File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.82793E+02 0.88713E-10 0.8400 0.00000000E+00 H2O 2 0. -0.71685E+01 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.14018E-03 0.28112E-03 0.8349 0.00000000E+00 SO4-- 4 -2. 0.13859E+00 0.17835E-11 0.5186 0.00000000E+00 HCO3- 5 -1. 0.41267E-04 0.15188E-05 0.8361 0.00000000E+00 HS- 6 -1. -0.13856E+00 0.70465E-04 0.8350 0.00000000E+00 Al+++ 7 3. 0.16304E+02 0.98481E-29 0.2304 0.00000000E+00 H4SiO4 8 0. 0.52064E+02 0.69598E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.57507E+01 0.13636E-06 0.5148 0.00000000E+00 Mg++ 10 2. 0.39683E+01 0.21333E-10 0.5125 0.00000000E+00 Fe++ 11 2. 0.35650E+01 0.58798E-13 0.5130 0.00000000E+00 K+ 12 1. 0.10616E+01 0.15726E-03 0.8363 0.00000000E+00 Na+ 13 1. 0.62764E+01 0.19956E-01 0.8348 0.00000000E+00 Mn++ 14 2. 0.86693E-01 0.18863E-10 0.5134 0.00000000E+00 F- 15 -1. 0.25600E-06 0.51410E-06 0.8332 0.00000000E+00 HPO4-- 16 -2. 0.29588E-01 0.44978E-07 0.5187 0.00000000E+00 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1402E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.800000E-03 TEMP = 100.0000 SINC = 0.2000E-04 TEMPC = 0.0000 TOTMIX = 0.390000E-03 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 2000.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.6260E+01 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.5545E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.1343E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.9863E-02 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.0000E+00 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.3220E+01 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.2613E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.7103E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.2056E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.1734E-01 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.2619E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.6793E-01 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.9308E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.4272E-01 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0003900 moles log = -3.4089 Original solution: 1000.0103000 g Original solution / Rock added: 2564128.97 (Water/Rock Ratio), log = 6.4089 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0003900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1140121E-01 Osmotic coef. = 0.9924 True ionic strength = .2011625E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1402E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88713E-10 -10.0520 0.74518E-10 -10.1277 0.83999E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28112E-03 -3.5511 0.23471E-03 -3.6295 0.83492E+00 -0.0784 4 SO4-- 0.17835E-11 -11.7487 0.92499E-12 -12.0339 0.51865E+00 -0.2851 5 HCO3- 0.15188E-05 -5.8185 0.12699E-05 -5.8962 0.83615E+00 -0.0777 6 HS- 0.70465E-04 -4.1520 0.58842E-04 -4.2303 0.83505E+00 -0.0783 7 Al+++ 0.98481E-29 -29.0066 0.22686E-29 -29.6442 0.23036E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13636E-06 -6.8653 0.70203E-07 -7.1536 0.51482E+00 -0.2883 10 Mg++ 0.21333E-10 -10.6709 0.10932E-10 -10.9613 0.51246E+00 -0.2903 11 Fe++ 0.58798E-13 -13.2306 0.30165E-13 -13.5205 0.51302E+00 -0.2899 12 K+ 0.15726E-03 -3.8034 0.13152E-03 -3.8810 0.83635E+00 -0.0776 13 Na+ 0.19956E-01 -1.6999 0.16658E-01 -1.7784 0.83477E+00 -0.0784 14 Mn++ 0.18863E-10 -10.7244 0.96853E-11 -11.0139 0.51345E+00 -0.2895 15 F- 0.51410E-06 -6.2890 0.42835E-06 -6.3682 0.83320E+00 -0.0793 16 HPO4-- 0.44978E-07 -7.3470 0.23331E-07 -7.6321 0.51872E+00 -0.2851 18 HSiO3- 0.10445E-01 -1.9811 0.87209E-02 -2.0594 0.83492E+00 -0.0784 19 Ca(HSiO3)+ 0.16667E-07 -7.7781 0.13943E-07 -7.8557 0.83653E+00 -0.0775 20 Mg(HSiO3)+ 0.32302E-11 -11.4908 0.27022E-11 -11.5683 0.83653E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66440E-16 -16.1776 0.55579E-16 -16.2551 0.83653E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52942E-05 -5.2762 0.44122E-05 -5.3553 0.83341E+00 -0.0791 26 CH4,aq 0.78746E-04 -4.1038 0.78472E-04 -4.1053 0.99652E+00 -0.0015 27 C2H6,aq 0.91206E-13 -13.0400 0.90888E-13 -13.0415 0.99652E+00 -0.0015 31 CO,aq 0.58835E-16 -16.2304 0.58835E-16 -16.2304 0.10000E+01 0.0000 32 CO2,aq 0.20291E-09 -9.6927 0.20221E-09 -9.6942 0.99652E+00 -0.0015 33 CO3-2 0.28762E-05 -5.5412 0.14885E-05 -5.8272 0.51754E+00 -0.2861 34 CaCO3,aq 0.13103E-08 -8.8826 0.13103E-08 -8.8826 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.27204E-11 -11.5654 0.22757E-11 -11.6429 0.83653E+00 -0.0775 36 CaCl+ 0.31877E-10 -10.4965 0.26666E-10 -10.5740 0.83653E+00 -0.0775 37 CaCl2,aq 0.14870E-14 -14.8277 0.14870E-14 -14.8277 0.10000E+01 0.0000 38 CaF+ 0.52484E-12 -12.2800 0.43904E-12 -12.3575 0.83653E+00 -0.0775 39 CaOH+ 0.80262E-07 -7.0955 0.67142E-07 -7.1730 0.83653E+00 -0.0775 40 CaSO4,aq 0.20620E-16 -16.6857 0.20620E-16 -16.6857 0.10000E+01 0.0000 41 HCl,aq 0.32051E-14 -14.4942 0.32051E-14 -14.4942 0.10000E+01 0.0000 45 HF,aq 0.21851E-12 -12.6605 0.21851E-12 -12.6605 0.10000E+01 0.0000 46 HF2- 0.37850E-19 -19.4219 0.31602E-19 -19.5003 0.83492E+00 -0.0784 48 FeCl+ 0.13397E-16 -16.8730 0.11207E-16 -16.9505 0.83653E+00 -0.0775 51 FeF+ 0.78932E-18 -18.1027 0.66029E-18 -18.1803 0.83653E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15751E-10 -10.8027 0.13177E-10 -10.8802 0.83653E+00 -0.0775 55 HFeO2- 0.35505E-07 -7.4497 0.29644E-07 -7.5281 0.83492E+00 -0.0784 56 FeO+ 0.11039E-16 -16.9571 0.92348E-17 -17.0346 0.83653E+00 -0.0775 58 FeO2- 0.40757E-09 -9.3898 0.34029E-09 -9.4681 0.83492E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55950E-09 -9.2522 0.55950E-09 -9.2522 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.22611E-14 -14.6457 0.18878E-14 -14.7240 0.83492E+00 -0.0784 65 MgCO3,aq 0.51147E-13 -13.2912 0.51147E-13 -13.2912 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.43288E-15 -15.3636 0.36212E-15 -15.4411 0.83653E+00 -0.0775 67 MgCl+ 0.44992E-14 -14.3469 0.37637E-14 -14.4244 0.83653E+00 -0.0775 68 MgF+ 0.30276E-15 -15.5189 0.25327E-15 -15.5964 0.83653E+00 -0.0775 69 MgOH+ 0.69163E-10 -10.1601 0.57857E-10 -10.2376 0.83653E+00 -0.0775 71 MnF+ 0.83534E-16 -16.0781 0.69878E-16 -16.1557 0.83653E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46982E-09 -9.3281 0.39302E-09 -9.4056 0.83653E+00 -0.0775 74 MnO2-2 0.20858E-10 -10.6807 0.10795E-10 -10.9668 0.51754E+00 -0.2861 75 HMnO2- 0.21108E-09 -9.6755 0.17624E-09 -9.7539 0.83492E+00 -0.0784 78 MnCl+ 0.16734E-13 -13.7764 0.13999E-13 -13.8539 0.83653E+00 -0.0775 80 NaCl,aq 0.12958E-05 -5.8875 0.12958E-05 -5.8875 0.10000E+01 0.0000 81 NaF,aq 0.16706E-08 -8.7771 0.16706E-08 -8.7771 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93033E-02 -2.0314 0.77534E-02 -2.1105 0.83341E+00 -0.0791 89 HPO3-2 0.16272E-14 -14.7886 0.84213E-15 -15.0746 0.51754E+00 -0.2861 91 H2PO3- 0.15072E-18 -18.8218 0.12584E-18 -18.9002 0.83492E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38377E-10 -10.4159 0.32072E-10 -10.4939 0.83572E+00 -0.0779 94 PO4-3 0.10556E-08 -8.9765 0.25545E-09 -9.5927 0.24199E+00 -0.6162 98 HP2O7-3 0.93724E-18 -18.0282 0.21612E-18 -18.6653 0.23059E+00 -0.6372 99 P2O7-4 0.90312E-17 -17.0443 0.69285E-18 -18.1594 0.76717E-01 -1.1151 100 H2S,aq 0.13599E-07 -7.8665 0.13552E-07 -7.8680 0.99652E+00 -0.0015 101 S2-2 0.12798E-13 -13.8928 0.66236E-14 -14.1789 0.51754E+00 -0.2861 107 SO3-2 0.26516E-17 -17.5765 0.13922E-17 -17.8563 0.52505E+00 -0.2798 109 HSO4- 0.79331E-19 -19.1006 0.66428E-19 -19.1777 0.83735E+00 -0.0771 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8871269E-10 -.2222198E-01 -.2235938E+02 0.0000 2 H2O 0.1000000E+01 0.5550496E+02 0.9981952E+06 0.0000 3 Cl- 0.2811200E-03 0.2824164E-03 0.9995053E+01 6.4983 4 SO4-- 0.1783473E-11 -.8165144E-04 -.7829894E+01 8.2216 5 HCO3- 0.1518780E-05 0.8314223E-04 0.5064262E+01 4.2315 6 HS- 0.7046493E-04 0.1521300E-03 0.5022471E+01 5.8974 7 Al+++ 0.9848144E-29 0.5294318E-05 0.1425996E+00 0.7390 8 H4SiO4 0.6959785E-03 0.1349075E-01 0.1294409E+04 -3.1574 9 Ca++ 0.1363625E-06 0.2346378E-06 0.9387421E-02 13.1018 10 Mg++ 0.2133330E-10 0.9378137E-10 0.2276038E-05 9.2942 11 Fe++ 0.5879820E-13 0.3614293E-07 0.2014955E-02 6.7350 12 K+ 0.1572593E-03 0.1580136E-03 0.6167878E+01 6.2467 13 Na+ 0.1995556E-01 0.2240253E-01 0.5141319E+03 8.3494 14 Mn++ 0.1886309E-10 0.2526893E-08 0.1385804E-03 9.2416 15 F- 0.5141019E-06 0.5157732E-06 0.9781576E-02 3.7595 16 HPO4-- 0.4497789E-07 0.4607188E-07 0.4414224E-02 12.6234 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279251E+02 -.1102971E-01 -.8278148E+02 0.0000000E+00 2 H2O -.7168469E+01 0.2754945E+02 -.3471792E+02 0.0000000E+00 3 Cl- 0.1401752E-03 0.1401752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385944E+00 -.4052706E-04 0.1386349E+00 0.0000000E+00 5 HCO3- 0.4126700E-04 0.4126700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385594E+00 0.7550853E-04 -.1386349E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627793E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6696030E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1164607E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4654765E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793926E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7842884E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111932E-01 0.6265258E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254204E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2560000E-06 0.2560000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2286742E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.7265E-14 Mass of aqueous solution: 0.497209E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0003900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.22 grossular 0.1343 -0.872 60.48 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2619 -0.582 56.73 1.754 1.039 17.34 hedenbergite 0.6793E-01 -1.168 16.85 1.227 0.3086 4.616 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4272E-01 -1.369 36.52 1.563 0.6686 11.75 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337991 g Volume = 2210.778938 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0003900 moles log = -3.4089 Original solution: 1000.0103000 g Original solution / Rock added: 2564128.97 (Water/Rock Ratio), log = 6.4089 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1514 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8876E+00 0.9843 0.1006E+01 0.1022E+01 CO2,gas 0.1868E-07 1.0057 0.2163E-07 0.2151E-07 CH4,gas 0.9920E-01 1.0113 0.1155E+00 0.1142E+00 H2,gas 0.1320E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3250E-06 0.9955 0.3725E-06 0.3742E-06 S2,gas 0.1956E-28 1.0000 0.2253E-28 0.2253E-28 CO,gas 0.7615E-13 1.0000 0.8768E-13 0.8768E-13 SO3,gas 0.1687E-47 1.0000 0.1942E-47 0.1942E-47 SO2,gas 0.9979E-27 1.0000 0.1149E-26 0.1149E-26 HF,gas 0.4660E-15 1.0000 0.5365E-15 0.5365E-15 HCl,gas 0.4912E-17 1.0000 0.5655E-17 0.5655E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.18198E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.02 -9.36 -3.121 0.15988E+05 -7.665 3 CH4,gas 4.54 1.91 -2.64 -0.659 0.45015E+04 -0.937 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.36 -8.13 -4.064 0.13878E+05 -6.429 6 S2,gas -7.34 -37.68 -30.35 -4.669 0.51815E+05 -28.647 7 CO,gas 3.21 -11.54 -14.76 -4.540 0.25196E+05 -13.057 8 SO3,gas 17.12 -32.29 -49.41 -12.353 0.84367E+05 -47.712 9 SO2,gas 0.83 -27.81 -28.64 -7.637 0.48900E+05 -26.940 10 HF,gas 0.47 -16.50 -16.97 -8.485 0.28975E+05 -15.270 11 HCl,gas 5.19 -13.76 -18.95 -9.473 0.32351E+05 -17.248 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.65 -0.35 -0.029 0.59496E+03 38 aragonite 0.97 -2.92 -3.89 -1.296 0.66398E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.92 -3.73 -1.245 0.63755E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.06 -3.96 -1.130 0.67546E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.06 -3.51 -1.003 0.59969E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.62 -3.36 -1.121 0.57418E+04 147 pyrrhotiteFe0.875 -6.02 -9.02 -3.00 -1.105 0.51290E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.62 -3.21 -1.071 0.54846E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.12 -4.14 -1.380 0.70665E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0003900 MOLES New total amount of reactant added: 0.0004100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8659E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0004100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1139955E-01 Osmotic coef. = 0.9942 True ionic strength = .2011716E-01 Chg. balance for total moles = -.8659E-10 Max. difference allowed = 0.1403E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88716E-10 -10.0520 0.74521E-10 -10.1277 0.83999E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28136E-03 -3.5507 0.23491E-03 -3.6291 0.83492E+00 -0.0784 4 SO4-- 0.18082E-11 -11.7428 0.93780E-12 -12.0279 0.51864E+00 -0.2851 5 HCO3- 0.15719E-05 -5.8036 0.13144E-05 -5.8813 0.83615E+00 -0.0777 6 HS- 0.71444E-04 -4.1460 0.59659E-04 -4.2243 0.83504E+00 -0.0783 7 Al+++ 0.98495E-29 -29.0066 0.22689E-29 -29.6442 0.23035E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13637E-06 -6.8653 0.70208E-07 -7.1536 0.51482E+00 -0.2883 10 Mg++ 0.21335E-10 -10.6709 0.10933E-10 -10.9613 0.51245E+00 -0.2903 11 Fe++ 0.58803E-13 -13.2306 0.30167E-13 -13.5205 0.51302E+00 -0.2899 12 K+ 0.15727E-03 -3.8034 0.13153E-03 -3.8810 0.83635E+00 -0.0776 13 Na+ 0.19956E-01 -1.6999 0.16659E-01 -1.7784 0.83477E+00 -0.0784 14 Mn++ 0.18865E-10 -10.7243 0.96860E-11 -11.0139 0.51344E+00 -0.2895 15 F- 0.53017E-06 -6.2756 0.44173E-06 -6.3548 0.83319E+00 -0.0793 16 HPO4-- 0.44975E-07 -7.3470 0.23329E-07 -7.6321 0.51871E+00 -0.2851 18 HSiO3- 0.10445E-01 -1.9811 0.87206E-02 -2.0595 0.83492E+00 -0.0784 19 Ca(HSiO3)+ 0.16668E-07 -7.7781 0.13943E-07 -7.8556 0.83653E+00 -0.0775 20 Mg(HSiO3)+ 0.32303E-11 -11.4908 0.27023E-11 -11.5683 0.83653E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66443E-16 -16.1776 0.55581E-16 -16.2551 0.83653E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52940E-05 -5.2762 0.44121E-05 -5.3554 0.83341E+00 -0.0791 26 CH4,aq 0.81505E-04 -4.0888 0.81222E-04 -4.0903 0.99652E+00 -0.0015 27 C2H6,aq 0.97710E-13 -13.0101 0.97370E-13 -13.0116 0.99652E+00 -0.0015 31 CO,aq 0.60897E-16 -16.2154 0.60897E-16 -16.2154 0.10000E+01 0.0000 32 CO2,aq 0.21002E-09 -9.6777 0.20929E-09 -9.6792 0.99652E+00 -0.0015 33 CO3-2 0.29768E-05 -5.5263 0.15406E-05 -5.8123 0.51753E+00 -0.2861 34 CaCO3,aq 0.13562E-08 -8.8677 0.13562E-08 -8.8677 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.28159E-11 -11.5504 0.23555E-11 -11.6279 0.83653E+00 -0.0775 36 CaCl+ 0.31906E-10 -10.4961 0.26690E-10 -10.5736 0.83653E+00 -0.0775 37 CaCl2,aq 0.14896E-14 -14.8269 0.14896E-14 -14.8269 0.10000E+01 0.0000 38 CaF+ 0.54128E-12 -12.2666 0.45279E-12 -12.3441 0.83653E+00 -0.0775 39 CaOH+ 0.80266E-07 -7.0955 0.67144E-07 -7.1730 0.83653E+00 -0.0775 40 CaSO4,aq 0.20908E-16 -16.6797 0.20908E-16 -16.6797 0.10000E+01 0.0000 41 HCl,aq 0.32079E-14 -14.4938 0.32079E-14 -14.4938 0.10000E+01 0.0000 45 HF,aq 0.22535E-12 -12.6471 0.22535E-12 -12.6471 0.10000E+01 0.0000 46 HF2- 0.40254E-19 -19.3952 0.33609E-19 -19.4735 0.83492E+00 -0.0784 48 FeCl+ 0.13409E-16 -16.8726 0.11217E-16 -16.9501 0.83653E+00 -0.0775 51 FeF+ 0.81404E-18 -18.0894 0.68097E-18 -18.1669 0.83653E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15752E-10 -10.8027 0.13177E-10 -10.8802 0.83653E+00 -0.0775 55 HFeO2- 0.35504E-07 -7.4497 0.29643E-07 -7.5281 0.83492E+00 -0.0784 56 FeO+ 0.11040E-16 -16.9570 0.92351E-17 -17.0346 0.83653E+00 -0.0775 58 FeO2- 0.40756E-09 -9.3898 0.34028E-09 -9.4682 0.83492E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.55999E-09 -9.2518 0.55999E-09 -9.2518 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.22925E-14 -14.6397 0.19141E-14 -14.7180 0.83492E+00 -0.0784 65 MgCO3,aq 0.52939E-13 -13.2762 0.52939E-13 -13.2762 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.44807E-15 -15.3487 0.37482E-15 -15.4262 0.83653E+00 -0.0775 67 MgCl+ 0.45033E-14 -14.3465 0.37671E-14 -14.4240 0.83653E+00 -0.0775 68 MgF+ 0.31224E-15 -15.5055 0.26120E-15 -15.5830 0.83653E+00 -0.0775 69 MgOH+ 0.69166E-10 -10.1601 0.57859E-10 -10.2376 0.83653E+00 -0.0775 71 MnF+ 0.86151E-16 -16.0647 0.72067E-16 -16.1423 0.83653E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46984E-09 -9.3280 0.39303E-09 -9.4056 0.83653E+00 -0.0775 74 MnO2-2 0.20857E-10 -10.6807 0.10794E-10 -10.9668 0.51753E+00 -0.2861 75 HMnO2- 0.21107E-09 -9.6756 0.17623E-09 -9.7539 0.83492E+00 -0.0784 78 MnCl+ 0.16749E-13 -13.7760 0.14011E-13 -13.8535 0.83653E+00 -0.0775 80 NaCl,aq 0.12969E-05 -5.8871 0.12969E-05 -5.8871 0.10000E+01 0.0000 81 NaF,aq 0.17228E-08 -8.7638 0.17228E-08 -8.7638 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93029E-02 -2.0314 0.77532E-02 -2.1105 0.83341E+00 -0.0791 89 HPO3-2 0.16271E-14 -14.7886 0.84207E-15 -15.0747 0.51753E+00 -0.2861 91 H2PO3- 0.15072E-18 -18.8218 0.12584E-18 -18.9002 0.83492E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38375E-10 -10.4159 0.32071E-10 -10.4939 0.83572E+00 -0.0779 94 PO4-3 0.10555E-08 -8.9765 0.25542E-09 -9.5927 0.24198E+00 -0.6162 98 HP2O7-3 0.93716E-18 -18.0282 0.21609E-18 -18.6654 0.23058E+00 -0.6372 99 P2O7-4 0.90302E-17 -17.0443 0.69274E-18 -18.1594 0.76714E-01 -1.1151 100 H2S,aq 0.13788E-07 -7.8605 0.13740E-07 -7.8620 0.99652E+00 -0.0015 101 S2-2 0.13156E-13 -13.8809 0.68089E-14 -14.1669 0.51753E+00 -0.2861 107 SO3-2 0.26884E-17 -17.5705 0.14115E-17 -17.8503 0.52505E+00 -0.2798 109 HSO4- 0.80433E-19 -19.0946 0.67350E-19 -19.1717 0.83734E+00 -0.0771 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8871626E-10 -.2222141E-01 -.2235880E+02 0.0000 2 H2O 0.1000000E+01 0.5550496E+02 0.9981952E+06 0.0000 3 Cl- 0.2813564E-03 0.2826539E-03 0.1000346E+02 6.4986 4 SO4-- 0.1808198E-11 -.8441086E-04 -.8094506E+01 8.2276 5 HCO3- 0.1571948E-05 0.8605548E-04 0.5241710E+01 4.2464 6 HS- 0.7144385E-04 0.1558685E-03 0.5145896E+01 5.9034 7 Al+++ 0.9849515E-29 0.5294137E-05 0.1425947E+00 0.7390 8 H4SiO4 0.6959785E-03 0.1349039E-01 0.1294374E+04 -3.1574 9 Ca++ 0.1363743E-06 0.2346996E-06 0.9389893E-02 13.1018 10 Mg++ 0.2133516E-10 0.9379025E-10 0.2276253E-05 9.2942 11 Fe++ 0.5880331E-13 0.3614170E-07 0.2014887E-02 6.7350 12 K+ 0.1572656E-03 0.1580199E-03 0.6168124E+01 6.2467 13 Na+ 0.1995636E-01 0.2240334E-01 0.5141503E+03 8.3494 14 Mn++ 0.1886477E-10 0.2526910E-08 0.1385813E-03 9.2416 15 F- 0.5301671E-06 0.5318907E-06 0.1008724E-01 3.7729 16 HPO4-- 0.4497506E-07 0.4606897E-07 0.4413945E-02 12.6233 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279250E+02 -.1102943E-01 -.8278147E+02 0.0000000E+00 2 H2O -.7168453E+01 0.2754948E+02 -.3471793E+02 0.0000000E+00 3 Cl- 0.1402932E-03 0.1402932E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385945E+00 -.4189671E-04 0.1386364E+00 0.0000000E+00 5 HCO3- 0.4271300E-04 0.4271300E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385590E+00 0.7736418E-04 -.1386364E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627706E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6695858E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1164914E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4655210E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793867E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7843203E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111973E-01 0.6265257E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254213E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2640000E-06 0.2640000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2286599E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.3414E-14 Mass of aqueous solution: 0.497209E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0004100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5545 -0.256 281.8 2.450 5.159 73.22 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2619 -0.582 56.72 1.754 1.038 17.33 hedenbergite 0.6792E-01 -1.168 16.85 1.227 0.3085 4.616 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4274E-01 -1.369 36.53 1.563 0.6688 11.76 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337998 g Volume = 2210.778994 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0004100 moles log = -3.3872 Original solution: 1000.0103000 g Original solution / Rock added: 2439049.51 (Water/Rock Ratio), log = 6.3872 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1555 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8845E+00 0.9843 0.1006E+01 0.1022E+01 CO2,gas 0.1927E-07 1.0056 0.2239E-07 0.2227E-07 CH4,gas 0.1023E+00 1.0112 0.1196E+00 0.1182E+00 H2,gas 0.1315E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3284E-06 0.9955 0.3777E-06 0.3794E-06 S2,gas 0.2004E-28 1.0000 0.2316E-28 0.2316E-28 CO,gas 0.7854E-13 1.0000 0.9075E-13 0.9075E-13 SO3,gas 0.1704E-47 1.0000 0.1969E-47 0.1969E-47 SO2,gas 0.1008E-26 1.0000 0.1165E-26 0.1165E-26 HF,gas 0.4789E-15 1.0000 0.5533E-15 0.5533E-15 HCl,gas 0.4899E-17 1.0000 0.5660E-17 0.5660E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.23317E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.01 -9.35 -3.116 0.15963E+05 -7.650 3 CH4,gas 4.54 1.92 -2.62 -0.655 0.44760E+04 -0.922 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.35 -8.12 -4.061 0.13868E+05 -6.423 6 S2,gas -7.34 -37.67 -30.33 -4.667 0.51795E+05 -28.635 7 CO,gas 3.21 -11.53 -14.74 -4.536 0.25170E+05 -13.042 8 SO3,gas 17.12 -32.28 -49.40 -12.351 0.84357E+05 -47.706 9 SO2,gas 0.83 -27.80 -28.63 -7.635 0.48889E+05 -26.934 10 HF,gas 0.47 -16.48 -16.96 -8.478 0.28952E+05 -15.257 11 HCl,gas 5.19 -13.76 -18.95 -9.473 0.32350E+05 -17.247 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.64 -0.34 -0.028 0.57211E+03 38 aragonite 0.97 -2.91 -3.87 -1.291 0.66142E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.91 -3.72 -1.240 0.63500E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.04 -3.94 -1.126 0.67291E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.04 -3.50 -0.999 0.59713E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.62 -3.36 -1.119 0.57316E+04 147 pyrrhotiteFe0.875 -6.02 -9.01 -3.00 -1.103 0.51188E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.62 -3.21 -1.069 0.54744E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.11 -4.13 -1.378 0.70563E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0004100 MOLES New total amount of reactant added: 0.0004300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8659E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0004300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1139789E-01 Osmotic coef. = 0.9962 True ionic strength = .2011807E-01 Chg. balance for total moles = -.8659E-10 Max. difference allowed = 0.1404E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88720E-10 -10.0520 0.74524E-10 -10.1277 0.83999E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28159E-03 -3.5504 0.23511E-03 -3.6287 0.83492E+00 -0.0784 4 SO4-- 0.18329E-11 -11.7369 0.95061E-12 -12.0220 0.51863E+00 -0.2851 5 HCO3- 0.16251E-05 -5.7891 0.13588E-05 -5.8668 0.83614E+00 -0.0777 6 HS- 0.72423E-04 -4.1401 0.60476E-04 -4.2184 0.83504E+00 -0.0783 7 Al+++ 0.98509E-29 -29.0065 0.22691E-29 -29.6441 0.23035E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13639E-06 -6.8652 0.70213E-07 -7.1536 0.51481E+00 -0.2884 10 Mg++ 0.21337E-10 -10.6709 0.10934E-10 -10.9612 0.51245E+00 -0.2904 11 Fe++ 0.58808E-13 -13.2306 0.30169E-13 -13.5204 0.51301E+00 -0.2899 12 K+ 0.15727E-03 -3.8033 0.13153E-03 -3.8810 0.83634E+00 -0.0776 13 Na+ 0.19957E-01 -1.6999 0.16660E-01 -1.7783 0.83477E+00 -0.0784 14 Mn++ 0.18866E-10 -10.7243 0.96867E-11 -11.0138 0.51344E+00 -0.2895 15 F- 0.54623E-06 -6.2626 0.45512E-06 -6.3419 0.83319E+00 -0.0793 16 HPO4-- 0.44972E-07 -7.3471 0.23327E-07 -7.6321 0.51871E+00 -0.2851 18 HSiO3- 0.10444E-01 -1.9811 0.87202E-02 -2.0595 0.83492E+00 -0.0784 19 Ca(HSiO3)+ 0.16669E-07 -7.7781 0.13944E-07 -7.8556 0.83652E+00 -0.0775 20 Mg(HSiO3)+ 0.32305E-11 -11.4907 0.27024E-11 -11.5683 0.83652E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66445E-16 -16.1775 0.55583E-16 -16.2551 0.83652E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52938E-05 -5.2762 0.44119E-05 -5.3554 0.83341E+00 -0.0791 26 CH4,aq 0.84265E-04 -4.0744 0.83972E-04 -4.0759 0.99652E+00 -0.0015 27 C2H6,aq 0.10444E-12 -12.9811 0.10407E-12 -12.9827 0.99652E+00 -0.0015 31 CO,aq 0.62959E-16 -16.2009 0.62959E-16 -16.2009 0.10000E+01 0.0000 32 CO2,aq 0.21713E-09 -9.6633 0.21638E-09 -9.6648 0.99652E+00 -0.0015 33 CO3-2 0.30774E-05 -5.5118 0.15926E-05 -5.7979 0.51753E+00 -0.2861 34 CaCO3,aq 0.14021E-08 -8.8532 0.14021E-08 -8.8532 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.29113E-11 -11.5359 0.24354E-11 -11.6134 0.83652E+00 -0.0775 36 CaCl+ 0.31935E-10 -10.4957 0.26714E-10 -10.5733 0.83652E+00 -0.0775 37 CaCl2,aq 0.14922E-14 -14.8262 0.14922E-14 -14.8262 0.10000E+01 0.0000 38 CaF+ 0.55772E-12 -12.2536 0.46655E-12 -12.3311 0.83652E+00 -0.0775 39 CaOH+ 0.80269E-07 -7.0955 0.67147E-07 -7.1730 0.83652E+00 -0.0775 40 CaSO4,aq 0.21195E-16 -16.6738 0.21195E-16 -16.6738 0.10000E+01 0.0000 41 HCl,aq 0.32107E-14 -14.4934 0.32107E-14 -14.4934 0.10000E+01 0.0000 45 HF,aq 0.23219E-12 -12.6342 0.23219E-12 -12.6342 0.10000E+01 0.0000 46 HF2- 0.42732E-19 -19.3693 0.35677E-19 -19.4476 0.83492E+00 -0.0784 48 FeCl+ 0.13421E-16 -16.8722 0.11227E-16 -16.9497 0.83652E+00 -0.0775 51 FeF+ 0.83877E-18 -18.0764 0.70165E-18 -18.1539 0.83652E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15753E-10 -10.8026 0.13178E-10 -10.8802 0.83652E+00 -0.0775 55 HFeO2- 0.35503E-07 -7.4497 0.29642E-07 -7.5281 0.83492E+00 -0.0784 56 FeO+ 0.11040E-16 -16.9570 0.92355E-17 -17.0345 0.83652E+00 -0.0775 58 FeO2- 0.40754E-09 -9.3898 0.34027E-09 -9.4682 0.83492E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.56048E-09 -9.2514 0.56048E-09 -9.2514 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.23239E-14 -14.6338 0.19403E-14 -14.7121 0.83492E+00 -0.0784 65 MgCO3,aq 0.54731E-13 -13.2618 0.54731E-13 -13.2618 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.46326E-15 -15.3342 0.38753E-15 -15.4117 0.83652E+00 -0.0775 67 MgCl+ 0.45074E-14 -14.3461 0.37705E-14 -14.4236 0.83652E+00 -0.0775 68 MgF+ 0.32173E-15 -15.4925 0.26913E-15 -15.5700 0.83652E+00 -0.0775 69 MgOH+ 0.69169E-10 -10.1601 0.57862E-10 -10.2376 0.83652E+00 -0.0775 71 MnF+ 0.88768E-16 -16.0517 0.74257E-16 -16.1293 0.83652E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46986E-09 -9.3280 0.39305E-09 -9.4056 0.83652E+00 -0.0775 74 MnO2-2 0.20856E-10 -10.6808 0.10793E-10 -10.9668 0.51753E+00 -0.2861 75 HMnO2- 0.21107E-09 -9.6756 0.17622E-09 -9.7539 0.83492E+00 -0.0784 78 MnCl+ 0.16765E-13 -13.7756 0.14024E-13 -13.8531 0.83652E+00 -0.0775 80 NaCl,aq 0.12980E-05 -5.8867 0.12980E-05 -5.8867 0.10000E+01 0.0000 81 NaF,aq 0.17751E-08 -8.7508 0.17751E-08 -8.7508 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93026E-02 -2.0314 0.77529E-02 -2.1105 0.83341E+00 -0.0791 89 HPO3-2 0.16270E-14 -14.7886 0.84201E-15 -15.0747 0.51753E+00 -0.2861 91 H2PO3- 0.15071E-18 -18.8219 0.12583E-18 -18.9002 0.83492E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38374E-10 -10.4160 0.32070E-10 -10.4939 0.83571E+00 -0.0779 94 PO4-3 0.10554E-08 -8.9766 0.25539E-09 -9.5928 0.24198E+00 -0.6162 98 HP2O7-3 0.93708E-18 -18.0282 0.21607E-18 -18.6654 0.23058E+00 -0.6372 99 P2O7-4 0.90293E-17 -17.0443 0.69264E-18 -18.1595 0.76710E-01 -1.1151 100 H2S,aq 0.13978E-07 -7.8546 0.13929E-07 -7.8561 0.99652E+00 -0.0015 101 S2-2 0.13520E-13 -13.8690 0.69967E-14 -14.1551 0.51753E+00 -0.2861 107 SO3-2 0.27251E-17 -17.5646 0.14308E-17 -17.8444 0.52504E+00 -0.2798 109 HSO4- 0.81535E-19 -19.0887 0.68273E-19 -19.1658 0.83734E+00 -0.0771 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8871982E-10 -.2222083E-01 -.2235821E+02 0.0000 2 H2O 0.1000000E+01 0.5550496E+02 0.9981952E+06 0.0000 3 Cl- 0.2815928E-03 0.2828915E-03 0.1001186E+02 6.4990 4 SO4-- 0.1832922E-11 -.8717029E-04 -.8359119E+01 8.2334 5 HCO3- 0.1625113E-05 0.8896872E-04 0.5419158E+01 4.2609 6 HS- 0.7242277E-04 0.1596070E-03 0.5269321E+01 5.9093 7 Al+++ 0.9850886E-29 0.5293956E-05 0.1425898E+00 0.7390 8 H4SiO4 0.6959784E-03 0.1349004E-01 0.1294340E+04 -3.1574 9 Ca++ 0.1363862E-06 0.2347614E-06 0.9392364E-02 13.1018 10 Mg++ 0.2133701E-10 0.9379734E-10 0.2276425E-05 9.2942 11 Fe++ 0.5880842E-13 0.3614047E-07 0.2014818E-02 6.7350 12 K+ 0.1572720E-03 0.1580263E-03 0.6168370E+01 6.2467 13 Na+ 0.1995716E-01 0.2240414E-01 0.5141687E+03 8.3494 14 Mn++ 0.1886645E-10 0.2526927E-08 0.1385823E-03 9.2416 15 F- 0.5462323E-06 0.5480082E-06 0.1039291E-01 3.7858 16 HPO4-- 0.4497224E-07 0.4606605E-07 0.4413665E-02 12.6233 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279250E+02 -.1102915E-01 -.8278147E+02 0.0000000E+00 2 H2O -.7168437E+01 0.2754950E+02 -.3471793E+02 0.0000000E+00 3 Cl- 0.1404112E-03 0.1404112E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385946E+00 -.4326636E-04 0.1386378E+00 0.0000000E+00 5 HCO3- 0.4415900E-04 0.4415900E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385586E+00 0.7921983E-04 -.1386378E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627618E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6695685E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1165222E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4655565E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793807E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7843523E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112014E-01 0.6265257E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254222E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2720000E-06 0.2720000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2286456E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1364E-13 Mass of aqueous solution: 0.497210E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0004300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.159 73.22 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2619 -0.582 56.71 1.754 1.038 17.33 hedenbergite 0.6791E-01 -1.168 16.85 1.227 0.3085 4.615 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4275E-01 -1.369 36.54 1.563 0.6690 11.76 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338004 g Volume = 2210.779049 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0004300 moles log = -3.3665 Original solution: 1000.0103000 g Original solution / Rock added: 2325605.35 (Water/Rock Ratio), log = 6.3665 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1595 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8815E+00 0.9842 0.1006E+01 0.1022E+01 CO2,gas 0.1985E-07 1.0056 0.2315E-07 0.2302E-07 CH4,gas 0.1054E+00 1.0112 0.1236E+00 0.1222E+00 H2,gas 0.1311E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3317E-06 0.9955 0.3829E-06 0.3846E-06 S2,gas 0.2053E-28 1.0000 0.2380E-28 0.2380E-28 CO,gas 0.8091E-13 1.0000 0.9382E-13 0.9382E-13 SO3,gas 0.1722E-47 1.0000 0.1996E-47 0.1996E-47 SO2,gas 0.1018E-26 1.0000 0.1181E-26 0.1181E-26 HF,gas 0.4917E-15 1.0000 0.5701E-15 0.5701E-15 HCl,gas 0.4886E-17 1.0000 0.5665E-17 0.5665E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.99 -9.33 -3.111 0.15938E+05 -7.635 3 CH4,gas 4.54 1.94 -2.61 -0.652 0.44513E+04 -0.908 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.35 -8.12 -4.058 0.13858E+05 -6.417 6 S2,gas -7.34 -37.66 -30.32 -4.665 0.51775E+05 -28.623 7 CO,gas 3.21 -11.51 -14.73 -4.531 0.25145E+05 -13.028 8 SO3,gas 17.12 -32.28 -49.40 -12.350 0.84347E+05 -47.700 9 SO2,gas 0.83 -27.79 -28.63 -7.634 0.48879E+05 -26.928 10 HF,gas 0.47 -16.47 -16.94 -8.472 0.28930E+05 -15.244 11 HCl,gas 5.19 -13.76 -18.95 -9.473 0.32349E+05 -17.247 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.62 -0.32 -0.027 0.54995E+03 38 aragonite 0.97 -2.89 -3.86 -1.286 0.65895E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.89 -3.70 -1.235 0.63253E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.03 -3.93 -1.122 0.67044E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.03 -3.48 -0.995 0.59467E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.61 -3.35 -1.117 0.57214E+04 147 pyrrhotiteFe0.875 -6.02 -9.01 -2.99 -1.100 0.51087E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.61 -3.20 -1.067 0.54642E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.10 -4.13 -1.376 0.70462E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0004300 MOLES New total amount of reactant added: 0.0004500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8658E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0004500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1139623E-01 Osmotic coef. = 0.9982 True ionic strength = .2011898E-01 Chg. balance for total moles = -.8658E-10 Max. difference allowed = 0.1405E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88723E-10 -10.0520 0.74527E-10 -10.1277 0.83999E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28183E-03 -3.5500 0.23530E-03 -3.6284 0.83492E+00 -0.0784 4 SO4-- 0.18576E-11 -11.7310 0.96342E-12 -12.0162 0.51863E+00 -0.2851 5 HCO3- 0.16783E-05 -5.7751 0.14033E-05 -5.8529 0.83614E+00 -0.0777 6 HS- 0.73402E-04 -4.1343 0.61293E-04 -4.2126 0.83504E+00 -0.0783 7 Al+++ 0.98523E-29 -29.0065 0.22694E-29 -29.6441 0.23034E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13640E-06 -6.8652 0.70218E-07 -7.1535 0.51480E+00 -0.2884 10 Mg++ 0.21339E-10 -10.6708 0.10935E-10 -10.9612 0.51244E+00 -0.2904 11 Fe++ 0.58814E-13 -13.2305 0.30172E-13 -13.5204 0.51300E+00 -0.2899 12 K+ 0.15728E-03 -3.8033 0.13154E-03 -3.8809 0.83634E+00 -0.0776 13 Na+ 0.19958E-01 -1.6999 0.16660E-01 -1.7783 0.83476E+00 -0.0784 14 Mn++ 0.18868E-10 -10.7243 0.96875E-11 -11.0138 0.51343E+00 -0.2895 15 F- 0.56230E-06 -6.2500 0.46850E-06 -6.3293 0.83319E+00 -0.0793 16 HPO4-- 0.44969E-07 -7.3471 0.23326E-07 -7.6322 0.51870E+00 -0.2851 18 HSiO3- 0.10444E-01 -1.9811 0.87199E-02 -2.0595 0.83492E+00 -0.0784 19 Ca(HSiO3)+ 0.16669E-07 -7.7781 0.13944E-07 -7.8556 0.83652E+00 -0.0775 20 Mg(HSiO3)+ 0.32306E-11 -11.4907 0.27025E-11 -11.5682 0.83652E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66448E-16 -16.1775 0.55585E-16 -16.2550 0.83652E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52936E-05 -5.2762 0.44117E-05 -5.3554 0.83340E+00 -0.0791 26 CH4,aq 0.87024E-04 -4.0604 0.86722E-04 -4.0619 0.99652E+00 -0.0015 27 C2H6,aq 0.11139E-12 -12.9532 0.11100E-12 -12.9547 0.99652E+00 -0.0015 31 CO,aq 0.65020E-16 -16.1870 0.65020E-16 -16.1870 0.10000E+01 0.0000 32 CO2,aq 0.22425E-09 -9.6493 0.22347E-09 -9.6508 0.99652E+00 -0.0015 33 CO3-2 0.31780E-05 -5.4979 0.16447E-05 -5.7839 0.51752E+00 -0.2861 34 CaCO3,aq 0.14481E-08 -8.8392 0.14481E-08 -8.8392 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.30068E-11 -11.5219 0.25152E-11 -11.5994 0.83652E+00 -0.0775 36 CaCl+ 0.31964E-10 -10.4953 0.26739E-10 -10.5729 0.83652E+00 -0.0775 37 CaCl2,aq 0.14948E-14 -14.8254 0.14948E-14 -14.8254 0.10000E+01 0.0000 38 CaF+ 0.57417E-12 -12.2410 0.48030E-12 -12.3185 0.83652E+00 -0.0775 39 CaOH+ 0.80272E-07 -7.0954 0.67149E-07 -7.1730 0.83652E+00 -0.0775 40 CaSO4,aq 0.21482E-16 -16.6679 0.21482E-16 -16.6679 0.10000E+01 0.0000 41 HCl,aq 0.32135E-14 -14.4930 0.32135E-14 -14.4930 0.10000E+01 0.0000 45 HF,aq 0.23902E-12 -12.6216 0.23902E-12 -12.6216 0.10000E+01 0.0000 46 HF2- 0.45284E-19 -19.3441 0.37808E-19 -19.4224 0.83492E+00 -0.0784 48 FeCl+ 0.13433E-16 -16.8718 0.11237E-16 -16.9493 0.83652E+00 -0.0775 51 FeF+ 0.86351E-18 -18.0637 0.72234E-18 -18.1413 0.83652E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15753E-10 -10.8026 0.13178E-10 -10.8801 0.83652E+00 -0.0775 55 HFeO2- 0.35502E-07 -7.4498 0.29641E-07 -7.5281 0.83492E+00 -0.0784 56 FeO+ 0.11041E-16 -16.9570 0.92358E-17 -17.0345 0.83652E+00 -0.0775 58 FeO2- 0.40753E-09 -9.3898 0.34025E-09 -9.4682 0.83492E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 61 KCl,aq 0.56097E-09 -9.2511 0.56097E-09 -9.2511 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.23553E-14 -14.6279 0.19665E-14 -14.7063 0.83492E+00 -0.0784 65 MgCO3,aq 0.56524E-13 -13.2478 0.56524E-13 -13.2478 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.47845E-15 -15.3202 0.40023E-15 -15.3977 0.83652E+00 -0.0775 67 MgCl+ 0.45115E-14 -14.3457 0.37740E-14 -14.4232 0.83652E+00 -0.0775 68 MgF+ 0.33122E-15 -15.4799 0.27707E-15 -15.5574 0.83652E+00 -0.0775 69 MgOH+ 0.69172E-10 -10.1601 0.57864E-10 -10.2376 0.83652E+00 -0.0775 71 MnF+ 0.91386E-16 -16.0391 0.76446E-16 -16.1166 0.83652E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46988E-09 -9.3280 0.39306E-09 -9.4055 0.83652E+00 -0.0775 74 MnO2-2 0.20855E-10 -10.6808 0.10793E-10 -10.9669 0.51752E+00 -0.2861 75 HMnO2- 0.21106E-09 -9.6756 0.17622E-09 -9.7539 0.83492E+00 -0.0784 78 MnCl+ 0.16780E-13 -13.7752 0.14037E-13 -13.8527 0.83652E+00 -0.0775 80 NaCl,aq 0.12992E-05 -5.8863 0.12992E-05 -5.8863 0.10000E+01 0.0000 81 NaF,aq 0.18274E-08 -8.7382 0.18274E-08 -8.7382 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93023E-02 -2.0314 0.77526E-02 -2.1106 0.83340E+00 -0.0791 89 HPO3-2 0.16269E-14 -14.7886 0.84194E-15 -15.0747 0.51752E+00 -0.2861 91 H2PO3- 0.15071E-18 -18.8219 0.12583E-18 -18.9002 0.83492E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38373E-10 -10.4160 0.32068E-10 -10.4939 0.83571E+00 -0.0779 94 PO4-3 0.10553E-08 -8.9766 0.25536E-09 -9.5928 0.24197E+00 -0.6162 98 HP2O7-3 0.93700E-18 -18.0283 0.21604E-18 -18.6655 0.23057E+00 -0.6372 99 P2O7-4 0.90284E-17 -17.0444 0.69254E-18 -18.1596 0.76707E-01 -1.1152 100 H2S,aq 0.14167E-07 -7.8487 0.14118E-07 -7.8502 0.99652E+00 -0.0015 101 S2-2 0.13888E-13 -13.8574 0.71871E-14 -14.1434 0.51752E+00 -0.2861 107 SO3-2 0.27619E-17 -17.5588 0.14501E-17 -17.8386 0.52504E+00 -0.2798 109 HSO4- 0.82637E-19 -19.0828 0.69195E-19 -19.1599 0.83734E+00 -0.0771 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8872339E-10 -.2222025E-01 -.2235763E+02 0.0000 2 H2O 0.1000000E+01 0.5550497E+02 0.9981951E+06 0.0000 3 Cl- 0.2818292E-03 0.2831290E-03 0.1002027E+02 6.4993 4 SO4-- 0.1857644E-11 -.8992974E-04 -.8623733E+01 8.2392 5 HCO3- 0.1678275E-05 0.9188197E-04 0.5596605E+01 4.2748 6 HS- 0.7340169E-04 0.1633456E-03 0.5392747E+01 5.9151 7 Al+++ 0.9852257E-29 0.5293775E-05 0.1425850E+00 0.7390 8 H4SiO4 0.6959784E-03 0.1348968E-01 0.1294305E+04 -3.1574 9 Ca++ 0.1363980E-06 0.2348232E-06 0.9394836E-02 13.1018 10 Mg++ 0.2133887E-10 0.9380443E-10 0.2276597E-05 9.2942 11 Fe++ 0.5881354E-13 0.3613924E-07 0.2014749E-02 6.7350 12 K+ 0.1572783E-03 0.1580326E-03 0.6168616E+01 6.2467 13 Na+ 0.1995797E-01 0.2240495E-01 0.5141871E+03 8.3494 14 Mn++ 0.1886812E-10 0.2526944E-08 0.1385832E-03 9.2416 15 F- 0.5622975E-06 0.5641257E-06 0.1069857E-01 3.7984 16 HPO4-- 0.4496942E-07 0.4606314E-07 0.4413385E-02 12.6232 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279250E+02 -.1102887E-01 -.8278147E+02 0.0000000E+00 2 H2O -.7168420E+01 0.2754952E+02 -.3471794E+02 0.0000000E+00 3 Cl- 0.1405292E-03 0.1405292E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385947E+00 -.4463603E-04 0.1386393E+00 0.0000000E+00 5 HCO3- 0.4560500E-04 0.4560500E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385582E+00 0.8107550E-04 -.1386393E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627530E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6695512E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1165529E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4655920E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793747E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7843842E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112055E-01 0.6265256E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254232E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2800000E-06 0.2800000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2286313E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.3636E-14 Mass of aqueous solution: 0.497210E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0004500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.159 73.22 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2618 -0.582 56.70 1.754 1.038 17.33 hedenbergite 0.6790E-01 -1.168 16.85 1.227 0.3084 4.614 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.30 tr.625ac.25prg.125 0.4276E-01 -1.369 36.55 1.563 0.6691 11.76 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338011 g Volume = 2210.779104 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0004500 moles log = -3.3468 Original solution: 1000.0103000 g Original solution / Rock added: 2222245.11 (Water/Rock Ratio), log = 6.3468 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1636 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8784E+00 0.9842 0.1006E+01 0.1022E+01 CO2,gas 0.2043E-07 1.0055 0.2391E-07 0.2378E-07 CH4,gas 0.1085E+00 1.0112 0.1276E+00 0.1262E+00 H2,gas 0.1306E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3350E-06 0.9955 0.3881E-06 0.3899E-06 S2,gas 0.2101E-28 1.0000 0.2445E-28 0.2445E-28 CO,gas 0.8327E-13 1.0000 0.9689E-13 0.9689E-13 SO3,gas 0.1739E-47 1.0000 0.2023E-47 0.2023E-47 SO2,gas 0.1029E-26 1.0000 0.1197E-26 0.1197E-26 HF,gas 0.5044E-15 1.0000 0.5869E-15 0.5869E-15 HCl,gas 0.4873E-17 1.0000 0.5670E-17 0.5670E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.36397E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.98 -9.32 -3.107 0.15914E+05 -7.621 3 CH4,gas 4.54 1.95 -2.59 -0.648 0.44274E+04 -0.894 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.34 -8.11 -4.055 0.13848E+05 -6.411 6 S2,gas -7.34 -37.65 -30.31 -4.663 0.51755E+05 -28.612 7 CO,gas 3.21 -11.50 -14.71 -4.527 0.25121E+05 -13.014 8 SO3,gas 17.12 -32.27 -49.39 -12.348 0.84337E+05 -47.694 9 SO2,gas 0.83 -27.79 -28.62 -7.632 0.48869E+05 -26.922 10 HF,gas 0.47 -16.46 -16.93 -8.465 0.28908E+05 -15.231 11 HCl,gas 5.19 -13.76 -18.95 -9.473 0.32349E+05 -17.246 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.61 -0.31 -0.026 0.52843E+03 38 aragonite 0.97 -2.88 -3.85 -1.282 0.65656E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.88 -3.69 -1.230 0.63014E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.01 -3.91 -1.118 0.66805E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.01 -3.47 -0.991 0.59228E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.61 -3.34 -1.115 0.57115E+04 147 pyrrhotiteFe0.875 -6.02 -9.00 -2.99 -1.098 0.50987E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.61 -3.19 -1.065 0.54543E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.10 -4.12 -1.374 0.70362E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0004500 MOLES New total amount of reactant added: 0.0004700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8658E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0004700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1139456E-01 Osmotic coef. = 1.0004 True ionic strength = .2011989E-01 Chg. balance for total moles = -.8658E-10 Max. difference allowed = 0.1406E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88727E-10 -10.0519 0.74529E-10 -10.1277 0.83998E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28207E-03 -3.5496 0.23550E-03 -3.6280 0.83491E+00 -0.0784 4 SO4-- 0.18824E-11 -11.7253 0.97623E-12 -12.0104 0.51862E+00 -0.2852 5 HCO3- 0.17314E-05 -5.7616 0.14477E-05 -5.8393 0.83614E+00 -0.0777 6 HS- 0.74381E-04 -4.1285 0.62111E-04 -4.2068 0.83504E+00 -0.0783 7 Al+++ 0.98536E-29 -29.0064 0.22696E-29 -29.6440 0.23033E+00 -0.6376 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13641E-06 -6.8652 0.70224E-07 -7.1535 0.51480E+00 -0.2884 10 Mg++ 0.21341E-10 -10.6708 0.10936E-10 -10.9612 0.51243E+00 -0.2904 11 Fe++ 0.58819E-13 -13.2305 0.30174E-13 -13.5204 0.51300E+00 -0.2899 12 K+ 0.15728E-03 -3.8033 0.13154E-03 -3.8809 0.83634E+00 -0.0776 13 Na+ 0.19959E-01 -1.6999 0.16661E-01 -1.7783 0.83476E+00 -0.0784 14 Mn++ 0.18870E-10 -10.7242 0.96882E-11 -11.0138 0.51342E+00 -0.2895 15 F- 0.57836E-06 -6.2378 0.48188E-06 -6.3171 0.83319E+00 -0.0793 16 HPO4-- 0.44967E-07 -7.3471 0.23324E-07 -7.6322 0.51869E+00 -0.2851 18 HSiO3- 0.10444E-01 -1.9811 0.87196E-02 -2.0595 0.83491E+00 -0.0784 19 Ca(HSiO3)+ 0.16670E-07 -7.7781 0.13945E-07 -7.8556 0.83652E+00 -0.0775 20 Mg(HSiO3)+ 0.32307E-11 -11.4907 0.27026E-11 -11.5682 0.83652E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66451E-16 -16.1775 0.55587E-16 -16.2550 0.83652E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52934E-05 -5.2763 0.44116E-05 -5.3554 0.83340E+00 -0.0791 26 CH4,aq 0.89784E-04 -4.0468 0.89472E-04 -4.0483 0.99653E+00 -0.0015 27 C2H6,aq 0.11857E-12 -12.9260 0.11815E-12 -12.9276 0.99653E+00 -0.0015 31 CO,aq 0.67082E-16 -16.1734 0.67082E-16 -16.1734 0.10000E+01 0.0000 32 CO2,aq 0.23136E-09 -9.6357 0.23055E-09 -9.6372 0.99653E+00 -0.0015 33 CO3-2 0.32785E-05 -5.4843 0.16967E-05 -5.7704 0.51752E+00 -0.2861 34 CaCO3,aq 0.14940E-08 -8.8257 0.14940E-08 -8.8257 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.31022E-11 -11.5083 0.25951E-11 -11.5858 0.83652E+00 -0.0775 36 CaCl+ 0.31993E-10 -10.4949 0.26763E-10 -10.5725 0.83652E+00 -0.0775 37 CaCl2,aq 0.14974E-14 -14.8247 0.14974E-14 -14.8247 0.10000E+01 0.0000 38 CaF+ 0.59062E-12 -12.2287 0.49406E-12 -12.3062 0.83652E+00 -0.0775 39 CaOH+ 0.80275E-07 -7.0954 0.67152E-07 -7.1729 0.83652E+00 -0.0775 40 CaSO4,aq 0.21769E-16 -16.6622 0.21769E-16 -16.6622 0.10000E+01 0.0000 41 HCl,aq 0.32163E-14 -14.4926 0.32163E-14 -14.4926 0.10000E+01 0.0000 45 HF,aq 0.24586E-12 -12.6093 0.24586E-12 -12.6093 0.10000E+01 0.0000 46 HF2- 0.47910E-19 -19.3196 0.40000E-19 -19.3979 0.83491E+00 -0.0784 48 FeCl+ 0.13446E-16 -16.8714 0.11248E-16 -16.9489 0.83652E+00 -0.0775 51 FeF+ 0.88824E-18 -18.0515 0.74303E-18 -18.1290 0.83652E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15754E-10 -10.8026 0.13179E-10 -10.8801 0.83652E+00 -0.0775 55 HFeO2- 0.35500E-07 -7.4498 0.29640E-07 -7.5281 0.83491E+00 -0.0784 56 FeO+ 0.11041E-16 -16.9570 0.92362E-17 -17.0345 0.83652E+00 -0.0775 58 FeO2- 0.40752E-09 -9.3899 0.34024E-09 -9.4682 0.83491E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56146E-09 -9.2507 0.56146E-09 -9.2507 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.23867E-14 -14.6222 0.19927E-14 -14.7006 0.83491E+00 -0.0784 65 MgCO3,aq 0.58316E-13 -13.2342 0.58316E-13 -13.2342 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.49364E-15 -15.3066 0.41294E-15 -15.3841 0.83652E+00 -0.0775 67 MgCl+ 0.45156E-14 -14.3453 0.37774E-14 -14.4228 0.83652E+00 -0.0775 68 MgF+ 0.34070E-15 -15.4676 0.28501E-15 -15.5451 0.83652E+00 -0.0775 69 MgOH+ 0.69175E-10 -10.1601 0.57866E-10 -10.2376 0.83652E+00 -0.0775 71 MnF+ 0.94004E-16 -16.0269 0.78636E-16 -16.1044 0.83652E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46990E-09 -9.3280 0.39308E-09 -9.4055 0.83652E+00 -0.0775 74 MnO2-2 0.20853E-10 -10.6808 0.10792E-10 -10.9669 0.51752E+00 -0.2861 75 HMnO2- 0.21105E-09 -9.6756 0.17621E-09 -9.7540 0.83491E+00 -0.0784 78 MnCl+ 0.16796E-13 -13.7748 0.14050E-13 -13.8523 0.83652E+00 -0.0775 80 NaCl,aq 0.13003E-05 -5.8860 0.13003E-05 -5.8860 0.10000E+01 0.0000 81 NaF,aq 0.18796E-08 -8.7259 0.18796E-08 -8.7259 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93020E-02 -2.0314 0.77523E-02 -2.1106 0.83340E+00 -0.0791 89 HPO3-2 0.16268E-14 -14.7887 0.84188E-15 -15.0747 0.51752E+00 -0.2861 91 H2PO3- 0.15070E-18 -18.8219 0.12582E-18 -18.9002 0.83491E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38371E-10 -10.4160 0.32067E-10 -10.4939 0.83571E+00 -0.0779 94 PO4-3 0.10553E-08 -8.9766 0.25533E-09 -9.5929 0.24196E+00 -0.6162 98 HP2O7-3 0.93692E-18 -18.0283 0.21602E-18 -18.6655 0.23056E+00 -0.6372 99 P2O7-4 0.90275E-17 -17.0444 0.69243E-18 -18.1596 0.76703E-01 -1.1152 100 H2S,aq 0.14357E-07 -7.8430 0.14307E-07 -7.8445 0.99653E+00 -0.0015 101 S2-2 0.14261E-13 -13.8459 0.73800E-14 -14.1319 0.51752E+00 -0.2861 107 SO3-2 0.27986E-17 -17.5531 0.14694E-17 -17.8329 0.52503E+00 -0.2798 109 HSO4- 0.83739E-19 -19.0771 0.70118E-19 -19.1542 0.83734E+00 -0.0771 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8872695E-10 -.2221968E-01 -.2235705E+02 0.0000 2 H2O 0.1000000E+01 0.5550497E+02 0.9981951E+06 0.0000 3 Cl- 0.2820656E-03 0.2833665E-03 0.1002868E+02 6.4997 4 SO4-- 0.1882364E-11 -.9268920E-04 -.8888347E+01 8.2449 5 HCO3- 0.1731433E-05 0.9479520E-04 0.5774052E+01 4.2884 6 HS- 0.7438060E-04 0.1670842E-03 0.5516172E+01 5.9208 7 Al+++ 0.9853628E-29 0.5293595E-05 0.1425801E+00 0.7390 8 H4SiO4 0.6959784E-03 0.1348932E-01 0.1294271E+04 -3.1574 9 Ca++ 0.1364098E-06 0.2348850E-06 0.9397307E-02 13.1018 10 Mg++ 0.2134072E-10 0.9381062E-10 0.2276747E-05 9.2942 11 Fe++ 0.5881865E-13 0.3613801E-07 0.2014680E-02 6.7350 12 K+ 0.1572846E-03 0.1580389E-03 0.6168862E+01 6.2467 13 Na+ 0.1995877E-01 0.2240575E-01 0.5142056E+03 8.3494 14 Mn++ 0.1886980E-10 0.2526961E-08 0.1385841E-03 9.2416 15 F- 0.5783626E-06 0.5802431E-06 0.1100424E-01 3.8106 16 HPO4-- 0.4496660E-07 0.4606022E-07 0.4413106E-02 12.6231 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279250E+02 -.1102860E-01 -.8278147E+02 0.0000000E+00 2 H2O -.7168404E+01 0.2754954E+02 -.3471794E+02 0.0000000E+00 3 Cl- 0.1406472E-03 0.1406472E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385948E+00 -.4600570E-04 0.1386408E+00 0.0000000E+00 5 HCO3- 0.4705100E-04 0.4705100E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385578E+00 0.8293117E-04 -.1386408E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627442E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6695339E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1165837E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4656231E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793687E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7844162E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112095E-01 0.6265256E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254241E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2880000E-06 0.2880000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2286170E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.9145E-14 Mass of aqueous solution: 0.497211E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0004700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.159 73.22 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2618 -0.582 56.69 1.754 1.038 17.33 hedenbergite 0.6789E-01 -1.168 16.84 1.226 0.3084 4.614 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.157 97.29 tr.625ac.25prg.125 0.4277E-01 -1.369 36.56 1.563 0.6693 11.77 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338017 g Volume = 2210.779160 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0004700 moles log = -3.3279 Original solution: 1000.0103000 g Original solution / Rock added: 2127681.49 (Water/Rock Ratio), log = 6.3279 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1676 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8754E+00 0.9841 0.1006E+01 0.1022E+01 CO2,gas 0.2101E-07 1.0055 0.2467E-07 0.2453E-07 CH4,gas 0.1115E+00 1.0111 0.1317E+00 0.1302E+00 H2,gas 0.1302E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3384E-06 0.9955 0.3933E-06 0.3951E-06 S2,gas 0.2150E-28 1.0000 0.2511E-28 0.2511E-28 CO,gas 0.8561E-13 1.0000 0.9997E-13 0.9997E-13 SO3,gas 0.1756E-47 1.0000 0.2050E-47 0.2050E-47 SO2,gas 0.1039E-26 1.0000 0.1213E-26 0.1213E-26 HF,gas 0.5170E-15 1.0000 0.6037E-15 0.6037E-15 HCl,gas 0.4860E-17 1.0000 0.5675E-17 0.5675E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.84926E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.97 -9.31 -3.102 0.15891E+05 -7.608 3 CH4,gas 4.54 1.96 -2.58 -0.645 0.44043E+04 -0.880 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.33 -8.10 -4.052 0.13838E+05 -6.405 6 S2,gas -7.34 -37.63 -30.30 -4.661 0.51735E+05 -28.600 7 CO,gas 3.21 -11.48 -14.70 -4.523 0.25098E+05 -13.000 8 SO3,gas 17.12 -32.27 -49.39 -12.347 0.84327E+05 -47.688 9 SO2,gas 0.83 -27.78 -28.62 -7.631 0.48860E+05 -26.916 10 HF,gas 0.47 -16.44 -16.92 -8.459 0.28887E+05 -15.219 11 HCl,gas 5.19 -13.76 -18.94 -9.472 0.32348E+05 -17.246 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.60 -0.30 -0.025 0.50752E+03 38 aragonite 0.97 -2.87 -3.83 -1.277 0.65425E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.87 -3.68 -1.226 0.62783E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -7.00 -3.90 -1.114 0.66574E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -7.00 -3.46 -0.987 0.58996E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.60 -3.34 -1.113 0.57016E+04 147 pyrrhotiteFe0.875 -6.02 -9.00 -2.98 -1.096 0.50888E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.60 -3.19 -1.063 0.54444E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.09 -4.12 -1.372 0.70263E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0004700 MOLES New total amount of reactant added: 0.0004900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8658E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0004900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1139290E-01 Osmotic coef. = 1.0027 True ionic strength = .2012080E-01 Chg. balance for total moles = -.8658E-10 Max. difference allowed = 0.1408E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88731E-10 -10.0519 0.74532E-10 -10.1277 0.83998E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28230E-03 -3.5493 0.23570E-03 -3.6276 0.83491E+00 -0.0784 4 SO4-- 0.19071E-11 -11.7196 0.98904E-12 -12.0048 0.51861E+00 -0.2852 5 HCO3- 0.17846E-05 -5.7485 0.14922E-05 -5.8262 0.83614E+00 -0.0777 6 HS- 0.75360E-04 -4.1229 0.62928E-04 -4.2012 0.83503E+00 -0.0783 7 Al+++ 0.98550E-29 -29.0063 0.22699E-29 -29.6440 0.23033E+00 -0.6377 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13642E-06 -6.8651 0.70229E-07 -7.1535 0.51479E+00 -0.2884 10 Mg++ 0.21343E-10 -10.6708 0.10937E-10 -10.9611 0.51243E+00 -0.2904 11 Fe++ 0.58824E-13 -13.2304 0.30176E-13 -13.5203 0.51299E+00 -0.2899 12 K+ 0.15729E-03 -3.8033 0.13155E-03 -3.8809 0.83634E+00 -0.0776 13 Na+ 0.19960E-01 -1.6998 0.16661E-01 -1.7783 0.83476E+00 -0.0784 14 Mn++ 0.18871E-10 -10.7242 0.96890E-11 -11.0137 0.51342E+00 -0.2895 15 F- 0.59443E-06 -6.2259 0.49527E-06 -6.3052 0.83318E+00 -0.0793 16 HPO4-- 0.44964E-07 -7.3471 0.23322E-07 -7.6322 0.51869E+00 -0.2851 18 HSiO3- 0.10443E-01 -1.9812 0.87193E-02 -2.0595 0.83491E+00 -0.0784 19 Ca(HSiO3)+ 0.16671E-07 -7.7780 0.13945E-07 -7.8556 0.83652E+00 -0.0775 20 Mg(HSiO3)+ 0.32309E-11 -11.4907 0.27027E-11 -11.5682 0.83652E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66453E-16 -16.1775 0.55589E-16 -16.2550 0.83652E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52933E-05 -5.2763 0.44114E-05 -5.3554 0.83340E+00 -0.0791 26 CH4,aq 0.92543E-04 -4.0337 0.92221E-04 -4.0352 0.99653E+00 -0.0015 27 C2H6,aq 0.12597E-12 -12.8997 0.12553E-12 -12.9013 0.99653E+00 -0.0015 31 CO,aq 0.69144E-16 -16.1602 0.69144E-16 -16.1602 0.10000E+01 0.0000 32 CO2,aq 0.23847E-09 -9.6226 0.23764E-09 -9.6241 0.99653E+00 -0.0015 33 CO3-2 0.33791E-05 -5.4712 0.17487E-05 -5.7573 0.51751E+00 -0.2861 34 CaCO3,aq 0.15399E-08 -8.8125 0.15399E-08 -8.8125 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.31977E-11 -11.4952 0.26749E-11 -11.5727 0.83652E+00 -0.0775 36 CaCl+ 0.32023E-10 -10.4945 0.26788E-10 -10.5721 0.83652E+00 -0.0775 37 CaCl2,aq 0.15000E-14 -14.8239 0.15000E-14 -14.8239 0.10000E+01 0.0000 38 CaF+ 0.60707E-12 -12.2168 0.50782E-12 -12.2943 0.83652E+00 -0.0775 39 CaOH+ 0.80279E-07 -7.0954 0.67154E-07 -7.1729 0.83652E+00 -0.0775 40 CaSO4,aq 0.22057E-16 -16.6565 0.22057E-16 -16.6565 0.10000E+01 0.0000 41 HCl,aq 0.32191E-14 -14.4923 0.32191E-14 -14.4923 0.10000E+01 0.0000 45 HF,aq 0.25270E-12 -12.5974 0.25270E-12 -12.5974 0.10000E+01 0.0000 46 HF2- 0.50610E-19 -19.2958 0.42255E-19 -19.3741 0.83491E+00 -0.0784 48 FeCl+ 0.13458E-16 -16.8710 0.11258E-16 -16.9485 0.83652E+00 -0.0775 51 FeF+ 0.91298E-18 -18.0395 0.76373E-18 -18.1171 0.83652E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15755E-10 -10.8026 0.13179E-10 -10.8801 0.83652E+00 -0.0775 55 HFeO2- 0.35499E-07 -7.4498 0.29639E-07 -7.5281 0.83491E+00 -0.0784 56 FeO+ 0.11042E-16 -16.9570 0.92365E-17 -17.0345 0.83652E+00 -0.0775 58 FeO2- 0.40750E-09 -9.3899 0.34023E-09 -9.4682 0.83491E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56195E-09 -9.2503 0.56195E-09 -9.2503 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.24181E-14 -14.6165 0.20189E-14 -14.6949 0.83491E+00 -0.0784 65 MgCO3,aq 0.60108E-13 -13.2211 0.60108E-13 -13.2211 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.50883E-15 -15.2934 0.42565E-15 -15.3709 0.83652E+00 -0.0775 67 MgCl+ 0.45198E-14 -14.3449 0.37809E-14 -14.4224 0.83652E+00 -0.0775 68 MgF+ 0.35019E-15 -15.4557 0.29294E-15 -15.5332 0.83652E+00 -0.0775 69 MgOH+ 0.69177E-10 -10.1600 0.57868E-10 -10.2376 0.83652E+00 -0.0775 71 MnF+ 0.96622E-16 -16.0149 0.80826E-16 -16.0924 0.83652E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46992E-09 -9.3280 0.39310E-09 -9.4055 0.83652E+00 -0.0775 74 MnO2-2 0.20852E-10 -10.6809 0.10791E-10 -10.9669 0.51751E+00 -0.2861 75 HMnO2- 0.21105E-09 -9.6756 0.17621E-09 -9.7540 0.83491E+00 -0.0784 78 MnCl+ 0.16811E-13 -13.7744 0.14063E-13 -13.8519 0.83652E+00 -0.0775 80 NaCl,aq 0.13014E-05 -5.8856 0.13014E-05 -5.8856 0.10000E+01 0.0000 81 NaF,aq 0.19319E-08 -8.7140 0.19319E-08 -8.7140 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93017E-02 -2.0314 0.77520E-02 -2.1106 0.83340E+00 -0.0791 89 HPO3-2 0.16267E-14 -14.7887 0.84182E-15 -15.0748 0.51751E+00 -0.2861 91 H2PO3- 0.15070E-18 -18.8219 0.12582E-18 -18.9003 0.83491E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38370E-10 -10.4160 0.32066E-10 -10.4940 0.83571E+00 -0.0779 94 PO4-3 0.10552E-08 -8.9767 0.25530E-09 -9.5929 0.24196E+00 -0.6163 98 HP2O7-3 0.93684E-18 -18.0283 0.21600E-18 -18.6656 0.23056E+00 -0.6372 99 P2O7-4 0.90265E-17 -17.0445 0.69233E-18 -18.1597 0.76699E-01 -1.1152 100 H2S,aq 0.14546E-07 -7.8373 0.14495E-07 -7.8388 0.99653E+00 -0.0015 101 S2-2 0.14638E-13 -13.8345 0.75755E-14 -14.1206 0.51751E+00 -0.2861 107 SO3-2 0.28354E-17 -17.5474 0.14887E-17 -17.8272 0.52502E+00 -0.2798 109 HSO4- 0.84841E-19 -19.0714 0.71041E-19 -19.1485 0.83733E+00 -0.0771 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8873052E-10 -.2221910E-01 -.2235647E+02 0.0000 2 H2O 0.1000000E+01 0.5550497E+02 0.9981951E+06 0.0000 3 Cl- 0.2823020E-03 0.2836040E-03 0.1003708E+02 6.5000 4 SO4-- 0.1907084E-11 -.9544867E-04 -.9152963E+01 8.2505 5 HCO3- 0.1784588E-05 0.9770843E-04 0.5951499E+01 4.3015 6 HS- 0.7535952E-04 0.1708227E-03 0.5639598E+01 5.9265 7 Al+++ 0.9855000E-29 0.5293414E-05 0.1425752E+00 0.7390 8 H4SiO4 0.6959783E-03 0.1348896E-01 0.1294236E+04 -3.1574 9 Ca++ 0.1364217E-06 0.2349468E-06 0.9399779E-02 13.1018 10 Mg++ 0.2134258E-10 0.9381592E-10 0.2276875E-05 9.2942 11 Fe++ 0.5882376E-13 0.3613678E-07 0.2014612E-02 6.7350 12 K+ 0.1572909E-03 0.1580452E-03 0.6169109E+01 6.2467 13 Na+ 0.1995957E-01 0.2240655E-01 0.5142240E+03 8.3494 14 Mn++ 0.1887147E-10 0.2526977E-08 0.1385850E-03 9.2416 15 F- 0.5944278E-06 0.5963605E-06 0.1130990E-01 3.8225 16 HPO4-- 0.4496378E-07 0.4605731E-07 0.4412826E-02 12.6231 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279249E+02 -.1102832E-01 -.8278147E+02 0.0000000E+00 2 H2O -.7168388E+01 0.2754956E+02 -.3471795E+02 0.0000000E+00 3 Cl- 0.1407652E-03 0.1407652E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385949E+00 -.4737538E-04 0.1386422E+00 0.0000000E+00 5 HCO3- 0.4849700E-04 0.4849700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385574E+00 0.8478685E-04 -.1386422E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627354E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6695167E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1166145E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4656497E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793627E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7844481E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112136E-01 0.6265256E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254250E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2960000E-06 0.2960000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2286027E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1407E-13 Mass of aqueous solution: 0.497211E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0004900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.159 73.22 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2618 -0.582 56.69 1.753 1.038 17.32 hedenbergite 0.6788E-01 -1.168 16.84 1.226 0.3083 4.613 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.156 97.29 tr.625ac.25prg.125 0.4279E-01 -1.369 36.57 1.563 0.6695 11.77 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338024 g Volume = 2210.779215 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0004900 moles log = -3.3098 Original solution: 1000.0103000 g Original solution / Rock added: 2040837.35 (Water/Rock Ratio), log = 6.3098 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1717 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8724E+00 0.9841 0.1006E+01 0.1022E+01 CO2,gas 0.2158E-07 1.0054 0.2542E-07 0.2529E-07 CH4,gas 0.1146E+00 1.0111 0.1357E+00 0.1343E+00 H2,gas 0.1297E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3416E-06 0.9954 0.3985E-06 0.4003E-06 S2,gas 0.2200E-28 1.0000 0.2577E-28 0.2577E-28 CO,gas 0.8794E-13 1.0000 0.1030E-12 0.1030E-12 SO3,gas 0.1773E-47 1.0000 0.2077E-47 0.2077E-47 SO2,gas 0.1049E-26 1.0000 0.1229E-26 0.1229E-26 HF,gas 0.5295E-15 1.0000 0.6205E-15 0.6205E-15 HCl,gas 0.4848E-17 1.0000 0.5680E-17 0.5680E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.95 -9.29 -3.098 0.15869E+05 -7.595 3 CH4,gas 4.54 1.98 -2.57 -0.642 0.43818E+04 -0.867 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.33 -8.10 -4.049 0.13828E+05 -6.400 6 S2,gas -7.34 -37.62 -30.29 -4.660 0.51716E+05 -28.589 7 CO,gas 3.21 -11.47 -14.69 -4.519 0.25076E+05 -12.987 8 SO3,gas 17.12 -32.26 -49.38 -12.345 0.84317E+05 -47.682 9 SO2,gas 0.83 -27.78 -28.61 -7.629 0.48850E+05 -26.910 10 HF,gas 0.47 -16.43 -16.91 -8.453 0.28867E+05 -15.207 11 HCl,gas 5.19 -13.76 -18.94 -9.472 0.32347E+05 -17.246 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.59 -0.29 -0.024 0.48717E+03 38 aragonite 0.97 -2.85 -3.82 -1.273 0.65200E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.85 -3.66 -1.221 0.62558E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.99 -3.89 -1.110 0.66349E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.99 -3.44 -0.983 0.58772E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.59 -3.33 -1.111 0.56919E+04 147 pyrrhotiteFe0.875 -6.02 -8.99 -2.97 -1.094 0.50791E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.59 -3.18 -1.061 0.54347E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.09 -4.11 -1.370 0.70166E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0004900 MOLES New total amount of reactant added: 0.0005100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8655E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0005100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1139124E-01 Osmotic coef. = 1.0051 True ionic strength = .2012171E-01 Chg. balance for total moles = -.8655E-10 Max. difference allowed = 0.1409E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88734E-10 -10.0519 0.74535E-10 -10.1276 0.83998E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28254E-03 -3.5489 0.23589E-03 -3.6273 0.83491E+00 -0.0784 4 SO4-- 0.19318E-11 -11.7140 0.10018E-11 -11.9992 0.51861E+00 -0.2852 5 HCO3- 0.18377E-05 -5.7357 0.15366E-05 -5.8134 0.83613E+00 -0.0777 6 HS- 0.76338E-04 -4.1173 0.63745E-04 -4.1956 0.83503E+00 -0.0783 7 Al+++ 0.98564E-29 -29.0063 0.22701E-29 -29.6439 0.23032E+00 -0.6377 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13643E-06 -6.8651 0.70234E-07 -7.1535 0.51479E+00 -0.2884 10 Mg++ 0.21344E-10 -10.6707 0.10937E-10 -10.9611 0.51242E+00 -0.2904 11 Fe++ 0.58829E-13 -13.2304 0.30178E-13 -13.5203 0.51299E+00 -0.2899 12 K+ 0.15730E-03 -3.8033 0.13155E-03 -3.8809 0.83633E+00 -0.0776 13 Na+ 0.19960E-01 -1.6998 0.16662E-01 -1.7783 0.83476E+00 -0.0784 14 Mn++ 0.18873E-10 -10.7242 0.96897E-11 -11.0137 0.51341E+00 -0.2895 15 F- 0.61049E-06 -6.2143 0.50865E-06 -6.2936 0.83318E+00 -0.0793 16 HPO4-- 0.44961E-07 -7.3472 0.23320E-07 -7.6323 0.51868E+00 -0.2851 18 HSiO3- 0.10443E-01 -1.9812 0.87189E-02 -2.0595 0.83491E+00 -0.0784 19 Ca(HSiO3)+ 0.16671E-07 -7.7780 0.13946E-07 -7.8556 0.83651E+00 -0.0775 20 Mg(HSiO3)+ 0.32310E-11 -11.4907 0.27028E-11 -11.5682 0.83651E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66456E-16 -16.1775 0.55591E-16 -16.2550 0.83651E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52931E-05 -5.2763 0.44112E-05 -5.3554 0.83340E+00 -0.0791 26 CH4,aq 0.95302E-04 -4.0209 0.94971E-04 -4.0224 0.99653E+00 -0.0015 27 C2H6,aq 0.13359E-12 -12.8742 0.13313E-12 -12.8757 0.99653E+00 -0.0015 31 CO,aq 0.71206E-16 -16.1475 0.71206E-16 -16.1475 0.10000E+01 0.0000 32 CO2,aq 0.24558E-09 -9.6098 0.24472E-09 -9.6113 0.99653E+00 -0.0015 33 CO3-2 0.34796E-05 -5.4585 0.18007E-05 -5.7446 0.51750E+00 -0.2861 34 CaCO3,aq 0.15858E-08 -8.7997 0.15858E-08 -8.7997 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.32932E-11 -11.4824 0.27548E-11 -11.5599 0.83651E+00 -0.0775 36 CaCl+ 0.32052E-10 -10.4941 0.26812E-10 -10.5717 0.83651E+00 -0.0775 37 CaCl2,aq 0.15026E-14 -14.8231 0.15026E-14 -14.8231 0.10000E+01 0.0000 38 CaF+ 0.62352E-12 -12.2051 0.52158E-12 -12.2827 0.83651E+00 -0.0775 39 CaOH+ 0.80282E-07 -7.0954 0.67157E-07 -7.1729 0.83651E+00 -0.0775 40 CaSO4,aq 0.22344E-16 -16.6508 0.22344E-16 -16.6508 0.10000E+01 0.0000 41 HCl,aq 0.32219E-14 -14.4919 0.32219E-14 -14.4919 0.10000E+01 0.0000 45 HF,aq 0.25954E-12 -12.5858 0.25954E-12 -12.5858 0.10000E+01 0.0000 46 HF2- 0.53384E-19 -19.2726 0.44571E-19 -19.3509 0.83491E+00 -0.0784 48 FeCl+ 0.13470E-16 -16.8706 0.11268E-16 -16.9482 0.83651E+00 -0.0775 51 FeF+ 0.93773E-18 -18.0279 0.78442E-18 -18.1054 0.83651E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15755E-10 -10.8026 0.13180E-10 -10.8801 0.83651E+00 -0.0775 55 HFeO2- 0.35498E-07 -7.4498 0.29638E-07 -7.5282 0.83491E+00 -0.0784 56 FeO+ 0.11042E-16 -16.9569 0.92368E-17 -17.0345 0.83651E+00 -0.0775 58 FeO2- 0.40749E-09 -9.3899 0.34021E-09 -9.4682 0.83491E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56244E-09 -9.2499 0.56244E-09 -9.2499 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.24496E-14 -14.6109 0.20452E-14 -14.6893 0.83491E+00 -0.0784 65 MgCO3,aq 0.61901E-13 -13.2083 0.61901E-13 -13.2083 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.52403E-15 -15.2806 0.43836E-15 -15.3582 0.83651E+00 -0.0775 67 MgCl+ 0.45239E-14 -14.3445 0.37843E-14 -14.4220 0.83651E+00 -0.0775 68 MgF+ 0.35968E-15 -15.4441 0.30088E-15 -15.5216 0.83651E+00 -0.0775 69 MgOH+ 0.69180E-10 -10.1600 0.57870E-10 -10.2375 0.83651E+00 -0.0775 71 MnF+ 0.99241E-16 -16.0033 0.83017E-16 -16.0808 0.83651E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46994E-09 -9.3280 0.39311E-09 -9.4055 0.83651E+00 -0.0775 74 MnO2-2 0.20851E-10 -10.6809 0.10790E-10 -10.9670 0.51750E+00 -0.2861 75 HMnO2- 0.21104E-09 -9.6756 0.17620E-09 -9.7540 0.83491E+00 -0.0784 78 MnCl+ 0.16826E-13 -13.7740 0.14075E-13 -13.8515 0.83651E+00 -0.0775 80 NaCl,aq 0.13026E-05 -5.8852 0.13026E-05 -5.8852 0.10000E+01 0.0000 81 NaF,aq 0.19842E-08 -8.7024 0.19842E-08 -8.7024 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93014E-02 -2.0315 0.77517E-02 -2.1106 0.83340E+00 -0.0791 89 HPO3-2 0.16266E-14 -14.7887 0.84176E-15 -15.0748 0.51750E+00 -0.2861 91 H2PO3- 0.15069E-18 -18.8219 0.12581E-18 -18.9003 0.83491E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38369E-10 -10.4160 0.32065E-10 -10.4940 0.83570E+00 -0.0779 94 PO4-3 0.10551E-08 -8.9767 0.25528E-09 -9.5930 0.24195E+00 -0.6163 98 HP2O7-3 0.93676E-18 -18.0284 0.21597E-18 -18.6656 0.23055E+00 -0.6372 99 P2O7-4 0.90256E-17 -17.0445 0.69223E-18 -18.1598 0.76696E-01 -1.1152 100 H2S,aq 0.14735E-07 -7.8316 0.14684E-07 -7.8331 0.99653E+00 -0.0015 101 S2-2 0.15021E-13 -13.8233 0.77736E-14 -14.1094 0.51750E+00 -0.2861 107 SO3-2 0.28721E-17 -17.5418 0.15079E-17 -17.8216 0.52502E+00 -0.2798 109 HSO4- 0.85943E-19 -19.0658 0.71963E-19 -19.1429 0.83733E+00 -0.0771 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8873408E-10 -.2221852E-01 -.2235589E+02 0.0000 2 H2O 0.1000000E+01 0.5550497E+02 0.9981951E+06 0.0000 3 Cl- 0.2825384E-03 0.2838416E-03 0.1004549E+02 6.5004 4 SO4-- 0.1931801E-11 -.9820814E-04 -.9417580E+01 8.2561 5 HCO3- 0.1837740E-05 0.1006217E-03 0.6128946E+01 4.3142 6 HS- 0.7633843E-04 0.1745613E-03 0.5763025E+01 5.9321 7 Al+++ 0.9856371E-29 0.5293233E-05 0.1425703E+00 0.7390 8 H4SiO4 0.6959783E-03 0.1348861E-01 0.1294202E+04 -3.1574 9 Ca++ 0.1364335E-06 0.2350086E-06 0.9402251E-02 13.1018 10 Mg++ 0.2134443E-10 0.9382301E-10 0.2277047E-05 9.2942 11 Fe++ 0.5882888E-13 0.3613555E-07 0.2014543E-02 6.7350 12 K+ 0.1572972E-03 0.1580516E-03 0.6169355E+01 6.2467 13 Na+ 0.1996038E-01 0.2240736E-01 0.5142424E+03 8.3494 14 Mn++ 0.1887315E-10 0.2526994E-08 0.1385859E-03 9.2416 15 F- 0.6104929E-06 0.6124779E-06 0.1161557E-01 3.8341 16 HPO4-- 0.4496096E-07 0.4605440E-07 0.4412547E-02 12.6230 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279249E+02 -.1102804E-01 -.8278146E+02 0.0000000E+00 2 H2O -.7168371E+01 0.2754958E+02 -.3471795E+02 0.0000000E+00 3 Cl- 0.1408832E-03 0.1408832E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385950E+00 -.4874506E-04 0.1386437E+00 0.0000000E+00 5 HCO3- 0.4994300E-04 0.4994300E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385571E+00 0.8664253E-04 -.1386437E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627267E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6694994E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1166452E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4656853E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793568E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7844800E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112177E-01 0.6265255E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254260E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3040000E-06 0.3040000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2285884E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1957E-14 Mass of aqueous solution: 0.497211E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0005100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.159 73.22 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2617 -0.582 56.68 1.753 1.038 17.32 hedenbergite 0.6787E-01 -1.168 16.84 1.226 0.3083 4.612 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.156 97.29 tr.625ac.25prg.125 0.4280E-01 -1.369 36.58 1.563 0.6697 11.77 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338031 g Volume = 2210.779271 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0005100 moles log = -3.2924 Original solution: 1000.0103000 g Original solution / Rock added: 1960804.51 (Water/Rock Ratio), log = 6.2924 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1758 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8695E+00 0.9840 0.1006E+01 0.1022E+01 CO2,gas 0.2215E-07 1.0054 0.2618E-07 0.2604E-07 CH4,gas 0.1176E+00 1.0110 0.1398E+00 0.1383E+00 H2,gas 0.1293E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3449E-06 0.9954 0.4037E-06 0.4055E-06 S2,gas 0.2250E-28 1.0000 0.2645E-28 0.2645E-28 CO,gas 0.9025E-13 1.0000 0.1061E-12 0.1061E-12 SO3,gas 0.1790E-47 1.0000 0.2104E-47 0.2104E-47 SO2,gas 0.1059E-26 1.0000 0.1245E-26 0.1245E-26 HF,gas 0.5420E-15 1.0000 0.6373E-15 0.6373E-15 HCl,gas 0.4835E-17 1.0000 0.5685E-17 0.5685E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.36397E-10 24 grossular 32.73 32.73 0.00 0.000 0.48529E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.94 -9.28 -3.094 0.15847E+05 -7.582 3 CH4,gas 4.54 1.99 -2.55 -0.638 0.43600E+04 -0.855 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.32 -8.09 -4.046 0.13819E+05 -6.394 6 S2,gas -7.34 -37.61 -30.28 -4.658 0.51696E+05 -28.578 7 CO,gas 3.21 -11.46 -14.67 -4.515 0.25054E+05 -12.974 8 SO3,gas 17.12 -32.25 -49.38 -12.344 0.84308E+05 -47.677 9 SO2,gas 0.83 -27.77 -28.60 -7.628 0.48840E+05 -26.905 10 HF,gas 0.47 -16.42 -16.89 -8.447 0.28847E+05 -15.196 11 HCl,gas 5.19 -13.75 -18.94 -9.472 0.32347E+05 -17.245 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.57 -0.27 -0.023 0.46737E+03 38 aragonite 0.97 -2.84 -3.81 -1.269 0.64983E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.84 -3.65 -1.217 0.62340E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.98 -3.87 -1.107 0.66131E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.98 -3.43 -0.980 0.58554E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.59 -3.33 -1.109 0.56823E+04 147 pyrrhotiteFe0.875 -6.02 -8.99 -2.97 -1.092 0.50695E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.59 -3.18 -1.059 0.54251E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.08 -4.10 -1.368 0.70070E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0005100 MOLES New total amount of reactant added: 0.0005300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8658E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0005300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138958E-01 Osmotic coef. = 1.0076 True ionic strength = .2012262E-01 Chg. balance for total moles = -.8658E-10 Max. difference allowed = 0.1410E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88738E-10 -10.0519 0.74538E-10 -10.1276 0.83998E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28277E-03 -3.5486 0.23609E-03 -3.6269 0.83491E+00 -0.0784 4 SO4-- 0.19565E-11 -11.7085 0.10147E-11 -11.9937 0.51860E+00 -0.2852 5 HCO3- 0.18909E-05 -5.7233 0.15810E-05 -5.8011 0.83613E+00 -0.0777 6 HS- 0.77317E-04 -4.1117 0.64562E-04 -4.1900 0.83503E+00 -0.0783 7 Al+++ 0.98577E-29 -29.0062 0.22704E-29 -29.6439 0.23031E+00 -0.6377 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13645E-06 -6.8650 0.70239E-07 -7.1534 0.51478E+00 -0.2884 10 Mg++ 0.21346E-10 -10.6707 0.10938E-10 -10.9611 0.51242E+00 -0.2904 11 Fe++ 0.58834E-13 -13.2304 0.30181E-13 -13.5203 0.51298E+00 -0.2899 12 K+ 0.15730E-03 -3.8033 0.13156E-03 -3.8809 0.83633E+00 -0.0776 13 Na+ 0.19961E-01 -1.6998 0.16663E-01 -1.7783 0.83475E+00 -0.0784 14 Mn++ 0.18875E-10 -10.7241 0.96904E-11 -11.0137 0.51341E+00 -0.2895 15 F- 0.62656E-06 -6.2030 0.52203E-06 -6.2823 0.83318E+00 -0.0793 16 HPO4-- 0.44958E-07 -7.3472 0.23319E-07 -7.6323 0.51868E+00 -0.2851 18 HSiO3- 0.10443E-01 -1.9812 0.87186E-02 -2.0596 0.83491E+00 -0.0784 19 Ca(HSiO3)+ 0.16672E-07 -7.7780 0.13946E-07 -7.8555 0.83651E+00 -0.0775 20 Mg(HSiO3)+ 0.32311E-11 -11.4906 0.27029E-11 -11.5682 0.83651E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66459E-16 -16.1774 0.55593E-16 -16.2550 0.83651E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52929E-05 -5.2763 0.44111E-05 -5.3555 0.83339E+00 -0.0792 26 CH4,aq 0.98062E-04 -4.0085 0.97721E-04 -4.0100 0.99653E+00 -0.0015 27 C2H6,aq 0.14144E-12 -12.8494 0.14095E-12 -12.8509 0.99653E+00 -0.0015 31 CO,aq 0.73268E-16 -16.1351 0.73268E-16 -16.1351 0.10000E+01 0.0000 32 CO2,aq 0.25269E-09 -9.5974 0.25181E-09 -9.5989 0.99653E+00 -0.0015 33 CO3-2 0.35801E-05 -5.4461 0.18527E-05 -5.7322 0.51750E+00 -0.2861 34 CaCO3,aq 0.16317E-08 -8.7874 0.16317E-08 -8.7874 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.33887E-11 -11.4700 0.28347E-11 -11.5475 0.83651E+00 -0.0775 36 CaCl+ 0.32081E-10 -10.4938 0.26836E-10 -10.5713 0.83651E+00 -0.0775 37 CaCl2,aq 0.15052E-14 -14.8224 0.15052E-14 -14.8224 0.10000E+01 0.0000 38 CaF+ 0.63998E-12 -12.1938 0.53535E-12 -12.2714 0.83651E+00 -0.0775 39 CaOH+ 0.80285E-07 -7.0954 0.67159E-07 -7.1729 0.83651E+00 -0.0775 40 CaSO4,aq 0.22631E-16 -16.6453 0.22631E-16 -16.6453 0.10000E+01 0.0000 41 HCl,aq 0.32247E-14 -14.4915 0.32247E-14 -14.4915 0.10000E+01 0.0000 45 HF,aq 0.26637E-12 -12.5745 0.26637E-12 -12.5745 0.10000E+01 0.0000 46 HF2- 0.56233E-19 -19.2500 0.46949E-19 -19.3284 0.83491E+00 -0.0784 48 FeCl+ 0.13482E-16 -16.8702 0.11278E-16 -16.9478 0.83651E+00 -0.0775 51 FeF+ 0.96248E-18 -18.0166 0.80512E-18 -18.0941 0.83651E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15756E-10 -10.8026 0.13180E-10 -10.8801 0.83651E+00 -0.0775 55 HFeO2- 0.35497E-07 -7.4498 0.29636E-07 -7.5282 0.83491E+00 -0.0784 56 FeO+ 0.11043E-16 -16.9569 0.92372E-17 -17.0345 0.83651E+00 -0.0775 58 FeO2- 0.40747E-09 -9.3899 0.34020E-09 -9.4683 0.83491E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56293E-09 -9.2495 0.56293E-09 -9.2495 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.24810E-14 -14.6054 0.20714E-14 -14.6837 0.83491E+00 -0.0784 65 MgCO3,aq 0.63693E-13 -13.1959 0.63693E-13 -13.1959 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.53922E-15 -15.2682 0.45107E-15 -15.3458 0.83651E+00 -0.0775 67 MgCl+ 0.45280E-14 -14.3441 0.37877E-14 -14.4216 0.83651E+00 -0.0775 68 MgF+ 0.36918E-15 -15.4328 0.30882E-15 -15.5103 0.83651E+00 -0.0775 69 MgOH+ 0.69183E-10 -10.1600 0.57872E-10 -10.2375 0.83651E+00 -0.0775 71 MnF+ 0.10186E-15 -15.9920 0.85208E-16 -16.0695 0.83651E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46996E-09 -9.3279 0.39313E-09 -9.4055 0.83651E+00 -0.0775 74 MnO2-2 0.20849E-10 -10.6809 0.10790E-10 -10.9670 0.51750E+00 -0.2861 75 HMnO2- 0.21103E-09 -9.6756 0.17619E-09 -9.7540 0.83491E+00 -0.0784 78 MnCl+ 0.16842E-13 -13.7736 0.14088E-13 -13.8511 0.83651E+00 -0.0775 80 NaCl,aq 0.13037E-05 -5.8848 0.13037E-05 -5.8848 0.10000E+01 0.0000 81 NaF,aq 0.20365E-08 -8.6911 0.20365E-08 -8.6911 0.10000E+01 0.0000 82 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93010E-02 -2.0315 0.77514E-02 -2.1106 0.83339E+00 -0.0792 89 HPO3-2 0.16265E-14 -14.7888 0.84169E-15 -15.0748 0.51750E+00 -0.2861 91 H2PO3- 0.15069E-18 -18.8219 0.12581E-18 -18.9003 0.83491E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38367E-10 -10.4160 0.32064E-10 -10.4940 0.83570E+00 -0.0779 94 PO4-3 0.10550E-08 -8.9768 0.25525E-09 -9.5930 0.24195E+00 -0.6163 98 HP2O7-3 0.93668E-18 -18.0284 0.21595E-18 -18.6657 0.23055E+00 -0.6372 99 P2O7-4 0.90247E-17 -17.0446 0.69212E-18 -18.1598 0.76692E-01 -1.1152 100 H2S,aq 0.14925E-07 -7.8261 0.14873E-07 -7.8276 0.99653E+00 -0.0015 101 S2-2 0.15409E-13 -13.8122 0.79742E-14 -14.0983 0.51750E+00 -0.2861 107 SO3-2 0.29089E-17 -17.5363 0.15272E-17 -17.8161 0.52501E+00 -0.2798 109 HSO4- 0.87046E-19 -19.0603 0.72886E-19 -19.1374 0.83733E+00 -0.0771 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8873765E-10 -.2221795E-01 -.2235531E+02 0.0000 2 H2O 0.1000000E+01 0.5550498E+02 0.9981950E+06 0.0000 3 Cl- 0.2827748E-03 0.2840791E-03 0.1005389E+02 6.5007 4 SO4-- 0.1956518E-11 -.1009676E-03 -.9682198E+01 8.2616 5 HCO3- 0.1890888E-05 0.1035349E-03 0.6306392E+01 4.3266 6 HS- 0.7731735E-04 0.1782999E-03 0.5886451E+01 5.9376 7 Al+++ 0.9857743E-29 0.5293052E-05 0.1425654E+00 0.7390 8 H4SiO4 0.6959783E-03 0.1348825E-01 0.1294167E+04 -3.1574 9 Ca++ 0.1364453E-06 0.2350704E-06 0.9404723E-02 13.1018 10 Mg++ 0.2134629E-10 0.9383010E-10 0.2277219E-05 9.2942 11 Fe++ 0.5883399E-13 0.3613432E-07 0.2014474E-02 6.7350 12 K+ 0.1573036E-03 0.1580579E-03 0.6169601E+01 6.2467 13 Na+ 0.1996118E-01 0.2240816E-01 0.5142608E+03 8.3494 14 Mn++ 0.1887483E-10 0.2527011E-08 0.1385868E-03 9.2416 15 F- 0.6265579E-06 0.6285953E-06 0.1192123E-01 3.8453 16 HPO4-- 0.4495814E-07 0.4605148E-07 0.4412267E-02 12.6230 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279249E+02 -.1102776E-01 -.8278146E+02 0.0000000E+00 2 H2O -.7168355E+01 0.2754961E+02 -.3471796E+02 0.0000000E+00 3 Cl- 0.1410012E-03 0.1410012E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385951E+00 -.5011476E-04 0.1386452E+00 0.0000000E+00 5 HCO3- 0.5138900E-04 0.5138900E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385567E+00 0.8849823E-04 -.1386452E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627179E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6694821E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1166760E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4657208E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793508E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7845120E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112217E-01 0.6265255E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254269E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3120000E-06 0.3120000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2285741E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1973E-13 Mass of aqueous solution: 0.497212E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0005300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.159 73.22 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2617 -0.582 56.67 1.753 1.037 17.32 hedenbergite 0.6786E-01 -1.168 16.84 1.226 0.3082 4.612 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.156 97.29 tr.625ac.25prg.125 0.4281E-01 -1.368 36.59 1.563 0.6699 11.78 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338037 g Volume = 2210.779326 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0005300 moles log = -3.2757 Original solution: 1000.0103000 g Original solution / Rock added: 1886811.89 (Water/Rock Ratio), log = 6.2757 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1798 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8665E+00 0.9840 0.1006E+01 0.1022E+01 CO2,gas 0.2271E-07 1.0053 0.2694E-07 0.2680E-07 CH4,gas 0.1206E+00 1.0110 0.1438E+00 0.1423E+00 H2,gas 0.1288E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3481E-06 0.9954 0.4088E-06 0.4107E-06 S2,gas 0.2300E-28 1.0000 0.2713E-28 0.2713E-28 CO,gas 0.9254E-13 1.0000 0.1092E-12 0.1092E-12 SO3,gas 0.1807E-47 1.0000 0.2131E-47 0.2131E-47 SO2,gas 0.1069E-26 1.0000 0.1261E-26 0.1261E-26 HF,gas 0.5544E-15 1.0000 0.6540E-15 0.6540E-15 HCl,gas 0.4823E-17 1.0000 0.5690E-17 0.5690E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.93 -9.27 -3.090 0.15826E+05 -7.570 3 CH4,gas 4.54 2.00 -2.54 -0.635 0.43388E+04 -0.842 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.32 -8.09 -4.044 0.13809E+05 -6.388 6 S2,gas -7.34 -37.60 -30.27 -4.656 0.51677E+05 -28.566 7 CO,gas 3.21 -11.45 -14.66 -4.511 0.25033E+05 -12.962 8 SO3,gas 17.12 -32.25 -49.37 -12.343 0.84298E+05 -47.671 9 SO2,gas 0.83 -27.77 -28.60 -7.626 0.48831E+05 -26.899 10 HF,gas 0.47 -16.41 -16.88 -8.442 0.28828E+05 -15.184 11 HCl,gas 5.19 -13.75 -18.94 -9.472 0.32346E+05 -17.245 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.56 -0.26 -0.022 0.44809E+03 38 aragonite 0.97 -2.83 -3.79 -1.264 0.64771E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.83 -3.64 -1.213 0.62129E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.96 -3.86 -1.103 0.65920E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.96 -3.42 -0.976 0.58342E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.58 -3.32 -1.107 0.56728E+04 147 pyrrhotiteFe0.875 -6.02 -8.98 -2.96 -1.090 0.50600E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.58 -3.17 -1.057 0.54156E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.08 -4.10 -1.366 0.69975E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0005300 MOLES New total amount of reactant added: 0.0005500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8656E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0005500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138791E-01 Osmotic coef. = 1.0103 True ionic strength = .2012353E-01 Chg. balance for total moles = -.8656E-10 Max. difference allowed = 0.1411E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88741E-10 -10.0519 0.74540E-10 -10.1276 0.83998E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28301E-03 -3.5482 0.23629E-03 -3.6266 0.83490E+00 -0.0784 4 SO4-- 0.19812E-11 -11.7031 0.10275E-11 -11.9882 0.51860E+00 -0.2852 5 HCO3- 0.19440E-05 -5.7113 0.16255E-05 -5.7890 0.83613E+00 -0.0777 6 HS- 0.78296E-04 -4.1063 0.65379E-04 -4.1846 0.83503E+00 -0.0783 7 Al+++ 0.98591E-29 -29.0062 0.22706E-29 -29.6439 0.23031E+00 -0.6377 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13646E-06 -6.8650 0.70245E-07 -7.1534 0.51477E+00 -0.2884 10 Mg++ 0.21348E-10 -10.6706 0.10939E-10 -10.9610 0.51241E+00 -0.2904 11 Fe++ 0.58839E-13 -13.2303 0.30183E-13 -13.5202 0.51297E+00 -0.2899 12 K+ 0.15731E-03 -3.8032 0.13156E-03 -3.8809 0.83633E+00 -0.0776 13 Na+ 0.19962E-01 -1.6998 0.16663E-01 -1.7782 0.83475E+00 -0.0784 14 Mn++ 0.18877E-10 -10.7241 0.96912E-11 -11.0136 0.51340E+00 -0.2895 15 F- 0.64262E-06 -6.1920 0.53542E-06 -6.2713 0.83318E+00 -0.0793 16 HPO4-- 0.44955E-07 -7.3472 0.23317E-07 -7.6323 0.51867E+00 -0.2851 18 HSiO3- 0.10442E-01 -1.9812 0.87183E-02 -2.0596 0.83490E+00 -0.0784 19 Ca(HSiO3)+ 0.16673E-07 -7.7780 0.13947E-07 -7.8555 0.83651E+00 -0.0775 20 Mg(HSiO3)+ 0.32313E-11 -11.4906 0.27030E-11 -11.5682 0.83651E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66461E-16 -16.1774 0.55596E-16 -16.2550 0.83651E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52927E-05 -5.2763 0.44109E-05 -5.3555 0.83339E+00 -0.0792 26 CH4,aq 0.10082E-03 -3.9964 0.10047E-03 -3.9980 0.99653E+00 -0.0015 27 C2H6,aq 0.14951E-12 -12.8253 0.14899E-12 -12.8268 0.99653E+00 -0.0015 31 CO,aq 0.75329E-16 -16.1230 0.75329E-16 -16.1230 0.10000E+01 0.0000 32 CO2,aq 0.25980E-09 -9.5854 0.25890E-09 -9.5869 0.99653E+00 -0.0015 33 CO3-2 0.36807E-05 -5.4341 0.19047E-05 -5.7202 0.51749E+00 -0.2861 34 CaCO3,aq 0.16776E-08 -8.7753 0.16776E-08 -8.7753 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.34842E-11 -11.4579 0.29146E-11 -11.5354 0.83651E+00 -0.0775 36 CaCl+ 0.32110E-10 -10.4934 0.26861E-10 -10.5709 0.83651E+00 -0.0775 37 CaCl2,aq 0.15079E-14 -14.8216 0.15079E-14 -14.8216 0.10000E+01 0.0000 38 CaF+ 0.65643E-12 -12.1828 0.54911E-12 -12.2603 0.83651E+00 -0.0775 39 CaOH+ 0.80288E-07 -7.0953 0.67162E-07 -7.1729 0.83651E+00 -0.0775 40 CaSO4,aq 0.22918E-16 -16.6398 0.22918E-16 -16.6398 0.10000E+01 0.0000 41 HCl,aq 0.32275E-14 -14.4911 0.32275E-14 -14.4911 0.10000E+01 0.0000 45 HF,aq 0.27321E-12 -12.5635 0.27321E-12 -12.5635 0.10000E+01 0.0000 46 HF2- 0.59155E-19 -19.2280 0.49389E-19 -19.3064 0.83490E+00 -0.0784 48 FeCl+ 0.13495E-16 -16.8698 0.11288E-16 -16.9474 0.83651E+00 -0.0775 51 FeF+ 0.98723E-18 -18.0056 0.82583E-18 -18.0831 0.83651E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15757E-10 -10.8025 0.13181E-10 -10.8801 0.83651E+00 -0.0775 55 HFeO2- 0.35495E-07 -7.4498 0.29635E-07 -7.5282 0.83490E+00 -0.0784 56 FeO+ 0.11043E-16 -16.9569 0.92375E-17 -17.0344 0.83651E+00 -0.0775 58 FeO2- 0.40746E-09 -9.3899 0.34019E-09 -9.4683 0.83490E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56342E-09 -9.2492 0.56342E-09 -9.2492 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.25124E-14 -14.5999 0.20976E-14 -14.6783 0.83490E+00 -0.0784 65 MgCO3,aq 0.65485E-13 -13.1839 0.65485E-13 -13.1839 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.55442E-15 -15.2562 0.46378E-15 -15.3337 0.83651E+00 -0.0775 67 MgCl+ 0.45321E-14 -14.3437 0.37912E-14 -14.4212 0.83651E+00 -0.0775 68 MgF+ 0.37867E-15 -15.4217 0.31676E-15 -15.4993 0.83651E+00 -0.0775 69 MgOH+ 0.69186E-10 -10.1600 0.57875E-10 -10.2375 0.83651E+00 -0.0775 71 MnF+ 0.10448E-15 -15.9810 0.87399E-16 -16.0585 0.83651E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.46998E-09 -9.3279 0.39314E-09 -9.4055 0.83651E+00 -0.0775 74 MnO2-2 0.20848E-10 -10.6809 0.10789E-10 -10.9670 0.51749E+00 -0.2861 75 HMnO2- 0.21103E-09 -9.6757 0.17619E-09 -9.7540 0.83490E+00 -0.0784 78 MnCl+ 0.16857E-13 -13.7732 0.14101E-13 -13.8507 0.83651E+00 -0.0775 80 NaCl,aq 0.13048E-05 -5.8844 0.13048E-05 -5.8844 0.10000E+01 0.0000 81 NaF,aq 0.20888E-08 -8.6801 0.20888E-08 -8.6801 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93007E-02 -2.0315 0.77511E-02 -2.1106 0.83339E+00 -0.0792 89 HPO3-2 0.16264E-14 -14.7888 0.84163E-15 -15.0749 0.51749E+00 -0.2861 91 H2PO3- 0.15068E-18 -18.8219 0.12580E-18 -18.9003 0.83490E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38366E-10 -10.4161 0.32062E-10 -10.4940 0.83570E+00 -0.0780 94 PO4-3 0.10549E-08 -8.9768 0.25522E-09 -9.5931 0.24194E+00 -0.6163 98 HP2O7-3 0.93660E-18 -18.0284 0.21592E-18 -18.6657 0.23054E+00 -0.6373 99 P2O7-4 0.90238E-17 -17.0446 0.69202E-18 -18.1599 0.76688E-01 -1.1153 100 H2S,aq 0.15114E-07 -7.8206 0.15062E-07 -7.8221 0.99653E+00 -0.0015 101 S2-2 0.15802E-13 -13.8013 0.81773E-14 -14.0874 0.51749E+00 -0.2861 107 SO3-2 0.29456E-17 -17.5308 0.15465E-17 -17.8107 0.52501E+00 -0.2798 109 HSO4- 0.88148E-19 -19.0548 0.73808E-19 -19.1319 0.83733E+00 -0.0771 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8874121E-10 -.2221737E-01 -.2235472E+02 0.0000 2 H2O 0.1000000E+01 0.5550498E+02 0.9981950E+06 0.0000 3 Cl- 0.2830112E-03 0.2843166E-03 0.1006230E+02 6.5010 4 SO4-- 0.1981233E-11 -.1037271E-03 -.9946818E+01 8.2670 5 HCO3- 0.1944033E-05 0.1064481E-03 0.6483838E+01 4.3386 6 HS- 0.7829626E-04 0.1820385E-03 0.6009878E+01 5.9430 7 Al+++ 0.9859115E-29 0.5292872E-05 0.1425606E+00 0.7390 8 H4SiO4 0.6959782E-03 0.1348789E-01 0.1294133E+04 -3.1574 9 Ca++ 0.1364572E-06 0.2351322E-06 0.9407195E-02 13.1018 10 Mg++ 0.2134814E-10 0.9383540E-10 0.2277348E-05 9.2942 11 Fe++ 0.5883910E-13 0.3613309E-07 0.2014405E-02 6.7350 12 K+ 0.1573099E-03 0.1580642E-03 0.6169847E+01 6.2467 13 Na+ 0.1996198E-01 0.2240897E-01 0.5142792E+03 8.3494 14 Mn++ 0.1887650E-10 0.2527028E-08 0.1385878E-03 9.2416 15 F- 0.6426230E-06 0.6447127E-06 0.1222689E-01 3.8563 16 HPO4-- 0.4495532E-07 0.4604857E-07 0.4411988E-02 12.6229 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279249E+02 -.1102748E-01 -.8278146E+02 0.0000000E+00 2 H2O -.7168338E+01 0.2754963E+02 -.3471797E+02 0.0000000E+00 3 Cl- 0.1411192E-03 0.1411192E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385951E+00 -.5148446E-04 0.1386466E+00 0.0000000E+00 5 HCO3- 0.5283500E-04 0.5283500E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385563E+00 0.9035393E-04 -.1386466E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627091E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6694648E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1167067E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4657474E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793448E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7845439E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112258E-01 0.6265254E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254278E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3200000E-06 0.3200000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2285598E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.2894E-14 Mass of aqueous solution: 0.497212E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0005500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.160 73.22 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2616 -0.582 56.66 1.753 1.037 17.32 hedenbergite 0.6785E-01 -1.168 16.83 1.226 0.3082 4.611 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.156 97.29 tr.625ac.25prg.125 0.4282E-01 -1.368 36.60 1.564 0.6701 11.78 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338044 g Volume = 2210.779382 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0005500 moles log = -3.2596 Original solution: 1000.0103000 g Original solution / Rock added: 1818200.55 (Water/Rock Ratio), log = 6.2596 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1839 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8636E+00 0.9839 0.1006E+01 0.1022E+01 CO2,gas 0.2327E-07 1.0053 0.2770E-07 0.2755E-07 CH4,gas 0.1236E+00 1.0109 0.1479E+00 0.1463E+00 H2,gas 0.1284E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3514E-06 0.9954 0.4140E-06 0.4160E-06 S2,gas 0.2351E-28 1.0000 0.2783E-28 0.2783E-28 CO,gas 0.9482E-13 1.0000 0.1123E-12 0.1123E-12 SO3,gas 0.1823E-47 1.0000 0.2159E-47 0.2159E-47 SO2,gas 0.1079E-26 1.0000 0.1277E-26 0.1277E-26 HF,gas 0.5667E-15 1.0000 0.6708E-15 0.6708E-15 HCl,gas 0.4811E-17 1.0000 0.5695E-17 0.5695E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.18198E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.84926E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.92 -9.26 -3.086 0.15805E+05 -7.558 3 CH4,gas 4.54 2.01 -2.53 -0.632 0.43183E+04 -0.830 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.31 -8.08 -4.041 0.13800E+05 -6.383 6 S2,gas -7.34 -37.59 -30.25 -4.655 0.51659E+05 -28.556 7 CO,gas 3.21 -11.43 -14.65 -4.507 0.25012E+05 -12.950 8 SO3,gas 17.12 -32.24 -49.36 -12.341 0.84289E+05 -47.666 9 SO2,gas 0.83 -27.76 -28.59 -7.625 0.48821E+05 -26.894 10 HF,gas 0.47 -16.40 -16.87 -8.436 0.28809E+05 -15.173 11 HCl,gas 5.19 -13.75 -18.94 -9.472 0.32345E+05 -17.245 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.55 -0.25 -0.021 0.42929E+03 38 aragonite 0.97 -2.81 -3.78 -1.260 0.64565E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.81 -3.63 -1.209 0.61923E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.95 -3.85 -1.100 0.65714E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.95 -3.40 -0.973 0.58136E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.58 -3.32 -1.106 0.56635E+04 147 pyrrhotiteFe0.875 -6.02 -8.97 -2.96 -1.088 0.50507E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.58 -3.17 -1.055 0.54063E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.07 -4.09 -1.364 0.69882E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0005500 MOLES New total amount of reactant added: 0.0005700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8656E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0005700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138625E-01 Osmotic coef. = 1.0132 True ionic strength = .2012444E-01 Chg. balance for total moles = -.8656E-10 Max. difference allowed = 0.1412E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88745E-10 -10.0519 0.74543E-10 -10.1276 0.83997E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28325E-03 -3.5478 0.23648E-03 -3.6262 0.83490E+00 -0.0784 4 SO4-- 0.20059E-11 -11.6977 0.10403E-11 -11.9829 0.51859E+00 -0.2852 5 HCO3- 0.19972E-05 -5.6996 0.16699E-05 -5.7773 0.83613E+00 -0.0777 6 HS- 0.79275E-04 -4.1009 0.66197E-04 -4.1792 0.83502E+00 -0.0783 7 Al+++ 0.98605E-29 -29.0061 0.22709E-29 -29.6438 0.23030E+00 -0.6377 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13647E-06 -6.8650 0.70250E-07 -7.1534 0.51477E+00 -0.2884 10 Mg++ 0.21350E-10 -10.6706 0.10940E-10 -10.9610 0.51240E+00 -0.2904 11 Fe++ 0.58844E-13 -13.2303 0.30185E-13 -13.5202 0.51297E+00 -0.2899 12 K+ 0.15732E-03 -3.8032 0.13157E-03 -3.8809 0.83633E+00 -0.0776 13 Na+ 0.19963E-01 -1.6998 0.16664E-01 -1.7782 0.83475E+00 -0.0784 14 Mn++ 0.18878E-10 -10.7240 0.96919E-11 -11.0136 0.51339E+00 -0.2895 15 F- 0.65869E-06 -6.1813 0.54880E-06 -6.2606 0.83317E+00 -0.0793 16 HPO4-- 0.44952E-07 -7.3472 0.23315E-07 -7.6324 0.51866E+00 -0.2851 18 HSiO3- 0.10442E-01 -1.9812 0.87180E-02 -2.0596 0.83490E+00 -0.0784 19 Ca(HSiO3)+ 0.16673E-07 -7.7780 0.13947E-07 -7.8555 0.83651E+00 -0.0775 20 Mg(HSiO3)+ 0.32314E-11 -11.4906 0.27031E-11 -11.5681 0.83651E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66464E-16 -16.1774 0.55598E-16 -16.2549 0.83651E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52925E-05 -5.2763 0.44107E-05 -5.3555 0.83339E+00 -0.0792 26 CH4,aq 0.10358E-03 -3.9847 0.10322E-03 -3.9862 0.99653E+00 -0.0015 27 C2H6,aq 0.15781E-12 -12.8019 0.15726E-12 -12.8034 0.99653E+00 -0.0015 31 CO,aq 0.77391E-16 -16.1113 0.77391E-16 -16.1113 0.10000E+01 0.0000 32 CO2,aq 0.26691E-09 -9.5736 0.26598E-09 -9.5751 0.99653E+00 -0.0015 33 CO3-2 0.37812E-05 -5.4224 0.19567E-05 -5.7085 0.51748E+00 -0.2861 34 CaCO3,aq 0.17236E-08 -8.7636 0.17236E-08 -8.7636 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.35797E-11 -11.4462 0.29944E-11 -11.5237 0.83651E+00 -0.0775 36 CaCl+ 0.32140E-10 -10.4930 0.26885E-10 -10.5705 0.83651E+00 -0.0775 37 CaCl2,aq 0.15105E-14 -14.8209 0.15105E-14 -14.8209 0.10000E+01 0.0000 38 CaF+ 0.67289E-12 -12.1721 0.56288E-12 -12.2496 0.83651E+00 -0.0775 39 CaOH+ 0.80292E-07 -7.0953 0.67164E-07 -7.1729 0.83651E+00 -0.0775 40 CaSO4,aq 0.23206E-16 -16.6344 0.23206E-16 -16.6344 0.10000E+01 0.0000 41 HCl,aq 0.32303E-14 -14.4908 0.32303E-14 -14.4908 0.10000E+01 0.0000 45 HF,aq 0.28005E-12 -12.5528 0.28005E-12 -12.5528 0.10000E+01 0.0000 46 HF2- 0.62152E-19 -19.2065 0.51891E-19 -19.2849 0.83490E+00 -0.0784 48 FeCl+ 0.13507E-16 -16.8694 0.11299E-16 -16.9470 0.83651E+00 -0.0775 51 FeF+ 0.10120E-17 -17.9948 0.84653E-18 -18.0724 0.83651E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15757E-10 -10.8025 0.13181E-10 -10.8801 0.83651E+00 -0.0775 55 HFeO2- 0.35494E-07 -7.4498 0.29634E-07 -7.5282 0.83490E+00 -0.0784 56 FeO+ 0.11043E-16 -16.9569 0.92379E-17 -17.0344 0.83651E+00 -0.0775 58 FeO2- 0.40745E-09 -9.3899 0.34018E-09 -9.4683 0.83490E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56391E-09 -9.2488 0.56391E-09 -9.2488 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.25438E-14 -14.5945 0.21238E-14 -14.6729 0.83490E+00 -0.0784 65 MgCO3,aq 0.67278E-13 -13.1721 0.67278E-13 -13.1721 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.56962E-15 -15.2444 0.47649E-15 -15.3219 0.83651E+00 -0.0775 67 MgCl+ 0.45362E-14 -14.3433 0.37946E-14 -14.4208 0.83651E+00 -0.0775 68 MgF+ 0.38817E-15 -15.4110 0.32470E-15 -15.4885 0.83651E+00 -0.0775 69 MgOH+ 0.69189E-10 -10.1600 0.57877E-10 -10.2375 0.83651E+00 -0.0775 71 MnF+ 0.10710E-15 -15.9702 0.89590E-16 -16.0477 0.83651E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47000E-09 -9.3279 0.39316E-09 -9.4054 0.83651E+00 -0.0775 74 MnO2-2 0.20847E-10 -10.6810 0.10788E-10 -10.9671 0.51748E+00 -0.2861 75 HMnO2- 0.21102E-09 -9.6757 0.17618E-09 -9.7540 0.83490E+00 -0.0784 78 MnCl+ 0.16872E-13 -13.7728 0.14114E-13 -13.8504 0.83651E+00 -0.0775 80 NaCl,aq 0.13060E-05 -5.8841 0.13060E-05 -5.8841 0.10000E+01 0.0000 81 NaF,aq 0.21411E-08 -8.6694 0.21411E-08 -8.6694 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93004E-02 -2.0315 0.77508E-02 -2.1107 0.83339E+00 -0.0792 89 HPO3-2 0.16263E-14 -14.7888 0.84157E-15 -15.0749 0.51748E+00 -0.2861 91 H2PO3- 0.15067E-18 -18.8220 0.12580E-18 -18.9003 0.83490E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38365E-10 -10.4161 0.32061E-10 -10.4940 0.83570E+00 -0.0780 94 PO4-3 0.10548E-08 -8.9768 0.25519E-09 -9.5931 0.24193E+00 -0.6163 98 HP2O7-3 0.93652E-18 -18.0285 0.21590E-18 -18.6657 0.23053E+00 -0.6373 99 P2O7-4 0.90229E-17 -17.0447 0.69192E-18 -18.1599 0.76685E-01 -1.1153 100 H2S,aq 0.15304E-07 -7.8152 0.15251E-07 -7.8167 0.99653E+00 -0.0015 101 S2-2 0.16200E-13 -13.7905 0.83830E-14 -14.0766 0.51748E+00 -0.2861 107 SO3-2 0.29824E-17 -17.5254 0.15657E-17 -17.8053 0.52500E+00 -0.2798 109 HSO4- 0.89250E-19 -19.0494 0.74731E-19 -19.1265 0.83732E+00 -0.0771 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8874478E-10 -.2221680E-01 -.2235414E+02 0.0000 2 H2O 0.1000000E+01 0.5550498E+02 0.9981950E+06 0.0000 3 Cl- 0.2832476E-03 0.2845542E-03 0.1007070E+02 6.5014 4 SO4-- 0.2005946E-11 -.1064866E-03 -.1021144E+02 8.2723 5 HCO3- 0.1997174E-05 0.1093613E-03 0.6661284E+01 4.3503 6 HS- 0.7927517E-04 0.1857771E-03 0.6133306E+01 5.9484 7 Al+++ 0.9860487E-29 0.5292691E-05 0.1425557E+00 0.7390 8 H4SiO4 0.6959782E-03 0.1348753E-01 0.1294099E+04 -3.1574 9 Ca++ 0.1364690E-06 0.2351940E-06 0.9409667E-02 13.1018 10 Mg++ 0.2135000E-10 0.9384249E-10 0.2277520E-05 9.2942 11 Fe++ 0.5884422E-13 0.3613186E-07 0.2014337E-02 6.7350 12 K+ 0.1573162E-03 0.1580705E-03 0.6170093E+01 6.2467 13 Na+ 0.1996279E-01 0.2240977E-01 0.5142976E+03 8.3494 14 Mn++ 0.1887818E-10 0.2527045E-08 0.1385887E-03 9.2416 15 F- 0.6586880E-06 0.6608300E-06 0.1253255E-01 3.8670 16 HPO4-- 0.4495249E-07 0.4604566E-07 0.4411708E-02 12.6228 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279249E+02 -.1102721E-01 -.8278146E+02 0.0000000E+00 2 H2O -.7168322E+01 0.2754965E+02 -.3471797E+02 0.0000000E+00 3 Cl- 0.1412372E-03 0.1412372E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385952E+00 -.5285417E-04 0.1386481E+00 0.0000000E+00 5 HCO3- 0.5428100E-04 0.5428100E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385559E+00 0.9220964E-04 -.1386481E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2627003E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6694476E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1167375E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4657830E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793388E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7845759E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112299E-01 0.6265254E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254287E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3280000E-06 0.3280000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2285455E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.4399E-14 Mass of aqueous solution: 0.497213E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0005700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.160 73.22 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2616 -0.582 56.65 1.753 1.037 17.31 hedenbergite 0.6784E-01 -1.168 16.83 1.226 0.3081 4.610 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.7 2.450 5.156 97.29 tr.625ac.25prg.125 0.4284E-01 -1.368 36.62 1.564 0.6703 11.78 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338051 g Volume = 2210.779437 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0005700 moles log = -3.2441 Original solution: 1000.0103000 g Original solution / Rock added: 1754404.04 (Water/Rock Ratio), log = 6.2441 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1879 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8607E+00 0.9839 0.1006E+01 0.1022E+01 CO2,gas 0.2383E-07 1.0052 0.2846E-07 0.2831E-07 CH4,gas 0.1265E+00 1.0109 0.1519E+00 0.1503E+00 H2,gas 0.1279E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3545E-06 0.9954 0.4192E-06 0.4212E-06 S2,gas 0.2402E-28 1.0000 0.2853E-28 0.2853E-28 CO,gas 0.9708E-13 1.0000 0.1153E-12 0.1153E-12 SO3,gas 0.1840E-47 1.0000 0.2186E-47 0.2186E-47 SO2,gas 0.1088E-26 1.0000 0.1293E-26 0.1293E-26 HF,gas 0.5789E-15 1.0000 0.6876E-15 0.6876E-15 HCl,gas 0.4798E-17 1.0000 0.5700E-17 0.5700E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.84926E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.90 -9.24 -3.082 0.15785E+05 -7.546 3 CH4,gas 4.54 2.03 -2.52 -0.629 0.42982E+04 -0.818 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.31 -8.08 -4.038 0.13790E+05 -6.378 6 S2,gas -7.34 -37.58 -30.24 -4.653 0.51640E+05 -28.545 7 CO,gas 3.21 -11.42 -14.64 -4.504 0.24992E+05 -12.938 8 SO3,gas 17.12 -32.24 -49.36 -12.340 0.84280E+05 -47.660 9 SO2,gas 0.83 -27.76 -28.59 -7.623 0.48812E+05 -26.888 10 HF,gas 0.47 -16.39 -16.86 -8.431 0.28791E+05 -15.163 11 HCl,gas 5.19 -13.75 -18.94 -9.472 0.32345E+05 -17.244 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.54 -0.24 -0.020 0.41095E+03 38 aragonite 0.97 -2.80 -3.77 -1.257 0.64365E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.80 -3.61 -1.205 0.61723E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.94 -3.84 -1.096 0.65514E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.94 -3.39 -0.969 0.57936E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.57 -3.31 -1.104 0.56542E+04 147 pyrrhotiteFe0.875 -6.02 -8.97 -2.95 -1.086 0.50414E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.57 -3.16 -1.054 0.53970E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.07 -4.09 -1.362 0.69789E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0005700 MOLES New total amount of reactant added: 0.0005900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8656E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0005900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138459E-01 Osmotic coef. = 1.0162 True ionic strength = .2012535E-01 Chg. balance for total moles = -.8656E-10 Max. difference allowed = 0.1414E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88748E-10 -10.0518 0.74546E-10 -10.1276 0.83997E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28348E-03 -3.5475 0.23668E-03 -3.6258 0.83490E+00 -0.0784 4 SO4-- 0.20307E-11 -11.6924 0.10531E-11 -11.9775 0.51858E+00 -0.2852 5 HCO3- 0.20503E-05 -5.6882 0.17143E-05 -5.7659 0.83612E+00 -0.0777 6 HS- 0.80254E-04 -4.0955 0.67014E-04 -4.1738 0.83502E+00 -0.0783 7 Al+++ 0.98619E-29 -29.0060 0.22711E-29 -29.6438 0.23030E+00 -0.6377 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13648E-06 -6.8649 0.70255E-07 -7.1533 0.51476E+00 -0.2884 10 Mg++ 0.21352E-10 -10.6706 0.10941E-10 -10.9610 0.51240E+00 -0.2904 11 Fe++ 0.58849E-13 -13.2303 0.30187E-13 -13.5202 0.51296E+00 -0.2899 12 K+ 0.15732E-03 -3.8032 0.13157E-03 -3.8808 0.83632E+00 -0.0776 13 Na+ 0.19964E-01 -1.6998 0.16665E-01 -1.7782 0.83475E+00 -0.0784 14 Mn++ 0.18880E-10 -10.7240 0.96927E-11 -11.0136 0.51339E+00 -0.2896 15 F- 0.67475E-06 -6.1709 0.56218E-06 -6.2501 0.83317E+00 -0.0793 16 HPO4-- 0.44950E-07 -7.3473 0.23313E-07 -7.6324 0.51866E+00 -0.2851 18 HSiO3- 0.10442E-01 -1.9812 0.87176E-02 -2.0596 0.83490E+00 -0.0784 19 Ca(HSiO3)+ 0.16674E-07 -7.7780 0.13948E-07 -7.8555 0.83650E+00 -0.0775 20 Mg(HSiO3)+ 0.32315E-11 -11.4906 0.27032E-11 -11.5681 0.83650E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66467E-16 -16.1774 0.55600E-16 -16.2549 0.83650E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52924E-05 -5.2764 0.44106E-05 -5.3555 0.83339E+00 -0.0792 26 CH4,aq 0.10634E-03 -3.9733 0.10597E-03 -3.9748 0.99653E+00 -0.0015 27 C2H6,aq 0.16633E-12 -12.7790 0.16575E-12 -12.7805 0.99653E+00 -0.0015 31 CO,aq 0.79453E-16 -16.0999 0.79453E-16 -16.0999 0.10000E+01 0.0000 32 CO2,aq 0.27402E-09 -9.5622 0.27307E-09 -9.5637 0.99653E+00 -0.0015 33 CO3-2 0.38817E-05 -5.4110 0.20087E-05 -5.6971 0.51748E+00 -0.2861 34 CaCO3,aq 0.17695E-08 -8.7522 0.17695E-08 -8.7522 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.36752E-11 -11.4347 0.30743E-11 -11.5122 0.83650E+00 -0.0775 36 CaCl+ 0.32169E-10 -10.4926 0.26909E-10 -10.5701 0.83650E+00 -0.0775 37 CaCl2,aq 0.15131E-14 -14.8201 0.15131E-14 -14.8201 0.10000E+01 0.0000 38 CaF+ 0.68936E-12 -12.1616 0.57665E-12 -12.2391 0.83650E+00 -0.0775 39 CaOH+ 0.80295E-07 -7.0953 0.67167E-07 -7.1728 0.83650E+00 -0.0775 40 CaSO4,aq 0.23493E-16 -16.6291 0.23493E-16 -16.6291 0.10000E+01 0.0000 41 HCl,aq 0.32331E-14 -14.4904 0.32331E-14 -14.4904 0.10000E+01 0.0000 45 HF,aq 0.28689E-12 -12.5423 0.28689E-12 -12.5423 0.10000E+01 0.0000 46 HF2- 0.65223E-19 -19.1856 0.54455E-19 -19.2640 0.83490E+00 -0.0784 48 FeCl+ 0.13519E-16 -16.8690 0.11309E-16 -16.9466 0.83650E+00 -0.0775 51 FeF+ 0.10367E-17 -17.9843 0.86724E-18 -18.0619 0.83650E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15758E-10 -10.8025 0.13181E-10 -10.8800 0.83650E+00 -0.0775 55 HFeO2- 0.35493E-07 -7.4499 0.29633E-07 -7.5282 0.83490E+00 -0.0784 56 FeO+ 0.11044E-16 -16.9569 0.92382E-17 -17.0344 0.83650E+00 -0.0775 58 FeO2- 0.40743E-09 -9.3899 0.34016E-09 -9.4683 0.83490E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56440E-09 -9.2484 0.56440E-09 -9.2484 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.25752E-14 -14.5892 0.21500E-14 -14.6676 0.83490E+00 -0.0784 65 MgCO3,aq 0.69070E-13 -13.1607 0.69070E-13 -13.1607 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.58482E-15 -15.2330 0.48920E-15 -15.3105 0.83650E+00 -0.0775 67 MgCl+ 0.45404E-14 -14.3429 0.37980E-14 -14.4204 0.83650E+00 -0.0775 68 MgF+ 0.39766E-15 -15.4005 0.33265E-15 -15.4780 0.83650E+00 -0.0775 69 MgOH+ 0.69191E-10 -10.1599 0.57879E-10 -10.2375 0.83650E+00 -0.0775 71 MnF+ 0.10972E-15 -15.9597 0.91782E-16 -16.0372 0.83650E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47002E-09 -9.3279 0.39317E-09 -9.4054 0.83650E+00 -0.0775 74 MnO2-2 0.20846E-10 -10.6810 0.10787E-10 -10.9671 0.51748E+00 -0.2861 75 HMnO2- 0.21101E-09 -9.6757 0.17617E-09 -9.7541 0.83490E+00 -0.0784 78 MnCl+ 0.16888E-13 -13.7724 0.14127E-13 -13.8500 0.83650E+00 -0.0775 80 NaCl,aq 0.13071E-05 -5.8837 0.13071E-05 -5.8837 0.10000E+01 0.0000 81 NaF,aq 0.21933E-08 -8.6589 0.21933E-08 -8.6589 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.93001E-02 -2.0315 0.77506E-02 -2.1107 0.83339E+00 -0.0792 89 HPO3-2 0.16262E-14 -14.7888 0.84150E-15 -15.0749 0.51748E+00 -0.2861 91 H2PO3- 0.15067E-18 -18.8220 0.12579E-18 -18.9003 0.83490E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38363E-10 -10.4161 0.32060E-10 -10.4940 0.83569E+00 -0.0780 94 PO4-3 0.10547E-08 -8.9769 0.25516E-09 -9.5932 0.24193E+00 -0.6163 98 HP2O7-3 0.93644E-18 -18.0285 0.21588E-18 -18.6658 0.23053E+00 -0.6373 99 P2O7-4 0.90219E-17 -17.0447 0.69181E-18 -18.1600 0.76681E-01 -1.1153 100 H2S,aq 0.15493E-07 -7.8099 0.15440E-07 -7.8114 0.99653E+00 -0.0015 101 S2-2 0.16602E-13 -13.7798 0.85913E-14 -14.0659 0.51748E+00 -0.2861 107 SO3-2 0.30191E-17 -17.5201 0.15850E-17 -17.8000 0.52499E+00 -0.2798 109 HSO4- 0.90352E-19 -19.0441 0.75654E-19 -19.1212 0.83732E+00 -0.0771 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8874834E-10 -.2221622E-01 -.2235356E+02 0.0000 2 H2O 0.1000000E+01 0.5550498E+02 0.9981949E+06 0.0000 3 Cl- 0.2834840E-03 0.2847917E-03 0.1007911E+02 6.5017 4 SO4-- 0.2030658E-11 -.1092462E-03 -.1047606E+02 8.2776 5 HCO3- 0.2050312E-05 0.1122745E-03 0.6838729E+01 4.3617 6 HS- 0.8025407E-04 0.1895157E-03 0.6256733E+01 5.9537 7 Al+++ 0.9861860E-29 0.5292510E-05 0.1425508E+00 0.7390 8 H4SiO4 0.6959781E-03 0.1348717E-01 0.1294064E+04 -3.1574 9 Ca++ 0.1364809E-06 0.2352558E-06 0.9412139E-02 13.1018 10 Mg++ 0.2135185E-10 0.9384868E-10 0.2277670E-05 9.2942 11 Fe++ 0.5884933E-13 0.3613063E-07 0.2014268E-02 6.7350 12 K+ 0.1573225E-03 0.1580768E-03 0.6170340E+01 6.2467 13 Na+ 0.1996359E-01 0.2241058E-01 0.5143160E+03 8.3494 14 Mn++ 0.1887985E-10 0.2527062E-08 0.1385896E-03 9.2416 15 F- 0.6747530E-06 0.6769473E-06 0.1283821E-01 3.8775 16 HPO4-- 0.4494967E-07 0.4604274E-07 0.4411429E-02 12.6228 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279248E+02 -.1102693E-01 -.8278146E+02 0.0000000E+00 2 H2O -.7168306E+01 0.2754967E+02 -.3471798E+02 0.0000000E+00 3 Cl- 0.1413552E-03 0.1413552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385953E+00 -.5422389E-04 0.1386496E+00 0.0000000E+00 5 HCO3- 0.5572700E-04 0.5572700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385555E+00 0.9406536E-04 -.1386496E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2626916E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6694303E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1167683E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4658141E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793329E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7846078E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112340E-01 0.6265254E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254297E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3360000E-06 0.3360000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2285313E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.7591E-14 Mass of aqueous solution: 0.497213E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0005900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.160 73.22 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2616 -0.582 56.64 1.753 1.037 17.31 hedenbergite 0.6783E-01 -1.169 16.83 1.226 0.3081 4.610 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.6 2.450 5.156 97.29 tr.625ac.25prg.125 0.4285E-01 -1.368 36.63 1.564 0.6705 11.79 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338057 g Volume = 2210.779492 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0005900 moles log = -3.2291 Original solution: 1000.0103000 g Original solution / Rock added: 1694932.71 (Water/Rock Ratio), log = 6.2292 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1920 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8578E+00 0.9839 0.1006E+01 0.1022E+01 CO2,gas 0.2438E-07 1.0052 0.2922E-07 0.2906E-07 CH4,gas 0.1295E+00 1.0109 0.1560E+00 0.1543E+00 H2,gas 0.1275E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3577E-06 0.9954 0.4244E-06 0.4264E-06 S2,gas 0.2453E-28 1.0000 0.2924E-28 0.2924E-28 CO,gas 0.9933E-13 1.0000 0.1184E-12 0.1184E-12 SO3,gas 0.1856E-47 1.0000 0.2213E-47 0.2213E-47 SO2,gas 0.1098E-26 1.0000 0.1309E-26 0.1309E-26 HF,gas 0.5910E-15 1.0000 0.7044E-15 0.7044E-15 HCl,gas 0.4786E-17 1.0000 0.5705E-17 0.5705E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.72794E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.89 -9.23 -3.078 0.15766E+05 -7.534 3 CH4,gas 4.54 2.04 -2.51 -0.626 0.42787E+04 -0.807 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.30 -8.07 -4.036 0.13781E+05 -6.372 6 S2,gas -7.34 -37.57 -30.23 -4.651 0.51622E+05 -28.534 7 CO,gas 3.21 -11.41 -14.63 -4.500 0.24973E+05 -12.927 8 SO3,gas 17.12 -32.23 -49.35 -12.339 0.84271E+05 -47.655 9 SO2,gas 0.83 -27.75 -28.58 -7.622 0.48803E+05 -26.883 10 HF,gas 0.47 -16.38 -16.85 -8.426 0.28773E+05 -15.152 11 HCl,gas 5.19 -13.75 -18.94 -9.471 0.32344E+05 -17.244 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.53 -0.23 -0.019 0.39306E+03 38 aragonite 0.97 -2.79 -3.76 -1.253 0.64170E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.79 -3.60 -1.201 0.61528E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.93 -3.83 -1.093 0.65319E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.93 -3.38 -0.966 0.57741E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.57 -3.31 -1.102 0.56451E+04 147 pyrrhotiteFe0.875 -6.02 -8.96 -2.95 -1.084 0.50323E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.57 -3.16 -1.052 0.53879E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.06 -4.08 -1.361 0.69698E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0005900 MOLES New total amount of reactant added: 0.0006100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8653E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0006100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138293E-01 Osmotic coef. = 1.0195 True ionic strength = .2012626E-01 Chg. balance for total moles = -.8653E-10 Max. difference allowed = 0.1415E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88752E-10 -10.0518 0.74549E-10 -10.1276 0.83997E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28372E-03 -3.5471 0.23688E-03 -3.6255 0.83490E+00 -0.0784 4 SO4-- 0.20554E-11 -11.6871 0.10659E-11 -11.9723 0.51858E+00 -0.2852 5 HCO3- 0.21034E-05 -5.6771 0.17587E-05 -5.7548 0.83612E+00 -0.0777 6 HS- 0.81233E-04 -4.0903 0.67831E-04 -4.1686 0.83502E+00 -0.0783 7 Al+++ 0.98632E-29 -29.0060 0.22714E-29 -29.6437 0.23029E+00 -0.6377 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13649E-06 -6.8649 0.70260E-07 -7.1533 0.51475E+00 -0.2884 10 Mg++ 0.21354E-10 -10.6705 0.10941E-10 -10.9609 0.51239E+00 -0.2904 11 Fe++ 0.58854E-13 -13.2302 0.30190E-13 -13.5201 0.51295E+00 -0.2899 12 K+ 0.15733E-03 -3.8032 0.13158E-03 -3.8808 0.83632E+00 -0.0776 13 Na+ 0.19964E-01 -1.6997 0.16665E-01 -1.7782 0.83474E+00 -0.0784 14 Mn++ 0.18882E-10 -10.7240 0.96934E-11 -11.0135 0.51338E+00 -0.2896 15 F- 0.69082E-06 -6.1606 0.57557E-06 -6.2399 0.83317E+00 -0.0793 16 HPO4-- 0.44947E-07 -7.3473 0.23312E-07 -7.6324 0.51865E+00 -0.2851 18 HSiO3- 0.10441E-01 -1.9812 0.87173E-02 -2.0596 0.83490E+00 -0.0784 19 Ca(HSiO3)+ 0.16675E-07 -7.7779 0.13948E-07 -7.8555 0.83650E+00 -0.0775 20 Mg(HSiO3)+ 0.32317E-11 -11.4906 0.27033E-11 -11.5681 0.83650E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66469E-16 -16.1774 0.55602E-16 -16.2549 0.83650E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52922E-05 -5.2764 0.44104E-05 -5.3555 0.83338E+00 -0.0792 26 CH4,aq 0.10910E-03 -3.9622 0.10872E-03 -3.9637 0.99653E+00 -0.0015 27 C2H6,aq 0.17507E-12 -12.7568 0.17447E-12 -12.7583 0.99653E+00 -0.0015 31 CO,aq 0.81515E-16 -16.0888 0.81515E-16 -16.0888 0.10000E+01 0.0000 32 CO2,aq 0.28113E-09 -9.5511 0.28016E-09 -9.5526 0.99653E+00 -0.0015 33 CO3-2 0.39821E-05 -5.3999 0.20607E-05 -5.6860 0.51747E+00 -0.2861 34 CaCO3,aq 0.18154E-08 -8.7410 0.18154E-08 -8.7410 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.37707E-11 -11.4236 0.31542E-11 -11.5011 0.83650E+00 -0.0775 36 CaCl+ 0.32198E-10 -10.4922 0.26934E-10 -10.5697 0.83650E+00 -0.0775 37 CaCl2,aq 0.15157E-14 -14.8194 0.15157E-14 -14.8194 0.10000E+01 0.0000 38 CaF+ 0.70582E-12 -12.1513 0.59042E-12 -12.2288 0.83650E+00 -0.0775 39 CaOH+ 0.80298E-07 -7.0953 0.67169E-07 -7.1728 0.83650E+00 -0.0775 40 CaSO4,aq 0.23780E-16 -16.6238 0.23780E-16 -16.6238 0.10000E+01 0.0000 41 HCl,aq 0.32359E-14 -14.4900 0.32359E-14 -14.4900 0.10000E+01 0.0000 45 HF,aq 0.29373E-12 -12.5320 0.29373E-12 -12.5320 0.10000E+01 0.0000 46 HF2- 0.68368E-19 -19.1651 0.57080E-19 -19.2435 0.83490E+00 -0.0784 48 FeCl+ 0.13532E-16 -16.8687 0.11319E-16 -16.9462 0.83650E+00 -0.0775 51 FeF+ 0.10615E-17 -17.9741 0.88795E-18 -18.0516 0.83650E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15758E-10 -10.8025 0.13182E-10 -10.8800 0.83650E+00 -0.0775 55 HFeO2- 0.35492E-07 -7.4499 0.29632E-07 -7.5282 0.83490E+00 -0.0784 56 FeO+ 0.11044E-16 -16.9569 0.92386E-17 -17.0344 0.83650E+00 -0.0775 58 FeO2- 0.40742E-09 -9.3900 0.34015E-09 -9.4683 0.83490E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56489E-09 -9.2480 0.56489E-09 -9.2480 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.26066E-14 -14.5839 0.21763E-14 -14.6623 0.83490E+00 -0.0784 65 MgCO3,aq 0.70863E-13 -13.1496 0.70863E-13 -13.1496 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.60002E-15 -15.2218 0.50192E-15 -15.2994 0.83650E+00 -0.0775 67 MgCl+ 0.45445E-14 -14.3425 0.38015E-14 -14.4200 0.83650E+00 -0.0775 68 MgF+ 0.40716E-15 -15.3902 0.34059E-15 -15.4678 0.83650E+00 -0.0775 69 MgOH+ 0.69194E-10 -10.1599 0.57881E-10 -10.2375 0.83650E+00 -0.0775 71 MnF+ 0.11234E-15 -15.9495 0.93974E-16 -16.0270 0.83650E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47004E-09 -9.3279 0.39319E-09 -9.4054 0.83650E+00 -0.0775 74 MnO2-2 0.20844E-10 -10.6810 0.10786E-10 -10.9671 0.51747E+00 -0.2861 75 HMnO2- 0.21101E-09 -9.6757 0.17617E-09 -9.7541 0.83490E+00 -0.0784 78 MnCl+ 0.16903E-13 -13.7720 0.14140E-13 -13.8496 0.83650E+00 -0.0775 80 NaCl,aq 0.13082E-05 -5.8833 0.13082E-05 -5.8833 0.10000E+01 0.0000 81 NaF,aq 0.22456E-08 -8.6487 0.22456E-08 -8.6487 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92998E-02 -2.0315 0.77503E-02 -2.1107 0.83338E+00 -0.0792 89 HPO3-2 0.16261E-14 -14.7889 0.84144E-15 -15.0750 0.51747E+00 -0.2861 91 H2PO3- 0.15066E-18 -18.8220 0.12579E-18 -18.9004 0.83490E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38362E-10 -10.4161 0.32059E-10 -10.4941 0.83569E+00 -0.0780 94 PO4-3 0.10546E-08 -8.9769 0.25513E-09 -9.5932 0.24192E+00 -0.6163 98 HP2O7-3 0.93636E-18 -18.0286 0.21585E-18 -18.6658 0.23052E+00 -0.6373 99 P2O7-4 0.90210E-17 -17.0447 0.69171E-18 -18.1601 0.76678E-01 -1.1153 100 H2S,aq 0.15683E-07 -7.8046 0.15628E-07 -7.8061 0.99653E+00 -0.0015 101 S2-2 0.17010E-13 -13.7693 0.88021E-14 -14.0554 0.51747E+00 -0.2861 107 SO3-2 0.30559E-17 -17.5149 0.16043E-17 -17.7947 0.52499E+00 -0.2799 109 HSO4- 0.91454E-19 -19.0388 0.76576E-19 -19.1159 0.83732E+00 -0.0771 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8875191E-10 -.2221564E-01 -.2235298E+02 0.0000 2 H2O 0.1000000E+01 0.5550499E+02 0.9981949E+06 0.0000 3 Cl- 0.2837204E-03 0.2850292E-03 0.1008752E+02 6.5021 4 SO4-- 0.2055369E-11 -.1120057E-03 -.1074068E+02 8.2828 5 HCO3- 0.2103447E-05 0.1151877E-03 0.7016174E+01 4.3728 6 HS- 0.8123298E-04 0.1932544E-03 0.6380161E+01 5.9590 7 Al+++ 0.9863232E-29 0.5292330E-05 0.1425459E+00 0.7390 8 H4SiO4 0.6959781E-03 0.1348682E-01 0.1294030E+04 -3.1574 9 Ca++ 0.1364927E-06 0.2353176E-06 0.9414611E-02 13.1018 10 Mg++ 0.2135371E-10 0.9385487E-10 0.2277820E-05 9.2942 11 Fe++ 0.5885445E-13 0.3612940E-07 0.2014199E-02 6.7350 12 K+ 0.1573288E-03 0.1580832E-03 0.6170586E+01 6.2467 13 Na+ 0.1996439E-01 0.2241138E-01 0.5143345E+03 8.3494 14 Mn++ 0.1888153E-10 0.2527079E-08 0.1385905E-03 9.2416 15 F- 0.6908179E-06 0.6930646E-06 0.1314388E-01 3.8877 16 HPO4-- 0.4494685E-07 0.4603983E-07 0.4411150E-02 12.6227 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279248E+02 -.1102665E-01 -.8278146E+02 0.0000000E+00 2 H2O -.7168289E+01 0.2754969E+02 -.3471798E+02 0.0000000E+00 3 Cl- 0.1414732E-03 0.1414732E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385954E+00 -.5559361E-04 0.1386510E+00 0.0000000E+00 5 HCO3- 0.5717300E-04 0.5717300E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385551E+00 0.9592108E-04 -.1386510E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2626828E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6694130E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1167990E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4658451E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793269E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7846398E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112380E-01 0.6265253E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254306E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3440000E-06 0.3440000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2285170E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1929E-14 Mass of aqueous solution: 0.497213E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0006100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.160 73.22 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2615 -0.582 56.64 1.753 1.037 17.31 hedenbergite 0.6782E-01 -1.169 16.83 1.226 0.3081 4.609 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.6 2.450 5.156 97.29 tr.625ac.25prg.125 0.4286E-01 -1.368 36.64 1.564 0.6707 11.79 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338064 g Volume = 2210.779548 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0006100 moles log = -3.2147 Original solution: 1000.0103000 g Original solution / Rock added: 1639361.15 (Water/Rock Ratio), log = 6.2147 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1960 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8549E+00 0.9838 0.1006E+01 0.1023E+01 CO2,gas 0.2493E-07 1.0051 0.2997E-07 0.2982E-07 CH4,gas 0.1324E+00 1.0108 0.1600E+00 0.1583E+00 H2,gas 0.1271E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3609E-06 0.9954 0.4296E-06 0.4316E-06 S2,gas 0.2505E-28 1.0000 0.2996E-28 0.2996E-28 CO,gas 0.1016E-12 1.0000 0.1215E-12 0.1215E-12 SO3,gas 0.1873E-47 1.0000 0.2240E-47 0.2240E-47 SO2,gas 0.1108E-26 1.0000 0.1325E-26 0.1325E-26 HF,gas 0.6030E-15 1.0000 0.7212E-15 0.7212E-15 HCl,gas 0.4774E-17 1.0000 0.5710E-17 0.5710E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.88 -9.22 -3.074 0.15747E+05 -7.523 3 CH4,gas 4.54 2.05 -2.49 -0.624 0.42597E+04 -0.796 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.30 -8.07 -4.033 0.13772E+05 -6.367 6 S2,gas -7.34 -37.56 -30.22 -4.650 0.51604E+05 -28.523 7 CO,gas 3.21 -11.40 -14.61 -4.497 0.24954E+05 -12.916 8 SO3,gas 17.12 -32.23 -49.35 -12.337 0.84262E+05 -47.650 9 SO2,gas 0.83 -27.74 -28.58 -7.620 0.48794E+05 -26.878 10 HF,gas 0.47 -16.37 -16.84 -8.420 0.28755E+05 -15.142 11 HCl,gas 5.19 -13.75 -18.94 -9.471 0.32344E+05 -17.243 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.52 -0.22 -0.018 0.37558E+03 38 aragonite 0.97 -2.78 -3.75 -1.249 0.63980E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.78 -3.59 -1.197 0.61338E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.92 -3.81 -1.090 0.65129E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.92 -3.37 -0.963 0.57551E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.56 -3.30 -1.100 0.56361E+04 147 pyrrhotiteFe0.875 -6.02 -8.96 -2.94 -1.082 0.50233E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.56 -3.15 -1.050 0.53789E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.05 -4.08 -1.359 0.69608E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0006100 MOLES New total amount of reactant added: 0.0006300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8653E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0006300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138126E-01 Osmotic coef. = 1.0230 True ionic strength = .2012717E-01 Chg. balance for total moles = -.8653E-10 Max. difference allowed = 0.1416E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88755E-10 -10.0518 0.74552E-10 -10.1275 0.83997E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28396E-03 -3.5467 0.23707E-03 -3.6251 0.83489E+00 -0.0784 4 SO4-- 0.20801E-11 -11.6819 0.10787E-11 -11.9671 0.51857E+00 -0.2852 5 HCO3- 0.21566E-05 -5.6662 0.18032E-05 -5.7440 0.83612E+00 -0.0777 6 HS- 0.82212E-04 -4.0851 0.68648E-04 -4.1634 0.83502E+00 -0.0783 7 Al+++ 0.98646E-29 -29.0059 0.22717E-29 -29.6437 0.23028E+00 -0.6377 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13650E-06 -6.8649 0.70266E-07 -7.1533 0.51475E+00 -0.2884 10 Mg++ 0.21356E-10 -10.6705 0.10942E-10 -10.9609 0.51238E+00 -0.2904 11 Fe++ 0.58860E-13 -13.2302 0.30192E-13 -13.5201 0.51295E+00 -0.2899 12 K+ 0.15734E-03 -3.8032 0.13158E-03 -3.8808 0.83632E+00 -0.0776 13 Na+ 0.19965E-01 -1.6997 0.16666E-01 -1.7782 0.83474E+00 -0.0784 14 Mn++ 0.18883E-10 -10.7239 0.96942E-11 -11.0135 0.51337E+00 -0.2896 15 F- 0.70688E-06 -6.1507 0.58895E-06 -6.2299 0.83317E+00 -0.0793 16 HPO4-- 0.44944E-07 -7.3473 0.23310E-07 -7.6325 0.51865E+00 -0.2851 18 HSiO3- 0.10441E-01 -1.9813 0.87170E-02 -2.0596 0.83489E+00 -0.0784 19 Ca(HSiO3)+ 0.16675E-07 -7.7779 0.13949E-07 -7.8555 0.83650E+00 -0.0775 20 Mg(HSiO3)+ 0.32318E-11 -11.4906 0.27034E-11 -11.5681 0.83650E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66472E-16 -16.1774 0.55604E-16 -16.2549 0.83650E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52920E-05 -5.2764 0.44102E-05 -5.3555 0.83338E+00 -0.0792 26 CH4,aq 0.11186E-03 -3.9513 0.11147E-03 -3.9528 0.99653E+00 -0.0015 27 C2H6,aq 0.18404E-12 -12.7351 0.18340E-12 -12.7366 0.99653E+00 -0.0015 31 CO,aq 0.83577E-16 -16.0779 0.83577E-16 -16.0779 0.10000E+01 0.0000 32 CO2,aq 0.28824E-09 -9.5402 0.28724E-09 -9.5418 0.99653E+00 -0.0015 33 CO3-2 0.40826E-05 -5.3891 0.21126E-05 -5.6752 0.51747E+00 -0.2861 34 CaCO3,aq 0.18613E-08 -8.7302 0.18613E-08 -8.7302 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.38663E-11 -11.4127 0.32341E-11 -11.4902 0.83650E+00 -0.0775 36 CaCl+ 0.32227E-10 -10.4918 0.26958E-10 -10.5693 0.83650E+00 -0.0775 37 CaCl2,aq 0.15184E-14 -14.8186 0.15184E-14 -14.8186 0.10000E+01 0.0000 38 CaF+ 0.72229E-12 -12.1413 0.60419E-12 -12.2188 0.83650E+00 -0.0775 39 CaOH+ 0.80301E-07 -7.0953 0.67172E-07 -7.1728 0.83650E+00 -0.0775 40 CaSO4,aq 0.24068E-16 -16.6186 0.24068E-16 -16.6186 0.10000E+01 0.0000 41 HCl,aq 0.32387E-14 -14.4896 0.32387E-14 -14.4896 0.10000E+01 0.0000 45 HF,aq 0.30058E-12 -12.5220 0.30058E-12 -12.5220 0.10000E+01 0.0000 46 HF2- 0.71587E-19 -19.1452 0.59768E-19 -19.2235 0.83489E+00 -0.0784 48 FeCl+ 0.13544E-16 -16.8683 0.11329E-16 -16.9458 0.83650E+00 -0.0775 51 FeF+ 0.10863E-17 -17.9641 0.90866E-18 -18.0416 0.83650E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15759E-10 -10.8025 0.13182E-10 -10.8800 0.83650E+00 -0.0775 55 HFeO2- 0.35491E-07 -7.4499 0.29631E-07 -7.5283 0.83489E+00 -0.0784 56 FeO+ 0.11045E-16 -16.9568 0.92389E-17 -17.0344 0.83650E+00 -0.0775 58 FeO2- 0.40740E-09 -9.3900 0.34014E-09 -9.4683 0.83489E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56538E-09 -9.2477 0.56538E-09 -9.2477 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.26380E-14 -14.5787 0.22025E-14 -14.6571 0.83489E+00 -0.0784 65 MgCO3,aq 0.72655E-13 -13.1387 0.72655E-13 -13.1387 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.61522E-15 -15.2110 0.51463E-15 -15.2885 0.83650E+00 -0.0775 67 MgCl+ 0.45486E-14 -14.3421 0.38049E-14 -14.4197 0.83650E+00 -0.0775 68 MgF+ 0.41666E-15 -15.3802 0.34854E-15 -15.4578 0.83650E+00 -0.0775 69 MgOH+ 0.69197E-10 -10.1599 0.57883E-10 -10.2374 0.83650E+00 -0.0775 71 MnF+ 0.11496E-15 -15.9394 0.96167E-16 -16.0170 0.83650E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47006E-09 -9.3278 0.39320E-09 -9.4054 0.83650E+00 -0.0775 74 MnO2-2 0.20843E-10 -10.6810 0.10786E-10 -10.9672 0.51747E+00 -0.2861 75 HMnO2- 0.21100E-09 -9.6757 0.17616E-09 -9.7541 0.83489E+00 -0.0784 78 MnCl+ 0.16919E-13 -13.7716 0.14152E-13 -13.8492 0.83650E+00 -0.0775 80 NaCl,aq 0.13094E-05 -5.8829 0.13094E-05 -5.8829 0.10000E+01 0.0000 81 NaF,aq 0.22979E-08 -8.6387 0.22979E-08 -8.6387 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92994E-02 -2.0315 0.77500E-02 -2.1107 0.83338E+00 -0.0792 89 HPO3-2 0.16260E-14 -14.7889 0.84138E-15 -15.0750 0.51747E+00 -0.2861 91 H2PO3- 0.15066E-18 -18.8220 0.12578E-18 -18.9004 0.83489E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38361E-10 -10.4161 0.32058E-10 -10.4941 0.83569E+00 -0.0780 94 PO4-3 0.10545E-08 -8.9769 0.25510E-09 -9.5933 0.24192E+00 -0.6163 98 HP2O7-3 0.93628E-18 -18.0286 0.21583E-18 -18.6659 0.23051E+00 -0.6373 99 P2O7-4 0.90201E-17 -17.0448 0.69161E-18 -18.1601 0.76674E-01 -1.1154 100 H2S,aq 0.15872E-07 -7.7994 0.15817E-07 -7.8009 0.99653E+00 -0.0015 101 S2-2 0.17422E-13 -13.7589 0.90154E-14 -14.0450 0.51747E+00 -0.2861 107 SO3-2 0.30926E-17 -17.5097 0.16236E-17 -17.7895 0.52498E+00 -0.2799 109 HSO4- 0.92556E-19 -19.0336 0.77499E-19 -19.1107 0.83732E+00 -0.0771 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8875547E-10 -.2221507E-01 -.2235240E+02 0.0000 2 H2O 0.1000000E+01 0.5550499E+02 0.9981949E+06 0.0000 3 Cl- 0.2839568E-03 0.2852667E-03 0.1009592E+02 6.5024 4 SO4-- 0.2080078E-11 -.1147653E-03 -.1100530E+02 8.2880 5 HCO3- 0.2156578E-05 0.1181009E-03 0.7193619E+01 4.3836 6 HS- 0.8221189E-04 0.1969930E-03 0.6503589E+01 5.9642 7 Al+++ 0.9864605E-29 0.5292149E-05 0.1425411E+00 0.7390 8 H4SiO4 0.6959781E-03 0.1348646E-01 0.1293995E+04 -3.1574 9 Ca++ 0.1365045E-06 0.2353794E-06 0.9417083E-02 13.1018 10 Mg++ 0.2135556E-10 0.9386286E-10 0.2278013E-05 9.2942 11 Fe++ 0.5885956E-13 0.3612817E-07 0.2014131E-02 6.7350 12 K+ 0.1573352E-03 0.1580895E-03 0.6170832E+01 6.2467 13 Na+ 0.1996520E-01 0.2241218E-01 0.5143529E+03 8.3494 14 Mn++ 0.1888321E-10 0.2527096E-08 0.1385914E-03 9.2416 15 F- 0.7068829E-06 0.7091818E-06 0.1344954E-01 3.8976 16 HPO4-- 0.4494404E-07 0.4603692E-07 0.4410870E-02 12.6226 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279248E+02 -.1102637E-01 -.8278145E+02 0.0000000E+00 2 H2O -.7168273E+01 0.2754971E+02 -.3471799E+02 0.0000000E+00 3 Cl- 0.1415912E-03 0.1415912E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385955E+00 -.5696334E-04 0.1386525E+00 0.0000000E+00 5 HCO3- 0.5861900E-04 0.5861900E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385547E+00 0.9777681E-04 -.1386525E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2626740E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6693958E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1168298E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4658851E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793209E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7846717E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112421E-01 0.6265253E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254315E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3520000E-06 0.3520000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2285027E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1307E-13 Mass of aqueous solution: 0.497214E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0006300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.160 73.22 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2615 -0.583 56.63 1.753 1.037 17.31 hedenbergite 0.6781E-01 -1.169 16.82 1.226 0.3080 4.608 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.6 2.450 5.156 97.29 tr.625ac.25prg.125 0.4287E-01 -1.368 36.65 1.564 0.6709 11.79 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338071 g Volume = 2210.779603 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0006300 moles log = -3.2007 Original solution: 1000.0103000 g Original solution / Rock added: 1587317.94 (Water/Rock Ratio), log = 6.2007 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2001 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8521E+00 0.9838 0.1006E+01 0.1023E+01 CO2,gas 0.2548E-07 1.0051 0.3073E-07 0.3058E-07 CH4,gas 0.1353E+00 1.0108 0.1641E+00 0.1623E+00 H2,gas 0.1266E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3640E-06 0.9953 0.4348E-06 0.4368E-06 S2,gas 0.2557E-28 1.0000 0.3069E-28 0.3069E-28 CO,gas 0.1038E-12 1.0000 0.1245E-12 0.1245E-12 SO3,gas 0.1889E-47 1.0000 0.2267E-47 0.2267E-47 SO2,gas 0.1117E-26 1.0000 0.1341E-26 0.1341E-26 HF,gas 0.6150E-15 1.0000 0.7380E-15 0.7380E-15 HCl,gas 0.4762E-17 1.0000 0.5715E-17 0.5715E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.60662E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.72794E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.87 -9.21 -3.070 0.15728E+05 -7.512 3 CH4,gas 4.54 2.06 -2.48 -0.621 0.42412E+04 -0.785 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.29 -8.06 -4.030 0.13763E+05 -6.362 6 S2,gas -7.34 -37.55 -30.21 -4.648 0.51586E+05 -28.513 7 CO,gas 3.21 -11.39 -14.60 -4.493 0.24935E+05 -12.905 8 SO3,gas 17.12 -32.22 -49.34 -12.336 0.84253E+05 -47.645 9 SO2,gas 0.83 -27.74 -28.57 -7.619 0.48785E+05 -26.873 10 HF,gas 0.47 -16.36 -16.83 -8.415 0.28738E+05 -15.132 11 HCl,gas 5.19 -13.75 -18.94 -9.471 0.32343E+05 -17.243 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.51 -0.21 -0.017 0.35851E+03 38 aragonite 0.97 -2.77 -3.74 -1.245 0.63795E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.77 -3.58 -1.194 0.61152E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.91 -3.80 -1.087 0.64943E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.91 -3.36 -0.960 0.57366E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.56 -3.30 -1.099 0.56272E+04 147 pyrrhotiteFe0.875 -6.02 -8.95 -2.94 -1.080 0.50144E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.56 -3.14 -1.048 0.53700E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.05 -4.07 -1.357 0.69519E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0006300 MOLES New total amount of reactant added: 0.0006500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8652E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0006500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137960E-01 Osmotic coef. = 1.0267 True ionic strength = .2012808E-01 Chg. balance for total moles = -.8652E-10 Max. difference allowed = 0.1417E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88759E-10 -10.0518 0.74554E-10 -10.1275 0.83996E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28419E-03 -3.5464 0.23727E-03 -3.6248 0.83489E+00 -0.0784 4 SO4-- 0.21048E-11 -11.6768 0.10915E-11 -11.9620 0.51857E+00 -0.2852 5 HCO3- 0.22097E-05 -5.6557 0.18476E-05 -5.7334 0.83612E+00 -0.0777 6 HS- 0.83191E-04 -4.0799 0.69465E-04 -4.1582 0.83501E+00 -0.0783 7 Al+++ 0.98660E-29 -29.0059 0.22719E-29 -29.6436 0.23028E+00 -0.6377 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13652E-06 -6.8648 0.70271E-07 -7.1532 0.51474E+00 -0.2884 10 Mg++ 0.21357E-10 -10.6705 0.10943E-10 -10.9609 0.51238E+00 -0.2904 11 Fe++ 0.58865E-13 -13.2301 0.30194E-13 -13.5201 0.51294E+00 -0.2899 12 K+ 0.15734E-03 -3.8032 0.13159E-03 -3.8808 0.83632E+00 -0.0776 13 Na+ 0.19966E-01 -1.6997 0.16666E-01 -1.7782 0.83474E+00 -0.0784 14 Mn++ 0.18885E-10 -10.7239 0.96949E-11 -11.0135 0.51337E+00 -0.2896 15 F- 0.72295E-06 -6.1409 0.60233E-06 -6.2202 0.83316E+00 -0.0793 16 HPO4-- 0.44941E-07 -7.3474 0.23308E-07 -7.6325 0.51864E+00 -0.2851 18 HSiO3- 0.10440E-01 -1.9813 0.87167E-02 -2.0596 0.83489E+00 -0.0784 19 Ca(HSiO3)+ 0.16676E-07 -7.7779 0.13950E-07 -7.8554 0.83650E+00 -0.0775 20 Mg(HSiO3)+ 0.32319E-11 -11.4905 0.27035E-11 -11.5681 0.83650E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66475E-16 -16.1773 0.55606E-16 -16.2549 0.83650E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52918E-05 -5.2764 0.44101E-05 -5.3556 0.83338E+00 -0.0792 26 CH4,aq 0.11462E-03 -3.9407 0.11422E-03 -3.9423 0.99653E+00 -0.0015 27 C2H6,aq 0.19323E-12 -12.7139 0.19256E-12 -12.7154 0.99653E+00 -0.0015 31 CO,aq 0.85639E-16 -16.0673 0.85639E-16 -16.0673 0.10000E+01 0.0000 32 CO2,aq 0.29535E-09 -9.5297 0.29433E-09 -9.5312 0.99653E+00 -0.0015 33 CO3-2 0.41831E-05 -5.3785 0.21646E-05 -5.6646 0.51746E+00 -0.2861 34 CaCO3,aq 0.19072E-08 -8.7196 0.19072E-08 -8.7196 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.39618E-11 -11.4021 0.33141E-11 -11.4796 0.83650E+00 -0.0775 36 CaCl+ 0.32256E-10 -10.4914 0.26982E-10 -10.5689 0.83650E+00 -0.0775 37 CaCl2,aq 0.15210E-14 -14.8179 0.15210E-14 -14.8179 0.10000E+01 0.0000 38 CaF+ 0.73876E-12 -12.1315 0.61797E-12 -12.2090 0.83650E+00 -0.0775 39 CaOH+ 0.80305E-07 -7.0953 0.67174E-07 -7.1728 0.83650E+00 -0.0775 40 CaSO4,aq 0.24355E-16 -16.6134 0.24355E-16 -16.6134 0.10000E+01 0.0000 41 HCl,aq 0.32415E-14 -14.4892 0.32415E-14 -14.4892 0.10000E+01 0.0000 45 HF,aq 0.30742E-12 -12.5123 0.30742E-12 -12.5123 0.10000E+01 0.0000 46 HF2- 0.74881E-19 -19.1256 0.62517E-19 -19.2040 0.83489E+00 -0.0784 48 FeCl+ 0.13556E-16 -16.8679 0.11340E-16 -16.9454 0.83650E+00 -0.0775 51 FeF+ 0.11110E-17 -17.9543 0.92938E-18 -18.0318 0.83650E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15760E-10 -10.8025 0.13183E-10 -10.8800 0.83650E+00 -0.0775 55 HFeO2- 0.35489E-07 -7.4499 0.29630E-07 -7.5283 0.83489E+00 -0.0784 56 FeO+ 0.11045E-16 -16.9568 0.92393E-17 -17.0344 0.83650E+00 -0.0775 58 FeO2- 0.40739E-09 -9.3900 0.34013E-09 -9.4684 0.83489E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56587E-09 -9.2473 0.56587E-09 -9.2473 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.26694E-14 -14.5736 0.22287E-14 -14.6520 0.83489E+00 -0.0784 65 MgCO3,aq 0.74447E-13 -13.1282 0.74447E-13 -13.1282 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.63042E-15 -15.2004 0.52735E-15 -15.2779 0.83650E+00 -0.0775 67 MgCl+ 0.45527E-14 -14.3417 0.38084E-14 -14.4193 0.83650E+00 -0.0775 68 MgF+ 0.42616E-15 -15.3704 0.35648E-15 -15.4480 0.83650E+00 -0.0775 69 MgOH+ 0.69200E-10 -10.1599 0.57885E-10 -10.2374 0.83650E+00 -0.0775 71 MnF+ 0.11758E-15 -15.9296 0.98359E-16 -16.0072 0.83650E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47008E-09 -9.3278 0.39322E-09 -9.4054 0.83650E+00 -0.0775 74 MnO2-2 0.20842E-10 -10.6811 0.10785E-10 -10.9672 0.51746E+00 -0.2861 75 HMnO2- 0.21099E-09 -9.6757 0.17616E-09 -9.7541 0.83489E+00 -0.0784 78 MnCl+ 0.16934E-13 -13.7712 0.14165E-13 -13.8488 0.83650E+00 -0.0775 80 NaCl,aq 0.13105E-05 -5.8826 0.13105E-05 -5.8826 0.10000E+01 0.0000 81 NaF,aq 0.23502E-08 -8.6289 0.23502E-08 -8.6289 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92991E-02 -2.0316 0.77497E-02 -2.1107 0.83338E+00 -0.0792 89 HPO3-2 0.16259E-14 -14.7889 0.84132E-15 -15.0750 0.51746E+00 -0.2861 91 H2PO3- 0.15065E-18 -18.8220 0.12578E-18 -18.9004 0.83489E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38359E-10 -10.4161 0.32056E-10 -10.4941 0.83569E+00 -0.0780 94 PO4-3 0.10544E-08 -8.9770 0.25508E-09 -9.5933 0.24191E+00 -0.6163 98 HP2O7-3 0.93620E-18 -18.0286 0.21580E-18 -18.6659 0.23051E+00 -0.6373 99 P2O7-4 0.90192E-17 -17.0448 0.69150E-18 -18.1602 0.76670E-01 -1.1154 100 H2S,aq 0.16062E-07 -7.7942 0.16006E-07 -7.7957 0.99653E+00 -0.0015 101 S2-2 0.17840E-13 -13.7486 0.92314E-14 -14.0347 0.51746E+00 -0.2861 107 SO3-2 0.31293E-17 -17.5045 0.16428E-17 -17.7844 0.52498E+00 -0.2799 109 HSO4- 0.93658E-19 -19.0285 0.78421E-19 -19.1056 0.83731E+00 -0.0771 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8875904E-10 -.2221449E-01 -.2235182E+02 0.0000 2 H2O 0.1000000E+01 0.5550499E+02 0.9981948E+06 0.0000 3 Cl- 0.2841932E-03 0.2855043E-03 0.1010433E+02 6.5028 4 SO4-- 0.2104786E-11 -.1175248E-03 -.1126993E+02 8.2931 5 HCO3- 0.2209706E-05 0.1210141E-03 0.7371064E+01 4.3941 6 HS- 0.8319079E-04 0.2007317E-03 0.6627018E+01 5.9693 7 Al+++ 0.9865977E-29 0.5291968E-05 0.1425362E+00 0.7390 8 H4SiO4 0.6959780E-03 0.1348610E-01 0.1293961E+04 -3.1574 9 Ca++ 0.1365164E-06 0.2354413E-06 0.9419555E-02 13.1018 10 Mg++ 0.2135742E-10 0.9386816E-10 0.2278142E-05 9.2942 11 Fe++ 0.5886468E-13 0.3612694E-07 0.2014062E-02 6.7350 12 K+ 0.1573415E-03 0.1580958E-03 0.6171078E+01 6.2467 13 Na+ 0.1996600E-01 0.2241299E-01 0.5143713E+03 8.3494 14 Mn++ 0.1888488E-10 0.2527113E-08 0.1385923E-03 9.2416 15 F- 0.7229478E-06 0.7252991E-06 0.1375520E-01 3.9074 16 HPO4-- 0.4494122E-07 0.4603401E-07 0.4410591E-02 12.6226 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279248E+02 -.1102610E-01 -.8278145E+02 0.0000000E+00 2 H2O -.7168257E+01 0.2754973E+02 -.3471799E+02 0.0000000E+00 3 Cl- 0.1417092E-03 0.1417092E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385956E+00 -.5833308E-04 0.1386540E+00 0.0000000E+00 5 HCO3- 0.6006500E-04 0.6006500E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385543E+00 0.9963255E-04 -.1386540E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2626652E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6693785E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1168606E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4659118E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793150E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7847037E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112462E-01 0.6265252E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254325E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3600000E-06 0.3600000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2284884E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.7452E-14 Mass of aqueous solution: 0.497214E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0006500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.160 73.23 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2615 -0.583 56.62 1.753 1.037 17.30 hedenbergite 0.6780E-01 -1.169 16.82 1.226 0.3080 4.608 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.6 2.450 5.156 97.28 tr.625ac.25prg.125 0.4289E-01 -1.368 36.66 1.564 0.6711 11.80 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338077 g Volume = 2210.779659 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0006500 moles log = -3.1871 Original solution: 1000.0103000 g Original solution / Rock added: 1538477.38 (Water/Rock Ratio), log = 6.1871 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2041 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8492E+00 0.9837 0.1006E+01 0.1023E+01 CO2,gas 0.2602E-07 1.0051 0.3149E-07 0.3133E-07 CH4,gas 0.1381E+00 1.0107 0.1681E+00 0.1663E+00 H2,gas 0.1262E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3671E-06 0.9953 0.4400E-06 0.4421E-06 S2,gas 0.2610E-28 1.0000 0.3143E-28 0.3143E-28 CO,gas 0.1060E-12 1.0000 0.1276E-12 0.1276E-12 SO3,gas 0.1905E-47 1.0000 0.2294E-47 0.2294E-47 SO2,gas 0.1127E-26 1.0000 0.1357E-26 0.1357E-26 HF,gas 0.6269E-15 1.0000 0.7548E-15 0.7548E-15 HCl,gas 0.4750E-17 1.0000 0.5720E-17 0.5720E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.86 -9.20 -3.067 0.15710E+05 -7.502 3 CH4,gas 4.54 2.07 -2.47 -0.618 0.42232E+04 -0.774 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.29 -8.06 -4.028 0.13755E+05 -6.357 6 S2,gas -7.34 -37.54 -30.20 -4.646 0.51569E+05 -28.503 7 CO,gas 3.21 -11.38 -14.59 -4.490 0.24917E+05 -12.894 8 SO3,gas 17.12 -32.22 -49.34 -12.335 0.84244E+05 -47.639 9 SO2,gas 0.83 -27.73 -28.57 -7.618 0.48776E+05 -26.867 10 HF,gas 0.47 -16.35 -16.82 -8.411 0.28722E+05 -15.122 11 HCl,gas 5.19 -13.75 -18.94 -9.471 0.32342E+05 -17.243 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.50 -0.20 -0.017 0.34182E+03 38 aragonite 0.97 -2.76 -3.73 -1.242 0.63614E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.76 -3.57 -1.190 0.60972E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.90 -3.79 -1.084 0.64763E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.90 -3.35 -0.957 0.57185E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.55 -3.29 -1.097 0.56184E+04 147 pyrrhotiteFe0.875 -6.02 -8.95 -2.93 -1.078 0.50056E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.55 -3.14 -1.047 0.53612E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.04 -4.07 -1.355 0.69431E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0006500 MOLES New total amount of reactant added: 0.0006700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8653E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0006700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137794E-01 Osmotic coef. = 1.0307 True ionic strength = .2012899E-01 Chg. balance for total moles = -.8653E-10 Max. difference allowed = 0.1418E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88763E-10 -10.0518 0.74557E-10 -10.1275 0.83996E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28443E-03 -3.5460 0.23747E-03 -3.6244 0.83489E+00 -0.0784 4 SO4-- 0.21295E-11 -11.6717 0.11043E-11 -11.9569 0.51856E+00 -0.2852 5 HCO3- 0.22628E-05 -5.6453 0.18920E-05 -5.7231 0.83611E+00 -0.0777 6 HS- 0.84170E-04 -4.0748 0.70283E-04 -4.1532 0.83501E+00 -0.0783 7 Al+++ 0.98674E-29 -29.0058 0.22722E-29 -29.6436 0.23027E+00 -0.6378 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13653E-06 -6.8648 0.70276E-07 -7.1532 0.51474E+00 -0.2884 10 Mg++ 0.21359E-10 -10.6704 0.10944E-10 -10.9608 0.51237E+00 -0.2904 11 Fe++ 0.58870E-13 -13.2301 0.30196E-13 -13.5200 0.51293E+00 -0.2899 12 K+ 0.15735E-03 -3.8031 0.13159E-03 -3.8808 0.83631E+00 -0.0776 13 Na+ 0.19967E-01 -1.6997 0.16667E-01 -1.7781 0.83474E+00 -0.0785 14 Mn++ 0.18887E-10 -10.7238 0.96956E-11 -11.0134 0.51336E+00 -0.2896 15 F- 0.73901E-06 -6.1313 0.61572E-06 -6.2106 0.83316E+00 -0.0793 16 HPO4-- 0.44938E-07 -7.3474 0.23307E-07 -7.6325 0.51863E+00 -0.2851 18 HSiO3- 0.10440E-01 -1.9813 0.87163E-02 -2.0597 0.83489E+00 -0.0784 19 Ca(HSiO3)+ 0.16677E-07 -7.7779 0.13950E-07 -7.8554 0.83649E+00 -0.0775 20 Mg(HSiO3)+ 0.32320E-11 -11.4905 0.27036E-11 -11.5681 0.83649E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66477E-16 -16.1773 0.55608E-16 -16.2549 0.83649E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52916E-05 -5.2764 0.44099E-05 -5.3556 0.83337E+00 -0.0792 26 CH4,aq 0.11738E-03 -3.9304 0.11697E-03 -3.9319 0.99653E+00 -0.0015 27 C2H6,aq 0.20265E-12 -12.6933 0.20195E-12 -12.6948 0.99653E+00 -0.0015 31 CO,aq 0.87701E-16 -16.0570 0.87701E-16 -16.0570 0.10000E+01 0.0000 32 CO2,aq 0.30246E-09 -9.5193 0.30141E-09 -9.5208 0.99653E+00 -0.0015 33 CO3-2 0.42835E-05 -5.3682 0.22165E-05 -5.6543 0.51745E+00 -0.2861 34 CaCO3,aq 0.19532E-08 -8.7093 0.19532E-08 -8.7093 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.40574E-11 -11.3918 0.33940E-11 -11.4693 0.83649E+00 -0.0775 36 CaCl+ 0.32286E-10 -10.4910 0.27007E-10 -10.5685 0.83649E+00 -0.0775 37 CaCl2,aq 0.15236E-14 -14.8171 0.15236E-14 -14.8171 0.10000E+01 0.0000 38 CaF+ 0.75523E-12 -12.1219 0.63175E-12 -12.1995 0.83649E+00 -0.0775 39 CaOH+ 0.80308E-07 -7.0952 0.67177E-07 -7.1728 0.83649E+00 -0.0775 40 CaSO4,aq 0.24643E-16 -16.6083 0.24643E-16 -16.6083 0.10000E+01 0.0000 41 HCl,aq 0.32443E-14 -14.4889 0.32443E-14 -14.4889 0.10000E+01 0.0000 45 HF,aq 0.31426E-12 -12.5027 0.31426E-12 -12.5027 0.10000E+01 0.0000 46 HF2- 0.78248E-19 -19.1065 0.65329E-19 -19.1849 0.83489E+00 -0.0784 48 FeCl+ 0.13568E-16 -16.8675 0.11350E-16 -16.9450 0.83649E+00 -0.0775 51 FeF+ 0.11358E-17 -17.9447 0.95010E-18 -18.0222 0.83649E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15760E-10 -10.8024 0.13183E-10 -10.8800 0.83649E+00 -0.0775 55 HFeO2- 0.35488E-07 -7.4499 0.29629E-07 -7.5283 0.83489E+00 -0.0784 56 FeO+ 0.11046E-16 -16.9568 0.92396E-17 -17.0343 0.83649E+00 -0.0775 58 FeO2- 0.40738E-09 -9.3900 0.34011E-09 -9.4684 0.83489E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56636E-09 -9.2469 0.56636E-09 -9.2469 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.27008E-14 -14.5685 0.22549E-14 -14.6469 0.83489E+00 -0.0784 65 MgCO3,aq 0.76240E-13 -13.1178 0.76240E-13 -13.1178 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.64563E-15 -15.1900 0.54006E-15 -15.2676 0.83649E+00 -0.0775 67 MgCl+ 0.45569E-14 -14.3413 0.38118E-14 -14.4189 0.83649E+00 -0.0775 68 MgF+ 0.43566E-15 -15.3608 0.36443E-15 -15.4384 0.83649E+00 -0.0775 69 MgOH+ 0.69203E-10 -10.1599 0.57887E-10 -10.2374 0.83649E+00 -0.0775 71 MnF+ 0.12021E-15 -15.9201 0.10055E-15 -15.9976 0.83649E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47010E-09 -9.3278 0.39323E-09 -9.4053 0.83649E+00 -0.0775 74 MnO2-2 0.20841E-10 -10.6811 0.10784E-10 -10.9672 0.51745E+00 -0.2861 75 HMnO2- 0.21099E-09 -9.6757 0.17615E-09 -9.7541 0.83489E+00 -0.0784 78 MnCl+ 0.16949E-13 -13.7708 0.14178E-13 -13.8484 0.83649E+00 -0.0775 80 NaCl,aq 0.13116E-05 -5.8822 0.13116E-05 -5.8822 0.10000E+01 0.0000 81 NaF,aq 0.24026E-08 -8.6193 0.24026E-08 -8.6193 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92988E-02 -2.0316 0.77494E-02 -2.1107 0.83337E+00 -0.0792 89 HPO3-2 0.16258E-14 -14.7889 0.84125E-15 -15.0751 0.51745E+00 -0.2861 91 H2PO3- 0.15065E-18 -18.8220 0.12578E-18 -18.9004 0.83489E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38358E-10 -10.4161 0.32055E-10 -10.4941 0.83568E+00 -0.0780 94 PO4-3 0.10543E-08 -8.9770 0.25505E-09 -9.5934 0.24190E+00 -0.6164 98 HP2O7-3 0.93613E-18 -18.0287 0.21578E-18 -18.6660 0.23050E+00 -0.6373 99 P2O7-4 0.90183E-17 -17.0449 0.69140E-18 -18.1603 0.76667E-01 -1.1154 100 H2S,aq 0.16251E-07 -7.7891 0.16195E-07 -7.7906 0.99653E+00 -0.0015 101 S2-2 0.18262E-13 -13.7384 0.94498E-14 -14.0246 0.51745E+00 -0.2861 107 SO3-2 0.31661E-17 -17.4995 0.16621E-17 -17.7793 0.52497E+00 -0.2799 109 HSO4- 0.94760E-19 -19.0234 0.79344E-19 -19.1005 0.83731E+00 -0.0771 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8876260E-10 -.2221391E-01 -.2235123E+02 0.0000 2 H2O 0.1000000E+01 0.5550500E+02 0.9981948E+06 0.0000 3 Cl- 0.2844296E-03 0.2857418E-03 0.1011273E+02 6.5031 4 SO4-- 0.2129492E-11 -.1202844E-03 -.1153455E+02 8.2981 5 HCO3- 0.2262831E-05 0.1239273E-03 0.7548508E+01 4.4044 6 HS- 0.8416969E-04 0.2044703E-03 0.6750446E+01 5.9744 7 Al+++ 0.9867350E-29 0.5291788E-05 0.1425313E+00 0.7390 8 H4SiO4 0.6959780E-03 0.1348574E-01 0.1293926E+04 -3.1574 9 Ca++ 0.1365282E-06 0.2355031E-06 0.9422027E-02 13.1018 10 Mg++ 0.2135928E-10 0.9387525E-10 0.2278314E-05 9.2942 11 Fe++ 0.5886979E-13 0.3612571E-07 0.2013993E-02 6.7350 12 K+ 0.1573478E-03 0.1581021E-03 0.6171325E+01 6.2467 13 Na+ 0.1996680E-01 0.2241379E-01 0.5143897E+03 8.3494 14 Mn++ 0.1888656E-10 0.2527130E-08 0.1385933E-03 9.2416 15 F- 0.7390127E-06 0.7414163E-06 0.1406086E-01 3.9169 16 HPO4-- 0.4493840E-07 0.4603110E-07 0.4410312E-02 12.6225 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279248E+02 -.1102582E-01 -.8278145E+02 0.0000000E+00 2 H2O -.7168240E+01 0.2754976E+02 -.3471800E+02 0.0000000E+00 3 Cl- 0.1418272E-03 0.1418272E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385957E+00 -.5970283E-04 0.1386554E+00 0.0000000E+00 5 HCO3- 0.6151100E-04 0.6151100E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385539E+00 0.1014883E-03 -.1386554E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2626565E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6693612E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1168913E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4659473E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793090E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7847356E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112503E-01 0.6265252E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254334E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3680000E-06 0.3680000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2284741E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1397E-13 Mass of aqueous solution: 0.497215E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0006700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.8 2.450 5.160 73.23 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2614 -0.583 56.61 1.753 1.036 17.30 hedenbergite 0.6779E-01 -1.169 16.82 1.226 0.3079 4.607 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.6 2.450 5.156 97.28 tr.625ac.25prg.125 0.4290E-01 -1.368 36.67 1.564 0.6713 11.80 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338084 g Volume = 2210.779714 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0006700 moles log = -3.1739 Original solution: 1000.0103000 g Original solution / Rock added: 1492552.69 (Water/Rock Ratio), log = 6.1739 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2082 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8464E+00 0.9837 0.1006E+01 0.1023E+01 CO2,gas 0.2656E-07 1.0050 0.3225E-07 0.3209E-07 CH4,gas 0.1410E+00 1.0107 0.1722E+00 0.1704E+00 H2,gas 0.1258E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3702E-06 0.9953 0.4452E-06 0.4473E-06 S2,gas 0.2663E-28 1.0000 0.3217E-28 0.3217E-28 CO,gas 0.1082E-12 1.0000 0.1307E-12 0.1307E-12 SO3,gas 0.1921E-47 1.0000 0.2321E-47 0.2321E-47 SO2,gas 0.1136E-26 1.0000 0.1373E-26 0.1373E-26 HF,gas 0.6387E-15 1.0000 0.7716E-15 0.7716E-15 HCl,gas 0.4738E-17 1.0000 0.5725E-17 0.5725E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.85 -9.19 -3.063 0.15692E+05 -7.491 3 CH4,gas 4.54 2.08 -2.46 -0.616 0.42055E+04 -0.764 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.28 -8.05 -4.025 0.13746E+05 -6.351 6 S2,gas -7.34 -37.53 -30.19 -4.645 0.51551E+05 -28.493 7 CO,gas 3.21 -11.37 -14.58 -4.487 0.24900E+05 -12.884 8 SO3,gas 17.12 -32.21 -49.33 -12.333 0.84235E+05 -47.634 9 SO2,gas 0.83 -27.73 -28.56 -7.616 0.48768E+05 -26.862 10 HF,gas 0.47 -16.34 -16.81 -8.406 0.28705E+05 -15.113 11 HCl,gas 5.19 -13.75 -18.94 -9.471 0.32342E+05 -17.242 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.49 -0.19 -0.016 0.32550E+03 38 aragonite 0.97 -2.75 -3.72 -1.238 0.63437E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.75 -3.56 -1.187 0.60795E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.88 -3.78 -1.081 0.64586E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.88 -3.34 -0.954 0.57009E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.55 -3.29 -1.095 0.56097E+04 147 pyrrhotiteFe0.875 -6.02 -8.94 -2.93 -1.076 0.49969E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.55 -3.13 -1.045 0.53525E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.04 -4.06 -1.354 0.69344E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0006700 MOLES New total amount of reactant added: 0.0006900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8653E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0006900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137628E-01 Osmotic coef. = 1.0350 True ionic strength = .2012990E-01 Chg. balance for total moles = -.8653E-10 Max. difference allowed = 0.1419E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88766E-10 -10.0518 0.74560E-10 -10.1275 0.83996E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28467E-03 -3.5457 0.23766E-03 -3.6240 0.83489E+00 -0.0784 4 SO4-- 0.21542E-11 -11.6667 0.11171E-11 -11.9519 0.51855E+00 -0.2852 5 HCO3- 0.23160E-05 -5.6353 0.19364E-05 -5.7130 0.83611E+00 -0.0777 6 HS- 0.85149E-04 -4.0698 0.71100E-04 -4.1481 0.83501E+00 -0.0783 7 Al+++ 0.98687E-29 -29.0057 0.22724E-29 -29.6435 0.23026E+00 -0.6378 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13654E-06 -6.8647 0.70281E-07 -7.1532 0.51473E+00 -0.2884 10 Mg++ 0.21361E-10 -10.6704 0.10945E-10 -10.9608 0.51236E+00 -0.2904 11 Fe++ 0.58875E-13 -13.2301 0.30199E-13 -13.5200 0.51293E+00 -0.2899 12 K+ 0.15735E-03 -3.8031 0.13160E-03 -3.8808 0.83631E+00 -0.0776 13 Na+ 0.19968E-01 -1.6997 0.16668E-01 -1.7781 0.83473E+00 -0.0785 14 Mn++ 0.18888E-10 -10.7238 0.96964E-11 -11.0134 0.51336E+00 -0.2896 15 F- 0.75508E-06 -6.1220 0.62910E-06 -6.2013 0.83316E+00 -0.0793 16 HPO4-- 0.44936E-07 -7.3474 0.23305E-07 -7.6326 0.51863E+00 -0.2851 18 HSiO3- 0.10440E-01 -1.9813 0.87160E-02 -2.0597 0.83489E+00 -0.0784 19 Ca(HSiO3)+ 0.16677E-07 -7.7779 0.13951E-07 -7.8554 0.83649E+00 -0.0775 20 Mg(HSiO3)+ 0.32322E-11 -11.4905 0.27037E-11 -11.5680 0.83649E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66480E-16 -16.1773 0.55610E-16 -16.2548 0.83649E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52915E-05 -5.2764 0.44098E-05 -5.3556 0.83337E+00 -0.0792 26 CH4,aq 0.12014E-03 -3.9203 0.11972E-03 -3.9218 0.99653E+00 -0.0015 27 C2H6,aq 0.21229E-12 -12.6731 0.21156E-12 -12.6746 0.99653E+00 -0.0015 31 CO,aq 0.89763E-16 -16.0469 0.89763E-16 -16.0469 0.10000E+01 0.0000 32 CO2,aq 0.30958E-09 -9.5092 0.30850E-09 -9.5107 0.99653E+00 -0.0015 33 CO3-2 0.43840E-05 -5.3581 0.22685E-05 -5.6443 0.51745E+00 -0.2861 34 CaCO3,aq 0.19991E-08 -8.6992 0.19991E-08 -8.6992 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.41529E-11 -11.3816 0.34739E-11 -11.4592 0.83649E+00 -0.0775 36 CaCl+ 0.32315E-10 -10.4906 0.27031E-10 -10.5681 0.83649E+00 -0.0775 37 CaCl2,aq 0.15263E-14 -14.8164 0.15263E-14 -14.8164 0.10000E+01 0.0000 38 CaF+ 0.77171E-12 -12.1125 0.64553E-12 -12.1901 0.83649E+00 -0.0775 39 CaOH+ 0.80311E-07 -7.0952 0.67179E-07 -7.1728 0.83649E+00 -0.0775 40 CaSO4,aq 0.24930E-16 -16.6033 0.24930E-16 -16.6033 0.10000E+01 0.0000 41 HCl,aq 0.32471E-14 -14.4885 0.32471E-14 -14.4885 0.10000E+01 0.0000 45 HF,aq 0.32110E-12 -12.4934 0.32110E-12 -12.4934 0.10000E+01 0.0000 46 HF2- 0.81690E-19 -19.0878 0.68202E-19 -19.1662 0.83489E+00 -0.0784 48 FeCl+ 0.13581E-16 -16.8671 0.11360E-16 -16.9446 0.83649E+00 -0.0775 51 FeF+ 0.11606E-17 -17.9353 0.97082E-18 -18.0129 0.83649E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15761E-10 -10.8024 0.13184E-10 -10.8800 0.83649E+00 -0.0775 55 HFeO2- 0.35487E-07 -7.4499 0.29628E-07 -7.5283 0.83489E+00 -0.0784 56 FeO+ 0.11046E-16 -16.9568 0.92399E-17 -17.0343 0.83649E+00 -0.0775 58 FeO2- 0.40736E-09 -9.3900 0.34010E-09 -9.4684 0.83489E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56685E-09 -9.2465 0.56685E-09 -9.2465 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.27323E-14 -14.5635 0.22811E-14 -14.6419 0.83489E+00 -0.0784 65 MgCO3,aq 0.78032E-13 -13.1077 0.78032E-13 -13.1077 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.66083E-15 -15.1799 0.55278E-15 -15.2574 0.83649E+00 -0.0775 67 MgCl+ 0.45610E-14 -14.3409 0.38152E-14 -14.4185 0.83649E+00 -0.0775 68 MgF+ 0.44517E-15 -15.3515 0.37238E-15 -15.4290 0.83649E+00 -0.0775 69 MgOH+ 0.69205E-10 -10.1599 0.57890E-10 -10.2374 0.83649E+00 -0.0775 71 MnF+ 0.12283E-15 -15.9107 0.10275E-15 -15.9882 0.83649E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47012E-09 -9.3278 0.39325E-09 -9.4053 0.83649E+00 -0.0775 74 MnO2-2 0.20839E-10 -10.6811 0.10783E-10 -10.9672 0.51745E+00 -0.2861 75 HMnO2- 0.21098E-09 -9.6758 0.17614E-09 -9.7541 0.83489E+00 -0.0784 78 MnCl+ 0.16965E-13 -13.7705 0.14191E-13 -13.8480 0.83649E+00 -0.0775 80 NaCl,aq 0.13128E-05 -5.8818 0.13128E-05 -5.8818 0.10000E+01 0.0000 81 NaF,aq 0.24549E-08 -8.6100 0.24549E-08 -8.6100 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92985E-02 -2.0316 0.77491E-02 -2.1107 0.83337E+00 -0.0792 89 HPO3-2 0.16257E-14 -14.7890 0.84119E-15 -15.0751 0.51745E+00 -0.2861 91 H2PO3- 0.15064E-18 -18.8220 0.12577E-18 -18.9004 0.83489E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38357E-10 -10.4162 0.32054E-10 -10.4941 0.83568E+00 -0.0780 94 PO4-3 0.10542E-08 -8.9771 0.25502E-09 -9.5934 0.24190E+00 -0.6164 98 HP2O7-3 0.93605E-18 -18.0287 0.21576E-18 -18.6660 0.23050E+00 -0.6373 99 P2O7-4 0.90173E-17 -17.0449 0.69130E-18 -18.1603 0.76663E-01 -1.1154 100 H2S,aq 0.16441E-07 -7.7841 0.16384E-07 -7.7856 0.99653E+00 -0.0015 101 S2-2 0.18690E-13 -13.7284 0.96709E-14 -14.0145 0.51745E+00 -0.2861 107 SO3-2 0.32028E-17 -17.4945 0.16813E-17 -17.7743 0.52496E+00 -0.2799 109 HSO4- 0.95862E-19 -19.0184 0.80266E-19 -19.0955 0.83731E+00 -0.0771 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8876617E-10 -.2221334E-01 -.2235065E+02 0.0000 2 H2O 0.1000000E+01 0.5550500E+02 0.9981948E+06 0.0000 3 Cl- 0.2846659E-03 0.2859793E-03 0.1012114E+02 6.5035 4 SO4-- 0.2154197E-11 -.1230440E-03 -.1179918E+02 8.3031 5 HCO3- 0.2315952E-05 0.1268405E-03 0.7725952E+01 4.4145 6 HS- 0.8514859E-04 0.2082090E-03 0.6873875E+01 5.9794 7 Al+++ 0.9868723E-29 0.5291607E-05 0.1425264E+00 0.7390 8 H4SiO4 0.6959779E-03 0.1348539E-01 0.1293892E+04 -3.1574 9 Ca++ 0.1365401E-06 0.2355649E-06 0.9424499E-02 13.1018 10 Mg++ 0.2136113E-10 0.9388144E-10 0.2278464E-05 9.2942 11 Fe++ 0.5887491E-13 0.3612448E-07 0.2013924E-02 6.7350 12 K+ 0.1573541E-03 0.1581084E-03 0.6171571E+01 6.2467 13 Na+ 0.1996761E-01 0.2241460E-01 0.5144081E+03 8.3494 14 Mn++ 0.1888824E-10 0.2527147E-08 0.1385942E-03 9.2416 15 F- 0.7550775E-06 0.7575335E-06 0.1436651E-01 3.9262 16 HPO4-- 0.4493558E-07 0.4602818E-07 0.4410032E-02 12.6224 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279247E+02 -.1102554E-01 -.8278145E+02 0.0000000E+00 2 H2O -.7168224E+01 0.2754978E+02 -.3471800E+02 0.0000000E+00 3 Cl- 0.1419452E-03 0.1419452E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385958E+00 -.6107259E-04 0.1386569E+00 0.0000000E+00 5 HCO3- 0.6295700E-04 0.6295700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385535E+00 0.1033441E-03 -.1386569E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2626477E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6693440E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1169221E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4659784E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1793030E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7847676E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112543E-01 0.6265252E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254343E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3760000E-06 0.3760000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2284598E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1409E-13 Mass of aqueous solution: 0.497215E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0006900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.9 2.450 5.160 73.23 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2614 -0.583 56.60 1.753 1.036 17.30 hedenbergite 0.6778E-01 -1.169 16.82 1.226 0.3079 4.606 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.6 2.450 5.156 97.28 tr.625ac.25prg.125 0.4291E-01 -1.367 36.68 1.564 0.6715 11.81 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338091 g Volume = 2210.779769 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0006900 moles log = -3.1612 Original solution: 1000.0103000 g Original solution / Rock added: 1449290.29 (Water/Rock Ratio), log = 6.1612 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2122 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8436E+00 0.9836 0.1006E+01 0.1023E+01 CO2,gas 0.2709E-07 1.0050 0.3301E-07 0.3284E-07 CH4,gas 0.1438E+00 1.0106 0.1762E+00 0.1744E+00 H2,gas 0.1254E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3733E-06 0.9953 0.4504E-06 0.4525E-06 S2,gas 0.2716E-28 1.0000 0.3293E-28 0.3293E-28 CO,gas 0.1103E-12 1.0000 0.1338E-12 0.1338E-12 SO3,gas 0.1937E-47 1.0000 0.2348E-47 0.2348E-47 SO2,gas 0.1146E-26 1.0000 0.1389E-26 0.1389E-26 HF,gas 0.6504E-15 1.0000 0.7884E-15 0.7884E-15 HCl,gas 0.4726E-17 1.0000 0.5730E-17 0.5730E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.60662E-10 50 daphnite 28.97 28.97 0.00 0.000 0.72794E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.60662E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.84 -9.18 -3.060 0.15675E+05 -7.481 3 CH4,gas 4.54 2.09 -2.45 -0.613 0.41883E+04 -0.754 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.28 -8.05 -4.023 0.13737E+05 -6.346 6 S2,gas -7.34 -37.52 -30.18 -4.643 0.51534E+05 -28.482 7 CO,gas 3.21 -11.36 -14.57 -4.484 0.24882E+05 -12.874 8 SO3,gas 17.12 -32.21 -49.33 -12.332 0.84227E+05 -47.629 9 SO2,gas 0.83 -27.72 -28.56 -7.615 0.48759E+05 -26.857 10 HF,gas 0.47 -16.33 -16.80 -8.401 0.28689E+05 -15.103 11 HCl,gas 5.19 -13.75 -18.94 -9.470 0.32341E+05 -17.242 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.48 -0.18 -0.015 0.30953E+03 38 aragonite 0.97 -2.74 -3.71 -1.235 0.63265E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.74 -3.55 -1.183 0.60623E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.87 -3.77 -1.078 0.64414E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.87 -3.33 -0.951 0.56836E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.54 -3.28 -1.093 0.56011E+04 147 pyrrhotiteFe0.875 -6.02 -8.94 -2.92 -1.074 0.49883E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.54 -3.13 -1.043 0.53439E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.03 -4.06 -1.352 0.69258E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0006900 MOLES New total amount of reactant added: 0.0007100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8650E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0007100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137461E-01 Osmotic coef. = 1.0397 True ionic strength = .2013081E-01 Chg. balance for total moles = -.8650E-10 Max. difference allowed = 0.1421E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88770E-10 -10.0517 0.74563E-10 -10.1275 0.83996E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28490E-03 -3.5453 0.23786E-03 -3.6237 0.83488E+00 -0.0784 4 SO4-- 0.21789E-11 -11.6618 0.11299E-11 -11.9470 0.51855E+00 -0.2852 5 HCO3- 0.23691E-05 -5.6254 0.19808E-05 -5.7032 0.83611E+00 -0.0777 6 HS- 0.86127E-04 -4.0649 0.71917E-04 -4.1432 0.83501E+00 -0.0783 7 Al+++ 0.98701E-29 -29.0057 0.22727E-29 -29.6435 0.23026E+00 -0.6378 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13655E-06 -6.8647 0.70286E-07 -7.1531 0.51472E+00 -0.2884 10 Mg++ 0.21363E-10 -10.6703 0.10946E-10 -10.9608 0.51236E+00 -0.2904 11 Fe++ 0.58880E-13 -13.2300 0.30201E-13 -13.5200 0.51292E+00 -0.2899 12 K+ 0.15736E-03 -3.8031 0.13160E-03 -3.8807 0.83631E+00 -0.0776 13 Na+ 0.19968E-01 -1.6997 0.16668E-01 -1.7781 0.83473E+00 -0.0785 14 Mn++ 0.18890E-10 -10.7238 0.96971E-11 -11.0134 0.51335E+00 -0.2896 15 F- 0.77114E-06 -6.1129 0.64248E-06 -6.1921 0.83316E+00 -0.0793 16 HPO4-- 0.44933E-07 -7.3474 0.23303E-07 -7.6326 0.51862E+00 -0.2852 18 HSiO3- 0.10439E-01 -1.9813 0.87157E-02 -2.0597 0.83488E+00 -0.0784 19 Ca(HSiO3)+ 0.16678E-07 -7.7779 0.13951E-07 -7.8554 0.83649E+00 -0.0775 20 Mg(HSiO3)+ 0.32323E-11 -11.4905 0.27038E-11 -11.5680 0.83649E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66483E-16 -16.1773 0.55612E-16 -16.2548 0.83649E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52913E-05 -5.2764 0.44096E-05 -5.3556 0.83337E+00 -0.0792 26 CH4,aq 0.12290E-03 -3.9105 0.12247E-03 -3.9120 0.99653E+00 -0.0015 27 C2H6,aq 0.22216E-12 -12.6533 0.22139E-12 -12.6548 0.99653E+00 -0.0015 31 CO,aq 0.91824E-16 -16.0370 0.91824E-16 -16.0370 0.10000E+01 0.0000 32 CO2,aq 0.31669E-09 -9.4994 0.31559E-09 -9.5009 0.99653E+00 -0.0015 33 CO3-2 0.44844E-05 -5.3483 0.23204E-05 -5.6344 0.51744E+00 -0.2861 34 CaCO3,aq 0.20450E-08 -8.6893 0.20450E-08 -8.6893 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.42485E-11 -11.3718 0.35538E-11 -11.4493 0.83649E+00 -0.0775 36 CaCl+ 0.32344E-10 -10.4902 0.27056E-10 -10.5677 0.83649E+00 -0.0775 37 CaCl2,aq 0.15289E-14 -14.8156 0.15289E-14 -14.8156 0.10000E+01 0.0000 38 CaF+ 0.78818E-12 -12.1034 0.65931E-12 -12.1809 0.83649E+00 -0.0775 39 CaOH+ 0.80314E-07 -7.0952 0.67182E-07 -7.1727 0.83649E+00 -0.0775 40 CaSO4,aq 0.25218E-16 -16.5983 0.25218E-16 -16.5983 0.10000E+01 0.0000 41 HCl,aq 0.32500E-14 -14.4881 0.32500E-14 -14.4881 0.10000E+01 0.0000 45 HF,aq 0.32794E-12 -12.4842 0.32794E-12 -12.4842 0.10000E+01 0.0000 46 HF2- 0.85206E-19 -19.0695 0.71137E-19 -19.1479 0.83488E+00 -0.0784 48 FeCl+ 0.13593E-16 -16.8667 0.11370E-16 -16.9442 0.83649E+00 -0.0775 51 FeF+ 0.11854E-17 -17.9261 0.99155E-18 -18.0037 0.83649E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15762E-10 -10.8024 0.13184E-10 -10.8799 0.83649E+00 -0.0775 55 HFeO2- 0.35486E-07 -7.4499 0.29626E-07 -7.5283 0.83488E+00 -0.0784 56 FeO+ 0.11047E-16 -16.9568 0.92403E-17 -17.0343 0.83649E+00 -0.0775 58 FeO2- 0.40735E-09 -9.3900 0.34009E-09 -9.4684 0.83488E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56734E-09 -9.2462 0.56734E-09 -9.2462 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.27637E-14 -14.5585 0.23073E-14 -14.6369 0.83488E+00 -0.0784 65 MgCO3,aq 0.79825E-13 -13.0979 0.79825E-13 -13.0979 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.67604E-15 -15.1700 0.56550E-15 -15.2476 0.83649E+00 -0.0775 67 MgCl+ 0.45651E-14 -14.3405 0.38187E-14 -14.4181 0.83649E+00 -0.0775 68 MgF+ 0.45467E-15 -15.3423 0.38033E-15 -15.4198 0.83649E+00 -0.0775 69 MgOH+ 0.69208E-10 -10.1598 0.57892E-10 -10.2374 0.83649E+00 -0.0775 71 MnF+ 0.12545E-15 -15.9015 0.10494E-15 -15.9791 0.83649E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47014E-09 -9.3278 0.39327E-09 -9.4053 0.83649E+00 -0.0775 74 MnO2-2 0.20838E-10 -10.6811 0.10782E-10 -10.9673 0.51744E+00 -0.2861 75 HMnO2- 0.21097E-09 -9.6758 0.17614E-09 -9.7541 0.83488E+00 -0.0784 78 MnCl+ 0.16980E-13 -13.7701 0.14204E-13 -13.8476 0.83649E+00 -0.0775 80 NaCl,aq 0.13139E-05 -5.8814 0.13139E-05 -5.8814 0.10000E+01 0.0000 81 NaF,aq 0.25072E-08 -8.6008 0.25072E-08 -8.6008 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92982E-02 -2.0316 0.77488E-02 -2.1108 0.83337E+00 -0.0792 89 HPO3-2 0.16256E-14 -14.7890 0.84113E-15 -15.0751 0.51744E+00 -0.2861 91 H2PO3- 0.15064E-18 -18.8221 0.12577E-18 -18.9004 0.83488E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38356E-10 -10.4162 0.32053E-10 -10.4941 0.83568E+00 -0.0780 94 PO4-3 0.10542E-08 -8.9771 0.25499E-09 -9.5935 0.24189E+00 -0.6164 98 HP2O7-3 0.93597E-18 -18.0287 0.21573E-18 -18.6661 0.23049E+00 -0.6373 99 P2O7-4 0.90164E-17 -17.0450 0.69119E-18 -18.1604 0.76660E-01 -1.1154 100 H2S,aq 0.16631E-07 -7.7791 0.16573E-07 -7.7806 0.99653E+00 -0.0015 101 S2-2 0.19122E-13 -13.7185 0.98944E-14 -14.0046 0.51744E+00 -0.2861 107 SO3-2 0.32395E-17 -17.4895 0.17006E-17 -17.7694 0.52496E+00 -0.2799 109 HSO4- 0.96964E-19 -19.0134 0.81189E-19 -19.0905 0.83731E+00 -0.0771 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8876973E-10 -.2221276E-01 -.2235007E+02 0.0000 2 H2O 0.1000000E+01 0.5550500E+02 0.9981948E+06 0.0000 3 Cl- 0.2849023E-03 0.2862169E-03 0.1012954E+02 6.5038 4 SO4-- 0.2178900E-11 -.1258036E-03 -.1206381E+02 8.3080 5 HCO3- 0.2369070E-05 0.1297537E-03 0.7903395E+01 4.4243 6 HS- 0.8612749E-04 0.2119477E-03 0.6997305E+01 5.9843 7 Al+++ 0.9870096E-29 0.5291426E-05 0.1425215E+00 0.7390 8 H4SiO4 0.6959779E-03 0.1348503E-01 0.1293858E+04 -3.1574 9 Ca++ 0.1365519E-06 0.2356267E-06 0.9426971E-02 13.1018 10 Mg++ 0.2136299E-10 0.9388853E-10 0.2278636E-05 9.2942 11 Fe++ 0.5888003E-13 0.3612325E-07 0.2013856E-02 6.7350 12 K+ 0.1573604E-03 0.1581148E-03 0.6171817E+01 6.2467 13 Na+ 0.1996841E-01 0.2241540E-01 0.5144265E+03 8.3494 14 Mn++ 0.1888992E-10 0.2527163E-08 0.1385951E-03 9.2416 15 F- 0.7711424E-06 0.7736506E-06 0.1467217E-01 3.9353 16 HPO4-- 0.4493276E-07 0.4602527E-07 0.4409753E-02 12.6224 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279247E+02 -.1102526E-01 -.8278145E+02 0.0000000E+00 2 H2O -.7168207E+01 0.2754980E+02 -.3471801E+02 0.0000000E+00 3 Cl- 0.1420632E-03 0.1420632E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385959E+00 -.6244235E-04 0.1386584E+00 0.0000000E+00 5 HCO3- 0.6440300E-04 0.6440300E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385532E+00 0.1051998E-03 -.1386584E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2626389E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6693267E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1169528E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4660139E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1792970E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7847995E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112584E-01 0.6265251E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254353E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3840000E-06 0.3840000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2284456E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1632E-13 Mass of aqueous solution: 0.497216E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0007100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.9 2.450 5.160 73.23 grossular 0.1343 -0.872 60.49 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2613 -0.583 56.60 1.753 1.036 17.30 hedenbergite 0.6777E-01 -1.169 16.81 1.226 0.3078 4.606 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2613 -0.583 281.6 2.450 5.156 97.28 tr.625ac.25prg.125 0.4292E-01 -1.367 36.69 1.565 0.6717 11.81 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338097 g Volume = 2210.779825 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0007100 moles log = -3.1487 Original solution: 1000.0103000 g Original solution / Rock added: 1408465.21 (Water/Rock Ratio), log = 6.1487 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2163 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8408E+00 0.9836 0.1006E+01 0.1023E+01 CO2,gas 0.2762E-07 1.0049 0.3376E-07 0.3360E-07 CH4,gas 0.1467E+00 1.0106 0.1803E+00 0.1784E+00 H2,gas 0.1249E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.3763E-06 0.9953 0.4556E-06 0.4577E-06 S2,gas 0.2770E-28 1.0000 0.3369E-28 0.3369E-28 CO,gas 0.1125E-12 1.0000 0.1368E-12 0.1368E-12 SO3,gas 0.1953E-47 1.0000 0.2375E-47 0.2375E-47 SO2,gas 0.1155E-26 1.0000 0.1405E-26 0.1405E-26 HF,gas 0.6620E-15 1.0000 0.8052E-15 0.8052E-15 HCl,gas 0.4715E-17 1.0000 0.5735E-17 0.5735E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.83 -9.17 -3.057 0.15658E+05 -7.472 3 CH4,gas 4.54 2.10 -2.44 -0.611 0.41714E+04 -0.744 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.27 -8.04 -4.020 0.13729E+05 -6.341 6 S2,gas -7.34 -37.51 -30.17 -4.642 0.51517E+05 -28.472 7 CO,gas 3.21 -11.35 -14.56 -4.481 0.24866E+05 -12.864 8 SO3,gas 17.12 -32.20 -49.32 -12.331 0.84218E+05 -47.624 9 SO2,gas 0.83 -27.72 -28.55 -7.614 0.48750E+05 -26.852 10 HF,gas 0.47 -16.32 -16.79 -8.397 0.28674E+05 -15.094 11 HCl,gas 5.19 -13.75 -18.94 -9.470 0.32340E+05 -17.241 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.47 -0.17 -0.014 0.29389E+03 38 aragonite 0.97 -2.73 -3.70 -1.232 0.63097E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.73 -3.54 -1.180 0.60454E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.86 -3.76 -1.075 0.64245E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.86 -3.32 -0.948 0.56668E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.54 -3.28 -1.092 0.55926E+04 147 pyrrhotiteFe0.875 -6.02 -8.93 -2.92 -1.073 0.49798E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.54 -3.12 -1.042 0.53354E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.03 -4.05 -1.350 0.69173E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0007100 MOLES New total amount of reactant added: 0.0007300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8650E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0007300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137295E-01 Osmotic coef. = 1.0447 True ionic strength = .2013172E-01 Chg. balance for total moles = -.8650E-10 Max. difference allowed = 0.1422E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88773E-10 -10.0517 0.74565E-10 -10.1275 0.83995E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28514E-03 -3.5449 0.23806E-03 -3.6233 0.83488E+00 -0.0784 4 SO4-- 0.22036E-11 -11.6569 0.11427E-11 -11.9421 0.51854E+00 -0.2852 5 HCO3- 0.24222E-05 -5.6158 0.20252E-05 -5.6935 0.83611E+00 -0.0777 6 HS- 0.87106E-04 -4.0599 0.72734E-04 -4.1383 0.83500E+00 -0.0783 7 Al+++ 0.98715E-29 -29.0056 0.22729E-29 -29.6434 0.23025E+00 -0.6378 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13656E-06 -6.8647 0.70292E-07 -7.1531 0.51472E+00 -0.2884 10 Mg++ 0.21365E-10 -10.6703 0.10946E-10 -10.9607 0.51235E+00 -0.2904 11 Fe++ 0.58885E-13 -13.2300 0.30203E-13 -13.5199 0.51292E+00 -0.2900 12 K+ 0.15737E-03 -3.8031 0.13161E-03 -3.8807 0.83631E+00 -0.0776 13 Na+ 0.19969E-01 -1.6996 0.16669E-01 -1.7781 0.83473E+00 -0.0785 14 Mn++ 0.18892E-10 -10.7237 0.96979E-11 -11.0133 0.51334E+00 -0.2896 15 F- 0.78721E-06 -6.1039 0.65586E-06 -6.1832 0.83315E+00 -0.0793 16 HPO4-- 0.44930E-07 -7.3475 0.23301E-07 -7.6326 0.51861E+00 -0.2852 18 HSiO3- 0.10439E-01 -1.9813 0.87154E-02 -2.0597 0.83488E+00 -0.0784 19 Ca(HSiO3)+ 0.16679E-07 -7.7778 0.13952E-07 -7.8554 0.83649E+00 -0.0775 20 Mg(HSiO3)+ 0.32324E-11 -11.4905 0.27039E-11 -11.5680 0.83649E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66485E-16 -16.1773 0.55614E-16 -16.2548 0.83649E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52911E-05 -5.2765 0.44094E-05 -5.3556 0.83337E+00 -0.0792 26 CH4,aq 0.12566E-03 -3.9008 0.12522E-03 -3.9023 0.99653E+00 -0.0015 27 C2H6,aq 0.23225E-12 -12.6341 0.23144E-12 -12.6356 0.99653E+00 -0.0015 31 CO,aq 0.93886E-16 -16.0274 0.93886E-16 -16.0274 0.10000E+01 0.0000 32 CO2,aq 0.32380E-09 -9.4897 0.32267E-09 -9.4912 0.99653E+00 -0.0015 33 CO3-2 0.45848E-05 -5.3387 0.23723E-05 -5.6248 0.51744E+00 -0.2861 34 CaCO3,aq 0.20909E-08 -8.6797 0.20909E-08 -8.6797 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.43441E-11 -11.3621 0.36338E-11 -11.4396 0.83649E+00 -0.0775 36 CaCl+ 0.32373E-10 -10.4898 0.27080E-10 -10.5674 0.83649E+00 -0.0775 37 CaCl2,aq 0.15316E-14 -14.8149 0.15316E-14 -14.8149 0.10000E+01 0.0000 38 CaF+ 0.80466E-12 -12.0944 0.67309E-12 -12.1719 0.83649E+00 -0.0775 39 CaOH+ 0.80317E-07 -7.0952 0.67184E-07 -7.1727 0.83649E+00 -0.0775 40 CaSO4,aq 0.25505E-16 -16.5934 0.25505E-16 -16.5934 0.10000E+01 0.0000 41 HCl,aq 0.32528E-14 -14.4877 0.32528E-14 -14.4877 0.10000E+01 0.0000 45 HF,aq 0.33479E-12 -12.4752 0.33479E-12 -12.4752 0.10000E+01 0.0000 46 HF2- 0.88796E-19 -19.0516 0.74134E-19 -19.1300 0.83488E+00 -0.0784 48 FeCl+ 0.13605E-16 -16.8663 0.11381E-16 -16.9438 0.83649E+00 -0.0775 51 FeF+ 0.12102E-17 -17.9172 0.10123E-17 -17.9947 0.83649E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15762E-10 -10.8024 0.13185E-10 -10.8799 0.83649E+00 -0.0775 55 HFeO2- 0.35485E-07 -7.4500 0.29625E-07 -7.5283 0.83488E+00 -0.0784 56 FeO+ 0.11047E-16 -16.9568 0.92406E-17 -17.0343 0.83649E+00 -0.0775 58 FeO2- 0.40733E-09 -9.3900 0.34008E-09 -9.4684 0.83488E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56783E-09 -9.2458 0.56783E-09 -9.2458 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.27951E-14 -14.5536 0.23336E-14 -14.6320 0.83488E+00 -0.0784 65 MgCO3,aq 0.81617E-13 -13.0882 0.81617E-13 -13.0882 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.69125E-15 -15.1604 0.57822E-15 -15.2379 0.83649E+00 -0.0775 67 MgCl+ 0.45693E-14 -14.3402 0.38221E-14 -14.4177 0.83649E+00 -0.0775 68 MgF+ 0.46418E-15 -15.3333 0.38828E-15 -15.4109 0.83649E+00 -0.0775 69 MgOH+ 0.69211E-10 -10.1598 0.57894E-10 -10.2374 0.83649E+00 -0.0775 71 MnF+ 0.12808E-15 -15.8925 0.10713E-15 -15.9701 0.83649E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47016E-09 -9.3278 0.39328E-09 -9.4053 0.83649E+00 -0.0775 74 MnO2-2 0.20837E-10 -10.6812 0.10782E-10 -10.9673 0.51744E+00 -0.2861 75 HMnO2- 0.21097E-09 -9.6758 0.17613E-09 -9.7542 0.83488E+00 -0.0784 78 MnCl+ 0.16995E-13 -13.7697 0.14216E-13 -13.8472 0.83649E+00 -0.0775 80 NaCl,aq 0.13150E-05 -5.8811 0.13150E-05 -5.8811 0.10000E+01 0.0000 81 NaF,aq 0.25595E-08 -8.5918 0.25595E-08 -8.5918 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92979E-02 -2.0316 0.77485E-02 -2.1108 0.83337E+00 -0.0792 89 HPO3-2 0.16254E-14 -14.7890 0.84106E-15 -15.0752 0.51744E+00 -0.2861 91 H2PO3- 0.15063E-18 -18.8221 0.12576E-18 -18.9005 0.83488E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38354E-10 -10.4162 0.32052E-10 -10.4941 0.83568E+00 -0.0780 94 PO4-3 0.10541E-08 -8.9771 0.25496E-09 -9.5935 0.24188E+00 -0.6164 98 HP2O7-3 0.93589E-18 -18.0288 0.21571E-18 -18.6661 0.23048E+00 -0.6374 99 P2O7-4 0.90155E-17 -17.0450 0.69109E-18 -18.1605 0.76656E-01 -1.1155 100 H2S,aq 0.16820E-07 -7.7742 0.16762E-07 -7.7757 0.99653E+00 -0.0015 101 S2-2 0.19559E-13 -13.7087 0.10121E-13 -13.9948 0.51744E+00 -0.2861 107 SO3-2 0.32762E-17 -17.4846 0.17199E-17 -17.7645 0.52495E+00 -0.2799 109 HSO4- 0.98066E-19 -19.0085 0.82111E-19 -19.0856 0.83730E+00 -0.0771 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8877330E-10 -.2221219E-01 -.2234949E+02 0.0000 2 H2O 0.1000000E+01 0.5550500E+02 0.9981947E+06 0.0000 3 Cl- 0.2851387E-03 0.2864544E-03 0.1013795E+02 6.5041 4 SO4-- 0.2203602E-11 -.1285632E-03 -.1232844E+02 8.3128 5 HCO3- 0.2422184E-05 0.1326669E-03 0.8080839E+01 4.4339 6 HS- 0.8710639E-04 0.2156864E-03 0.7120734E+01 5.9892 7 Al+++ 0.9871470E-29 0.5291246E-05 0.1425167E+00 0.7390 8 H4SiO4 0.6959779E-03 0.1348467E-01 0.1293823E+04 -3.1574 9 Ca++ 0.1365638E-06 0.2356885E-06 0.9429443E-02 13.1018 10 Mg++ 0.2136485E-10 0.9389562E-10 0.2278808E-05 9.2942 11 Fe++ 0.5888514E-13 0.3612202E-07 0.2013787E-02 6.7350 12 K+ 0.1573668E-03 0.1581211E-03 0.6172063E+01 6.2467 13 Na+ 0.1996922E-01 0.2241621E-01 0.5144450E+03 8.3494 14 Mn++ 0.1889159E-10 0.2527180E-08 0.1385960E-03 9.2416 15 F- 0.7872072E-06 0.7897678E-06 0.1497783E-01 3.9443 16 HPO4-- 0.4492994E-07 0.4602236E-07 0.4409474E-02 12.6223 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279247E+02 -.1102498E-01 -.8278144E+02 0.0000000E+00 2 H2O -.7168191E+01 0.2754982E+02 -.3471801E+02 0.0000000E+00 3 Cl- 0.1421812E-03 0.1421812E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385960E+00 -.6381212E-04 0.1386598E+00 0.0000000E+00 5 HCO3- 0.6584900E-04 0.6584900E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385528E+00 0.1070556E-03 -.1386598E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2626302E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6693095E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1169836E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4660494E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1792911E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7848315E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112625E-01 0.6265251E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254362E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3920000E-06 0.3920000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2284313E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.3733E-14 Mass of aqueous solution: 0.497216E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0007300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.9 2.450 5.160 73.23 grossular 0.1343 -0.872 60.50 1.782 1.108 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2613 -0.583 56.59 1.753 1.036 17.29 hedenbergite 0.6776E-01 -1.169 16.81 1.226 0.3078 4.605 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.156 97.28 tr.625ac.25prg.125 0.4294E-01 -1.367 36.70 1.565 0.6719 11.81 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338104 g Volume = 2210.779880 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0007300 moles log = -3.1367 Original solution: 1000.0103000 g Original solution / Rock added: 1369877.12 (Water/Rock Ratio), log = 6.1367 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8381E+00 0.9836 0.1006E+01 0.1023E+01 CO2,gas 0.2815E-07 1.0049 0.3452E-07 0.3436E-07 CH4,gas 0.1495E+00 1.0106 0.1843E+00 0.1824E+00 H2,gas 0.1245E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.3794E-06 0.9953 0.4608E-06 0.4630E-06 S2,gas 0.2824E-28 1.0000 0.3446E-28 0.3446E-28 CO,gas 0.1146E-12 1.0000 0.1399E-12 0.1399E-12 SO3,gas 0.1968E-47 1.0000 0.2402E-47 0.2402E-47 SO2,gas 0.1165E-26 1.0000 0.1421E-26 0.1421E-26 HF,gas 0.6736E-15 1.0000 0.8220E-15 0.8220E-15 HCl,gas 0.4703E-17 1.0000 0.5740E-17 0.5740E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.82 -9.16 -3.054 0.15642E+05 -7.462 3 CH4,gas 4.54 2.11 -2.43 -0.608 0.41550E+04 -0.734 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.27 -8.04 -4.018 0.13720E+05 -6.337 6 S2,gas -7.34 -37.50 -30.16 -4.640 0.51500E+05 -28.463 7 CO,gas 3.21 -11.34 -14.55 -4.478 0.24849E+05 -12.854 8 SO3,gas 17.12 -32.20 -49.32 -12.330 0.84210E+05 -47.619 9 SO2,gas 0.83 -27.71 -28.55 -7.612 0.48742E+05 -26.847 10 HF,gas 0.47 -16.31 -16.78 -8.392 0.28658E+05 -15.085 11 HCl,gas 5.19 -13.75 -18.94 -9.470 0.32340E+05 -17.241 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.46 -0.16 -0.014 0.27857E+03 38 aragonite 0.97 -2.72 -3.69 -1.229 0.62932E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.72 -3.53 -1.177 0.60290E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.86 -3.75 -1.072 0.64081E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.86 -3.31 -0.945 0.56503E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.53 -3.27 -1.090 0.55842E+04 147 pyrrhotiteFe0.875 -6.02 -8.93 -2.91 -1.071 0.49714E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.53 -3.12 -1.040 0.53270E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.02 -4.05 -1.349 0.69089E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0007300 MOLES New total amount of reactant added: 0.0007500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8648E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0007500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137129E-01 Osmotic coef. = 1.0502 True ionic strength = .2013263E-01 Chg. balance for total moles = -.8648E-10 Max. difference allowed = 0.1423E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88777E-10 -10.0517 0.74568E-10 -10.1274 0.83995E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28538E-03 -3.5446 0.23825E-03 -3.6230 0.83488E+00 -0.0784 4 SO4-- 0.22283E-11 -11.6520 0.11555E-11 -11.9372 0.51853E+00 -0.2852 5 HCO3- 0.24753E-05 -5.6064 0.20696E-05 -5.6841 0.83610E+00 -0.0777 6 HS- 0.88085E-04 -4.0551 0.73551E-04 -4.1334 0.83500E+00 -0.0783 7 Al+++ 0.98728E-29 -29.0056 0.22732E-29 -29.6434 0.23025E+00 -0.6378 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13658E-06 -6.8646 0.70297E-07 -7.1531 0.51471E+00 -0.2884 10 Mg++ 0.21367E-10 -10.6703 0.10947E-10 -10.9607 0.51235E+00 -0.2904 11 Fe++ 0.58890E-13 -13.2300 0.30205E-13 -13.5199 0.51291E+00 -0.2900 12 K+ 0.15737E-03 -3.8031 0.13161E-03 -3.8807 0.83630E+00 -0.0776 13 Na+ 0.19970E-01 -1.6996 0.16669E-01 -1.7781 0.83473E+00 -0.0785 14 Mn++ 0.18893E-10 -10.7237 0.96986E-11 -11.0133 0.51334E+00 -0.2896 15 F- 0.80327E-06 -6.0951 0.66925E-06 -6.1744 0.83315E+00 -0.0793 16 HPO4-- 0.44927E-07 -7.3475 0.23300E-07 -7.6327 0.51861E+00 -0.2852 18 HSiO3- 0.10439E-01 -1.9814 0.87150E-02 -2.0597 0.83488E+00 -0.0784 19 Ca(HSiO3)+ 0.16679E-07 -7.7778 0.13952E-07 -7.8554 0.83648E+00 -0.0775 20 Mg(HSiO3)+ 0.32326E-11 -11.4905 0.27040E-11 -11.5680 0.83648E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66488E-16 -16.1773 0.55616E-16 -16.2548 0.83648E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52909E-05 -5.2765 0.44093E-05 -5.3556 0.83336E+00 -0.0792 26 CH4,aq 0.12842E-03 -3.8914 0.12797E-03 -3.8929 0.99653E+00 -0.0015 27 C2H6,aq 0.24256E-12 -12.6152 0.24172E-12 -12.6167 0.99653E+00 -0.0015 28 C3H8,aq 0.10578E-19 -19.9756 0.10541E-19 -19.9771 0.99653E+00 -0.0015 31 CO,aq 0.95948E-16 -16.0180 0.95948E-16 -16.0180 0.10000E+01 0.0000 32 CO2,aq 0.33091E-09 -9.4803 0.32976E-09 -9.4818 0.99653E+00 -0.0015 33 CO3-2 0.46852E-05 -5.3293 0.24242E-05 -5.6154 0.51743E+00 -0.2861 34 CaCO3,aq 0.21368E-08 -8.6702 0.21368E-08 -8.6702 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.44397E-11 -11.3527 0.37137E-11 -11.4302 0.83648E+00 -0.0775 36 CaCl+ 0.32403E-10 -10.4894 0.27104E-10 -10.5670 0.83648E+00 -0.0775 37 CaCl2,aq 0.15342E-14 -14.8141 0.15342E-14 -14.8141 0.10000E+01 0.0000 38 CaF+ 0.82115E-12 -12.0856 0.68688E-12 -12.1631 0.83648E+00 -0.0775 39 CaOH+ 0.80321E-07 -7.0952 0.67187E-07 -7.1727 0.83648E+00 -0.0775 40 CaSO4,aq 0.25793E-16 -16.5885 0.25793E-16 -16.5885 0.10000E+01 0.0000 41 HCl,aq 0.32556E-14 -14.4874 0.32556E-14 -14.4874 0.10000E+01 0.0000 45 HF,aq 0.34163E-12 -12.4664 0.34163E-12 -12.4664 0.10000E+01 0.0000 46 HF2- 0.92460E-19 -19.0340 0.77193E-19 -19.1124 0.83488E+00 -0.0784 48 FeCl+ 0.13618E-16 -16.8659 0.11391E-16 -16.9434 0.83648E+00 -0.0775 51 FeF+ 0.12349E-17 -17.9084 0.10330E-17 -17.9859 0.83648E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15763E-10 -10.8024 0.13185E-10 -10.8799 0.83648E+00 -0.0775 55 HFeO2- 0.35483E-07 -7.4500 0.29624E-07 -7.5284 0.83488E+00 -0.0784 56 FeO+ 0.11047E-16 -16.9567 0.92410E-17 -17.0343 0.83648E+00 -0.0775 58 FeO2- 0.40732E-09 -9.3901 0.34006E-09 -9.4684 0.83488E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56832E-09 -9.2454 0.56832E-09 -9.2454 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.28265E-14 -14.5488 0.23598E-14 -14.6271 0.83488E+00 -0.0784 65 MgCO3,aq 0.83410E-13 -13.0788 0.83410E-13 -13.0788 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.70646E-15 -15.1509 0.59094E-15 -15.2285 0.83648E+00 -0.0775 67 MgCl+ 0.45734E-14 -14.3398 0.38256E-14 -14.4173 0.83648E+00 -0.0775 68 MgF+ 0.47369E-15 -15.3245 0.39623E-15 -15.4021 0.83648E+00 -0.0775 69 MgOH+ 0.69214E-10 -10.1598 0.57896E-10 -10.2374 0.83648E+00 -0.0775 71 MnF+ 0.13070E-15 -15.8837 0.10933E-15 -15.9613 0.83648E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47018E-09 -9.3277 0.39330E-09 -9.4053 0.83648E+00 -0.0775 74 MnO2-2 0.20836E-10 -10.6812 0.10781E-10 -10.9673 0.51743E+00 -0.2861 75 HMnO2- 0.21096E-09 -9.6758 0.17612E-09 -9.7542 0.83488E+00 -0.0784 78 MnCl+ 0.17011E-13 -13.7693 0.14229E-13 -13.8468 0.83648E+00 -0.0775 80 NaCl,aq 0.13162E-05 -5.8807 0.13162E-05 -5.8807 0.10000E+01 0.0000 81 NaF,aq 0.26118E-08 -8.5831 0.26118E-08 -8.5831 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92975E-02 -2.0316 0.77482E-02 -2.1108 0.83336E+00 -0.0792 89 HPO3-2 0.16253E-14 -14.7891 0.84100E-15 -15.0752 0.51743E+00 -0.2861 91 H2PO3- 0.15063E-18 -18.8221 0.12576E-18 -18.9005 0.83488E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38353E-10 -10.4162 0.32050E-10 -10.4942 0.83567E+00 -0.0780 94 PO4-3 0.10540E-08 -8.9772 0.25493E-09 -9.5936 0.24188E+00 -0.6164 98 HP2O7-3 0.93581E-18 -18.0288 0.21568E-18 -18.6662 0.23048E+00 -0.6374 99 P2O7-4 0.90146E-17 -17.0451 0.69099E-18 -18.1605 0.76652E-01 -1.1155 100 H2S,aq 0.17010E-07 -7.7693 0.16951E-07 -7.7708 0.99653E+00 -0.0015 101 S2-2 0.20001E-13 -13.6989 0.10349E-13 -13.9851 0.51743E+00 -0.2861 107 SO3-2 0.33130E-17 -17.4798 0.17391E-17 -17.7597 0.52495E+00 -0.2799 109 HSO4- 0.99168E-19 -19.0036 0.83034E-19 -19.0807 0.83730E+00 -0.0771 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8877686E-10 -.2221161E-01 -.2234891E+02 0.0000 2 H2O 0.1000000E+01 0.5550501E+02 0.9981947E+06 0.0000 3 Cl- 0.2853751E-03 0.2866919E-03 0.1014635E+02 6.5045 4 SO4-- 0.2228302E-11 -.1313228E-03 -.1259306E+02 8.3176 5 HCO3- 0.2475296E-05 0.1355801E-03 0.8258282E+01 4.4433 6 HS- 0.8808529E-04 0.2194251E-03 0.7244164E+01 5.9940 7 Al+++ 0.9872843E-29 0.5291065E-05 0.1425118E+00 0.7390 8 H4SiO4 0.6959778E-03 0.1348431E-01 0.1293789E+04 -3.1574 9 Ca++ 0.1365756E-06 0.2357503E-06 0.9431916E-02 13.1018 10 Mg++ 0.2136670E-10 0.9390271E-10 0.2278979E-05 9.2942 11 Fe++ 0.5889026E-13 0.3612079E-07 0.2013718E-02 6.7350 12 K+ 0.1573731E-03 0.1581274E-03 0.6172310E+01 6.2467 13 Na+ 0.1997002E-01 0.2241701E-01 0.5144634E+03 8.3494 14 Mn++ 0.1889327E-10 0.2527197E-08 0.1385969E-03 9.2416 15 F- 0.8032719E-06 0.8058849E-06 0.1528349E-01 3.9530 16 HPO4-- 0.4492712E-07 0.4601945E-07 0.4409195E-02 12.6222 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279247E+02 -.1102471E-01 -.8278144E+02 0.0000000E+00 2 H2O -.7168175E+01 0.2754984E+02 -.3471802E+02 0.0000000E+00 3 Cl- 0.1422992E-03 0.1422992E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385961E+00 -.6518190E-04 0.1386613E+00 0.0000000E+00 5 HCO3- 0.6729500E-04 0.6729500E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385524E+00 0.1089114E-03 -.1386613E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2626214E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6692922E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1170144E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4660849E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1792851E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7848635E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112666E-01 0.6265250E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254371E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4000000E-06 0.4000000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2284170E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1103E-13 Mass of aqueous solution: 0.497216E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0007500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5546 -0.256 281.9 2.450 5.160 73.23 grossular 0.1343 -0.872 60.50 1.782 1.108 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2613 -0.583 56.58 1.753 1.036 17.29 hedenbergite 0.6775E-01 -1.169 16.81 1.226 0.3077 4.604 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.156 97.28 tr.625ac.25prg.125 0.4295E-01 -1.367 36.71 1.565 0.6721 11.82 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338110 g Volume = 2210.779936 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0007500 moles log = -3.1249 Original solution: 1000.0103000 g Original solution / Rock added: 1333347.07 (Water/Rock Ratio), log = 6.1249 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2244 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8353E+00 0.9835 0.1006E+01 0.1023E+01 CO2,gas 0.2868E-07 1.0048 0.3528E-07 0.3511E-07 CH4,gas 0.1522E+00 1.0105 0.1884E+00 0.1864E+00 H2,gas 0.1241E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.3824E-06 0.9952 0.4660E-06 0.4682E-06 S2,gas 0.2879E-28 1.0000 0.3525E-28 0.3525E-28 CO,gas 0.1168E-12 1.0000 0.1430E-12 0.1430E-12 SO3,gas 0.1984E-47 1.0000 0.2429E-47 0.2429E-47 SO2,gas 0.1174E-26 1.0000 0.1437E-26 0.1437E-26 HF,gas 0.6851E-15 1.0000 0.8388E-15 0.8388E-15 HCl,gas 0.4692E-17 1.0000 0.5745E-17 0.5745E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 0.42463E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.81 -9.15 -3.050 0.15626E+05 -7.452 3 CH4,gas 4.54 2.12 -2.42 -0.606 0.41389E+04 -0.725 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.26 -8.03 -4.015 0.13712E+05 -6.332 6 S2,gas -7.34 -37.49 -30.15 -4.639 0.51483E+05 -28.453 7 CO,gas 3.21 -11.33 -14.54 -4.475 0.24833E+05 -12.845 8 SO3,gas 17.12 -32.19 -49.31 -12.328 0.84201E+05 -47.615 9 SO2,gas 0.83 -27.71 -28.54 -7.611 0.48734E+05 -26.842 10 HF,gas 0.47 -16.30 -16.78 -8.388 0.28643E+05 -15.076 11 HCl,gas 5.19 -13.75 -18.94 -9.470 0.32339E+05 -17.241 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.46 -0.15 -0.013 0.26357E+03 38 aragonite 0.97 -2.71 -3.68 -1.225 0.62771E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.71 -3.52 -1.174 0.60129E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.85 -3.74 -1.070 0.63920E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.85 -3.30 -0.943 0.56342E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.53 -3.27 -1.089 0.55759E+04 147 pyrrhotiteFe0.875 -6.02 -8.92 -2.91 -1.069 0.49631E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.53 -3.11 -1.038 0.53187E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.02 -4.04 -1.347 0.69006E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0007500 MOLES New total amount of reactant added: 0.0007700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8650E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0007700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136963E-01 Osmotic coef. = 1.0562 True ionic strength = .2013354E-01 Chg. balance for total moles = -.8650E-10 Max. difference allowed = 0.1424E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88780E-10 -10.0517 0.74571E-10 -10.1274 0.83995E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28561E-03 -3.5442 0.23845E-03 -3.6226 0.83488E+00 -0.0784 4 SO4-- 0.22530E-11 -11.6472 0.11682E-11 -11.9325 0.51853E+00 -0.2852 5 HCO3- 0.25284E-05 -5.5972 0.21140E-05 -5.6749 0.83610E+00 -0.0777 6 HS- 0.89064E-04 -4.0503 0.74368E-04 -4.1286 0.83500E+00 -0.0783 7 Al+++ 0.98742E-29 -29.0055 0.22734E-29 -29.6433 0.23024E+00 -0.6378 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13659E-06 -6.8646 0.70302E-07 -7.1530 0.51470E+00 -0.2884 10 Mg++ 0.21369E-10 -10.6702 0.10948E-10 -10.9607 0.51234E+00 -0.2904 11 Fe++ 0.58895E-13 -13.2299 0.30208E-13 -13.5199 0.51290E+00 -0.2900 12 K+ 0.15738E-03 -3.8031 0.13162E-03 -3.8807 0.83630E+00 -0.0776 13 Na+ 0.19971E-01 -1.6996 0.16670E-01 -1.7781 0.83472E+00 -0.0785 14 Mn++ 0.18895E-10 -10.7237 0.96994E-11 -11.0133 0.51333E+00 -0.2896 15 F- 0.81934E-06 -6.0865 0.68263E-06 -6.1658 0.83315E+00 -0.0793 16 HPO4-- 0.44924E-07 -7.3475 0.23298E-07 -7.6327 0.51860E+00 -0.2852 18 HSiO3- 0.10438E-01 -1.9814 0.87147E-02 -2.0597 0.83488E+00 -0.0784 19 Ca(HSiO3)+ 0.16680E-07 -7.7778 0.13953E-07 -7.8553 0.83648E+00 -0.0775 20 Mg(HSiO3)+ 0.32327E-11 -11.4904 0.27041E-11 -11.5680 0.83648E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66491E-16 -16.1772 0.55618E-16 -16.2548 0.83648E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52907E-05 -5.2765 0.44091E-05 -5.3557 0.83336E+00 -0.0792 26 CH4,aq 0.13118E-03 -3.8821 0.13072E-03 -3.8837 0.99653E+00 -0.0015 27 C2H6,aq 0.25310E-12 -12.5967 0.25222E-12 -12.5982 0.99653E+00 -0.0015 28 C3H8,aq 0.11274E-19 -19.9479 0.11235E-19 -19.9494 0.99653E+00 -0.0015 31 CO,aq 0.98010E-16 -16.0087 0.98010E-16 -16.0087 0.10000E+01 0.0000 32 CO2,aq 0.33802E-09 -9.4711 0.33685E-09 -9.4726 0.99653E+00 -0.0015 33 CO3-2 0.47856E-05 -5.3201 0.24762E-05 -5.6062 0.51742E+00 -0.2862 34 CaCO3,aq 0.21828E-08 -8.6610 0.21828E-08 -8.6610 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.45352E-11 -11.3434 0.37937E-11 -11.4209 0.83648E+00 -0.0775 36 CaCl+ 0.32432E-10 -10.4890 0.27129E-10 -10.5666 0.83648E+00 -0.0775 37 CaCl2,aq 0.15369E-14 -14.8134 0.15369E-14 -14.8134 0.10000E+01 0.0000 38 CaF+ 0.83763E-12 -12.0769 0.70066E-12 -12.1545 0.83648E+00 -0.0775 39 CaOH+ 0.80324E-07 -7.0952 0.67190E-07 -7.1727 0.83648E+00 -0.0775 40 CaSO4,aq 0.26080E-16 -16.5837 0.26080E-16 -16.5837 0.10000E+01 0.0000 41 HCl,aq 0.32584E-14 -14.4870 0.32584E-14 -14.4870 0.10000E+01 0.0000 45 HF,aq 0.34848E-12 -12.4578 0.34848E-12 -12.4578 0.10000E+01 0.0000 46 HF2- 0.96199E-19 -19.0168 0.80314E-19 -19.0952 0.83488E+00 -0.0784 48 FeCl+ 0.13630E-16 -16.8655 0.11401E-16 -16.9431 0.83648E+00 -0.0775 51 FeF+ 0.12597E-17 -17.8997 0.10537E-17 -17.9773 0.83648E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15764E-10 -10.8023 0.13186E-10 -10.8799 0.83648E+00 -0.0775 55 HFeO2- 0.35482E-07 -7.4500 0.29623E-07 -7.5284 0.83488E+00 -0.0784 56 FeO+ 0.11048E-16 -16.9567 0.92413E-17 -17.0343 0.83648E+00 -0.0775 58 FeO2- 0.40731E-09 -9.3901 0.34005E-09 -9.4685 0.83488E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56881E-09 -9.2450 0.56881E-09 -9.2450 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.28579E-14 -14.5440 0.23860E-14 -14.6223 0.83488E+00 -0.0784 65 MgCO3,aq 0.85202E-13 -13.0695 0.85202E-13 -13.0695 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.72167E-15 -15.1417 0.60366E-15 -15.2192 0.83648E+00 -0.0775 67 MgCl+ 0.45775E-14 -14.3394 0.38290E-14 -14.4169 0.83648E+00 -0.0775 68 MgF+ 0.48320E-15 -15.3159 0.40418E-15 -15.3934 0.83648E+00 -0.0775 69 MgOH+ 0.69216E-10 -10.1598 0.57898E-10 -10.2373 0.83648E+00 -0.0775 71 MnF+ 0.13332E-15 -15.8751 0.11152E-15 -15.9526 0.83648E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47020E-09 -9.3277 0.39331E-09 -9.4053 0.83648E+00 -0.0775 74 MnO2-2 0.20834E-10 -10.6812 0.10780E-10 -10.9674 0.51742E+00 -0.2862 75 HMnO2- 0.21095E-09 -9.6758 0.17612E-09 -9.7542 0.83488E+00 -0.0784 78 MnCl+ 0.17026E-13 -13.7689 0.14242E-13 -13.8464 0.83648E+00 -0.0775 80 NaCl,aq 0.13173E-05 -5.8803 0.13173E-05 -5.8803 0.10000E+01 0.0000 81 NaF,aq 0.26641E-08 -8.5744 0.26641E-08 -8.5744 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92972E-02 -2.0316 0.77479E-02 -2.1108 0.83336E+00 -0.0792 89 HPO3-2 0.16252E-14 -14.7891 0.84094E-15 -15.0752 0.51742E+00 -0.2862 91 H2PO3- 0.15062E-18 -18.8221 0.12575E-18 -18.9005 0.83488E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38352E-10 -10.4162 0.32049E-10 -10.4942 0.83567E+00 -0.0780 94 PO4-3 0.10539E-08 -8.9772 0.25491E-09 -9.5936 0.24187E+00 -0.6164 98 HP2O7-3 0.93573E-18 -18.0289 0.21566E-18 -18.6662 0.23047E+00 -0.6374 99 P2O7-4 0.90137E-17 -17.0451 0.69089E-18 -18.1606 0.76649E-01 -1.1155 100 H2S,aq 0.17199E-07 -7.7645 0.17140E-07 -7.7660 0.99653E+00 -0.0015 101 S2-2 0.20448E-13 -13.6893 0.10580E-13 -13.9755 0.51742E+00 -0.2862 107 SO3-2 0.33497E-17 -17.4750 0.17584E-17 -17.7549 0.52494E+00 -0.2799 109 HSO4- 0.10027E-18 -18.9988 0.83956E-19 -19.0759 0.83730E+00 -0.0771 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8878043E-10 -.2221103E-01 -.2234833E+02 0.0000 2 H2O 0.1000000E+01 0.5550501E+02 0.9981947E+06 0.0000 3 Cl- 0.2856115E-03 0.2869294E-03 0.1015476E+02 6.5048 4 SO4-- 0.2253001E-11 -.1340824E-03 -.1285770E+02 8.3224 5 HCO3- 0.2528403E-05 0.1384932E-03 0.8435725E+01 4.4525 6 HS- 0.8906418E-04 0.2231638E-03 0.7367595E+01 5.9988 7 Al+++ 0.9874217E-29 0.5290885E-05 0.1425069E+00 0.7390 8 H4SiO4 0.6959778E-03 0.1348395E-01 0.1293754E+04 -3.1574 9 Ca++ 0.1365874E-06 0.2358121E-06 0.9434388E-02 13.1018 10 Mg++ 0.2136856E-10 0.9390801E-10 0.2279108E-05 9.2942 11 Fe++ 0.5889538E-13 0.3611956E-07 0.2013650E-02 6.7350 12 K+ 0.1573794E-03 0.1581337E-03 0.6172556E+01 6.2467 13 Na+ 0.1997082E-01 0.2241781E-01 0.5144818E+03 8.3494 14 Mn++ 0.1889495E-10 0.2527214E-08 0.1385978E-03 9.2416 15 F- 0.8193367E-06 0.8220020E-06 0.1558915E-01 3.9616 16 HPO4-- 0.4492431E-07 0.4601654E-07 0.4408915E-02 12.6222 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279246E+02 -.1102443E-01 -.8278144E+02 0.0000000E+00 2 H2O -.7168158E+01 0.2754986E+02 -.3471802E+02 0.0000000E+00 3 Cl- 0.1424172E-03 0.1424172E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385962E+00 -.6655168E-04 0.1386627E+00 0.0000000E+00 5 HCO3- 0.6874100E-04 0.6874100E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385520E+00 0.1107672E-03 -.1386627E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2626126E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6692749E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1170451E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4661116E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1792791E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7848954E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112706E-01 0.6265250E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254381E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4080000E-06 0.4080000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2284027E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.4760E-14 Mass of aqueous solution: 0.497217E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0007700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5547 -0.256 281.9 2.450 5.160 73.23 grossular 0.1343 -0.872 60.50 1.782 1.108 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2612 -0.583 56.57 1.753 1.036 17.29 hedenbergite 0.6774E-01 -1.169 16.81 1.226 0.3077 4.604 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.156 97.28 tr.625ac.25prg.125 0.4296E-01 -1.367 36.72 1.565 0.6723 11.82 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338117 g Volume = 2210.779991 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0007700 moles log = -3.1135 Original solution: 1000.0103000 g Original solution / Rock added: 1298714.68 (Water/Rock Ratio), log = 6.1135 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2285 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8326E+00 0.9835 0.1006E+01 0.1023E+01 CO2,gas 0.2920E-07 1.0048 0.3604E-07 0.3587E-07 CH4,gas 0.1550E+00 1.0105 0.1924E+00 0.1904E+00 H2,gas 0.1237E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.3854E-06 0.9952 0.4712E-06 0.4734E-06 S2,gas 0.2933E-28 1.0000 0.3604E-28 0.3604E-28 CO,gas 0.1189E-12 1.0000 0.1461E-12 0.1461E-12 SO3,gas 0.1999E-47 1.0000 0.2456E-47 0.2456E-47 SO2,gas 0.1183E-26 1.0000 0.1453E-26 0.1453E-26 HF,gas 0.6965E-15 1.0000 0.8556E-15 0.8556E-15 HCl,gas 0.4680E-17 1.0000 0.5749E-17 0.5749E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.80 -9.14 -3.047 0.15610E+05 -7.443 3 CH4,gas 4.54 2.13 -2.41 -0.604 0.41231E+04 -0.716 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.26 -8.03 -4.013 0.13704E+05 -6.327 6 S2,gas -7.34 -37.48 -30.14 -4.637 0.51467E+05 -28.443 7 CO,gas 3.21 -11.32 -14.53 -4.472 0.24817E+05 -12.835 8 SO3,gas 17.12 -32.19 -49.31 -12.327 0.84193E+05 -47.610 9 SO2,gas 0.83 -27.70 -28.54 -7.610 0.48726E+05 -26.838 10 HF,gas 0.47 -16.29 -16.77 -8.383 0.28629E+05 -15.068 11 HCl,gas 5.19 -13.75 -18.94 -9.470 0.32338E+05 -17.240 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.45 -0.15 -0.012 0.24886E+03 38 aragonite 0.97 -2.70 -3.67 -1.222 0.62613E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.70 -3.51 -1.171 0.59971E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.84 -3.73 -1.067 0.63762E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.84 -3.29 -0.940 0.56184E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.52 -3.26 -1.087 0.55676E+04 147 pyrrhotiteFe0.875 -6.02 -8.92 -2.90 -1.067 0.49548E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.52 -3.11 -1.037 0.53104E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.01 -4.04 -1.346 0.68923E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0007700 MOLES New total amount of reactant added: 0.0007900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8650E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0007900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136796E-01 Osmotic coef. = 1.0628 True ionic strength = .2013445E-01 Chg. balance for total moles = -.8650E-10 Max. difference allowed = 0.1425E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88784E-10 -10.0517 0.74574E-10 -10.1274 0.83995E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28585E-03 -3.5439 0.23865E-03 -3.6222 0.83487E+00 -0.0784 4 SO4-- 0.22777E-11 -11.6425 0.11810E-11 -11.9277 0.51852E+00 -0.2852 5 HCO3- 0.25815E-05 -5.5881 0.21584E-05 -5.6659 0.83610E+00 -0.0777 6 HS- 0.90043E-04 -4.0455 0.75186E-04 -4.1239 0.83500E+00 -0.0783 7 Al+++ 0.98756E-29 -29.0054 0.22737E-29 -29.6433 0.23023E+00 -0.6378 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13660E-06 -6.8646 0.70307E-07 -7.1530 0.51470E+00 -0.2884 10 Mg++ 0.21370E-10 -10.6702 0.10949E-10 -10.9606 0.51233E+00 -0.2904 11 Fe++ 0.58900E-13 -13.2299 0.30210E-13 -13.5199 0.51290E+00 -0.2900 12 K+ 0.15739E-03 -3.8030 0.13162E-03 -3.8807 0.83630E+00 -0.0776 13 Na+ 0.19972E-01 -1.6996 0.16671E-01 -1.7780 0.83472E+00 -0.0785 14 Mn++ 0.18897E-10 -10.7236 0.97001E-11 -11.0132 0.51332E+00 -0.2896 15 F- 0.83540E-06 -6.0781 0.69601E-06 -6.1574 0.83314E+00 -0.0793 16 HPO4-- 0.44921E-07 -7.3475 0.23296E-07 -7.6327 0.51860E+00 -0.2852 18 HSiO3- 0.10438E-01 -1.9814 0.87144E-02 -2.0598 0.83487E+00 -0.0784 19 Ca(HSiO3)+ 0.16681E-07 -7.7778 0.13953E-07 -7.8553 0.83648E+00 -0.0775 20 Mg(HSiO3)+ 0.32328E-11 -11.4904 0.27042E-11 -11.5680 0.83648E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66494E-16 -16.1772 0.55620E-16 -16.2548 0.83648E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52906E-05 -5.2765 0.44089E-05 -5.3557 0.83336E+00 -0.0792 26 CH4,aq 0.13394E-03 -3.8731 0.13347E-03 -3.8746 0.99653E+00 -0.0015 27 C2H6,aq 0.26386E-12 -12.5786 0.26294E-12 -12.5801 0.99653E+00 -0.0015 28 C3H8,aq 0.12001E-19 -19.9208 0.11959E-19 -19.9223 0.99653E+00 -0.0015 31 CO,aq 0.10007E-15 -15.9997 0.10007E-15 -15.9997 0.10000E+01 0.0000 32 CO2,aq 0.34513E-09 -9.4620 0.34393E-09 -9.4635 0.99653E+00 -0.0015 33 CO3-2 0.48859E-05 -5.3111 0.25281E-05 -5.5972 0.51742E+00 -0.2862 34 CaCO3,aq 0.22287E-08 -8.6520 0.22287E-08 -8.6520 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.46308E-11 -11.3343 0.38736E-11 -11.4119 0.83648E+00 -0.0775 36 CaCl+ 0.32461E-10 -10.4886 0.27153E-10 -10.5662 0.83648E+00 -0.0775 37 CaCl2,aq 0.15395E-14 -14.8126 0.15395E-14 -14.8126 0.10000E+01 0.0000 38 CaF+ 0.85412E-12 -12.0685 0.71445E-12 -12.1460 0.83648E+00 -0.0775 39 CaOH+ 0.80327E-07 -7.0951 0.67192E-07 -7.1727 0.83648E+00 -0.0775 40 CaSO4,aq 0.26368E-16 -16.5789 0.26368E-16 -16.5789 0.10000E+01 0.0000 41 HCl,aq 0.32612E-14 -14.4866 0.32612E-14 -14.4866 0.10000E+01 0.0000 45 HF,aq 0.35532E-12 -12.4494 0.35532E-12 -12.4494 0.10000E+01 0.0000 46 HF2- 0.10001E-18 -18.9999 0.83497E-19 -19.0783 0.83487E+00 -0.0784 48 FeCl+ 0.13642E-16 -16.8651 0.11411E-16 -16.9427 0.83648E+00 -0.0775 51 FeF+ 0.12845E-17 -17.8913 0.10745E-17 -17.9688 0.83648E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15764E-10 -10.8023 0.13186E-10 -10.8799 0.83648E+00 -0.0775 55 HFeO2- 0.35481E-07 -7.4500 0.29622E-07 -7.5284 0.83487E+00 -0.0784 56 FeO+ 0.11048E-16 -16.9567 0.92417E-17 -17.0342 0.83648E+00 -0.0775 58 FeO2- 0.40729E-09 -9.3901 0.34004E-09 -9.4685 0.83487E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56930E-09 -9.2447 0.56930E-09 -9.2447 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.28893E-14 -14.5392 0.24122E-14 -14.6176 0.83487E+00 -0.0784 65 MgCO3,aq 0.86995E-13 -13.0605 0.86995E-13 -13.0605 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.73688E-15 -15.1326 0.61639E-15 -15.2101 0.83648E+00 -0.0775 67 MgCl+ 0.45816E-14 -14.3390 0.38324E-14 -14.4165 0.83648E+00 -0.0775 68 MgF+ 0.49271E-15 -15.3074 0.41214E-15 -15.3850 0.83648E+00 -0.0775 69 MgOH+ 0.69219E-10 -10.1598 0.57900E-10 -10.2373 0.83648E+00 -0.0775 71 MnF+ 0.13595E-15 -15.8666 0.11372E-15 -15.9442 0.83648E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47022E-09 -9.3277 0.39333E-09 -9.4052 0.83648E+00 -0.0775 74 MnO2-2 0.20833E-10 -10.6812 0.10779E-10 -10.9674 0.51742E+00 -0.2862 75 HMnO2- 0.21095E-09 -9.6758 0.17611E-09 -9.7542 0.83487E+00 -0.0784 78 MnCl+ 0.17042E-13 -13.7685 0.14255E-13 -13.8460 0.83648E+00 -0.0775 80 NaCl,aq 0.13185E-05 -5.8799 0.13185E-05 -5.8799 0.10000E+01 0.0000 81 NaF,aq 0.27165E-08 -8.5660 0.27165E-08 -8.5660 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92969E-02 -2.0317 0.77477E-02 -2.1108 0.83336E+00 -0.0792 89 HPO3-2 0.16251E-14 -14.7891 0.84088E-15 -15.0753 0.51742E+00 -0.2862 91 H2PO3- 0.15062E-18 -18.8221 0.12575E-18 -18.9005 0.83487E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38350E-10 -10.4162 0.32048E-10 -10.4942 0.83567E+00 -0.0780 94 PO4-3 0.10538E-08 -8.9772 0.25488E-09 -9.5937 0.24187E+00 -0.6164 98 HP2O7-3 0.93565E-18 -18.0289 0.21563E-18 -18.6663 0.23047E+00 -0.6374 99 P2O7-4 0.90127E-17 -17.0451 0.69078E-18 -18.1607 0.76645E-01 -1.1155 100 H2S,aq 0.17389E-07 -7.7597 0.17329E-07 -7.7612 0.99653E+00 -0.0015 101 S2-2 0.20901E-13 -13.6798 0.10814E-13 -13.9660 0.51742E+00 -0.2862 107 SO3-2 0.33864E-17 -17.4703 0.17776E-17 -17.7502 0.52493E+00 -0.2799 109 HSO4- 0.10137E-18 -18.9941 0.84879E-19 -19.0712 0.83730E+00 -0.0771 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8878399E-10 -.2221046E-01 -.2234775E+02 0.0000 2 H2O 0.1000000E+01 0.5550501E+02 0.9981946E+06 0.0000 3 Cl- 0.2858479E-03 0.2871670E-03 0.1016317E+02 6.5052 4 SO4-- 0.2277699E-11 -.1368420E-03 -.1312233E+02 8.3271 5 HCO3- 0.2581508E-05 0.1414064E-03 0.8613167E+01 4.4615 6 HS- 0.9004308E-04 0.2269025E-03 0.7491025E+01 6.0035 7 Al+++ 0.9875591E-29 0.5290704E-05 0.1425020E+00 0.7390 8 H4SiO4 0.6959777E-03 0.1348360E-01 0.1293720E+04 -3.1574 9 Ca++ 0.1365993E-06 0.2358739E-06 0.9436860E-02 13.1018 10 Mg++ 0.2137042E-10 0.9391599E-10 0.2279301E-05 9.2942 11 Fe++ 0.5890049E-13 0.3611833E-07 0.2013581E-02 6.7350 12 K+ 0.1573857E-03 0.1581400E-03 0.6172802E+01 6.2467 13 Na+ 0.1997163E-01 0.2241862E-01 0.5145002E+03 8.3494 14 Mn++ 0.1889663E-10 0.2527231E-08 0.1385988E-03 9.2416 15 F- 0.8354014E-06 0.8381191E-06 0.1589480E-01 3.9700 16 HPO4-- 0.4492149E-07 0.4601363E-07 0.4408636E-02 12.6221 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279246E+02 -.1102415E-01 -.8278144E+02 0.0000000E+00 2 H2O -.7168142E+01 0.2754989E+02 -.3471803E+02 0.0000000E+00 3 Cl- 0.1425352E-03 0.1425352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385963E+00 -.6792147E-04 0.1386642E+00 0.0000000E+00 5 HCO3- 0.7018700E-04 0.7018700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385516E+00 0.1126229E-03 -.1386642E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2626038E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6692577E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1170759E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4661516E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1792732E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7849274E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112747E-01 0.6265249E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254390E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4160000E-06 0.4160000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2283884E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.7841E-15 Mass of aqueous solution: 0.497217E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0007900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5547 -0.256 281.9 2.450 5.160 73.23 grossular 0.1343 -0.872 60.50 1.782 1.108 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2612 -0.583 56.56 1.753 1.035 17.29 hedenbergite 0.6773E-01 -1.169 16.80 1.225 0.3077 4.603 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.156 97.28 tr.625ac.25prg.125 0.4297E-01 -1.367 36.73 1.565 0.6725 11.82 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338124 g Volume = 2210.780046 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0007900 moles log = -3.1024 Original solution: 1000.0103000 g Original solution / Rock added: 1265835.82 (Water/Rock Ratio), log = 6.1024 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2325 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8299E+00 0.9834 0.1006E+01 0.1023E+01 CO2,gas 0.2971E-07 1.0047 0.3680E-07 0.3662E-07 CH4,gas 0.1578E+00 1.0104 0.1965E+00 0.1944E+00 H2,gas 0.1233E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.3883E-06 0.9952 0.4764E-06 0.4786E-06 S2,gas 0.2989E-28 1.0000 0.3683E-28 0.3683E-28 CO,gas 0.1210E-12 1.0000 0.1491E-12 0.1491E-12 SO3,gas 0.2015E-47 1.0000 0.2483E-47 0.2483E-47 SO2,gas 0.1192E-26 1.0000 0.1469E-26 0.1469E-26 HF,gas 0.7078E-15 1.0000 0.8724E-15 0.8724E-15 HCl,gas 0.4669E-17 1.0000 0.5754E-17 0.5754E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 -0.60662E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.79 -9.13 -3.044 0.15595E+05 -7.434 3 CH4,gas 4.54 2.14 -2.41 -0.601 0.41077E+04 -0.707 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.25 -8.02 -4.011 0.13696E+05 -6.322 6 S2,gas -7.34 -37.47 -30.13 -4.636 0.51451E+05 -28.434 7 CO,gas 3.21 -11.31 -14.53 -4.469 0.24802E+05 -12.826 8 SO3,gas 17.12 -32.18 -49.30 -12.326 0.84185E+05 -47.605 9 SO2,gas 0.83 -27.70 -28.53 -7.609 0.48717E+05 -26.833 10 HF,gas 0.47 -16.28 -16.76 -8.379 0.28614E+05 -15.059 11 HCl,gas 5.19 -13.75 -18.94 -9.469 0.32338E+05 -17.240 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.44 -0.14 -0.011 0.23443E+03 38 aragonite 0.97 -2.69 -3.66 -1.219 0.62459E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.69 -3.50 -1.168 0.59817E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.83 -3.73 -1.064 0.63608E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.83 -3.28 -0.938 0.56030E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.52 -3.26 -1.085 0.55595E+04 147 pyrrhotiteFe0.875 -6.02 -8.91 -2.90 -1.066 0.49467E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.52 -3.11 -1.035 0.53023E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.01 -4.03 -1.344 0.68842E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000200 MOLES Current total amount of reactant added: 0.0007900 MOLES New total amount of reactant added: 0.0008100 MOLES Mixing fraction reached given limit of 0.8000E-03 TOTMIX = 0.8100E-03 Execution stopped.