File SKIP_SPECIES.TXT lists species and minerals omitted from the
calculations due to given T, P, option switches, or suppression
in CHIMRUN, or are suppressed in the SOLTHERM database.
It also lists minerals for which density is not specified
in SOLTHERM.
This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1).
methanol,aq is suppressed in SOLTHERM data file.
methanol,aq is suppressed in SOLTHERM data file.
CuCl4-3 is suppressed in SOLTHERM data file.
H2BO3- is suppressed in SOLTHERM data file.
UO2CO3,aq is suppressed in SOLTHERM data file.
UO2SO4,aq is suppressed in SOLTHERM data file.
UO2Cl2,aq is suppressed in SOLTHERM data file.
UO2F2,aq is suppressed in SOLTHERM data file.
PO4-3 is suppressed in SOLTHERM data file.
H2PO4- is suppressed in SOLTHERM data file.
H3PO4 is suppressed in SOLTHERM data file.
amesite is suppressed in SOLTHERM data file.
antigorite is suppressed in SOLTHERM data file.
sapphirine-Fe(221) is suppressed in SOLTHERM data file.
sapphirine(221) is suppressed in SOLTHERM data file.
talc-prl is suppressed in SOLTHERM data file.
PrO1.833(s) is suppressed in SOLTHERM data file.
niter-NH4 is suppressed in SOLTHERM data file.
FMQ_HS-1 is suppressed in THIS RUN.
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Species No. Charge Tot.moles Trial molality Gamma Mixing solution
H+ 1 1. 0.12020E-03 0.10244E-06 0.9818 0.00000000E+00
H2O 2 0. 0.55508E+02 0.10000E+01 1.0000 0.00000000E+00
Cl- 3 -1. 0.10000E-06 0.10000E-06 0.9818 0.00000000E+00
SO4-- 4 -2. 0.12000E-03 0.43237E-20 0.9802 0.00000000E+00
HCO3- 5 -1. 0.10000E-06 0.10000E-06 0.9818 0.00000000E+00
HS- 6 -1. -0.12000E-03 0.36416-158 0.9818 0.00000000E+00
Na+ 7 1. 0.10000E-06 0.10000E-06 0.9818 0.00000000E+00
F- 8 -1. 0.10000E-06 0.10000E-06 0.9818 0.00000000E+00
NH4+ 9 1. 0.10000E-49 0.24356-109 0.9818 0.00000000E+00
Chg. balance for total moles = -.1355E-19 Max. difference allowed = 0.1000E-10
The following parameters were given:
ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 1.0000
SLIM = 0.100000E-19 TEMP = 25.0000 SINC = 0.1000E-21
TEMPC = 0.0000 TOTMIX = 0.000000E+00 ENTH = 0.0000
SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000
SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 0.0000
SUPRNT = 0.1000-199 VBOX-1 = 1.0000 RHOFRS = 0.0000
RHOROC = 2.5000
The following options were selected:
CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 1
NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0
IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1
INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0
AWAT = 0 CHGF = 0
Of the derived species, only those with molality > 0.10-199 will appear in the output
Species No. Charge Log K(diss) Species No. Charge Log K(diss)
CH4,aq 10 0. 5.8930 NaCl,aq 40 0. 0.7770
C2H6,aq 11 0. 12.4490 NaF,aq 41 0. 0.9980
C3H8,aq 12 0. 17.2960 NaOH,aq 42 0. 14.2050
C4H10,aq 13 0. 22.1990 O2,aq 43 0. 69.1580
ethanol,aq 14 0. 16.7320 OH- 44 -1. 13.9950
CO,aq 15 0. 7.1210 HO2- 45 -1. 62.8880
CO2,aq 16 0. -6.3450 H2O2,aq 46 0. 51.2040
CO3-2 17 -2. 10.3290 H2S,aq 47 0. -6.9880
HCN,aq 18 0. 21.4760 S2-2 48 -2. 1.3120
CN- 19 -1. 30.7120 S3-2 49 -2. -10.2330
OCN- 20 -1. 16.5780 S3- 50 -1. -17.6990
SCN- 21 -1. 6.2370 S4-2 51 -2. -21.5580
HCl,aq 22 0. 0.7100 S5-2 52 -2. -32.6630
HClO,aq 23 0. 42.1310 SO2,aq 53 0. 2.9800
ClO- 24 -1. 49.6810 SO3-2 54 -2. 12.0450
HClO2,aq 25 0. 90.2870 HSO3- 55 -1. 4.8400
HF,aq 26 0. -3.1680 HSO4- 56 -1. -1.9790
HF2- 27 -1. -2.5510 HSO5- 57 -1. 51.8660
H2,aq 28 0. 11.5270 S2O3-2 58 -2. -4.7780
NH3,aq 29 0. 9.2410 HS2O3- 59 -1. -6.4630
HNO2,aq 30 0. 62.8880 H2S2O3,aq 60 0. -7.0500
NO2- 31 -1. 66.1130 S2O4-2 61 -2. 14.7190
HNO3,aq 32 0. 86.7600 HS2O4- 62 -1. 12.2260
NO3- 33 -1. 85.4580 H2S2O4,aq 63 0. 11.8600
N2,aq 34 0. 5.7590 S2O5-2 64 -2. 14.4970
N2O2-2 35 -2. 101.5910 S2O6-2 65 -2. 16.8410
HN2O2- 36 -1. 90.5960 S2O8-2 66 -2. 57.0790
H2N2O2,aq 37 0. 83.5590 S3O6-2 67 -2. 7.7880
N2H5+ 38 1. 33.8570 S4O6-2 68 -2. -17.1710
N2H6+2 39 2. 34.8840 S5O6-2 69 -2. -13.2500
For mixed gases (JSOLS=6), log K(hydrol) = log (K*P)
Log K Trial Log K Trial
Mineral No. hydrol Moles Mineral No. hydrol Moles
H2O,gas 1 1.511 0.0000E+00 SO2,gas 13 3.150 0.0000E+00
CO2,gas 2 -7.812 0.0000E+00 HF,gas 14 1.111 0.0000E+00
CH4,gas 3 2.976 0.0000E+00 HCl,gas 15 6.306 0.0000E+00
H2,gas 4 8.421 0.0000E+00 fCO2,1bar20C 16 -7.788 0.0000E+00
H2S,gas 5 -7.901 0.0000E+00 diamond 17 -4.477 0.0000E+00
S2,gas 6 -7.236 0.0000E+00 graphite 18 -4.986 0.0000E+00
CO,gas 7 4.114 0.0000E+00 halite 19 1.572 0.0000E+00
NO2,gas 8 76.516 0.0000E+00 sulfur 20 -10.519 0.0000E+00
SO3,gas 9 23.875 0.0000E+00 mascagnite 21 -0.023 0.0000E+00
O2,gas 10 66.258 0.0000E+00 niter-Na 22 81.636 0.0000E+00
NH3,gas 11 11.038 0.0000E+00 sodium-oxide 23 67.427 0.0000E+00
N2,gas 12 2.572 0.0000E+00 24 0.000 0.0000E+00
Initial composition of reactant (mole%):
N2 gas 100.0 0.000
Sum of wt% of reactants: 100.0000
Reactant consumed: 0.0000000 moles log =-100.0000
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
The following minerals and/or gases with identical index are in solid solution:
H2O,gas 6
CO2,gas 6
CH4,gas 6
H2,gas 6
H2S,gas 6
S2,gas 6
CO,gas 6
NO2,gas 6
SO3,gas 6
NH3,gas 6
N2,gas 6
SO2,gas 6
HF,gas 6
HCl,gas 6
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1355E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43266E-20 -20.3639 0.42388E-20 -20.3728 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77073-158 -158.1131 0.75659-158 -158.1211 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.10905-108 -108.9624 0.10705-108 -108.9704 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.40862-170 -170.3887 0.40862-170 -170.3887 0.10000E+01 0.0000
19 CN- 0.11359-172 -172.9446 0.11151-172 -172.9527 0.98165E+00 -0.0080
20 OCN- 0.90877-126 -126.0415 0.89210-126 -126.0496 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.28880-111 -111.5394 0.28879-111 -111.5394 0.99996E+00 0.0000
30 HNO2,aq 0.13209E-66 -66.8791 0.13209E-66 -66.8791 0.10000E+01 0.0000
31 NO2- 0.37662E-63 -63.4241 0.36971E-63 -63.4321 0.98165E+00 -0.0080
32 HNO3,aq 0.10422E-57 -57.9820 0.10422E-57 -57.9820 0.10000E+01 0.0000
33 NO3- 0.10000E-49 -50.0000 0.98165E-50 -50.0080 0.98165E+00 -0.0080
34 N2,aq 0.89425-112 -112.0485 0.89421-112 -112.0486 0.99996E+00 0.0000
35 N2O2-2 0.17435-161 -161.7586 0.17082-161 -161.7675 0.97971E+00 -0.0089
36 HN2O2- 0.36608-157 -157.4364 0.35936-157 -157.4445 0.98165E+00 -0.0080
37 H2N2O2,aq 0.83279-157 -157.0795 0.83279-157 -157.0795 0.10000E+01 0.0000
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15663-157 -157.8051 0.15663-157 -157.8051 0.99996E+00 0.0000
53 SO2,aq 0.34210E-69 -69.4658 0.34210E-69 -69.4658 0.10000E+01 0.0000
54 SO3-2 0.66381E-65 -65.1780 0.65035E-65 -65.1869 0.97971E+00 -0.0089
55 HSO3- 0.22604E-64 -64.6458 0.22190E-64 -64.6539 0.98165E+00 -0.0080
56 HSO4- 0.87556E-25 -25.0577 0.85950E-25 -25.0658 0.98165E+00 -0.0080
57 HSO5- 0.73516E-46 -46.1336 0.72167E-46 -46.1417 0.98165E+00 -0.0080
58 S2O3-2 0.41783-180 -180.3790 0.40936-180 -180.3879 0.97971E+00 -0.0089
59 HS2O3- 0.42968-185 -185.3669 0.42180-185 -185.3749 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34682-191 -191.4599 0.34682-191 -191.4599 0.10000E+01 0.0000
61 S2O4-2 0.78181-167 -167.1069 0.76595-167 -167.1158 0.97971E+00 -0.0089
62 HS2O4- 0.51671-171 -171.2868 0.50723-171 -171.2948 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25073-177 -177.6008 0.25073-177 -177.6008 0.10000E+01 0.0000
64 S2O5-2 0.76594-134 -134.1158 0.75041-134 -134.1247 0.97971E+00 -0.0089
65 S2O6-2 0.20384-103 -103.6907 0.19971-103 -103.6996 0.97971E+00 -0.0089
66 S2O8-2 0.40690E-78 -78.3905 0.39864E-78 -78.3994 0.97971E+00 -0.0089
Charge balance for all species = -.3084E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log =-100.0000
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3713-222 1.0000 0.1282-156 0.1282-156
S2,gas 0.4447-322 1.0000 0.1541-256 0.1541-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.2184-129 1.0000 0.7541E-64 0.7541E-64
SO3,gas 0.7414-123 1.0000 0.2560E-57 0.2560E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.1335-178 1.0000 0.4609-113 0.4609-113
N2,gas 0.3983-174 1.0000 0.1375-108 0.1375-108
SO2,gas 0.6698-135 1.0000 0.2313E-69 0.2313E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35036E+06 -256.812
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 12.39 -64.12 -14.657 0.87481E+05 -64.123
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -102.30 -113.34 -56.668 0.15462E+06 -113.336
12 N2,gas 2.57 -106.29 -108.86 -14.047 0.14852E+06 -108.862
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95003E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1335E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1335E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43263E-20 -20.3639 0.42386E-20 -20.3728 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77069-158 -158.1131 0.75655-158 -158.1212 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.21810E-80 -80.6613 0.21410E-80 -80.6694 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.81724-142 -142.0876 0.81724-142 -142.0876 0.10000E+01 0.0000
19 CN- 0.22719-144 -144.6436 0.22302-144 -144.6517 0.98165E+00 -0.0080
20 OCN- 0.18175E-97 -97.7405 0.17842E-97 -97.7486 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.57760E-83 -83.2384 0.57757E-83 -83.2384 0.99996E+00 0.0000
30 HNO2,aq 0.26418E-38 -38.5781 0.26418E-38 -38.5781 0.10000E+01 0.0000
31 NO2- 0.75324E-35 -35.1231 0.73942E-35 -35.1311 0.98165E+00 -0.0080
32 HNO3,aq 0.20844E-29 -29.6810 0.20844E-29 -29.6810 0.10000E+01 0.0000
33 NO3- 0.20000E-21 -21.6990 0.19633E-21 -21.7070 0.98165E+00 -0.0080
34 N2,aq 0.35770E-55 -55.4465 0.35768E-55 -55.4465 0.99996E+00 0.0000
35 N2O2-2 0.69741-105 -105.1565 0.68326-105 -105.1654 0.97971E+00 -0.0089
36 HN2O2- 0.14643-100 -100.8344 0.14374-100 -100.8424 0.98165E+00 -0.0080
37 H2N2O2,aq 0.33312-100 -100.4774 0.33312-100 -100.4774 0.10000E+01 0.0000
38 N2H5+ 0.17921-155 -155.7466 0.17592-155 -155.7547 0.98165E+00 -0.0080
39 N2H6+2 0.35910-163 -163.4448 0.35181-163 -163.4537 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15662-157 -157.8051 0.15662-157 -157.8052 0.99996E+00 0.0000
53 SO2,aq 0.34208E-69 -69.4659 0.34208E-69 -69.4659 0.10000E+01 0.0000
54 SO3-2 0.66378E-65 -65.1780 0.65031E-65 -65.1869 0.97971E+00 -0.0089
55 HSO3- 0.22603E-64 -64.6458 0.22188E-64 -64.6539 0.98165E+00 -0.0080
56 HSO4- 0.87552E-25 -25.0577 0.85945E-25 -25.0658 0.98165E+00 -0.0080
57 HSO5- 0.73513E-46 -46.1336 0.72164E-46 -46.1417 0.98165E+00 -0.0080
58 S2O3-2 0.41779-180 -180.3790 0.40932-180 -180.3879 0.97971E+00 -0.0089
59 HS2O3- 0.42964-185 -185.3669 0.42176-185 -185.3749 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34679-191 -191.4599 0.34679-191 -191.4599 0.10000E+01 0.0000
61 S2O4-2 0.78173-167 -167.1069 0.76587-167 -167.1158 0.97971E+00 -0.0089
62 HS2O4- 0.51666-171 -171.2868 0.50718-171 -171.2948 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25070-177 -177.6008 0.25070-177 -177.6008 0.10000E+01 0.0000
64 S2O5-2 0.76587-134 -134.1158 0.75033-134 -134.1247 0.97971E+00 -0.0089
65 S2O6-2 0.20382-103 -103.6908 0.19969-103 -103.6997 0.97971E+00 -0.0089
66 S2O8-2 0.40686E-78 -78.3906 0.39860E-78 -78.3995 0.97971E+00 -0.0089
Charge balance for all species = -.3636E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -22.0000
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3712-222 1.0000 0.1282-156 0.1282-156
S2,gas 0.4447-322 1.0000 0.1541-256 0.1541-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.4368-101 1.0000 0.1508E-35 0.1508E-35
SO3,gas 0.7414-123 1.0000 0.2560E-57 0.2560E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.2669-150 1.0000 0.9217E-85 0.9217E-85
N2,gas 0.1593-117 1.0000 0.5502E-52 0.5502E-52
SO2,gas 0.6698-135 1.0000 0.2313E-69 0.2313E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35036E+06 -256.812
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 40.69 -35.82 -8.188 0.48871E+05 -35.822
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -74.00 -85.04 -42.518 0.11601E+06 -85.035
12 N2,gas 2.57 -49.69 -52.26 -6.743 0.71297E+05 -52.260
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95003E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1315E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1315E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43261E-20 -20.3639 0.42384E-20 -20.3728 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77065-158 -158.1131 0.75651-158 -158.1212 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.43620E-80 -80.3603 0.42819E-80 -80.3684 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.16345-141 -141.7866 0.16345-141 -141.7866 0.10000E+01 0.0000
19 CN- 0.45438-144 -144.3426 0.44604-144 -144.3506 0.98165E+00 -0.0080
20 OCN- 0.36351E-97 -97.4395 0.35684E-97 -97.4475 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.11552E-82 -82.9373 0.11551E-82 -82.9374 0.99996E+00 0.0000
30 HNO2,aq 0.52835E-38 -38.2771 0.52835E-38 -38.2771 0.10000E+01 0.0000
31 NO2- 0.15065E-34 -34.8220 0.14788E-34 -34.8301 0.98165E+00 -0.0080
32 HNO3,aq 0.41689E-29 -29.3800 0.41689E-29 -29.3800 0.10000E+01 0.0000
33 NO3- 0.40000E-21 -21.3979 0.39266E-21 -21.4060 0.98165E+00 -0.0080
34 N2,aq 0.14308E-54 -54.8444 0.14307E-54 -54.8444 0.99996E+00 0.0000
35 N2O2-2 0.27897-104 -104.5544 0.27331-104 -104.5634 0.97971E+00 -0.0089
36 HN2O2- 0.58573-100 -100.2323 0.57498-100 -100.2403 0.98165E+00 -0.0080
37 H2N2O2,aq 0.13325E-99 -99.8753 0.13325E-99 -99.8753 0.10000E+01 0.0000
38 N2H5+ 0.71682-155 -155.1446 0.70367-155 -155.1526 0.98165E+00 -0.0080
39 N2H6+2 0.14364-162 -162.8427 0.14073-162 -162.8516 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15662-157 -157.8052 0.15661-157 -157.8052 0.99996E+00 0.0000
53 SO2,aq 0.34206E-69 -69.4659 0.34206E-69 -69.4659 0.10000E+01 0.0000
54 SO3-2 0.66375E-65 -65.1780 0.65028E-65 -65.1869 0.97971E+00 -0.0089
55 HSO3- 0.22602E-64 -64.6459 0.22187E-64 -64.6539 0.98165E+00 -0.0080
56 HSO4- 0.87547E-25 -25.0578 0.85941E-25 -25.0658 0.98165E+00 -0.0080
57 HSO5- 0.73509E-46 -46.1337 0.72160E-46 -46.1417 0.98165E+00 -0.0080
58 S2O3-2 0.41775-180 -180.3791 0.40927-180 -180.3880 0.97971E+00 -0.0089
59 HS2O3- 0.42960-185 -185.3669 0.42171-185 -185.3750 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34675-191 -191.4600 0.34675-191 -191.4600 0.10000E+01 0.0000
61 S2O4-2 0.78165-167 -167.1070 0.76579-167 -167.1159 0.97971E+00 -0.0089
62 HS2O4- 0.51660-171 -171.2868 0.50712-171 -171.2949 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25068-177 -177.6009 0.25068-177 -177.6009 0.10000E+01 0.0000
64 S2O5-2 0.76579-134 -134.1159 0.75025-134 -134.1248 0.97971E+00 -0.0089
65 S2O6-2 0.20380-103 -103.6908 0.19967-103 -103.6997 0.97971E+00 -0.0089
66 S2O8-2 0.40682E-78 -78.3906 0.39856E-78 -78.3995 0.97971E+00 -0.0089
Charge balance for all species = -.2581E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -21.6990
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3712-222 1.0000 0.1282-156 0.1282-156
S2,gas 0.4447-322 1.0000 0.1541-256 0.1541-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.8735-101 1.0000 0.3016E-35 0.3016E-35
SO3,gas 0.7413-123 1.0000 0.2560E-57 0.2560E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.5339-150 1.0000 0.1843E-84 0.1843E-84
N2,gas 0.6373-117 1.0000 0.2201E-51 0.2201E-51
SO2,gas 0.6698-135 1.0000 0.2313E-69 0.2313E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.812
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.00 -35.52 -8.119 0.48460E+05 -35.521
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -73.70 -84.73 -42.367 0.11560E+06 -84.734
12 N2,gas 2.57 -49.09 -51.66 -6.665 0.70475E+05 -51.657
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95003E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1295E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1295E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43259E-20 -20.3639 0.42381E-20 -20.3728 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77061-158 -158.1132 0.75647-158 -158.1212 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.65429E-80 -80.1842 0.64229E-80 -80.1923 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.24517-141 -141.6105 0.24517-141 -141.6105 0.10000E+01 0.0000
19 CN- 0.68157-144 -144.1665 0.66906-144 -144.1745 0.98165E+00 -0.0080
20 OCN- 0.54526E-97 -97.2634 0.53526E-97 -97.2714 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.17328E-82 -82.7613 0.17327E-82 -82.7613 0.99996E+00 0.0000
30 HNO2,aq 0.79253E-38 -38.1010 0.79253E-38 -38.1010 0.10000E+01 0.0000
31 NO2- 0.22597E-34 -34.6459 0.22183E-34 -34.6540 0.98165E+00 -0.0080
32 HNO3,aq 0.62533E-29 -29.2039 0.62533E-29 -29.2039 0.10000E+01 0.0000
33 NO3- 0.60000E-21 -21.2218 0.58899E-21 -21.2299 0.98165E+00 -0.0080
34 N2,aq 0.32193E-54 -54.4922 0.32192E-54 -54.4923 0.99996E+00 0.0000
35 N2O2-2 0.62767-104 -104.2023 0.61494-104 -104.2112 0.97971E+00 -0.0089
36 HN2O2- 0.13179E-99 -99.8801 0.12937E-99 -99.8882 0.98165E+00 -0.0080
37 H2N2O2,aq 0.29980E-99 -99.5232 0.29980E-99 -99.5232 0.10000E+01 0.0000
38 N2H5+ 0.16129-154 -154.7924 0.15833-154 -154.8004 0.98165E+00 -0.0080
39 N2H6+2 0.32319-162 -162.4905 0.31663-162 -162.4994 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15661-157 -157.8052 0.15660-157 -157.8052 0.99996E+00 0.0000
53 SO2,aq 0.34205E-69 -69.4659 0.34205E-69 -69.4659 0.10000E+01 0.0000
54 SO3-2 0.66371E-65 -65.1780 0.65025E-65 -65.1869 0.97971E+00 -0.0089
55 HSO3- 0.22601E-64 -64.6459 0.22186E-64 -64.6539 0.98165E+00 -0.0080
56 HSO4- 0.87543E-25 -25.0578 0.85937E-25 -25.0658 0.98165E+00 -0.0080
57 HSO5- 0.73505E-46 -46.1337 0.72156E-46 -46.1417 0.98165E+00 -0.0080
58 S2O3-2 0.41771-180 -180.3791 0.40923-180 -180.3880 0.97971E+00 -0.0089
59 HS2O3- 0.42955-185 -185.3670 0.42167-185 -185.3750 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34672-191 -191.4600 0.34672-191 -191.4600 0.10000E+01 0.0000
61 S2O4-2 0.78157-167 -167.1070 0.76572-167 -167.1159 0.97971E+00 -0.0089
62 HS2O4- 0.51655-171 -171.2869 0.50707-171 -171.2949 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25065-177 -177.6009 0.25065-177 -177.6009 0.10000E+01 0.0000
64 S2O5-2 0.76571-134 -134.1159 0.75018-134 -134.1248 0.97971E+00 -0.0089
65 S2O6-2 0.20378-103 -103.6908 0.19965-103 -103.6997 0.97971E+00 -0.0089
66 S2O8-2 0.40678E-78 -78.3906 0.39852E-78 -78.3995 0.97971E+00 -0.0089
Charge balance for all species = -.2880E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -21.5229
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3712-222 1.0000 0.1282-156 0.1282-156
S2,gas 0.4447-322 1.0000 0.1541-256 0.1541-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.1310-100 1.0000 0.4524E-35 0.4524E-35
SO3,gas 0.7413-123 1.0000 0.2560E-57 0.2560E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.8008-150 1.0000 0.2765E-84 0.2765E-84
N2,gas 0.1434-116 1.0000 0.4952E-51 0.4952E-51
SO2,gas 0.6697-135 1.0000 0.2313E-69 0.2313E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.812
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.17 -35.34 -8.079 0.48220E+05 -35.344
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -73.52 -84.56 -42.279 0.11536E+06 -84.558
12 N2,gas 2.57 -48.73 -51.31 -6.620 0.69995E+05 -51.305
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95003E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1275E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1275E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43257E-20 -20.3639 0.42379E-20 -20.3728 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77057-158 -158.1132 0.75643-158 -158.1212 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.87239E-80 -80.0593 0.85638E-80 -80.0673 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.32690-141 -141.4856 0.32690-141 -141.4856 0.10000E+01 0.0000
19 CN- 0.90876-144 -144.0416 0.89209-144 -144.0496 0.98165E+00 -0.0080
20 OCN- 0.72702E-97 -97.1385 0.71368E-97 -97.1465 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.23104E-82 -82.6363 0.23103E-82 -82.6363 0.99996E+00 0.0000
30 HNO2,aq 0.10567E-37 -37.9760 0.10567E-37 -37.9760 0.10000E+01 0.0000
31 NO2- 0.30130E-34 -34.5210 0.29577E-34 -34.5290 0.98165E+00 -0.0080
32 HNO3,aq 0.83378E-29 -29.0789 0.83378E-29 -29.0789 0.10000E+01 0.0000
33 NO3- 0.80000E-21 -21.0969 0.78532E-21 -21.1050 0.98165E+00 -0.0080
34 N2,aq 0.57232E-54 -54.2424 0.57229E-54 -54.2424 0.99996E+00 0.0000
35 N2O2-2 0.11159-103 -103.9524 0.10932-103 -103.9613 0.97971E+00 -0.0089
36 HN2O2- 0.23429E-99 -99.6302 0.22999E-99 -99.6383 0.98165E+00 -0.0080
37 H2N2O2,aq 0.53299E-99 -99.2733 0.53299E-99 -99.2733 0.10000E+01 0.0000
38 N2H5+ 0.28673-154 -154.5425 0.28147-154 -154.5506 0.98165E+00 -0.0080
39 N2H6+2 0.57456-162 -162.2407 0.56290-162 -162.2496 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15660-157 -157.8052 0.15659-157 -157.8052 0.99996E+00 0.0000
53 SO2,aq 0.34203E-69 -69.4659 0.34203E-69 -69.4659 0.10000E+01 0.0000
54 SO3-2 0.66368E-65 -65.1780 0.65021E-65 -65.1869 0.97971E+00 -0.0089
55 HSO3- 0.22600E-64 -64.6459 0.22185E-64 -64.6539 0.98165E+00 -0.0080
56 HSO4- 0.87538E-25 -25.0578 0.85932E-25 -25.0658 0.98165E+00 -0.0080
57 HSO5- 0.73501E-46 -46.1337 0.72153E-46 -46.1417 0.98165E+00 -0.0080
58 S2O3-2 0.41767-180 -180.3792 0.40919-180 -180.3881 0.97971E+00 -0.0089
59 HS2O3- 0.42951-185 -185.3670 0.42163-185 -185.3751 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34668-191 -191.4601 0.34668-191 -191.4601 0.10000E+01 0.0000
61 S2O4-2 0.78149-167 -167.1071 0.76564-167 -167.1160 0.97971E+00 -0.0089
62 HS2O4- 0.51650-171 -171.2869 0.50702-171 -171.2950 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25063-177 -177.6010 0.25063-177 -177.6010 0.10000E+01 0.0000
64 S2O5-2 0.76563-134 -134.1160 0.75010-134 -134.1249 0.97971E+00 -0.0089
65 S2O6-2 0.20376-103 -103.6909 0.19963-103 -103.6998 0.97971E+00 -0.0089
66 S2O8-2 0.40673E-78 -78.3907 0.39848E-78 -78.3996 0.97971E+00 -0.0089
Charge balance for all species = -.1598E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -21.3979
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3712-222 1.0000 0.1282-156 0.1282-156
S2,gas 0.4447-322 1.0000 0.1541-256 0.1541-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.1747-100 1.0000 0.6033E-35 0.6033E-35
SO3,gas 0.7413-123 1.0000 0.2560E-57 0.2560E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.1068-149 1.0000 0.3687E-84 0.3687E-84
N2,gas 0.2549-116 1.0000 0.8803E-51 0.8803E-51
SO2,gas 0.6697-135 1.0000 0.2312E-69 0.2312E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.812
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.30 -35.22 -8.050 0.48049E+05 -35.219
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -73.40 -84.43 -42.217 0.11519E+06 -84.433
12 N2,gas 2.57 -48.48 -51.06 -6.588 0.69654E+05 -51.055
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95003E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1255E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1255E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43255E-20 -20.3640 0.42377E-20 -20.3729 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77053-158 -158.1132 0.75639-158 -158.1213 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.10905E-79 -79.9624 0.10705E-79 -79.9704 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.40862-141 -141.3887 0.40862-141 -141.3887 0.10000E+01 0.0000
19 CN- 0.11359-143 -143.9446 0.11151-143 -143.9527 0.98165E+00 -0.0080
20 OCN- 0.90877E-97 -97.0415 0.89210E-97 -97.0496 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.28880E-82 -82.5394 0.28879E-82 -82.5394 0.99996E+00 0.0000
30 HNO2,aq 0.13209E-37 -37.8791 0.13209E-37 -37.8791 0.10000E+01 0.0000
31 NO2- 0.37662E-34 -34.4241 0.36971E-34 -34.4321 0.98165E+00 -0.0080
32 HNO3,aq 0.10422E-28 -28.9820 0.10422E-28 -28.9820 0.10000E+01 0.0000
33 NO3- 0.10000E-20 -21.0000 0.98165E-21 -21.0080 0.98165E+00 -0.0080
34 N2,aq 0.89425E-54 -54.0485 0.89421E-54 -54.0486 0.99996E+00 0.0000
35 N2O2-2 0.17435-103 -103.7586 0.17082-103 -103.7675 0.97971E+00 -0.0089
36 HN2O2- 0.36608E-99 -99.4364 0.35936E-99 -99.4445 0.98165E+00 -0.0080
37 H2N2O2,aq 0.83279E-99 -99.0795 0.83279E-99 -99.0795 0.10000E+01 0.0000
38 N2H5+ 0.44802-154 -154.3487 0.43979-154 -154.3567 0.98165E+00 -0.0080
39 N2H6+2 0.89775-162 -162.0468 0.87954-162 -162.0557 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15659-157 -157.8052 0.15659-157 -157.8052 0.99996E+00 0.0000
53 SO2,aq 0.34201E-69 -69.4660 0.34201E-69 -69.4660 0.10000E+01 0.0000
54 SO3-2 0.66365E-65 -65.1781 0.65018E-65 -65.1870 0.97971E+00 -0.0089
55 HSO3- 0.22599E-64 -64.6459 0.22184E-64 -64.6540 0.98165E+00 -0.0080
56 HSO4- 0.87534E-25 -25.0578 0.85928E-25 -25.0659 0.98165E+00 -0.0080
57 HSO5- 0.73498E-46 -46.1337 0.72149E-46 -46.1418 0.98165E+00 -0.0080
58 S2O3-2 0.41762-180 -180.3792 0.40915-180 -180.3881 0.97971E+00 -0.0089
59 HS2O3- 0.42947-185 -185.3671 0.42159-185 -185.3751 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34665-191 -191.4601 0.34665-191 -191.4601 0.10000E+01 0.0000
61 S2O4-2 0.78141-167 -167.1071 0.76556-167 -167.1160 0.97971E+00 -0.0089
62 HS2O4- 0.51645-171 -171.2870 0.50697-171 -171.2950 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25060-177 -177.6010 0.25060-177 -177.6010 0.10000E+01 0.0000
64 S2O5-2 0.76556-134 -134.1160 0.75003-134 -134.1249 0.97971E+00 -0.0089
65 S2O6-2 0.20374-103 -103.6909 0.19961-103 -103.6998 0.97971E+00 -0.0089
66 S2O8-2 0.40669E-78 -78.3907 0.39844E-78 -78.3996 0.97971E+00 -0.0089
Charge balance for all species = -.3301E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -21.3010
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3712-222 1.0000 0.1282-156 0.1282-156
S2,gas 0.4447-322 1.0000 0.1541-256 0.1541-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.2184-100 1.0000 0.7541E-35 0.7541E-35
SO3,gas 0.7412-123 1.0000 0.2559E-57 0.2559E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.1335-149 1.0000 0.4609E-84 0.4609E-84
N2,gas 0.3983-116 1.0000 0.1375E-50 0.1375E-50
SO2,gas 0.6697-135 1.0000 0.2312E-69 0.2312E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.812
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.39 -35.12 -8.028 0.47917E+05 -35.123
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -73.30 -84.34 -42.168 0.11506E+06 -84.336
12 N2,gas 2.57 -48.29 -50.86 -6.563 0.69390E+05 -50.862
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95003E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1235E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1235E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43252E-20 -20.3640 0.42375E-20 -20.3729 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77049-158 -158.1132 0.75636-158 -158.1213 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.13086E-79 -79.8832 0.12846E-79 -79.8912 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.49034-141 -141.3095 0.49034-141 -141.3095 0.10000E+01 0.0000
19 CN- 0.13631-143 -143.8655 0.13381-143 -143.8735 0.98165E+00 -0.0080
20 OCN- 0.10905E-96 -96.9624 0.10705E-96 -96.9704 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.34656E-82 -82.4602 0.34654E-82 -82.4602 0.99996E+00 0.0000
30 HNO2,aq 0.15851E-37 -37.8000 0.15851E-37 -37.8000 0.10000E+01 0.0000
31 NO2- 0.45194E-34 -34.3449 0.44365E-34 -34.3530 0.98165E+00 -0.0080
32 HNO3,aq 0.12507E-28 -28.9029 0.12507E-28 -28.9029 0.10000E+01 0.0000
33 NO3- 0.12000E-20 -20.9208 0.11780E-20 -20.9289 0.98165E+00 -0.0080
34 N2,aq 0.12877E-53 -53.8902 0.12877E-53 -53.8902 0.99996E+00 0.0000
35 N2O2-2 0.25107-103 -103.6002 0.24598-103 -103.6091 0.97971E+00 -0.0089
36 HN2O2- 0.52715E-99 -99.2781 0.51748E-99 -99.2861 0.98165E+00 -0.0080
37 H2N2O2,aq 0.11992E-98 -98.9211 0.11992E-98 -98.9211 0.10000E+01 0.0000
38 N2H5+ 0.64514-154 -154.1903 0.63330-154 -154.1984 0.98165E+00 -0.0080
39 N2H6+2 0.12928-161 -161.8885 0.12665-161 -161.8974 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15658-157 -157.8053 0.15658-157 -157.8053 0.99996E+00 0.0000
53 SO2,aq 0.34199E-69 -69.4660 0.34199E-69 -69.4660 0.10000E+01 0.0000
54 SO3-2 0.66361E-65 -65.1781 0.65015E-65 -65.1870 0.97971E+00 -0.0089
55 HSO3- 0.22597E-64 -64.6459 0.22183E-64 -64.6540 0.98165E+00 -0.0080
56 HSO4- 0.87530E-25 -25.0578 0.85924E-25 -25.0659 0.98165E+00 -0.0080
57 HSO5- 0.73494E-46 -46.1337 0.72145E-46 -46.1418 0.98165E+00 -0.0080
58 S2O3-2 0.41758-180 -180.3793 0.40911-180 -180.3882 0.97971E+00 -0.0089
59 HS2O3- 0.42942-185 -185.3671 0.42154-185 -185.3752 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34661-191 -191.4602 0.34661-191 -191.4602 0.10000E+01 0.0000
61 S2O4-2 0.78133-167 -167.1072 0.76548-167 -167.1161 0.97971E+00 -0.0089
62 HS2O4- 0.51639-171 -171.2870 0.50692-171 -171.2951 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25058-177 -177.6011 0.25058-177 -177.6011 0.10000E+01 0.0000
64 S2O5-2 0.76548-134 -134.1161 0.74995-134 -134.1250 0.97971E+00 -0.0089
65 S2O6-2 0.20372-103 -103.6910 0.19959-103 -103.6999 0.97971E+00 -0.0089
66 S2O8-2 0.40665E-78 -78.3908 0.39840E-78 -78.3997 0.97971E+00 -0.0089
Charge balance for all species = -.2081E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -21.2218
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3711-222 1.0000 0.1282-156 0.1282-156
S2,gas 0.4447-322 1.0000 0.1540-256 0.1540-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.2621-100 1.0000 0.9049E-35 0.9049E-35
SO3,gas 0.7412-123 1.0000 0.2559E-57 0.2559E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.1602-149 1.0000 0.5530E-84 0.5530E-84
N2,gas 0.5736-116 1.0000 0.1981E-50 0.1981E-50
SO2,gas 0.6696-135 1.0000 0.2312E-69 0.2312E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.812
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.47 -35.04 -8.010 0.47809E+05 -35.043
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -73.22 -84.26 -42.129 0.11495E+06 -84.257
12 N2,gas 2.57 -48.13 -50.70 -6.542 0.69174E+05 -50.703
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95003E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1215E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1215E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43250E-20 -20.3640 0.42373E-20 -20.3729 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77045-158 -158.1133 0.75632-158 -158.1213 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.15267E-79 -79.8163 0.14987E-79 -79.8243 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.57207-141 -141.2426 0.57207-141 -141.2426 0.10000E+01 0.0000
19 CN- 0.15903-143 -143.7985 0.15612-143 -143.8066 0.98165E+00 -0.0080
20 OCN- 0.12723E-96 -96.8954 0.12489E-96 -96.9035 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.40432E-82 -82.3933 0.40430E-82 -82.3933 0.99996E+00 0.0000
30 HNO2,aq 0.18492E-37 -37.7330 0.18492E-37 -37.7330 0.10000E+01 0.0000
31 NO2- 0.52727E-34 -34.2780 0.51759E-34 -34.2860 0.98165E+00 -0.0080
32 HNO3,aq 0.14591E-28 -28.8359 0.14591E-28 -28.8359 0.10000E+01 0.0000
33 NO3- 0.14000E-20 -20.8539 0.13743E-20 -20.8619 0.98165E+00 -0.0080
34 N2,aq 0.17527E-53 -53.7563 0.17527E-53 -53.7563 0.99996E+00 0.0000
35 N2O2-2 0.34173-103 -103.4663 0.33480-103 -103.4752 0.97971E+00 -0.0089
36 HN2O2- 0.71752E-99 -99.1442 0.70435E-99 -99.1522 0.98165E+00 -0.0080
37 H2N2O2,aq 0.16323E-98 -98.7872 0.16323E-98 -98.7872 0.10000E+01 0.0000
38 N2H5+ 0.87811-154 -154.0565 0.86200-154 -154.0645 0.98165E+00 -0.0080
39 N2H6+2 0.17596-161 -161.7546 0.17239-161 -161.7635 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15658-157 -157.8053 0.15657-157 -157.8053 0.99996E+00 0.0000
53 SO2,aq 0.34198E-69 -69.4660 0.34198E-69 -69.4660 0.10000E+01 0.0000
54 SO3-2 0.66358E-65 -65.1781 0.65012E-65 -65.1870 0.97971E+00 -0.0089
55 HSO3- 0.22596E-64 -64.6460 0.22182E-64 -64.6540 0.98165E+00 -0.0080
56 HSO4- 0.87525E-25 -25.0579 0.85919E-25 -25.0659 0.98165E+00 -0.0080
57 HSO5- 0.73490E-46 -46.1338 0.72142E-46 -46.1418 0.98165E+00 -0.0080
58 S2O3-2 0.41754-180 -180.3793 0.40907-180 -180.3882 0.97971E+00 -0.0089
59 HS2O3- 0.42938-185 -185.3672 0.42150-185 -185.3752 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34658-191 -191.4602 0.34658-191 -191.4602 0.10000E+01 0.0000
61 S2O4-2 0.78126-167 -167.1072 0.76541-167 -167.1161 0.97971E+00 -0.0089
62 HS2O4- 0.51634-171 -171.2871 0.50687-171 -171.2951 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25055-177 -177.6011 0.25055-177 -177.6011 0.10000E+01 0.0000
64 S2O5-2 0.76540-134 -134.1161 0.74987-134 -134.1250 0.97971E+00 -0.0089
65 S2O6-2 0.20370-103 -103.6910 0.19957-103 -103.6999 0.97971E+00 -0.0089
66 S2O8-2 0.40661E-78 -78.3908 0.39836E-78 -78.3997 0.97971E+00 -0.0089
Charge balance for all species = -.3864E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -21.1549
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3711-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1540-256 0.1540-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.3057-100 1.0000 0.1056E-34 0.1056E-34
SO3,gas 0.7411-123 1.0000 0.2559E-57 0.2559E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.1869-149 1.0000 0.6452E-84 0.6452E-84
N2,gas 0.7807-116 1.0000 0.2696E-50 0.2696E-50
SO2,gas 0.6696-135 1.0000 0.2312E-69 0.2312E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.812
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.54 -34.98 -7.995 0.47718E+05 -34.976
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -73.15 -84.19 -42.095 0.11486E+06 -84.190
12 N2,gas 2.57 -48.00 -50.57 -6.525 0.68991E+05 -50.569
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95003E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1195E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1195E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43248E-20 -20.3640 0.42371E-20 -20.3729 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77042-158 -158.1133 0.75628-158 -158.1213 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.17448E-79 -79.7583 0.17128E-79 -79.7663 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.65379-141 -141.1846 0.65379-141 -141.1846 0.10000E+01 0.0000
19 CN- 0.18175-143 -143.7405 0.17842-143 -143.7486 0.98165E+00 -0.0080
20 OCN- 0.14540E-96 -96.8374 0.14274E-96 -96.8455 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.46208E-82 -82.3353 0.46206E-82 -82.3353 0.99996E+00 0.0000
30 HNO2,aq 0.21134E-37 -37.6750 0.21134E-37 -37.6750 0.10000E+01 0.0000
31 NO2- 0.60259E-34 -34.2200 0.59154E-34 -34.2280 0.98165E+00 -0.0080
32 HNO3,aq 0.16676E-28 -28.7779 0.16676E-28 -28.7779 0.10000E+01 0.0000
33 NO3- 0.16000E-20 -20.7959 0.15706E-20 -20.8039 0.98165E+00 -0.0080
34 N2,aq 0.22893E-53 -53.6403 0.22892E-53 -53.6403 0.99996E+00 0.0000
35 N2O2-2 0.44634-103 -103.3503 0.43729-103 -103.3592 0.97971E+00 -0.0089
36 HN2O2- 0.93716E-99 -99.0282 0.91997E-99 -99.0362 0.98165E+00 -0.0080
37 H2N2O2,aq 0.21319E-98 -98.6712 0.21319E-98 -98.6712 0.10000E+01 0.0000
38 N2H5+ 0.11469-153 -153.9405 0.11259-153 -153.9485 0.98165E+00 -0.0080
39 N2H6+2 0.22982-161 -161.6386 0.22516-161 -161.6475 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15657-157 -157.8053 0.15656-157 -157.8053 0.99996E+00 0.0000
53 SO2,aq 0.34196E-69 -69.4660 0.34196E-69 -69.4660 0.10000E+01 0.0000
54 SO3-2 0.66354E-65 -65.1781 0.65008E-65 -65.1870 0.97971E+00 -0.0089
55 HSO3- 0.22595E-64 -64.6460 0.22181E-64 -64.6540 0.98165E+00 -0.0080
56 HSO4- 0.87521E-25 -25.0579 0.85915E-25 -25.0659 0.98165E+00 -0.0080
57 HSO5- 0.73486E-46 -46.1338 0.72138E-46 -46.1418 0.98165E+00 -0.0080
58 S2O3-2 0.41750-180 -180.3793 0.40903-180 -180.3882 0.97971E+00 -0.0089
59 HS2O3- 0.42934-185 -185.3672 0.42146-185 -185.3752 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34654-191 -191.4602 0.34654-191 -191.4602 0.10000E+01 0.0000
61 S2O4-2 0.78118-167 -167.1073 0.76533-167 -167.1162 0.97971E+00 -0.0089
62 HS2O4- 0.51629-171 -171.2871 0.50682-171 -171.2951 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25053-177 -177.6011 0.25053-177 -177.6011 0.10000E+01 0.0000
64 S2O5-2 0.76532-134 -134.1162 0.74980-134 -134.1251 0.97971E+00 -0.0089
65 S2O6-2 0.20368-103 -103.6911 0.19954-103 -103.7000 0.97971E+00 -0.0089
66 S2O8-2 0.40657E-78 -78.3909 0.39832E-78 -78.3998 0.97971E+00 -0.0089
Charge balance for all species = -.2744E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -21.0969
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3711-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1540-256 0.1540-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.3494-100 1.0000 0.1207E-34 0.1207E-34
SO3,gas 0.7411-123 1.0000 0.2559E-57 0.2559E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.2136-149 1.0000 0.7374E-84 0.7374E-84
N2,gas 0.1020-115 1.0000 0.3521E-50 0.3521E-50
SO2,gas 0.6695-135 1.0000 0.2312E-69 0.2312E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.812
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.60 -34.92 -7.981 0.47639E+05 -34.918
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -73.09 -84.13 -42.066 0.11478E+06 -84.132
12 N2,gas 2.57 -47.88 -50.45 -6.510 0.68833E+05 -50.453
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95003E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1175E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1175E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43246E-20 -20.3641 0.42368E-20 -20.3730 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77038-158 -158.1133 0.75624-158 -158.1213 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.19629E-79 -79.7071 0.19269E-79 -79.7151 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.73552-141 -141.1334 0.73552-141 -141.1334 0.10000E+01 0.0000
19 CN- 0.20447-143 -143.6894 0.20072-143 -143.6974 0.98165E+00 -0.0080
20 OCN- 0.16358E-96 -96.7863 0.16058E-96 -96.7943 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.51984E-82 -82.2841 0.51981E-82 -82.2842 0.99996E+00 0.0000
30 HNO2,aq 0.23776E-37 -37.6239 0.23776E-37 -37.6239 0.10000E+01 0.0000
31 NO2- 0.67792E-34 -34.1688 0.66548E-34 -34.1769 0.98165E+00 -0.0080
32 HNO3,aq 0.18760E-28 -28.7268 0.18760E-28 -28.7268 0.10000E+01 0.0000
33 NO3- 0.18000E-20 -20.7447 0.17670E-20 -20.7528 0.98165E+00 -0.0080
34 N2,aq 0.28974E-53 -53.5380 0.28972E-53 -53.5380 0.99996E+00 0.0000
35 N2O2-2 0.56491-103 -103.2480 0.55344-103 -103.2569 0.97971E+00 -0.0089
36 HN2O2- 0.11861E-98 -98.9259 0.11643E-98 -98.9339 0.98165E+00 -0.0080
37 H2N2O2,aq 0.26982E-98 -98.5689 0.26982E-98 -98.5689 0.10000E+01 0.0000
38 N2H5+ 0.14516-153 -153.8382 0.14249-153 -153.8462 0.98165E+00 -0.0080
39 N2H6+2 0.29087-161 -161.5363 0.28497-161 -161.5452 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15656-157 -157.8053 0.15655-157 -157.8053 0.99996E+00 0.0000
53 SO2,aq 0.34194E-69 -69.4660 0.34194E-69 -69.4660 0.10000E+01 0.0000
54 SO3-2 0.66351E-65 -65.1782 0.65005E-65 -65.1871 0.97971E+00 -0.0089
55 HSO3- 0.22594E-64 -64.6460 0.22179E-64 -64.6540 0.98165E+00 -0.0080
56 HSO4- 0.87516E-25 -25.0579 0.85911E-25 -25.0660 0.98165E+00 -0.0080
57 HSO5- 0.73483E-46 -46.1338 0.72134E-46 -46.1419 0.98165E+00 -0.0080
58 S2O3-2 0.41745-180 -180.3794 0.40898-180 -180.3883 0.97971E+00 -0.0089
59 HS2O3- 0.42929-185 -185.3672 0.42142-185 -185.3753 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34651-191 -191.4603 0.34651-191 -191.4603 0.10000E+01 0.0000
61 S2O4-2 0.78110-167 -167.1073 0.76525-167 -167.1162 0.97971E+00 -0.0089
62 HS2O4- 0.51624-171 -171.2872 0.50677-171 -171.2952 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25050-177 -177.6012 0.25050-177 -177.6012 0.10000E+01 0.0000
64 S2O5-2 0.76525-134 -134.1162 0.74972-134 -134.1251 0.97971E+00 -0.0089
65 S2O6-2 0.20366-103 -103.6911 0.19952-103 -103.7000 0.97971E+00 -0.0089
66 S2O8-2 0.40653E-78 -78.3909 0.39828E-78 -78.3998 0.97971E+00 -0.0089
Charge balance for all species = -.3031E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -21.0458
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3711-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1540-256 0.1540-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.3931-100 1.0000 0.1357E-34 0.1357E-34
SO3,gas 0.7411-123 1.0000 0.2559E-57 0.2559E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.2402-149 1.0000 0.8296E-84 0.8296E-84
N2,gas 0.1291-115 1.0000 0.4456E-50 0.4456E-50
SO2,gas 0.6695-135 1.0000 0.2312E-69 0.2312E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.812
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.65 -34.87 -7.970 0.47569E+05 -34.867
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -73.04 -84.08 -42.041 0.11471E+06 -84.081
12 N2,gas 2.57 -47.78 -50.35 -6.497 0.68693E+05 -50.351
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95003E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1155E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1155E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43244E-20 -20.3641 0.42366E-20 -20.3730 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77034-158 -158.1133 0.75620-158 -158.1214 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.21810E-79 -79.6613 0.21410E-79 -79.6694 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.81724-141 -141.0876 0.81724-141 -141.0876 0.10000E+01 0.0000
19 CN- 0.22719-143 -143.6436 0.22302-143 -143.6517 0.98165E+00 -0.0080
20 OCN- 0.18175E-96 -96.7405 0.17842E-96 -96.7486 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.57760E-82 -82.2384 0.57757E-82 -82.2384 0.99996E+00 0.0000
30 HNO2,aq 0.26418E-37 -37.5781 0.26418E-37 -37.5781 0.10000E+01 0.0000
31 NO2- 0.75324E-34 -34.1231 0.73942E-34 -34.1311 0.98165E+00 -0.0080
32 HNO3,aq 0.20844E-28 -28.6810 0.20844E-28 -28.6810 0.10000E+01 0.0000
33 NO3- 0.20000E-20 -20.6990 0.19633E-20 -20.7070 0.98165E+00 -0.0080
34 N2,aq 0.35770E-53 -53.4465 0.35768E-53 -53.4465 0.99996E+00 0.0000
35 N2O2-2 0.69741-103 -103.1565 0.68326-103 -103.1654 0.97971E+00 -0.0089
36 HN2O2- 0.14643E-98 -98.8344 0.14374E-98 -98.8424 0.98165E+00 -0.0080
37 H2N2O2,aq 0.33312E-98 -98.4774 0.33312E-98 -98.4774 0.10000E+01 0.0000
38 N2H5+ 0.17921-153 -153.7466 0.17592-153 -153.7547 0.98165E+00 -0.0080
39 N2H6+2 0.35910-161 -161.4448 0.35181-161 -161.4537 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15655-157 -157.8053 0.15655-157 -157.8054 0.99996E+00 0.0000
53 SO2,aq 0.34193E-69 -69.4661 0.34193E-69 -69.4661 0.10000E+01 0.0000
54 SO3-2 0.66348E-65 -65.1782 0.65002E-65 -65.1871 0.97971E+00 -0.0089
55 HSO3- 0.22593E-64 -64.6460 0.22178E-64 -64.6541 0.98165E+00 -0.0080
56 HSO4- 0.87512E-25 -25.0579 0.85906E-25 -25.0660 0.98165E+00 -0.0080
57 HSO5- 0.73479E-46 -46.1338 0.72131E-46 -46.1419 0.98165E+00 -0.0080
58 S2O3-2 0.41741-180 -180.3794 0.40894-180 -180.3883 0.97971E+00 -0.0089
59 HS2O3- 0.42925-185 -185.3673 0.42137-185 -185.3753 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34647-191 -191.4603 0.34647-191 -191.4603 0.10000E+01 0.0000
61 S2O4-2 0.78102-167 -167.1073 0.76517-167 -167.1162 0.97971E+00 -0.0089
62 HS2O4- 0.51619-171 -171.2872 0.50671-171 -171.2952 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25048-177 -177.6012 0.25048-177 -177.6012 0.10000E+01 0.0000
64 S2O5-2 0.76517-134 -134.1162 0.74965-134 -134.1251 0.97971E+00 -0.0089
65 S2O6-2 0.20364-103 -103.6911 0.19950-103 -103.7000 0.97971E+00 -0.0089
66 S2O8-2 0.40649E-78 -78.3910 0.39824E-78 -78.3999 0.97971E+00 -0.0089
Charge balance for all species = -.1724E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -21.0000
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3711-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1540-256 0.1540-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.4368-100 1.0000 0.1508E-34 0.1508E-34
SO3,gas 0.7410-123 1.0000 0.2559E-57 0.2559E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.2669-149 1.0000 0.9217E-84 0.9217E-84
N2,gas 0.1593-115 1.0000 0.5502E-50 0.5502E-50
SO2,gas 0.6695-135 1.0000 0.2312E-69 0.2312E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.813
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.69 -34.82 -7.959 0.47507E+05 -34.822
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -73.00 -84.04 -42.018 0.11465E+06 -84.035
12 N2,gas 2.57 -47.69 -50.26 -6.485 0.68568E+05 -50.260
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95003E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1135E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1135E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43241E-20 -20.3641 0.42364E-20 -20.3730 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77030-158 -158.1133 0.75617-158 -158.1214 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.23991E-79 -79.6200 0.23551E-79 -79.6280 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.89897-141 -141.0463 0.89897-141 -141.0463 0.10000E+01 0.0000
19 CN- 0.24991-143 -143.6022 0.24532-143 -143.6103 0.98165E+00 -0.0080
20 OCN- 0.19993E-96 -96.6991 0.19626E-96 -96.7072 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.63535E-82 -82.1970 0.63533E-82 -82.1970 0.99996E+00 0.0000
30 HNO2,aq 0.29059E-37 -37.5367 0.29059E-37 -37.5367 0.10000E+01 0.0000
31 NO2- 0.82856E-34 -34.0817 0.81336E-34 -34.0897 0.98165E+00 -0.0080
32 HNO3,aq 0.22929E-28 -28.6396 0.22929E-28 -28.6396 0.10000E+01 0.0000
33 NO3- 0.22000E-20 -20.6576 0.21596E-20 -20.6656 0.98165E+00 -0.0080
34 N2,aq 0.43282E-53 -53.3637 0.43280E-53 -53.3637 0.99996E+00 0.0000
35 N2O2-2 0.84387-103 -103.0737 0.82675-103 -103.0826 0.97971E+00 -0.0089
36 HN2O2- 0.17718E-98 -98.7516 0.17393E-98 -98.7596 0.98165E+00 -0.0080
37 H2N2O2,aq 0.40307E-98 -98.3946 0.40307E-98 -98.3946 0.10000E+01 0.0000
38 N2H5+ 0.21684-153 -153.6639 0.21286-153 -153.6719 0.98165E+00 -0.0080
39 N2H6+2 0.43451-161 -161.3620 0.42570-161 -161.3709 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15654-157 -157.8054 0.15654-157 -157.8054 0.99996E+00 0.0000
53 SO2,aq 0.34191E-69 -69.4661 0.34191E-69 -69.4661 0.10000E+01 0.0000
54 SO3-2 0.66344E-65 -65.1782 0.64998E-65 -65.1871 0.97971E+00 -0.0089
55 HSO3- 0.22592E-64 -64.6461 0.22177E-64 -64.6541 0.98165E+00 -0.0080
56 HSO4- 0.87507E-25 -25.0580 0.85902E-25 -25.0660 0.98165E+00 -0.0080
57 HSO5- 0.73475E-46 -46.1339 0.72127E-46 -46.1419 0.98165E+00 -0.0080
58 S2O3-2 0.41737-180 -180.3795 0.40890-180 -180.3884 0.97971E+00 -0.0089
59 HS2O3- 0.42921-185 -185.3673 0.42133-185 -185.3754 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34644-191 -191.4604 0.34644-191 -191.4604 0.10000E+01 0.0000
61 S2O4-2 0.78094-167 -167.1074 0.76510-167 -167.1163 0.97971E+00 -0.0089
62 HS2O4- 0.51613-171 -171.2872 0.50666-171 -171.2953 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25045-177 -177.6013 0.25045-177 -177.6013 0.10000E+01 0.0000
64 S2O5-2 0.76509-134 -134.1163 0.74957-134 -134.1252 0.97971E+00 -0.0089
65 S2O6-2 0.20362-103 -103.6912 0.19948-103 -103.7001 0.97971E+00 -0.0089
66 S2O8-2 0.40645E-78 -78.3910 0.39820E-78 -78.3999 0.97971E+00 -0.0089
Charge balance for all species = -.3421E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -20.9586
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3710-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1540-256 0.1540-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.4804-100 1.0000 0.1659E-34 0.1659E-34
SO3,gas 0.7410-123 1.0000 0.2559E-57 0.2559E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.2936-149 1.0000 0.1014E-83 0.1014E-83
N2,gas 0.1928-115 1.0000 0.6657E-50 0.6657E-50
SO2,gas 0.6694-135 1.0000 0.2312E-69 0.2312E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.813
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.74 -34.78 -7.950 0.47450E+05 -34.780
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -72.96 -83.99 -41.997 0.11459E+06 -83.994
12 N2,gas 2.57 -47.60 -50.18 -6.474 0.68455E+05 -50.177
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95003E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1115E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1115E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43239E-20 -20.3641 0.42362E-20 -20.3730 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77026-158 -158.1134 0.75613-158 -158.1214 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.26172E-79 -79.5822 0.25692E-79 -79.5902 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.98069-141 -141.0085 0.98069-141 -141.0085 0.10000E+01 0.0000
19 CN- 0.27263-143 -143.5644 0.26763-143 -143.5725 0.98165E+00 -0.0080
20 OCN- 0.21811E-96 -96.6613 0.21410E-96 -96.6694 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.69311E-82 -82.1592 0.69308E-82 -82.1592 0.99996E+00 0.0000
30 HNO2,aq 0.31701E-37 -37.4989 0.31701E-37 -37.4989 0.10000E+01 0.0000
31 NO2- 0.90389E-34 -34.0439 0.88730E-34 -34.0519 0.98165E+00 -0.0080
32 HNO3,aq 0.25013E-28 -28.6018 0.25013E-28 -28.6018 0.10000E+01 0.0000
33 NO3- 0.24000E-20 -20.6198 0.23560E-20 -20.6278 0.98165E+00 -0.0080
34 N2,aq 0.51509E-53 -53.2881 0.51507E-53 -53.2881 0.99996E+00 0.0000
35 N2O2-2 0.10043-102 -102.9981 0.98390-103 -103.0070 0.97971E+00 -0.0089
36 HN2O2- 0.21086E-98 -98.6760 0.20699E-98 -98.6840 0.98165E+00 -0.0080
37 H2N2O2,aq 0.47969E-98 -98.3190 0.47969E-98 -98.3190 0.10000E+01 0.0000
38 N2H5+ 0.25806-153 -153.5883 0.25332-153 -153.5963 0.98165E+00 -0.0080
39 N2H6+2 0.51710-161 -161.2864 0.50661-161 -161.2953 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15654-157 -157.8054 0.15653-157 -157.8054 0.99996E+00 0.0000
53 SO2,aq 0.34189E-69 -69.4661 0.34189E-69 -69.4661 0.10000E+01 0.0000
54 SO3-2 0.66341E-65 -65.1782 0.64995E-65 -65.1871 0.97971E+00 -0.0089
55 HSO3- 0.22591E-64 -64.6461 0.22176E-64 -64.6541 0.98165E+00 -0.0080
56 HSO4- 0.87503E-25 -25.0580 0.85898E-25 -25.0660 0.98165E+00 -0.0080
57 HSO5- 0.73472E-46 -46.1339 0.72124E-46 -46.1419 0.98165E+00 -0.0080
58 S2O3-2 0.41733-180 -180.3795 0.40886-180 -180.3884 0.97971E+00 -0.0089
59 HS2O3- 0.42916-185 -185.3674 0.42129-185 -185.3754 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34640-191 -191.4604 0.34640-191 -191.4604 0.10000E+01 0.0000
61 S2O4-2 0.78086-167 -167.1074 0.76502-167 -167.1163 0.97971E+00 -0.0089
62 HS2O4- 0.51608-171 -171.2873 0.50661-171 -171.2953 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25043-177 -177.6013 0.25043-177 -177.6013 0.10000E+01 0.0000
64 S2O5-2 0.76501-134 -134.1163 0.74949-134 -134.1252 0.97971E+00 -0.0089
65 S2O6-2 0.20359-103 -103.6912 0.19946-103 -103.7001 0.97971E+00 -0.0089
66 S2O8-2 0.40641E-78 -78.3910 0.39816E-78 -78.3999 0.97971E+00 -0.0089
Charge balance for all species = -.2204E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -20.9208
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3710-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1540-256 0.1540-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.5241-100 1.0000 0.1810E-34 0.1810E-34
SO3,gas 0.7410-123 1.0000 0.2558E-57 0.2558E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.3203-149 1.0000 0.1106E-83 0.1106E-83
N2,gas 0.2294-115 1.0000 0.7922E-50 0.7922E-50
SO2,gas 0.6694-135 1.0000 0.2311E-69 0.2311E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.813
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.77 -34.74 -7.941 0.47399E+05 -34.742
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -72.92 -83.96 -41.978 0.11454E+06 -83.956
12 N2,gas 2.57 -47.53 -50.10 -6.465 0.68352E+05 -50.101
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95004E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1095E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1095E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43237E-20 -20.3641 0.42360E-20 -20.3730 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77022-158 -158.1134 0.75609-158 -158.1214 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.28353E-79 -79.5474 0.27832E-79 -79.5554 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.10624-140 -140.9737 0.10624-140 -140.9737 0.10000E+01 0.0000
19 CN- 0.29535-143 -143.5297 0.28993-143 -143.5377 0.98165E+00 -0.0080
20 OCN- 0.23628E-96 -96.6266 0.23195E-96 -96.6346 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.75087E-82 -82.1244 0.75084E-82 -82.1245 0.99996E+00 0.0000
30 HNO2,aq 0.34343E-37 -37.4642 0.34343E-37 -37.4642 0.10000E+01 0.0000
31 NO2- 0.97921E-34 -34.0091 0.96125E-34 -34.0172 0.98165E+00 -0.0080
32 HNO3,aq 0.27098E-28 -28.5671 0.27098E-28 -28.5671 0.10000E+01 0.0000
33 NO3- 0.26000E-20 -20.5850 0.25523E-20 -20.5931 0.98165E+00 -0.0080
34 N2,aq 0.60451E-53 -53.2186 0.60449E-53 -53.2186 0.99996E+00 0.0000
35 N2O2-2 0.11786-102 -102.9286 0.11547-102 -102.9375 0.97971E+00 -0.0089
36 HN2O2- 0.24747E-98 -98.6065 0.24293E-98 -98.6145 0.98165E+00 -0.0080
37 H2N2O2,aq 0.56297E-98 -98.2495 0.56297E-98 -98.2495 0.10000E+01 0.0000
38 N2H5+ 0.30286-153 -153.5188 0.29730-153 -153.5268 0.98165E+00 -0.0080
39 N2H6+2 0.60688-161 -161.2169 0.59457-161 -161.2258 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15653-157 -157.8054 0.15652-157 -157.8054 0.99996E+00 0.0000
53 SO2,aq 0.34187E-69 -69.4661 0.34187E-69 -69.4661 0.10000E+01 0.0000
54 SO3-2 0.66338E-65 -65.1782 0.64992E-65 -65.1871 0.97971E+00 -0.0089
55 HSO3- 0.22589E-64 -64.6461 0.22175E-64 -64.6541 0.98165E+00 -0.0080
56 HSO4- 0.87499E-25 -25.0580 0.85893E-25 -25.0660 0.98165E+00 -0.0080
57 HSO5- 0.73468E-46 -46.1339 0.72120E-46 -46.1419 0.98165E+00 -0.0080
58 S2O3-2 0.41729-180 -180.3796 0.40882-180 -180.3885 0.97971E+00 -0.0089
59 HS2O3- 0.42912-185 -185.3674 0.42125-185 -185.3755 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34637-191 -191.4605 0.34637-191 -191.4605 0.10000E+01 0.0000
61 S2O4-2 0.78078-167 -167.1075 0.76494-167 -167.1164 0.97971E+00 -0.0089
62 HS2O4- 0.51603-171 -171.2873 0.50656-171 -171.2954 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25040-177 -177.6014 0.25040-177 -177.6014 0.10000E+01 0.0000
64 S2O5-2 0.76494-134 -134.1164 0.74942-134 -134.1253 0.97971E+00 -0.0089
65 S2O6-2 0.20357-103 -103.6913 0.19944-103 -103.7002 0.97971E+00 -0.0089
66 S2O8-2 0.40636E-78 -78.3911 0.39812E-78 -78.4000 0.97971E+00 -0.0089
Charge balance for all species = -.3986E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -20.8861
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3710-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1539-256 0.1539-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.5678-100 1.0000 0.1961E-34 0.1961E-34
SO3,gas 0.7409-123 1.0000 0.2558E-57 0.2558E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.3470-149 1.0000 0.1198E-83 0.1198E-83
N2,gas 0.2693-115 1.0000 0.9298E-50 0.9298E-50
SO2,gas 0.6694-135 1.0000 0.2311E-69 0.2311E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.813
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.81 -34.71 -7.933 0.47351E+05 -34.708
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -72.88 -83.92 -41.961 0.11449E+06 -83.921
12 N2,gas 2.57 -47.46 -50.03 -6.456 0.68257E+05 -50.032
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95004E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1075E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1075E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43235E-20 -20.3642 0.42358E-20 -20.3731 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77018-158 -158.1134 0.75605-158 -158.1214 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.30534E-79 -79.5152 0.29973E-79 -79.5233 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.11441-140 -140.9415 0.11441-140 -140.9415 0.10000E+01 0.0000
19 CN- 0.31807-143 -143.4975 0.31223-143 -143.5055 0.98165E+00 -0.0080
20 OCN- 0.25446E-96 -96.5944 0.24979E-96 -96.6024 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.80863E-82 -82.0922 0.80860E-82 -82.0923 0.99996E+00 0.0000
30 HNO2,aq 0.36985E-37 -37.4320 0.36985E-37 -37.4320 0.10000E+01 0.0000
31 NO2- 0.10545E-33 -33.9769 0.10352E-33 -33.9850 0.98165E+00 -0.0080
32 HNO3,aq 0.29182E-28 -28.5349 0.29182E-28 -28.5349 0.10000E+01 0.0000
33 NO3- 0.28000E-20 -20.5528 0.27486E-20 -20.5609 0.98165E+00 -0.0080
34 N2,aq 0.70109E-53 -53.1542 0.70106E-53 -53.1542 0.99996E+00 0.0000
35 N2O2-2 0.13669-102 -102.8643 0.13392-102 -102.8732 0.97971E+00 -0.0089
36 HN2O2- 0.28701E-98 -98.5421 0.28174E-98 -98.5502 0.98165E+00 -0.0080
37 H2N2O2,aq 0.65291E-98 -98.1851 0.65291E-98 -98.1851 0.10000E+01 0.0000
38 N2H5+ 0.35124-153 -153.4544 0.34480-153 -153.4624 0.98165E+00 -0.0080
39 N2H6+2 0.70384-161 -161.1525 0.68956-161 -161.1614 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15652-157 -157.8054 0.15651-157 -157.8054 0.99996E+00 0.0000
53 SO2,aq 0.34186E-69 -69.4662 0.34186E-69 -69.4662 0.10000E+01 0.0000
54 SO3-2 0.66334E-65 -65.1783 0.64989E-65 -65.1872 0.97971E+00 -0.0089
55 HSO3- 0.22588E-64 -64.6461 0.22174E-64 -64.6542 0.98165E+00 -0.0080
56 HSO4- 0.87494E-25 -25.0580 0.85889E-25 -25.0661 0.98165E+00 -0.0080
57 HSO5- 0.73464E-46 -46.1339 0.72116E-46 -46.1420 0.98165E+00 -0.0080
58 S2O3-2 0.41724-180 -180.3796 0.40878-180 -180.3885 0.97971E+00 -0.0089
59 HS2O3- 0.42908-185 -185.3675 0.42120-185 -185.3755 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34633-191 -191.4605 0.34633-191 -191.4605 0.10000E+01 0.0000
61 S2O4-2 0.78070-167 -167.1075 0.76486-167 -167.1164 0.97971E+00 -0.0089
62 HS2O4- 0.51598-171 -171.2874 0.50651-171 -171.2954 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25037-177 -177.6014 0.25037-177 -177.6014 0.10000E+01 0.0000
64 S2O5-2 0.76486-134 -134.1164 0.74934-134 -134.1253 0.97971E+00 -0.0089
65 S2O6-2 0.20355-103 -103.6913 0.19942-103 -103.7002 0.97971E+00 -0.0089
66 S2O8-2 0.40632E-78 -78.3911 0.39808E-78 -78.4000 0.97971E+00 -0.0089
Charge balance for all species = -.2848E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -20.8539
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3710-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1539-256 0.1539-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.6115-100 1.0000 0.2111E-34 0.2111E-34
SO3,gas 0.7409-123 1.0000 0.2558E-57 0.2558E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.3737-149 1.0000 0.1290E-83 0.1290E-83
N2,gas 0.3123-115 1.0000 0.1078E-49 0.1078E-49
SO2,gas 0.6693-135 1.0000 0.2311E-69 0.2311E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.813
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.84 -34.68 -7.926 0.47307E+05 -34.675
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -72.85 -83.89 -41.945 0.11445E+06 -83.889
12 N2,gas 2.57 -47.40 -49.97 -6.447 0.68170E+05 -49.967
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95004E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1055E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1055E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43233E-20 -20.3642 0.42356E-20 -20.3731 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77014-158 -158.1134 0.75601-158 -158.1215 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.32715E-79 -79.4853 0.32114E-79 -79.4933 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.12259-140 -140.9116 0.12259-140 -140.9116 0.10000E+01 0.0000
19 CN- 0.34078-143 -143.4675 0.33453-143 -143.4756 0.98165E+00 -0.0080
20 OCN- 0.27263E-96 -96.5644 0.26763E-96 -96.5725 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.86639E-82 -82.0623 0.86636E-82 -82.0623 0.99996E+00 0.0000
30 HNO2,aq 0.39627E-37 -37.4020 0.39627E-37 -37.4020 0.10000E+01 0.0000
31 NO2- 0.11299E-33 -33.9470 0.11091E-33 -33.9550 0.98165E+00 -0.0080
32 HNO3,aq 0.31267E-28 -28.5049 0.31267E-28 -28.5049 0.10000E+01 0.0000
33 NO3- 0.30000E-20 -20.5229 0.29450E-20 -20.5309 0.98165E+00 -0.0080
34 N2,aq 0.80482E-53 -53.0943 0.80479E-53 -53.0943 0.99996E+00 0.0000
35 N2O2-2 0.15692-102 -102.8043 0.15373-102 -102.8132 0.97971E+00 -0.0089
36 HN2O2- 0.32947E-98 -98.4822 0.32343E-98 -98.4902 0.98165E+00 -0.0080
37 H2N2O2,aq 0.74951E-98 -98.1252 0.74951E-98 -98.1252 0.10000E+01 0.0000
38 N2H5+ 0.40321-153 -153.3945 0.39582-153 -153.4025 0.98165E+00 -0.0080
39 N2H6+2 0.80797-161 -161.0926 0.79158-161 -161.1015 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15651-157 -157.8054 0.15651-157 -157.8055 0.99996E+00 0.0000
53 SO2,aq 0.34184E-69 -69.4662 0.34184E-69 -69.4662 0.10000E+01 0.0000
54 SO3-2 0.66331E-65 -65.1783 0.64985E-65 -65.1872 0.97971E+00 -0.0089
55 HSO3- 0.22587E-64 -64.6461 0.22173E-64 -64.6542 0.98165E+00 -0.0080
56 HSO4- 0.87490E-25 -25.0580 0.85884E-25 -25.0661 0.98165E+00 -0.0080
57 HSO5- 0.73460E-46 -46.1339 0.72113E-46 -46.1420 0.98165E+00 -0.0080
58 S2O3-2 0.41720-180 -180.3797 0.40874-180 -180.3886 0.97971E+00 -0.0089
59 HS2O3- 0.42903-185 -185.3675 0.42116-185 -185.3756 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34630-191 -191.4605 0.34630-191 -191.4605 0.10000E+01 0.0000
61 S2O4-2 0.78062-167 -167.1076 0.76479-167 -167.1165 0.97971E+00 -0.0089
62 HS2O4- 0.51592-171 -171.2874 0.50646-171 -171.2955 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25035-177 -177.6015 0.25035-177 -177.6015 0.10000E+01 0.0000
64 S2O5-2 0.76478-134 -134.1165 0.74927-134 -134.1254 0.97971E+00 -0.0089
65 S2O6-2 0.20353-103 -103.6914 0.19940-103 -103.7003 0.97971E+00 -0.0089
66 S2O8-2 0.40628E-78 -78.3912 0.39804E-78 -78.4001 0.97971E+00 -0.0089
Charge balance for all species = -.3140E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -20.8239
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3710-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1539-256 0.1539-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.6552-100 1.0000 0.2262E-34 0.2262E-34
SO3,gas 0.7408-123 1.0000 0.2558E-57 0.2558E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.4004-149 1.0000 0.1383E-83 0.1383E-83
N2,gas 0.3585-115 1.0000 0.1238E-49 0.1238E-49
SO2,gas 0.6693-135 1.0000 0.2311E-69 0.2311E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.813
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.87 -34.65 -7.919 0.47266E+05 -34.645
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -72.82 -83.86 -41.930 0.11441E+06 -83.859
12 N2,gas 2.57 -47.34 -49.91 -6.440 0.68088E+05 -49.907
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95004E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1035E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1035E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43231E-20 -20.3642 0.42353E-20 -20.3731 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77010-158 -158.1135 0.75597-158 -158.1215 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.34896E-79 -79.4572 0.34255E-79 -79.4653 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.13076-140 -140.8835 0.13076-140 -140.8835 0.10000E+01 0.0000
19 CN- 0.36350-143 -143.4395 0.35683-143 -143.4475 0.98165E+00 -0.0080
20 OCN- 0.29081E-96 -96.5364 0.28547E-96 -96.5444 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.92415E-82 -82.0343 0.92411E-82 -82.0343 0.99996E+00 0.0000
30 HNO2,aq 0.42268E-37 -37.3740 0.42268E-37 -37.3740 0.10000E+01 0.0000
31 NO2- 0.12052E-33 -33.9189 0.11831E-33 -33.9270 0.98165E+00 -0.0080
32 HNO3,aq 0.33351E-28 -28.4769 0.33351E-28 -28.4769 0.10000E+01 0.0000
33 NO3- 0.32000E-20 -20.4949 0.31413E-20 -20.5029 0.98165E+00 -0.0080
34 N2,aq 0.91571E-53 -53.0382 0.91567E-53 -53.0383 0.99996E+00 0.0000
35 N2O2-2 0.17854-102 -102.7483 0.17492-102 -102.7572 0.97971E+00 -0.0089
36 HN2O2- 0.37487E-98 -98.4261 0.36799E-98 -98.4342 0.98165E+00 -0.0080
37 H2N2O2,aq 0.85278E-98 -98.0692 0.85278E-98 -98.0692 0.10000E+01 0.0000
38 N2H5+ 0.45877-153 -153.3384 0.45035-153 -153.3464 0.98165E+00 -0.0080
39 N2H6+2 0.91930-161 -161.0365 0.90065-161 -161.0454 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15651-157 -157.8055 0.15650-157 -157.8055 0.99996E+00 0.0000
53 SO2,aq 0.34182E-69 -69.4662 0.34182E-69 -69.4662 0.10000E+01 0.0000
54 SO3-2 0.66328E-65 -65.1783 0.64982E-65 -65.1872 0.97971E+00 -0.0089
55 HSO3- 0.22586E-64 -64.6462 0.22172E-64 -64.6542 0.98165E+00 -0.0080
56 HSO4- 0.87485E-25 -25.0581 0.85880E-25 -25.0661 0.98165E+00 -0.0080
57 HSO5- 0.73457E-46 -46.1340 0.72109E-46 -46.1420 0.98165E+00 -0.0080
58 S2O3-2 0.41716-180 -180.3797 0.40870-180 -180.3886 0.97971E+00 -0.0089
59 HS2O3- 0.42899-185 -185.3676 0.42112-185 -185.3756 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34626-191 -191.4606 0.34626-191 -191.4606 0.10000E+01 0.0000
61 S2O4-2 0.78054-167 -167.1076 0.76471-167 -167.1165 0.97971E+00 -0.0089
62 HS2O4- 0.51587-171 -171.2875 0.50641-171 -171.2955 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25032-177 -177.6015 0.25032-177 -177.6015 0.10000E+01 0.0000
64 S2O5-2 0.76471-134 -134.1165 0.74919-134 -134.1254 0.97971E+00 -0.0089
65 S2O6-2 0.20351-103 -103.6914 0.19938-103 -103.7003 0.97971E+00 -0.0089
66 S2O8-2 0.40624E-78 -78.3912 0.39800E-78 -78.4001 0.97971E+00 -0.0089
Charge balance for all species = -.1839E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -20.7959
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3710-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1539-256 0.1539-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.6988-100 1.0000 0.2413E-34 0.2413E-34
SO3,gas 0.7408-123 1.0000 0.2558E-57 0.2558E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.4271-149 1.0000 0.1475E-83 0.1475E-83
N2,gas 0.4079-115 1.0000 0.1408E-49 0.1408E-49
SO2,gas 0.6693-135 1.0000 0.2311E-69 0.2311E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.892
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.813
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.90 -34.62 -7.913 0.47228E+05 -34.617
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -72.79 -83.83 -41.916 0.11437E+06 -83.831
12 N2,gas 2.57 -47.28 -49.85 -6.432 0.68011E+05 -49.851
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95004E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.1015E-19
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.1015E-19 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43228E-20 -20.3642 0.42351E-20 -20.3731 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77006-158 -158.1135 0.75594-158 -158.1215 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.37077E-79 -79.4309 0.36396E-79 -79.4389 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.13893-140 -140.8572 0.13893-140 -140.8572 0.10000E+01 0.0000
19 CN- 0.38622-143 -143.4132 0.37914-143 -143.4212 0.98165E+00 -0.0080
20 OCN- 0.30898E-96 -96.5101 0.30331E-96 -96.5181 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.98191E-82 -82.0079 0.98187E-82 -82.0079 0.99996E+00 0.0000
30 HNO2,aq 0.44910E-37 -37.3477 0.44910E-37 -37.3477 0.10000E+01 0.0000
31 NO2- 0.12805E-33 -33.8926 0.12570E-33 -33.9007 0.98165E+00 -0.0080
32 HNO3,aq 0.35436E-28 -28.4506 0.35436E-28 -28.4506 0.10000E+01 0.0000
33 NO3- 0.34000E-20 -20.4685 0.33376E-20 -20.4766 0.98165E+00 -0.0080
34 N2,aq 0.10338E-52 -52.9856 0.10337E-52 -52.9856 0.99996E+00 0.0000
35 N2O2-2 0.20155-102 -102.6956 0.19746-102 -102.7045 0.97971E+00 -0.0089
36 HN2O2- 0.42319E-98 -98.3735 0.41542E-98 -98.3815 0.98165E+00 -0.0080
37 H2N2O2,aq 0.96271E-98 -98.0165 0.96271E-98 -98.0165 0.10000E+01 0.0000
38 N2H5+ 0.51791-153 -153.2857 0.50840-153 -153.2938 0.98165E+00 -0.0080
39 N2H6+2 0.10378-160 -160.9839 0.10167-160 -160.9928 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15650-157 -157.8055 0.15649-157 -157.8055 0.99996E+00 0.0000
53 SO2,aq 0.34180E-69 -69.4662 0.34180E-69 -69.4662 0.10000E+01 0.0000
54 SO3-2 0.66324E-65 -65.1783 0.64979E-65 -65.1872 0.97971E+00 -0.0089
55 HSO3- 0.22585E-64 -64.6462 0.22170E-64 -64.6542 0.98165E+00 -0.0080
56 HSO4- 0.87481E-25 -25.0581 0.85876E-25 -25.0661 0.98165E+00 -0.0080
57 HSO5- 0.73453E-46 -46.1340 0.72105E-46 -46.1420 0.98165E+00 -0.0080
58 S2O3-2 0.41712-180 -180.3797 0.40865-180 -180.3886 0.97971E+00 -0.0089
59 HS2O3- 0.42894-185 -185.3676 0.42107-185 -185.3756 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34623-191 -191.4606 0.34623-191 -191.4606 0.10000E+01 0.0000
61 S2O4-2 0.78047-167 -167.1076 0.76463-167 -167.1165 0.97971E+00 -0.0089
62 HS2O4- 0.51582-171 -171.2875 0.50636-171 -171.2955 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25030-177 -177.6015 0.25030-177 -177.6015 0.10000E+01 0.0000
64 S2O5-2 0.76463-134 -134.1166 0.74911-134 -134.1255 0.97971E+00 -0.0089
65 S2O6-2 0.20349-103 -103.6915 0.19936-103 -103.7004 0.97971E+00 -0.0089
66 S2O8-2 0.40620E-78 -78.3913 0.39796E-78 -78.4002 0.97971E+00 -0.0089
Charge balance for all species = -.3536E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -20.7696
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3709-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1539-256 0.1539-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.7425-100 1.0000 0.2564E-34 0.2564E-34
SO3,gas 0.7408-123 1.0000 0.2558E-57 0.2558E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.4538-149 1.0000 0.1567E-83 0.1567E-83
N2,gas 0.4605-115 1.0000 0.1590E-49 0.1590E-49
SO2,gas 0.6692-135 1.0000 0.2311E-69 0.2311E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.893
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.813
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.92 -34.59 -7.907 0.47192E+05 -34.591
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -72.77 -83.80 -41.902 0.11433E+06 -83.805
12 N2,gas 2.57 -47.23 -49.80 -6.426 0.67939E+05 -49.799
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95004E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.9953E-20
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.9953E-20 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43226E-20 -20.3643 0.42349E-20 -20.3732 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.77003-158 -158.1135 0.75590-158 -158.1215 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.39258E-79 -79.4061 0.38537E-79 -79.4141 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.14710-140 -140.8324 0.14710-140 -140.8324 0.10000E+01 0.0000
19 CN- 0.40894-143 -143.3883 0.40144-143 -143.3964 0.98165E+00 -0.0080
20 OCN- 0.32716E-96 -96.4852 0.32116E-96 -96.4933 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.10397E-81 -81.9831 0.10396E-81 -81.9831 0.99996E+00 0.0000
30 HNO2,aq 0.47552E-37 -37.3228 0.47552E-37 -37.3228 0.10000E+01 0.0000
31 NO2- 0.13558E-33 -33.8678 0.13310E-33 -33.8758 0.98165E+00 -0.0080
32 HNO3,aq 0.37520E-28 -28.4257 0.37520E-28 -28.4257 0.10000E+01 0.0000
33 NO3- 0.36000E-20 -20.4437 0.35339E-20 -20.4517 0.98165E+00 -0.0080
34 N2,aq 0.11589E-52 -52.9359 0.11589E-52 -52.9360 0.99996E+00 0.0000
35 N2O2-2 0.22596-102 -102.6460 0.22138-102 -102.6549 0.97971E+00 -0.0089
36 HN2O2- 0.47444E-98 -98.3238 0.46573E-98 -98.3319 0.98165E+00 -0.0080
37 H2N2O2,aq 0.10793E-97 -97.9669 0.10793E-97 -97.9669 0.10000E+01 0.0000
38 N2H5+ 0.58063-153 -153.2361 0.56997-153 -153.2441 0.98165E+00 -0.0080
39 N2H6+2 0.11635-160 -160.9342 0.11399-160 -160.9431 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15649-157 -157.8055 0.15648-157 -157.8055 0.99996E+00 0.0000
53 SO2,aq 0.34179E-69 -69.4662 0.34179E-69 -69.4662 0.10000E+01 0.0000
54 SO3-2 0.66321E-65 -65.1783 0.64975E-65 -65.1873 0.97971E+00 -0.0089
55 HSO3- 0.22584E-64 -64.6462 0.22169E-64 -64.6542 0.98165E+00 -0.0080
56 HSO4- 0.87476E-25 -25.0581 0.85871E-25 -25.0662 0.98165E+00 -0.0080
57 HSO5- 0.73449E-46 -46.1340 0.72102E-46 -46.1421 0.98165E+00 -0.0080
58 S2O3-2 0.41707-180 -180.3798 0.40861-180 -180.3887 0.97971E+00 -0.0089
59 HS2O3- 0.42890-185 -185.3676 0.42103-185 -185.3757 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34619-191 -191.4607 0.34619-191 -191.4607 0.10000E+01 0.0000
61 S2O4-2 0.78039-167 -167.1077 0.76455-167 -167.1166 0.97971E+00 -0.0089
62 HS2O4- 0.51577-171 -171.2875 0.50630-171 -171.2956 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25027-177 -177.6016 0.25027-177 -177.6016 0.10000E+01 0.0000
64 S2O5-2 0.76455-134 -134.1166 0.74904-134 -134.1255 0.97971E+00 -0.0089
65 S2O6-2 0.20347-103 -103.6915 0.19934-103 -103.7004 0.97971E+00 -0.0089
66 S2O8-2 0.40616E-78 -78.3913 0.39792E-78 -78.4002 0.97971E+00 -0.0089
Charge balance for all species = -.2318E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -20.7447
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3709-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1539-256 0.1539-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.7862-100 1.0000 0.2715E-34 0.2715E-34
SO3,gas 0.7407-123 1.0000 0.2558E-57 0.2558E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.4805-149 1.0000 0.1659E-83 0.1659E-83
N2,gas 0.5162-115 1.0000 0.1783E-49 0.1783E-49
SO2,gas 0.6692-135 1.0000 0.2311E-69 0.2311E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.893
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.813
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.95 -34.57 -7.901 0.47158E+05 -34.566
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -72.74 -83.78 -41.890 0.11430E+06 -83.780
12 N2,gas 2.57 -47.18 -49.75 -6.419 0.67872E+05 -49.749
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95004E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.9753E-20
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.9753E-20 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43224E-20 -20.3643 0.42347E-20 -20.3732 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.76999-158 -158.1135 0.75586-158 -158.1216 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.41439E-79 -79.3826 0.40678E-79 -79.3906 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.15528-140 -140.8089 0.15528-140 -140.8089 0.10000E+01 0.0000
19 CN- 0.43166-143 -143.3649 0.42374-143 -143.3729 0.98165E+00 -0.0080
20 OCN- 0.34533E-96 -96.4618 0.33900E-96 -96.4698 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.10974E-81 -81.9596 0.10974E-81 -81.9596 0.99996E+00 0.0000
30 HNO2,aq 0.50194E-37 -37.2994 0.50194E-37 -37.2994 0.10000E+01 0.0000
31 NO2- 0.14312E-33 -33.8443 0.14049E-33 -33.8524 0.98165E+00 -0.0080
32 HNO3,aq 0.39605E-28 -28.4023 0.39605E-28 -28.4023 0.10000E+01 0.0000
33 NO3- 0.38000E-20 -20.4202 0.37303E-20 -20.4283 0.98165E+00 -0.0080
34 N2,aq 0.12913E-52 -52.8890 0.12912E-52 -52.8890 0.99996E+00 0.0000
35 N2O2-2 0.25177-102 -102.5990 0.24666-102 -102.6079 0.97971E+00 -0.0089
36 HN2O2- 0.52862E-98 -98.2769 0.51892E-98 -98.2849 0.98165E+00 -0.0080
37 H2N2O2,aq 0.12026E-97 -97.9199 0.12026E-97 -97.9199 0.10000E+01 0.0000
38 N2H5+ 0.64693-153 -153.1891 0.63506-153 -153.1972 0.98165E+00 -0.0080
39 N2H6+2 0.12964-160 -160.8873 0.12701-160 -160.8962 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15648-157 -157.8055 0.15647-157 -157.8056 0.99996E+00 0.0000
53 SO2,aq 0.34177E-69 -69.4663 0.34177E-69 -69.4663 0.10000E+01 0.0000
54 SO3-2 0.66318E-65 -65.1784 0.64972E-65 -65.1873 0.97971E+00 -0.0089
55 HSO3- 0.22583E-64 -64.6462 0.22168E-64 -64.6543 0.98165E+00 -0.0080
56 HSO4- 0.87472E-25 -25.0581 0.85867E-25 -25.0662 0.98165E+00 -0.0080
57 HSO5- 0.73446E-46 -46.1340 0.72098E-46 -46.1421 0.98165E+00 -0.0080
58 S2O3-2 0.41703-180 -180.3798 0.40857-180 -180.3887 0.97971E+00 -0.0089
59 HS2O3- 0.42886-185 -185.3677 0.42099-185 -185.3757 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34616-191 -191.4607 0.34616-191 -191.4607 0.10000E+01 0.0000
61 S2O4-2 0.78031-167 -167.1077 0.76448-167 -167.1166 0.97971E+00 -0.0089
62 HS2O4- 0.51572-171 -171.2876 0.50625-171 -171.2956 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25025-177 -177.6016 0.25025-177 -177.6016 0.10000E+01 0.0000
64 S2O5-2 0.76447-134 -134.1166 0.74896-134 -134.1255 0.97971E+00 -0.0089
65 S2O6-2 0.20345-103 -103.6915 0.19932-103 -103.7004 0.97971E+00 -0.0089
66 S2O8-2 0.40612E-78 -78.3913 0.39788E-78 -78.4003 0.97971E+00 -0.0089
Charge balance for all species = -.4101E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -20.7212
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3709-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1538-256 0.1538-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.8299-100 1.0000 0.2865E-34 0.2865E-34
SO3,gas 0.7407-123 1.0000 0.2558E-57 0.2558E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.5072-149 1.0000 0.1751E-83 0.1751E-83
N2,gas 0.5752-115 1.0000 0.1986E-49 0.1986E-49
SO2,gas 0.6692-135 1.0000 0.2311E-69 0.2311E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.893
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.813
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 41.97 -34.54 -7.895 0.47126E+05 -34.543
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -72.72 -83.76 -41.878 0.11427E+06 -83.757
12 N2,gas 2.57 -47.13 -49.70 -6.413 0.67808E+05 -49.702
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95004E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.9553E-20
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.9553E-20 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43222E-20 -20.3643 0.42345E-20 -20.3732 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.76995-158 -158.1135 0.75582-158 -158.1216 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.43620E-79 -79.3603 0.42819E-79 -79.3684 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.16345-140 -140.7866 0.16345-140 -140.7866 0.10000E+01 0.0000
19 CN- 0.45438-143 -143.3426 0.44604-143 -143.3506 0.98165E+00 -0.0080
20 OCN- 0.36351E-96 -96.4395 0.35684E-96 -96.4475 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.11552E-81 -81.9373 0.11551E-81 -81.9374 0.99996E+00 0.0000
30 HNO2,aq 0.52835E-37 -37.2771 0.52835E-37 -37.2771 0.10000E+01 0.0000
31 NO2- 0.15065E-33 -33.8220 0.14788E-33 -33.8301 0.98165E+00 -0.0080
32 HNO3,aq 0.41689E-28 -28.3800 0.41689E-28 -28.3800 0.10000E+01 0.0000
33 NO3- 0.40000E-20 -20.3979 0.39266E-20 -20.4060 0.98165E+00 -0.0080
34 N2,aq 0.14308E-52 -52.8444 0.14307E-52 -52.8444 0.99996E+00 0.0000
35 N2O2-2 0.27897-102 -102.5544 0.27331-102 -102.5634 0.97971E+00 -0.0089
36 HN2O2- 0.58573E-98 -98.2323 0.57498E-98 -98.2403 0.98165E+00 -0.0080
37 H2N2O2,aq 0.13325E-97 -97.8753 0.13325E-97 -97.8753 0.10000E+01 0.0000
38 N2H5+ 0.71682-153 -153.1446 0.70367-153 -153.1526 0.98165E+00 -0.0080
39 N2H6+2 0.14364-160 -160.8427 0.14073-160 -160.8516 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15647-157 -157.8056 0.15647-157 -157.8056 0.99996E+00 0.0000
53 SO2,aq 0.34175E-69 -69.4663 0.34175E-69 -69.4663 0.10000E+01 0.0000
54 SO3-2 0.66314E-65 -65.1784 0.64969E-65 -65.1873 0.97971E+00 -0.0089
55 HSO3- 0.22581E-64 -64.6462 0.22167E-64 -64.6543 0.98165E+00 -0.0080
56 HSO4- 0.87468E-25 -25.0582 0.85863E-25 -25.0662 0.98165E+00 -0.0080
57 HSO5- 0.73442E-46 -46.1341 0.72094E-46 -46.1421 0.98165E+00 -0.0080
58 S2O3-2 0.41699-180 -180.3799 0.40853-180 -180.3888 0.97971E+00 -0.0089
59 HS2O3- 0.42881-185 -185.3677 0.42095-185 -185.3758 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34612-191 -191.4608 0.34612-191 -191.4608 0.10000E+01 0.0000
61 S2O4-2 0.78023-167 -167.1078 0.76440-167 -167.1167 0.97971E+00 -0.0089
62 HS2O4- 0.51566-171 -171.2876 0.50620-171 -171.2957 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25022-177 -177.6017 0.25022-177 -177.6017 0.10000E+01 0.0000
64 S2O5-2 0.76440-134 -134.1167 0.74889-134 -134.1256 0.97971E+00 -0.0089
65 S2O6-2 0.20343-103 -103.6916 0.19930-103 -103.7005 0.97971E+00 -0.0089
66 S2O8-2 0.40608E-78 -78.3914 0.39784E-78 -78.4003 0.97971E+00 -0.0089
Charge balance for all species = -.2978E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -20.6990
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3709-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1538-256 0.1538-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.8735-100 1.0000 0.3016E-34 0.3016E-34
SO3,gas 0.7407-123 1.0000 0.2557E-57 0.2557E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.5339-149 1.0000 0.1843E-83 0.1843E-83
N2,gas 0.6373-115 1.0000 0.2201E-49 0.2201E-49
SO2,gas 0.6691-135 1.0000 0.2311E-69 0.2311E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.893
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.813
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 42.00 -34.52 -7.890 0.47096E+05 -34.521
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -72.70 -83.73 -41.867 0.11424E+06 -83.734
12 N2,gas 2.57 -47.09 -49.66 -6.407 0.67747E+05 -49.657
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95004E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.9353E-20
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Merapi workup for air saturated water (ASW). Oxygen part already done in Solveq.
Now add N2
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
Number of loops used = 6 Loop limit = 400
Temperature = 25.00 C Pressure = 1.00 bar Mixer fraction = 0.0000000
Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01
Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000
Stoichiometric ionic strength = .1802000E-03 Osmotic coef. = 0.9898
True ionic strength = .3168084E-06
Chg. balance for total moles = -.9353E-20 Max. difference allowed = 0.1000E-10
Log Log Log
Species(n) Molality Molality Activity Activity Gamma Gamma
1 H+ 0.21679E-06 -6.6640 0.21282E-06 -6.6720 0.98165E+00 -0.0080
2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000
3 Cl- 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
4 SO4-- 0.43220E-20 -20.3643 0.42343E-20 -20.3732 0.97971E+00 -0.0089
5 HCO3- 0.68372E-07 -7.1651 0.67118E-07 -7.1732 0.98165E+00 -0.0080
6 HS- 0.76991-158 -158.1136 0.75578-158 -158.1216 0.98165E+00 -0.0080
7 Na+ 0.10000E-06 -7.0000 0.98165E-07 -7.0080 0.98165E+00 -0.0080
8 F- 0.99969E-07 -7.0001 0.98135E-07 -7.0082 0.98165E+00 -0.0080
9 NH4+ 0.45801E-79 -79.3391 0.44960E-79 -79.3472 0.98165E+00 -0.0080
10 CH4,aq 0.15328-150 -150.8145 0.15327-150 -150.8145 0.99996E+00 0.0000
15 CO,aq 0.18397E-53 -53.7353 0.18397E-53 -53.7353 0.10000E+01 0.0000
16 CO2,aq 0.31613E-07 -7.5001 0.31611E-07 -7.5002 0.99996E+00 0.0000
17 CO3-2 0.15092E-10 -10.8213 0.14785E-10 -10.8302 0.97971E+00 -0.0089
18 HCN,aq 0.17162-140 -140.7654 0.17162-140 -140.7654 0.10000E+01 0.0000
19 CN- 0.47710-143 -143.3214 0.46835-143 -143.3294 0.98165E+00 -0.0080
20 OCN- 0.38168E-96 -96.4183 0.37468E-96 -96.4263 0.98165E+00 -0.0080
22 HCl,aq 0.40734E-14 -14.3900 0.40734E-14 -14.3900 0.10000E+01 0.0000
23 HClO,aq 0.90794E-23 -23.0419 0.90794E-23 -23.0419 0.10000E+01 0.0000
24 ClO- 0.12249E-23 -23.9119 0.12024E-23 -23.9199 0.98165E+00 -0.0080
25 HClO2,aq 0.37252E-38 -38.4288 0.37252E-38 -38.4288 0.10000E+01 0.0000
26 HF,aq 0.30749E-10 -10.5122 0.30749E-10 -10.5122 0.10000E+01 0.0000
27 HF2- 0.74250E-18 -18.1293 0.72887E-18 -18.1373 0.98165E+00 -0.0080
28 H2,aq 0.50573E-44 -44.2961 0.50571E-44 -44.2961 0.99996E+00 0.0000
29 NH3,aq 0.12129E-81 -81.9162 0.12129E-81 -81.9162 0.99996E+00 0.0000
30 HNO2,aq 0.55477E-37 -37.2559 0.55477E-37 -37.2559 0.10000E+01 0.0000
31 NO2- 0.15818E-33 -33.8008 0.15528E-33 -33.8089 0.98165E+00 -0.0080
32 HNO3,aq 0.43773E-28 -28.3588 0.43773E-28 -28.3588 0.10000E+01 0.0000
33 NO3- 0.42000E-20 -20.3768 0.41229E-20 -20.3848 0.98165E+00 -0.0080
34 N2,aq 0.15775E-52 -52.8020 0.15774E-52 -52.8021 0.99996E+00 0.0000
35 N2O2-2 0.30756-102 -102.5121 0.30132-102 -102.5210 0.97971E+00 -0.0089
36 HN2O2- 0.64576E-98 -98.1899 0.63392E-98 -98.1980 0.98165E+00 -0.0080
37 H2N2O2,aq 0.14690E-97 -97.8330 0.14690E-97 -97.8330 0.10000E+01 0.0000
38 N2H5+ 0.79030-153 -153.1022 0.77580-153 -153.1103 0.98165E+00 -0.0080
39 N2H6+2 0.15836-160 -160.8003 0.15515-160 -160.8092 0.97971E+00 -0.0089
40 NaCl,aq 0.16103E-14 -14.7931 0.16103E-14 -14.7931 0.10000E+01 0.0000
41 NaF,aq 0.96779E-15 -15.0142 0.96779E-15 -15.0142 0.10000E+01 0.0000
42 NaOH,aq 0.28771E-14 -14.5410 0.28771E-14 -14.5410 0.10000E+01 0.0000
43 O2,aq 0.24000E-03 -3.6198 0.23999E-03 -3.6198 0.99996E+00 0.0000
44 OH- 0.48422E-07 -7.3150 0.47533E-07 -7.3230 0.98165E+00 -0.0080
45 HO2- 0.36403E-23 -23.4389 0.35735E-23 -23.4469 0.98165E+00 -0.0080
46 H2O2,aq 0.36736E-18 -18.4349 0.36736E-18 -18.4349 0.10000E+01 0.0000
47 H2S,aq 0.15647-157 -157.8056 0.15646-157 -157.8056 0.99996E+00 0.0000
53 SO2,aq 0.34174E-69 -69.4663 0.34174E-69 -69.4663 0.10000E+01 0.0000
54 SO3-2 0.66311E-65 -65.1784 0.64965E-65 -65.1873 0.97971E+00 -0.0089
55 HSO3- 0.22580E-64 -64.6463 0.22166E-64 -64.6543 0.98165E+00 -0.0080
56 HSO4- 0.87463E-25 -25.0582 0.85858E-25 -25.0662 0.98165E+00 -0.0080
57 HSO5- 0.73438E-46 -46.1341 0.72091E-46 -46.1421 0.98165E+00 -0.0080
58 S2O3-2 0.41695-180 -180.3799 0.40849-180 -180.3888 0.97971E+00 -0.0089
59 HS2O3- 0.42877-185 -185.3678 0.42090-185 -185.3758 0.98165E+00 -0.0080
60 H2S2O3,aq 0.34609-191 -191.4608 0.34609-191 -191.4608 0.10000E+01 0.0000
61 S2O4-2 0.78015-167 -167.1078 0.76432-167 -167.1167 0.97971E+00 -0.0089
62 HS2O4- 0.51561-171 -171.2877 0.50615-171 -171.2957 0.98165E+00 -0.0080
63 H2S2O4,aq 0.25020-177 -177.6017 0.25020-177 -177.6017 0.10000E+01 0.0000
64 S2O5-2 0.76432-134 -134.1167 0.74881-134 -134.1256 0.97971E+00 -0.0089
65 S2O6-2 0.20341-103 -103.6916 0.19928-103 -103.7005 0.97971E+00 -0.0089
66 S2O8-2 0.40604E-78 -78.3914 0.39780E-78 -78.4003 0.97971E+00 -0.0089
Charge balance for all species = -.3268E-19
Solid products produced: Mass = 0.000000 g Volume = 0.000000 cm3
WARNING: mineral volume may be in error because some mineral densities
were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt.
Reactant consumed: 0.0000000 moles log = -20.6778
Original solution: 0.0000000 g
Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000
Gas composition at saturation ( 0 iterations)
-------------------------------------------------
Temperature: 25.0000 deg.C
Sat. pressure: 600.0000 bar
Gas Mole fraction phi Fugacity Partial P(bar)
H2O,gas 0.8929E-67 1.0000 0.3083E-01 0.3083E-01
CO2,gas 0.2683E-71 1.0000 0.9265E-06 0.9265E-06
CH4,gas 0.3667-213 1.0000 0.1266-147 0.1266-147
H2,gas 0.1869-106 1.0000 0.6455E-41 0.6455E-41
H2S,gas 0.3709-222 1.0000 0.1281-156 0.1281-156
S2,gas 0.4447-322 1.0000 0.1538-256 0.1538-256
CO,gas 0.5414-116 1.0000 0.1870E-50 0.1870E-50
NO2,gas 0.9172-100 1.0000 0.3167E-34 0.3167E-34
SO3,gas 0.7406-123 1.0000 0.2557E-57 0.2557E-57
O2,gas 0.1000E+01 1.0000 0.3453E+66 0.3453E+66
NH3,gas 0.5606-149 1.0000 0.1936E-83 0.1936E-83
N2,gas 0.7027-115 1.0000 0.2426E-49 0.2426E-49
SO2,gas 0.6691-135 1.0000 0.2310E-69 0.2310E-69
HF,gas 0.4684E-80 1.0000 0.1617E-14 0.1617E-14
NON-Ideal mixing with H2O, CO2, CH4 Gases
++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
The following gases and minerals are presently EXCLUDED from matrix
(Gases and minerals with log(Q/K) less than -5 are not listed below)
Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity
1 H2O,gas 1.51 0.00 -1.51 -1.511 0.20614E+04 -1.511
2 CO2,gas -7.81 -13.85 -6.03 -2.011 0.82309E+04 -6.033
3 CH4,gas 2.98 -144.92 -147.90 -36.974 0.20177E+06 -147.898
4 H2,gas 8.42 -32.77 -41.19 -23.537 0.56195E+05 -41.190
5 H2S,gas -7.90 -164.79 -156.89 -78.446 0.21405E+06 -156.893
6 S2,gas -7.24 -264.05 -256.81 -39.510 0.35037E+06 -256.813
7 CO,gas 4.11 -46.61 -50.73 -15.609 0.69208E+05 -50.728
8 NO2,gas 76.52 42.02 -34.50 -7.886 0.47067E+05 -34.499
9 SO3,gas 23.88 -33.72 -57.59 -14.398 0.78572E+05 -57.592
10 O2,gas 66.26 65.54 -0.72 -0.480 0.98202E+03 -0.720
11 NH3,gas 11.04 -72.68 -83.71 -41.857 0.11421E+06 -83.713
12 N2,gas 2.57 -47.04 -49.62 -6.402 0.67689E+05 -49.615
13 SO2,gas 3.15 -66.49 -69.64 -18.570 0.95004E+05 -69.636
14 HF,gas 1.11 -13.68 -14.79 -7.396 0.20179E+05 -14.791
15 HCl,gas 6.31 -13.68 -19.99 -9.993 0.27267E+05 -19.986
Calculations done for 25.0000 Deg. C; 1.0000 bar
Next reactant titration increment of: 0.0000000 MOLES
Current total amount of reactant added: 0.0000000 MOLES
New total amount of reactant added: 0.0000000 MOLES
Solids and gases carried
Charge balance check after fractionation or titration: TBAL = -.9153E-20
******** WARNING ********
Computational singularity, IV(N) = 0.0