File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.82793E+02 0.88643E-10 0.8400 0.00000000E+00 H2O 2 0. -0.71688E+01 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13787E-03 0.27671E-03 0.8350 0.00000000E+00 SO4-- 4 -2. 0.13859E+00 0.13010E-11 0.5188 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.48132E-06 0.8362 0.00000000E+00 HS- 6 -1. -0.13857E+00 0.51376E-04 0.8351 0.00000000E+00 Al+++ 7 3. 0.16304E+02 0.98214E-29 0.2305 0.00000000E+00 H4SiO4 8 0. 0.52064E+02 0.69598E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.57507E+01 0.13613E-06 0.5149 0.00000000E+00 Mg++ 10 2. 0.39683E+01 0.21297E-10 0.5126 0.00000000E+00 Fe++ 11 2. 0.35650E+01 0.58699E-13 0.5131 0.00000000E+00 K+ 12 1. 0.10616E+01 0.15714E-03 0.8364 0.00000000E+00 Na+ 13 1. 0.62764E+01 0.19940E-01 0.8348 0.00000000E+00 Mn++ 14 2. 0.86693E-01 0.18830E-10 0.5136 0.00000000E+00 F- 15 -1. 0.10000E-06 0.10000E-05 1.0000 0.00000000E+00 HPO4-- 16 -2. 0.29588E-01 0.45033E-07 0.5188 0.00000000E+00 Chg. balance for total moles = -.3660E-10 Max. difference allowed = 0.1379E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.400000E-03 TEMP = 100.0000 SINC = 0.1000E-04 TEMPC = 0.0000 TOTMIX = 0.000000E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 2000.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 1 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.6260E+01 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.5544E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.1342E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.9863E-02 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.0000E+00 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.3220E+01 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.2614E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.7103E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.2056E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.1734E-01 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.2627E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.6813E-01 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.9308E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.4248E-01 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0000000 moles log =-100.0000 Original solution: 1000.0103000 g Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000000 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1143362E-01 Osmotic coef. = 0.9685 True ionic strength = .2009850E-01 Chg. balance for total moles = -.3660E-10 Max. difference allowed = 0.1379E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88643E-10 -10.0524 0.74464E-10 -10.1281 0.84004E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27651E-03 -3.5583 0.23088E-03 -3.6366 0.83497E+00 -0.0783 4 SO4-- 0.13010E-11 -11.8857 0.67494E-12 -12.1707 0.51877E+00 -0.2850 5 HCO3- 0.48132E-06 -6.3176 0.40248E-06 -6.3953 0.83620E+00 -0.0777 6 HS- 0.51376E-04 -4.2892 0.42904E-04 -4.3675 0.83510E+00 -0.0783 7 Al+++ 0.98214E-29 -29.0078 0.22636E-29 -29.6452 0.23048E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13613E-06 -6.8660 0.70100E-07 -7.1543 0.51495E+00 -0.2882 10 Mg++ 0.21297E-10 -10.6717 0.10917E-10 -10.9619 0.51258E+00 -0.2902 11 Fe++ 0.58699E-13 -13.2314 0.30121E-13 -13.5211 0.51315E+00 -0.2898 12 K+ 0.15714E-03 -3.8037 0.13143E-03 -3.8813 0.83640E+00 -0.0776 13 Na+ 0.19940E-01 -1.7003 0.16646E-01 -1.7787 0.83482E+00 -0.0784 14 Mn++ 0.18830E-10 -10.7251 0.96708E-11 -11.0145 0.51357E+00 -0.2894 15 F- 0.20082E-06 -6.6972 0.16734E-06 -6.7764 0.83325E+00 -0.0792 16 HPO4-- 0.45033E-07 -7.3465 0.23365E-07 -7.6314 0.51884E+00 -0.2850 18 HSiO3- 0.10452E-01 -1.9808 0.87272E-02 -2.0591 0.83497E+00 -0.0783 19 Ca(HSiO3)+ 0.16654E-07 -7.7785 0.13933E-07 -7.8560 0.83658E+00 -0.0775 20 Mg(HSiO3)+ 0.32277E-11 -11.4911 0.27002E-11 -11.5686 0.83658E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66388E-16 -16.1779 0.55538E-16 -16.2554 0.83658E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52977E-05 -5.2759 0.44154E-05 -5.3550 0.83346E+00 -0.0791 26 CH4,aq 0.24939E-04 -4.6031 0.24852E-04 -4.6046 0.99651E+00 -0.0015 27 C2H6,aq 0.91480E-14 -14.0387 0.91161E-14 -14.0402 0.99651E+00 -0.0015 31 CO,aq 0.18633E-16 -16.7297 0.18633E-16 -16.7297 0.10000E+01 0.0000 32 CO2,aq 0.64264E-10 -10.1920 0.64040E-10 -10.1936 0.99651E+00 -0.0015 33 CO3-2 0.91201E-06 -6.0400 0.47211E-06 -6.3260 0.51766E+00 -0.2860 34 CaCO3,aq 0.41498E-09 -9.3820 0.41498E-09 -9.3820 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.86088E-12 -12.0651 0.72020E-12 -12.1425 0.83658E+00 -0.0775 36 CaCl+ 0.31308E-10 -10.5043 0.26192E-10 -10.5818 0.83658E+00 -0.0775 37 CaCl2,aq 0.14367E-14 -14.8426 0.14367E-14 -14.8426 0.10000E+01 0.0000 38 CaF+ 0.20472E-12 -12.6888 0.17126E-12 -12.7663 0.83658E+00 -0.0775 39 CaOH+ 0.80199E-07 -7.0958 0.67093E-07 -7.1733 0.83658E+00 -0.0775 40 CaSO4,aq 0.15024E-16 -16.8232 0.15024E-16 -16.8232 0.10000E+01 0.0000 41 HCl,aq 0.31504E-14 -14.5016 0.31504E-14 -14.5016 0.10000E+01 0.0000 45 HF,aq 0.85301E-13 -13.0690 0.85301E-13 -13.0690 0.10000E+01 0.0000 48 FeCl+ 0.13158E-16 -16.8808 0.11007E-16 -16.9583 0.83658E+00 -0.0775 51 FeF+ 0.30788E-18 -18.5116 0.25757E-18 -18.5891 0.83658E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15739E-10 -10.8030 0.13167E-10 -10.8805 0.83658E+00 -0.0775 55 HFeO2- 0.35529E-07 -7.4494 0.29666E-07 -7.5277 0.83497E+00 -0.0783 56 FeO+ 0.11031E-16 -16.9574 0.92281E-17 -17.0349 0.83658E+00 -0.0775 58 FeO2- 0.40784E-09 -9.3895 0.34054E-09 -9.4678 0.83497E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99651E+00 -0.0015 61 KCl,aq 0.54996E-09 -9.2597 0.54996E-09 -9.2597 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.16486E-14 -14.7829 0.13765E-14 -14.8612 0.83497E+00 -0.0783 65 MgCO3,aq 0.16198E-13 -13.7905 0.16198E-13 -13.7905 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13699E-15 -15.8633 0.11460E-15 -15.9408 0.83658E+00 -0.0775 67 MgCl+ 0.44189E-14 -14.3547 0.36968E-14 -14.4322 0.83658E+00 -0.0775 68 MgF+ 0.11810E-15 -15.9278 0.98796E-16 -16.0053 0.83658E+00 -0.0775 69 MgOH+ 0.69109E-10 -10.1605 0.57815E-10 -10.2380 0.83658E+00 -0.0775 71 MnF+ 0.32582E-16 -16.4870 0.27258E-16 -16.5645 0.83658E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46943E-09 -9.3284 0.39272E-09 -9.4059 0.83658E+00 -0.0775 74 MnO2-2 0.20883E-10 -10.6802 0.10810E-10 -10.9662 0.51766E+00 -0.2860 75 HMnO2- 0.21121E-09 -9.6753 0.17636E-09 -9.7536 0.83497E+00 -0.0783 78 MnCl+ 0.16435E-13 -13.7842 0.13749E-13 -13.8617 0.83658E+00 -0.0775 80 NaCl,aq 0.12737E-05 -5.8949 0.12737E-05 -5.8949 0.10000E+01 0.0000 81 NaF,aq 0.65214E-09 -9.1857 0.65214E-09 -9.1857 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93095E-02 -2.0311 0.77591E-02 -2.1102 0.83346E+00 -0.0791 89 HPO3-2 0.16292E-14 -14.7880 0.84336E-15 -15.0740 0.51766E+00 -0.2860 91 H2PO3- 0.15082E-18 -18.8215 0.12593E-18 -18.8999 0.83497E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38402E-10 -10.4156 0.32095E-10 -10.4936 0.83577E+00 -0.0779 94 PO4-3 0.10574E-08 -8.9758 0.25601E-09 -9.5918 0.24211E+00 -0.6160 98 HP2O7-3 0.93879E-18 -18.0274 0.21659E-18 -18.6644 0.23071E+00 -0.6369 99 P2O7-4 0.90491E-17 -17.0434 0.69487E-18 -18.1581 0.76788E-01 -1.1147 100 H2S,aq 0.99084E-08 -8.0040 0.98738E-08 -8.0055 0.99651E+00 -0.0015 101 S2-2 0.68025E-14 -14.1673 0.35214E-14 -14.4533 0.51766E+00 -0.2860 107 SO3-2 0.19344E-17 -17.7135 0.10159E-17 -17.9932 0.52517E+00 -0.2797 109 HSO4- 0.57840E-19 -19.2378 0.48435E-19 -19.3148 0.83740E+00 -0.0771 Charge balance for all species = -.7375E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8864319E-10 -.2223323E-01 -.2237073E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981958E+06 0.0000 3 Cl- 0.2765102E-03 0.2777845E-03 0.9831139E+01 6.4914 4 SO4-- 0.1301046E-11 -.2784492E-04 -.2670169E+01 8.0854 5 HCO3- 0.4813224E-06 0.2633301E-04 0.1603968E+01 3.7328 6 HS- 0.5137567E-04 0.7923050E-04 0.2615747E+01 5.7605 7 Al+++ 0.9821442E-29 0.5297845E-05 0.1426948E+00 0.7390 8 H4SiO4 0.6959793E-03 0.1349774E-01 0.1295081E+04 -3.1574 9 Ca++ 0.1361319E-06 0.2334330E-06 0.9339233E-02 13.1018 10 Mg++ 0.2129716E-10 0.9365477E-10 0.2272969E-05 9.2942 11 Fe++ 0.5869858E-13 0.3616694E-07 0.2016297E-02 6.7350 12 K+ 0.1571361E-03 0.1578904E-03 0.6163077E+01 6.2467 13 Na+ 0.1993990E-01 0.2238686E-01 0.5137729E+03 8.3494 14 Mn++ 0.1883044E-10 0.2526564E-08 0.1385626E-03 9.2416 15 F- 0.2008243E-06 0.2014768E-06 0.3820989E-02 3.3516 16 HPO4-- 0.4503297E-07 0.4612877E-07 0.4419682E-02 12.6247 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279255E+02 -.1103513E-01 -.8278151E+02 0.0000000E+00 2 H2O -.7168789E+01 0.2754903E+02 -.3471782E+02 0.0000000E+00 3 Cl- 0.1378742E-03 0.1378742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385925E+00 -.1382041E-04 0.1386063E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385670E+00 0.3932488E-04 -.1386063E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629506E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6699401E-02 0.5205720E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1158610E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4648415E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1795092E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7836655E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111138E-01 0.6265266E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254022E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1000000E-06 0.1000000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2289533E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.8674E-14 Mass of aqueous solution: 0.497201E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5544 -0.256 281.7 2.450 5.158 73.20 grossular 0.1342 -0.872 60.47 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2627 -0.581 56.89 1.755 1.041 17.39 hedenbergite 0.6813E-01 -1.167 16.90 1.228 0.3094 4.629 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2614 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4248E-01 -1.372 36.31 1.560 0.6648 11.69 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337861 g Volume = 2210.777858 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000000 moles log =-100.0000 Original solution: 1000.0103000 g Original solution / Rock added: 0.00 (Water/Rock Ratio), log = 0.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0724 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9521E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.6347E-08 1.0067 0.6852E-08 0.6806E-08 CH4,gas 0.3370E-01 1.0122 0.3658E-01 0.3614E-01 H2,gas 0.1417E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2542E-06 0.9958 0.2714E-06 0.2726E-06 S2,gas 0.1115E-28 1.0000 0.1196E-28 0.1196E-28 CO,gas 0.2589E-13 1.0000 0.2777E-13 0.2777E-13 SO3,gas 0.1320E-47 1.0000 0.1415E-47 0.1415E-47 SO2,gas 0.7807E-27 1.0000 0.8371E-27 0.8371E-27 HF,gas 0.1953E-15 1.0000 0.2094E-15 0.2094E-15 HCl,gas 0.5184E-17 1.0000 0.5559E-17 0.5559E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.18198E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.18198E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.25781E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.52 -9.86 -3.288 0.16841E+05 -8.164 3 CH4,gas 4.54 1.41 -3.14 -0.784 0.53542E+04 -1.437 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.50 -8.27 -4.133 0.14113E+05 -6.566 6 S2,gas -7.34 -37.96 -30.62 -4.711 0.52285E+05 -28.922 7 CO,gas 3.21 -12.04 -15.26 -4.694 0.26048E+05 -13.556 8 SO3,gas 17.12 -32.43 -49.55 -12.387 0.84602E+05 -47.849 9 SO2,gas 0.83 -27.94 -28.78 -7.674 0.49135E+05 -27.077 10 HF,gas 0.47 -16.90 -17.38 -8.689 0.29672E+05 -15.679 11 HCl,gas 5.19 -13.76 -18.95 -9.477 0.32363E+05 -17.255 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -35.06 -0.76 -0.063 0.12925E+04 38 aragonite 0.97 -3.42 -4.39 -1.463 0.74924E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.42 -4.23 -1.411 0.72282E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.56 -4.46 -1.273 0.76073E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.56 -4.01 -1.146 0.68495E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.76 -3.50 -1.167 0.59766E+04 147 pyrrhotiteFe0.875 -6.02 -9.16 -3.14 -1.155 0.53638E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.76 -3.35 -1.117 0.57194E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.25 -4.28 -1.425 0.73014E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000000 MOLES New total amount of reactant added: 0.0000100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3660E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1143279E-01 Osmotic coef. = 0.9689 True ionic strength = .2009895E-01 Chg. balance for total moles = -.3660E-10 Max. difference allowed = 0.1379E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88645E-10 -10.0523 0.74465E-10 -10.1280 0.84004E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27663E-03 -3.5581 0.23098E-03 -3.6364 0.83497E+00 -0.0783 4 SO4-- 0.13134E-11 -11.8816 0.68135E-12 -12.1666 0.51876E+00 -0.2850 5 HCO3- 0.50794E-06 -6.2942 0.42474E-06 -6.3719 0.83620E+00 -0.0777 6 HS- 0.51865E-04 -4.2851 0.43312E-04 -4.3634 0.83510E+00 -0.0783 7 Al+++ 0.98221E-29 -29.0078 0.22638E-29 -29.6452 0.23048E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13614E-06 -6.8660 0.70103E-07 -7.1543 0.51494E+00 -0.2882 10 Mg++ 0.21298E-10 -10.6717 0.10917E-10 -10.9619 0.51258E+00 -0.2902 11 Fe++ 0.58701E-13 -13.2314 0.30122E-13 -13.5211 0.51314E+00 -0.2898 12 K+ 0.15714E-03 -3.8037 0.13143E-03 -3.8813 0.83640E+00 -0.0776 13 Na+ 0.19940E-01 -1.7003 0.16647E-01 -1.7787 0.83482E+00 -0.0784 14 Mn++ 0.18831E-10 -10.7251 0.96712E-11 -11.0145 0.51357E+00 -0.2894 15 F- 0.20886E-06 -6.6802 0.17403E-06 -6.7594 0.83325E+00 -0.0792 16 HPO4-- 0.45032E-07 -7.3465 0.23364E-07 -7.6315 0.51884E+00 -0.2850 18 HSiO3- 0.10452E-01 -1.9808 0.87271E-02 -2.0591 0.83497E+00 -0.0783 19 Ca(HSiO3)+ 0.16655E-07 -7.7785 0.13933E-07 -7.8560 0.83658E+00 -0.0775 20 Mg(HSiO3)+ 0.32277E-11 -11.4911 0.27003E-11 -11.5686 0.83658E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66389E-16 -16.1779 0.55539E-16 -16.2554 0.83658E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52976E-05 -5.2759 0.44153E-05 -5.3550 0.83346E+00 -0.0791 26 CH4,aq 0.26319E-04 -4.5797 0.26227E-04 -4.5813 0.99651E+00 -0.0015 27 C2H6,aq 0.10188E-13 -13.9919 0.10153E-13 -13.9934 0.99651E+00 -0.0015 31 CO,aq 0.19664E-16 -16.7063 0.19664E-16 -16.7063 0.10000E+01 0.0000 32 CO2,aq 0.67819E-10 -10.1687 0.67582E-10 -10.1702 0.99651E+00 -0.0015 33 CO3-2 0.96243E-06 -6.0166 0.49821E-06 -6.3026 0.51766E+00 -0.2860 34 CaCO3,aq 0.43793E-09 -9.3586 0.43793E-09 -9.3586 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.90852E-12 -12.0417 0.76005E-12 -12.1192 0.83658E+00 -0.0775 36 CaCl+ 0.31323E-10 -10.5041 0.26204E-10 -10.5816 0.83658E+00 -0.0775 37 CaCl2,aq 0.14380E-14 -14.8423 0.14380E-14 -14.8423 0.10000E+01 0.0000 38 CaF+ 0.21292E-12 -12.6718 0.17812E-12 -12.7493 0.83658E+00 -0.0775 39 CaOH+ 0.80201E-07 -7.0958 0.67094E-07 -7.1733 0.83658E+00 -0.0775 40 CaSO4,aq 0.15168E-16 -16.8191 0.15168E-16 -16.8191 0.10000E+01 0.0000 41 HCl,aq 0.31518E-14 -14.5014 0.31518E-14 -14.5014 0.10000E+01 0.0000 45 HF,aq 0.88715E-13 -13.0520 0.88715E-13 -13.0520 0.10000E+01 0.0000 48 FeCl+ 0.13164E-16 -16.8806 0.11013E-16 -16.9581 0.83658E+00 -0.0775 51 FeF+ 0.32021E-18 -18.4946 0.26788E-18 -18.5721 0.83658E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15739E-10 -10.8030 0.13167E-10 -10.8805 0.83658E+00 -0.0775 55 HFeO2- 0.35528E-07 -7.4494 0.29665E-07 -7.5278 0.83497E+00 -0.0783 56 FeO+ 0.11031E-16 -16.9574 0.92282E-17 -17.0349 0.83658E+00 -0.0775 58 FeO2- 0.40784E-09 -9.3895 0.34053E-09 -9.4678 0.83497E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99651E+00 -0.0015 61 KCl,aq 0.55021E-09 -9.2595 0.55021E-09 -9.2595 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.16643E-14 -14.7788 0.13896E-14 -14.8571 0.83497E+00 -0.0783 65 MgCO3,aq 0.17094E-13 -13.7671 0.17094E-13 -13.7671 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14457E-15 -15.8399 0.12094E-15 -15.9174 0.83658E+00 -0.0775 67 MgCl+ 0.44210E-14 -14.3545 0.36985E-14 -14.4320 0.83658E+00 -0.0775 68 MgF+ 0.12282E-15 -15.9107 0.10275E-15 -15.9882 0.83658E+00 -0.0775 69 MgOH+ 0.69111E-10 -10.1605 0.57816E-10 -10.2379 0.83658E+00 -0.0775 71 MnF+ 0.33887E-16 -16.4700 0.28349E-16 -16.5475 0.83658E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46944E-09 -9.3284 0.39273E-09 -9.4059 0.83658E+00 -0.0775 74 MnO2-2 0.20882E-10 -10.6802 0.10810E-10 -10.9662 0.51766E+00 -0.2860 75 HMnO2- 0.21121E-09 -9.6753 0.17636E-09 -9.7536 0.83497E+00 -0.0783 78 MnCl+ 0.16443E-13 -13.7840 0.13756E-13 -13.8615 0.83658E+00 -0.0775 80 NaCl,aq 0.12742E-05 -5.8948 0.12742E-05 -5.8948 0.10000E+01 0.0000 81 NaF,aq 0.67824E-09 -9.1686 0.67824E-09 -9.1686 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93093E-02 -2.0311 0.77590E-02 -2.1102 0.83346E+00 -0.0791 89 HPO3-2 0.16291E-14 -14.7880 0.84333E-15 -15.0740 0.51766E+00 -0.2860 91 H2PO3- 0.15082E-18 -18.8215 0.12593E-18 -18.8999 0.83497E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38402E-10 -10.4157 0.32095E-10 -10.4936 0.83577E+00 -0.0779 94 PO4-3 0.10574E-08 -8.9758 0.25599E-09 -9.5918 0.24211E+00 -0.6160 98 HP2O7-3 0.93875E-18 -18.0275 0.21658E-18 -18.6644 0.23071E+00 -0.6369 99 P2O7-4 0.90487E-17 -17.0434 0.69481E-18 -18.1581 0.76786E-01 -1.1147 100 H2S,aq 0.10003E-07 -7.9999 0.99681E-08 -8.0014 0.99651E+00 -0.0015 101 S2-2 0.69328E-14 -14.1591 0.35888E-14 -14.4450 0.51766E+00 -0.2860 107 SO3-2 0.19528E-17 -17.7093 0.10255E-17 -17.9890 0.52517E+00 -0.2797 109 HSO4- 0.58391E-19 -19.2337 0.48896E-19 -19.3107 0.83739E+00 -0.0771 Charge balance for all species = -.7372E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8864497E-10 -.2223294E-01 -.2237044E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981958E+06 0.0000 3 Cl- 0.2766284E-03 0.2779032E-03 0.9835342E+01 6.4916 4 SO4-- 0.1313423E-11 -.2922452E-04 -.2802464E+01 8.0895 5 HCO3- 0.5079399E-06 0.2778968E-04 0.1692695E+01 3.7562 6 HS- 0.5186515E-04 0.8109968E-04 0.2677457E+01 5.7647 7 Al+++ 0.9822126E-29 0.5297754E-05 0.1426924E+00 0.7390 8 H4SiO4 0.6959793E-03 0.1349756E-01 0.1295064E+04 -3.1574 9 Ca++ 0.1361378E-06 0.2334639E-06 0.9340468E-02 13.1018 10 Mg++ 0.2129809E-10 0.9365831E-10 0.2273055E-05 9.2942 11 Fe++ 0.5870114E-13 0.3616633E-07 0.2016263E-02 6.7350 12 K+ 0.1571393E-03 0.1578936E-03 0.6163200E+01 6.2467 13 Na+ 0.1994030E-01 0.2238726E-01 0.5137821E+03 8.3494 14 Mn++ 0.1883128E-10 0.2526572E-08 0.1385631E-03 9.2416 15 F- 0.2088572E-06 0.2095358E-06 0.3973827E-02 3.3687 16 HPO4-- 0.4503156E-07 0.4612731E-07 0.4419542E-02 12.6246 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279255E+02 -.1103499E-01 -.8278151E+02 0.0000000E+00 2 H2O -.7168781E+01 0.2754904E+02 -.3471782E+02 0.0000000E+00 3 Cl- 0.1379332E-03 0.1379332E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385926E+00 -.1450516E-04 0.1386071E+00 0.0000000E+00 5 HCO3- 0.1379300E-04 0.1379300E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385668E+00 0.4025263E-04 -.1386071E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629463E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6699315E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1158764E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4648593E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1795063E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7836815E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111159E-01 0.6265265E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254027E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1040000E-06 0.1040000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2289461E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.5704E-14 Mass of aqueous solution: 0.497201E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5544 -0.256 281.7 2.450 5.158 73.20 grossular 0.1342 -0.872 60.47 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2627 -0.581 56.88 1.755 1.041 17.39 hedenbergite 0.6812E-01 -1.167 16.90 1.228 0.3094 4.629 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2614 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4249E-01 -1.372 36.32 1.560 0.6649 11.69 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337864 g Volume = 2210.777886 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000100 moles log = -5.0000 Original solution: 1000.0103000 g Original solution / Rock added: 100001030.00 (Water/Rock Ratio), log = 8.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0744 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9504E+00 0.9852 0.1006E+01 0.1021E+01 CO2,gas 0.6685E-08 1.0067 0.7231E-08 0.7183E-08 CH4,gas 0.3550E-01 1.0122 0.3860E-01 0.3814E-01 H2,gas 0.1415E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2561E-06 0.9958 0.2740E-06 0.2752E-06 S2,gas 0.1134E-28 1.0000 0.1219E-28 0.1219E-28 CO,gas 0.2727E-13 1.0000 0.2930E-13 0.2930E-13 SO3,gas 0.1330E-47 1.0000 0.1429E-47 0.1429E-47 SO2,gas 0.7866E-27 1.0000 0.8451E-27 0.8451E-27 HF,gas 0.2027E-15 1.0000 0.2178E-15 0.2178E-15 HCl,gas 0.5176E-17 1.0000 0.5561E-17 0.5561E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.50 -9.84 -3.280 0.16801E+05 -8.141 3 CH4,gas 4.54 1.43 -3.11 -0.778 0.53142E+04 -1.413 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.49 -8.26 -4.131 0.14106E+05 -6.562 6 S2,gas -7.34 -37.95 -30.61 -4.710 0.52271E+05 -28.914 7 CO,gas 3.21 -12.02 -15.23 -4.687 0.26008E+05 -13.533 8 SO3,gas 17.12 -32.42 -49.54 -12.386 0.84595E+05 -47.845 9 SO2,gas 0.83 -27.94 -28.77 -7.673 0.49127E+05 -27.073 10 HF,gas 0.47 -16.89 -17.36 -8.680 0.29643E+05 -15.662 11 HCl,gas 5.19 -13.76 -18.95 -9.477 0.32363E+05 -17.255 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -35.04 -0.74 -0.062 0.12634E+04 38 aragonite 0.97 -3.40 -4.36 -1.455 0.74525E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.40 -4.21 -1.403 0.71882E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.53 -4.43 -1.266 0.75673E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.53 -3.99 -1.139 0.68096E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.76 -3.50 -1.165 0.59696E+04 147 pyrrhotiteFe0.875 -6.02 -9.15 -3.14 -1.154 0.53568E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.76 -3.35 -1.115 0.57124E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.25 -4.27 -1.424 0.72943E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000100 MOLES New total amount of reactant added: 0.0000200 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3660E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000200 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1143196E-01 Osmotic coef. = 0.9694 True ionic strength = .2009941E-01 Chg. balance for total moles = -.3660E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88647E-10 -10.0523 0.74467E-10 -10.1280 0.84004E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27675E-03 -3.5579 0.23108E-03 -3.6362 0.83497E+00 -0.0783 4 SO4-- 0.13258E-11 -11.8775 0.68777E-12 -12.1626 0.51876E+00 -0.2850 5 HCO3- 0.53456E-06 -6.2720 0.44699E-06 -6.3497 0.83620E+00 -0.0777 6 HS- 0.52355E-04 -4.2810 0.43721E-04 -4.3593 0.83509E+00 -0.0783 7 Al+++ 0.98228E-29 -29.0078 0.22639E-29 -29.6451 0.23047E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13614E-06 -6.8660 0.70106E-07 -7.1542 0.51494E+00 -0.2882 10 Mg++ 0.21299E-10 -10.6716 0.10917E-10 -10.9619 0.51258E+00 -0.2902 11 Fe++ 0.58704E-13 -13.2313 0.30123E-13 -13.5211 0.51314E+00 -0.2898 12 K+ 0.15714E-03 -3.8037 0.13143E-03 -3.8813 0.83640E+00 -0.0776 13 Na+ 0.19941E-01 -1.7003 0.16647E-01 -1.7787 0.83482E+00 -0.0784 14 Mn++ 0.18832E-10 -10.7251 0.96715E-11 -11.0145 0.51357E+00 -0.2894 15 F- 0.21689E-06 -6.6638 0.18072E-06 -6.7430 0.83325E+00 -0.0792 16 HPO4-- 0.45030E-07 -7.3465 0.23363E-07 -7.6315 0.51883E+00 -0.2850 18 HSiO3- 0.10452E-01 -1.9808 0.87269E-02 -2.0591 0.83497E+00 -0.0783 19 Ca(HSiO3)+ 0.16655E-07 -7.7785 0.13933E-07 -7.8560 0.83658E+00 -0.0775 20 Mg(HSiO3)+ 0.32278E-11 -11.4911 0.27003E-11 -11.5686 0.83658E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66390E-16 -16.1779 0.55540E-16 -16.2554 0.83658E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52975E-05 -5.2759 0.44153E-05 -5.3550 0.83346E+00 -0.0791 26 CH4,aq 0.27698E-04 -4.5575 0.27602E-04 -4.5591 0.99651E+00 -0.0015 27 C2H6,aq 0.11284E-13 -13.9475 0.11245E-13 -13.9490 0.99651E+00 -0.0015 31 CO,aq 0.20695E-16 -16.6841 0.20695E-16 -16.6841 0.10000E+01 0.0000 32 CO2,aq 0.71374E-10 -10.1465 0.71125E-10 -10.1480 0.99651E+00 -0.0015 33 CO3-2 0.10128E-05 -5.9945 0.52430E-06 -6.2804 0.51765E+00 -0.2860 34 CaCO3,aq 0.46089E-09 -9.3364 0.46089E-09 -9.3364 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.95617E-12 -12.0195 0.79991E-12 -12.0970 0.83658E+00 -0.0775 36 CaCl+ 0.31338E-10 -10.5039 0.26216E-10 -10.5814 0.83658E+00 -0.0775 37 CaCl2,aq 0.14392E-14 -14.8419 0.14392E-14 -14.8419 0.10000E+01 0.0000 38 CaF+ 0.22111E-12 -12.6554 0.18498E-12 -12.7329 0.83658E+00 -0.0775 39 CaOH+ 0.80203E-07 -7.0958 0.67096E-07 -7.1733 0.83658E+00 -0.0775 40 CaSO4,aq 0.15311E-16 -16.8150 0.15311E-16 -16.8150 0.10000E+01 0.0000 41 HCl,aq 0.31532E-14 -14.5012 0.31532E-14 -14.5012 0.10000E+01 0.0000 45 HF,aq 0.92128E-13 -13.0356 0.92128E-13 -13.0356 0.10000E+01 0.0000 48 FeCl+ 0.13170E-16 -16.8804 0.11018E-16 -16.9579 0.83658E+00 -0.0775 51 FeF+ 0.33254E-18 -18.4782 0.27819E-18 -18.5557 0.83658E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15740E-10 -10.8030 0.13167E-10 -10.8805 0.83658E+00 -0.0775 55 HFeO2- 0.35528E-07 -7.4494 0.29665E-07 -7.5278 0.83497E+00 -0.0783 56 FeO+ 0.11031E-16 -16.9574 0.92284E-17 -17.0349 0.83658E+00 -0.0775 58 FeO2- 0.40783E-09 -9.3895 0.34053E-09 -9.4678 0.83497E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99651E+00 -0.0015 61 KCl,aq 0.55045E-09 -9.2593 0.55045E-09 -9.2593 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.16800E-14 -14.7747 0.14027E-14 -14.8530 0.83497E+00 -0.0783 65 MgCO3,aq 0.17990E-13 -13.7450 0.17990E-13 -13.7450 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15215E-15 -15.8177 0.12728E-15 -15.8952 0.83658E+00 -0.0775 67 MgCl+ 0.44231E-14 -14.3543 0.37002E-14 -14.4318 0.83658E+00 -0.0775 68 MgF+ 0.12755E-15 -15.8943 0.10671E-15 -15.9718 0.83658E+00 -0.0775 69 MgOH+ 0.69112E-10 -10.1604 0.57817E-10 -10.2379 0.83658E+00 -0.0775 71 MnF+ 0.35192E-16 -16.4536 0.29440E-16 -16.5311 0.83658E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46945E-09 -9.3284 0.39273E-09 -9.4059 0.83658E+00 -0.0775 74 MnO2-2 0.20882E-10 -10.6802 0.10810E-10 -10.9662 0.51765E+00 -0.2860 75 HMnO2- 0.21121E-09 -9.6753 0.17635E-09 -9.7536 0.83497E+00 -0.0783 78 MnCl+ 0.16450E-13 -13.7838 0.13762E-13 -13.8613 0.83658E+00 -0.0775 80 NaCl,aq 0.12748E-05 -5.8946 0.12748E-05 -5.8946 0.10000E+01 0.0000 81 NaF,aq 0.70434E-09 -9.1522 0.70434E-09 -9.1522 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93092E-02 -2.0311 0.77588E-02 -2.1102 0.83346E+00 -0.0791 89 HPO3-2 0.16291E-14 -14.7881 0.84330E-15 -15.0740 0.51765E+00 -0.2860 91 H2PO3- 0.15082E-18 -18.8216 0.12593E-18 -18.8999 0.83497E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38401E-10 -10.4157 0.32094E-10 -10.4936 0.83577E+00 -0.0779 94 PO4-3 0.10573E-08 -8.9758 0.25598E-09 -9.5918 0.24210E+00 -0.6160 98 HP2O7-3 0.93871E-18 -18.0275 0.21657E-18 -18.6644 0.23071E+00 -0.6369 99 P2O7-4 0.90482E-17 -17.0434 0.69476E-18 -18.1582 0.76784E-01 -1.1147 100 H2S,aq 0.10098E-07 -7.9958 0.10062E-07 -7.9973 0.99651E+00 -0.0015 101 S2-2 0.70643E-14 -14.1509 0.36569E-14 -14.4369 0.51765E+00 -0.2860 107 SO3-2 0.19712E-17 -17.7053 0.10352E-17 -17.9850 0.52517E+00 -0.2797 109 HSO4- 0.58942E-19 -19.2296 0.49358E-19 -19.3066 0.83739E+00 -0.0771 Charge balance for all species = -.7370E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8864676E-10 -.2223266E-01 -.2237015E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981958E+06 0.0000 3 Cl- 0.2767466E-03 0.2780220E-03 0.9839545E+01 6.4918 4 SO4-- 0.1325799E-11 -.3060413E-04 -.2934760E+01 8.0935 5 HCO3- 0.5345565E-06 0.2924635E-04 0.1781422E+01 3.7783 6 HS- 0.5235462E-04 0.8296885E-04 0.2739166E+01 5.7687 7 Al+++ 0.9822810E-29 0.5297664E-05 0.1426899E+00 0.7390 8 H4SiO4 0.6959792E-03 0.1349738E-01 0.1295046E+04 -3.1574 9 Ca++ 0.1361437E-06 0.2334948E-06 0.9341704E-02 13.1018 10 Mg++ 0.2129901E-10 0.9366186E-10 0.2273141E-05 9.2942 11 Fe++ 0.5870369E-13 0.3616571E-07 0.2016228E-02 6.7350 12 K+ 0.1571424E-03 0.1578967E-03 0.6163323E+01 6.2467 13 Na+ 0.1994070E-01 0.2238766E-01 0.5137913E+03 8.3494 14 Mn++ 0.1883212E-10 0.2526581E-08 0.1385635E-03 9.2416 15 F- 0.2168901E-06 0.2175948E-06 0.4126665E-02 3.3851 16 HPO4-- 0.4503014E-07 0.4612585E-07 0.4419402E-02 12.6246 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279255E+02 -.1103486E-01 -.8278151E+02 0.0000000E+00 2 H2O -.7168772E+01 0.2754905E+02 -.3471783E+02 0.0000000E+00 3 Cl- 0.1379922E-03 0.1379922E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385926E+00 -.1518991E-04 0.1386078E+00 0.0000000E+00 5 HCO3- 0.1451600E-04 0.1451600E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385666E+00 0.4118038E-04 -.1386078E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629419E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6699228E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1158917E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4648770E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1795033E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7836975E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111179E-01 0.6265265E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254032E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1080000E-06 0.1080000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2289390E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.5149E-14 Mass of aqueous solution: 0.497202E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000200 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5544 -0.256 281.8 2.450 5.158 73.20 grossular 0.1342 -0.872 60.47 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2627 -0.581 56.88 1.755 1.041 17.38 hedenbergite 0.6812E-01 -1.167 16.90 1.228 0.3094 4.629 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2614 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4249E-01 -1.372 36.32 1.560 0.6650 11.69 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337868 g Volume = 2210.777913 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000200 moles log = -4.6990 Original solution: 1000.0103000 g Original solution / Rock added: 50000515.00 (Water/Rock Ratio), log = 7.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0764 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9486E+00 0.9852 0.1006E+01 0.1021E+01 CO2,gas 0.7023E-08 1.0066 0.7610E-08 0.7559E-08 CH4,gas 0.3729E-01 1.0122 0.4063E-01 0.4014E-01 H2,gas 0.1412E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2581E-06 0.9958 0.2766E-06 0.2778E-06 S2,gas 0.1154E-28 1.0000 0.1242E-28 0.1242E-28 CO,gas 0.2865E-13 1.0000 0.3084E-13 0.3084E-13 SO3,gas 0.1340E-47 1.0000 0.1442E-47 0.1442E-47 SO2,gas 0.7926E-27 1.0000 0.8531E-27 0.8531E-27 HF,gas 0.2102E-15 1.0000 0.2262E-15 0.2262E-15 HCl,gas 0.5169E-17 1.0000 0.5564E-17 0.5564E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.48 -9.82 -3.273 0.16763E+05 -8.119 3 CH4,gas 4.54 1.45 -3.09 -0.773 0.52763E+04 -1.391 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.49 -8.26 -4.129 0.14099E+05 -6.558 6 S2,gas -7.34 -37.94 -30.60 -4.708 0.52257E+05 -28.906 7 CO,gas 3.21 -11.99 -15.21 -4.680 0.25970E+05 -13.511 8 SO3,gas 17.12 -32.42 -49.54 -12.385 0.84588E+05 -47.841 9 SO2,gas 0.83 -27.94 -28.77 -7.671 0.49121E+05 -27.069 10 HF,gas 0.47 -16.87 -17.34 -8.672 0.29615E+05 -15.645 11 HCl,gas 5.19 -13.76 -18.95 -9.477 0.32363E+05 -17.255 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -35.02 -0.72 -0.060 0.12354E+04 38 aragonite 0.97 -3.38 -4.34 -1.447 0.74146E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.38 -4.19 -1.396 0.71504E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.51 -4.41 -1.260 0.75294E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.51 -3.97 -1.133 0.67717E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.75 -3.49 -1.164 0.59626E+04 147 pyrrhotiteFe0.875 -6.02 -9.15 -3.13 -1.152 0.53498E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.75 -3.34 -1.114 0.57054E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.25 -4.27 -1.423 0.72873E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000200 MOLES New total amount of reactant added: 0.0000300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1143113E-01 Osmotic coef. = 0.9698 True ionic strength = .2009986E-01 Chg. balance for total moles = -.3663E-10 Max. difference allowed = 0.1381E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88649E-10 -10.0523 0.74468E-10 -10.1280 0.84004E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27686E-03 -3.5577 0.23117E-03 -3.6361 0.83497E+00 -0.0783 4 SO4-- 0.13382E-11 -11.8735 0.69419E-12 -12.1585 0.51876E+00 -0.2850 5 HCO3- 0.56117E-06 -6.2509 0.46925E-06 -6.3286 0.83620E+00 -0.0777 6 HS- 0.52844E-04 -4.2770 0.44130E-04 -4.3553 0.83509E+00 -0.0783 7 Al+++ 0.98235E-29 -29.0077 0.22640E-29 -29.6451 0.23047E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13615E-06 -6.8660 0.70108E-07 -7.1542 0.51494E+00 -0.2882 10 Mg++ 0.21300E-10 -10.6716 0.10918E-10 -10.9619 0.51257E+00 -0.2902 11 Fe++ 0.58706E-13 -13.2313 0.30124E-13 -13.5211 0.51314E+00 -0.2898 12 K+ 0.15715E-03 -3.8037 0.13144E-03 -3.8813 0.83639E+00 -0.0776 13 Na+ 0.19941E-01 -1.7003 0.16647E-01 -1.7787 0.83482E+00 -0.0784 14 Mn++ 0.18833E-10 -10.7251 0.96719E-11 -11.0145 0.51356E+00 -0.2894 15 F- 0.22492E-06 -6.6480 0.18742E-06 -6.7272 0.83324E+00 -0.0792 16 HPO4-- 0.45029E-07 -7.3465 0.23362E-07 -7.6315 0.51883E+00 -0.2850 18 HSiO3- 0.10452E-01 -1.9808 0.87268E-02 -2.0591 0.83497E+00 -0.0783 19 Ca(HSiO3)+ 0.16655E-07 -7.7784 0.13933E-07 -7.8559 0.83658E+00 -0.0775 20 Mg(HSiO3)+ 0.32279E-11 -11.4911 0.27004E-11 -11.5686 0.83658E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66392E-16 -16.1779 0.55542E-16 -16.2554 0.83658E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52974E-05 -5.2759 0.44152E-05 -5.3551 0.83346E+00 -0.0791 26 CH4,aq 0.29078E-04 -4.5364 0.28977E-04 -4.5380 0.99651E+00 -0.0015 27 C2H6,aq 0.12436E-13 -13.9053 0.12393E-13 -13.9068 0.99651E+00 -0.0015 31 CO,aq 0.21725E-16 -16.6630 0.21725E-16 -16.6630 0.10000E+01 0.0000 32 CO2,aq 0.74929E-10 -10.1254 0.74667E-10 -10.1269 0.99651E+00 -0.0015 33 CO3-2 0.10633E-05 -5.9734 0.55040E-06 -6.2593 0.51765E+00 -0.2860 34 CaCO3,aq 0.48384E-09 -9.3153 0.48384E-09 -9.3153 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10038E-11 -11.9983 0.83976E-12 -12.0758 0.83658E+00 -0.0775 36 CaCl+ 0.31352E-10 -10.5037 0.26228E-10 -10.5812 0.83658E+00 -0.0775 37 CaCl2,aq 0.14405E-14 -14.8415 0.14405E-14 -14.8415 0.10000E+01 0.0000 38 CaF+ 0.22931E-12 -12.6396 0.19184E-12 -12.7171 0.83658E+00 -0.0775 39 CaOH+ 0.80204E-07 -7.0958 0.67097E-07 -7.1733 0.83658E+00 -0.0775 40 CaSO4,aq 0.15454E-16 -16.8109 0.15454E-16 -16.8109 0.10000E+01 0.0000 41 HCl,aq 0.31546E-14 -14.5011 0.31546E-14 -14.5011 0.10000E+01 0.0000 45 HF,aq 0.95542E-13 -13.0198 0.95542E-13 -13.0198 0.10000E+01 0.0000 48 FeCl+ 0.13176E-16 -16.8802 0.11023E-16 -16.9577 0.83658E+00 -0.0775 51 FeF+ 0.34487E-18 -18.4623 0.28851E-18 -18.5398 0.83658E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15740E-10 -10.8030 0.13168E-10 -10.8805 0.83658E+00 -0.0775 55 HFeO2- 0.35527E-07 -7.4494 0.29664E-07 -7.5278 0.83497E+00 -0.0783 56 FeO+ 0.11031E-16 -16.9574 0.92286E-17 -17.0349 0.83658E+00 -0.0775 58 FeO2- 0.40782E-09 -9.3895 0.34052E-09 -9.4679 0.83497E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99651E+00 -0.0015 61 KCl,aq 0.55070E-09 -9.2591 0.55070E-09 -9.2591 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.16957E-14 -14.7707 0.14158E-14 -14.8490 0.83497E+00 -0.0783 65 MgCO3,aq 0.18886E-13 -13.7239 0.18886E-13 -13.7239 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15973E-15 -15.7966 0.13363E-15 -15.8741 0.83658E+00 -0.0775 67 MgCl+ 0.44251E-14 -14.3541 0.37019E-14 -14.4316 0.83658E+00 -0.0775 68 MgF+ 0.13228E-15 -15.8785 0.11066E-15 -15.9560 0.83658E+00 -0.0775 69 MgOH+ 0.69113E-10 -10.1604 0.57819E-10 -10.2379 0.83658E+00 -0.0775 71 MnF+ 0.36496E-16 -16.4378 0.30532E-16 -16.5152 0.83658E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46946E-09 -9.3284 0.39274E-09 -9.4059 0.83658E+00 -0.0775 74 MnO2-2 0.20881E-10 -10.6802 0.10809E-10 -10.9662 0.51765E+00 -0.2860 75 HMnO2- 0.21120E-09 -9.6753 0.17635E-09 -9.7536 0.83497E+00 -0.0783 78 MnCl+ 0.16458E-13 -13.7836 0.13768E-13 -13.8611 0.83658E+00 -0.0775 80 NaCl,aq 0.12754E-05 -5.8944 0.12754E-05 -5.8944 0.10000E+01 0.0000 81 NaF,aq 0.73044E-09 -9.1364 0.73044E-09 -9.1364 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93090E-02 -2.0311 0.77587E-02 -2.1102 0.83346E+00 -0.0791 89 HPO3-2 0.16290E-14 -14.7881 0.84326E-15 -15.0740 0.51765E+00 -0.2860 91 H2PO3- 0.15081E-18 -18.8216 0.12593E-18 -18.8999 0.83497E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38400E-10 -10.4157 0.32094E-10 -10.4936 0.83576E+00 -0.0779 94 PO4-3 0.10573E-08 -8.9758 0.25596E-09 -9.5918 0.24210E+00 -0.6160 98 HP2O7-3 0.93867E-18 -18.0275 0.21655E-18 -18.6644 0.23070E+00 -0.6369 99 P2O7-4 0.90478E-17 -17.0435 0.69471E-18 -18.1582 0.76783E-01 -1.1147 100 H2S,aq 0.10192E-07 -7.9917 0.10157E-07 -7.9933 0.99651E+00 -0.0015 101 S2-2 0.71970E-14 -14.1428 0.37255E-14 -14.4288 0.51765E+00 -0.2860 107 SO3-2 0.19896E-17 -17.7012 0.10449E-17 -17.9809 0.52516E+00 -0.2797 109 HSO4- 0.59493E-19 -19.2255 0.49819E-19 -19.3026 0.83739E+00 -0.0771 Charge balance for all species = -.7371E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8864854E-10 -.2223237E-01 -.2236986E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981958E+06 0.0000 3 Cl- 0.2768648E-03 0.2781408E-03 0.9843748E+01 6.4920 4 SO4-- 0.1338175E-11 -.3198373E-04 -.3067057E+01 8.0975 5 HCO3- 0.5611723E-06 0.3070301E-04 0.1870149E+01 3.7994 6 HS- 0.5284410E-04 0.8483802E-04 0.2800876E+01 5.7728 7 Al+++ 0.9823494E-29 0.5297573E-05 0.1426875E+00 0.7390 8 H4SiO4 0.6959792E-03 0.1349720E-01 0.1295029E+04 -3.1574 9 Ca++ 0.1361496E-06 0.2335257E-06 0.9342939E-02 13.1018 10 Mg++ 0.2129994E-10 0.9366361E-10 0.2273183E-05 9.2942 11 Fe++ 0.5870624E-13 0.3616510E-07 0.2016194E-02 6.7350 12 K+ 0.1571456E-03 0.1578999E-03 0.6163446E+01 6.2467 13 Na+ 0.1994110E-01 0.2238806E-01 0.5138005E+03 8.3494 14 Mn++ 0.1883295E-10 0.2526589E-08 0.1385640E-03 9.2416 15 F- 0.2249230E-06 0.2256537E-06 0.4279502E-02 3.4008 16 HPO4-- 0.4502873E-07 0.4612439E-07 0.4419262E-02 12.6246 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279254E+02 -.1103472E-01 -.8278151E+02 0.0000000E+00 2 H2O -.7168764E+01 0.2754906E+02 -.3471783E+02 0.0000000E+00 3 Cl- 0.1380512E-03 0.1380512E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385927E+00 -.1587467E-04 0.1386085E+00 0.0000000E+00 5 HCO3- 0.1523900E-04 0.1523900E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385664E+00 0.4210814E-04 -.1386085E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629375E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6699142E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1159071E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4648859E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1795003E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7837134E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111199E-01 0.6265265E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254036E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1120000E-06 0.1120000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2289318E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1243E-13 Mass of aqueous solution: 0.497202E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5544 -0.256 281.8 2.450 5.158 73.20 grossular 0.1343 -0.872 60.47 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2626 -0.581 56.88 1.755 1.041 17.38 hedenbergite 0.6811E-01 -1.167 16.90 1.228 0.3094 4.628 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2614 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4250E-01 -1.372 36.33 1.560 0.6651 11.69 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337871 g Volume = 2210.777941 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000300 moles log = -4.5229 Original solution: 1000.0103000 g Original solution / Rock added: 33333676.67 (Water/Rock Ratio), log = 7.5229 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0784 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9468E+00 0.9852 0.1006E+01 0.1021E+01 CO2,gas 0.7359E-08 1.0066 0.7989E-08 0.7936E-08 CH4,gas 0.3907E-01 1.0122 0.4265E-01 0.4214E-01 H2,gas 0.1409E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2600E-06 0.9958 0.2792E-06 0.2804E-06 S2,gas 0.1173E-28 1.0000 0.1265E-28 0.1265E-28 CO,gas 0.3002E-13 1.0000 0.3238E-13 0.3238E-13 SO3,gas 0.1350E-47 1.0000 0.1456E-47 0.1456E-47 SO2,gas 0.7985E-27 1.0000 0.8611E-27 0.8611E-27 HF,gas 0.2175E-15 1.0000 0.2346E-15 0.2346E-15 HCl,gas 0.5162E-17 1.0000 0.5566E-17 0.5566E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.46 -9.80 -3.265 0.16727E+05 -8.098 3 CH4,gas 4.54 1.47 -3.07 -0.767 0.52403E+04 -1.370 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.48 -8.25 -4.127 0.14092E+05 -6.554 6 S2,gas -7.34 -37.93 -30.60 -4.707 0.52243E+05 -28.898 7 CO,gas 3.21 -11.97 -15.19 -4.673 0.25934E+05 -13.490 8 SO3,gas 17.12 -32.41 -49.54 -12.384 0.84581E+05 -47.837 9 SO2,gas 0.83 -27.93 -28.76 -7.670 0.49114E+05 -27.065 10 HF,gas 0.47 -16.86 -17.33 -8.664 0.29588E+05 -15.630 11 HCl,gas 5.19 -13.76 -18.95 -9.477 0.32362E+05 -17.254 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -35.01 -0.71 -0.059 0.12084E+04 38 aragonite 0.97 -3.35 -4.32 -1.440 0.73785E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.35 -4.17 -1.389 0.71143E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.49 -4.39 -1.254 0.74934E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.49 -3.94 -1.127 0.67357E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.75 -3.49 -1.163 0.59557E+04 147 pyrrhotiteFe0.875 -6.02 -9.15 -3.13 -1.151 0.53429E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.75 -3.34 -1.112 0.56985E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.24 -4.26 -1.421 0.72804E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000300 MOLES New total amount of reactant added: 0.0000400 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000400 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1143030E-01 Osmotic coef. = 0.9702 True ionic strength = .2010032E-01 Chg. balance for total moles = -.3663E-10 Max. difference allowed = 0.1381E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88650E-10 -10.0523 0.74470E-10 -10.1280 0.84004E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27698E-03 -3.5575 0.23127E-03 -3.6359 0.83497E+00 -0.0783 4 SO4-- 0.13506E-11 -11.8695 0.70060E-12 -12.1545 0.51875E+00 -0.2850 5 HCO3- 0.58779E-06 -6.2308 0.49150E-06 -6.3085 0.83619E+00 -0.0777 6 HS- 0.53334E-04 -4.2730 0.44538E-04 -4.3513 0.83509E+00 -0.0783 7 Al+++ 0.98242E-29 -29.0077 0.22642E-29 -29.6451 0.23047E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13616E-06 -6.8660 0.70111E-07 -7.1542 0.51493E+00 -0.2882 10 Mg++ 0.21301E-10 -10.6716 0.10918E-10 -10.9618 0.51257E+00 -0.2902 11 Fe++ 0.58709E-13 -13.2313 0.30125E-13 -13.5211 0.51313E+00 -0.2898 12 K+ 0.15715E-03 -3.8037 0.13144E-03 -3.8813 0.83639E+00 -0.0776 13 Na+ 0.19942E-01 -1.7002 0.16648E-01 -1.7787 0.83482E+00 -0.0784 14 Mn++ 0.18834E-10 -10.7251 0.96723E-11 -11.0145 0.51356E+00 -0.2894 15 F- 0.23296E-06 -6.6327 0.19411E-06 -6.7120 0.83324E+00 -0.0792 16 HPO4-- 0.45027E-07 -7.3465 0.23361E-07 -7.6315 0.51883E+00 -0.2850 18 HSiO3- 0.10451E-01 -1.9808 0.87266E-02 -2.0592 0.83497E+00 -0.0783 19 Ca(HSiO3)+ 0.16656E-07 -7.7784 0.13934E-07 -7.8559 0.83657E+00 -0.0775 20 Mg(HSiO3)+ 0.32279E-11 -11.4911 0.27004E-11 -11.5686 0.83657E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66393E-16 -16.1779 0.55543E-16 -16.2554 0.83657E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52973E-05 -5.2759 0.44151E-05 -5.3551 0.83346E+00 -0.0791 26 CH4,aq 0.30458E-04 -4.5163 0.30351E-04 -4.5178 0.99651E+00 -0.0015 27 C2H6,aq 0.13644E-13 -13.8650 0.13597E-13 -13.8666 0.99651E+00 -0.0015 31 CO,aq 0.22756E-16 -16.6429 0.22756E-16 -16.6429 0.10000E+01 0.0000 32 CO2,aq 0.78484E-10 -10.1052 0.78210E-10 -10.1067 0.99651E+00 -0.0015 33 CO3-2 0.11137E-05 -5.9532 0.57649E-06 -6.2392 0.51765E+00 -0.2860 34 CaCO3,aq 0.50680E-09 -9.2952 0.50680E-09 -9.2952 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10515E-11 -11.9782 0.87962E-12 -12.0557 0.83657E+00 -0.0775 36 CaCl+ 0.31367E-10 -10.5035 0.26241E-10 -10.5810 0.83657E+00 -0.0775 37 CaCl2,aq 0.14418E-14 -14.8411 0.14418E-14 -14.8411 0.10000E+01 0.0000 38 CaF+ 0.23751E-12 -12.6243 0.19869E-12 -12.7018 0.83657E+00 -0.0775 39 CaOH+ 0.80206E-07 -7.0958 0.67098E-07 -7.1733 0.83657E+00 -0.0775 40 CaSO4,aq 0.15598E-16 -16.8069 0.15598E-16 -16.8069 0.10000E+01 0.0000 41 HCl,aq 0.31560E-14 -14.5009 0.31560E-14 -14.5009 0.10000E+01 0.0000 45 HF,aq 0.98956E-13 -13.0046 0.98956E-13 -13.0046 0.10000E+01 0.0000 48 FeCl+ 0.13182E-16 -16.8800 0.11028E-16 -16.9575 0.83657E+00 -0.0775 51 FeF+ 0.35720E-18 -18.4471 0.29882E-18 -18.5246 0.83657E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15740E-10 -10.8030 0.13168E-10 -10.8805 0.83657E+00 -0.0775 55 HFeO2- 0.35527E-07 -7.4494 0.29664E-07 -7.5278 0.83497E+00 -0.0783 56 FeO+ 0.11032E-16 -16.9574 0.92287E-17 -17.0349 0.83657E+00 -0.0775 58 FeO2- 0.40782E-09 -9.3895 0.34051E-09 -9.4679 0.83497E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99651E+00 -0.0015 61 KCl,aq 0.55094E-09 -9.2589 0.55094E-09 -9.2589 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.17114E-14 -14.7667 0.14290E-14 -14.8450 0.83497E+00 -0.0783 65 MgCO3,aq 0.19782E-13 -13.7037 0.19782E-13 -13.7037 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16731E-15 -15.7765 0.13997E-15 -15.8540 0.83657E+00 -0.0775 67 MgCl+ 0.44272E-14 -14.3539 0.37036E-14 -14.4314 0.83657E+00 -0.0775 68 MgF+ 0.13701E-15 -15.8632 0.11462E-15 -15.9407 0.83657E+00 -0.0775 69 MgOH+ 0.69115E-10 -10.1604 0.57820E-10 -10.2379 0.83657E+00 -0.0775 71 MnF+ 0.37801E-16 -16.4225 0.31623E-16 -16.5000 0.83657E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46947E-09 -9.3284 0.39275E-09 -9.4059 0.83657E+00 -0.0775 74 MnO2-2 0.20881E-10 -10.6803 0.10809E-10 -10.9662 0.51765E+00 -0.2860 75 HMnO2- 0.21120E-09 -9.6753 0.17635E-09 -9.7536 0.83497E+00 -0.0783 78 MnCl+ 0.16466E-13 -13.7834 0.13775E-13 -13.8609 0.83657E+00 -0.0775 80 NaCl,aq 0.12759E-05 -5.8942 0.12759E-05 -5.8942 0.10000E+01 0.0000 81 NaF,aq 0.75654E-09 -9.1212 0.75654E-09 -9.1212 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93088E-02 -2.0311 0.77585E-02 -2.1102 0.83346E+00 -0.0791 89 HPO3-2 0.16290E-14 -14.7881 0.84323E-15 -15.0741 0.51765E+00 -0.2860 91 H2PO3- 0.15081E-18 -18.8216 0.12592E-18 -18.8999 0.83497E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38400E-10 -10.4157 0.32093E-10 -10.4936 0.83576E+00 -0.0779 94 PO4-3 0.10572E-08 -8.9758 0.25595E-09 -9.5918 0.24210E+00 -0.6160 98 HP2O7-3 0.93863E-18 -18.0275 0.21654E-18 -18.6645 0.23070E+00 -0.6370 99 P2O7-4 0.90473E-17 -17.0435 0.69466E-18 -18.1582 0.76781E-01 -1.1147 100 H2S,aq 0.10287E-07 -7.9877 0.10251E-07 -7.9892 0.99651E+00 -0.0015 101 S2-2 0.73310E-14 -14.1348 0.37949E-14 -14.4208 0.51765E+00 -0.2860 107 SO3-2 0.20080E-17 -17.6972 0.10545E-17 -17.9769 0.52516E+00 -0.2797 109 HSO4- 0.60044E-19 -19.2215 0.50280E-19 -19.2986 0.83739E+00 -0.0771 Charge balance for all species = -.7366E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8865032E-10 -.2223208E-01 -.2236957E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981958E+06 0.0000 3 Cl- 0.2769830E-03 0.2782595E-03 0.9847951E+01 6.4921 4 SO4-- 0.1350551E-11 -.3336334E-04 -.3199353E+01 8.1015 5 HCO3- 0.5877873E-06 0.3215968E-04 0.1958875E+01 3.8195 6 HS- 0.5333357E-04 0.8670720E-04 0.2862585E+01 5.7768 7 Al+++ 0.9824178E-29 0.5297483E-05 0.1426851E+00 0.7390 8 H4SiO4 0.6959792E-03 0.1349702E-01 0.1295012E+04 -3.1574 9 Ca++ 0.1361555E-06 0.2335566E-06 0.9344175E-02 13.1018 10 Mg++ 0.2130087E-10 0.9366805E-10 0.2273291E-05 9.2942 11 Fe++ 0.5870880E-13 0.3616448E-07 0.2016160E-02 6.7350 12 K+ 0.1571487E-03 0.1579030E-03 0.6163570E+01 6.2467 13 Na+ 0.1994150E-01 0.2238846E-01 0.5138097E+03 8.3494 14 Mn++ 0.1883379E-10 0.2526597E-08 0.1385644E-03 9.2416 15 F- 0.2329558E-06 0.2337127E-06 0.4432340E-02 3.4161 16 HPO4-- 0.4502732E-07 0.4612293E-07 0.4419122E-02 12.6245 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279254E+02 -.1103458E-01 -.8278151E+02 0.0000000E+00 2 H2O -.7168756E+01 0.2754908E+02 -.3471783E+02 0.0000000E+00 3 Cl- 0.1381102E-03 0.1381102E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385927E+00 -.1655942E-04 0.1386093E+00 0.0000000E+00 5 HCO3- 0.1596200E-04 0.1596200E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385662E+00 0.4303589E-04 -.1386093E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629331E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6699056E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1159225E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4649081E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794973E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7837294E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111220E-01 0.6265265E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254041E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1160000E-06 0.1160000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2289247E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1598E-13 Mass of aqueous solution: 0.497202E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000400 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5544 -0.256 281.8 2.450 5.158 73.20 grossular 0.1343 -0.872 60.47 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2626 -0.581 56.87 1.755 1.041 17.38 hedenbergite 0.6811E-01 -1.167 16.90 1.228 0.3093 4.628 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2614 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4251E-01 -1.372 36.33 1.560 0.6652 11.69 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337874 g Volume = 2210.777969 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000400 moles log = -4.3979 Original solution: 1000.0103000 g Original solution / Rock added: 25000257.50 (Water/Rock Ratio), log = 7.3979 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0805 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9451E+00 0.9852 0.1006E+01 0.1021E+01 CO2,gas 0.7694E-08 1.0066 0.8368E-08 0.8313E-08 CH4,gas 0.4085E-01 1.0121 0.4468E-01 0.4414E-01 H2,gas 0.1407E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2619E-06 0.9958 0.2818E-06 0.2830E-06 S2,gas 0.1193E-28 1.0000 0.1289E-28 0.1289E-28 CO,gas 0.3139E-13 1.0000 0.3391E-13 0.3391E-13 SO3,gas 0.1360E-47 1.0000 0.1469E-47 0.1469E-47 SO2,gas 0.8044E-27 1.0000 0.8691E-27 0.8691E-27 HF,gas 0.2249E-15 1.0000 0.2430E-15 0.2430E-15 HCl,gas 0.5154E-17 1.0000 0.5569E-17 0.5569E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.44 -9.78 -3.259 0.16693E+05 -8.077 3 CH4,gas 4.54 1.49 -3.05 -0.762 0.52059E+04 -1.350 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.48 -8.25 -4.125 0.14085E+05 -6.550 6 S2,gas -7.34 -37.92 -30.59 -4.706 0.52229E+05 -28.890 7 CO,gas 3.21 -11.95 -15.17 -4.667 0.25900E+05 -13.470 8 SO3,gas 17.12 -32.41 -49.53 -12.383 0.84574E+05 -47.833 9 SO2,gas 0.83 -27.93 -28.76 -7.669 0.49107E+05 -27.061 10 HF,gas 0.47 -16.84 -17.31 -8.657 0.29562E+05 -15.614 11 HCl,gas 5.19 -13.76 -18.95 -9.477 0.32362E+05 -17.254 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.99 -0.69 -0.058 0.11824E+04 38 aragonite 0.97 -3.33 -4.30 -1.434 0.73442E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.33 -4.15 -1.382 0.70799E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.47 -4.37 -1.248 0.74590E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.47 -3.92 -1.121 0.67013E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.74 -3.48 -1.161 0.59488E+04 147 pyrrhotiteFe0.875 -6.02 -9.14 -3.13 -1.149 0.53360E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.74 -3.33 -1.111 0.56916E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.24 -4.26 -1.420 0.72736E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000400 MOLES New total amount of reactant added: 0.0000500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142947E-01 Osmotic coef. = 0.9707 True ionic strength = .2010077E-01 Chg. balance for total moles = -.3663E-10 Max. difference allowed = 0.1382E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88652E-10 -10.0523 0.74471E-10 -10.1280 0.84004E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27710E-03 -3.5574 0.23137E-03 -3.6357 0.83497E+00 -0.0783 4 SO4-- 0.13629E-11 -11.8655 0.70702E-12 -12.1506 0.51875E+00 -0.2850 5 HCO3- 0.61440E-06 -6.2115 0.51376E-06 -6.2892 0.83619E+00 -0.0777 6 HS- 0.53823E-04 -4.2690 0.44947E-04 -4.3473 0.83509E+00 -0.0783 7 Al+++ 0.98249E-29 -29.0077 0.22643E-29 -29.6451 0.23046E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13616E-06 -6.8659 0.70114E-07 -7.1542 0.51493E+00 -0.2883 10 Mg++ 0.21302E-10 -10.6716 0.10919E-10 -10.9618 0.51257E+00 -0.2902 11 Fe++ 0.58711E-13 -13.2313 0.30127E-13 -13.5211 0.51313E+00 -0.2898 12 K+ 0.15715E-03 -3.8037 0.13144E-03 -3.8813 0.83639E+00 -0.0776 13 Na+ 0.19942E-01 -1.7002 0.16648E-01 -1.7786 0.83482E+00 -0.0784 14 Mn++ 0.18835E-10 -10.7250 0.96726E-11 -11.0145 0.51356E+00 -0.2894 15 F- 0.24099E-06 -6.6180 0.20080E-06 -6.6972 0.83324E+00 -0.0792 16 HPO4-- 0.45026E-07 -7.3465 0.23361E-07 -7.6315 0.51882E+00 -0.2850 18 HSiO3- 0.10451E-01 -1.9808 0.87264E-02 -2.0592 0.83497E+00 -0.0783 19 Ca(HSiO3)+ 0.16656E-07 -7.7784 0.13934E-07 -7.8559 0.83657E+00 -0.0775 20 Mg(HSiO3)+ 0.32280E-11 -11.4911 0.27005E-11 -11.5686 0.83657E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66394E-16 -16.1779 0.55544E-16 -16.2554 0.83657E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52972E-05 -5.2760 0.44150E-05 -5.3551 0.83346E+00 -0.0791 26 CH4,aq 0.31837E-04 -4.4971 0.31726E-04 -4.4986 0.99651E+00 -0.0015 27 C2H6,aq 0.14908E-13 -13.8266 0.14857E-13 -13.8281 0.99651E+00 -0.0015 31 CO,aq 0.23787E-16 -16.6237 0.23787E-16 -16.6237 0.10000E+01 0.0000 32 CO2,aq 0.82039E-10 -10.0860 0.81753E-10 -10.0875 0.99651E+00 -0.0015 33 CO3-2 0.11641E-05 -5.9340 0.60258E-06 -6.2200 0.51765E+00 -0.2860 34 CaCO3,aq 0.52976E-09 -9.2759 0.52976E-09 -9.2759 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10991E-11 -11.9590 0.91948E-12 -12.0365 0.83657E+00 -0.0775 36 CaCl+ 0.31381E-10 -10.5033 0.26253E-10 -10.5808 0.83657E+00 -0.0775 37 CaCl2,aq 0.14431E-14 -14.8407 0.14431E-14 -14.8407 0.10000E+01 0.0000 38 CaF+ 0.24571E-12 -12.6096 0.20555E-12 -12.6871 0.83657E+00 -0.0775 39 CaOH+ 0.80208E-07 -7.0958 0.67099E-07 -7.1733 0.83657E+00 -0.0775 40 CaSO4,aq 0.15741E-16 -16.8030 0.15741E-16 -16.8030 0.10000E+01 0.0000 41 HCl,aq 0.31574E-14 -14.5007 0.31574E-14 -14.5007 0.10000E+01 0.0000 45 HF,aq 0.10237E-12 -12.9898 0.10237E-12 -12.9898 0.10000E+01 0.0000 48 FeCl+ 0.13188E-16 -16.8798 0.11033E-16 -16.9573 0.83657E+00 -0.0775 51 FeF+ 0.36953E-18 -18.4324 0.30914E-18 -18.5098 0.83657E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15741E-10 -10.8030 0.13168E-10 -10.8805 0.83657E+00 -0.0775 55 HFeO2- 0.35526E-07 -7.4495 0.29663E-07 -7.5278 0.83497E+00 -0.0783 56 FeO+ 0.11032E-16 -16.9574 0.92289E-17 -17.0348 0.83657E+00 -0.0775 58 FeO2- 0.40781E-09 -9.3895 0.34051E-09 -9.4679 0.83497E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99651E+00 -0.0015 61 KCl,aq 0.55118E-09 -9.2587 0.55118E-09 -9.2587 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.17271E-14 -14.7627 0.14421E-14 -14.8410 0.83497E+00 -0.0783 65 MgCO3,aq 0.20679E-13 -13.6845 0.20679E-13 -13.6845 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.17489E-15 -15.7572 0.14631E-15 -15.8347 0.83657E+00 -0.0775 67 MgCl+ 0.44292E-14 -14.3537 0.37054E-14 -14.4312 0.83657E+00 -0.0775 68 MgF+ 0.14174E-15 -15.8485 0.11858E-15 -15.9260 0.83657E+00 -0.0775 69 MgOH+ 0.69116E-10 -10.1604 0.57821E-10 -10.2379 0.83657E+00 -0.0775 71 MnF+ 0.39106E-16 -16.4078 0.32715E-16 -16.4853 0.83657E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46948E-09 -9.3284 0.39276E-09 -9.4059 0.83657E+00 -0.0775 74 MnO2-2 0.20880E-10 -10.6803 0.10808E-10 -10.9662 0.51765E+00 -0.2860 75 HMnO2- 0.21120E-09 -9.6753 0.17634E-09 -9.7536 0.83497E+00 -0.0783 78 MnCl+ 0.16473E-13 -13.7832 0.13781E-13 -13.8607 0.83657E+00 -0.0775 80 NaCl,aq 0.12765E-05 -5.8940 0.12765E-05 -5.8940 0.10000E+01 0.0000 81 NaF,aq 0.78264E-09 -9.1064 0.78264E-09 -9.1064 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93087E-02 -2.0311 0.77584E-02 -2.1102 0.83346E+00 -0.0791 89 HPO3-2 0.16289E-14 -14.7881 0.84320E-15 -15.0741 0.51765E+00 -0.2860 91 H2PO3- 0.15081E-18 -18.8216 0.12592E-18 -18.8999 0.83497E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38399E-10 -10.4157 0.32092E-10 -10.4936 0.83576E+00 -0.0779 94 PO4-3 0.10572E-08 -8.9759 0.25593E-09 -9.5919 0.24209E+00 -0.6160 98 HP2O7-3 0.93859E-18 -18.0275 0.21653E-18 -18.6645 0.23070E+00 -0.6370 99 P2O7-4 0.90468E-17 -17.0435 0.69461E-18 -18.1583 0.76779E-01 -1.1148 100 H2S,aq 0.10381E-07 -7.9837 0.10345E-07 -7.9853 0.99651E+00 -0.0015 101 S2-2 0.74662E-14 -14.1269 0.38648E-14 -14.4129 0.51765E+00 -0.2860 107 SO3-2 0.20264E-17 -17.6933 0.10642E-17 -17.9730 0.52516E+00 -0.2797 109 HSO4- 0.60595E-19 -19.2176 0.50742E-19 -19.2946 0.83739E+00 -0.0771 Charge balance for all species = -.7372E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8865210E-10 -.2223179E-01 -.2236928E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981957E+06 0.0000 3 Cl- 0.2771012E-03 0.2783783E-03 0.9852154E+01 6.4923 4 SO4-- 0.1362926E-11 -.3474295E-04 -.3331650E+01 8.1055 5 HCO3- 0.6144015E-06 0.3361634E-04 0.2047602E+01 3.8388 6 HS- 0.5382305E-04 0.8857638E-04 0.2924295E+01 5.7807 7 Al+++ 0.9824862E-29 0.5297392E-05 0.1426826E+00 0.7390 8 H4SiO4 0.6959792E-03 0.1349684E-01 0.1294995E+04 -3.1574 9 Ca++ 0.1361615E-06 0.2335875E-06 0.9345410E-02 13.1018 10 Mg++ 0.2130179E-10 0.9367160E-10 0.2273377E-05 9.2942 11 Fe++ 0.5871135E-13 0.3616386E-07 0.2016125E-02 6.7350 12 K+ 0.1571519E-03 0.1579062E-03 0.6163693E+01 6.2467 13 Na+ 0.1994190E-01 0.2238887E-01 0.5138189E+03 8.3494 14 Mn++ 0.1883463E-10 0.2526606E-08 0.1385649E-03 9.2416 15 F- 0.2409887E-06 0.2417717E-06 0.4585177E-02 3.4308 16 HPO4-- 0.4502590E-07 0.4612147E-07 0.4418982E-02 12.6245 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279254E+02 -.1103444E-01 -.8278151E+02 0.0000000E+00 2 H2O -.7168748E+01 0.2754909E+02 -.3471783E+02 0.0000000E+00 3 Cl- 0.1381692E-03 0.1381692E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385928E+00 -.1724418E-04 0.1386100E+00 0.0000000E+00 5 HCO3- 0.1668500E-04 0.1668500E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385660E+00 0.4396365E-04 -.1386100E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629287E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6698969E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1159379E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4649259E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794943E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7837454E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111240E-01 0.6265265E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254046E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1200000E-06 0.1200000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2289175E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.2720E-14 Mass of aqueous solution: 0.497202E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5544 -0.256 281.8 2.450 5.158 73.20 grossular 0.1343 -0.872 60.47 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2626 -0.581 56.87 1.755 1.041 17.38 hedenbergite 0.6810E-01 -1.167 16.90 1.228 0.3093 4.628 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2614 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4251E-01 -1.371 36.34 1.560 0.6652 11.70 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337878 g Volume = 2210.777996 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000500 moles log = -4.3010 Original solution: 1000.0103000 g Original solution / Rock added: 20000206.00 (Water/Rock Ratio), log = 7.3010 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0825 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9433E+00 0.9851 0.1006E+01 0.1021E+01 CO2,gas 0.8028E-08 1.0065 0.8747E-08 0.8690E-08 CH4,gas 0.4262E-01 1.0121 0.4670E-01 0.4614E-01 H2,gas 0.1404E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2638E-06 0.9958 0.2844E-06 0.2856E-06 S2,gas 0.1213E-28 1.0000 0.1313E-28 0.1313E-28 CO,gas 0.3275E-13 1.0000 0.3545E-13 0.3545E-13 SO3,gas 0.1370E-47 1.0000 0.1483E-47 0.1483E-47 SO2,gas 0.8103E-27 1.0000 0.8771E-27 0.8771E-27 HF,gas 0.2322E-15 1.0000 0.2514E-15 0.2514E-15 HCl,gas 0.5147E-17 1.0000 0.5571E-17 0.5571E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.42 -9.76 -3.252 0.16660E+05 -8.058 3 CH4,gas 4.54 1.51 -3.03 -0.757 0.51731E+04 -1.331 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.48 -8.25 -4.123 0.14078E+05 -6.546 6 S2,gas -7.34 -37.92 -30.58 -4.705 0.52216E+05 -28.882 7 CO,gas 3.21 -11.93 -15.15 -4.661 0.25867E+05 -13.450 8 SO3,gas 17.12 -32.41 -49.53 -12.382 0.84568E+05 -47.829 9 SO2,gas 0.83 -27.92 -28.76 -7.668 0.49100E+05 -27.057 10 HF,gas 0.47 -16.83 -17.30 -8.649 0.29537E+05 -15.600 11 HCl,gas 5.19 -13.76 -18.95 -9.477 0.32362E+05 -17.254 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.98 -0.68 -0.056 0.11572E+04 38 aragonite 0.97 -3.32 -4.28 -1.427 0.73113E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.32 -4.13 -1.376 0.70471E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.45 -4.35 -1.243 0.74262E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.45 -3.91 -1.116 0.66684E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.74 -3.48 -1.160 0.59420E+04 147 pyrrhotiteFe0.875 -6.02 -9.14 -3.12 -1.148 0.53292E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.74 -3.33 -1.110 0.56848E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.23 -4.26 -1.419 0.72668E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000500 MOLES New total amount of reactant added: 0.0000600 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3664E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000600 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142864E-01 Osmotic coef. = 0.9712 True ionic strength = .2010123E-01 Chg. balance for total moles = -.3664E-10 Max. difference allowed = 0.1382E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88654E-10 -10.0523 0.74472E-10 -10.1280 0.84003E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27722E-03 -3.5572 0.23147E-03 -3.6355 0.83497E+00 -0.0783 4 SO4-- 0.13753E-11 -11.8616 0.71343E-12 -12.1466 0.51875E+00 -0.2850 5 HCO3- 0.64101E-06 -6.1931 0.53601E-06 -6.2708 0.83619E+00 -0.0777 6 HS- 0.54313E-04 -4.2651 0.45356E-04 -4.3434 0.83509E+00 -0.0783 7 Al+++ 0.98255E-29 -29.0076 0.22644E-29 -29.6450 0.23046E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13617E-06 -6.8659 0.70116E-07 -7.1542 0.51493E+00 -0.2883 10 Mg++ 0.21303E-10 -10.6716 0.10919E-10 -10.9618 0.51256E+00 -0.2903 11 Fe++ 0.58714E-13 -13.2313 0.30128E-13 -13.5210 0.51313E+00 -0.2898 12 K+ 0.15716E-03 -3.8037 0.13144E-03 -3.8813 0.83639E+00 -0.0776 13 Na+ 0.19942E-01 -1.7002 0.16648E-01 -1.7786 0.83481E+00 -0.0784 14 Mn++ 0.18835E-10 -10.7250 0.96730E-11 -11.0144 0.51355E+00 -0.2894 15 F- 0.24902E-06 -6.6038 0.20749E-06 -6.6830 0.83324E+00 -0.0792 16 HPO4-- 0.45024E-07 -7.3466 0.23360E-07 -7.6315 0.51882E+00 -0.2850 18 HSiO3- 0.10451E-01 -1.9808 0.87263E-02 -2.0592 0.83497E+00 -0.0783 19 Ca(HSiO3)+ 0.16656E-07 -7.7784 0.13934E-07 -7.8559 0.83657E+00 -0.0775 20 Mg(HSiO3)+ 0.32281E-11 -11.4911 0.27005E-11 -11.5686 0.83657E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66396E-16 -16.1779 0.55545E-16 -16.2554 0.83657E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52972E-05 -5.2760 0.44149E-05 -5.3551 0.83345E+00 -0.0791 26 CH4,aq 0.33217E-04 -4.4786 0.33101E-04 -4.4802 0.99652E+00 -0.0015 27 C2H6,aq 0.16229E-13 -13.7897 0.16172E-13 -13.7912 0.99652E+00 -0.0015 31 CO,aq 0.24818E-16 -16.6052 0.24818E-16 -16.6052 0.10000E+01 0.0000 32 CO2,aq 0.85594E-10 -10.0676 0.85295E-10 -10.0691 0.99652E+00 -0.0015 33 CO3-2 0.12145E-05 -5.9156 0.62867E-06 -6.2016 0.51764E+00 -0.2860 34 CaCO3,aq 0.55271E-09 -9.2575 0.55271E-09 -9.2575 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11468E-11 -11.9405 0.95935E-12 -12.0180 0.83657E+00 -0.0775 36 CaCl+ 0.31396E-10 -10.5031 0.26265E-10 -10.5806 0.83657E+00 -0.0775 37 CaCl2,aq 0.14444E-14 -14.8403 0.14444E-14 -14.8403 0.10000E+01 0.0000 38 CaF+ 0.25391E-12 -12.5953 0.21241E-12 -12.6728 0.83657E+00 -0.0775 39 CaOH+ 0.80209E-07 -7.0958 0.67101E-07 -7.1733 0.83657E+00 -0.0775 40 CaSO4,aq 0.15885E-16 -16.7990 0.15885E-16 -16.7990 0.10000E+01 0.0000 41 HCl,aq 0.31588E-14 -14.5005 0.31588E-14 -14.5005 0.10000E+01 0.0000 45 HF,aq 0.10578E-12 -12.9756 0.10578E-12 -12.9756 0.10000E+01 0.0000 48 FeCl+ 0.13194E-16 -16.8796 0.11038E-16 -16.9571 0.83657E+00 -0.0775 51 FeF+ 0.38186E-18 -18.4181 0.31945E-18 -18.4956 0.83657E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15741E-10 -10.8030 0.13168E-10 -10.8805 0.83657E+00 -0.0775 55 HFeO2- 0.35525E-07 -7.4495 0.29662E-07 -7.5278 0.83497E+00 -0.0783 56 FeO+ 0.11032E-16 -16.9573 0.92291E-17 -17.0348 0.83657E+00 -0.0775 58 FeO2- 0.40780E-09 -9.3896 0.34050E-09 -9.4679 0.83497E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55143E-09 -9.2585 0.55143E-09 -9.2585 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.17428E-14 -14.7588 0.14552E-14 -14.8371 0.83497E+00 -0.0783 65 MgCO3,aq 0.21575E-13 -13.6661 0.21575E-13 -13.6661 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.18248E-15 -15.7388 0.15266E-15 -15.8163 0.83657E+00 -0.0775 67 MgCl+ 0.44313E-14 -14.3535 0.37071E-14 -14.4310 0.83657E+00 -0.0775 68 MgF+ 0.14647E-15 -15.8343 0.12253E-15 -15.9117 0.83657E+00 -0.0775 69 MgOH+ 0.69118E-10 -10.1604 0.57822E-10 -10.2379 0.83657E+00 -0.0775 71 MnF+ 0.40411E-16 -16.3935 0.33807E-16 -16.4710 0.83657E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46949E-09 -9.3284 0.39276E-09 -9.4059 0.83657E+00 -0.0775 74 MnO2-2 0.20879E-10 -10.6803 0.10808E-10 -10.9663 0.51764E+00 -0.2860 75 HMnO2- 0.21119E-09 -9.6753 0.17634E-09 -9.7536 0.83497E+00 -0.0783 78 MnCl+ 0.16481E-13 -13.7830 0.13788E-13 -13.8605 0.83657E+00 -0.0775 80 NaCl,aq 0.12771E-05 -5.8938 0.12771E-05 -5.8938 0.10000E+01 0.0000 81 NaF,aq 0.80874E-09 -9.0922 0.80874E-09 -9.0922 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93085E-02 -2.0311 0.77582E-02 -2.1102 0.83345E+00 -0.0791 89 HPO3-2 0.16289E-14 -14.7881 0.84317E-15 -15.0741 0.51764E+00 -0.2860 91 H2PO3- 0.15081E-18 -18.8216 0.12592E-18 -18.8999 0.83497E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38398E-10 -10.4157 0.32092E-10 -10.4936 0.83576E+00 -0.0779 94 PO4-3 0.10571E-08 -8.9759 0.25592E-09 -9.5919 0.24209E+00 -0.6160 98 HP2O7-3 0.93855E-18 -18.0275 0.21652E-18 -18.6645 0.23069E+00 -0.6370 99 P2O7-4 0.90464E-17 -17.0435 0.69455E-18 -18.1583 0.76777E-01 -1.1148 100 H2S,aq 0.10476E-07 -7.9798 0.10439E-07 -7.9813 0.99652E+00 -0.0015 101 S2-2 0.76026E-14 -14.1190 0.39354E-14 -14.4050 0.51764E+00 -0.2860 107 SO3-2 0.20448E-17 -17.6894 0.10738E-17 -17.9691 0.52515E+00 -0.2797 109 HSO4- 0.61146E-19 -19.2136 0.51203E-19 -19.2907 0.83739E+00 -0.0771 Charge balance for all species = -.7374E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8865388E-10 -.2223150E-01 -.2236898E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981957E+06 0.0000 3 Cl- 0.2772194E-03 0.2784971E-03 0.9856357E+01 6.4925 4 SO4-- 0.1375301E-11 -.3612257E-04 -.3463947E+01 8.1094 5 HCO3- 0.6410147E-06 0.3507300E-04 0.2136328E+01 3.8572 6 HS- 0.5431252E-04 0.9044556E-04 0.2986005E+01 5.7846 7 Al+++ 0.9825546E-29 0.5297302E-05 0.1426802E+00 0.7390 8 H4SiO4 0.6959792E-03 0.1349666E-01 0.1294977E+04 -3.1574 9 Ca++ 0.1361674E-06 0.2336183E-06 0.9346646E-02 13.1018 10 Mg++ 0.2130272E-10 0.9367335E-10 0.2273419E-05 9.2942 11 Fe++ 0.5871390E-13 0.3616325E-07 0.2016091E-02 6.7350 12 K+ 0.1571551E-03 0.1579094E-03 0.6163816E+01 6.2467 13 Na+ 0.1994230E-01 0.2238927E-01 0.5138281E+03 8.3494 14 Mn++ 0.1883546E-10 0.2526614E-08 0.1385653E-03 9.2416 15 F- 0.2490216E-06 0.2498307E-06 0.4738015E-02 3.4450 16 HPO4-- 0.4502449E-07 0.4612001E-07 0.4418842E-02 12.6245 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279254E+02 -.1103430E-01 -.8278151E+02 0.0000000E+00 2 H2O -.7168740E+01 0.2754910E+02 -.3471784E+02 0.0000000E+00 3 Cl- 0.1382282E-03 0.1382282E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385928E+00 -.1792894E-04 0.1386107E+00 0.0000000E+00 5 HCO3- 0.1740800E-04 0.1740800E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385658E+00 0.4489141E-04 -.1386107E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629243E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6698883E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1159532E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4649348E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794913E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7837613E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111260E-01 0.6265264E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254050E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1240000E-06 0.1240000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2289103E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1688E-13 Mass of aqueous solution: 0.497202E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000600 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5544 -0.256 281.8 2.450 5.158 73.20 grossular 0.1343 -0.872 60.47 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2626 -0.581 56.86 1.755 1.041 17.38 hedenbergite 0.6810E-01 -1.167 16.89 1.228 0.3093 4.627 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2614 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4252E-01 -1.371 36.34 1.560 0.6653 11.70 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337881 g Volume = 2210.778024 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000600 moles log = -4.2218 Original solution: 1000.0103000 g Original solution / Rock added: 16666838.33 (Water/Rock Ratio), log = 7.2219 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0845 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9416E+00 0.9851 0.1006E+01 0.1021E+01 CO2,gas 0.8360E-08 1.0065 0.9126E-08 0.9067E-08 CH4,gas 0.4439E-01 1.0121 0.4872E-01 0.4814E-01 H2,gas 0.1401E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2657E-06 0.9958 0.2870E-06 0.2882E-06 S2,gas 0.1233E-28 1.0000 0.1337E-28 0.1337E-28 CO,gas 0.3410E-13 1.0000 0.3698E-13 0.3698E-13 SO3,gas 0.1379E-47 1.0000 0.1496E-47 0.1496E-47 SO2,gas 0.8161E-27 1.0000 0.8851E-27 0.8851E-27 HF,gas 0.2395E-15 1.0000 0.2597E-15 0.2597E-15 HCl,gas 0.5139E-17 1.0000 0.5574E-17 0.5574E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.40 -9.74 -3.246 0.16629E+05 -8.040 3 CH4,gas 4.54 1.53 -3.01 -0.753 0.51416E+04 -1.312 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.47 -8.24 -4.121 0.14072E+05 -6.542 6 S2,gas -7.34 -37.91 -30.57 -4.704 0.52202E+05 -28.874 7 CO,gas 3.21 -11.92 -15.13 -4.656 0.25836E+05 -13.432 8 SO3,gas 17.12 -32.40 -49.52 -12.381 0.84561E+05 -47.825 9 SO2,gas 0.83 -27.92 -28.75 -7.667 0.49093E+05 -27.053 10 HF,gas 0.47 -16.81 -17.28 -8.642 0.29513E+05 -15.585 11 HCl,gas 5.19 -13.76 -18.95 -9.476 0.32361E+05 -17.254 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.96 -0.66 -0.055 0.11329E+04 38 aragonite 0.97 -3.30 -4.26 -1.421 0.72798E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.30 -4.11 -1.370 0.70156E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.43 -4.33 -1.237 0.73947E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.43 -3.89 -1.111 0.66370E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.74 -3.48 -1.159 0.59353E+04 147 pyrrhotiteFe0.875 -6.02 -9.13 -3.12 -1.146 0.53225E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.74 -3.33 -1.108 0.56781E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.23 -4.25 -1.417 0.72601E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000600 MOLES New total amount of reactant added: 0.0000700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142781E-01 Osmotic coef. = 0.9716 True ionic strength = .2010168E-01 Chg. balance for total moles = -.3663E-10 Max. difference allowed = 0.1383E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88656E-10 -10.0523 0.74474E-10 -10.1280 0.84003E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27734E-03 -3.5570 0.23157E-03 -3.6353 0.83497E+00 -0.0783 4 SO4-- 0.13877E-11 -11.8577 0.71985E-12 -12.1428 0.51874E+00 -0.2850 5 HCO3- 0.66763E-06 -6.1755 0.55826E-06 -6.2532 0.83619E+00 -0.0777 6 HS- 0.54802E-04 -4.2612 0.45764E-04 -4.3395 0.83509E+00 -0.0783 7 Al+++ 0.98262E-29 -29.0076 0.22645E-29 -29.6450 0.23046E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13617E-06 -6.8659 0.70119E-07 -7.1542 0.51492E+00 -0.2883 10 Mg++ 0.21304E-10 -10.6715 0.10919E-10 -10.9618 0.51256E+00 -0.2903 11 Fe++ 0.58716E-13 -13.2312 0.30129E-13 -13.5210 0.51312E+00 -0.2898 12 K+ 0.15716E-03 -3.8037 0.13145E-03 -3.8813 0.83639E+00 -0.0776 13 Na+ 0.19943E-01 -1.7002 0.16648E-01 -1.7786 0.83481E+00 -0.0784 14 Mn++ 0.18836E-10 -10.7250 0.96734E-11 -11.0144 0.51355E+00 -0.2894 15 F- 0.25705E-06 -6.5900 0.21419E-06 -6.6692 0.83324E+00 -0.0792 16 HPO4-- 0.45023E-07 -7.3466 0.23359E-07 -7.6316 0.51882E+00 -0.2850 18 HSiO3- 0.10451E-01 -1.9808 0.87261E-02 -2.0592 0.83497E+00 -0.0783 19 Ca(HSiO3)+ 0.16657E-07 -7.7784 0.13934E-07 -7.8559 0.83657E+00 -0.0775 20 Mg(HSiO3)+ 0.32281E-11 -11.4910 0.27006E-11 -11.5685 0.83657E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66397E-16 -16.1779 0.55546E-16 -16.2553 0.83657E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52971E-05 -5.2760 0.44149E-05 -5.3551 0.83345E+00 -0.0791 26 CH4,aq 0.34596E-04 -4.4610 0.34476E-04 -4.4625 0.99652E+00 -0.0015 27 C2H6,aq 0.17605E-13 -13.7544 0.17543E-13 -13.7559 0.99652E+00 -0.0015 31 CO,aq 0.25849E-16 -16.5876 0.25849E-16 -16.5876 0.10000E+01 0.0000 32 CO2,aq 0.89149E-10 -10.0499 0.88838E-10 -10.0514 0.99652E+00 -0.0015 33 CO3-2 0.12649E-05 -5.8979 0.65476E-06 -6.1839 0.51764E+00 -0.2860 34 CaCO3,aq 0.57567E-09 -9.2398 0.57567E-09 -9.2398 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11944E-11 -11.9228 0.99921E-12 -12.0003 0.83657E+00 -0.0775 36 CaCl+ 0.31410E-10 -10.5029 0.26277E-10 -10.5804 0.83657E+00 -0.0775 37 CaCl2,aq 0.14456E-14 -14.8399 0.14456E-14 -14.8399 0.10000E+01 0.0000 38 CaF+ 0.26211E-12 -12.5815 0.21927E-12 -12.6590 0.83657E+00 -0.0775 39 CaOH+ 0.80211E-07 -7.0958 0.67102E-07 -7.1733 0.83657E+00 -0.0775 40 CaSO4,aq 0.16028E-16 -16.7951 0.16028E-16 -16.7951 0.10000E+01 0.0000 41 HCl,aq 0.31602E-14 -14.5003 0.31602E-14 -14.5003 0.10000E+01 0.0000 45 HF,aq 0.10920E-12 -12.9618 0.10920E-12 -12.9618 0.10000E+01 0.0000 48 FeCl+ 0.13201E-16 -16.8794 0.11043E-16 -16.9569 0.83657E+00 -0.0775 51 FeF+ 0.39419E-18 -18.4043 0.32977E-18 -18.4818 0.83657E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15741E-10 -10.8030 0.13169E-10 -10.8805 0.83657E+00 -0.0775 55 HFeO2- 0.35525E-07 -7.4495 0.29662E-07 -7.5278 0.83497E+00 -0.0783 56 FeO+ 0.11032E-16 -16.9573 0.92293E-17 -17.0348 0.83657E+00 -0.0775 58 FeO2- 0.40779E-09 -9.3896 0.34049E-09 -9.4679 0.83497E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55167E-09 -9.2583 0.55167E-09 -9.2583 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.17585E-14 -14.7549 0.14683E-14 -14.8332 0.83497E+00 -0.0783 65 MgCO3,aq 0.22471E-13 -13.6484 0.22471E-13 -13.6484 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.19006E-15 -15.7211 0.15900E-15 -15.7986 0.83657E+00 -0.0775 67 MgCl+ 0.44333E-14 -14.3533 0.37088E-14 -14.4308 0.83657E+00 -0.0775 68 MgF+ 0.15120E-15 -15.8204 0.12649E-15 -15.8979 0.83657E+00 -0.0775 69 MgOH+ 0.69119E-10 -10.1604 0.57823E-10 -10.2379 0.83657E+00 -0.0775 71 MnF+ 0.41716E-16 -16.3797 0.34899E-16 -16.4572 0.83657E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46950E-09 -9.3284 0.39277E-09 -9.4059 0.83657E+00 -0.0775 74 MnO2-2 0.20879E-10 -10.6803 0.10808E-10 -10.9663 0.51764E+00 -0.2860 75 HMnO2- 0.21119E-09 -9.6753 0.17634E-09 -9.7537 0.83497E+00 -0.0783 78 MnCl+ 0.16489E-13 -13.7828 0.13794E-13 -13.8603 0.83657E+00 -0.0775 80 NaCl,aq 0.12776E-05 -5.8936 0.12776E-05 -5.8936 0.10000E+01 0.0000 81 NaF,aq 0.83484E-09 -9.0784 0.83484E-09 -9.0784 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93084E-02 -2.0311 0.77581E-02 -2.1102 0.83345E+00 -0.0791 89 HPO3-2 0.16288E-14 -14.7881 0.84314E-15 -15.0741 0.51764E+00 -0.2860 91 H2PO3- 0.15080E-18 -18.8216 0.12592E-18 -18.8999 0.83497E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38398E-10 -10.4157 0.32091E-10 -10.4936 0.83576E+00 -0.0779 94 PO4-3 0.10571E-08 -8.9759 0.25591E-09 -9.5919 0.24209E+00 -0.6160 98 HP2O7-3 0.93851E-18 -18.0276 0.21650E-18 -18.6645 0.23069E+00 -0.6370 99 P2O7-4 0.90459E-17 -17.0435 0.69450E-18 -18.1583 0.76775E-01 -1.1148 100 H2S,aq 0.10570E-07 -7.9759 0.10534E-07 -7.9774 0.99652E+00 -0.0015 101 S2-2 0.77403E-14 -14.1112 0.40067E-14 -14.3972 0.51764E+00 -0.2860 107 SO3-2 0.20632E-17 -17.6855 0.10835E-17 -17.9652 0.52515E+00 -0.2797 109 HSO4- 0.61697E-19 -19.2097 0.51665E-19 -19.2868 0.83739E+00 -0.0771 Charge balance for all species = -.7379E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8865566E-10 -.2223121E-01 -.2236869E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981957E+06 0.0000 3 Cl- 0.2773376E-03 0.2786158E-03 0.9860560E+01 6.4927 4 SO4-- 0.1387676E-11 -.3750219E-04 -.3596244E+01 8.1132 5 HCO3- 0.6676272E-06 0.3652966E-04 0.2225055E+01 3.8748 6 HS- 0.5480199E-04 0.9231475E-04 0.3047715E+01 5.7885 7 Al+++ 0.9826231E-29 0.5297211E-05 0.1426777E+00 0.7390 8 H4SiO4 0.6959791E-03 0.1349648E-01 0.1294960E+04 -3.1574 9 Ca++ 0.1361733E-06 0.2336492E-06 0.9347881E-02 13.1018 10 Mg++ 0.2130364E-10 0.9367779E-10 0.2273527E-05 9.2942 11 Fe++ 0.5871646E-13 0.3616263E-07 0.2016056E-02 6.7350 12 K+ 0.1571582E-03 0.1579125E-03 0.6163939E+01 6.2467 13 Na+ 0.1994271E-01 0.2238967E-01 0.5138373E+03 8.3494 14 Mn++ 0.1883630E-10 0.2526623E-08 0.1385658E-03 9.2416 15 F- 0.2570544E-06 0.2578896E-06 0.4890852E-02 3.4588 16 HPO4-- 0.4502308E-07 0.4611855E-07 0.4418702E-02 12.6244 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279254E+02 -.1103416E-01 -.8278151E+02 0.0000000E+00 2 H2O -.7168731E+01 0.2754911E+02 -.3471784E+02 0.0000000E+00 3 Cl- 0.1382872E-03 0.1382872E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385929E+00 -.1861370E-04 0.1386115E+00 0.0000000E+00 5 HCO3- 0.1813100E-04 0.1813100E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385657E+00 0.4581917E-04 -.1386115E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629199E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6698796E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1159686E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4649570E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794883E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7837773E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111281E-01 0.6265264E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254055E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1280000E-06 0.1280000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2289032E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.8896E-14 Mass of aqueous solution: 0.497203E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5544 -0.256 281.8 2.450 5.158 73.20 grossular 0.1343 -0.872 60.47 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2626 -0.581 56.86 1.755 1.041 17.38 hedenbergite 0.6809E-01 -1.167 16.89 1.228 0.3093 4.627 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2614 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4253E-01 -1.371 36.35 1.560 0.6654 11.70 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337884 g Volume = 2210.778052 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000700 moles log = -4.1549 Original solution: 1000.0103000 g Original solution / Rock added: 14285861.43 (Water/Rock Ratio), log = 7.1549 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0865 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9399E+00 0.9851 0.1006E+01 0.1021E+01 CO2,gas 0.8691E-08 1.0065 0.9505E-08 0.9443E-08 CH4,gas 0.4615E-01 1.0121 0.5075E-01 0.5014E-01 H2,gas 0.1399E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2676E-06 0.9958 0.2896E-06 0.2908E-06 S2,gas 0.1253E-28 1.0000 0.1361E-28 0.1361E-28 CO,gas 0.3545E-13 1.0000 0.3852E-13 0.3852E-13 SO3,gas 0.1389E-47 1.0000 0.1510E-47 0.1510E-47 SO2,gas 0.8219E-27 1.0000 0.8931E-27 0.8931E-27 HF,gas 0.2468E-15 1.0000 0.2681E-15 0.2681E-15 HCl,gas 0.5132E-17 1.0000 0.5576E-17 0.5576E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.78860E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.72794E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.38 -9.72 -3.240 0.16598E+05 -8.022 3 CH4,gas 4.54 1.55 -2.99 -0.748 0.51114E+04 -1.295 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.47 -8.24 -4.119 0.14065E+05 -6.538 6 S2,gas -7.34 -37.90 -30.57 -4.702 0.52189E+05 -28.866 7 CO,gas 3.21 -11.90 -15.11 -4.650 0.25806E+05 -13.414 8 SO3,gas 17.12 -32.40 -49.52 -12.380 0.84554E+05 -47.821 9 SO2,gas 0.83 -27.92 -28.75 -7.666 0.49087E+05 -27.049 10 HF,gas 0.47 -16.80 -17.27 -8.635 0.29489E+05 -15.572 11 HCl,gas 5.19 -13.76 -18.95 -9.476 0.32361E+05 -17.254 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.95 -0.65 -0.054 0.11094E+04 38 aragonite 0.97 -3.28 -4.25 -1.415 0.72497E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.28 -4.09 -1.364 0.69854E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.42 -4.31 -1.232 0.73645E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.42 -3.87 -1.106 0.66068E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.73 -3.47 -1.157 0.59286E+04 147 pyrrhotiteFe0.875 -6.02 -9.13 -3.11 -1.145 0.53158E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.73 -3.32 -1.107 0.56714E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.23 -4.25 -1.416 0.72534E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000700 MOLES New total amount of reactant added: 0.0000800 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3664E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000800 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142698E-01 Osmotic coef. = 0.9721 True ionic strength = .2010214E-01 Chg. balance for total moles = -.3664E-10 Max. difference allowed = 0.1383E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88657E-10 -10.0523 0.74475E-10 -10.1280 0.84003E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27746E-03 -3.5568 0.23167E-03 -3.6351 0.83496E+00 -0.0783 4 SO4-- 0.14001E-11 -11.8539 0.72626E-12 -12.1389 0.51874E+00 -0.2850 5 HCO3- 0.69424E-06 -6.1585 0.58052E-06 -6.2362 0.83619E+00 -0.0777 6 HS- 0.55291E-04 -4.2573 0.46173E-04 -4.3356 0.83509E+00 -0.0783 7 Al+++ 0.98269E-29 -29.0076 0.22647E-29 -29.6450 0.23046E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13618E-06 -6.8659 0.70121E-07 -7.1541 0.51492E+00 -0.2883 10 Mg++ 0.21305E-10 -10.6715 0.10920E-10 -10.9618 0.51256E+00 -0.2903 11 Fe++ 0.58719E-13 -13.2312 0.30130E-13 -13.5210 0.51312E+00 -0.2898 12 K+ 0.15716E-03 -3.8037 0.13145E-03 -3.8812 0.83639E+00 -0.0776 13 Na+ 0.19943E-01 -1.7002 0.16649E-01 -1.7786 0.83481E+00 -0.0784 14 Mn++ 0.18837E-10 -10.7250 0.96738E-11 -11.0144 0.51355E+00 -0.2894 15 F- 0.26509E-06 -6.5766 0.22088E-06 -6.6558 0.83324E+00 -0.0792 16 HPO4-- 0.45022E-07 -7.3466 0.23358E-07 -7.6316 0.51881E+00 -0.2850 18 HSiO3- 0.10451E-01 -1.9809 0.87259E-02 -2.0592 0.83496E+00 -0.0783 19 Ca(HSiO3)+ 0.16657E-07 -7.7784 0.13935E-07 -7.8559 0.83657E+00 -0.0775 20 Mg(HSiO3)+ 0.32282E-11 -11.4910 0.27006E-11 -11.5685 0.83657E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66398E-16 -16.1778 0.55547E-16 -16.2553 0.83657E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52970E-05 -5.2760 0.44148E-05 -5.3551 0.83345E+00 -0.0791 26 CH4,aq 0.35976E-04 -4.4440 0.35851E-04 -4.4455 0.99652E+00 -0.0015 27 C2H6,aq 0.19037E-13 -13.7204 0.18970E-13 -13.7219 0.99652E+00 -0.0015 31 CO,aq 0.26879E-16 -16.5706 0.26879E-16 -16.5706 0.10000E+01 0.0000 32 CO2,aq 0.92704E-10 -10.0329 0.92381E-10 -10.0344 0.99652E+00 -0.0015 33 CO3-2 0.13153E-05 -5.8810 0.68084E-06 -6.1670 0.51764E+00 -0.2860 34 CaCO3,aq 0.59863E-09 -9.2228 0.59863E-09 -9.2228 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.12421E-11 -11.9059 0.10391E-11 -11.9834 0.83657E+00 -0.0775 36 CaCl+ 0.31425E-10 -10.5027 0.26289E-10 -10.5802 0.83657E+00 -0.0775 37 CaCl2,aq 0.14469E-14 -14.8396 0.14469E-14 -14.8396 0.10000E+01 0.0000 38 CaF+ 0.27031E-12 -12.5681 0.22613E-12 -12.6456 0.83657E+00 -0.0775 39 CaOH+ 0.80212E-07 -7.0958 0.67103E-07 -7.1733 0.83657E+00 -0.0775 40 CaSO4,aq 0.16172E-16 -16.7912 0.16172E-16 -16.7912 0.10000E+01 0.0000 41 HCl,aq 0.31616E-14 -14.5001 0.31616E-14 -14.5001 0.10000E+01 0.0000 45 HF,aq 0.11261E-12 -12.9484 0.11261E-12 -12.9484 0.10000E+01 0.0000 46 HF2- 0.10058E-19 -19.9975 0.83981E-20 -20.0758 0.83496E+00 -0.0783 48 FeCl+ 0.13207E-16 -16.8792 0.11048E-16 -16.9567 0.83657E+00 -0.0775 51 FeF+ 0.40653E-18 -18.3909 0.34009E-18 -18.4684 0.83657E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15742E-10 -10.8029 0.13169E-10 -10.8804 0.83657E+00 -0.0775 55 HFeO2- 0.35524E-07 -7.4495 0.29661E-07 -7.5278 0.83496E+00 -0.0783 56 FeO+ 0.11032E-16 -16.9573 0.92294E-17 -17.0348 0.83657E+00 -0.0775 58 FeO2- 0.40779E-09 -9.3896 0.34049E-09 -9.4679 0.83496E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55192E-09 -9.2581 0.55192E-09 -9.2581 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.17742E-14 -14.7510 0.14814E-14 -14.8293 0.83496E+00 -0.0783 65 MgCO3,aq 0.23367E-13 -13.6314 0.23367E-13 -13.6314 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.19764E-15 -15.7041 0.16534E-15 -15.7816 0.83657E+00 -0.0775 67 MgCl+ 0.44354E-14 -14.3531 0.37105E-14 -14.4306 0.83657E+00 -0.0775 68 MgF+ 0.15593E-15 -15.8071 0.13045E-15 -15.8846 0.83657E+00 -0.0775 69 MgOH+ 0.69120E-10 -10.1604 0.57824E-10 -10.2379 0.83657E+00 -0.0775 71 MnF+ 0.43022E-16 -16.3663 0.35991E-16 -16.4438 0.83657E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46951E-09 -9.3284 0.39278E-09 -9.4059 0.83657E+00 -0.0775 74 MnO2-2 0.20878E-10 -10.6803 0.10807E-10 -10.9663 0.51764E+00 -0.2860 75 HMnO2- 0.21119E-09 -9.6753 0.17633E-09 -9.7537 0.83496E+00 -0.0783 78 MnCl+ 0.16496E-13 -13.7826 0.13800E-13 -13.8601 0.83657E+00 -0.0775 80 NaCl,aq 0.12782E-05 -5.8934 0.12782E-05 -5.8934 0.10000E+01 0.0000 81 NaF,aq 0.86094E-09 -9.0650 0.86094E-09 -9.0650 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93082E-02 -2.0311 0.77579E-02 -2.1103 0.83345E+00 -0.0791 89 HPO3-2 0.16288E-14 -14.7881 0.84311E-15 -15.0741 0.51764E+00 -0.2860 91 H2PO3- 0.15080E-18 -18.8216 0.12591E-18 -18.8999 0.83496E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38397E-10 -10.4157 0.32091E-10 -10.4936 0.83576E+00 -0.0779 94 PO4-3 0.10570E-08 -8.9759 0.25589E-09 -9.5919 0.24208E+00 -0.6160 98 HP2O7-3 0.93847E-18 -18.0276 0.21649E-18 -18.6646 0.23069E+00 -0.6370 99 P2O7-4 0.90454E-17 -17.0436 0.69445E-18 -18.1584 0.76773E-01 -1.1148 100 H2S,aq 0.10665E-07 -7.9720 0.10628E-07 -7.9736 0.99652E+00 -0.0015 101 S2-2 0.78792E-14 -14.1035 0.40786E-14 -14.3895 0.51764E+00 -0.2860 107 SO3-2 0.20816E-17 -17.6816 0.10931E-17 -17.9613 0.52515E+00 -0.2797 109 HSO4- 0.62248E-19 -19.2059 0.52126E-19 -19.2829 0.83739E+00 -0.0771 Charge balance for all species = -.7375E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8865745E-10 -.2223092E-01 -.2236840E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981957E+06 0.0000 3 Cl- 0.2774558E-03 0.2787346E-03 0.9864763E+01 6.4929 4 SO4-- 0.1400050E-11 -.3888181E-04 -.3728542E+01 8.1171 5 HCO3- 0.6942388E-06 0.3798632E-04 0.2313781E+01 3.8918 6 HS- 0.5529146E-04 0.9418394E-04 0.3109425E+01 5.7924 7 Al+++ 0.9826915E-29 0.5297121E-05 0.1426753E+00 0.7390 8 H4SiO4 0.6959791E-03 0.1349630E-01 0.1294943E+04 -3.1574 9 Ca++ 0.1361792E-06 0.2336801E-06 0.9349116E-02 13.1018 10 Mg++ 0.2130457E-10 0.9368044E-10 0.2273591E-05 9.2942 11 Fe++ 0.5871901E-13 0.3616202E-07 0.2016022E-02 6.7350 12 K+ 0.1571614E-03 0.1579157E-03 0.6164062E+01 6.2467 13 Na+ 0.1994311E-01 0.2239007E-01 0.5138465E+03 8.3494 14 Mn++ 0.1883714E-10 0.2526631E-08 0.1385663E-03 9.2416 15 F- 0.2650872E-06 0.2659486E-06 0.5043689E-02 3.4721 16 HPO4-- 0.4502166E-07 0.4611710E-07 0.4418562E-02 12.6244 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279254E+02 -.1103402E-01 -.8278150E+02 0.0000000E+00 2 H2O -.7168723E+01 0.2754912E+02 -.3471784E+02 0.0000000E+00 3 Cl- 0.1383462E-03 0.1383462E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385929E+00 -.1929846E-04 0.1386122E+00 0.0000000E+00 5 HCO3- 0.1885400E-04 0.1885400E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385655E+00 0.4674693E-04 -.1386122E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629155E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6698710E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1159840E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4649703E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794853E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7837933E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111301E-01 0.6265264E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254060E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1320000E-06 0.1320000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288960E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.5516E-14 Mass of aqueous solution: 0.497203E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000800 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5544 -0.256 281.8 2.450 5.158 73.20 grossular 0.1343 -0.872 60.47 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2625 -0.581 56.86 1.755 1.041 17.38 hedenbergite 0.6809E-01 -1.167 16.89 1.228 0.3092 4.627 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4253E-01 -1.371 36.35 1.561 0.6655 11.70 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337888 g Volume = 2210.778079 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000800 moles log = -4.0969 Original solution: 1000.0103000 g Original solution / Rock added: 12500128.75 (Water/Rock Ratio), log = 7.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0886 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9381E+00 0.9850 0.1006E+01 0.1021E+01 CO2,gas 0.9021E-08 1.0065 0.9884E-08 0.9820E-08 CH4,gas 0.4790E-01 1.0120 0.5277E-01 0.5214E-01 H2,gas 0.1396E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2695E-06 0.9958 0.2922E-06 0.2934E-06 S2,gas 0.1273E-28 1.0000 0.1386E-28 0.1386E-28 CO,gas 0.3680E-13 1.0000 0.4006E-13 0.4006E-13 SO3,gas 0.1399E-47 1.0000 0.1523E-47 0.1523E-47 SO2,gas 0.8278E-27 1.0000 0.9011E-27 0.9011E-27 HF,gas 0.2540E-15 1.0000 0.2765E-15 0.2765E-15 HCl,gas 0.5125E-17 1.0000 0.5579E-17 0.5579E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.36 -9.70 -3.235 0.16569E+05 -8.005 3 CH4,gas 4.54 1.57 -2.98 -0.744 0.50824E+04 -1.278 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.46 -8.23 -4.117 0.14058E+05 -6.534 6 S2,gas -7.34 -37.89 -30.56 -4.701 0.52176E+05 -28.858 7 CO,gas 3.21 -11.88 -15.10 -4.645 0.25777E+05 -13.397 8 SO3,gas 17.12 -32.39 -49.52 -12.379 0.84548E+05 -47.817 9 SO2,gas 0.83 -27.91 -28.74 -7.665 0.49080E+05 -27.045 10 HF,gas 0.47 -16.78 -17.26 -8.629 0.29466E+05 -15.558 11 HCl,gas 5.19 -13.76 -18.95 -9.476 0.32361E+05 -17.253 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.94 -0.64 -0.053 0.10865E+04 38 aragonite 0.97 -3.26 -4.23 -1.410 0.72207E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.26 -4.07 -1.358 0.69565E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.40 -4.30 -1.227 0.73355E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.40 -3.85 -1.101 0.65778E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.73 -3.47 -1.156 0.59220E+04 147 pyrrhotiteFe0.875 -6.02 -9.13 -3.11 -1.144 0.53092E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.73 -3.32 -1.106 0.56648E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.22 -4.24 -1.415 0.72468E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000800 MOLES New total amount of reactant added: 0.0000900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0000900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142615E-01 Osmotic coef. = 0.9726 True ionic strength = .2010259E-01 Chg. balance for total moles = -.3665E-10 Max. difference allowed = 0.1384E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88659E-10 -10.0523 0.74476E-10 -10.1280 0.84003E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27757E-03 -3.5566 0.23176E-03 -3.6350 0.83496E+00 -0.0783 4 SO4-- 0.14124E-11 -11.8500 0.73268E-12 -12.1351 0.51874E+00 -0.2851 5 HCO3- 0.72085E-06 -6.1422 0.60277E-06 -6.2199 0.83619E+00 -0.0777 6 HS- 0.55781E-04 -4.2535 0.46582E-04 -4.3318 0.83509E+00 -0.0783 7 Al+++ 0.98276E-29 -29.0076 0.22648E-29 -29.6450 0.23045E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13619E-06 -6.8659 0.70124E-07 -7.1541 0.51492E+00 -0.2883 10 Mg++ 0.21305E-10 -10.6715 0.10920E-10 -10.9618 0.51255E+00 -0.2903 11 Fe++ 0.58722E-13 -13.2312 0.30131E-13 -13.5210 0.51312E+00 -0.2898 12 K+ 0.15716E-03 -3.8036 0.13145E-03 -3.8812 0.83639E+00 -0.0776 13 Na+ 0.19944E-01 -1.7002 0.16649E-01 -1.7786 0.83481E+00 -0.0784 14 Mn++ 0.18838E-10 -10.7250 0.96741E-11 -11.0144 0.51354E+00 -0.2894 15 F- 0.27312E-06 -6.5636 0.22757E-06 -6.6429 0.83324E+00 -0.0792 16 HPO4-- 0.45020E-07 -7.3466 0.23357E-07 -7.6316 0.51881E+00 -0.2850 18 HSiO3- 0.10450E-01 -1.9809 0.87258E-02 -2.0592 0.83496E+00 -0.0783 19 Ca(HSiO3)+ 0.16657E-07 -7.7784 0.13935E-07 -7.8559 0.83657E+00 -0.0775 20 Mg(HSiO3)+ 0.32283E-11 -11.4910 0.27007E-11 -11.5685 0.83657E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66400E-16 -16.1778 0.55548E-16 -16.2553 0.83657E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52969E-05 -5.2760 0.44147E-05 -5.3551 0.83345E+00 -0.0791 26 CH4,aq 0.37356E-04 -4.4276 0.37226E-04 -4.4292 0.99652E+00 -0.0015 27 C2H6,aq 0.20525E-13 -13.6877 0.20453E-13 -13.6892 0.99652E+00 -0.0015 31 CO,aq 0.27910E-16 -16.5542 0.27910E-16 -16.5542 0.10000E+01 0.0000 32 CO2,aq 0.96259E-10 -10.0166 0.95923E-10 -10.0181 0.99652E+00 -0.0015 33 CO3-2 0.13657E-05 -5.8646 0.70692E-06 -6.1506 0.51763E+00 -0.2860 34 CaCO3,aq 0.62158E-09 -9.2065 0.62158E-09 -9.2065 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.12897E-11 -11.8895 0.10789E-11 -11.9670 0.83657E+00 -0.0775 36 CaCl+ 0.31439E-10 -10.5025 0.26301E-10 -10.5800 0.83657E+00 -0.0775 37 CaCl2,aq 0.14482E-14 -14.8392 0.14482E-14 -14.8392 0.10000E+01 0.0000 38 CaF+ 0.27851E-12 -12.5552 0.23299E-12 -12.6327 0.83657E+00 -0.0775 39 CaOH+ 0.80214E-07 -7.0957 0.67104E-07 -7.1732 0.83657E+00 -0.0775 40 CaSO4,aq 0.16315E-16 -16.7874 0.16315E-16 -16.7874 0.10000E+01 0.0000 41 HCl,aq 0.31630E-14 -14.4999 0.31630E-14 -14.4999 0.10000E+01 0.0000 45 HF,aq 0.11603E-12 -12.9354 0.11603E-12 -12.9354 0.10000E+01 0.0000 46 HF2- 0.10677E-19 -19.9716 0.89149E-20 -20.0499 0.83496E+00 -0.0783 48 FeCl+ 0.13213E-16 -16.8790 0.11053E-16 -16.9565 0.83657E+00 -0.0775 51 FeF+ 0.41886E-18 -18.3779 0.35041E-18 -18.4554 0.83657E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15742E-10 -10.8029 0.13169E-10 -10.8804 0.83657E+00 -0.0775 55 HFeO2- 0.35523E-07 -7.4495 0.29661E-07 -7.5278 0.83496E+00 -0.0783 56 FeO+ 0.11033E-16 -16.9573 0.92296E-17 -17.0348 0.83657E+00 -0.0775 58 FeO2- 0.40778E-09 -9.3896 0.34048E-09 -9.4679 0.83496E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55216E-09 -9.2579 0.55216E-09 -9.2579 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.17899E-14 -14.7472 0.14945E-14 -14.8255 0.83496E+00 -0.0783 65 MgCO3,aq 0.24263E-13 -13.6151 0.24263E-13 -13.6151 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.20523E-15 -15.6878 0.17169E-15 -15.7653 0.83657E+00 -0.0775 67 MgCl+ 0.44374E-14 -14.3529 0.37122E-14 -14.4304 0.83657E+00 -0.0775 68 MgF+ 0.16066E-15 -15.7941 0.13441E-15 -15.8716 0.83657E+00 -0.0775 69 MgOH+ 0.69122E-10 -10.1604 0.57825E-10 -10.2379 0.83657E+00 -0.0775 71 MnF+ 0.44327E-16 -16.3533 0.37082E-16 -16.4308 0.83657E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46952E-09 -9.3283 0.39279E-09 -9.4058 0.83657E+00 -0.0775 74 MnO2-2 0.20877E-10 -10.6803 0.10807E-10 -10.9663 0.51763E+00 -0.2860 75 HMnO2- 0.21118E-09 -9.6753 0.17633E-09 -9.7537 0.83496E+00 -0.0783 78 MnCl+ 0.16504E-13 -13.7824 0.13807E-13 -13.8599 0.83657E+00 -0.0775 80 NaCl,aq 0.12788E-05 -5.8932 0.12788E-05 -5.8932 0.10000E+01 0.0000 81 NaF,aq 0.88705E-09 -9.0521 0.88705E-09 -9.0521 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93080E-02 -2.0311 0.77578E-02 -2.1103 0.83345E+00 -0.0791 89 HPO3-2 0.16287E-14 -14.7882 0.84308E-15 -15.0741 0.51763E+00 -0.2860 91 H2PO3- 0.15080E-18 -18.8216 0.12591E-18 -18.8999 0.83496E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38396E-10 -10.4157 0.32090E-10 -10.4936 0.83576E+00 -0.0779 94 PO4-3 0.10570E-08 -8.9759 0.25588E-09 -9.5920 0.24208E+00 -0.6160 98 HP2O7-3 0.93843E-18 -18.0276 0.21648E-18 -18.6646 0.23068E+00 -0.6370 99 P2O7-4 0.90450E-17 -17.0436 0.69440E-18 -18.1584 0.76772E-01 -1.1148 100 H2S,aq 0.10760E-07 -7.9682 0.10722E-07 -7.9697 0.99652E+00 -0.0015 101 S2-2 0.80193E-14 -14.0959 0.41511E-14 -14.3818 0.51763E+00 -0.2860 107 SO3-2 0.21000E-17 -17.6778 0.11028E-17 -17.9575 0.52514E+00 -0.2797 109 HSO4- 0.62800E-19 -19.2020 0.52587E-19 -19.2791 0.83738E+00 -0.0771 Charge balance for all species = -.7379E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8865923E-10 -.2223064E-01 -.2236811E+02 0.0000 2 H2O 0.1000000E+01 0.5550491E+02 0.9981957E+06 0.0000 3 Cl- 0.2775740E-03 0.2788534E-03 0.9868966E+01 6.4930 4 SO4-- 0.1412424E-11 -.4026143E-04 -.3860840E+01 8.1209 5 HCO3- 0.7208495E-06 0.3944298E-04 0.2402507E+01 3.9081 6 HS- 0.5578094E-04 0.9605313E-04 0.3171135E+01 5.7962 7 Al+++ 0.9827599E-29 0.5297031E-05 0.1426728E+00 0.7390 8 H4SiO4 0.6959791E-03 0.1349613E-01 0.1294926E+04 -3.1574 9 Ca++ 0.1361851E-06 0.2337110E-06 0.9350352E-02 13.1018 10 Mg++ 0.2130550E-10 0.9368309E-10 0.2273655E-05 9.2942 11 Fe++ 0.5872156E-13 0.3616140E-07 0.2015988E-02 6.7350 12 K+ 0.1571645E-03 0.1579188E-03 0.6164185E+01 6.2467 13 Na+ 0.1994351E-01 0.2239047E-01 0.5138557E+03 8.3494 14 Mn++ 0.1883797E-10 0.2526640E-08 0.1385667E-03 9.2416 15 F- 0.2731201E-06 0.2740075E-06 0.5196526E-02 3.4851 16 HPO4-- 0.4502025E-07 0.4611564E-07 0.4418422E-02 12.6244 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279254E+02 -.1103388E-01 -.8278150E+02 0.0000000E+00 2 H2O -.7168715E+01 0.2754913E+02 -.3471784E+02 0.0000000E+00 3 Cl- 0.1384052E-03 0.1384052E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385930E+00 -.1998323E-04 0.1386129E+00 0.0000000E+00 5 HCO3- 0.1957700E-04 0.1957700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385653E+00 0.4767470E-04 -.1386129E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629111E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6698623E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1159994E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4649836E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794823E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7838092E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111322E-01 0.6265264E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254064E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1360000E-06 0.1360000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288889E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.4857E-15 Mass of aqueous solution: 0.497203E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0000900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.158 73.20 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2625 -0.581 56.85 1.755 1.041 17.38 hedenbergite 0.6808E-01 -1.167 16.89 1.228 0.3092 4.626 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4254E-01 -1.371 36.36 1.561 0.6656 11.70 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337891 g Volume = 2210.778107 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0000900 moles log = -4.0458 Original solution: 1000.0103000 g Original solution / Rock added: 11111225.56 (Water/Rock Ratio), log = 7.0458 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0906 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9364E+00 0.9850 0.1006E+01 0.1021E+01 CO2,gas 0.9350E-08 1.0064 0.1026E-07 0.1020E-07 CH4,gas 0.4965E-01 1.0120 0.5479E-01 0.5414E-01 H2,gas 0.1394E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2714E-06 0.9958 0.2947E-06 0.2960E-06 S2,gas 0.1293E-28 1.0000 0.1410E-28 0.1410E-28 CO,gas 0.3814E-13 1.0000 0.4159E-13 0.4159E-13 SO3,gas 0.1409E-47 1.0000 0.1537E-47 0.1537E-47 SO2,gas 0.8335E-27 1.0000 0.9091E-27 0.9091E-27 HF,gas 0.2612E-15 1.0000 0.2849E-15 0.2849E-15 HCl,gas 0.5118E-17 1.0000 0.5581E-17 0.5581E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.35 -9.69 -3.229 0.16541E+05 -7.989 3 CH4,gas 4.54 1.58 -2.96 -0.740 0.50545E+04 -1.261 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.46 -8.23 -4.115 0.14052E+05 -6.531 6 S2,gas -7.34 -37.89 -30.55 -4.700 0.52163E+05 -28.851 7 CO,gas 3.21 -11.87 -15.08 -4.640 0.25749E+05 -13.381 8 SO3,gas 17.12 -32.39 -49.51 -12.378 0.84541E+05 -47.813 9 SO2,gas 0.83 -27.91 -28.74 -7.664 0.49073E+05 -27.041 10 HF,gas 0.47 -16.77 -17.24 -8.622 0.29444E+05 -15.545 11 HCl,gas 5.19 -13.76 -18.95 -9.476 0.32360E+05 -17.253 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.92 -0.62 -0.052 0.10644E+04 38 aragonite 0.97 -3.25 -4.21 -1.404 0.71928E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.25 -4.06 -1.353 0.69285E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.38 -4.28 -1.223 0.73076E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.38 -3.84 -1.096 0.65499E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.72 -3.46 -1.155 0.59155E+04 147 pyrrhotiteFe0.875 -6.02 -9.12 -3.11 -1.142 0.53027E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.72 -3.31 -1.105 0.56583E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.22 -4.24 -1.413 0.72402E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0000900 MOLES New total amount of reactant added: 0.0001000 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001000 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142531E-01 Osmotic coef. = 0.9731 True ionic strength = .2010305E-01 Chg. balance for total moles = -.3665E-10 Max. difference allowed = 0.1385E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88661E-10 -10.0523 0.74478E-10 -10.1280 0.84003E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27769E-03 -3.5564 0.23186E-03 -3.6348 0.83496E+00 -0.0783 4 SO4-- 0.14248E-11 -11.8462 0.73909E-12 -12.1313 0.51873E+00 -0.2851 5 HCO3- 0.74746E-06 -6.1264 0.62502E-06 -6.2041 0.83619E+00 -0.0777 6 HS- 0.56270E-04 -4.2497 0.46991E-04 -4.3280 0.83508E+00 -0.0783 7 Al+++ 0.98283E-29 -29.0075 0.22649E-29 -29.6449 0.23045E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13619E-06 -6.8659 0.70127E-07 -7.1541 0.51491E+00 -0.2883 10 Mg++ 0.21306E-10 -10.6715 0.10921E-10 -10.9618 0.51255E+00 -0.2903 11 Fe++ 0.58724E-13 -13.2312 0.30132E-13 -13.5210 0.51311E+00 -0.2898 12 K+ 0.15717E-03 -3.8036 0.13145E-03 -3.8812 0.83639E+00 -0.0776 13 Na+ 0.19944E-01 -1.7002 0.16649E-01 -1.7786 0.83481E+00 -0.0784 14 Mn++ 0.18839E-10 -10.7249 0.96745E-11 -11.0144 0.51354E+00 -0.2894 15 F- 0.28115E-06 -6.5511 0.23427E-06 -6.6303 0.83324E+00 -0.0792 16 HPO4-- 0.45019E-07 -7.3466 0.23356E-07 -7.6316 0.51881E+00 -0.2850 18 HSiO3- 0.10450E-01 -1.9809 0.87256E-02 -2.0592 0.83496E+00 -0.0783 19 Ca(HSiO3)+ 0.16658E-07 -7.7784 0.13935E-07 -7.8559 0.83657E+00 -0.0775 20 Mg(HSiO3)+ 0.32283E-11 -11.4910 0.27007E-11 -11.5685 0.83657E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66401E-16 -16.1778 0.55549E-16 -16.2553 0.83657E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52968E-05 -5.2760 0.44146E-05 -5.3551 0.83345E+00 -0.0791 26 CH4,aq 0.38735E-04 -4.4119 0.38600E-04 -4.4134 0.99652E+00 -0.0015 27 C2H6,aq 0.22069E-13 -13.6562 0.21992E-13 -13.6577 0.99652E+00 -0.0015 31 CO,aq 0.28941E-16 -16.5385 0.28941E-16 -16.5385 0.10000E+01 0.0000 32 CO2,aq 0.99814E-10 -10.0008 0.99466E-10 -10.0023 0.99652E+00 -0.0015 33 CO3-2 0.14161E-05 -5.8489 0.73301E-06 -6.1349 0.51763E+00 -0.2860 34 CaCO3,aq 0.64454E-09 -9.1908 0.64454E-09 -9.1908 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.13374E-11 -11.8737 0.11188E-11 -11.9512 0.83657E+00 -0.0775 36 CaCl+ 0.31454E-10 -10.5023 0.26313E-10 -10.5798 0.83657E+00 -0.0775 37 CaCl2,aq 0.14495E-14 -14.8388 0.14495E-14 -14.8388 0.10000E+01 0.0000 38 CaF+ 0.28671E-12 -12.5426 0.23986E-12 -12.6201 0.83657E+00 -0.0775 39 CaOH+ 0.80216E-07 -7.0957 0.67106E-07 -7.1732 0.83657E+00 -0.0775 40 CaSO4,aq 0.16458E-16 -16.7836 0.16458E-16 -16.7836 0.10000E+01 0.0000 41 HCl,aq 0.31644E-14 -14.4997 0.31644E-14 -14.4997 0.10000E+01 0.0000 45 HF,aq 0.11944E-12 -12.9228 0.11944E-12 -12.9228 0.10000E+01 0.0000 46 HF2- 0.11314E-19 -19.9464 0.94472E-20 -20.0247 0.83496E+00 -0.0783 48 FeCl+ 0.13219E-16 -16.8788 0.11058E-16 -16.9563 0.83657E+00 -0.0775 51 FeF+ 0.43120E-18 -18.3653 0.36072E-18 -18.4428 0.83657E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15742E-10 -10.8029 0.13169E-10 -10.8804 0.83657E+00 -0.0775 55 HFeO2- 0.35523E-07 -7.4495 0.29660E-07 -7.5278 0.83496E+00 -0.0783 56 FeO+ 0.11033E-16 -16.9573 0.92298E-17 -17.0348 0.83657E+00 -0.0775 58 FeO2- 0.40777E-09 -9.3896 0.34048E-09 -9.4679 0.83496E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55241E-09 -9.2577 0.55241E-09 -9.2577 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.18056E-14 -14.7434 0.15076E-14 -14.8217 0.83496E+00 -0.0783 65 MgCO3,aq 0.25159E-13 -13.5993 0.25159E-13 -13.5993 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.21281E-15 -15.6720 0.17803E-15 -15.7495 0.83657E+00 -0.0775 67 MgCl+ 0.44395E-14 -14.3527 0.37139E-14 -14.4302 0.83657E+00 -0.0775 68 MgF+ 0.16539E-15 -15.7815 0.13836E-15 -15.8590 0.83657E+00 -0.0775 69 MgOH+ 0.69123E-10 -10.1604 0.57826E-10 -10.2379 0.83657E+00 -0.0775 71 MnF+ 0.45632E-16 -16.3407 0.38175E-16 -16.4182 0.83657E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46953E-09 -9.3283 0.39280E-09 -9.4058 0.83657E+00 -0.0775 74 MnO2-2 0.20877E-10 -10.6803 0.10806E-10 -10.9663 0.51763E+00 -0.2860 75 HMnO2- 0.21118E-09 -9.6753 0.17633E-09 -9.7537 0.83496E+00 -0.0783 78 MnCl+ 0.16512E-13 -13.7822 0.13813E-13 -13.8597 0.83657E+00 -0.0775 80 NaCl,aq 0.12793E-05 -5.8930 0.12793E-05 -5.8930 0.10000E+01 0.0000 81 NaF,aq 0.91315E-09 -9.0395 0.91315E-09 -9.0395 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93079E-02 -2.0311 0.77577E-02 -2.1103 0.83345E+00 -0.0791 89 HPO3-2 0.16287E-14 -14.7882 0.84304E-15 -15.0741 0.51763E+00 -0.2860 91 H2PO3- 0.15080E-18 -18.8216 0.12591E-18 -18.8999 0.83496E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38396E-10 -10.4157 0.32089E-10 -10.4936 0.83576E+00 -0.0779 94 PO4-3 0.10569E-08 -8.9759 0.25586E-09 -9.5920 0.24208E+00 -0.6160 98 HP2O7-3 0.93839E-18 -18.0276 0.21647E-18 -18.6646 0.23068E+00 -0.6370 99 P2O7-4 0.90445E-17 -17.0436 0.69435E-18 -18.1584 0.76770E-01 -1.1148 100 H2S,aq 0.10854E-07 -7.9644 0.10816E-07 -7.9659 0.99652E+00 -0.0015 101 S2-2 0.81607E-14 -14.0883 0.42242E-14 -14.3743 0.51763E+00 -0.2860 107 SO3-2 0.21184E-17 -17.6740 0.11124E-17 -17.9537 0.52514E+00 -0.2797 109 HSO4- 0.63351E-19 -19.1982 0.53049E-19 -19.2753 0.83738E+00 -0.0771 Charge balance for all species = -.7380E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8866101E-10 -.2223035E-01 -.2236782E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981957E+06 0.0000 3 Cl- 0.2776922E-03 0.2789721E-03 0.9873169E+01 6.4932 4 SO4-- 0.1424798E-11 -.4164106E-04 -.3993138E+01 8.1246 5 HCO3- 0.7474594E-06 0.4089964E-04 0.2491234E+01 3.9239 6 HS- 0.5627041E-04 0.9792232E-04 0.3232845E+01 5.8000 7 Al+++ 0.9828283E-29 0.5296940E-05 0.1426704E+00 0.7390 8 H4SiO4 0.6959791E-03 0.1349595E-01 0.1294908E+04 -3.1574 9 Ca++ 0.1361910E-06 0.2337419E-06 0.9351587E-02 13.1018 10 Mg++ 0.2130642E-10 0.9368753E-10 0.2273763E-05 9.2942 11 Fe++ 0.5872412E-13 0.3616078E-07 0.2015953E-02 6.7350 12 K+ 0.1571677E-03 0.1579220E-03 0.6164308E+01 6.2467 13 Na+ 0.1994391E-01 0.2239088E-01 0.5138650E+03 8.3494 14 Mn++ 0.1883881E-10 0.2526648E-08 0.1385672E-03 9.2416 15 F- 0.2811529E-06 0.2820665E-06 0.5349363E-02 3.4977 16 HPO4-- 0.4501884E-07 0.4611418E-07 0.4418282E-02 12.6243 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279254E+02 -.1103374E-01 -.8278150E+02 0.0000000E+00 2 H2O -.7168707E+01 0.2754914E+02 -.3471785E+02 0.0000000E+00 3 Cl- 0.1384642E-03 0.1384642E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385930E+00 -.2066799E-04 0.1386137E+00 0.0000000E+00 5 HCO3- 0.2030000E-04 0.2030000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385651E+00 0.4860246E-04 -.1386137E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629067E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6698537E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1160147E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4650058E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794793E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7838252E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111342E-01 0.6265264E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254069E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1400000E-06 0.1400000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288817E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1174E-13 Mass of aqueous solution: 0.497203E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.158 73.20 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2625 -0.581 56.85 1.755 1.041 17.37 hedenbergite 0.6808E-01 -1.167 16.89 1.228 0.3092 4.626 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4254E-01 -1.371 36.36 1.561 0.6657 11.70 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337894 g Volume = 2210.778135 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001000 moles log = -4.0000 Original solution: 1000.0103000 g Original solution / Rock added: 10000103.00 (Water/Rock Ratio), log = 7.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0926 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9347E+00 0.9850 0.1006E+01 0.1021E+01 CO2,gas 0.9678E-08 1.0064 0.1064E-07 0.1057E-07 CH4,gas 0.5139E-01 1.0120 0.5682E-01 0.5614E-01 H2,gas 0.1391E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2733E-06 0.9958 0.2973E-06 0.2986E-06 S2,gas 0.1313E-28 1.0000 0.1435E-28 0.1435E-28 CO,gas 0.3947E-13 1.0000 0.4313E-13 0.4313E-13 SO3,gas 0.1419E-47 1.0000 0.1550E-47 0.1550E-47 SO2,gas 0.8393E-27 1.0000 0.9171E-27 0.9171E-27 HF,gas 0.2684E-15 1.0000 0.2933E-15 0.2933E-15 HCl,gas 0.5110E-17 1.0000 0.5584E-17 0.5584E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.33 -9.67 -3.224 0.16515E+05 -7.973 3 CH4,gas 4.54 1.60 -2.94 -0.736 0.50276E+04 -1.246 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.46 -8.23 -4.113 0.14045E+05 -6.527 6 S2,gas -7.34 -37.88 -30.54 -4.699 0.52150E+05 -28.843 7 CO,gas 3.21 -11.85 -15.06 -4.635 0.25722E+05 -13.365 8 SO3,gas 17.12 -32.39 -49.51 -12.377 0.84535E+05 -47.810 9 SO2,gas 0.83 -27.90 -28.74 -7.663 0.49067E+05 -27.038 10 HF,gas 0.47 -16.76 -17.23 -8.616 0.29423E+05 -15.533 11 HCl,gas 5.19 -13.76 -18.95 -9.476 0.32360E+05 -17.253 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.91 -0.61 -0.051 0.10429E+04 38 aragonite 0.97 -3.23 -4.20 -1.399 0.71659E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.23 -4.04 -1.347 0.69017E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.37 -4.26 -1.218 0.72807E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.37 -3.82 -1.092 0.65230E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.72 -3.46 -1.154 0.59090E+04 147 pyrrhotiteFe0.875 -6.02 -9.12 -3.10 -1.141 0.52962E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.72 -3.31 -1.103 0.56518E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.21 -4.24 -1.412 0.72337E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001000 MOLES New total amount of reactant added: 0.0001100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142448E-01 Osmotic coef. = 0.9736 True ionic strength = .2010350E-01 Chg. balance for total moles = -.3665E-10 Max. difference allowed = 0.1385E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88663E-10 -10.0523 0.74479E-10 -10.1280 0.84003E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27781E-03 -3.5563 0.23196E-03 -3.6346 0.83496E+00 -0.0783 4 SO4-- 0.14372E-11 -11.8425 0.74551E-12 -12.1275 0.51873E+00 -0.2851 5 HCO3- 0.77407E-06 -6.1112 0.64726E-06 -6.1889 0.83619E+00 -0.0777 6 HS- 0.56760E-04 -4.2460 0.47399E-04 -4.3242 0.83508E+00 -0.0783 7 Al+++ 0.98290E-29 -29.0075 0.22650E-29 -29.6449 0.23045E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13620E-06 -6.8658 0.70129E-07 -7.1541 0.51491E+00 -0.2883 10 Mg++ 0.21307E-10 -10.6715 0.10921E-10 -10.9617 0.51255E+00 -0.2903 11 Fe++ 0.58727E-13 -13.2312 0.30133E-13 -13.5210 0.51311E+00 -0.2898 12 K+ 0.15717E-03 -3.8036 0.13146E-03 -3.8812 0.83638E+00 -0.0776 13 Na+ 0.19944E-01 -1.7002 0.16650E-01 -1.7786 0.83481E+00 -0.0784 14 Mn++ 0.18840E-10 -10.7249 0.96749E-11 -11.0144 0.51354E+00 -0.2894 15 F- 0.28919E-06 -6.5388 0.24096E-06 -6.6181 0.83323E+00 -0.0792 16 HPO4-- 0.45017E-07 -7.3466 0.23355E-07 -7.6316 0.51881E+00 -0.2850 18 HSiO3- 0.10450E-01 -1.9809 0.87254E-02 -2.0592 0.83496E+00 -0.0783 19 Ca(HSiO3)+ 0.16658E-07 -7.7784 0.13935E-07 -7.8559 0.83656E+00 -0.0775 20 Mg(HSiO3)+ 0.32284E-11 -11.4910 0.27008E-11 -11.5685 0.83656E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66402E-16 -16.1778 0.55550E-16 -16.2553 0.83656E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52967E-05 -5.2760 0.44145E-05 -5.3551 0.83345E+00 -0.0791 26 CH4,aq 0.40115E-04 -4.3967 0.39975E-04 -4.3982 0.99652E+00 -0.0015 27 C2H6,aq 0.23669E-13 -13.6258 0.23586E-13 -13.6273 0.99652E+00 -0.0015 31 CO,aq 0.29972E-16 -16.5233 0.29972E-16 -16.5233 0.10000E+01 0.0000 32 CO2,aq 0.10337E-09 -9.9856 0.10301E-09 -9.9871 0.99652E+00 -0.0015 33 CO3-2 0.14665E-05 -5.8337 0.75908E-06 -6.1197 0.51763E+00 -0.2860 34 CaCO3,aq 0.66750E-09 -9.1756 0.66750E-09 -9.1756 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.13850E-11 -11.8585 0.11587E-11 -11.9360 0.83656E+00 -0.0775 36 CaCl+ 0.31469E-10 -10.5021 0.26325E-10 -10.5796 0.83656E+00 -0.0775 37 CaCl2,aq 0.14508E-14 -14.8384 0.14508E-14 -14.8384 0.10000E+01 0.0000 38 CaF+ 0.29492E-12 -12.5303 0.24672E-12 -12.6078 0.83656E+00 -0.0775 39 CaOH+ 0.80217E-07 -7.0957 0.67107E-07 -7.1732 0.83656E+00 -0.0775 40 CaSO4,aq 0.16602E-16 -16.7798 0.16602E-16 -16.7798 0.10000E+01 0.0000 41 HCl,aq 0.31658E-14 -14.4995 0.31658E-14 -14.4995 0.10000E+01 0.0000 45 HF,aq 0.12286E-12 -12.9106 0.12286E-12 -12.9106 0.10000E+01 0.0000 46 HF2- 0.11970E-19 -19.9219 0.99948E-20 -20.0002 0.83496E+00 -0.0783 48 FeCl+ 0.13225E-16 -16.8786 0.11064E-16 -16.9561 0.83656E+00 -0.0775 51 FeF+ 0.44353E-18 -18.3531 0.37104E-18 -18.4306 0.83656E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15743E-10 -10.8029 0.13170E-10 -10.8804 0.83656E+00 -0.0775 55 HFeO2- 0.35522E-07 -7.4495 0.29660E-07 -7.5278 0.83496E+00 -0.0783 56 FeO+ 0.11033E-16 -16.9573 0.92299E-17 -17.0348 0.83656E+00 -0.0775 58 FeO2- 0.40777E-09 -9.3896 0.34047E-09 -9.4679 0.83496E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55265E-09 -9.2575 0.55265E-09 -9.2575 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.18213E-14 -14.7396 0.15207E-14 -14.8179 0.83496E+00 -0.0783 65 MgCO3,aq 0.26055E-13 -13.5841 0.26055E-13 -13.5841 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.22039E-15 -15.6568 0.18437E-15 -15.7343 0.83656E+00 -0.0775 67 MgCl+ 0.44415E-14 -14.3525 0.37156E-14 -14.4300 0.83656E+00 -0.0775 68 MgF+ 0.17013E-15 -15.7692 0.14232E-15 -15.8467 0.83656E+00 -0.0775 69 MgOH+ 0.69124E-10 -10.1604 0.57827E-10 -10.2379 0.83656E+00 -0.0775 71 MnF+ 0.46938E-16 -16.3285 0.39267E-16 -16.4060 0.83656E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46954E-09 -9.3283 0.39280E-09 -9.4058 0.83656E+00 -0.0775 74 MnO2-2 0.20876E-10 -10.6803 0.10806E-10 -10.9663 0.51763E+00 -0.2860 75 HMnO2- 0.21118E-09 -9.6754 0.17632E-09 -9.7537 0.83496E+00 -0.0783 78 MnCl+ 0.16519E-13 -13.7820 0.13820E-13 -13.8595 0.83656E+00 -0.0775 80 NaCl,aq 0.12799E-05 -5.8928 0.12799E-05 -5.8928 0.10000E+01 0.0000 81 NaF,aq 0.93926E-09 -9.0272 0.93926E-09 -9.0272 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93077E-02 -2.0312 0.77575E-02 -2.1103 0.83345E+00 -0.0791 89 HPO3-2 0.16286E-14 -14.7882 0.84301E-15 -15.0742 0.51763E+00 -0.2860 91 H2PO3- 0.15079E-18 -18.8216 0.12591E-18 -18.9000 0.83496E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38395E-10 -10.4157 0.32089E-10 -10.4936 0.83575E+00 -0.0779 94 PO4-3 0.10569E-08 -8.9760 0.25585E-09 -9.5920 0.24207E+00 -0.6161 98 HP2O7-3 0.93835E-18 -18.0276 0.21646E-18 -18.6646 0.23068E+00 -0.6370 99 P2O7-4 0.90441E-17 -17.0436 0.69430E-18 -18.1585 0.76768E-01 -1.1148 100 H2S,aq 0.10949E-07 -7.9606 0.10911E-07 -7.9621 0.99652E+00 -0.0015 101 S2-2 0.83033E-14 -14.0807 0.42980E-14 -14.3667 0.51763E+00 -0.2860 107 SO3-2 0.21368E-17 -17.6702 0.11221E-17 -17.9500 0.52514E+00 -0.2797 109 HSO4- 0.63902E-19 -19.1945 0.53510E-19 -19.2716 0.83738E+00 -0.0771 Charge balance for all species = -.7380E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8866279E-10 -.2223006E-01 -.2236753E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981956E+06 0.0000 3 Cl- 0.2778104E-03 0.2790909E-03 0.9877372E+01 6.4934 4 SO4-- 0.1437171E-11 -.4302069E-04 -.4125436E+01 8.1284 5 HCO3- 0.7740685E-06 0.4235629E-04 0.2579960E+01 3.9390 6 HS- 0.5675988E-04 0.9979152E-04 0.3294555E+01 5.8037 7 Al+++ 0.9828968E-29 0.5296850E-05 0.1426680E+00 0.7390 8 H4SiO4 0.6959791E-03 0.1349577E-01 0.1294891E+04 -3.1574 9 Ca++ 0.1361969E-06 0.2337728E-06 0.9352823E-02 13.1018 10 Mg++ 0.2130735E-10 0.9369018E-10 0.2273827E-05 9.2942 11 Fe++ 0.5872667E-13 0.3616017E-07 0.2015919E-02 6.7350 12 K+ 0.1571709E-03 0.1579252E-03 0.6164431E+01 6.2467 13 Na+ 0.1994431E-01 0.2239128E-01 0.5138742E+03 8.3494 14 Mn++ 0.1883965E-10 0.2526657E-08 0.1385676E-03 9.2416 15 F- 0.2891857E-06 0.2901254E-06 0.5502199E-02 3.5099 16 HPO4-- 0.4501742E-07 0.4611272E-07 0.4418142E-02 12.6243 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279254E+02 -.1103360E-01 -.8278150E+02 0.0000000E+00 2 H2O -.7168699E+01 0.2754915E+02 -.3471785E+02 0.0000000E+00 3 Cl- 0.1385232E-03 0.1385232E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385930E+00 -.2135276E-04 0.1386144E+00 0.0000000E+00 5 HCO3- 0.2102300E-04 0.2102300E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385649E+00 0.4953023E-04 -.1386144E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629023E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6698450E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1160301E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4650191E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794763E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7838412E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111362E-01 0.6265263E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254073E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1440000E-06 0.1440000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288745E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.5176E-14 Mass of aqueous solution: 0.497203E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.158 73.20 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2625 -0.581 56.84 1.755 1.041 17.37 hedenbergite 0.6807E-01 -1.167 16.89 1.228 0.3092 4.626 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.158 97.31 tr.625ac.25prg.125 0.4255E-01 -1.371 36.37 1.561 0.6658 11.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337898 g Volume = 2210.778163 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001100 moles log = -3.9586 Original solution: 1000.0103000 g Original solution / Rock added: 9091002.73 (Water/Rock Ratio), log = 6.9586 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0947 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9330E+00 0.9850 0.1006E+01 0.1021E+01 CO2,gas 0.1000E-07 1.0064 0.1102E-07 0.1095E-07 CH4,gas 0.5312E-01 1.0120 0.5884E-01 0.5815E-01 H2,gas 0.1388E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2752E-06 0.9957 0.2999E-06 0.3012E-06 S2,gas 0.1334E-28 1.0000 0.1460E-28 0.1460E-28 CO,gas 0.4080E-13 1.0000 0.4466E-13 0.4466E-13 SO3,gas 0.1428E-47 1.0000 0.1564E-47 0.1564E-47 SO2,gas 0.8451E-27 1.0000 0.9251E-27 0.9251E-27 HF,gas 0.2756E-15 1.0000 0.3017E-15 0.3017E-15 HCl,gas 0.5103E-17 1.0000 0.5586E-17 0.5586E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.60662E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.15165E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.32 -9.66 -3.219 0.16489E+05 -7.958 3 CH4,gas 4.54 1.61 -2.93 -0.732 0.50017E+04 -1.230 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.45 -8.22 -4.111 0.14039E+05 -6.523 6 S2,gas -7.34 -37.87 -30.53 -4.698 0.52137E+05 -28.836 7 CO,gas 3.21 -11.83 -15.05 -4.630 0.25696E+05 -13.350 8 SO3,gas 17.12 -32.38 -49.50 -12.376 0.84528E+05 -47.806 9 SO2,gas 0.83 -27.90 -28.73 -7.662 0.49060E+05 -27.034 10 HF,gas 0.47 -16.75 -17.22 -8.610 0.29402E+05 -15.520 11 HCl,gas 5.19 -13.76 -18.95 -9.476 0.32360E+05 -17.253 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.90 -0.60 -0.050 0.10220E+04 38 aragonite 0.97 -3.22 -4.18 -1.394 0.71399E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.22 -4.03 -1.342 0.68757E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.35 -4.25 -1.214 0.72548E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.35 -3.81 -1.087 0.64970E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.72 -3.46 -1.152 0.59026E+04 147 pyrrhotiteFe0.875 -6.02 -9.11 -3.10 -1.139 0.52898E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.72 -3.31 -1.102 0.56454E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.21 -4.23 -1.411 0.72273E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001100 MOLES New total amount of reactant added: 0.0001200 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001200 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142365E-01 Osmotic coef. = 0.9741 True ionic strength = .2010396E-01 Chg. balance for total moles = -.3665E-10 Max. difference allowed = 0.1386E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88665E-10 -10.0522 0.74481E-10 -10.1280 0.84003E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27793E-03 -3.5561 0.23206E-03 -3.6344 0.83496E+00 -0.0783 4 SO4-- 0.14495E-11 -11.8388 0.75192E-12 -12.1238 0.51873E+00 -0.2851 5 HCO3- 0.80068E-06 -6.0965 0.66951E-06 -6.1742 0.83618E+00 -0.0777 6 HS- 0.57249E-04 -4.2422 0.47808E-04 -4.3205 0.83508E+00 -0.0783 7 Al+++ 0.98297E-29 -29.0075 0.22652E-29 -29.6449 0.23044E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13620E-06 -6.8658 0.70132E-07 -7.1541 0.51491E+00 -0.2883 10 Mg++ 0.21308E-10 -10.6715 0.10921E-10 -10.9617 0.51254E+00 -0.2903 11 Fe++ 0.58729E-13 -13.2311 0.30134E-13 -13.5209 0.51311E+00 -0.2898 12 K+ 0.15717E-03 -3.8036 0.13146E-03 -3.8812 0.83638E+00 -0.0776 13 Na+ 0.19945E-01 -1.7002 0.16650E-01 -1.7786 0.83481E+00 -0.0784 14 Mn++ 0.18840E-10 -10.7249 0.96752E-11 -11.0143 0.51353E+00 -0.2894 15 F- 0.29722E-06 -6.5269 0.24765E-06 -6.6062 0.83323E+00 -0.0792 16 HPO4-- 0.45016E-07 -7.3466 0.23354E-07 -7.6316 0.51880E+00 -0.2850 18 HSiO3- 0.10450E-01 -1.9809 0.87253E-02 -2.0592 0.83496E+00 -0.0783 19 Ca(HSiO3)+ 0.16658E-07 -7.7784 0.13936E-07 -7.8559 0.83656E+00 -0.0775 20 Mg(HSiO3)+ 0.32285E-11 -11.4910 0.27008E-11 -11.5685 0.83656E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66404E-16 -16.1778 0.55551E-16 -16.2553 0.83656E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52966E-05 -5.2760 0.44144E-05 -5.3551 0.83345E+00 -0.0791 26 CH4,aq 0.41495E-04 -4.3820 0.41350E-04 -4.3835 0.99652E+00 -0.0015 27 C2H6,aq 0.25325E-13 -13.5965 0.25237E-13 -13.5980 0.99652E+00 -0.0015 31 CO,aq 0.31003E-16 -16.5086 0.31003E-16 -16.5086 0.10000E+01 0.0000 32 CO2,aq 0.10692E-09 -9.9709 0.10655E-09 -9.9724 0.99652E+00 -0.0015 33 CO3-2 0.15169E-05 -5.8191 0.78516E-06 -6.1050 0.51762E+00 -0.2860 34 CaCO3,aq 0.69045E-09 -9.1609 0.69045E-09 -9.1609 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.14327E-11 -11.8438 0.11986E-11 -11.9213 0.83656E+00 -0.0775 36 CaCl+ 0.31483E-10 -10.5019 0.26338E-10 -10.5794 0.83656E+00 -0.0775 37 CaCl2,aq 0.14521E-14 -14.8380 0.14521E-14 -14.8380 0.10000E+01 0.0000 38 CaF+ 0.30312E-12 -12.5184 0.25358E-12 -12.5959 0.83656E+00 -0.0775 39 CaOH+ 0.80219E-07 -7.0957 0.67108E-07 -7.1732 0.83656E+00 -0.0775 40 CaSO4,aq 0.16745E-16 -16.7761 0.16745E-16 -16.7761 0.10000E+01 0.0000 41 HCl,aq 0.31672E-14 -14.4993 0.31672E-14 -14.4993 0.10000E+01 0.0000 45 HF,aq 0.12627E-12 -12.8987 0.12627E-12 -12.8987 0.10000E+01 0.0000 46 HF2- 0.12645E-19 -19.8981 0.10558E-19 -19.9764 0.83496E+00 -0.0783 48 FeCl+ 0.13231E-16 -16.8784 0.11069E-16 -16.9559 0.83656E+00 -0.0775 51 FeF+ 0.45587E-18 -18.3412 0.38136E-18 -18.4187 0.83656E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15743E-10 -10.8029 0.13170E-10 -10.8804 0.83656E+00 -0.0775 55 HFeO2- 0.35522E-07 -7.4495 0.29659E-07 -7.5278 0.83496E+00 -0.0783 56 FeO+ 0.11033E-16 -16.9573 0.92301E-17 -17.0348 0.83656E+00 -0.0775 58 FeO2- 0.40776E-09 -9.3896 0.34046E-09 -9.4679 0.83496E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55290E-09 -9.2574 0.55290E-09 -9.2574 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.18370E-14 -14.7359 0.15338E-14 -14.8142 0.83496E+00 -0.0783 65 MgCO3,aq 0.26951E-13 -13.5694 0.26951E-13 -13.5694 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.22798E-15 -15.6421 0.19072E-15 -15.7196 0.83656E+00 -0.0775 67 MgCl+ 0.44436E-14 -14.3523 0.37174E-14 -14.4298 0.83656E+00 -0.0775 68 MgF+ 0.17486E-15 -15.7573 0.14628E-15 -15.8348 0.83656E+00 -0.0775 69 MgOH+ 0.69126E-10 -10.1604 0.57828E-10 -10.2379 0.83656E+00 -0.0775 71 MnF+ 0.48244E-16 -16.3166 0.40359E-16 -16.3941 0.83656E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46955E-09 -9.3283 0.39281E-09 -9.4058 0.83656E+00 -0.0775 74 MnO2-2 0.20876E-10 -10.6804 0.10806E-10 -10.9663 0.51762E+00 -0.2860 75 HMnO2- 0.21117E-09 -9.6754 0.17632E-09 -9.7537 0.83496E+00 -0.0783 78 MnCl+ 0.16527E-13 -13.7818 0.13826E-13 -13.8593 0.83656E+00 -0.0775 80 NaCl,aq 0.12805E-05 -5.8926 0.12805E-05 -5.8926 0.10000E+01 0.0000 81 NaF,aq 0.96536E-09 -9.0153 0.96536E-09 -9.0153 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93076E-02 -2.0312 0.77574E-02 -2.1103 0.83345E+00 -0.0791 89 HPO3-2 0.16286E-14 -14.7882 0.84298E-15 -15.0742 0.51762E+00 -0.2860 91 H2PO3- 0.15079E-18 -18.8216 0.12590E-18 -18.9000 0.83496E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38394E-10 -10.4157 0.32088E-10 -10.4937 0.83575E+00 -0.0779 94 PO4-3 0.10569E-08 -8.9760 0.25583E-09 -9.5920 0.24207E+00 -0.6161 98 HP2O7-3 0.93831E-18 -18.0277 0.21644E-18 -18.6647 0.23067E+00 -0.6370 99 P2O7-4 0.90436E-17 -17.0437 0.69424E-18 -18.1585 0.76766E-01 -1.1148 100 H2S,aq 0.11043E-07 -7.9569 0.11005E-07 -7.9584 0.99652E+00 -0.0015 101 S2-2 0.84472E-14 -14.0733 0.43725E-14 -14.3593 0.51762E+00 -0.2860 107 SO3-2 0.21552E-17 -17.6665 0.11317E-17 -17.9462 0.52514E+00 -0.2797 109 HSO4- 0.64453E-19 -19.1908 0.53971E-19 -19.2678 0.83738E+00 -0.0771 Charge balance for all species = -.7382E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8866457E-10 -.2222977E-01 -.2236724E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981956E+06 0.0000 3 Cl- 0.2779286E-03 0.2792097E-03 0.9881575E+01 6.4936 4 SO4-- 0.1449544E-11 -.4440032E-04 -.4257735E+01 8.1321 5 HCO3- 0.8006767E-06 0.4381295E-04 0.2668686E+01 3.9537 6 HS- 0.5724935E-04 0.1016607E-03 0.3356265E+01 5.8075 7 Al+++ 0.9829652E-29 0.5296759E-05 0.1426655E+00 0.7390 8 H4SiO4 0.6959790E-03 0.1349559E-01 0.1294874E+04 -3.1574 9 Ca++ 0.1362028E-06 0.2338037E-06 0.9354059E-02 13.1018 10 Mg++ 0.2130828E-10 0.9369372E-10 0.2273913E-05 9.2942 11 Fe++ 0.5872922E-13 0.3615955E-07 0.2015884E-02 6.7350 12 K+ 0.1571740E-03 0.1579283E-03 0.6164554E+01 6.2467 13 Na+ 0.1994471E-01 0.2239168E-01 0.5138834E+03 8.3494 14 Mn++ 0.1884048E-10 0.2526665E-08 0.1385681E-03 9.2416 15 F- 0.2972185E-06 0.2981843E-06 0.5655036E-02 3.5218 16 HPO4-- 0.4501601E-07 0.4611126E-07 0.4418002E-02 12.6243 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279253E+02 -.1103346E-01 -.8278150E+02 0.0000000E+00 2 H2O -.7168690E+01 0.2754916E+02 -.3471785E+02 0.0000000E+00 3 Cl- 0.1385822E-03 0.1385822E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385931E+00 -.2203753E-04 0.1386151E+00 0.0000000E+00 5 HCO3- 0.2174600E-04 0.2174600E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385647E+00 0.5045800E-04 -.1386151E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628979E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6698364E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1160455E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4650369E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794734E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7838571E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111383E-01 0.6265263E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254078E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1480000E-06 0.1480000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288674E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.9451E-14 Mass of aqueous solution: 0.497204E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001200 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.158 73.20 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2625 -0.581 56.84 1.755 1.041 17.37 hedenbergite 0.6807E-01 -1.167 16.89 1.228 0.3092 4.625 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.158 97.31 tr.625ac.25prg.125 0.4256E-01 -1.371 36.38 1.561 0.6659 11.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337901 g Volume = 2210.778190 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001200 moles log = -3.9208 Original solution: 1000.0103000 g Original solution / Rock added: 8333419.17 (Water/Rock Ratio), log = 6.9208 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0967 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9313E+00 0.9849 0.1006E+01 0.1021E+01 CO2,gas 0.1033E-07 1.0064 0.1140E-07 0.1133E-07 CH4,gas 0.5484E-01 1.0119 0.6086E-01 0.6015E-01 H2,gas 0.1386E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2770E-06 0.9957 0.3025E-06 0.3038E-06 S2,gas 0.1355E-28 1.0000 0.1486E-28 0.1486E-28 CO,gas 0.4213E-13 1.0000 0.4620E-13 0.4620E-13 SO3,gas 0.1438E-47 1.0000 0.1577E-47 0.1577E-47 SO2,gas 0.8508E-27 1.0000 0.9330E-27 0.9330E-27 HF,gas 0.2827E-15 1.0000 0.3100E-15 0.3100E-15 HCl,gas 0.5096E-17 1.0000 0.5589E-17 0.5589E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.84926E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.30 -9.64 -3.214 0.16464E+05 -7.943 3 CH4,gas 4.54 1.63 -2.91 -0.729 0.49766E+04 -1.216 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.45 -8.22 -4.109 0.14032E+05 -6.519 6 S2,gas -7.34 -37.86 -30.53 -4.696 0.52124E+05 -28.828 7 CO,gas 3.21 -11.82 -15.03 -4.626 0.25671E+05 -13.335 8 SO3,gas 17.12 -32.38 -49.50 -12.375 0.84522E+05 -47.802 9 SO2,gas 0.83 -27.90 -28.73 -7.661 0.49054E+05 -27.030 10 HF,gas 0.47 -16.73 -17.21 -8.604 0.29381E+05 -15.509 11 HCl,gas 5.19 -13.76 -18.95 -9.476 0.32359E+05 -17.253 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.89 -0.59 -0.049 0.10016E+04 38 aragonite 0.97 -3.20 -4.17 -1.389 0.71148E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.20 -4.01 -1.337 0.68506E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.34 -4.23 -1.210 0.72297E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.34 -3.79 -1.083 0.64720E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.71 -3.45 -1.151 0.58962E+04 147 pyrrhotiteFe0.875 -6.02 -9.11 -3.09 -1.138 0.52834E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.71 -3.30 -1.101 0.56390E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.21 -4.23 -1.410 0.72209E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001200 MOLES New total amount of reactant added: 0.0001300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3667E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142282E-01 Osmotic coef. = 0.9746 True ionic strength = .2010441E-01 Chg. balance for total moles = -.3667E-10 Max. difference allowed = 0.1386E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88666E-10 -10.0522 0.74482E-10 -10.1279 0.84003E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27805E-03 -3.5559 0.23216E-03 -3.6342 0.83496E+00 -0.0783 4 SO4-- 0.14619E-11 -11.8351 0.75833E-12 -12.1201 0.51873E+00 -0.2851 5 HCO3- 0.82728E-06 -6.0823 0.69176E-06 -6.1600 0.83618E+00 -0.0777 6 HS- 0.57739E-04 -4.2385 0.48217E-04 -4.3168 0.83508E+00 -0.0783 7 Al+++ 0.98303E-29 -29.0074 0.22653E-29 -29.6449 0.23044E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13621E-06 -6.8658 0.70135E-07 -7.1541 0.51490E+00 -0.2883 10 Mg++ 0.21309E-10 -10.6714 0.10922E-10 -10.9617 0.51254E+00 -0.2903 11 Fe++ 0.58732E-13 -13.2311 0.30136E-13 -13.5209 0.51310E+00 -0.2898 12 K+ 0.15718E-03 -3.8036 0.13146E-03 -3.8812 0.83638E+00 -0.0776 13 Na+ 0.19945E-01 -1.7002 0.16650E-01 -1.7786 0.83481E+00 -0.0784 14 Mn++ 0.18841E-10 -10.7249 0.96756E-11 -11.0143 0.51353E+00 -0.2894 15 F- 0.30525E-06 -6.5153 0.25435E-06 -6.5946 0.83323E+00 -0.0792 16 HPO4-- 0.45015E-07 -7.3466 0.23354E-07 -7.6316 0.51880E+00 -0.2850 18 HSiO3- 0.10450E-01 -1.9809 0.87251E-02 -2.0592 0.83496E+00 -0.0783 19 Ca(HSiO3)+ 0.16659E-07 -7.7784 0.13936E-07 -7.8559 0.83656E+00 -0.0775 20 Mg(HSiO3)+ 0.32285E-11 -11.4910 0.27009E-11 -11.5685 0.83656E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66405E-16 -16.1778 0.55552E-16 -16.2553 0.83656E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52965E-05 -5.2760 0.44144E-05 -5.3551 0.83345E+00 -0.0791 26 CH4,aq 0.42874E-04 -4.3678 0.42725E-04 -4.3693 0.99652E+00 -0.0015 27 C2H6,aq 0.27037E-13 -13.5680 0.26943E-13 -13.5696 0.99652E+00 -0.0015 31 CO,aq 0.32033E-16 -16.4944 0.32033E-16 -16.4944 0.10000E+01 0.0000 32 CO2,aq 0.11048E-09 -9.9567 0.11009E-09 -9.9582 0.99652E+00 -0.0015 33 CO3-2 0.15672E-05 -5.8049 0.81124E-06 -6.0909 0.51762E+00 -0.2860 34 CaCO3,aq 0.71341E-09 -9.1467 0.71341E-09 -9.1467 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.14804E-11 -11.8296 0.12384E-11 -11.9071 0.83656E+00 -0.0775 36 CaCl+ 0.31498E-10 -10.5017 0.26350E-10 -10.5792 0.83656E+00 -0.0775 37 CaCl2,aq 0.14533E-14 -14.8376 0.14533E-14 -14.8376 0.10000E+01 0.0000 38 CaF+ 0.31132E-12 -12.5068 0.26044E-12 -12.5843 0.83656E+00 -0.0775 39 CaOH+ 0.80220E-07 -7.0957 0.67109E-07 -7.1732 0.83656E+00 -0.0775 40 CaSO4,aq 0.16889E-16 -16.7724 0.16889E-16 -16.7724 0.10000E+01 0.0000 41 HCl,aq 0.31686E-14 -14.4991 0.31686E-14 -14.4991 0.10000E+01 0.0000 45 HF,aq 0.12969E-12 -12.8871 0.12969E-12 -12.8871 0.10000E+01 0.0000 46 HF2- 0.13338E-19 -19.8749 0.11137E-19 -19.9532 0.83496E+00 -0.0783 48 FeCl+ 0.13237E-16 -16.8782 0.11074E-16 -16.9557 0.83656E+00 -0.0775 51 FeF+ 0.46821E-18 -18.3296 0.39169E-18 -18.4071 0.83656E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15743E-10 -10.8029 0.13170E-10 -10.8804 0.83656E+00 -0.0775 55 HFeO2- 0.35521E-07 -7.4495 0.29659E-07 -7.5278 0.83496E+00 -0.0783 56 FeO+ 0.11034E-16 -16.9573 0.92303E-17 -17.0348 0.83656E+00 -0.0775 58 FeO2- 0.40775E-09 -9.3896 0.34046E-09 -9.4679 0.83496E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55314E-09 -9.2572 0.55314E-09 -9.2572 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.18527E-14 -14.7322 0.15470E-14 -14.8105 0.83496E+00 -0.0783 65 MgCO3,aq 0.27847E-13 -13.5552 0.27847E-13 -13.5552 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.23556E-15 -15.6279 0.19706E-15 -15.7054 0.83656E+00 -0.0775 67 MgCl+ 0.44457E-14 -14.3521 0.37191E-14 -14.4296 0.83656E+00 -0.0775 68 MgF+ 0.17959E-15 -15.7457 0.15024E-15 -15.8232 0.83656E+00 -0.0775 69 MgOH+ 0.69127E-10 -10.1604 0.57829E-10 -10.2379 0.83656E+00 -0.0775 71 MnF+ 0.49549E-16 -16.3050 0.41451E-16 -16.3825 0.83656E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46956E-09 -9.3283 0.39282E-09 -9.4058 0.83656E+00 -0.0775 74 MnO2-2 0.20875E-10 -10.6804 0.10805E-10 -10.9664 0.51762E+00 -0.2860 75 HMnO2- 0.21117E-09 -9.6754 0.17632E-09 -9.7537 0.83496E+00 -0.0783 78 MnCl+ 0.16535E-13 -13.7816 0.13832E-13 -13.8591 0.83656E+00 -0.0775 80 NaCl,aq 0.12810E-05 -5.8924 0.12810E-05 -5.8924 0.10000E+01 0.0000 81 NaF,aq 0.99147E-09 -9.0037 0.99147E-09 -9.0037 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93074E-02 -2.0312 0.77572E-02 -2.1103 0.83345E+00 -0.0791 89 HPO3-2 0.16285E-14 -14.7882 0.84295E-15 -15.0742 0.51762E+00 -0.2860 91 H2PO3- 0.15079E-18 -18.8216 0.12590E-18 -18.9000 0.83496E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38394E-10 -10.4157 0.32088E-10 -10.4937 0.83575E+00 -0.0779 94 PO4-3 0.10568E-08 -8.9760 0.25582E-09 -9.5921 0.24207E+00 -0.6161 98 HP2O7-3 0.93827E-18 -18.0277 0.21643E-18 -18.6647 0.23067E+00 -0.6370 99 P2O7-4 0.90431E-17 -17.0437 0.69419E-18 -18.1585 0.76764E-01 -1.1148 100 H2S,aq 0.11138E-07 -7.9532 0.11099E-07 -7.9547 0.99652E+00 -0.0015 101 S2-2 0.85923E-14 -14.0659 0.44475E-14 -14.3519 0.51762E+00 -0.2860 107 SO3-2 0.21736E-17 -17.6628 0.11414E-17 -17.9426 0.52513E+00 -0.2797 109 HSO4- 0.65004E-19 -19.1871 0.54433E-19 -19.2641 0.83738E+00 -0.0771 Charge balance for all species = -.7389E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8866636E-10 -.2222948E-01 -.2236695E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981956E+06 0.0000 3 Cl- 0.2780468E-03 0.2793284E-03 0.9885778E+01 6.4937 4 SO4-- 0.1461916E-11 -.4577995E-04 -.4390033E+01 8.1358 5 HCO3- 0.8272841E-06 0.4526960E-04 0.2757412E+01 3.9679 6 HS- 0.5773882E-04 0.1035299E-03 0.3417976E+01 5.8111 7 Al+++ 0.9830336E-29 0.5296669E-05 0.1426631E+00 0.7390 8 H4SiO4 0.6959790E-03 0.1349541E-01 0.1294857E+04 -3.1574 9 Ca++ 0.1362087E-06 0.2338346E-06 0.9355294E-02 13.1018 10 Mg++ 0.2130920E-10 0.9369637E-10 0.2273977E-05 9.2942 11 Fe++ 0.5873178E-13 0.3615894E-07 0.2015850E-02 6.7350 12 K+ 0.1571772E-03 0.1579315E-03 0.6164677E+01 6.2467 13 Na+ 0.1994512E-01 0.2239208E-01 0.5138926E+03 8.3494 14 Mn++ 0.1884132E-10 0.2526673E-08 0.1385685E-03 9.2416 15 F- 0.3052513E-06 0.3062432E-06 0.5807872E-02 3.5334 16 HPO4-- 0.4501460E-07 0.4610980E-07 0.4417862E-02 12.6242 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279253E+02 -.1103333E-01 -.8278150E+02 0.0000000E+00 2 H2O -.7168682E+01 0.2754917E+02 -.3471785E+02 0.0000000E+00 3 Cl- 0.1386412E-03 0.1386412E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385931E+00 -.2272231E-04 0.1386159E+00 0.0000000E+00 5 HCO3- 0.2246900E-04 0.2246900E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385645E+00 0.5138578E-04 -.1386159E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628935E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6698277E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1160609E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4650502E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794704E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7838731E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111403E-01 0.6265263E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254083E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1520000E-06 0.1520000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288602E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.3005E-13 Mass of aqueous solution: 0.497204E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.158 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2624 -0.581 56.84 1.755 1.040 17.37 hedenbergite 0.6806E-01 -1.167 16.89 1.228 0.3091 4.625 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.158 97.31 tr.625ac.25prg.125 0.4256E-01 -1.371 36.38 1.561 0.6660 11.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337904 g Volume = 2210.778218 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001300 moles log = -3.8861 Original solution: 1000.0103000 g Original solution / Rock added: 7692386.92 (Water/Rock Ratio), log = 6.8861 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0987 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9296E+00 0.9849 0.1006E+01 0.1021E+01 CO2,gas 0.1065E-07 1.0063 0.1178E-07 0.1170E-07 CH4,gas 0.5656E-01 1.0119 0.6289E-01 0.6215E-01 H2,gas 0.1383E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2789E-06 0.9957 0.3051E-06 0.3064E-06 S2,gas 0.1375E-28 1.0000 0.1511E-28 0.1511E-28 CO,gas 0.4345E-13 1.0000 0.4774E-13 0.4774E-13 SO3,gas 0.1448E-47 1.0000 0.1591E-47 0.1591E-47 SO2,gas 0.8565E-27 1.0000 0.9410E-27 0.9410E-27 HF,gas 0.2898E-15 1.0000 0.3184E-15 0.3184E-15 HCl,gas 0.5089E-17 1.0000 0.5591E-17 0.5591E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.29 -9.63 -3.209 0.16439E+05 -7.929 3 CH4,gas 4.54 1.64 -2.90 -0.725 0.49524E+04 -1.201 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.44 -8.21 -4.107 0.14026E+05 -6.516 6 S2,gas -7.34 -37.86 -30.52 -4.695 0.52111E+05 -28.821 7 CO,gas 3.21 -11.81 -15.02 -4.622 0.25646E+05 -13.321 8 SO3,gas 17.12 -32.38 -49.50 -12.374 0.84515E+05 -47.798 9 SO2,gas 0.83 -27.89 -28.73 -7.660 0.49048E+05 -27.026 10 HF,gas 0.47 -16.72 -17.20 -8.598 0.29362E+05 -15.497 11 HCl,gas 5.19 -13.76 -18.95 -9.476 0.32359E+05 -17.253 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.88 -0.58 -0.048 0.98184E+03 38 aragonite 0.97 -3.19 -4.15 -1.384 0.70906E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.19 -4.00 -1.333 0.68264E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.32 -4.22 -1.206 0.72055E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.32 -3.78 -1.079 0.64477E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.71 -3.45 -1.150 0.58898E+04 147 pyrrhotiteFe0.875 -6.02 -9.11 -3.09 -1.137 0.52771E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.71 -3.30 -1.100 0.56327E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.20 -4.23 -1.408 0.72146E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001300 MOLES New total amount of reactant added: 0.0001400 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3667E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001400 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142199E-01 Osmotic coef. = 0.9751 True ionic strength = .2010487E-01 Chg. balance for total moles = -.3667E-10 Max. difference allowed = 0.1387E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88668E-10 -10.0522 0.74483E-10 -10.1279 0.84002E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27817E-03 -3.5557 0.23226E-03 -3.6340 0.83496E+00 -0.0783 4 SO4-- 0.14743E-11 -11.8314 0.76475E-12 -12.1165 0.51872E+00 -0.2851 5 HCO3- 0.85389E-06 -6.0686 0.71401E-06 -6.1463 0.83618E+00 -0.0777 6 HS- 0.58228E-04 -4.2349 0.48625E-04 -4.3131 0.83508E+00 -0.0783 7 Al+++ 0.98310E-29 -29.0074 0.22654E-29 -29.6449 0.23044E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13621E-06 -6.8658 0.70137E-07 -7.1541 0.51490E+00 -0.2883 10 Mg++ 0.21310E-10 -10.6714 0.10922E-10 -10.9617 0.51254E+00 -0.2903 11 Fe++ 0.58734E-13 -13.2311 0.30137E-13 -13.5209 0.51310E+00 -0.2898 12 K+ 0.15718E-03 -3.8036 0.13146E-03 -3.8812 0.83638E+00 -0.0776 13 Na+ 0.19946E-01 -1.7002 0.16651E-01 -1.7786 0.83480E+00 -0.0784 14 Mn++ 0.18842E-10 -10.7249 0.96760E-11 -11.0143 0.51353E+00 -0.2894 15 F- 0.31328E-06 -6.5041 0.26104E-06 -6.5833 0.83323E+00 -0.0792 16 HPO4-- 0.45013E-07 -7.3467 0.23353E-07 -7.6317 0.51880E+00 -0.2850 18 HSiO3- 0.10450E-01 -1.9809 0.87250E-02 -2.0592 0.83496E+00 -0.0783 19 Ca(HSiO3)+ 0.16659E-07 -7.7784 0.13936E-07 -7.8559 0.83656E+00 -0.0775 20 Mg(HSiO3)+ 0.32286E-11 -11.4910 0.27009E-11 -11.5685 0.83656E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66406E-16 -16.1778 0.55553E-16 -16.2553 0.83656E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52964E-05 -5.2760 0.44143E-05 -5.3551 0.83344E+00 -0.0791 26 CH4,aq 0.44254E-04 -4.3540 0.44100E-04 -4.3556 0.99652E+00 -0.0015 27 C2H6,aq 0.28805E-13 -13.5405 0.28705E-13 -13.5420 0.99652E+00 -0.0015 31 CO,aq 0.33064E-16 -16.4806 0.33064E-16 -16.4806 0.10000E+01 0.0000 32 CO2,aq 0.11403E-09 -9.9430 0.11364E-09 -9.9445 0.99652E+00 -0.0015 33 CO3-2 0.16176E-05 -5.7911 0.83731E-06 -6.0771 0.51762E+00 -0.2860 34 CaCO3,aq 0.73637E-09 -9.1329 0.73637E-09 -9.1329 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.15280E-11 -11.8159 0.12783E-11 -11.8934 0.83656E+00 -0.0775 36 CaCl+ 0.31512E-10 -10.5015 0.26362E-10 -10.5790 0.83656E+00 -0.0775 37 CaCl2,aq 0.14546E-14 -14.8372 0.14546E-14 -14.8372 0.10000E+01 0.0000 38 CaF+ 0.31953E-12 -12.4955 0.26730E-12 -12.5730 0.83656E+00 -0.0775 39 CaOH+ 0.80222E-07 -7.0957 0.67111E-07 -7.1732 0.83656E+00 -0.0775 40 CaSO4,aq 0.17032E-16 -16.7687 0.17032E-16 -16.7687 0.10000E+01 0.0000 41 HCl,aq 0.31700E-14 -14.4989 0.31700E-14 -14.4989 0.10000E+01 0.0000 45 HF,aq 0.13310E-12 -12.8758 0.13310E-12 -12.8758 0.10000E+01 0.0000 46 HF2- 0.14049E-19 -19.8523 0.11731E-19 -19.9307 0.83496E+00 -0.0783 48 FeCl+ 0.13243E-16 -16.8780 0.11079E-16 -16.9555 0.83656E+00 -0.0775 51 FeF+ 0.48055E-18 -18.3183 0.40201E-18 -18.3958 0.83656E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15744E-10 -10.8029 0.13170E-10 -10.8804 0.83656E+00 -0.0775 55 HFeO2- 0.35520E-07 -7.4495 0.29658E-07 -7.5279 0.83496E+00 -0.0783 56 FeO+ 0.11034E-16 -16.9573 0.92305E-17 -17.0348 0.83656E+00 -0.0775 58 FeO2- 0.40775E-09 -9.3896 0.34045E-09 -9.4679 0.83496E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55339E-09 -9.2570 0.55339E-09 -9.2570 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.18684E-14 -14.7285 0.15601E-14 -14.8069 0.83496E+00 -0.0783 65 MgCO3,aq 0.28743E-13 -13.5415 0.28743E-13 -13.5415 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.24315E-15 -15.6141 0.20341E-15 -15.6916 0.83656E+00 -0.0775 67 MgCl+ 0.44477E-14 -14.3519 0.37208E-14 -14.4294 0.83656E+00 -0.0775 68 MgF+ 0.18432E-15 -15.7344 0.15420E-15 -15.8119 0.83656E+00 -0.0775 69 MgOH+ 0.69129E-10 -10.1603 0.57830E-10 -10.2378 0.83656E+00 -0.0775 71 MnF+ 0.50855E-16 -16.2937 0.42544E-16 -16.3712 0.83656E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46957E-09 -9.3283 0.39283E-09 -9.4058 0.83656E+00 -0.0775 74 MnO2-2 0.20874E-10 -10.6804 0.10805E-10 -10.9664 0.51762E+00 -0.2860 75 HMnO2- 0.21117E-09 -9.6754 0.17632E-09 -9.7537 0.83496E+00 -0.0783 78 MnCl+ 0.16542E-13 -13.7814 0.13839E-13 -13.8589 0.83656E+00 -0.0775 80 NaCl,aq 0.12816E-05 -5.8922 0.12816E-05 -5.8922 0.10000E+01 0.0000 81 NaF,aq 0.10176E-08 -8.9924 0.10176E-08 -8.9924 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93072E-02 -2.0312 0.77571E-02 -2.1103 0.83344E+00 -0.0791 89 HPO3-2 0.16285E-14 -14.7882 0.84292E-15 -15.0742 0.51762E+00 -0.2860 91 H2PO3- 0.15079E-18 -18.8216 0.12590E-18 -18.9000 0.83496E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38393E-10 -10.4157 0.32087E-10 -10.4937 0.83575E+00 -0.0779 94 PO4-3 0.10568E-08 -8.9760 0.25581E-09 -9.5921 0.24207E+00 -0.6161 98 HP2O7-3 0.93823E-18 -18.0277 0.21642E-18 -18.6647 0.23067E+00 -0.6370 99 P2O7-4 0.90427E-17 -17.0437 0.69414E-18 -18.1586 0.76763E-01 -1.1149 100 H2S,aq 0.11233E-07 -7.9495 0.11194E-07 -7.9510 0.99652E+00 -0.0015 101 S2-2 0.87386E-14 -14.0586 0.45233E-14 -14.3445 0.51762E+00 -0.2860 107 SO3-2 0.21919E-17 -17.6592 0.11511E-17 -17.9389 0.52513E+00 -0.2797 109 HSO4- 0.65555E-19 -19.1834 0.54894E-19 -19.2605 0.83738E+00 -0.0771 Charge balance for all species = -.7389E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8866814E-10 -.2222919E-01 -.2236666E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981956E+06 0.0000 3 Cl- 0.2781650E-03 0.2794472E-03 0.9889981E+01 6.4939 4 SO4-- 0.1474288E-11 -.4715959E-04 -.4522333E+01 8.1394 5 HCO3- 0.8538907E-06 0.4672625E-04 0.2846138E+01 3.9816 6 HS- 0.5822829E-04 0.1053991E-03 0.3479686E+01 5.8148 7 Al+++ 0.9831021E-29 0.5296578E-05 0.1426606E+00 0.7390 8 H4SiO4 0.6959790E-03 0.1349523E-01 0.1294839E+04 -3.1574 9 Ca++ 0.1362147E-06 0.2338655E-06 0.9356530E-02 13.1018 10 Mg++ 0.2131013E-10 0.9369902E-10 0.2274042E-05 9.2942 11 Fe++ 0.5873433E-13 0.3615832E-07 0.2015815E-02 6.7350 12 K+ 0.1571803E-03 0.1579346E-03 0.6164800E+01 6.2467 13 Na+ 0.1994552E-01 0.2239248E-01 0.5139018E+03 8.3494 14 Mn++ 0.1884216E-10 0.2526682E-08 0.1385690E-03 9.2416 15 F- 0.3132841E-06 0.3143022E-06 0.5960709E-02 3.5446 16 HPO4-- 0.4501319E-07 0.4610834E-07 0.4417722E-02 12.6242 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279253E+02 -.1103319E-01 -.8278150E+02 0.0000000E+00 2 H2O -.7168674E+01 0.2754918E+02 -.3471786E+02 0.0000000E+00 3 Cl- 0.1387002E-03 0.1387002E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385932E+00 -.2340708E-04 0.1386166E+00 0.0000000E+00 5 HCO3- 0.2319200E-04 0.2319200E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385643E+00 0.5231355E-04 -.1386166E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628891E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6698191E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1160762E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4650635E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794674E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7838891E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111423E-01 0.6265263E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254087E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1560000E-06 0.1560000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288531E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1757E-13 Mass of aqueous solution: 0.497204E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001400 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.158 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2624 -0.581 56.83 1.755 1.040 17.37 hedenbergite 0.6806E-01 -1.167 16.88 1.227 0.3091 4.625 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.158 97.31 tr.625ac.25prg.125 0.4257E-01 -1.371 36.39 1.561 0.6661 11.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337908 g Volume = 2210.778246 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001400 moles log = -3.8539 Original solution: 1000.0103000 g Original solution / Rock added: 7142930.71 (Water/Rock Ratio), log = 6.8539 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1007 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9279E+00 0.9849 0.1006E+01 0.1021E+01 CO2,gas 0.1098E-07 1.0063 0.1216E-07 0.1208E-07 CH4,gas 0.5828E-01 1.0119 0.6491E-01 0.6415E-01 H2,gas 0.1381E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2807E-06 0.9957 0.3077E-06 0.3090E-06 S2,gas 0.1396E-28 1.0000 0.1537E-28 0.1537E-28 CO,gas 0.4476E-13 1.0000 0.4927E-13 0.4927E-13 SO3,gas 0.1457E-47 1.0000 0.1604E-47 0.1604E-47 SO2,gas 0.8622E-27 1.0000 0.9490E-27 0.9490E-27 HF,gas 0.2969E-15 1.0000 0.3268E-15 0.3268E-15 HCl,gas 0.5082E-17 1.0000 0.5594E-17 0.5594E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.27 -9.61 -3.205 0.16416E+05 -7.915 3 CH4,gas 4.54 1.66 -2.89 -0.722 0.49289E+04 -1.188 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.44 -8.21 -4.105 0.14020E+05 -6.512 6 S2,gas -7.34 -37.85 -30.51 -4.694 0.52099E+05 -28.813 7 CO,gas 3.21 -11.79 -15.01 -4.617 0.25623E+05 -13.307 8 SO3,gas 17.12 -32.37 -49.49 -12.373 0.84509E+05 -47.795 9 SO2,gas 0.83 -27.89 -28.72 -7.659 0.49042E+05 -27.023 10 HF,gas 0.47 -16.71 -17.18 -8.592 0.29342E+05 -15.486 11 HCl,gas 5.19 -13.76 -18.95 -9.476 0.32359E+05 -17.252 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.86 -0.56 -0.047 0.96257E+03 38 aragonite 0.97 -3.17 -4.14 -1.380 0.70671E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.17 -3.98 -1.328 0.68029E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.31 -4.21 -1.202 0.71820E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.31 -3.76 -1.075 0.64242E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.71 -3.45 -1.149 0.58836E+04 147 pyrrhotiteFe0.875 -6.02 -9.10 -3.09 -1.135 0.52708E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.71 -3.30 -1.098 0.56264E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.20 -4.22 -1.407 0.72083E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001400 MOLES New total amount of reactant added: 0.0001500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3667E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142116E-01 Osmotic coef. = 0.9756 True ionic strength = .2010532E-01 Chg. balance for total moles = -.3667E-10 Max. difference allowed = 0.1388E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88670E-10 -10.0522 0.74485E-10 -10.1279 0.84002E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27828E-03 -3.5555 0.23235E-03 -3.6338 0.83496E+00 -0.0783 4 SO4-- 0.14867E-11 -11.8278 0.77116E-12 -12.1129 0.51872E+00 -0.2851 5 HCO3- 0.88050E-06 -6.0553 0.73625E-06 -6.1330 0.83618E+00 -0.0777 6 HS- 0.58718E-04 -4.2312 0.49034E-04 -4.3095 0.83508E+00 -0.0783 7 Al+++ 0.98317E-29 -29.0074 0.22656E-29 -29.6448 0.23043E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13622E-06 -6.8658 0.70140E-07 -7.1540 0.51490E+00 -0.2883 10 Mg++ 0.21311E-10 -10.6714 0.10923E-10 -10.9617 0.51254E+00 -0.2903 11 Fe++ 0.58737E-13 -13.2311 0.30138E-13 -13.5209 0.51310E+00 -0.2898 12 K+ 0.15718E-03 -3.8036 0.13147E-03 -3.8812 0.83638E+00 -0.0776 13 Na+ 0.19946E-01 -1.7001 0.16651E-01 -1.7786 0.83480E+00 -0.0784 14 Mn++ 0.18843E-10 -10.7249 0.96764E-11 -11.0143 0.51353E+00 -0.2894 15 F- 0.32132E-06 -6.4931 0.26773E-06 -6.5723 0.83323E+00 -0.0792 16 HPO4-- 0.45012E-07 -7.3467 0.23352E-07 -7.6317 0.51879E+00 -0.2850 18 HSiO3- 0.10449E-01 -1.9809 0.87248E-02 -2.0592 0.83496E+00 -0.0783 19 Ca(HSiO3)+ 0.16659E-07 -7.7783 0.13937E-07 -7.8558 0.83656E+00 -0.0775 20 Mg(HSiO3)+ 0.32287E-11 -11.4910 0.27010E-11 -11.5685 0.83656E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66408E-16 -16.1778 0.55554E-16 -16.2553 0.83656E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52963E-05 -5.2760 0.44142E-05 -5.3551 0.83344E+00 -0.0791 26 CH4,aq 0.45634E-04 -4.3407 0.45475E-04 -4.3422 0.99652E+00 -0.0015 27 C2H6,aq 0.30629E-13 -13.5139 0.30522E-13 -13.5154 0.99652E+00 -0.0015 31 CO,aq 0.34095E-16 -16.4673 0.34095E-16 -16.4673 0.10000E+01 0.0000 32 CO2,aq 0.11759E-09 -9.9296 0.11718E-09 -9.9311 0.99652E+00 -0.0015 33 CO3-2 0.16680E-05 -5.7778 0.86338E-06 -6.0638 0.51761E+00 -0.2860 34 CaCO3,aq 0.75932E-09 -9.1196 0.75932E-09 -9.1196 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.15757E-11 -11.8025 0.13182E-11 -11.8800 0.83656E+00 -0.0775 36 CaCl+ 0.31527E-10 -10.5013 0.26374E-10 -10.5788 0.83656E+00 -0.0775 37 CaCl2,aq 0.14559E-14 -14.8369 0.14559E-14 -14.8369 0.10000E+01 0.0000 38 CaF+ 0.32773E-12 -12.4845 0.27417E-12 -12.5620 0.83656E+00 -0.0775 39 CaOH+ 0.80224E-07 -7.0957 0.67112E-07 -7.1732 0.83656E+00 -0.0775 40 CaSO4,aq 0.17176E-16 -16.7651 0.17176E-16 -16.7651 0.10000E+01 0.0000 41 HCl,aq 0.31714E-14 -14.4987 0.31714E-14 -14.4987 0.10000E+01 0.0000 45 HF,aq 0.13652E-12 -12.8648 0.13652E-12 -12.8648 0.10000E+01 0.0000 46 HF2- 0.14779E-19 -19.8303 0.12340E-19 -19.9087 0.83496E+00 -0.0783 48 FeCl+ 0.13250E-16 -16.8778 0.11084E-16 -16.9553 0.83656E+00 -0.0775 51 FeF+ 0.49289E-18 -18.3073 0.41233E-18 -18.3848 0.83656E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15744E-10 -10.8029 0.13171E-10 -10.8804 0.83656E+00 -0.0775 55 HFeO2- 0.35520E-07 -7.4495 0.29657E-07 -7.5279 0.83496E+00 -0.0783 56 FeO+ 0.11034E-16 -16.9573 0.92306E-17 -17.0348 0.83656E+00 -0.0775 58 FeO2- 0.40774E-09 -9.3896 0.34044E-09 -9.4680 0.83496E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55363E-09 -9.2568 0.55363E-09 -9.2568 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.18841E-14 -14.7249 0.15732E-14 -14.8032 0.83496E+00 -0.0783 65 MgCO3,aq 0.29639E-13 -13.5281 0.29639E-13 -13.5281 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.25073E-15 -15.6008 0.20975E-15 -15.6783 0.83656E+00 -0.0775 67 MgCl+ 0.44498E-14 -14.3517 0.37225E-14 -14.4292 0.83656E+00 -0.0775 68 MgF+ 0.18906E-15 -15.7234 0.15816E-15 -15.8009 0.83656E+00 -0.0775 69 MgOH+ 0.69130E-10 -10.1603 0.57831E-10 -10.2378 0.83656E+00 -0.0775 71 MnF+ 0.52161E-16 -16.2827 0.43636E-16 -16.3602 0.83656E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46958E-09 -9.3283 0.39283E-09 -9.4058 0.83656E+00 -0.0775 74 MnO2-2 0.20874E-10 -10.6804 0.10804E-10 -10.9664 0.51761E+00 -0.2860 75 HMnO2- 0.21116E-09 -9.6754 0.17631E-09 -9.7537 0.83496E+00 -0.0783 78 MnCl+ 0.16550E-13 -13.7812 0.13845E-13 -13.8587 0.83656E+00 -0.0775 80 NaCl,aq 0.12822E-05 -5.8921 0.12822E-05 -5.8921 0.10000E+01 0.0000 81 NaF,aq 0.10437E-08 -8.9814 0.10437E-08 -8.9814 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93071E-02 -2.0312 0.77569E-02 -2.1103 0.83344E+00 -0.0791 89 HPO3-2 0.16284E-14 -14.7882 0.84289E-15 -15.0742 0.51761E+00 -0.2860 91 H2PO3- 0.15078E-18 -18.8216 0.12590E-18 -18.9000 0.83496E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38392E-10 -10.4158 0.32086E-10 -10.4937 0.83575E+00 -0.0779 94 PO4-3 0.10567E-08 -8.9760 0.25579E-09 -9.5921 0.24206E+00 -0.6161 98 HP2O7-3 0.93819E-18 -18.0277 0.21641E-18 -18.6647 0.23066E+00 -0.6370 99 P2O7-4 0.90422E-17 -17.0437 0.69409E-18 -18.1586 0.76761E-01 -1.1149 100 H2S,aq 0.11327E-07 -7.9459 0.11288E-07 -7.9474 0.99652E+00 -0.0015 101 S2-2 0.88862E-14 -14.0513 0.45996E-14 -14.3373 0.51761E+00 -0.2860 107 SO3-2 0.22103E-17 -17.6555 0.11607E-17 -17.9353 0.52513E+00 -0.2797 109 HSO4- 0.66106E-19 -19.1798 0.55356E-19 -19.2568 0.83738E+00 -0.0771 Charge balance for all species = -.7389E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8866992E-10 -.2222890E-01 -.2236636E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981956E+06 0.0000 3 Cl- 0.2782832E-03 0.2795660E-03 0.9894184E+01 6.4941 4 SO4-- 0.1486660E-11 -.4853923E-04 -.4654632E+01 8.1430 5 HCO3- 0.8804964E-06 0.4818291E-04 0.2934863E+01 3.9950 6 HS- 0.5871776E-04 0.1072683E-03 0.3541397E+01 5.8184 7 Al+++ 0.9831705E-29 0.5296488E-05 0.1426582E+00 0.7390 8 H4SiO4 0.6959790E-03 0.1349505E-01 0.1294822E+04 -3.1574 9 Ca++ 0.1362206E-06 0.2338964E-06 0.9357765E-02 13.1018 10 Mg++ 0.2131106E-10 0.9370346E-10 0.2274149E-05 9.2942 11 Fe++ 0.5873688E-13 0.3615771E-07 0.2015781E-02 6.7350 12 K+ 0.1571835E-03 0.1579378E-03 0.6164923E+01 6.2467 13 Na+ 0.1994592E-01 0.2239289E-01 0.5139110E+03 8.3494 14 Mn++ 0.1884300E-10 0.2526690E-08 0.1385695E-03 9.2416 15 F- 0.3213169E-06 0.3223611E-06 0.6113545E-02 3.5556 16 HPO4-- 0.4501177E-07 0.4610688E-07 0.4417582E-02 12.6242 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279253E+02 -.1103305E-01 -.8278150E+02 0.0000000E+00 2 H2O -.7168666E+01 0.2754919E+02 -.3471786E+02 0.0000000E+00 3 Cl- 0.1387592E-03 0.1387592E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385932E+00 -.2409186E-04 0.1386173E+00 0.0000000E+00 5 HCO3- 0.2391500E-04 0.2391500E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385641E+00 0.5324133E-04 -.1386173E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628847E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6698104E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1160916E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4650857E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794644E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7839051E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111444E-01 0.6265263E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254092E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1600000E-06 0.1600000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288459E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.2179E-14 Mass of aqueous solution: 0.497204E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.158 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2624 -0.581 56.83 1.755 1.040 17.37 hedenbergite 0.6805E-01 -1.167 16.88 1.227 0.3091 4.624 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.158 97.31 tr.625ac.25prg.125 0.4258E-01 -1.371 36.39 1.561 0.6662 11.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337911 g Volume = 2210.778273 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001500 moles log = -3.8239 Original solution: 1000.0103000 g Original solution / Rock added: 6666735.33 (Water/Rock Ratio), log = 6.8239 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1028 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9262E+00 0.9849 0.1006E+01 0.1021E+01 CO2,gas 0.1130E-07 1.0063 0.1254E-07 0.1246E-07 CH4,gas 0.5999E-01 1.0119 0.6694E-01 0.6615E-01 H2,gas 0.1378E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2826E-06 0.9957 0.3103E-06 0.3116E-06 S2,gas 0.1417E-28 1.0000 0.1563E-28 0.1563E-28 CO,gas 0.4607E-13 1.0000 0.5081E-13 0.5081E-13 SO3,gas 0.1467E-47 1.0000 0.1618E-47 0.1618E-47 SO2,gas 0.8678E-27 1.0000 0.9570E-27 0.9570E-27 HF,gas 0.3040E-15 1.0000 0.3352E-15 0.3352E-15 HCl,gas 0.5075E-17 1.0000 0.5596E-17 0.5596E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.26 -9.60 -3.200 0.16393E+05 -7.902 3 CH4,gas 4.54 1.67 -2.87 -0.718 0.49061E+04 -1.174 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.44 -8.21 -4.104 0.14014E+05 -6.508 6 S2,gas -7.34 -37.84 -30.51 -4.693 0.52087E+05 -28.806 7 CO,gas 3.21 -11.78 -14.99 -4.613 0.25600E+05 -13.294 8 SO3,gas 17.12 -32.37 -49.49 -12.373 0.84503E+05 -47.791 9 SO2,gas 0.83 -27.89 -28.72 -7.658 0.49035E+05 -27.019 10 HF,gas 0.47 -16.70 -17.17 -8.587 0.29324E+05 -15.475 11 HCl,gas 5.19 -13.76 -18.95 -9.476 0.32358E+05 -17.252 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.85 -0.55 -0.046 0.94378E+03 38 aragonite 0.97 -3.16 -4.13 -1.375 0.70443E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.16 -3.97 -1.324 0.67801E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.30 -4.19 -1.198 0.71592E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.30 -3.75 -1.071 0.64015E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.70 -3.44 -1.147 0.58774E+04 147 pyrrhotiteFe0.875 -6.02 -9.10 -3.08 -1.134 0.52646E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.70 -3.29 -1.097 0.56202E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.20 -4.22 -1.406 0.72021E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001500 MOLES New total amount of reactant added: 0.0001600 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3668E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001600 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142033E-01 Osmotic coef. = 0.9762 True ionic strength = .2010578E-01 Chg. balance for total moles = -.3668E-10 Max. difference allowed = 0.1388E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88672E-10 -10.0522 0.74486E-10 -10.1279 0.84002E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27840E-03 -3.5553 0.23245E-03 -3.6337 0.83495E+00 -0.0783 4 SO4-- 0.14990E-11 -11.8242 0.77757E-12 -12.1093 0.51872E+00 -0.2851 5 HCO3- 0.90710E-06 -6.0423 0.75850E-06 -6.1200 0.83618E+00 -0.0777 6 HS- 0.59207E-04 -4.2276 0.49443E-04 -4.3059 0.83508E+00 -0.0783 7 Al+++ 0.98324E-29 -29.0073 0.22657E-29 -29.6448 0.23043E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13623E-06 -6.8657 0.70142E-07 -7.1540 0.51490E+00 -0.2883 10 Mg++ 0.21312E-10 -10.6714 0.10923E-10 -10.9617 0.51253E+00 -0.2903 11 Fe++ 0.58739E-13 -13.2311 0.30139E-13 -13.5209 0.51310E+00 -0.2898 12 K+ 0.15719E-03 -3.8036 0.13147E-03 -3.8812 0.83638E+00 -0.0776 13 Na+ 0.19946E-01 -1.7001 0.16651E-01 -1.7786 0.83480E+00 -0.0784 14 Mn++ 0.18844E-10 -10.7248 0.96767E-11 -11.0143 0.51352E+00 -0.2894 15 F- 0.32935E-06 -6.4823 0.27442E-06 -6.5616 0.83323E+00 -0.0792 16 HPO4-- 0.45010E-07 -7.3467 0.23351E-07 -7.6317 0.51879E+00 -0.2850 18 HSiO3- 0.10449E-01 -1.9809 0.87246E-02 -2.0593 0.83495E+00 -0.0783 19 Ca(HSiO3)+ 0.16660E-07 -7.7783 0.13937E-07 -7.8558 0.83656E+00 -0.0775 20 Mg(HSiO3)+ 0.32287E-11 -11.4910 0.27010E-11 -11.5685 0.83656E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66409E-16 -16.1778 0.55555E-16 -16.2553 0.83656E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52962E-05 -5.2760 0.44141E-05 -5.3552 0.83344E+00 -0.0791 26 CH4,aq 0.47013E-04 -4.3278 0.46849E-04 -4.3293 0.99652E+00 -0.0015 27 C2H6,aq 0.32509E-13 -13.4880 0.32396E-13 -13.4895 0.99652E+00 -0.0015 31 CO,aq 0.35126E-16 -16.4544 0.35126E-16 -16.4544 0.10000E+01 0.0000 32 CO2,aq 0.12114E-09 -9.9167 0.12072E-09 -9.9182 0.99652E+00 -0.0015 33 CO3-2 0.17184E-05 -5.7649 0.88945E-06 -6.0509 0.51761E+00 -0.2860 34 CaCO3,aq 0.78228E-09 -9.1066 0.78228E-09 -9.1066 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.16234E-11 -11.7896 0.13581E-11 -11.8671 0.83656E+00 -0.0775 36 CaCl+ 0.31541E-10 -10.5011 0.26386E-10 -10.5786 0.83656E+00 -0.0775 37 CaCl2,aq 0.14572E-14 -14.8365 0.14572E-14 -14.8365 0.10000E+01 0.0000 38 CaF+ 0.33594E-12 -12.4737 0.28103E-12 -12.5512 0.83656E+00 -0.0775 39 CaOH+ 0.80225E-07 -7.0957 0.67113E-07 -7.1732 0.83656E+00 -0.0775 40 CaSO4,aq 0.17319E-16 -16.7615 0.17319E-16 -16.7615 0.10000E+01 0.0000 41 HCl,aq 0.31728E-14 -14.4986 0.31728E-14 -14.4986 0.10000E+01 0.0000 45 HF,aq 0.13993E-12 -12.8541 0.13993E-12 -12.8541 0.10000E+01 0.0000 46 HF2- 0.15528E-19 -19.8089 0.12965E-19 -19.8872 0.83495E+00 -0.0783 48 FeCl+ 0.13256E-16 -16.8776 0.11089E-16 -16.9551 0.83656E+00 -0.0775 51 FeF+ 0.50523E-18 -18.2965 0.42265E-18 -18.3740 0.83656E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15744E-10 -10.8029 0.13171E-10 -10.8804 0.83656E+00 -0.0775 55 HFeO2- 0.35519E-07 -7.4495 0.29657E-07 -7.5279 0.83495E+00 -0.0783 56 FeO+ 0.11034E-16 -16.9573 0.92308E-17 -17.0348 0.83656E+00 -0.0775 58 FeO2- 0.40773E-09 -9.3896 0.34044E-09 -9.4680 0.83495E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55387E-09 -9.2566 0.55387E-09 -9.2566 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.18999E-14 -14.7213 0.15863E-14 -14.7996 0.83495E+00 -0.0783 65 MgCO3,aq 0.30536E-13 -13.5152 0.30536E-13 -13.5152 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.25832E-15 -15.5878 0.21610E-15 -15.6653 0.83656E+00 -0.0775 67 MgCl+ 0.44518E-14 -14.3515 0.37242E-14 -14.4290 0.83656E+00 -0.0775 68 MgF+ 0.19379E-15 -15.7127 0.16212E-15 -15.7902 0.83656E+00 -0.0775 69 MgOH+ 0.69131E-10 -10.1603 0.57833E-10 -10.2378 0.83656E+00 -0.0775 71 MnF+ 0.53467E-16 -16.2719 0.44728E-16 -16.3494 0.83656E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46959E-09 -9.3283 0.39284E-09 -9.4058 0.83656E+00 -0.0775 74 MnO2-2 0.20873E-10 -10.6804 0.10804E-10 -10.9664 0.51761E+00 -0.2860 75 HMnO2- 0.21116E-09 -9.6754 0.17631E-09 -9.7537 0.83495E+00 -0.0783 78 MnCl+ 0.16558E-13 -13.7810 0.13852E-13 -13.8585 0.83656E+00 -0.0775 80 NaCl,aq 0.12827E-05 -5.8919 0.12827E-05 -5.8919 0.10000E+01 0.0000 81 NaF,aq 0.10698E-08 -8.9707 0.10698E-08 -8.9707 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93069E-02 -2.0312 0.77568E-02 -2.1103 0.83344E+00 -0.0791 89 HPO3-2 0.16284E-14 -14.7883 0.84286E-15 -15.0742 0.51761E+00 -0.2860 91 H2PO3- 0.15078E-18 -18.8217 0.12589E-18 -18.9000 0.83495E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38392E-10 -10.4158 0.32086E-10 -10.4937 0.83575E+00 -0.0779 94 PO4-3 0.10567E-08 -8.9761 0.25578E-09 -9.5921 0.24206E+00 -0.6161 98 HP2O7-3 0.93815E-18 -18.0277 0.21640E-18 -18.6648 0.23066E+00 -0.6370 99 P2O7-4 0.90418E-17 -17.0437 0.69404E-18 -18.1586 0.76759E-01 -1.1149 100 H2S,aq 0.11422E-07 -7.9423 0.11382E-07 -7.9438 0.99652E+00 -0.0015 101 S2-2 0.90350E-14 -14.0441 0.46766E-14 -14.3301 0.51761E+00 -0.2860 107 SO3-2 0.22287E-17 -17.6519 0.11704E-17 -17.9317 0.52512E+00 -0.2797 109 HSO4- 0.66657E-19 -19.1762 0.55817E-19 -19.2532 0.83738E+00 -0.0771 Charge balance for all species = -.7389E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8867170E-10 -.2222862E-01 -.2236607E+02 0.0000 2 H2O 0.1000000E+01 0.5550492E+02 0.9981956E+06 0.0000 3 Cl- 0.2784014E-03 0.2796848E-03 0.9898386E+01 6.4943 4 SO4-- 0.1499031E-11 -.4991887E-04 -.4786932E+01 8.1466 5 HCO3- 0.9071012E-06 0.4963956E-04 0.3023589E+01 4.0079 6 HS- 0.5920723E-04 0.1091375E-03 0.3603107E+01 5.8220 7 Al+++ 0.9832390E-29 0.5296397E-05 0.1426557E+00 0.7390 8 H4SiO4 0.6959790E-03 0.1349487E-01 0.1294805E+04 -3.1574 9 Ca++ 0.1362265E-06 0.2339272E-06 0.9359001E-02 13.1018 10 Mg++ 0.2131198E-10 0.9370701E-10 0.2274235E-05 9.2942 11 Fe++ 0.5873944E-13 0.3615709E-07 0.2015747E-02 6.7350 12 K+ 0.1571866E-03 0.1579410E-03 0.6165046E+01 6.2467 13 Na+ 0.1994632E-01 0.2239329E-01 0.5139202E+03 8.3494 14 Mn++ 0.1884383E-10 0.2526699E-08 0.1385699E-03 9.2416 15 F- 0.3293497E-06 0.3304200E-06 0.6266381E-02 3.5663 16 HPO4-- 0.4501036E-07 0.4610542E-07 0.4417442E-02 12.6242 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279253E+02 -.1103291E-01 -.8278150E+02 0.0000000E+00 2 H2O -.7168658E+01 0.2754921E+02 -.3471786E+02 0.0000000E+00 3 Cl- 0.1388182E-03 0.1388182E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385933E+00 -.2477664E-04 0.1386181E+00 0.0000000E+00 5 HCO3- 0.2463800E-04 0.2463800E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385639E+00 0.5416911E-04 -.1386181E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628803E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6698018E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1161070E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4651035E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794614E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7839210E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111464E-01 0.6265262E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254097E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1640000E-06 0.1640000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288387E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1265E-13 Mass of aqueous solution: 0.497204E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001600 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.158 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2624 -0.581 56.82 1.755 1.040 17.37 hedenbergite 0.6805E-01 -1.167 16.88 1.227 0.3091 4.624 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4258E-01 -1.371 36.40 1.561 0.6663 11.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337914 g Volume = 2210.778301 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001600 moles log = -3.7959 Original solution: 1000.0103000 g Original solution / Rock added: 6250064.38 (Water/Rock Ratio), log = 6.7959 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1048 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9246E+00 0.9848 0.1006E+01 0.1021E+01 CO2,gas 0.1162E-07 1.0063 0.1292E-07 0.1284E-07 CH4,gas 0.6169E-01 1.0118 0.6896E-01 0.6815E-01 H2,gas 0.1376E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2844E-06 0.9957 0.3129E-06 0.3142E-06 S2,gas 0.1438E-28 1.0000 0.1589E-28 0.1589E-28 CO,gas 0.4738E-13 1.0000 0.5234E-13 0.5234E-13 SO3,gas 0.1476E-47 1.0000 0.1631E-47 0.1631E-47 SO2,gas 0.8735E-27 1.0000 0.9650E-27 0.9650E-27 HF,gas 0.3110E-15 1.0000 0.3436E-15 0.3436E-15 HCl,gas 0.5067E-17 1.0000 0.5598E-17 0.5598E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.25 -9.59 -3.196 0.16371E+05 -7.889 3 CH4,gas 4.54 1.68 -2.86 -0.715 0.48840E+04 -1.161 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.43 -8.20 -4.102 0.14007E+05 -6.505 6 S2,gas -7.34 -37.83 -30.50 -4.692 0.52074E+05 -28.799 7 CO,gas 3.21 -11.77 -14.98 -4.609 0.25578E+05 -13.281 8 SO3,gas 17.12 -32.37 -49.49 -12.372 0.84497E+05 -47.787 9 SO2,gas 0.83 -27.88 -28.71 -7.657 0.49029E+05 -27.015 10 HF,gas 0.47 -16.69 -17.16 -8.581 0.29305E+05 -15.464 11 HCl,gas 5.19 -13.76 -18.95 -9.475 0.32358E+05 -17.252 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.84 -0.54 -0.045 0.92546E+03 38 aragonite 0.97 -3.15 -4.11 -1.371 0.70223E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.15 -3.96 -1.319 0.67580E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.28 -4.18 -1.194 0.71371E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.28 -3.74 -1.067 0.63794E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.70 -3.44 -1.146 0.58712E+04 147 pyrrhotiteFe0.875 -6.02 -9.10 -3.08 -1.133 0.52584E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.70 -3.29 -1.096 0.56140E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.19 -4.21 -1.405 0.71959E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001600 MOLES New total amount of reactant added: 0.0001700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3668E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141950E-01 Osmotic coef. = 0.9767 True ionic strength = .2010624E-01 Chg. balance for total moles = -.3668E-10 Max. difference allowed = 0.1389E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88673E-10 -10.0522 0.74488E-10 -10.1279 0.84002E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27852E-03 -3.5551 0.23255E-03 -3.6335 0.83495E+00 -0.0783 4 SO4-- 0.15114E-11 -11.8206 0.78398E-12 -12.1057 0.51871E+00 -0.2851 5 HCO3- 0.93371E-06 -6.0298 0.78074E-06 -6.1075 0.83618E+00 -0.0777 6 HS- 0.59697E-04 -4.2240 0.49851E-04 -4.3023 0.83508E+00 -0.0783 7 Al+++ 0.98331E-29 -29.0073 0.22658E-29 -29.6448 0.23043E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13623E-06 -6.8657 0.70145E-07 -7.1540 0.51489E+00 -0.2883 10 Mg++ 0.21313E-10 -10.6714 0.10923E-10 -10.9616 0.51253E+00 -0.2903 11 Fe++ 0.58742E-13 -13.2311 0.30140E-13 -13.5209 0.51309E+00 -0.2898 12 K+ 0.15719E-03 -3.8036 0.13147E-03 -3.8812 0.83638E+00 -0.0776 13 Na+ 0.19947E-01 -1.7001 0.16652E-01 -1.7785 0.83480E+00 -0.0784 14 Mn++ 0.18845E-10 -10.7248 0.96771E-11 -11.0143 0.51352E+00 -0.2894 15 F- 0.33738E-06 -6.4719 0.28112E-06 -6.5511 0.83323E+00 -0.0792 16 HPO4-- 0.45009E-07 -7.3467 0.23350E-07 -7.6317 0.51879E+00 -0.2850 18 HSiO3- 0.10449E-01 -1.9809 0.87245E-02 -2.0593 0.83495E+00 -0.0783 19 Ca(HSiO3)+ 0.16660E-07 -7.7783 0.13937E-07 -7.8558 0.83656E+00 -0.0775 20 Mg(HSiO3)+ 0.32288E-11 -11.4910 0.27011E-11 -11.5685 0.83656E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66410E-16 -16.1778 0.55556E-16 -16.2553 0.83656E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52962E-05 -5.2760 0.44140E-05 -5.3552 0.83344E+00 -0.0791 26 CH4,aq 0.48393E-04 -4.3152 0.48224E-04 -4.3167 0.99652E+00 -0.0015 27 C2H6,aq 0.34445E-13 -13.4629 0.34325E-13 -13.4644 0.99652E+00 -0.0015 31 CO,aq 0.36157E-16 -16.4418 0.36157E-16 -16.4418 0.10000E+01 0.0000 32 CO2,aq 0.12470E-09 -9.9041 0.12427E-09 -9.9057 0.99652E+00 -0.0015 33 CO3-2 0.17688E-05 -5.7523 0.91552E-06 -6.0383 0.51761E+00 -0.2860 34 CaCO3,aq 0.80524E-09 -9.0941 0.80524E-09 -9.0941 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.16711E-11 -11.7770 0.13979E-11 -11.8545 0.83656E+00 -0.0775 36 CaCl+ 0.31556E-10 -10.5009 0.26398E-10 -10.5784 0.83656E+00 -0.0775 37 CaCl2,aq 0.14585E-14 -14.8361 0.14585E-14 -14.8361 0.10000E+01 0.0000 38 CaF+ 0.34415E-12 -12.4633 0.28790E-12 -12.5408 0.83656E+00 -0.0775 39 CaOH+ 0.80227E-07 -7.0957 0.67114E-07 -7.1732 0.83656E+00 -0.0775 40 CaSO4,aq 0.17463E-16 -16.7579 0.17463E-16 -16.7579 0.10000E+01 0.0000 41 HCl,aq 0.31742E-14 -14.4984 0.31742E-14 -14.4984 0.10000E+01 0.0000 45 HF,aq 0.14335E-12 -12.8436 0.14335E-12 -12.8436 0.10000E+01 0.0000 46 HF2- 0.16295E-19 -19.7880 0.13605E-19 -19.8663 0.83495E+00 -0.0783 48 FeCl+ 0.13262E-16 -16.8774 0.11094E-16 -16.9549 0.83656E+00 -0.0775 51 FeF+ 0.51757E-18 -18.2860 0.43298E-18 -18.3635 0.83656E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15745E-10 -10.8029 0.13171E-10 -10.8804 0.83656E+00 -0.0775 55 HFeO2- 0.35519E-07 -7.4495 0.29656E-07 -7.5279 0.83495E+00 -0.0783 56 FeO+ 0.11034E-16 -16.9572 0.92310E-17 -17.0348 0.83656E+00 -0.0775 58 FeO2- 0.40772E-09 -9.3896 0.34043E-09 -9.4680 0.83495E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55412E-09 -9.2564 0.55412E-09 -9.2564 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.19156E-14 -14.7177 0.15994E-14 -14.7960 0.83495E+00 -0.0783 65 MgCO3,aq 0.31432E-13 -13.5026 0.31432E-13 -13.5026 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.26591E-15 -15.5753 0.22245E-15 -15.6528 0.83656E+00 -0.0775 67 MgCl+ 0.44539E-14 -14.3513 0.37259E-14 -14.4288 0.83656E+00 -0.0775 68 MgF+ 0.19852E-15 -15.7022 0.16608E-15 -15.7797 0.83656E+00 -0.0775 69 MgOH+ 0.69133E-10 -10.1603 0.57834E-10 -10.2378 0.83656E+00 -0.0775 71 MnF+ 0.54773E-16 -16.2614 0.45821E-16 -16.3389 0.83656E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46960E-09 -9.3283 0.39285E-09 -9.4058 0.83656E+00 -0.0775 74 MnO2-2 0.20872E-10 -10.6804 0.10804E-10 -10.9664 0.51761E+00 -0.2860 75 HMnO2- 0.21116E-09 -9.6754 0.17631E-09 -9.7537 0.83495E+00 -0.0783 78 MnCl+ 0.16565E-13 -13.7808 0.13858E-13 -13.8583 0.83656E+00 -0.0775 80 NaCl,aq 0.12833E-05 -5.8917 0.12833E-05 -5.8917 0.10000E+01 0.0000 81 NaF,aq 0.10959E-08 -8.9602 0.10959E-08 -8.9602 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93068E-02 -2.0312 0.77566E-02 -2.1103 0.83344E+00 -0.0791 89 HPO3-2 0.16283E-14 -14.7883 0.84282E-15 -15.0743 0.51761E+00 -0.2860 91 H2PO3- 0.15078E-18 -18.8217 0.12589E-18 -18.9000 0.83495E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38391E-10 -10.4158 0.32085E-10 -10.4937 0.83575E+00 -0.0779 94 PO4-3 0.10566E-08 -8.9761 0.25576E-09 -9.5922 0.24206E+00 -0.6161 98 HP2O7-3 0.93811E-18 -18.0277 0.21638E-18 -18.6648 0.23066E+00 -0.6370 99 P2O7-4 0.90413E-17 -17.0438 0.69398E-18 -18.1587 0.76757E-01 -1.1149 100 H2S,aq 0.11517E-07 -7.9387 0.11476E-07 -7.9402 0.99652E+00 -0.0015 101 S2-2 0.91850E-14 -14.0369 0.47542E-14 -14.3229 0.51761E+00 -0.2860 107 SO3-2 0.22471E-17 -17.6484 0.11800E-17 -17.9281 0.52512E+00 -0.2797 109 HSO4- 0.67208E-19 -19.1726 0.56278E-19 -19.2497 0.83737E+00 -0.0771 Charge balance for all species = -.7384E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8867348E-10 -.2222833E-01 -.2236578E+02 0.0000 2 H2O 0.1000000E+01 0.5550493E+02 0.9981956E+06 0.0000 3 Cl- 0.2785196E-03 0.2798035E-03 0.9902589E+01 6.4944 4 SO4-- 0.1511402E-11 -.5129852E-04 -.4919231E+01 8.1501 5 HCO3- 0.9337052E-06 0.5109621E-04 0.3112315E+01 4.0204 6 HS- 0.5969670E-04 0.1110067E-03 0.3664818E+01 5.8256 7 Al+++ 0.9833074E-29 0.5296307E-05 0.1426533E+00 0.7390 8 H4SiO4 0.6959790E-03 0.1349469E-01 0.1294788E+04 -3.1574 9 Ca++ 0.1362324E-06 0.2339581E-06 0.9360236E-02 13.1018 10 Mg++ 0.2131291E-10 0.9371055E-10 0.2274321E-05 9.2942 11 Fe++ 0.5874199E-13 0.3615647E-07 0.2015712E-02 6.7350 12 K+ 0.1571898E-03 0.1579441E-03 0.6165170E+01 6.2467 13 Na+ 0.1994672E-01 0.2239369E-01 0.5139294E+03 8.3494 14 Mn++ 0.1884467E-10 0.2526707E-08 0.1385704E-03 9.2416 15 F- 0.3373825E-06 0.3384789E-06 0.6419217E-02 3.5768 16 HPO4-- 0.4500895E-07 0.4610396E-07 0.4417302E-02 12.6241 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279253E+02 -.1103277E-01 -.8278150E+02 0.0000000E+00 2 H2O -.7168650E+01 0.2754922E+02 -.3471787E+02 0.0000000E+00 3 Cl- 0.1388772E-03 0.1388772E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385933E+00 -.2546142E-04 0.1386188E+00 0.0000000E+00 5 HCO3- 0.2536100E-04 0.2536100E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385637E+00 0.5509689E-04 -.1386188E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628759E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6697932E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1161224E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4651213E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794584E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7839370E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111484E-01 0.6265262E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254101E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1680000E-06 0.1680000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288316E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.2223E-13 Mass of aqueous solution: 0.497205E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.158 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2624 -0.581 56.82 1.754 1.040 17.37 hedenbergite 0.6804E-01 -1.167 16.88 1.227 0.3090 4.624 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4259E-01 -1.371 36.40 1.561 0.6664 11.72 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337918 g Volume = 2210.778329 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001700 moles log = -3.7696 Original solution: 1000.0103000 g Original solution / Rock added: 5882413.53 (Water/Rock Ratio), log = 6.7696 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1068 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9229E+00 0.9848 0.1006E+01 0.1021E+01 CO2,gas 0.1194E-07 1.0062 0.1330E-07 0.1321E-07 CH4,gas 0.6338E-01 1.0118 0.7098E-01 0.7015E-01 H2,gas 0.1373E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2863E-06 0.9957 0.3155E-06 0.3168E-06 S2,gas 0.1460E-28 1.0000 0.1616E-28 0.1616E-28 CO,gas 0.4868E-13 1.0000 0.5388E-13 0.5388E-13 SO3,gas 0.1486E-47 1.0000 0.1645E-47 0.1645E-47 SO2,gas 0.8791E-27 1.0000 0.9730E-27 0.9730E-27 HF,gas 0.3180E-15 1.0000 0.3520E-15 0.3520E-15 HCl,gas 0.5060E-17 1.0000 0.5601E-17 0.5601E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.24 -9.58 -3.192 0.16350E+05 -7.876 3 CH4,gas 4.54 1.70 -2.85 -0.712 0.48626E+04 -1.149 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.43 -8.20 -4.100 0.14001E+05 -6.501 6 S2,gas -7.34 -37.83 -30.49 -4.691 0.52062E+05 -28.792 7 CO,gas 3.21 -11.75 -14.97 -4.605 0.25557E+05 -13.269 8 SO3,gas 17.12 -32.36 -49.48 -12.371 0.84491E+05 -47.784 9 SO2,gas 0.83 -27.88 -28.71 -7.656 0.49023E+05 -27.012 10 HF,gas 0.47 -16.68 -17.15 -8.576 0.29287E+05 -15.453 11 HCl,gas 5.19 -13.76 -18.95 -9.475 0.32358E+05 -17.252 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.83 -0.53 -0.044 0.90758E+03 38 aragonite 0.97 -3.13 -4.10 -1.367 0.70008E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.13 -3.95 -1.315 0.67366E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.27 -4.17 -1.191 0.71157E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.27 -3.72 -1.064 0.63579E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.70 -3.43 -1.145 0.58651E+04 147 pyrrhotiteFe0.875 -6.02 -9.09 -3.08 -1.131 0.52523E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.70 -3.28 -1.095 0.56079E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.19 -4.21 -1.404 0.71898E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001700 MOLES New total amount of reactant added: 0.0001800 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3667E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001800 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141867E-01 Osmotic coef. = 0.9773 True ionic strength = .2010669E-01 Chg. balance for total moles = -.3667E-10 Max. difference allowed = 0.1389E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88675E-10 -10.0522 0.74489E-10 -10.1279 0.84002E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27864E-03 -3.5550 0.23265E-03 -3.6333 0.83495E+00 -0.0783 4 SO4-- 0.15238E-11 -11.8171 0.79040E-12 -12.1022 0.51871E+00 -0.2851 5 HCO3- 0.96031E-06 -6.0176 0.80299E-06 -6.0953 0.83618E+00 -0.0777 6 HS- 0.60186E-04 -4.2205 0.50260E-04 -4.2988 0.83507E+00 -0.0783 7 Al+++ 0.98338E-29 -29.0073 0.22659E-29 -29.6448 0.23042E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13624E-06 -6.8657 0.70148E-07 -7.1540 0.51489E+00 -0.2883 10 Mg++ 0.21314E-10 -10.6713 0.10924E-10 -10.9616 0.51253E+00 -0.2903 11 Fe++ 0.58745E-13 -13.2310 0.30141E-13 -13.5208 0.51309E+00 -0.2898 12 K+ 0.15719E-03 -3.8036 0.13147E-03 -3.8812 0.83638E+00 -0.0776 13 Na+ 0.19947E-01 -1.7001 0.16652E-01 -1.7785 0.83480E+00 -0.0784 14 Mn++ 0.18846E-10 -10.7248 0.96775E-11 -11.0142 0.51352E+00 -0.2894 15 F- 0.34542E-06 -6.4617 0.28781E-06 -6.5409 0.83323E+00 -0.0792 16 HPO4-- 0.45008E-07 -7.3467 0.23349E-07 -7.6317 0.51878E+00 -0.2850 18 HSiO3- 0.10449E-01 -1.9809 0.87243E-02 -2.0593 0.83495E+00 -0.0783 19 Ca(HSiO3)+ 0.16660E-07 -7.7783 0.13937E-07 -7.8558 0.83656E+00 -0.0775 20 Mg(HSiO3)+ 0.32289E-11 -11.4910 0.27011E-11 -11.5685 0.83656E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66412E-16 -16.1778 0.55557E-16 -16.2553 0.83656E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52961E-05 -5.2760 0.44139E-05 -5.3552 0.83344E+00 -0.0791 26 CH4,aq 0.49772E-04 -4.3030 0.49599E-04 -4.3045 0.99652E+00 -0.0015 27 C2H6,aq 0.36437E-13 -13.4385 0.36310E-13 -13.4400 0.99652E+00 -0.0015 31 CO,aq 0.37187E-16 -16.4296 0.37187E-16 -16.4296 0.10000E+01 0.0000 32 CO2,aq 0.12825E-09 -9.8919 0.12781E-09 -9.8934 0.99652E+00 -0.0015 33 CO3-2 0.18191E-05 -5.7401 0.94159E-06 -6.0261 0.51761E+00 -0.2860 34 CaCO3,aq 0.82819E-09 -9.0819 0.82819E-09 -9.0819 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.17187E-11 -11.7648 0.14378E-11 -11.8423 0.83656E+00 -0.0775 36 CaCl+ 0.31571E-10 -10.5007 0.26411E-10 -10.5782 0.83656E+00 -0.0775 37 CaCl2,aq 0.14598E-14 -14.8357 0.14598E-14 -14.8357 0.10000E+01 0.0000 38 CaF+ 0.35235E-12 -12.4530 0.29476E-12 -12.5305 0.83656E+00 -0.0775 39 CaOH+ 0.80229E-07 -7.0957 0.67116E-07 -7.1732 0.83656E+00 -0.0775 40 CaSO4,aq 0.17606E-16 -16.7543 0.17606E-16 -16.7543 0.10000E+01 0.0000 41 HCl,aq 0.31756E-14 -14.4982 0.31756E-14 -14.4982 0.10000E+01 0.0000 45 HF,aq 0.14676E-12 -12.8334 0.14676E-12 -12.8334 0.10000E+01 0.0000 46 HF2- 0.17080E-19 -19.7675 0.14261E-19 -19.8458 0.83495E+00 -0.0783 48 FeCl+ 0.13268E-16 -16.8772 0.11099E-16 -16.9547 0.83656E+00 -0.0775 51 FeF+ 0.52991E-18 -18.2758 0.44330E-18 -18.3533 0.83656E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15745E-10 -10.8029 0.13171E-10 -10.8804 0.83656E+00 -0.0775 55 HFeO2- 0.35518E-07 -7.4496 0.29656E-07 -7.5279 0.83495E+00 -0.0783 56 FeO+ 0.11035E-16 -16.9572 0.92312E-17 -17.0347 0.83656E+00 -0.0775 58 FeO2- 0.40772E-09 -9.3896 0.34042E-09 -9.4680 0.83495E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55436E-09 -9.2562 0.55436E-09 -9.2562 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.19313E-14 -14.7142 0.16125E-14 -14.7925 0.83495E+00 -0.0783 65 MgCO3,aq 0.32328E-13 -13.4904 0.32328E-13 -13.4904 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.27349E-15 -15.5631 0.22879E-15 -15.6406 0.83656E+00 -0.0775 67 MgCl+ 0.44559E-14 -14.3511 0.37276E-14 -14.4286 0.83656E+00 -0.0775 68 MgF+ 0.20326E-15 -15.6920 0.17004E-15 -15.7695 0.83656E+00 -0.0775 69 MgOH+ 0.69134E-10 -10.1603 0.57835E-10 -10.2378 0.83656E+00 -0.0775 71 MnF+ 0.56080E-16 -16.2512 0.46914E-16 -16.3287 0.83656E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46961E-09 -9.3283 0.39286E-09 -9.4058 0.83656E+00 -0.0775 74 MnO2-2 0.20872E-10 -10.6804 0.10803E-10 -10.9664 0.51761E+00 -0.2860 75 HMnO2- 0.21115E-09 -9.6754 0.17630E-09 -9.7537 0.83495E+00 -0.0783 78 MnCl+ 0.16573E-13 -13.7806 0.13864E-13 -13.8581 0.83656E+00 -0.0775 80 NaCl,aq 0.12839E-05 -5.8915 0.12839E-05 -5.8915 0.10000E+01 0.0000 81 NaF,aq 0.11220E-08 -8.9500 0.11220E-08 -8.9500 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93066E-02 -2.0312 0.77565E-02 -2.1103 0.83344E+00 -0.0791 89 HPO3-2 0.16283E-14 -14.7883 0.84279E-15 -15.0743 0.51761E+00 -0.2860 91 H2PO3- 0.15078E-18 -18.8217 0.12589E-18 -18.9000 0.83495E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38390E-10 -10.4158 0.32085E-10 -10.4937 0.83575E+00 -0.0779 94 PO4-3 0.10566E-08 -8.9761 0.25575E-09 -9.5922 0.24205E+00 -0.6161 98 HP2O7-3 0.93807E-18 -18.0278 0.21637E-18 -18.6648 0.23066E+00 -0.6370 99 P2O7-4 0.90408E-17 -17.0438 0.69393E-18 -18.1587 0.76755E-01 -1.1149 100 H2S,aq 0.11611E-07 -7.9351 0.11571E-07 -7.9366 0.99652E+00 -0.0015 101 S2-2 0.93362E-14 -14.0298 0.48325E-14 -14.3158 0.51761E+00 -0.2860 107 SO3-2 0.22655E-17 -17.6448 0.11897E-17 -17.9246 0.52512E+00 -0.2797 109 HSO4- 0.67759E-19 -19.1690 0.56740E-19 -19.2461 0.83737E+00 -0.0771 Charge balance for all species = -.7388E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8867527E-10 -.2222804E-01 -.2236549E+02 0.0000 2 H2O 0.1000000E+01 0.5550493E+02 0.9981955E+06 0.0000 3 Cl- 0.2786378E-03 0.2799223E-03 0.9906792E+01 6.4946 4 SO4-- 0.1523773E-11 -.5267817E-04 -.5051532E+01 8.1537 5 HCO3- 0.9603084E-06 0.5255286E-04 0.3201041E+01 4.0326 6 HS- 0.6018617E-04 0.1128759E-03 0.3726529E+01 5.8291 7 Al+++ 0.9833759E-29 0.5296216E-05 0.1426509E+00 0.7390 8 H4SiO4 0.6959789E-03 0.1349451E-01 0.1294770E+04 -3.1574 9 Ca++ 0.1362383E-06 0.2339890E-06 0.9361472E-02 13.1018 10 Mg++ 0.2131384E-10 0.9371409E-10 0.2274407E-05 9.2942 11 Fe++ 0.5874455E-13 0.3615586E-07 0.2015678E-02 6.7350 12 K+ 0.1571930E-03 0.1579473E-03 0.6165293E+01 6.2467 13 Na+ 0.1994712E-01 0.2239409E-01 0.5139386E+03 8.3494 14 Mn++ 0.1884551E-10 0.2526716E-08 0.1385708E-03 9.2416 15 F- 0.3454152E-06 0.3465378E-06 0.6572053E-02 3.5870 16 HPO4-- 0.4500753E-07 0.4610250E-07 0.4417162E-02 12.6241 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279253E+02 -.1103263E-01 -.8278150E+02 0.0000000E+00 2 H2O -.7168641E+01 0.2754923E+02 -.3471787E+02 0.0000000E+00 3 Cl- 0.1389362E-03 0.1389362E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385934E+00 -.2614620E-04 0.1386195E+00 0.0000000E+00 5 HCO3- 0.2608400E-04 0.2608400E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385635E+00 0.5602467E-04 -.1386195E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628716E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6697845E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1161377E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4651390E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794554E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7839530E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111505E-01 0.6265262E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254106E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1720000E-06 0.1720000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288244E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.8188E-15 Mass of aqueous solution: 0.497205E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001800 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.158 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2623 -0.581 56.81 1.754 1.040 17.36 hedenbergite 0.6804E-01 -1.167 16.88 1.227 0.3090 4.623 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4259E-01 -1.371 36.41 1.561 0.6665 11.72 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337921 g Volume = 2210.778357 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001800 moles log = -3.7447 Original solution: 1000.0103000 g Original solution / Rock added: 5555612.78 (Water/Rock Ratio), log = 6.7447 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1088 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9212E+00 0.9848 0.1006E+01 0.1021E+01 CO2,gas 0.1226E-07 1.0062 0.1367E-07 0.1359E-07 CH4,gas 0.6507E-01 1.0118 0.7301E-01 0.7216E-01 H2,gas 0.1371E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2881E-06 0.9957 0.3181E-06 0.3194E-06 S2,gas 0.1481E-28 1.0000 0.1642E-28 0.1642E-28 CO,gas 0.4998E-13 1.0000 0.5542E-13 0.5542E-13 SO3,gas 0.1495E-47 1.0000 0.1658E-47 0.1658E-47 SO2,gas 0.8847E-27 1.0000 0.9810E-27 0.9810E-27 HF,gas 0.3250E-15 1.0000 0.3604E-15 0.3604E-15 HCl,gas 0.5053E-17 1.0000 0.5603E-17 0.5603E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.22 -9.56 -3.188 0.16329E+05 -7.864 3 CH4,gas 4.54 1.71 -2.84 -0.709 0.48417E+04 -1.137 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.43 -8.20 -4.098 0.13995E+05 -6.497 6 S2,gas -7.34 -37.82 -30.48 -4.690 0.52050E+05 -28.785 7 CO,gas 3.21 -11.74 -14.96 -4.602 0.25536E+05 -13.256 8 SO3,gas 17.12 -32.36 -49.48 -12.370 0.84485E+05 -47.780 9 SO2,gas 0.83 -27.88 -28.71 -7.655 0.49017E+05 -27.008 10 HF,gas 0.47 -16.67 -17.14 -8.571 0.29270E+05 -15.443 11 HCl,gas 5.19 -13.76 -18.95 -9.475 0.32357E+05 -17.252 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.82 -0.52 -0.043 0.89012E+03 38 aragonite 0.97 -3.12 -4.09 -1.363 0.69800E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.12 -3.93 -1.311 0.67157E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.26 -4.16 -1.187 0.70948E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.26 -3.71 -1.060 0.63371E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.69 -3.43 -1.144 0.58590E+04 147 pyrrhotiteFe0.875 -6.02 -9.09 -3.07 -1.130 0.52462E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.69 -3.28 -1.094 0.56018E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.19 -4.21 -1.402 0.71837E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001800 MOLES New total amount of reactant added: 0.0001900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3668E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0001900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141784E-01 Osmotic coef. = 0.9779 True ionic strength = .2010715E-01 Chg. balance for total moles = -.3668E-10 Max. difference allowed = 0.1390E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88677E-10 -10.0522 0.74490E-10 -10.1279 0.84002E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27876E-03 -3.5548 0.23275E-03 -3.6331 0.83495E+00 -0.0783 4 SO4-- 0.15361E-11 -11.8136 0.79681E-12 -12.0986 0.51871E+00 -0.2851 5 HCO3- 0.98691E-06 -6.0057 0.82523E-06 -6.0834 0.83618E+00 -0.0777 6 HS- 0.60676E-04 -4.2170 0.50669E-04 -4.2953 0.83507E+00 -0.0783 7 Al+++ 0.98344E-29 -29.0073 0.22661E-29 -29.6447 0.23042E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13624E-06 -6.8657 0.70150E-07 -7.1540 0.51489E+00 -0.2883 10 Mg++ 0.21315E-10 -10.6713 0.10924E-10 -10.9616 0.51252E+00 -0.2903 11 Fe++ 0.58747E-13 -13.2310 0.30142E-13 -13.5208 0.51309E+00 -0.2898 12 K+ 0.15720E-03 -3.8036 0.13147E-03 -3.8812 0.83637E+00 -0.0776 13 Na+ 0.19948E-01 -1.7001 0.16652E-01 -1.7785 0.83480E+00 -0.0784 14 Mn++ 0.18846E-10 -10.7248 0.96778E-11 -11.0142 0.51351E+00 -0.2894 15 F- 0.35345E-06 -6.4517 0.29450E-06 -6.5309 0.83322E+00 -0.0792 16 HPO4-- 0.45006E-07 -7.3467 0.23348E-07 -7.6317 0.51878E+00 -0.2850 18 HSiO3- 0.10449E-01 -1.9809 0.87241E-02 -2.0593 0.83495E+00 -0.0783 19 Ca(HSiO3)+ 0.16661E-07 -7.7783 0.13938E-07 -7.8558 0.83655E+00 -0.0775 20 Mg(HSiO3)+ 0.32289E-11 -11.4909 0.27012E-11 -11.5684 0.83655E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66413E-16 -16.1777 0.55558E-16 -16.2553 0.83655E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52960E-05 -5.2761 0.44139E-05 -5.3552 0.83344E+00 -0.0791 26 CH4,aq 0.51152E-04 -4.2911 0.50974E-04 -4.2927 0.99652E+00 -0.0015 27 C2H6,aq 0.38485E-13 -13.4147 0.38351E-13 -13.4162 0.99652E+00 -0.0015 31 CO,aq 0.38218E-16 -16.4177 0.38218E-16 -16.4177 0.10000E+01 0.0000 32 CO2,aq 0.13181E-09 -9.8801 0.13135E-09 -9.8816 0.99652E+00 -0.0015 33 CO3-2 0.18695E-05 -5.7283 0.96765E-06 -6.0143 0.51760E+00 -0.2860 34 CaCO3,aq 0.85115E-09 -9.0700 0.85115E-09 -9.0700 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.17664E-11 -11.7529 0.14777E-11 -11.8304 0.83655E+00 -0.0775 36 CaCl+ 0.31585E-10 -10.5005 0.26423E-10 -10.5780 0.83655E+00 -0.0775 37 CaCl2,aq 0.14611E-14 -14.8353 0.14611E-14 -14.8353 0.10000E+01 0.0000 38 CaF+ 0.36056E-12 -12.4430 0.30163E-12 -12.5205 0.83655E+00 -0.0775 39 CaOH+ 0.80230E-07 -7.0957 0.67117E-07 -7.1732 0.83655E+00 -0.0775 40 CaSO4,aq 0.17750E-16 -16.7508 0.17750E-16 -16.7508 0.10000E+01 0.0000 41 HCl,aq 0.31770E-14 -14.4980 0.31770E-14 -14.4980 0.10000E+01 0.0000 45 HF,aq 0.15018E-12 -12.8234 0.15018E-12 -12.8234 0.10000E+01 0.0000 46 HF2- 0.17884E-19 -19.7475 0.14932E-19 -19.8259 0.83495E+00 -0.0783 48 FeCl+ 0.13274E-16 -16.8770 0.11104E-16 -16.9545 0.83655E+00 -0.0775 51 FeF+ 0.54226E-18 -18.2658 0.45363E-18 -18.3433 0.83655E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15745E-10 -10.8029 0.13172E-10 -10.8804 0.83655E+00 -0.0775 55 HFeO2- 0.35517E-07 -7.4496 0.29655E-07 -7.5279 0.83495E+00 -0.0783 56 FeO+ 0.11035E-16 -16.9572 0.92313E-17 -17.0347 0.83655E+00 -0.0775 58 FeO2- 0.40771E-09 -9.3896 0.34042E-09 -9.4680 0.83495E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55461E-09 -9.2560 0.55461E-09 -9.2560 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.19470E-14 -14.7106 0.16256E-14 -14.7890 0.83495E+00 -0.0783 65 MgCO3,aq 0.33224E-13 -13.4785 0.33224E-13 -13.4785 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.28108E-15 -15.5512 0.23514E-15 -15.6287 0.83655E+00 -0.0775 67 MgCl+ 0.44580E-14 -14.3509 0.37294E-14 -14.4284 0.83655E+00 -0.0775 68 MgF+ 0.20799E-15 -15.6820 0.17400E-15 -15.7595 0.83655E+00 -0.0775 69 MgOH+ 0.69136E-10 -10.1603 0.57836E-10 -10.2378 0.83655E+00 -0.0775 71 MnF+ 0.57386E-16 -16.2412 0.48007E-16 -16.3187 0.83655E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46962E-09 -9.3283 0.39286E-09 -9.4058 0.83655E+00 -0.0775 74 MnO2-2 0.20871E-10 -10.6805 0.10803E-10 -10.9665 0.51760E+00 -0.2860 75 HMnO2- 0.21115E-09 -9.6754 0.17630E-09 -9.7537 0.83495E+00 -0.0783 78 MnCl+ 0.16581E-13 -13.7804 0.13871E-13 -13.8579 0.83655E+00 -0.0775 80 NaCl,aq 0.12844E-05 -5.8913 0.12844E-05 -5.8913 0.10000E+01 0.0000 81 NaF,aq 0.11481E-08 -8.9400 0.11481E-08 -8.9400 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93065E-02 -2.0312 0.77563E-02 -2.1103 0.83344E+00 -0.0791 89 HPO3-2 0.16282E-14 -14.7883 0.84276E-15 -15.0743 0.51760E+00 -0.2860 91 H2PO3- 0.15077E-18 -18.8217 0.12589E-18 -18.9000 0.83495E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38390E-10 -10.4158 0.32084E-10 -10.4937 0.83574E+00 -0.0779 94 PO4-3 0.10565E-08 -8.9761 0.25573E-09 -9.5922 0.24205E+00 -0.6161 98 HP2O7-3 0.93803E-18 -18.0278 0.21636E-18 -18.6648 0.23065E+00 -0.6370 99 P2O7-4 0.90404E-17 -17.0438 0.69388E-18 -18.1587 0.76754E-01 -1.1149 100 H2S,aq 0.11706E-07 -7.9316 0.11665E-07 -7.9331 0.99652E+00 -0.0015 101 S2-2 0.94887E-14 -14.0228 0.49114E-14 -14.3088 0.51760E+00 -0.2860 107 SO3-2 0.22839E-17 -17.6413 0.11993E-17 -17.9211 0.52511E+00 -0.2797 109 HSO4- 0.68310E-19 -19.1655 0.57201E-19 -19.2426 0.83737E+00 -0.0771 Charge balance for all species = -.7386E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8867705E-10 -.2222775E-01 -.2236520E+02 0.0000 2 H2O 0.1000000E+01 0.5550493E+02 0.9981955E+06 0.0000 3 Cl- 0.2787560E-03 0.2800411E-03 0.9910995E+01 6.4948 4 SO4-- 0.1536143E-11 -.5405782E-04 -.5183832E+01 8.1572 5 HCO3- 0.9869107E-06 0.5400950E-04 0.3289766E+01 4.0445 6 HS- 0.6067564E-04 0.1147452E-03 0.3788239E+01 5.8326 7 Al+++ 0.9834443E-29 0.5296126E-05 0.1426484E+00 0.7390 8 H4SiO4 0.6959789E-03 0.1349433E-01 0.1294753E+04 -3.1574 9 Ca++ 0.1362442E-06 0.2340199E-06 0.9362707E-02 13.1018 10 Mg++ 0.2131476E-10 0.9371764E-10 0.2274493E-05 9.2942 11 Fe++ 0.5874710E-13 0.3615524E-07 0.2015643E-02 6.7350 12 K+ 0.1571961E-03 0.1579504E-03 0.6165416E+01 6.2467 13 Na+ 0.1994753E-01 0.2239449E-01 0.5139478E+03 8.3494 14 Mn++ 0.1884634E-10 0.2526724E-08 0.1385713E-03 9.2416 15 F- 0.3534480E-06 0.3545967E-06 0.6724889E-02 3.5970 16 HPO4-- 0.4500612E-07 0.4610104E-07 0.4417022E-02 12.6241 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279253E+02 -.1103249E-01 -.8278149E+02 0.0000000E+00 2 H2O -.7168633E+01 0.2754924E+02 -.3471787E+02 0.0000000E+00 3 Cl- 0.1389952E-03 0.1389952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385934E+00 -.2683098E-04 0.1386203E+00 0.0000000E+00 5 HCO3- 0.2680700E-04 0.2680700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385633E+00 0.5695245E-04 -.1386203E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628672E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6697759E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1161531E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4651568E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794524E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7839689E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111525E-01 0.6265262E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254111E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1760000E-06 0.1760000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288173E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.6342E-14 Mass of aqueous solution: 0.497205E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0001900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2623 -0.581 56.81 1.754 1.040 17.36 hedenbergite 0.6803E-01 -1.167 16.88 1.227 0.3090 4.623 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4260E-01 -1.371 36.41 1.561 0.6666 11.72 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337924 g Volume = 2210.778384 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0001900 moles log = -3.7212 Original solution: 1000.0103000 g Original solution / Rock added: 5263212.11 (Water/Rock Ratio), log = 6.7213 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1109 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9196E+00 0.9848 0.1006E+01 0.1022E+01 CO2,gas 0.1257E-07 1.0062 0.1405E-07 0.1397E-07 CH4,gas 0.6676E-01 1.0118 0.7503E-01 0.7416E-01 H2,gas 0.1368E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2899E-06 0.9957 0.3207E-06 0.3221E-06 S2,gas 0.1503E-28 1.0000 0.1669E-28 0.1669E-28 CO,gas 0.5127E-13 1.0000 0.5695E-13 0.5695E-13 SO3,gas 0.1505E-47 1.0000 0.1672E-47 0.1672E-47 SO2,gas 0.8903E-27 1.0000 0.9890E-27 0.9890E-27 HF,gas 0.3319E-15 1.0000 0.3687E-15 0.3687E-15 HCl,gas 0.5046E-17 1.0000 0.5606E-17 0.5606E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.21 -9.55 -3.184 0.16308E+05 -7.852 3 CH4,gas 4.54 1.72 -2.82 -0.706 0.48214E+04 -1.125 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.42 -8.19 -4.096 0.13989E+05 -6.494 6 S2,gas -7.34 -37.81 -30.48 -4.689 0.52038E+05 -28.778 7 CO,gas 3.21 -11.73 -14.94 -4.598 0.25516E+05 -13.244 8 SO3,gas 17.12 -32.35 -49.48 -12.369 0.84479E+05 -47.777 9 SO2,gas 0.83 -27.87 -28.70 -7.654 0.49011E+05 -27.005 10 HF,gas 0.47 -16.66 -17.13 -8.566 0.29253E+05 -15.433 11 HCl,gas 5.19 -13.76 -18.95 -9.475 0.32357E+05 -17.251 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.81 -0.51 -0.043 0.87306E+03 38 aragonite 0.97 -3.11 -4.08 -1.359 0.69597E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.11 -3.92 -1.307 0.66955E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.25 -4.14 -1.184 0.70746E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.25 -3.70 -1.057 0.63168E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.69 -3.43 -1.143 0.58530E+04 147 pyrrhotiteFe0.875 -6.02 -9.09 -3.07 -1.129 0.52402E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.69 -3.28 -1.092 0.55958E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.18 -4.20 -1.401 0.71777E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0001900 MOLES New total amount of reactant added: 0.0002000 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3668E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002000 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141700E-01 Osmotic coef. = 0.9785 True ionic strength = .2010760E-01 Chg. balance for total moles = -.3668E-10 Max. difference allowed = 0.1391E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88679E-10 -10.0522 0.74492E-10 -10.1279 0.84002E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27887E-03 -3.5546 0.23285E-03 -3.6329 0.83495E+00 -0.0783 4 SO4-- 0.15485E-11 -11.8101 0.80322E-12 -12.0952 0.51870E+00 -0.2851 5 HCO3- 0.10135E-05 -5.9942 0.84747E-06 -6.0719 0.83617E+00 -0.0777 6 HS- 0.61165E-04 -4.2135 0.51077E-04 -4.2918 0.83507E+00 -0.0783 7 Al+++ 0.98351E-29 -29.0072 0.22662E-29 -29.6447 0.23042E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13625E-06 -6.8657 0.70153E-07 -7.1540 0.51488E+00 -0.2883 10 Mg++ 0.21316E-10 -10.6713 0.10925E-10 -10.9616 0.51252E+00 -0.2903 11 Fe++ 0.58750E-13 -13.2310 0.30143E-13 -13.5208 0.51308E+00 -0.2898 12 K+ 0.15720E-03 -3.8035 0.13148E-03 -3.8811 0.83637E+00 -0.0776 13 Na+ 0.19948E-01 -1.7001 0.16652E-01 -1.7785 0.83480E+00 -0.0784 14 Mn++ 0.18847E-10 -10.7248 0.96782E-11 -11.0142 0.51351E+00 -0.2895 15 F- 0.36148E-06 -6.4419 0.30119E-06 -6.5212 0.83322E+00 -0.0792 16 HPO4-- 0.45005E-07 -7.3467 0.23347E-07 -7.6318 0.51878E+00 -0.2850 18 HSiO3- 0.10449E-01 -1.9809 0.87240E-02 -2.0593 0.83495E+00 -0.0783 19 Ca(HSiO3)+ 0.16661E-07 -7.7783 0.13938E-07 -7.8558 0.83655E+00 -0.0775 20 Mg(HSiO3)+ 0.32290E-11 -11.4909 0.27012E-11 -11.5684 0.83655E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66414E-16 -16.1777 0.55559E-16 -16.2552 0.83655E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52959E-05 -5.2761 0.44138E-05 -5.3552 0.83344E+00 -0.0791 26 CH4,aq 0.52532E-04 -4.2796 0.52349E-04 -4.2811 0.99652E+00 -0.0015 27 C2H6,aq 0.40589E-13 -13.3916 0.40448E-13 -13.3931 0.99652E+00 -0.0015 31 CO,aq 0.39249E-16 -16.4062 0.39249E-16 -16.4062 0.10000E+01 0.0000 32 CO2,aq 0.13536E-09 -9.8685 0.13489E-09 -9.8700 0.99652E+00 -0.0015 33 CO3-2 0.19199E-05 -5.7167 0.99371E-06 -6.0027 0.51760E+00 -0.2860 34 CaCO3,aq 0.87411E-09 -9.0584 0.87411E-09 -9.0584 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.18141E-11 -11.7413 0.15176E-11 -11.8188 0.83655E+00 -0.0775 36 CaCl+ 0.31600E-10 -10.5003 0.26435E-10 -10.5778 0.83655E+00 -0.0775 37 CaCl2,aq 0.14624E-14 -14.8349 0.14624E-14 -14.8349 0.10000E+01 0.0000 38 CaF+ 0.36877E-12 -12.4332 0.30849E-12 -12.5108 0.83655E+00 -0.0775 39 CaOH+ 0.80232E-07 -7.0957 0.67118E-07 -7.1732 0.83655E+00 -0.0775 40 CaSO4,aq 0.17893E-16 -16.7473 0.17893E-16 -16.7473 0.10000E+01 0.0000 41 HCl,aq 0.31784E-14 -14.4978 0.31784E-14 -14.4978 0.10000E+01 0.0000 45 HF,aq 0.15359E-12 -12.8136 0.15359E-12 -12.8136 0.10000E+01 0.0000 46 HF2- 0.18707E-19 -19.7280 0.15619E-19 -19.8063 0.83495E+00 -0.0783 48 FeCl+ 0.13280E-16 -16.8768 0.11110E-16 -16.9543 0.83655E+00 -0.0775 51 FeF+ 0.55460E-18 -18.2560 0.46395E-18 -18.3335 0.83655E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15745E-10 -10.8028 0.13172E-10 -10.8804 0.83655E+00 -0.0775 55 HFeO2- 0.35517E-07 -7.4496 0.29655E-07 -7.5279 0.83495E+00 -0.0783 56 FeO+ 0.11035E-16 -16.9572 0.92315E-17 -17.0347 0.83655E+00 -0.0775 58 FeO2- 0.40770E-09 -9.3897 0.34041E-09 -9.4680 0.83495E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55485E-09 -9.2558 0.55485E-09 -9.2558 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.19627E-14 -14.7072 0.16387E-14 -14.7855 0.83495E+00 -0.0783 65 MgCO3,aq 0.34120E-13 -13.4670 0.34120E-13 -13.4670 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.28867E-15 -15.5396 0.24149E-15 -15.6171 0.83655E+00 -0.0775 67 MgCl+ 0.44600E-14 -14.3507 0.37311E-14 -14.4282 0.83655E+00 -0.0775 68 MgF+ 0.21273E-15 -15.6722 0.17796E-15 -15.7497 0.83655E+00 -0.0775 69 MgOH+ 0.69137E-10 -10.1603 0.57837E-10 -10.2378 0.83655E+00 -0.0775 71 MnF+ 0.58692E-16 -16.2314 0.49099E-16 -16.3089 0.83655E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46963E-09 -9.3282 0.39287E-09 -9.4057 0.83655E+00 -0.0775 74 MnO2-2 0.20870E-10 -10.6805 0.10803E-10 -10.9665 0.51760E+00 -0.2860 75 HMnO2- 0.21115E-09 -9.6754 0.17630E-09 -9.7538 0.83495E+00 -0.0783 78 MnCl+ 0.16588E-13 -13.7802 0.13877E-13 -13.8577 0.83655E+00 -0.0775 80 NaCl,aq 0.12850E-05 -5.8911 0.12850E-05 -5.8911 0.10000E+01 0.0000 81 NaF,aq 0.11742E-08 -8.9302 0.11742E-08 -8.9302 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93063E-02 -2.0312 0.77562E-02 -2.1104 0.83344E+00 -0.0791 89 HPO3-2 0.16282E-14 -14.7883 0.84273E-15 -15.0743 0.51760E+00 -0.2860 91 H2PO3- 0.15077E-18 -18.8217 0.12589E-18 -18.9000 0.83495E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38389E-10 -10.4158 0.32083E-10 -10.4937 0.83574E+00 -0.0779 94 PO4-3 0.10565E-08 -8.9761 0.25572E-09 -9.5922 0.24205E+00 -0.6161 98 HP2O7-3 0.93799E-18 -18.0278 0.21635E-18 -18.6648 0.23065E+00 -0.6370 99 P2O7-4 0.90399E-17 -17.0438 0.69383E-18 -18.1587 0.76752E-01 -1.1149 100 H2S,aq 0.11800E-07 -7.9281 0.11759E-07 -7.9296 0.99652E+00 -0.0015 101 S2-2 0.96425E-14 -14.0158 0.49909E-14 -14.3018 0.51760E+00 -0.2860 107 SO3-2 0.23023E-17 -17.6378 0.12090E-17 -17.9176 0.52511E+00 -0.2797 109 HSO4- 0.68861E-19 -19.1620 0.57662E-19 -19.2391 0.83737E+00 -0.0771 Charge balance for all species = -.7390E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8867883E-10 -.2222746E-01 -.2236491E+02 0.0000 2 H2O 0.1000000E+01 0.5550493E+02 0.9981955E+06 0.0000 3 Cl- 0.2788742E-03 0.2801598E-03 0.9915198E+01 6.4950 4 SO4-- 0.1548513E-11 -.5543747E-04 -.5316133E+01 8.1606 5 HCO3- 0.1013512E-05 0.5546615E-04 0.3378492E+01 4.0560 6 HS- 0.6116510E-04 0.1166144E-03 0.3849950E+01 5.8361 7 Al+++ 0.9835128E-29 0.5296035E-05 0.1426460E+00 0.7390 8 H4SiO4 0.6959789E-03 0.1349415E-01 0.1294736E+04 -3.1574 9 Ca++ 0.1362501E-06 0.2340508E-06 0.9363943E-02 13.1018 10 Mg++ 0.2131569E-10 0.9372029E-10 0.2274557E-05 9.2942 11 Fe++ 0.5874966E-13 0.3615463E-07 0.2015609E-02 6.7350 12 K+ 0.1571993E-03 0.1579536E-03 0.6165539E+01 6.2467 13 Na+ 0.1994793E-01 0.2239490E-01 0.5139570E+03 8.3494 14 Mn++ 0.1884718E-10 0.2526732E-08 0.1385717E-03 9.2416 15 F- 0.3614808E-06 0.3626555E-06 0.6877724E-02 3.6067 16 HPO4-- 0.4500471E-07 0.4609959E-07 0.4416882E-02 12.6240 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279253E+02 -.1103235E-01 -.8278149E+02 0.0000000E+00 2 H2O -.7168625E+01 0.2754925E+02 -.3471787E+02 0.0000000E+00 3 Cl- 0.1390542E-03 0.1390542E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385935E+00 -.2751577E-04 0.1386210E+00 0.0000000E+00 5 HCO3- 0.2753000E-04 0.2753000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385631E+00 0.5788024E-04 -.1386210E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628628E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6697672E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1161685E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4651701E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794494E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7839849E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111545E-01 0.6265261E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254115E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1800000E-06 0.1800000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288101E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.2491E-13 Mass of aqueous solution: 0.497205E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2623 -0.581 56.81 1.754 1.040 17.36 hedenbergite 0.6803E-01 -1.167 16.88 1.227 0.3090 4.623 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4261E-01 -1.371 36.42 1.561 0.6667 11.72 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337928 g Volume = 2210.778412 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002000 moles log = -3.6990 Original solution: 1000.0103000 g Original solution / Rock added: 5000051.50 (Water/Rock Ratio), log = 6.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1129 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9179E+00 0.9847 0.1006E+01 0.1022E+01 CO2,gas 0.1289E-07 1.0061 0.1443E-07 0.1434E-07 CH4,gas 0.6843E-01 1.0117 0.7705E-01 0.7616E-01 H2,gas 0.1366E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2917E-06 0.9957 0.3233E-06 0.3247E-06 S2,gas 0.1524E-28 1.0000 0.1696E-28 0.1696E-28 CO,gas 0.5256E-13 1.0000 0.5849E-13 0.5849E-13 SO3,gas 0.1514E-47 1.0000 0.1685E-47 0.1685E-47 SO2,gas 0.8959E-27 1.0000 0.9970E-27 0.9970E-27 HF,gas 0.3389E-15 1.0000 0.3771E-15 0.3771E-15 HCl,gas 0.5039E-17 1.0000 0.5608E-17 0.5608E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.20 -9.54 -3.180 0.16289E+05 -7.841 3 CH4,gas 4.54 1.73 -2.81 -0.703 0.48017E+04 -1.113 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.42 -8.19 -4.095 0.13983E+05 -6.490 6 S2,gas -7.34 -37.80 -30.47 -4.688 0.52026E+05 -28.771 7 CO,gas 3.21 -11.72 -14.93 -4.594 0.25496E+05 -13.233 8 SO3,gas 17.12 -32.35 -49.47 -12.368 0.84473E+05 -47.773 9 SO2,gas 0.83 -27.87 -28.70 -7.653 0.49005E+05 -27.001 10 HF,gas 0.47 -16.65 -17.12 -8.561 0.29236E+05 -15.424 11 HCl,gas 5.19 -13.76 -18.95 -9.475 0.32357E+05 -17.251 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.80 -0.50 -0.042 0.85638E+03 38 aragonite 0.97 -3.10 -4.06 -1.355 0.69399E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.10 -3.91 -1.303 0.66757E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.23 -4.13 -1.180 0.70548E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.23 -3.69 -1.054 0.62971E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.68 -3.42 -1.141 0.58470E+04 147 pyrrhotiteFe0.875 -6.02 -9.08 -3.07 -1.127 0.52342E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.68 -3.27 -1.091 0.55898E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.18 -4.20 -1.400 0.71718E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002000 MOLES New total amount of reactant added: 0.0002100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3668E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141617E-01 Osmotic coef. = 0.9791 True ionic strength = .2010806E-01 Chg. balance for total moles = -.3668E-10 Max. difference allowed = 0.1391E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88681E-10 -10.0522 0.74493E-10 -10.1279 0.84002E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27899E-03 -3.5544 0.23294E-03 -3.6327 0.83495E+00 -0.0783 4 SO4-- 0.15609E-11 -11.8066 0.80963E-12 -12.0917 0.51870E+00 -0.2851 5 HCO3- 0.10401E-05 -5.9829 0.86971E-06 -6.0606 0.83617E+00 -0.0777 6 HS- 0.61655E-04 -4.2100 0.51486E-04 -4.2883 0.83507E+00 -0.0783 7 Al+++ 0.98358E-29 -29.0072 0.22663E-29 -29.6447 0.23041E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13626E-06 -6.8656 0.70155E-07 -7.1539 0.51488E+00 -0.2883 10 Mg++ 0.21317E-10 -10.6713 0.10925E-10 -10.9616 0.51252E+00 -0.2903 11 Fe++ 0.58752E-13 -13.2310 0.30145E-13 -13.5208 0.51308E+00 -0.2898 12 K+ 0.15720E-03 -3.8035 0.13148E-03 -3.8811 0.83637E+00 -0.0776 13 Na+ 0.19948E-01 -1.7001 0.16653E-01 -1.7785 0.83480E+00 -0.0784 14 Mn++ 0.18848E-10 -10.7247 0.96786E-11 -11.0142 0.51351E+00 -0.2895 15 F- 0.36951E-06 -6.4324 0.30789E-06 -6.5116 0.83322E+00 -0.0792 16 HPO4-- 0.45003E-07 -7.3468 0.23347E-07 -7.6318 0.51877E+00 -0.2850 18 HSiO3- 0.10448E-01 -1.9810 0.87238E-02 -2.0593 0.83495E+00 -0.0783 19 Ca(HSiO3)+ 0.16661E-07 -7.7783 0.13938E-07 -7.8558 0.83655E+00 -0.0775 20 Mg(HSiO3)+ 0.32290E-11 -11.4909 0.27013E-11 -11.5684 0.83655E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66416E-16 -16.1777 0.55560E-16 -16.2552 0.83655E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52958E-05 -5.2761 0.44137E-05 -5.3552 0.83343E+00 -0.0791 26 CH4,aq 0.53911E-04 -4.2683 0.53724E-04 -4.2698 0.99652E+00 -0.0015 27 C2H6,aq 0.42749E-13 -13.3691 0.42600E-13 -13.3706 0.99652E+00 -0.0015 31 CO,aq 0.40280E-16 -16.3949 0.40280E-16 -16.3949 0.10000E+01 0.0000 32 CO2,aq 0.13892E-09 -9.8572 0.13844E-09 -9.8588 0.99652E+00 -0.0015 33 CO3-2 0.19702E-05 -5.7055 0.10198E-05 -5.9915 0.51760E+00 -0.2860 34 CaCO3,aq 0.89707E-09 -9.0472 0.89707E-09 -9.0472 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.18618E-11 -11.7301 0.15575E-11 -11.8076 0.83655E+00 -0.0775 36 CaCl+ 0.31614E-10 -10.5001 0.26447E-10 -10.5776 0.83655E+00 -0.0775 37 CaCl2,aq 0.14636E-14 -14.8346 0.14636E-14 -14.8346 0.10000E+01 0.0000 38 CaF+ 0.37698E-12 -12.4237 0.31536E-12 -12.5012 0.83655E+00 -0.0775 39 CaOH+ 0.80233E-07 -7.0956 0.67119E-07 -7.1732 0.83655E+00 -0.0775 40 CaSO4,aq 0.18037E-16 -16.7438 0.18037E-16 -16.7438 0.10000E+01 0.0000 41 HCl,aq 0.31798E-14 -14.4976 0.31798E-14 -14.4976 0.10000E+01 0.0000 45 HF,aq 0.15701E-12 -12.8041 0.15701E-12 -12.8041 0.10000E+01 0.0000 46 HF2- 0.19548E-19 -19.7089 0.16321E-19 -19.7872 0.83495E+00 -0.0783 48 FeCl+ 0.13286E-16 -16.8766 0.11115E-16 -16.9541 0.83655E+00 -0.0775 51 FeF+ 0.56695E-18 -18.2465 0.47428E-18 -18.3240 0.83655E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15746E-10 -10.8028 0.13172E-10 -10.8803 0.83655E+00 -0.0775 55 HFeO2- 0.35516E-07 -7.4496 0.29654E-07 -7.5279 0.83495E+00 -0.0783 56 FeO+ 0.11035E-16 -16.9572 0.92317E-17 -17.0347 0.83655E+00 -0.0775 58 FeO2- 0.40770E-09 -9.3897 0.34041E-09 -9.4680 0.83495E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55510E-09 -9.2556 0.55510E-09 -9.2556 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.19784E-14 -14.7037 0.16518E-14 -14.7820 0.83495E+00 -0.0783 65 MgCO3,aq 0.35016E-13 -13.4557 0.35016E-13 -13.4557 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.29625E-15 -15.5283 0.24783E-15 -15.6058 0.83655E+00 -0.0775 67 MgCl+ 0.44621E-14 -14.3505 0.37328E-14 -14.4280 0.83655E+00 -0.0775 68 MgF+ 0.21746E-15 -15.6626 0.18192E-15 -15.7401 0.83655E+00 -0.0775 69 MgOH+ 0.69138E-10 -10.1603 0.57838E-10 -10.2378 0.83655E+00 -0.0775 71 MnF+ 0.59999E-16 -16.2219 0.50192E-16 -16.2994 0.83655E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46964E-09 -9.3282 0.39288E-09 -9.4057 0.83655E+00 -0.0775 74 MnO2-2 0.20870E-10 -10.6805 0.10802E-10 -10.9665 0.51760E+00 -0.2860 75 HMnO2- 0.21114E-09 -9.6754 0.17629E-09 -9.7538 0.83495E+00 -0.0783 78 MnCl+ 0.16596E-13 -13.7800 0.13883E-13 -13.8575 0.83655E+00 -0.0775 80 NaCl,aq 0.12856E-05 -5.8909 0.12856E-05 -5.8909 0.10000E+01 0.0000 81 NaF,aq 0.12004E-08 -8.9207 0.12004E-08 -8.9207 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93061E-02 -2.0312 0.77561E-02 -2.1104 0.83343E+00 -0.0791 89 HPO3-2 0.16281E-14 -14.7883 0.84270E-15 -15.0743 0.51760E+00 -0.2860 91 H2PO3- 0.15077E-18 -18.8217 0.12588E-18 -18.9000 0.83495E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38388E-10 -10.4158 0.32083E-10 -10.4937 0.83574E+00 -0.0779 94 PO4-3 0.10564E-08 -8.9762 0.25571E-09 -9.5923 0.24204E+00 -0.6161 98 HP2O7-3 0.93795E-18 -18.0278 0.21634E-18 -18.6649 0.23065E+00 -0.6371 99 P2O7-4 0.90395E-17 -17.0439 0.69378E-18 -18.1588 0.76750E-01 -1.1149 100 H2S,aq 0.11895E-07 -7.9246 0.11854E-07 -7.9261 0.99652E+00 -0.0015 101 S2-2 0.97975E-14 -14.0089 0.50711E-14 -14.2949 0.51760E+00 -0.2860 107 SO3-2 0.23207E-17 -17.6344 0.12186E-17 -17.9141 0.52511E+00 -0.2798 109 HSO4- 0.69412E-19 -19.1586 0.58124E-19 -19.2356 0.83737E+00 -0.0771 Charge balance for all species = -.7383E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8868061E-10 -.2222717E-01 -.2236462E+02 0.0000 2 H2O 0.1000000E+01 0.5550493E+02 0.9981955E+06 0.0000 3 Cl- 0.2789924E-03 0.2802786E-03 0.9919401E+01 6.4951 4 SO4-- 0.1560883E-11 -.5681713E-04 -.5448433E+01 8.1641 5 HCO3- 0.1040113E-05 0.5692279E-04 0.3467217E+01 4.0673 6 HS- 0.6165457E-04 0.1184836E-03 0.3911661E+01 5.8396 7 Al+++ 0.9835813E-29 0.5295945E-05 0.1426435E+00 0.7390 8 H4SiO4 0.6959789E-03 0.1349398E-01 0.1294719E+04 -3.1574 9 Ca++ 0.1362560E-06 0.2340817E-06 0.9365179E-02 13.1018 10 Mg++ 0.2131662E-10 0.9372383E-10 0.2274643E-05 9.2942 11 Fe++ 0.5875221E-13 0.3615401E-07 0.2015575E-02 6.7350 12 K+ 0.1572024E-03 0.1579568E-03 0.6165662E+01 6.2467 13 Na+ 0.1994833E-01 0.2239530E-01 0.5139662E+03 8.3494 14 Mn++ 0.1884802E-10 0.2526741E-08 0.1385722E-03 9.2416 15 F- 0.3695135E-06 0.3707144E-06 0.7030560E-02 3.6163 16 HPO4-- 0.4500330E-07 0.4609813E-07 0.4416742E-02 12.6240 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279252E+02 -.1103221E-01 -.8278149E+02 0.0000000E+00 2 H2O -.7168617E+01 0.2754926E+02 -.3471788E+02 0.0000000E+00 3 Cl- 0.1391132E-03 0.1391132E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385935E+00 -.2820055E-04 0.1386217E+00 0.0000000E+00 5 HCO3- 0.2825300E-04 0.2825300E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385629E+00 0.5880802E-04 -.1386217E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628584E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6697586E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1161839E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4651879E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794464E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7840009E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111566E-01 0.6265261E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254120E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1840000E-06 0.1840000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2288030E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1790E-14 Mass of aqueous solution: 0.497205E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2623 -0.581 56.80 1.754 1.040 17.36 hedenbergite 0.6802E-01 -1.167 16.88 1.227 0.3090 4.622 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4261E-01 -1.370 36.42 1.561 0.6668 11.72 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337931 g Volume = 2210.778440 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002100 moles log = -3.6778 Original solution: 1000.0103000 g Original solution / Rock added: 4761953.81 (Water/Rock Ratio), log = 6.6778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1149 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9163E+00 0.9847 0.1006E+01 0.1022E+01 CO2,gas 0.1320E-07 1.0061 0.1481E-07 0.1472E-07 CH4,gas 0.7011E-01 1.0117 0.7908E-01 0.7816E-01 H2,gas 0.1363E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2935E-06 0.9957 0.3258E-06 0.3273E-06 S2,gas 0.1546E-28 1.0000 0.1724E-28 0.1724E-28 CO,gas 0.5384E-13 1.0000 0.6002E-13 0.6002E-13 SO3,gas 0.1524E-47 1.0000 0.1699E-47 0.1699E-47 SO2,gas 0.9014E-27 1.0000 0.1005E-26 0.1005E-26 HF,gas 0.3458E-15 1.0000 0.3855E-15 0.3855E-15 HCl,gas 0.5032E-17 1.0000 0.5611E-17 0.5611E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.19 -9.53 -3.176 0.16269E+05 -7.829 3 CH4,gas 4.54 1.74 -2.80 -0.700 0.47825E+04 -1.102 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.42 -8.19 -4.093 0.13977E+05 -6.487 6 S2,gas -7.34 -37.80 -30.46 -4.687 0.52014E+05 -28.764 7 CO,gas 3.21 -11.71 -14.92 -4.591 0.25477E+05 -13.222 8 SO3,gas 17.12 -32.35 -49.47 -12.367 0.84467E+05 -47.770 9 SO2,gas 0.83 -27.86 -28.70 -7.652 0.48999E+05 -26.998 10 HF,gas 0.47 -16.64 -17.11 -8.556 0.29220E+05 -15.414 11 HCl,gas 5.19 -13.76 -18.95 -9.475 0.32357E+05 -17.251 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.79 -0.49 -0.041 0.84007E+03 38 aragonite 0.97 -3.09 -4.05 -1.351 0.69207E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.09 -3.90 -1.299 0.66565E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.22 -4.12 -1.177 0.70356E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.22 -3.68 -1.050 0.62778E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.68 -3.42 -1.140 0.58411E+04 147 pyrrhotiteFe0.875 -6.02 -9.08 -3.06 -1.126 0.52283E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.68 -3.27 -1.090 0.55839E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.17 -4.20 -1.399 0.71658E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002100 MOLES New total amount of reactant added: 0.0002200 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3669E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002200 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141534E-01 Osmotic coef. = 0.9797 True ionic strength = .2010851E-01 Chg. balance for total moles = -.3669E-10 Max. difference allowed = 0.1392E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88682E-10 -10.0522 0.74495E-10 -10.1279 0.84002E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27911E-03 -3.5542 0.23304E-03 -3.6326 0.83495E+00 -0.0783 4 SO4-- 0.15733E-11 -11.8032 0.81604E-12 -12.0883 0.51870E+00 -0.2851 5 HCO3- 0.10667E-05 -5.9720 0.89195E-06 -6.0497 0.83617E+00 -0.0777 6 HS- 0.62144E-04 -4.2066 0.51895E-04 -4.2849 0.83507E+00 -0.0783 7 Al+++ 0.98365E-29 -29.0072 0.22664E-29 -29.6447 0.23041E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13626E-06 -6.8656 0.70158E-07 -7.1539 0.51488E+00 -0.2883 10 Mg++ 0.21318E-10 -10.6713 0.10926E-10 -10.9616 0.51251E+00 -0.2903 11 Fe++ 0.58755E-13 -13.2310 0.30146E-13 -13.5208 0.51308E+00 -0.2898 12 K+ 0.15721E-03 -3.8035 0.13148E-03 -3.8811 0.83637E+00 -0.0776 13 Na+ 0.19949E-01 -1.7001 0.16653E-01 -1.7785 0.83479E+00 -0.0784 14 Mn++ 0.18849E-10 -10.7247 0.96789E-11 -11.0142 0.51350E+00 -0.2895 15 F- 0.37755E-06 -6.4230 0.31458E-06 -6.5023 0.83322E+00 -0.0792 16 HPO4-- 0.45002E-07 -7.3468 0.23346E-07 -7.6318 0.51877E+00 -0.2850 18 HSiO3- 0.10448E-01 -1.9810 0.87237E-02 -2.0593 0.83495E+00 -0.0783 19 Ca(HSiO3)+ 0.16662E-07 -7.7783 0.13938E-07 -7.8558 0.83655E+00 -0.0775 20 Mg(HSiO3)+ 0.32291E-11 -11.4909 0.27013E-11 -11.5684 0.83655E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66417E-16 -16.1777 0.55561E-16 -16.2552 0.83655E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52957E-05 -5.2761 0.44136E-05 -5.3552 0.83343E+00 -0.0791 26 CH4,aq 0.55291E-04 -4.2573 0.55099E-04 -4.2589 0.99652E+00 -0.0015 27 C2H6,aq 0.44965E-13 -13.3471 0.44809E-13 -13.3486 0.99652E+00 -0.0015 31 CO,aq 0.41311E-16 -16.3839 0.41311E-16 -16.3839 0.10000E+01 0.0000 32 CO2,aq 0.14248E-09 -9.8463 0.14198E-09 -9.8478 0.99652E+00 -0.0015 33 CO3-2 0.20206E-05 -5.6945 0.10458E-05 -5.9805 0.51759E+00 -0.2860 34 CaCO3,aq 0.92002E-09 -9.0362 0.92002E-09 -9.0362 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.19095E-11 -11.7191 0.15974E-11 -11.7966 0.83655E+00 -0.0775 36 CaCl+ 0.31629E-10 -10.4999 0.26459E-10 -10.5774 0.83655E+00 -0.0775 37 CaCl2,aq 0.14649E-14 -14.8342 0.14649E-14 -14.8342 0.10000E+01 0.0000 38 CaF+ 0.38519E-12 -12.4143 0.32223E-12 -12.4918 0.83655E+00 -0.0775 39 CaOH+ 0.80235E-07 -7.0956 0.67121E-07 -7.1731 0.83655E+00 -0.0775 40 CaSO4,aq 0.18180E-16 -16.7404 0.18180E-16 -16.7404 0.10000E+01 0.0000 41 HCl,aq 0.31812E-14 -14.4974 0.31812E-14 -14.4974 0.10000E+01 0.0000 45 HF,aq 0.16043E-12 -12.7947 0.16043E-12 -12.7947 0.10000E+01 0.0000 46 HF2- 0.20407E-19 -19.6902 0.17039E-19 -19.7686 0.83495E+00 -0.0783 48 FeCl+ 0.13292E-16 -16.8764 0.11120E-16 -16.9539 0.83655E+00 -0.0775 51 FeF+ 0.57929E-18 -18.2371 0.48461E-18 -18.3146 0.83655E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15746E-10 -10.8028 0.13172E-10 -10.8803 0.83655E+00 -0.0775 55 HFeO2- 0.35516E-07 -7.4496 0.29654E-07 -7.5279 0.83495E+00 -0.0783 56 FeO+ 0.11036E-16 -16.9572 0.92318E-17 -17.0347 0.83655E+00 -0.0775 58 FeO2- 0.40769E-09 -9.3897 0.34040E-09 -9.4680 0.83495E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55534E-09 -9.2554 0.55534E-09 -9.2554 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.19941E-14 -14.7003 0.16650E-14 -14.7786 0.83495E+00 -0.0783 65 MgCO3,aq 0.35912E-13 -13.4448 0.35912E-13 -13.4448 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.30384E-15 -15.5174 0.25418E-15 -15.5949 0.83655E+00 -0.0775 67 MgCl+ 0.44642E-14 -14.3503 0.37345E-14 -14.4278 0.83655E+00 -0.0775 68 MgF+ 0.22220E-15 -15.6533 0.18588E-15 -15.7308 0.83655E+00 -0.0775 69 MgOH+ 0.69140E-10 -10.1603 0.57839E-10 -10.2378 0.83655E+00 -0.0775 71 MnF+ 0.61306E-16 -16.2125 0.51285E-16 -16.2900 0.83655E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46965E-09 -9.3282 0.39289E-09 -9.4057 0.83655E+00 -0.0775 74 MnO2-2 0.20869E-10 -10.6805 0.10802E-10 -10.9665 0.51759E+00 -0.2860 75 HMnO2- 0.21114E-09 -9.6754 0.17629E-09 -9.7538 0.83495E+00 -0.0783 78 MnCl+ 0.16604E-13 -13.7798 0.13890E-13 -13.8573 0.83655E+00 -0.0775 80 NaCl,aq 0.12861E-05 -5.8907 0.12861E-05 -5.8907 0.10000E+01 0.0000 81 NaF,aq 0.12265E-08 -8.9113 0.12265E-08 -8.9113 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93060E-02 -2.0312 0.77559E-02 -2.1104 0.83343E+00 -0.0791 89 HPO3-2 0.16280E-14 -14.7883 0.84267E-15 -15.0743 0.51759E+00 -0.2860 91 H2PO3- 0.15077E-18 -18.8217 0.12588E-18 -18.9000 0.83495E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38388E-10 -10.4158 0.32082E-10 -10.4937 0.83574E+00 -0.0779 94 PO4-3 0.10564E-08 -8.9762 0.25569E-09 -9.5923 0.24204E+00 -0.6161 98 HP2O7-3 0.93791E-18 -18.0278 0.21632E-18 -18.6649 0.23064E+00 -0.6371 99 P2O7-4 0.90390E-17 -17.0439 0.69373E-18 -18.1588 0.76748E-01 -1.1149 100 H2S,aq 0.11990E-07 -7.9212 0.11948E-07 -7.9227 0.99652E+00 -0.0015 101 S2-2 0.99537E-14 -14.0020 0.51519E-14 -14.2880 0.51759E+00 -0.2860 107 SO3-2 0.23391E-17 -17.6310 0.12283E-17 -17.9107 0.52511E+00 -0.2798 109 HSO4- 0.69963E-19 -19.1551 0.58585E-19 -19.2322 0.83737E+00 -0.0771 Charge balance for all species = -.7397E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8868240E-10 -.2222689E-01 -.2236433E+02 0.0000 2 H2O 0.1000000E+01 0.5550493E+02 0.9981955E+06 0.0000 3 Cl- 0.2791106E-03 0.2803974E-03 0.9923604E+01 6.4953 4 SO4-- 0.1573252E-11 -.5819679E-04 -.5580735E+01 8.1675 5 HCO3- 0.1066713E-05 0.5837944E-04 0.3555942E+01 4.0782 6 HS- 0.6214404E-04 0.1203528E-03 0.3973372E+01 5.8430 7 Al+++ 0.9836498E-29 0.5295855E-05 0.1426411E+00 0.7390 8 H4SiO4 0.6959789E-03 0.1349380E-01 0.1294702E+04 -3.1574 9 Ca++ 0.1362620E-06 0.2341126E-06 0.9366414E-02 13.1018 10 Mg++ 0.2131754E-10 0.9372648E-10 0.2274707E-05 9.2942 11 Fe++ 0.5875476E-13 0.3615340E-07 0.2015540E-02 6.7350 12 K+ 0.1572056E-03 0.1579599E-03 0.6165785E+01 6.2467 13 Na+ 0.1994873E-01 0.2239570E-01 0.5139754E+03 8.3494 14 Mn++ 0.1884886E-10 0.2526749E-08 0.1385727E-03 9.2416 15 F- 0.3775463E-06 0.3787733E-06 0.7183395E-02 3.6256 16 HPO4-- 0.4500189E-07 0.4609667E-07 0.4416602E-02 12.6240 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279252E+02 -.1103207E-01 -.8278149E+02 0.0000000E+00 2 H2O -.7168609E+01 0.2754927E+02 -.3471788E+02 0.0000000E+00 3 Cl- 0.1391722E-03 0.1391722E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385936E+00 -.2888534E-04 0.1386225E+00 0.0000000E+00 5 HCO3- 0.2897600E-04 0.2897600E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385627E+00 0.5973581E-04 -.1386225E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628540E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6697499E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1161992E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4652012E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794434E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7840168E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111586E-01 0.6265261E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254125E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1880000E-06 0.1880000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287958E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.3747E-14 Mass of aqueous solution: 0.497206E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002200 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2623 -0.581 56.80 1.754 1.040 17.36 hedenbergite 0.6802E-01 -1.167 16.87 1.227 0.3089 4.622 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4262E-01 -1.370 36.43 1.561 0.6669 11.72 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337934 g Volume = 2210.778467 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002200 moles log = -3.6576 Original solution: 1000.0103000 g Original solution / Rock added: 4545501.36 (Water/Rock Ratio), log = 6.6576 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1170 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9146E+00 0.9847 0.1006E+01 0.1022E+01 CO2,gas 0.1352E-07 1.0061 0.1519E-07 0.1510E-07 CH4,gas 0.7177E-01 1.0117 0.8110E-01 0.8016E-01 H2,gas 0.1361E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2953E-06 0.9957 0.3284E-06 0.3299E-06 S2,gas 0.1568E-28 1.0000 0.1751E-28 0.1751E-28 CO,gas 0.5512E-13 1.0000 0.6156E-13 0.6156E-13 SO3,gas 0.1533E-47 1.0000 0.1712E-47 0.1712E-47 SO2,gas 0.9069E-27 1.0000 0.1013E-26 0.1013E-26 HF,gas 0.3527E-15 1.0000 0.3939E-15 0.3939E-15 HCl,gas 0.5026E-17 1.0000 0.5613E-17 0.5613E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.18 -9.52 -3.172 0.16251E+05 -7.818 3 CH4,gas 4.54 1.75 -2.79 -0.697 0.47637E+04 -1.091 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.41 -8.18 -4.091 0.13971E+05 -6.484 6 S2,gas -7.34 -37.79 -30.46 -4.685 0.52002E+05 -28.757 7 CO,gas 3.21 -11.69 -14.91 -4.588 0.25458E+05 -13.211 8 SO3,gas 17.12 -32.34 -49.47 -12.366 0.84461E+05 -47.766 9 SO2,gas 0.83 -27.86 -28.69 -7.652 0.48993E+05 -26.994 10 HF,gas 0.47 -16.63 -17.10 -8.552 0.29204E+05 -15.405 11 HCl,gas 5.19 -13.76 -18.95 -9.475 0.32356E+05 -17.251 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.78 -0.48 -0.040 0.82411E+03 38 aragonite 0.97 -3.08 -4.04 -1.347 0.69020E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.08 -3.89 -1.296 0.66378E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.21 -4.11 -1.174 0.70169E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.21 -3.67 -1.047 0.62591E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.68 -3.42 -1.139 0.58352E+04 147 pyrrhotiteFe0.875 -6.02 -9.08 -3.06 -1.125 0.52224E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.68 -3.27 -1.089 0.55780E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.17 -4.19 -1.398 0.71600E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002200 MOLES New total amount of reactant added: 0.0002300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3671E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141451E-01 Osmotic coef. = 0.9803 True ionic strength = .2010897E-01 Chg. balance for total moles = -.3671E-10 Max. difference allowed = 0.1392E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88684E-10 -10.0522 0.74496E-10 -10.1279 0.84001E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27923E-03 -3.5540 0.23314E-03 -3.6324 0.83495E+00 -0.0783 4 SO4-- 0.15856E-11 -11.7998 0.82245E-12 -12.0849 0.51869E+00 -0.2851 5 HCO3- 0.10933E-05 -5.9613 0.91419E-06 -6.0390 0.83617E+00 -0.0777 6 HS- 0.62634E-04 -4.2032 0.52303E-04 -4.2815 0.83507E+00 -0.0783 7 Al+++ 0.98372E-29 -29.0071 0.22666E-29 -29.6446 0.23041E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13627E-06 -6.8656 0.70161E-07 -7.1539 0.51487E+00 -0.2883 10 Mg++ 0.21318E-10 -10.6712 0.10926E-10 -10.9615 0.51251E+00 -0.2903 11 Fe++ 0.58757E-13 -13.2309 0.30147E-13 -13.5208 0.51307E+00 -0.2898 12 K+ 0.15721E-03 -3.8035 0.13148E-03 -3.8811 0.83637E+00 -0.0776 13 Na+ 0.19949E-01 -1.7001 0.16653E-01 -1.7785 0.83479E+00 -0.0784 14 Mn++ 0.18850E-10 -10.7247 0.96793E-11 -11.0142 0.51350E+00 -0.2895 15 F- 0.38558E-06 -6.4139 0.32127E-06 -6.4931 0.83322E+00 -0.0792 16 HPO4-- 0.45000E-07 -7.3468 0.23345E-07 -7.6318 0.51877E+00 -0.2850 18 HSiO3- 0.10448E-01 -1.9810 0.87235E-02 -2.0593 0.83495E+00 -0.0783 19 Ca(HSiO3)+ 0.16662E-07 -7.7783 0.13939E-07 -7.8558 0.83655E+00 -0.0775 20 Mg(HSiO3)+ 0.32292E-11 -11.4909 0.27014E-11 -11.5684 0.83655E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66418E-16 -16.1777 0.55562E-16 -16.2552 0.83655E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52956E-05 -5.2761 0.44135E-05 -5.3552 0.83343E+00 -0.0791 26 CH4,aq 0.56671E-04 -4.2466 0.56474E-04 -4.2482 0.99652E+00 -0.0015 27 C2H6,aq 0.47237E-13 -13.3257 0.47073E-13 -13.3272 0.99652E+00 -0.0015 31 CO,aq 0.42342E-16 -16.3732 0.42342E-16 -16.3732 0.10000E+01 0.0000 32 CO2,aq 0.14603E-09 -9.8356 0.14552E-09 -9.8371 0.99652E+00 -0.0015 33 CO3-2 0.20709E-05 -5.6838 0.10719E-05 -5.9699 0.51759E+00 -0.2860 34 CaCO3,aq 0.94298E-09 -9.0255 0.94298E-09 -9.0255 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.19571E-11 -11.7084 0.16373E-11 -11.7859 0.83655E+00 -0.0775 36 CaCl+ 0.31643E-10 -10.4997 0.26471E-10 -10.5772 0.83655E+00 -0.0775 37 CaCl2,aq 0.14662E-14 -14.8338 0.14662E-14 -14.8338 0.10000E+01 0.0000 38 CaF+ 0.39340E-12 -12.4052 0.32910E-12 -12.4827 0.83655E+00 -0.0775 39 CaOH+ 0.80237E-07 -7.0956 0.67122E-07 -7.1731 0.83655E+00 -0.0775 40 CaSO4,aq 0.18324E-16 -16.7370 0.18324E-16 -16.7370 0.10000E+01 0.0000 41 HCl,aq 0.31826E-14 -14.4972 0.31826E-14 -14.4972 0.10000E+01 0.0000 45 HF,aq 0.16384E-12 -12.7856 0.16384E-12 -12.7856 0.10000E+01 0.0000 46 HF2- 0.21285E-19 -19.6719 0.17772E-19 -19.7503 0.83495E+00 -0.0783 48 FeCl+ 0.13298E-16 -16.8762 0.11125E-16 -16.9537 0.83655E+00 -0.0775 51 FeF+ 0.59164E-18 -18.2279 0.49494E-18 -18.3055 0.83655E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15746E-10 -10.8028 0.13173E-10 -10.8803 0.83655E+00 -0.0775 55 HFeO2- 0.35515E-07 -7.4496 0.29653E-07 -7.5279 0.83495E+00 -0.0783 56 FeO+ 0.11036E-16 -16.9572 0.92320E-17 -17.0347 0.83655E+00 -0.0775 58 FeO2- 0.40768E-09 -9.3897 0.34039E-09 -9.4680 0.83495E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55559E-09 -9.2552 0.55559E-09 -9.2552 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.20098E-14 -14.6968 0.16781E-14 -14.7752 0.83495E+00 -0.0783 65 MgCO3,aq 0.36808E-13 -13.4341 0.36808E-13 -13.4341 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.31143E-15 -15.5066 0.26053E-15 -15.5841 0.83655E+00 -0.0775 67 MgCl+ 0.44662E-14 -14.3501 0.37362E-14 -14.4276 0.83655E+00 -0.0775 68 MgF+ 0.22693E-15 -15.6441 0.18984E-15 -15.7216 0.83655E+00 -0.0775 69 MgOH+ 0.69141E-10 -10.1603 0.57840E-10 -10.2378 0.83655E+00 -0.0775 71 MnF+ 0.62612E-16 -16.2033 0.52378E-16 -16.2808 0.83655E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46966E-09 -9.3282 0.39290E-09 -9.4057 0.83655E+00 -0.0775 74 MnO2-2 0.20869E-10 -10.6805 0.10801E-10 -10.9665 0.51759E+00 -0.2860 75 HMnO2- 0.21114E-09 -9.6754 0.17629E-09 -9.7538 0.83495E+00 -0.0783 78 MnCl+ 0.16611E-13 -13.7796 0.13896E-13 -13.8571 0.83655E+00 -0.0775 80 NaCl,aq 0.12867E-05 -5.8905 0.12867E-05 -5.8905 0.10000E+01 0.0000 81 NaF,aq 0.12526E-08 -8.9022 0.12526E-08 -8.9022 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93058E-02 -2.0312 0.77558E-02 -2.1104 0.83343E+00 -0.0791 89 HPO3-2 0.16280E-14 -14.7883 0.84264E-15 -15.0744 0.51759E+00 -0.2860 91 H2PO3- 0.15076E-18 -18.8217 0.12588E-18 -18.9000 0.83495E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38387E-10 -10.4158 0.32082E-10 -10.4937 0.83574E+00 -0.0779 94 PO4-3 0.10563E-08 -8.9762 0.25568E-09 -9.5923 0.24204E+00 -0.6161 98 HP2O7-3 0.93787E-18 -18.0279 0.21631E-18 -18.6649 0.23064E+00 -0.6371 99 P2O7-4 0.90385E-17 -17.0439 0.69367E-18 -18.1588 0.76746E-01 -1.1149 100 H2S,aq 0.12084E-07 -7.9178 0.12042E-07 -7.9193 0.99652E+00 -0.0015 101 S2-2 0.10111E-13 -13.9952 0.52334E-14 -14.2812 0.51759E+00 -0.2860 107 SO3-2 0.23575E-17 -17.6276 0.12379E-17 -17.9073 0.52510E+00 -0.2798 109 HSO4- 0.70514E-19 -19.1517 0.59046E-19 -19.2288 0.83737E+00 -0.0771 Charge balance for all species = -.7394E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8868418E-10 -.2222660E-01 -.2236404E+02 0.0000 2 H2O 0.1000000E+01 0.5550493E+02 0.9981955E+06 0.0000 3 Cl- 0.2792288E-03 0.2805161E-03 0.9927807E+01 6.4955 4 SO4-- 0.1585621E-11 -.5957645E-04 -.5713036E+01 8.1708 5 HCO3- 0.1093312E-05 0.5983608E-04 0.3644668E+01 4.0889 6 HS- 0.6263351E-04 0.1222220E-03 0.4035083E+01 5.8464 7 Al+++ 0.9837182E-29 0.5295764E-05 0.1426387E+00 0.7390 8 H4SiO4 0.6959788E-03 0.1349362E-01 0.1294684E+04 -3.1574 9 Ca++ 0.1362679E-06 0.2341435E-06 0.9367650E-02 13.1018 10 Mg++ 0.2131847E-10 0.9373003E-10 0.2274793E-05 9.2942 11 Fe++ 0.5875732E-13 0.3615278E-07 0.2015506E-02 6.7350 12 K+ 0.1572088E-03 0.1579631E-03 0.6165908E+01 6.2467 13 Na+ 0.1994913E-01 0.2239610E-01 0.5139846E+03 8.3494 14 Mn++ 0.1884969E-10 0.2526758E-08 0.1385731E-03 9.2416 15 F- 0.3855790E-06 0.3868321E-06 0.7336230E-02 3.6347 16 HPO4-- 0.4500047E-07 0.4609521E-07 0.4416462E-02 12.6239 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279252E+02 -.1103193E-01 -.8278149E+02 0.0000000E+00 2 H2O -.7168600E+01 0.2754928E+02 -.3471788E+02 0.0000000E+00 3 Cl- 0.1392312E-03 0.1392312E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385936E+00 -.2957014E-04 0.1386232E+00 0.0000000E+00 5 HCO3- 0.2969900E-04 0.2969900E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385625E+00 0.6066361E-04 -.1386232E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628496E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6697413E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1162146E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4652190E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794405E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7840328E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111607E-01 0.6265261E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254129E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1920000E-06 0.1920000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287886E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1296E-13 Mass of aqueous solution: 0.497206E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2623 -0.581 56.79 1.754 1.040 17.36 hedenbergite 0.6801E-01 -1.167 16.87 1.227 0.3089 4.622 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4262E-01 -1.370 36.43 1.562 0.6670 11.73 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337938 g Volume = 2210.778495 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002300 moles log = -3.6383 Original solution: 1000.0103000 g Original solution / Rock added: 4347870.87 (Water/Rock Ratio), log = 6.6383 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1190 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9130E+00 0.9847 0.1006E+01 0.1022E+01 CO2,gas 0.1383E-07 1.0061 0.1557E-07 0.1548E-07 CH4,gas 0.7343E-01 1.0117 0.8313E-01 0.8217E-01 H2,gas 0.1358E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2971E-06 0.9957 0.3310E-06 0.3325E-06 S2,gas 0.1590E-28 1.0000 0.1779E-28 0.1779E-28 CO,gas 0.5639E-13 1.0000 0.6310E-13 0.6310E-13 SO3,gas 0.1542E-47 1.0000 0.1726E-47 0.1726E-47 SO2,gas 0.9124E-27 1.0000 0.1021E-26 0.1021E-26 HF,gas 0.3595E-15 1.0000 0.4023E-15 0.4023E-15 HCl,gas 0.5019E-17 1.0000 0.5616E-17 0.5616E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.18198E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.17 -9.51 -3.169 0.16232E+05 -7.808 3 CH4,gas 4.54 1.76 -2.78 -0.695 0.47455E+04 -1.080 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.41 -8.18 -4.090 0.13966E+05 -6.480 6 S2,gas -7.34 -37.78 -30.45 -4.684 0.51991E+05 -28.750 7 CO,gas 3.21 -11.68 -14.90 -4.584 0.25440E+05 -13.200 8 SO3,gas 17.12 -32.34 -49.46 -12.365 0.84455E+05 -47.763 9 SO2,gas 0.83 -27.86 -28.69 -7.651 0.48987E+05 -26.991 10 HF,gas 0.47 -16.62 -17.09 -8.547 0.29188E+05 -15.395 11 HCl,gas 5.19 -13.76 -18.95 -9.475 0.32356E+05 -17.251 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.77 -0.47 -0.039 0.80848E+03 38 aragonite 0.97 -3.06 -4.03 -1.344 0.68837E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.06 -3.88 -1.292 0.66195E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.20 -4.10 -1.171 0.69986E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.20 -3.66 -1.044 0.62408E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.67 -3.41 -1.138 0.58294E+04 147 pyrrhotiteFe0.875 -6.02 -9.07 -3.06 -1.124 0.52166E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.67 -3.26 -1.088 0.55722E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.17 -4.19 -1.397 0.71541E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002300 MOLES New total amount of reactant added: 0.0002400 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3671E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002400 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141368E-01 Osmotic coef. = 0.9810 True ionic strength = .2010942E-01 Chg. balance for total moles = -.3671E-10 Max. difference allowed = 0.1393E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88686E-10 -10.0521 0.74497E-10 -10.1279 0.84001E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27935E-03 -3.5539 0.23324E-03 -3.6322 0.83494E+00 -0.0783 4 SO4-- 0.15980E-11 -11.7964 0.82886E-12 -12.0815 0.51869E+00 -0.2851 5 HCO3- 0.11199E-05 -5.9508 0.93643E-06 -6.0285 0.83617E+00 -0.0777 6 HS- 0.63123E-04 -4.1998 0.52712E-04 -4.2781 0.83507E+00 -0.0783 7 Al+++ 0.98379E-29 -29.0071 0.22667E-29 -29.6446 0.23041E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13627E-06 -6.8656 0.70163E-07 -7.1539 0.51487E+00 -0.2883 10 Mg++ 0.21319E-10 -10.6712 0.10926E-10 -10.9615 0.51251E+00 -0.2903 11 Fe++ 0.58760E-13 -13.2309 0.30148E-13 -13.5207 0.51307E+00 -0.2898 12 K+ 0.15721E-03 -3.8035 0.13149E-03 -3.8811 0.83637E+00 -0.0776 13 Na+ 0.19950E-01 -1.7001 0.16654E-01 -1.7785 0.83479E+00 -0.0784 14 Mn++ 0.18851E-10 -10.7247 0.96797E-11 -11.0141 0.51350E+00 -0.2895 15 F- 0.39361E-06 -6.4049 0.32796E-06 -6.4842 0.83322E+00 -0.0792 16 HPO4-- 0.44999E-07 -7.3468 0.23344E-07 -7.6318 0.51877E+00 -0.2850 18 HSiO3- 0.10448E-01 -1.9810 0.87233E-02 -2.0593 0.83494E+00 -0.0783 19 Ca(HSiO3)+ 0.16662E-07 -7.7783 0.13939E-07 -7.8558 0.83655E+00 -0.0775 20 Mg(HSiO3)+ 0.32292E-11 -11.4909 0.27014E-11 -11.5684 0.83655E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66420E-16 -16.1777 0.55563E-16 -16.2552 0.83655E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52955E-05 -5.2761 0.44135E-05 -5.3552 0.83343E+00 -0.0791 26 CH4,aq 0.58050E-04 -4.2362 0.57848E-04 -4.2377 0.99652E+00 -0.0015 27 C2H6,aq 0.49565E-13 -13.3048 0.49393E-13 -13.3063 0.99652E+00 -0.0015 31 CO,aq 0.43372E-16 -16.3628 0.43372E-16 -16.3628 0.10000E+01 0.0000 32 CO2,aq 0.14959E-09 -9.8251 0.14906E-09 -9.8266 0.99652E+00 -0.0015 33 CO3-2 0.21213E-05 -5.6734 0.10979E-05 -5.9594 0.51759E+00 -0.2860 34 CaCO3,aq 0.96594E-09 -9.0151 0.96594E-09 -9.0151 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.20048E-11 -11.6979 0.16771E-11 -11.7754 0.83655E+00 -0.0775 36 CaCl+ 0.31658E-10 -10.4995 0.26483E-10 -10.5770 0.83655E+00 -0.0775 37 CaCl2,aq 0.14675E-14 -14.8334 0.14675E-14 -14.8334 0.10000E+01 0.0000 38 CaF+ 0.40161E-12 -12.3962 0.33596E-12 -12.4737 0.83655E+00 -0.0775 39 CaOH+ 0.80238E-07 -7.0956 0.67123E-07 -7.1731 0.83655E+00 -0.0775 40 CaSO4,aq 0.18467E-16 -16.7336 0.18467E-16 -16.7336 0.10000E+01 0.0000 41 HCl,aq 0.31840E-14 -14.4970 0.31840E-14 -14.4970 0.10000E+01 0.0000 45 HF,aq 0.16726E-12 -12.7766 0.16726E-12 -12.7766 0.10000E+01 0.0000 46 HF2- 0.22181E-19 -19.6540 0.18520E-19 -19.7324 0.83494E+00 -0.0783 48 FeCl+ 0.13305E-16 -16.8760 0.11130E-16 -16.9535 0.83655E+00 -0.0775 51 FeF+ 0.60399E-18 -18.2190 0.50526E-18 -18.2965 0.83655E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15747E-10 -10.8028 0.13173E-10 -10.8803 0.83655E+00 -0.0775 55 HFeO2- 0.35514E-07 -7.4496 0.29652E-07 -7.5279 0.83494E+00 -0.0783 56 FeO+ 0.11036E-16 -16.9572 0.92322E-17 -17.0347 0.83655E+00 -0.0775 58 FeO2- 0.40768E-09 -9.3897 0.34039E-09 -9.4680 0.83494E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55583E-09 -9.2551 0.55583E-09 -9.2551 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.20255E-14 -14.6935 0.16912E-14 -14.7718 0.83494E+00 -0.0783 65 MgCO3,aq 0.37704E-13 -13.4236 0.37704E-13 -13.4236 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.31902E-15 -15.4962 0.26687E-15 -15.5737 0.83655E+00 -0.0775 67 MgCl+ 0.44683E-14 -14.3499 0.37379E-14 -14.4274 0.83655E+00 -0.0775 68 MgF+ 0.23167E-15 -15.6351 0.19380E-15 -15.7126 0.83655E+00 -0.0775 69 MgOH+ 0.69143E-10 -10.1603 0.57841E-10 -10.2378 0.83655E+00 -0.0775 71 MnF+ 0.63919E-16 -16.1944 0.53472E-16 -16.2719 0.83655E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46967E-09 -9.3282 0.39290E-09 -9.4057 0.83655E+00 -0.0775 74 MnO2-2 0.20868E-10 -10.6805 0.10801E-10 -10.9665 0.51759E+00 -0.2860 75 HMnO2- 0.21113E-09 -9.6754 0.17628E-09 -9.7538 0.83494E+00 -0.0783 78 MnCl+ 0.16619E-13 -13.7794 0.13903E-13 -13.8569 0.83655E+00 -0.0775 80 NaCl,aq 0.12873E-05 -5.8903 0.12873E-05 -5.8903 0.10000E+01 0.0000 81 NaF,aq 0.12787E-08 -8.8932 0.12787E-08 -8.8932 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93057E-02 -2.0313 0.77556E-02 -2.1104 0.83343E+00 -0.0791 89 HPO3-2 0.16279E-14 -14.7884 0.84260E-15 -15.0744 0.51759E+00 -0.2860 91 H2PO3- 0.15076E-18 -18.8217 0.12588E-18 -18.9001 0.83494E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38386E-10 -10.4158 0.32081E-10 -10.4938 0.83574E+00 -0.0779 94 PO4-3 0.10563E-08 -8.9762 0.25566E-09 -9.5923 0.24204E+00 -0.6161 98 HP2O7-3 0.93783E-18 -18.0279 0.21630E-18 -18.6649 0.23064E+00 -0.6371 99 P2O7-4 0.90381E-17 -17.0439 0.69362E-18 -18.1589 0.76745E-01 -1.1150 100 H2S,aq 0.12179E-07 -7.9144 0.12137E-07 -7.9159 0.99652E+00 -0.0015 101 S2-2 0.10270E-13 -13.9884 0.53155E-14 -14.2745 0.51759E+00 -0.2860 107 SO3-2 0.23759E-17 -17.6242 0.12476E-17 -17.9039 0.52510E+00 -0.2798 109 HSO4- 0.71065E-19 -19.1483 0.59508E-19 -19.2254 0.83737E+00 -0.0771 Charge balance for all species = -.7403E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8868596E-10 -.2222631E-01 -.2236374E+02 0.0000 2 H2O 0.1000000E+01 0.5550494E+02 0.9981955E+06 0.0000 3 Cl- 0.2793470E-03 0.2806349E-03 0.9932010E+01 6.4957 4 SO4-- 0.1597989E-11 -.6095612E-04 -.5845338E+01 8.1742 5 HCO3- 0.1119910E-05 0.6129272E-04 0.3733393E+01 4.0993 6 HS- 0.6312297E-04 0.1240913E-03 0.4096795E+01 5.8498 7 Al+++ 0.9837867E-29 0.5295674E-05 0.1426362E+00 0.7390 8 H4SiO4 0.6959788E-03 0.1349344E-01 0.1294667E+04 -3.1574 9 Ca++ 0.1362738E-06 0.2341744E-06 0.9368885E-02 13.1018 10 Mg++ 0.2131940E-10 0.9373357E-10 0.2274879E-05 9.2942 11 Fe++ 0.5875987E-13 0.3615216E-07 0.2015471E-02 6.7350 12 K+ 0.1572119E-03 0.1579662E-03 0.6166031E+01 6.2467 13 Na+ 0.1994953E-01 0.2239650E-01 0.5139938E+03 8.3494 14 Mn++ 0.1885053E-10 0.2526766E-08 0.1385736E-03 9.2416 15 F- 0.3936117E-06 0.3948910E-06 0.7489065E-02 3.6437 16 HPO4-- 0.4499906E-07 0.4609375E-07 0.4416322E-02 12.6239 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279252E+02 -.1103179E-01 -.8278149E+02 0.0000000E+00 2 H2O -.7168592E+01 0.2754929E+02 -.3471788E+02 0.0000000E+00 3 Cl- 0.1392902E-03 0.1392902E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385937E+00 -.3025493E-04 0.1386239E+00 0.0000000E+00 5 HCO3- 0.3042200E-04 0.3042200E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385623E+00 0.6159140E-04 -.1386239E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628452E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6697326E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1162300E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4652367E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794375E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7840488E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111627E-01 0.6265261E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254134E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1960000E-06 0.1960000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287815E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.2449E-14 Mass of aqueous solution: 0.497206E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002400 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2622 -0.581 56.79 1.754 1.040 17.36 hedenbergite 0.6801E-01 -1.167 16.87 1.227 0.3089 4.621 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4263E-01 -1.370 36.44 1.562 0.6671 11.73 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337941 g Volume = 2210.778523 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002400 moles log = -3.6198 Original solution: 1000.0103000 g Original solution / Rock added: 4166709.58 (Water/Rock Ratio), log = 6.6198 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1210 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9114E+00 0.9847 0.1006E+01 0.1022E+01 CO2,gas 0.1414E-07 1.0060 0.1595E-07 0.1585E-07 CH4,gas 0.7508E-01 1.0116 0.8515E-01 0.8417E-01 H2,gas 0.1356E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2989E-06 0.9956 0.3336E-06 0.3351E-06 S2,gas 0.1612E-28 1.0000 0.1807E-28 0.1807E-28 CO,gas 0.5766E-13 1.0000 0.6463E-13 0.6463E-13 SO3,gas 0.1552E-47 1.0000 0.1739E-47 0.1739E-47 SO2,gas 0.9179E-27 1.0000 0.1029E-26 0.1029E-26 HF,gas 0.3663E-15 1.0000 0.4107E-15 0.4107E-15 HCl,gas 0.5012E-17 1.0000 0.5618E-17 0.5618E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.54595E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.16 -9.50 -3.165 0.16215E+05 -7.797 3 CH4,gas 4.54 1.77 -2.77 -0.692 0.47276E+04 -1.070 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.41 -8.18 -4.088 0.13960E+05 -6.477 6 S2,gas -7.34 -37.78 -30.44 -4.683 0.51979E+05 -28.743 7 CO,gas 3.21 -11.67 -14.89 -4.581 0.25422E+05 -13.190 8 SO3,gas 17.12 -32.34 -49.46 -12.365 0.84449E+05 -47.760 9 SO2,gas 0.83 -27.85 -28.69 -7.650 0.48982E+05 -26.988 10 HF,gas 0.47 -16.61 -17.09 -8.543 0.29173E+05 -15.387 11 HCl,gas 5.19 -13.76 -18.95 -9.475 0.32356E+05 -17.250 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.77 -0.46 -0.039 0.79318E+03 38 aragonite 0.97 -3.05 -4.02 -1.340 0.68659E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.05 -3.87 -1.289 0.66017E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.19 -4.09 -1.168 0.69807E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.19 -3.64 -1.041 0.62230E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.67 -3.41 -1.137 0.58236E+04 147 pyrrhotiteFe0.875 -6.02 -9.07 -3.05 -1.122 0.52108E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.67 -3.26 -1.087 0.55664E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.16 -4.19 -1.396 0.71483E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002400 MOLES New total amount of reactant added: 0.0002500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3671E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141285E-01 Osmotic coef. = 0.9816 True ionic strength = .2010988E-01 Chg. balance for total moles = -.3671E-10 Max. difference allowed = 0.1393E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88688E-10 -10.0521 0.74499E-10 -10.1279 0.84001E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27947E-03 -3.5537 0.23334E-03 -3.6320 0.83494E+00 -0.0783 4 SO4-- 0.16104E-11 -11.7931 0.83527E-12 -12.0782 0.51869E+00 -0.2851 5 HCO3- 0.11465E-05 -5.9406 0.95867E-06 -6.0183 0.83617E+00 -0.0777 6 HS- 0.63612E-04 -4.1965 0.53121E-04 -4.2747 0.83507E+00 -0.0783 7 Al+++ 0.98386E-29 -29.0071 0.22668E-29 -29.6446 0.23040E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13628E-06 -6.8656 0.70166E-07 -7.1539 0.51487E+00 -0.2883 10 Mg++ 0.21320E-10 -10.6712 0.10927E-10 -10.9615 0.51250E+00 -0.2903 11 Fe++ 0.58762E-13 -13.2309 0.30149E-13 -13.5207 0.51307E+00 -0.2898 12 K+ 0.15722E-03 -3.8035 0.13149E-03 -3.8811 0.83637E+00 -0.0776 13 Na+ 0.19950E-01 -1.7001 0.16654E-01 -1.7785 0.83479E+00 -0.0784 14 Mn++ 0.18851E-10 -10.7247 0.96801E-11 -11.0141 0.51349E+00 -0.2895 15 F- 0.40164E-06 -6.3962 0.33466E-06 -6.4754 0.83322E+00 -0.0792 16 HPO4-- 0.44998E-07 -7.3468 0.23343E-07 -7.6318 0.51876E+00 -0.2850 18 HSiO3- 0.10448E-01 -1.9810 0.87232E-02 -2.0593 0.83494E+00 -0.0783 19 Ca(HSiO3)+ 0.16663E-07 -7.7783 0.13939E-07 -7.8558 0.83655E+00 -0.0775 20 Mg(HSiO3)+ 0.32293E-11 -11.4909 0.27015E-11 -11.5684 0.83655E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66421E-16 -16.1777 0.55564E-16 -16.2552 0.83655E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52954E-05 -5.2761 0.44134E-05 -5.3552 0.83343E+00 -0.0791 26 CH4,aq 0.59430E-04 -4.2260 0.59223E-04 -4.2275 0.99652E+00 -0.0015 27 C2H6,aq 0.51949E-13 -13.2844 0.51768E-13 -13.2859 0.99652E+00 -0.0015 31 CO,aq 0.44403E-16 -16.3526 0.44403E-16 -16.3526 0.10000E+01 0.0000 32 CO2,aq 0.15314E-09 -9.8149 0.15261E-09 -9.8164 0.99652E+00 -0.0015 33 CO3-2 0.21716E-05 -5.6632 0.11240E-05 -5.9492 0.51758E+00 -0.2860 34 CaCO3,aq 0.98889E-09 -9.0048 0.98889E-09 -9.0048 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.20525E-11 -11.6877 0.17170E-11 -11.7652 0.83655E+00 -0.0775 36 CaCl+ 0.31673E-10 -10.4993 0.26496E-10 -10.5768 0.83655E+00 -0.0775 37 CaCl2,aq 0.14688E-14 -14.8330 0.14688E-14 -14.8330 0.10000E+01 0.0000 38 CaF+ 0.40982E-12 -12.3874 0.34283E-12 -12.4649 0.83655E+00 -0.0775 39 CaOH+ 0.80240E-07 -7.0956 0.67124E-07 -7.1731 0.83655E+00 -0.0775 40 CaSO4,aq 0.18611E-16 -16.7302 0.18611E-16 -16.7302 0.10000E+01 0.0000 41 HCl,aq 0.31854E-14 -14.4968 0.31854E-14 -14.4968 0.10000E+01 0.0000 45 HF,aq 0.17067E-12 -12.7678 0.17067E-12 -12.7678 0.10000E+01 0.0000 46 HF2- 0.23096E-19 -19.6365 0.19284E-19 -19.7148 0.83494E+00 -0.0783 48 FeCl+ 0.13311E-16 -16.8758 0.11135E-16 -16.9533 0.83655E+00 -0.0775 51 FeF+ 0.61634E-18 -18.2102 0.51559E-18 -18.2877 0.83655E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15747E-10 -10.8028 0.13173E-10 -10.8803 0.83655E+00 -0.0775 55 HFeO2- 0.35514E-07 -7.4496 0.29652E-07 -7.5279 0.83494E+00 -0.0783 56 FeO+ 0.11036E-16 -16.9572 0.92324E-17 -17.0347 0.83655E+00 -0.0775 58 FeO2- 0.40767E-09 -9.3897 0.34038E-09 -9.4680 0.83494E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55608E-09 -9.2549 0.55608E-09 -9.2549 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.20412E-14 -14.6901 0.17043E-14 -14.7685 0.83494E+00 -0.0783 65 MgCO3,aq 0.38601E-13 -13.4134 0.38601E-13 -13.4134 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.32661E-15 -15.4860 0.27322E-15 -15.5635 0.83655E+00 -0.0775 67 MgCl+ 0.44703E-14 -14.3497 0.37396E-14 -14.4272 0.83655E+00 -0.0775 68 MgF+ 0.23641E-15 -15.6263 0.19777E-15 -15.7038 0.83655E+00 -0.0775 69 MgOH+ 0.69144E-10 -10.1602 0.57842E-10 -10.2378 0.83655E+00 -0.0775 71 MnF+ 0.65226E-16 -16.1856 0.54565E-16 -16.2631 0.83655E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46968E-09 -9.3282 0.39291E-09 -9.4057 0.83655E+00 -0.0775 74 MnO2-2 0.20867E-10 -10.6805 0.10801E-10 -10.9666 0.51758E+00 -0.2860 75 HMnO2- 0.21113E-09 -9.6755 0.17628E-09 -9.7538 0.83494E+00 -0.0783 78 MnCl+ 0.16627E-13 -13.7792 0.13909E-13 -13.8567 0.83655E+00 -0.0775 80 NaCl,aq 0.12878E-05 -5.8901 0.12878E-05 -5.8901 0.10000E+01 0.0000 81 NaF,aq 0.13048E-08 -8.8844 0.13048E-08 -8.8844 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93055E-02 -2.0313 0.77555E-02 -2.1104 0.83343E+00 -0.0791 89 HPO3-2 0.16279E-14 -14.7884 0.84257E-15 -15.0744 0.51758E+00 -0.2860 91 H2PO3- 0.15076E-18 -18.8217 0.12587E-18 -18.9001 0.83494E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38386E-10 -10.4158 0.32080E-10 -10.4938 0.83574E+00 -0.0779 94 PO4-3 0.10563E-08 -8.9762 0.25565E-09 -9.5924 0.24203E+00 -0.6161 98 HP2O7-3 0.93779E-18 -18.0279 0.21629E-18 -18.6650 0.23063E+00 -0.6371 99 P2O7-4 0.90376E-17 -17.0439 0.69357E-18 -18.1589 0.76743E-01 -1.1150 100 H2S,aq 0.12274E-07 -7.9110 0.12231E-07 -7.9125 0.99652E+00 -0.0015 101 S2-2 0.10430E-13 -13.9817 0.53982E-14 -14.2677 0.51758E+00 -0.2860 107 SO3-2 0.23942E-17 -17.6208 0.12572E-17 -17.9006 0.52510E+00 -0.2798 109 HSO4- 0.71616E-19 -19.1450 0.59969E-19 -19.2221 0.83736E+00 -0.0771 Charge balance for all species = -.7399E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8868774E-10 -.2222602E-01 -.2236345E+02 0.0000 2 H2O 0.1000000E+01 0.5550494E+02 0.9981954E+06 0.0000 3 Cl- 0.2794652E-03 0.2807537E-03 0.9936213E+01 6.4958 4 SO4-- 0.1610357E-11 -.6233579E-04 -.5977640E+01 8.1775 5 HCO3- 0.1146507E-05 0.6274937E-04 0.3822118E+01 4.1095 6 HS- 0.6361244E-04 0.1259605E-03 0.4158506E+01 5.8531 7 Al+++ 0.9838552E-29 0.5295583E-05 0.1426338E+00 0.7390 8 H4SiO4 0.6959788E-03 0.1349326E-01 0.1294650E+04 -3.1574 9 Ca++ 0.1362797E-06 0.2342053E-06 0.9370121E-02 13.1018 10 Mg++ 0.2132032E-10 0.9373712E-10 0.2274965E-05 9.2942 11 Fe++ 0.5876243E-13 0.3615155E-07 0.2015437E-02 6.7350 12 K+ 0.1572151E-03 0.1579694E-03 0.6166154E+01 6.2467 13 Na+ 0.1994993E-01 0.2239691E-01 0.5140030E+03 8.3494 14 Mn++ 0.1885137E-10 0.2526775E-08 0.1385740E-03 9.2416 15 F- 0.4016444E-06 0.4029499E-06 0.7641900E-02 3.6525 16 HPO4-- 0.4499765E-07 0.4609229E-07 0.4416182E-02 12.6239 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279252E+02 -.1103166E-01 -.8278149E+02 0.0000000E+00 2 H2O -.7168584E+01 0.2754930E+02 -.3471789E+02 0.0000000E+00 3 Cl- 0.1393492E-03 0.1393492E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385937E+00 -.3093972E-04 0.1386247E+00 0.0000000E+00 5 HCO3- 0.3114500E-04 0.3114500E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385621E+00 0.6251919E-04 -.1386247E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628408E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6697240E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1162454E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4652545E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794345E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7840648E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111647E-01 0.6265260E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254139E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2000000E-06 0.2000000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287743E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1076E-13 Mass of aqueous solution: 0.497206E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2622 -0.581 56.79 1.754 1.040 17.35 hedenbergite 0.6800E-01 -1.167 16.87 1.227 0.3089 4.621 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4264E-01 -1.370 36.44 1.562 0.6672 11.73 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337944 g Volume = 2210.778550 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002500 moles log = -3.6021 Original solution: 1000.0103000 g Original solution / Rock added: 4000041.20 (Water/Rock Ratio), log = 6.6021 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1230 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9097E+00 0.9846 0.1006E+01 0.1022E+01 CO2,gas 0.1445E-07 1.0060 0.1633E-07 0.1623E-07 CH4,gas 0.7673E-01 1.0116 0.8717E-01 0.8617E-01 H2,gas 0.1353E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3007E-06 0.9956 0.3362E-06 0.3377E-06 S2,gas 0.1634E-28 1.0000 0.1835E-28 0.1835E-28 CO,gas 0.5892E-13 1.0000 0.6617E-13 0.6617E-13 SO3,gas 0.1561E-47 1.0000 0.1753E-47 0.1753E-47 SO2,gas 0.9234E-27 1.0000 0.1037E-26 0.1037E-26 HF,gas 0.3732E-15 1.0000 0.4191E-15 0.4191E-15 HCl,gas 0.5005E-17 1.0000 0.5621E-17 0.5621E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.15 -9.49 -3.162 0.16197E+05 -7.787 3 CH4,gas 4.54 1.79 -2.76 -0.690 0.47102E+04 -1.060 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.40 -8.17 -4.086 0.13954E+05 -6.473 6 S2,gas -7.34 -37.77 -30.44 -4.682 0.51968E+05 -28.736 7 CO,gas 3.21 -11.66 -14.88 -4.578 0.25404E+05 -13.179 8 SO3,gas 17.12 -32.33 -49.46 -12.364 0.84443E+05 -47.756 9 SO2,gas 0.83 -27.85 -28.68 -7.649 0.48976E+05 -26.984 10 HF,gas 0.47 -16.60 -17.08 -8.538 0.29158E+05 -15.378 11 HCl,gas 5.19 -13.76 -18.95 -9.475 0.32355E+05 -17.250 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.76 -0.46 -0.038 0.77819E+03 38 aragonite 0.97 -3.04 -4.01 -1.337 0.68485E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.04 -3.86 -1.285 0.65842E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.18 -4.08 -1.165 0.69633E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.18 -3.63 -1.038 0.62056E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.67 -3.41 -1.136 0.58179E+04 147 pyrrhotiteFe0.875 -6.02 -9.07 -3.05 -1.121 0.52051E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.67 -3.26 -1.086 0.55607E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.16 -4.18 -1.394 0.71426E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002500 MOLES New total amount of reactant added: 0.0002600 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3672E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002600 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141202E-01 Osmotic coef. = 0.9823 True ionic strength = .2011033E-01 Chg. balance for total moles = -.3672E-10 Max. difference allowed = 0.1394E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88690E-10 -10.0521 0.74500E-10 -10.1278 0.84001E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27958E-03 -3.5535 0.23344E-03 -3.6318 0.83494E+00 -0.0783 4 SO4-- 0.16227E-11 -11.7898 0.84168E-12 -12.0749 0.51869E+00 -0.2851 5 HCO3- 0.11731E-05 -5.9307 0.98091E-06 -6.0084 0.83617E+00 -0.0777 6 HS- 0.64102E-04 -4.1931 0.53529E-04 -4.2714 0.83506E+00 -0.0783 7 Al+++ 0.98392E-29 -29.0070 0.22669E-29 -29.6446 0.23040E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13629E-06 -6.8656 0.70169E-07 -7.1539 0.51486E+00 -0.2883 10 Mg++ 0.21321E-10 -10.6712 0.10927E-10 -10.9615 0.51250E+00 -0.2903 11 Fe++ 0.58765E-13 -13.2309 0.30150E-13 -13.5207 0.51306E+00 -0.2898 12 K+ 0.15722E-03 -3.8035 0.13149E-03 -3.8811 0.83637E+00 -0.0776 13 Na+ 0.19950E-01 -1.7000 0.16654E-01 -1.7785 0.83479E+00 -0.0784 14 Mn++ 0.18852E-10 -10.7246 0.96804E-11 -11.0141 0.51349E+00 -0.2895 15 F- 0.40968E-06 -6.3876 0.34135E-06 -6.4668 0.83321E+00 -0.0792 16 HPO4-- 0.44996E-07 -7.3468 0.23342E-07 -7.6319 0.51876E+00 -0.2850 18 HSiO3- 0.10447E-01 -1.9810 0.87230E-02 -2.0593 0.83494E+00 -0.0783 19 Ca(HSiO3)+ 0.16663E-07 -7.7782 0.13939E-07 -7.8558 0.83655E+00 -0.0775 20 Mg(HSiO3)+ 0.32294E-11 -11.4909 0.27015E-11 -11.5684 0.83655E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66422E-16 -16.1777 0.55565E-16 -16.2552 0.83655E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52953E-05 -5.2761 0.44133E-05 -5.3552 0.83343E+00 -0.0791 26 CH4,aq 0.60810E-04 -4.2160 0.60598E-04 -4.2175 0.99652E+00 -0.0015 27 C2H6,aq 0.54389E-13 -13.2645 0.54200E-13 -13.2660 0.99652E+00 -0.0015 31 CO,aq 0.45434E-16 -16.3426 0.45434E-16 -16.3426 0.10000E+01 0.0000 32 CO2,aq 0.15670E-09 -9.8049 0.15615E-09 -9.8065 0.99652E+00 -0.0015 33 CO3-2 0.22220E-05 -5.6533 0.11500E-05 -5.9393 0.51758E+00 -0.2860 34 CaCO3,aq 0.10119E-08 -8.9949 0.10119E-08 -8.9949 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.21002E-11 -11.6777 0.17569E-11 -11.7552 0.83655E+00 -0.0775 36 CaCl+ 0.31687E-10 -10.4991 0.26508E-10 -10.5766 0.83655E+00 -0.0775 37 CaCl2,aq 0.14701E-14 -14.8327 0.14701E-14 -14.8327 0.10000E+01 0.0000 38 CaF+ 0.41803E-12 -12.3788 0.34970E-12 -12.4563 0.83655E+00 -0.0775 39 CaOH+ 0.80241E-07 -7.0956 0.67126E-07 -7.1731 0.83655E+00 -0.0775 40 CaSO4,aq 0.18754E-16 -16.7269 0.18754E-16 -16.7269 0.10000E+01 0.0000 41 HCl,aq 0.31868E-14 -14.4966 0.31868E-14 -14.4966 0.10000E+01 0.0000 45 HF,aq 0.17409E-12 -12.7592 0.17409E-12 -12.7592 0.10000E+01 0.0000 46 HF2- 0.24030E-19 -19.6192 0.20064E-19 -19.6976 0.83494E+00 -0.0783 48 FeCl+ 0.13317E-16 -16.8756 0.11140E-16 -16.9531 0.83655E+00 -0.0775 51 FeF+ 0.62869E-18 -18.2016 0.52592E-18 -18.2791 0.83655E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15747E-10 -10.8028 0.13173E-10 -10.8803 0.83655E+00 -0.0775 55 HFeO2- 0.35513E-07 -7.4496 0.29651E-07 -7.5280 0.83494E+00 -0.0783 56 FeO+ 0.11036E-16 -16.9572 0.92325E-17 -17.0347 0.83655E+00 -0.0775 58 FeO2- 0.40766E-09 -9.3897 0.34037E-09 -9.4680 0.83494E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55632E-09 -9.2547 0.55632E-09 -9.2547 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.20569E-14 -14.6868 0.17174E-14 -14.7651 0.83494E+00 -0.0783 65 MgCO3,aq 0.39497E-13 -13.4034 0.39497E-13 -13.4034 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.33420E-15 -15.4760 0.27957E-15 -15.5535 0.83655E+00 -0.0775 67 MgCl+ 0.44724E-14 -14.3495 0.37414E-14 -14.4270 0.83655E+00 -0.0775 68 MgF+ 0.24115E-15 -15.6177 0.20173E-15 -15.6952 0.83655E+00 -0.0775 69 MgOH+ 0.69145E-10 -10.1602 0.57843E-10 -10.2377 0.83655E+00 -0.0775 71 MnF+ 0.66533E-16 -16.1770 0.55658E-16 -16.2545 0.83655E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46969E-09 -9.3282 0.39292E-09 -9.4057 0.83655E+00 -0.0775 74 MnO2-2 0.20867E-10 -10.6805 0.10800E-10 -10.9666 0.51758E+00 -0.2860 75 HMnO2- 0.21113E-09 -9.6755 0.17628E-09 -9.7538 0.83494E+00 -0.0783 78 MnCl+ 0.16634E-13 -13.7790 0.13915E-13 -13.8565 0.83655E+00 -0.0775 80 NaCl,aq 0.12884E-05 -5.8900 0.12884E-05 -5.8900 0.10000E+01 0.0000 81 NaF,aq 0.13309E-08 -8.8758 0.13309E-08 -8.8758 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93053E-02 -2.0313 0.77553E-02 -2.1104 0.83343E+00 -0.0791 89 HPO3-2 0.16278E-14 -14.7884 0.84254E-15 -15.0744 0.51758E+00 -0.2860 91 H2PO3- 0.15075E-18 -18.8217 0.12587E-18 -18.9001 0.83494E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38385E-10 -10.4158 0.32080E-10 -10.4938 0.83573E+00 -0.0779 94 PO4-3 0.10562E-08 -8.9762 0.25563E-09 -9.5924 0.24203E+00 -0.6161 98 HP2O7-3 0.93775E-18 -18.0279 0.21627E-18 -18.6650 0.23063E+00 -0.6371 99 P2O7-4 0.90371E-17 -17.0440 0.69352E-18 -18.1589 0.76741E-01 -1.1150 100 H2S,aq 0.12368E-07 -7.9077 0.12325E-07 -7.9092 0.99652E+00 -0.0015 101 S2-2 0.10591E-13 -13.9751 0.54816E-14 -14.2611 0.51758E+00 -0.2860 107 SO3-2 0.24126E-17 -17.6175 0.12669E-17 -17.8973 0.52509E+00 -0.2798 109 HSO4- 0.72167E-19 -19.1417 0.60430E-19 -19.2187 0.83736E+00 -0.0771 Charge balance for all species = -.7397E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8868952E-10 -.2222573E-01 -.2236316E+02 0.0000 2 H2O 0.1000000E+01 0.5550494E+02 0.9981954E+06 0.0000 3 Cl- 0.2795834E-03 0.2808724E-03 0.9940416E+01 6.4960 4 SO4-- 0.1622725E-11 -.6371546E-04 -.6109942E+01 8.1808 5 HCO3- 0.1173103E-05 0.6420601E-04 0.3910843E+01 4.1195 6 HS- 0.6410190E-04 0.1278297E-03 0.4220217E+01 5.8564 7 Al+++ 0.9839237E-29 0.5295493E-05 0.1426313E+00 0.7390 8 H4SiO4 0.6959788E-03 0.1349308E-01 0.1294633E+04 -3.1574 9 Ca++ 0.1362856E-06 0.2342362E-06 0.9371357E-02 13.1018 10 Mg++ 0.2132125E-10 0.9373977E-10 0.2275029E-05 9.2942 11 Fe++ 0.5876498E-13 0.3615093E-07 0.2015403E-02 6.7350 12 K+ 0.1572182E-03 0.1579726E-03 0.6166277E+01 6.2467 13 Na+ 0.1995034E-01 0.2239731E-01 0.5140122E+03 8.3494 14 Mn++ 0.1885221E-10 0.2526783E-08 0.1385745E-03 9.2416 15 F- 0.4096772E-06 0.4110087E-06 0.7794735E-02 3.6610 16 HPO4-- 0.4499624E-07 0.4609083E-07 0.4416042E-02 12.6238 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279252E+02 -.1103152E-01 -.8278149E+02 0.0000000E+00 2 H2O -.7168576E+01 0.2754931E+02 -.3471789E+02 0.0000000E+00 3 Cl- 0.1394082E-03 0.1394082E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385938E+00 -.3162452E-04 0.1386254E+00 0.0000000E+00 5 HCO3- 0.3186800E-04 0.3186800E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385619E+00 0.6344699E-04 -.1386254E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628364E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6697154E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1162608E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4652678E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794315E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7840807E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111668E-01 0.6265260E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254143E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2040000E-06 0.2040000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287672E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.6578E-14 Mass of aqueous solution: 0.497206E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002600 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2622 -0.581 56.78 1.754 1.040 17.35 hedenbergite 0.6800E-01 -1.168 16.87 1.227 0.3088 4.621 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4264E-01 -1.370 36.45 1.562 0.6673 11.73 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337948 g Volume = 2210.778578 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002600 moles log = -3.5850 Original solution: 1000.0103000 g Original solution / Rock added: 3846193.46 (Water/Rock Ratio), log = 6.5850 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1251 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9081E+00 0.9846 0.1006E+01 0.1022E+01 CO2,gas 0.1476E-07 1.0060 0.1671E-07 0.1661E-07 CH4,gas 0.7837E-01 1.0116 0.8920E-01 0.8817E-01 H2,gas 0.1351E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3025E-06 0.9956 0.3388E-06 0.3403E-06 S2,gas 0.1656E-28 1.0000 0.1863E-28 0.1863E-28 CO,gas 0.6018E-13 1.0000 0.6771E-13 0.6771E-13 SO3,gas 0.1570E-47 1.0000 0.1766E-47 0.1766E-47 SO2,gas 0.9288E-27 1.0000 0.1045E-26 0.1045E-26 HF,gas 0.3799E-15 1.0000 0.4275E-15 0.4275E-15 HCl,gas 0.4998E-17 1.0000 0.5623E-17 0.5623E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.14 -9.48 -3.159 0.16180E+05 -7.777 3 CH4,gas 4.54 1.80 -2.75 -0.687 0.46932E+04 -1.050 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.40 -8.17 -4.085 0.13948E+05 -6.470 6 S2,gas -7.34 -37.76 -30.43 -4.681 0.51956E+05 -28.730 7 CO,gas 3.21 -11.65 -14.87 -4.575 0.25387E+05 -13.169 8 SO3,gas 17.12 -32.33 -49.45 -12.363 0.84438E+05 -47.753 9 SO2,gas 0.83 -27.85 -28.68 -7.648 0.48970E+05 -26.981 10 HF,gas 0.47 -16.59 -17.07 -8.534 0.29143E+05 -15.369 11 HCl,gas 5.19 -13.76 -18.95 -9.474 0.32355E+05 -17.250 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.75 -0.45 -0.037 0.76349E+03 38 aragonite 0.97 -3.03 -4.00 -1.334 0.68314E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.03 -3.85 -1.282 0.65672E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.17 -4.07 -1.162 0.69463E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.17 -3.62 -1.036 0.61886E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.66 -3.40 -1.135 0.58122E+04 147 pyrrhotiteFe0.875 -6.02 -9.06 -3.05 -1.120 0.51994E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.66 -3.25 -1.084 0.55550E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.16 -4.18 -1.393 0.71369E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002600 MOLES New total amount of reactant added: 0.0002700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3672E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141119E-01 Osmotic coef. = 0.9830 True ionic strength = .2011079E-01 Chg. balance for total moles = -.3672E-10 Max. difference allowed = 0.1395E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88691E-10 -10.0521 0.74501E-10 -10.1278 0.84001E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27970E-03 -3.5533 0.23353E-03 -3.6316 0.83494E+00 -0.0783 4 SO4-- 0.16351E-11 -11.7865 0.84809E-12 -12.0716 0.51868E+00 -0.2851 5 HCO3- 0.11997E-05 -5.9209 0.10031E-05 -5.9986 0.83617E+00 -0.0777 6 HS- 0.64591E-04 -4.1898 0.53938E-04 -4.2681 0.83506E+00 -0.0783 7 Al+++ 0.98399E-29 -29.0070 0.22671E-29 -29.6445 0.23040E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13629E-06 -6.8655 0.70171E-07 -7.1538 0.51486E+00 -0.2883 10 Mg++ 0.21322E-10 -10.6712 0.10928E-10 -10.9615 0.51250E+00 -0.2903 11 Fe++ 0.58768E-13 -13.2309 0.30151E-13 -13.5207 0.51306E+00 -0.2898 12 K+ 0.15722E-03 -3.8035 0.13149E-03 -3.8811 0.83636E+00 -0.0776 13 Na+ 0.19951E-01 -1.7000 0.16655E-01 -1.7785 0.83479E+00 -0.0784 14 Mn++ 0.18853E-10 -10.7246 0.96808E-11 -11.0141 0.51349E+00 -0.2895 15 F- 0.41771E-06 -6.3791 0.34804E-06 -6.4584 0.83321E+00 -0.0792 16 HPO4-- 0.44995E-07 -7.3468 0.23341E-07 -7.6319 0.51876E+00 -0.2850 18 HSiO3- 0.10447E-01 -1.9810 0.87228E-02 -2.0593 0.83494E+00 -0.0783 19 Ca(HSiO3)+ 0.16663E-07 -7.7782 0.13940E-07 -7.8557 0.83654E+00 -0.0775 20 Mg(HSiO3)+ 0.32294E-11 -11.4909 0.27016E-11 -11.5684 0.83654E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66424E-16 -16.1777 0.55566E-16 -16.2552 0.83654E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52953E-05 -5.2761 0.44132E-05 -5.3552 0.83343E+00 -0.0791 26 CH4,aq 0.62189E-04 -4.2063 0.61973E-04 -4.2078 0.99652E+00 -0.0015 27 C2H6,aq 0.56885E-13 -13.2450 0.56687E-13 -13.2465 0.99652E+00 -0.0015 31 CO,aq 0.46465E-16 -16.3329 0.46465E-16 -16.3329 0.10000E+01 0.0000 32 CO2,aq 0.16025E-09 -9.7952 0.15969E-09 -9.7967 0.99652E+00 -0.0015 33 CO3-2 0.22723E-05 -5.6435 0.11761E-05 -5.9296 0.51758E+00 -0.2860 34 CaCO3,aq 0.10348E-08 -8.9851 0.10348E-08 -8.9851 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.21479E-11 -11.6680 0.17968E-11 -11.7455 0.83654E+00 -0.0775 36 CaCl+ 0.31702E-10 -10.4989 0.26520E-10 -10.5764 0.83654E+00 -0.0775 37 CaCl2,aq 0.14714E-14 -14.8323 0.14714E-14 -14.8323 0.10000E+01 0.0000 38 CaF+ 0.42624E-12 -12.3703 0.35657E-12 -12.4479 0.83654E+00 -0.0775 39 CaOH+ 0.80243E-07 -7.0956 0.67127E-07 -7.1731 0.83654E+00 -0.0775 40 CaSO4,aq 0.18898E-16 -16.7236 0.18898E-16 -16.7236 0.10000E+01 0.0000 41 HCl,aq 0.31882E-14 -14.4965 0.31882E-14 -14.4965 0.10000E+01 0.0000 45 HF,aq 0.17751E-12 -12.7508 0.17751E-12 -12.7508 0.10000E+01 0.0000 46 HF2- 0.24982E-19 -19.6024 0.20858E-19 -19.6807 0.83494E+00 -0.0783 48 FeCl+ 0.13323E-16 -16.8754 0.11145E-16 -16.9529 0.83654E+00 -0.0775 51 FeF+ 0.64104E-18 -18.1931 0.53626E-18 -18.2706 0.83654E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15748E-10 -10.8028 0.13174E-10 -10.8803 0.83654E+00 -0.0775 55 HFeO2- 0.35513E-07 -7.4496 0.29651E-07 -7.5280 0.83494E+00 -0.0783 56 FeO+ 0.11037E-16 -16.9572 0.92327E-17 -17.0347 0.83654E+00 -0.0775 58 FeO2- 0.40765E-09 -9.3897 0.34037E-09 -9.4681 0.83494E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55657E-09 -9.2545 0.55657E-09 -9.2545 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.20726E-14 -14.6835 0.17305E-14 -14.7618 0.83494E+00 -0.0783 65 MgCO3,aq 0.40393E-13 -13.3937 0.40393E-13 -13.3937 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.34179E-15 -15.4662 0.28592E-15 -15.5438 0.83654E+00 -0.0775 67 MgCl+ 0.44744E-14 -14.3493 0.37431E-14 -14.4268 0.83654E+00 -0.0775 68 MgF+ 0.24588E-15 -15.6093 0.20569E-15 -15.6868 0.83654E+00 -0.0775 69 MgOH+ 0.69147E-10 -10.1602 0.57844E-10 -10.2377 0.83654E+00 -0.0775 71 MnF+ 0.67840E-16 -16.1685 0.56751E-16 -16.2460 0.83654E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46970E-09 -9.3282 0.39293E-09 -9.4057 0.83654E+00 -0.0775 74 MnO2-2 0.20866E-10 -10.6806 0.10800E-10 -10.9666 0.51758E+00 -0.2860 75 HMnO2- 0.21112E-09 -9.6755 0.17627E-09 -9.7538 0.83494E+00 -0.0783 78 MnCl+ 0.16642E-13 -13.7788 0.13922E-13 -13.8563 0.83654E+00 -0.0775 80 NaCl,aq 0.12890E-05 -5.8898 0.12890E-05 -5.8898 0.10000E+01 0.0000 81 NaF,aq 0.13571E-08 -8.8674 0.13571E-08 -8.8674 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93052E-02 -2.0313 0.77552E-02 -2.1104 0.83343E+00 -0.0791 89 HPO3-2 0.16278E-14 -14.7884 0.84251E-15 -15.0744 0.51758E+00 -0.2860 91 H2PO3- 0.15075E-18 -18.8217 0.12587E-18 -18.9001 0.83494E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38384E-10 -10.4158 0.32079E-10 -10.4938 0.83573E+00 -0.0779 94 PO4-3 0.10562E-08 -8.9763 0.25562E-09 -9.5924 0.24203E+00 -0.6161 98 HP2O7-3 0.93771E-18 -18.0279 0.21626E-18 -18.6650 0.23063E+00 -0.6371 99 P2O7-4 0.90367E-17 -17.0440 0.69347E-18 -18.1590 0.76739E-01 -1.1150 100 H2S,aq 0.12463E-07 -7.9044 0.12420E-07 -7.9059 0.99652E+00 -0.0015 101 S2-2 0.10753E-13 -13.9685 0.55656E-14 -14.2545 0.51758E+00 -0.2860 107 SO3-2 0.24310E-17 -17.6142 0.12765E-17 -17.8940 0.52509E+00 -0.2798 109 HSO4- 0.72718E-19 -19.1384 0.60892E-19 -19.2154 0.83736E+00 -0.0771 Charge balance for all species = -.7395E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8869131E-10 -.2222544E-01 -.2236287E+02 0.0000 2 H2O 0.1000000E+01 0.5550494E+02 0.9981954E+06 0.0000 3 Cl- 0.2797016E-03 0.2809912E-03 0.9944619E+01 6.4962 4 SO4-- 0.1635093E-11 -.6509513E-04 -.6242244E+01 8.1841 5 HCO3- 0.1199699E-05 0.6566265E-04 0.3999568E+01 4.1292 6 HS- 0.6459137E-04 0.1296990E-03 0.4281928E+01 5.8597 7 Al+++ 0.9839922E-29 0.5295402E-05 0.1426289E+00 0.7390 8 H4SiO4 0.6959788E-03 0.1349290E-01 0.1294615E+04 -3.1574 9 Ca++ 0.1362915E-06 0.2342671E-06 0.9372592E-02 13.1018 10 Mg++ 0.2132218E-10 0.9374242E-10 0.2275094E-05 9.2942 11 Fe++ 0.5876754E-13 0.3615032E-07 0.2015368E-02 6.7350 12 K+ 0.1572214E-03 0.1579757E-03 0.6166400E+01 6.2467 13 Na+ 0.1995074E-01 0.2239771E-01 0.5140214E+03 8.3494 14 Mn++ 0.1885304E-10 0.2526792E-08 0.1385749E-03 9.2416 15 F- 0.4177099E-06 0.4190675E-06 0.7947570E-02 3.6695 16 HPO4-- 0.4499482E-07 0.4608938E-07 0.4415903E-02 12.6238 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279252E+02 -.1103138E-01 -.8278149E+02 0.0000000E+00 2 H2O -.7168568E+01 0.2754932E+02 -.3471789E+02 0.0000000E+00 3 Cl- 0.1394672E-03 0.1394672E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385938E+00 -.3230932E-04 0.1386261E+00 0.0000000E+00 5 HCO3- 0.3259100E-04 0.3259100E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385617E+00 0.6437479E-04 -.1386261E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628320E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6697067E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1162761E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4652811E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794285E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7840967E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111688E-01 0.6265260E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254148E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2080000E-06 0.2080000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287600E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1901E-14 Mass of aqueous solution: 0.497207E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2622 -0.581 56.78 1.754 1.039 17.35 hedenbergite 0.6799E-01 -1.168 16.87 1.227 0.3088 4.620 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4265E-01 -1.370 36.46 1.562 0.6674 11.73 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337951 g Volume = 2210.778606 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002700 moles log = -3.5686 Original solution: 1000.0103000 g Original solution / Rock added: 3703741.85 (Water/Rock Ratio), log = 6.5686 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1271 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9065E+00 0.9846 0.1006E+01 0.1022E+01 CO2,gas 0.1507E-07 1.0060 0.1709E-07 0.1698E-07 CH4,gas 0.8001E-01 1.0116 0.9122E-01 0.9018E-01 H2,gas 0.1348E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3042E-06 0.9956 0.3414E-06 0.3429E-06 S2,gas 0.1679E-28 1.0000 0.1892E-28 0.1892E-28 CO,gas 0.6143E-13 1.0000 0.6924E-13 0.6924E-13 SO3,gas 0.1579E-47 1.0000 0.1780E-47 0.1780E-47 SO2,gas 0.9342E-27 1.0000 0.1053E-26 0.1053E-26 HF,gas 0.3867E-15 1.0000 0.4358E-15 0.4358E-15 HCl,gas 0.4991E-17 1.0000 0.5626E-17 0.5626E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.13 -9.47 -3.155 0.16164E+05 -7.767 3 CH4,gas 4.54 1.80 -2.74 -0.685 0.46766E+04 -1.040 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.40 -8.17 -4.083 0.13943E+05 -6.467 6 S2,gas -7.34 -37.76 -30.42 -4.680 0.51945E+05 -28.723 7 CO,gas 3.21 -11.64 -14.86 -4.572 0.25371E+05 -13.160 8 SO3,gas 17.12 -32.33 -49.45 -12.362 0.84432E+05 -47.750 9 SO2,gas 0.83 -27.84 -28.68 -7.647 0.48964E+05 -26.978 10 HF,gas 0.47 -16.59 -17.06 -8.530 0.29129E+05 -15.361 11 HCl,gas 5.19 -13.76 -18.95 -9.474 0.32355E+05 -17.250 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.74 -0.44 -0.037 0.74908E+03 38 aragonite 0.97 -3.02 -3.99 -1.330 0.68148E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.02 -3.84 -1.279 0.65506E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.16 -4.06 -1.160 0.69297E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.16 -3.61 -1.033 0.61719E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.66 -3.40 -1.134 0.58065E+04 147 pyrrhotiteFe0.875 -6.02 -9.06 -3.04 -1.119 0.51937E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.66 -3.25 -1.083 0.55493E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.15 -4.18 -1.392 0.71312E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002700 MOLES New total amount of reactant added: 0.0002800 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3673E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002800 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1141036E-01 Osmotic coef. = 0.9836 True ionic strength = .2011124E-01 Chg. balance for total moles = -.3673E-10 Max. difference allowed = 0.1395E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88693E-10 -10.0521 0.74503E-10 -10.1278 0.84001E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27982E-03 -3.5531 0.23363E-03 -3.6315 0.83494E+00 -0.0783 4 SO4-- 0.16475E-11 -11.7832 0.85450E-12 -12.0683 0.51868E+00 -0.2851 5 HCO3- 0.12263E-05 -5.9114 0.10254E-05 -5.9891 0.83616E+00 -0.0777 6 HS- 0.65081E-04 -4.1865 0.54346E-04 -4.2648 0.83506E+00 -0.0783 7 Al+++ 0.98406E-29 -29.0070 0.22672E-29 -29.6445 0.23039E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13630E-06 -6.8655 0.70174E-07 -7.1538 0.51486E+00 -0.2883 10 Mg++ 0.21323E-10 -10.6711 0.10928E-10 -10.9615 0.51249E+00 -0.2903 11 Fe++ 0.58770E-13 -13.2308 0.30152E-13 -13.5207 0.51306E+00 -0.2898 12 K+ 0.15722E-03 -3.8035 0.13150E-03 -3.8811 0.83636E+00 -0.0776 13 Na+ 0.19951E-01 -1.7000 0.16655E-01 -1.7785 0.83479E+00 -0.0784 14 Mn++ 0.18854E-10 -10.7246 0.96812E-11 -11.0141 0.51348E+00 -0.2895 15 F- 0.42574E-06 -6.3709 0.35473E-06 -6.4501 0.83321E+00 -0.0792 16 HPO4-- 0.44993E-07 -7.3469 0.23340E-07 -7.6319 0.51875E+00 -0.2850 18 HSiO3- 0.10447E-01 -1.9810 0.87227E-02 -2.0593 0.83494E+00 -0.0783 19 Ca(HSiO3)+ 0.16664E-07 -7.7782 0.13940E-07 -7.8557 0.83654E+00 -0.0775 20 Mg(HSiO3)+ 0.32295E-11 -11.4909 0.27016E-11 -11.5684 0.83654E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66425E-16 -16.1777 0.55567E-16 -16.2552 0.83654E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52952E-05 -5.2761 0.44131E-05 -5.3553 0.83343E+00 -0.0791 26 CH4,aq 0.63569E-04 -4.1968 0.63348E-04 -4.1983 0.99652E+00 -0.0015 27 C2H6,aq 0.59437E-13 -13.2259 0.59230E-13 -13.2275 0.99652E+00 -0.0015 31 CO,aq 0.47496E-16 -16.3233 0.47496E-16 -16.3233 0.10000E+01 0.0000 32 CO2,aq 0.16381E-09 -9.7857 0.16324E-09 -9.7872 0.99652E+00 -0.0015 33 CO3-2 0.23226E-05 -5.6340 0.12021E-05 -5.9200 0.51757E+00 -0.2860 34 CaCO3,aq 0.10578E-08 -8.9756 0.10578E-08 -8.9756 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.21956E-11 -11.6584 0.18367E-11 -11.7360 0.83654E+00 -0.0775 36 CaCl+ 0.31716E-10 -10.4987 0.26532E-10 -10.5762 0.83654E+00 -0.0775 37 CaCl2,aq 0.14727E-14 -14.8319 0.14727E-14 -14.8319 0.10000E+01 0.0000 38 CaF+ 0.43445E-12 -12.3621 0.36344E-12 -12.4396 0.83654E+00 -0.0775 39 CaOH+ 0.80245E-07 -7.0956 0.67128E-07 -7.1731 0.83654E+00 -0.0775 40 CaSO4,aq 0.19041E-16 -16.7203 0.19041E-16 -16.7203 0.10000E+01 0.0000 41 HCl,aq 0.31896E-14 -14.4963 0.31896E-14 -14.4963 0.10000E+01 0.0000 45 HF,aq 0.18092E-12 -12.7425 0.18092E-12 -12.7425 0.10000E+01 0.0000 46 HF2- 0.25952E-19 -19.5858 0.21669E-19 -19.6642 0.83494E+00 -0.0783 48 FeCl+ 0.13329E-16 -16.8752 0.11150E-16 -16.9527 0.83654E+00 -0.0775 51 FeF+ 0.65339E-18 -18.1848 0.54659E-18 -18.2623 0.83654E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15748E-10 -10.8028 0.13174E-10 -10.8803 0.83654E+00 -0.0775 55 HFeO2- 0.35512E-07 -7.4496 0.29650E-07 -7.5280 0.83494E+00 -0.0783 56 FeO+ 0.11037E-16 -16.9572 0.92329E-17 -17.0347 0.83654E+00 -0.0775 58 FeO2- 0.40765E-09 -9.3897 0.34036E-09 -9.4681 0.83494E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55681E-09 -9.2543 0.55681E-09 -9.2543 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.20883E-14 -14.6802 0.17436E-14 -14.7585 0.83494E+00 -0.0783 65 MgCO3,aq 0.41289E-13 -13.3842 0.41289E-13 -13.3842 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.34938E-15 -15.4567 0.29227E-15 -15.5342 0.83654E+00 -0.0775 67 MgCl+ 0.44765E-14 -14.3491 0.37448E-14 -14.4266 0.83654E+00 -0.0775 68 MgF+ 0.25062E-15 -15.6010 0.20965E-15 -15.6785 0.83654E+00 -0.0775 69 MgOH+ 0.69148E-10 -10.1602 0.57845E-10 -10.2377 0.83654E+00 -0.0775 71 MnF+ 0.69148E-16 -16.1602 0.57845E-16 -16.2377 0.83654E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46971E-09 -9.3282 0.39293E-09 -9.4057 0.83654E+00 -0.0775 74 MnO2-2 0.20865E-10 -10.6806 0.10799E-10 -10.9666 0.51757E+00 -0.2860 75 HMnO2- 0.21112E-09 -9.6755 0.17627E-09 -9.7538 0.83494E+00 -0.0783 78 MnCl+ 0.16650E-13 -13.7786 0.13928E-13 -13.8561 0.83654E+00 -0.0775 80 NaCl,aq 0.12895E-05 -5.8896 0.12895E-05 -5.8896 0.10000E+01 0.0000 81 NaF,aq 0.13832E-08 -8.8591 0.13832E-08 -8.8591 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93050E-02 -2.0313 0.77550E-02 -2.1104 0.83343E+00 -0.0791 89 HPO3-2 0.16277E-14 -14.7884 0.84248E-15 -15.0744 0.51757E+00 -0.2860 91 H2PO3- 0.15075E-18 -18.8217 0.12587E-18 -18.9001 0.83494E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38384E-10 -10.4159 0.32079E-10 -10.4938 0.83573E+00 -0.0779 94 PO4-3 0.10561E-08 -8.9763 0.25560E-09 -9.5924 0.24202E+00 -0.6161 98 HP2O7-3 0.93767E-18 -18.0279 0.21625E-18 -18.6650 0.23062E+00 -0.6371 99 P2O7-4 0.90362E-17 -17.0440 0.69342E-18 -18.1590 0.76737E-01 -1.1150 100 H2S,aq 0.12558E-07 -7.9011 0.12514E-07 -7.9026 0.99652E+00 -0.0015 101 S2-2 0.10917E-13 -13.9619 0.56503E-14 -14.2479 0.51757E+00 -0.2860 107 SO3-2 0.24494E-17 -17.6109 0.12862E-17 -17.8907 0.52509E+00 -0.2798 109 HSO4- 0.73270E-19 -19.1351 0.61353E-19 -19.2122 0.83736E+00 -0.0771 Charge balance for all species = -.7402E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8869309E-10 -.2222516E-01 -.2236258E+02 0.0000 2 H2O 0.1000000E+01 0.5550494E+02 0.9981954E+06 0.0000 3 Cl- 0.2798198E-03 0.2811100E-03 0.9948822E+01 6.4964 4 SO4-- 0.1647460E-11 -.6647481E-04 -.6374547E+01 8.1874 5 HCO3- 0.1226294E-05 0.6711928E-04 0.4088293E+01 4.1387 6 HS- 0.6508084E-04 0.1315682E-03 0.4343640E+01 5.8630 7 Al+++ 0.9840607E-29 0.5295312E-05 0.1426264E+00 0.7390 8 H4SiO4 0.6959787E-03 0.1349272E-01 0.1294598E+04 -3.1574 9 Ca++ 0.1362974E-06 0.2342980E-06 0.9373828E-02 13.1018 10 Mg++ 0.2132310E-10 0.9374596E-10 0.2275180E-05 9.2942 11 Fe++ 0.5877009E-13 0.3614970E-07 0.2015334E-02 6.7350 12 K+ 0.1572246E-03 0.1579789E-03 0.6166524E+01 6.2467 13 Na+ 0.1995114E-01 0.2239811E-01 0.5140306E+03 8.3494 14 Mn++ 0.1885388E-10 0.2526800E-08 0.1385754E-03 9.2416 15 F- 0.4257426E-06 0.4271264E-06 0.8100404E-02 3.6777 16 HPO4-- 0.4499341E-07 0.4608792E-07 0.4415763E-02 12.6238 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279252E+02 -.1103124E-01 -.8278149E+02 0.0000000E+00 2 H2O -.7168560E+01 0.2754933E+02 -.3471789E+02 0.0000000E+00 3 Cl- 0.1395262E-03 0.1395262E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385939E+00 -.3299412E-04 0.1386269E+00 0.0000000E+00 5 HCO3- 0.3331400E-04 0.3331400E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385615E+00 0.6530259E-04 -.1386269E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628276E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696981E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1162915E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4652989E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794255E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7841127E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111708E-01 0.6265260E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254153E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2120000E-06 0.2120000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287529E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.9513E-14 Mass of aqueous solution: 0.497207E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002800 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2622 -0.581 56.77 1.754 1.039 17.35 hedenbergite 0.6799E-01 -1.168 16.87 1.227 0.3088 4.620 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.31 tr.625ac.25prg.125 0.4266E-01 -1.370 36.46 1.562 0.6675 11.73 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337954 g Volume = 2210.778634 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002800 moles log = -3.5528 Original solution: 1000.0103000 g Original solution / Rock added: 3571465.36 (Water/Rock Ratio), log = 6.5528 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1291 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9049E+00 0.9846 0.1006E+01 0.1022E+01 CO2,gas 0.1538E-07 1.0059 0.1746E-07 0.1736E-07 CH4,gas 0.8164E-01 1.0115 0.9324E-01 0.9218E-01 H2,gas 0.1346E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3060E-06 0.9956 0.3440E-06 0.3455E-06 S2,gas 0.1701E-28 1.0000 0.1921E-28 0.1921E-28 CO,gas 0.6268E-13 1.0000 0.7078E-13 0.7078E-13 SO3,gas 0.1588E-47 1.0000 0.1793E-47 0.1793E-47 SO2,gas 0.9397E-27 1.0000 0.1061E-26 0.1061E-26 HF,gas 0.3934E-15 1.0000 0.4442E-15 0.4442E-15 HCl,gas 0.4985E-17 1.0000 0.5628E-17 0.5628E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.12 -9.46 -3.152 0.16147E+05 -7.758 3 CH4,gas 4.54 1.81 -2.73 -0.682 0.46603E+04 -1.030 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.39 -8.16 -4.081 0.13937E+05 -6.463 6 S2,gas -7.34 -37.75 -30.42 -4.679 0.51934E+05 -28.717 7 CO,gas 3.21 -11.63 -14.85 -4.569 0.25354E+05 -13.150 8 SO3,gas 17.12 -32.32 -49.45 -12.361 0.84427E+05 -47.746 9 SO2,gas 0.83 -27.84 -28.67 -7.646 0.48959E+05 -26.974 10 HF,gas 0.47 -16.58 -17.05 -8.526 0.29115E+05 -15.352 11 HCl,gas 5.19 -13.76 -18.95 -9.474 0.32354E+05 -17.250 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.73 -0.43 -0.036 0.73494E+03 38 aragonite 0.97 -3.02 -3.98 -1.327 0.67985E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.02 -3.83 -1.276 0.65343E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.15 -4.05 -1.157 0.69134E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.15 -3.61 -1.030 0.61556E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.66 -3.40 -1.132 0.58009E+04 147 pyrrhotiteFe0.875 -6.02 -9.06 -3.04 -1.117 0.51881E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.66 -3.25 -1.082 0.55437E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.15 -4.17 -1.391 0.71256E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002800 MOLES New total amount of reactant added: 0.0002900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3673E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0002900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140952E-01 Osmotic coef. = 0.9844 True ionic strength = .2011170E-01 Chg. balance for total moles = -.3673E-10 Max. difference allowed = 0.1396E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88695E-10 -10.0521 0.74504E-10 -10.1278 0.84001E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27994E-03 -3.5529 0.23373E-03 -3.6313 0.83494E+00 -0.0783 4 SO4-- 0.16598E-11 -11.7799 0.86091E-12 -12.0650 0.51868E+00 -0.2851 5 HCO3- 0.12529E-05 -5.9021 0.10476E-05 -5.9798 0.83616E+00 -0.0777 6 HS- 0.65570E-04 -4.1833 0.54755E-04 -4.2616 0.83506E+00 -0.0783 7 Al+++ 0.98413E-29 -29.0069 0.22673E-29 -29.6445 0.23039E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13630E-06 -6.8655 0.70176E-07 -7.1538 0.51485E+00 -0.2883 10 Mg++ 0.21324E-10 -10.6711 0.10928E-10 -10.9614 0.51249E+00 -0.2903 11 Fe++ 0.58773E-13 -13.2308 0.30154E-13 -13.5207 0.51305E+00 -0.2898 12 K+ 0.15723E-03 -3.8035 0.13150E-03 -3.8811 0.83636E+00 -0.0776 13 Na+ 0.19952E-01 -1.7000 0.16655E-01 -1.7784 0.83479E+00 -0.0784 14 Mn++ 0.18855E-10 -10.7246 0.96815E-11 -11.0141 0.51348E+00 -0.2895 15 F- 0.43378E-06 -6.3627 0.36143E-06 -6.4420 0.83321E+00 -0.0792 16 HPO4-- 0.44992E-07 -7.3469 0.23340E-07 -7.6319 0.51875E+00 -0.2850 18 HSiO3- 0.10447E-01 -1.9810 0.87225E-02 -2.0594 0.83494E+00 -0.0783 19 Ca(HSiO3)+ 0.16664E-07 -7.7782 0.13940E-07 -7.8557 0.83654E+00 -0.0775 20 Mg(HSiO3)+ 0.32296E-11 -11.4909 0.27017E-11 -11.5684 0.83654E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66426E-16 -16.1777 0.55569E-16 -16.2552 0.83654E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52951E-05 -5.2761 0.44130E-05 -5.3553 0.83342E+00 -0.0791 26 CH4,aq 0.64949E-04 -4.1874 0.64723E-04 -4.1889 0.99652E+00 -0.0015 27 C2H6,aq 0.62045E-13 -13.2073 0.61829E-13 -13.2088 0.99652E+00 -0.0015 31 CO,aq 0.48527E-16 -16.3140 0.48527E-16 -16.3140 0.10000E+01 0.0000 32 CO2,aq 0.16736E-09 -9.7763 0.16678E-09 -9.7779 0.99652E+00 -0.0015 33 CO3-2 0.23730E-05 -5.6247 0.12282E-05 -5.9107 0.51757E+00 -0.2860 34 CaCO3,aq 0.10807E-08 -8.9663 0.10807E-08 -8.9663 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.22433E-11 -11.6491 0.18766E-11 -11.7266 0.83654E+00 -0.0775 36 CaCl+ 0.31731E-10 -10.4985 0.26544E-10 -10.5760 0.83654E+00 -0.0775 37 CaCl2,aq 0.14740E-14 -14.8315 0.14740E-14 -14.8315 0.10000E+01 0.0000 38 CaF+ 0.44267E-12 -12.3539 0.37031E-12 -12.4314 0.83654E+00 -0.0775 39 CaOH+ 0.80246E-07 -7.0956 0.67129E-07 -7.1731 0.83654E+00 -0.0775 40 CaSO4,aq 0.19185E-16 -16.7170 0.19185E-16 -16.7170 0.10000E+01 0.0000 41 HCl,aq 0.31910E-14 -14.4961 0.31910E-14 -14.4961 0.10000E+01 0.0000 45 HF,aq 0.18434E-12 -12.7344 0.18434E-12 -12.7344 0.10000E+01 0.0000 46 HF2- 0.26941E-19 -19.5696 0.22494E-19 -19.6479 0.83494E+00 -0.0783 48 FeCl+ 0.13335E-16 -16.8750 0.11156E-16 -16.9525 0.83654E+00 -0.0775 51 FeF+ 0.66574E-18 -18.1767 0.55692E-18 -18.2542 0.83654E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15748E-10 -10.8028 0.13174E-10 -10.8803 0.83654E+00 -0.0775 55 HFeO2- 0.35511E-07 -7.4496 0.29650E-07 -7.5280 0.83494E+00 -0.0783 56 FeO+ 0.11037E-16 -16.9571 0.92331E-17 -17.0347 0.83654E+00 -0.0775 58 FeO2- 0.40764E-09 -9.3897 0.34035E-09 -9.4681 0.83494E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55706E-09 -9.2541 0.55706E-09 -9.2541 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.21040E-14 -14.6769 0.17567E-14 -14.7553 0.83494E+00 -0.0783 65 MgCO3,aq 0.42185E-13 -13.3748 0.42185E-13 -13.3748 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.35697E-15 -15.4474 0.29862E-15 -15.5249 0.83654E+00 -0.0775 67 MgCl+ 0.44786E-14 -14.3489 0.37465E-14 -14.4264 0.83654E+00 -0.0775 68 MgF+ 0.25536E-15 -15.5929 0.21362E-15 -15.6704 0.83654E+00 -0.0775 69 MgOH+ 0.69150E-10 -10.1602 0.57847E-10 -10.2377 0.83654E+00 -0.0775 71 MnF+ 0.70455E-16 -16.1521 0.58939E-16 -16.2296 0.83654E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46972E-09 -9.3282 0.39294E-09 -9.4057 0.83654E+00 -0.0775 74 MnO2-2 0.20865E-10 -10.6806 0.10799E-10 -10.9666 0.51757E+00 -0.2860 75 HMnO2- 0.21112E-09 -9.6755 0.17627E-09 -9.7538 0.83494E+00 -0.0783 78 MnCl+ 0.16657E-13 -13.7784 0.13935E-13 -13.8559 0.83654E+00 -0.0775 80 NaCl,aq 0.12901E-05 -5.8894 0.12901E-05 -5.8894 0.10000E+01 0.0000 81 NaF,aq 0.14093E-08 -8.8510 0.14093E-08 -8.8510 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93049E-02 -2.0313 0.77549E-02 -2.1104 0.83342E+00 -0.0791 89 HPO3-2 0.16277E-14 -14.7884 0.84245E-15 -15.0745 0.51757E+00 -0.2860 91 H2PO3- 0.15075E-18 -18.8218 0.12586E-18 -18.9001 0.83494E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38383E-10 -10.4159 0.32078E-10 -10.4938 0.83573E+00 -0.0779 94 PO4-3 0.10561E-08 -8.9763 0.25559E-09 -9.5925 0.24202E+00 -0.6161 98 HP2O7-3 0.93763E-18 -18.0280 0.21624E-18 -18.6651 0.23062E+00 -0.6371 99 P2O7-4 0.90358E-17 -17.0440 0.69336E-18 -18.1590 0.76735E-01 -1.1150 100 H2S,aq 0.12652E-07 -7.8978 0.12608E-07 -7.8993 0.99652E+00 -0.0015 101 S2-2 0.11082E-13 -13.9554 0.57356E-14 -14.2414 0.51757E+00 -0.2860 107 SO3-2 0.24678E-17 -17.6077 0.12958E-17 -17.8875 0.52508E+00 -0.2798 109 HSO4- 0.73821E-19 -19.1318 0.61814E-19 -19.2089 0.83736E+00 -0.0771 Charge balance for all species = -.7405E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8869487E-10 -.2222487E-01 -.2236229E+02 0.0000 2 H2O 0.1000000E+01 0.5550494E+02 0.9981954E+06 0.0000 3 Cl- 0.2799380E-03 0.2812287E-03 0.9953024E+01 6.4965 4 SO4-- 0.1659826E-11 -.6785449E-04 -.6506850E+01 8.1906 5 HCO3- 0.1252888E-05 0.6857592E-04 0.4177018E+01 4.1480 6 HS- 0.6557030E-04 0.1334374E-03 0.4405352E+01 5.8662 7 Al+++ 0.9841292E-29 0.5295222E-05 0.1426240E+00 0.7390 8 H4SiO4 0.6959787E-03 0.1349254E-01 0.1294581E+04 -3.1574 9 Ca++ 0.1363033E-06 0.2343289E-06 0.9375064E-02 13.1018 10 Mg++ 0.2132403E-10 0.9375040E-10 0.2275287E-05 9.2942 11 Fe++ 0.5877265E-13 0.3614909E-07 0.2015299E-02 6.7350 12 K+ 0.1572277E-03 0.1579820E-03 0.6166647E+01 6.2467 13 Na+ 0.1995154E-01 0.2239851E-01 0.5140399E+03 8.3494 14 Mn++ 0.1885472E-10 0.2526809E-08 0.1385759E-03 9.2416 15 F- 0.4337753E-06 0.4351852E-06 0.8253239E-02 3.6858 16 HPO4-- 0.4499200E-07 0.4608646E-07 0.4415623E-02 12.6237 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279252E+02 -.1103110E-01 -.8278149E+02 0.0000000E+00 2 H2O -.7168551E+01 0.2754935E+02 -.3471790E+02 0.0000000E+00 3 Cl- 0.1395852E-03 0.1395852E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385939E+00 -.3367892E-04 0.1386276E+00 0.0000000E+00 5 HCO3- 0.3403700E-04 0.3403700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385614E+00 0.6623039E-04 -.1386276E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628232E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696894E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1163069E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4653211E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794225E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7841286E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111729E-01 0.6265260E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254157E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2160000E-06 0.2160000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287457E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1479E-13 Mass of aqueous solution: 0.497207E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0002900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2621 -0.581 56.77 1.754 1.039 17.35 hedenbergite 0.6798E-01 -1.168 16.87 1.227 0.3088 4.620 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4266E-01 -1.370 36.47 1.562 0.6676 11.74 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337958 g Volume = 2210.778661 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0002900 moles log = -3.5376 Original solution: 1000.0103000 g Original solution / Rock added: 3448311.38 (Water/Rock Ratio), log = 6.5376 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1311 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9033E+00 0.9845 0.1006E+01 0.1022E+01 CO2,gas 0.1568E-07 1.0059 0.1784E-07 0.1774E-07 CH4,gas 0.8326E-01 1.0115 0.9527E-01 0.9418E-01 H2,gas 0.1344E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3078E-06 0.9956 0.3466E-06 0.3481E-06 S2,gas 0.1724E-28 1.0000 0.1950E-28 0.1950E-28 CO,gas 0.6393E-13 1.0000 0.7231E-13 0.7231E-13 SO3,gas 0.1597E-47 1.0000 0.1807E-47 0.1807E-47 SO2,gas 0.9450E-27 1.0000 0.1069E-26 0.1069E-26 HF,gas 0.4001E-15 1.0000 0.4526E-15 0.4526E-15 HCl,gas 0.4978E-17 1.0000 0.5631E-17 0.5631E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.11 -9.45 -3.149 0.16131E+05 -7.749 3 CH4,gas 4.54 1.82 -2.72 -0.680 0.46444E+04 -1.021 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.39 -8.16 -4.080 0.13932E+05 -6.460 6 S2,gas -7.34 -37.74 -30.41 -4.678 0.51922E+05 -28.710 7 CO,gas 3.21 -11.62 -14.84 -4.566 0.25338E+05 -13.141 8 SO3,gas 17.12 -32.32 -49.44 -12.361 0.84421E+05 -47.743 9 SO2,gas 0.83 -27.84 -28.67 -7.645 0.48953E+05 -26.971 10 HF,gas 0.47 -16.57 -17.04 -8.522 0.29101E+05 -15.344 11 HCl,gas 5.19 -13.76 -18.95 -9.474 0.32354E+05 -17.249 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.72 -0.42 -0.035 0.72107E+03 38 aragonite 0.97 -3.01 -3.97 -1.324 0.67826E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.01 -3.82 -1.273 0.65184E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.14 -4.04 -1.154 0.68975E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.14 -3.60 -1.027 0.61397E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.65 -3.39 -1.131 0.57953E+04 147 pyrrhotiteFe0.875 -6.02 -9.05 -3.04 -1.116 0.51825E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.65 -3.24 -1.081 0.55381E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.15 -4.17 -1.390 0.71201E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0002900 MOLES New total amount of reactant added: 0.0003000 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3673E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003000 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140869E-01 Osmotic coef. = 0.9851 True ionic strength = .2011215E-01 Chg. balance for total moles = -.3673E-10 Max. difference allowed = 0.1396E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88697E-10 -10.0521 0.74506E-10 -10.1278 0.84001E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28006E-03 -3.5528 0.23383E-03 -3.6311 0.83494E+00 -0.0783 4 SO4-- 0.16722E-11 -11.7767 0.86732E-12 -12.0618 0.51867E+00 -0.2851 5 HCO3- 0.12795E-05 -5.8930 0.10699E-05 -5.9707 0.83616E+00 -0.0777 6 HS- 0.66060E-04 -4.1801 0.55164E-04 -4.2583 0.83506E+00 -0.0783 7 Al+++ 0.98420E-29 -29.0069 0.22675E-29 -29.6445 0.23039E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13631E-06 -6.8655 0.70179E-07 -7.1538 0.51485E+00 -0.2883 10 Mg++ 0.21325E-10 -10.6711 0.10929E-10 -10.9614 0.51249E+00 -0.2903 11 Fe++ 0.58775E-13 -13.2308 0.30155E-13 -13.5206 0.51305E+00 -0.2898 12 K+ 0.15723E-03 -3.8035 0.13150E-03 -3.8811 0.83636E+00 -0.0776 13 Na+ 0.19952E-01 -1.7000 0.16656E-01 -1.7784 0.83478E+00 -0.0784 14 Mn++ 0.18856E-10 -10.7246 0.96819E-11 -11.0140 0.51348E+00 -0.2895 15 F- 0.44181E-06 -6.3548 0.36812E-06 -6.4340 0.83321E+00 -0.0792 16 HPO4-- 0.44991E-07 -7.3469 0.23339E-07 -7.6319 0.51875E+00 -0.2850 18 HSiO3- 0.10447E-01 -1.9810 0.87224E-02 -2.0594 0.83494E+00 -0.0783 19 Ca(HSiO3)+ 0.16664E-07 -7.7782 0.13940E-07 -7.8557 0.83654E+00 -0.0775 20 Mg(HSiO3)+ 0.32296E-11 -11.4908 0.27017E-11 -11.5684 0.83654E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66428E-16 -16.1777 0.55570E-16 -16.2552 0.83654E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52950E-05 -5.2761 0.44130E-05 -5.3553 0.83342E+00 -0.0791 26 CH4,aq 0.66328E-04 -4.1783 0.66098E-04 -4.1798 0.99652E+00 -0.0015 27 C2H6,aq 0.64709E-13 -13.1890 0.64484E-13 -13.1905 0.99652E+00 -0.0015 31 CO,aq 0.49557E-16 -16.3049 0.49557E-16 -16.3049 0.10000E+01 0.0000 32 CO2,aq 0.17092E-09 -9.7672 0.17032E-09 -9.7687 0.99652E+00 -0.0015 33 CO3-2 0.24233E-05 -5.6156 0.12542E-05 -5.9016 0.51757E+00 -0.2860 34 CaCO3,aq 0.11037E-08 -8.9572 0.11037E-08 -8.9572 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.22910E-11 -11.6400 0.19165E-11 -11.7175 0.83654E+00 -0.0775 36 CaCl+ 0.31745E-10 -10.4983 0.26556E-10 -10.5758 0.83654E+00 -0.0775 37 CaCl2,aq 0.14753E-14 -14.8311 0.14753E-14 -14.8311 0.10000E+01 0.0000 38 CaF+ 0.45088E-12 -12.3459 0.37718E-12 -12.4234 0.83654E+00 -0.0775 39 CaOH+ 0.80248E-07 -7.0956 0.67131E-07 -7.1731 0.83654E+00 -0.0775 40 CaSO4,aq 0.19328E-16 -16.7138 0.19328E-16 -16.7138 0.10000E+01 0.0000 41 HCl,aq 0.31924E-14 -14.4959 0.31924E-14 -14.4959 0.10000E+01 0.0000 45 HF,aq 0.18776E-12 -12.7264 0.18776E-12 -12.7264 0.10000E+01 0.0000 46 HF2- 0.27949E-19 -19.5536 0.23336E-19 -19.6320 0.83494E+00 -0.0783 48 FeCl+ 0.13341E-16 -16.8748 0.11161E-16 -16.9523 0.83654E+00 -0.0775 51 FeF+ 0.67809E-18 -18.1687 0.56725E-18 -18.2462 0.83654E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15749E-10 -10.8028 0.13174E-10 -10.8803 0.83654E+00 -0.0775 55 HFeO2- 0.35511E-07 -7.4496 0.29649E-07 -7.5280 0.83494E+00 -0.0783 56 FeO+ 0.11037E-16 -16.9571 0.92332E-17 -17.0346 0.83654E+00 -0.0775 58 FeO2- 0.40763E-09 -9.3897 0.34035E-09 -9.4681 0.83494E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55730E-09 -9.2539 0.55730E-09 -9.2539 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.21197E-14 -14.6737 0.17698E-14 -14.7521 0.83494E+00 -0.0783 65 MgCO3,aq 0.43081E-13 -13.3657 0.43081E-13 -13.3657 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.36456E-15 -15.4382 0.30497E-15 -15.5157 0.83654E+00 -0.0775 67 MgCl+ 0.44806E-14 -14.3487 0.37482E-14 -14.4262 0.83654E+00 -0.0775 68 MgF+ 0.26010E-15 -15.5849 0.21758E-15 -15.6624 0.83654E+00 -0.0775 69 MgOH+ 0.69151E-10 -10.1602 0.57848E-10 -10.2377 0.83654E+00 -0.0775 71 MnF+ 0.71762E-16 -16.1441 0.60032E-16 -16.2216 0.83654E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46973E-09 -9.3282 0.39295E-09 -9.4057 0.83654E+00 -0.0775 74 MnO2-2 0.20864E-10 -10.6806 0.10799E-10 -10.9666 0.51757E+00 -0.2860 75 HMnO2- 0.21111E-09 -9.6755 0.17627E-09 -9.7538 0.83494E+00 -0.0783 78 MnCl+ 0.16665E-13 -13.7782 0.13941E-13 -13.8557 0.83654E+00 -0.0775 80 NaCl,aq 0.12907E-05 -5.8892 0.12907E-05 -5.8892 0.10000E+01 0.0000 81 NaF,aq 0.14354E-08 -8.8430 0.14354E-08 -8.8430 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93047E-02 -2.0313 0.77548E-02 -2.1104 0.83342E+00 -0.0791 89 HPO3-2 0.16276E-14 -14.7884 0.84242E-15 -15.0745 0.51757E+00 -0.2860 91 H2PO3- 0.15074E-18 -18.8218 0.12586E-18 -18.9001 0.83494E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38382E-10 -10.4159 0.32077E-10 -10.4938 0.83573E+00 -0.0779 94 PO4-3 0.10560E-08 -8.9763 0.25558E-09 -9.5925 0.24202E+00 -0.6162 98 HP2O7-3 0.93759E-18 -18.0280 0.21623E-18 -18.6651 0.23062E+00 -0.6371 99 P2O7-4 0.90353E-17 -17.0441 0.69331E-18 -18.1591 0.76734E-01 -1.1150 100 H2S,aq 0.12747E-07 -7.8946 0.12702E-07 -7.8961 0.99652E+00 -0.0015 101 S2-2 0.11248E-13 -13.9489 0.58215E-14 -14.2350 0.51757E+00 -0.2860 107 SO3-2 0.24862E-17 -17.6045 0.13054E-17 -17.8842 0.52508E+00 -0.2798 109 HSO4- 0.74372E-19 -19.1286 0.62276E-19 -19.2057 0.83736E+00 -0.0771 Charge balance for all species = -.7412E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8869665E-10 -.2222458E-01 -.2236200E+02 0.0000 2 H2O 0.1000000E+01 0.5550494E+02 0.9981954E+06 0.0000 3 Cl- 0.2800562E-03 0.2813475E-03 0.9957227E+01 6.4967 4 SO4-- 0.1672193E-11 -.6923417E-04 -.6639153E+01 8.1938 5 HCO3- 0.1279481E-05 0.7003256E-04 0.4265742E+01 4.1571 6 HS- 0.6605976E-04 0.1353067E-03 0.4467063E+01 5.8695 7 Al+++ 0.9841977E-29 0.5295131E-05 0.1426216E+00 0.7390 8 H4SiO4 0.6959787E-03 0.1349236E-01 0.1294564E+04 -3.1574 9 Ca++ 0.1363093E-06 0.2343598E-06 0.9376299E-02 13.1018 10 Mg++ 0.2132496E-10 0.9375216E-10 0.2275330E-05 9.2942 11 Fe++ 0.5877520E-13 0.3614847E-07 0.2015265E-02 6.7350 12 K+ 0.1572309E-03 0.1579852E-03 0.6166770E+01 6.2467 13 Na+ 0.1995194E-01 0.2239892E-01 0.5140491E+03 8.3494 14 Mn++ 0.1885556E-10 0.2526817E-08 0.1385763E-03 9.2416 15 F- 0.4418080E-06 0.4432440E-06 0.8406073E-02 3.6938 16 HPO4-- 0.4499059E-07 0.4608500E-07 0.4415483E-02 12.6237 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279252E+02 -.1103096E-01 -.8278148E+02 0.0000000E+00 2 H2O -.7168543E+01 0.2754936E+02 -.3471790E+02 0.0000000E+00 3 Cl- 0.1396442E-03 0.1396442E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385940E+00 -.3436373E-04 0.1386283E+00 0.0000000E+00 5 HCO3- 0.3476000E-04 0.3476000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385612E+00 0.6715820E-04 -.1386283E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628189E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696808E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1163223E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4653300E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794195E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7841446E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111749E-01 0.6265259E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254162E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2200000E-06 0.2200000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287386E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.9673E-14 Mass of aqueous solution: 0.497207E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2621 -0.581 56.76 1.754 1.039 17.35 hedenbergite 0.6798E-01 -1.168 16.87 1.227 0.3088 4.619 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4267E-01 -1.370 36.47 1.562 0.6677 11.74 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337961 g Volume = 2210.778689 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003000 moles log = -3.5229 Original solution: 1000.0103000 g Original solution / Rock added: 3333367.67 (Water/Rock Ratio), log = 6.5229 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1332 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9017E+00 0.9845 0.1006E+01 0.1022E+01 CO2,gas 0.1599E-07 1.0059 0.1822E-07 0.1812E-07 CH4,gas 0.8488E-01 1.0115 0.9729E-01 0.9619E-01 H2,gas 0.1341E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3095E-06 0.9956 0.3492E-06 0.3507E-06 S2,gas 0.1747E-28 1.0000 0.1979E-28 0.1979E-28 CO,gas 0.6517E-13 1.0000 0.7385E-13 0.7385E-13 SO3,gas 0.1606E-47 1.0000 0.1820E-47 0.1820E-47 SO2,gas 0.9504E-27 1.0000 0.1077E-26 0.1077E-26 HF,gas 0.4068E-15 1.0000 0.4610E-15 0.4610E-15 HCl,gas 0.4971E-17 1.0000 0.5633E-17 0.5633E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.10 -9.44 -3.146 0.16116E+05 -7.739 3 CH4,gas 4.54 1.83 -2.71 -0.678 0.46288E+04 -1.012 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.39 -8.16 -4.078 0.13926E+05 -6.457 6 S2,gas -7.34 -37.74 -30.40 -4.677 0.51911E+05 -28.704 7 CO,gas 3.21 -11.62 -14.83 -4.563 0.25323E+05 -13.132 8 SO3,gas 17.12 -32.32 -49.44 -12.360 0.84415E+05 -47.740 9 SO2,gas 0.83 -27.83 -28.67 -7.644 0.48948E+05 -26.968 10 HF,gas 0.47 -16.56 -17.04 -8.518 0.29087E+05 -15.336 11 HCl,gas 5.19 -13.76 -18.95 -9.474 0.32354E+05 -17.249 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.72 -0.41 -0.035 0.70745E+03 38 aragonite 0.97 -3.00 -3.96 -1.321 0.67670E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -3.00 -3.81 -1.269 0.65028E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.13 -4.03 -1.152 0.68819E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.13 -3.59 -1.025 0.61241E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.65 -3.39 -1.130 0.57898E+04 147 pyrrhotiteFe0.875 -6.02 -9.05 -3.03 -1.115 0.51770E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.65 -3.24 -1.080 0.55326E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.14 -4.17 -1.389 0.71145E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003000 MOLES New total amount of reactant added: 0.0003100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3673E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140786E-01 Osmotic coef. = 0.9858 True ionic strength = .2011261E-01 Chg. balance for total moles = -.3673E-10 Max. difference allowed = 0.1397E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88698E-10 -10.0521 0.74507E-10 -10.1278 0.84000E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28017E-03 -3.5526 0.23393E-03 -3.6309 0.83493E+00 -0.0783 4 SO4-- 0.16846E-11 -11.7735 0.87373E-12 -12.0586 0.51867E+00 -0.2851 5 HCO3- 0.13061E-05 -5.8840 0.10921E-05 -5.9617 0.83616E+00 -0.0777 6 HS- 0.66549E-04 -4.1769 0.55572E-04 -4.2551 0.83506E+00 -0.0783 7 Al+++ 0.98427E-29 -29.0069 0.22676E-29 -29.6444 0.23038E+00 -0.6375 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13632E-06 -6.8655 0.70182E-07 -7.1538 0.51485E+00 -0.2883 10 Mg++ 0.21326E-10 -10.6711 0.10929E-10 -10.9614 0.51248E+00 -0.2903 11 Fe++ 0.58778E-13 -13.2308 0.30156E-13 -13.5206 0.51305E+00 -0.2898 12 K+ 0.15723E-03 -3.8035 0.13150E-03 -3.8811 0.83636E+00 -0.0776 13 Na+ 0.19952E-01 -1.7000 0.16656E-01 -1.7784 0.83478E+00 -0.0784 14 Mn++ 0.18856E-10 -10.7245 0.96823E-11 -11.0140 0.51347E+00 -0.2895 15 F- 0.44984E-06 -6.3469 0.37481E-06 -6.4262 0.83321E+00 -0.0792 16 HPO4-- 0.44989E-07 -7.3469 0.23338E-07 -7.6319 0.51874E+00 -0.2850 18 HSiO3- 0.10447E-01 -1.9810 0.87222E-02 -2.0594 0.83493E+00 -0.0783 19 Ca(HSiO3)+ 0.16665E-07 -7.7782 0.13941E-07 -7.8557 0.83654E+00 -0.0775 20 Mg(HSiO3)+ 0.32297E-11 -11.4908 0.27018E-11 -11.5684 0.83654E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66429E-16 -16.1776 0.55571E-16 -16.2552 0.83654E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52949E-05 -5.2761 0.44129E-05 -5.3553 0.83342E+00 -0.0791 26 CH4,aq 0.67708E-04 -4.1694 0.67473E-04 -4.1709 0.99652E+00 -0.0015 27 C2H6,aq 0.67429E-13 -13.1712 0.67195E-13 -13.1727 0.99652E+00 -0.0015 31 CO,aq 0.50588E-16 -16.2960 0.50588E-16 -16.2960 0.10000E+01 0.0000 32 CO2,aq 0.17447E-09 -9.7583 0.17386E-09 -9.7598 0.99652E+00 -0.0015 33 CO3-2 0.24736E-05 -5.6067 0.12803E-05 -5.8927 0.51757E+00 -0.2860 34 CaCO3,aq 0.11266E-08 -8.9482 0.11266E-08 -8.9482 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.23387E-11 -11.6310 0.19564E-11 -11.7085 0.83654E+00 -0.0775 36 CaCl+ 0.31760E-10 -10.4981 0.26569E-10 -10.5756 0.83654E+00 -0.0775 37 CaCl2,aq 0.14766E-14 -14.8307 0.14766E-14 -14.8307 0.10000E+01 0.0000 38 CaF+ 0.45910E-12 -12.3381 0.38405E-12 -12.4156 0.83654E+00 -0.0775 39 CaOH+ 0.80250E-07 -7.0956 0.67132E-07 -7.1731 0.83654E+00 -0.0775 40 CaSO4,aq 0.19472E-16 -16.7106 0.19472E-16 -16.7106 0.10000E+01 0.0000 41 HCl,aq 0.31938E-14 -14.4957 0.31938E-14 -14.4957 0.10000E+01 0.0000 45 HF,aq 0.19117E-12 -12.7186 0.19117E-12 -12.7186 0.10000E+01 0.0000 46 HF2- 0.28975E-19 -19.5380 0.24192E-19 -19.6163 0.83493E+00 -0.0783 48 FeCl+ 0.13348E-16 -16.8746 0.11166E-16 -16.9521 0.83654E+00 -0.0775 51 FeF+ 0.69045E-18 -18.1609 0.57759E-18 -18.2384 0.83654E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15749E-10 -10.8027 0.13175E-10 -10.8803 0.83654E+00 -0.0775 55 HFeO2- 0.35510E-07 -7.4496 0.29649E-07 -7.5280 0.83493E+00 -0.0783 56 FeO+ 0.11038E-16 -16.9571 0.92334E-17 -17.0346 0.83654E+00 -0.0775 58 FeO2- 0.40763E-09 -9.3897 0.34034E-09 -9.4681 0.83493E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55754E-09 -9.2537 0.55754E-09 -9.2537 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.21354E-14 -14.6705 0.17830E-14 -14.7489 0.83493E+00 -0.0783 65 MgCO3,aq 0.43977E-13 -13.3568 0.43977E-13 -13.3568 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.37215E-15 -15.4293 0.31132E-15 -15.5068 0.83654E+00 -0.0775 67 MgCl+ 0.44827E-14 -14.3485 0.37499E-14 -14.4260 0.83654E+00 -0.0775 68 MgF+ 0.26484E-15 -15.5770 0.22155E-15 -15.6545 0.83654E+00 -0.0775 69 MgOH+ 0.69152E-10 -10.1602 0.57849E-10 -10.2377 0.83654E+00 -0.0775 71 MnF+ 0.73070E-16 -16.1363 0.61126E-16 -16.2138 0.83654E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46974E-09 -9.3281 0.39296E-09 -9.4057 0.83654E+00 -0.0775 74 MnO2-2 0.20863E-10 -10.6806 0.10798E-10 -10.9666 0.51757E+00 -0.2860 75 HMnO2- 0.21111E-09 -9.6755 0.17626E-09 -9.7538 0.83493E+00 -0.0783 78 MnCl+ 0.16673E-13 -13.7780 0.13947E-13 -13.8555 0.83654E+00 -0.0775 80 NaCl,aq 0.12912E-05 -5.8890 0.12912E-05 -5.8890 0.10000E+01 0.0000 81 NaF,aq 0.14616E-08 -8.8352 0.14616E-08 -8.8352 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93045E-02 -2.0313 0.77546E-02 -2.1104 0.83342E+00 -0.0791 89 HPO3-2 0.16276E-14 -14.7885 0.84238E-15 -15.0745 0.51757E+00 -0.2860 91 H2PO3- 0.15074E-18 -18.8218 0.12586E-18 -18.9001 0.83493E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38382E-10 -10.4159 0.32077E-10 -10.4938 0.83573E+00 -0.0779 94 PO4-3 0.10560E-08 -8.9763 0.25556E-09 -9.5925 0.24201E+00 -0.6162 98 HP2O7-3 0.93755E-18 -18.0280 0.21621E-18 -18.6651 0.23061E+00 -0.6371 99 P2O7-4 0.90348E-17 -17.0441 0.69326E-18 -18.1591 0.76732E-01 -1.1150 100 H2S,aq 0.12842E-07 -7.8914 0.12797E-07 -7.8929 0.99652E+00 -0.0015 101 S2-2 0.11415E-13 -13.9425 0.59081E-14 -14.2286 0.51757E+00 -0.2860 107 SO3-2 0.25046E-17 -17.6013 0.13151E-17 -17.8810 0.52508E+00 -0.2798 109 HSO4- 0.74923E-19 -19.1254 0.62737E-19 -19.2025 0.83736E+00 -0.0771 Charge balance for all species = -.7406E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8869843E-10 -.2222429E-01 -.2236171E+02 0.0000 2 H2O 0.1000000E+01 0.5550495E+02 0.9981953E+06 0.0000 3 Cl- 0.2801744E-03 0.2814663E-03 0.9961430E+01 6.4969 4 SO4-- 0.1684558E-11 -.7061386E-04 -.6771457E+01 8.1970 5 HCO3- 0.1306073E-05 0.7148919E-04 0.4354467E+01 4.1661 6 HS- 0.6654923E-04 0.1371759E-03 0.4528775E+01 5.8727 7 Al+++ 0.9842662E-29 0.5295041E-05 0.1426191E+00 0.7390 8 H4SiO4 0.6959787E-03 0.1349219E-01 0.1294546E+04 -3.1574 9 Ca++ 0.1363152E-06 0.2343907E-06 0.9377535E-02 13.1018 10 Mg++ 0.2132589E-10 0.9375749E-10 0.2275459E-05 9.2942 11 Fe++ 0.5877776E-13 0.3614785E-07 0.2015231E-02 6.7350 12 K+ 0.1572340E-03 0.1579883E-03 0.6166893E+01 6.2467 13 Na+ 0.1995234E-01 0.2239932E-01 0.5140583E+03 8.3494 14 Mn++ 0.1885639E-10 0.2526825E-08 0.1385768E-03 9.2416 15 F- 0.4498406E-06 0.4513028E-06 0.8558907E-02 3.7016 16 HPO4-- 0.4498918E-07 0.4608354E-07 0.4415343E-02 12.6237 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279251E+02 -.1103082E-01 -.8278148E+02 0.0000000E+00 2 H2O -.7168535E+01 0.2754937E+02 -.3471790E+02 0.0000000E+00 3 Cl- 0.1397032E-03 0.1397032E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385940E+00 -.3504854E-04 0.1386291E+00 0.0000000E+00 5 HCO3- 0.3548300E-04 0.3548300E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385610E+00 0.6808601E-04 -.1386291E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628145E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696722E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1163376E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4653566E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794165E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7841606E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111769E-01 0.6265259E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254166E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2240000E-06 0.2240000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287314E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.4524E-14 Mass of aqueous solution: 0.497207E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2621 -0.582 56.76 1.754 1.039 17.35 hedenbergite 0.6797E-01 -1.168 16.86 1.227 0.3087 4.619 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4267E-01 -1.370 36.48 1.562 0.6678 11.74 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337964 g Volume = 2210.778717 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003100 moles log = -3.5086 Original solution: 1000.0103000 g Original solution / Rock added: 3225839.68 (Water/Rock Ratio), log = 6.5086 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1352 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9001E+00 0.9845 0.1006E+01 0.1022E+01 CO2,gas 0.1629E-07 1.0059 0.1860E-07 0.1849E-07 CH4,gas 0.8649E-01 1.0115 0.9932E-01 0.9819E-01 H2,gas 0.1339E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3113E-06 0.9956 0.3518E-06 0.3533E-06 S2,gas 0.1770E-28 1.0000 0.2009E-28 0.2009E-28 CO,gas 0.6641E-13 1.0000 0.7539E-13 0.7539E-13 SO3,gas 0.1616E-47 1.0000 0.1834E-47 0.1834E-47 SO2,gas 0.9558E-27 1.0000 0.1085E-26 0.1085E-26 HF,gas 0.4135E-15 1.0000 0.4694E-15 0.4694E-15 HCl,gas 0.4964E-17 1.0000 0.5636E-17 0.5636E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.09 -9.43 -3.143 0.16100E+05 -7.730 3 CH4,gas 4.54 1.84 -2.70 -0.675 0.46135E+04 -1.003 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.38 -8.15 -4.076 0.13921E+05 -6.454 6 S2,gas -7.34 -37.73 -30.40 -4.676 0.51900E+05 -28.697 7 CO,gas 3.21 -11.61 -14.82 -4.561 0.25308E+05 -13.123 8 SO3,gas 17.12 -32.31 -49.44 -12.359 0.84410E+05 -47.737 9 SO2,gas 0.83 -27.83 -28.66 -7.644 0.48942E+05 -26.965 10 HF,gas 0.47 -16.55 -17.03 -8.514 0.29074E+05 -15.328 11 HCl,gas 5.19 -13.76 -18.95 -9.474 0.32353E+05 -17.249 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.71 -0.41 -0.034 0.69407E+03 38 aragonite 0.97 -2.99 -3.95 -1.318 0.67518E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.99 -3.80 -1.266 0.64875E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.12 -4.02 -1.149 0.68666E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.12 -3.58 -1.022 0.61089E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.65 -3.39 -1.129 0.57843E+04 147 pyrrhotiteFe0.875 -6.02 -9.05 -3.03 -1.114 0.51715E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.65 -3.24 -1.079 0.55271E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.14 -4.16 -1.388 0.71090E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003100 MOLES New total amount of reactant added: 0.0003200 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3673E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003200 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140703E-01 Osmotic coef. = 0.9866 True ionic strength = .2011306E-01 Chg. balance for total moles = -.3673E-10 Max. difference allowed = 0.1398E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88700E-10 -10.0521 0.74508E-10 -10.1278 0.84000E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28029E-03 -3.5524 0.23403E-03 -3.6307 0.83493E+00 -0.0783 4 SO4-- 0.16969E-11 -11.7703 0.88014E-12 -12.0554 0.51867E+00 -0.2851 5 HCO3- 0.13327E-05 -5.8753 0.11143E-05 -5.9530 0.83616E+00 -0.0777 6 HS- 0.67039E-04 -4.1737 0.55981E-04 -4.2520 0.83506E+00 -0.0783 7 Al+++ 0.98433E-29 -29.0069 0.22677E-29 -29.6444 0.23038E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13632E-06 -6.8654 0.70184E-07 -7.1538 0.51485E+00 -0.2883 10 Mg++ 0.21327E-10 -10.6711 0.10930E-10 -10.9614 0.51248E+00 -0.2903 11 Fe++ 0.58780E-13 -13.2308 0.30157E-13 -13.5206 0.51304E+00 -0.2898 12 K+ 0.15724E-03 -3.8034 0.13151E-03 -3.8811 0.83636E+00 -0.0776 13 Na+ 0.19953E-01 -1.7000 0.16656E-01 -1.7784 0.83478E+00 -0.0784 14 Mn++ 0.18857E-10 -10.7245 0.96827E-11 -11.0140 0.51347E+00 -0.2895 15 F- 0.45787E-06 -6.3393 0.38150E-06 -6.4185 0.83321E+00 -0.0792 16 HPO4-- 0.44988E-07 -7.3469 0.23337E-07 -7.6320 0.51874E+00 -0.2850 18 HSiO3- 0.10446E-01 -1.9810 0.87220E-02 -2.0594 0.83493E+00 -0.0783 19 Ca(HSiO3)+ 0.16665E-07 -7.7782 0.13941E-07 -7.8557 0.83654E+00 -0.0775 20 Mg(HSiO3)+ 0.32298E-11 -11.4908 0.27018E-11 -11.5683 0.83654E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66430E-16 -16.1776 0.55572E-16 -16.2551 0.83654E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52948E-05 -5.2762 0.44128E-05 -5.3553 0.83342E+00 -0.0791 26 CH4,aq 0.69088E-04 -4.1606 0.68848E-04 -4.1621 0.99652E+00 -0.0015 27 C2H6,aq 0.70205E-13 -13.1536 0.69961E-13 -13.1551 0.99652E+00 -0.0015 31 CO,aq 0.51619E-16 -16.2872 0.51619E-16 -16.2872 0.10000E+01 0.0000 32 CO2,aq 0.17803E-09 -9.7495 0.17741E-09 -9.7510 0.99652E+00 -0.0015 33 CO3-2 0.25240E-05 -5.5979 0.13063E-05 -5.8840 0.51756E+00 -0.2860 34 CaCO3,aq 0.11496E-08 -8.9395 0.11496E-08 -8.9395 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.23864E-11 -11.6223 0.19963E-11 -11.6998 0.83654E+00 -0.0775 36 CaCl+ 0.31775E-10 -10.4979 0.26581E-10 -10.5754 0.83654E+00 -0.0775 37 CaCl2,aq 0.14779E-14 -14.8304 0.14779E-14 -14.8304 0.10000E+01 0.0000 38 CaF+ 0.46731E-12 -12.3304 0.39092E-12 -12.4079 0.83654E+00 -0.0775 39 CaOH+ 0.80251E-07 -7.0955 0.67133E-07 -7.1731 0.83654E+00 -0.0775 40 CaSO4,aq 0.19615E-16 -16.7074 0.19615E-16 -16.7074 0.10000E+01 0.0000 41 HCl,aq 0.31952E-14 -14.4955 0.31952E-14 -14.4955 0.10000E+01 0.0000 45 HF,aq 0.19459E-12 -12.7109 0.19459E-12 -12.7109 0.10000E+01 0.0000 46 HF2- 0.30019E-19 -19.5226 0.25064E-19 -19.6009 0.83493E+00 -0.0783 48 FeCl+ 0.13354E-16 -16.8744 0.11171E-16 -16.9519 0.83654E+00 -0.0775 51 FeF+ 0.70280E-18 -18.1532 0.58792E-18 -18.2307 0.83654E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15749E-10 -10.8027 0.13175E-10 -10.8803 0.83654E+00 -0.0775 55 HFeO2- 0.35509E-07 -7.4497 0.29648E-07 -7.5280 0.83493E+00 -0.0783 56 FeO+ 0.11038E-16 -16.9571 0.92336E-17 -17.0346 0.83654E+00 -0.0775 58 FeO2- 0.40762E-09 -9.3897 0.34034E-09 -9.4681 0.83493E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55779E-09 -9.2535 0.55779E-09 -9.2535 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.21511E-14 -14.6673 0.17961E-14 -14.7457 0.83493E+00 -0.0783 65 MgCO3,aq 0.44874E-13 -13.3480 0.44874E-13 -13.3480 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.37974E-15 -15.4205 0.31766E-15 -15.4980 0.83654E+00 -0.0775 67 MgCl+ 0.44847E-14 -14.3483 0.37517E-14 -14.4258 0.83654E+00 -0.0775 68 MgF+ 0.26957E-15 -15.5693 0.22551E-15 -15.6468 0.83654E+00 -0.0775 69 MgOH+ 0.69154E-10 -10.1602 0.57850E-10 -10.2377 0.83654E+00 -0.0775 71 MnF+ 0.74378E-16 -16.1286 0.62220E-16 -16.2061 0.83654E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46975E-09 -9.3281 0.39296E-09 -9.4056 0.83654E+00 -0.0775 74 MnO2-2 0.20863E-10 -10.6806 0.10798E-10 -10.9667 0.51756E+00 -0.2860 75 HMnO2- 0.21111E-09 -9.6755 0.17626E-09 -9.7538 0.83493E+00 -0.0783 78 MnCl+ 0.16680E-13 -13.7778 0.13954E-13 -13.8553 0.83654E+00 -0.0775 80 NaCl,aq 0.12918E-05 -5.8888 0.12918E-05 -5.8888 0.10000E+01 0.0000 81 NaF,aq 0.14877E-08 -8.8275 0.14877E-08 -8.8275 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93044E-02 -2.0313 0.77545E-02 -2.1104 0.83342E+00 -0.0791 89 HPO3-2 0.16275E-14 -14.7885 0.84235E-15 -15.0745 0.51756E+00 -0.2860 91 H2PO3- 0.15074E-18 -18.8218 0.12586E-18 -18.9001 0.83493E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38381E-10 -10.4159 0.32076E-10 -10.4938 0.83573E+00 -0.0779 94 PO4-3 0.10559E-08 -8.9764 0.25555E-09 -9.5925 0.24201E+00 -0.6162 98 HP2O7-3 0.93751E-18 -18.0280 0.21620E-18 -18.6651 0.23061E+00 -0.6371 99 P2O7-4 0.90344E-17 -17.0441 0.69321E-18 -18.1591 0.76730E-01 -1.1150 100 H2S,aq 0.12936E-07 -7.8882 0.12891E-07 -7.8897 0.99652E+00 -0.0015 101 S2-2 0.11584E-13 -13.9362 0.59953E-14 -14.2222 0.51756E+00 -0.2860 107 SO3-2 0.25229E-17 -17.5981 0.13247E-17 -17.8779 0.52508E+00 -0.2798 109 HSO4- 0.75474E-19 -19.1222 0.63198E-19 -19.1993 0.83736E+00 -0.0771 Charge balance for all species = -.7398E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8870022E-10 -.2222400E-01 -.2236142E+02 0.0000 2 H2O 0.1000000E+01 0.5550495E+02 0.9981953E+06 0.0000 3 Cl- 0.2802926E-03 0.2815850E-03 0.9965633E+01 6.4971 4 SO4-- 0.1696924E-11 -.7199354E-04 -.6903760E+01 8.2001 5 HCO3- 0.1332664E-05 0.7294582E-04 0.4443192E+01 4.1748 6 HS- 0.6703869E-04 0.1390452E-03 0.4590487E+01 5.8758 7 Al+++ 0.9843347E-29 0.5294950E-05 0.1426167E+00 0.7390 8 H4SiO4 0.6959787E-03 0.1349201E-01 0.1294529E+04 -3.1574 9 Ca++ 0.1363211E-06 0.2344216E-06 0.9378771E-02 13.1018 10 Mg++ 0.2132681E-10 0.9376014E-10 0.2275523E-05 9.2942 11 Fe++ 0.5878031E-13 0.3614724E-07 0.2015196E-02 6.7350 12 K+ 0.1572372E-03 0.1579915E-03 0.6167016E+01 6.2467 13 Na+ 0.1995275E-01 0.2239972E-01 0.5140675E+03 8.3494 14 Mn++ 0.1885723E-10 0.2526834E-08 0.1385772E-03 9.2416 15 F- 0.4578733E-06 0.4593617E-06 0.8711741E-02 3.7093 16 HPO4-- 0.4498777E-07 0.4608209E-07 0.4415203E-02 12.6236 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279251E+02 -.1103068E-01 -.8278148E+02 0.0000000E+00 2 H2O -.7168527E+01 0.2754938E+02 -.3471790E+02 0.0000000E+00 3 Cl- 0.1397622E-03 0.1397622E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385940E+00 -.3573334E-04 0.1386298E+00 0.0000000E+00 5 HCO3- 0.3620600E-04 0.3620600E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385608E+00 0.6901381E-04 -.1386298E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628101E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696635E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1163530E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4653700E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794136E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7841766E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111790E-01 0.6265259E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254171E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2280000E-06 0.2280000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287243E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.6897E-14 Mass of aqueous solution: 0.497208E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003200 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2621 -0.582 56.76 1.754 1.039 17.35 hedenbergite 0.6797E-01 -1.168 16.86 1.227 0.3087 4.619 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4268E-01 -1.370 36.48 1.562 0.6679 11.74 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337968 g Volume = 2210.778744 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003200 moles log = -3.4949 Original solution: 1000.0103000 g Original solution / Rock added: 3125032.19 (Water/Rock Ratio), log = 6.4949 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1372 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8985E+00 0.9845 0.1006E+01 0.1022E+01 CO2,gas 0.1659E-07 1.0058 0.1898E-07 0.1887E-07 CH4,gas 0.8810E-01 1.0115 0.1013E+00 0.1002E+00 H2,gas 0.1336E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3130E-06 0.9956 0.3544E-06 0.3559E-06 S2,gas 0.1792E-28 1.0000 0.2038E-28 0.2038E-28 CO,gas 0.6764E-13 1.0000 0.7692E-13 0.7692E-13 SO3,gas 0.1625E-47 1.0000 0.1847E-47 0.1847E-47 SO2,gas 0.9611E-27 1.0000 0.1093E-26 0.1093E-26 HF,gas 0.4201E-15 1.0000 0.4778E-15 0.4778E-15 HCl,gas 0.4958E-17 1.0000 0.5638E-17 0.5638E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.08 -9.42 -3.140 0.16086E+05 -7.722 3 CH4,gas 4.54 1.85 -2.69 -0.673 0.45986E+04 -0.994 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.38 -8.15 -4.075 0.13915E+05 -6.451 6 S2,gas -7.34 -37.73 -30.39 -4.675 0.51890E+05 -28.691 7 CO,gas 3.21 -11.60 -14.81 -4.558 0.25293E+05 -13.114 8 SO3,gas 17.12 -32.31 -49.43 -12.358 0.84404E+05 -47.733 9 SO2,gas 0.83 -27.83 -28.66 -7.643 0.48937E+05 -26.961 10 HF,gas 0.47 -16.55 -17.02 -8.510 0.29061E+05 -15.321 11 HCl,gas 5.19 -13.76 -18.95 -9.474 0.32353E+05 -17.249 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.70 -0.40 -0.033 0.68094E+03 38 aragonite 0.97 -2.98 -3.95 -1.315 0.67368E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.98 -3.79 -1.264 0.64726E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.12 -4.01 -1.147 0.68517E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.12 -3.57 -1.020 0.60939E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.64 -3.38 -1.128 0.57789E+04 147 pyrrhotiteFe0.875 -6.02 -9.04 -3.03 -1.113 0.51661E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.64 -3.23 -1.078 0.55217E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.14 -4.16 -1.387 0.71036E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003200 MOLES New total amount of reactant added: 0.0003300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3675E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140620E-01 Osmotic coef. = 0.9874 True ionic strength = .2011352E-01 Chg. balance for total moles = -.3675E-10 Max. difference allowed = 0.1398E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88702E-10 -10.0521 0.74510E-10 -10.1278 0.84000E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28041E-03 -3.5522 0.23412E-03 -3.6306 0.83493E+00 -0.0783 4 SO4-- 0.17093E-11 -11.7672 0.88655E-12 -12.0523 0.51866E+00 -0.2851 5 HCO3- 0.13593E-05 -5.8667 0.11366E-05 -5.9444 0.83616E+00 -0.0777 6 HS- 0.67528E-04 -4.1705 0.56390E-04 -4.2488 0.83505E+00 -0.0783 7 Al+++ 0.98440E-29 -29.0068 0.22678E-29 -29.6444 0.23038E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13633E-06 -6.8654 0.70187E-07 -7.1537 0.51484E+00 -0.2883 10 Mg++ 0.21328E-10 -10.6711 0.10930E-10 -10.9614 0.51248E+00 -0.2903 11 Fe++ 0.58783E-13 -13.2307 0.30158E-13 -13.5206 0.51304E+00 -0.2898 12 K+ 0.15724E-03 -3.8034 0.13151E-03 -3.8810 0.83636E+00 -0.0776 13 Na+ 0.19953E-01 -1.7000 0.16656E-01 -1.7784 0.83478E+00 -0.0784 14 Mn++ 0.18858E-10 -10.7245 0.96830E-11 -11.0140 0.51347E+00 -0.2895 15 F- 0.46591E-06 -6.3317 0.38820E-06 -6.4109 0.83321E+00 -0.0792 16 HPO4-- 0.44986E-07 -7.3469 0.23336E-07 -7.6320 0.51874E+00 -0.2851 18 HSiO3- 0.10446E-01 -1.9810 0.87219E-02 -2.0594 0.83493E+00 -0.0783 19 Ca(HSiO3)+ 0.16665E-07 -7.7782 0.13941E-07 -7.8557 0.83654E+00 -0.0775 20 Mg(HSiO3)+ 0.32298E-11 -11.4908 0.27019E-11 -11.5683 0.83654E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66432E-16 -16.1776 0.55573E-16 -16.2551 0.83654E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52947E-05 -5.2762 0.44127E-05 -5.3553 0.83342E+00 -0.0791 26 CH4,aq 0.70468E-04 -4.1520 0.70222E-04 -4.1535 0.99652E+00 -0.0015 27 C2H6,aq 0.73037E-13 -13.1365 0.72783E-13 -13.1380 0.99652E+00 -0.0015 31 CO,aq 0.52650E-16 -16.2786 0.52650E-16 -16.2786 0.10000E+01 0.0000 32 CO2,aq 0.18158E-09 -9.7409 0.18095E-09 -9.7424 0.99652E+00 -0.0015 33 CO3-2 0.25743E-05 -5.5893 0.13324E-05 -5.8754 0.51756E+00 -0.2860 34 CaCO3,aq 0.11726E-08 -8.9309 0.11726E-08 -8.9309 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.24341E-11 -11.6137 0.20362E-11 -11.6912 0.83654E+00 -0.0775 36 CaCl+ 0.31789E-10 -10.4977 0.26593E-10 -10.5752 0.83654E+00 -0.0775 37 CaCl2,aq 0.14792E-14 -14.8300 0.14792E-14 -14.8300 0.10000E+01 0.0000 38 CaF+ 0.47553E-12 -12.3228 0.39780E-12 -12.4003 0.83654E+00 -0.0775 39 CaOH+ 0.80253E-07 -7.0955 0.67134E-07 -7.1731 0.83654E+00 -0.0775 40 CaSO4,aq 0.19759E-16 -16.7042 0.19759E-16 -16.7042 0.10000E+01 0.0000 41 HCl,aq 0.31966E-14 -14.4953 0.31966E-14 -14.4953 0.10000E+01 0.0000 45 HF,aq 0.19801E-12 -12.7033 0.19801E-12 -12.7033 0.10000E+01 0.0000 46 HF2- 0.31083E-19 -19.5075 0.25952E-19 -19.5858 0.83493E+00 -0.0783 48 FeCl+ 0.13360E-16 -16.8742 0.11176E-16 -16.9517 0.83654E+00 -0.0775 51 FeF+ 0.71516E-18 -18.1456 0.59826E-18 -18.2231 0.83654E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15750E-10 -10.8027 0.13175E-10 -10.8802 0.83654E+00 -0.0775 55 HFeO2- 0.35509E-07 -7.4497 0.29647E-07 -7.5280 0.83493E+00 -0.0783 56 FeO+ 0.11038E-16 -16.9571 0.92337E-17 -17.0346 0.83654E+00 -0.0775 58 FeO2- 0.40761E-09 -9.3898 0.34033E-09 -9.4681 0.83493E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55803E-09 -9.2533 0.55803E-09 -9.2533 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.21669E-14 -14.6642 0.18092E-14 -14.7425 0.83493E+00 -0.0783 65 MgCO3,aq 0.45770E-13 -13.3394 0.45770E-13 -13.3394 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.38733E-15 -15.4119 0.32401E-15 -15.4894 0.83654E+00 -0.0775 67 MgCl+ 0.44868E-14 -14.3481 0.37534E-14 -14.4256 0.83654E+00 -0.0775 68 MgF+ 0.27431E-15 -15.5618 0.22947E-15 -15.6393 0.83654E+00 -0.0775 69 MgOH+ 0.69155E-10 -10.1602 0.57851E-10 -10.2377 0.83654E+00 -0.0775 71 MnF+ 0.75685E-16 -16.1210 0.63314E-16 -16.1985 0.83654E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46976E-09 -9.3281 0.39297E-09 -9.4056 0.83654E+00 -0.0775 74 MnO2-2 0.20862E-10 -10.6806 0.10797E-10 -10.9667 0.51756E+00 -0.2860 75 HMnO2- 0.21110E-09 -9.6755 0.17626E-09 -9.7539 0.83493E+00 -0.0783 78 MnCl+ 0.16688E-13 -13.7776 0.13960E-13 -13.8551 0.83654E+00 -0.0775 80 NaCl,aq 0.12924E-05 -5.8886 0.12924E-05 -5.8886 0.10000E+01 0.0000 81 NaF,aq 0.15138E-08 -8.8199 0.15138E-08 -8.8199 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93042E-02 -2.0313 0.77543E-02 -2.1105 0.83342E+00 -0.0791 89 HPO3-2 0.16275E-14 -14.7885 0.84232E-15 -15.0745 0.51756E+00 -0.2860 91 H2PO3- 0.15074E-18 -18.8218 0.12586E-18 -18.9001 0.83493E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38381E-10 -10.4159 0.32076E-10 -10.4938 0.83573E+00 -0.0779 94 PO4-3 0.10559E-08 -8.9764 0.25553E-09 -9.5926 0.24201E+00 -0.6162 98 HP2O7-3 0.93748E-18 -18.0280 0.21619E-18 -18.6652 0.23061E+00 -0.6371 99 P2O7-4 0.90339E-17 -17.0441 0.69316E-18 -18.1592 0.76728E-01 -1.1150 100 H2S,aq 0.13031E-07 -7.8850 0.12986E-07 -7.8865 0.99652E+00 -0.0015 101 S2-2 0.11754E-13 -13.9298 0.60831E-14 -14.2159 0.51756E+00 -0.2860 107 SO3-2 0.25413E-17 -17.5949 0.13344E-17 -17.8747 0.52507E+00 -0.2798 109 HSO4- 0.76025E-19 -19.1190 0.63660E-19 -19.1961 0.83735E+00 -0.0771 Charge balance for all species = -.7403E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8870200E-10 -.2222371E-01 -.2236112E+02 0.0000 2 H2O 0.1000000E+01 0.5550495E+02 0.9981953E+06 0.0000 3 Cl- 0.2804108E-03 0.2817038E-03 0.9969836E+01 6.4972 4 SO4-- 0.1709289E-11 -.7337323E-04 -.7036064E+01 8.2033 5 HCO3- 0.1359255E-05 0.7440246E-04 0.4531916E+01 4.1834 6 HS- 0.6752816E-04 0.1409144E-03 0.4652198E+01 5.8790 7 Al+++ 0.9844032E-29 0.5294860E-05 0.1426142E+00 0.7390 8 H4SiO4 0.6959786E-03 0.1349183E-01 0.1294512E+04 -3.1574 9 Ca++ 0.1363270E-06 0.2344524E-06 0.9380006E-02 13.1018 10 Mg++ 0.2132774E-10 0.9376279E-10 0.2275587E-05 9.2942 11 Fe++ 0.5878287E-13 0.3614662E-07 0.2015162E-02 6.7350 12 K+ 0.1572404E-03 0.1579947E-03 0.6167139E+01 6.2467 13 Na+ 0.1995315E-01 0.2240012E-01 0.5140767E+03 8.3494 14 Mn++ 0.1885807E-10 0.2526842E-08 0.1385777E-03 9.2416 15 F- 0.4659060E-06 0.4674205E-06 0.8864575E-02 3.7168 16 HPO4-- 0.4498635E-07 0.4608063E-07 0.4415063E-02 12.6236 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279251E+02 -.1103054E-01 -.8278148E+02 0.0000000E+00 2 H2O -.7168519E+01 0.2754939E+02 -.3471791E+02 0.0000000E+00 3 Cl- 0.1398212E-03 0.1398212E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385941E+00 -.3641815E-04 0.1386305E+00 0.0000000E+00 5 HCO3- 0.3692900E-04 0.3692900E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385606E+00 0.6994162E-04 -.1386305E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628057E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696549E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1163684E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4653833E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794106E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7841925E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111810E-01 0.6265259E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254176E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2320000E-06 0.2320000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287171E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1715E-13 Mass of aqueous solution: 0.497208E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2621 -0.582 56.75 1.754 1.039 17.34 hedenbergite 0.6796E-01 -1.168 16.86 1.227 0.3087 4.618 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4269E-01 -1.370 36.49 1.562 0.6680 11.74 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337971 g Volume = 2210.778772 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003300 moles log = -3.4815 Original solution: 1000.0103000 g Original solution / Rock added: 3030334.24 (Water/Rock Ratio), log = 6.4815 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1393 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8970E+00 0.9844 0.1006E+01 0.1022E+01 CO2,gas 0.1690E-07 1.0058 0.1936E-07 0.1925E-07 CH4,gas 0.8970E-01 1.0114 0.1034E+00 0.1022E+00 H2,gas 0.1334E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3147E-06 0.9956 0.3570E-06 0.3585E-06 S2,gas 0.1816E-28 1.0000 0.2068E-28 0.2068E-28 CO,gas 0.6887E-13 1.0000 0.7846E-13 0.7846E-13 SO3,gas 0.1634E-47 1.0000 0.1861E-47 0.1861E-47 SO2,gas 0.9664E-27 1.0000 0.1101E-26 0.1101E-26 HF,gas 0.4268E-15 1.0000 0.4862E-15 0.4862E-15 HCl,gas 0.4951E-17 1.0000 0.5641E-17 0.5641E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.07 -9.41 -3.137 0.16071E+05 -7.713 3 CH4,gas 4.54 1.86 -2.68 -0.671 0.45839E+04 -0.986 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.38 -8.15 -4.073 0.13910E+05 -6.447 6 S2,gas -7.34 -37.72 -30.38 -4.674 0.51879E+05 -28.684 7 CO,gas 3.21 -11.59 -14.80 -4.555 0.25278E+05 -13.105 8 SO3,gas 17.12 -32.31 -49.43 -12.357 0.84399E+05 -47.730 9 SO2,gas 0.83 -27.83 -28.66 -7.642 0.48931E+05 -26.958 10 HF,gas 0.47 -16.54 -17.01 -8.506 0.29048E+05 -15.313 11 HCl,gas 5.19 -13.76 -18.95 -9.474 0.32353E+05 -17.249 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.69 -0.39 -0.033 0.66803E+03 38 aragonite 0.97 -2.97 -3.94 -1.312 0.67221E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.97 -3.78 -1.261 0.64579E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.11 -4.00 -1.144 0.68370E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.11 -3.56 -1.017 0.60792E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.64 -3.38 -1.127 0.57735E+04 147 pyrrhotiteFe0.875 -6.02 -9.04 -3.02 -1.112 0.51607E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.64 -3.23 -1.077 0.55163E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.14 -4.16 -1.386 0.70982E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003300 MOLES New total amount of reactant added: 0.0003400 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3675E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003400 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140537E-01 Osmotic coef. = 0.9881 True ionic strength = .2011397E-01 Chg. balance for total moles = -.3675E-10 Max. difference allowed = 0.1399E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88704E-10 -10.0521 0.74511E-10 -10.1278 0.84000E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28053E-03 -3.5520 0.23422E-03 -3.6304 0.83493E+00 -0.0783 4 SO4-- 0.17217E-11 -11.7641 0.89295E-12 -12.0492 0.51866E+00 -0.2851 5 HCO3- 0.13858E-05 -5.8583 0.11588E-05 -5.9360 0.83616E+00 -0.0777 6 HS- 0.68018E-04 -4.1674 0.56798E-04 -4.2457 0.83505E+00 -0.0783 7 Al+++ 0.98447E-29 -29.0068 0.22680E-29 -29.6444 0.23037E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13633E-06 -6.8654 0.70190E-07 -7.1537 0.51484E+00 -0.2883 10 Mg++ 0.21329E-10 -10.6710 0.10930E-10 -10.9614 0.51248E+00 -0.2903 11 Fe++ 0.58785E-13 -13.2307 0.30159E-13 -13.5206 0.51304E+00 -0.2899 12 K+ 0.15724E-03 -3.8034 0.13151E-03 -3.8810 0.83636E+00 -0.0776 13 Na+ 0.19954E-01 -1.7000 0.16657E-01 -1.7784 0.83478E+00 -0.0784 14 Mn++ 0.18859E-10 -10.7245 0.96834E-11 -11.0140 0.51347E+00 -0.2895 15 F- 0.47394E-06 -6.3243 0.39489E-06 -6.4035 0.83320E+00 -0.0792 16 HPO4-- 0.44985E-07 -7.3469 0.23335E-07 -7.6320 0.51873E+00 -0.2851 18 HSiO3- 0.10446E-01 -1.9810 0.87217E-02 -2.0594 0.83493E+00 -0.0783 19 Ca(HSiO3)+ 0.16666E-07 -7.7782 0.13941E-07 -7.8557 0.83654E+00 -0.0775 20 Mg(HSiO3)+ 0.32299E-11 -11.4908 0.27019E-11 -11.5683 0.83654E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66433E-16 -16.1776 0.55574E-16 -16.2551 0.83654E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52946E-05 -5.2762 0.44126E-05 -5.3553 0.83342E+00 -0.0791 26 CH4,aq 0.71847E-04 -4.1436 0.71597E-04 -4.1451 0.99652E+00 -0.0015 27 C2H6,aq 0.75925E-13 -13.1196 0.75661E-13 -13.1211 0.99652E+00 -0.0015 31 CO,aq 0.53681E-16 -16.2702 0.53681E-16 -16.2702 0.10000E+01 0.0000 32 CO2,aq 0.18514E-09 -9.7325 0.18449E-09 -9.7340 0.99652E+00 -0.0015 33 CO3-2 0.26246E-05 -5.5809 0.13584E-05 -5.8670 0.51756E+00 -0.2860 34 CaCO3,aq 0.11955E-08 -8.9224 0.11955E-08 -8.9224 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.24818E-11 -11.6052 0.20761E-11 -11.6827 0.83654E+00 -0.0775 36 CaCl+ 0.31804E-10 -10.4975 0.26605E-10 -10.5750 0.83654E+00 -0.0775 37 CaCl2,aq 0.14805E-14 -14.8296 0.14805E-14 -14.8296 0.10000E+01 0.0000 38 CaF+ 0.48375E-12 -12.3154 0.40467E-12 -12.3929 0.83654E+00 -0.0775 39 CaOH+ 0.80254E-07 -7.0955 0.67136E-07 -7.1730 0.83654E+00 -0.0775 40 CaSO4,aq 0.19903E-16 -16.7011 0.19903E-16 -16.7011 0.10000E+01 0.0000 41 HCl,aq 0.31980E-14 -14.4951 0.31980E-14 -14.4951 0.10000E+01 0.0000 45 HF,aq 0.20142E-12 -12.6959 0.20142E-12 -12.6959 0.10000E+01 0.0000 46 HF2- 0.32164E-19 -19.4926 0.26855E-19 -19.5710 0.83493E+00 -0.0783 48 FeCl+ 0.13366E-16 -16.8740 0.11181E-16 -16.9515 0.83654E+00 -0.0775 51 FeF+ 0.72752E-18 -18.1382 0.60859E-18 -18.2157 0.83654E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15750E-10 -10.8027 0.13175E-10 -10.8802 0.83654E+00 -0.0775 55 HFeO2- 0.35508E-07 -7.4497 0.29647E-07 -7.5280 0.83493E+00 -0.0783 56 FeO+ 0.11038E-16 -16.9571 0.92339E-17 -17.0346 0.83654E+00 -0.0775 58 FeO2- 0.40761E-09 -9.3898 0.34032E-09 -9.4681 0.83493E+00 -0.0783 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55828E-09 -9.2531 0.55828E-09 -9.2531 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.21826E-14 -14.6610 0.18223E-14 -14.7394 0.83493E+00 -0.0783 65 MgCO3,aq 0.46666E-13 -13.3310 0.46666E-13 -13.3310 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.39492E-15 -15.4035 0.33036E-15 -15.4810 0.83654E+00 -0.0775 67 MgCl+ 0.44889E-14 -14.3479 0.37551E-14 -14.4254 0.83654E+00 -0.0775 68 MgF+ 0.27905E-15 -15.5543 0.23344E-15 -15.6318 0.83654E+00 -0.0775 69 MgOH+ 0.69157E-10 -10.1602 0.57852E-10 -10.2377 0.83654E+00 -0.0775 71 MnF+ 0.76993E-16 -16.1135 0.64407E-16 -16.1911 0.83654E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46977E-09 -9.3281 0.39298E-09 -9.4056 0.83654E+00 -0.0775 74 MnO2-2 0.20862E-10 -10.6807 0.10797E-10 -10.9667 0.51756E+00 -0.2860 75 HMnO2- 0.21110E-09 -9.6755 0.17625E-09 -9.7539 0.83493E+00 -0.0783 78 MnCl+ 0.16696E-13 -13.7774 0.13967E-13 -13.8549 0.83654E+00 -0.0775 80 NaCl,aq 0.12929E-05 -5.8884 0.12929E-05 -5.8884 0.10000E+01 0.0000 81 NaF,aq 0.15399E-08 -8.8125 0.15399E-08 -8.8125 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93041E-02 -2.0313 0.77542E-02 -2.1105 0.83342E+00 -0.0791 89 HPO3-2 0.16274E-14 -14.7885 0.84229E-15 -15.0745 0.51756E+00 -0.2860 91 H2PO3- 0.15073E-18 -18.8218 0.12585E-18 -18.9001 0.83493E+00 -0.0783 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38380E-10 -10.4159 0.32075E-10 -10.4938 0.83572E+00 -0.0779 94 PO4-3 0.10558E-08 -8.9764 0.25552E-09 -9.5926 0.24200E+00 -0.6162 98 HP2O7-3 0.93744E-18 -18.0281 0.21618E-18 -18.6652 0.23061E+00 -0.6371 99 P2O7-4 0.90335E-17 -17.0441 0.69310E-18 -18.1592 0.76726E-01 -1.1151 100 H2S,aq 0.13126E-07 -7.8819 0.13080E-07 -7.8834 0.99652E+00 -0.0015 101 S2-2 0.11925E-13 -13.9236 0.61716E-14 -14.2096 0.51756E+00 -0.2860 107 SO3-2 0.25597E-17 -17.5918 0.13440E-17 -17.8716 0.52507E+00 -0.2798 109 HSO4- 0.76576E-19 -19.1159 0.64121E-19 -19.1930 0.83735E+00 -0.0771 Charge balance for all species = -.7405E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8870378E-10 -.2222343E-01 -.2236083E+02 0.0000 2 H2O 0.1000000E+01 0.5550495E+02 0.9981953E+06 0.0000 3 Cl- 0.2805290E-03 0.2818226E-03 0.9974039E+01 6.4974 4 SO4-- 0.1721654E-11 -.7475293E-04 -.7168369E+01 8.2064 5 HCO3- 0.1385844E-05 0.7585909E-04 0.4620641E+01 4.1918 6 HS- 0.6801762E-04 0.1427837E-03 0.4713910E+01 5.8821 7 Al+++ 0.9844717E-29 0.5294770E-05 0.1426118E+00 0.7390 8 H4SiO4 0.6959786E-03 0.1349165E-01 0.1294495E+04 -3.1574 9 Ca++ 0.1363329E-06 0.2344833E-06 0.9381242E-02 13.1018 10 Mg++ 0.2132867E-10 0.9376544E-10 0.2275652E-05 9.2942 11 Fe++ 0.5878542E-13 0.3614601E-07 0.2015127E-02 6.7350 12 K+ 0.1572435E-03 0.1579978E-03 0.6167262E+01 6.2467 13 Na+ 0.1995355E-01 0.2240052E-01 0.5140859E+03 8.3494 14 Mn++ 0.1885891E-10 0.2526851E-08 0.1385781E-03 9.2416 15 F- 0.4739386E-06 0.4754793E-06 0.9017409E-02 3.7243 16 HPO4-- 0.4498494E-07 0.4607917E-07 0.4414923E-02 12.6236 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279251E+02 -.1103040E-01 -.8278148E+02 0.0000000E+00 2 H2O -.7168510E+01 0.2754940E+02 -.3471791E+02 0.0000000E+00 3 Cl- 0.1398802E-03 0.1398802E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385941E+00 -.3710297E-04 0.1386312E+00 0.0000000E+00 5 HCO3- 0.3765200E-04 0.3765200E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385604E+00 0.7086944E-04 -.1386312E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2628013E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696462E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1163838E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4653966E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794076E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7842085E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111831E-01 0.6265259E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254180E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2360000E-06 0.2360000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287100E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1976E-13 Mass of aqueous solution: 0.497208E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003400 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2620 -0.582 56.75 1.754 1.039 17.34 hedenbergite 0.6796E-01 -1.168 16.86 1.227 0.3087 4.618 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4269E-01 -1.370 36.49 1.562 0.6681 11.75 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337974 g Volume = 2210.778800 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003400 moles log = -3.4685 Original solution: 1000.0103000 g Original solution / Rock added: 2941206.76 (Water/Rock Ratio), log = 6.4685 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1413 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8954E+00 0.9844 0.1006E+01 0.1022E+01 CO2,gas 0.1720E-07 1.0058 0.1974E-07 0.1963E-07 CH4,gas 0.9130E-01 1.0114 0.1054E+00 0.1042E+00 H2,gas 0.1332E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3164E-06 0.9956 0.3596E-06 0.3612E-06 S2,gas 0.1839E-28 1.0000 0.2099E-28 0.2099E-28 CO,gas 0.7009E-13 1.0000 0.7999E-13 0.7999E-13 SO3,gas 0.1642E-47 1.0000 0.1874E-47 0.1874E-47 SO2,gas 0.9717E-27 1.0000 0.1109E-26 0.1109E-26 HF,gas 0.4333E-15 1.0000 0.4946E-15 0.4946E-15 HCl,gas 0.4944E-17 1.0000 0.5643E-17 0.5643E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.06 -9.40 -3.135 0.16056E+05 -7.705 3 CH4,gas 4.54 1.87 -2.68 -0.669 0.45695E+04 -0.977 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.37 -8.14 -4.072 0.13904E+05 -6.444 6 S2,gas -7.34 -37.71 -30.38 -4.673 0.51868E+05 -28.678 7 CO,gas 3.21 -11.58 -14.80 -4.553 0.25264E+05 -13.097 8 SO3,gas 17.12 -32.30 -49.43 -12.357 0.84394E+05 -47.727 9 SO2,gas 0.83 -27.82 -28.65 -7.641 0.48926E+05 -26.955 10 HF,gas 0.47 -16.53 -17.00 -8.502 0.29035E+05 -15.306 11 HCl,gas 5.19 -13.76 -18.95 -9.474 0.32352E+05 -17.248 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.68 -0.38 -0.032 0.65534E+03 38 aragonite 0.97 -2.96 -3.93 -1.309 0.67078E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.96 -3.77 -1.258 0.64435E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.10 -4.00 -1.142 0.68226E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.10 -3.55 -1.015 0.60649E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.64 -3.38 -1.126 0.57681E+04 147 pyrrhotiteFe0.875 -6.02 -9.04 -3.02 -1.110 0.51553E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.64 -3.23 -1.076 0.55109E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.13 -4.15 -1.385 0.70928E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003400 MOLES New total amount of reactant added: 0.0003500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3674E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140454E-01 Osmotic coef. = 0.9890 True ionic strength = .2011443E-01 Chg. balance for total moles = -.3674E-10 Max. difference allowed = 0.1399E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88706E-10 -10.0520 0.74513E-10 -10.1278 0.84000E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28065E-03 -3.5518 0.23432E-03 -3.6302 0.83493E+00 -0.0784 4 SO4-- 0.17340E-11 -11.7609 0.89936E-12 -12.0461 0.51866E+00 -0.2851 5 HCO3- 0.14124E-05 -5.8500 0.11810E-05 -5.9277 0.83616E+00 -0.0777 6 HS- 0.68507E-04 -4.1643 0.57207E-04 -4.2426 0.83505E+00 -0.0783 7 Al+++ 0.98454E-29 -29.0068 0.22681E-29 -29.6443 0.23037E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13634E-06 -6.8654 0.70192E-07 -7.1537 0.51484E+00 -0.2883 10 Mg++ 0.21330E-10 -10.6710 0.10931E-10 -10.9613 0.51247E+00 -0.2903 11 Fe++ 0.58788E-13 -13.2307 0.30160E-13 -13.5206 0.51304E+00 -0.2899 12 K+ 0.15725E-03 -3.8034 0.13151E-03 -3.8810 0.83635E+00 -0.0776 13 Na+ 0.19954E-01 -1.7000 0.16657E-01 -1.7784 0.83478E+00 -0.0784 14 Mn++ 0.18860E-10 -10.7245 0.96838E-11 -11.0140 0.51346E+00 -0.2895 15 F- 0.48197E-06 -6.3170 0.40158E-06 -6.3962 0.83320E+00 -0.0792 16 HPO4-- 0.44984E-07 -7.3469 0.23334E-07 -7.6320 0.51873E+00 -0.2851 18 HSiO3- 0.10446E-01 -1.9811 0.87215E-02 -2.0594 0.83493E+00 -0.0784 19 Ca(HSiO3)+ 0.16666E-07 -7.7782 0.13942E-07 -7.8557 0.83653E+00 -0.0775 20 Mg(HSiO3)+ 0.32300E-11 -11.4908 0.27020E-11 -11.5683 0.83653E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66434E-16 -16.1776 0.55575E-16 -16.2551 0.83653E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52945E-05 -5.2762 0.44125E-05 -5.3553 0.83342E+00 -0.0791 26 CH4,aq 0.73227E-04 -4.1353 0.72972E-04 -4.1368 0.99652E+00 -0.0015 27 C2H6,aq 0.78869E-13 -13.1031 0.78595E-13 -13.1046 0.99652E+00 -0.0015 31 CO,aq 0.54712E-16 -16.2619 0.54712E-16 -16.2619 0.10000E+01 0.0000 32 CO2,aq 0.18869E-09 -9.7242 0.18804E-09 -9.7258 0.99652E+00 -0.0015 33 CO3-2 0.26749E-05 -5.5727 0.13844E-05 -5.8587 0.51755E+00 -0.2860 34 CaCO3,aq 0.12185E-08 -8.9142 0.12185E-08 -8.9142 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.25295E-11 -11.5970 0.21161E-11 -11.6745 0.83653E+00 -0.0775 36 CaCl+ 0.31818E-10 -10.4973 0.26617E-10 -10.5748 0.83653E+00 -0.0775 37 CaCl2,aq 0.14818E-14 -14.8292 0.14818E-14 -14.8292 0.10000E+01 0.0000 38 CaF+ 0.49196E-12 -12.3081 0.41154E-12 -12.3856 0.83653E+00 -0.0775 39 CaOH+ 0.80256E-07 -7.0955 0.67137E-07 -7.1730 0.83653E+00 -0.0775 40 CaSO4,aq 0.20046E-16 -16.6980 0.20046E-16 -16.6980 0.10000E+01 0.0000 41 HCl,aq 0.31994E-14 -14.4949 0.31994E-14 -14.4949 0.10000E+01 0.0000 45 HF,aq 0.20484E-12 -12.6886 0.20484E-12 -12.6886 0.10000E+01 0.0000 46 HF2- 0.33264E-19 -19.4780 0.27773E-19 -19.5564 0.83493E+00 -0.0784 48 FeCl+ 0.13372E-16 -16.8738 0.11186E-16 -16.9513 0.83653E+00 -0.0775 51 FeF+ 0.73988E-18 -18.1308 0.61893E-18 -18.2084 0.83653E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15750E-10 -10.8027 0.13176E-10 -10.8802 0.83653E+00 -0.0775 55 HFeO2- 0.35508E-07 -7.4497 0.29646E-07 -7.5280 0.83493E+00 -0.0784 56 FeO+ 0.11038E-16 -16.9571 0.92341E-17 -17.0346 0.83653E+00 -0.0775 58 FeO2- 0.40760E-09 -9.3898 0.34032E-09 -9.4681 0.83493E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55852E-09 -9.2530 0.55852E-09 -9.2530 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.21983E-14 -14.6579 0.18354E-14 -14.7363 0.83493E+00 -0.0784 65 MgCO3,aq 0.47562E-13 -13.3227 0.47562E-13 -13.3227 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.40251E-15 -15.3952 0.33672E-15 -15.4727 0.83653E+00 -0.0775 67 MgCl+ 0.44909E-14 -14.3477 0.37568E-14 -14.4252 0.83653E+00 -0.0775 68 MgF+ 0.28379E-15 -15.5470 0.23740E-15 -15.6245 0.83653E+00 -0.0775 69 MgOH+ 0.69158E-10 -10.1602 0.57853E-10 -10.2377 0.83653E+00 -0.0775 71 MnF+ 0.78301E-16 -16.1062 0.65501E-16 -16.1837 0.83653E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46978E-09 -9.3281 0.39299E-09 -9.4056 0.83653E+00 -0.0775 74 MnO2-2 0.20861E-10 -10.6807 0.10797E-10 -10.9667 0.51755E+00 -0.2860 75 HMnO2- 0.21110E-09 -9.6755 0.17625E-09 -9.7539 0.83493E+00 -0.0784 78 MnCl+ 0.16703E-13 -13.7772 0.13973E-13 -13.8547 0.83653E+00 -0.0775 80 NaCl,aq 0.12935E-05 -5.8882 0.12935E-05 -5.8882 0.10000E+01 0.0000 81 NaF,aq 0.15661E-08 -8.8052 0.15661E-08 -8.8052 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93039E-02 -2.0313 0.77540E-02 -2.1105 0.83342E+00 -0.0791 89 HPO3-2 0.16274E-14 -14.7885 0.84226E-15 -15.0746 0.51755E+00 -0.2860 91 H2PO3- 0.15073E-18 -18.8218 0.12585E-18 -18.9001 0.83493E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38379E-10 -10.4159 0.32074E-10 -10.4938 0.83572E+00 -0.0779 94 PO4-3 0.10558E-08 -8.9764 0.25550E-09 -9.5926 0.24200E+00 -0.6162 98 HP2O7-3 0.93740E-18 -18.0281 0.21617E-18 -18.6652 0.23060E+00 -0.6371 99 P2O7-4 0.90330E-17 -17.0442 0.69305E-18 -18.1592 0.76725E-01 -1.1151 100 H2S,aq 0.13220E-07 -7.8788 0.13174E-07 -7.8803 0.99652E+00 -0.0015 101 S2-2 0.12097E-13 -13.9173 0.62607E-14 -14.2034 0.51755E+00 -0.2860 107 SO3-2 0.25781E-17 -17.5887 0.13537E-17 -17.8685 0.52507E+00 -0.2798 109 HSO4- 0.77127E-19 -19.1128 0.64582E-19 -19.1899 0.83735E+00 -0.0771 Charge balance for all species = -.7398E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8870556E-10 -.2222314E-01 -.2236054E+02 0.0000 2 H2O 0.1000000E+01 0.5550495E+02 0.9981953E+06 0.0000 3 Cl- 0.2806472E-03 0.2819413E-03 0.9978242E+01 6.4976 4 SO4-- 0.1734019E-11 -.7613262E-04 -.7300673E+01 8.2095 5 HCO3- 0.1412433E-05 0.7731572E-04 0.4709365E+01 4.2000 6 HS- 0.6850708E-04 0.1446529E-03 0.4775622E+01 5.8852 7 Al+++ 0.9845403E-29 0.5294679E-05 0.1426094E+00 0.7390 8 H4SiO4 0.6959786E-03 0.1349147E-01 0.1294478E+04 -3.1574 9 Ca++ 0.1363388E-06 0.2345142E-06 0.9382478E-02 13.1018 10 Mg++ 0.2132959E-10 0.9376898E-10 0.2275738E-05 9.2942 11 Fe++ 0.5878798E-13 0.3614539E-07 0.2015093E-02 6.7350 12 K+ 0.1572467E-03 0.1580010E-03 0.6167385E+01 6.2467 13 Na+ 0.1995395E-01 0.2240093E-01 0.5140951E+03 8.3494 14 Mn++ 0.1885974E-10 0.2526859E-08 0.1385786E-03 9.2416 15 F- 0.4819713E-06 0.4835380E-06 0.9170243E-02 3.7315 16 HPO4-- 0.4498353E-07 0.4607771E-07 0.4414784E-02 12.6235 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279251E+02 -.1103027E-01 -.8278148E+02 0.0000000E+00 2 H2O -.7168502E+01 0.2754941E+02 -.3471791E+02 0.0000000E+00 3 Cl- 0.1399392E-03 0.1399392E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385942E+00 -.3778778E-04 0.1386320E+00 0.0000000E+00 5 HCO3- 0.3837500E-04 0.3837500E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385602E+00 0.7179725E-04 -.1386320E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627969E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696376E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1163991E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4654144E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794046E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7842245E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111851E-01 0.6265258E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254185E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2400000E-06 0.2400000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2287028E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.2059E-13 Mass of aqueous solution: 0.497208E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2620 -0.582 56.74 1.754 1.039 17.34 hedenbergite 0.6795E-01 -1.168 16.86 1.227 0.3086 4.618 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4270E-01 -1.370 36.50 1.562 0.6682 11.75 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337978 g Volume = 2210.778827 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003500 moles log = -3.4559 Original solution: 1000.0103000 g Original solution / Rock added: 2857172.29 (Water/Rock Ratio), log = 6.4559 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1433 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8938E+00 0.9844 0.1006E+01 0.1022E+01 CO2,gas 0.1750E-07 1.0058 0.2012E-07 0.2000E-07 CH4,gas 0.9289E-01 1.0114 0.1074E+00 0.1062E+00 H2,gas 0.1329E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3182E-06 0.9956 0.3622E-06 0.3638E-06 S2,gas 0.1862E-28 1.0000 0.2129E-28 0.2129E-28 CO,gas 0.7131E-13 1.0000 0.8153E-13 0.8153E-13 SO3,gas 0.1651E-47 1.0000 0.1888E-47 0.1888E-47 SO2,gas 0.9770E-27 1.0000 0.1117E-26 0.1117E-26 HF,gas 0.4399E-15 1.0000 0.5030E-15 0.5030E-15 HCl,gas 0.4938E-17 1.0000 0.5645E-17 0.5645E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.18198E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.06 -9.40 -3.132 0.16042E+05 -7.696 3 CH4,gas 4.54 1.88 -2.67 -0.667 0.45554E+04 -0.969 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.37 -8.14 -4.070 0.13899E+05 -6.441 6 S2,gas -7.34 -37.71 -30.37 -4.672 0.51857E+05 -28.672 7 CO,gas 3.21 -11.57 -14.79 -4.550 0.25250E+05 -13.089 8 SO3,gas 17.12 -32.30 -49.42 -12.356 0.84388E+05 -47.724 9 SO2,gas 0.83 -27.82 -28.65 -7.640 0.48921E+05 -26.952 10 HF,gas 0.47 -16.52 -17.00 -8.499 0.29023E+05 -15.298 11 HCl,gas 5.19 -13.76 -18.95 -9.474 0.32352E+05 -17.248 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.68 -0.38 -0.031 0.64286E+03 38 aragonite 0.97 -2.95 -3.92 -1.307 0.66936E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.95 -3.77 -1.255 0.64294E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.09 -3.99 -1.139 0.68085E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.09 -3.54 -1.012 0.60508E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.64 -3.38 -1.125 0.57628E+04 147 pyrrhotiteFe0.875 -6.02 -9.03 -3.02 -1.109 0.51500E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.64 -3.22 -1.075 0.55056E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.13 -4.15 -1.384 0.70875E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003500 MOLES New total amount of reactant added: 0.0003600 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3677E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003600 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140371E-01 Osmotic coef. = 0.9898 True ionic strength = .2011488E-01 Chg. balance for total moles = -.3677E-10 Max. difference allowed = 0.1400E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88707E-10 -10.0520 0.74514E-10 -10.1278 0.84000E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28077E-03 -3.5517 0.23442E-03 -3.6300 0.83493E+00 -0.0784 4 SO4-- 0.17464E-11 -11.7579 0.90577E-12 -12.0430 0.51865E+00 -0.2851 5 HCO3- 0.14390E-05 -5.8419 0.12032E-05 -5.9196 0.83615E+00 -0.0777 6 HS- 0.68997E-04 -4.1612 0.57616E-04 -4.2395 0.83505E+00 -0.0783 7 Al+++ 0.98461E-29 -29.0067 0.22682E-29 -29.6443 0.23037E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13634E-06 -6.8654 0.70195E-07 -7.1537 0.51483E+00 -0.2883 10 Mg++ 0.21331E-10 -10.6710 0.10931E-10 -10.9613 0.51247E+00 -0.2903 11 Fe++ 0.58791E-13 -13.2307 0.30161E-13 -13.5205 0.51303E+00 -0.2899 12 K+ 0.15725E-03 -3.8034 0.13152E-03 -3.8810 0.83635E+00 -0.0776 13 Na+ 0.19954E-01 -1.7000 0.16657E-01 -1.7784 0.83478E+00 -0.0784 14 Mn++ 0.18861E-10 -10.7244 0.96841E-11 -11.0139 0.51346E+00 -0.2895 15 F- 0.49000E-06 -6.3098 0.40827E-06 -6.3891 0.83320E+00 -0.0792 16 HPO4-- 0.44982E-07 -7.3470 0.23334E-07 -7.6320 0.51873E+00 -0.2851 18 HSiO3- 0.10446E-01 -1.9811 0.87214E-02 -2.0594 0.83493E+00 -0.0784 19 Ca(HSiO3)+ 0.16666E-07 -7.7782 0.13942E-07 -7.8557 0.83653E+00 -0.0775 20 Mg(HSiO3)+ 0.32300E-11 -11.4908 0.27020E-11 -11.5683 0.83653E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66436E-16 -16.1776 0.55576E-16 -16.2551 0.83653E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52944E-05 -5.2762 0.44125E-05 -5.3553 0.83342E+00 -0.0791 26 CH4,aq 0.74607E-04 -4.1272 0.74347E-04 -4.1287 0.99652E+00 -0.0015 27 C2H6,aq 0.81869E-13 -13.0869 0.81585E-13 -13.0884 0.99652E+00 -0.0015 31 CO,aq 0.55743E-16 -16.2538 0.55743E-16 -16.2538 0.10000E+01 0.0000 32 CO2,aq 0.19225E-09 -9.7161 0.19158E-09 -9.7177 0.99652E+00 -0.0015 33 CO3-2 0.27253E-05 -5.5646 0.14105E-05 -5.8506 0.51755E+00 -0.2860 34 CaCO3,aq 0.12414E-08 -8.9061 0.12414E-08 -8.9061 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.25773E-11 -11.5888 0.21560E-11 -11.6664 0.83653E+00 -0.0775 36 CaCl+ 0.31833E-10 -10.4971 0.26629E-10 -10.5746 0.83653E+00 -0.0775 37 CaCl2,aq 0.14831E-14 -14.8288 0.14831E-14 -14.8288 0.10000E+01 0.0000 38 CaF+ 0.50018E-12 -12.3009 0.41842E-12 -12.3784 0.83653E+00 -0.0775 39 CaOH+ 0.80258E-07 -7.0955 0.67138E-07 -7.1730 0.83653E+00 -0.0775 40 CaSO4,aq 0.20190E-16 -16.6949 0.20190E-16 -16.6949 0.10000E+01 0.0000 41 HCl,aq 0.32008E-14 -14.4947 0.32008E-14 -14.4947 0.10000E+01 0.0000 45 HF,aq 0.20826E-12 -12.6814 0.20826E-12 -12.6814 0.10000E+01 0.0000 46 HF2- 0.34383E-19 -19.4637 0.28707E-19 -19.5420 0.83493E+00 -0.0784 48 FeCl+ 0.13378E-16 -16.8736 0.11191E-16 -16.9511 0.83653E+00 -0.0775 51 FeF+ 0.75223E-18 -18.1236 0.62927E-18 -18.2012 0.83653E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15751E-10 -10.8027 0.13176E-10 -10.8802 0.83653E+00 -0.0775 55 HFeO2- 0.35507E-07 -7.4497 0.29646E-07 -7.5280 0.83493E+00 -0.0784 56 FeO+ 0.11039E-16 -16.9571 0.92343E-17 -17.0346 0.83653E+00 -0.0775 58 FeO2- 0.40759E-09 -9.3898 0.34031E-09 -9.4681 0.83493E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55877E-09 -9.2528 0.55877E-09 -9.2528 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.22140E-14 -14.6548 0.18485E-14 -14.7332 0.83493E+00 -0.0784 65 MgCO3,aq 0.48458E-13 -13.3146 0.48458E-13 -13.3146 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.41010E-15 -15.3871 0.34307E-15 -15.4646 0.83653E+00 -0.0775 67 MgCl+ 0.44930E-14 -14.3475 0.37585E-14 -14.4250 0.83653E+00 -0.0775 68 MgF+ 0.28853E-15 -15.5398 0.24137E-15 -15.6173 0.83653E+00 -0.0775 69 MgOH+ 0.69159E-10 -10.1601 0.57854E-10 -10.2377 0.83653E+00 -0.0775 71 MnF+ 0.79609E-16 -16.0990 0.66596E-16 -16.1766 0.83653E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46979E-09 -9.3281 0.39300E-09 -9.4056 0.83653E+00 -0.0775 74 MnO2-2 0.20860E-10 -10.6807 0.10796E-10 -10.9667 0.51755E+00 -0.2860 75 HMnO2- 0.21109E-09 -9.6755 0.17625E-09 -9.7539 0.83493E+00 -0.0784 78 MnCl+ 0.16711E-13 -13.7770 0.13979E-13 -13.8545 0.83653E+00 -0.0775 80 NaCl,aq 0.12941E-05 -5.8880 0.12941E-05 -5.8880 0.10000E+01 0.0000 81 NaF,aq 0.15922E-08 -8.7980 0.15922E-08 -8.7980 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93037E-02 -2.0313 0.77539E-02 -2.1105 0.83342E+00 -0.0791 89 HPO3-2 0.16273E-14 -14.7885 0.84223E-15 -15.0746 0.51755E+00 -0.2860 91 H2PO3- 0.15073E-18 -18.8218 0.12585E-18 -18.9002 0.83493E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38379E-10 -10.4159 0.32074E-10 -10.4938 0.83572E+00 -0.0779 94 PO4-3 0.10558E-08 -8.9764 0.25549E-09 -9.5926 0.24200E+00 -0.6162 98 HP2O7-3 0.93736E-18 -18.0281 0.21615E-18 -18.6652 0.23060E+00 -0.6371 99 P2O7-4 0.90325E-17 -17.0442 0.69300E-18 -18.1593 0.76723E-01 -1.1151 100 H2S,aq 0.13315E-07 -7.8757 0.13269E-07 -7.8772 0.99652E+00 -0.0015 101 S2-2 0.12270E-13 -13.9111 0.63505E-14 -14.1972 0.51755E+00 -0.2860 107 SO3-2 0.25965E-17 -17.5856 0.13633E-17 -17.8654 0.52506E+00 -0.2798 109 HSO4- 0.77678E-19 -19.1097 0.65044E-19 -19.1868 0.83735E+00 -0.0771 Charge balance for all species = -.7408E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8870735E-10 -.2222285E-01 -.2236025E+02 0.0000 2 H2O 0.1000000E+01 0.5550495E+02 0.9981953E+06 0.0000 3 Cl- 0.2807654E-03 0.2820601E-03 0.9982445E+01 6.4978 4 SO4-- 0.1746383E-11 -.7751232E-04 -.7432978E+01 8.2125 5 HCO3- 0.1439021E-05 0.7877235E-04 0.4798090E+01 4.2081 6 HS- 0.6899654E-04 0.1465222E-03 0.4837334E+01 5.8883 7 Al+++ 0.9846088E-29 0.5294589E-05 0.1426069E+00 0.7390 8 H4SiO4 0.6959786E-03 0.1349129E-01 0.1294460E+04 -3.1574 9 Ca++ 0.1363448E-06 0.2345451E-06 0.9383714E-02 13.1018 10 Mg++ 0.2133052E-10 0.9377253E-10 0.2275824E-05 9.2942 11 Fe++ 0.5879053E-13 0.3614478E-07 0.2015059E-02 6.7350 12 K+ 0.1572498E-03 0.1580041E-03 0.6167508E+01 6.2467 13 Na+ 0.1995435E-01 0.2240133E-01 0.5141043E+03 8.3494 14 Mn++ 0.1886058E-10 0.2526868E-08 0.1385791E-03 9.2416 15 F- 0.4900039E-06 0.4915968E-06 0.9323076E-02 3.7387 16 HPO4-- 0.4498212E-07 0.4607625E-07 0.4414644E-02 12.6235 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279251E+02 -.1103013E-01 -.8278148E+02 0.0000000E+00 2 H2O -.7168494E+01 0.2754942E+02 -.3471792E+02 0.0000000E+00 3 Cl- 0.1399982E-03 0.1399982E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385942E+00 -.3847260E-04 0.1386327E+00 0.0000000E+00 5 HCO3- 0.3909800E-04 0.3909800E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385600E+00 0.7272507E-04 -.1386327E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627925E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696290E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1164145E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4654321E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1794016E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7842405E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111871E-01 0.6265258E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254190E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2440000E-06 0.2440000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2286957E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.8465E-15 Mass of aqueous solution: 0.497208E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003600 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2620 -0.582 56.74 1.754 1.039 17.34 hedenbergite 0.6795E-01 -1.168 16.86 1.227 0.3086 4.617 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4271E-01 -1.370 36.50 1.562 0.6683 11.75 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337981 g Volume = 2210.778855 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003600 moles log = -3.4437 Original solution: 1000.0103000 g Original solution / Rock added: 2777806.39 (Water/Rock Ratio), log = 6.4437 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1453 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8923E+00 0.9844 0.1006E+01 0.1022E+01 CO2,gas 0.1779E-07 1.0057 0.2050E-07 0.2038E-07 CH4,gas 0.9447E-01 1.0114 0.1094E+00 0.1082E+00 H2,gas 0.1327E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3199E-06 0.9956 0.3647E-06 0.3664E-06 S2,gas 0.1886E-28 1.0000 0.2160E-28 0.2160E-28 CO,gas 0.7253E-13 1.0000 0.8307E-13 0.8307E-13 SO3,gas 0.1660E-47 1.0000 0.1902E-47 0.1902E-47 SO2,gas 0.9822E-27 1.0000 0.1125E-26 0.1125E-26 HF,gas 0.4465E-15 1.0000 0.5114E-15 0.5114E-15 HCl,gas 0.4931E-17 1.0000 0.5648E-17 0.5648E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.05 -9.39 -3.129 0.16029E+05 -7.688 3 CH4,gas 4.54 1.88 -2.66 -0.665 0.45416E+04 -0.961 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.37 -8.14 -4.068 0.13894E+05 -6.438 6 S2,gas -7.34 -37.70 -30.36 -4.671 0.51847E+05 -28.666 7 CO,gas 3.21 -11.56 -14.78 -4.548 0.25236E+05 -13.081 8 SO3,gas 17.12 -32.30 -49.42 -12.355 0.84383E+05 -47.721 9 SO2,gas 0.83 -27.82 -28.65 -7.639 0.48915E+05 -26.949 10 HF,gas 0.47 -16.52 -16.99 -8.495 0.29010E+05 -15.291 11 HCl,gas 5.19 -13.76 -18.95 -9.474 0.32352E+05 -17.248 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.67 -0.37 -0.031 0.63059E+03 38 aragonite 0.97 -2.95 -3.91 -1.304 0.66798E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.95 -3.76 -1.252 0.64156E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.08 -3.98 -1.137 0.67947E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.08 -3.54 -1.010 0.60369E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.63 -3.37 -1.124 0.57575E+04 147 pyrrhotiteFe0.875 -6.02 -9.03 -3.01 -1.108 0.51447E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.63 -3.22 -1.074 0.55003E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.13 -4.15 -1.383 0.70822E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003600 MOLES New total amount of reactant added: 0.0003700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3677E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140288E-01 Osmotic coef. = 0.9906 True ionic strength = .2011534E-01 Chg. balance for total moles = -.3677E-10 Max. difference allowed = 0.1401E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88709E-10 -10.0520 0.74515E-10 -10.1278 0.84000E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28088E-03 -3.5515 0.23452E-03 -3.6298 0.83493E+00 -0.0784 4 SO4-- 0.17587E-11 -11.7548 0.91218E-12 -12.0399 0.51865E+00 -0.2851 5 HCO3- 0.14656E-05 -5.8340 0.12255E-05 -5.9117 0.83615E+00 -0.0777 6 HS- 0.69486E-04 -4.1581 0.58024E-04 -4.2364 0.83505E+00 -0.0783 7 Al+++ 0.98468E-29 -29.0067 0.22683E-29 -29.6443 0.23036E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13635E-06 -6.8653 0.70197E-07 -7.1537 0.51483E+00 -0.2883 10 Mg++ 0.21331E-10 -10.6710 0.10932E-10 -10.9613 0.51247E+00 -0.2903 11 Fe++ 0.58793E-13 -13.2307 0.30163E-13 -13.5205 0.51303E+00 -0.2899 12 K+ 0.15725E-03 -3.8034 0.13152E-03 -3.8810 0.83635E+00 -0.0776 13 Na+ 0.19955E-01 -1.7000 0.16658E-01 -1.7784 0.83477E+00 -0.0784 14 Mn++ 0.18861E-10 -10.7244 0.96845E-11 -11.0139 0.51346E+00 -0.2895 15 F- 0.49804E-06 -6.3027 0.41496E-06 -6.3820 0.83320E+00 -0.0793 16 HPO4-- 0.44981E-07 -7.3470 0.23333E-07 -7.6320 0.51873E+00 -0.2851 18 HSiO3- 0.10445E-01 -1.9811 0.87212E-02 -2.0594 0.83493E+00 -0.0784 19 Ca(HSiO3)+ 0.16667E-07 -7.7781 0.13942E-07 -7.8557 0.83653E+00 -0.0775 20 Mg(HSiO3)+ 0.32301E-11 -11.4908 0.27021E-11 -11.5683 0.83653E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66437E-16 -16.1776 0.55577E-16 -16.2551 0.83653E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52943E-05 -5.2762 0.44124E-05 -5.3553 0.83341E+00 -0.0791 26 CH4,aq 0.75986E-04 -4.1193 0.75722E-04 -4.1208 0.99652E+00 -0.0015 27 C2H6,aq 0.84925E-13 -13.0710 0.84630E-13 -13.0725 0.99652E+00 -0.0015 31 CO,aq 0.56773E-16 -16.2459 0.56773E-16 -16.2459 0.10000E+01 0.0000 32 CO2,aq 0.19580E-09 -9.7082 0.19512E-09 -9.7097 0.99652E+00 -0.0015 33 CO3-2 0.27756E-05 -5.5566 0.14365E-05 -5.8427 0.51755E+00 -0.2861 34 CaCO3,aq 0.12644E-08 -8.8981 0.12644E-08 -8.8981 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.26250E-11 -11.5809 0.21959E-11 -11.6584 0.83653E+00 -0.0775 36 CaCl+ 0.31848E-10 -10.4969 0.26641E-10 -10.5744 0.83653E+00 -0.0775 37 CaCl2,aq 0.14844E-14 -14.8285 0.14844E-14 -14.8285 0.10000E+01 0.0000 38 CaF+ 0.50840E-12 -12.2938 0.42529E-12 -12.3713 0.83653E+00 -0.0775 39 CaOH+ 0.80259E-07 -7.0955 0.67139E-07 -7.1730 0.83653E+00 -0.0775 40 CaSO4,aq 0.20333E-16 -16.6918 0.20333E-16 -16.6918 0.10000E+01 0.0000 41 HCl,aq 0.32022E-14 -14.4945 0.32022E-14 -14.4945 0.10000E+01 0.0000 45 HF,aq 0.21168E-12 -12.6743 0.21168E-12 -12.6743 0.10000E+01 0.0000 46 HF2- 0.35520E-19 -19.4495 0.29657E-19 -19.5279 0.83493E+00 -0.0784 48 FeCl+ 0.13384E-16 -16.8734 0.11196E-16 -16.9509 0.83653E+00 -0.0775 51 FeF+ 0.76459E-18 -18.1166 0.63961E-18 -18.1941 0.83653E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15751E-10 -10.8027 0.13176E-10 -10.8802 0.83653E+00 -0.0775 55 HFeO2- 0.35506E-07 -7.4497 0.29645E-07 -7.5280 0.83493E+00 -0.0784 56 FeO+ 0.11039E-16 -16.9571 0.92344E-17 -17.0346 0.83653E+00 -0.0775 58 FeO2- 0.40759E-09 -9.3898 0.34030E-09 -9.4681 0.83493E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55901E-09 -9.2526 0.55901E-09 -9.2526 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.22297E-14 -14.6518 0.18616E-14 -14.7301 0.83493E+00 -0.0784 65 MgCO3,aq 0.49354E-13 -13.3067 0.49354E-13 -13.3067 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.41770E-15 -15.3791 0.34942E-15 -15.4567 0.83653E+00 -0.0775 67 MgCl+ 0.44950E-14 -14.3473 0.37602E-14 -14.4248 0.83653E+00 -0.0775 68 MgF+ 0.29328E-15 -15.5327 0.24533E-15 -15.6102 0.83653E+00 -0.0775 69 MgOH+ 0.69161E-10 -10.1601 0.57855E-10 -10.2377 0.83653E+00 -0.0775 71 MnF+ 0.80917E-16 -16.0920 0.67690E-16 -16.1695 0.83653E+00 -0.0775 72 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46980E-09 -9.3281 0.39300E-09 -9.4056 0.83653E+00 -0.0775 74 MnO2-2 0.20860E-10 -10.6807 0.10796E-10 -10.9667 0.51755E+00 -0.2861 75 HMnO2- 0.21109E-09 -9.6755 0.17624E-09 -9.7539 0.83493E+00 -0.0784 78 MnCl+ 0.16719E-13 -13.7768 0.13986E-13 -13.8543 0.83653E+00 -0.0775 80 NaCl,aq 0.12946E-05 -5.8879 0.12946E-05 -5.8879 0.10000E+01 0.0000 81 NaF,aq 0.16183E-08 -8.7909 0.16183E-08 -8.7909 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93036E-02 -2.0313 0.77537E-02 -2.1105 0.83341E+00 -0.0791 89 HPO3-2 0.16273E-14 -14.7885 0.84220E-15 -15.0746 0.51755E+00 -0.2861 91 H2PO3- 0.15073E-18 -18.8218 0.12585E-18 -18.9002 0.83493E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38378E-10 -10.4159 0.32073E-10 -10.4939 0.83572E+00 -0.0779 94 PO4-3 0.10557E-08 -8.9765 0.25548E-09 -9.5926 0.24200E+00 -0.6162 98 HP2O7-3 0.93732E-18 -18.0281 0.21614E-18 -18.6653 0.23060E+00 -0.6371 99 P2O7-4 0.90321E-17 -17.0442 0.69295E-18 -18.1593 0.76721E-01 -1.1151 100 H2S,aq 0.13410E-07 -7.8726 0.13363E-07 -7.8741 0.99652E+00 -0.0015 101 S2-2 0.12445E-13 -13.9050 0.64409E-14 -14.1911 0.51755E+00 -0.2861 107 SO3-2 0.26149E-17 -17.5826 0.13730E-17 -17.8623 0.52506E+00 -0.2798 109 HSO4- 0.78229E-19 -19.1066 0.65505E-19 -19.1837 0.83735E+00 -0.0771 Charge balance for all species = -.7402E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8870913E-10 -.2222256E-01 -.2235996E+02 0.0000 2 H2O 0.1000000E+01 0.5550495E+02 0.9981953E+06 0.0000 3 Cl- 0.2808836E-03 0.2821789E-03 0.9986648E+01 6.4979 4 SO4-- 0.1758747E-11 -.7889202E-04 -.7565283E+01 8.2156 5 HCO3- 0.1465608E-05 0.8022898E-04 0.4886814E+01 4.2161 6 HS- 0.6948601E-04 0.1483914E-03 0.4899047E+01 5.8914 7 Al+++ 0.9846773E-29 0.5294498E-05 0.1426045E+00 0.7390 8 H4SiO4 0.6959786E-03 0.1349111E-01 0.1294443E+04 -3.1574 9 Ca++ 0.1363507E-06 0.2345760E-06 0.9384949E-02 13.1018 10 Mg++ 0.2133145E-10 0.9377518E-10 0.2275888E-05 9.2942 11 Fe++ 0.5879309E-13 0.3614416E-07 0.2015024E-02 6.7350 12 K+ 0.1572530E-03 0.1580073E-03 0.6167631E+01 6.2467 13 Na+ 0.1995475E-01 0.2240173E-01 0.5141135E+03 8.3494 14 Mn++ 0.1886142E-10 0.2526876E-08 0.1385795E-03 9.2416 15 F- 0.4980366E-06 0.4996556E-06 0.9475910E-02 3.7458 16 HPO4-- 0.4498071E-07 0.4607480E-07 0.4414504E-02 12.6235 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279251E+02 -.1102999E-01 -.8278148E+02 0.0000000E+00 2 H2O -.7168486E+01 0.2754943E+02 -.3471792E+02 0.0000000E+00 3 Cl- 0.1400572E-03 0.1400572E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385943E+00 -.3915741E-04 0.1386334E+00 0.0000000E+00 5 HCO3- 0.3982100E-04 0.3982100E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385598E+00 0.7365288E-04 -.1386334E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627881E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696203E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1164299E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4654455E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793986E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7842564E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111892E-01 0.6265258E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254194E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2480000E-06 0.2480000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2286885E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1130E-13 Mass of aqueous solution: 0.497209E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2620 -0.582 56.74 1.754 1.039 17.34 hedenbergite 0.6794E-01 -1.168 16.86 1.227 0.3086 4.617 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4271E-01 -1.369 36.51 1.562 0.6684 11.75 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337984 g Volume = 2210.778883 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003700 moles log = -3.4318 Original solution: 1000.0103000 g Original solution / Rock added: 2702730.54 (Water/Rock Ratio), log = 6.4318 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1474 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8907E+00 0.9843 0.1006E+01 0.1022E+01 CO2,gas 0.1809E-07 1.0057 0.2088E-07 0.2076E-07 CH4,gas 0.9605E-01 1.0113 0.1115E+00 0.1102E+00 H2,gas 0.1325E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3216E-06 0.9955 0.3673E-06 0.3690E-06 S2,gas 0.1909E-28 1.0000 0.2190E-28 0.2190E-28 CO,gas 0.7374E-13 1.0000 0.8460E-13 0.8460E-13 SO3,gas 0.1669E-47 1.0000 0.1915E-47 0.1915E-47 SO2,gas 0.9875E-27 1.0000 0.1133E-26 0.1133E-26 HF,gas 0.4530E-15 1.0000 0.5197E-15 0.5197E-15 HCl,gas 0.4925E-17 1.0000 0.5650E-17 0.5650E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.42463E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.04 -9.38 -3.126 0.16015E+05 -7.680 3 CH4,gas 4.54 1.89 -2.65 -0.663 0.45280E+04 -0.953 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.36 -8.13 -4.067 0.13888E+05 -6.435 6 S2,gas -7.34 -37.69 -30.36 -4.671 0.51836E+05 -28.659 7 CO,gas 3.21 -11.56 -14.77 -4.545 0.25222E+05 -13.073 8 SO3,gas 17.12 -32.30 -49.42 -12.354 0.84378E+05 -47.718 9 SO2,gas 0.83 -27.81 -28.64 -7.639 0.48910E+05 -26.946 10 HF,gas 0.47 -16.51 -16.98 -8.492 0.28998E+05 -15.284 11 HCl,gas 5.19 -13.76 -18.95 -9.473 0.32351E+05 -17.248 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.66 -0.36 -0.030 0.61852E+03 38 aragonite 0.97 -2.94 -3.90 -1.301 0.66662E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.94 -3.75 -1.250 0.64020E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.07 -3.97 -1.135 0.67811E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.07 -3.53 -1.008 0.60233E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.63 -3.37 -1.123 0.57522E+04 147 pyrrhotiteFe0.875 -6.02 -9.03 -3.01 -1.107 0.51394E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.63 -3.22 -1.073 0.54950E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.12 -4.14 -1.382 0.70769E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003700 MOLES New total amount of reactant added: 0.0003800 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3677E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003800 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140204E-01 Osmotic coef. = 0.9915 True ionic strength = .2011579E-01 Chg. balance for total moles = -.3677E-10 Max. difference allowed = 0.1401E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88711E-10 -10.0520 0.74517E-10 -10.1277 0.84000E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28100E-03 -3.5513 0.23462E-03 -3.6296 0.83493E+00 -0.0784 4 SO4-- 0.17711E-11 -11.7518 0.91858E-12 -12.0369 0.51865E+00 -0.2851 5 HCO3- 0.14922E-05 -5.8262 0.12477E-05 -5.9039 0.83615E+00 -0.0777 6 HS- 0.69975E-04 -4.1551 0.58433E-04 -4.2333 0.83505E+00 -0.0783 7 Al+++ 0.98475E-29 -29.0067 0.22685E-29 -29.6443 0.23036E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13636E-06 -6.8653 0.70200E-07 -7.1537 0.51483E+00 -0.2883 10 Mg++ 0.21332E-10 -10.6710 0.10932E-10 -10.9613 0.51246E+00 -0.2903 11 Fe++ 0.58796E-13 -13.2307 0.30164E-13 -13.5205 0.51303E+00 -0.2899 12 K+ 0.15726E-03 -3.8034 0.13152E-03 -3.8810 0.83635E+00 -0.0776 13 Na+ 0.19955E-01 -1.6999 0.16658E-01 -1.7784 0.83477E+00 -0.0784 14 Mn++ 0.18862E-10 -10.7244 0.96849E-11 -11.0139 0.51345E+00 -0.2895 15 F- 0.50607E-06 -6.2958 0.42166E-06 -6.3750 0.83320E+00 -0.0793 16 HPO4-- 0.44979E-07 -7.3470 0.23332E-07 -7.6321 0.51872E+00 -0.2851 18 HSiO3- 0.10445E-01 -1.9811 0.87211E-02 -2.0594 0.83493E+00 -0.0784 19 Ca(HSiO3)+ 0.16667E-07 -7.7781 0.13943E-07 -7.8557 0.83653E+00 -0.0775 20 Mg(HSiO3)+ 0.32302E-11 -11.4908 0.27021E-11 -11.5683 0.83653E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66439E-16 -16.1776 0.55578E-16 -16.2551 0.83653E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52943E-05 -5.2762 0.44123E-05 -5.3553 0.83341E+00 -0.0791 26 CH4,aq 0.77366E-04 -4.1114 0.77097E-04 -4.1130 0.99652E+00 -0.0015 27 C2H6,aq 0.88037E-13 -13.0553 0.87731E-13 -13.0568 0.99652E+00 -0.0015 31 CO,aq 0.57804E-16 -16.2380 0.57804E-16 -16.2380 0.10000E+01 0.0000 32 CO2,aq 0.19936E-09 -9.7004 0.19867E-09 -9.7019 0.99652E+00 -0.0015 33 CO3-2 0.28259E-05 -5.5488 0.14625E-05 -5.8349 0.51754E+00 -0.2861 34 CaCO3,aq 0.12873E-08 -8.8903 0.12873E-08 -8.8903 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.26727E-11 -11.5731 0.22358E-11 -11.6506 0.83653E+00 -0.0775 36 CaCl+ 0.31862E-10 -10.4967 0.26654E-10 -10.5742 0.83653E+00 -0.0775 37 CaCl2,aq 0.14857E-14 -14.8281 0.14857E-14 -14.8281 0.10000E+01 0.0000 38 CaF+ 0.51662E-12 -12.2868 0.43217E-12 -12.3643 0.83653E+00 -0.0775 39 CaOH+ 0.80261E-07 -7.0955 0.67141E-07 -7.1730 0.83653E+00 -0.0775 40 CaSO4,aq 0.20477E-16 -16.6887 0.20477E-16 -16.6887 0.10000E+01 0.0000 41 HCl,aq 0.32036E-14 -14.4944 0.32036E-14 -14.4944 0.10000E+01 0.0000 45 HF,aq 0.21510E-12 -12.6674 0.21510E-12 -12.6674 0.10000E+01 0.0000 46 HF2- 0.36676E-19 -19.4356 0.30621E-19 -19.5140 0.83493E+00 -0.0784 48 FeCl+ 0.13390E-16 -16.8732 0.11202E-16 -16.9507 0.83653E+00 -0.0775 51 FeF+ 0.77696E-18 -18.1096 0.64995E-18 -18.1871 0.83653E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15751E-10 -10.8027 0.13176E-10 -10.8802 0.83653E+00 -0.0775 55 HFeO2- 0.35506E-07 -7.4497 0.29645E-07 -7.5281 0.83493E+00 -0.0784 56 FeO+ 0.11039E-16 -16.9571 0.92346E-17 -17.0346 0.83653E+00 -0.0775 58 FeO2- 0.40758E-09 -9.3898 0.34030E-09 -9.4681 0.83493E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55926E-09 -9.2524 0.55926E-09 -9.2524 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.22454E-14 -14.6487 0.18747E-14 -14.7271 0.83493E+00 -0.0784 65 MgCO3,aq 0.50250E-13 -13.2989 0.50250E-13 -13.2989 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.42529E-15 -15.3713 0.35577E-15 -15.4488 0.83653E+00 -0.0775 67 MgCl+ 0.44971E-14 -14.3471 0.37620E-14 -14.4246 0.83653E+00 -0.0775 68 MgF+ 0.29802E-15 -15.5258 0.24930E-15 -15.6033 0.83653E+00 -0.0775 69 MgOH+ 0.69162E-10 -10.1601 0.57856E-10 -10.2376 0.83653E+00 -0.0775 71 MnF+ 0.82225E-16 -16.0850 0.68784E-16 -16.1625 0.83653E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46981E-09 -9.3281 0.39301E-09 -9.4056 0.83653E+00 -0.0775 74 MnO2-2 0.20859E-10 -10.6807 0.10795E-10 -10.9668 0.51754E+00 -0.2861 75 HMnO2- 0.21109E-09 -9.6755 0.17624E-09 -9.7539 0.83493E+00 -0.0784 78 MnCl+ 0.16726E-13 -13.7766 0.13992E-13 -13.8541 0.83653E+00 -0.0775 80 NaCl,aq 0.12952E-05 -5.8877 0.12952E-05 -5.8877 0.10000E+01 0.0000 81 NaF,aq 0.16444E-08 -8.7840 0.16444E-08 -8.7840 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93034E-02 -2.0314 0.77536E-02 -2.1105 0.83341E+00 -0.0791 89 HPO3-2 0.16272E-14 -14.7886 0.84216E-15 -15.0746 0.51754E+00 -0.2861 91 H2PO3- 0.15072E-18 -18.8218 0.12584E-18 -18.9002 0.83493E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38377E-10 -10.4159 0.32073E-10 -10.4939 0.83572E+00 -0.0779 94 PO4-3 0.10557E-08 -8.9765 0.25546E-09 -9.5927 0.24199E+00 -0.6162 98 HP2O7-3 0.93728E-18 -18.0281 0.21613E-18 -18.6653 0.23059E+00 -0.6372 99 P2O7-4 0.90316E-17 -17.0442 0.69290E-18 -18.1593 0.76719E-01 -1.1151 100 H2S,aq 0.13504E-07 -7.8695 0.13457E-07 -7.8710 0.99652E+00 -0.0015 101 S2-2 0.12621E-13 -13.8989 0.65319E-14 -14.1850 0.51754E+00 -0.2861 107 SO3-2 0.26332E-17 -17.5795 0.13826E-17 -17.8593 0.52506E+00 -0.2798 109 HSO4- 0.78780E-19 -19.1036 0.65966E-19 -19.1807 0.83735E+00 -0.0771 Charge balance for all species = -.7409E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8871091E-10 -.2222227E-01 -.2235967E+02 0.0000 2 H2O 0.1000000E+01 0.5550496E+02 0.9981952E+06 0.0000 3 Cl- 0.2810018E-03 0.2822976E-03 0.9990850E+01 6.4981 4 SO4-- 0.1771110E-11 -.8027173E-04 -.7697588E+01 8.2186 5 HCO3- 0.1492195E-05 0.8168560E-04 0.4975538E+01 4.2239 6 HS- 0.6997547E-04 0.1502607E-03 0.4960759E+01 5.8944 7 Al+++ 0.9847458E-29 0.5294408E-05 0.1426020E+00 0.7390 8 H4SiO4 0.6959785E-03 0.1349093E-01 0.1294426E+04 -3.1574 9 Ca++ 0.1363566E-06 0.2346069E-06 0.9386185E-02 13.1018 10 Mg++ 0.2133238E-10 0.9377783E-10 0.2275952E-05 9.2942 11 Fe++ 0.5879565E-13 0.3614355E-07 0.2014990E-02 6.7350 12 K+ 0.1572562E-03 0.1580105E-03 0.6167754E+01 6.2467 13 Na+ 0.1995516E-01 0.2240213E-01 0.5141227E+03 8.3494 14 Mn++ 0.1886226E-10 0.2526885E-08 0.1385800E-03 9.2416 15 F- 0.5060692E-06 0.5077144E-06 0.9628743E-02 3.7527 16 HPO4-- 0.4497930E-07 0.4607334E-07 0.4414364E-02 12.6234 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279251E+02 -.1102985E-01 -.8278148E+02 0.0000000E+00 2 H2O -.7168478E+01 0.2754944E+02 -.3471792E+02 0.0000000E+00 3 Cl- 0.1401162E-03 0.1401162E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385943E+00 -.3984223E-04 0.1386342E+00 0.0000000E+00 5 HCO3- 0.4054400E-04 0.4054400E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385596E+00 0.7458070E-04 -.1386342E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627837E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696117E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1164453E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4654588E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793956E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7842724E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111912E-01 0.6265258E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254199E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2520000E-06 0.2520000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2286813E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.9326E-14 Mass of aqueous solution: 0.497209E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003800 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.21 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2620 -0.582 56.73 1.754 1.039 17.34 hedenbergite 0.6794E-01 -1.168 16.86 1.227 0.3086 4.617 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4272E-01 -1.369 36.51 1.562 0.6685 11.75 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337988 g Volume = 2210.778911 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003800 moles log = -3.4202 Original solution: 1000.0103000 g Original solution / Rock added: 2631606.05 (Water/Rock Ratio), log = 6.4202 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1494 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8892E+00 0.9843 0.1006E+01 0.1022E+01 CO2,gas 0.1839E-07 1.0057 0.2126E-07 0.2113E-07 CH4,gas 0.9763E-01 1.0113 0.1135E+00 0.1122E+00 H2,gas 0.1322E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3233E-06 0.9955 0.3699E-06 0.3716E-06 S2,gas 0.1933E-28 1.0000 0.2221E-28 0.2221E-28 CO,gas 0.7494E-13 1.0000 0.8614E-13 0.8614E-13 SO3,gas 0.1678E-47 1.0000 0.1929E-47 0.1929E-47 SO2,gas 0.9927E-27 1.0000 0.1141E-26 0.1141E-26 HF,gas 0.4595E-15 1.0000 0.5281E-15 0.5281E-15 HCl,gas 0.4918E-17 1.0000 0.5653E-17 0.5653E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.03 -9.37 -3.124 0.16002E+05 -7.673 3 CH4,gas 4.54 1.90 -2.64 -0.661 0.45146E+04 -0.945 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.36 -8.13 -4.065 0.13883E+05 -6.432 6 S2,gas -7.34 -37.69 -30.35 -4.670 0.51826E+05 -28.653 7 CO,gas 3.21 -11.55 -14.76 -4.543 0.25209E+05 -13.065 8 SO3,gas 17.12 -32.29 -49.41 -12.353 0.84373E+05 -47.715 9 SO2,gas 0.83 -27.81 -28.64 -7.638 0.48905E+05 -26.943 10 HF,gas 0.47 -16.50 -16.98 -8.488 0.28986E+05 -15.277 11 HCl,gas 5.19 -13.76 -18.95 -9.473 0.32351E+05 -17.248 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.66 -0.36 -0.030 0.60665E+03 38 aragonite 0.97 -2.93 -3.90 -1.299 0.66529E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.93 -3.74 -1.247 0.63886E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.07 -3.96 -1.132 0.67677E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.07 -3.52 -1.006 0.60100E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.63 -3.37 -1.122 0.57470E+04 147 pyrrhotiteFe0.875 -6.02 -9.02 -3.01 -1.106 0.51342E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.63 -3.22 -1.072 0.54898E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.12 -4.14 -1.381 0.70717E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003800 MOLES New total amount of reactant added: 0.0003900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.3677E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140121E-01 Osmotic coef. = 0.9924 True ionic strength = .2011625E-01 Chg. balance for total moles = -.3677E-10 Max. difference allowed = 0.1402E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88713E-10 -10.0520 0.74518E-10 -10.1277 0.83999E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28112E-03 -3.5511 0.23471E-03 -3.6295 0.83492E+00 -0.0784 4 SO4-- 0.17835E-11 -11.7487 0.92499E-12 -12.0339 0.51865E+00 -0.2851 5 HCO3- 0.15188E-05 -5.8185 0.12699E-05 -5.8962 0.83615E+00 -0.0777 6 HS- 0.70465E-04 -4.1520 0.58842E-04 -4.2303 0.83505E+00 -0.0783 7 Al+++ 0.98481E-29 -29.0066 0.22686E-29 -29.6442 0.23036E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13636E-06 -6.8653 0.70203E-07 -7.1536 0.51482E+00 -0.2883 10 Mg++ 0.21333E-10 -10.6709 0.10932E-10 -10.9613 0.51246E+00 -0.2903 11 Fe++ 0.58798E-13 -13.2306 0.30165E-13 -13.5205 0.51302E+00 -0.2899 12 K+ 0.15726E-03 -3.8034 0.13152E-03 -3.8810 0.83635E+00 -0.0776 13 Na+ 0.19956E-01 -1.6999 0.16658E-01 -1.7784 0.83477E+00 -0.0784 14 Mn++ 0.18863E-10 -10.7244 0.96853E-11 -11.0139 0.51345E+00 -0.2895 15 F- 0.51410E-06 -6.2890 0.42835E-06 -6.3682 0.83320E+00 -0.0793 16 HPO4-- 0.44978E-07 -7.3470 0.23331E-07 -7.6321 0.51872E+00 -0.2851 18 HSiO3- 0.10445E-01 -1.9811 0.87209E-02 -2.0594 0.83492E+00 -0.0784 19 Ca(HSiO3)+ 0.16667E-07 -7.7781 0.13943E-07 -7.8557 0.83653E+00 -0.0775 20 Mg(HSiO3)+ 0.32302E-11 -11.4908 0.27022E-11 -11.5683 0.83653E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66440E-16 -16.1776 0.55579E-16 -16.2551 0.83653E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52942E-05 -5.2762 0.44122E-05 -5.3553 0.83341E+00 -0.0791 26 CH4,aq 0.78746E-04 -4.1038 0.78472E-04 -4.1053 0.99652E+00 -0.0015 27 C2H6,aq 0.91206E-13 -13.0400 0.90888E-13 -13.0415 0.99652E+00 -0.0015 31 CO,aq 0.58835E-16 -16.2304 0.58835E-16 -16.2304 0.10000E+01 0.0000 32 CO2,aq 0.20291E-09 -9.6927 0.20221E-09 -9.6942 0.99652E+00 -0.0015 33 CO3-2 0.28762E-05 -5.5412 0.14885E-05 -5.8272 0.51754E+00 -0.2861 34 CaCO3,aq 0.13103E-08 -8.8826 0.13103E-08 -8.8826 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.27204E-11 -11.5654 0.22757E-11 -11.6429 0.83653E+00 -0.0775 36 CaCl+ 0.31877E-10 -10.4965 0.26666E-10 -10.5740 0.83653E+00 -0.0775 37 CaCl2,aq 0.14870E-14 -14.8277 0.14870E-14 -14.8277 0.10000E+01 0.0000 38 CaF+ 0.52484E-12 -12.2800 0.43904E-12 -12.3575 0.83653E+00 -0.0775 39 CaOH+ 0.80263E-07 -7.0955 0.67142E-07 -7.1730 0.83653E+00 -0.0775 40 CaSO4,aq 0.20620E-16 -16.6857 0.20620E-16 -16.6857 0.10000E+01 0.0000 41 HCl,aq 0.32051E-14 -14.4942 0.32051E-14 -14.4942 0.10000E+01 0.0000 45 HF,aq 0.21851E-12 -12.6605 0.21851E-12 -12.6605 0.10000E+01 0.0000 46 HF2- 0.37850E-19 -19.4219 0.31602E-19 -19.5003 0.83492E+00 -0.0784 48 FeCl+ 0.13397E-16 -16.8730 0.11207E-16 -16.9505 0.83653E+00 -0.0775 51 FeF+ 0.78932E-18 -18.1027 0.66029E-18 -18.1803 0.83653E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15751E-10 -10.8027 0.13177E-10 -10.8802 0.83653E+00 -0.0775 55 HFeO2- 0.35505E-07 -7.4497 0.29644E-07 -7.5281 0.83492E+00 -0.0784 56 FeO+ 0.11039E-16 -16.9571 0.92348E-17 -17.0346 0.83653E+00 -0.0775 58 FeO2- 0.40757E-09 -9.3898 0.34029E-09 -9.4681 0.83492E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55950E-09 -9.2522 0.55950E-09 -9.2522 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.22611E-14 -14.6457 0.18878E-14 -14.7240 0.83492E+00 -0.0784 65 MgCO3,aq 0.51147E-13 -13.2912 0.51147E-13 -13.2912 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.43288E-15 -15.3636 0.36212E-15 -15.4411 0.83653E+00 -0.0775 67 MgCl+ 0.44992E-14 -14.3469 0.37637E-14 -14.4244 0.83653E+00 -0.0775 68 MgF+ 0.30276E-15 -15.5189 0.25327E-15 -15.5964 0.83653E+00 -0.0775 69 MgOH+ 0.69163E-10 -10.1601 0.57857E-10 -10.2376 0.83653E+00 -0.0775 71 MnF+ 0.83534E-16 -16.0781 0.69878E-16 -16.1557 0.83653E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46982E-09 -9.3281 0.39302E-09 -9.4056 0.83653E+00 -0.0775 74 MnO2-2 0.20858E-10 -10.6807 0.10795E-10 -10.9668 0.51754E+00 -0.2861 75 HMnO2- 0.21108E-09 -9.6755 0.17624E-09 -9.7539 0.83492E+00 -0.0784 78 MnCl+ 0.16734E-13 -13.7764 0.13999E-13 -13.8539 0.83653E+00 -0.0775 80 NaCl,aq 0.12958E-05 -5.8875 0.12958E-05 -5.8875 0.10000E+01 0.0000 81 NaF,aq 0.16706E-08 -8.7771 0.16706E-08 -8.7771 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93033E-02 -2.0314 0.77534E-02 -2.1105 0.83341E+00 -0.0791 89 HPO3-2 0.16272E-14 -14.7886 0.84213E-15 -15.0746 0.51754E+00 -0.2861 91 H2PO3- 0.15072E-18 -18.8218 0.12584E-18 -18.9002 0.83492E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38377E-10 -10.4159 0.32072E-10 -10.4939 0.83572E+00 -0.0779 94 PO4-3 0.10556E-08 -8.9765 0.25545E-09 -9.5927 0.24199E+00 -0.6162 98 HP2O7-3 0.93724E-18 -18.0282 0.21612E-18 -18.6653 0.23059E+00 -0.6372 99 P2O7-4 0.90312E-17 -17.0443 0.69285E-18 -18.1594 0.76717E-01 -1.1151 100 H2S,aq 0.13599E-07 -7.8665 0.13552E-07 -7.8680 0.99652E+00 -0.0015 101 S2-2 0.12798E-13 -13.8928 0.66236E-14 -14.1789 0.51754E+00 -0.2861 107 SO3-2 0.26516E-17 -17.5765 0.13922E-17 -17.8563 0.52505E+00 -0.2798 109 HSO4- 0.79331E-19 -19.1006 0.66428E-19 -19.1777 0.83735E+00 -0.0771 Charge balance for all species = -.7409E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8871269E-10 -.2222198E-01 -.2235938E+02 0.0000 2 H2O 0.1000000E+01 0.5550496E+02 0.9981952E+06 0.0000 3 Cl- 0.2811200E-03 0.2824164E-03 0.9995053E+01 6.4983 4 SO4-- 0.1783473E-11 -.8165144E-04 -.7829894E+01 8.2216 5 HCO3- 0.1518780E-05 0.8314223E-04 0.5064262E+01 4.2315 6 HS- 0.7046493E-04 0.1521300E-03 0.5022471E+01 5.8974 7 Al+++ 0.9848144E-29 0.5294318E-05 0.1425996E+00 0.7390 8 H4SiO4 0.6959785E-03 0.1349075E-01 0.1294409E+04 -3.1574 9 Ca++ 0.1363625E-06 0.2346378E-06 0.9387421E-02 13.1018 10 Mg++ 0.2133330E-10 0.9378227E-10 0.2276060E-05 9.2942 11 Fe++ 0.5879820E-13 0.3614293E-07 0.2014955E-02 6.7350 12 K+ 0.1572593E-03 0.1580136E-03 0.6167878E+01 6.2467 13 Na+ 0.1995556E-01 0.2240253E-01 0.5141319E+03 8.3494 14 Mn++ 0.1886309E-10 0.2526893E-08 0.1385804E-03 9.2416 15 F- 0.5141019E-06 0.5157732E-06 0.9781576E-02 3.7595 16 HPO4-- 0.4497789E-07 0.4607188E-07 0.4414224E-02 12.6234 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279251E+02 -.1102971E-01 -.8278148E+02 0.0000000E+00 2 H2O -.7168469E+01 0.2754945E+02 -.3471792E+02 0.0000000E+00 3 Cl- 0.1401752E-03 0.1401752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385944E+00 -.4052706E-04 0.1386349E+00 0.0000000E+00 5 HCO3- 0.4126700E-04 0.4126700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385594E+00 0.7550853E-04 -.1386349E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627793E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696030E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1164607E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4654810E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793926E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7842884E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111932E-01 0.6265258E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254204E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2560000E-06 0.2560000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2286742E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.9839E-14 Mass of aqueous solution: 0.497209E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.22 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2619 -0.582 56.73 1.754 1.039 17.34 hedenbergite 0.6793E-01 -1.168 16.85 1.227 0.3086 4.616 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4272E-01 -1.369 36.52 1.563 0.6686 11.75 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337991 g Volume = 2210.778938 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003900 moles log = -3.4089 Original solution: 1000.0103000 g Original solution / Rock added: 2564128.97 (Water/Rock Ratio), log = 6.4089 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1514 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8876E+00 0.9843 0.1006E+01 0.1022E+01 CO2,gas 0.1868E-07 1.0057 0.2163E-07 0.2151E-07 CH4,gas 0.9920E-01 1.0113 0.1155E+00 0.1142E+00 H2,gas 0.1320E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3250E-06 0.9955 0.3725E-06 0.3742E-06 S2,gas 0.1956E-28 1.0000 0.2253E-28 0.2253E-28 CO,gas 0.7615E-13 1.0000 0.8768E-13 0.8768E-13 SO3,gas 0.1687E-47 1.0000 0.1942E-47 0.1942E-47 SO2,gas 0.9979E-27 1.0000 0.1149E-26 0.1149E-26 HF,gas 0.4660E-15 1.0000 0.5365E-15 0.5365E-15 HCl,gas 0.4912E-17 1.0000 0.5655E-17 0.5655E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.02 -9.36 -3.121 0.15988E+05 -7.665 3 CH4,gas 4.54 1.91 -2.64 -0.659 0.45015E+04 -0.937 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.36 -8.13 -4.064 0.13878E+05 -6.429 6 S2,gas -7.34 -37.68 -30.35 -4.669 0.51815E+05 -28.647 7 CO,gas 3.21 -11.54 -14.76 -4.540 0.25196E+05 -13.057 8 SO3,gas 17.12 -32.29 -49.41 -12.353 0.84367E+05 -47.712 9 SO2,gas 0.83 -27.81 -28.64 -7.637 0.48900E+05 -26.940 10 HF,gas 0.47 -16.50 -16.97 -8.485 0.28975E+05 -15.270 11 HCl,gas 5.19 -13.76 -18.95 -9.473 0.32351E+05 -17.248 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.65 -0.35 -0.029 0.59496E+03 38 aragonite 0.97 -2.92 -3.89 -1.296 0.66398E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.92 -3.73 -1.245 0.63755E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.06 -3.96 -1.130 0.67546E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.06 -3.51 -1.003 0.59969E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.62 -3.36 -1.121 0.57418E+04 147 pyrrhotiteFe0.875 -6.02 -9.02 -3.00 -1.105 0.51290E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.62 -3.21 -1.071 0.54846E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.12 -4.14 -1.380 0.70665E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000100 MOLES Current total amount of reactant added: 0.0003900 MOLES New total amount of reactant added: 0.0004000 MOLES Mixing fraction reached given limit of 0.4000E-03 TOTMIX = 0.4000E-03 Execution stopped.