File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. fCO2,1bar20C is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. 0.32344E+00 0.43025E-05 0.4449 0.00000000E+00 H2O 2 0. 0.55318E+02 0.10000E+01 0.9517 0.55508250E+02 Cl- 3 -1. 0.15454E+01 0.11700E+01 0.4691 0.00000000E+00 SO4-- 4 -2. 0.18864E-03 0.81054E-04 0.0440 0.00000000E+00 HCO3- 5 -1. 0.34993E+00 0.20644E-01 0.4929 0.00000000E+00 HS- 6 -1. 0.14030E-04 0.29717E-05 0.4717 0.00000000E+00 H4SiO4 7 0. 0.28117E-02 0.27794E-02 1.0000 0.00000000E+00 Al+++ 8 3. 0.24073E-05 0.82727E-15 0.0011 0.00000000E+00 Ca++ 9 2. 0.21052E-02 0.14726E-02 0.0372 0.00000000E+00 Mg++ 10 2. 0.17177E-03 0.10466E-03 0.0305 0.00000000E+00 Fe++ 11 2. 0.16033E-05 0.10700E-05 0.0321 0.00000000E+00 K+ 12 1. 0.45456E-01 0.40961E-01 0.5001 0.00000000E+00 Na+ 13 1. 0.15238E+01 0.11475E+01 0.4715 0.00000000E+00 Mn++ 14 2. 0.34477E-04 0.25340E-06 0.0333 0.00000000E+00 Zn++ 15 2. 0.74682E-05 0.44513E-08 0.0321 0.00000000E+00 Cu+ 16 1. 0.17016E-06 0.60617E-11 0.4707 0.00000000E+00 Pb++ 17 2. 0.15650E-05 0.15583E-08 0.0416 0.00000000E+00 Ag+ 18 1. 0.42713E-06 0.13296E-10 0.4948 0.00000000E+00 Au+ 19 1. 0.31110E-11 0.62614E-20 0.5031 0.00000000E+00 Ba++ 20 2. 0.40644E-05 0.11059E-05 0.0446 0.00000000E+00 F- 21 -1. 0.16304E-02 0.12576E-02 0.4232 0.00000000E+00 H2AsO3- 22 -1. 0.12964E-03 0.12914E-03 1.0000 0.00000000E+00 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Chg. balance for the mixing solution = 0.0000E+00 Max. difference allowed = 0.1545E-03 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 500.0000 SLIM = 0.500000E+00 TEMP = 199.9700 SINC = 0.5000E-01 TEMPC = 25.0000 TOTMIX = 0.000000E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1082.4053 SUPRNT = 0.1000E-10 VBOX-1 = 0.0000 RHOFRS = 0.0000 RHOROC = 0.0000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 1 NLOOP = 70 ISTEP = 2 LIMSOL = 2 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 0 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-10 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 23 -2. -24.0537 FeCl2,aq 102 0. 0.2961 HSiO3- 24 -1. 8.6869 FeCl+2 103 2. 5.3673 Ca(HSiO3)+ 25 1. 6.5692 FeF+ 104 1. -2.3547 Mg(HSiO3)+ 26 1. 6.6492 FeF+2 105 2. -0.2035 NaHSiO3,aq 27 0. 7.7929 FeO,aq 106 0. 13.0998 Ag(CO3)- 28 -1. 8.2019 FeOH+ 107 1. 5.8994 Ag(CO3)2-3 29 -3. 18.6148 HFeO2- 108 -1. 20.3859 Ag+2 30 2. 20.7929 FeO+ 109 1. 9.0645 AgCl,aq 31 0. -2.7620 FeOH+2 110 2. 7.5523 AgCl2- 32 -1. -4.3979 FeO2- 111 -1. 19.3670 AgCl3-2 33 -2. -3.4129 HFeO2,aq 112 0. 12.6557 AgCl4-3 34 -3. -1.1479 H2,aq 113 0. 7.5785 AgF,aq 35 0. -0.8709 KCl,aq 114 0. 0.9263 Ag(OH),aq 36 0. 10.2921 KHSO4,aq 115 0. -2.8712 AgO- 37 -1. 17.6335 KOH,aq 116 0. 10.9103 Ag(HS),aq 38 0. -8.7276 KSO4- 117 -1. -1.8198 Ag(HS)2- 39 -1. -11.5285 MgCO3,aq 118 0. 5.9151 AlO+ 40 1. 4.1937 Mg(HCO3)+ 119 1. -2.2427 AlOH+2 41 2. 1.5595 MgCl+ 120 1. -0.8647 HAlO2,aq 42 0. 6.8769 MgF+ 121 1. -2.5527 AlO2- 43 -1. 11.4851 MgOH+ 122 1. 7.4445 AsO2- 44 -1. 1.0128 Mn+3 123 3. 17.3354 HAsO2,aq 45 0. -6.8443 MnF+ 124 1. -1.9627 H3AsO3,aq 46 0. -7.3462 MnO,aq 125 0. 14.6048 H3AsO4,aq 47 0. -0.0418 MnOH+ 126 1. 6.7734 H2AsO4- 48 -1. 3.0520 MnO2-2 127 -2. 34.6622 HAsO4-2 49 -2. 10.2498 HMnO2- 128 -1. 24.6020 AsO4-3 50 -3. 21.6036 MnO4- 129 -1. 63.9466 HAs3S6-2 51 -2. -67.0569 MnO4-2 130 -2. 65.0977 H2As3S6- 52 -1. -73.5090 MnCl+ 131 1. -2.0346 H3As3S6,aq 53 0. -75.8261 MnSO4,aq 132 0. -3.2837 Au+3 54 3. 28.9931 NaCl,aq 133 0. 0.0242 AuCl,aq 55 0. -5.4902 NaF,aq 134 0. 0.1462 AuCl2- 56 -1. -6.5792 NaOH,aq 135 0. 11.0562 AuCl3-2 57 -2. -6.0312 O2,aq 136 0. 40.0003 AuCl4- 58 -1. 22.9250 OH- 137 -1. 11.0862 AuOH,aq 59 0. -2.6546 HO2- 138 -1. 40.9792 AuHS,aq 60 0. -15.6928 H2O2,aq 139 0. 30.6972 Au(HS)2- 61 -1. -19.3129 PbCl+ 140 1. -2.4907 BaCO3,aq 62 0. 5.6352 PbCl2,aq 141 0. -3.6936 Ba(HCO3)+ 63 1. -3.1086 PbCl3- 142 -1. -3.5655 BaCl+ 64 1. -1.1867 PbCl4-2 143 -2. -2.8875 BaF+ 65 1. -1.2167 PbF+ 144 1. -2.6328 CH4,aq 66 0. 5.9610 PbF2,aq 145 0. -3.9607 C2H6,aq 67 0. 11.8951 PbO,aq 146 0. 11.3675 C3H8,aq 68 0. 16.9421 HPbO2- 147 -1. 20.7485 C4H10,aq 69 0. 22.0061 Pb(HS)2,aq 148 0. -12.1690 ethanol,aq 70 0. 13.8464 Pb(HS)3- 149 -1. -13.4229 CO,aq 71 0. 2.0568 H2S,aq 150 0. -6.6368 CO2,aq 72 0. -6.8387 S2-2 151 -2. 0.9421 CO3-2 73 -2. 10.1908 S3-2 152 -2. -8.3380 CaCO3,aq 74 0. 5.0362 S3- 153 -1. -16.9295 Ca(HCO3)+ 75 1. -2.2607 S4-2 154 -2. -17.4720 CaCl+ 76 1. -1.0987 S5-2 155 -2. -26.4660 CaCl2,aq 77 0. -0.5706 SO2,aq 156 0. -3.7489 CaF+ 78 1. -2.0837 SO3-2 157 -2. 8.8623 CaOH+ 79 1. 7.9815 HSO3- 158 -1. 0.1956 CaSO4,aq 80 0. -3.2107 HSO4- 159 -1. -4.2776 HCl,aq 81 0. 0.1482 HSO5- 160 -1. 27.2139 HClO,aq 82 0. 23.9001 S2O3-2 161 -2. -4.7748 ClO- 83 -1. 31.0400 HS2O3- 162 -1. -8.0035 HClO2,aq 84 0. 52.7923 H2S2O3,aq 163 0. -9.8793 Cu+2 85 2. 0.8987 S2O4-2 164 -2. 6.5321 CuCl+ 86 1. -0.5610 HS2O4- 165 -1. 2.8354 CuCl2,aq 87 0. -0.2188 H2S2O4,aq 166 0. 1.0896 CuCl3- 88 -1. 1.4563 S2O5-2 167 -2. 5.7892 CuCl4-2 89 -2. 4.7703 S2O6-2 168 -2. 6.4904 CuCl,aq 90 0. -3.6810 S2O8-2 169 -2. 28.7284 CuCl2- 91 -1. -4.8960 S3O6-2 170 -2. -0.6917 CuCl3-2 92 -2. -3.3940 S4O6-2 171 -2. -20.1281 CuF+ 93 1. -1.6060 S5O6-2 172 -2. -16.9919 CuO,aq 94 0. 10.9972 ZnCl+ 173 1. -3.8774 CuOH+ 95 1. 5.8920 ZnCl2,aq 174 0. -3.8263 CuO2-2 96 -2. 31.0966 ZnCl3- 175 -1. -2.9093 HCuO2- 97 -1. 20.0295 ZnF+ 176 1. -2.1827 HF,aq 98 0. -4.6897 ZnO,aq 177 0. 11.0137 HF2- 99 -1. -4.1287 ZnOH+ 178 1. 3.0755 Fe+3 100 3. 7.9851 ZnO2-2 179 -2. 30.0709 FeCl+ 101 1. -0.9587 HZnO2- 180 -1. 19.5688 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.444 0.0000E+00 pumpellyite-Mg 140 25.779 0.0000E+00 CO2,gas 2 -6.490 0.0000E+00 px-Mg-tschermaks 141 9.115 0.0000E+00 CH4,gas 3 5.496 0.0000E+00 px-Ca-tschermaks 142 9.049 0.0000E+00 H2,gas 4 7.305 0.0000E+00 pyrite 143 -19.225 0.0000E+00 H2S,gas 5 -5.674 0.0000E+00 pyrrhotite 144 -5.014 0.0000E+00 S2,gas 6 -8.912 0.0000E+00 pyrrhotiteFe0.875 145 -6.331 0.0000E+00 CO,gas 7 1.745 0.0000E+00 pyroxmangite 146 5.393 0.0000E+00 SO3,gas 8 10.225 0.0000E+00 pyrophyllite 147 -9.510 0.0000E+00 O2,gas 9 36.925 0.0000E+00 quartz 148 -2.315 0.0000E+00 SO2,gas 10 -2.252 0.0000E+00 rankinite 149 31.464 0.0000E+00 HF,gas 11 -0.768 0.0000E+00 riebeckite 150 14.095 0.0000E+00 HCl,gas 12 3.417 0.0000E+00 ringwoodite-Fe 151 10.558 0.0000E+00 acmite 13 5.980 0.0000E+00 ringwoodite-Mg 152 20.124 0.0000E+00 akermanite 14 27.286 0.0000E+00 rhodochrosite 153 -1.850 0.0000E+00 akimotoite 15 12.340 0.0000E+00 rhodonite 154 5.417 0.0000E+00 akimotoite-Fe 16 9.487 0.0000E+00 sanidine 155 -2.692 0.0000E+00 albite-high 17 -1.581 0.0000E+00 sapphirine(351) 156 32.190 0.0000E+00 albite 18 -2.246 0.0000E+00 siderite 157 -3.539 0.0000E+00 almandine 19 11.204 0.0000E+00 sillimanite 158 -1.252 0.0000E+00 pyrope 20 21.269 0.0000E+00 sodalite 159 27.486 0.0000E+00 spessartine 21 12.643 0.0000E+00 spinel 160 10.156 0.0000E+00 analcite 22 0.781 0.0000E+00 spurrite 161 45.196 0.0000E+00 andalusite 23 -1.419 0.0000E+00 staurolite-Fe 162 7.480 0.0000E+00 andradite 24 28.552 0.0000E+00 staurolite-Mg 163 20.224 0.0000E+00 grossular 25 20.249 0.0000E+00 staurolite-Mn 164 17.143 0.0000E+00 anhydrite 26 -6.831 0.0000E+00 stilbite 165 -8.820 0.0000E+00 ankerite 27 -4.145 0.0000E+00 stilpnomelane-Fe 166 3.871 0.0000E+00 annite 28 11.905 0.0000E+00 stilpnomelane-Mg 167 14.745 0.0000E+00 phlogopite 29 17.565 0.0000E+00 stishovite 168 2.333 0.0000E+00 biotite-Mn 30 23.206 0.0000E+00 sudoite-Fe 169 3.773 0.0000E+00 anorthite 31 4.238 0.0000E+00 sudoite 170 6.082 0.0000E+00 anthophyllite 32 35.809 0.0000E+00 sulfur 171 -8.492 0.0000E+00 anthophyllite-Fe 33 17.955 0.0000E+00 sylvite 172 1.388 0.0000E+00 aragonite 34 -0.172 0.0000E+00 talc 173 11.302 0.0000E+00 brucite 35 9.504 0.0000E+00 talc-Fe 174 8.735 0.0000E+00 calcite 36 -0.312 0.0000E+00 talc-tschermaks 175 8.610 0.0000E+00 carnegieite-low 37 5.151 0.0000E+00 tenorite 176 4.581 0.0000E+00 carnegieite-high 38 5.825 0.0000E+00 tephroite 177 13.370 0.0000E+00 carpholite-Mg 39 1.631 0.0000E+00 tilleyite 178 30.134 0.0000E+00 carpholite-Fe 40 0.099 0.0000E+00 titanite-CaSi 179 12.259 0.0000E+00 celadonite 41 2.387 0.0000E+00 topaz-H 180 -0.992 0.0000E+00 celadonite-Fe 42 1.073 0.0000E+00 tridymite 181 -2.052 0.0000E+00 chrysotile 43 17.444 0.0000E+00 tremolite 182 34.067 0.0000E+00 chondrodite 44 40.687 0.0000E+00 ferroactinolite 183 26.346 0.0000E+00 clinochlore 45 23.381 0.0000E+00 troilite-low 184 -5.072 0.0000E+00 daphnite 46 15.138 0.0000E+00 tschermakite 185 25.059 0.0000E+00 chlorite-Mn 47 31.446 0.0000E+00 vesuvianite 186 144.223 0.0000E+00 chlorite-Al-free 48 34.510 0.0000E+00 wadeite-Si 187 18.152 0.0000E+00 chloritoid-Mg 49 4.763 0.0000E+00 wadsleyite-Fe 188 10.658 0.0000E+00 chloritoid-Fe 50 1.650 0.0000E+00 wadsleyite-Mg 189 18.712 0.0000E+00 chloritoid-Mn 51 3.842 0.0000E+00 wairakite 190 -1.865 0.0000E+00 clinohumite 52 69.471 0.0000E+00 walstromite 191 8.871 0.0000E+00 coesite 53 -1.825 0.0000E+00 wollastonite 192 8.067 0.0000E+00 cordierite-H 54 6.041 0.0000E+00 pseudo-wollastonite 193 8.440 0.0000E+00 cordierite 55 6.387 0.0000E+00 zoisite 194 9.786 0.0000E+00 cordierite-Fe 56 3.466 0.0000E+00 Ag2O 195 10.213 0.0000E+00 cordierite-Mn 57 7.898 0.0000E+00 argentite 196 -21.917 0.0000E+00 corundum 58 1.193 0.0000E+00 arsenic 197 -5.406 0.0000E+00 corundum-MgSi 59 14.154 0.0000E+00 arsenolite 198 -13.681 0.0000E+00 cristobalite 60 -2.023 0.0000E+00 arsenopyrite 199 -13.344 0.0000E+00 cummingtonite 61 35.983 0.0000E+00 beidellite-Ca 200 -6.927 0.0000E+00 cuprite 62 0.598 0.0000E+00 beidellite-H 201 -7.368 0.0000E+00 cymrite-K 63 -0.291 0.0000E+00 beidellite-K 202 -6.459 0.0000E+00 deerite 64 61.501 0.0000E+00 beidellite-Mg 203 -7.170 0.0000E+00 diaspore 65 -0.096 0.0000E+00 beidellite-Na 204 -6.381 0.0000E+00 diamond 66 -2.117 0.0000E+00 bornite 205 -71.938 0.0000E+00 diopside 67 11.804 0.0000E+00 calcium 206 66.388 0.0000E+00 hedenbergite 68 10.174 0.0000E+00 chalcedony 207 -2.168 0.0000E+00 dolomite,ordered 69 -1.960 0.0000E+00 chalcocite 208 -21.889 0.0000E+00 eastonite 70 14.028 0.0000E+00 claudetite 209 -13.854 0.0000E+00 enstatite 71 11.991 0.0000E+00 covellite 210 -16.149 0.0000E+00 clinoenstatite-HiP 72 12.851 0.0000E+00 dawsonite 211 -0.237 0.0000E+00 clinoenstatite 73 11.917 0.0000E+00 loellingite 212 -2.214 0.0000E+00 protoenstatite 74 12.393 0.0000E+00 montmorillonite-Ca 213 -5.923 0.0000E+00 epidote 75 13.035 0.0000E+00 montmorillonite-K 214 -5.560 0.0000E+00 clinozoisite 76 9.748 0.0000E+00 montmorillonite-Mg 215 -6.162 0.0000E+00 epidote-Fe 77 18.972 0.0000E+00 montmorillonite-Na 216 -5.401 0.0000E+00 fayalite 78 9.329 0.0000E+00 nontronite-Ca 217 0.526 0.0000E+00 ferrosilite 79 7.104 0.0000E+00 nontronite-H 218 0.081 0.0000E+00 forsterite 80 14.892 0.0000E+00 nontronite-K 219 0.993 0.0000E+00 gedrite 81 25.459 0.0000E+00 nontronite-Mg 220 0.312 0.0000E+00 gehlenite 82 22.852 0.0000E+00 nontronite-Na 221 1.073 0.0000E+00 gibbsite 83 1.163 0.0000E+00 orpiment 222 -45.717 0.0000E+00 glaucophane 84 12.995 0.0000E+00 realgar 223 -54.918 0.0000E+00 glaucophane-Fe 85 8.321 0.0000E+00 sepiolite 224 19.097 0.0000E+00 goethite 86 4.385 0.0000E+00 topaz 225 -20.542 0.0000E+00 graphite 87 -2.503 0.0000E+00 alite 226 45.043 0.0000E+00 greenalite 88 11.219 0.0000E+00 belite 227 23.514 0.0000E+00 grunerite 89 19.348 0.0000E+00 ettringite 228 31.345 0.0000E+00 halite 90 1.352 0.0000E+00 gypsum 229 -5.820 0.0000E+00 hematite 91 8.107 0.0000E+00 hemicarboaluminate 230 53.881 0.0000E+00 heulandite 92 -9.126 0.0000E+00 hydrogarnet 231 44.148 0.0000E+00 hercynite 93 7.245 0.0000E+00 hydrogarnet-Si 232 35.786 0.0000E+00 hollandite 94 18.899 0.0000E+00 jennite 233 20.300 0.0000E+00 iron 95 14.758 0.0000E+00 monosulfoaluminate 234 37.267 0.0000E+00 jadeite 96 1.602 0.0000E+00 monocarboaluminate 235 46.336 0.0000E+00 julgoldite 97 51.350 0.0000E+00 portlandite 236 14.574 0.0000E+00 kalsilite 98 4.138 0.0000E+00 stratlingite 237 25.579 0.0000E+00 kaolinite 99 -5.325 0.0000E+00 tricarboaluminate 238 57.612 0.0000E+00 kyanite 100 -1.451 0.0000E+00 tobermorite 239 8.730 0.0000E+00 larnite-bredigite 101 23.729 0.0000E+00 C4AH13 240 63.437 0.0000E+00 laumontite 102 -2.023 0.0000E+00 C2AH8 241 33.067 0.0000E+00 lawsonite 103 3.119 0.0000E+00 C3A 242 62.199 0.0000E+00 leucite 104 1.261 0.0000E+00 C4AF 243 84.180 0.0000E+00 lime 105 20.310 0.0000E+00 CAH10 244 20.307 0.0000E+00 lizardite 106 17.069 0.0000E+00 acanthite 245 -21.745 0.0000E+00 magnesite 107 -0.916 0.0000E+00 alabandite 246 -2.147 0.0000E+00 magnetite 108 13.110 0.0000E+00 alunite 247 -17.802 0.0000E+00 minnesotaite 109 6.319 0.0000E+00 anglesite 248 -8.492 0.0000E+00 minnesotaite-Mg 110 14.522 0.0000E+00 artinite 249 11.466 0.0000E+00 magnesioferrite 111 17.946 0.0000E+00 azurite 250 3.624 0.0000E+00 majorite 112 38.841 0.0000E+00 barite 251 -9.748 0.0000E+00 manganosite 113 10.591 0.0000E+00 boehmite 252 0.944 0.0000E+00 margarite 114 3.147 0.0000E+00 cerussite 253 -2.859 0.0000E+00 meionite 115 16.450 0.0000E+00 chalcopyrite 254 -24.630 0.0000E+00 merwinite 116 42.390 0.0000E+00 chlorargyrite 255 -6.026 0.0000E+00 microcline 117 -3.647 0.0000E+00 copper,native 256 -1.515 0.0000E+00 monticellite 118 18.154 0.0000E+00 dolomite,disordered 257 -1.535 0.0000E+00 mullite-Al 119 273.876 0.0000E+00 ferrous-oxide 258 6.763 0.0000E+00 mullite-Si 120 0.260 0.0000E+00 fluorite 259 -10.333 0.0000E+00 muscovite 121 -4.543 0.0000E+00 galena 260 -10.172 0.0000E+00 paragonite 122 -3.402 0.0000E+00 gold,native 261 -13.311 0.0000E+00 nepheline 123 4.574 0.0000E+00 silver,native 262 -4.166 0.0000E+00 osumilite(1) 124 2.311 0.0000E+00 huntite 263 -2.476 0.0000E+00 osumilite(2) 125 6.413 0.0000E+00 litharge 264 8.423 0.0000E+00 osumilite-Fe 126 -3.189 0.0000E+00 hydromagnesite 265 10.608 0.0000E+00 pargasite 127 40.301 0.0000E+00 malachite 266 2.812 0.0000E+00 periclase 128 11.872 0.0000E+00 nesquehonite 267 4.514 0.0000E+00 periclase-Fe 129 8.234 0.0000E+00 potassium-oxide 268 56.480 0.0000E+00 perovskite-Al 130 4.307 0.0000E+00 silica-amorphous 269 -1.667 0.0000E+00 perovskite-Ca 131 18.629 0.0000E+00 smithsonite 270 -1.932 0.0000E+00 perovskite-Fe 132 15.856 0.0000E+00 sodium-oxide 271 45.147 0.0000E+00 perovskite-Mg 133 17.453 0.0000E+00 sphalerite 272 -9.708 0.0000E+00 phase_A 134 58.964 0.0000E+00 wurtzite 273 -8.265 0.0000E+00 phlogopite-Na 135 19.371 0.0000E+00 zincite 274 5.675 0.0000E+00 piemontite(ordered) 136 20.446 0.0000E+00 an20ab80 275 -1.167 0.0000E+00 prehnite 137 10.012 0.0000E+00 an25ab75 276 -0.869 0.0000E+00 prehnite-Fe 138 14.212 0.0000E+00 an30ab70 277 -0.566 0.0000E+00 pumpellyite-Fe 139 23.604 0.0000E+00 tr.625ac.25prg.125 278 30.414 0.0000E+00 Mixing solution: Stoch.ionic strengh 0.5000E-10 Temperature 25.00 HEAT 0.64600 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 gold,native 10 silver,native 10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 70 Temperature = 199.97 C Pressure = 500.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5564E+02 kg liquid = 0.1002E+01 Moles total = 0.5532E+02 kg total = 0.9966E+00 Activity = 0.9513 Stoichiometric ionic strength = .1744202E+01 Osmotic coef. = 0.8983 True ionic strength = .1230111E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.63515E-05 -5.1971 0.29704E-05 -5.5272 0.46766E+00 -0.3301 2 H2O 0.95132E+00 -0.0217 0.95132E+00 -0.0217 3 Cl- 0.12006E+01 0.0794 0.60234E+00 -0.2202 0.50171E+00 -0.2995 4 SO4-- 0.16704E-03 -3.7772 0.66000E-05 -5.1805 0.39511E-01 -1.4033 5 HCO3- 0.26393E-01 -1.5785 0.13822E-01 -1.8594 0.52371E+00 -0.2809 6 HS- 0.17299E-05 -5.7620 0.87203E-06 -6.0595 0.50408E+00 -0.2975 7 H4SiO4 0.27915E-02 -2.5542 0.27915E-02 -2.5542 0.10000E+01 0.0000 8 Al+++ 0.52356E-13 -13.2810 0.27885E-16 -16.5546 0.53261E-03 -3.2736 9 Ca++ 0.12334E-02 -2.9089 0.42355E-04 -4.3731 0.34341E-01 -1.4642 10 Mg++ 0.12190E-03 -3.9140 0.37353E-05 -5.4277 0.30642E-01 -1.5137 11 Fe++ 0.11741E-05 -5.9303 0.37022E-07 -7.4315 0.31532E-01 -1.5012 12 K+ 0.43675E-01 -1.3598 0.23144E-01 -1.6356 0.52991E+00 -0.2758 13 Na+ 0.11812E+01 0.0723 0.59449E+00 -0.2259 0.50329E+00 -0.2982 14 Mn++ 0.69483E-05 -5.1581 0.22376E-06 -6.6502 0.32203E-01 -1.4921 15 Zn++ 0.19937E-07 -7.7003 0.62867E-09 -9.2016 0.31532E-01 -1.5012 16 Cu+ 0.45563E-11 -11.3414 0.22896E-11 -11.6402 0.50251E+00 -0.2989 17 Pb++ 0.65771E-08 -8.1820 0.24157E-09 -9.6170 0.36729E-01 -1.4350 18 Ag+ 0.21641E-10 -10.6647 0.11360E-10 -10.9446 0.52494E+00 -0.2799 19 Au+ 0.12995E-20 -20.8862 0.69224E-21 -21.1597 0.53271E+00 -0.2735 20 Ba++ 0.13913E-05 -5.8566 0.53335E-07 -7.2730 0.38335E-01 -1.4164 21 F- 0.12829E-02 -2.8918 0.59020E-03 -3.2290 0.46006E+00 -0.3372 22 H2AsO3- 0.21324E-05 -5.6711 0.14465E-05 -5.8397 0.67834E+00 -0.1686 24 HSiO3- 0.40485E-05 -5.3927 0.20312E-05 -5.6922 0.50171E+00 -0.2995 25 Ca(HSiO3)+ 0.21178E-07 -7.6741 0.11282E-07 -7.9476 0.53271E+00 -0.2735 26 Mg(HSiO3)+ 0.15536E-08 -8.8087 0.82763E-09 -9.0822 0.53271E+00 -0.2735 27 NaHSiO3,aq 0.94602E-05 -5.0241 0.94602E-05 -5.0241 0.10000E+01 0.0000 31 AgCl,aq 0.39553E-08 -8.4028 0.39553E-08 -8.4028 0.10000E+01 0.0000 32 AgCl2- 0.20537E-06 -6.6875 0.10303E-06 -6.9870 0.50171E+00 -0.2995 33 AgCl3-2 0.17013E-06 -6.7692 0.64245E-08 -8.1922 0.37762E-01 -1.4229 34 AgCl4-3 0.41335E-07 -7.3837 0.21023E-10 -10.6773 0.50860E-03 -3.2936 38 Ag(HS),aq 0.52907E-08 -8.2765 0.52907E-08 -8.2765 0.10000E+01 0.0000 40 AlO+ 0.36134E-09 -9.4421 0.19249E-09 -9.7156 0.53271E+00 -0.2735 42 HAlO2,aq 0.12786E-06 -6.8933 0.12786E-06 -6.8933 0.10000E+01 0.0000 43 AlO2- 0.22733E-05 -5.6433 0.10609E-05 -5.9743 0.46666E+00 -0.3310 44 AsO2- 0.29429E-06 -6.5312 0.14765E-06 -6.8308 0.50171E+00 -0.2995 45 HAsO2,aq 0.31556E-04 -4.5009 0.31556E-04 -4.5009 0.10000E+01 0.0000 46 H3AsO3,aq 0.95348E-04 -4.0207 0.95348E-04 -4.0207 0.10000E+01 0.0000 48 H2AsO4- 0.17612E-09 -9.7542 0.88362E-10 -10.0537 0.50171E+00 -0.2995 49 HAsO4-2 0.49958E-10 -10.3014 0.18865E-11 -11.7243 0.37762E-01 -1.4229 62 BaCO3,aq 0.57487E-09 -9.2404 0.57487E-09 -9.2404 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.17350E-05 -5.7607 0.94663E-06 -6.0238 0.54562E+00 -0.2631 64 BaCl+ 0.92689E-06 -6.0330 0.49376E-06 -6.3065 0.53271E+00 -0.2735 65 BaF+ 0.97325E-09 -9.0118 0.51846E-09 -9.2853 0.53271E+00 -0.2735 66 CH4,aq 0.20586E-08 -8.6864 0.19004E-08 -8.7211 0.92316E+00 -0.0347 71 CO,aq 0.54995E-08 -8.2597 0.54995E-08 -8.2597 0.10000E+01 0.0000 72 CO2,aq 0.32247E+00 -0.4915 0.29769E+00 -0.5262 0.92316E+00 -0.0347 73 CO3-2 0.79413E-05 -5.1001 0.29988E-06 -6.5231 0.37762E-01 -1.4229 74 CaCO3,aq 0.18133E-05 -5.7415 0.18133E-05 -5.7415 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.20030E-03 -3.6983 0.10670E-03 -3.9718 0.53271E+00 -0.2735 76 CaCl+ 0.60110E-03 -3.2211 0.32021E-03 -3.4946 0.53271E+00 -0.2735 77 CaCl2,aq 0.57169E-04 -4.2428 0.57169E-04 -4.2428 0.10000E+01 0.0000 78 CaF+ 0.56897E-05 -5.2449 0.30309E-05 -5.5184 0.53271E+00 -0.2735 79 CaOH+ 0.26572E-06 -6.5756 0.14155E-06 -6.8491 0.53271E+00 -0.2735 80 CaSO4,aq 0.45412E-06 -6.3428 0.45412E-06 -6.3428 0.10000E+01 0.0000 81 HCl,aq 0.12718E-05 -5.8956 0.12718E-05 -5.8956 0.10000E+01 0.0000 90 CuCl,aq 0.66157E-08 -8.1794 0.66157E-08 -8.1794 0.10000E+01 0.0000 91 CuCl2- 0.13030E-06 -6.8850 0.65374E-07 -7.1846 0.50171E+00 -0.2995 92 CuCl3-2 0.32829E-07 -7.4837 0.12397E-08 -8.9067 0.37762E-01 -1.4229 98 HF,aq 0.85804E-04 -4.0665 0.85804E-04 -4.0665 0.10000E+01 0.0000 99 HF2- 0.27738E-07 -7.5569 0.13916E-07 -7.8565 0.50171E+00 -0.2995 101 FeCl+ 0.38065E-06 -6.4195 0.20278E-06 -6.6930 0.53271E+00 -0.2735 102 FeCl2,aq 0.67922E-08 -8.1680 0.67922E-08 -8.1680 0.10000E+01 0.0000 104 FeF+ 0.92836E-08 -8.0323 0.49455E-08 -8.3058 0.53271E+00 -0.2735 106 FeO,aq 0.31725E-09 -9.4986 0.31725E-09 -9.4986 0.10000E+01 0.0000 107 FeOH+ 0.28062E-07 -7.5519 0.14949E-07 -7.8254 0.53271E+00 -0.2735 108 HFeO2- 0.10480E-10 -10.9796 0.52580E-11 -11.2792 0.50171E+00 -0.2995 111 FeO2- 0.29446E-10 -10.5310 0.14773E-10 -10.8305 0.50171E+00 -0.2995 112 HFeO2,aq 0.22574E-09 -9.6464 0.22574E-09 -9.6464 0.10000E+01 0.0000 113 H2,aq 0.39503E-06 -6.4034 0.36468E-06 -6.4381 0.92316E+00 -0.0347 114 KCl,aq 0.16520E-02 -2.7820 0.16520E-02 -2.7820 0.10000E+01 0.0000 115 KHSO4,aq 0.33730E-09 -9.4720 0.33730E-09 -9.4720 0.10000E+01 0.0000 116 KOH,aq 0.91133E-07 -7.0403 0.91133E-07 -7.0403 0.10000E+01 0.0000 117 KSO4- 0.20105E-04 -4.6967 0.10087E-04 -4.9962 0.50171E+00 -0.2995 118 MgCO3,aq 0.21133E-07 -7.6750 0.21133E-07 -7.6750 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.16948E-04 -4.7709 0.90282E-05 -5.0444 0.53271E+00 -0.2735 120 MgCl+ 0.30932E-04 -4.5096 0.16478E-04 -4.7831 0.53271E+00 -0.2735 121 MgF+ 0.14775E-05 -5.8305 0.78708E-06 -6.1040 0.53271E+00 -0.2735 122 MgOH+ 0.80699E-07 -7.0931 0.42989E-07 -7.3666 0.53271E+00 -0.2735 124 MnF+ 0.22751E-07 -7.6430 0.12120E-07 -7.9165 0.53271E+00 -0.2735 125 MnO,aq 0.59940E-10 -10.2223 0.59940E-10 -10.2223 0.10000E+01 0.0000 126 MnOH+ 0.22668E-07 -7.6446 0.12075E-07 -7.9181 0.53271E+00 -0.2735 131 MnCl+ 0.27398E-04 -4.5623 0.14595E-04 -4.8358 0.53271E+00 -0.2735 132 MnSO4,aq 0.28380E-08 -8.5470 0.28380E-08 -8.5470 0.10000E+01 0.0000 133 NaCl,aq 0.33870E+00 -0.4702 0.33870E+00 -0.4702 0.10000E+01 0.0000 134 NaF,aq 0.25059E-03 -3.6010 0.25059E-03 -3.6010 0.10000E+01 0.0000 135 NaOH,aq 0.16727E-05 -5.7766 0.16727E-05 -5.7766 0.10000E+01 0.0000 137 OH- 0.56280E-05 -5.2496 0.26264E-05 -5.5806 0.46666E+00 -0.3310 140 PbCl+ 0.84553E-07 -7.0729 0.45042E-07 -7.3464 0.53271E+00 -0.2735 141 PbCl2,aq 0.43281E-06 -6.3637 0.43281E-06 -6.3637 0.10000E+01 0.0000 142 PbCl3- 0.38691E-06 -6.4124 0.19412E-06 -6.7119 0.50171E+00 -0.2995 143 PbCl4-2 0.64994E-06 -6.1871 0.24543E-07 -7.6101 0.37762E-01 -1.4229 144 PbF+ 0.11491E-09 -9.9397 0.61211E-10 -10.2132 0.53271E+00 -0.2735 146 PbO,aq 0.11175E-09 -9.9518 0.11175E-09 -9.9518 0.10000E+01 0.0000 148 Pb(HS)2,aq 0.27106E-09 -9.5669 0.27106E-09 -9.5669 0.10000E+01 0.0000 150 H2S,aq 0.12159E-04 -4.9151 0.11225E-04 -4.9498 0.92316E+00 -0.0347 158 HSO3- 0.36166E-09 -9.4417 0.18145E-09 -9.7412 0.50171E+00 -0.2995 159 HSO4- 0.68460E-06 -6.1646 0.37147E-06 -6.4301 0.54261E+00 -0.2655 161 S2O3-2 0.28337E-10 -10.5476 0.10701E-11 -11.9706 0.37762E-01 -1.4229 173 ZnCl+ 0.53607E-05 -5.2708 0.28557E-05 -5.5443 0.53271E+00 -0.2735 174 ZnCl2,aq 0.15291E-05 -5.8156 0.15291E-05 -5.8156 0.10000E+01 0.0000 175 ZnCl3- 0.22223E-06 -6.6532 0.11150E-06 -6.9527 0.50171E+00 -0.2995 176 ZnF+ 0.10609E-09 -9.9743 0.56515E-10 -10.2478 0.53271E+00 -0.2735 177 ZnO,aq 0.65681E-09 -9.1826 0.65681E-09 -9.1826 0.10000E+01 0.0000 178 ZnOH+ 0.31765E-06 -6.4981 0.16921E-06 -6.7716 0.53271E+00 -0.2735 Charge balance for all species = -.1293E-03 Total fraction of mixing solution added: 0.0000000 Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.300 AFFINITY: 0.7643E+03 GOLD Q/K: 0.0177 SILVER Q/K: 0.2081 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 199.9700 deg.C Sat. pressure: 100.3665 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2676E+00 0.6367 0.1710E+02 0.2686E+02 CO2,gas 0.7323E+00 0.9068 0.6665E+02 0.7350E+02 CH4,gas 0.2420E-07 1.1419 0.2773E-05 0.2429E-05 H2,gas 0.3267E-05 1.0430 0.3420E-03 0.3279E-03 H2S,gas 0.7333E-05 0.8305 0.6112E-03 0.7360E-03 S2,gas 0.1431E-15 1.0000 0.1436E-13 0.1436E-13 CO,gas 0.5622E-07 1.0000 0.5643E-05 0.5643E-05 SO3,gas 0.1817E-25 1.0000 0.1823E-23 0.1823E-23 O2,gas 0.4724E-04 1.0000 0.4741E-02 0.4741E-02 SO2,gas 0.7910E-12 1.0000 0.7939E-10 0.7939E-10 HF,gas 0.5124E-07 1.0000 0.5143E-05 0.5143E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 122 paragonite -3.40 -2.28 1.12 0.066 -0.24282E+04 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.44 -0.02 -1.47 -1.466 0.31735E+04 1.233 2 CO2,gas -6.49 -7.36 -0.88 -0.292 0.18946E+04 1.824 3 CH4,gas 5.50 -2.76 -8.26 -2.064 0.17874E+05 -5.557 4 H2,gas 7.31 1.14 -6.16 -3.523 0.13347E+05 -3.466 5 H2S,gas -5.67 -11.59 -5.91 -2.956 0.12801E+05 -3.214 6 S2,gas -8.91 -25.45 -16.54 -2.545 0.35812E+05 -13.843 7 CO,gas 1.74 -6.20 -7.95 -2.445 0.17206E+05 -5.249 8 SO3,gas 10.22 -16.21 -26.44 -6.610 0.57236E+05 -23.739 9 O2,gas 36.93 -2.32 -39.25 -26.166 0.84972E+05 -36.550 10 SO2,gas -2.25 -15.05 -12.80 -3.413 0.27709E+05 -10.100 11 HF,gas -0.77 -8.76 -7.99 -3.994 0.17293E+05 -5.289 12 HCl,gas 3.42 -5.75 -9.16 -4.582 0.19839E+05 -9.164 13 acmite 5.98 3.29 -2.69 -0.280 0.58268E+04 17 albite-high -1.58 -2.25 -0.67 -0.051 0.14422E+04 18 albite -2.25 -2.25 0.00 0.000 0.23300E+01 22 analcite 0.78 0.24 -0.54 -0.060 0.11671E+04 23 andalusite -1.42 -2.52 -1.10 -0.110 0.23872E+04 26 anhydrite -6.83 -9.55 -2.72 -1.361 0.58932E+04 27 ankerite -4.15 -4.47 -0.32 -0.054 0.70102E+03 28 annite 11.91 7.12 -4.78 -0.266 0.10349E+05 29 phlogopite 17.57 13.14 -4.43 -0.246 0.95889E+04 31 anorthite 4.24 1.63 -2.61 -0.201 0.56535E+04 34 aragonite -0.17 -0.71 -0.53 -0.178 0.11554E+04 35 brucite 9.50 5.58 -3.92 -0.784 0.84873E+04 36 calcite -0.31 -0.71 -0.39 -0.131 0.85235E+03 37 carnegieite-low 5.15 2.77 -2.38 -0.340 0.51458E+04 38 carnegieite-high 5.83 2.77 -3.05 -0.436 0.66051E+04 39 carpholite-Mg 1.63 0.53 -1.10 -0.073 0.23855E+04 40 carpholite-Fe 0.10 -1.47 -1.57 -0.105 0.34069E+04 41 celadonite 2.39 -0.58 -2.97 -0.175 0.64331E+04 42 celadonite-Fe 1.07 -2.59 -3.66 -0.215 0.79265E+04 45 clinochlore 23.38 20.39 -2.99 -0.093 0.64647E+04 46 daphnite 15.14 10.38 -4.76 -0.149 0.10309E+05 49 chloritoid-Mg 4.76 3.06 -1.70 -0.113 0.36842E+04 50 chloritoid-Fe 1.65 1.06 -0.59 -0.039 0.12826E+04 51 chloritoid-Mn 3.84 1.84 -2.00 -0.134 0.43366E+04 53 coesite -1.83 -2.51 -0.69 -0.229 0.14845E+04 58 corundum 1.19 -0.01 -1.20 -0.109 0.26066E+04 60 cristobalite -2.02 -2.51 -0.49 -0.163 0.10558E+04 63 cymrite-K -0.29 -3.68 -3.39 -0.282 0.73336E+04 65 diaspore -0.10 -0.02 0.08 0.013 -0.17280E+03 66 diamond -2.12 -5.04 -2.92 -0.835 0.63294E+04 67 diopside 11.80 7.24 -4.56 -0.456 0.98744E+04 68 hedenbergite 10.17 5.24 -4.93 -0.493 0.10684E+05 69 dolomite,ordered -1.96 -2.47 -0.51 -0.084 0.10934E+04 70 eastonite 14.03 10.03 -4.00 -0.154 0.86530E+04 75 epidote 13.04 8.78 -4.25 -0.206 0.92011E+04 76 clinozoisite 9.75 5.76 -3.99 -0.181 0.86363E+04 78 fayalite 9.33 4.69 -4.64 -0.663 0.10040E+05 79 ferrosilite 7.10 2.18 -4.92 -0.492 0.10659E+05 83 gibbsite 1.16 -0.04 -1.20 -0.172 0.25997E+04 86 goethite 4.38 3.01 -1.38 -0.297 0.29772E+04 87 graphite -2.50 -5.04 -2.54 -0.725 0.54938E+04 90 halite 1.35 -0.45 -1.80 -0.899 0.38928E+04 91 hematite 8.11 6.04 -2.07 -0.251 0.44746E+04 92 heulandite -9.13 -11.06 -1.93 -0.088 0.41811E+04 93 hercynite 7.24 3.59 -3.65 -0.244 0.79118E+04 96 jadeite 1.60 0.26 -1.34 -0.134 0.28975E+04 98 kalsilite 4.14 1.36 -2.77 -0.396 0.60044E+04 99 kaolinite -5.32 -5.08 0.25 0.023 -0.53861E+03 100 kyanite -1.45 -2.52 -1.07 -0.107 0.23178E+04 102 laumontite -2.02 -3.48 -1.46 -0.097 0.31583E+04 103 lawsonite 3.12 1.58 -1.54 -0.102 0.33236E+04 104 leucite 1.26 -1.15 -2.41 -0.241 0.52114E+04 107 magnesite -0.92 -1.76 -0.84 -0.281 0.18281E+04 108 magnetite 13.11 9.64 -3.47 -0.283 0.75086E+04 114 margarite 3.15 1.59 -1.55 -0.062 0.33615E+04 117 microcline -3.65 -3.66 -0.01 -0.001 0.23007E+02 120 mullite-Si 0.26 -2.52 -2.78 -0.278 0.60224E+04 121 muscovite -4.54 -3.69 0.85 0.050 -0.18467E+04 123 nepheline 4.57 2.77 -1.80 -0.257 0.38966E+04 129 periclase-Fe 8.23 3.60 -4.63 -1.158 0.10029E+05 130 perovskite-Al 4.31 -0.01 -4.32 -0.393 0.93486E+04 135 phlogopite-Na 19.37 14.55 -4.82 -0.268 0.10445E+05 137 prehnite 10.01 5.75 -4.26 -0.250 0.92193E+04 142 px-Ca-tschermaks 9.05 4.14 -4.91 -0.351 0.10634E+05 143 pyrite -19.23 -20.69 -1.47 -0.345 0.31729E+04 144 pyrrhotite -5.01 -7.96 -2.95 -0.983 0.63868E+04 145 pyrrhotiteFe0.875 -6.33 -8.56 -2.23 -0.819 0.48218E+04 146 pyroxmangite 5.39 1.87 -3.52 -0.704 0.76223E+04 147 pyrophyllite -9.51 -10.08 -0.57 -0.035 0.12255E+04 148 quartz -2.32 -2.51 -0.20 -0.065 0.42360E+03 153 rhodochrosite -1.85 -2.98 -1.13 -0.378 0.24524E+04 154 rhodonite 5.42 1.87 -3.54 -0.709 0.76743E+04 155 sanidine -2.69 -3.66 -0.97 -0.074 0.20906E+04 157 siderite -3.54 -3.76 -0.23 -0.075 0.48734E+03 158 sillimanite -1.25 -2.52 -1.27 -0.127 0.27488E+04 160 spinel 10.16 5.59 -4.56 -0.304 0.98760E+04 165 stilbite -8.82 -11.08 -2.26 -0.108 0.48894E+04 166 stilpnomelane-Fe 3.87 -0.29 -4.16 -0.124 0.90026E+04 168 stishovite 2.33 -2.51 -4.84 -1.615 0.10487E+05 169 sudoite-Fe 3.77 -0.44 -4.21 -0.136 0.91185E+04 170 sudoite 6.08 3.57 -2.51 -0.081 0.54411E+04 171 sulfur -8.49 -12.73 -4.24 -1.303 0.91684E+04 172 sylvite 1.39 -1.86 -3.24 -1.622 0.70226E+04 173 talc 11.30 6.75 -4.55 -0.268 0.98551E+04 175 talc-tschermaks 8.61 3.64 -4.96 -0.292 0.10749E+05 180 topaz-H -0.99 -2.54 -1.55 -0.141 0.33602E+04 181 tridymite -2.05 -2.51 -0.46 -0.153 0.99305E+03 184 troilite-low -5.07 -7.96 -2.89 -0.964 0.62612E+04 190 wairakite -1.87 -3.44 -1.57 -0.093 0.34049E+04 191 walstromite 8.87 4.15 -4.72 -0.944 0.10222E+05 192 wollastonite 8.07 4.15 -3.92 -0.784 0.84817E+04 193 pseudo-wollastonite 8.44 4.15 -4.29 -0.858 0.92893E+04 194 zoisite 9.79 5.76 -4.03 -0.183 0.87185E+04 196 argentite -21.92 -22.42 -0.50 -0.126 0.10913E+04 197 arsenic -5.41 -9.59 -4.18 -1.080 0.90599E+04 199 arsenopyrite -13.34 -17.56 -4.21 -0.749 0.91161E+04 200 beidellite-Ca -6.93 -8.15 -1.22 -0.076 0.26498E+04 201 beidellite-H -7.37 -9.25 -1.89 -0.120 0.40816E+04 202 beidellite-K -6.46 -7.97 -1.51 -0.092 0.32692E+04 203 beidellite-Mg -7.17 -8.32 -1.16 -0.071 0.25005E+04 204 beidellite-Na -6.38 -7.50 -1.12 -0.069 0.24310E+04 205 bornite -71.94 -73.86 -1.92 -0.144 0.41603E+04 207 chalcedony -2.17 -2.51 -0.34 -0.114 0.74187E+03 208 chalcocite -21.89 -23.81 -1.92 -0.481 0.41641E+04 210 covellite -16.15 -18.27 -2.12 -0.808 0.45920E+04 211 dawsonite -0.24 -2.10 -1.86 -0.233 0.40359E+04 213 montmorillonite-Ca -5.92 -7.13 -1.20 -0.074 0.26039E+04 214 montmorillonite-K -5.56 -6.94 -1.38 -0.085 0.29960E+04 215 montmorillonite-Mg -6.16 -7.30 -1.14 -0.070 0.24633E+04 216 montmorillonite-Na -5.40 -6.48 -1.08 -0.066 0.23331E+04 217 nontronite-Ca 0.53 -2.10 -2.62 -0.170 0.56826E+04 218 nontronite-H 0.08 -3.20 -3.28 -0.220 0.71057E+04 219 nontronite-K 0.99 -1.92 -2.91 -0.187 0.62998E+04 220 nontronite-Mg 0.31 -2.27 -2.58 -0.168 0.55961E+04 221 nontronite-Na 1.07 -1.45 -2.52 -0.162 0.54659E+04 225 topaz -20.54 -20.01 0.53 0.059 -0.11453E+04 229 gypsum -5.82 -9.60 -3.78 -0.944 0.81776E+04 245 acanthite -21.75 -22.42 -0.68 -0.169 0.14637E+04 251 barite -9.75 -12.45 -2.71 -1.353 0.58577E+04 252 boehmite 0.94 -0.02 -0.96 -0.160 0.20790E+04 253 cerussite -2.86 -5.95 -3.09 -1.030 0.66903E+04 254 chalcopyrite -24.63 -26.23 -1.60 -0.298 0.34726E+04 256 copper,native -1.52 -5.54 -4.03 -1.401 0.87192E+04 257 dolomite,disordered -1.54 -2.47 -0.93 -0.155 0.20136E+04 258 ferrous-oxide 6.76 3.60 -3.16 -0.790 0.68446E+04 259 fluorite -10.33 -10.83 -0.50 -0.166 0.10790E+04 260 galena -10.17 -10.15 0.02 0.008 -0.49976E+02 261 gold,native -13.31 -15.06 -1.75 -0.609 0.37911E+04 262 silver,native -4.17 -4.85 -0.68 -0.237 0.14757E+04 263 huntite -2.48 -5.99 -3.51 -0.292 0.75966E+04 269 silica-amorphous -1.67 -2.51 -0.84 -0.281 0.18266E+04 270 smithsonite -1.93 -5.53 -3.60 -1.201 0.77985E+04 272 sphalerite -9.71 -9.73 -0.03 -0.009 0.55926E+02 273 wurtzite -8.26 -9.73 -1.47 -0.490 0.31801E+04 274 zincite 5.67 1.83 -3.84 -0.961 0.83208E+04 275 an20ab80 -1.17 -1.47 -0.31 -0.024 0.66148E+03 276 an25ab75 -0.87 -1.28 -0.41 -0.032 0.88742E+03 277 an30ab70 -0.57 -1.09 -0.52 -0.040 0.11242E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 70 Temperature = 199.97 C Pressure = 500.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5564E+02 kg liquid = 0.1002E+01 Moles total = 0.5532E+02 kg total = 0.9966E+00 Activity = 0.9513 Stoichiometric ionic strength = .1744195E+01 Osmotic coef. = 0.8983 True ionic strength = .1230110E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.63513E-05 -5.1971 0.29703E-05 -5.5272 0.46766E+00 -0.3301 2 H2O 0.95132E+00 -0.0217 0.95132E+00 -0.0217 3 Cl- 0.12006E+01 0.0794 0.60234E+00 -0.2202 0.50171E+00 -0.2995 4 SO4-- 0.16704E-03 -3.7772 0.66000E-05 -5.1805 0.39511E-01 -1.4033 5 HCO3- 0.26394E-01 -1.5785 0.13823E-01 -1.8594 0.52371E+00 -0.2809 6 HS- 0.17300E-05 -5.7620 0.87206E-06 -6.0595 0.50408E+00 -0.2975 7 H4SiO4 0.27901E-02 -2.5544 0.27901E-02 -2.5544 0.10000E+01 0.0000 8 Al+++ 0.22144E-13 -13.6547 0.11794E-16 -16.9283 0.53261E-03 -3.2736 9 Ca++ 0.12334E-02 -2.9089 0.42355E-04 -4.3731 0.34341E-01 -1.4642 10 Mg++ 0.12190E-03 -3.9140 0.37353E-05 -5.4277 0.30642E-01 -1.5137 11 Fe++ 0.11741E-05 -5.9303 0.37022E-07 -7.4315 0.31533E-01 -1.5012 12 K+ 0.43675E-01 -1.3598 0.23144E-01 -1.6356 0.52991E+00 -0.2758 13 Na+ 0.11812E+01 0.0723 0.59449E+00 -0.2259 0.50329E+00 -0.2982 14 Mn++ 0.69483E-05 -5.1581 0.22376E-06 -6.6502 0.32203E-01 -1.4921 15 Zn++ 0.19937E-07 -7.7003 0.62867E-09 -9.2016 0.31533E-01 -1.5012 16 Cu+ 0.45563E-11 -11.3414 0.22896E-11 -11.6402 0.50251E+00 -0.2989 17 Pb++ 0.65771E-08 -8.1820 0.24157E-09 -9.6170 0.36729E-01 -1.4350 18 Ag+ 0.21641E-10 -10.6647 0.11360E-10 -10.9446 0.52494E+00 -0.2799 19 Au+ 0.12994E-20 -20.8862 0.69221E-21 -21.1598 0.53271E+00 -0.2735 20 Ba++ 0.13913E-05 -5.8566 0.53334E-07 -7.2730 0.38335E-01 -1.4164 21 F- 0.12829E-02 -2.8918 0.59020E-03 -3.2290 0.46006E+00 -0.3372 22 H2AsO3- 0.21325E-05 -5.6711 0.14466E-05 -5.8397 0.67834E+00 -0.1686 24 HSiO3- 0.40467E-05 -5.3929 0.20303E-05 -5.6924 0.50171E+00 -0.2995 25 Ca(HSiO3)+ 0.21168E-07 -7.6743 0.11276E-07 -7.9478 0.53271E+00 -0.2735 26 Mg(HSiO3)+ 0.15529E-08 -8.8089 0.82725E-09 -9.0824 0.53271E+00 -0.2735 27 NaHSiO3,aq 0.94559E-05 -5.0243 0.94559E-05 -5.0243 0.10000E+01 0.0000 31 AgCl,aq 0.39553E-08 -8.4028 0.39553E-08 -8.4028 0.10000E+01 0.0000 32 AgCl2- 0.20537E-06 -6.6875 0.10303E-06 -6.9870 0.50171E+00 -0.2995 33 AgCl3-2 0.17013E-06 -6.7692 0.64245E-08 -8.1922 0.37762E-01 -1.4229 34 AgCl4-3 0.41335E-07 -7.3837 0.21023E-10 -10.6773 0.50860E-03 -3.2936 38 Ag(HS),aq 0.52908E-08 -8.2765 0.52908E-08 -8.2765 0.10000E+01 0.0000 40 AlO+ 0.15284E-09 -9.8158 0.81420E-10 -10.0893 0.53271E+00 -0.2735 42 HAlO2,aq 0.54084E-07 -7.2669 0.54084E-07 -7.2669 0.10000E+01 0.0000 43 AlO2- 0.96165E-06 -6.0170 0.44876E-06 -6.3480 0.46666E+00 -0.3310 44 AsO2- 0.29430E-06 -6.5312 0.14766E-06 -6.8307 0.50171E+00 -0.2995 45 HAsO2,aq 0.31556E-04 -4.5009 0.31556E-04 -4.5009 0.10000E+01 0.0000 46 H3AsO3,aq 0.95348E-04 -4.0207 0.95348E-04 -4.0207 0.10000E+01 0.0000 48 H2AsO4- 0.17613E-09 -9.7542 0.88364E-10 -10.0537 0.50171E+00 -0.2995 49 HAsO4-2 0.49961E-10 -10.3014 0.18866E-11 -11.7243 0.37762E-01 -1.4229 62 BaCO3,aq 0.57491E-09 -9.2404 0.57491E-09 -9.2404 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.17350E-05 -5.7607 0.94665E-06 -6.0238 0.54562E+00 -0.2631 64 BaCl+ 0.92688E-06 -6.0330 0.49376E-06 -6.3065 0.53271E+00 -0.2735 65 BaF+ 0.97323E-09 -9.0118 0.51845E-09 -9.2853 0.53271E+00 -0.2735 66 CH4,aq 0.20588E-08 -8.6864 0.19006E-08 -8.7211 0.92316E+00 -0.0347 71 CO,aq 0.54996E-08 -8.2597 0.54996E-08 -8.2597 0.10000E+01 0.0000 72 CO2,aq 0.32247E+00 -0.4915 0.29769E+00 -0.5262 0.92316E+00 -0.0347 73 CO3-2 0.79419E-05 -5.1001 0.29990E-06 -6.5230 0.37762E-01 -1.4229 74 CaCO3,aq 0.18134E-05 -5.7415 0.18134E-05 -5.7415 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.20031E-03 -3.6983 0.10670E-03 -3.9718 0.53271E+00 -0.2735 76 CaCl+ 0.60109E-03 -3.2211 0.32021E-03 -3.4946 0.53271E+00 -0.2735 77 CaCl2,aq 0.57169E-04 -4.2428 0.57169E-04 -4.2428 0.10000E+01 0.0000 78 CaF+ 0.56897E-05 -5.2449 0.30309E-05 -5.5184 0.53271E+00 -0.2735 79 CaOH+ 0.26573E-06 -6.5756 0.14155E-06 -6.8491 0.53271E+00 -0.2735 80 CaSO4,aq 0.45412E-06 -6.3428 0.45412E-06 -6.3428 0.10000E+01 0.0000 81 HCl,aq 0.12718E-05 -5.8956 0.12718E-05 -5.8956 0.10000E+01 0.0000 90 CuCl,aq 0.66157E-08 -8.1794 0.66157E-08 -8.1794 0.10000E+01 0.0000 91 CuCl2- 0.13030E-06 -6.8850 0.65374E-07 -7.1846 0.50171E+00 -0.2995 92 CuCl3-2 0.32829E-07 -7.4837 0.12397E-08 -8.9067 0.37762E-01 -1.4229 98 HF,aq 0.85801E-04 -4.0665 0.85801E-04 -4.0665 0.10000E+01 0.0000 99 HF2- 0.27737E-07 -7.5569 0.13916E-07 -7.8565 0.50171E+00 -0.2995 101 FeCl+ 0.38065E-06 -6.4195 0.20278E-06 -6.6930 0.53271E+00 -0.2735 102 FeCl2,aq 0.67921E-08 -8.1680 0.67921E-08 -8.1680 0.10000E+01 0.0000 104 FeF+ 0.92837E-08 -8.0323 0.49455E-08 -8.3058 0.53271E+00 -0.2735 106 FeO,aq 0.31727E-09 -9.4986 0.31727E-09 -9.4986 0.10000E+01 0.0000 107 FeOH+ 0.28063E-07 -7.5519 0.14950E-07 -7.8254 0.53271E+00 -0.2735 108 HFeO2- 0.10481E-10 -10.9796 0.52585E-11 -11.2791 0.50171E+00 -0.2995 111 FeO2- 0.29449E-10 -10.5309 0.14775E-10 -10.8305 0.50171E+00 -0.2995 112 HFeO2,aq 0.22575E-09 -9.6464 0.22575E-09 -9.6464 0.10000E+01 0.0000 113 H2,aq 0.39504E-06 -6.4034 0.36469E-06 -6.4381 0.92316E+00 -0.0347 114 KCl,aq 0.16520E-02 -2.7820 0.16520E-02 -2.7820 0.10000E+01 0.0000 115 KHSO4,aq 0.33729E-09 -9.4720 0.33729E-09 -9.4720 0.10000E+01 0.0000 116 KOH,aq 0.91136E-07 -7.0403 0.91136E-07 -7.0403 0.10000E+01 0.0000 117 KSO4- 0.20105E-04 -4.6967 0.10087E-04 -4.9962 0.50171E+00 -0.2995 118 MgCO3,aq 0.21134E-07 -7.6750 0.21134E-07 -7.6750 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.16948E-04 -4.7709 0.90284E-05 -5.0444 0.53271E+00 -0.2735 120 MgCl+ 0.30932E-04 -4.5096 0.16478E-04 -4.7831 0.53271E+00 -0.2735 121 MgF+ 0.14775E-05 -5.8305 0.78707E-06 -6.1040 0.53271E+00 -0.2735 122 MgOH+ 0.80701E-07 -7.0931 0.42990E-07 -7.3666 0.53271E+00 -0.2735 124 MnF+ 0.22751E-07 -7.6430 0.12120E-07 -7.9165 0.53271E+00 -0.2735 125 MnO,aq 0.59944E-10 -10.2223 0.59944E-10 -10.2223 0.10000E+01 0.0000 126 MnOH+ 0.22669E-07 -7.6446 0.12076E-07 -7.9181 0.53271E+00 -0.2735 131 MnCl+ 0.27398E-04 -4.5623 0.14595E-04 -4.8358 0.53271E+00 -0.2735 132 MnSO4,aq 0.28380E-08 -8.5470 0.28380E-08 -8.5470 0.10000E+01 0.0000 133 NaCl,aq 0.33870E+00 -0.4702 0.33870E+00 -0.4702 0.10000E+01 0.0000 134 NaF,aq 0.25059E-03 -3.6010 0.25059E-03 -3.6010 0.10000E+01 0.0000 135 NaOH,aq 0.16727E-05 -5.7766 0.16727E-05 -5.7766 0.10000E+01 0.0000 137 OH- 0.56282E-05 -5.2496 0.26265E-05 -5.5806 0.46666E+00 -0.3310 140 PbCl+ 0.84553E-07 -7.0729 0.45042E-07 -7.3464 0.53271E+00 -0.2735 141 PbCl2,aq 0.43281E-06 -6.3637 0.43281E-06 -6.3637 0.10000E+01 0.0000 142 PbCl3- 0.38691E-06 -6.4124 0.19412E-06 -6.7119 0.50171E+00 -0.2995 143 PbCl4-2 0.64994E-06 -6.1871 0.24543E-07 -7.6101 0.37762E-01 -1.4229 144 PbF+ 0.11491E-09 -9.9397 0.61211E-10 -10.2132 0.53271E+00 -0.2735 146 PbO,aq 0.11175E-09 -9.9517 0.11175E-09 -9.9517 0.10000E+01 0.0000 148 Pb(HS)2,aq 0.27107E-09 -9.5669 0.27107E-09 -9.5669 0.10000E+01 0.0000 150 H2S,aq 0.12159E-04 -4.9151 0.11224E-04 -4.9498 0.92316E+00 -0.0347 158 HSO3- 0.36165E-09 -9.4417 0.18144E-09 -9.7413 0.50171E+00 -0.2995 159 HSO4- 0.68458E-06 -6.1646 0.37146E-06 -6.4301 0.54261E+00 -0.2655 161 S2O3-2 0.28337E-10 -10.5476 0.10700E-11 -11.9706 0.37762E-01 -1.4229 173 ZnCl+ 0.53607E-05 -5.2708 0.28557E-05 -5.5443 0.53271E+00 -0.2735 174 ZnCl2,aq 0.15291E-05 -5.8156 0.15291E-05 -5.8156 0.10000E+01 0.0000 175 ZnCl3- 0.22223E-06 -6.6532 0.11150E-06 -6.9527 0.50171E+00 -0.2995 176 ZnF+ 0.10609E-09 -9.9743 0.56515E-10 -10.2478 0.53271E+00 -0.2735 177 ZnO,aq 0.65686E-09 -9.1825 0.65686E-09 -9.1825 0.10000E+01 0.0000 178 ZnOH+ 0.31766E-06 -6.4980 0.16922E-06 -6.7716 0.53271E+00 -0.2735 Charge balance for all species = -.1293E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6351315E-05 0.3226674E+00 0.2936290E+03 0.0000 2 H2O 0.1000000E+01 0.5518575E+02 0.8975892E+06 0.0000 3 Cl- 0.1200569E+01 0.1541709E+01 0.4934745E+05 5.3070 4 SO4-- 0.1670438E-03 0.1881888E-03 0.1632122E+02 5.8740 5 HCO3- 0.2639386E-01 0.3490923E+00 0.1923100E+05 3.6678 6 HS- 0.1729995E-05 0.1399680E-04 0.4179252E+00 -0.5323 7 H4SiO4 0.2790115E-02 0.2803640E-02 0.2432901E+03 -2.5544 8 Al+++ 0.2214427E-13 0.1015889E-05 0.2474695E-01 -0.3467 9 Ca++ 0.1233382E-02 0.2100196E-02 0.7599325E+02 6.6813 10 Mg++ 0.1219012E-03 0.1713622E-03 0.3761360E+01 5.6267 11 Fe++ 0.1174096E-05 0.1599476E-05 0.8064674E-01 3.6229 12 K+ 0.4367533E-01 0.4534756E-01 0.1600892E+04 3.8916 13 Na+ 0.1181201E+01 0.1520159E+01 0.3155247E+05 5.3013 14 Mn++ 0.6948269E-05 0.3439479E-04 0.1705983E+01 4.4042 15 Zn++ 0.1993722E-07 0.7450341E-05 0.4397075E+00 1.8528 16 Cu+ 0.4556341E-11 0.1697508E-06 0.9737964E-02 -6.1130 17 Pb++ 0.6577074E-08 0.1561283E-05 0.2920516E+00 1.4374 18 Ag+ 0.2164090E-10 0.4261080E-06 0.4149823E-01 -5.4174 19 Au+ 0.1299426E-20 0.3103531E-11 0.5518980E-06 -15.6326 20 Ba++ 0.1391255E-05 0.4054694E-05 0.5027641E+00 3.7814 21 F- 0.1282861E-02 0.1626506E-02 0.2789799E+02 2.2982 22 H2AsO3- 0.2132473E-05 0.1293304E-03 0.1458802E+02 -0.3125 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234398E+00 -.4629859E-05 0.0000000E+00 2 H2O 0.5531785E+02 0.5531785E+02 0.0000000E+00 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1403031E-04 0.0000000E+00 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810352E-02 0.1388958E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.1018321E-05 0.1388958E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.4629859E-06 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.7468176E-05 0.0000000E+00 0.0000000E+00 16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00 17 Pb++ 0.1565021E-05 0.1565021E-05 0.0000000E+00 0.0000000E+00 18 Ag+ 0.4271281E-06 0.4271281E-06 0.0000000E+00 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1630400E-02 0.0000000E+00 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.3706E-21 Mass of aqueous solution: 0.111027E+04 g Temperature = 199.97 C Pressure = 500.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) paragonite 0.4630E-06 -6.334 0.1770E-03 -3.752 100.0 0.6117E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.0000000 Solid products produced: Mass = 0.000177 g Volume = 0.000061 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.300 AFFINITY: 0.7642E+03 GOLD Q/K: 0.0177 SILVER Q/K: 0.2081 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 199.9700 deg.C Sat. pressure: 100.3663 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2676E+00 0.6367 0.1710E+02 0.2686E+02 CO2,gas 0.7323E+00 0.9068 0.6665E+02 0.7350E+02 CH4,gas 0.2420E-07 1.1419 0.2773E-05 0.2429E-05 H2,gas 0.3267E-05 1.0430 0.3420E-03 0.3279E-03 H2S,gas 0.7333E-05 0.8305 0.6112E-03 0.7360E-03 S2,gas 0.1431E-15 1.0000 0.1436E-13 0.1436E-13 CO,gas 0.5622E-07 1.0000 0.5643E-05 0.5643E-05 SO3,gas 0.1816E-25 1.0000 0.1823E-23 0.1823E-23 O2,gas 0.4724E-04 1.0000 0.4741E-02 0.4741E-02 SO2,gas 0.7910E-12 1.0000 0.7939E-10 0.7939E-10 HF,gas 0.5124E-07 1.0000 0.5143E-05 0.5143E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 122 paragonite -3.40 -3.40 0.00 0.000 -0.22113E-10 260 galena -10.17 -10.15 0.02 0.008 -0.50037E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.44 -0.02 -1.47 -1.466 0.31735E+04 1.233 2 CO2,gas -6.49 -7.36 -0.88 -0.292 0.18946E+04 1.824 3 CH4,gas 5.50 -2.76 -8.26 -2.064 0.17873E+05 -5.557 4 H2,gas 7.31 1.14 -6.16 -3.523 0.13347E+05 -3.466 5 H2S,gas -5.67 -11.59 -5.91 -2.956 0.12801E+05 -3.214 6 S2,gas -8.91 -25.45 -16.54 -2.545 0.35812E+05 -13.843 7 CO,gas 1.74 -6.20 -7.95 -2.445 0.17206E+05 -5.249 8 SO3,gas 10.22 -16.21 -26.44 -6.610 0.57237E+05 -23.739 9 O2,gas 36.93 -2.32 -39.25 -26.166 0.84972E+05 -36.550 10 SO2,gas -2.25 -15.05 -12.80 -3.413 0.27709E+05 -10.100 11 HF,gas -0.77 -8.76 -7.99 -3.994 0.17293E+05 -5.289 12 HCl,gas 3.42 -5.75 -9.16 -4.582 0.19839E+05 -9.164 13 acmite 5.98 3.29 -2.69 -0.280 0.58276E+04 17 albite-high -1.58 -2.62 -1.04 -0.080 0.22525E+04 18 albite -2.25 -2.62 -0.38 -0.029 0.81263E+03 22 analcite 0.78 -0.13 -0.91 -0.101 0.19769E+04 23 andalusite -1.42 -3.27 -1.85 -0.185 0.40055E+04 26 anhydrite -6.83 -9.55 -2.72 -1.361 0.58932E+04 27 ankerite -4.15 -4.47 -0.32 -0.054 0.70089E+03 29 phlogopite 17.57 12.76 -4.80 -0.267 0.10399E+05 31 anorthite 4.24 0.88 -3.36 -0.258 0.72722E+04 34 aragonite -0.17 -0.71 -0.53 -0.178 0.11554E+04 35 brucite 9.50 5.58 -3.92 -0.784 0.84872E+04 36 calcite -0.31 -0.71 -0.39 -0.131 0.85229E+03 37 carnegieite-low 5.15 2.40 -2.75 -0.393 0.59552E+04 38 carnegieite-high 5.83 2.40 -3.42 -0.489 0.74145E+04 39 carpholite-Mg 1.63 -0.22 -1.85 -0.123 0.40043E+04 40 carpholite-Fe 0.10 -2.22 -2.32 -0.155 0.50257E+04 41 celadonite 2.39 -0.96 -3.35 -0.197 0.72438E+04 42 celadonite-Fe 1.07 -2.96 -4.04 -0.237 0.87372E+04 45 clinochlore 23.38 19.65 -3.73 -0.117 0.80836E+04 49 chloritoid-Mg 4.76 2.31 -2.45 -0.163 0.53025E+04 50 chloritoid-Fe 1.65 0.31 -1.34 -0.089 0.29008E+04 51 chloritoid-Mn 3.84 1.09 -2.75 -0.183 0.59549E+04 53 coesite -1.83 -2.51 -0.69 -0.229 0.14849E+04 58 corundum 1.19 -0.76 -1.95 -0.177 0.42245E+04 60 cristobalite -2.02 -2.51 -0.49 -0.163 0.10563E+04 63 cymrite-K -0.29 -4.05 -3.76 -0.313 0.81439E+04 65 diaspore -0.10 -0.39 -0.29 -0.049 0.63614E+03 66 diamond -2.12 -5.04 -2.92 -0.835 0.63294E+04 67 diopside 11.80 7.24 -4.56 -0.456 0.98752E+04 68 hedenbergite 10.17 5.24 -4.94 -0.494 0.10684E+05 69 dolomite,ordered -1.96 -2.47 -0.50 -0.084 0.10933E+04 75 epidote 13.04 8.04 -5.00 -0.242 0.10820E+05 78 fayalite 9.33 4.69 -4.64 -0.663 0.10041E+05 79 ferrosilite 7.10 2.18 -4.92 -0.492 0.10659E+05 83 gibbsite 1.16 -0.41 -1.57 -0.225 0.34086E+04 86 goethite 4.38 3.01 -1.38 -0.297 0.29772E+04 87 graphite -2.50 -5.04 -2.54 -0.725 0.54937E+04 90 halite 1.35 -0.45 -1.80 -0.899 0.38928E+04 91 hematite 8.11 6.04 -2.07 -0.251 0.44745E+04 92 heulandite -9.13 -11.81 -2.68 -0.122 0.58022E+04 93 hercynite 7.24 2.84 -4.40 -0.293 0.95296E+04 96 jadeite 1.60 -0.11 -1.71 -0.171 0.37074E+04 98 kalsilite 4.14 0.99 -3.15 -0.450 0.68138E+04 99 kaolinite -5.32 -5.82 -0.50 -0.045 0.10802E+04 100 kyanite -1.45 -3.27 -1.82 -0.182 0.39362E+04 102 laumontite -2.02 -4.23 -2.21 -0.147 0.47780E+04 103 lawsonite 3.12 0.84 -2.28 -0.152 0.49423E+04 104 leucite 1.26 -1.52 -2.78 -0.278 0.60212E+04 107 magnesite -0.92 -1.76 -0.84 -0.281 0.18280E+04 108 magnetite 13.11 9.64 -3.47 -0.283 0.75085E+04 114 margarite 3.15 0.10 -3.05 -0.122 0.65981E+04 117 microcline -3.65 -4.03 -0.38 -0.030 0.83330E+03 120 mullite-Si 0.26 -3.27 -3.53 -0.353 0.76407E+04 121 muscovite -4.54 -4.81 -0.27 -0.016 0.58149E+03 123 nepheline 4.57 2.40 -2.17 -0.311 0.47059E+04 129 periclase-Fe 8.23 3.60 -4.63 -1.158 0.10029E+05 143 pyrite -19.23 -20.69 -1.47 -0.345 0.31729E+04 144 pyrrhotite -5.01 -7.96 -2.95 -0.983 0.63867E+04 145 pyrrhotiteFe0.875 -6.33 -8.56 -2.23 -0.819 0.48218E+04 146 pyroxmangite 5.39 1.87 -3.52 -0.704 0.76227E+04 147 pyrophyllite -9.51 -10.82 -1.31 -0.082 0.28452E+04 148 quartz -2.32 -2.51 -0.20 -0.065 0.42407E+03 153 rhodochrosite -1.85 -2.98 -1.13 -0.378 0.24523E+04 154 rhodonite 5.42 1.87 -3.55 -0.709 0.76747E+04 155 sanidine -2.69 -4.03 -1.34 -0.103 0.29009E+04 157 siderite -3.54 -3.76 -0.23 -0.075 0.48728E+03 158 sillimanite -1.25 -3.27 -2.02 -0.202 0.43671E+04 165 stilbite -8.82 -11.83 -3.01 -0.143 0.65105E+04 166 stilpnomelane-Fe 3.87 -1.04 -4.91 -0.146 0.10624E+05 168 stishovite 2.33 -2.51 -4.84 -1.615 0.10487E+05 170 sudoite 6.08 2.07 -4.01 -0.129 0.86781E+04 171 sulfur -8.49 -12.73 -4.24 -1.303 0.91685E+04 172 sylvite 1.39 -1.86 -3.24 -1.622 0.70226E+04 173 talc 11.30 6.75 -4.55 -0.268 0.98568E+04 180 topaz-H -0.99 -3.29 -2.30 -0.209 0.49785E+04 181 tridymite -2.05 -2.51 -0.46 -0.153 0.99352E+03 184 troilite-low -5.07 -7.96 -2.89 -0.964 0.62611E+04 190 wairakite -1.87 -4.19 -2.32 -0.137 0.50246E+04 191 walstromite 8.87 4.15 -4.72 -0.944 0.10223E+05 192 wollastonite 8.07 4.15 -3.92 -0.784 0.84822E+04 193 pseudo-wollastonite 8.44 4.15 -4.29 -0.858 0.92897E+04 196 argentite -21.92 -22.42 -0.50 -0.126 0.10913E+04 197 arsenic -5.41 -9.59 -4.18 -1.080 0.90599E+04 199 arsenopyrite -13.34 -17.56 -4.21 -0.749 0.91160E+04 200 beidellite-Ca -6.93 -9.02 -2.10 -0.130 0.45364E+04 201 beidellite-H -7.37 -10.12 -2.76 -0.176 0.59681E+04 202 beidellite-K -6.46 -8.84 -2.38 -0.146 0.51557E+04 203 beidellite-Mg -7.17 -9.20 -2.03 -0.125 0.43870E+04 204 beidellite-Na -6.38 -8.37 -1.99 -0.122 0.43175E+04 205 bornite -71.94 -73.86 -1.92 -0.144 0.41601E+04 207 chalcedony -2.17 -2.51 -0.34 -0.114 0.74233E+03 208 chalcocite -21.89 -23.81 -1.92 -0.481 0.41640E+04 210 covellite -16.15 -18.27 -2.12 -0.808 0.45920E+04 211 dawsonite -0.24 -2.48 -2.24 -0.280 0.48448E+04 213 montmorillonite-Ca -5.92 -7.75 -1.83 -0.113 0.39567E+04 214 montmorillonite-K -5.56 -7.57 -2.01 -0.123 0.43488E+04 215 montmorillonite-Mg -6.16 -7.92 -1.76 -0.109 0.38160E+04 216 montmorillonite-Na -5.40 -7.10 -1.70 -0.104 0.36859E+04 217 nontronite-Ca 0.53 -2.22 -2.75 -0.178 0.59512E+04 218 nontronite-H 0.08 -3.33 -3.41 -0.228 0.73743E+04 219 nontronite-K 0.99 -2.04 -3.03 -0.195 0.65683E+04 220 nontronite-Mg 0.31 -2.40 -2.71 -0.176 0.58646E+04 221 nontronite-Na 1.07 -1.58 -2.65 -0.170 0.57345E+04 225 topaz -20.54 -20.76 -0.22 -0.024 0.47311E+03 229 gypsum -5.82 -9.60 -3.78 -0.944 0.81776E+04 245 acanthite -21.75 -22.42 -0.68 -0.169 0.14637E+04 251 barite -9.75 -12.45 -2.71 -1.353 0.58577E+04 252 boehmite 0.94 -0.39 -1.33 -0.222 0.28879E+04 253 cerussite -2.86 -5.95 -3.09 -1.030 0.66902E+04 254 chalcopyrite -24.63 -26.23 -1.60 -0.298 0.34725E+04 256 copper,native -1.52 -5.54 -4.03 -1.401 0.87191E+04 257 dolomite,disordered -1.54 -2.47 -0.93 -0.155 0.20135E+04 258 ferrous-oxide 6.76 3.60 -3.16 -0.790 0.68445E+04 259 fluorite -10.33 -10.83 -0.50 -0.166 0.10790E+04 261 gold,native -13.31 -15.06 -1.75 -0.609 0.37911E+04 262 silver,native -4.17 -4.85 -0.68 -0.237 0.14757E+04 263 huntite -2.48 -5.98 -3.51 -0.292 0.75964E+04 269 silica-amorphous -1.67 -2.51 -0.84 -0.281 0.18271E+04 270 smithsonite -1.93 -5.53 -3.60 -1.201 0.77984E+04 272 sphalerite -9.71 -9.73 -0.03 -0.009 0.55866E+02 273 wurtzite -8.26 -9.73 -1.47 -0.490 0.31800E+04 274 zincite 5.67 1.83 -3.84 -0.961 0.83208E+04 275 an20ab80 -1.17 -1.92 -0.75 -0.058 0.16335E+04 276 an25ab75 -0.87 -1.75 -0.88 -0.068 0.18998E+04 277 an30ab70 -0.57 -1.57 -1.01 -0.077 0.21770E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 70 Temperature = 199.97 C Pressure = 500.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.5564E+02 kg liquid = 0.1002E+01 Moles total = 0.5532E+02 kg total = 0.9966E+00 Activity = 0.9513 Stoichiometric ionic strength = .1744195E+01 Osmotic coef. = 0.8983 True ionic strength = .1230110E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.63514E-05 -5.1971 0.29703E-05 -5.5272 0.46766E+00 -0.3301 2 H2O 0.95132E+00 -0.0217 0.95132E+00 -0.0217 3 Cl- 0.12006E+01 0.0794 0.60234E+00 -0.2202 0.50171E+00 -0.2995 4 SO4-- 0.16704E-03 -3.7772 0.66000E-05 -5.1805 0.39511E-01 -1.4033 5 HCO3- 0.26394E-01 -1.5785 0.13823E-01 -1.8594 0.52371E+00 -0.2809 6 HS- 0.17209E-05 -5.7642 0.86747E-06 -6.0617 0.50408E+00 -0.2975 7 H4SiO4 0.27901E-02 -2.5544 0.27901E-02 -2.5544 0.10000E+01 0.0000 8 Al+++ 0.22145E-13 -13.6547 0.11795E-16 -16.9283 0.53261E-03 -3.2736 9 Ca++ 0.12334E-02 -2.9089 0.42355E-04 -4.3731 0.34341E-01 -1.4642 10 Mg++ 0.12190E-03 -3.9140 0.37353E-05 -5.4277 0.30642E-01 -1.5137 11 Fe++ 0.11741E-05 -5.9303 0.37022E-07 -7.4315 0.31533E-01 -1.5012 12 K+ 0.43675E-01 -1.3598 0.23144E-01 -1.6356 0.52991E+00 -0.2758 13 Na+ 0.11812E+01 0.0723 0.59449E+00 -0.2259 0.50329E+00 -0.2982 14 Mn++ 0.69483E-05 -5.1581 0.22376E-06 -6.6502 0.32203E-01 -1.4921 15 Zn++ 0.19937E-07 -7.7003 0.62867E-09 -9.2016 0.31533E-01 -1.5012 16 Cu+ 0.45563E-11 -11.3414 0.22896E-11 -11.6402 0.50251E+00 -0.2989 17 Pb++ 0.62692E-08 -8.2028 0.23026E-09 -9.6378 0.36729E-01 -1.4350 18 Ag+ 0.21642E-10 -10.6647 0.11361E-10 -10.9446 0.52494E+00 -0.2799 19 Au+ 0.13061E-20 -20.8840 0.69577E-21 -21.1575 0.53271E+00 -0.2735 20 Ba++ 0.13913E-05 -5.8566 0.53334E-07 -7.2730 0.38335E-01 -1.4164 21 F- 0.12829E-02 -2.8918 0.59020E-03 -3.2290 0.46006E+00 -0.3372 22 H2AsO3- 0.21325E-05 -5.6711 0.14465E-05 -5.8397 0.67834E+00 -0.1686 24 HSiO3- 0.40466E-05 -5.3929 0.20302E-05 -5.6925 0.50171E+00 -0.2995 25 Ca(HSiO3)+ 0.21168E-07 -7.6743 0.11276E-07 -7.9478 0.53271E+00 -0.2735 26 Mg(HSiO3)+ 0.15529E-08 -8.8089 0.82725E-09 -9.0824 0.53271E+00 -0.2735 27 NaHSiO3,aq 0.94558E-05 -5.0243 0.94558E-05 -5.0243 0.10000E+01 0.0000 31 AgCl,aq 0.39556E-08 -8.4028 0.39556E-08 -8.4028 0.10000E+01 0.0000 32 AgCl2- 0.20538E-06 -6.6874 0.10304E-06 -6.9870 0.50171E+00 -0.2995 33 AgCl3-2 0.17014E-06 -6.7692 0.64249E-08 -8.1921 0.37762E-01 -1.4229 34 AgCl4-3 0.41338E-07 -7.3837 0.21025E-10 -10.6773 0.50860E-03 -3.2936 38 Ag(HS),aq 0.52634E-08 -8.2787 0.52634E-08 -8.2787 0.10000E+01 0.0000 40 AlO+ 0.15284E-09 -9.8158 0.81421E-10 -10.0893 0.53271E+00 -0.2735 42 HAlO2,aq 0.54084E-07 -7.2669 0.54084E-07 -7.2669 0.10000E+01 0.0000 43 AlO2- 0.96165E-06 -6.0170 0.44876E-06 -6.3480 0.46666E+00 -0.3310 44 AsO2- 0.29430E-06 -6.5312 0.14765E-06 -6.8308 0.50171E+00 -0.2995 45 HAsO2,aq 0.31556E-04 -4.5009 0.31556E-04 -4.5009 0.10000E+01 0.0000 46 H3AsO3,aq 0.95348E-04 -4.0207 0.95348E-04 -4.0207 0.10000E+01 0.0000 48 H2AsO4- 0.17636E-09 -9.7536 0.88480E-10 -10.0532 0.50171E+00 -0.2995 49 HAsO4-2 0.50026E-10 -10.3008 0.18891E-11 -11.7238 0.37762E-01 -1.4229 62 BaCO3,aq 0.57490E-09 -9.2404 0.57490E-09 -9.2404 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.17350E-05 -5.7607 0.94665E-06 -6.0238 0.54562E+00 -0.2631 64 BaCl+ 0.92688E-06 -6.0330 0.49376E-06 -6.3065 0.53271E+00 -0.2735 65 BaF+ 0.97324E-09 -9.0118 0.51845E-09 -9.2853 0.53271E+00 -0.2735 66 CH4,aq 0.20479E-08 -8.6887 0.18906E-08 -8.7234 0.92316E+00 -0.0347 71 CO,aq 0.54924E-08 -8.2602 0.54924E-08 -8.2602 0.10000E+01 0.0000 72 CO2,aq 0.32247E+00 -0.4915 0.29769E+00 -0.5262 0.92316E+00 -0.0347 73 CO3-2 0.79418E-05 -5.1001 0.29989E-06 -6.5230 0.37762E-01 -1.4229 74 CaCO3,aq 0.18134E-05 -5.7415 0.18134E-05 -5.7415 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.20031E-03 -3.6983 0.10670E-03 -3.9718 0.53271E+00 -0.2735 76 CaCl+ 0.60109E-03 -3.2211 0.32021E-03 -3.4946 0.53271E+00 -0.2735 77 CaCl2,aq 0.57169E-04 -4.2428 0.57169E-04 -4.2428 0.10000E+01 0.0000 78 CaF+ 0.56897E-05 -5.2449 0.30309E-05 -5.5184 0.53271E+00 -0.2735 79 CaOH+ 0.26573E-06 -6.5756 0.14155E-06 -6.8491 0.53271E+00 -0.2735 80 CaSO4,aq 0.45412E-06 -6.3428 0.45412E-06 -6.3428 0.10000E+01 0.0000 81 HCl,aq 0.12718E-05 -5.8956 0.12718E-05 -5.8956 0.10000E+01 0.0000 90 CuCl,aq 0.66157E-08 -8.1794 0.66157E-08 -8.1794 0.10000E+01 0.0000 91 CuCl2- 0.13030E-06 -6.8850 0.65374E-07 -7.1846 0.50171E+00 -0.2995 92 CuCl3-2 0.32829E-07 -7.4837 0.12397E-08 -8.9067 0.37762E-01 -1.4229 98 HF,aq 0.85802E-04 -4.0665 0.85802E-04 -4.0665 0.10000E+01 0.0000 99 HF2- 0.27737E-07 -7.5569 0.13916E-07 -7.8565 0.50171E+00 -0.2995 101 FeCl+ 0.38065E-06 -6.4195 0.20278E-06 -6.6930 0.53271E+00 -0.2735 102 FeCl2,aq 0.67922E-08 -8.1680 0.67922E-08 -8.1680 0.10000E+01 0.0000 104 FeF+ 0.92837E-08 -8.0323 0.49455E-08 -8.3058 0.53271E+00 -0.2735 106 FeO,aq 0.31727E-09 -9.4986 0.31727E-09 -9.4986 0.10000E+01 0.0000 107 FeOH+ 0.28063E-07 -7.5519 0.14950E-07 -7.8254 0.53271E+00 -0.2735 108 HFeO2- 0.10481E-10 -10.9796 0.52584E-11 -11.2791 0.50171E+00 -0.2995 111 FeO2- 0.29468E-10 -10.5307 0.14784E-10 -10.8302 0.50171E+00 -0.2995 112 HFeO2,aq 0.22590E-09 -9.6461 0.22590E-09 -9.6461 0.10000E+01 0.0000 113 H2,aq 0.39452E-06 -6.4039 0.36421E-06 -6.4387 0.92316E+00 -0.0347 114 KCl,aq 0.16520E-02 -2.7820 0.16520E-02 -2.7820 0.10000E+01 0.0000 115 KHSO4,aq 0.33729E-09 -9.4720 0.33729E-09 -9.4720 0.10000E+01 0.0000 116 KOH,aq 0.91135E-07 -7.0403 0.91135E-07 -7.0403 0.10000E+01 0.0000 117 KSO4- 0.20105E-04 -4.6967 0.10087E-04 -4.9962 0.50171E+00 -0.2995 118 MgCO3,aq 0.21134E-07 -7.6750 0.21134E-07 -7.6750 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.16948E-04 -4.7709 0.90284E-05 -5.0444 0.53271E+00 -0.2735 120 MgCl+ 0.30932E-04 -4.5096 0.16478E-04 -4.7831 0.53271E+00 -0.2735 121 MgF+ 0.14775E-05 -5.8305 0.78708E-06 -6.1040 0.53271E+00 -0.2735 122 MgOH+ 0.80701E-07 -7.0931 0.42990E-07 -7.3666 0.53271E+00 -0.2735 124 MnF+ 0.22751E-07 -7.6430 0.12120E-07 -7.9165 0.53271E+00 -0.2735 125 MnO,aq 0.59944E-10 -10.2223 0.59944E-10 -10.2223 0.10000E+01 0.0000 126 MnOH+ 0.22669E-07 -7.6446 0.12076E-07 -7.9181 0.53271E+00 -0.2735 131 MnCl+ 0.27398E-04 -4.5623 0.14595E-04 -4.8358 0.53271E+00 -0.2735 132 MnSO4,aq 0.28380E-08 -8.5470 0.28380E-08 -8.5470 0.10000E+01 0.0000 133 NaCl,aq 0.33870E+00 -0.4702 0.33870E+00 -0.4702 0.10000E+01 0.0000 134 NaF,aq 0.25059E-03 -3.6010 0.25059E-03 -3.6010 0.10000E+01 0.0000 135 NaOH,aq 0.16727E-05 -5.7766 0.16727E-05 -5.7766 0.10000E+01 0.0000 137 OH- 0.56282E-05 -5.2496 0.26265E-05 -5.5806 0.46666E+00 -0.3310 140 PbCl+ 0.80595E-07 -7.0937 0.42933E-07 -7.3672 0.53271E+00 -0.2735 141 PbCl2,aq 0.41255E-06 -6.3845 0.41255E-06 -6.3845 0.10000E+01 0.0000 142 PbCl3- 0.36880E-06 -6.4332 0.18503E-06 -6.7328 0.50171E+00 -0.2995 143 PbCl4-2 0.61951E-06 -6.2080 0.23394E-07 -7.6309 0.37762E-01 -1.4229 144 PbF+ 0.10953E-09 -9.9605 0.58346E-10 -10.2340 0.53271E+00 -0.2735 146 PbO,aq 0.10652E-09 -9.9726 0.10652E-09 -9.9726 0.10000E+01 0.0000 148 Pb(HS)2,aq 0.25568E-09 -9.5923 0.25568E-09 -9.5923 0.10000E+01 0.0000 150 H2S,aq 0.12095E-04 -4.9174 0.11166E-04 -4.9521 0.92316E+00 -0.0347 158 HSO3- 0.36118E-09 -9.4423 0.18121E-09 -9.7418 0.50171E+00 -0.2995 159 HSO4- 0.68458E-06 -6.1646 0.37146E-06 -6.4301 0.54261E+00 -0.2655 161 S2O3-2 0.28188E-10 -10.5499 0.10644E-11 -11.9729 0.37762E-01 -1.4229 173 ZnCl+ 0.53607E-05 -5.2708 0.28557E-05 -5.5443 0.53271E+00 -0.2735 174 ZnCl2,aq 0.15291E-05 -5.8156 0.15291E-05 -5.8156 0.10000E+01 0.0000 175 ZnCl3- 0.22223E-06 -6.6532 0.11150E-06 -6.9527 0.50171E+00 -0.2995 176 ZnF+ 0.10609E-09 -9.9743 0.56515E-10 -10.2478 0.53271E+00 -0.2735 177 ZnO,aq 0.65685E-09 -9.1825 0.65685E-09 -9.1825 0.10000E+01 0.0000 178 ZnOH+ 0.31766E-06 -6.4980 0.16922E-06 -6.7716 0.53271E+00 -0.2735 Charge balance for all species = -.1293E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6351350E-05 0.3226674E+00 0.2936291E+03 0.0000 2 H2O 0.1000000E+01 0.5518575E+02 0.8975892E+06 0.0000 3 Cl- 0.1200569E+01 0.1541709E+01 0.4934745E+05 5.3070 4 SO4-- 0.1670436E-03 0.1881888E-03 0.1632122E+02 5.8739 5 HCO3- 0.2639373E-01 0.3490923E+00 0.1923100E+05 3.6678 6 HS- 0.1720908E-05 0.1392371E-04 0.4157427E+00 -0.5345 7 H4SiO4 0.2790115E-02 0.2803640E-02 0.2432901E+03 -2.5544 8 Al+++ 0.2214467E-13 0.1015886E-05 0.2474686E-01 -0.3467 9 Ca++ 0.1233383E-02 0.2100196E-02 0.7599326E+02 6.6813 10 Mg++ 0.1219012E-03 0.1713622E-03 0.3761360E+01 5.6267 11 Fe++ 0.1174096E-05 0.1599476E-05 0.8064674E-01 3.6229 12 K+ 0.4367533E-01 0.4534756E-01 0.1600892E+04 3.8916 13 Na+ 0.1181201E+01 0.1520159E+01 0.3155247E+05 5.3013 14 Mn++ 0.6948267E-05 0.3439479E-04 0.1705983E+01 4.4042 15 Zn++ 0.1993722E-07 0.7450341E-05 0.4397075E+00 1.8528 16 Cu+ 0.4556340E-11 0.1697508E-06 0.9737964E-02 -6.1130 17 Pb++ 0.6269166E-08 0.1488189E-05 0.2783788E+00 1.4166 18 Ag+ 0.2164231E-10 0.4261080E-06 0.4149824E-01 -5.4174 19 Au+ 0.1306100E-20 0.3103531E-11 0.5518980E-06 -15.6303 20 Ba++ 0.1391258E-05 0.4054694E-05 0.5027641E+00 3.7814 21 F- 0.1282860E-02 0.1626506E-02 0.2789799E+02 2.2982 22 H2AsO3- 0.2132462E-05 0.1293304E-03 0.1458802E+02 -0.3125 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234399E+00 -.4703140E-05 0.0000000E+00 2 H2O 0.5531785E+02 0.5531785E+02 0.0000000E+00 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1395704E-04 0.7326883E-07 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810352E-02 0.1388961E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.1018318E-05 0.1388961E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.4629871E-06 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.7468176E-05 0.0000000E+00 0.0000000E+00 16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00 17 Pb++ 0.1565021E-05 0.1491752E-05 0.7326883E-07 0.0000000E+00 18 Ag+ 0.4271281E-06 0.4271281E-06 0.0000000E+00 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1630400E-02 0.0000000E+00 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1323E-21 Mass of aqueous solution: 0.111027E+04 g Temperature = 199.97 C Pressure = 500.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) paragonite 0.4630E-06 -6.334 0.1770E-03 -3.752 90.99 0.6117E-04 galena 0.7327E-07 -7.135 0.1753E-04 -4.756 9.013 0.2307E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.0000000 Solid products produced: Mass = 0.000194 g Volume = 0.000063 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.300 AFFINITY: 0.7634E+03 GOLD Q/K: 0.0178 SILVER Q/K: 0.2080 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 199.9700 deg.C Sat. pressure: 100.3663 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2676E+00 0.6367 0.1710E+02 0.2686E+02 CO2,gas 0.7323E+00 0.9068 0.6665E+02 0.7350E+02 CH4,gas 0.2407E-07 1.1419 0.2759E-05 0.2416E-05 H2,gas 0.3263E-05 1.0430 0.3416E-03 0.3275E-03 H2S,gas 0.7294E-05 0.8305 0.6080E-03 0.7321E-03 S2,gas 0.1419E-15 1.0000 0.1425E-13 0.1425E-13 CO,gas 0.5615E-07 1.0000 0.5635E-05 0.5635E-05 SO3,gas 0.1816E-25 1.0000 0.1823E-23 0.1823E-23 O2,gas 0.4736E-04 1.0000 0.4754E-02 0.4754E-02 SO2,gas 0.7900E-12 1.0000 0.7929E-10 0.7929E-10 HF,gas 0.5124E-07 1.0000 0.5143E-05 0.5143E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 122 paragonite -3.40 -3.40 0.00 0.000 0.86528E-11 260 galena -10.17 -10.17 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.44 -0.02 -1.47 -1.466 0.31735E+04 1.233 2 CO2,gas -6.49 -7.36 -0.88 -0.292 0.18946E+04 1.824 3 CH4,gas 5.50 -2.76 -8.26 -2.065 0.17878E+05 -5.559 4 H2,gas 7.31 1.14 -6.17 -3.523 0.13348E+05 -3.467 5 H2S,gas -5.67 -11.59 -5.92 -2.958 0.12806E+05 -3.216 6 S2,gas -8.91 -25.46 -16.55 -2.545 0.35819E+05 -13.846 7 CO,gas 1.74 -6.20 -7.95 -2.446 0.17207E+05 -5.249 8 SO3,gas 10.22 -16.21 -26.44 -6.610 0.57236E+05 -23.739 9 O2,gas 36.93 -2.32 -39.25 -26.165 0.84969E+05 -36.549 10 SO2,gas -2.25 -15.05 -12.80 -3.413 0.27710E+05 -10.101 11 HF,gas -0.77 -8.76 -7.99 -3.994 0.17293E+05 -5.289 12 HCl,gas 3.42 -5.75 -9.16 -4.582 0.19839E+05 -9.164 13 acmite 5.98 3.29 -2.69 -0.280 0.58270E+04 17 albite-high -1.58 -2.62 -1.04 -0.080 0.22525E+04 18 albite -2.25 -2.62 -0.38 -0.029 0.81263E+03 22 analcite 0.78 -0.13 -0.91 -0.101 0.19769E+04 23 andalusite -1.42 -3.27 -1.85 -0.185 0.40055E+04 26 anhydrite -6.83 -9.55 -2.72 -1.361 0.58932E+04 27 ankerite -4.15 -4.47 -0.32 -0.054 0.70091E+03 29 phlogopite 17.57 12.76 -4.80 -0.267 0.10399E+05 31 anorthite 4.24 0.88 -3.36 -0.258 0.72722E+04 34 aragonite -0.17 -0.71 -0.53 -0.178 0.11554E+04 35 brucite 9.50 5.58 -3.92 -0.784 0.84872E+04 36 calcite -0.31 -0.71 -0.39 -0.131 0.85230E+03 37 carnegieite-low 5.15 2.40 -2.75 -0.393 0.59552E+04 38 carnegieite-high 5.83 2.40 -3.42 -0.489 0.74145E+04 39 carpholite-Mg 1.63 -0.22 -1.85 -0.123 0.40043E+04 40 carpholite-Fe 0.10 -2.22 -2.32 -0.155 0.50257E+04 41 celadonite 2.39 -0.96 -3.35 -0.197 0.72438E+04 42 celadonite-Fe 1.07 -2.96 -4.04 -0.237 0.87372E+04 45 clinochlore 23.38 19.65 -3.73 -0.117 0.80837E+04 49 chloritoid-Mg 4.76 2.31 -2.45 -0.163 0.53025E+04 50 chloritoid-Fe 1.65 0.31 -1.34 -0.089 0.29008E+04 51 chloritoid-Mn 3.84 1.09 -2.75 -0.183 0.59549E+04 53 coesite -1.83 -2.51 -0.69 -0.229 0.14849E+04 58 corundum 1.19 -0.76 -1.95 -0.177 0.42245E+04 60 cristobalite -2.02 -2.51 -0.49 -0.163 0.10563E+04 63 cymrite-K -0.29 -4.05 -3.76 -0.313 0.81439E+04 65 diaspore -0.10 -0.39 -0.29 -0.049 0.63614E+03 66 diamond -2.12 -5.04 -2.92 -0.836 0.63319E+04 67 diopside 11.80 7.24 -4.56 -0.456 0.98752E+04 68 hedenbergite 10.17 5.24 -4.94 -0.494 0.10684E+05 69 dolomite,ordered -1.96 -2.47 -0.51 -0.084 0.10933E+04 75 epidote 13.04 8.04 -5.00 -0.242 0.10820E+05 78 fayalite 9.33 4.69 -4.64 -0.663 0.10041E+05 79 ferrosilite 7.10 2.18 -4.92 -0.492 0.10659E+05 83 gibbsite 1.16 -0.41 -1.57 -0.225 0.34086E+04 86 goethite 4.38 3.01 -1.37 -0.297 0.29765E+04 87 graphite -2.50 -5.04 -2.54 -0.725 0.54962E+04 90 halite 1.35 -0.45 -1.80 -0.899 0.38928E+04 91 hematite 8.11 6.04 -2.07 -0.250 0.44733E+04 92 heulandite -9.13 -11.81 -2.68 -0.122 0.58022E+04 93 hercynite 7.24 2.84 -4.40 -0.293 0.95296E+04 96 jadeite 1.60 -0.11 -1.71 -0.171 0.37074E+04 98 kalsilite 4.14 0.99 -3.15 -0.450 0.68138E+04 99 kaolinite -5.32 -5.82 -0.50 -0.045 0.10802E+04 100 kyanite -1.45 -3.27 -1.82 -0.182 0.39362E+04 102 laumontite -2.02 -4.23 -2.21 -0.147 0.47780E+04 103 lawsonite 3.12 0.84 -2.28 -0.152 0.49424E+04 104 leucite 1.26 -1.52 -2.78 -0.278 0.60212E+04 107 magnesite -0.92 -1.76 -0.84 -0.281 0.18280E+04 108 magnetite 13.11 9.64 -3.47 -0.283 0.75072E+04 114 margarite 3.15 0.10 -3.05 -0.122 0.65981E+04 117 microcline -3.65 -4.03 -0.38 -0.030 0.83331E+03 120 mullite-Si 0.26 -3.27 -3.53 -0.353 0.76407E+04 121 muscovite -4.54 -4.81 -0.27 -0.016 0.58149E+03 123 nepheline 4.57 2.40 -2.17 -0.311 0.47059E+04 129 periclase-Fe 8.23 3.60 -4.63 -1.158 0.10029E+05 143 pyrite -19.23 -20.69 -1.47 -0.346 0.31815E+04 144 pyrrhotite -5.01 -7.97 -2.95 -0.984 0.63917E+04 145 pyrrhotiteFe0.875 -6.33 -8.56 -2.23 -0.820 0.48266E+04 146 pyroxmangite 5.39 1.87 -3.52 -0.704 0.76227E+04 147 pyrophyllite -9.51 -10.82 -1.31 -0.082 0.28452E+04 148 quartz -2.32 -2.51 -0.20 -0.065 0.42407E+03 153 rhodochrosite -1.85 -2.98 -1.13 -0.378 0.24523E+04 154 rhodonite 5.42 1.87 -3.55 -0.709 0.76747E+04 155 sanidine -2.69 -4.03 -1.34 -0.103 0.29009E+04 157 siderite -3.54 -3.76 -0.23 -0.075 0.48729E+03 158 sillimanite -1.25 -3.27 -2.02 -0.202 0.43671E+04 165 stilbite -8.82 -11.83 -3.01 -0.143 0.65105E+04 166 stilpnomelane-Fe 3.87 -1.04 -4.91 -0.146 0.10624E+05 168 stishovite 2.33 -2.51 -4.84 -1.615 0.10487E+05 170 sudoite 6.08 2.07 -4.01 -0.129 0.86781E+04 171 sulfur -8.49 -12.73 -4.24 -1.304 0.91722E+04 172 sylvite 1.39 -1.86 -3.24 -1.622 0.70225E+04 173 talc 11.30 6.75 -4.55 -0.268 0.98568E+04 180 topaz-H -0.99 -3.29 -2.30 -0.209 0.49785E+04 181 tridymite -2.05 -2.51 -0.46 -0.153 0.99352E+03 184 troilite-low -5.07 -7.97 -2.89 -0.965 0.62661E+04 190 wairakite -1.87 -4.19 -2.32 -0.137 0.50246E+04 191 walstromite 8.87 4.15 -4.72 -0.944 0.10223E+05 192 wollastonite 8.07 4.15 -3.92 -0.784 0.84822E+04 193 pseudo-wollastonite 8.44 4.15 -4.29 -0.858 0.92898E+04 196 argentite -21.92 -22.42 -0.51 -0.127 0.10961E+04 197 arsenic -5.41 -9.59 -4.19 -1.080 0.90617E+04 199 arsenopyrite -13.34 -17.56 -4.21 -0.749 0.91228E+04 200 beidellite-Ca -6.93 -9.02 -2.10 -0.130 0.45363E+04 201 beidellite-H -7.37 -10.12 -2.76 -0.176 0.59681E+04 202 beidellite-K -6.46 -8.84 -2.38 -0.146 0.51557E+04 203 beidellite-Mg -7.17 -9.20 -2.03 -0.125 0.43870E+04 204 beidellite-Na -6.38 -8.37 -1.99 -0.122 0.43175E+04 205 bornite -71.94 -73.87 -1.93 -0.144 0.41793E+04 207 chalcedony -2.17 -2.51 -0.34 -0.114 0.74233E+03 208 chalcocite -21.89 -23.82 -1.93 -0.481 0.41690E+04 210 covellite -16.15 -18.27 -2.12 -0.809 0.45963E+04 211 dawsonite -0.24 -2.48 -2.24 -0.280 0.48448E+04 213 montmorillonite-Ca -5.92 -7.75 -1.83 -0.113 0.39567E+04 214 montmorillonite-K -5.56 -7.57 -2.01 -0.123 0.43488E+04 215 montmorillonite-Mg -6.16 -7.92 -1.76 -0.109 0.38160E+04 216 montmorillonite-Na -5.40 -7.10 -1.70 -0.104 0.36859E+04 217 nontronite-Ca 0.53 -2.22 -2.75 -0.178 0.59499E+04 218 nontronite-H 0.08 -3.32 -3.41 -0.228 0.73731E+04 219 nontronite-K 0.99 -2.04 -3.03 -0.195 0.65671E+04 220 nontronite-Mg 0.31 -2.40 -2.71 -0.176 0.58634E+04 221 nontronite-Na 1.07 -1.58 -2.65 -0.170 0.57332E+04 225 topaz -20.54 -20.76 -0.22 -0.024 0.47309E+03 229 gypsum -5.82 -9.60 -3.78 -0.944 0.81776E+04 245 acanthite -21.75 -22.42 -0.68 -0.170 0.14685E+04 251 barite -9.75 -12.45 -2.71 -1.353 0.58577E+04 252 boehmite 0.94 -0.39 -1.33 -0.222 0.28879E+04 253 cerussite -2.86 -5.97 -3.11 -1.037 0.67353E+04 254 chalcopyrite -24.63 -26.24 -1.61 -0.299 0.34818E+04 256 copper,native -1.52 -5.54 -4.03 -1.401 0.87198E+04 257 dolomite,disordered -1.54 -2.47 -0.93 -0.155 0.20135E+04 258 ferrous-oxide 6.76 3.60 -3.16 -0.790 0.68445E+04 259 fluorite -10.33 -10.83 -0.50 -0.166 0.10790E+04 261 gold,native -13.31 -15.06 -1.75 -0.608 0.37869E+04 262 silver,native -4.17 -4.85 -0.68 -0.237 0.14762E+04 263 huntite -2.48 -5.98 -3.51 -0.292 0.75964E+04 269 silica-amorphous -1.67 -2.51 -0.84 -0.281 0.18271E+04 270 smithsonite -1.93 -5.53 -3.60 -1.201 0.77984E+04 272 sphalerite -9.71 -9.74 -0.03 -0.009 0.60823E+02 273 wurtzite -8.26 -9.74 -1.47 -0.490 0.31850E+04 274 zincite 5.67 1.83 -3.84 -0.961 0.83208E+04 275 an20ab80 -1.17 -1.92 -0.75 -0.058 0.16335E+04 276 an25ab75 -0.87 -1.75 -0.88 -0.068 0.18998E+04 277 an30ab70 -0.57 -1.57 -1.01 -0.077 0.21770E+04 Calculations done for 199.9700 Deg. C; 500.0000 bar Mixer fraction: 0.0000000 Temperature Stoc.ionic strength Heat per mole Actual solution: 199.970 .17442E+01 3.768 Mixing solution: 25.000 .50000E-10 0.646 Fract. of mixing solution added: 0.050000 BITMOL = 0.2775E+01 OLDMOL = 0.5706E+02 New heat: 3.623 New temperature: 192.085 New mixer fraction: 0.0500000 Resulting temperature: 192.085Deg. C Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1296E-03 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 70 Temperature = 192.08 C Pressure = 500.00 bar Mixer fraction = 0.0500000 Water: Moles liquid = 0.5842E+02 kg liquid = 0.1052E+01 Moles total = 0.5809E+02 kg total = 0.1047E+01 Activity = 0.9533 Stoichiometric ionic strength = .1660864E+01 Osmotic coef. = 0.9046 True ionic strength = .1193297E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.71525E-05 -5.1455 0.34501E-05 -5.4622 0.48237E+00 -0.3166 2 H2O 0.95326E+00 -0.0208 0.95326E+00 -0.0208 3 Cl- 0.11651E+01 0.0664 0.59880E+00 -0.2227 0.51396E+00 -0.2891 4 SO4-- 0.16022E-03 -3.7953 0.71046E-05 -5.1485 0.44342E-01 -1.3532 5 HCO3- 0.25162E-01 -1.5992 0.13443E-01 -1.8715 0.53426E+00 -0.2722 6 HS- 0.14976E-05 -5.8246 0.77295E-06 -6.1119 0.51614E+00 -0.2872 7 H4SiO4 0.26589E-02 -2.5753 0.26589E-02 -2.5753 0.10000E+01 0.0000 8 Al+++ 0.44329E-13 -13.3533 0.31209E-16 -16.5057 0.70404E-03 -3.1524 9 Ca++ 0.12219E-02 -2.9130 0.47514E-04 -4.3232 0.38886E-01 -1.4102 10 Mg++ 0.11822E-03 -3.9273 0.41439E-05 -5.3826 0.35054E-01 -1.4553 11 Fe++ 0.11418E-05 -5.9424 0.41080E-07 -7.3864 0.35977E-01 -1.4440 12 K+ 0.41808E-01 -1.3787 0.22563E-01 -1.6466 0.53968E+00 -0.2679 13 Na+ 0.11464E+01 0.0593 0.59038E+00 -0.2289 0.51499E+00 -0.2882 14 Mn++ 0.73761E-05 -5.1322 0.27050E-06 -6.5678 0.36672E-01 -1.4357 15 Zn++ 0.24339E-07 -7.6137 0.87566E-09 -9.0577 0.35977E-01 -1.4440 16 Cu+ 0.45403E-11 -11.3429 0.23349E-11 -11.6317 0.51427E+00 -0.2888 17 Pb++ 0.59033E-08 -8.2289 0.24415E-09 -9.6123 0.41359E-01 -1.3834 18 Ag+ 0.23151E-10 -10.6354 0.12387E-10 -10.9070 0.53506E+00 -0.2716 19 Au+ 0.84764E-21 -21.0718 0.45967E-21 -21.3376 0.54229E+00 -0.2658 20 Ba++ 0.14608E-05 -5.8354 0.62844E-07 -7.2017 0.43021E-01 -1.3663 21 F- 0.12368E-02 -2.9077 0.58884E-03 -3.2300 0.47609E+00 -0.3223 22 H2AsO3- 0.15445E-05 -5.8112 0.10498E-05 -5.9789 0.67972E+00 -0.1677 24 HSiO3- 0.33207E-05 -5.4788 0.17067E-05 -5.7678 0.51396E+00 -0.2891 25 Ca(HSiO3)+ 0.16547E-07 -7.7813 0.89734E-08 -8.0470 0.54229E+00 -0.2658 26 Mg(HSiO3)+ 0.12377E-08 -8.9074 0.67119E-09 -9.1732 0.54229E+00 -0.2658 27 NaHSiO3,aq 0.79542E-05 -5.0994 0.79542E-05 -5.0994 0.10000E+01 0.0000 31 AgCl,aq 0.41905E-08 -8.3777 0.41905E-08 -8.3777 0.10000E+01 0.0000 32 AgCl2- 0.20618E-06 -6.6858 0.10597E-06 -6.9748 0.51396E+00 -0.2891 33 AgCl3-2 0.15594E-06 -6.8070 0.66335E-08 -8.1783 0.42538E-01 -1.3712 34 AgCl4-3 0.32130E-07 -7.4931 0.21867E-10 -10.6602 0.68058E-03 -3.1671 38 Ag(HS),aq 0.73898E-08 -8.1314 0.73898E-08 -8.1314 0.10000E+01 0.0000 40 AlO+ 0.19469E-09 -9.7106 0.10558E-09 -9.9764 0.54229E+00 -0.2658 42 HAlO2,aq 0.53446E-07 -7.2721 0.53446E-07 -7.2721 0.10000E+01 0.0000 43 AlO2- 0.67779E-06 -6.1689 0.32672E-06 -6.4858 0.48203E+00 -0.3169 44 AsO2- 0.24096E-06 -6.6181 0.12384E-06 -6.9071 0.51396E+00 -0.2891 45 HAsO2,aq 0.31459E-04 -4.5022 0.31459E-04 -4.5022 0.10000E+01 0.0000 46 H3AsO3,aq 0.89941E-04 -4.0460 0.89941E-04 -4.0460 0.10000E+01 0.0000 48 H2AsO4- 0.13505E-09 -9.8695 0.69410E-10 -10.1586 0.51396E+00 -0.2891 49 HAsO4-2 0.33823E-10 -10.4708 0.14387E-11 -11.8420 0.42538E-01 -1.3712 62 BaCO3,aq 0.50013E-09 -9.3009 0.50013E-09 -9.3009 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.15283E-05 -5.8158 0.84723E-06 -6.0720 0.55434E+00 -0.2562 64 BaCl+ 0.87151E-06 -6.0597 0.47261E-06 -6.3255 0.54229E+00 -0.2658 65 BaF+ 0.93950E-09 -9.0271 0.50948E-09 -9.2929 0.54229E+00 -0.2658 66 CH4,aq 0.16294E-08 -8.7880 0.14950E-08 -8.8254 0.91753E+00 -0.0374 71 CO,aq 0.35376E-08 -8.4513 0.35376E-08 -8.4513 0.10000E+01 0.0000 72 CO2,aq 0.30714E+00 -0.5127 0.28181E+00 -0.5500 0.91753E+00 -0.0374 73 CO3-2 0.65533E-05 -5.1835 0.27876E-06 -6.5548 0.42538E-01 -1.3712 74 CaCO3,aq 0.15034E-05 -5.8229 0.15034E-05 -5.8229 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.17785E-03 -3.7500 0.96445E-04 -4.0157 0.54229E+00 -0.2658 76 CaCl+ 0.54436E-03 -3.2641 0.29520E-03 -3.5299 0.54229E+00 -0.2658 77 CaCl2,aq 0.49025E-04 -4.3096 0.49025E-04 -4.3096 0.10000E+01 0.0000 78 CaF+ 0.51324E-05 -5.2897 0.27833E-05 -5.5554 0.54229E+00 -0.2658 79 CaOH+ 0.18388E-06 -6.7355 0.99718E-07 -7.0012 0.54229E+00 -0.2658 80 CaSO4,aq 0.46261E-06 -6.3348 0.46261E-06 -6.3348 0.10000E+01 0.0000 81 HCl,aq 0.12897E-05 -5.8895 0.12897E-05 -5.8895 0.10000E+01 0.0000 90 CuCl,aq 0.65999E-08 -8.1805 0.65999E-08 -8.1805 0.10000E+01 0.0000 91 CuCl2- 0.12548E-06 -6.9014 0.64489E-07 -7.1905 0.51396E+00 -0.2891 92 CuCl3-2 0.29606E-07 -7.5286 0.12594E-08 -8.8998 0.42538E-01 -1.3712 98 HF,aq 0.82940E-04 -4.0812 0.82940E-04 -4.0812 0.10000E+01 0.0000 99 HF2- 0.26470E-07 -7.5772 0.13605E-07 -7.8663 0.51396E+00 -0.2891 101 FeCl+ 0.34781E-06 -6.4587 0.18861E-06 -6.7244 0.54229E+00 -0.2658 102 FeCl2,aq 0.37260E-08 -8.4288 0.37260E-08 -8.4288 0.10000E+01 0.0000 104 FeF+ 0.86879E-08 -8.0611 0.47114E-08 -8.3269 0.54229E+00 -0.2658 106 FeO,aq 0.16331E-09 -9.7870 0.16331E-09 -9.7870 0.10000E+01 0.0000 107 FeOH+ 0.21108E-07 -7.6755 0.11447E-07 -7.9413 0.54229E+00 -0.2658 111 FeO2- 0.11345E-10 -10.9452 0.58310E-11 -11.2343 0.51396E+00 -0.2891 112 HFeO2,aq 0.12543E-09 -9.9016 0.12543E-09 -9.9016 0.10000E+01 0.0000 113 H2,aq 0.27577E-06 -6.5595 0.25303E-06 -6.5968 0.91753E+00 -0.0374 114 KCl,aq 0.13673E-02 -2.8641 0.13673E-02 -2.8641 0.10000E+01 0.0000 115 KHSO4,aq 0.25668E-09 -9.5906 0.25668E-09 -9.5906 0.10000E+01 0.0000 116 KOH,aq 0.64389E-07 -7.1912 0.64389E-07 -7.1912 0.10000E+01 0.0000 117 KSO4- 0.17983E-04 -4.7451 0.92426E-05 -5.0342 0.51396E+00 -0.2891 118 MgCO3,aq 0.18067E-07 -7.7431 0.18067E-07 -7.7431 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.15001E-04 -4.8239 0.81350E-05 -5.0896 0.54229E+00 -0.2658 120 MgCl+ 0.28588E-04 -4.5438 0.15503E-04 -4.8096 0.54229E+00 -0.2658 121 MgF+ 0.13403E-05 -5.8728 0.72681E-06 -6.1386 0.54229E+00 -0.2658 122 MgOH+ 0.56373E-07 -7.2489 0.30571E-07 -7.5147 0.54229E+00 -0.2658 124 MnF+ 0.22795E-07 -7.6422 0.12362E-07 -7.9079 0.54229E+00 -0.2658 125 MnO,aq 0.33649E-10 -10.4730 0.33649E-10 -10.4730 0.10000E+01 0.0000 126 MnOH+ 0.18265E-07 -7.7384 0.99048E-08 -8.0042 0.54229E+00 -0.2658 131 MnCl+ 0.25340E-04 -4.5962 0.13742E-04 -4.8620 0.54229E+00 -0.2658 132 MnSO4,aq 0.30736E-08 -8.5124 0.30736E-08 -8.5124 0.10000E+01 0.0000 133 NaCl,aq 0.30131E+00 -0.5210 0.30131E+00 -0.5210 0.10000E+01 0.0000 134 NaF,aq 0.22292E-03 -3.6519 0.22292E-03 -3.6519 0.10000E+01 0.0000 135 NaOH,aq 0.12298E-05 -5.9102 0.12298E-05 -5.9102 0.10000E+01 0.0000 137 OH- 0.42433E-05 -5.3723 0.20454E-05 -5.6892 0.48203E+00 -0.3169 140 PbCl+ 0.71366E-07 -7.1465 0.38701E-07 -7.4123 0.54229E+00 -0.2658 141 PbCl2,aq 0.33540E-06 -6.4744 0.33540E-06 -6.4744 0.10000E+01 0.0000 142 PbCl3- 0.27801E-06 -6.5559 0.14289E-06 -6.8450 0.51396E+00 -0.2891 143 PbCl4-2 0.42681E-06 -6.3698 0.18155E-07 -7.7410 0.42538E-01 -1.3712 144 PbF+ 0.10086E-09 -9.9963 0.54694E-10 -10.2621 0.54229E+00 -0.2658 146 PbO,aq 0.61143E-10 -10.2137 0.61143E-10 -10.2137 0.10000E+01 0.0000 148 Pb(HS)2,aq 0.21219E-09 -9.6733 0.21219E-09 -9.6733 0.10000E+01 0.0000 150 H2S,aq 0.11386E-04 -4.9436 0.10447E-04 -4.9810 0.91753E+00 -0.0374 158 HSO3- 0.27268E-09 -9.5643 0.14015E-09 -9.8534 0.51396E+00 -0.2891 159 HSO4- 0.64864E-06 -6.1880 0.35794E-06 -6.4462 0.55182E+00 -0.2582 161 S2O3-2 0.25391E-10 -10.5953 0.10801E-11 -11.9665 0.42538E-01 -1.3712 173 ZnCl+ 0.52009E-05 -5.2839 0.28204E-05 -5.5497 0.54229E+00 -0.2658 174 ZnCl2,aq 0.14000E-05 -5.8539 0.14000E-05 -5.8539 0.10000E+01 0.0000 175 ZnCl3- 0.19597E-06 -6.7078 0.10072E-06 -6.9969 0.51396E+00 -0.2891 176 ZnF+ 0.12406E-09 -9.9064 0.67274E-10 -10.1722 0.54229E+00 -0.2658 177 ZnO,aq 0.44471E-09 -9.3519 0.44471E-09 -9.3519 0.10000E+01 0.0000 178 ZnOH+ 0.27452E-06 -6.5614 0.14887E-06 -6.8272 0.54229E+00 -0.2658 Charge balance for all species = -.1232E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7152453E-05 0.3073384E+00 0.2809766E+03 0.0000 2 H2O 0.1000000E+01 0.5520107E+02 0.9020025E+06 0.0000 3 Cl- 0.1165076E+01 0.1468462E+01 0.4722091E+05 5.2395 4 SO4-- 0.1602213E-03 0.1792478E-03 0.1561789E+02 5.7759 5 HCO3- 0.2516232E-01 0.3325067E+00 0.1840227E+05 3.5907 6 HS- 0.1497558E-05 0.1296256E-04 0.3888392E+00 -0.6497 7 H4SiO4 0.2658909E-02 0.2670201E-02 0.2327854E+03 -2.5753 8 Al+++ 0.4432889E-13 0.7314393E-06 0.1790042E-01 -0.1192 9 Ca++ 0.1221888E-02 0.2000414E-02 0.7271846E+02 6.6012 10 Mg++ 0.1182155E-03 0.1632207E-03 0.3599271E+01 5.5417 11 Fe++ 0.1141845E-05 0.1523484E-05 0.7717142E-01 3.5380 12 K+ 0.4180769E-01 0.4319307E-01 0.1531905E+04 3.8156 13 Na+ 0.1146397E+01 0.1447935E+01 0.3019277E+05 5.2333 14 Mn++ 0.7376128E-05 0.3276067E-04 0.1632467E+01 4.3565 15 Zn++ 0.2433930E-07 0.7096371E-05 0.4207591E+00 1.8667 16 Cu+ 0.4540285E-11 0.1616858E-06 0.9318324E-02 -6.1696 17 Pb++ 0.5903320E-08 0.1117860E-05 0.2100752E+00 1.3120 18 Ag+ 0.2315101E-10 0.4058634E-06 0.3970994E-01 -5.4449 19 Au+ 0.8476423E-21 0.2956080E-11 0.5281149E-06 -15.8754 20 Ba++ 0.1460765E-05 0.3862052E-05 0.4810984E+00 3.7226 21 F- 0.1236814E-02 0.1549230E-02 0.2669577E+02 2.2322 22 H2AsO3- 0.1544496E-05 0.1231858E-03 0.1395938E+02 -0.5167 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234410E+00 -.5846981E-05 0.0000000E+00 2 H2O 0.5809327E+02 0.5809327E+02 0.0000000E+00 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1364172E-04 0.3885920E-06 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810103E-02 0.1637517E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.7697622E-06 0.1637517E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.5458389E-06 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.7468176E-05 0.0000000E+00 0.0000000E+00 16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00 17 Pb++ 0.1565021E-05 0.1176429E-05 0.3885920E-06 0.0000000E+00 18 Ag+ 0.4271281E-06 0.4271281E-06 0.0000000E+00 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1630400E-02 0.0000000E+00 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.7412E-21 Mass of aqueous solution: 0.116027E+04 g Temperature = 192.08 C Pressure = 500.00 bar Mixer frac. = 0.0500000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) paragonite 0.5458E-06 -6.263 0.2086E-03 -3.681 69.17 0.7211E-04 galena 0.3886E-06 -6.411 0.9297E-04 -4.032 30.83 0.1224E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.0500000 Solid products produced: Mass = 0.000302 g Volume = 0.000084 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.300 AFFINITY: 0.5226E+03 GOLD Q/K: 0.0207 SILVER Q/K: 0.2704 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 192.0845 deg.C Sat. pressure: 94.0408 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2403E+00 0.6491 0.1467E+02 0.2260E+02 CO2,gas 0.7597E+00 0.9049 0.6465E+02 0.7144E+02 CH4,gas 0.2229E-07 1.1282 0.2365E-05 0.2096E-05 H2,gas 0.2600E-05 1.0410 0.2545E-03 0.2445E-03 H2S,gas 0.7390E-05 0.8320 0.5782E-03 0.6949E-03 S2,gas 0.1175E-15 1.0000 0.1105E-13 0.1105E-13 CO,gas 0.4251E-07 1.0000 0.3997E-05 0.3997E-05 SO3,gas 0.8179E-26 1.0000 0.7691E-24 0.7691E-24 O2,gas 0.9819E-42 1.0000 0.9234E-40 0.9234E-40 SO2,gas 0.5742E-12 1.0000 0.5400E-10 0.5400E-10 HF,gas 0.4415E-07 1.0000 0.4152E-05 0.4152E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 122 paragonite -2.85 -2.85 0.00 0.000 0.20799E-10 260 galena -10.26 -10.26 0.00 0.000 0.00000E+00 272 sphalerite -9.72 -9.71 0.01 0.003 -0.19543E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.51 -0.02 -1.53 -1.533 0.32627E+04 1.166 2 CO2,gas -6.42 -7.31 -0.89 -0.296 0.18913E+04 1.811 3 CH4,gas 5.47 -2.86 -8.33 -2.081 0.17723E+05 -5.626 4 H2,gas 7.40 1.10 -6.29 -3.596 0.13397E+05 -3.594 5 H2S,gas -5.64 -11.57 -5.94 -2.968 0.12639E+05 -3.238 6 S2,gas -8.70 -25.36 -16.66 -2.562 0.35457E+05 -13.957 7 CO,gas 1.91 -6.19 -8.10 -2.491 0.17238E+05 -5.398 8 SO3,gas 10.76 -16.05 -26.81 -6.703 0.57080E+05 -24.114 9 O2,gas 40.48 -2.25 -42.73 -28.489 0.90973E+05 -40.035 10 SO2,gas -1.96 -14.93 -12.97 -3.458 0.27604E+05 -10.268 11 HF,gas -0.61 -8.69 -8.08 -4.040 0.17203E+05 -5.382 12 HCl,gas 0.90 -5.68 -6.59 -3.293 0.14022E+05 -6.587 13 acmite 6.10 3.11 -2.99 -0.311 0.63657E+04 17 albite-high -1.41 -2.53 -1.12 -0.086 0.23879E+04 18 albite -2.10 -2.53 -0.43 -0.033 0.91566E+03 22 analcite 0.97 -0.02 -0.98 -0.109 0.20908E+04 23 andalusite -0.96 -2.83 -1.87 -0.187 0.39831E+04 26 anhydrite -6.68 -9.47 -2.80 -1.398 0.59518E+04 27 ankerite -3.96 -4.53 -0.57 -0.095 0.12125E+04 31 anorthite 4.84 1.21 -3.63 -0.279 0.77205E+04 34 aragonite -0.07 -0.73 -0.66 -0.221 0.14094E+04 35 brucite 9.70 5.50 -4.20 -0.840 0.89382E+04 36 calcite -0.21 -0.73 -0.52 -0.174 0.11122E+04 37 carnegieite-low 5.42 2.54 -2.88 -0.412 0.61344E+04 38 carnegieite-high 6.12 2.54 -3.58 -0.512 0.76229E+04 39 carpholite-Mg 2.12 0.11 -2.01 -0.134 0.42686E+04 40 carpholite-Fe 0.57 -1.89 -2.46 -0.164 0.52346E+04 41 celadonite 2.60 -0.98 -3.58 -0.211 0.76311E+04 42 celadonite-Fe 1.28 -2.98 -4.27 -0.251 0.90856E+04 45 clinochlore 24.44 19.62 -4.82 -0.151 0.10257E+05 49 chloritoid-Mg 5.34 2.67 -2.68 -0.179 0.57007E+04 50 chloritoid-Fe 2.18 0.66 -1.51 -0.101 0.32216E+04 51 chloritoid-Mn 4.37 1.48 -2.89 -0.192 0.61454E+04 53 coesite -1.86 -2.53 -0.68 -0.225 0.14394E+04 58 corundum 1.69 -0.30 -1.99 -0.181 0.42433E+04 60 cristobalite -2.05 -2.53 -0.48 -0.161 0.10251E+04 63 cymrite-K -0.14 -3.97 -3.83 -0.319 0.81446E+04 65 diaspore 0.11 -0.16 -0.27 -0.045 0.57853E+03 66 diamond -2.17 -5.06 -2.89 -0.825 0.61503E+04 69 dolomite,ordered -1.75 -2.52 -0.78 -0.130 0.16588E+04 83 gibbsite 1.36 -0.18 -1.54 -0.220 0.32823E+04 86 goethite 4.52 2.94 -1.58 -0.341 0.33593E+04 87 graphite -2.56 -5.06 -2.50 -0.714 0.53228E+04 90 halite 1.38 -0.45 -1.84 -0.918 0.39066E+04 91 hematite 8.41 5.91 -2.50 -0.304 0.53312E+04 92 heulandite -8.85 -11.58 -2.73 -0.124 0.58049E+04 93 hercynite 7.93 3.22 -4.72 -0.314 0.10043E+05 96 jadeite 1.79 0.01 -1.78 -0.178 0.37941E+04 98 kalsilite 4.38 1.12 -3.26 -0.466 0.69420E+04 99 kaolinite -5.03 -5.41 -0.38 -0.034 0.80209E+03 100 kyanite -1.00 -2.83 -1.83 -0.183 0.38952E+04 102 laumontite -1.66 -3.94 -2.28 -0.152 0.48561E+04 103 lawsonite 3.57 1.17 -2.40 -0.160 0.51173E+04 104 leucite 1.47 -1.41 -2.88 -0.288 0.61405E+04 107 magnesite -0.79 -1.79 -1.00 -0.335 0.21385E+04 108 magnetite 13.58 9.43 -4.16 -0.339 0.88515E+04 114 margarite 4.14 0.89 -3.25 -0.130 0.69270E+04 117 microcline -3.54 -3.95 -0.41 -0.031 0.86412E+03 120 mullite-Si 0.75 -2.83 -3.59 -0.359 0.76341E+04 121 muscovite -4.02 -4.27 -0.25 -0.015 0.52654E+03 123 nepheline 4.84 2.54 -2.30 -0.328 0.48892E+04 129 periclase-Fe 8.46 3.52 -4.94 -1.235 0.10515E+05 143 pyrite -19.29 -20.71 -1.42 -0.334 0.30226E+04 144 pyrrhotite -4.94 -8.04 -3.10 -1.034 0.66014E+04 145 pyrrhotiteFe0.875 -6.28 -8.62 -2.34 -0.859 0.49719E+04 146 pyroxmangite 5.53 1.80 -3.73 -0.745 0.79307E+04 147 pyrophyllite -9.25 -10.46 -1.21 -0.076 0.25743E+04 148 quartz -2.36 -2.53 -0.18 -0.060 0.38031E+03 153 rhodochrosite -1.77 -2.98 -1.21 -0.403 0.25744E+04 154 rhodonite 5.55 1.80 -3.75 -0.750 0.79861E+04 155 sanidine -2.57 -3.95 -1.38 -0.106 0.29324E+04 157 siderite -3.45 -3.80 -0.35 -0.115 0.73500E+03 158 sillimanite -0.79 -2.83 -2.04 -0.204 0.43496E+04 165 stilbite -8.68 -11.60 -2.92 -0.139 0.62197E+04 168 stishovite 2.36 -2.53 -4.89 -1.630 0.10411E+05 170 sudoite 7.13 2.76 -4.38 -0.141 0.93212E+04 171 sulfur -8.50 -12.68 -4.18 -1.285 0.88899E+04 172 sylvite 1.41 -1.87 -3.28 -1.638 0.69722E+04 180 topaz-H -0.60 -2.86 -2.26 -0.205 0.48082E+04 181 tridymite -2.08 -2.53 -0.45 -0.150 0.96041E+03 184 troilite-low -5.00 -8.04 -3.04 -1.012 0.64658E+04 190 wairakite -1.43 -3.90 -2.47 -0.145 0.52545E+04 192 wollastonite 8.23 4.05 -4.18 -0.837 0.89051E+04 193 pseudo-wollastonite 8.61 4.05 -4.57 -0.913 0.97210E+04 196 argentite -22.30 -22.46 -0.17 -0.042 0.35800E+03 197 arsenic -5.52 -9.72 -4.20 -1.084 0.89395E+04 199 arsenopyrite -13.42 -17.76 -4.34 -0.771 0.92311E+04 200 beidellite-Ca -6.53 -8.58 -2.05 -0.127 0.43686E+04 201 beidellite-H -6.99 -9.67 -2.68 -0.171 0.57133E+04 202 beidellite-K -6.09 -8.41 -2.33 -0.142 0.49535E+04 203 beidellite-Mg -6.77 -8.76 -1.99 -0.123 0.42308E+04 204 beidellite-Na -6.00 -7.95 -1.94 -0.119 0.41350E+04 205 bornite -72.89 -74.16 -1.27 -0.095 0.26968E+04 207 chalcedony -2.21 -2.53 -0.33 -0.109 0.69931E+03 208 chalcocite -22.24 -23.91 -1.67 -0.417 0.35550E+04 210 covellite -16.36 -18.30 -1.93 -0.737 0.41188E+04 211 dawsonite -0.10 -2.26 -2.17 -0.271 0.46103E+04 213 montmorillonite-Ca -5.64 -7.50 -1.85 -0.115 0.39484E+04 214 montmorillonite-K -5.30 -7.33 -2.03 -0.124 0.43170E+04 215 montmorillonite-Mg -5.88 -7.67 -1.79 -0.111 0.38180E+04 216 montmorillonite-Na -5.14 -6.86 -1.72 -0.105 0.36624E+04 217 nontronite-Ca 0.73 -2.37 -3.11 -0.202 0.66177E+04 218 nontronite-H 0.27 -3.46 -3.74 -0.250 0.79536E+04 219 nontronite-K 1.18 -2.20 -3.38 -0.217 0.72016E+04 220 nontronite-Mg 0.52 -2.55 -3.07 -0.199 0.65423E+04 221 nontronite-Na 1.26 -1.74 -3.00 -0.193 0.63863E+04 225 topaz -20.20 -20.20 0.00 0.000 0.52093E+01 229 gypsum -5.71 -9.51 -3.80 -0.950 0.80923E+04 245 acanthite -22.12 -22.46 -0.34 -0.086 0.72901E+03 251 barite -9.67 -12.35 -2.68 -1.340 0.57055E+04 252 boehmite 1.18 -0.16 -1.34 -0.224 0.28594E+04 253 cerussite -2.83 -6.02 -3.19 -1.064 0.67963E+04 254 chalcopyrite -24.82 -26.33 -1.51 -0.281 0.32154E+04 256 copper,native -1.61 -5.62 -4.00 -1.392 0.85209E+04 257 dolomite,disordered -1.30 -2.52 -1.22 -0.204 0.26020E+04 258 ferrous-oxide 6.96 3.52 -3.45 -0.862 0.73380E+04 259 fluorite -10.25 -10.78 -0.53 -0.177 0.11321E+04 261 gold,native -13.64 -15.32 -1.68 -0.585 0.35828E+04 262 silver,native -4.32 -4.89 -0.57 -0.198 0.12093E+04 263 huntite -1.97 -6.11 -4.14 -0.345 0.88077E+04 269 silica-amorphous -1.69 -2.53 -0.85 -0.282 0.18007E+04 270 smithsonite -1.83 -5.47 -3.64 -1.213 0.77463E+04 273 wurtzite -8.25 -9.71 -1.46 -0.486 0.31044E+04 274 zincite 5.84 1.85 -3.99 -0.998 0.84974E+04 275 an20ab80 -0.93 -1.78 -0.85 -0.066 0.18139E+04 276 an25ab75 -0.61 -1.59 -0.99 -0.076 0.20975E+04 277 an30ab70 -0.28 -1.41 -1.12 -0.086 0.23926E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 70 Temperature = 192.08 C Pressure = 500.00 bar Mixer fraction = 0.0500000 Water: Moles liquid = 0.5842E+02 kg liquid = 0.1052E+01 Moles total = 0.5809E+02 kg total = 0.1047E+01 Activity = 0.9533 Stoichiometric ionic strength = .1660864E+01 Osmotic coef. = 0.9046 True ionic strength = .1193297E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.71525E-05 -5.1455 0.34501E-05 -5.4622 0.48237E+00 -0.3166 2 H2O 0.95326E+00 -0.0208 0.95326E+00 -0.0208 3 Cl- 0.11651E+01 0.0664 0.59880E+00 -0.2227 0.51396E+00 -0.2891 4 SO4-- 0.16022E-03 -3.7953 0.71046E-05 -5.1485 0.44342E-01 -1.3532 5 HCO3- 0.25162E-01 -1.5993 0.13443E-01 -1.8715 0.53426E+00 -0.2722 6 HS- 0.14870E-05 -5.8277 0.76749E-06 -6.1149 0.51614E+00 -0.2872 7 H4SiO4 0.26589E-02 -2.5753 0.26589E-02 -2.5753 0.10000E+01 0.0000 8 Al+++ 0.44330E-13 -13.3533 0.31210E-16 -16.5057 0.70404E-03 -3.1524 9 Ca++ 0.12219E-02 -2.9130 0.47515E-04 -4.3232 0.38886E-01 -1.4102 10 Mg++ 0.11822E-03 -3.9273 0.41439E-05 -5.3826 0.35054E-01 -1.4553 11 Fe++ 0.11418E-05 -5.9424 0.41080E-07 -7.3864 0.35977E-01 -1.4440 12 K+ 0.41808E-01 -1.3787 0.22563E-01 -1.6466 0.53968E+00 -0.2679 13 Na+ 0.11464E+01 0.0593 0.59038E+00 -0.2289 0.51499E+00 -0.2882 14 Mn++ 0.73761E-05 -5.1322 0.27050E-06 -6.5678 0.36672E-01 -1.4357 15 Zn++ 0.24000E-07 -7.6198 0.86344E-09 -9.0638 0.35977E-01 -1.4440 16 Cu+ 0.45403E-11 -11.3429 0.23349E-11 -11.6317 0.51427E+00 -0.2888 17 Pb++ 0.59453E-08 -8.2258 0.24589E-09 -9.6093 0.41359E-01 -1.3834 18 Ag+ 0.23154E-10 -10.6354 0.12389E-10 -10.9070 0.53506E+00 -0.2716 19 Au+ 0.85353E-21 -21.0688 0.46286E-21 -21.3345 0.54229E+00 -0.2658 20 Ba++ 0.14608E-05 -5.8354 0.62844E-07 -7.2017 0.43021E-01 -1.3663 21 F- 0.12368E-02 -2.9077 0.58884E-03 -3.2300 0.47609E+00 -0.3223 22 H2AsO3- 0.15445E-05 -5.8112 0.10498E-05 -5.9789 0.67972E+00 -0.1677 24 HSiO3- 0.33207E-05 -5.4788 0.17067E-05 -5.7678 0.51396E+00 -0.2891 25 Ca(HSiO3)+ 0.16547E-07 -7.7813 0.89734E-08 -8.0470 0.54229E+00 -0.2658 26 Mg(HSiO3)+ 0.12377E-08 -8.9074 0.67118E-09 -9.1732 0.54229E+00 -0.2658 27 NaHSiO3,aq 0.79541E-05 -5.0994 0.79541E-05 -5.0994 0.10000E+01 0.0000 31 AgCl,aq 0.41911E-08 -8.3777 0.41911E-08 -8.3777 0.10000E+01 0.0000 32 AgCl2- 0.20621E-06 -6.6857 0.10598E-06 -6.9748 0.51396E+00 -0.2891 33 AgCl3-2 0.15596E-06 -6.8070 0.66344E-08 -8.1782 0.42538E-01 -1.3712 34 AgCl4-3 0.32134E-07 -7.4930 0.21870E-10 -10.6602 0.68058E-03 -3.1671 38 Ag(HS),aq 0.73386E-08 -8.1344 0.73386E-08 -8.1344 0.10000E+01 0.0000 40 AlO+ 0.19470E-09 -9.7106 0.10558E-09 -9.9764 0.54229E+00 -0.2658 42 HAlO2,aq 0.53446E-07 -7.2721 0.53446E-07 -7.2721 0.10000E+01 0.0000 43 AlO2- 0.67779E-06 -6.1689 0.32671E-06 -6.4858 0.48203E+00 -0.3169 44 AsO2- 0.24096E-06 -6.6181 0.12384E-06 -6.9071 0.51396E+00 -0.2891 45 HAsO2,aq 0.31459E-04 -4.5022 0.31459E-04 -4.5022 0.10000E+01 0.0000 46 H3AsO3,aq 0.89941E-04 -4.0460 0.89941E-04 -4.0460 0.10000E+01 0.0000 48 H2AsO4- 0.13529E-09 -9.8687 0.69532E-10 -10.1578 0.51396E+00 -0.2891 49 HAsO4-2 0.33883E-10 -10.4700 0.14413E-11 -11.8413 0.42538E-01 -1.3712 62 BaCO3,aq 0.50012E-09 -9.3009 0.50012E-09 -9.3009 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.15283E-05 -5.8158 0.84722E-06 -6.0720 0.55434E+00 -0.2562 64 BaCl+ 0.87151E-06 -6.0597 0.47261E-06 -6.3255 0.54229E+00 -0.2658 65 BaF+ 0.93950E-09 -9.0271 0.50948E-09 -9.2929 0.54229E+00 -0.2658 66 CH4,aq 0.16179E-08 -8.7911 0.14844E-08 -8.8284 0.91753E+00 -0.0374 71 CO,aq 0.35313E-08 -8.4521 0.35313E-08 -8.4521 0.10000E+01 0.0000 72 CO2,aq 0.30714E+00 -0.5127 0.28181E+00 -0.5500 0.91753E+00 -0.0374 73 CO3-2 0.65532E-05 -5.1835 0.27876E-06 -6.5548 0.42538E-01 -1.3712 74 CaCO3,aq 0.15033E-05 -5.8229 0.15033E-05 -5.8229 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.17785E-03 -3.7500 0.96444E-04 -4.0157 0.54229E+00 -0.2658 76 CaCl+ 0.54436E-03 -3.2641 0.29520E-03 -3.5299 0.54229E+00 -0.2658 77 CaCl2,aq 0.49025E-04 -4.3096 0.49025E-04 -4.3096 0.10000E+01 0.0000 78 CaF+ 0.51324E-05 -5.2897 0.27833E-05 -5.5554 0.54229E+00 -0.2658 79 CaOH+ 0.18388E-06 -6.7355 0.99717E-07 -7.0012 0.54229E+00 -0.2658 80 CaSO4,aq 0.46261E-06 -6.3348 0.46261E-06 -6.3348 0.10000E+01 0.0000 81 HCl,aq 0.12897E-05 -5.8895 0.12897E-05 -5.8895 0.10000E+01 0.0000 90 CuCl,aq 0.65999E-08 -8.1805 0.65999E-08 -8.1805 0.10000E+01 0.0000 91 CuCl2- 0.12548E-06 -6.9014 0.64489E-07 -7.1905 0.51396E+00 -0.2891 92 CuCl3-2 0.29606E-07 -7.5286 0.12594E-08 -8.8998 0.42538E-01 -1.3712 98 HF,aq 0.82941E-04 -4.0812 0.82941E-04 -4.0812 0.10000E+01 0.0000 99 HF2- 0.26470E-07 -7.5772 0.13605E-07 -7.8663 0.51396E+00 -0.2891 101 FeCl+ 0.34781E-06 -6.4587 0.18861E-06 -6.7244 0.54229E+00 -0.2658 102 FeCl2,aq 0.37260E-08 -8.4288 0.37260E-08 -8.4288 0.10000E+01 0.0000 104 FeF+ 0.86879E-08 -8.0611 0.47114E-08 -8.3269 0.54229E+00 -0.2658 106 FeO,aq 0.16330E-09 -9.7870 0.16330E-09 -9.7870 0.10000E+01 0.0000 107 FeOH+ 0.21108E-07 -7.6755 0.11447E-07 -7.9413 0.54229E+00 -0.2658 111 FeO2- 0.11355E-10 -10.9448 0.58361E-11 -11.2339 0.51396E+00 -0.2891 112 HFeO2,aq 0.12554E-09 -9.9012 0.12554E-09 -9.9012 0.10000E+01 0.0000 113 H2,aq 0.27528E-06 -6.5602 0.25258E-06 -6.5976 0.91753E+00 -0.0374 114 KCl,aq 0.13673E-02 -2.8641 0.13673E-02 -2.8641 0.10000E+01 0.0000 115 KHSO4,aq 0.25668E-09 -9.5906 0.25668E-09 -9.5906 0.10000E+01 0.0000 116 KOH,aq 0.64388E-07 -7.1912 0.64388E-07 -7.1912 0.10000E+01 0.0000 117 KSO4- 0.17983E-04 -4.7451 0.92426E-05 -5.0342 0.51396E+00 -0.2891 118 MgCO3,aq 0.18067E-07 -7.7431 0.18067E-07 -7.7431 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.15001E-04 -4.8239 0.81349E-05 -5.0896 0.54229E+00 -0.2658 120 MgCl+ 0.28588E-04 -4.5438 0.15503E-04 -4.8096 0.54229E+00 -0.2658 121 MgF+ 0.13403E-05 -5.8728 0.72681E-06 -6.1386 0.54229E+00 -0.2658 122 MgOH+ 0.56373E-07 -7.2489 0.30570E-07 -7.5147 0.54229E+00 -0.2658 124 MnF+ 0.22795E-07 -7.6422 0.12362E-07 -7.9079 0.54229E+00 -0.2658 125 MnO,aq 0.33649E-10 -10.4730 0.33649E-10 -10.4730 0.10000E+01 0.0000 126 MnOH+ 0.18265E-07 -7.7384 0.99048E-08 -8.0042 0.54229E+00 -0.2658 131 MnCl+ 0.25340E-04 -4.5962 0.13742E-04 -4.8620 0.54229E+00 -0.2658 132 MnSO4,aq 0.30736E-08 -8.5124 0.30736E-08 -8.5124 0.10000E+01 0.0000 133 NaCl,aq 0.30131E+00 -0.5210 0.30131E+00 -0.5210 0.10000E+01 0.0000 134 NaF,aq 0.22292E-03 -3.6519 0.22292E-03 -3.6519 0.10000E+01 0.0000 135 NaOH,aq 0.12298E-05 -5.9102 0.12298E-05 -5.9102 0.10000E+01 0.0000 137 OH- 0.42433E-05 -5.3723 0.20454E-05 -5.6892 0.48203E+00 -0.3169 140 PbCl+ 0.71874E-07 -7.1434 0.38977E-07 -7.4092 0.54229E+00 -0.2658 141 PbCl2,aq 0.33778E-06 -6.4714 0.33778E-06 -6.4714 0.10000E+01 0.0000 142 PbCl3- 0.27999E-06 -6.5529 0.14390E-06 -6.8419 0.51396E+00 -0.2891 143 PbCl4-2 0.42985E-06 -6.3667 0.18285E-07 -7.7379 0.42538E-01 -1.3712 144 PbF+ 0.10158E-09 -9.9932 0.55083E-10 -10.2590 0.54229E+00 -0.2658 146 PbO,aq 0.61577E-10 -10.2106 0.61577E-10 -10.2106 0.10000E+01 0.0000 148 Pb(HS)2,aq 0.21069E-09 -9.6763 0.21069E-09 -9.6763 0.10000E+01 0.0000 150 H2S,aq 0.11305E-04 -4.9467 0.10373E-04 -4.9841 0.91753E+00 -0.0374 158 HSO3- 0.27220E-09 -9.5651 0.13990E-09 -9.8542 0.51396E+00 -0.2891 159 HSO4- 0.64865E-06 -6.1880 0.35794E-06 -6.4462 0.55182E+00 -0.2582 161 S2O3-2 0.25212E-10 -10.5984 0.10725E-11 -11.9696 0.42538E-01 -1.3712 173 ZnCl+ 0.51284E-05 -5.2900 0.27811E-05 -5.5558 0.54229E+00 -0.2658 174 ZnCl2,aq 0.13805E-05 -5.8600 0.13805E-05 -5.8600 0.10000E+01 0.0000 175 ZnCl3- 0.19323E-06 -6.7139 0.99314E-07 -7.0030 0.51396E+00 -0.2891 176 ZnF+ 0.12233E-09 -9.9125 0.66336E-10 -10.1783 0.54229E+00 -0.2658 177 ZnO,aq 0.43850E-09 -9.3580 0.43850E-09 -9.3580 0.10000E+01 0.0000 178 ZnOH+ 0.27069E-06 -6.5675 0.14679E-06 -6.8333 0.54229E+00 -0.2658 Charge balance for all species = -.1232E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7152504E-05 0.3073385E+00 0.2809767E+03 0.0000 2 H2O 0.1000000E+01 0.5520107E+02 0.9020025E+06 0.0000 3 Cl- 0.1165076E+01 0.1468462E+01 0.4722091E+05 5.2394 4 SO4-- 0.1602211E-03 0.1792478E-03 0.1561789E+02 5.7759 5 HCO3- 0.2516215E-01 0.3325067E+00 0.1840227E+05 3.5907 6 HS- 0.1486988E-05 0.1287152E-04 0.3861081E+00 -0.6528 7 H4SiO4 0.2658909E-02 0.2670201E-02 0.2327854E+03 -2.5753 8 Al+++ 0.4432993E-13 0.7314362E-06 0.1790034E-01 -0.1192 9 Ca++ 0.1221888E-02 0.2000414E-02 0.7271846E+02 6.6012 10 Mg++ 0.1182155E-03 0.1632207E-03 0.3599271E+01 5.5417 11 Fe++ 0.1141845E-05 0.1523484E-05 0.7717142E-01 3.5380 12 K+ 0.4180769E-01 0.4319307E-01 0.1531905E+04 3.8156 13 Na+ 0.1146397E+01 0.1447935E+01 0.3019277E+05 5.2333 14 Mn++ 0.7376127E-05 0.3276067E-04 0.1632467E+01 4.3565 15 Zn++ 0.2399977E-07 0.6997376E-05 0.4148895E+00 1.8606 16 Cu+ 0.4540285E-11 0.1616858E-06 0.9318324E-02 -6.1696 17 Pb++ 0.5945325E-08 0.1125811E-05 0.2115695E+00 1.3151 18 Ag+ 0.2315399E-10 0.4058634E-06 0.3970994E-01 -5.4448 19 Au+ 0.8535291E-21 0.2956080E-11 0.5281149E-06 -15.8724 20 Ba++ 0.1460769E-05 0.3862052E-05 0.4810984E+00 3.7226 21 F- 0.1236814E-02 0.1549230E-02 0.2669577E+02 2.2322 22 H2AsO3- 0.1544485E-05 0.1231858E-03 0.1395938E+02 -0.5167 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234411E+00 -.5942805E-05 0.0000000E+00 2 H2O 0.5809327E+02 0.5809327E+02 0.0000000E+00 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1354591E-04 0.4844047E-06 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810103E-02 0.1637520E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.7697590E-06 0.1637520E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.5458400E-06 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.7363996E-05 0.1041807E-06 0.0000000E+00 16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00 17 Pb++ 0.1565021E-05 0.1184797E-05 0.3802240E-06 0.0000000E+00 18 Ag+ 0.4271281E-06 0.4271281E-06 0.0000000E+00 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1630400E-02 0.0000000E+00 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5294E-21 Mass of aqueous solution: 0.116027E+04 g Temperature = 192.08 C Pressure = 500.00 bar Mixer frac. = 0.0500000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) paragonite 0.5458E-06 -6.263 0.2086E-03 -3.681 67.35 0.7211E-04 galena 0.3802E-06 -6.420 0.9097E-04 -4.041 29.37 0.1197E-04 sphalerite 0.1042E-06 -6.982 0.1015E-04 -4.994 3.277 0.2482E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.0500000 Solid products produced: Mass = 0.000310 g Volume = 0.000087 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.300 AFFINITY: 0.5214E+03 GOLD Q/K: 0.0209 SILVER Q/K: 0.2702 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 192.0845 deg.C Sat. pressure: 94.0408 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2403E+00 0.6491 0.1467E+02 0.2260E+02 CO2,gas 0.7597E+00 0.9049 0.6465E+02 0.7144E+02 CH4,gas 0.2213E-07 1.1282 0.2348E-05 0.2081E-05 H2,gas 0.2595E-05 1.0410 0.2540E-03 0.2440E-03 H2S,gas 0.7338E-05 0.8320 0.5742E-03 0.6900E-03 S2,gas 0.1163E-15 1.0000 0.1093E-13 0.1093E-13 CO,gas 0.4243E-07 1.0000 0.3990E-05 0.3990E-05 SO3,gas 0.8179E-26 1.0000 0.7691E-24 0.7691E-24 O2,gas 0.9854E-42 1.0000 0.9267E-40 0.9267E-40 SO2,gas 0.5732E-12 1.0000 0.5390E-10 0.5390E-10 HF,gas 0.4415E-07 1.0000 0.4152E-05 0.4152E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 122 paragonite -2.85 -2.85 0.00 0.000 -0.94539E-11 260 galena -10.26 -10.26 0.00 0.000 -0.37816E-11 272 sphalerite -9.72 -9.72 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.51 -0.02 -1.53 -1.533 0.32627E+04 1.166 2 CO2,gas -6.42 -7.31 -0.89 -0.296 0.18913E+04 1.811 3 CH4,gas 5.47 -2.86 -8.33 -2.082 0.17729E+05 -5.629 4 H2,gas 7.40 1.10 -6.29 -3.597 0.13399E+05 -3.595 5 H2S,gas -5.64 -11.58 -5.94 -2.970 0.12645E+05 -3.241 6 S2,gas -8.70 -25.36 -16.66 -2.563 0.35467E+05 -13.961 7 CO,gas 1.91 -6.19 -8.10 -2.492 0.17239E+05 -5.399 8 SO3,gas 10.76 -16.05 -26.81 -6.703 0.57080E+05 -24.114 9 O2,gas 40.48 -2.25 -42.73 -28.488 0.90970E+05 -40.033 10 SO2,gas -1.96 -14.93 -12.97 -3.458 0.27605E+05 -10.268 11 HF,gas -0.61 -8.69 -8.08 -4.040 0.17203E+05 -5.382 12 HCl,gas 0.90 -5.68 -6.59 -3.293 0.14022E+05 -6.587 13 acmite 6.10 3.11 -2.99 -0.311 0.63649E+04 17 albite-high -1.41 -2.53 -1.12 -0.086 0.23879E+04 18 albite -2.10 -2.53 -0.43 -0.033 0.91566E+03 22 analcite 0.97 -0.02 -0.98 -0.109 0.20908E+04 23 andalusite -0.96 -2.83 -1.87 -0.187 0.39831E+04 26 anhydrite -6.68 -9.47 -2.80 -1.398 0.59518E+04 27 ankerite -3.96 -4.53 -0.57 -0.095 0.12125E+04 31 anorthite 4.84 1.21 -3.63 -0.279 0.77205E+04 34 aragonite -0.07 -0.73 -0.66 -0.221 0.14094E+04 35 brucite 9.70 5.50 -4.20 -0.840 0.89382E+04 36 calcite -0.21 -0.73 -0.52 -0.174 0.11122E+04 37 carnegieite-low 5.42 2.54 -2.88 -0.412 0.61344E+04 38 carnegieite-high 6.12 2.54 -3.58 -0.512 0.76229E+04 39 carpholite-Mg 2.12 0.11 -2.01 -0.134 0.42686E+04 40 carpholite-Fe 0.57 -1.89 -2.46 -0.164 0.52346E+04 41 celadonite 2.60 -0.98 -3.58 -0.211 0.76311E+04 42 celadonite-Fe 1.28 -2.98 -4.27 -0.251 0.90857E+04 45 clinochlore 24.44 19.62 -4.82 -0.151 0.10258E+05 49 chloritoid-Mg 5.34 2.67 -2.68 -0.179 0.57007E+04 50 chloritoid-Fe 2.18 0.66 -1.51 -0.101 0.32216E+04 51 chloritoid-Mn 4.37 1.48 -2.89 -0.192 0.61455E+04 53 coesite -1.86 -2.53 -0.68 -0.225 0.14394E+04 58 corundum 1.69 -0.30 -1.99 -0.181 0.42433E+04 60 cristobalite -2.05 -2.53 -0.48 -0.161 0.10251E+04 63 cymrite-K -0.14 -3.97 -3.83 -0.319 0.81446E+04 65 diaspore 0.11 -0.16 -0.27 -0.045 0.57853E+03 66 diamond -2.17 -5.07 -2.89 -0.826 0.61536E+04 69 dolomite,ordered -1.75 -2.52 -0.78 -0.130 0.16589E+04 83 gibbsite 1.36 -0.18 -1.54 -0.220 0.32823E+04 86 goethite 4.52 2.94 -1.58 -0.341 0.33585E+04 87 graphite -2.56 -5.07 -2.50 -0.715 0.53261E+04 90 halite 1.38 -0.45 -1.84 -0.918 0.39066E+04 91 hematite 8.41 5.91 -2.50 -0.303 0.53295E+04 92 heulandite -8.85 -11.58 -2.73 -0.124 0.58049E+04 93 hercynite 7.93 3.22 -4.72 -0.314 0.10043E+05 96 jadeite 1.79 0.01 -1.78 -0.178 0.37941E+04 98 kalsilite 4.38 1.12 -3.26 -0.466 0.69420E+04 99 kaolinite -5.03 -5.41 -0.38 -0.034 0.80209E+03 100 kyanite -1.00 -2.83 -1.83 -0.183 0.38952E+04 102 laumontite -1.66 -3.94 -2.28 -0.152 0.48561E+04 103 lawsonite 3.57 1.17 -2.40 -0.160 0.51173E+04 104 leucite 1.47 -1.41 -2.88 -0.288 0.61405E+04 107 magnesite -0.79 -1.79 -1.00 -0.335 0.21385E+04 108 magnetite 13.58 9.43 -4.16 -0.339 0.88499E+04 114 margarite 4.14 0.89 -3.25 -0.130 0.69270E+04 117 microcline -3.54 -3.95 -0.41 -0.031 0.86412E+03 120 mullite-Si 0.75 -2.83 -3.59 -0.359 0.76341E+04 121 muscovite -4.02 -4.27 -0.25 -0.015 0.52654E+03 123 nepheline 4.84 2.54 -2.30 -0.328 0.48892E+04 129 periclase-Fe 8.46 3.52 -4.94 -1.235 0.10515E+05 143 pyrite -19.29 -20.72 -1.43 -0.335 0.30341E+04 144 pyrrhotite -4.94 -8.04 -3.10 -1.035 0.66079E+04 145 pyrrhotiteFe0.875 -6.28 -8.62 -2.34 -0.860 0.49783E+04 146 pyroxmangite 5.53 1.80 -3.73 -0.745 0.79308E+04 147 pyrophyllite -9.25 -10.46 -1.21 -0.076 0.25743E+04 148 quartz -2.36 -2.53 -0.18 -0.060 0.38031E+03 153 rhodochrosite -1.77 -2.98 -1.21 -0.403 0.25744E+04 154 rhodonite 5.55 1.80 -3.75 -0.750 0.79861E+04 155 sanidine -2.57 -3.95 -1.38 -0.106 0.29324E+04 157 siderite -3.45 -3.80 -0.35 -0.115 0.73501E+03 158 sillimanite -0.79 -2.83 -2.04 -0.204 0.43496E+04 165 stilbite -8.68 -11.60 -2.92 -0.139 0.62197E+04 168 stishovite 2.36 -2.53 -4.89 -1.630 0.10411E+05 170 sudoite 7.13 2.76 -4.38 -0.141 0.93212E+04 171 sulfur -8.50 -12.68 -4.18 -1.286 0.88948E+04 172 sylvite 1.41 -1.87 -3.28 -1.638 0.69722E+04 180 topaz-H -0.60 -2.86 -2.26 -0.205 0.48082E+04 181 tridymite -2.08 -2.53 -0.45 -0.150 0.96041E+03 184 troilite-low -5.00 -8.04 -3.04 -1.013 0.64723E+04 190 wairakite -1.43 -3.90 -2.47 -0.145 0.52545E+04 192 wollastonite 8.23 4.05 -4.18 -0.837 0.89051E+04 193 pseudo-wollastonite 8.61 4.05 -4.57 -0.913 0.97210E+04 196 argentite -22.30 -22.47 -0.17 -0.043 0.36431E+03 197 arsenic -5.52 -9.72 -4.20 -1.084 0.89420E+04 199 arsenopyrite -13.42 -17.76 -4.34 -0.772 0.92401E+04 200 beidellite-Ca -6.53 -8.58 -2.05 -0.127 0.43686E+04 201 beidellite-H -6.99 -9.67 -2.68 -0.171 0.57133E+04 202 beidellite-K -6.09 -8.41 -2.33 -0.142 0.49535E+04 203 beidellite-Mg -6.77 -8.76 -1.99 -0.123 0.42308E+04 204 beidellite-Na -6.00 -7.95 -1.94 -0.119 0.41350E+04 205 bornite -72.89 -74.17 -1.28 -0.096 0.27222E+04 207 chalcedony -2.21 -2.53 -0.33 -0.109 0.69931E+03 208 chalcocite -22.24 -23.92 -1.67 -0.418 0.35615E+04 210 covellite -16.36 -18.30 -1.94 -0.738 0.41245E+04 211 dawsonite -0.10 -2.26 -2.17 -0.271 0.46103E+04 213 montmorillonite-Ca -5.64 -7.50 -1.85 -0.115 0.39484E+04 214 montmorillonite-K -5.30 -7.33 -2.03 -0.124 0.43170E+04 215 montmorillonite-Mg -5.88 -7.67 -1.79 -0.111 0.38180E+04 216 montmorillonite-Na -5.14 -6.86 -1.72 -0.105 0.36624E+04 217 nontronite-Ca 0.73 -2.37 -3.11 -0.202 0.66161E+04 218 nontronite-H 0.27 -3.46 -3.74 -0.250 0.79520E+04 219 nontronite-K 1.18 -2.20 -3.38 -0.217 0.72000E+04 220 nontronite-Mg 0.52 -2.55 -3.07 -0.199 0.65407E+04 221 nontronite-Na 1.26 -1.74 -3.00 -0.192 0.63846E+04 225 topaz -20.20 -20.20 0.00 0.000 0.51925E+01 229 gypsum -5.71 -9.51 -3.80 -0.950 0.80923E+04 245 acanthite -22.12 -22.47 -0.35 -0.086 0.73533E+03 251 barite -9.67 -12.35 -2.68 -1.340 0.57055E+04 252 boehmite 1.18 -0.16 -1.34 -0.224 0.28594E+04 253 cerussite -2.83 -6.02 -3.19 -1.063 0.67898E+04 254 chalcopyrite -24.82 -26.34 -1.52 -0.282 0.32277E+04 256 copper,native -1.61 -5.62 -4.00 -1.392 0.85218E+04 257 dolomite,disordered -1.30 -2.52 -1.22 -0.204 0.26020E+04 258 ferrous-oxide 6.96 3.52 -3.45 -0.862 0.73380E+04 259 fluorite -10.25 -10.78 -0.53 -0.177 0.11321E+04 261 gold,native -13.64 -15.32 -1.68 -0.584 0.35772E+04 262 silver,native -4.32 -4.89 -0.57 -0.198 0.12100E+04 263 huntite -1.97 -6.11 -4.14 -0.345 0.88078E+04 269 silica-amorphous -1.69 -2.53 -0.85 -0.282 0.18007E+04 270 smithsonite -1.83 -5.47 -3.64 -1.215 0.77593E+04 273 wurtzite -8.25 -9.72 -1.47 -0.489 0.31240E+04 274 zincite 5.84 1.84 -4.00 -0.999 0.85104E+04 275 an20ab80 -0.93 -1.78 -0.85 -0.066 0.18139E+04 276 an25ab75 -0.61 -1.59 -0.99 -0.076 0.20975E+04 277 an30ab70 -0.28 -1.41 -1.12 -0.086 0.23927E+04 Calculations done for 192.0845 Deg. C; 500.0000 bar Mixer fraction: 0.0500000 Temperature Stoc.ionic strength Heat per mole Actual solution: 192.085 .16609E+01 3.623 Mixing solution: 25.000 .50000E-10 0.646 Fract. of mixing solution added: 0.050000 BITMOL = 0.2775E+01 OLDMOL = 0.5983E+02 New heat: 3.491 New temperature: 184.873 New mixer fraction: 0.1000000 Resulting temperature: 184.873Deg. C Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1296E-03 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 70 Temperature = 184.87 C Pressure = 500.00 bar Mixer fraction = 0.1000000 Water: Moles liquid = 0.6119E+02 kg liquid = 0.1102E+01 Moles total = 0.6087E+02 kg total = 0.1097E+01 Activity = 0.9551 Stoichiometric ionic strength = .1585132E+01 Osmotic coef. = 0.9098 True ionic strength = .1157677E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.79479E-05 -5.0997 0.39417E-05 -5.4043 0.49594E+00 -0.3046 2 H2O 0.95508E+00 -0.0200 0.95508E+00 -0.0200 3 Cl- 0.11307E+01 0.0533 0.59352E+00 -0.2266 0.52493E+00 -0.2799 4 SO4-- 0.15389E-03 -3.8128 0.75718E-05 -5.1208 0.49202E-01 -1.3080 5 HCO3- 0.24039E-01 -1.6191 0.13068E-01 -1.8838 0.54364E+00 -0.2647 6 HS- 0.12676E-05 -5.8970 0.66791E-06 -6.1753 0.52692E+00 -0.2783 7 H4SiO4 0.25394E-02 -2.5953 0.25394E-02 -2.5953 0.10000E+01 0.0000 8 Al+++ 0.84058E-13 -13.0754 0.76126E-16 -16.1185 0.90564E-03 -3.0430 9 Ca++ 0.12071E-02 -2.9182 0.52503E-04 -4.2798 0.43494E-01 -1.3616 10 Mg++ 0.11466E-03 -3.9406 0.45369E-05 -5.3432 0.39567E-01 -1.4027 11 Fe++ 0.11091E-05 -5.9550 0.44932E-07 -7.3474 0.40512E-01 -1.3924 12 K+ 0.40076E-01 -1.3971 0.21975E-01 -1.6581 0.54834E+00 -0.2609 13 Na+ 0.11126E+01 0.0464 0.58463E+00 -0.2331 0.52544E+00 -0.2795 14 Mn++ 0.77725E-05 -5.1094 0.32041E-06 -6.4943 0.41224E-01 -1.3848 15 Zn++ 0.27226E-07 -7.5650 0.11030E-08 -8.9574 0.40512E-01 -1.3924 16 Cu+ 0.45232E-11 -11.3446 0.23737E-11 -11.6246 0.52478E+00 -0.2800 17 Pb++ 0.57124E-08 -8.2432 0.26294E-09 -9.5801 0.46030E-01 -1.3370 18 Ag+ 0.24387E-10 -10.6128 0.13267E-10 -10.8772 0.54404E+00 -0.2644 19 Au+ 0.57903E-21 -21.2373 0.31891E-21 -21.4963 0.55077E+00 -0.2590 20 Ba++ 0.15188E-05 -5.8185 0.72500E-07 -7.1397 0.47735E-01 -1.3212 21 F- 0.11938E-02 -2.9231 0.58573E-03 -3.2323 0.49064E+00 -0.3092 22 H2AsO3- 0.11446E-05 -5.9414 0.77909E-06 -6.1084 0.68068E+00 -0.1671 24 HSiO3- 0.27573E-05 -5.5595 0.14474E-05 -5.8394 0.52493E+00 -0.2799 25 Ca(HSiO3)+ 0.13116E-07 -7.8822 0.72239E-08 -8.1412 0.55077E+00 -0.2590 26 Mg(HSiO3)+ 0.99951E-09 -9.0002 0.55051E-09 -9.2592 0.55077E+00 -0.2590 27 NaHSiO3,aq 0.67643E-05 -5.1698 0.67643E-05 -5.1698 0.10000E+01 0.0000 31 AgCl,aq 0.43784E-08 -8.3587 0.43784E-08 -8.3587 0.10000E+01 0.0000 32 AgCl2- 0.20513E-06 -6.6880 0.10768E-06 -6.9679 0.52493E+00 -0.2799 33 AgCl3-2 0.14281E-06 -6.8452 0.67631E-08 -8.1699 0.47356E-01 -1.3246 34 AgCl4-3 0.25360E-07 -7.5959 0.22442E-10 -10.6489 0.88496E-03 -3.0531 38 Ag(HS),aq 0.97425E-08 -8.0113 0.97425E-08 -8.0113 0.10000E+01 0.0000 40 AlO+ 0.24202E-09 -9.6162 0.13330E-09 -9.8752 0.55077E+00 -0.2590 42 HAlO2,aq 0.52450E-07 -7.2803 0.52450E-07 -7.2803 0.10000E+01 0.0000 43 AlO2- 0.48857E-06 -6.3111 0.24230E-06 -6.6156 0.49594E+00 -0.3046 44 AsO2- 0.19972E-06 -6.6996 0.10484E-06 -6.9795 0.52493E+00 -0.2799 45 HAsO2,aq 0.31282E-04 -4.5047 0.31282E-04 -4.5047 0.10000E+01 0.0000 46 H3AsO3,aq 0.84973E-04 -4.0707 0.84973E-04 -4.0707 0.10000E+01 0.0000 48 H2AsO4- 0.10577E-09 -9.9756 0.55523E-10 -10.2555 0.52493E+00 -0.2799 49 HAsO4-2 0.23653E-10 -10.6261 0.11201E-11 -11.9507 0.47356E-01 -1.3246 62 BaCO3,aq 0.43660E-09 -9.3599 0.43660E-09 -9.3599 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.13496E-05 -5.8698 0.75850E-06 -6.1200 0.56203E+00 -0.2502 64 BaCl+ 0.81719E-06 -6.0877 0.45009E-06 -6.3467 0.55077E+00 -0.2590 65 BaF+ 0.90306E-09 -9.0443 0.49738E-09 -9.3033 0.55077E+00 -0.2590 66 CH4,aq 0.12720E-08 -8.8955 0.11616E-08 -8.9349 0.91321E+00 -0.0394 71 CO,aq 0.23201E-08 -8.6345 0.23201E-08 -8.6345 0.10000E+01 0.0000 72 CO2,aq 0.29321E+00 -0.5328 0.26776E+00 -0.5723 0.91321E+00 -0.0394 73 CO3-2 0.54790E-05 -5.2613 0.25946E-06 -6.5859 0.47356E-01 -1.3246 74 CaCO3,aq 0.12586E-05 -5.9001 0.12586E-05 -5.9001 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.15892E-03 -3.7988 0.87532E-04 -4.0578 0.55077E+00 -0.2590 76 CaCl+ 0.49470E-03 -3.3057 0.27247E-03 -3.5647 0.55077E+00 -0.2590 77 CaCl2,aq 0.42417E-04 -4.3725 0.42417E-04 -4.3725 0.10000E+01 0.0000 78 CaF+ 0.46499E-05 -5.3326 0.25610E-05 -5.5916 0.55077E+00 -0.2590 79 CaOH+ 0.12978E-06 -6.8868 0.71481E-07 -7.1458 0.55077E+00 -0.2590 80 CaSO4,aq 0.46856E-06 -6.3292 0.46856E-06 -6.3292 0.10000E+01 0.0000 81 HCl,aq 0.13044E-05 -5.8846 0.13044E-05 -5.8846 0.10000E+01 0.0000 90 CuCl,aq 0.65807E-08 -8.1817 0.65807E-08 -8.1817 0.10000E+01 0.0000 91 CuCl2- 0.12092E-06 -6.9175 0.63474E-07 -7.1974 0.52493E+00 -0.2799 92 CuCl3-2 0.26848E-07 -7.5711 0.12714E-08 -8.8957 0.47356E-01 -1.3246 98 HF,aq 0.79934E-04 -4.0973 0.79934E-04 -4.0973 0.10000E+01 0.0000 99 HF2- 0.25131E-07 -7.5998 0.13192E-07 -7.8797 0.52493E+00 -0.2799 101 FeCl+ 0.31873E-06 -6.4966 0.17555E-06 -6.7556 0.55077E+00 -0.2590 102 FeCl2,aq 0.21097E-08 -8.6758 0.21097E-08 -8.6758 0.10000E+01 0.0000 104 FeF+ 0.81401E-08 -8.0894 0.44833E-08 -8.3484 0.55077E+00 -0.2590 106 FeO,aq 0.87747E-10 -10.0568 0.87747E-10 -10.0568 0.10000E+01 0.0000 107 FeOH+ 0.16143E-07 -7.7920 0.88910E-08 -8.0511 0.55077E+00 -0.2590 112 HFeO2,aq 0.72036E-10 -10.1424 0.72036E-10 -10.1424 0.10000E+01 0.0000 113 H2,aq 0.19530E-06 -6.7093 0.17835E-06 -6.7487 0.91321E+00 -0.0394 114 KCl,aq 0.11421E-02 -2.9423 0.11421E-02 -2.9423 0.10000E+01 0.0000 115 KHSO4,aq 0.19781E-09 -9.7038 0.19781E-09 -9.7038 0.10000E+01 0.0000 116 KOH,aq 0.46426E-07 -7.3332 0.46426E-07 -7.3332 0.10000E+01 0.0000 117 KSO4- 0.16190E-04 -4.7908 0.84984E-05 -5.0707 0.52493E+00 -0.2799 118 MgCO3,aq 0.15585E-07 -7.8073 0.15585E-07 -7.8073 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.13371E-04 -4.8738 0.73646E-05 -5.1329 0.55077E+00 -0.2590 120 MgCl+ 0.26503E-04 -4.5767 0.14597E-04 -4.8357 0.55077E+00 -0.2590 121 MgF+ 0.12216E-05 -5.9131 0.67283E-06 -6.1721 0.55077E+00 -0.2590 122 MgOH+ 0.40257E-07 -7.3952 0.22172E-07 -7.6542 0.55077E+00 -0.2590 124 MnF+ 0.22765E-07 -7.6427 0.12538E-07 -7.9018 0.55077E+00 -0.2590 125 MnO,aq 0.19571E-10 -10.7084 0.19571E-10 -10.7084 0.10000E+01 0.0000 126 MnOH+ 0.14871E-07 -7.8276 0.81908E-08 -8.0867 0.55077E+00 -0.2590 131 MnCl+ 0.23461E-04 -4.6296 0.12922E-04 -4.8887 0.55077E+00 -0.2590 132 MnSO4,aq 0.32936E-08 -8.4823 0.32936E-08 -8.4823 0.10000E+01 0.0000 133 NaCl,aq 0.26941E+00 -0.5696 0.26941E+00 -0.5696 0.10000E+01 0.0000 134 NaF,aq 0.19925E-03 -3.7006 0.19925E-03 -3.7006 0.10000E+01 0.0000 135 NaOH,aq 0.92017E-06 -6.0361 0.92017E-06 -6.0361 0.10000E+01 0.0000 137 OH- 0.32569E-05 -5.4872 0.16152E-05 -5.7918 0.49594E+00 -0.3046 140 PbCl+ 0.65214E-07 -7.1857 0.35918E-07 -7.4447 0.55077E+00 -0.2590 141 PbCl2,aq 0.28275E-06 -6.5486 0.28275E-06 -6.5486 0.10000E+01 0.0000 142 PbCl3- 0.21839E-06 -6.6608 0.11464E-06 -6.9407 0.52493E+00 -0.2799 143 PbCl4-2 0.30829E-06 -6.5110 0.14599E-07 -7.8357 0.47356E-01 -1.3246 144 PbF+ 0.95610E-10 -10.0195 0.52659E-10 -10.2785 0.55077E+00 -0.2590 146 PbO,aq 0.37307E-10 -10.4282 0.37307E-10 -10.4282 0.10000E+01 0.0000 148 Pb(HS)2,aq 0.17128E-09 -9.7663 0.17128E-09 -9.7663 0.10000E+01 0.0000 150 H2S,aq 0.10377E-04 -4.9839 0.94760E-05 -5.0234 0.91321E+00 -0.0394 158 HSO3- 0.20654E-09 -9.6850 0.10842E-09 -9.9649 0.52493E+00 -0.2799 159 HSO4- 0.61358E-06 -6.2121 0.34358E-06 -6.4640 0.55996E+00 -0.2518 161 S2O3-2 0.22146E-10 -10.6547 0.10487E-11 -11.9793 0.47356E-01 -1.3246 173 ZnCl+ 0.46833E-05 -5.3294 0.25794E-05 -5.5885 0.55077E+00 -0.2590 174 ZnCl2,aq 0.11963E-05 -5.9222 0.11963E-05 -5.9222 0.10000E+01 0.0000 175 ZnCl3- 0.16190E-06 -6.7908 0.84985E-07 -7.0707 0.52493E+00 -0.2799 176 ZnF+ 0.13324E-09 -9.8754 0.73386E-10 -10.1344 0.55077E+00 -0.2590 177 ZnO,aq 0.28713E-09 -9.5419 0.28713E-09 -9.5419 0.10000E+01 0.0000 178 ZnOH+ 0.22217E-06 -6.6533 0.12237E-06 -6.9123 0.55077E+00 -0.2590 Charge balance for all species = -.1176E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7947919E-05 0.2934000E+00 0.2693698E+03 0.0000 2 H2O 0.1000000E+01 0.5521501E+02 0.9060512E+06 0.0000 3 Cl- 0.1130665E+01 0.1401859E+01 0.4527008E+05 5.1777 4 SO4-- 0.1538930E-03 0.1711179E-03 0.1497267E+02 5.6878 5 HCO3- 0.2403856E-01 0.3174256E+00 0.1764202E+05 3.5205 6 HS- 0.1267570E-05 0.1170496E-04 0.3526017E+00 -0.7710 7 H4SiO4 0.2539400E-02 0.2548935E-02 0.2231546E+03 -2.5953 8 Al+++ 0.8405785E-13 0.5412687E-06 0.1330249E-01 0.0945 9 Ca++ 0.1207122E-02 0.1909684E-02 0.6971426E+02 6.5288 10 Mg++ 0.1146644E-03 0.1558177E-03 0.3450575E+01 5.4654 11 Fe++ 0.1109097E-05 0.1454385E-05 0.7398325E-01 3.4612 12 K+ 0.4007569E-01 0.4123401E-01 0.1468617E+04 3.7462 13 Na+ 0.1112648E+01 0.1382263E+01 0.2894542E+05 5.1712 14 Mn++ 0.7772453E-05 0.3127478E-04 0.1565025E+01 4.3143 15 Zn++ 0.2722563E-07 0.6291336E-05 0.3746066E+00 1.8512 16 Cu+ 0.4523186E-11 0.1543524E-06 0.8933357E-02 -6.2203 17 Pb++ 0.5712385E-08 0.8806558E-06 0.1661993E+00 1.2285 18 Ag+ 0.2438663E-10 0.3874551E-06 0.3806941E-01 -5.4729 19 Au+ 0.5790294E-21 0.2822005E-11 0.5062970E-06 -16.0920 20 Ba++ 0.1518785E-05 0.3686886E-05 0.4612229E+00 3.6690 21 F- 0.1193822E-02 0.1478963E-02 0.2559289E+02 2.1720 22 H2AsO3- 0.1144580E-05 0.1175986E-03 0.1338267E+02 -0.7041 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234423E+00 -.7162131E-05 0.0000000E+00 2 H2O 0.6086868E+02 0.6086868E+02 0.0000000E+00 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1290347E-04 0.1126838E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2809930E-02 0.1810588E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.5966912E-06 0.1810588E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.6035292E-06 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.6935529E-05 0.5326473E-06 0.0000000E+00 16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00 17 Pb++ 0.1565021E-05 0.9708294E-06 0.5941912E-06 0.0000000E+00 18 Ag+ 0.4271281E-06 0.4271281E-06 0.0000000E+00 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1630400E-02 0.0000000E+00 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1271E-20 Mass of aqueous solution: 0.121027E+04 g Temperature = 184.87 C Pressure = 500.00 bar Mixer frac. = 0.1000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) paragonite 0.6035E-06 -6.219 0.2307E-03 -3.637 54.31 0.7973E-04 galena 0.5942E-06 -6.226 0.1422E-03 -3.847 33.47 0.1871E-04 sphalerite 0.5326E-06 -6.274 0.5190E-04 -4.285 12.22 0.1269E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.1000000 Solid products produced: Mass = 0.000425 g Volume = 0.000111 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.300 AFFINITY: 0.2990E+03 GOLD Q/K: 0.0248 SILVER Q/K: 0.3433 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 184.8730 deg.C Sat. pressure: 88.3608 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2168E+00 0.6609 0.1266E+02 0.1915E+02 CO2,gas 0.7832E+00 0.9036 0.6253E+02 0.6921E+02 CH4,gas 0.1999E-07 1.1161 0.1971E-05 0.1766E-05 H2,gas 0.2080E-05 1.0391 0.1910E-03 0.1838E-03 H2S,gas 0.7198E-05 0.8338 0.5304E-03 0.6361E-03 S2,gas 0.9251E-16 1.0000 0.8174E-14 0.8174E-14 CO,gas 0.3229E-07 1.0000 0.2854E-05 0.2854E-05 SO3,gas 0.3803E-26 1.0000 0.3361E-24 0.3361E-24 O2,gas 0.1903E-42 1.0000 0.1681E-40 0.1681E-40 SO2,gas 0.4176E-12 1.0000 0.3690E-10 0.3690E-10 HF,gas 0.3811E-07 1.0000 0.3368E-05 0.3368E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 122 paragonite -2.33 -2.33 0.00 0.000 -0.93074E-11 260 galena -10.35 -10.35 0.00 0.000 0.00000E+00 272 sphalerite -9.73 -9.73 0.00 0.000 0.00000E+00 196 argentite -22.66 -22.53 0.13 0.033 -0.27584E+03 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.58 -0.02 -1.60 -1.597 0.33462E+04 1.102 2 CO2,gas -6.37 -7.27 -0.90 -0.301 0.18923E+04 1.796 3 CH4,gas 5.45 -2.96 -8.40 -2.101 0.17614E+05 -5.705 4 H2,gas 7.49 1.07 -6.42 -3.667 0.13451E+05 -3.719 5 H2S,gas -5.61 -11.58 -5.97 -2.987 0.12521E+05 -3.275 6 S2,gas -8.51 -25.29 -16.79 -2.583 0.35182E+05 -14.088 7 CO,gas 2.06 -6.18 -8.24 -2.536 0.17277E+05 -5.545 8 SO3,gas 11.26 -15.91 -27.17 -6.793 0.56949E+05 -24.474 9 O2,gas 41.30 -2.17 -43.47 -28.982 0.91113E+05 -40.774 10 SO2,gas -1.69 -14.82 -13.13 -3.502 0.27522E+05 -10.433 11 HF,gas -0.46 -8.64 -8.17 -4.086 0.17126E+05 -5.473 12 HCl,gas 1.07 -5.63 -6.70 -3.352 0.14051E+05 -6.704 13 acmite 6.21 2.95 -3.27 -0.339 0.68460E+04 17 albite-high -1.24 -2.44 -1.20 -0.092 0.25107E+04 18 albite -1.96 -2.44 -0.48 -0.037 0.10089E+04 22 analcite 1.14 0.10 -1.05 -0.116 0.21945E+04 23 andalusite -0.53 -2.43 -1.89 -0.189 0.39639E+04 26 anhydrite -6.54 -9.40 -2.87 -1.433 0.60050E+04 27 ankerite -3.79 -4.59 -0.80 -0.133 0.16720E+04 31 anorthite 5.40 1.53 -3.88 -0.298 0.81258E+04 34 aragonite 0.02 -0.76 -0.78 -0.260 0.16377E+04 35 brucite 9.88 5.43 -4.46 -0.892 0.93443E+04 36 calcite -0.12 -0.76 -0.64 -0.214 0.13458E+04 37 carnegieite-low 5.67 2.67 -3.00 -0.429 0.62969E+04 38 carnegieite-high 6.40 2.67 -3.73 -0.532 0.78122E+04 39 carpholite-Mg 2.57 0.42 -2.15 -0.143 0.45063E+04 40 carpholite-Fe 1.01 -1.58 -2.59 -0.172 0.54216E+04 41 celadonite 2.81 -1.00 -3.81 -0.224 0.79758E+04 42 celadonite-Fe 1.48 -3.00 -4.48 -0.264 0.93949E+04 49 chloritoid-Mg 5.89 3.00 -2.89 -0.193 0.60600E+04 50 chloritoid-Fe 2.67 0.99 -1.67 -0.112 0.35100E+04 51 chloritoid-Mn 4.86 1.85 -3.01 -0.201 0.63165E+04 53 coesite -1.89 -2.56 -0.67 -0.222 0.13980E+04 58 corundum 2.16 0.13 -2.03 -0.185 0.42620E+04 60 cristobalite -2.08 -2.56 -0.48 -0.159 0.99673E+03 63 cymrite-K 0.00 -3.89 -3.89 -0.324 0.81434E+04 65 diaspore 0.31 0.05 -0.25 -0.042 0.52664E+03 66 diamond -2.23 -5.09 -2.86 -0.818 0.60009E+04 69 dolomite,ordered -1.55 -2.58 -1.03 -0.172 0.21677E+04 83 gibbsite 1.55 0.03 -1.51 -0.216 0.31691E+04 86 goethite 4.65 2.89 -1.77 -0.382 0.36993E+04 87 graphite -2.62 -5.09 -2.47 -0.706 0.51808E+04 90 halite 1.41 -0.46 -1.87 -0.935 0.39202E+04 91 hematite 8.70 5.79 -2.91 -0.352 0.60947E+04 92 heulandite -8.60 -11.37 -2.77 -0.126 0.58079E+04 96 jadeite 1.96 0.12 -1.85 -0.185 0.38721E+04 98 kalsilite 4.61 1.25 -3.37 -0.481 0.70554E+04 99 kaolinite -4.76 -5.02 -0.26 -0.024 0.55173E+03 100 kyanite -0.58 -2.43 -1.84 -0.184 0.38593E+04 102 laumontite -1.31 -3.66 -2.35 -0.157 0.49257E+04 103 lawsonite 4.00 1.49 -2.52 -0.168 0.52734E+04 104 leucite 1.67 -1.31 -2.98 -0.298 0.62466E+04 107 magnesite -0.67 -1.82 -1.15 -0.385 0.24180E+04 108 magnetite 14.03 9.24 -4.80 -0.392 0.10053E+05 114 margarite 5.08 1.64 -3.45 -0.138 0.72244E+04 117 microcline -3.44 -3.87 -0.42 -0.033 0.88917E+03 120 mullite-Si 1.21 -2.43 -3.64 -0.364 0.76300E+04 121 muscovite -3.53 -3.76 -0.23 -0.013 0.47407E+03 123 nepheline 5.08 2.67 -2.41 -0.345 0.50553E+04 143 pyrite -19.37 -20.77 -1.40 -0.329 0.29295E+04 144 pyrrhotite -4.86 -8.12 -3.25 -1.085 0.68195E+04 145 pyrrhotiteFe0.875 -6.24 -8.68 -2.45 -0.900 0.51311E+04 146 pyroxmangite 5.66 1.74 -3.92 -0.783 0.82076E+04 147 pyrophyllite -9.00 -10.11 -1.11 -0.069 0.23295E+04 148 quartz -2.39 -2.56 -0.16 -0.054 0.34086E+03 153 rhodochrosite -1.69 -2.97 -1.28 -0.427 0.26834E+04 154 rhodonite 5.68 1.74 -3.94 -0.789 0.82658E+04 155 sanidine -2.45 -3.87 -1.41 -0.109 0.29579E+04 157 siderite -3.37 -3.83 -0.46 -0.152 0.95722E+03 158 sillimanite -0.36 -2.43 -2.07 -0.207 0.43350E+04 165 stilbite -8.55 -11.39 -2.84 -0.135 0.59544E+04 168 stishovite 2.38 -2.56 -4.93 -1.645 0.10343E+05 170 sudoite 8.13 3.40 -4.72 -0.152 0.98979E+04 171 sulfur -8.52 -12.65 -4.13 -1.271 0.86585E+04 172 sylvite 1.42 -1.88 -3.30 -1.652 0.69253E+04 180 topaz-H -0.23 -2.45 -2.22 -0.202 0.46546E+04 181 tridymite -2.11 -2.56 -0.44 -0.148 0.93011E+03 184 troilite-low -4.93 -8.12 -3.18 -1.062 0.66746E+04 190 wairakite -1.02 -3.62 -2.61 -0.153 0.54618E+04 192 wollastonite 8.38 3.95 -4.43 -0.886 0.92856E+04 193 pseudo-wollastonite 8.78 3.95 -4.82 -0.965 0.10109E+05 197 arsenic -5.63 -9.85 -4.22 -1.088 0.88385E+04 199 arsenopyrite -13.50 -17.97 -4.47 -0.795 0.93667E+04 200 beidellite-Ca -6.16 -8.17 -2.01 -0.124 0.42173E+04 201 beidellite-H -6.63 -9.25 -2.62 -0.167 0.54835E+04 202 beidellite-K -5.74 -8.01 -2.28 -0.139 0.47702E+04 203 beidellite-Mg -6.40 -8.35 -1.95 -0.121 0.40902E+04 204 beidellite-Na -5.65 -7.54 -1.89 -0.116 0.39702E+04 205 bornite -73.81 -74.49 -0.68 -0.051 0.14351E+04 207 chalcedony -2.24 -2.56 -0.32 -0.105 0.66036E+03 208 chalcocite -22.58 -24.02 -1.44 -0.360 0.30153E+04 210 covellite -16.57 -18.33 -1.77 -0.674 0.37065E+04 211 dawsonite 0.04 -2.06 -2.10 -0.263 0.44022E+04 213 montmorillonite-Ca -5.38 -7.26 -1.88 -0.116 0.39403E+04 214 montmorillonite-K -5.06 -7.10 -2.05 -0.125 0.42864E+04 215 montmorillonite-Mg -5.62 -7.44 -1.82 -0.113 0.38193E+04 216 montmorillonite-Na -4.90 -6.63 -1.74 -0.106 0.36404E+04 217 nontronite-Ca 0.93 -2.51 -3.44 -0.223 0.72082E+04 218 nontronite-H 0.45 -3.59 -4.04 -0.271 0.84659E+04 219 nontronite-K 1.35 -2.35 -3.70 -0.238 0.77609E+04 220 nontronite-Mg 0.72 -2.68 -3.41 -0.221 0.71432E+04 221 nontronite-Na 1.44 -1.88 -3.32 -0.213 0.69633E+04 225 topaz -19.88 -19.68 0.20 0.022 -0.41360E+03 229 gypsum -5.62 -9.44 -3.82 -0.956 0.80148E+04 245 acanthite -22.48 -22.53 -0.04 -0.011 0.89386E+02 251 barite -9.60 -12.26 -2.66 -1.328 0.55681E+04 252 boehmite 1.41 0.05 -1.35 -0.225 0.28347E+04 253 cerussite -2.80 -6.06 -3.26 -1.085 0.68225E+04 254 chalcopyrite -25.01 -26.45 -1.44 -0.268 0.30221E+04 255 chlorargyrite -6.18 -11.10 -4.92 -2.460 0.10313E+05 256 copper,native -1.71 -5.69 -3.98 -1.384 0.83374E+04 257 dolomite,disordered -1.09 -2.58 -1.49 -0.249 0.31317E+04 258 ferrous-oxide 7.15 3.44 -3.71 -0.928 0.77826E+04 259 fluorite -10.18 -10.74 -0.56 -0.188 0.11812E+04 261 gold,native -13.95 -15.56 -1.61 -0.559 0.33663E+04 262 silver,native -4.47 -4.94 -0.46 -0.161 0.97305E+03 263 huntite -1.50 -6.23 -4.72 -0.394 0.98990E+04 269 silica-amorphous -1.71 -2.56 -0.85 -0.283 0.17766E+04 270 smithsonite -1.73 -5.44 -3.70 -1.234 0.77619E+04 273 wurtzite -8.24 -9.73 -1.49 -0.497 0.31243E+04 274 zincite 5.99 1.83 -4.16 -1.040 0.87195E+04 275 an20ab80 -0.70 -1.65 -0.94 -0.073 0.19771E+04 276 an25ab75 -0.36 -1.45 -1.09 -0.084 0.22765E+04 277 an30ab70 -0.02 -1.25 -1.23 -0.095 0.25879E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 70 Temperature = 184.87 C Pressure = 500.00 bar Mixer fraction = 0.1000000 Water: Moles liquid = 0.6119E+02 kg liquid = 0.1102E+01 Moles total = 0.6087E+02 kg total = 0.1097E+01 Activity = 0.9551 Stoichiometric ionic strength = .1585132E+01 Osmotic coef. = 0.9098 True ionic strength = .1157677E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.79479E-05 -5.0997 0.39417E-05 -5.4043 0.49594E+00 -0.3046 2 H2O 0.95508E+00 -0.0200 0.95508E+00 -0.0200 3 Cl- 0.11307E+01 0.0533 0.59352E+00 -0.2266 0.52493E+00 -0.2799 4 SO4-- 0.15389E-03 -3.8128 0.75718E-05 -5.1208 0.49202E-01 -1.3080 5 HCO3- 0.24039E-01 -1.6191 0.13068E-01 -1.8838 0.54364E+00 -0.2647 6 HS- 0.12658E-05 -5.8976 0.66700E-06 -6.1759 0.52692E+00 -0.2783 7 H4SiO4 0.25394E-02 -2.5953 0.25394E-02 -2.5953 0.10000E+01 0.0000 8 Al+++ 0.84058E-13 -13.0754 0.76127E-16 -16.1185 0.90564E-03 -3.0430 9 Ca++ 0.12071E-02 -2.9182 0.52503E-04 -4.2798 0.43494E-01 -1.3616 10 Mg++ 0.11466E-03 -3.9406 0.45369E-05 -5.3432 0.39567E-01 -1.4027 11 Fe++ 0.11091E-05 -5.9550 0.44932E-07 -7.3474 0.40512E-01 -1.3924 12 K+ 0.40076E-01 -1.3971 0.21975E-01 -1.6581 0.54834E+00 -0.2609 13 Na+ 0.11126E+01 0.0464 0.58463E+00 -0.2331 0.52544E+00 -0.2795 14 Mn++ 0.77725E-05 -5.1094 0.32041E-06 -6.4943 0.41224E-01 -1.3848 15 Zn++ 0.27263E-07 -7.5644 0.11045E-08 -8.9568 0.40512E-01 -1.3924 16 Cu+ 0.45232E-11 -11.3446 0.23737E-11 -11.6246 0.52478E+00 -0.2800 17 Pb++ 0.57202E-08 -8.2426 0.26330E-09 -9.5795 0.46030E-01 -1.3370 18 Ag+ 0.20972E-10 -10.6784 0.11410E-10 -10.9427 0.54404E+00 -0.2644 19 Au+ 0.57981E-21 -21.2367 0.31934E-21 -21.4957 0.55077E+00 -0.2590 20 Ba++ 0.15188E-05 -5.8185 0.72500E-07 -7.1397 0.47735E-01 -1.3212 21 F- 0.11938E-02 -2.9231 0.58573E-03 -3.2323 0.49064E+00 -0.3092 22 H2AsO3- 0.11446E-05 -5.9414 0.77909E-06 -6.1084 0.68068E+00 -0.1671 24 HSiO3- 0.27573E-05 -5.5595 0.14474E-05 -5.8394 0.52493E+00 -0.2799 25 Ca(HSiO3)+ 0.13116E-07 -7.8822 0.72239E-08 -8.1412 0.55077E+00 -0.2590 26 Mg(HSiO3)+ 0.99951E-09 -9.0002 0.55051E-09 -9.2592 0.55077E+00 -0.2590 27 NaHSiO3,aq 0.67643E-05 -5.1698 0.67643E-05 -5.1698 0.10000E+01 0.0000 31 AgCl,aq 0.37653E-08 -8.4242 0.37653E-08 -8.4242 0.10000E+01 0.0000 32 AgCl2- 0.17641E-06 -6.7535 0.92602E-07 -7.0334 0.52493E+00 -0.2799 33 AgCl3-2 0.12282E-06 -6.9107 0.58162E-08 -8.2354 0.47356E-01 -1.3246 34 AgCl4-3 0.21809E-07 -7.6614 0.19300E-10 -10.7144 0.88496E-03 -3.0531 38 Ag(HS),aq 0.83669E-08 -8.0774 0.83669E-08 -8.0774 0.10000E+01 0.0000 40 AlO+ 0.24202E-09 -9.6162 0.13330E-09 -9.8752 0.55077E+00 -0.2590 42 HAlO2,aq 0.52450E-07 -7.2803 0.52450E-07 -7.2803 0.10000E+01 0.0000 43 AlO2- 0.48857E-06 -6.3111 0.24230E-06 -6.6156 0.49594E+00 -0.3046 44 AsO2- 0.19972E-06 -6.6996 0.10484E-06 -6.9795 0.52493E+00 -0.2799 45 HAsO2,aq 0.31282E-04 -4.5047 0.31282E-04 -4.5047 0.10000E+01 0.0000 46 H3AsO3,aq 0.84973E-04 -4.0707 0.84973E-04 -4.0707 0.10000E+01 0.0000 48 H2AsO4- 0.10581E-09 -9.9755 0.55542E-10 -10.2554 0.52493E+00 -0.2799 49 HAsO4-2 0.23661E-10 -10.6260 0.11205E-11 -11.9506 0.47356E-01 -1.3246 62 BaCO3,aq 0.43660E-09 -9.3599 0.43660E-09 -9.3599 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.13496E-05 -5.8698 0.75850E-06 -6.1200 0.56203E+00 -0.2502 64 BaCl+ 0.81719E-06 -6.0877 0.45009E-06 -6.3467 0.55077E+00 -0.2590 65 BaF+ 0.90306E-09 -9.0443 0.49738E-09 -9.3033 0.55077E+00 -0.2590 66 CH4,aq 0.12703E-08 -8.8961 0.11600E-08 -8.9355 0.91321E+00 -0.0394 71 CO,aq 0.23193E-08 -8.6346 0.23193E-08 -8.6346 0.10000E+01 0.0000 72 CO2,aq 0.29321E+00 -0.5328 0.26776E+00 -0.5723 0.91321E+00 -0.0394 73 CO3-2 0.54790E-05 -5.2613 0.25946E-06 -6.5859 0.47356E-01 -1.3246 74 CaCO3,aq 0.12586E-05 -5.9001 0.12586E-05 -5.9001 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.15892E-03 -3.7988 0.87531E-04 -4.0578 0.55077E+00 -0.2590 76 CaCl+ 0.49470E-03 -3.3057 0.27247E-03 -3.5647 0.55077E+00 -0.2590 77 CaCl2,aq 0.42417E-04 -4.3725 0.42417E-04 -4.3725 0.10000E+01 0.0000 78 CaF+ 0.46499E-05 -5.3326 0.25610E-05 -5.5916 0.55077E+00 -0.2590 79 CaOH+ 0.12978E-06 -6.8868 0.71481E-07 -7.1458 0.55077E+00 -0.2590 80 CaSO4,aq 0.46856E-06 -6.3292 0.46856E-06 -6.3292 0.10000E+01 0.0000 81 HCl,aq 0.13044E-05 -5.8846 0.13044E-05 -5.8846 0.10000E+01 0.0000 90 CuCl,aq 0.65807E-08 -8.1817 0.65807E-08 -8.1817 0.10000E+01 0.0000 91 CuCl2- 0.12092E-06 -6.9175 0.63474E-07 -7.1974 0.52493E+00 -0.2799 92 CuCl3-2 0.26848E-07 -7.5711 0.12714E-08 -8.8957 0.47356E-01 -1.3246 98 HF,aq 0.79934E-04 -4.0973 0.79934E-04 -4.0973 0.10000E+01 0.0000 99 HF2- 0.25131E-07 -7.5998 0.13192E-07 -7.8797 0.52493E+00 -0.2799 101 FeCl+ 0.31873E-06 -6.4966 0.17555E-06 -6.7556 0.55077E+00 -0.2590 102 FeCl2,aq 0.21097E-08 -8.6758 0.21097E-08 -8.6758 0.10000E+01 0.0000 104 FeF+ 0.81401E-08 -8.0894 0.44833E-08 -8.3484 0.55077E+00 -0.2590 106 FeO,aq 0.87747E-10 -10.0568 0.87747E-10 -10.0568 0.10000E+01 0.0000 107 FeOH+ 0.16143E-07 -7.7920 0.88910E-08 -8.0511 0.55077E+00 -0.2590 112 HFeO2,aq 0.72049E-10 -10.1424 0.72049E-10 -10.1424 0.10000E+01 0.0000 113 H2,aq 0.19523E-06 -6.7094 0.17829E-06 -6.7489 0.91321E+00 -0.0394 114 KCl,aq 0.11421E-02 -2.9423 0.11421E-02 -2.9423 0.10000E+01 0.0000 115 KHSO4,aq 0.19781E-09 -9.7038 0.19781E-09 -9.7038 0.10000E+01 0.0000 116 KOH,aq 0.46425E-07 -7.3332 0.46425E-07 -7.3332 0.10000E+01 0.0000 117 KSO4- 0.16190E-04 -4.7908 0.84984E-05 -5.0707 0.52493E+00 -0.2799 118 MgCO3,aq 0.15585E-07 -7.8073 0.15585E-07 -7.8073 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.13371E-04 -4.8738 0.73646E-05 -5.1329 0.55077E+00 -0.2590 120 MgCl+ 0.26503E-04 -4.5767 0.14597E-04 -4.8357 0.55077E+00 -0.2590 121 MgF+ 0.12216E-05 -5.9131 0.67283E-06 -6.1721 0.55077E+00 -0.2590 122 MgOH+ 0.40257E-07 -7.3952 0.22172E-07 -7.6542 0.55077E+00 -0.2590 124 MnF+ 0.22765E-07 -7.6427 0.12538E-07 -7.9018 0.55077E+00 -0.2590 125 MnO,aq 0.19571E-10 -10.7084 0.19571E-10 -10.7084 0.10000E+01 0.0000 126 MnOH+ 0.14871E-07 -7.8276 0.81908E-08 -8.0867 0.55077E+00 -0.2590 131 MnCl+ 0.23461E-04 -4.6296 0.12922E-04 -4.8887 0.55077E+00 -0.2590 132 MnSO4,aq 0.32936E-08 -8.4823 0.32936E-08 -8.4823 0.10000E+01 0.0000 133 NaCl,aq 0.26941E+00 -0.5696 0.26941E+00 -0.5696 0.10000E+01 0.0000 134 NaF,aq 0.19925E-03 -3.7006 0.19925E-03 -3.7006 0.10000E+01 0.0000 135 NaOH,aq 0.92017E-06 -6.0361 0.92017E-06 -6.0361 0.10000E+01 0.0000 137 OH- 0.32569E-05 -5.4872 0.16152E-05 -5.7918 0.49594E+00 -0.3046 140 PbCl+ 0.65303E-07 -7.1851 0.35967E-07 -7.4441 0.55077E+00 -0.2590 141 PbCl2,aq 0.28314E-06 -6.5480 0.28314E-06 -6.5480 0.10000E+01 0.0000 142 PbCl3- 0.21869E-06 -6.6602 0.11480E-06 -6.9401 0.52493E+00 -0.2799 143 PbCl4-2 0.30871E-06 -6.5105 0.14619E-07 -7.8351 0.47356E-01 -1.3246 144 PbF+ 0.95741E-10 -10.0189 0.52732E-10 -10.2779 0.55077E+00 -0.2590 146 PbO,aq 0.37358E-10 -10.4276 0.37358E-10 -10.4276 0.10000E+01 0.0000 148 Pb(HS)2,aq 0.17105E-09 -9.7669 0.17105E-09 -9.7669 0.10000E+01 0.0000 150 H2S,aq 0.10362E-04 -4.9845 0.94631E-05 -5.0240 0.91321E+00 -0.0394 158 HSO3- 0.20647E-09 -9.6851 0.10838E-09 -9.9650 0.52493E+00 -0.2799 159 HSO4- 0.61358E-06 -6.2121 0.34358E-06 -6.4640 0.55996E+00 -0.2518 161 S2O3-2 0.22115E-10 -10.6553 0.10473E-11 -11.9799 0.47356E-01 -1.3246 173 ZnCl+ 0.46897E-05 -5.3289 0.25830E-05 -5.5879 0.55077E+00 -0.2590 174 ZnCl2,aq 0.11980E-05 -5.9216 0.11980E-05 -5.9216 0.10000E+01 0.0000 175 ZnCl3- 0.16212E-06 -6.7902 0.85101E-07 -7.0701 0.52493E+00 -0.2799 176 ZnF+ 0.13342E-09 -9.8748 0.73487E-10 -10.1338 0.55077E+00 -0.2590 177 ZnO,aq 0.28753E-09 -9.5413 0.28753E-09 -9.5413 0.10000E+01 0.0000 178 ZnOH+ 0.22247E-06 -6.6527 0.12253E-06 -6.9117 0.55077E+00 -0.2590 Charge balance for all species = -.1176E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7947930E-05 0.2934000E+00 0.2693698E+03 0.0000 2 H2O 0.1000000E+01 0.5521501E+02 0.9060512E+06 0.0000 3 Cl- 0.1130665E+01 0.1401859E+01 0.4527008E+05 5.1777 4 SO4-- 0.1538930E-03 0.1711179E-03 0.1497267E+02 5.6878 5 HCO3- 0.2403853E-01 0.3174256E+00 0.1764202E+05 3.5205 6 HS- 0.1265837E-05 0.1168766E-04 0.3520805E+00 -0.7716 7 H4SiO4 0.2539400E-02 0.2548935E-02 0.2231546E+03 -2.5953 8 Al+++ 0.8405824E-13 0.5412683E-06 0.1330248E-01 0.0945 9 Ca++ 0.1207122E-02 0.1909684E-02 0.6971426E+02 6.5288 10 Mg++ 0.1146644E-03 0.1558177E-03 0.3450575E+01 5.4654 11 Fe++ 0.1109097E-05 0.1454385E-05 0.7398325E-01 3.4612 12 K+ 0.4007569E-01 0.4123401E-01 0.1468617E+04 3.7462 13 Na+ 0.1112648E+01 0.1382263E+01 0.2894542E+05 5.1712 14 Mn++ 0.7772452E-05 0.3127478E-04 0.1565025E+01 4.3143 15 Zn++ 0.2726294E-07 0.6299958E-05 0.3751200E+00 1.8518 16 Cu+ 0.4523185E-11 0.1543524E-06 0.8933357E-02 -6.2203 17 Pb++ 0.5720214E-08 0.8818624E-06 0.1664270E+00 1.2291 18 Ag+ 0.2097214E-10 0.3331942E-06 0.3273801E-01 -5.5384 19 Au+ 0.5798062E-21 0.2822005E-11 0.5062970E-06 -16.0914 20 Ba++ 0.1518786E-05 0.3686886E-05 0.4612229E+00 3.6690 21 F- 0.1193822E-02 0.1478963E-02 0.2559289E+02 2.1720 22 H2AsO3- 0.1144578E-05 0.1175986E-03 0.1338267E+02 -0.7041 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234423E+00 -.7181205E-05 0.0000000E+00 2 H2O 0.6086868E+02 0.6086868E+02 0.0000000E+00 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1288440E-04 0.1145912E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2809930E-02 0.1810588E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.5966908E-06 0.1810588E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.6035294E-06 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.6945034E-05 0.5231421E-06 0.0000000E+00 16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00 17 Pb++ 0.1565021E-05 0.9721596E-06 0.5928610E-06 0.0000000E+00 18 Ag+ 0.4271281E-06 0.3673112E-06 0.5981688E-07 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1630400E-02 0.0000000E+00 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5956E-21 Mass of aqueous solution: 0.121027E+04 g Temperature = 184.87 C Pressure = 500.00 bar Mixer frac. = 0.1000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) paragonite 0.6035E-06 -6.219 0.2307E-03 -3.637 53.53 0.7973E-04 galena 0.5929E-06 -6.227 0.1418E-03 -3.848 32.92 0.1867E-04 sphalerite 0.5231E-06 -6.281 0.5097E-04 -4.293 11.83 0.1247E-04 argentite 0.2991E-07 -7.524 0.7411E-05 -5.130 1.720 0.1041E-05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 argentite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.1000000 Solid products produced: Mass = 0.000431 g Volume = 0.000112 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.300 AFFINITY: 0.3949E+03 GOLD Q/K: 0.0248 SILVER Q/K: 0.2952 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 184.8730 deg.C Sat. pressure: 88.3608 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2168E+00 0.6609 0.1266E+02 0.1915E+02 CO2,gas 0.7832E+00 0.9036 0.6253E+02 0.6921E+02 CH4,gas 0.1996E-07 1.1161 0.1969E-05 0.1764E-05 H2,gas 0.2079E-05 1.0391 0.1909E-03 0.1837E-03 H2S,gas 0.7189E-05 0.8338 0.5296E-03 0.6352E-03 S2,gas 0.9232E-16 1.0000 0.8157E-14 0.8157E-14 CO,gas 0.3228E-07 1.0000 0.2853E-05 0.2853E-05 SO3,gas 0.3803E-26 1.0000 0.3361E-24 0.3361E-24 O2,gas 0.1904E-42 1.0000 0.1683E-40 0.1683E-40 SO2,gas 0.4175E-12 1.0000 0.3689E-10 0.3689E-10 HF,gas 0.3811E-07 1.0000 0.3368E-05 0.3368E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 122 paragonite -2.33 -2.33 0.00 0.000 -0.93074E-11 196 argentite -22.66 -22.66 0.00 0.000 0.74459E-11 260 galena -10.35 -10.35 0.00 0.000 0.37230E-11 272 sphalerite -9.73 -9.73 0.00 0.000 0.37230E-11 225 topaz -19.88 -19.68 0.20 0.022 -0.41361E+03 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.58 -0.02 -1.60 -1.597 0.33462E+04 1.102 2 CO2,gas -6.37 -7.27 -0.90 -0.301 0.18923E+04 1.796 3 CH4,gas 5.45 -2.96 -8.40 -2.101 0.17615E+05 -5.706 4 H2,gas 7.49 1.07 -6.42 -3.668 0.13451E+05 -3.719 5 H2S,gas -5.61 -11.58 -5.97 -2.987 0.12523E+05 -3.276 6 S2,gas -8.51 -25.30 -16.79 -2.583 0.35184E+05 -14.088 7 CO,gas 2.06 -6.18 -8.24 -2.537 0.17278E+05 -5.545 8 SO3,gas 11.26 -15.91 -27.17 -6.793 0.56949E+05 -24.474 9 O2,gas 41.30 -2.17 -43.47 -28.982 0.91112E+05 -40.774 10 SO2,gas -1.69 -14.82 -13.13 -3.502 0.27523E+05 -10.433 11 HF,gas -0.46 -8.64 -8.17 -4.086 0.17126E+05 -5.473 12 HCl,gas 1.07 -5.63 -6.70 -3.352 0.14051E+05 -6.704 13 acmite 6.21 2.95 -3.27 -0.339 0.68458E+04 17 albite-high -1.24 -2.44 -1.20 -0.092 0.25107E+04 18 albite -1.96 -2.44 -0.48 -0.037 0.10089E+04 22 analcite 1.14 0.10 -1.05 -0.116 0.21945E+04 23 andalusite -0.53 -2.43 -1.89 -0.189 0.39639E+04 26 anhydrite -6.54 -9.40 -2.87 -1.433 0.60050E+04 27 ankerite -3.79 -4.59 -0.80 -0.133 0.16721E+04 31 anorthite 5.40 1.53 -3.88 -0.298 0.81258E+04 34 aragonite 0.02 -0.76 -0.78 -0.260 0.16377E+04 35 brucite 9.88 5.43 -4.46 -0.892 0.93443E+04 36 calcite -0.12 -0.76 -0.64 -0.214 0.13458E+04 37 carnegieite-low 5.67 2.67 -3.00 -0.429 0.62969E+04 38 carnegieite-high 6.40 2.67 -3.73 -0.532 0.78122E+04 39 carpholite-Mg 2.57 0.42 -2.15 -0.143 0.45063E+04 40 carpholite-Fe 1.01 -1.58 -2.59 -0.172 0.54216E+04 41 celadonite 2.81 -1.00 -3.81 -0.224 0.79758E+04 42 celadonite-Fe 1.48 -3.00 -4.48 -0.264 0.93949E+04 49 chloritoid-Mg 5.89 3.00 -2.89 -0.193 0.60600E+04 50 chloritoid-Fe 2.67 0.99 -1.67 -0.112 0.35100E+04 51 chloritoid-Mn 4.86 1.85 -3.01 -0.201 0.63166E+04 53 coesite -1.89 -2.56 -0.67 -0.222 0.13980E+04 58 corundum 2.16 0.13 -2.03 -0.185 0.42620E+04 60 cristobalite -2.08 -2.56 -0.48 -0.159 0.99673E+03 63 cymrite-K 0.00 -3.89 -3.89 -0.324 0.81434E+04 65 diaspore 0.31 0.05 -0.25 -0.042 0.52664E+03 66 diamond -2.23 -5.09 -2.86 -0.818 0.60015E+04 69 dolomite,ordered -1.55 -2.58 -1.03 -0.172 0.21677E+04 83 gibbsite 1.55 0.03 -1.51 -0.216 0.31691E+04 86 goethite 4.65 2.89 -1.77 -0.382 0.36992E+04 87 graphite -2.62 -5.09 -2.47 -0.706 0.51814E+04 90 halite 1.41 -0.46 -1.87 -0.935 0.39202E+04 91 hematite 8.70 5.80 -2.91 -0.352 0.60944E+04 92 heulandite -8.60 -11.37 -2.77 -0.126 0.58079E+04 96 jadeite 1.96 0.12 -1.85 -0.185 0.38721E+04 98 kalsilite 4.61 1.25 -3.37 -0.481 0.70554E+04 99 kaolinite -4.76 -5.02 -0.26 -0.024 0.55172E+03 100 kyanite -0.58 -2.43 -1.84 -0.184 0.38593E+04 102 laumontite -1.31 -3.66 -2.35 -0.157 0.49257E+04 103 lawsonite 4.00 1.49 -2.52 -0.168 0.52734E+04 104 leucite 1.67 -1.31 -2.98 -0.298 0.62466E+04 107 magnesite -0.67 -1.82 -1.15 -0.385 0.24180E+04 108 magnetite 14.03 9.24 -4.80 -0.392 0.10053E+05 114 margarite 5.08 1.64 -3.45 -0.138 0.72244E+04 117 microcline -3.44 -3.87 -0.42 -0.033 0.88917E+03 120 mullite-Si 1.21 -2.43 -3.64 -0.364 0.76300E+04 121 muscovite -3.53 -3.76 -0.23 -0.013 0.47407E+03 123 nepheline 5.08 2.67 -2.41 -0.345 0.50554E+04 143 pyrite -19.37 -20.77 -1.40 -0.329 0.29317E+04 144 pyrrhotite -4.86 -8.12 -3.25 -1.085 0.68208E+04 145 pyrrhotiteFe0.875 -6.24 -8.68 -2.45 -0.901 0.51323E+04 146 pyroxmangite 5.66 1.74 -3.92 -0.783 0.82076E+04 147 pyrophyllite -9.00 -10.11 -1.11 -0.069 0.23295E+04 148 quartz -2.39 -2.56 -0.16 -0.054 0.34086E+03 153 rhodochrosite -1.69 -2.97 -1.28 -0.427 0.26834E+04 154 rhodonite 5.68 1.74 -3.94 -0.789 0.82658E+04 155 sanidine -2.45 -3.87 -1.41 -0.109 0.29579E+04 157 siderite -3.37 -3.83 -0.46 -0.152 0.95722E+03 158 sillimanite -0.36 -2.43 -2.07 -0.207 0.43350E+04 165 stilbite -8.55 -11.39 -2.84 -0.135 0.59544E+04 168 stishovite 2.38 -2.56 -4.93 -1.645 0.10343E+05 170 sudoite 8.13 3.40 -4.72 -0.152 0.98979E+04 171 sulfur -8.52 -12.65 -4.13 -1.271 0.86594E+04 172 sylvite 1.42 -1.88 -3.30 -1.652 0.69253E+04 180 topaz-H -0.23 -2.45 -2.22 -0.202 0.46546E+04 181 tridymite -2.11 -2.56 -0.44 -0.148 0.93011E+03 184 troilite-low -4.93 -8.12 -3.19 -1.062 0.66759E+04 190 wairakite -1.02 -3.62 -2.61 -0.153 0.54618E+04 192 wollastonite 8.38 3.95 -4.43 -0.886 0.92856E+04 193 pseudo-wollastonite 8.78 3.95 -4.82 -0.965 0.10109E+05 197 arsenic -5.63 -9.85 -4.22 -1.088 0.88390E+04 199 arsenopyrite -13.50 -17.97 -4.47 -0.795 0.93684E+04 200 beidellite-Ca -6.16 -8.17 -2.01 -0.124 0.42173E+04 201 beidellite-H -6.63 -9.25 -2.62 -0.167 0.54835E+04 202 beidellite-K -5.74 -8.01 -2.28 -0.139 0.47702E+04 203 beidellite-Mg -6.40 -8.35 -1.95 -0.121 0.40902E+04 204 beidellite-Na -5.65 -7.54 -1.89 -0.116 0.39702E+04 205 bornite -73.81 -74.49 -0.69 -0.051 0.14400E+04 207 chalcedony -2.24 -2.56 -0.32 -0.105 0.66036E+03 208 chalcocite -22.58 -24.02 -1.44 -0.360 0.30165E+04 210 covellite -16.57 -18.33 -1.77 -0.674 0.37076E+04 211 dawsonite 0.04 -2.06 -2.10 -0.263 0.44022E+04 213 montmorillonite-Ca -5.38 -7.26 -1.88 -0.116 0.39403E+04 214 montmorillonite-K -5.06 -7.10 -2.05 -0.125 0.42864E+04 215 montmorillonite-Mg -5.62 -7.44 -1.82 -0.113 0.38193E+04 216 montmorillonite-Na -4.90 -6.63 -1.74 -0.106 0.36404E+04 217 nontronite-Ca 0.93 -2.51 -3.44 -0.223 0.72079E+04 218 nontronite-H 0.45 -3.58 -4.04 -0.271 0.84656E+04 219 nontronite-K 1.35 -2.35 -3.70 -0.238 0.77606E+04 220 nontronite-Mg 0.72 -2.68 -3.41 -0.221 0.71429E+04 221 nontronite-Na 1.44 -1.88 -3.32 -0.213 0.69630E+04 229 gypsum -5.62 -9.44 -3.82 -0.956 0.80148E+04 245 acanthite -22.48 -22.66 -0.17 -0.044 0.36523E+03 251 barite -9.60 -12.26 -2.66 -1.328 0.55681E+04 252 boehmite 1.41 0.05 -1.35 -0.225 0.28347E+04 253 cerussite -2.80 -6.06 -3.25 -1.085 0.68213E+04 254 chalcopyrite -25.01 -26.45 -1.44 -0.268 0.30244E+04 255 chlorargyrite -6.18 -11.17 -4.99 -2.493 0.10450E+05 256 copper,native -1.71 -5.69 -3.98 -1.384 0.83376E+04 257 dolomite,disordered -1.09 -2.58 -1.49 -0.249 0.31317E+04 258 ferrous-oxide 7.15 3.44 -3.71 -0.928 0.77826E+04 259 fluorite -10.18 -10.74 -0.56 -0.188 0.11812E+04 261 gold,native -13.95 -15.56 -1.61 -0.559 0.33653E+04 262 silver,native -4.47 -5.00 -0.53 -0.184 0.11105E+04 263 huntite -1.50 -6.23 -4.72 -0.394 0.98991E+04 269 silica-amorphous -1.71 -2.56 -0.85 -0.283 0.17766E+04 270 smithsonite -1.73 -5.44 -3.70 -1.234 0.77607E+04 273 wurtzite -8.24 -9.73 -1.49 -0.497 0.31243E+04 274 zincite 5.99 1.83 -4.16 -1.040 0.87183E+04 275 an20ab80 -0.70 -1.65 -0.94 -0.073 0.19771E+04 276 an25ab75 -0.36 -1.45 -1.09 -0.084 0.22765E+04 277 an30ab70 -0.02 -1.25 -1.23 -0.095 0.25879E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 70 Temperature = 184.87 C Pressure = 500.00 bar Mixer fraction = 0.1000000 Water: Moles liquid = 0.6119E+02 kg liquid = 0.1102E+01 Moles total = 0.6087E+02 kg total = 0.1097E+01 Activity = 0.9551 Stoichiometric ionic strength = .1585048E+01 Osmotic coef. = 0.9098 True ionic strength = .1157778E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.78365E-05 -5.1059 0.38864E-05 -5.4104 0.49594E+00 -0.3046 2 H2O 0.95508E+00 -0.0200 0.95508E+00 -0.0200 3 Cl- 0.11307E+01 0.0533 0.59351E+00 -0.2266 0.52493E+00 -0.2799 4 SO4-- 0.15390E-03 -3.8128 0.75718E-05 -5.1208 0.49198E-01 -1.3080 5 HCO3- 0.24354E-01 -1.6134 0.13240E-01 -1.8781 0.54364E+00 -0.2647 6 HS- 0.12690E-05 -5.8965 0.66866E-06 -6.1748 0.52692E+00 -0.2783 7 H4SiO4 0.26638E-02 -2.5745 0.26638E-02 -2.5745 0.10000E+01 0.0000 8 Al+++ 0.76459E-13 -13.1166 0.69232E-16 -16.1597 0.90548E-03 -3.0431 9 Ca++ 0.12063E-02 -2.9185 0.52464E-04 -4.2801 0.43491E-01 -1.3616 10 Mg++ 0.11469E-03 -3.9405 0.45375E-05 -5.3432 0.39563E-01 -1.4027 11 Fe++ 0.11100E-05 -5.9547 0.44965E-07 -7.3471 0.40509E-01 -1.3924 12 K+ 0.40076E-01 -1.3971 0.21975E-01 -1.6581 0.54835E+00 -0.2609 13 Na+ 0.11127E+01 0.0464 0.58469E+00 -0.2331 0.52545E+00 -0.2795 14 Mn++ 0.77739E-05 -5.1094 0.32045E-06 -6.4942 0.41221E-01 -1.3849 15 Zn++ 0.26816E-07 -7.5716 0.10863E-08 -8.9641 0.40509E-01 -1.3924 16 Cu+ 0.45233E-11 -11.3445 0.23737E-11 -11.6246 0.52478E+00 -0.2800 17 Pb++ 0.56264E-08 -8.2498 0.25897E-09 -9.5868 0.46027E-01 -1.3370 18 Ag+ 0.20799E-10 -10.6820 0.11315E-10 -10.9463 0.54404E+00 -0.2644 19 Au+ 0.57820E-21 -21.2379 0.31846E-21 -21.4970 0.55078E+00 -0.2590 20 Ba++ 0.15117E-05 -5.8205 0.72155E-07 -7.1417 0.47732E-01 -1.3212 21 F- 0.99276E-03 -3.0032 0.48708E-03 -3.3124 0.49064E+00 -0.3092 22 H2AsO3- 0.11607E-05 -5.9353 0.79005E-06 -6.1023 0.68068E+00 -0.1671 24 HSiO3- 0.29335E-05 -5.5326 0.15399E-05 -5.8125 0.52493E+00 -0.2799 25 Ca(HSiO3)+ 0.13944E-07 -7.8556 0.76799E-08 -8.1146 0.55078E+00 -0.2590 26 Mg(HSiO3)+ 0.10635E-08 -8.9732 0.58577E-09 -9.2323 0.55078E+00 -0.2590 27 NaHSiO3,aq 0.71972E-05 -5.1428 0.71972E-05 -5.1428 0.10000E+01 0.0000 31 AgCl,aq 0.37341E-08 -8.4278 0.37341E-08 -8.4278 0.10000E+01 0.0000 32 AgCl2- 0.17495E-06 -6.7571 0.91834E-07 -7.0370 0.52493E+00 -0.2799 33 AgCl3-2 0.12181E-06 -6.9143 0.57679E-08 -8.2390 0.47353E-01 -1.3247 34 AgCl4-3 0.21632E-07 -7.6649 0.19140E-10 -10.7181 0.88480E-03 -3.0532 38 Ag(HS),aq 0.83184E-08 -8.0800 0.83184E-08 -8.0800 0.10000E+01 0.0000 40 AlO+ 0.22640E-09 -9.6451 0.12470E-09 -9.9041 0.55078E+00 -0.2590 42 HAlO2,aq 0.49764E-07 -7.3031 0.49764E-07 -7.3031 0.10000E+01 0.0000 43 AlO2- 0.47015E-06 -6.3278 0.23317E-06 -6.6323 0.49594E+00 -0.3046 44 AsO2- 0.20253E-06 -6.6935 0.10631E-06 -6.9734 0.52493E+00 -0.2799 45 HAsO2,aq 0.31277E-04 -4.5048 0.31277E-04 -4.5048 0.10000E+01 0.0000 46 H3AsO3,aq 0.84959E-04 -4.0708 0.84959E-04 -4.0708 0.10000E+01 0.0000 48 H2AsO4- 0.10685E-09 -9.9712 0.56089E-10 -10.2511 0.52493E+00 -0.2799 49 HAsO4-2 0.24236E-10 -10.6155 0.11476E-11 -11.9402 0.47353E-01 -1.3247 62 BaCO3,aq 0.44649E-09 -9.3502 0.44649E-09 -9.3502 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.13608E-05 -5.8662 0.76480E-06 -6.1165 0.56203E+00 -0.2502 64 BaCl+ 0.81329E-06 -6.0898 0.44794E-06 -6.3488 0.55078E+00 -0.2590 65 BaF+ 0.74738E-09 -9.1265 0.41164E-09 -9.3855 0.55078E+00 -0.2590 66 CH4,aq 0.12902E-08 -8.8894 0.11782E-08 -8.9288 0.91321E+00 -0.0394 71 CO,aq 0.23264E-08 -8.6333 0.23264E-08 -8.6333 0.10000E+01 0.0000 72 CO2,aq 0.29289E+00 -0.5333 0.26747E+00 -0.5727 0.91321E+00 -0.0394 73 CO3-2 0.56303E-05 -5.2495 0.26661E-06 -6.5741 0.47353E-01 -1.3247 74 CaCO3,aq 0.12923E-05 -5.8886 0.12923E-05 -5.8886 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.16089E-03 -3.7935 0.88615E-04 -4.0525 0.55078E+00 -0.2590 76 CaCl+ 0.49433E-03 -3.3060 0.27226E-03 -3.5650 0.55078E+00 -0.2590 77 CaCl2,aq 0.42385E-04 -4.3728 0.42385E-04 -4.3728 0.10000E+01 0.0000 78 CaF+ 0.38639E-05 -5.4130 0.21281E-05 -5.6720 0.55078E+00 -0.2590 79 CaOH+ 0.13153E-06 -6.8810 0.72444E-07 -7.1400 0.55078E+00 -0.2590 80 CaSO4,aq 0.46821E-06 -6.3296 0.46821E-06 -6.3296 0.10000E+01 0.0000 81 HCl,aq 0.12860E-05 -5.8907 0.12860E-05 -5.8907 0.10000E+01 0.0000 90 CuCl,aq 0.65807E-08 -8.1817 0.65807E-08 -8.1817 0.10000E+01 0.0000 91 CuCl2- 0.12092E-06 -6.9175 0.63473E-07 -7.1974 0.52493E+00 -0.2799 92 CuCl3-2 0.26850E-07 -7.5711 0.12714E-08 -8.8957 0.47353E-01 -1.3247 98 HF,aq 0.65539E-04 -4.1835 0.65539E-04 -4.1835 0.10000E+01 0.0000 99 HF2- 0.17135E-07 -7.7661 0.89947E-08 -8.0460 0.52493E+00 -0.2799 101 FeCl+ 0.31896E-06 -6.4963 0.17567E-06 -6.7553 0.55078E+00 -0.2590 102 FeCl2,aq 0.21112E-08 -8.6755 0.21112E-08 -8.6755 0.10000E+01 0.0000 104 FeF+ 0.67741E-08 -8.1692 0.37310E-08 -8.4282 0.55078E+00 -0.2590 106 FeO,aq 0.90327E-10 -10.0442 0.90327E-10 -10.0442 0.10000E+01 0.0000 107 FeOH+ 0.16384E-07 -7.7856 0.90240E-08 -8.0446 0.55078E+00 -0.2590 112 HFeO2,aq 0.74013E-10 -10.1307 0.74013E-10 -10.1307 0.10000E+01 0.0000 113 H2,aq 0.19605E-06 -6.7076 0.17903E-06 -6.7471 0.91321E+00 -0.0394 114 KCl,aq 0.11421E-02 -2.9423 0.11421E-02 -2.9423 0.10000E+01 0.0000 115 KHSO4,aq 0.19503E-09 -9.7099 0.19503E-09 -9.7099 0.10000E+01 0.0000 116 KOH,aq 0.47086E-07 -7.3271 0.47086E-07 -7.3271 0.10000E+01 0.0000 117 KSO4- 0.16190E-04 -4.7908 0.84984E-05 -5.0707 0.52493E+00 -0.2799 118 MgCO3,aq 0.16016E-07 -7.7954 0.16016E-07 -7.7954 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.13549E-04 -4.8681 0.74623E-05 -5.1271 0.55078E+00 -0.2590 120 MgCl+ 0.26507E-04 -4.5766 0.14599E-04 -4.8357 0.55078E+00 -0.2590 121 MgF+ 0.10160E-05 -5.9931 0.55959E-06 -6.2521 0.55078E+00 -0.2590 122 MgOH+ 0.40835E-07 -7.3890 0.22491E-07 -7.6480 0.55078E+00 -0.2590 124 MnF+ 0.18933E-07 -7.7228 0.10428E-07 -7.9818 0.55078E+00 -0.2590 125 MnO,aq 0.20134E-10 -10.6961 0.20134E-10 -10.6961 0.10000E+01 0.0000 126 MnOH+ 0.15085E-07 -7.8215 0.83083E-08 -8.0805 0.55078E+00 -0.2590 131 MnCl+ 0.23464E-04 -4.6296 0.12923E-04 -4.8886 0.55078E+00 -0.2590 132 MnSO4,aq 0.32939E-08 -8.4823 0.32939E-08 -8.4823 0.10000E+01 0.0000 133 NaCl,aq 0.26943E+00 -0.5696 0.26943E+00 -0.5696 0.10000E+01 0.0000 134 NaF,aq 0.16571E-03 -3.7806 0.16571E-03 -3.7806 0.10000E+01 0.0000 135 NaOH,aq 0.93334E-06 -6.0300 0.93334E-06 -6.0300 0.10000E+01 0.0000 137 OH- 0.33032E-05 -5.4811 0.16382E-05 -5.7856 0.49594E+00 -0.3046 140 PbCl+ 0.64227E-07 -7.1923 0.35375E-07 -7.4513 0.55078E+00 -0.2590 141 PbCl2,aq 0.27847E-06 -6.5552 0.27847E-06 -6.5552 0.10000E+01 0.0000 142 PbCl3- 0.21508E-06 -6.6674 0.11290E-06 -6.9473 0.52493E+00 -0.2799 143 PbCl4-2 0.30363E-06 -6.5177 0.14378E-07 -7.8423 0.47353E-01 -1.3247 144 PbF+ 0.78305E-10 -10.1062 0.43128E-10 -10.3652 0.55078E+00 -0.2590 146 PbO,aq 0.37796E-10 -10.4226 0.37796E-10 -10.4226 0.10000E+01 0.0000 148 Pb(HS)2,aq 0.16907E-09 -9.7719 0.16907E-09 -9.7719 0.10000E+01 0.0000 150 H2S,aq 0.10242E-04 -4.9896 0.93535E-05 -5.0290 0.91321E+00 -0.0394 158 HSO3- 0.20442E-09 -9.6895 0.10731E-09 -9.9694 0.52493E+00 -0.2799 159 HSO4- 0.60497E-06 -6.2183 0.33876E-06 -6.4701 0.55996E+00 -0.2518 161 S2O3-2 0.21861E-10 -10.6603 0.10352E-11 -11.9850 0.47353E-01 -1.3247 173 ZnCl+ 0.46124E-05 -5.3361 0.25404E-05 -5.5951 0.55078E+00 -0.2590 174 ZnCl2,aq 0.11782E-05 -5.9288 0.11782E-05 -5.9288 0.10000E+01 0.0000 175 ZnCl3- 0.15944E-06 -6.7974 0.83697E-07 -7.0773 0.52493E+00 -0.2799 176 ZnF+ 0.10913E-09 -9.9621 0.60104E-10 -10.2211 0.55078E+00 -0.2590 177 ZnO,aq 0.29089E-09 -9.5363 0.29089E-09 -9.5363 0.10000E+01 0.0000 178 ZnOH+ 0.22192E-06 -6.6538 0.12223E-06 -6.9128 0.55078E+00 -0.2590 Charge balance for all species = -.1176E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7836534E-05 0.2930685E+00 0.2690618E+03 0.0000 2 H2O 0.1000000E+01 0.5521532E+02 0.9060439E+06 0.0000 3 Cl- 0.1130652E+01 0.1401867E+01 0.4526972E+05 5.1839 4 SO4-- 0.1539031E-03 0.1711188E-03 0.1497255E+02 5.7001 5 HCO3- 0.2435405E-01 0.3174274E+00 0.1764188E+05 3.5323 6 HS- 0.1268978E-05 0.1157104E-04 0.3485626E+00 -0.7643 7 H4SiO4 0.2663793E-02 0.2673939E-02 0.2340952E+03 -2.5745 8 Al+++ 0.7645864E-13 0.5201437E-06 0.1278314E-01 0.0716 9 Ca++ 0.1206321E-02 0.1909695E-02 0.6971370E+02 6.5408 10 Mg++ 0.1146892E-03 0.1558186E-03 0.3450547E+01 5.4777 11 Fe++ 0.1109995E-05 0.1454394E-05 0.7398265E-01 3.4738 12 K+ 0.4007593E-01 0.4123425E-01 0.1468605E+04 3.7524 13 Na+ 0.1112750E+01 0.1382354E+01 0.2894693E+05 5.1774 14 Mn++ 0.7773935E-05 0.3127496E-04 0.1565012E+01 4.3267 15 Zn++ 0.2681610E-07 0.6199219E-05 0.3691166E+00 1.8568 16 Cu+ 0.4523257E-11 0.1543533E-06 0.8933285E-02 -6.2141 17 Pb++ 0.5626434E-08 0.8673215E-06 0.1636805E+00 1.2341 18 Ag+ 0.2079869E-10 0.3304639E-06 0.3246929E-01 -5.5359 19 Au+ 0.5781950E-21 0.2822021E-11 0.5062929E-06 -16.0865 20 Ba++ 0.1511660E-05 0.3686907E-05 0.4612192E+00 3.6792 21 F- 0.9927610E-03 0.1228952E-02 0.2126624E+02 2.0981 22 H2AsO3- 0.1160667E-05 0.1175993E-03 0.1338257E+02 -0.6919 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3230751E+00 0.3601047E-03 0.0000000E+00 2 H2O 0.6086868E+02 0.6086868E+02 0.0000000E+00 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1275576E-04 0.1274546E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2947717E-02 -.1359757E-03 0.0000000E+00 8 Al+++ 0.2407279E-05 0.5733999E-06 0.1833879E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523890E+01 -.9126175E-04 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.6833941E-05 0.6342356E-06 0.0000000E+00 16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00 17 Pb++ 0.1565021E-05 0.9561244E-06 0.6088963E-06 0.0000000E+00 18 Ag+ 0.4271281E-06 0.3642992E-06 0.6282886E-07 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1354781E-02 0.2756191E-03 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.5421E-19 Mass of aqueous solution: 0.121028E+04 g Temperature = 184.87 C Pressure = 500.00 bar Mixer frac. = 0.1000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) paragonite -.9126E-04 1.000 -.3488E-01 1.000 375.0 -.1206E-01 argentite 0.3141E-07 -7.503 0.7784E-05 -5.109 -.8369E-01 0.1093E-05 galena 0.6089E-06 -6.215 0.1457E-03 -3.837 -1.566 0.1917E-04 sphalerite 0.6342E-06 -6.198 0.6179E-04 -4.209 -.6643 0.1511E-04 topaz 0.1378E-03 -3.861 0.2536E-01 -1.596 -272.7 0.7100E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 argentite 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 topaz 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.1000000 Solid products produced: Mass = -0.009302 g Volume = -0.004921 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.300 AFFINITY: 0.3862E+03 GOLD Q/K: 0.0251 SILVER Q/K: 0.2976 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 184.8730 deg.C Sat. pressure: 88.2711 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2169E+00 0.6611 0.1266E+02 0.1915E+02 CO2,gas 0.7831E+00 0.9037 0.6246E+02 0.6912E+02 CH4,gas 0.2030E-07 1.1161 0.1999E-05 0.1791E-05 H2,gas 0.2090E-05 1.0391 0.1917E-03 0.1845E-03 H2S,gas 0.7111E-05 0.8340 0.5235E-03 0.6277E-03 S2,gas 0.8954E-16 1.0000 0.7904E-14 0.7904E-14 CO,gas 0.3242E-07 1.0000 0.2861E-05 0.2861E-05 SO3,gas 0.3701E-26 1.0000 0.3267E-24 0.3267E-24 O2,gas 0.1890E-42 1.0000 0.1669E-40 0.1669E-40 SO2,gas 0.4080E-12 1.0000 0.3601E-10 0.3601E-10 HF,gas 0.3128E-07 1.0000 0.2761E-05 0.2761E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 196 argentite -22.66 -22.66 0.00 0.000 0.00000E+00 225 topaz -19.88 -19.88 0.00 0.000 -0.74459E-11 260 galena -10.35 -10.35 0.00 0.000 -0.74459E-11 272 sphalerite -9.73 -9.73 0.00 0.000 -0.74459E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.58 -0.02 -1.60 -1.597 0.33462E+04 1.102 2 CO2,gas -6.37 -7.27 -0.90 -0.301 0.18932E+04 1.796 3 CH4,gas 5.45 -2.95 -8.40 -2.100 0.17601E+05 -5.699 4 H2,gas 7.49 1.07 -6.42 -3.666 0.13448E+05 -3.717 5 H2S,gas -5.61 -11.59 -5.98 -2.990 0.12533E+05 -3.281 6 S2,gas -8.51 -25.31 -16.80 -2.585 0.35212E+05 -14.102 7 CO,gas 2.06 -6.18 -8.24 -2.536 0.17275E+05 -5.543 8 SO3,gas 11.26 -15.92 -27.18 -6.796 0.56975E+05 -24.486 9 O2,gas 41.30 -2.18 -43.48 -28.984 0.91120E+05 -40.778 10 SO2,gas -1.69 -14.83 -13.14 -3.505 0.27545E+05 -10.444 11 HF,gas -0.46 -8.72 -8.26 -4.129 0.17307E+05 -5.559 12 HCl,gas 1.07 -5.64 -6.71 -3.355 0.14064E+05 -6.710 13 acmite 6.21 3.01 -3.21 -0.333 0.67213E+04 17 albite-high -1.24 -2.39 -1.15 -0.089 0.24150E+04 18 albite -1.96 -2.39 -0.44 -0.034 0.91322E+03 22 analcite 1.14 0.12 -1.02 -0.114 0.21424E+04 23 andalusite -0.53 -2.45 -1.92 -0.192 0.40161E+04 26 anhydrite -6.54 -9.40 -2.87 -1.433 0.60057E+04 27 ankerite -3.79 -4.56 -0.77 -0.129 0.16226E+04 31 anorthite 5.40 1.54 -3.87 -0.298 0.81094E+04 34 aragonite 0.02 -0.75 -0.77 -0.257 0.16136E+04 35 brucite 9.88 5.44 -4.45 -0.889 0.93184E+04 36 calcite -0.12 -0.75 -0.63 -0.210 0.13217E+04 37 carnegieite-low 5.67 2.67 -3.00 -0.429 0.62882E+04 38 carnegieite-high 6.40 2.67 -3.72 -0.532 0.78036E+04 39 carpholite-Mg 2.57 0.43 -2.14 -0.143 0.44891E+04 40 carpholite-Fe 1.01 -1.57 -2.58 -0.172 0.54039E+04 41 celadonite 2.81 -0.92 -3.73 -0.219 0.78108E+04 42 celadonite-Fe 1.48 -2.92 -4.40 -0.259 0.92294E+04 49 chloritoid-Mg 5.89 2.99 -2.90 -0.194 0.60863E+04 50 chloritoid-Fe 2.67 0.98 -1.69 -0.112 0.35358E+04 51 chloritoid-Mn 4.86 1.84 -3.03 -0.202 0.63429E+04 53 coesite -1.89 -2.53 -0.65 -0.215 0.13545E+04 58 corundum 2.16 0.08 -2.08 -0.189 0.43577E+04 60 cristobalite -2.08 -2.53 -0.45 -0.152 0.95320E+03 63 cymrite-K 0.00 -3.84 -3.84 -0.320 0.80478E+04 65 diaspore 0.31 0.03 -0.27 -0.046 0.57449E+03 66 diamond -2.23 -5.09 -2.86 -0.817 0.59950E+04 69 dolomite,ordered -1.55 -2.56 -1.01 -0.168 0.21188E+04 83 gibbsite 1.55 0.01 -1.53 -0.219 0.32170E+04 86 goethite 4.65 2.90 -1.75 -0.379 0.36747E+04 87 graphite -2.62 -5.09 -2.47 -0.705 0.51748E+04 90 halite 1.41 -0.46 -1.87 -0.935 0.39201E+04 91 hematite 8.70 5.82 -2.88 -0.350 0.60454E+04 92 heulandite -8.60 -11.26 -2.66 -0.121 0.55738E+04 96 jadeite 1.96 0.14 -1.82 -0.182 0.38199E+04 98 kalsilite 4.61 1.25 -3.36 -0.480 0.70469E+04 99 kaolinite -4.76 -5.03 -0.27 -0.024 0.56035E+03 100 kyanite -0.58 -2.45 -1.87 -0.187 0.39114E+04 102 laumontite -1.31 -3.61 -2.30 -0.153 0.48222E+04 103 lawsonite 4.00 1.50 -2.51 -0.167 0.52570E+04 104 leucite 1.67 -1.29 -2.96 -0.296 0.61945E+04 107 magnesite -0.67 -1.81 -1.14 -0.381 0.23932E+04 108 magnetite 14.03 9.27 -4.76 -0.389 0.99775E+04 114 margarite 5.08 1.60 -3.48 -0.139 0.73037E+04 117 microcline -3.44 -3.82 -0.38 -0.029 0.79356E+03 120 mullite-Si 1.21 -2.45 -3.67 -0.367 0.76821E+04 121 muscovite -3.53 -3.76 -0.23 -0.013 0.47415E+03 122 paragonite -2.33 -2.33 0.00 0.000 -0.93074E-11 123 nepheline 5.08 2.67 -2.41 -0.344 0.50467E+04 143 pyrite -19.37 -20.77 -1.40 -0.329 0.29303E+04 144 pyrrhotite -4.86 -8.11 -3.25 -1.082 0.68050E+04 145 pyrrhotiteFe0.875 -6.24 -8.68 -2.44 -0.899 0.51203E+04 146 pyroxmangite 5.66 1.77 -3.88 -0.777 0.81382E+04 147 pyrophyllite -9.00 -10.07 -1.07 -0.067 0.22510E+04 148 quartz -2.39 -2.53 -0.14 -0.047 0.29733E+03 153 rhodochrosite -1.69 -2.96 -1.27 -0.423 0.26586E+04 154 rhodonite 5.68 1.77 -3.91 -0.782 0.81964E+04 155 sanidine -2.45 -3.82 -1.37 -0.105 0.28623E+04 157 siderite -3.37 -3.81 -0.44 -0.148 0.93183E+03 158 sillimanite -0.36 -2.45 -2.09 -0.209 0.43871E+04 165 stilbite -8.55 -11.28 -2.73 -0.130 0.57204E+04 168 stishovite 2.38 -2.53 -4.91 -1.638 0.10299E+05 170 sudoite 8.13 3.40 -4.73 -0.152 0.99070E+04 171 sulfur -8.52 -12.65 -4.14 -1.273 0.86738E+04 172 sylvite 1.42 -1.88 -3.30 -1.652 0.69253E+04 180 topaz-H -0.23 -2.47 -2.25 -0.204 0.47068E+04 181 tridymite -2.11 -2.53 -0.42 -0.141 0.88658E+03 184 troilite-low -4.93 -8.11 -3.18 -1.059 0.66601E+04 190 wairakite -1.02 -3.57 -2.56 -0.150 0.53583E+04 192 wollastonite 8.38 3.99 -4.40 -0.880 0.92170E+04 193 pseudo-wollastonite 8.78 3.99 -4.79 -0.958 0.10041E+05 197 arsenic -5.63 -9.85 -4.21 -1.088 0.88335E+04 199 arsenopyrite -13.50 -17.96 -4.46 -0.793 0.93471E+04 200 beidellite-Ca -6.16 -8.15 -1.99 -0.123 0.41648E+04 201 beidellite-H -6.63 -9.23 -2.59 -0.165 0.54352E+04 202 beidellite-K -5.74 -7.99 -2.25 -0.138 0.47177E+04 203 beidellite-Mg -6.40 -8.32 -1.93 -0.119 0.40376E+04 204 beidellite-Na -5.65 -7.52 -1.87 -0.114 0.39177E+04 205 bornite -73.81 -74.47 -0.66 -0.050 0.13935E+04 207 chalcedony -2.24 -2.53 -0.29 -0.098 0.61683E+03 208 chalcocite -22.58 -24.01 -1.43 -0.358 0.30014E+04 210 covellite -16.57 -18.33 -1.77 -0.674 0.37072E+04 211 dawsonite 0.04 -2.08 -2.12 -0.265 0.44381E+04 213 montmorillonite-Ca -5.38 -7.21 -1.83 -0.113 0.38334E+04 214 montmorillonite-K -5.06 -7.05 -1.99 -0.122 0.41794E+04 215 montmorillonite-Mg -5.62 -7.39 -1.77 -0.110 0.37123E+04 216 montmorillonite-Na -4.90 -6.58 -1.69 -0.103 0.35334E+04 217 nontronite-Ca 0.93 -2.41 -3.35 -0.217 0.70109E+04 218 nontronite-H 0.45 -3.49 -3.95 -0.265 0.82726E+04 219 nontronite-K 1.35 -2.25 -3.61 -0.232 0.75634E+04 220 nontronite-Mg 0.72 -2.59 -3.31 -0.215 0.69457E+04 221 nontronite-Na 1.44 -1.78 -3.23 -0.207 0.67658E+04 229 gypsum -5.62 -9.44 -3.82 -0.956 0.80155E+04 245 acanthite -22.48 -22.66 -0.17 -0.044 0.36523E+03 251 barite -9.60 -12.26 -2.66 -1.329 0.55725E+04 252 boehmite 1.41 0.03 -1.38 -0.229 0.28825E+04 253 cerussite -2.80 -6.05 -3.25 -1.083 0.68117E+04 254 chalcopyrite -25.01 -26.45 -1.44 -0.267 0.30082E+04 255 chlorargyrite -6.18 -11.17 -4.99 -2.495 0.10458E+05 256 copper,native -1.71 -5.68 -3.97 -1.381 0.83228E+04 257 dolomite,disordered -1.09 -2.56 -1.47 -0.245 0.30828E+04 258 ferrous-oxide 7.15 3.45 -3.70 -0.925 0.77562E+04 259 fluorite -10.18 -10.90 -0.72 -0.241 0.15176E+04 261 gold,native -13.95 -15.55 -1.60 -0.556 0.33531E+04 262 silver,native -4.47 -5.00 -0.53 -0.183 0.11033E+04 263 huntite -1.50 -6.18 -4.68 -0.390 0.98004E+04 269 silica-amorphous -1.71 -2.53 -0.83 -0.276 0.17331E+04 270 smithsonite -1.73 -5.43 -3.70 -1.233 0.77511E+04 273 wurtzite -8.24 -9.73 -1.49 -0.497 0.31243E+04 274 zincite 5.99 1.84 -4.15 -1.039 0.87077E+04 275 an20ab80 -0.70 -1.61 -0.91 -0.070 0.18973E+04 276 an25ab75 -0.36 -1.41 -1.05 -0.081 0.22006E+04 277 an30ab70 -0.02 -1.22 -1.20 -0.092 0.25160E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 70 Temperature = 184.87 C Pressure = 500.00 bar Mixer fraction = 0.1000000 Water: Moles liquid = 0.6119E+02 kg liquid = 0.1102E+01 Moles total = 0.6087E+02 kg total = 0.1097E+01 Activity = 0.9551 Stoichiometric ionic strength = .1585131E+01 Osmotic coef. = 0.9098 True ionic strength = .1157678E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.79471E-05 -5.0998 0.39413E-05 -5.4044 0.49594E+00 -0.3046 2 H2O 0.95508E+00 -0.0200 0.95508E+00 -0.0200 3 Cl- 0.11307E+01 0.0533 0.59352E+00 -0.2266 0.52493E+00 -0.2799 4 SO4-- 0.15389E-03 -3.8128 0.75718E-05 -5.1208 0.49202E-01 -1.3080 5 HCO3- 0.24041E-01 -1.6191 0.13069E-01 -1.8837 0.54364E+00 -0.2647 6 HS- 0.12659E-05 -5.8976 0.66701E-06 -6.1759 0.52692E+00 -0.2783 7 H4SiO4 0.25402E-02 -2.5951 0.25402E-02 -2.5951 0.10000E+01 0.0000 8 Al+++ 0.67029E-13 -13.1737 0.60705E-16 -16.2168 0.90564E-03 -3.0430 9 Ca++ 0.12071E-02 -2.9183 0.52502E-04 -4.2798 0.43494E-01 -1.3616 10 Mg++ 0.11466E-03 -3.9406 0.45369E-05 -5.3432 0.39567E-01 -1.4027 11 Fe++ 0.11091E-05 -5.9550 0.44932E-07 -7.3474 0.40512E-01 -1.3924 12 K+ 0.40076E-01 -1.3971 0.21975E-01 -1.6581 0.54834E+00 -0.2609 13 Na+ 0.11126E+01 0.0464 0.58463E+00 -0.2331 0.52544E+00 -0.2795 14 Mn++ 0.77725E-05 -5.1094 0.32041E-06 -6.4943 0.41224E-01 -1.3848 15 Zn++ 0.27260E-07 -7.5645 0.11043E-08 -8.9569 0.40512E-01 -1.3924 16 Cu+ 0.45232E-11 -11.3446 0.23737E-11 -11.6246 0.52478E+00 -0.2800 17 Pb++ 0.57195E-08 -8.2426 0.26327E-09 -9.5796 0.46030E-01 -1.3370 18 Ag+ 0.20971E-10 -10.6784 0.11409E-10 -10.9428 0.54404E+00 -0.2644 19 Au+ 0.57979E-21 -21.2367 0.31934E-21 -21.4958 0.55077E+00 -0.2590 20 Ba++ 0.15187E-05 -5.8185 0.72497E-07 -7.1397 0.47735E-01 -1.3212 21 F- 0.11924E-02 -2.9236 0.58504E-03 -3.2328 0.49064E+00 -0.3092 22 H2AsO3- 0.11447E-05 -5.9413 0.77917E-06 -6.1084 0.68068E+00 -0.1671 24 HSiO3- 0.27584E-05 -5.5593 0.14480E-05 -5.8392 0.52493E+00 -0.2799 25 Ca(HSiO3)+ 0.13121E-07 -7.8820 0.72268E-08 -8.1411 0.55077E+00 -0.2590 26 Mg(HSiO3)+ 0.99992E-09 -9.0000 0.55073E-09 -9.2591 0.55077E+00 -0.2590 27 NaHSiO3,aq 0.67670E-05 -5.1696 0.67670E-05 -5.1696 0.10000E+01 0.0000 31 AgCl,aq 0.37651E-08 -8.4242 0.37651E-08 -8.4242 0.10000E+01 0.0000 32 AgCl2- 0.17640E-06 -6.7535 0.92596E-07 -7.0334 0.52493E+00 -0.2799 33 AgCl3-2 0.12281E-06 -6.9108 0.58158E-08 -8.2354 0.47356E-01 -1.3246 34 AgCl4-3 0.21808E-07 -7.6614 0.19299E-10 -10.7145 0.88495E-03 -3.0531 38 Ag(HS),aq 0.83666E-08 -8.0775 0.83666E-08 -8.0775 0.10000E+01 0.0000 40 AlO+ 0.19303E-09 -9.7144 0.10631E-09 -9.9734 0.55077E+00 -0.2590 42 HAlO2,aq 0.41837E-07 -7.3784 0.41837E-07 -7.3784 0.10000E+01 0.0000 43 AlO2- 0.38975E-06 -6.4092 0.19330E-06 -6.7138 0.49594E+00 -0.3046 44 AsO2- 0.19974E-06 -6.6995 0.10485E-06 -6.9794 0.52493E+00 -0.2799 45 HAsO2,aq 0.31281E-04 -4.5047 0.31281E-04 -4.5047 0.10000E+01 0.0000 46 H3AsO3,aq 0.84973E-04 -4.0707 0.84973E-04 -4.0707 0.10000E+01 0.0000 48 H2AsO4- 0.10582E-09 -9.9754 0.55545E-10 -10.2554 0.52493E+00 -0.2799 49 HAsO4-2 0.23665E-10 -10.6259 0.11207E-11 -11.9505 0.47356E-01 -1.3246 62 BaCO3,aq 0.43667E-09 -9.3598 0.43667E-09 -9.3598 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.13497E-05 -5.8698 0.75855E-06 -6.1200 0.56203E+00 -0.2502 64 BaCl+ 0.81716E-06 -6.0877 0.45007E-06 -6.3467 0.55077E+00 -0.2590 65 BaF+ 0.90196E-09 -9.0448 0.49678E-09 -9.3038 0.55077E+00 -0.2590 66 CH4,aq 0.12704E-08 -8.8961 0.11602E-08 -8.9355 0.91321E+00 -0.0394 71 CO,aq 0.23194E-08 -8.6346 0.23194E-08 -8.6346 0.10000E+01 0.0000 72 CO2,aq 0.29320E+00 -0.5328 0.26776E+00 -0.5723 0.91321E+00 -0.0394 73 CO3-2 0.54800E-05 -5.2612 0.25951E-06 -6.5858 0.47356E-01 -1.3246 74 CaCO3,aq 0.12589E-05 -5.9000 0.12589E-05 -5.9000 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.15894E-03 -3.7988 0.87539E-04 -4.0578 0.55077E+00 -0.2590 76 CaCl+ 0.49470E-03 -3.3057 0.27247E-03 -3.5647 0.55077E+00 -0.2590 77 CaCl2,aq 0.42417E-04 -4.3725 0.42417E-04 -4.3725 0.10000E+01 0.0000 78 CaF+ 0.46444E-05 -5.3331 0.25580E-05 -5.5921 0.55077E+00 -0.2590 79 CaOH+ 0.12980E-06 -6.8867 0.71488E-07 -7.1458 0.55077E+00 -0.2590 80 CaSO4,aq 0.46856E-06 -6.3292 0.46856E-06 -6.3292 0.10000E+01 0.0000 81 HCl,aq 0.13042E-05 -5.8846 0.13042E-05 -5.8846 0.10000E+01 0.0000 90 CuCl,aq 0.65807E-08 -8.1817 0.65807E-08 -8.1817 0.10000E+01 0.0000 91 CuCl2- 0.12092E-06 -6.9175 0.63474E-07 -7.1974 0.52493E+00 -0.2799 92 CuCl3-2 0.26848E-07 -7.5711 0.12714E-08 -8.8957 0.47356E-01 -1.3246 98 HF,aq 0.79831E-04 -4.0978 0.79831E-04 -4.0978 0.10000E+01 0.0000 99 HF2- 0.25070E-07 -7.6009 0.13160E-07 -7.8808 0.52493E+00 -0.2799 101 FeCl+ 0.31873E-06 -6.4966 0.17555E-06 -6.7556 0.55077E+00 -0.2590 102 FeCl2,aq 0.21097E-08 -8.6758 0.21097E-08 -8.6758 0.10000E+01 0.0000 104 FeF+ 0.81305E-08 -8.0899 0.44781E-08 -8.3489 0.55077E+00 -0.2590 106 FeO,aq 0.87765E-10 -10.0567 0.87765E-10 -10.0567 0.10000E+01 0.0000 107 FeOH+ 0.16144E-07 -7.7920 0.88919E-08 -8.0510 0.55077E+00 -0.2590 112 HFeO2,aq 0.72063E-10 -10.1423 0.72063E-10 -10.1423 0.10000E+01 0.0000 113 H2,aq 0.19524E-06 -6.7094 0.17829E-06 -6.7489 0.91321E+00 -0.0394 114 KCl,aq 0.11421E-02 -2.9423 0.11421E-02 -2.9423 0.10000E+01 0.0000 115 KHSO4,aq 0.19779E-09 -9.7038 0.19779E-09 -9.7038 0.10000E+01 0.0000 116 KOH,aq 0.46430E-07 -7.3332 0.46430E-07 -7.3332 0.10000E+01 0.0000 117 KSO4- 0.16190E-04 -4.7908 0.84984E-05 -5.0707 0.52493E+00 -0.2799 118 MgCO3,aq 0.15588E-07 -7.8072 0.15588E-07 -7.8072 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.13373E-04 -4.8738 0.73653E-05 -5.1328 0.55077E+00 -0.2590 120 MgCl+ 0.26503E-04 -4.5767 0.14597E-04 -4.8357 0.55077E+00 -0.2590 121 MgF+ 0.12202E-05 -5.9136 0.67204E-06 -6.1726 0.55077E+00 -0.2590 122 MgOH+ 0.40261E-07 -7.3951 0.22175E-07 -7.6541 0.55077E+00 -0.2590 124 MnF+ 0.22738E-07 -7.6433 0.12523E-07 -7.9023 0.55077E+00 -0.2590 125 MnO,aq 0.19575E-10 -10.7083 0.19575E-10 -10.7083 0.10000E+01 0.0000 126 MnOH+ 0.14873E-07 -7.8276 0.81917E-08 -8.0866 0.55077E+00 -0.2590 131 MnCl+ 0.23461E-04 -4.6296 0.12922E-04 -4.8887 0.55077E+00 -0.2590 132 MnSO4,aq 0.32936E-08 -8.4823 0.32936E-08 -8.4823 0.10000E+01 0.0000 133 NaCl,aq 0.26941E+00 -0.5696 0.26941E+00 -0.5696 0.10000E+01 0.0000 134 NaF,aq 0.19902E-03 -3.7011 0.19902E-03 -3.7011 0.10000E+01 0.0000 135 NaOH,aq 0.92026E-06 -6.0361 0.92026E-06 -6.0361 0.10000E+01 0.0000 137 OH- 0.32572E-05 -5.4872 0.16154E-05 -5.7917 0.49594E+00 -0.3046 140 PbCl+ 0.65295E-07 -7.1851 0.35963E-07 -7.4441 0.55077E+00 -0.2590 141 PbCl2,aq 0.28310E-06 -6.5481 0.28310E-06 -6.5481 0.10000E+01 0.0000 142 PbCl3- 0.21866E-06 -6.6602 0.11478E-06 -6.9401 0.52493E+00 -0.2799 143 PbCl4-2 0.30867E-06 -6.5105 0.14618E-07 -7.8351 0.47356E-01 -1.3246 144 PbF+ 0.95616E-10 -10.0195 0.52663E-10 -10.2785 0.55077E+00 -0.2590 146 PbO,aq 0.37361E-10 -10.4276 0.37361E-10 -10.4276 0.10000E+01 0.0000 148 Pb(HS)2,aq 0.17103E-09 -9.7669 0.17103E-09 -9.7669 0.10000E+01 0.0000 150 H2S,aq 0.10362E-04 -4.9846 0.94623E-05 -5.0240 0.91321E+00 -0.0394 158 HSO3- 0.20646E-09 -9.6852 0.10838E-09 -9.9651 0.52493E+00 -0.2799 159 HSO4- 0.61352E-06 -6.2122 0.34355E-06 -6.4640 0.55996E+00 -0.2518 161 S2O3-2 0.22114E-10 -10.6553 0.10472E-11 -11.9800 0.47356E-01 -1.3246 173 ZnCl+ 0.46892E-05 -5.3289 0.25827E-05 -5.5879 0.55077E+00 -0.2590 174 ZnCl2,aq 0.11978E-05 -5.9216 0.11978E-05 -5.9216 0.10000E+01 0.0000 175 ZnCl3- 0.16210E-06 -6.7902 0.85091E-07 -7.0701 0.52493E+00 -0.2799 176 ZnF+ 0.13325E-09 -9.8753 0.73391E-10 -10.1344 0.55077E+00 -0.2590 177 ZnO,aq 0.28755E-09 -9.5413 0.28755E-09 -9.5413 0.10000E+01 0.0000 178 ZnOH+ 0.22247E-06 -6.6527 0.12253E-06 -6.9118 0.55077E+00 -0.2590 Charge balance for all species = -.1176E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7947117E-05 0.2933981E+00 0.2693680E+03 0.0000 2 H2O 0.1000000E+01 0.5521501E+02 0.9060511E+06 0.0000 3 Cl- 0.1130665E+01 0.1401859E+01 0.4527008E+05 5.1778 4 SO4-- 0.1538930E-03 0.1711179E-03 0.1497267E+02 5.6879 5 HCO3- 0.2404080E-01 0.3174256E+00 0.1764202E+05 3.5206 6 HS- 0.1265860E-05 0.1168681E-04 0.3520548E+00 -0.7715 7 H4SiO4 0.2540162E-02 0.2549702E-02 0.2232217E+03 -2.5951 8 Al+++ 0.6702950E-13 0.4317885E-06 0.1061185E-01 -0.0037 9 Ca++ 0.1207116E-02 0.1909684E-02 0.6971425E+02 6.5289 10 Mg++ 0.1146646E-03 0.1558177E-03 0.3450575E+01 5.4655 11 Fe++ 0.1109103E-05 0.1454385E-05 0.7398324E-01 3.4613 12 K+ 0.4007569E-01 0.4123401E-01 0.1468617E+04 3.7463 13 Na+ 0.1112648E+01 0.1382263E+01 0.2894543E+05 5.1712 14 Mn++ 0.7772462E-05 0.3127478E-04 0.1565025E+01 4.3144 15 Zn++ 0.2725968E-07 0.6299223E-05 0.3750762E+00 1.8518 16 Cu+ 0.4523186E-11 0.1543524E-06 0.8933357E-02 -6.2202 17 Pb++ 0.5719529E-08 0.8817564E-06 0.1664069E+00 1.2291 18 Ag+ 0.2097088E-10 0.3331744E-06 0.3273605E-01 -5.5384 19 Au+ 0.5797946E-21 0.2822005E-11 0.5062970E-06 -16.0914 20 Ba++ 0.1518734E-05 0.3686886E-05 0.4612229E+00 3.6690 21 F- 0.1192415E-02 0.1477212E-02 0.2556258E+02 2.1715 22 H2AsO3- 0.1144694E-05 0.1175986E-03 0.1338267E+02 -0.7040 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234402E+00 -.5009406E-05 0.0000000E+00 2 H2O 0.6086868E+02 0.6086868E+02 0.0000000E+00 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1288346E-04 0.1146850E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810775E-02 0.9656390E-06 0.0000000E+00 8 Al+++ 0.2407279E-05 0.4760010E-06 0.1931278E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.6944224E-05 0.5239526E-06 0.0000000E+00 16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00 17 Pb++ 0.1565021E-05 0.9720426E-06 0.5929780E-06 0.0000000E+00 18 Ag+ 0.4271281E-06 0.3672893E-06 0.5983877E-07 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1628469E-02 0.1931278E-05 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.121027E+04 g Temperature = 184.87 C Pressure = 500.00 bar Mixer frac. = 0.1000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) argentite 0.2992E-07 -7.524 0.7414E-05 -5.130 1.961 0.1041E-05 topaz 0.9656E-06 -6.015 0.1777E-03 -3.750 47.01 0.4975E-04 galena 0.5930E-06 -6.227 0.1419E-03 -3.848 37.53 0.1867E-04 sphalerite 0.5240E-06 -6.281 0.5105E-04 -4.292 13.50 0.1248E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity argentite 0.1000E+01 0.1000E+01 1.0000 0.000 topaz 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.1000000 Solid products produced: Mass = 0.000378 g Volume = 0.000082 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.300 AFFINITY: 0.3949E+03 GOLD Q/K: 0.0248 SILVER Q/K: 0.2952 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 184.8730 deg.C Sat. pressure: 88.3601 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2168E+00 0.6609 0.1266E+02 0.1915E+02 CO2,gas 0.7832E+00 0.9036 0.6253E+02 0.6921E+02 CH4,gas 0.1996E-07 1.1161 0.1969E-05 0.1764E-05 H2,gas 0.2079E-05 1.0391 0.1909E-03 0.1837E-03 H2S,gas 0.7188E-05 0.8338 0.5296E-03 0.6351E-03 S2,gas 0.9230E-16 1.0000 0.8155E-14 0.8155E-14 CO,gas 0.3228E-07 1.0000 0.2853E-05 0.2853E-05 SO3,gas 0.3803E-26 1.0000 0.3360E-24 0.3360E-24 O2,gas 0.1904E-42 1.0000 0.1682E-40 0.1682E-40 SO2,gas 0.4174E-12 1.0000 0.3688E-10 0.3688E-10 HF,gas 0.3807E-07 1.0000 0.3363E-05 0.3363E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 196 argentite -22.66 -22.66 0.00 0.000 0.74459E-11 225 topaz -19.88 -19.88 0.00 0.000 0.14892E-10 260 galena -10.35 -10.35 0.00 0.000 0.37230E-11 272 sphalerite -9.73 -9.73 0.00 0.000 0.37230E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.58 -0.02 -1.60 -1.597 0.33462E+04 1.102 2 CO2,gas -6.37 -7.27 -0.90 -0.301 0.18923E+04 1.796 3 CH4,gas 5.45 -2.96 -8.40 -2.101 0.17615E+05 -5.706 4 H2,gas 7.49 1.07 -6.42 -3.667 0.13451E+05 -3.719 5 H2S,gas -5.61 -11.58 -5.98 -2.988 0.12523E+05 -3.276 6 S2,gas -8.51 -25.30 -16.79 -2.583 0.35184E+05 -14.089 7 CO,gas 2.06 -6.18 -8.24 -2.537 0.17278E+05 -5.545 8 SO3,gas 11.26 -15.91 -27.17 -6.793 0.56949E+05 -24.474 9 O2,gas 41.30 -2.17 -43.47 -28.982 0.91112E+05 -40.774 10 SO2,gas -1.69 -14.82 -13.13 -3.502 0.27523E+05 -10.433 11 HF,gas -0.46 -8.64 -8.17 -4.086 0.17128E+05 -5.473 12 HCl,gas 1.07 -5.63 -6.70 -3.352 0.14051E+05 -6.704 13 acmite 6.21 2.95 -3.27 -0.339 0.68450E+04 17 albite-high -1.24 -2.54 -1.30 -0.100 0.27156E+04 18 albite -1.96 -2.54 -0.58 -0.045 0.12138E+04 22 analcite 1.14 0.00 -1.14 -0.127 0.23997E+04 23 andalusite -0.53 -2.62 -2.09 -0.209 0.43752E+04 26 anhydrite -6.54 -9.40 -2.87 -1.433 0.60050E+04 27 ankerite -3.79 -4.59 -0.80 -0.133 0.16717E+04 31 anorthite 5.40 1.33 -4.07 -0.313 0.85366E+04 34 aragonite 0.02 -0.76 -0.78 -0.260 0.16375E+04 35 brucite 9.88 5.43 -4.46 -0.892 0.93441E+04 36 calcite -0.12 -0.76 -0.64 -0.214 0.13456E+04 37 carnegieite-low 5.67 2.57 -3.10 -0.443 0.65023E+04 38 carnegieite-high 6.40 2.57 -3.83 -0.546 0.80176E+04 39 carpholite-Mg 2.57 0.23 -2.35 -0.156 0.49171E+04 40 carpholite-Fe 1.01 -1.78 -2.78 -0.186 0.58325E+04 41 celadonite 2.81 -1.09 -3.90 -0.230 0.81802E+04 42 celadonite-Fe 1.48 -3.10 -4.58 -0.269 0.95993E+04 49 chloritoid-Mg 5.89 2.80 -3.09 -0.206 0.64710E+04 50 chloritoid-Fe 2.67 0.80 -1.87 -0.125 0.39211E+04 51 chloritoid-Mn 4.86 1.65 -3.21 -0.214 0.67276E+04 53 coesite -1.89 -2.56 -0.67 -0.222 0.13977E+04 58 corundum 2.16 -0.07 -2.23 -0.203 0.46736E+04 60 cristobalite -2.08 -2.56 -0.48 -0.158 0.99645E+03 63 cymrite-K 0.00 -3.98 -3.98 -0.332 0.83483E+04 65 diaspore 0.31 -0.04 -0.35 -0.058 0.73242E+03 66 diamond -2.23 -5.09 -2.86 -0.818 0.60015E+04 69 dolomite,ordered -1.55 -2.58 -1.03 -0.172 0.21673E+04 83 gibbsite 1.55 -0.06 -1.61 -0.230 0.33749E+04 86 goethite 4.65 2.89 -1.76 -0.382 0.36990E+04 87 graphite -2.62 -5.09 -2.47 -0.706 0.51813E+04 90 halite 1.41 -0.46 -1.87 -0.935 0.39202E+04 91 hematite 8.70 5.80 -2.91 -0.352 0.60941E+04 92 heulandite -8.60 -11.56 -2.97 -0.135 0.62173E+04 96 jadeite 1.96 0.02 -1.95 -0.195 0.40772E+04 98 kalsilite 4.61 1.15 -3.46 -0.495 0.72609E+04 99 kaolinite -4.76 -5.22 -0.46 -0.042 0.96272E+03 100 kyanite -0.58 -2.62 -2.04 -0.204 0.42706E+04 102 laumontite -1.31 -3.86 -2.55 -0.170 0.53360E+04 103 lawsonite 4.00 1.29 -2.71 -0.181 0.56842E+04 104 leucite 1.67 -1.41 -3.08 -0.308 0.64517E+04 107 magnesite -0.67 -1.82 -1.15 -0.385 0.24178E+04 108 magnetite 14.03 9.24 -4.80 -0.392 0.10052E+05 114 margarite 5.08 1.24 -3.84 -0.154 0.80468E+04 117 microcline -3.44 -3.96 -0.52 -0.040 0.10940E+04 120 mullite-Si 1.21 -2.62 -3.84 -0.384 0.80412E+04 121 muscovite -3.53 -4.05 -0.52 -0.031 0.10905E+04 122 paragonite -2.33 -2.63 -0.29 -0.017 0.61640E+03 123 nepheline 5.08 2.57 -2.51 -0.359 0.52608E+04 143 pyrite -19.37 -20.77 -1.40 -0.329 0.29316E+04 144 pyrrhotite -4.86 -8.12 -3.25 -1.085 0.68207E+04 145 pyrrhotiteFe0.875 -6.24 -8.68 -2.45 -0.901 0.51322E+04 146 pyroxmangite 5.66 1.74 -3.92 -0.783 0.82071E+04 147 pyrophyllite -9.00 -10.31 -1.31 -0.082 0.27399E+04 148 quartz -2.39 -2.56 -0.16 -0.054 0.34059E+03 153 rhodochrosite -1.69 -2.97 -1.28 -0.427 0.26832E+04 154 rhodonite 5.68 1.74 -3.94 -0.789 0.82653E+04 155 sanidine -2.45 -3.96 -1.51 -0.116 0.31628E+04 157 siderite -3.37 -3.83 -0.46 -0.152 0.95704E+03 158 sillimanite -0.36 -2.62 -2.26 -0.226 0.47462E+04 165 stilbite -8.55 -11.58 -3.04 -0.145 0.63639E+04 168 stishovite 2.38 -2.56 -4.93 -1.645 0.10342E+05 171 sulfur -8.52 -12.65 -4.13 -1.271 0.86595E+04 172 sylvite 1.42 -1.88 -3.30 -1.652 0.69253E+04 180 topaz-H -0.23 -2.64 -2.42 -0.220 0.50659E+04 181 tridymite -2.11 -2.56 -0.44 -0.148 0.92984E+03 184 troilite-low -4.93 -8.12 -3.19 -1.062 0.66758E+04 190 wairakite -1.02 -3.82 -2.80 -0.165 0.58721E+04 192 wollastonite 8.38 3.95 -4.43 -0.886 0.92852E+04 193 pseudo-wollastonite 8.78 3.95 -4.82 -0.965 0.10109E+05 197 arsenic -5.63 -9.85 -4.22 -1.088 0.88389E+04 199 arsenopyrite -13.50 -17.97 -4.47 -0.795 0.93682E+04 200 beidellite-Ca -6.16 -8.40 -2.24 -0.139 0.46957E+04 201 beidellite-H -6.63 -9.48 -2.84 -0.182 0.59620E+04 202 beidellite-K -5.74 -8.24 -2.50 -0.153 0.52486E+04 203 beidellite-Mg -6.40 -8.58 -2.18 -0.135 0.45686E+04 204 beidellite-Na -5.65 -7.77 -2.12 -0.130 0.44487E+04 205 bornite -73.81 -74.49 -0.69 -0.051 0.14396E+04 207 chalcedony -2.24 -2.56 -0.31 -0.105 0.66009E+03 208 chalcocite -22.58 -24.02 -1.44 -0.360 0.30164E+04 210 covellite -16.57 -18.33 -1.77 -0.674 0.37076E+04 211 dawsonite 0.04 -2.16 -2.20 -0.275 0.46079E+04 213 montmorillonite-Ca -5.38 -7.43 -2.04 -0.126 0.42828E+04 214 montmorillonite-K -5.06 -7.27 -2.21 -0.135 0.46288E+04 215 montmorillonite-Mg -5.62 -7.60 -1.99 -0.123 0.41618E+04 216 montmorillonite-Na -4.90 -6.80 -1.90 -0.116 0.39829E+04 217 nontronite-Ca 0.93 -2.54 -3.47 -0.225 0.72745E+04 218 nontronite-H 0.45 -3.62 -4.07 -0.273 0.85321E+04 219 nontronite-K 1.35 -2.38 -3.73 -0.240 0.78271E+04 220 nontronite-Mg 0.72 -2.71 -3.44 -0.223 0.72094E+04 221 nontronite-Na 1.44 -1.91 -3.35 -0.215 0.70295E+04 229 gypsum -5.62 -9.44 -3.82 -0.956 0.80148E+04 245 acanthite -22.48 -22.66 -0.17 -0.044 0.36523E+03 251 barite -9.60 -12.26 -2.66 -1.328 0.55682E+04 252 boehmite 1.41 -0.04 -1.45 -0.242 0.30405E+04 253 cerussite -2.80 -6.06 -3.25 -1.085 0.68212E+04 254 chalcopyrite -25.01 -26.45 -1.44 -0.268 0.30243E+04 255 chlorargyrite -6.18 -11.17 -4.99 -2.493 0.10450E+05 256 copper,native -1.71 -5.69 -3.98 -1.384 0.83375E+04 257 dolomite,disordered -1.09 -2.58 -1.49 -0.249 0.31314E+04 258 ferrous-oxide 7.15 3.44 -3.71 -0.928 0.77824E+04 259 fluorite -10.18 -10.75 -0.56 -0.188 0.11833E+04 261 gold,native -13.95 -15.56 -1.61 -0.558 0.33652E+04 262 silver,native -4.47 -5.00 -0.53 -0.184 0.11105E+04 263 huntite -1.50 -6.23 -4.72 -0.394 0.98983E+04 269 silica-amorphous -1.71 -2.56 -0.85 -0.283 0.17763E+04 270 smithsonite -1.73 -5.44 -3.70 -1.234 0.77606E+04 273 wurtzite -8.24 -9.73 -1.49 -0.497 0.31243E+04 274 zincite 5.99 1.83 -4.16 -1.040 0.87182E+04 275 an20ab80 -0.70 -1.76 -1.06 -0.082 0.22232E+04 276 an25ab75 -0.36 -1.57 -1.21 -0.093 0.25329E+04 277 an30ab70 -0.02 -1.38 -1.36 -0.105 0.28545E+04 Calculations done for 184.8730 Deg. C; 500.0000 bar Mixer fraction: 0.1000000 Temperature Stoc.ionic strength Heat per mole Actual solution: 184.873 .15851E+01 3.491 Mixing solution: 25.000 .50000E-10 0.646 Fract. of mixing solution added: 0.050000 BITMOL = 0.2775E+01 OLDMOL = 0.6261E+02 New heat: 3.370 New temperature: 178.252 New mixer fraction: 0.1500000 Resulting temperature: 178.252Deg. C Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1296E-03 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 70 Temperature = 178.25 C Pressure = 500.00 bar Mixer fraction = 0.1500000 Water: Moles liquid = 0.6397E+02 kg liquid = 0.1152E+01 Moles total = 0.6364E+02 kg total = 0.1147E+01 Activity = 0.9568 Stoichiometric ionic strength = .1516004E+01 Osmotic coef. = 0.9140 True ionic strength = .1123357E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.87311E-05 -5.0589 0.44396E-05 -5.3527 0.50848E+00 -0.2937 2 H2O 0.95679E+00 -0.0192 0.95679E+00 -0.0192 3 Cl- 0.10975E+01 0.0404 0.58690E+00 -0.2314 0.53478E+00 -0.2718 4 SO4-- 0.14802E-03 -3.8297 0.80013E-05 -5.0968 0.54057E-01 -1.2671 5 HCO3- 0.23012E-01 -1.6380 0.12703E-01 -1.8961 0.55202E+00 -0.2580 6 HS- 0.10846E-05 -5.9647 0.58201E-06 -6.2351 0.53661E+00 -0.2703 7 H4SiO4 0.24309E-02 -2.6142 0.24309E-02 -2.6142 0.10000E+01 0.0000 8 Al+++ 0.97909E-13 -13.0092 0.11139E-15 -15.9532 0.11377E-02 -2.9440 9 Ca++ 0.11900E-02 -2.9244 0.57278E-04 -4.2420 0.48131E-01 -1.3176 10 Mg++ 0.11126E-03 -3.9536 0.49113E-05 -5.3088 0.44141E-01 -1.3552 11 Fe++ 0.10768E-05 -5.9679 0.48565E-07 -7.3137 0.45101E-01 -1.3458 12 K+ 0.38468E-01 -1.4149 0.21391E-01 -1.6698 0.55606E+00 -0.2549 13 Na+ 0.10801E+01 0.0335 0.57766E+00 -0.2383 0.53483E+00 -0.2718 14 Mn++ 0.81367E-05 -5.0896 0.37285E-06 -6.4285 0.45824E-01 -1.3389 15 Zn++ 0.30583E-07 -7.5145 0.13793E-08 -8.8603 0.45101E-01 -1.3458 16 Cu+ 0.45060E-11 -11.3462 0.24072E-11 -11.6185 0.53422E+00 -0.2723 17 Pb++ 0.54762E-08 -8.2615 0.27770E-09 -9.5564 0.50711E-01 -1.2949 18 Ag+ 0.15785E-10 -10.8018 0.87141E-11 -11.0598 0.55206E+00 -0.2580 19 Au+ 0.40085E-21 -21.3970 0.22381E-21 -21.6501 0.55833E+00 -0.2531 20 Ba++ 0.15661E-05 -5.8052 0.82138E-07 -7.0855 0.52448E-01 -1.2803 21 F- 0.11521E-02 -2.9385 0.58050E-03 -3.2362 0.50386E+00 -0.2977 22 H2AsO3- 0.86599E-06 -6.0625 0.59004E-06 -6.2291 0.68134E+00 -0.1666 24 HSiO3- 0.23155E-05 -5.6354 0.12383E-05 -5.9072 0.53478E+00 -0.2718 25 Ca(HSiO3)+ 0.10534E-07 -7.9774 0.58816E-08 -8.2305 0.55833E+00 -0.2531 26 Mg(HSiO3)+ 0.81725E-09 -9.0876 0.45629E-09 -9.3408 0.55833E+00 -0.2531 27 NaHSiO3,aq 0.58116E-05 -5.2357 0.58116E-05 -5.2357 0.10000E+01 0.0000 31 AgCl,aq 0.28143E-08 -8.5506 0.28143E-08 -8.5506 0.10000E+01 0.0000 32 AgCl2- 0.12607E-06 -6.8994 0.67418E-07 -7.1712 0.53478E+00 -0.2718 33 AgCl3-2 0.81362E-07 -7.0896 0.42458E-08 -8.3720 0.52184E-01 -1.2825 34 AgCl4-3 0.12628E-07 -7.8987 0.14172E-10 -10.8486 0.11223E-02 -2.9499 38 Ag(HS),aq 0.78275E-08 -8.1064 0.78275E-08 -8.1064 0.10000E+01 0.0000 40 AlO+ 0.18989E-09 -9.7215 0.10602E-09 -9.9746 0.55833E+00 -0.2531 42 HAlO2,aq 0.33015E-07 -7.4813 0.33015E-07 -7.4813 0.10000E+01 0.0000 43 AlO2- 0.23182E-06 -6.6349 0.11789E-06 -6.9285 0.50857E+00 -0.2937 44 AsO2- 0.16746E-06 -6.7761 0.89554E-07 -7.0479 0.53478E+00 -0.2718 45 HAsO2,aq 0.31043E-04 -4.5080 0.31043E-04 -4.5080 0.10000E+01 0.0000 46 H3AsO3,aq 0.80419E-04 -4.0946 0.80419E-04 -4.0946 0.10000E+01 0.0000 48 H2AsO4- 0.83860E-10 -10.0764 0.44846E-10 -10.3483 0.53478E+00 -0.2718 49 HAsO4-2 0.16914E-10 -10.7718 0.88262E-12 -12.0542 0.52184E-01 -1.2825 62 BaCO3,aq 0.38261E-09 -9.4172 0.38261E-09 -9.4172 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.11949E-05 -5.9227 0.67972E-06 -6.1677 0.56885E+00 -0.2450 64 BaCl+ 0.76468E-06 -6.1165 0.42694E-06 -6.3696 0.55833E+00 -0.2531 65 BaF+ 0.86386E-09 -9.0636 0.48232E-09 -9.3167 0.55833E+00 -0.2531 66 CH4,aq 0.10117E-08 -8.9949 0.92057E-09 -9.0359 0.90992E+00 -0.0410 71 CO,aq 0.15612E-08 -8.8065 0.15612E-08 -8.8065 0.10000E+01 0.0000 72 CO2,aq 0.28048E+00 -0.5521 0.25521E+00 -0.5931 0.90992E+00 -0.0410 73 CO3-2 0.46370E-05 -5.3338 0.24198E-06 -6.6162 0.52184E-01 -1.2825 74 CaCO3,aq 0.10637E-05 -5.9732 0.10637E-05 -5.9732 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.14286E-03 -3.8451 0.79761E-04 -4.0982 0.55833E+00 -0.2531 76 CaCl+ 0.45107E-03 -3.3458 0.25184E-03 -3.5989 0.55833E+00 -0.2531 77 CaCl2,aq 0.36989E-04 -4.4319 0.36989E-04 -4.4319 0.10000E+01 0.0000 78 CaF+ 0.42240E-05 -5.3743 0.23584E-05 -5.6274 0.55833E+00 -0.2531 79 CaOH+ 0.93325E-07 -7.0300 0.52106E-07 -7.2831 0.55833E+00 -0.2531 80 CaSO4,aq 0.47227E-06 -6.3258 0.47227E-06 -6.3258 0.10000E+01 0.0000 81 HCl,aq 0.13160E-05 -5.8807 0.13160E-05 -5.8807 0.10000E+01 0.0000 90 CuCl,aq 0.65590E-08 -8.1832 0.65590E-08 -8.1832 0.10000E+01 0.0000 91 CuCl2- 0.11662E-06 -6.9332 0.62367E-07 -7.2050 0.53478E+00 -0.2718 92 CuCl3-2 0.24471E-07 -7.6114 0.12770E-08 -8.8938 0.52184E-01 -1.2825 98 HF,aq 0.76758E-04 -4.1149 0.76758E-04 -4.1149 0.10000E+01 0.0000 99 HF2- 0.23704E-07 -7.6252 0.12677E-07 -7.8970 0.53478E+00 -0.2718 101 FeCl+ 0.29297E-06 -6.5332 0.16357E-06 -6.7863 0.55833E+00 -0.2531 102 FeCl2,aq 0.12307E-08 -8.9099 0.12307E-08 -8.9099 0.10000E+01 0.0000 104 FeF+ 0.76282E-08 -8.1176 0.42590E-08 -8.3707 0.55833E+00 -0.2531 106 FeO,aq 0.49060E-10 -10.3093 0.49060E-10 -10.3093 0.10000E+01 0.0000 107 FeOH+ 0.12541E-07 -7.9017 0.70019E-08 -8.1548 0.55833E+00 -0.2531 112 HFeO2,aq 0.42557E-10 -10.3710 0.42557E-10 -10.3710 0.10000E+01 0.0000 113 H2,aq 0.14128E-06 -6.8499 0.12856E-06 -6.8909 0.90992E+00 -0.0410 114 KCl,aq 0.96219E-03 -3.0167 0.96219E-03 -3.0167 0.10000E+01 0.0000 115 KHSO4,aq 0.15425E-09 -9.8118 0.15425E-09 -9.8118 0.10000E+01 0.0000 116 KOH,aq 0.34116E-07 -7.4670 0.34116E-07 -7.4670 0.10000E+01 0.0000 117 KSO4- 0.14659E-04 -4.8339 0.78392E-05 -5.1057 0.53478E+00 -0.2718 118 MgCO3,aq 0.13556E-07 -7.8679 0.13556E-07 -7.8679 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.11994E-04 -4.9210 0.66969E-05 -5.1741 0.55833E+00 -0.2531 120 MgCl+ 0.24639E-04 -4.6084 0.13756E-04 -4.8615 0.55833E+00 -0.2531 121 MgF+ 0.11167E-05 -5.9521 0.62350E-06 -6.2052 0.55833E+00 -0.2531 122 MgOH+ 0.29338E-07 -7.5326 0.16380E-07 -7.7857 0.55833E+00 -0.2531 124 MnF+ 0.22634E-07 -7.6452 0.12637E-07 -7.8984 0.55833E+00 -0.2531 125 MnO,aq 0.11762E-10 -10.9295 0.11762E-10 -10.9295 0.10000E+01 0.0000 126 MnOH+ 0.12228E-07 -7.9126 0.68275E-08 -8.1657 0.55833E+00 -0.2531 131 MnCl+ 0.21743E-04 -4.6627 0.12140E-04 -4.9158 0.55833E+00 -0.2531 132 MnSO4,aq 0.34960E-08 -8.4564 0.34960E-08 -8.4564 0.10000E+01 0.0000 133 NaCl,aq 0.24203E+00 -0.6161 0.24203E+00 -0.6161 0.10000E+01 0.0000 134 NaF,aq 0.17868E-03 -3.7479 0.17868E-03 -3.7479 0.10000E+01 0.0000 135 NaOH,aq 0.69998E-06 -6.1549 0.69998E-06 -6.1549 0.10000E+01 0.0000 137 OH- 0.25416E-05 -5.5949 0.12926E-05 -5.8885 0.50857E+00 -0.2937 140 PbCl+ 0.59247E-07 -7.2273 0.33079E-07 -7.4804 0.55833E+00 -0.2531 141 PbCl2,aq 0.23804E-06 -6.6233 0.23804E-06 -6.6233 0.10000E+01 0.0000 142 PbCl3- 0.17206E-06 -6.7643 0.92016E-07 -7.0361 0.53478E+00 -0.2718 143 PbCl4-2 0.22456E-06 -6.6487 0.11719E-07 -7.9311 0.52184E-01 -1.2825 144 PbF+ 0.89791E-10 -10.0468 0.50133E-10 -10.2999 0.55833E+00 -0.2531 146 PbO,aq 0.23261E-10 -10.6334 0.23261E-10 -10.6334 0.10000E+01 0.0000 148 Pb(HS)2,aq 0.13981E-09 -9.8545 0.13981E-09 -9.8545 0.10000E+01 0.0000 150 H2S,aq 0.95173E-05 -5.0215 0.86600E-05 -5.0625 0.90992E+00 -0.0410 158 HSO3- 0.15843E-09 -9.8002 0.84725E-10 -10.0720 0.53478E+00 -0.2718 159 HSO4- 0.57975E-06 -6.2368 0.32883E-06 -6.4830 0.56718E+00 -0.2463 161 S2O3-2 0.19446E-10 -10.7112 0.10148E-11 -11.9936 0.52184E-01 -1.2825 173 ZnCl+ 0.42852E-05 -5.3680 0.23925E-05 -5.6211 0.55833E+00 -0.2531 174 ZnCl2,aq 0.10435E-05 -5.9815 0.10435E-05 -5.9815 0.10000E+01 0.0000 175 ZnCl3- 0.13698E-06 -6.8634 0.73252E-07 -7.1352 0.53478E+00 -0.2718 176 ZnF+ 0.14381E-09 -9.8422 0.80293E-10 -10.0953 0.55833E+00 -0.2531 177 ZnO,aq 0.19311E-09 -9.7142 0.19311E-09 -9.7142 0.10000E+01 0.0000 178 ZnOH+ 0.18422E-06 -6.7347 0.10286E-06 -6.9878 0.55833E+00 -0.2531 Charge balance for all species = -.1125E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8731124E-05 0.2806690E+00 0.2586819E+03 0.0000 2 H2O 0.1000000E+01 0.5522774E+02 0.9097785E+06 0.0000 3 Cl- 0.1097454E+01 0.1341035E+01 0.4347404E+05 5.1212 4 SO4-- 0.1480156E-03 0.1636934E-03 0.1437865E+02 5.6085 5 HCO3- 0.2301233E-01 0.3036532E+00 0.1694209E+05 3.4566 6 HS- 0.1084612E-05 0.1064681E-04 0.3219710E+00 -0.8824 7 H4SiO4 0.2430863E-02 0.2439002E-02 0.2143591E+03 -2.6142 8 Al+++ 0.9790893E-13 0.2650273E-06 0.6538735E-02 0.1048 9 Ca++ 0.1190048E-02 0.1826827E-02 0.6694842E+02 6.4633 10 Mg++ 0.1112635E-03 0.1490571E-03 0.3313677E+01 5.3965 11 Fe++ 0.1076816E-05 0.1391283E-05 0.7104804E-01 3.3916 12 K+ 0.3846807E-01 0.3944495E-01 0.1410352E+04 3.6829 13 Na+ 0.1080070E+01 0.1322290E+01 0.2779705E+05 5.1143 14 Mn++ 0.8136663E-05 0.2991783E-04 0.1502934E+01 4.2768 15 Zn++ 0.3058307E-07 0.5680835E-05 0.3395687E+00 1.8450 16 Cu+ 0.4506005E-11 0.1476554E-06 0.8578936E-02 -6.2658 17 Pb++ 0.5476186E-08 0.6996430E-06 0.1325508E+00 1.1489 18 Ag+ 0.1578489E-10 0.2307189E-06 0.2275730E-01 -5.7071 19 Au+ 0.4008488E-21 0.2699564E-11 0.4862102E-06 -16.2975 20 Ba++ 0.1566094E-05 0.3526920E-05 0.4429244E+00 3.6199 21 F- 0.1152116E-02 0.1412970E-02 0.2454584E+02 2.1165 22 H2AsO3- 0.8659936E-06 0.1124963E-03 0.1285173E+02 -0.8765 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234411E+00 -.5964725E-05 0.0000000E+00 2 H2O 0.6364409E+02 0.6364409E+02 0.0000000E+00 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1226931E-04 0.1760999E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810690E-02 0.1050932E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.3054158E-06 0.2101863E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.6546559E-05 0.9216176E-06 0.0000000E+00 16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00 17 Pb++ 0.1565021E-05 0.8062641E-06 0.7587566E-06 0.0000000E+00 18 Ag+ 0.4271281E-06 0.2658790E-06 0.1612491E-06 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1628298E-02 0.2101863E-05 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.126027E+04 g Temperature = 178.25 C Pressure = 500.00 bar Mixer frac. = 0.1500000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) argentite 0.8062E-07 -7.094 0.1998E-04 -4.699 4.122 0.2806E-05 topaz 0.1051E-05 -5.978 0.1934E-03 -3.714 39.90 0.5415E-04 galena 0.7588E-06 -6.120 0.1815E-03 -3.741 37.45 0.2389E-04 sphalerite 0.9216E-06 -6.035 0.8979E-04 -4.047 18.52 0.2196E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity argentite 0.1000E+01 0.1000E+01 1.0000 0.000 topaz 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.1500000 Solid products produced: Mass = 0.000485 g Volume = 0.000103 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.300 AFFINITY: 0.3936E+03 GOLD Q/K: 0.0293 SILVER Q/K: 0.2669 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 178.2522 deg.C Sat. pressure: 83.2311 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1965E+00 0.6722 0.1099E+02 0.1636E+02 CO2,gas 0.8035E+00 0.9026 0.6036E+02 0.6688E+02 CH4,gas 0.1805E-07 1.1056 0.1661E-05 0.1503E-05 H2,gas 0.1687E-05 1.0374 0.1456E-03 0.1404E-03 H2S,gas 0.7016E-05 0.8358 0.4881E-03 0.5840E-03 S2,gas 0.7351E-16 1.0000 0.6118E-14 0.6118E-14 CO,gas 0.2487E-07 1.0000 0.2070E-05 0.2070E-05 SO3,gas 0.1827E-26 1.0000 0.1520E-24 0.1520E-24 O2,gas 0.4002E-43 1.0000 0.3331E-41 0.3331E-41 SO2,gas 0.3072E-12 1.0000 0.2557E-10 0.2557E-10 HF,gas 0.3296E-07 1.0000 0.2743E-05 0.2743E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 196 argentite -23.00 -23.00 0.00 0.000 -0.73383E-11 225 topaz -19.58 -19.58 0.00 0.000 0.00000E+00 260 galena -10.44 -10.44 0.00 0.000 0.00000E+00 272 sphalerite -9.74 -9.74 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.64 -0.02 -1.66 -1.658 0.34243E+04 1.041 2 CO2,gas -6.31 -7.23 -0.92 -0.306 0.18966E+04 1.781 3 CH4,gas 5.43 -3.05 -8.48 -2.120 0.17513E+05 -5.780 4 H2,gas 7.57 1.03 -6.54 -3.735 0.13500E+05 -3.837 5 H2S,gas -5.58 -11.59 -6.01 -3.005 0.12415E+05 -3.311 6 S2,gas -8.33 -25.24 -16.91 -2.602 0.34933E+05 -14.213 7 CO,gas 2.21 -6.18 -8.38 -2.579 0.17316E+05 -5.684 8 SO3,gas 11.73 -15.78 -27.52 -6.879 0.56838E+05 -24.818 9 O2,gas 42.07 -2.11 -44.18 -29.451 0.91248E+05 -41.477 10 SO2,gas -1.44 -14.73 -13.29 -3.544 0.27454E+05 -10.592 11 HF,gas -0.33 -8.59 -8.26 -4.130 0.17063E+05 -5.562 12 HCl,gas 1.23 -5.58 -6.82 -3.409 0.14083E+05 -6.818 13 acmite 6.32 2.80 -3.52 -0.366 0.72790E+04 17 albite-high -1.09 -2.55 -1.46 -0.112 0.30157E+04 18 albite -1.83 -2.55 -0.72 -0.055 0.14868E+04 22 analcite 1.31 0.01 -1.30 -0.144 0.26825E+04 23 andalusite -0.13 -2.42 -2.29 -0.229 0.47347E+04 26 anhydrite -6.41 -9.34 -2.93 -1.465 0.60537E+04 27 ankerite -3.63 -4.64 -1.01 -0.168 0.20864E+04 31 anorthite 5.94 1.44 -4.49 -0.346 0.92803E+04 34 aragonite 0.11 -0.79 -0.89 -0.298 0.18438E+04 35 brucite 10.06 5.36 -4.70 -0.940 0.97112E+04 36 calcite -0.03 -0.79 -0.75 -0.251 0.15565E+04 37 carnegieite-low 5.92 2.60 -3.31 -0.473 0.68381E+04 38 carnegieite-high 6.66 2.60 -4.06 -0.579 0.83782E+04 39 carpholite-Mg 3.01 0.34 -2.67 -0.178 0.55079E+04 40 carpholite-Fe 1.42 -1.67 -3.09 -0.206 0.63764E+04 41 celadonite 3.00 -1.20 -4.20 -0.247 0.86767E+04 42 celadonite-Fe 1.67 -3.20 -4.87 -0.287 0.10063E+05 49 chloritoid-Mg 6.41 2.93 -3.47 -0.231 0.71723E+04 50 chloritoid-Fe 3.14 0.93 -2.21 -0.147 0.45574E+04 51 chloritoid-Mn 5.33 1.81 -3.51 -0.234 0.72581E+04 53 coesite -1.92 -2.58 -0.66 -0.219 0.13601E+04 58 corundum 2.61 0.15 -2.45 -0.223 0.50677E+04 60 cristobalite -2.11 -2.58 -0.47 -0.157 0.97077E+03 63 cymrite-K 0.13 -4.00 -4.13 -0.344 0.85338E+04 65 diaspore 0.49 0.07 -0.42 -0.070 0.87343E+03 66 diamond -2.28 -5.12 -2.84 -0.811 0.58634E+04 69 dolomite,ordered -1.37 -2.64 -1.27 -0.212 0.26274E+04 83 gibbsite 1.72 0.05 -1.68 -0.239 0.34609E+04 86 goethite 4.78 2.84 -1.94 -0.419 0.40059E+04 87 graphite -2.68 -5.12 -2.44 -0.699 0.50501E+04 90 halite 1.43 -0.47 -1.90 -0.952 0.39337E+04 91 hematite 8.98 5.69 -3.28 -0.398 0.67838E+04 92 heulandite -8.36 -11.55 -3.19 -0.145 0.65971E+04 96 jadeite 2.13 0.03 -2.10 -0.210 0.43357E+04 98 kalsilite 4.83 1.17 -3.66 -0.522 0.75498E+04 99 kaolinite -4.50 -5.04 -0.54 -0.049 0.11125E+04 100 kyanite -0.19 -2.42 -2.23 -0.223 0.46149E+04 102 laumontite -0.99 -3.78 -2.80 -0.186 0.57744E+04 103 lawsonite 4.41 1.41 -3.00 -0.200 0.62001E+04 104 leucite 1.86 -1.40 -3.26 -0.326 0.67348E+04 107 magnesite -0.56 -1.85 -1.29 -0.431 0.26707E+04 114 margarite 5.97 1.58 -4.39 -0.176 0.90687E+04 117 microcline -3.35 -3.98 -0.63 -0.049 0.13028E+04 120 mullite-Si 1.65 -2.42 -4.07 -0.407 0.84148E+04 121 muscovite -3.07 -3.85 -0.78 -0.046 0.16048E+04 122 paragonite -1.84 -2.41 -0.57 -0.034 0.11807E+04 123 nepheline 5.32 2.60 -2.71 -0.387 0.55999E+04 143 pyrite -19.44 -20.82 -1.37 -0.323 0.28380E+04 144 pyrrhotite -4.80 -8.20 -3.40 -1.132 0.70129E+04 145 pyrrhotiteFe0.875 -6.20 -8.75 -2.55 -0.939 0.52711E+04 146 pyroxmangite 5.78 1.68 -4.09 -0.819 0.84572E+04 147 pyrophyllite -8.77 -10.17 -1.40 -0.088 0.28942E+04 148 quartz -2.43 -2.58 -0.15 -0.049 0.30498E+03 153 rhodochrosite -1.63 -2.97 -1.35 -0.449 0.27814E+04 154 rhodonite 5.81 1.68 -4.12 -0.825 0.85177E+04 155 sanidine -2.35 -3.98 -1.63 -0.126 0.33718E+04 157 siderite -3.30 -3.86 -0.56 -0.187 0.11572E+04 158 sillimanite 0.05 -2.42 -2.47 -0.247 0.51099E+04 165 stilbite -8.42 -11.57 -3.15 -0.150 0.64978E+04 168 stishovite 2.40 -2.58 -4.98 -1.659 0.10280E+05 171 sulfur -8.53 -12.62 -4.09 -1.258 0.84475E+04 172 sylvite 1.43 -1.90 -3.33 -1.666 0.68816E+04 180 topaz-H 0.12 -2.44 -2.57 -0.233 0.53028E+04 181 tridymite -2.14 -2.58 -0.44 -0.146 0.90212E+03 184 troilite-low -4.88 -8.20 -3.32 -1.107 0.68593E+04 190 wairakite -0.63 -3.75 -3.12 -0.183 0.64359E+04 192 wollastonite 8.53 3.87 -4.66 -0.932 0.96288E+04 197 arsenic -5.74 -9.97 -4.23 -1.092 0.87439E+04 199 arsenopyrite -13.58 -18.17 -4.59 -0.816 0.94820E+04 200 beidellite-Ca -5.81 -8.23 -2.42 -0.150 0.49969E+04 201 beidellite-H -6.30 -9.30 -3.00 -0.191 0.61923E+04 202 beidellite-K -5.41 -8.08 -2.67 -0.164 0.55202E+04 203 beidellite-Mg -6.05 -8.41 -2.36 -0.146 0.48797E+04 204 beidellite-Na -5.32 -7.61 -2.29 -0.140 0.47376E+04 205 bornite -74.69 -74.81 -0.12 -0.009 0.24657E+03 207 chalcedony -2.27 -2.58 -0.30 -0.101 0.62479E+03 208 chalcocite -22.90 -24.12 -1.22 -0.304 0.25101E+04 210 covellite -16.76 -18.37 -1.61 -0.613 0.33241E+04 211 dawsonite 0.16 -2.07 -2.23 -0.279 0.46103E+04 213 montmorillonite-Ca -5.14 -7.36 -2.22 -0.137 0.45892E+04 214 montmorillonite-K -4.83 -7.21 -2.38 -0.146 0.49138E+04 215 montmorillonite-Mg -5.37 -7.53 -2.17 -0.134 0.44768E+04 216 montmorillonite-Na -4.67 -6.74 -2.07 -0.127 0.42767E+04 217 nontronite-Ca 1.12 -2.69 -3.81 -0.247 0.78687E+04 218 nontronite-H 0.62 -3.76 -4.38 -0.294 0.90557E+04 219 nontronite-K 1.52 -2.54 -4.06 -0.261 0.83920E+04 220 nontronite-Mg 0.91 -2.87 -3.78 -0.245 0.78132E+04 221 nontronite-Na 1.61 -2.07 -3.68 -0.237 0.76115E+04 229 gypsum -5.53 -9.38 -3.85 -0.962 0.79444E+04 245 acanthite -22.83 -23.00 -0.17 -0.043 0.35628E+03 251 barite -9.55 -12.18 -2.64 -1.318 0.54440E+04 252 boehmite 1.62 0.07 -1.55 -0.259 0.32068E+04 253 cerussite -2.78 -6.10 -3.32 -1.105 0.68500E+04 254 chalcopyrite -25.20 -26.57 -1.37 -0.255 0.28335E+04 256 copper,native -1.80 -5.75 -3.95 -1.375 0.81639E+04 257 dolomite,disordered -0.89 -2.64 -1.75 -0.291 0.36105E+04 258 ferrous-oxide 7.33 3.37 -3.96 -0.991 0.81841E+04 259 fluorite -10.12 -10.71 -0.60 -0.198 0.12295E+04 261 gold,native -14.25 -15.78 -1.53 -0.533 0.31670E+04 262 silver,native -4.62 -5.19 -0.57 -0.200 0.11849E+04 269 silica-amorphous -1.73 -2.58 -0.85 -0.283 0.17544E+04 270 smithsonite -1.65 -5.40 -3.76 -1.253 0.77618E+04 273 wurtzite -8.23 -9.74 -1.51 -0.504 0.31248E+04 274 zincite 6.14 1.83 -4.31 -1.078 0.89064E+04 275 an20ab80 -0.49 -1.75 -1.26 -0.097 0.25972E+04 276 an25ab75 -0.13 -1.55 -1.42 -0.109 0.29308E+04 277 an30ab70 0.24 -1.35 -1.59 -0.122 0.32766E+04 Calculations done for 178.2522 Deg. C; 500.0000 bar Mixer fraction: 0.1500000 Temperature Stoc.ionic strength Heat per mole Actual solution: 178.252 .15160E+01 3.370 Mixing solution: 25.000 .50000E-10 0.646 Fract. of mixing solution added: 0.050000 BITMOL = 0.2775E+01 OLDMOL = 0.6538E+02 New heat: 3.260 New temperature: 172.152 New mixer fraction: 0.2000000 Resulting temperature: 172.152Deg. C Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1296E-03 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 70 Temperature = 172.15 C Pressure = 500.00 bar Mixer fraction = 0.2000000 Water: Moles liquid = 0.6674E+02 kg liquid = 0.1202E+01 Moles total = 0.6642E+02 kg total = 0.1197E+01 Activity = 0.9584 Stoichiometric ionic strength = .1452654E+01 Osmotic coef. = 0.9174 True ionic strength = .1090202E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95020E-05 -5.0222 0.49419E-05 -5.3061 0.52009E+00 -0.2839 2 H2O 0.95840E+00 -0.0185 0.95840E+00 -0.0185 3 Cl- 0.10653E+01 0.0275 0.57943E+00 -0.2370 0.54390E+00 -0.2645 4 SO4-- 0.14254E-03 -3.8461 0.83980E-05 -5.0758 0.58918E-01 -1.2298 5 HCO3- 0.22067E-01 -1.6562 0.12353E-01 -1.9082 0.55977E+00 -0.2520 6 HS- 0.93694E-06 -6.0283 0.51117E-06 -6.2914 0.54558E+00 -0.2631 7 H4SiO4 0.23305E-02 -2.6325 0.23305E-02 -2.6325 0.10000E+01 0.0000 8 Al+++ 0.13893E-12 -12.8572 0.19463E-15 -15.7108 0.14009E-02 -2.8536 9 Ca++ 0.11712E-02 -2.9314 0.61837E-04 -4.2087 0.52799E-01 -1.2774 10 Mg++ 0.10801E-03 -3.9665 0.52684E-05 -5.2783 0.48777E-01 -1.3118 11 Fe++ 0.10454E-05 -5.9807 0.51999E-07 -7.2840 0.49743E-01 -1.3033 12 K+ 0.36973E-01 -1.4321 0.20824E-01 -1.6814 0.56321E+00 -0.2493 13 Na+ 0.10485E+01 0.0206 0.56991E+00 -0.2442 0.54352E+00 -0.2648 14 Mn++ 0.84651E-05 -5.0724 0.42724E-06 -6.3693 0.50471E-01 -1.2970 15 Zn++ 0.33870E-07 -7.4702 0.16848E-08 -8.7734 0.49743E-01 -1.3033 16 Cu+ 0.44872E-11 -11.3480 0.24364E-11 -11.6133 0.54296E+00 -0.2652 17 Pb++ 0.52195E-08 -8.2824 0.28920E-09 -9.5388 0.55408E-01 -1.2564 18 Ag+ 0.12027E-10 -10.9199 0.67286E-11 -11.1721 0.55948E+00 -0.2522 19 Au+ 0.28182E-21 -21.5500 0.15932E-21 -21.7977 0.56533E+00 -0.2477 20 Ba++ 0.16031E-05 -5.7950 0.91646E-07 -7.0379 0.57166E-01 -1.2429 21 F- 0.11142E-02 -2.9530 0.57508E-03 -3.2403 0.51612E+00 -0.2872 22 H2AsO3- 0.66724E-06 -6.1757 0.45509E-06 -6.3419 0.68205E+00 -0.1662 24 HSiO3- 0.19626E-05 -5.7072 0.10675E-05 -5.9716 0.54390E+00 -0.2645 25 Ca(HSiO3)+ 0.85599E-08 -8.0675 0.48391E-08 -8.3152 0.56533E+00 -0.2477 26 Mg(HSiO3)+ 0.67542E-09 -9.1704 0.38183E-09 -9.4181 0.56533E+00 -0.2477 27 NaHSiO3,aq 0.50369E-05 -5.2978 0.50369E-05 -5.2978 0.10000E+01 0.0000 31 AgCl,aq 0.21325E-08 -8.6711 0.21325E-08 -8.6711 0.10000E+01 0.0000 32 AgCl2- 0.91584E-07 -7.0382 0.49813E-07 -7.3027 0.54390E+00 -0.2645 33 AgCl3-2 0.55117E-07 -7.2587 0.31432E-08 -8.5026 0.57028E-01 -1.2439 34 AgCl4-3 0.75622E-08 -8.1214 0.10540E-10 -10.9772 0.13937E-02 -2.8558 38 Ag(HS),aq 0.73357E-08 -8.1346 0.73357E-08 -8.1346 0.10000E+01 0.0000 40 AlO+ 0.18629E-09 -9.7298 0.10532E-09 -9.9775 0.56533E+00 -0.2477 42 HAlO2,aq 0.26395E-07 -7.5785 0.26395E-07 -7.5785 0.10000E+01 0.0000 43 AlO2- 0.14281E-06 -6.8453 0.74299E-07 -7.1290 0.52028E+00 -0.2838 44 AsO2- 0.14184E-06 -6.8482 0.77145E-07 -7.1127 0.54390E+00 -0.2645 45 HAsO2,aq 0.30768E-04 -4.5119 0.30768E-04 -4.5119 0.10000E+01 0.0000 46 H3AsO3,aq 0.76241E-04 -4.1178 0.76241E-04 -4.1178 0.10000E+01 0.0000 48 H2AsO4- 0.67278E-10 -10.1721 0.36593E-10 -10.4366 0.54390E+00 -0.2645 49 HAsO4-2 0.12339E-10 -10.9087 0.70365E-12 -12.1526 0.57028E-01 -1.2439 62 BaCO3,aq 0.33691E-09 -9.4725 0.33691E-09 -9.4725 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.10614E-05 -5.9741 0.61046E-06 -6.2143 0.57517E+00 -0.2402 64 BaCl+ 0.71459E-06 -6.1459 0.40398E-06 -6.3936 0.56533E+00 -0.2477 65 BaF+ 0.82529E-09 -9.0834 0.46656E-09 -9.3311 0.56533E+00 -0.2477 66 CH4,aq 0.81776E-09 -9.0874 0.74208E-09 -9.1296 0.90745E+00 -0.0422 71 CO,aq 0.10770E-08 -8.9678 0.10770E-08 -8.9678 0.10000E+01 0.0000 72 CO2,aq 0.26881E+00 -0.5706 0.24393E+00 -0.6127 0.90745E+00 -0.0422 73 CO3-2 0.39655E-05 -5.4017 0.22615E-06 -6.6456 0.57028E-01 -1.2439 74 CaCO3,aq 0.90785E-06 -6.0420 0.90785E-06 -6.0420 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.12912E-03 -3.8890 0.72993E-04 -4.1367 0.56533E+00 -0.2477 76 CaCl+ 0.41274E-03 -3.3843 0.23333E-03 -3.6320 0.56533E+00 -0.2477 77 CaCl2,aq 0.32506E-04 -4.4880 0.32506E-04 -4.4880 0.10000E+01 0.0000 78 CaF+ 0.38573E-05 -5.4137 0.21806E-05 -5.6614 0.56533E+00 -0.2477 79 CaOH+ 0.68347E-07 -7.1653 0.38639E-07 -7.4130 0.56533E+00 -0.2477 80 CaSO4,aq 0.47463E-06 -6.3236 0.47463E-06 -6.3236 0.10000E+01 0.0000 81 HCl,aq 0.13255E-05 -5.8776 0.13255E-05 -5.8776 0.10000E+01 0.0000 90 CuCl,aq 0.65369E-08 -8.1846 0.65369E-08 -8.1846 0.10000E+01 0.0000 91 CuCl2- 0.11257E-06 -6.9486 0.61227E-07 -7.2131 0.54390E+00 -0.2645 92 CuCl3-2 0.22403E-07 -7.6497 0.12776E-08 -8.8936 0.57028E-01 -1.2439 98 HF,aq 0.73747E-04 -4.1323 0.73747E-04 -4.1323 0.10000E+01 0.0000 99 HF2- 0.22376E-07 -7.6502 0.12170E-07 -7.9147 0.54390E+00 -0.2645 101 FeCl+ 0.27020E-06 -6.5683 0.15275E-06 -6.8160 0.56533E+00 -0.2477 102 FeCl2,aq 0.74008E-09 -9.1307 0.74008E-09 -9.1307 0.10000E+01 0.0000 104 FeF+ 0.71715E-08 -8.1444 0.40542E-08 -8.3921 0.56533E+00 -0.2477 106 FeO,aq 0.28487E-10 -10.5453 0.28487E-10 -10.5453 0.10000E+01 0.0000 107 FeOH+ 0.98925E-08 -8.0047 0.55925E-08 -8.2524 0.56533E+00 -0.2477 112 HFeO2,aq 0.25898E-10 -10.5867 0.25898E-10 -10.5867 0.10000E+01 0.0000 113 H2,aq 0.10429E-06 -6.9818 0.94638E-07 -7.0239 0.90745E+00 -0.0422 114 KCl,aq 0.81809E-03 -3.0872 0.81809E-03 -3.0872 0.10000E+01 0.0000 115 KHSO4,aq 0.12187E-09 -9.9141 0.12187E-09 -9.9141 0.10000E+01 0.0000 116 KOH,aq 0.25551E-07 -7.5926 0.25551E-07 -7.5926 0.10000E+01 0.0000 117 KSO4- 0.13350E-04 -4.8745 0.72609E-05 -5.1390 0.54390E+00 -0.2645 118 MgCO3,aq 0.11895E-07 -7.9246 0.11895E-07 -7.9246 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.10821E-04 -4.9657 0.61172E-05 -5.2134 0.56533E+00 -0.2477 120 MgCl+ 0.22969E-04 -4.6389 0.12985E-04 -4.8866 0.56533E+00 -0.2477 121 MgF+ 0.10262E-05 -5.9888 0.58013E-06 -6.2365 0.56533E+00 -0.2477 122 MgOH+ 0.21796E-07 -7.6616 0.12322E-07 -7.9093 0.56533E+00 -0.2477 124 MnF+ 0.22465E-07 -7.6485 0.12700E-07 -7.8962 0.56533E+00 -0.2477 126 MnOH+ 0.10151E-07 -7.9935 0.57386E-08 -8.2412 0.56533E+00 -0.2477 131 MnCl+ 0.20172E-04 -4.6952 0.11404E-04 -4.9429 0.56533E+00 -0.2477 132 MnSO4,aq 0.36838E-08 -8.4337 0.36838E-08 -8.4337 0.10000E+01 0.0000 133 NaCl,aq 0.21860E+00 -0.6604 0.21860E+00 -0.6604 0.10000E+01 0.0000 134 NaF,aq 0.16119E-03 -3.7927 0.16119E-03 -3.7927 0.10000E+01 0.0000 135 NaOH,aq 0.54126E-06 -6.2666 0.54126E-06 -6.2666 0.10000E+01 0.0000 137 OH- 0.20137E-05 -5.6960 0.10477E-05 -5.9798 0.52028E+00 -0.2838 140 PbCl+ 0.53709E-07 -7.2700 0.30363E-07 -7.5177 0.56533E+00 -0.2477 141 PbCl2,aq 0.20089E-06 -6.6971 0.20089E-06 -6.6971 0.10000E+01 0.0000 142 PbCl3- 0.13638E-06 -6.8653 0.74177E-07 -7.1297 0.54390E+00 -0.2645 143 PbCl4-2 0.16541E-06 -6.7815 0.94327E-08 -8.0254 0.57028E-01 -1.2439 144 PbF+ 0.84045E-10 -10.0755 0.47513E-10 -10.3232 0.56533E+00 -0.2477 146 PbO,aq 0.14856E-10 -10.8281 0.14856E-10 -10.8281 0.10000E+01 0.0000 148 Pb(HS)2,aq 0.11538E-09 -9.9379 0.11538E-09 -9.9379 0.10000E+01 0.0000 150 H2S,aq 0.87791E-05 -5.0566 0.79665E-05 -5.0987 0.90745E+00 -0.0422 158 HSO3- 0.12313E-09 -9.9096 0.66969E-10 -10.1741 0.54390E+00 -0.2645 159 HSO4- 0.54796E-06 -6.2612 0.31446E-06 -6.5024 0.57387E+00 -0.2412 161 S2O3-2 0.17186E-10 -10.7648 0.98008E-12 -12.0087 0.57028E-01 -1.2439 173 ZnCl+ 0.39123E-05 -5.4076 0.22117E-05 -5.6553 0.56533E+00 -0.2477 174 ZnCl2,aq 0.91239E-06 -6.0398 0.91239E-06 -6.0398 0.10000E+01 0.0000 175 ZnCl3- 0.11635E-06 -6.9342 0.63281E-07 -7.1987 0.54390E+00 -0.2645 176 ZnF+ 0.15353E-09 -9.8138 0.86793E-10 -10.0615 0.56533E+00 -0.2477 177 ZnO,aq 0.13257E-09 -9.8776 0.13257E-09 -9.8776 0.10000E+01 0.0000 178 ZnOH+ 0.15356E-06 -6.8137 0.86813E-07 -7.0614 0.56533E+00 -0.2477 Charge balance for all species = -.1078E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9502035E-05 0.2689983E+00 0.2488112E+03 0.0000 2 H2O 0.1000000E+01 0.5523940E+02 0.9132214E+06 0.0000 3 Cl- 0.1065324E+01 0.1285270E+01 0.4181508E+05 5.0691 4 SO4-- 0.1425374E-03 0.1568864E-03 0.1382996E+02 5.5364 5 HCO3- 0.2206747E-01 0.2910262E+00 0.1629558E+05 3.3979 6 HS- 0.9369410E-06 0.9750786E-05 0.2959278E+00 -0.9853 7 H4SiO4 0.2330528E-02 0.2337537E-02 0.2061755E+03 -2.6325 8 Al+++ 0.1389260E-12 0.1693953E-06 0.4194239E-02 0.2075 9 Ca++ 0.1171179E-02 0.1750861E-02 0.6439368E+02 6.4035 10 Mg++ 0.1080086E-03 0.1428587E-03 0.3187228E+01 5.3339 11 Fe++ 0.1045364E-05 0.1333428E-05 0.6833686E-01 3.3282 12 K+ 0.3697322E-01 0.3780469E-01 0.1356533E+04 3.6247 13 Na+ 0.1048541E+01 0.1267304E+01 0.2673632E+05 5.0619 14 Mn++ 0.8465060E-05 0.2867374E-04 0.1445582E+01 4.2429 15 Zn++ 0.3387048E-07 0.5128743E-05 0.3076629E+00 1.8388 16 Cu+ 0.4487244E-11 0.1415153E-06 0.8251565E-02 -6.3071 17 Pb++ 0.5219514E-08 0.5618129E-06 0.1068184E+00 1.0734 18 Ag+ 0.1202664E-10 0.1637472E-06 0.1620915E-01 -5.8660 19 Au+ 0.2818203E-21 0.2587306E-11 0.4676565E-06 -16.4916 20 Ba++ 0.1603142E-05 0.3380258E-05 0.4260224E+00 3.5743 21 F- 0.1114230E-02 0.1354129E-02 0.2360770E+02 2.0658 22 H2AsO3- 0.6672383E-06 0.1078183E-03 0.1236131E+02 -1.0358 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234419E+00 -.6713226E-05 0.0000000E+00 2 H2O 0.6641950E+02 0.6641950E+02 0.0000000E+00 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886393E-03 0.0000000E+00 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1172428E-04 0.2306028E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810639E-02 0.1101800E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.2036799E-06 0.2203599E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1603305E-05 0.0000000E+00 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.6166768E-05 0.1301408E-05 0.0000000E+00 16 Cu+ 0.1701571E-06 0.1701571E-06 0.0000000E+00 0.0000000E+00 17 Pb++ 0.1565021E-05 0.6755203E-06 0.8895004E-06 0.0000000E+00 18 Ag+ 0.4271281E-06 0.1968886E-06 0.2302395E-06 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1628196E-02 0.2203599E-05 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1271E-20 Mass of aqueous solution: 0.131027E+04 g Temperature = 172.15 C Pressure = 500.00 bar Mixer frac. = 0.2000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) argentite 0.1151E-06 -6.939 0.2853E-04 -4.545 4.997 0.4006E-05 topaz 0.1102E-05 -5.958 0.2028E-03 -3.693 35.52 0.5677E-04 galena 0.8895E-06 -6.051 0.2128E-03 -3.672 37.28 0.2801E-04 sphalerite 0.1301E-05 -5.886 0.1268E-03 -3.897 22.21 0.3101E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity argentite 0.1000E+01 0.1000E+01 1.0000 0.000 topaz 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.2000000 Solid products produced: Mass = 0.000571 g Volume = 0.000120 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.300 AFFINITY: 0.3918E+03 GOLD Q/K: 0.0343 SILVER Q/K: 0.2428 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 172.1521 deg.C Sat. pressure: 78.6515 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1790E+00 0.6828 0.9615E+01 0.1408E+02 CO2,gas 0.8209E+00 0.9019 0.5824E+02 0.6457E+02 CH4,gas 0.1640E-07 1.0965 0.1414E-05 0.1290E-05 H2,gas 0.1385E-05 1.0358 0.1129E-03 0.1090E-03 H2S,gas 0.6842E-05 0.8379 0.4509E-03 0.5382E-03 S2,gas 0.5901E-16 1.0000 0.4641E-14 0.4641E-14 CO,gas 0.1941E-07 1.0000 0.1527E-05 0.1527E-05 SO3,gas 0.9091E-27 1.0000 0.7150E-25 0.7150E-25 O2,gas 0.9164E-44 1.0000 0.7208E-42 0.7208E-42 SO2,gas 0.2290E-12 1.0000 0.1801E-10 0.1801E-10 HF,gas 0.2865E-07 1.0000 0.2253E-05 0.2253E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 196 argentite -23.33 -23.33 0.00 0.000 0.72391E-11 225 topaz -19.31 -19.31 0.00 0.000 -0.14478E-10 260 galena -10.52 -10.52 0.00 0.000 -0.36196E-11 272 sphalerite -9.76 -9.76 0.00 0.000 0.00000E+00 205 bornite -75.52 -75.10 0.42 0.032 -0.86362E+03 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 -0.02 -1.72 -1.716 0.34966E+04 0.983 2 CO2,gas -6.26 -7.20 -0.93 -0.311 0.19027E+04 1.765 3 CH4,gas 5.41 -3.14 -8.55 -2.137 0.17418E+05 -5.849 4 H2,gas 7.65 1.00 -6.65 -3.798 0.13543E+05 -3.947 5 H2S,gas -5.55 -11.60 -6.04 -3.022 0.12317E+05 -3.346 6 S2,gas -8.17 -25.20 -17.03 -2.620 0.34706E+05 -14.333 7 CO,gas 2.34 -6.17 -8.52 -2.620 0.17351E+05 -5.816 8 SO3,gas 12.18 -15.67 -27.84 -6.961 0.56737E+05 -25.146 9 O2,gas 42.80 -2.05 -44.84 -29.894 0.91370E+05 -42.142 10 SO2,gas -1.20 -14.65 -13.44 -3.585 0.27393E+05 -10.744 11 HF,gas -0.20 -8.55 -8.35 -4.173 0.17006E+05 -5.647 12 HCl,gas 1.38 -5.54 -6.93 -3.464 0.14115E+05 -6.927 13 acmite 6.42 2.66 -3.76 -0.391 0.76713E+04 17 albite-high -0.94 -2.55 -1.61 -0.124 0.32879E+04 18 albite -1.70 -2.55 -0.85 -0.065 0.17347E+04 22 analcite 1.47 0.02 -1.44 -0.160 0.29392E+04 23 andalusite 0.25 -2.24 -2.48 -0.248 0.50587E+04 26 anhydrite -6.29 -9.28 -2.99 -1.496 0.60975E+04 27 ankerite -3.49 -4.70 -1.21 -0.201 0.24604E+04 31 anorthite 6.44 1.55 -4.88 -0.376 0.99528E+04 34 aragonite 0.19 -0.81 -1.00 -0.332 0.20302E+04 35 brucite 10.23 5.30 -4.93 -0.986 0.10042E+05 36 calcite 0.05 -0.81 -0.86 -0.286 0.17469E+04 37 carnegieite-low 6.14 2.64 -3.50 -0.501 0.71416E+04 38 carnegieite-high 6.91 2.64 -4.27 -0.610 0.87045E+04 39 carpholite-Mg 3.41 0.45 -2.96 -0.198 0.60405E+04 40 carpholite-Fe 1.81 -1.56 -3.37 -0.225 0.68660E+04 41 celadonite 3.19 -1.29 -4.48 -0.263 0.91235E+04 49 chloritoid-Mg 6.89 3.06 -3.83 -0.255 0.78048E+04 50 chloritoid-Fe 3.57 1.06 -2.52 -0.168 0.51306E+04 51 chloritoid-Mn 5.77 1.97 -3.80 -0.253 0.77364E+04 53 coesite -1.94 -2.60 -0.65 -0.217 0.13261E+04 58 corundum 3.02 0.36 -2.66 -0.242 0.54234E+04 60 cristobalite -2.13 -2.60 -0.47 -0.155 0.94751E+03 63 cymrite-K 0.26 -4.01 -4.27 -0.356 0.87005E+04 65 diaspore 0.66 0.17 -0.49 -0.082 0.99988E+03 66 diamond -2.34 -5.15 -2.82 -0.804 0.57369E+04 69 dolomite,ordered -1.20 -2.69 -1.49 -0.249 0.30431E+04 83 gibbsite 1.89 0.15 -1.74 -0.248 0.35378E+04 86 goethite 4.89 2.79 -2.10 -0.454 0.42826E+04 87 graphite -2.73 -5.15 -2.42 -0.691 0.49301E+04 90 halite 1.46 -0.48 -1.94 -0.968 0.39466E+04 91 hematite 9.23 5.60 -3.63 -0.441 0.74061E+04 92 heulandite -8.13 -11.54 -3.41 -0.155 0.69411E+04 96 jadeite 2.28 0.04 -2.24 -0.224 0.45694E+04 98 kalsilite 5.03 1.20 -3.83 -0.547 0.78091E+04 99 kaolinite -4.26 -4.87 -0.61 -0.056 0.12468E+04 100 kyanite 0.18 -2.24 -2.42 -0.242 0.49254E+04 102 laumontite -0.68 -3.71 -3.03 -0.202 0.61701E+04 103 lawsonite 4.79 1.52 -3.27 -0.218 0.66645E+04 104 leucite 2.03 -1.40 -3.43 -0.343 0.69899E+04 107 magnesite -0.46 -1.88 -1.42 -0.474 0.28989E+04 114 margarite 6.80 1.89 -4.90 -0.196 0.99907E+04 117 microcline -3.26 -3.99 -0.73 -0.056 0.14904E+04 120 mullite-Si 2.06 -2.24 -4.30 -0.430 0.87518E+04 121 muscovite -2.64 -3.65 -1.01 -0.060 0.20666E+04 122 paragonite -1.38 -2.21 -0.83 -0.049 0.16895E+04 123 nepheline 5.54 2.64 -2.90 -0.414 0.59064E+04 143 pyrite -19.52 -20.87 -1.35 -0.318 0.27499E+04 144 pyrrhotite -4.74 -8.27 -3.53 -1.175 0.71848E+04 145 pyrrhotiteFe0.875 -6.16 -8.81 -2.65 -0.974 0.53949E+04 146 pyroxmangite 5.89 1.63 -4.26 -0.852 0.86835E+04 147 pyrophyllite -8.55 -10.04 -1.49 -0.093 0.30328E+04 148 quartz -2.46 -2.60 -0.13 -0.045 0.27333E+03 153 rhodochrosite -1.56 -2.97 -1.41 -0.469 0.28699E+04 154 rhodonite 5.92 1.63 -4.29 -0.858 0.87457E+04 155 sanidine -2.24 -3.99 -1.75 -0.134 0.35592E+04 157 siderite -3.23 -3.89 -0.66 -0.219 0.13371E+04 158 sillimanite 0.43 -2.24 -2.67 -0.267 0.54377E+04 165 stilbite -8.31 -11.55 -3.25 -0.155 0.66171E+04 171 sulfur -8.55 -12.60 -4.05 -1.246 0.82544E+04 172 sylvite 1.44 -1.92 -3.36 -1.679 0.68408E+04 180 topaz-H 0.45 -2.25 -2.71 -0.246 0.55151E+04 181 tridymite -2.17 -2.60 -0.43 -0.143 0.87681E+03 184 troilite-low -4.82 -8.27 -3.45 -1.149 0.70231E+04 190 wairakite -0.27 -3.67 -3.41 -0.201 0.69457E+04 192 wollastonite 8.67 3.79 -4.88 -0.976 0.99391E+04 197 arsenic -5.84 -10.09 -4.25 -1.096 0.86558E+04 199 arsenopyrite -13.65 -18.36 -4.70 -0.836 0.95812E+04 200 beidellite-Ca -5.49 -8.07 -2.59 -0.160 0.52681E+04 201 beidellite-H -5.99 -9.13 -3.14 -0.200 0.63993E+04 202 beidellite-K -5.10 -7.93 -2.83 -0.173 0.57642E+04 203 beidellite-Mg -5.72 -8.25 -2.53 -0.157 0.51603E+04 204 beidellite-Na -5.01 -7.46 -2.45 -0.150 0.49977E+04 207 chalcedony -2.30 -2.60 -0.29 -0.097 0.59319E+03 208 chalcocite -23.21 -24.21 -1.00 -0.250 0.20403E+04 210 covellite -16.95 -18.41 -1.46 -0.555 0.29706E+04 211 dawsonite 0.28 -1.98 -2.26 -0.283 0.46128E+04 213 montmorillonite-Ca -4.91 -7.29 -2.39 -0.148 0.48658E+04 214 montmorillonite-K -4.62 -7.15 -2.54 -0.155 0.51701E+04 215 montmorillonite-Mg -5.13 -7.47 -2.34 -0.145 0.47612E+04 216 montmorillonite-Na -4.45 -6.68 -2.23 -0.136 0.45419E+04 217 nontronite-Ca 1.29 -2.83 -4.12 -0.268 0.84044E+04 218 nontronite-H 0.78 -3.89 -4.68 -0.313 0.95278E+04 219 nontronite-K 1.67 -2.70 -4.37 -0.280 0.89002E+04 220 nontronite-Mg 1.09 -3.01 -4.10 -0.266 0.83579E+04 221 nontronite-Na 1.77 -2.22 -3.99 -0.256 0.81361E+04 229 gypsum -5.45 -9.32 -3.87 -0.967 0.78793E+04 245 acanthite -23.16 -23.33 -0.17 -0.042 0.34294E+03 251 barite -9.50 -12.11 -2.62 -1.308 0.53315E+04 252 boehmite 1.82 0.17 -1.65 -0.275 0.33569E+04 253 cerussite -2.77 -6.14 -3.38 -1.125 0.68771E+04 254 chalcopyrite -25.37 -26.68 -1.30 -0.242 0.26531E+04 256 copper,native -1.88 -5.81 -3.93 -1.366 0.80007E+04 257 dolomite,disordered -0.71 -2.69 -1.98 -0.331 0.40438E+04 258 ferrous-oxide 7.50 3.31 -4.19 -1.049 0.85468E+04 259 fluorite -10.07 -10.69 -0.62 -0.208 0.12720E+04 261 gold,native -14.53 -15.99 -1.46 -0.509 0.29839E+04 262 silver,native -4.75 -5.36 -0.61 -0.214 0.12526E+04 269 silica-amorphous -1.74 -2.60 -0.85 -0.284 0.17344E+04 270 smithsonite -1.57 -5.38 -3.81 -1.270 0.77634E+04 273 wurtzite -8.22 -9.76 -1.53 -0.511 0.31257E+04 274 zincite 6.28 1.82 -4.45 -1.114 0.90776E+04 275 an20ab80 -0.29 -1.73 -1.44 -0.111 0.29362E+04 276 an25ab75 0.09 -1.53 -1.62 -0.124 0.32915E+04 277 an30ab70 0.47 -1.32 -1.80 -0.138 0.36591E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 70 Temperature = 172.15 C Pressure = 500.00 bar Mixer fraction = 0.2000000 Water: Moles liquid = 0.6674E+02 kg liquid = 0.1202E+01 Moles total = 0.6642E+02 kg total = 0.1197E+01 Activity = 0.9584 Stoichiometric ionic strength = .1452654E+01 Osmotic coef. = 0.9174 True ionic strength = .1090202E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95020E-05 -5.0222 0.49419E-05 -5.3061 0.52009E+00 -0.2839 2 H2O 0.95840E+00 -0.0185 0.95840E+00 -0.0185 3 Cl- 0.10653E+01 0.0275 0.57943E+00 -0.2370 0.54390E+00 -0.2645 4 SO4-- 0.14254E-03 -3.8461 0.83979E-05 -5.0758 0.58918E-01 -1.2298 5 HCO3- 0.22067E-01 -1.6562 0.12353E-01 -1.9082 0.55977E+00 -0.2520 6 HS- 0.93577E-06 -6.0288 0.51053E-06 -6.2920 0.54558E+00 -0.2631 7 H4SiO4 0.23305E-02 -2.6325 0.23305E-02 -2.6325 0.10000E+01 0.0000 8 Al+++ 0.13893E-12 -12.8572 0.19463E-15 -15.7108 0.14009E-02 -2.8536 9 Ca++ 0.11712E-02 -2.9314 0.61837E-04 -4.2087 0.52799E-01 -1.2774 10 Mg++ 0.10801E-03 -3.9665 0.52684E-05 -5.2783 0.48777E-01 -1.3118 11 Fe++ 0.10415E-05 -5.9824 0.51805E-07 -7.2856 0.49743E-01 -1.3033 12 K+ 0.36973E-01 -1.4321 0.20824E-01 -1.6814 0.56321E+00 -0.2493 13 Na+ 0.10485E+01 0.0206 0.56991E+00 -0.2442 0.54352E+00 -0.2648 14 Mn++ 0.84651E-05 -5.0724 0.42724E-06 -6.3693 0.50471E-01 -1.2970 15 Zn++ 0.33913E-07 -7.4696 0.16869E-08 -8.7729 0.49743E-01 -1.3033 16 Cu+ 0.36979E-11 -11.4320 0.20078E-11 -11.6973 0.54296E+00 -0.2652 17 Pb++ 0.52260E-08 -8.2818 0.28957E-09 -9.5383 0.55408E-01 -1.2564 18 Ag+ 0.12034E-10 -10.9196 0.67328E-11 -11.1718 0.55948E+00 -0.2522 19 Au+ 0.28217E-21 -21.5495 0.15952E-21 -21.7972 0.56533E+00 -0.2477 20 Ba++ 0.16031E-05 -5.7950 0.91646E-07 -7.0379 0.57166E-01 -1.2429 21 F- 0.11142E-02 -2.9530 0.57508E-03 -3.2403 0.51612E+00 -0.2872 22 H2AsO3- 0.66724E-06 -6.1757 0.45509E-06 -6.3419 0.68205E+00 -0.1662 24 HSiO3- 0.19626E-05 -5.7072 0.10675E-05 -5.9716 0.54390E+00 -0.2645 25 Ca(HSiO3)+ 0.85599E-08 -8.0675 0.48391E-08 -8.3152 0.56533E+00 -0.2477 26 Mg(HSiO3)+ 0.67542E-09 -9.1704 0.38183E-09 -9.4181 0.56533E+00 -0.2477 27 NaHSiO3,aq 0.50369E-05 -5.2978 0.50369E-05 -5.2978 0.10000E+01 0.0000 31 AgCl,aq 0.21339E-08 -8.6708 0.21339E-08 -8.6708 0.10000E+01 0.0000 32 AgCl2- 0.91642E-07 -7.0379 0.49844E-07 -7.3024 0.54390E+00 -0.2645 33 AgCl3-2 0.55151E-07 -7.2584 0.31452E-08 -8.5024 0.57028E-01 -1.2439 34 AgCl4-3 0.75669E-08 -8.1211 0.10546E-10 -10.9769 0.13937E-02 -2.8558 38 Ag(HS),aq 0.73311E-08 -8.1348 0.73311E-08 -8.1348 0.10000E+01 0.0000 40 AlO+ 0.18629E-09 -9.7298 0.10532E-09 -9.9775 0.56533E+00 -0.2477 42 HAlO2,aq 0.26395E-07 -7.5785 0.26395E-07 -7.5785 0.10000E+01 0.0000 43 AlO2- 0.14281E-06 -6.8453 0.74299E-07 -7.1290 0.52028E+00 -0.2838 44 AsO2- 0.14184E-06 -6.8482 0.77145E-07 -7.1127 0.54390E+00 -0.2645 45 HAsO2,aq 0.30768E-04 -4.5119 0.30768E-04 -4.5119 0.10000E+01 0.0000 46 H3AsO3,aq 0.76241E-04 -4.1178 0.76241E-04 -4.1178 0.10000E+01 0.0000 48 H2AsO4- 0.67299E-10 -10.1720 0.36604E-10 -10.4365 0.54390E+00 -0.2645 49 HAsO4-2 0.12342E-10 -10.9086 0.70386E-12 -12.1525 0.57028E-01 -1.2439 62 BaCO3,aq 0.33691E-09 -9.4725 0.33691E-09 -9.4725 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.10614E-05 -5.9741 0.61046E-06 -6.2143 0.57517E+00 -0.2402 64 BaCl+ 0.71459E-06 -6.1459 0.40398E-06 -6.3936 0.56533E+00 -0.2477 65 BaF+ 0.82529E-09 -9.0834 0.46656E-09 -9.3311 0.56533E+00 -0.2477 66 CH4,aq 0.81675E-09 -9.0879 0.74115E-09 -9.1301 0.90745E+00 -0.0422 71 CO,aq 0.10767E-08 -8.9679 0.10767E-08 -8.9679 0.10000E+01 0.0000 72 CO2,aq 0.26881E+00 -0.5705 0.24393E+00 -0.6127 0.90745E+00 -0.0422 73 CO3-2 0.39655E-05 -5.4017 0.22615E-06 -6.6456 0.57028E-01 -1.2439 74 CaCO3,aq 0.90784E-06 -6.0420 0.90784E-06 -6.0420 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.12912E-03 -3.8890 0.72993E-04 -4.1367 0.56533E+00 -0.2477 76 CaCl+ 0.41274E-03 -3.3843 0.23333E-03 -3.6320 0.56533E+00 -0.2477 77 CaCl2,aq 0.32506E-04 -4.4880 0.32506E-04 -4.4880 0.10000E+01 0.0000 78 CaF+ 0.38573E-05 -5.4137 0.21806E-05 -5.6614 0.56533E+00 -0.2477 79 CaOH+ 0.68347E-07 -7.1653 0.38639E-07 -7.4130 0.56533E+00 -0.2477 80 CaSO4,aq 0.47463E-06 -6.3236 0.47463E-06 -6.3236 0.10000E+01 0.0000 81 HCl,aq 0.13255E-05 -5.8776 0.13255E-05 -5.8776 0.10000E+01 0.0000 90 CuCl,aq 0.53871E-08 -8.2686 0.53871E-08 -8.2686 0.10000E+01 0.0000 91 CuCl2- 0.92769E-07 -7.0326 0.50457E-07 -7.2971 0.54390E+00 -0.2645 92 CuCl3-2 0.18463E-07 -7.7337 0.10529E-08 -8.9776 0.57028E-01 -1.2439 98 HF,aq 0.73747E-04 -4.1323 0.73747E-04 -4.1323 0.10000E+01 0.0000 99 HF2- 0.22376E-07 -7.6502 0.12170E-07 -7.9147 0.54390E+00 -0.2645 101 FeCl+ 0.26919E-06 -6.5699 0.15218E-06 -6.8176 0.56533E+00 -0.2477 102 FeCl2,aq 0.73732E-09 -9.1323 0.73732E-09 -9.1323 0.10000E+01 0.0000 104 FeF+ 0.71447E-08 -8.1460 0.40391E-08 -8.3937 0.56533E+00 -0.2477 106 FeO,aq 0.28381E-10 -10.5470 0.28381E-10 -10.5470 0.10000E+01 0.0000 107 FeOH+ 0.98555E-08 -8.0063 0.55716E-08 -8.2540 0.56533E+00 -0.2477 112 HFeO2,aq 0.25805E-10 -10.5883 0.25805E-10 -10.5883 0.10000E+01 0.0000 113 H2,aq 0.10426E-06 -6.9819 0.94608E-07 -7.0241 0.90745E+00 -0.0422 114 KCl,aq 0.81809E-03 -3.0872 0.81809E-03 -3.0872 0.10000E+01 0.0000 115 KHSO4,aq 0.12187E-09 -9.9141 0.12187E-09 -9.9141 0.10000E+01 0.0000 116 KOH,aq 0.25551E-07 -7.5926 0.25551E-07 -7.5926 0.10000E+01 0.0000 117 KSO4- 0.13350E-04 -4.8745 0.72609E-05 -5.1390 0.54390E+00 -0.2645 118 MgCO3,aq 0.11895E-07 -7.9246 0.11895E-07 -7.9246 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.10821E-04 -4.9657 0.61172E-05 -5.2134 0.56533E+00 -0.2477 120 MgCl+ 0.22969E-04 -4.6389 0.12985E-04 -4.8866 0.56533E+00 -0.2477 121 MgF+ 0.10262E-05 -5.9888 0.58013E-06 -6.2365 0.56533E+00 -0.2477 122 MgOH+ 0.21796E-07 -7.6616 0.12322E-07 -7.9093 0.56533E+00 -0.2477 124 MnF+ 0.22465E-07 -7.6485 0.12700E-07 -7.8962 0.56533E+00 -0.2477 126 MnOH+ 0.10151E-07 -7.9935 0.57386E-08 -8.2412 0.56533E+00 -0.2477 131 MnCl+ 0.20172E-04 -4.6952 0.11404E-04 -4.9429 0.56533E+00 -0.2477 132 MnSO4,aq 0.36838E-08 -8.4337 0.36838E-08 -8.4337 0.10000E+01 0.0000 133 NaCl,aq 0.21860E+00 -0.6604 0.21860E+00 -0.6604 0.10000E+01 0.0000 134 NaF,aq 0.16119E-03 -3.7927 0.16119E-03 -3.7927 0.10000E+01 0.0000 135 NaOH,aq 0.54126E-06 -6.2666 0.54126E-06 -6.2666 0.10000E+01 0.0000 137 OH- 0.20137E-05 -5.6960 0.10477E-05 -5.9798 0.52028E+00 -0.2838 140 PbCl+ 0.53776E-07 -7.2694 0.30401E-07 -7.5171 0.56533E+00 -0.2477 141 PbCl2,aq 0.20114E-06 -6.6965 0.20114E-06 -6.6965 0.10000E+01 0.0000 142 PbCl3- 0.13655E-06 -6.8647 0.74269E-07 -7.1292 0.54390E+00 -0.2645 143 PbCl4-2 0.16561E-06 -6.7809 0.94445E-08 -8.0248 0.57028E-01 -1.2439 144 PbF+ 0.84150E-10 -10.0749 0.47572E-10 -10.3226 0.56533E+00 -0.2477 146 PbO,aq 0.14874E-10 -10.8276 0.14874E-10 -10.8276 0.10000E+01 0.0000 148 Pb(HS)2,aq 0.11524E-09 -9.9384 0.11524E-09 -9.9384 0.10000E+01 0.0000 150 H2S,aq 0.87681E-05 -5.0571 0.79566E-05 -5.0993 0.90745E+00 -0.0422 158 HSO3- 0.12309E-09 -9.9098 0.66948E-10 -10.1743 0.54390E+00 -0.2645 159 HSO4- 0.54796E-06 -6.2612 0.31446E-06 -6.5024 0.57387E+00 -0.2412 161 S2O3-2 0.17165E-10 -10.7654 0.97886E-12 -12.0093 0.57028E-01 -1.2439 173 ZnCl+ 0.39172E-05 -5.4070 0.22145E-05 -5.6547 0.56533E+00 -0.2477 174 ZnCl2,aq 0.91353E-06 -6.0393 0.91353E-06 -6.0393 0.10000E+01 0.0000 175 ZnCl3- 0.11649E-06 -6.9337 0.63360E-07 -7.1982 0.54390E+00 -0.2645 176 ZnF+ 0.15372E-09 -9.8133 0.86902E-10 -10.0610 0.56533E+00 -0.2477 177 ZnO,aq 0.13273E-09 -9.8770 0.13273E-09 -9.8770 0.10000E+01 0.0000 178 ZnOH+ 0.15375E-06 -6.8132 0.86922E-07 -7.0609 0.56533E+00 -0.2477 Charge balance for all species = -.1078E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9502044E-05 0.2689983E+00 0.2488112E+03 0.0000 2 H2O 0.1000000E+01 0.5523940E+02 0.9132214E+06 0.0000 3 Cl- 0.1065324E+01 0.1285270E+01 0.4181508E+05 5.0691 4 SO4-- 0.1425368E-03 0.1568858E-03 0.1382990E+02 5.5364 5 HCO3- 0.2206745E-01 0.2910262E+00 0.1629558E+05 3.3979 6 HS- 0.9357718E-06 0.9738655E-05 0.2955596E+00 -0.9859 7 H4SiO4 0.2330528E-02 0.2337537E-02 0.2061755E+03 -2.6325 8 Al+++ 0.1389262E-12 0.1693951E-06 0.4194232E-02 0.2075 9 Ca++ 0.1171179E-02 0.1750861E-02 0.6439368E+02 6.4035 10 Mg++ 0.1080086E-03 0.1428587E-03 0.3187228E+01 5.3339 11 Fe++ 0.1041460E-05 0.1328449E-05 0.6808171E-01 3.3266 12 K+ 0.3697322E-01 0.3780469E-01 0.1356533E+04 3.6247 13 Na+ 0.1048541E+01 0.1267304E+01 0.2673632E+05 5.0619 14 Mn++ 0.8465060E-05 0.2867374E-04 0.1445582E+01 4.2429 15 Zn++ 0.3391283E-07 0.5135156E-05 0.3080475E+00 1.8393 16 Cu+ 0.3697927E-11 0.1166224E-06 0.6800094E-02 -6.3912 17 Pb++ 0.5226040E-08 0.5625152E-06 0.1069519E+00 1.0740 18 Ag+ 0.1203415E-10 0.1638404E-06 0.1621837E-01 -5.8657 19 Au+ 0.2821669E-21 0.2587306E-11 0.4676565E-06 -16.4911 20 Ba++ 0.1603143E-05 0.3380258E-05 0.4260224E+00 3.5743 21 F- 0.1114230E-02 0.1354129E-02 0.2360770E+02 2.0658 22 H2AsO3- 0.6672377E-06 0.1078183E-03 0.1236131E+02 -1.0358 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234419E+00 -.6721827E-05 0.0000000E+00 2 H2O 0.6641950E+02 0.6641950E+02 -.2993107E-08 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886385E-03 0.7482766E-09 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1170970E-04 0.2320614E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810639E-02 0.1101800E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.2036795E-06 0.2203599E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1597319E-05 0.5986213E-08 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.6174479E-05 0.1293698E-05 0.0000000E+00 16 Cu+ 0.1701571E-06 0.1402261E-06 0.2993107E-07 0.0000000E+00 17 Pb++ 0.1565021E-05 0.6763646E-06 0.8886560E-06 0.0000000E+00 18 Ag+ 0.4271281E-06 0.1970006E-06 0.2301275E-06 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1628196E-02 0.2203599E-05 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.8470E-21 Mass of aqueous solution: 0.131027E+04 g Temperature = 172.15 C Pressure = 500.00 bar Mixer frac. = 0.2000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) argentite 0.1151E-06 -6.939 0.2851E-04 -4.545 4.976 0.4004E-05 topaz 0.1102E-05 -5.958 0.2028E-03 -3.693 35.39 0.5677E-04 galena 0.8887E-06 -6.051 0.2126E-03 -3.672 37.11 0.2798E-04 sphalerite 0.1294E-05 -5.888 0.1260E-03 -3.899 22.00 0.3083E-04 bornite 0.5986E-08 -8.223 0.3004E-05 -5.522 0.5243 0.5910E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity argentite 0.1000E+01 0.1000E+01 1.0000 0.000 topaz 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.2000000 Solid products produced: Mass = 0.000573 g Volume = 0.000120 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.300 AFFINITY: 0.3912E+03 GOLD Q/K: 0.0344 SILVER Q/K: 0.2429 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 172.1521 deg.C Sat. pressure: 78.6515 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1790E+00 0.6828 0.9615E+01 0.1408E+02 CO2,gas 0.8209E+00 0.9019 0.5824E+02 0.6457E+02 CH4,gas 0.1638E-07 1.0965 0.1413E-05 0.1288E-05 H2,gas 0.1385E-05 1.0358 0.1128E-03 0.1089E-03 H2S,gas 0.6834E-05 0.8379 0.4503E-03 0.5375E-03 S2,gas 0.5890E-16 1.0000 0.4632E-14 0.4632E-14 CO,gas 0.1940E-07 1.0000 0.1526E-05 0.1526E-05 SO3,gas 0.9091E-27 1.0000 0.7150E-25 0.7150E-25 O2,gas 0.9170E-44 1.0000 0.7212E-42 0.7212E-42 SO2,gas 0.2289E-12 1.0000 0.1800E-10 0.1800E-10 HF,gas 0.2865E-07 1.0000 0.2253E-05 0.2253E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 196 argentite -23.33 -23.33 0.00 0.000 0.72391E-11 205 bornite -75.52 -75.52 0.00 0.000 0.00000E+00 225 topaz -19.31 -19.31 0.00 0.000 0.00000E+00 260 galena -10.52 -10.52 0.00 0.000 0.10859E-10 272 sphalerite -9.76 -9.76 0.00 0.000 0.72391E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 -0.02 -1.72 -1.716 0.34966E+04 0.983 2 CO2,gas -6.26 -7.20 -0.93 -0.311 0.19027E+04 1.765 3 CH4,gas 5.41 -3.14 -8.55 -2.137 0.17420E+05 -5.850 4 H2,gas 7.65 1.00 -6.65 -3.798 0.13543E+05 -3.948 5 H2S,gas -5.55 -11.60 -6.05 -3.023 0.12318E+05 -3.346 6 S2,gas -8.17 -25.20 -17.03 -2.620 0.34707E+05 -14.334 7 CO,gas 2.34 -6.17 -8.52 -2.620 0.17351E+05 -5.816 8 SO3,gas 12.18 -15.67 -27.84 -6.961 0.56737E+05 -25.146 9 O2,gas 42.80 -2.04 -44.84 -29.894 0.91369E+05 -42.142 10 SO2,gas -1.20 -14.65 -13.44 -3.585 0.27393E+05 -10.745 11 HF,gas -0.20 -8.55 -8.35 -4.173 0.17006E+05 -5.647 12 HCl,gas 1.38 -5.54 -6.93 -3.464 0.14115E+05 -6.927 13 acmite 6.42 2.66 -3.77 -0.391 0.76745E+04 17 albite-high -0.94 -2.55 -1.61 -0.124 0.32879E+04 18 albite -1.70 -2.55 -0.85 -0.065 0.17347E+04 22 analcite 1.47 0.02 -1.44 -0.160 0.29392E+04 23 andalusite 0.25 -2.24 -2.48 -0.248 0.50587E+04 26 anhydrite -6.29 -9.28 -2.99 -1.496 0.60975E+04 27 ankerite -3.49 -4.70 -1.21 -0.202 0.24637E+04 31 anorthite 6.44 1.55 -4.88 -0.376 0.99528E+04 34 aragonite 0.19 -0.81 -1.00 -0.332 0.20302E+04 35 brucite 10.23 5.30 -4.93 -0.986 0.10042E+05 36 calcite 0.05 -0.81 -0.86 -0.286 0.17469E+04 37 carnegieite-low 6.14 2.64 -3.50 -0.501 0.71416E+04 38 carnegieite-high 6.91 2.64 -4.27 -0.610 0.87045E+04 39 carpholite-Mg 3.41 0.45 -2.96 -0.198 0.60405E+04 40 carpholite-Fe 1.81 -1.56 -3.37 -0.225 0.68693E+04 41 celadonite 3.19 -1.29 -4.48 -0.263 0.91235E+04 49 chloritoid-Mg 6.89 3.06 -3.83 -0.255 0.78048E+04 50 chloritoid-Fe 3.57 1.05 -2.52 -0.168 0.51339E+04 51 chloritoid-Mn 5.77 1.97 -3.80 -0.253 0.77364E+04 53 coesite -1.94 -2.60 -0.65 -0.217 0.13261E+04 58 corundum 3.02 0.36 -2.66 -0.242 0.54234E+04 60 cristobalite -2.13 -2.60 -0.47 -0.155 0.94751E+03 63 cymrite-K 0.26 -4.01 -4.27 -0.356 0.87005E+04 65 diaspore 0.66 0.17 -0.49 -0.082 0.99988E+03 66 diamond -2.34 -5.15 -2.82 -0.805 0.57375E+04 69 dolomite,ordered -1.20 -2.69 -1.49 -0.249 0.30431E+04 83 gibbsite 1.89 0.15 -1.74 -0.248 0.35378E+04 86 goethite 4.89 2.79 -2.10 -0.455 0.42858E+04 87 graphite -2.73 -5.15 -2.42 -0.691 0.49306E+04 90 halite 1.46 -0.48 -1.94 -0.968 0.39466E+04 91 hematite 9.23 5.59 -3.64 -0.441 0.74125E+04 92 heulandite -8.13 -11.54 -3.41 -0.155 0.69411E+04 96 jadeite 2.28 0.04 -2.24 -0.224 0.45694E+04 98 kalsilite 5.03 1.20 -3.83 -0.547 0.78091E+04 99 kaolinite -4.26 -4.87 -0.61 -0.056 0.12468E+04 100 kyanite 0.18 -2.24 -2.42 -0.242 0.49254E+04 102 laumontite -0.68 -3.71 -3.03 -0.202 0.61701E+04 103 lawsonite 4.79 1.52 -3.27 -0.218 0.66646E+04 104 leucite 2.03 -1.40 -3.43 -0.343 0.69899E+04 107 magnesite -0.46 -1.88 -1.42 -0.474 0.28989E+04 114 margarite 6.80 1.89 -4.90 -0.196 0.99907E+04 117 microcline -3.26 -3.99 -0.73 -0.056 0.14904E+04 120 mullite-Si 2.06 -2.24 -4.30 -0.430 0.87518E+04 121 muscovite -2.64 -3.65 -1.01 -0.060 0.20666E+04 122 paragonite -1.38 -2.21 -0.83 -0.049 0.16895E+04 123 nepheline 5.54 2.64 -2.90 -0.414 0.59064E+04 143 pyrite -19.52 -20.87 -1.35 -0.318 0.27551E+04 144 pyrrhotite -4.74 -8.27 -3.53 -1.176 0.71893E+04 145 pyrrhotiteFe0.875 -6.16 -8.81 -2.65 -0.974 0.53988E+04 146 pyroxmangite 5.89 1.63 -4.26 -0.852 0.86835E+04 147 pyrophyllite -8.55 -10.04 -1.49 -0.093 0.30328E+04 148 quartz -2.46 -2.60 -0.13 -0.045 0.27333E+03 153 rhodochrosite -1.56 -2.97 -1.41 -0.469 0.28699E+04 154 rhodonite 5.92 1.63 -4.29 -0.858 0.87457E+04 155 sanidine -2.24 -3.99 -1.75 -0.134 0.35592E+04 157 siderite -3.23 -3.89 -0.66 -0.219 0.13404E+04 158 sillimanite 0.43 -2.24 -2.67 -0.267 0.54377E+04 165 stilbite -8.31 -11.55 -3.25 -0.155 0.66171E+04 171 sulfur -8.55 -12.60 -4.05 -1.247 0.82552E+04 172 sylvite 1.44 -1.92 -3.36 -1.679 0.68408E+04 180 topaz-H 0.45 -2.25 -2.71 -0.246 0.55151E+04 181 tridymite -2.17 -2.60 -0.43 -0.143 0.87681E+03 184 troilite-low -4.82 -8.27 -3.45 -1.150 0.70276E+04 190 wairakite -0.27 -3.67 -3.41 -0.201 0.69457E+04 192 wollastonite 8.67 3.79 -4.88 -0.976 0.99391E+04 197 arsenic -5.84 -10.09 -4.25 -1.096 0.86562E+04 199 arsenopyrite -13.65 -18.36 -4.70 -0.836 0.95861E+04 200 beidellite-Ca -5.49 -8.07 -2.59 -0.160 0.52681E+04 201 beidellite-H -5.99 -9.13 -3.14 -0.200 0.63993E+04 202 beidellite-K -5.10 -7.93 -2.83 -0.173 0.57642E+04 203 beidellite-Mg -5.72 -8.25 -2.53 -0.157 0.51603E+04 204 beidellite-Na -5.01 -7.46 -2.45 -0.150 0.49977E+04 207 chalcedony -2.30 -2.60 -0.29 -0.097 0.59319E+03 208 chalcocite -23.21 -24.38 -1.17 -0.292 0.23838E+04 210 covellite -16.95 -18.49 -1.54 -0.588 0.31428E+04 211 dawsonite 0.28 -1.98 -2.26 -0.283 0.46128E+04 213 montmorillonite-Ca -4.91 -7.29 -2.39 -0.148 0.48658E+04 214 montmorillonite-K -4.62 -7.15 -2.54 -0.155 0.51701E+04 215 montmorillonite-Mg -5.13 -7.47 -2.34 -0.145 0.47612E+04 216 montmorillonite-Na -4.45 -6.68 -2.23 -0.136 0.45419E+04 217 nontronite-Ca 1.29 -2.84 -4.13 -0.268 0.84107E+04 218 nontronite-H 0.78 -3.89 -4.68 -0.314 0.95341E+04 219 nontronite-K 1.67 -2.70 -4.37 -0.281 0.89065E+04 220 nontronite-Mg 1.09 -3.01 -4.10 -0.266 0.83643E+04 221 nontronite-Na 1.77 -2.22 -4.00 -0.256 0.81425E+04 229 gypsum -5.45 -9.32 -3.87 -0.967 0.78793E+04 245 acanthite -23.16 -23.33 -0.17 -0.042 0.34294E+03 251 barite -9.50 -12.11 -2.62 -1.308 0.53315E+04 252 boehmite 1.82 0.17 -1.65 -0.275 0.33569E+04 253 cerussite -2.77 -6.14 -3.37 -1.125 0.68760E+04 254 chalcopyrite -25.37 -26.76 -1.39 -0.258 0.28297E+04 256 copper,native -1.88 -5.89 -4.01 -1.395 0.81721E+04 257 dolomite,disordered -0.71 -2.69 -1.98 -0.331 0.40438E+04 258 ferrous-oxide 7.50 3.31 -4.20 -1.049 0.85501E+04 259 fluorite -10.07 -10.69 -0.62 -0.208 0.12720E+04 261 gold,native -14.53 -15.99 -1.46 -0.509 0.29829E+04 262 silver,native -4.75 -5.36 -0.61 -0.214 0.12522E+04 269 silica-amorphous -1.74 -2.60 -0.85 -0.284 0.17344E+04 270 smithsonite -1.57 -5.38 -3.81 -1.270 0.77623E+04 273 wurtzite -8.22 -9.76 -1.53 -0.511 0.31257E+04 274 zincite 6.28 1.82 -4.45 -1.114 0.90765E+04 275 an20ab80 -0.29 -1.73 -1.44 -0.111 0.29362E+04 276 an25ab75 0.09 -1.53 -1.62 -0.124 0.32915E+04 277 an30ab70 0.47 -1.32 -1.80 -0.138 0.36591E+04 Calculations done for 172.1521 Deg. C; 500.0000 bar Mixer fraction: 0.2000000 Temperature Stoc.ionic strength Heat per mole Actual solution: 172.152 .14527E+01 3.260 Mixing solution: 25.000 .50000E-10 0.646 Fract. of mixing solution added: 0.050000 BITMOL = 0.2775E+01 OLDMOL = 0.6816E+02 New heat: 3.157 New temperature: 166.510 New mixer fraction: 0.2500000 Resulting temperature: 166.510Deg. C Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1296E-03 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 70 Temperature = 166.51 C Pressure = 500.00 bar Mixer fraction = 0.2500000 Water: Moles liquid = 0.6952E+02 kg liquid = 0.1252E+01 Moles total = 0.6919E+02 kg total = 0.1247E+01 Activity = 0.9599 Stoichiometric ionic strength = .1394387E+01 Osmotic coef. = 0.9202 True ionic strength = .1058416E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10256E-04 -4.9890 0.54445E-05 -5.2640 0.53084E+00 -0.2750 2 H2O 0.95991E+00 -0.0178 0.95991E+00 -0.0178 3 Cl- 0.10345E+01 0.0147 0.57128E+00 -0.2432 0.55223E+00 -0.2579 4 SO4-- 0.13743E-03 -3.8619 0.87597E-05 -5.0575 0.63739E-01 -1.1956 5 HCO3- 0.21197E-01 -1.6737 0.12015E-01 -1.9203 0.56683E+00 -0.2465 6 HS- 0.81327E-06 -6.0898 0.45036E-06 -6.3464 0.55376E+00 -0.2567 7 H4SiO4 0.22381E-02 -2.6501 0.22381E-02 -2.6501 0.10000E+01 0.0000 8 Al+++ 0.19241E-12 -12.7158 0.32600E-15 -15.4868 0.16942E-02 -2.7710 9 Ca++ 0.11513E-02 -2.9388 0.66148E-04 -4.1795 0.57456E-01 -1.2407 10 Mg++ 0.10491E-03 -3.9792 0.56050E-05 -5.2514 0.53427E-01 -1.2722 11 Fe++ 0.10076E-05 -5.9967 0.54803E-07 -7.2612 0.54392E-01 -1.2645 12 K+ 0.35582E-01 -1.4488 0.20272E-01 -1.6931 0.56973E+00 -0.2443 13 Na+ 0.10183E+01 0.0079 0.56154E+00 -0.2506 0.55147E+00 -0.2585 14 Mn++ 0.87614E-05 -5.0574 0.48293E-06 -6.3161 0.55121E-01 -1.2587 15 Zn++ 0.37221E-07 -7.4292 0.20245E-08 -8.6937 0.54392E-01 -1.2645 16 Cu+ 0.29017E-11 -11.5373 0.15987E-11 -11.7962 0.55095E+00 -0.2589 17 Pb++ 0.49719E-08 -8.3035 0.29871E-09 -9.5248 0.60079E-01 -1.2213 18 Ag+ 0.92779E-11 -11.0326 0.52535E-11 -11.2795 0.56625E+00 -0.2470 19 Au+ 0.20170E-21 -21.6953 0.11531E-21 -21.9381 0.57170E+00 -0.2428 20 Ba++ 0.16315E-05 -5.7874 0.10091E-06 -6.9961 0.61849E-01 -1.2087 21 F- 0.10787E-02 -2.9671 0.56887E-03 -3.2450 0.52739E+00 -0.2779 22 H2AsO3- 0.52267E-06 -6.2818 0.35681E-06 -6.4476 0.68268E+00 -0.1658 24 HSiO3- 0.16787E-05 -5.7750 0.92701E-06 -6.0329 0.55223E+00 -0.2579 25 Ca(HSiO3)+ 0.70303E-08 -8.1530 0.40193E-08 -8.3959 0.57170E+00 -0.2428 26 Mg(HSiO3)+ 0.56374E-09 -9.2489 0.32229E-09 -9.4918 0.57170E+00 -0.2428 27 NaHSiO3,aq 0.44006E-05 -5.3565 0.44006E-05 -5.3565 0.10000E+01 0.0000 31 AgCl,aq 0.16375E-08 -8.7858 0.16375E-08 -8.7858 0.10000E+01 0.0000 32 AgCl2- 0.67610E-07 -7.1700 0.37336E-07 -7.4279 0.55223E+00 -0.2579 33 AgCl3-2 0.38146E-07 -7.4186 0.23590E-08 -8.6273 0.61842E-01 -1.2087 34 AgCl4-3 0.46755E-08 -8.3302 0.79399E-11 -11.1002 0.16982E-02 -2.7700 38 Ag(HS),aq 0.68748E-08 -8.1627 0.68748E-08 -8.1627 0.10000E+01 0.0000 40 AlO+ 0.18241E-09 -9.7390 0.10428E-09 -9.9818 0.57170E+00 -0.2428 42 HAlO2,aq 0.21344E-07 -7.6707 0.21344E-07 -7.6707 0.10000E+01 0.0000 43 AlO2- 0.90766E-07 -7.0421 0.48198E-07 -7.3170 0.53102E+00 -0.2749 44 AsO2- 0.12128E-06 -6.9162 0.66974E-07 -7.1741 0.55223E+00 -0.2579 45 HAsO2,aq 0.30461E-04 -4.5163 0.30461E-04 -4.5163 0.10000E+01 0.0000 46 H3AsO3,aq 0.72408E-04 -4.1402 0.72408E-04 -4.1402 0.10000E+01 0.0000 48 H2AsO4- 0.54617E-10 -10.2627 0.30161E-10 -10.5206 0.55223E+00 -0.2579 62 BaCO3,aq 0.29784E-09 -9.5260 0.29784E-09 -9.5260 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.94548E-06 -6.0243 0.54925E-06 -6.2602 0.58092E+00 -0.2359 64 BaCl+ 0.66721E-06 -6.1757 0.38144E-06 -6.4186 0.57170E+00 -0.2428 65 BaF+ 0.78680E-09 -9.1041 0.44981E-09 -9.3470 0.57170E+00 -0.2428 66 CH4,aq 0.66814E-09 -9.1751 0.60507E-09 -9.2182 0.90561E+00 -0.0431 71 CO,aq 0.75850E-09 -9.1200 0.75850E-09 -9.1200 0.10000E+01 0.0000 72 CO2,aq 0.25808E+00 -0.5882 0.23372E+00 -0.6313 0.90561E+00 -0.0431 73 CO3-2 0.34246E-05 -5.4654 0.21179E-06 -6.6741 0.61842E-01 -1.2087 74 CaCO3,aq 0.78108E-06 -6.1073 0.78108E-06 -6.1073 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.11725E-03 -3.9309 0.67034E-04 -4.1737 0.57170E+00 -0.2428 76 CaCl+ 0.37882E-03 -3.4216 0.21657E-03 -3.6644 0.57170E+00 -0.2428 77 CaCl2,aq 0.28748E-04 -4.5414 0.28748E-04 -4.5414 0.10000E+01 0.0000 78 CaF+ 0.35345E-05 -5.4517 0.20207E-05 -5.6945 0.57170E+00 -0.2428 79 CaOH+ 0.50872E-07 -7.2935 0.29084E-07 -7.5364 0.57170E+00 -0.2428 80 CaSO4,aq 0.47539E-06 -6.3230 0.47539E-06 -6.3230 0.10000E+01 0.0000 81 HCl,aq 0.13328E-05 -5.8752 0.13328E-05 -5.8752 0.10000E+01 0.0000 90 CuCl,aq 0.42295E-08 -8.3737 0.42295E-08 -8.3737 0.10000E+01 0.0000 91 CuCl2- 0.70614E-07 -7.1511 0.38995E-07 -7.4090 0.55223E+00 -0.2579 92 CuCl3-2 0.13375E-07 -7.8737 0.82711E-09 -9.0824 0.61842E-01 -1.2087 98 HF,aq 0.70794E-04 -4.1500 0.70794E-04 -4.1500 0.10000E+01 0.0000 99 HF2- 0.21085E-07 -7.6760 0.11644E-07 -7.9339 0.55223E+00 -0.2579 101 FeCl+ 0.24807E-06 -6.6054 0.14182E-06 -6.8483 0.57170E+00 -0.2428 102 FeCl2,aq 0.45351E-09 -9.3434 0.45351E-09 -9.3434 0.10000E+01 0.0000 104 FeF+ 0.67027E-08 -8.1737 0.38320E-08 -8.4166 0.57170E+00 -0.2428 106 FeO,aq 0.16971E-10 -10.7703 0.16971E-10 -10.7703 0.10000E+01 0.0000 107 FeOH+ 0.78495E-08 -8.1052 0.44876E-08 -8.3480 0.57170E+00 -0.2428 112 HFeO2,aq 0.16056E-10 -10.7944 0.16056E-10 -10.7944 0.10000E+01 0.0000 113 H2,aq 0.78302E-07 -7.1062 0.70911E-07 -7.1493 0.90561E+00 -0.0431 114 KCl,aq 0.70098E-03 -3.1543 0.70098E-03 -3.1543 0.10000E+01 0.0000 115 KHSO4,aq 0.97335E-10 -10.0117 0.97335E-10 -10.0117 0.10000E+01 0.0000 116 KOH,aq 0.19452E-07 -7.7110 0.19452E-07 -7.7110 0.10000E+01 0.0000 117 KSO4- 0.12214E-04 -4.9131 0.67451E-05 -5.1710 0.55223E+00 -0.2579 118 MgCO3,aq 0.10510E-07 -7.9784 0.10510E-07 -7.9784 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.98102E-05 -5.0083 0.56085E-05 -5.2512 0.57170E+00 -0.2428 120 MgCl+ 0.21462E-04 -4.6683 0.12270E-04 -4.9112 0.57170E+00 -0.2428 121 MgF+ 0.94617E-06 -6.0240 0.54093E-06 -6.2669 0.57170E+00 -0.2428 122 MgOH+ 0.16470E-07 -7.7833 0.94157E-08 -8.0261 0.57170E+00 -0.2428 124 MnF+ 0.22237E-07 -7.6529 0.12713E-07 -7.8958 0.57170E+00 -0.2428 126 MnOH+ 0.84972E-08 -8.0707 0.48579E-08 -8.3136 0.57170E+00 -0.2428 131 MnCl+ 0.18733E-04 -4.7274 0.10710E-04 -4.9702 0.57170E+00 -0.2428 132 MnSO4,aq 0.38533E-08 -8.4142 0.38533E-08 -8.4142 0.10000E+01 0.0000 133 NaCl,aq 0.19829E+00 -0.7027 0.19829E+00 -0.7027 0.10000E+01 0.0000 134 NaF,aq 0.14602E-03 -3.8356 0.14602E-03 -3.8356 0.10000E+01 0.0000 135 NaOH,aq 0.42452E-06 -6.3721 0.42452E-06 -6.3721 0.10000E+01 0.0000 137 OH- 0.16176E-05 -5.7911 0.85897E-06 -6.0660 0.53102E+00 -0.2749 140 PbCl+ 0.48793E-07 -7.3116 0.27895E-07 -7.5545 0.57170E+00 -0.2428 141 PbCl2,aq 0.17054E-06 -6.7682 0.17054E-06 -6.7682 0.10000E+01 0.0000 142 PbCl3- 0.10911E-06 -6.9622 0.60252E-07 -7.2200 0.55223E+00 -0.2579 143 PbCl4-2 0.12353E-06 -6.9082 0.76395E-08 -8.1169 0.61842E-01 -1.2087 144 PbF+ 0.78677E-10 -10.1042 0.44980E-10 -10.3470 0.57170E+00 -0.2428 148 Pb(HS)2,aq 0.95784E-10 -10.0187 0.95784E-10 -10.0187 0.10000E+01 0.0000 150 H2S,aq 0.81071E-05 -5.0911 0.73419E-05 -5.1342 0.90561E+00 -0.0431 158 HSO3- 0.96708E-10 -10.0145 0.53405E-10 -10.2724 0.55223E+00 -0.2579 159 HSO4- 0.51791E-06 -6.2857 0.30037E-06 -6.5223 0.57996E+00 -0.2366 161 S2O3-2 0.15217E-10 -10.8177 0.94106E-12 -12.0264 0.61842E-01 -1.2087 173 ZnCl+ 0.35801E-05 -5.4461 0.20467E-05 -5.6889 0.57170E+00 -0.2428 174 ZnCl2,aq 0.80236E-06 -6.0956 0.80236E-06 -6.0956 0.10000E+01 0.0000 175 ZnCl3- 0.99598E-07 -7.0017 0.55001E-07 -7.2596 0.55223E+00 -0.2579 176 ZnF+ 0.16287E-09 -9.7882 0.93111E-10 -10.0310 0.57170E+00 -0.2428 177 ZnO,aq 0.93054E-10 -10.0313 0.93054E-10 -10.0313 0.10000E+01 0.0000 178 ZnOH+ 0.12916E-06 -6.8889 0.73843E-07 -7.1317 0.57170E+00 -0.2428 Charge balance for all species = -.1035E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1025626E-04 0.2582595E+00 0.2396660E+03 0.0000 2 H2O 0.1000000E+01 0.5525014E+02 0.9164112E+06 0.0000 3 Cl- 0.1034484E+01 0.1233957E+01 0.4027807E+05 5.0209 4 SO4-- 0.1374307E-03 0.1506218E-03 0.1332150E+02 5.4706 5 HCO3- 0.2119655E-01 0.2794074E+00 0.1569660E+05 3.3438 6 HS- 0.8132694E-06 0.8947891E-05 0.2724562E+00 -1.0824 7 H4SiO4 0.2238102E-02 0.2244189E-02 0.1985948E+03 -2.6501 8 Al+++ 0.1924147E-12 0.1123006E-06 0.2789741E-02 0.3053 9 Ca++ 0.1151287E-02 0.1680960E-02 0.6202674E+02 6.3486 10 Mg++ 0.1049095E-03 0.1371553E-03 0.3070074E+01 5.2767 11 Fe++ 0.1007553E-05 0.1270664E-05 0.6533502E-01 3.2669 12 K+ 0.3558218E-01 0.3629539E-01 0.1306670E+04 3.5709 13 Na+ 0.1018272E+01 0.1216709E+01 0.2575357E+05 5.0134 14 Mn++ 0.8761352E-05 0.2752898E-04 0.1392447E+01 4.2120 15 Zn++ 0.3722134E-07 0.4648690E-05 0.2797851E+00 1.8344 16 Cu+ 0.2901712E-11 0.8822057E-07 0.5160985E-02 -6.5322 17 Pb++ 0.4971920E-08 0.4571222E-06 0.8720004E-01 1.0033 18 Ag+ 0.9277860E-11 0.1189559E-06 0.1181414E-01 -6.0155 19 Au+ 0.2016958E-21 0.2484012E-11 0.4504667E-06 -16.6741 20 Ba++ 0.1631536E-05 0.3245306E-05 0.4103630E+00 3.5320 21 F- 0.1078654E-02 0.1300017E-02 0.2273906E+02 2.0191 22 H2AsO3- 0.5226650E-06 0.1035138E-03 0.1190694E+02 -1.1835 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234425E+00 -.7345363E-05 0.0000000E+00 2 H2O 0.6919492E+02 0.6919492E+02 -.5967025E-08 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886378E-03 0.1491756E-08 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1120628E-04 0.2824029E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810608E-02 0.1133317E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.1406446E-06 0.2266634E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1591371E-05 0.1193405E-07 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.5821990E-05 0.1646186E-05 0.0000000E+00 16 Cu+ 0.1701571E-06 0.1104869E-06 0.5967025E-07 0.0000000E+00 17 Pb++ 0.1565021E-05 0.5724970E-06 0.9925237E-06 0.0000000E+00 18 Ag+ 0.4271281E-06 0.1489796E-06 0.2781485E-06 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1628133E-02 0.2266634E-05 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8470E-21 Mass of aqueous solution: 0.136027E+04 g Temperature = 166.51 C Pressure = 500.00 bar Mixer frac. = 0.2500000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) argentite 0.1391E-06 -6.857 0.3446E-04 -4.463 5.328 0.4840E-05 bornite 0.1193E-07 -7.923 0.5989E-05 -5.223 0.9258 0.1178E-05 topaz 0.1133E-05 -5.946 0.2086E-03 -3.681 32.24 0.5839E-04 galena 0.9925E-06 -6.003 0.2375E-03 -3.624 36.71 0.3125E-04 sphalerite 0.1646E-05 -5.784 0.1604E-03 -3.795 24.79 0.3922E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity argentite 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 topaz 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.2500000 Solid products produced: Mass = 0.000647 g Volume = 0.000135 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.400 AFFINITY: 0.3825E+03 GOLD Q/K: 0.0400 SILVER Q/K: 0.2223 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 166.5096 deg.C Sat. pressure: 74.4921 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1639E+00 0.6928 0.8461E+01 0.1221E+02 CO2,gas 0.8361E+00 0.9015 0.5614E+02 0.6228E+02 CH4,gas 0.1493E-07 1.0884 0.1211E-05 0.1112E-05 H2,gas 0.1150E-05 1.0343 0.8861E-04 0.8567E-04 H2S,gas 0.6652E-05 0.8400 0.4163E-03 0.4955E-03 S2,gas 0.4752E-16 1.0000 0.3540E-14 0.3540E-14 CO,gas 0.1532E-07 1.0000 0.1141E-05 0.1141E-05 SO3,gas 0.4669E-27 1.0000 0.3478E-25 0.3478E-25 O2,gas 0.2266E-44 1.0000 0.1688E-42 0.1688E-42 SO2,gas 0.1725E-12 1.0000 0.1285E-10 0.1285E-10 HF,gas 0.2501E-07 1.0000 0.1863E-05 0.1863E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 196 argentite -23.64 -23.64 0.00 0.000 -0.71474E-11 205 bornite -76.32 -76.32 0.00 0.000 0.00000E+00 225 topaz -19.06 -19.06 0.00 0.000 0.71474E-11 260 galena -10.61 -10.61 0.00 0.000 0.00000E+00 272 sphalerite -9.78 -9.78 0.00 0.000 0.35737E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.75 -0.02 -1.77 -1.772 0.35640E+04 0.927 2 CO2,gas -6.22 -7.17 -0.95 -0.317 0.19105E+04 1.749 3 CH4,gas 5.39 -3.23 -8.62 -2.154 0.17334E+05 -5.917 4 H2,gas 7.73 0.98 -6.75 -3.858 0.13583E+05 -4.053 5 H2S,gas -5.53 -11.61 -6.08 -3.040 0.12231E+05 -3.381 6 S2,gas -8.02 -25.17 -17.15 -2.638 0.34502E+05 -14.451 7 CO,gas 2.47 -6.17 -8.64 -2.659 0.17385E+05 -5.943 8 SO3,gas 12.59 -15.57 -28.16 -7.039 0.56648E+05 -25.459 9 O2,gas 43.48 -1.99 -45.47 -30.314 0.91480E+05 -42.773 10 SO2,gas -0.98 -14.57 -13.59 -3.624 0.27340E+05 -10.891 11 HF,gas -0.08 -8.51 -8.43 -4.214 0.16957E+05 -5.730 12 HCl,gas 1.52 -5.51 -7.03 -3.516 0.14147E+05 -7.032 13 acmite 6.52 2.53 -3.99 -0.415 0.80347E+04 17 albite-high -0.80 -2.56 -1.76 -0.135 0.35362E+04 18 albite -1.59 -2.56 -0.97 -0.075 0.19607E+04 22 analcite 1.61 0.04 -1.58 -0.175 0.31731E+04 23 andalusite 0.60 -2.06 -2.66 -0.266 0.53521E+04 26 anhydrite -6.19 -9.24 -3.05 -1.525 0.61379E+04 27 ankerite -3.36 -4.75 -1.40 -0.233 0.28072E+04 34 aragonite 0.26 -0.84 -1.09 -0.365 0.22002E+04 36 calcite 0.12 -0.84 -0.95 -0.318 0.19203E+04 37 carnegieite-low 6.36 2.67 -3.69 -0.527 0.74176E+04 38 carnegieite-high 7.14 2.67 -4.47 -0.639 0.90016E+04 39 carpholite-Mg 3.79 0.55 -3.24 -0.216 0.65236E+04 40 carpholite-Fe 2.18 -1.46 -3.64 -0.242 0.73156E+04 41 celadonite 3.36 -1.38 -4.74 -0.279 0.95281E+04 49 chloritoid-Mg 7.35 3.18 -4.16 -0.278 0.83791E+04 50 chloritoid-Fe 3.99 1.17 -2.81 -0.187 0.56566E+04 51 chloritoid-Mn 6.18 2.12 -4.06 -0.271 0.81701E+04 53 coesite -1.97 -2.61 -0.64 -0.215 0.12951E+04 58 corundum 3.41 0.56 -2.86 -0.260 0.57460E+04 60 cristobalite -2.15 -2.61 -0.46 -0.153 0.92638E+03 63 cymrite-K 0.38 -4.02 -4.40 -0.367 0.88508E+04 65 diaspore 0.82 0.27 -0.55 -0.092 0.11138E+04 66 diamond -2.38 -5.18 -2.79 -0.798 0.56217E+04 69 dolomite,ordered -1.04 -2.74 -1.70 -0.284 0.34222E+04 83 gibbsite 2.04 0.25 -1.79 -0.256 0.36068E+04 86 goethite 5.00 2.74 -2.26 -0.488 0.45401E+04 87 graphite -2.78 -5.18 -2.40 -0.685 0.48209E+04 90 halite 1.47 -0.49 -1.97 -0.984 0.39591E+04 91 hematite 9.47 5.50 -3.97 -0.481 0.79842E+04 92 heulandite -7.91 -11.52 -3.61 -0.164 0.72543E+04 96 jadeite 2.43 0.05 -2.38 -0.238 0.47815E+04 98 kalsilite 5.22 1.23 -4.00 -0.571 0.80430E+04 99 kaolinite -4.03 -4.71 -0.68 -0.062 0.13674E+04 100 kyanite 0.53 -2.06 -2.59 -0.259 0.52067E+04 102 laumontite -0.40 -3.64 -3.25 -0.216 0.65289E+04 103 lawsonite 5.15 1.62 -3.52 -0.235 0.70850E+04 104 leucite 2.20 -1.39 -3.59 -0.359 0.72208E+04 107 magnesite -0.36 -1.91 -1.54 -0.515 0.31068E+04 117 microcline -3.18 -4.00 -0.82 -0.063 0.16597E+04 120 mullite-Si 2.44 -2.06 -4.50 -0.450 0.90573E+04 121 muscovite -2.23 -3.46 -1.23 -0.073 0.24832E+04 122 paragonite -0.95 -2.02 -1.07 -0.063 0.21505E+04 123 nepheline 5.74 2.67 -3.07 -0.439 0.61852E+04 143 pyrite -19.60 -20.93 -1.33 -0.313 0.26776E+04 144 pyrrhotite -4.69 -8.34 -3.65 -1.218 0.73488E+04 145 pyrrhotiteFe0.875 -6.13 -8.87 -2.74 -1.008 0.55142E+04 146 pyroxmangite 6.00 1.58 -4.42 -0.884 0.88899E+04 147 pyrophyllite -8.35 -9.92 -1.57 -0.098 0.31574E+04 148 quartz -2.49 -2.61 -0.12 -0.041 0.24482E+03 153 rhodochrosite -1.51 -2.97 -1.47 -0.489 0.29508E+04 154 rhodonite 6.03 1.58 -4.45 -0.890 0.89535E+04 155 sanidine -2.15 -4.00 -1.85 -0.143 0.37281E+04 157 siderite -3.17 -3.92 -0.75 -0.250 0.15069E+04 158 sillimanite 0.79 -2.06 -2.85 -0.285 0.57346E+04 165 stilbite -8.20 -11.54 -3.34 -0.159 0.67235E+04 171 sulfur -8.57 -12.59 -4.02 -1.236 0.80797E+04 172 sylvite 1.45 -1.94 -3.38 -1.691 0.68028E+04 180 topaz-H 0.76 -2.07 -2.84 -0.258 0.57062E+04 181 tridymite -2.19 -2.61 -0.42 -0.141 0.85365E+03 184 troilite-low -4.77 -8.34 -3.57 -1.190 0.71795E+04 190 wairakite 0.08 -3.61 -3.68 -0.217 0.74090E+04 197 arsenic -5.93 -10.19 -4.26 -1.100 0.85745E+04 199 arsenopyrite -13.73 -18.54 -4.81 -0.855 0.96781E+04 200 beidellite-Ca -5.18 -7.92 -2.74 -0.170 0.55133E+04 201 beidellite-H -5.69 -8.97 -3.27 -0.209 0.65859E+04 202 beidellite-K -4.81 -7.79 -2.97 -0.182 0.59841E+04 203 beidellite-Mg -5.41 -8.10 -2.69 -0.166 0.54142E+04 204 beidellite-Na -4.71 -7.31 -2.60 -0.159 0.52326E+04 207 chalcedony -2.33 -2.61 -0.28 -0.094 0.56459E+03 208 chalcocite -23.50 -24.67 -1.17 -0.293 0.23589E+04 210 covellite -17.13 -18.63 -1.50 -0.572 0.30225E+04 211 dawsonite 0.39 -1.90 -2.29 -0.287 0.46156E+04 213 montmorillonite-Ca -4.69 -7.23 -2.54 -0.157 0.51167E+04 214 montmorillonite-K -4.41 -7.10 -2.68 -0.164 0.54017E+04 215 montmorillonite-Mg -4.91 -7.41 -2.49 -0.154 0.50191E+04 216 montmorillonite-Na -4.25 -6.62 -2.38 -0.146 0.47821E+04 217 nontronite-Ca 1.45 -2.97 -4.43 -0.287 0.89033E+04 218 nontronite-H 0.94 -4.02 -4.96 -0.332 0.99688E+04 219 nontronite-K 1.82 -2.84 -4.66 -0.299 0.93733E+04 220 nontronite-Mg 1.26 -3.15 -4.41 -0.286 0.88653E+04 221 nontronite-Na 1.92 -2.37 -4.29 -0.275 0.86249E+04 229 gypsum -5.39 -9.27 -3.89 -0.972 0.78197E+04 245 acanthite -23.48 -23.64 -0.16 -0.041 0.32762E+03 251 barite -9.45 -12.05 -2.60 -1.300 0.52295E+04 252 boehmite 2.01 0.27 -1.74 -0.289 0.34928E+04 253 cerussite -2.75 -6.18 -3.43 -1.143 0.69006E+04 254 chalcopyrite -25.55 -26.97 -1.43 -0.265 0.28702E+04 256 copper,native -1.96 -6.04 -4.09 -1.422 0.82243E+04 257 dolomite,disordered -0.54 -2.74 -2.21 -0.368 0.44390E+04 258 ferrous-oxide 7.66 3.25 -4.42 -1.104 0.88832E+04 259 fluorite -10.02 -10.67 -0.65 -0.217 0.13121E+04 261 gold,native -14.79 -16.19 -1.40 -0.486 0.28116E+04 262 silver,native -4.87 -5.53 -0.65 -0.227 0.13136E+04 269 silica-amorphous -1.76 -2.61 -0.85 -0.284 0.17163E+04 270 smithsonite -1.49 -5.35 -3.86 -1.286 0.77633E+04 273 wurtzite -8.22 -9.78 -1.55 -0.518 0.31266E+04 274 zincite 6.41 1.82 -4.59 -1.147 0.92320E+04 275 an20ab80 -0.10 -1.72 -1.61 -0.124 0.32448E+04 276 an25ab75 0.29 -1.51 -1.80 -0.138 0.36201E+04 277 an30ab70 0.70 -1.29 -1.99 -0.153 0.40076E+04 Calculations done for 166.5096 Deg. C; 500.0000 bar Mixer fraction: 0.2500000 Temperature Stoc.ionic strength Heat per mole Actual solution: 166.510 .13944E+01 3.157 Mixing solution: 25.000 .50000E-10 0.646 Fract. of mixing solution added: 0.050000 BITMOL = 0.2775E+01 OLDMOL = 0.7093E+02 New heat: 3.063 New temperature: 161.282 New mixer fraction: 0.3000000 Resulting temperature: 161.282Deg. C Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1296E-03 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 70 Temperature = 161.28 C Pressure = 500.00 bar Mixer fraction = 0.3000000 Water: Moles liquid = 0.7229E+02 kg liquid = 0.1302E+01 Moles total = 0.7197E+02 kg total = 0.1297E+01 Activity = 0.9613 Stoichiometric ionic strength = .1340614E+01 Osmotic coef. = 0.9225 True ionic strength = .1028167E+01 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10987E-04 -4.9591 0.59415E-05 -5.2261 0.54078E+00 -0.2670 2 H2O 0.96132E+00 -0.0171 0.96132E+00 -0.0171 3 Cl- 0.10051E+01 0.0022 0.56246E+00 -0.2499 0.55960E+00 -0.2521 4 SO4-- 0.13267E-03 -3.8772 0.90823E-05 -5.0418 0.68456E-01 -1.1646 5 HCO3- 0.20391E-01 -1.6906 0.11685E-01 -1.9324 0.57304E+00 -0.2418 6 HS- 0.71180E-06 -6.1476 0.39932E-06 -6.3987 0.56100E+00 -0.2510 7 H4SiO4 0.21527E-02 -2.6670 0.21527E-02 -2.6670 0.10000E+01 0.0000 8 Al+++ 0.26116E-12 -12.5831 0.52607E-15 -15.2790 0.20143E-02 -2.6959 9 Ca++ 0.11310E-02 -2.9466 0.70159E-04 -4.1539 0.62035E-01 -1.2074 10 Mg++ 0.10197E-03 -3.9915 0.59165E-05 -5.2279 0.58023E-01 -1.2364 11 Fe++ 0.97611E-06 -6.0105 0.57572E-07 -7.2398 0.58981E-01 -1.2293 12 K+ 0.34286E-01 -1.4649 0.19730E-01 -1.7049 0.57543E+00 -0.2400 13 Na+ 0.98944E+00 -0.0046 0.55258E+00 -0.2576 0.55848E+00 -0.2530 14 Mn++ 0.90294E-05 -5.0443 0.53911E-06 -6.2683 0.59706E-01 -1.2240 15 Zn++ 0.40509E-07 -7.3925 0.23892E-08 -8.6217 0.58981E-01 -1.2293 16 Cu+ 0.22970E-11 -11.6388 0.12818E-11 -11.8922 0.55801E+00 -0.2534 17 Pb++ 0.47173E-08 -8.3263 0.30502E-09 -9.5157 0.64659E-01 -1.1894 18 Ag+ 0.72239E-11 -11.1412 0.41334E-11 -11.3837 0.57218E+00 -0.2425 19 Au+ 0.14612E-21 -21.8353 0.84350E-22 -22.0739 0.57728E+00 -0.2386 20 Ba++ 0.16528E-05 -5.7818 0.10980E-06 -6.9594 0.66434E-01 -1.1776 21 F- 0.10453E-02 -2.9808 0.56183E-03 -3.2504 0.53747E+00 -0.2696 22 H2AsO3- 0.41584E-06 -6.3811 0.28402E-06 -6.5467 0.68299E+00 -0.1656 24 HSiO3- 0.14484E-05 -5.8391 0.81052E-06 -6.0912 0.55960E+00 -0.2521 25 Ca(HSiO3)+ 0.58305E-08 -8.2343 0.33658E-08 -8.4729 0.57728E+00 -0.2386 26 Mg(HSiO3)+ 0.47477E-09 -9.3235 0.27408E-09 -9.5621 0.57728E+00 -0.2386 27 NaHSiO3,aq 0.38718E-05 -5.4121 0.38718E-05 -5.4121 0.10000E+01 0.0000 31 AgCl,aq 0.12688E-08 -8.8966 0.12688E-08 -8.8966 0.10000E+01 0.0000 32 AgCl2- 0.50534E-07 -7.2964 0.28279E-07 -7.5485 0.55960E+00 -0.2521 33 AgCl3-2 0.26865E-07 -7.5708 0.17881E-08 -8.7476 0.66561E-01 -1.1768 34 AgCl4-3 0.29719E-08 -8.5270 0.60398E-11 -11.2190 0.20323E-02 -2.6920 38 Ag(HS),aq 0.64507E-08 -8.1904 0.64507E-08 -8.1904 0.10000E+01 0.0000 40 AlO+ 0.17839E-09 -9.7486 0.10298E-09 -9.9872 0.57728E+00 -0.2386 42 HAlO2,aq 0.17428E-07 -7.7587 0.17428E-07 -7.7587 0.10000E+01 0.0000 43 AlO2- 0.59353E-07 -7.2266 0.32087E-07 -7.4937 0.54061E+00 -0.2671 44 AsO2- 0.10465E-06 -6.9803 0.58562E-07 -7.2324 0.55960E+00 -0.2521 45 HAsO2,aq 0.30122E-04 -4.5211 0.30122E-04 -4.5211 0.10000E+01 0.0000 46 H3AsO3,aq 0.68898E-04 -4.1618 0.68898E-04 -4.1618 0.10000E+01 0.0000 48 H2AsO4- 0.44782E-10 -10.3489 0.25060E-10 -10.6010 0.55960E+00 -0.2521 62 BaCO3,aq 0.26396E-09 -9.5785 0.26396E-09 -9.5785 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.84423E-06 -6.0735 0.49465E-06 -6.3057 0.58593E+00 -0.2322 64 BaCl+ 0.62266E-06 -6.2057 0.35945E-06 -6.4444 0.57728E+00 -0.2386 65 BaF+ 0.74868E-09 -9.1257 0.43219E-09 -9.3643 0.57728E+00 -0.2386 66 CH4,aq 0.55338E-09 -9.2570 0.50041E-09 -9.3007 0.90429E+00 -0.0437 71 CO,aq 0.54426E-09 -9.2642 0.54426E-09 -9.2642 0.10000E+01 0.0000 72 CO2,aq 0.24817E+00 -0.6053 0.22442E+00 -0.6489 0.90429E+00 -0.0437 73 CO3-2 0.29851E-05 -5.5250 0.19870E-06 -6.7018 0.66561E-01 -1.1768 74 CaCO3,aq 0.67602E-06 -6.1700 0.67602E-06 -6.1700 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.10691E-03 -3.9710 0.61718E-04 -4.2096 0.57728E+00 -0.2386 76 CaCl+ 0.34855E-03 -3.4577 0.20121E-03 -3.6963 0.57728E+00 -0.2386 77 CaCl2,aq 0.25554E-04 -4.5925 0.25554E-04 -4.5925 0.10000E+01 0.0000 78 CaF+ 0.32478E-05 -5.4884 0.18749E-05 -5.7270 0.57728E+00 -0.2386 79 CaOH+ 0.38411E-07 -7.4155 0.22174E-07 -7.6542 0.57728E+00 -0.2386 80 CaSO4,aq 0.47406E-06 -6.3242 0.47406E-06 -6.3242 0.10000E+01 0.0000 81 HCl,aq 0.13376E-05 -5.8737 0.13376E-05 -5.8737 0.10000E+01 0.0000 90 CuCl,aq 0.33465E-08 -8.4754 0.33465E-08 -8.4754 0.10000E+01 0.0000 91 CuCl2- 0.54226E-07 -7.2658 0.30345E-07 -7.5179 0.55960E+00 -0.2521 92 CuCl3-2 0.98060E-08 -8.0085 0.65270E-09 -9.1853 0.66561E-01 -1.1768 98 HF,aq 0.67868E-04 -4.1683 0.67868E-04 -4.1683 0.10000E+01 0.0000 99 HF2- 0.19819E-07 -7.7029 0.11091E-07 -7.9550 0.55960E+00 -0.2521 101 FeCl+ 0.22934E-06 -6.6395 0.13239E-06 -6.8781 0.57728E+00 -0.2386 102 FeCl2,aq 0.28545E-09 -9.5445 0.28545E-09 -9.5445 0.10000E+01 0.0000 104 FeF+ 0.63003E-08 -8.2006 0.36370E-08 -8.4393 0.57728E+00 -0.2386 106 FeO,aq 0.10455E-10 -10.9807 0.10455E-10 -10.9807 0.10000E+01 0.0000 107 FeOH+ 0.63304E-08 -8.1986 0.36544E-08 -8.4372 0.57728E+00 -0.2386 112 HFeO2,aq 0.10212E-10 -10.9909 0.10212E-10 -10.9909 0.10000E+01 0.0000 113 H2,aq 0.59746E-07 -7.2237 0.54028E-07 -7.2674 0.90429E+00 -0.0437 114 KCl,aq 0.60428E-03 -3.2188 0.60428E-03 -3.2188 0.10000E+01 0.0000 115 KHSO4,aq 0.78395E-10 -10.1057 0.78395E-10 -10.1057 0.10000E+01 0.0000 116 KOH,aq 0.15012E-07 -7.8236 0.15012E-07 -7.8236 0.10000E+01 0.0000 117 KSO4- 0.11214E-04 -4.9502 0.62754E-05 -5.2024 0.55960E+00 -0.2521 118 MgCO3,aq 0.93302E-08 -8.0301 0.93302E-08 -8.0301 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.89326E-05 -5.0490 0.51566E-05 -5.2876 0.57728E+00 -0.2386 120 MgCl+ 0.20091E-04 -4.6970 0.11598E-04 -4.9356 0.57728E+00 -0.2386 121 MgF+ 0.87488E-06 -6.0581 0.50505E-06 -6.2967 0.57728E+00 -0.2386 122 MgOH+ 0.12631E-07 -7.8986 0.72913E-08 -8.1372 0.57728E+00 -0.2386 124 MnF+ 0.21955E-07 -7.6585 0.12674E-07 -7.8971 0.57728E+00 -0.2386 126 MnOH+ 0.71652E-08 -8.1448 0.41363E-08 -8.3834 0.57728E+00 -0.2386 131 MnCl+ 0.17410E-04 -4.7592 0.10050E-04 -4.9978 0.57728E+00 -0.2386 132 MnSO4,aq 0.39984E-08 -8.3981 0.39984E-08 -8.3981 0.10000E+01 0.0000 133 NaCl,aq 0.18042E+00 -0.7437 0.18042E+00 -0.7437 0.10000E+01 0.0000 134 NaF,aq 0.13270E-03 -3.8771 0.13270E-03 -3.8771 0.10000E+01 0.0000 135 NaOH,aq 0.33698E-06 -6.4724 0.33698E-06 -6.4724 0.10000E+01 0.0000 137 OH- 0.13163E-05 -5.8806 0.71163E-06 -6.1477 0.54061E+00 -0.2671 140 PbCl+ 0.44231E-07 -7.3543 0.25533E-07 -7.5929 0.57728E+00 -0.2386 141 PbCl2,aq 0.14488E-06 -6.8390 0.14488E-06 -6.8390 0.10000E+01 0.0000 142 PbCl3- 0.87653E-07 -7.0572 0.49050E-07 -7.3094 0.55960E+00 -0.2521 143 PbCl4-2 0.93006E-07 -7.0315 0.61906E-08 -8.2083 0.66561E-01 -1.1768 144 PbF+ 0.73379E-10 -10.1344 0.42360E-10 -10.3730 0.57728E+00 -0.2386 148 Pb(HS)2,aq 0.80210E-10 -10.0958 0.80210E-10 -10.0958 0.10000E+01 0.0000 150 H2S,aq 0.75213E-05 -5.1237 0.68014E-05 -5.1674 0.90429E+00 -0.0437 158 HSO3- 0.76733E-10 -10.1150 0.42940E-10 -10.3671 0.55960E+00 -0.2521 159 HSO4- 0.48924E-06 -6.3105 0.28633E-06 -6.5431 0.58526E+00 -0.2326 161 S2O3-2 0.13545E-10 -10.8682 0.90160E-12 -12.0450 0.66561E-01 -1.1768 173 ZnCl+ 0.32711E-05 -5.4853 0.18883E-05 -5.7239 0.57728E+00 -0.2386 174 ZnCl2,aq 0.70624E-06 -6.1510 0.70624E-06 -6.1510 0.10000E+01 0.0000 175 ZnCl3- 0.85577E-07 -7.0676 0.47889E-07 -7.3198 0.55960E+00 -0.2521 176 ZnF+ 0.17124E-09 -9.7664 0.98851E-10 -10.0050 0.57728E+00 -0.2386 177 ZnO,aq 0.66385E-10 -10.1779 0.66385E-10 -10.1779 0.10000E+01 0.0000 178 ZnOH+ 0.10914E-06 -6.9620 0.63002E-07 -7.2006 0.57728E+00 -0.2386 Charge balance for all species = -.9952E-04 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1098695E-04 0.2483451E+00 0.2311693E+03 0.0000 2 H2O 0.1000000E+01 0.5526005E+02 0.9193748E+06 0.0000 3 Cl- 0.1005112E+01 0.1186585E+01 0.3885005E+05 4.9762 4 SO4-- 0.1326729E-03 0.1448389E-03 0.1284916E+02 5.4104 5 HCO3- 0.2039134E-01 0.2686807E+00 0.1514009E+05 3.2937 6 HS- 0.7117958E-06 0.8255346E-05 0.2521364E+00 -1.1726 7 H4SiO4 0.2152691E-02 0.2158017E-02 0.1915524E+03 -2.6670 8 Al+++ 0.2611621E-12 0.7696943E-07 0.1917892E-02 0.3994 9 Ca++ 0.1130965E-02 0.1616427E-02 0.5982764E+02 6.2983 10 Mg++ 0.1019691E-03 0.1318898E-03 0.2961227E+01 5.2243 11 Fe++ 0.9761097E-06 0.1218391E-05 0.6283860E-01 3.2124 12 K+ 0.3428648E-01 0.3490198E-01 0.1260343E+04 3.5212 13 Na+ 0.9894386E+00 0.1169998E+01 0.2484050E+05 4.9685 14 Mn++ 0.9029403E-05 0.2647212E-04 0.1343079E+01 4.1839 15 Zn++ 0.4050866E-07 0.4212787E-05 0.2543243E+00 1.8305 16 Cu+ 0.2297034E-11 0.6738126E-07 0.3953904E-02 -6.6661 17 Pb++ 0.4717326E-08 0.3746519E-06 0.7168637E-01 0.9365 18 Ag+ 0.7223929E-11 0.8809903E-07 0.8776304E-02 -6.1576 19 Au+ 0.1461167E-21 0.2388649E-11 0.4344958E-06 -16.8478 20 Ba++ 0.1652814E-05 0.3120716E-05 0.3958140E+00 3.4928 21 F- 0.1045321E-02 0.1250078E-02 0.2193233E+02 1.9757 22 H2AsO3- 0.4158429E-06 0.9953981E-04 0.1148479E+02 -1.3205 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234430E+00 -.7876190E-05 0.0000000E+00 2 H2O 0.7197033E+02 0.7197033E+02 -.8240021E-08 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886372E-03 0.2060005E-08 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1075171E-04 0.3278601E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810587E-02 0.1153517E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.1002445E-06 0.2307034E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1586825E-05 0.1648004E-07 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.5486706E-05 0.1981470E-05 0.0000000E+00 16 Cu+ 0.1701571E-06 0.8775691E-07 0.8240021E-07 0.0000000E+00 17 Pb++ 0.1565021E-05 0.4879442E-06 0.1077076E-05 0.0000000E+00 18 Ag+ 0.4271281E-06 0.1147396E-06 0.3123885E-06 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1628093E-02 0.2307034E-05 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1271E-20 Mass of aqueous solution: 0.141027E+04 g Temperature = 161.28 C Pressure = 500.00 bar Mixer frac. = 0.3000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) argentite 0.1562E-06 -6.806 0.3870E-04 -4.412 5.451 0.5435E-05 bornite 0.1648E-07 -7.783 0.8270E-05 -5.083 1.165 0.1627E-05 topaz 0.1154E-05 -5.938 0.2123E-03 -3.673 29.90 0.5943E-04 galena 0.1077E-05 -5.968 0.2577E-03 -3.589 36.29 0.3392E-04 sphalerite 0.1981E-05 -5.703 0.1931E-03 -3.714 27.19 0.4721E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity argentite 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 topaz 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.3000000 Solid products produced: Mass = 0.000710 g Volume = 0.000148 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.400 AFFINITY: 0.3573E+03 GOLD Q/K: 0.0464 SILVER Q/K: 0.2046 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 161.2823 deg.C Sat. pressure: 70.6223 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1508E+00 0.7028 0.7484E+01 0.1065E+02 CO2,gas 0.8492E+00 0.9014 0.5406E+02 0.5997E+02 CH4,gas 0.1368E-07 1.0813 0.1045E-05 0.9663E-06 H2,gas 0.9654E-06 1.0329 0.7042E-04 0.6818E-04 H2S,gas 0.6477E-05 0.8424 0.3853E-03 0.4574E-03 S2,gas 0.3860E-16 1.0000 0.2726E-14 0.2726E-14 CO,gas 0.1223E-07 1.0000 0.8640E-06 0.8640E-06 SO3,gas 0.2463E-27 1.0000 0.1740E-25 0.1740E-25 O2,gas 0.5978E-45 1.0000 0.4222E-43 0.4222E-43 SO2,gas 0.1314E-12 1.0000 0.9277E-11 0.9277E-11 HF,gas 0.2193E-07 1.0000 0.1549E-05 0.1549E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 196 argentite -23.94 -23.94 0.00 0.000 0.00000E+00 205 bornite -77.09 -77.09 0.00 0.000 0.00000E+00 225 topaz -18.82 -18.82 0.00 0.000 0.70624E-11 260 galena -10.69 -10.69 0.00 0.000 0.00000E+00 272 sphalerite -9.79 -9.79 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.81 -0.02 -1.82 -1.825 0.36275E+04 0.874 2 CO2,gas -6.18 -7.14 -0.97 -0.322 0.19206E+04 1.733 3 CH4,gas 5.37 -3.31 -8.68 -2.170 0.17255E+05 -5.981 4 H2,gas 7.80 0.95 -6.85 -3.915 0.13620E+05 -4.152 5 H2S,gas -5.51 -11.62 -6.11 -3.057 0.12152E+05 -3.414 6 S2,gas -7.89 -25.15 -17.26 -2.656 0.34318E+05 -14.564 7 CO,gas 2.59 -6.17 -8.76 -2.696 0.17419E+05 -6.063 8 SO3,gas 12.98 -15.48 -28.46 -7.115 0.56572E+05 -25.760 9 O2,gas 44.14 -1.93 -46.07 -30.716 0.91589E+05 -43.375 10 SO2,gas -0.78 -14.51 -13.73 -3.662 0.27297E+05 -11.033 11 HF,gas 0.03 -8.48 -8.51 -4.255 0.16915E+05 -5.810 12 HCl,gas 1.66 -5.48 -7.13 -3.567 0.14180E+05 -7.133 13 acmite 6.61 2.41 -4.21 -0.437 0.83644E+04 17 albite-high -0.67 -2.56 -1.89 -0.146 0.37634E+04 18 albite -1.47 -2.56 -1.09 -0.084 0.21670E+04 22 analcite 1.75 0.05 -1.70 -0.189 0.33869E+04 23 andalusite 0.94 -1.89 -2.83 -0.283 0.56189E+04 26 anhydrite -6.09 -9.20 -3.11 -1.554 0.61766E+04 27 ankerite -3.24 -4.81 -1.57 -0.262 0.31225E+04 34 aragonite 0.33 -0.86 -1.19 -0.395 0.23564E+04 36 calcite 0.19 -0.86 -1.05 -0.349 0.20798E+04 37 carnegieite-low 6.56 2.70 -3.86 -0.551 0.76701E+04 38 carnegieite-high 7.37 2.70 -4.67 -0.666 0.92737E+04 39 carpholite-Mg 4.16 0.65 -3.50 -0.234 0.69642E+04 40 carpholite-Fe 2.53 -1.36 -3.88 -0.259 0.77209E+04 41 celadonite 3.52 -1.45 -4.98 -0.293 0.98965E+04 49 chloritoid-Mg 7.78 3.30 -4.48 -0.299 0.89037E+04 50 chloritoid-Fe 4.38 1.29 -3.08 -0.206 0.61323E+04 51 chloritoid-Mn 6.57 2.26 -4.31 -0.287 0.85652E+04 53 coesite -2.00 -2.63 -0.64 -0.212 0.12667E+04 58 corundum 3.79 0.75 -3.04 -0.276 0.60393E+04 60 cristobalite -2.18 -2.63 -0.46 -0.152 0.90728E+03 63 cymrite-K 0.49 -4.03 -4.52 -0.377 0.89865E+04 65 diaspore 0.98 0.37 -0.61 -0.102 0.12169E+04 66 diamond -2.43 -5.21 -2.77 -0.793 0.55150E+04 69 dolomite,ordered -0.90 -2.79 -1.90 -0.316 0.37713E+04 83 gibbsite 2.19 0.35 -1.85 -0.264 0.36689E+04 86 goethite 5.10 2.70 -2.40 -0.519 0.47723E+04 87 graphite -2.83 -5.21 -2.37 -0.678 0.47196E+04 90 halite 1.49 -0.51 -2.00 -0.999 0.39721E+04 91 hematite 9.70 5.42 -4.28 -0.519 0.85067E+04 92 heulandite -7.71 -11.50 -3.79 -0.172 0.75403E+04 96 jadeite 2.57 0.07 -2.50 -0.250 0.49748E+04 98 kalsilite 5.41 1.25 -4.15 -0.593 0.82552E+04 99 kaolinite -3.81 -4.55 -0.74 -0.067 0.14753E+04 100 kyanite 0.86 -1.89 -2.75 -0.275 0.54620E+04 102 laumontite -0.12 -3.57 -3.45 -0.230 0.68551E+04 103 lawsonite 5.48 1.73 -3.76 -0.250 0.74670E+04 104 leucite 2.36 -1.38 -3.74 -0.374 0.74306E+04 107 magnesite -0.27 -1.93 -1.66 -0.553 0.32988E+04 117 microcline -3.10 -4.01 -0.91 -0.070 0.18124E+04 120 mullite-Si 2.81 -1.89 -4.70 -0.470 0.93354E+04 121 muscovite -1.84 -3.28 -1.44 -0.085 0.28596E+04 122 paragonite -0.54 -1.83 -1.29 -0.076 0.25695E+04 123 nepheline 5.94 2.70 -3.24 -0.463 0.64402E+04 143 pyrite -19.68 -20.99 -1.31 -0.308 0.26040E+04 144 pyrrhotite -4.64 -8.41 -3.77 -1.257 0.74936E+04 145 pyrrhotiteFe0.875 -6.11 -8.93 -2.83 -1.039 0.56184E+04 146 pyroxmangite 6.10 1.53 -4.57 -0.913 0.90797E+04 147 pyrophyllite -8.16 -9.80 -1.64 -0.103 0.32688E+04 148 quartz -2.52 -2.63 -0.11 -0.037 0.21861E+03 153 rhodochrosite -1.45 -2.97 -1.52 -0.507 0.30257E+04 154 rhodonite 6.13 1.53 -4.60 -0.920 0.91445E+04 155 sanidine -2.06 -4.01 -1.95 -0.150 0.38805E+04 157 siderite -3.11 -3.95 -0.83 -0.278 0.16593E+04 158 sillimanite 1.14 -1.89 -3.02 -0.302 0.60047E+04 165 stilbite -8.09 -11.52 -3.43 -0.163 0.68176E+04 171 sulfur -8.59 -12.57 -3.98 -1.226 0.79189E+04 172 sylvite 1.45 -1.95 -3.40 -1.702 0.67677E+04 180 topaz-H 1.05 -1.90 -2.96 -0.269 0.58783E+04 181 tridymite -2.21 -2.63 -0.42 -0.140 0.83255E+03 184 troilite-low -4.73 -8.41 -3.68 -1.227 0.73173E+04 190 wairakite 0.40 -3.54 -3.94 -0.232 0.78314E+04 197 arsenic -6.02 -10.30 -4.27 -1.103 0.84978E+04 199 arsenopyrite -13.80 -18.71 -4.91 -0.873 0.97590E+04 200 beidellite-Ca -4.89 -7.77 -2.88 -0.178 0.57349E+04 201 beidellite-H -5.41 -8.81 -3.40 -0.217 0.67538E+04 202 beidellite-K -4.54 -7.65 -3.11 -0.190 0.61820E+04 203 beidellite-Mg -5.11 -7.95 -2.84 -0.176 0.56438E+04 204 beidellite-Na -4.43 -7.17 -2.74 -0.168 0.54448E+04 207 chalcedony -2.36 -2.63 -0.27 -0.090 0.53829E+03 208 chalcocite -23.78 -24.96 -1.18 -0.294 0.23366E+04 210 covellite -17.30 -18.77 -1.47 -0.558 0.29125E+04 211 dawsonite 0.50 -1.82 -2.32 -0.290 0.46193E+04 213 montmorillonite-Ca -4.48 -7.17 -2.69 -0.166 0.53444E+04 214 montmorillonite-K -4.22 -7.05 -2.82 -0.173 0.56112E+04 215 montmorillonite-Mg -4.70 -7.35 -2.64 -0.163 0.52536E+04 216 montmorillonite-Na -4.05 -6.57 -2.52 -0.154 0.50003E+04 217 nontronite-Ca 1.61 -3.10 -4.70 -0.305 0.93524E+04 219 nontronite-K 1.96 -2.97 -4.93 -0.316 0.97981E+04 220 nontronite-Mg 1.42 -3.27 -4.69 -0.304 0.93221E+04 221 nontronite-Na 2.06 -2.50 -4.56 -0.293 0.90646E+04 229 gypsum -5.32 -9.23 -3.91 -0.977 0.77663E+04 245 acanthite -23.78 -23.94 -0.16 -0.039 0.31340E+03 251 barite -9.42 -12.00 -2.58 -1.292 0.51373E+04 252 boehmite 2.18 0.37 -1.82 -0.303 0.36163E+04 253 cerussite -2.74 -6.22 -3.48 -1.161 0.69248E+04 254 chalcopyrite -25.72 -27.18 -1.46 -0.272 0.29055E+04 256 copper,native -2.03 -6.19 -4.16 -1.448 0.82727E+04 257 dolomite,disordered -0.38 -2.79 -2.42 -0.403 0.48029E+04 258 ferrous-oxide 7.82 3.20 -4.62 -1.155 0.91880E+04 259 fluorite -9.97 -10.65 -0.68 -0.227 0.13513E+04 261 gold,native -15.04 -16.37 -1.33 -0.464 0.26512E+04 262 silver,native -4.99 -5.68 -0.69 -0.240 0.13698E+04 269 silica-amorphous -1.78 -2.63 -0.86 -0.285 0.16998E+04 270 smithsonite -1.42 -5.33 -3.91 -1.302 0.77657E+04 273 wurtzite -8.22 -9.79 -1.57 -0.524 0.31274E+04 274 zincite 6.53 1.81 -4.72 -1.179 0.93756E+04 275 an20ab80 0.08 -1.70 -1.77 -0.136 0.35268E+04 276 an25ab75 0.49 -1.48 -1.97 -0.152 0.39203E+04 277 an30ab70 0.91 -1.27 -2.18 -0.167 0.43260E+04 Calculations done for 161.2823 Deg. C; 500.0000 bar Mixer fraction: 0.3000000 Temperature Stoc.ionic strength Heat per mole Actual solution: 161.282 .13406E+01 3.063 Mixing solution: 25.000 .50000E-10 0.646 Fract. of mixing solution added: 0.050000 BITMOL = 0.2775E+01 OLDMOL = 0.7371E+02 New heat: 2.975 New temperature: 156.426 New mixer fraction: 0.3500000 Resulting temperature: 156.426Deg. C Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1296E-03 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 70 Temperature = 156.43 C Pressure = 500.00 bar Mixer fraction = 0.3500000 Water: Moles liquid = 0.7507E+02 kg liquid = 0.1352E+01 Moles total = 0.7475E+02 kg total = 0.1347E+01 Activity = 0.9627 Stoichiometric ionic strength = .1290834E+01 Osmotic coef. = 0.9244 True ionic strength = .9993539E+00 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11692E-04 -4.9321 0.64303E-05 -5.1918 0.54996E+00 -0.2597 2 H2O 0.96265E+00 -0.0165 0.96265E+00 -0.0165 3 Cl- 0.97711E+00 -0.0101 0.55319E+00 -0.2571 0.56615E+00 -0.2471 4 SO4-- 0.12823E-03 -3.8920 0.93685E-05 -5.0283 0.73061E-01 -1.1363 5 HCO3- 0.19645E-01 -1.7068 0.11365E-01 -1.9444 0.57852E+00 -0.2377 6 HS- 0.62711E-06 -6.2027 0.35584E-06 -6.4487 0.56743E+00 -0.2461 7 H4SiO4 0.20735E-02 -2.6833 0.20735E-02 -2.6833 0.10000E+01 0.0000 8 Al+++ 0.34800E-12 -12.4584 0.82109E-15 -15.0856 0.23595E-02 -2.6272 9 Ca++ 0.11104E-02 -2.9545 0.73871E-04 -4.1315 0.66524E-01 -1.1770 10 Mg++ 0.99177E-04 -4.0036 0.62033E-05 -5.2074 0.62548E-01 -1.2038 11 Fe++ 0.94681E-06 -6.0237 0.60117E-07 -7.2210 0.63495E-01 -1.1973 12 K+ 0.33077E-01 -1.4805 0.19200E-01 -1.7167 0.58046E+00 -0.2362 13 Na+ 0.96195E+00 -0.0168 0.54323E+00 -0.2650 0.56472E+00 -0.2482 14 Mn++ 0.92693E-05 -5.0330 0.59520E-06 -6.2253 0.64212E-01 -1.1924 15 Zn++ 0.43757E-07 -7.3590 0.27783E-08 -8.5562 0.63495E-01 -1.1973 16 Cu+ 0.18343E-11 -11.7365 0.10350E-11 -11.9850 0.56428E+00 -0.2485 17 Pb++ 0.44673E-08 -8.3500 0.30887E-09 -9.5102 0.69139E-01 -1.1603 18 Ag+ 0.56795E-11 -11.2457 0.32795E-11 -11.4842 0.57742E+00 -0.2385 19 Au+ 0.10723E-21 -21.9697 0.62430E-22 -22.2046 0.58219E+00 -0.2349 20 Ba++ 0.16677E-05 -5.7779 0.11826E-06 -6.9272 0.70912E-01 -1.1493 21 F- 0.10140E-02 -2.9940 0.55416E-03 -3.2564 0.54651E+00 -0.2624 22 H2AsO3- 0.33555E-06 -6.4742 0.22920E-06 -6.6398 0.68308E+00 -0.1655 24 HSiO3- 0.12598E-05 -5.8997 0.71323E-06 -6.1468 0.56615E+00 -0.2471 25 Ca(HSiO3)+ 0.48791E-08 -8.3117 0.28406E-08 -8.5466 0.58219E+00 -0.2349 26 Mg(HSiO3)+ 0.40319E-09 -9.3945 0.23473E-09 -9.6294 0.58219E+00 -0.2349 27 NaHSiO3,aq 0.34285E-05 -5.4649 0.34285E-05 -5.4649 0.10000E+01 0.0000 31 AgCl,aq 0.99261E-09 -9.0032 0.99261E-09 -9.0032 0.10000E+01 0.0000 32 AgCl2- 0.38239E-07 -7.4175 0.21649E-07 -7.6646 0.56615E+00 -0.2471 33 AgCl3-2 0.19239E-07 -7.7158 0.13693E-08 -8.8635 0.71175E-01 -1.1477 34 AgCl4-3 0.19381E-08 -8.7126 0.46404E-11 -11.3334 0.23943E-02 -2.6208 38 Ag(HS),aq 0.60586E-08 -8.2176 0.60586E-08 -8.2176 0.10000E+01 0.0000 40 AlO+ 0.17433E-09 -9.7586 0.10149E-09 -9.9936 0.58219E+00 -0.2349 41 AlOH+2 0.10339E-10 -10.9855 0.67265E-12 -12.1722 0.65057E-01 -1.1867 42 HAlO2,aq 0.14367E-07 -7.8426 0.14367E-07 -7.8426 0.10000E+01 0.0000 43 AlO2- 0.39838E-07 -7.3997 0.21879E-07 -7.6600 0.54921E+00 -0.2603 44 AsO2- 0.91057E-07 -7.0407 0.51552E-07 -7.2878 0.56615E+00 -0.2471 45 HAsO2,aq 0.29758E-04 -4.5264 0.29758E-04 -4.5264 0.10000E+01 0.0000 46 H3AsO3,aq 0.65675E-04 -4.1826 0.65675E-04 -4.1826 0.10000E+01 0.0000 48 H2AsO4- 0.37073E-10 -10.4309 0.20989E-10 -10.6780 0.56615E+00 -0.2471 62 BaCO3,aq 0.23459E-09 -9.6297 0.23459E-09 -9.6297 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.75568E-06 -6.1217 0.44609E-06 -6.3506 0.59031E+00 -0.2289 64 BaCl+ 0.58099E-06 -6.2358 0.33825E-06 -6.4708 0.58219E+00 -0.2349 65 BaF+ 0.71137E-09 -9.1479 0.41415E-09 -9.3828 0.58219E+00 -0.2349 66 CH4,aq 0.46356E-09 -9.3339 0.41877E-09 -9.3780 0.90338E+00 -0.0441 71 CO,aq 0.39728E-09 -9.4009 0.39728E-09 -9.4009 0.10000E+01 0.0000 72 CO2,aq 0.23899E+00 -0.6216 0.21590E+00 -0.6657 0.90338E+00 -0.0441 73 CO3-2 0.26241E-05 -5.5810 0.18677E-06 -6.7287 0.71175E-01 -1.1477 74 CaCO3,aq 0.58846E-06 -6.2303 0.58846E-06 -6.2303 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.97850E-04 -4.0094 0.56967E-04 -4.2444 0.58219E+00 -0.2349 76 CaCl+ 0.32148E-03 -3.4929 0.18716E-03 -3.7278 0.58219E+00 -0.2349 77 CaCl2,aq 0.22820E-04 -4.6417 0.22820E-04 -4.6417 0.10000E+01 0.0000 78 CaF+ 0.29925E-05 -5.5240 0.17422E-05 -5.7589 0.58219E+00 -0.2349 79 CaOH+ 0.29396E-07 -7.5317 0.17114E-07 -7.7666 0.58219E+00 -0.2349 80 CaSO4,aq 0.47104E-06 -6.3269 0.47104E-06 -6.3269 0.10000E+01 0.0000 81 HCl,aq 0.13401E-05 -5.8729 0.13401E-05 -5.8729 0.10000E+01 0.0000 90 CuCl,aq 0.26686E-08 -8.5737 0.26686E-08 -8.5737 0.10000E+01 0.0000 91 CuCl2- 0.42011E-07 -7.3766 0.23784E-07 -7.6237 0.56615E+00 -0.2471 92 CuCl3-2 0.72738E-08 -8.1382 0.51771E-09 -9.2859 0.71175E-01 -1.1477 98 HF,aq 0.65005E-04 -4.1871 0.65005E-04 -4.1871 0.10000E+01 0.0000 99 HF2- 0.18596E-07 -7.7306 0.10528E-07 -7.9776 0.56615E+00 -0.2471 101 FeCl+ 0.21266E-06 -6.6723 0.12381E-06 -6.9073 0.58219E+00 -0.2349 102 FeCl2,aq 0.18360E-09 -9.7361 0.18360E-09 -9.7361 0.10000E+01 0.0000 104 FeF+ 0.59326E-08 -8.2268 0.34539E-08 -8.4617 0.58219E+00 -0.2349 107 FeOH+ 0.51643E-08 -8.2870 0.30066E-08 -8.5219 0.58219E+00 -0.2349 113 H2,aq 0.46263E-07 -7.3348 0.41793E-07 -7.3789 0.90338E+00 -0.0441 114 KCl,aq 0.52396E-03 -3.2807 0.52396E-03 -3.2807 0.10000E+01 0.0000 115 KHSO4,aq 0.63657E-10 -10.1962 0.63657E-10 -10.1962 0.10000E+01 0.0000 116 KOH,aq 0.11734E-07 -7.9305 0.11734E-07 -7.9305 0.10000E+01 0.0000 117 KSO4- 0.10329E-04 -4.9859 0.58480E-05 -5.2330 0.56615E+00 -0.2471 118 MgCO3,aq 0.83215E-08 -8.0798 0.83215E-08 -8.0798 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.81660E-05 -5.0880 0.47541E-05 -5.3229 0.58219E+00 -0.2349 120 MgCl+ 0.18841E-04 -4.7249 0.10969E-04 -4.9598 0.58219E+00 -0.2349 121 MgF+ 0.81112E-06 -6.0909 0.47222E-06 -6.3259 0.58219E+00 -0.2349 122 MgOH+ 0.98209E-08 -8.0078 0.57176E-08 -8.2428 0.58219E+00 -0.2349 124 MnF+ 0.21626E-07 -7.6650 0.12591E-07 -7.9000 0.58219E+00 -0.2349 126 MnOH+ 0.60839E-08 -8.2158 0.35420E-08 -8.4508 0.58219E+00 -0.2349 131 MnCl+ 0.16192E-04 -4.7907 0.94269E-05 -5.0256 0.58219E+00 -0.2349 132 MnSO4,aq 0.41200E-08 -8.3851 0.41200E-08 -8.3851 0.10000E+01 0.0000 133 NaCl,aq 0.16467E+00 -0.7834 0.16467E+00 -0.7834 0.10000E+01 0.0000 134 NaF,aq 0.12097E-03 -3.9173 0.12097E-03 -3.9173 0.10000E+01 0.0000 135 NaOH,aq 0.27053E-06 -6.5678 0.27053E-06 -6.5678 0.10000E+01 0.0000 137 OH- 0.10840E-05 -5.9650 0.59535E-06 -6.2252 0.54921E+00 -0.2603 140 PbCl+ 0.40088E-07 -7.3970 0.23339E-07 -7.6319 0.58219E+00 -0.2349 141 PbCl2,aq 0.12341E-06 -6.9086 0.12341E-06 -6.9086 0.10000E+01 0.0000 142 PbCl3- 0.70815E-07 -7.1499 0.40092E-07 -7.3969 0.56615E+00 -0.2471 143 PbCl4-2 0.70667E-07 -7.1508 0.50297E-08 -8.2985 0.71175E-01 -1.1477 144 PbF+ 0.68325E-10 -10.1654 0.39778E-10 -10.4004 0.58219E+00 -0.2349 148 Pb(HS)2,aq 0.67657E-10 -10.1697 0.67657E-10 -10.1697 0.10000E+01 0.0000 150 H2S,aq 0.70005E-05 -5.1549 0.63241E-05 -5.1990 0.90338E+00 -0.0441 158 HSO3- 0.61462E-10 -10.2114 0.34797E-10 -10.4585 0.56615E+00 -0.2471 159 HSO4- 0.46207E-06 -6.3353 0.27258E-06 -6.5645 0.58992E+00 -0.2292 161 S2O3-2 0.12105E-10 -10.9170 0.86161E-12 -12.0647 0.71175E-01 -1.1477 173 ZnCl+ 0.29895E-05 -5.5244 0.17404E-05 -5.7593 0.58219E+00 -0.2349 174 ZnCl2,aq 0.62316E-06 -6.2054 0.62316E-06 -6.2054 0.10000E+01 0.0000 175 ZnCl3- 0.73879E-07 -7.1315 0.41827E-07 -7.3785 0.56615E+00 -0.2471 176 ZnF+ 0.17883E-09 -9.7476 0.10411E-09 -9.9825 0.58219E+00 -0.2349 177 ZnO,aq 0.48147E-10 -10.3174 0.48147E-10 -10.3174 0.10000E+01 0.0000 178 ZnOH+ 0.92753E-07 -7.0327 0.54000E-07 -7.2676 0.58219E+00 -0.2349 Charge balance for all species = -.9584E-04 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1169227E-04 0.2391637E+00 0.2232543E+03 0.0000 2 H2O 0.1000000E+01 0.5526922E+02 0.9221355E+06 0.0000 3 Cl- 0.9771142E+00 0.1142715E+01 0.3751982E+05 4.9346 4 SO4-- 0.1282290E-03 0.1394836E-03 0.1240918E+02 5.3552 5 HCO3- 0.1964475E-01 0.2587472E+00 0.1462170E+05 3.2473 6 HS- 0.6271142E-06 0.7645955E-05 0.2341866E+00 -1.2570 7 H4SiO4 0.2073529E-02 0.2078222E-02 0.1849928E+03 -2.6833 8 Al+++ 0.3479956E-12 0.5438999E-07 0.1359111E-02 0.4897 9 Ca++ 0.1110432E-02 0.1556665E-02 0.5777913E+02 6.2520 10 Mg++ 0.9917720E-04 0.1270136E-03 0.2859834E+01 5.1762 11 Fe++ 0.9468070E-06 0.1170759E-05 0.6055320E-01 3.1625 12 K+ 0.3307730E-01 0.3361160E-01 0.1217189E+04 3.4751 13 Na+ 0.9619503E+00 0.1126742E+01 0.2398996E+05 4.9268 14 Mn++ 0.9269303E-05 0.2549341E-04 0.1297092E+01 4.1582 15 Zn++ 0.4375717E-07 0.3823272E-05 0.2314641E+00 1.8273 16 Cu+ 0.1834266E-11 0.5195513E-07 0.3057352E-02 -6.7933 17 Pb++ 0.4467327E-08 0.3095911E-06 0.5940557E-01 0.8733 18 Ag+ 0.5679490E-11 0.6647457E-07 0.6640887E-02 -6.2924 19 Au+ 0.1072329E-21 0.2300337E-11 0.4196186E-06 -17.0128 20 Ba++ 0.1667722E-05 0.3005338E-05 0.3822612E+00 3.4564 21 F- 0.1013996E-02 0.1203841E-02 0.2118101E+02 1.9354 22 H2AsO3- 0.3355463E-06 0.9585967E-04 0.1109155E+02 -1.4480 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234435E+00 -.8337436E-05 0.0000000E+00 2 H2O 0.7474574E+02 0.7474574E+02 -.9989335E-08 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886368E-03 0.2497334E-08 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.1034034E-04 0.3689970E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810574E-02 0.1166861E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.7355668E-07 0.2333722E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1583326E-05 0.1997867E-07 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.5170569E-05 0.2297607E-05 0.0000000E+00 16 Cu+ 0.1701571E-06 0.7026377E-07 0.9989335E-07 0.0000000E+00 17 Pb++ 0.1565021E-05 0.4186890E-06 0.1146332E-05 0.0000000E+00 18 Ag+ 0.4271281E-06 0.8989977E-07 0.3372283E-06 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1628066E-02 0.2333722E-05 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4235E-21 Mass of aqueous solution: 0.146027E+04 g Temperature = 156.43 C Pressure = 500.00 bar Mixer frac. = 0.3500000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) argentite 0.1686E-06 -6.773 0.4178E-04 -4.379 5.464 0.5868E-05 bornite 0.1998E-07 -7.699 0.1003E-04 -4.999 1.311 0.1972E-05 topaz 0.1167E-05 -5.933 0.2148E-03 -3.668 28.08 0.6012E-04 galena 0.1146E-05 -5.941 0.2743E-03 -3.562 35.87 0.3610E-04 sphalerite 0.2298E-05 -5.639 0.2239E-03 -3.650 29.27 0.5475E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity argentite 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 topaz 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.3500000 Solid products produced: Mass = 0.000765 g Volume = 0.000159 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.400 AFFINITY: 0.3330E+03 GOLD Q/K: 0.0534 SILVER Q/K: 0.1892 Gas composition at saturation ( 4 iterations) ------------------------------------------------- Temperature: 156.4257 deg.C Sat. pressure: 67.0225 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1394E+00 0.7125 0.6655E+01 0.9340E+01 CO2,gas 0.8606E+00 0.9015 0.5200E+02 0.5768E+02 CH4,gas 0.1260E-07 1.0749 0.9076E-06 0.8444E-06 H2,gas 0.8186E-06 1.0316 0.5660E-04 0.5487E-04 H2S,gas 0.6309E-05 0.8449 0.3572E-03 0.4228E-03 S2,gas 0.3158E-16 1.0000 0.2116E-14 0.2116E-14 CO,gas 0.9872E-08 1.0000 0.6617E-06 0.6617E-06 SO3,gas 0.1334E-27 1.0000 0.8943E-26 0.8943E-26 O2,gas 0.1678E-45 1.0000 0.1125E-43 0.1125E-43 SO2,gas 0.1010E-12 1.0000 0.6771E-11 0.6771E-11 HF,gas 0.1931E-07 1.0000 0.1294E-05 0.1294E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 196 argentite -24.23 -24.23 0.00 0.000 -0.69835E-11 205 bornite -77.83 -77.83 0.00 0.000 -0.27934E-10 225 topaz -18.60 -18.60 0.00 0.000 0.69835E-11 260 galena -10.77 -10.77 0.00 0.000 0.00000E+00 272 sphalerite -9.81 -9.81 0.00 0.000 0.34917E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.86 -0.02 -1.88 -1.876 0.36873E+04 0.823 2 CO2,gas -6.14 -7.12 -0.98 -0.328 0.19322E+04 1.716 3 CH4,gas 5.36 -3.38 -8.74 -2.185 0.17182E+05 -6.042 4 H2,gas 7.87 0.93 -6.95 -3.969 0.13654E+05 -4.247 5 H2S,gas -5.49 -11.64 -6.15 -3.073 0.12081E+05 -3.447 6 S2,gas -7.76 -25.13 -17.37 -2.673 0.34150E+05 -14.674 7 CO,gas 2.70 -6.18 -8.88 -2.732 0.17452E+05 -6.179 8 SO3,gas 13.35 -15.40 -28.75 -7.187 0.56508E+05 -26.048 9 O2,gas 44.76 -1.89 -46.65 -31.099 0.91694E+05 -43.949 10 SO2,gas -0.58 -14.45 -13.87 -3.698 0.27261E+05 -11.169 11 HF,gas 0.14 -8.45 -8.59 -4.294 0.16879E+05 -5.888 12 HCl,gas 1.78 -5.45 -7.23 -3.616 0.14214E+05 -7.231 13 acmite 6.70 2.29 -4.41 -0.458 0.86672E+04 17 albite-high -0.55 -2.57 -2.02 -0.155 0.39720E+04 18 albite -1.37 -2.57 -1.20 -0.092 0.23561E+04 22 analcite 1.89 0.07 -1.82 -0.203 0.35830E+04 23 andalusite 1.26 -1.72 -2.98 -0.298 0.58621E+04 26 anhydrite -6.00 -9.16 -3.16 -1.581 0.62136E+04 27 ankerite -3.12 -4.86 -1.74 -0.289 0.34126E+04 34 aragonite 0.39 -0.88 -1.27 -0.424 0.25004E+04 36 calcite 0.25 -0.88 -1.13 -0.378 0.22270E+04 37 carnegieite-low 6.75 2.73 -4.02 -0.574 0.79016E+04 38 carnegieite-high 7.58 2.73 -4.84 -0.692 0.95233E+04 39 carpholite-Mg 4.50 0.76 -3.75 -0.250 0.73672E+04 40 carpholite-Fe 2.86 -1.26 -4.12 -0.274 0.80902E+04 49 chloritoid-Mg 8.20 3.42 -4.77 -0.318 0.93841E+04 50 chloritoid-Fe 4.75 1.41 -3.34 -0.223 0.65665E+04 51 chloritoid-Mn 6.95 2.40 -4.54 -0.303 0.89261E+04 53 coesite -2.02 -2.65 -0.63 -0.210 0.12406E+04 58 corundum 4.14 0.93 -3.21 -0.292 0.63067E+04 60 cristobalite -2.20 -2.65 -0.45 -0.151 0.89002E+03 63 cymrite-K 0.60 -4.04 -4.63 -0.386 0.91093E+04 65 diaspore 1.12 0.46 -0.67 -0.111 0.13104E+04 66 diamond -2.48 -5.23 -2.76 -0.787 0.54164E+04 69 dolomite,ordered -0.76 -2.84 -2.08 -0.347 0.40937E+04 83 gibbsite 2.34 0.44 -1.89 -0.271 0.37248E+04 86 goethite 5.20 2.67 -2.54 -0.548 0.49849E+04 87 graphite -2.88 -5.23 -2.35 -0.672 0.46259E+04 90 halite 1.51 -0.52 -2.03 -1.014 0.39854E+04 91 hematite 9.92 5.35 -4.57 -0.554 0.89857E+04 92 heulandite -7.52 -11.49 -3.97 -0.180 0.78025E+04 96 jadeite 2.70 0.08 -2.62 -0.262 0.51513E+04 98 kalsilite 5.58 1.28 -4.30 -0.614 0.84483E+04 99 kaolinite -3.60 -4.40 -0.80 -0.073 0.15723E+04 100 kyanite 1.18 -1.72 -2.90 -0.290 0.56945E+04 102 laumontite 0.14 -3.50 -3.64 -0.243 0.71525E+04 103 lawsonite 5.81 1.83 -3.98 -0.265 0.78153E+04 104 leucite 2.51 -1.37 -3.88 -0.388 0.76218E+04 107 magnesite -0.19 -1.96 -1.77 -0.590 0.34763E+04 117 microcline -3.03 -4.02 -0.99 -0.076 0.19508E+04 120 mullite-Si 3.16 -1.72 -4.88 -0.488 0.95891E+04 121 muscovite -1.48 -3.11 -1.63 -0.096 0.32009E+04 122 paragonite -0.15 -1.65 -1.50 -0.088 0.29514E+04 123 nepheline 6.13 2.73 -3.40 -0.485 0.66743E+04 143 pyrite -19.76 -21.04 -1.29 -0.303 0.25342E+04 144 pyrrhotite -4.60 -8.48 -3.88 -1.293 0.76255E+04 145 pyrrhotiteFe0.875 -6.08 -8.99 -2.91 -1.069 0.57131E+04 146 pyroxmangite 6.20 1.49 -4.71 -0.942 0.92547E+04 147 pyrophyllite -7.97 -9.69 -1.71 -0.107 0.33687E+04 148 quartz -2.55 -2.65 -0.10 -0.033 0.19452E+03 153 rhodochrosite -1.40 -2.98 -1.57 -0.525 0.30956E+04 154 rhodonite 6.23 1.49 -4.74 -0.948 0.93207E+04 155 sanidine -1.97 -4.02 -2.04 -0.157 0.40188E+04 157 siderite -3.06 -3.97 -0.92 -0.305 0.17994E+04 158 sillimanite 1.46 -1.72 -3.18 -0.318 0.62510E+04 165 stilbite -7.99 -11.50 -3.51 -0.167 0.69014E+04 171 sulfur -8.61 -12.57 -3.95 -1.216 0.77712E+04 172 sylvite 1.45 -1.97 -3.43 -1.713 0.67354E+04 180 topaz-H 1.33 -1.74 -3.07 -0.279 0.60336E+04 181 tridymite -2.24 -2.65 -0.41 -0.138 0.81334E+03 184 troilite-low -4.69 -8.48 -3.79 -1.262 0.74426E+04 190 wairakite 0.71 -3.47 -4.18 -0.246 0.82179E+04 197 arsenic -6.11 -10.39 -4.29 -1.106 0.84257E+04 200 beidellite-Ca -4.61 -7.63 -3.02 -0.187 0.59359E+04 201 beidellite-H -5.15 -8.66 -3.51 -0.224 0.69056E+04 202 beidellite-K -4.28 -7.52 -3.24 -0.198 0.63607E+04 203 beidellite-Mg -4.83 -7.81 -2.98 -0.184 0.58523E+04 204 beidellite-Na -4.17 -7.04 -2.87 -0.176 0.56373E+04 207 chalcedony -2.39 -2.65 -0.26 -0.087 0.51412E+03 208 chalcocite -24.05 -25.23 -1.18 -0.295 0.23166E+04 210 covellite -17.47 -18.90 -1.43 -0.545 0.28115E+04 211 dawsonite 0.60 -1.75 -2.35 -0.294 0.46238E+04 213 montmorillonite-Ca -4.29 -7.11 -2.82 -0.175 0.55520E+04 214 montmorillonite-K -4.04 -6.99 -2.95 -0.181 0.58015E+04 215 montmorillonite-Mg -4.51 -7.29 -2.78 -0.172 0.54675E+04 216 montmorillonite-Na -3.87 -6.52 -2.64 -0.162 0.51991E+04 217 nontronite-Ca 1.76 -3.21 -4.97 -0.322 0.97634E+04 220 nontronite-Mg 1.57 -3.39 -4.96 -0.321 0.97402E+04 221 nontronite-Na 2.20 -2.62 -4.82 -0.309 0.94669E+04 229 gypsum -5.27 -9.19 -3.93 -0.982 0.77183E+04 245 acanthite -24.07 -24.23 -0.15 -0.038 0.30018E+03 251 barite -9.38 -11.96 -2.57 -1.285 0.50536E+04 252 boehmite 2.35 0.46 -1.90 -0.316 0.37288E+04 253 cerussite -2.73 -6.26 -3.53 -1.178 0.69483E+04 254 chalcopyrite -25.88 -27.37 -1.49 -0.278 0.29365E+04 256 copper,native -2.10 -6.33 -4.23 -1.472 0.83176E+04 257 dolomite,disordered -0.23 -2.84 -2.61 -0.436 0.51389E+04 258 ferrous-oxide 7.96 3.15 -4.82 -1.204 0.94678E+04 259 fluorite -9.94 -10.64 -0.71 -0.236 0.13896E+04 261 gold,native -15.28 -16.55 -1.27 -0.443 0.25010E+04 262 silver,native -5.11 -5.83 -0.72 -0.251 0.14212E+04 269 silica-amorphous -1.79 -2.65 -0.86 -0.286 0.16848E+04 270 smithsonite -1.36 -5.31 -3.95 -1.317 0.77690E+04 273 wurtzite -8.22 -9.81 -1.59 -0.530 0.31282E+04 274 zincite 6.65 1.81 -4.84 -1.209 0.95084E+04 275 an20ab80 0.24 -1.68 -1.93 -0.148 0.37852E+04 276 an25ab75 0.68 -1.46 -2.13 -0.164 0.41955E+04 277 an30ab70 1.11 -1.24 -2.35 -0.181 0.46177E+04 Calculations done for 156.4257 Deg. C; 500.0000 bar Mixer fraction: 0.3500000 Temperature Stoc.ionic strength Heat per mole Actual solution: 156.426 .12908E+01 2.975 Mixing solution: 25.000 .50000E-10 0.646 Fract. of mixing solution added: 0.050000 BITMOL = 0.2775E+01 OLDMOL = 0.7648E+02 New heat: 2.894 New temperature: 151.902 New mixer fraction: 0.4000000 Resulting temperature: 151.902Deg. C Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1296E-03 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 70 Temperature = 151.90 C Pressure = 500.00 bar Mixer fraction = 0.4000000 Water: Moles liquid = 0.7784E+02 kg liquid = 0.1402E+01 Moles total = 0.7752E+02 kg total = 0.1397E+01 Activity = 0.9639 Stoichiometric ionic strength = .1244619E+01 Osmotic coef. = 0.9259 True ionic strength = .9718891E+00 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12371E-04 -4.9076 0.69089E-05 -5.1606 0.55848E+00 -0.2530 2 H2O 0.96390E+00 -0.0160 0.96390E+00 -0.0160 3 Cl- 0.95041E+00 -0.0221 0.54364E+00 -0.2647 0.57200E+00 -0.2426 4 SO4-- 0.12407E-03 -3.9063 0.96213E-05 -5.0168 0.77548E-01 -1.1104 5 HCO3- 0.18951E-01 -1.7224 0.11056E-01 -1.9564 0.58339E+00 -0.2340 6 HS- 0.55595E-06 -6.2550 0.31865E-06 -6.4967 0.57317E+00 -0.2417 7 H4SiO4 0.20000E-02 -2.6990 0.20000E-02 -2.6990 0.10000E+01 0.0000 8 Al+++ 0.45595E-12 -12.3411 0.12438E-14 -14.9053 0.27279E-02 -2.5642 9 Ca++ 0.10899E-02 -2.9626 0.77289E-04 -4.1119 0.70916E-01 -1.1493 10 Mg++ 0.96524E-04 -4.0154 0.64663E-05 -5.1893 0.66991E-01 -1.1740 11 Fe++ 0.91938E-06 -6.0365 0.62446E-07 -7.2045 0.67922E-01 -1.1680 12 K+ 0.31947E-01 -1.4956 0.18686E-01 -1.7285 0.58492E+00 -0.2329 13 Na+ 0.93573E+00 -0.0289 0.53364E+00 -0.2728 0.57029E+00 -0.2439 14 Mn++ 0.94816E-05 -5.0231 0.65072E-06 -6.1866 0.68630E-01 -1.1635 15 Zn++ 0.46952E-07 -7.3283 0.31891E-08 -8.4963 0.67922E-01 -1.1680 16 Cu+ 0.14773E-11 -11.8305 0.84187E-12 -12.0748 0.56988E+00 -0.2442 17 Pb++ 0.42253E-08 -8.3741 0.31062E-09 -9.5078 0.73513E-01 -1.1336 18 Ag+ 0.45075E-11 -11.3461 0.26237E-11 -11.5811 0.58208E+00 -0.2350 19 Au+ 0.79682E-22 -22.0986 0.46737E-22 -22.3303 0.58654E+00 -0.2317 20 Ba++ 0.16770E-05 -5.7755 0.12624E-06 -6.8988 0.75279E-01 -1.1233 21 F- 0.98448E-03 -3.0068 0.54605E-03 -3.2628 0.55466E+00 -0.2560 22 H2AsO3- 0.27424E-06 -6.5619 0.18731E-06 -6.7274 0.68301E+00 -0.1656 24 HSiO3- 0.11038E-05 -5.9571 0.63140E-06 -6.1997 0.57200E+00 -0.2426 25 Ca(HSiO3)+ 0.41173E-08 -8.3854 0.24150E-08 -8.6171 0.58654E+00 -0.2317 26 Mg(HSiO3)+ 0.34505E-09 -9.4621 0.20239E-09 -9.6938 0.58654E+00 -0.2317 27 NaHSiO3,aq 0.30541E-05 -5.5151 0.30541E-05 -5.5151 0.10000E+01 0.0000 31 AgCl,aq 0.78379E-09 -9.1058 0.78379E-09 -9.1058 0.10000E+01 0.0000 32 AgCl2- 0.29276E-07 -7.5335 0.16746E-07 -7.7761 0.57200E+00 -0.2426 33 AgCl3-2 0.13993E-07 -7.8541 0.10590E-08 -8.9751 0.75677E-01 -1.1210 34 AgCl4-3 0.12937E-08 -8.8882 0.35994E-11 -11.4438 0.27823E-02 -2.5556 38 Ag(HS),aq 0.56971E-08 -8.2443 0.56971E-08 -8.2443 0.10000E+01 0.0000 40 AlO+ 0.17031E-09 -9.7688 0.99892E-10 -10.0005 0.58654E+00 -0.2317 41 AlOH+2 0.11404E-10 -10.9429 0.79216E-12 -12.1012 0.69464E-01 -1.1582 42 HAlO2,aq 0.11952E-07 -7.9226 0.11952E-07 -7.9226 0.10000E+01 0.0000 43 AlO2- 0.27389E-07 -7.5624 0.15254E-07 -7.8166 0.55694E+00 -0.2542 44 AsO2- 0.79836E-07 -7.0978 0.45667E-07 -7.3404 0.57200E+00 -0.2426 45 HAsO2,aq 0.29376E-04 -4.5320 0.29376E-04 -4.5320 0.10000E+01 0.0000 46 H3AsO3,aq 0.62711E-04 -4.2027 0.62711E-04 -4.2027 0.10000E+01 0.0000 48 H2AsO4- 0.30967E-10 -10.5091 0.17713E-10 -10.7517 0.57200E+00 -0.2426 62 BaCO3,aq 0.20910E-09 -9.6797 0.20910E-09 -9.6797 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.67814E-06 -6.1687 0.40294E-06 -6.3948 0.59419E+00 -0.2261 64 BaCl+ 0.54217E-06 -6.2659 0.31801E-06 -6.4976 0.58654E+00 -0.2317 65 BaF+ 0.67521E-09 -9.1706 0.39604E-09 -9.4023 0.58654E+00 -0.2317 66 CH4,aq 0.39239E-09 -9.4063 0.35425E-09 -9.4507 0.90281E+00 -0.0444 71 CO,aq 0.29464E-09 -9.5307 0.29464E-09 -9.5307 0.10000E+01 0.0000 72 CO2,aq 0.23047E+00 -0.6374 0.20807E+00 -0.6818 0.90281E+00 -0.0444 73 CO3-2 0.23244E-05 -5.6337 0.17590E-06 -6.7547 0.75677E-01 -1.1210 74 CaCO3,aq 0.51509E-06 -6.2881 0.51509E-06 -6.2881 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.89869E-04 -4.0464 0.52712E-04 -4.2781 0.58654E+00 -0.2317 76 CaCl+ 0.29720E-03 -3.5270 0.17432E-03 -3.7587 0.58654E+00 -0.2317 77 CaCl2,aq 0.20468E-04 -4.6889 0.20468E-04 -4.6889 0.10000E+01 0.0000 78 CaF+ 0.27643E-05 -5.5584 0.16214E-05 -5.7901 0.58654E+00 -0.2317 79 CaOH+ 0.22784E-07 -7.6424 0.13364E-07 -7.8741 0.58654E+00 -0.2317 80 CaSO4,aq 0.46663E-06 -6.3310 0.46663E-06 -6.3310 0.10000E+01 0.0000 81 HCl,aq 0.13405E-05 -5.8727 0.13405E-05 -5.8727 0.10000E+01 0.0000 90 CuCl,aq 0.21447E-08 -8.6686 0.21447E-08 -8.6686 0.10000E+01 0.0000 91 CuCl2- 0.32831E-07 -7.4837 0.18779E-07 -7.7263 0.57200E+00 -0.2426 92 CuCl3-2 0.54562E-08 -8.2631 0.41291E-09 -9.3841 0.75677E-01 -1.1210 98 HF,aq 0.62229E-04 -4.2060 0.62229E-04 -4.2060 0.10000E+01 0.0000 99 HF2- 0.17427E-07 -7.7588 0.99686E-08 -8.0014 0.57200E+00 -0.2426 101 FeCl+ 0.19772E-06 -6.7040 0.11597E-06 -6.9357 0.58654E+00 -0.2317 102 FeCl2,aq 0.12051E-09 -9.9190 0.12051E-09 -9.9190 0.10000E+01 0.0000 104 FeF+ 0.55955E-08 -8.2522 0.32820E-08 -8.4839 0.58654E+00 -0.2317 107 FeOH+ 0.42579E-08 -8.3708 0.24974E-08 -8.6025 0.58654E+00 -0.2317 113 H2,aq 0.36316E-07 -7.4399 0.32787E-07 -7.4843 0.90281E+00 -0.0444 114 KCl,aq 0.45686E-03 -3.3402 0.45686E-03 -3.3402 0.10000E+01 0.0000 115 KHSO4,aq 0.52099E-10 -10.2832 0.52099E-10 -10.2832 0.10000E+01 0.0000 116 KOH,aq 0.92836E-08 -8.0323 0.92836E-08 -8.0323 0.10000E+01 0.0000 117 KSO4- 0.95437E-05 -5.0203 0.54591E-05 -5.2629 0.57200E+00 -0.2426 118 MgCO3,aq 0.74551E-08 -8.1275 0.74551E-08 -8.1275 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.74929E-05 -5.1254 0.43949E-05 -5.3571 0.58654E+00 -0.2317 120 MgCl+ 0.17699E-04 -4.7521 0.10381E-04 -4.9838 0.58654E+00 -0.2317 121 MgF+ 0.75388E-06 -6.1227 0.44218E-06 -6.3544 0.58654E+00 -0.2317 122 MgOH+ 0.77346E-08 -8.1116 0.45367E-08 -8.3433 0.58654E+00 -0.2317 124 MnF+ 0.21258E-07 -7.6725 0.12469E-07 -7.9042 0.58654E+00 -0.2317 126 MnOH+ 0.51993E-08 -8.2841 0.30496E-08 -8.5158 0.58654E+00 -0.2317 131 MnCl+ 0.15072E-04 -4.8218 0.88405E-05 -5.0535 0.58654E+00 -0.2317 132 MnSO4,aq 0.42194E-08 -8.3747 0.42194E-08 -8.3747 0.10000E+01 0.0000 133 NaCl,aq 0.15073E+00 -0.8218 0.15073E+00 -0.8218 0.10000E+01 0.0000 134 NaF,aq 0.11061E-03 -3.9562 0.11061E-03 -3.9562 0.10000E+01 0.0000 135 NaOH,aq 0.21951E-06 -6.6586 0.21951E-06 -6.6586 0.10000E+01 0.0000 137 OH- 0.90252E-06 -6.0445 0.50265E-06 -6.2987 0.55694E+00 -0.2542 140 PbCl+ 0.36347E-07 -7.4395 0.21319E-07 -7.6712 0.58654E+00 -0.2317 141 PbCl2,aq 0.10544E-06 -6.9770 0.10544E-06 -6.9770 0.10000E+01 0.0000 142 PbCl3- 0.57539E-07 -7.2400 0.32913E-07 -7.4826 0.57200E+00 -0.2426 143 PbCl4-2 0.54173E-07 -7.2662 0.40997E-08 -8.3873 0.75677E-01 -1.1210 144 PbF+ 0.63555E-10 -10.1969 0.37278E-10 -10.4286 0.58654E+00 -0.2317 148 Pb(HS)2,aq 0.57471E-10 -10.2406 0.57471E-10 -10.2406 0.10000E+01 0.0000 150 H2S,aq 0.65361E-05 -5.1847 0.59008E-05 -5.2291 0.90281E+00 -0.0444 158 HSO3- 0.49680E-10 -10.3038 0.28417E-10 -10.5464 0.57200E+00 -0.2426 159 HSO4- 0.43646E-06 -6.3601 0.25928E-06 -6.5862 0.59404E+00 -0.2262 161 S2O3-2 0.10861E-10 -10.9641 0.82193E-12 -12.0852 0.75677E-01 -1.1210 173 ZnCl+ 0.27339E-05 -5.5632 0.16036E-05 -5.7949 0.58654E+00 -0.2317 174 ZnCl2,aq 0.55130E-06 -6.2586 0.55130E-06 -6.2586 0.10000E+01 0.0000 175 ZnCl3- 0.64069E-07 -7.1933 0.36648E-07 -7.4360 0.57200E+00 -0.2426 176 ZnF+ 0.18566E-09 -9.7313 0.10890E-09 -9.9630 0.58654E+00 -0.2317 177 ZnO,aq 0.35466E-10 -10.4502 0.35466E-10 -10.4502 0.10000E+01 0.0000 178 ZnOH+ 0.79285E-07 -7.1008 0.46504E-07 -7.3325 0.58654E+00 -0.2317 Charge balance for all species = -.9243E-04 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1237103E-04 0.2306371E+00 0.2158634E+03 0.0000 2 H2O 0.1000000E+01 0.5527775E+02 0.9247134E+06 0.0000 3 Cl- 0.9504092E+00 0.1101973E+01 0.3627766E+05 4.8959 4 SO4-- 0.1240687E-03 0.1345103E-03 0.1199833E+02 5.3044 5 HCO3- 0.1895064E-01 0.2495220E+00 0.1413762E+05 3.2042 6 HS- 0.5559490E-06 0.7107400E-05 0.2182662E+00 -1.3361 7 H4SiO4 0.1999958E-02 0.2004120E-02 0.1788677E+03 -2.6990 8 Al+++ 0.4559524E-12 0.3952294E-07 0.9902176E-03 0.5765 9 Ca++ 0.1089859E-02 0.1501165E-02 0.5586627E+02 6.2093 10 Mg++ 0.9652422E-04 0.1224852E-03 0.2765155E+01 5.1318 11 Fe++ 0.9193818E-06 0.1127083E-05 0.5844820E-01 3.1167 12 K+ 0.3194682E-01 0.3241324E-01 0.1176892E+04 3.4321 13 Na+ 0.9357265E+00 0.1086570E+01 0.2319573E+05 4.8878 14 Mn++ 0.9481576E-05 0.2458449E-04 0.1254149E+01 4.1346 15 Zn++ 0.4695166E-07 0.3475735E-05 0.2109796E+00 1.8248 16 Cu+ 0.1477264E-11 0.4043324E-07 0.2385619E-02 -6.9142 17 Pb++ 0.4225304E-08 0.2578484E-06 0.4960764E-01 0.8134 18 Ag+ 0.4507489E-11 0.5104949E-07 0.5113372E-02 -6.4205 19 Au+ 0.7968237E-22 0.2218322E-11 0.4057265E-06 -17.1697 20 Ba++ 0.1676996E-05 0.2898188E-05 0.3696059E+00 3.4224 21 F- 0.9844833E-03 0.1160907E-02 0.2047956E+02 1.8978 22 H2AsO3- 0.2742362E-06 0.9244196E-04 0.1072435E+02 -1.5669 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234439E+00 -.8743953E-05 0.0000000E+00 2 H2O 0.7752115E+02 0.7752115E+02 -.1134538E-07 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886364E-03 0.2836345E-08 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.9967371E-05 0.4062939E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810565E-02 0.1175926E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.5542672E-07 0.2351852E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1580614E-05 0.2269076E-07 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.4874348E-05 0.2593829E-05 0.0000000E+00 16 Cu+ 0.1701571E-06 0.5670331E-07 0.1134538E-06 0.0000000E+00 17 Pb++ 0.1565021E-05 0.3616049E-06 0.1203416E-05 0.0000000E+00 18 Ag+ 0.4271281E-06 0.7159148E-07 0.3555366E-06 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1628048E-02 0.2351852E-05 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1271E-20 Mass of aqueous solution: 0.151027E+04 g Temperature = 151.90 C Pressure = 500.00 bar Mixer frac. = 0.4000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) argentite 0.1778E-06 -6.750 0.4405E-04 -4.356 5.422 0.6186E-05 bornite 0.2269E-07 -7.644 0.1139E-04 -4.944 1.401 0.2240E-05 topaz 0.1176E-05 -5.930 0.2164E-03 -3.665 26.64 0.6059E-04 galena 0.1203E-05 -5.920 0.2879E-03 -3.541 35.44 0.3789E-04 sphalerite 0.2594E-05 -5.586 0.2527E-03 -3.597 31.10 0.6180E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity argentite 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 topaz 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.4000000 Solid products produced: Mass = 0.000812 g Volume = 0.000169 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.400 AFFINITY: 0.3095E+03 GOLD Q/K: 0.0612 SILVER Q/K: 0.1758 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 151.9018 deg.C Sat. pressure: 63.6736 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1293E+00 0.7219 0.5946E+01 0.8236E+01 CO2,gas 0.8706E+00 0.9018 0.4999E+02 0.5544E+02 CH4,gas 0.1165E-07 1.0692 0.7935E-06 0.7421E-06 H2,gas 0.7007E-06 1.0303 0.4597E-04 0.4462E-04 H2S,gas 0.6149E-05 0.8476 0.3319E-03 0.3915E-03 S2,gas 0.2601E-16 1.0000 0.1656E-14 0.1656E-14 CO,gas 0.8047E-08 1.0000 0.5124E-06 0.5124E-06 SO3,gas 0.7416E-28 1.0000 0.4722E-26 0.4722E-26 O2,gas 0.5000E-46 1.0000 0.3184E-44 0.3184E-44 SO2,gas 0.7846E-13 1.0000 0.4996E-11 0.4996E-11 HF,gas 0.1707E-07 1.0000 0.1087E-05 0.1087E-05 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 196 argentite -24.50 -24.50 0.00 0.000 0.69099E-11 205 bornite -78.54 -78.54 0.00 0.000 0.00000E+00 225 topaz -18.39 -18.39 0.00 0.000 0.69099E-11 260 galena -10.84 -10.84 0.00 0.000 -0.34550E-11 272 sphalerite -9.83 -9.83 0.00 0.000 0.69099E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.91 -0.02 -1.92 -1.925 0.37436E+04 0.774 2 CO2,gas -6.10 -7.10 -1.00 -0.333 0.19451E+04 1.699 3 CH4,gas 5.35 -3.45 -8.80 -2.200 0.17115E+05 -6.100 4 H2,gas 7.94 0.90 -7.04 -4.021 0.13686E+05 -4.338 5 H2S,gas -5.48 -11.66 -6.18 -3.089 0.12016E+05 -3.479 6 S2,gas -7.64 -25.12 -17.48 -2.689 0.33998E+05 -14.781 7 CO,gas 2.81 -6.18 -8.99 -2.766 0.17484E+05 -6.290 8 SO3,gas 13.70 -15.32 -29.02 -7.256 0.56452E+05 -26.326 9 O2,gas 45.36 -1.84 -47.20 -31.464 0.91795E+05 -44.497 10 SO2,gas -0.40 -14.40 -14.00 -3.733 0.27230E+05 -11.301 11 HF,gas 0.24 -8.42 -8.66 -4.331 0.16849E+05 -5.964 12 HCl,gas 1.90 -5.43 -7.33 -3.663 0.14249E+05 -7.326 13 acmite 6.79 2.19 -4.60 -0.478 0.89462E+04 17 albite-high -0.43 -2.57 -2.14 -0.165 0.41642E+04 18 albite -1.27 -2.57 -1.30 -0.100 0.25300E+04 22 analcite 2.02 0.08 -1.93 -0.215 0.37634E+04 23 andalusite 1.57 -1.56 -3.13 -0.313 0.60844E+04 26 anhydrite -5.92 -9.13 -3.21 -1.606 0.62490E+04 27 ankerite -3.02 -4.91 -1.89 -0.315 0.36806E+04 34 aragonite 0.45 -0.91 -1.35 -0.451 0.26336E+04 36 calcite 0.31 -0.91 -1.22 -0.405 0.23632E+04 37 carnegieite-low 6.94 2.77 -4.17 -0.596 0.81143E+04 39 carpholite-Mg 4.83 0.85 -3.98 -0.265 0.77367E+04 40 carpholite-Fe 3.17 -1.16 -4.33 -0.289 0.84276E+04 50 chloritoid-Fe 5.10 1.52 -3.58 -0.239 0.69639E+04 51 chloritoid-Mn 7.30 2.54 -4.76 -0.317 0.92567E+04 53 coesite -2.04 -2.67 -0.63 -0.209 0.12168E+04 58 corundum 4.47 1.11 -3.37 -0.306 0.65510E+04 60 cristobalite -2.22 -2.67 -0.45 -0.150 0.87440E+03 63 cymrite-K 0.70 -4.04 -4.74 -0.395 0.92211E+04 65 diaspore 1.26 0.54 -0.72 -0.120 0.13952E+04 66 diamond -2.52 -5.26 -2.74 -0.782 0.53249E+04 69 dolomite,ordered -0.63 -2.89 -2.26 -0.376 0.43923E+04 83 gibbsite 2.47 0.53 -1.94 -0.277 0.37752E+04 86 goethite 5.30 2.63 -2.66 -0.576 0.51802E+04 87 graphite -2.93 -5.26 -2.33 -0.667 0.45389E+04 90 halite 1.52 -0.54 -2.06 -1.028 0.39989E+04 91 hematite 10.13 5.28 -4.85 -0.587 0.94261E+04 92 heulandite -7.33 -11.47 -4.14 -0.188 0.80437E+04 96 jadeite 2.83 0.10 -2.73 -0.273 0.53131E+04 98 kalsilite 5.74 1.31 -4.43 -0.633 0.86245E+04 99 kaolinite -3.41 -4.26 -0.85 -0.078 0.16596E+04 100 kyanite 1.47 -1.56 -3.04 -0.304 0.59066E+04 102 laumontite 0.38 -3.43 -3.82 -0.254 0.74247E+04 103 lawsonite 6.11 1.93 -4.18 -0.279 0.81337E+04 104 leucite 2.65 -1.36 -4.01 -0.401 0.77967E+04 107 magnesite -0.11 -1.99 -1.87 -0.624 0.36410E+04 117 microcline -2.96 -4.02 -1.07 -0.082 0.20767E+04 121 muscovite -1.13 -2.94 -1.81 -0.106 0.35114E+04 122 paragonite 0.22 -1.48 -1.70 -0.100 0.33005E+04 123 nepheline 6.31 2.77 -3.54 -0.506 0.68896E+04 143 pyrite -19.83 -21.10 -1.27 -0.299 0.24682E+04 144 pyrrhotite -4.56 -8.54 -3.98 -1.328 0.77461E+04 145 pyrrhotiteFe0.875 -6.06 -9.04 -2.98 -1.097 0.57993E+04 146 pyroxmangite 6.29 1.45 -4.84 -0.968 0.94166E+04 147 pyrophyllite -7.80 -9.58 -1.78 -0.111 0.34588E+04 148 quartz -2.58 -2.67 -0.09 -0.030 0.17239E+03 153 rhodochrosite -1.36 -2.98 -1.63 -0.542 0.31609E+04 154 rhodonite 6.33 1.45 -4.88 -0.975 0.94839E+04 155 sanidine -1.89 -4.02 -2.13 -0.164 0.41446E+04 157 siderite -3.01 -4.00 -0.99 -0.331 0.19285E+04 158 sillimanite 1.77 -1.56 -3.33 -0.333 0.64762E+04 165 stilbite -7.90 -11.48 -3.59 -0.171 0.69765E+04 171 sulfur -8.64 -12.56 -3.93 -1.208 0.76351E+04 172 sylvite 1.45 -1.99 -3.45 -1.724 0.67057E+04 180 topaz-H 1.60 -1.58 -3.17 -0.289 0.61742E+04 181 tridymite -2.26 -2.67 -0.41 -0.136 0.79583E+03 184 troilite-low -4.66 -8.54 -3.89 -1.295 0.75570E+04 190 wairakite 1.01 -3.40 -4.41 -0.259 0.85724E+04 197 arsenic -6.19 -10.48 -4.30 -1.109 0.83579E+04 200 beidellite-Ca -4.35 -7.49 -3.15 -0.195 0.61188E+04 201 beidellite-H -4.90 -8.52 -3.62 -0.231 0.70431E+04 202 beidellite-K -4.03 -7.39 -3.35 -0.205 0.65226E+04 203 beidellite-Mg -4.57 -7.67 -3.11 -0.192 0.60421E+04 204 beidellite-Na -3.92 -6.91 -2.99 -0.183 0.58123E+04 207 chalcedony -2.41 -2.67 -0.25 -0.084 0.49190E+03 208 chalcocite -24.30 -25.49 -1.18 -0.295 0.22986E+04 210 covellite -17.63 -19.02 -1.40 -0.532 0.27187E+04 211 dawsonite 0.70 -1.68 -2.38 -0.297 0.46286E+04 213 montmorillonite-Ca -4.10 -7.05 -2.95 -0.183 0.57417E+04 214 montmorillonite-K -3.87 -6.94 -3.07 -0.188 0.59750E+04 215 montmorillonite-Mg -4.32 -7.23 -2.91 -0.180 0.56634E+04 216 montmorillonite-Na -3.70 -6.46 -2.77 -0.169 0.53809E+04 229 gypsum -5.21 -9.16 -3.95 -0.987 0.76750E+04 245 acanthite -24.35 -24.50 -0.15 -0.037 0.28787E+03 251 barite -9.36 -11.92 -2.56 -1.280 0.49777E+04 252 boehmite 2.51 0.54 -1.97 -0.328 0.38314E+04 253 cerussite -2.72 -6.30 -3.58 -1.195 0.69712E+04 254 chalcopyrite -26.04 -27.56 -1.52 -0.284 0.29639E+04 256 copper,native -2.16 -6.46 -4.30 -1.495 0.83593E+04 257 dolomite,disordered -0.09 -2.89 -2.80 -0.467 0.54500E+04 259 fluorite -9.90 -10.64 -0.73 -0.245 0.14270E+04 261 gold,native -15.50 -16.72 -1.21 -0.422 0.23601E+04 262 silver,native -5.21 -5.97 -0.76 -0.263 0.14685E+04 269 silica-amorphous -1.81 -2.67 -0.86 -0.286 0.16713E+04 270 smithsonite -1.30 -5.29 -4.00 -1.332 0.77730E+04 273 wurtzite -8.22 -9.83 -1.61 -0.536 0.31288E+04 274 zincite 6.76 1.81 -4.95 -1.238 0.96314E+04 275 an20ab80 0.41 -1.66 -2.07 -0.159 0.40228E+04 276 an25ab75 0.85 -1.44 -2.29 -0.176 0.44485E+04 277 an30ab70 1.30 -1.21 -2.51 -0.193 0.48859E+04 Calculations done for 151.9018 Deg. C; 500.0000 bar Mixer fraction: 0.4000000 Temperature Stoc.ionic strength Heat per mole Actual solution: 151.902 .12446E+01 2.894 Mixing solution: 25.000 .50000E-10 0.646 Fract. of mixing solution added: 0.050000 BITMOL = 0.2775E+01 OLDMOL = 0.7926E+02 New heat: 2.818 New temperature: 147.678 New mixer fraction: 0.4500000 Resulting temperature: 147.678Deg. C Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1296E-03 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 70 Temperature = 147.68 C Pressure = 500.00 bar Mixer fraction = 0.4500000 Water: Moles liquid = 0.8062E+02 kg liquid = 0.1452E+01 Moles total = 0.8030E+02 kg total = 0.1447E+01 Activity = 0.9651 Stoichiometric ionic strength = .1201599E+01 Osmotic coef. = 0.9271 True ionic strength = .9458582E+00 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13040E-04 -4.8847 0.73858E-05 -5.1316 0.56639E+00 -0.2469 2 H2O 0.96508E+00 -0.0154 0.96508E+00 -0.0154 3 Cl- 0.92509E+00 -0.0338 0.53361E+00 -0.2728 0.57682E+00 -0.2390 4 SO4-- 0.12017E-03 -3.9202 0.98358E-05 -5.0072 0.81846E-01 -1.0870 5 HCO3- 0.18304E-01 -1.7375 0.10750E-01 -1.9686 0.58730E+00 -0.2311 6 HS- 0.49635E-06 -6.3042 0.28683E-06 -6.5424 0.57788E+00 -0.2382 7 H4SiO4 0.19314E-02 -2.7141 0.19314E-02 -2.7141 0.10000E+01 0.0000 8 Al+++ 0.59024E-12 -12.2290 0.18385E-14 -14.7355 0.31149E-02 -2.5066 9 Ca++ 0.10696E-02 -2.9708 0.80376E-04 -4.0949 0.75143E-01 -1.1241 10 Mg++ 0.94015E-04 -4.0268 0.67019E-05 -5.1738 0.71285E-01 -1.1470 11 Fe++ 0.89376E-06 -6.0488 0.64526E-07 -7.1903 0.72196E-01 -1.1415 12 K+ 0.30888E-01 -1.5102 0.18177E-01 -1.7405 0.58846E+00 -0.2303 13 Na+ 0.91086E+00 -0.0405 0.52361E+00 -0.2810 0.57485E+00 -0.2404 14 Mn++ 0.96701E-05 -5.0146 0.70486E-06 -6.1519 0.72891E-01 -1.1373 15 Zn++ 0.50205E-07 -7.2993 0.36246E-08 -8.4407 0.72196E-01 -1.1415 16 Cu+ 0.12036E-11 -11.9195 0.69144E-12 -12.1602 0.57448E+00 -0.2407 17 Pb++ 0.40062E-08 -8.3973 0.31133E-09 -9.5068 0.77713E-01 -1.1095 18 Ag+ 0.36215E-11 -11.4411 0.21214E-11 -11.6734 0.58580E+00 -0.2323 19 Au+ 0.60097E-22 -22.2212 0.35456E-22 -22.4503 0.58998E+00 -0.2292 20 Ba++ 0.16817E-05 -5.7743 0.13364E-06 -6.8741 0.79465E-01 -1.0998 21 F- 0.95666E-03 -3.0192 0.53726E-03 -3.2698 0.56160E+00 -0.2506 22 H2AsO3- 0.22671E-06 -6.6445 0.15469E-06 -6.8105 0.68231E+00 -0.1660 24 HSiO3- 0.97406E-06 -6.0114 0.56186E-06 -6.2504 0.57682E+00 -0.2390 25 Ca(HSiO3)+ 0.34991E-08 -8.4560 0.20644E-08 -8.6852 0.58998E+00 -0.2292 26 Mg(HSiO3)+ 0.29722E-09 -9.5269 0.17535E-09 -9.7561 0.58998E+00 -0.2292 27 NaHSiO3,aq 0.27315E-05 -5.5636 0.27315E-05 -5.5636 0.10000E+01 0.0000 31 AgCl,aq 0.62538E-09 -9.2039 0.62538E-09 -9.2039 0.10000E+01 0.0000 32 AgCl2- 0.22691E-07 -7.6441 0.13089E-07 -7.8831 0.57682E+00 -0.2390 33 AgCl3-2 0.10326E-07 -7.9861 0.82605E-09 -9.0830 0.79997E-01 -1.0969 34 AgCl4-3 0.88138E-09 -9.0548 0.28127E-11 -11.5509 0.31913E-02 -2.4960 38 Ag(HS),aq 0.53710E-08 -8.2699 0.53710E-08 -8.2699 0.10000E+01 0.0000 40 AlO+ 0.16678E-09 -9.7778 0.98398E-10 -10.0070 0.58998E+00 -0.2292 41 AlOH+2 0.12540E-10 -10.9017 0.92437E-12 -12.0342 0.73711E-01 -1.1325 42 HAlO2,aq 0.10047E-07 -7.9980 0.10047E-07 -7.9980 0.10000E+01 0.0000 43 AlO2- 0.19265E-07 -7.7152 0.10856E-07 -7.9643 0.56350E+00 -0.2491 44 AsO2- 0.70490E-07 -7.1519 0.40660E-07 -7.3908 0.57682E+00 -0.2390 45 HAsO2,aq 0.28983E-04 -4.5379 0.28983E-04 -4.5379 0.10000E+01 0.0000 46 H3AsO3,aq 0.59979E-04 -4.2220 0.59979E-04 -4.2220 0.10000E+01 0.0000 48 H2AsO4- 0.26098E-10 -10.5834 0.15054E-10 -10.8223 0.57682E+00 -0.2390 62 BaCO3,aq 0.18661E-09 -9.7291 0.18661E-09 -9.7291 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.60994E-06 -6.2147 0.36424E-06 -6.4386 0.59717E+00 -0.2239 64 BaCl+ 0.50594E-06 -6.2959 0.29850E-06 -6.5251 0.58998E+00 -0.2292 65 BaF+ 0.63995E-09 -9.1939 0.37756E-09 -9.4230 0.58998E+00 -0.2292 66 CH4,aq 0.33546E-09 -9.4744 0.30276E-09 -9.5189 0.90251E+00 -0.0446 71 CO,aq 0.22195E-09 -9.6537 0.22195E-09 -9.6537 0.10000E+01 0.0000 72 CO2,aq 0.22254E+00 -0.6526 0.20084E+00 -0.6972 0.90251E+00 -0.0446 73 CO3-2 0.20721E-05 -5.6836 0.16576E-06 -6.7805 0.79997E-01 -1.0969 74 CaCO3,aq 0.45243E-06 -6.3444 0.45243E-06 -6.3444 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.82729E-04 -4.0823 0.48808E-04 -4.3115 0.58998E+00 -0.2292 76 CaCl+ 0.27523E-03 -3.5603 0.16238E-03 -3.7895 0.58998E+00 -0.2292 77 CaCl2,aq 0.18392E-04 -4.7354 0.18392E-04 -4.7354 0.10000E+01 0.0000 78 CaF+ 0.25579E-05 -5.5921 0.15091E-05 -5.8213 0.58998E+00 -0.2292 79 CaOH+ 0.17878E-07 -7.7477 0.10547E-07 -7.9769 0.58998E+00 -0.2292 80 CaSO4,aq 0.46068E-06 -6.3366 0.46068E-06 -6.3366 0.10000E+01 0.0000 81 HCl,aq 0.13396E-05 -5.8730 0.13396E-05 -5.8730 0.10000E+01 0.0000 90 CuCl,aq 0.17397E-08 -8.7595 0.17397E-08 -8.7595 0.10000E+01 0.0000 91 CuCl2- 0.25927E-07 -7.5862 0.14955E-07 -7.8252 0.57682E+00 -0.2390 92 CuCl3-2 0.41410E-08 -8.3829 0.33127E-09 -9.4798 0.79997E-01 -1.0969 98 HF,aq 0.59601E-04 -4.2247 0.59601E-04 -4.2247 0.10000E+01 0.0000 99 HF2- 0.16340E-07 -7.7867 0.94255E-08 -8.0257 0.57682E+00 -0.2390 101 FeCl+ 0.18417E-06 -6.7348 0.10865E-06 -6.9640 0.58998E+00 -0.2292 102 FeCl2,aq 0.80584E-10 -10.0938 0.80584E-10 -10.0938 0.10000E+01 0.0000 104 FeF+ 0.52817E-08 -8.2772 0.31161E-08 -8.5064 0.58998E+00 -0.2292 107 FeOH+ 0.35438E-08 -8.4505 0.20908E-08 -8.6797 0.58998E+00 -0.2292 113 H2,aq 0.28895E-07 -7.5392 0.26078E-07 -7.5837 0.90251E+00 -0.0446 114 KCl,aq 0.40005E-03 -3.3979 0.40005E-03 -3.3979 0.10000E+01 0.0000 115 KHSO4,aq 0.42956E-10 -10.3670 0.42956E-10 -10.3670 0.10000E+01 0.0000 116 KOH,aq 0.74218E-08 -8.1295 0.74218E-08 -8.1295 0.10000E+01 0.0000 117 KSO4- 0.88349E-05 -5.0538 0.50961E-05 -5.2928 0.57682E+00 -0.2390 118 MgCO3,aq 0.66947E-08 -8.1743 0.66947E-08 -8.1743 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.68944E-05 -5.1615 0.40675E-05 -5.3907 0.58998E+00 -0.2292 120 MgCl+ 0.16644E-04 -4.7788 0.98194E-05 -5.0079 0.58998E+00 -0.2292 121 MgF+ 0.70177E-06 -6.1538 0.41403E-06 -6.3830 0.58998E+00 -0.2292 122 MgOH+ 0.61635E-08 -8.2102 0.36363E-08 -8.4393 0.58998E+00 -0.2292 124 MnF+ 0.20845E-07 -7.6810 0.12298E-07 -7.9102 0.58998E+00 -0.2292 126 MnOH+ 0.44714E-08 -8.3496 0.26380E-08 -8.5787 0.58998E+00 -0.2292 131 MnCl+ 0.14038E-04 -4.8527 0.82823E-05 -5.0818 0.58998E+00 -0.2292 132 MnSO4,aq 0.42935E-08 -8.3672 0.42935E-08 -8.3672 0.10000E+01 0.0000 133 NaCl,aq 0.13820E+00 -0.8595 0.13820E+00 -0.8595 0.10000E+01 0.0000 134 NaF,aq 0.10135E-03 -3.9942 0.10135E-03 -3.9942 0.10000E+01 0.0000 135 NaOH,aq 0.17976E-06 -6.7453 0.17976E-06 -6.7453 0.10000E+01 0.0000 137 OH- 0.75948E-06 -6.1195 0.42796E-06 -6.3686 0.56350E+00 -0.2491 140 PbCl+ 0.33060E-07 -7.4807 0.19505E-07 -7.7099 0.58998E+00 -0.2292 141 PbCl2,aq 0.90495E-07 -7.0434 0.90495E-07 -7.0434 0.10000E+01 0.0000 142 PbCl3- 0.47088E-07 -7.3271 0.27161E-07 -7.5661 0.57682E+00 -0.2390 143 PbCl4-2 0.41910E-07 -7.3777 0.33527E-08 -8.4746 0.79997E-01 -1.0969 144 PbF+ 0.59224E-10 -10.2275 0.34941E-10 -10.4567 0.58998E+00 -0.2292 148 Pb(HS)2,aq 0.49248E-10 -10.3076 0.49248E-10 -10.3076 0.10000E+01 0.0000 150 H2S,aq 0.61269E-05 -5.2128 0.55296E-05 -5.2573 0.90251E+00 -0.0446 158 HSO3- 0.40595E-10 -10.3915 0.23416E-10 -10.6305 0.57682E+00 -0.2390 159 HSO4- 0.41290E-06 -6.3842 0.24660E-06 -6.6080 0.59724E+00 -0.2239 173 ZnCl+ 0.25084E-05 -5.6006 0.14799E-05 -5.8298 0.58998E+00 -0.2292 174 ZnCl2,aq 0.48930E-06 -6.3104 0.48930E-06 -6.3104 0.10000E+01 0.0000 175 ZnCl3- 0.55824E-07 -7.2532 0.32200E-07 -7.4921 0.57682E+00 -0.2390 176 ZnF+ 0.19210E-09 -9.7165 0.11334E-09 -9.9456 0.58998E+00 -0.2292 177 ZnO,aq 0.26542E-10 -10.5761 0.26542E-10 -10.5761 0.10000E+01 0.0000 178 ZnOH+ 0.68331E-07 -7.1654 0.40314E-07 -7.3945 0.58998E+00 -0.2292 Charge balance for all species = -.8924E-04 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1304007E-04 0.2226974E+00 0.2089462E+03 0.0000 2 H2O 0.1000000E+01 0.5528568E+02 0.9271260E+06 0.0000 3 Cl- 0.9250874E+00 0.1064037E+01 0.3511512E+05 4.8588 4 SO4-- 0.1201743E-03 0.1298795E-03 0.1161382E+02 5.2560 5 HCO3- 0.1830388E-01 0.2409320E+00 0.1368457E+05 3.1630 6 HS- 0.4963477E-06 0.6636349E-05 0.2043028E+00 -1.4108 7 H4SiO4 0.1931413E-02 0.1935122E-02 0.1731354E+03 -2.7141 8 Al+++ 0.5902388E-12 0.2949168E-07 0.7407134E-03 0.6593 9 Ca++ 0.1069641E-02 0.1449486E-02 0.5407600E+02 6.1683 10 Mg++ 0.9401549E-04 0.1182685E-03 0.2676544E+01 5.0894 11 Fe++ 0.8937583E-06 0.1086836E-05 0.5650000E-01 3.0729 12 K+ 0.3088849E-01 0.3129738E-01 0.1139178E+04 3.3911 13 Na+ 0.9108591E+00 0.1049164E+01 0.2245241E+05 4.8506 14 Mn++ 0.9670139E-05 0.2373814E-04 0.1213959E+01 4.1113 15 Zn++ 0.5020454E-07 0.3172309E-05 0.1930361E+00 1.8225 16 Cu+ 0.1203591E-11 0.3180926E-07 0.1881418E-02 -7.0286 17 Pb++ 0.4006184E-08 0.2166702E-06 0.4178810E-01 0.7564 18 Ag+ 0.3621467E-11 0.3989995E-07 0.4006430E-02 -6.5418 19 Au+ 0.6009656E-22 0.2141954E-11 0.3927248E-06 -17.3187 20 Ba++ 0.1681706E-05 0.2798415E-05 0.3577616E+00 3.3891 21 F- 0.9566579E-03 0.1120933E-02 0.1982312E+02 1.8618 22 H2AsO3- 0.2267112E-06 0.8925956E-04 0.1038068E+02 -1.6789 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234443E+00 -.9095820E-05 0.0000000E+00 2 H2O 0.8029657E+02 0.8029657E+02 -.1239576E-07 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886362E-03 0.3098939E-08 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.9638590E-05 0.4391721E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810559E-02 0.1182223E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.4283352E-07 0.2364445E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1578514E-05 0.2479151E-07 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.4607442E-05 0.2860735E-05 0.0000000E+00 16 Cu+ 0.1701571E-06 0.4619956E-07 0.1239576E-06 0.0000000E+00 17 Pb++ 0.1565021E-05 0.3146904E-06 0.1250330E-05 0.0000000E+00 18 Ag+ 0.4271281E-06 0.5795042E-07 0.3691777E-06 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1628036E-02 0.2364445E-05 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.156027E+04 g Temperature = 147.68 C Pressure = 500.00 bar Mixer frac. = 0.4500000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) argentite 0.1846E-06 -6.734 0.4574E-04 -4.340 5.358 0.6423E-05 bornite 0.2479E-07 -7.606 0.1244E-04 -4.905 1.457 0.2447E-05 topaz 0.1182E-05 -5.927 0.2176E-03 -3.662 25.49 0.6091E-04 galena 0.1250E-05 -5.903 0.2991E-03 -3.524 35.04 0.3937E-04 sphalerite 0.2861E-05 -5.544 0.2787E-03 -3.555 32.65 0.6816E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity argentite 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 topaz 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.4500000 Solid products produced: Mass = 0.000854 g Volume = 0.000177 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.400 AFFINITY: 0.2877E+03 GOLD Q/K: 0.0695 SILVER Q/K: 0.1640 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 147.6775 deg.C Sat. pressure: 60.6006 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1206E+00 0.7310 0.5343E+01 0.7310E+01 CO2,gas 0.8794E+00 0.9023 0.4808E+02 0.5329E+02 CH4,gas 0.1083E-07 1.0642 0.6984E-06 0.6563E-06 H2,gas 0.6053E-06 1.0291 0.3775E-04 0.3668E-04 H2S,gas 0.6005E-05 0.8502 0.3094E-03 0.3639E-03 S2,gas 0.2165E-16 1.0000 0.1312E-14 0.1312E-14 CO,gas 0.6629E-08 1.0000 0.4017E-06 0.4017E-06 SO3,gas 0.4243E-28 1.0000 0.2571E-26 0.2571E-26 O2,gas 0.1586E-46 1.0000 0.9609E-45 0.9609E-45 SO2,gas 0.6168E-13 1.0000 0.3738E-11 0.3738E-11 HF,gas 0.1518E-07 1.0000 0.9199E-06 0.9199E-06 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 196 argentite -24.76 -24.76 0.00 0.000 0.00000E+00 205 bornite -79.21 -79.21 0.00 0.000 0.00000E+00 225 topaz -18.20 -18.20 0.00 0.000 0.00000E+00 260 galena -10.92 -10.92 0.00 0.000 0.00000E+00 272 sphalerite -9.85 -9.85 0.00 0.000 0.34206E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.96 -0.02 -1.97 -1.971 0.37958E+04 0.728 2 CO2,gas -6.07 -7.08 -1.02 -0.339 0.19583E+04 1.682 3 CH4,gas 5.34 -3.52 -8.85 -2.214 0.17051E+05 -6.156 4 H2,gas 8.01 0.88 -7.12 -4.070 0.13714E+05 -4.423 5 H2S,gas -5.47 -11.67 -6.21 -3.104 0.11955E+05 -3.509 6 S2,gas -7.53 -25.12 -17.58 -2.705 0.33855E+05 -14.882 7 CO,gas 2.91 -6.19 -9.10 -2.798 0.17514E+05 -6.396 8 SO3,gas 14.03 -15.25 -29.29 -7.322 0.56400E+05 -26.590 9 O2,gas 45.92 -1.80 -47.72 -31.811 0.91884E+05 -45.017 10 SO2,gas -0.23 -14.36 -14.13 -3.767 0.27202E+05 -11.427 11 HF,gas 0.33 -8.40 -8.74 -4.368 0.16821E+05 -6.036 12 HCl,gas 2.01 -5.40 -7.42 -3.708 0.14282E+05 -7.417 13 acmite 6.87 2.08 -4.78 -0.497 0.92072E+04 17 albite-high -0.32 -2.57 -2.26 -0.174 0.43433E+04 18 albite -1.17 -2.57 -1.40 -0.108 0.26920E+04 22 analcite 2.14 0.10 -2.04 -0.227 0.39311E+04 23 andalusite 1.85 -1.41 -3.27 -0.327 0.62872E+04 26 anhydrite -5.84 -9.10 -3.26 -1.632 0.62839E+04 27 ankerite -2.92 -4.96 -2.04 -0.340 0.39329E+04 34 aragonite 0.50 -0.93 -1.43 -0.478 0.27589E+04 36 calcite 0.36 -0.93 -1.29 -0.431 0.24915E+04 37 carnegieite-low 7.11 2.80 -4.32 -0.617 0.83113E+04 39 carpholite-Mg 5.14 0.95 -4.19 -0.280 0.80779E+04 40 carpholite-Fe 3.47 -1.07 -4.54 -0.303 0.87383E+04 50 chloritoid-Fe 5.44 1.63 -3.81 -0.254 0.73299E+04 51 chloritoid-Mn 7.63 2.67 -4.97 -0.331 0.95613E+04 53 coesite -2.06 -2.68 -0.62 -0.207 0.11951E+04 58 corundum 4.79 1.27 -3.52 -0.320 0.67735E+04 60 cristobalite -2.24 -2.68 -0.45 -0.149 0.86052E+03 63 cymrite-K 0.80 -4.05 -4.84 -0.404 0.93247E+04 65 diaspore 1.39 0.63 -0.76 -0.127 0.14722E+04 66 diamond -2.57 -5.29 -2.72 -0.778 0.52401E+04 69 dolomite,ordered -0.52 -2.94 -2.43 -0.404 0.46731E+04 83 gibbsite 2.60 0.61 -1.98 -0.283 0.38200E+04 86 goethite 5.38 2.60 -2.78 -0.602 0.53618E+04 87 graphite -2.97 -5.29 -2.32 -0.661 0.44580E+04 90 halite 1.53 -0.55 -2.08 -1.042 0.40136E+04 92 heulandite -7.16 -11.45 -4.29 -0.195 0.82694E+04 96 jadeite 2.95 0.11 -2.84 -0.284 0.54633E+04 98 kalsilite 5.90 1.34 -4.56 -0.652 0.87867E+04 99 kaolinite -3.22 -4.13 -0.90 -0.082 0.17386E+04 100 kyanite 1.76 -1.41 -3.17 -0.317 0.60999E+04 102 laumontite 0.62 -3.37 -3.99 -0.266 0.76766E+04 103 lawsonite 6.40 2.03 -4.38 -0.292 0.84270E+04 104 leucite 2.79 -1.35 -4.13 -0.413 0.79585E+04 107 magnesite -0.04 -2.01 -1.97 -0.657 0.37958E+04 117 microcline -2.89 -4.03 -1.14 -0.088 0.21941E+04 121 muscovite -0.80 -2.77 -1.97 -0.116 0.37963E+04 122 paragonite 0.57 -1.31 -1.88 -0.111 0.36219E+04 123 nepheline 6.48 2.80 -3.68 -0.526 0.70889E+04 143 pyrite -19.91 -21.16 -1.25 -0.294 0.24071E+04 144 pyrrhotite -4.52 -8.60 -4.08 -1.360 0.78578E+04 145 pyrrhotiteFe0.875 -6.04 -9.09 -3.05 -1.123 0.58791E+04 146 pyroxmangite 6.38 1.41 -4.97 -0.994 0.95684E+04 147 pyrophyllite -7.64 -9.48 -1.84 -0.115 0.35410E+04 148 quartz -2.60 -2.68 -0.08 -0.026 0.15229E+03 153 rhodochrosite -1.31 -2.99 -1.67 -0.558 0.32239E+04 155 sanidine -1.82 -4.03 -2.21 -0.170 0.42620E+04 157 siderite -2.96 -4.03 -1.06 -0.355 0.20500E+04 158 sillimanite 2.06 -1.41 -3.47 -0.347 0.66818E+04 165 stilbite -7.81 -11.47 -3.66 -0.174 0.70478E+04 171 sulfur -8.66 -12.56 -3.90 -1.200 0.75087E+04 172 sylvite 1.46 -2.01 -3.47 -1.734 0.66794E+04 180 topaz-H 1.85 -1.43 -3.27 -0.297 0.63011E+04 181 tridymite -2.28 -2.68 -0.41 -0.135 0.78029E+03 184 troilite-low -4.62 -8.60 -3.98 -1.326 0.76629E+04 190 wairakite 1.28 -3.34 -4.62 -0.272 0.89006E+04 197 arsenic -6.26 -10.57 -4.31 -1.112 0.82944E+04 200 beidellite-Ca -4.10 -7.37 -3.26 -0.202 0.62863E+04 201 beidellite-H -4.66 -8.38 -3.72 -0.238 0.71684E+04 202 beidellite-K -3.80 -7.26 -3.46 -0.212 0.66707E+04 203 beidellite-Mg -4.32 -7.54 -3.23 -0.200 0.62160E+04 204 beidellite-Na -3.68 -6.78 -3.10 -0.190 0.59728E+04 207 chalcedony -2.44 -2.68 -0.24 -0.082 0.47164E+03 208 chalcocite -24.55 -25.73 -1.19 -0.296 0.22821E+04 210 covellite -17.78 -19.14 -1.37 -0.521 0.26326E+04 211 dawsonite 0.79 -1.62 -2.41 -0.301 0.46342E+04 213 montmorillonite-Ca -3.92 -7.00 -3.07 -0.190 0.59170E+04 214 montmorillonite-K -3.71 -6.90 -3.19 -0.195 0.61356E+04 215 montmorillonite-Mg -4.14 -7.17 -3.04 -0.188 0.58447E+04 216 montmorillonite-Na -3.53 -6.41 -2.88 -0.176 0.55494E+04 229 gypsum -5.17 -9.13 -3.97 -0.992 0.76372E+04 245 acanthite -24.61 -24.76 -0.14 -0.036 0.27622E+03 251 barite -9.33 -11.88 -2.55 -1.275 0.49102E+04 252 boehmite 2.67 0.63 -2.04 -0.340 0.39246E+04 253 cerussite -2.71 -6.34 -3.63 -1.211 0.69933E+04 254 chalcopyrite -26.19 -27.75 -1.55 -0.289 0.29891E+04 256 copper,native -2.23 -6.59 -4.36 -1.517 0.83972E+04 257 dolomite,disordered 0.04 -2.94 -2.98 -0.497 0.57422E+04 259 fluorite -9.87 -10.63 -0.76 -0.254 0.14655E+04 261 gold,native -15.72 -16.88 -1.16 -0.403 0.22294E+04 262 silver,native -5.31 -6.10 -0.79 -0.273 0.15120E+04 269 silica-amorphous -1.82 -2.68 -0.86 -0.287 0.16591E+04 270 smithsonite -1.24 -5.28 -4.04 -1.346 0.77774E+04 273 wurtzite -8.23 -9.85 -1.62 -0.542 0.31289E+04 275 an20ab80 0.56 -1.64 -2.20 -0.170 0.42434E+04 276 an25ab75 1.02 -1.41 -2.43 -0.187 0.46833E+04 277 an30ab70 1.48 -1.18 -2.67 -0.205 0.51345E+04 Calculations done for 147.6775 Deg. C; 500.0000 bar Mixer fraction: 0.4500000 Temperature Stoc.ionic strength Heat per mole Actual solution: 147.678 .12016E+01 2.818 Mixing solution: 25.000 .50000E-10 0.646 Fract. of mixing solution added: 0.050000 BITMOL = 0.2775E+01 OLDMOL = 0.8203E+02 New heat: 2.746 New temperature: 143.723 New mixer fraction: 0.5000000 Resulting temperature: 143.723Deg. C Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1296E-03 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Test file for CHIM-XPT. Mixing of cold water into metal bearing water starting at 199.97 C. Illustrates fluid-fluid mixing. CHIMRUN demo-3 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 70 Temperature = 143.72 C Pressure = 500.00 bar Mixer fraction = 0.5000000 Water: Moles liquid = 0.8340E+02 kg liquid = 0.1502E+01 Moles total = 0.8307E+02 kg total = 0.1497E+01 Activity = 0.9662 Stoichiometric ionic strength = .1161453E+01 Osmotic coef. = 0.9280 True ionic strength = .9210274E+00 Chg. balance for total moles = -.1296E-03 Max. difference allowed = 0.1545E-03 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13687E-04 -4.8637 0.78530E-05 -5.1050 0.57375E+00 -0.2413 2 H2O 0.96619E+00 -0.0149 0.96619E+00 -0.0149 3 Cl- 0.90092E+00 -0.0453 0.52347E+00 -0.2811 0.58104E+00 -0.2358 4 SO4-- 0.11651E-03 -3.9336 0.10021E-04 -4.9991 0.86006E-01 -1.0655 5 HCO3- 0.17700E-01 -1.7520 0.10455E-01 -1.9807 0.59069E+00 -0.2286 6 HS- 0.44566E-06 -6.3510 0.25938E-06 -6.5861 0.58201E+00 -0.2351 7 H4SiO4 0.18674E-02 -2.7288 0.18674E-02 -2.7288 0.10000E+01 0.0000 8 Al+++ 0.75379E-12 -12.1228 0.26534E-14 -14.5762 0.35202E-02 -2.4534 9 Ca++ 0.10496E-02 -2.9790 0.83180E-04 -4.0800 0.79246E-01 -1.1010 10 Mg++ 0.91629E-04 -4.0380 0.69149E-05 -5.1602 0.75466E-01 -1.1222 11 Fe++ 0.86962E-06 -6.0607 0.66400E-07 -7.1778 0.76355E-01 -1.1172 12 K+ 0.29896E-01 -1.5244 0.17684E-01 -1.7524 0.59151E+00 -0.2280 13 Na+ 0.88712E+00 -0.0520 0.51351E+00 -0.2895 0.57885E+00 -0.2374 14 Mn++ 0.98335E-05 -5.0073 0.75752E-06 -6.1206 0.77034E-01 -1.1133 15 Zn++ 0.53422E-07 -7.2723 0.40791E-08 -8.3894 0.76355E-01 -1.1172 16 Cu+ 0.98913E-12 -12.0047 0.57222E-12 -12.2424 0.57851E+00 -0.2377 17 Pb++ 0.37995E-08 -8.4203 0.31073E-09 -9.5076 0.81783E-01 -1.0873 18 Ag+ 0.29370E-11 -11.5321 0.17299E-11 -11.7620 0.58902E+00 -0.2299 19 Au+ 0.45870E-22 -22.3385 0.27198E-22 -22.5655 0.59294E+00 -0.2270 20 Ba++ 0.16822E-05 -5.7741 0.14049E-06 -6.8523 0.83519E-01 -1.0782 21 F- 0.93033E-03 -3.0314 0.52822E-03 -3.2772 0.56777E+00 -0.2458 22 H2AsO3- 0.18941E-06 -6.7226 0.12907E-06 -6.8892 0.68146E+00 -0.1666 24 HSiO3- 0.86498E-06 -6.0630 0.50259E-06 -6.2988 0.58104E+00 -0.2358 25 Ca(HSiO3)+ 0.29949E-08 -8.5236 0.17758E-08 -8.7506 0.59294E+00 -0.2270 26 Mg(HSiO3)+ 0.25770E-09 -9.5889 0.15280E-09 -9.8159 0.59294E+00 -0.2270 27 NaHSiO3,aq 0.24547E-05 -5.6100 0.24547E-05 -5.6100 0.10000E+01 0.0000 31 AgCl,aq 0.50347E-09 -9.2980 0.50347E-09 -9.2980 0.10000E+01 0.0000 32 AgCl2- 0.17777E-07 -7.7501 0.10329E-07 -7.9859 0.58104E+00 -0.2358 33 AgCl3-2 0.77225E-08 -8.1122 0.65009E-09 -9.1870 0.84181E-01 -1.0748 34 AgCl4-3 0.61212E-09 -9.2132 0.22164E-11 -11.6543 0.36209E-02 -2.4412 38 Ag(HS),aq 0.50723E-08 -8.2948 0.50723E-08 -8.2948 0.10000E+01 0.0000 40 AlO+ 0.16344E-09 -9.7866 0.96909E-10 -10.0136 0.59294E+00 -0.2270 41 AlOH+2 0.13726E-10 -10.8625 0.10684E-11 -11.9713 0.77839E-01 -1.1088 42 HAlO2,aq 0.85193E-08 -8.0696 0.85193E-08 -8.0696 0.10000E+01 0.0000 43 AlO2- 0.13831E-07 -7.8591 0.78743E-08 -8.1038 0.56932E+00 -0.2446 44 AsO2- 0.62639E-07 -7.2032 0.36396E-07 -7.4389 0.58104E+00 -0.2358 45 HAsO2,aq 0.28583E-04 -4.5439 0.28583E-04 -4.5439 0.10000E+01 0.0000 46 H3AsO3,aq 0.57454E-04 -4.2407 0.57454E-04 -4.2407 0.10000E+01 0.0000 48 H2AsO4- 0.22170E-10 -10.6542 0.12882E-10 -10.8900 0.58104E+00 -0.2358 62 BaCO3,aq 0.16699E-09 -9.7773 0.16699E-09 -9.7773 0.10000E+01 0.0000 63 Ba(HCO3)+ 0.55000E-06 -6.2596 0.32984E-06 -6.4817 0.59972E+00 -0.2221 64 BaCl+ 0.47235E-06 -6.3257 0.28007E-06 -6.5527 0.59294E+00 -0.2270 65 BaF+ 0.60617E-09 -9.2174 0.35942E-09 -9.4444 0.59294E+00 -0.2270 66 CH4,aq 0.28936E-09 -9.5386 0.26112E-09 -9.5832 0.90242E+00 -0.0446 71 CO,aq 0.16955E-09 -9.7707 0.16955E-09 -9.7707 0.10000E+01 0.0000 72 CO2,aq 0.21513E+00 -0.6673 0.19414E+00 -0.7119 0.90242E+00 -0.0446 73 CO3-2 0.18588E-05 -5.7308 0.15647E-06 -6.8056 0.84181E-01 -1.0748 74 CaCO3,aq 0.39928E-06 -6.3987 0.39928E-06 -6.3987 0.10000E+01 0.0000 75 Ca(HCO3)+ 0.76373E-04 -4.1171 0.45284E-04 -4.3441 0.59294E+00 -0.2270 76 CaCl+ 0.25542E-03 -3.5928 0.15145E-03 -3.8197 0.59294E+00 -0.2270 77 CaCl2,aq 0.16581E-04 -4.7804 0.16581E-04 -4.7804 0.10000E+01 0.0000 78 CaF+ 0.23721E-05 -5.6249 0.14065E-05 -5.8519 0.59294E+00 -0.2270 79 CaOH+ 0.14186E-07 -7.8481 0.84117E-08 -8.0751 0.59294E+00 -0.2270 80 CaSO4,aq 0.45382E-06 -6.3431 0.45382E-06 -6.3431 0.10000E+01 0.0000 81 HCl,aq 0.13372E-05 -5.8738 0.13372E-05 -5.8738 0.10000E+01 0.0000 90 CuCl,aq 0.14223E-08 -8.8470 0.14223E-08 -8.8470 0.10000E+01 0.0000 91 CuCl2- 0.20653E-07 -7.6850 0.12000E-07 -7.9208 0.58104E+00 -0.2358 92 CuCl3-2 0.31758E-08 -8.4982 0.26734E-09 -9.5729 0.84181E-01 -1.0748 98 HF,aq 0.57090E-04 -4.2434 0.57090E-04 -4.2434 0.10000E+01 0.0000 99 HF2- 0.15319E-07 -7.8148 0.89011E-08 -8.0506 0.58104E+00 -0.2358 101 FeCl+ 0.17191E-06 -6.7647 0.10193E-06 -6.9917 0.59294E+00 -0.2270 102 FeCl2,aq 0.54849E-10 -10.2608 0.54849E-10 -10.2608 0.10000E+01 0.0000 104 FeF+ 0.49918E-08 -8.3017 0.29598E-08 -8.5287 0.59294E+00 -0.2270 107 FeOH+ 0.29761E-08 -8.5263 0.17647E-08 -8.7533 0.59294E+00 -0.2270 113 H2,aq 0.23266E-07 -7.6333 0.20996E-07 -7.6779 0.90242E+00 -0.0446 114 KCl,aq 0.35202E-03 -3.4534 0.35202E-03 -3.4534 0.10000E+01 0.0000 115 KHSO4,aq 0.35676E-10 -10.4476 0.35676E-10 -10.4476 0.10000E+01 0.0000 116 KOH,aq 0.59957E-08 -8.2222 0.59957E-08 -8.2222 0.10000E+01 0.0000 117 KSO4- 0.81994E-05 -5.0862 0.47642E-05 -5.3220 0.58104E+00 -0.2358 118 MgCO3,aq 0.60347E-08 -8.2193 0.60347E-08 -8.2193 0.10000E+01 0.0000 119 Mg(HCO3)+ 0.63633E-05 -5.1963 0.37730E-05 -5.4233 0.59294E+00 -0.2270 120 MgCl+ 0.15675E-04 -4.8048 0.92940E-05 -5.0318 0.59294E+00 -0.2270 121 MgF+ 0.65461E-06 -6.1840 0.38814E-06 -6.4110 0.59294E+00 -0.2270 122 MgOH+ 0.49660E-08 -8.3040 0.29445E-08 -8.5310 0.59294E+00 -0.2270 124 MnF+ 0.20404E-07 -7.6903 0.12098E-07 -7.9173 0.59294E+00 -0.2270 126 MnOH+ 0.38677E-08 -8.4125 0.22933E-08 -8.6395 0.59294E+00 -0.2270 131 MnCl+ 0.13086E-04 -4.8832 0.77592E-05 -5.1102 0.59294E+00 -0.2270 132 MnSO4,aq 0.43477E-08 -8.3617 0.43477E-08 -8.3617 0.10000E+01 0.0000 133 NaCl,aq 0.12703E+00 -0.8961 0.12703E+00 -0.8961 0.10000E+01 0.0000 134 NaF,aq 0.93118E-04 -4.0310 0.93118E-04 -4.0310 0.10000E+01 0.0000 135 NaOH,aq 0.14858E-06 -6.8280 0.14858E-06 -6.8280 0.10000E+01 0.0000 137 OH- 0.64516E-06 -6.1903 0.36730E-06 -6.4350 0.56932E+00 -0.2446 140 PbCl+ 0.30118E-07 -7.5212 0.17858E-07 -7.7482 0.59294E+00 -0.2270 141 PbCl2,aq 0.77958E-07 -7.1081 0.77958E-07 -7.1081 0.10000E+01 0.0000 142 PbCl3- 0.38764E-07 -7.4116 0.22524E-07 -7.6474 0.58104E+00 -0.2358 143 PbCl4-2 0.32697E-07 -7.4855 0.27524E-08 -8.5603 0.84181E-01 -1.0748 144 PbF+ 0.55208E-10 -10.2580 0.32735E-10 -10.4850 0.59294E+00 -0.2270 148 Pb(HS)2,aq 0.42492E-10 -10.3717 0.42492E-10 -10.3717 0.10000E+01 0.0000 150 H2S,aq 0.57606E-05 -5.2395 0.51985E-05 -5.2841 0.90242E+00 -0.0446 158 HSO3- 0.33462E-10 -10.4755 0.19443E-10 -10.7112 0.58104E+00 -0.2358 159 HSO4- 0.39091E-06 -6.4079 0.23454E-06 -6.6298 0.59998E+00 -0.2219 173 ZnCl+ 0.23053E-05 -5.6373 0.13669E-05 -5.8643 0.59294E+00 -0.2270 174 ZnCl2,aq 0.43554E-06 -6.3610 0.43554E-06 -6.3610 0.10000E+01 0.0000 175 ZnCl3- 0.48843E-07 -7.3112 0.28380E-07 -7.5470 0.58104E+00 -0.2358 176 ZnF+ 0.19793E-09 -9.7035 0.11736E-09 -9.9305 0.59294E+00 -0.2270 177 ZnO,aq 0.20144E-10 -10.6959 0.20144E-10 -10.6959 0.10000E+01 0.0000 178 ZnOH+ 0.59245E-07 -7.2273 0.35128E-07 -7.4543 0.59294E+00 -0.2270 Charge balance for all species = -.8627E-04 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1368714E-04 0.2152862E+00 0.2024585E+03 0.0000 2 H2O 0.1000000E+01 0.5529309E+02 0.9293888E+06 0.0000 3 Cl- 0.9009206E+00 0.1028625E+01 0.3402478E+05 4.8239 4 SO4-- 0.1165145E-03 0.1255570E-03 0.1125319E+02 5.2108 5 HCO3- 0.1769970E-01 0.2329137E+00 0.1325966E+05 3.1243 6 HS- 0.4456621E-06 0.6217624E-05 0.1918536E+00 -1.4811 7 H4SiO4 0.1867395E-02 0.1870718E-02 0.1677592E+03 -2.7288 8 Al+++ 0.7537861E-12 0.2252816E-07 0.5671225E-03 0.7387 9 Ca++ 0.1049633E-02 0.1401246E-02 0.5239690E+02 6.1299 10 Mg++ 0.9162876E-04 0.1143325E-03 0.2593436E+01 5.0497 11 Fe++ 0.8696241E-06 0.1049566E-05 0.5468834E-01 3.0321 12 K+ 0.2989557E-01 0.3025580E-01 0.1103806E+04 3.3525 13 Na+ 0.8871219E+00 0.1014247E+01 0.2175525E+05 4.8155 14 Mn++ 0.9833488E-05 0.2294813E-04 0.1176265E+01 4.0893 15 Zn++ 0.5342204E-07 0.2902594E-05 0.1770312E+00 1.8205 16 Cu+ 0.9891254E-12 0.2525181E-07 0.1497010E-02 -7.1375 17 Pb++ 0.3799496E-08 0.1834365E-06 0.3546007E-01 0.7023 18 Ag+ 0.2936982E-11 0.3169092E-07 0.3189485E-02 -6.6570 19 Au+ 0.4587030E-22 0.2070670E-11 0.3805304E-06 -17.4605 20 Ba++ 0.1682164E-05 0.2705283E-05 0.3466529E+00 3.3576 21 F- 0.9303303E-03 0.1083622E-02 0.1920750E+02 1.8278 22 H2AsO3- 0.1894083E-06 0.8628898E-04 0.1005835E+02 -1.7842 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3234352E+00 0.3234446E+00 -.9409414E-05 0.0000000E+00 2 H2O 0.8307198E+02 0.8307198E+02 -.1322190E-07 0.0000000E+00 3 Cl- 0.1545400E+01 0.1545400E+01 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1886393E-03 0.1886360E-03 0.3305474E-08 0.0000000E+00 5 HCO3- 0.3499280E+00 0.3499280E+00 0.0000000E+00 0.0000000E+00 6 HS- 0.1403031E-04 0.9341318E-05 0.4688993E-05 0.0000000E+00 7 H4SiO4 0.2811741E-02 0.2810554E-02 0.1186716E-05 0.0000000E+00 8 Al+++ 0.2407279E-05 0.3384616E-07 0.2373433E-05 0.0000000E+00 9 Ca++ 0.2105223E-02 0.2105223E-02 0.0000000E+00 0.0000000E+00 10 Mg++ 0.1717724E-03 0.1717724E-03 0.0000000E+00 0.0000000E+00 11 Fe++ 0.1603305E-05 0.1576861E-05 0.2644380E-07 0.0000000E+00 12 K+ 0.4545612E-01 0.4545612E-01 0.0000000E+00 0.0000000E+00 13 Na+ 0.1523798E+01 0.1523798E+01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3447712E-04 0.3447712E-04 0.0000000E+00 0.0000000E+00 15 Zn++ 0.7468176E-05 0.4360838E-05 0.3107338E-05 0.0000000E+00 16 Cu+ 0.1701571E-06 0.3793815E-07 0.1322190E-06 0.0000000E+00 17 Pb++ 0.1565021E-05 0.2755938E-06 0.1289427E-05 0.0000000E+00 18 Ag+ 0.4271281E-06 0.4761223E-07 0.3795159E-06 0.0000000E+00 19 Au+ 0.3110961E-11 0.3110961E-11 0.0000000E+00 0.0000000E+00 20 Ba++ 0.4064400E-05 0.4064400E-05 0.0000000E+00 0.0000000E+00 21 F- 0.1630400E-02 0.1628027E-02 0.2373433E-05 0.0000000E+00 22 H2AsO3- 0.1296400E-03 0.1296400E-03 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4235E-21 Mass of aqueous solution: 0.161027E+04 g Temperature = 143.72 C Pressure = 500.00 bar Mixer frac. = 0.5000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) argentite 0.1898E-06 -6.722 0.4702E-04 -4.328 5.284 0.6603E-05 bornite 0.2644E-07 -7.578 0.1327E-04 -4.877 1.491 0.2611E-05 topaz 0.1187E-05 -5.926 0.2184E-03 -3.661 24.54 0.6114E-04 galena 0.1289E-05 -5.890 0.3085E-03 -3.511 34.66 0.4060E-04 sphalerite 0.3107E-05 -5.508 0.3027E-03 -3.519 34.02 0.7404E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity argentite 0.1000E+01 0.1000E+01 1.0000 0.000 bornite 0.1000E+01 0.1000E+01 1.0000 0.000 topaz 0.1000E+01 0.1000E+01 1.0000 0.000 galena 0.1000E+01 0.1000E+01 1.0000 0.000 sphalerite 0.1000E+01 0.1000E+01 1.0000 0.000 Total fraction of mixing solution added: 0.5000000 Solid products produced: Mass = 0.000890 g Volume = 0.000185 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Estimated lowest electrum affinity for X gold = 0.400 AFFINITY: 0.2668E+03 GOLD Q/K: 0.0786 SILVER Q/K: 0.1536 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 143.7232 deg.C Sat. pressure: 57.7469 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1129E+00 0.7397 0.4824E+01 0.6522E+01 CO2,gas 0.8871E+00 0.9029 0.4625E+02 0.5122E+02 CH4,gas 0.1011E-07 1.0598 0.6184E-06 0.5836E-06 H2,gas 0.5273E-06 1.0280 0.3130E-04 0.3045E-04 H2S,gas 0.5871E-05 0.8529 0.2892E-03 0.3391E-03 S2,gas 0.1816E-16 1.0000 0.1049E-14 0.1049E-14 CO,gas 0.5512E-08 1.0000 0.3183E-06 0.3183E-06 SO3,gas 0.2488E-28 1.0000 0.1437E-26 0.1437E-26 O2,gas 0.5310E-47 1.0000 0.3066E-45 0.3066E-45 SO2,gas 0.4897E-13 1.0000 0.2828E-11 0.2828E-11 HF,gas 0.1356E-07 1.0000 0.7830E-06 0.7830E-06 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 196 argentite -25.01 -25.01 0.00 0.000 0.00000E+00 205 bornite -79.85 -79.85 0.00 0.000 0.00000E+00 225 topaz -18.02 -18.02 0.00 0.000 0.00000E+00 260 galena -10.99 -10.99 0.00 0.000 0.33885E-11 272 sphalerite -9.87 -9.87 0.00 0.000 -0.33885E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 2.00 -0.01 -2.02 -2.016 0.38447E+04 0.683 2 CO2,gas -6.04 -7.07 -1.03 -0.345 0.19721E+04 1.665 3 CH4,gas 5.33 -3.58 -8.91 -2.227 0.16992E+05 -6.209 4 H2,gas 8.07 0.86 -7.20 -4.116 0.13741E+05 -4.504 5 H2S,gas -5.45 -11.69 -6.24 -3.119 0.11899E+05 -3.539 6 S2,gas -7.43 -25.11 -17.68 -2.720 0.33722E+05 -14.979 7 CO,gas 3.00 -6.19 -9.20 -2.830 0.17542E+05 -6.497 8 SO3,gas 14.35 -15.19 -29.54 -7.385 0.56352E+05 -26.843 9 O2,gas 46.45 -1.76 -48.21 -32.142 0.91967E+05 -45.513 10 SO2,gas -0.07 -14.31 -14.25 -3.799 0.27178E+05 -11.549 11 HF,gas 0.42 -8.38 -8.81 -4.403 0.16796E+05 -6.106 12 HCl,gas 2.12 -5.39 -7.50 -3.752 0.14315E+05 -7.504 13 acmite 6.94 1.99 -4.95 -0.515 0.94499E+04 17 albite-high -0.21 -2.57 -2.36 -0.182 0.45098E+04 18 albite -1.08 -2.57 -1.49 -0.115 0.28423E+04 22 analcite 2.25 0.11 -2.14 -0.238 0.40864E+04 23 andalusite 2.13 -1.27 -3.39 -0.339 0.64732E+04 26 anhydrite -5.77 -9.08 -3.31 -1.656 0.63176E+04 27 ankerite -2.82 -5.01 -2.19 -0.364 0.41681E+04 34 aragonite 0.55 -0.96 -1.51 -0.503 0.28758E+04 36 calcite 0.41 -0.96 -1.37 -0.456 0.26113E+04 37 carnegieite-low 7.28 2.83 -4.45 -0.636 0.84934E+04 39 carpholite-Mg 5.44 1.04 -4.40 -0.293 0.83927E+04 40 carpholite-Fe 3.75 -0.98 -4.73 -0.315 0.90241E+04 50 chloritoid-Fe 5.76 1.74 -4.02 -0.268 0.76670E+04 53 coesite -2.08 -2.70 -0.62 -0.205 0.11752E+04 58 corundum 5.09 1.43 -3.66 -0.333 0.69772E+04 60 cristobalite -2.25 -2.70 -0.44 -0.148 0.84805E+03 63 cymrite-K 0.89 -4.05 -4.94 -0.412 0.94200E+04 65 diaspore 1.52 0.71 -0.81 -0.135 0.15422E+04 66 diamond -2.61 -5.31 -2.71 -0.773 0.51613E+04 69 dolomite,ordered -0.40 -2.99 -2.59 -0.431 0.49354E+04 83 gibbsite 2.72 0.69 -2.02 -0.289 0.38602E+04 86 goethite 5.47 2.57 -2.90 -0.627 0.55299E+04 87 graphite -3.01 -5.31 -2.30 -0.656 0.43827E+04 90 halite 1.54 -0.57 -2.11 -1.056 0.40285E+04 92 heulandite -6.99 -11.43 -4.45 -0.202 0.84792E+04 96 jadeite 3.06 0.13 -2.94 -0.294 0.56020E+04 98 kalsilite 6.05 1.36 -4.68 -0.669 0.89358E+04 99 kaolinite -3.05 -4.00 -0.95 -0.086 0.18101E+04 100 kyanite 2.02 -1.27 -3.29 -0.329 0.62769E+04 102 laumontite 0.84 -3.31 -4.15 -0.276 0.79090E+04 103 lawsonite 6.68 2.12 -4.56 -0.304 0.86970E+04 104 leucite 2.91 -1.34 -4.25 -0.425 0.81076E+04 107 magnesite 0.03 -2.04 -2.07 -0.689 0.39405E+04 117 microcline -2.83 -4.04 -1.21 -0.093 0.23024E+04 121 muscovite -0.49 -2.62 -2.13 -0.125 0.40574E+04 122 paragonite 0.90 -1.15 -2.05 -0.121 0.39176E+04 123 nepheline 6.64 2.83 -3.81 -0.545 0.72733E+04 143 pyrite -19.98 -21.21 -1.23 -0.290 0.23496E+04 144 pyrrhotite -4.49 -8.66 -4.17 -1.391 0.79609E+04 145 pyrrhotiteFe0.875 -6.02 -9.15 -3.12 -1.148 0.59526E+04 147 pyrophyllite -7.48 -9.38 -1.90 -0.118 0.36158E+04 148 quartz -2.63 -2.70 -0.07 -0.023 0.13388E+03 153 rhodochrosite -1.27 -3.00 -1.72 -0.574 0.32838E+04 155 sanidine -1.74 -4.04 -2.29 -0.176 0.43703E+04 157 siderite -2.92 -4.05 -1.13 -0.378 0.21633E+04 158 sillimanite 2.34 -1.27 -3.60 -0.360 0.68704E+04 165 stilbite -7.72 -11.45 -3.73 -0.178 0.71135E+04 171 sulfur -8.68 -12.56 -3.87 -1.192 0.73915E+04 172 sylvite 1.46 -2.03 -3.49 -1.745 0.66555E+04 180 topaz-H 2.08 -1.28 -3.36 -0.306 0.64162E+04 181 tridymite -2.30 -2.70 -0.40 -0.134 0.76624E+03 184 troilite-low -4.59 -8.66 -4.07 -1.356 0.77604E+04 190 wairakite 1.55 -3.28 -4.83 -0.284 0.92039E+04 197 arsenic -6.34 -10.65 -4.32 -1.114 0.82345E+04 200 beidellite-Ca -3.87 -7.24 -3.38 -0.209 0.64398E+04 201 beidellite-H -4.44 -8.25 -3.82 -0.244 0.72827E+04 202 beidellite-K -3.58 -7.15 -3.57 -0.218 0.68059E+04 203 beidellite-Mg -4.08 -7.42 -3.34 -0.207 0.63754E+04 204 beidellite-Na -3.46 -6.66 -3.21 -0.196 0.61198E+04 207 chalcedony -2.46 -2.70 -0.24 -0.079 0.45306E+03 208 chalcocite -24.78 -25.97 -1.19 -0.297 0.22670E+04 210 covellite -17.92 -19.26 -1.34 -0.510 0.25528E+04 211 dawsonite 0.87 -1.56 -2.43 -0.304 0.46400E+04 213 montmorillonite-Ca -3.76 -6.94 -3.19 -0.197 0.60787E+04 214 montmorillonite-K -3.55 -6.85 -3.29 -0.202 0.62835E+04 215 montmorillonite-Mg -3.97 -7.12 -3.15 -0.195 0.60121E+04 216 montmorillonite-Na -3.38 -6.37 -2.99 -0.183 0.57048E+04 229 gypsum -5.12 -9.11 -3.99 -0.996 0.76032E+04 245 acanthite -24.87 -25.01 -0.14 -0.035 0.26527E+03 251 barite -9.31 -11.85 -2.54 -1.271 0.48491E+04 252 boehmite 2.81 0.71 -2.10 -0.350 0.40097E+04 253 cerussite -2.71 -6.38 -3.68 -1.226 0.70145E+04 254 chalcopyrite -26.34 -27.92 -1.58 -0.294 0.30118E+04 256 copper,native -2.28 -6.71 -4.42 -1.538 0.84323E+04 257 dolomite,disordered 0.16 -2.99 -3.15 -0.526 0.60148E+04 259 fluorite -9.85 -10.63 -0.79 -0.263 0.15035E+04 261 gold,native -15.92 -17.03 -1.10 -0.384 0.21071E+04 262 silver,native -5.41 -6.22 -0.81 -0.283 0.15522E+04 269 silica-amorphous -1.83 -2.70 -0.86 -0.288 0.16481E+04 270 smithsonite -1.19 -5.27 -4.08 -1.360 0.77822E+04 273 wurtzite -8.23 -9.87 -1.64 -0.547 0.31288E+04 275 an20ab80 0.70 -1.63 -2.33 -0.179 0.44477E+04 276 an25ab75 1.18 -1.39 -2.57 -0.198 0.49008E+04 277 an30ab70 1.66 -1.16 -2.81 -0.216 0.53646E+04 Calculations done for 143.7232 Deg. C; 500.0000 bar Mixer fraction: 0.5000000 Temperature Stoc.ionic strength Heat per mole Actual solution: 143.723 .11615E+01 2.746 Mixing solution: 25.000 .50000E-10 0.646 Fract. of mixing solution added: 0.050000 BITMOL = 0.2775E+01 OLDMOL = 0.8481E+02 New heat: 2.680 New temperature: 140.015 New mixer fraction: 0.5500000 Resulting temperature: 140.015Deg. C Mixing fraction reached given limit of 0.5000E+00 TOTMIX = 0.5500E+00 Execution stopped.