File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.82792E+02 0.88784E-10 0.8399 0.00000000E+00 H2O 2 0. -0.71681E+01 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.14254E-03 0.28585E-03 0.8349 0.00000000E+00 SO4-- 4 -2. 0.13860E+00 0.22777E-11 0.5185 0.00000000E+00 HCO3- 5 -1. 0.70187E-04 0.25815E-05 0.8361 0.00000000E+00 HS- 6 -1. -0.13855E+00 0.90043E-04 0.8350 0.00000000E+00 Al+++ 7 3. 0.16304E+02 0.98756E-29 0.2302 0.00000000E+00 H4SiO4 8 0. 0.52064E+02 0.69598E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.57507E+01 0.13660E-06 0.5147 0.00000000E+00 Mg++ 10 2. 0.39683E+01 0.21370E-10 0.5123 0.00000000E+00 Fe++ 11 2. 0.35650E+01 0.58900E-13 0.5129 0.00000000E+00 K+ 12 1. 0.10616E+01 0.15739E-03 0.8363 0.00000000E+00 Na+ 13 1. 0.62764E+01 0.19972E-01 0.8347 0.00000000E+00 Mn++ 14 2. 0.86693E-01 0.18897E-10 0.5133 0.00000000E+00 F- 15 -1. 0.41600E-06 0.83540E-06 0.8331 0.00000000E+00 HPO4-- 16 -2. 0.29588E-01 0.44921E-07 0.5186 0.00000000E+00 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1425E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E-02 TEMP = 100.0000 SINC = 0.4000E-04 TEMPC = 0.0000 TOTMIX = 0.790000E-03 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 2000.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.6260E+01 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.5547E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.1343E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.9863E-02 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.0000E+00 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.3220E+01 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.2612E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.7103E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.2056E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.1734E-01 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.2612E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.6773E-01 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.9309E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.4297E-01 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0007900 moles log = -3.1024 Original solution: 1000.0103000 g Original solution / Rock added: 1265835.82 (Water/Rock Ratio), log = 6.1024 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0007900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136796E-01 Osmotic coef. = 1.0628 True ionic strength = .2013445E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1425E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88784E-10 -10.0517 0.74574E-10 -10.1274 0.83995E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28585E-03 -3.5439 0.23865E-03 -3.6222 0.83487E+00 -0.0784 4 SO4-- 0.22777E-11 -11.6425 0.11810E-11 -11.9277 0.51852E+00 -0.2852 5 HCO3- 0.25815E-05 -5.5881 0.21584E-05 -5.6659 0.83610E+00 -0.0777 6 HS- 0.90043E-04 -4.0455 0.75186E-04 -4.1239 0.83500E+00 -0.0783 7 Al+++ 0.98756E-29 -29.0054 0.22737E-29 -29.6433 0.23023E+00 -0.6378 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13660E-06 -6.8646 0.70307E-07 -7.1530 0.51470E+00 -0.2884 10 Mg++ 0.21370E-10 -10.6702 0.10949E-10 -10.9606 0.51233E+00 -0.2904 11 Fe++ 0.58900E-13 -13.2299 0.30210E-13 -13.5199 0.51290E+00 -0.2900 12 K+ 0.15739E-03 -3.8030 0.13162E-03 -3.8807 0.83630E+00 -0.0776 13 Na+ 0.19972E-01 -1.6996 0.16671E-01 -1.7780 0.83472E+00 -0.0785 14 Mn++ 0.18897E-10 -10.7236 0.97001E-11 -11.0132 0.51332E+00 -0.2896 15 F- 0.83540E-06 -6.0781 0.69601E-06 -6.1574 0.83314E+00 -0.0793 16 HPO4-- 0.44921E-07 -7.3475 0.23296E-07 -7.6327 0.51860E+00 -0.2852 18 HSiO3- 0.10438E-01 -1.9814 0.87144E-02 -2.0598 0.83487E+00 -0.0784 19 Ca(HSiO3)+ 0.16681E-07 -7.7778 0.13953E-07 -7.8553 0.83648E+00 -0.0775 20 Mg(HSiO3)+ 0.32328E-11 -11.4904 0.27042E-11 -11.5680 0.83648E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66494E-16 -16.1772 0.55620E-16 -16.2548 0.83648E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52906E-05 -5.2765 0.44089E-05 -5.3557 0.83336E+00 -0.0792 26 CH4,aq 0.13394E-03 -3.8731 0.13347E-03 -3.8746 0.99653E+00 -0.0015 27 C2H6,aq 0.26386E-12 -12.5786 0.26294E-12 -12.5801 0.99653E+00 -0.0015 28 C3H8,aq 0.12001E-19 -19.9208 0.11959E-19 -19.9223 0.99653E+00 -0.0015 31 CO,aq 0.10007E-15 -15.9997 0.10007E-15 -15.9997 0.10000E+01 0.0000 32 CO2,aq 0.34513E-09 -9.4620 0.34393E-09 -9.4635 0.99653E+00 -0.0015 33 CO3-2 0.48859E-05 -5.3111 0.25281E-05 -5.5972 0.51742E+00 -0.2862 34 CaCO3,aq 0.22287E-08 -8.6520 0.22287E-08 -8.6520 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.46308E-11 -11.3343 0.38736E-11 -11.4119 0.83648E+00 -0.0775 36 CaCl+ 0.32461E-10 -10.4886 0.27153E-10 -10.5662 0.83648E+00 -0.0775 37 CaCl2,aq 0.15395E-14 -14.8126 0.15395E-14 -14.8126 0.10000E+01 0.0000 38 CaF+ 0.85412E-12 -12.0685 0.71445E-12 -12.1460 0.83648E+00 -0.0775 39 CaOH+ 0.80327E-07 -7.0951 0.67192E-07 -7.1727 0.83648E+00 -0.0775 40 CaSO4,aq 0.26368E-16 -16.5789 0.26368E-16 -16.5789 0.10000E+01 0.0000 41 HCl,aq 0.32612E-14 -14.4866 0.32612E-14 -14.4866 0.10000E+01 0.0000 45 HF,aq 0.35532E-12 -12.4494 0.35532E-12 -12.4494 0.10000E+01 0.0000 46 HF2- 0.10001E-18 -18.9999 0.83497E-19 -19.0783 0.83487E+00 -0.0784 48 FeCl+ 0.13642E-16 -16.8651 0.11411E-16 -16.9427 0.83648E+00 -0.0775 51 FeF+ 0.12845E-17 -17.8913 0.10745E-17 -17.9688 0.83648E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15764E-10 -10.8023 0.13186E-10 -10.8799 0.83648E+00 -0.0775 55 HFeO2- 0.35481E-07 -7.4500 0.29622E-07 -7.5284 0.83487E+00 -0.0784 56 FeO+ 0.11048E-16 -16.9567 0.92417E-17 -17.0342 0.83648E+00 -0.0775 58 FeO2- 0.40729E-09 -9.3901 0.34004E-09 -9.4685 0.83487E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.56930E-09 -9.2447 0.56930E-09 -9.2447 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.28893E-14 -14.5392 0.24122E-14 -14.6176 0.83487E+00 -0.0784 65 MgCO3,aq 0.86995E-13 -13.0605 0.86995E-13 -13.0605 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.73688E-15 -15.1326 0.61639E-15 -15.2101 0.83648E+00 -0.0775 67 MgCl+ 0.45816E-14 -14.3390 0.38324E-14 -14.4165 0.83648E+00 -0.0775 68 MgF+ 0.49271E-15 -15.3074 0.41214E-15 -15.3850 0.83648E+00 -0.0775 69 MgOH+ 0.69219E-10 -10.1598 0.57900E-10 -10.2373 0.83648E+00 -0.0775 71 MnF+ 0.13595E-15 -15.8666 0.11372E-15 -15.9442 0.83648E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47022E-09 -9.3277 0.39333E-09 -9.4052 0.83648E+00 -0.0775 74 MnO2-2 0.20833E-10 -10.6812 0.10779E-10 -10.9674 0.51742E+00 -0.2862 75 HMnO2- 0.21095E-09 -9.6758 0.17611E-09 -9.7542 0.83487E+00 -0.0784 78 MnCl+ 0.17042E-13 -13.7685 0.14255E-13 -13.8460 0.83648E+00 -0.0775 80 NaCl,aq 0.13185E-05 -5.8799 0.13185E-05 -5.8799 0.10000E+01 0.0000 81 NaF,aq 0.27165E-08 -8.5660 0.27165E-08 -8.5660 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92969E-02 -2.0317 0.77477E-02 -2.1108 0.83336E+00 -0.0792 89 HPO3-2 0.16251E-14 -14.7891 0.84088E-15 -15.0753 0.51742E+00 -0.2862 91 H2PO3- 0.15062E-18 -18.8221 0.12575E-18 -18.9005 0.83487E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38350E-10 -10.4162 0.32048E-10 -10.4942 0.83567E+00 -0.0780 94 PO4-3 0.10538E-08 -8.9772 0.25488E-09 -9.5937 0.24187E+00 -0.6164 98 HP2O7-3 0.93565E-18 -18.0289 0.21563E-18 -18.6663 0.23047E+00 -0.6374 99 P2O7-4 0.90127E-17 -17.0451 0.69078E-18 -18.1607 0.76645E-01 -1.1155 100 H2S,aq 0.17389E-07 -7.7597 0.17329E-07 -7.7612 0.99653E+00 -0.0015 101 S2-2 0.20901E-13 -13.6798 0.10814E-13 -13.9660 0.51742E+00 -0.2862 107 SO3-2 0.33864E-17 -17.4703 0.17776E-17 -17.7502 0.52493E+00 -0.2799 109 HSO4- 0.10137E-18 -18.9941 0.84879E-19 -19.0712 0.83730E+00 -0.0771 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8878399E-10 -.2221046E-01 -.2234775E+02 0.0000 2 H2O 0.1000000E+01 0.5550501E+02 0.9981946E+06 0.0000 3 Cl- 0.2858479E-03 0.2871670E-03 0.1016317E+02 6.5052 4 SO4-- 0.2277699E-11 -.1368420E-03 -.1312233E+02 8.3271 5 HCO3- 0.2581508E-05 0.1414064E-03 0.8613167E+01 4.4615 6 HS- 0.9004308E-04 0.2269025E-03 0.7491025E+01 6.0035 7 Al+++ 0.9875591E-29 0.5290704E-05 0.1425020E+00 0.7390 8 H4SiO4 0.6959777E-03 0.1348360E-01 0.1293720E+04 -3.1574 9 Ca++ 0.1365993E-06 0.2358739E-06 0.9436860E-02 13.1018 10 Mg++ 0.2137042E-10 0.9391599E-10 0.2279301E-05 9.2942 11 Fe++ 0.5890049E-13 0.3611833E-07 0.2013581E-02 6.7350 12 K+ 0.1573857E-03 0.1581400E-03 0.6172802E+01 6.2467 13 Na+ 0.1997163E-01 0.2241862E-01 0.5145002E+03 8.3494 14 Mn++ 0.1889663E-10 0.2527231E-08 0.1385988E-03 9.2416 15 F- 0.8354014E-06 0.8381191E-06 0.1589480E-01 3.9700 16 HPO4-- 0.4492149E-07 0.4601363E-07 0.4408636E-02 12.6221 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279246E+02 -.1102415E-01 -.8278144E+02 0.0000000E+00 2 H2O -.7168142E+01 0.2754989E+02 -.3471803E+02 0.0000000E+00 3 Cl- 0.1425352E-03 0.1425352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385963E+00 -.6792147E-04 0.1386642E+00 0.0000000E+00 5 HCO3- 0.7018700E-04 0.7018700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385516E+00 0.1126229E-03 -.1386642E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2626038E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6692577E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1170759E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4661516E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1792732E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7849274E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112747E-01 0.6265249E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254390E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4160000E-06 0.4160000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2283884E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.7841E-15 Mass of aqueous solution: 0.497217E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0007900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5547 -0.256 281.9 2.450 5.160 73.23 grossular 0.1343 -0.872 60.50 1.782 1.108 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2612 -0.583 56.56 1.753 1.035 17.29 hedenbergite 0.6773E-01 -1.169 16.80 1.225 0.3077 4.603 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.156 97.28 tr.625ac.25prg.125 0.4297E-01 -1.367 36.73 1.565 0.6725 11.82 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338124 g Volume = 2210.780046 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0007900 moles log = -3.1024 Original solution: 1000.0103000 g Original solution / Rock added: 1265835.82 (Water/Rock Ratio), log = 6.1024 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2325 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8299E+00 0.9834 0.1006E+01 0.1023E+01 CO2,gas 0.2971E-07 1.0047 0.3680E-07 0.3662E-07 CH4,gas 0.1578E+00 1.0104 0.1965E+00 0.1944E+00 H2,gas 0.1233E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.3883E-06 0.9952 0.4764E-06 0.4786E-06 S2,gas 0.2989E-28 1.0000 0.3683E-28 0.3683E-28 CO,gas 0.1210E-12 1.0000 0.1491E-12 0.1491E-12 SO3,gas 0.2015E-47 1.0000 0.2483E-47 0.2483E-47 SO2,gas 0.1192E-26 1.0000 0.1469E-26 0.1469E-26 HF,gas 0.7078E-15 1.0000 0.8724E-15 0.8724E-15 HCl,gas 0.4669E-17 1.0000 0.5754E-17 0.5754E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.79 -9.13 -3.044 0.15595E+05 -7.434 3 CH4,gas 4.54 2.14 -2.41 -0.601 0.41077E+04 -0.707 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.25 -8.02 -4.011 0.13696E+05 -6.322 6 S2,gas -7.34 -37.47 -30.13 -4.636 0.51451E+05 -28.434 7 CO,gas 3.21 -11.31 -14.53 -4.469 0.24802E+05 -12.826 8 SO3,gas 17.12 -32.18 -49.30 -12.326 0.84185E+05 -47.605 9 SO2,gas 0.83 -27.70 -28.53 -7.609 0.48717E+05 -26.833 10 HF,gas 0.47 -16.28 -16.76 -8.379 0.28614E+05 -15.059 11 HCl,gas 5.19 -13.75 -18.94 -9.469 0.32338E+05 -17.240 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.44 -0.14 -0.011 0.23443E+03 38 aragonite 0.97 -2.69 -3.66 -1.219 0.62459E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.69 -3.50 -1.168 0.59817E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.83 -3.73 -1.064 0.63608E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.83 -3.28 -0.938 0.56030E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 146 pyrrhotite -4.26 -7.52 -3.26 -1.085 0.55595E+04 147 pyrrhotiteFe0.875 -6.02 -8.91 -2.90 -1.066 0.49467E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.52 -3.11 -1.035 0.53023E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.01 -4.03 -1.344 0.68842E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0007900 MOLES New total amount of reactant added: 0.0008300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0008300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136464E-01 Osmotic coef. = 1.0779 True ionic strength = .2013627E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1428E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88791E-10 -10.0516 0.74579E-10 -10.1274 0.83994E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28632E-03 -3.5431 0.23904E-03 -3.6215 0.83487E+00 -0.0784 4 SO4-- 0.23271E-11 -11.6332 0.12066E-11 -11.9184 0.51851E+00 -0.2852 5 HCO3- 0.26877E-05 -5.5706 0.22472E-05 -5.6484 0.83609E+00 -0.0777 6 HS- 0.92001E-04 -4.0362 0.76820E-04 -4.1145 0.83499E+00 -0.0783 7 Al+++ 0.98783E-29 -29.0053 0.22742E-29 -29.6432 0.23022E+00 -0.6379 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13662E-06 -6.8645 0.70318E-07 -7.1529 0.51469E+00 -0.2885 10 Mg++ 0.21374E-10 -10.6701 0.10950E-10 -10.9606 0.51232E+00 -0.2905 11 Fe++ 0.58911E-13 -13.2298 0.30214E-13 -13.5198 0.51288E+00 -0.2900 12 K+ 0.15740E-03 -3.8030 0.13163E-03 -3.8806 0.83629E+00 -0.0776 13 Na+ 0.19973E-01 -1.6996 0.16672E-01 -1.7780 0.83472E+00 -0.0785 14 Mn++ 0.18900E-10 -10.7235 0.97016E-11 -11.0132 0.51331E+00 -0.2896 15 F- 0.86753E-06 -6.0617 0.72277E-06 -6.1410 0.83314E+00 -0.0793 16 HPO4-- 0.44916E-07 -7.3476 0.23293E-07 -7.6328 0.51858E+00 -0.2852 18 HSiO3- 0.10437E-01 -1.9814 0.87137E-02 -2.0598 0.83487E+00 -0.0784 19 Ca(HSiO3)+ 0.16682E-07 -7.7777 0.13954E-07 -7.8553 0.83647E+00 -0.0775 20 Mg(HSiO3)+ 0.32331E-11 -11.4904 0.27044E-11 -11.5679 0.83647E+00 -0.0775 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66499E-16 -16.1772 0.55625E-16 -16.2547 0.83647E+00 -0.0775 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52902E-05 -5.2765 0.44086E-05 -5.3557 0.83335E+00 -0.0792 26 CH4,aq 0.13946E-03 -3.8556 0.13897E-03 -3.8571 0.99653E+00 -0.0015 27 C2H6,aq 0.28605E-12 -12.5436 0.28506E-12 -12.5451 0.99653E+00 -0.0015 28 C3H8,aq 0.13546E-19 -19.8682 0.13500E-19 -19.8697 0.99653E+00 -0.0015 30 ethanol,aq 0.10499E-19 -19.9788 0.10463E-19 -19.9804 0.99653E+00 -0.0015 31 CO,aq 0.10420E-15 -15.9821 0.10420E-15 -15.9821 0.10000E+01 0.0000 32 CO2,aq 0.35935E-09 -9.4445 0.35811E-09 -9.4460 0.99653E+00 -0.0015 33 CO3-2 0.50866E-05 -5.2936 0.26319E-05 -5.5797 0.51740E+00 -0.2862 34 CaCO3,aq 0.23205E-08 -8.6344 0.23205E-08 -8.6344 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.48221E-11 -11.3168 0.40335E-11 -11.3943 0.83647E+00 -0.0775 36 CaCl+ 0.32520E-10 -10.4879 0.27202E-10 -10.5654 0.83647E+00 -0.0775 37 CaCl2,aq 0.15448E-14 -14.8111 0.15448E-14 -14.8111 0.10000E+01 0.0000 38 CaF+ 0.88710E-12 -12.0520 0.74203E-12 -12.1296 0.83647E+00 -0.0775 39 CaOH+ 0.80334E-07 -7.0951 0.67197E-07 -7.1727 0.83647E+00 -0.0775 40 CaSO4,aq 0.26943E-16 -16.5696 0.26943E-16 -16.5696 0.10000E+01 0.0000 41 HCl,aq 0.32668E-14 -14.4859 0.32668E-14 -14.4859 0.10000E+01 0.0000 45 HF,aq 0.36901E-12 -12.4330 0.36901E-12 -12.4330 0.10000E+01 0.0000 46 HF2- 0.10786E-18 -18.9671 0.90049E-19 -19.0455 0.83487E+00 -0.0784 48 FeCl+ 0.13667E-16 -16.8643 0.11432E-16 -16.9419 0.83647E+00 -0.0775 51 FeF+ 0.13341E-17 -17.8748 0.11160E-17 -17.9523 0.83647E+00 -0.0775 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15765E-10 -10.8023 0.13187E-10 -10.8798 0.83647E+00 -0.0775 55 HFeO2- 0.35478E-07 -7.4500 0.29620E-07 -7.5284 0.83487E+00 -0.0784 56 FeO+ 0.11049E-16 -16.9567 0.92424E-17 -17.0342 0.83647E+00 -0.0775 58 FeO2- 0.40726E-09 -9.3901 0.34001E-09 -9.4685 0.83487E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 61 KCl,aq 0.57028E-09 -9.2439 0.57028E-09 -9.2439 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.29521E-14 -14.5299 0.24646E-14 -14.6082 0.83487E+00 -0.0784 65 MgCO3,aq 0.90580E-13 -13.0430 0.90580E-13 -13.0430 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.76731E-15 -15.1150 0.64183E-15 -15.1926 0.83647E+00 -0.0775 67 MgCl+ 0.45899E-14 -14.3382 0.38393E-14 -14.4157 0.83647E+00 -0.0775 68 MgF+ 0.51173E-15 -15.2910 0.42805E-15 -15.3685 0.83647E+00 -0.0775 69 MgOH+ 0.69225E-10 -10.1597 0.57905E-10 -10.2373 0.83647E+00 -0.0775 71 MnF+ 0.14120E-15 -15.8502 0.11811E-15 -15.9277 0.83647E+00 -0.0775 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47026E-09 -9.3277 0.39336E-09 -9.4052 0.83647E+00 -0.0775 74 MnO2-2 0.20830E-10 -10.6813 0.10778E-10 -10.9675 0.51740E+00 -0.2862 75 HMnO2- 0.21093E-09 -9.6759 0.17610E-09 -9.7542 0.83487E+00 -0.0784 78 MnCl+ 0.17072E-13 -13.7677 0.14281E-13 -13.8453 0.83647E+00 -0.0775 80 NaCl,aq 0.13207E-05 -5.8792 0.13207E-05 -5.8792 0.10000E+01 0.0000 81 NaF,aq 0.28211E-08 -8.5496 0.28211E-08 -8.5496 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92963E-02 -2.0317 0.77471E-02 -2.1109 0.83335E+00 -0.0792 89 HPO3-2 0.16249E-14 -14.7892 0.84075E-15 -15.0753 0.51740E+00 -0.2862 91 H2PO3- 0.15061E-18 -18.8222 0.12574E-18 -18.9005 0.83487E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38348E-10 -10.4163 0.32046E-10 -10.4942 0.83566E+00 -0.0780 94 PO4-3 0.10536E-08 -8.9773 0.25482E-09 -9.5938 0.24185E+00 -0.6164 98 HP2O7-3 0.93549E-18 -18.0290 0.21559E-18 -18.6664 0.23045E+00 -0.6374 99 P2O7-4 0.90109E-17 -17.0452 0.69058E-18 -18.1608 0.76638E-01 -1.1156 100 H2S,aq 0.17768E-07 -7.7504 0.17707E-07 -7.7519 0.99653E+00 -0.0015 101 S2-2 0.21820E-13 -13.6612 0.11290E-13 -13.9473 0.51740E+00 -0.2862 107 SO3-2 0.34598E-17 -17.4609 0.18161E-17 -17.7409 0.52492E+00 -0.2799 108 HSO3- 0.10158E-19 -19.9932 0.84806E-20 -20.0716 0.83487E+00 -0.0784 109 HSO4- 0.10358E-18 -18.9847 0.86724E-19 -19.0619 0.83729E+00 -0.0771 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8879113E-10 -.2220931E-01 -.2234658E+02 0.0000 2 H2O 0.1000000E+01 0.5550502E+02 0.9981946E+06 0.0000 3 Cl- 0.2863207E-03 0.2876420E-03 0.1017998E+02 6.5059 4 SO4-- 0.2327090E-11 -.1423613E-03 -.1365159E+02 8.3363 5 HCO3- 0.2687706E-05 0.1472327E-03 0.8968051E+01 4.4790 6 HS- 0.9200086E-04 0.2343800E-03 0.7737887E+01 6.0129 7 Al+++ 0.9878339E-29 0.5290343E-05 0.1424923E+00 0.7390 8 H4SiO4 0.6959777E-03 0.1348288E-01 0.1293651E+04 -3.1574 9 Ca++ 0.1366230E-06 0.2359976E-06 0.9441805E-02 13.1018 10 Mg++ 0.2137413E-10 0.9392838E-10 0.2279602E-05 9.2942 11 Fe++ 0.5891073E-13 0.3611587E-07 0.2013443E-02 6.7350 12 K+ 0.1573984E-03 0.1581527E-03 0.6173295E+01 6.2467 13 Na+ 0.1997323E-01 0.2242023E-01 0.5145370E+03 8.3494 14 Mn++ 0.1889998E-10 0.2527265E-08 0.1386006E-03 9.2416 15 F- 0.8675307E-06 0.8703531E-06 0.1650611E-01 3.9864 16 HPO4-- 0.4491585E-07 0.4600781E-07 0.4408078E-02 12.6220 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279246E+02 -.1102359E-01 -.8278143E+02 0.0000000E+00 2 H2O -.7168109E+01 0.2754993E+02 -.3471804E+02 0.0000000E+00 3 Cl- 0.1427712E-03 0.1427712E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385965E+00 -.7066108E-04 0.1386671E+00 0.0000000E+00 5 HCO3- 0.7307900E-04 0.7307900E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385508E+00 0.1163346E-03 -.1386671E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2625863E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6692232E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1171375E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4662137E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1792612E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7849913E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112829E-01 0.6265249E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254409E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4320000E-06 0.4320000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2283599E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1368E-13 Mass of aqueous solution: 0.497218E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0008300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5547 -0.256 281.9 2.450 5.160 73.23 grossular 0.1343 -0.872 60.50 1.782 1.108 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2611 -0.583 56.55 1.752 1.035 17.28 hedenbergite 0.6771E-01 -1.169 16.80 1.225 0.3076 4.601 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.155 97.27 tr.625ac.25prg.125 0.4300E-01 -1.367 36.75 1.565 0.6729 11.83 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338137 g Volume = 2210.780157 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0008300 moles log = -3.0809 Original solution: 1000.0103000 g Original solution / Rock added: 1204831.69 (Water/Rock Ratio), log = 6.0809 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2406 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8246E+00 0.9834 0.1006E+01 0.1023E+01 CO2,gas 0.3074E-07 1.0047 0.3831E-07 0.3814E-07 CH4,gas 0.1632E+00 1.0104 0.2046E+00 0.2025E+00 H2,gas 0.1225E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.3942E-06 0.9952 0.4867E-06 0.4891E-06 S2,gas 0.3100E-28 1.0000 0.3846E-28 0.3846E-28 CO,gas 0.1252E-12 1.0000 0.1553E-12 0.1553E-12 SO3,gas 0.2045E-47 1.0000 0.2538E-47 0.2538E-47 SO2,gas 0.1210E-26 1.0000 0.1501E-26 0.1501E-26 HF,gas 0.7303E-15 1.0000 0.9061E-15 0.9061E-15 HCl,gas 0.4646E-17 1.0000 0.5764E-17 0.5764E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.78 -9.12 -3.039 0.15565E+05 -7.417 3 CH4,gas 4.54 2.16 -2.39 -0.597 0.40777E+04 -0.689 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.24 -8.01 -4.006 0.13680E+05 -6.313 6 S2,gas -7.34 -37.45 -30.11 -4.633 0.51419E+05 -28.415 7 CO,gas 3.21 -11.29 -14.51 -4.464 0.24772E+05 -12.809 8 SO3,gas 17.12 -32.17 -49.29 -12.324 0.84169E+05 -47.596 9 SO2,gas 0.83 -27.69 -28.52 -7.606 0.48701E+05 -26.824 10 HF,gas 0.47 -16.27 -16.74 -8.371 0.28586E+05 -15.043 11 HCl,gas 5.19 -13.75 -18.94 -9.469 0.32336E+05 -17.239 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80709E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.42 -0.12 -0.010 0.20640E+03 38 aragonite 0.97 -2.67 -3.64 -1.213 0.62159E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.67 -3.49 -1.162 0.59517E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.81 -3.71 -1.059 0.63308E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.81 -3.26 -0.933 0.55731E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.23 -4.98 -1.173 0.85113E+04 146 pyrrhotite -4.26 -7.51 -3.25 -1.082 0.55435E+04 147 pyrrhotiteFe0.875 -6.02 -8.90 -2.89 -1.062 0.49307E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.51 -3.10 -1.032 0.52863E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -5.00 -4.02 -1.341 0.68682E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0008300 MOLES New total amount of reactant added: 0.0008700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0008700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136131E-01 Osmotic coef. = 1.0967 True ionic strength = .2013809E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1430E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88798E-10 -10.0516 0.74585E-10 -10.1273 0.83994E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28679E-03 -3.5424 0.23943E-03 -3.6208 0.83486E+00 -0.0784 4 SO4-- 0.23765E-11 -11.6241 0.12322E-11 -11.9093 0.51850E+00 -0.2853 5 HCO3- 0.27939E-05 -5.5538 0.23359E-05 -5.6315 0.83609E+00 -0.0777 6 HS- 0.93959E-04 -4.0271 0.78454E-04 -4.1054 0.83499E+00 -0.0783 7 Al+++ 0.98811E-29 -29.0052 0.22747E-29 -29.6431 0.23021E+00 -0.6379 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13665E-06 -6.8644 0.70328E-07 -7.1529 0.51467E+00 -0.2885 10 Mg++ 0.21378E-10 -10.6700 0.10952E-10 -10.9605 0.51231E+00 -0.2905 11 Fe++ 0.58921E-13 -13.2297 0.30219E-13 -13.5197 0.51287E+00 -0.2900 12 K+ 0.15741E-03 -3.8030 0.13164E-03 -3.8806 0.83629E+00 -0.0776 13 Na+ 0.19975E-01 -1.6995 0.16673E-01 -1.7780 0.83471E+00 -0.0785 14 Mn++ 0.18903E-10 -10.7235 0.97031E-11 -11.0131 0.51330E+00 -0.2896 15 F- 0.89966E-06 -6.0459 0.74954E-06 -6.1252 0.83313E+00 -0.0793 16 HPO4-- 0.44910E-07 -7.3477 0.23289E-07 -7.6328 0.51857E+00 -0.2852 18 HSiO3- 0.10437E-01 -1.9814 0.87131E-02 -2.0598 0.83486E+00 -0.0784 19 Ca(HSiO3)+ 0.16684E-07 -7.7777 0.13955E-07 -7.8553 0.83647E+00 -0.0776 20 Mg(HSiO3)+ 0.32333E-11 -11.4903 0.27046E-11 -11.5679 0.83647E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66504E-16 -16.1772 0.55629E-16 -16.2547 0.83647E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52898E-05 -5.2766 0.44083E-05 -5.3557 0.83335E+00 -0.0792 26 CH4,aq 0.14498E-03 -3.8387 0.14447E-03 -3.8402 0.99654E+00 -0.0015 27 C2H6,aq 0.30914E-12 -12.5098 0.30807E-12 -12.5113 0.99654E+00 -0.0015 28 C3H8,aq 0.15219E-19 -19.8176 0.15167E-19 -19.8191 0.99654E+00 -0.0015 30 ethanol,aq 0.11347E-19 -19.9451 0.11307E-19 -19.9466 0.99654E+00 -0.0015 31 CO,aq 0.10832E-15 -15.9653 0.10832E-15 -15.9653 0.10000E+01 0.0000 32 CO2,aq 0.37358E-09 -9.4276 0.37228E-09 -9.4291 0.99654E+00 -0.0015 33 CO3-2 0.52873E-05 -5.2768 0.27356E-05 -5.5629 0.51739E+00 -0.2862 34 CaCO3,aq 0.24124E-08 -8.6176 0.24124E-08 -8.6176 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.50133E-11 -11.2999 0.41935E-11 -11.3774 0.83647E+00 -0.0776 36 CaCl+ 0.32578E-10 -10.4871 0.27251E-10 -10.5646 0.83647E+00 -0.0776 37 CaCl2,aq 0.15501E-14 -14.8096 0.15501E-14 -14.8096 0.10000E+01 0.0000 38 CaF+ 0.92009E-12 -12.0362 0.76963E-12 -12.1137 0.83647E+00 -0.0776 39 CaOH+ 0.80340E-07 -7.0951 0.67202E-07 -7.1726 0.83647E+00 -0.0776 40 CaSO4,aq 0.27518E-16 -16.5604 0.27518E-16 -16.5604 0.10000E+01 0.0000 41 HCl,aq 0.32724E-14 -14.4851 0.32724E-14 -14.4851 0.10000E+01 0.0000 45 HF,aq 0.38270E-12 -12.4171 0.38270E-12 -12.4171 0.10000E+01 0.0000 46 HF2- 0.11600E-18 -18.9355 0.96848E-19 -19.0139 0.83486E+00 -0.0784 48 FeCl+ 0.13691E-16 -16.8636 0.11452E-16 -16.9411 0.83647E+00 -0.0776 51 FeF+ 0.13837E-17 -17.8589 0.11575E-17 -17.9365 0.83647E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15767E-10 -10.8023 0.13188E-10 -10.8798 0.83647E+00 -0.0776 55 HFeO2- 0.35476E-07 -7.4501 0.29618E-07 -7.5285 0.83486E+00 -0.0784 56 FeO+ 0.11050E-16 -16.9566 0.92431E-17 -17.0342 0.83647E+00 -0.0776 58 FeO2- 0.40724E-09 -9.3902 0.33999E-09 -9.4685 0.83486E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 61 KCl,aq 0.57126E-09 -9.2432 0.57126E-09 -9.2432 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.30150E-14 -14.5207 0.25171E-14 -14.5991 0.83486E+00 -0.0784 65 MgCO3,aq 0.94165E-13 -13.0261 0.94165E-13 -13.0261 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.79774E-15 -15.0981 0.66729E-15 -15.1757 0.83647E+00 -0.0776 67 MgCl+ 0.45982E-14 -14.3374 0.38462E-14 -14.4150 0.83647E+00 -0.0776 68 MgF+ 0.53076E-15 -15.2751 0.44397E-15 -15.3526 0.83647E+00 -0.0776 69 MgOH+ 0.69230E-10 -10.1597 0.57909E-10 -10.2373 0.83647E+00 -0.0776 71 MnF+ 0.14645E-15 -15.8343 0.12250E-15 -15.9119 0.83647E+00 -0.0776 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47030E-09 -9.3276 0.39339E-09 -9.4052 0.83647E+00 -0.0776 74 MnO2-2 0.20828E-10 -10.6814 0.10776E-10 -10.9675 0.51739E+00 -0.2862 75 HMnO2- 0.21092E-09 -9.6759 0.17609E-09 -9.7543 0.83486E+00 -0.0784 78 MnCl+ 0.17103E-13 -13.7669 0.14306E-13 -13.8445 0.83647E+00 -0.0776 80 NaCl,aq 0.13230E-05 -5.8784 0.13230E-05 -5.8784 0.10000E+01 0.0000 81 NaF,aq 0.29258E-08 -8.5338 0.29258E-08 -8.5338 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92956E-02 -2.0317 0.77465E-02 -2.1109 0.83335E+00 -0.0792 89 HPO3-2 0.16247E-14 -14.7892 0.84063E-15 -15.0754 0.51739E+00 -0.2862 91 H2PO3- 0.15060E-18 -18.8222 0.12573E-18 -18.9006 0.83486E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38345E-10 -10.4163 0.32043E-10 -10.4943 0.83566E+00 -0.0780 94 PO4-3 0.10534E-08 -8.9774 0.25476E-09 -9.5939 0.24184E+00 -0.6165 98 HP2O7-3 0.93533E-18 -18.0290 0.21554E-18 -18.6665 0.23044E+00 -0.6374 99 P2O7-4 0.90091E-17 -17.0453 0.69037E-18 -18.1609 0.76631E-01 -1.1156 100 H2S,aq 0.18148E-07 -7.7412 0.18085E-07 -7.7427 0.99654E+00 -0.0015 101 S2-2 0.22758E-13 -13.6429 0.11775E-13 -13.9290 0.51739E+00 -0.2862 107 SO3-2 0.35332E-17 -17.4518 0.18546E-17 -17.7317 0.52491E+00 -0.2799 108 HSO3- 0.10374E-19 -19.9840 0.86610E-20 -20.0624 0.83486E+00 -0.0784 109 HSO4- 0.10578E-18 -18.9756 0.88569E-19 -19.0527 0.83729E+00 -0.0771 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8879826E-10 -.2220815E-01 -.2234542E+02 0.0000 2 H2O 0.1000000E+01 0.5550502E+02 0.9981945E+06 0.0000 3 Cl- 0.2867934E-03 0.2881171E-03 0.1019679E+02 6.5065 4 SO4-- 0.2376475E-11 -.1478807E-03 -.1418086E+02 8.3454 5 HCO3- 0.2793892E-05 0.1530590E-03 0.9322934E+01 4.4958 6 HS- 0.9395864E-04 0.2418575E-03 0.7984750E+01 6.0220 7 Al+++ 0.9881087E-29 0.5289982E-05 0.1424825E+00 0.7390 8 H4SiO4 0.6959776E-03 0.1348217E-01 0.1293582E+04 -3.1574 9 Ca++ 0.1366467E-06 0.2361212E-06 0.9446750E-02 13.1018 10 Mg++ 0.2137784E-10 0.9394166E-10 0.2279924E-05 9.2942 11 Fe++ 0.5892097E-13 0.3611341E-07 0.2013306E-02 6.7350 12 K+ 0.1574110E-03 0.1581653E-03 0.6173787E+01 6.2467 13 Na+ 0.1997484E-01 0.2242184E-01 0.5145739E+03 8.3494 14 Mn++ 0.1890334E-10 0.2527299E-08 0.1386024E-03 9.2416 15 F- 0.8996600E-06 0.9025871E-06 0.1711742E-01 4.0021 16 HPO4-- 0.4491022E-07 0.4600199E-07 0.4407520E-02 12.6219 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279245E+02 -.1102304E-01 -.8278143E+02 0.0000000E+00 2 H2O -.7168076E+01 0.2754997E+02 -.3471805E+02 0.0000000E+00 3 Cl- 0.1430072E-03 0.1430072E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385967E+00 -.7340072E-04 0.1386701E+00 0.0000000E+00 5 HCO3- 0.7597100E-04 0.7597100E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385500E+00 0.1200462E-03 -.1386701E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2625688E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6691887E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1171990E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4662803E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1792493E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7850552E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112910E-01 0.6265248E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254427E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4480000E-06 0.4480000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2283313E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.7105E-14 Mass of aqueous solution: 0.497219E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0008700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5547 -0.256 281.9 2.450 5.160 73.23 grossular 0.1343 -0.872 60.50 1.782 1.108 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2610 -0.583 56.53 1.752 1.035 17.28 hedenbergite 0.6769E-01 -1.169 16.80 1.225 0.3075 4.600 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.155 97.27 tr.625ac.25prg.125 0.4302E-01 -1.366 36.77 1.566 0.6732 11.84 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338150 g Volume = 2210.780268 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0008700 moles log = -3.0605 Original solution: 1000.0103000 g Original solution / Rock added: 1149437.13 (Water/Rock Ratio), log = 6.0605 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2488 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8193E+00 0.9833 0.1006E+01 0.1023E+01 CO2,gas 0.3175E-07 1.0046 0.3983E-07 0.3965E-07 CH4,gas 0.1686E+00 1.0103 0.2127E+00 0.2105E+00 H2,gas 0.1217E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4000E-06 0.9952 0.4971E-06 0.4996E-06 S2,gas 0.3213E-28 1.0000 0.4012E-28 0.4012E-28 CO,gas 0.1293E-12 1.0000 0.1614E-12 0.1614E-12 SO3,gas 0.2075E-47 1.0000 0.2592E-47 0.2592E-47 SO2,gas 0.1228E-26 1.0000 0.1533E-26 0.1533E-26 HF,gas 0.7525E-15 1.0000 0.9397E-15 0.9397E-15 HCl,gas 0.4624E-17 1.0000 0.5774E-17 0.5774E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.76 -9.10 -3.033 0.15536E+05 -7.400 3 CH4,gas 4.54 2.17 -2.37 -0.593 0.40489E+04 -0.672 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.23 -8.00 -4.001 0.13664E+05 -6.304 6 S2,gas -7.34 -37.43 -30.10 -4.630 0.51387E+05 -28.397 7 CO,gas 3.21 -11.28 -14.49 -4.459 0.24743E+05 -12.792 8 SO3,gas 17.12 -32.16 -49.29 -12.321 0.84153E+05 -47.586 9 SO2,gas 0.83 -27.68 -28.51 -7.604 0.48686E+05 -26.814 10 HF,gas 0.47 -16.25 -16.73 -8.363 0.28559E+05 -15.027 11 HCl,gas 5.19 -13.75 -18.94 -9.469 0.32335E+05 -17.239 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.41 -0.11 -0.009 0.17938E+03 38 aragonite 0.97 -2.66 -3.62 -1.208 0.61872E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.66 -3.47 -1.156 0.59229E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.79 -3.69 -1.055 0.63020E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.79 -3.25 -0.928 0.55443E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.21 -4.97 -1.169 0.84800E+04 146 pyrrhotite -4.26 -7.50 -3.24 -1.079 0.55278E+04 147 pyrrhotiteFe0.875 -6.02 -8.90 -2.88 -1.059 0.49150E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.50 -3.09 -1.029 0.52706E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.99 -4.01 -1.338 0.68525E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0008700 MOLES New total amount of reactant added: 0.0009100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0009100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135799E-01 Osmotic coef. = 1.1204 True ionic strength = .2013991E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1432E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88805E-10 -10.0516 0.74590E-10 -10.1273 0.83993E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28727E-03 -3.5417 0.23983E-03 -3.6201 0.83486E+00 -0.0784 4 SO4-- 0.24259E-11 -11.6151 0.12578E-11 -11.9004 0.51849E+00 -0.2853 5 HCO3- 0.29001E-05 -5.5376 0.24247E-05 -5.6153 0.83608E+00 -0.0778 6 HS- 0.95916E-04 -4.0181 0.80088E-04 -4.0964 0.83498E+00 -0.0783 7 Al+++ 0.98838E-29 -29.0051 0.22752E-29 -29.6430 0.23020E+00 -0.6379 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13667E-06 -6.8643 0.70339E-07 -7.1528 0.51466E+00 -0.2885 10 Mg++ 0.21382E-10 -10.6700 0.10954E-10 -10.9604 0.51230E+00 -0.2905 11 Fe++ 0.58931E-13 -13.2297 0.30223E-13 -13.5197 0.51286E+00 -0.2900 12 K+ 0.15742E-03 -3.8029 0.13165E-03 -3.8806 0.83628E+00 -0.0776 13 Na+ 0.19976E-01 -1.6995 0.16674E-01 -1.7779 0.83471E+00 -0.0785 14 Mn++ 0.18907E-10 -10.7234 0.97046E-11 -11.0130 0.51329E+00 -0.2896 15 F- 0.93179E-06 -6.0307 0.77630E-06 -6.1100 0.83313E+00 -0.0793 16 HPO4-- 0.44905E-07 -7.3477 0.23286E-07 -7.6329 0.51856E+00 -0.2852 18 HSiO3- 0.10436E-01 -1.9815 0.87124E-02 -2.0599 0.83486E+00 -0.0784 19 Ca(HSiO3)+ 0.16685E-07 -7.7777 0.13956E-07 -7.8552 0.83646E+00 -0.0776 20 Mg(HSiO3)+ 0.32336E-11 -11.4903 0.27048E-11 -11.5679 0.83646E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66510E-16 -16.1771 0.55633E-16 -16.2547 0.83646E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52895E-05 -5.2766 0.44079E-05 -5.3558 0.83334E+00 -0.0792 26 CH4,aq 0.15049E-03 -3.8225 0.14997E-03 -3.8240 0.99654E+00 -0.0015 27 C2H6,aq 0.33313E-12 -12.4774 0.33198E-12 -12.4789 0.99654E+00 -0.0015 28 C3H8,aq 0.17025E-19 -19.7689 0.16966E-19 -19.7704 0.99654E+00 -0.0015 30 ethanol,aq 0.12227E-19 -19.9127 0.12185E-19 -19.9142 0.99654E+00 -0.0015 31 CO,aq 0.11244E-15 -15.9491 0.11244E-15 -15.9491 0.10000E+01 0.0000 32 CO2,aq 0.38780E-09 -9.4114 0.38645E-09 -9.4129 0.99654E+00 -0.0015 33 CO3-2 0.54879E-05 -5.2606 0.28393E-05 -5.5468 0.51738E+00 -0.2862 34 CaCO3,aq 0.25042E-08 -8.6013 0.25042E-08 -8.6013 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.52046E-11 -11.2836 0.43535E-11 -11.3612 0.83646E+00 -0.0776 36 CaCl+ 0.32637E-10 -10.4863 0.27300E-10 -10.5638 0.83646E+00 -0.0776 37 CaCl2,aq 0.15555E-14 -14.8081 0.15555E-14 -14.8081 0.10000E+01 0.0000 38 CaF+ 0.95309E-12 -12.0209 0.79723E-12 -12.0984 0.83646E+00 -0.0776 39 CaOH+ 0.80347E-07 -7.0950 0.67207E-07 -7.1726 0.83646E+00 -0.0776 40 CaSO4,aq 0.28093E-16 -16.5514 0.28093E-16 -16.5514 0.10000E+01 0.0000 41 HCl,aq 0.32780E-14 -14.4844 0.32780E-14 -14.4844 0.10000E+01 0.0000 45 HF,aq 0.39640E-12 -12.4019 0.39640E-12 -12.4019 0.10000E+01 0.0000 46 HF2- 0.12445E-18 -18.9050 0.10390E-18 -18.9834 0.83486E+00 -0.0784 48 FeCl+ 0.13716E-16 -16.8628 0.11473E-16 -16.9403 0.83646E+00 -0.0776 51 FeF+ 0.14334E-17 -17.8436 0.11990E-17 -17.9212 0.83646E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15768E-10 -10.8022 0.13189E-10 -10.8798 0.83646E+00 -0.0776 55 HFeO2- 0.35474E-07 -7.4501 0.29615E-07 -7.5285 0.83486E+00 -0.0784 56 FeO+ 0.11051E-16 -16.9566 0.92437E-17 -17.0342 0.83646E+00 -0.0776 58 FeO2- 0.40721E-09 -9.3902 0.33996E-09 -9.4686 0.83486E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 61 KCl,aq 0.57224E-09 -9.2424 0.57224E-09 -9.2424 0.10000E+01 0.0000 63 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.30778E-14 -14.5118 0.25695E-14 -14.5902 0.83486E+00 -0.0784 65 MgCO3,aq 0.97750E-13 -13.0099 0.97750E-13 -13.0099 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.82818E-15 -15.0819 0.69274E-15 -15.1594 0.83646E+00 -0.0776 67 MgCl+ 0.46064E-14 -14.3366 0.38531E-14 -14.4142 0.83646E+00 -0.0776 68 MgF+ 0.54980E-15 -15.2598 0.45989E-15 -15.3373 0.83646E+00 -0.0776 69 MgOH+ 0.69236E-10 -10.1597 0.57913E-10 -10.2372 0.83646E+00 -0.0776 71 MnF+ 0.15170E-15 -15.8190 0.12689E-15 -15.8966 0.83646E+00 -0.0776 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47034E-09 -9.3276 0.39342E-09 -9.4051 0.83646E+00 -0.0776 74 MnO2-2 0.20825E-10 -10.6814 0.10775E-10 -10.9676 0.51738E+00 -0.2862 75 HMnO2- 0.21090E-09 -9.6759 0.17607E-09 -9.7543 0.83486E+00 -0.0784 78 MnCl+ 0.17134E-13 -13.7661 0.14332E-13 -13.8437 0.83646E+00 -0.0776 80 NaCl,aq 0.13253E-05 -5.8777 0.13253E-05 -5.8777 0.10000E+01 0.0000 81 NaF,aq 0.30305E-08 -8.5185 0.30305E-08 -8.5185 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92950E-02 -2.0318 0.77459E-02 -2.1109 0.83334E+00 -0.0792 89 HPO3-2 0.16245E-14 -14.7893 0.84050E-15 -15.0755 0.51738E+00 -0.2862 91 H2PO3- 0.15059E-18 -18.8222 0.12572E-18 -18.9006 0.83486E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38342E-10 -10.4163 0.32041E-10 -10.4943 0.83565E+00 -0.0780 94 PO4-3 0.10532E-08 -8.9775 0.25471E-09 -9.5940 0.24183E+00 -0.6165 98 HP2O7-3 0.93517E-18 -18.0291 0.21549E-18 -18.6666 0.23043E+00 -0.6375 99 P2O7-4 0.90072E-17 -17.0454 0.69017E-18 -18.1610 0.76623E-01 -1.1156 100 H2S,aq 0.18527E-07 -7.7322 0.18463E-07 -7.7337 0.99654E+00 -0.0015 101 S2-2 0.23717E-13 -13.6249 0.12271E-13 -13.9111 0.51738E+00 -0.2862 107 SO3-2 0.36067E-17 -17.4429 0.18931E-17 -17.7228 0.52490E+00 -0.2799 108 HSO3- 0.10590E-19 -19.9751 0.88415E-20 -20.0535 0.83486E+00 -0.0784 109 HSO4- 0.10798E-18 -18.9666 0.90414E-19 -19.0438 0.83728E+00 -0.0771 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8880539E-10 -.2220700E-01 -.2234426E+02 0.0000 2 H2O 0.1000000E+01 0.5550503E+02 0.9981945E+06 0.0000 3 Cl- 0.2872662E-03 0.2885921E-03 0.1021360E+02 6.5072 4 SO4-- 0.2425854E-11 -.1534001E-03 -.1471014E+02 8.3542 5 HCO3- 0.2900063E-05 0.1588853E-03 0.9677816E+01 4.5120 6 HS- 0.9591641E-04 0.2493350E-03 0.8231615E+01 6.0309 7 Al+++ 0.9883837E-29 0.5289621E-05 0.1424728E+00 0.7390 8 H4SiO4 0.6959775E-03 0.1348145E-01 0.1293513E+04 -3.1574 9 Ca++ 0.1366704E-06 0.2362449E-06 0.9451695E-02 13.1018 10 Mg++ 0.2138156E-10 0.9395494E-10 0.2280246E-05 9.2942 11 Fe++ 0.5893121E-13 0.3611096E-07 0.2013169E-02 6.7350 12 K+ 0.1574237E-03 0.1581780E-03 0.6174280E+01 6.2467 13 Na+ 0.1997645E-01 0.2242344E-01 0.5146107E+03 8.3494 14 Mn++ 0.1890669E-10 0.2527333E-08 0.1386043E-03 9.2416 15 F- 0.9317891E-06 0.9348210E-06 0.1772873E-01 4.0173 16 HPO4-- 0.4490459E-07 0.4599618E-07 0.4406962E-02 12.6217 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279245E+02 -.1102248E-01 -.8278143E+02 0.0000000E+00 2 H2O -.7168044E+01 0.2755002E+02 -.3471806E+02 0.0000000E+00 3 Cl- 0.1432432E-03 0.1432432E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385969E+00 -.7614039E-04 0.1386730E+00 0.0000000E+00 5 HCO3- 0.7886300E-04 0.7886300E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385492E+00 0.1237579E-03 -.1386730E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2625512E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6691542E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1172605E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4663470E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1792374E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7851191E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1112991E-01 0.6265247E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254446E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4640000E-06 0.4640000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2283028E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1573E-13 Mass of aqueous solution: 0.497220E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0009100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5547 -0.256 281.9 2.450 5.160 73.24 grossular 0.1343 -0.872 60.50 1.782 1.108 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2610 -0.583 56.51 1.752 1.035 17.27 hedenbergite 0.6768E-01 -1.170 16.79 1.225 0.3074 4.599 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.155 97.27 tr.625ac.25prg.125 0.4305E-01 -1.366 36.80 1.566 0.6736 11.84 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338164 g Volume = 2210.780379 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0009100 moles log = -3.0410 Original solution: 1000.0103000 g Original solution / Rock added: 1098912.42 (Water/Rock Ratio), log = 6.0410 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2569 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8140E+00 0.9832 0.1006E+01 0.1023E+01 CO2,gas 0.3275E-07 1.0045 0.4135E-07 0.4116E-07 CH4,gas 0.1739E+00 1.0102 0.2208E+00 0.2185E+00 H2,gas 0.1209E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4058E-06 0.9951 0.5075E-06 0.5100E-06 S2,gas 0.3327E-28 1.0000 0.4181E-28 0.4181E-28 CO,gas 0.1333E-12 1.0000 0.1676E-12 0.1676E-12 SO3,gas 0.2105E-47 1.0000 0.2646E-47 0.2646E-47 SO2,gas 0.1245E-26 1.0000 0.1565E-26 0.1565E-26 HF,gas 0.7744E-15 1.0000 0.9733E-15 0.9733E-15 HCl,gas 0.4602E-17 1.0000 0.5784E-17 0.5784E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.74 -9.08 -3.028 0.15508E+05 -7.384 3 CH4,gas 4.54 2.19 -2.36 -0.589 0.40212E+04 -0.656 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.22 -7.99 -3.997 0.13649E+05 -6.295 6 S2,gas -7.34 -37.41 -30.08 -4.627 0.51357E+05 -28.379 7 CO,gas 3.21 -11.26 -14.47 -4.454 0.24715E+05 -12.776 8 SO3,gas 17.12 -32.16 -49.28 -12.319 0.84138E+05 -47.577 9 SO2,gas 0.83 -27.67 -28.50 -7.601 0.48670E+05 -26.805 10 HF,gas 0.47 -16.24 -16.71 -8.355 0.28533E+05 -15.012 11 HCl,gas 5.19 -13.75 -18.94 -9.468 0.32334E+05 -17.238 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.39 -0.09 -0.007 0.15331E+03 38 aragonite 0.97 -2.64 -3.61 -1.202 0.61595E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.64 -3.45 -1.151 0.58952E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.78 -3.67 -1.050 0.62743E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.78 -3.23 -0.923 0.55166E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.20 -4.95 -1.164 0.84493E+04 146 pyrrhotite -4.26 -7.49 -3.23 -1.076 0.55125E+04 147 pyrrhotiteFe0.875 -6.02 -8.89 -2.87 -1.055 0.48997E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.49 -3.08 -1.026 0.52553E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.98 -4.00 -1.335 0.68372E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0009100 MOLES New total amount of reactant added: 0.0009500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0009500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135466E-01 Osmotic coef. = 1.1515 True ionic strength = .2014174E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1435E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88813E-10 -10.0515 0.74596E-10 -10.1273 0.83993E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28774E-03 -3.5410 0.24022E-03 -3.6194 0.83485E+00 -0.0784 4 SO4-- 0.24752E-11 -11.6064 0.12833E-11 -11.8917 0.51847E+00 -0.2853 5 HCO3- 0.30062E-05 -5.5220 0.25134E-05 -5.5997 0.83608E+00 -0.0778 6 HS- 0.97874E-04 -4.0093 0.81723E-04 -4.0877 0.83498E+00 -0.0783 7 Al+++ 0.98866E-29 -29.0050 0.22757E-29 -29.6429 0.23018E+00 -0.6379 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13669E-06 -6.8643 0.70349E-07 -7.1527 0.51465E+00 -0.2885 10 Mg++ 0.21385E-10 -10.6699 0.10955E-10 -10.9604 0.51228E+00 -0.2905 11 Fe++ 0.58941E-13 -13.2296 0.30228E-13 -13.5196 0.51285E+00 -0.2900 12 K+ 0.15744E-03 -3.8029 0.13166E-03 -3.8805 0.83628E+00 -0.0776 13 Na+ 0.19978E-01 -1.6994 0.16676E-01 -1.7779 0.83470E+00 -0.0785 14 Mn++ 0.18910E-10 -10.7233 0.97060E-11 -11.0130 0.51327E+00 -0.2897 15 F- 0.96392E-06 -6.0160 0.80306E-06 -6.0953 0.83312E+00 -0.0793 16 HPO4-- 0.44899E-07 -7.3478 0.23282E-07 -7.6330 0.51855E+00 -0.2852 18 HSiO3- 0.10435E-01 -1.9815 0.87118E-02 -2.0599 0.83485E+00 -0.0784 19 Ca(HSiO3)+ 0.16686E-07 -7.7776 0.13957E-07 -7.8552 0.83646E+00 -0.0776 20 Mg(HSiO3)+ 0.32339E-11 -11.4903 0.27050E-11 -11.5678 0.83646E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66515E-16 -16.1771 0.55637E-16 -16.2546 0.83646E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52891E-05 -5.2766 0.44076E-05 -5.3558 0.83334E+00 -0.0792 26 CH4,aq 0.15601E-03 -3.8068 0.15547E-03 -3.8083 0.99654E+00 -0.0015 27 C2H6,aq 0.35801E-12 -12.4461 0.35677E-12 -12.4476 0.99654E+00 -0.0015 28 C3H8,aq 0.18967E-19 -19.7220 0.18902E-19 -19.7235 0.99654E+00 -0.0015 30 ethanol,aq 0.13140E-19 -19.8814 0.13095E-19 -19.8829 0.99654E+00 -0.0015 31 CO,aq 0.11657E-15 -15.9334 0.11657E-15 -15.9334 0.10000E+01 0.0000 32 CO2,aq 0.40202E-09 -9.3958 0.40063E-09 -9.3973 0.99654E+00 -0.0015 33 CO3-2 0.56885E-05 -5.2450 0.29430E-05 -5.5312 0.51737E+00 -0.2862 34 CaCO3,aq 0.25961E-08 -8.5857 0.25961E-08 -8.5857 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.53959E-11 -11.2679 0.45135E-11 -11.3455 0.83646E+00 -0.0776 36 CaCl+ 0.32695E-10 -10.4855 0.27348E-10 -10.5631 0.83646E+00 -0.0776 37 CaCl2,aq 0.15608E-14 -14.8067 0.15608E-14 -14.8067 0.10000E+01 0.0000 38 CaF+ 0.98610E-12 -12.0061 0.82483E-12 -12.0836 0.83646E+00 -0.0776 39 CaOH+ 0.80353E-07 -7.0950 0.67212E-07 -7.1726 0.83646E+00 -0.0776 40 CaSO4,aq 0.28669E-16 -16.5426 0.28669E-16 -16.5426 0.10000E+01 0.0000 41 HCl,aq 0.32837E-14 -14.4836 0.32837E-14 -14.4836 0.10000E+01 0.0000 45 HF,aq 0.41009E-12 -12.3871 0.41009E-12 -12.3871 0.10000E+01 0.0000 46 HF2- 0.13319E-18 -18.8755 0.11119E-18 -18.9539 0.83485E+00 -0.0784 48 FeCl+ 0.13741E-16 -16.8620 0.11493E-16 -16.9395 0.83646E+00 -0.0776 51 FeF+ 0.14830E-17 -17.8289 0.12405E-17 -17.9064 0.83646E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15769E-10 -10.8022 0.13190E-10 -10.8797 0.83646E+00 -0.0776 55 HFeO2- 0.35471E-07 -7.4501 0.29613E-07 -7.5285 0.83485E+00 -0.0784 56 FeO+ 0.11052E-16 -16.9566 0.92444E-17 -17.0341 0.83646E+00 -0.0776 58 FeO2- 0.40718E-09 -9.3902 0.33994E-09 -9.4686 0.83485E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 61 KCl,aq 0.57322E-09 -9.2417 0.57322E-09 -9.2417 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.31406E-14 -14.5030 0.26219E-14 -14.5814 0.83485E+00 -0.0784 65 MgCO3,aq 0.10133E-12 -12.9942 0.10133E-12 -12.9942 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.85863E-15 -15.0662 0.71821E-15 -15.1438 0.83646E+00 -0.0776 67 MgCl+ 0.46147E-14 -14.3359 0.38600E-14 -14.4134 0.83646E+00 -0.0776 68 MgF+ 0.56884E-15 -15.2450 0.47581E-15 -15.3226 0.83646E+00 -0.0776 69 MgOH+ 0.69242E-10 -10.1596 0.57918E-10 -10.2372 0.83646E+00 -0.0776 71 MnF+ 0.15696E-15 -15.8042 0.13129E-15 -15.8818 0.83646E+00 -0.0776 72 MnO,aq 0.18063E-08 -8.7432 0.18063E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47038E-09 -9.3276 0.39345E-09 -9.4051 0.83646E+00 -0.0776 74 MnO2-2 0.20823E-10 -10.6815 0.10773E-10 -10.9677 0.51737E+00 -0.2862 75 HMnO2- 0.21089E-09 -9.6759 0.17606E-09 -9.7543 0.83485E+00 -0.0784 78 MnCl+ 0.17165E-13 -13.7654 0.14358E-13 -13.8429 0.83646E+00 -0.0776 80 NaCl,aq 0.13275E-05 -5.8770 0.13275E-05 -5.8770 0.10000E+01 0.0000 81 NaF,aq 0.31352E-08 -8.5037 0.31352E-08 -8.5037 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92944E-02 -2.0318 0.77453E-02 -2.1110 0.83334E+00 -0.0792 89 HPO3-2 0.16243E-14 -14.7893 0.84038E-15 -15.0755 0.51737E+00 -0.2862 91 H2PO3- 0.15058E-18 -18.8222 0.12571E-18 -18.9006 0.83485E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38340E-10 -10.4164 0.32039E-10 -10.4943 0.83565E+00 -0.0780 94 PO4-3 0.10531E-08 -8.9775 0.25465E-09 -9.5941 0.24182E+00 -0.6165 98 HP2O7-3 0.93502E-18 -18.0292 0.21544E-18 -18.6667 0.23042E+00 -0.6375 99 P2O7-4 0.90054E-17 -17.0455 0.68996E-18 -18.1612 0.76616E-01 -1.1157 100 H2S,aq 0.18906E-07 -7.7234 0.18841E-07 -7.7249 0.99654E+00 -0.0015 101 S2-2 0.24695E-13 -13.6074 0.12776E-13 -13.8936 0.51737E+00 -0.2862 107 SO3-2 0.36801E-17 -17.4341 0.19316E-17 -17.7141 0.52489E+00 -0.2799 108 HSO3- 0.10807E-19 -19.9663 0.90219E-20 -20.0447 0.83485E+00 -0.0784 109 HSO4- 0.11019E-18 -18.9579 0.92258E-19 -19.0350 0.83728E+00 -0.0771 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8881252E-10 -.2220585E-01 -.2234310E+02 0.0000 2 H2O 0.1000000E+01 0.5550503E+02 0.9981944E+06 0.0000 3 Cl- 0.2877390E-03 0.2890671E-03 0.1023041E+02 6.5079 4 SO4-- 0.2475227E-11 -.1589195E-03 -.1523941E+02 8.3629 5 HCO3- 0.3006222E-05 0.1647116E-03 0.1003270E+02 4.5276 6 HS- 0.9787417E-04 0.2568126E-03 0.8478481E+01 6.0396 7 Al+++ 0.9886587E-29 0.5289260E-05 0.1424631E+00 0.7390 8 H4SiO4 0.6959774E-03 0.1348074E-01 0.1293445E+04 -3.1574 9 Ca++ 0.1366941E-06 0.2363685E-06 0.9456641E-02 13.1018 10 Mg++ 0.2138527E-10 0.9396822E-10 0.2280568E-05 9.2942 11 Fe++ 0.5894145E-13 0.3610850E-07 0.2013031E-02 6.7350 12 K+ 0.1574363E-03 0.1581906E-03 0.6174772E+01 6.2467 13 Na+ 0.1997805E-01 0.2242505E-01 0.5146476E+03 8.3494 14 Mn++ 0.1891005E-10 0.2527366E-08 0.1386061E-03 9.2416 15 F- 0.9639182E-06 0.9670548E-06 0.1834004E-01 4.0320 16 HPO4-- 0.4489896E-07 0.4599036E-07 0.4406404E-02 12.6216 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279245E+02 -.1102193E-01 -.8278142E+02 0.0000000E+00 2 H2O -.7168011E+01 0.2755006E+02 -.3471807E+02 0.0000000E+00 3 Cl- 0.1434792E-03 0.1434792E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385971E+00 -.7888009E-04 0.1386759E+00 0.0000000E+00 5 HCO3- 0.8175500E-04 0.8175500E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385485E+00 0.1274696E-03 -.1386759E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2625337E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6691197E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1173221E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4664136E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1792254E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7851830E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113073E-01 0.6265246E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254464E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4800000E-06 0.4800000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2282743E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1561E-13 Mass of aqueous solution: 0.497220E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0009500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5547 -0.256 281.9 2.450 5.161 73.24 grossular 0.1343 -0.872 60.50 1.782 1.108 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2609 -0.584 56.50 1.752 1.034 17.27 hedenbergite 0.6766E-01 -1.170 16.79 1.225 0.3073 4.597 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.155 97.27 tr.625ac.25prg.125 0.4307E-01 -1.366 36.82 1.566 0.6740 11.85 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338177 g Volume = 2210.780490 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0009500 moles log = -3.0223 Original solution: 1000.0103000 g Original solution / Rock added: 1052642.42 (Water/Rock Ratio), log = 6.0223 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2650 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8089E+00 0.9831 0.1006E+01 0.1023E+01 CO2,gas 0.3374E-07 1.0044 0.4286E-07 0.4268E-07 CH4,gas 0.1791E+00 1.0101 0.2288E+00 0.2266E+00 H2,gas 0.1201E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4115E-06 0.9951 0.5179E-06 0.5205E-06 S2,gas 0.3442E-28 1.0000 0.4354E-28 0.4354E-28 CO,gas 0.1373E-12 1.0000 0.1737E-12 0.1737E-12 SO3,gas 0.2135E-47 1.0000 0.2700E-47 0.2700E-47 SO2,gas 0.1263E-26 1.0000 0.1597E-26 0.1597E-26 HF,gas 0.7960E-15 1.0000 0.1007E-14 0.1007E-14 HCl,gas 0.4580E-17 1.0000 0.5794E-17 0.5794E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.97059E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.73 -9.07 -3.022 0.15481E+05 -7.368 3 CH4,gas 4.54 2.20 -2.34 -0.585 0.39945E+04 -0.640 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.21 -7.98 -3.992 0.13634E+05 -6.286 6 S2,gas -7.34 -37.40 -30.06 -4.625 0.51327E+05 -28.361 7 CO,gas 3.21 -11.24 -14.46 -4.449 0.24689E+05 -12.760 8 SO3,gas 17.12 -32.15 -49.27 -12.317 0.84123E+05 -47.569 9 SO2,gas 0.83 -27.66 -28.50 -7.599 0.48655E+05 -26.797 10 HF,gas 0.47 -16.22 -16.70 -8.348 0.28508E+05 -14.997 11 HCl,gas 5.19 -13.75 -18.94 -9.468 0.32333E+05 -17.237 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.38 -0.08 -0.006 0.12812E+03 38 aragonite 0.97 -2.63 -3.59 -1.197 0.61327E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.63 -3.44 -1.146 0.58685E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.76 -3.66 -1.045 0.62476E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.76 -3.22 -0.919 0.54899E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.18 -4.93 -1.160 0.84192E+04 146 pyrrhotite -4.26 -7.48 -3.22 -1.073 0.54975E+04 147 pyrrhotiteFe0.875 -6.02 -8.88 -2.86 -1.052 0.48847E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.48 -3.07 -1.023 0.52403E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.97 -4.00 -1.332 0.68221E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0009500 MOLES New total amount of reactant added: 0.0009900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0009900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135134E-01 Osmotic coef. = 1.1939 True ionic strength = .2014356E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.1437E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88820E-10 -10.0515 0.74602E-10 -10.1273 0.83992E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28821E-03 -3.5403 0.24061E-03 -3.6187 0.83485E+00 -0.0784 4 SO4-- 0.25246E-11 -11.5978 0.13089E-11 -11.8831 0.51846E+00 -0.2853 5 HCO3- 0.31124E-05 -5.5069 0.26022E-05 -5.5847 0.83607E+00 -0.0778 6 HS- 0.99832E-04 -4.0007 0.83357E-04 -4.0791 0.83497E+00 -0.0783 7 Al+++ 0.98893E-29 -29.0048 0.22762E-29 -29.6428 0.23017E+00 -0.6379 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13672E-06 -6.8642 0.70360E-07 -7.1527 0.51464E+00 -0.2885 10 Mg++ 0.21389E-10 -10.6698 0.10957E-10 -10.9603 0.51227E+00 -0.2905 11 Fe++ 0.58952E-13 -13.2295 0.30232E-13 -13.5195 0.51283E+00 -0.2900 12 K+ 0.15745E-03 -3.8029 0.13167E-03 -3.8805 0.83627E+00 -0.0777 13 Na+ 0.19980E-01 -1.6994 0.16677E-01 -1.7779 0.83469E+00 -0.0785 14 Mn++ 0.18913E-10 -10.7232 0.97075E-11 -11.0129 0.51326E+00 -0.2897 15 F- 0.99605E-06 -6.0017 0.82983E-06 -6.0810 0.83312E+00 -0.0793 16 HPO4-- 0.44893E-07 -7.3478 0.23279E-07 -7.6330 0.51853E+00 -0.2852 18 HSiO3- 0.10434E-01 -1.9815 0.87111E-02 -2.0599 0.83485E+00 -0.0784 19 Ca(HSiO3)+ 0.16688E-07 -7.7776 0.13958E-07 -7.8552 0.83645E+00 -0.0776 20 Mg(HSiO3)+ 0.32341E-11 -11.4902 0.27052E-11 -11.5678 0.83645E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66520E-16 -16.1770 0.55641E-16 -16.2546 0.83645E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52888E-05 -5.2766 0.44073E-05 -5.3558 0.83333E+00 -0.0792 26 CH4,aq 0.16153E-03 -3.7917 0.16097E-03 -3.7932 0.99654E+00 -0.0015 27 C2H6,aq 0.38379E-12 -12.4159 0.38247E-12 -12.4174 0.99654E+00 -0.0015 28 C3H8,aq 0.21053E-19 -19.6767 0.20980E-19 -19.6782 0.99654E+00 -0.0015 30 ethanol,aq 0.14087E-19 -19.8512 0.14038E-19 -19.8527 0.99654E+00 -0.0015 31 CO,aq 0.12069E-15 -15.9183 0.12069E-15 -15.9183 0.10000E+01 0.0000 32 CO2,aq 0.41624E-09 -9.3807 0.41480E-09 -9.3822 0.99654E+00 -0.0015 33 CO3-2 0.58890E-05 -5.2300 0.30467E-05 -5.5162 0.51735E+00 -0.2862 34 CaCO3,aq 0.26879E-08 -8.5706 0.26879E-08 -8.5706 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.55873E-11 -11.2528 0.46735E-11 -11.3304 0.83645E+00 -0.0776 36 CaCl+ 0.32754E-10 -10.4847 0.27397E-10 -10.5623 0.83645E+00 -0.0776 37 CaCl2,aq 0.15661E-14 -14.8052 0.15661E-14 -14.8052 0.10000E+01 0.0000 38 CaF+ 0.10191E-11 -11.9918 0.85245E-12 -12.0693 0.83645E+00 -0.0776 39 CaOH+ 0.80360E-07 -7.0950 0.67217E-07 -7.1725 0.83645E+00 -0.0776 40 CaSO4,aq 0.29244E-16 -16.5340 0.29244E-16 -16.5340 0.10000E+01 0.0000 41 HCl,aq 0.32893E-14 -14.4829 0.32893E-14 -14.4829 0.10000E+01 0.0000 45 HF,aq 0.42379E-12 -12.3728 0.42379E-12 -12.3728 0.10000E+01 0.0000 46 HF2- 0.14222E-18 -18.8470 0.11873E-18 -18.9254 0.83485E+00 -0.0784 48 FeCl+ 0.13765E-16 -16.8612 0.11514E-16 -16.9388 0.83645E+00 -0.0776 51 FeF+ 0.15327E-17 -17.8145 0.12820E-17 -17.8921 0.83645E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15771E-10 -10.8022 0.13191E-10 -10.8797 0.83645E+00 -0.0776 55 HFeO2- 0.35469E-07 -7.4502 0.29611E-07 -7.5285 0.83485E+00 -0.0784 56 FeO+ 0.11053E-16 -16.9565 0.92451E-17 -17.0341 0.83645E+00 -0.0776 58 FeO2- 0.40715E-09 -9.3902 0.33991E-09 -9.4686 0.83485E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 61 KCl,aq 0.57420E-09 -9.2409 0.57420E-09 -9.2409 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.32034E-14 -14.4944 0.26744E-14 -14.5728 0.83485E+00 -0.0784 65 MgCO3,aq 0.10492E-12 -12.9791 0.10492E-12 -12.9791 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.88907E-15 -15.0511 0.74367E-15 -15.1286 0.83645E+00 -0.0776 67 MgCl+ 0.46230E-14 -14.3351 0.38669E-14 -14.4126 0.83645E+00 -0.0776 68 MgF+ 0.58789E-15 -15.2307 0.49174E-15 -15.3083 0.83645E+00 -0.0776 69 MgOH+ 0.69247E-10 -10.1596 0.57922E-10 -10.2372 0.83645E+00 -0.0776 71 MnF+ 0.16221E-15 -15.7899 0.13568E-15 -15.8675 0.83645E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47042E-09 -9.3275 0.39348E-09 -9.4051 0.83645E+00 -0.0776 74 MnO2-2 0.20820E-10 -10.6815 0.10772E-10 -10.9677 0.51735E+00 -0.2862 75 HMnO2- 0.21088E-09 -9.6760 0.17605E-09 -9.7544 0.83485E+00 -0.0784 78 MnCl+ 0.17196E-13 -13.7646 0.14383E-13 -13.8421 0.83645E+00 -0.0776 80 NaCl,aq 0.13298E-05 -5.8762 0.13298E-05 -5.8762 0.10000E+01 0.0000 81 NaF,aq 0.32399E-08 -8.4895 0.32399E-08 -8.4895 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92937E-02 -2.0318 0.77448E-02 -2.1110 0.83333E+00 -0.0792 89 HPO3-2 0.16241E-14 -14.7894 0.84025E-15 -15.0756 0.51735E+00 -0.2862 91 H2PO3- 0.15057E-18 -18.8223 0.12570E-18 -18.9007 0.83485E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38337E-10 -10.4164 0.32036E-10 -10.4944 0.83564E+00 -0.0780 94 PO4-3 0.10529E-08 -8.9776 0.25459E-09 -9.5942 0.24180E+00 -0.6165 98 HP2O7-3 0.93486E-18 -18.0293 0.21539E-18 -18.6668 0.23040E+00 -0.6375 99 P2O7-4 0.90036E-17 -17.0456 0.68975E-18 -18.1613 0.76609E-01 -1.1157 100 H2S,aq 0.19286E-07 -7.7148 0.19219E-07 -7.7163 0.99654E+00 -0.0015 101 S2-2 0.25693E-13 -13.5902 0.13293E-13 -13.8764 0.51735E+00 -0.2862 107 SO3-2 0.37535E-17 -17.4256 0.19701E-17 -17.7055 0.52487E+00 -0.2799 108 HSO3- 0.11023E-19 -19.9577 0.92023E-20 -20.0361 0.83485E+00 -0.0784 109 HSO4- 0.11239E-18 -18.9493 0.94103E-19 -19.0264 0.83727E+00 -0.0771 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8881965E-10 -.2220470E-01 -.2234193E+02 0.0000 2 H2O 0.1000000E+01 0.5550504E+02 0.9981943E+06 0.0000 3 Cl- 0.2882118E-03 0.2895422E-03 0.1024722E+02 6.5086 4 SO4-- 0.2524595E-11 -.1644390E-03 -.1576870E+02 8.3714 5 HCO3- 0.3112367E-05 0.1705378E-03 0.1038758E+02 4.5426 6 HS- 0.9983193E-04 0.2642902E-03 0.8725347E+01 6.0482 7 Al+++ 0.9889337E-29 0.5288899E-05 0.1424533E+00 0.7390 8 H4SiO4 0.6959774E-03 0.1348002E-01 0.1293376E+04 -3.1574 9 Ca++ 0.1367178E-06 0.2364921E-06 0.9461586E-02 13.1018 10 Mg++ 0.2138899E-10 0.9398151E-10 0.2280890E-05 9.2942 11 Fe++ 0.5895169E-13 0.3610604E-07 0.2012894E-02 6.7350 12 K+ 0.1574489E-03 0.1582033E-03 0.6175265E+01 6.2467 13 Na+ 0.1997966E-01 0.2242666E-01 0.5146844E+03 8.3494 14 Mn++ 0.1891341E-10 0.2527400E-08 0.1386079E-03 9.2416 15 F- 0.9960471E-06 0.9992885E-06 0.1895134E-01 4.0462 16 HPO4-- 0.4489333E-07 0.4598455E-07 0.4405846E-02 12.6215 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279244E+02 -.1102137E-01 -.8278142E+02 0.0000000E+00 2 H2O -.7167978E+01 0.2755010E+02 -.3471808E+02 0.0000000E+00 3 Cl- 0.1437152E-03 0.1437152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385972E+00 -.8161982E-04 0.1386789E+00 0.0000000E+00 5 HCO3- 0.8464700E-04 0.8464700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385477E+00 0.1311813E-03 -.1386789E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2625162E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6690852E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1173836E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4664802E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1792135E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7852469E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113154E-01 0.6265245E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254483E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4960000E-06 0.4960000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2282457E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1389E-13 Mass of aqueous solution: 0.497221E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0009900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5547 -0.256 281.9 2.450 5.161 73.24 grossular 0.1343 -0.872 60.50 1.782 1.108 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2608 -0.584 56.48 1.752 1.034 17.26 hedenbergite 0.6764E-01 -1.170 16.78 1.225 0.3072 4.596 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.155 97.26 tr.625ac.25prg.125 0.4310E-01 -1.366 36.84 1.566 0.6744 11.86 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338190 g Volume = 2210.780600 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0009900 moles log = -3.0044 Original solution: 1000.0103000 g Original solution / Rock added: 1010111.41 (Water/Rock Ratio), log = 6.0044 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2731 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8038E+00 0.9830 0.1006E+01 0.1023E+01 CO2,gas 0.3471E-07 1.0043 0.4438E-07 0.4419E-07 CH4,gas 0.1843E+00 1.0101 0.2369E+00 0.2346E+00 H2,gas 0.1194E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4171E-06 0.9951 0.5283E-06 0.5309E-06 S2,gas 0.3559E-28 1.0000 0.4531E-28 0.4531E-28 CO,gas 0.1413E-12 1.0000 0.1799E-12 0.1799E-12 SO3,gas 0.2164E-47 1.0000 0.2754E-47 0.2754E-47 SO2,gas 0.1280E-26 1.0000 0.1629E-26 0.1629E-26 HF,gas 0.8173E-15 1.0000 0.1041E-14 0.1041E-14 HCl,gas 0.4559E-17 1.0000 0.5804E-17 0.5804E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.71 -9.05 -3.017 0.15456E+05 -7.353 3 CH4,gas 4.54 2.22 -2.32 -0.581 0.39687E+04 -0.625 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.21 -7.98 -3.988 0.13619E+05 -6.277 6 S2,gas -7.34 -37.38 -30.04 -4.622 0.51297E+05 -28.344 7 CO,gas 3.21 -11.23 -14.44 -4.444 0.24663E+05 -12.745 8 SO3,gas 17.12 -32.14 -49.26 -12.315 0.84108E+05 -47.560 9 SO2,gas 0.83 -27.65 -28.49 -7.597 0.48641E+05 -26.788 10 HF,gas 0.47 -16.21 -16.68 -8.341 0.28484E+05 -14.983 11 HCl,gas 5.19 -13.75 -18.94 -9.468 0.32331E+05 -17.236 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.36 -0.06 -0.005 0.10376E+03 38 aragonite 0.97 -2.61 -3.58 -1.192 0.61070E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.61 -3.42 -1.141 0.58427E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.75 -3.64 -1.041 0.62218E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.75 -3.20 -0.914 0.54641E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.16 -4.91 -1.156 0.83897E+04 146 pyrrhotite -4.26 -7.47 -3.21 -1.070 0.54827E+04 147 pyrrhotiteFe0.875 -6.02 -8.87 -2.85 -1.049 0.48699E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.47 -3.06 -1.020 0.52255E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.96 -3.99 -1.329 0.68074E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0009900 MOLES New total amount of reactant added: 0.0010300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0010300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134801E-01 Osmotic coef. = 1.2551 True ionic strength = .2014538E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.1440E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88827E-10 -10.0515 0.74607E-10 -10.1272 0.83992E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28868E-03 -3.5396 0.24101E-03 -3.6180 0.83484E+00 -0.0784 4 SO4-- 0.25740E-11 -11.5894 0.13345E-11 -11.8747 0.51845E+00 -0.2853 5 HCO3- 0.32185E-05 -5.4923 0.26909E-05 -5.5701 0.83607E+00 -0.0778 6 HS- 0.10179E-03 -3.9923 0.84991E-04 -4.0706 0.83496E+00 -0.0783 7 Al+++ 0.98921E-29 -29.0047 0.22767E-29 -29.6427 0.23016E+00 -0.6380 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13674E-06 -6.8641 0.70370E-07 -7.1526 0.51462E+00 -0.2885 10 Mg++ 0.21393E-10 -10.6697 0.10959E-10 -10.9602 0.51226E+00 -0.2905 11 Fe++ 0.58962E-13 -13.2294 0.30237E-13 -13.5195 0.51282E+00 -0.2900 12 K+ 0.15746E-03 -3.8028 0.13168E-03 -3.8805 0.83627E+00 -0.0777 13 Na+ 0.19981E-01 -1.6994 0.16678E-01 -1.7779 0.83469E+00 -0.0785 14 Mn++ 0.18917E-10 -10.7232 0.97090E-11 -11.0128 0.51325E+00 -0.2897 15 F- 0.10282E-05 -5.9879 0.85659E-06 -6.0672 0.83311E+00 -0.0793 16 HPO4-- 0.44888E-07 -7.3479 0.23275E-07 -7.6331 0.51852E+00 -0.2852 18 HSiO3- 0.10434E-01 -1.9816 0.87105E-02 -2.0600 0.83484E+00 -0.0784 19 Ca(HSiO3)+ 0.16689E-07 -7.7776 0.13959E-07 -7.8551 0.83645E+00 -0.0776 20 Mg(HSiO3)+ 0.32344E-11 -11.4902 0.27054E-11 -11.5678 0.83645E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66526E-16 -16.1770 0.55645E-16 -16.2546 0.83645E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52884E-05 -5.2767 0.44070E-05 -5.3559 0.83333E+00 -0.0792 26 CH4,aq 0.16705E-03 -3.7771 0.16647E-03 -3.7787 0.99654E+00 -0.0015 27 C2H6,aq 0.41047E-12 -12.3867 0.40905E-12 -12.3882 0.99654E+00 -0.0015 28 C3H8,aq 0.23285E-19 -19.6329 0.23205E-19 -19.6344 0.99654E+00 -0.0015 30 ethanol,aq 0.15066E-19 -19.8220 0.15014E-19 -19.8235 0.99654E+00 -0.0015 31 CO,aq 0.12482E-15 -15.9037 0.12482E-15 -15.9037 0.10000E+01 0.0000 32 CO2,aq 0.43047E-09 -9.3661 0.42898E-09 -9.3676 0.99654E+00 -0.0015 33 CO3-2 0.60895E-05 -5.2154 0.31503E-05 -5.5016 0.51734E+00 -0.2862 34 CaCO3,aq 0.27798E-08 -8.5560 0.27798E-08 -8.5560 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.57787E-11 -11.2382 0.48336E-11 -11.3157 0.83645E+00 -0.0776 36 CaCl+ 0.32813E-10 -10.4840 0.27446E-10 -10.5615 0.83645E+00 -0.0776 37 CaCl2,aq 0.15715E-14 -14.8037 0.15715E-14 -14.8037 0.10000E+01 0.0000 38 CaF+ 0.10521E-11 -11.9779 0.88007E-12 -12.0555 0.83645E+00 -0.0776 39 CaOH+ 0.80366E-07 -7.0949 0.67222E-07 -7.1725 0.83645E+00 -0.0776 40 CaSO4,aq 0.29820E-16 -16.5255 0.29820E-16 -16.5255 0.10000E+01 0.0000 41 HCl,aq 0.32949E-14 -14.4822 0.32949E-14 -14.4822 0.10000E+01 0.0000 45 HF,aq 0.43749E-12 -12.3590 0.43749E-12 -12.3590 0.10000E+01 0.0000 46 HF2- 0.15156E-18 -18.8194 0.12653E-18 -18.8978 0.83484E+00 -0.0784 48 FeCl+ 0.13790E-16 -16.8604 0.11535E-16 -16.9380 0.83645E+00 -0.0776 51 FeF+ 0.15824E-17 -17.8007 0.13236E-17 -17.8783 0.83645E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15772E-10 -10.8021 0.13192E-10 -10.8797 0.83645E+00 -0.0776 55 HFeO2- 0.35466E-07 -7.4502 0.29609E-07 -7.5286 0.83484E+00 -0.0784 56 FeO+ 0.11054E-16 -16.9565 0.92458E-17 -17.0341 0.83645E+00 -0.0776 58 FeO2- 0.40712E-09 -9.3903 0.33988E-09 -9.4687 0.83484E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 61 KCl,aq 0.57518E-09 -9.2402 0.57518E-09 -9.2402 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.32662E-14 -14.4860 0.27268E-14 -14.5643 0.83484E+00 -0.0784 65 MgCO3,aq 0.10851E-12 -12.9645 0.10851E-12 -12.9645 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.91953E-15 -15.0364 0.76914E-15 -15.1140 0.83645E+00 -0.0776 67 MgCl+ 0.46312E-14 -14.3343 0.38738E-14 -14.4119 0.83645E+00 -0.0776 68 MgF+ 0.60694E-15 -15.2169 0.50768E-15 -15.2944 0.83645E+00 -0.0776 69 MgOH+ 0.69253E-10 -10.1596 0.57926E-10 -10.2371 0.83645E+00 -0.0776 71 MnF+ 0.16747E-15 -15.7761 0.14008E-15 -15.8536 0.83645E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47046E-09 -9.3275 0.39351E-09 -9.4050 0.83645E+00 -0.0776 74 MnO2-2 0.20818E-10 -10.6816 0.10770E-10 -10.9678 0.51734E+00 -0.2862 75 HMnO2- 0.21086E-09 -9.6760 0.17604E-09 -9.7544 0.83484E+00 -0.0784 78 MnCl+ 0.17227E-13 -13.7638 0.14409E-13 -13.8414 0.83645E+00 -0.0776 80 NaCl,aq 0.13321E-05 -5.8755 0.13321E-05 -5.8755 0.10000E+01 0.0000 81 NaF,aq 0.33447E-08 -8.4756 0.33447E-08 -8.4756 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92931E-02 -2.0318 0.77442E-02 -2.1110 0.83333E+00 -0.0792 89 HPO3-2 0.16239E-14 -14.7894 0.84012E-15 -15.0757 0.51734E+00 -0.2862 91 H2PO3- 0.15056E-18 -18.8223 0.12569E-18 -18.9007 0.83484E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38335E-10 -10.4164 0.32034E-10 -10.4944 0.83564E+00 -0.0780 94 PO4-3 0.10527E-08 -8.9777 0.25453E-09 -9.5943 0.24179E+00 -0.6166 98 HP2O7-3 0.93470E-18 -18.0293 0.21535E-18 -18.6669 0.23039E+00 -0.6375 99 P2O7-4 0.90017E-17 -17.0457 0.68955E-18 -18.1614 0.76602E-01 -1.1158 100 H2S,aq 0.19665E-07 -7.7063 0.19597E-07 -7.7078 0.99654E+00 -0.0015 101 S2-2 0.26711E-13 -13.5733 0.13819E-13 -13.8595 0.51734E+00 -0.2862 107 SO3-2 0.38268E-17 -17.4172 0.20086E-17 -17.6971 0.52486E+00 -0.2800 108 HSO3- 0.11239E-19 -19.9493 0.93827E-20 -20.0277 0.83484E+00 -0.0784 109 HSO4- 0.11460E-18 -18.9408 0.95948E-19 -19.0180 0.83727E+00 -0.0771 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8882679E-10 -.2220355E-01 -.2234077E+02 0.0000 2 H2O 0.1000000E+01 0.5550505E+02 0.9981943E+06 0.0000 3 Cl- 0.2886845E-03 0.2900172E-03 0.1026403E+02 6.5092 4 SO4-- 0.2573957E-11 -.1699585E-03 -.1629798E+02 8.3797 5 HCO3- 0.3218498E-05 0.1763641E-03 0.1074245E+02 4.5571 6 HS- 0.1017897E-03 0.2717679E-03 0.8972215E+01 6.0566 7 Al+++ 0.9892088E-29 0.5288538E-05 0.1424436E+00 0.7390 8 H4SiO4 0.6959773E-03 0.1347931E-01 0.1293307E+04 -3.1574 9 Ca++ 0.1367415E-06 0.2366158E-06 0.9466532E-02 13.1018 10 Mg++ 0.2139270E-10 0.9399390E-10 0.2281190E-05 9.2942 11 Fe++ 0.5896193E-13 0.3610359E-07 0.2012757E-02 6.7350 12 K+ 0.1574616E-03 0.1582159E-03 0.6175758E+01 6.2467 13 Na+ 0.1998127E-01 0.2242827E-01 0.5147212E+03 8.3494 14 Mn++ 0.1891676E-10 0.2527434E-08 0.1386098E-03 9.2416 15 F- 0.1028176E-05 0.1031522E-05 0.1956264E-01 4.0600 16 HPO4-- 0.4488770E-07 0.4597873E-07 0.4405288E-02 12.6213 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279244E+02 -.1102082E-01 -.8278142E+02 0.0000000E+00 2 H2O -.7167945E+01 0.2755015E+02 -.3471809E+02 0.0000000E+00 3 Cl- 0.1439512E-03 0.1439512E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385974E+00 -.8435958E-04 0.1386818E+00 0.0000000E+00 5 HCO3- 0.8753900E-04 0.8753900E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385469E+00 0.1348930E-03 -.1386818E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2624987E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6690507E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1174452E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4665424E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1792016E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7853109E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113236E-01 0.6265245E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254502E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5120000E-06 0.5120000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2282172E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.5981E-14 Mass of aqueous solution: 0.497222E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0010300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5547 -0.256 281.9 2.450 5.161 73.24 grossular 0.1343 -0.872 60.51 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2607 -0.584 56.46 1.752 1.034 17.26 hedenbergite 0.6762E-01 -1.170 16.78 1.225 0.3071 4.595 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.155 97.26 tr.625ac.25prg.125 0.4312E-01 -1.365 36.86 1.567 0.6748 11.86 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338203 g Volume = 2210.780711 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0010300 moles log = -2.9872 Original solution: 1000.0103000 g Original solution / Rock added: 970883.79 (Water/Rock Ratio), log = 5.9872 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2812 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7988E+00 0.9830 0.1006E+01 0.1023E+01 CO2,gas 0.3567E-07 1.0042 0.4590E-07 0.4570E-07 CH4,gas 0.1894E+00 1.0100 0.2450E+00 0.2426E+00 H2,gas 0.1186E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4226E-06 0.9950 0.5387E-06 0.5414E-06 S2,gas 0.3677E-28 1.0000 0.4711E-28 0.4711E-28 CO,gas 0.1452E-12 1.0000 0.1860E-12 0.1860E-12 SO3,gas 0.2192E-47 1.0000 0.2809E-47 0.2809E-47 SO2,gas 0.1297E-26 1.0000 0.1662E-26 0.1662E-26 HF,gas 0.8384E-15 1.0000 0.1074E-14 0.1074E-14 HCl,gas 0.4538E-17 1.0000 0.5814E-17 0.5814E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.70 -9.04 -3.012 0.15431E+05 -7.338 3 CH4,gas 4.54 2.23 -2.31 -0.577 0.39438E+04 -0.611 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.20 -7.97 -3.984 0.13604E+05 -6.269 6 S2,gas -7.34 -37.36 -30.03 -4.619 0.51268E+05 -28.327 7 CO,gas 3.21 -11.21 -14.43 -4.440 0.24638E+05 -12.730 8 SO3,gas 17.12 -32.13 -49.25 -12.313 0.84094E+05 -47.552 9 SO2,gas 0.83 -27.65 -28.48 -7.594 0.48626E+05 -26.779 10 HF,gas 0.47 -16.19 -16.67 -8.334 0.28460E+05 -14.969 11 HCl,gas 5.19 -13.75 -18.93 -9.467 0.32330E+05 -17.236 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.35 -0.05 -0.004 0.80164E+02 38 aragonite 0.97 -2.60 -3.56 -1.187 0.60820E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.60 -3.41 -1.136 0.58178E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.73 -3.63 -1.037 0.61969E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.73 -3.19 -0.910 0.54392E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.14 -4.90 -1.152 0.83608E+04 146 pyrrhotite -4.26 -7.46 -3.20 -1.068 0.54683E+04 147 pyrrhotiteFe0.875 -6.02 -8.86 -2.84 -1.046 0.48555E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.46 -3.05 -1.017 0.52111E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.96 -3.98 -1.326 0.67929E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0010300 MOLES New total amount of reactant added: 0.0010700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0010700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134469E-01 Osmotic coef. = 1.3513 True ionic strength = .2014720E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.1442E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88834E-10 -10.0514 0.74613E-10 -10.1272 0.83991E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28916E-03 -3.5389 0.24140E-03 -3.6173 0.83484E+00 -0.0784 4 SO4-- 0.26233E-11 -11.5811 0.13600E-11 -11.8665 0.51844E+00 -0.2853 5 HCO3- 0.33246E-05 -5.4783 0.27796E-05 -5.5560 0.83606E+00 -0.0778 6 HS- 0.10375E-03 -3.9840 0.86625E-04 -4.0624 0.83496E+00 -0.0783 7 Al+++ 0.98948E-29 -29.0046 0.22773E-29 -29.6426 0.23015E+00 -0.6380 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13677E-06 -6.8640 0.70381E-07 -7.1525 0.51461E+00 -0.2885 10 Mg++ 0.21396E-10 -10.6697 0.10960E-10 -10.9602 0.51225E+00 -0.2905 11 Fe++ 0.58972E-13 -13.2294 0.30241E-13 -13.5194 0.51281E+00 -0.2900 12 K+ 0.15747E-03 -3.8028 0.13169E-03 -3.8804 0.83626E+00 -0.0777 13 Na+ 0.19983E-01 -1.6993 0.16679E-01 -1.7778 0.83468E+00 -0.0785 14 Mn++ 0.18920E-10 -10.7231 0.97105E-11 -11.0128 0.51324E+00 -0.2897 15 F- 0.10603E-05 -5.9746 0.88335E-06 -6.0539 0.83311E+00 -0.0793 16 HPO4-- 0.44882E-07 -7.3479 0.23272E-07 -7.6332 0.51851E+00 -0.2852 18 HSiO3- 0.10433E-01 -1.9816 0.87098E-02 -2.0600 0.83484E+00 -0.0784 19 Ca(HSiO3)+ 0.16690E-07 -7.7775 0.13960E-07 -7.8551 0.83644E+00 -0.0776 20 Mg(HSiO3)+ 0.32346E-11 -11.4902 0.27056E-11 -11.5677 0.83644E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66531E-16 -16.1770 0.55650E-16 -16.2545 0.83644E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52880E-05 -5.2767 0.44066E-05 -5.3559 0.83332E+00 -0.0792 26 CH4,aq 0.17257E-03 -3.7630 0.17198E-03 -3.7645 0.99654E+00 -0.0015 27 C2H6,aq 0.43804E-12 -12.3585 0.43653E-12 -12.3600 0.99654E+00 -0.0015 28 C3H8,aq 0.25671E-19 -19.5906 0.25582E-19 -19.5921 0.99654E+00 -0.0015 30 ethanol,aq 0.16078E-19 -19.7938 0.16022E-19 -19.7953 0.99654E+00 -0.0015 31 CO,aq 0.12894E-15 -15.8896 0.12894E-15 -15.8896 0.10000E+01 0.0000 32 CO2,aq 0.44469E-09 -9.3519 0.44315E-09 -9.3534 0.99654E+00 -0.0015 33 CO3-2 0.62899E-05 -5.2014 0.32540E-05 -5.4876 0.51733E+00 -0.2862 34 CaCO3,aq 0.28716E-08 -8.5419 0.28716E-08 -8.5419 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.59701E-11 -11.2240 0.49937E-11 -11.3016 0.83644E+00 -0.0776 36 CaCl+ 0.32871E-10 -10.4832 0.27495E-10 -10.5607 0.83644E+00 -0.0776 37 CaCl2,aq 0.15769E-14 -14.8022 0.15769E-14 -14.8022 0.10000E+01 0.0000 38 CaF+ 0.10852E-11 -11.9645 0.90770E-12 -12.0421 0.83644E+00 -0.0776 39 CaOH+ 0.80372E-07 -7.0949 0.67227E-07 -7.1725 0.83644E+00 -0.0776 40 CaSO4,aq 0.30395E-16 -16.5172 0.30395E-16 -16.5172 0.10000E+01 0.0000 41 HCl,aq 0.33005E-14 -14.4814 0.33005E-14 -14.4814 0.10000E+01 0.0000 45 HF,aq 0.45119E-12 -12.3456 0.45119E-12 -12.3456 0.10000E+01 0.0000 46 HF2- 0.16119E-18 -18.7927 0.13456E-18 -18.8711 0.83484E+00 -0.0784 48 FeCl+ 0.13815E-16 -16.8597 0.11555E-16 -16.9372 0.83644E+00 -0.0776 51 FeF+ 0.16320E-17 -17.7873 0.13651E-17 -17.8648 0.83644E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15773E-10 -10.8021 0.13193E-10 -10.8796 0.83644E+00 -0.0776 55 HFeO2- 0.35464E-07 -7.4502 0.29607E-07 -7.5286 0.83484E+00 -0.0784 56 FeO+ 0.11055E-16 -16.9565 0.92465E-17 -17.0340 0.83644E+00 -0.0776 58 FeO2- 0.40710E-09 -9.3903 0.33986E-09 -9.4687 0.83484E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 61 KCl,aq 0.57617E-09 -9.2395 0.57617E-09 -9.2395 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.33290E-14 -14.4777 0.27792E-14 -14.5561 0.83484E+00 -0.0784 65 MgCO3,aq 0.11209E-12 -12.9504 0.11209E-12 -12.9504 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.94999E-15 -15.0223 0.79461E-15 -15.0998 0.83644E+00 -0.0776 67 MgCl+ 0.46395E-14 -14.3335 0.38807E-14 -14.4111 0.83644E+00 -0.0776 68 MgF+ 0.62600E-15 -15.2034 0.52362E-15 -15.2810 0.83644E+00 -0.0776 69 MgOH+ 0.69258E-10 -10.1595 0.57931E-10 -10.2371 0.83644E+00 -0.0776 71 MnF+ 0.17273E-15 -15.7626 0.14448E-15 -15.8402 0.83644E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47050E-09 -9.3274 0.39354E-09 -9.4050 0.83644E+00 -0.0776 74 MnO2-2 0.20815E-10 -10.6816 0.10768E-10 -10.9678 0.51733E+00 -0.2862 75 HMnO2- 0.21085E-09 -9.6760 0.17603E-09 -9.7544 0.83484E+00 -0.0784 78 MnCl+ 0.17257E-13 -13.7630 0.14435E-13 -13.8406 0.83644E+00 -0.0776 80 NaCl,aq 0.13344E-05 -5.8747 0.13344E-05 -5.8747 0.10000E+01 0.0000 81 NaF,aq 0.34494E-08 -8.4623 0.34494E-08 -8.4623 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92925E-02 -2.0319 0.77436E-02 -2.1111 0.83332E+00 -0.0792 89 HPO3-2 0.16237E-14 -14.7895 0.84000E-15 -15.0757 0.51733E+00 -0.2862 91 H2PO3- 0.15055E-18 -18.8223 0.12568E-18 -18.9007 0.83484E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38332E-10 -10.4164 0.32031E-10 -10.4944 0.83563E+00 -0.0780 94 PO4-3 0.10525E-08 -8.9778 0.25448E-09 -9.5944 0.24178E+00 -0.6166 98 HP2O7-3 0.93454E-18 -18.0294 0.21530E-18 -18.6670 0.23038E+00 -0.6376 99 P2O7-4 0.89999E-17 -17.0458 0.68934E-18 -18.1616 0.76595E-01 -1.1158 100 H2S,aq 0.20045E-07 -7.6980 0.19976E-07 -7.6995 0.99654E+00 -0.0015 101 S2-2 0.27749E-13 -13.5568 0.14355E-13 -13.8430 0.51733E+00 -0.2862 107 SO3-2 0.39002E-17 -17.4089 0.20470E-17 -17.6889 0.52485E+00 -0.2800 108 HSO3- 0.11455E-19 -19.9410 0.95631E-20 -20.0194 0.83484E+00 -0.0784 109 HSO4- 0.11680E-18 -18.9326 0.97793E-19 -19.0097 0.83726E+00 -0.0771 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8883392E-10 -.2220240E-01 -.2233961E+02 0.0000 2 H2O 0.1000000E+01 0.5550505E+02 0.9981942E+06 0.0000 3 Cl- 0.2891573E-03 0.2904923E-03 0.1028084E+02 6.5099 4 SO4-- 0.2623313E-11 -.1754781E-03 -.1682727E+02 8.3879 5 HCO3- 0.3324616E-05 0.1821903E-03 0.1109733E+02 4.5712 6 HS- 0.1037474E-03 0.2792456E-03 0.9219085E+01 6.0648 7 Al+++ 0.9894840E-29 0.5288177E-05 0.1424338E+00 0.7390 8 H4SiO4 0.6959772E-03 0.1347859E-01 0.1293238E+04 -3.1574 9 Ca++ 0.1367652E-06 0.2367395E-06 0.9471477E-02 13.1018 10 Mg++ 0.2139642E-10 0.9400718E-10 0.2281512E-05 9.2942 11 Fe++ 0.5897217E-13 0.3610113E-07 0.2012619E-02 6.7350 12 K+ 0.1574742E-03 0.1582286E-03 0.6176250E+01 6.2467 13 Na+ 0.1998288E-01 0.2242988E-01 0.5147581E+03 8.3494 14 Mn++ 0.1892012E-10 0.2527468E-08 0.1386116E-03 9.2416 15 F- 0.1060305E-05 0.1063756E-05 0.2017394E-01 4.0733 16 HPO4-- 0.4488207E-07 0.4597292E-07 0.4404730E-02 12.6212 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279243E+02 -.1102026E-01 -.8278141E+02 0.0000000E+00 2 H2O -.7167913E+01 0.2755019E+02 -.3471810E+02 0.0000000E+00 3 Cl- 0.1441872E-03 0.1441872E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385976E+00 -.8709936E-04 0.1386847E+00 0.0000000E+00 5 HCO3- 0.9043100E-04 0.9043100E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385461E+00 0.1386048E-03 -.1386847E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2624811E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6690162E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1175067E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4666090E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1791896E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7853748E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113317E-01 0.6265244E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254520E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5280000E-06 0.5280000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2281887E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.4469E-14 Mass of aqueous solution: 0.497223E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0010700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5547 -0.256 281.9 2.450 5.161 73.24 grossular 0.1343 -0.872 60.51 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2606 -0.584 56.45 1.752 1.033 17.25 hedenbergite 0.6760E-01 -1.170 16.77 1.225 0.3070 4.593 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.155 97.26 tr.625ac.25prg.125 0.4315E-01 -1.365 36.88 1.567 0.6752 11.87 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338217 g Volume = 2210.780822 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0010700 moles log = -2.9706 Original solution: 1000.0103000 g Original solution / Rock added: 934589.07 (Water/Rock Ratio), log = 5.9706 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2893 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7938E+00 0.9829 0.1006E+01 0.1023E+01 CO2,gas 0.3662E-07 1.0042 0.4741E-07 0.4722E-07 CH4,gas 0.1944E+00 1.0099 0.2531E+00 0.2507E+00 H2,gas 0.1179E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4280E-06 0.9950 0.5491E-06 0.5519E-06 S2,gas 0.3796E-28 1.0000 0.4895E-28 0.4895E-28 CO,gas 0.1490E-12 1.0000 0.1921E-12 0.1921E-12 SO3,gas 0.2220E-47 1.0000 0.2863E-47 0.2863E-47 SO2,gas 0.1314E-26 1.0000 0.1694E-26 0.1694E-26 HF,gas 0.8592E-15 1.0000 0.1108E-14 0.1108E-14 HCl,gas 0.4517E-17 1.0000 0.5824E-17 0.5824E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.63695E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.68 -9.02 -3.008 0.15407E+05 -7.324 3 CH4,gas 4.54 2.25 -2.30 -0.574 0.39197E+04 -0.597 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.19 -7.96 -3.980 0.13590E+05 -6.260 6 S2,gas -7.34 -37.34 -30.01 -4.617 0.51240E+05 -28.310 7 CO,gas 3.21 -11.20 -14.42 -4.435 0.24614E+05 -12.716 8 SO3,gas 17.12 -32.12 -49.24 -12.311 0.84080E+05 -47.543 9 SO2,gas 0.83 -27.64 -28.47 -7.592 0.48612E+05 -26.771 10 HF,gas 0.47 -16.18 -16.65 -8.327 0.28437E+05 -14.956 11 HCl,gas 5.19 -13.74 -18.93 -9.467 0.32329E+05 -17.235 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.33 -0.03 -0.003 0.57296E+02 38 aragonite 0.97 -2.58 -3.55 -1.183 0.60579E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.58 -3.39 -1.131 0.57937E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.72 -3.62 -1.033 0.61728E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.72 -3.17 -0.906 0.54151E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.13 -4.88 -1.148 0.83325E+04 146 pyrrhotite -4.26 -7.45 -3.19 -1.065 0.54541E+04 147 pyrrhotiteFe0.875 -6.02 -8.85 -2.84 -1.043 0.48413E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.45 -3.04 -1.015 0.51969E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.95 -3.97 -1.323 0.67788E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0010700 MOLES New total amount of reactant added: 0.0011100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0011100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134136E-01 Osmotic coef. = 1.5247 True ionic strength = .2014902E-01 Chg. balance for total moles = -.8663E-10 Max. difference allowed = 0.1444E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88841E-10 -10.0514 0.74618E-10 -10.1272 0.83991E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28963E-03 -3.5382 0.24179E-03 -3.6166 0.83483E+00 -0.0784 4 SO4-- 0.26727E-11 -11.5731 0.13856E-11 -11.8584 0.51842E+00 -0.2853 5 HCO3- 0.34307E-05 -5.4646 0.28683E-05 -5.5424 0.83606E+00 -0.0778 6 HS- 0.10571E-03 -3.9759 0.88259E-04 -4.0542 0.83495E+00 -0.0783 7 Al+++ 0.98976E-29 -29.0045 0.22778E-29 -29.6425 0.23013E+00 -0.6380 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13679E-06 -6.8639 0.70391E-07 -7.1525 0.51460E+00 -0.2885 10 Mg++ 0.21400E-10 -10.6696 0.10962E-10 -10.9601 0.51223E+00 -0.2905 11 Fe++ 0.58982E-13 -13.2293 0.30246E-13 -13.5193 0.51280E+00 -0.2901 12 K+ 0.15749E-03 -3.8028 0.13170E-03 -3.8804 0.83626E+00 -0.0777 13 Na+ 0.19984E-01 -1.6993 0.16681E-01 -1.7778 0.83468E+00 -0.0785 14 Mn++ 0.18923E-10 -10.7230 0.97120E-11 -11.0127 0.51322E+00 -0.2897 15 F- 0.10924E-05 -5.9616 0.91011E-06 -6.0409 0.83310E+00 -0.0793 16 HPO4-- 0.44876E-07 -7.3480 0.23268E-07 -7.6332 0.51850E+00 -0.2853 18 HSiO3- 0.10432E-01 -1.9816 0.87092E-02 -2.0600 0.83483E+00 -0.0784 19 Ca(HSiO3)+ 0.16692E-07 -7.7775 0.13962E-07 -7.8551 0.83644E+00 -0.0776 20 Mg(HSiO3)+ 0.32349E-11 -11.4901 0.27058E-11 -11.5677 0.83644E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66537E-16 -16.1769 0.55654E-16 -16.2545 0.83644E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52877E-05 -5.2767 0.44063E-05 -5.3559 0.83332E+00 -0.0792 26 CH4,aq 0.17809E-03 -3.7494 0.17748E-03 -3.7509 0.99654E+00 -0.0015 27 C2H6,aq 0.46651E-12 -12.3311 0.46490E-12 -12.3326 0.99654E+00 -0.0015 28 C3H8,aq 0.28214E-19 -19.5495 0.28116E-19 -19.5510 0.99654E+00 -0.0015 30 ethanol,aq 0.17123E-19 -19.7664 0.17064E-19 -19.7679 0.99654E+00 -0.0015 31 CO,aq 0.13306E-15 -15.8759 0.13306E-15 -15.8759 0.10000E+01 0.0000 32 CO2,aq 0.45891E-09 -9.3383 0.45733E-09 -9.3398 0.99654E+00 -0.0015 33 CO3-2 0.64903E-05 -5.1877 0.33575E-05 -5.4740 0.51732E+00 -0.2862 34 CaCO3,aq 0.29635E-08 -8.5282 0.29635E-08 -8.5282 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.61616E-11 -11.2103 0.51538E-11 -11.2879 0.83644E+00 -0.0776 36 CaCl+ 0.32930E-10 -10.4824 0.27544E-10 -10.5600 0.83644E+00 -0.0776 37 CaCl2,aq 0.15822E-14 -14.8007 0.15822E-14 -14.8007 0.10000E+01 0.0000 38 CaF+ 0.11182E-11 -11.9515 0.93534E-12 -12.0290 0.83644E+00 -0.0776 39 CaOH+ 0.80379E-07 -7.0949 0.67232E-07 -7.1724 0.83644E+00 -0.0776 40 CaSO4,aq 0.30971E-16 -16.5090 0.30971E-16 -16.5090 0.10000E+01 0.0000 41 HCl,aq 0.33061E-14 -14.4807 0.33061E-14 -14.4807 0.10000E+01 0.0000 45 HF,aq 0.46490E-12 -12.3326 0.46490E-12 -12.3326 0.10000E+01 0.0000 46 HF2- 0.17111E-18 -18.7667 0.14285E-18 -18.8451 0.83483E+00 -0.0784 48 FeCl+ 0.13839E-16 -16.8589 0.11576E-16 -16.9365 0.83644E+00 -0.0776 51 FeF+ 0.16818E-17 -17.7742 0.14067E-17 -17.8518 0.83644E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15774E-10 -10.8020 0.13194E-10 -10.8796 0.83644E+00 -0.0776 55 HFeO2- 0.35461E-07 -7.4502 0.29604E-07 -7.5286 0.83483E+00 -0.0784 56 FeO+ 0.11055E-16 -16.9564 0.92472E-17 -17.0340 0.83644E+00 -0.0776 58 FeO2- 0.40707E-09 -9.3903 0.33983E-09 -9.4687 0.83483E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 61 KCl,aq 0.57715E-09 -9.2387 0.57715E-09 -9.2387 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.33919E-14 -14.4696 0.28316E-14 -14.5480 0.83483E+00 -0.0784 65 MgCO3,aq 0.11568E-12 -12.9368 0.11568E-12 -12.9368 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.98045E-15 -15.0086 0.82009E-15 -15.0861 0.83644E+00 -0.0776 67 MgCl+ 0.46478E-14 -14.3328 0.38876E-14 -14.4103 0.83644E+00 -0.0776 68 MgF+ 0.64507E-15 -15.1904 0.53956E-15 -15.2680 0.83644E+00 -0.0776 69 MgOH+ 0.69264E-10 -10.1595 0.57935E-10 -10.2371 0.83644E+00 -0.0776 71 MnF+ 0.17799E-15 -15.7496 0.14888E-15 -15.8272 0.83644E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47053E-09 -9.3274 0.39357E-09 -9.4050 0.83644E+00 -0.0776 74 MnO2-2 0.20813E-10 -10.6817 0.10767E-10 -10.9679 0.51732E+00 -0.2862 75 HMnO2- 0.21084E-09 -9.6761 0.17601E-09 -9.7545 0.83483E+00 -0.0784 78 MnCl+ 0.17288E-13 -13.7622 0.14461E-13 -13.8398 0.83644E+00 -0.0776 80 NaCl,aq 0.13366E-05 -5.8740 0.13366E-05 -5.8740 0.10000E+01 0.0000 81 NaF,aq 0.35542E-08 -8.4493 0.35542E-08 -8.4493 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92918E-02 -2.0319 0.77430E-02 -2.1111 0.83332E+00 -0.0792 89 HPO3-2 0.16235E-14 -14.7895 0.83987E-15 -15.0758 0.51732E+00 -0.2862 91 H2PO3- 0.15054E-18 -18.8224 0.12567E-18 -18.9008 0.83483E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38329E-10 -10.4165 0.32029E-10 -10.4945 0.83563E+00 -0.0780 94 PO4-3 0.10523E-08 -8.9778 0.25442E-09 -9.5944 0.24177E+00 -0.6166 98 HP2O7-3 0.93438E-18 -18.0295 0.21525E-18 -18.6671 0.23037E+00 -0.6376 99 P2O7-4 0.89981E-17 -17.0459 0.68914E-18 -18.1617 0.76587E-01 -1.1158 100 H2S,aq 0.20425E-07 -7.6898 0.20354E-07 -7.6913 0.99654E+00 -0.0015 101 S2-2 0.28806E-13 -13.5405 0.14902E-13 -13.8268 0.51732E+00 -0.2862 107 SO3-2 0.39736E-17 -17.4008 0.20855E-17 -17.6808 0.52484E+00 -0.2800 108 HSO3- 0.11671E-19 -19.9329 0.97435E-20 -20.0113 0.83483E+00 -0.0784 109 HSO4- 0.11900E-18 -18.9244 0.99638E-19 -19.0016 0.83726E+00 -0.0771 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8884105E-10 -.2220125E-01 -.2233845E+02 0.0000 2 H2O 0.1000000E+01 0.5550506E+02 0.9981942E+06 0.0000 3 Cl- 0.2896301E-03 0.2909673E-03 0.1029765E+02 6.5106 4 SO4-- 0.2672663E-11 -.1809977E-03 -.1735657E+02 8.3959 5 HCO3- 0.3430721E-05 0.1880165E-03 0.1145221E+02 4.5848 6 HS- 0.1057052E-03 0.2867233E-03 0.9465955E+01 6.0729 7 Al+++ 0.9897592E-29 0.5287816E-05 0.1424241E+00 0.7390 8 H4SiO4 0.6959771E-03 0.1347788E-01 0.1293170E+04 -3.1574 9 Ca++ 0.1367889E-06 0.2368631E-06 0.9476424E-02 13.1018 10 Mg++ 0.2140014E-10 0.9402135E-10 0.2281856E-05 9.2942 11 Fe++ 0.5898242E-13 0.3609867E-07 0.2012482E-02 6.7350 12 K+ 0.1574869E-03 0.1582412E-03 0.6176743E+01 6.2467 13 Na+ 0.1998448E-01 0.2243149E-01 0.5147949E+03 8.3494 14 Mn++ 0.1892348E-10 0.2527502E-08 0.1386134E-03 9.2416 15 F- 0.1092433E-05 0.1095989E-05 0.2078524E-01 4.0862 16 HPO4-- 0.4487644E-07 0.4596711E-07 0.4404173E-02 12.6211 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279243E+02 -.1101971E-01 -.8278141E+02 0.0000000E+00 2 H2O -.7167880E+01 0.2755023E+02 -.3471811E+02 0.0000000E+00 3 Cl- 0.1444232E-03 0.1444232E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385978E+00 -.8983918E-04 0.1386877E+00 0.0000000E+00 5 HCO3- 0.9332300E-04 0.9332300E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385453E+00 0.1423167E-03 -.1386877E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2624636E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6689817E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1175683E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4666800E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1791777E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7854387E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113399E-01 0.6265243E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254539E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5440000E-06 0.5440000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2281602E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.2168E-13 Mass of aqueous solution: 0.497224E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0011100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5548 -0.256 281.9 2.450 5.161 73.24 grossular 0.1343 -0.872 60.51 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2606 -0.584 56.43 1.752 1.033 17.25 hedenbergite 0.6758E-01 -1.170 16.77 1.224 0.3069 4.592 microcline 0.9309 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.155 97.26 tr.625ac.25prg.125 0.4317E-01 -1.365 36.90 1.567 0.6756 11.88 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338230 g Volume = 2210.780933 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0011100 moles log = -2.9547 Original solution: 1000.0103000 g Original solution / Rock added: 900910.18 (Water/Rock Ratio), log = 5.9547 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2974 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7889E+00 0.9828 0.1006E+01 0.1024E+01 CO2,gas 0.3756E-07 1.0041 0.4893E-07 0.4873E-07 CH4,gas 0.1994E+00 1.0098 0.2612E+00 0.2587E+00 H2,gas 0.1171E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4334E-06 0.9950 0.5595E-06 0.5624E-06 S2,gas 0.3917E-28 1.0000 0.5082E-28 0.5082E-28 CO,gas 0.1528E-12 1.0000 0.1983E-12 0.1983E-12 SO3,gas 0.2248E-47 1.0000 0.2917E-47 0.2917E-47 SO2,gas 0.1330E-26 1.0000 0.1726E-26 0.1726E-26 HF,gas 0.8798E-15 1.0000 0.1141E-14 0.1141E-14 HCl,gas 0.4496E-17 1.0000 0.5834E-17 0.5834E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.67 -9.01 -3.003 0.15383E+05 -7.310 3 CH4,gas 4.54 2.26 -2.28 -0.570 0.38964E+04 -0.583 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.18 -7.95 -3.976 0.13576E+05 -6.252 6 S2,gas -7.34 -37.33 -29.99 -4.614 0.51212E+05 -28.294 7 CO,gas 3.21 -11.19 -14.40 -4.431 0.24590E+05 -12.703 8 SO3,gas 17.12 -32.11 -49.23 -12.309 0.84066E+05 -47.535 9 SO2,gas 0.83 -27.63 -28.46 -7.590 0.48598E+05 -26.763 10 HF,gas 0.47 -16.17 -16.64 -8.321 0.28415E+05 -14.943 11 HCl,gas 5.19 -13.74 -18.93 -9.467 0.32328E+05 -17.234 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.32 -0.02 -0.002 0.35109E+02 38 aragonite 0.97 -2.57 -3.53 -1.178 0.60346E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.57 -3.38 -1.126 0.57704E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.70 -3.60 -1.029 0.61495E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.70 -3.16 -0.902 0.53917E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.11 -4.86 -1.144 0.83046E+04 146 pyrrhotite -4.26 -7.45 -3.19 -1.062 0.54402E+04 147 pyrrhotiteFe0.875 -6.02 -8.84 -2.83 -1.040 0.48274E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.45 -3.04 -1.012 0.51830E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.94 -3.96 -1.321 0.67649E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0011100 MOLES New total amount of reactant added: 0.0011500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0011500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133804E-01 Osmotic coef. = 1.9300 True ionic strength = .2015084E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1447E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88848E-10 -10.0514 0.74624E-10 -10.1271 0.83990E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29010E-03 -3.5374 0.24219E-03 -3.6159 0.83483E+00 -0.0784 4 SO4-- 0.27220E-11 -11.5651 0.14111E-11 -11.8504 0.51841E+00 -0.2853 5 HCO3- 0.35368E-05 -5.4514 0.29570E-05 -5.5292 0.83605E+00 -0.0778 6 HS- 0.10766E-03 -3.9679 0.89893E-04 -4.0463 0.83495E+00 -0.0783 7 Al+++ 0.99003E-29 -29.0043 0.22783E-29 -29.6424 0.23012E+00 -0.6380 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13681E-06 -6.8639 0.70402E-07 -7.1524 0.51459E+00 -0.2885 10 Mg++ 0.21404E-10 -10.6695 0.10963E-10 -10.9601 0.51222E+00 -0.2905 11 Fe++ 0.58993E-13 -13.2292 0.30250E-13 -13.5193 0.51278E+00 -0.2901 12 K+ 0.15750E-03 -3.8027 0.13171E-03 -3.8804 0.83625E+00 -0.0777 13 Na+ 0.19986E-01 -1.6993 0.16682E-01 -1.7778 0.83467E+00 -0.0785 14 Mn++ 0.18927E-10 -10.7229 0.97135E-11 -11.0126 0.51321E+00 -0.2897 15 F- 0.11246E-05 -5.9490 0.93687E-06 -6.0283 0.83310E+00 -0.0793 16 HPO4-- 0.44871E-07 -7.3480 0.23265E-07 -7.6333 0.51849E+00 -0.2853 18 HSiO3- 0.10432E-01 -1.9817 0.87085E-02 -2.0601 0.83483E+00 -0.0784 19 Ca(HSiO3)+ 0.16693E-07 -7.7775 0.13963E-07 -7.8550 0.83643E+00 -0.0776 20 Mg(HSiO3)+ 0.32352E-11 -11.4901 0.27060E-11 -11.5677 0.83643E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66542E-16 -16.1769 0.55658E-16 -16.2545 0.83643E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52873E-05 -5.2768 0.44060E-05 -5.3560 0.83331E+00 -0.0792 26 CH4,aq 0.18361E-03 -3.7361 0.18298E-03 -3.7376 0.99654E+00 -0.0015 27 C2H6,aq 0.49588E-12 -12.3046 0.49417E-12 -12.3061 0.99654E+00 -0.0015 28 C3H8,aq 0.30919E-19 -19.5098 0.30812E-19 -19.5113 0.99654E+00 -0.0015 30 ethanol,aq 0.18201E-19 -19.7399 0.18138E-19 -19.7414 0.99654E+00 -0.0015 31 CO,aq 0.13719E-15 -15.8627 0.13719E-15 -15.8627 0.10000E+01 0.0000 32 CO2,aq 0.47314E-09 -9.3250 0.47150E-09 -9.3265 0.99654E+00 -0.0015 33 CO3-2 0.66906E-05 -5.1745 0.34611E-05 -5.4608 0.51731E+00 -0.2863 34 CaCO3,aq 0.30553E-08 -8.5149 0.30553E-08 -8.5149 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.63530E-11 -11.1970 0.53139E-11 -11.2746 0.83643E+00 -0.0776 36 CaCl+ 0.32989E-10 -10.4816 0.27593E-10 -10.5592 0.83643E+00 -0.0776 37 CaCl2,aq 0.15876E-14 -14.7992 0.15876E-14 -14.7992 0.10000E+01 0.0000 38 CaF+ 0.11513E-11 -11.9388 0.96298E-12 -12.0164 0.83643E+00 -0.0776 39 CaOH+ 0.80385E-07 -7.0948 0.67237E-07 -7.1724 0.83643E+00 -0.0776 40 CaSO4,aq 0.31547E-16 -16.5010 0.31547E-16 -16.5010 0.10000E+01 0.0000 41 HCl,aq 0.33118E-14 -14.4799 0.33118E-14 -14.4799 0.10000E+01 0.0000 45 HF,aq 0.47860E-12 -12.3200 0.47860E-12 -12.3200 0.10000E+01 0.0000 46 HF2- 0.18134E-18 -18.7415 0.15139E-18 -18.8199 0.83483E+00 -0.0784 48 FeCl+ 0.13864E-16 -16.8581 0.11596E-16 -16.9357 0.83643E+00 -0.0776 51 FeF+ 0.17315E-17 -17.7616 0.14483E-17 -17.8392 0.83643E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15776E-10 -10.8020 0.13195E-10 -10.8796 0.83643E+00 -0.0776 55 HFeO2- 0.35459E-07 -7.4503 0.29602E-07 -7.5287 0.83483E+00 -0.0784 56 FeO+ 0.11056E-16 -16.9564 0.92479E-17 -17.0340 0.83643E+00 -0.0776 58 FeO2- 0.40704E-09 -9.3904 0.33981E-09 -9.4688 0.83483E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 61 KCl,aq 0.57813E-09 -9.2380 0.57813E-09 -9.2380 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.34547E-14 -14.4616 0.28841E-14 -14.5400 0.83483E+00 -0.0784 65 MgCO3,aq 0.11926E-12 -12.9235 0.11926E-12 -12.9235 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10109E-14 -14.9953 0.84557E-15 -15.0728 0.83643E+00 -0.0776 67 MgCl+ 0.46561E-14 -14.3320 0.38945E-14 -14.4095 0.83643E+00 -0.0776 68 MgF+ 0.66414E-15 -15.1777 0.55551E-15 -15.2553 0.83643E+00 -0.0776 69 MgOH+ 0.69269E-10 -10.1595 0.57939E-10 -10.2370 0.83643E+00 -0.0776 71 MnF+ 0.18326E-15 -15.7369 0.15328E-15 -15.8145 0.83643E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47057E-09 -9.3274 0.39360E-09 -9.4049 0.83643E+00 -0.0776 74 MnO2-2 0.20810E-10 -10.6817 0.10765E-10 -10.9680 0.51731E+00 -0.2863 75 HMnO2- 0.21082E-09 -9.6761 0.17600E-09 -9.7545 0.83483E+00 -0.0784 78 MnCl+ 0.17319E-13 -13.7615 0.14486E-13 -13.8390 0.83643E+00 -0.0776 80 NaCl,aq 0.13389E-05 -5.8733 0.13389E-05 -5.8733 0.10000E+01 0.0000 81 NaF,aq 0.36590E-08 -8.4366 0.36590E-08 -8.4366 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92912E-02 -2.0319 0.77425E-02 -2.1111 0.83331E+00 -0.0792 89 HPO3-2 0.16233E-14 -14.7896 0.83975E-15 -15.0759 0.51731E+00 -0.2863 91 H2PO3- 0.15053E-18 -18.8224 0.12566E-18 -18.9008 0.83483E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38327E-10 -10.4165 0.32027E-10 -10.4945 0.83562E+00 -0.0780 94 PO4-3 0.10522E-08 -8.9779 0.25436E-09 -9.5945 0.24176E+00 -0.6166 98 HP2O7-3 0.93422E-18 -18.0295 0.21520E-18 -18.6672 0.23035E+00 -0.6376 99 P2O7-4 0.89962E-17 -17.0459 0.68893E-18 -18.1618 0.76580E-01 -1.1159 100 H2S,aq 0.20804E-07 -7.6818 0.20732E-07 -7.6834 0.99654E+00 -0.0015 101 S2-2 0.29884E-13 -13.5246 0.15459E-13 -13.8108 0.51731E+00 -0.2863 107 SO3-2 0.40469E-17 -17.3929 0.21239E-17 -17.6729 0.52483E+00 -0.2800 108 HSO3- 0.11887E-19 -19.9249 0.99239E-20 -20.0033 0.83483E+00 -0.0784 109 HSO4- 0.12121E-18 -18.9165 0.10148E-18 -18.9936 0.83725E+00 -0.0771 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8884818E-10 -.2220009E-01 -.2233729E+02 0.0000 2 H2O 0.1000000E+01 0.5550506E+02 0.9981941E+06 0.0000 3 Cl- 0.2901028E-03 0.2914423E-03 0.1031446E+02 6.5113 4 SO4-- 0.2722008E-11 -.1865174E-03 -.1788587E+02 8.4038 5 HCO3- 0.3536812E-05 0.1938427E-03 0.1180708E+02 4.5980 6 HS- 0.1076629E-03 0.2942011E-03 0.9712827E+01 6.0808 7 Al+++ 0.9900345E-29 0.5287456E-05 0.1424143E+00 0.7390 8 H4SiO4 0.6959770E-03 0.1347716E-01 0.1293101E+04 -3.1574 9 Ca++ 0.1368126E-06 0.2369868E-06 0.9481369E-02 13.1018 10 Mg++ 0.2140385E-10 0.9403464E-10 0.2282178E-05 9.2942 11 Fe++ 0.5899266E-13 0.3609622E-07 0.2012345E-02 6.7350 12 K+ 0.1574995E-03 0.1582539E-03 0.6177236E+01 6.2467 13 Na+ 0.1998609E-01 0.2243310E-01 0.5148318E+03 8.3494 14 Mn++ 0.1892684E-10 0.2527536E-08 0.1386153E-03 9.2416 15 F- 0.1124562E-05 0.1128222E-05 0.2139654E-01 4.0988 16 HPO4-- 0.4487081E-07 0.4596129E-07 0.4403615E-02 12.6209 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279242E+02 -.1101915E-01 -.8278140E+02 0.0000000E+00 2 H2O -.7167847E+01 0.2755028E+02 -.3471812E+02 0.0000000E+00 3 Cl- 0.1446592E-03 0.1446592E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385980E+00 -.9257903E-04 0.1386906E+00 0.0000000E+00 5 HCO3- 0.9621500E-04 0.9621500E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385446E+00 0.1460285E-03 -.1386906E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2624461E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6689472E-02 0.5205721E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1176298E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4667466E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1791658E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7855026E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113480E-01 0.6265242E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254558E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5600000E-06 0.5600000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2281317E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.7258E-14 Mass of aqueous solution: 0.497224E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0011500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5548 -0.256 281.9 2.450 5.161 73.24 grossular 0.1343 -0.872 60.51 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2605 -0.584 56.41 1.751 1.033 17.24 hedenbergite 0.6756E-01 -1.170 16.76 1.224 0.3068 4.591 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.6 2.450 5.154 97.26 tr.625ac.25prg.125 0.4320E-01 -1.365 36.92 1.567 0.6760 11.88 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338243 g Volume = 2210.781044 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0011500 moles log = -2.9393 Original solution: 1000.0103000 g Original solution / Rock added: 869574.17 (Water/Rock Ratio), log = 5.9393 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3055 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7841E+00 0.9827 0.1006E+01 0.1024E+01 CO2,gas 0.3849E-07 1.0040 0.5045E-07 0.5024E-07 CH4,gas 0.2043E+00 1.0098 0.2693E+00 0.2667E+00 H2,gas 0.1164E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4388E-06 0.9949 0.5699E-06 0.5728E-06 S2,gas 0.4039E-28 1.0000 0.5273E-28 0.5273E-28 CO,gas 0.1566E-12 1.0000 0.2044E-12 0.2044E-12 SO3,gas 0.2276E-47 1.0000 0.2971E-47 0.2971E-47 SO2,gas 0.1346E-26 1.0000 0.1758E-26 0.1758E-26 HF,gas 0.9001E-15 1.0000 0.1175E-14 0.1175E-14 HCl,gas 0.4476E-17 1.0000 0.5844E-17 0.5844E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.66 -9.00 -2.999 0.15361E+05 -7.297 3 CH4,gas 4.54 2.28 -2.27 -0.567 0.38737E+04 -0.570 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.17 -7.94 -3.972 0.13563E+05 -6.244 6 S2,gas -7.34 -37.31 -29.98 -4.612 0.51185E+05 -28.278 7 CO,gas 3.21 -11.17 -14.39 -4.427 0.24568E+05 -12.689 8 SO3,gas 17.12 -32.10 -49.23 -12.307 0.84052E+05 -47.527 9 SO2,gas 0.83 -27.62 -28.45 -7.588 0.48584E+05 -26.755 10 HF,gas 0.47 -16.16 -16.63 -8.314 0.28393E+05 -14.930 11 HCl,gas 5.19 -13.74 -18.93 -9.466 0.32326E+05 -17.233 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 34 apatite-F -34.30 -34.31 -0.01 -0.001 0.13564E+02 38 aragonite 0.97 -2.55 -3.52 -1.174 0.60120E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.55 -3.37 -1.122 0.57477E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.69 -3.59 -1.025 0.61268E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.69 -3.14 -0.898 0.53691E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.09 -4.85 -1.141 0.82773E+04 146 pyrrhotite -4.26 -7.44 -3.18 -1.059 0.54265E+04 147 pyrrhotiteFe0.875 -6.02 -8.84 -2.82 -1.037 0.48137E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47126E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.44 -3.03 -1.009 0.51693E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.93 -3.95 -1.318 0.67512E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0011500 MOLES New total amount of reactant added: 0.0011900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0011900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133471E-01 Osmotic coef. = 3.9736 True ionic strength = .2015266E-01 Chg. balance for total moles = -.8663E-10 Max. difference allowed = 0.1449E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88855E-10 -10.0513 0.74629E-10 -10.1271 0.83990E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29058E-03 -3.5367 0.24258E-03 -3.6151 0.83482E+00 -0.0784 4 SO4-- 0.27713E-11 -11.5573 0.14367E-11 -11.8426 0.51840E+00 -0.2853 5 HCO3- 0.36429E-05 -5.4386 0.30456E-05 -5.5163 0.83605E+00 -0.0778 6 HS- 0.10962E-03 -3.9601 0.91527E-04 -4.0385 0.83494E+00 -0.0783 7 Al+++ 0.99031E-29 -29.0042 0.22788E-29 -29.6423 0.23011E+00 -0.6381 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13684E-06 -6.8638 0.70412E-07 -7.1524 0.51457E+00 -0.2886 10 Mg++ 0.21408E-10 -10.6694 0.10965E-10 -10.9600 0.51221E+00 -0.2906 11 Fe++ 0.59003E-13 -13.2291 0.30255E-13 -13.5192 0.51277E+00 -0.2901 12 K+ 0.15751E-03 -3.8027 0.13172E-03 -3.8804 0.83625E+00 -0.0777 13 Na+ 0.19988E-01 -1.6992 0.16683E-01 -1.7777 0.83467E+00 -0.0785 14 Mn++ 0.18930E-10 -10.7228 0.97150E-11 -11.0126 0.51320E+00 -0.2897 15 F- 0.11567E-05 -5.9368 0.96363E-06 -6.0161 0.83309E+00 -0.0793 16 HPO4-- 0.44865E-07 -7.3481 0.23261E-07 -7.6334 0.51847E+00 -0.2853 18 HSiO3- 0.10431E-01 -1.9817 0.87079E-02 -2.0601 0.83482E+00 -0.0784 19 Ca(HSiO3)+ 0.16694E-07 -7.7774 0.13964E-07 -7.8550 0.83643E+00 -0.0776 20 Mg(HSiO3)+ 0.32354E-11 -11.4901 0.27062E-11 -11.5676 0.83643E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66547E-16 -16.1769 0.55662E-16 -16.2544 0.83643E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52869E-05 -5.2768 0.44056E-05 -5.3560 0.83331E+00 -0.0792 26 CH4,aq 0.18913E-03 -3.7232 0.18848E-03 -3.7247 0.99654E+00 -0.0015 27 C2H6,aq 0.52614E-12 -12.2789 0.52432E-12 -12.2804 0.99654E+00 -0.0015 28 C3H8,aq 0.33792E-19 -19.4712 0.33675E-19 -19.4727 0.99654E+00 -0.0015 30 ethanol,aq 0.19311E-19 -19.7142 0.19245E-19 -19.7157 0.99654E+00 -0.0015 31 CO,aq 0.14131E-15 -15.8498 0.14131E-15 -15.8498 0.10000E+01 0.0000 32 CO2,aq 0.48736E-09 -9.3122 0.48568E-09 -9.3137 0.99654E+00 -0.0015 33 CO3-2 0.68909E-05 -5.1617 0.35646E-05 -5.4480 0.51729E+00 -0.2863 34 CaCO3,aq 0.31472E-08 -8.5021 0.31472E-08 -8.5021 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.65446E-11 -11.1841 0.54741E-11 -11.2617 0.83643E+00 -0.0776 36 CaCl+ 0.33047E-10 -10.4809 0.27642E-10 -10.5584 0.83643E+00 -0.0776 37 CaCl2,aq 0.15930E-14 -14.7978 0.15930E-14 -14.7978 0.10000E+01 0.0000 38 CaF+ 0.11844E-11 -11.9265 0.99064E-12 -12.0041 0.83643E+00 -0.0776 39 CaOH+ 0.80392E-07 -7.0948 0.67242E-07 -7.1724 0.83643E+00 -0.0776 40 CaSO4,aq 0.32123E-16 -16.4932 0.32123E-16 -16.4932 0.10000E+01 0.0000 41 HCl,aq 0.33174E-14 -14.4792 0.33174E-14 -14.4792 0.10000E+01 0.0000 45 HF,aq 0.49231E-12 -12.3078 0.49231E-12 -12.3078 0.10000E+01 0.0000 46 HF2- 0.19186E-18 -18.7170 0.16017E-18 -18.7954 0.83482E+00 -0.0784 48 FeCl+ 0.13889E-16 -16.8573 0.11617E-16 -16.9349 0.83643E+00 -0.0776 51 FeF+ 0.17812E-17 -17.7493 0.14898E-17 -17.8269 0.83643E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15777E-10 -10.8020 0.13196E-10 -10.8795 0.83643E+00 -0.0776 55 HFeO2- 0.35457E-07 -7.4503 0.29600E-07 -7.5287 0.83482E+00 -0.0784 56 FeO+ 0.11057E-16 -16.9564 0.92486E-17 -17.0339 0.83643E+00 -0.0776 58 FeO2- 0.40701E-09 -9.3904 0.33978E-09 -9.4688 0.83482E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 61 KCl,aq 0.57911E-09 -9.2372 0.57911E-09 -9.2372 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.35175E-14 -14.4538 0.29365E-14 -14.5322 0.83482E+00 -0.0784 65 MgCO3,aq 0.12285E-12 -12.9106 0.12285E-12 -12.9106 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10414E-14 -14.9824 0.87106E-15 -15.0600 0.83643E+00 -0.0776 67 MgCl+ 0.46644E-14 -14.3312 0.39014E-14 -14.4088 0.83643E+00 -0.0776 68 MgF+ 0.68321E-15 -15.1654 0.57146E-15 -15.2430 0.83643E+00 -0.0776 69 MgOH+ 0.69275E-10 -10.1594 0.57944E-10 -10.2370 0.83643E+00 -0.0776 71 MnF+ 0.18852E-15 -15.7246 0.15768E-15 -15.8022 0.83643E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47061E-09 -9.3273 0.39364E-09 -9.4049 0.83643E+00 -0.0776 74 MnO2-2 0.20808E-10 -10.6818 0.10764E-10 -10.9680 0.51729E+00 -0.2863 75 HMnO2- 0.21081E-09 -9.6761 0.17599E-09 -9.7545 0.83482E+00 -0.0784 78 MnCl+ 0.17350E-13 -13.7607 0.14512E-13 -13.8383 0.83643E+00 -0.0776 80 NaCl,aq 0.13412E-05 -5.8725 0.13412E-05 -5.8725 0.10000E+01 0.0000 81 NaF,aq 0.37638E-08 -8.4244 0.37638E-08 -8.4244 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92906E-02 -2.0320 0.77419E-02 -2.1112 0.83331E+00 -0.0792 89 HPO3-2 0.16231E-14 -14.7897 0.83962E-15 -15.0759 0.51729E+00 -0.2863 91 H2PO3- 0.15052E-18 -18.8224 0.12565E-18 -18.9008 0.83482E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38324E-10 -10.4165 0.32024E-10 -10.4945 0.83562E+00 -0.0780 94 PO4-3 0.10520E-08 -8.9780 0.25431E-09 -9.5946 0.24174E+00 -0.6166 98 HP2O7-3 0.93407E-18 -18.0296 0.21515E-18 -18.6673 0.23034E+00 -0.6376 99 P2O7-4 0.89944E-17 -17.0460 0.68873E-18 -18.1620 0.76573E-01 -1.1159 100 H2S,aq 0.21184E-07 -7.6740 0.21111E-07 -7.6755 0.99654E+00 -0.0015 101 S2-2 0.30981E-13 -13.5089 0.16026E-13 -13.7952 0.51729E+00 -0.2863 107 SO3-2 0.41203E-17 -17.3851 0.21624E-17 -17.6651 0.52481E+00 -0.2800 108 HSO3- 0.12103E-19 -19.9171 0.10104E-19 -19.9955 0.83482E+00 -0.0784 109 HSO4- 0.12341E-18 -18.9086 0.10333E-18 -18.9858 0.83725E+00 -0.0771 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8885532E-10 -.2219894E-01 -.2233612E+02 0.0000 2 H2O 0.1000000E+01 0.5550507E+02 0.9981940E+06 0.0000 3 Cl- 0.2905756E-03 0.2919174E-03 0.1033127E+02 6.5119 4 SO4-- 0.2771347E-11 -.1920371E-03 -.1841517E+02 8.4115 5 HCO3- 0.3642889E-05 0.1996689E-03 0.1216196E+02 4.6108 6 HS- 0.1096206E-03 0.3016789E-03 0.9959700E+01 6.0886 7 Al+++ 0.9903099E-29 0.5287095E-05 0.1424046E+00 0.7390 8 H4SiO4 0.6959770E-03 0.1347645E-01 0.1293032E+04 -3.1574 9 Ca++ 0.1368364E-06 0.2371105E-06 0.9486316E-02 13.1018 10 Mg++ 0.2140757E-10 0.9404702E-10 0.2282478E-05 9.2942 11 Fe++ 0.5900291E-13 0.3609376E-07 0.2012208E-02 6.7350 12 K+ 0.1575122E-03 0.1582665E-03 0.6177728E+01 6.2467 13 Na+ 0.1998770E-01 0.2243471E-01 0.5148686E+03 8.3494 14 Mn++ 0.1893020E-10 0.2527570E-08 0.1386171E-03 9.2416 15 F- 0.1156690E-05 0.1160456E-05 0.2200783E-01 4.1110 16 HPO4-- 0.4486519E-07 0.4595548E-07 0.4403058E-02 12.6208 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279242E+02 -.1101860E-01 -.8278140E+02 0.0000000E+00 2 H2O -.7167814E+01 0.2755032E+02 -.3471813E+02 0.0000000E+00 3 Cl- 0.1448952E-03 0.1448952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385982E+00 -.9531891E-04 0.1386935E+00 0.0000000E+00 5 HCO3- 0.9910700E-04 0.9910700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385438E+00 0.1497404E-03 -.1386935E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2624286E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6689128E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1176914E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4668088E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1791538E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7855666E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113562E-01 0.6265241E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254576E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5760000E-06 0.5760000E-06 0.0000000E+00 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2281032E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1454E-13 Mass of aqueous solution: 0.497225E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0011900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5548 -0.256 281.9 2.450 5.161 73.25 grossular 0.1343 -0.872 60.51 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2604 -0.584 56.40 1.751 1.032 17.24 hedenbergite 0.6754E-01 -1.170 16.76 1.224 0.3068 4.589 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.5 2.450 5.154 97.25 tr.625ac.25prg.125 0.4322E-01 -1.364 36.95 1.568 0.6764 11.89 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338256 g Volume = 2210.781155 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0011900 moles log = -2.9245 Original solution: 1000.0103000 g Original solution / Rock added: 840344.79 (Water/Rock Ratio), log = 5.9245 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3137 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7793E+00 0.9827 0.1006E+01 0.1024E+01 CO2,gas 0.3940E-07 1.0039 0.5196E-07 0.5176E-07 CH4,gas 0.2092E+00 1.0097 0.2774E+00 0.2748E+00 H2,gas 0.1157E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4440E-06 0.9949 0.5803E-06 0.5833E-06 S2,gas 0.4162E-28 1.0000 0.5467E-28 0.5467E-28 CO,gas 0.1603E-12 1.0000 0.2106E-12 0.2106E-12 SO3,gas 0.2303E-47 1.0000 0.3025E-47 0.3025E-47 SO2,gas 0.1363E-26 1.0000 0.1790E-26 0.1790E-26 HF,gas 0.9202E-15 1.0000 0.1209E-14 0.1209E-14 HCl,gas 0.4456E-17 1.0000 0.5854E-17 0.5854E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.73753E+01 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.64 -8.98 -2.994 0.15339E+05 -7.284 3 CH4,gas 4.54 2.29 -2.26 -0.564 0.38518E+04 -0.557 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.17 -7.94 -3.968 0.13549E+05 -6.236 6 S2,gas -7.34 -37.30 -29.96 -4.609 0.51158E+05 -28.262 7 CO,gas 3.21 -11.16 -14.38 -4.423 0.24546E+05 -12.677 8 SO3,gas 17.12 -32.10 -49.22 -12.305 0.84039E+05 -47.519 9 SO2,gas 0.83 -27.61 -28.45 -7.586 0.48571E+05 -26.747 10 HF,gas 0.47 -16.14 -16.62 -8.308 0.28372E+05 -14.918 11 HCl,gas 5.19 -13.74 -18.93 -9.466 0.32325E+05 -17.233 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.54 -3.51 -1.169 0.59900E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.54 -3.35 -1.118 0.57258E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.68 -3.58 -1.022 0.61049E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.68 -3.13 -0.895 0.53471E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.08 -4.83 -1.137 0.82505E+04 146 pyrrhotite -4.26 -7.43 -3.17 -1.057 0.54131E+04 147 pyrrhotiteFe0.875 -6.02 -8.83 -2.81 -1.034 0.48003E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.43 -3.02 -1.007 0.51559E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.92 -3.95 -1.315 0.67378E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0011900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133470E-01 Osmotic coef. = 3.9736 True ionic strength = .2015265E-01 Chg. balance for total moles = -.8663E-10 Max. difference allowed = 0.1449E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88855E-10 -10.0513 0.74629E-10 -10.1271 0.83990E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29058E-03 -3.5367 0.24258E-03 -3.6151 0.83482E+00 -0.0784 4 SO4-- 0.27713E-11 -11.5573 0.14367E-11 -11.8426 0.51840E+00 -0.2853 5 HCO3- 0.36429E-05 -5.4386 0.30456E-05 -5.5163 0.83605E+00 -0.0778 6 HS- 0.10962E-03 -3.9601 0.91527E-04 -4.0385 0.83494E+00 -0.0783 7 Al+++ 0.99031E-29 -29.0042 0.22788E-29 -29.6423 0.23011E+00 -0.6381 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13684E-06 -6.8638 0.70412E-07 -7.1524 0.51457E+00 -0.2886 10 Mg++ 0.21408E-10 -10.6694 0.10965E-10 -10.9600 0.51221E+00 -0.2906 11 Fe++ 0.59003E-13 -13.2291 0.30255E-13 -13.5192 0.51277E+00 -0.2901 12 K+ 0.15751E-03 -3.8027 0.13172E-03 -3.8804 0.83625E+00 -0.0777 13 Na+ 0.19988E-01 -1.6992 0.16683E-01 -1.7777 0.83467E+00 -0.0785 14 Mn++ 0.18930E-10 -10.7228 0.97149E-11 -11.0126 0.51320E+00 -0.2897 15 F- 0.11452E-05 -5.9411 0.95409E-06 -6.0204 0.83309E+00 -0.0793 16 HPO4-- 0.44865E-07 -7.3481 0.23261E-07 -7.6334 0.51847E+00 -0.2853 18 HSiO3- 0.10431E-01 -1.9817 0.87079E-02 -2.0601 0.83482E+00 -0.0784 19 Ca(HSiO3)+ 0.16694E-07 -7.7774 0.13964E-07 -7.8550 0.83643E+00 -0.0776 20 Mg(HSiO3)+ 0.32354E-11 -11.4901 0.27062E-11 -11.5676 0.83643E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66547E-16 -16.1769 0.55662E-16 -16.2544 0.83643E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52869E-05 -5.2768 0.44056E-05 -5.3560 0.83331E+00 -0.0792 26 CH4,aq 0.18913E-03 -3.7232 0.18848E-03 -3.7247 0.99654E+00 -0.0015 27 C2H6,aq 0.52614E-12 -12.2789 0.52432E-12 -12.2804 0.99654E+00 -0.0015 28 C3H8,aq 0.33792E-19 -19.4712 0.33675E-19 -19.4727 0.99654E+00 -0.0015 30 ethanol,aq 0.19311E-19 -19.7142 0.19245E-19 -19.7157 0.99654E+00 -0.0015 31 CO,aq 0.14131E-15 -15.8498 0.14131E-15 -15.8498 0.10000E+01 0.0000 32 CO2,aq 0.48736E-09 -9.3122 0.48568E-09 -9.3137 0.99654E+00 -0.0015 33 CO3-2 0.68909E-05 -5.1617 0.35646E-05 -5.4480 0.51729E+00 -0.2863 34 CaCO3,aq 0.31472E-08 -8.5021 0.31472E-08 -8.5021 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.65446E-11 -11.1841 0.54741E-11 -11.2617 0.83643E+00 -0.0776 36 CaCl+ 0.33047E-10 -10.4809 0.27642E-10 -10.5584 0.83643E+00 -0.0776 37 CaCl2,aq 0.15930E-14 -14.7978 0.15930E-14 -14.7978 0.10000E+01 0.0000 38 CaF+ 0.11726E-11 -11.9308 0.98083E-12 -12.0084 0.83643E+00 -0.0776 39 CaOH+ 0.80392E-07 -7.0948 0.67242E-07 -7.1724 0.83643E+00 -0.0776 40 CaSO4,aq 0.32123E-16 -16.4932 0.32123E-16 -16.4932 0.10000E+01 0.0000 41 HCl,aq 0.33174E-14 -14.4792 0.33174E-14 -14.4792 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18808E-18 -18.7256 0.15702E-18 -18.8041 0.83482E+00 -0.0784 48 FeCl+ 0.13889E-16 -16.8573 0.11617E-16 -16.9349 0.83643E+00 -0.0776 51 FeF+ 0.17636E-17 -17.7536 0.14751E-17 -17.8312 0.83643E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15777E-10 -10.8020 0.13196E-10 -10.8795 0.83643E+00 -0.0776 55 HFeO2- 0.35457E-07 -7.4503 0.29600E-07 -7.5287 0.83482E+00 -0.0784 56 FeO+ 0.11057E-16 -16.9564 0.92486E-17 -17.0339 0.83643E+00 -0.0776 58 FeO2- 0.40701E-09 -9.3904 0.33978E-09 -9.4688 0.83482E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 61 KCl,aq 0.57911E-09 -9.2372 0.57911E-09 -9.2372 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.35175E-14 -14.4538 0.29365E-14 -14.5322 0.83482E+00 -0.0784 65 MgCO3,aq 0.12285E-12 -12.9106 0.12285E-12 -12.9106 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10414E-14 -14.9824 0.87106E-15 -15.0600 0.83643E+00 -0.0776 67 MgCl+ 0.46644E-14 -14.3312 0.39014E-14 -14.4088 0.83643E+00 -0.0776 68 MgF+ 0.67645E-15 -15.1698 0.56580E-15 -15.2473 0.83643E+00 -0.0776 69 MgOH+ 0.69275E-10 -10.1594 0.57944E-10 -10.2370 0.83643E+00 -0.0776 71 MnF+ 0.18665E-15 -15.7290 0.15612E-15 -15.8065 0.83643E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47061E-09 -9.3273 0.39364E-09 -9.4049 0.83643E+00 -0.0776 74 MnO2-2 0.20808E-10 -10.6818 0.10764E-10 -10.9680 0.51729E+00 -0.2863 75 HMnO2- 0.21081E-09 -9.6761 0.17599E-09 -9.7545 0.83482E+00 -0.0784 78 MnCl+ 0.17350E-13 -13.7607 0.14512E-13 -13.8383 0.83643E+00 -0.0776 80 NaCl,aq 0.13412E-05 -5.8725 0.13412E-05 -5.8725 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92906E-02 -2.0320 0.77419E-02 -2.1112 0.83331E+00 -0.0792 89 HPO3-2 0.16231E-14 -14.7897 0.83962E-15 -15.0759 0.51729E+00 -0.2863 91 H2PO3- 0.15052E-18 -18.8224 0.12565E-18 -18.9008 0.83482E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38324E-10 -10.4165 0.32024E-10 -10.4945 0.83562E+00 -0.0780 94 PO4-3 0.10520E-08 -8.9780 0.25431E-09 -9.5946 0.24174E+00 -0.6166 98 HP2O7-3 0.93407E-18 -18.0296 0.21515E-18 -18.6673 0.23034E+00 -0.6376 99 P2O7-4 0.89944E-17 -17.0460 0.68873E-18 -18.1620 0.76573E-01 -1.1159 100 H2S,aq 0.21184E-07 -7.6740 0.21111E-07 -7.6755 0.99654E+00 -0.0015 101 S2-2 0.30981E-13 -13.5089 0.16026E-13 -13.7952 0.51729E+00 -0.2863 107 SO3-2 0.41203E-17 -17.3851 0.21624E-17 -17.6651 0.52481E+00 -0.2800 108 HSO3- 0.12103E-19 -19.9171 0.10104E-19 -19.9955 0.83482E+00 -0.0784 109 HSO4- 0.12341E-18 -18.9086 0.10333E-18 -18.9858 0.83725E+00 -0.0771 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8885529E-10 -.2219895E-01 -.2233613E+02 0.0000 2 H2O 0.1000000E+01 0.5550507E+02 0.9981940E+06 0.0000 3 Cl- 0.2905756E-03 0.2919174E-03 0.1033127E+02 6.5119 4 SO4-- 0.2771347E-11 -.1920371E-03 -.1841517E+02 8.4115 5 HCO3- 0.3642890E-05 0.1996689E-03 0.1216196E+02 4.6108 6 HS- 0.1096206E-03 0.3016789E-03 0.9959699E+01 6.0886 7 Al+++ 0.9903089E-29 0.5287096E-05 0.1424046E+00 0.7390 8 H4SiO4 0.6959770E-03 0.1347645E-01 0.1293032E+04 -3.1574 9 Ca++ 0.1368363E-06 0.2371103E-06 0.9486310E-02 13.1018 10 Mg++ 0.2140756E-10 0.9404524E-10 0.2282434E-05 9.2942 11 Fe++ 0.5900287E-13 0.3609377E-07 0.2012208E-02 6.7350 12 K+ 0.1575121E-03 0.1582665E-03 0.6177726E+01 6.2467 13 Na+ 0.1998769E-01 0.2243470E-01 0.5148685E+03 8.3494 14 Mn++ 0.1893019E-10 0.2527569E-08 0.1386171E-03 9.2416 15 F- 0.1145243E-05 0.1148971E-05 0.2179003E-01 4.1067 16 HPO4-- 0.4486521E-07 0.4595551E-07 0.4403060E-02 12.6208 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279242E+02 -.1101860E-01 -.8278140E+02 0.0000000E+00 2 H2O -.7167814E+01 0.2755032E+02 -.3471813E+02 0.0000000E+00 3 Cl- 0.1448952E-03 0.1448952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385982E+00 -.9531891E-04 0.1386935E+00 0.0000000E+00 5 HCO3- 0.9910700E-04 0.9910700E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385438E+00 0.1497404E-03 -.1386935E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2624286E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6689129E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1176913E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4667999E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1791539E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7855663E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113562E-01 0.6265241E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254576E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5760000E-06 0.5702998E-06 0.5700236E-08 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2281033E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.3636E-14 Mass of aqueous solution: 0.497225E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0011900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5548 -0.256 281.9 2.450 5.161 73.25 grossular 0.1343 -0.872 60.51 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2604 -0.584 56.40 1.751 1.032 17.24 hedenbergite 0.6754E-01 -1.170 16.76 1.224 0.3068 4.589 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.5 2.450 5.154 97.25 tr.625ac.25prg.125 0.4322E-01 -1.364 36.95 1.568 0.6764 11.89 apatite-F 0.5700E-08 -8.244 0.2875E-05 -5.541 0.5263E-07 0.8981E-06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338256 g Volume = 2210.781154 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0011900 moles log = -2.9245 Original solution: 1000.0103000 g Original solution / Rock added: 840344.79 (Water/Rock Ratio), log = 5.9245 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3137 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7793E+00 0.9827 0.1006E+01 0.1024E+01 CO2,gas 0.3940E-07 1.0039 0.5196E-07 0.5176E-07 CH4,gas 0.2092E+00 1.0097 0.2774E+00 0.2748E+00 H2,gas 0.1157E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4440E-06 0.9949 0.5803E-06 0.5833E-06 S2,gas 0.4162E-28 1.0000 0.5467E-28 0.5467E-28 CO,gas 0.1603E-12 1.0000 0.2106E-12 0.2106E-12 SO3,gas 0.2303E-47 1.0000 0.3025E-47 0.3025E-47 SO2,gas 0.1363E-26 1.0000 0.1790E-26 0.1790E-26 HF,gas 0.9111E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4456E-17 1.0000 0.5854E-17 0.5854E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.64 -8.98 -2.994 0.15339E+05 -7.284 3 CH4,gas 4.54 2.29 -2.26 -0.564 0.38518E+04 -0.557 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.17 -7.94 -3.968 0.13549E+05 -6.236 6 S2,gas -7.34 -37.30 -29.96 -4.609 0.51158E+05 -28.262 7 CO,gas 3.21 -11.16 -14.38 -4.423 0.24546E+05 -12.677 8 SO3,gas 17.12 -32.10 -49.22 -12.305 0.84039E+05 -47.519 9 SO2,gas 0.83 -27.61 -28.45 -7.586 0.48571E+05 -26.747 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.74 -18.93 -9.466 0.32325E+05 -17.233 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.54 -3.51 -1.169 0.59900E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.54 -3.35 -1.118 0.57258E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.68 -3.58 -1.022 0.61049E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.68 -3.13 -0.895 0.53471E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.08 -4.83 -1.137 0.82505E+04 146 pyrrhotite -4.26 -7.43 -3.17 -1.057 0.54131E+04 147 pyrrhotiteFe0.875 -6.02 -8.83 -2.81 -1.034 0.48003E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.43 -3.02 -1.007 0.51559E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.92 -3.95 -1.315 0.67378E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0011900 MOLES New total amount of reactant added: 0.0012300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0012300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1133135E-01 Osmotic coef. = -2.0731 True ionic strength = .2015445E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.1451E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88862E-10 -10.0513 0.74635E-10 -10.1271 0.83989E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29105E-03 -3.5360 0.24297E-03 -3.6144 0.83482E+00 -0.0784 4 SO4-- 0.28207E-11 -11.5496 0.14622E-11 -11.8350 0.51839E+00 -0.2853 5 HCO3- 0.37490E-05 -5.4261 0.31343E-05 -5.5039 0.83604E+00 -0.0778 6 HS- 0.11158E-03 -3.9524 0.93161E-04 -4.0308 0.83494E+00 -0.0783 7 Al+++ 0.99058E-29 -29.0041 0.22793E-29 -29.6422 0.23010E+00 -0.6381 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13686E-06 -6.8637 0.70423E-07 -7.1523 0.51456E+00 -0.2886 10 Mg++ 0.21411E-10 -10.6694 0.10967E-10 -10.9599 0.51219E+00 -0.2906 11 Fe++ 0.59013E-13 -13.2291 0.30259E-13 -13.5191 0.51276E+00 -0.2901 12 K+ 0.15752E-03 -3.8027 0.13173E-03 -3.8803 0.83624E+00 -0.0777 13 Na+ 0.19989E-01 -1.6992 0.16684E-01 -1.7777 0.83466E+00 -0.0785 14 Mn++ 0.18934E-10 -10.7228 0.97164E-11 -11.0125 0.51319E+00 -0.2897 15 F- 0.11452E-05 -5.9411 0.95402E-06 -6.0204 0.83309E+00 -0.0793 16 HPO4-- 0.44860E-07 -7.3481 0.23258E-07 -7.6334 0.51846E+00 -0.2853 18 HSiO3- 0.10430E-01 -1.9817 0.87072E-02 -2.0601 0.83482E+00 -0.0784 19 Ca(HSiO3)+ 0.16696E-07 -7.7774 0.13965E-07 -7.8550 0.83642E+00 -0.0776 20 Mg(HSiO3)+ 0.32357E-11 -11.4900 0.27064E-11 -11.5676 0.83642E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66553E-16 -16.1768 0.55666E-16 -16.2544 0.83642E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52866E-05 -5.2768 0.44053E-05 -5.3560 0.83330E+00 -0.0792 26 CH4,aq 0.19465E-03 -3.7107 0.19398E-03 -3.7122 0.99654E+00 -0.0015 27 C2H6,aq 0.55730E-12 -12.2539 0.55538E-12 -12.2554 0.99654E+00 -0.0015 28 C3H8,aq 0.36838E-19 -19.4337 0.36711E-19 -19.4352 0.99654E+00 -0.0015 30 ethanol,aq 0.20455E-19 -19.6892 0.20384E-19 -19.6907 0.99654E+00 -0.0015 31 CO,aq 0.14544E-15 -15.8373 0.14544E-15 -15.8373 0.10000E+01 0.0000 32 CO2,aq 0.50158E-09 -9.2997 0.49985E-09 -9.3012 0.99654E+00 -0.0015 33 CO3-2 0.70911E-05 -5.1493 0.36681E-05 -5.4356 0.51728E+00 -0.2863 34 CaCO3,aq 0.32390E-08 -8.4896 0.32390E-08 -8.4896 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.67361E-11 -11.1716 0.56342E-11 -11.2492 0.83642E+00 -0.0776 36 CaCl+ 0.33106E-10 -10.4801 0.27691E-10 -10.5577 0.83642E+00 -0.0776 37 CaCl2,aq 0.15984E-14 -14.7963 0.15984E-14 -14.7963 0.10000E+01 0.0000 38 CaF+ 0.11727E-11 -11.9308 0.98091E-12 -12.0084 0.83642E+00 -0.0776 39 CaOH+ 0.80398E-07 -7.0948 0.67247E-07 -7.1723 0.83642E+00 -0.0776 40 CaSO4,aq 0.32699E-16 -16.4855 0.32699E-16 -16.4855 0.10000E+01 0.0000 41 HCl,aq 0.33230E-14 -14.4785 0.33230E-14 -14.4785 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18807E-18 -18.7257 0.15700E-18 -18.8041 0.83482E+00 -0.0784 48 FeCl+ 0.13913E-16 -16.8566 0.11637E-16 -16.9341 0.83642E+00 -0.0776 51 FeF+ 0.17637E-17 -17.7536 0.14752E-17 -17.8311 0.83642E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15778E-10 -10.8019 0.13197E-10 -10.8795 0.83642E+00 -0.0776 55 HFeO2- 0.35454E-07 -7.4503 0.29598E-07 -7.5287 0.83482E+00 -0.0784 56 FeO+ 0.11058E-16 -16.9563 0.92492E-17 -17.0339 0.83642E+00 -0.0776 58 FeO2- 0.40699E-09 -9.3904 0.33976E-09 -9.4688 0.83482E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 61 KCl,aq 0.58009E-09 -9.2365 0.58009E-09 -9.2365 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.35803E-14 -14.4461 0.29889E-14 -14.5245 0.83482E+00 -0.0784 65 MgCO3,aq 0.12643E-12 -12.8981 0.12643E-12 -12.8981 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10719E-14 -14.9699 0.89654E-15 -15.0474 0.83642E+00 -0.0776 67 MgCl+ 0.46726E-14 -14.3304 0.39083E-14 -14.4080 0.83642E+00 -0.0776 68 MgF+ 0.67651E-15 -15.1697 0.56585E-15 -15.2473 0.83642E+00 -0.0776 69 MgOH+ 0.69280E-10 -10.1594 0.57948E-10 -10.2370 0.83642E+00 -0.0776 71 MnF+ 0.18667E-15 -15.7289 0.15613E-15 -15.8065 0.83642E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47065E-09 -9.3273 0.39367E-09 -9.4049 0.83642E+00 -0.0776 74 MnO2-2 0.20805E-10 -10.6818 0.10762E-10 -10.9681 0.51728E+00 -0.2863 75 HMnO2- 0.21080E-09 -9.6761 0.17598E-09 -9.7545 0.83482E+00 -0.0784 78 MnCl+ 0.17381E-13 -13.7599 0.14538E-13 -13.8375 0.83642E+00 -0.0776 80 NaCl,aq 0.13434E-05 -5.8718 0.13434E-05 -5.8718 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92899E-02 -2.0320 0.77413E-02 -2.1112 0.83330E+00 -0.0792 89 HPO3-2 0.16229E-14 -14.7897 0.83950E-15 -15.0760 0.51728E+00 -0.2863 91 H2PO3- 0.15051E-18 -18.8224 0.12564E-18 -18.9009 0.83482E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38321E-10 -10.4166 0.32022E-10 -10.4946 0.83561E+00 -0.0780 94 PO4-3 0.10518E-08 -8.9781 0.25425E-09 -9.5947 0.24173E+00 -0.6167 98 HP2O7-3 0.93391E-18 -18.0297 0.21511E-18 -18.6673 0.23033E+00 -0.6377 99 P2O7-4 0.89926E-17 -17.0461 0.68852E-18 -18.1621 0.76566E-01 -1.1160 100 H2S,aq 0.21564E-07 -7.6663 0.21489E-07 -7.6678 0.99654E+00 -0.0015 101 S2-2 0.32098E-13 -13.4935 0.16603E-13 -13.7798 0.51728E+00 -0.2863 107 SO3-2 0.41936E-17 -17.3774 0.22008E-17 -17.6574 0.52480E+00 -0.2800 108 HSO3- 0.12320E-19 -19.9094 0.10285E-19 -19.9878 0.83482E+00 -0.0784 109 HSO4- 0.12562E-18 -18.9010 0.10517E-18 -18.9781 0.83724E+00 -0.0771 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8886235E-10 -.2219781E-01 -.2233498E+02 0.0000 2 H2O 0.1000000E+01 0.5550507E+02 0.9981940E+06 0.0000 3 Cl- 0.2910484E-03 0.2923924E-03 0.1034808E+02 6.5126 4 SO4-- 0.2820682E-11 -.1975568E-03 -.1894448E+02 8.4191 5 HCO3- 0.3748957E-05 0.2054950E-03 0.1251683E+02 4.6232 6 HS- 0.1115784E-03 0.3091567E-03 0.1020657E+02 6.0963 7 Al+++ 0.9905814E-29 0.5286740E-05 0.1423950E+00 0.7390 8 H4SiO4 0.6959769E-03 0.1347575E-01 0.1292964E+04 -3.1574 9 Ca++ 0.1368597E-06 0.2372336E-06 0.9491242E-02 13.1018 10 Mg++ 0.2141124E-10 0.9405941E-10 0.2282778E-05 9.2942 11 Fe++ 0.5901301E-13 0.3609134E-07 0.2012072E-02 6.7350 12 K+ 0.1575246E-03 0.1582790E-03 0.6178214E+01 6.2467 13 Na+ 0.1998928E-01 0.2243629E-01 0.5149049E+03 8.3494 14 Mn++ 0.1893351E-10 0.2527603E-08 0.1386189E-03 9.2416 15 F- 0.1145166E-05 0.1148894E-05 0.2178856E-01 4.1066 16 HPO4-- 0.4485965E-07 0.4594976E-07 0.4402509E-02 12.6207 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279241E+02 -.1101805E-01 -.8278140E+02 0.0000000E+00 2 H2O -.7167782E+01 0.2755036E+02 -.3471814E+02 0.0000000E+00 3 Cl- 0.1451312E-03 0.1451312E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385984E+00 -.9805881E-04 0.1386965E+00 0.0000000E+00 5 HCO3- 0.1019990E-03 0.1019990E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385430E+00 0.1534523E-03 -.1386965E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2624113E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6688788E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1177527E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4668710E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1791421E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7856296E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113642E-01 0.6265241E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254595E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5920000E-06 0.5702622E-06 0.2173782E-07 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2280751E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.2519E-14 Mass of aqueous solution: 0.497226E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0012300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5548 -0.256 281.9 2.450 5.161 73.25 grossular 0.1343 -0.872 60.51 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.2174E-07 -7.663 0.1096E-04 -4.960 0.2007E-06 0.3425E-05 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2603 -0.584 56.38 1.751 1.032 17.23 hedenbergite 0.6752E-01 -1.171 16.75 1.224 0.3067 4.588 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.5 2.450 5.154 97.25 tr.625ac.25prg.125 0.4325E-01 -1.364 36.97 1.568 0.6768 11.90 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338269 g Volume = 2210.781265 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0012300 moles log = -2.9101 Original solution: 1000.0103000 g Original solution / Rock added: 813016.50 (Water/Rock Ratio), log = 5.9101 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3218 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7745E+00 0.9826 0.1006E+01 0.1024E+01 CO2,gas 0.4031E-07 1.0038 0.5348E-07 0.5327E-07 CH4,gas 0.2140E+00 1.0096 0.2855E+00 0.2828E+00 H2,gas 0.1150E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4492E-06 0.9949 0.5907E-06 0.5938E-06 S2,gas 0.4286E-28 1.0000 0.5665E-28 0.5665E-28 CO,gas 0.1640E-12 1.0000 0.2167E-12 0.2167E-12 SO3,gas 0.2330E-47 1.0000 0.3080E-47 0.3080E-47 SO2,gas 0.1378E-26 1.0000 0.1822E-26 0.1822E-26 HF,gas 0.9055E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4436E-17 1.0000 0.5864E-17 0.5864E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.63 -8.97 -2.990 0.15317E+05 -7.272 3 CH4,gas 4.54 2.30 -2.24 -0.561 0.38304E+04 -0.544 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.16 -7.93 -3.964 0.13536E+05 -6.229 6 S2,gas -7.34 -37.28 -29.95 -4.607 0.51132E+05 -28.247 7 CO,gas 3.21 -11.15 -14.36 -4.419 0.24525E+05 -12.664 8 SO3,gas 17.12 -32.09 -49.21 -12.303 0.84026E+05 -47.511 9 SO2,gas 0.83 -27.61 -28.44 -7.584 0.48558E+05 -26.739 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.74 -18.93 -9.465 0.32324E+05 -17.232 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.53 -3.50 -1.165 0.59687E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.53 -3.34 -1.114 0.57044E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.67 -3.56 -1.018 0.60835E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.67 -3.12 -0.891 0.53258E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.06 -4.82 -1.133 0.82241E+04 146 pyrrhotite -4.26 -7.42 -3.16 -1.054 0.53999E+04 147 pyrrhotiteFe0.875 -6.02 -8.82 -2.80 -1.031 0.47871E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.42 -3.01 -1.004 0.51427E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.92 -3.94 -1.313 0.67246E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0012300 MOLES New total amount of reactant added: 0.0012700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8664E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0012700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132800E-01 Osmotic coef. = -0.0853 True ionic strength = .2015626E-01 Chg. balance for total moles = -.8664E-10 Max. difference allowed = 0.1454E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88869E-10 -10.0512 0.74640E-10 -10.1270 0.83989E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29152E-03 -3.5353 0.24337E-03 -3.6137 0.83481E+00 -0.0784 4 SO4-- 0.28700E-11 -11.5421 0.14877E-11 -11.8275 0.51837E+00 -0.2854 5 HCO3- 0.38550E-05 -5.4140 0.32229E-05 -5.4917 0.83604E+00 -0.0778 6 HS- 0.11354E-03 -3.9449 0.94795E-04 -4.0232 0.83493E+00 -0.0783 7 Al+++ 0.99085E-29 -29.0040 0.22798E-29 -29.6421 0.23008E+00 -0.6381 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13688E-06 -6.8636 0.70433E-07 -7.1522 0.51455E+00 -0.2886 10 Mg++ 0.21415E-10 -10.6693 0.10968E-10 -10.9599 0.51218E+00 -0.2906 11 Fe++ 0.59023E-13 -13.2290 0.30264E-13 -13.5191 0.51275E+00 -0.2901 12 K+ 0.15754E-03 -3.8026 0.13174E-03 -3.8803 0.83624E+00 -0.0777 13 Na+ 0.19991E-01 -1.6992 0.16686E-01 -1.7777 0.83466E+00 -0.0785 14 Mn++ 0.18937E-10 -10.7227 0.97179E-11 -11.0124 0.51317E+00 -0.2897 15 F- 0.11451E-05 -5.9412 0.95395E-06 -6.0205 0.83308E+00 -0.0793 16 HPO4-- 0.44854E-07 -7.3482 0.23255E-07 -7.6335 0.51845E+00 -0.2853 18 HSiO3- 0.10429E-01 -1.9817 0.87066E-02 -2.0602 0.83481E+00 -0.0784 19 Ca(HSiO3)+ 0.16697E-07 -7.7774 0.13966E-07 -7.8549 0.83642E+00 -0.0776 20 Mg(HSiO3)+ 0.32359E-11 -11.4900 0.27066E-11 -11.5676 0.83642E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66558E-16 -16.1768 0.55670E-16 -16.2544 0.83642E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52862E-05 -5.2769 0.44050E-05 -5.3561 0.83330E+00 -0.0792 26 CH4,aq 0.20017E-03 -3.6986 0.19948E-03 -3.7001 0.99655E+00 -0.0015 27 C2H6,aq 0.58936E-12 -12.2296 0.58732E-12 -12.2311 0.99655E+00 -0.0015 28 C3H8,aq 0.40062E-19 -19.3973 0.39923E-19 -19.3988 0.99655E+00 -0.0015 30 ethanol,aq 0.21632E-19 -19.6649 0.21557E-19 -19.6664 0.99655E+00 -0.0015 31 CO,aq 0.14956E-15 -15.8252 0.14956E-15 -15.8252 0.10000E+01 0.0000 32 CO2,aq 0.51581E-09 -9.2875 0.51402E-09 -9.2890 0.99655E+00 -0.0015 33 CO3-2 0.72913E-05 -5.1372 0.37716E-05 -5.4235 0.51727E+00 -0.2863 34 CaCO3,aq 0.33309E-08 -8.4774 0.33309E-08 -8.4774 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.69277E-11 -11.1594 0.57944E-11 -11.2370 0.83642E+00 -0.0776 36 CaCl+ 0.33165E-10 -10.4793 0.27739E-10 -10.5569 0.83642E+00 -0.0776 37 CaCl2,aq 0.16038E-14 -14.7948 0.16038E-14 -14.7948 0.10000E+01 0.0000 38 CaF+ 0.11728E-11 -11.9308 0.98098E-12 -12.0083 0.83642E+00 -0.0776 39 CaOH+ 0.80405E-07 -7.0947 0.67252E-07 -7.1723 0.83642E+00 -0.0776 40 CaSO4,aq 0.33275E-16 -16.4779 0.33275E-16 -16.4779 0.10000E+01 0.0000 41 HCl,aq 0.33286E-14 -14.4777 0.33286E-14 -14.4777 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18806E-18 -18.7257 0.15699E-18 -18.8041 0.83481E+00 -0.0784 48 FeCl+ 0.13938E-16 -16.8558 0.11658E-16 -16.9334 0.83642E+00 -0.0776 51 FeF+ 0.17639E-17 -17.7535 0.14753E-17 -17.8311 0.83642E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15779E-10 -10.8019 0.13198E-10 -10.8795 0.83642E+00 -0.0776 55 HFeO2- 0.35452E-07 -7.4504 0.29596E-07 -7.5288 0.83481E+00 -0.0784 56 FeO+ 0.11059E-16 -16.9563 0.92499E-17 -17.0339 0.83642E+00 -0.0776 58 FeO2- 0.40696E-09 -9.3905 0.33973E-09 -9.4689 0.83481E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99655E+00 -0.0015 61 KCl,aq 0.58107E-09 -9.2358 0.58107E-09 -9.2358 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.36431E-14 -14.4385 0.30413E-14 -14.5169 0.83481E+00 -0.0784 65 MgCO3,aq 0.13002E-12 -12.8860 0.13002E-12 -12.8860 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11024E-14 -14.9577 0.92204E-15 -15.0353 0.83642E+00 -0.0776 67 MgCl+ 0.46809E-14 -14.3297 0.39152E-14 -14.4072 0.83642E+00 -0.0776 68 MgF+ 0.67656E-15 -15.1697 0.56589E-15 -15.2473 0.83642E+00 -0.0776 69 MgOH+ 0.69286E-10 -10.1594 0.57952E-10 -10.2369 0.83642E+00 -0.0776 71 MnF+ 0.18669E-15 -15.7289 0.15615E-15 -15.8065 0.83642E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47069E-09 -9.3273 0.39370E-09 -9.4048 0.83642E+00 -0.0776 74 MnO2-2 0.20803E-10 -10.6819 0.10761E-10 -10.9682 0.51727E+00 -0.2863 75 HMnO2- 0.21078E-09 -9.6762 0.17596E-09 -9.7546 0.83481E+00 -0.0784 78 MnCl+ 0.17412E-13 -13.7592 0.14563E-13 -13.8367 0.83642E+00 -0.0776 80 NaCl,aq 0.13457E-05 -5.8710 0.13457E-05 -5.8710 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92893E-02 -2.0320 0.77407E-02 -2.1112 0.83330E+00 -0.0792 89 HPO3-2 0.16227E-14 -14.7898 0.83938E-15 -15.0760 0.51727E+00 -0.2863 91 H2PO3- 0.15049E-18 -18.8225 0.12563E-18 -18.9009 0.83481E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38319E-10 -10.4166 0.32019E-10 -10.4946 0.83561E+00 -0.0780 94 PO4-3 0.10516E-08 -8.9781 0.25419E-09 -9.5948 0.24172E+00 -0.6167 98 HP2O7-3 0.93375E-18 -18.0298 0.21506E-18 -18.6674 0.23032E+00 -0.6377 99 P2O7-4 0.89908E-17 -17.0462 0.68832E-18 -18.1622 0.76559E-01 -1.1160 100 H2S,aq 0.21944E-07 -7.6587 0.21868E-07 -7.6602 0.99655E+00 -0.0015 101 S2-2 0.33234E-13 -13.4784 0.17191E-13 -13.7647 0.51727E+00 -0.2863 107 SO3-2 0.42670E-17 -17.3699 0.22393E-17 -17.6499 0.52479E+00 -0.2800 108 HSO3- 0.12536E-19 -19.9018 0.10465E-19 -19.9803 0.83481E+00 -0.0784 109 HSO4- 0.12782E-18 -18.8934 0.10702E-18 -18.9705 0.83724E+00 -0.0772 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8886940E-10 -.2219668E-01 -.2233384E+02 0.0000 2 H2O 0.1000000E+01 0.5550508E+02 0.9981939E+06 0.0000 3 Cl- 0.2915211E-03 0.2928674E-03 0.1036489E+02 6.5133 4 SO4-- 0.2870011E-11 -.2030766E-03 -.1947379E+02 8.4266 5 HCO3- 0.3855010E-05 0.2113211E-03 0.1287170E+02 4.6353 6 HS- 0.1135361E-03 0.3166346E-03 0.1045345E+02 6.1038 7 Al+++ 0.9908540E-29 0.5286383E-05 0.1423854E+00 0.7390 8 H4SiO4 0.6959768E-03 0.1347504E-01 0.1292896E+04 -3.1574 9 Ca++ 0.1368832E-06 0.2373569E-06 0.9496174E-02 13.1018 10 Mg++ 0.2141492E-10 0.9407180E-10 0.2283078E-05 9.2942 11 Fe++ 0.5902315E-13 0.3608891E-07 0.2011937E-02 6.7350 12 K+ 0.1575371E-03 0.1582915E-03 0.6178701E+01 6.2467 13 Na+ 0.1999087E-01 0.2243788E-01 0.5149414E+03 8.3494 14 Mn++ 0.1893684E-10 0.2527637E-08 0.1386207E-03 9.2416 15 F- 0.1145088E-05 0.1148817E-05 0.2178709E-01 4.1066 16 HPO4-- 0.4485409E-07 0.4594402E-07 0.4401958E-02 12.6206 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279241E+02 -.1101750E-01 -.8278139E+02 0.0000000E+00 2 H2O -.7167749E+01 0.2755041E+02 -.3471815E+02 0.0000000E+00 3 Cl- 0.1453672E-03 0.1453672E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385986E+00 -.1007987E-03 0.1386994E+00 0.0000000E+00 5 HCO3- 0.1048910E-03 0.1048910E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385422E+00 0.1571642E-03 -.1386994E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2623940E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6688447E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1178141E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4669332E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1791303E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7856928E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113723E-01 0.6265240E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254613E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6080000E-06 0.5702246E-06 0.3777540E-07 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2280469E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1915E-14 Mass of aqueous solution: 0.497227E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0012700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5548 -0.256 281.9 2.450 5.161 73.25 grossular 0.1343 -0.872 60.51 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.3778E-07 -7.423 0.1905E-04 -4.720 0.3488E-06 0.5951E-05 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2603 -0.585 56.36 1.751 1.032 17.23 hedenbergite 0.6750E-01 -1.171 16.75 1.224 0.3066 4.587 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.5 2.450 5.154 97.25 tr.625ac.25prg.125 0.4327E-01 -1.364 36.99 1.568 0.6771 11.90 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338282 g Volume = 2210.781375 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0012700 moles log = -2.8962 Original solution: 1000.0103000 g Original solution / Rock added: 787409.69 (Water/Rock Ratio), log = 5.8962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3299 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7699E+00 0.9825 0.1006E+01 0.1024E+01 CO2,gas 0.4120E-07 1.0038 0.5500E-07 0.5479E-07 CH4,gas 0.2187E+00 1.0096 0.2936E+00 0.2908E+00 H2,gas 0.1143E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4544E-06 0.9948 0.6011E-06 0.6043E-06 S2,gas 0.4411E-28 1.0000 0.5866E-28 0.5866E-28 CO,gas 0.1676E-12 1.0000 0.2229E-12 0.2229E-12 SO3,gas 0.2357E-47 1.0000 0.3134E-47 0.3134E-47 SO2,gas 0.1394E-26 1.0000 0.1854E-26 0.1854E-26 HF,gas 0.9000E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4417E-17 1.0000 0.5873E-17 0.5873E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.62 -8.96 -2.986 0.15297E+05 -7.260 3 CH4,gas 4.54 2.31 -2.23 -0.558 0.38097E+04 -0.532 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.15 -7.92 -3.960 0.13523E+05 -6.221 6 S2,gas -7.34 -37.27 -29.93 -4.605 0.51106E+05 -28.232 7 CO,gas 3.21 -11.14 -14.35 -4.416 0.24504E+05 -12.652 8 SO3,gas 17.12 -32.08 -49.20 -12.301 0.84013E+05 -47.504 9 SO2,gas 0.83 -27.60 -28.43 -7.582 0.48545E+05 -26.732 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.74 -18.93 -9.465 0.32323E+05 -17.231 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80708E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.52 -3.48 -1.161 0.59479E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.52 -3.33 -1.110 0.56837E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.65 -3.55 -1.014 0.60628E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.65 -3.11 -0.888 0.53050E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.05 -4.80 -1.130 0.81982E+04 146 pyrrhotite -4.26 -7.42 -3.15 -1.052 0.53870E+04 147 pyrrhotiteFe0.875 -6.02 -8.81 -2.80 -1.028 0.47742E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.42 -3.00 -1.001 0.51298E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.91 -3.93 -1.310 0.67116E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0012700 MOLES New total amount of reactant added: 0.0013100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8664E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0013100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132465E-01 Osmotic coef. = 0.3155 True ionic strength = .2015806E-01 Chg. balance for total moles = -.8664E-10 Max. difference allowed = 0.1456E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88876E-10 -10.0512 0.74646E-10 -10.1270 0.83988E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29199E-03 -3.5346 0.24376E-03 -3.6130 0.83481E+00 -0.0784 4 SO4-- 0.29193E-11 -11.5347 0.15133E-11 -11.8201 0.51836E+00 -0.2854 5 HCO3- 0.39611E-05 -5.4022 0.33116E-05 -5.4800 0.83603E+00 -0.0778 6 HS- 0.11549E-03 -3.9374 0.96429E-04 -4.0158 0.83493E+00 -0.0784 7 Al+++ 0.99113E-29 -29.0039 0.22803E-29 -29.6420 0.23007E+00 -0.6381 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13691E-06 -6.8636 0.70444E-07 -7.1522 0.51454E+00 -0.2886 10 Mg++ 0.21419E-10 -10.6692 0.10970E-10 -10.9598 0.51217E+00 -0.2906 11 Fe++ 0.59033E-13 -13.2289 0.30268E-13 -13.5190 0.51273E+00 -0.2901 12 K+ 0.15755E-03 -3.8026 0.13175E-03 -3.8803 0.83623E+00 -0.0777 13 Na+ 0.19992E-01 -1.6991 0.16687E-01 -1.7776 0.83465E+00 -0.0785 14 Mn++ 0.18940E-10 -10.7226 0.97194E-11 -11.0124 0.51316E+00 -0.2897 15 F- 0.11450E-05 -5.9412 0.95388E-06 -6.0205 0.83308E+00 -0.0793 16 HPO4-- 0.44849E-07 -7.3483 0.23251E-07 -7.6336 0.51844E+00 -0.2853 18 HSiO3- 0.10429E-01 -1.9818 0.87060E-02 -2.0602 0.83481E+00 -0.0784 19 Ca(HSiO3)+ 0.16698E-07 -7.7773 0.13967E-07 -7.8549 0.83641E+00 -0.0776 20 Mg(HSiO3)+ 0.32362E-11 -11.4900 0.27068E-11 -11.5675 0.83641E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66563E-16 -16.1768 0.55674E-16 -16.2543 0.83641E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52859E-05 -5.2769 0.44047E-05 -5.3561 0.83329E+00 -0.0792 26 CH4,aq 0.20569E-03 -3.6868 0.20498E-03 -3.6883 0.99655E+00 -0.0015 27 C2H6,aq 0.62231E-12 -12.2060 0.62016E-12 -12.2075 0.99655E+00 -0.0015 28 C3H8,aq 0.43468E-19 -19.3618 0.43318E-19 -19.3633 0.99655E+00 -0.0015 30 ethanol,aq 0.22841E-19 -19.6413 0.22762E-19 -19.6428 0.99655E+00 -0.0015 31 CO,aq 0.15369E-15 -15.8134 0.15369E-15 -15.8134 0.10000E+01 0.0000 32 CO2,aq 0.53003E-09 -9.2757 0.52820E-09 -9.2772 0.99655E+00 -0.0015 33 CO3-2 0.74914E-05 -5.1254 0.38750E-05 -5.4117 0.51726E+00 -0.2863 34 CaCO3,aq 0.34227E-08 -8.4656 0.34227E-08 -8.4656 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.71193E-11 -11.1476 0.59547E-11 -11.2251 0.83641E+00 -0.0776 36 CaCl+ 0.33223E-10 -10.4786 0.27788E-10 -10.5561 0.83641E+00 -0.0776 37 CaCl2,aq 0.16093E-14 -14.7934 0.16093E-14 -14.7934 0.10000E+01 0.0000 38 CaF+ 0.11729E-11 -11.9307 0.98105E-12 -12.0083 0.83641E+00 -0.0776 39 CaOH+ 0.80411E-07 -7.0947 0.67257E-07 -7.1723 0.83641E+00 -0.0776 40 CaSO4,aq 0.33851E-16 -16.4704 0.33851E-16 -16.4704 0.10000E+01 0.0000 41 HCl,aq 0.33343E-14 -14.4770 0.33343E-14 -14.4770 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18805E-18 -18.7257 0.15698E-18 -18.8042 0.83481E+00 -0.0784 48 FeCl+ 0.13962E-16 -16.8550 0.11678E-16 -16.9326 0.83641E+00 -0.0776 51 FeF+ 0.17640E-17 -17.7535 0.14754E-17 -17.8311 0.83641E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15781E-10 -10.8019 0.13199E-10 -10.8795 0.83641E+00 -0.0776 55 HFeO2- 0.35449E-07 -7.4504 0.29593E-07 -7.5288 0.83481E+00 -0.0784 56 FeO+ 0.11060E-16 -16.9563 0.92506E-17 -17.0338 0.83641E+00 -0.0776 58 FeO2- 0.40693E-09 -9.3905 0.33971E-09 -9.4689 0.83481E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99655E+00 -0.0015 61 KCl,aq 0.58205E-09 -9.2350 0.58205E-09 -9.2350 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.37060E-14 -14.4311 0.30938E-14 -14.5095 0.83481E+00 -0.0784 65 MgCO3,aq 0.13360E-12 -12.8742 0.13360E-12 -12.8742 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11329E-14 -14.9458 0.94753E-15 -15.0234 0.83641E+00 -0.0776 67 MgCl+ 0.46892E-14 -14.3289 0.39221E-14 -14.4065 0.83641E+00 -0.0776 68 MgF+ 0.67661E-15 -15.1697 0.56593E-15 -15.2472 0.83641E+00 -0.0776 69 MgOH+ 0.69291E-10 -10.1593 0.57956E-10 -10.2369 0.83641E+00 -0.0776 71 MnF+ 0.18670E-15 -15.7289 0.15616E-15 -15.8064 0.83641E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47073E-09 -9.3272 0.39373E-09 -9.4048 0.83641E+00 -0.0776 74 MnO2-2 0.20800E-10 -10.6819 0.10759E-10 -10.9682 0.51726E+00 -0.2863 75 HMnO2- 0.21077E-09 -9.6762 0.17595E-09 -9.7546 0.83481E+00 -0.0784 78 MnCl+ 0.17443E-13 -13.7584 0.14589E-13 -13.8360 0.83641E+00 -0.0776 80 NaCl,aq 0.13480E-05 -5.8703 0.13480E-05 -5.8703 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92887E-02 -2.0320 0.77402E-02 -2.1112 0.83329E+00 -0.0792 89 HPO3-2 0.16225E-14 -14.7898 0.83925E-15 -15.0761 0.51726E+00 -0.2863 91 H2PO3- 0.15048E-18 -18.8225 0.12563E-18 -18.9009 0.83481E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38316E-10 -10.4166 0.32017E-10 -10.4946 0.83560E+00 -0.0780 94 PO4-3 0.10514E-08 -8.9782 0.25414E-09 -9.5949 0.24171E+00 -0.6167 98 HP2O7-3 0.93360E-18 -18.0298 0.21501E-18 -18.6675 0.23030E+00 -0.6377 99 P2O7-4 0.89890E-17 -17.0463 0.68812E-18 -18.1623 0.76552E-01 -1.1160 100 H2S,aq 0.22324E-07 -7.6512 0.22246E-07 -7.6527 0.99655E+00 -0.0015 101 S2-2 0.34391E-13 -13.4636 0.17789E-13 -13.7499 0.51726E+00 -0.2863 107 SO3-2 0.43403E-17 -17.3625 0.22777E-17 -17.6425 0.52478E+00 -0.2800 108 HSO3- 0.12752E-19 -19.8944 0.10645E-19 -19.9728 0.83481E+00 -0.0784 109 HSO4- 0.13002E-18 -18.8860 0.10886E-18 -18.9631 0.83723E+00 -0.0772 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8887646E-10 -.2219554E-01 -.2233269E+02 0.0000 2 H2O 0.1000000E+01 0.5550509E+02 0.9981939E+06 0.0000 3 Cl- 0.2919939E-03 0.2933425E-03 0.1038170E+02 6.5140 4 SO4-- 0.2919335E-11 -.2085964E-03 -.2000310E+02 8.4339 5 HCO3- 0.3961051E-05 0.2171473E-03 0.1322657E+02 4.6470 6 HS- 0.1154938E-03 0.3241125E-03 0.1070032E+02 6.1112 7 Al+++ 0.9911266E-29 0.5286026E-05 0.1423758E+00 0.7390 8 H4SiO4 0.6959767E-03 0.1347433E-01 0.1292828E+04 -3.1574 9 Ca++ 0.1369067E-06 0.2374803E-06 0.9501106E-02 13.1018 10 Mg++ 0.2141860E-10 0.9408598E-10 0.2283422E-05 9.2942 11 Fe++ 0.5903329E-13 0.3608648E-07 0.2011801E-02 6.7350 12 K+ 0.1575497E-03 0.1583040E-03 0.6179188E+01 6.2467 13 Na+ 0.1999246E-01 0.2243948E-01 0.5149778E+03 8.3494 14 Mn++ 0.1894016E-10 0.2527670E-08 0.1386226E-03 9.2416 15 F- 0.1145011E-05 0.1148739E-05 0.2178562E-01 4.1065 16 HPO4-- 0.4484853E-07 0.4593828E-07 0.4401407E-02 12.6204 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279241E+02 -.1101696E-01 -.8278139E+02 0.0000000E+00 2 H2O -.7167716E+01 0.2755045E+02 -.3471817E+02 0.0000000E+00 3 Cl- 0.1456032E-03 0.1456032E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385988E+00 -.1035387E-03 0.1387023E+00 0.0000000E+00 5 HCO3- 0.1077830E-03 0.1077830E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385414E+00 0.1608762E-03 -.1387023E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2623767E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6688107E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1178755E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4670042E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1791185E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7857561E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113804E-01 0.6265239E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254632E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6240000E-06 0.5701870E-06 0.5381298E-07 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2280188E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.6196E-14 Mass of aqueous solution: 0.497228E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0013100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5548 -0.256 281.9 2.450 5.162 73.25 grossular 0.1343 -0.872 60.51 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.5381E-07 -7.269 0.2714E-04 -4.566 0.4968E-06 0.8478E-05 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2602 -0.585 56.35 1.751 1.032 17.22 hedenbergite 0.6748E-01 -1.171 16.74 1.224 0.3065 4.585 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.5 2.450 5.154 97.25 tr.625ac.25prg.125 0.4330E-01 -1.364 37.01 1.568 0.6775 11.91 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338294 g Volume = 2210.781485 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0013100 moles log = -2.8827 Original solution: 1000.0103000 g Original solution / Rock added: 763366.64 (Water/Rock Ratio), log = 5.8827 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3380 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7653E+00 0.9825 0.1006E+01 0.1024E+01 CO2,gas 0.4208E-07 1.0037 0.5651E-07 0.5630E-07 CH4,gas 0.2234E+00 1.0095 0.3017E+00 0.2989E+00 H2,gas 0.1136E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4594E-06 0.9948 0.6115E-06 0.6147E-06 S2,gas 0.4537E-28 1.0000 0.6071E-28 0.6071E-28 CO,gas 0.1712E-12 1.0000 0.2290E-12 0.2290E-12 SO3,gas 0.2383E-47 1.0000 0.3188E-47 0.3188E-47 SO2,gas 0.1410E-26 1.0000 0.1886E-26 0.1886E-26 HF,gas 0.8945E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4397E-17 1.0000 0.5883E-17 0.5883E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.61 -8.95 -2.982 0.15276E+05 -7.248 3 CH4,gas 4.54 2.32 -2.22 -0.555 0.37895E+04 -0.520 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.14 -7.91 -3.956 0.13510E+05 -6.214 6 S2,gas -7.34 -37.25 -29.92 -4.602 0.51080E+05 -28.217 7 CO,gas 3.21 -11.12 -14.34 -4.412 0.24484E+05 -12.640 8 SO3,gas 17.12 -32.07 -49.20 -12.299 0.84000E+05 -47.496 9 SO2,gas 0.83 -27.59 -28.42 -7.580 0.48532E+05 -26.724 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.74 -18.93 -9.465 0.32321E+05 -17.230 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.51 -3.47 -1.157 0.59277E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.51 -3.32 -1.106 0.56635E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.64 -3.54 -1.011 0.60426E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.64 -3.10 -0.884 0.52849E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.03 -4.79 -1.126 0.81728E+04 146 pyrrhotite -4.26 -7.41 -3.15 -1.049 0.53742E+04 147 pyrrhotiteFe0.875 -6.02 -8.81 -2.79 -1.026 0.47615E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.41 -3.00 -0.999 0.51171E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.90 -3.92 -1.308 0.66989E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0013100 MOLES New total amount of reactant added: 0.0013500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0013500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1132130E-01 Osmotic coef. = 0.4877 True ionic strength = .2015986E-01 Chg. balance for total moles = -.8663E-10 Max. difference allowed = 0.1458E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88884E-10 -10.0512 0.74651E-10 -10.1270 0.83988E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29247E-03 -3.5339 0.24415E-03 -3.6123 0.83480E+00 -0.0784 4 SO4-- 0.29687E-11 -11.5274 0.15388E-11 -11.8128 0.51835E+00 -0.2854 5 HCO3- 0.40671E-05 -5.3907 0.34002E-05 -5.4685 0.83603E+00 -0.0778 6 HS- 0.11745E-03 -3.9301 0.98063E-04 -4.0085 0.83492E+00 -0.0784 7 Al+++ 0.99140E-29 -29.0038 0.22808E-29 -29.6419 0.23006E+00 -0.6382 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13693E-06 -6.8635 0.70454E-07 -7.1521 0.51452E+00 -0.2886 10 Mg++ 0.21422E-10 -10.6691 0.10972E-10 -10.9597 0.51216E+00 -0.2906 11 Fe++ 0.59043E-13 -13.2288 0.30273E-13 -13.5189 0.51272E+00 -0.2901 12 K+ 0.15756E-03 -3.8025 0.13176E-03 -3.8802 0.83623E+00 -0.0777 13 Na+ 0.19994E-01 -1.6991 0.16688E-01 -1.7776 0.83465E+00 -0.0785 14 Mn++ 0.18943E-10 -10.7225 0.97208E-11 -11.0123 0.51315E+00 -0.2898 15 F- 0.11449E-05 -5.9412 0.95381E-06 -6.0205 0.83307E+00 -0.0793 16 HPO4-- 0.44843E-07 -7.3483 0.23248E-07 -7.6336 0.51842E+00 -0.2853 18 HSiO3- 0.10428E-01 -1.9818 0.87053E-02 -2.0602 0.83480E+00 -0.0784 19 Ca(HSiO3)+ 0.16700E-07 -7.7773 0.13968E-07 -7.8549 0.83641E+00 -0.0776 20 Mg(HSiO3)+ 0.32365E-11 -11.4899 0.27070E-11 -11.5675 0.83641E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66568E-16 -16.1767 0.55678E-16 -16.2543 0.83641E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52855E-05 -5.2769 0.44043E-05 -5.3561 0.83329E+00 -0.0792 26 CH4,aq 0.21121E-03 -3.6753 0.21048E-03 -3.6768 0.99655E+00 -0.0015 27 C2H6,aq 0.65616E-12 -12.1830 0.65390E-12 -12.1845 0.99655E+00 -0.0015 28 C3H8,aq 0.47063E-19 -19.3273 0.46900E-19 -19.3288 0.99655E+00 -0.0015 30 ethanol,aq 0.24084E-19 -19.6183 0.24000E-19 -19.6198 0.99655E+00 -0.0015 31 CO,aq 0.15781E-15 -15.8019 0.15781E-15 -15.8019 0.10000E+01 0.0000 32 CO2,aq 0.54425E-09 -9.2642 0.54238E-09 -9.2657 0.99655E+00 -0.0015 33 CO3-2 0.76915E-05 -5.1140 0.39784E-05 -5.4003 0.51724E+00 -0.2863 34 CaCO3,aq 0.35146E-08 -8.4541 0.35146E-08 -8.4541 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.73109E-11 -11.1360 0.61149E-11 -11.2136 0.83641E+00 -0.0776 36 CaCl+ 0.33282E-10 -10.4778 0.27837E-10 -10.5554 0.83641E+00 -0.0776 37 CaCl2,aq 0.16147E-14 -14.7919 0.16147E-14 -14.7919 0.10000E+01 0.0000 38 CaF+ 0.11730E-11 -11.9307 0.98112E-12 -12.0083 0.83641E+00 -0.0776 39 CaOH+ 0.80417E-07 -7.0946 0.67262E-07 -7.1722 0.83641E+00 -0.0776 40 CaSO4,aq 0.34427E-16 -16.4631 0.34427E-16 -16.4631 0.10000E+01 0.0000 41 HCl,aq 0.33399E-14 -14.4763 0.33399E-14 -14.4763 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18803E-18 -18.7258 0.15697E-18 -18.8042 0.83480E+00 -0.0784 48 FeCl+ 0.13987E-16 -16.8543 0.11699E-16 -16.9319 0.83641E+00 -0.0776 51 FeF+ 0.17641E-17 -17.7535 0.14755E-17 -17.8310 0.83641E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15782E-10 -10.8018 0.13200E-10 -10.8794 0.83641E+00 -0.0776 55 HFeO2- 0.35447E-07 -7.4504 0.29591E-07 -7.5288 0.83480E+00 -0.0784 56 FeO+ 0.11061E-16 -16.9562 0.92513E-17 -17.0338 0.83641E+00 -0.0776 58 FeO2- 0.40690E-09 -9.3905 0.33968E-09 -9.4689 0.83480E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99655E+00 -0.0015 61 KCl,aq 0.58304E-09 -9.2343 0.58304E-09 -9.2343 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.37688E-14 -14.4238 0.31462E-14 -14.5022 0.83480E+00 -0.0784 65 MgCO3,aq 0.13719E-12 -12.8627 0.13719E-12 -12.8627 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11633E-14 -14.9343 0.97303E-15 -15.0119 0.83641E+00 -0.0776 67 MgCl+ 0.46975E-14 -14.3281 0.39290E-14 -14.4057 0.83641E+00 -0.0776 68 MgF+ 0.67667E-15 -15.1696 0.56597E-15 -15.2472 0.83641E+00 -0.0776 69 MgOH+ 0.69297E-10 -10.1593 0.57961E-10 -10.2369 0.83641E+00 -0.0776 71 MnF+ 0.18672E-15 -15.7288 0.15617E-15 -15.8064 0.83641E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47077E-09 -9.3272 0.39376E-09 -9.4048 0.83641E+00 -0.0776 74 MnO2-2 0.20798E-10 -10.6820 0.10758E-10 -10.9683 0.51724E+00 -0.2863 75 HMnO2- 0.21075E-09 -9.6762 0.17594E-09 -9.7546 0.83480E+00 -0.0784 78 MnCl+ 0.17473E-13 -13.7576 0.14615E-13 -13.8352 0.83641E+00 -0.0776 80 NaCl,aq 0.13503E-05 -5.8696 0.13503E-05 -5.8696 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92880E-02 -2.0321 0.77396E-02 -2.1113 0.83329E+00 -0.0792 89 HPO3-2 0.16223E-14 -14.7899 0.83913E-15 -15.0762 0.51724E+00 -0.2863 91 H2PO3- 0.15047E-18 -18.8225 0.12562E-18 -18.9010 0.83480E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38314E-10 -10.4166 0.32015E-10 -10.4946 0.83560E+00 -0.0780 94 PO4-3 0.10513E-08 -8.9783 0.25408E-09 -9.5950 0.24170E+00 -0.6167 98 HP2O7-3 0.93344E-18 -18.0299 0.21496E-18 -18.6676 0.23029E+00 -0.6377 99 P2O7-4 0.89871E-17 -17.0464 0.68792E-18 -18.1625 0.76544E-01 -1.1161 100 H2S,aq 0.22703E-07 -7.6439 0.22625E-07 -7.6454 0.99655E+00 -0.0015 101 S2-2 0.35567E-13 -13.4490 0.18397E-13 -13.7353 0.51724E+00 -0.2863 107 SO3-2 0.44136E-17 -17.3552 0.23161E-17 -17.6352 0.52477E+00 -0.2800 108 HSO3- 0.12968E-19 -19.8871 0.10826E-19 -19.9655 0.83480E+00 -0.0784 109 HSO4- 0.13223E-18 -18.8787 0.11071E-18 -18.9558 0.83723E+00 -0.0772 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8888352E-10 -.2219440E-01 -.2233154E+02 0.0000 2 H2O 0.1000000E+01 0.5550509E+02 0.9981938E+06 0.0000 3 Cl- 0.2924666E-03 0.2938175E-03 0.1039851E+02 6.5146 4 SO4-- 0.2968652E-11 -.2141163E-03 -.2053242E+02 8.4411 5 HCO3- 0.4067078E-05 0.2229734E-03 0.1358144E+02 4.6585 6 HS- 0.1174515E-03 0.3315905E-03 0.1094720E+02 6.1185 7 Al+++ 0.9913993E-29 0.5285670E-05 0.1423661E+00 0.7390 8 H4SiO4 0.6959767E-03 0.1347363E-01 0.1292760E+04 -3.1574 9 Ca++ 0.1369302E-06 0.2376036E-06 0.9506038E-02 13.1018 10 Mg++ 0.2142228E-10 0.9409836E-10 0.2283722E-05 9.2942 11 Fe++ 0.5904344E-13 0.3608406E-07 0.2011666E-02 6.7350 12 K+ 0.1575622E-03 0.1583165E-03 0.6179676E+01 6.2467 13 Na+ 0.1999405E-01 0.2244107E-01 0.5150143E+03 8.3494 14 Mn++ 0.1894349E-10 0.2527704E-08 0.1386244E-03 9.2416 15 F- 0.1144934E-05 0.1148662E-05 0.2178415E-01 4.1064 16 HPO4-- 0.4484297E-07 0.4593253E-07 0.4400856E-02 12.6203 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279240E+02 -.1101641E-01 -.8278139E+02 0.0000000E+00 2 H2O -.7167683E+01 0.2755049E+02 -.3471818E+02 0.0000000E+00 3 Cl- 0.1458392E-03 0.1458392E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385990E+00 -.1062787E-03 0.1387052E+00 0.0000000E+00 5 HCO3- 0.1106750E-03 0.1106750E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385407E+00 0.1645882E-03 -.1387052E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2623594E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6687766E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1179368E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4670664E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1791067E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7858193E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113884E-01 0.6265238E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254650E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6400000E-06 0.5701494E-06 0.6985056E-07 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2279906E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.2519E-14 Mass of aqueous solution: 0.497228E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0013500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5548 -0.256 281.9 2.450 5.162 73.25 grossular 0.1343 -0.872 60.52 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.6985E-07 -7.156 0.3523E-04 -4.453 0.6449E-06 0.1100E-04 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2601 -0.585 56.33 1.751 1.031 17.22 hedenbergite 0.6746E-01 -1.171 16.74 1.224 0.3064 4.584 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2612 -0.583 281.5 2.450 5.154 97.24 tr.625ac.25prg.125 0.4332E-01 -1.363 37.03 1.569 0.6779 11.92 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338307 g Volume = 2210.781595 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0013500 moles log = -2.8697 Original solution: 1000.0103000 g Original solution / Rock added: 740748.37 (Water/Rock Ratio), log = 5.8697 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3461 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7607E+00 0.9824 0.1006E+01 0.1024E+01 CO2,gas 0.4295E-07 1.0036 0.5803E-07 0.5782E-07 CH4,gas 0.2280E+00 1.0094 0.3098E+00 0.3069E+00 H2,gas 0.1129E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4645E-06 0.9948 0.6219E-06 0.6252E-06 S2,gas 0.4665E-28 1.0000 0.6279E-28 0.6279E-28 CO,gas 0.1747E-12 1.0000 0.2352E-12 0.2352E-12 SO3,gas 0.2409E-47 1.0000 0.3242E-47 0.3242E-47 SO2,gas 0.1425E-26 1.0000 0.1918E-26 0.1918E-26 HF,gas 0.8891E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4378E-17 1.0000 0.5893E-17 0.5893E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.60 -8.94 -2.978 0.15257E+05 -7.236 3 CH4,gas 4.54 2.34 -2.21 -0.552 0.37699E+04 -0.509 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.14 -7.91 -3.953 0.13498E+05 -6.206 6 S2,gas -7.34 -37.24 -29.90 -4.600 0.51055E+05 -28.202 7 CO,gas 3.21 -11.11 -14.33 -4.408 0.24464E+05 -12.629 8 SO3,gas 17.12 -32.07 -49.19 -12.297 0.83987E+05 -47.489 9 SO2,gas 0.83 -27.58 -28.42 -7.578 0.48520E+05 -26.717 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.74 -18.93 -9.464 0.32320E+05 -17.230 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.49 -3.46 -1.153 0.59081E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.49 -3.31 -1.102 0.56439E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.63 -3.53 -1.008 0.60230E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.63 -3.08 -0.881 0.52652E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.02 -4.77 -1.123 0.81478E+04 146 pyrrhotite -4.26 -7.40 -3.14 -1.047 0.53617E+04 147 pyrrhotiteFe0.875 -6.02 -8.80 -2.78 -1.023 0.47489E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.40 -2.99 -0.997 0.51045E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.89 -3.92 -1.305 0.66864E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0013500 MOLES New total amount of reactant added: 0.0013900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0013900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131795E-01 Osmotic coef. = 0.5834 True ionic strength = .2016167E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.1461E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88891E-10 -10.0511 0.74657E-10 -10.1269 0.83987E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29294E-03 -3.5332 0.24454E-03 -3.6116 0.83480E+00 -0.0784 4 SO4-- 0.30180E-11 -11.5203 0.15643E-11 -11.8057 0.51834E+00 -0.2854 5 HCO3- 0.41731E-05 -5.3795 0.34888E-05 -5.4573 0.83602E+00 -0.0778 6 HS- 0.11941E-03 -3.9230 0.99697E-04 -4.0013 0.83492E+00 -0.0784 7 Al+++ 0.99167E-29 -29.0036 0.22813E-29 -29.6418 0.23005E+00 -0.6382 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13695E-06 -6.8634 0.70464E-07 -7.1520 0.51451E+00 -0.2886 10 Mg++ 0.21426E-10 -10.6691 0.10973E-10 -10.9597 0.51215E+00 -0.2906 11 Fe++ 0.59054E-13 -13.2288 0.30277E-13 -13.5189 0.51271E+00 -0.2901 12 K+ 0.15757E-03 -3.8025 0.13177E-03 -3.8802 0.83622E+00 -0.0777 13 Na+ 0.19996E-01 -1.6991 0.16689E-01 -1.7776 0.83464E+00 -0.0785 14 Mn++ 0.18947E-10 -10.7225 0.97223E-11 -11.0122 0.51314E+00 -0.2898 15 F- 0.11449E-05 -5.9412 0.95374E-06 -6.0206 0.83307E+00 -0.0793 16 HPO4-- 0.44837E-07 -7.3484 0.23244E-07 -7.6337 0.51841E+00 -0.2853 18 HSiO3- 0.10427E-01 -1.9818 0.87047E-02 -2.0602 0.83480E+00 -0.0784 19 Ca(HSiO3)+ 0.16701E-07 -7.7773 0.13969E-07 -7.8548 0.83640E+00 -0.0776 20 Mg(HSiO3)+ 0.32367E-11 -11.4899 0.27072E-11 -11.5675 0.83640E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66574E-16 -16.1767 0.55683E-16 -16.2543 0.83640E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52852E-05 -5.2769 0.44040E-05 -5.3562 0.83328E+00 -0.0792 26 CH4,aq 0.21673E-03 -3.6641 0.21598E-03 -3.6656 0.99655E+00 -0.0015 27 C2H6,aq 0.69091E-12 -12.1606 0.68852E-12 -12.1621 0.99655E+00 -0.0015 28 C3H8,aq 0.50850E-19 -19.2937 0.50674E-19 -19.2952 0.99655E+00 -0.0015 30 ethanol,aq 0.25359E-19 -19.5959 0.25271E-19 -19.5974 0.99655E+00 -0.0015 31 CO,aq 0.16194E-15 -15.7907 0.16194E-15 -15.7907 0.10000E+01 0.0000 32 CO2,aq 0.55848E-09 -9.2530 0.55655E-09 -9.2545 0.99655E+00 -0.0015 33 CO3-2 0.78916E-05 -5.1028 0.40818E-05 -5.3892 0.51723E+00 -0.2863 34 CaCO3,aq 0.36064E-08 -8.4429 0.36064E-08 -8.4429 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.75026E-11 -11.1248 0.62752E-11 -11.2024 0.83640E+00 -0.0776 36 CaCl+ 0.33341E-10 -10.4770 0.27886E-10 -10.5546 0.83640E+00 -0.0776 37 CaCl2,aq 0.16202E-14 -14.7904 0.16202E-14 -14.7904 0.10000E+01 0.0000 38 CaF+ 0.11731E-11 -11.9307 0.98119E-12 -12.0082 0.83640E+00 -0.0776 39 CaOH+ 0.80424E-07 -7.0946 0.67267E-07 -7.1722 0.83640E+00 -0.0776 40 CaSO4,aq 0.35003E-16 -16.4559 0.35003E-16 -16.4559 0.10000E+01 0.0000 41 HCl,aq 0.33455E-14 -14.4755 0.33455E-14 -14.4755 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18802E-18 -18.7258 0.15696E-18 -18.8042 0.83480E+00 -0.0784 48 FeCl+ 0.14012E-16 -16.8535 0.11720E-16 -16.9311 0.83640E+00 -0.0776 51 FeF+ 0.17643E-17 -17.7534 0.14756E-17 -17.8310 0.83640E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15783E-10 -10.8018 0.13201E-10 -10.8794 0.83640E+00 -0.0776 55 HFeO2- 0.35445E-07 -7.4505 0.29589E-07 -7.5289 0.83480E+00 -0.0784 56 FeO+ 0.11062E-16 -16.9562 0.92520E-17 -17.0338 0.83640E+00 -0.0776 58 FeO2- 0.40688E-09 -9.3905 0.33966E-09 -9.4690 0.83480E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99655E+00 -0.0015 61 KCl,aq 0.58402E-09 -9.2336 0.58402E-09 -9.2336 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.38316E-14 -14.4166 0.31986E-14 -14.4950 0.83480E+00 -0.0784 65 MgCO3,aq 0.14077E-12 -12.8515 0.14077E-12 -12.8515 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11938E-14 -14.9231 0.99854E-15 -15.0006 0.83640E+00 -0.0776 67 MgCl+ 0.47058E-14 -14.3274 0.39359E-14 -14.4050 0.83640E+00 -0.0776 68 MgF+ 0.67672E-15 -15.1696 0.56601E-15 -15.2472 0.83640E+00 -0.0776 69 MgOH+ 0.69303E-10 -10.1593 0.57965E-10 -10.2368 0.83640E+00 -0.0776 71 MnF+ 0.18673E-15 -15.7288 0.15618E-15 -15.8064 0.83640E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47081E-09 -9.3272 0.39379E-09 -9.4047 0.83640E+00 -0.0776 74 MnO2-2 0.20795E-10 -10.6820 0.10756E-10 -10.9684 0.51723E+00 -0.2863 75 HMnO2- 0.21074E-09 -9.6763 0.17593E-09 -9.7547 0.83480E+00 -0.0784 78 MnCl+ 0.17504E-13 -13.7569 0.14641E-13 -13.8344 0.83640E+00 -0.0776 80 NaCl,aq 0.13525E-05 -5.8688 0.13525E-05 -5.8688 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92874E-02 -2.0321 0.77390E-02 -2.1113 0.83328E+00 -0.0792 89 HPO3-2 0.16221E-14 -14.7899 0.83901E-15 -15.0762 0.51723E+00 -0.2863 91 H2PO3- 0.15046E-18 -18.8226 0.12561E-18 -18.9010 0.83480E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38311E-10 -10.4167 0.32012E-10 -10.4947 0.83559E+00 -0.0780 94 PO4-3 0.10511E-08 -8.9784 0.25403E-09 -9.5951 0.24168E+00 -0.6168 98 HP2O7-3 0.93328E-18 -18.0300 0.21492E-18 -18.6677 0.23028E+00 -0.6377 99 P2O7-4 0.89853E-17 -17.0465 0.68771E-18 -18.1626 0.76537E-01 -1.1161 100 H2S,aq 0.23083E-07 -7.6367 0.23004E-07 -7.6382 0.99655E+00 -0.0015 101 S2-2 0.36763E-13 -13.4346 0.19015E-13 -13.7209 0.51723E+00 -0.2863 107 SO3-2 0.44869E-17 -17.3480 0.23545E-17 -17.6281 0.52475E+00 -0.2800 108 HSO3- 0.13184E-19 -19.8799 0.11006E-19 -19.9584 0.83480E+00 -0.0784 109 HSO4- 0.13443E-18 -18.8715 0.11255E-18 -18.9487 0.83722E+00 -0.0772 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8889058E-10 -.2219327E-01 -.2233040E+02 0.0000 2 H2O 0.1000000E+01 0.5550510E+02 0.9981937E+06 0.0000 3 Cl- 0.2929394E-03 0.2942925E-03 0.1041532E+02 6.5153 4 SO4-- 0.3017964E-11 -.2196362E-03 -.2106174E+02 8.4482 5 HCO3- 0.4173091E-05 0.2287994E-03 0.1393631E+02 4.6696 6 HS- 0.1194092E-03 0.3390685E-03 0.1119408E+02 6.1256 7 Al+++ 0.9916720E-29 0.5285313E-05 0.1423565E+00 0.7390 8 H4SiO4 0.6959766E-03 0.1347292E-01 0.1292692E+04 -3.1574 9 Ca++ 0.1369537E-06 0.2377269E-06 0.9510970E-02 13.1018 10 Mg++ 0.2142596E-10 0.9411343E-10 0.2284088E-05 9.2942 11 Fe++ 0.5905358E-13 0.3608163E-07 0.2011530E-02 6.7350 12 K+ 0.1575747E-03 0.1583290E-03 0.6180163E+01 6.2467 13 Na+ 0.1999564E-01 0.2244266E-01 0.5150507E+03 8.3494 14 Mn++ 0.1894681E-10 0.2527738E-08 0.1386262E-03 9.2416 15 F- 0.1144856E-05 0.1148584E-05 0.2178268E-01 4.1064 16 HPO4-- 0.4483741E-07 0.4592679E-07 0.4400306E-02 12.6202 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279240E+02 -.1101586E-01 -.8278138E+02 0.0000000E+00 2 H2O -.7167651E+01 0.2755054E+02 -.3471819E+02 0.0000000E+00 3 Cl- 0.1460752E-03 0.1460752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385992E+00 -.1090187E-03 0.1387082E+00 0.0000000E+00 5 HCO3- 0.1135670E-03 0.1135670E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385399E+00 0.1683002E-03 -.1387082E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2623420E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6687425E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1179982E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4671419E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1790950E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7858826E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1113965E-01 0.6265237E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254669E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6560000E-06 0.5701119E-06 0.8588812E-07 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2279624E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1731E-13 Mass of aqueous solution: 0.497229E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0013900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5548 -0.256 282.0 2.450 5.162 73.25 grossular 0.1343 -0.872 60.52 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.8589E-07 -7.066 0.4331E-04 -4.363 0.7930E-06 0.1353E-04 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2600 -0.585 56.31 1.751 1.031 17.21 hedenbergite 0.6744E-01 -1.171 16.73 1.224 0.3063 4.583 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.5 2.450 5.154 97.24 tr.625ac.25prg.125 0.4335E-01 -1.363 37.05 1.569 0.6783 11.93 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338320 g Volume = 2210.781706 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0013900 moles log = -2.8570 Original solution: 1000.0103000 g Original solution / Rock added: 719431.87 (Water/Rock Ratio), log = 5.8570 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3542 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7562E+00 0.9823 0.1006E+01 0.1024E+01 CO2,gas 0.4382E-07 1.0035 0.5954E-07 0.5934E-07 CH4,gas 0.2326E+00 1.0093 0.3179E+00 0.3150E+00 H2,gas 0.1122E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4694E-06 0.9947 0.6324E-06 0.6357E-06 S2,gas 0.4793E-28 1.0000 0.6491E-28 0.6491E-28 CO,gas 0.1782E-12 1.0000 0.2413E-12 0.2413E-12 SO3,gas 0.2434E-47 1.0000 0.3297E-47 0.3297E-47 SO2,gas 0.1440E-26 1.0000 0.1950E-26 0.1950E-26 HF,gas 0.8838E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4359E-17 1.0000 0.5903E-17 0.5903E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.58 -8.92 -2.975 0.15238E+05 -7.225 3 CH4,gas 4.54 2.35 -2.20 -0.549 0.37507E+04 -0.498 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.13 -7.90 -3.949 0.13486E+05 -6.199 6 S2,gas -7.34 -37.22 -29.89 -4.598 0.51031E+05 -28.188 7 CO,gas 3.21 -11.10 -14.32 -4.405 0.24445E+05 -12.617 8 SO3,gas 17.12 -32.06 -49.18 -12.295 0.83975E+05 -47.482 9 SO2,gas 0.83 -27.58 -28.41 -7.576 0.48507E+05 -26.710 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.74 -18.93 -9.464 0.32319E+05 -17.229 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.48 -3.45 -1.150 0.58890E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.48 -3.29 -1.098 0.56248E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.62 -3.52 -1.005 0.60039E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.62 -3.07 -0.878 0.52461E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -26.00 -4.76 -1.119 0.81231E+04 146 pyrrhotite -4.26 -7.39 -3.13 -1.044 0.53494E+04 147 pyrrhotiteFe0.875 -6.02 -8.79 -2.77 -1.020 0.47366E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.39 -2.98 -0.994 0.50922E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.89 -3.91 -1.303 0.66741E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0013900 MOLES New total amount of reactant added: 0.0014300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0014300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131460E-01 Osmotic coef. = 0.6443 True ionic strength = .2016347E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.1463E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88898E-10 -10.0511 0.74662E-10 -10.1269 0.83987E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29341E-03 -3.5325 0.24494E-03 -3.6109 0.83479E+00 -0.0784 4 SO4-- 0.30673E-11 -11.5132 0.15898E-11 -11.7986 0.51833E+00 -0.2854 5 HCO3- 0.42791E-05 -5.3686 0.35774E-05 -5.4464 0.83602E+00 -0.0778 6 HS- 0.12137E-03 -3.9159 0.10133E-03 -3.9943 0.83491E+00 -0.0784 7 Al+++ 0.99194E-29 -29.0035 0.22818E-29 -29.6417 0.23003E+00 -0.6382 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13698E-06 -6.8634 0.70475E-07 -7.1520 0.51450E+00 -0.2886 10 Mg++ 0.21430E-10 -10.6690 0.10975E-10 -10.9596 0.51213E+00 -0.2906 11 Fe++ 0.59064E-13 -13.2287 0.30282E-13 -13.5188 0.51270E+00 -0.2901 12 K+ 0.15759E-03 -3.8025 0.13178E-03 -3.8802 0.83622E+00 -0.0777 13 Na+ 0.19997E-01 -1.6990 0.16690E-01 -1.7775 0.83464E+00 -0.0785 14 Mn++ 0.18950E-10 -10.7224 0.97238E-11 -11.0122 0.51312E+00 -0.2898 15 F- 0.11448E-05 -5.9413 0.95367E-06 -6.0206 0.83306E+00 -0.0793 16 HPO4-- 0.44832E-07 -7.3484 0.23241E-07 -7.6337 0.51840E+00 -0.2853 18 HSiO3- 0.10427E-01 -1.9819 0.87040E-02 -2.0603 0.83479E+00 -0.0784 19 Ca(HSiO3)+ 0.16702E-07 -7.7772 0.13970E-07 -7.8548 0.83640E+00 -0.0776 20 Mg(HSiO3)+ 0.32370E-11 -11.4899 0.27074E-11 -11.5674 0.83640E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66579E-16 -16.1767 0.55687E-16 -16.2542 0.83640E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52848E-05 -5.2770 0.44037E-05 -5.3562 0.83328E+00 -0.0792 26 CH4,aq 0.22225E-03 -3.6532 0.22148E-03 -3.6547 0.99655E+00 -0.0015 27 C2H6,aq 0.72655E-12 -12.1387 0.72404E-12 -12.1402 0.99655E+00 -0.0015 28 C3H8,aq 0.54835E-19 -19.2609 0.54646E-19 -19.2624 0.99655E+00 -0.0015 30 ethanol,aq 0.26667E-19 -19.5740 0.26575E-19 -19.5755 0.99655E+00 -0.0015 31 CO,aq 0.16606E-15 -15.7797 0.16606E-15 -15.7797 0.10000E+01 0.0000 32 CO2,aq 0.57270E-09 -9.2421 0.57073E-09 -9.2436 0.99655E+00 -0.0015 33 CO3-2 0.80916E-05 -5.0920 0.41851E-05 -5.3783 0.51722E+00 -0.2863 34 CaCO3,aq 0.36983E-08 -8.4320 0.36983E-08 -8.4320 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.76943E-11 -11.1138 0.64355E-11 -11.1914 0.83640E+00 -0.0776 36 CaCl+ 0.33399E-10 -10.4763 0.27935E-10 -10.5538 0.83640E+00 -0.0776 37 CaCl2,aq 0.16256E-14 -14.7890 0.16256E-14 -14.7890 0.10000E+01 0.0000 38 CaF+ 0.11732E-11 -11.9306 0.98127E-12 -12.0082 0.83640E+00 -0.0776 39 CaOH+ 0.80430E-07 -7.0946 0.67272E-07 -7.1722 0.83640E+00 -0.0776 40 CaSO4,aq 0.35579E-16 -16.4488 0.35579E-16 -16.4488 0.10000E+01 0.0000 41 HCl,aq 0.33511E-14 -14.4748 0.33511E-14 -14.4748 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18801E-18 -18.7258 0.15695E-18 -18.8042 0.83479E+00 -0.0784 48 FeCl+ 0.14036E-16 -16.8527 0.11740E-16 -16.9303 0.83640E+00 -0.0776 51 FeF+ 0.17644E-17 -17.7534 0.14758E-17 -17.8310 0.83640E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15784E-10 -10.8018 0.13202E-10 -10.8794 0.83640E+00 -0.0776 55 HFeO2- 0.35442E-07 -7.4505 0.29587E-07 -7.5289 0.83479E+00 -0.0784 56 FeO+ 0.11062E-16 -16.9561 0.92527E-17 -17.0337 0.83640E+00 -0.0776 58 FeO2- 0.40685E-09 -9.3906 0.33963E-09 -9.4690 0.83479E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99655E+00 -0.0015 61 KCl,aq 0.58500E-09 -9.2328 0.58500E-09 -9.2328 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.38944E-14 -14.4096 0.32510E-14 -14.4880 0.83479E+00 -0.0784 65 MgCO3,aq 0.14436E-12 -12.8406 0.14436E-12 -12.8406 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12244E-14 -14.9121 0.10240E-14 -14.9897 0.83640E+00 -0.0776 67 MgCl+ 0.47141E-14 -14.3266 0.39428E-14 -14.4042 0.83640E+00 -0.0776 68 MgF+ 0.67678E-15 -15.1696 0.56605E-15 -15.2471 0.83640E+00 -0.0776 69 MgOH+ 0.69308E-10 -10.1592 0.57969E-10 -10.2368 0.83640E+00 -0.0776 71 MnF+ 0.18675E-15 -15.7287 0.15620E-15 -15.8063 0.83640E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47085E-09 -9.3271 0.39382E-09 -9.4047 0.83640E+00 -0.0776 74 MnO2-2 0.20793E-10 -10.6821 0.10754E-10 -10.9684 0.51722E+00 -0.2863 75 HMnO2- 0.21073E-09 -9.6763 0.17591E-09 -9.7547 0.83479E+00 -0.0784 78 MnCl+ 0.17535E-13 -13.7561 0.14666E-13 -13.8337 0.83640E+00 -0.0776 80 NaCl,aq 0.13548E-05 -5.8681 0.13548E-05 -5.8681 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92868E-02 -2.0321 0.77384E-02 -2.1113 0.83328E+00 -0.0792 89 HPO3-2 0.16219E-14 -14.7900 0.83888E-15 -15.0763 0.51722E+00 -0.2863 91 H2PO3- 0.15045E-18 -18.8226 0.12560E-18 -18.9010 0.83479E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38308E-10 -10.4167 0.32010E-10 -10.4947 0.83559E+00 -0.0780 94 PO4-3 0.10509E-08 -8.9784 0.25397E-09 -9.5952 0.24167E+00 -0.6168 98 HP2O7-3 0.93313E-18 -18.0301 0.21487E-18 -18.6678 0.23027E+00 -0.6378 99 P2O7-4 0.89835E-17 -17.0466 0.68751E-18 -18.1627 0.76530E-01 -1.1162 100 H2S,aq 0.23463E-07 -7.6296 0.23382E-07 -7.6311 0.99655E+00 -0.0015 101 S2-2 0.37978E-13 -13.4205 0.19643E-13 -13.7068 0.51722E+00 -0.2863 107 SO3-2 0.45602E-17 -17.3410 0.23930E-17 -17.6211 0.52474E+00 -0.2801 108 HSO3- 0.13400E-19 -19.8729 0.11187E-19 -19.9513 0.83479E+00 -0.0784 109 HSO4- 0.13664E-18 -18.8644 0.11439E-18 -18.9416 0.83722E+00 -0.0772 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8889763E-10 -.2219213E-01 -.2232925E+02 0.0000 2 H2O 0.1000000E+01 0.5550510E+02 0.9981937E+06 0.0000 3 Cl- 0.2934121E-03 0.2947676E-03 0.1043213E+02 6.5160 4 SO4-- 0.3067271E-11 -.2251562E-03 -.2159106E+02 8.4552 5 HCO3- 0.4279092E-05 0.2346255E-03 0.1429117E+02 4.6805 6 HS- 0.1213669E-03 0.3465465E-03 0.1144096E+02 6.1326 7 Al+++ 0.9919448E-29 0.5284957E-05 0.1423469E+00 0.7390 8 H4SiO4 0.6959765E-03 0.1347221E-01 0.1292625E+04 -3.1574 9 Ca++ 0.1369771E-06 0.2378502E-06 0.9515903E-02 13.1018 10 Mg++ 0.2142964E-10 0.9412582E-10 0.2284388E-05 9.2942 11 Fe++ 0.5906373E-13 0.3607920E-07 0.2011394E-02 6.7350 12 K+ 0.1575872E-03 0.1583415E-03 0.6180651E+01 6.2467 13 Na+ 0.1999723E-01 0.2244425E-01 0.5150872E+03 8.3494 14 Mn++ 0.1895014E-10 0.2527771E-08 0.1386280E-03 9.2416 15 F- 0.1144779E-05 0.1148507E-05 0.2178121E-01 4.1063 16 HPO4-- 0.4483185E-07 0.4592105E-07 0.4399755E-02 12.6200 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279239E+02 -.1101531E-01 -.8278138E+02 0.0000000E+00 2 H2O -.7167618E+01 0.2755058E+02 -.3471820E+02 0.0000000E+00 3 Cl- 0.1463112E-03 0.1463112E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385993E+00 -.1117588E-03 0.1387111E+00 0.0000000E+00 5 HCO3- 0.1164590E-03 0.1164590E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385391E+00 0.1720122E-03 -.1387111E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2623247E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6687085E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1180596E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4672041E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1790832E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7859459E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1114046E-01 0.6265236E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254687E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6720000E-06 0.5700743E-06 0.1019257E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2279343E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1773E-13 Mass of aqueous solution: 0.497230E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0014300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5548 -0.256 282.0 2.450 5.162 73.26 grossular 0.1344 -0.872 60.52 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.1019E-06 -6.992 0.5140E-04 -4.289 0.9410E-06 0.1606E-04 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2600 -0.585 56.30 1.750 1.031 17.21 hedenbergite 0.6742E-01 -1.171 16.73 1.223 0.3062 4.581 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.5 2.449 5.154 97.24 tr.625ac.25prg.125 0.4337E-01 -1.363 37.07 1.569 0.6787 11.93 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338333 g Volume = 2210.781816 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0014300 moles log = -2.8447 Original solution: 1000.0103000 g Original solution / Rock added: 699307.90 (Water/Rock Ratio), log = 5.8447 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3623 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7517E+00 0.9823 0.1006E+01 0.1024E+01 CO2,gas 0.4467E-07 1.0035 0.6106E-07 0.6085E-07 CH4,gas 0.2371E+00 1.0093 0.3260E+00 0.3230E+00 H2,gas 0.1115E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4743E-06 0.9947 0.6428E-06 0.6462E-06 S2,gas 0.4923E-28 1.0000 0.6707E-28 0.6707E-28 CO,gas 0.1816E-12 1.0000 0.2475E-12 0.2475E-12 SO3,gas 0.2460E-47 1.0000 0.3351E-47 0.3351E-47 SO2,gas 0.1455E-26 1.0000 0.1982E-26 0.1982E-26 HF,gas 0.8785E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4340E-17 1.0000 0.5913E-17 0.5913E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.57 -8.91 -2.971 0.15219E+05 -7.214 3 CH4,gas 4.54 2.36 -2.19 -0.546 0.37321E+04 -0.487 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.12 -7.89 -3.945 0.13474E+05 -6.192 6 S2,gas -7.34 -37.21 -29.87 -4.596 0.51006E+05 -28.173 7 CO,gas 3.21 -11.09 -14.31 -4.402 0.24426E+05 -12.606 8 SO3,gas 17.12 -32.05 -49.17 -12.293 0.83963E+05 -47.475 9 SO2,gas 0.83 -27.57 -28.40 -7.574 0.48495E+05 -26.703 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.74 -18.93 -9.464 0.32318E+05 -17.228 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.47 -3.44 -1.146 0.58703E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.47 -3.28 -1.094 0.56061E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.61 -3.51 -1.002 0.59852E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.61 -3.06 -0.875 0.52274E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.99 -4.74 -1.116 0.80989E+04 146 pyrrhotite -4.26 -7.39 -3.13 -1.042 0.53373E+04 147 pyrrhotiteFe0.875 -6.02 -8.78 -2.77 -1.018 0.47245E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.39 -2.98 -0.992 0.50801E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.88 -3.90 -1.301 0.66620E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0014300 MOLES New total amount of reactant added: 0.0014700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0014700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1131125E-01 Osmotic coef. = 0.6866 True ionic strength = .2016527E-01 Chg. balance for total moles = -.8663E-10 Max. difference allowed = 0.1465E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88905E-10 -10.0511 0.74668E-10 -10.1269 0.83986E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29388E-03 -3.5318 0.24533E-03 -3.6102 0.83479E+00 -0.0784 4 SO4-- 0.31166E-11 -11.5063 0.16154E-11 -11.7917 0.51831E+00 -0.2854 5 HCO3- 0.43851E-05 -5.3580 0.36660E-05 -5.4358 0.83601E+00 -0.0778 6 HS- 0.12332E-03 -3.9090 0.10296E-03 -3.9873 0.83491E+00 -0.0784 7 Al+++ 0.99222E-29 -29.0034 0.22823E-29 -29.6416 0.23002E+00 -0.6382 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13700E-06 -6.8633 0.70485E-07 -7.1519 0.51449E+00 -0.2886 10 Mg++ 0.21433E-10 -10.6689 0.10976E-10 -10.9595 0.51212E+00 -0.2906 11 Fe++ 0.59074E-13 -13.2286 0.30286E-13 -13.5188 0.51268E+00 -0.2902 12 K+ 0.15760E-03 -3.8024 0.13179E-03 -3.8801 0.83621E+00 -0.0777 13 Na+ 0.19999E-01 -1.6990 0.16692E-01 -1.7775 0.83463E+00 -0.0785 14 Mn++ 0.18953E-10 -10.7223 0.97252E-11 -11.0121 0.51311E+00 -0.2898 15 F- 0.11447E-05 -5.9413 0.95360E-06 -6.0206 0.83306E+00 -0.0793 16 HPO4-- 0.44826E-07 -7.3485 0.23237E-07 -7.6338 0.51839E+00 -0.2853 18 HSiO3- 0.10426E-01 -1.9819 0.87034E-02 -2.0603 0.83479E+00 -0.0784 19 Ca(HSiO3)+ 0.16704E-07 -7.7772 0.13971E-07 -7.8548 0.83639E+00 -0.0776 20 Mg(HSiO3)+ 0.32372E-11 -11.4898 0.27076E-11 -11.5674 0.83639E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66584E-16 -16.1766 0.55691E-16 -16.2542 0.83639E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52845E-05 -5.2770 0.44034E-05 -5.3562 0.83327E+00 -0.0792 26 CH4,aq 0.22777E-03 -3.6425 0.22698E-03 -3.6440 0.99655E+00 -0.0015 27 C2H6,aq 0.76309E-12 -12.1174 0.76046E-12 -12.1189 0.99655E+00 -0.0015 28 C3H8,aq 0.59023E-19 -19.2290 0.58820E-19 -19.2305 0.99655E+00 -0.0015 30 ethanol,aq 0.28008E-19 -19.5527 0.27912E-19 -19.5542 0.99655E+00 -0.0015 31 CO,aq 0.17019E-15 -15.7691 0.17019E-15 -15.7691 0.10000E+01 0.0000 32 CO2,aq 0.58693E-09 -9.2314 0.58490E-09 -9.2329 0.99655E+00 -0.0015 33 CO3-2 0.82915E-05 -5.0814 0.42884E-05 -5.3677 0.51721E+00 -0.2863 34 CaCO3,aq 0.37901E-08 -8.4213 0.37901E-08 -8.4213 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.78861E-11 -11.1031 0.65959E-11 -11.1807 0.83639E+00 -0.0776 36 CaCl+ 0.33458E-10 -10.4755 0.27984E-10 -10.5531 0.83639E+00 -0.0776 37 CaCl2,aq 0.16311E-14 -14.7875 0.16311E-14 -14.7875 0.10000E+01 0.0000 38 CaF+ 0.11733E-11 -11.9306 0.98134E-12 -12.0082 0.83639E+00 -0.0776 39 CaOH+ 0.80437E-07 -7.0945 0.67277E-07 -7.1721 0.83639E+00 -0.0776 40 CaSO4,aq 0.36155E-16 -16.4418 0.36155E-16 -16.4418 0.10000E+01 0.0000 41 HCl,aq 0.33568E-14 -14.4741 0.33568E-14 -14.4741 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18799E-18 -18.7259 0.15694E-18 -18.8043 0.83479E+00 -0.0784 48 FeCl+ 0.14061E-16 -16.8520 0.11761E-16 -16.9296 0.83639E+00 -0.0776 51 FeF+ 0.17646E-17 -17.7534 0.14759E-17 -17.8310 0.83639E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15786E-10 -10.8017 0.13203E-10 -10.8793 0.83639E+00 -0.0776 55 HFeO2- 0.35440E-07 -7.4505 0.29585E-07 -7.5289 0.83479E+00 -0.0784 56 FeO+ 0.11063E-16 -16.9561 0.92533E-17 -17.0337 0.83639E+00 -0.0776 58 FeO2- 0.40682E-09 -9.3906 0.33961E-09 -9.4690 0.83479E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99655E+00 -0.0015 61 KCl,aq 0.58598E-09 -9.2321 0.58598E-09 -9.2321 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.39572E-14 -14.4026 0.33034E-14 -14.4810 0.83479E+00 -0.0784 65 MgCO3,aq 0.14794E-12 -12.8299 0.14794E-12 -12.8299 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12549E-14 -14.9014 0.10496E-14 -14.9790 0.83639E+00 -0.0776 67 MgCl+ 0.47224E-14 -14.3258 0.39497E-14 -14.4034 0.83639E+00 -0.0776 68 MgF+ 0.67683E-15 -15.1695 0.56610E-15 -15.2471 0.83639E+00 -0.0776 69 MgOH+ 0.69314E-10 -10.1592 0.57973E-10 -10.2368 0.83639E+00 -0.0776 71 MnF+ 0.18676E-15 -15.7287 0.15621E-15 -15.8063 0.83639E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47089E-09 -9.3271 0.39385E-09 -9.4047 0.83639E+00 -0.0776 74 MnO2-2 0.20790E-10 -10.6821 0.10753E-10 -10.9685 0.51721E+00 -0.2863 75 HMnO2- 0.21071E-09 -9.6763 0.17590E-09 -9.7547 0.83479E+00 -0.0784 78 MnCl+ 0.17566E-13 -13.7553 0.14692E-13 -13.8329 0.83639E+00 -0.0776 80 NaCl,aq 0.13571E-05 -5.8674 0.13571E-05 -5.8674 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92862E-02 -2.0322 0.77379E-02 -2.1114 0.83327E+00 -0.0792 89 HPO3-2 0.16217E-14 -14.7900 0.83876E-15 -15.0764 0.51721E+00 -0.2863 91 H2PO3- 0.15044E-18 -18.8226 0.12559E-18 -18.9010 0.83479E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38306E-10 -10.4167 0.32008E-10 -10.4947 0.83558E+00 -0.0780 94 PO4-3 0.10507E-08 -8.9785 0.25391E-09 -9.5953 0.24166E+00 -0.6168 98 HP2O7-3 0.93297E-18 -18.0301 0.21482E-18 -18.6679 0.23025E+00 -0.6378 99 P2O7-4 0.89817E-17 -17.0466 0.68731E-18 -18.1628 0.76523E-01 -1.1162 100 H2S,aq 0.23843E-07 -7.6226 0.23761E-07 -7.6241 0.99655E+00 -0.0015 101 S2-2 0.39214E-13 -13.4066 0.20282E-13 -13.6929 0.51721E+00 -0.2863 107 SO3-2 0.46335E-17 -17.3341 0.24314E-17 -17.6142 0.52473E+00 -0.2801 108 HSO3- 0.13617E-19 -19.8659 0.11367E-19 -19.9444 0.83479E+00 -0.0784 109 HSO4- 0.13884E-18 -18.8575 0.11624E-18 -18.9346 0.83721E+00 -0.0772 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8890469E-10 -.2219100E-01 -.2232810E+02 0.0000 2 H2O 0.1000000E+01 0.5550511E+02 0.9981936E+06 0.0000 3 Cl- 0.2938849E-03 0.2952426E-03 0.1044894E+02 6.5166 4 SO4-- 0.3116571E-11 -.2306762E-03 -.2212039E+02 8.4620 5 HCO3- 0.4385079E-05 0.2404516E-03 0.1464604E+02 4.6911 6 HS- 0.1233246E-03 0.3540246E-03 0.1168784E+02 6.1396 7 Al+++ 0.9922177E-29 0.5284600E-05 0.1423372E+00 0.7390 8 H4SiO4 0.6959764E-03 0.1347151E-01 0.1292557E+04 -3.1574 9 Ca++ 0.1370006E-06 0.2379735E-06 0.9520835E-02 13.1018 10 Mg++ 0.2143332E-10 0.9413821E-10 0.2284688E-05 9.2942 11 Fe++ 0.5907387E-13 0.3607678E-07 0.2011259E-02 6.7350 12 K+ 0.1575997E-03 0.1583540E-03 0.6181138E+01 6.2467 13 Na+ 0.1999882E-01 0.2244584E-01 0.5151236E+03 8.3494 14 Mn++ 0.1895347E-10 0.2527805E-08 0.1386298E-03 9.2416 15 F- 0.1144701E-05 0.1148430E-05 0.2177974E-01 4.1062 16 HPO4-- 0.4482630E-07 0.4591532E-07 0.4399204E-02 12.6199 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279239E+02 -.1101477E-01 -.8278137E+02 0.0000000E+00 2 H2O -.7167585E+01 0.2755062E+02 -.3471821E+02 0.0000000E+00 3 Cl- 0.1465472E-03 0.1465472E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385995E+00 -.1144989E-03 0.1387140E+00 0.0000000E+00 5 HCO3- 0.1193510E-03 0.1193510E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385383E+00 0.1757243E-03 -.1387140E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2623074E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6686744E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1181210E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4672662E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1790714E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7860091E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1114126E-01 0.6265236E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254706E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6880000E-06 0.5700368E-06 0.1179632E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2279061E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1917E-13 Mass of aqueous solution: 0.497231E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0014700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5549 -0.256 282.0 2.450 5.162 73.26 grossular 0.1344 -0.872 60.52 1.782 1.108 16.84 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.1180E-06 -6.928 0.5949E-04 -4.226 0.1089E-05 0.1858E-04 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2599 -0.585 56.28 1.750 1.030 17.20 hedenbergite 0.6740E-01 -1.171 16.72 1.223 0.3061 4.580 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.5 2.449 5.153 97.24 tr.625ac.25prg.125 0.4340E-01 -1.363 37.09 1.569 0.6791 11.94 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338345 g Volume = 2210.781926 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0014700 moles log = -2.8327 Original solution: 1000.0103000 g Original solution / Rock added: 680279.12 (Water/Rock Ratio), log = 5.8327 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3705 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7473E+00 0.9822 0.1006E+01 0.1024E+01 CO2,gas 0.4551E-07 1.0034 0.6258E-07 0.6237E-07 CH4,gas 0.2416E+00 1.0092 0.3341E+00 0.3311E+00 H2,gas 0.1109E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4792E-06 0.9947 0.6532E-06 0.6567E-06 S2,gas 0.5054E-28 1.0000 0.6926E-28 0.6926E-28 CO,gas 0.1851E-12 1.0000 0.2536E-12 0.2536E-12 SO3,gas 0.2485E-47 1.0000 0.3405E-47 0.3405E-47 SO2,gas 0.1470E-26 1.0000 0.2015E-26 0.2015E-26 HF,gas 0.8733E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4322E-17 1.0000 0.5923E-17 0.5923E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.56 -8.90 -2.968 0.15201E+05 -7.204 3 CH4,gas 4.54 2.37 -2.18 -0.544 0.37139E+04 -0.476 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.11 -7.88 -3.942 0.13462E+05 -6.185 6 S2,gas -7.34 -37.19 -29.86 -4.594 0.50983E+05 -28.160 7 CO,gas 3.21 -11.08 -14.29 -4.398 0.24408E+05 -12.596 8 SO3,gas 17.12 -32.05 -49.17 -12.292 0.83951E+05 -47.468 9 SO2,gas 0.83 -27.56 -28.39 -7.572 0.48483E+05 -26.696 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.74 -18.93 -9.463 0.32316E+05 -17.227 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.46 -3.43 -1.142 0.58521E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.46 -3.27 -1.091 0.55879E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.60 -3.49 -0.998 0.59670E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.60 -3.05 -0.872 0.52093E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.98 -4.73 -1.113 0.80751E+04 146 pyrrhotite -4.26 -7.38 -3.12 -1.040 0.53254E+04 147 pyrrhotiteFe0.875 -6.02 -8.78 -2.76 -1.015 0.47126E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.38 -2.97 -0.989 0.50682E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.87 -3.89 -1.298 0.66501E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0014700 MOLES New total amount of reactant added: 0.0015100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8664E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0015100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1130790E-01 Osmotic coef. = 0.7175 True ionic strength = .2016708E-01 Chg. balance for total moles = -.8664E-10 Max. difference allowed = 0.1468E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88912E-10 -10.0510 0.74673E-10 -10.1268 0.83986E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29436E-03 -3.5311 0.24572E-03 -3.6096 0.83478E+00 -0.0784 4 SO4-- 0.31659E-11 -11.4995 0.16409E-11 -11.7849 0.51830E+00 -0.2854 5 HCO3- 0.44911E-05 -5.3477 0.37546E-05 -5.4254 0.83601E+00 -0.0778 6 HS- 0.12528E-03 -3.9021 0.10460E-03 -3.9805 0.83490E+00 -0.0784 7 Al+++ 0.99249E-29 -29.0033 0.22828E-29 -29.6415 0.23001E+00 -0.6383 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13702E-06 -6.8632 0.70495E-07 -7.1518 0.51447E+00 -0.2886 10 Mg++ 0.21437E-10 -10.6688 0.10978E-10 -10.9595 0.51211E+00 -0.2906 11 Fe++ 0.59084E-13 -13.2285 0.30291E-13 -13.5187 0.51267E+00 -0.2902 12 K+ 0.15761E-03 -3.8024 0.13180E-03 -3.8801 0.83621E+00 -0.0777 13 Na+ 0.20000E-01 -1.6990 0.16693E-01 -1.7775 0.83463E+00 -0.0785 14 Mn++ 0.18957E-10 -10.7222 0.97267E-11 -11.0120 0.51310E+00 -0.2898 15 F- 0.11446E-05 -5.9413 0.95353E-06 -6.0207 0.83305E+00 -0.0793 16 HPO4-- 0.44821E-07 -7.3485 0.23234E-07 -7.6339 0.51838E+00 -0.2854 18 HSiO3- 0.10425E-01 -1.9819 0.87028E-02 -2.0603 0.83478E+00 -0.0784 19 Ca(HSiO3)+ 0.16705E-07 -7.7772 0.13972E-07 -7.8547 0.83639E+00 -0.0776 20 Mg(HSiO3)+ 0.32375E-11 -11.4898 0.27078E-11 -11.5674 0.83639E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66590E-16 -16.1766 0.55695E-16 -16.2542 0.83639E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52841E-05 -5.2770 0.44031E-05 -5.3562 0.83326E+00 -0.0792 26 CH4,aq 0.23329E-03 -3.6321 0.23249E-03 -3.6336 0.99655E+00 -0.0015 27 C2H6,aq 0.80053E-12 -12.0966 0.79776E-12 -12.0981 0.99655E+00 -0.0015 28 C3H8,aq 0.63420E-19 -19.1978 0.63201E-19 -19.1993 0.99655E+00 -0.0015 30 ethanol,aq 0.29382E-19 -19.5319 0.29281E-19 -19.5334 0.99655E+00 -0.0015 31 CO,aq 0.17431E-15 -15.7587 0.17431E-15 -15.7587 0.10000E+01 0.0000 32 CO2,aq 0.60115E-09 -9.2210 0.59908E-09 -9.2225 0.99655E+00 -0.0015 33 CO3-2 0.84914E-05 -5.0710 0.43917E-05 -5.3574 0.51720E+00 -0.2863 34 CaCO3,aq 0.38820E-08 -8.4109 0.38820E-08 -8.4109 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.80778E-11 -11.0927 0.67562E-11 -11.1703 0.83639E+00 -0.0776 36 CaCl+ 0.33517E-10 -10.4747 0.28033E-10 -10.5523 0.83639E+00 -0.0776 37 CaCl2,aq 0.16365E-14 -14.7861 0.16365E-14 -14.7861 0.10000E+01 0.0000 38 CaF+ 0.11734E-11 -11.9306 0.98141E-12 -12.0081 0.83639E+00 -0.0776 39 CaOH+ 0.80443E-07 -7.0945 0.67282E-07 -7.1721 0.83639E+00 -0.0776 40 CaSO4,aq 0.36732E-16 -16.4350 0.36732E-16 -16.4350 0.10000E+01 0.0000 41 HCl,aq 0.33624E-14 -14.4734 0.33624E-14 -14.4734 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18798E-18 -18.7259 0.15692E-18 -18.8043 0.83478E+00 -0.0784 48 FeCl+ 0.14086E-16 -16.8512 0.11781E-16 -16.9288 0.83639E+00 -0.0776 51 FeF+ 0.17647E-17 -17.7533 0.14760E-17 -17.8309 0.83639E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15787E-10 -10.8017 0.13204E-10 -10.8793 0.83639E+00 -0.0776 55 HFeO2- 0.35437E-07 -7.4505 0.29582E-07 -7.5290 0.83478E+00 -0.0784 56 FeO+ 0.11064E-16 -16.9561 0.92540E-17 -17.0337 0.83639E+00 -0.0776 58 FeO2- 0.40679E-09 -9.3906 0.33958E-09 -9.4691 0.83478E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99655E+00 -0.0015 61 KCl,aq 0.58696E-09 -9.2314 0.58696E-09 -9.2314 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.40200E-14 -14.3958 0.33559E-14 -14.4742 0.83478E+00 -0.0784 65 MgCO3,aq 0.15153E-12 -12.8195 0.15153E-12 -12.8195 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12854E-14 -14.8910 0.10751E-14 -14.9686 0.83639E+00 -0.0776 67 MgCl+ 0.47306E-14 -14.3251 0.39567E-14 -14.4027 0.83639E+00 -0.0776 68 MgF+ 0.67688E-15 -15.1695 0.56614E-15 -15.2471 0.83639E+00 -0.0776 69 MgOH+ 0.69319E-10 -10.1591 0.57978E-10 -10.2367 0.83639E+00 -0.0776 71 MnF+ 0.18678E-15 -15.7287 0.15622E-15 -15.8063 0.83639E+00 -0.0776 72 MnO,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47093E-09 -9.3270 0.39388E-09 -9.4046 0.83639E+00 -0.0776 74 MnO2-2 0.20788E-10 -10.6822 0.10751E-10 -10.9685 0.51720E+00 -0.2863 75 HMnO2- 0.21070E-09 -9.6763 0.17589E-09 -9.7548 0.83478E+00 -0.0784 78 MnCl+ 0.17597E-13 -13.7546 0.14718E-13 -13.8322 0.83639E+00 -0.0776 80 NaCl,aq 0.13594E-05 -5.8667 0.13594E-05 -5.8667 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92855E-02 -2.0322 0.77373E-02 -2.1114 0.83326E+00 -0.0792 89 HPO3-2 0.16215E-14 -14.7901 0.83863E-15 -15.0764 0.51720E+00 -0.2863 91 H2PO3- 0.15043E-18 -18.8227 0.12558E-18 -18.9011 0.83478E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38303E-10 -10.4168 0.32005E-10 -10.4948 0.83558E+00 -0.0780 94 PO4-3 0.10505E-08 -8.9786 0.25386E-09 -9.5954 0.24165E+00 -0.6168 98 HP2O7-3 0.93282E-18 -18.0302 0.21477E-18 -18.6680 0.23024E+00 -0.6378 99 P2O7-4 0.89799E-17 -17.0467 0.68710E-18 -18.1630 0.76516E-01 -1.1162 100 H2S,aq 0.24224E-07 -7.6158 0.24140E-07 -7.6173 0.99655E+00 -0.0015 101 S2-2 0.40469E-13 -13.3929 0.20931E-13 -13.6792 0.51720E+00 -0.2863 107 SO3-2 0.47068E-17 -17.3273 0.24698E-17 -17.6073 0.52472E+00 -0.2801 108 HSO3- 0.13833E-19 -19.8591 0.11547E-19 -19.9375 0.83478E+00 -0.0784 109 HSO4- 0.14104E-18 -18.8506 0.11808E-18 -18.9278 0.83721E+00 -0.0772 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8891175E-10 -.2218986E-01 -.2232696E+02 0.0000 2 H2O 0.1000000E+01 0.5550511E+02 0.9981936E+06 0.0000 3 Cl- 0.2943576E-03 0.2957176E-03 0.1046575E+02 6.5173 4 SO4-- 0.3165866E-11 -.2361962E-03 -.2264973E+02 8.4687 5 HCO3- 0.4491053E-05 0.2462776E-03 0.1500090E+02 4.7014 6 HS- 0.1252823E-03 0.3615027E-03 0.1193472E+02 6.1464 7 Al+++ 0.9924907E-29 0.5284244E-05 0.1423276E+00 0.7390 8 H4SiO4 0.6959763E-03 0.1347080E-01 0.1292489E+04 -3.1574 9 Ca++ 0.1370241E-06 0.2380969E-06 0.9525768E-02 13.1018 10 Mg++ 0.2143700E-10 0.9415239E-10 0.2285032E-05 9.2942 11 Fe++ 0.5908402E-13 0.3607435E-07 0.2011123E-02 6.7350 12 K+ 0.1576122E-03 0.1583665E-03 0.6181626E+01 6.2467 13 Na+ 0.2000042E-01 0.2244744E-01 0.5151601E+03 8.3494 14 Mn++ 0.1895680E-10 0.2527838E-08 0.1386317E-03 9.2416 15 F- 0.1144624E-05 0.1148352E-05 0.2177827E-01 4.1062 16 HPO4-- 0.4482074E-07 0.4590958E-07 0.4398654E-02 12.6198 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279238E+02 -.1101422E-01 -.8278137E+02 0.0000000E+00 2 H2O -.7167553E+01 0.2755067E+02 -.3471822E+02 0.0000000E+00 3 Cl- 0.1467832E-03 0.1467832E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385997E+00 -.1172390E-03 0.1387170E+00 0.0000000E+00 5 HCO3- 0.1222430E-03 0.1222430E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385375E+00 0.1794364E-03 -.1387170E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2622901E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6686403E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1181824E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4673373E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1790596E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7860724E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1114207E-01 0.6265235E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254725E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7040000E-06 0.5699992E-06 0.1340008E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2278780E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.8327E-15 Mass of aqueous solution: 0.497232E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0015100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5549 -0.256 282.0 2.450 5.162 73.26 grossular 0.1344 -0.872 60.52 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.1340E-06 -6.873 0.6758E-04 -4.170 0.1237E-05 0.2111E-04 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2598 -0.585 56.26 1.750 1.030 17.20 hedenbergite 0.6738E-01 -1.171 16.72 1.223 0.3060 4.579 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.5 2.449 5.153 97.23 tr.625ac.25prg.125 0.4342E-01 -1.362 37.12 1.570 0.6795 11.95 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338358 g Volume = 2210.782036 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0015100 moles log = -2.8210 Original solution: 1000.0103000 g Original solution / Rock added: 662258.48 (Water/Rock Ratio), log = 5.8210 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3786 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7430E+00 0.9821 0.1006E+01 0.1024E+01 CO2,gas 0.4634E-07 1.0033 0.6409E-07 0.6388E-07 CH4,gas 0.2460E+00 1.0092 0.3422E+00 0.3391E+00 H2,gas 0.1102E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4840E-06 0.9946 0.6636E-06 0.6672E-06 S2,gas 0.5185E-28 1.0000 0.7148E-28 0.7148E-28 CO,gas 0.1884E-12 1.0000 0.2598E-12 0.2598E-12 SO3,gas 0.2510E-47 1.0000 0.3460E-47 0.3460E-47 SO2,gas 0.1485E-26 1.0000 0.2047E-26 0.2047E-26 HF,gas 0.8682E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4304E-17 1.0000 0.5933E-17 0.5933E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.55 -8.89 -2.964 0.15183E+05 -7.193 3 CH4,gas 4.54 2.38 -2.16 -0.541 0.36961E+04 -0.466 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.11 -7.88 -3.939 0.13450E+05 -6.178 6 S2,gas -7.34 -37.18 -29.84 -4.592 0.50959E+05 -28.146 7 CO,gas 3.21 -11.07 -14.28 -4.395 0.24390E+05 -12.585 8 SO3,gas 17.12 -32.04 -49.16 -12.290 0.83939E+05 -47.461 9 SO2,gas 0.83 -27.56 -28.39 -7.570 0.48472E+05 -26.689 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.74 -18.93 -9.463 0.32315E+05 -17.227 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.45 -3.42 -1.139 0.58344E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.45 -3.26 -1.087 0.55702E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.59 -3.48 -0.995 0.59492E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.59 -3.04 -0.869 0.51915E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.96 -4.72 -1.110 0.80516E+04 146 pyrrhotite -4.26 -7.37 -3.11 -1.037 0.53137E+04 147 pyrrhotiteFe0.875 -6.02 -8.77 -2.75 -1.013 0.47009E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.37 -2.96 -0.987 0.50565E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.87 -3.89 -1.296 0.66383E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0015100 MOLES New total amount of reactant added: 0.0015500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8666E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0015500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7168E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1130454E-01 Osmotic coef. = 0.7412 True ionic strength = .2016888E-01 Chg. balance for total moles = -.8666E-10 Max. difference allowed = 0.1470E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88919E-10 -10.0510 0.74679E-10 -10.1268 0.83986E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29483E-03 -3.5304 0.24612E-03 -3.6089 0.83478E+00 -0.0784 4 SO4-- 0.32152E-11 -11.4928 0.16664E-11 -11.7782 0.51829E+00 -0.2854 5 HCO3- 0.45970E-05 -5.3375 0.38431E-05 -5.4153 0.83600E+00 -0.0778 6 HS- 0.12724E-03 -3.8954 0.10623E-03 -3.9737 0.83490E+00 -0.0784 7 Al+++ 0.99276E-29 -29.0032 0.22833E-29 -29.6414 0.23000E+00 -0.6383 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13705E-06 -6.8631 0.70506E-07 -7.1518 0.51446E+00 -0.2886 10 Mg++ 0.21441E-10 -10.6688 0.10980E-10 -10.9594 0.51210E+00 -0.2906 11 Fe++ 0.59094E-13 -13.2285 0.30295E-13 -13.5186 0.51266E+00 -0.2902 12 K+ 0.15762E-03 -3.8024 0.13181E-03 -3.8801 0.83620E+00 -0.0777 13 Na+ 0.20002E-01 -1.6989 0.16694E-01 -1.7774 0.83462E+00 -0.0785 14 Mn++ 0.18960E-10 -10.7222 0.97282E-11 -11.0120 0.51309E+00 -0.2898 15 F- 0.11445E-05 -5.9414 0.95346E-06 -6.0207 0.83305E+00 -0.0793 16 HPO4-- 0.44815E-07 -7.3486 0.23231E-07 -7.6339 0.51836E+00 -0.2854 18 HSiO3- 0.10424E-01 -1.9819 0.87021E-02 -2.0604 0.83478E+00 -0.0784 19 Ca(HSiO3)+ 0.16706E-07 -7.7771 0.13973E-07 -7.8547 0.83638E+00 -0.0776 20 Mg(HSiO3)+ 0.32378E-11 -11.4898 0.27080E-11 -11.5674 0.83638E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66595E-16 -16.1766 0.55699E-16 -16.2542 0.83638E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52837E-05 -5.2771 0.44027E-05 -5.3563 0.83326E+00 -0.0792 26 CH4,aq 0.23881E-03 -3.6219 0.23799E-03 -3.6234 0.99655E+00 -0.0015 27 C2H6,aq 0.83886E-12 -12.0763 0.83597E-12 -12.0778 0.99655E+00 -0.0015 28 C3H8,aq 0.68029E-19 -19.1673 0.67795E-19 -19.1688 0.99655E+00 -0.0015 30 ethanol,aq 0.30789E-19 -19.5116 0.30683E-19 -19.5131 0.99655E+00 -0.0015 31 CO,aq 0.17843E-15 -15.7485 0.17843E-15 -15.7485 0.10000E+01 0.0000 32 CO2,aq 0.61538E-09 -9.2109 0.61325E-09 -9.2124 0.99655E+00 -0.0015 33 CO3-2 0.86913E-05 -5.0609 0.44950E-05 -5.3473 0.51718E+00 -0.2864 34 CaCO3,aq 0.39739E-08 -8.4008 0.39739E-08 -8.4008 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.82696E-11 -11.0825 0.69166E-11 -11.1601 0.83638E+00 -0.0776 36 CaCl+ 0.33576E-10 -10.4740 0.28082E-10 -10.5516 0.83638E+00 -0.0776 37 CaCl2,aq 0.16420E-14 -14.7846 0.16420E-14 -14.7846 0.10000E+01 0.0000 38 CaF+ 0.11735E-11 -11.9305 0.98148E-12 -12.0081 0.83638E+00 -0.0776 39 CaOH+ 0.80449E-07 -7.0945 0.67287E-07 -7.1721 0.83638E+00 -0.0776 40 CaSO4,aq 0.37308E-16 -16.4282 0.37308E-16 -16.4282 0.10000E+01 0.0000 41 HCl,aq 0.33680E-14 -14.4726 0.33680E-14 -14.4726 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18797E-18 -18.7259 0.15691E-18 -18.8043 0.83478E+00 -0.0784 48 FeCl+ 0.14111E-16 -16.8505 0.11802E-16 -16.9280 0.83638E+00 -0.0776 51 FeF+ 0.17648E-17 -17.7533 0.14761E-17 -17.8309 0.83638E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15788E-10 -10.8017 0.13205E-10 -10.8793 0.83638E+00 -0.0776 55 HFeO2- 0.35435E-07 -7.4506 0.29580E-07 -7.5290 0.83478E+00 -0.0784 56 FeO+ 0.11065E-16 -16.9560 0.92547E-17 -17.0336 0.83638E+00 -0.0776 58 FeO2- 0.40677E-09 -9.3907 0.33956E-09 -9.4691 0.83478E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99655E+00 -0.0015 61 KCl,aq 0.58795E-09 -9.2307 0.58795E-09 -9.2307 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.40829E-14 -14.3890 0.34083E-14 -14.4675 0.83478E+00 -0.0784 65 MgCO3,aq 0.15512E-12 -12.8093 0.15512E-12 -12.8093 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13159E-14 -14.8808 0.11006E-14 -14.9584 0.83638E+00 -0.0776 67 MgCl+ 0.47389E-14 -14.3243 0.39636E-14 -14.4019 0.83638E+00 -0.0776 68 MgF+ 0.67694E-15 -15.1695 0.56618E-15 -15.2470 0.83638E+00 -0.0776 69 MgOH+ 0.69325E-10 -10.1591 0.57982E-10 -10.2367 0.83638E+00 -0.0776 71 MnF+ 0.18679E-15 -15.7286 0.15623E-15 -15.8062 0.83638E+00 -0.0776 72 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47097E-09 -9.3270 0.39391E-09 -9.4046 0.83638E+00 -0.0776 74 MnO2-2 0.20785E-10 -10.6822 0.10750E-10 -10.9686 0.51718E+00 -0.2864 75 HMnO2- 0.21069E-09 -9.6764 0.17588E-09 -9.7548 0.83478E+00 -0.0784 78 MnCl+ 0.17628E-13 -13.7538 0.14744E-13 -13.8314 0.83638E+00 -0.0776 80 NaCl,aq 0.13616E-05 -5.8659 0.13616E-05 -5.8659 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96046E-04 -4.0175 0.96046E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92849E-02 -2.0322 0.77367E-02 -2.1114 0.83326E+00 -0.0792 89 HPO3-2 0.16213E-14 -14.7901 0.83851E-15 -15.0765 0.51718E+00 -0.2864 91 H2PO3- 0.15042E-18 -18.8227 0.12557E-18 -18.9011 0.83478E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38301E-10 -10.4168 0.32003E-10 -10.4948 0.83557E+00 -0.0780 94 PO4-3 0.10504E-08 -8.9787 0.25380E-09 -9.5955 0.24163E+00 -0.6168 98 HP2O7-3 0.93266E-18 -18.0303 0.21473E-18 -18.6681 0.23023E+00 -0.6378 99 P2O7-4 0.89781E-17 -17.0468 0.68690E-18 -18.1631 0.76509E-01 -1.1163 100 H2S,aq 0.24604E-07 -7.6090 0.24519E-07 -7.6105 0.99655E+00 -0.0015 101 S2-2 0.41744E-13 -13.3794 0.21590E-13 -13.6658 0.51718E+00 -0.2864 107 SO3-2 0.47801E-17 -17.3206 0.25081E-17 -17.6006 0.52471E+00 -0.2801 108 HSO3- 0.14049E-19 -19.8524 0.11728E-19 -19.9308 0.83478E+00 -0.0784 109 HSO4- 0.14325E-18 -18.8439 0.11993E-18 -18.9211 0.83720E+00 -0.0772 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8891881E-10 -.2218873E-01 -.2232581E+02 0.0000 2 H2O 0.1000000E+01 0.5550512E+02 0.9981935E+06 0.0000 3 Cl- 0.2948304E-03 0.2961926E-03 0.1048256E+02 6.5179 4 SO4-- 0.3215156E-11 -.2417163E-03 -.2317907E+02 8.4754 5 HCO3- 0.4597013E-05 0.2521036E-03 0.1535577E+02 4.7115 6 HS- 0.1272400E-03 0.3689809E-03 0.1218160E+02 6.1531 7 Al+++ 0.9927637E-29 0.5283887E-05 0.1423180E+00 0.7390 8 H4SiO4 0.6959763E-03 0.1347010E-01 0.1292421E+04 -3.1574 9 Ca++ 0.1370476E-06 0.2382202E-06 0.9530701E-02 13.1018 10 Mg++ 0.2144068E-10 0.9416298E-10 0.2285289E-05 9.2942 11 Fe++ 0.5909417E-13 0.3607192E-07 0.2010987E-02 6.7350 12 K+ 0.1576247E-03 0.1583791E-03 0.6182113E+01 6.2467 13 Na+ 0.2000201E-01 0.2244903E-01 0.5151965E+03 8.3494 14 Mn++ 0.1896012E-10 0.2527872E-08 0.1386335E-03 9.2416 15 F- 0.1144547E-05 0.1148275E-05 0.2177680E-01 4.1061 16 HPO4-- 0.4481519E-07 0.4590384E-07 0.4398104E-02 12.6197 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279238E+02 -.1101367E-01 -.8278137E+02 0.0000000E+00 2 H2O -.7167520E+01 0.2755071E+02 -.3471823E+02 0.0000000E+00 3 Cl- 0.1470192E-03 0.1470192E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385999E+00 -.1199791E-03 0.1387199E+00 0.0000000E+00 5 HCO3- 0.1251350E-03 0.1251350E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385368E+00 0.1831486E-03 -.1387199E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2622728E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6686063E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1182438E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4673906E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1790478E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7861357E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1114288E-01 0.6265234E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254743E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7200000E-06 0.5699616E-06 0.1500384E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2278499E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.6967E-14 Mass of aqueous solution: 0.497233E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0015500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5549 -0.256 282.0 2.450 5.162 73.26 grossular 0.1344 -0.872 60.52 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.1500E-06 -6.824 0.7567E-04 -4.121 0.1385E-05 0.2364E-04 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2597 -0.585 56.25 1.750 1.030 17.19 hedenbergite 0.6736E-01 -1.172 16.71 1.223 0.3059 4.577 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.5 2.449 5.153 97.23 tr.625ac.25prg.125 0.4345E-01 -1.362 37.14 1.570 0.6799 11.95 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338371 g Volume = 2210.782147 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0015500 moles log = -2.8097 Original solution: 1000.0103000 g Original solution / Rock added: 645167.94 (Water/Rock Ratio), log = 5.8097 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3867 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7387E+00 0.9821 0.1006E+01 0.1024E+01 CO2,gas 0.4716E-07 1.0032 0.6561E-07 0.6540E-07 CH4,gas 0.2503E+00 1.0091 0.3503E+00 0.3471E+00 H2,gas 0.1096E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4887E-06 0.9946 0.6740E-06 0.6777E-06 S2,gas 0.5318E-28 1.0000 0.7374E-28 0.7374E-28 CO,gas 0.1918E-12 1.0000 0.2659E-12 0.2659E-12 SO3,gas 0.2534E-47 1.0000 0.3514E-47 0.3514E-47 SO2,gas 0.1499E-26 1.0000 0.2079E-26 0.2079E-26 HF,gas 0.8631E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4286E-17 1.0000 0.5943E-17 0.5943E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.54 -8.88 -2.961 0.15166E+05 -7.183 3 CH4,gas 4.54 2.39 -2.15 -0.539 0.36788E+04 -0.456 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.10 -7.87 -3.935 0.13438E+05 -6.171 6 S2,gas -7.34 -37.17 -29.83 -4.589 0.50936E+05 -28.132 7 CO,gas 3.21 -11.06 -14.27 -4.392 0.24373E+05 -12.575 8 SO3,gas 17.12 -32.03 -49.15 -12.288 0.83928E+05 -47.454 9 SO2,gas 0.83 -27.55 -28.38 -7.568 0.48460E+05 -26.682 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.74 -18.92 -9.462 0.32314E+05 -17.226 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.44 -3.41 -1.136 0.58170E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.44 -3.25 -1.084 0.55528E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.58 -3.47 -0.993 0.59319E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.58 -3.03 -0.866 0.51742E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.95 -4.70 -1.106 0.80285E+04 146 pyrrhotite -4.26 -7.37 -3.11 -1.035 0.53021E+04 147 pyrrhotiteFe0.875 -6.02 -8.76 -2.75 -1.010 0.46893E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.37 -2.95 -0.985 0.50449E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.86 -3.88 -1.294 0.66268E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0015500 MOLES New total amount of reactant added: 0.0015900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0015900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7167E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1130119E-01 Osmotic coef. = 0.7599 True ionic strength = .2017068E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.1473E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88926E-10 -10.0510 0.74684E-10 -10.1268 0.83985E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29530E-03 -3.5297 0.24651E-03 -3.6082 0.83477E+00 -0.0784 4 SO4-- 0.32644E-11 -11.4862 0.16919E-11 -11.7716 0.51828E+00 -0.2854 5 HCO3- 0.47030E-05 -5.3276 0.39317E-05 -5.4054 0.83600E+00 -0.0778 6 HS- 0.12920E-03 -3.8887 0.10787E-03 -3.9671 0.83489E+00 -0.0784 7 Al+++ 0.99304E-29 -29.0030 0.22838E-29 -29.6413 0.22999E+00 -0.6383 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13707E-06 -6.8631 0.70516E-07 -7.1517 0.51445E+00 -0.2887 10 Mg++ 0.21444E-10 -10.6687 0.10981E-10 -10.9593 0.51208E+00 -0.2907 11 Fe++ 0.59104E-13 -13.2284 0.30300E-13 -13.5186 0.51265E+00 -0.2902 12 K+ 0.15764E-03 -3.8023 0.13182E-03 -3.8800 0.83620E+00 -0.0777 13 Na+ 0.20004E-01 -1.6989 0.16695E-01 -1.7774 0.83462E+00 -0.0785 14 Mn++ 0.18963E-10 -10.7221 0.97297E-11 -11.0119 0.51307E+00 -0.2898 15 F- 0.11445E-05 -5.9414 0.95339E-06 -6.0207 0.83304E+00 -0.0793 16 HPO4-- 0.44810E-07 -7.3486 0.23227E-07 -7.6340 0.51835E+00 -0.2854 18 HSiO3- 0.10424E-01 -1.9820 0.87015E-02 -2.0604 0.83477E+00 -0.0784 19 Ca(HSiO3)+ 0.16708E-07 -7.7771 0.13974E-07 -7.8547 0.83638E+00 -0.0776 20 Mg(HSiO3)+ 0.32380E-11 -11.4897 0.27082E-11 -11.5673 0.83638E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66600E-16 -16.1765 0.55703E-16 -16.2541 0.83638E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52834E-05 -5.2771 0.44024E-05 -5.3563 0.83325E+00 -0.0792 26 CH4,aq 0.24433E-03 -3.6120 0.24349E-03 -3.6135 0.99655E+00 -0.0015 27 C2H6,aq 0.87809E-12 -12.0565 0.87506E-12 -12.0580 0.99655E+00 -0.0015 28 C3H8,aq 0.72857E-19 -19.1375 0.72606E-19 -19.1390 0.99655E+00 -0.0015 30 ethanol,aq 0.32229E-19 -19.4918 0.32118E-19 -19.4933 0.99655E+00 -0.0015 31 CO,aq 0.18256E-15 -15.7386 0.18256E-15 -15.7386 0.10000E+01 0.0000 32 CO2,aq 0.62960E-09 -9.2009 0.62743E-09 -9.2024 0.99655E+00 -0.0015 33 CO3-2 0.88911E-05 -5.0510 0.45982E-05 -5.3374 0.51717E+00 -0.2864 34 CaCO3,aq 0.40657E-08 -8.3909 0.40657E-08 -8.3909 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.84615E-11 -11.0726 0.70770E-11 -11.1502 0.83638E+00 -0.0776 36 CaCl+ 0.33634E-10 -10.4732 0.28131E-10 -10.5508 0.83638E+00 -0.0776 37 CaCl2,aq 0.16475E-14 -14.7832 0.16475E-14 -14.7832 0.10000E+01 0.0000 38 CaF+ 0.11736E-11 -11.9305 0.98156E-12 -12.0081 0.83638E+00 -0.0776 39 CaOH+ 0.80456E-07 -7.0944 0.67292E-07 -7.1720 0.83638E+00 -0.0776 40 CaSO4,aq 0.37885E-16 -16.4215 0.37885E-16 -16.4215 0.10000E+01 0.0000 41 HCl,aq 0.33736E-14 -14.4719 0.33736E-14 -14.4719 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18796E-18 -18.7259 0.15690E-18 -18.8044 0.83477E+00 -0.0784 48 FeCl+ 0.14135E-16 -16.8497 0.11822E-16 -16.9273 0.83638E+00 -0.0776 51 FeF+ 0.17650E-17 -17.7533 0.14762E-17 -17.8309 0.83638E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15789E-10 -10.8016 0.13206E-10 -10.8792 0.83638E+00 -0.0776 55 HFeO2- 0.35433E-07 -7.4506 0.29578E-07 -7.5290 0.83477E+00 -0.0784 56 FeO+ 0.11066E-16 -16.9560 0.92554E-17 -17.0336 0.83638E+00 -0.0776 58 FeO2- 0.40674E-09 -9.3907 0.33953E-09 -9.4691 0.83477E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99655E+00 -0.0015 61 KCl,aq 0.58893E-09 -9.2299 0.58893E-09 -9.2299 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.41457E-14 -14.3824 0.34607E-14 -14.4608 0.83477E+00 -0.0784 65 MgCO3,aq 0.15870E-12 -12.7994 0.15870E-12 -12.7994 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13464E-14 -14.8708 0.11261E-14 -14.9484 0.83638E+00 -0.0776 67 MgCl+ 0.47472E-14 -14.3236 0.39705E-14 -14.4012 0.83638E+00 -0.0776 68 MgF+ 0.67699E-15 -15.1694 0.56622E-15 -15.2470 0.83638E+00 -0.0776 69 MgOH+ 0.69330E-10 -10.1591 0.57986E-10 -10.2367 0.83638E+00 -0.0776 71 MnF+ 0.18681E-15 -15.7286 0.15624E-15 -15.8062 0.83638E+00 -0.0776 72 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47101E-09 -9.3270 0.39394E-09 -9.4046 0.83638E+00 -0.0776 74 MnO2-2 0.20783E-10 -10.6823 0.10748E-10 -10.9687 0.51717E+00 -0.2864 75 HMnO2- 0.21067E-09 -9.6764 0.17586E-09 -9.7548 0.83477E+00 -0.0784 78 MnCl+ 0.17659E-13 -13.7530 0.14770E-13 -13.8306 0.83638E+00 -0.0776 80 NaCl,aq 0.13639E-05 -5.8652 0.13639E-05 -5.8652 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92843E-02 -2.0323 0.77362E-02 -2.1115 0.83325E+00 -0.0792 89 HPO3-2 0.16211E-14 -14.7902 0.83839E-15 -15.0766 0.51717E+00 -0.2864 91 H2PO3- 0.15041E-18 -18.8227 0.12556E-18 -18.9011 0.83477E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38298E-10 -10.4168 0.32001E-10 -10.4948 0.83557E+00 -0.0780 94 PO4-3 0.10502E-08 -8.9787 0.25375E-09 -9.5956 0.24162E+00 -0.6169 98 HP2O7-3 0.93250E-18 -18.0303 0.21468E-18 -18.6682 0.23022E+00 -0.6379 99 P2O7-4 0.89763E-17 -17.0469 0.68670E-18 -18.1632 0.76502E-01 -1.1163 100 H2S,aq 0.24984E-07 -7.6023 0.24898E-07 -7.6038 0.99655E+00 -0.0015 101 S2-2 0.43039E-13 -13.3661 0.22259E-13 -13.6525 0.51717E+00 -0.2864 107 SO3-2 0.48534E-17 -17.3140 0.25465E-17 -17.5941 0.52470E+00 -0.2801 108 HSO3- 0.14265E-19 -19.8457 0.11908E-19 -19.9242 0.83477E+00 -0.0784 109 HSO4- 0.14545E-18 -18.8373 0.12177E-18 -18.9144 0.83720E+00 -0.0772 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8892587E-10 -.2218759E-01 -.2232467E+02 0.0000 2 H2O 0.1000000E+01 0.5550512E+02 0.9981934E+06 0.0000 3 Cl- 0.2953031E-03 0.2966677E-03 0.1049937E+02 6.5186 4 SO4-- 0.3264439E-11 -.2472364E-03 -.2370841E+02 8.4819 5 HCO3- 0.4702960E-05 0.2579296E-03 0.1571063E+02 4.7213 6 HS- 0.1291976E-03 0.3764590E-03 0.1242849E+02 6.1597 7 Al+++ 0.9930367E-29 0.5283531E-05 0.1423084E+00 0.7390 8 H4SiO4 0.6959762E-03 0.1346939E-01 0.1292353E+04 -3.1574 9 Ca++ 0.1370711E-06 0.2383436E-06 0.9535634E-02 13.1018 10 Mg++ 0.2144436E-10 0.9417805E-10 0.2285654E-05 9.2942 11 Fe++ 0.5910432E-13 0.3606950E-07 0.2010852E-02 6.7350 12 K+ 0.1576372E-03 0.1583916E-03 0.6182601E+01 6.2467 13 Na+ 0.2000360E-01 0.2245062E-01 0.5152330E+03 8.3494 14 Mn++ 0.1896345E-10 0.2527906E-08 0.1386353E-03 9.2416 15 F- 0.1144469E-05 0.1148198E-05 0.2177533E-01 4.1060 16 HPO4-- 0.4480963E-07 0.4589811E-07 0.4397553E-02 12.6195 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279238E+02 -.1101312E-01 -.8278136E+02 0.0000000E+00 2 H2O -.7167487E+01 0.2755075E+02 -.3471824E+02 0.0000000E+00 3 Cl- 0.1472552E-03 0.1472552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386001E+00 -.1227193E-03 0.1387228E+00 0.0000000E+00 5 HCO3- 0.1280270E-03 0.1280270E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385360E+00 0.1868608E-03 -.1387228E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2622555E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6685723E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1183052E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4674661E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1790360E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7861989E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1114368E-01 0.6265233E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254762E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7360000E-06 0.5699241E-06 0.1660759E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2278217E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.2359E-14 Mass of aqueous solution: 0.497233E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0015900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5549 -0.256 282.0 2.450 5.162 73.26 grossular 0.1344 -0.872 60.52 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.1661E-06 -6.780 0.8375E-04 -4.077 0.1533E-05 0.2616E-04 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2597 -0.586 56.23 1.750 1.029 17.19 hedenbergite 0.6734E-01 -1.172 16.71 1.223 0.3059 4.576 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.5 2.449 5.153 97.23 tr.625ac.25prg.125 0.4347E-01 -1.362 37.16 1.570 0.6803 11.96 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338383 g Volume = 2210.782257 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0015900 moles log = -2.7986 Original solution: 1000.0103000 g Original solution / Rock added: 628937.30 (Water/Rock Ratio), log = 5.7986 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.3948 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7344E+00 0.9820 0.1006E+01 0.1024E+01 CO2,gas 0.4798E-07 1.0032 0.6713E-07 0.6692E-07 CH4,gas 0.2547E+00 1.0090 0.3584E+00 0.3552E+00 H2,gas 0.1089E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4934E-06 0.9946 0.6844E-06 0.6881E-06 S2,gas 0.5452E-28 1.0000 0.7604E-28 0.7604E-28 CO,gas 0.1950E-12 1.0000 0.2720E-12 0.2720E-12 SO3,gas 0.2558E-47 1.0000 0.3568E-47 0.3568E-47 SO2,gas 0.1513E-26 1.0000 0.2111E-26 0.2111E-26 HF,gas 0.8581E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4268E-17 1.0000 0.5953E-17 0.5953E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.53 -8.87 -2.957 0.15149E+05 -7.173 3 CH4,gas 4.54 2.40 -2.14 -0.536 0.36619E+04 -0.446 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.09 -7.86 -3.932 0.13427E+05 -6.165 6 S2,gas -7.34 -37.15 -29.82 -4.587 0.50913E+05 -28.119 7 CO,gas 3.21 -11.05 -14.26 -4.389 0.24356E+05 -12.565 8 SO3,gas 17.12 -32.03 -49.15 -12.287 0.83916E+05 -47.448 9 SO2,gas 0.83 -27.54 -28.37 -7.567 0.48449E+05 -26.676 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.73 -18.92 -9.462 0.32313E+05 -17.225 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.43 -3.40 -1.132 0.58001E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.43 -3.24 -1.081 0.55359E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.57 -3.46 -0.990 0.59150E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.57 -3.02 -0.863 0.51572E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.94 -4.69 -1.103 0.80058E+04 146 pyrrhotite -4.26 -7.36 -3.10 -1.033 0.52908E+04 147 pyrrhotiteFe0.875 -6.02 -8.76 -2.74 -1.008 0.46780E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.36 -2.95 -0.983 0.50336E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.85 -3.87 -1.291 0.66154E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0015900 MOLES New total amount of reactant added: 0.0016300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0016300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7167E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1129784E-01 Osmotic coef. = 0.7751 True ionic strength = .2017248E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.1475E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88933E-10 -10.0509 0.74690E-10 -10.1267 0.83985E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29578E-03 -3.5290 0.24690E-03 -3.6075 0.83477E+00 -0.0784 4 SO4-- 0.33137E-11 -11.4797 0.17174E-11 -11.7651 0.51827E+00 -0.2854 5 HCO3- 0.48089E-05 -5.3180 0.40202E-05 -5.3958 0.83599E+00 -0.0778 6 HS- 0.13116E-03 -3.8822 0.10950E-03 -3.9606 0.83489E+00 -0.0784 7 Al+++ 0.99331E-29 -29.0029 0.22843E-29 -29.6412 0.22997E+00 -0.6383 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13709E-06 -6.8630 0.70527E-07 -7.1516 0.51444E+00 -0.2887 10 Mg++ 0.21448E-10 -10.6686 0.10983E-10 -10.9593 0.51207E+00 -0.2907 11 Fe++ 0.59114E-13 -13.2283 0.30304E-13 -13.5185 0.51263E+00 -0.2902 12 K+ 0.15765E-03 -3.8023 0.13183E-03 -3.8800 0.83619E+00 -0.0777 13 Na+ 0.20005E-01 -1.6989 0.16697E-01 -1.7774 0.83461E+00 -0.0785 14 Mn++ 0.18967E-10 -10.7220 0.97311E-11 -11.0118 0.51306E+00 -0.2898 15 F- 0.11444E-05 -5.9414 0.95332E-06 -6.0208 0.83304E+00 -0.0793 16 HPO4-- 0.44804E-07 -7.3487 0.23224E-07 -7.6341 0.51834E+00 -0.2854 18 HSiO3- 0.10423E-01 -1.9820 0.87008E-02 -2.0604 0.83477E+00 -0.0784 19 Ca(HSiO3)+ 0.16709E-07 -7.7771 0.13975E-07 -7.8547 0.83637E+00 -0.0776 20 Mg(HSiO3)+ 0.32383E-11 -11.4897 0.27084E-11 -11.5673 0.83637E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66606E-16 -16.1765 0.55707E-16 -16.2541 0.83637E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52830E-05 -5.2771 0.44021E-05 -5.3563 0.83325E+00 -0.0792 26 CH4,aq 0.24985E-03 -3.6023 0.24899E-03 -3.6038 0.99655E+00 -0.0015 27 C2H6,aq 0.91821E-12 -12.0371 0.91505E-12 -12.0386 0.99655E+00 -0.0015 28 C3H8,aq 0.77908E-19 -19.1084 0.77639E-19 -19.1099 0.99655E+00 -0.0015 30 ethanol,aq 0.33702E-19 -19.4723 0.33586E-19 -19.4738 0.99655E+00 -0.0015 31 CO,aq 0.18668E-15 -15.7289 0.18668E-15 -15.7289 0.10000E+01 0.0000 32 CO2,aq 0.64383E-09 -9.1912 0.64161E-09 -9.1927 0.99655E+00 -0.0015 33 CO3-2 0.90909E-05 -5.0414 0.47014E-05 -5.3278 0.51716E+00 -0.2864 34 CaCO3,aq 0.41576E-08 -8.3812 0.41576E-08 -8.3812 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.86533E-11 -11.0628 0.72374E-11 -11.1404 0.83637E+00 -0.0776 36 CaCl+ 0.33693E-10 -10.4725 0.28180E-10 -10.5501 0.83637E+00 -0.0776 37 CaCl2,aq 0.16530E-14 -14.7817 0.16530E-14 -14.7817 0.10000E+01 0.0000 38 CaF+ 0.11737E-11 -11.9305 0.98163E-12 -12.0081 0.83637E+00 -0.0776 39 CaOH+ 0.80462E-07 -7.0944 0.67297E-07 -7.1720 0.83637E+00 -0.0776 40 CaSO4,aq 0.38462E-16 -16.4150 0.38462E-16 -16.4150 0.10000E+01 0.0000 41 HCl,aq 0.33793E-14 -14.4712 0.33793E-14 -14.4712 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18794E-18 -18.7260 0.15689E-18 -18.8044 0.83477E+00 -0.0784 48 FeCl+ 0.14160E-16 -16.8489 0.11843E-16 -16.9265 0.83637E+00 -0.0776 51 FeF+ 0.17651E-17 -17.7532 0.14763E-17 -17.8308 0.83637E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15791E-10 -10.8016 0.13207E-10 -10.8792 0.83637E+00 -0.0776 55 HFeO2- 0.35430E-07 -7.4506 0.29576E-07 -7.5291 0.83477E+00 -0.0784 56 FeO+ 0.11067E-16 -16.9560 0.92561E-17 -17.0336 0.83637E+00 -0.0776 58 FeO2- 0.40671E-09 -9.3907 0.33951E-09 -9.4692 0.83477E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99655E+00 -0.0015 61 KCl,aq 0.58991E-09 -9.2292 0.58991E-09 -9.2292 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.42085E-14 -14.3759 0.35131E-14 -14.4543 0.83477E+00 -0.0784 65 MgCO3,aq 0.16229E-12 -12.7897 0.16229E-12 -12.7897 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13770E-14 -14.8611 0.11517E-14 -14.9387 0.83637E+00 -0.0776 67 MgCl+ 0.47555E-14 -14.3228 0.39774E-14 -14.4004 0.83637E+00 -0.0776 68 MgF+ 0.67705E-15 -15.1694 0.56626E-15 -15.2470 0.83637E+00 -0.0776 69 MgOH+ 0.69336E-10 -10.1590 0.57990E-10 -10.2366 0.83637E+00 -0.0776 71 MnF+ 0.18683E-15 -15.7286 0.15626E-15 -15.8062 0.83637E+00 -0.0776 72 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47105E-09 -9.3269 0.39397E-09 -9.4045 0.83637E+00 -0.0776 74 MnO2-2 0.20780E-10 -10.6823 0.10747E-10 -10.9687 0.51716E+00 -0.2864 75 HMnO2- 0.21066E-09 -9.6764 0.17585E-09 -9.7549 0.83477E+00 -0.0784 78 MnCl+ 0.17690E-13 -13.7523 0.14795E-13 -13.8299 0.83637E+00 -0.0776 80 NaCl,aq 0.13662E-05 -5.8645 0.13662E-05 -5.8645 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92836E-02 -2.0323 0.77356E-02 -2.1115 0.83325E+00 -0.0792 89 HPO3-2 0.16209E-14 -14.7902 0.83826E-15 -15.0766 0.51716E+00 -0.2864 91 H2PO3- 0.15040E-18 -18.8227 0.12555E-18 -18.9012 0.83477E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38296E-10 -10.4169 0.31998E-10 -10.4949 0.83556E+00 -0.0780 94 PO4-3 0.10500E-08 -8.9788 0.25369E-09 -9.5957 0.24161E+00 -0.6169 98 HP2O7-3 0.93235E-18 -18.0304 0.21463E-18 -18.6683 0.23020E+00 -0.6379 99 P2O7-4 0.89745E-17 -17.0470 0.68650E-18 -18.1634 0.76494E-01 -1.1164 100 H2S,aq 0.25364E-07 -7.5958 0.25277E-07 -7.5973 0.99655E+00 -0.0015 101 S2-2 0.44354E-13 -13.3531 0.22938E-13 -13.6394 0.51716E+00 -0.2864 107 SO3-2 0.49266E-17 -17.3075 0.25849E-17 -17.5876 0.52468E+00 -0.2801 108 HSO3- 0.14481E-19 -19.8392 0.12088E-19 -19.9176 0.83477E+00 -0.0784 109 HSO4- 0.14766E-18 -18.8307 0.12362E-18 -18.9079 0.83719E+00 -0.0772 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8893292E-10 -.2218646E-01 -.2232352E+02 0.0000 2 H2O 0.1000000E+01 0.5550513E+02 0.9981934E+06 0.0000 3 Cl- 0.2957759E-03 0.2971427E-03 0.1051618E+02 6.5193 4 SO4-- 0.3313717E-11 -.2527566E-03 -.2423775E+02 8.4883 5 HCO3- 0.4808894E-05 0.2637556E-03 0.1606549E+02 4.7310 6 HS- 0.1311553E-03 0.3839373E-03 0.1267537E+02 6.1662 7 Al+++ 0.9933098E-29 0.5283175E-05 0.1422988E+00 0.7390 8 H4SiO4 0.6959761E-03 0.1346869E-01 0.1292285E+04 -3.1574 9 Ca++ 0.1370946E-06 0.2384669E-06 0.9540567E-02 13.1018 10 Mg++ 0.2144805E-10 0.9419134E-10 0.2285976E-05 9.2942 11 Fe++ 0.5911447E-13 0.3606707E-07 0.2010716E-02 6.7350 12 K+ 0.1576498E-03 0.1584041E-03 0.6183088E+01 6.2467 13 Na+ 0.2000519E-01 0.2245221E-01 0.5152694E+03 8.3494 14 Mn++ 0.1896678E-10 0.2527939E-08 0.1386371E-03 9.2416 15 F- 0.1144392E-05 0.1148120E-05 0.2177386E-01 4.1060 16 HPO4-- 0.4480408E-07 0.4589237E-07 0.4397003E-02 12.6194 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279237E+02 -.1101258E-01 -.8278136E+02 0.0000000E+00 2 H2O -.7167454E+01 0.2755080E+02 -.3471825E+02 0.0000000E+00 3 Cl- 0.1474912E-03 0.1474912E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386003E+00 -.1254595E-03 0.1387258E+00 0.0000000E+00 5 HCO3- 0.1309190E-03 0.1309190E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385352E+00 0.1905730E-03 -.1387258E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2622382E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6685382E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1183666E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4675327E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1790243E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7862622E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1114449E-01 0.6265232E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254780E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7520000E-06 0.5698866E-06 0.1821134E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2277936E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.3011E-14 Mass of aqueous solution: 0.497234E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0016300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5549 -0.256 282.0 2.450 5.162 73.26 grossular 0.1344 -0.872 60.52 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.1821E-06 -6.740 0.9184E-04 -4.037 0.1681E-05 0.2869E-04 clinochlore 0.7102 -0.149 394.8 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2596 -0.586 56.21 1.750 1.029 17.18 hedenbergite 0.6732E-01 -1.172 16.70 1.223 0.3058 4.575 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.5 2.449 5.153 97.23 tr.625ac.25prg.125 0.4350E-01 -1.362 37.18 1.570 0.6807 11.97 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338396 g Volume = 2210.782367 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0016300 moles log = -2.7878 Original solution: 1000.0103000 g Original solution / Rock added: 613503.25 (Water/Rock Ratio), log = 5.7878 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.4029 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7302E+00 0.9819 0.1006E+01 0.1024E+01 CO2,gas 0.4878E-07 1.0031 0.6864E-07 0.6843E-07 CH4,gas 0.2589E+00 1.0090 0.3665E+00 0.3632E+00 H2,gas 0.1083E-01 1.0007 0.1521E-01 0.1520E-01 H2S,gas 0.4980E-06 0.9946 0.6948E-06 0.6986E-06 S2,gas 0.5586E-28 1.0000 0.7837E-28 0.7837E-28 CO,gas 0.1983E-12 1.0000 0.2782E-12 0.2782E-12 SO3,gas 0.2582E-47 1.0000 0.3622E-47 0.3622E-47 SO2,gas 0.1528E-26 1.0000 0.2143E-26 0.2143E-26 HF,gas 0.8531E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4250E-17 1.0000 0.5963E-17 0.5963E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.60662E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.60662E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.52 -8.86 -2.954 0.15132E+05 -7.163 3 CH4,gas 4.54 2.41 -2.13 -0.534 0.36453E+04 -0.436 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.09 -7.86 -3.929 0.13416E+05 -6.158 6 S2,gas -7.34 -37.14 -29.80 -4.585 0.50891E+05 -28.106 7 CO,gas 3.21 -11.04 -14.25 -4.386 0.24339E+05 -12.556 8 SO3,gas 17.12 -32.02 -49.14 -12.285 0.83905E+05 -47.441 9 SO2,gas 0.83 -27.54 -28.37 -7.565 0.48437E+05 -26.669 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.73 -18.92 -9.462 0.32311E+05 -17.225 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.42 -3.39 -1.129 0.57835E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.42 -3.23 -1.077 0.55193E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.56 -3.45 -0.987 0.58984E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.56 -3.01 -0.860 0.51406E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.92 -4.68 -1.100 0.79834E+04 146 pyrrhotite -4.26 -7.35 -3.09 -1.031 0.52795E+04 147 pyrrhotiteFe0.875 -6.02 -8.75 -2.73 -1.005 0.46668E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.35 -2.94 -0.980 0.50224E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.85 -3.87 -1.289 0.66042E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0016300 MOLES New total amount of reactant added: 0.0016700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8667E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0016700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7167E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1129449E-01 Osmotic coef. = 0.7876 True ionic strength = .2017429E-01 Chg. balance for total moles = -.8667E-10 Max. difference allowed = 0.1477E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88940E-10 -10.0509 0.74695E-10 -10.1267 0.83984E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29625E-03 -3.5283 0.24730E-03 -3.6068 0.83476E+00 -0.0784 4 SO4-- 0.33630E-11 -11.4733 0.17429E-11 -11.7587 0.51825E+00 -0.2855 5 HCO3- 0.49148E-05 -5.3085 0.41087E-05 -5.3863 0.83599E+00 -0.0778 6 HS- 0.13311E-03 -3.8758 0.11113E-03 -3.9542 0.83488E+00 -0.0784 7 Al+++ 0.99358E-29 -29.0028 0.22848E-29 -29.6411 0.22996E+00 -0.6383 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13712E-06 -6.8629 0.70537E-07 -7.1516 0.51443E+00 -0.2887 10 Mg++ 0.21452E-10 -10.6685 0.10985E-10 -10.9592 0.51206E+00 -0.2907 11 Fe++ 0.59125E-13 -13.2282 0.30309E-13 -13.5184 0.51262E+00 -0.2902 12 K+ 0.15766E-03 -3.8023 0.13184E-03 -3.8800 0.83619E+00 -0.0777 13 Na+ 0.20007E-01 -1.6988 0.16698E-01 -1.7773 0.83461E+00 -0.0785 14 Mn++ 0.18970E-10 -10.7219 0.97326E-11 -11.0118 0.51305E+00 -0.2898 15 F- 0.11443E-05 -5.9415 0.95325E-06 -6.0208 0.83303E+00 -0.0793 16 HPO4-- 0.44799E-07 -7.3487 0.23220E-07 -7.6341 0.51833E+00 -0.2854 18 HSiO3- 0.10422E-01 -1.9820 0.87002E-02 -2.0605 0.83476E+00 -0.0784 19 Ca(HSiO3)+ 0.16710E-07 -7.7770 0.13976E-07 -7.8546 0.83637E+00 -0.0776 20 Mg(HSiO3)+ 0.32385E-11 -11.4897 0.27086E-11 -11.5673 0.83637E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66611E-16 -16.1765 0.55711E-16 -16.2541 0.83637E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52827E-05 -5.2771 0.44018E-05 -5.3564 0.83324E+00 -0.0792 26 CH4,aq 0.25537E-03 -3.5928 0.25449E-03 -3.5943 0.99656E+00 -0.0015 27 C2H6,aq 0.95924E-12 -12.0181 0.95593E-12 -12.0196 0.99656E+00 -0.0015 28 C3H8,aq 0.83187E-19 -19.0799 0.82900E-19 -19.0814 0.99656E+00 -0.0015 30 ethanol,aq 0.35208E-19 -19.4534 0.35086E-19 -19.4549 0.99656E+00 -0.0015 31 CO,aq 0.19081E-15 -15.7194 0.19081E-15 -15.7194 0.10000E+01 0.0000 32 CO2,aq 0.65805E-09 -9.1817 0.65578E-09 -9.1832 0.99656E+00 -0.0015 33 CO3-2 0.92906E-05 -5.0320 0.48046E-05 -5.3183 0.51715E+00 -0.2864 34 CaCO3,aq 0.42495E-08 -8.3717 0.42495E-08 -8.3717 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.88452E-11 -11.0533 0.73979E-11 -11.1309 0.83637E+00 -0.0776 36 CaCl+ 0.33752E-10 -10.4717 0.28229E-10 -10.5493 0.83637E+00 -0.0776 37 CaCl2,aq 0.16585E-14 -14.7803 0.16585E-14 -14.7803 0.10000E+01 0.0000 38 CaF+ 0.11738E-11 -11.9304 0.98170E-12 -12.0080 0.83637E+00 -0.0776 39 CaOH+ 0.80469E-07 -7.0944 0.67301E-07 -7.1720 0.83637E+00 -0.0776 40 CaSO4,aq 0.39038E-16 -16.4085 0.39038E-16 -16.4085 0.10000E+01 0.0000 41 HCl,aq 0.33849E-14 -14.4705 0.33849E-14 -14.4705 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18793E-18 -18.7260 0.15688E-18 -18.8044 0.83476E+00 -0.0784 48 FeCl+ 0.14185E-16 -16.8482 0.11864E-16 -16.9258 0.83637E+00 -0.0776 51 FeF+ 0.17653E-17 -17.7532 0.14764E-17 -17.8308 0.83637E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15792E-10 -10.8016 0.13208E-10 -10.8792 0.83637E+00 -0.0776 55 HFeO2- 0.35428E-07 -7.4507 0.29574E-07 -7.5291 0.83476E+00 -0.0784 56 FeO+ 0.11068E-16 -16.9559 0.92568E-17 -17.0335 0.83637E+00 -0.0776 58 FeO2- 0.40668E-09 -9.3907 0.33948E-09 -9.4692 0.83476E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99656E+00 -0.0015 61 KCl,aq 0.59089E-09 -9.2285 0.59089E-09 -9.2285 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.42713E-14 -14.3694 0.35655E-14 -14.4479 0.83476E+00 -0.0784 65 MgCO3,aq 0.16587E-12 -12.7802 0.16587E-12 -12.7802 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14075E-14 -14.8516 0.11772E-14 -14.9292 0.83637E+00 -0.0776 67 MgCl+ 0.47638E-14 -14.3220 0.39843E-14 -14.3996 0.83637E+00 -0.0776 68 MgF+ 0.67710E-15 -15.1693 0.56630E-15 -15.2469 0.83637E+00 -0.0776 69 MgOH+ 0.69341E-10 -10.1590 0.57995E-10 -10.2366 0.83637E+00 -0.0776 71 MnF+ 0.18684E-15 -15.7285 0.15627E-15 -15.8061 0.83637E+00 -0.0776 72 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47109E-09 -9.3269 0.39400E-09 -9.4045 0.83637E+00 -0.0776 74 MnO2-2 0.20778E-10 -10.6824 0.10745E-10 -10.9688 0.51715E+00 -0.2864 75 HMnO2- 0.21065E-09 -9.6764 0.17584E-09 -9.7549 0.83476E+00 -0.0784 78 MnCl+ 0.17721E-13 -13.7515 0.14821E-13 -13.8291 0.83637E+00 -0.0776 80 NaCl,aq 0.13685E-05 -5.8638 0.13685E-05 -5.8638 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92830E-02 -2.0323 0.77350E-02 -2.1115 0.83324E+00 -0.0792 89 HPO3-2 0.16207E-14 -14.7903 0.83814E-15 -15.0767 0.51715E+00 -0.2864 91 H2PO3- 0.15039E-18 -18.8228 0.12554E-18 -18.9012 0.83476E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38293E-10 -10.4169 0.31996E-10 -10.4949 0.83556E+00 -0.0780 94 PO4-3 0.10498E-08 -8.9789 0.25363E-09 -9.5958 0.24160E+00 -0.6169 98 HP2O7-3 0.93219E-18 -18.0305 0.21458E-18 -18.6684 0.23019E+00 -0.6379 99 P2O7-4 0.89727E-17 -17.0471 0.68630E-18 -18.1635 0.76487E-01 -1.1164 100 H2S,aq 0.25745E-07 -7.5893 0.25656E-07 -7.5908 0.99656E+00 -0.0015 101 S2-2 0.45689E-13 -13.3402 0.23628E-13 -13.6266 0.51715E+00 -0.2864 107 SO3-2 0.49999E-17 -17.3010 0.26233E-17 -17.5812 0.52467E+00 -0.2801 108 HSO3- 0.14697E-19 -19.8328 0.12269E-19 -19.9112 0.83476E+00 -0.0784 109 HSO4- 0.14986E-18 -18.8243 0.12546E-18 -18.9015 0.83719E+00 -0.0772 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8893998E-10 -.2218532E-01 -.2232238E+02 0.0000 2 H2O 0.1000000E+01 0.5550514E+02 0.9981933E+06 0.0000 3 Cl- 0.2962486E-03 0.2976177E-03 0.1053299E+02 6.5199 4 SO4-- 0.3362989E-11 -.2582768E-03 -.2476710E+02 8.4947 5 HCO3- 0.4914815E-05 0.2695815E-03 0.1642035E+02 4.7404 6 HS- 0.1331130E-03 0.3914155E-03 0.1292226E+02 6.1726 7 Al+++ 0.9935830E-29 0.5282818E-05 0.1422891E+00 0.7390 8 H4SiO4 0.6959760E-03 0.1346798E-01 0.1292217E+04 -3.1574 9 Ca++ 0.1371181E-06 0.2385902E-06 0.9545501E-02 13.1018 10 Mg++ 0.2145173E-10 0.9420462E-10 0.2286298E-05 9.2942 11 Fe++ 0.5912462E-13 0.3606465E-07 0.2010581E-02 6.7350 12 K+ 0.1576623E-03 0.1584166E-03 0.6183575E+01 6.2467 13 Na+ 0.2000678E-01 0.2245380E-01 0.5153059E+03 8.3494 14 Mn++ 0.1897011E-10 0.2527973E-08 0.1386390E-03 9.2416 15 F- 0.1144315E-05 0.1148043E-05 0.2177239E-01 4.1059 16 HPO4-- 0.4479853E-07 0.4588664E-07 0.4396453E-02 12.6193 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279237E+02 -.1101203E-01 -.8278136E+02 0.0000000E+00 2 H2O -.7167422E+01 0.2755084E+02 -.3471826E+02 0.0000000E+00 3 Cl- 0.1477272E-03 0.1477272E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386005E+00 -.1281997E-03 0.1387287E+00 0.0000000E+00 5 HCO3- 0.1338110E-03 0.1338110E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385344E+00 0.1942852E-03 -.1387287E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2622209E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6685042E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1184280E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4675993E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1790125E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7863255E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1114530E-01 0.6265232E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254799E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7680000E-06 0.5698490E-06 0.1981510E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2277655E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.2963E-14 Mass of aqueous solution: 0.497235E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0016700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5549 -0.256 282.0 2.450 5.163 73.26 grossular 0.1344 -0.872 60.53 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.1982E-06 -6.703 0.9993E-04 -4.000 0.1829E-05 0.3122E-04 clinochlore 0.7102 -0.149 394.7 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2595 -0.586 56.20 1.750 1.029 17.18 hedenbergite 0.6730E-01 -1.172 16.70 1.223 0.3057 4.573 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.5 2.449 5.153 97.23 tr.625ac.25prg.125 0.4352E-01 -1.361 37.20 1.571 0.6810 11.97 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338409 g Volume = 2210.782477 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0016700 moles log = -2.7773 Original solution: 1000.0103000 g Original solution / Rock added: 598808.56 (Water/Rock Ratio), log = 5.7773 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.4110 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7261E+00 0.9819 0.1006E+01 0.1025E+01 CO2,gas 0.4957E-07 1.0030 0.7016E-07 0.6995E-07 CH4,gas 0.2631E+00 1.0089 0.3746E+00 0.3713E+00 H2,gas 0.1077E-01 1.0008 0.1521E-01 0.1520E-01 H2S,gas 0.5026E-06 0.9945 0.7053E-06 0.7091E-06 S2,gas 0.5722E-28 1.0000 0.8074E-28 0.8074E-28 CO,gas 0.2015E-12 1.0000 0.2843E-12 0.2843E-12 SO3,gas 0.2606E-47 1.0000 0.3677E-47 0.3677E-47 SO2,gas 0.1542E-26 1.0000 0.2175E-26 0.2175E-26 HF,gas 0.8482E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4233E-17 1.0000 0.5973E-17 0.5973E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.51 -8.85 -2.951 0.15116E+05 -7.154 3 CH4,gas 4.54 2.42 -2.13 -0.531 0.36291E+04 -0.426 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.08 -7.85 -3.925 0.13405E+05 -6.152 6 S2,gas -7.34 -37.13 -29.79 -4.583 0.50869E+05 -28.093 7 CO,gas 3.21 -11.03 -14.25 -4.383 0.24323E+05 -12.546 8 SO3,gas 17.12 -32.01 -49.13 -12.283 0.83894E+05 -47.435 9 SO2,gas 0.83 -27.53 -28.36 -7.563 0.48426E+05 -26.662 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.73 -18.92 -9.461 0.32310E+05 -17.224 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.41 -3.38 -1.126 0.57673E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.41 -3.22 -1.074 0.55031E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.55 -3.44 -0.984 0.58822E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.55 -3.00 -0.857 0.51244E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.91 -4.66 -1.097 0.79613E+04 146 pyrrhotite -4.26 -7.35 -3.09 -1.029 0.52685E+04 147 pyrrhotiteFe0.875 -6.02 -8.74 -2.73 -1.003 0.46557E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.35 -2.93 -0.978 0.50113E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.84 -3.86 -1.287 0.65931E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0016700 MOLES New total amount of reactant added: 0.0017100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0017100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7167E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1129114E-01 Osmotic coef. = 0.7981 True ionic strength = .2017609E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.1480E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88947E-10 -10.0509 0.74701E-10 -10.1267 0.83984E+00 -0.0758 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.29672E-03 -3.5277 0.24769E-03 -3.6061 0.83476E+00 -0.0784 4 SO4-- 0.34123E-11 -11.4670 0.17684E-11 -11.7524 0.51824E+00 -0.2855 5 HCO3- 0.50207E-05 -5.2992 0.41972E-05 -5.3770 0.83598E+00 -0.0778 6 HS- 0.13507E-03 -3.8694 0.11277E-03 -3.9478 0.83488E+00 -0.0784 7 Al+++ 0.99386E-29 -29.0027 0.22854E-29 -29.6410 0.22995E+00 -0.6384 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13714E-06 -6.8628 0.70547E-07 -7.1515 0.51441E+00 -0.2887 10 Mg++ 0.21455E-10 -10.6685 0.10986E-10 -10.9592 0.51205E+00 -0.2907 11 Fe++ 0.59135E-13 -13.2282 0.30313E-13 -13.5184 0.51261E+00 -0.2902 12 K+ 0.15767E-03 -3.8022 0.13185E-03 -3.8799 0.83618E+00 -0.0777 13 Na+ 0.20008E-01 -1.6988 0.16699E-01 -1.7773 0.83460E+00 -0.0785 14 Mn++ 0.18973E-10 -10.7219 0.97341E-11 -11.0117 0.51304E+00 -0.2899 15 F- 0.11442E-05 -5.9415 0.95318E-06 -6.0208 0.83302E+00 -0.0793 16 HPO4-- 0.44793E-07 -7.3488 0.23217E-07 -7.6342 0.51832E+00 -0.2854 18 HSiO3- 0.10422E-01 -1.9821 0.86995E-02 -2.0605 0.83476E+00 -0.0784 19 Ca(HSiO3)+ 0.16712E-07 -7.7770 0.13977E-07 -7.8546 0.83636E+00 -0.0776 20 Mg(HSiO3)+ 0.32388E-11 -11.4896 0.27088E-11 -11.5672 0.83636E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66616E-16 -16.1764 0.55715E-16 -16.2540 0.83636E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52823E-05 -5.2772 0.44014E-05 -5.3564 0.83324E+00 -0.0792 26 CH4,aq 0.26089E-03 -3.5835 0.25999E-03 -3.5850 0.99656E+00 -0.0015 27 C2H6,aq 0.10012E-11 -11.9995 0.99771E-12 -12.0010 0.99656E+00 -0.0015 28 C3H8,aq 0.88699E-19 -19.0521 0.88393E-19 -19.0536 0.99656E+00 -0.0015 30 ethanol,aq 0.36746E-19 -19.4348 0.36620E-19 -19.4363 0.99656E+00 -0.0015 31 CO,aq 0.19493E-15 -15.7101 0.19493E-15 -15.7101 0.10000E+01 0.0000 32 CO2,aq 0.67228E-09 -9.1725 0.66996E-09 -9.1740 0.99656E+00 -0.0015 33 CO3-2 0.94903E-05 -5.0227 0.49077E-05 -5.3091 0.51713E+00 -0.2864 34 CaCO3,aq 0.43413E-08 -8.3624 0.43413E-08 -8.3624 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.90372E-11 -11.0440 0.75584E-11 -11.1216 0.83636E+00 -0.0776 36 CaCl+ 0.33811E-10 -10.4709 0.28278E-10 -10.5485 0.83636E+00 -0.0776 37 CaCl2,aq 0.16641E-14 -14.7788 0.16641E-14 -14.7788 0.10000E+01 0.0000 38 CaF+ 0.11739E-11 -11.9304 0.98177E-12 -12.0080 0.83636E+00 -0.0776 39 CaOH+ 0.80475E-07 -7.0943 0.67306E-07 -7.1719 0.83636E+00 -0.0776 40 CaSO4,aq 0.39615E-16 -16.4021 0.39615E-16 -16.4021 0.10000E+01 0.0000 41 HCl,aq 0.33905E-14 -14.4697 0.33905E-14 -14.4697 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18792E-18 -18.7260 0.15687E-18 -18.8045 0.83476E+00 -0.0784 48 FeCl+ 0.14209E-16 -16.8474 0.11884E-16 -16.9250 0.83636E+00 -0.0776 51 FeF+ 0.17654E-17 -17.7532 0.14765E-17 -17.8308 0.83636E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15793E-10 -10.8015 0.13209E-10 -10.8791 0.83636E+00 -0.0776 55 HFeO2- 0.35425E-07 -7.4507 0.29572E-07 -7.5291 0.83476E+00 -0.0784 56 FeO+ 0.11069E-16 -16.9559 0.92574E-17 -17.0335 0.83636E+00 -0.0776 58 FeO2- 0.40666E-09 -9.3908 0.33946E-09 -9.4692 0.83476E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99656E+00 -0.0015 61 KCl,aq 0.59188E-09 -9.2278 0.59188E-09 -9.2278 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.43341E-14 -14.3631 0.36179E-14 -14.4415 0.83476E+00 -0.0784 65 MgCO3,aq 0.16946E-12 -12.7709 0.16946E-12 -12.7709 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14380E-14 -14.8422 0.12027E-14 -14.9198 0.83636E+00 -0.0776 67 MgCl+ 0.47721E-14 -14.3213 0.39912E-14 -14.3989 0.83636E+00 -0.0776 68 MgF+ 0.67715E-15 -15.1693 0.56635E-15 -15.2469 0.83636E+00 -0.0776 69 MgOH+ 0.69347E-10 -10.1590 0.57999E-10 -10.2366 0.83636E+00 -0.0776 71 MnF+ 0.18686E-15 -15.7285 0.15628E-15 -15.8061 0.83636E+00 -0.0776 72 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47113E-09 -9.3269 0.39403E-09 -9.4045 0.83636E+00 -0.0776 74 MnO2-2 0.20775E-10 -10.6825 0.10744E-10 -10.9688 0.51713E+00 -0.2864 75 HMnO2- 0.21063E-09 -9.6765 0.17583E-09 -9.7549 0.83476E+00 -0.0784 78 MnCl+ 0.17752E-13 -13.7508 0.14847E-13 -13.8284 0.83636E+00 -0.0776 80 NaCl,aq 0.13707E-05 -5.8630 0.13707E-05 -5.8630 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92824E-02 -2.0323 0.77345E-02 -2.1116 0.83324E+00 -0.0792 89 HPO3-2 0.16205E-14 -14.7904 0.83802E-15 -15.0767 0.51713E+00 -0.2864 91 H2PO3- 0.15038E-18 -18.8228 0.12553E-18 -18.9012 0.83476E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38290E-10 -10.4169 0.31994E-10 -10.4949 0.83555E+00 -0.0780 94 PO4-3 0.10496E-08 -8.9790 0.25358E-09 -9.5959 0.24159E+00 -0.6169 98 HP2O7-3 0.93203E-18 -18.0306 0.21454E-18 -18.6685 0.23018E+00 -0.6379 99 P2O7-4 0.89709E-17 -17.0472 0.68609E-18 -18.1636 0.76480E-01 -1.1165 100 H2S,aq 0.26125E-07 -7.5829 0.26035E-07 -7.5844 0.99656E+00 -0.0015 101 S2-2 0.47043E-13 -13.3275 0.24327E-13 -13.6139 0.51713E+00 -0.2864 107 SO3-2 0.50731E-17 -17.2947 0.26617E-17 -17.5748 0.52466E+00 -0.2801 108 HSO3- 0.14913E-19 -19.8264 0.12449E-19 -19.9049 0.83476E+00 -0.0784 109 HSO4- 0.15206E-18 -18.8180 0.12731E-18 -18.8952 0.83718E+00 -0.0772 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8894704E-10 -.2218419E-01 -.2232123E+02 0.0000 2 H2O 0.1000000E+01 0.5550514E+02 0.9981933E+06 0.0000 3 Cl- 0.2967214E-03 0.2980927E-03 0.1054980E+02 6.5206 4 SO4-- 0.3412256E-11 -.2637971E-03 -.2529646E+02 8.5009 5 HCO3- 0.5020723E-05 0.2754075E-03 0.1677521E+02 4.7496 6 HS- 0.1350706E-03 0.3988938E-03 0.1316915E+02 6.1789 7 Al+++ 0.9938562E-29 0.5282462E-05 0.1422795E+00 0.7390 8 H4SiO4 0.6959760E-03 0.1346727E-01 0.1292149E+04 -3.1574 9 Ca++ 0.1371416E-06 0.2387136E-06 0.9550434E-02 13.1018 10 Mg++ 0.2145541E-10 0.9421701E-10 0.2286598E-05 9.2942 11 Fe++ 0.5913478E-13 0.3606222E-07 0.2010445E-02 6.7350 12 K+ 0.1576748E-03 0.1584291E-03 0.6184063E+01 6.2467 13 Na+ 0.2000837E-01 0.2245540E-01 0.5153424E+03 8.3494 14 Mn++ 0.1897344E-10 0.2528007E-08 0.1386408E-03 9.2416 15 F- 0.1144238E-05 0.1147966E-05 0.2177092E-01 4.1058 16 HPO4-- 0.4479298E-07 0.4588090E-07 0.4395903E-02 12.6192 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279236E+02 -.1101148E-01 -.8278135E+02 0.0000000E+00 2 H2O -.7167389E+01 0.2755088E+02 -.3471827E+02 0.0000000E+00 3 Cl- 0.1479632E-03 0.1479632E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386007E+00 -.1309400E-03 0.1387316E+00 0.0000000E+00 5 HCO3- 0.1367030E-03 0.1367030E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385336E+00 0.1979974E-03 -.1387316E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2622036E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6684701E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1184894E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4676615E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1790007E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7863888E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1114610E-01 0.6265231E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254817E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7840000E-06 0.5698115E-06 0.2141885E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2277374E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1314E-13 Mass of aqueous solution: 0.497236E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0017100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5549 -0.256 282.0 2.450 5.163 73.27 grossular 0.1344 -0.872 60.53 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.2142E-06 -6.669 0.1080E-03 -3.967 0.1977E-05 0.3374E-04 clinochlore 0.7102 -0.149 394.7 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2594 -0.586 56.18 1.750 1.029 17.17 hedenbergite 0.6728E-01 -1.172 16.69 1.223 0.3056 4.572 microcline 0.9309 -0.031 259.1 2.413 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.5 2.449 5.153 97.22 tr.625ac.25prg.125 0.4355E-01 -1.361 37.22 1.571 0.6814 11.98 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338422 g Volume = 2210.782588 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0017100 moles log = -2.7670 Original solution: 1000.0103000 g Original solution / Rock added: 584801.35 (Water/Rock Ratio), log = 5.7670 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.4191 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7220E+00 0.9818 0.1006E+01 0.1025E+01 CO2,gas 0.5036E-07 1.0030 0.7168E-07 0.7147E-07 CH4,gas 0.2673E+00 1.0088 0.3827E+00 0.3793E+00 H2,gas 0.1071E-01 1.0008 0.1521E-01 0.1519E-01 H2S,gas 0.5071E-06 0.9945 0.7157E-06 0.7196E-06 S2,gas 0.5859E-28 1.0000 0.8314E-28 0.8314E-28 CO,gas 0.2047E-12 1.0000 0.2905E-12 0.2905E-12 SO3,gas 0.2629E-47 1.0000 0.3731E-47 0.3731E-47 SO2,gas 0.1555E-26 1.0000 0.2207E-26 0.2207E-26 HF,gas 0.8433E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4216E-17 1.0000 0.5983E-17 0.5983E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.50 -8.84 -2.948 0.15100E+05 -7.145 3 CH4,gas 4.54 2.43 -2.12 -0.529 0.36132E+04 -0.417 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.07 -7.84 -3.922 0.13394E+05 -6.145 6 S2,gas -7.34 -37.11 -29.78 -4.581 0.50847E+05 -28.080 7 CO,gas 3.21 -11.02 -14.24 -4.380 0.24307E+05 -12.537 8 SO3,gas 17.12 -32.01 -49.13 -12.282 0.83883E+05 -47.428 9 SO2,gas 0.83 -27.52 -28.36 -7.561 0.48416E+05 -26.656 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.73 -18.92 -9.461 0.32309E+05 -17.223 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80707E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.40 -3.37 -1.123 0.57515E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.40 -3.21 -1.071 0.54872E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.54 -3.44 -0.982 0.58663E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.54 -2.99 -0.855 0.51086E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.90 -4.65 -1.094 0.79396E+04 146 pyrrhotite -4.26 -7.34 -3.08 -1.026 0.52576E+04 147 pyrrhotiteFe0.875 -6.02 -8.74 -2.72 -1.000 0.46448E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.34 -2.93 -0.976 0.50004E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.83 -3.85 -1.285 0.65823E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0017100 MOLES New total amount of reactant added: 0.0017500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0017500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7167E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1128779E-01 Osmotic coef. = 0.8071 True ionic strength = .2017789E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.1482E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88954E-10 -10.0508 0.74706E-10 -10.1266 0.83983E+00 -0.0758 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.29719E-03 -3.5270 0.24808E-03 -3.6054 0.83475E+00 -0.0784 4 SO4-- 0.34615E-11 -11.4607 0.17939E-11 -11.7462 0.51823E+00 -0.2855 5 HCO3- 0.51266E-05 -5.2902 0.42857E-05 -5.3680 0.83598E+00 -0.0778 6 HS- 0.13703E-03 -3.8632 0.11440E-03 -3.9416 0.83487E+00 -0.0784 7 Al+++ 0.99413E-29 -29.0026 0.22859E-29 -29.6410 0.22994E+00 -0.6384 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13717E-06 -6.8628 0.70558E-07 -7.1515 0.51440E+00 -0.2887 10 Mg++ 0.21459E-10 -10.6684 0.10988E-10 -10.9591 0.51203E+00 -0.2907 11 Fe++ 0.59145E-13 -13.2281 0.30318E-13 -13.5183 0.51260E+00 -0.2902 12 K+ 0.15769E-03 -3.8022 0.13185E-03 -3.8799 0.83618E+00 -0.0777 13 Na+ 0.20010E-01 -1.6988 0.16700E-01 -1.7773 0.83460E+00 -0.0785 14 Mn++ 0.18977E-10 -10.7218 0.97356E-11 -11.0116 0.51302E+00 -0.2899 15 F- 0.11442E-05 -5.9415 0.95311E-06 -6.0209 0.83302E+00 -0.0793 16 HPO4-- 0.44787E-07 -7.3488 0.23213E-07 -7.6343 0.51830E+00 -0.2854 18 HSiO3- 0.10421E-01 -1.9821 0.86989E-02 -2.0605 0.83475E+00 -0.0784 19 Ca(HSiO3)+ 0.16713E-07 -7.7769 0.13978E-07 -7.8546 0.83636E+00 -0.0776 20 Mg(HSiO3)+ 0.32390E-11 -11.4896 0.27090E-11 -11.5672 0.83636E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66622E-16 -16.1764 0.55720E-16 -16.2540 0.83636E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52820E-05 -5.2772 0.44011E-05 -5.3564 0.83323E+00 -0.0792 26 CH4,aq 0.26641E-03 -3.5744 0.26549E-03 -3.5759 0.99656E+00 -0.0015 27 C2H6,aq 0.10440E-11 -11.9813 0.10404E-11 -11.9828 0.99656E+00 -0.0015 28 C3H8,aq 0.94449E-19 -19.0248 0.94124E-19 -19.0263 0.99656E+00 -0.0015 30 ethanol,aq 0.38318E-19 -19.4166 0.38186E-19 -19.4181 0.99656E+00 -0.0015 31 CO,aq 0.19906E-15 -15.7010 0.19906E-15 -15.7010 0.10000E+01 0.0000 32 CO2,aq 0.68650E-09 -9.1634 0.68414E-09 -9.1649 0.99656E+00 -0.0015 33 CO3-2 0.96899E-05 -5.0137 0.50108E-05 -5.3001 0.51712E+00 -0.2864 34 CaCO3,aq 0.44332E-08 -8.3533 0.44332E-08 -8.3533 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.92292E-11 -11.0348 0.77189E-11 -11.1124 0.83636E+00 -0.0776 36 CaCl+ 0.33870E-10 -10.4702 0.28327E-10 -10.5478 0.83636E+00 -0.0776 37 CaCl2,aq 0.16696E-14 -14.7774 0.16696E-14 -14.7774 0.10000E+01 0.0000 38 CaF+ 0.11740E-11 -11.9303 0.98184E-12 -12.0080 0.83636E+00 -0.0776 39 CaOH+ 0.80481E-07 -7.0943 0.67311E-07 -7.1719 0.83636E+00 -0.0776 40 CaSO4,aq 0.40192E-16 -16.3959 0.40192E-16 -16.3959 0.10000E+01 0.0000 41 HCl,aq 0.33962E-14 -14.4690 0.33962E-14 -14.4690 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18791E-18 -18.7261 0.15685E-18 -18.8045 0.83475E+00 -0.0784 48 FeCl+ 0.14234E-16 -16.8467 0.11905E-16 -16.9243 0.83636E+00 -0.0776 51 FeF+ 0.17655E-17 -17.7531 0.14766E-17 -17.8307 0.83636E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15794E-10 -10.8015 0.13210E-10 -10.8791 0.83636E+00 -0.0776 55 HFeO2- 0.35423E-07 -7.4507 0.29569E-07 -7.5292 0.83475E+00 -0.0784 56 FeO+ 0.11070E-16 -16.9559 0.92581E-17 -17.0335 0.83636E+00 -0.0776 58 FeO2- 0.40663E-09 -9.3908 0.33943E-09 -9.4692 0.83475E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11623E-04 -4.9347 0.11582E-04 -4.9362 0.99656E+00 -0.0015 61 KCl,aq 0.59286E-09 -9.2270 0.59286E-09 -9.2270 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.43969E-14 -14.3568 0.36704E-14 -14.4353 0.83475E+00 -0.0784 65 MgCO3,aq 0.17305E-12 -12.7618 0.17305E-12 -12.7618 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14686E-14 -14.8331 0.12283E-14 -14.9107 0.83636E+00 -0.0776 67 MgCl+ 0.47805E-14 -14.3205 0.39982E-14 -14.3981 0.83636E+00 -0.0776 68 MgF+ 0.67721E-15 -15.1693 0.56639E-15 -15.2469 0.83636E+00 -0.0776 69 MgOH+ 0.69352E-10 -10.1589 0.58003E-10 -10.2365 0.83636E+00 -0.0776 71 MnF+ 0.18687E-15 -15.7285 0.15629E-15 -15.8061 0.83636E+00 -0.0776 72 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47116E-09 -9.3268 0.39406E-09 -9.4044 0.83636E+00 -0.0776 74 MnO2-2 0.20773E-10 -10.6825 0.10742E-10 -10.9689 0.51712E+00 -0.2864 75 HMnO2- 0.21062E-09 -9.6765 0.17582E-09 -9.7549 0.83475E+00 -0.0784 78 MnCl+ 0.17783E-13 -13.7500 0.14873E-13 -13.8276 0.83636E+00 -0.0776 80 NaCl,aq 0.13730E-05 -5.8623 0.13730E-05 -5.8623 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92818E-02 -2.0324 0.77339E-02 -2.1116 0.83323E+00 -0.0792 89 HPO3-2 0.16203E-14 -14.7904 0.83789E-15 -15.0768 0.51712E+00 -0.2864 91 H2PO3- 0.15037E-18 -18.8228 0.12552E-18 -18.9013 0.83475E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38288E-10 -10.4169 0.31991E-10 -10.4950 0.83555E+00 -0.0780 94 PO4-3 0.10495E-08 -8.9790 0.25352E-09 -9.5960 0.24157E+00 -0.6170 98 HP2O7-3 0.93188E-18 -18.0306 0.21449E-18 -18.6686 0.23017E+00 -0.6380 99 P2O7-4 0.89691E-17 -17.0473 0.68589E-18 -18.1637 0.76473E-01 -1.1165 100 H2S,aq 0.26505E-07 -7.5767 0.26414E-07 -7.5782 0.99656E+00 -0.0015 101 S2-2 0.48417E-13 -13.3150 0.25037E-13 -13.6014 0.51712E+00 -0.2864 107 SO3-2 0.51463E-17 -17.2885 0.27000E-17 -17.5686 0.52465E+00 -0.2801 108 HSO3- 0.15130E-19 -19.8202 0.12629E-19 -19.8986 0.83475E+00 -0.0784 109 HSO4- 0.15427E-18 -18.8117 0.12915E-18 -18.8889 0.83718E+00 -0.0772 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8895410E-10 -.2218305E-01 -.2232009E+02 0.0000 2 H2O 0.1000000E+01 0.5550515E+02 0.9981932E+06 0.0000 3 Cl- 0.2971941E-03 0.2985677E-03 0.1056661E+02 6.5212 4 SO4-- 0.3461516E-11 -.2693174E-03 -.2582582E+02 8.5071 5 HCO3- 0.5126617E-05 0.2812334E-03 0.1713007E+02 4.7587 6 HS- 0.1370283E-03 0.4063721E-03 0.1341604E+02 6.1851 7 Al+++ 0.9941295E-29 0.5282106E-05 0.1422699E+00 0.7390 8 H4SiO4 0.6959759E-03 0.1346657E-01 0.1292081E+04 -3.1574 9 Ca++ 0.1371651E-06 0.2388369E-06 0.9555368E-02 13.1018 10 Mg++ 0.2145910E-10 0.9422939E-10 0.2286899E-05 9.2942 11 Fe++ 0.5914493E-13 0.3605980E-07 0.2010310E-02 6.7350 12 K+ 0.1576873E-03 0.1584416E-03 0.6184551E+01 6.2467 13 Na+ 0.2000996E-01 0.2245699E-01 0.5153788E+03 8.3494 14 Mn++ 0.1897677E-10 0.2528040E-08 0.1386426E-03 9.2416 15 F- 0.1144160E-05 0.1147888E-05 0.2176945E-01 4.1058 16 HPO4-- 0.4478743E-07 0.4587517E-07 0.4395353E-02 12.6190 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279236E+02 -.1101094E-01 -.8278135E+02 0.0000000E+00 2 H2O -.7167356E+01 0.2755093E+02 -.3471828E+02 0.0000000E+00 3 Cl- 0.1481992E-03 0.1481992E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386009E+00 -.1336803E-03 0.1387346E+00 0.0000000E+00 5 HCO3- 0.1395950E-03 0.1395950E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385328E+00 0.2017097E-03 -.1387346E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2621863E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6684361E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1185508E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4677236E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1789889E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7864520E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1114691E-01 0.6265230E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254836E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8000000E-06 0.5697740E-06 0.2302260E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2277092E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.7057E-14 Mass of aqueous solution: 0.497237E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0017500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5549 -0.256 282.0 2.450 5.163 73.27 grossular 0.1344 -0.872 60.53 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9070E-01 1.574 apatite-F 0.2302E-06 -6.638 0.1161E-03 -3.935 0.2126E-05 0.3627E-04 clinochlore 0.7102 -0.149 394.7 2.596 7.227 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2594 -0.586 56.16 1.749 1.028 17.17 hedenbergite 0.6726E-01 -1.172 16.69 1.222 0.3055 4.571 microcline 0.9309 -0.031 259.1 2.414 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.5 2.449 5.153 97.22 tr.625ac.25prg.125 0.4357E-01 -1.361 37.24 1.571 0.6818 11.99 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338434 g Volume = 2210.782698 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0017500 moles log = -2.7570 Original solution: 1000.0103000 g Original solution / Rock added: 571434.46 (Water/Rock Ratio), log = 5.7570 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.4273 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7179E+00 0.9817 0.1006E+01 0.1025E+01 CO2,gas 0.5114E-07 1.0029 0.7320E-07 0.7298E-07 CH4,gas 0.2714E+00 1.0088 0.3908E+00 0.3874E+00 H2,gas 0.1065E-01 1.0008 0.1521E-01 0.1519E-01 H2S,gas 0.5116E-06 0.9945 0.7261E-06 0.7301E-06 S2,gas 0.5996E-28 1.0000 0.8558E-28 0.8558E-28 CO,gas 0.2078E-12 1.0000 0.2966E-12 0.2966E-12 SO3,gas 0.2652E-47 1.0000 0.3785E-47 0.3785E-47 SO2,gas 0.1569E-26 1.0000 0.2240E-26 0.2240E-26 HF,gas 0.8385E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4199E-17 1.0000 0.5993E-17 0.5993E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.49 -8.83 -2.945 0.15085E+05 -7.136 3 CH4,gas 4.54 2.44 -2.11 -0.527 0.35977E+04 -0.408 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.07 -7.84 -3.919 0.13383E+05 -6.139 6 S2,gas -7.34 -37.10 -29.77 -4.579 0.50826E+05 -28.068 7 CO,gas 3.21 -11.01 -14.23 -4.377 0.24292E+05 -12.528 8 SO3,gas 17.12 -32.00 -49.12 -12.280 0.83873E+05 -47.422 9 SO2,gas 0.83 -27.52 -28.35 -7.560 0.48405E+05 -26.650 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.73 -18.92 -9.461 0.32308E+05 -17.222 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80706E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.39 -3.36 -1.120 0.57359E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.39 -3.20 -1.068 0.54717E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.53 -3.43 -0.979 0.58508E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.53 -2.98 -0.852 0.50930E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.88 -4.64 -1.091 0.79181E+04 146 pyrrhotite -4.26 -7.33 -3.07 -1.024 0.52469E+04 147 pyrrhotiteFe0.875 -6.02 -8.73 -2.71 -0.998 0.46341E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.33 -2.92 -0.974 0.49897E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.83 -3.85 -1.283 0.65715E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0017500 MOLES New total amount of reactant added: 0.0017900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8666E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0017900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7167E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1128444E-01 Osmotic coef. = 0.8148 True ionic strength = .2017970E-01 Chg. balance for total moles = -.8666E-10 Max. difference allowed = 0.1484E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88961E-10 -10.0508 0.74712E-10 -10.1266 0.83983E+00 -0.0758 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.29767E-03 -3.5263 0.24848E-03 -3.6047 0.83475E+00 -0.0784 4 SO4-- 0.35108E-11 -11.4546 0.18193E-11 -11.7401 0.51822E+00 -0.2855 5 HCO3- 0.52325E-05 -5.2813 0.43742E-05 -5.3591 0.83597E+00 -0.0778 6 HS- 0.13899E-03 -3.8570 0.11603E-03 -3.9354 0.83487E+00 -0.0784 7 Al+++ 0.99440E-29 -29.0024 0.22864E-29 -29.6409 0.22992E+00 -0.6384 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13719E-06 -6.8627 0.70568E-07 -7.1514 0.51439E+00 -0.2887 10 Mg++ 0.21463E-10 -10.6683 0.10989E-10 -10.9590 0.51202E+00 -0.2907 11 Fe++ 0.59155E-13 -13.2280 0.30322E-13 -13.5182 0.51258E+00 -0.2902 12 K+ 0.15770E-03 -3.8022 0.13186E-03 -3.8799 0.83617E+00 -0.0777 13 Na+ 0.20012E-01 -1.6987 0.16701E-01 -1.7772 0.83459E+00 -0.0785 14 Mn++ 0.18980E-10 -10.7217 0.97370E-11 -11.0116 0.51301E+00 -0.2899 15 F- 0.11441E-05 -5.9415 0.95304E-06 -6.0209 0.83301E+00 -0.0793 16 HPO4-- 0.44782E-07 -7.3489 0.23210E-07 -7.6343 0.51829E+00 -0.2854 18 HSiO3- 0.10420E-01 -1.9821 0.86983E-02 -2.0606 0.83475E+00 -0.0784 19 Ca(HSiO3)+ 0.16714E-07 -7.7769 0.13979E-07 -7.8545 0.83635E+00 -0.0776 20 Mg(HSiO3)+ 0.32393E-11 -11.4895 0.27092E-11 -11.5672 0.83635E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66627E-16 -16.1764 0.55724E-16 -16.2540 0.83635E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52816E-05 -5.2772 0.44008E-05 -5.3565 0.83323E+00 -0.0792 26 CH4,aq 0.27193E-03 -3.5655 0.27100E-03 -3.5670 0.99656E+00 -0.0015 27 C2H6,aq 0.10877E-11 -11.9635 0.10839E-11 -11.9650 0.99656E+00 -0.0015 28 C3H8,aq 0.10044E-18 -18.9981 0.10010E-18 -18.9996 0.99656E+00 -0.0015 30 ethanol,aq 0.39922E-19 -19.3988 0.39785E-19 -19.4003 0.99656E+00 -0.0015 31 CO,aq 0.20318E-15 -15.6921 0.20318E-15 -15.6921 0.10000E+01 0.0000 32 CO2,aq 0.70073E-09 -9.1545 0.69831E-09 -9.1559 0.99656E+00 -0.0015 33 CO3-2 0.98894E-05 -5.0048 0.51139E-05 -5.2912 0.51711E+00 -0.2864 34 CaCO3,aq 0.45250E-08 -8.3444 0.45250E-08 -8.3444 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.94211E-11 -11.0259 0.78794E-11 -11.1035 0.83635E+00 -0.0776 36 CaCl+ 0.33929E-10 -10.4694 0.28376E-10 -10.5470 0.83635E+00 -0.0776 37 CaCl2,aq 0.16751E-14 -14.7760 0.16751E-14 -14.7760 0.10000E+01 0.0000 38 CaF+ 0.11740E-11 -11.9303 0.98192E-12 -12.0079 0.83635E+00 -0.0776 39 CaOH+ 0.80488E-07 -7.0943 0.67316E-07 -7.1719 0.83635E+00 -0.0776 40 CaSO4,aq 0.40769E-16 -16.3897 0.40769E-16 -16.3897 0.10000E+01 0.0000 41 HCl,aq 0.34018E-14 -14.4683 0.34018E-14 -14.4683 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18789E-18 -18.7261 0.15684E-18 -18.8045 0.83475E+00 -0.0784 48 FeCl+ 0.14259E-16 -16.8459 0.11926E-16 -16.9235 0.83635E+00 -0.0776 51 FeF+ 0.17657E-17 -17.7531 0.14767E-17 -17.8307 0.83635E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15796E-10 -10.8015 0.13211E-10 -10.8791 0.83635E+00 -0.0776 55 HFeO2- 0.35421E-07 -7.4507 0.29567E-07 -7.5292 0.83475E+00 -0.0784 56 FeO+ 0.11070E-16 -16.9558 0.92588E-17 -17.0334 0.83635E+00 -0.0776 58 FeO2- 0.40660E-09 -9.3908 0.33941E-09 -9.4693 0.83475E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11622E-04 -4.9347 0.11582E-04 -4.9362 0.99656E+00 -0.0015 61 KCl,aq 0.59384E-09 -9.2263 0.59384E-09 -9.2263 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.44598E-14 -14.3507 0.37228E-14 -14.4291 0.83475E+00 -0.0784 65 MgCO3,aq 0.17663E-12 -12.7529 0.17663E-12 -12.7529 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14991E-14 -14.8242 0.12538E-14 -14.9018 0.83635E+00 -0.0776 67 MgCl+ 0.47888E-14 -14.3198 0.40051E-14 -14.3974 0.83635E+00 -0.0776 68 MgF+ 0.67726E-15 -15.1692 0.56643E-15 -15.2469 0.83635E+00 -0.0776 69 MgOH+ 0.69358E-10 -10.1589 0.58008E-10 -10.2365 0.83635E+00 -0.0776 71 MnF+ 0.18689E-15 -15.7284 0.15630E-15 -15.8060 0.83635E+00 -0.0776 72 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47120E-09 -9.3268 0.39409E-09 -9.4044 0.83635E+00 -0.0776 74 MnO2-2 0.20770E-10 -10.6826 0.10741E-10 -10.9690 0.51711E+00 -0.2864 75 HMnO2- 0.21061E-09 -9.6765 0.17580E-09 -9.7550 0.83475E+00 -0.0784 78 MnCl+ 0.17814E-13 -13.7492 0.14899E-13 -13.8269 0.83635E+00 -0.0776 80 NaCl,aq 0.13753E-05 -5.8616 0.13753E-05 -5.8616 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92811E-02 -2.0324 0.77333E-02 -2.1116 0.83323E+00 -0.0792 89 HPO3-2 0.16201E-14 -14.7905 0.83777E-15 -15.0769 0.51711E+00 -0.2864 91 H2PO3- 0.15036E-18 -18.8229 0.12551E-18 -18.9013 0.83475E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38285E-10 -10.4170 0.31989E-10 -10.4950 0.83554E+00 -0.0780 94 PO4-3 0.10493E-08 -8.9791 0.25347E-09 -9.5961 0.24156E+00 -0.6170 98 HP2O7-3 0.93172E-18 -18.0307 0.21444E-18 -18.6687 0.23016E+00 -0.6380 99 P2O7-4 0.89672E-17 -17.0473 0.68569E-18 -18.1639 0.76466E-01 -1.1165 100 H2S,aq 0.26886E-07 -7.5705 0.26793E-07 -7.5720 0.99656E+00 -0.0015 101 S2-2 0.49811E-13 -13.3027 0.25758E-13 -13.5891 0.51711E+00 -0.2864 107 SO3-2 0.52196E-17 -17.2824 0.27384E-17 -17.5625 0.52464E+00 -0.2801 108 HSO3- 0.15346E-19 -19.8140 0.12810E-19 -19.8925 0.83475E+00 -0.0784 109 HSO4- 0.15647E-18 -18.8056 0.13099E-18 -18.8827 0.83717E+00 -0.0772 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8896116E-10 -.2218192E-01 -.2231894E+02 0.0000 2 H2O 0.1000000E+01 0.5550515E+02 0.9981931E+06 0.0000 3 Cl- 0.2976668E-03 0.2990427E-03 0.1058342E+02 6.5219 4 SO4-- 0.3510771E-11 -.2748377E-03 -.2635518E+02 8.5131 5 HCO3- 0.5232498E-05 0.2870593E-03 0.1748492E+02 4.7675 6 HS- 0.1389859E-03 0.4138505E-03 0.1366293E+02 6.1912 7 Al+++ 0.9944029E-29 0.5281750E-05 0.1422603E+00 0.7390 8 H4SiO4 0.6959758E-03 0.1346586E-01 0.1292013E+04 -3.1574 9 Ca++ 0.1371886E-06 0.2389603E-06 0.9560302E-02 13.1018 10 Mg++ 0.2146278E-10 0.9424267E-10 0.2287221E-05 9.2942 11 Fe++ 0.5915509E-13 0.3605737E-07 0.2010174E-02 6.7350 12 K+ 0.1576998E-03 0.1584542E-03 0.6185038E+01 6.2467 13 Na+ 0.2001155E-01 0.2245858E-01 0.5154153E+03 8.3494 14 Mn++ 0.1898010E-10 0.2528074E-08 0.1386444E-03 9.2416 15 F- 0.1144083E-05 0.1147811E-05 0.2176798E-01 4.1057 16 HPO4-- 0.4478188E-07 0.4586944E-07 0.4394804E-02 12.6189 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279235E+02 -.1101039E-01 -.8278134E+02 0.0000000E+00 2 H2O -.7167323E+01 0.2755097E+02 -.3471829E+02 0.0000000E+00 3 Cl- 0.1484352E-03 0.1484352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386011E+00 -.1364206E-03 0.1387375E+00 0.0000000E+00 5 HCO3- 0.1424870E-03 0.1424870E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385321E+00 0.2054221E-03 -.1387375E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2621690E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6684021E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1186122E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4677903E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1789772E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7865153E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1114772E-01 0.6265229E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254854E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8160000E-06 0.5697364E-06 0.2462636E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2276811E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1926E-13 Mass of aqueous solution: 0.497237E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0017900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5549 -0.256 282.0 2.450 5.163 73.27 grossular 0.1344 -0.872 60.53 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9069E-01 1.574 apatite-F 0.2463E-06 -6.609 0.1242E-03 -3.906 0.2274E-05 0.3880E-04 clinochlore 0.7102 -0.149 394.7 2.596 7.227 150.1 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2593 -0.586 56.15 1.749 1.028 17.16 hedenbergite 0.6724E-01 -1.172 16.68 1.222 0.3054 4.569 microcline 0.9309 -0.031 259.1 2.414 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.4 2.449 5.153 97.22 tr.625ac.25prg.125 0.4360E-01 -1.361 37.26 1.571 0.6822 11.99 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338447 g Volume = 2210.782808 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0017900 moles log = -2.7471 Original solution: 1000.0103000 g Original solution / Rock added: 558664.97 (Water/Rock Ratio), log = 5.7472 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.4354 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7139E+00 0.9817 0.1006E+01 0.1025E+01 CO2,gas 0.5190E-07 1.0028 0.7471E-07 0.7450E-07 CH4,gas 0.2755E+00 1.0087 0.3989E+00 0.3954E+00 H2,gas 0.1059E-01 1.0008 0.1521E-01 0.1519E-01 H2S,gas 0.5160E-06 0.9944 0.7365E-06 0.7407E-06 S2,gas 0.6135E-28 1.0000 0.8806E-28 0.8806E-28 CO,gas 0.2109E-12 1.0000 0.3028E-12 0.3028E-12 SO3,gas 0.2675E-47 1.0000 0.3840E-47 0.3840E-47 SO2,gas 0.1583E-26 1.0000 0.2272E-26 0.2272E-26 HF,gas 0.8338E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4182E-17 1.0000 0.6003E-17 0.6003E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.49 -8.83 -2.942 0.15069E+05 -7.127 3 CH4,gas 4.54 2.45 -2.10 -0.525 0.35825E+04 -0.399 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.06 -7.83 -3.916 0.13373E+05 -6.133 6 S2,gas -7.34 -37.09 -29.75 -4.578 0.50804E+05 -28.055 7 CO,gas 3.21 -11.00 -14.22 -4.375 0.24277E+05 -12.519 8 SO3,gas 17.12 -31.99 -49.11 -12.279 0.83862E+05 -47.416 9 SO2,gas 0.83 -27.51 -28.34 -7.558 0.48394E+05 -26.644 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.73 -18.92 -9.460 0.32306E+05 -17.222 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80706E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.38 -3.35 -1.117 0.57207E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.38 -3.20 -1.065 0.54565E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.52 -3.42 -0.976 0.58356E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.52 -2.97 -0.850 0.50778E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.87 -4.62 -1.088 0.78970E+04 146 pyrrhotite -4.26 -7.33 -3.07 -1.022 0.52363E+04 147 pyrrhotiteFe0.875 -6.02 -8.72 -2.71 -0.996 0.46236E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.33 -2.92 -0.972 0.49792E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.82 -3.84 -1.281 0.65610E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0017900 MOLES New total amount of reactant added: 0.0018300 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8668E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0018300 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7167E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1128109E-01 Osmotic coef. = 0.8215 True ionic strength = .2018150E-01 Chg. balance for total moles = -.8668E-10 Max. difference allowed = 0.1487E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88968E-10 -10.0508 0.74717E-10 -10.1266 0.83982E+00 -0.0758 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.29814E-03 -3.5256 0.24887E-03 -3.6040 0.83474E+00 -0.0784 4 SO4-- 0.35600E-11 -11.4485 0.18448E-11 -11.7340 0.51820E+00 -0.2855 5 HCO3- 0.53384E-05 -5.2726 0.44627E-05 -5.3504 0.83597E+00 -0.0778 6 HS- 0.14094E-03 -3.8510 0.11767E-03 -3.9293 0.83486E+00 -0.0784 7 Al+++ 0.99468E-29 -29.0023 0.22869E-29 -29.6408 0.22991E+00 -0.6384 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13721E-06 -6.8626 0.70579E-07 -7.1513 0.51438E+00 -0.2887 10 Mg++ 0.21466E-10 -10.6682 0.10991E-10 -10.9590 0.51201E+00 -0.2907 11 Fe++ 0.59165E-13 -13.2279 0.30326E-13 -13.5182 0.51257E+00 -0.2902 12 K+ 0.15771E-03 -3.8021 0.13187E-03 -3.8798 0.83617E+00 -0.0777 13 Na+ 0.20013E-01 -1.6987 0.16703E-01 -1.7772 0.83459E+00 -0.0785 14 Mn++ 0.18983E-10 -10.7216 0.97385E-11 -11.0115 0.51300E+00 -0.2899 15 F- 0.11440E-05 -5.9416 0.95297E-06 -6.0209 0.83301E+00 -0.0794 16 HPO4-- 0.44776E-07 -7.3490 0.23207E-07 -7.6344 0.51828E+00 -0.2854 18 HSiO3- 0.10420E-01 -1.9822 0.86976E-02 -2.0606 0.83474E+00 -0.0784 19 Ca(HSiO3)+ 0.16716E-07 -7.7769 0.13980E-07 -7.8545 0.83635E+00 -0.0776 20 Mg(HSiO3)+ 0.32396E-11 -11.4895 0.27094E-11 -11.5671 0.83635E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66632E-16 -16.1763 0.55728E-16 -16.2539 0.83635E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52812E-05 -5.2773 0.44005E-05 -5.3565 0.83322E+00 -0.0792 26 CH4,aq 0.27745E-03 -3.5568 0.27650E-03 -3.5583 0.99656E+00 -0.0015 27 C2H6,aq 0.11323E-11 -11.9460 0.11284E-11 -11.9475 0.99656E+00 -0.0015 28 C3H8,aq 0.10669E-18 -18.9719 0.10632E-18 -18.9734 0.99656E+00 -0.0015 30 ethanol,aq 0.41560E-19 -19.3813 0.41417E-19 -19.3828 0.99656E+00 -0.0015 31 CO,aq 0.20731E-15 -15.6834 0.20731E-15 -15.6834 0.10000E+01 0.0000 32 CO2,aq 0.71495E-09 -9.1457 0.71249E-09 -9.1472 0.99656E+00 -0.0015 33 CO3-2 0.10089E-04 -4.9962 0.52170E-05 -5.2826 0.51710E+00 -0.2864 34 CaCO3,aq 0.46169E-08 -8.3356 0.46169E-08 -8.3356 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.96132E-11 -11.0171 0.80400E-11 -11.0947 0.83635E+00 -0.0776 36 CaCl+ 0.33988E-10 -10.4687 0.28425E-10 -10.5463 0.83635E+00 -0.0776 37 CaCl2,aq 0.16807E-14 -14.7745 0.16807E-14 -14.7745 0.10000E+01 0.0000 38 CaF+ 0.11741E-11 -11.9303 0.98199E-12 -12.0079 0.83635E+00 -0.0776 39 CaOH+ 0.80494E-07 -7.0942 0.67321E-07 -7.1718 0.83635E+00 -0.0776 40 CaSO4,aq 0.41346E-16 -16.3836 0.41346E-16 -16.3836 0.10000E+01 0.0000 41 HCl,aq 0.34074E-14 -14.4676 0.34074E-14 -14.4676 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18788E-18 -18.7261 0.15683E-18 -18.8046 0.83474E+00 -0.0784 48 FeCl+ 0.14284E-16 -16.8452 0.11946E-16 -16.9228 0.83635E+00 -0.0776 51 FeF+ 0.17658E-17 -17.7531 0.14768E-17 -17.8307 0.83635E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15797E-10 -10.8014 0.13212E-10 -10.8790 0.83635E+00 -0.0776 55 HFeO2- 0.35418E-07 -7.4508 0.29565E-07 -7.5292 0.83474E+00 -0.0784 56 FeO+ 0.11071E-16 -16.9558 0.92595E-17 -17.0334 0.83635E+00 -0.0776 58 FeO2- 0.40657E-09 -9.3909 0.33938E-09 -9.4693 0.83474E+00 -0.0784 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11622E-04 -4.9347 0.11582E-04 -4.9362 0.99656E+00 -0.0015 61 KCl,aq 0.59483E-09 -9.2256 0.59483E-09 -9.2256 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.45226E-14 -14.3446 0.37752E-14 -14.4231 0.83474E+00 -0.0784 65 MgCO3,aq 0.18022E-12 -12.7442 0.18022E-12 -12.7442 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15297E-14 -14.8154 0.12794E-14 -14.8930 0.83635E+00 -0.0776 67 MgCl+ 0.47971E-14 -14.3190 0.40120E-14 -14.3966 0.83635E+00 -0.0776 68 MgF+ 0.67731E-15 -15.1692 0.56647E-15 -15.2468 0.83635E+00 -0.0776 69 MgOH+ 0.69363E-10 -10.1589 0.58012E-10 -10.2365 0.83635E+00 -0.0776 71 MnF+ 0.18690E-15 -15.7284 0.15632E-15 -15.8060 0.83635E+00 -0.0776 72 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47124E-09 -9.3268 0.39412E-09 -9.4044 0.83635E+00 -0.0776 74 MnO2-2 0.20768E-10 -10.6826 0.10739E-10 -10.9690 0.51710E+00 -0.2864 75 HMnO2- 0.21059E-09 -9.6766 0.17579E-09 -9.7550 0.83474E+00 -0.0784 78 MnCl+ 0.17845E-13 -13.7485 0.14924E-13 -13.8261 0.83635E+00 -0.0776 80 NaCl,aq 0.13776E-05 -5.8609 0.13776E-05 -5.8609 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92805E-02 -2.0324 0.77327E-02 -2.1117 0.83322E+00 -0.0792 89 HPO3-2 0.16199E-14 -14.7905 0.83765E-15 -15.0769 0.51710E+00 -0.2864 91 H2PO3- 0.15035E-18 -18.8229 0.12551E-18 -18.9013 0.83474E+00 -0.0784 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38283E-10 -10.4170 0.31986E-10 -10.4950 0.83554E+00 -0.0780 94 PO4-3 0.10491E-08 -8.9792 0.25341E-09 -9.5962 0.24155E+00 -0.6170 98 HP2O7-3 0.93157E-18 -18.0308 0.21439E-18 -18.6688 0.23014E+00 -0.6380 99 P2O7-4 0.89654E-17 -17.0474 0.68549E-18 -18.1640 0.76459E-01 -1.1166 100 H2S,aq 0.27266E-07 -7.5644 0.27172E-07 -7.5659 0.99656E+00 -0.0015 101 S2-2 0.51224E-13 -13.2905 0.26488E-13 -13.5769 0.51710E+00 -0.2864 107 SO3-2 0.52928E-17 -17.2763 0.27767E-17 -17.5565 0.52462E+00 -0.2802 108 HSO3- 0.15562E-19 -19.8079 0.12990E-19 -19.8864 0.83474E+00 -0.0784 109 HSO4- 0.15868E-18 -18.7995 0.13284E-18 -18.8767 0.83717E+00 -0.0772 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8896822E-10 -.2218078E-01 -.2231780E+02 0.0000 2 H2O 0.1000000E+01 0.5550516E+02 0.9981931E+06 0.0000 3 Cl- 0.2981396E-03 0.2995178E-03 0.1060023E+02 6.5225 4 SO4-- 0.3560021E-11 -.2803581E-03 -.2688454E+02 8.5191 5 HCO3- 0.5338365E-05 0.2928852E-03 0.1783978E+02 4.7762 6 HS- 0.1409435E-03 0.4213289E-03 0.1390982E+02 6.1972 7 Al+++ 0.9946763E-29 0.5281394E-05 0.1422507E+00 0.7390 8 H4SiO4 0.6959757E-03 0.1346516E-01 0.1291945E+04 -3.1574 9 Ca++ 0.1372121E-06 0.2390837E-06 0.9565236E-02 13.1018 10 Mg++ 0.2146647E-10 0.9425596E-10 0.2287543E-05 9.2942 11 Fe++ 0.5916524E-13 0.3605495E-07 0.2010039E-02 6.7350 12 K+ 0.1577123E-03 0.1584667E-03 0.6185526E+01 6.2467 13 Na+ 0.2001314E-01 0.2246017E-01 0.5154517E+03 8.3494 14 Mn++ 0.1898343E-10 0.2528108E-08 0.1386462E-03 9.2416 15 F- 0.1144006E-05 0.1147734E-05 0.2176651E-01 4.1057 16 HPO4-- 0.4477633E-07 0.4586371E-07 0.4394254E-02 12.6188 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279235E+02 -.1100984E-01 -.8278134E+02 0.0000000E+00 2 H2O -.7167291E+01 0.2755101E+02 -.3471830E+02 0.0000000E+00 3 Cl- 0.1486712E-03 0.1486712E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386013E+00 -.1391609E-03 0.1387404E+00 0.0000000E+00 5 HCO3- 0.1453790E-03 0.1453790E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385313E+00 0.2091344E-03 -.1387404E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2621517E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6683681E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1186736E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4678569E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1789654E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7865786E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1114852E-01 0.6265228E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254873E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8320000E-06 0.5696989E-06 0.2623011E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2276530E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.2220E-15 Mass of aqueous solution: 0.497238E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0018300 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5550 -0.256 282.0 2.450 5.163 73.27 grossular 0.1344 -0.872 60.53 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9069E-01 1.574 apatite-F 0.2623E-06 -6.581 0.1323E-03 -3.879 0.2422E-05 0.4132E-04 clinochlore 0.7102 -0.149 394.7 2.596 7.227 150.1 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2592 -0.586 56.13 1.749 1.028 17.16 hedenbergite 0.6722E-01 -1.173 16.68 1.222 0.3053 4.568 microcline 0.9310 -0.031 259.1 2.414 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.4 2.449 5.152 97.22 tr.625ac.25prg.125 0.4362E-01 -1.360 37.29 1.572 0.6826 12.00 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338460 g Volume = 2210.782918 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0018300 moles log = -2.7375 Original solution: 1000.0103000 g Original solution / Rock added: 546453.72 (Water/Rock Ratio), log = 5.7376 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.4435 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7099E+00 0.9816 0.1006E+01 0.1025E+01 CO2,gas 0.5266E-07 1.0027 0.7623E-07 0.7602E-07 CH4,gas 0.2795E+00 1.0087 0.4070E+00 0.4035E+00 H2,gas 0.1053E-01 1.0008 0.1521E-01 0.1519E-01 H2S,gas 0.5204E-06 0.9944 0.7470E-06 0.7512E-06 S2,gas 0.6274E-28 1.0000 0.9057E-28 0.9057E-28 CO,gas 0.2140E-12 1.0000 0.3089E-12 0.3089E-12 SO3,gas 0.2698E-47 1.0000 0.3894E-47 0.3894E-47 SO2,gas 0.1596E-26 1.0000 0.2304E-26 0.2304E-26 HF,gas 0.8291E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4165E-17 1.0000 0.6012E-17 0.6012E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.18198E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.48 -8.82 -2.939 0.15055E+05 -7.118 3 CH4,gas 4.54 2.45 -2.09 -0.522 0.35676E+04 -0.390 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.06 -7.83 -3.913 0.13362E+05 -6.127 6 S2,gas -7.34 -37.08 -29.74 -4.576 0.50784E+05 -28.043 7 CO,gas 3.21 -10.99 -14.21 -4.372 0.24262E+05 -12.510 8 SO3,gas 17.12 -31.99 -49.11 -12.277 0.83852E+05 -47.410 9 SO2,gas 0.83 -27.50 -28.34 -7.556 0.48384E+05 -26.638 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.73 -18.92 -9.460 0.32305E+05 -17.221 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80706E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.38 -3.34 -1.114 0.57058E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.38 -3.19 -1.062 0.54416E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.51 -3.41 -0.974 0.58207E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.51 -2.97 -0.847 0.50629E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.86 -4.61 -1.085 0.78761E+04 146 pyrrhotite -4.26 -7.32 -3.06 -1.020 0.52259E+04 147 pyrrhotiteFe0.875 -6.02 -8.72 -2.70 -0.994 0.46131E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.32 -2.91 -0.970 0.49687E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.81 -3.84 -1.279 0.65505E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0018300 MOLES New total amount of reactant added: 0.0018700 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8667E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0018700 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7167E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1127773E-01 Osmotic coef. = 0.8274 True ionic strength = .2018330E-01 Chg. balance for total moles = -.8667E-10 Max. difference allowed = 0.1489E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88975E-10 -10.0507 0.74723E-10 -10.1265 0.83982E+00 -0.0758 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.29861E-03 -3.5249 0.24926E-03 -3.6033 0.83474E+00 -0.0785 4 SO4-- 0.36093E-11 -11.4426 0.18703E-11 -11.7281 0.51819E+00 -0.2855 5 HCO3- 0.54442E-05 -5.2641 0.45512E-05 -5.3419 0.83596E+00 -0.0778 6 HS- 0.14290E-03 -3.8450 0.11930E-03 -3.9234 0.83486E+00 -0.0784 7 Al+++ 0.99495E-29 -29.0022 0.22874E-29 -29.6407 0.22990E+00 -0.6385 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13724E-06 -6.8625 0.70589E-07 -7.1513 0.51436E+00 -0.2887 10 Mg++ 0.21470E-10 -10.6682 0.10993E-10 -10.9589 0.51200E+00 -0.2907 11 Fe++ 0.59175E-13 -13.2279 0.30331E-13 -13.5181 0.51256E+00 -0.2903 12 K+ 0.15772E-03 -3.8021 0.13188E-03 -3.8798 0.83616E+00 -0.0777 13 Na+ 0.20015E-01 -1.6987 0.16704E-01 -1.7772 0.83458E+00 -0.0785 14 Mn++ 0.18987E-10 -10.7215 0.97400E-11 -11.0114 0.51299E+00 -0.2899 15 F- 0.11439E-05 -5.9416 0.95290E-06 -6.0210 0.83300E+00 -0.0794 16 HPO4-- 0.44771E-07 -7.3490 0.23203E-07 -7.6345 0.51827E+00 -0.2854 18 HSiO3- 0.10419E-01 -1.9822 0.86970E-02 -2.0606 0.83474E+00 -0.0785 19 Ca(HSiO3)+ 0.16717E-07 -7.7768 0.13981E-07 -7.8545 0.83634E+00 -0.0776 20 Mg(HSiO3)+ 0.32398E-11 -11.4895 0.27096E-11 -11.5671 0.83634E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66638E-16 -16.1763 0.55732E-16 -16.2539 0.83634E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52809E-05 -5.2773 0.44001E-05 -5.3565 0.83322E+00 -0.0792 26 CH4,aq 0.28297E-03 -3.5483 0.28200E-03 -3.5498 0.99656E+00 -0.0015 27 C2H6,aq 0.11778E-11 -11.9289 0.11738E-11 -11.9304 0.99656E+00 -0.0015 28 C3H8,aq 0.11318E-18 -18.9462 0.11279E-18 -18.9477 0.99656E+00 -0.0015 30 ethanol,aq 0.43230E-19 -19.3642 0.43081E-19 -19.3657 0.99656E+00 -0.0015 31 CO,aq 0.21143E-15 -15.6748 0.21143E-15 -15.6748 0.10000E+01 0.0000 32 CO2,aq 0.72918E-09 -9.1372 0.72667E-09 -9.1387 0.99656E+00 -0.0015 33 CO3-2 0.10288E-04 -4.9877 0.53200E-05 -5.2741 0.51709E+00 -0.2864 34 CaCO3,aq 0.47088E-08 -8.3271 0.47088E-08 -8.3271 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.98052E-11 -11.0085 0.82006E-11 -11.0862 0.83634E+00 -0.0776 36 CaCl+ 0.34046E-10 -10.4679 0.28475E-10 -10.5455 0.83634E+00 -0.0776 37 CaCl2,aq 0.16862E-14 -14.7731 0.16862E-14 -14.7731 0.10000E+01 0.0000 38 CaF+ 0.11742E-11 -11.9302 0.98206E-12 -12.0079 0.83634E+00 -0.0776 39 CaOH+ 0.80501E-07 -7.0942 0.67326E-07 -7.1718 0.83634E+00 -0.0776 40 CaSO4,aq 0.41923E-16 -16.3775 0.41923E-16 -16.3775 0.10000E+01 0.0000 41 HCl,aq 0.34131E-14 -14.4669 0.34131E-14 -14.4669 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18787E-18 -18.7261 0.15682E-18 -18.8046 0.83474E+00 -0.0785 48 FeCl+ 0.14308E-16 -16.8444 0.11967E-16 -16.9220 0.83634E+00 -0.0776 51 FeF+ 0.17660E-17 -17.7530 0.14770E-17 -17.8306 0.83634E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15798E-10 -10.8014 0.13213E-10 -10.8790 0.83634E+00 -0.0776 55 HFeO2- 0.35416E-07 -7.4508 0.29563E-07 -7.5293 0.83474E+00 -0.0785 56 FeO+ 0.11072E-16 -16.9558 0.92602E-17 -17.0334 0.83634E+00 -0.0776 58 FeO2- 0.40655E-09 -9.3909 0.33936E-09 -9.4693 0.83474E+00 -0.0785 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11622E-04 -4.9347 0.11582E-04 -4.9362 0.99656E+00 -0.0015 61 KCl,aq 0.59581E-09 -9.2249 0.59581E-09 -9.2249 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.45854E-14 -14.3386 0.38276E-14 -14.4171 0.83474E+00 -0.0785 65 MgCO3,aq 0.18380E-12 -12.7356 0.18380E-12 -12.7356 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15603E-14 -14.8068 0.13049E-14 -14.8844 0.83634E+00 -0.0776 67 MgCl+ 0.48054E-14 -14.3183 0.40190E-14 -14.3959 0.83634E+00 -0.0776 68 MgF+ 0.67737E-15 -15.1692 0.56651E-15 -15.2468 0.83634E+00 -0.0776 69 MgOH+ 0.69369E-10 -10.1588 0.58016E-10 -10.2365 0.83634E+00 -0.0776 71 MnF+ 0.18692E-15 -15.7283 0.15633E-15 -15.8060 0.83634E+00 -0.0776 72 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47128E-09 -9.3267 0.39415E-09 -9.4043 0.83634E+00 -0.0776 74 MnO2-2 0.20765E-10 -10.6827 0.10737E-10 -10.9691 0.51709E+00 -0.2864 75 HMnO2- 0.21058E-09 -9.6766 0.17578E-09 -9.7550 0.83474E+00 -0.0785 78 MnCl+ 0.17876E-13 -13.7477 0.14950E-13 -13.8254 0.83634E+00 -0.0776 80 NaCl,aq 0.13798E-05 -5.8602 0.13798E-05 -5.8602 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92799E-02 -2.0325 0.77322E-02 -2.1117 0.83322E+00 -0.0792 89 HPO3-2 0.16197E-14 -14.7906 0.83752E-15 -15.0770 0.51709E+00 -0.2864 91 H2PO3- 0.15034E-18 -18.8229 0.12550E-18 -18.9014 0.83474E+00 -0.0785 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38280E-10 -10.4170 0.31984E-10 -10.4951 0.83553E+00 -0.0780 94 PO4-3 0.10489E-08 -8.9793 0.25335E-09 -9.5963 0.24154E+00 -0.6170 98 HP2O7-3 0.93141E-18 -18.0309 0.21435E-18 -18.6689 0.23013E+00 -0.6380 99 P2O7-4 0.89636E-17 -17.0475 0.68529E-18 -18.1641 0.76452E-01 -1.1166 100 H2S,aq 0.27647E-07 -7.5584 0.27552E-07 -7.5599 0.99656E+00 -0.0015 101 S2-2 0.52658E-13 -13.2785 0.27229E-13 -13.5650 0.51709E+00 -0.2864 107 SO3-2 0.53660E-17 -17.2703 0.28151E-17 -17.5505 0.52461E+00 -0.2802 108 HSO3- 0.15778E-19 -19.8019 0.13171E-19 -19.8804 0.83474E+00 -0.0785 109 HSO4- 0.16088E-18 -18.7935 0.13468E-18 -18.8707 0.83716E+00 -0.0772 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8897528E-10 -.2217965E-01 -.2231665E+02 0.0000 2 H2O 0.1000000E+01 0.5550516E+02 0.9981930E+06 0.0000 3 Cl- 0.2986123E-03 0.2999928E-03 0.1061704E+02 6.5232 4 SO4-- 0.3609264E-11 -.2858786E-03 -.2741391E+02 8.5250 5 HCO3- 0.5444220E-05 0.2987111E-03 0.1819463E+02 4.7847 6 HS- 0.1429012E-03 0.4288074E-03 0.1415671E+02 6.2032 7 Al+++ 0.9949498E-29 0.5281038E-05 0.1422411E+00 0.7390 8 H4SiO4 0.6959756E-03 0.1346445E-01 0.1291878E+04 -3.1574 9 Ca++ 0.1372356E-06 0.2392070E-06 0.9570170E-02 13.1018 10 Mg++ 0.2147015E-10 0.9427013E-10 0.2287886E-05 9.2942 11 Fe++ 0.5917540E-13 0.3605252E-07 0.2009903E-02 6.7350 12 K+ 0.1577248E-03 0.1584792E-03 0.6186013E+01 6.2467 13 Na+ 0.2001473E-01 0.2246177E-01 0.5154882E+03 8.3494 14 Mn++ 0.1898676E-10 0.2528141E-08 0.1386481E-03 9.2416 15 F- 0.1143928E-05 0.1147657E-05 0.2176504E-01 4.1056 16 HPO4-- 0.4477078E-07 0.4585798E-07 0.4393704E-02 12.6186 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279235E+02 -.1100930E-01 -.8278134E+02 0.0000000E+00 2 H2O -.7167258E+01 0.2755105E+02 -.3471831E+02 0.0000000E+00 3 Cl- 0.1489072E-03 0.1489072E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386015E+00 -.1419013E-03 0.1387434E+00 0.0000000E+00 5 HCO3- 0.1482710E-03 0.1482710E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385305E+00 0.2128468E-03 -.1387434E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2621345E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6683340E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1187350E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4679279E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1789536E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7866419E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1114933E-01 0.6265228E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254892E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8480000E-06 0.5696614E-06 0.2783386E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2276249E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.7772E-14 Mass of aqueous solution: 0.497239E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0018700 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5550 -0.256 282.0 2.450 5.163 73.27 grossular 0.1344 -0.872 60.53 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9069E-01 1.574 apatite-F 0.2783E-06 -6.555 0.1404E-03 -3.853 0.2570E-05 0.4385E-04 clinochlore 0.7102 -0.149 394.7 2.596 7.227 150.1 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2591 -0.586 56.12 1.749 1.027 17.15 hedenbergite 0.6720E-01 -1.173 16.67 1.222 0.3052 4.566 microcline 0.9310 -0.031 259.1 2.414 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.4 2.449 5.152 97.21 tr.625ac.25prg.125 0.4365E-01 -1.360 37.31 1.572 0.6830 12.01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338472 g Volume = 2210.783029 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0018700 moles log = -2.7282 Original solution: 1000.0103000 g Original solution / Rock added: 534764.87 (Water/Rock Ratio), log = 5.7282 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.4516 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7060E+00 0.9815 0.1006E+01 0.1025E+01 CO2,gas 0.5341E-07 1.0027 0.7775E-07 0.7754E-07 CH4,gas 0.2835E+00 1.0086 0.4151E+00 0.4115E+00 H2,gas 0.1047E-01 1.0008 0.1521E-01 0.1519E-01 H2S,gas 0.5247E-06 0.9944 0.7574E-06 0.7617E-06 S2,gas 0.6415E-28 1.0000 0.9311E-28 0.9311E-28 CO,gas 0.2171E-12 1.0000 0.3151E-12 0.3151E-12 SO3,gas 0.2720E-47 1.0000 0.3948E-47 0.3948E-47 SO2,gas 0.1609E-26 1.0000 0.2336E-26 0.2336E-26 HF,gas 0.8245E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4149E-17 1.0000 0.6022E-17 0.6022E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.47 -8.81 -2.936 0.15040E+05 -7.109 3 CH4,gas 4.54 2.46 -2.08 -0.520 0.35530E+04 -0.382 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.05 -7.82 -3.910 0.13352E+05 -6.121 6 S2,gas -7.34 -37.07 -29.73 -4.574 0.50763E+05 -28.031 7 CO,gas 3.21 -10.99 -14.20 -4.369 0.24247E+05 -12.502 8 SO3,gas 17.12 -31.98 -49.10 -12.276 0.83841E+05 -47.404 9 SO2,gas 0.83 -27.50 -28.33 -7.555 0.48374E+05 -26.632 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.73 -18.92 -9.460 0.32304E+05 -17.220 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80706E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.37 -3.33 -1.111 0.56912E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.37 -3.18 -1.059 0.54270E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.50 -3.40 -0.972 0.58061E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.50 -2.96 -0.845 0.50483E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.85 -4.60 -1.083 0.78556E+04 146 pyrrhotite -4.26 -7.31 -3.05 -1.018 0.52156E+04 147 pyrrhotiteFe0.875 -6.02 -8.71 -2.70 -0.991 0.46029E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47125E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.31 -2.90 -0.968 0.49585E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.81 -3.83 -1.277 0.65403E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0018700 MOLES New total amount of reactant added: 0.0019100 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8666E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0019100 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7167E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1127438E-01 Osmotic coef. = 0.8327 True ionic strength = .2018511E-01 Chg. balance for total moles = -.8666E-10 Max. difference allowed = 0.1491E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88982E-10 -10.0507 0.74728E-10 -10.1265 0.83981E+00 -0.0758 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.29909E-03 -3.5242 0.24966E-03 -3.6027 0.83473E+00 -0.0785 4 SO4-- 0.36585E-11 -11.4367 0.18958E-11 -11.7222 0.51818E+00 -0.2855 5 HCO3- 0.55501E-05 -5.2557 0.46396E-05 -5.3335 0.83596E+00 -0.0778 6 HS- 0.14486E-03 -3.8391 0.12094E-03 -3.9174 0.83485E+00 -0.0784 7 Al+++ 0.99522E-29 -29.0021 0.22879E-29 -29.6406 0.22989E+00 -0.6385 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13726E-06 -6.8625 0.70599E-07 -7.1512 0.51435E+00 -0.2887 10 Mg++ 0.21474E-10 -10.6681 0.10994E-10 -10.9588 0.51198E+00 -0.2907 11 Fe++ 0.59186E-13 -13.2278 0.30335E-13 -13.5181 0.51255E+00 -0.2903 12 K+ 0.15774E-03 -3.8021 0.13189E-03 -3.8798 0.83616E+00 -0.0777 13 Na+ 0.20016E-01 -1.6986 0.16705E-01 -1.7771 0.83458E+00 -0.0785 14 Mn++ 0.18990E-10 -10.7215 0.97414E-11 -11.0114 0.51298E+00 -0.2899 15 F- 0.11439E-05 -5.9416 0.95283E-06 -6.0210 0.83300E+00 -0.0794 16 HPO4-- 0.44765E-07 -7.3491 0.23200E-07 -7.6345 0.51825E+00 -0.2855 18 HSiO3- 0.10418E-01 -1.9822 0.86963E-02 -2.0607 0.83473E+00 -0.0785 19 Ca(HSiO3)+ 0.16718E-07 -7.7768 0.13982E-07 -7.8544 0.83634E+00 -0.0776 20 Mg(HSiO3)+ 0.32401E-11 -11.4894 0.27098E-11 -11.5671 0.83634E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66643E-16 -16.1762 0.55736E-16 -16.2539 0.83634E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52805E-05 -5.2773 0.43998E-05 -5.3566 0.83321E+00 -0.0792 26 CH4,aq 0.28849E-03 -3.5399 0.28750E-03 -3.5414 0.99656E+00 -0.0015 27 C2H6,aq 0.12242E-11 -11.9121 0.12200E-11 -11.9136 0.99656E+00 -0.0015 28 C3H8,aq 0.11994E-18 -18.9210 0.11952E-18 -18.9225 0.99656E+00 -0.0015 30 ethanol,aq 0.44933E-19 -19.3474 0.44779E-19 -19.3489 0.99656E+00 -0.0015 31 CO,aq 0.21556E-15 -15.6664 0.21556E-15 -15.6664 0.10000E+01 0.0000 32 CO2,aq 0.74340E-09 -9.1288 0.74085E-09 -9.1303 0.99656E+00 -0.0015 33 CO3-2 0.10488E-04 -4.9793 0.54230E-05 -5.2658 0.51707E+00 -0.2864 34 CaCO3,aq 0.48007E-08 -8.3187 0.48007E-08 -8.3187 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.99973E-11 -11.0001 0.83612E-11 -11.0777 0.83634E+00 -0.0776 36 CaCl+ 0.34105E-10 -10.4672 0.28524E-10 -10.5448 0.83634E+00 -0.0776 37 CaCl2,aq 0.16918E-14 -14.7716 0.16918E-14 -14.7716 0.10000E+01 0.0000 38 CaF+ 0.11743E-11 -11.9302 0.98213E-12 -12.0078 0.83634E+00 -0.0776 39 CaOH+ 0.80507E-07 -7.0942 0.67331E-07 -7.1718 0.83634E+00 -0.0776 40 CaSO4,aq 0.42500E-16 -16.3716 0.42500E-16 -16.3716 0.10000E+01 0.0000 41 HCl,aq 0.34187E-14 -14.4661 0.34187E-14 -14.4661 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18785E-18 -18.7262 0.15681E-18 -18.8046 0.83473E+00 -0.0785 48 FeCl+ 0.14333E-16 -16.8437 0.11987E-16 -16.9213 0.83634E+00 -0.0776 51 FeF+ 0.17661E-17 -17.7530 0.14771E-17 -17.8306 0.83634E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15800E-10 -10.8014 0.13214E-10 -10.8790 0.83634E+00 -0.0776 55 HFeO2- 0.35413E-07 -7.4508 0.29561E-07 -7.5293 0.83473E+00 -0.0785 56 FeO+ 0.11073E-16 -16.9557 0.92609E-17 -17.0333 0.83634E+00 -0.0776 58 FeO2- 0.40652E-09 -9.3909 0.33933E-09 -9.4694 0.83473E+00 -0.0785 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11622E-04 -4.9347 0.11582E-04 -4.9362 0.99656E+00 -0.0015 61 KCl,aq 0.59679E-09 -9.2242 0.59679E-09 -9.2242 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.46482E-14 -14.3327 0.38800E-14 -14.4112 0.83473E+00 -0.0785 65 MgCO3,aq 0.18739E-12 -12.7273 0.18739E-12 -12.7273 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15908E-14 -14.7984 0.13305E-14 -14.8760 0.83634E+00 -0.0776 67 MgCl+ 0.48137E-14 -14.3175 0.40259E-14 -14.3951 0.83634E+00 -0.0776 68 MgF+ 0.67742E-15 -15.1691 0.56655E-15 -15.2468 0.83634E+00 -0.0776 69 MgOH+ 0.69374E-10 -10.1588 0.58020E-10 -10.2364 0.83634E+00 -0.0776 71 MnF+ 0.18693E-15 -15.7283 0.15634E-15 -15.8059 0.83634E+00 -0.0776 72 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47132E-09 -9.3267 0.39419E-09 -9.4043 0.83634E+00 -0.0776 74 MnO2-2 0.20763E-10 -10.6827 0.10736E-10 -10.9692 0.51707E+00 -0.2864 75 HMnO2- 0.21057E-09 -9.6766 0.17577E-09 -9.7551 0.83473E+00 -0.0785 78 MnCl+ 0.17907E-13 -13.7470 0.14976E-13 -13.8246 0.83634E+00 -0.0776 80 NaCl,aq 0.13821E-05 -5.8595 0.13821E-05 -5.8595 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92793E-02 -2.0325 0.77316E-02 -2.1117 0.83321E+00 -0.0792 89 HPO3-2 0.16195E-14 -14.7906 0.83740E-15 -15.0771 0.51707E+00 -0.2864 91 H2PO3- 0.15033E-18 -18.8229 0.12549E-18 -18.9014 0.83473E+00 -0.0785 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38277E-10 -10.4171 0.31982E-10 -10.4951 0.83553E+00 -0.0780 94 PO4-3 0.10487E-08 -8.9793 0.25330E-09 -9.5964 0.24153E+00 -0.6170 98 HP2O7-3 0.93125E-18 -18.0309 0.21430E-18 -18.6690 0.23012E+00 -0.6380 99 P2O7-4 0.89618E-17 -17.0476 0.68508E-18 -18.1643 0.76445E-01 -1.1167 100 H2S,aq 0.28027E-07 -7.5524 0.27931E-07 -7.5539 0.99656E+00 -0.0015 101 S2-2 0.54111E-13 -13.2667 0.27979E-13 -13.5532 0.51707E+00 -0.2864 107 SO3-2 0.54392E-17 -17.2645 0.28534E-17 -17.5446 0.52460E+00 -0.2802 108 HSO3- 0.15994E-19 -19.7960 0.13351E-19 -19.8745 0.83473E+00 -0.0785 109 HSO4- 0.16308E-18 -18.7876 0.13653E-18 -18.8648 0.83716E+00 -0.0772 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8898234E-10 -.2217852E-01 -.2231551E+02 0.0000 2 H2O 0.1000000E+01 0.5550517E+02 0.9981930E+06 0.0000 3 Cl- 0.2990850E-03 0.3004678E-03 0.1063385E+02 6.5239 4 SO4-- 0.3658502E-11 -.2913990E-03 -.2794329E+02 8.5308 5 HCO3- 0.5550061E-05 0.3045370E-03 0.1854949E+02 4.7930 6 HS- 0.1448588E-03 0.4362859E-03 0.1440360E+02 6.2091 7 Al+++ 0.9952233E-29 0.5280682E-05 0.1422315E+00 0.7390 8 H4SiO4 0.6959756E-03 0.1346375E-01 0.1291810E+04 -3.1574 9 Ca++ 0.1372592E-06 0.2393304E-06 0.9575104E-02 13.1018 10 Mg++ 0.2147384E-10 0.9428252E-10 0.2288187E-05 9.2942 11 Fe++ 0.5918556E-13 0.3605010E-07 0.2009768E-02 6.7350 12 K+ 0.1577374E-03 0.1584917E-03 0.6186501E+01 6.2467 13 Na+ 0.2001632E-01 0.2246336E-01 0.5155247E+03 8.3494 14 Mn++ 0.1899009E-10 0.2528175E-08 0.1386499E-03 9.2417 15 F- 0.1143851E-05 0.1147579E-05 0.2176357E-01 4.1055 16 HPO4-- 0.4476524E-07 0.4585226E-07 0.4393155E-02 12.6185 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279234E+02 -.1100875E-01 -.8278133E+02 0.0000000E+00 2 H2O -.7167225E+01 0.2755110E+02 -.3471832E+02 0.0000000E+00 3 Cl- 0.1491432E-03 0.1491432E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386016E+00 -.1446417E-03 0.1387463E+00 0.0000000E+00 5 HCO3- 0.1511630E-03 0.1511630E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385297E+00 0.2165592E-03 -.1387463E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2621172E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6683000E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1187964E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4679901E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1789419E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7867052E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1115014E-01 0.6265227E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254910E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8640000E-06 0.5696239E-06 0.2943761E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2275968E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1074E-13 Mass of aqueous solution: 0.497240E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0019100 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5550 -0.256 282.0 2.450 5.163 73.27 grossular 0.1344 -0.872 60.53 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9069E-01 1.574 apatite-F 0.2944E-06 -6.531 0.1485E-03 -3.828 0.2718E-05 0.4638E-04 clinochlore 0.7102 -0.149 394.7 2.596 7.227 150.1 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2590 -0.587 56.10 1.749 1.027 17.15 hedenbergite 0.6718E-01 -1.173 16.67 1.222 0.3051 4.565 microcline 0.9310 -0.031 259.1 2.414 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.4 2.449 5.152 97.21 tr.625ac.25prg.125 0.4367E-01 -1.360 37.33 1.572 0.6834 12.01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338485 g Volume = 2210.783139 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0019100 moles log = -2.7190 Original solution: 1000.0103000 g Original solution / Rock added: 523565.60 (Water/Rock Ratio), log = 5.7190 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.4597 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7021E+00 0.9815 0.1006E+01 0.1025E+01 CO2,gas 0.5416E-07 1.0026 0.7926E-07 0.7906E-07 CH4,gas 0.2875E+00 1.0085 0.4232E+00 0.4196E+00 H2,gas 0.1041E-01 1.0008 0.1521E-01 0.1519E-01 H2S,gas 0.5290E-06 0.9943 0.7678E-06 0.7722E-06 S2,gas 0.6556E-28 1.0000 0.9570E-28 0.9570E-28 CO,gas 0.2201E-12 1.0000 0.3212E-12 0.3212E-12 SO3,gas 0.2742E-47 1.0000 0.4003E-47 0.4003E-47 SO2,gas 0.1622E-26 1.0000 0.2368E-26 0.2368E-26 HF,gas 0.8199E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4133E-17 1.0000 0.6032E-17 0.6032E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.36397E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.46 -8.80 -2.933 0.15026E+05 -7.101 3 CH4,gas 4.54 2.47 -2.07 -0.518 0.35386E+04 -0.373 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.04 -7.81 -3.907 0.13342E+05 -6.115 6 S2,gas -7.34 -37.05 -29.72 -4.572 0.50743E+05 -28.019 7 CO,gas 3.21 -10.98 -14.19 -4.367 0.24233E+05 -12.493 8 SO3,gas 17.12 -31.98 -49.10 -12.274 0.83831E+05 -47.398 9 SO2,gas 0.83 -27.49 -28.32 -7.553 0.48363E+05 -26.626 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.73 -18.92 -9.459 0.32303E+05 -17.220 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80706E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.36 -3.32 -1.108 0.56769E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.36 -3.17 -1.057 0.54126E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.49 -3.39 -0.969 0.57917E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.49 -2.95 -0.842 0.50340E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.84 -4.59 -1.080 0.78353E+04 146 pyrrhotite -4.26 -7.31 -3.05 -1.016 0.52055E+04 147 pyrrhotiteFe0.875 -6.02 -8.71 -2.69 -0.989 0.45927E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47124E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.31 -2.90 -0.966 0.49483E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.80 -3.82 -1.275 0.65301E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0019100 MOLES New total amount of reactant added: 0.0019500 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8666E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0019500 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7167E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1127103E-01 Osmotic coef. = 0.8373 True ionic strength = .2018691E-01 Chg. balance for total moles = -.8666E-10 Max. difference allowed = 0.1494E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88989E-10 -10.0507 0.74734E-10 -10.1265 0.83981E+00 -0.0758 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.29956E-03 -3.5235 0.25005E-03 -3.6020 0.83472E+00 -0.0785 4 SO4-- 0.37077E-11 -11.4309 0.19212E-11 -11.7164 0.51817E+00 -0.2855 5 HCO3- 0.56559E-05 -5.2475 0.47281E-05 -5.3253 0.83595E+00 -0.0778 6 HS- 0.14682E-03 -3.8332 0.12257E-03 -3.9116 0.83485E+00 -0.0784 7 Al+++ 0.99550E-29 -29.0020 0.22884E-29 -29.6405 0.22987E+00 -0.6385 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13728E-06 -6.8624 0.70610E-07 -7.1511 0.51434E+00 -0.2888 10 Mg++ 0.21478E-10 -10.6680 0.10996E-10 -10.9588 0.51197E+00 -0.2908 11 Fe++ 0.59196E-13 -13.2277 0.30340E-13 -13.5180 0.51254E+00 -0.2903 12 K+ 0.15775E-03 -3.8020 0.13190E-03 -3.8797 0.83615E+00 -0.0777 13 Na+ 0.20018E-01 -1.6986 0.16706E-01 -1.7771 0.83457E+00 -0.0785 14 Mn++ 0.18993E-10 -10.7214 0.97429E-11 -11.0113 0.51296E+00 -0.2899 15 F- 0.11438E-05 -5.9417 0.95276E-06 -6.0210 0.83299E+00 -0.0794 16 HPO4-- 0.44760E-07 -7.3491 0.23196E-07 -7.6346 0.51824E+00 -0.2855 18 HSiO3- 0.10417E-01 -1.9822 0.86957E-02 -2.0607 0.83472E+00 -0.0785 19 Ca(HSiO3)+ 0.16720E-07 -7.7768 0.13983E-07 -7.8544 0.83633E+00 -0.0776 20 Mg(HSiO3)+ 0.32403E-11 -11.4894 0.27100E-11 -11.5670 0.83633E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66648E-16 -16.1762 0.55740E-16 -16.2538 0.83633E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52802E-05 -5.2774 0.43995E-05 -5.3566 0.83321E+00 -0.0792 26 CH4,aq 0.29401E-03 -3.5316 0.29300E-03 -3.5331 0.99656E+00 -0.0015 27 C2H6,aq 0.12715E-11 -11.8957 0.12671E-11 -11.8972 0.99656E+00 -0.0015 28 C3H8,aq 0.12695E-18 -18.8964 0.12652E-18 -18.8978 0.99656E+00 -0.0015 30 ethanol,aq 0.46669E-19 -19.3310 0.46509E-19 -19.3325 0.99656E+00 -0.0015 31 CO,aq 0.21968E-15 -15.6582 0.21968E-15 -15.6582 0.10000E+01 0.0000 32 CO2,aq 0.75763E-09 -9.1205 0.75502E-09 -9.1220 0.99656E+00 -0.0015 33 CO3-2 0.10687E-04 -4.9711 0.55260E-05 -5.2576 0.51706E+00 -0.2865 34 CaCO3,aq 0.48925E-08 -8.3105 0.48925E-08 -8.3105 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10189E-10 -10.9918 0.85218E-11 -11.0695 0.83633E+00 -0.0776 36 CaCl+ 0.34164E-10 -10.4664 0.28573E-10 -10.5440 0.83633E+00 -0.0776 37 CaCl2,aq 0.16974E-14 -14.7702 0.16974E-14 -14.7702 0.10000E+01 0.0000 38 CaF+ 0.11744E-11 -11.9302 0.98221E-12 -12.0078 0.83633E+00 -0.0776 39 CaOH+ 0.80513E-07 -7.0941 0.67336E-07 -7.1718 0.83633E+00 -0.0776 40 CaSO4,aq 0.43078E-16 -16.3657 0.43078E-16 -16.3657 0.10000E+01 0.0000 41 HCl,aq 0.34243E-14 -14.4654 0.34243E-14 -14.4654 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18784E-18 -18.7262 0.15680E-18 -18.8047 0.83472E+00 -0.0785 48 FeCl+ 0.14358E-16 -16.8429 0.12008E-16 -16.9205 0.83633E+00 -0.0776 51 FeF+ 0.17662E-17 -17.7529 0.14772E-17 -17.8306 0.83633E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15801E-10 -10.8013 0.13215E-10 -10.8789 0.83633E+00 -0.0776 55 HFeO2- 0.35411E-07 -7.4509 0.29558E-07 -7.5293 0.83472E+00 -0.0785 56 FeO+ 0.11074E-16 -16.9557 0.92615E-17 -17.0333 0.83633E+00 -0.0776 58 FeO2- 0.40649E-09 -9.3909 0.33931E-09 -9.4694 0.83472E+00 -0.0785 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11622E-04 -4.9347 0.11582E-04 -4.9362 0.99656E+00 -0.0015 61 KCl,aq 0.59778E-09 -9.2235 0.59778E-09 -9.2235 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.47110E-14 -14.3269 0.39324E-14 -14.4053 0.83472E+00 -0.0785 65 MgCO3,aq 0.19097E-12 -12.7190 0.19097E-12 -12.7190 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16214E-14 -14.7901 0.13560E-14 -14.8677 0.83633E+00 -0.0776 67 MgCl+ 0.48220E-14 -14.3168 0.40328E-14 -14.3944 0.83633E+00 -0.0776 68 MgF+ 0.67748E-15 -15.1691 0.56660E-15 -15.2467 0.83633E+00 -0.0776 69 MgOH+ 0.69380E-10 -10.1588 0.58025E-10 -10.2364 0.83633E+00 -0.0776 71 MnF+ 0.18695E-15 -15.7283 0.15635E-15 -15.8059 0.83633E+00 -0.0776 72 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47136E-09 -9.3266 0.39422E-09 -9.4043 0.83633E+00 -0.0776 74 MnO2-2 0.20760E-10 -10.6828 0.10734E-10 -10.9692 0.51706E+00 -0.2865 75 HMnO2- 0.21055E-09 -9.6766 0.17575E-09 -9.7551 0.83472E+00 -0.0785 78 MnCl+ 0.17938E-13 -13.7462 0.15002E-13 -13.8239 0.83633E+00 -0.0776 80 NaCl,aq 0.13844E-05 -5.8587 0.13844E-05 -5.8587 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92786E-02 -2.0325 0.77310E-02 -2.1118 0.83321E+00 -0.0792 89 HPO3-2 0.16193E-14 -14.7907 0.83728E-15 -15.0771 0.51706E+00 -0.2865 91 H2PO3- 0.15032E-18 -18.8230 0.12548E-18 -18.9014 0.83472E+00 -0.0785 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38275E-10 -10.4171 0.31979E-10 -10.4951 0.83552E+00 -0.0780 94 PO4-3 0.10486E-08 -8.9794 0.25324E-09 -9.5965 0.24151E+00 -0.6171 98 HP2O7-3 0.93110E-18 -18.0310 0.21425E-18 -18.6691 0.23011E+00 -0.6381 99 P2O7-4 0.89600E-17 -17.0477 0.68488E-18 -18.1644 0.76437E-01 -1.1167 100 H2S,aq 0.28408E-07 -7.5466 0.28310E-07 -7.5481 0.99656E+00 -0.0015 101 S2-2 0.55584E-13 -13.2550 0.28740E-13 -13.5415 0.51706E+00 -0.2865 107 SO3-2 0.55124E-17 -17.2587 0.28917E-17 -17.5388 0.52459E+00 -0.2802 108 HSO3- 0.16210E-19 -19.7902 0.13531E-19 -19.8687 0.83472E+00 -0.0785 109 HSO4- 0.16529E-18 -18.7818 0.13837E-18 -18.8590 0.83715E+00 -0.0772 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8898940E-10 -.2217738E-01 -.2231436E+02 0.0000 2 H2O 0.1000000E+01 0.5550517E+02 0.9981929E+06 0.0000 3 Cl- 0.2995578E-03 0.3009428E-03 0.1065066E+02 6.5245 4 SO4-- 0.3707735E-11 -.2969196E-03 -.2847267E+02 8.5365 5 HCO3- 0.5655889E-05 0.3103628E-03 0.1890434E+02 4.8012 6 HS- 0.1468164E-03 0.4437644E-03 0.1465050E+02 6.2149 7 Al+++ 0.9954969E-29 0.5280326E-05 0.1422218E+00 0.7390 8 H4SiO4 0.6959755E-03 0.1346304E-01 0.1291742E+04 -3.1574 9 Ca++ 0.1372827E-06 0.2394538E-06 0.9580039E-02 13.1018 10 Mg++ 0.2147753E-10 0.9429580E-10 0.2288509E-05 9.2942 11 Fe++ 0.5919572E-13 0.3604768E-07 0.2009632E-02 6.7350 12 K+ 0.1577499E-03 0.1585042E-03 0.6186988E+01 6.2467 13 Na+ 0.2001791E-01 0.2246495E-01 0.5155611E+03 8.3494 14 Mn++ 0.1899343E-10 0.2528209E-08 0.1386517E-03 9.2417 15 F- 0.1143774E-05 0.1147502E-05 0.2176210E-01 4.1055 16 HPO4-- 0.4475969E-07 0.4584653E-07 0.4392605E-02 12.6184 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279234E+02 -.1100820E-01 -.8278133E+02 0.0000000E+00 2 H2O -.7167192E+01 0.2755114E+02 -.3471833E+02 0.0000000E+00 3 Cl- 0.1493792E-03 0.1493792E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386018E+00 -.1473822E-03 0.1387492E+00 0.0000000E+00 5 HCO3- 0.1540550E-03 0.1540550E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385289E+00 0.2202716E-03 -.1387492E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2620999E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6682660E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1188578E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4680567E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1789301E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7867685E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1115094E-01 0.6265226E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254929E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8800000E-06 0.5695864E-06 0.3104136E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2275687E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.8417E-14 Mass of aqueous solution: 0.497241E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0019500 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5550 -0.256 282.0 2.450 5.163 73.28 grossular 0.1344 -0.872 60.53 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9069E-01 1.574 apatite-F 0.3104E-06 -6.508 0.1565E-03 -3.805 0.2866E-05 0.4890E-04 clinochlore 0.7102 -0.149 394.7 2.596 7.227 150.1 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2590 -0.587 56.08 1.749 1.027 17.14 hedenbergite 0.6716E-01 -1.173 16.66 1.222 0.3050 4.564 microcline 0.9310 -0.031 259.1 2.414 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.4 2.449 5.152 97.21 tr.625ac.25prg.125 0.4370E-01 -1.360 37.35 1.572 0.6838 12.02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338498 g Volume = 2210.783249 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0019500 moles log = -2.7100 Original solution: 1000.0103000 g Original solution / Rock added: 512825.79 (Water/Rock Ratio), log = 5.7100 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.4678 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.6983E+00 0.9814 0.1006E+01 0.1025E+01 CO2,gas 0.5489E-07 1.0025 0.8078E-07 0.8057E-07 CH4,gas 0.2913E+00 1.0085 0.4313E+00 0.4277E+00 H2,gas 0.1035E-01 1.0008 0.1521E-01 0.1519E-01 H2S,gas 0.5332E-06 0.9943 0.7782E-06 0.7827E-06 S2,gas 0.6698E-28 1.0000 0.9831E-28 0.9831E-28 CO,gas 0.2230E-12 1.0000 0.3274E-12 0.3274E-12 SO3,gas 0.2764E-47 1.0000 0.4057E-47 0.4057E-47 SO2,gas 0.1635E-26 1.0000 0.2400E-26 0.2400E-26 HF,gas 0.8154E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4116E-17 1.0000 0.6042E-17 0.6042E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.45 -8.79 -2.931 0.15012E+05 -7.093 3 CH4,gas 4.54 2.48 -2.06 -0.516 0.35246E+04 -0.365 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.04 -7.81 -3.904 0.13332E+05 -6.109 6 S2,gas -7.34 -37.04 -29.71 -4.570 0.50723E+05 -28.007 7 CO,gas 3.21 -10.97 -14.18 -4.364 0.24219E+05 -12.485 8 SO3,gas 17.12 -31.97 -49.09 -12.273 0.83821E+05 -47.392 9 SO2,gas 0.83 -27.49 -28.32 -7.552 0.48353E+05 -26.620 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.73 -18.92 -9.459 0.32302E+05 -17.219 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80706E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.35 -3.32 -1.105 0.56628E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.35 -3.16 -1.054 0.53986E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.49 -3.38 -0.967 0.57777E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.49 -2.94 -0.840 0.50199E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.82 -4.58 -1.077 0.78153E+04 146 pyrrhotite -4.26 -7.30 -3.04 -1.014 0.51955E+04 147 pyrrhotiteFe0.875 -6.02 -8.70 -2.68 -0.987 0.45827E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22444E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47124E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.30 -2.89 -0.964 0.49383E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.80 -3.82 -1.273 0.65201E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0019500 MOLES New total amount of reactant added: 0.0019900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8668E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0019900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7167E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1126768E-01 Osmotic coef. = 0.8415 True ionic strength = .2018871E-01 Chg. balance for total moles = -.8668E-10 Max. difference allowed = 0.1496E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88996E-10 -10.0506 0.74739E-10 -10.1264 0.83980E+00 -0.0758 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.30003E-03 -3.5228 0.25044E-03 -3.6013 0.83472E+00 -0.0785 4 SO4-- 0.37570E-11 -11.4252 0.19467E-11 -11.7107 0.51816E+00 -0.2855 5 HCO3- 0.57617E-05 -5.2394 0.48165E-05 -5.3173 0.83595E+00 -0.0778 6 HS- 0.14877E-03 -3.8275 0.12420E-03 -3.9059 0.83484E+00 -0.0784 7 Al+++ 0.99577E-29 -29.0018 0.22889E-29 -29.6404 0.22986E+00 -0.6385 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13731E-06 -6.8623 0.70620E-07 -7.1511 0.51433E+00 -0.2888 10 Mg++ 0.21481E-10 -10.6679 0.10997E-10 -10.9587 0.51196E+00 -0.2908 11 Fe++ 0.59206E-13 -13.2276 0.30344E-13 -13.5179 0.51252E+00 -0.2903 12 K+ 0.15776E-03 -3.8020 0.13191E-03 -3.8797 0.83615E+00 -0.0777 13 Na+ 0.20020E-01 -1.6985 0.16708E-01 -1.7771 0.83457E+00 -0.0785 14 Mn++ 0.18997E-10 -10.7213 0.97444E-11 -11.0112 0.51295E+00 -0.2899 15 F- 0.11437E-05 -5.9417 0.95269E-06 -6.0211 0.83299E+00 -0.0794 16 HPO4-- 0.44754E-07 -7.3492 0.23193E-07 -7.6346 0.51823E+00 -0.2855 18 HSiO3- 0.10417E-01 -1.9823 0.86951E-02 -2.0607 0.83472E+00 -0.0785 19 Ca(HSiO3)+ 0.16721E-07 -7.7767 0.13984E-07 -7.8544 0.83633E+00 -0.0776 20 Mg(HSiO3)+ 0.32406E-11 -11.4894 0.27102E-11 -11.5670 0.83633E+00 -0.0776 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66654E-16 -16.1762 0.55744E-16 -16.2538 0.83633E+00 -0.0776 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52798E-05 -5.2774 0.43992E-05 -5.3566 0.83320E+00 -0.0792 26 CH4,aq 0.29953E-03 -3.5236 0.29851E-03 -3.5250 0.99656E+00 -0.0015 27 C2H6,aq 0.13197E-11 -11.8795 0.13152E-11 -11.8810 0.99656E+00 -0.0015 28 C3H8,aq 0.13424E-18 -18.8721 0.13378E-18 -18.8736 0.99656E+00 -0.0015 30 ethanol,aq 0.48438E-19 -19.3148 0.48272E-19 -19.3163 0.99656E+00 -0.0015 31 CO,aq 0.22381E-15 -15.6501 0.22381E-15 -15.6501 0.10000E+01 0.0000 32 CO2,aq 0.77185E-09 -9.1125 0.76920E-09 -9.1140 0.99656E+00 -0.0015 33 CO3-2 0.10887E-04 -4.9631 0.56289E-05 -5.2496 0.51705E+00 -0.2865 34 CaCO3,aq 0.49844E-08 -8.3024 0.49844E-08 -8.3024 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10382E-10 -10.9837 0.86825E-11 -11.0614 0.83633E+00 -0.0776 36 CaCl+ 0.34223E-10 -10.4657 0.28622E-10 -10.5433 0.83633E+00 -0.0776 37 CaCl2,aq 0.17030E-14 -14.7688 0.17030E-14 -14.7688 0.10000E+01 0.0000 38 CaF+ 0.11745E-11 -11.9301 0.98228E-12 -12.0078 0.83633E+00 -0.0776 39 CaOH+ 0.80520E-07 -7.0941 0.67341E-07 -7.1717 0.83633E+00 -0.0776 40 CaSO4,aq 0.43655E-16 -16.3600 0.43655E-16 -16.3600 0.10000E+01 0.0000 41 HCl,aq 0.34300E-14 -14.4647 0.34300E-14 -14.4647 0.10000E+01 0.0000 45 HF,aq 0.48744E-12 -12.3121 0.48744E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18783E-18 -18.7262 0.15678E-18 -18.8047 0.83472E+00 -0.0785 48 FeCl+ 0.14383E-16 -16.8422 0.12029E-16 -16.9198 0.83633E+00 -0.0776 51 FeF+ 0.17664E-17 -17.7529 0.14773E-17 -17.8305 0.83633E+00 -0.0776 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15802E-10 -10.8013 0.13216E-10 -10.8789 0.83633E+00 -0.0776 55 HFeO2- 0.35409E-07 -7.4509 0.29556E-07 -7.5294 0.83472E+00 -0.0785 56 FeO+ 0.11075E-16 -16.9557 0.92622E-17 -17.0333 0.83633E+00 -0.0776 58 FeO2- 0.40646E-09 -9.3910 0.33928E-09 -9.4694 0.83472E+00 -0.0785 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11622E-04 -4.9347 0.11582E-04 -4.9362 0.99656E+00 -0.0015 61 KCl,aq 0.59876E-09 -9.2227 0.59876E-09 -9.2227 0.10000E+01 0.0000 63 KOH,aq 0.75374E-06 -6.1228 0.75374E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.47738E-14 -14.3211 0.39848E-14 -14.3996 0.83472E+00 -0.0785 65 MgCO3,aq 0.19456E-12 -12.7109 0.19456E-12 -12.7109 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16520E-14 -14.7820 0.13816E-14 -14.8596 0.83633E+00 -0.0776 67 MgCl+ 0.48303E-14 -14.3160 0.40398E-14 -14.3936 0.83633E+00 -0.0776 68 MgF+ 0.67753E-15 -15.1691 0.56664E-15 -15.2467 0.83633E+00 -0.0776 69 MgOH+ 0.69385E-10 -10.1587 0.58029E-10 -10.2364 0.83633E+00 -0.0776 71 MnF+ 0.18697E-15 -15.7282 0.15637E-15 -15.8059 0.83633E+00 -0.0776 72 MnO,aq 0.18065E-08 -8.7432 0.18065E-08 -8.7432 0.10000E+01 0.0000 73 MnOH+ 0.47140E-09 -9.3266 0.39425E-09 -9.4042 0.83633E+00 -0.0776 74 MnO2-2 0.20758E-10 -10.6828 0.10733E-10 -10.9693 0.51705E+00 -0.2865 75 HMnO2- 0.21054E-09 -9.6767 0.17574E-09 -9.7551 0.83472E+00 -0.0785 78 MnCl+ 0.17969E-13 -13.7455 0.15028E-13 -13.8231 0.83633E+00 -0.0776 80 NaCl,aq 0.13867E-05 -5.8580 0.13867E-05 -5.8580 0.10000E+01 0.0000 81 NaF,aq 0.37265E-08 -8.4287 0.37265E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96045E-04 -4.0175 0.96045E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92780E-02 -2.0325 0.77305E-02 -2.1118 0.83320E+00 -0.0792 89 HPO3-2 0.16191E-14 -14.7907 0.83715E-15 -15.0772 0.51705E+00 -0.2865 91 H2PO3- 0.15031E-18 -18.8230 0.12547E-18 -18.9015 0.83472E+00 -0.0785 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38272E-10 -10.4171 0.31977E-10 -10.4952 0.83552E+00 -0.0780 94 PO4-3 0.10484E-08 -8.9795 0.25319E-09 -9.5966 0.24150E+00 -0.6171 98 HP2O7-3 0.93094E-18 -18.0311 0.21420E-18 -18.6692 0.23009E+00 -0.6381 99 P2O7-4 0.89582E-17 -17.0478 0.68468E-18 -18.1645 0.76430E-01 -1.1167 100 H2S,aq 0.28789E-07 -7.5408 0.28690E-07 -7.5423 0.99656E+00 -0.0015 101 S2-2 0.57077E-13 -13.2435 0.29512E-13 -13.5300 0.51705E+00 -0.2865 107 SO3-2 0.55856E-17 -17.2529 0.29301E-17 -17.5331 0.52458E+00 -0.2802 108 HSO3- 0.16427E-19 -19.7845 0.13712E-19 -19.8629 0.83472E+00 -0.0785 109 HSO4- 0.16749E-18 -18.7760 0.14022E-18 -18.8532 0.83715E+00 -0.0772 Charge balance for all species = -.1746E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8899646E-10 -.2217625E-01 -.2231322E+02 0.0000 2 H2O 0.1000000E+01 0.5550518E+02 0.9981929E+06 0.0000 3 Cl- 0.3000305E-03 0.3014178E-03 0.1066747E+02 6.5252 4 SO4-- 0.3756961E-11 -.3024401E-03 -.2900205E+02 8.5422 5 HCO3- 0.5761703E-05 0.3161886E-03 0.1925919E+02 4.8092 6 HS- 0.1487740E-03 0.4512430E-03 0.1489739E+02 6.2206 7 Al+++ 0.9957706E-29 0.5279970E-05 0.1422122E+00 0.7390 8 H4SiO4 0.6959754E-03 0.1346234E-01 0.1291674E+04 -3.1574 9 Ca++ 0.1373062E-06 0.2395772E-06 0.9584973E-02 13.1018 10 Mg++ 0.2148121E-10 0.9430908E-10 0.2288831E-05 9.2942 11 Fe++ 0.5920589E-13 0.3604525E-07 0.2009497E-02 6.7350 12 K+ 0.1577624E-03 0.1585167E-03 0.6187476E+01 6.2467 13 Na+ 0.2001950E-01 0.2246654E-01 0.5155976E+03 8.3494 14 Mn++ 0.1899676E-10 0.2528242E-08 0.1386535E-03 9.2417 15 F- 0.1143697E-05 0.1147425E-05 0.2176063E-01 4.1054 16 HPO4-- 0.4475415E-07 0.4584080E-07 0.4392056E-02 12.6183 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279233E+02 -.1100766E-01 -.8278133E+02 0.0000000E+00 2 H2O -.7167160E+01 0.2755118E+02 -.3471834E+02 0.0000000E+00 3 Cl- 0.1496152E-03 0.1496152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386020E+00 -.1501226E-03 0.1387521E+00 0.0000000E+00 5 HCO3- 0.1569470E-03 0.1569470E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1385282E+00 0.2239841E-03 -.1387521E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2620826E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6682320E-02 0.5205722E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1189193E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4681233E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1789183E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7868318E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1115175E-01 0.6265225E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254947E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8960000E-06 0.5695489E-06 0.3264511E-06 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2275406E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.9187E-14 Mass of aqueous solution: 0.497241E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0019900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5550 -0.256 282.0 2.450 5.163 73.28 grossular 0.1344 -0.872 60.54 1.782 1.108 16.84 apatite-OH 0.9862E-02 -2.006 4.954 0.695 0.9069E-01 1.574 apatite-F 0.3265E-06 -6.486 0.1646E-03 -3.783 0.3014E-05 0.5143E-04 clinochlore 0.7102 -0.149 394.7 2.596 7.227 150.1 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2589 -0.587 56.07 1.749 1.026 17.13 hedenbergite 0.6714E-01 -1.173 16.66 1.222 0.3050 4.562 microcline 0.9310 -0.031 259.1 2.414 4.744 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2611 -0.583 281.4 2.449 5.152 97.21 tr.625ac.25prg.125 0.4372E-01 -1.359 37.37 1.573 0.6842 12.03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.338511 g Volume = 2210.783359 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0019900 moles log = -2.7011 Original solution: 1000.0103000 g Original solution / Rock added: 502517.74 (Water/Rock Ratio), log = 5.7012 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.4760 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.6945E+00 0.9814 0.1006E+01 0.1025E+01 CO2,gas 0.5562E-07 1.0025 0.8230E-07 0.8209E-07 CH4,gas 0.2952E+00 1.0084 0.4394E+00 0.4357E+00 H2,gas 0.1029E-01 1.0008 0.1521E-01 0.1519E-01 H2S,gas 0.5374E-06 0.9943 0.7887E-06 0.7932E-06 S2,gas 0.6841E-28 1.0000 0.1010E-27 0.1010E-27 CO,gas 0.2260E-12 1.0000 0.3335E-12 0.3335E-12 SO3,gas 0.2786E-47 1.0000 0.4112E-47 0.4112E-47 SO2,gas 0.1648E-26 1.0000 0.2432E-26 0.2432E-26 HF,gas 0.8109E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.4101E-17 1.0000 0.6052E-17 0.6052E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.18198E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.44 -8.78 -2.928 0.14998E+05 -7.085 3 CH4,gas 4.54 2.49 -2.06 -0.514 0.35108E+04 -0.357 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.03 -7.80 -3.901 0.13322E+05 -6.103 6 S2,gas -7.34 -37.03 -29.69 -4.568 0.50703E+05 -27.996 7 CO,gas 3.21 -10.96 -14.18 -4.362 0.24205E+05 -12.477 8 SO3,gas 17.12 -31.96 -49.08 -12.271 0.83811E+05 -47.386 9 SO2,gas 0.83 -27.48 -28.31 -7.550 0.48344E+05 -26.614 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.73 -18.92 -9.459 0.32300E+05 -17.218 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80706E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.34 -3.31 -1.103 0.56490E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.34 -3.15 -1.051 0.53848E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65548E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.48 -3.38 -0.964 0.57639E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.48 -2.93 -0.838 0.50061E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82240E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.81 -4.57 -1.074 0.77955E+04 146 pyrrhotite -4.26 -7.30 -3.04 -1.012 0.51856E+04 147 pyrrhotiteFe0.875 -6.02 -8.70 -2.68 -0.985 0.45728E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22443E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23246E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47124E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.30 -2.89 -0.962 0.49284E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.79 -3.81 -1.271 0.65102E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0000400 MOLES Current total amount of reactant added: 0.0019900 MOLES New total amount of reactant added: 0.0020300 MOLES Mixing fraction reached given limit of 0.2000E-02 TOTMIX = 0.2030E-02 Execution stopped.