File SKIP_SPECIES.TXT lists species and minerals omitted from the
calculations due to given T, P, option switches, or suppression
in CHIMRUN, or are suppressed in the SOLTHERM database.
It also lists minerals for which density is not specified
in SOLTHERM.
This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1).
methanol,aq is suppressed in SOLTHERM data file.
methanol,aq is suppressed in SOLTHERM data file.
CuCl4-3 is suppressed in SOLTHERM data file.
H2BO3- is suppressed in SOLTHERM data file.
UO2CO3,aq is suppressed in SOLTHERM data file.
UO2SO4,aq is suppressed in SOLTHERM data file.
UO2Cl2,aq is suppressed in SOLTHERM data file.
UO2F2,aq is suppressed in SOLTHERM data file.
PO4-3 is suppressed in SOLTHERM data file.
H2PO4- is suppressed in SOLTHERM data file.
H3PO4 is suppressed in SOLTHERM data file.
fCO2,1bar20C is suppressed in THIS RUN.
amesite is suppressed in SOLTHERM data file.
antigorite is suppressed in SOLTHERM data file.
sapphirine-Fe(221) is suppressed in SOLTHERM data file.
sapphirine(221) is suppressed in SOLTHERM data file.
talc-prl is suppressed in SOLTHERM data file.
PrO1.833(s) is suppressed in SOLTHERM data file.
niter-NH4 is suppressed in SOLTHERM data file.
FMQ_HS-1 is suppressed in THIS RUN.
kf-ab-equil is suppressed in THIS RUN.
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Species No. Charge Tot.moles Trial molality Gamma Mixing solution
H+ 1 1. 0.32344E+00 0.43025E-05 0.4449 0.00000000E+00
H2O 2 0. 0.55318E+02 0.10000E+01 0.9517 0.55508250E+02
Cl- 3 -1. 0.15454E+01 0.11700E+01 0.4691 0.00000000E+00
SO4-- 4 -2. 0.18864E-03 0.81054E-04 0.0440 0.00000000E+00
HCO3- 5 -1. 0.34993E+00 0.20644E-01 0.4929 0.00000000E+00
HS- 6 -1. 0.14030E-04 0.29717E-05 0.4717 0.00000000E+00
H4SiO4 7 0. 0.28117E-02 0.27794E-02 1.0000 0.00000000E+00
Al+++ 8 3. 0.24073E-05 0.82727E-15 0.0011 0.00000000E+00
Ca++ 9 2. 0.21052E-02 0.14726E-02 0.0372 0.00000000E+00
Mg++ 10 2. 0.17177E-03 0.10466E-03 0.0305 0.00000000E+00
Fe++ 11 2. 0.16033E-05 0.10700E-05 0.0321 0.00000000E+00
K+ 12 1. 0.45456E-01 0.40961E-01 0.5001 0.00000000E+00
Na+ 13 1. 0.15238E+01 0.11475E+01 0.4715 0.00000000E+00
Mn++ 14 2. 0.34477E-04 0.25340E-06 0.0333 0.00000000E+00
Zn++ 15 2. 0.74682E-05 0.44513E-08 0.0321 0.00000000E+00
Cu+ 16 1. 0.17016E-06 0.60617E-11 0.4707 0.00000000E+00
Pb++ 17 2. 0.15650E-05 0.15583E-08 0.0416 0.00000000E+00
Ag+ 18 1. 0.42713E-06 0.13296E-10 0.4948 0.00000000E+00
Au+ 19 1. 0.31110E-11 0.62614E-20 0.5031 0.00000000E+00
Ba++ 20 2. 0.40644E-05 0.11059E-05 0.0446 0.00000000E+00
F- 21 -1. 0.16304E-02 0.12576E-02 0.4232 0.00000000E+00
H2AsO3- 22 -1. 0.12964E-03 0.12914E-03 1.0000 0.00000000E+00
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Chg. balance for the mixing solution = 0.0000E+00 Max. difference allowed = 0.1545E-03
The following parameters were given:
ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 500.0000
SLIM = 0.500000E+00 TEMP = 199.9700 SINC = 0.5000E-01
TEMPC = 25.0000 TOTMIX = 0.000000E+00 ENTH = 0.0000
SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000
SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1082.4053
SUPRNT = 0.1000E-10 VBOX-1 = 0.0000 RHOFRS = 0.0000
RHOROC = 0.0000
The following options were selected:
CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 1
NLOOP = 70 ISTEP = 2 LIMSOL = 2 LOOC = 0
IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1
INCREM = 0 INCP = 0 MINSOL = 0 NEUT = 0
AWAT = 0 CHGF = 0
Of the derived species, only those with molality > 0.10E-10 will appear in the output
Species No. Charge Log K(diss) Species No. Charge Log K(diss)
SiF6-2 23 -2. -24.0537 FeCl2,aq 102 0. 0.2961
HSiO3- 24 -1. 8.6869 FeCl+2 103 2. 5.3673
Ca(HSiO3)+ 25 1. 6.5692 FeF+ 104 1. -2.3547
Mg(HSiO3)+ 26 1. 6.6492 FeF+2 105 2. -0.2035
NaHSiO3,aq 27 0. 7.7929 FeO,aq 106 0. 13.0998
Ag(CO3)- 28 -1. 8.2019 FeOH+ 107 1. 5.8994
Ag(CO3)2-3 29 -3. 18.6148 HFeO2- 108 -1. 20.3859
Ag+2 30 2. 20.7929 FeO+ 109 1. 9.0645
AgCl,aq 31 0. -2.7620 FeOH+2 110 2. 7.5523
AgCl2- 32 -1. -4.3979 FeO2- 111 -1. 19.3670
AgCl3-2 33 -2. -3.4129 HFeO2,aq 112 0. 12.6557
AgCl4-3 34 -3. -1.1479 H2,aq 113 0. 7.5785
AgF,aq 35 0. -0.8709 KCl,aq 114 0. 0.9263
Ag(OH),aq 36 0. 10.2921 KHSO4,aq 115 0. -2.8712
AgO- 37 -1. 17.6335 KOH,aq 116 0. 10.9103
Ag(HS),aq 38 0. -8.7276 KSO4- 117 -1. -1.8198
Ag(HS)2- 39 -1. -11.5285 MgCO3,aq 118 0. 5.9151
AlO+ 40 1. 4.1937 Mg(HCO3)+ 119 1. -2.2427
AlOH+2 41 2. 1.5595 MgCl+ 120 1. -0.8647
HAlO2,aq 42 0. 6.8769 MgF+ 121 1. -2.5527
AlO2- 43 -1. 11.4851 MgOH+ 122 1. 7.4445
AsO2- 44 -1. 1.0128 Mn+3 123 3. 17.3354
HAsO2,aq 45 0. -6.8443 MnF+ 124 1. -1.9627
H3AsO3,aq 46 0. -7.3462 MnO,aq 125 0. 14.6048
H3AsO4,aq 47 0. -0.0418 MnOH+ 126 1. 6.7734
H2AsO4- 48 -1. 3.0520 MnO2-2 127 -2. 34.6622
HAsO4-2 49 -2. 10.2498 HMnO2- 128 -1. 24.6020
AsO4-3 50 -3. 21.6036 MnO4- 129 -1. 63.9466
HAs3S6-2 51 -2. -67.0569 MnO4-2 130 -2. 65.0977
H2As3S6- 52 -1. -73.5090 MnCl+ 131 1. -2.0346
H3As3S6,aq 53 0. -75.8261 MnSO4,aq 132 0. -3.2837
Au+3 54 3. 28.9931 NaCl,aq 133 0. 0.0242
AuCl,aq 55 0. -5.4902 NaF,aq 134 0. 0.1462
AuCl2- 56 -1. -6.5792 NaOH,aq 135 0. 11.0562
AuCl3-2 57 -2. -6.0312 O2,aq 136 0. 40.0003
AuCl4- 58 -1. 22.9250 OH- 137 -1. 11.0862
AuOH,aq 59 0. -2.6546 HO2- 138 -1. 40.9792
AuHS,aq 60 0. -15.6928 H2O2,aq 139 0. 30.6972
Au(HS)2- 61 -1. -19.3129 PbCl+ 140 1. -2.4907
BaCO3,aq 62 0. 5.6352 PbCl2,aq 141 0. -3.6936
Ba(HCO3)+ 63 1. -3.1086 PbCl3- 142 -1. -3.5655
BaCl+ 64 1. -1.1867 PbCl4-2 143 -2. -2.8875
BaF+ 65 1. -1.2167 PbF+ 144 1. -2.6328
CH4,aq 66 0. 5.9610 PbF2,aq 145 0. -3.9607
C2H6,aq 67 0. 11.8951 PbO,aq 146 0. 11.3675
C3H8,aq 68 0. 16.9421 HPbO2- 147 -1. 20.7485
C4H10,aq 69 0. 22.0061 Pb(HS)2,aq 148 0. -12.1690
ethanol,aq 70 0. 13.8464 Pb(HS)3- 149 -1. -13.4229
CO,aq 71 0. 2.0568 H2S,aq 150 0. -6.6368
CO2,aq 72 0. -6.8387 S2-2 151 -2. 0.9421
CO3-2 73 -2. 10.1908 S3-2 152 -2. -8.3380
CaCO3,aq 74 0. 5.0362 S3- 153 -1. -16.9295
Ca(HCO3)+ 75 1. -2.2607 S4-2 154 -2. -17.4720
CaCl+ 76 1. -1.0987 S5-2 155 -2. -26.4660
CaCl2,aq 77 0. -0.5706 SO2,aq 156 0. -3.7489
CaF+ 78 1. -2.0837 SO3-2 157 -2. 8.8623
CaOH+ 79 1. 7.9815 HSO3- 158 -1. 0.1956
CaSO4,aq 80 0. -3.2107 HSO4- 159 -1. -4.2776
HCl,aq 81 0. 0.1482 HSO5- 160 -1. 27.2139
HClO,aq 82 0. 23.9001 S2O3-2 161 -2. -4.7748
ClO- 83 -1. 31.0400 HS2O3- 162 -1. -8.0035
HClO2,aq 84 0. 52.7923 H2S2O3,aq 163 0. -9.8793
Cu+2 85 2. 0.8987 S2O4-2 164 -2. 6.5321
CuCl+ 86 1. -0.5610 HS2O4- 165 -1. 2.8354
CuCl2,aq 87 0. -0.2188 H2S2O4,aq 166 0. 1.0896
CuCl3- 88 -1. 1.4563 S2O5-2 167 -2. 5.7892
CuCl4-2 89 -2. 4.7703 S2O6-2 168 -2. 6.4904
CuCl,aq 90 0. -3.6810 S2O8-2 169 -2. 28.7284
CuCl2- 91 -1. -4.8960 S3O6-2 170 -2. -0.6917
CuCl3-2 92 -2. -3.3940 S4O6-2 171 -2. -20.1281
CuF+ 93 1. -1.6060 S5O6-2 172 -2. -16.9919
CuO,aq 94 0. 10.9972 ZnCl+ 173 1. -3.8774
CuOH+ 95 1. 5.8920 ZnCl2,aq 174 0. -3.8263
CuO2-2 96 -2. 31.0966 ZnCl3- 175 -1. -2.9093
HCuO2- 97 -1. 20.0295 ZnF+ 176 1. -2.1827
HF,aq 98 0. -4.6897 ZnO,aq 177 0. 11.0137
HF2- 99 -1. -4.1287 ZnOH+ 178 1. 3.0755
Fe+3 100 3. 7.9851 ZnO2-2 179 -2. 30.0709
FeCl+ 101 1. -0.9587 HZnO2- 180 -1. 19.5688
For mixed gases (JSOLS=6), log K(hydrol) = log (K*P)
Log K Trial Log K Trial
Mineral No. hydrol Moles Mineral No. hydrol Moles
H2O,gas 1 1.444 0.0000E+00 pumpellyite-Mg 140 25.779 0.0000E+00
CO2,gas 2 -6.490 0.0000E+00 px-Mg-tschermaks 141 9.115 0.0000E+00
CH4,gas 3 5.496 0.0000E+00 px-Ca-tschermaks 142 9.049 0.0000E+00
H2,gas 4 7.305 0.0000E+00 pyrite 143 -19.225 0.0000E+00
H2S,gas 5 -5.674 0.0000E+00 pyrrhotite 144 -5.014 0.0000E+00
S2,gas 6 -8.912 0.0000E+00 pyrrhotiteFe0.875 145 -6.331 0.0000E+00
CO,gas 7 1.745 0.0000E+00 pyroxmangite 146 5.393 0.0000E+00
SO3,gas 8 10.225 0.0000E+00 pyrophyllite 147 -9.510 0.0000E+00
O2,gas 9 36.925 0.0000E+00 quartz 148 -2.315 0.0000E+00
SO2,gas 10 -2.252 0.0000E+00 rankinite 149 31.464 0.0000E+00
HF,gas 11 -0.768 0.0000E+00 riebeckite 150 14.095 0.0000E+00
HCl,gas 12 3.417 0.0000E+00 ringwoodite-Fe 151 10.558 0.0000E+00
acmite 13 5.980 0.0000E+00 ringwoodite-Mg 152 20.124 0.0000E+00
akermanite 14 27.286 0.0000E+00 rhodochrosite 153 -1.850 0.0000E+00
akimotoite 15 12.340 0.0000E+00 rhodonite 154 5.417 0.0000E+00
akimotoite-Fe 16 9.487 0.0000E+00 sanidine 155 -2.692 0.0000E+00
albite-high 17 -1.581 0.0000E+00 sapphirine(351) 156 32.190 0.0000E+00
albite 18 -2.246 0.0000E+00 siderite 157 -3.539 0.0000E+00
almandine 19 11.204 0.0000E+00 sillimanite 158 -1.252 0.0000E+00
pyrope 20 21.269 0.0000E+00 sodalite 159 27.486 0.0000E+00
spessartine 21 12.643 0.0000E+00 spinel 160 10.156 0.0000E+00
analcite 22 0.781 0.0000E+00 spurrite 161 45.196 0.0000E+00
andalusite 23 -1.419 0.0000E+00 staurolite-Fe 162 7.480 0.0000E+00
andradite 24 28.552 0.0000E+00 staurolite-Mg 163 20.224 0.0000E+00
grossular 25 20.249 0.0000E+00 staurolite-Mn 164 17.143 0.0000E+00
anhydrite 26 -6.831 0.0000E+00 stilbite 165 -8.820 0.0000E+00
ankerite 27 -4.145 0.0000E+00 stilpnomelane-Fe 166 3.871 0.0000E+00
annite 28 11.905 0.0000E+00 stilpnomelane-Mg 167 14.745 0.0000E+00
phlogopite 29 17.565 0.0000E+00 stishovite 168 2.333 0.0000E+00
biotite-Mn 30 23.206 0.0000E+00 sudoite-Fe 169 3.773 0.0000E+00
anorthite 31 4.238 0.0000E+00 sudoite 170 6.082 0.0000E+00
anthophyllite 32 35.809 0.0000E+00 sulfur 171 -8.492 0.0000E+00
anthophyllite-Fe 33 17.955 0.0000E+00 sylvite 172 1.388 0.0000E+00
aragonite 34 -0.172 0.0000E+00 talc 173 11.302 0.0000E+00
brucite 35 9.504 0.0000E+00 talc-Fe 174 8.735 0.0000E+00
calcite 36 -0.312 0.0000E+00 talc-tschermaks 175 8.610 0.0000E+00
carnegieite-low 37 5.151 0.0000E+00 tenorite 176 4.581 0.0000E+00
carnegieite-high 38 5.825 0.0000E+00 tephroite 177 13.370 0.0000E+00
carpholite-Mg 39 1.631 0.0000E+00 tilleyite 178 30.134 0.0000E+00
carpholite-Fe 40 0.099 0.0000E+00 titanite-CaSi 179 12.259 0.0000E+00
celadonite 41 2.387 0.0000E+00 topaz-H 180 -0.992 0.0000E+00
celadonite-Fe 42 1.073 0.0000E+00 tridymite 181 -2.052 0.0000E+00
chrysotile 43 17.444 0.0000E+00 tremolite 182 34.067 0.0000E+00
chondrodite 44 40.687 0.0000E+00 ferroactinolite 183 26.346 0.0000E+00
clinochlore 45 23.381 0.0000E+00 troilite-low 184 -5.072 0.0000E+00
daphnite 46 15.138 0.0000E+00 tschermakite 185 25.059 0.0000E+00
chlorite-Mn 47 31.446 0.0000E+00 vesuvianite 186 144.223 0.0000E+00
chlorite-Al-free 48 34.510 0.0000E+00 wadeite-Si 187 18.152 0.0000E+00
chloritoid-Mg 49 4.763 0.0000E+00 wadsleyite-Fe 188 10.658 0.0000E+00
chloritoid-Fe 50 1.650 0.0000E+00 wadsleyite-Mg 189 18.712 0.0000E+00
chloritoid-Mn 51 3.842 0.0000E+00 wairakite 190 -1.865 0.0000E+00
clinohumite 52 69.471 0.0000E+00 walstromite 191 8.871 0.0000E+00
coesite 53 -1.825 0.0000E+00 wollastonite 192 8.067 0.0000E+00
cordierite-H 54 6.041 0.0000E+00 pseudo-wollastonite 193 8.440 0.0000E+00
cordierite 55 6.387 0.0000E+00 zoisite 194 9.786 0.0000E+00
cordierite-Fe 56 3.466 0.0000E+00 Ag2O 195 10.213 0.0000E+00
cordierite-Mn 57 7.898 0.0000E+00 argentite 196 -21.917 0.0000E+00
corundum 58 1.193 0.0000E+00 arsenic 197 -5.406 0.0000E+00
corundum-MgSi 59 14.154 0.0000E+00 arsenolite 198 -13.681 0.0000E+00
cristobalite 60 -2.023 0.0000E+00 arsenopyrite 199 -13.344 0.0000E+00
cummingtonite 61 35.983 0.0000E+00 beidellite-Ca 200 -6.927 0.0000E+00
cuprite 62 0.598 0.0000E+00 beidellite-H 201 -7.368 0.0000E+00
cymrite-K 63 -0.291 0.0000E+00 beidellite-K 202 -6.459 0.0000E+00
deerite 64 61.501 0.0000E+00 beidellite-Mg 203 -7.170 0.0000E+00
diaspore 65 -0.096 0.0000E+00 beidellite-Na 204 -6.381 0.0000E+00
diamond 66 -2.117 0.0000E+00 bornite 205 -71.938 0.0000E+00
diopside 67 11.804 0.0000E+00 calcium 206 66.388 0.0000E+00
hedenbergite 68 10.174 0.0000E+00 chalcedony 207 -2.168 0.0000E+00
dolomite,ordered 69 -1.960 0.0000E+00 chalcocite 208 -21.889 0.0000E+00
eastonite 70 14.028 0.0000E+00 claudetite 209 -13.854 0.0000E+00
enstatite 71 11.991 0.0000E+00 covellite 210 -16.149 0.0000E+00
clinoenstatite-HiP 72 12.851 0.0000E+00 dawsonite 211 -0.237 0.0000E+00
clinoenstatite 73 11.917 0.0000E+00 loellingite 212 -2.214 0.0000E+00
protoenstatite 74 12.393 0.0000E+00 montmorillonite-Ca 213 -5.923 0.0000E+00
epidote 75 13.035 0.0000E+00 montmorillonite-K 214 -5.560 0.0000E+00
clinozoisite 76 9.748 0.0000E+00 montmorillonite-Mg 215 -6.162 0.0000E+00
epidote-Fe 77 18.972 0.0000E+00 montmorillonite-Na 216 -5.401 0.0000E+00
fayalite 78 9.329 0.0000E+00 nontronite-Ca 217 0.526 0.0000E+00
ferrosilite 79 7.104 0.0000E+00 nontronite-H 218 0.081 0.0000E+00
forsterite 80 14.892 0.0000E+00 nontronite-K 219 0.993 0.0000E+00
gedrite 81 25.459 0.0000E+00 nontronite-Mg 220 0.312 0.0000E+00
gehlenite 82 22.852 0.0000E+00 nontronite-Na 221 1.073 0.0000E+00
gibbsite 83 1.163 0.0000E+00 orpiment 222 -45.717 0.0000E+00
glaucophane 84 12.995 0.0000E+00 realgar 223 -54.918 0.0000E+00
glaucophane-Fe 85 8.321 0.0000E+00 sepiolite 224 19.097 0.0000E+00
goethite 86 4.385 0.0000E+00 topaz 225 -20.542 0.0000E+00
graphite 87 -2.503 0.0000E+00 alite 226 45.043 0.0000E+00
greenalite 88 11.219 0.0000E+00 belite 227 23.514 0.0000E+00
grunerite 89 19.348 0.0000E+00 ettringite 228 31.345 0.0000E+00
halite 90 1.352 0.0000E+00 gypsum 229 -5.820 0.0000E+00
hematite 91 8.107 0.0000E+00 hemicarboaluminate 230 53.881 0.0000E+00
heulandite 92 -9.126 0.0000E+00 hydrogarnet 231 44.148 0.0000E+00
hercynite 93 7.245 0.0000E+00 hydrogarnet-Si 232 35.786 0.0000E+00
hollandite 94 18.899 0.0000E+00 jennite 233 20.300 0.0000E+00
iron 95 14.758 0.0000E+00 monosulfoaluminate 234 37.267 0.0000E+00
jadeite 96 1.602 0.0000E+00 monocarboaluminate 235 46.336 0.0000E+00
julgoldite 97 51.350 0.0000E+00 portlandite 236 14.574 0.0000E+00
kalsilite 98 4.138 0.0000E+00 stratlingite 237 25.579 0.0000E+00
kaolinite 99 -5.325 0.0000E+00 tricarboaluminate 238 57.612 0.0000E+00
kyanite 100 -1.451 0.0000E+00 tobermorite 239 8.730 0.0000E+00
larnite-bredigite 101 23.729 0.0000E+00 C4AH13 240 63.437 0.0000E+00
laumontite 102 -2.023 0.0000E+00 C2AH8 241 33.067 0.0000E+00
lawsonite 103 3.119 0.0000E+00 C3A 242 62.199 0.0000E+00
leucite 104 1.261 0.0000E+00 C4AF 243 84.180 0.0000E+00
lime 105 20.310 0.0000E+00 CAH10 244 20.307 0.0000E+00
lizardite 106 17.069 0.0000E+00 acanthite 245 -21.745 0.0000E+00
magnesite 107 -0.916 0.0000E+00 alabandite 246 -2.147 0.0000E+00
magnetite 108 13.110 0.0000E+00 alunite 247 -17.802 0.0000E+00
minnesotaite 109 6.319 0.0000E+00 anglesite 248 -8.492 0.0000E+00
minnesotaite-Mg 110 14.522 0.0000E+00 artinite 249 11.466 0.0000E+00
magnesioferrite 111 17.946 0.0000E+00 azurite 250 3.624 0.0000E+00
majorite 112 38.841 0.0000E+00 barite 251 -9.748 0.0000E+00
manganosite 113 10.591 0.0000E+00 boehmite 252 0.944 0.0000E+00
margarite 114 3.147 0.0000E+00 cerussite 253 -2.859 0.0000E+00
meionite 115 16.450 0.0000E+00 chalcopyrite 254 -24.630 0.0000E+00
merwinite 116 42.390 0.0000E+00 chlorargyrite 255 -6.026 0.0000E+00
microcline 117 -3.647 0.0000E+00 copper,native 256 -1.515 0.0000E+00
monticellite 118 18.154 0.0000E+00 dolomite,disordered 257 -1.535 0.0000E+00
mullite-Al 119 273.876 0.0000E+00 ferrous-oxide 258 6.763 0.0000E+00
mullite-Si 120 0.260 0.0000E+00 fluorite 259 -10.333 0.0000E+00
muscovite 121 -4.543 0.0000E+00 galena 260 -10.172 0.0000E+00
paragonite 122 -3.402 0.0000E+00 gold,native 261 -13.311 0.0000E+00
nepheline 123 4.574 0.0000E+00 silver,native 262 -4.166 0.0000E+00
osumilite(1) 124 2.311 0.0000E+00 huntite 263 -2.476 0.0000E+00
osumilite(2) 125 6.413 0.0000E+00 litharge 264 8.423 0.0000E+00
osumilite-Fe 126 -3.189 0.0000E+00 hydromagnesite 265 10.608 0.0000E+00
pargasite 127 40.301 0.0000E+00 malachite 266 2.812 0.0000E+00
periclase 128 11.872 0.0000E+00 nesquehonite 267 4.514 0.0000E+00
periclase-Fe 129 8.234 0.0000E+00 potassium-oxide 268 56.480 0.0000E+00
perovskite-Al 130 4.307 0.0000E+00 silica-amorphous 269 -1.667 0.0000E+00
perovskite-Ca 131 18.629 0.0000E+00 smithsonite 270 -1.932 0.0000E+00
perovskite-Fe 132 15.856 0.0000E+00 sodium-oxide 271 45.147 0.0000E+00
perovskite-Mg 133 17.453 0.0000E+00 sphalerite 272 -9.708 0.0000E+00
phase_A 134 58.964 0.0000E+00 wurtzite 273 -8.265 0.0000E+00
phlogopite-Na 135 19.371 0.0000E+00 zincite 274 5.675 0.0000E+00
piemontite(ordered) 136 20.446 0.0000E+00 an20ab80 275 -1.167 0.0000E+00
prehnite 137 10.012 0.0000E+00 an25ab75 276 -0.869 0.0000E+00
prehnite-Fe 138 14.212 0.0000E+00 an30ab70 277 -0.566 0.0000E+00
pumpellyite-Fe 139 23.604 0.0000E+00 tr.625ac.25prg.125 278 30.414 0.0000E+00
Mixing solution: Stoch.ionic strengh 0.5000E-10
Temperature 25.00
HEAT 0.64600
The following minerals and/or gases with identical index are in solid solution:
H2O,gas 6
CO2,gas 6
CH4,gas 6
H2,gas 6
H2S,gas 6
S2,gas 6
CO,gas 6
SO3,gas 6
SO2,gas 6
HF,gas 6
HCl,gas 6
almandine 16
pyrope 16
spessartine 16
andradite 8
grossular 8
annite 15
phlogopite 15
biotite-Mn 15
clinochlore 1
daphnite 1
chlorite-Mn 1
diopside 5
hedenbergite 5
epidote 3
clinozoisite 3
iron 9
magnetite 14
talc 7
talc-Fe 7
tremolite 2
ferroactinolite 2
gold,native 10
silver,native 10
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 9 Loop limit = 70
Temperature = 199.97 C Pressure = 500.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5564E+02 kg liquid = 0.1002E+01
Moles total = 0.5532E+02 kg total = 0.9966E+00 Activity = 0.9513
Stoichiometric ionic strength = .1744202E+01 Osmotic coef. = 0.8983
True ionic strength = .1230111E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.63515E-05 -5.1971 0.29704E-05 -5.5272 0.46766E+00 -0.3301
2 H2O 0.95132E+00 -0.0217 0.95132E+00 -0.0217
3 Cl- 0.12006E+01 0.0794 0.60234E+00 -0.2202 0.50171E+00 -0.2995
4 SO4-- 0.16704E-03 -3.7772 0.66000E-05 -5.1805 0.39511E-01 -1.4033
5 HCO3- 0.26393E-01 -1.5785 0.13822E-01 -1.8594 0.52371E+00 -0.2809
6 HS- 0.17299E-05 -5.7620 0.87203E-06 -6.0595 0.50408E+00 -0.2975
7 H4SiO4 0.27915E-02 -2.5542 0.27915E-02 -2.5542 0.10000E+01 0.0000
8 Al+++ 0.52356E-13 -13.2810 0.27885E-16 -16.5546 0.53261E-03 -3.2736
9 Ca++ 0.12334E-02 -2.9089 0.42355E-04 -4.3731 0.34341E-01 -1.4642
10 Mg++ 0.12190E-03 -3.9140 0.37353E-05 -5.4277 0.30642E-01 -1.5137
11 Fe++ 0.11741E-05 -5.9303 0.37022E-07 -7.4315 0.31532E-01 -1.5012
12 K+ 0.43675E-01 -1.3598 0.23144E-01 -1.6356 0.52991E+00 -0.2758
13 Na+ 0.11812E+01 0.0723 0.59449E+00 -0.2259 0.50329E+00 -0.2982
14 Mn++ 0.69483E-05 -5.1581 0.22376E-06 -6.6502 0.32203E-01 -1.4921
15 Zn++ 0.19937E-07 -7.7003 0.62867E-09 -9.2016 0.31532E-01 -1.5012
16 Cu+ 0.45563E-11 -11.3414 0.22896E-11 -11.6402 0.50251E+00 -0.2989
17 Pb++ 0.65771E-08 -8.1820 0.24157E-09 -9.6170 0.36729E-01 -1.4350
18 Ag+ 0.21641E-10 -10.6647 0.11360E-10 -10.9446 0.52494E+00 -0.2799
19 Au+ 0.12995E-20 -20.8862 0.69224E-21 -21.1597 0.53271E+00 -0.2735
20 Ba++ 0.13913E-05 -5.8566 0.53335E-07 -7.2730 0.38335E-01 -1.4164
21 F- 0.12829E-02 -2.8918 0.59020E-03 -3.2290 0.46006E+00 -0.3372
22 H2AsO3- 0.21324E-05 -5.6711 0.14465E-05 -5.8397 0.67834E+00 -0.1686
24 HSiO3- 0.40485E-05 -5.3927 0.20312E-05 -5.6922 0.50171E+00 -0.2995
25 Ca(HSiO3)+ 0.21178E-07 -7.6741 0.11282E-07 -7.9476 0.53271E+00 -0.2735
26 Mg(HSiO3)+ 0.15536E-08 -8.8087 0.82763E-09 -9.0822 0.53271E+00 -0.2735
27 NaHSiO3,aq 0.94602E-05 -5.0241 0.94602E-05 -5.0241 0.10000E+01 0.0000
31 AgCl,aq 0.39553E-08 -8.4028 0.39553E-08 -8.4028 0.10000E+01 0.0000
32 AgCl2- 0.20537E-06 -6.6875 0.10303E-06 -6.9870 0.50171E+00 -0.2995
33 AgCl3-2 0.17013E-06 -6.7692 0.64245E-08 -8.1922 0.37762E-01 -1.4229
34 AgCl4-3 0.41335E-07 -7.3837 0.21023E-10 -10.6773 0.50860E-03 -3.2936
38 Ag(HS),aq 0.52907E-08 -8.2765 0.52907E-08 -8.2765 0.10000E+01 0.0000
40 AlO+ 0.36134E-09 -9.4421 0.19249E-09 -9.7156 0.53271E+00 -0.2735
42 HAlO2,aq 0.12786E-06 -6.8933 0.12786E-06 -6.8933 0.10000E+01 0.0000
43 AlO2- 0.22733E-05 -5.6433 0.10609E-05 -5.9743 0.46666E+00 -0.3310
44 AsO2- 0.29429E-06 -6.5312 0.14765E-06 -6.8308 0.50171E+00 -0.2995
45 HAsO2,aq 0.31556E-04 -4.5009 0.31556E-04 -4.5009 0.10000E+01 0.0000
46 H3AsO3,aq 0.95348E-04 -4.0207 0.95348E-04 -4.0207 0.10000E+01 0.0000
48 H2AsO4- 0.17612E-09 -9.7542 0.88362E-10 -10.0537 0.50171E+00 -0.2995
49 HAsO4-2 0.49958E-10 -10.3014 0.18865E-11 -11.7243 0.37762E-01 -1.4229
62 BaCO3,aq 0.57487E-09 -9.2404 0.57487E-09 -9.2404 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.17350E-05 -5.7607 0.94663E-06 -6.0238 0.54562E+00 -0.2631
64 BaCl+ 0.92689E-06 -6.0330 0.49376E-06 -6.3065 0.53271E+00 -0.2735
65 BaF+ 0.97325E-09 -9.0118 0.51846E-09 -9.2853 0.53271E+00 -0.2735
66 CH4,aq 0.20586E-08 -8.6864 0.19004E-08 -8.7211 0.92316E+00 -0.0347
71 CO,aq 0.54995E-08 -8.2597 0.54995E-08 -8.2597 0.10000E+01 0.0000
72 CO2,aq 0.32247E+00 -0.4915 0.29769E+00 -0.5262 0.92316E+00 -0.0347
73 CO3-2 0.79413E-05 -5.1001 0.29988E-06 -6.5231 0.37762E-01 -1.4229
74 CaCO3,aq 0.18133E-05 -5.7415 0.18133E-05 -5.7415 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.20030E-03 -3.6983 0.10670E-03 -3.9718 0.53271E+00 -0.2735
76 CaCl+ 0.60110E-03 -3.2211 0.32021E-03 -3.4946 0.53271E+00 -0.2735
77 CaCl2,aq 0.57169E-04 -4.2428 0.57169E-04 -4.2428 0.10000E+01 0.0000
78 CaF+ 0.56897E-05 -5.2449 0.30309E-05 -5.5184 0.53271E+00 -0.2735
79 CaOH+ 0.26572E-06 -6.5756 0.14155E-06 -6.8491 0.53271E+00 -0.2735
80 CaSO4,aq 0.45412E-06 -6.3428 0.45412E-06 -6.3428 0.10000E+01 0.0000
81 HCl,aq 0.12718E-05 -5.8956 0.12718E-05 -5.8956 0.10000E+01 0.0000
90 CuCl,aq 0.66157E-08 -8.1794 0.66157E-08 -8.1794 0.10000E+01 0.0000
91 CuCl2- 0.13030E-06 -6.8850 0.65374E-07 -7.1846 0.50171E+00 -0.2995
92 CuCl3-2 0.32829E-07 -7.4837 0.12397E-08 -8.9067 0.37762E-01 -1.4229
98 HF,aq 0.85804E-04 -4.0665 0.85804E-04 -4.0665 0.10000E+01 0.0000
99 HF2- 0.27738E-07 -7.5569 0.13916E-07 -7.8565 0.50171E+00 -0.2995
101 FeCl+ 0.38065E-06 -6.4195 0.20278E-06 -6.6930 0.53271E+00 -0.2735
102 FeCl2,aq 0.67922E-08 -8.1680 0.67922E-08 -8.1680 0.10000E+01 0.0000
104 FeF+ 0.92836E-08 -8.0323 0.49455E-08 -8.3058 0.53271E+00 -0.2735
106 FeO,aq 0.31725E-09 -9.4986 0.31725E-09 -9.4986 0.10000E+01 0.0000
107 FeOH+ 0.28062E-07 -7.5519 0.14949E-07 -7.8254 0.53271E+00 -0.2735
108 HFeO2- 0.10480E-10 -10.9796 0.52580E-11 -11.2792 0.50171E+00 -0.2995
111 FeO2- 0.29446E-10 -10.5310 0.14773E-10 -10.8305 0.50171E+00 -0.2995
112 HFeO2,aq 0.22574E-09 -9.6464 0.22574E-09 -9.6464 0.10000E+01 0.0000
113 H2,aq 0.39503E-06 -6.4034 0.36468E-06 -6.4381 0.92316E+00 -0.0347
114 KCl,aq 0.16520E-02 -2.7820 0.16520E-02 -2.7820 0.10000E+01 0.0000
115 KHSO4,aq 0.33730E-09 -9.4720 0.33730E-09 -9.4720 0.10000E+01 0.0000
116 KOH,aq 0.91133E-07 -7.0403 0.91133E-07 -7.0403 0.10000E+01 0.0000
117 KSO4- 0.20105E-04 -4.6967 0.10087E-04 -4.9962 0.50171E+00 -0.2995
118 MgCO3,aq 0.21133E-07 -7.6750 0.21133E-07 -7.6750 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.16948E-04 -4.7709 0.90282E-05 -5.0444 0.53271E+00 -0.2735
120 MgCl+ 0.30932E-04 -4.5096 0.16478E-04 -4.7831 0.53271E+00 -0.2735
121 MgF+ 0.14775E-05 -5.8305 0.78708E-06 -6.1040 0.53271E+00 -0.2735
122 MgOH+ 0.80699E-07 -7.0931 0.42989E-07 -7.3666 0.53271E+00 -0.2735
124 MnF+ 0.22751E-07 -7.6430 0.12120E-07 -7.9165 0.53271E+00 -0.2735
125 MnO,aq 0.59940E-10 -10.2223 0.59940E-10 -10.2223 0.10000E+01 0.0000
126 MnOH+ 0.22668E-07 -7.6446 0.12075E-07 -7.9181 0.53271E+00 -0.2735
131 MnCl+ 0.27398E-04 -4.5623 0.14595E-04 -4.8358 0.53271E+00 -0.2735
132 MnSO4,aq 0.28380E-08 -8.5470 0.28380E-08 -8.5470 0.10000E+01 0.0000
133 NaCl,aq 0.33870E+00 -0.4702 0.33870E+00 -0.4702 0.10000E+01 0.0000
134 NaF,aq 0.25059E-03 -3.6010 0.25059E-03 -3.6010 0.10000E+01 0.0000
135 NaOH,aq 0.16727E-05 -5.7766 0.16727E-05 -5.7766 0.10000E+01 0.0000
137 OH- 0.56280E-05 -5.2496 0.26264E-05 -5.5806 0.46666E+00 -0.3310
140 PbCl+ 0.84553E-07 -7.0729 0.45042E-07 -7.3464 0.53271E+00 -0.2735
141 PbCl2,aq 0.43281E-06 -6.3637 0.43281E-06 -6.3637 0.10000E+01 0.0000
142 PbCl3- 0.38691E-06 -6.4124 0.19412E-06 -6.7119 0.50171E+00 -0.2995
143 PbCl4-2 0.64994E-06 -6.1871 0.24543E-07 -7.6101 0.37762E-01 -1.4229
144 PbF+ 0.11491E-09 -9.9397 0.61211E-10 -10.2132 0.53271E+00 -0.2735
146 PbO,aq 0.11175E-09 -9.9518 0.11175E-09 -9.9518 0.10000E+01 0.0000
148 Pb(HS)2,aq 0.27106E-09 -9.5669 0.27106E-09 -9.5669 0.10000E+01 0.0000
150 H2S,aq 0.12159E-04 -4.9151 0.11225E-04 -4.9498 0.92316E+00 -0.0347
158 HSO3- 0.36166E-09 -9.4417 0.18145E-09 -9.7412 0.50171E+00 -0.2995
159 HSO4- 0.68460E-06 -6.1646 0.37147E-06 -6.4301 0.54261E+00 -0.2655
161 S2O3-2 0.28337E-10 -10.5476 0.10701E-11 -11.9706 0.37762E-01 -1.4229
173 ZnCl+ 0.53607E-05 -5.2708 0.28557E-05 -5.5443 0.53271E+00 -0.2735
174 ZnCl2,aq 0.15291E-05 -5.8156 0.15291E-05 -5.8156 0.10000E+01 0.0000
175 ZnCl3- 0.22223E-06 -6.6532 0.11150E-06 -6.9527 0.50171E+00 -0.2995
176 ZnF+ 0.10609E-09 -9.9743 0.56515E-10 -10.2478 0.53271E+00 -0.2735
177 ZnO,aq 0.65681E-09 -9.1826 0.65681E-09 -9.1826 0.10000E+01 0.0000
178 ZnOH+ 0.31765E-06 -6.4981 0.16921E-06 -6.7716 0.53271E+00 -0.2735
Charge balance for all species = -.1293E-03
Total fraction of mixing solution added: 0.0000000
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.300
AFFINITY: 0.7643E+03
GOLD Q/K: 0.0177
SILVER Q/K: 0.2081
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 199.9700 deg.C
Sat. pressure: 100.3665 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.2676E+00 0.6367 0.1710E+02 0.2686E+02
CO2,gas 0.7323E+00 0.9068 0.6665E+02 0.7350E+02
CH4,gas 0.2420E-07 1.1419 0.2773E-05 0.2429E-05
H2,gas 0.3267E-05 1.0430 0.3420E-03 0.3279E-03
H2S,gas 0.7333E-05 0.8305 0.6112E-03 0.7360E-03
S2,gas 0.1431E-15 1.0000 0.1436E-13 0.1436E-13
CO,gas 0.5622E-07 1.0000 0.5643E-05 0.5643E-05
SO3,gas 0.1817E-25 1.0000 0.1823E-23 0.1823E-23
O2,gas 0.4724E-04 1.0000 0.4741E-02 0.4741E-02
SO2,gas 0.7910E-12 1.0000 0.7939E-10 0.7939E-10
HF,gas 0.5124E-07 1.0000 0.5143E-05 0.5143E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
122 paragonite -3.40 -2.28 1.12 0.066 -0.24282E+04
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.44 -0.02 -1.47 -1.466 0.31735E+04 1.233
2 CO2,gas -6.49 -7.36 -0.88 -0.292 0.18946E+04 1.824
3 CH4,gas 5.50 -2.76 -8.26 -2.064 0.17874E+05 -5.557
4 H2,gas 7.31 1.14 -6.16 -3.523 0.13347E+05 -3.466
5 H2S,gas -5.67 -11.59 -5.91 -2.956 0.12801E+05 -3.214
6 S2,gas -8.91 -25.45 -16.54 -2.545 0.35812E+05 -13.843
7 CO,gas 1.74 -6.20 -7.95 -2.445 0.17206E+05 -5.249
8 SO3,gas 10.22 -16.21 -26.44 -6.610 0.57236E+05 -23.739
9 O2,gas 36.93 -2.32 -39.25 -26.166 0.84972E+05 -36.550
10 SO2,gas -2.25 -15.05 -12.80 -3.413 0.27709E+05 -10.100
11 HF,gas -0.77 -8.76 -7.99 -3.994 0.17293E+05 -5.289
12 HCl,gas 3.42 -5.75 -9.16 -4.582 0.19839E+05 -9.164
13 acmite 5.98 3.29 -2.69 -0.280 0.58268E+04
17 albite-high -1.58 -2.25 -0.67 -0.051 0.14422E+04
18 albite -2.25 -2.25 0.00 0.000 0.23300E+01
22 analcite 0.78 0.24 -0.54 -0.060 0.11671E+04
23 andalusite -1.42 -2.52 -1.10 -0.110 0.23872E+04
26 anhydrite -6.83 -9.55 -2.72 -1.361 0.58932E+04
27 ankerite -4.15 -4.47 -0.32 -0.054 0.70102E+03
28 annite 11.91 7.12 -4.78 -0.266 0.10349E+05
29 phlogopite 17.57 13.14 -4.43 -0.246 0.95889E+04
31 anorthite 4.24 1.63 -2.61 -0.201 0.56535E+04
34 aragonite -0.17 -0.71 -0.53 -0.178 0.11554E+04
35 brucite 9.50 5.58 -3.92 -0.784 0.84873E+04
36 calcite -0.31 -0.71 -0.39 -0.131 0.85235E+03
37 carnegieite-low 5.15 2.77 -2.38 -0.340 0.51458E+04
38 carnegieite-high 5.83 2.77 -3.05 -0.436 0.66051E+04
39 carpholite-Mg 1.63 0.53 -1.10 -0.073 0.23855E+04
40 carpholite-Fe 0.10 -1.47 -1.57 -0.105 0.34069E+04
41 celadonite 2.39 -0.58 -2.97 -0.175 0.64331E+04
42 celadonite-Fe 1.07 -2.59 -3.66 -0.215 0.79265E+04
45 clinochlore 23.38 20.39 -2.99 -0.093 0.64647E+04
46 daphnite 15.14 10.38 -4.76 -0.149 0.10309E+05
49 chloritoid-Mg 4.76 3.06 -1.70 -0.113 0.36842E+04
50 chloritoid-Fe 1.65 1.06 -0.59 -0.039 0.12826E+04
51 chloritoid-Mn 3.84 1.84 -2.00 -0.134 0.43366E+04
53 coesite -1.83 -2.51 -0.69 -0.229 0.14845E+04
58 corundum 1.19 -0.01 -1.20 -0.109 0.26066E+04
60 cristobalite -2.02 -2.51 -0.49 -0.163 0.10558E+04
63 cymrite-K -0.29 -3.68 -3.39 -0.282 0.73336E+04
65 diaspore -0.10 -0.02 0.08 0.013 -0.17280E+03
66 diamond -2.12 -5.04 -2.92 -0.835 0.63294E+04
67 diopside 11.80 7.24 -4.56 -0.456 0.98744E+04
68 hedenbergite 10.17 5.24 -4.93 -0.493 0.10684E+05
69 dolomite,ordered -1.96 -2.47 -0.51 -0.084 0.10934E+04
70 eastonite 14.03 10.03 -4.00 -0.154 0.86530E+04
75 epidote 13.04 8.78 -4.25 -0.206 0.92011E+04
76 clinozoisite 9.75 5.76 -3.99 -0.181 0.86363E+04
78 fayalite 9.33 4.69 -4.64 -0.663 0.10040E+05
79 ferrosilite 7.10 2.18 -4.92 -0.492 0.10659E+05
83 gibbsite 1.16 -0.04 -1.20 -0.172 0.25997E+04
86 goethite 4.38 3.01 -1.38 -0.297 0.29772E+04
87 graphite -2.50 -5.04 -2.54 -0.725 0.54938E+04
90 halite 1.35 -0.45 -1.80 -0.899 0.38928E+04
91 hematite 8.11 6.04 -2.07 -0.251 0.44746E+04
92 heulandite -9.13 -11.06 -1.93 -0.088 0.41811E+04
93 hercynite 7.24 3.59 -3.65 -0.244 0.79118E+04
96 jadeite 1.60 0.26 -1.34 -0.134 0.28975E+04
98 kalsilite 4.14 1.36 -2.77 -0.396 0.60044E+04
99 kaolinite -5.32 -5.08 0.25 0.023 -0.53861E+03
100 kyanite -1.45 -2.52 -1.07 -0.107 0.23178E+04
102 laumontite -2.02 -3.48 -1.46 -0.097 0.31583E+04
103 lawsonite 3.12 1.58 -1.54 -0.102 0.33236E+04
104 leucite 1.26 -1.15 -2.41 -0.241 0.52114E+04
107 magnesite -0.92 -1.76 -0.84 -0.281 0.18281E+04
108 magnetite 13.11 9.64 -3.47 -0.283 0.75086E+04
114 margarite 3.15 1.59 -1.55 -0.062 0.33615E+04
117 microcline -3.65 -3.66 -0.01 -0.001 0.23007E+02
120 mullite-Si 0.26 -2.52 -2.78 -0.278 0.60224E+04
121 muscovite -4.54 -3.69 0.85 0.050 -0.18467E+04
123 nepheline 4.57 2.77 -1.80 -0.257 0.38966E+04
129 periclase-Fe 8.23 3.60 -4.63 -1.158 0.10029E+05
130 perovskite-Al 4.31 -0.01 -4.32 -0.393 0.93486E+04
135 phlogopite-Na 19.37 14.55 -4.82 -0.268 0.10445E+05
137 prehnite 10.01 5.75 -4.26 -0.250 0.92193E+04
142 px-Ca-tschermaks 9.05 4.14 -4.91 -0.351 0.10634E+05
143 pyrite -19.23 -20.69 -1.47 -0.345 0.31729E+04
144 pyrrhotite -5.01 -7.96 -2.95 -0.983 0.63868E+04
145 pyrrhotiteFe0.875 -6.33 -8.56 -2.23 -0.819 0.48218E+04
146 pyroxmangite 5.39 1.87 -3.52 -0.704 0.76223E+04
147 pyrophyllite -9.51 -10.08 -0.57 -0.035 0.12255E+04
148 quartz -2.32 -2.51 -0.20 -0.065 0.42360E+03
153 rhodochrosite -1.85 -2.98 -1.13 -0.378 0.24524E+04
154 rhodonite 5.42 1.87 -3.54 -0.709 0.76743E+04
155 sanidine -2.69 -3.66 -0.97 -0.074 0.20906E+04
157 siderite -3.54 -3.76 -0.23 -0.075 0.48734E+03
158 sillimanite -1.25 -2.52 -1.27 -0.127 0.27488E+04
160 spinel 10.16 5.59 -4.56 -0.304 0.98760E+04
165 stilbite -8.82 -11.08 -2.26 -0.108 0.48894E+04
166 stilpnomelane-Fe 3.87 -0.29 -4.16 -0.124 0.90026E+04
168 stishovite 2.33 -2.51 -4.84 -1.615 0.10487E+05
169 sudoite-Fe 3.77 -0.44 -4.21 -0.136 0.91185E+04
170 sudoite 6.08 3.57 -2.51 -0.081 0.54411E+04
171 sulfur -8.49 -12.73 -4.24 -1.303 0.91684E+04
172 sylvite 1.39 -1.86 -3.24 -1.622 0.70226E+04
173 talc 11.30 6.75 -4.55 -0.268 0.98551E+04
175 talc-tschermaks 8.61 3.64 -4.96 -0.292 0.10749E+05
180 topaz-H -0.99 -2.54 -1.55 -0.141 0.33602E+04
181 tridymite -2.05 -2.51 -0.46 -0.153 0.99305E+03
184 troilite-low -5.07 -7.96 -2.89 -0.964 0.62612E+04
190 wairakite -1.87 -3.44 -1.57 -0.093 0.34049E+04
191 walstromite 8.87 4.15 -4.72 -0.944 0.10222E+05
192 wollastonite 8.07 4.15 -3.92 -0.784 0.84817E+04
193 pseudo-wollastonite 8.44 4.15 -4.29 -0.858 0.92893E+04
194 zoisite 9.79 5.76 -4.03 -0.183 0.87185E+04
196 argentite -21.92 -22.42 -0.50 -0.126 0.10913E+04
197 arsenic -5.41 -9.59 -4.18 -1.080 0.90599E+04
199 arsenopyrite -13.34 -17.56 -4.21 -0.749 0.91161E+04
200 beidellite-Ca -6.93 -8.15 -1.22 -0.076 0.26498E+04
201 beidellite-H -7.37 -9.25 -1.89 -0.120 0.40816E+04
202 beidellite-K -6.46 -7.97 -1.51 -0.092 0.32692E+04
203 beidellite-Mg -7.17 -8.32 -1.16 -0.071 0.25005E+04
204 beidellite-Na -6.38 -7.50 -1.12 -0.069 0.24310E+04
205 bornite -71.94 -73.86 -1.92 -0.144 0.41603E+04
207 chalcedony -2.17 -2.51 -0.34 -0.114 0.74187E+03
208 chalcocite -21.89 -23.81 -1.92 -0.481 0.41641E+04
210 covellite -16.15 -18.27 -2.12 -0.808 0.45920E+04
211 dawsonite -0.24 -2.10 -1.86 -0.233 0.40359E+04
213 montmorillonite-Ca -5.92 -7.13 -1.20 -0.074 0.26039E+04
214 montmorillonite-K -5.56 -6.94 -1.38 -0.085 0.29960E+04
215 montmorillonite-Mg -6.16 -7.30 -1.14 -0.070 0.24633E+04
216 montmorillonite-Na -5.40 -6.48 -1.08 -0.066 0.23331E+04
217 nontronite-Ca 0.53 -2.10 -2.62 -0.170 0.56826E+04
218 nontronite-H 0.08 -3.20 -3.28 -0.220 0.71057E+04
219 nontronite-K 0.99 -1.92 -2.91 -0.187 0.62998E+04
220 nontronite-Mg 0.31 -2.27 -2.58 -0.168 0.55961E+04
221 nontronite-Na 1.07 -1.45 -2.52 -0.162 0.54659E+04
225 topaz -20.54 -20.01 0.53 0.059 -0.11453E+04
229 gypsum -5.82 -9.60 -3.78 -0.944 0.81776E+04
245 acanthite -21.75 -22.42 -0.68 -0.169 0.14637E+04
251 barite -9.75 -12.45 -2.71 -1.353 0.58577E+04
252 boehmite 0.94 -0.02 -0.96 -0.160 0.20790E+04
253 cerussite -2.86 -5.95 -3.09 -1.030 0.66903E+04
254 chalcopyrite -24.63 -26.23 -1.60 -0.298 0.34726E+04
256 copper,native -1.52 -5.54 -4.03 -1.401 0.87192E+04
257 dolomite,disordered -1.54 -2.47 -0.93 -0.155 0.20136E+04
258 ferrous-oxide 6.76 3.60 -3.16 -0.790 0.68446E+04
259 fluorite -10.33 -10.83 -0.50 -0.166 0.10790E+04
260 galena -10.17 -10.15 0.02 0.008 -0.49976E+02
261 gold,native -13.31 -15.06 -1.75 -0.609 0.37911E+04
262 silver,native -4.17 -4.85 -0.68 -0.237 0.14757E+04
263 huntite -2.48 -5.99 -3.51 -0.292 0.75966E+04
269 silica-amorphous -1.67 -2.51 -0.84 -0.281 0.18266E+04
270 smithsonite -1.93 -5.53 -3.60 -1.201 0.77985E+04
272 sphalerite -9.71 -9.73 -0.03 -0.009 0.55926E+02
273 wurtzite -8.26 -9.73 -1.47 -0.490 0.31801E+04
274 zincite 5.67 1.83 -3.84 -0.961 0.83208E+04
275 an20ab80 -1.17 -1.47 -0.31 -0.024 0.66148E+03
276 an25ab75 -0.87 -1.28 -0.41 -0.032 0.88742E+03
277 an30ab70 -0.57 -1.09 -0.52 -0.040 0.11242E+04
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 9 Loop limit = 70
Temperature = 199.97 C Pressure = 500.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5564E+02 kg liquid = 0.1002E+01
Moles total = 0.5532E+02 kg total = 0.9966E+00 Activity = 0.9513
Stoichiometric ionic strength = .1744195E+01 Osmotic coef. = 0.8983
True ionic strength = .1230110E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.63513E-05 -5.1971 0.29703E-05 -5.5272 0.46766E+00 -0.3301
2 H2O 0.95132E+00 -0.0217 0.95132E+00 -0.0217
3 Cl- 0.12006E+01 0.0794 0.60234E+00 -0.2202 0.50171E+00 -0.2995
4 SO4-- 0.16704E-03 -3.7772 0.66000E-05 -5.1805 0.39511E-01 -1.4033
5 HCO3- 0.26394E-01 -1.5785 0.13823E-01 -1.8594 0.52371E+00 -0.2809
6 HS- 0.17300E-05 -5.7620 0.87206E-06 -6.0595 0.50408E+00 -0.2975
7 H4SiO4 0.27901E-02 -2.5544 0.27901E-02 -2.5544 0.10000E+01 0.0000
8 Al+++ 0.22144E-13 -13.6547 0.11794E-16 -16.9283 0.53261E-03 -3.2736
9 Ca++ 0.12334E-02 -2.9089 0.42355E-04 -4.3731 0.34341E-01 -1.4642
10 Mg++ 0.12190E-03 -3.9140 0.37353E-05 -5.4277 0.30642E-01 -1.5137
11 Fe++ 0.11741E-05 -5.9303 0.37022E-07 -7.4315 0.31533E-01 -1.5012
12 K+ 0.43675E-01 -1.3598 0.23144E-01 -1.6356 0.52991E+00 -0.2758
13 Na+ 0.11812E+01 0.0723 0.59449E+00 -0.2259 0.50329E+00 -0.2982
14 Mn++ 0.69483E-05 -5.1581 0.22376E-06 -6.6502 0.32203E-01 -1.4921
15 Zn++ 0.19937E-07 -7.7003 0.62867E-09 -9.2016 0.31533E-01 -1.5012
16 Cu+ 0.45563E-11 -11.3414 0.22896E-11 -11.6402 0.50251E+00 -0.2989
17 Pb++ 0.65771E-08 -8.1820 0.24157E-09 -9.6170 0.36729E-01 -1.4350
18 Ag+ 0.21641E-10 -10.6647 0.11360E-10 -10.9446 0.52494E+00 -0.2799
19 Au+ 0.12994E-20 -20.8862 0.69221E-21 -21.1598 0.53271E+00 -0.2735
20 Ba++ 0.13913E-05 -5.8566 0.53334E-07 -7.2730 0.38335E-01 -1.4164
21 F- 0.12829E-02 -2.8918 0.59020E-03 -3.2290 0.46006E+00 -0.3372
22 H2AsO3- 0.21325E-05 -5.6711 0.14466E-05 -5.8397 0.67834E+00 -0.1686
24 HSiO3- 0.40467E-05 -5.3929 0.20303E-05 -5.6924 0.50171E+00 -0.2995
25 Ca(HSiO3)+ 0.21168E-07 -7.6743 0.11276E-07 -7.9478 0.53271E+00 -0.2735
26 Mg(HSiO3)+ 0.15529E-08 -8.8089 0.82725E-09 -9.0824 0.53271E+00 -0.2735
27 NaHSiO3,aq 0.94559E-05 -5.0243 0.94559E-05 -5.0243 0.10000E+01 0.0000
31 AgCl,aq 0.39553E-08 -8.4028 0.39553E-08 -8.4028 0.10000E+01 0.0000
32 AgCl2- 0.20537E-06 -6.6875 0.10303E-06 -6.9870 0.50171E+00 -0.2995
33 AgCl3-2 0.17013E-06 -6.7692 0.64245E-08 -8.1922 0.37762E-01 -1.4229
34 AgCl4-3 0.41335E-07 -7.3837 0.21023E-10 -10.6773 0.50860E-03 -3.2936
38 Ag(HS),aq 0.52908E-08 -8.2765 0.52908E-08 -8.2765 0.10000E+01 0.0000
40 AlO+ 0.15284E-09 -9.8158 0.81420E-10 -10.0893 0.53271E+00 -0.2735
42 HAlO2,aq 0.54084E-07 -7.2669 0.54084E-07 -7.2669 0.10000E+01 0.0000
43 AlO2- 0.96165E-06 -6.0170 0.44876E-06 -6.3480 0.46666E+00 -0.3310
44 AsO2- 0.29430E-06 -6.5312 0.14766E-06 -6.8307 0.50171E+00 -0.2995
45 HAsO2,aq 0.31556E-04 -4.5009 0.31556E-04 -4.5009 0.10000E+01 0.0000
46 H3AsO3,aq 0.95348E-04 -4.0207 0.95348E-04 -4.0207 0.10000E+01 0.0000
48 H2AsO4- 0.17613E-09 -9.7542 0.88364E-10 -10.0537 0.50171E+00 -0.2995
49 HAsO4-2 0.49961E-10 -10.3014 0.18866E-11 -11.7243 0.37762E-01 -1.4229
62 BaCO3,aq 0.57491E-09 -9.2404 0.57491E-09 -9.2404 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.17350E-05 -5.7607 0.94665E-06 -6.0238 0.54562E+00 -0.2631
64 BaCl+ 0.92688E-06 -6.0330 0.49376E-06 -6.3065 0.53271E+00 -0.2735
65 BaF+ 0.97323E-09 -9.0118 0.51845E-09 -9.2853 0.53271E+00 -0.2735
66 CH4,aq 0.20588E-08 -8.6864 0.19006E-08 -8.7211 0.92316E+00 -0.0347
71 CO,aq 0.54996E-08 -8.2597 0.54996E-08 -8.2597 0.10000E+01 0.0000
72 CO2,aq 0.32247E+00 -0.4915 0.29769E+00 -0.5262 0.92316E+00 -0.0347
73 CO3-2 0.79419E-05 -5.1001 0.29990E-06 -6.5230 0.37762E-01 -1.4229
74 CaCO3,aq 0.18134E-05 -5.7415 0.18134E-05 -5.7415 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.20031E-03 -3.6983 0.10670E-03 -3.9718 0.53271E+00 -0.2735
76 CaCl+ 0.60109E-03 -3.2211 0.32021E-03 -3.4946 0.53271E+00 -0.2735
77 CaCl2,aq 0.57169E-04 -4.2428 0.57169E-04 -4.2428 0.10000E+01 0.0000
78 CaF+ 0.56897E-05 -5.2449 0.30309E-05 -5.5184 0.53271E+00 -0.2735
79 CaOH+ 0.26573E-06 -6.5756 0.14155E-06 -6.8491 0.53271E+00 -0.2735
80 CaSO4,aq 0.45412E-06 -6.3428 0.45412E-06 -6.3428 0.10000E+01 0.0000
81 HCl,aq 0.12718E-05 -5.8956 0.12718E-05 -5.8956 0.10000E+01 0.0000
90 CuCl,aq 0.66157E-08 -8.1794 0.66157E-08 -8.1794 0.10000E+01 0.0000
91 CuCl2- 0.13030E-06 -6.8850 0.65374E-07 -7.1846 0.50171E+00 -0.2995
92 CuCl3-2 0.32829E-07 -7.4837 0.12397E-08 -8.9067 0.37762E-01 -1.4229
98 HF,aq 0.85801E-04 -4.0665 0.85801E-04 -4.0665 0.10000E+01 0.0000
99 HF2- 0.27737E-07 -7.5569 0.13916E-07 -7.8565 0.50171E+00 -0.2995
101 FeCl+ 0.38065E-06 -6.4195 0.20278E-06 -6.6930 0.53271E+00 -0.2735
102 FeCl2,aq 0.67921E-08 -8.1680 0.67921E-08 -8.1680 0.10000E+01 0.0000
104 FeF+ 0.92837E-08 -8.0323 0.49455E-08 -8.3058 0.53271E+00 -0.2735
106 FeO,aq 0.31727E-09 -9.4986 0.31727E-09 -9.4986 0.10000E+01 0.0000
107 FeOH+ 0.28063E-07 -7.5519 0.14950E-07 -7.8254 0.53271E+00 -0.2735
108 HFeO2- 0.10481E-10 -10.9796 0.52585E-11 -11.2791 0.50171E+00 -0.2995
111 FeO2- 0.29449E-10 -10.5309 0.14775E-10 -10.8305 0.50171E+00 -0.2995
112 HFeO2,aq 0.22575E-09 -9.6464 0.22575E-09 -9.6464 0.10000E+01 0.0000
113 H2,aq 0.39504E-06 -6.4034 0.36469E-06 -6.4381 0.92316E+00 -0.0347
114 KCl,aq 0.16520E-02 -2.7820 0.16520E-02 -2.7820 0.10000E+01 0.0000
115 KHSO4,aq 0.33729E-09 -9.4720 0.33729E-09 -9.4720 0.10000E+01 0.0000
116 KOH,aq 0.91136E-07 -7.0403 0.91136E-07 -7.0403 0.10000E+01 0.0000
117 KSO4- 0.20105E-04 -4.6967 0.10087E-04 -4.9962 0.50171E+00 -0.2995
118 MgCO3,aq 0.21134E-07 -7.6750 0.21134E-07 -7.6750 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.16948E-04 -4.7709 0.90284E-05 -5.0444 0.53271E+00 -0.2735
120 MgCl+ 0.30932E-04 -4.5096 0.16478E-04 -4.7831 0.53271E+00 -0.2735
121 MgF+ 0.14775E-05 -5.8305 0.78707E-06 -6.1040 0.53271E+00 -0.2735
122 MgOH+ 0.80701E-07 -7.0931 0.42990E-07 -7.3666 0.53271E+00 -0.2735
124 MnF+ 0.22751E-07 -7.6430 0.12120E-07 -7.9165 0.53271E+00 -0.2735
125 MnO,aq 0.59944E-10 -10.2223 0.59944E-10 -10.2223 0.10000E+01 0.0000
126 MnOH+ 0.22669E-07 -7.6446 0.12076E-07 -7.9181 0.53271E+00 -0.2735
131 MnCl+ 0.27398E-04 -4.5623 0.14595E-04 -4.8358 0.53271E+00 -0.2735
132 MnSO4,aq 0.28380E-08 -8.5470 0.28380E-08 -8.5470 0.10000E+01 0.0000
133 NaCl,aq 0.33870E+00 -0.4702 0.33870E+00 -0.4702 0.10000E+01 0.0000
134 NaF,aq 0.25059E-03 -3.6010 0.25059E-03 -3.6010 0.10000E+01 0.0000
135 NaOH,aq 0.16727E-05 -5.7766 0.16727E-05 -5.7766 0.10000E+01 0.0000
137 OH- 0.56282E-05 -5.2496 0.26265E-05 -5.5806 0.46666E+00 -0.3310
140 PbCl+ 0.84553E-07 -7.0729 0.45042E-07 -7.3464 0.53271E+00 -0.2735
141 PbCl2,aq 0.43281E-06 -6.3637 0.43281E-06 -6.3637 0.10000E+01 0.0000
142 PbCl3- 0.38691E-06 -6.4124 0.19412E-06 -6.7119 0.50171E+00 -0.2995
143 PbCl4-2 0.64994E-06 -6.1871 0.24543E-07 -7.6101 0.37762E-01 -1.4229
144 PbF+ 0.11491E-09 -9.9397 0.61211E-10 -10.2132 0.53271E+00 -0.2735
146 PbO,aq 0.11175E-09 -9.9517 0.11175E-09 -9.9517 0.10000E+01 0.0000
148 Pb(HS)2,aq 0.27107E-09 -9.5669 0.27107E-09 -9.5669 0.10000E+01 0.0000
150 H2S,aq 0.12159E-04 -4.9151 0.11224E-04 -4.9498 0.92316E+00 -0.0347
158 HSO3- 0.36165E-09 -9.4417 0.18144E-09 -9.7413 0.50171E+00 -0.2995
159 HSO4- 0.68458E-06 -6.1646 0.37146E-06 -6.4301 0.54261E+00 -0.2655
161 S2O3-2 0.28337E-10 -10.5476 0.10700E-11 -11.9706 0.37762E-01 -1.4229
173 ZnCl+ 0.53607E-05 -5.2708 0.28557E-05 -5.5443 0.53271E+00 -0.2735
174 ZnCl2,aq 0.15291E-05 -5.8156 0.15291E-05 -5.8156 0.10000E+01 0.0000
175 ZnCl3- 0.22223E-06 -6.6532 0.11150E-06 -6.9527 0.50171E+00 -0.2995
176 ZnF+ 0.10609E-09 -9.9743 0.56515E-10 -10.2478 0.53271E+00 -0.2735
177 ZnO,aq 0.65686E-09 -9.1825 0.65686E-09 -9.1825 0.10000E+01 0.0000
178 ZnOH+ 0.31766E-06 -6.4980 0.16922E-06 -6.7716 0.53271E+00 -0.2735
Charge balance for all species = -.1293E-03
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.6351315E-05 0.3226674E+00 0.2936290E+03 0.0000
2 H2O 0.1000000E+01 0.5518575E+02 0.8975892E+06 0.0000
3 Cl- 0.1200569E+01 0.1541709E+01 0.4934745E+05 5.3070
4 SO4-- 0.1670438E-03 0.1881888E-03 0.1632122E+02 5.8740
5 HCO3- 0.2639386E-01 0.3490923E+00 0.1923100E+05 3.6678
6 HS- 0.1729995E-05 0.1399680E-04 0.4179252E+00 -0.5323
7 H4SiO4 0.2790115E-02 0.2803640E-02 0.2432901E+03 -2.5544
8 Al+++ 0.2214427E-13 0.1015889E-05 0.2474695E-01 -0.3467
9 Ca++ 0.1233382E-02 0.2100196E-02 0.7599325E+02 6.6813
10 Mg++ 0.1219012E-03 0.1713622E-03 0.3761360E+01 5.6267
11 Fe++ 0.1174096E-05 0.1599476E-05 0.8064674E-01 3.6229
12 K+ 0.4367533E-01 0.4534756E-01 0.1600892E+04 3.8916
13 Na+ 0.1181201E+01 0.1520159E+01 0.3155247E+05 5.3013
14 Mn++ 0.6948269E-05 0.3439479E-04 0.1705983E+01 4.4042
15 Zn++ 0.1993722E-07 0.7450341E-05 0.4397075E+00 1.8528
16 Cu+ 0.4556341E-11 0.1697508E-06 0.9737964E-02 -6.1130
17 Pb++ 0.6577074E-08 0.1561283E-05 0.2920516E+00 1.4374
18 Ag+ 0.2164090E-10 0.4261080E-06 0.4149823E-01 -5.4174
19 Au+ 0.1299426E-20 0.3103531E-11 0.5518980E-06 -15.6326
20 Ba++ 0.1391255E-05 0.4054694E-05 0.5027641E+00 3.7814
21 F- 0.1282861E-02 0.1626506E-02 0.2789799E+02 2.2982
22 H2AsO3- 0.2132473E-05 0.1293304E-03 0.1458802E+02 -0.3125
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234398E+00 -.4629859E-05 0.0000000E+00
2 H2O 0.5531785E+02 0.5531785E+02 0.0000000E+00 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1403031E-04 0.0000000E+00 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810352E-02 0.1388958E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.1018321E-05 0.1388958E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.4629859E-06 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.7468176E-05 0.0000000E+00 0.0000000E+00
16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00
17 Pb++ 0.1565021E-05 0.1565021E-05 0.0000000E+00 0.0000000E+00
18 Ag+ 0.4271281E-06 0.4271281E-06 0.0000000E+00 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1630400E-02 0.0000000E+00 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: -.3706E-21 Mass of aqueous solution: 0.111027E+04 g
Temperature = 199.97 C Pressure = 500.00 bar Mixer frac. = 0.0000000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
paragonite 0.4630E-06 -6.334 0.1770E-03 -3.752 100.0 0.6117E-04
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
paragonite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.0000000
Solid products produced: Mass = 0.000177 g Volume = 0.000061 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.300
AFFINITY: 0.7642E+03
GOLD Q/K: 0.0177
SILVER Q/K: 0.2081
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 199.9700 deg.C
Sat. pressure: 100.3663 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.2676E+00 0.6367 0.1710E+02 0.2686E+02
CO2,gas 0.7323E+00 0.9068 0.6665E+02 0.7350E+02
CH4,gas 0.2420E-07 1.1419 0.2773E-05 0.2429E-05
H2,gas 0.3267E-05 1.0430 0.3420E-03 0.3279E-03
H2S,gas 0.7333E-05 0.8305 0.6112E-03 0.7360E-03
S2,gas 0.1431E-15 1.0000 0.1436E-13 0.1436E-13
CO,gas 0.5622E-07 1.0000 0.5643E-05 0.5643E-05
SO3,gas 0.1816E-25 1.0000 0.1823E-23 0.1823E-23
O2,gas 0.4724E-04 1.0000 0.4741E-02 0.4741E-02
SO2,gas 0.7910E-12 1.0000 0.7939E-10 0.7939E-10
HF,gas 0.5124E-07 1.0000 0.5143E-05 0.5143E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
122 paragonite -3.40 -3.40 0.00 0.000 -0.22113E-10
260 galena -10.17 -10.15 0.02 0.008 -0.50037E+02
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.44 -0.02 -1.47 -1.466 0.31735E+04 1.233
2 CO2,gas -6.49 -7.36 -0.88 -0.292 0.18946E+04 1.824
3 CH4,gas 5.50 -2.76 -8.26 -2.064 0.17873E+05 -5.557
4 H2,gas 7.31 1.14 -6.16 -3.523 0.13347E+05 -3.466
5 H2S,gas -5.67 -11.59 -5.91 -2.956 0.12801E+05 -3.214
6 S2,gas -8.91 -25.45 -16.54 -2.545 0.35812E+05 -13.843
7 CO,gas 1.74 -6.20 -7.95 -2.445 0.17206E+05 -5.249
8 SO3,gas 10.22 -16.21 -26.44 -6.610 0.57237E+05 -23.739
9 O2,gas 36.93 -2.32 -39.25 -26.166 0.84972E+05 -36.550
10 SO2,gas -2.25 -15.05 -12.80 -3.413 0.27709E+05 -10.100
11 HF,gas -0.77 -8.76 -7.99 -3.994 0.17293E+05 -5.289
12 HCl,gas 3.42 -5.75 -9.16 -4.582 0.19839E+05 -9.164
13 acmite 5.98 3.29 -2.69 -0.280 0.58276E+04
17 albite-high -1.58 -2.62 -1.04 -0.080 0.22525E+04
18 albite -2.25 -2.62 -0.38 -0.029 0.81263E+03
22 analcite 0.78 -0.13 -0.91 -0.101 0.19769E+04
23 andalusite -1.42 -3.27 -1.85 -0.185 0.40055E+04
26 anhydrite -6.83 -9.55 -2.72 -1.361 0.58932E+04
27 ankerite -4.15 -4.47 -0.32 -0.054 0.70089E+03
29 phlogopite 17.57 12.76 -4.80 -0.267 0.10399E+05
31 anorthite 4.24 0.88 -3.36 -0.258 0.72722E+04
34 aragonite -0.17 -0.71 -0.53 -0.178 0.11554E+04
35 brucite 9.50 5.58 -3.92 -0.784 0.84872E+04
36 calcite -0.31 -0.71 -0.39 -0.131 0.85229E+03
37 carnegieite-low 5.15 2.40 -2.75 -0.393 0.59552E+04
38 carnegieite-high 5.83 2.40 -3.42 -0.489 0.74145E+04
39 carpholite-Mg 1.63 -0.22 -1.85 -0.123 0.40043E+04
40 carpholite-Fe 0.10 -2.22 -2.32 -0.155 0.50257E+04
41 celadonite 2.39 -0.96 -3.35 -0.197 0.72438E+04
42 celadonite-Fe 1.07 -2.96 -4.04 -0.237 0.87372E+04
45 clinochlore 23.38 19.65 -3.73 -0.117 0.80836E+04
49 chloritoid-Mg 4.76 2.31 -2.45 -0.163 0.53025E+04
50 chloritoid-Fe 1.65 0.31 -1.34 -0.089 0.29008E+04
51 chloritoid-Mn 3.84 1.09 -2.75 -0.183 0.59549E+04
53 coesite -1.83 -2.51 -0.69 -0.229 0.14849E+04
58 corundum 1.19 -0.76 -1.95 -0.177 0.42245E+04
60 cristobalite -2.02 -2.51 -0.49 -0.163 0.10563E+04
63 cymrite-K -0.29 -4.05 -3.76 -0.313 0.81439E+04
65 diaspore -0.10 -0.39 -0.29 -0.049 0.63614E+03
66 diamond -2.12 -5.04 -2.92 -0.835 0.63294E+04
67 diopside 11.80 7.24 -4.56 -0.456 0.98752E+04
68 hedenbergite 10.17 5.24 -4.94 -0.494 0.10684E+05
69 dolomite,ordered -1.96 -2.47 -0.50 -0.084 0.10933E+04
75 epidote 13.04 8.04 -5.00 -0.242 0.10820E+05
78 fayalite 9.33 4.69 -4.64 -0.663 0.10041E+05
79 ferrosilite 7.10 2.18 -4.92 -0.492 0.10659E+05
83 gibbsite 1.16 -0.41 -1.57 -0.225 0.34086E+04
86 goethite 4.38 3.01 -1.38 -0.297 0.29772E+04
87 graphite -2.50 -5.04 -2.54 -0.725 0.54937E+04
90 halite 1.35 -0.45 -1.80 -0.899 0.38928E+04
91 hematite 8.11 6.04 -2.07 -0.251 0.44745E+04
92 heulandite -9.13 -11.81 -2.68 -0.122 0.58022E+04
93 hercynite 7.24 2.84 -4.40 -0.293 0.95296E+04
96 jadeite 1.60 -0.11 -1.71 -0.171 0.37074E+04
98 kalsilite 4.14 0.99 -3.15 -0.450 0.68138E+04
99 kaolinite -5.32 -5.82 -0.50 -0.045 0.10802E+04
100 kyanite -1.45 -3.27 -1.82 -0.182 0.39362E+04
102 laumontite -2.02 -4.23 -2.21 -0.147 0.47780E+04
103 lawsonite 3.12 0.84 -2.28 -0.152 0.49423E+04
104 leucite 1.26 -1.52 -2.78 -0.278 0.60212E+04
107 magnesite -0.92 -1.76 -0.84 -0.281 0.18280E+04
108 magnetite 13.11 9.64 -3.47 -0.283 0.75085E+04
114 margarite 3.15 0.10 -3.05 -0.122 0.65981E+04
117 microcline -3.65 -4.03 -0.38 -0.030 0.83330E+03
120 mullite-Si 0.26 -3.27 -3.53 -0.353 0.76407E+04
121 muscovite -4.54 -4.81 -0.27 -0.016 0.58149E+03
123 nepheline 4.57 2.40 -2.17 -0.311 0.47059E+04
129 periclase-Fe 8.23 3.60 -4.63 -1.158 0.10029E+05
143 pyrite -19.23 -20.69 -1.47 -0.345 0.31729E+04
144 pyrrhotite -5.01 -7.96 -2.95 -0.983 0.63867E+04
145 pyrrhotiteFe0.875 -6.33 -8.56 -2.23 -0.819 0.48218E+04
146 pyroxmangite 5.39 1.87 -3.52 -0.704 0.76227E+04
147 pyrophyllite -9.51 -10.82 -1.31 -0.082 0.28452E+04
148 quartz -2.32 -2.51 -0.20 -0.065 0.42407E+03
153 rhodochrosite -1.85 -2.98 -1.13 -0.378 0.24523E+04
154 rhodonite 5.42 1.87 -3.55 -0.709 0.76747E+04
155 sanidine -2.69 -4.03 -1.34 -0.103 0.29009E+04
157 siderite -3.54 -3.76 -0.23 -0.075 0.48728E+03
158 sillimanite -1.25 -3.27 -2.02 -0.202 0.43671E+04
165 stilbite -8.82 -11.83 -3.01 -0.143 0.65105E+04
166 stilpnomelane-Fe 3.87 -1.04 -4.91 -0.146 0.10624E+05
168 stishovite 2.33 -2.51 -4.84 -1.615 0.10487E+05
170 sudoite 6.08 2.07 -4.01 -0.129 0.86781E+04
171 sulfur -8.49 -12.73 -4.24 -1.303 0.91685E+04
172 sylvite 1.39 -1.86 -3.24 -1.622 0.70226E+04
173 talc 11.30 6.75 -4.55 -0.268 0.98568E+04
180 topaz-H -0.99 -3.29 -2.30 -0.209 0.49785E+04
181 tridymite -2.05 -2.51 -0.46 -0.153 0.99352E+03
184 troilite-low -5.07 -7.96 -2.89 -0.964 0.62611E+04
190 wairakite -1.87 -4.19 -2.32 -0.137 0.50246E+04
191 walstromite 8.87 4.15 -4.72 -0.944 0.10223E+05
192 wollastonite 8.07 4.15 -3.92 -0.784 0.84822E+04
193 pseudo-wollastonite 8.44 4.15 -4.29 -0.858 0.92897E+04
196 argentite -21.92 -22.42 -0.50 -0.126 0.10913E+04
197 arsenic -5.41 -9.59 -4.18 -1.080 0.90599E+04
199 arsenopyrite -13.34 -17.56 -4.21 -0.749 0.91160E+04
200 beidellite-Ca -6.93 -9.02 -2.10 -0.130 0.45364E+04
201 beidellite-H -7.37 -10.12 -2.76 -0.176 0.59681E+04
202 beidellite-K -6.46 -8.84 -2.38 -0.146 0.51557E+04
203 beidellite-Mg -7.17 -9.20 -2.03 -0.125 0.43870E+04
204 beidellite-Na -6.38 -8.37 -1.99 -0.122 0.43175E+04
205 bornite -71.94 -73.86 -1.92 -0.144 0.41601E+04
207 chalcedony -2.17 -2.51 -0.34 -0.114 0.74233E+03
208 chalcocite -21.89 -23.81 -1.92 -0.481 0.41640E+04
210 covellite -16.15 -18.27 -2.12 -0.808 0.45920E+04
211 dawsonite -0.24 -2.48 -2.24 -0.280 0.48448E+04
213 montmorillonite-Ca -5.92 -7.75 -1.83 -0.113 0.39567E+04
214 montmorillonite-K -5.56 -7.57 -2.01 -0.123 0.43488E+04
215 montmorillonite-Mg -6.16 -7.92 -1.76 -0.109 0.38160E+04
216 montmorillonite-Na -5.40 -7.10 -1.70 -0.104 0.36859E+04
217 nontronite-Ca 0.53 -2.22 -2.75 -0.178 0.59512E+04
218 nontronite-H 0.08 -3.33 -3.41 -0.228 0.73743E+04
219 nontronite-K 0.99 -2.04 -3.03 -0.195 0.65683E+04
220 nontronite-Mg 0.31 -2.40 -2.71 -0.176 0.58646E+04
221 nontronite-Na 1.07 -1.58 -2.65 -0.170 0.57345E+04
225 topaz -20.54 -20.76 -0.22 -0.024 0.47311E+03
229 gypsum -5.82 -9.60 -3.78 -0.944 0.81776E+04
245 acanthite -21.75 -22.42 -0.68 -0.169 0.14637E+04
251 barite -9.75 -12.45 -2.71 -1.353 0.58577E+04
252 boehmite 0.94 -0.39 -1.33 -0.222 0.28879E+04
253 cerussite -2.86 -5.95 -3.09 -1.030 0.66902E+04
254 chalcopyrite -24.63 -26.23 -1.60 -0.298 0.34725E+04
256 copper,native -1.52 -5.54 -4.03 -1.401 0.87191E+04
257 dolomite,disordered -1.54 -2.47 -0.93 -0.155 0.20135E+04
258 ferrous-oxide 6.76 3.60 -3.16 -0.790 0.68445E+04
259 fluorite -10.33 -10.83 -0.50 -0.166 0.10790E+04
261 gold,native -13.31 -15.06 -1.75 -0.609 0.37911E+04
262 silver,native -4.17 -4.85 -0.68 -0.237 0.14757E+04
263 huntite -2.48 -5.98 -3.51 -0.292 0.75964E+04
269 silica-amorphous -1.67 -2.51 -0.84 -0.281 0.18271E+04
270 smithsonite -1.93 -5.53 -3.60 -1.201 0.77984E+04
272 sphalerite -9.71 -9.73 -0.03 -0.009 0.55866E+02
273 wurtzite -8.26 -9.73 -1.47 -0.490 0.31800E+04
274 zincite 5.67 1.83 -3.84 -0.961 0.83208E+04
275 an20ab80 -1.17 -1.92 -0.75 -0.058 0.16335E+04
276 an25ab75 -0.87 -1.75 -0.88 -0.068 0.18998E+04
277 an30ab70 -0.57 -1.57 -1.01 -0.077 0.21770E+04
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 70
Temperature = 199.97 C Pressure = 500.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5564E+02 kg liquid = 0.1002E+01
Moles total = 0.5532E+02 kg total = 0.9966E+00 Activity = 0.9513
Stoichiometric ionic strength = .1744195E+01 Osmotic coef. = 0.8983
True ionic strength = .1230110E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.63514E-05 -5.1971 0.29703E-05 -5.5272 0.46766E+00 -0.3301
2 H2O 0.95132E+00 -0.0217 0.95132E+00 -0.0217
3 Cl- 0.12006E+01 0.0794 0.60234E+00 -0.2202 0.50171E+00 -0.2995
4 SO4-- 0.16704E-03 -3.7772 0.66000E-05 -5.1805 0.39511E-01 -1.4033
5 HCO3- 0.26394E-01 -1.5785 0.13823E-01 -1.8594 0.52371E+00 -0.2809
6 HS- 0.17209E-05 -5.7642 0.86747E-06 -6.0617 0.50408E+00 -0.2975
7 H4SiO4 0.27901E-02 -2.5544 0.27901E-02 -2.5544 0.10000E+01 0.0000
8 Al+++ 0.22145E-13 -13.6547 0.11795E-16 -16.9283 0.53261E-03 -3.2736
9 Ca++ 0.12334E-02 -2.9089 0.42355E-04 -4.3731 0.34341E-01 -1.4642
10 Mg++ 0.12190E-03 -3.9140 0.37353E-05 -5.4277 0.30642E-01 -1.5137
11 Fe++ 0.11741E-05 -5.9303 0.37022E-07 -7.4315 0.31533E-01 -1.5012
12 K+ 0.43675E-01 -1.3598 0.23144E-01 -1.6356 0.52991E+00 -0.2758
13 Na+ 0.11812E+01 0.0723 0.59449E+00 -0.2259 0.50329E+00 -0.2982
14 Mn++ 0.69483E-05 -5.1581 0.22376E-06 -6.6502 0.32203E-01 -1.4921
15 Zn++ 0.19937E-07 -7.7003 0.62867E-09 -9.2016 0.31533E-01 -1.5012
16 Cu+ 0.45563E-11 -11.3414 0.22896E-11 -11.6402 0.50251E+00 -0.2989
17 Pb++ 0.62692E-08 -8.2028 0.23026E-09 -9.6378 0.36729E-01 -1.4350
18 Ag+ 0.21642E-10 -10.6647 0.11361E-10 -10.9446 0.52494E+00 -0.2799
19 Au+ 0.13061E-20 -20.8840 0.69577E-21 -21.1575 0.53271E+00 -0.2735
20 Ba++ 0.13913E-05 -5.8566 0.53334E-07 -7.2730 0.38335E-01 -1.4164
21 F- 0.12829E-02 -2.8918 0.59020E-03 -3.2290 0.46006E+00 -0.3372
22 H2AsO3- 0.21325E-05 -5.6711 0.14465E-05 -5.8397 0.67834E+00 -0.1686
24 HSiO3- 0.40466E-05 -5.3929 0.20302E-05 -5.6925 0.50171E+00 -0.2995
25 Ca(HSiO3)+ 0.21168E-07 -7.6743 0.11276E-07 -7.9478 0.53271E+00 -0.2735
26 Mg(HSiO3)+ 0.15529E-08 -8.8089 0.82725E-09 -9.0824 0.53271E+00 -0.2735
27 NaHSiO3,aq 0.94558E-05 -5.0243 0.94558E-05 -5.0243 0.10000E+01 0.0000
31 AgCl,aq 0.39556E-08 -8.4028 0.39556E-08 -8.4028 0.10000E+01 0.0000
32 AgCl2- 0.20538E-06 -6.6874 0.10304E-06 -6.9870 0.50171E+00 -0.2995
33 AgCl3-2 0.17014E-06 -6.7692 0.64249E-08 -8.1921 0.37762E-01 -1.4229
34 AgCl4-3 0.41338E-07 -7.3837 0.21025E-10 -10.6773 0.50860E-03 -3.2936
38 Ag(HS),aq 0.52634E-08 -8.2787 0.52634E-08 -8.2787 0.10000E+01 0.0000
40 AlO+ 0.15284E-09 -9.8158 0.81421E-10 -10.0893 0.53271E+00 -0.2735
42 HAlO2,aq 0.54084E-07 -7.2669 0.54084E-07 -7.2669 0.10000E+01 0.0000
43 AlO2- 0.96165E-06 -6.0170 0.44876E-06 -6.3480 0.46666E+00 -0.3310
44 AsO2- 0.29430E-06 -6.5312 0.14765E-06 -6.8308 0.50171E+00 -0.2995
45 HAsO2,aq 0.31556E-04 -4.5009 0.31556E-04 -4.5009 0.10000E+01 0.0000
46 H3AsO3,aq 0.95348E-04 -4.0207 0.95348E-04 -4.0207 0.10000E+01 0.0000
48 H2AsO4- 0.17636E-09 -9.7536 0.88480E-10 -10.0532 0.50171E+00 -0.2995
49 HAsO4-2 0.50026E-10 -10.3008 0.18891E-11 -11.7238 0.37762E-01 -1.4229
62 BaCO3,aq 0.57490E-09 -9.2404 0.57490E-09 -9.2404 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.17350E-05 -5.7607 0.94665E-06 -6.0238 0.54562E+00 -0.2631
64 BaCl+ 0.92688E-06 -6.0330 0.49376E-06 -6.3065 0.53271E+00 -0.2735
65 BaF+ 0.97324E-09 -9.0118 0.51845E-09 -9.2853 0.53271E+00 -0.2735
66 CH4,aq 0.20479E-08 -8.6887 0.18906E-08 -8.7234 0.92316E+00 -0.0347
71 CO,aq 0.54924E-08 -8.2602 0.54924E-08 -8.2602 0.10000E+01 0.0000
72 CO2,aq 0.32247E+00 -0.4915 0.29769E+00 -0.5262 0.92316E+00 -0.0347
73 CO3-2 0.79418E-05 -5.1001 0.29989E-06 -6.5230 0.37762E-01 -1.4229
74 CaCO3,aq 0.18134E-05 -5.7415 0.18134E-05 -5.7415 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.20031E-03 -3.6983 0.10670E-03 -3.9718 0.53271E+00 -0.2735
76 CaCl+ 0.60109E-03 -3.2211 0.32021E-03 -3.4946 0.53271E+00 -0.2735
77 CaCl2,aq 0.57169E-04 -4.2428 0.57169E-04 -4.2428 0.10000E+01 0.0000
78 CaF+ 0.56897E-05 -5.2449 0.30309E-05 -5.5184 0.53271E+00 -0.2735
79 CaOH+ 0.26573E-06 -6.5756 0.14155E-06 -6.8491 0.53271E+00 -0.2735
80 CaSO4,aq 0.45412E-06 -6.3428 0.45412E-06 -6.3428 0.10000E+01 0.0000
81 HCl,aq 0.12718E-05 -5.8956 0.12718E-05 -5.8956 0.10000E+01 0.0000
90 CuCl,aq 0.66157E-08 -8.1794 0.66157E-08 -8.1794 0.10000E+01 0.0000
91 CuCl2- 0.13030E-06 -6.8850 0.65374E-07 -7.1846 0.50171E+00 -0.2995
92 CuCl3-2 0.32829E-07 -7.4837 0.12397E-08 -8.9067 0.37762E-01 -1.4229
98 HF,aq 0.85802E-04 -4.0665 0.85802E-04 -4.0665 0.10000E+01 0.0000
99 HF2- 0.27737E-07 -7.5569 0.13916E-07 -7.8565 0.50171E+00 -0.2995
101 FeCl+ 0.38065E-06 -6.4195 0.20278E-06 -6.6930 0.53271E+00 -0.2735
102 FeCl2,aq 0.67922E-08 -8.1680 0.67922E-08 -8.1680 0.10000E+01 0.0000
104 FeF+ 0.92837E-08 -8.0323 0.49455E-08 -8.3058 0.53271E+00 -0.2735
106 FeO,aq 0.31727E-09 -9.4986 0.31727E-09 -9.4986 0.10000E+01 0.0000
107 FeOH+ 0.28063E-07 -7.5519 0.14950E-07 -7.8254 0.53271E+00 -0.2735
108 HFeO2- 0.10481E-10 -10.9796 0.52584E-11 -11.2791 0.50171E+00 -0.2995
111 FeO2- 0.29468E-10 -10.5307 0.14784E-10 -10.8302 0.50171E+00 -0.2995
112 HFeO2,aq 0.22590E-09 -9.6461 0.22590E-09 -9.6461 0.10000E+01 0.0000
113 H2,aq 0.39452E-06 -6.4039 0.36421E-06 -6.4387 0.92316E+00 -0.0347
114 KCl,aq 0.16520E-02 -2.7820 0.16520E-02 -2.7820 0.10000E+01 0.0000
115 KHSO4,aq 0.33729E-09 -9.4720 0.33729E-09 -9.4720 0.10000E+01 0.0000
116 KOH,aq 0.91135E-07 -7.0403 0.91135E-07 -7.0403 0.10000E+01 0.0000
117 KSO4- 0.20105E-04 -4.6967 0.10087E-04 -4.9962 0.50171E+00 -0.2995
118 MgCO3,aq 0.21134E-07 -7.6750 0.21134E-07 -7.6750 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.16948E-04 -4.7709 0.90284E-05 -5.0444 0.53271E+00 -0.2735
120 MgCl+ 0.30932E-04 -4.5096 0.16478E-04 -4.7831 0.53271E+00 -0.2735
121 MgF+ 0.14775E-05 -5.8305 0.78708E-06 -6.1040 0.53271E+00 -0.2735
122 MgOH+ 0.80701E-07 -7.0931 0.42990E-07 -7.3666 0.53271E+00 -0.2735
124 MnF+ 0.22751E-07 -7.6430 0.12120E-07 -7.9165 0.53271E+00 -0.2735
125 MnO,aq 0.59944E-10 -10.2223 0.59944E-10 -10.2223 0.10000E+01 0.0000
126 MnOH+ 0.22669E-07 -7.6446 0.12076E-07 -7.9181 0.53271E+00 -0.2735
131 MnCl+ 0.27398E-04 -4.5623 0.14595E-04 -4.8358 0.53271E+00 -0.2735
132 MnSO4,aq 0.28380E-08 -8.5470 0.28380E-08 -8.5470 0.10000E+01 0.0000
133 NaCl,aq 0.33870E+00 -0.4702 0.33870E+00 -0.4702 0.10000E+01 0.0000
134 NaF,aq 0.25059E-03 -3.6010 0.25059E-03 -3.6010 0.10000E+01 0.0000
135 NaOH,aq 0.16727E-05 -5.7766 0.16727E-05 -5.7766 0.10000E+01 0.0000
137 OH- 0.56282E-05 -5.2496 0.26265E-05 -5.5806 0.46666E+00 -0.3310
140 PbCl+ 0.80595E-07 -7.0937 0.42933E-07 -7.3672 0.53271E+00 -0.2735
141 PbCl2,aq 0.41255E-06 -6.3845 0.41255E-06 -6.3845 0.10000E+01 0.0000
142 PbCl3- 0.36880E-06 -6.4332 0.18503E-06 -6.7328 0.50171E+00 -0.2995
143 PbCl4-2 0.61951E-06 -6.2080 0.23394E-07 -7.6309 0.37762E-01 -1.4229
144 PbF+ 0.10953E-09 -9.9605 0.58346E-10 -10.2340 0.53271E+00 -0.2735
146 PbO,aq 0.10652E-09 -9.9726 0.10652E-09 -9.9726 0.10000E+01 0.0000
148 Pb(HS)2,aq 0.25568E-09 -9.5923 0.25568E-09 -9.5923 0.10000E+01 0.0000
150 H2S,aq 0.12095E-04 -4.9174 0.11166E-04 -4.9521 0.92316E+00 -0.0347
158 HSO3- 0.36118E-09 -9.4423 0.18121E-09 -9.7418 0.50171E+00 -0.2995
159 HSO4- 0.68458E-06 -6.1646 0.37146E-06 -6.4301 0.54261E+00 -0.2655
161 S2O3-2 0.28188E-10 -10.5499 0.10644E-11 -11.9729 0.37762E-01 -1.4229
173 ZnCl+ 0.53607E-05 -5.2708 0.28557E-05 -5.5443 0.53271E+00 -0.2735
174 ZnCl2,aq 0.15291E-05 -5.8156 0.15291E-05 -5.8156 0.10000E+01 0.0000
175 ZnCl3- 0.22223E-06 -6.6532 0.11150E-06 -6.9527 0.50171E+00 -0.2995
176 ZnF+ 0.10609E-09 -9.9743 0.56515E-10 -10.2478 0.53271E+00 -0.2735
177 ZnO,aq 0.65685E-09 -9.1825 0.65685E-09 -9.1825 0.10000E+01 0.0000
178 ZnOH+ 0.31766E-06 -6.4980 0.16922E-06 -6.7716 0.53271E+00 -0.2735
Charge balance for all species = -.1293E-03
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.6351350E-05 0.3226674E+00 0.2936291E+03 0.0000
2 H2O 0.1000000E+01 0.5518575E+02 0.8975892E+06 0.0000
3 Cl- 0.1200569E+01 0.1541709E+01 0.4934745E+05 5.3070
4 SO4-- 0.1670436E-03 0.1881888E-03 0.1632122E+02 5.8739
5 HCO3- 0.2639373E-01 0.3490923E+00 0.1923100E+05 3.6678
6 HS- 0.1720908E-05 0.1392371E-04 0.4157427E+00 -0.5345
7 H4SiO4 0.2790115E-02 0.2803640E-02 0.2432901E+03 -2.5544
8 Al+++ 0.2214467E-13 0.1015886E-05 0.2474686E-01 -0.3467
9 Ca++ 0.1233383E-02 0.2100196E-02 0.7599326E+02 6.6813
10 Mg++ 0.1219012E-03 0.1713622E-03 0.3761360E+01 5.6267
11 Fe++ 0.1174096E-05 0.1599476E-05 0.8064674E-01 3.6229
12 K+ 0.4367533E-01 0.4534756E-01 0.1600892E+04 3.8916
13 Na+ 0.1181201E+01 0.1520159E+01 0.3155247E+05 5.3013
14 Mn++ 0.6948267E-05 0.3439479E-04 0.1705983E+01 4.4042
15 Zn++ 0.1993722E-07 0.7450341E-05 0.4397075E+00 1.8528
16 Cu+ 0.4556340E-11 0.1697508E-06 0.9737964E-02 -6.1130
17 Pb++ 0.6269166E-08 0.1488189E-05 0.2783788E+00 1.4166
18 Ag+ 0.2164231E-10 0.4261080E-06 0.4149824E-01 -5.4174
19 Au+ 0.1306100E-20 0.3103531E-11 0.5518980E-06 -15.6303
20 Ba++ 0.1391258E-05 0.4054694E-05 0.5027641E+00 3.7814
21 F- 0.1282860E-02 0.1626506E-02 0.2789799E+02 2.2982
22 H2AsO3- 0.2132462E-05 0.1293304E-03 0.1458802E+02 -0.3125
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234399E+00 -.4703140E-05 0.0000000E+00
2 H2O 0.5531785E+02 0.5531785E+02 0.0000000E+00 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1395704E-04 0.7326883E-07 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810352E-02 0.1388961E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.1018318E-05 0.1388961E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.4629871E-06 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.7468176E-05 0.0000000E+00 0.0000000E+00
16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00
17 Pb++ 0.1565021E-05 0.1491752E-05 0.7326883E-07 0.0000000E+00
18 Ag+ 0.4271281E-06 0.4271281E-06 0.0000000E+00 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1630400E-02 0.0000000E+00 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: 0.1323E-21 Mass of aqueous solution: 0.111027E+04 g
Temperature = 199.97 C Pressure = 500.00 bar Mixer frac. = 0.0000000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
paragonite 0.4630E-06 -6.334 0.1770E-03 -3.752 90.99 0.6117E-04
galena 0.7327E-07 -7.135 0.1753E-04 -4.756 9.013 0.2307E-05
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
paragonite 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.0000000
Solid products produced: Mass = 0.000194 g Volume = 0.000063 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.300
AFFINITY: 0.7634E+03
GOLD Q/K: 0.0178
SILVER Q/K: 0.2080
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 199.9700 deg.C
Sat. pressure: 100.3663 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.2676E+00 0.6367 0.1710E+02 0.2686E+02
CO2,gas 0.7323E+00 0.9068 0.6665E+02 0.7350E+02
CH4,gas 0.2407E-07 1.1419 0.2759E-05 0.2416E-05
H2,gas 0.3263E-05 1.0430 0.3416E-03 0.3275E-03
H2S,gas 0.7294E-05 0.8305 0.6080E-03 0.7321E-03
S2,gas 0.1419E-15 1.0000 0.1425E-13 0.1425E-13
CO,gas 0.5615E-07 1.0000 0.5635E-05 0.5635E-05
SO3,gas 0.1816E-25 1.0000 0.1823E-23 0.1823E-23
O2,gas 0.4736E-04 1.0000 0.4754E-02 0.4754E-02
SO2,gas 0.7900E-12 1.0000 0.7929E-10 0.7929E-10
HF,gas 0.5124E-07 1.0000 0.5143E-05 0.5143E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
122 paragonite -3.40 -3.40 0.00 0.000 0.86528E-11
260 galena -10.17 -10.17 0.00 0.000 0.00000E+00
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.44 -0.02 -1.47 -1.466 0.31735E+04 1.233
2 CO2,gas -6.49 -7.36 -0.88 -0.292 0.18946E+04 1.824
3 CH4,gas 5.50 -2.76 -8.26 -2.065 0.17878E+05 -5.559
4 H2,gas 7.31 1.14 -6.17 -3.523 0.13348E+05 -3.467
5 H2S,gas -5.67 -11.59 -5.92 -2.958 0.12806E+05 -3.216
6 S2,gas -8.91 -25.46 -16.55 -2.545 0.35819E+05 -13.846
7 CO,gas 1.74 -6.20 -7.95 -2.446 0.17207E+05 -5.249
8 SO3,gas 10.22 -16.21 -26.44 -6.610 0.57236E+05 -23.739
9 O2,gas 36.93 -2.32 -39.25 -26.165 0.84969E+05 -36.549
10 SO2,gas -2.25 -15.05 -12.80 -3.413 0.27710E+05 -10.101
11 HF,gas -0.77 -8.76 -7.99 -3.994 0.17293E+05 -5.289
12 HCl,gas 3.42 -5.75 -9.16 -4.582 0.19839E+05 -9.164
13 acmite 5.98 3.29 -2.69 -0.280 0.58270E+04
17 albite-high -1.58 -2.62 -1.04 -0.080 0.22525E+04
18 albite -2.25 -2.62 -0.38 -0.029 0.81263E+03
22 analcite 0.78 -0.13 -0.91 -0.101 0.19769E+04
23 andalusite -1.42 -3.27 -1.85 -0.185 0.40055E+04
26 anhydrite -6.83 -9.55 -2.72 -1.361 0.58932E+04
27 ankerite -4.15 -4.47 -0.32 -0.054 0.70091E+03
29 phlogopite 17.57 12.76 -4.80 -0.267 0.10399E+05
31 anorthite 4.24 0.88 -3.36 -0.258 0.72722E+04
34 aragonite -0.17 -0.71 -0.53 -0.178 0.11554E+04
35 brucite 9.50 5.58 -3.92 -0.784 0.84872E+04
36 calcite -0.31 -0.71 -0.39 -0.131 0.85230E+03
37 carnegieite-low 5.15 2.40 -2.75 -0.393 0.59552E+04
38 carnegieite-high 5.83 2.40 -3.42 -0.489 0.74145E+04
39 carpholite-Mg 1.63 -0.22 -1.85 -0.123 0.40043E+04
40 carpholite-Fe 0.10 -2.22 -2.32 -0.155 0.50257E+04
41 celadonite 2.39 -0.96 -3.35 -0.197 0.72438E+04
42 celadonite-Fe 1.07 -2.96 -4.04 -0.237 0.87372E+04
45 clinochlore 23.38 19.65 -3.73 -0.117 0.80837E+04
49 chloritoid-Mg 4.76 2.31 -2.45 -0.163 0.53025E+04
50 chloritoid-Fe 1.65 0.31 -1.34 -0.089 0.29008E+04
51 chloritoid-Mn 3.84 1.09 -2.75 -0.183 0.59549E+04
53 coesite -1.83 -2.51 -0.69 -0.229 0.14849E+04
58 corundum 1.19 -0.76 -1.95 -0.177 0.42245E+04
60 cristobalite -2.02 -2.51 -0.49 -0.163 0.10563E+04
63 cymrite-K -0.29 -4.05 -3.76 -0.313 0.81439E+04
65 diaspore -0.10 -0.39 -0.29 -0.049 0.63614E+03
66 diamond -2.12 -5.04 -2.92 -0.836 0.63319E+04
67 diopside 11.80 7.24 -4.56 -0.456 0.98752E+04
68 hedenbergite 10.17 5.24 -4.94 -0.494 0.10684E+05
69 dolomite,ordered -1.96 -2.47 -0.51 -0.084 0.10933E+04
75 epidote 13.04 8.04 -5.00 -0.242 0.10820E+05
78 fayalite 9.33 4.69 -4.64 -0.663 0.10041E+05
79 ferrosilite 7.10 2.18 -4.92 -0.492 0.10659E+05
83 gibbsite 1.16 -0.41 -1.57 -0.225 0.34086E+04
86 goethite 4.38 3.01 -1.37 -0.297 0.29765E+04
87 graphite -2.50 -5.04 -2.54 -0.725 0.54962E+04
90 halite 1.35 -0.45 -1.80 -0.899 0.38928E+04
91 hematite 8.11 6.04 -2.07 -0.250 0.44733E+04
92 heulandite -9.13 -11.81 -2.68 -0.122 0.58022E+04
93 hercynite 7.24 2.84 -4.40 -0.293 0.95296E+04
96 jadeite 1.60 -0.11 -1.71 -0.171 0.37074E+04
98 kalsilite 4.14 0.99 -3.15 -0.450 0.68138E+04
99 kaolinite -5.32 -5.82 -0.50 -0.045 0.10802E+04
100 kyanite -1.45 -3.27 -1.82 -0.182 0.39362E+04
102 laumontite -2.02 -4.23 -2.21 -0.147 0.47780E+04
103 lawsonite 3.12 0.84 -2.28 -0.152 0.49424E+04
104 leucite 1.26 -1.52 -2.78 -0.278 0.60212E+04
107 magnesite -0.92 -1.76 -0.84 -0.281 0.18280E+04
108 magnetite 13.11 9.64 -3.47 -0.283 0.75072E+04
114 margarite 3.15 0.10 -3.05 -0.122 0.65981E+04
117 microcline -3.65 -4.03 -0.38 -0.030 0.83331E+03
120 mullite-Si 0.26 -3.27 -3.53 -0.353 0.76407E+04
121 muscovite -4.54 -4.81 -0.27 -0.016 0.58149E+03
123 nepheline 4.57 2.40 -2.17 -0.311 0.47059E+04
129 periclase-Fe 8.23 3.60 -4.63 -1.158 0.10029E+05
143 pyrite -19.23 -20.69 -1.47 -0.346 0.31815E+04
144 pyrrhotite -5.01 -7.97 -2.95 -0.984 0.63917E+04
145 pyrrhotiteFe0.875 -6.33 -8.56 -2.23 -0.820 0.48266E+04
146 pyroxmangite 5.39 1.87 -3.52 -0.704 0.76227E+04
147 pyrophyllite -9.51 -10.82 -1.31 -0.082 0.28452E+04
148 quartz -2.32 -2.51 -0.20 -0.065 0.42407E+03
153 rhodochrosite -1.85 -2.98 -1.13 -0.378 0.24523E+04
154 rhodonite 5.42 1.87 -3.55 -0.709 0.76747E+04
155 sanidine -2.69 -4.03 -1.34 -0.103 0.29009E+04
157 siderite -3.54 -3.76 -0.23 -0.075 0.48729E+03
158 sillimanite -1.25 -3.27 -2.02 -0.202 0.43671E+04
165 stilbite -8.82 -11.83 -3.01 -0.143 0.65105E+04
166 stilpnomelane-Fe 3.87 -1.04 -4.91 -0.146 0.10624E+05
168 stishovite 2.33 -2.51 -4.84 -1.615 0.10487E+05
170 sudoite 6.08 2.07 -4.01 -0.129 0.86781E+04
171 sulfur -8.49 -12.73 -4.24 -1.304 0.91722E+04
172 sylvite 1.39 -1.86 -3.24 -1.622 0.70225E+04
173 talc 11.30 6.75 -4.55 -0.268 0.98568E+04
180 topaz-H -0.99 -3.29 -2.30 -0.209 0.49785E+04
181 tridymite -2.05 -2.51 -0.46 -0.153 0.99352E+03
184 troilite-low -5.07 -7.97 -2.89 -0.965 0.62661E+04
190 wairakite -1.87 -4.19 -2.32 -0.137 0.50246E+04
191 walstromite 8.87 4.15 -4.72 -0.944 0.10223E+05
192 wollastonite 8.07 4.15 -3.92 -0.784 0.84822E+04
193 pseudo-wollastonite 8.44 4.15 -4.29 -0.858 0.92898E+04
196 argentite -21.92 -22.42 -0.51 -0.127 0.10961E+04
197 arsenic -5.41 -9.59 -4.19 -1.080 0.90617E+04
199 arsenopyrite -13.34 -17.56 -4.21 -0.749 0.91228E+04
200 beidellite-Ca -6.93 -9.02 -2.10 -0.130 0.45363E+04
201 beidellite-H -7.37 -10.12 -2.76 -0.176 0.59681E+04
202 beidellite-K -6.46 -8.84 -2.38 -0.146 0.51557E+04
203 beidellite-Mg -7.17 -9.20 -2.03 -0.125 0.43870E+04
204 beidellite-Na -6.38 -8.37 -1.99 -0.122 0.43175E+04
205 bornite -71.94 -73.87 -1.93 -0.144 0.41793E+04
207 chalcedony -2.17 -2.51 -0.34 -0.114 0.74233E+03
208 chalcocite -21.89 -23.82 -1.93 -0.481 0.41690E+04
210 covellite -16.15 -18.27 -2.12 -0.809 0.45963E+04
211 dawsonite -0.24 -2.48 -2.24 -0.280 0.48448E+04
213 montmorillonite-Ca -5.92 -7.75 -1.83 -0.113 0.39567E+04
214 montmorillonite-K -5.56 -7.57 -2.01 -0.123 0.43488E+04
215 montmorillonite-Mg -6.16 -7.92 -1.76 -0.109 0.38160E+04
216 montmorillonite-Na -5.40 -7.10 -1.70 -0.104 0.36859E+04
217 nontronite-Ca 0.53 -2.22 -2.75 -0.178 0.59499E+04
218 nontronite-H 0.08 -3.32 -3.41 -0.228 0.73731E+04
219 nontronite-K 0.99 -2.04 -3.03 -0.195 0.65671E+04
220 nontronite-Mg 0.31 -2.40 -2.71 -0.176 0.58634E+04
221 nontronite-Na 1.07 -1.58 -2.65 -0.170 0.57332E+04
225 topaz -20.54 -20.76 -0.22 -0.024 0.47309E+03
229 gypsum -5.82 -9.60 -3.78 -0.944 0.81776E+04
245 acanthite -21.75 -22.42 -0.68 -0.170 0.14685E+04
251 barite -9.75 -12.45 -2.71 -1.353 0.58577E+04
252 boehmite 0.94 -0.39 -1.33 -0.222 0.28879E+04
253 cerussite -2.86 -5.97 -3.11 -1.037 0.67353E+04
254 chalcopyrite -24.63 -26.24 -1.61 -0.299 0.34818E+04
256 copper,native -1.52 -5.54 -4.03 -1.401 0.87198E+04
257 dolomite,disordered -1.54 -2.47 -0.93 -0.155 0.20135E+04
258 ferrous-oxide 6.76 3.60 -3.16 -0.790 0.68445E+04
259 fluorite -10.33 -10.83 -0.50 -0.166 0.10790E+04
261 gold,native -13.31 -15.06 -1.75 -0.608 0.37869E+04
262 silver,native -4.17 -4.85 -0.68 -0.237 0.14762E+04
263 huntite -2.48 -5.98 -3.51 -0.292 0.75964E+04
269 silica-amorphous -1.67 -2.51 -0.84 -0.281 0.18271E+04
270 smithsonite -1.93 -5.53 -3.60 -1.201 0.77984E+04
272 sphalerite -9.71 -9.74 -0.03 -0.009 0.60823E+02
273 wurtzite -8.26 -9.74 -1.47 -0.490 0.31850E+04
274 zincite 5.67 1.83 -3.84 -0.961 0.83208E+04
275 an20ab80 -1.17 -1.92 -0.75 -0.058 0.16335E+04
276 an25ab75 -0.87 -1.75 -0.88 -0.068 0.18998E+04
277 an30ab70 -0.57 -1.57 -1.01 -0.077 0.21770E+04
Calculations done for 199.9700 Deg. C; 500.0000 bar
Mixer fraction: 0.0000000
Temperature Stoc.ionic strength Heat per mole
Actual solution: 199.970 .17442E+01 3.768
Mixing solution: 25.000 .50000E-10 0.646
Fract. of mixing solution added: 0.050000
BITMOL = 0.2775E+01 OLDMOL = 0.5706E+02
New heat: 3.623 New temperature: 192.085
New mixer fraction: 0.0500000
Resulting temperature: 192.085Deg. C
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1296E-03
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 8 Loop limit = 70
Temperature = 192.08 C Pressure = 500.00 bar Mixer fraction = 0.0500000
Water: Moles liquid = 0.5842E+02 kg liquid = 0.1052E+01
Moles total = 0.5809E+02 kg total = 0.1047E+01 Activity = 0.9533
Stoichiometric ionic strength = .1660864E+01 Osmotic coef. = 0.9046
True ionic strength = .1193297E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.71525E-05 -5.1455 0.34501E-05 -5.4622 0.48237E+00 -0.3166
2 H2O 0.95326E+00 -0.0208 0.95326E+00 -0.0208
3 Cl- 0.11651E+01 0.0664 0.59880E+00 -0.2227 0.51396E+00 -0.2891
4 SO4-- 0.16022E-03 -3.7953 0.71046E-05 -5.1485 0.44342E-01 -1.3532
5 HCO3- 0.25162E-01 -1.5992 0.13443E-01 -1.8715 0.53426E+00 -0.2722
6 HS- 0.14976E-05 -5.8246 0.77295E-06 -6.1119 0.51614E+00 -0.2872
7 H4SiO4 0.26589E-02 -2.5753 0.26589E-02 -2.5753 0.10000E+01 0.0000
8 Al+++ 0.44329E-13 -13.3533 0.31209E-16 -16.5057 0.70404E-03 -3.1524
9 Ca++ 0.12219E-02 -2.9130 0.47514E-04 -4.3232 0.38886E-01 -1.4102
10 Mg++ 0.11822E-03 -3.9273 0.41439E-05 -5.3826 0.35054E-01 -1.4553
11 Fe++ 0.11418E-05 -5.9424 0.41080E-07 -7.3864 0.35977E-01 -1.4440
12 K+ 0.41808E-01 -1.3787 0.22563E-01 -1.6466 0.53968E+00 -0.2679
13 Na+ 0.11464E+01 0.0593 0.59038E+00 -0.2289 0.51499E+00 -0.2882
14 Mn++ 0.73761E-05 -5.1322 0.27050E-06 -6.5678 0.36672E-01 -1.4357
15 Zn++ 0.24339E-07 -7.6137 0.87566E-09 -9.0577 0.35977E-01 -1.4440
16 Cu+ 0.45403E-11 -11.3429 0.23349E-11 -11.6317 0.51427E+00 -0.2888
17 Pb++ 0.59033E-08 -8.2289 0.24415E-09 -9.6123 0.41359E-01 -1.3834
18 Ag+ 0.23151E-10 -10.6354 0.12387E-10 -10.9070 0.53506E+00 -0.2716
19 Au+ 0.84764E-21 -21.0718 0.45967E-21 -21.3376 0.54229E+00 -0.2658
20 Ba++ 0.14608E-05 -5.8354 0.62844E-07 -7.2017 0.43021E-01 -1.3663
21 F- 0.12368E-02 -2.9077 0.58884E-03 -3.2300 0.47609E+00 -0.3223
22 H2AsO3- 0.15445E-05 -5.8112 0.10498E-05 -5.9789 0.67972E+00 -0.1677
24 HSiO3- 0.33207E-05 -5.4788 0.17067E-05 -5.7678 0.51396E+00 -0.2891
25 Ca(HSiO3)+ 0.16547E-07 -7.7813 0.89734E-08 -8.0470 0.54229E+00 -0.2658
26 Mg(HSiO3)+ 0.12377E-08 -8.9074 0.67119E-09 -9.1732 0.54229E+00 -0.2658
27 NaHSiO3,aq 0.79542E-05 -5.0994 0.79542E-05 -5.0994 0.10000E+01 0.0000
31 AgCl,aq 0.41905E-08 -8.3777 0.41905E-08 -8.3777 0.10000E+01 0.0000
32 AgCl2- 0.20618E-06 -6.6858 0.10597E-06 -6.9748 0.51396E+00 -0.2891
33 AgCl3-2 0.15594E-06 -6.8070 0.66335E-08 -8.1783 0.42538E-01 -1.3712
34 AgCl4-3 0.32130E-07 -7.4931 0.21867E-10 -10.6602 0.68058E-03 -3.1671
38 Ag(HS),aq 0.73898E-08 -8.1314 0.73898E-08 -8.1314 0.10000E+01 0.0000
40 AlO+ 0.19469E-09 -9.7106 0.10558E-09 -9.9764 0.54229E+00 -0.2658
42 HAlO2,aq 0.53446E-07 -7.2721 0.53446E-07 -7.2721 0.10000E+01 0.0000
43 AlO2- 0.67779E-06 -6.1689 0.32672E-06 -6.4858 0.48203E+00 -0.3169
44 AsO2- 0.24096E-06 -6.6181 0.12384E-06 -6.9071 0.51396E+00 -0.2891
45 HAsO2,aq 0.31459E-04 -4.5022 0.31459E-04 -4.5022 0.10000E+01 0.0000
46 H3AsO3,aq 0.89941E-04 -4.0460 0.89941E-04 -4.0460 0.10000E+01 0.0000
48 H2AsO4- 0.13505E-09 -9.8695 0.69410E-10 -10.1586 0.51396E+00 -0.2891
49 HAsO4-2 0.33823E-10 -10.4708 0.14387E-11 -11.8420 0.42538E-01 -1.3712
62 BaCO3,aq 0.50013E-09 -9.3009 0.50013E-09 -9.3009 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.15283E-05 -5.8158 0.84723E-06 -6.0720 0.55434E+00 -0.2562
64 BaCl+ 0.87151E-06 -6.0597 0.47261E-06 -6.3255 0.54229E+00 -0.2658
65 BaF+ 0.93950E-09 -9.0271 0.50948E-09 -9.2929 0.54229E+00 -0.2658
66 CH4,aq 0.16294E-08 -8.7880 0.14950E-08 -8.8254 0.91753E+00 -0.0374
71 CO,aq 0.35376E-08 -8.4513 0.35376E-08 -8.4513 0.10000E+01 0.0000
72 CO2,aq 0.30714E+00 -0.5127 0.28181E+00 -0.5500 0.91753E+00 -0.0374
73 CO3-2 0.65533E-05 -5.1835 0.27876E-06 -6.5548 0.42538E-01 -1.3712
74 CaCO3,aq 0.15034E-05 -5.8229 0.15034E-05 -5.8229 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.17785E-03 -3.7500 0.96445E-04 -4.0157 0.54229E+00 -0.2658
76 CaCl+ 0.54436E-03 -3.2641 0.29520E-03 -3.5299 0.54229E+00 -0.2658
77 CaCl2,aq 0.49025E-04 -4.3096 0.49025E-04 -4.3096 0.10000E+01 0.0000
78 CaF+ 0.51324E-05 -5.2897 0.27833E-05 -5.5554 0.54229E+00 -0.2658
79 CaOH+ 0.18388E-06 -6.7355 0.99718E-07 -7.0012 0.54229E+00 -0.2658
80 CaSO4,aq 0.46261E-06 -6.3348 0.46261E-06 -6.3348 0.10000E+01 0.0000
81 HCl,aq 0.12897E-05 -5.8895 0.12897E-05 -5.8895 0.10000E+01 0.0000
90 CuCl,aq 0.65999E-08 -8.1805 0.65999E-08 -8.1805 0.10000E+01 0.0000
91 CuCl2- 0.12548E-06 -6.9014 0.64489E-07 -7.1905 0.51396E+00 -0.2891
92 CuCl3-2 0.29606E-07 -7.5286 0.12594E-08 -8.8998 0.42538E-01 -1.3712
98 HF,aq 0.82940E-04 -4.0812 0.82940E-04 -4.0812 0.10000E+01 0.0000
99 HF2- 0.26470E-07 -7.5772 0.13605E-07 -7.8663 0.51396E+00 -0.2891
101 FeCl+ 0.34781E-06 -6.4587 0.18861E-06 -6.7244 0.54229E+00 -0.2658
102 FeCl2,aq 0.37260E-08 -8.4288 0.37260E-08 -8.4288 0.10000E+01 0.0000
104 FeF+ 0.86879E-08 -8.0611 0.47114E-08 -8.3269 0.54229E+00 -0.2658
106 FeO,aq 0.16331E-09 -9.7870 0.16331E-09 -9.7870 0.10000E+01 0.0000
107 FeOH+ 0.21108E-07 -7.6755 0.11447E-07 -7.9413 0.54229E+00 -0.2658
111 FeO2- 0.11345E-10 -10.9452 0.58310E-11 -11.2343 0.51396E+00 -0.2891
112 HFeO2,aq 0.12543E-09 -9.9016 0.12543E-09 -9.9016 0.10000E+01 0.0000
113 H2,aq 0.27577E-06 -6.5595 0.25303E-06 -6.5968 0.91753E+00 -0.0374
114 KCl,aq 0.13673E-02 -2.8641 0.13673E-02 -2.8641 0.10000E+01 0.0000
115 KHSO4,aq 0.25668E-09 -9.5906 0.25668E-09 -9.5906 0.10000E+01 0.0000
116 KOH,aq 0.64389E-07 -7.1912 0.64389E-07 -7.1912 0.10000E+01 0.0000
117 KSO4- 0.17983E-04 -4.7451 0.92426E-05 -5.0342 0.51396E+00 -0.2891
118 MgCO3,aq 0.18067E-07 -7.7431 0.18067E-07 -7.7431 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.15001E-04 -4.8239 0.81350E-05 -5.0896 0.54229E+00 -0.2658
120 MgCl+ 0.28588E-04 -4.5438 0.15503E-04 -4.8096 0.54229E+00 -0.2658
121 MgF+ 0.13403E-05 -5.8728 0.72681E-06 -6.1386 0.54229E+00 -0.2658
122 MgOH+ 0.56373E-07 -7.2489 0.30571E-07 -7.5147 0.54229E+00 -0.2658
124 MnF+ 0.22795E-07 -7.6422 0.12362E-07 -7.9079 0.54229E+00 -0.2658
125 MnO,aq 0.33649E-10 -10.4730 0.33649E-10 -10.4730 0.10000E+01 0.0000
126 MnOH+ 0.18265E-07 -7.7384 0.99048E-08 -8.0042 0.54229E+00 -0.2658
131 MnCl+ 0.25340E-04 -4.5962 0.13742E-04 -4.8620 0.54229E+00 -0.2658
132 MnSO4,aq 0.30736E-08 -8.5124 0.30736E-08 -8.5124 0.10000E+01 0.0000
133 NaCl,aq 0.30131E+00 -0.5210 0.30131E+00 -0.5210 0.10000E+01 0.0000
134 NaF,aq 0.22292E-03 -3.6519 0.22292E-03 -3.6519 0.10000E+01 0.0000
135 NaOH,aq 0.12298E-05 -5.9102 0.12298E-05 -5.9102 0.10000E+01 0.0000
137 OH- 0.42433E-05 -5.3723 0.20454E-05 -5.6892 0.48203E+00 -0.3169
140 PbCl+ 0.71366E-07 -7.1465 0.38701E-07 -7.4123 0.54229E+00 -0.2658
141 PbCl2,aq 0.33540E-06 -6.4744 0.33540E-06 -6.4744 0.10000E+01 0.0000
142 PbCl3- 0.27801E-06 -6.5559 0.14289E-06 -6.8450 0.51396E+00 -0.2891
143 PbCl4-2 0.42681E-06 -6.3698 0.18155E-07 -7.7410 0.42538E-01 -1.3712
144 PbF+ 0.10086E-09 -9.9963 0.54694E-10 -10.2621 0.54229E+00 -0.2658
146 PbO,aq 0.61143E-10 -10.2137 0.61143E-10 -10.2137 0.10000E+01 0.0000
148 Pb(HS)2,aq 0.21219E-09 -9.6733 0.21219E-09 -9.6733 0.10000E+01 0.0000
150 H2S,aq 0.11386E-04 -4.9436 0.10447E-04 -4.9810 0.91753E+00 -0.0374
158 HSO3- 0.27268E-09 -9.5643 0.14015E-09 -9.8534 0.51396E+00 -0.2891
159 HSO4- 0.64864E-06 -6.1880 0.35794E-06 -6.4462 0.55182E+00 -0.2582
161 S2O3-2 0.25391E-10 -10.5953 0.10801E-11 -11.9665 0.42538E-01 -1.3712
173 ZnCl+ 0.52009E-05 -5.2839 0.28204E-05 -5.5497 0.54229E+00 -0.2658
174 ZnCl2,aq 0.14000E-05 -5.8539 0.14000E-05 -5.8539 0.10000E+01 0.0000
175 ZnCl3- 0.19597E-06 -6.7078 0.10072E-06 -6.9969 0.51396E+00 -0.2891
176 ZnF+ 0.12406E-09 -9.9064 0.67274E-10 -10.1722 0.54229E+00 -0.2658
177 ZnO,aq 0.44471E-09 -9.3519 0.44471E-09 -9.3519 0.10000E+01 0.0000
178 ZnOH+ 0.27452E-06 -6.5614 0.14887E-06 -6.8272 0.54229E+00 -0.2658
Charge balance for all species = -.1232E-03
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.7152453E-05 0.3073384E+00 0.2809766E+03 0.0000
2 H2O 0.1000000E+01 0.5520107E+02 0.9020025E+06 0.0000
3 Cl- 0.1165076E+01 0.1468462E+01 0.4722091E+05 5.2395
4 SO4-- 0.1602213E-03 0.1792478E-03 0.1561789E+02 5.7759
5 HCO3- 0.2516232E-01 0.3325067E+00 0.1840227E+05 3.5907
6 HS- 0.1497558E-05 0.1296256E-04 0.3888392E+00 -0.6497
7 H4SiO4 0.2658909E-02 0.2670201E-02 0.2327854E+03 -2.5753
8 Al+++ 0.4432889E-13 0.7314393E-06 0.1790042E-01 -0.1192
9 Ca++ 0.1221888E-02 0.2000414E-02 0.7271846E+02 6.6012
10 Mg++ 0.1182155E-03 0.1632207E-03 0.3599271E+01 5.5417
11 Fe++ 0.1141845E-05 0.1523484E-05 0.7717142E-01 3.5380
12 K+ 0.4180769E-01 0.4319307E-01 0.1531905E+04 3.8156
13 Na+ 0.1146397E+01 0.1447935E+01 0.3019277E+05 5.2333
14 Mn++ 0.7376128E-05 0.3276067E-04 0.1632467E+01 4.3565
15 Zn++ 0.2433930E-07 0.7096371E-05 0.4207591E+00 1.8667
16 Cu+ 0.4540285E-11 0.1616858E-06 0.9318324E-02 -6.1696
17 Pb++ 0.5903320E-08 0.1117860E-05 0.2100752E+00 1.3120
18 Ag+ 0.2315101E-10 0.4058634E-06 0.3970994E-01 -5.4449
19 Au+ 0.8476423E-21 0.2956080E-11 0.5281149E-06 -15.8754
20 Ba++ 0.1460765E-05 0.3862052E-05 0.4810984E+00 3.7226
21 F- 0.1236814E-02 0.1549230E-02 0.2669577E+02 2.2322
22 H2AsO3- 0.1544496E-05 0.1231858E-03 0.1395938E+02 -0.5167
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234410E+00 -.5846981E-05 0.0000000E+00
2 H2O 0.5809327E+02 0.5809327E+02 0.0000000E+00 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1364172E-04 0.3885920E-06 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810103E-02 0.1637517E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.7697622E-06 0.1637517E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.5458389E-06 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.7468176E-05 0.0000000E+00 0.0000000E+00
16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00
17 Pb++ 0.1565021E-05 0.1176429E-05 0.3885920E-06 0.0000000E+00
18 Ag+ 0.4271281E-06 0.4271281E-06 0.0000000E+00 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1630400E-02 0.0000000E+00 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: 0.7412E-21 Mass of aqueous solution: 0.116027E+04 g
Temperature = 192.08 C Pressure = 500.00 bar Mixer frac. = 0.0500000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
paragonite 0.5458E-06 -6.263 0.2086E-03 -3.681 69.17 0.7211E-04
galena 0.3886E-06 -6.411 0.9297E-04 -4.032 30.83 0.1224E-04
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
paragonite 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.0500000
Solid products produced: Mass = 0.000302 g Volume = 0.000084 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.300
AFFINITY: 0.5226E+03
GOLD Q/K: 0.0207
SILVER Q/K: 0.2704
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 192.0845 deg.C
Sat. pressure: 94.0408 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.2403E+00 0.6491 0.1467E+02 0.2260E+02
CO2,gas 0.7597E+00 0.9049 0.6465E+02 0.7144E+02
CH4,gas 0.2229E-07 1.1282 0.2365E-05 0.2096E-05
H2,gas 0.2600E-05 1.0410 0.2545E-03 0.2445E-03
H2S,gas 0.7390E-05 0.8320 0.5782E-03 0.6949E-03
S2,gas 0.1175E-15 1.0000 0.1105E-13 0.1105E-13
CO,gas 0.4251E-07 1.0000 0.3997E-05 0.3997E-05
SO3,gas 0.8179E-26 1.0000 0.7691E-24 0.7691E-24
O2,gas 0.9819E-42 1.0000 0.9234E-40 0.9234E-40
SO2,gas 0.5742E-12 1.0000 0.5400E-10 0.5400E-10
HF,gas 0.4415E-07 1.0000 0.4152E-05 0.4152E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
122 paragonite -2.85 -2.85 0.00 0.000 0.20799E-10
260 galena -10.26 -10.26 0.00 0.000 0.00000E+00
272 sphalerite -9.72 -9.71 0.01 0.003 -0.19543E+02
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 -0.02 -1.53 -1.533 0.32627E+04 1.166
2 CO2,gas -6.42 -7.31 -0.89 -0.296 0.18913E+04 1.811
3 CH4,gas 5.47 -2.86 -8.33 -2.081 0.17723E+05 -5.626
4 H2,gas 7.40 1.10 -6.29 -3.596 0.13397E+05 -3.594
5 H2S,gas -5.64 -11.57 -5.94 -2.968 0.12639E+05 -3.238
6 S2,gas -8.70 -25.36 -16.66 -2.562 0.35457E+05 -13.957
7 CO,gas 1.91 -6.19 -8.10 -2.491 0.17238E+05 -5.398
8 SO3,gas 10.76 -16.05 -26.81 -6.703 0.57080E+05 -24.114
9 O2,gas 40.48 -2.25 -42.73 -28.489 0.90973E+05 -40.035
10 SO2,gas -1.96 -14.93 -12.97 -3.458 0.27604E+05 -10.268
11 HF,gas -0.61 -8.69 -8.08 -4.040 0.17203E+05 -5.382
12 HCl,gas 0.90 -5.68 -6.59 -3.293 0.14022E+05 -6.587
13 acmite 6.10 3.11 -2.99 -0.311 0.63657E+04
17 albite-high -1.41 -2.53 -1.12 -0.086 0.23879E+04
18 albite -2.10 -2.53 -0.43 -0.033 0.91566E+03
22 analcite 0.97 -0.02 -0.98 -0.109 0.20908E+04
23 andalusite -0.96 -2.83 -1.87 -0.187 0.39831E+04
26 anhydrite -6.68 -9.47 -2.80 -1.398 0.59518E+04
27 ankerite -3.96 -4.53 -0.57 -0.095 0.12125E+04
31 anorthite 4.84 1.21 -3.63 -0.279 0.77205E+04
34 aragonite -0.07 -0.73 -0.66 -0.221 0.14094E+04
35 brucite 9.70 5.50 -4.20 -0.840 0.89382E+04
36 calcite -0.21 -0.73 -0.52 -0.174 0.11122E+04
37 carnegieite-low 5.42 2.54 -2.88 -0.412 0.61344E+04
38 carnegieite-high 6.12 2.54 -3.58 -0.512 0.76229E+04
39 carpholite-Mg 2.12 0.11 -2.01 -0.134 0.42686E+04
40 carpholite-Fe 0.57 -1.89 -2.46 -0.164 0.52346E+04
41 celadonite 2.60 -0.98 -3.58 -0.211 0.76311E+04
42 celadonite-Fe 1.28 -2.98 -4.27 -0.251 0.90856E+04
45 clinochlore 24.44 19.62 -4.82 -0.151 0.10257E+05
49 chloritoid-Mg 5.34 2.67 -2.68 -0.179 0.57007E+04
50 chloritoid-Fe 2.18 0.66 -1.51 -0.101 0.32216E+04
51 chloritoid-Mn 4.37 1.48 -2.89 -0.192 0.61454E+04
53 coesite -1.86 -2.53 -0.68 -0.225 0.14394E+04
58 corundum 1.69 -0.30 -1.99 -0.181 0.42433E+04
60 cristobalite -2.05 -2.53 -0.48 -0.161 0.10251E+04
63 cymrite-K -0.14 -3.97 -3.83 -0.319 0.81446E+04
65 diaspore 0.11 -0.16 -0.27 -0.045 0.57853E+03
66 diamond -2.17 -5.06 -2.89 -0.825 0.61503E+04
69 dolomite,ordered -1.75 -2.52 -0.78 -0.130 0.16588E+04
83 gibbsite 1.36 -0.18 -1.54 -0.220 0.32823E+04
86 goethite 4.52 2.94 -1.58 -0.341 0.33593E+04
87 graphite -2.56 -5.06 -2.50 -0.714 0.53228E+04
90 halite 1.38 -0.45 -1.84 -0.918 0.39066E+04
91 hematite 8.41 5.91 -2.50 -0.304 0.53312E+04
92 heulandite -8.85 -11.58 -2.73 -0.124 0.58049E+04
93 hercynite 7.93 3.22 -4.72 -0.314 0.10043E+05
96 jadeite 1.79 0.01 -1.78 -0.178 0.37941E+04
98 kalsilite 4.38 1.12 -3.26 -0.466 0.69420E+04
99 kaolinite -5.03 -5.41 -0.38 -0.034 0.80209E+03
100 kyanite -1.00 -2.83 -1.83 -0.183 0.38952E+04
102 laumontite -1.66 -3.94 -2.28 -0.152 0.48561E+04
103 lawsonite 3.57 1.17 -2.40 -0.160 0.51173E+04
104 leucite 1.47 -1.41 -2.88 -0.288 0.61405E+04
107 magnesite -0.79 -1.79 -1.00 -0.335 0.21385E+04
108 magnetite 13.58 9.43 -4.16 -0.339 0.88515E+04
114 margarite 4.14 0.89 -3.25 -0.130 0.69270E+04
117 microcline -3.54 -3.95 -0.41 -0.031 0.86412E+03
120 mullite-Si 0.75 -2.83 -3.59 -0.359 0.76341E+04
121 muscovite -4.02 -4.27 -0.25 -0.015 0.52654E+03
123 nepheline 4.84 2.54 -2.30 -0.328 0.48892E+04
129 periclase-Fe 8.46 3.52 -4.94 -1.235 0.10515E+05
143 pyrite -19.29 -20.71 -1.42 -0.334 0.30226E+04
144 pyrrhotite -4.94 -8.04 -3.10 -1.034 0.66014E+04
145 pyrrhotiteFe0.875 -6.28 -8.62 -2.34 -0.859 0.49719E+04
146 pyroxmangite 5.53 1.80 -3.73 -0.745 0.79307E+04
147 pyrophyllite -9.25 -10.46 -1.21 -0.076 0.25743E+04
148 quartz -2.36 -2.53 -0.18 -0.060 0.38031E+03
153 rhodochrosite -1.77 -2.98 -1.21 -0.403 0.25744E+04
154 rhodonite 5.55 1.80 -3.75 -0.750 0.79861E+04
155 sanidine -2.57 -3.95 -1.38 -0.106 0.29324E+04
157 siderite -3.45 -3.80 -0.35 -0.115 0.73500E+03
158 sillimanite -0.79 -2.83 -2.04 -0.204 0.43496E+04
165 stilbite -8.68 -11.60 -2.92 -0.139 0.62197E+04
168 stishovite 2.36 -2.53 -4.89 -1.630 0.10411E+05
170 sudoite 7.13 2.76 -4.38 -0.141 0.93212E+04
171 sulfur -8.50 -12.68 -4.18 -1.285 0.88899E+04
172 sylvite 1.41 -1.87 -3.28 -1.638 0.69722E+04
180 topaz-H -0.60 -2.86 -2.26 -0.205 0.48082E+04
181 tridymite -2.08 -2.53 -0.45 -0.150 0.96041E+03
184 troilite-low -5.00 -8.04 -3.04 -1.012 0.64658E+04
190 wairakite -1.43 -3.90 -2.47 -0.145 0.52545E+04
192 wollastonite 8.23 4.05 -4.18 -0.837 0.89051E+04
193 pseudo-wollastonite 8.61 4.05 -4.57 -0.913 0.97210E+04
196 argentite -22.30 -22.46 -0.17 -0.042 0.35800E+03
197 arsenic -5.52 -9.72 -4.20 -1.084 0.89395E+04
199 arsenopyrite -13.42 -17.76 -4.34 -0.771 0.92311E+04
200 beidellite-Ca -6.53 -8.58 -2.05 -0.127 0.43686E+04
201 beidellite-H -6.99 -9.67 -2.68 -0.171 0.57133E+04
202 beidellite-K -6.09 -8.41 -2.33 -0.142 0.49535E+04
203 beidellite-Mg -6.77 -8.76 -1.99 -0.123 0.42308E+04
204 beidellite-Na -6.00 -7.95 -1.94 -0.119 0.41350E+04
205 bornite -72.89 -74.16 -1.27 -0.095 0.26968E+04
207 chalcedony -2.21 -2.53 -0.33 -0.109 0.69931E+03
208 chalcocite -22.24 -23.91 -1.67 -0.417 0.35550E+04
210 covellite -16.36 -18.30 -1.93 -0.737 0.41188E+04
211 dawsonite -0.10 -2.26 -2.17 -0.271 0.46103E+04
213 montmorillonite-Ca -5.64 -7.50 -1.85 -0.115 0.39484E+04
214 montmorillonite-K -5.30 -7.33 -2.03 -0.124 0.43170E+04
215 montmorillonite-Mg -5.88 -7.67 -1.79 -0.111 0.38180E+04
216 montmorillonite-Na -5.14 -6.86 -1.72 -0.105 0.36624E+04
217 nontronite-Ca 0.73 -2.37 -3.11 -0.202 0.66177E+04
218 nontronite-H 0.27 -3.46 -3.74 -0.250 0.79536E+04
219 nontronite-K 1.18 -2.20 -3.38 -0.217 0.72016E+04
220 nontronite-Mg 0.52 -2.55 -3.07 -0.199 0.65423E+04
221 nontronite-Na 1.26 -1.74 -3.00 -0.193 0.63863E+04
225 topaz -20.20 -20.20 0.00 0.000 0.52093E+01
229 gypsum -5.71 -9.51 -3.80 -0.950 0.80923E+04
245 acanthite -22.12 -22.46 -0.34 -0.086 0.72901E+03
251 barite -9.67 -12.35 -2.68 -1.340 0.57055E+04
252 boehmite 1.18 -0.16 -1.34 -0.224 0.28594E+04
253 cerussite -2.83 -6.02 -3.19 -1.064 0.67963E+04
254 chalcopyrite -24.82 -26.33 -1.51 -0.281 0.32154E+04
256 copper,native -1.61 -5.62 -4.00 -1.392 0.85209E+04
257 dolomite,disordered -1.30 -2.52 -1.22 -0.204 0.26020E+04
258 ferrous-oxide 6.96 3.52 -3.45 -0.862 0.73380E+04
259 fluorite -10.25 -10.78 -0.53 -0.177 0.11321E+04
261 gold,native -13.64 -15.32 -1.68 -0.585 0.35828E+04
262 silver,native -4.32 -4.89 -0.57 -0.198 0.12093E+04
263 huntite -1.97 -6.11 -4.14 -0.345 0.88077E+04
269 silica-amorphous -1.69 -2.53 -0.85 -0.282 0.18007E+04
270 smithsonite -1.83 -5.47 -3.64 -1.213 0.77463E+04
273 wurtzite -8.25 -9.71 -1.46 -0.486 0.31044E+04
274 zincite 5.84 1.85 -3.99 -0.998 0.84974E+04
275 an20ab80 -0.93 -1.78 -0.85 -0.066 0.18139E+04
276 an25ab75 -0.61 -1.59 -0.99 -0.076 0.20975E+04
277 an30ab70 -0.28 -1.41 -1.12 -0.086 0.23926E+04
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 70
Temperature = 192.08 C Pressure = 500.00 bar Mixer fraction = 0.0500000
Water: Moles liquid = 0.5842E+02 kg liquid = 0.1052E+01
Moles total = 0.5809E+02 kg total = 0.1047E+01 Activity = 0.9533
Stoichiometric ionic strength = .1660864E+01 Osmotic coef. = 0.9046
True ionic strength = .1193297E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.71525E-05 -5.1455 0.34501E-05 -5.4622 0.48237E+00 -0.3166
2 H2O 0.95326E+00 -0.0208 0.95326E+00 -0.0208
3 Cl- 0.11651E+01 0.0664 0.59880E+00 -0.2227 0.51396E+00 -0.2891
4 SO4-- 0.16022E-03 -3.7953 0.71046E-05 -5.1485 0.44342E-01 -1.3532
5 HCO3- 0.25162E-01 -1.5993 0.13443E-01 -1.8715 0.53426E+00 -0.2722
6 HS- 0.14870E-05 -5.8277 0.76749E-06 -6.1149 0.51614E+00 -0.2872
7 H4SiO4 0.26589E-02 -2.5753 0.26589E-02 -2.5753 0.10000E+01 0.0000
8 Al+++ 0.44330E-13 -13.3533 0.31210E-16 -16.5057 0.70404E-03 -3.1524
9 Ca++ 0.12219E-02 -2.9130 0.47515E-04 -4.3232 0.38886E-01 -1.4102
10 Mg++ 0.11822E-03 -3.9273 0.41439E-05 -5.3826 0.35054E-01 -1.4553
11 Fe++ 0.11418E-05 -5.9424 0.41080E-07 -7.3864 0.35977E-01 -1.4440
12 K+ 0.41808E-01 -1.3787 0.22563E-01 -1.6466 0.53968E+00 -0.2679
13 Na+ 0.11464E+01 0.0593 0.59038E+00 -0.2289 0.51499E+00 -0.2882
14 Mn++ 0.73761E-05 -5.1322 0.27050E-06 -6.5678 0.36672E-01 -1.4357
15 Zn++ 0.24000E-07 -7.6198 0.86344E-09 -9.0638 0.35977E-01 -1.4440
16 Cu+ 0.45403E-11 -11.3429 0.23349E-11 -11.6317 0.51427E+00 -0.2888
17 Pb++ 0.59453E-08 -8.2258 0.24589E-09 -9.6093 0.41359E-01 -1.3834
18 Ag+ 0.23154E-10 -10.6354 0.12389E-10 -10.9070 0.53506E+00 -0.2716
19 Au+ 0.85353E-21 -21.0688 0.46286E-21 -21.3345 0.54229E+00 -0.2658
20 Ba++ 0.14608E-05 -5.8354 0.62844E-07 -7.2017 0.43021E-01 -1.3663
21 F- 0.12368E-02 -2.9077 0.58884E-03 -3.2300 0.47609E+00 -0.3223
22 H2AsO3- 0.15445E-05 -5.8112 0.10498E-05 -5.9789 0.67972E+00 -0.1677
24 HSiO3- 0.33207E-05 -5.4788 0.17067E-05 -5.7678 0.51396E+00 -0.2891
25 Ca(HSiO3)+ 0.16547E-07 -7.7813 0.89734E-08 -8.0470 0.54229E+00 -0.2658
26 Mg(HSiO3)+ 0.12377E-08 -8.9074 0.67118E-09 -9.1732 0.54229E+00 -0.2658
27 NaHSiO3,aq 0.79541E-05 -5.0994 0.79541E-05 -5.0994 0.10000E+01 0.0000
31 AgCl,aq 0.41911E-08 -8.3777 0.41911E-08 -8.3777 0.10000E+01 0.0000
32 AgCl2- 0.20621E-06 -6.6857 0.10598E-06 -6.9748 0.51396E+00 -0.2891
33 AgCl3-2 0.15596E-06 -6.8070 0.66344E-08 -8.1782 0.42538E-01 -1.3712
34 AgCl4-3 0.32134E-07 -7.4930 0.21870E-10 -10.6602 0.68058E-03 -3.1671
38 Ag(HS),aq 0.73386E-08 -8.1344 0.73386E-08 -8.1344 0.10000E+01 0.0000
40 AlO+ 0.19470E-09 -9.7106 0.10558E-09 -9.9764 0.54229E+00 -0.2658
42 HAlO2,aq 0.53446E-07 -7.2721 0.53446E-07 -7.2721 0.10000E+01 0.0000
43 AlO2- 0.67779E-06 -6.1689 0.32671E-06 -6.4858 0.48203E+00 -0.3169
44 AsO2- 0.24096E-06 -6.6181 0.12384E-06 -6.9071 0.51396E+00 -0.2891
45 HAsO2,aq 0.31459E-04 -4.5022 0.31459E-04 -4.5022 0.10000E+01 0.0000
46 H3AsO3,aq 0.89941E-04 -4.0460 0.89941E-04 -4.0460 0.10000E+01 0.0000
48 H2AsO4- 0.13529E-09 -9.8687 0.69532E-10 -10.1578 0.51396E+00 -0.2891
49 HAsO4-2 0.33883E-10 -10.4700 0.14413E-11 -11.8413 0.42538E-01 -1.3712
62 BaCO3,aq 0.50012E-09 -9.3009 0.50012E-09 -9.3009 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.15283E-05 -5.8158 0.84722E-06 -6.0720 0.55434E+00 -0.2562
64 BaCl+ 0.87151E-06 -6.0597 0.47261E-06 -6.3255 0.54229E+00 -0.2658
65 BaF+ 0.93950E-09 -9.0271 0.50948E-09 -9.2929 0.54229E+00 -0.2658
66 CH4,aq 0.16179E-08 -8.7911 0.14844E-08 -8.8284 0.91753E+00 -0.0374
71 CO,aq 0.35313E-08 -8.4521 0.35313E-08 -8.4521 0.10000E+01 0.0000
72 CO2,aq 0.30714E+00 -0.5127 0.28181E+00 -0.5500 0.91753E+00 -0.0374
73 CO3-2 0.65532E-05 -5.1835 0.27876E-06 -6.5548 0.42538E-01 -1.3712
74 CaCO3,aq 0.15033E-05 -5.8229 0.15033E-05 -5.8229 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.17785E-03 -3.7500 0.96444E-04 -4.0157 0.54229E+00 -0.2658
76 CaCl+ 0.54436E-03 -3.2641 0.29520E-03 -3.5299 0.54229E+00 -0.2658
77 CaCl2,aq 0.49025E-04 -4.3096 0.49025E-04 -4.3096 0.10000E+01 0.0000
78 CaF+ 0.51324E-05 -5.2897 0.27833E-05 -5.5554 0.54229E+00 -0.2658
79 CaOH+ 0.18388E-06 -6.7355 0.99717E-07 -7.0012 0.54229E+00 -0.2658
80 CaSO4,aq 0.46261E-06 -6.3348 0.46261E-06 -6.3348 0.10000E+01 0.0000
81 HCl,aq 0.12897E-05 -5.8895 0.12897E-05 -5.8895 0.10000E+01 0.0000
90 CuCl,aq 0.65999E-08 -8.1805 0.65999E-08 -8.1805 0.10000E+01 0.0000
91 CuCl2- 0.12548E-06 -6.9014 0.64489E-07 -7.1905 0.51396E+00 -0.2891
92 CuCl3-2 0.29606E-07 -7.5286 0.12594E-08 -8.8998 0.42538E-01 -1.3712
98 HF,aq 0.82941E-04 -4.0812 0.82941E-04 -4.0812 0.10000E+01 0.0000
99 HF2- 0.26470E-07 -7.5772 0.13605E-07 -7.8663 0.51396E+00 -0.2891
101 FeCl+ 0.34781E-06 -6.4587 0.18861E-06 -6.7244 0.54229E+00 -0.2658
102 FeCl2,aq 0.37260E-08 -8.4288 0.37260E-08 -8.4288 0.10000E+01 0.0000
104 FeF+ 0.86879E-08 -8.0611 0.47114E-08 -8.3269 0.54229E+00 -0.2658
106 FeO,aq 0.16330E-09 -9.7870 0.16330E-09 -9.7870 0.10000E+01 0.0000
107 FeOH+ 0.21108E-07 -7.6755 0.11447E-07 -7.9413 0.54229E+00 -0.2658
111 FeO2- 0.11355E-10 -10.9448 0.58361E-11 -11.2339 0.51396E+00 -0.2891
112 HFeO2,aq 0.12554E-09 -9.9012 0.12554E-09 -9.9012 0.10000E+01 0.0000
113 H2,aq 0.27528E-06 -6.5602 0.25258E-06 -6.5976 0.91753E+00 -0.0374
114 KCl,aq 0.13673E-02 -2.8641 0.13673E-02 -2.8641 0.10000E+01 0.0000
115 KHSO4,aq 0.25668E-09 -9.5906 0.25668E-09 -9.5906 0.10000E+01 0.0000
116 KOH,aq 0.64388E-07 -7.1912 0.64388E-07 -7.1912 0.10000E+01 0.0000
117 KSO4- 0.17983E-04 -4.7451 0.92426E-05 -5.0342 0.51396E+00 -0.2891
118 MgCO3,aq 0.18067E-07 -7.7431 0.18067E-07 -7.7431 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.15001E-04 -4.8239 0.81349E-05 -5.0896 0.54229E+00 -0.2658
120 MgCl+ 0.28588E-04 -4.5438 0.15503E-04 -4.8096 0.54229E+00 -0.2658
121 MgF+ 0.13403E-05 -5.8728 0.72681E-06 -6.1386 0.54229E+00 -0.2658
122 MgOH+ 0.56373E-07 -7.2489 0.30570E-07 -7.5147 0.54229E+00 -0.2658
124 MnF+ 0.22795E-07 -7.6422 0.12362E-07 -7.9079 0.54229E+00 -0.2658
125 MnO,aq 0.33649E-10 -10.4730 0.33649E-10 -10.4730 0.10000E+01 0.0000
126 MnOH+ 0.18265E-07 -7.7384 0.99048E-08 -8.0042 0.54229E+00 -0.2658
131 MnCl+ 0.25340E-04 -4.5962 0.13742E-04 -4.8620 0.54229E+00 -0.2658
132 MnSO4,aq 0.30736E-08 -8.5124 0.30736E-08 -8.5124 0.10000E+01 0.0000
133 NaCl,aq 0.30131E+00 -0.5210 0.30131E+00 -0.5210 0.10000E+01 0.0000
134 NaF,aq 0.22292E-03 -3.6519 0.22292E-03 -3.6519 0.10000E+01 0.0000
135 NaOH,aq 0.12298E-05 -5.9102 0.12298E-05 -5.9102 0.10000E+01 0.0000
137 OH- 0.42433E-05 -5.3723 0.20454E-05 -5.6892 0.48203E+00 -0.3169
140 PbCl+ 0.71874E-07 -7.1434 0.38977E-07 -7.4092 0.54229E+00 -0.2658
141 PbCl2,aq 0.33778E-06 -6.4714 0.33778E-06 -6.4714 0.10000E+01 0.0000
142 PbCl3- 0.27999E-06 -6.5529 0.14390E-06 -6.8419 0.51396E+00 -0.2891
143 PbCl4-2 0.42985E-06 -6.3667 0.18285E-07 -7.7379 0.42538E-01 -1.3712
144 PbF+ 0.10158E-09 -9.9932 0.55083E-10 -10.2590 0.54229E+00 -0.2658
146 PbO,aq 0.61577E-10 -10.2106 0.61577E-10 -10.2106 0.10000E+01 0.0000
148 Pb(HS)2,aq 0.21069E-09 -9.6763 0.21069E-09 -9.6763 0.10000E+01 0.0000
150 H2S,aq 0.11305E-04 -4.9467 0.10373E-04 -4.9841 0.91753E+00 -0.0374
158 HSO3- 0.27220E-09 -9.5651 0.13990E-09 -9.8542 0.51396E+00 -0.2891
159 HSO4- 0.64865E-06 -6.1880 0.35794E-06 -6.4462 0.55182E+00 -0.2582
161 S2O3-2 0.25212E-10 -10.5984 0.10725E-11 -11.9696 0.42538E-01 -1.3712
173 ZnCl+ 0.51284E-05 -5.2900 0.27811E-05 -5.5558 0.54229E+00 -0.2658
174 ZnCl2,aq 0.13805E-05 -5.8600 0.13805E-05 -5.8600 0.10000E+01 0.0000
175 ZnCl3- 0.19323E-06 -6.7139 0.99314E-07 -7.0030 0.51396E+00 -0.2891
176 ZnF+ 0.12233E-09 -9.9125 0.66336E-10 -10.1783 0.54229E+00 -0.2658
177 ZnO,aq 0.43850E-09 -9.3580 0.43850E-09 -9.3580 0.10000E+01 0.0000
178 ZnOH+ 0.27069E-06 -6.5675 0.14679E-06 -6.8333 0.54229E+00 -0.2658
Charge balance for all species = -.1232E-03
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.7152504E-05 0.3073385E+00 0.2809767E+03 0.0000
2 H2O 0.1000000E+01 0.5520107E+02 0.9020025E+06 0.0000
3 Cl- 0.1165076E+01 0.1468462E+01 0.4722091E+05 5.2394
4 SO4-- 0.1602211E-03 0.1792478E-03 0.1561789E+02 5.7759
5 HCO3- 0.2516215E-01 0.3325067E+00 0.1840227E+05 3.5907
6 HS- 0.1486988E-05 0.1287152E-04 0.3861081E+00 -0.6528
7 H4SiO4 0.2658909E-02 0.2670201E-02 0.2327854E+03 -2.5753
8 Al+++ 0.4432993E-13 0.7314362E-06 0.1790034E-01 -0.1192
9 Ca++ 0.1221888E-02 0.2000414E-02 0.7271846E+02 6.6012
10 Mg++ 0.1182155E-03 0.1632207E-03 0.3599271E+01 5.5417
11 Fe++ 0.1141845E-05 0.1523484E-05 0.7717142E-01 3.5380
12 K+ 0.4180769E-01 0.4319307E-01 0.1531905E+04 3.8156
13 Na+ 0.1146397E+01 0.1447935E+01 0.3019277E+05 5.2333
14 Mn++ 0.7376127E-05 0.3276067E-04 0.1632467E+01 4.3565
15 Zn++ 0.2399977E-07 0.6997376E-05 0.4148895E+00 1.8606
16 Cu+ 0.4540285E-11 0.1616858E-06 0.9318324E-02 -6.1696
17 Pb++ 0.5945325E-08 0.1125811E-05 0.2115695E+00 1.3151
18 Ag+ 0.2315399E-10 0.4058634E-06 0.3970994E-01 -5.4448
19 Au+ 0.8535291E-21 0.2956080E-11 0.5281149E-06 -15.8724
20 Ba++ 0.1460769E-05 0.3862052E-05 0.4810984E+00 3.7226
21 F- 0.1236814E-02 0.1549230E-02 0.2669577E+02 2.2322
22 H2AsO3- 0.1544485E-05 0.1231858E-03 0.1395938E+02 -0.5167
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234411E+00 -.5942805E-05 0.0000000E+00
2 H2O 0.5809327E+02 0.5809327E+02 0.0000000E+00 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1354591E-04 0.4844047E-06 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810103E-02 0.1637520E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.7697590E-06 0.1637520E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.5458400E-06 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.7363996E-05 0.1041807E-06 0.0000000E+00
16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00
17 Pb++ 0.1565021E-05 0.1184797E-05 0.3802240E-06 0.0000000E+00
18 Ag+ 0.4271281E-06 0.4271281E-06 0.0000000E+00 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1630400E-02 0.0000000E+00 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: -.5294E-21 Mass of aqueous solution: 0.116027E+04 g
Temperature = 192.08 C Pressure = 500.00 bar Mixer frac. = 0.0500000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
paragonite 0.5458E-06 -6.263 0.2086E-03 -3.681 67.35 0.7211E-04
galena 0.3802E-06 -6.420 0.9097E-04 -4.041 29.37 0.1197E-04
sphalerite 0.1042E-06 -6.982 0.1015E-04 -4.994 3.277 0.2482E-05
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
paragonite 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.0500000
Solid products produced: Mass = 0.000310 g Volume = 0.000087 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.300
AFFINITY: 0.5214E+03
GOLD Q/K: 0.0209
SILVER Q/K: 0.2702
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 192.0845 deg.C
Sat. pressure: 94.0408 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.2403E+00 0.6491 0.1467E+02 0.2260E+02
CO2,gas 0.7597E+00 0.9049 0.6465E+02 0.7144E+02
CH4,gas 0.2213E-07 1.1282 0.2348E-05 0.2081E-05
H2,gas 0.2595E-05 1.0410 0.2540E-03 0.2440E-03
H2S,gas 0.7338E-05 0.8320 0.5742E-03 0.6900E-03
S2,gas 0.1163E-15 1.0000 0.1093E-13 0.1093E-13
CO,gas 0.4243E-07 1.0000 0.3990E-05 0.3990E-05
SO3,gas 0.8179E-26 1.0000 0.7691E-24 0.7691E-24
O2,gas 0.9854E-42 1.0000 0.9267E-40 0.9267E-40
SO2,gas 0.5732E-12 1.0000 0.5390E-10 0.5390E-10
HF,gas 0.4415E-07 1.0000 0.4152E-05 0.4152E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
122 paragonite -2.85 -2.85 0.00 0.000 -0.94539E-11
260 galena -10.26 -10.26 0.00 0.000 -0.37816E-11
272 sphalerite -9.72 -9.72 0.00 0.000 0.00000E+00
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 -0.02 -1.53 -1.533 0.32627E+04 1.166
2 CO2,gas -6.42 -7.31 -0.89 -0.296 0.18913E+04 1.811
3 CH4,gas 5.47 -2.86 -8.33 -2.082 0.17729E+05 -5.629
4 H2,gas 7.40 1.10 -6.29 -3.597 0.13399E+05 -3.595
5 H2S,gas -5.64 -11.58 -5.94 -2.970 0.12645E+05 -3.241
6 S2,gas -8.70 -25.36 -16.66 -2.563 0.35467E+05 -13.961
7 CO,gas 1.91 -6.19 -8.10 -2.492 0.17239E+05 -5.399
8 SO3,gas 10.76 -16.05 -26.81 -6.703 0.57080E+05 -24.114
9 O2,gas 40.48 -2.25 -42.73 -28.488 0.90970E+05 -40.033
10 SO2,gas -1.96 -14.93 -12.97 -3.458 0.27605E+05 -10.268
11 HF,gas -0.61 -8.69 -8.08 -4.040 0.17203E+05 -5.382
12 HCl,gas 0.90 -5.68 -6.59 -3.293 0.14022E+05 -6.587
13 acmite 6.10 3.11 -2.99 -0.311 0.63649E+04
17 albite-high -1.41 -2.53 -1.12 -0.086 0.23879E+04
18 albite -2.10 -2.53 -0.43 -0.033 0.91566E+03
22 analcite 0.97 -0.02 -0.98 -0.109 0.20908E+04
23 andalusite -0.96 -2.83 -1.87 -0.187 0.39831E+04
26 anhydrite -6.68 -9.47 -2.80 -1.398 0.59518E+04
27 ankerite -3.96 -4.53 -0.57 -0.095 0.12125E+04
31 anorthite 4.84 1.21 -3.63 -0.279 0.77205E+04
34 aragonite -0.07 -0.73 -0.66 -0.221 0.14094E+04
35 brucite 9.70 5.50 -4.20 -0.840 0.89382E+04
36 calcite -0.21 -0.73 -0.52 -0.174 0.11122E+04
37 carnegieite-low 5.42 2.54 -2.88 -0.412 0.61344E+04
38 carnegieite-high 6.12 2.54 -3.58 -0.512 0.76229E+04
39 carpholite-Mg 2.12 0.11 -2.01 -0.134 0.42686E+04
40 carpholite-Fe 0.57 -1.89 -2.46 -0.164 0.52346E+04
41 celadonite 2.60 -0.98 -3.58 -0.211 0.76311E+04
42 celadonite-Fe 1.28 -2.98 -4.27 -0.251 0.90857E+04
45 clinochlore 24.44 19.62 -4.82 -0.151 0.10258E+05
49 chloritoid-Mg 5.34 2.67 -2.68 -0.179 0.57007E+04
50 chloritoid-Fe 2.18 0.66 -1.51 -0.101 0.32216E+04
51 chloritoid-Mn 4.37 1.48 -2.89 -0.192 0.61455E+04
53 coesite -1.86 -2.53 -0.68 -0.225 0.14394E+04
58 corundum 1.69 -0.30 -1.99 -0.181 0.42433E+04
60 cristobalite -2.05 -2.53 -0.48 -0.161 0.10251E+04
63 cymrite-K -0.14 -3.97 -3.83 -0.319 0.81446E+04
65 diaspore 0.11 -0.16 -0.27 -0.045 0.57853E+03
66 diamond -2.17 -5.07 -2.89 -0.826 0.61536E+04
69 dolomite,ordered -1.75 -2.52 -0.78 -0.130 0.16589E+04
83 gibbsite 1.36 -0.18 -1.54 -0.220 0.32823E+04
86 goethite 4.52 2.94 -1.58 -0.341 0.33585E+04
87 graphite -2.56 -5.07 -2.50 -0.715 0.53261E+04
90 halite 1.38 -0.45 -1.84 -0.918 0.39066E+04
91 hematite 8.41 5.91 -2.50 -0.303 0.53295E+04
92 heulandite -8.85 -11.58 -2.73 -0.124 0.58049E+04
93 hercynite 7.93 3.22 -4.72 -0.314 0.10043E+05
96 jadeite 1.79 0.01 -1.78 -0.178 0.37941E+04
98 kalsilite 4.38 1.12 -3.26 -0.466 0.69420E+04
99 kaolinite -5.03 -5.41 -0.38 -0.034 0.80209E+03
100 kyanite -1.00 -2.83 -1.83 -0.183 0.38952E+04
102 laumontite -1.66 -3.94 -2.28 -0.152 0.48561E+04
103 lawsonite 3.57 1.17 -2.40 -0.160 0.51173E+04
104 leucite 1.47 -1.41 -2.88 -0.288 0.61405E+04
107 magnesite -0.79 -1.79 -1.00 -0.335 0.21385E+04
108 magnetite 13.58 9.43 -4.16 -0.339 0.88499E+04
114 margarite 4.14 0.89 -3.25 -0.130 0.69270E+04
117 microcline -3.54 -3.95 -0.41 -0.031 0.86412E+03
120 mullite-Si 0.75 -2.83 -3.59 -0.359 0.76341E+04
121 muscovite -4.02 -4.27 -0.25 -0.015 0.52654E+03
123 nepheline 4.84 2.54 -2.30 -0.328 0.48892E+04
129 periclase-Fe 8.46 3.52 -4.94 -1.235 0.10515E+05
143 pyrite -19.29 -20.72 -1.43 -0.335 0.30341E+04
144 pyrrhotite -4.94 -8.04 -3.10 -1.035 0.66079E+04
145 pyrrhotiteFe0.875 -6.28 -8.62 -2.34 -0.860 0.49783E+04
146 pyroxmangite 5.53 1.80 -3.73 -0.745 0.79308E+04
147 pyrophyllite -9.25 -10.46 -1.21 -0.076 0.25743E+04
148 quartz -2.36 -2.53 -0.18 -0.060 0.38031E+03
153 rhodochrosite -1.77 -2.98 -1.21 -0.403 0.25744E+04
154 rhodonite 5.55 1.80 -3.75 -0.750 0.79861E+04
155 sanidine -2.57 -3.95 -1.38 -0.106 0.29324E+04
157 siderite -3.45 -3.80 -0.35 -0.115 0.73501E+03
158 sillimanite -0.79 -2.83 -2.04 -0.204 0.43496E+04
165 stilbite -8.68 -11.60 -2.92 -0.139 0.62197E+04
168 stishovite 2.36 -2.53 -4.89 -1.630 0.10411E+05
170 sudoite 7.13 2.76 -4.38 -0.141 0.93212E+04
171 sulfur -8.50 -12.68 -4.18 -1.286 0.88948E+04
172 sylvite 1.41 -1.87 -3.28 -1.638 0.69722E+04
180 topaz-H -0.60 -2.86 -2.26 -0.205 0.48082E+04
181 tridymite -2.08 -2.53 -0.45 -0.150 0.96041E+03
184 troilite-low -5.00 -8.04 -3.04 -1.013 0.64723E+04
190 wairakite -1.43 -3.90 -2.47 -0.145 0.52545E+04
192 wollastonite 8.23 4.05 -4.18 -0.837 0.89051E+04
193 pseudo-wollastonite 8.61 4.05 -4.57 -0.913 0.97210E+04
196 argentite -22.30 -22.47 -0.17 -0.043 0.36431E+03
197 arsenic -5.52 -9.72 -4.20 -1.084 0.89420E+04
199 arsenopyrite -13.42 -17.76 -4.34 -0.772 0.92401E+04
200 beidellite-Ca -6.53 -8.58 -2.05 -0.127 0.43686E+04
201 beidellite-H -6.99 -9.67 -2.68 -0.171 0.57133E+04
202 beidellite-K -6.09 -8.41 -2.33 -0.142 0.49535E+04
203 beidellite-Mg -6.77 -8.76 -1.99 -0.123 0.42308E+04
204 beidellite-Na -6.00 -7.95 -1.94 -0.119 0.41350E+04
205 bornite -72.89 -74.17 -1.28 -0.096 0.27222E+04
207 chalcedony -2.21 -2.53 -0.33 -0.109 0.69931E+03
208 chalcocite -22.24 -23.92 -1.67 -0.418 0.35615E+04
210 covellite -16.36 -18.30 -1.94 -0.738 0.41245E+04
211 dawsonite -0.10 -2.26 -2.17 -0.271 0.46103E+04
213 montmorillonite-Ca -5.64 -7.50 -1.85 -0.115 0.39484E+04
214 montmorillonite-K -5.30 -7.33 -2.03 -0.124 0.43170E+04
215 montmorillonite-Mg -5.88 -7.67 -1.79 -0.111 0.38180E+04
216 montmorillonite-Na -5.14 -6.86 -1.72 -0.105 0.36624E+04
217 nontronite-Ca 0.73 -2.37 -3.11 -0.202 0.66161E+04
218 nontronite-H 0.27 -3.46 -3.74 -0.250 0.79520E+04
219 nontronite-K 1.18 -2.20 -3.38 -0.217 0.72000E+04
220 nontronite-Mg 0.52 -2.55 -3.07 -0.199 0.65407E+04
221 nontronite-Na 1.26 -1.74 -3.00 -0.192 0.63846E+04
225 topaz -20.20 -20.20 0.00 0.000 0.51925E+01
229 gypsum -5.71 -9.51 -3.80 -0.950 0.80923E+04
245 acanthite -22.12 -22.47 -0.35 -0.086 0.73533E+03
251 barite -9.67 -12.35 -2.68 -1.340 0.57055E+04
252 boehmite 1.18 -0.16 -1.34 -0.224 0.28594E+04
253 cerussite -2.83 -6.02 -3.19 -1.063 0.67898E+04
254 chalcopyrite -24.82 -26.34 -1.52 -0.282 0.32277E+04
256 copper,native -1.61 -5.62 -4.00 -1.392 0.85218E+04
257 dolomite,disordered -1.30 -2.52 -1.22 -0.204 0.26020E+04
258 ferrous-oxide 6.96 3.52 -3.45 -0.862 0.73380E+04
259 fluorite -10.25 -10.78 -0.53 -0.177 0.11321E+04
261 gold,native -13.64 -15.32 -1.68 -0.584 0.35772E+04
262 silver,native -4.32 -4.89 -0.57 -0.198 0.12100E+04
263 huntite -1.97 -6.11 -4.14 -0.345 0.88078E+04
269 silica-amorphous -1.69 -2.53 -0.85 -0.282 0.18007E+04
270 smithsonite -1.83 -5.47 -3.64 -1.215 0.77593E+04
273 wurtzite -8.25 -9.72 -1.47 -0.489 0.31240E+04
274 zincite 5.84 1.84 -4.00 -0.999 0.85104E+04
275 an20ab80 -0.93 -1.78 -0.85 -0.066 0.18139E+04
276 an25ab75 -0.61 -1.59 -0.99 -0.076 0.20975E+04
277 an30ab70 -0.28 -1.41 -1.12 -0.086 0.23927E+04
Calculations done for 192.0845 Deg. C; 500.0000 bar
Mixer fraction: 0.0500000
Temperature Stoc.ionic strength Heat per mole
Actual solution: 192.085 .16609E+01 3.623
Mixing solution: 25.000 .50000E-10 0.646
Fract. of mixing solution added: 0.050000
BITMOL = 0.2775E+01 OLDMOL = 0.5983E+02
New heat: 3.491 New temperature: 184.873
New mixer fraction: 0.1000000
Resulting temperature: 184.873Deg. C
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1296E-03
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 7 Loop limit = 70
Temperature = 184.87 C Pressure = 500.00 bar Mixer fraction = 0.1000000
Water: Moles liquid = 0.6119E+02 kg liquid = 0.1102E+01
Moles total = 0.6087E+02 kg total = 0.1097E+01 Activity = 0.9551
Stoichiometric ionic strength = .1585132E+01 Osmotic coef. = 0.9098
True ionic strength = .1157677E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.79479E-05 -5.0997 0.39417E-05 -5.4043 0.49594E+00 -0.3046
2 H2O 0.95508E+00 -0.0200 0.95508E+00 -0.0200
3 Cl- 0.11307E+01 0.0533 0.59352E+00 -0.2266 0.52493E+00 -0.2799
4 SO4-- 0.15389E-03 -3.8128 0.75718E-05 -5.1208 0.49202E-01 -1.3080
5 HCO3- 0.24039E-01 -1.6191 0.13068E-01 -1.8838 0.54364E+00 -0.2647
6 HS- 0.12676E-05 -5.8970 0.66791E-06 -6.1753 0.52692E+00 -0.2783
7 H4SiO4 0.25394E-02 -2.5953 0.25394E-02 -2.5953 0.10000E+01 0.0000
8 Al+++ 0.84058E-13 -13.0754 0.76126E-16 -16.1185 0.90564E-03 -3.0430
9 Ca++ 0.12071E-02 -2.9182 0.52503E-04 -4.2798 0.43494E-01 -1.3616
10 Mg++ 0.11466E-03 -3.9406 0.45369E-05 -5.3432 0.39567E-01 -1.4027
11 Fe++ 0.11091E-05 -5.9550 0.44932E-07 -7.3474 0.40512E-01 -1.3924
12 K+ 0.40076E-01 -1.3971 0.21975E-01 -1.6581 0.54834E+00 -0.2609
13 Na+ 0.11126E+01 0.0464 0.58463E+00 -0.2331 0.52544E+00 -0.2795
14 Mn++ 0.77725E-05 -5.1094 0.32041E-06 -6.4943 0.41224E-01 -1.3848
15 Zn++ 0.27226E-07 -7.5650 0.11030E-08 -8.9574 0.40512E-01 -1.3924
16 Cu+ 0.45232E-11 -11.3446 0.23737E-11 -11.6246 0.52478E+00 -0.2800
17 Pb++ 0.57124E-08 -8.2432 0.26294E-09 -9.5801 0.46030E-01 -1.3370
18 Ag+ 0.24387E-10 -10.6128 0.13267E-10 -10.8772 0.54404E+00 -0.2644
19 Au+ 0.57903E-21 -21.2373 0.31891E-21 -21.4963 0.55077E+00 -0.2590
20 Ba++ 0.15188E-05 -5.8185 0.72500E-07 -7.1397 0.47735E-01 -1.3212
21 F- 0.11938E-02 -2.9231 0.58573E-03 -3.2323 0.49064E+00 -0.3092
22 H2AsO3- 0.11446E-05 -5.9414 0.77909E-06 -6.1084 0.68068E+00 -0.1671
24 HSiO3- 0.27573E-05 -5.5595 0.14474E-05 -5.8394 0.52493E+00 -0.2799
25 Ca(HSiO3)+ 0.13116E-07 -7.8822 0.72239E-08 -8.1412 0.55077E+00 -0.2590
26 Mg(HSiO3)+ 0.99951E-09 -9.0002 0.55051E-09 -9.2592 0.55077E+00 -0.2590
27 NaHSiO3,aq 0.67643E-05 -5.1698 0.67643E-05 -5.1698 0.10000E+01 0.0000
31 AgCl,aq 0.43784E-08 -8.3587 0.43784E-08 -8.3587 0.10000E+01 0.0000
32 AgCl2- 0.20513E-06 -6.6880 0.10768E-06 -6.9679 0.52493E+00 -0.2799
33 AgCl3-2 0.14281E-06 -6.8452 0.67631E-08 -8.1699 0.47356E-01 -1.3246
34 AgCl4-3 0.25360E-07 -7.5959 0.22442E-10 -10.6489 0.88496E-03 -3.0531
38 Ag(HS),aq 0.97425E-08 -8.0113 0.97425E-08 -8.0113 0.10000E+01 0.0000
40 AlO+ 0.24202E-09 -9.6162 0.13330E-09 -9.8752 0.55077E+00 -0.2590
42 HAlO2,aq 0.52450E-07 -7.2803 0.52450E-07 -7.2803 0.10000E+01 0.0000
43 AlO2- 0.48857E-06 -6.3111 0.24230E-06 -6.6156 0.49594E+00 -0.3046
44 AsO2- 0.19972E-06 -6.6996 0.10484E-06 -6.9795 0.52493E+00 -0.2799
45 HAsO2,aq 0.31282E-04 -4.5047 0.31282E-04 -4.5047 0.10000E+01 0.0000
46 H3AsO3,aq 0.84973E-04 -4.0707 0.84973E-04 -4.0707 0.10000E+01 0.0000
48 H2AsO4- 0.10577E-09 -9.9756 0.55523E-10 -10.2555 0.52493E+00 -0.2799
49 HAsO4-2 0.23653E-10 -10.6261 0.11201E-11 -11.9507 0.47356E-01 -1.3246
62 BaCO3,aq 0.43660E-09 -9.3599 0.43660E-09 -9.3599 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.13496E-05 -5.8698 0.75850E-06 -6.1200 0.56203E+00 -0.2502
64 BaCl+ 0.81719E-06 -6.0877 0.45009E-06 -6.3467 0.55077E+00 -0.2590
65 BaF+ 0.90306E-09 -9.0443 0.49738E-09 -9.3033 0.55077E+00 -0.2590
66 CH4,aq 0.12720E-08 -8.8955 0.11616E-08 -8.9349 0.91321E+00 -0.0394
71 CO,aq 0.23201E-08 -8.6345 0.23201E-08 -8.6345 0.10000E+01 0.0000
72 CO2,aq 0.29321E+00 -0.5328 0.26776E+00 -0.5723 0.91321E+00 -0.0394
73 CO3-2 0.54790E-05 -5.2613 0.25946E-06 -6.5859 0.47356E-01 -1.3246
74 CaCO3,aq 0.12586E-05 -5.9001 0.12586E-05 -5.9001 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.15892E-03 -3.7988 0.87532E-04 -4.0578 0.55077E+00 -0.2590
76 CaCl+ 0.49470E-03 -3.3057 0.27247E-03 -3.5647 0.55077E+00 -0.2590
77 CaCl2,aq 0.42417E-04 -4.3725 0.42417E-04 -4.3725 0.10000E+01 0.0000
78 CaF+ 0.46499E-05 -5.3326 0.25610E-05 -5.5916 0.55077E+00 -0.2590
79 CaOH+ 0.12978E-06 -6.8868 0.71481E-07 -7.1458 0.55077E+00 -0.2590
80 CaSO4,aq 0.46856E-06 -6.3292 0.46856E-06 -6.3292 0.10000E+01 0.0000
81 HCl,aq 0.13044E-05 -5.8846 0.13044E-05 -5.8846 0.10000E+01 0.0000
90 CuCl,aq 0.65807E-08 -8.1817 0.65807E-08 -8.1817 0.10000E+01 0.0000
91 CuCl2- 0.12092E-06 -6.9175 0.63474E-07 -7.1974 0.52493E+00 -0.2799
92 CuCl3-2 0.26848E-07 -7.5711 0.12714E-08 -8.8957 0.47356E-01 -1.3246
98 HF,aq 0.79934E-04 -4.0973 0.79934E-04 -4.0973 0.10000E+01 0.0000
99 HF2- 0.25131E-07 -7.5998 0.13192E-07 -7.8797 0.52493E+00 -0.2799
101 FeCl+ 0.31873E-06 -6.4966 0.17555E-06 -6.7556 0.55077E+00 -0.2590
102 FeCl2,aq 0.21097E-08 -8.6758 0.21097E-08 -8.6758 0.10000E+01 0.0000
104 FeF+ 0.81401E-08 -8.0894 0.44833E-08 -8.3484 0.55077E+00 -0.2590
106 FeO,aq 0.87747E-10 -10.0568 0.87747E-10 -10.0568 0.10000E+01 0.0000
107 FeOH+ 0.16143E-07 -7.7920 0.88910E-08 -8.0511 0.55077E+00 -0.2590
112 HFeO2,aq 0.72036E-10 -10.1424 0.72036E-10 -10.1424 0.10000E+01 0.0000
113 H2,aq 0.19530E-06 -6.7093 0.17835E-06 -6.7487 0.91321E+00 -0.0394
114 KCl,aq 0.11421E-02 -2.9423 0.11421E-02 -2.9423 0.10000E+01 0.0000
115 KHSO4,aq 0.19781E-09 -9.7038 0.19781E-09 -9.7038 0.10000E+01 0.0000
116 KOH,aq 0.46426E-07 -7.3332 0.46426E-07 -7.3332 0.10000E+01 0.0000
117 KSO4- 0.16190E-04 -4.7908 0.84984E-05 -5.0707 0.52493E+00 -0.2799
118 MgCO3,aq 0.15585E-07 -7.8073 0.15585E-07 -7.8073 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.13371E-04 -4.8738 0.73646E-05 -5.1329 0.55077E+00 -0.2590
120 MgCl+ 0.26503E-04 -4.5767 0.14597E-04 -4.8357 0.55077E+00 -0.2590
121 MgF+ 0.12216E-05 -5.9131 0.67283E-06 -6.1721 0.55077E+00 -0.2590
122 MgOH+ 0.40257E-07 -7.3952 0.22172E-07 -7.6542 0.55077E+00 -0.2590
124 MnF+ 0.22765E-07 -7.6427 0.12538E-07 -7.9018 0.55077E+00 -0.2590
125 MnO,aq 0.19571E-10 -10.7084 0.19571E-10 -10.7084 0.10000E+01 0.0000
126 MnOH+ 0.14871E-07 -7.8276 0.81908E-08 -8.0867 0.55077E+00 -0.2590
131 MnCl+ 0.23461E-04 -4.6296 0.12922E-04 -4.8887 0.55077E+00 -0.2590
132 MnSO4,aq 0.32936E-08 -8.4823 0.32936E-08 -8.4823 0.10000E+01 0.0000
133 NaCl,aq 0.26941E+00 -0.5696 0.26941E+00 -0.5696 0.10000E+01 0.0000
134 NaF,aq 0.19925E-03 -3.7006 0.19925E-03 -3.7006 0.10000E+01 0.0000
135 NaOH,aq 0.92017E-06 -6.0361 0.92017E-06 -6.0361 0.10000E+01 0.0000
137 OH- 0.32569E-05 -5.4872 0.16152E-05 -5.7918 0.49594E+00 -0.3046
140 PbCl+ 0.65214E-07 -7.1857 0.35918E-07 -7.4447 0.55077E+00 -0.2590
141 PbCl2,aq 0.28275E-06 -6.5486 0.28275E-06 -6.5486 0.10000E+01 0.0000
142 PbCl3- 0.21839E-06 -6.6608 0.11464E-06 -6.9407 0.52493E+00 -0.2799
143 PbCl4-2 0.30829E-06 -6.5110 0.14599E-07 -7.8357 0.47356E-01 -1.3246
144 PbF+ 0.95610E-10 -10.0195 0.52659E-10 -10.2785 0.55077E+00 -0.2590
146 PbO,aq 0.37307E-10 -10.4282 0.37307E-10 -10.4282 0.10000E+01 0.0000
148 Pb(HS)2,aq 0.17128E-09 -9.7663 0.17128E-09 -9.7663 0.10000E+01 0.0000
150 H2S,aq 0.10377E-04 -4.9839 0.94760E-05 -5.0234 0.91321E+00 -0.0394
158 HSO3- 0.20654E-09 -9.6850 0.10842E-09 -9.9649 0.52493E+00 -0.2799
159 HSO4- 0.61358E-06 -6.2121 0.34358E-06 -6.4640 0.55996E+00 -0.2518
161 S2O3-2 0.22146E-10 -10.6547 0.10487E-11 -11.9793 0.47356E-01 -1.3246
173 ZnCl+ 0.46833E-05 -5.3294 0.25794E-05 -5.5885 0.55077E+00 -0.2590
174 ZnCl2,aq 0.11963E-05 -5.9222 0.11963E-05 -5.9222 0.10000E+01 0.0000
175 ZnCl3- 0.16190E-06 -6.7908 0.84985E-07 -7.0707 0.52493E+00 -0.2799
176 ZnF+ 0.13324E-09 -9.8754 0.73386E-10 -10.1344 0.55077E+00 -0.2590
177 ZnO,aq 0.28713E-09 -9.5419 0.28713E-09 -9.5419 0.10000E+01 0.0000
178 ZnOH+ 0.22217E-06 -6.6533 0.12237E-06 -6.9123 0.55077E+00 -0.2590
Charge balance for all species = -.1176E-03
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.7947919E-05 0.2934000E+00 0.2693698E+03 0.0000
2 H2O 0.1000000E+01 0.5521501E+02 0.9060512E+06 0.0000
3 Cl- 0.1130665E+01 0.1401859E+01 0.4527008E+05 5.1777
4 SO4-- 0.1538930E-03 0.1711179E-03 0.1497267E+02 5.6878
5 HCO3- 0.2403856E-01 0.3174256E+00 0.1764202E+05 3.5205
6 HS- 0.1267570E-05 0.1170496E-04 0.3526017E+00 -0.7710
7 H4SiO4 0.2539400E-02 0.2548935E-02 0.2231546E+03 -2.5953
8 Al+++ 0.8405785E-13 0.5412687E-06 0.1330249E-01 0.0945
9 Ca++ 0.1207122E-02 0.1909684E-02 0.6971426E+02 6.5288
10 Mg++ 0.1146644E-03 0.1558177E-03 0.3450575E+01 5.4654
11 Fe++ 0.1109097E-05 0.1454385E-05 0.7398325E-01 3.4612
12 K+ 0.4007569E-01 0.4123401E-01 0.1468617E+04 3.7462
13 Na+ 0.1112648E+01 0.1382263E+01 0.2894542E+05 5.1712
14 Mn++ 0.7772453E-05 0.3127478E-04 0.1565025E+01 4.3143
15 Zn++ 0.2722563E-07 0.6291336E-05 0.3746066E+00 1.8512
16 Cu+ 0.4523186E-11 0.1543524E-06 0.8933357E-02 -6.2203
17 Pb++ 0.5712385E-08 0.8806558E-06 0.1661993E+00 1.2285
18 Ag+ 0.2438663E-10 0.3874551E-06 0.3806941E-01 -5.4729
19 Au+ 0.5790294E-21 0.2822005E-11 0.5062970E-06 -16.0920
20 Ba++ 0.1518785E-05 0.3686886E-05 0.4612229E+00 3.6690
21 F- 0.1193822E-02 0.1478963E-02 0.2559289E+02 2.1720
22 H2AsO3- 0.1144580E-05 0.1175986E-03 0.1338267E+02 -0.7041
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234423E+00 -.7162131E-05 0.0000000E+00
2 H2O 0.6086868E+02 0.6086868E+02 0.0000000E+00 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1290347E-04 0.1126838E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2809930E-02 0.1810588E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.5966912E-06 0.1810588E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.6035292E-06 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.6935529E-05 0.5326473E-06 0.0000000E+00
16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00
17 Pb++ 0.1565021E-05 0.9708294E-06 0.5941912E-06 0.0000000E+00
18 Ag+ 0.4271281E-06 0.4271281E-06 0.0000000E+00 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1630400E-02 0.0000000E+00 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: 0.1271E-20 Mass of aqueous solution: 0.121027E+04 g
Temperature = 184.87 C Pressure = 500.00 bar Mixer frac. = 0.1000000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
paragonite 0.6035E-06 -6.219 0.2307E-03 -3.637 54.31 0.7973E-04
galena 0.5942E-06 -6.226 0.1422E-03 -3.847 33.47 0.1871E-04
sphalerite 0.5326E-06 -6.274 0.5190E-04 -4.285 12.22 0.1269E-04
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
paragonite 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.1000000
Solid products produced: Mass = 0.000425 g Volume = 0.000111 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.300
AFFINITY: 0.2990E+03
GOLD Q/K: 0.0248
SILVER Q/K: 0.3433
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 184.8730 deg.C
Sat. pressure: 88.3608 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.2168E+00 0.6609 0.1266E+02 0.1915E+02
CO2,gas 0.7832E+00 0.9036 0.6253E+02 0.6921E+02
CH4,gas 0.1999E-07 1.1161 0.1971E-05 0.1766E-05
H2,gas 0.2080E-05 1.0391 0.1910E-03 0.1838E-03
H2S,gas 0.7198E-05 0.8338 0.5304E-03 0.6361E-03
S2,gas 0.9251E-16 1.0000 0.8174E-14 0.8174E-14
CO,gas 0.3229E-07 1.0000 0.2854E-05 0.2854E-05
SO3,gas 0.3803E-26 1.0000 0.3361E-24 0.3361E-24
O2,gas 0.1903E-42 1.0000 0.1681E-40 0.1681E-40
SO2,gas 0.4176E-12 1.0000 0.3690E-10 0.3690E-10
HF,gas 0.3811E-07 1.0000 0.3368E-05 0.3368E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
122 paragonite -2.33 -2.33 0.00 0.000 -0.93074E-11
260 galena -10.35 -10.35 0.00 0.000 0.00000E+00
272 sphalerite -9.73 -9.73 0.00 0.000 0.00000E+00
196 argentite -22.66 -22.53 0.13 0.033 -0.27584E+03
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.58 -0.02 -1.60 -1.597 0.33462E+04 1.102
2 CO2,gas -6.37 -7.27 -0.90 -0.301 0.18923E+04 1.796
3 CH4,gas 5.45 -2.96 -8.40 -2.101 0.17614E+05 -5.705
4 H2,gas 7.49 1.07 -6.42 -3.667 0.13451E+05 -3.719
5 H2S,gas -5.61 -11.58 -5.97 -2.987 0.12521E+05 -3.275
6 S2,gas -8.51 -25.29 -16.79 -2.583 0.35182E+05 -14.088
7 CO,gas 2.06 -6.18 -8.24 -2.536 0.17277E+05 -5.545
8 SO3,gas 11.26 -15.91 -27.17 -6.793 0.56949E+05 -24.474
9 O2,gas 41.30 -2.17 -43.47 -28.982 0.91113E+05 -40.774
10 SO2,gas -1.69 -14.82 -13.13 -3.502 0.27522E+05 -10.433
11 HF,gas -0.46 -8.64 -8.17 -4.086 0.17126E+05 -5.473
12 HCl,gas 1.07 -5.63 -6.70 -3.352 0.14051E+05 -6.704
13 acmite 6.21 2.95 -3.27 -0.339 0.68460E+04
17 albite-high -1.24 -2.44 -1.20 -0.092 0.25107E+04
18 albite -1.96 -2.44 -0.48 -0.037 0.10089E+04
22 analcite 1.14 0.10 -1.05 -0.116 0.21945E+04
23 andalusite -0.53 -2.43 -1.89 -0.189 0.39639E+04
26 anhydrite -6.54 -9.40 -2.87 -1.433 0.60050E+04
27 ankerite -3.79 -4.59 -0.80 -0.133 0.16720E+04
31 anorthite 5.40 1.53 -3.88 -0.298 0.81258E+04
34 aragonite 0.02 -0.76 -0.78 -0.260 0.16377E+04
35 brucite 9.88 5.43 -4.46 -0.892 0.93443E+04
36 calcite -0.12 -0.76 -0.64 -0.214 0.13458E+04
37 carnegieite-low 5.67 2.67 -3.00 -0.429 0.62969E+04
38 carnegieite-high 6.40 2.67 -3.73 -0.532 0.78122E+04
39 carpholite-Mg 2.57 0.42 -2.15 -0.143 0.45063E+04
40 carpholite-Fe 1.01 -1.58 -2.59 -0.172 0.54216E+04
41 celadonite 2.81 -1.00 -3.81 -0.224 0.79758E+04
42 celadonite-Fe 1.48 -3.00 -4.48 -0.264 0.93949E+04
49 chloritoid-Mg 5.89 3.00 -2.89 -0.193 0.60600E+04
50 chloritoid-Fe 2.67 0.99 -1.67 -0.112 0.35100E+04
51 chloritoid-Mn 4.86 1.85 -3.01 -0.201 0.63165E+04
53 coesite -1.89 -2.56 -0.67 -0.222 0.13980E+04
58 corundum 2.16 0.13 -2.03 -0.185 0.42620E+04
60 cristobalite -2.08 -2.56 -0.48 -0.159 0.99673E+03
63 cymrite-K 0.00 -3.89 -3.89 -0.324 0.81434E+04
65 diaspore 0.31 0.05 -0.25 -0.042 0.52664E+03
66 diamond -2.23 -5.09 -2.86 -0.818 0.60009E+04
69 dolomite,ordered -1.55 -2.58 -1.03 -0.172 0.21677E+04
83 gibbsite 1.55 0.03 -1.51 -0.216 0.31691E+04
86 goethite 4.65 2.89 -1.77 -0.382 0.36993E+04
87 graphite -2.62 -5.09 -2.47 -0.706 0.51808E+04
90 halite 1.41 -0.46 -1.87 -0.935 0.39202E+04
91 hematite 8.70 5.79 -2.91 -0.352 0.60947E+04
92 heulandite -8.60 -11.37 -2.77 -0.126 0.58079E+04
96 jadeite 1.96 0.12 -1.85 -0.185 0.38721E+04
98 kalsilite 4.61 1.25 -3.37 -0.481 0.70554E+04
99 kaolinite -4.76 -5.02 -0.26 -0.024 0.55173E+03
100 kyanite -0.58 -2.43 -1.84 -0.184 0.38593E+04
102 laumontite -1.31 -3.66 -2.35 -0.157 0.49257E+04
103 lawsonite 4.00 1.49 -2.52 -0.168 0.52734E+04
104 leucite 1.67 -1.31 -2.98 -0.298 0.62466E+04
107 magnesite -0.67 -1.82 -1.15 -0.385 0.24180E+04
108 magnetite 14.03 9.24 -4.80 -0.392 0.10053E+05
114 margarite 5.08 1.64 -3.45 -0.138 0.72244E+04
117 microcline -3.44 -3.87 -0.42 -0.033 0.88917E+03
120 mullite-Si 1.21 -2.43 -3.64 -0.364 0.76300E+04
121 muscovite -3.53 -3.76 -0.23 -0.013 0.47407E+03
123 nepheline 5.08 2.67 -2.41 -0.345 0.50553E+04
143 pyrite -19.37 -20.77 -1.40 -0.329 0.29295E+04
144 pyrrhotite -4.86 -8.12 -3.25 -1.085 0.68195E+04
145 pyrrhotiteFe0.875 -6.24 -8.68 -2.45 -0.900 0.51311E+04
146 pyroxmangite 5.66 1.74 -3.92 -0.783 0.82076E+04
147 pyrophyllite -9.00 -10.11 -1.11 -0.069 0.23295E+04
148 quartz -2.39 -2.56 -0.16 -0.054 0.34086E+03
153 rhodochrosite -1.69 -2.97 -1.28 -0.427 0.26834E+04
154 rhodonite 5.68 1.74 -3.94 -0.789 0.82658E+04
155 sanidine -2.45 -3.87 -1.41 -0.109 0.29579E+04
157 siderite -3.37 -3.83 -0.46 -0.152 0.95722E+03
158 sillimanite -0.36 -2.43 -2.07 -0.207 0.43350E+04
165 stilbite -8.55 -11.39 -2.84 -0.135 0.59544E+04
168 stishovite 2.38 -2.56 -4.93 -1.645 0.10343E+05
170 sudoite 8.13 3.40 -4.72 -0.152 0.98979E+04
171 sulfur -8.52 -12.65 -4.13 -1.271 0.86585E+04
172 sylvite 1.42 -1.88 -3.30 -1.652 0.69253E+04
180 topaz-H -0.23 -2.45 -2.22 -0.202 0.46546E+04
181 tridymite -2.11 -2.56 -0.44 -0.148 0.93011E+03
184 troilite-low -4.93 -8.12 -3.18 -1.062 0.66746E+04
190 wairakite -1.02 -3.62 -2.61 -0.153 0.54618E+04
192 wollastonite 8.38 3.95 -4.43 -0.886 0.92856E+04
193 pseudo-wollastonite 8.78 3.95 -4.82 -0.965 0.10109E+05
197 arsenic -5.63 -9.85 -4.22 -1.088 0.88385E+04
199 arsenopyrite -13.50 -17.97 -4.47 -0.795 0.93667E+04
200 beidellite-Ca -6.16 -8.17 -2.01 -0.124 0.42173E+04
201 beidellite-H -6.63 -9.25 -2.62 -0.167 0.54835E+04
202 beidellite-K -5.74 -8.01 -2.28 -0.139 0.47702E+04
203 beidellite-Mg -6.40 -8.35 -1.95 -0.121 0.40902E+04
204 beidellite-Na -5.65 -7.54 -1.89 -0.116 0.39702E+04
205 bornite -73.81 -74.49 -0.68 -0.051 0.14351E+04
207 chalcedony -2.24 -2.56 -0.32 -0.105 0.66036E+03
208 chalcocite -22.58 -24.02 -1.44 -0.360 0.30153E+04
210 covellite -16.57 -18.33 -1.77 -0.674 0.37065E+04
211 dawsonite 0.04 -2.06 -2.10 -0.263 0.44022E+04
213 montmorillonite-Ca -5.38 -7.26 -1.88 -0.116 0.39403E+04
214 montmorillonite-K -5.06 -7.10 -2.05 -0.125 0.42864E+04
215 montmorillonite-Mg -5.62 -7.44 -1.82 -0.113 0.38193E+04
216 montmorillonite-Na -4.90 -6.63 -1.74 -0.106 0.36404E+04
217 nontronite-Ca 0.93 -2.51 -3.44 -0.223 0.72082E+04
218 nontronite-H 0.45 -3.59 -4.04 -0.271 0.84659E+04
219 nontronite-K 1.35 -2.35 -3.70 -0.238 0.77609E+04
220 nontronite-Mg 0.72 -2.68 -3.41 -0.221 0.71432E+04
221 nontronite-Na 1.44 -1.88 -3.32 -0.213 0.69633E+04
225 topaz -19.88 -19.68 0.20 0.022 -0.41360E+03
229 gypsum -5.62 -9.44 -3.82 -0.956 0.80148E+04
245 acanthite -22.48 -22.53 -0.04 -0.011 0.89386E+02
251 barite -9.60 -12.26 -2.66 -1.328 0.55681E+04
252 boehmite 1.41 0.05 -1.35 -0.225 0.28347E+04
253 cerussite -2.80 -6.06 -3.26 -1.085 0.68225E+04
254 chalcopyrite -25.01 -26.45 -1.44 -0.268 0.30221E+04
255 chlorargyrite -6.18 -11.10 -4.92 -2.460 0.10313E+05
256 copper,native -1.71 -5.69 -3.98 -1.384 0.83374E+04
257 dolomite,disordered -1.09 -2.58 -1.49 -0.249 0.31317E+04
258 ferrous-oxide 7.15 3.44 -3.71 -0.928 0.77826E+04
259 fluorite -10.18 -10.74 -0.56 -0.188 0.11812E+04
261 gold,native -13.95 -15.56 -1.61 -0.559 0.33663E+04
262 silver,native -4.47 -4.94 -0.46 -0.161 0.97305E+03
263 huntite -1.50 -6.23 -4.72 -0.394 0.98990E+04
269 silica-amorphous -1.71 -2.56 -0.85 -0.283 0.17766E+04
270 smithsonite -1.73 -5.44 -3.70 -1.234 0.77619E+04
273 wurtzite -8.24 -9.73 -1.49 -0.497 0.31243E+04
274 zincite 5.99 1.83 -4.16 -1.040 0.87195E+04
275 an20ab80 -0.70 -1.65 -0.94 -0.073 0.19771E+04
276 an25ab75 -0.36 -1.45 -1.09 -0.084 0.22765E+04
277 an30ab70 -0.02 -1.25 -1.23 -0.095 0.25879E+04
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 70
Temperature = 184.87 C Pressure = 500.00 bar Mixer fraction = 0.1000000
Water: Moles liquid = 0.6119E+02 kg liquid = 0.1102E+01
Moles total = 0.6087E+02 kg total = 0.1097E+01 Activity = 0.9551
Stoichiometric ionic strength = .1585132E+01 Osmotic coef. = 0.9098
True ionic strength = .1157677E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.79479E-05 -5.0997 0.39417E-05 -5.4043 0.49594E+00 -0.3046
2 H2O 0.95508E+00 -0.0200 0.95508E+00 -0.0200
3 Cl- 0.11307E+01 0.0533 0.59352E+00 -0.2266 0.52493E+00 -0.2799
4 SO4-- 0.15389E-03 -3.8128 0.75718E-05 -5.1208 0.49202E-01 -1.3080
5 HCO3- 0.24039E-01 -1.6191 0.13068E-01 -1.8838 0.54364E+00 -0.2647
6 HS- 0.12658E-05 -5.8976 0.66700E-06 -6.1759 0.52692E+00 -0.2783
7 H4SiO4 0.25394E-02 -2.5953 0.25394E-02 -2.5953 0.10000E+01 0.0000
8 Al+++ 0.84058E-13 -13.0754 0.76127E-16 -16.1185 0.90564E-03 -3.0430
9 Ca++ 0.12071E-02 -2.9182 0.52503E-04 -4.2798 0.43494E-01 -1.3616
10 Mg++ 0.11466E-03 -3.9406 0.45369E-05 -5.3432 0.39567E-01 -1.4027
11 Fe++ 0.11091E-05 -5.9550 0.44932E-07 -7.3474 0.40512E-01 -1.3924
12 K+ 0.40076E-01 -1.3971 0.21975E-01 -1.6581 0.54834E+00 -0.2609
13 Na+ 0.11126E+01 0.0464 0.58463E+00 -0.2331 0.52544E+00 -0.2795
14 Mn++ 0.77725E-05 -5.1094 0.32041E-06 -6.4943 0.41224E-01 -1.3848
15 Zn++ 0.27263E-07 -7.5644 0.11045E-08 -8.9568 0.40512E-01 -1.3924
16 Cu+ 0.45232E-11 -11.3446 0.23737E-11 -11.6246 0.52478E+00 -0.2800
17 Pb++ 0.57202E-08 -8.2426 0.26330E-09 -9.5795 0.46030E-01 -1.3370
18 Ag+ 0.20972E-10 -10.6784 0.11410E-10 -10.9427 0.54404E+00 -0.2644
19 Au+ 0.57981E-21 -21.2367 0.31934E-21 -21.4957 0.55077E+00 -0.2590
20 Ba++ 0.15188E-05 -5.8185 0.72500E-07 -7.1397 0.47735E-01 -1.3212
21 F- 0.11938E-02 -2.9231 0.58573E-03 -3.2323 0.49064E+00 -0.3092
22 H2AsO3- 0.11446E-05 -5.9414 0.77909E-06 -6.1084 0.68068E+00 -0.1671
24 HSiO3- 0.27573E-05 -5.5595 0.14474E-05 -5.8394 0.52493E+00 -0.2799
25 Ca(HSiO3)+ 0.13116E-07 -7.8822 0.72239E-08 -8.1412 0.55077E+00 -0.2590
26 Mg(HSiO3)+ 0.99951E-09 -9.0002 0.55051E-09 -9.2592 0.55077E+00 -0.2590
27 NaHSiO3,aq 0.67643E-05 -5.1698 0.67643E-05 -5.1698 0.10000E+01 0.0000
31 AgCl,aq 0.37653E-08 -8.4242 0.37653E-08 -8.4242 0.10000E+01 0.0000
32 AgCl2- 0.17641E-06 -6.7535 0.92602E-07 -7.0334 0.52493E+00 -0.2799
33 AgCl3-2 0.12282E-06 -6.9107 0.58162E-08 -8.2354 0.47356E-01 -1.3246
34 AgCl4-3 0.21809E-07 -7.6614 0.19300E-10 -10.7144 0.88496E-03 -3.0531
38 Ag(HS),aq 0.83669E-08 -8.0774 0.83669E-08 -8.0774 0.10000E+01 0.0000
40 AlO+ 0.24202E-09 -9.6162 0.13330E-09 -9.8752 0.55077E+00 -0.2590
42 HAlO2,aq 0.52450E-07 -7.2803 0.52450E-07 -7.2803 0.10000E+01 0.0000
43 AlO2- 0.48857E-06 -6.3111 0.24230E-06 -6.6156 0.49594E+00 -0.3046
44 AsO2- 0.19972E-06 -6.6996 0.10484E-06 -6.9795 0.52493E+00 -0.2799
45 HAsO2,aq 0.31282E-04 -4.5047 0.31282E-04 -4.5047 0.10000E+01 0.0000
46 H3AsO3,aq 0.84973E-04 -4.0707 0.84973E-04 -4.0707 0.10000E+01 0.0000
48 H2AsO4- 0.10581E-09 -9.9755 0.55542E-10 -10.2554 0.52493E+00 -0.2799
49 HAsO4-2 0.23661E-10 -10.6260 0.11205E-11 -11.9506 0.47356E-01 -1.3246
62 BaCO3,aq 0.43660E-09 -9.3599 0.43660E-09 -9.3599 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.13496E-05 -5.8698 0.75850E-06 -6.1200 0.56203E+00 -0.2502
64 BaCl+ 0.81719E-06 -6.0877 0.45009E-06 -6.3467 0.55077E+00 -0.2590
65 BaF+ 0.90306E-09 -9.0443 0.49738E-09 -9.3033 0.55077E+00 -0.2590
66 CH4,aq 0.12703E-08 -8.8961 0.11600E-08 -8.9355 0.91321E+00 -0.0394
71 CO,aq 0.23193E-08 -8.6346 0.23193E-08 -8.6346 0.10000E+01 0.0000
72 CO2,aq 0.29321E+00 -0.5328 0.26776E+00 -0.5723 0.91321E+00 -0.0394
73 CO3-2 0.54790E-05 -5.2613 0.25946E-06 -6.5859 0.47356E-01 -1.3246
74 CaCO3,aq 0.12586E-05 -5.9001 0.12586E-05 -5.9001 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.15892E-03 -3.7988 0.87531E-04 -4.0578 0.55077E+00 -0.2590
76 CaCl+ 0.49470E-03 -3.3057 0.27247E-03 -3.5647 0.55077E+00 -0.2590
77 CaCl2,aq 0.42417E-04 -4.3725 0.42417E-04 -4.3725 0.10000E+01 0.0000
78 CaF+ 0.46499E-05 -5.3326 0.25610E-05 -5.5916 0.55077E+00 -0.2590
79 CaOH+ 0.12978E-06 -6.8868 0.71481E-07 -7.1458 0.55077E+00 -0.2590
80 CaSO4,aq 0.46856E-06 -6.3292 0.46856E-06 -6.3292 0.10000E+01 0.0000
81 HCl,aq 0.13044E-05 -5.8846 0.13044E-05 -5.8846 0.10000E+01 0.0000
90 CuCl,aq 0.65807E-08 -8.1817 0.65807E-08 -8.1817 0.10000E+01 0.0000
91 CuCl2- 0.12092E-06 -6.9175 0.63474E-07 -7.1974 0.52493E+00 -0.2799
92 CuCl3-2 0.26848E-07 -7.5711 0.12714E-08 -8.8957 0.47356E-01 -1.3246
98 HF,aq 0.79934E-04 -4.0973 0.79934E-04 -4.0973 0.10000E+01 0.0000
99 HF2- 0.25131E-07 -7.5998 0.13192E-07 -7.8797 0.52493E+00 -0.2799
101 FeCl+ 0.31873E-06 -6.4966 0.17555E-06 -6.7556 0.55077E+00 -0.2590
102 FeCl2,aq 0.21097E-08 -8.6758 0.21097E-08 -8.6758 0.10000E+01 0.0000
104 FeF+ 0.81401E-08 -8.0894 0.44833E-08 -8.3484 0.55077E+00 -0.2590
106 FeO,aq 0.87747E-10 -10.0568 0.87747E-10 -10.0568 0.10000E+01 0.0000
107 FeOH+ 0.16143E-07 -7.7920 0.88910E-08 -8.0511 0.55077E+00 -0.2590
112 HFeO2,aq 0.72049E-10 -10.1424 0.72049E-10 -10.1424 0.10000E+01 0.0000
113 H2,aq 0.19523E-06 -6.7094 0.17829E-06 -6.7489 0.91321E+00 -0.0394
114 KCl,aq 0.11421E-02 -2.9423 0.11421E-02 -2.9423 0.10000E+01 0.0000
115 KHSO4,aq 0.19781E-09 -9.7038 0.19781E-09 -9.7038 0.10000E+01 0.0000
116 KOH,aq 0.46425E-07 -7.3332 0.46425E-07 -7.3332 0.10000E+01 0.0000
117 KSO4- 0.16190E-04 -4.7908 0.84984E-05 -5.0707 0.52493E+00 -0.2799
118 MgCO3,aq 0.15585E-07 -7.8073 0.15585E-07 -7.8073 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.13371E-04 -4.8738 0.73646E-05 -5.1329 0.55077E+00 -0.2590
120 MgCl+ 0.26503E-04 -4.5767 0.14597E-04 -4.8357 0.55077E+00 -0.2590
121 MgF+ 0.12216E-05 -5.9131 0.67283E-06 -6.1721 0.55077E+00 -0.2590
122 MgOH+ 0.40257E-07 -7.3952 0.22172E-07 -7.6542 0.55077E+00 -0.2590
124 MnF+ 0.22765E-07 -7.6427 0.12538E-07 -7.9018 0.55077E+00 -0.2590
125 MnO,aq 0.19571E-10 -10.7084 0.19571E-10 -10.7084 0.10000E+01 0.0000
126 MnOH+ 0.14871E-07 -7.8276 0.81908E-08 -8.0867 0.55077E+00 -0.2590
131 MnCl+ 0.23461E-04 -4.6296 0.12922E-04 -4.8887 0.55077E+00 -0.2590
132 MnSO4,aq 0.32936E-08 -8.4823 0.32936E-08 -8.4823 0.10000E+01 0.0000
133 NaCl,aq 0.26941E+00 -0.5696 0.26941E+00 -0.5696 0.10000E+01 0.0000
134 NaF,aq 0.19925E-03 -3.7006 0.19925E-03 -3.7006 0.10000E+01 0.0000
135 NaOH,aq 0.92017E-06 -6.0361 0.92017E-06 -6.0361 0.10000E+01 0.0000
137 OH- 0.32569E-05 -5.4872 0.16152E-05 -5.7918 0.49594E+00 -0.3046
140 PbCl+ 0.65303E-07 -7.1851 0.35967E-07 -7.4441 0.55077E+00 -0.2590
141 PbCl2,aq 0.28314E-06 -6.5480 0.28314E-06 -6.5480 0.10000E+01 0.0000
142 PbCl3- 0.21869E-06 -6.6602 0.11480E-06 -6.9401 0.52493E+00 -0.2799
143 PbCl4-2 0.30871E-06 -6.5105 0.14619E-07 -7.8351 0.47356E-01 -1.3246
144 PbF+ 0.95741E-10 -10.0189 0.52732E-10 -10.2779 0.55077E+00 -0.2590
146 PbO,aq 0.37358E-10 -10.4276 0.37358E-10 -10.4276 0.10000E+01 0.0000
148 Pb(HS)2,aq 0.17105E-09 -9.7669 0.17105E-09 -9.7669 0.10000E+01 0.0000
150 H2S,aq 0.10362E-04 -4.9845 0.94631E-05 -5.0240 0.91321E+00 -0.0394
158 HSO3- 0.20647E-09 -9.6851 0.10838E-09 -9.9650 0.52493E+00 -0.2799
159 HSO4- 0.61358E-06 -6.2121 0.34358E-06 -6.4640 0.55996E+00 -0.2518
161 S2O3-2 0.22115E-10 -10.6553 0.10473E-11 -11.9799 0.47356E-01 -1.3246
173 ZnCl+ 0.46897E-05 -5.3289 0.25830E-05 -5.5879 0.55077E+00 -0.2590
174 ZnCl2,aq 0.11980E-05 -5.9216 0.11980E-05 -5.9216 0.10000E+01 0.0000
175 ZnCl3- 0.16212E-06 -6.7902 0.85101E-07 -7.0701 0.52493E+00 -0.2799
176 ZnF+ 0.13342E-09 -9.8748 0.73487E-10 -10.1338 0.55077E+00 -0.2590
177 ZnO,aq 0.28753E-09 -9.5413 0.28753E-09 -9.5413 0.10000E+01 0.0000
178 ZnOH+ 0.22247E-06 -6.6527 0.12253E-06 -6.9117 0.55077E+00 -0.2590
Charge balance for all species = -.1176E-03
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.7947930E-05 0.2934000E+00 0.2693698E+03 0.0000
2 H2O 0.1000000E+01 0.5521501E+02 0.9060512E+06 0.0000
3 Cl- 0.1130665E+01 0.1401859E+01 0.4527008E+05 5.1777
4 SO4-- 0.1538930E-03 0.1711179E-03 0.1497267E+02 5.6878
5 HCO3- 0.2403853E-01 0.3174256E+00 0.1764202E+05 3.5205
6 HS- 0.1265837E-05 0.1168766E-04 0.3520805E+00 -0.7716
7 H4SiO4 0.2539400E-02 0.2548935E-02 0.2231546E+03 -2.5953
8 Al+++ 0.8405824E-13 0.5412683E-06 0.1330248E-01 0.0945
9 Ca++ 0.1207122E-02 0.1909684E-02 0.6971426E+02 6.5288
10 Mg++ 0.1146644E-03 0.1558177E-03 0.3450575E+01 5.4654
11 Fe++ 0.1109097E-05 0.1454385E-05 0.7398325E-01 3.4612
12 K+ 0.4007569E-01 0.4123401E-01 0.1468617E+04 3.7462
13 Na+ 0.1112648E+01 0.1382263E+01 0.2894542E+05 5.1712
14 Mn++ 0.7772452E-05 0.3127478E-04 0.1565025E+01 4.3143
15 Zn++ 0.2726294E-07 0.6299958E-05 0.3751200E+00 1.8518
16 Cu+ 0.4523185E-11 0.1543524E-06 0.8933357E-02 -6.2203
17 Pb++ 0.5720214E-08 0.8818624E-06 0.1664270E+00 1.2291
18 Ag+ 0.2097214E-10 0.3331942E-06 0.3273801E-01 -5.5384
19 Au+ 0.5798062E-21 0.2822005E-11 0.5062970E-06 -16.0914
20 Ba++ 0.1518786E-05 0.3686886E-05 0.4612229E+00 3.6690
21 F- 0.1193822E-02 0.1478963E-02 0.2559289E+02 2.1720
22 H2AsO3- 0.1144578E-05 0.1175986E-03 0.1338267E+02 -0.7041
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234423E+00 -.7181205E-05 0.0000000E+00
2 H2O 0.6086868E+02 0.6086868E+02 0.0000000E+00 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1288440E-04 0.1145912E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2809930E-02 0.1810588E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.5966908E-06 0.1810588E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.6035294E-06 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.6945034E-05 0.5231421E-06 0.0000000E+00
16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00
17 Pb++ 0.1565021E-05 0.9721596E-06 0.5928610E-06 0.0000000E+00
18 Ag+ 0.4271281E-06 0.3673112E-06 0.5981688E-07 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1630400E-02 0.0000000E+00 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: -.5956E-21 Mass of aqueous solution: 0.121027E+04 g
Temperature = 184.87 C Pressure = 500.00 bar Mixer frac. = 0.1000000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
paragonite 0.6035E-06 -6.219 0.2307E-03 -3.637 53.53 0.7973E-04
galena 0.5929E-06 -6.227 0.1418E-03 -3.848 32.92 0.1867E-04
sphalerite 0.5231E-06 -6.281 0.5097E-04 -4.293 11.83 0.1247E-04
argentite 0.2991E-07 -7.524 0.7411E-05 -5.130 1.720 0.1041E-05
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
paragonite 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
argentite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.1000000
Solid products produced: Mass = 0.000431 g Volume = 0.000112 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.300
AFFINITY: 0.3949E+03
GOLD Q/K: 0.0248
SILVER Q/K: 0.2952
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 184.8730 deg.C
Sat. pressure: 88.3608 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.2168E+00 0.6609 0.1266E+02 0.1915E+02
CO2,gas 0.7832E+00 0.9036 0.6253E+02 0.6921E+02
CH4,gas 0.1996E-07 1.1161 0.1969E-05 0.1764E-05
H2,gas 0.2079E-05 1.0391 0.1909E-03 0.1837E-03
H2S,gas 0.7189E-05 0.8338 0.5296E-03 0.6352E-03
S2,gas 0.9232E-16 1.0000 0.8157E-14 0.8157E-14
CO,gas 0.3228E-07 1.0000 0.2853E-05 0.2853E-05
SO3,gas 0.3803E-26 1.0000 0.3361E-24 0.3361E-24
O2,gas 0.1904E-42 1.0000 0.1683E-40 0.1683E-40
SO2,gas 0.4175E-12 1.0000 0.3689E-10 0.3689E-10
HF,gas 0.3811E-07 1.0000 0.3368E-05 0.3368E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
122 paragonite -2.33 -2.33 0.00 0.000 -0.93074E-11
196 argentite -22.66 -22.66 0.00 0.000 0.74459E-11
260 galena -10.35 -10.35 0.00 0.000 0.37230E-11
272 sphalerite -9.73 -9.73 0.00 0.000 0.37230E-11
225 topaz -19.88 -19.68 0.20 0.022 -0.41361E+03
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.58 -0.02 -1.60 -1.597 0.33462E+04 1.102
2 CO2,gas -6.37 -7.27 -0.90 -0.301 0.18923E+04 1.796
3 CH4,gas 5.45 -2.96 -8.40 -2.101 0.17615E+05 -5.706
4 H2,gas 7.49 1.07 -6.42 -3.668 0.13451E+05 -3.719
5 H2S,gas -5.61 -11.58 -5.97 -2.987 0.12523E+05 -3.276
6 S2,gas -8.51 -25.30 -16.79 -2.583 0.35184E+05 -14.088
7 CO,gas 2.06 -6.18 -8.24 -2.537 0.17278E+05 -5.545
8 SO3,gas 11.26 -15.91 -27.17 -6.793 0.56949E+05 -24.474
9 O2,gas 41.30 -2.17 -43.47 -28.982 0.91112E+05 -40.774
10 SO2,gas -1.69 -14.82 -13.13 -3.502 0.27523E+05 -10.433
11 HF,gas -0.46 -8.64 -8.17 -4.086 0.17126E+05 -5.473
12 HCl,gas 1.07 -5.63 -6.70 -3.352 0.14051E+05 -6.704
13 acmite 6.21 2.95 -3.27 -0.339 0.68458E+04
17 albite-high -1.24 -2.44 -1.20 -0.092 0.25107E+04
18 albite -1.96 -2.44 -0.48 -0.037 0.10089E+04
22 analcite 1.14 0.10 -1.05 -0.116 0.21945E+04
23 andalusite -0.53 -2.43 -1.89 -0.189 0.39639E+04
26 anhydrite -6.54 -9.40 -2.87 -1.433 0.60050E+04
27 ankerite -3.79 -4.59 -0.80 -0.133 0.16721E+04
31 anorthite 5.40 1.53 -3.88 -0.298 0.81258E+04
34 aragonite 0.02 -0.76 -0.78 -0.260 0.16377E+04
35 brucite 9.88 5.43 -4.46 -0.892 0.93443E+04
36 calcite -0.12 -0.76 -0.64 -0.214 0.13458E+04
37 carnegieite-low 5.67 2.67 -3.00 -0.429 0.62969E+04
38 carnegieite-high 6.40 2.67 -3.73 -0.532 0.78122E+04
39 carpholite-Mg 2.57 0.42 -2.15 -0.143 0.45063E+04
40 carpholite-Fe 1.01 -1.58 -2.59 -0.172 0.54216E+04
41 celadonite 2.81 -1.00 -3.81 -0.224 0.79758E+04
42 celadonite-Fe 1.48 -3.00 -4.48 -0.264 0.93949E+04
49 chloritoid-Mg 5.89 3.00 -2.89 -0.193 0.60600E+04
50 chloritoid-Fe 2.67 0.99 -1.67 -0.112 0.35100E+04
51 chloritoid-Mn 4.86 1.85 -3.01 -0.201 0.63166E+04
53 coesite -1.89 -2.56 -0.67 -0.222 0.13980E+04
58 corundum 2.16 0.13 -2.03 -0.185 0.42620E+04
60 cristobalite -2.08 -2.56 -0.48 -0.159 0.99673E+03
63 cymrite-K 0.00 -3.89 -3.89 -0.324 0.81434E+04
65 diaspore 0.31 0.05 -0.25 -0.042 0.52664E+03
66 diamond -2.23 -5.09 -2.86 -0.818 0.60015E+04
69 dolomite,ordered -1.55 -2.58 -1.03 -0.172 0.21677E+04
83 gibbsite 1.55 0.03 -1.51 -0.216 0.31691E+04
86 goethite 4.65 2.89 -1.77 -0.382 0.36992E+04
87 graphite -2.62 -5.09 -2.47 -0.706 0.51814E+04
90 halite 1.41 -0.46 -1.87 -0.935 0.39202E+04
91 hematite 8.70 5.80 -2.91 -0.352 0.60944E+04
92 heulandite -8.60 -11.37 -2.77 -0.126 0.58079E+04
96 jadeite 1.96 0.12 -1.85 -0.185 0.38721E+04
98 kalsilite 4.61 1.25 -3.37 -0.481 0.70554E+04
99 kaolinite -4.76 -5.02 -0.26 -0.024 0.55172E+03
100 kyanite -0.58 -2.43 -1.84 -0.184 0.38593E+04
102 laumontite -1.31 -3.66 -2.35 -0.157 0.49257E+04
103 lawsonite 4.00 1.49 -2.52 -0.168 0.52734E+04
104 leucite 1.67 -1.31 -2.98 -0.298 0.62466E+04
107 magnesite -0.67 -1.82 -1.15 -0.385 0.24180E+04
108 magnetite 14.03 9.24 -4.80 -0.392 0.10053E+05
114 margarite 5.08 1.64 -3.45 -0.138 0.72244E+04
117 microcline -3.44 -3.87 -0.42 -0.033 0.88917E+03
120 mullite-Si 1.21 -2.43 -3.64 -0.364 0.76300E+04
121 muscovite -3.53 -3.76 -0.23 -0.013 0.47407E+03
123 nepheline 5.08 2.67 -2.41 -0.345 0.50554E+04
143 pyrite -19.37 -20.77 -1.40 -0.329 0.29317E+04
144 pyrrhotite -4.86 -8.12 -3.25 -1.085 0.68208E+04
145 pyrrhotiteFe0.875 -6.24 -8.68 -2.45 -0.901 0.51323E+04
146 pyroxmangite 5.66 1.74 -3.92 -0.783 0.82076E+04
147 pyrophyllite -9.00 -10.11 -1.11 -0.069 0.23295E+04
148 quartz -2.39 -2.56 -0.16 -0.054 0.34086E+03
153 rhodochrosite -1.69 -2.97 -1.28 -0.427 0.26834E+04
154 rhodonite 5.68 1.74 -3.94 -0.789 0.82658E+04
155 sanidine -2.45 -3.87 -1.41 -0.109 0.29579E+04
157 siderite -3.37 -3.83 -0.46 -0.152 0.95722E+03
158 sillimanite -0.36 -2.43 -2.07 -0.207 0.43350E+04
165 stilbite -8.55 -11.39 -2.84 -0.135 0.59544E+04
168 stishovite 2.38 -2.56 -4.93 -1.645 0.10343E+05
170 sudoite 8.13 3.40 -4.72 -0.152 0.98979E+04
171 sulfur -8.52 -12.65 -4.13 -1.271 0.86594E+04
172 sylvite 1.42 -1.88 -3.30 -1.652 0.69253E+04
180 topaz-H -0.23 -2.45 -2.22 -0.202 0.46546E+04
181 tridymite -2.11 -2.56 -0.44 -0.148 0.93011E+03
184 troilite-low -4.93 -8.12 -3.19 -1.062 0.66759E+04
190 wairakite -1.02 -3.62 -2.61 -0.153 0.54618E+04
192 wollastonite 8.38 3.95 -4.43 -0.886 0.92856E+04
193 pseudo-wollastonite 8.78 3.95 -4.82 -0.965 0.10109E+05
197 arsenic -5.63 -9.85 -4.22 -1.088 0.88390E+04
199 arsenopyrite -13.50 -17.97 -4.47 -0.795 0.93684E+04
200 beidellite-Ca -6.16 -8.17 -2.01 -0.124 0.42173E+04
201 beidellite-H -6.63 -9.25 -2.62 -0.167 0.54835E+04
202 beidellite-K -5.74 -8.01 -2.28 -0.139 0.47702E+04
203 beidellite-Mg -6.40 -8.35 -1.95 -0.121 0.40902E+04
204 beidellite-Na -5.65 -7.54 -1.89 -0.116 0.39702E+04
205 bornite -73.81 -74.49 -0.69 -0.051 0.14400E+04
207 chalcedony -2.24 -2.56 -0.32 -0.105 0.66036E+03
208 chalcocite -22.58 -24.02 -1.44 -0.360 0.30165E+04
210 covellite -16.57 -18.33 -1.77 -0.674 0.37076E+04
211 dawsonite 0.04 -2.06 -2.10 -0.263 0.44022E+04
213 montmorillonite-Ca -5.38 -7.26 -1.88 -0.116 0.39403E+04
214 montmorillonite-K -5.06 -7.10 -2.05 -0.125 0.42864E+04
215 montmorillonite-Mg -5.62 -7.44 -1.82 -0.113 0.38193E+04
216 montmorillonite-Na -4.90 -6.63 -1.74 -0.106 0.36404E+04
217 nontronite-Ca 0.93 -2.51 -3.44 -0.223 0.72079E+04
218 nontronite-H 0.45 -3.58 -4.04 -0.271 0.84656E+04
219 nontronite-K 1.35 -2.35 -3.70 -0.238 0.77606E+04
220 nontronite-Mg 0.72 -2.68 -3.41 -0.221 0.71429E+04
221 nontronite-Na 1.44 -1.88 -3.32 -0.213 0.69630E+04
229 gypsum -5.62 -9.44 -3.82 -0.956 0.80148E+04
245 acanthite -22.48 -22.66 -0.17 -0.044 0.36523E+03
251 barite -9.60 -12.26 -2.66 -1.328 0.55681E+04
252 boehmite 1.41 0.05 -1.35 -0.225 0.28347E+04
253 cerussite -2.80 -6.06 -3.25 -1.085 0.68213E+04
254 chalcopyrite -25.01 -26.45 -1.44 -0.268 0.30244E+04
255 chlorargyrite -6.18 -11.17 -4.99 -2.493 0.10450E+05
256 copper,native -1.71 -5.69 -3.98 -1.384 0.83376E+04
257 dolomite,disordered -1.09 -2.58 -1.49 -0.249 0.31317E+04
258 ferrous-oxide 7.15 3.44 -3.71 -0.928 0.77826E+04
259 fluorite -10.18 -10.74 -0.56 -0.188 0.11812E+04
261 gold,native -13.95 -15.56 -1.61 -0.559 0.33653E+04
262 silver,native -4.47 -5.00 -0.53 -0.184 0.11105E+04
263 huntite -1.50 -6.23 -4.72 -0.394 0.98991E+04
269 silica-amorphous -1.71 -2.56 -0.85 -0.283 0.17766E+04
270 smithsonite -1.73 -5.44 -3.70 -1.234 0.77607E+04
273 wurtzite -8.24 -9.73 -1.49 -0.497 0.31243E+04
274 zincite 5.99 1.83 -4.16 -1.040 0.87183E+04
275 an20ab80 -0.70 -1.65 -0.94 -0.073 0.19771E+04
276 an25ab75 -0.36 -1.45 -1.09 -0.084 0.22765E+04
277 an30ab70 -0.02 -1.25 -1.23 -0.095 0.25879E+04
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 9 Loop limit = 70
Temperature = 184.87 C Pressure = 500.00 bar Mixer fraction = 0.1000000
Water: Moles liquid = 0.6119E+02 kg liquid = 0.1102E+01
Moles total = 0.6087E+02 kg total = 0.1097E+01 Activity = 0.9551
Stoichiometric ionic strength = .1585048E+01 Osmotic coef. = 0.9098
True ionic strength = .1157778E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.78365E-05 -5.1059 0.38864E-05 -5.4104 0.49594E+00 -0.3046
2 H2O 0.95508E+00 -0.0200 0.95508E+00 -0.0200
3 Cl- 0.11307E+01 0.0533 0.59351E+00 -0.2266 0.52493E+00 -0.2799
4 SO4-- 0.15390E-03 -3.8128 0.75718E-05 -5.1208 0.49198E-01 -1.3080
5 HCO3- 0.24354E-01 -1.6134 0.13240E-01 -1.8781 0.54364E+00 -0.2647
6 HS- 0.12690E-05 -5.8965 0.66866E-06 -6.1748 0.52692E+00 -0.2783
7 H4SiO4 0.26638E-02 -2.5745 0.26638E-02 -2.5745 0.10000E+01 0.0000
8 Al+++ 0.76459E-13 -13.1166 0.69232E-16 -16.1597 0.90548E-03 -3.0431
9 Ca++ 0.12063E-02 -2.9185 0.52464E-04 -4.2801 0.43491E-01 -1.3616
10 Mg++ 0.11469E-03 -3.9405 0.45375E-05 -5.3432 0.39563E-01 -1.4027
11 Fe++ 0.11100E-05 -5.9547 0.44965E-07 -7.3471 0.40509E-01 -1.3924
12 K+ 0.40076E-01 -1.3971 0.21975E-01 -1.6581 0.54835E+00 -0.2609
13 Na+ 0.11127E+01 0.0464 0.58469E+00 -0.2331 0.52545E+00 -0.2795
14 Mn++ 0.77739E-05 -5.1094 0.32045E-06 -6.4942 0.41221E-01 -1.3849
15 Zn++ 0.26816E-07 -7.5716 0.10863E-08 -8.9641 0.40509E-01 -1.3924
16 Cu+ 0.45233E-11 -11.3445 0.23737E-11 -11.6246 0.52478E+00 -0.2800
17 Pb++ 0.56264E-08 -8.2498 0.25897E-09 -9.5868 0.46027E-01 -1.3370
18 Ag+ 0.20799E-10 -10.6820 0.11315E-10 -10.9463 0.54404E+00 -0.2644
19 Au+ 0.57820E-21 -21.2379 0.31846E-21 -21.4970 0.55078E+00 -0.2590
20 Ba++ 0.15117E-05 -5.8205 0.72155E-07 -7.1417 0.47732E-01 -1.3212
21 F- 0.99276E-03 -3.0032 0.48708E-03 -3.3124 0.49064E+00 -0.3092
22 H2AsO3- 0.11607E-05 -5.9353 0.79005E-06 -6.1023 0.68068E+00 -0.1671
24 HSiO3- 0.29335E-05 -5.5326 0.15399E-05 -5.8125 0.52493E+00 -0.2799
25 Ca(HSiO3)+ 0.13944E-07 -7.8556 0.76799E-08 -8.1146 0.55078E+00 -0.2590
26 Mg(HSiO3)+ 0.10635E-08 -8.9732 0.58577E-09 -9.2323 0.55078E+00 -0.2590
27 NaHSiO3,aq 0.71972E-05 -5.1428 0.71972E-05 -5.1428 0.10000E+01 0.0000
31 AgCl,aq 0.37341E-08 -8.4278 0.37341E-08 -8.4278 0.10000E+01 0.0000
32 AgCl2- 0.17495E-06 -6.7571 0.91834E-07 -7.0370 0.52493E+00 -0.2799
33 AgCl3-2 0.12181E-06 -6.9143 0.57679E-08 -8.2390 0.47353E-01 -1.3247
34 AgCl4-3 0.21632E-07 -7.6649 0.19140E-10 -10.7181 0.88480E-03 -3.0532
38 Ag(HS),aq 0.83184E-08 -8.0800 0.83184E-08 -8.0800 0.10000E+01 0.0000
40 AlO+ 0.22640E-09 -9.6451 0.12470E-09 -9.9041 0.55078E+00 -0.2590
42 HAlO2,aq 0.49764E-07 -7.3031 0.49764E-07 -7.3031 0.10000E+01 0.0000
43 AlO2- 0.47015E-06 -6.3278 0.23317E-06 -6.6323 0.49594E+00 -0.3046
44 AsO2- 0.20253E-06 -6.6935 0.10631E-06 -6.9734 0.52493E+00 -0.2799
45 HAsO2,aq 0.31277E-04 -4.5048 0.31277E-04 -4.5048 0.10000E+01 0.0000
46 H3AsO3,aq 0.84959E-04 -4.0708 0.84959E-04 -4.0708 0.10000E+01 0.0000
48 H2AsO4- 0.10685E-09 -9.9712 0.56089E-10 -10.2511 0.52493E+00 -0.2799
49 HAsO4-2 0.24236E-10 -10.6155 0.11476E-11 -11.9402 0.47353E-01 -1.3247
62 BaCO3,aq 0.44649E-09 -9.3502 0.44649E-09 -9.3502 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.13608E-05 -5.8662 0.76480E-06 -6.1165 0.56203E+00 -0.2502
64 BaCl+ 0.81329E-06 -6.0898 0.44794E-06 -6.3488 0.55078E+00 -0.2590
65 BaF+ 0.74738E-09 -9.1265 0.41164E-09 -9.3855 0.55078E+00 -0.2590
66 CH4,aq 0.12902E-08 -8.8894 0.11782E-08 -8.9288 0.91321E+00 -0.0394
71 CO,aq 0.23264E-08 -8.6333 0.23264E-08 -8.6333 0.10000E+01 0.0000
72 CO2,aq 0.29289E+00 -0.5333 0.26747E+00 -0.5727 0.91321E+00 -0.0394
73 CO3-2 0.56303E-05 -5.2495 0.26661E-06 -6.5741 0.47353E-01 -1.3247
74 CaCO3,aq 0.12923E-05 -5.8886 0.12923E-05 -5.8886 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.16089E-03 -3.7935 0.88615E-04 -4.0525 0.55078E+00 -0.2590
76 CaCl+ 0.49433E-03 -3.3060 0.27226E-03 -3.5650 0.55078E+00 -0.2590
77 CaCl2,aq 0.42385E-04 -4.3728 0.42385E-04 -4.3728 0.10000E+01 0.0000
78 CaF+ 0.38639E-05 -5.4130 0.21281E-05 -5.6720 0.55078E+00 -0.2590
79 CaOH+ 0.13153E-06 -6.8810 0.72444E-07 -7.1400 0.55078E+00 -0.2590
80 CaSO4,aq 0.46821E-06 -6.3296 0.46821E-06 -6.3296 0.10000E+01 0.0000
81 HCl,aq 0.12860E-05 -5.8907 0.12860E-05 -5.8907 0.10000E+01 0.0000
90 CuCl,aq 0.65807E-08 -8.1817 0.65807E-08 -8.1817 0.10000E+01 0.0000
91 CuCl2- 0.12092E-06 -6.9175 0.63473E-07 -7.1974 0.52493E+00 -0.2799
92 CuCl3-2 0.26850E-07 -7.5711 0.12714E-08 -8.8957 0.47353E-01 -1.3247
98 HF,aq 0.65539E-04 -4.1835 0.65539E-04 -4.1835 0.10000E+01 0.0000
99 HF2- 0.17135E-07 -7.7661 0.89947E-08 -8.0460 0.52493E+00 -0.2799
101 FeCl+ 0.31896E-06 -6.4963 0.17567E-06 -6.7553 0.55078E+00 -0.2590
102 FeCl2,aq 0.21112E-08 -8.6755 0.21112E-08 -8.6755 0.10000E+01 0.0000
104 FeF+ 0.67741E-08 -8.1692 0.37310E-08 -8.4282 0.55078E+00 -0.2590
106 FeO,aq 0.90327E-10 -10.0442 0.90327E-10 -10.0442 0.10000E+01 0.0000
107 FeOH+ 0.16384E-07 -7.7856 0.90240E-08 -8.0446 0.55078E+00 -0.2590
112 HFeO2,aq 0.74013E-10 -10.1307 0.74013E-10 -10.1307 0.10000E+01 0.0000
113 H2,aq 0.19605E-06 -6.7076 0.17903E-06 -6.7471 0.91321E+00 -0.0394
114 KCl,aq 0.11421E-02 -2.9423 0.11421E-02 -2.9423 0.10000E+01 0.0000
115 KHSO4,aq 0.19503E-09 -9.7099 0.19503E-09 -9.7099 0.10000E+01 0.0000
116 KOH,aq 0.47086E-07 -7.3271 0.47086E-07 -7.3271 0.10000E+01 0.0000
117 KSO4- 0.16190E-04 -4.7908 0.84984E-05 -5.0707 0.52493E+00 -0.2799
118 MgCO3,aq 0.16016E-07 -7.7954 0.16016E-07 -7.7954 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.13549E-04 -4.8681 0.74623E-05 -5.1271 0.55078E+00 -0.2590
120 MgCl+ 0.26507E-04 -4.5766 0.14599E-04 -4.8357 0.55078E+00 -0.2590
121 MgF+ 0.10160E-05 -5.9931 0.55959E-06 -6.2521 0.55078E+00 -0.2590
122 MgOH+ 0.40835E-07 -7.3890 0.22491E-07 -7.6480 0.55078E+00 -0.2590
124 MnF+ 0.18933E-07 -7.7228 0.10428E-07 -7.9818 0.55078E+00 -0.2590
125 MnO,aq 0.20134E-10 -10.6961 0.20134E-10 -10.6961 0.10000E+01 0.0000
126 MnOH+ 0.15085E-07 -7.8215 0.83083E-08 -8.0805 0.55078E+00 -0.2590
131 MnCl+ 0.23464E-04 -4.6296 0.12923E-04 -4.8886 0.55078E+00 -0.2590
132 MnSO4,aq 0.32939E-08 -8.4823 0.32939E-08 -8.4823 0.10000E+01 0.0000
133 NaCl,aq 0.26943E+00 -0.5696 0.26943E+00 -0.5696 0.10000E+01 0.0000
134 NaF,aq 0.16571E-03 -3.7806 0.16571E-03 -3.7806 0.10000E+01 0.0000
135 NaOH,aq 0.93334E-06 -6.0300 0.93334E-06 -6.0300 0.10000E+01 0.0000
137 OH- 0.33032E-05 -5.4811 0.16382E-05 -5.7856 0.49594E+00 -0.3046
140 PbCl+ 0.64227E-07 -7.1923 0.35375E-07 -7.4513 0.55078E+00 -0.2590
141 PbCl2,aq 0.27847E-06 -6.5552 0.27847E-06 -6.5552 0.10000E+01 0.0000
142 PbCl3- 0.21508E-06 -6.6674 0.11290E-06 -6.9473 0.52493E+00 -0.2799
143 PbCl4-2 0.30363E-06 -6.5177 0.14378E-07 -7.8423 0.47353E-01 -1.3247
144 PbF+ 0.78305E-10 -10.1062 0.43128E-10 -10.3652 0.55078E+00 -0.2590
146 PbO,aq 0.37796E-10 -10.4226 0.37796E-10 -10.4226 0.10000E+01 0.0000
148 Pb(HS)2,aq 0.16907E-09 -9.7719 0.16907E-09 -9.7719 0.10000E+01 0.0000
150 H2S,aq 0.10242E-04 -4.9896 0.93535E-05 -5.0290 0.91321E+00 -0.0394
158 HSO3- 0.20442E-09 -9.6895 0.10731E-09 -9.9694 0.52493E+00 -0.2799
159 HSO4- 0.60497E-06 -6.2183 0.33876E-06 -6.4701 0.55996E+00 -0.2518
161 S2O3-2 0.21861E-10 -10.6603 0.10352E-11 -11.9850 0.47353E-01 -1.3247
173 ZnCl+ 0.46124E-05 -5.3361 0.25404E-05 -5.5951 0.55078E+00 -0.2590
174 ZnCl2,aq 0.11782E-05 -5.9288 0.11782E-05 -5.9288 0.10000E+01 0.0000
175 ZnCl3- 0.15944E-06 -6.7974 0.83697E-07 -7.0773 0.52493E+00 -0.2799
176 ZnF+ 0.10913E-09 -9.9621 0.60104E-10 -10.2211 0.55078E+00 -0.2590
177 ZnO,aq 0.29089E-09 -9.5363 0.29089E-09 -9.5363 0.10000E+01 0.0000
178 ZnOH+ 0.22192E-06 -6.6538 0.12223E-06 -6.9128 0.55078E+00 -0.2590
Charge balance for all species = -.1176E-03
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.7836534E-05 0.2930685E+00 0.2690618E+03 0.0000
2 H2O 0.1000000E+01 0.5521532E+02 0.9060439E+06 0.0000
3 Cl- 0.1130652E+01 0.1401867E+01 0.4526972E+05 5.1839
4 SO4-- 0.1539031E-03 0.1711188E-03 0.1497255E+02 5.7001
5 HCO3- 0.2435405E-01 0.3174274E+00 0.1764188E+05 3.5323
6 HS- 0.1268978E-05 0.1157104E-04 0.3485626E+00 -0.7643
7 H4SiO4 0.2663793E-02 0.2673939E-02 0.2340952E+03 -2.5745
8 Al+++ 0.7645864E-13 0.5201437E-06 0.1278314E-01 0.0716
9 Ca++ 0.1206321E-02 0.1909695E-02 0.6971370E+02 6.5408
10 Mg++ 0.1146892E-03 0.1558186E-03 0.3450547E+01 5.4777
11 Fe++ 0.1109995E-05 0.1454394E-05 0.7398265E-01 3.4738
12 K+ 0.4007593E-01 0.4123425E-01 0.1468605E+04 3.7524
13 Na+ 0.1112750E+01 0.1382354E+01 0.2894693E+05 5.1774
14 Mn++ 0.7773935E-05 0.3127496E-04 0.1565012E+01 4.3267
15 Zn++ 0.2681610E-07 0.6199219E-05 0.3691166E+00 1.8568
16 Cu+ 0.4523257E-11 0.1543533E-06 0.8933285E-02 -6.2141
17 Pb++ 0.5626434E-08 0.8673215E-06 0.1636805E+00 1.2341
18 Ag+ 0.2079869E-10 0.3304639E-06 0.3246929E-01 -5.5359
19 Au+ 0.5781950E-21 0.2822021E-11 0.5062929E-06 -16.0865
20 Ba++ 0.1511660E-05 0.3686907E-05 0.4612192E+00 3.6792
21 F- 0.9927610E-03 0.1228952E-02 0.2126624E+02 2.0981
22 H2AsO3- 0.1160667E-05 0.1175993E-03 0.1338257E+02 -0.6919
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3230751E+00 0.3601047E-03 0.0000000E+00
2 H2O 0.6086868E+02 0.6086868E+02 0.0000000E+00 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1275576E-04 0.1274546E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2947717E-02 -.1359757E-03 0.0000000E+00
8 Al+++ 0.2407279E-05 0.5733999E-06 0.1833879E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523890E+01 -.9126175E-04 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.6833941E-05 0.6342356E-06 0.0000000E+00
16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00
17 Pb++ 0.1565021E-05 0.9561244E-06 0.6088963E-06 0.0000000E+00
18 Ag+ 0.4271281E-06 0.3642992E-06 0.6282886E-07 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1354781E-02 0.2756191E-03 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: 0.5421E-19 Mass of aqueous solution: 0.121028E+04 g
Temperature = 184.87 C Pressure = 500.00 bar Mixer frac. = 0.1000000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
paragonite -.9126E-04 1.000 -.3488E-01 1.000 375.0 -.1206E-01
argentite 0.3141E-07 -7.503 0.7784E-05 -5.109 -.8369E-01 0.1093E-05
galena 0.6089E-06 -6.215 0.1457E-03 -3.837 -1.566 0.1917E-04
sphalerite 0.6342E-06 -6.198 0.6179E-04 -4.209 -.6643 0.1511E-04
topaz 0.1378E-03 -3.861 0.2536E-01 -1.596 -272.7 0.7100E-02
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
paragonite 0.1000E+01 0.1000E+01 1.0000 0.000
argentite 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
topaz 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.1000000
Solid products produced: Mass = -0.009302 g Volume = -0.004921 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.300
AFFINITY: 0.3862E+03
GOLD Q/K: 0.0251
SILVER Q/K: 0.2976
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 184.8730 deg.C
Sat. pressure: 88.2711 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.2169E+00 0.6611 0.1266E+02 0.1915E+02
CO2,gas 0.7831E+00 0.9037 0.6246E+02 0.6912E+02
CH4,gas 0.2030E-07 1.1161 0.1999E-05 0.1791E-05
H2,gas 0.2090E-05 1.0391 0.1917E-03 0.1845E-03
H2S,gas 0.7111E-05 0.8340 0.5235E-03 0.6277E-03
S2,gas 0.8954E-16 1.0000 0.7904E-14 0.7904E-14
CO,gas 0.3242E-07 1.0000 0.2861E-05 0.2861E-05
SO3,gas 0.3701E-26 1.0000 0.3267E-24 0.3267E-24
O2,gas 0.1890E-42 1.0000 0.1669E-40 0.1669E-40
SO2,gas 0.4080E-12 1.0000 0.3601E-10 0.3601E-10
HF,gas 0.3128E-07 1.0000 0.2761E-05 0.2761E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
196 argentite -22.66 -22.66 0.00 0.000 0.00000E+00
225 topaz -19.88 -19.88 0.00 0.000 -0.74459E-11
260 galena -10.35 -10.35 0.00 0.000 -0.74459E-11
272 sphalerite -9.73 -9.73 0.00 0.000 -0.74459E-11
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.58 -0.02 -1.60 -1.597 0.33462E+04 1.102
2 CO2,gas -6.37 -7.27 -0.90 -0.301 0.18932E+04 1.796
3 CH4,gas 5.45 -2.95 -8.40 -2.100 0.17601E+05 -5.699
4 H2,gas 7.49 1.07 -6.42 -3.666 0.13448E+05 -3.717
5 H2S,gas -5.61 -11.59 -5.98 -2.990 0.12533E+05 -3.281
6 S2,gas -8.51 -25.31 -16.80 -2.585 0.35212E+05 -14.102
7 CO,gas 2.06 -6.18 -8.24 -2.536 0.17275E+05 -5.543
8 SO3,gas 11.26 -15.92 -27.18 -6.796 0.56975E+05 -24.486
9 O2,gas 41.30 -2.18 -43.48 -28.984 0.91120E+05 -40.778
10 SO2,gas -1.69 -14.83 -13.14 -3.505 0.27545E+05 -10.444
11 HF,gas -0.46 -8.72 -8.26 -4.129 0.17307E+05 -5.559
12 HCl,gas 1.07 -5.64 -6.71 -3.355 0.14064E+05 -6.710
13 acmite 6.21 3.01 -3.21 -0.333 0.67213E+04
17 albite-high -1.24 -2.39 -1.15 -0.089 0.24150E+04
18 albite -1.96 -2.39 -0.44 -0.034 0.91322E+03
22 analcite 1.14 0.12 -1.02 -0.114 0.21424E+04
23 andalusite -0.53 -2.45 -1.92 -0.192 0.40161E+04
26 anhydrite -6.54 -9.40 -2.87 -1.433 0.60057E+04
27 ankerite -3.79 -4.56 -0.77 -0.129 0.16226E+04
31 anorthite 5.40 1.54 -3.87 -0.298 0.81094E+04
34 aragonite 0.02 -0.75 -0.77 -0.257 0.16136E+04
35 brucite 9.88 5.44 -4.45 -0.889 0.93184E+04
36 calcite -0.12 -0.75 -0.63 -0.210 0.13217E+04
37 carnegieite-low 5.67 2.67 -3.00 -0.429 0.62882E+04
38 carnegieite-high 6.40 2.67 -3.72 -0.532 0.78036E+04
39 carpholite-Mg 2.57 0.43 -2.14 -0.143 0.44891E+04
40 carpholite-Fe 1.01 -1.57 -2.58 -0.172 0.54039E+04
41 celadonite 2.81 -0.92 -3.73 -0.219 0.78108E+04
42 celadonite-Fe 1.48 -2.92 -4.40 -0.259 0.92294E+04
49 chloritoid-Mg 5.89 2.99 -2.90 -0.194 0.60863E+04
50 chloritoid-Fe 2.67 0.98 -1.69 -0.112 0.35358E+04
51 chloritoid-Mn 4.86 1.84 -3.03 -0.202 0.63429E+04
53 coesite -1.89 -2.53 -0.65 -0.215 0.13545E+04
58 corundum 2.16 0.08 -2.08 -0.189 0.43577E+04
60 cristobalite -2.08 -2.53 -0.45 -0.152 0.95320E+03
63 cymrite-K 0.00 -3.84 -3.84 -0.320 0.80478E+04
65 diaspore 0.31 0.03 -0.27 -0.046 0.57449E+03
66 diamond -2.23 -5.09 -2.86 -0.817 0.59950E+04
69 dolomite,ordered -1.55 -2.56 -1.01 -0.168 0.21188E+04
83 gibbsite 1.55 0.01 -1.53 -0.219 0.32170E+04
86 goethite 4.65 2.90 -1.75 -0.379 0.36747E+04
87 graphite -2.62 -5.09 -2.47 -0.705 0.51748E+04
90 halite 1.41 -0.46 -1.87 -0.935 0.39201E+04
91 hematite 8.70 5.82 -2.88 -0.350 0.60454E+04
92 heulandite -8.60 -11.26 -2.66 -0.121 0.55738E+04
96 jadeite 1.96 0.14 -1.82 -0.182 0.38199E+04
98 kalsilite 4.61 1.25 -3.36 -0.480 0.70469E+04
99 kaolinite -4.76 -5.03 -0.27 -0.024 0.56035E+03
100 kyanite -0.58 -2.45 -1.87 -0.187 0.39114E+04
102 laumontite -1.31 -3.61 -2.30 -0.153 0.48222E+04
103 lawsonite 4.00 1.50 -2.51 -0.167 0.52570E+04
104 leucite 1.67 -1.29 -2.96 -0.296 0.61945E+04
107 magnesite -0.67 -1.81 -1.14 -0.381 0.23932E+04
108 magnetite 14.03 9.27 -4.76 -0.389 0.99775E+04
114 margarite 5.08 1.60 -3.48 -0.139 0.73037E+04
117 microcline -3.44 -3.82 -0.38 -0.029 0.79356E+03
120 mullite-Si 1.21 -2.45 -3.67 -0.367 0.76821E+04
121 muscovite -3.53 -3.76 -0.23 -0.013 0.47415E+03
122 paragonite -2.33 -2.33 0.00 0.000 -0.93074E-11
123 nepheline 5.08 2.67 -2.41 -0.344 0.50467E+04
143 pyrite -19.37 -20.77 -1.40 -0.329 0.29303E+04
144 pyrrhotite -4.86 -8.11 -3.25 -1.082 0.68050E+04
145 pyrrhotiteFe0.875 -6.24 -8.68 -2.44 -0.899 0.51203E+04
146 pyroxmangite 5.66 1.77 -3.88 -0.777 0.81382E+04
147 pyrophyllite -9.00 -10.07 -1.07 -0.067 0.22510E+04
148 quartz -2.39 -2.53 -0.14 -0.047 0.29733E+03
153 rhodochrosite -1.69 -2.96 -1.27 -0.423 0.26586E+04
154 rhodonite 5.68 1.77 -3.91 -0.782 0.81964E+04
155 sanidine -2.45 -3.82 -1.37 -0.105 0.28623E+04
157 siderite -3.37 -3.81 -0.44 -0.148 0.93183E+03
158 sillimanite -0.36 -2.45 -2.09 -0.209 0.43871E+04
165 stilbite -8.55 -11.28 -2.73 -0.130 0.57204E+04
168 stishovite 2.38 -2.53 -4.91 -1.638 0.10299E+05
170 sudoite 8.13 3.40 -4.73 -0.152 0.99070E+04
171 sulfur -8.52 -12.65 -4.14 -1.273 0.86738E+04
172 sylvite 1.42 -1.88 -3.30 -1.652 0.69253E+04
180 topaz-H -0.23 -2.47 -2.25 -0.204 0.47068E+04
181 tridymite -2.11 -2.53 -0.42 -0.141 0.88658E+03
184 troilite-low -4.93 -8.11 -3.18 -1.059 0.66601E+04
190 wairakite -1.02 -3.57 -2.56 -0.150 0.53583E+04
192 wollastonite 8.38 3.99 -4.40 -0.880 0.92170E+04
193 pseudo-wollastonite 8.78 3.99 -4.79 -0.958 0.10041E+05
197 arsenic -5.63 -9.85 -4.21 -1.088 0.88335E+04
199 arsenopyrite -13.50 -17.96 -4.46 -0.793 0.93471E+04
200 beidellite-Ca -6.16 -8.15 -1.99 -0.123 0.41648E+04
201 beidellite-H -6.63 -9.23 -2.59 -0.165 0.54352E+04
202 beidellite-K -5.74 -7.99 -2.25 -0.138 0.47177E+04
203 beidellite-Mg -6.40 -8.32 -1.93 -0.119 0.40376E+04
204 beidellite-Na -5.65 -7.52 -1.87 -0.114 0.39177E+04
205 bornite -73.81 -74.47 -0.66 -0.050 0.13935E+04
207 chalcedony -2.24 -2.53 -0.29 -0.098 0.61683E+03
208 chalcocite -22.58 -24.01 -1.43 -0.358 0.30014E+04
210 covellite -16.57 -18.33 -1.77 -0.674 0.37072E+04
211 dawsonite 0.04 -2.08 -2.12 -0.265 0.44381E+04
213 montmorillonite-Ca -5.38 -7.21 -1.83 -0.113 0.38334E+04
214 montmorillonite-K -5.06 -7.05 -1.99 -0.122 0.41794E+04
215 montmorillonite-Mg -5.62 -7.39 -1.77 -0.110 0.37123E+04
216 montmorillonite-Na -4.90 -6.58 -1.69 -0.103 0.35334E+04
217 nontronite-Ca 0.93 -2.41 -3.35 -0.217 0.70109E+04
218 nontronite-H 0.45 -3.49 -3.95 -0.265 0.82726E+04
219 nontronite-K 1.35 -2.25 -3.61 -0.232 0.75634E+04
220 nontronite-Mg 0.72 -2.59 -3.31 -0.215 0.69457E+04
221 nontronite-Na 1.44 -1.78 -3.23 -0.207 0.67658E+04
229 gypsum -5.62 -9.44 -3.82 -0.956 0.80155E+04
245 acanthite -22.48 -22.66 -0.17 -0.044 0.36523E+03
251 barite -9.60 -12.26 -2.66 -1.329 0.55725E+04
252 boehmite 1.41 0.03 -1.38 -0.229 0.28825E+04
253 cerussite -2.80 -6.05 -3.25 -1.083 0.68117E+04
254 chalcopyrite -25.01 -26.45 -1.44 -0.267 0.30082E+04
255 chlorargyrite -6.18 -11.17 -4.99 -2.495 0.10458E+05
256 copper,native -1.71 -5.68 -3.97 -1.381 0.83228E+04
257 dolomite,disordered -1.09 -2.56 -1.47 -0.245 0.30828E+04
258 ferrous-oxide 7.15 3.45 -3.70 -0.925 0.77562E+04
259 fluorite -10.18 -10.90 -0.72 -0.241 0.15176E+04
261 gold,native -13.95 -15.55 -1.60 -0.556 0.33531E+04
262 silver,native -4.47 -5.00 -0.53 -0.183 0.11033E+04
263 huntite -1.50 -6.18 -4.68 -0.390 0.98004E+04
269 silica-amorphous -1.71 -2.53 -0.83 -0.276 0.17331E+04
270 smithsonite -1.73 -5.43 -3.70 -1.233 0.77511E+04
273 wurtzite -8.24 -9.73 -1.49 -0.497 0.31243E+04
274 zincite 5.99 1.84 -4.15 -1.039 0.87077E+04
275 an20ab80 -0.70 -1.61 -0.91 -0.070 0.18973E+04
276 an25ab75 -0.36 -1.41 -1.05 -0.081 0.22006E+04
277 an30ab70 -0.02 -1.22 -1.20 -0.092 0.25160E+04
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 8 Loop limit = 70
Temperature = 184.87 C Pressure = 500.00 bar Mixer fraction = 0.1000000
Water: Moles liquid = 0.6119E+02 kg liquid = 0.1102E+01
Moles total = 0.6087E+02 kg total = 0.1097E+01 Activity = 0.9551
Stoichiometric ionic strength = .1585131E+01 Osmotic coef. = 0.9098
True ionic strength = .1157678E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.79471E-05 -5.0998 0.39413E-05 -5.4044 0.49594E+00 -0.3046
2 H2O 0.95508E+00 -0.0200 0.95508E+00 -0.0200
3 Cl- 0.11307E+01 0.0533 0.59352E+00 -0.2266 0.52493E+00 -0.2799
4 SO4-- 0.15389E-03 -3.8128 0.75718E-05 -5.1208 0.49202E-01 -1.3080
5 HCO3- 0.24041E-01 -1.6191 0.13069E-01 -1.8837 0.54364E+00 -0.2647
6 HS- 0.12659E-05 -5.8976 0.66701E-06 -6.1759 0.52692E+00 -0.2783
7 H4SiO4 0.25402E-02 -2.5951 0.25402E-02 -2.5951 0.10000E+01 0.0000
8 Al+++ 0.67029E-13 -13.1737 0.60705E-16 -16.2168 0.90564E-03 -3.0430
9 Ca++ 0.12071E-02 -2.9183 0.52502E-04 -4.2798 0.43494E-01 -1.3616
10 Mg++ 0.11466E-03 -3.9406 0.45369E-05 -5.3432 0.39567E-01 -1.4027
11 Fe++ 0.11091E-05 -5.9550 0.44932E-07 -7.3474 0.40512E-01 -1.3924
12 K+ 0.40076E-01 -1.3971 0.21975E-01 -1.6581 0.54834E+00 -0.2609
13 Na+ 0.11126E+01 0.0464 0.58463E+00 -0.2331 0.52544E+00 -0.2795
14 Mn++ 0.77725E-05 -5.1094 0.32041E-06 -6.4943 0.41224E-01 -1.3848
15 Zn++ 0.27260E-07 -7.5645 0.11043E-08 -8.9569 0.40512E-01 -1.3924
16 Cu+ 0.45232E-11 -11.3446 0.23737E-11 -11.6246 0.52478E+00 -0.2800
17 Pb++ 0.57195E-08 -8.2426 0.26327E-09 -9.5796 0.46030E-01 -1.3370
18 Ag+ 0.20971E-10 -10.6784 0.11409E-10 -10.9428 0.54404E+00 -0.2644
19 Au+ 0.57979E-21 -21.2367 0.31934E-21 -21.4958 0.55077E+00 -0.2590
20 Ba++ 0.15187E-05 -5.8185 0.72497E-07 -7.1397 0.47735E-01 -1.3212
21 F- 0.11924E-02 -2.9236 0.58504E-03 -3.2328 0.49064E+00 -0.3092
22 H2AsO3- 0.11447E-05 -5.9413 0.77917E-06 -6.1084 0.68068E+00 -0.1671
24 HSiO3- 0.27584E-05 -5.5593 0.14480E-05 -5.8392 0.52493E+00 -0.2799
25 Ca(HSiO3)+ 0.13121E-07 -7.8820 0.72268E-08 -8.1411 0.55077E+00 -0.2590
26 Mg(HSiO3)+ 0.99992E-09 -9.0000 0.55073E-09 -9.2591 0.55077E+00 -0.2590
27 NaHSiO3,aq 0.67670E-05 -5.1696 0.67670E-05 -5.1696 0.10000E+01 0.0000
31 AgCl,aq 0.37651E-08 -8.4242 0.37651E-08 -8.4242 0.10000E+01 0.0000
32 AgCl2- 0.17640E-06 -6.7535 0.92596E-07 -7.0334 0.52493E+00 -0.2799
33 AgCl3-2 0.12281E-06 -6.9108 0.58158E-08 -8.2354 0.47356E-01 -1.3246
34 AgCl4-3 0.21808E-07 -7.6614 0.19299E-10 -10.7145 0.88495E-03 -3.0531
38 Ag(HS),aq 0.83666E-08 -8.0775 0.83666E-08 -8.0775 0.10000E+01 0.0000
40 AlO+ 0.19303E-09 -9.7144 0.10631E-09 -9.9734 0.55077E+00 -0.2590
42 HAlO2,aq 0.41837E-07 -7.3784 0.41837E-07 -7.3784 0.10000E+01 0.0000
43 AlO2- 0.38975E-06 -6.4092 0.19330E-06 -6.7138 0.49594E+00 -0.3046
44 AsO2- 0.19974E-06 -6.6995 0.10485E-06 -6.9794 0.52493E+00 -0.2799
45 HAsO2,aq 0.31281E-04 -4.5047 0.31281E-04 -4.5047 0.10000E+01 0.0000
46 H3AsO3,aq 0.84973E-04 -4.0707 0.84973E-04 -4.0707 0.10000E+01 0.0000
48 H2AsO4- 0.10582E-09 -9.9754 0.55545E-10 -10.2554 0.52493E+00 -0.2799
49 HAsO4-2 0.23665E-10 -10.6259 0.11207E-11 -11.9505 0.47356E-01 -1.3246
62 BaCO3,aq 0.43667E-09 -9.3598 0.43667E-09 -9.3598 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.13497E-05 -5.8698 0.75855E-06 -6.1200 0.56203E+00 -0.2502
64 BaCl+ 0.81716E-06 -6.0877 0.45007E-06 -6.3467 0.55077E+00 -0.2590
65 BaF+ 0.90196E-09 -9.0448 0.49678E-09 -9.3038 0.55077E+00 -0.2590
66 CH4,aq 0.12704E-08 -8.8961 0.11602E-08 -8.9355 0.91321E+00 -0.0394
71 CO,aq 0.23194E-08 -8.6346 0.23194E-08 -8.6346 0.10000E+01 0.0000
72 CO2,aq 0.29320E+00 -0.5328 0.26776E+00 -0.5723 0.91321E+00 -0.0394
73 CO3-2 0.54800E-05 -5.2612 0.25951E-06 -6.5858 0.47356E-01 -1.3246
74 CaCO3,aq 0.12589E-05 -5.9000 0.12589E-05 -5.9000 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.15894E-03 -3.7988 0.87539E-04 -4.0578 0.55077E+00 -0.2590
76 CaCl+ 0.49470E-03 -3.3057 0.27247E-03 -3.5647 0.55077E+00 -0.2590
77 CaCl2,aq 0.42417E-04 -4.3725 0.42417E-04 -4.3725 0.10000E+01 0.0000
78 CaF+ 0.46444E-05 -5.3331 0.25580E-05 -5.5921 0.55077E+00 -0.2590
79 CaOH+ 0.12980E-06 -6.8867 0.71488E-07 -7.1458 0.55077E+00 -0.2590
80 CaSO4,aq 0.46856E-06 -6.3292 0.46856E-06 -6.3292 0.10000E+01 0.0000
81 HCl,aq 0.13042E-05 -5.8846 0.13042E-05 -5.8846 0.10000E+01 0.0000
90 CuCl,aq 0.65807E-08 -8.1817 0.65807E-08 -8.1817 0.10000E+01 0.0000
91 CuCl2- 0.12092E-06 -6.9175 0.63474E-07 -7.1974 0.52493E+00 -0.2799
92 CuCl3-2 0.26848E-07 -7.5711 0.12714E-08 -8.8957 0.47356E-01 -1.3246
98 HF,aq 0.79831E-04 -4.0978 0.79831E-04 -4.0978 0.10000E+01 0.0000
99 HF2- 0.25070E-07 -7.6009 0.13160E-07 -7.8808 0.52493E+00 -0.2799
101 FeCl+ 0.31873E-06 -6.4966 0.17555E-06 -6.7556 0.55077E+00 -0.2590
102 FeCl2,aq 0.21097E-08 -8.6758 0.21097E-08 -8.6758 0.10000E+01 0.0000
104 FeF+ 0.81305E-08 -8.0899 0.44781E-08 -8.3489 0.55077E+00 -0.2590
106 FeO,aq 0.87765E-10 -10.0567 0.87765E-10 -10.0567 0.10000E+01 0.0000
107 FeOH+ 0.16144E-07 -7.7920 0.88919E-08 -8.0510 0.55077E+00 -0.2590
112 HFeO2,aq 0.72063E-10 -10.1423 0.72063E-10 -10.1423 0.10000E+01 0.0000
113 H2,aq 0.19524E-06 -6.7094 0.17829E-06 -6.7489 0.91321E+00 -0.0394
114 KCl,aq 0.11421E-02 -2.9423 0.11421E-02 -2.9423 0.10000E+01 0.0000
115 KHSO4,aq 0.19779E-09 -9.7038 0.19779E-09 -9.7038 0.10000E+01 0.0000
116 KOH,aq 0.46430E-07 -7.3332 0.46430E-07 -7.3332 0.10000E+01 0.0000
117 KSO4- 0.16190E-04 -4.7908 0.84984E-05 -5.0707 0.52493E+00 -0.2799
118 MgCO3,aq 0.15588E-07 -7.8072 0.15588E-07 -7.8072 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.13373E-04 -4.8738 0.73653E-05 -5.1328 0.55077E+00 -0.2590
120 MgCl+ 0.26503E-04 -4.5767 0.14597E-04 -4.8357 0.55077E+00 -0.2590
121 MgF+ 0.12202E-05 -5.9136 0.67204E-06 -6.1726 0.55077E+00 -0.2590
122 MgOH+ 0.40261E-07 -7.3951 0.22175E-07 -7.6541 0.55077E+00 -0.2590
124 MnF+ 0.22738E-07 -7.6433 0.12523E-07 -7.9023 0.55077E+00 -0.2590
125 MnO,aq 0.19575E-10 -10.7083 0.19575E-10 -10.7083 0.10000E+01 0.0000
126 MnOH+ 0.14873E-07 -7.8276 0.81917E-08 -8.0866 0.55077E+00 -0.2590
131 MnCl+ 0.23461E-04 -4.6296 0.12922E-04 -4.8887 0.55077E+00 -0.2590
132 MnSO4,aq 0.32936E-08 -8.4823 0.32936E-08 -8.4823 0.10000E+01 0.0000
133 NaCl,aq 0.26941E+00 -0.5696 0.26941E+00 -0.5696 0.10000E+01 0.0000
134 NaF,aq 0.19902E-03 -3.7011 0.19902E-03 -3.7011 0.10000E+01 0.0000
135 NaOH,aq 0.92026E-06 -6.0361 0.92026E-06 -6.0361 0.10000E+01 0.0000
137 OH- 0.32572E-05 -5.4872 0.16154E-05 -5.7917 0.49594E+00 -0.3046
140 PbCl+ 0.65295E-07 -7.1851 0.35963E-07 -7.4441 0.55077E+00 -0.2590
141 PbCl2,aq 0.28310E-06 -6.5481 0.28310E-06 -6.5481 0.10000E+01 0.0000
142 PbCl3- 0.21866E-06 -6.6602 0.11478E-06 -6.9401 0.52493E+00 -0.2799
143 PbCl4-2 0.30867E-06 -6.5105 0.14618E-07 -7.8351 0.47356E-01 -1.3246
144 PbF+ 0.95616E-10 -10.0195 0.52663E-10 -10.2785 0.55077E+00 -0.2590
146 PbO,aq 0.37361E-10 -10.4276 0.37361E-10 -10.4276 0.10000E+01 0.0000
148 Pb(HS)2,aq 0.17103E-09 -9.7669 0.17103E-09 -9.7669 0.10000E+01 0.0000
150 H2S,aq 0.10362E-04 -4.9846 0.94623E-05 -5.0240 0.91321E+00 -0.0394
158 HSO3- 0.20646E-09 -9.6852 0.10838E-09 -9.9651 0.52493E+00 -0.2799
159 HSO4- 0.61352E-06 -6.2122 0.34355E-06 -6.4640 0.55996E+00 -0.2518
161 S2O3-2 0.22114E-10 -10.6553 0.10472E-11 -11.9800 0.47356E-01 -1.3246
173 ZnCl+ 0.46892E-05 -5.3289 0.25827E-05 -5.5879 0.55077E+00 -0.2590
174 ZnCl2,aq 0.11978E-05 -5.9216 0.11978E-05 -5.9216 0.10000E+01 0.0000
175 ZnCl3- 0.16210E-06 -6.7902 0.85091E-07 -7.0701 0.52493E+00 -0.2799
176 ZnF+ 0.13325E-09 -9.8753 0.73391E-10 -10.1344 0.55077E+00 -0.2590
177 ZnO,aq 0.28755E-09 -9.5413 0.28755E-09 -9.5413 0.10000E+01 0.0000
178 ZnOH+ 0.22247E-06 -6.6527 0.12253E-06 -6.9118 0.55077E+00 -0.2590
Charge balance for all species = -.1176E-03
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.7947117E-05 0.2933981E+00 0.2693680E+03 0.0000
2 H2O 0.1000000E+01 0.5521501E+02 0.9060511E+06 0.0000
3 Cl- 0.1130665E+01 0.1401859E+01 0.4527008E+05 5.1778
4 SO4-- 0.1538930E-03 0.1711179E-03 0.1497267E+02 5.6879
5 HCO3- 0.2404080E-01 0.3174256E+00 0.1764202E+05 3.5206
6 HS- 0.1265860E-05 0.1168681E-04 0.3520548E+00 -0.7715
7 H4SiO4 0.2540162E-02 0.2549702E-02 0.2232217E+03 -2.5951
8 Al+++ 0.6702950E-13 0.4317885E-06 0.1061185E-01 -0.0037
9 Ca++ 0.1207116E-02 0.1909684E-02 0.6971425E+02 6.5289
10 Mg++ 0.1146646E-03 0.1558177E-03 0.3450575E+01 5.4655
11 Fe++ 0.1109103E-05 0.1454385E-05 0.7398324E-01 3.4613
12 K+ 0.4007569E-01 0.4123401E-01 0.1468617E+04 3.7463
13 Na+ 0.1112648E+01 0.1382263E+01 0.2894543E+05 5.1712
14 Mn++ 0.7772462E-05 0.3127478E-04 0.1565025E+01 4.3144
15 Zn++ 0.2725968E-07 0.6299223E-05 0.3750762E+00 1.8518
16 Cu+ 0.4523186E-11 0.1543524E-06 0.8933357E-02 -6.2202
17 Pb++ 0.5719529E-08 0.8817564E-06 0.1664069E+00 1.2291
18 Ag+ 0.2097088E-10 0.3331744E-06 0.3273605E-01 -5.5384
19 Au+ 0.5797946E-21 0.2822005E-11 0.5062970E-06 -16.0914
20 Ba++ 0.1518734E-05 0.3686886E-05 0.4612229E+00 3.6690
21 F- 0.1192415E-02 0.1477212E-02 0.2556258E+02 2.1715
22 H2AsO3- 0.1144694E-05 0.1175986E-03 0.1338267E+02 -0.7040
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234402E+00 -.5009406E-05 0.0000000E+00
2 H2O 0.6086868E+02 0.6086868E+02 0.0000000E+00 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1288346E-04 0.1146850E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810775E-02 0.9656390E-06 0.0000000E+00
8 Al+++ 0.2407279E-05 0.4760010E-06 0.1931278E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.6944224E-05 0.5239526E-06 0.0000000E+00
16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00
17 Pb++ 0.1565021E-05 0.9720426E-06 0.5929780E-06 0.0000000E+00
18 Ag+ 0.4271281E-06 0.3672893E-06 0.5983877E-07 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1628469E-02 0.1931278E-05 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.121027E+04 g
Temperature = 184.87 C Pressure = 500.00 bar Mixer frac. = 0.1000000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
argentite 0.2992E-07 -7.524 0.7414E-05 -5.130 1.961 0.1041E-05
topaz 0.9656E-06 -6.015 0.1777E-03 -3.750 47.01 0.4975E-04
galena 0.5930E-06 -6.227 0.1419E-03 -3.848 37.53 0.1867E-04
sphalerite 0.5240E-06 -6.281 0.5105E-04 -4.292 13.50 0.1248E-04
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
argentite 0.1000E+01 0.1000E+01 1.0000 0.000
topaz 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.1000000
Solid products produced: Mass = 0.000378 g Volume = 0.000082 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.300
AFFINITY: 0.3949E+03
GOLD Q/K: 0.0248
SILVER Q/K: 0.2952
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 184.8730 deg.C
Sat. pressure: 88.3601 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.2168E+00 0.6609 0.1266E+02 0.1915E+02
CO2,gas 0.7832E+00 0.9036 0.6253E+02 0.6921E+02
CH4,gas 0.1996E-07 1.1161 0.1969E-05 0.1764E-05
H2,gas 0.2079E-05 1.0391 0.1909E-03 0.1837E-03
H2S,gas 0.7188E-05 0.8338 0.5296E-03 0.6351E-03
S2,gas 0.9230E-16 1.0000 0.8155E-14 0.8155E-14
CO,gas 0.3228E-07 1.0000 0.2853E-05 0.2853E-05
SO3,gas 0.3803E-26 1.0000 0.3360E-24 0.3360E-24
O2,gas 0.1904E-42 1.0000 0.1682E-40 0.1682E-40
SO2,gas 0.4174E-12 1.0000 0.3688E-10 0.3688E-10
HF,gas 0.3807E-07 1.0000 0.3363E-05 0.3363E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
196 argentite -22.66 -22.66 0.00 0.000 0.74459E-11
225 topaz -19.88 -19.88 0.00 0.000 0.14892E-10
260 galena -10.35 -10.35 0.00 0.000 0.37230E-11
272 sphalerite -9.73 -9.73 0.00 0.000 0.37230E-11
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.58 -0.02 -1.60 -1.597 0.33462E+04 1.102
2 CO2,gas -6.37 -7.27 -0.90 -0.301 0.18923E+04 1.796
3 CH4,gas 5.45 -2.96 -8.40 -2.101 0.17615E+05 -5.706
4 H2,gas 7.49 1.07 -6.42 -3.667 0.13451E+05 -3.719
5 H2S,gas -5.61 -11.58 -5.98 -2.988 0.12523E+05 -3.276
6 S2,gas -8.51 -25.30 -16.79 -2.583 0.35184E+05 -14.089
7 CO,gas 2.06 -6.18 -8.24 -2.537 0.17278E+05 -5.545
8 SO3,gas 11.26 -15.91 -27.17 -6.793 0.56949E+05 -24.474
9 O2,gas 41.30 -2.17 -43.47 -28.982 0.91112E+05 -40.774
10 SO2,gas -1.69 -14.82 -13.13 -3.502 0.27523E+05 -10.433
11 HF,gas -0.46 -8.64 -8.17 -4.086 0.17128E+05 -5.473
12 HCl,gas 1.07 -5.63 -6.70 -3.352 0.14051E+05 -6.704
13 acmite 6.21 2.95 -3.27 -0.339 0.68450E+04
17 albite-high -1.24 -2.54 -1.30 -0.100 0.27156E+04
18 albite -1.96 -2.54 -0.58 -0.045 0.12138E+04
22 analcite 1.14 0.00 -1.14 -0.127 0.23997E+04
23 andalusite -0.53 -2.62 -2.09 -0.209 0.43752E+04
26 anhydrite -6.54 -9.40 -2.87 -1.433 0.60050E+04
27 ankerite -3.79 -4.59 -0.80 -0.133 0.16717E+04
31 anorthite 5.40 1.33 -4.07 -0.313 0.85366E+04
34 aragonite 0.02 -0.76 -0.78 -0.260 0.16375E+04
35 brucite 9.88 5.43 -4.46 -0.892 0.93441E+04
36 calcite -0.12 -0.76 -0.64 -0.214 0.13456E+04
37 carnegieite-low 5.67 2.57 -3.10 -0.443 0.65023E+04
38 carnegieite-high 6.40 2.57 -3.83 -0.546 0.80176E+04
39 carpholite-Mg 2.57 0.23 -2.35 -0.156 0.49171E+04
40 carpholite-Fe 1.01 -1.78 -2.78 -0.186 0.58325E+04
41 celadonite 2.81 -1.09 -3.90 -0.230 0.81802E+04
42 celadonite-Fe 1.48 -3.10 -4.58 -0.269 0.95993E+04
49 chloritoid-Mg 5.89 2.80 -3.09 -0.206 0.64710E+04
50 chloritoid-Fe 2.67 0.80 -1.87 -0.125 0.39211E+04
51 chloritoid-Mn 4.86 1.65 -3.21 -0.214 0.67276E+04
53 coesite -1.89 -2.56 -0.67 -0.222 0.13977E+04
58 corundum 2.16 -0.07 -2.23 -0.203 0.46736E+04
60 cristobalite -2.08 -2.56 -0.48 -0.158 0.99645E+03
63 cymrite-K 0.00 -3.98 -3.98 -0.332 0.83483E+04
65 diaspore 0.31 -0.04 -0.35 -0.058 0.73242E+03
66 diamond -2.23 -5.09 -2.86 -0.818 0.60015E+04
69 dolomite,ordered -1.55 -2.58 -1.03 -0.172 0.21673E+04
83 gibbsite 1.55 -0.06 -1.61 -0.230 0.33749E+04
86 goethite 4.65 2.89 -1.76 -0.382 0.36990E+04
87 graphite -2.62 -5.09 -2.47 -0.706 0.51813E+04
90 halite 1.41 -0.46 -1.87 -0.935 0.39202E+04
91 hematite 8.70 5.80 -2.91 -0.352 0.60941E+04
92 heulandite -8.60 -11.56 -2.97 -0.135 0.62173E+04
96 jadeite 1.96 0.02 -1.95 -0.195 0.40772E+04
98 kalsilite 4.61 1.15 -3.46 -0.495 0.72609E+04
99 kaolinite -4.76 -5.22 -0.46 -0.042 0.96272E+03
100 kyanite -0.58 -2.62 -2.04 -0.204 0.42706E+04
102 laumontite -1.31 -3.86 -2.55 -0.170 0.53360E+04
103 lawsonite 4.00 1.29 -2.71 -0.181 0.56842E+04
104 leucite 1.67 -1.41 -3.08 -0.308 0.64517E+04
107 magnesite -0.67 -1.82 -1.15 -0.385 0.24178E+04
108 magnetite 14.03 9.24 -4.80 -0.392 0.10052E+05
114 margarite 5.08 1.24 -3.84 -0.154 0.80468E+04
117 microcline -3.44 -3.96 -0.52 -0.040 0.10940E+04
120 mullite-Si 1.21 -2.62 -3.84 -0.384 0.80412E+04
121 muscovite -3.53 -4.05 -0.52 -0.031 0.10905E+04
122 paragonite -2.33 -2.63 -0.29 -0.017 0.61640E+03
123 nepheline 5.08 2.57 -2.51 -0.359 0.52608E+04
143 pyrite -19.37 -20.77 -1.40 -0.329 0.29316E+04
144 pyrrhotite -4.86 -8.12 -3.25 -1.085 0.68207E+04
145 pyrrhotiteFe0.875 -6.24 -8.68 -2.45 -0.901 0.51322E+04
146 pyroxmangite 5.66 1.74 -3.92 -0.783 0.82071E+04
147 pyrophyllite -9.00 -10.31 -1.31 -0.082 0.27399E+04
148 quartz -2.39 -2.56 -0.16 -0.054 0.34059E+03
153 rhodochrosite -1.69 -2.97 -1.28 -0.427 0.26832E+04
154 rhodonite 5.68 1.74 -3.94 -0.789 0.82653E+04
155 sanidine -2.45 -3.96 -1.51 -0.116 0.31628E+04
157 siderite -3.37 -3.83 -0.46 -0.152 0.95704E+03
158 sillimanite -0.36 -2.62 -2.26 -0.226 0.47462E+04
165 stilbite -8.55 -11.58 -3.04 -0.145 0.63639E+04
168 stishovite 2.38 -2.56 -4.93 -1.645 0.10342E+05
171 sulfur -8.52 -12.65 -4.13 -1.271 0.86595E+04
172 sylvite 1.42 -1.88 -3.30 -1.652 0.69253E+04
180 topaz-H -0.23 -2.64 -2.42 -0.220 0.50659E+04
181 tridymite -2.11 -2.56 -0.44 -0.148 0.92984E+03
184 troilite-low -4.93 -8.12 -3.19 -1.062 0.66758E+04
190 wairakite -1.02 -3.82 -2.80 -0.165 0.58721E+04
192 wollastonite 8.38 3.95 -4.43 -0.886 0.92852E+04
193 pseudo-wollastonite 8.78 3.95 -4.82 -0.965 0.10109E+05
197 arsenic -5.63 -9.85 -4.22 -1.088 0.88389E+04
199 arsenopyrite -13.50 -17.97 -4.47 -0.795 0.93682E+04
200 beidellite-Ca -6.16 -8.40 -2.24 -0.139 0.46957E+04
201 beidellite-H -6.63 -9.48 -2.84 -0.182 0.59620E+04
202 beidellite-K -5.74 -8.24 -2.50 -0.153 0.52486E+04
203 beidellite-Mg -6.40 -8.58 -2.18 -0.135 0.45686E+04
204 beidellite-Na -5.65 -7.77 -2.12 -0.130 0.44487E+04
205 bornite -73.81 -74.49 -0.69 -0.051 0.14396E+04
207 chalcedony -2.24 -2.56 -0.31 -0.105 0.66009E+03
208 chalcocite -22.58 -24.02 -1.44 -0.360 0.30164E+04
210 covellite -16.57 -18.33 -1.77 -0.674 0.37076E+04
211 dawsonite 0.04 -2.16 -2.20 -0.275 0.46079E+04
213 montmorillonite-Ca -5.38 -7.43 -2.04 -0.126 0.42828E+04
214 montmorillonite-K -5.06 -7.27 -2.21 -0.135 0.46288E+04
215 montmorillonite-Mg -5.62 -7.60 -1.99 -0.123 0.41618E+04
216 montmorillonite-Na -4.90 -6.80 -1.90 -0.116 0.39829E+04
217 nontronite-Ca 0.93 -2.54 -3.47 -0.225 0.72745E+04
218 nontronite-H 0.45 -3.62 -4.07 -0.273 0.85321E+04
219 nontronite-K 1.35 -2.38 -3.73 -0.240 0.78271E+04
220 nontronite-Mg 0.72 -2.71 -3.44 -0.223 0.72094E+04
221 nontronite-Na 1.44 -1.91 -3.35 -0.215 0.70295E+04
229 gypsum -5.62 -9.44 -3.82 -0.956 0.80148E+04
245 acanthite -22.48 -22.66 -0.17 -0.044 0.36523E+03
251 barite -9.60 -12.26 -2.66 -1.328 0.55682E+04
252 boehmite 1.41 -0.04 -1.45 -0.242 0.30405E+04
253 cerussite -2.80 -6.06 -3.25 -1.085 0.68212E+04
254 chalcopyrite -25.01 -26.45 -1.44 -0.268 0.30243E+04
255 chlorargyrite -6.18 -11.17 -4.99 -2.493 0.10450E+05
256 copper,native -1.71 -5.69 -3.98 -1.384 0.83375E+04
257 dolomite,disordered -1.09 -2.58 -1.49 -0.249 0.31314E+04
258 ferrous-oxide 7.15 3.44 -3.71 -0.928 0.77824E+04
259 fluorite -10.18 -10.75 -0.56 -0.188 0.11833E+04
261 gold,native -13.95 -15.56 -1.61 -0.558 0.33652E+04
262 silver,native -4.47 -5.00 -0.53 -0.184 0.11105E+04
263 huntite -1.50 -6.23 -4.72 -0.394 0.98983E+04
269 silica-amorphous -1.71 -2.56 -0.85 -0.283 0.17763E+04
270 smithsonite -1.73 -5.44 -3.70 -1.234 0.77606E+04
273 wurtzite -8.24 -9.73 -1.49 -0.497 0.31243E+04
274 zincite 5.99 1.83 -4.16 -1.040 0.87182E+04
275 an20ab80 -0.70 -1.76 -1.06 -0.082 0.22232E+04
276 an25ab75 -0.36 -1.57 -1.21 -0.093 0.25329E+04
277 an30ab70 -0.02 -1.38 -1.36 -0.105 0.28545E+04
Calculations done for 184.8730 Deg. C; 500.0000 bar
Mixer fraction: 0.1000000
Temperature Stoc.ionic strength Heat per mole
Actual solution: 184.873 .15851E+01 3.491
Mixing solution: 25.000 .50000E-10 0.646
Fract. of mixing solution added: 0.050000
BITMOL = 0.2775E+01 OLDMOL = 0.6261E+02
New heat: 3.370 New temperature: 178.252
New mixer fraction: 0.1500000
Resulting temperature: 178.252Deg. C
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1296E-03
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 8 Loop limit = 70
Temperature = 178.25 C Pressure = 500.00 bar Mixer fraction = 0.1500000
Water: Moles liquid = 0.6397E+02 kg liquid = 0.1152E+01
Moles total = 0.6364E+02 kg total = 0.1147E+01 Activity = 0.9568
Stoichiometric ionic strength = .1516004E+01 Osmotic coef. = 0.9140
True ionic strength = .1123357E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.87311E-05 -5.0589 0.44396E-05 -5.3527 0.50848E+00 -0.2937
2 H2O 0.95679E+00 -0.0192 0.95679E+00 -0.0192
3 Cl- 0.10975E+01 0.0404 0.58690E+00 -0.2314 0.53478E+00 -0.2718
4 SO4-- 0.14802E-03 -3.8297 0.80013E-05 -5.0968 0.54057E-01 -1.2671
5 HCO3- 0.23012E-01 -1.6380 0.12703E-01 -1.8961 0.55202E+00 -0.2580
6 HS- 0.10846E-05 -5.9647 0.58201E-06 -6.2351 0.53661E+00 -0.2703
7 H4SiO4 0.24309E-02 -2.6142 0.24309E-02 -2.6142 0.10000E+01 0.0000
8 Al+++ 0.97909E-13 -13.0092 0.11139E-15 -15.9532 0.11377E-02 -2.9440
9 Ca++ 0.11900E-02 -2.9244 0.57278E-04 -4.2420 0.48131E-01 -1.3176
10 Mg++ 0.11126E-03 -3.9536 0.49113E-05 -5.3088 0.44141E-01 -1.3552
11 Fe++ 0.10768E-05 -5.9679 0.48565E-07 -7.3137 0.45101E-01 -1.3458
12 K+ 0.38468E-01 -1.4149 0.21391E-01 -1.6698 0.55606E+00 -0.2549
13 Na+ 0.10801E+01 0.0335 0.57766E+00 -0.2383 0.53483E+00 -0.2718
14 Mn++ 0.81367E-05 -5.0896 0.37285E-06 -6.4285 0.45824E-01 -1.3389
15 Zn++ 0.30583E-07 -7.5145 0.13793E-08 -8.8603 0.45101E-01 -1.3458
16 Cu+ 0.45060E-11 -11.3462 0.24072E-11 -11.6185 0.53422E+00 -0.2723
17 Pb++ 0.54762E-08 -8.2615 0.27770E-09 -9.5564 0.50711E-01 -1.2949
18 Ag+ 0.15785E-10 -10.8018 0.87141E-11 -11.0598 0.55206E+00 -0.2580
19 Au+ 0.40085E-21 -21.3970 0.22381E-21 -21.6501 0.55833E+00 -0.2531
20 Ba++ 0.15661E-05 -5.8052 0.82138E-07 -7.0855 0.52448E-01 -1.2803
21 F- 0.11521E-02 -2.9385 0.58050E-03 -3.2362 0.50386E+00 -0.2977
22 H2AsO3- 0.86599E-06 -6.0625 0.59004E-06 -6.2291 0.68134E+00 -0.1666
24 HSiO3- 0.23155E-05 -5.6354 0.12383E-05 -5.9072 0.53478E+00 -0.2718
25 Ca(HSiO3)+ 0.10534E-07 -7.9774 0.58816E-08 -8.2305 0.55833E+00 -0.2531
26 Mg(HSiO3)+ 0.81725E-09 -9.0876 0.45629E-09 -9.3408 0.55833E+00 -0.2531
27 NaHSiO3,aq 0.58116E-05 -5.2357 0.58116E-05 -5.2357 0.10000E+01 0.0000
31 AgCl,aq 0.28143E-08 -8.5506 0.28143E-08 -8.5506 0.10000E+01 0.0000
32 AgCl2- 0.12607E-06 -6.8994 0.67418E-07 -7.1712 0.53478E+00 -0.2718
33 AgCl3-2 0.81362E-07 -7.0896 0.42458E-08 -8.3720 0.52184E-01 -1.2825
34 AgCl4-3 0.12628E-07 -7.8987 0.14172E-10 -10.8486 0.11223E-02 -2.9499
38 Ag(HS),aq 0.78275E-08 -8.1064 0.78275E-08 -8.1064 0.10000E+01 0.0000
40 AlO+ 0.18989E-09 -9.7215 0.10602E-09 -9.9746 0.55833E+00 -0.2531
42 HAlO2,aq 0.33015E-07 -7.4813 0.33015E-07 -7.4813 0.10000E+01 0.0000
43 AlO2- 0.23182E-06 -6.6349 0.11789E-06 -6.9285 0.50857E+00 -0.2937
44 AsO2- 0.16746E-06 -6.7761 0.89554E-07 -7.0479 0.53478E+00 -0.2718
45 HAsO2,aq 0.31043E-04 -4.5080 0.31043E-04 -4.5080 0.10000E+01 0.0000
46 H3AsO3,aq 0.80419E-04 -4.0946 0.80419E-04 -4.0946 0.10000E+01 0.0000
48 H2AsO4- 0.83860E-10 -10.0764 0.44846E-10 -10.3483 0.53478E+00 -0.2718
49 HAsO4-2 0.16914E-10 -10.7718 0.88262E-12 -12.0542 0.52184E-01 -1.2825
62 BaCO3,aq 0.38261E-09 -9.4172 0.38261E-09 -9.4172 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.11949E-05 -5.9227 0.67972E-06 -6.1677 0.56885E+00 -0.2450
64 BaCl+ 0.76468E-06 -6.1165 0.42694E-06 -6.3696 0.55833E+00 -0.2531
65 BaF+ 0.86386E-09 -9.0636 0.48232E-09 -9.3167 0.55833E+00 -0.2531
66 CH4,aq 0.10117E-08 -8.9949 0.92057E-09 -9.0359 0.90992E+00 -0.0410
71 CO,aq 0.15612E-08 -8.8065 0.15612E-08 -8.8065 0.10000E+01 0.0000
72 CO2,aq 0.28048E+00 -0.5521 0.25521E+00 -0.5931 0.90992E+00 -0.0410
73 CO3-2 0.46370E-05 -5.3338 0.24198E-06 -6.6162 0.52184E-01 -1.2825
74 CaCO3,aq 0.10637E-05 -5.9732 0.10637E-05 -5.9732 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.14286E-03 -3.8451 0.79761E-04 -4.0982 0.55833E+00 -0.2531
76 CaCl+ 0.45107E-03 -3.3458 0.25184E-03 -3.5989 0.55833E+00 -0.2531
77 CaCl2,aq 0.36989E-04 -4.4319 0.36989E-04 -4.4319 0.10000E+01 0.0000
78 CaF+ 0.42240E-05 -5.3743 0.23584E-05 -5.6274 0.55833E+00 -0.2531
79 CaOH+ 0.93325E-07 -7.0300 0.52106E-07 -7.2831 0.55833E+00 -0.2531
80 CaSO4,aq 0.47227E-06 -6.3258 0.47227E-06 -6.3258 0.10000E+01 0.0000
81 HCl,aq 0.13160E-05 -5.8807 0.13160E-05 -5.8807 0.10000E+01 0.0000
90 CuCl,aq 0.65590E-08 -8.1832 0.65590E-08 -8.1832 0.10000E+01 0.0000
91 CuCl2- 0.11662E-06 -6.9332 0.62367E-07 -7.2050 0.53478E+00 -0.2718
92 CuCl3-2 0.24471E-07 -7.6114 0.12770E-08 -8.8938 0.52184E-01 -1.2825
98 HF,aq 0.76758E-04 -4.1149 0.76758E-04 -4.1149 0.10000E+01 0.0000
99 HF2- 0.23704E-07 -7.6252 0.12677E-07 -7.8970 0.53478E+00 -0.2718
101 FeCl+ 0.29297E-06 -6.5332 0.16357E-06 -6.7863 0.55833E+00 -0.2531
102 FeCl2,aq 0.12307E-08 -8.9099 0.12307E-08 -8.9099 0.10000E+01 0.0000
104 FeF+ 0.76282E-08 -8.1176 0.42590E-08 -8.3707 0.55833E+00 -0.2531
106 FeO,aq 0.49060E-10 -10.3093 0.49060E-10 -10.3093 0.10000E+01 0.0000
107 FeOH+ 0.12541E-07 -7.9017 0.70019E-08 -8.1548 0.55833E+00 -0.2531
112 HFeO2,aq 0.42557E-10 -10.3710 0.42557E-10 -10.3710 0.10000E+01 0.0000
113 H2,aq 0.14128E-06 -6.8499 0.12856E-06 -6.8909 0.90992E+00 -0.0410
114 KCl,aq 0.96219E-03 -3.0167 0.96219E-03 -3.0167 0.10000E+01 0.0000
115 KHSO4,aq 0.15425E-09 -9.8118 0.15425E-09 -9.8118 0.10000E+01 0.0000
116 KOH,aq 0.34116E-07 -7.4670 0.34116E-07 -7.4670 0.10000E+01 0.0000
117 KSO4- 0.14659E-04 -4.8339 0.78392E-05 -5.1057 0.53478E+00 -0.2718
118 MgCO3,aq 0.13556E-07 -7.8679 0.13556E-07 -7.8679 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.11994E-04 -4.9210 0.66969E-05 -5.1741 0.55833E+00 -0.2531
120 MgCl+ 0.24639E-04 -4.6084 0.13756E-04 -4.8615 0.55833E+00 -0.2531
121 MgF+ 0.11167E-05 -5.9521 0.62350E-06 -6.2052 0.55833E+00 -0.2531
122 MgOH+ 0.29338E-07 -7.5326 0.16380E-07 -7.7857 0.55833E+00 -0.2531
124 MnF+ 0.22634E-07 -7.6452 0.12637E-07 -7.8984 0.55833E+00 -0.2531
125 MnO,aq 0.11762E-10 -10.9295 0.11762E-10 -10.9295 0.10000E+01 0.0000
126 MnOH+ 0.12228E-07 -7.9126 0.68275E-08 -8.1657 0.55833E+00 -0.2531
131 MnCl+ 0.21743E-04 -4.6627 0.12140E-04 -4.9158 0.55833E+00 -0.2531
132 MnSO4,aq 0.34960E-08 -8.4564 0.34960E-08 -8.4564 0.10000E+01 0.0000
133 NaCl,aq 0.24203E+00 -0.6161 0.24203E+00 -0.6161 0.10000E+01 0.0000
134 NaF,aq 0.17868E-03 -3.7479 0.17868E-03 -3.7479 0.10000E+01 0.0000
135 NaOH,aq 0.69998E-06 -6.1549 0.69998E-06 -6.1549 0.10000E+01 0.0000
137 OH- 0.25416E-05 -5.5949 0.12926E-05 -5.8885 0.50857E+00 -0.2937
140 PbCl+ 0.59247E-07 -7.2273 0.33079E-07 -7.4804 0.55833E+00 -0.2531
141 PbCl2,aq 0.23804E-06 -6.6233 0.23804E-06 -6.6233 0.10000E+01 0.0000
142 PbCl3- 0.17206E-06 -6.7643 0.92016E-07 -7.0361 0.53478E+00 -0.2718
143 PbCl4-2 0.22456E-06 -6.6487 0.11719E-07 -7.9311 0.52184E-01 -1.2825
144 PbF+ 0.89791E-10 -10.0468 0.50133E-10 -10.2999 0.55833E+00 -0.2531
146 PbO,aq 0.23261E-10 -10.6334 0.23261E-10 -10.6334 0.10000E+01 0.0000
148 Pb(HS)2,aq 0.13981E-09 -9.8545 0.13981E-09 -9.8545 0.10000E+01 0.0000
150 H2S,aq 0.95173E-05 -5.0215 0.86600E-05 -5.0625 0.90992E+00 -0.0410
158 HSO3- 0.15843E-09 -9.8002 0.84725E-10 -10.0720 0.53478E+00 -0.2718
159 HSO4- 0.57975E-06 -6.2368 0.32883E-06 -6.4830 0.56718E+00 -0.2463
161 S2O3-2 0.19446E-10 -10.7112 0.10148E-11 -11.9936 0.52184E-01 -1.2825
173 ZnCl+ 0.42852E-05 -5.3680 0.23925E-05 -5.6211 0.55833E+00 -0.2531
174 ZnCl2,aq 0.10435E-05 -5.9815 0.10435E-05 -5.9815 0.10000E+01 0.0000
175 ZnCl3- 0.13698E-06 -6.8634 0.73252E-07 -7.1352 0.53478E+00 -0.2718
176 ZnF+ 0.14381E-09 -9.8422 0.80293E-10 -10.0953 0.55833E+00 -0.2531
177 ZnO,aq 0.19311E-09 -9.7142 0.19311E-09 -9.7142 0.10000E+01 0.0000
178 ZnOH+ 0.18422E-06 -6.7347 0.10286E-06 -6.9878 0.55833E+00 -0.2531
Charge balance for all species = -.1125E-03
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.8731124E-05 0.2806690E+00 0.2586819E+03 0.0000
2 H2O 0.1000000E+01 0.5522774E+02 0.9097785E+06 0.0000
3 Cl- 0.1097454E+01 0.1341035E+01 0.4347404E+05 5.1212
4 SO4-- 0.1480156E-03 0.1636934E-03 0.1437865E+02 5.6085
5 HCO3- 0.2301233E-01 0.3036532E+00 0.1694209E+05 3.4566
6 HS- 0.1084612E-05 0.1064681E-04 0.3219710E+00 -0.8824
7 H4SiO4 0.2430863E-02 0.2439002E-02 0.2143591E+03 -2.6142
8 Al+++ 0.9790893E-13 0.2650273E-06 0.6538735E-02 0.1048
9 Ca++ 0.1190048E-02 0.1826827E-02 0.6694842E+02 6.4633
10 Mg++ 0.1112635E-03 0.1490571E-03 0.3313677E+01 5.3965
11 Fe++ 0.1076816E-05 0.1391283E-05 0.7104804E-01 3.3916
12 K+ 0.3846807E-01 0.3944495E-01 0.1410352E+04 3.6829
13 Na+ 0.1080070E+01 0.1322290E+01 0.2779705E+05 5.1143
14 Mn++ 0.8136663E-05 0.2991783E-04 0.1502934E+01 4.2768
15 Zn++ 0.3058307E-07 0.5680835E-05 0.3395687E+00 1.8450
16 Cu+ 0.4506005E-11 0.1476554E-06 0.8578936E-02 -6.2658
17 Pb++ 0.5476186E-08 0.6996430E-06 0.1325508E+00 1.1489
18 Ag+ 0.1578489E-10 0.2307189E-06 0.2275730E-01 -5.7071
19 Au+ 0.4008488E-21 0.2699564E-11 0.4862102E-06 -16.2975
20 Ba++ 0.1566094E-05 0.3526920E-05 0.4429244E+00 3.6199
21 F- 0.1152116E-02 0.1412970E-02 0.2454584E+02 2.1165
22 H2AsO3- 0.8659936E-06 0.1124963E-03 0.1285173E+02 -0.8765
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234411E+00 -.5964725E-05 0.0000000E+00
2 H2O 0.6364409E+02 0.6364409E+02 0.0000000E+00 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1226931E-04 0.1760999E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810690E-02 0.1050932E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.3054158E-06 0.2101863E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.6546559E-05 0.9216176E-06 0.0000000E+00
16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00
17 Pb++ 0.1565021E-05 0.8062641E-06 0.7587566E-06 0.0000000E+00
18 Ag+ 0.4271281E-06 0.2658790E-06 0.1612491E-06 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1628298E-02 0.2101863E-05 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.126027E+04 g
Temperature = 178.25 C Pressure = 500.00 bar Mixer frac. = 0.1500000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
argentite 0.8062E-07 -7.094 0.1998E-04 -4.699 4.122 0.2806E-05
topaz 0.1051E-05 -5.978 0.1934E-03 -3.714 39.90 0.5415E-04
galena 0.7588E-06 -6.120 0.1815E-03 -3.741 37.45 0.2389E-04
sphalerite 0.9216E-06 -6.035 0.8979E-04 -4.047 18.52 0.2196E-04
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
argentite 0.1000E+01 0.1000E+01 1.0000 0.000
topaz 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.1500000
Solid products produced: Mass = 0.000485 g Volume = 0.000103 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.300
AFFINITY: 0.3936E+03
GOLD Q/K: 0.0293
SILVER Q/K: 0.2669
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 178.2522 deg.C
Sat. pressure: 83.2311 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.1965E+00 0.6722 0.1099E+02 0.1636E+02
CO2,gas 0.8035E+00 0.9026 0.6036E+02 0.6688E+02
CH4,gas 0.1805E-07 1.1056 0.1661E-05 0.1503E-05
H2,gas 0.1687E-05 1.0374 0.1456E-03 0.1404E-03
H2S,gas 0.7016E-05 0.8358 0.4881E-03 0.5840E-03
S2,gas 0.7351E-16 1.0000 0.6118E-14 0.6118E-14
CO,gas 0.2487E-07 1.0000 0.2070E-05 0.2070E-05
SO3,gas 0.1827E-26 1.0000 0.1520E-24 0.1520E-24
O2,gas 0.4002E-43 1.0000 0.3331E-41 0.3331E-41
SO2,gas 0.3072E-12 1.0000 0.2557E-10 0.2557E-10
HF,gas 0.3296E-07 1.0000 0.2743E-05 0.2743E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
196 argentite -23.00 -23.00 0.00 0.000 -0.73383E-11
225 topaz -19.58 -19.58 0.00 0.000 0.00000E+00
260 galena -10.44 -10.44 0.00 0.000 0.00000E+00
272 sphalerite -9.74 -9.74 0.00 0.000 0.00000E+00
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.64 -0.02 -1.66 -1.658 0.34243E+04 1.041
2 CO2,gas -6.31 -7.23 -0.92 -0.306 0.18966E+04 1.781
3 CH4,gas 5.43 -3.05 -8.48 -2.120 0.17513E+05 -5.780
4 H2,gas 7.57 1.03 -6.54 -3.735 0.13500E+05 -3.837
5 H2S,gas -5.58 -11.59 -6.01 -3.005 0.12415E+05 -3.311
6 S2,gas -8.33 -25.24 -16.91 -2.602 0.34933E+05 -14.213
7 CO,gas 2.21 -6.18 -8.38 -2.579 0.17316E+05 -5.684
8 SO3,gas 11.73 -15.78 -27.52 -6.879 0.56838E+05 -24.818
9 O2,gas 42.07 -2.11 -44.18 -29.451 0.91248E+05 -41.477
10 SO2,gas -1.44 -14.73 -13.29 -3.544 0.27454E+05 -10.592
11 HF,gas -0.33 -8.59 -8.26 -4.130 0.17063E+05 -5.562
12 HCl,gas 1.23 -5.58 -6.82 -3.409 0.14083E+05 -6.818
13 acmite 6.32 2.80 -3.52 -0.366 0.72790E+04
17 albite-high -1.09 -2.55 -1.46 -0.112 0.30157E+04
18 albite -1.83 -2.55 -0.72 -0.055 0.14868E+04
22 analcite 1.31 0.01 -1.30 -0.144 0.26825E+04
23 andalusite -0.13 -2.42 -2.29 -0.229 0.47347E+04
26 anhydrite -6.41 -9.34 -2.93 -1.465 0.60537E+04
27 ankerite -3.63 -4.64 -1.01 -0.168 0.20864E+04
31 anorthite 5.94 1.44 -4.49 -0.346 0.92803E+04
34 aragonite 0.11 -0.79 -0.89 -0.298 0.18438E+04
35 brucite 10.06 5.36 -4.70 -0.940 0.97112E+04
36 calcite -0.03 -0.79 -0.75 -0.251 0.15565E+04
37 carnegieite-low 5.92 2.60 -3.31 -0.473 0.68381E+04
38 carnegieite-high 6.66 2.60 -4.06 -0.579 0.83782E+04
39 carpholite-Mg 3.01 0.34 -2.67 -0.178 0.55079E+04
40 carpholite-Fe 1.42 -1.67 -3.09 -0.206 0.63764E+04
41 celadonite 3.00 -1.20 -4.20 -0.247 0.86767E+04
42 celadonite-Fe 1.67 -3.20 -4.87 -0.287 0.10063E+05
49 chloritoid-Mg 6.41 2.93 -3.47 -0.231 0.71723E+04
50 chloritoid-Fe 3.14 0.93 -2.21 -0.147 0.45574E+04
51 chloritoid-Mn 5.33 1.81 -3.51 -0.234 0.72581E+04
53 coesite -1.92 -2.58 -0.66 -0.219 0.13601E+04
58 corundum 2.61 0.15 -2.45 -0.223 0.50677E+04
60 cristobalite -2.11 -2.58 -0.47 -0.157 0.97077E+03
63 cymrite-K 0.13 -4.00 -4.13 -0.344 0.85338E+04
65 diaspore 0.49 0.07 -0.42 -0.070 0.87343E+03
66 diamond -2.28 -5.12 -2.84 -0.811 0.58634E+04
69 dolomite,ordered -1.37 -2.64 -1.27 -0.212 0.26274E+04
83 gibbsite 1.72 0.05 -1.68 -0.239 0.34609E+04
86 goethite 4.78 2.84 -1.94 -0.419 0.40059E+04
87 graphite -2.68 -5.12 -2.44 -0.699 0.50501E+04
90 halite 1.43 -0.47 -1.90 -0.952 0.39337E+04
91 hematite 8.98 5.69 -3.28 -0.398 0.67838E+04
92 heulandite -8.36 -11.55 -3.19 -0.145 0.65971E+04
96 jadeite 2.13 0.03 -2.10 -0.210 0.43357E+04
98 kalsilite 4.83 1.17 -3.66 -0.522 0.75498E+04
99 kaolinite -4.50 -5.04 -0.54 -0.049 0.11125E+04
100 kyanite -0.19 -2.42 -2.23 -0.223 0.46149E+04
102 laumontite -0.99 -3.78 -2.80 -0.186 0.57744E+04
103 lawsonite 4.41 1.41 -3.00 -0.200 0.62001E+04
104 leucite 1.86 -1.40 -3.26 -0.326 0.67348E+04
107 magnesite -0.56 -1.85 -1.29 -0.431 0.26707E+04
114 margarite 5.97 1.58 -4.39 -0.176 0.90687E+04
117 microcline -3.35 -3.98 -0.63 -0.049 0.13028E+04
120 mullite-Si 1.65 -2.42 -4.07 -0.407 0.84148E+04
121 muscovite -3.07 -3.85 -0.78 -0.046 0.16048E+04
122 paragonite -1.84 -2.41 -0.57 -0.034 0.11807E+04
123 nepheline 5.32 2.60 -2.71 -0.387 0.55999E+04
143 pyrite -19.44 -20.82 -1.37 -0.323 0.28380E+04
144 pyrrhotite -4.80 -8.20 -3.40 -1.132 0.70129E+04
145 pyrrhotiteFe0.875 -6.20 -8.75 -2.55 -0.939 0.52711E+04
146 pyroxmangite 5.78 1.68 -4.09 -0.819 0.84572E+04
147 pyrophyllite -8.77 -10.17 -1.40 -0.088 0.28942E+04
148 quartz -2.43 -2.58 -0.15 -0.049 0.30498E+03
153 rhodochrosite -1.63 -2.97 -1.35 -0.449 0.27814E+04
154 rhodonite 5.81 1.68 -4.12 -0.825 0.85177E+04
155 sanidine -2.35 -3.98 -1.63 -0.126 0.33718E+04
157 siderite -3.30 -3.86 -0.56 -0.187 0.11572E+04
158 sillimanite 0.05 -2.42 -2.47 -0.247 0.51099E+04
165 stilbite -8.42 -11.57 -3.15 -0.150 0.64978E+04
168 stishovite 2.40 -2.58 -4.98 -1.659 0.10280E+05
171 sulfur -8.53 -12.62 -4.09 -1.258 0.84475E+04
172 sylvite 1.43 -1.90 -3.33 -1.666 0.68816E+04
180 topaz-H 0.12 -2.44 -2.57 -0.233 0.53028E+04
181 tridymite -2.14 -2.58 -0.44 -0.146 0.90212E+03
184 troilite-low -4.88 -8.20 -3.32 -1.107 0.68593E+04
190 wairakite -0.63 -3.75 -3.12 -0.183 0.64359E+04
192 wollastonite 8.53 3.87 -4.66 -0.932 0.96288E+04
197 arsenic -5.74 -9.97 -4.23 -1.092 0.87439E+04
199 arsenopyrite -13.58 -18.17 -4.59 -0.816 0.94820E+04
200 beidellite-Ca -5.81 -8.23 -2.42 -0.150 0.49969E+04
201 beidellite-H -6.30 -9.30 -3.00 -0.191 0.61923E+04
202 beidellite-K -5.41 -8.08 -2.67 -0.164 0.55202E+04
203 beidellite-Mg -6.05 -8.41 -2.36 -0.146 0.48797E+04
204 beidellite-Na -5.32 -7.61 -2.29 -0.140 0.47376E+04
205 bornite -74.69 -74.81 -0.12 -0.009 0.24657E+03
207 chalcedony -2.27 -2.58 -0.30 -0.101 0.62479E+03
208 chalcocite -22.90 -24.12 -1.22 -0.304 0.25101E+04
210 covellite -16.76 -18.37 -1.61 -0.613 0.33241E+04
211 dawsonite 0.16 -2.07 -2.23 -0.279 0.46103E+04
213 montmorillonite-Ca -5.14 -7.36 -2.22 -0.137 0.45892E+04
214 montmorillonite-K -4.83 -7.21 -2.38 -0.146 0.49138E+04
215 montmorillonite-Mg -5.37 -7.53 -2.17 -0.134 0.44768E+04
216 montmorillonite-Na -4.67 -6.74 -2.07 -0.127 0.42767E+04
217 nontronite-Ca 1.12 -2.69 -3.81 -0.247 0.78687E+04
218 nontronite-H 0.62 -3.76 -4.38 -0.294 0.90557E+04
219 nontronite-K 1.52 -2.54 -4.06 -0.261 0.83920E+04
220 nontronite-Mg 0.91 -2.87 -3.78 -0.245 0.78132E+04
221 nontronite-Na 1.61 -2.07 -3.68 -0.237 0.76115E+04
229 gypsum -5.53 -9.38 -3.85 -0.962 0.79444E+04
245 acanthite -22.83 -23.00 -0.17 -0.043 0.35628E+03
251 barite -9.55 -12.18 -2.64 -1.318 0.54440E+04
252 boehmite 1.62 0.07 -1.55 -0.259 0.32068E+04
253 cerussite -2.78 -6.10 -3.32 -1.105 0.68500E+04
254 chalcopyrite -25.20 -26.57 -1.37 -0.255 0.28335E+04
256 copper,native -1.80 -5.75 -3.95 -1.375 0.81639E+04
257 dolomite,disordered -0.89 -2.64 -1.75 -0.291 0.36105E+04
258 ferrous-oxide 7.33 3.37 -3.96 -0.991 0.81841E+04
259 fluorite -10.12 -10.71 -0.60 -0.198 0.12295E+04
261 gold,native -14.25 -15.78 -1.53 -0.533 0.31670E+04
262 silver,native -4.62 -5.19 -0.57 -0.200 0.11849E+04
269 silica-amorphous -1.73 -2.58 -0.85 -0.283 0.17544E+04
270 smithsonite -1.65 -5.40 -3.76 -1.253 0.77618E+04
273 wurtzite -8.23 -9.74 -1.51 -0.504 0.31248E+04
274 zincite 6.14 1.83 -4.31 -1.078 0.89064E+04
275 an20ab80 -0.49 -1.75 -1.26 -0.097 0.25972E+04
276 an25ab75 -0.13 -1.55 -1.42 -0.109 0.29308E+04
277 an30ab70 0.24 -1.35 -1.59 -0.122 0.32766E+04
Calculations done for 178.2522 Deg. C; 500.0000 bar
Mixer fraction: 0.1500000
Temperature Stoc.ionic strength Heat per mole
Actual solution: 178.252 .15160E+01 3.370
Mixing solution: 25.000 .50000E-10 0.646
Fract. of mixing solution added: 0.050000
BITMOL = 0.2775E+01 OLDMOL = 0.6538E+02
New heat: 3.260 New temperature: 172.152
New mixer fraction: 0.2000000
Resulting temperature: 172.152Deg. C
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1296E-03
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 7 Loop limit = 70
Temperature = 172.15 C Pressure = 500.00 bar Mixer fraction = 0.2000000
Water: Moles liquid = 0.6674E+02 kg liquid = 0.1202E+01
Moles total = 0.6642E+02 kg total = 0.1197E+01 Activity = 0.9584
Stoichiometric ionic strength = .1452654E+01 Osmotic coef. = 0.9174
True ionic strength = .1090202E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.95020E-05 -5.0222 0.49419E-05 -5.3061 0.52009E+00 -0.2839
2 H2O 0.95840E+00 -0.0185 0.95840E+00 -0.0185
3 Cl- 0.10653E+01 0.0275 0.57943E+00 -0.2370 0.54390E+00 -0.2645
4 SO4-- 0.14254E-03 -3.8461 0.83980E-05 -5.0758 0.58918E-01 -1.2298
5 HCO3- 0.22067E-01 -1.6562 0.12353E-01 -1.9082 0.55977E+00 -0.2520
6 HS- 0.93694E-06 -6.0283 0.51117E-06 -6.2914 0.54558E+00 -0.2631
7 H4SiO4 0.23305E-02 -2.6325 0.23305E-02 -2.6325 0.10000E+01 0.0000
8 Al+++ 0.13893E-12 -12.8572 0.19463E-15 -15.7108 0.14009E-02 -2.8536
9 Ca++ 0.11712E-02 -2.9314 0.61837E-04 -4.2087 0.52799E-01 -1.2774
10 Mg++ 0.10801E-03 -3.9665 0.52684E-05 -5.2783 0.48777E-01 -1.3118
11 Fe++ 0.10454E-05 -5.9807 0.51999E-07 -7.2840 0.49743E-01 -1.3033
12 K+ 0.36973E-01 -1.4321 0.20824E-01 -1.6814 0.56321E+00 -0.2493
13 Na+ 0.10485E+01 0.0206 0.56991E+00 -0.2442 0.54352E+00 -0.2648
14 Mn++ 0.84651E-05 -5.0724 0.42724E-06 -6.3693 0.50471E-01 -1.2970
15 Zn++ 0.33870E-07 -7.4702 0.16848E-08 -8.7734 0.49743E-01 -1.3033
16 Cu+ 0.44872E-11 -11.3480 0.24364E-11 -11.6133 0.54296E+00 -0.2652
17 Pb++ 0.52195E-08 -8.2824 0.28920E-09 -9.5388 0.55408E-01 -1.2564
18 Ag+ 0.12027E-10 -10.9199 0.67286E-11 -11.1721 0.55948E+00 -0.2522
19 Au+ 0.28182E-21 -21.5500 0.15932E-21 -21.7977 0.56533E+00 -0.2477
20 Ba++ 0.16031E-05 -5.7950 0.91646E-07 -7.0379 0.57166E-01 -1.2429
21 F- 0.11142E-02 -2.9530 0.57508E-03 -3.2403 0.51612E+00 -0.2872
22 H2AsO3- 0.66724E-06 -6.1757 0.45509E-06 -6.3419 0.68205E+00 -0.1662
24 HSiO3- 0.19626E-05 -5.7072 0.10675E-05 -5.9716 0.54390E+00 -0.2645
25 Ca(HSiO3)+ 0.85599E-08 -8.0675 0.48391E-08 -8.3152 0.56533E+00 -0.2477
26 Mg(HSiO3)+ 0.67542E-09 -9.1704 0.38183E-09 -9.4181 0.56533E+00 -0.2477
27 NaHSiO3,aq 0.50369E-05 -5.2978 0.50369E-05 -5.2978 0.10000E+01 0.0000
31 AgCl,aq 0.21325E-08 -8.6711 0.21325E-08 -8.6711 0.10000E+01 0.0000
32 AgCl2- 0.91584E-07 -7.0382 0.49813E-07 -7.3027 0.54390E+00 -0.2645
33 AgCl3-2 0.55117E-07 -7.2587 0.31432E-08 -8.5026 0.57028E-01 -1.2439
34 AgCl4-3 0.75622E-08 -8.1214 0.10540E-10 -10.9772 0.13937E-02 -2.8558
38 Ag(HS),aq 0.73357E-08 -8.1346 0.73357E-08 -8.1346 0.10000E+01 0.0000
40 AlO+ 0.18629E-09 -9.7298 0.10532E-09 -9.9775 0.56533E+00 -0.2477
42 HAlO2,aq 0.26395E-07 -7.5785 0.26395E-07 -7.5785 0.10000E+01 0.0000
43 AlO2- 0.14281E-06 -6.8453 0.74299E-07 -7.1290 0.52028E+00 -0.2838
44 AsO2- 0.14184E-06 -6.8482 0.77145E-07 -7.1127 0.54390E+00 -0.2645
45 HAsO2,aq 0.30768E-04 -4.5119 0.30768E-04 -4.5119 0.10000E+01 0.0000
46 H3AsO3,aq 0.76241E-04 -4.1178 0.76241E-04 -4.1178 0.10000E+01 0.0000
48 H2AsO4- 0.67278E-10 -10.1721 0.36593E-10 -10.4366 0.54390E+00 -0.2645
49 HAsO4-2 0.12339E-10 -10.9087 0.70365E-12 -12.1526 0.57028E-01 -1.2439
62 BaCO3,aq 0.33691E-09 -9.4725 0.33691E-09 -9.4725 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.10614E-05 -5.9741 0.61046E-06 -6.2143 0.57517E+00 -0.2402
64 BaCl+ 0.71459E-06 -6.1459 0.40398E-06 -6.3936 0.56533E+00 -0.2477
65 BaF+ 0.82529E-09 -9.0834 0.46656E-09 -9.3311 0.56533E+00 -0.2477
66 CH4,aq 0.81776E-09 -9.0874 0.74208E-09 -9.1296 0.90745E+00 -0.0422
71 CO,aq 0.10770E-08 -8.9678 0.10770E-08 -8.9678 0.10000E+01 0.0000
72 CO2,aq 0.26881E+00 -0.5706 0.24393E+00 -0.6127 0.90745E+00 -0.0422
73 CO3-2 0.39655E-05 -5.4017 0.22615E-06 -6.6456 0.57028E-01 -1.2439
74 CaCO3,aq 0.90785E-06 -6.0420 0.90785E-06 -6.0420 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.12912E-03 -3.8890 0.72993E-04 -4.1367 0.56533E+00 -0.2477
76 CaCl+ 0.41274E-03 -3.3843 0.23333E-03 -3.6320 0.56533E+00 -0.2477
77 CaCl2,aq 0.32506E-04 -4.4880 0.32506E-04 -4.4880 0.10000E+01 0.0000
78 CaF+ 0.38573E-05 -5.4137 0.21806E-05 -5.6614 0.56533E+00 -0.2477
79 CaOH+ 0.68347E-07 -7.1653 0.38639E-07 -7.4130 0.56533E+00 -0.2477
80 CaSO4,aq 0.47463E-06 -6.3236 0.47463E-06 -6.3236 0.10000E+01 0.0000
81 HCl,aq 0.13255E-05 -5.8776 0.13255E-05 -5.8776 0.10000E+01 0.0000
90 CuCl,aq 0.65369E-08 -8.1846 0.65369E-08 -8.1846 0.10000E+01 0.0000
91 CuCl2- 0.11257E-06 -6.9486 0.61227E-07 -7.2131 0.54390E+00 -0.2645
92 CuCl3-2 0.22403E-07 -7.6497 0.12776E-08 -8.8936 0.57028E-01 -1.2439
98 HF,aq 0.73747E-04 -4.1323 0.73747E-04 -4.1323 0.10000E+01 0.0000
99 HF2- 0.22376E-07 -7.6502 0.12170E-07 -7.9147 0.54390E+00 -0.2645
101 FeCl+ 0.27020E-06 -6.5683 0.15275E-06 -6.8160 0.56533E+00 -0.2477
102 FeCl2,aq 0.74008E-09 -9.1307 0.74008E-09 -9.1307 0.10000E+01 0.0000
104 FeF+ 0.71715E-08 -8.1444 0.40542E-08 -8.3921 0.56533E+00 -0.2477
106 FeO,aq 0.28487E-10 -10.5453 0.28487E-10 -10.5453 0.10000E+01 0.0000
107 FeOH+ 0.98925E-08 -8.0047 0.55925E-08 -8.2524 0.56533E+00 -0.2477
112 HFeO2,aq 0.25898E-10 -10.5867 0.25898E-10 -10.5867 0.10000E+01 0.0000
113 H2,aq 0.10429E-06 -6.9818 0.94638E-07 -7.0239 0.90745E+00 -0.0422
114 KCl,aq 0.81809E-03 -3.0872 0.81809E-03 -3.0872 0.10000E+01 0.0000
115 KHSO4,aq 0.12187E-09 -9.9141 0.12187E-09 -9.9141 0.10000E+01 0.0000
116 KOH,aq 0.25551E-07 -7.5926 0.25551E-07 -7.5926 0.10000E+01 0.0000
117 KSO4- 0.13350E-04 -4.8745 0.72609E-05 -5.1390 0.54390E+00 -0.2645
118 MgCO3,aq 0.11895E-07 -7.9246 0.11895E-07 -7.9246 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.10821E-04 -4.9657 0.61172E-05 -5.2134 0.56533E+00 -0.2477
120 MgCl+ 0.22969E-04 -4.6389 0.12985E-04 -4.8866 0.56533E+00 -0.2477
121 MgF+ 0.10262E-05 -5.9888 0.58013E-06 -6.2365 0.56533E+00 -0.2477
122 MgOH+ 0.21796E-07 -7.6616 0.12322E-07 -7.9093 0.56533E+00 -0.2477
124 MnF+ 0.22465E-07 -7.6485 0.12700E-07 -7.8962 0.56533E+00 -0.2477
126 MnOH+ 0.10151E-07 -7.9935 0.57386E-08 -8.2412 0.56533E+00 -0.2477
131 MnCl+ 0.20172E-04 -4.6952 0.11404E-04 -4.9429 0.56533E+00 -0.2477
132 MnSO4,aq 0.36838E-08 -8.4337 0.36838E-08 -8.4337 0.10000E+01 0.0000
133 NaCl,aq 0.21860E+00 -0.6604 0.21860E+00 -0.6604 0.10000E+01 0.0000
134 NaF,aq 0.16119E-03 -3.7927 0.16119E-03 -3.7927 0.10000E+01 0.0000
135 NaOH,aq 0.54126E-06 -6.2666 0.54126E-06 -6.2666 0.10000E+01 0.0000
137 OH- 0.20137E-05 -5.6960 0.10477E-05 -5.9798 0.52028E+00 -0.2838
140 PbCl+ 0.53709E-07 -7.2700 0.30363E-07 -7.5177 0.56533E+00 -0.2477
141 PbCl2,aq 0.20089E-06 -6.6971 0.20089E-06 -6.6971 0.10000E+01 0.0000
142 PbCl3- 0.13638E-06 -6.8653 0.74177E-07 -7.1297 0.54390E+00 -0.2645
143 PbCl4-2 0.16541E-06 -6.7815 0.94327E-08 -8.0254 0.57028E-01 -1.2439
144 PbF+ 0.84045E-10 -10.0755 0.47513E-10 -10.3232 0.56533E+00 -0.2477
146 PbO,aq 0.14856E-10 -10.8281 0.14856E-10 -10.8281 0.10000E+01 0.0000
148 Pb(HS)2,aq 0.11538E-09 -9.9379 0.11538E-09 -9.9379 0.10000E+01 0.0000
150 H2S,aq 0.87791E-05 -5.0566 0.79665E-05 -5.0987 0.90745E+00 -0.0422
158 HSO3- 0.12313E-09 -9.9096 0.66969E-10 -10.1741 0.54390E+00 -0.2645
159 HSO4- 0.54796E-06 -6.2612 0.31446E-06 -6.5024 0.57387E+00 -0.2412
161 S2O3-2 0.17186E-10 -10.7648 0.98008E-12 -12.0087 0.57028E-01 -1.2439
173 ZnCl+ 0.39123E-05 -5.4076 0.22117E-05 -5.6553 0.56533E+00 -0.2477
174 ZnCl2,aq 0.91239E-06 -6.0398 0.91239E-06 -6.0398 0.10000E+01 0.0000
175 ZnCl3- 0.11635E-06 -6.9342 0.63281E-07 -7.1987 0.54390E+00 -0.2645
176 ZnF+ 0.15353E-09 -9.8138 0.86793E-10 -10.0615 0.56533E+00 -0.2477
177 ZnO,aq 0.13257E-09 -9.8776 0.13257E-09 -9.8776 0.10000E+01 0.0000
178 ZnOH+ 0.15356E-06 -6.8137 0.86813E-07 -7.0614 0.56533E+00 -0.2477
Charge balance for all species = -.1078E-03
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.9502035E-05 0.2689983E+00 0.2488112E+03 0.0000
2 H2O 0.1000000E+01 0.5523940E+02 0.9132214E+06 0.0000
3 Cl- 0.1065324E+01 0.1285270E+01 0.4181508E+05 5.0691
4 SO4-- 0.1425374E-03 0.1568864E-03 0.1382996E+02 5.5364
5 HCO3- 0.2206747E-01 0.2910262E+00 0.1629558E+05 3.3979
6 HS- 0.9369410E-06 0.9750786E-05 0.2959278E+00 -0.9853
7 H4SiO4 0.2330528E-02 0.2337537E-02 0.2061755E+03 -2.6325
8 Al+++ 0.1389260E-12 0.1693953E-06 0.4194239E-02 0.2075
9 Ca++ 0.1171179E-02 0.1750861E-02 0.6439368E+02 6.4035
10 Mg++ 0.1080086E-03 0.1428587E-03 0.3187228E+01 5.3339
11 Fe++ 0.1045364E-05 0.1333428E-05 0.6833686E-01 3.3282
12 K+ 0.3697322E-01 0.3780469E-01 0.1356533E+04 3.6247
13 Na+ 0.1048541E+01 0.1267304E+01 0.2673632E+05 5.0619
14 Mn++ 0.8465060E-05 0.2867374E-04 0.1445582E+01 4.2429
15 Zn++ 0.3387048E-07 0.5128743E-05 0.3076629E+00 1.8388
16 Cu+ 0.4487244E-11 0.1415153E-06 0.8251565E-02 -6.3071
17 Pb++ 0.5219514E-08 0.5618129E-06 0.1068184E+00 1.0734
18 Ag+ 0.1202664E-10 0.1637472E-06 0.1620915E-01 -5.8660
19 Au+ 0.2818203E-21 0.2587306E-11 0.4676565E-06 -16.4916
20 Ba++ 0.1603142E-05 0.3380258E-05 0.4260224E+00 3.5743
21 F- 0.1114230E-02 0.1354129E-02 0.2360770E+02 2.0658
22 H2AsO3- 0.6672383E-06 0.1078183E-03 0.1236131E+02 -1.0358
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234419E+00 -.6713226E-05 0.0000000E+00
2 H2O 0.6641950E+02 0.6641950E+02 0.0000000E+00 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1172428E-04 0.2306028E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810639E-02 0.1101800E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.2036799E-06 0.2203599E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.6166768E-05 0.1301408E-05 0.0000000E+00
16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00
17 Pb++ 0.1565021E-05 0.6755203E-06 0.8895004E-06 0.0000000E+00
18 Ag+ 0.4271281E-06 0.1968886E-06 0.2302395E-06 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1628196E-02 0.2203599E-05 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: 0.1271E-20 Mass of aqueous solution: 0.131027E+04 g
Temperature = 172.15 C Pressure = 500.00 bar Mixer frac. = 0.2000000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
argentite 0.1151E-06 -6.939 0.2853E-04 -4.545 4.997 0.4006E-05
topaz 0.1102E-05 -5.958 0.2028E-03 -3.693 35.52 0.5677E-04
galena 0.8895E-06 -6.051 0.2128E-03 -3.672 37.28 0.2801E-04
sphalerite 0.1301E-05 -5.886 0.1268E-03 -3.897 22.21 0.3101E-04
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
argentite 0.1000E+01 0.1000E+01 1.0000 0.000
topaz 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.2000000
Solid products produced: Mass = 0.000571 g Volume = 0.000120 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.300
AFFINITY: 0.3918E+03
GOLD Q/K: 0.0343
SILVER Q/K: 0.2428
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 172.1521 deg.C
Sat. pressure: 78.6515 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.1790E+00 0.6828 0.9615E+01 0.1408E+02
CO2,gas 0.8209E+00 0.9019 0.5824E+02 0.6457E+02
CH4,gas 0.1640E-07 1.0965 0.1414E-05 0.1290E-05
H2,gas 0.1385E-05 1.0358 0.1129E-03 0.1090E-03
H2S,gas 0.6842E-05 0.8379 0.4509E-03 0.5382E-03
S2,gas 0.5901E-16 1.0000 0.4641E-14 0.4641E-14
CO,gas 0.1941E-07 1.0000 0.1527E-05 0.1527E-05
SO3,gas 0.9091E-27 1.0000 0.7150E-25 0.7150E-25
O2,gas 0.9164E-44 1.0000 0.7208E-42 0.7208E-42
SO2,gas 0.2290E-12 1.0000 0.1801E-10 0.1801E-10
HF,gas 0.2865E-07 1.0000 0.2253E-05 0.2253E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
196 argentite -23.33 -23.33 0.00 0.000 0.72391E-11
225 topaz -19.31 -19.31 0.00 0.000 -0.14478E-10
260 galena -10.52 -10.52 0.00 0.000 -0.36196E-11
272 sphalerite -9.76 -9.76 0.00 0.000 0.00000E+00
205 bornite -75.52 -75.10 0.42 0.032 -0.86362E+03
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.70 -0.02 -1.72 -1.716 0.34966E+04 0.983
2 CO2,gas -6.26 -7.20 -0.93 -0.311 0.19027E+04 1.765
3 CH4,gas 5.41 -3.14 -8.55 -2.137 0.17418E+05 -5.849
4 H2,gas 7.65 1.00 -6.65 -3.798 0.13543E+05 -3.947
5 H2S,gas -5.55 -11.60 -6.04 -3.022 0.12317E+05 -3.346
6 S2,gas -8.17 -25.20 -17.03 -2.620 0.34706E+05 -14.333
7 CO,gas 2.34 -6.17 -8.52 -2.620 0.17351E+05 -5.816
8 SO3,gas 12.18 -15.67 -27.84 -6.961 0.56737E+05 -25.146
9 O2,gas 42.80 -2.05 -44.84 -29.894 0.91370E+05 -42.142
10 SO2,gas -1.20 -14.65 -13.44 -3.585 0.27393E+05 -10.744
11 HF,gas -0.20 -8.55 -8.35 -4.173 0.17006E+05 -5.647
12 HCl,gas 1.38 -5.54 -6.93 -3.464 0.14115E+05 -6.927
13 acmite 6.42 2.66 -3.76 -0.391 0.76713E+04
17 albite-high -0.94 -2.55 -1.61 -0.124 0.32879E+04
18 albite -1.70 -2.55 -0.85 -0.065 0.17347E+04
22 analcite 1.47 0.02 -1.44 -0.160 0.29392E+04
23 andalusite 0.25 -2.24 -2.48 -0.248 0.50587E+04
26 anhydrite -6.29 -9.28 -2.99 -1.496 0.60975E+04
27 ankerite -3.49 -4.70 -1.21 -0.201 0.24604E+04
31 anorthite 6.44 1.55 -4.88 -0.376 0.99528E+04
34 aragonite 0.19 -0.81 -1.00 -0.332 0.20302E+04
35 brucite 10.23 5.30 -4.93 -0.986 0.10042E+05
36 calcite 0.05 -0.81 -0.86 -0.286 0.17469E+04
37 carnegieite-low 6.14 2.64 -3.50 -0.501 0.71416E+04
38 carnegieite-high 6.91 2.64 -4.27 -0.610 0.87045E+04
39 carpholite-Mg 3.41 0.45 -2.96 -0.198 0.60405E+04
40 carpholite-Fe 1.81 -1.56 -3.37 -0.225 0.68660E+04
41 celadonite 3.19 -1.29 -4.48 -0.263 0.91235E+04
49 chloritoid-Mg 6.89 3.06 -3.83 -0.255 0.78048E+04
50 chloritoid-Fe 3.57 1.06 -2.52 -0.168 0.51306E+04
51 chloritoid-Mn 5.77 1.97 -3.80 -0.253 0.77364E+04
53 coesite -1.94 -2.60 -0.65 -0.217 0.13261E+04
58 corundum 3.02 0.36 -2.66 -0.242 0.54234E+04
60 cristobalite -2.13 -2.60 -0.47 -0.155 0.94751E+03
63 cymrite-K 0.26 -4.01 -4.27 -0.356 0.87005E+04
65 diaspore 0.66 0.17 -0.49 -0.082 0.99988E+03
66 diamond -2.34 -5.15 -2.82 -0.804 0.57369E+04
69 dolomite,ordered -1.20 -2.69 -1.49 -0.249 0.30431E+04
83 gibbsite 1.89 0.15 -1.74 -0.248 0.35378E+04
86 goethite 4.89 2.79 -2.10 -0.454 0.42826E+04
87 graphite -2.73 -5.15 -2.42 -0.691 0.49301E+04
90 halite 1.46 -0.48 -1.94 -0.968 0.39466E+04
91 hematite 9.23 5.60 -3.63 -0.441 0.74061E+04
92 heulandite -8.13 -11.54 -3.41 -0.155 0.69411E+04
96 jadeite 2.28 0.04 -2.24 -0.224 0.45694E+04
98 kalsilite 5.03 1.20 -3.83 -0.547 0.78091E+04
99 kaolinite -4.26 -4.87 -0.61 -0.056 0.12468E+04
100 kyanite 0.18 -2.24 -2.42 -0.242 0.49254E+04
102 laumontite -0.68 -3.71 -3.03 -0.202 0.61701E+04
103 lawsonite 4.79 1.52 -3.27 -0.218 0.66645E+04
104 leucite 2.03 -1.40 -3.43 -0.343 0.69899E+04
107 magnesite -0.46 -1.88 -1.42 -0.474 0.28989E+04
114 margarite 6.80 1.89 -4.90 -0.196 0.99907E+04
117 microcline -3.26 -3.99 -0.73 -0.056 0.14904E+04
120 mullite-Si 2.06 -2.24 -4.30 -0.430 0.87518E+04
121 muscovite -2.64 -3.65 -1.01 -0.060 0.20666E+04
122 paragonite -1.38 -2.21 -0.83 -0.049 0.16895E+04
123 nepheline 5.54 2.64 -2.90 -0.414 0.59064E+04
143 pyrite -19.52 -20.87 -1.35 -0.318 0.27499E+04
144 pyrrhotite -4.74 -8.27 -3.53 -1.175 0.71848E+04
145 pyrrhotiteFe0.875 -6.16 -8.81 -2.65 -0.974 0.53949E+04
146 pyroxmangite 5.89 1.63 -4.26 -0.852 0.86835E+04
147 pyrophyllite -8.55 -10.04 -1.49 -0.093 0.30328E+04
148 quartz -2.46 -2.60 -0.13 -0.045 0.27333E+03
153 rhodochrosite -1.56 -2.97 -1.41 -0.469 0.28699E+04
154 rhodonite 5.92 1.63 -4.29 -0.858 0.87457E+04
155 sanidine -2.24 -3.99 -1.75 -0.134 0.35592E+04
157 siderite -3.23 -3.89 -0.66 -0.219 0.13371E+04
158 sillimanite 0.43 -2.24 -2.67 -0.267 0.54377E+04
165 stilbite -8.31 -11.55 -3.25 -0.155 0.66171E+04
171 sulfur -8.55 -12.60 -4.05 -1.246 0.82544E+04
172 sylvite 1.44 -1.92 -3.36 -1.679 0.68408E+04
180 topaz-H 0.45 -2.25 -2.71 -0.246 0.55151E+04
181 tridymite -2.17 -2.60 -0.43 -0.143 0.87681E+03
184 troilite-low -4.82 -8.27 -3.45 -1.149 0.70231E+04
190 wairakite -0.27 -3.67 -3.41 -0.201 0.69457E+04
192 wollastonite 8.67 3.79 -4.88 -0.976 0.99391E+04
197 arsenic -5.84 -10.09 -4.25 -1.096 0.86558E+04
199 arsenopyrite -13.65 -18.36 -4.70 -0.836 0.95812E+04
200 beidellite-Ca -5.49 -8.07 -2.59 -0.160 0.52681E+04
201 beidellite-H -5.99 -9.13 -3.14 -0.200 0.63993E+04
202 beidellite-K -5.10 -7.93 -2.83 -0.173 0.57642E+04
203 beidellite-Mg -5.72 -8.25 -2.53 -0.157 0.51603E+04
204 beidellite-Na -5.01 -7.46 -2.45 -0.150 0.49977E+04
207 chalcedony -2.30 -2.60 -0.29 -0.097 0.59319E+03
208 chalcocite -23.21 -24.21 -1.00 -0.250 0.20403E+04
210 covellite -16.95 -18.41 -1.46 -0.555 0.29706E+04
211 dawsonite 0.28 -1.98 -2.26 -0.283 0.46128E+04
213 montmorillonite-Ca -4.91 -7.29 -2.39 -0.148 0.48658E+04
214 montmorillonite-K -4.62 -7.15 -2.54 -0.155 0.51701E+04
215 montmorillonite-Mg -5.13 -7.47 -2.34 -0.145 0.47612E+04
216 montmorillonite-Na -4.45 -6.68 -2.23 -0.136 0.45419E+04
217 nontronite-Ca 1.29 -2.83 -4.12 -0.268 0.84044E+04
218 nontronite-H 0.78 -3.89 -4.68 -0.313 0.95278E+04
219 nontronite-K 1.67 -2.70 -4.37 -0.280 0.89002E+04
220 nontronite-Mg 1.09 -3.01 -4.10 -0.266 0.83579E+04
221 nontronite-Na 1.77 -2.22 -3.99 -0.256 0.81361E+04
229 gypsum -5.45 -9.32 -3.87 -0.967 0.78793E+04
245 acanthite -23.16 -23.33 -0.17 -0.042 0.34294E+03
251 barite -9.50 -12.11 -2.62 -1.308 0.53315E+04
252 boehmite 1.82 0.17 -1.65 -0.275 0.33569E+04
253 cerussite -2.77 -6.14 -3.38 -1.125 0.68771E+04
254 chalcopyrite -25.37 -26.68 -1.30 -0.242 0.26531E+04
256 copper,native -1.88 -5.81 -3.93 -1.366 0.80007E+04
257 dolomite,disordered -0.71 -2.69 -1.98 -0.331 0.40438E+04
258 ferrous-oxide 7.50 3.31 -4.19 -1.049 0.85468E+04
259 fluorite -10.07 -10.69 -0.62 -0.208 0.12720E+04
261 gold,native -14.53 -15.99 -1.46 -0.509 0.29839E+04
262 silver,native -4.75 -5.36 -0.61 -0.214 0.12526E+04
269 silica-amorphous -1.74 -2.60 -0.85 -0.284 0.17344E+04
270 smithsonite -1.57 -5.38 -3.81 -1.270 0.77634E+04
273 wurtzite -8.22 -9.76 -1.53 -0.511 0.31257E+04
274 zincite 6.28 1.82 -4.45 -1.114 0.90776E+04
275 an20ab80 -0.29 -1.73 -1.44 -0.111 0.29362E+04
276 an25ab75 0.09 -1.53 -1.62 -0.124 0.32915E+04
277 an30ab70 0.47 -1.32 -1.80 -0.138 0.36591E+04
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 70
Temperature = 172.15 C Pressure = 500.00 bar Mixer fraction = 0.2000000
Water: Moles liquid = 0.6674E+02 kg liquid = 0.1202E+01
Moles total = 0.6642E+02 kg total = 0.1197E+01 Activity = 0.9584
Stoichiometric ionic strength = .1452654E+01 Osmotic coef. = 0.9174
True ionic strength = .1090202E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.95020E-05 -5.0222 0.49419E-05 -5.3061 0.52009E+00 -0.2839
2 H2O 0.95840E+00 -0.0185 0.95840E+00 -0.0185
3 Cl- 0.10653E+01 0.0275 0.57943E+00 -0.2370 0.54390E+00 -0.2645
4 SO4-- 0.14254E-03 -3.8461 0.83979E-05 -5.0758 0.58918E-01 -1.2298
5 HCO3- 0.22067E-01 -1.6562 0.12353E-01 -1.9082 0.55977E+00 -0.2520
6 HS- 0.93577E-06 -6.0288 0.51053E-06 -6.2920 0.54558E+00 -0.2631
7 H4SiO4 0.23305E-02 -2.6325 0.23305E-02 -2.6325 0.10000E+01 0.0000
8 Al+++ 0.13893E-12 -12.8572 0.19463E-15 -15.7108 0.14009E-02 -2.8536
9 Ca++ 0.11712E-02 -2.9314 0.61837E-04 -4.2087 0.52799E-01 -1.2774
10 Mg++ 0.10801E-03 -3.9665 0.52684E-05 -5.2783 0.48777E-01 -1.3118
11 Fe++ 0.10415E-05 -5.9824 0.51805E-07 -7.2856 0.49743E-01 -1.3033
12 K+ 0.36973E-01 -1.4321 0.20824E-01 -1.6814 0.56321E+00 -0.2493
13 Na+ 0.10485E+01 0.0206 0.56991E+00 -0.2442 0.54352E+00 -0.2648
14 Mn++ 0.84651E-05 -5.0724 0.42724E-06 -6.3693 0.50471E-01 -1.2970
15 Zn++ 0.33913E-07 -7.4696 0.16869E-08 -8.7729 0.49743E-01 -1.3033
16 Cu+ 0.36979E-11 -11.4320 0.20078E-11 -11.6973 0.54296E+00 -0.2652
17 Pb++ 0.52260E-08 -8.2818 0.28957E-09 -9.5383 0.55408E-01 -1.2564
18 Ag+ 0.12034E-10 -10.9196 0.67328E-11 -11.1718 0.55948E+00 -0.2522
19 Au+ 0.28217E-21 -21.5495 0.15952E-21 -21.7972 0.56533E+00 -0.2477
20 Ba++ 0.16031E-05 -5.7950 0.91646E-07 -7.0379 0.57166E-01 -1.2429
21 F- 0.11142E-02 -2.9530 0.57508E-03 -3.2403 0.51612E+00 -0.2872
22 H2AsO3- 0.66724E-06 -6.1757 0.45509E-06 -6.3419 0.68205E+00 -0.1662
24 HSiO3- 0.19626E-05 -5.7072 0.10675E-05 -5.9716 0.54390E+00 -0.2645
25 Ca(HSiO3)+ 0.85599E-08 -8.0675 0.48391E-08 -8.3152 0.56533E+00 -0.2477
26 Mg(HSiO3)+ 0.67542E-09 -9.1704 0.38183E-09 -9.4181 0.56533E+00 -0.2477
27 NaHSiO3,aq 0.50369E-05 -5.2978 0.50369E-05 -5.2978 0.10000E+01 0.0000
31 AgCl,aq 0.21339E-08 -8.6708 0.21339E-08 -8.6708 0.10000E+01 0.0000
32 AgCl2- 0.91642E-07 -7.0379 0.49844E-07 -7.3024 0.54390E+00 -0.2645
33 AgCl3-2 0.55151E-07 -7.2584 0.31452E-08 -8.5024 0.57028E-01 -1.2439
34 AgCl4-3 0.75669E-08 -8.1211 0.10546E-10 -10.9769 0.13937E-02 -2.8558
38 Ag(HS),aq 0.73311E-08 -8.1348 0.73311E-08 -8.1348 0.10000E+01 0.0000
40 AlO+ 0.18629E-09 -9.7298 0.10532E-09 -9.9775 0.56533E+00 -0.2477
42 HAlO2,aq 0.26395E-07 -7.5785 0.26395E-07 -7.5785 0.10000E+01 0.0000
43 AlO2- 0.14281E-06 -6.8453 0.74299E-07 -7.1290 0.52028E+00 -0.2838
44 AsO2- 0.14184E-06 -6.8482 0.77145E-07 -7.1127 0.54390E+00 -0.2645
45 HAsO2,aq 0.30768E-04 -4.5119 0.30768E-04 -4.5119 0.10000E+01 0.0000
46 H3AsO3,aq 0.76241E-04 -4.1178 0.76241E-04 -4.1178 0.10000E+01 0.0000
48 H2AsO4- 0.67299E-10 -10.1720 0.36604E-10 -10.4365 0.54390E+00 -0.2645
49 HAsO4-2 0.12342E-10 -10.9086 0.70386E-12 -12.1525 0.57028E-01 -1.2439
62 BaCO3,aq 0.33691E-09 -9.4725 0.33691E-09 -9.4725 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.10614E-05 -5.9741 0.61046E-06 -6.2143 0.57517E+00 -0.2402
64 BaCl+ 0.71459E-06 -6.1459 0.40398E-06 -6.3936 0.56533E+00 -0.2477
65 BaF+ 0.82529E-09 -9.0834 0.46656E-09 -9.3311 0.56533E+00 -0.2477
66 CH4,aq 0.81675E-09 -9.0879 0.74115E-09 -9.1301 0.90745E+00 -0.0422
71 CO,aq 0.10767E-08 -8.9679 0.10767E-08 -8.9679 0.10000E+01 0.0000
72 CO2,aq 0.26881E+00 -0.5705 0.24393E+00 -0.6127 0.90745E+00 -0.0422
73 CO3-2 0.39655E-05 -5.4017 0.22615E-06 -6.6456 0.57028E-01 -1.2439
74 CaCO3,aq 0.90784E-06 -6.0420 0.90784E-06 -6.0420 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.12912E-03 -3.8890 0.72993E-04 -4.1367 0.56533E+00 -0.2477
76 CaCl+ 0.41274E-03 -3.3843 0.23333E-03 -3.6320 0.56533E+00 -0.2477
77 CaCl2,aq 0.32506E-04 -4.4880 0.32506E-04 -4.4880 0.10000E+01 0.0000
78 CaF+ 0.38573E-05 -5.4137 0.21806E-05 -5.6614 0.56533E+00 -0.2477
79 CaOH+ 0.68347E-07 -7.1653 0.38639E-07 -7.4130 0.56533E+00 -0.2477
80 CaSO4,aq 0.47463E-06 -6.3236 0.47463E-06 -6.3236 0.10000E+01 0.0000
81 HCl,aq 0.13255E-05 -5.8776 0.13255E-05 -5.8776 0.10000E+01 0.0000
90 CuCl,aq 0.53871E-08 -8.2686 0.53871E-08 -8.2686 0.10000E+01 0.0000
91 CuCl2- 0.92769E-07 -7.0326 0.50457E-07 -7.2971 0.54390E+00 -0.2645
92 CuCl3-2 0.18463E-07 -7.7337 0.10529E-08 -8.9776 0.57028E-01 -1.2439
98 HF,aq 0.73747E-04 -4.1323 0.73747E-04 -4.1323 0.10000E+01 0.0000
99 HF2- 0.22376E-07 -7.6502 0.12170E-07 -7.9147 0.54390E+00 -0.2645
101 FeCl+ 0.26919E-06 -6.5699 0.15218E-06 -6.8176 0.56533E+00 -0.2477
102 FeCl2,aq 0.73732E-09 -9.1323 0.73732E-09 -9.1323 0.10000E+01 0.0000
104 FeF+ 0.71447E-08 -8.1460 0.40391E-08 -8.3937 0.56533E+00 -0.2477
106 FeO,aq 0.28381E-10 -10.5470 0.28381E-10 -10.5470 0.10000E+01 0.0000
107 FeOH+ 0.98555E-08 -8.0063 0.55716E-08 -8.2540 0.56533E+00 -0.2477
112 HFeO2,aq 0.25805E-10 -10.5883 0.25805E-10 -10.5883 0.10000E+01 0.0000
113 H2,aq 0.10426E-06 -6.9819 0.94608E-07 -7.0241 0.90745E+00 -0.0422
114 KCl,aq 0.81809E-03 -3.0872 0.81809E-03 -3.0872 0.10000E+01 0.0000
115 KHSO4,aq 0.12187E-09 -9.9141 0.12187E-09 -9.9141 0.10000E+01 0.0000
116 KOH,aq 0.25551E-07 -7.5926 0.25551E-07 -7.5926 0.10000E+01 0.0000
117 KSO4- 0.13350E-04 -4.8745 0.72609E-05 -5.1390 0.54390E+00 -0.2645
118 MgCO3,aq 0.11895E-07 -7.9246 0.11895E-07 -7.9246 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.10821E-04 -4.9657 0.61172E-05 -5.2134 0.56533E+00 -0.2477
120 MgCl+ 0.22969E-04 -4.6389 0.12985E-04 -4.8866 0.56533E+00 -0.2477
121 MgF+ 0.10262E-05 -5.9888 0.58013E-06 -6.2365 0.56533E+00 -0.2477
122 MgOH+ 0.21796E-07 -7.6616 0.12322E-07 -7.9093 0.56533E+00 -0.2477
124 MnF+ 0.22465E-07 -7.6485 0.12700E-07 -7.8962 0.56533E+00 -0.2477
126 MnOH+ 0.10151E-07 -7.9935 0.57386E-08 -8.2412 0.56533E+00 -0.2477
131 MnCl+ 0.20172E-04 -4.6952 0.11404E-04 -4.9429 0.56533E+00 -0.2477
132 MnSO4,aq 0.36838E-08 -8.4337 0.36838E-08 -8.4337 0.10000E+01 0.0000
133 NaCl,aq 0.21860E+00 -0.6604 0.21860E+00 -0.6604 0.10000E+01 0.0000
134 NaF,aq 0.16119E-03 -3.7927 0.16119E-03 -3.7927 0.10000E+01 0.0000
135 NaOH,aq 0.54126E-06 -6.2666 0.54126E-06 -6.2666 0.10000E+01 0.0000
137 OH- 0.20137E-05 -5.6960 0.10477E-05 -5.9798 0.52028E+00 -0.2838
140 PbCl+ 0.53776E-07 -7.2694 0.30401E-07 -7.5171 0.56533E+00 -0.2477
141 PbCl2,aq 0.20114E-06 -6.6965 0.20114E-06 -6.6965 0.10000E+01 0.0000
142 PbCl3- 0.13655E-06 -6.8647 0.74269E-07 -7.1292 0.54390E+00 -0.2645
143 PbCl4-2 0.16561E-06 -6.7809 0.94445E-08 -8.0248 0.57028E-01 -1.2439
144 PbF+ 0.84150E-10 -10.0749 0.47572E-10 -10.3226 0.56533E+00 -0.2477
146 PbO,aq 0.14874E-10 -10.8276 0.14874E-10 -10.8276 0.10000E+01 0.0000
148 Pb(HS)2,aq 0.11524E-09 -9.9384 0.11524E-09 -9.9384 0.10000E+01 0.0000
150 H2S,aq 0.87681E-05 -5.0571 0.79566E-05 -5.0993 0.90745E+00 -0.0422
158 HSO3- 0.12309E-09 -9.9098 0.66948E-10 -10.1743 0.54390E+00 -0.2645
159 HSO4- 0.54796E-06 -6.2612 0.31446E-06 -6.5024 0.57387E+00 -0.2412
161 S2O3-2 0.17165E-10 -10.7654 0.97886E-12 -12.0093 0.57028E-01 -1.2439
173 ZnCl+ 0.39172E-05 -5.4070 0.22145E-05 -5.6547 0.56533E+00 -0.2477
174 ZnCl2,aq 0.91353E-06 -6.0393 0.91353E-06 -6.0393 0.10000E+01 0.0000
175 ZnCl3- 0.11649E-06 -6.9337 0.63360E-07 -7.1982 0.54390E+00 -0.2645
176 ZnF+ 0.15372E-09 -9.8133 0.86902E-10 -10.0610 0.56533E+00 -0.2477
177 ZnO,aq 0.13273E-09 -9.8770 0.13273E-09 -9.8770 0.10000E+01 0.0000
178 ZnOH+ 0.15375E-06 -6.8132 0.86922E-07 -7.0609 0.56533E+00 -0.2477
Charge balance for all species = -.1078E-03
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.9502044E-05 0.2689983E+00 0.2488112E+03 0.0000
2 H2O 0.1000000E+01 0.5523940E+02 0.9132214E+06 0.0000
3 Cl- 0.1065324E+01 0.1285270E+01 0.4181508E+05 5.0691
4 SO4-- 0.1425368E-03 0.1568858E-03 0.1382990E+02 5.5364
5 HCO3- 0.2206745E-01 0.2910262E+00 0.1629558E+05 3.3979
6 HS- 0.9357718E-06 0.9738655E-05 0.2955596E+00 -0.9859
7 H4SiO4 0.2330528E-02 0.2337537E-02 0.2061755E+03 -2.6325
8 Al+++ 0.1389262E-12 0.1693951E-06 0.4194232E-02 0.2075
9 Ca++ 0.1171179E-02 0.1750861E-02 0.6439368E+02 6.4035
10 Mg++ 0.1080086E-03 0.1428587E-03 0.3187228E+01 5.3339
11 Fe++ 0.1041460E-05 0.1328449E-05 0.6808171E-01 3.3266
12 K+ 0.3697322E-01 0.3780469E-01 0.1356533E+04 3.6247
13 Na+ 0.1048541E+01 0.1267304E+01 0.2673632E+05 5.0619
14 Mn++ 0.8465060E-05 0.2867374E-04 0.1445582E+01 4.2429
15 Zn++ 0.3391283E-07 0.5135156E-05 0.3080475E+00 1.8393
16 Cu+ 0.3697927E-11 0.1166224E-06 0.6800094E-02 -6.3912
17 Pb++ 0.5226040E-08 0.5625152E-06 0.1069519E+00 1.0740
18 Ag+ 0.1203415E-10 0.1638404E-06 0.1621837E-01 -5.8657
19 Au+ 0.2821669E-21 0.2587306E-11 0.4676565E-06 -16.4911
20 Ba++ 0.1603143E-05 0.3380258E-05 0.4260224E+00 3.5743
21 F- 0.1114230E-02 0.1354129E-02 0.2360770E+02 2.0658
22 H2AsO3- 0.6672377E-06 0.1078183E-03 0.1236131E+02 -1.0358
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234419E+00 -.6721827E-05 0.0000000E+00
2 H2O 0.6641950E+02 0.6641950E+02 -.2993107E-08 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886385E-03 0.7482766E-09 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1170970E-04 0.2320614E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810639E-02 0.1101800E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.2036795E-06 0.2203599E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1597319E-05 0.5986213E-08 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.6174479E-05 0.1293698E-05 0.0000000E+00
16 Cu+ 0.1701571E-06 0.1402261E-06 0.2993107E-07 0.0000000E+00
17 Pb++ 0.1565021E-05 0.6763646E-06 0.8886560E-06 0.0000000E+00
18 Ag+ 0.4271281E-06 0.1970006E-06 0.2301275E-06 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1628196E-02 0.2203599E-05 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: 0.8470E-21 Mass of aqueous solution: 0.131027E+04 g
Temperature = 172.15 C Pressure = 500.00 bar Mixer frac. = 0.2000000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
argentite 0.1151E-06 -6.939 0.2851E-04 -4.545 4.976 0.4004E-05
topaz 0.1102E-05 -5.958 0.2028E-03 -3.693 35.39 0.5677E-04
galena 0.8887E-06 -6.051 0.2126E-03 -3.672 37.11 0.2798E-04
sphalerite 0.1294E-05 -5.888 0.1260E-03 -3.899 22.00 0.3083E-04
bornite 0.5986E-08 -8.223 0.3004E-05 -5.522 0.5243 0.5910E-06
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
argentite 0.1000E+01 0.1000E+01 1.0000 0.000
topaz 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
bornite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.2000000
Solid products produced: Mass = 0.000573 g Volume = 0.000120 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.300
AFFINITY: 0.3912E+03
GOLD Q/K: 0.0344
SILVER Q/K: 0.2429
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 172.1521 deg.C
Sat. pressure: 78.6515 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.1790E+00 0.6828 0.9615E+01 0.1408E+02
CO2,gas 0.8209E+00 0.9019 0.5824E+02 0.6457E+02
CH4,gas 0.1638E-07 1.0965 0.1413E-05 0.1288E-05
H2,gas 0.1385E-05 1.0358 0.1128E-03 0.1089E-03
H2S,gas 0.6834E-05 0.8379 0.4503E-03 0.5375E-03
S2,gas 0.5890E-16 1.0000 0.4632E-14 0.4632E-14
CO,gas 0.1940E-07 1.0000 0.1526E-05 0.1526E-05
SO3,gas 0.9091E-27 1.0000 0.7150E-25 0.7150E-25
O2,gas 0.9170E-44 1.0000 0.7212E-42 0.7212E-42
SO2,gas 0.2289E-12 1.0000 0.1800E-10 0.1800E-10
HF,gas 0.2865E-07 1.0000 0.2253E-05 0.2253E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
196 argentite -23.33 -23.33 0.00 0.000 0.72391E-11
205 bornite -75.52 -75.52 0.00 0.000 0.00000E+00
225 topaz -19.31 -19.31 0.00 0.000 0.00000E+00
260 galena -10.52 -10.52 0.00 0.000 0.10859E-10
272 sphalerite -9.76 -9.76 0.00 0.000 0.72391E-11
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.70 -0.02 -1.72 -1.716 0.34966E+04 0.983
2 CO2,gas -6.26 -7.20 -0.93 -0.311 0.19027E+04 1.765
3 CH4,gas 5.41 -3.14 -8.55 -2.137 0.17420E+05 -5.850
4 H2,gas 7.65 1.00 -6.65 -3.798 0.13543E+05 -3.948
5 H2S,gas -5.55 -11.60 -6.05 -3.023 0.12318E+05 -3.346
6 S2,gas -8.17 -25.20 -17.03 -2.620 0.34707E+05 -14.334
7 CO,gas 2.34 -6.17 -8.52 -2.620 0.17351E+05 -5.816
8 SO3,gas 12.18 -15.67 -27.84 -6.961 0.56737E+05 -25.146
9 O2,gas 42.80 -2.04 -44.84 -29.894 0.91369E+05 -42.142
10 SO2,gas -1.20 -14.65 -13.44 -3.585 0.27393E+05 -10.745
11 HF,gas -0.20 -8.55 -8.35 -4.173 0.17006E+05 -5.647
12 HCl,gas 1.38 -5.54 -6.93 -3.464 0.14115E+05 -6.927
13 acmite 6.42 2.66 -3.77 -0.391 0.76745E+04
17 albite-high -0.94 -2.55 -1.61 -0.124 0.32879E+04
18 albite -1.70 -2.55 -0.85 -0.065 0.17347E+04
22 analcite 1.47 0.02 -1.44 -0.160 0.29392E+04
23 andalusite 0.25 -2.24 -2.48 -0.248 0.50587E+04
26 anhydrite -6.29 -9.28 -2.99 -1.496 0.60975E+04
27 ankerite -3.49 -4.70 -1.21 -0.202 0.24637E+04
31 anorthite 6.44 1.55 -4.88 -0.376 0.99528E+04
34 aragonite 0.19 -0.81 -1.00 -0.332 0.20302E+04
35 brucite 10.23 5.30 -4.93 -0.986 0.10042E+05
36 calcite 0.05 -0.81 -0.86 -0.286 0.17469E+04
37 carnegieite-low 6.14 2.64 -3.50 -0.501 0.71416E+04
38 carnegieite-high 6.91 2.64 -4.27 -0.610 0.87045E+04
39 carpholite-Mg 3.41 0.45 -2.96 -0.198 0.60405E+04
40 carpholite-Fe 1.81 -1.56 -3.37 -0.225 0.68693E+04
41 celadonite 3.19 -1.29 -4.48 -0.263 0.91235E+04
49 chloritoid-Mg 6.89 3.06 -3.83 -0.255 0.78048E+04
50 chloritoid-Fe 3.57 1.05 -2.52 -0.168 0.51339E+04
51 chloritoid-Mn 5.77 1.97 -3.80 -0.253 0.77364E+04
53 coesite -1.94 -2.60 -0.65 -0.217 0.13261E+04
58 corundum 3.02 0.36 -2.66 -0.242 0.54234E+04
60 cristobalite -2.13 -2.60 -0.47 -0.155 0.94751E+03
63 cymrite-K 0.26 -4.01 -4.27 -0.356 0.87005E+04
65 diaspore 0.66 0.17 -0.49 -0.082 0.99988E+03
66 diamond -2.34 -5.15 -2.82 -0.805 0.57375E+04
69 dolomite,ordered -1.20 -2.69 -1.49 -0.249 0.30431E+04
83 gibbsite 1.89 0.15 -1.74 -0.248 0.35378E+04
86 goethite 4.89 2.79 -2.10 -0.455 0.42858E+04
87 graphite -2.73 -5.15 -2.42 -0.691 0.49306E+04
90 halite 1.46 -0.48 -1.94 -0.968 0.39466E+04
91 hematite 9.23 5.59 -3.64 -0.441 0.74125E+04
92 heulandite -8.13 -11.54 -3.41 -0.155 0.69411E+04
96 jadeite 2.28 0.04 -2.24 -0.224 0.45694E+04
98 kalsilite 5.03 1.20 -3.83 -0.547 0.78091E+04
99 kaolinite -4.26 -4.87 -0.61 -0.056 0.12468E+04
100 kyanite 0.18 -2.24 -2.42 -0.242 0.49254E+04
102 laumontite -0.68 -3.71 -3.03 -0.202 0.61701E+04
103 lawsonite 4.79 1.52 -3.27 -0.218 0.66646E+04
104 leucite 2.03 -1.40 -3.43 -0.343 0.69899E+04
107 magnesite -0.46 -1.88 -1.42 -0.474 0.28989E+04
114 margarite 6.80 1.89 -4.90 -0.196 0.99907E+04
117 microcline -3.26 -3.99 -0.73 -0.056 0.14904E+04
120 mullite-Si 2.06 -2.24 -4.30 -0.430 0.87518E+04
121 muscovite -2.64 -3.65 -1.01 -0.060 0.20666E+04
122 paragonite -1.38 -2.21 -0.83 -0.049 0.16895E+04
123 nepheline 5.54 2.64 -2.90 -0.414 0.59064E+04
143 pyrite -19.52 -20.87 -1.35 -0.318 0.27551E+04
144 pyrrhotite -4.74 -8.27 -3.53 -1.176 0.71893E+04
145 pyrrhotiteFe0.875 -6.16 -8.81 -2.65 -0.974 0.53988E+04
146 pyroxmangite 5.89 1.63 -4.26 -0.852 0.86835E+04
147 pyrophyllite -8.55 -10.04 -1.49 -0.093 0.30328E+04
148 quartz -2.46 -2.60 -0.13 -0.045 0.27333E+03
153 rhodochrosite -1.56 -2.97 -1.41 -0.469 0.28699E+04
154 rhodonite 5.92 1.63 -4.29 -0.858 0.87457E+04
155 sanidine -2.24 -3.99 -1.75 -0.134 0.35592E+04
157 siderite -3.23 -3.89 -0.66 -0.219 0.13404E+04
158 sillimanite 0.43 -2.24 -2.67 -0.267 0.54377E+04
165 stilbite -8.31 -11.55 -3.25 -0.155 0.66171E+04
171 sulfur -8.55 -12.60 -4.05 -1.247 0.82552E+04
172 sylvite 1.44 -1.92 -3.36 -1.679 0.68408E+04
180 topaz-H 0.45 -2.25 -2.71 -0.246 0.55151E+04
181 tridymite -2.17 -2.60 -0.43 -0.143 0.87681E+03
184 troilite-low -4.82 -8.27 -3.45 -1.150 0.70276E+04
190 wairakite -0.27 -3.67 -3.41 -0.201 0.69457E+04
192 wollastonite 8.67 3.79 -4.88 -0.976 0.99391E+04
197 arsenic -5.84 -10.09 -4.25 -1.096 0.86562E+04
199 arsenopyrite -13.65 -18.36 -4.70 -0.836 0.95861E+04
200 beidellite-Ca -5.49 -8.07 -2.59 -0.160 0.52681E+04
201 beidellite-H -5.99 -9.13 -3.14 -0.200 0.63993E+04
202 beidellite-K -5.10 -7.93 -2.83 -0.173 0.57642E+04
203 beidellite-Mg -5.72 -8.25 -2.53 -0.157 0.51603E+04
204 beidellite-Na -5.01 -7.46 -2.45 -0.150 0.49977E+04
207 chalcedony -2.30 -2.60 -0.29 -0.097 0.59319E+03
208 chalcocite -23.21 -24.38 -1.17 -0.292 0.23838E+04
210 covellite -16.95 -18.49 -1.54 -0.588 0.31428E+04
211 dawsonite 0.28 -1.98 -2.26 -0.283 0.46128E+04
213 montmorillonite-Ca -4.91 -7.29 -2.39 -0.148 0.48658E+04
214 montmorillonite-K -4.62 -7.15 -2.54 -0.155 0.51701E+04
215 montmorillonite-Mg -5.13 -7.47 -2.34 -0.145 0.47612E+04
216 montmorillonite-Na -4.45 -6.68 -2.23 -0.136 0.45419E+04
217 nontronite-Ca 1.29 -2.84 -4.13 -0.268 0.84107E+04
218 nontronite-H 0.78 -3.89 -4.68 -0.314 0.95341E+04
219 nontronite-K 1.67 -2.70 -4.37 -0.281 0.89065E+04
220 nontronite-Mg 1.09 -3.01 -4.10 -0.266 0.83643E+04
221 nontronite-Na 1.77 -2.22 -4.00 -0.256 0.81425E+04
229 gypsum -5.45 -9.32 -3.87 -0.967 0.78793E+04
245 acanthite -23.16 -23.33 -0.17 -0.042 0.34294E+03
251 barite -9.50 -12.11 -2.62 -1.308 0.53315E+04
252 boehmite 1.82 0.17 -1.65 -0.275 0.33569E+04
253 cerussite -2.77 -6.14 -3.37 -1.125 0.68760E+04
254 chalcopyrite -25.37 -26.76 -1.39 -0.258 0.28297E+04
256 copper,native -1.88 -5.89 -4.01 -1.395 0.81721E+04
257 dolomite,disordered -0.71 -2.69 -1.98 -0.331 0.40438E+04
258 ferrous-oxide 7.50 3.31 -4.20 -1.049 0.85501E+04
259 fluorite -10.07 -10.69 -0.62 -0.208 0.12720E+04
261 gold,native -14.53 -15.99 -1.46 -0.509 0.29829E+04
262 silver,native -4.75 -5.36 -0.61 -0.214 0.12522E+04
269 silica-amorphous -1.74 -2.60 -0.85 -0.284 0.17344E+04
270 smithsonite -1.57 -5.38 -3.81 -1.270 0.77623E+04
273 wurtzite -8.22 -9.76 -1.53 -0.511 0.31257E+04
274 zincite 6.28 1.82 -4.45 -1.114 0.90765E+04
275 an20ab80 -0.29 -1.73 -1.44 -0.111 0.29362E+04
276 an25ab75 0.09 -1.53 -1.62 -0.124 0.32915E+04
277 an30ab70 0.47 -1.32 -1.80 -0.138 0.36591E+04
Calculations done for 172.1521 Deg. C; 500.0000 bar
Mixer fraction: 0.2000000
Temperature Stoc.ionic strength Heat per mole
Actual solution: 172.152 .14527E+01 3.260
Mixing solution: 25.000 .50000E-10 0.646
Fract. of mixing solution added: 0.050000
BITMOL = 0.2775E+01 OLDMOL = 0.6816E+02
New heat: 3.157 New temperature: 166.510
New mixer fraction: 0.2500000
Resulting temperature: 166.510Deg. C
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1296E-03
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 7 Loop limit = 70
Temperature = 166.51 C Pressure = 500.00 bar Mixer fraction = 0.2500000
Water: Moles liquid = 0.6952E+02 kg liquid = 0.1252E+01
Moles total = 0.6919E+02 kg total = 0.1247E+01 Activity = 0.9599
Stoichiometric ionic strength = .1394387E+01 Osmotic coef. = 0.9202
True ionic strength = .1058416E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.10256E-04 -4.9890 0.54445E-05 -5.2640 0.53084E+00 -0.2750
2 H2O 0.95991E+00 -0.0178 0.95991E+00 -0.0178
3 Cl- 0.10345E+01 0.0147 0.57128E+00 -0.2432 0.55223E+00 -0.2579
4 SO4-- 0.13743E-03 -3.8619 0.87597E-05 -5.0575 0.63739E-01 -1.1956
5 HCO3- 0.21197E-01 -1.6737 0.12015E-01 -1.9203 0.56683E+00 -0.2465
6 HS- 0.81327E-06 -6.0898 0.45036E-06 -6.3464 0.55376E+00 -0.2567
7 H4SiO4 0.22381E-02 -2.6501 0.22381E-02 -2.6501 0.10000E+01 0.0000
8 Al+++ 0.19241E-12 -12.7158 0.32600E-15 -15.4868 0.16942E-02 -2.7710
9 Ca++ 0.11513E-02 -2.9388 0.66148E-04 -4.1795 0.57456E-01 -1.2407
10 Mg++ 0.10491E-03 -3.9792 0.56050E-05 -5.2514 0.53427E-01 -1.2722
11 Fe++ 0.10076E-05 -5.9967 0.54803E-07 -7.2612 0.54392E-01 -1.2645
12 K+ 0.35582E-01 -1.4488 0.20272E-01 -1.6931 0.56973E+00 -0.2443
13 Na+ 0.10183E+01 0.0079 0.56154E+00 -0.2506 0.55147E+00 -0.2585
14 Mn++ 0.87614E-05 -5.0574 0.48293E-06 -6.3161 0.55121E-01 -1.2587
15 Zn++ 0.37221E-07 -7.4292 0.20245E-08 -8.6937 0.54392E-01 -1.2645
16 Cu+ 0.29017E-11 -11.5373 0.15987E-11 -11.7962 0.55095E+00 -0.2589
17 Pb++ 0.49719E-08 -8.3035 0.29871E-09 -9.5248 0.60079E-01 -1.2213
18 Ag+ 0.92779E-11 -11.0326 0.52535E-11 -11.2795 0.56625E+00 -0.2470
19 Au+ 0.20170E-21 -21.6953 0.11531E-21 -21.9381 0.57170E+00 -0.2428
20 Ba++ 0.16315E-05 -5.7874 0.10091E-06 -6.9961 0.61849E-01 -1.2087
21 F- 0.10787E-02 -2.9671 0.56887E-03 -3.2450 0.52739E+00 -0.2779
22 H2AsO3- 0.52267E-06 -6.2818 0.35681E-06 -6.4476 0.68268E+00 -0.1658
24 HSiO3- 0.16787E-05 -5.7750 0.92701E-06 -6.0329 0.55223E+00 -0.2579
25 Ca(HSiO3)+ 0.70303E-08 -8.1530 0.40193E-08 -8.3959 0.57170E+00 -0.2428
26 Mg(HSiO3)+ 0.56374E-09 -9.2489 0.32229E-09 -9.4918 0.57170E+00 -0.2428
27 NaHSiO3,aq 0.44006E-05 -5.3565 0.44006E-05 -5.3565 0.10000E+01 0.0000
31 AgCl,aq 0.16375E-08 -8.7858 0.16375E-08 -8.7858 0.10000E+01 0.0000
32 AgCl2- 0.67610E-07 -7.1700 0.37336E-07 -7.4279 0.55223E+00 -0.2579
33 AgCl3-2 0.38146E-07 -7.4186 0.23590E-08 -8.6273 0.61842E-01 -1.2087
34 AgCl4-3 0.46755E-08 -8.3302 0.79399E-11 -11.1002 0.16982E-02 -2.7700
38 Ag(HS),aq 0.68748E-08 -8.1627 0.68748E-08 -8.1627 0.10000E+01 0.0000
40 AlO+ 0.18241E-09 -9.7390 0.10428E-09 -9.9818 0.57170E+00 -0.2428
42 HAlO2,aq 0.21344E-07 -7.6707 0.21344E-07 -7.6707 0.10000E+01 0.0000
43 AlO2- 0.90766E-07 -7.0421 0.48198E-07 -7.3170 0.53102E+00 -0.2749
44 AsO2- 0.12128E-06 -6.9162 0.66974E-07 -7.1741 0.55223E+00 -0.2579
45 HAsO2,aq 0.30461E-04 -4.5163 0.30461E-04 -4.5163 0.10000E+01 0.0000
46 H3AsO3,aq 0.72408E-04 -4.1402 0.72408E-04 -4.1402 0.10000E+01 0.0000
48 H2AsO4- 0.54617E-10 -10.2627 0.30161E-10 -10.5206 0.55223E+00 -0.2579
62 BaCO3,aq 0.29784E-09 -9.5260 0.29784E-09 -9.5260 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.94548E-06 -6.0243 0.54925E-06 -6.2602 0.58092E+00 -0.2359
64 BaCl+ 0.66721E-06 -6.1757 0.38144E-06 -6.4186 0.57170E+00 -0.2428
65 BaF+ 0.78680E-09 -9.1041 0.44981E-09 -9.3470 0.57170E+00 -0.2428
66 CH4,aq 0.66814E-09 -9.1751 0.60507E-09 -9.2182 0.90561E+00 -0.0431
71 CO,aq 0.75850E-09 -9.1200 0.75850E-09 -9.1200 0.10000E+01 0.0000
72 CO2,aq 0.25808E+00 -0.5882 0.23372E+00 -0.6313 0.90561E+00 -0.0431
73 CO3-2 0.34246E-05 -5.4654 0.21179E-06 -6.6741 0.61842E-01 -1.2087
74 CaCO3,aq 0.78108E-06 -6.1073 0.78108E-06 -6.1073 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.11725E-03 -3.9309 0.67034E-04 -4.1737 0.57170E+00 -0.2428
76 CaCl+ 0.37882E-03 -3.4216 0.21657E-03 -3.6644 0.57170E+00 -0.2428
77 CaCl2,aq 0.28748E-04 -4.5414 0.28748E-04 -4.5414 0.10000E+01 0.0000
78 CaF+ 0.35345E-05 -5.4517 0.20207E-05 -5.6945 0.57170E+00 -0.2428
79 CaOH+ 0.50872E-07 -7.2935 0.29084E-07 -7.5364 0.57170E+00 -0.2428
80 CaSO4,aq 0.47539E-06 -6.3230 0.47539E-06 -6.3230 0.10000E+01 0.0000
81 HCl,aq 0.13328E-05 -5.8752 0.13328E-05 -5.8752 0.10000E+01 0.0000
90 CuCl,aq 0.42295E-08 -8.3737 0.42295E-08 -8.3737 0.10000E+01 0.0000
91 CuCl2- 0.70614E-07 -7.1511 0.38995E-07 -7.4090 0.55223E+00 -0.2579
92 CuCl3-2 0.13375E-07 -7.8737 0.82711E-09 -9.0824 0.61842E-01 -1.2087
98 HF,aq 0.70794E-04 -4.1500 0.70794E-04 -4.1500 0.10000E+01 0.0000
99 HF2- 0.21085E-07 -7.6760 0.11644E-07 -7.9339 0.55223E+00 -0.2579
101 FeCl+ 0.24807E-06 -6.6054 0.14182E-06 -6.8483 0.57170E+00 -0.2428
102 FeCl2,aq 0.45351E-09 -9.3434 0.45351E-09 -9.3434 0.10000E+01 0.0000
104 FeF+ 0.67027E-08 -8.1737 0.38320E-08 -8.4166 0.57170E+00 -0.2428
106 FeO,aq 0.16971E-10 -10.7703 0.16971E-10 -10.7703 0.10000E+01 0.0000
107 FeOH+ 0.78495E-08 -8.1052 0.44876E-08 -8.3480 0.57170E+00 -0.2428
112 HFeO2,aq 0.16056E-10 -10.7944 0.16056E-10 -10.7944 0.10000E+01 0.0000
113 H2,aq 0.78302E-07 -7.1062 0.70911E-07 -7.1493 0.90561E+00 -0.0431
114 KCl,aq 0.70098E-03 -3.1543 0.70098E-03 -3.1543 0.10000E+01 0.0000
115 KHSO4,aq 0.97335E-10 -10.0117 0.97335E-10 -10.0117 0.10000E+01 0.0000
116 KOH,aq 0.19452E-07 -7.7110 0.19452E-07 -7.7110 0.10000E+01 0.0000
117 KSO4- 0.12214E-04 -4.9131 0.67451E-05 -5.1710 0.55223E+00 -0.2579
118 MgCO3,aq 0.10510E-07 -7.9784 0.10510E-07 -7.9784 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.98102E-05 -5.0083 0.56085E-05 -5.2512 0.57170E+00 -0.2428
120 MgCl+ 0.21462E-04 -4.6683 0.12270E-04 -4.9112 0.57170E+00 -0.2428
121 MgF+ 0.94617E-06 -6.0240 0.54093E-06 -6.2669 0.57170E+00 -0.2428
122 MgOH+ 0.16470E-07 -7.7833 0.94157E-08 -8.0261 0.57170E+00 -0.2428
124 MnF+ 0.22237E-07 -7.6529 0.12713E-07 -7.8958 0.57170E+00 -0.2428
126 MnOH+ 0.84972E-08 -8.0707 0.48579E-08 -8.3136 0.57170E+00 -0.2428
131 MnCl+ 0.18733E-04 -4.7274 0.10710E-04 -4.9702 0.57170E+00 -0.2428
132 MnSO4,aq 0.38533E-08 -8.4142 0.38533E-08 -8.4142 0.10000E+01 0.0000
133 NaCl,aq 0.19829E+00 -0.7027 0.19829E+00 -0.7027 0.10000E+01 0.0000
134 NaF,aq 0.14602E-03 -3.8356 0.14602E-03 -3.8356 0.10000E+01 0.0000
135 NaOH,aq 0.42452E-06 -6.3721 0.42452E-06 -6.3721 0.10000E+01 0.0000
137 OH- 0.16176E-05 -5.7911 0.85897E-06 -6.0660 0.53102E+00 -0.2749
140 PbCl+ 0.48793E-07 -7.3116 0.27895E-07 -7.5545 0.57170E+00 -0.2428
141 PbCl2,aq 0.17054E-06 -6.7682 0.17054E-06 -6.7682 0.10000E+01 0.0000
142 PbCl3- 0.10911E-06 -6.9622 0.60252E-07 -7.2200 0.55223E+00 -0.2579
143 PbCl4-2 0.12353E-06 -6.9082 0.76395E-08 -8.1169 0.61842E-01 -1.2087
144 PbF+ 0.78677E-10 -10.1042 0.44980E-10 -10.3470 0.57170E+00 -0.2428
148 Pb(HS)2,aq 0.95784E-10 -10.0187 0.95784E-10 -10.0187 0.10000E+01 0.0000
150 H2S,aq 0.81071E-05 -5.0911 0.73419E-05 -5.1342 0.90561E+00 -0.0431
158 HSO3- 0.96708E-10 -10.0145 0.53405E-10 -10.2724 0.55223E+00 -0.2579
159 HSO4- 0.51791E-06 -6.2857 0.30037E-06 -6.5223 0.57996E+00 -0.2366
161 S2O3-2 0.15217E-10 -10.8177 0.94106E-12 -12.0264 0.61842E-01 -1.2087
173 ZnCl+ 0.35801E-05 -5.4461 0.20467E-05 -5.6889 0.57170E+00 -0.2428
174 ZnCl2,aq 0.80236E-06 -6.0956 0.80236E-06 -6.0956 0.10000E+01 0.0000
175 ZnCl3- 0.99598E-07 -7.0017 0.55001E-07 -7.2596 0.55223E+00 -0.2579
176 ZnF+ 0.16287E-09 -9.7882 0.93111E-10 -10.0310 0.57170E+00 -0.2428
177 ZnO,aq 0.93054E-10 -10.0313 0.93054E-10 -10.0313 0.10000E+01 0.0000
178 ZnOH+ 0.12916E-06 -6.8889 0.73843E-07 -7.1317 0.57170E+00 -0.2428
Charge balance for all species = -.1035E-03
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.1025626E-04 0.2582595E+00 0.2396660E+03 0.0000
2 H2O 0.1000000E+01 0.5525014E+02 0.9164112E+06 0.0000
3 Cl- 0.1034484E+01 0.1233957E+01 0.4027807E+05 5.0209
4 SO4-- 0.1374307E-03 0.1506218E-03 0.1332150E+02 5.4706
5 HCO3- 0.2119655E-01 0.2794074E+00 0.1569660E+05 3.3438
6 HS- 0.8132694E-06 0.8947891E-05 0.2724562E+00 -1.0824
7 H4SiO4 0.2238102E-02 0.2244189E-02 0.1985948E+03 -2.6501
8 Al+++ 0.1924147E-12 0.1123006E-06 0.2789741E-02 0.3053
9 Ca++ 0.1151287E-02 0.1680960E-02 0.6202674E+02 6.3486
10 Mg++ 0.1049095E-03 0.1371553E-03 0.3070074E+01 5.2767
11 Fe++ 0.1007553E-05 0.1270664E-05 0.6533502E-01 3.2669
12 K+ 0.3558218E-01 0.3629539E-01 0.1306670E+04 3.5709
13 Na+ 0.1018272E+01 0.1216709E+01 0.2575357E+05 5.0134
14 Mn++ 0.8761352E-05 0.2752898E-04 0.1392447E+01 4.2120
15 Zn++ 0.3722134E-07 0.4648690E-05 0.2797851E+00 1.8344
16 Cu+ 0.2901712E-11 0.8822057E-07 0.5160985E-02 -6.5322
17 Pb++ 0.4971920E-08 0.4571222E-06 0.8720004E-01 1.0033
18 Ag+ 0.9277860E-11 0.1189559E-06 0.1181414E-01 -6.0155
19 Au+ 0.2016958E-21 0.2484012E-11 0.4504667E-06 -16.6741
20 Ba++ 0.1631536E-05 0.3245306E-05 0.4103630E+00 3.5320
21 F- 0.1078654E-02 0.1300017E-02 0.2273906E+02 2.0191
22 H2AsO3- 0.5226650E-06 0.1035138E-03 0.1190694E+02 -1.1835
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234425E+00 -.7345363E-05 0.0000000E+00
2 H2O 0.6919492E+02 0.6919492E+02 -.5967025E-08 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886378E-03 0.1491756E-08 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1120628E-04 0.2824029E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810608E-02 0.1133317E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.1406446E-06 0.2266634E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1591371E-05 0.1193405E-07 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.5821990E-05 0.1646186E-05 0.0000000E+00
16 Cu+ 0.1701571E-06 0.1104869E-06 0.5967025E-07 0.0000000E+00
17 Pb++ 0.1565021E-05 0.5724970E-06 0.9925237E-06 0.0000000E+00
18 Ag+ 0.4271281E-06 0.1489796E-06 0.2781485E-06 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1628133E-02 0.2266634E-05 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.136027E+04 g
Temperature = 166.51 C Pressure = 500.00 bar Mixer frac. = 0.2500000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
argentite 0.1391E-06 -6.857 0.3446E-04 -4.463 5.328 0.4840E-05
bornite 0.1193E-07 -7.923 0.5989E-05 -5.223 0.9258 0.1178E-05
topaz 0.1133E-05 -5.946 0.2086E-03 -3.681 32.24 0.5839E-04
galena 0.9925E-06 -6.003 0.2375E-03 -3.624 36.71 0.3125E-04
sphalerite 0.1646E-05 -5.784 0.1604E-03 -3.795 24.79 0.3922E-04
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
argentite 0.1000E+01 0.1000E+01 1.0000 0.000
bornite 0.1000E+01 0.1000E+01 1.0000 0.000
topaz 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.2500000
Solid products produced: Mass = 0.000647 g Volume = 0.000135 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.400
AFFINITY: 0.3825E+03
GOLD Q/K: 0.0400
SILVER Q/K: 0.2223
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 166.5096 deg.C
Sat. pressure: 74.4921 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.1639E+00 0.6928 0.8461E+01 0.1221E+02
CO2,gas 0.8361E+00 0.9015 0.5614E+02 0.6228E+02
CH4,gas 0.1493E-07 1.0884 0.1211E-05 0.1112E-05
H2,gas 0.1150E-05 1.0343 0.8861E-04 0.8567E-04
H2S,gas 0.6652E-05 0.8400 0.4163E-03 0.4955E-03
S2,gas 0.4752E-16 1.0000 0.3540E-14 0.3540E-14
CO,gas 0.1532E-07 1.0000 0.1141E-05 0.1141E-05
SO3,gas 0.4669E-27 1.0000 0.3478E-25 0.3478E-25
O2,gas 0.2266E-44 1.0000 0.1688E-42 0.1688E-42
SO2,gas 0.1725E-12 1.0000 0.1285E-10 0.1285E-10
HF,gas 0.2501E-07 1.0000 0.1863E-05 0.1863E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
196 argentite -23.64 -23.64 0.00 0.000 -0.71474E-11
205 bornite -76.32 -76.32 0.00 0.000 0.00000E+00
225 topaz -19.06 -19.06 0.00 0.000 0.71474E-11
260 galena -10.61 -10.61 0.00 0.000 0.00000E+00
272 sphalerite -9.78 -9.78 0.00 0.000 0.35737E-11
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.75 -0.02 -1.77 -1.772 0.35640E+04 0.927
2 CO2,gas -6.22 -7.17 -0.95 -0.317 0.19105E+04 1.749
3 CH4,gas 5.39 -3.23 -8.62 -2.154 0.17334E+05 -5.917
4 H2,gas 7.73 0.98 -6.75 -3.858 0.13583E+05 -4.053
5 H2S,gas -5.53 -11.61 -6.08 -3.040 0.12231E+05 -3.381
6 S2,gas -8.02 -25.17 -17.15 -2.638 0.34502E+05 -14.451
7 CO,gas 2.47 -6.17 -8.64 -2.659 0.17385E+05 -5.943
8 SO3,gas 12.59 -15.57 -28.16 -7.039 0.56648E+05 -25.459
9 O2,gas 43.48 -1.99 -45.47 -30.314 0.91480E+05 -42.773
10 SO2,gas -0.98 -14.57 -13.59 -3.624 0.27340E+05 -10.891
11 HF,gas -0.08 -8.51 -8.43 -4.214 0.16957E+05 -5.730
12 HCl,gas 1.52 -5.51 -7.03 -3.516 0.14147E+05 -7.032
13 acmite 6.52 2.53 -3.99 -0.415 0.80347E+04
17 albite-high -0.80 -2.56 -1.76 -0.135 0.35362E+04
18 albite -1.59 -2.56 -0.97 -0.075 0.19607E+04
22 analcite 1.61 0.04 -1.58 -0.175 0.31731E+04
23 andalusite 0.60 -2.06 -2.66 -0.266 0.53521E+04
26 anhydrite -6.19 -9.24 -3.05 -1.525 0.61379E+04
27 ankerite -3.36 -4.75 -1.40 -0.233 0.28072E+04
34 aragonite 0.26 -0.84 -1.09 -0.365 0.22002E+04
36 calcite 0.12 -0.84 -0.95 -0.318 0.19203E+04
37 carnegieite-low 6.36 2.67 -3.69 -0.527 0.74176E+04
38 carnegieite-high 7.14 2.67 -4.47 -0.639 0.90016E+04
39 carpholite-Mg 3.79 0.55 -3.24 -0.216 0.65236E+04
40 carpholite-Fe 2.18 -1.46 -3.64 -0.242 0.73156E+04
41 celadonite 3.36 -1.38 -4.74 -0.279 0.95281E+04
49 chloritoid-Mg 7.35 3.18 -4.16 -0.278 0.83791E+04
50 chloritoid-Fe 3.99 1.17 -2.81 -0.187 0.56566E+04
51 chloritoid-Mn 6.18 2.12 -4.06 -0.271 0.81701E+04
53 coesite -1.97 -2.61 -0.64 -0.215 0.12951E+04
58 corundum 3.41 0.56 -2.86 -0.260 0.57460E+04
60 cristobalite -2.15 -2.61 -0.46 -0.153 0.92638E+03
63 cymrite-K 0.38 -4.02 -4.40 -0.367 0.88508E+04
65 diaspore 0.82 0.27 -0.55 -0.092 0.11138E+04
66 diamond -2.38 -5.18 -2.79 -0.798 0.56217E+04
69 dolomite,ordered -1.04 -2.74 -1.70 -0.284 0.34222E+04
83 gibbsite 2.04 0.25 -1.79 -0.256 0.36068E+04
86 goethite 5.00 2.74 -2.26 -0.488 0.45401E+04
87 graphite -2.78 -5.18 -2.40 -0.685 0.48209E+04
90 halite 1.47 -0.49 -1.97 -0.984 0.39591E+04
91 hematite 9.47 5.50 -3.97 -0.481 0.79842E+04
92 heulandite -7.91 -11.52 -3.61 -0.164 0.72543E+04
96 jadeite 2.43 0.05 -2.38 -0.238 0.47815E+04
98 kalsilite 5.22 1.23 -4.00 -0.571 0.80430E+04
99 kaolinite -4.03 -4.71 -0.68 -0.062 0.13674E+04
100 kyanite 0.53 -2.06 -2.59 -0.259 0.52067E+04
102 laumontite -0.40 -3.64 -3.25 -0.216 0.65289E+04
103 lawsonite 5.15 1.62 -3.52 -0.235 0.70850E+04
104 leucite 2.20 -1.39 -3.59 -0.359 0.72208E+04
107 magnesite -0.36 -1.91 -1.54 -0.515 0.31068E+04
117 microcline -3.18 -4.00 -0.82 -0.063 0.16597E+04
120 mullite-Si 2.44 -2.06 -4.50 -0.450 0.90573E+04
121 muscovite -2.23 -3.46 -1.23 -0.073 0.24832E+04
122 paragonite -0.95 -2.02 -1.07 -0.063 0.21505E+04
123 nepheline 5.74 2.67 -3.07 -0.439 0.61852E+04
143 pyrite -19.60 -20.93 -1.33 -0.313 0.26776E+04
144 pyrrhotite -4.69 -8.34 -3.65 -1.218 0.73488E+04
145 pyrrhotiteFe0.875 -6.13 -8.87 -2.74 -1.008 0.55142E+04
146 pyroxmangite 6.00 1.58 -4.42 -0.884 0.88899E+04
147 pyrophyllite -8.35 -9.92 -1.57 -0.098 0.31574E+04
148 quartz -2.49 -2.61 -0.12 -0.041 0.24482E+03
153 rhodochrosite -1.51 -2.97 -1.47 -0.489 0.29508E+04
154 rhodonite 6.03 1.58 -4.45 -0.890 0.89535E+04
155 sanidine -2.15 -4.00 -1.85 -0.143 0.37281E+04
157 siderite -3.17 -3.92 -0.75 -0.250 0.15069E+04
158 sillimanite 0.79 -2.06 -2.85 -0.285 0.57346E+04
165 stilbite -8.20 -11.54 -3.34 -0.159 0.67235E+04
171 sulfur -8.57 -12.59 -4.02 -1.236 0.80797E+04
172 sylvite 1.45 -1.94 -3.38 -1.691 0.68028E+04
180 topaz-H 0.76 -2.07 -2.84 -0.258 0.57062E+04
181 tridymite -2.19 -2.61 -0.42 -0.141 0.85365E+03
184 troilite-low -4.77 -8.34 -3.57 -1.190 0.71795E+04
190 wairakite 0.08 -3.61 -3.68 -0.217 0.74090E+04
197 arsenic -5.93 -10.19 -4.26 -1.100 0.85745E+04
199 arsenopyrite -13.73 -18.54 -4.81 -0.855 0.96781E+04
200 beidellite-Ca -5.18 -7.92 -2.74 -0.170 0.55133E+04
201 beidellite-H -5.69 -8.97 -3.27 -0.209 0.65859E+04
202 beidellite-K -4.81 -7.79 -2.97 -0.182 0.59841E+04
203 beidellite-Mg -5.41 -8.10 -2.69 -0.166 0.54142E+04
204 beidellite-Na -4.71 -7.31 -2.60 -0.159 0.52326E+04
207 chalcedony -2.33 -2.61 -0.28 -0.094 0.56459E+03
208 chalcocite -23.50 -24.67 -1.17 -0.293 0.23589E+04
210 covellite -17.13 -18.63 -1.50 -0.572 0.30225E+04
211 dawsonite 0.39 -1.90 -2.29 -0.287 0.46156E+04
213 montmorillonite-Ca -4.69 -7.23 -2.54 -0.157 0.51167E+04
214 montmorillonite-K -4.41 -7.10 -2.68 -0.164 0.54017E+04
215 montmorillonite-Mg -4.91 -7.41 -2.49 -0.154 0.50191E+04
216 montmorillonite-Na -4.25 -6.62 -2.38 -0.146 0.47821E+04
217 nontronite-Ca 1.45 -2.97 -4.43 -0.287 0.89033E+04
218 nontronite-H 0.94 -4.02 -4.96 -0.332 0.99688E+04
219 nontronite-K 1.82 -2.84 -4.66 -0.299 0.93733E+04
220 nontronite-Mg 1.26 -3.15 -4.41 -0.286 0.88653E+04
221 nontronite-Na 1.92 -2.37 -4.29 -0.275 0.86249E+04
229 gypsum -5.39 -9.27 -3.89 -0.972 0.78197E+04
245 acanthite -23.48 -23.64 -0.16 -0.041 0.32762E+03
251 barite -9.45 -12.05 -2.60 -1.300 0.52295E+04
252 boehmite 2.01 0.27 -1.74 -0.289 0.34928E+04
253 cerussite -2.75 -6.18 -3.43 -1.143 0.69006E+04
254 chalcopyrite -25.55 -26.97 -1.43 -0.265 0.28702E+04
256 copper,native -1.96 -6.04 -4.09 -1.422 0.82243E+04
257 dolomite,disordered -0.54 -2.74 -2.21 -0.368 0.44390E+04
258 ferrous-oxide 7.66 3.25 -4.42 -1.104 0.88832E+04
259 fluorite -10.02 -10.67 -0.65 -0.217 0.13121E+04
261 gold,native -14.79 -16.19 -1.40 -0.486 0.28116E+04
262 silver,native -4.87 -5.53 -0.65 -0.227 0.13136E+04
269 silica-amorphous -1.76 -2.61 -0.85 -0.284 0.17163E+04
270 smithsonite -1.49 -5.35 -3.86 -1.286 0.77633E+04
273 wurtzite -8.22 -9.78 -1.55 -0.518 0.31266E+04
274 zincite 6.41 1.82 -4.59 -1.147 0.92320E+04
275 an20ab80 -0.10 -1.72 -1.61 -0.124 0.32448E+04
276 an25ab75 0.29 -1.51 -1.80 -0.138 0.36201E+04
277 an30ab70 0.70 -1.29 -1.99 -0.153 0.40076E+04
Calculations done for 166.5096 Deg. C; 500.0000 bar
Mixer fraction: 0.2500000
Temperature Stoc.ionic strength Heat per mole
Actual solution: 166.510 .13944E+01 3.157
Mixing solution: 25.000 .50000E-10 0.646
Fract. of mixing solution added: 0.050000
BITMOL = 0.2775E+01 OLDMOL = 0.7093E+02
New heat: 3.063 New temperature: 161.282
New mixer fraction: 0.3000000
Resulting temperature: 161.282Deg. C
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1296E-03
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 7 Loop limit = 70
Temperature = 161.28 C Pressure = 500.00 bar Mixer fraction = 0.3000000
Water: Moles liquid = 0.7229E+02 kg liquid = 0.1302E+01
Moles total = 0.7197E+02 kg total = 0.1297E+01 Activity = 0.9613
Stoichiometric ionic strength = .1340614E+01 Osmotic coef. = 0.9225
True ionic strength = .1028167E+01
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.10987E-04 -4.9591 0.59415E-05 -5.2261 0.54078E+00 -0.2670
2 H2O 0.96132E+00 -0.0171 0.96132E+00 -0.0171
3 Cl- 0.10051E+01 0.0022 0.56246E+00 -0.2499 0.55960E+00 -0.2521
4 SO4-- 0.13267E-03 -3.8772 0.90823E-05 -5.0418 0.68456E-01 -1.1646
5 HCO3- 0.20391E-01 -1.6906 0.11685E-01 -1.9324 0.57304E+00 -0.2418
6 HS- 0.71180E-06 -6.1476 0.39932E-06 -6.3987 0.56100E+00 -0.2510
7 H4SiO4 0.21527E-02 -2.6670 0.21527E-02 -2.6670 0.10000E+01 0.0000
8 Al+++ 0.26116E-12 -12.5831 0.52607E-15 -15.2790 0.20143E-02 -2.6959
9 Ca++ 0.11310E-02 -2.9466 0.70159E-04 -4.1539 0.62035E-01 -1.2074
10 Mg++ 0.10197E-03 -3.9915 0.59165E-05 -5.2279 0.58023E-01 -1.2364
11 Fe++ 0.97611E-06 -6.0105 0.57572E-07 -7.2398 0.58981E-01 -1.2293
12 K+ 0.34286E-01 -1.4649 0.19730E-01 -1.7049 0.57543E+00 -0.2400
13 Na+ 0.98944E+00 -0.0046 0.55258E+00 -0.2576 0.55848E+00 -0.2530
14 Mn++ 0.90294E-05 -5.0443 0.53911E-06 -6.2683 0.59706E-01 -1.2240
15 Zn++ 0.40509E-07 -7.3925 0.23892E-08 -8.6217 0.58981E-01 -1.2293
16 Cu+ 0.22970E-11 -11.6388 0.12818E-11 -11.8922 0.55801E+00 -0.2534
17 Pb++ 0.47173E-08 -8.3263 0.30502E-09 -9.5157 0.64659E-01 -1.1894
18 Ag+ 0.72239E-11 -11.1412 0.41334E-11 -11.3837 0.57218E+00 -0.2425
19 Au+ 0.14612E-21 -21.8353 0.84350E-22 -22.0739 0.57728E+00 -0.2386
20 Ba++ 0.16528E-05 -5.7818 0.10980E-06 -6.9594 0.66434E-01 -1.1776
21 F- 0.10453E-02 -2.9808 0.56183E-03 -3.2504 0.53747E+00 -0.2696
22 H2AsO3- 0.41584E-06 -6.3811 0.28402E-06 -6.5467 0.68299E+00 -0.1656
24 HSiO3- 0.14484E-05 -5.8391 0.81052E-06 -6.0912 0.55960E+00 -0.2521
25 Ca(HSiO3)+ 0.58305E-08 -8.2343 0.33658E-08 -8.4729 0.57728E+00 -0.2386
26 Mg(HSiO3)+ 0.47477E-09 -9.3235 0.27408E-09 -9.5621 0.57728E+00 -0.2386
27 NaHSiO3,aq 0.38718E-05 -5.4121 0.38718E-05 -5.4121 0.10000E+01 0.0000
31 AgCl,aq 0.12688E-08 -8.8966 0.12688E-08 -8.8966 0.10000E+01 0.0000
32 AgCl2- 0.50534E-07 -7.2964 0.28279E-07 -7.5485 0.55960E+00 -0.2521
33 AgCl3-2 0.26865E-07 -7.5708 0.17881E-08 -8.7476 0.66561E-01 -1.1768
34 AgCl4-3 0.29719E-08 -8.5270 0.60398E-11 -11.2190 0.20323E-02 -2.6920
38 Ag(HS),aq 0.64507E-08 -8.1904 0.64507E-08 -8.1904 0.10000E+01 0.0000
40 AlO+ 0.17839E-09 -9.7486 0.10298E-09 -9.9872 0.57728E+00 -0.2386
42 HAlO2,aq 0.17428E-07 -7.7587 0.17428E-07 -7.7587 0.10000E+01 0.0000
43 AlO2- 0.59353E-07 -7.2266 0.32087E-07 -7.4937 0.54061E+00 -0.2671
44 AsO2- 0.10465E-06 -6.9803 0.58562E-07 -7.2324 0.55960E+00 -0.2521
45 HAsO2,aq 0.30122E-04 -4.5211 0.30122E-04 -4.5211 0.10000E+01 0.0000
46 H3AsO3,aq 0.68898E-04 -4.1618 0.68898E-04 -4.1618 0.10000E+01 0.0000
48 H2AsO4- 0.44782E-10 -10.3489 0.25060E-10 -10.6010 0.55960E+00 -0.2521
62 BaCO3,aq 0.26396E-09 -9.5785 0.26396E-09 -9.5785 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.84423E-06 -6.0735 0.49465E-06 -6.3057 0.58593E+00 -0.2322
64 BaCl+ 0.62266E-06 -6.2057 0.35945E-06 -6.4444 0.57728E+00 -0.2386
65 BaF+ 0.74868E-09 -9.1257 0.43219E-09 -9.3643 0.57728E+00 -0.2386
66 CH4,aq 0.55338E-09 -9.2570 0.50041E-09 -9.3007 0.90429E+00 -0.0437
71 CO,aq 0.54426E-09 -9.2642 0.54426E-09 -9.2642 0.10000E+01 0.0000
72 CO2,aq 0.24817E+00 -0.6053 0.22442E+00 -0.6489 0.90429E+00 -0.0437
73 CO3-2 0.29851E-05 -5.5250 0.19870E-06 -6.7018 0.66561E-01 -1.1768
74 CaCO3,aq 0.67602E-06 -6.1700 0.67602E-06 -6.1700 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.10691E-03 -3.9710 0.61718E-04 -4.2096 0.57728E+00 -0.2386
76 CaCl+ 0.34855E-03 -3.4577 0.20121E-03 -3.6963 0.57728E+00 -0.2386
77 CaCl2,aq 0.25554E-04 -4.5925 0.25554E-04 -4.5925 0.10000E+01 0.0000
78 CaF+ 0.32478E-05 -5.4884 0.18749E-05 -5.7270 0.57728E+00 -0.2386
79 CaOH+ 0.38411E-07 -7.4155 0.22174E-07 -7.6542 0.57728E+00 -0.2386
80 CaSO4,aq 0.47406E-06 -6.3242 0.47406E-06 -6.3242 0.10000E+01 0.0000
81 HCl,aq 0.13376E-05 -5.8737 0.13376E-05 -5.8737 0.10000E+01 0.0000
90 CuCl,aq 0.33465E-08 -8.4754 0.33465E-08 -8.4754 0.10000E+01 0.0000
91 CuCl2- 0.54226E-07 -7.2658 0.30345E-07 -7.5179 0.55960E+00 -0.2521
92 CuCl3-2 0.98060E-08 -8.0085 0.65270E-09 -9.1853 0.66561E-01 -1.1768
98 HF,aq 0.67868E-04 -4.1683 0.67868E-04 -4.1683 0.10000E+01 0.0000
99 HF2- 0.19819E-07 -7.7029 0.11091E-07 -7.9550 0.55960E+00 -0.2521
101 FeCl+ 0.22934E-06 -6.6395 0.13239E-06 -6.8781 0.57728E+00 -0.2386
102 FeCl2,aq 0.28545E-09 -9.5445 0.28545E-09 -9.5445 0.10000E+01 0.0000
104 FeF+ 0.63003E-08 -8.2006 0.36370E-08 -8.4393 0.57728E+00 -0.2386
106 FeO,aq 0.10455E-10 -10.9807 0.10455E-10 -10.9807 0.10000E+01 0.0000
107 FeOH+ 0.63304E-08 -8.1986 0.36544E-08 -8.4372 0.57728E+00 -0.2386
112 HFeO2,aq 0.10212E-10 -10.9909 0.10212E-10 -10.9909 0.10000E+01 0.0000
113 H2,aq 0.59746E-07 -7.2237 0.54028E-07 -7.2674 0.90429E+00 -0.0437
114 KCl,aq 0.60428E-03 -3.2188 0.60428E-03 -3.2188 0.10000E+01 0.0000
115 KHSO4,aq 0.78395E-10 -10.1057 0.78395E-10 -10.1057 0.10000E+01 0.0000
116 KOH,aq 0.15012E-07 -7.8236 0.15012E-07 -7.8236 0.10000E+01 0.0000
117 KSO4- 0.11214E-04 -4.9502 0.62754E-05 -5.2024 0.55960E+00 -0.2521
118 MgCO3,aq 0.93302E-08 -8.0301 0.93302E-08 -8.0301 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.89326E-05 -5.0490 0.51566E-05 -5.2876 0.57728E+00 -0.2386
120 MgCl+ 0.20091E-04 -4.6970 0.11598E-04 -4.9356 0.57728E+00 -0.2386
121 MgF+ 0.87488E-06 -6.0581 0.50505E-06 -6.2967 0.57728E+00 -0.2386
122 MgOH+ 0.12631E-07 -7.8986 0.72913E-08 -8.1372 0.57728E+00 -0.2386
124 MnF+ 0.21955E-07 -7.6585 0.12674E-07 -7.8971 0.57728E+00 -0.2386
126 MnOH+ 0.71652E-08 -8.1448 0.41363E-08 -8.3834 0.57728E+00 -0.2386
131 MnCl+ 0.17410E-04 -4.7592 0.10050E-04 -4.9978 0.57728E+00 -0.2386
132 MnSO4,aq 0.39984E-08 -8.3981 0.39984E-08 -8.3981 0.10000E+01 0.0000
133 NaCl,aq 0.18042E+00 -0.7437 0.18042E+00 -0.7437 0.10000E+01 0.0000
134 NaF,aq 0.13270E-03 -3.8771 0.13270E-03 -3.8771 0.10000E+01 0.0000
135 NaOH,aq 0.33698E-06 -6.4724 0.33698E-06 -6.4724 0.10000E+01 0.0000
137 OH- 0.13163E-05 -5.8806 0.71163E-06 -6.1477 0.54061E+00 -0.2671
140 PbCl+ 0.44231E-07 -7.3543 0.25533E-07 -7.5929 0.57728E+00 -0.2386
141 PbCl2,aq 0.14488E-06 -6.8390 0.14488E-06 -6.8390 0.10000E+01 0.0000
142 PbCl3- 0.87653E-07 -7.0572 0.49050E-07 -7.3094 0.55960E+00 -0.2521
143 PbCl4-2 0.93006E-07 -7.0315 0.61906E-08 -8.2083 0.66561E-01 -1.1768
144 PbF+ 0.73379E-10 -10.1344 0.42360E-10 -10.3730 0.57728E+00 -0.2386
148 Pb(HS)2,aq 0.80210E-10 -10.0958 0.80210E-10 -10.0958 0.10000E+01 0.0000
150 H2S,aq 0.75213E-05 -5.1237 0.68014E-05 -5.1674 0.90429E+00 -0.0437
158 HSO3- 0.76733E-10 -10.1150 0.42940E-10 -10.3671 0.55960E+00 -0.2521
159 HSO4- 0.48924E-06 -6.3105 0.28633E-06 -6.5431 0.58526E+00 -0.2326
161 S2O3-2 0.13545E-10 -10.8682 0.90160E-12 -12.0450 0.66561E-01 -1.1768
173 ZnCl+ 0.32711E-05 -5.4853 0.18883E-05 -5.7239 0.57728E+00 -0.2386
174 ZnCl2,aq 0.70624E-06 -6.1510 0.70624E-06 -6.1510 0.10000E+01 0.0000
175 ZnCl3- 0.85577E-07 -7.0676 0.47889E-07 -7.3198 0.55960E+00 -0.2521
176 ZnF+ 0.17124E-09 -9.7664 0.98851E-10 -10.0050 0.57728E+00 -0.2386
177 ZnO,aq 0.66385E-10 -10.1779 0.66385E-10 -10.1779 0.10000E+01 0.0000
178 ZnOH+ 0.10914E-06 -6.9620 0.63002E-07 -7.2006 0.57728E+00 -0.2386
Charge balance for all species = -.9952E-04
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.1098695E-04 0.2483451E+00 0.2311693E+03 0.0000
2 H2O 0.1000000E+01 0.5526005E+02 0.9193748E+06 0.0000
3 Cl- 0.1005112E+01 0.1186585E+01 0.3885005E+05 4.9762
4 SO4-- 0.1326729E-03 0.1448389E-03 0.1284916E+02 5.4104
5 HCO3- 0.2039134E-01 0.2686807E+00 0.1514009E+05 3.2937
6 HS- 0.7117958E-06 0.8255346E-05 0.2521364E+00 -1.1726
7 H4SiO4 0.2152691E-02 0.2158017E-02 0.1915524E+03 -2.6670
8 Al+++ 0.2611621E-12 0.7696943E-07 0.1917892E-02 0.3994
9 Ca++ 0.1130965E-02 0.1616427E-02 0.5982764E+02 6.2983
10 Mg++ 0.1019691E-03 0.1318898E-03 0.2961227E+01 5.2243
11 Fe++ 0.9761097E-06 0.1218391E-05 0.6283860E-01 3.2124
12 K+ 0.3428648E-01 0.3490198E-01 0.1260343E+04 3.5212
13 Na+ 0.9894386E+00 0.1169998E+01 0.2484050E+05 4.9685
14 Mn++ 0.9029403E-05 0.2647212E-04 0.1343079E+01 4.1839
15 Zn++ 0.4050866E-07 0.4212787E-05 0.2543243E+00 1.8305
16 Cu+ 0.2297034E-11 0.6738126E-07 0.3953904E-02 -6.6661
17 Pb++ 0.4717326E-08 0.3746519E-06 0.7168637E-01 0.9365
18 Ag+ 0.7223929E-11 0.8809903E-07 0.8776304E-02 -6.1576
19 Au+ 0.1461167E-21 0.2388649E-11 0.4344958E-06 -16.8478
20 Ba++ 0.1652814E-05 0.3120716E-05 0.3958140E+00 3.4928
21 F- 0.1045321E-02 0.1250078E-02 0.2193233E+02 1.9757
22 H2AsO3- 0.4158429E-06 0.9953981E-04 0.1148479E+02 -1.3205
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234430E+00 -.7876190E-05 0.0000000E+00
2 H2O 0.7197033E+02 0.7197033E+02 -.8240021E-08 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886372E-03 0.2060005E-08 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1075171E-04 0.3278601E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810587E-02 0.1153517E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.1002445E-06 0.2307034E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1586825E-05 0.1648004E-07 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.5486706E-05 0.1981470E-05 0.0000000E+00
16 Cu+ 0.1701571E-06 0.8775691E-07 0.8240021E-07 0.0000000E+00
17 Pb++ 0.1565021E-05 0.4879442E-06 0.1077076E-05 0.0000000E+00
18 Ag+ 0.4271281E-06 0.1147396E-06 0.3123885E-06 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1628093E-02 0.2307034E-05 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: -.1271E-20 Mass of aqueous solution: 0.141027E+04 g
Temperature = 161.28 C Pressure = 500.00 bar Mixer frac. = 0.3000000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
argentite 0.1562E-06 -6.806 0.3870E-04 -4.412 5.451 0.5435E-05
bornite 0.1648E-07 -7.783 0.8270E-05 -5.083 1.165 0.1627E-05
topaz 0.1154E-05 -5.938 0.2123E-03 -3.673 29.90 0.5943E-04
galena 0.1077E-05 -5.968 0.2577E-03 -3.589 36.29 0.3392E-04
sphalerite 0.1981E-05 -5.703 0.1931E-03 -3.714 27.19 0.4721E-04
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
argentite 0.1000E+01 0.1000E+01 1.0000 0.000
bornite 0.1000E+01 0.1000E+01 1.0000 0.000
topaz 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.3000000
Solid products produced: Mass = 0.000710 g Volume = 0.000148 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.400
AFFINITY: 0.3573E+03
GOLD Q/K: 0.0464
SILVER Q/K: 0.2046
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 161.2823 deg.C
Sat. pressure: 70.6223 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.1508E+00 0.7028 0.7484E+01 0.1065E+02
CO2,gas 0.8492E+00 0.9014 0.5406E+02 0.5997E+02
CH4,gas 0.1368E-07 1.0813 0.1045E-05 0.9663E-06
H2,gas 0.9654E-06 1.0329 0.7042E-04 0.6818E-04
H2S,gas 0.6477E-05 0.8424 0.3853E-03 0.4574E-03
S2,gas 0.3860E-16 1.0000 0.2726E-14 0.2726E-14
CO,gas 0.1223E-07 1.0000 0.8640E-06 0.8640E-06
SO3,gas 0.2463E-27 1.0000 0.1740E-25 0.1740E-25
O2,gas 0.5978E-45 1.0000 0.4222E-43 0.4222E-43
SO2,gas 0.1314E-12 1.0000 0.9277E-11 0.9277E-11
HF,gas 0.2193E-07 1.0000 0.1549E-05 0.1549E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
196 argentite -23.94 -23.94 0.00 0.000 0.00000E+00
205 bornite -77.09 -77.09 0.00 0.000 0.00000E+00
225 topaz -18.82 -18.82 0.00 0.000 0.70624E-11
260 galena -10.69 -10.69 0.00 0.000 0.00000E+00
272 sphalerite -9.79 -9.79 0.00 0.000 0.00000E+00
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.81 -0.02 -1.82 -1.825 0.36275E+04 0.874
2 CO2,gas -6.18 -7.14 -0.97 -0.322 0.19206E+04 1.733
3 CH4,gas 5.37 -3.31 -8.68 -2.170 0.17255E+05 -5.981
4 H2,gas 7.80 0.95 -6.85 -3.915 0.13620E+05 -4.152
5 H2S,gas -5.51 -11.62 -6.11 -3.057 0.12152E+05 -3.414
6 S2,gas -7.89 -25.15 -17.26 -2.656 0.34318E+05 -14.564
7 CO,gas 2.59 -6.17 -8.76 -2.696 0.17419E+05 -6.063
8 SO3,gas 12.98 -15.48 -28.46 -7.115 0.56572E+05 -25.760
9 O2,gas 44.14 -1.93 -46.07 -30.716 0.91589E+05 -43.375
10 SO2,gas -0.78 -14.51 -13.73 -3.662 0.27297E+05 -11.033
11 HF,gas 0.03 -8.48 -8.51 -4.255 0.16915E+05 -5.810
12 HCl,gas 1.66 -5.48 -7.13 -3.567 0.14180E+05 -7.133
13 acmite 6.61 2.41 -4.21 -0.437 0.83644E+04
17 albite-high -0.67 -2.56 -1.89 -0.146 0.37634E+04
18 albite -1.47 -2.56 -1.09 -0.084 0.21670E+04
22 analcite 1.75 0.05 -1.70 -0.189 0.33869E+04
23 andalusite 0.94 -1.89 -2.83 -0.283 0.56189E+04
26 anhydrite -6.09 -9.20 -3.11 -1.554 0.61766E+04
27 ankerite -3.24 -4.81 -1.57 -0.262 0.31225E+04
34 aragonite 0.33 -0.86 -1.19 -0.395 0.23564E+04
36 calcite 0.19 -0.86 -1.05 -0.349 0.20798E+04
37 carnegieite-low 6.56 2.70 -3.86 -0.551 0.76701E+04
38 carnegieite-high 7.37 2.70 -4.67 -0.666 0.92737E+04
39 carpholite-Mg 4.16 0.65 -3.50 -0.234 0.69642E+04
40 carpholite-Fe 2.53 -1.36 -3.88 -0.259 0.77209E+04
41 celadonite 3.52 -1.45 -4.98 -0.293 0.98965E+04
49 chloritoid-Mg 7.78 3.30 -4.48 -0.299 0.89037E+04
50 chloritoid-Fe 4.38 1.29 -3.08 -0.206 0.61323E+04
51 chloritoid-Mn 6.57 2.26 -4.31 -0.287 0.85652E+04
53 coesite -2.00 -2.63 -0.64 -0.212 0.12667E+04
58 corundum 3.79 0.75 -3.04 -0.276 0.60393E+04
60 cristobalite -2.18 -2.63 -0.46 -0.152 0.90728E+03
63 cymrite-K 0.49 -4.03 -4.52 -0.377 0.89865E+04
65 diaspore 0.98 0.37 -0.61 -0.102 0.12169E+04
66 diamond -2.43 -5.21 -2.77 -0.793 0.55150E+04
69 dolomite,ordered -0.90 -2.79 -1.90 -0.316 0.37713E+04
83 gibbsite 2.19 0.35 -1.85 -0.264 0.36689E+04
86 goethite 5.10 2.70 -2.40 -0.519 0.47723E+04
87 graphite -2.83 -5.21 -2.37 -0.678 0.47196E+04
90 halite 1.49 -0.51 -2.00 -0.999 0.39721E+04
91 hematite 9.70 5.42 -4.28 -0.519 0.85067E+04
92 heulandite -7.71 -11.50 -3.79 -0.172 0.75403E+04
96 jadeite 2.57 0.07 -2.50 -0.250 0.49748E+04
98 kalsilite 5.41 1.25 -4.15 -0.593 0.82552E+04
99 kaolinite -3.81 -4.55 -0.74 -0.067 0.14753E+04
100 kyanite 0.86 -1.89 -2.75 -0.275 0.54620E+04
102 laumontite -0.12 -3.57 -3.45 -0.230 0.68551E+04
103 lawsonite 5.48 1.73 -3.76 -0.250 0.74670E+04
104 leucite 2.36 -1.38 -3.74 -0.374 0.74306E+04
107 magnesite -0.27 -1.93 -1.66 -0.553 0.32988E+04
117 microcline -3.10 -4.01 -0.91 -0.070 0.18124E+04
120 mullite-Si 2.81 -1.89 -4.70 -0.470 0.93354E+04
121 muscovite -1.84 -3.28 -1.44 -0.085 0.28596E+04
122 paragonite -0.54 -1.83 -1.29 -0.076 0.25695E+04
123 nepheline 5.94 2.70 -3.24 -0.463 0.64402E+04
143 pyrite -19.68 -20.99 -1.31 -0.308 0.26040E+04
144 pyrrhotite -4.64 -8.41 -3.77 -1.257 0.74936E+04
145 pyrrhotiteFe0.875 -6.11 -8.93 -2.83 -1.039 0.56184E+04
146 pyroxmangite 6.10 1.53 -4.57 -0.913 0.90797E+04
147 pyrophyllite -8.16 -9.80 -1.64 -0.103 0.32688E+04
148 quartz -2.52 -2.63 -0.11 -0.037 0.21861E+03
153 rhodochrosite -1.45 -2.97 -1.52 -0.507 0.30257E+04
154 rhodonite 6.13 1.53 -4.60 -0.920 0.91445E+04
155 sanidine -2.06 -4.01 -1.95 -0.150 0.38805E+04
157 siderite -3.11 -3.95 -0.83 -0.278 0.16593E+04
158 sillimanite 1.14 -1.89 -3.02 -0.302 0.60047E+04
165 stilbite -8.09 -11.52 -3.43 -0.163 0.68176E+04
171 sulfur -8.59 -12.57 -3.98 -1.226 0.79189E+04
172 sylvite 1.45 -1.95 -3.40 -1.702 0.67677E+04
180 topaz-H 1.05 -1.90 -2.96 -0.269 0.58783E+04
181 tridymite -2.21 -2.63 -0.42 -0.140 0.83255E+03
184 troilite-low -4.73 -8.41 -3.68 -1.227 0.73173E+04
190 wairakite 0.40 -3.54 -3.94 -0.232 0.78314E+04
197 arsenic -6.02 -10.30 -4.27 -1.103 0.84978E+04
199 arsenopyrite -13.80 -18.71 -4.91 -0.873 0.97590E+04
200 beidellite-Ca -4.89 -7.77 -2.88 -0.178 0.57349E+04
201 beidellite-H -5.41 -8.81 -3.40 -0.217 0.67538E+04
202 beidellite-K -4.54 -7.65 -3.11 -0.190 0.61820E+04
203 beidellite-Mg -5.11 -7.95 -2.84 -0.176 0.56438E+04
204 beidellite-Na -4.43 -7.17 -2.74 -0.168 0.54448E+04
207 chalcedony -2.36 -2.63 -0.27 -0.090 0.53829E+03
208 chalcocite -23.78 -24.96 -1.18 -0.294 0.23366E+04
210 covellite -17.30 -18.77 -1.47 -0.558 0.29125E+04
211 dawsonite 0.50 -1.82 -2.32 -0.290 0.46193E+04
213 montmorillonite-Ca -4.48 -7.17 -2.69 -0.166 0.53444E+04
214 montmorillonite-K -4.22 -7.05 -2.82 -0.173 0.56112E+04
215 montmorillonite-Mg -4.70 -7.35 -2.64 -0.163 0.52536E+04
216 montmorillonite-Na -4.05 -6.57 -2.52 -0.154 0.50003E+04
217 nontronite-Ca 1.61 -3.10 -4.70 -0.305 0.93524E+04
219 nontronite-K 1.96 -2.97 -4.93 -0.316 0.97981E+04
220 nontronite-Mg 1.42 -3.27 -4.69 -0.304 0.93221E+04
221 nontronite-Na 2.06 -2.50 -4.56 -0.293 0.90646E+04
229 gypsum -5.32 -9.23 -3.91 -0.977 0.77663E+04
245 acanthite -23.78 -23.94 -0.16 -0.039 0.31340E+03
251 barite -9.42 -12.00 -2.58 -1.292 0.51373E+04
252 boehmite 2.18 0.37 -1.82 -0.303 0.36163E+04
253 cerussite -2.74 -6.22 -3.48 -1.161 0.69248E+04
254 chalcopyrite -25.72 -27.18 -1.46 -0.272 0.29055E+04
256 copper,native -2.03 -6.19 -4.16 -1.448 0.82727E+04
257 dolomite,disordered -0.38 -2.79 -2.42 -0.403 0.48029E+04
258 ferrous-oxide 7.82 3.20 -4.62 -1.155 0.91880E+04
259 fluorite -9.97 -10.65 -0.68 -0.227 0.13513E+04
261 gold,native -15.04 -16.37 -1.33 -0.464 0.26512E+04
262 silver,native -4.99 -5.68 -0.69 -0.240 0.13698E+04
269 silica-amorphous -1.78 -2.63 -0.86 -0.285 0.16998E+04
270 smithsonite -1.42 -5.33 -3.91 -1.302 0.77657E+04
273 wurtzite -8.22 -9.79 -1.57 -0.524 0.31274E+04
274 zincite 6.53 1.81 -4.72 -1.179 0.93756E+04
275 an20ab80 0.08 -1.70 -1.77 -0.136 0.35268E+04
276 an25ab75 0.49 -1.48 -1.97 -0.152 0.39203E+04
277 an30ab70 0.91 -1.27 -2.18 -0.167 0.43260E+04
Calculations done for 161.2823 Deg. C; 500.0000 bar
Mixer fraction: 0.3000000
Temperature Stoc.ionic strength Heat per mole
Actual solution: 161.282 .13406E+01 3.063
Mixing solution: 25.000 .50000E-10 0.646
Fract. of mixing solution added: 0.050000
BITMOL = 0.2775E+01 OLDMOL = 0.7371E+02
New heat: 2.975 New temperature: 156.426
New mixer fraction: 0.3500000
Resulting temperature: 156.426Deg. C
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1296E-03
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 7 Loop limit = 70
Temperature = 156.43 C Pressure = 500.00 bar Mixer fraction = 0.3500000
Water: Moles liquid = 0.7507E+02 kg liquid = 0.1352E+01
Moles total = 0.7475E+02 kg total = 0.1347E+01 Activity = 0.9627
Stoichiometric ionic strength = .1290834E+01 Osmotic coef. = 0.9244
True ionic strength = .9993539E+00
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.11692E-04 -4.9321 0.64303E-05 -5.1918 0.54996E+00 -0.2597
2 H2O 0.96265E+00 -0.0165 0.96265E+00 -0.0165
3 Cl- 0.97711E+00 -0.0101 0.55319E+00 -0.2571 0.56615E+00 -0.2471
4 SO4-- 0.12823E-03 -3.8920 0.93685E-05 -5.0283 0.73061E-01 -1.1363
5 HCO3- 0.19645E-01 -1.7068 0.11365E-01 -1.9444 0.57852E+00 -0.2377
6 HS- 0.62711E-06 -6.2027 0.35584E-06 -6.4487 0.56743E+00 -0.2461
7 H4SiO4 0.20735E-02 -2.6833 0.20735E-02 -2.6833 0.10000E+01 0.0000
8 Al+++ 0.34800E-12 -12.4584 0.82109E-15 -15.0856 0.23595E-02 -2.6272
9 Ca++ 0.11104E-02 -2.9545 0.73871E-04 -4.1315 0.66524E-01 -1.1770
10 Mg++ 0.99177E-04 -4.0036 0.62033E-05 -5.2074 0.62548E-01 -1.2038
11 Fe++ 0.94681E-06 -6.0237 0.60117E-07 -7.2210 0.63495E-01 -1.1973
12 K+ 0.33077E-01 -1.4805 0.19200E-01 -1.7167 0.58046E+00 -0.2362
13 Na+ 0.96195E+00 -0.0168 0.54323E+00 -0.2650 0.56472E+00 -0.2482
14 Mn++ 0.92693E-05 -5.0330 0.59520E-06 -6.2253 0.64212E-01 -1.1924
15 Zn++ 0.43757E-07 -7.3590 0.27783E-08 -8.5562 0.63495E-01 -1.1973
16 Cu+ 0.18343E-11 -11.7365 0.10350E-11 -11.9850 0.56428E+00 -0.2485
17 Pb++ 0.44673E-08 -8.3500 0.30887E-09 -9.5102 0.69139E-01 -1.1603
18 Ag+ 0.56795E-11 -11.2457 0.32795E-11 -11.4842 0.57742E+00 -0.2385
19 Au+ 0.10723E-21 -21.9697 0.62430E-22 -22.2046 0.58219E+00 -0.2349
20 Ba++ 0.16677E-05 -5.7779 0.11826E-06 -6.9272 0.70912E-01 -1.1493
21 F- 0.10140E-02 -2.9940 0.55416E-03 -3.2564 0.54651E+00 -0.2624
22 H2AsO3- 0.33555E-06 -6.4742 0.22920E-06 -6.6398 0.68308E+00 -0.1655
24 HSiO3- 0.12598E-05 -5.8997 0.71323E-06 -6.1468 0.56615E+00 -0.2471
25 Ca(HSiO3)+ 0.48791E-08 -8.3117 0.28406E-08 -8.5466 0.58219E+00 -0.2349
26 Mg(HSiO3)+ 0.40319E-09 -9.3945 0.23473E-09 -9.6294 0.58219E+00 -0.2349
27 NaHSiO3,aq 0.34285E-05 -5.4649 0.34285E-05 -5.4649 0.10000E+01 0.0000
31 AgCl,aq 0.99261E-09 -9.0032 0.99261E-09 -9.0032 0.10000E+01 0.0000
32 AgCl2- 0.38239E-07 -7.4175 0.21649E-07 -7.6646 0.56615E+00 -0.2471
33 AgCl3-2 0.19239E-07 -7.7158 0.13693E-08 -8.8635 0.71175E-01 -1.1477
34 AgCl4-3 0.19381E-08 -8.7126 0.46404E-11 -11.3334 0.23943E-02 -2.6208
38 Ag(HS),aq 0.60586E-08 -8.2176 0.60586E-08 -8.2176 0.10000E+01 0.0000
40 AlO+ 0.17433E-09 -9.7586 0.10149E-09 -9.9936 0.58219E+00 -0.2349
41 AlOH+2 0.10339E-10 -10.9855 0.67265E-12 -12.1722 0.65057E-01 -1.1867
42 HAlO2,aq 0.14367E-07 -7.8426 0.14367E-07 -7.8426 0.10000E+01 0.0000
43 AlO2- 0.39838E-07 -7.3997 0.21879E-07 -7.6600 0.54921E+00 -0.2603
44 AsO2- 0.91057E-07 -7.0407 0.51552E-07 -7.2878 0.56615E+00 -0.2471
45 HAsO2,aq 0.29758E-04 -4.5264 0.29758E-04 -4.5264 0.10000E+01 0.0000
46 H3AsO3,aq 0.65675E-04 -4.1826 0.65675E-04 -4.1826 0.10000E+01 0.0000
48 H2AsO4- 0.37073E-10 -10.4309 0.20989E-10 -10.6780 0.56615E+00 -0.2471
62 BaCO3,aq 0.23459E-09 -9.6297 0.23459E-09 -9.6297 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.75568E-06 -6.1217 0.44609E-06 -6.3506 0.59031E+00 -0.2289
64 BaCl+ 0.58099E-06 -6.2358 0.33825E-06 -6.4708 0.58219E+00 -0.2349
65 BaF+ 0.71137E-09 -9.1479 0.41415E-09 -9.3828 0.58219E+00 -0.2349
66 CH4,aq 0.46356E-09 -9.3339 0.41877E-09 -9.3780 0.90338E+00 -0.0441
71 CO,aq 0.39728E-09 -9.4009 0.39728E-09 -9.4009 0.10000E+01 0.0000
72 CO2,aq 0.23899E+00 -0.6216 0.21590E+00 -0.6657 0.90338E+00 -0.0441
73 CO3-2 0.26241E-05 -5.5810 0.18677E-06 -6.7287 0.71175E-01 -1.1477
74 CaCO3,aq 0.58846E-06 -6.2303 0.58846E-06 -6.2303 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.97850E-04 -4.0094 0.56967E-04 -4.2444 0.58219E+00 -0.2349
76 CaCl+ 0.32148E-03 -3.4929 0.18716E-03 -3.7278 0.58219E+00 -0.2349
77 CaCl2,aq 0.22820E-04 -4.6417 0.22820E-04 -4.6417 0.10000E+01 0.0000
78 CaF+ 0.29925E-05 -5.5240 0.17422E-05 -5.7589 0.58219E+00 -0.2349
79 CaOH+ 0.29396E-07 -7.5317 0.17114E-07 -7.7666 0.58219E+00 -0.2349
80 CaSO4,aq 0.47104E-06 -6.3269 0.47104E-06 -6.3269 0.10000E+01 0.0000
81 HCl,aq 0.13401E-05 -5.8729 0.13401E-05 -5.8729 0.10000E+01 0.0000
90 CuCl,aq 0.26686E-08 -8.5737 0.26686E-08 -8.5737 0.10000E+01 0.0000
91 CuCl2- 0.42011E-07 -7.3766 0.23784E-07 -7.6237 0.56615E+00 -0.2471
92 CuCl3-2 0.72738E-08 -8.1382 0.51771E-09 -9.2859 0.71175E-01 -1.1477
98 HF,aq 0.65005E-04 -4.1871 0.65005E-04 -4.1871 0.10000E+01 0.0000
99 HF2- 0.18596E-07 -7.7306 0.10528E-07 -7.9776 0.56615E+00 -0.2471
101 FeCl+ 0.21266E-06 -6.6723 0.12381E-06 -6.9073 0.58219E+00 -0.2349
102 FeCl2,aq 0.18360E-09 -9.7361 0.18360E-09 -9.7361 0.10000E+01 0.0000
104 FeF+ 0.59326E-08 -8.2268 0.34539E-08 -8.4617 0.58219E+00 -0.2349
107 FeOH+ 0.51643E-08 -8.2870 0.30066E-08 -8.5219 0.58219E+00 -0.2349
113 H2,aq 0.46263E-07 -7.3348 0.41793E-07 -7.3789 0.90338E+00 -0.0441
114 KCl,aq 0.52396E-03 -3.2807 0.52396E-03 -3.2807 0.10000E+01 0.0000
115 KHSO4,aq 0.63657E-10 -10.1962 0.63657E-10 -10.1962 0.10000E+01 0.0000
116 KOH,aq 0.11734E-07 -7.9305 0.11734E-07 -7.9305 0.10000E+01 0.0000
117 KSO4- 0.10329E-04 -4.9859 0.58480E-05 -5.2330 0.56615E+00 -0.2471
118 MgCO3,aq 0.83215E-08 -8.0798 0.83215E-08 -8.0798 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.81660E-05 -5.0880 0.47541E-05 -5.3229 0.58219E+00 -0.2349
120 MgCl+ 0.18841E-04 -4.7249 0.10969E-04 -4.9598 0.58219E+00 -0.2349
121 MgF+ 0.81112E-06 -6.0909 0.47222E-06 -6.3259 0.58219E+00 -0.2349
122 MgOH+ 0.98209E-08 -8.0078 0.57176E-08 -8.2428 0.58219E+00 -0.2349
124 MnF+ 0.21626E-07 -7.6650 0.12591E-07 -7.9000 0.58219E+00 -0.2349
126 MnOH+ 0.60839E-08 -8.2158 0.35420E-08 -8.4508 0.58219E+00 -0.2349
131 MnCl+ 0.16192E-04 -4.7907 0.94269E-05 -5.0256 0.58219E+00 -0.2349
132 MnSO4,aq 0.41200E-08 -8.3851 0.41200E-08 -8.3851 0.10000E+01 0.0000
133 NaCl,aq 0.16467E+00 -0.7834 0.16467E+00 -0.7834 0.10000E+01 0.0000
134 NaF,aq 0.12097E-03 -3.9173 0.12097E-03 -3.9173 0.10000E+01 0.0000
135 NaOH,aq 0.27053E-06 -6.5678 0.27053E-06 -6.5678 0.10000E+01 0.0000
137 OH- 0.10840E-05 -5.9650 0.59535E-06 -6.2252 0.54921E+00 -0.2603
140 PbCl+ 0.40088E-07 -7.3970 0.23339E-07 -7.6319 0.58219E+00 -0.2349
141 PbCl2,aq 0.12341E-06 -6.9086 0.12341E-06 -6.9086 0.10000E+01 0.0000
142 PbCl3- 0.70815E-07 -7.1499 0.40092E-07 -7.3969 0.56615E+00 -0.2471
143 PbCl4-2 0.70667E-07 -7.1508 0.50297E-08 -8.2985 0.71175E-01 -1.1477
144 PbF+ 0.68325E-10 -10.1654 0.39778E-10 -10.4004 0.58219E+00 -0.2349
148 Pb(HS)2,aq 0.67657E-10 -10.1697 0.67657E-10 -10.1697 0.10000E+01 0.0000
150 H2S,aq 0.70005E-05 -5.1549 0.63241E-05 -5.1990 0.90338E+00 -0.0441
158 HSO3- 0.61462E-10 -10.2114 0.34797E-10 -10.4585 0.56615E+00 -0.2471
159 HSO4- 0.46207E-06 -6.3353 0.27258E-06 -6.5645 0.58992E+00 -0.2292
161 S2O3-2 0.12105E-10 -10.9170 0.86161E-12 -12.0647 0.71175E-01 -1.1477
173 ZnCl+ 0.29895E-05 -5.5244 0.17404E-05 -5.7593 0.58219E+00 -0.2349
174 ZnCl2,aq 0.62316E-06 -6.2054 0.62316E-06 -6.2054 0.10000E+01 0.0000
175 ZnCl3- 0.73879E-07 -7.1315 0.41827E-07 -7.3785 0.56615E+00 -0.2471
176 ZnF+ 0.17883E-09 -9.7476 0.10411E-09 -9.9825 0.58219E+00 -0.2349
177 ZnO,aq 0.48147E-10 -10.3174 0.48147E-10 -10.3174 0.10000E+01 0.0000
178 ZnOH+ 0.92753E-07 -7.0327 0.54000E-07 -7.2676 0.58219E+00 -0.2349
Charge balance for all species = -.9584E-04
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.1169227E-04 0.2391637E+00 0.2232543E+03 0.0000
2 H2O 0.1000000E+01 0.5526922E+02 0.9221355E+06 0.0000
3 Cl- 0.9771142E+00 0.1142715E+01 0.3751982E+05 4.9346
4 SO4-- 0.1282290E-03 0.1394836E-03 0.1240918E+02 5.3552
5 HCO3- 0.1964475E-01 0.2587472E+00 0.1462170E+05 3.2473
6 HS- 0.6271142E-06 0.7645955E-05 0.2341866E+00 -1.2570
7 H4SiO4 0.2073529E-02 0.2078222E-02 0.1849928E+03 -2.6833
8 Al+++ 0.3479956E-12 0.5438999E-07 0.1359111E-02 0.4897
9 Ca++ 0.1110432E-02 0.1556665E-02 0.5777913E+02 6.2520
10 Mg++ 0.9917720E-04 0.1270136E-03 0.2859834E+01 5.1762
11 Fe++ 0.9468070E-06 0.1170759E-05 0.6055320E-01 3.1625
12 K+ 0.3307730E-01 0.3361160E-01 0.1217189E+04 3.4751
13 Na+ 0.9619503E+00 0.1126742E+01 0.2398996E+05 4.9268
14 Mn++ 0.9269303E-05 0.2549341E-04 0.1297092E+01 4.1582
15 Zn++ 0.4375717E-07 0.3823272E-05 0.2314641E+00 1.8273
16 Cu+ 0.1834266E-11 0.5195513E-07 0.3057352E-02 -6.7933
17 Pb++ 0.4467327E-08 0.3095911E-06 0.5940557E-01 0.8733
18 Ag+ 0.5679490E-11 0.6647457E-07 0.6640887E-02 -6.2924
19 Au+ 0.1072329E-21 0.2300337E-11 0.4196186E-06 -17.0128
20 Ba++ 0.1667722E-05 0.3005338E-05 0.3822612E+00 3.4564
21 F- 0.1013996E-02 0.1203841E-02 0.2118101E+02 1.9354
22 H2AsO3- 0.3355463E-06 0.9585967E-04 0.1109155E+02 -1.4480
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234435E+00 -.8337436E-05 0.0000000E+00
2 H2O 0.7474574E+02 0.7474574E+02 -.9989335E-08 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886368E-03 0.2497334E-08 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.1034034E-04 0.3689970E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810574E-02 0.1166861E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.7355668E-07 0.2333722E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1583326E-05 0.1997867E-07 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.5170569E-05 0.2297607E-05 0.0000000E+00
16 Cu+ 0.1701571E-06 0.7026377E-07 0.9989335E-07 0.0000000E+00
17 Pb++ 0.1565021E-05 0.4186890E-06 0.1146332E-05 0.0000000E+00
18 Ag+ 0.4271281E-06 0.8989977E-07 0.3372283E-06 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1628066E-02 0.2333722E-05 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.146027E+04 g
Temperature = 156.43 C Pressure = 500.00 bar Mixer frac. = 0.3500000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
argentite 0.1686E-06 -6.773 0.4178E-04 -4.379 5.464 0.5868E-05
bornite 0.1998E-07 -7.699 0.1003E-04 -4.999 1.311 0.1972E-05
topaz 0.1167E-05 -5.933 0.2148E-03 -3.668 28.08 0.6012E-04
galena 0.1146E-05 -5.941 0.2743E-03 -3.562 35.87 0.3610E-04
sphalerite 0.2298E-05 -5.639 0.2239E-03 -3.650 29.27 0.5475E-04
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
argentite 0.1000E+01 0.1000E+01 1.0000 0.000
bornite 0.1000E+01 0.1000E+01 1.0000 0.000
topaz 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.3500000
Solid products produced: Mass = 0.000765 g Volume = 0.000159 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.400
AFFINITY: 0.3330E+03
GOLD Q/K: 0.0534
SILVER Q/K: 0.1892
Gas composition at saturation ( 4 iterations)
-------------------------------------------------
Temperature: 156.4257 deg.C
Sat. pressure: 67.0225 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.1394E+00 0.7125 0.6655E+01 0.9340E+01
CO2,gas 0.8606E+00 0.9015 0.5200E+02 0.5768E+02
CH4,gas 0.1260E-07 1.0749 0.9076E-06 0.8444E-06
H2,gas 0.8186E-06 1.0316 0.5660E-04 0.5487E-04
H2S,gas 0.6309E-05 0.8449 0.3572E-03 0.4228E-03
S2,gas 0.3158E-16 1.0000 0.2116E-14 0.2116E-14
CO,gas 0.9872E-08 1.0000 0.6617E-06 0.6617E-06
SO3,gas 0.1334E-27 1.0000 0.8943E-26 0.8943E-26
O2,gas 0.1678E-45 1.0000 0.1125E-43 0.1125E-43
SO2,gas 0.1010E-12 1.0000 0.6771E-11 0.6771E-11
HF,gas 0.1931E-07 1.0000 0.1294E-05 0.1294E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
196 argentite -24.23 -24.23 0.00 0.000 -0.69835E-11
205 bornite -77.83 -77.83 0.00 0.000 -0.27934E-10
225 topaz -18.60 -18.60 0.00 0.000 0.69835E-11
260 galena -10.77 -10.77 0.00 0.000 0.00000E+00
272 sphalerite -9.81 -9.81 0.00 0.000 0.34917E-11
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.86 -0.02 -1.88 -1.876 0.36873E+04 0.823
2 CO2,gas -6.14 -7.12 -0.98 -0.328 0.19322E+04 1.716
3 CH4,gas 5.36 -3.38 -8.74 -2.185 0.17182E+05 -6.042
4 H2,gas 7.87 0.93 -6.95 -3.969 0.13654E+05 -4.247
5 H2S,gas -5.49 -11.64 -6.15 -3.073 0.12081E+05 -3.447
6 S2,gas -7.76 -25.13 -17.37 -2.673 0.34150E+05 -14.674
7 CO,gas 2.70 -6.18 -8.88 -2.732 0.17452E+05 -6.179
8 SO3,gas 13.35 -15.40 -28.75 -7.187 0.56508E+05 -26.048
9 O2,gas 44.76 -1.89 -46.65 -31.099 0.91694E+05 -43.949
10 SO2,gas -0.58 -14.45 -13.87 -3.698 0.27261E+05 -11.169
11 HF,gas 0.14 -8.45 -8.59 -4.294 0.16879E+05 -5.888
12 HCl,gas 1.78 -5.45 -7.23 -3.616 0.14214E+05 -7.231
13 acmite 6.70 2.29 -4.41 -0.458 0.86672E+04
17 albite-high -0.55 -2.57 -2.02 -0.155 0.39720E+04
18 albite -1.37 -2.57 -1.20 -0.092 0.23561E+04
22 analcite 1.89 0.07 -1.82 -0.203 0.35830E+04
23 andalusite 1.26 -1.72 -2.98 -0.298 0.58621E+04
26 anhydrite -6.00 -9.16 -3.16 -1.581 0.62136E+04
27 ankerite -3.12 -4.86 -1.74 -0.289 0.34126E+04
34 aragonite 0.39 -0.88 -1.27 -0.424 0.25004E+04
36 calcite 0.25 -0.88 -1.13 -0.378 0.22270E+04
37 carnegieite-low 6.75 2.73 -4.02 -0.574 0.79016E+04
38 carnegieite-high 7.58 2.73 -4.84 -0.692 0.95233E+04
39 carpholite-Mg 4.50 0.76 -3.75 -0.250 0.73672E+04
40 carpholite-Fe 2.86 -1.26 -4.12 -0.274 0.80902E+04
49 chloritoid-Mg 8.20 3.42 -4.77 -0.318 0.93841E+04
50 chloritoid-Fe 4.75 1.41 -3.34 -0.223 0.65665E+04
51 chloritoid-Mn 6.95 2.40 -4.54 -0.303 0.89261E+04
53 coesite -2.02 -2.65 -0.63 -0.210 0.12406E+04
58 corundum 4.14 0.93 -3.21 -0.292 0.63067E+04
60 cristobalite -2.20 -2.65 -0.45 -0.151 0.89002E+03
63 cymrite-K 0.60 -4.04 -4.63 -0.386 0.91093E+04
65 diaspore 1.12 0.46 -0.67 -0.111 0.13104E+04
66 diamond -2.48 -5.23 -2.76 -0.787 0.54164E+04
69 dolomite,ordered -0.76 -2.84 -2.08 -0.347 0.40937E+04
83 gibbsite 2.34 0.44 -1.89 -0.271 0.37248E+04
86 goethite 5.20 2.67 -2.54 -0.548 0.49849E+04
87 graphite -2.88 -5.23 -2.35 -0.672 0.46259E+04
90 halite 1.51 -0.52 -2.03 -1.014 0.39854E+04
91 hematite 9.92 5.35 -4.57 -0.554 0.89857E+04
92 heulandite -7.52 -11.49 -3.97 -0.180 0.78025E+04
96 jadeite 2.70 0.08 -2.62 -0.262 0.51513E+04
98 kalsilite 5.58 1.28 -4.30 -0.614 0.84483E+04
99 kaolinite -3.60 -4.40 -0.80 -0.073 0.15723E+04
100 kyanite 1.18 -1.72 -2.90 -0.290 0.56945E+04
102 laumontite 0.14 -3.50 -3.64 -0.243 0.71525E+04
103 lawsonite 5.81 1.83 -3.98 -0.265 0.78153E+04
104 leucite 2.51 -1.37 -3.88 -0.388 0.76218E+04
107 magnesite -0.19 -1.96 -1.77 -0.590 0.34763E+04
117 microcline -3.03 -4.02 -0.99 -0.076 0.19508E+04
120 mullite-Si 3.16 -1.72 -4.88 -0.488 0.95891E+04
121 muscovite -1.48 -3.11 -1.63 -0.096 0.32009E+04
122 paragonite -0.15 -1.65 -1.50 -0.088 0.29514E+04
123 nepheline 6.13 2.73 -3.40 -0.485 0.66743E+04
143 pyrite -19.76 -21.04 -1.29 -0.303 0.25342E+04
144 pyrrhotite -4.60 -8.48 -3.88 -1.293 0.76255E+04
145 pyrrhotiteFe0.875 -6.08 -8.99 -2.91 -1.069 0.57131E+04
146 pyroxmangite 6.20 1.49 -4.71 -0.942 0.92547E+04
147 pyrophyllite -7.97 -9.69 -1.71 -0.107 0.33687E+04
148 quartz -2.55 -2.65 -0.10 -0.033 0.19452E+03
153 rhodochrosite -1.40 -2.98 -1.57 -0.525 0.30956E+04
154 rhodonite 6.23 1.49 -4.74 -0.948 0.93207E+04
155 sanidine -1.97 -4.02 -2.04 -0.157 0.40188E+04
157 siderite -3.06 -3.97 -0.92 -0.305 0.17994E+04
158 sillimanite 1.46 -1.72 -3.18 -0.318 0.62510E+04
165 stilbite -7.99 -11.50 -3.51 -0.167 0.69014E+04
171 sulfur -8.61 -12.57 -3.95 -1.216 0.77712E+04
172 sylvite 1.45 -1.97 -3.43 -1.713 0.67354E+04
180 topaz-H 1.33 -1.74 -3.07 -0.279 0.60336E+04
181 tridymite -2.24 -2.65 -0.41 -0.138 0.81334E+03
184 troilite-low -4.69 -8.48 -3.79 -1.262 0.74426E+04
190 wairakite 0.71 -3.47 -4.18 -0.246 0.82179E+04
197 arsenic -6.11 -10.39 -4.29 -1.106 0.84257E+04
200 beidellite-Ca -4.61 -7.63 -3.02 -0.187 0.59359E+04
201 beidellite-H -5.15 -8.66 -3.51 -0.224 0.69056E+04
202 beidellite-K -4.28 -7.52 -3.24 -0.198 0.63607E+04
203 beidellite-Mg -4.83 -7.81 -2.98 -0.184 0.58523E+04
204 beidellite-Na -4.17 -7.04 -2.87 -0.176 0.56373E+04
207 chalcedony -2.39 -2.65 -0.26 -0.087 0.51412E+03
208 chalcocite -24.05 -25.23 -1.18 -0.295 0.23166E+04
210 covellite -17.47 -18.90 -1.43 -0.545 0.28115E+04
211 dawsonite 0.60 -1.75 -2.35 -0.294 0.46238E+04
213 montmorillonite-Ca -4.29 -7.11 -2.82 -0.175 0.55520E+04
214 montmorillonite-K -4.04 -6.99 -2.95 -0.181 0.58015E+04
215 montmorillonite-Mg -4.51 -7.29 -2.78 -0.172 0.54675E+04
216 montmorillonite-Na -3.87 -6.52 -2.64 -0.162 0.51991E+04
217 nontronite-Ca 1.76 -3.21 -4.97 -0.322 0.97634E+04
220 nontronite-Mg 1.57 -3.39 -4.96 -0.321 0.97402E+04
221 nontronite-Na 2.20 -2.62 -4.82 -0.309 0.94669E+04
229 gypsum -5.27 -9.19 -3.93 -0.982 0.77183E+04
245 acanthite -24.07 -24.23 -0.15 -0.038 0.30018E+03
251 barite -9.38 -11.96 -2.57 -1.285 0.50536E+04
252 boehmite 2.35 0.46 -1.90 -0.316 0.37288E+04
253 cerussite -2.73 -6.26 -3.53 -1.178 0.69483E+04
254 chalcopyrite -25.88 -27.37 -1.49 -0.278 0.29365E+04
256 copper,native -2.10 -6.33 -4.23 -1.472 0.83176E+04
257 dolomite,disordered -0.23 -2.84 -2.61 -0.436 0.51389E+04
258 ferrous-oxide 7.96 3.15 -4.82 -1.204 0.94678E+04
259 fluorite -9.94 -10.64 -0.71 -0.236 0.13896E+04
261 gold,native -15.28 -16.55 -1.27 -0.443 0.25010E+04
262 silver,native -5.11 -5.83 -0.72 -0.251 0.14212E+04
269 silica-amorphous -1.79 -2.65 -0.86 -0.286 0.16848E+04
270 smithsonite -1.36 -5.31 -3.95 -1.317 0.77690E+04
273 wurtzite -8.22 -9.81 -1.59 -0.530 0.31282E+04
274 zincite 6.65 1.81 -4.84 -1.209 0.95084E+04
275 an20ab80 0.24 -1.68 -1.93 -0.148 0.37852E+04
276 an25ab75 0.68 -1.46 -2.13 -0.164 0.41955E+04
277 an30ab70 1.11 -1.24 -2.35 -0.181 0.46177E+04
Calculations done for 156.4257 Deg. C; 500.0000 bar
Mixer fraction: 0.3500000
Temperature Stoc.ionic strength Heat per mole
Actual solution: 156.426 .12908E+01 2.975
Mixing solution: 25.000 .50000E-10 0.646
Fract. of mixing solution added: 0.050000
BITMOL = 0.2775E+01 OLDMOL = 0.7648E+02
New heat: 2.894 New temperature: 151.902
New mixer fraction: 0.4000000
Resulting temperature: 151.902Deg. C
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1296E-03
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 7 Loop limit = 70
Temperature = 151.90 C Pressure = 500.00 bar Mixer fraction = 0.4000000
Water: Moles liquid = 0.7784E+02 kg liquid = 0.1402E+01
Moles total = 0.7752E+02 kg total = 0.1397E+01 Activity = 0.9639
Stoichiometric ionic strength = .1244619E+01 Osmotic coef. = 0.9259
True ionic strength = .9718891E+00
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.12371E-04 -4.9076 0.69089E-05 -5.1606 0.55848E+00 -0.2530
2 H2O 0.96390E+00 -0.0160 0.96390E+00 -0.0160
3 Cl- 0.95041E+00 -0.0221 0.54364E+00 -0.2647 0.57200E+00 -0.2426
4 SO4-- 0.12407E-03 -3.9063 0.96213E-05 -5.0168 0.77548E-01 -1.1104
5 HCO3- 0.18951E-01 -1.7224 0.11056E-01 -1.9564 0.58339E+00 -0.2340
6 HS- 0.55595E-06 -6.2550 0.31865E-06 -6.4967 0.57317E+00 -0.2417
7 H4SiO4 0.20000E-02 -2.6990 0.20000E-02 -2.6990 0.10000E+01 0.0000
8 Al+++ 0.45595E-12 -12.3411 0.12438E-14 -14.9053 0.27279E-02 -2.5642
9 Ca++ 0.10899E-02 -2.9626 0.77289E-04 -4.1119 0.70916E-01 -1.1493
10 Mg++ 0.96524E-04 -4.0154 0.64663E-05 -5.1893 0.66991E-01 -1.1740
11 Fe++ 0.91938E-06 -6.0365 0.62446E-07 -7.2045 0.67922E-01 -1.1680
12 K+ 0.31947E-01 -1.4956 0.18686E-01 -1.7285 0.58492E+00 -0.2329
13 Na+ 0.93573E+00 -0.0289 0.53364E+00 -0.2728 0.57029E+00 -0.2439
14 Mn++ 0.94816E-05 -5.0231 0.65072E-06 -6.1866 0.68630E-01 -1.1635
15 Zn++ 0.46952E-07 -7.3283 0.31891E-08 -8.4963 0.67922E-01 -1.1680
16 Cu+ 0.14773E-11 -11.8305 0.84187E-12 -12.0748 0.56988E+00 -0.2442
17 Pb++ 0.42253E-08 -8.3741 0.31062E-09 -9.5078 0.73513E-01 -1.1336
18 Ag+ 0.45075E-11 -11.3461 0.26237E-11 -11.5811 0.58208E+00 -0.2350
19 Au+ 0.79682E-22 -22.0986 0.46737E-22 -22.3303 0.58654E+00 -0.2317
20 Ba++ 0.16770E-05 -5.7755 0.12624E-06 -6.8988 0.75279E-01 -1.1233
21 F- 0.98448E-03 -3.0068 0.54605E-03 -3.2628 0.55466E+00 -0.2560
22 H2AsO3- 0.27424E-06 -6.5619 0.18731E-06 -6.7274 0.68301E+00 -0.1656
24 HSiO3- 0.11038E-05 -5.9571 0.63140E-06 -6.1997 0.57200E+00 -0.2426
25 Ca(HSiO3)+ 0.41173E-08 -8.3854 0.24150E-08 -8.6171 0.58654E+00 -0.2317
26 Mg(HSiO3)+ 0.34505E-09 -9.4621 0.20239E-09 -9.6938 0.58654E+00 -0.2317
27 NaHSiO3,aq 0.30541E-05 -5.5151 0.30541E-05 -5.5151 0.10000E+01 0.0000
31 AgCl,aq 0.78379E-09 -9.1058 0.78379E-09 -9.1058 0.10000E+01 0.0000
32 AgCl2- 0.29276E-07 -7.5335 0.16746E-07 -7.7761 0.57200E+00 -0.2426
33 AgCl3-2 0.13993E-07 -7.8541 0.10590E-08 -8.9751 0.75677E-01 -1.1210
34 AgCl4-3 0.12937E-08 -8.8882 0.35994E-11 -11.4438 0.27823E-02 -2.5556
38 Ag(HS),aq 0.56971E-08 -8.2443 0.56971E-08 -8.2443 0.10000E+01 0.0000
40 AlO+ 0.17031E-09 -9.7688 0.99892E-10 -10.0005 0.58654E+00 -0.2317
41 AlOH+2 0.11404E-10 -10.9429 0.79216E-12 -12.1012 0.69464E-01 -1.1582
42 HAlO2,aq 0.11952E-07 -7.9226 0.11952E-07 -7.9226 0.10000E+01 0.0000
43 AlO2- 0.27389E-07 -7.5624 0.15254E-07 -7.8166 0.55694E+00 -0.2542
44 AsO2- 0.79836E-07 -7.0978 0.45667E-07 -7.3404 0.57200E+00 -0.2426
45 HAsO2,aq 0.29376E-04 -4.5320 0.29376E-04 -4.5320 0.10000E+01 0.0000
46 H3AsO3,aq 0.62711E-04 -4.2027 0.62711E-04 -4.2027 0.10000E+01 0.0000
48 H2AsO4- 0.30967E-10 -10.5091 0.17713E-10 -10.7517 0.57200E+00 -0.2426
62 BaCO3,aq 0.20910E-09 -9.6797 0.20910E-09 -9.6797 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.67814E-06 -6.1687 0.40294E-06 -6.3948 0.59419E+00 -0.2261
64 BaCl+ 0.54217E-06 -6.2659 0.31801E-06 -6.4976 0.58654E+00 -0.2317
65 BaF+ 0.67521E-09 -9.1706 0.39604E-09 -9.4023 0.58654E+00 -0.2317
66 CH4,aq 0.39239E-09 -9.4063 0.35425E-09 -9.4507 0.90281E+00 -0.0444
71 CO,aq 0.29464E-09 -9.5307 0.29464E-09 -9.5307 0.10000E+01 0.0000
72 CO2,aq 0.23047E+00 -0.6374 0.20807E+00 -0.6818 0.90281E+00 -0.0444
73 CO3-2 0.23244E-05 -5.6337 0.17590E-06 -6.7547 0.75677E-01 -1.1210
74 CaCO3,aq 0.51509E-06 -6.2881 0.51509E-06 -6.2881 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.89869E-04 -4.0464 0.52712E-04 -4.2781 0.58654E+00 -0.2317
76 CaCl+ 0.29720E-03 -3.5270 0.17432E-03 -3.7587 0.58654E+00 -0.2317
77 CaCl2,aq 0.20468E-04 -4.6889 0.20468E-04 -4.6889 0.10000E+01 0.0000
78 CaF+ 0.27643E-05 -5.5584 0.16214E-05 -5.7901 0.58654E+00 -0.2317
79 CaOH+ 0.22784E-07 -7.6424 0.13364E-07 -7.8741 0.58654E+00 -0.2317
80 CaSO4,aq 0.46663E-06 -6.3310 0.46663E-06 -6.3310 0.10000E+01 0.0000
81 HCl,aq 0.13405E-05 -5.8727 0.13405E-05 -5.8727 0.10000E+01 0.0000
90 CuCl,aq 0.21447E-08 -8.6686 0.21447E-08 -8.6686 0.10000E+01 0.0000
91 CuCl2- 0.32831E-07 -7.4837 0.18779E-07 -7.7263 0.57200E+00 -0.2426
92 CuCl3-2 0.54562E-08 -8.2631 0.41291E-09 -9.3841 0.75677E-01 -1.1210
98 HF,aq 0.62229E-04 -4.2060 0.62229E-04 -4.2060 0.10000E+01 0.0000
99 HF2- 0.17427E-07 -7.7588 0.99686E-08 -8.0014 0.57200E+00 -0.2426
101 FeCl+ 0.19772E-06 -6.7040 0.11597E-06 -6.9357 0.58654E+00 -0.2317
102 FeCl2,aq 0.12051E-09 -9.9190 0.12051E-09 -9.9190 0.10000E+01 0.0000
104 FeF+ 0.55955E-08 -8.2522 0.32820E-08 -8.4839 0.58654E+00 -0.2317
107 FeOH+ 0.42579E-08 -8.3708 0.24974E-08 -8.6025 0.58654E+00 -0.2317
113 H2,aq 0.36316E-07 -7.4399 0.32787E-07 -7.4843 0.90281E+00 -0.0444
114 KCl,aq 0.45686E-03 -3.3402 0.45686E-03 -3.3402 0.10000E+01 0.0000
115 KHSO4,aq 0.52099E-10 -10.2832 0.52099E-10 -10.2832 0.10000E+01 0.0000
116 KOH,aq 0.92836E-08 -8.0323 0.92836E-08 -8.0323 0.10000E+01 0.0000
117 KSO4- 0.95437E-05 -5.0203 0.54591E-05 -5.2629 0.57200E+00 -0.2426
118 MgCO3,aq 0.74551E-08 -8.1275 0.74551E-08 -8.1275 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.74929E-05 -5.1254 0.43949E-05 -5.3571 0.58654E+00 -0.2317
120 MgCl+ 0.17699E-04 -4.7521 0.10381E-04 -4.9838 0.58654E+00 -0.2317
121 MgF+ 0.75388E-06 -6.1227 0.44218E-06 -6.3544 0.58654E+00 -0.2317
122 MgOH+ 0.77346E-08 -8.1116 0.45367E-08 -8.3433 0.58654E+00 -0.2317
124 MnF+ 0.21258E-07 -7.6725 0.12469E-07 -7.9042 0.58654E+00 -0.2317
126 MnOH+ 0.51993E-08 -8.2841 0.30496E-08 -8.5158 0.58654E+00 -0.2317
131 MnCl+ 0.15072E-04 -4.8218 0.88405E-05 -5.0535 0.58654E+00 -0.2317
132 MnSO4,aq 0.42194E-08 -8.3747 0.42194E-08 -8.3747 0.10000E+01 0.0000
133 NaCl,aq 0.15073E+00 -0.8218 0.15073E+00 -0.8218 0.10000E+01 0.0000
134 NaF,aq 0.11061E-03 -3.9562 0.11061E-03 -3.9562 0.10000E+01 0.0000
135 NaOH,aq 0.21951E-06 -6.6586 0.21951E-06 -6.6586 0.10000E+01 0.0000
137 OH- 0.90252E-06 -6.0445 0.50265E-06 -6.2987 0.55694E+00 -0.2542
140 PbCl+ 0.36347E-07 -7.4395 0.21319E-07 -7.6712 0.58654E+00 -0.2317
141 PbCl2,aq 0.10544E-06 -6.9770 0.10544E-06 -6.9770 0.10000E+01 0.0000
142 PbCl3- 0.57539E-07 -7.2400 0.32913E-07 -7.4826 0.57200E+00 -0.2426
143 PbCl4-2 0.54173E-07 -7.2662 0.40997E-08 -8.3873 0.75677E-01 -1.1210
144 PbF+ 0.63555E-10 -10.1969 0.37278E-10 -10.4286 0.58654E+00 -0.2317
148 Pb(HS)2,aq 0.57471E-10 -10.2406 0.57471E-10 -10.2406 0.10000E+01 0.0000
150 H2S,aq 0.65361E-05 -5.1847 0.59008E-05 -5.2291 0.90281E+00 -0.0444
158 HSO3- 0.49680E-10 -10.3038 0.28417E-10 -10.5464 0.57200E+00 -0.2426
159 HSO4- 0.43646E-06 -6.3601 0.25928E-06 -6.5862 0.59404E+00 -0.2262
161 S2O3-2 0.10861E-10 -10.9641 0.82193E-12 -12.0852 0.75677E-01 -1.1210
173 ZnCl+ 0.27339E-05 -5.5632 0.16036E-05 -5.7949 0.58654E+00 -0.2317
174 ZnCl2,aq 0.55130E-06 -6.2586 0.55130E-06 -6.2586 0.10000E+01 0.0000
175 ZnCl3- 0.64069E-07 -7.1933 0.36648E-07 -7.4360 0.57200E+00 -0.2426
176 ZnF+ 0.18566E-09 -9.7313 0.10890E-09 -9.9630 0.58654E+00 -0.2317
177 ZnO,aq 0.35466E-10 -10.4502 0.35466E-10 -10.4502 0.10000E+01 0.0000
178 ZnOH+ 0.79285E-07 -7.1008 0.46504E-07 -7.3325 0.58654E+00 -0.2317
Charge balance for all species = -.9243E-04
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.1237103E-04 0.2306371E+00 0.2158634E+03 0.0000
2 H2O 0.1000000E+01 0.5527775E+02 0.9247134E+06 0.0000
3 Cl- 0.9504092E+00 0.1101973E+01 0.3627766E+05 4.8959
4 SO4-- 0.1240687E-03 0.1345103E-03 0.1199833E+02 5.3044
5 HCO3- 0.1895064E-01 0.2495220E+00 0.1413762E+05 3.2042
6 HS- 0.5559490E-06 0.7107400E-05 0.2182662E+00 -1.3361
7 H4SiO4 0.1999958E-02 0.2004120E-02 0.1788677E+03 -2.6990
8 Al+++ 0.4559524E-12 0.3952294E-07 0.9902176E-03 0.5765
9 Ca++ 0.1089859E-02 0.1501165E-02 0.5586627E+02 6.2093
10 Mg++ 0.9652422E-04 0.1224852E-03 0.2765155E+01 5.1318
11 Fe++ 0.9193818E-06 0.1127083E-05 0.5844820E-01 3.1167
12 K+ 0.3194682E-01 0.3241324E-01 0.1176892E+04 3.4321
13 Na+ 0.9357265E+00 0.1086570E+01 0.2319573E+05 4.8878
14 Mn++ 0.9481576E-05 0.2458449E-04 0.1254149E+01 4.1346
15 Zn++ 0.4695166E-07 0.3475735E-05 0.2109796E+00 1.8248
16 Cu+ 0.1477264E-11 0.4043324E-07 0.2385619E-02 -6.9142
17 Pb++ 0.4225304E-08 0.2578484E-06 0.4960764E-01 0.8134
18 Ag+ 0.4507489E-11 0.5104949E-07 0.5113372E-02 -6.4205
19 Au+ 0.7968237E-22 0.2218322E-11 0.4057265E-06 -17.1697
20 Ba++ 0.1676996E-05 0.2898188E-05 0.3696059E+00 3.4224
21 F- 0.9844833E-03 0.1160907E-02 0.2047956E+02 1.8978
22 H2AsO3- 0.2742362E-06 0.9244196E-04 0.1072435E+02 -1.5669
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234439E+00 -.8743953E-05 0.0000000E+00
2 H2O 0.7752115E+02 0.7752115E+02 -.1134538E-07 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886364E-03 0.2836345E-08 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.9967371E-05 0.4062939E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810565E-02 0.1175926E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.5542672E-07 0.2351852E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1580614E-05 0.2269076E-07 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.4874348E-05 0.2593829E-05 0.0000000E+00
16 Cu+ 0.1701571E-06 0.5670331E-07 0.1134538E-06 0.0000000E+00
17 Pb++ 0.1565021E-05 0.3616049E-06 0.1203416E-05 0.0000000E+00
18 Ag+ 0.4271281E-06 0.7159148E-07 0.3555366E-06 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1628048E-02 0.2351852E-05 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: -.1271E-20 Mass of aqueous solution: 0.151027E+04 g
Temperature = 151.90 C Pressure = 500.00 bar Mixer frac. = 0.4000000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
argentite 0.1778E-06 -6.750 0.4405E-04 -4.356 5.422 0.6186E-05
bornite 0.2269E-07 -7.644 0.1139E-04 -4.944 1.401 0.2240E-05
topaz 0.1176E-05 -5.930 0.2164E-03 -3.665 26.64 0.6059E-04
galena 0.1203E-05 -5.920 0.2879E-03 -3.541 35.44 0.3789E-04
sphalerite 0.2594E-05 -5.586 0.2527E-03 -3.597 31.10 0.6180E-04
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
argentite 0.1000E+01 0.1000E+01 1.0000 0.000
bornite 0.1000E+01 0.1000E+01 1.0000 0.000
topaz 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.4000000
Solid products produced: Mass = 0.000812 g Volume = 0.000169 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.400
AFFINITY: 0.3095E+03
GOLD Q/K: 0.0612
SILVER Q/K: 0.1758
Gas composition at saturation ( 3 iterations)
-------------------------------------------------
Temperature: 151.9018 deg.C
Sat. pressure: 63.6736 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.1293E+00 0.7219 0.5946E+01 0.8236E+01
CO2,gas 0.8706E+00 0.9018 0.4999E+02 0.5544E+02
CH4,gas 0.1165E-07 1.0692 0.7935E-06 0.7421E-06
H2,gas 0.7007E-06 1.0303 0.4597E-04 0.4462E-04
H2S,gas 0.6149E-05 0.8476 0.3319E-03 0.3915E-03
S2,gas 0.2601E-16 1.0000 0.1656E-14 0.1656E-14
CO,gas 0.8047E-08 1.0000 0.5124E-06 0.5124E-06
SO3,gas 0.7416E-28 1.0000 0.4722E-26 0.4722E-26
O2,gas 0.5000E-46 1.0000 0.3184E-44 0.3184E-44
SO2,gas 0.7846E-13 1.0000 0.4996E-11 0.4996E-11
HF,gas 0.1707E-07 1.0000 0.1087E-05 0.1087E-05
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
196 argentite -24.50 -24.50 0.00 0.000 0.69099E-11
205 bornite -78.54 -78.54 0.00 0.000 0.00000E+00
225 topaz -18.39 -18.39 0.00 0.000 0.69099E-11
260 galena -10.84 -10.84 0.00 0.000 -0.34550E-11
272 sphalerite -9.83 -9.83 0.00 0.000 0.69099E-11
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.91 -0.02 -1.92 -1.925 0.37436E+04 0.774
2 CO2,gas -6.10 -7.10 -1.00 -0.333 0.19451E+04 1.699
3 CH4,gas 5.35 -3.45 -8.80 -2.200 0.17115E+05 -6.100
4 H2,gas 7.94 0.90 -7.04 -4.021 0.13686E+05 -4.338
5 H2S,gas -5.48 -11.66 -6.18 -3.089 0.12016E+05 -3.479
6 S2,gas -7.64 -25.12 -17.48 -2.689 0.33998E+05 -14.781
7 CO,gas 2.81 -6.18 -8.99 -2.766 0.17484E+05 -6.290
8 SO3,gas 13.70 -15.32 -29.02 -7.256 0.56452E+05 -26.326
9 O2,gas 45.36 -1.84 -47.20 -31.464 0.91795E+05 -44.497
10 SO2,gas -0.40 -14.40 -14.00 -3.733 0.27230E+05 -11.301
11 HF,gas 0.24 -8.42 -8.66 -4.331 0.16849E+05 -5.964
12 HCl,gas 1.90 -5.43 -7.33 -3.663 0.14249E+05 -7.326
13 acmite 6.79 2.19 -4.60 -0.478 0.89462E+04
17 albite-high -0.43 -2.57 -2.14 -0.165 0.41642E+04
18 albite -1.27 -2.57 -1.30 -0.100 0.25300E+04
22 analcite 2.02 0.08 -1.93 -0.215 0.37634E+04
23 andalusite 1.57 -1.56 -3.13 -0.313 0.60844E+04
26 anhydrite -5.92 -9.13 -3.21 -1.606 0.62490E+04
27 ankerite -3.02 -4.91 -1.89 -0.315 0.36806E+04
34 aragonite 0.45 -0.91 -1.35 -0.451 0.26336E+04
36 calcite 0.31 -0.91 -1.22 -0.405 0.23632E+04
37 carnegieite-low 6.94 2.77 -4.17 -0.596 0.81143E+04
39 carpholite-Mg 4.83 0.85 -3.98 -0.265 0.77367E+04
40 carpholite-Fe 3.17 -1.16 -4.33 -0.289 0.84276E+04
50 chloritoid-Fe 5.10 1.52 -3.58 -0.239 0.69639E+04
51 chloritoid-Mn 7.30 2.54 -4.76 -0.317 0.92567E+04
53 coesite -2.04 -2.67 -0.63 -0.209 0.12168E+04
58 corundum 4.47 1.11 -3.37 -0.306 0.65510E+04
60 cristobalite -2.22 -2.67 -0.45 -0.150 0.87440E+03
63 cymrite-K 0.70 -4.04 -4.74 -0.395 0.92211E+04
65 diaspore 1.26 0.54 -0.72 -0.120 0.13952E+04
66 diamond -2.52 -5.26 -2.74 -0.782 0.53249E+04
69 dolomite,ordered -0.63 -2.89 -2.26 -0.376 0.43923E+04
83 gibbsite 2.47 0.53 -1.94 -0.277 0.37752E+04
86 goethite 5.30 2.63 -2.66 -0.576 0.51802E+04
87 graphite -2.93 -5.26 -2.33 -0.667 0.45389E+04
90 halite 1.52 -0.54 -2.06 -1.028 0.39989E+04
91 hematite 10.13 5.28 -4.85 -0.587 0.94261E+04
92 heulandite -7.33 -11.47 -4.14 -0.188 0.80437E+04
96 jadeite 2.83 0.10 -2.73 -0.273 0.53131E+04
98 kalsilite 5.74 1.31 -4.43 -0.633 0.86245E+04
99 kaolinite -3.41 -4.26 -0.85 -0.078 0.16596E+04
100 kyanite 1.47 -1.56 -3.04 -0.304 0.59066E+04
102 laumontite 0.38 -3.43 -3.82 -0.254 0.74247E+04
103 lawsonite 6.11 1.93 -4.18 -0.279 0.81337E+04
104 leucite 2.65 -1.36 -4.01 -0.401 0.77967E+04
107 magnesite -0.11 -1.99 -1.87 -0.624 0.36410E+04
117 microcline -2.96 -4.02 -1.07 -0.082 0.20767E+04
121 muscovite -1.13 -2.94 -1.81 -0.106 0.35114E+04
122 paragonite 0.22 -1.48 -1.70 -0.100 0.33005E+04
123 nepheline 6.31 2.77 -3.54 -0.506 0.68896E+04
143 pyrite -19.83 -21.10 -1.27 -0.299 0.24682E+04
144 pyrrhotite -4.56 -8.54 -3.98 -1.328 0.77461E+04
145 pyrrhotiteFe0.875 -6.06 -9.04 -2.98 -1.097 0.57993E+04
146 pyroxmangite 6.29 1.45 -4.84 -0.968 0.94166E+04
147 pyrophyllite -7.80 -9.58 -1.78 -0.111 0.34588E+04
148 quartz -2.58 -2.67 -0.09 -0.030 0.17239E+03
153 rhodochrosite -1.36 -2.98 -1.63 -0.542 0.31609E+04
154 rhodonite 6.33 1.45 -4.88 -0.975 0.94839E+04
155 sanidine -1.89 -4.02 -2.13 -0.164 0.41446E+04
157 siderite -3.01 -4.00 -0.99 -0.331 0.19285E+04
158 sillimanite 1.77 -1.56 -3.33 -0.333 0.64762E+04
165 stilbite -7.90 -11.48 -3.59 -0.171 0.69765E+04
171 sulfur -8.64 -12.56 -3.93 -1.208 0.76351E+04
172 sylvite 1.45 -1.99 -3.45 -1.724 0.67057E+04
180 topaz-H 1.60 -1.58 -3.17 -0.289 0.61742E+04
181 tridymite -2.26 -2.67 -0.41 -0.136 0.79583E+03
184 troilite-low -4.66 -8.54 -3.89 -1.295 0.75570E+04
190 wairakite 1.01 -3.40 -4.41 -0.259 0.85724E+04
197 arsenic -6.19 -10.48 -4.30 -1.109 0.83579E+04
200 beidellite-Ca -4.35 -7.49 -3.15 -0.195 0.61188E+04
201 beidellite-H -4.90 -8.52 -3.62 -0.231 0.70431E+04
202 beidellite-K -4.03 -7.39 -3.35 -0.205 0.65226E+04
203 beidellite-Mg -4.57 -7.67 -3.11 -0.192 0.60421E+04
204 beidellite-Na -3.92 -6.91 -2.99 -0.183 0.58123E+04
207 chalcedony -2.41 -2.67 -0.25 -0.084 0.49190E+03
208 chalcocite -24.30 -25.49 -1.18 -0.295 0.22986E+04
210 covellite -17.63 -19.02 -1.40 -0.532 0.27187E+04
211 dawsonite 0.70 -1.68 -2.38 -0.297 0.46286E+04
213 montmorillonite-Ca -4.10 -7.05 -2.95 -0.183 0.57417E+04
214 montmorillonite-K -3.87 -6.94 -3.07 -0.188 0.59750E+04
215 montmorillonite-Mg -4.32 -7.23 -2.91 -0.180 0.56634E+04
216 montmorillonite-Na -3.70 -6.46 -2.77 -0.169 0.53809E+04
229 gypsum -5.21 -9.16 -3.95 -0.987 0.76750E+04
245 acanthite -24.35 -24.50 -0.15 -0.037 0.28787E+03
251 barite -9.36 -11.92 -2.56 -1.280 0.49777E+04
252 boehmite 2.51 0.54 -1.97 -0.328 0.38314E+04
253 cerussite -2.72 -6.30 -3.58 -1.195 0.69712E+04
254 chalcopyrite -26.04 -27.56 -1.52 -0.284 0.29639E+04
256 copper,native -2.16 -6.46 -4.30 -1.495 0.83593E+04
257 dolomite,disordered -0.09 -2.89 -2.80 -0.467 0.54500E+04
259 fluorite -9.90 -10.64 -0.73 -0.245 0.14270E+04
261 gold,native -15.50 -16.72 -1.21 -0.422 0.23601E+04
262 silver,native -5.21 -5.97 -0.76 -0.263 0.14685E+04
269 silica-amorphous -1.81 -2.67 -0.86 -0.286 0.16713E+04
270 smithsonite -1.30 -5.29 -4.00 -1.332 0.77730E+04
273 wurtzite -8.22 -9.83 -1.61 -0.536 0.31288E+04
274 zincite 6.76 1.81 -4.95 -1.238 0.96314E+04
275 an20ab80 0.41 -1.66 -2.07 -0.159 0.40228E+04
276 an25ab75 0.85 -1.44 -2.29 -0.176 0.44485E+04
277 an30ab70 1.30 -1.21 -2.51 -0.193 0.48859E+04
Calculations done for 151.9018 Deg. C; 500.0000 bar
Mixer fraction: 0.4000000
Temperature Stoc.ionic strength Heat per mole
Actual solution: 151.902 .12446E+01 2.894
Mixing solution: 25.000 .50000E-10 0.646
Fract. of mixing solution added: 0.050000
BITMOL = 0.2775E+01 OLDMOL = 0.7926E+02
New heat: 2.818 New temperature: 147.678
New mixer fraction: 0.4500000
Resulting temperature: 147.678Deg. C
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1296E-03
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 7 Loop limit = 70
Temperature = 147.68 C Pressure = 500.00 bar Mixer fraction = 0.4500000
Water: Moles liquid = 0.8062E+02 kg liquid = 0.1452E+01
Moles total = 0.8030E+02 kg total = 0.1447E+01 Activity = 0.9651
Stoichiometric ionic strength = .1201599E+01 Osmotic coef. = 0.9271
True ionic strength = .9458582E+00
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.13040E-04 -4.8847 0.73858E-05 -5.1316 0.56639E+00 -0.2469
2 H2O 0.96508E+00 -0.0154 0.96508E+00 -0.0154
3 Cl- 0.92509E+00 -0.0338 0.53361E+00 -0.2728 0.57682E+00 -0.2390
4 SO4-- 0.12017E-03 -3.9202 0.98358E-05 -5.0072 0.81846E-01 -1.0870
5 HCO3- 0.18304E-01 -1.7375 0.10750E-01 -1.9686 0.58730E+00 -0.2311
6 HS- 0.49635E-06 -6.3042 0.28683E-06 -6.5424 0.57788E+00 -0.2382
7 H4SiO4 0.19314E-02 -2.7141 0.19314E-02 -2.7141 0.10000E+01 0.0000
8 Al+++ 0.59024E-12 -12.2290 0.18385E-14 -14.7355 0.31149E-02 -2.5066
9 Ca++ 0.10696E-02 -2.9708 0.80376E-04 -4.0949 0.75143E-01 -1.1241
10 Mg++ 0.94015E-04 -4.0268 0.67019E-05 -5.1738 0.71285E-01 -1.1470
11 Fe++ 0.89376E-06 -6.0488 0.64526E-07 -7.1903 0.72196E-01 -1.1415
12 K+ 0.30888E-01 -1.5102 0.18177E-01 -1.7405 0.58846E+00 -0.2303
13 Na+ 0.91086E+00 -0.0405 0.52361E+00 -0.2810 0.57485E+00 -0.2404
14 Mn++ 0.96701E-05 -5.0146 0.70486E-06 -6.1519 0.72891E-01 -1.1373
15 Zn++ 0.50205E-07 -7.2993 0.36246E-08 -8.4407 0.72196E-01 -1.1415
16 Cu+ 0.12036E-11 -11.9195 0.69144E-12 -12.1602 0.57448E+00 -0.2407
17 Pb++ 0.40062E-08 -8.3973 0.31133E-09 -9.5068 0.77713E-01 -1.1095
18 Ag+ 0.36215E-11 -11.4411 0.21214E-11 -11.6734 0.58580E+00 -0.2323
19 Au+ 0.60097E-22 -22.2212 0.35456E-22 -22.4503 0.58998E+00 -0.2292
20 Ba++ 0.16817E-05 -5.7743 0.13364E-06 -6.8741 0.79465E-01 -1.0998
21 F- 0.95666E-03 -3.0192 0.53726E-03 -3.2698 0.56160E+00 -0.2506
22 H2AsO3- 0.22671E-06 -6.6445 0.15469E-06 -6.8105 0.68231E+00 -0.1660
24 HSiO3- 0.97406E-06 -6.0114 0.56186E-06 -6.2504 0.57682E+00 -0.2390
25 Ca(HSiO3)+ 0.34991E-08 -8.4560 0.20644E-08 -8.6852 0.58998E+00 -0.2292
26 Mg(HSiO3)+ 0.29722E-09 -9.5269 0.17535E-09 -9.7561 0.58998E+00 -0.2292
27 NaHSiO3,aq 0.27315E-05 -5.5636 0.27315E-05 -5.5636 0.10000E+01 0.0000
31 AgCl,aq 0.62538E-09 -9.2039 0.62538E-09 -9.2039 0.10000E+01 0.0000
32 AgCl2- 0.22691E-07 -7.6441 0.13089E-07 -7.8831 0.57682E+00 -0.2390
33 AgCl3-2 0.10326E-07 -7.9861 0.82605E-09 -9.0830 0.79997E-01 -1.0969
34 AgCl4-3 0.88138E-09 -9.0548 0.28127E-11 -11.5509 0.31913E-02 -2.4960
38 Ag(HS),aq 0.53710E-08 -8.2699 0.53710E-08 -8.2699 0.10000E+01 0.0000
40 AlO+ 0.16678E-09 -9.7778 0.98398E-10 -10.0070 0.58998E+00 -0.2292
41 AlOH+2 0.12540E-10 -10.9017 0.92437E-12 -12.0342 0.73711E-01 -1.1325
42 HAlO2,aq 0.10047E-07 -7.9980 0.10047E-07 -7.9980 0.10000E+01 0.0000
43 AlO2- 0.19265E-07 -7.7152 0.10856E-07 -7.9643 0.56350E+00 -0.2491
44 AsO2- 0.70490E-07 -7.1519 0.40660E-07 -7.3908 0.57682E+00 -0.2390
45 HAsO2,aq 0.28983E-04 -4.5379 0.28983E-04 -4.5379 0.10000E+01 0.0000
46 H3AsO3,aq 0.59979E-04 -4.2220 0.59979E-04 -4.2220 0.10000E+01 0.0000
48 H2AsO4- 0.26098E-10 -10.5834 0.15054E-10 -10.8223 0.57682E+00 -0.2390
62 BaCO3,aq 0.18661E-09 -9.7291 0.18661E-09 -9.7291 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.60994E-06 -6.2147 0.36424E-06 -6.4386 0.59717E+00 -0.2239
64 BaCl+ 0.50594E-06 -6.2959 0.29850E-06 -6.5251 0.58998E+00 -0.2292
65 BaF+ 0.63995E-09 -9.1939 0.37756E-09 -9.4230 0.58998E+00 -0.2292
66 CH4,aq 0.33546E-09 -9.4744 0.30276E-09 -9.5189 0.90251E+00 -0.0446
71 CO,aq 0.22195E-09 -9.6537 0.22195E-09 -9.6537 0.10000E+01 0.0000
72 CO2,aq 0.22254E+00 -0.6526 0.20084E+00 -0.6972 0.90251E+00 -0.0446
73 CO3-2 0.20721E-05 -5.6836 0.16576E-06 -6.7805 0.79997E-01 -1.0969
74 CaCO3,aq 0.45243E-06 -6.3444 0.45243E-06 -6.3444 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.82729E-04 -4.0823 0.48808E-04 -4.3115 0.58998E+00 -0.2292
76 CaCl+ 0.27523E-03 -3.5603 0.16238E-03 -3.7895 0.58998E+00 -0.2292
77 CaCl2,aq 0.18392E-04 -4.7354 0.18392E-04 -4.7354 0.10000E+01 0.0000
78 CaF+ 0.25579E-05 -5.5921 0.15091E-05 -5.8213 0.58998E+00 -0.2292
79 CaOH+ 0.17878E-07 -7.7477 0.10547E-07 -7.9769 0.58998E+00 -0.2292
80 CaSO4,aq 0.46068E-06 -6.3366 0.46068E-06 -6.3366 0.10000E+01 0.0000
81 HCl,aq 0.13396E-05 -5.8730 0.13396E-05 -5.8730 0.10000E+01 0.0000
90 CuCl,aq 0.17397E-08 -8.7595 0.17397E-08 -8.7595 0.10000E+01 0.0000
91 CuCl2- 0.25927E-07 -7.5862 0.14955E-07 -7.8252 0.57682E+00 -0.2390
92 CuCl3-2 0.41410E-08 -8.3829 0.33127E-09 -9.4798 0.79997E-01 -1.0969
98 HF,aq 0.59601E-04 -4.2247 0.59601E-04 -4.2247 0.10000E+01 0.0000
99 HF2- 0.16340E-07 -7.7867 0.94255E-08 -8.0257 0.57682E+00 -0.2390
101 FeCl+ 0.18417E-06 -6.7348 0.10865E-06 -6.9640 0.58998E+00 -0.2292
102 FeCl2,aq 0.80584E-10 -10.0938 0.80584E-10 -10.0938 0.10000E+01 0.0000
104 FeF+ 0.52817E-08 -8.2772 0.31161E-08 -8.5064 0.58998E+00 -0.2292
107 FeOH+ 0.35438E-08 -8.4505 0.20908E-08 -8.6797 0.58998E+00 -0.2292
113 H2,aq 0.28895E-07 -7.5392 0.26078E-07 -7.5837 0.90251E+00 -0.0446
114 KCl,aq 0.40005E-03 -3.3979 0.40005E-03 -3.3979 0.10000E+01 0.0000
115 KHSO4,aq 0.42956E-10 -10.3670 0.42956E-10 -10.3670 0.10000E+01 0.0000
116 KOH,aq 0.74218E-08 -8.1295 0.74218E-08 -8.1295 0.10000E+01 0.0000
117 KSO4- 0.88349E-05 -5.0538 0.50961E-05 -5.2928 0.57682E+00 -0.2390
118 MgCO3,aq 0.66947E-08 -8.1743 0.66947E-08 -8.1743 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.68944E-05 -5.1615 0.40675E-05 -5.3907 0.58998E+00 -0.2292
120 MgCl+ 0.16644E-04 -4.7788 0.98194E-05 -5.0079 0.58998E+00 -0.2292
121 MgF+ 0.70177E-06 -6.1538 0.41403E-06 -6.3830 0.58998E+00 -0.2292
122 MgOH+ 0.61635E-08 -8.2102 0.36363E-08 -8.4393 0.58998E+00 -0.2292
124 MnF+ 0.20845E-07 -7.6810 0.12298E-07 -7.9102 0.58998E+00 -0.2292
126 MnOH+ 0.44714E-08 -8.3496 0.26380E-08 -8.5787 0.58998E+00 -0.2292
131 MnCl+ 0.14038E-04 -4.8527 0.82823E-05 -5.0818 0.58998E+00 -0.2292
132 MnSO4,aq 0.42935E-08 -8.3672 0.42935E-08 -8.3672 0.10000E+01 0.0000
133 NaCl,aq 0.13820E+00 -0.8595 0.13820E+00 -0.8595 0.10000E+01 0.0000
134 NaF,aq 0.10135E-03 -3.9942 0.10135E-03 -3.9942 0.10000E+01 0.0000
135 NaOH,aq 0.17976E-06 -6.7453 0.17976E-06 -6.7453 0.10000E+01 0.0000
137 OH- 0.75948E-06 -6.1195 0.42796E-06 -6.3686 0.56350E+00 -0.2491
140 PbCl+ 0.33060E-07 -7.4807 0.19505E-07 -7.7099 0.58998E+00 -0.2292
141 PbCl2,aq 0.90495E-07 -7.0434 0.90495E-07 -7.0434 0.10000E+01 0.0000
142 PbCl3- 0.47088E-07 -7.3271 0.27161E-07 -7.5661 0.57682E+00 -0.2390
143 PbCl4-2 0.41910E-07 -7.3777 0.33527E-08 -8.4746 0.79997E-01 -1.0969
144 PbF+ 0.59224E-10 -10.2275 0.34941E-10 -10.4567 0.58998E+00 -0.2292
148 Pb(HS)2,aq 0.49248E-10 -10.3076 0.49248E-10 -10.3076 0.10000E+01 0.0000
150 H2S,aq 0.61269E-05 -5.2128 0.55296E-05 -5.2573 0.90251E+00 -0.0446
158 HSO3- 0.40595E-10 -10.3915 0.23416E-10 -10.6305 0.57682E+00 -0.2390
159 HSO4- 0.41290E-06 -6.3842 0.24660E-06 -6.6080 0.59724E+00 -0.2239
173 ZnCl+ 0.25084E-05 -5.6006 0.14799E-05 -5.8298 0.58998E+00 -0.2292
174 ZnCl2,aq 0.48930E-06 -6.3104 0.48930E-06 -6.3104 0.10000E+01 0.0000
175 ZnCl3- 0.55824E-07 -7.2532 0.32200E-07 -7.4921 0.57682E+00 -0.2390
176 ZnF+ 0.19210E-09 -9.7165 0.11334E-09 -9.9456 0.58998E+00 -0.2292
177 ZnO,aq 0.26542E-10 -10.5761 0.26542E-10 -10.5761 0.10000E+01 0.0000
178 ZnOH+ 0.68331E-07 -7.1654 0.40314E-07 -7.3945 0.58998E+00 -0.2292
Charge balance for all species = -.8924E-04
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.1304007E-04 0.2226974E+00 0.2089462E+03 0.0000
2 H2O 0.1000000E+01 0.5528568E+02 0.9271260E+06 0.0000
3 Cl- 0.9250874E+00 0.1064037E+01 0.3511512E+05 4.8588
4 SO4-- 0.1201743E-03 0.1298795E-03 0.1161382E+02 5.2560
5 HCO3- 0.1830388E-01 0.2409320E+00 0.1368457E+05 3.1630
6 HS- 0.4963477E-06 0.6636349E-05 0.2043028E+00 -1.4108
7 H4SiO4 0.1931413E-02 0.1935122E-02 0.1731354E+03 -2.7141
8 Al+++ 0.5902388E-12 0.2949168E-07 0.7407134E-03 0.6593
9 Ca++ 0.1069641E-02 0.1449486E-02 0.5407600E+02 6.1683
10 Mg++ 0.9401549E-04 0.1182685E-03 0.2676544E+01 5.0894
11 Fe++ 0.8937583E-06 0.1086836E-05 0.5650000E-01 3.0729
12 K+ 0.3088849E-01 0.3129738E-01 0.1139178E+04 3.3911
13 Na+ 0.9108591E+00 0.1049164E+01 0.2245241E+05 4.8506
14 Mn++ 0.9670139E-05 0.2373814E-04 0.1213959E+01 4.1113
15 Zn++ 0.5020454E-07 0.3172309E-05 0.1930361E+00 1.8225
16 Cu+ 0.1203591E-11 0.3180926E-07 0.1881418E-02 -7.0286
17 Pb++ 0.4006184E-08 0.2166702E-06 0.4178810E-01 0.7564
18 Ag+ 0.3621467E-11 0.3989995E-07 0.4006430E-02 -6.5418
19 Au+ 0.6009656E-22 0.2141954E-11 0.3927248E-06 -17.3187
20 Ba++ 0.1681706E-05 0.2798415E-05 0.3577616E+00 3.3891
21 F- 0.9566579E-03 0.1120933E-02 0.1982312E+02 1.8618
22 H2AsO3- 0.2267112E-06 0.8925956E-04 0.1038068E+02 -1.6789
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234443E+00 -.9095820E-05 0.0000000E+00
2 H2O 0.8029657E+02 0.8029657E+02 -.1239576E-07 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886362E-03 0.3098939E-08 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.9638590E-05 0.4391721E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810559E-02 0.1182223E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.4283352E-07 0.2364445E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1578514E-05 0.2479151E-07 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.4607442E-05 0.2860735E-05 0.0000000E+00
16 Cu+ 0.1701571E-06 0.4619956E-07 0.1239576E-06 0.0000000E+00
17 Pb++ 0.1565021E-05 0.3146904E-06 0.1250330E-05 0.0000000E+00
18 Ag+ 0.4271281E-06 0.5795042E-07 0.3691777E-06 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1628036E-02 0.2364445E-05 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.156027E+04 g
Temperature = 147.68 C Pressure = 500.00 bar Mixer frac. = 0.4500000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
argentite 0.1846E-06 -6.734 0.4574E-04 -4.340 5.358 0.6423E-05
bornite 0.2479E-07 -7.606 0.1244E-04 -4.905 1.457 0.2447E-05
topaz 0.1182E-05 -5.927 0.2176E-03 -3.662 25.49 0.6091E-04
galena 0.1250E-05 -5.903 0.2991E-03 -3.524 35.04 0.3937E-04
sphalerite 0.2861E-05 -5.544 0.2787E-03 -3.555 32.65 0.6816E-04
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
argentite 0.1000E+01 0.1000E+01 1.0000 0.000
bornite 0.1000E+01 0.1000E+01 1.0000 0.000
topaz 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.4500000
Solid products produced: Mass = 0.000854 g Volume = 0.000177 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.400
AFFINITY: 0.2877E+03
GOLD Q/K: 0.0695
SILVER Q/K: 0.1640
Gas composition at saturation ( 3 iterations)
-------------------------------------------------
Temperature: 147.6775 deg.C
Sat. pressure: 60.6006 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.1206E+00 0.7310 0.5343E+01 0.7310E+01
CO2,gas 0.8794E+00 0.9023 0.4808E+02 0.5329E+02
CH4,gas 0.1083E-07 1.0642 0.6984E-06 0.6563E-06
H2,gas 0.6053E-06 1.0291 0.3775E-04 0.3668E-04
H2S,gas 0.6005E-05 0.8502 0.3094E-03 0.3639E-03
S2,gas 0.2165E-16 1.0000 0.1312E-14 0.1312E-14
CO,gas 0.6629E-08 1.0000 0.4017E-06 0.4017E-06
SO3,gas 0.4243E-28 1.0000 0.2571E-26 0.2571E-26
O2,gas 0.1586E-46 1.0000 0.9609E-45 0.9609E-45
SO2,gas 0.6168E-13 1.0000 0.3738E-11 0.3738E-11
HF,gas 0.1518E-07 1.0000 0.9199E-06 0.9199E-06
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
196 argentite -24.76 -24.76 0.00 0.000 0.00000E+00
205 bornite -79.21 -79.21 0.00 0.000 0.00000E+00
225 topaz -18.20 -18.20 0.00 0.000 0.00000E+00
260 galena -10.92 -10.92 0.00 0.000 0.00000E+00
272 sphalerite -9.85 -9.85 0.00 0.000 0.34206E-11
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.96 -0.02 -1.97 -1.971 0.37958E+04 0.728
2 CO2,gas -6.07 -7.08 -1.02 -0.339 0.19583E+04 1.682
3 CH4,gas 5.34 -3.52 -8.85 -2.214 0.17051E+05 -6.156
4 H2,gas 8.01 0.88 -7.12 -4.070 0.13714E+05 -4.423
5 H2S,gas -5.47 -11.67 -6.21 -3.104 0.11955E+05 -3.509
6 S2,gas -7.53 -25.12 -17.58 -2.705 0.33855E+05 -14.882
7 CO,gas 2.91 -6.19 -9.10 -2.798 0.17514E+05 -6.396
8 SO3,gas 14.03 -15.25 -29.29 -7.322 0.56400E+05 -26.590
9 O2,gas 45.92 -1.80 -47.72 -31.811 0.91884E+05 -45.017
10 SO2,gas -0.23 -14.36 -14.13 -3.767 0.27202E+05 -11.427
11 HF,gas 0.33 -8.40 -8.74 -4.368 0.16821E+05 -6.036
12 HCl,gas 2.01 -5.40 -7.42 -3.708 0.14282E+05 -7.417
13 acmite 6.87 2.08 -4.78 -0.497 0.92072E+04
17 albite-high -0.32 -2.57 -2.26 -0.174 0.43433E+04
18 albite -1.17 -2.57 -1.40 -0.108 0.26920E+04
22 analcite 2.14 0.10 -2.04 -0.227 0.39311E+04
23 andalusite 1.85 -1.41 -3.27 -0.327 0.62872E+04
26 anhydrite -5.84 -9.10 -3.26 -1.632 0.62839E+04
27 ankerite -2.92 -4.96 -2.04 -0.340 0.39329E+04
34 aragonite 0.50 -0.93 -1.43 -0.478 0.27589E+04
36 calcite 0.36 -0.93 -1.29 -0.431 0.24915E+04
37 carnegieite-low 7.11 2.80 -4.32 -0.617 0.83113E+04
39 carpholite-Mg 5.14 0.95 -4.19 -0.280 0.80779E+04
40 carpholite-Fe 3.47 -1.07 -4.54 -0.303 0.87383E+04
50 chloritoid-Fe 5.44 1.63 -3.81 -0.254 0.73299E+04
51 chloritoid-Mn 7.63 2.67 -4.97 -0.331 0.95613E+04
53 coesite -2.06 -2.68 -0.62 -0.207 0.11951E+04
58 corundum 4.79 1.27 -3.52 -0.320 0.67735E+04
60 cristobalite -2.24 -2.68 -0.45 -0.149 0.86052E+03
63 cymrite-K 0.80 -4.05 -4.84 -0.404 0.93247E+04
65 diaspore 1.39 0.63 -0.76 -0.127 0.14722E+04
66 diamond -2.57 -5.29 -2.72 -0.778 0.52401E+04
69 dolomite,ordered -0.52 -2.94 -2.43 -0.404 0.46731E+04
83 gibbsite 2.60 0.61 -1.98 -0.283 0.38200E+04
86 goethite 5.38 2.60 -2.78 -0.602 0.53618E+04
87 graphite -2.97 -5.29 -2.32 -0.661 0.44580E+04
90 halite 1.53 -0.55 -2.08 -1.042 0.40136E+04
92 heulandite -7.16 -11.45 -4.29 -0.195 0.82694E+04
96 jadeite 2.95 0.11 -2.84 -0.284 0.54633E+04
98 kalsilite 5.90 1.34 -4.56 -0.652 0.87867E+04
99 kaolinite -3.22 -4.13 -0.90 -0.082 0.17386E+04
100 kyanite 1.76 -1.41 -3.17 -0.317 0.60999E+04
102 laumontite 0.62 -3.37 -3.99 -0.266 0.76766E+04
103 lawsonite 6.40 2.03 -4.38 -0.292 0.84270E+04
104 leucite 2.79 -1.35 -4.13 -0.413 0.79585E+04
107 magnesite -0.04 -2.01 -1.97 -0.657 0.37958E+04
117 microcline -2.89 -4.03 -1.14 -0.088 0.21941E+04
121 muscovite -0.80 -2.77 -1.97 -0.116 0.37963E+04
122 paragonite 0.57 -1.31 -1.88 -0.111 0.36219E+04
123 nepheline 6.48 2.80 -3.68 -0.526 0.70889E+04
143 pyrite -19.91 -21.16 -1.25 -0.294 0.24071E+04
144 pyrrhotite -4.52 -8.60 -4.08 -1.360 0.78578E+04
145 pyrrhotiteFe0.875 -6.04 -9.09 -3.05 -1.123 0.58791E+04
146 pyroxmangite 6.38 1.41 -4.97 -0.994 0.95684E+04
147 pyrophyllite -7.64 -9.48 -1.84 -0.115 0.35410E+04
148 quartz -2.60 -2.68 -0.08 -0.026 0.15229E+03
153 rhodochrosite -1.31 -2.99 -1.67 -0.558 0.32239E+04
155 sanidine -1.82 -4.03 -2.21 -0.170 0.42620E+04
157 siderite -2.96 -4.03 -1.06 -0.355 0.20500E+04
158 sillimanite 2.06 -1.41 -3.47 -0.347 0.66818E+04
165 stilbite -7.81 -11.47 -3.66 -0.174 0.70478E+04
171 sulfur -8.66 -12.56 -3.90 -1.200 0.75087E+04
172 sylvite 1.46 -2.01 -3.47 -1.734 0.66794E+04
180 topaz-H 1.85 -1.43 -3.27 -0.297 0.63011E+04
181 tridymite -2.28 -2.68 -0.41 -0.135 0.78029E+03
184 troilite-low -4.62 -8.60 -3.98 -1.326 0.76629E+04
190 wairakite 1.28 -3.34 -4.62 -0.272 0.89006E+04
197 arsenic -6.26 -10.57 -4.31 -1.112 0.82944E+04
200 beidellite-Ca -4.10 -7.37 -3.26 -0.202 0.62863E+04
201 beidellite-H -4.66 -8.38 -3.72 -0.238 0.71684E+04
202 beidellite-K -3.80 -7.26 -3.46 -0.212 0.66707E+04
203 beidellite-Mg -4.32 -7.54 -3.23 -0.200 0.62160E+04
204 beidellite-Na -3.68 -6.78 -3.10 -0.190 0.59728E+04
207 chalcedony -2.44 -2.68 -0.24 -0.082 0.47164E+03
208 chalcocite -24.55 -25.73 -1.19 -0.296 0.22821E+04
210 covellite -17.78 -19.14 -1.37 -0.521 0.26326E+04
211 dawsonite 0.79 -1.62 -2.41 -0.301 0.46342E+04
213 montmorillonite-Ca -3.92 -7.00 -3.07 -0.190 0.59170E+04
214 montmorillonite-K -3.71 -6.90 -3.19 -0.195 0.61356E+04
215 montmorillonite-Mg -4.14 -7.17 -3.04 -0.188 0.58447E+04
216 montmorillonite-Na -3.53 -6.41 -2.88 -0.176 0.55494E+04
229 gypsum -5.17 -9.13 -3.97 -0.992 0.76372E+04
245 acanthite -24.61 -24.76 -0.14 -0.036 0.27622E+03
251 barite -9.33 -11.88 -2.55 -1.275 0.49102E+04
252 boehmite 2.67 0.63 -2.04 -0.340 0.39246E+04
253 cerussite -2.71 -6.34 -3.63 -1.211 0.69933E+04
254 chalcopyrite -26.19 -27.75 -1.55 -0.289 0.29891E+04
256 copper,native -2.23 -6.59 -4.36 -1.517 0.83972E+04
257 dolomite,disordered 0.04 -2.94 -2.98 -0.497 0.57422E+04
259 fluorite -9.87 -10.63 -0.76 -0.254 0.14655E+04
261 gold,native -15.72 -16.88 -1.16 -0.403 0.22294E+04
262 silver,native -5.31 -6.10 -0.79 -0.273 0.15120E+04
269 silica-amorphous -1.82 -2.68 -0.86 -0.287 0.16591E+04
270 smithsonite -1.24 -5.28 -4.04 -1.346 0.77774E+04
273 wurtzite -8.23 -9.85 -1.62 -0.542 0.31289E+04
275 an20ab80 0.56 -1.64 -2.20 -0.170 0.42434E+04
276 an25ab75 1.02 -1.41 -2.43 -0.187 0.46833E+04
277 an30ab70 1.48 -1.18 -2.67 -0.205 0.51345E+04
Calculations done for 147.6775 Deg. C; 500.0000 bar
Mixer fraction: 0.4500000
Temperature Stoc.ionic strength Heat per mole
Actual solution: 147.678 .12016E+01 2.818
Mixing solution: 25.000 .50000E-10 0.646
Fract. of mixing solution added: 0.050000
BITMOL = 0.2775E+01 OLDMOL = 0.8203E+02
New heat: 2.746 New temperature: 143.723
New mixer fraction: 0.5000000
Resulting temperature: 143.723Deg. C
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1296E-03
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C.
Illustrates fluid-fluid mixing. CHIMRUN demo-3
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 7 Loop limit = 70
Temperature = 143.72 C Pressure = 500.00 bar Mixer fraction = 0.5000000
Water: Moles liquid = 0.8340E+02 kg liquid = 0.1502E+01
Moles total = 0.8307E+02 kg total = 0.1497E+01 Activity = 0.9662
Stoichiometric ionic strength = .1161453E+01 Osmotic coef. = 0.9280
True ionic strength = .9210274E+00
Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.13687E-04 -4.8637 0.78530E-05 -5.1050 0.57375E+00 -0.2413
2 H2O 0.96619E+00 -0.0149 0.96619E+00 -0.0149
3 Cl- 0.90092E+00 -0.0453 0.52347E+00 -0.2811 0.58104E+00 -0.2358
4 SO4-- 0.11651E-03 -3.9336 0.10021E-04 -4.9991 0.86006E-01 -1.0655
5 HCO3- 0.17700E-01 -1.7520 0.10455E-01 -1.9807 0.59069E+00 -0.2286
6 HS- 0.44566E-06 -6.3510 0.25938E-06 -6.5861 0.58201E+00 -0.2351
7 H4SiO4 0.18674E-02 -2.7288 0.18674E-02 -2.7288 0.10000E+01 0.0000
8 Al+++ 0.75379E-12 -12.1228 0.26534E-14 -14.5762 0.35202E-02 -2.4534
9 Ca++ 0.10496E-02 -2.9790 0.83180E-04 -4.0800 0.79246E-01 -1.1010
10 Mg++ 0.91629E-04 -4.0380 0.69149E-05 -5.1602 0.75466E-01 -1.1222
11 Fe++ 0.86962E-06 -6.0607 0.66400E-07 -7.1778 0.76355E-01 -1.1172
12 K+ 0.29896E-01 -1.5244 0.17684E-01 -1.7524 0.59151E+00 -0.2280
13 Na+ 0.88712E+00 -0.0520 0.51351E+00 -0.2895 0.57885E+00 -0.2374
14 Mn++ 0.98335E-05 -5.0073 0.75752E-06 -6.1206 0.77034E-01 -1.1133
15 Zn++ 0.53422E-07 -7.2723 0.40791E-08 -8.3894 0.76355E-01 -1.1172
16 Cu+ 0.98913E-12 -12.0047 0.57222E-12 -12.2424 0.57851E+00 -0.2377
17 Pb++ 0.37995E-08 -8.4203 0.31073E-09 -9.5076 0.81783E-01 -1.0873
18 Ag+ 0.29370E-11 -11.5321 0.17299E-11 -11.7620 0.58902E+00 -0.2299
19 Au+ 0.45870E-22 -22.3385 0.27198E-22 -22.5655 0.59294E+00 -0.2270
20 Ba++ 0.16822E-05 -5.7741 0.14049E-06 -6.8523 0.83519E-01 -1.0782
21 F- 0.93033E-03 -3.0314 0.52822E-03 -3.2772 0.56777E+00 -0.2458
22 H2AsO3- 0.18941E-06 -6.7226 0.12907E-06 -6.8892 0.68146E+00 -0.1666
24 HSiO3- 0.86498E-06 -6.0630 0.50259E-06 -6.2988 0.58104E+00 -0.2358
25 Ca(HSiO3)+ 0.29949E-08 -8.5236 0.17758E-08 -8.7506 0.59294E+00 -0.2270
26 Mg(HSiO3)+ 0.25770E-09 -9.5889 0.15280E-09 -9.8159 0.59294E+00 -0.2270
27 NaHSiO3,aq 0.24547E-05 -5.6100 0.24547E-05 -5.6100 0.10000E+01 0.0000
31 AgCl,aq 0.50347E-09 -9.2980 0.50347E-09 -9.2980 0.10000E+01 0.0000
32 AgCl2- 0.17777E-07 -7.7501 0.10329E-07 -7.9859 0.58104E+00 -0.2358
33 AgCl3-2 0.77225E-08 -8.1122 0.65009E-09 -9.1870 0.84181E-01 -1.0748
34 AgCl4-3 0.61212E-09 -9.2132 0.22164E-11 -11.6543 0.36209E-02 -2.4412
38 Ag(HS),aq 0.50723E-08 -8.2948 0.50723E-08 -8.2948 0.10000E+01 0.0000
40 AlO+ 0.16344E-09 -9.7866 0.96909E-10 -10.0136 0.59294E+00 -0.2270
41 AlOH+2 0.13726E-10 -10.8625 0.10684E-11 -11.9713 0.77839E-01 -1.1088
42 HAlO2,aq 0.85193E-08 -8.0696 0.85193E-08 -8.0696 0.10000E+01 0.0000
43 AlO2- 0.13831E-07 -7.8591 0.78743E-08 -8.1038 0.56932E+00 -0.2446
44 AsO2- 0.62639E-07 -7.2032 0.36396E-07 -7.4389 0.58104E+00 -0.2358
45 HAsO2,aq 0.28583E-04 -4.5439 0.28583E-04 -4.5439 0.10000E+01 0.0000
46 H3AsO3,aq 0.57454E-04 -4.2407 0.57454E-04 -4.2407 0.10000E+01 0.0000
48 H2AsO4- 0.22170E-10 -10.6542 0.12882E-10 -10.8900 0.58104E+00 -0.2358
62 BaCO3,aq 0.16699E-09 -9.7773 0.16699E-09 -9.7773 0.10000E+01 0.0000
63 Ba(HCO3)+ 0.55000E-06 -6.2596 0.32984E-06 -6.4817 0.59972E+00 -0.2221
64 BaCl+ 0.47235E-06 -6.3257 0.28007E-06 -6.5527 0.59294E+00 -0.2270
65 BaF+ 0.60617E-09 -9.2174 0.35942E-09 -9.4444 0.59294E+00 -0.2270
66 CH4,aq 0.28936E-09 -9.5386 0.26112E-09 -9.5832 0.90242E+00 -0.0446
71 CO,aq 0.16955E-09 -9.7707 0.16955E-09 -9.7707 0.10000E+01 0.0000
72 CO2,aq 0.21513E+00 -0.6673 0.19414E+00 -0.7119 0.90242E+00 -0.0446
73 CO3-2 0.18588E-05 -5.7308 0.15647E-06 -6.8056 0.84181E-01 -1.0748
74 CaCO3,aq 0.39928E-06 -6.3987 0.39928E-06 -6.3987 0.10000E+01 0.0000
75 Ca(HCO3)+ 0.76373E-04 -4.1171 0.45284E-04 -4.3441 0.59294E+00 -0.2270
76 CaCl+ 0.25542E-03 -3.5928 0.15145E-03 -3.8197 0.59294E+00 -0.2270
77 CaCl2,aq 0.16581E-04 -4.7804 0.16581E-04 -4.7804 0.10000E+01 0.0000
78 CaF+ 0.23721E-05 -5.6249 0.14065E-05 -5.8519 0.59294E+00 -0.2270
79 CaOH+ 0.14186E-07 -7.8481 0.84117E-08 -8.0751 0.59294E+00 -0.2270
80 CaSO4,aq 0.45382E-06 -6.3431 0.45382E-06 -6.3431 0.10000E+01 0.0000
81 HCl,aq 0.13372E-05 -5.8738 0.13372E-05 -5.8738 0.10000E+01 0.0000
90 CuCl,aq 0.14223E-08 -8.8470 0.14223E-08 -8.8470 0.10000E+01 0.0000
91 CuCl2- 0.20653E-07 -7.6850 0.12000E-07 -7.9208 0.58104E+00 -0.2358
92 CuCl3-2 0.31758E-08 -8.4982 0.26734E-09 -9.5729 0.84181E-01 -1.0748
98 HF,aq 0.57090E-04 -4.2434 0.57090E-04 -4.2434 0.10000E+01 0.0000
99 HF2- 0.15319E-07 -7.8148 0.89011E-08 -8.0506 0.58104E+00 -0.2358
101 FeCl+ 0.17191E-06 -6.7647 0.10193E-06 -6.9917 0.59294E+00 -0.2270
102 FeCl2,aq 0.54849E-10 -10.2608 0.54849E-10 -10.2608 0.10000E+01 0.0000
104 FeF+ 0.49918E-08 -8.3017 0.29598E-08 -8.5287 0.59294E+00 -0.2270
107 FeOH+ 0.29761E-08 -8.5263 0.17647E-08 -8.7533 0.59294E+00 -0.2270
113 H2,aq 0.23266E-07 -7.6333 0.20996E-07 -7.6779 0.90242E+00 -0.0446
114 KCl,aq 0.35202E-03 -3.4534 0.35202E-03 -3.4534 0.10000E+01 0.0000
115 KHSO4,aq 0.35676E-10 -10.4476 0.35676E-10 -10.4476 0.10000E+01 0.0000
116 KOH,aq 0.59957E-08 -8.2222 0.59957E-08 -8.2222 0.10000E+01 0.0000
117 KSO4- 0.81994E-05 -5.0862 0.47642E-05 -5.3220 0.58104E+00 -0.2358
118 MgCO3,aq 0.60347E-08 -8.2193 0.60347E-08 -8.2193 0.10000E+01 0.0000
119 Mg(HCO3)+ 0.63633E-05 -5.1963 0.37730E-05 -5.4233 0.59294E+00 -0.2270
120 MgCl+ 0.15675E-04 -4.8048 0.92940E-05 -5.0318 0.59294E+00 -0.2270
121 MgF+ 0.65461E-06 -6.1840 0.38814E-06 -6.4110 0.59294E+00 -0.2270
122 MgOH+ 0.49660E-08 -8.3040 0.29445E-08 -8.5310 0.59294E+00 -0.2270
124 MnF+ 0.20404E-07 -7.6903 0.12098E-07 -7.9173 0.59294E+00 -0.2270
126 MnOH+ 0.38677E-08 -8.4125 0.22933E-08 -8.6395 0.59294E+00 -0.2270
131 MnCl+ 0.13086E-04 -4.8832 0.77592E-05 -5.1102 0.59294E+00 -0.2270
132 MnSO4,aq 0.43477E-08 -8.3617 0.43477E-08 -8.3617 0.10000E+01 0.0000
133 NaCl,aq 0.12703E+00 -0.8961 0.12703E+00 -0.8961 0.10000E+01 0.0000
134 NaF,aq 0.93118E-04 -4.0310 0.93118E-04 -4.0310 0.10000E+01 0.0000
135 NaOH,aq 0.14858E-06 -6.8280 0.14858E-06 -6.8280 0.10000E+01 0.0000
137 OH- 0.64516E-06 -6.1903 0.36730E-06 -6.4350 0.56932E+00 -0.2446
140 PbCl+ 0.30118E-07 -7.5212 0.17858E-07 -7.7482 0.59294E+00 -0.2270
141 PbCl2,aq 0.77958E-07 -7.1081 0.77958E-07 -7.1081 0.10000E+01 0.0000
142 PbCl3- 0.38764E-07 -7.4116 0.22524E-07 -7.6474 0.58104E+00 -0.2358
143 PbCl4-2 0.32697E-07 -7.4855 0.27524E-08 -8.5603 0.84181E-01 -1.0748
144 PbF+ 0.55208E-10 -10.2580 0.32735E-10 -10.4850 0.59294E+00 -0.2270
148 Pb(HS)2,aq 0.42492E-10 -10.3717 0.42492E-10 -10.3717 0.10000E+01 0.0000
150 H2S,aq 0.57606E-05 -5.2395 0.51985E-05 -5.2841 0.90242E+00 -0.0446
158 HSO3- 0.33462E-10 -10.4755 0.19443E-10 -10.7112 0.58104E+00 -0.2358
159 HSO4- 0.39091E-06 -6.4079 0.23454E-06 -6.6298 0.59998E+00 -0.2219
173 ZnCl+ 0.23053E-05 -5.6373 0.13669E-05 -5.8643 0.59294E+00 -0.2270
174 ZnCl2,aq 0.43554E-06 -6.3610 0.43554E-06 -6.3610 0.10000E+01 0.0000
175 ZnCl3- 0.48843E-07 -7.3112 0.28380E-07 -7.5470 0.58104E+00 -0.2358
176 ZnF+ 0.19793E-09 -9.7035 0.11736E-09 -9.9305 0.59294E+00 -0.2270
177 ZnO,aq 0.20144E-10 -10.6959 0.20144E-10 -10.6959 0.10000E+01 0.0000
178 ZnOH+ 0.59245E-07 -7.2273 0.35128E-07 -7.4543 0.59294E+00 -0.2270
Charge balance for all species = -.8627E-04
Component Molality Aq.molality ppm log[A(N)/A(H+)**Z]
(total)
1 H+ 0.1368714E-04 0.2152862E+00 0.2024585E+03 0.0000
2 H2O 0.1000000E+01 0.5529309E+02 0.9293888E+06 0.0000
3 Cl- 0.9009206E+00 0.1028625E+01 0.3402478E+05 4.8239
4 SO4-- 0.1165145E-03 0.1255570E-03 0.1125319E+02 5.2108
5 HCO3- 0.1769970E-01 0.2329137E+00 0.1325966E+05 3.1243
6 HS- 0.4456621E-06 0.6217624E-05 0.1918536E+00 -1.4811
7 H4SiO4 0.1867395E-02 0.1870718E-02 0.1677592E+03 -2.7288
8 Al+++ 0.7537861E-12 0.2252816E-07 0.5671225E-03 0.7387
9 Ca++ 0.1049633E-02 0.1401246E-02 0.5239690E+02 6.1299
10 Mg++ 0.9162876E-04 0.1143325E-03 0.2593436E+01 5.0497
11 Fe++ 0.8696241E-06 0.1049566E-05 0.5468834E-01 3.0321
12 K+ 0.2989557E-01 0.3025580E-01 0.1103806E+04 3.3525
13 Na+ 0.8871219E+00 0.1014247E+01 0.2175525E+05 4.8155
14 Mn++ 0.9833488E-05 0.2294813E-04 0.1176265E+01 4.0893
15 Zn++ 0.5342204E-07 0.2902594E-05 0.1770312E+00 1.8205
16 Cu+ 0.9891254E-12 0.2525181E-07 0.1497010E-02 -7.1375
17 Pb++ 0.3799496E-08 0.1834365E-06 0.3546007E-01 0.7023
18 Ag+ 0.2936982E-11 0.3169092E-07 0.3189485E-02 -6.6570
19 Au+ 0.4587030E-22 0.2070670E-11 0.3805304E-06 -17.4605
20 Ba++ 0.1682164E-05 0.2705283E-05 0.3466529E+00 3.3576
21 F- 0.9303303E-03 0.1083622E-02 0.1920750E+02 1.8278
22 H2AsO3- 0.1894083E-06 0.8628898E-04 0.1005835E+02 -1.7842
Component Tot moles Aq. moles Solid moles Gas moles
1 H+ 0.3234352E+00 0.3234446E+00 -.9409414E-05 0.0000000E+00
2 H2O 0.8307198E+02 0.8307198E+02 -.1322190E-07 0.0000000E+00
3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00
4 SO4-- 0.1886393E-03 0.1886360E-03 0.3305474E-08 0.0000000E+00
5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00
6 HS- 0.1403031E-04 0.9341318E-05 0.4688993E-05 0.0000000E+00
7 H4SiO4 0.2811741E-02 0.2810554E-02 0.1186716E-05 0.0000000E+00
8 Al+++ 0.2407279E-05 0.3384616E-07 0.2373433E-05 0.0000000E+00
9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00
10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00
11 Fe++ 0.1603305E-05 0.1576861E-05 0.2644380E-07 0.0000000E+00
12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00
13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00
14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00
15 Zn++ 0.7468176E-05 0.4360838E-05 0.3107338E-05 0.0000000E+00
16 Cu+ 0.1701571E-06 0.3793815E-07 0.1322190E-06 0.0000000E+00
17 Pb++ 0.1565021E-05 0.2755938E-06 0.1289427E-05 0.0000000E+00
18 Ag+ 0.4271281E-06 0.4761223E-07 0.3795159E-06 0.0000000E+00
19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00
20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00
21 F- 0.1630400E-02 0.1628027E-02 0.2373433E-05 0.0000000E+00
22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00
Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.161027E+04 g
Temperature = 143.72 C Pressure = 500.00 bar Mixer frac. = 0.5000000
Log Log Vol
Gas or mineral Moles Moles Grams Grams Wt.% (cm3)
argentite 0.1898E-06 -6.722 0.4702E-04 -4.328 5.284 0.6603E-05
bornite 0.2644E-07 -7.578 0.1327E-04 -4.877 1.491 0.2611E-05
topaz 0.1187E-05 -5.926 0.2184E-03 -3.661 24.54 0.6114E-04
galena 0.1289E-05 -5.890 0.3085E-03 -3.511 34.66 0.4060E-04
sphalerite 0.3107E-05 -5.508 0.3027E-03 -3.519 34.02 0.7404E-04
Partial press. Fugacity coef Log fugacity
Gas or Mineral Mole fraction or activity Activity coef Log activity
argentite 0.1000E+01 0.1000E+01 1.0000 0.000
bornite 0.1000E+01 0.1000E+01 1.0000 0.000
topaz 0.1000E+01 0.1000E+01 1.0000 0.000
galena 0.1000E+01 0.1000E+01 1.0000 0.000
sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000
Total fraction of mixing solution added: 0.5000000
Solid products produced: Mass = 0.000890 g Volume = 0.000185 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Estimated lowest electrum affinity for X gold = 0.400
AFFINITY: 0.2668E+03
GOLD Q/K: 0.0786
SILVER Q/K: 0.1536
Gas composition at saturation ( 3 iterations)
-------------------------------------------------
Temperature: 143.7232 deg.C
Sat. pressure: 57.7469 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.1129E+00 0.7397 0.4824E+01 0.6522E+01
CO2,gas 0.8871E+00 0.9029 0.4625E+02 0.5122E+02
CH4,gas 0.1011E-07 1.0598 0.6184E-06 0.5836E-06
H2,gas 0.5273E-06 1.0280 0.3130E-04 0.3045E-04
H2S,gas 0.5871E-05 0.8529 0.2892E-03 0.3391E-03
S2,gas 0.1816E-16 1.0000 0.1049E-14 0.1049E-14
CO,gas 0.5512E-08 1.0000 0.3183E-06 0.3183E-06
SO3,gas 0.2488E-28 1.0000 0.1437E-26 0.1437E-26
O2,gas 0.5310E-47 1.0000 0.3066E-45 0.3066E-45
SO2,gas 0.4897E-13 1.0000 0.2828E-11 0.2828E-11
HF,gas 0.1356E-07 1.0000 0.7830E-06 0.7830E-06
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently in matrix or were just added
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
196 argentite -25.01 -25.01 0.00 0.000 0.00000E+00
205 bornite -79.85 -79.85 0.00 0.000 0.00000E+00
225 topaz -18.02 -18.02 0.00 0.000 0.00000E+00
260 galena -10.99 -10.99 0.00 0.000 0.33885E-11
272 sphalerite -9.87 -9.87 0.00 0.000 -0.33885E-11
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 2.00 -0.01 -2.02 -2.016 0.38447E+04 0.683
2 CO2,gas -6.04 -7.07 -1.03 -0.345 0.19721E+04 1.665
3 CH4,gas 5.33 -3.58 -8.91 -2.227 0.16992E+05 -6.209
4 H2,gas 8.07 0.86 -7.20 -4.116 0.13741E+05 -4.504
5 H2S,gas -5.45 -11.69 -6.24 -3.119 0.11899E+05 -3.539
6 S2,gas -7.43 -25.11 -17.68 -2.720 0.33722E+05 -14.979
7 CO,gas 3.00 -6.19 -9.20 -2.830 0.17542E+05 -6.497
8 SO3,gas 14.35 -15.19 -29.54 -7.385 0.56352E+05 -26.843
9 O2,gas 46.45 -1.76 -48.21 -32.142 0.91967E+05 -45.513
10 SO2,gas -0.07 -14.31 -14.25 -3.799 0.27178E+05 -11.549
11 HF,gas 0.42 -8.38 -8.81 -4.403 0.16796E+05 -6.106
12 HCl,gas 2.12 -5.39 -7.50 -3.752 0.14315E+05 -7.504
13 acmite 6.94 1.99 -4.95 -0.515 0.94499E+04
17 albite-high -0.21 -2.57 -2.36 -0.182 0.45098E+04
18 albite -1.08 -2.57 -1.49 -0.115 0.28423E+04
22 analcite 2.25 0.11 -2.14 -0.238 0.40864E+04
23 andalusite 2.13 -1.27 -3.39 -0.339 0.64732E+04
26 anhydrite -5.77 -9.08 -3.31 -1.656 0.63176E+04
27 ankerite -2.82 -5.01 -2.19 -0.364 0.41681E+04
34 aragonite 0.55 -0.96 -1.51 -0.503 0.28758E+04
36 calcite 0.41 -0.96 -1.37 -0.456 0.26113E+04
37 carnegieite-low 7.28 2.83 -4.45 -0.636 0.84934E+04
39 carpholite-Mg 5.44 1.04 -4.40 -0.293 0.83927E+04
40 carpholite-Fe 3.75 -0.98 -4.73 -0.315 0.90241E+04
50 chloritoid-Fe 5.76 1.74 -4.02 -0.268 0.76670E+04
53 coesite -2.08 -2.70 -0.62 -0.205 0.11752E+04
58 corundum 5.09 1.43 -3.66 -0.333 0.69772E+04
60 cristobalite -2.25 -2.70 -0.44 -0.148 0.84805E+03
63 cymrite-K 0.89 -4.05 -4.94 -0.412 0.94200E+04
65 diaspore 1.52 0.71 -0.81 -0.135 0.15422E+04
66 diamond -2.61 -5.31 -2.71 -0.773 0.51613E+04
69 dolomite,ordered -0.40 -2.99 -2.59 -0.431 0.49354E+04
83 gibbsite 2.72 0.69 -2.02 -0.289 0.38602E+04
86 goethite 5.47 2.57 -2.90 -0.627 0.55299E+04
87 graphite -3.01 -5.31 -2.30 -0.656 0.43827E+04
90 halite 1.54 -0.57 -2.11 -1.056 0.40285E+04
92 heulandite -6.99 -11.43 -4.45 -0.202 0.84792E+04
96 jadeite 3.06 0.13 -2.94 -0.294 0.56020E+04
98 kalsilite 6.05 1.36 -4.68 -0.669 0.89358E+04
99 kaolinite -3.05 -4.00 -0.95 -0.086 0.18101E+04
100 kyanite 2.02 -1.27 -3.29 -0.329 0.62769E+04
102 laumontite 0.84 -3.31 -4.15 -0.276 0.79090E+04
103 lawsonite 6.68 2.12 -4.56 -0.304 0.86970E+04
104 leucite 2.91 -1.34 -4.25 -0.425 0.81076E+04
107 magnesite 0.03 -2.04 -2.07 -0.689 0.39405E+04
117 microcline -2.83 -4.04 -1.21 -0.093 0.23024E+04
121 muscovite -0.49 -2.62 -2.13 -0.125 0.40574E+04
122 paragonite 0.90 -1.15 -2.05 -0.121 0.39176E+04
123 nepheline 6.64 2.83 -3.81 -0.545 0.72733E+04
143 pyrite -19.98 -21.21 -1.23 -0.290 0.23496E+04
144 pyrrhotite -4.49 -8.66 -4.17 -1.391 0.79609E+04
145 pyrrhotiteFe0.875 -6.02 -9.15 -3.12 -1.148 0.59526E+04
147 pyrophyllite -7.48 -9.38 -1.90 -0.118 0.36158E+04
148 quartz -2.63 -2.70 -0.07 -0.023 0.13388E+03
153 rhodochrosite -1.27 -3.00 -1.72 -0.574 0.32838E+04
155 sanidine -1.74 -4.04 -2.29 -0.176 0.43703E+04
157 siderite -2.92 -4.05 -1.13 -0.378 0.21633E+04
158 sillimanite 2.34 -1.27 -3.60 -0.360 0.68704E+04
165 stilbite -7.72 -11.45 -3.73 -0.178 0.71135E+04
171 sulfur -8.68 -12.56 -3.87 -1.192 0.73915E+04
172 sylvite 1.46 -2.03 -3.49 -1.745 0.66555E+04
180 topaz-H 2.08 -1.28 -3.36 -0.306 0.64162E+04
181 tridymite -2.30 -2.70 -0.40 -0.134 0.76624E+03
184 troilite-low -4.59 -8.66 -4.07 -1.356 0.77604E+04
190 wairakite 1.55 -3.28 -4.83 -0.284 0.92039E+04
197 arsenic -6.34 -10.65 -4.32 -1.114 0.82345E+04
200 beidellite-Ca -3.87 -7.24 -3.38 -0.209 0.64398E+04
201 beidellite-H -4.44 -8.25 -3.82 -0.244 0.72827E+04
202 beidellite-K -3.58 -7.15 -3.57 -0.218 0.68059E+04
203 beidellite-Mg -4.08 -7.42 -3.34 -0.207 0.63754E+04
204 beidellite-Na -3.46 -6.66 -3.21 -0.196 0.61198E+04
207 chalcedony -2.46 -2.70 -0.24 -0.079 0.45306E+03
208 chalcocite -24.78 -25.97 -1.19 -0.297 0.22670E+04
210 covellite -17.92 -19.26 -1.34 -0.510 0.25528E+04
211 dawsonite 0.87 -1.56 -2.43 -0.304 0.46400E+04
213 montmorillonite-Ca -3.76 -6.94 -3.19 -0.197 0.60787E+04
214 montmorillonite-K -3.55 -6.85 -3.29 -0.202 0.62835E+04
215 montmorillonite-Mg -3.97 -7.12 -3.15 -0.195 0.60121E+04
216 montmorillonite-Na -3.38 -6.37 -2.99 -0.183 0.57048E+04
229 gypsum -5.12 -9.11 -3.99 -0.996 0.76032E+04
245 acanthite -24.87 -25.01 -0.14 -0.035 0.26527E+03
251 barite -9.31 -11.85 -2.54 -1.271 0.48491E+04
252 boehmite 2.81 0.71 -2.10 -0.350 0.40097E+04
253 cerussite -2.71 -6.38 -3.68 -1.226 0.70145E+04
254 chalcopyrite -26.34 -27.92 -1.58 -0.294 0.30118E+04
256 copper,native -2.28 -6.71 -4.42 -1.538 0.84323E+04
257 dolomite,disordered 0.16 -2.99 -3.15 -0.526 0.60148E+04
259 fluorite -9.85 -10.63 -0.79 -0.263 0.15035E+04
261 gold,native -15.92 -17.03 -1.10 -0.384 0.21071E+04
262 silver,native -5.41 -6.22 -0.81 -0.283 0.15522E+04
269 silica-amorphous -1.83 -2.70 -0.86 -0.288 0.16481E+04
270 smithsonite -1.19 -5.27 -4.08 -1.360 0.77822E+04
273 wurtzite -8.23 -9.87 -1.64 -0.547 0.31288E+04
275 an20ab80 0.70 -1.63 -2.33 -0.179 0.44477E+04
276 an25ab75 1.18 -1.39 -2.57 -0.198 0.49008E+04
277 an30ab70 1.66 -1.16 -2.81 -0.216 0.53646E+04
Calculations done for 143.7232 Deg. C; 500.0000 bar
Mixer fraction: 0.5000000
Temperature Stoc.ionic strength Heat per mole
Actual solution: 143.723 .11615E+01 2.746
Mixing solution: 25.000 .50000E-10 0.646
Fract. of mixing solution added: 0.050000
BITMOL = 0.2775E+01 OLDMOL = 0.8481E+02
New heat: 2.680 New temperature: 140.015
New mixer fraction: 0.5500000
Resulting temperature: 140.015Deg. C
Mixing fraction reached given limit of 0.5000E+00
TOTMIX = 0.5500E+00 Execution stopped.