510E-04 0.1476514E-03 0.4849074E+01 3.5991 10 Mg++ 0.9932770E-05 0.2080916E-04 0.4145628E+00 3.3591 11 Fe++ 0.1908618E-06 0.1488124E-02 0.6810111E+02 1.6740 12 K+ 0.4020329E-01 0.1255310E+00 0.4022212E+04 3.8139 13 Na+ 0.1334572E+00 0.5581536E+00 0.1051487E+05 4.2799 14 Mn++ 0.1738189E-04 0.1156867E-02 0.5208004E+02 3.6563 15 Zn++ 0.5242678E-08 0.5789903E-03 0.3101451E+02 0.1129 16 Cu+ 0.1318225E-07 0.1035034E-03 0.5389107E+01 -2.7271 17 Pb++ 0.2051767E-07 0.3398922E-03 0.5770654E+02 0.8708 18 Ag+ 0.2176821E-10 0.8756602E-05 0.7740186E+00 -5.4626 19 Ba++ 0.3970479E-06 0.6892200E-05 0.7756575E+00 2.2037 20 HPO4-- 0.9726259E-08 0.8622406E-05 0.6781407E+00 0.6218 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265315E+01 -.2952400E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5219370E+02 -.2289184E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2495081E+00 0.2214654E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1145626E+01 0.1451776E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3202645E-01 0.1115679E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1601723E-04 0.6785223E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1467112E-03 0.3811987E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1478648E-02 0.7288105E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247316E+00 0.6785223E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.5753034E-03 0.1724031E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1028443E-03 0.2967654E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3377278E-03 0.2444843E-05 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.6848312E-05 0.4852414E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1057E-17 Mass of aqueous solution: 0.121258E+04 g Temperature = 538.00 C Pressure = 820.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3812E-03 -3.419 0.5190E-01 -1.285 0.6574 0.1751E-01 microcline 0.6785E-03 -3.168 0.1889 -0.724 2.392 0.7377E-01 pyrite 0.6991E-02 -2.155 0.8388 -0.076 10.63 0.1674 quartz 0.1095 -0.960 6.581 0.818 83.36 2.485 barite 0.4852E-04 -4.314 0.1133E-01 -1.946 0.1435 0.2528E-02 chalcopyrite 0.2968E-03 -3.528 0.5446E-01 -1.264 0.6898 0.1271E-01 galena 0.2445E-05 -5.612 0.5849E-03 -3.233 0.7409E-02 0.7698E-04 sphalerite 0.1724E-02 -2.763 0.1680 -0.775 2.128 0.4108E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.894618 g Volume = 2.800205 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.47 -15.47 0.00 0.000 0.00000E+00 112 microcline -4.08 -4.08 -0.00 -0.000 0.32966E-11 137 pyrite -22.65 -22.65 0.00 0.000 0.00000E+00 141 quartz -1.49 -1.49 -0.00 -0.000 0.82416E-12 234 barite -16.86 -16.86 0.00 0.000 0.00000E+00 237 chalcopyrite -24.40 -24.40 0.00 0.000 0.00000E+00 242 galena -10.31 -10.31 -0.00 -0.000 0.65933E-11 252 sphalerite -11.07 -11.07 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.24 -0.00 -0.25 -0.246 0.91192E+03 2.668 2 CO2,gas -10.64 -12.46 -1.82 -0.608 0.67673E+04 1.091 3 CH4,gas 6.72 -4.58 -11.30 -2.826 0.41953E+05 -8.389 4 H2,gas 6.10 1.97 -4.13 -2.358 0.15318E+05 -1.213 5 H2S,gas -8.85 -11.18 -2.33 -1.164 0.86395E+04 0.586 6 CO,gas -4.19 -10.49 -6.30 -1.937 0.23370E+05 -3.383 7 SO3,gas -8.12 -19.06 -10.94 -2.736 0.40618E+05 -8.029 8 O2,gas 17.33 -3.94 -21.27 -14.182 0.78958E+05 -18.359 9 HCl,gas -6.43 -8.17 -1.74 -0.868 0.64405E+04 -1.735 10 acmite 3.70 1.99 -1.71 -0.177 0.63388E+04 12 akimotoite 6.76 1.87 -4.89 -0.978 0.18154E+05 13 akimotoite-Fe 4.52 0.18 -4.34 -0.867 0.16096E+05 14 albite-high -3.42 -3.61 -0.19 -0.015 0.72188E+03 15 albite -3.44 -3.61 -0.17 -0.013 0.64430E+03 16 almandine -3.74 -6.30 -2.56 -0.128 0.94960E+04 17 pyrope 3.37 -1.25 -4.62 -0.231 0.17130E+05 18 analcite -1.09 -2.13 -1.04 -0.115 0.38561E+04 19 andalusite -7.71 -8.34 -0.63 -0.063 0.23337E+04 24 anorthite -5.20 -6.23 -1.04 -0.080 0.38425E+04 26 anthophyllite-Fe 4.05 -0.21 -4.25 -0.115 0.15787E+05 27 apatite-OH -54.54 -55.06 -0.52 -0.040 0.19146E+04 28 apatite-OH-zs -52.28 -55.06 -2.78 -0.214 0.10320E+05 29 apatite-Cl-zs -59.36 -63.22 -3.86 -0.322 0.14334E+05 30 aragonite -4.91 -8.86 -3.95 -1.318 0.14672E+05 31 brucite 6.19 3.36 -2.83 -0.566 0.10512E+05 32 calcite -5.02 -8.86 -3.84 -1.280 0.14253E+05 33 carnegieite-low 1.23 -0.64 -1.86 -0.266 0.69197E+04 34 carnegieite-high 1.33 -0.64 -1.97 -0.281 0.72935E+04 35 carpholite-Mg -3.86 -6.47 -2.61 -0.174 0.96996E+04 36 carpholite-Fe -5.33 -8.16 -2.83 -0.189 0.10516E+05 37 celadonite 0.45 -2.21 -2.67 -0.157 0.98972E+04 38 celadonite-Fe -1.05 -3.90 -2.85 -0.168 0.10572E+05 39 chrysotile 11.09 7.09 -4.00 -0.333 0.14843E+05 41 clinochlore 9.47 5.47 -4.00 -0.125 0.14850E+05 42 daphnite 1.84 -2.96 -4.80 -0.150 0.17808E+05 45 chloritoid-Mg -3.03 -4.98 -1.95 -0.130 0.72524E+04 46 chloritoid-Fe -5.13 -6.67 -1.54 -0.103 0.57104E+04 47 chloritoid-Mn -3.01 -4.69 -1.68 -0.112 0.62271E+04 49 coesite -1.19 -1.49 -0.30 -0.101 0.11259E+04 50 cordierite-H -12.20 -14.43 -2.24 -0.080 0.83038E+04 51 cordierite-Fe -15.05 -17.80 -2.76 -0.095 0.10227E+05 52 cordierite-Mn -10.74 -13.84 -3.10 -0.107 0.11493E+05 53 corundum -6.04 -6.85 -0.81 -0.074 0.30226E+04 55 cristobalite -1.44 -1.49 -0.05 -0.017 0.18525E+03 58 cymrite-K -1.67 -4.08 -2.41 -0.201 0.89362E+04 60 diaspore -2.55 -3.43 -0.88 -0.146 0.32535E+04 62 diopside 6.11 3.98 -2.13 -0.213 0.78990E+04 63 hedenbergite 4.57 2.29 -2.28 -0.228 0.84518E+04 65 eastonite -0.21 -2.73 -2.52 -0.097 0.93476E+04 66 enstatite 5.74 3.74 -2.01 -0.201 0.74457E+04 67 clinoenstatite-HiP 6.26 3.74 -2.52 -0.252 0.93593E+04 68 clinoenstatite 5.72 3.74 -1.98 -0.198 0.73664E+04 69 protoenstatite 5.88 3.74 -2.15 -0.215 0.79702E+04 70 epidote -0.54 -3.44 -2.90 -0.140 0.10750E+05 71 clinozoisite -4.31 -7.55 -3.24 -0.147 0.12021E+05 72 epidote-Fe 4.96 0.68 -4.28 -0.222 0.15888E+05 73 fayalite 3.28 1.86 -1.43 -0.204 0.52912E+04 74 ferrosilite 1.90 0.37 -1.53 -0.153 0.56789E+04 75 forsterite 7.55 5.23 -2.33 -0.333 0.86407E+04 78 gibbsite -0.91 -3.43 -2.52 -0.359 0.93349E+04 79 glaucophane 4.61 -0.13 -4.74 -0.128 0.17598E+05 81 goethite 1.68 0.69 -1.00 -0.215 0.36985E+04 83 greenalite 5.83 2.04 -3.79 -0.316 0.14083E+05 84 grunerite 4.64 -0.21 -4.85 -0.131 0.17995E+05 85 halite -1.81 -3.89 -2.08 -1.040 0.77214E+04 86 hematite 1.82 1.37 -0.44 -0.053 0.16364E+04 87 heulandite -10.25 -13.69 -3.44 -0.156 0.12757E+05 88 hercynite -3.67 -5.18 -1.51 -0.100 0.55907E+04 91 jadeite -0.40 -2.12 -1.72 -0.172 0.63892E+04 93 kalsilite 0.59 -1.10 -1.69 -0.242 0.62907E+04 94 kaolinite -7.08 -9.83 -2.75 -0.250 0.10207E+05 95 kyanite -7.54 -8.34 -0.80 -0.080 0.29549E+04 97 laumontite -5.34 -9.22 -3.87 -0.258 0.14376E+05 98 lawsonite -2.47 -6.23 -3.77 -0.251 0.13983E+05 99 leucite -1.56 -2.59 -1.03 -0.103 0.38080E+04 101 lizardite 11.24 7.09 -4.15 -0.345 0.15385E+05 102 magnesite -5.51 -9.10 -3.59 -1.198 0.13335E+05 103 magnetite 3.64 3.05 -0.59 -0.048 0.21945E+04 104 minnesotaite 1.60 -0.94 -2.54 -0.150 0.94348E+04 105 minnesotaite-Mg 7.99 4.12 -3.87 -0.228 0.14370E+05 106 magnesioferrite 6.89 4.73 -2.16 -0.176 0.80153E+04 108 manganosite 6.03 3.66 -2.38 -0.594 0.88254E+04 109 margarite -10.83 -13.08 -2.25 -0.090 0.83683E+04 113 monticellite 9.82 5.47 -4.36 -0.622 0.16168E+05 115 mullite-Si -6.92 -8.34 -1.42 -0.142 0.52794E+04 116 muscovite -10.02 -10.93 -0.91 -0.053 0.33678E+04 117 paragonite -9.32 -10.47 -1.14 -0.067 0.42410E+04 118 nepheline 0.92 -0.64 -1.55 -0.222 0.57587E+04 119 osumilite(2) -8.93 -12.77 -3.84 -0.080 0.14264E+05 120 osumilite-Fe -21.65 -24.86 -3.21 -0.067 0.11928E+05 122 periclase 6.44 3.36 -3.08 -0.770 0.11435E+05 123 periclase-Fe 3.71 1.67 -2.04 -0.510 0.75654E+04 124 perovskite-Al -4.24 -6.85 -2.61 -0.237 0.96898E+04 129 phlogopite-Na 8.99 6.46 -2.53 -0.140 0.93855E+04 131 prehnite -0.31 -4.12 -3.82 -0.224 0.14161E+05 132 prehnite-Fe 3.87 -0.01 -3.88 -0.233 0.14395E+05 135 px-Mg-tschermaks -2.30 -4.98 -2.68 -0.191 0.99467E+04 136 px-Ca-tschermaks -1.76 -4.74 -2.98 -0.213 0.11075E+05 138 pyrrhotite -8.70 -9.51 -0.81 -0.270 0.30040E+04 139 pyrrhotiteFe0.875 -9.57 -9.96 -0.39 -0.144 0.14537E+04 140 pyrophyllite -11.35 -12.81 -1.46 -0.091 0.54263E+04 143 riebeckite 6.66 3.04 -3.62 -0.100 0.13444E+05 144 ringwoodite-Fe 4.30 1.86 -2.44 -0.349 0.90585E+04 146 rhodochrosite -5.65 -8.81 -3.16 -1.052 0.11711E+05 147 rhodonite 2.86 2.17 -0.70 -0.140 0.25907E+04 148 sanidine -3.52 -4.08 -0.56 -0.043 0.20682E+04 150 siderite -7.49 -10.79 -3.30 -1.100 0.12249E+05 151 sillimanite -7.67 -8.34 -0.67 -0.067 0.24985E+04 153 spinel -1.37 -3.49 -2.13 -0.142 0.78984E+04 160 stilpnomelane-Mg 4.75 -0.08 -4.83 -0.144 0.17909E+05 161 stishovite 1.56 -1.49 -3.05 -1.017 0.11320E+05 162 sudoite-Fe -9.92 -14.83 -4.91 -0.158 0.18231E+05 163 sudoite -7.49 -11.46 -3.97 -0.128 0.14730E+05 164 sulfur -11.66 -13.15 -1.49 -0.458 0.55284E+04 165 sylvite -1.72 -4.35 -2.64 -1.319 0.97878E+04 166 talc 6.20 4.12 -2.09 -0.123 0.77493E+04 167 talc-Fe 3.06 -0.94 -4.00 -0.235 0.14858E+05 168 talc-tschermaks -1.76 -4.60 -2.84 -0.167 0.10545E+05 170 tephroite 7.48 5.82 -1.66 -0.237 0.61558E+04 173 topaz-H -5.63 -8.34 -2.71 -0.246 0.10063E+05 176 troilite-low -8.61 -9.51 -0.90 -0.298 0.33235E+04 180 wadsleyite-Fe 4.16 1.86 -2.30 -0.329 0.85471E+04 181 wadsleyite-Mg 9.85 5.23 -4.62 -0.660 0.17143E+05 182 wairakite -7.23 -9.21 -1.99 -0.117 0.73722E+04 183 walstromite 4.88 2.11 -2.77 -0.555 0.10295E+05 184 wollastonite 4.44 2.11 -2.33 -0.466 0.86520E+04 185 pseudo-wollastonite 4.57 2.11 -2.46 -0.492 0.91223E+04 186 zoisite -4.35 -7.55 -3.19 -0.145 0.11858E+05 189 beidellite-Ca -11.00 -12.85 -1.86 -0.115 0.68942E+04 190 beidellite-H -11.08 -13.45 -2.37 -0.151 0.87839E+04 191 beidellite-K -10.05 -12.19 -2.14 -0.131 0.79510E+04 192 beidellite-Mg -11.21 -12.89 -1.69 -0.104 0.62636E+04 193 beidellite-Na -9.99 -12.04 -2.05 -0.125 0.75990E+04 194 bornite -57.52 -57.66 -0.15 -0.011 0.55307E+03 196 chalcocite -15.23 -16.63 -1.41 -0.351 0.52165E+04 197 covellite -13.59 -14.89 -1.30 -0.495 0.48212E+04 199 montmorillonite-Ca -8.42 -9.98 -1.56 -0.096 0.57813E+04 200 montmorillonite-K -7.74 -9.31 -1.57 -0.096 0.58399E+04 201 montmorillonite-Mg -8.60 -10.02 -1.42 -0.088 0.52592E+04 202 montmorillonite-Na -7.42 -9.16 -1.74 -0.107 0.64567E+04 203 nontronite-Ca -2.86 -4.63 -1.77 -0.115 0.65561E+04 204 nontronite-H -2.95 -5.22 -2.27 -0.152 0.84186E+04 205 nontronite-K -1.92 -3.96 -2.05 -0.132 0.76054E+04 206 nontronite-Mg -3.05 -4.67 -1.62 -0.105 0.60260E+04 207 nontronite-Na -1.85 -3.81 -1.96 -0.126 0.72631E+04 212 gypsum -13.18 -15.47 -2.29 -0.573 0.85014E+04 229 alabandite -6.43 -7.52 -1.09 -0.364 0.40512E+04 231 anglesite -15.90 -18.19 -2.30 -1.148 0.85249E+04 235 boehmite -2.23 -3.43 -1.19 -0.199 0.44255E+04 239 copper,native 1.67 -1.74 -3.41 -1.188 0.12672E+05 241 ferrous-oxide 2.76 1.67 -1.09 -0.272 0.40386E+04 243 silver,native 0.32 -4.48 -4.79 -1.668 0.17796E+05 245 litharge 5.60 0.87 -4.73 -1.183 0.17565E+05 253 wurtzite -10.23 -11.07 -0.83 -0.278 0.30909E+04 254 zincite 2.81 0.11 -2.69 -0.674 0.99998E+04 255 an20ab80 -4.01 -4.14 -0.13 -0.010 0.47736E+03 256 an25ab75 -4.12 -4.27 -0.14 -0.011 0.53753E+03 257 an30ab70 -4.23 -4.40 -0.17 -0.013 0.61998E+03 258 tr.625ac.25prg.125 12.77 9.17 -3.61 -0.097 0.13394E+05 Calculations done for 538.0000 Deg. C; 820.0000 bar Temperature changed by -1.000 degrees to 537.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 70 Loop limit = 500 Temperature = 537.00 C Pressure = 812.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5516E+02 kg liquid = 0.9936E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9971 Stoichiometric ionic strength = .3267744E+01 Osmotic coef. = 0.0000 True ionic strength = .1780255E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54776E-05 -5.2614 0.55954E-06 -6.2522 0.10215E+00 -0.9908 2 H2O 0.99708E+00 -0.0013 0.99708E+00 -0.0013 3 Cl- 0.14861E+00 -0.8279 0.11626E-01 -1.9346 0.78229E-01 -1.1066 4 SO4-- 0.20396E-02 -2.6905 0.25741E-06 -6.5894 0.12621E-03 -3.8989 5 HCO3- 0.66211E-05 -5.1791 0.57723E-06 -6.2386 0.87181E-01 -1.0596 6 HS- 0.14297E-03 -3.8448 0.11319E-04 -4.9462 0.79170E-01 -1.1014 7 H4SiO4 0.31683E-01 -1.4992 0.31683E-01 -1.4992 0.10000E+01 0.0000 8 Al+++ 0.69102E-13 -13.1605 0.75815E-22 -22.1202 0.10972E-08 -8.9597 9 Ca++ 0.14137E-04 -4.8496 0.12737E-08 -8.8949 0.90100E-04 -4.0453 10 Mg++ 0.10377E-04 -4.9839 0.70055E-09 -9.1546 0.67508E-04 -4.1706 11 Fe++ 0.21102E-06 -6.6757 0.15322E-10 -10.8147 0.72610E-04 -4.1390 12 K+ 0.40320E-01 -1.3945 0.36358E-02 -2.4394 0.90173E-01 -1.0449 13 Na+ 0.13408E+00 -0.8726 0.10635E-01 -1.9733 0.79320E-01 -1.1006 14 Mn++ 0.19302E-04 -4.7144 0.14783E-08 -8.8302 0.76590E-04 -4.1158 15 Zn++ 0.58288E-08 -8.2344 0.42323E-12 -12.3734 0.72610E-04 -4.1390 16 Cu+ 0.13136E-07 -7.8815 0.10380E-08 -8.9838 0.79013E-01 -1.1023 17 Pb++ 0.22013E-07 -7.6573 0.23491E-11 -11.6291 0.10672E-03 -3.9718 18 Ag+ 0.19090E-10 -10.7192 0.16816E-11 -11.7743 0.88090E-01 -1.0551 19 Ba++ 0.42272E-06 -6.3739 0.50235E-10 -10.2990 0.11884E-03 -3.9251 20 HPO4-- 0.99229E-08 -8.0034 0.12618E-11 -11.8990 0.12716E-03 -3.8956 21 HSiO3- 0.15378E-05 -5.8131 0.12030E-06 -6.9197 0.78229E-01 -1.1066 22 Ca(HSiO3)+ 0.47843E-08 -8.3202 0.43709E-09 -9.3594 0.91359E-01 -1.0393 23 Mg(HSiO3)+ 0.10205E-08 -8.9912 0.93235E-10 -10.0304 0.91359E-01 -1.0393 24 NaHSiO3,aq 0.17834E-05 -5.7488 0.17834E-05 -5.7488 0.10000E+01 0.0000 28 AgCl,aq 0.67175E-08 -8.1728 0.67175E-08 -8.1728 0.10000E+01 0.0000 29 AgCl2- 0.34237E-06 -6.4655 0.26783E-07 -7.5721 0.78229E-01 -1.1066 30 AgCl3-2 0.37219E-06 -6.4292 0.41861E-10 -10.3782 0.11247E-03 -3.9490 31 AgCl4-3 0.80346E-05 -5.0950 0.74191E-14 -14.1296 0.92340E-09 -9.0346 34 Ag(HS),aq 0.15503E-09 -9.8096 0.15503E-09 -9.8096 0.10000E+01 0.0000 35 Ag(HS)2- 0.46804E-09 -9.3297 0.36615E-10 -10.4363 0.78229E-01 -1.1066 36 AlO+ 0.41034E-10 -10.3869 0.37488E-11 -11.4261 0.91359E-01 -1.0393 38 HAlO2,aq 0.54578E-08 -8.2630 0.54578E-08 -8.2630 0.10000E+01 0.0000 39 AlO2- 0.16270E-04 -4.7886 0.10553E-05 -5.9766 0.64865E-01 -1.1880 41 Ba(HCO3)+ 0.12597E-06 -6.8997 0.12213E-07 -7.9132 0.96947E-01 -1.0135 42 BaCl+ 0.62725E-05 -5.2026 0.57305E-06 -6.2418 0.91359E-01 -1.0393 43 CH4,aq 0.11569E-08 -8.9367 0.13386E-08 -8.8733 0.11571E+01 0.0634 48 CO,aq 0.34047E-03 -3.4679 0.34047E-03 -3.4679 0.10000E+01 0.0000 49 CO2,aq 0.26728E+01 0.4270 0.30925E+01 0.4903 0.11571E+01 0.0634 50 CO3-2 0.22885E-09 -9.6405 0.25739E-13 -13.5894 0.11247E-03 -3.9490 52 Ca(HCO3)+ 0.58008E-07 -7.2365 0.52995E-08 -8.2758 0.91359E-01 -1.0393 53 CaCl+ 0.75842E-04 -4.1201 0.69288E-05 -5.1593 0.91359E-01 -1.0393 54 CaCl2,aq 0.57586E-04 -4.2397 0.57586E-04 -4.2397 0.10000E+01 0.0000 55 CaOH+ 0.13539E-06 -6.8684 0.12369E-07 -7.9077 0.91359E-01 -1.0393 56 CaSO4,aq 0.22850E-06 -6.6411 0.22850E-06 -6.6411 0.10000E+01 0.0000 57 HCl,aq 0.86959E-02 -2.0607 0.86959E-02 -2.0607 0.10000E+01 0.0000 66 CuCl,aq 0.17837E-04 -4.7487 0.17837E-04 -4.7487 0.10000E+01 0.0000 67 CuCl2- 0.80907E-04 -4.0920 0.63293E-05 -5.1986 0.78229E-01 -1.1066 68 CuCl3-2 0.49413E-05 -5.3062 0.55575E-09 -9.2551 0.11247E-03 -3.9490 74 FeCl+ 0.32758E-06 -6.4847 0.29927E-07 -7.5239 0.91359E-01 -1.0393 75 FeCl2,aq 0.14418E-02 -2.8411 0.14418E-02 -2.8411 0.10000E+01 0.0000 77 FeO,aq 0.37461E-07 -7.4264 0.37461E-07 -7.4264 0.10000E+01 0.0000 78 FeOH+ 0.26181E-07 -7.5820 0.23919E-08 -8.6213 0.91359E-01 -1.0393 79 HFeO2- 0.59993E-08 -8.2219 0.46932E-09 -9.3285 0.78229E-01 -1.1066 82 FeO2- 0.30976E-08 -8.5090 0.24233E-09 -9.6156 0.78229E-01 -1.1066 83 HFeO2,aq 0.28171E-09 -9.5502 0.28171E-09 -9.5502 0.10000E+01 0.0000 84 H2,aq 0.41040E-02 -2.3868 0.47485E-02 -2.3234 0.11571E+01 0.0634 85 KCl,aq 0.68053E-01 -1.1672 0.68053E-01 -1.1672 0.10000E+01 0.0000 86 KHSO4,aq 0.10823E-01 -1.9657 0.10823E-01 -1.9657 0.10000E+01 0.0000 87 KOH,aq 0.12678E-05 -5.8969 0.12678E-05 -5.8969 0.10000E+01 0.0000 88 KSO4- 0.63323E-02 -2.1984 0.49537E-03 -3.3051 0.78229E-01 -1.1066 90 Mg(HCO3)+ 0.88192E-08 -8.0546 0.80571E-09 -9.0938 0.91359E-01 -1.0393 91 MgCl+ 0.10079E-04 -4.9966 0.92084E-06 -6.0358 0.91359E-01 -1.0393 92 MgOH+ 0.34231E-06 -6.4656 0.31273E-07 -7.5048 0.91359E-01 -1.0393 94 MnO,aq 0.69504E-07 -7.1580 0.69504E-07 -7.1580 0.10000E+01 0.0000 95 MnOH+ 0.24319E-06 -6.6141 0.22217E-07 -7.6533 0.91359E-01 -1.0393 97 HMnO2- 0.37260E-10 -10.4288 0.29148E-11 -11.5354 0.78229E-01 -1.1066 100 MnCl+ 0.11370E-02 -2.9442 0.10387E-03 -3.9835 0.91359E-01 -1.0393 101 MnSO4,aq 0.24023E-06 -6.6194 0.24023E-06 -6.6194 0.10000E+01 0.0000 102 NaCl,aq 0.42407E+00 -0.3726 0.42407E+00 -0.3726 0.10000E+01 0.0000 103 NaOH,aq 0.16507E-05 -5.7823 0.16507E-05 -5.7823 0.10000E+01 0.0000 105 OH- 0.10367E-04 -4.9843 0.67247E-06 -6.1723 0.64865E-01 -1.1880 110 HPO3-2 0.31685E-10 -10.4992 0.35636E-14 -14.4481 0.11247E-03 -3.9490 111 H3PO3,aq 0.93746E-10 -10.0280 0.93746E-10 -10.0280 0.10000E+01 0.0000 112 H2PO3- 0.96271E-09 -9.0165 0.75311E-10 -10.1231 0.78229E-01 -1.1066 113 H3PO4,aq 0.16992E-05 -5.7697 0.16992E-05 -5.7697 0.10000E+01 0.0000 114 H2PO4- 0.13249E-05 -5.8778 0.11146E-06 -6.9529 0.84128E-01 -1.0751 116 H4P2O7,aq 0.29208E-09 -9.5345 0.29208E-09 -9.5345 0.10000E+01 0.0000 117 H3P2O7- 0.67082E-09 -9.1734 0.52478E-10 -10.2800 0.78229E-01 -1.1066 118 H2P2O7-2 0.54779E-06 -6.2614 0.61610E-10 -10.2103 0.11247E-03 -3.9490 119 HP2O7-3 0.22442E-05 -5.6489 0.20723E-14 -14.6836 0.92340E-09 -9.0346 120 P2O7-4 0.63433E-09 -9.1977 0.29625E-24 -24.5283 0.46702E-15 -15.3307 121 PbCl+ 0.11158E-05 -5.9524 0.10194E-06 -6.9917 0.91359E-01 -1.0393 122 PbCl2,aq 0.68065E-04 -4.1671 0.68065E-04 -4.1671 0.10000E+01 0.0000 123 PbCl3- 0.10983E-03 -3.9593 0.85918E-05 -5.0659 0.78229E-01 -1.1066 124 PbCl4-2 0.57820E-04 -4.2379 0.65031E-08 -8.1869 0.11247E-03 -3.9490 125 PbO,aq 0.57331E-08 -8.2416 0.57331E-08 -8.2416 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.88436E-04 -4.0534 0.88436E-04 -4.0534 0.10000E+01 0.0000 128 Pb(HS)3- 0.14037E-04 -4.8527 0.10981E-05 -5.9594 0.78229E-01 -1.1066 129 H2S,aq 0.10611E+01 0.0257 0.12277E+01 0.0891 0.11571E+01 0.0634 130 S2-2 0.58659E-07 -7.2317 0.65974E-11 -11.1806 0.11247E-03 -3.9490 131 S3-2 0.49714E-08 -8.3035 0.55914E-12 -12.2525 0.11247E-03 -3.9490 132 S3- 0.71950E-02 -2.1430 0.56286E-03 -3.2496 0.78229E-01 -1.1066 133 S4-2 0.36667E-09 -9.4357 0.41240E-13 -13.3847 0.11247E-03 -3.9490 134 S5-2 0.24025E-10 -10.6193 0.27021E-14 -14.5683 0.11247E-03 -3.9490 135 SO2,aq 0.29269E+00 -0.5336 0.29269E+00 -0.5336 0.10000E+01 0.0000 136 SO3-2 0.38948E-08 -8.4095 0.87728E-12 -12.0569 0.22524E-03 -3.6474 137 HSO3- 0.22531E-03 -3.6472 0.17626E-04 -4.7539 0.78229E-01 -1.1066 138 HSO4- 0.88221E-02 -2.0544 0.84062E-03 -3.0754 0.95286E-01 -1.0210 140 S2O3-2 0.31304E-05 -5.5044 0.35208E-09 -9.4534 0.11247E-03 -3.9490 141 HS2O3- 0.35323E-06 -6.4519 0.27632E-07 -7.5586 0.78229E-01 -1.1066 142 H2S2O3,aq 0.52525E-07 -7.2796 0.52525E-07 -7.2796 0.10000E+01 0.0000 150 S4O6-2 0.20128E-08 -8.6962 0.22638E-12 -12.6452 0.11247E-03 -3.9490 152 ZnCl+ 0.12188E-03 -3.9141 0.11135E-04 -4.9533 0.91359E-01 -1.0393 153 ZnCl2,aq 0.42055E-03 -3.3762 0.42055E-03 -3.3762 0.10000E+01 0.0000 154 ZnCl3- 0.27190E-04 -4.5656 0.21270E-05 -5.6722 0.78229E-01 -1.1066 155 ZnO,aq 0.20879E-07 -7.6803 0.20879E-07 -7.6803 0.10000E+01 0.0000 156 ZnOH+ 0.94285E-06 -6.0256 0.86137E-07 -7.0648 0.91359E-01 -1.0393 158 HZnO2- 0.22124E-09 -9.6551 0.17307E-10 -10.7618 0.78229E-01 -1.1066 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5477630E-05 0.4292589E+01 0.3545592E+04 0.0000 2 H2O 0.1000000E+01 0.5252862E+02 0.7754831E+06 0.0000 3 Cl- 0.1486123E+00 0.6556269E+00 0.1904779E+05 4.3176 4 SO4-- 0.2039577E-02 0.2510926E+00 0.1976599E+05 5.9150 5 HCO3- 0.6621083E-05 0.2673099E+01 0.1336602E+06 0.0135 6 HS- 0.1429690E-03 0.1152864E+01 0.3124449E+05 1.3060 7 H4SiO4 0.3168311E-01 0.3168644E-01 0.2495751E+04 -1.4992 8 Al+++ 0.6910197E-13 0.1627518E-04 0.3598543E+00 -3.3637 9 Ca++ 0.1413696E-04 0.1479914E-03 0.4860459E+01 3.6094 10 Mg++ 0.1037735E-04 0.2080888E-04 0.4145761E+00 3.3498 11 Fe++ 0.2110151E-06 0.1442456E-02 0.6601417E+02 1.6896 12 K+ 0.4031977E-01 0.1255294E+00 0.4022346E+04 3.8128 13 Na+ 0.1340764E+00 0.5581461E+00 0.1051521E+05 4.2789 14 Mn++ 0.1930171E-04 0.1156851E-02 0.5208170E+02 3.6741 15 Zn++ 0.5828778E-08 0.5705855E-03 0.3056568E+02 0.1309 16 Cu+ 0.1313640E-07 0.1036990E-03 0.5399539E+01 -2.7317 17 Pb++ 0.2201263E-07 0.3393311E-03 0.5761389E+02 0.8752 18 Ag+ 0.1908967E-10 0.8756486E-05 0.7740434E+00 -5.5221 19 Ba++ 0.4227211E-06 0.6821207E-05 0.7677028E+00 2.2053 20 HPO4-- 0.9922917E-08 0.8622291E-05 0.6781624E+00 0.6053 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265311E+01 -.2949119E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5219483E+02 -.2300469E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2494970E+00 0.2225748E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1145538E+01 0.1460601E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3148509E-01 0.1121092E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1617176E-04 0.6783678E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1470510E-03 0.3808589E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1433290E-02 0.7333464E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247318E+00 0.6783678E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.5669596E-03 0.1732375E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1030401E-03 0.2965696E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3371748E-03 0.2997880E-05 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.6777862E-05 0.4859459E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1220E-17 Mass of aqueous solution: 0.121254E+04 g Temperature = 537.00 C Pressure = 812.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3809E-03 -3.419 0.5185E-01 -1.285 0.6536 0.1750E-01 microcline 0.6784E-03 -3.169 0.1888 -0.724 2.380 0.7376E-01 pyrite 0.7037E-02 -2.153 0.8443 -0.074 10.64 0.1685 quartz 0.1101 -0.958 6.613 0.820 83.36 2.497 barite 0.4859E-04 -4.313 0.1134E-01 -1.945 0.1430 0.2532E-02 chalcopyrite 0.2966E-03 -3.528 0.5442E-01 -1.264 0.6860 0.1270E-01 galena 0.2998E-05 -5.523 0.7172E-03 -3.144 0.9041E-02 0.9440E-04 sphalerite 0.1732E-02 -2.761 0.1688 -0.773 2.128 0.4128E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.933473 g Volume = 2.813768 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.48 -15.48 0.00 0.000 0.00000E+00 112 microcline -4.04 -4.04 -0.00 -0.000 0.16463E-10 137 pyrite -22.68 -22.68 0.00 0.000 0.00000E+00 141 quartz -1.50 -1.50 -0.00 -0.000 0.82314E-12 234 barite -16.89 -16.89 0.00 0.000 0.00000E+00 237 chalcopyrite -24.43 -24.43 0.00 0.000 0.00000E+00 242 galena -10.32 -10.32 -0.00 -0.000 0.65852E-11 252 sphalerite -11.07 -11.07 -0.00 -0.000 0.13170E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.24 -0.00 -0.25 -0.245 0.90922E+03 2.664 2 CO2,gas -10.66 -12.49 -1.83 -0.610 0.67785E+04 1.081 3 CH4,gas 6.72 -4.60 -11.31 -2.829 0.41944E+05 -8.405 4 H2,gas 6.10 1.97 -4.13 -2.360 0.15310E+05 -1.220 5 H2S,gas -8.87 -11.20 -2.33 -1.164 0.86310E+04 0.581 6 CO,gas -4.21 -10.52 -6.31 -1.941 0.23384E+05 -3.398 7 SO3,gas -8.14 -19.09 -10.96 -2.739 0.40614E+05 -8.046 8 O2,gas 17.35 -3.95 -21.30 -14.201 0.78965E+05 -18.391 9 HCl,gas -6.44 -8.19 -1.74 -0.872 0.64657E+04 -1.744 10 acmite 3.70 1.99 -1.72 -0.178 0.63621E+04 12 akimotoite 6.79 1.85 -4.93 -0.987 0.18289E+05 13 akimotoite-Fe 4.54 0.19 -4.35 -0.870 0.16124E+05 14 albite-high -3.38 -3.58 -0.20 -0.015 0.72947E+03 15 albite -3.40 -3.58 -0.17 -0.013 0.64833E+03 16 almandine -3.57 -6.16 -2.59 -0.129 0.95889E+04 17 pyrope 3.56 -1.18 -4.73 -0.237 0.17548E+05 18 analcite -1.04 -2.08 -1.04 -0.116 0.38594E+04 19 andalusite -7.60 -8.23 -0.63 -0.063 0.23375E+04 24 anorthite -5.07 -6.12 -1.04 -0.080 0.38729E+04 26 anthophyllite-Fe 4.15 -0.16 -4.31 -0.116 0.15969E+05 27 apatite-OH -54.56 -55.16 -0.61 -0.047 0.22549E+04 28 apatite-OH-zs -52.29 -55.16 -2.88 -0.221 0.10662E+05 29 apatite-Cl-zs -59.39 -63.35 -3.96 -0.330 0.14673E+05 30 aragonite -4.92 -8.88 -3.96 -1.321 0.14695E+05 31 brucite 6.22 3.35 -2.87 -0.574 0.10639E+05 32 calcite -5.03 -8.88 -3.85 -1.284 0.14275E+05 33 carnegieite-low 1.28 -0.58 -1.87 -0.267 0.69233E+04 34 carnegieite-high 1.39 -0.58 -1.97 -0.281 0.73001E+04 35 carpholite-Mg -3.73 -6.38 -2.65 -0.177 0.98183E+04 36 carpholite-Fe -5.20 -8.04 -2.84 -0.189 0.10527E+05 37 celadonite 0.51 -2.19 -2.70 -0.159 0.10022E+05 38 celadonite-Fe -1.00 -3.85 -2.86 -0.168 0.10592E+05 39 chrysotile 11.16 7.05 -4.11 -0.342 0.15229E+05 41 clinochlore 9.69 5.52 -4.18 -0.131 0.15486E+05 42 daphnite 2.05 -2.78 -4.83 -0.151 0.17909E+05 45 chloritoid-Mg -2.89 -4.88 -1.99 -0.133 0.73797E+04 46 chloritoid-Fe -5.00 -6.54 -1.54 -0.103 0.57263E+04 47 chloritoid-Mn -2.88 -4.56 -1.68 -0.112 0.62304E+04 49 coesite -1.19 -1.50 -0.30 -0.101 0.11268E+04 50 cordierite-H -11.93 -14.25 -2.32 -0.083 0.85876E+04 51 cordierite-Fe -14.79 -17.57 -2.78 -0.096 0.10294E+05 52 cordierite-Mn -10.49 -13.60 -3.11 -0.107 0.11531E+05 53 corundum -5.91 -6.73 -0.82 -0.074 0.30265E+04 55 cristobalite -1.45 -1.50 -0.05 -0.017 0.18558E+03 58 cymrite-K -1.63 -4.04 -2.41 -0.201 0.89356E+04 60 diaspore -2.49 -3.37 -0.88 -0.146 0.32480E+04 62 diopside 6.14 3.96 -2.17 -0.217 0.80572E+04 63 hedenbergite 4.60 2.30 -2.29 -0.229 0.85031E+04 65 eastonite 0.01 -2.58 -2.59 -0.100 0.96148E+04 66 enstatite 5.79 3.70 -2.08 -0.208 0.77189E+04 67 clinoenstatite-HiP 6.30 3.70 -2.60 -0.260 0.96324E+04 68 clinoenstatite 5.76 3.70 -2.06 -0.206 0.76388E+04 69 protoenstatite 5.93 3.70 -2.22 -0.222 0.82434E+04 70 epidote -0.39 -3.30 -2.92 -0.141 0.10817E+05 71 clinozoisite -4.12 -7.37 -3.26 -0.148 0.12067E+05 72 epidote-Fe 5.07 0.76 -4.31 -0.224 0.15973E+05 73 fayalite 3.32 1.88 -1.44 -0.206 0.53471E+04 74 ferrosilite 1.93 0.38 -1.55 -0.155 0.57355E+04 75 forsterite 7.60 5.20 -2.40 -0.343 0.89128E+04 78 gibbsite -0.85 -3.37 -2.51 -0.359 0.93215E+04 79 glaucophane 4.75 -0.10 -4.85 -0.131 0.17989E+05 81 goethite 1.70 0.70 -1.00 -0.217 0.37169E+04 83 greenalite 5.89 2.07 -3.82 -0.318 0.14145E+05 84 grunerite 4.75 -0.16 -4.90 -0.133 0.18179E+05 85 halite -1.83 -3.91 -2.08 -1.041 0.77165E+04 86 hematite 1.86 1.40 -0.45 -0.055 0.16812E+04 87 heulandite -10.16 -13.61 -3.44 -0.157 0.12768E+05 88 hercynite -3.53 -5.04 -1.52 -0.101 0.56246E+04 91 jadeite -0.36 -2.08 -1.72 -0.172 0.63886E+04 93 kalsilite 0.65 -1.05 -1.70 -0.243 0.62936E+04 94 kaolinite -6.98 -9.73 -2.75 -0.250 0.10181E+05 95 kyanite -7.43 -8.23 -0.80 -0.080 0.29574E+04 97 laumontite -5.24 -9.11 -3.88 -0.259 0.14379E+05 98 lawsonite -2.35 -6.12 -3.77 -0.252 0.13989E+05 99 leucite -1.52 -2.55 -1.03 -0.103 0.38130E+04 101 lizardite 11.30 7.05 -4.25 -0.354 0.15766E+05 102 magnesite -5.51 -9.14 -3.63 -1.211 0.13469E+05 103 magnetite 3.70 3.09 -0.61 -0.050 0.22675E+04 104 minnesotaite 1.64 -0.92 -2.56 -0.151 0.95050E+04 105 minnesotaite-Mg 8.04 4.06 -3.98 -0.234 0.14763E+05 106 magnesioferrite 6.96 4.75 -2.21 -0.181 0.81971E+04 108 manganosite 6.06 3.67 -2.38 -0.596 0.88399E+04 109 margarite -10.59 -12.85 -2.26 -0.091 0.83891E+04 113 monticellite 9.86 5.46 -4.40 -0.629 0.16327E+05 115 mullite-Si -6.80 -8.23 -1.43 -0.143 0.52856E+04 116 muscovite -9.87 -10.78 -0.91 -0.053 0.33635E+04 117 paragonite -9.17 -10.31 -1.14 -0.067 0.42382E+04 118 nepheline 0.97 -0.58 -1.55 -0.222 0.57618E+04 119 osumilite(2) -8.74 -12.70 -3.96 -0.083 0.14685E+05 120 osumilite-Fe -21.37 -24.61 -3.24 -0.067 0.12000E+05 122 periclase 6.47 3.35 -3.12 -0.780 0.11571E+05 123 periclase-Fe 3.74 1.69 -2.05 -0.512 0.75940E+04 124 perovskite-Al -4.12 -6.73 -2.62 -0.238 0.96946E+04 129 phlogopite-Na 9.11 6.47 -2.64 -0.147 0.97872E+04 131 prehnite -0.18 -4.01 -3.83 -0.225 0.14201E+05 132 prehnite-Fe 3.96 0.06 -3.90 -0.235 0.14456E+05 135 px-Mg-tschermaks -2.16 -4.88 -2.72 -0.194 0.10089E+05 136 px-Ca-tschermaks -1.62 -4.62 -3.00 -0.214 0.11103E+05 138 pyrrhotite -8.69 -9.51 -0.82 -0.272 0.30242E+04 139 pyrrhotiteFe0.875 -9.57 -9.96 -0.40 -0.146 0.14699E+04 140 pyrophyllite -11.26 -12.72 -1.46 -0.091 0.54181E+04 143 riebeckite 6.71 3.05 -3.66 -0.101 0.13561E+05 144 ringwoodite-Fe 4.34 1.88 -2.46 -0.351 0.91120E+04 146 rhodochrosite -5.65 -8.82 -3.16 -1.054 0.11723E+05 147 rhodonite 2.88 2.18 -0.70 -0.141 0.26056E+04 148 sanidine -3.49 -4.04 -0.56 -0.043 0.20676E+04 150 siderite -7.49 -10.80 -3.31 -1.104 0.12274E+05 151 sillimanite -7.55 -8.23 -0.68 -0.068 0.25028E+04 153 spinel -1.21 -3.38 -2.17 -0.145 0.80390E+04 161 stishovite 1.56 -1.50 -3.05 -1.018 0.11318E+05 162 sudoite-Fe -9.65 -14.58 -4.93 -0.159 0.18275E+05 163 sudoite -7.22 -11.26 -4.04 -0.130 0.14988E+05 164 sulfur -11.68 -13.17 -1.49 -0.458 0.55191E+04 165 sylvite -1.74 -4.37 -2.64 -1.319 0.97800E+04 166 talc 6.25 4.06 -2.20 -0.129 0.81425E+04 167 talc-Fe 3.10 -0.92 -4.03 -0.237 0.14928E+05 168 talc-tschermaks -1.61 -4.53 -2.92 -0.172 0.10809E+05 170 tephroite 7.52 5.85 -1.67 -0.238 0.61842E+04 173 topaz-H -5.52 -8.23 -2.71 -0.247 0.10052E+05 176 troilite-low -8.61 -9.51 -0.90 -0.300 0.33419E+04 180 wadsleyite-Fe 4.20 1.88 -2.32 -0.332 0.86025E+04 181 wadsleyite-Mg 9.90 5.20 -4.70 -0.671 0.17415E+05 182 wairakite -7.12 -9.11 -1.99 -0.117 0.73878E+04 183 walstromite 4.89 2.11 -2.78 -0.557 0.10318E+05 184 wollastonite 4.45 2.11 -2.34 -0.468 0.86750E+04 185 pseudo-wollastonite 4.58 2.11 -2.47 -0.493 0.91461E+04 186 zoisite -4.16 -7.37 -3.21 -0.146 0.11905E+05 189 beidellite-Ca -10.88 -12.74 -1.86 -0.115 0.68907E+04 190 beidellite-H -10.97 -13.34 -2.37 -0.151 0.87760E+04 191 beidellite-K -9.94 -12.08 -2.14 -0.131 0.79436E+04 192 beidellite-Mg -11.09 -12.78 -1.69 -0.105 0.62801E+04 193 beidellite-Na -9.88 -11.92 -2.05 -0.125 0.75921E+04 194 bornite -57.61 -57.75 -0.14 -0.010 0.51452E+03 196 chalcocite -15.26 -16.66 -1.40 -0.350 0.51935E+04 197 covellite -13.62 -14.92 -1.29 -0.493 0.48004E+04 199 montmorillonite-Ca -8.34 -9.91 -1.57 -0.097 0.58211E+04 200 montmorillonite-K -7.66 -9.25 -1.59 -0.097 0.58790E+04 201 montmorillonite-Mg -8.52 -9.95 -1.43 -0.089 0.53180E+04 202 montmorillonite-Na -7.34 -9.09 -1.75 -0.107 0.64917E+04 203 nontronite-Ca -2.83 -4.61 -1.78 -0.115 0.65944E+04 204 nontronite-H -2.92 -5.20 -2.28 -0.153 0.84522E+04 205 nontronite-K -1.88 -3.94 -2.06 -0.132 0.76398E+04 206 nontronite-Mg -3.01 -4.65 -1.64 -0.106 0.60834E+04 207 nontronite-Na -1.82 -3.79 -1.97 -0.126 0.72978E+04 212 gypsum -13.20 -15.49 -2.29 -0.573 0.84931E+04 229 alabandite -6.43 -7.52 -1.10 -0.365 0.40597E+04 231 anglesite -15.92 -18.22 -2.30 -1.148 0.85120E+04 235 boehmite -2.17 -3.37 -1.19 -0.199 0.44220E+04 239 copper,native 1.67 -1.75 -3.42 -1.188 0.12660E+05 241 ferrous-oxide 2.79 1.69 -1.10 -0.274 0.40689E+04 243 silver,native 0.31 -4.54 -4.85 -1.686 0.17968E+05 245 litharge 5.61 0.87 -4.74 -1.185 0.17571E+05 253 wurtzite -10.23 -11.07 -0.83 -0.278 0.30911E+04 254 zincite 2.83 0.13 -2.70 -0.675 0.10007E+05 255 an20ab80 -3.95 -4.09 -0.13 -0.010 0.48750E+03 256 an25ab75 -4.06 -4.21 -0.15 -0.011 0.54943E+03 257 an30ab70 -4.17 -4.34 -0.17 -0.013 0.63350E+03 258 tr.625ac.25prg.125 12.91 9.14 -3.77 -0.101 0.13968E+05 Calculations done for 537.0000 Deg. C; 812.0000 bar Temperature changed by -1.000 degrees to 536.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 72 Loop limit = 500 Temperature = 536.00 C Pressure = 803.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5516E+02 kg liquid = 0.9937E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9971 Stoichiometric ionic strength = .3267420E+01 Osmotic coef. = 0.0000 True ionic strength = .1781601E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54273E-05 -5.2654 0.54022E-06 -6.2674 0.99536E-01 -1.0020 2 H2O 0.99709E+00 -0.0013 0.99709E+00 -0.0013 3 Cl- 0.14834E+00 -0.8287 0.11265E-01 -1.9483 0.75939E-01 -1.1195 4 SO4-- 0.22069E-02 -2.6562 0.25040E-06 -6.6014 0.11346E-03 -3.9452 5 HCO3- 0.64803E-05 -5.1884 0.54898E-06 -6.2604 0.84715E-01 -1.0720 6 HS- 0.14385E-03 -3.8421 0.11056E-04 -4.9564 0.76861E-01 -1.1143 7 H4SiO4 0.31070E-01 -1.5077 0.31070E-01 -1.5077 0.10000E+01 0.0000 8 Al+++ 0.93085E-13 -13.0311 0.79846E-22 -22.0977 0.85778E-09 -9.0666 9 Ca++ 0.15239E-04 -4.8170 0.12297E-08 -8.9102 0.80695E-04 -4.0932 10 Mg++ 0.10826E-04 -4.9655 0.65273E-09 -9.1853 0.60291E-04 -4.2197 11 Fe++ 0.23204E-06 -6.6344 0.15058E-10 -10.8222 0.64893E-04 -4.1878 12 K+ 0.40261E-01 -1.3951 0.35287E-02 -2.4524 0.87644E-01 -1.0573 13 Na+ 0.13410E+00 -0.8726 0.10325E-01 -1.9861 0.77000E-01 -1.1135 14 Mn++ 0.21546E-04 -4.6666 0.14756E-08 -8.8310 0.68486E-04 -4.1644 15 Zn++ 0.64198E-08 -8.1925 0.41660E-12 -12.3803 0.64893E-04 -4.1878 16 Cu+ 0.12931E-07 -7.8884 0.99180E-09 -9.0036 0.76699E-01 -1.1152 17 Pb++ 0.23269E-07 -7.6332 0.22278E-11 -11.6521 0.95741E-04 -4.0189 18 Ag+ 0.16744E-10 -10.7761 0.14333E-11 -11.8437 0.85599E-01 -1.0675 19 Ba++ 0.44406E-06 -6.3526 0.47395E-10 -10.3243 0.10673E-03 -3.9717 20 HPO4-- 0.10154E-07 -7.9934 0.11609E-11 -11.9352 0.11433E-03 -3.9419 21 HSiO3- 0.15443E-05 -5.8113 0.11727E-06 -6.9308 0.75939E-01 -1.1195 22 Ca(HSiO3)+ 0.47615E-08 -8.3223 0.42286E-09 -9.3738 0.88808E-01 -1.0515 23 Mg(HSiO3)+ 0.98979E-09 -9.0045 0.87902E-10 -10.0560 0.88808E-01 -1.0515 24 NaHSiO3,aq 0.17966E-05 -5.7455 0.17966E-05 -5.7455 0.10000E+01 0.0000 28 AgCl,aq 0.59239E-08 -8.2274 0.59239E-08 -8.2274 0.10000E+01 0.0000 29 AgCl2- 0.30036E-06 -6.5224 0.22809E-07 -7.6419 0.75939E-01 -1.1195 30 AgCl3-2 0.33698E-06 -6.4724 0.34033E-10 -10.4681 0.10099E-03 -3.9957 31 AgCl4-3 0.81125E-05 -5.0908 0.58530E-14 -14.2326 0.72147E-09 -9.1418 34 Ag(HS),aq 0.13943E-09 -9.8556 0.13943E-09 -9.8556 0.10000E+01 0.0000 35 Ag(HS)2- 0.41502E-09 -9.3819 0.31516E-10 -10.5015 0.75939E-01 -1.1195 36 AlO+ 0.43032E-10 -10.3662 0.38216E-11 -11.4178 0.88808E-01 -1.0515 38 HAlO2,aq 0.54771E-08 -8.2614 0.54771E-08 -8.2614 0.10000E+01 0.0000 39 AlO2- 0.16369E-04 -4.7860 0.10291E-05 -5.9876 0.62865E-01 -1.2016 41 Ba(HCO3)+ 0.12161E-06 -6.9150 0.11467E-07 -7.9405 0.94297E-01 -1.0255 42 BaCl+ 0.60944E-05 -5.2151 0.54123E-06 -6.2666 0.88808E-01 -1.0515 43 CH4,aq 0.11485E-08 -8.9399 0.13267E-08 -8.8772 0.11552E+01 0.0627 48 CO,aq 0.33500E-03 -3.4749 0.33500E-03 -3.4749 0.10000E+01 0.0000 49 CO2,aq 0.26727E+01 0.4270 0.30875E+01 0.4896 0.11552E+01 0.0627 50 CO3-2 0.24499E-09 -9.6108 0.24742E-13 -13.6066 0.10099E-03 -3.9957 52 Ca(HCO3)+ 0.55879E-07 -7.2528 0.49625E-08 -8.3043 0.88808E-01 -1.0515 53 CaCl+ 0.74738E-04 -4.1265 0.66374E-05 -5.1780 0.88808E-01 -1.0515 54 CaCl2,aq 0.56432E-04 -4.2485 0.56432E-04 -4.2485 0.10000E+01 0.0000 55 CaOH+ 0.13389E-06 -6.8732 0.11891E-07 -7.9248 0.88808E-01 -1.0515 56 CaSO4,aq 0.23176E-06 -6.6350 0.23176E-06 -6.6350 0.10000E+01 0.0000 57 HCl,aq 0.91185E-02 -2.0401 0.91185E-02 -2.0401 0.10000E+01 0.0000 66 CuCl,aq 0.17593E-04 -4.7547 0.17593E-04 -4.7547 0.10000E+01 0.0000 67 CuCl2- 0.80166E-04 -4.0960 0.60877E-05 -5.2155 0.75939E-01 -1.1195 68 CuCl3-2 0.50564E-05 -5.2962 0.51066E-09 -9.2919 0.10099E-03 -3.9957 74 FeCl+ 0.32867E-06 -6.4832 0.29189E-07 -7.5348 0.88808E-01 -1.0515 75 FeCl2,aq 0.13888E-02 -2.8573 0.13888E-02 -2.8573 0.10000E+01 0.0000 77 FeO,aq 0.36978E-07 -7.4321 0.36978E-07 -7.4321 0.10000E+01 0.0000 78 FeOH+ 0.26371E-07 -7.5789 0.23420E-08 -8.6304 0.88808E-01 -1.0515 79 HFeO2- 0.60379E-08 -8.2191 0.45851E-09 -9.3387 0.75939E-01 -1.1195 82 FeO2- 0.30679E-08 -8.5132 0.23298E-09 -9.6327 0.75939E-01 -1.1195 83 HFeO2,aq 0.28307E-09 -9.5481 0.28307E-09 -9.5481 0.10000E+01 0.0000 84 H2,aq 0.41020E-02 -2.3870 0.47386E-02 -2.3244 0.11552E+01 0.0627 85 KCl,aq 0.68068E-01 -1.1671 0.68068E-01 -1.1671 0.10000E+01 0.0000 86 KHSO4,aq 0.10773E-01 -1.9677 0.10773E-01 -1.9677 0.10000E+01 0.0000 87 KOH,aq 0.12760E-05 -5.8942 0.12760E-05 -5.8942 0.10000E+01 0.0000 88 KSO4- 0.64243E-02 -2.1922 0.48785E-03 -3.3117 0.75939E-01 -1.1195 90 Mg(HCO3)+ 0.81034E-08 -8.0913 0.71964E-09 -9.1429 0.88808E-01 -1.0515 91 MgCl+ 0.96452E-05 -5.0157 0.85657E-06 -6.0672 0.88808E-01 -1.0515 92 MgOH+ 0.32799E-06 -6.4841 0.29128E-07 -7.5357 0.88808E-01 -1.0515 94 MnO,aq 0.70099E-07 -7.1543 0.70099E-07 -7.1543 0.10000E+01 0.0000 95 MnOH+ 0.24691E-06 -6.6075 0.21928E-07 -7.6590 0.88808E-01 -1.0515 97 HMnO2- 0.37941E-10 -10.4209 0.28812E-11 -11.5404 0.75939E-01 -1.1195 100 MnCl+ 0.11347E-02 -2.9451 0.10077E-03 -3.9967 0.88808E-01 -1.0515 101 MnSO4,aq 0.24924E-06 -6.6034 0.24924E-06 -6.6034 0.10000E+01 0.0000 102 NaCl,aq 0.42404E+00 -0.3726 0.42404E+00 -0.3726 0.10000E+01 0.0000 103 NaOH,aq 0.16590E-05 -5.7801 0.16590E-05 -5.7801 0.10000E+01 0.0000 105 OH- 0.10527E-04 -4.9777 0.66181E-06 -6.1793 0.62865E-01 -1.2016 110 HPO3-2 0.31226E-10 -10.5055 0.31536E-14 -14.5012 0.10099E-03 -3.9957 111 H3PO3,aq 0.88309E-10 -10.0540 0.88309E-10 -10.0540 0.10000E+01 0.0000 112 H2PO3- 0.88194E-09 -9.0546 0.66973E-10 -10.1741 0.75939E-01 -1.1195 113 H3PO4,aq 0.16276E-05 -5.7885 0.16276E-05 -5.7885 0.10000E+01 0.0000 114 H2PO4- 0.12473E-05 -5.9040 0.10193E-06 -6.9917 0.81720E-01 -1.0877 116 H4P2O7,aq 0.26987E-09 -9.5688 0.26987E-09 -9.5688 0.10000E+01 0.0000 117 H3P2O7- 0.59147E-09 -9.2281 0.44916E-10 -10.3476 0.75939E-01 -1.1195 118 H2P2O7-2 0.50232E-06 -6.2990 0.50731E-10 -10.2947 0.10099E-03 -3.9957 119 HP2O7-3 0.23641E-05 -5.6263 0.17056E-14 -14.7681 0.72147E-09 -9.1418 120 P2O7-4 0.83717E-09 -9.0772 0.25580E-24 -24.5921 0.30556E-15 -15.5149 121 PbCl+ 0.10877E-05 -5.9635 0.96599E-07 -7.0150 0.88808E-01 -1.0515 122 PbCl2,aq 0.66615E-04 -4.1764 0.66615E-04 -4.1764 0.10000E+01 0.0000 123 PbCl3- 0.10822E-03 -3.9657 0.82179E-05 -5.0852 0.75939E-01 -1.1195 124 PbCl4-2 0.58590E-04 -4.2322 0.59171E-08 -8.2279 0.10099E-03 -3.9957 125 PbO,aq 0.57020E-08 -8.2440 0.57020E-08 -8.2440 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.86879E-04 -4.0611 0.86879E-04 -4.0611 0.10000E+01 0.0000 128 Pb(HS)3- 0.13962E-04 -4.8550 0.10603E-05 -5.9746 0.75939E-01 -1.1195 129 H2S,aq 0.10614E+01 0.0259 0.12261E+01 0.0885 0.11552E+01 0.0627 130 S2-2 0.61773E-07 -7.2092 0.62387E-11 -11.2049 0.10099E-03 -3.9957 131 S3-2 0.51911E-08 -8.2847 0.52427E-12 -12.2804 0.10099E-03 -3.9957 132 S3- 0.70284E-02 -2.1531 0.53373E-03 -3.2727 0.75939E-01 -1.1195 133 S4-2 0.38020E-09 -9.4200 0.38397E-13 -13.4157 0.10099E-03 -3.9957 134 S5-2 0.24790E-10 -10.6057 0.25036E-14 -14.6014 0.10099E-03 -3.9957 135 SO2,aq 0.29256E+00 -0.5338 0.29256E+00 -0.5338 0.10000E+01 0.0000 136 SO3-2 0.41771E-08 -8.3791 0.85103E-12 -12.0701 0.20374E-03 -3.6909 137 HSO3- 0.22302E-03 -3.6517 0.16936E-04 -4.7712 0.75939E-01 -1.1195 138 HSO4- 0.87987E-02 -2.0556 0.81539E-03 -3.0886 0.92672E-01 -1.0331 140 S2O3-2 0.33248E-05 -5.4782 0.33578E-09 -9.4739 0.10099E-03 -3.9957 141 HS2O3- 0.34932E-06 -6.4568 0.26527E-07 -7.5763 0.75939E-01 -1.1195 142 H2S2O3,aq 0.53465E-07 -7.2719 0.53465E-07 -7.2719 0.10000E+01 0.0000 150 S4O6-2 0.20924E-08 -8.6794 0.21131E-12 -12.6751 0.10099E-03 -3.9957 152 ZnCl+ 0.11856E-03 -3.9261 0.10529E-04 -4.9776 0.88808E-01 -1.0515 153 ZnCl2,aq 0.40983E-03 -3.3874 0.40983E-03 -3.3874 0.10000E+01 0.0000 154 ZnCl3- 0.26118E-04 -4.5831 0.19833E-05 -5.7026 0.75939E-01 -1.1195 155 ZnO,aq 0.20682E-07 -7.6844 0.20682E-07 -7.6844 0.10000E+01 0.0000 156 ZnOH+ 0.92851E-06 -6.0322 0.82459E-07 -7.0838 0.88808E-01 -1.0515 158 HZnO2- 0.22348E-09 -9.6508 0.16971E-10 -10.7703 0.75939E-01 -1.1195 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5427342E-05 0.4292538E+01 0.3545731E+04 0.0000 2 H2O 0.1000000E+01 0.5252921E+02 0.7755311E+06 0.0000 3 Cl- 0.1483396E+00 0.6556182E+00 0.1904850E+05 4.3192 4 SO4-- 0.2206922E-02 0.2510748E+00 0.1976560E+05 5.9335 5 HCO3- 0.6480313E-05 0.2673064E+01 0.1336652E+06 0.0070 6 HS- 0.1438495E-03 0.1152737E+01 0.3124263E+05 1.3110 7 H4SiO4 0.3106968E-01 0.3107303E-01 0.2447561E+04 -1.5077 8 Al+++ 0.9308547E-13 0.1637485E-04 0.3620764E+00 -3.2954 9 Ca++ 0.1523894E-04 0.1468359E-03 0.4822756E+01 3.6247 10 Mg++ 0.1082634E-04 0.2080861E-04 0.4145917E+00 3.3496 11 Fe++ 0.2320370E-06 0.1389473E-02 0.6359263E+02 1.7126 12 K+ 0.4026119E-01 0.1255279E+00 0.4022500E+04 3.8150 13 Na+ 0.1340965E+00 0.5581387E+00 0.1051560E+05 4.2813 14 Mn++ 0.2154638E-04 0.1156836E-02 0.5208366E+02 3.7038 15 Zn++ 0.6419755E-08 0.5554662E-03 0.2975726E+02 0.1546 16 Cu+ 0.1293102E-07 0.1028289E-03 0.5354507E+01 -2.7361 17 Pb++ 0.2326898E-07 0.3353795E-03 0.5694587E+02 0.8827 18 Ag+ 0.1674405E-10 0.8756370E-05 0.7740725E+00 -5.5762 19 Ba++ 0.4440564E-06 0.6660047E-05 0.7496028E+00 2.2106 20 HPO4-- 0.1015414E-07 0.8622177E-05 0.6781879E+00 0.5997 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265318E+01 -.2955474E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5219610E+02 -.2313175E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2494827E+00 0.2240104E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1145427E+01 0.1471715E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3087598E-01 0.1127183E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1627101E-04 0.6782685E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1459048E-03 0.3820051E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1380662E-02 0.7386092E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247319E+00 0.6782685E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.5519438E-03 0.1747391E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1021769E-03 0.2974329E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3332527E-03 0.6919898E-05 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.6617813E-05 0.4875464E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.6099E-18 Mass of aqueous solution: 0.121250E+04 g Temperature = 536.00 C Pressure = 803.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3820E-03 -3.418 0.5201E-01 -1.284 0.6518 0.1755E-01 microcline 0.6783E-03 -3.169 0.1888 -0.724 2.366 0.7375E-01 pyrite 0.7089E-02 -2.149 0.8505 -0.070 10.66 0.1697 quartz 0.1107 -0.956 6.650 0.823 83.34 2.511 barite 0.4875E-04 -4.312 0.1138E-01 -1.944 0.1426 0.2540E-02 chalcopyrite 0.2974E-03 -3.527 0.5458E-01 -1.263 0.6840 0.1274E-01 galena 0.6920E-05 -5.160 0.1656E-02 -2.781 0.2075E-01 0.2179E-03 sphalerite 0.1747E-02 -2.758 0.1702 -0.769 2.134 0.4164E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.979022 g Volume = 2.829403 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.51 -15.51 0.00 0.000 0.00000E+00 112 microcline -4.00 -4.00 0.00 0.000 -0.98655E-11 137 pyrite -22.71 -22.71 0.00 0.000 0.00000E+00 141 quartz -1.51 -1.51 0.00 0.000 0.00000E+00 234 barite -16.93 -16.93 0.00 0.000 0.00000E+00 237 chalcopyrite -24.46 -24.46 0.00 0.000 0.00000E+00 242 galena -10.34 -10.34 -0.00 -0.000 0.65770E-11 252 sphalerite -11.07 -11.07 0.00 0.000 -0.65770E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.24 -0.00 -0.24 -0.245 0.90575E+03 2.660 2 CO2,gas -10.69 -12.53 -1.84 -0.612 0.67985E+04 1.069 3 CH4,gas 6.71 -4.62 -11.33 -2.832 0.41943E+05 -8.424 4 H2,gas 6.11 1.98 -4.13 -2.361 0.15299E+05 -1.227 5 H2S,gas -8.89 -11.22 -2.33 -1.165 0.86271E+04 0.575 6 CO,gas -4.23 -10.55 -6.32 -1.945 0.23406E+05 -3.417 7 SO3,gas -8.16 -19.13 -10.97 -2.743 0.40618E+05 -8.066 8 O2,gas 17.37 -3.96 -21.33 -14.219 0.78971E+05 -18.424 9 HCl,gas -6.46 -8.22 -1.76 -0.878 0.65032E+04 -1.756 10 acmite 3.71 1.99 -1.72 -0.178 0.63611E+04 12 akimotoite 6.81 1.84 -4.97 -0.994 0.18408E+05 13 akimotoite-Fe 4.57 0.21 -4.36 -0.872 0.16140E+05 14 albite-high -3.33 -3.53 -0.20 -0.015 0.73756E+03 15 albite -3.36 -3.53 -0.18 -0.014 0.65290E+03 16 almandine -3.36 -5.98 -2.61 -0.131 0.96725E+04 17 pyrope 3.78 -1.07 -4.85 -0.242 0.17947E+05 18 analcite -0.98 -2.03 -1.04 -0.116 0.38641E+04 19 andalusite -7.46 -8.10 -0.64 -0.064 0.23681E+04 24 anorthite -4.92 -5.98 -1.06 -0.081 0.39208E+04 26 anthophyllite-Fe 4.28 -0.06 -4.34 -0.117 0.16067E+05 27 apatite-OH -54.59 -55.29 -0.70 -0.054 0.25890E+04 28 apatite-OH-zs -52.32 -55.29 -2.97 -0.228 0.10998E+05 29 apatite-Cl-zs -59.45 -63.50 -4.06 -0.338 0.15016E+05 30 aragonite -4.93 -8.90 -3.98 -1.325 0.14720E+05 31 brucite 6.25 3.35 -2.90 -0.581 0.10752E+05 32 calcite -5.04 -8.90 -3.86 -1.287 0.14298E+05 33 carnegieite-low 1.35 -0.52 -1.87 -0.267 0.69280E+04 34 carnegieite-high 1.45 -0.52 -1.97 -0.282 0.73078E+04 35 carpholite-Mg -3.57 -6.26 -2.69 -0.179 0.99499E+04 36 carpholite-Fe -5.05 -7.90 -2.85 -0.190 0.10555E+05 37 celadonite 0.58 -2.16 -2.74 -0.161 0.10132E+05 38 celadonite-Fe -0.93 -3.79 -2.86 -0.168 0.10600E+05 39 chrysotile 11.24 7.03 -4.20 -0.350 0.15568E+05 41 clinochlore 9.97 5.63 -4.34 -0.136 0.16074E+05 42 daphnite 2.30 -2.56 -4.86 -0.152 0.17978E+05 45 chloritoid-Mg -2.72 -4.75 -2.03 -0.135 0.75194E+04 46 chloritoid-Fe -4.83 -6.39 -1.56 -0.104 0.57579E+04 47 chloritoid-Mn -2.72 -4.40 -1.68 -0.112 0.62312E+04 49 coesite -1.20 -1.51 -0.30 -0.102 0.11279E+04 50 cordierite-H -11.62 -14.02 -2.40 -0.086 0.88933E+04 51 cordierite-Fe -14.49 -17.29 -2.81 -0.097 0.10388E+05 52 cordierite-Mn -10.19 -13.31 -3.12 -0.108 0.11562E+05 53 corundum -5.77 -6.59 -0.83 -0.075 0.30575E+04 55 cristobalite -1.45 -1.51 -0.05 -0.017 0.18566E+03 58 cymrite-K -1.59 -4.00 -2.41 -0.201 0.89360E+04 60 diaspore -2.42 -3.30 -0.88 -0.147 0.32563E+04 62 diopside 6.17 3.96 -2.21 -0.221 0.81906E+04 63 hedenbergite 4.63 2.32 -2.30 -0.230 0.85334E+04 65 eastonite 0.28 -2.39 -2.67 -0.103 0.98787E+04 66 enstatite 5.84 3.69 -2.15 -0.215 0.79609E+04 67 clinoenstatite-HiP 6.35 3.69 -2.67 -0.267 0.98742E+04 68 clinoenstatite 5.81 3.69 -2.13 -0.213 0.78799E+04 69 protoenstatite 5.98 3.69 -2.29 -0.229 0.84851E+04 70 epidote -0.20 -3.14 -2.94 -0.142 0.10881E+05 71 clinozoisite -3.88 -7.16 -3.28 -0.149 0.12136E+05 72 epidote-Fe 5.21 0.88 -4.33 -0.225 0.16032E+05 73 fayalite 3.37 1.92 -1.45 -0.208 0.53788E+04 74 ferrosilite 1.97 0.41 -1.56 -0.156 0.57675E+04 75 forsterite 7.66 5.19 -2.47 -0.353 0.91537E+04 78 gibbsite -0.78 -3.30 -2.52 -0.360 0.93221E+04 79 glaucophane 4.92 -0.03 -4.95 -0.134 0.18336E+05 81 goethite 1.73 0.72 -1.01 -0.217 0.37240E+04 83 greenalite 5.95 2.12 -3.83 -0.319 0.14172E+05 84 grunerite 4.87 -0.06 -4.94 -0.133 0.18279E+05 85 halite -1.85 -3.93 -2.08 -1.041 0.77105E+04 86 hematite 1.90 1.44 -0.46 -0.056 0.17027E+04 87 heulandite -10.06 -13.51 -3.46 -0.157 0.12800E+05 88 hercynite -3.35 -4.88 -1.53 -0.102 0.56732E+04 91 jadeite -0.30 -2.03 -1.73 -0.173 0.63892E+04 93 kalsilite 0.71 -0.99 -1.70 -0.243 0.62969E+04 94 kaolinite -6.86 -9.61 -2.75 -0.250 0.10185E+05 95 kyanite -7.29 -8.10 -0.81 -0.081 0.29870E+04 97 laumontite -5.11 -9.00 -3.89 -0.259 0.14403E+05 98 lawsonite -2.20 -5.98 -3.78 -0.252 0.14014E+05 99 leucite -1.46 -2.49 -1.03 -0.103 0.38182E+04 101 lizardite 11.38 7.03 -4.35 -0.362 0.16102E+05 102 magnesite -5.51 -9.18 -3.67 -1.224 0.13598E+05 103 magnetite 3.78 3.16 -0.62 -0.051 0.23050E+04 104 minnesotaite 1.69 -0.89 -2.58 -0.152 0.95389E+04 105 minnesotaite-Mg 8.10 4.02 -4.08 -0.240 0.15109E+05 106 magnesioferrite 7.05 4.79 -2.25 -0.184 0.83398E+04 108 manganosite 6.09 3.70 -2.38 -0.596 0.88245E+04 109 margarite -10.29 -12.58 -2.28 -0.091 0.84555E+04 113 monticellite 9.91 5.47 -4.45 -0.635 0.16461E+05 115 mullite-Si -6.66 -8.10 -1.44 -0.144 0.53185E+04 116 muscovite -9.68 -10.59 -0.91 -0.054 0.33869E+04 117 paragonite -8.98 -10.13 -1.15 -0.068 0.42641E+04 118 nepheline 1.04 -0.52 -1.56 -0.222 0.57656E+04 119 osumilite(2) -8.52 -12.59 -4.07 -0.085 0.15084E+05 120 osumilite-Fe -21.03 -24.30 -3.27 -0.068 0.12100E+05 122 periclase 6.51 3.35 -3.16 -0.789 0.11691E+05 123 periclase-Fe 3.77 1.71 -2.06 -0.514 0.76105E+04 124 perovskite-Al -3.97 -6.59 -2.63 -0.239 0.97264E+04 129 phlogopite-Na 9.25 6.51 -2.74 -0.152 0.10143E+05 131 prehnite -0.02 -3.86 -3.85 -0.226 0.14250E+05 132 prehnite-Fe 4.07 0.16 -3.92 -0.236 0.14501E+05 135 px-Mg-tschermaks -1.99 -4.75 -2.77 -0.198 0.10243E+05 136 px-Ca-tschermaks -1.47 -4.48 -3.01 -0.215 0.11149E+05 138 pyrrhotite -8.69 -9.51 -0.82 -0.274 0.30380E+04 139 pyrrhotiteFe0.875 -9.57 -9.97 -0.40 -0.147 0.14812E+04 140 pyrophyllite -11.15 -12.62 -1.47 -0.092 0.54372E+04 143 riebeckite 6.77 3.10 -3.67 -0.101 0.13594E+05 144 ringwoodite-Fe 4.39 1.92 -2.47 -0.353 0.91411E+04 146 rhodochrosite -5.66 -8.82 -3.16 -1.055 0.11715E+05 147 rhodonite 2.90 2.20 -0.70 -0.140 0.25901E+04 148 sanidine -3.44 -4.00 -0.56 -0.043 0.20668E+04 150 siderite -7.49 -10.82 -3.32 -1.107 0.12298E+05 151 sillimanite -7.42 -8.10 -0.68 -0.068 0.25340E+04 153 spinel -1.03 -3.25 -2.21 -0.147 0.81912E+04 161 stishovite 1.55 -1.51 -3.06 -1.019 0.11315E+05 162 sudoite-Fe -9.33 -14.29 -4.96 -0.160 0.18352E+05 163 sudoite -6.89 -11.01 -4.12 -0.133 0.15272E+05 164 sulfur -11.71 -13.20 -1.49 -0.458 0.55159E+04 165 sylvite -1.76 -4.40 -2.64 -1.319 0.97705E+04 166 talc 6.32 4.02 -2.29 -0.135 0.84894E+04 167 talc-Fe 3.15 -0.89 -4.04 -0.238 0.14962E+05 168 talc-tschermaks -1.43 -4.41 -2.99 -0.176 0.11069E+05 170 tephroite 7.56 5.90 -1.66 -0.237 0.61522E+04 173 topaz-H -5.38 -8.10 -2.72 -0.247 0.10070E+05 176 troilite-low -8.61 -9.51 -0.91 -0.302 0.33537E+04 180 wadsleyite-Fe 4.25 1.92 -2.33 -0.333 0.86339E+04 181 wadsleyite-Mg 9.96 5.19 -4.77 -0.681 0.17656E+05 182 wairakite -6.99 -8.99 -2.00 -0.118 0.74222E+04 183 walstromite 4.91 2.12 -2.79 -0.558 0.10332E+05 184 wollastonite 4.47 2.12 -2.35 -0.469 0.86893E+04 185 pseudo-wollastonite 4.59 2.12 -2.47 -0.495 0.91613E+04 186 zoisite -3.93 -7.16 -3.23 -0.147 0.11975E+05 189 beidellite-Ca -10.74 -12.61 -1.87 -0.116 0.69173E+04 190 beidellite-H -10.83 -13.21 -2.38 -0.152 0.87997E+04 191 beidellite-K -9.80 -11.95 -2.15 -0.132 0.79637E+04 192 beidellite-Mg -10.95 -12.66 -1.71 -0.106 0.63261E+04 193 beidellite-Na -9.74 -11.80 -2.06 -0.126 0.76128E+04 194 bornite -57.72 -57.85 -0.13 -0.010 0.48967E+03 196 chalcocite -15.30 -16.70 -1.40 -0.350 0.51773E+04 197 covellite -13.66 -14.95 -1.29 -0.492 0.47864E+04 199 montmorillonite-Ca -8.24 -9.83 -1.59 -0.098 0.58771E+04 200 montmorillonite-K -7.56 -9.16 -1.60 -0.098 0.59316E+04 201 montmorillonite-Mg -8.41 -9.87 -1.46 -0.090 0.53918E+04 202 montmorillonite-Na -7.24 -9.01 -1.77 -0.108 0.65399E+04 203 nontronite-Ca -2.78 -4.57 -1.79 -0.116 0.66125E+04 204 nontronite-H -2.88 -5.17 -2.29 -0.153 0.84673E+04 205 nontronite-K -1.84 -3.91 -2.07 -0.133 0.76514E+04 206 nontronite-Mg -2.96 -4.62 -1.65 -0.107 0.61199E+04 207 nontronite-Na -1.78 -3.76 -1.97 -0.127 0.73100E+04 212 gypsum -13.22 -15.51 -2.29 -0.573 0.84861E+04 229 alabandite -6.43 -7.52 -1.09 -0.364 0.40433E+04 231 anglesite -15.96 -18.25 -2.30 -1.148 0.85026E+04 235 boehmite -2.10 -3.30 -1.20 -0.200 0.44327E+04 239 copper,native 1.67 -1.75 -3.42 -1.188 0.12649E+05 241 ferrous-oxide 2.82 1.71 -1.10 -0.276 0.40870E+04 243 silver,native 0.31 -4.59 -4.89 -1.702 0.18118E+05 245 litharge 5.63 0.88 -4.75 -1.187 0.17573E+05 253 wurtzite -10.23 -11.07 -0.84 -0.278 0.30917E+04 254 zincite 2.86 0.15 -2.70 -0.676 0.10009E+05 255 an20ab80 -3.89 -4.02 -0.14 -0.010 0.50159E+03 256 an25ab75 -3.99 -4.14 -0.15 -0.012 0.56605E+03 257 an30ab70 -4.09 -4.27 -0.18 -0.014 0.65267E+03 258 tr.625ac.25prg.125 13.06 9.16 -3.90 -0.105 0.14456E+05 Calculations done for 536.0000 Deg. C; 803.0000 bar Temperature changed by -1.000 degrees to 535.000 degrees C. Solids and gases carried ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Isoenthalpic cooling and depressurization of Butte, MT magmatic fluid, using T-P curve option. CHIMRUN demo-5 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 74 Loop limit = 500 Temperature = 535.00 C Pressure = 795.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5516E+02 kg liquid = 0.9937E+00 Moles total = 0.5196E+02 kg total = 0.9362E+00 Activity = 0.9971 Stoichiometric ionic strength = .3267117E+01 Osmotic coef. = 0.0000 True ionic strength = .1779371E+00 Chg. balance for total moles = 0.2531E-05 Max. difference allowed = 0.6515E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.53839E-05 -5.2689 0.52527E-06 -6.2796 0.97562E-01 -1.0107 2 H2O 0.99709E+00 -0.0013 0.99709E+00 -0.0013 3 Cl- 0.14778E+00 -0.8304 0.10969E-01 -1.9598 0.74223E-01 -1.1295 4 SO4-- 0.23476E-02 -2.6294 0.24529E-06 -6.6103 0.10449E-03 -3.9809 5 HCO3- 0.63476E-05 -5.1974 0.52594E-06 -6.2791 0.82856E-01 -1.0817 6 HS- 0.14420E-03 -3.8410 0.10834E-04 -4.9652 0.75129E-01 -1.1242 7 H4SiO4 0.30526E-01 -1.5153 0.30526E-01 -1.5153 0.10000E+01 0.0000 8 Al+++ 0.11915E-12 -12.9239 0.84501E-22 -22.0731 0.70920E-09 -9.1492 9 Ca++ 0.16109E-04 -4.7929 0.11939E-08 -8.9230 0.74114E-04 -4.1301 10 Mg++ 0.11178E-04 -4.9517 0.61777E-09 -9.2092 0.55269E-04 -4.2575 11 Fe++ 0.24930E-06 -6.6033 0.14837E-10 -10.8286 0.59516E-04 -4.2254 12 K+ 0.40150E-01 -1.3963 0.34422E-02 -2.4632 0.85734E-01 -1.0668 13 Na+ 0.13384E+00 -0.8734 0.10073E-01 -1.9969 0.75259E-01 -1.1234 14 Mn++ 0.23554E-04 -4.6279 0.14800E-08 -8.8297 0.62833E-04 -4.2018 15 Zn++ 0.69262E-08 -8.1595 0.41222E-12 -12.3849 0.59516E-04 -4.2254 16 Cu+ 0.12730E-07 -7.8952 0.95427E-09 -9.0203 0.74964E-01 -1.1251 17 Pb++ 0.24226E-07 -7.6157 0.21328E-11 -11.6710 0.88036E-04 -4.0553 18 Ag+ 0.15227E-10 -10.8174 0.12748E-11 -11.8946 0.83720E-01 -1.0772 19 Ba++ 0.45873E-06 -6.3384 0.45056E-10 -10.3462 0.98219E-04 -4.0078 20 HPO4-- 0.10338E-07 -7.9856 0.10885E-11 -11.9632 0.10529E-03 -3.9776 21 HSiO3- 0.15435E-05 -5.8115 0.11456E-06 -6.9410 0.74223E-01 -1.1295 22 Ca(HSiO3)+ 0.47166E-08 -8.3264 0.40978E-09 -9.3875 0.86880E-01 -1.0611 23 Mg(HSiO3)+ 0.96444E-09 -9.0157 0.83790E-10 -10.0768 0.86880E-01 -1.0611 24 NaHSiO3,aq 0.18064E-05 -5.7432 0.18064E-05 -5.7432 0.10000E+01 0.0000 28 AgCl,aq 0.54267E-08 -8.2655 0.54267E-08 -8.2655 0.10000E+01 0.0000 29 AgCl2- 0.27314E-06 -6.5636 0.20273E-07 -7.6931 0.74223E-01 -1.1295 30 AgCl3-2 0.31268E-06 -6.5049 0.29058E-10 -10.5367 0.92931E-04 -4.0318 31 AgCl4-3 0.81645E-05 -5.0881 0.48695E-14 -14.3125 0.59642E-09 -9.2244 34 Ag(HS),aq 0.13014E-09 -9.8856 0.13014E-09 -9.8856 0.10000E+01 0.0000 35 Ag(HS)2- 0.38105E-09 -9.4190 0.28283E-10 -10.5485 0.74223E-01 -1.1295 36 AlO+ 0.44949E-10 -10.3473 0.39052E-11 -11.4084 0.86880E-01 -1.0611 38 HAlO2,aq 0.55093E-08 -8.2589 0.55093E-08 -8.2589 0.10000E+01 0.0000 39 AlO2- 0.16380E-04 -4.7857 0.10054E-05 -5.9976 0.61384E-01 -1.2119 41 Ba(HCO3)+ 0.11740E-06 -6.9303 0.10835E-07 -7.9652 0.92288E-01 -1.0349 42 BaCl+ 0.59180E-05 -5.2278 0.51416E-06 -6.2889 0.86880E-01 -1.0611 43 CH4,aq 0.11375E-08 -8.9441 0.13122E-08 -8.8820 0.11536E+01 0.0621 48 CO,aq 0.32920E-03 -3.4825 0.32920E-03 -3.4825 0.10000E+01 0.0000 49 CO2,aq 0.26727E+01 0.4269 0.30833E+01 0.4890 0.11536E+01 0.0621 50 CO3-2 0.25730E-09 -9.5896 0.23911E-13 -13.6214 0.92931E-04 -4.0318 52 Ca(HCO3)+ 0.53907E-07 -7.2684 0.46834E-08 -8.3294 0.86880E-01 -1.0611 53 CaCl+ 0.73558E-04 -4.1334 0.63907E-05 -5.1945 0.86880E-01 -1.0611 54 CaCl2,aq 0.55369E-04 -4.2567 0.55369E-04 -4.2567 0.10000E+01 0.0000 55 CaOH+ 0.13187E-06 -6.8799 0.11457E-07 -7.9409 0.86880E-01 -1.0611 56 CaSO4,aq 0.23519E-06 -6.6286 0.23519E-06 -6.6286 0.10000E+01 0.0000 57 HCl,aq 0.95053E-02 -2.0220 0.95053E-02 -2.0220 0.10000E+01 0.0000 66 CuCl,aq 0.17406E-04 -4.7593 0.17406E-04 -4.7593 0.10000E+01 0.0000 67 CuCl2- 0.79436E-04 -4.1000 0.58960E-05 -5.2294 0.74223E-01 -1.1295 68 CuCl3-2 0.51185E-05 -5.2909 0.47567E-09 -9.3227 0.92931E-04 -4.0318 74 FeCl+ 0.32836E-06 -6.4837 0.28528E-07 -7.5447 0.86880E-01 -1.0611 75 FeCl2,aq 0.13384E-02 -2.8734 0.13384E-02 -2.8734 0.10000E+01 0.0000 77 FeO,aq 0.36317E-07 -7.4399 0.36317E-07 -7.4399 0.10000E+01 0.0000 78 FeOH+ 0.26387E-07 -7.5786 0.22925E-08 -8.6397 0.86880E-01 -1.0611 79 HFeO2- 0.59971E-08 -8.2221 0.44512E-09 -9.3515 0.74223E-01 -1.1295 82 FeO2- 0.30100E-08 -8.5214 0.22341E-09 -9.6509 0.74223E-01 -1.1295 83 HFeO2,aq 0.28317E-09 -9.5480 0.28317E-09 -9.5480 0.10000E+01 0.0000 84 H2,aq 0.40866E-02 -2.3886 0.47144E-02 -2.3266 0.11536E+01 0.0621 85 KCl,aq 0.68119E-01 -1.1667 0.68119E-01 -1.1667 0.10000E+01 0.0000 86 KHSO4,aq 0.10750E-01 -1.9686 0.10750E-01 -1.9686 0.10000E+01 0.0000 87 KOH,aq 0.12813E-05 -5.8923 0.12813E-05 -5.8923 0.10000E+01 0.0000 88 KSO4- 0.65051E-02 -2.1867 0.48283E-03 -3.3162 0.74223E-01 -1.1295 90 Mg(HCO3)+ 0.75428E-08 -8.1225 0.65532E-09 -9.1835 0.86880E-01 -1.0611 91 MgCl+ 0.93063E-05 -5.0312 0.80853E-06 -6.0923 0.86880E-01 -1.0611 92 MgOH+ 0.31597E-06 -6.5004 0.27451E-07 -7.5614 0.86880E-01 -1.0611 94 MnO,aq 0.70465E-07 -7.1520 0.70465E-07 -7.1520 0.10000E+01 0.0000 95 MnOH+ 0.24980E-06 -6.6024 0.21702E-07 -7.6635 0.86880E-01 -1.0611 97 HMnO2- 0.38243E-10 -10.4174 0.28385E-11 -11.5469 0.74223E-01 -1.1295 100 MnCl+ 0.11327E-02 -2.9459 0.98408E-04 -4.0070 0.86880E-01 -1.0611 101 MnSO4,aq 0.25886E-06 -6.5869 0.25886E-06 -6.5869 0.10000E+01 0.0000 102 NaCl,aq 0.42429E+00 -0.3723 0.42429E+00 -0.3723 0.10000E+01 0.0000 103 NaOH,aq 0.16635E-05 -5.7790 0.16635E-05 -5.7790 0.10000E+01 0.0000 105 OH- 0.10615E-04 -4.9741 0.65160E-06 -6.1860 0.61384E-01 -1.2119 110 HPO3-2 0.30625E-10 -10.5139 0.28460E-14 -14.5458 0.92931E-04 -4.0318 111 H3PO3,aq 0.84326E-10 -10.0740 0.84326E-10 -10.0740 0.10000E+01 0.0000 112 H2PO3- 0.81839E-09 -9.0870 0.60744E-10 -10.2165 0.74223E-01 -1.1295 113 H3PO4,aq 0.15829E-05 -5.8006 0.15829E-05 -5.8006 0.10000E+01 0.0000 114 H2PO4- 0.11905E-05 -5.9243 0.95132E-07 -7.0217 0.79909E-01 -1.0974 116 H4P2O7,aq 0.25629E-09 -9.5913 0.25629E-09 -9.5913 0.10000E+01 0.0000 117 H3P2O7- 0.53724E-09 -9.2698 0.39875E-10 -10.3993 0.74223E-01 -1.1295 118 H2P2O7-2 0.46799E-06 -6.3298 0.43490E-10 -10.3616 0.92931E-04 -4.0318 119 HP2O7-3 0.24489E-05 -5.6110 0.14606E-14 -14.8355 0.59642E-09 -9.2244 120 P2O7-4 0.10399E-08 -8.9830 0.22868E-24 -24.6408 0.21990E-15 -15.6578 121 PbCl+ 0.10624E-05 -5.9737 0.92303E-07 -7.0348 0.86880E-01 -1.0611 122 PbCl2,aq 0.65422E-04 -4.1843 0.65422E-04 -4.1843 0.10000E+01 0.0000 123 PbCl3- 0.10662E-03 -3.9721 0.79139E-05 -5.1016 0.74223E-01 -1.1295 124 PbCl4-2 0.58756E-04 -4.2309 0.54602E-08 -8.2628 0.92931E-04 -4.0318 125 PbO,aq 0.56591E-08 -8.2473 0.56591E-08 -8.2473 0.10000E+01 0.0000 127 Pb(HS)2,aq 0.85528E-04 -4.0679 0.85528E-04 -4.0679 0.10000E+01 0.0000 128 Pb(HS)3- 0.13844E-04 -4.8587 0.10276E-05 -5.9882 0.74223E-01 -1.1295 129 H2S,aq 0.10617E+01 0.0260 0.12248E+01 0.0881 0.11536E+01 0.0621 130 S2-2 0.63963E-07 -7.1941 0.59441E-11 -11.2259 0.92931E-04 -4.0318 131 S3-2 0.53497E-08 -8.2717 0.49715E-12 -12.3035 0.92931E-04 -4.0318 132 S3- 0.68771E-02 -2.1626 0.51044E-03 -3.2921 0.74223E-01 -1.1295 133 S4-2 0.39048E-09 -9.4084 0.36287E-13 -13.4402 0.92931E-04 -4.0318 134 S5-2 0.25409E-10 -10.5950 0.23613E-14 -14.6269 0.92931E-04 -4.0318 135 SO2,aq 0.29241E+00 -0.5340 0.29241E+00 -0.5340 0.10000E+01 0.0000 136 SO3-2 0.44034E-08 -8.3562 0.82975E-12 -12.0811 0.18844E-03 -3.7248 137 HSO3- 0.22063E-03 -3.6563 0.16376E-04 -4.7858 0.74223E-01 -1.1295 138 HSO4- 0.87815E-02 -2.0564 0.79641E-03 -3.0989 0.90692E-01 -1.0424 140 S2O3-2 0.34814E-05 -5.4582 0.32353E-09 -9.4901 0.92931E-04 -4.0318 141 HS2O3- 0.34632E-06 -6.4605 0.25705E-07 -7.5900 0.74223E-01 -1.1295 142 H2S2O3,aq 0.54556E-07 -7.2632 0.54556E-07 -7.2632 0.10000E+01 0.0000 150 S4O6-2 0.21623E-08 -8.6651 0.20094E-12 -12.6969 0.92931E-04 -4.0318 152 ZnCl+ 0.11552E-03 -3.9373 0.10036E-04 -4.9984 0.86880E-01 -1.0611 153 ZnCl2,aq 0.40077E-03 -3.3971 0.40077E-03 -3.3971 0.10000E+01 0.0000 154 ZnCl3- 0.25148E-04 -4.5995 0.18666E-05 -5.7290 0.74223E-01 -1.1295 155 ZnO,aq 0.20444E-07 -7.6894 0.20444E-07 -7.6894 0.10000E+01 0.0000 156 ZnOH+ 0.91320E-06 -6.0394 0.79339E-07 -7.1005 0.86880E-01 -1.0611 158 HZnO2- 0.22345E-09 -9.6508 0.16585E-10 -10.7803 0.74223E-01 -1.1295 Charge balance for all species = 0.2547E-05 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5383933E-05 0.4292495E+01 0.3545855E+04 0.0000 2 H2O 0.1000000E+01 0.5252974E+02 0.7755741E+06 0.0000 3 Cl- 0.1477828E+00 0.6556107E+00 0.1904915E+05 4.3198 4 SO4-- 0.2347598E-02 0.2510580E+00 0.1976516E+05 5.9489 5 HCO3- 0.6347598E-05 0.2673033E+01 0.1336698E+06 0.0006 6 HS- 0.1442041E-03 0.1152618E+01 0.3124083E+05 1.3144 7 H4SiO4 0.3052638E-01 0.3052973E-01 0.2404875E+04 -1.5153 8 Al+++ 0.1191493E-12 0.1638525E-04 0.3623228E+00 -3.2343 9 Ca++ 0.1610924E-04 0.1454620E-03 0.4777844E+01 3.6362 10 Mg++ 0.1117756E-04 0.2080837E-04 0.4146057E+00 3.3501 11 Fe++ 0.2493005E-06 0.1339087E-02 0.6128938E+02 1.7306 12 K+ 0.4015015E-01 0.1255265E+00 0.4022636E+04 3.8165 13 Na+ 0.1338402E+00 0.5581324E+00 0.1051596E+05 4.2828 14 Mn++ 0.2355435E-04 0.1156823E-02 0.5208542E+02 3.7295 15 Zn++ 0.6926186E-08 0.5423812E-03 0.2905759E+02 0.1744 16 Cu+ 0.1272972E-07 0.1019727E-03 0.5310162E+01 -2.7407 17 Pb++ 0.2422634E-07 0.3312662E-03 0.5624998E+02 0.8882 18 Ag+ 0.1522660E-10 0.8756270E-05 0.7740987E+00 -5.6149 19 Ba++ 0.4587309E-06 0.6494128E-05 0.7309613E+00 2.2130 20 HPO4-- 0.1033797E-07 0.8622079E-05 0.6782108E+00 0.5961 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4262362E+01 0.4265323E+01 -.2960954E-02 0.0000000E+00 2 H2O 0.5196478E+02 0.5219723E+02 -.2324462E+00 0.0000000E+00 3 Cl- 0.6514607E+00 0.6514607E+00 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2517228E+00 0.2494687E+00 0.2254039E-02 0.0000000E+00 5 HCO3- 0.2656113E+01 0.2656113E+01 0.0000000E+00 0.0000000E+00 6 HS- 0.1160144E+01 0.1145322E+01 0.1482193E-01 0.0000000E+00 7 H4SiO4 0.1435943E+00 0.3033648E-01 0.1132578E+00 0.0000000E+00 8 Al+++ 0.6945395E-03 0.1628153E-04 0.6782580E-03 0.0000000E+00 9 Ca++ 0.5279099E-03 0.1445412E-03 0.3833687E-03 0.0000000E+00 10 Mg++ 0.2067665E-04 0.2067665E-04 0.0000000E+00 0.0000000E+00 11 Fe++ 0.8766754E-02 0.1330611E-02 0.7436143E-02 0.0000000E+00 12 K+ 0.1254101E+00 0.1247319E+00 0.6782580E-03 0.0000000E+00 13 Na+ 0.5545993E+00 0.5545993E+00 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1149500E-02 0.1149500E-02 0.0000000E+00 0.0000000E+00 15 Zn++ 0.2299335E-02 0.5389479E-03 0.1760387E-02 0.0000000E+00 16 Cu+ 0.3996097E-03 0.1013272E-03 0.2982825E-03 0.0000000E+00 17 Pb++ 0.3401726E-03 0.3291692E-03 0.1100341E-04 0.0000000E+00 18 Ag+ 0.8700842E-05 0.8700842E-05 0.0000000E+00 0.0000000E+00 19 Ba++ 0.5537245E-04 0.6453020E-05 0.4891943E-04 0.0000000E+00 20 HPO4-- 0.8567500E-05 0.8567500E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2114E-17 Mass of aqueous solution: 0.121246E+04 g Temperature = 535.00 C Pressure = 795.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) anhydrite 0.3834E-03 -3.416 0.5219E-01 -1.282 0.6508 0.1761E-01 microcline 0.6783E-03 -3.169 0.1888 -0.724 2.354 0.7374E-01 pyrite 0.7138E-02 -2.146 0.8564 -0.067 10.68 0.1709 quartz 0.1112 -0.954 6.682 0.825 83.32 2.524 barite 0.4892E-04 -4.311 0.1142E-01 -1.942 0.1424 0.2549E-02 chalcopyrite 0.2983E-03 -3.525 0.5473E-01 -1.262 0.6825 0.1278E-01 galena 0.1100E-04 -4.958 0.2633E-02 -2.580 0.3283E-01 0.3465E-03 sphalerite 0.1760E-02 -2.754 0.1715 -0.766 2.139 0.4195E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity anhydrite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 pyrite 0.1000E+01 0.1000E+01 1.0000 0.000 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 barite 0.1000E+01 0.1000E+01 1.0000 0.000 chalcopyrite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8.019961 g Volume = 2.843367 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 22 anhydrite -15.53 -15.53 -0.00 -0.000 0.65689E-11 112 microcline -3.96 -3.96 0.00 0.000 -0.82111E-11 137 pyrite -22.74 -22.74 0.00 0.000 0.00000E+00 141 quartz -1.51 -1.51 -0.00 -0.000 0.82111E-12 234 barite -16.96 -16.96 -0.00 -0.000 0.13138E-10 237 chalcopyrite -24.49 -24.49 -0.00 -0.000 0.13138E-10 242 galena -10.36 -10.36 0.00 0.000 0.00000E+00 252 sphalerite -11.07 -11.07 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 0.24 -0.00 -0.24 -0.244 0.90290E+03 2.656 2 CO2,gas -10.72 -12.56 -1.84 -0.614 0.68126E+04 1.058 3 CH4,gas 6.71 -4.64 -11.34 -2.835 0.41937E+05 -8.440 4 H2,gas 6.11 1.98 -4.13 -2.363 0.15290E+05 -1.234 5 H2S,gas -8.91 -11.24 -2.33 -1.166 0.86204E+04 0.569 6 CO,gas -4.24 -10.58 -6.33 -1.949 0.23422E+05 -3.434 7 SO3,gas -8.18 -19.17 -10.98 -2.746 0.40616E+05 -8.083 8 O2,gas 17.39 -3.96 -21.36 -14.238 0.78978E+05 -18.457 9 HCl,gas -6.47 -8.24 -1.77 -0.884 0.65352E+04 -1.767 10 acmite 3.72 2.00 -1.72 -0.179 0.63714E+04 13 akimotoite-Fe 4.59 0.22 -4.37 -0.874 0.16164E+05 14 albite-high -3.29 -3.49 -0.20 -0.016 0.74619E+03 15 albite -3.31 -3.49 -0.18 -0.014 0.65742E+03 16 almandine -3.18 -5.82 -2.64 -0.132 0.97723E+04 17 pyrope 3.98 -0.96 -4.95 -0.247 0.18292E+05 18 analcite -0.93 -1.98 -1.05 -0.116 0.38680E+04 19 andalusite -7.34 -7.99 -0.65 -0.065 0.23915E+04 24 anorthite -4.79 -5.86 -1.07 -0.083 0.39688E+04 26 anthophyllite-Fe 4.39 0.00 -4.39 -0.119 0.16220E+05 27 apatite-OH -54.61 -55.39 -0.78 -0.060 0.28724E+04 28 apatite-OH-zs -52.34 -55.39 -3.05 -0.235 0.11284E+05 29 apatite-Cl-zs -59.49 -63.63 -4.14 -0.345 0.15304E+05 30 aragonite -4.94 -8.92 -3.99 -1.329 0.14743E+05 31 brucite 6.28 3.35 -2.93 -0.587 0.10849E+05 32 calcite -5.05 -8.92 -3.87 -1.291 0.14321E+05 33 carnegieite-low 1.41 -0.47 -1.87 -0.268 0.69327E+04 34 carnegieite-high 1.51 -0.47 -1.98 -0.283 0.73153E+04 35 carpholite-Mg -3.43 -6.15 -2.72 -0.181 0.10057E+05 36 carpholite-Fe -4.91 -7.77 -2.86 -0.191 0.10582E+05 37 celadonite 0.64 -2.12 -2.77 -0.163 0.10225E+05 38 celadonite-Fe -0.87 -3.74 -2.87 -0.169 0.10616E+05 39 chrysotile 11.31 7.02 -4.29 -0.357 0.15860E+05 41 clinochlore 10.21 5.73 -4.48 -0.140 0.16575E+05 42 daphnite 2.52 -2.37 -4.89 -0.153 0.18078E+05 45 chloritoid-Mg -2.57 -4.64 -2.06 -0.138 0.76355E+04 46 chloritoid-Fe -4.69 -6.26 -1.57 -0.104 0.57896E+04 47 chloritoid-Mn -2.57 -4.26 -1.68 -0.112 0.62295E+04 49 coesite -1.21 -1.51 -0.31 -0.102 0.11286E+04 50 cordierite-H -11.34 -13.81 -2.48 -0.088 0.91543E+04 51 cordierite-Fe -14.21 -17.05 -2.84 -0.098 0.10486E+05 52 cordierite-Mn -9.92 -13.05 -3.13 -0.108 0.11590E+05 53 corundum -5.64 -6.47 -0.83 -0.076 0.30813E+04 55 cristobalite -1.46 -1.51 -0.05 -0.017 0.18608E+03 58 cymrite-K -1.54 -3.96 -2.42 -0.201 0.89356E+04 60 diaspore -2.36 -3.24 -0.88 -0.147 0.32606E+04 62 diopside 6.21 3.96 -2.25 -0.225 0.83156E+04 63 hedenbergite 4.66 2.34 -2.32 -0.232 0.85785E+04 65 eastonite 0.51 -2.22 -2.73 -0.105 0.10103E+05 66 enstatite 5.88 3.67 -2.21 -0.221 0.81722E+04 67 clinoenstatite-HiP 6.40 3.67 -2.73 -0.273 0.10085E+05 68 clinoenstatite 5.86 3.67 -2.19 -0.219 0.80904E+04 69 protoenstatite 6.02 3.67 -2.35 -0.235 0.86964E+04 70 epidote -0.04 -3.00 -2.96 -0.144 0.10959E+05 71 clinozoisite -3.68 -6.98 -3.30 -0.150 0.12207E+05 72 epidote-Fe 5.33 0.97 -4.36 -0.226 0.16115E+05 73 fayalite 3.41 1.95 -1.47 -0.210 0.54270E+04 74 ferrosilite 2.01 0.43 -1.57 -0.157 0.58156E+04 75 forsterite 7.72 5.18 -2.53 -0.362 0.93639E+04 78 gibbsite -0.72 -3.24 -2.52 -0.360 0.93181E+04 81 goethite 1.75 0.74 -1.01 -0.219 0.37382E+04 83 greenalite 6.01 2.16 -3.85 -0.320 0.14222E+05 84 grunerite 4.99 0.00 -4.99 -0.135 0.18435E+05 85 halite -1.87 -3.96 -2.08 -1.042 0.77035E+04 86 hematite 1.95 1.48 -0.47 -0.057 0.17394E+04 87 heulandite -9.97 -13.43 -3.47 -0.158 0.12828E+05 88 hercynite -3.20 -4.74 -1.55 -0.103 0.57224E+04 91 jadeite -0.25 -1.98 -1.73 -0.173 0.63896E+04 93 kalsilite 0.77 -0.93 -1.70 -0.243 0.62997E+04 94 kaolinite -6.75 -9.50 -2.75 -0.250 0.10179E+05 95 kyanite -7.17 -7.99 -0.81 -0.081 0.30095E+04 97 laumontite -4.99 -8.89 -3.90 -0.260 0.14424E+05 98 lawsonite -2.07 -5.87 -3.80 -0.253 0.14036E+05 99 leucite -1.41 -2.45 -1.03 -0.103 0.38232E+04 101 lizardite 11.45 7.02 -4.43 -0.369 0.16390E+05 102 magnesite -5.50 -9.21 -3.71 -1.235 0.13704E+05 103 magnetite 3.85 3.21 -0.64 -0.052 0.23660E+04 104 minnesotaite 1.73 -0.86 -2.60 -0.153 0.95964E+04 105 minnesotaite-Mg 8.16 3.99 -4.17 -0.245 0.15409E+05 106 magnesioferrite 7.12 4.83 -2.29 -0.187 0.84825E+04 108 manganosite 6.11 3.73 -2.38 -0.596 0.88143E+04 109 margarite -10.03 -12.34 -2.30 -0.092 0.85138E+04 113 monticellite 9.96 5.47 -4.49 -0.641 0.16587E+05 115 mullite-Si -6.54 -7.99 -1.45 -0.145 0.53441E+04 116 muscovite -9.51 -10.43 -0.92 -0.054 0.34018E+04 117 paragonite -8.81 -9.97 -1.16 -0.068 0.42814E+04 118 nepheline 1.09 -0.47 -1.56 -0.223 0.57694E+04 119 osumilite(2) -8.31 -12.49 -4.17 -0.087 0.15431E+05 120 osumilite-Fe -20.73 -24.03 -3.30 -0.069 0.12203E+05 122 periclase 6.54 3.35 -3.19 -0.797 0.11795E+05 123 periclase-Fe 3.79 1.73 -2.06 -0.516 0.76355E+04 124 perovskite-Al -3.84 -6.47 -2.64 -0.240 0.97506E+04 129 phlogopite-Na 9.38 6.55 -2.83 -0.157 0.10453E+05 131 prehnite 0.13 -3.74 -3.87 -0.228 0.14305E+05 132 prehnite-Fe 4.17 0.23 -3.94 -0.237 0.14564E+05 135 px-Mg-tschermaks -1.83 -4.64 -2.81 -0.200 0.10374E+05 136 px-Ca-tschermaks -1.32 -4.35 -3.03 -0.216 0.11194E+05 138 pyrrhotite -8.69 -9.51 -0.83 -0.275 0.30557E+04 139 pyrrhotiteFe0.875 -9.57 -9.98 -0.40 -0.149 0.14958E+04 140 pyrophyllite -11.05 -12.52 -1.47 -0.092 0.54486E+04 143 riebeckite 6.82 3.13 -3.70 -0.102 0.13672E+05 144 ringwoodite-Fe 4.43 1.95 -2.48 -0.355 0.91864E+04 146 rhodochrosite -5.66 -8.83 -3.17 -1.055 0.11705E+05 147 rhodonite 2.91 2.22 -0.70 -0.140 0.25801E+04 148 sanidine -3.40 -3.96 -0.56 -0.043 0.20663E+04 150 siderite -7.50 -10.83 -3.33 -1.111 0.12321E+05 151 sillimanite -7.29 -7.99 -0.69 -0.069 0.25582E+04 153 spinel -0.87 -3.12 -2.25 -0.150 0.83203E+04 161 stishovite 1.55 -1.51 -3.06 -1.020 0.11313E+05 162 sudoite-Fe -9.05 -14.03 -4.98 -0.161 0.18426E+05 163 sudoite -6.60 -10.79 -4.19 -0.135 0.15507E+05 164 sulfur -11.74 -13.22 -1.49 -0.458 0.55087E+04 165 sylvite -1.78 -4.42 -2.64 -1.320 0.97596E+04 166 talc 6.37 3.99 -2.38 -0.140 0.87896E+04 167 talc-Fe 3.20 -0.86 -4.06 -0.239 0.15021E+05 168 talc-tschermaks -1.26 -4.31 -3.05 -0.180 0.11290E+05 170 tephroite 7.60 5.94 -1.66 -0.237 0.61307E+04 173 topaz-H -5.26 -7.99 -2.73 -0.248 0.10079E+05 176 troilite-low -8.60 -9.51 -0.91 -0.304 0.33700E+04 180 wadsleyite-Fe 4.29 1.95 -2.35 -0.335 0.86816E+04 181 wadsleyite-Mg 10.02 5.18 -4.83 -0.690 0.17865E+05 182 wairakite -6.88 -8.89 -2.02 -0.119 0.74553E+04 183 walstromite 4.92 2.12 -2.80 -0.560 0.10353E+05 184 wollastonite 4.48 2.12 -2.36 -0.471 0.87103E+04 185 pseudo-wollastonite 4.61 2.12 -2.48 -0.497 0.91832E+04 186 zoisite -3.72 -6.98 -3.26 -0.148 0.12048E+05 189 beidellite-Ca -10.62 -12.49 -1.88 -0.116 0.69361E+04 190 beidellite-H -10.71 -13.09 -2.38 -0.152 0.88141E+04 191 beidellite-K -9.68 -11.83 -2.16 -0.132 0.79756E+04 192 beidellite-Mg -10.82 -12.54 -1.72 -0.106 0.63602E+04 193 beidellite-Na -9.62 -11.68 -2.06 -0.126 0.76252E+04 194 bornite -57.82 -57.94 -0.12 -0.009 0.45589E+03 196 chalcocite -15.33 -16.73 -1.39 -0.349 0.51565E+04 197 covellite -13.69 -14.98 -1.29 -0.491 0.47678E+04 199 montmorillonite-Ca -8.15 -9.75 -1.60 -0.099 0.59228E+04 200 montmorillonite-K -7.48 -9.09 -1.62 -0.099 0.59734E+04 201 montmorillonite-Mg -8.33 -9.80 -1.47 -0.091 0.54510E+04 202 montmorillonite-Na -7.16 -8.94 -1.78 -0.109 0.65782E+04 203 nontronite-Ca -2.75 -4.54 -1.80 -0.117 0.66455E+04 204 nontronite-H -2.85 -5.14 -2.30 -0.154 0.84959E+04 205 nontronite-K -1.81 -3.88 -2.08 -0.133 0.76774E+04 206 nontronite-Mg -2.92 -4.59 -1.67 -0.108 0.61673E+04 207 nontronite-Na -1.75 -3.73 -1.98 -0.127 0.73367E+04 212 gypsum -13.24 -15.54 -2.29 -0.573 0.84775E+04 229 alabandite -6.43 -7.52 -1.09 -0.363 0.40290E+04 231 anglesite -15.99 -18.28 -2.30 -1.148 0.84894E+04 235 boehmite -2.04 -3.24 -1.20 -0.200 0.44393E+04 239 copper,native 1.67 -1.75 -3.42 -1.189 0.12637E+05 241 ferrous-oxide 2.84 1.73 -1.11 -0.278 0.41131E+04 243 silver,native 0.30 -4.62 -4.92 -1.713 0.18212E+05 245 litharge 5.64 0.89 -4.75 -1.188 0.17577E+05 253 wurtzite -10.23 -11.07 -0.84 -0.279 0.30923E+04 254 zincite 2.88 0.17 -2.71 -0.677 0.10014E+05 255 an20ab80 -3.83 -3.97 -0.14 -0.011 0.51586E+03 256 an25ab75 -3.93 -4.09 -0.16 -0.012 0.58261E+03 257 an30ab70 -4.02 -4.20 -0.18 -0.014 0.67153E+03 258 tr.625ac.25prg.125 13.20 9.17 -4.03 -0.109 0.14912E+05 Calculations done for 535.0000 Deg. C; 795.0000 bar Temperature changed by -1.000 degrees to 534.000 degrees C. Temperature reached given limit of 535.0000 TEMP = 534.0000 Execution stopped.