File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.82792E+02 0.89350E-10 0.8396 0.00000000E+00 H2O 2 0. -0.71655E+01 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.16142E-03 0.32366E-03 0.8345 0.00000000E+00 SO4-- 4 -2. 0.13861E+00 0.62111E-11 0.5175 0.00000000E+00 HCO3- 5 -1. 0.30155E-03 0.11036E-04 0.8357 0.00000000E+00 HS- 6 -1. -0.13849E+00 0.24665E-03 0.8346 0.00000000E+00 Al+++ 7 3. 0.16304E+02 0.10095E-28 0.2292 0.00000000E+00 H4SiO4 8 0. 0.52064E+02 0.69597E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.57507E+01 0.13849E-06 0.5137 0.00000000E+00 Mg++ 10 2. 0.39683E+01 0.21666E-10 0.5113 0.00000000E+00 Fe++ 11 2. 0.35650E+01 0.59716E-13 0.5119 0.00000000E+00 K+ 12 1. 0.10616E+01 0.15839E-03 0.8359 0.00000000E+00 Na+ 13 1. 0.62764E+01 0.20099E-01 0.8343 0.00000000E+00 Mn++ 14 2. 0.86693E-01 0.19164E-10 0.5123 0.00000000E+00 F- 15 -1. 0.16960E-05 0.11398E-05 0.8327 0.00000000E+00 HPO4-- 16 -2. 0.29588E-01 0.44478E-07 0.5176 0.00000000E+00 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.1614E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E-01 TEMP = 100.0000 SINC = 0.4000E-03 TEMPC = 0.0000 TOTMIX = 0.399000E-02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 2000.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.6260E+01 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.5556E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.1345E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.9861E-02 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.1128E-05 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.3220E+01 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.2607E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.7100E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.2056E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.1734E-01 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.2551E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.6615E-01 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.9311E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.4497E-01 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0039900 moles log = -2.3990 Original solution: 1000.0103000 g Original solution / Rock added: 250629.15 (Water/Rock Ratio), log = 5.3990 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0039900 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4964E+00 Moles total = -.7166E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1110003E-01 Osmotic coef. = 0.8978 True ionic strength = .2027885E-01 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.1614E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89350E-10 -10.0489 0.75015E-10 -10.1249 0.83957E+00 -0.0759 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.32366E-03 -3.4899 0.27009E-03 -3.5685 0.83447E+00 -0.0786 4 SO4-- 0.62111E-11 -11.2068 0.32145E-11 -11.4929 0.51755E+00 -0.2860 5 HCO3- 0.11036E-04 -4.9572 0.92224E-05 -5.0352 0.83570E+00 -0.0780 6 HS- 0.24665E-03 -3.6079 0.20585E-03 -3.6865 0.83459E+00 -0.0785 7 Al+++ 0.10095E-28 -28.9959 0.23143E-29 -29.6356 0.22925E+00 -0.6397 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13849E-06 -6.8586 0.71142E-07 -7.1479 0.51371E+00 -0.2893 10 Mg++ 0.21666E-10 -10.6642 0.11079E-10 -10.9555 0.51134E+00 -0.2913 11 Fe++ 0.59716E-13 -13.2239 0.30569E-13 -13.5147 0.51190E+00 -0.2908 12 K+ 0.15839E-03 -3.8003 0.13240E-03 -3.8781 0.83590E+00 -0.0778 13 Na+ 0.20099E-01 -1.6968 0.16769E-01 -1.7755 0.83431E+00 -0.0787 14 Mn++ 0.19164E-10 -10.7175 0.98183E-11 -11.0080 0.51233E+00 -0.2904 15 F- 0.11398E-05 -5.9432 0.94918E-06 -6.0226 0.83273E+00 -0.0795 16 HPO4-- 0.44478E-07 -7.3519 0.23023E-07 -7.6378 0.51762E+00 -0.2860 18 HSiO3- 0.10382E-01 -1.9837 0.86631E-02 -2.0623 0.83447E+00 -0.0786 19 Ca(HSiO3)+ 0.16788E-07 -7.7750 0.14036E-07 -7.8528 0.83608E+00 -0.0778 20 Mg(HSiO3)+ 0.32535E-11 -11.4876 0.27202E-11 -11.5654 0.83608E+00 -0.0778 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66920E-16 -16.1744 0.55950E-16 -16.2522 0.83608E+00 -0.0778 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52621E-05 -5.2788 0.43830E-05 -5.3582 0.83294E+00 -0.0794 26 CH4,aq 0.57562E-03 -3.2399 0.57367E-03 -3.2413 0.99661E+00 -0.0015 27 C2H6,aq 0.48739E-11 -11.3121 0.48574E-11 -11.3136 0.99661E+00 -0.0015 28 C3H8,aq 0.95279E-18 -18.0210 0.94956E-18 -18.0225 0.99661E+00 -0.0015 30 ethanol,aq 0.17889E-18 -18.7474 0.17829E-18 -18.7489 0.99661E+00 -0.0015 31 CO,aq 0.43012E-15 -15.3664 0.43012E-15 -15.3664 0.10000E+01 0.0000 32 CO2,aq 0.14833E-08 -8.8288 0.14783E-08 -8.8302 0.99661E+00 -0.0015 33 CO3-2 0.20793E-04 -4.6821 0.10738E-04 -4.9691 0.51644E+00 -0.2870 34 CaCO3,aq 0.95791E-08 -8.0187 0.95791E-08 -8.0187 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.20031E-10 -10.6983 0.16748E-10 -10.7760 0.83608E+00 -0.0778 36 CaCl+ 0.37191E-10 -10.4296 0.31095E-10 -10.5073 0.83608E+00 -0.0778 37 CaCl2,aq 0.19953E-14 -14.7000 0.19953E-14 -14.7000 0.10000E+01 0.0000 38 CaF+ 0.11792E-11 -11.9284 0.98589E-12 -12.0062 0.83608E+00 -0.0778 39 CaOH+ 0.80840E-07 -7.0924 0.67589E-07 -7.1701 0.83608E+00 -0.0778 40 CaSO4,aq 0.72619E-16 -16.1390 0.72619E-16 -16.1390 0.10000E+01 0.0000 41 HCl,aq 0.37127E-14 -14.4303 0.37127E-14 -14.4303 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18719E-18 -18.7277 0.15621E-18 -18.8063 0.83447E+00 -0.0786 48 FeCl+ 0.15630E-16 -16.8060 0.13068E-16 -16.8838 0.83608E+00 -0.0778 51 FeF+ 0.17734E-17 -17.7512 0.14827E-17 -17.8289 0.83608E+00 -0.0778 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15865E-10 -10.7996 0.13264E-10 -10.8773 0.83608E+00 -0.0778 55 HFeO2- 0.35289E-07 -7.4524 0.29448E-07 -7.5310 0.83447E+00 -0.0786 56 FeO+ 0.11119E-16 -16.9539 0.92964E-17 -17.0317 0.83608E+00 -0.0778 58 FeO2- 0.40509E-09 -9.3924 0.33804E-09 -9.4710 0.83447E+00 -0.0786 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11622E-04 -4.9347 0.11582E-04 -4.9362 0.99661E+00 -0.0015 61 KCl,aq 0.64810E-09 -9.1884 0.64810E-09 -9.1884 0.10000E+01 0.0000 63 KOH,aq 0.75372E-06 -6.1228 0.75372E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.79143E-14 -14.1016 0.66042E-14 -14.1802 0.83447E+00 -0.0786 65 MgCO3,aq 0.37391E-12 -12.4272 0.37391E-12 -12.4272 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.31874E-14 -14.4966 0.26649E-14 -14.5743 0.83608E+00 -0.0778 67 MgCl+ 0.52493E-14 -14.2799 0.43888E-14 -14.3577 0.83608E+00 -0.0778 68 MgF+ 0.68023E-15 -15.1673 0.56872E-15 -15.2451 0.83608E+00 -0.0778 69 MgOH+ 0.69661E-10 -10.1570 0.58242E-10 -10.2348 0.83608E+00 -0.0778 71 MnF+ 0.18775E-15 -15.7264 0.15697E-15 -15.8042 0.83608E+00 -0.0778 72 MnO,aq 0.18069E-08 -8.7431 0.18069E-08 -8.7431 0.10000E+01 0.0000 73 MnOH+ 0.47337E-09 -9.3248 0.39577E-09 -9.4026 0.83608E+00 -0.0778 74 MnO2-2 0.20634E-10 -10.6854 0.10656E-10 -10.9724 0.51644E+00 -0.2870 75 HMnO2- 0.20987E-09 -9.6781 0.17513E-09 -9.7566 0.83447E+00 -0.0786 78 MnCl+ 0.19531E-13 -13.7093 0.16330E-13 -13.7870 0.83608E+00 -0.0778 80 NaCl,aq 0.15009E-05 -5.8236 0.15009E-05 -5.8236 0.10000E+01 0.0000 81 NaF,aq 0.37264E-08 -8.4287 0.37264E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96043E-04 -4.0175 0.96043E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92468E-02 -2.0340 0.77020E-02 -2.1134 0.83294E+00 -0.0794 89 HPO3-2 0.16091E-14 -14.7934 0.83102E-15 -15.0804 0.51644E+00 -0.2870 91 H2PO3- 0.14981E-18 -18.8245 0.12501E-18 -18.9031 0.83447E+00 -0.0786 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38143E-10 -10.4186 0.31860E-10 -10.4968 0.83526E+00 -0.0782 94 PO4-3 0.10395E-08 -8.9832 0.25041E-09 -9.6014 0.24090E+00 -0.6182 98 HP2O7-3 0.92320E-18 -18.0347 0.21185E-18 -18.6740 0.22948E+00 -0.6393 99 P2O7-4 0.88686E-17 -17.0521 0.67468E-18 -18.1709 0.76076E-01 -1.1188 100 H2S,aq 0.47887E-07 -7.3198 0.47725E-07 -7.3213 0.99661E+00 -0.0015 101 S2-2 0.15697E-12 -12.8042 0.81064E-13 -13.0912 0.51644E+00 -0.2870 107 SO3-2 0.92337E-17 -17.0346 0.48383E-17 -17.3153 0.52399E+00 -0.2807 108 HSO3- 0.27233E-19 -19.5649 0.22725E-19 -19.6435 0.83447E+00 -0.0786 109 HSO4- 0.27768E-18 -18.5565 0.23239E-18 -18.6338 0.83690E+00 -0.0773 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8934971E-10 -.2211969E-01 -.2225613E+02 0.0000 2 H2O 0.1000000E+01 0.5550546E+02 0.9981899E+06 0.0000 3 Cl- 0.3236648E-03 0.3251664E-03 0.1150786E+02 6.5564 4 SO4-- 0.6211058E-11 -.5785236E-03 -.5547622E+02 8.7568 5 HCO3- 0.1103558E-04 0.6074581E-03 0.3700024E+02 5.0897 6 HS- 0.2466474E-03 0.8252189E-03 0.2724367E+02 6.4384 7 Al+++ 0.1009531E-28 0.5262227E-05 0.1417332E+00 0.7390 8 H4SiO4 0.6959715E-03 0.1342720E-01 0.1288292E+04 -3.1574 9 Ca++ 0.1384859E-06 0.2457512E-06 0.9831904E-02 13.1018 10 Mg++ 0.2166612E-10 0.9496505E-10 0.2304732E-05 9.2942 11 Fe++ 0.5971553E-13 0.3592446E-07 0.2002747E-02 6.7350 12 K+ 0.1583886E-03 0.1591430E-03 0.6211872E+01 6.2467 13 Na+ 0.2009911E-01 0.2254622E-01 0.5174221E+03 8.3494 14 Mn++ 0.1916391E-10 0.2529931E-08 0.1387451E-03 9.2417 15 F- 0.1139846E-05 0.1143574E-05 0.2168744E-01 4.1022 16 HPO4-- 0.4447818E-07 0.4555580E-07 0.4364714E-02 12.6119 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279212E+02 -.1098039E-01 -.8278114E+02 0.0000000E+00 2 H2O -.7165522E+01 0.2755335E+02 -.3471887E+02 0.0000000E+00 3 Cl- 0.1614152E-03 0.1614152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386116E+00 -.2871837E-03 0.1388988E+00 0.0000000E+00 5 HCO3- 0.3015470E-03 0.3015470E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1384891E+00 0.4096452E-03 -.1388988E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2612211E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6665369E-02 0.5205724E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1219928E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4714140E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1783319E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7899985E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1119212E-01 0.6265185E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1255878E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1696000E-05 0.5676794E-06 0.1128321E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2261426E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.4038E-14 Mass of aqueous solution: 0.497282E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0039900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5556 -0.255 282.3 2.451 5.169 73.35 grossular 0.1345 -0.871 60.60 1.782 1.109 16.86 apatite-OH 0.9861E-02 -2.006 4.954 0.695 0.9069E-01 1.574 apatite-F 0.1128E-05 -5.948 0.5690E-03 -3.245 0.1042E-04 0.1778E-03 clinochlore 0.7100 -0.149 394.7 2.596 7.225 150.1 daphnite 0.2056 -0.687 146.7 2.166 2.685 44.44 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2551 -0.593 55.24 1.742 1.011 16.88 hedenbergite 0.6615E-01 -1.179 16.41 1.215 0.3005 4.495 microcline 0.9311 -0.031 259.2 2.414 4.745 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2607 -0.584 281.1 2.449 5.146 97.09 tr.625ac.25prg.125 0.4497E-01 -1.347 38.44 1.585 0.7037 12.37 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.339142 g Volume = 2210.788873 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0039900 moles log = -2.3990 Original solution: 1000.0103000 g Original solution / Rock added: 250629.15 (Water/Rock Ratio), log = 5.3990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.8820 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.5460E+00 0.9790 0.1006E+01 0.1028E+01 CO2,gas 0.8405E-07 0.9998 0.1582E-06 0.1582E-06 CH4,gas 0.4459E+00 1.0061 0.8444E+00 0.8392E+00 H2,gas 0.8072E-02 1.0010 0.1521E-01 0.1519E-01 H2S,gas 0.7022E-06 0.9927 0.1312E-05 0.1322E-05 S2,gas 0.1485E-27 1.0000 0.2794E-27 0.2794E-27 CO,gas 0.3406E-12 1.0000 0.6410E-12 0.6410E-12 SO3,gas 0.3634E-47 1.0000 0.6840E-47 0.6840E-47 SO2,gas 0.2150E-26 1.0000 0.4046E-26 0.4046E-26 HF,gas 0.6359E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.3481E-17 1.0000 0.6551E-17 0.6551E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.16 -8.50 -2.833 0.14513E+05 -6.801 3 CH4,gas 4.54 2.77 -1.77 -0.443 0.30264E+04 -0.073 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.81 -7.58 -3.791 0.12944E+05 -5.882 6 S2,gas -7.34 -36.59 -29.25 -4.500 0.49948E+05 -27.554 7 CO,gas 3.21 -10.68 -13.89 -4.275 0.23720E+05 -12.193 8 SO3,gas 17.12 -31.74 -48.86 -12.216 0.83434E+05 -47.165 9 SO2,gas 0.83 -27.26 -28.09 -7.491 0.47966E+05 -26.393 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.69 -18.88 -9.441 0.32242E+05 -17.184 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80702E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93626E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.06 -3.02 -1.008 0.51646E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.06 -2.87 -0.957 0.49004E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65546E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.19 -3.09 -0.883 0.52795E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.19 -2.65 -0.757 0.45217E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82238E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.37 -4.12 -0.970 0.70408E+04 146 pyrrhotite -4.26 -7.08 -2.82 -0.939 0.48082E+04 147 pyrrhotiteFe0.875 -6.02 -8.47 -2.46 -0.904 0.41955E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22442E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.92 -4.94 -1.647 0.84382E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23245E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47121E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.08 -2.67 -0.888 0.45511E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.57 -3.59 -1.197 0.61327E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0039900 MOLES New total amount of reactant added: 0.0043900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8659E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0043900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4964E+00 Moles total = -.7165E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1106648E-01 Osmotic coef. = 0.9006 True ionic strength = .2029688E-01 Chg. balance for total moles = -.8659E-10 Max. difference allowed = 0.1638E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89420E-10 -10.0486 0.75070E-10 -10.1245 0.83952E+00 -0.0760 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.32839E-03 -3.4836 0.27401E-03 -3.5622 0.83442E+00 -0.0786 4 SO4-- 0.67002E-11 -11.1739 0.34669E-11 -11.4601 0.51743E+00 -0.2861 5 HCO3- 0.12086E-04 -4.9177 0.10100E-04 -4.9957 0.83565E+00 -0.0780 6 HS- 0.26622E-03 -3.5748 0.22217E-03 -3.6533 0.83454E+00 -0.0786 7 Al+++ 0.10123E-28 -28.9947 0.23194E-29 -29.6346 0.22912E+00 -0.6399 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13872E-06 -6.8579 0.71246E-07 -7.1472 0.51359E+00 -0.2894 10 Mg++ 0.21703E-10 -10.6635 0.11095E-10 -10.9549 0.51121E+00 -0.2914 11 Fe++ 0.59818E-13 -13.2232 0.30614E-13 -13.5141 0.51178E+00 -0.2909 12 K+ 0.15851E-03 -3.7999 0.13249E-03 -3.8778 0.83585E+00 -0.0779 13 Na+ 0.20115E-01 -1.6965 0.16781E-01 -1.7752 0.83426E+00 -0.0787 14 Mn++ 0.19197E-10 -10.7168 0.98331E-11 -11.0073 0.51221E+00 -0.2906 15 F- 0.11391E-05 -5.9434 0.94849E-06 -6.0230 0.83268E+00 -0.0795 16 HPO4-- 0.44423E-07 -7.3524 0.22989E-07 -7.6385 0.51750E+00 -0.2861 18 HSiO3- 0.10375E-01 -1.9840 0.86568E-02 -2.0626 0.83442E+00 -0.0786 19 Ca(HSiO3)+ 0.16801E-07 -7.7747 0.14046E-07 -7.8524 0.83603E+00 -0.0778 20 Mg(HSiO3)+ 0.32561E-11 -11.4873 0.27222E-11 -11.5651 0.83603E+00 -0.0778 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.66973E-16 -16.1741 0.55991E-16 -16.2519 0.83603E+00 -0.0778 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52585E-05 -5.2791 0.43798E-05 -5.3585 0.83289E+00 -0.0794 26 CH4,aq 0.63085E-03 -3.2001 0.62872E-03 -3.2015 0.99662E+00 -0.0015 27 C2H6,aq 0.58542E-11 -11.2325 0.58344E-11 -11.2340 0.99662E+00 -0.0015 28 C3H8,aq 0.12542E-17 -17.9016 0.12500E-17 -17.9031 0.99662E+00 -0.0015 30 ethanol,aq 0.21487E-18 -18.6678 0.21414E-18 -18.6693 0.99662E+00 -0.0015 31 CO,aq 0.47140E-15 -15.3266 0.47140E-15 -15.3266 0.10000E+01 0.0000 32 CO2,aq 0.16256E-08 -8.7890 0.16201E-08 -8.7905 0.99662E+00 -0.0015 33 CO3-2 0.22760E-04 -4.6428 0.11752E-04 -4.9299 0.51632E+00 -0.2871 34 CaCO3,aq 0.10498E-07 -7.9789 0.10498E-07 -7.9789 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.21971E-10 -10.6582 0.18368E-10 -10.7359 0.83603E+00 -0.0778 36 CaCl+ 0.37790E-10 -10.4226 0.31594E-10 -10.5004 0.83603E+00 -0.0778 37 CaCl2,aq 0.20567E-14 -14.6868 0.20567E-14 -14.6868 0.10000E+01 0.0000 38 CaF+ 0.11801E-11 -11.9281 0.98662E-12 -12.0059 0.83603E+00 -0.0778 39 CaOH+ 0.80904E-07 -7.0920 0.67639E-07 -7.1698 0.83603E+00 -0.0778 40 CaSO4,aq 0.78434E-16 -16.1055 0.78434E-16 -16.1055 0.10000E+01 0.0000 41 HCl,aq 0.37694E-14 -14.4237 0.37694E-14 -14.4237 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18707E-18 -18.7280 0.15609E-18 -18.8066 0.83442E+00 -0.0786 48 FeCl+ 0.15882E-16 -16.7991 0.13278E-16 -16.8769 0.83603E+00 -0.0778 51 FeF+ 0.17748E-17 -17.7508 0.14838E-17 -17.8286 0.83603E+00 -0.0778 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15878E-10 -10.7992 0.13274E-10 -10.8770 0.83603E+00 -0.0778 55 HFeO2- 0.35265E-07 -7.4527 0.29426E-07 -7.5313 0.83442E+00 -0.0786 56 FeO+ 0.11128E-16 -16.9536 0.93032E-17 -17.0314 0.83603E+00 -0.0778 58 FeO2- 0.40482E-09 -9.3927 0.33779E-09 -9.4714 0.83442E+00 -0.0786 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11622E-04 -4.9347 0.11582E-04 -4.9362 0.99662E+00 -0.0015 61 KCl,aq 0.65800E-09 -9.1818 0.65800E-09 -9.1818 0.10000E+01 0.0000 63 KOH,aq 0.75372E-06 -6.1228 0.75372E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.85423E-14 -14.0684 0.71278E-14 -14.1470 0.83442E+00 -0.0786 65 MgCO3,aq 0.40979E-12 -12.3874 0.40979E-12 -12.3874 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.34961E-14 -14.4564 0.29228E-14 -14.5342 0.83603E+00 -0.0778 67 MgCl+ 0.53338E-14 -14.2730 0.44592E-14 -14.3507 0.83603E+00 -0.0778 68 MgF+ 0.68077E-15 -15.1670 0.56914E-15 -15.2448 0.83603E+00 -0.0778 69 MgOH+ 0.69717E-10 -10.1567 0.58285E-10 -10.2344 0.83603E+00 -0.0778 71 MnF+ 0.18790E-15 -15.7261 0.15709E-15 -15.8038 0.83603E+00 -0.0778 72 MnO,aq 0.18069E-08 -8.7431 0.18069E-08 -8.7431 0.10000E+01 0.0000 73 MnOH+ 0.47376E-09 -9.3244 0.39608E-09 -9.4022 0.83603E+00 -0.0778 74 MnO2-2 0.20609E-10 -10.6859 0.10641E-10 -10.9730 0.51632E+00 -0.2871 75 HMnO2- 0.20974E-09 -9.6783 0.17501E-09 -9.7569 0.83442E+00 -0.0786 78 MnCl+ 0.19846E-13 -13.7023 0.16592E-13 -13.7801 0.83603E+00 -0.0778 80 NaCl,aq 0.15239E-05 -5.8170 0.15239E-05 -5.8170 0.10000E+01 0.0000 81 NaF,aq 0.37264E-08 -8.4287 0.37264E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96043E-04 -4.0175 0.96043E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92405E-02 -2.0343 0.76964E-02 -2.1137 0.83289E+00 -0.0794 89 HPO3-2 0.16071E-14 -14.7939 0.82980E-15 -15.0810 0.51632E+00 -0.2871 91 H2PO3- 0.14970E-18 -18.8248 0.12492E-18 -18.9034 0.83442E+00 -0.0786 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38118E-10 -10.4189 0.31836E-10 -10.4971 0.83521E+00 -0.0782 94 PO4-3 0.10377E-08 -8.9839 0.24986E-09 -9.6023 0.24078E+00 -0.6184 98 HP2O7-3 0.92166E-18 -18.0354 0.21139E-18 -18.6749 0.22936E+00 -0.6395 99 P2O7-4 0.88508E-17 -17.0530 0.67271E-18 -18.1722 0.76005E-01 -1.1192 100 H2S,aq 0.51721E-07 -7.2863 0.51547E-07 -7.2878 0.99662E+00 -0.0015 101 S2-2 0.18289E-12 -12.7378 0.94429E-13 -13.0249 0.51632E+00 -0.2871 107 SO3-2 0.99608E-17 -17.0017 0.52181E-17 -17.2825 0.52387E+00 -0.2808 108 HSO3- 0.29394E-19 -19.5317 0.24527E-19 -19.6104 0.83442E+00 -0.0786 109 HSO4- 0.29971E-18 -18.5233 0.25081E-18 -18.6006 0.83685E+00 -0.0774 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8942042E-10 -.2210841E-01 -.2224475E+02 0.0000 2 H2O 0.1000000E+01 0.5550552E+02 0.9981893E+06 0.0000 3 Cl- 0.3283911E-03 0.3299157E-03 0.1167592E+02 6.5623 4 SO4-- 0.6700181E-11 -.6337532E-03 -.6077224E+02 8.7890 5 HCO3- 0.1208641E-04 0.6657068E-03 0.4054810E+02 5.1289 6 HS- 0.2662203E-03 0.9000252E-03 0.2971327E+02 6.4712 7 Al+++ 0.1012301E-28 0.5258692E-05 0.1416378E+00 0.7390 8 H4SiO4 0.6959707E-03 0.1342020E-01 0.1287618E+04 -3.1574 9 Ca++ 0.1387227E-06 0.2469872E-06 0.9881338E-02 13.1018 10 Mg++ 0.2170323E-10 0.9509516E-10 0.2307886E-05 9.2942 11 Fe++ 0.5981782E-13 0.3590039E-07 0.2001402E-02 6.7350 12 K+ 0.1585140E-03 0.1592684E-03 0.6216755E+01 6.2467 13 Na+ 0.2011504E-01 0.2256217E-01 0.5177872E+03 8.3494 14 Mn++ 0.1919746E-10 0.2530270E-08 0.1387634E-03 9.2418 15 F- 0.1139079E-05 0.1142807E-05 0.2167285E-01 4.1016 16 HPO4-- 0.4442327E-07 0.4549910E-07 0.4359275E-02 12.6106 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279207E+02 -.1097495E-01 -.8278110E+02 0.0000000E+00 2 H2O -.7165195E+01 0.2755378E+02 -.3471898E+02 0.0000000E+00 3 Cl- 0.1637752E-03 0.1637752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386135E+00 -.3146047E-03 0.1389281E+00 0.0000000E+00 5 HCO3- 0.3304670E-03 0.3304670E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1384813E+00 0.4467862E-03 -.1389281E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2610494E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6661991E-02 0.5205724E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1226082E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4720668E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1782150E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7906324E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1120020E-01 0.6265177E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1256065E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1856000E-05 0.5673068E-06 0.1288693E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2258644E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.9395E-14 Mass of aqueous solution: 0.497290E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0043900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5557 -0.255 282.4 2.451 5.170 73.37 grossular 0.1346 -0.871 60.61 1.783 1.110 16.87 apatite-OH 0.9861E-02 -2.006 4.954 0.695 0.9069E-01 1.574 apatite-F 0.1289E-05 -5.890 0.6499E-03 -3.187 0.1190E-04 0.2030E-03 clinochlore 0.7100 -0.149 394.6 2.596 7.225 150.1 daphnite 0.2055 -0.687 146.7 2.166 2.685 44.44 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2543 -0.595 55.07 1.741 1.008 16.83 hedenbergite 0.6595E-01 -1.181 16.36 1.214 0.2995 4.482 microcline 0.9311 -0.031 259.2 2.414 4.745 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2607 -0.584 281.0 2.449 5.145 97.07 tr.625ac.25prg.125 0.4522E-01 -1.345 38.65 1.587 0.7076 12.44 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.339268 g Volume = 2210.789976 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0043900 moles log = -2.3575 Original solution: 1000.0103000 g Original solution / Rock added: 227792.78 (Water/Rock Ratio), log = 5.3575 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.9633 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.5236E+00 0.9786 0.1006E+01 0.1028E+01 CO2,gas 0.8835E-07 0.9994 0.1733E-06 0.1734E-06 CH4,gas 0.4687E+00 1.0058 0.9254E+00 0.9201E+00 H2,gas 0.7737E-02 1.0010 0.1521E-01 0.1519E-01 H2S,gas 0.7273E-06 0.9924 0.1417E-05 0.1428E-05 S2,gas 0.1660E-27 1.0000 0.3259E-27 0.3259E-27 CO,gas 0.3578E-12 1.0000 0.7025E-12 0.7025E-12 SO3,gas 0.3763E-47 1.0000 0.7387E-47 0.7387E-47 SO2,gas 0.2226E-26 1.0000 0.4370E-26 0.4370E-26 HF,gas 0.6096E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.3388E-17 1.0000 0.6651E-17 0.6651E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.12 -8.46 -2.820 0.14445E+05 -6.761 3 CH4,gas 4.54 2.81 -1.73 -0.433 0.29584E+04 -0.034 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.78 -7.55 -3.774 0.12887E+05 -5.849 6 S2,gas -7.34 -36.52 -29.19 -4.490 0.49834E+05 -27.487 7 CO,gas 3.21 -10.64 -13.85 -4.262 0.23652E+05 -12.153 8 SO3,gas 17.12 -31.71 -48.83 -12.208 0.83377E+05 -47.132 9 SO2,gas 0.83 -27.23 -28.06 -7.482 0.47909E+05 -26.359 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.69 -18.88 -9.438 0.32230E+05 -17.177 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80701E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93627E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -2.02 -2.98 -0.995 0.50966E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -2.02 -2.83 -0.943 0.48324E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65546E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.15 -3.05 -0.872 0.52115E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.15 -2.61 -0.745 0.44538E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82238E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.30 -4.06 -0.954 0.69265E+04 146 pyrrhotite -4.26 -7.04 -2.78 -0.928 0.47511E+04 147 pyrrhotiteFe0.875 -6.02 -8.44 -2.42 -0.891 0.41383E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22442E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.88 -4.90 -1.634 0.83703E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23244E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47121E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.04 -2.63 -0.877 0.44939E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.54 -3.56 -1.186 0.60756E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0043900 MOLES New total amount of reactant added: 0.0047900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8659E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0047900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4964E+00 Moles total = -.7165E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1103293E-01 Osmotic coef. = 0.9028 True ionic strength = .2031491E-01 Chg. balance for total moles = -.8659E-10 Max. difference allowed = 0.1661E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89491E-10 -10.0482 0.75125E-10 -10.1242 0.83947E+00 -0.0760 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.33312E-03 -3.4774 0.27794E-03 -3.5560 0.83436E+00 -0.0786 4 SO4-- 0.71887E-11 -11.1433 0.37188E-11 -11.4296 0.51731E+00 -0.2863 5 HCO3- 0.13136E-04 -4.8815 0.10976E-04 -4.9595 0.83560E+00 -0.0780 6 HS- 0.28579E-03 -3.5439 0.23849E-03 -3.6225 0.83449E+00 -0.0786 7 Al+++ 0.10151E-28 -28.9935 0.23246E-29 -29.6337 0.22900E+00 -0.6402 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13896E-06 -6.8571 0.71351E-07 -7.1466 0.51347E+00 -0.2895 10 Mg++ 0.21740E-10 -10.6627 0.11111E-10 -10.9542 0.51109E+00 -0.2915 11 Fe++ 0.59920E-13 -13.2224 0.30659E-13 -13.5134 0.51166E+00 -0.2910 12 K+ 0.15864E-03 -3.7996 0.13259E-03 -3.8775 0.83580E+00 -0.0779 13 Na+ 0.20131E-01 -1.6961 0.16793E-01 -1.7749 0.83421E+00 -0.0787 14 Mn++ 0.19231E-10 -10.7160 0.98479E-11 -11.0067 0.51208E+00 -0.2907 15 F- 0.11383E-05 -5.9437 0.94779E-06 -6.0233 0.83263E+00 -0.0796 16 HPO4-- 0.44368E-07 -7.3529 0.22955E-07 -7.6391 0.51738E+00 -0.2862 18 HSiO3- 0.10368E-01 -1.9843 0.86504E-02 -2.0630 0.83436E+00 -0.0786 19 Ca(HSiO3)+ 0.16814E-07 -7.7743 0.14056E-07 -7.8521 0.83598E+00 -0.0778 20 Mg(HSiO3)+ 0.32587E-11 -11.4870 0.27242E-11 -11.5648 0.83598E+00 -0.0778 21 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67026E-16 -16.1738 0.56033E-16 -16.2516 0.83598E+00 -0.0778 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52550E-05 -5.2794 0.43766E-05 -5.3589 0.83284E+00 -0.0794 26 CH4,aq 0.68608E-03 -3.1636 0.68377E-03 -3.1651 0.99663E+00 -0.0015 27 C2H6,aq 0.69242E-11 -11.1596 0.69009E-11 -11.1611 0.99663E+00 -0.0015 28 C3H8,aq 0.16134E-17 -17.7923 0.16080E-17 -17.7937 0.99663E+00 -0.0015 30 ethanol,aq 0.25415E-18 -18.5949 0.25329E-18 -18.5964 0.99663E+00 -0.0015 31 CO,aq 0.51268E-15 -15.2902 0.51268E-15 -15.2902 0.10000E+01 0.0000 32 CO2,aq 0.17680E-08 -8.7525 0.17620E-08 -8.7540 0.99663E+00 -0.0015 33 CO3-2 0.24723E-04 -4.6069 0.12762E-04 -4.8941 0.51620E+00 -0.2872 34 CaCO3,aq 0.11418E-07 -7.9424 0.11418E-07 -7.9424 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.23914E-10 -10.6214 0.19991E-10 -10.6992 0.83598E+00 -0.0778 36 CaCl+ 0.38390E-10 -10.4158 0.32093E-10 -10.4936 0.83598E+00 -0.0778 37 CaCl2,aq 0.21192E-14 -14.6738 0.21192E-14 -14.6738 0.10000E+01 0.0000 38 CaF+ 0.11811E-11 -11.9277 0.98734E-12 -12.0055 0.83598E+00 -0.0778 39 CaOH+ 0.80969E-07 -7.0917 0.67688E-07 -7.1695 0.83598E+00 -0.0778 40 CaSO4,aq 0.84258E-16 -16.0744 0.84258E-16 -16.0744 0.10000E+01 0.0000 41 HCl,aq 0.38262E-14 -14.4172 0.38262E-14 -14.4172 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18694E-18 -18.7283 0.15598E-18 -18.8069 0.83436E+00 -0.0786 48 FeCl+ 0.16134E-16 -16.7923 0.13488E-16 -16.8701 0.83598E+00 -0.0778 51 FeF+ 0.17762E-17 -17.7505 0.14849E-17 -17.8283 0.83598E+00 -0.0778 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15890E-10 -10.7989 0.13284E-10 -10.8767 0.83598E+00 -0.0778 55 HFeO2- 0.35242E-07 -7.4529 0.29404E-07 -7.5316 0.83436E+00 -0.0786 56 FeO+ 0.11137E-16 -16.9532 0.93100E-17 -17.0310 0.83598E+00 -0.0778 58 FeO2- 0.40455E-09 -9.3930 0.33754E-09 -9.4717 0.83436E+00 -0.0786 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11622E-04 -4.9347 0.11582E-04 -4.9362 0.99663E+00 -0.0015 61 KCl,aq 0.66792E-09 -9.1753 0.66792E-09 -9.1753 0.10000E+01 0.0000 63 KOH,aq 0.75372E-06 -6.1228 0.75372E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.91703E-14 -14.0376 0.76514E-14 -14.1163 0.83436E+00 -0.0786 65 MgCO3,aq 0.44568E-12 -12.3510 0.44568E-12 -12.3510 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.38052E-14 -14.4196 0.31811E-14 -14.4974 0.83598E+00 -0.0778 67 MgCl+ 0.54185E-14 -14.2661 0.45297E-14 -14.3439 0.83598E+00 -0.0778 68 MgF+ 0.68131E-15 -15.1667 0.56956E-15 -15.2445 0.83598E+00 -0.0778 69 MgOH+ 0.69772E-10 -10.1563 0.58328E-10 -10.2341 0.83598E+00 -0.0778 71 MnF+ 0.18806E-15 -15.7257 0.15721E-15 -15.8035 0.83598E+00 -0.0778 72 MnO,aq 0.18070E-08 -8.7430 0.18070E-08 -8.7430 0.10000E+01 0.0000 73 MnOH+ 0.47416E-09 -9.3241 0.39639E-09 -9.4019 0.83598E+00 -0.0778 74 MnO2-2 0.20585E-10 -10.6865 0.10626E-10 -10.9736 0.51620E+00 -0.2872 75 HMnO2- 0.20960E-09 -9.6786 0.17488E-09 -9.7572 0.83436E+00 -0.0786 78 MnCl+ 0.20162E-13 -13.6955 0.16855E-13 -13.7733 0.83598E+00 -0.0778 79 MnSO4,aq 0.10573E-19 -19.9758 0.10573E-19 -19.9758 0.10000E+01 0.0000 80 NaCl,aq 0.15469E-05 -5.8106 0.15469E-05 -5.8106 0.10000E+01 0.0000 81 NaF,aq 0.37264E-08 -8.4287 0.37264E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96042E-04 -4.0175 0.96042E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92343E-02 -2.0346 0.76907E-02 -2.1140 0.83284E+00 -0.0794 89 HPO3-2 0.16052E-14 -14.7945 0.82858E-15 -15.0817 0.51620E+00 -0.2872 91 H2PO3- 0.14960E-18 -18.8251 0.12482E-18 -18.9037 0.83436E+00 -0.0786 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38092E-10 -10.4192 0.31813E-10 -10.4974 0.83516E+00 -0.0782 94 PO4-3 0.10359E-08 -8.9847 0.24931E-09 -9.6033 0.24066E+00 -0.6186 98 HP2O7-3 0.92012E-18 -18.0362 0.21092E-18 -18.6759 0.22924E+00 -0.6397 99 P2O7-4 0.88330E-17 -17.0539 0.67073E-18 -18.1734 0.75935E-01 -1.1196 100 H2S,aq 0.55561E-07 -7.2552 0.55374E-07 -7.2567 0.99663E+00 -0.0015 101 S2-2 0.21079E-12 -12.6761 0.10881E-12 -12.9633 0.51620E+00 -0.2872 107 SO3-2 0.10687E-16 -16.9711 0.55973E-17 -17.2520 0.52375E+00 -0.2809 108 HSO3- 0.31555E-19 -19.5009 0.26329E-19 -19.5796 0.83436E+00 -0.0786 109 HSO4- 0.32175E-18 -18.4925 0.26924E-18 -18.5699 0.83680E+00 -0.0774 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8949115E-10 -.2209714E-01 -.2223337E+02 0.0000 2 H2O 0.1000000E+01 0.5550557E+02 0.9981887E+06 0.0000 3 Cl- 0.3331173E-03 0.3346649E-03 0.1184398E+02 6.5682 4 SO4-- 0.7188740E-11 -.6889871E-03 -.6606866E+02 8.8188 5 HCO3- 0.1313592E-04 0.7239539E-03 0.4409585E+02 5.1647 6 HS- 0.2857926E-03 0.9748353E-03 0.3218298E+02 6.5017 7 Al+++ 0.1015077E-28 0.5255160E-05 0.1415424E+00 0.7390 8 H4SiO4 0.6959700E-03 0.1341320E-01 0.1286945E+04 -3.1574 9 Ca++ 0.1389597E-06 0.2482236E-06 0.9930787E-02 13.1018 10 Mg++ 0.2174038E-10 0.9522616E-10 0.2311062E-05 9.2942 11 Fe++ 0.5992023E-13 0.3587635E-07 0.2000058E-02 6.7350 12 K+ 0.1586394E-03 0.1593938E-03 0.6221640E+01 6.2467 13 Na+ 0.2013098E-01 0.2257812E-01 0.5181525E+03 8.3494 14 Mn++ 0.1923106E-10 0.2530610E-08 0.1387818E-03 9.2418 15 F- 0.1138313E-05 0.1142041E-05 0.2165828E-01 4.1009 16 HPO4-- 0.4436846E-07 0.4544249E-07 0.4353845E-02 12.6093 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279203E+02 -.1096952E-01 -.8278106E+02 0.0000000E+00 2 H2O -.7164867E+01 0.2755422E+02 -.3471908E+02 0.0000000E+00 3 Cl- 0.1661352E-03 0.1661352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386154E+00 -.3420287E-03 0.1389574E+00 0.0000000E+00 5 HCO3- 0.3593870E-03 0.3593870E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1384735E+00 0.4839302E-03 -.1389574E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2608780E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6658617E-02 0.5205725E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1232238E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4727241E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1780983E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7912665E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1120829E-01 0.6265169E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1256252E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2016000E-05 0.5669347E-06 0.1449065E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2255868E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.5086E-14 Mass of aqueous solution: 0.497298E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0047900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.1 andradite 0.5558 -0.255 282.5 2.451 5.171 73.39 grossular 0.1346 -0.871 60.63 1.783 1.110 16.87 apatite-OH 0.9861E-02 -2.006 4.953 0.695 0.9068E-01 1.574 apatite-F 0.1449E-05 -5.839 0.7308E-03 -3.136 0.1338E-04 0.2283E-03 clinochlore 0.7100 -0.149 394.6 2.596 7.225 150.1 daphnite 0.2055 -0.687 146.7 2.166 2.685 44.44 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2535 -0.596 54.91 1.740 1.005 16.78 hedenbergite 0.6575E-01 -1.182 16.31 1.213 0.2986 4.468 microcline 0.9312 -0.031 259.2 2.414 4.745 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2606 -0.584 280.9 2.449 5.143 97.05 tr.625ac.25prg.125 0.4547E-01 -1.342 38.86 1.590 0.7115 12.51 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.339393 g Volume = 2210.791078 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0047900 moles log = -2.3197 Original solution: 1000.0103000 g Original solution / Rock added: 208770.42 (Water/Rock Ratio), log = 5.3197 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.0446 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.5030E+00 0.9782 0.1006E+01 0.1028E+01 CO2,gas 0.9230E-07 0.9989 0.1885E-06 0.1887E-06 CH4,gas 0.4896E+00 1.0055 0.1006E+01 0.1001E+01 H2,gas 0.7429E-02 1.0011 0.1521E-01 0.1519E-01 H2S,gas 0.7505E-06 0.9921 0.1522E-05 0.1534E-05 S2,gas 0.1840E-27 1.0000 0.3761E-27 0.3761E-27 CO,gas 0.3737E-12 1.0000 0.7640E-12 0.7640E-12 SO3,gas 0.3881E-47 1.0000 0.7936E-47 0.7936E-47 SO2,gas 0.2296E-26 1.0000 0.4695E-26 0.4695E-26 HF,gas 0.5854E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.3302E-17 1.0000 0.6751E-17 0.6751E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.08 -8.42 -2.808 0.14383E+05 -6.725 3 CH4,gas 4.54 2.85 -1.70 -0.424 0.28962E+04 0.003 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.75 -7.52 -3.758 0.12834E+05 -5.818 6 S2,gas -7.34 -36.46 -29.12 -4.481 0.49728E+05 -27.425 7 CO,gas 3.21 -10.60 -13.82 -4.251 0.23590E+05 -12.117 8 SO3,gas 17.12 -31.68 -48.80 -12.200 0.83324E+05 -47.100 9 SO2,gas 0.83 -27.20 -28.03 -7.474 0.47856E+05 -26.328 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.68 -18.87 -9.435 0.32219E+05 -17.171 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80700E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93627E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.98 -2.95 -0.983 0.50344E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.98 -2.79 -0.931 0.47702E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65546E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.12 -3.02 -0.862 0.51493E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.12 -2.57 -0.735 0.43915E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82238E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.24 -3.99 -0.940 0.68203E+04 146 pyrrhotite -4.26 -7.01 -2.75 -0.917 0.46980E+04 147 pyrrhotiteFe0.875 -6.02 -8.41 -2.39 -0.880 0.40852E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22441E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.84 -4.87 -1.622 0.83080E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23244E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47120E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -7.01 -2.60 -0.867 0.44408E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.50 -3.53 -1.176 0.60224E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0047900 MOLES New total amount of reactant added: 0.0051900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8659E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0051900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4964E+00 Moles total = -.7165E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1099937E-01 Osmotic coef. = 0.9046 True ionic strength = .2033293E-01 Chg. balance for total moles = -.8659E-10 Max. difference allowed = 0.1685E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89562E-10 -10.0479 0.75180E-10 -10.1239 0.83942E+00 -0.0760 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.33784E-03 -3.4713 0.28187E-03 -3.5500 0.83431E+00 -0.0787 4 SO4-- 0.76767E-11 -11.1148 0.39703E-11 -11.4012 0.51719E+00 -0.2864 5 HCO3- 0.14184E-04 -4.8482 0.11852E-04 -4.9262 0.83555E+00 -0.0780 6 HS- 0.30536E-03 -3.5152 0.25481E-03 -3.5938 0.83444E+00 -0.0786 7 Al+++ 0.10179E-28 -28.9923 0.23297E-29 -29.6327 0.22888E+00 -0.6404 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13920E-06 -6.8564 0.71456E-07 -7.1460 0.51334E+00 -0.2896 10 Mg++ 0.21778E-10 -10.6620 0.11128E-10 -10.9536 0.51097E+00 -0.2916 11 Fe++ 0.60023E-13 -13.2217 0.30704E-13 -13.5128 0.51153E+00 -0.2911 12 K+ 0.15876E-03 -3.7992 0.13269E-03 -3.8772 0.83575E+00 -0.0779 13 Na+ 0.20147E-01 -1.6958 0.16806E-01 -1.7745 0.83416E+00 -0.0788 14 Mn++ 0.19265E-10 -10.7152 0.98628E-11 -11.0060 0.51196E+00 -0.2908 15 F- 0.11375E-05 -5.9440 0.94709E-06 -6.0236 0.83257E+00 -0.0796 16 HPO4-- 0.44314E-07 -7.3535 0.22922E-07 -7.6398 0.51726E+00 -0.2863 18 HSiO3- 0.10361E-01 -1.9846 0.86441E-02 -2.0633 0.83431E+00 -0.0787 19 Ca(HSiO3)+ 0.16828E-07 -7.7740 0.14067E-07 -7.8518 0.83593E+00 -0.0778 20 Mg(HSiO3)+ 0.32612E-11 -11.4866 0.27262E-11 -11.5644 0.83593E+00 -0.0778 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67079E-16 -16.1734 0.56074E-16 -16.2512 0.83593E+00 -0.0778 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52515E-05 -5.2797 0.43734E-05 -5.3592 0.83279E+00 -0.0795 26 CH4,aq 0.74132E-03 -3.1300 0.73883E-03 -3.1315 0.99664E+00 -0.0015 27 C2H6,aq 0.80842E-11 -11.0924 0.80571E-11 -11.0938 0.99664E+00 -0.0015 28 C3H8,aq 0.20354E-17 -17.6914 0.20285E-17 -17.6928 0.99664E+00 -0.0015 30 ethanol,aq 0.29672E-18 -18.5277 0.29572E-18 -18.5291 0.99664E+00 -0.0015 31 CO,aq 0.55396E-15 -15.2565 0.55396E-15 -15.2565 0.10000E+01 0.0000 32 CO2,aq 0.19103E-08 -8.7189 0.19039E-08 -8.7204 0.99664E+00 -0.0015 33 CO3-2 0.26681E-04 -4.5738 0.13769E-04 -4.8611 0.51608E+00 -0.2873 34 CaCO3,aq 0.12337E-07 -7.9088 0.12337E-07 -7.9088 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.25860E-10 -10.5874 0.21617E-10 -10.6652 0.83593E+00 -0.0778 36 CaCl+ 0.38992E-10 -10.4090 0.32595E-10 -10.4869 0.83593E+00 -0.0778 37 CaCl2,aq 0.21827E-14 -14.6610 0.21827E-14 -14.6610 0.10000E+01 0.0000 38 CaF+ 0.11820E-11 -11.9274 0.98806E-12 -12.0052 0.83593E+00 -0.0778 39 CaOH+ 0.81033E-07 -7.0913 0.67738E-07 -7.1692 0.83593E+00 -0.0778 40 CaSO4,aq 0.90088E-16 -16.0453 0.90088E-16 -16.0453 0.10000E+01 0.0000 41 HCl,aq 0.38831E-14 -14.4108 0.38831E-14 -14.4108 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18682E-18 -18.7286 0.15586E-18 -18.8073 0.83431E+00 -0.0787 48 FeCl+ 0.16387E-16 -16.7855 0.13698E-16 -16.8633 0.83593E+00 -0.0778 51 FeF+ 0.17776E-17 -17.7502 0.14860E-17 -17.8280 0.83593E+00 -0.0778 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15903E-10 -10.7985 0.13294E-10 -10.8764 0.83593E+00 -0.0778 55 HFeO2- 0.35218E-07 -7.4532 0.29383E-07 -7.5319 0.83431E+00 -0.0787 56 FeO+ 0.11146E-16 -16.9529 0.93169E-17 -17.0307 0.83593E+00 -0.0778 58 FeO2- 0.40427E-09 -9.3933 0.33729E-09 -9.4720 0.83431E+00 -0.0787 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11621E-04 -4.9347 0.11582E-04 -4.9362 0.99664E+00 -0.0015 61 KCl,aq 0.67785E-09 -9.1689 0.67785E-09 -9.1689 0.10000E+01 0.0000 63 KOH,aq 0.75371E-06 -6.1228 0.75371E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.97983E-14 -14.0089 0.81748E-14 -14.0875 0.83431E+00 -0.0787 65 MgCO3,aq 0.48156E-12 -12.3173 0.48156E-12 -12.3173 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.41149E-14 -14.3856 0.34398E-14 -14.4635 0.83593E+00 -0.0778 67 MgCl+ 0.55034E-14 -14.2594 0.46005E-14 -14.3372 0.83593E+00 -0.0778 68 MgF+ 0.68185E-15 -15.1663 0.56998E-15 -15.2441 0.83593E+00 -0.0778 69 MgOH+ 0.69827E-10 -10.1560 0.58371E-10 -10.2338 0.83593E+00 -0.0778 71 MnF+ 0.18822E-15 -15.7253 0.15734E-15 -15.8032 0.83593E+00 -0.0778 72 MnO,aq 0.18071E-08 -8.7430 0.18071E-08 -8.7430 0.10000E+01 0.0000 73 MnOH+ 0.47455E-09 -9.3237 0.39669E-09 -9.4015 0.83593E+00 -0.0778 74 MnO2-2 0.20560E-10 -10.6870 0.10610E-10 -10.9743 0.51608E+00 -0.2873 75 HMnO2- 0.20947E-09 -9.6789 0.17476E-09 -9.7576 0.83431E+00 -0.0787 78 MnCl+ 0.20479E-13 -13.6887 0.17119E-13 -13.7665 0.83593E+00 -0.0778 79 MnSO4,aq 0.11305E-19 -19.9467 0.11305E-19 -19.9467 0.10000E+01 0.0000 80 NaCl,aq 0.15699E-05 -5.8041 0.15699E-05 -5.8041 0.10000E+01 0.0000 81 NaF,aq 0.37264E-08 -8.4287 0.37264E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96042E-04 -4.0175 0.96042E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92281E-02 -2.0349 0.76851E-02 -2.1144 0.83279E+00 -0.0795 89 HPO3-2 0.16032E-14 -14.7950 0.82736E-15 -15.0823 0.51608E+00 -0.2873 91 H2PO3- 0.14950E-18 -18.8253 0.12473E-18 -18.9040 0.83431E+00 -0.0787 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38066E-10 -10.4195 0.31790E-10 -10.4977 0.83511E+00 -0.0783 94 PO4-3 0.10342E-08 -8.9854 0.24876E-09 -9.6042 0.24054E+00 -0.6188 98 HP2O7-3 0.91859E-18 -18.0369 0.21046E-18 -18.6768 0.22911E+00 -0.6399 99 P2O7-4 0.88153E-17 -17.0548 0.66877E-18 -18.1747 0.75864E-01 -1.1200 100 H2S,aq 0.59405E-07 -7.2262 0.59206E-07 -7.2276 0.99664E+00 -0.0015 101 S2-2 0.24068E-12 -12.6186 0.12421E-12 -12.9058 0.51608E+00 -0.2873 107 SO3-2 0.11412E-16 -16.9426 0.59759E-17 -17.2236 0.52363E+00 -0.2810 108 HSO3- 0.33716E-19 -19.4722 0.28130E-19 -19.5508 0.83431E+00 -0.0787 109 HSO4- 0.34378E-18 -18.4637 0.28766E-18 -18.5411 0.83676E+00 -0.0774 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8956189E-10 -.2208589E-01 -.2222201E+02 0.0000 2 H2O 0.1000000E+01 0.5550563E+02 0.9981881E+06 0.0000 3 Cl- 0.3378433E-03 0.3394139E-03 0.1201203E+02 6.5739 4 SO4-- 0.7676737E-11 -.7442252E-03 -.7136546E+02 8.8466 5 HCO3- 0.1418412E-04 0.7821992E-03 0.4764348E+02 5.1977 6 HS- 0.3053644E-03 0.1049649E-02 0.3465281E+02 6.5301 7 Al+++ 0.1017860E-28 0.5251632E-05 0.1414472E+00 0.7390 8 H4SiO4 0.6959692E-03 0.1340622E-01 0.1286273E+04 -3.1574 9 Ca++ 0.1391970E-06 0.2494604E-06 0.9980251E-02 13.1018 10 Mg++ 0.2177758E-10 0.9535894E-10 0.2314280E-05 9.2942 11 Fe++ 0.6002276E-13 0.3585233E-07 0.1998716E-02 6.7350 12 K+ 0.1587648E-03 0.1595192E-03 0.6226525E+01 6.2467 13 Na+ 0.2014692E-01 0.2259408E-01 0.5185179E+03 8.3494 14 Mn++ 0.1926469E-10 0.2530950E-08 0.1388002E-03 9.2418 15 F- 0.1137547E-05 0.1141275E-05 0.2164373E-01 4.1003 16 HPO4-- 0.4431374E-07 0.4538599E-07 0.4348424E-02 12.6080 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279199E+02 -.1096409E-01 -.8278102E+02 0.0000000E+00 2 H2O -.7164540E+01 0.2755465E+02 -.3471919E+02 0.0000000E+00 3 Cl- 0.1684952E-03 0.1684952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386173E+00 -.3694556E-03 0.1389868E+00 0.0000000E+00 5 HCO3- 0.3883070E-03 0.3883070E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1384657E+00 0.5210771E-03 -.1389868E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2607067E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6655246E-02 0.5205725E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1238396E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4733902E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1779817E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7919008E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1121638E-01 0.6265161E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1256439E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2176000E-05 0.5665630E-06 0.1609437E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2253096E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.2532E-13 Mass of aqueous solution: 0.497306E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0051900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.1 andradite 0.5559 -0.255 282.5 2.451 5.172 73.40 grossular 0.1346 -0.871 60.64 1.783 1.110 16.87 apatite-OH 0.9861E-02 -2.006 4.953 0.695 0.9068E-01 1.574 apatite-F 0.1609E-05 -5.793 0.8117E-03 -3.091 0.1486E-04 0.2536E-03 clinochlore 0.7100 -0.149 394.6 2.596 7.224 150.1 daphnite 0.2055 -0.687 146.6 2.166 2.685 44.44 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2528 -0.597 54.74 1.738 1.002 16.73 hedenbergite 0.6555E-01 -1.183 16.26 1.211 0.2977 4.455 microcline 0.9312 -0.031 259.2 2.414 4.745 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2606 -0.584 280.9 2.449 5.142 97.02 tr.625ac.25prg.125 0.4572E-01 -1.340 39.08 1.592 0.7154 12.58 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.339519 g Volume = 2210.792181 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0051900 moles log = -2.2848 Original solution: 1000.0103000 g Original solution / Rock added: 192680.21 (Water/Rock Ratio), log = 5.2848 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.1258 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4839E+00 0.9779 0.1006E+01 0.1029E+01 CO2,gas 0.9596E-07 0.9986 0.2037E-06 0.2040E-06 CH4,gas 0.5089E+00 1.0051 0.1088E+01 0.1082E+01 H2,gas 0.7145E-02 1.0011 0.1521E-01 0.1519E-01 H2S,gas 0.7719E-06 0.9918 0.1628E-05 0.1641E-05 S2,gas 0.2023E-27 1.0000 0.4300E-27 0.4300E-27 CO,gas 0.3883E-12 1.0000 0.8255E-12 0.8255E-12 SO3,gas 0.3991E-47 1.0000 0.8485E-47 0.8485E-47 SO2,gas 0.2361E-26 1.0000 0.5020E-26 0.5020E-26 HF,gas 0.5630E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.3223E-17 1.0000 0.6852E-17 0.6852E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.05 -8.39 -2.797 0.14326E+05 -6.691 3 CH4,gas 4.54 2.88 -1.66 -0.416 0.28387E+04 0.036 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.72 -7.49 -3.744 0.12785E+05 -5.788 6 S2,gas -7.34 -36.40 -29.07 -4.472 0.49629E+05 -27.367 7 CO,gas 3.21 -10.57 -13.78 -4.241 0.23533E+05 -12.083 8 SO3,gas 17.12 -31.65 -48.77 -12.193 0.83274E+05 -47.071 9 SO2,gas 0.83 -27.17 -28.00 -7.466 0.47806E+05 -26.299 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.67 -18.86 -9.432 0.32208E+05 -17.164 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80699E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93627E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.95 -2.91 -0.972 0.49770E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.95 -2.76 -0.920 0.47127E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.08 -2.98 -0.852 0.50918E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.08 -2.54 -0.725 0.43341E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82237E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.18 -3.94 -0.926 0.67211E+04 146 pyrrhotite -4.26 -6.98 -2.72 -0.907 0.46484E+04 147 pyrrhotiteFe0.875 -6.02 -8.38 -2.36 -0.869 0.40356E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22441E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.81 -4.83 -1.611 0.82505E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23244E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47120E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.98 -2.57 -0.857 0.43912E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.48 -3.50 -1.166 0.59728E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0051900 MOLES New total amount of reactant added: 0.0055900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8659E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0055900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4964E+00 Moles total = -.7164E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1096581E-01 Osmotic coef. = 0.9061 True ionic strength = .2035096E-01 Chg. balance for total moles = -.8659E-10 Max. difference allowed = 0.1709E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89633E-10 -10.0475 0.75235E-10 -10.1236 0.83938E+00 -0.0760 2 H2O 0.99999E+00 0.0000 0.99999E+00 0.0000 3 Cl- 0.34257E-03 -3.4653 0.28579E-03 -3.5439 0.83426E+00 -0.0787 4 SO4-- 0.81642E-11 -11.0881 0.42214E-11 -11.3745 0.51707E+00 -0.2865 5 HCO3- 0.15231E-04 -4.8173 0.12725E-04 -4.8953 0.83550E+00 -0.0781 6 HS- 0.32494E-03 -3.4882 0.27112E-03 -3.5668 0.83439E+00 -0.0786 7 Al+++ 0.10206E-28 -28.9911 0.23348E-29 -29.6317 0.22876E+00 -0.6406 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13943E-06 -6.8556 0.71561E-07 -7.1453 0.51322E+00 -0.2897 10 Mg++ 0.21815E-10 -10.6612 0.11144E-10 -10.9530 0.51084E+00 -0.2917 11 Fe++ 0.60125E-13 -13.2209 0.30749E-13 -13.5122 0.51141E+00 -0.2912 12 K+ 0.15889E-03 -3.7989 0.13278E-03 -3.8769 0.83570E+00 -0.0779 13 Na+ 0.20163E-01 -1.6954 0.16818E-01 -1.7742 0.83411E+00 -0.0788 14 Mn++ 0.19298E-10 -10.7145 0.98777E-11 -11.0053 0.51184E+00 -0.2909 15 F- 0.11368E-05 -5.9443 0.94640E-06 -6.0239 0.83252E+00 -0.0796 16 HPO4-- 0.44259E-07 -7.3540 0.22888E-07 -7.6404 0.51714E+00 -0.2864 18 HSiO3- 0.10354E-01 -1.9849 0.86377E-02 -2.0636 0.83426E+00 -0.0787 19 Ca(HSiO3)+ 0.16841E-07 -7.7736 0.14077E-07 -7.8515 0.83588E+00 -0.0779 20 Mg(HSiO3)+ 0.32638E-11 -11.4863 0.27282E-11 -11.5641 0.83588E+00 -0.0779 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67133E-16 -16.1731 0.56115E-16 -16.2509 0.83588E+00 -0.0779 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52480E-05 -5.2800 0.43702E-05 -5.3595 0.83274E+00 -0.0795 26 CH4,aq 0.79656E-03 -3.0988 0.79390E-03 -3.1002 0.99665E+00 -0.0015 27 C2H6,aq 0.93340E-11 -11.0299 0.93028E-11 -11.0314 0.99665E+00 -0.0015 28 C3H8,aq 0.25252E-17 -17.5977 0.25167E-17 -17.5992 0.99665E+00 -0.0015 30 ethanol,aq 0.34259E-18 -18.4652 0.34145E-18 -18.4667 0.99665E+00 -0.0015 31 CO,aq 0.59525E-15 -15.2253 0.59525E-15 -15.2253 0.10000E+01 0.0000 32 CO2,aq 0.20527E-08 -8.6877 0.20458E-08 -8.6891 0.99665E+00 -0.0015 33 CO3-2 0.28634E-04 -4.5431 0.14774E-04 -4.8305 0.51595E+00 -0.2874 34 CaCO3,aq 0.13257E-07 -7.8776 0.13257E-07 -7.8776 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.27809E-10 -10.5558 0.23245E-10 -10.6337 0.83588E+00 -0.0779 36 CaCl+ 0.39595E-10 -10.4024 0.33097E-10 -10.4802 0.83588E+00 -0.0779 37 CaCl2,aq 0.22472E-14 -14.6484 0.22472E-14 -14.6484 0.10000E+01 0.0000 38 CaF+ 0.11829E-11 -11.9270 0.98879E-12 -12.0049 0.83588E+00 -0.0779 39 CaOH+ 0.81097E-07 -7.0910 0.67787E-07 -7.1689 0.83588E+00 -0.0779 40 CaSO4,aq 0.95927E-16 -16.0181 0.95927E-16 -16.0181 0.10000E+01 0.0000 41 HCl,aq 0.39401E-14 -14.4045 0.39401E-14 -14.4045 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18669E-18 -18.7289 0.15575E-18 -18.8076 0.83426E+00 -0.0787 48 FeCl+ 0.16641E-16 -16.7788 0.13910E-16 -16.8567 0.83588E+00 -0.0779 51 FeF+ 0.17791E-17 -17.7498 0.14871E-17 -17.8277 0.83588E+00 -0.0779 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15915E-10 -10.7982 0.13303E-10 -10.8760 0.83588E+00 -0.0779 55 HFeO2- 0.35194E-07 -7.4535 0.29361E-07 -7.5322 0.83426E+00 -0.0787 56 FeO+ 0.11154E-16 -16.9526 0.93237E-17 -17.0304 0.83588E+00 -0.0779 58 FeO2- 0.40400E-09 -9.3936 0.33704E-09 -9.4723 0.83426E+00 -0.0787 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11621E-04 -4.9347 0.11582E-04 -4.9362 0.99665E+00 -0.0015 61 KCl,aq 0.68779E-09 -9.1625 0.68779E-09 -9.1625 0.10000E+01 0.0000 63 KOH,aq 0.75371E-06 -6.1228 0.75371E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.10426E-13 -13.9819 0.86982E-14 -14.0606 0.83426E+00 -0.0787 65 MgCO3,aq 0.51745E-12 -12.2861 0.51745E-12 -12.2861 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.44251E-14 -14.3541 0.36989E-14 -14.4319 0.83588E+00 -0.0779 67 MgCl+ 0.55886E-14 -14.2527 0.46714E-14 -14.3306 0.83588E+00 -0.0779 68 MgF+ 0.68239E-15 -15.1660 0.57039E-15 -15.2438 0.83588E+00 -0.0779 69 MgOH+ 0.69882E-10 -10.1556 0.58413E-10 -10.2335 0.83588E+00 -0.0779 71 MnF+ 0.18837E-15 -15.7250 0.15746E-15 -15.8028 0.83588E+00 -0.0779 72 MnO,aq 0.18072E-08 -8.7430 0.18072E-08 -8.7430 0.10000E+01 0.0000 73 MnOH+ 0.47495E-09 -9.3234 0.39700E-09 -9.4012 0.83588E+00 -0.0779 74 MnO2-2 0.20535E-10 -10.6875 0.10595E-10 -10.9749 0.51595E+00 -0.2874 75 HMnO2- 0.20934E-09 -9.6792 0.17464E-09 -9.7579 0.83426E+00 -0.0787 78 MnCl+ 0.20797E-13 -13.6820 0.17384E-13 -13.7599 0.83588E+00 -0.0779 79 MnSO4,aq 0.12038E-19 -19.9195 0.12038E-19 -19.9195 0.10000E+01 0.0000 80 NaCl,aq 0.15929E-05 -5.7978 0.15929E-05 -5.7978 0.10000E+01 0.0000 81 NaF,aq 0.37264E-08 -8.4287 0.37264E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96042E-04 -4.0175 0.96042E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92219E-02 -2.0352 0.76794E-02 -2.1147 0.83274E+00 -0.0795 89 HPO3-2 0.16012E-14 -14.7956 0.82615E-15 -15.0829 0.51595E+00 -0.2874 91 H2PO3- 0.14940E-18 -18.8256 0.12464E-18 -18.9043 0.83426E+00 -0.0787 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38041E-10 -10.4198 0.31766E-10 -10.4980 0.83506E+00 -0.0783 94 PO4-3 0.10324E-08 -8.9861 0.24821E-09 -9.6052 0.24042E+00 -0.6190 98 HP2O7-3 0.91706E-18 -18.0376 0.21000E-18 -18.6778 0.22899E+00 -0.6402 99 P2O7-4 0.87977E-17 -17.0556 0.66681E-18 -18.1760 0.75794E-01 -1.1204 100 H2S,aq 0.63254E-07 -7.1989 0.63042E-07 -7.2004 0.99665E+00 -0.0015 101 S2-2 0.27255E-12 -12.5645 0.14063E-12 -12.8519 0.51595E+00 -0.2874 107 SO3-2 0.12137E-16 -16.9159 0.63539E-17 -17.1970 0.52351E+00 -0.2811 108 HSO3- 0.35877E-19 -19.4452 0.29931E-19 -19.5239 0.83426E+00 -0.0787 109 HSO4- 0.36581E-18 -18.4367 0.30608E-18 -18.5142 0.83671E+00 -0.0774 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8963265E-10 -.2207464E-01 -.2221066E+02 0.0000 2 H2O 0.1000000E+01 0.5550568E+02 0.9981875E+06 0.0000 3 Cl- 0.3425692E-03 0.3441628E-03 0.1218008E+02 6.5796 4 SO4-- 0.8164172E-11 -.7994676E-03 -.7666265E+02 8.8726 5 HCO3- 0.1523101E-04 0.8404428E-03 0.5119100E+02 5.2283 6 HS- 0.3249356E-03 0.1124466E-02 0.3712275E+02 6.5567 7 Al+++ 0.1020649E-28 0.5248109E-05 0.1413520E+00 0.7390 8 H4SiO4 0.6959684E-03 0.1339924E-01 0.1285601E+04 -3.1574 9 Ca++ 0.1394347E-06 0.2506976E-06 0.1002973E-01 13.1018 10 Mg++ 0.2181482E-10 0.9548904E-10 0.2317434E-05 9.2942 11 Fe++ 0.6012541E-13 0.3582835E-07 0.1997376E-02 6.7350 12 K+ 0.1588902E-03 0.1596446E-03 0.6231412E+01 6.2467 13 Na+ 0.2016287E-01 0.2261004E-01 0.5188833E+03 8.3494 14 Mn++ 0.1929837E-10 0.2531290E-08 0.1388187E-03 9.2418 15 F- 0.1136783E-05 0.1140511E-05 0.2162919E-01 4.0997 16 HPO4-- 0.4425912E-07 0.4532958E-07 0.4343013E-02 12.6068 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279195E+02 -.1095867E-01 -.8278099E+02 0.0000000E+00 2 H2O -.7164212E+01 0.2755508E+02 -.3471929E+02 0.0000000E+00 3 Cl- 0.1708552E-03 0.1708552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386192E+00 -.3968854E-03 0.1390161E+00 0.0000000E+00 5 HCO3- 0.4172270E-03 0.4172270E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1384579E+00 0.5582269E-03 -.1390161E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2605356E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6651880E-02 0.5205725E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1244556E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4740430E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1778652E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7925352E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1122446E-01 0.6265152E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1256626E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2336000E-05 0.5661918E-06 0.1769808E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2250329E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.3572E-13 Mass of aqueous solution: 0.497314E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0055900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.1 andradite 0.5561 -0.255 282.6 2.451 5.173 73.42 grossular 0.1346 -0.871 60.65 1.783 1.110 16.88 apatite-OH 0.9861E-02 -2.006 4.953 0.695 0.9068E-01 1.574 apatite-F 0.1770E-05 -5.752 0.8925E-03 -3.049 0.1634E-04 0.2788E-03 clinochlore 0.7099 -0.149 394.6 2.596 7.224 150.1 daphnite 0.2055 -0.687 146.6 2.166 2.685 44.44 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2520 -0.599 54.58 1.737 0.9991 16.68 hedenbergite 0.6536E-01 -1.185 16.21 1.210 0.2968 4.441 microcline 0.9312 -0.031 259.2 2.414 4.745 101.3 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2605 -0.584 280.8 2.448 5.141 97.00 tr.625ac.25prg.125 0.4597E-01 -1.338 39.29 1.594 0.7193 12.65 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.339644 g Volume = 2210.793284 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0055900 moles log = -2.2526 Original solution: 1000.0103000 g Original solution / Rock added: 178892.72 (Water/Rock Ratio), log = 5.2526 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.2072 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4662E+00 0.9776 0.1006E+01 0.1029E+01 CO2,gas 0.9935E-07 0.9982 0.2189E-06 0.2193E-06 CH4,gas 0.5269E+00 1.0049 0.1169E+01 0.1163E+01 H2,gas 0.6881E-02 1.0012 0.1521E-01 0.1519E-01 H2S,gas 0.7919E-06 0.9915 0.1733E-05 0.1748E-05 S2,gas 0.2209E-27 1.0000 0.4875E-27 0.4875E-27 CO,gas 0.4019E-12 1.0000 0.8870E-12 0.8870E-12 SO3,gas 0.4093E-47 1.0000 0.9035E-47 0.9035E-47 SO2,gas 0.2422E-26 1.0000 0.5345E-26 0.5345E-26 HF,gas 0.5422E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.3150E-17 1.0000 0.6952E-17 0.6952E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.66728E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 0.18198E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.18198E-10 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -15.02 -8.36 -2.786 0.14272E+05 -6.660 3 CH4,gas 4.54 2.91 -1.63 -0.408 0.27854E+04 0.068 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.69 -7.46 -3.730 0.12738E+05 -5.761 6 S2,gas -7.34 -36.35 -29.01 -4.463 0.49535E+05 -27.312 7 CO,gas 3.21 -10.54 -13.75 -4.231 0.23480E+05 -12.052 8 SO3,gas 17.12 -31.62 -48.74 -12.186 0.83227E+05 -47.044 9 SO2,gas 0.83 -27.14 -27.97 -7.459 0.47760E+05 -26.272 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.67 -18.86 -9.428 0.32198E+05 -17.158 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80698E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93627E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.92 -2.88 -0.961 0.49237E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.92 -2.73 -0.910 0.46594E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.05 -2.95 -0.843 0.50385E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.05 -2.51 -0.716 0.42808E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82237E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.13 -3.88 -0.913 0.66279E+04 146 pyrrhotite -4.26 -6.96 -2.70 -0.898 0.46018E+04 147 pyrrhotiteFe0.875 -6.02 -8.35 -2.34 -0.859 0.39890E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22441E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.78 -4.80 -1.600 0.81972E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47119E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.96 -2.54 -0.848 0.43446E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.45 -3.47 -1.157 0.59262E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0055900 MOLES New total amount of reactant added: 0.0059900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8658E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0059900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4964E+00 Moles total = -.7164E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1093224E-01 Osmotic coef. = 0.9074 True ionic strength = .2036898E-01 Chg. balance for total moles = -.8658E-10 Max. difference allowed = 0.1732E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89703E-10 -10.0472 0.75291E-10 -10.1233 0.83933E+00 -0.0761 2 H2O 0.99998E+00 0.0000 0.99998E+00 0.0000 3 Cl- 0.34729E-03 -3.4593 0.28972E-03 -3.5380 0.83421E+00 -0.0787 4 SO4-- 0.86510E-11 -11.0629 0.44721E-11 -11.3495 0.51695E+00 -0.2866 5 HCO3- 0.16277E-04 -4.7884 0.13598E-04 -4.8665 0.83545E+00 -0.0781 6 HS- 0.34451E-03 -3.4628 0.28743E-03 -3.5415 0.83434E+00 -0.0787 7 Al+++ 0.10234E-28 -28.9899 0.23400E-29 -29.6308 0.22864E+00 -0.6409 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13967E-06 -6.8549 0.71666E-07 -7.1447 0.51310E+00 -0.2898 10 Mg++ 0.21852E-10 -10.6605 0.11160E-10 -10.9523 0.51072E+00 -0.2918 11 Fe++ 0.60228E-13 -13.2202 0.30794E-13 -13.5115 0.51129E+00 -0.2913 12 K+ 0.15902E-03 -3.7986 0.13288E-03 -3.8765 0.83565E+00 -0.0780 13 Na+ 0.20179E-01 -1.6951 0.16830E-01 -1.7739 0.83406E+00 -0.0788 14 Mn++ 0.19332E-10 -10.7137 0.98925E-11 -11.0047 0.51172E+00 -0.2910 15 F- 0.11360E-05 -5.9446 0.94570E-06 -6.0242 0.83247E+00 -0.0796 16 HPO4-- 0.44205E-07 -7.3545 0.22855E-07 -7.6410 0.51702E+00 -0.2865 18 HSiO3- 0.10347E-01 -1.9852 0.86314E-02 -2.0639 0.83421E+00 -0.0787 19 Ca(HSiO3)+ 0.16854E-07 -7.7733 0.14087E-07 -7.8512 0.83583E+00 -0.0779 20 Mg(HSiO3)+ 0.32664E-11 -11.4859 0.27302E-11 -11.5638 0.83583E+00 -0.0779 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67186E-16 -16.1727 0.56156E-16 -16.2506 0.83583E+00 -0.0779 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52444E-05 -5.2803 0.43670E-05 -5.3598 0.83269E+00 -0.0795 26 CH4,aq 0.85181E-03 -3.0697 0.84897E-03 -3.0711 0.99666E+00 -0.0015 27 C2H6,aq 0.10674E-10 -10.9717 0.10638E-10 -10.9731 0.99666E+00 -0.0015 28 C3H8,aq 0.30879E-17 -17.5103 0.30776E-17 -17.5118 0.99666E+00 -0.0015 30 ethanol,aq 0.39177E-18 -18.4070 0.39046E-18 -18.4084 0.99666E+00 -0.0015 31 CO,aq 0.63654E-15 -15.1962 0.63654E-15 -15.1962 0.10000E+01 0.0000 32 CO2,aq 0.21950E-08 -8.6586 0.21877E-08 -8.6600 0.99666E+00 -0.0015 33 CO3-2 0.30583E-04 -4.5145 0.15776E-04 -4.8020 0.51583E+00 -0.2875 34 CaCO3,aq 0.14176E-07 -7.8484 0.14176E-07 -7.8484 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.29762E-10 -10.5263 0.24876E-10 -10.6042 0.83583E+00 -0.0779 36 CaCl+ 0.40200E-10 -10.3958 0.33601E-10 -10.4737 0.83583E+00 -0.0779 37 CaCl2,aq 0.23128E-14 -14.6359 0.23128E-14 -14.6359 0.10000E+01 0.0000 38 CaF+ 0.11839E-11 -11.9267 0.98951E-12 -12.0046 0.83583E+00 -0.0779 39 CaOH+ 0.81161E-07 -7.0907 0.67837E-07 -7.1685 0.83583E+00 -0.0779 40 CaSO4,aq 0.10177E-15 -15.9924 0.10177E-15 -15.9924 0.10000E+01 0.0000 41 HCl,aq 0.39971E-14 -14.3982 0.39971E-14 -14.3982 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18656E-18 -18.7292 0.15563E-18 -18.8079 0.83421E+00 -0.0787 48 FeCl+ 0.16895E-16 -16.7722 0.14121E-16 -16.8501 0.83583E+00 -0.0779 51 FeF+ 0.17805E-17 -17.7495 0.14882E-17 -17.8273 0.83583E+00 -0.0779 53 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15928E-10 -10.7978 0.13313E-10 -10.8757 0.83583E+00 -0.0779 55 HFeO2- 0.35170E-07 -7.4538 0.29340E-07 -7.5325 0.83421E+00 -0.0787 56 FeO+ 0.11163E-16 -16.9522 0.93306E-17 -17.0301 0.83583E+00 -0.0779 58 FeO2- 0.40373E-09 -9.3939 0.33680E-09 -9.4726 0.83421E+00 -0.0787 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11621E-04 -4.9348 0.11582E-04 -4.9362 0.99666E+00 -0.0015 61 KCl,aq 0.69775E-09 -9.1563 0.69775E-09 -9.1563 0.10000E+01 0.0000 63 KOH,aq 0.75371E-06 -6.1228 0.75371E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.11054E-13 -13.9565 0.92215E-14 -14.0352 0.83421E+00 -0.0787 65 MgCO3,aq 0.55335E-12 -12.2570 0.55335E-12 -12.2570 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.47358E-14 -14.3246 0.39584E-14 -14.4025 0.83583E+00 -0.0779 67 MgCl+ 0.56740E-14 -14.2461 0.47425E-14 -14.3240 0.83583E+00 -0.0779 68 MgF+ 0.68293E-15 -15.1656 0.57081E-15 -15.2435 0.83583E+00 -0.0779 69 MgOH+ 0.69938E-10 -10.1553 0.58456E-10 -10.2332 0.83583E+00 -0.0779 71 MnF+ 0.18853E-15 -15.7246 0.15758E-15 -15.8025 0.83583E+00 -0.0779 72 MnO,aq 0.18072E-08 -8.7430 0.18072E-08 -8.7430 0.10000E+01 0.0000 73 MnOH+ 0.47534E-09 -9.3230 0.39731E-09 -9.4009 0.83583E+00 -0.0779 74 MnO2-2 0.20511E-10 -10.6880 0.10580E-10 -10.9755 0.51583E+00 -0.2875 75 HMnO2- 0.20920E-09 -9.6794 0.17452E-09 -9.7582 0.83421E+00 -0.0787 78 MnCl+ 0.21115E-13 -13.6754 0.17649E-13 -13.7533 0.83583E+00 -0.0779 79 MnSO4,aq 0.12772E-19 -19.8937 0.12772E-19 -19.8937 0.10000E+01 0.0000 80 NaCl,aq 0.16159E-05 -5.7916 0.16159E-05 -5.7916 0.10000E+01 0.0000 81 NaF,aq 0.37263E-08 -8.4287 0.37263E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96041E-04 -4.0175 0.96041E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92157E-02 -2.0355 0.76738E-02 -2.1150 0.83269E+00 -0.0795 89 HPO3-2 0.15992E-14 -14.7961 0.82494E-15 -15.0836 0.51583E+00 -0.2875 91 H2PO3- 0.14930E-18 -18.8259 0.12455E-18 -18.9047 0.83421E+00 -0.0787 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.38015E-10 -10.4200 0.31743E-10 -10.4984 0.83501E+00 -0.0783 94 PO4-3 0.10307E-08 -8.9869 0.24767E-09 -9.6061 0.24030E+00 -0.6193 98 HP2O7-3 0.91553E-18 -18.0383 0.20954E-18 -18.6787 0.22887E+00 -0.6404 99 P2O7-4 0.87801E-17 -17.0565 0.66486E-18 -18.1773 0.75724E-01 -1.1208 100 H2S,aq 0.67108E-07 -7.1732 0.66884E-07 -7.1747 0.99666E+00 -0.0015 101 S2-2 0.30641E-12 -12.5137 0.15806E-12 -12.8012 0.51583E+00 -0.2875 107 SO3-2 0.12861E-16 -16.8907 0.67312E-17 -17.1719 0.52340E+00 -0.2812 108 HSO3- 0.38038E-19 -19.4198 0.31732E-19 -19.4985 0.83421E+00 -0.0787 109 HSO4- 0.38784E-18 -18.4113 0.32449E-18 -18.4888 0.83666E+00 -0.0775 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8970343E-10 -.2206341E-01 -.2219932E+02 0.0000 2 H2O 0.1000000E+01 0.5550574E+02 0.9981869E+06 0.0000 3 Cl- 0.3472949E-03 0.3489115E-03 0.1234812E+02 6.5852 4 SO4-- 0.8651046E-11 -.8547142E-03 -.8196024E+02 8.8970 5 HCO3- 0.1627659E-04 0.8986847E-03 0.5473840E+02 5.2567 6 HS- 0.3445062E-03 0.1199287E-02 0.3959280E+02 6.5818 7 Al+++ 0.1023443E-28 0.5244590E-05 0.1412570E+00 0.7390 8 H4SiO4 0.6959676E-03 0.1339227E-01 0.1284931E+04 -3.1574 9 Ca++ 0.1396725E-06 0.2519351E-06 0.1007923E-01 13.1018 10 Mg++ 0.2185211E-10 0.9562003E-10 0.2320609E-05 9.2942 11 Fe++ 0.6022819E-13 0.3580439E-07 0.1996037E-02 6.7350 12 K+ 0.1590157E-03 0.1597701E-03 0.6236300E+01 6.2467 13 Na+ 0.2017882E-01 0.2262601E-01 0.5192489E+03 8.3494 14 Mn++ 0.1933209E-10 0.2531630E-08 0.1388371E-03 9.2418 15 F- 0.1136019E-05 0.1139747E-05 0.2161468E-01 4.0990 16 HPO4-- 0.4420459E-07 0.4527327E-07 0.4337611E-02 12.6055 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279190E+02 -.1095326E-01 -.8278095E+02 0.0000000E+00 2 H2O -.7163885E+01 0.2755551E+02 -.3471940E+02 0.0000000E+00 3 Cl- 0.1732152E-03 0.1732152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386211E+00 -.4243181E-03 0.1390454E+00 0.0000000E+00 5 HCO3- 0.4461470E-03 0.4461470E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1384501E+00 0.5953796E-03 -.1390454E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2603647E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6648518E-02 0.5205726E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1250718E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4747003E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1777489E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7931698E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1123256E-01 0.6265144E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1256814E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2496000E-05 0.5658209E-06 0.1930179E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2247566E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.2881E-13 Mass of aqueous solution: 0.497323E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0059900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.1 andradite 0.5562 -0.255 282.6 2.451 5.174 73.43 grossular 0.1347 -0.871 60.66 1.783 1.111 16.88 apatite-OH 0.9861E-02 -2.006 4.953 0.695 0.9068E-01 1.574 apatite-F 0.1930E-05 -5.714 0.9734E-03 -3.012 0.1782E-04 0.3041E-03 clinochlore 0.7099 -0.149 394.6 2.596 7.224 150.1 daphnite 0.2055 -0.687 146.6 2.166 2.684 44.43 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2512 -0.600 54.41 1.736 0.9961 16.63 hedenbergite 0.6516E-01 -1.186 16.17 1.209 0.2959 4.428 microcline 0.9313 -0.031 259.2 2.414 4.745 101.3 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2604 -0.584 280.7 2.448 5.140 96.98 tr.625ac.25prg.125 0.4622E-01 -1.335 39.50 1.597 0.7232 12.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.339768 g Volume = 2210.794387 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0059900 moles log = -2.2226 Original solution: 1000.0103000 g Original solution / Rock added: 166946.63 (Water/Rock Ratio), log = 5.2226 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.2885 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4498E+00 0.9772 0.1006E+01 0.1029E+01 CO2,gas 0.1025E-06 0.9978 0.2341E-06 0.2346E-06 CH4,gas 0.5436E+00 1.0046 0.1250E+01 0.1244E+01 H2,gas 0.6637E-02 1.0012 0.1521E-01 0.1519E-01 H2S,gas 0.8106E-06 0.9911 0.1839E-05 0.1855E-05 S2,gas 0.2398E-27 1.0000 0.5488E-27 0.5488E-27 CO,gas 0.4145E-12 1.0000 0.9486E-12 0.9486E-12 SO3,gas 0.4189E-47 1.0000 0.9585E-47 0.9585E-47 SO2,gas 0.2478E-26 1.0000 0.5671E-26 0.5671E-26 HF,gas 0.5230E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.3082E-17 1.0000 0.7053E-17 0.7053E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.99 -8.33 -2.777 0.14223E+05 -6.631 3 CH4,gas 4.54 2.94 -1.60 -0.401 0.27357E+04 0.097 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.66 -7.43 -3.717 0.12694E+05 -5.736 6 S2,gas -7.34 -36.30 -28.96 -4.455 0.49448E+05 -27.261 7 CO,gas 3.21 -10.51 -13.72 -4.222 0.23430E+05 -12.023 8 SO3,gas 17.12 -31.60 -48.72 -12.179 0.83184E+05 -47.018 9 SO2,gas 0.83 -27.11 -27.95 -7.452 0.47716E+05 -26.246 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.66 -18.85 -9.425 0.32187E+05 -17.152 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80697E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93627E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.89 -2.85 -0.951 0.48739E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.89 -2.70 -0.900 0.46097E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.02 -2.92 -0.835 0.49888E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.02 -2.48 -0.708 0.42310E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82237E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.08 -3.83 -0.901 0.65402E+04 146 pyrrhotite -4.26 -6.93 -2.67 -0.890 0.45580E+04 147 pyrrhotiteFe0.875 -6.02 -8.33 -2.31 -0.850 0.39452E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22441E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.75 -4.77 -1.591 0.81474E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47119E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.93 -2.52 -0.840 0.43008E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.42 -3.45 -1.148 0.58823E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0059900 MOLES New total amount of reactant added: 0.0063900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8657E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0063900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7164E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1089867E-01 Osmotic coef. = 0.9084 True ionic strength = .2038701E-01 Chg. balance for total moles = -.8657E-10 Max. difference allowed = 0.1756E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89774E-10 -10.0468 0.75346E-10 -10.1229 0.83928E+00 -0.0761 2 H2O 0.99998E+00 0.0000 0.99998E+00 0.0000 3 Cl- 0.35202E-03 -3.4534 0.29364E-03 -3.5322 0.83416E+00 -0.0787 4 SO4-- 0.91374E-11 -11.0392 0.47224E-11 -11.3258 0.51683E+00 -0.2867 5 HCO3- 0.17321E-04 -4.7614 0.14470E-04 -4.8395 0.83540E+00 -0.0781 6 HS- 0.36408E-03 -3.4388 0.30374E-03 -3.5175 0.83429E+00 -0.0787 7 Al+++ 0.10262E-28 -28.9887 0.23451E-29 -29.6298 0.22851E+00 -0.6411 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13991E-06 -6.8541 0.71771E-07 -7.1441 0.51298E+00 -0.2899 10 Mg++ 0.21889E-10 -10.6598 0.11177E-10 -10.9517 0.51060E+00 -0.2919 11 Fe++ 0.60331E-13 -13.2195 0.30839E-13 -13.5109 0.51116E+00 -0.2914 12 K+ 0.15914E-03 -3.7982 0.13298E-03 -3.8762 0.83560E+00 -0.0780 13 Na+ 0.20195E-01 -1.6948 0.16843E-01 -1.7736 0.83401E+00 -0.0788 14 Mn++ 0.19366E-10 -10.7130 0.99074E-11 -11.0040 0.51159E+00 -0.2911 15 F- 0.11353E-05 -5.9449 0.94501E-06 -6.0246 0.83242E+00 -0.0797 16 HPO4-- 0.44150E-07 -7.3551 0.22821E-07 -7.6417 0.51690E+00 -0.2866 18 HSiO3- 0.10340E-01 -1.9855 0.86251E-02 -2.0642 0.83416E+00 -0.0787 19 Ca(HSiO3)+ 0.16868E-07 -7.7729 0.14098E-07 -7.8509 0.83578E+00 -0.0779 20 Mg(HSiO3)+ 0.32690E-11 -11.4856 0.27322E-11 -11.5635 0.83578E+00 -0.0779 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67239E-16 -16.1724 0.56197E-16 -16.2503 0.83578E+00 -0.0779 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52409E-05 -5.2806 0.43638E-05 -5.3601 0.83263E+00 -0.0795 26 CH4,aq 0.90706E-03 -3.0424 0.90404E-03 -3.0438 0.99667E+00 -0.0014 27 C2H6,aq 0.12104E-10 -10.9171 0.12063E-10 -10.9185 0.99667E+00 -0.0014 28 C3H8,aq 0.37287E-17 -17.4284 0.37163E-17 -17.4299 0.99667E+00 -0.0014 30 ethanol,aq 0.44424E-18 -18.3524 0.44277E-18 -18.3538 0.99667E+00 -0.0014 31 CO,aq 0.67784E-15 -15.1689 0.67784E-15 -15.1689 0.10000E+01 0.0000 32 CO2,aq 0.23374E-08 -8.6313 0.23296E-08 -8.6327 0.99667E+00 -0.0014 33 CO3-2 0.32527E-04 -4.4878 0.16774E-04 -4.7754 0.51571E+00 -0.2876 34 CaCO3,aq 0.15096E-07 -7.8211 0.15096E-07 -7.8211 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.31718E-10 -10.4987 0.26509E-10 -10.5766 0.83578E+00 -0.0779 36 CaCl+ 0.40807E-10 -10.3893 0.34106E-10 -10.4672 0.83578E+00 -0.0779 37 CaCl2,aq 0.23793E-14 -14.6235 0.23793E-14 -14.6235 0.10000E+01 0.0000 38 CaF+ 0.11848E-11 -11.9264 0.99024E-12 -12.0043 0.83578E+00 -0.0779 39 CaOH+ 0.81225E-07 -7.0903 0.67887E-07 -7.1682 0.83578E+00 -0.0779 40 CaSO4,aq 0.10763E-15 -15.9681 0.10763E-15 -15.9681 0.10000E+01 0.0000 41 HCl,aq 0.40543E-14 -14.3921 0.40543E-14 -14.3921 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18644E-18 -18.7295 0.15552E-18 -18.8082 0.83416E+00 -0.0787 48 FeCl+ 0.17150E-16 -16.7657 0.14334E-16 -16.8436 0.83578E+00 -0.0779 51 FeF+ 0.17819E-17 -17.7491 0.14893E-17 -17.8270 0.83578E+00 -0.0779 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15941E-10 -10.7975 0.13323E-10 -10.8754 0.83578E+00 -0.0779 55 HFeO2- 0.35147E-07 -7.4541 0.29318E-07 -7.5329 0.83416E+00 -0.0787 56 FeO+ 0.11172E-16 -16.9519 0.93374E-17 -17.0298 0.83578E+00 -0.0779 58 FeO2- 0.40346E-09 -9.3942 0.33655E-09 -9.4730 0.83416E+00 -0.0787 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11621E-04 -4.9348 0.11582E-04 -4.9362 0.99667E+00 -0.0014 61 KCl,aq 0.70772E-09 -9.1501 0.70772E-09 -9.1501 0.10000E+01 0.0000 63 KOH,aq 0.75370E-06 -6.1228 0.75370E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.11682E-13 -13.9325 0.97447E-14 -14.0112 0.83416E+00 -0.0787 65 MgCO3,aq 0.58925E-12 -12.2297 0.58925E-12 -12.2297 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.50471E-14 -14.2970 0.42182E-14 -14.3749 0.83578E+00 -0.0779 67 MgCl+ 0.57596E-14 -14.2396 0.48138E-14 -14.3175 0.83578E+00 -0.0779 68 MgF+ 0.68347E-15 -15.1653 0.57123E-15 -15.2432 0.83578E+00 -0.0779 69 MgOH+ 0.69993E-10 -10.1549 0.58499E-10 -10.2329 0.83578E+00 -0.0779 71 MnF+ 0.18869E-15 -15.7243 0.15770E-15 -15.8022 0.83578E+00 -0.0779 72 MnO,aq 0.18073E-08 -8.7430 0.18073E-08 -8.7430 0.10000E+01 0.0000 73 MnOH+ 0.47574E-09 -9.3226 0.39761E-09 -9.4005 0.83578E+00 -0.0779 74 MnO2-2 0.20486E-10 -10.6885 0.10565E-10 -10.9761 0.51571E+00 -0.2876 75 HMnO2- 0.20907E-09 -9.6797 0.17440E-09 -9.7585 0.83416E+00 -0.0787 78 MnCl+ 0.21435E-13 -13.6689 0.17915E-13 -13.7468 0.83578E+00 -0.0779 79 MnSO4,aq 0.13507E-19 -19.8694 0.13507E-19 -19.8694 0.10000E+01 0.0000 80 NaCl,aq 0.16390E-05 -5.7854 0.16390E-05 -5.7854 0.10000E+01 0.0000 81 NaF,aq 0.37263E-08 -8.4287 0.37263E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96041E-04 -4.0175 0.96041E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92095E-02 -2.0358 0.76682E-02 -2.1153 0.83263E+00 -0.0795 89 HPO3-2 0.15973E-14 -14.7966 0.82373E-15 -15.0842 0.51571E+00 -0.2876 91 H2PO3- 0.14920E-18 -18.8262 0.12446E-18 -18.9050 0.83416E+00 -0.0787 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37989E-10 -10.4203 0.31720E-10 -10.4987 0.83496E+00 -0.0783 94 PO4-3 0.10289E-08 -8.9876 0.24712E-09 -9.6071 0.24018E+00 -0.6195 98 HP2O7-3 0.91401E-18 -18.0391 0.20908E-18 -18.6797 0.22875E+00 -0.6406 99 P2O7-4 0.87625E-17 -17.0574 0.66291E-18 -18.1785 0.75654E-01 -1.1212 100 H2S,aq 0.70967E-07 -7.1489 0.70731E-07 -7.1504 0.99667E+00 -0.0014 101 S2-2 0.34225E-12 -12.4657 0.17650E-12 -12.7533 0.51571E+00 -0.2876 107 SO3-2 0.13583E-16 -16.8670 0.71079E-17 -17.1483 0.52328E+00 -0.2813 108 HSO3- 0.40199E-19 -19.3958 0.33532E-19 -19.4745 0.83416E+00 -0.0787 109 HSO4- 0.40987E-18 -18.3873 0.34290E-18 -18.4648 0.83661E+00 -0.0775 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8977423E-10 -.2205218E-01 -.2218799E+02 0.0000 2 H2O 0.1000000E+01 0.5550580E+02 0.9981863E+06 0.0000 3 Cl- 0.3520204E-03 0.3536601E-03 0.1251615E+02 6.5908 4 SO4-- 0.9137361E-11 -.9099650E-03 -.8725821E+02 8.9200 5 HCO3- 0.1732087E-04 0.9569249E-03 0.5828568E+02 5.2834 6 HS- 0.3640762E-03 0.1274112E-02 0.4206297E+02 6.6054 7 Al+++ 0.1026244E-28 0.5241074E-05 0.1411621E+00 0.7390 8 H4SiO4 0.6959668E-03 0.1338531E-01 0.1284261E+04 -3.1574 9 Ca++ 0.1399107E-06 0.2531731E-06 0.1012874E-01 13.1018 10 Mg++ 0.2188944E-10 0.9575191E-10 0.2323806E-05 9.2942 11 Fe++ 0.6033108E-13 0.3578046E-07 0.1994700E-02 6.7350 12 K+ 0.1591412E-03 0.1598956E-03 0.6241190E+01 6.2467 13 Na+ 0.2019477E-01 0.2264198E-01 0.5196146E+03 8.3494 14 Mn++ 0.1936585E-10 0.2531971E-08 0.1388556E-03 9.2418 15 F- 0.1135256E-05 0.1138984E-05 0.2160018E-01 4.0984 16 HPO4-- 0.4415016E-07 0.4521706E-07 0.4332218E-02 12.6042 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279186E+02 -.1094784E-01 -.8278091E+02 0.0000000E+00 2 H2O -.7163557E+01 0.2755595E+02 -.3471950E+02 0.0000000E+00 3 Cl- 0.1755752E-03 0.1755752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386230E+00 -.4517537E-03 0.1390748E+00 0.0000000E+00 5 HCO3- 0.4750670E-03 0.4750670E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1384423E+00 0.6325352E-03 -.1390748E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2601940E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6645160E-02 0.5205726E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1256882E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4753620E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1776327E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7938046E-04 0.1061492E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1124065E-01 0.6265136E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1257001E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2656000E-05 0.5654506E-06 0.2090549E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2244809E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.5919E-14 Mass of aqueous solution: 0.497331E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0063900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.1 andradite 0.5563 -0.255 282.7 2.451 5.175 73.45 grossular 0.1347 -0.871 60.68 1.783 1.111 16.88 apatite-OH 0.9861E-02 -2.006 4.953 0.695 0.9068E-01 1.574 apatite-F 0.2091E-05 -5.680 0.1054E-02 -2.977 0.1930E-04 0.3294E-03 clinochlore 0.7099 -0.149 394.6 2.596 7.223 150.1 daphnite 0.2055 -0.687 146.6 2.166 2.684 44.43 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2505 -0.601 54.24 1.734 0.9931 16.58 hedenbergite 0.6496E-01 -1.187 16.12 1.207 0.2950 4.414 microcline 0.9313 -0.031 259.2 2.414 4.746 101.3 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2604 -0.584 280.7 2.448 5.138 96.95 tr.625ac.25prg.125 0.4647E-01 -1.333 39.72 1.599 0.7271 12.78 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.339893 g Volume = 2210.795490 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0063900 moles log = -2.1945 Original solution: 1000.0103000 g Original solution / Rock added: 156496.13 (Water/Rock Ratio), log = 5.1945 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.3698 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4345E+00 0.9770 0.1006E+01 0.1030E+01 CO2,gas 0.1054E-06 0.9975 0.2492E-06 0.2499E-06 CH4,gas 0.5591E+00 1.0043 0.1331E+01 0.1325E+01 H2,gas 0.6409E-02 1.0013 0.1521E-01 0.1519E-01 H2S,gas 0.8281E-06 0.9908 0.1944E-05 0.1962E-05 S2,gas 0.2590E-27 1.0000 0.6137E-27 0.6137E-27 CO,gas 0.4262E-12 1.0000 0.1010E-11 0.1010E-11 SO3,gas 0.4277E-47 1.0000 0.1014E-46 0.1014E-46 SO2,gas 0.2531E-26 1.0000 0.5997E-26 0.5997E-26 HF,gas 0.5050E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.3019E-17 1.0000 0.7154E-17 0.7154E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.96 -8.30 -2.767 0.14176E+05 -6.603 3 CH4,gas 4.54 2.97 -1.57 -0.394 0.26891E+04 0.124 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.64 -7.41 -3.705 0.12653E+05 -5.711 6 S2,gas -7.34 -36.25 -28.91 -4.448 0.49365E+05 -27.212 7 CO,gas 3.21 -10.48 -13.69 -4.214 0.23383E+05 -11.996 8 SO3,gas 17.12 -31.57 -48.69 -12.173 0.83142E+05 -46.994 9 SO2,gas 0.83 -27.09 -27.92 -7.446 0.47674E+05 -26.222 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.66 -18.84 -9.422 0.32176E+05 -17.145 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80696E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93627E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.86 -2.83 -0.942 0.48273E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.86 -2.67 -0.891 0.45631E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65545E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -6.00 -2.89 -0.827 0.49422E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -6.00 -2.45 -0.700 0.41844E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82237E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -25.03 -3.78 -0.890 0.64573E+04 146 pyrrhotite -4.26 -6.91 -2.65 -0.882 0.45165E+04 147 pyrrhotiteFe0.875 -6.02 -8.30 -2.29 -0.841 0.39037E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.72 -4.74 -1.581 0.81008E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47118E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.91 -2.49 -0.832 0.42593E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.40 -3.42 -1.140 0.58408E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0063900 MOLES New total amount of reactant added: 0.0067900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8658E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0067900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7163E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1086509E-01 Osmotic coef. = 0.9094 True ionic strength = .2040503E-01 Chg. balance for total moles = -.8658E-10 Max. difference allowed = 0.1779E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89845E-10 -10.0465 0.75401E-10 -10.1226 0.83923E+00 -0.0761 2 H2O 0.99998E+00 0.0000 0.99998E+00 0.0000 3 Cl- 0.35675E-03 -3.4476 0.29757E-03 -3.5264 0.83411E+00 -0.0788 4 SO4-- 0.96231E-11 -11.0167 0.49723E-11 -11.3034 0.51670E+00 -0.2868 5 HCO3- 0.18364E-04 -4.7360 0.15340E-04 -4.8142 0.83535E+00 -0.0781 6 HS- 0.38365E-03 -3.4161 0.32005E-03 -3.4948 0.83424E+00 -0.0787 7 Al+++ 0.10291E-28 -28.9876 0.23503E-29 -29.6289 0.22839E+00 -0.6413 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14015E-06 -6.8534 0.71876E-07 -7.1434 0.51285E+00 -0.2900 10 Mg++ 0.21927E-10 -10.6590 0.11193E-10 -10.9511 0.51047E+00 -0.2920 11 Fe++ 0.60434E-13 -13.2187 0.30884E-13 -13.5103 0.51104E+00 -0.2915 12 K+ 0.15927E-03 -3.7979 0.13308E-03 -3.8759 0.83555E+00 -0.0780 13 Na+ 0.20211E-01 -1.6944 0.16855E-01 -1.7733 0.83396E+00 -0.0789 14 Mn++ 0.19400E-10 -10.7122 0.99223E-11 -11.0034 0.51147E+00 -0.2912 15 F- 0.11345E-05 -5.9452 0.94432E-06 -6.0249 0.83237E+00 -0.0797 16 HPO4-- 0.44096E-07 -7.3556 0.22788E-07 -7.6423 0.51678E+00 -0.2867 18 HSiO3- 0.10333E-01 -1.9858 0.86188E-02 -2.0646 0.83411E+00 -0.0788 19 Ca(HSiO3)+ 0.16881E-07 -7.7726 0.14108E-07 -7.8505 0.83573E+00 -0.0779 20 Mg(HSiO3)+ 0.32716E-11 -11.4852 0.27342E-11 -11.5632 0.83573E+00 -0.0779 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67293E-16 -16.1720 0.56239E-16 -16.2500 0.83573E+00 -0.0779 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52374E-05 -5.2809 0.43606E-05 -5.3605 0.83258E+00 -0.0796 26 CH4,aq 0.96231E-03 -3.0167 0.95912E-03 -3.0181 0.99668E+00 -0.0014 27 C2H6,aq 0.13623E-10 -10.8657 0.13578E-10 -10.8672 0.99668E+00 -0.0014 28 C3H8,aq 0.44526E-17 -17.3514 0.44378E-17 -17.3528 0.99668E+00 -0.0014 30 ethanol,aq 0.50002E-18 -18.3010 0.49836E-18 -18.3025 0.99668E+00 -0.0014 31 CO,aq 0.71914E-15 -15.1432 0.71914E-15 -15.1432 0.10000E+01 0.0000 32 CO2,aq 0.24798E-08 -8.6056 0.24716E-08 -8.6070 0.99668E+00 -0.0014 33 CO3-2 0.34466E-04 -4.4626 0.17770E-04 -4.7503 0.51559E+00 -0.2877 34 CaCO3,aq 0.16016E-07 -7.7955 0.16016E-07 -7.7955 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.33677E-10 -10.4727 0.28145E-10 -10.5506 0.83573E+00 -0.0779 36 CaCl+ 0.41415E-10 -10.3828 0.34612E-10 -10.4608 0.83573E+00 -0.0779 37 CaCl2,aq 0.24469E-14 -14.6114 0.24469E-14 -14.6114 0.10000E+01 0.0000 38 CaF+ 0.11857E-11 -11.9260 0.99096E-12 -12.0039 0.83573E+00 -0.0779 39 CaOH+ 0.81290E-07 -7.0900 0.67936E-07 -7.1679 0.83573E+00 -0.0779 40 CaSO4,aq 0.11349E-15 -15.9451 0.11349E-15 -15.9451 0.10000E+01 0.0000 41 HCl,aq 0.41114E-14 -14.3860 0.41114E-14 -14.3860 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18631E-18 -18.7298 0.15541E-18 -18.8085 0.83411E+00 -0.0788 48 FeCl+ 0.17406E-16 -16.7593 0.14546E-16 -16.8372 0.83573E+00 -0.0779 51 FeF+ 0.17833E-17 -17.7488 0.14904E-17 -17.8267 0.83573E+00 -0.0779 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15953E-10 -10.7972 0.13333E-10 -10.8751 0.83573E+00 -0.0779 55 HFeO2- 0.35123E-07 -7.4544 0.29297E-07 -7.5332 0.83411E+00 -0.0788 56 FeO+ 0.11181E-16 -16.9515 0.93442E-17 -17.0295 0.83573E+00 -0.0779 58 FeO2- 0.40319E-09 -9.3945 0.33630E-09 -9.4733 0.83411E+00 -0.0788 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11621E-04 -4.9348 0.11582E-04 -4.9362 0.99668E+00 -0.0014 61 KCl,aq 0.71770E-09 -9.1441 0.71770E-09 -9.1441 0.10000E+01 0.0000 63 KOH,aq 0.75370E-06 -6.1228 0.75370E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.12310E-13 -13.9097 0.10268E-13 -13.9885 0.83411E+00 -0.0788 65 MgCO3,aq 0.62515E-12 -12.2040 0.62515E-12 -12.2040 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.53588E-14 -14.2709 0.44785E-14 -14.3489 0.83573E+00 -0.0779 67 MgCl+ 0.58455E-14 -14.2332 0.48852E-14 -14.3111 0.83573E+00 -0.0779 68 MgF+ 0.68401E-15 -15.1649 0.57165E-15 -15.2429 0.83573E+00 -0.0779 69 MgOH+ 0.70048E-10 -10.1546 0.58542E-10 -10.2325 0.83573E+00 -0.0779 71 MnF+ 0.18884E-15 -15.7239 0.15782E-15 -15.8018 0.83573E+00 -0.0779 72 MnO,aq 0.18074E-08 -8.7430 0.18074E-08 -8.7430 0.10000E+01 0.0000 73 MnOH+ 0.47613E-09 -9.3223 0.39792E-09 -9.4002 0.83573E+00 -0.0779 74 MnO2-2 0.20462E-10 -10.6891 0.10550E-10 -10.9767 0.51559E+00 -0.2877 75 HMnO2- 0.20894E-09 -9.6800 0.17428E-09 -9.7588 0.83411E+00 -0.0788 78 MnCl+ 0.21755E-13 -13.6624 0.18182E-13 -13.7404 0.83573E+00 -0.0779 79 MnSO4,aq 0.14243E-19 -19.8464 0.14243E-19 -19.8464 0.10000E+01 0.0000 80 NaCl,aq 0.16621E-05 -5.7793 0.16621E-05 -5.7793 0.10000E+01 0.0000 81 NaF,aq 0.37263E-08 -8.4287 0.37263E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96040E-04 -4.0175 0.96040E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.92033E-02 -2.0361 0.76625E-02 -2.1156 0.83258E+00 -0.0796 89 HPO3-2 0.15953E-14 -14.7972 0.82253E-15 -15.0848 0.51559E+00 -0.2877 91 H2PO3- 0.14910E-18 -18.8265 0.12437E-18 -18.9053 0.83411E+00 -0.0788 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37964E-10 -10.4206 0.31697E-10 -10.4990 0.83491E+00 -0.0784 94 PO4-3 0.10272E-08 -8.9884 0.24658E-09 -9.6080 0.24006E+00 -0.6197 98 HP2O7-3 0.91249E-18 -18.0398 0.20862E-18 -18.6806 0.22863E+00 -0.6409 99 P2O7-4 0.87449E-17 -17.0582 0.66098E-18 -18.1798 0.75584E-01 -1.1216 100 H2S,aq 0.74832E-07 -7.1259 0.74583E-07 -7.1274 0.99668E+00 -0.0014 101 S2-2 0.38007E-12 -12.4201 0.19596E-12 -12.7078 0.51559E+00 -0.2877 107 SO3-2 0.14305E-16 -16.8445 0.74841E-17 -17.1259 0.52316E+00 -0.2814 108 HSO3- 0.42359E-19 -19.3730 0.35333E-19 -19.4518 0.83411E+00 -0.0788 109 HSO4- 0.43190E-18 -18.3646 0.36131E-18 -18.4421 0.83656E+00 -0.0775 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8984505E-10 -.2204097E-01 -.2217668E+02 0.0000 2 H2O 0.1000000E+01 0.5550585E+02 0.9981857E+06 0.0000 3 Cl- 0.3567457E-03 0.3584086E-03 0.1268418E+02 6.5962 4 SO4-- 0.9623116E-11 -.9652201E-03 -.9255656E+02 8.9418 5 HCO3- 0.1836385E-04 0.1015163E-02 0.6183285E+02 5.3085 6 HS- 0.3836456E-03 0.1348941E-02 0.4453324E+02 6.6278 7 Al+++ 0.1029051E-28 0.5237564E-05 0.1410673E+00 0.7390 8 H4SiO4 0.6959661E-03 0.1337836E-01 0.1283591E+04 -3.1574 9 Ca++ 0.1401492E-06 0.2544115E-06 0.1017827E-01 13.1018 10 Mg++ 0.2192682E-10 0.9588468E-10 0.2327025E-05 9.2942 11 Fe++ 0.6043409E-13 0.3575656E-07 0.1993364E-02 6.7350 12 K+ 0.1592668E-03 0.1600212E-03 0.6246080E+01 6.2467 13 Na+ 0.2021073E-01 0.2265795E-01 0.5199803E+03 8.3493 14 Mn++ 0.1939966E-10 0.2532312E-08 0.1388741E-03 9.2419 15 F- 0.1134494E-05 0.1138222E-05 0.2158569E-01 4.0977 16 HPO4-- 0.4409582E-07 0.4516095E-07 0.4326835E-02 12.6029 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279182E+02 -.1094244E-01 -.8278087E+02 0.0000000E+00 2 H2O -.7163230E+01 0.2755638E+02 -.3471961E+02 0.0000000E+00 3 Cl- 0.1779352E-03 0.1779352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386249E+00 -.4791922E-03 0.1391041E+00 0.0000000E+00 5 HCO3- 0.5039870E-03 0.5039870E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1384344E+00 0.6696936E-03 -.1391041E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2600236E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6641806E-02 0.5205726E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1263049E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4760281E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1775167E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7944396E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1124874E-01 0.6265128E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1257189E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2816000E-05 0.5650806E-06 0.2250919E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2242056E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.7536E-14 Mass of aqueous solution: 0.497339E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0067900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.1 andradite 0.5564 -0.255 282.8 2.451 5.177 73.46 grossular 0.1347 -0.871 60.69 1.783 1.111 16.89 apatite-OH 0.9860E-02 -2.006 4.953 0.695 0.9068E-01 1.574 apatite-F 0.2251E-05 -5.648 0.1135E-02 -2.945 0.2078E-04 0.3546E-03 clinochlore 0.7098 -0.149 394.5 2.596 7.223 150.1 daphnite 0.2055 -0.687 146.6 2.166 2.684 44.43 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2497 -0.603 54.08 1.733 0.9900 16.53 hedenbergite 0.6476E-01 -1.189 16.07 1.206 0.2941 4.401 microcline 0.9313 -0.031 259.2 2.414 4.746 101.3 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2603 -0.585 280.6 2.448 5.137 96.93 tr.625ac.25prg.125 0.4671E-01 -1.331 39.93 1.601 0.7310 12.85 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.340017 g Volume = 2210.796593 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0067900 moles log = -2.1681 Original solution: 1000.0103000 g Original solution / Rock added: 147276.92 (Water/Rock Ratio), log = 5.1681 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.4512 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4202E+00 0.9767 0.1006E+01 0.1030E+01 CO2,gas 0.1082E-06 0.9972 0.2644E-06 0.2652E-06 CH4,gas 0.5736E+00 1.0041 0.1412E+01 0.1406E+01 H2,gas 0.6196E-02 1.0013 0.1521E-01 0.1519E-01 H2S,gas 0.8444E-06 0.9905 0.2050E-05 0.2070E-05 S2,gas 0.2784E-27 1.0000 0.6824E-27 0.6824E-27 CO,gas 0.4372E-12 1.0000 0.1072E-11 0.1072E-11 SO3,gas 0.4361E-47 1.0000 0.1069E-46 0.1069E-46 SO2,gas 0.2580E-26 1.0000 0.6324E-26 0.6324E-26 HF,gas 0.4883E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2960E-17 1.0000 0.7255E-17 0.7255E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -14.94 -8.28 -2.759 0.14132E+05 -6.578 3 CH4,gas 4.54 2.99 -1.55 -0.387 0.26452E+04 0.150 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.62 -7.39 -3.694 0.12613E+05 -5.688 6 S2,gas -7.34 -36.20 -28.86 -4.441 0.49286E+05 -27.166 7 CO,gas 3.21 -10.45 -13.67 -4.206 0.23339E+05 -11.970 8 SO3,gas 17.12 -31.55 -48.67 -12.168 0.83103E+05 -46.971 9 SO2,gas 0.83 -27.07 -27.90 -7.439 0.47635E+05 -26.199 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.65 -18.84 -9.419 0.32166E+05 -17.139 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80695E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93627E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.83 -2.80 -0.934 0.47835E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.83 -2.65 -0.882 0.45192E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.97 -2.87 -0.820 0.48983E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.97 -2.42 -0.693 0.41406E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.98 -3.74 -0.879 0.63786E+04 146 pyrrhotite -4.26 -6.88 -2.62 -0.874 0.44772E+04 147 pyrrhotiteFe0.875 -6.02 -8.28 -2.26 -0.832 0.38644E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.69 -4.72 -1.573 0.80569E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23243E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47117E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.88 -2.47 -0.824 0.42200E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.38 -3.40 -1.133 0.58014E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0067900 MOLES New total amount of reactant added: 0.0071900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8657E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0071900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7163E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1083150E-01 Osmotic coef. = 0.9102 True ionic strength = .2042305E-01 Chg. balance for total moles = -.8657E-10 Max. difference allowed = 0.1803E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89916E-10 -10.0462 0.75456E-10 -10.1223 0.83919E+00 -0.0761 2 H2O 0.99998E+00 0.0000 0.99998E+00 0.0000 3 Cl- 0.36147E-03 -3.4419 0.30149E-03 -3.5207 0.83406E+00 -0.0788 4 SO4-- 0.10108E-10 -10.9953 0.52218E-11 -11.2822 0.51658E+00 -0.2869 5 HCO3- 0.19406E-04 -4.7121 0.16209E-04 -4.7902 0.83530E+00 -0.0782 6 HS- 0.40321E-03 -3.3945 0.33636E-03 -3.4732 0.83419E+00 -0.0787 7 Al+++ 0.10319E-28 -28.9864 0.23555E-29 -29.6279 0.22827E+00 -0.6415 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14039E-06 -6.8527 0.71981E-07 -7.1428 0.51273E+00 -0.2901 10 Mg++ 0.21964E-10 -10.6583 0.11209E-10 -10.9504 0.51035E+00 -0.2921 11 Fe++ 0.60537E-13 -13.2180 0.30929E-13 -13.5096 0.51092E+00 -0.2916 12 K+ 0.15939E-03 -3.7975 0.13317E-03 -3.8756 0.83550E+00 -0.0781 13 Na+ 0.20227E-01 -1.6941 0.16867E-01 -1.7730 0.83391E+00 -0.0789 14 Mn++ 0.19433E-10 -10.7114 0.99373E-11 -11.0027 0.51135E+00 -0.2913 15 F- 0.11337E-05 -5.9455 0.94362E-06 -6.0252 0.83232E+00 -0.0797 16 HPO4-- 0.44042E-07 -7.3561 0.22754E-07 -7.6429 0.51666E+00 -0.2868 18 HSiO3- 0.10326E-01 -1.9861 0.86125E-02 -2.0649 0.83406E+00 -0.0788 19 Ca(HSiO3)+ 0.16894E-07 -7.7723 0.14118E-07 -7.8502 0.83568E+00 -0.0780 20 Mg(HSiO3)+ 0.32742E-11 -11.4849 0.27362E-11 -11.5629 0.83568E+00 -0.0780 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67346E-16 -16.1717 0.56280E-16 -16.2496 0.83568E+00 -0.0780 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52339E-05 -5.2812 0.43574E-05 -5.3608 0.83253E+00 -0.0796 26 CH4,aq 0.10176E-02 -2.9924 0.10142E-02 -2.9939 0.99669E+00 -0.0014 27 C2H6,aq 0.15233E-10 -10.8172 0.15182E-10 -10.8187 0.99669E+00 -0.0014 28 C3H8,aq 0.52646E-17 -17.2786 0.52472E-17 -17.2801 0.99669E+00 -0.0014 30 ethanol,aq 0.55910E-18 -18.2525 0.55725E-18 -18.2539 0.99669E+00 -0.0014 31 CO,aq 0.76044E-15 -15.1189 0.76044E-15 -15.1189 0.10000E+01 0.0000 32 CO2,aq 0.26222E-08 -8.5813 0.26135E-08 -8.5828 0.99669E+00 -0.0014 33 CO3-2 0.36401E-04 -4.4389 0.18764E-04 -4.7267 0.51547E+00 -0.2878 34 CaCO3,aq 0.16935E-07 -7.7712 0.16935E-07 -7.7712 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.35639E-10 -10.4481 0.29783E-10 -10.5260 0.83568E+00 -0.0780 36 CaCl+ 0.42025E-10 -10.3765 0.35120E-10 -10.4544 0.83568E+00 -0.0780 37 CaCl2,aq 0.25155E-14 -14.5994 0.25155E-14 -14.5994 0.10000E+01 0.0000 38 CaF+ 0.11867E-11 -11.9257 0.99169E-12 -12.0036 0.83568E+00 -0.0780 39 CaOH+ 0.81354E-07 -7.0896 0.67986E-07 -7.1676 0.83568E+00 -0.0780 40 CaSO4,aq 0.11936E-15 -15.9232 0.11936E-15 -15.9232 0.10000E+01 0.0000 41 HCl,aq 0.41687E-14 -14.3800 0.41687E-14 -14.3800 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18619E-18 -18.7301 0.15529E-18 -18.8089 0.83406E+00 -0.0788 48 FeCl+ 0.17662E-16 -16.7530 0.14760E-16 -16.8309 0.83568E+00 -0.0780 51 FeF+ 0.17847E-17 -17.7484 0.14914E-17 -17.8264 0.83568E+00 -0.0780 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15966E-10 -10.7968 0.13342E-10 -10.8748 0.83568E+00 -0.0780 55 HFeO2- 0.35099E-07 -7.4547 0.29275E-07 -7.5335 0.83406E+00 -0.0788 56 FeO+ 0.11190E-16 -16.9512 0.93511E-17 -17.0291 0.83568E+00 -0.0780 58 FeO2- 0.40292E-09 -9.3948 0.33606E-09 -9.4736 0.83406E+00 -0.0788 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11621E-04 -4.9348 0.11582E-04 -4.9362 0.99669E+00 -0.0014 61 KCl,aq 0.72769E-09 -9.1381 0.72769E-09 -9.1381 0.10000E+01 0.0000 63 KOH,aq 0.75370E-06 -6.1228 0.75370E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.12938E-13 -13.8881 0.10791E-13 -13.9669 0.83406E+00 -0.0788 65 MgCO3,aq 0.66106E-12 -12.1798 0.66106E-12 -12.1798 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.56711E-14 -14.2463 0.47392E-14 -14.3243 0.83568E+00 -0.0780 67 MgCl+ 0.59316E-14 -14.2268 0.49569E-14 -14.3048 0.83568E+00 -0.0780 68 MgF+ 0.68455E-15 -15.1646 0.57206E-15 -15.2426 0.83568E+00 -0.0780 69 MgOH+ 0.70104E-10 -10.1543 0.58585E-10 -10.2322 0.83568E+00 -0.0780 71 MnF+ 0.18900E-15 -15.7235 0.15794E-15 -15.8015 0.83568E+00 -0.0780 72 MnO,aq 0.18074E-08 -8.7429 0.18074E-08 -8.7429 0.10000E+01 0.0000 73 MnOH+ 0.47653E-09 -9.3219 0.39823E-09 -9.3999 0.83568E+00 -0.0780 74 MnO2-2 0.20438E-10 -10.6896 0.10535E-10 -10.9774 0.51547E+00 -0.2878 75 HMnO2- 0.20881E-09 -9.6803 0.17416E-09 -9.7591 0.83406E+00 -0.0788 78 MnCl+ 0.22077E-13 -13.6561 0.18449E-13 -13.7340 0.83568E+00 -0.0780 79 MnSO4,aq 0.14980E-19 -19.8245 0.14980E-19 -19.8245 0.10000E+01 0.0000 80 NaCl,aq 0.16853E-05 -5.7733 0.16853E-05 -5.7733 0.10000E+01 0.0000 81 NaF,aq 0.37263E-08 -8.4287 0.37263E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96040E-04 -4.0175 0.96040E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.91972E-02 -2.0363 0.76569E-02 -2.1159 0.83253E+00 -0.0796 89 HPO3-2 0.15934E-14 -14.7977 0.82133E-15 -15.0855 0.51547E+00 -0.2878 91 H2PO3- 0.14900E-18 -18.8268 0.12428E-18 -18.9056 0.83406E+00 -0.0788 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37938E-10 -10.4209 0.31673E-10 -10.4993 0.83486E+00 -0.0784 94 PO4-3 0.10254E-08 -8.9891 0.24604E-09 -9.6090 0.23994E+00 -0.6199 98 HP2O7-3 0.91097E-18 -18.0405 0.20816E-18 -18.6816 0.22851E+00 -0.6411 99 P2O7-4 0.87275E-17 -17.0591 0.65905E-18 -18.1811 0.75514E-01 -1.1220 100 H2S,aq 0.78701E-07 -7.1040 0.78440E-07 -7.1055 0.99669E+00 -0.0014 101 S2-2 0.41988E-12 -12.3769 0.21644E-12 -12.6647 0.51547E+00 -0.2878 107 SO3-2 0.15027E-16 -16.8231 0.78596E-17 -17.1046 0.52304E+00 -0.2815 108 HSO3- 0.44520E-19 -19.3514 0.37132E-19 -19.4302 0.83406E+00 -0.0788 109 HSO4- 0.45393E-18 -18.3430 0.37972E-18 -18.4205 0.83651E+00 -0.0775 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8991589E-10 -.2202977E-01 -.2216537E+02 0.0000 2 H2O 0.1000000E+01 0.5550591E+02 0.9981851E+06 0.0000 3 Cl- 0.3614709E-03 0.3631569E-03 0.1285221E+02 6.6016 4 SO4-- 0.1010831E-10 -.1020479E-02 -.9785530E+02 8.9624 5 HCO3- 0.1940552E-04 0.1073400E-02 0.6537991E+02 5.3321 6 HS- 0.4032145E-03 0.1423772E-02 0.4700363E+02 6.6491 7 Al+++ 0.1031865E-28 0.5234057E-05 0.1409727E+00 0.7390 8 H4SiO4 0.6959653E-03 0.1337141E-01 0.1282923E+04 -3.1574 9 Ca++ 0.1403879E-06 0.2556502E-06 0.1022781E-01 13.1018 10 Mg++ 0.2196423E-10 0.9601565E-10 0.2330199E-05 9.2942 11 Fe++ 0.6053723E-13 0.3573268E-07 0.1992030E-02 6.7350 12 K+ 0.1593924E-03 0.1601468E-03 0.6250972E+01 6.2467 13 Na+ 0.2022669E-01 0.2267393E-01 0.5203462E+03 8.3493 14 Mn++ 0.1943350E-10 0.2532654E-08 0.1388926E-03 9.2419 15 F- 0.1133733E-05 0.1137461E-05 0.2157122E-01 4.0971 16 HPO4-- 0.4404157E-07 0.4510494E-07 0.4321462E-02 12.6017 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279177E+02 -.1093704E-01 -.8278084E+02 0.0000000E+00 2 H2O -.7162902E+01 0.2755681E+02 -.3471971E+02 0.0000000E+00 3 Cl- 0.1802952E-03 0.1802952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386269E+00 -.5066336E-03 0.1391335E+00 0.0000000E+00 5 HCO3- 0.5329070E-03 0.5329070E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1384266E+00 0.7068550E-03 -.1391335E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2598533E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6638455E-02 0.5205727E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1269217E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4766854E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1774007E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7950748E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1125684E-01 0.6265120E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1257377E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2976000E-05 0.5647111E-06 0.2411289E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2239308E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1161E-13 Mass of aqueous solution: 0.497347E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0071900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.1 andradite 0.5565 -0.255 282.8 2.452 5.178 73.48 grossular 0.1348 -0.870 60.70 1.783 1.111 16.89 apatite-OH 0.9860E-02 -2.006 4.953 0.695 0.9068E-01 1.574 apatite-F 0.2411E-05 -5.618 0.1216E-02 -2.915 0.2226E-04 0.3799E-03 clinochlore 0.7098 -0.149 394.5 2.596 7.223 150.1 daphnite 0.2055 -0.687 146.6 2.166 2.684 44.43 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2490 -0.604 53.91 1.732 0.9870 16.48 hedenbergite 0.6456E-01 -1.190 16.02 1.205 0.2932 4.387 microcline 0.9314 -0.031 259.2 2.414 4.746 101.3 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2603 -0.585 280.5 2.448 5.136 96.91 tr.625ac.25prg.125 0.4696E-01 -1.328 40.14 1.604 0.7349 12.92 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.340141 g Volume = 2210.797696 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0071900 moles log = -2.1433 Original solution: 1000.0103000 g Original solution / Rock added: 139083.49 (Water/Rock Ratio), log = 5.1433 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.5326 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4068E+00 0.9764 0.1006E+01 0.1030E+01 CO2,gas 0.1108E-06 0.9968 0.2796E-06 0.2805E-06 CH4,gas 0.5872E+00 1.0038 0.1493E+01 0.1487E+01 H2,gas 0.5996E-02 1.0014 0.1521E-01 0.1519E-01 H2S,gas 0.8598E-06 0.9902 0.2156E-05 0.2178E-05 S2,gas 0.2980E-27 1.0000 0.7548E-27 0.7548E-27 CO,gas 0.4475E-12 1.0000 0.1133E-11 0.1133E-11 SO3,gas 0.4439E-47 1.0000 0.1124E-46 0.1124E-46 SO2,gas 0.2626E-26 1.0000 0.6651E-26 0.6651E-26 HF,gas 0.4726E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2904E-17 1.0000 0.7356E-17 0.7356E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.66728E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.91 -8.25 -2.751 0.14091E+05 -6.553 3 CH4,gas 4.54 3.02 -1.52 -0.381 0.26038E+04 0.174 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.60 -7.37 -3.683 0.12576E+05 -5.666 6 S2,gas -7.34 -36.16 -28.82 -4.434 0.49211E+05 -27.122 7 CO,gas 3.21 -10.43 -13.64 -4.198 0.23298E+05 -11.946 8 SO3,gas 17.12 -31.53 -48.65 -12.162 0.83065E+05 -46.949 9 SO2,gas 0.83 -27.04 -27.88 -7.434 0.47598E+05 -26.177 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.64 -18.83 -9.416 0.32156E+05 -17.133 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80694E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93627E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.81 -2.78 -0.926 0.47420E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.81 -2.62 -0.874 0.44778E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.95 -2.84 -0.813 0.48569E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.95 -2.40 -0.686 0.40991E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.94 -3.69 -0.869 0.63038E+04 146 pyrrhotite -4.26 -6.86 -2.60 -0.867 0.44398E+04 147 pyrrhotiteFe0.875 -6.02 -8.26 -2.24 -0.824 0.38270E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22440E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.67 -4.69 -1.565 0.80155E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47117E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.86 -2.45 -0.817 0.41826E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.35 -3.38 -1.125 0.57640E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0071900 MOLES New total amount of reactant added: 0.0075900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8656E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0075900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7163E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1079791E-01 Osmotic coef. = 0.9109 True ionic strength = .2044108E-01 Chg. balance for total moles = -.8656E-10 Max. difference allowed = 0.1827E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89987E-10 -10.0458 0.75511E-10 -10.1220 0.83914E+00 -0.0762 2 H2O 0.99998E+00 0.0000 0.99998E+00 0.0000 3 Cl- 0.36620E-03 -3.4363 0.30541E-03 -3.5151 0.83401E+00 -0.0788 4 SO4-- 0.10593E-10 -10.9750 0.54709E-11 -11.2619 0.51646E+00 -0.2870 5 HCO3- 0.20446E-04 -4.6894 0.17077E-04 -4.7676 0.83525E+00 -0.0782 6 HS- 0.42278E-03 -3.3739 0.35266E-03 -3.4526 0.83414E+00 -0.0788 7 Al+++ 0.10347E-28 -28.9852 0.23606E-29 -29.6270 0.22815E+00 -0.6418 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14063E-06 -6.8519 0.72087E-07 -7.1421 0.51261E+00 -0.2902 10 Mg++ 0.22002E-10 -10.6575 0.11226E-10 -10.9498 0.51023E+00 -0.2922 11 Fe++ 0.60640E-13 -13.2172 0.30975E-13 -13.5090 0.51079E+00 -0.2918 12 K+ 0.15952E-03 -3.7972 0.13327E-03 -3.8753 0.83545E+00 -0.0781 13 Na+ 0.20243E-01 -1.6937 0.16879E-01 -1.7726 0.83386E+00 -0.0789 14 Mn++ 0.19467E-10 -10.7107 0.99522E-11 -11.0021 0.51122E+00 -0.2914 15 F- 0.11330E-05 -5.9458 0.94293E-06 -6.0255 0.83226E+00 -0.0797 16 HPO4-- 0.43987E-07 -7.3567 0.22721E-07 -7.6436 0.51654E+00 -0.2869 18 HSiO3- 0.10319E-01 -1.9864 0.86062E-02 -2.0652 0.83401E+00 -0.0788 19 Ca(HSiO3)+ 0.16908E-07 -7.7719 0.14129E-07 -7.8499 0.83563E+00 -0.0780 20 Mg(HSiO3)+ 0.32768E-11 -11.4846 0.27382E-11 -11.5625 0.83563E+00 -0.0780 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67399E-16 -16.1713 0.56321E-16 -16.2493 0.83563E+00 -0.0780 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52304E-05 -5.2815 0.43542E-05 -5.3611 0.83248E+00 -0.0796 26 CH4,aq 0.10728E-02 -2.9695 0.10693E-02 -2.9709 0.99670E+00 -0.0014 27 C2H6,aq 0.16933E-10 -10.7713 0.16877E-10 -10.7727 0.99670E+00 -0.0014 28 C3H8,aq 0.61700E-17 -17.2097 0.61496E-17 -17.2112 0.99670E+00 -0.0014 30 ethanol,aq 0.62149E-18 -18.2066 0.61944E-18 -18.2080 0.99670E+00 -0.0014 31 CO,aq 0.80175E-15 -15.0960 0.80175E-15 -15.0960 0.10000E+01 0.0000 32 CO2,aq 0.27646E-08 -8.5584 0.27555E-08 -8.5598 0.99670E+00 -0.0014 33 CO3-2 0.38331E-04 -4.4164 0.19754E-04 -4.7043 0.51535E+00 -0.2879 34 CaCO3,aq 0.17855E-07 -7.7482 0.17855E-07 -7.7482 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.37605E-10 -10.4248 0.31424E-10 -10.5027 0.83563E+00 -0.0780 36 CaCl+ 0.42637E-10 -10.3702 0.35629E-10 -10.4482 0.83563E+00 -0.0780 37 CaCl2,aq 0.25852E-14 -14.5875 0.25852E-14 -14.5875 0.10000E+01 0.0000 38 CaF+ 0.11876E-11 -11.9253 0.99241E-12 -12.0033 0.83563E+00 -0.0780 39 CaOH+ 0.81418E-07 -7.0893 0.68036E-07 -7.1673 0.83563E+00 -0.0780 40 CaSO4,aq 0.12523E-15 -15.9023 0.12523E-15 -15.9023 0.10000E+01 0.0000 41 HCl,aq 0.42260E-14 -14.3741 0.42260E-14 -14.3741 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18606E-18 -18.7303 0.15518E-18 -18.8092 0.83401E+00 -0.0788 48 FeCl+ 0.17919E-16 -16.7467 0.14974E-16 -16.8247 0.83563E+00 -0.0780 51 FeF+ 0.17861E-17 -17.7481 0.14925E-17 -17.8261 0.83563E+00 -0.0780 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15978E-10 -10.7965 0.13352E-10 -10.8744 0.83563E+00 -0.0780 55 HFeO2- 0.35076E-07 -7.4550 0.29254E-07 -7.5338 0.83401E+00 -0.0788 56 FeO+ 0.11199E-16 -16.9508 0.93579E-17 -17.0288 0.83563E+00 -0.0780 58 FeO2- 0.40265E-09 -9.3951 0.33581E-09 -9.4739 0.83401E+00 -0.0788 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11621E-04 -4.9348 0.11582E-04 -4.9362 0.99670E+00 -0.0014 61 KCl,aq 0.73769E-09 -9.1321 0.73769E-09 -9.1321 0.10000E+01 0.0000 63 KOH,aq 0.75369E-06 -6.1228 0.75369E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.13566E-13 -13.8676 0.11314E-13 -13.9464 0.83401E+00 -0.0788 65 MgCO3,aq 0.69697E-12 -12.1568 0.69697E-12 -12.1568 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.59839E-14 -14.2230 0.50003E-14 -14.3010 0.83563E+00 -0.0780 67 MgCl+ 0.60179E-14 -14.2206 0.50287E-14 -14.2985 0.83563E+00 -0.0780 68 MgF+ 0.68509E-15 -15.1643 0.57248E-15 -15.2422 0.83563E+00 -0.0780 69 MgOH+ 0.70159E-10 -10.1539 0.58627E-10 -10.2319 0.83563E+00 -0.0780 71 MnF+ 0.18916E-15 -15.7232 0.15806E-15 -15.8012 0.83563E+00 -0.0780 72 MnO,aq 0.18075E-08 -8.7429 0.18075E-08 -8.7429 0.10000E+01 0.0000 73 MnOH+ 0.47692E-09 -9.3216 0.39853E-09 -9.3995 0.83563E+00 -0.0780 74 MnO2-2 0.20413E-10 -10.6901 0.10520E-10 -10.9780 0.51535E+00 -0.2879 75 HMnO2- 0.20867E-09 -9.6805 0.17404E-09 -9.7594 0.83401E+00 -0.0788 78 MnCl+ 0.22399E-13 -13.6498 0.18717E-13 -13.7278 0.83563E+00 -0.0780 79 MnSO4,aq 0.15719E-19 -19.8036 0.15719E-19 -19.8036 0.10000E+01 0.0000 80 NaCl,aq 0.17084E-05 -5.7674 0.17084E-05 -5.7674 0.10000E+01 0.0000 81 NaF,aq 0.37263E-08 -8.4287 0.37263E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96040E-04 -4.0175 0.96040E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.91910E-02 -2.0366 0.76513E-02 -2.1163 0.83248E+00 -0.0796 89 HPO3-2 0.15914E-14 -14.7982 0.82013E-15 -15.0861 0.51535E+00 -0.2879 91 H2PO3- 0.14890E-18 -18.8271 0.12419E-18 -18.9059 0.83401E+00 -0.0788 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37913E-10 -10.4212 0.31650E-10 -10.4996 0.83481E+00 -0.0784 94 PO4-3 0.10237E-08 -8.9898 0.24550E-09 -9.6099 0.23982E+00 -0.6201 98 HP2O7-3 0.90946E-18 -18.0412 0.20771E-18 -18.6826 0.22838E+00 -0.6413 99 P2O7-4 0.87100E-17 -17.0600 0.65712E-18 -18.1824 0.75444E-01 -1.1224 100 H2S,aq 0.82575E-07 -7.0832 0.82302E-07 -7.0846 0.99670E+00 -0.0014 101 S2-2 0.46168E-12 -12.3357 0.23793E-12 -12.6236 0.51535E+00 -0.2879 107 SO3-2 0.15747E-16 -16.8028 0.82345E-17 -17.0844 0.52293E+00 -0.2816 108 HSO3- 0.46681E-19 -19.3309 0.38932E-19 -19.4097 0.83401E+00 -0.0788 109 HSO4- 0.47596E-18 -18.3224 0.39813E-18 -18.4000 0.83646E+00 -0.0776 111 S2O3-2 0.10264E-19 -19.9887 0.52893E-20 -20.2766 0.51535E+00 -0.2879 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8998674E-10 -.2201858E-01 -.2215407E+02 0.0000 2 H2O 0.1000000E+01 0.5550596E+02 0.9981845E+06 0.0000 3 Cl- 0.3661959E-03 0.3679051E-03 0.1302023E+02 6.6069 4 SO4-- 0.1059295E-10 -.1075743E-02 -.1031544E+03 8.9820 5 HCO3- 0.2044590E-04 0.1131635E-02 0.6892684E+02 5.3544 6 HS- 0.4227827E-03 0.1498608E-02 0.4947413E+02 6.6693 7 Al+++ 0.1034684E-28 0.5230554E-05 0.1408781E+00 0.7390 8 H4SiO4 0.6959645E-03 0.1336448E-01 0.1282255E+04 -3.1574 9 Ca++ 0.1406269E-06 0.2568894E-06 0.1027737E-01 13.1018 10 Mg++ 0.2200170E-10 0.9614752E-10 0.2333396E-05 9.2942 11 Fe++ 0.6064049E-13 0.3570884E-07 0.1990697E-02 6.7350 12 K+ 0.1595180E-03 0.1602724E-03 0.6255865E+01 6.2467 13 Na+ 0.2024266E-01 0.2268991E-01 0.5207121E+03 8.3493 14 Mn++ 0.1946738E-10 0.2532996E-08 0.1389111E-03 9.2419 15 F- 0.1132973E-05 0.1136701E-05 0.2155677E-01 4.0965 16 HPO4-- 0.4398742E-07 0.4504902E-07 0.4316097E-02 12.6004 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279173E+02 -.1093164E-01 -.8278080E+02 0.0000000E+00 2 H2O -.7162575E+01 0.2755725E+02 -.3471982E+02 0.0000000E+00 3 Cl- 0.1826552E-03 0.1826552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386288E+00 -.5340778E-03 0.1391628E+00 0.0000000E+00 5 HCO3- 0.5618270E-03 0.5618270E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1384188E+00 0.7440193E-03 -.1391628E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2596832E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6635109E-02 0.5205727E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1275388E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4773471E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1772849E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7957102E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1126494E-01 0.6265112E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1257566E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3136000E-05 0.5643420E-06 0.2571658E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2236565E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.2140E-13 Mass of aqueous solution: 0.497355E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0075900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.1 andradite 0.5567 -0.254 282.9 2.452 5.179 73.49 grossular 0.1348 -0.870 60.72 1.783 1.112 16.89 apatite-OH 0.9860E-02 -2.006 4.953 0.695 0.9067E-01 1.574 apatite-F 0.2572E-05 -5.590 0.1297E-02 -2.887 0.2374E-04 0.4052E-03 clinochlore 0.7098 -0.149 394.5 2.596 7.223 150.1 daphnite 0.2055 -0.687 146.6 2.166 2.684 44.43 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2482 -0.605 53.75 1.730 0.9840 16.43 hedenbergite 0.6436E-01 -1.191 15.97 1.203 0.2923 4.374 microcline 0.9314 -0.031 259.2 2.414 4.746 101.3 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2602 -0.585 280.5 2.448 5.135 96.89 tr.625ac.25prg.125 0.4721E-01 -1.326 40.36 1.606 0.7388 12.99 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.340265 g Volume = 2210.798799 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0075900 moles log = -2.1198 Original solution: 1000.0103000 g Original solution / Rock added: 131753.66 (Water/Rock Ratio), log = 5.1198 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.6140 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3942E+00 0.9762 0.1006E+01 0.1031E+01 CO2,gas 0.1132E-06 0.9965 0.2948E-06 0.2958E-06 CH4,gas 0.6000E+00 1.0036 0.1574E+01 0.1568E+01 H2,gas 0.5809E-02 1.0014 0.1521E-01 0.1519E-01 H2S,gas 0.8744E-06 0.9899 0.2262E-05 0.2286E-05 S2,gas 0.3179E-27 1.0000 0.8309E-27 0.8309E-27 CO,gas 0.4571E-12 1.0000 0.1195E-11 0.1195E-11 SO3,gas 0.4512E-47 1.0000 0.1180E-46 0.1180E-46 SO2,gas 0.2670E-26 1.0000 0.6978E-26 0.6978E-26 HF,gas 0.4579E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2853E-17 1.0000 0.7457E-17 0.7457E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.72794E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.89 -8.23 -2.743 0.14052E+05 -6.530 3 CH4,gas 4.54 3.04 -1.50 -0.375 0.25646E+04 0.197 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.57 -7.34 -3.672 0.12540E+05 -5.645 6 S2,gas -7.34 -36.11 -28.78 -4.428 0.49140E+05 -27.080 7 CO,gas 3.21 -10.41 -13.62 -4.191 0.23259E+05 -11.923 8 SO3,gas 17.12 -31.51 -48.63 -12.157 0.83030E+05 -46.928 9 SO2,gas 0.83 -27.02 -27.86 -7.428 0.47562E+05 -26.156 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.64 -18.83 -9.413 0.32146E+05 -17.127 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80694E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93628E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.79 -2.75 -0.918 0.47028E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.79 -2.60 -0.867 0.44386E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65544E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.92 -2.82 -0.806 0.48177E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.92 -2.38 -0.679 0.40599E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.90 -3.65 -0.859 0.62326E+04 146 pyrrhotite -4.26 -6.84 -2.58 -0.860 0.44041E+04 147 pyrrhotiteFe0.875 -6.02 -8.24 -2.22 -0.817 0.37913E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.65 -4.67 -1.557 0.79762E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47116E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.84 -2.43 -0.810 0.41469E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.33 -3.35 -1.118 0.57283E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0075900 MOLES New total amount of reactant added: 0.0079900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8656E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0079900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7162E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1076432E-01 Osmotic coef. = 0.9116 True ionic strength = .2045910E-01 Chg. balance for total moles = -.8656E-10 Max. difference allowed = 0.1850E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90058E-10 -10.0455 0.75567E-10 -10.1217 0.83909E+00 -0.0762 2 H2O 0.99998E+00 0.0000 0.99998E+00 0.0000 3 Cl- 0.37092E-03 -3.4307 0.30933E-03 -3.5096 0.83396E+00 -0.0789 4 SO4-- 0.11077E-10 -10.9556 0.57196E-11 -11.2426 0.51634E+00 -0.2871 5 HCO3- 0.21485E-04 -4.6679 0.17944E-04 -4.7461 0.83520E+00 -0.0782 6 HS- 0.44235E-03 -3.3542 0.36896E-03 -3.4330 0.83408E+00 -0.0788 7 Al+++ 0.10375E-28 -28.9840 0.23658E-29 -29.6260 0.22803E+00 -0.6420 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14087E-06 -6.8512 0.72192E-07 -7.1415 0.51249E+00 -0.2903 10 Mg++ 0.22039E-10 -10.6568 0.11242E-10 -10.9491 0.51010E+00 -0.2923 11 Fe++ 0.60744E-13 -13.2165 0.31020E-13 -13.5084 0.51067E+00 -0.2919 12 K+ 0.15964E-03 -3.7968 0.13337E-03 -3.8750 0.83540E+00 -0.0781 13 Na+ 0.20259E-01 -1.6934 0.16892E-01 -1.7723 0.83381E+00 -0.0789 14 Mn++ 0.19501E-10 -10.7099 0.99672E-11 -11.0014 0.51110E+00 -0.2915 15 F- 0.11322E-05 -5.9461 0.94224E-06 -6.0258 0.83221E+00 -0.0798 16 HPO4-- 0.43933E-07 -7.3572 0.22688E-07 -7.6442 0.51642E+00 -0.2870 18 HSiO3- 0.10312E-01 -1.9867 0.85999E-02 -2.0655 0.83396E+00 -0.0789 19 Ca(HSiO3)+ 0.16921E-07 -7.7716 0.14139E-07 -7.8496 0.83559E+00 -0.0780 20 Mg(HSiO3)+ 0.32794E-11 -11.4842 0.27402E-11 -11.5622 0.83559E+00 -0.0780 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67453E-16 -16.1710 0.56362E-16 -16.2490 0.83559E+00 -0.0780 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52269E-05 -5.2818 0.43510E-05 -5.3614 0.83243E+00 -0.0797 26 CH4,aq 0.11281E-02 -2.9477 0.11244E-02 -2.9491 0.99671E+00 -0.0014 27 C2H6,aq 0.18722E-10 -10.7276 0.18661E-10 -10.7291 0.99671E+00 -0.0014 28 C3H8,aq 0.71736E-17 -17.1443 0.71501E-17 -17.1457 0.99671E+00 -0.0014 30 ethanol,aq 0.68718E-18 -18.1629 0.68492E-18 -18.1644 0.99671E+00 -0.0014 31 CO,aq 0.84306E-15 -15.0741 0.84306E-15 -15.0741 0.10000E+01 0.0000 32 CO2,aq 0.29070E-08 -8.5365 0.28975E-08 -8.5380 0.99671E+00 -0.0014 33 CO3-2 0.40257E-04 -4.3952 0.20741E-04 -4.6832 0.51523E+00 -0.2880 34 CaCO3,aq 0.18775E-07 -7.7264 0.18775E-07 -7.7264 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.39574E-10 -10.4026 0.33067E-10 -10.4806 0.83559E+00 -0.0780 36 CaCl+ 0.43250E-10 -10.3640 0.36139E-10 -10.4420 0.83559E+00 -0.0780 37 CaCl2,aq 0.26559E-14 -14.5758 0.26559E-14 -14.5758 0.10000E+01 0.0000 38 CaF+ 0.11886E-11 -11.9250 0.99314E-12 -12.0030 0.83559E+00 -0.0780 39 CaOH+ 0.81482E-07 -7.0889 0.68085E-07 -7.1669 0.83559E+00 -0.0780 40 CaSO4,aq 0.13112E-15 -15.8823 0.13112E-15 -15.8823 0.10000E+01 0.0000 41 HCl,aq 0.42834E-14 -14.3682 0.42834E-14 -14.3682 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18594E-18 -18.7306 0.15506E-18 -18.8095 0.83396E+00 -0.0789 48 FeCl+ 0.18177E-16 -16.7405 0.15188E-16 -16.8185 0.83559E+00 -0.0780 51 FeF+ 0.17875E-17 -17.7477 0.14936E-17 -17.8258 0.83559E+00 -0.0780 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.15991E-10 -10.7961 0.13362E-10 -10.8741 0.83559E+00 -0.0780 55 HFeO2- 0.35052E-07 -7.4553 0.29232E-07 -7.5341 0.83396E+00 -0.0789 56 FeO+ 0.11207E-16 -16.9505 0.93648E-17 -17.0285 0.83559E+00 -0.0780 58 FeO2- 0.40238E-09 -9.3954 0.33557E-09 -9.4742 0.83396E+00 -0.0789 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11620E-04 -4.9348 0.11582E-04 -4.9362 0.99671E+00 -0.0014 61 KCl,aq 0.74771E-09 -9.1263 0.74771E-09 -9.1263 0.10000E+01 0.0000 63 KOH,aq 0.75369E-06 -6.1228 0.75369E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.14193E-13 -13.8479 0.11837E-13 -13.9268 0.83396E+00 -0.0789 65 MgCO3,aq 0.73288E-12 -12.1350 0.73288E-12 -12.1350 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.62972E-14 -14.2009 0.52618E-14 -14.2789 0.83559E+00 -0.0780 67 MgCl+ 0.61044E-14 -14.2144 0.51008E-14 -14.2924 0.83559E+00 -0.0780 68 MgF+ 0.68563E-15 -15.1639 0.57290E-15 -15.2419 0.83559E+00 -0.0780 69 MgOH+ 0.70215E-10 -10.1536 0.58670E-10 -10.2316 0.83559E+00 -0.0780 71 MnF+ 0.18931E-15 -15.7228 0.15819E-15 -15.8008 0.83559E+00 -0.0780 72 MnO,aq 0.18076E-08 -8.7429 0.18076E-08 -8.7429 0.10000E+01 0.0000 73 MnOH+ 0.47732E-09 -9.3212 0.39884E-09 -9.3992 0.83559E+00 -0.0780 74 MnO2-2 0.20389E-10 -10.6906 0.10505E-10 -10.9786 0.51523E+00 -0.2880 75 HMnO2- 0.20854E-09 -9.6808 0.17392E-09 -9.7597 0.83396E+00 -0.0789 78 MnCl+ 0.22722E-13 -13.6436 0.18986E-13 -13.7216 0.83559E+00 -0.0780 79 MnSO4,aq 0.16458E-19 -19.7836 0.16458E-19 -19.7836 0.10000E+01 0.0000 80 NaCl,aq 0.17316E-05 -5.7615 0.17316E-05 -5.7615 0.10000E+01 0.0000 81 NaF,aq 0.37263E-08 -8.4287 0.37263E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96039E-04 -4.0176 0.96039E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91848E-02 -2.0369 0.76457E-02 -2.1166 0.83243E+00 -0.0797 89 HPO3-2 0.15894E-14 -14.7988 0.81893E-15 -15.0868 0.51523E+00 -0.2880 91 H2PO3- 0.14880E-18 -18.8274 0.12410E-18 -18.9062 0.83396E+00 -0.0789 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37887E-10 -10.4215 0.31627E-10 -10.4999 0.83476E+00 -0.0784 94 PO4-3 0.10220E-08 -8.9906 0.24496E-09 -9.6109 0.23970E+00 -0.6203 98 HP2O7-3 0.90795E-18 -18.0419 0.20725E-18 -18.6835 0.22826E+00 -0.6416 99 P2O7-4 0.86926E-17 -17.0609 0.65520E-18 -18.1836 0.75375E-01 -1.1228 100 H2S,aq 0.86453E-07 -7.0632 0.86169E-07 -7.0646 0.99671E+00 -0.0014 101 S2-2 0.50546E-12 -12.2963 0.26043E-12 -12.5843 0.51523E+00 -0.2880 107 SO3-2 0.16466E-16 -16.7834 0.86088E-17 -17.0651 0.52281E+00 -0.2817 108 HSO3- 0.48841E-19 -19.3112 0.40732E-19 -19.3901 0.83396E+00 -0.0789 109 HSO4- 0.49799E-18 -18.3028 0.41653E-18 -18.3804 0.83641E+00 -0.0776 111 S2O3-2 0.11237E-19 -19.9494 0.57896E-20 -20.2374 0.51523E+00 -0.2880 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9005762E-10 -.2200740E-01 -.2214279E+02 0.0000 2 H2O 0.1000000E+01 0.5550602E+02 0.9981839E+06 0.0000 3 Cl- 0.3709207E-03 0.3726532E-03 0.1318824E+02 6.6121 4 SO4-- 0.1107704E-10 -.1131010E-02 -.1084539E+03 9.0007 5 HCO3- 0.2148499E-04 0.1189869E-02 0.7247367E+02 5.3756 6 HS- 0.4423504E-03 0.1573447E-02 0.5194474E+02 6.6886 7 Al+++ 0.1037510E-28 0.5227056E-05 0.1407836E+00 0.7390 8 H4SiO4 0.6959637E-03 0.1335755E-01 0.1281589E+04 -3.1574 9 Ca++ 0.1408662E-06 0.2581290E-06 0.1032694E-01 13.1018 10 Mg++ 0.2203920E-10 0.9627938E-10 0.2336592E-05 9.2942 11 Fe++ 0.6074387E-13 0.3568502E-07 0.1989366E-02 6.7350 12 K+ 0.1596436E-03 0.1603981E-03 0.6260760E+01 6.2467 13 Na+ 0.2025863E-01 0.2270590E-01 0.5210782E+03 8.3493 14 Mn++ 0.1950131E-10 0.2533339E-08 0.1389297E-03 9.2419 15 F- 0.1132214E-05 0.1135942E-05 0.2154234E-01 4.0958 16 HPO4-- 0.4393336E-07 0.4499320E-07 0.4310743E-02 12.5991 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279169E+02 -.1092625E-01 -.8278076E+02 0.0000000E+00 2 H2O -.7162247E+01 0.2755768E+02 -.3471993E+02 0.0000000E+00 3 Cl- 0.1850152E-03 0.1850152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386307E+00 -.5615249E-03 0.1391922E+00 0.0000000E+00 5 HCO3- 0.5907470E-03 0.5907470E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1384110E+00 0.7811864E-03 -.1391922E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2595133E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6631767E-02 0.5205727E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1281561E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4780087E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1771693E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7963457E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1127305E-01 0.6265104E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1257754E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3296000E-05 0.5639734E-06 0.2732027E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2233826E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.6592E-14 Mass of aqueous solution: 0.497363E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0079900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.0 andradite 0.5568 -0.254 282.9 2.452 5.180 73.51 grossular 0.1348 -0.870 60.73 1.783 1.112 16.90 apatite-OH 0.9860E-02 -2.006 4.953 0.695 0.9067E-01 1.574 apatite-F 0.2732E-05 -5.564 0.1378E-02 -2.861 0.2522E-04 0.4304E-03 clinochlore 0.7098 -0.149 394.5 2.596 7.222 150.1 daphnite 0.2055 -0.687 146.6 2.166 2.684 44.43 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2474 -0.607 53.58 1.729 0.9809 16.38 hedenbergite 0.6417E-01 -1.193 15.92 1.202 0.2914 4.360 microcline 0.9314 -0.031 259.3 2.414 4.746 101.3 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2601 -0.585 280.4 2.448 5.134 96.86 tr.625ac.25prg.125 0.4746E-01 -1.324 40.57 1.608 0.7427 13.06 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.340389 g Volume = 2210.799903 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0079900 moles log = -2.0975 Original solution: 1000.0103000 g Original solution / Rock added: 125157.73 (Water/Rock Ratio), log = 5.0975 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.6954 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3824E+00 0.9759 0.1006E+01 0.1031E+01 CO2,gas 0.1154E-06 0.9962 0.3100E-06 0.3112E-06 CH4,gas 0.6119E+00 1.0034 0.1655E+01 0.1649E+01 H2,gas 0.5634E-02 1.0014 0.1521E-01 0.1518E-01 H2S,gas 0.8881E-06 0.9896 0.2369E-05 0.2394E-05 S2,gas 0.3379E-27 1.0000 0.9108E-27 0.9108E-27 CO,gas 0.4661E-12 1.0000 0.1256E-11 0.1256E-11 SO3,gas 0.4582E-47 1.0000 0.1235E-46 0.1235E-46 SO2,gas 0.2711E-26 1.0000 0.7306E-26 0.7306E-26 HF,gas 0.4440E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2804E-17 1.0000 0.7558E-17 0.7558E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.87 -8.21 -2.736 0.14014E+05 -6.509 3 CH4,gas 4.54 3.06 -1.48 -0.370 0.25273E+04 0.219 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.55 -7.32 -3.662 0.12506E+05 -5.625 6 S2,gas -7.34 -36.08 -28.74 -4.421 0.49072E+05 -27.041 7 CO,gas 3.21 -10.38 -13.60 -4.185 0.23221E+05 -11.901 8 SO3,gas 17.12 -31.49 -48.61 -12.152 0.82996E+05 -46.908 9 SO2,gas 0.83 -27.00 -27.84 -7.423 0.47528E+05 -26.136 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.63 -18.82 -9.410 0.32136E+05 -17.122 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80693E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93628E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.77 -2.73 -0.911 0.46656E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.77 -2.58 -0.859 0.44013E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65543E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.90 -2.80 -0.800 0.47804E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.90 -2.36 -0.673 0.40227E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82236E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.86 -3.61 -0.849 0.61645E+04 146 pyrrhotite -4.26 -6.82 -2.56 -0.853 0.43701E+04 147 pyrrhotiteFe0.875 -6.02 -8.22 -2.20 -0.809 0.37573E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.63 -4.65 -1.550 0.79389E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23242E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47116E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90677E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.82 -2.41 -0.803 0.41129E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60609E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.31 -3.33 -1.112 0.56943E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0079900 MOLES New total amount of reactant added: 0.0083900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8656E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0083900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7162E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1073072E-01 Osmotic coef. = 0.9122 True ionic strength = .2047712E-01 Chg. balance for total moles = -.8656E-10 Max. difference allowed = 0.1874E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90129E-10 -10.0451 0.75622E-10 -10.1214 0.83905E+00 -0.0762 2 H2O 0.99998E+00 0.0000 0.99998E+00 0.0000 3 Cl- 0.37565E-03 -3.4252 0.31325E-03 -3.5041 0.83391E+00 -0.0789 4 SO4-- 0.11561E-10 -10.9370 0.59678E-11 -11.2242 0.51622E+00 -0.2872 5 HCO3- 0.22523E-04 -4.6474 0.18810E-04 -4.7256 0.83515E+00 -0.0782 6 HS- 0.46192E-03 -3.3354 0.38526E-03 -3.4143 0.83403E+00 -0.0788 7 Al+++ 0.10403E-28 -28.9828 0.23710E-29 -29.6251 0.22791E+00 -0.6422 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14111E-06 -6.8505 0.72298E-07 -7.1409 0.51237E+00 -0.2904 10 Mg++ 0.22077E-10 -10.6561 0.11259E-10 -10.9485 0.50998E+00 -0.2924 11 Fe++ 0.60847E-13 -13.2158 0.31066E-13 -13.5077 0.51055E+00 -0.2920 12 K+ 0.15977E-03 -3.7965 0.13346E-03 -3.8746 0.83535E+00 -0.0781 13 Na+ 0.20275E-01 -1.6930 0.16904E-01 -1.7720 0.83376E+00 -0.0790 14 Mn++ 0.19535E-10 -10.7092 0.99821E-11 -11.0008 0.51098E+00 -0.2916 15 F- 0.11315E-05 -5.9464 0.94155E-06 -6.0262 0.83216E+00 -0.0798 16 HPO4-- 0.43879E-07 -7.3577 0.22655E-07 -7.6448 0.51630E+00 -0.2871 18 HSiO3- 0.10305E-01 -1.9869 0.85936E-02 -2.0658 0.83391E+00 -0.0789 19 Ca(HSiO3)+ 0.16934E-07 -7.7712 0.14149E-07 -7.8493 0.83554E+00 -0.0780 20 Mg(HSiO3)+ 0.32820E-11 -11.4839 0.27422E-11 -11.5619 0.83554E+00 -0.0780 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67506E-16 -16.1707 0.56404E-16 -16.2487 0.83554E+00 -0.0780 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52234E-05 -5.2820 0.43479E-05 -5.3617 0.83238E+00 -0.0797 26 CH4,aq 0.11834E-02 -2.9269 0.11795E-02 -2.9283 0.99672E+00 -0.0014 27 C2H6,aq 0.20602E-10 -10.6861 0.20535E-10 -10.6875 0.99672E+00 -0.0014 28 C3H8,aq 0.82807E-17 -17.0819 0.82536E-17 -17.0834 0.99672E+00 -0.0014 30 ethanol,aq 0.75617E-18 -18.1214 0.75369E-18 -18.1228 0.99672E+00 -0.0014 31 CO,aq 0.88438E-15 -15.0534 0.88438E-15 -15.0534 0.10000E+01 0.0000 32 CO2,aq 0.30495E-08 -8.5158 0.30395E-08 -8.5172 0.99672E+00 -0.0014 33 CO3-2 0.42178E-04 -4.3749 0.21726E-04 -4.6630 0.51511E+00 -0.2881 34 CaCO3,aq 0.19696E-07 -7.7056 0.19696E-07 -7.7056 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.41546E-10 -10.3815 0.34713E-10 -10.4595 0.83554E+00 -0.0780 36 CaCl+ 0.43865E-10 -10.3579 0.36651E-10 -10.4359 0.83554E+00 -0.0780 37 CaCl2,aq 0.27277E-14 -14.5642 0.27277E-14 -14.5642 0.10000E+01 0.0000 38 CaF+ 0.11895E-11 -11.9246 0.99386E-12 -12.0027 0.83554E+00 -0.0780 39 CaOH+ 0.81547E-07 -7.0886 0.68135E-07 -7.1666 0.83554E+00 -0.0780 40 CaSO4,aq 0.13701E-15 -15.8633 0.13701E-15 -15.8633 0.10000E+01 0.0000 41 HCl,aq 0.43409E-14 -14.3624 0.43409E-14 -14.3624 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18581E-18 -18.7309 0.15495E-18 -18.8098 0.83391E+00 -0.0789 48 FeCl+ 0.18435E-16 -16.7344 0.15403E-16 -16.8124 0.83554E+00 -0.0780 51 FeF+ 0.17889E-17 -17.7474 0.14947E-17 -17.8254 0.83554E+00 -0.0780 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16004E-10 -10.7958 0.13372E-10 -10.8738 0.83554E+00 -0.0780 55 HFeO2- 0.35029E-07 -7.4556 0.29211E-07 -7.5345 0.83391E+00 -0.0789 56 FeO+ 0.11216E-16 -16.9502 0.93716E-17 -17.0282 0.83554E+00 -0.0780 58 FeO2- 0.40211E-09 -9.3957 0.33532E-09 -9.4745 0.83391E+00 -0.0789 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11620E-04 -4.9348 0.11582E-04 -4.9362 0.99672E+00 -0.0014 61 KCl,aq 0.75774E-09 -9.1205 0.75774E-09 -9.1205 0.10000E+01 0.0000 63 KOH,aq 0.75369E-06 -6.1228 0.75369E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.14821E-13 -13.8291 0.12360E-13 -13.9080 0.83391E+00 -0.0789 65 MgCO3,aq 0.76879E-12 -12.1142 0.76879E-12 -12.1142 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.66110E-14 -14.1797 0.55237E-14 -14.2578 0.83554E+00 -0.0780 67 MgCl+ 0.61912E-14 -14.2082 0.51730E-14 -14.2863 0.83554E+00 -0.0780 68 MgF+ 0.68617E-15 -15.1636 0.57332E-15 -15.2416 0.83554E+00 -0.0780 69 MgOH+ 0.70270E-10 -10.1532 0.58713E-10 -10.2313 0.83554E+00 -0.0780 71 MnF+ 0.18947E-15 -15.7225 0.15831E-15 -15.8005 0.83554E+00 -0.0780 72 MnO,aq 0.18076E-08 -8.7429 0.18076E-08 -8.7429 0.10000E+01 0.0000 73 MnOH+ 0.47771E-09 -9.3208 0.39915E-09 -9.3989 0.83554E+00 -0.0780 74 MnO2-2 0.20365E-10 -10.6911 0.10490E-10 -10.9792 0.51511E+00 -0.2881 75 HMnO2- 0.20841E-09 -9.6811 0.17379E-09 -9.7600 0.83391E+00 -0.0789 78 MnCl+ 0.23046E-13 -13.6374 0.19256E-13 -13.7154 0.83554E+00 -0.0780 79 MnSO4,aq 0.17198E-19 -19.7645 0.17198E-19 -19.7645 0.10000E+01 0.0000 80 NaCl,aq 0.17549E-05 -5.7558 0.17549E-05 -5.7558 0.10000E+01 0.0000 81 NaF,aq 0.37262E-08 -8.4287 0.37262E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96039E-04 -4.0176 0.96039E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91787E-02 -2.0372 0.76401E-02 -2.1169 0.83238E+00 -0.0797 89 HPO3-2 0.15875E-14 -14.7993 0.81773E-15 -15.0874 0.51511E+00 -0.2881 91 H2PO3- 0.14870E-18 -18.8277 0.12400E-18 -18.9066 0.83391E+00 -0.0789 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37862E-10 -10.4218 0.31604E-10 -10.5003 0.83471E+00 -0.0785 94 PO4-3 0.10202E-08 -8.9913 0.24443E-09 -9.6119 0.23958E+00 -0.6205 98 HP2O7-3 0.90644E-18 -18.0427 0.20680E-18 -18.6845 0.22814E+00 -0.6418 99 P2O7-4 0.86752E-17 -17.0617 0.65329E-18 -18.1849 0.75305E-01 -1.1232 100 H2S,aq 0.90337E-07 -7.0441 0.90041E-07 -7.0456 0.99672E+00 -0.0014 101 S2-2 0.55123E-12 -12.2587 0.28394E-12 -12.5468 0.51511E+00 -0.2881 107 SO3-2 0.17185E-16 -16.7649 0.89825E-17 -17.0466 0.52269E+00 -0.2818 108 HSO3- 0.51002E-19 -19.2924 0.42531E-19 -19.3713 0.83391E+00 -0.0789 109 HSO4- 0.52002E-18 -18.2840 0.43493E-18 -18.3616 0.83636E+00 -0.0776 111 S2O3-2 0.12254E-19 -19.9117 0.63123E-20 -20.1998 0.51511E+00 -0.2881 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9012851E-10 -.2199623E-01 -.2213152E+02 0.0000 2 H2O 0.1000000E+01 0.5550608E+02 0.9981833E+06 0.0000 3 Cl- 0.3756454E-03 0.3774011E-03 0.1335625E+02 6.6172 4 SO4-- 0.1156056E-10 -.1186282E-02 -.1137538E+03 9.0185 5 HCO3- 0.2252277E-04 0.1248100E-02 0.7602037E+02 5.3957 6 HS- 0.4619176E-03 0.1648290E-02 0.5441546E+02 6.7071 7 Al+++ 0.1040341E-28 0.5223561E-05 0.1406893E+00 0.7390 8 H4SiO4 0.6959629E-03 0.1335063E-01 0.1280923E+04 -3.1574 9 Ca++ 0.1411057E-06 0.2593689E-06 0.1037653E-01 13.1018 10 Mg++ 0.2207675E-10 0.9641214E-10 0.2339810E-05 9.2942 11 Fe++ 0.6084737E-13 0.3566123E-07 0.1988037E-02 6.7350 12 K+ 0.1597693E-03 0.1605237E-03 0.6265655E+01 6.2467 13 Na+ 0.2027461E-01 0.2272189E-01 0.5214443E+03 8.3493 14 Mn++ 0.1953528E-10 0.2533681E-08 0.1389483E-03 9.2419 15 F- 0.1131455E-05 0.1135183E-05 0.2152793E-01 4.0952 16 HPO4-- 0.4387939E-07 0.4493748E-07 0.4305397E-02 12.5979 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279164E+02 -.1092087E-01 -.8278072E+02 0.0000000E+00 2 H2O -.7161920E+01 0.2755811E+02 -.3472003E+02 0.0000000E+00 3 Cl- 0.1873752E-03 0.1873752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386326E+00 -.5889749E-03 0.1392216E+00 0.0000000E+00 5 HCO3- 0.6196670E-03 0.6196670E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1384032E+00 0.8183564E-03 -.1392216E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2593436E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6628428E-02 0.5205728E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1287736E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4786749E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1770538E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7969814E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1128115E-01 0.6265096E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1257943E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3456000E-05 0.5636052E-06 0.2892395E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2231093E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.9950E-14 Mass of aqueous solution: 0.497371E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0083900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.0 andradite 0.5569 -0.254 283.0 2.452 5.181 73.53 grossular 0.1348 -0.870 60.74 1.783 1.112 16.90 apatite-OH 0.9860E-02 -2.006 4.953 0.695 0.9067E-01 1.574 apatite-F 0.2892E-05 -5.539 0.1459E-02 -2.836 0.2670E-04 0.4557E-03 clinochlore 0.7097 -0.149 394.5 2.596 7.222 150.1 daphnite 0.2055 -0.687 146.6 2.166 2.684 44.42 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2467 -0.608 53.42 1.728 0.9779 16.32 hedenbergite 0.6397E-01 -1.194 15.87 1.201 0.2905 4.347 microcline 0.9315 -0.031 259.3 2.414 4.746 101.3 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2601 -0.585 280.3 2.448 5.132 96.84 tr.625ac.25prg.125 0.4771E-01 -1.321 40.78 1.610 0.7466 13.13 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.340512 g Volume = 2210.801006 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0083900 moles log = -2.0762 Original solution: 1000.0103000 g Original solution / Rock added: 119190.74 (Water/Rock Ratio), log = 5.0762 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.7768 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3713E+00 0.9757 0.1006E+01 0.1031E+01 CO2,gas 0.1176E-06 0.9960 0.3252E-06 0.3265E-06 CH4,gas 0.6232E+00 1.0032 0.1736E+01 0.1731E+01 H2,gas 0.5468E-02 1.0015 0.1521E-01 0.1518E-01 H2S,gas 0.9011E-06 0.9893 0.2475E-05 0.2502E-05 S2,gas 0.3582E-27 1.0000 0.9945E-27 0.9945E-27 CO,gas 0.4746E-12 1.0000 0.1318E-11 0.1318E-11 SO3,gas 0.4647E-47 1.0000 0.1290E-46 0.1290E-46 SO2,gas 0.2749E-26 1.0000 0.7634E-26 0.7634E-26 HF,gas 0.4310E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2758E-17 1.0000 0.7660E-17 0.7660E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.18198E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.85 -8.19 -2.729 0.13979E+05 -6.488 3 CH4,gas 4.54 3.08 -1.46 -0.365 0.24919E+04 0.240 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.54 -7.31 -3.653 0.12474E+05 -5.606 6 S2,gas -7.34 -36.04 -28.70 -4.416 0.49007E+05 -27.002 7 CO,gas 3.21 -10.36 -13.58 -4.178 0.23186E+05 -11.880 8 SO3,gas 17.12 -31.47 -48.59 -12.147 0.82963E+05 -46.889 9 SO2,gas 0.83 -26.98 -27.82 -7.418 0.47495E+05 -26.117 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.63 -18.81 -9.407 0.32126E+05 -17.116 12 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80692E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93628E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.75 -2.71 -0.904 0.46301E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.75 -2.56 -0.852 0.43659E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65543E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.88 -2.78 -0.794 0.47449E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.88 -2.34 -0.667 0.39872E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.82 -3.57 -0.840 0.60993E+04 146 pyrrhotite -4.26 -6.80 -2.54 -0.847 0.43375E+04 147 pyrrhotiteFe0.875 -6.02 -8.20 -2.18 -0.802 0.37247E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.61 -4.63 -1.543 0.79034E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47115E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.80 -2.39 -0.797 0.40803E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.29 -3.32 -1.105 0.56616E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0083900 MOLES New total amount of reactant added: 0.0087900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8656E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0087900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7162E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1069711E-01 Osmotic coef. = 0.9127 True ionic strength = .2049515E-01 Chg. balance for total moles = -.8656E-10 Max. difference allowed = 0.1897E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90199E-10 -10.0448 0.75677E-10 -10.1210 0.83900E+00 -0.0762 2 H2O 0.99998E+00 0.0000 0.99998E+00 0.0000 3 Cl- 0.38037E-03 -3.4198 0.31718E-03 -3.4987 0.83386E+00 -0.0789 4 SO4-- 0.12044E-10 -10.9192 0.62157E-11 -11.2065 0.51610E+00 -0.2873 5 HCO3- 0.23559E-04 -4.6278 0.19674E-04 -4.7061 0.83510E+00 -0.0783 6 HS- 0.48148E-03 -3.3174 0.40155E-03 -3.3963 0.83398E+00 -0.0788 7 Al+++ 0.10432E-28 -28.9816 0.23762E-29 -29.6241 0.22779E+00 -0.6425 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14135E-06 -6.8497 0.72403E-07 -7.1402 0.51224E+00 -0.2905 10 Mg++ 0.22114E-10 -10.6553 0.11275E-10 -10.9479 0.50986E+00 -0.2926 11 Fe++ 0.60951E-13 -13.2150 0.31111E-13 -13.5071 0.51043E+00 -0.2921 12 K+ 0.15990E-03 -3.7962 0.13356E-03 -3.8743 0.83530E+00 -0.0782 13 Na+ 0.20291E-01 -1.6927 0.16916E-01 -1.7717 0.83371E+00 -0.0790 14 Mn++ 0.19569E-10 -10.7084 0.99971E-11 -11.0001 0.51086E+00 -0.2917 15 F- 0.11307E-05 -5.9467 0.94087E-06 -6.0265 0.83211E+00 -0.0798 16 HPO4-- 0.43826E-07 -7.3583 0.22622E-07 -7.6455 0.51618E+00 -0.2872 18 HSiO3- 0.10298E-01 -1.9872 0.85873E-02 -2.0661 0.83386E+00 -0.0789 19 Ca(HSiO3)+ 0.16948E-07 -7.7709 0.14160E-07 -7.8489 0.83549E+00 -0.0781 20 Mg(HSiO3)+ 0.32845E-11 -11.4835 0.27442E-11 -11.5616 0.83549E+00 -0.0781 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67559E-16 -16.1703 0.56445E-16 -16.2484 0.83549E+00 -0.0781 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52199E-05 -5.2823 0.43447E-05 -5.3620 0.83233E+00 -0.0797 26 CH4,aq 0.12387E-02 -2.9071 0.12346E-02 -2.9085 0.99673E+00 -0.0014 27 C2H6,aq 0.22572E-10 -10.6464 0.22498E-10 -10.6479 0.99673E+00 -0.0014 28 C3H8,aq 0.94964E-17 -17.0224 0.94654E-17 -17.0239 0.99673E+00 -0.0014 30 ethanol,aq 0.82847E-18 -18.0817 0.82577E-18 -18.0831 0.99673E+00 -0.0014 31 CO,aq 0.92570E-15 -15.0335 0.92570E-15 -15.0335 0.10000E+01 0.0000 32 CO2,aq 0.31919E-08 -8.4959 0.31815E-08 -8.4974 0.99673E+00 -0.0014 33 CO3-2 0.44094E-04 -4.3556 0.22708E-04 -4.6438 0.51499E+00 -0.2882 34 CaCO3,aq 0.20616E-07 -7.6858 0.20616E-07 -7.6858 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.43522E-10 -10.3613 0.36362E-10 -10.4394 0.83549E+00 -0.0781 36 CaCl+ 0.44482E-10 -10.3518 0.37164E-10 -10.4299 0.83549E+00 -0.0781 37 CaCl2,aq 0.28005E-14 -14.5528 0.28005E-14 -14.5528 0.10000E+01 0.0000 38 CaF+ 0.11904E-11 -11.9243 0.99459E-12 -12.0024 0.83549E+00 -0.0781 39 CaOH+ 0.81611E-07 -7.0883 0.68185E-07 -7.1663 0.83549E+00 -0.0781 40 CaSO4,aq 0.14291E-15 -15.8449 0.14291E-15 -15.8449 0.10000E+01 0.0000 41 HCl,aq 0.43984E-14 -14.3567 0.43984E-14 -14.3567 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18569E-18 -18.7312 0.15484E-18 -18.8101 0.83386E+00 -0.0789 48 FeCl+ 0.18694E-16 -16.7283 0.15619E-16 -16.8064 0.83549E+00 -0.0781 51 FeF+ 0.17903E-17 -17.7471 0.14958E-17 -17.8251 0.83549E+00 -0.0781 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16016E-10 -10.7954 0.13381E-10 -10.8735 0.83549E+00 -0.0781 55 HFeO2- 0.35005E-07 -7.4559 0.29189E-07 -7.5348 0.83386E+00 -0.0789 56 FeO+ 0.11225E-16 -16.9498 0.93785E-17 -17.0279 0.83549E+00 -0.0781 58 FeO2- 0.40184E-09 -9.3960 0.33508E-09 -9.4749 0.83386E+00 -0.0789 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11620E-04 -4.9348 0.11582E-04 -4.9362 0.99673E+00 -0.0014 61 KCl,aq 0.76778E-09 -9.1148 0.76778E-09 -9.1148 0.10000E+01 0.0000 63 KOH,aq 0.75369E-06 -6.1228 0.75369E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.15449E-13 -13.8111 0.12882E-13 -13.8900 0.83386E+00 -0.0789 65 MgCO3,aq 0.80471E-12 -12.0944 0.80471E-12 -12.0944 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.69253E-14 -14.1596 0.57860E-14 -14.2376 0.83549E+00 -0.0781 67 MgCl+ 0.62782E-14 -14.2022 0.52454E-14 -14.2802 0.83549E+00 -0.0781 68 MgF+ 0.68671E-15 -15.1632 0.57374E-15 -15.2413 0.83549E+00 -0.0781 69 MgOH+ 0.70325E-10 -10.1529 0.58756E-10 -10.2309 0.83549E+00 -0.0781 71 MnF+ 0.18963E-15 -15.7221 0.15843E-15 -15.8002 0.83549E+00 -0.0781 72 MnO,aq 0.18077E-08 -8.7429 0.18077E-08 -8.7429 0.10000E+01 0.0000 73 MnOH+ 0.47811E-09 -9.3205 0.39945E-09 -9.3985 0.83549E+00 -0.0781 74 MnO2-2 0.20340E-10 -10.6916 0.10475E-10 -10.9798 0.51499E+00 -0.2882 75 HMnO2- 0.20828E-09 -9.6814 0.17367E-09 -9.7603 0.83386E+00 -0.0789 78 MnCl+ 0.23371E-13 -13.6313 0.19526E-13 -13.7094 0.83549E+00 -0.0781 79 MnSO4,aq 0.17939E-19 -19.7462 0.17939E-19 -19.7462 0.10000E+01 0.0000 80 NaCl,aq 0.17781E-05 -5.7500 0.17781E-05 -5.7500 0.10000E+01 0.0000 81 NaF,aq 0.37262E-08 -8.4287 0.37262E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96039E-04 -4.0176 0.96039E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91725E-02 -2.0375 0.76345E-02 -2.1172 0.83233E+00 -0.0797 89 HPO3-2 0.15855E-14 -14.7998 0.81654E-15 -15.0880 0.51499E+00 -0.2882 91 H2PO3- 0.14860E-18 -18.8280 0.12391E-18 -18.9069 0.83386E+00 -0.0789 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37837E-10 -10.4221 0.31581E-10 -10.5006 0.83466E+00 -0.0785 94 PO4-3 0.10185E-08 -8.9920 0.24389E-09 -9.6128 0.23946E+00 -0.6208 98 HP2O7-3 0.90494E-18 -18.0434 0.20635E-18 -18.6854 0.22802E+00 -0.6420 99 P2O7-4 0.86579E-17 -17.0626 0.65139E-18 -18.1862 0.75236E-01 -1.1236 100 H2S,aq 0.94226E-07 -7.0258 0.93918E-07 -7.0272 0.99673E+00 -0.0014 101 S2-2 0.59899E-12 -12.2226 0.30847E-12 -12.5108 0.51499E+00 -0.2882 107 SO3-2 0.17903E-16 -16.7471 0.93556E-17 -17.0289 0.52258E+00 -0.2819 108 HSO3- 0.53162E-19 -19.2744 0.44330E-19 -19.3533 0.83386E+00 -0.0789 109 HSO4- 0.54205E-18 -18.2660 0.45332E-18 -18.3436 0.83632E+00 -0.0776 111 S2O3-2 0.13316E-19 -19.8756 0.68576E-20 -20.1638 0.51499E+00 -0.2882 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9019942E-10 -.2198507E-01 -.2212025E+02 0.0000 2 H2O 0.1000000E+01 0.5550613E+02 0.9981827E+06 0.0000 3 Cl- 0.3803699E-03 0.3821489E-03 0.1352425E+02 6.6223 4 SO4-- 0.1204354E-10 -.1241558E-02 -.1190541E+03 9.0356 5 HCO3- 0.2355927E-04 0.1306330E-02 0.7956696E+02 5.4149 6 HS- 0.4814841E-03 0.1723136E-02 0.5688629E+02 6.7248 7 Al+++ 0.1043179E-28 0.5220071E-05 0.1405951E+00 0.7390 8 H4SiO4 0.6959622E-03 0.1334371E-01 0.1280257E+04 -3.1574 9 Ca++ 0.1413456E-06 0.2606093E-06 0.1042614E-01 13.1018 10 Mg++ 0.2211435E-10 0.9654399E-10 0.2343007E-05 9.2942 11 Fe++ 0.6095099E-13 0.3563747E-07 0.1986709E-02 6.7350 12 K+ 0.1598950E-03 0.1606495E-03 0.6270552E+01 6.2467 13 Na+ 0.2029059E-01 0.2273789E-01 0.5218105E+03 8.3493 14 Mn++ 0.1956929E-10 0.2534025E-08 0.1389669E-03 9.2419 15 F- 0.1130698E-05 0.1134426E-05 0.2151353E-01 4.0946 16 HPO4-- 0.4382552E-07 0.4488185E-07 0.4300061E-02 12.5966 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279160E+02 -.1091549E-01 -.8278069E+02 0.0000000E+00 2 H2O -.7161592E+01 0.2755854E+02 -.3472014E+02 0.0000000E+00 3 Cl- 0.1897352E-03 0.1897352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386345E+00 -.6164278E-03 0.1392509E+00 0.0000000E+00 5 HCO3- 0.6485870E-03 0.6485870E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383954E+00 0.8555293E-03 -.1392509E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2591742E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6625094E-02 0.5205728E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1293913E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4793366E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1769384E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7976173E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1128926E-01 0.6265088E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1258132E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3616000E-05 0.5632374E-06 0.3052763E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2228364E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.2900E-14 Mass of aqueous solution: 0.497379E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0087900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.0 andradite 0.5570 -0.254 283.1 2.452 5.182 73.54 grossular 0.1349 -0.870 60.75 1.784 1.112 16.90 apatite-OH 0.9860E-02 -2.006 4.953 0.695 0.9067E-01 1.574 apatite-F 0.3053E-05 -5.515 0.1540E-02 -2.813 0.2818E-04 0.4810E-03 clinochlore 0.7097 -0.149 394.5 2.596 7.222 150.0 daphnite 0.2055 -0.687 146.6 2.166 2.684 44.42 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2459 -0.609 53.25 1.726 0.9748 16.27 hedenbergite 0.6377E-01 -1.195 15.82 1.199 0.2896 4.333 microcline 0.9315 -0.031 259.3 2.414 4.747 101.3 stilbite 3.220 0.508 2269. 3.356 41.55 1058. stilpnomelane-Fe 0.2600 -0.585 280.3 2.448 5.131 96.82 tr.625ac.25prg.125 0.4796E-01 -1.319 41.00 1.613 0.7505 13.20 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.340635 g Volume = 2210.802109 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0087900 moles log = -2.0560 Original solution: 1000.0103000 g Original solution / Rock added: 113766.81 (Water/Rock Ratio), log = 5.0560 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.8582 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3608E+00 0.9755 0.1006E+01 0.1031E+01 CO2,gas 0.1196E-06 0.9957 0.3404E-06 0.3419E-06 CH4,gas 0.6339E+00 1.0030 0.1817E+01 0.1812E+01 H2,gas 0.5312E-02 1.0015 0.1521E-01 0.1518E-01 H2S,gas 0.9134E-06 0.9890 0.2582E-05 0.2611E-05 S2,gas 0.3786E-27 1.0000 0.1082E-26 0.1082E-26 CO,gas 0.4826E-12 1.0000 0.1379E-11 0.1379E-11 SO3,gas 0.4709E-47 1.0000 0.1346E-46 0.1346E-46 SO2,gas 0.2786E-26 1.0000 0.7963E-26 0.7963E-26 HF,gas 0.4187E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2715E-17 1.0000 0.7761E-17 0.7761E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.36397E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.18198E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.72794E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.83 -8.17 -2.722 0.13945E+05 -6.468 3 CH4,gas 4.54 3.10 -1.44 -0.360 0.24580E+04 0.259 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.52 -7.29 -3.644 0.12442E+05 -5.588 6 S2,gas -7.34 -36.00 -28.66 -4.410 0.48944E+05 -26.966 7 CO,gas 3.21 -10.34 -13.56 -4.172 0.23152E+05 -11.860 8 SO3,gas 17.12 -31.45 -48.57 -12.142 0.82932E+05 -46.871 9 SO2,gas 0.83 -26.97 -27.80 -7.413 0.47464E+05 -26.099 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.62 -18.81 -9.405 0.32116E+05 -17.110 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80691E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93628E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.73 -2.69 -0.897 0.45962E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.73 -2.54 -0.846 0.43320E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65543E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.86 -2.76 -0.788 0.47111E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.86 -2.32 -0.662 0.39533E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.78 -3.54 -0.832 0.60367E+04 146 pyrrhotite -4.26 -6.78 -2.52 -0.841 0.43062E+04 147 pyrrhotiteFe0.875 -6.02 -8.18 -2.16 -0.796 0.36934E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22439E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.59 -4.61 -1.536 0.78695E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47115E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.78 -2.37 -0.790 0.40490E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.28 -3.30 -1.099 0.56304E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0087900 MOLES New total amount of reactant added: 0.0091900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8655E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0091900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7161E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1066350E-01 Osmotic coef. = 0.9132 True ionic strength = .2051317E-01 Chg. balance for total moles = -.8655E-10 Max. difference allowed = 0.1921E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90270E-10 -10.0445 0.75732E-10 -10.1207 0.83895E+00 -0.0763 2 H2O 0.99998E+00 0.0000 0.99998E+00 0.0000 3 Cl- 0.38509E-03 -3.4144 0.32110E-03 -3.4934 0.83381E+00 -0.0789 4 SO4-- 0.12526E-10 -10.9022 0.64632E-11 -11.1896 0.51598E+00 -0.2874 5 HCO3- 0.24594E-04 -4.6092 0.20538E-04 -4.6874 0.83505E+00 -0.0783 6 HS- 0.50105E-03 -3.3001 0.41784E-03 -3.3790 0.83393E+00 -0.0789 7 Al+++ 0.10460E-28 -28.9805 0.23814E-29 -29.6232 0.22767E+00 -0.6427 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14159E-06 -6.8490 0.72509E-07 -7.1396 0.51212E+00 -0.2906 10 Mg++ 0.22152E-10 -10.6546 0.11292E-10 -10.9472 0.50973E+00 -0.2927 11 Fe++ 0.61055E-13 -13.2143 0.31156E-13 -13.5065 0.51030E+00 -0.2922 12 K+ 0.16002E-03 -3.7958 0.13366E-03 -3.8740 0.83525E+00 -0.0782 13 Na+ 0.20307E-01 -1.6924 0.16929E-01 -1.7714 0.83365E+00 -0.0790 14 Mn++ 0.19603E-10 -10.7077 0.10012E-10 -10.9995 0.51074E+00 -0.2918 15 F- 0.11299E-05 -5.9469 0.94018E-06 -6.0268 0.83206E+00 -0.0798 16 HPO4-- 0.43772E-07 -7.3588 0.22589E-07 -7.6461 0.51606E+00 -0.2873 18 HSiO3- 0.10291E-01 -1.9875 0.85810E-02 -2.0665 0.83381E+00 -0.0789 19 Ca(HSiO3)+ 0.16961E-07 -7.7705 0.14170E-07 -7.8486 0.83544E+00 -0.0781 20 Mg(HSiO3)+ 0.32871E-11 -11.4832 0.27462E-11 -11.5613 0.83544E+00 -0.0781 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67613E-16 -16.1700 0.56486E-16 -16.2481 0.83544E+00 -0.0781 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52164E-05 -5.2826 0.43415E-05 -5.3624 0.83228E+00 -0.0797 26 CH4,aq 0.12939E-02 -2.8881 0.12897E-02 -2.8895 0.99674E+00 -0.0014 27 C2H6,aq 0.24632E-10 -10.6085 0.24552E-10 -10.6099 0.99674E+00 -0.0014 28 C3H8,aq 0.10826E-16 -16.9655 0.10790E-16 -16.9670 0.99674E+00 -0.0014 30 ethanol,aq 0.90408E-18 -18.0438 0.90114E-18 -18.0452 0.99674E+00 -0.0014 31 CO,aq 0.96703E-15 -15.0146 0.96703E-15 -15.0146 0.10000E+01 0.0000 32 CO2,aq 0.33344E-08 -8.4770 0.33235E-08 -8.4784 0.99674E+00 -0.0014 33 CO3-2 0.46006E-04 -4.3372 0.23687E-04 -4.6255 0.51487E+00 -0.2883 34 CaCO3,aq 0.21536E-07 -7.6668 0.21536E-07 -7.6668 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.45500E-10 -10.3420 0.38013E-10 -10.4201 0.83544E+00 -0.0781 36 CaCl+ 0.45100E-10 -10.3458 0.37678E-10 -10.4239 0.83544E+00 -0.0781 37 CaCl2,aq 0.28743E-14 -14.5415 0.28743E-14 -14.5415 0.10000E+01 0.0000 38 CaF+ 0.11914E-11 -11.9240 0.99531E-12 -12.0020 0.83544E+00 -0.0781 39 CaOH+ 0.81675E-07 -7.0879 0.68235E-07 -7.1660 0.83544E+00 -0.0781 40 CaSO4,aq 0.14882E-15 -15.8274 0.14882E-15 -15.8274 0.10000E+01 0.0000 41 HCl,aq 0.44560E-14 -14.3511 0.44560E-14 -14.3511 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18556E-18 -18.7315 0.15472E-18 -18.8104 0.83381E+00 -0.0789 48 FeCl+ 0.18954E-16 -16.7223 0.15835E-16 -16.8004 0.83544E+00 -0.0781 51 FeF+ 0.17918E-17 -17.7467 0.14969E-17 -17.8248 0.83544E+00 -0.0781 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16029E-10 -10.7951 0.13391E-10 -10.8732 0.83544E+00 -0.0781 55 HFeO2- 0.34982E-07 -7.4562 0.29168E-07 -7.5351 0.83381E+00 -0.0789 56 FeO+ 0.11234E-16 -16.9495 0.93853E-17 -17.0276 0.83544E+00 -0.0781 58 FeO2- 0.40157E-09 -9.3962 0.33483E-09 -9.4752 0.83381E+00 -0.0789 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11620E-04 -4.9348 0.11582E-04 -4.9362 0.99674E+00 -0.0014 61 KCl,aq 0.77784E-09 -9.1091 0.77784E-09 -9.1091 0.10000E+01 0.0000 63 KOH,aq 0.75368E-06 -6.1228 0.75368E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.16077E-13 -13.7938 0.13405E-13 -13.8727 0.83381E+00 -0.0789 65 MgCO3,aq 0.84064E-12 -12.0754 0.84064E-12 -12.0754 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.72402E-14 -14.1402 0.60487E-14 -14.2183 0.83544E+00 -0.0781 67 MgCl+ 0.63655E-14 -14.1962 0.53180E-14 -14.2743 0.83544E+00 -0.0781 68 MgF+ 0.68725E-15 -15.1629 0.57416E-15 -15.2410 0.83544E+00 -0.0781 69 MgOH+ 0.70381E-10 -10.1525 0.58799E-10 -10.2306 0.83544E+00 -0.0781 71 MnF+ 0.18978E-15 -15.7217 0.15855E-15 -15.7998 0.83544E+00 -0.0781 72 MnO,aq 0.18078E-08 -8.7429 0.18078E-08 -8.7429 0.10000E+01 0.0000 73 MnOH+ 0.47850E-09 -9.3201 0.39976E-09 -9.3982 0.83544E+00 -0.0781 74 MnO2-2 0.20316E-10 -10.6922 0.10460E-10 -10.9805 0.51487E+00 -0.2883 75 HMnO2- 0.20815E-09 -9.6816 0.17355E-09 -9.7606 0.83381E+00 -0.0789 78 MnCl+ 0.23696E-13 -13.6253 0.19797E-13 -13.7034 0.83544E+00 -0.0781 79 MnSO4,aq 0.18681E-19 -19.7286 0.18681E-19 -19.7286 0.10000E+01 0.0000 80 NaCl,aq 0.18014E-05 -5.7444 0.18014E-05 -5.7444 0.10000E+01 0.0000 81 NaF,aq 0.37262E-08 -8.4287 0.37262E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96038E-04 -4.0176 0.96038E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91664E-02 -2.0378 0.76290E-02 -2.1175 0.83228E+00 -0.0797 89 HPO3-2 0.15836E-14 -14.8004 0.81535E-15 -15.0887 0.51487E+00 -0.2883 91 H2PO3- 0.14850E-18 -18.8283 0.12382E-18 -18.9072 0.83381E+00 -0.0789 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37811E-10 -10.4224 0.31558E-10 -10.5009 0.83462E+00 -0.0785 94 PO4-3 0.10168E-08 -8.9928 0.24336E-09 -9.6138 0.23934E+00 -0.6210 98 HP2O7-3 0.90344E-18 -18.0441 0.20589E-18 -18.6864 0.22790E+00 -0.6423 99 P2O7-4 0.86407E-17 -17.0635 0.64949E-18 -18.1874 0.75167E-01 -1.1240 100 H2S,aq 0.98120E-07 -7.0082 0.97800E-07 -7.0097 0.99674E+00 -0.0014 101 S2-2 0.64873E-12 -12.1879 0.33401E-12 -12.4762 0.51487E+00 -0.2883 107 SO3-2 0.18620E-16 -16.7300 0.97281E-17 -17.0120 0.52246E+00 -0.2819 108 HSO3- 0.55322E-19 -19.2571 0.46128E-19 -19.3360 0.83381E+00 -0.0789 109 HSO4- 0.56407E-18 -18.2487 0.47171E-18 -18.3263 0.83627E+00 -0.0777 111 S2O3-2 0.14422E-19 -19.8410 0.74254E-20 -20.1293 0.51487E+00 -0.2883 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9027035E-10 -.2197392E-01 -.2210900E+02 0.0000 2 H2O 0.1000000E+01 0.5550619E+02 0.9981821E+06 0.0000 3 Cl- 0.3850942E-03 0.3868965E-03 0.1369224E+02 6.6274 4 SO4-- 0.1252596E-10 -.1296838E-02 -.1243547E+03 9.0519 5 HCO3- 0.2459447E-04 0.1364558E-02 0.8311344E+02 5.4333 6 HS- 0.5010501E-03 0.1797986E-02 0.5935723E+02 6.7417 7 Al+++ 0.1046024E-28 0.5216585E-05 0.1405009E+00 0.7390 8 H4SiO4 0.6959614E-03 0.1333681E-01 0.1279593E+04 -3.1574 9 Ca++ 0.1415857E-06 0.2618500E-06 0.1047576E-01 13.1018 10 Mg++ 0.2215199E-10 0.9667406E-10 0.2346159E-05 9.2942 11 Fe++ 0.6105473E-13 0.3561374E-07 0.1985383E-02 6.7350 12 K+ 0.1600207E-03 0.1607752E-03 0.6275451E+01 6.2467 13 Na+ 0.2030657E-01 0.2275389E-01 0.5221769E+03 8.3493 14 Mn++ 0.1960334E-10 0.2534368E-08 0.1389855E-03 9.2420 15 F- 0.1129942E-05 0.1133669E-05 0.2149914E-01 4.0939 16 HPO4-- 0.4377174E-07 0.4482633E-07 0.4294734E-02 12.5953 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279156E+02 -.1091011E-01 -.8278065E+02 0.0000000E+00 2 H2O -.7161265E+01 0.2755898E+02 -.3472024E+02 0.0000000E+00 3 Cl- 0.1920952E-03 0.1920952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386364E+00 -.6438835E-03 0.1392803E+00 0.0000000E+00 5 HCO3- 0.6775070E-03 0.6775070E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383876E+00 0.8927050E-03 -.1392803E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2590049E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6621763E-02 0.5205728E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1300093E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4799894E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1768232E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7982534E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1129737E-01 0.6265080E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1258321E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3776000E-05 0.5628700E-06 0.3213130E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2225640E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.6849E-14 Mass of aqueous solution: 0.497387E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0091900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.0 andradite 0.5571 -0.254 283.1 2.452 5.183 73.56 grossular 0.1349 -0.870 60.77 1.784 1.112 16.91 apatite-OH 0.9859E-02 -2.006 4.953 0.695 0.9067E-01 1.574 apatite-F 0.3213E-05 -5.493 0.1620E-02 -2.790 0.2967E-04 0.5062E-03 clinochlore 0.7097 -0.149 394.5 2.596 7.221 150.0 daphnite 0.2054 -0.687 146.6 2.166 2.684 44.42 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2451 -0.611 53.08 1.725 0.9718 16.22 hedenbergite 0.6357E-01 -1.197 15.77 1.198 0.2887 4.320 microcline 0.9315 -0.031 259.3 2.414 4.747 101.3 stilbite 3.220 0.508 2269. 3.356 41.55 1058. stilpnomelane-Fe 0.2599 -0.585 280.2 2.447 5.130 96.79 tr.625ac.25prg.125 0.4821E-01 -1.317 41.21 1.615 0.7544 13.26 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1859E-01 0.1859E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.340758 g Volume = 2210.803212 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0091900 moles log = -2.0367 Original solution: 1000.0103000 g Original solution / Rock added: 108815.05 (Water/Rock Ratio), log = 5.0367 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 2.9397 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3509E+00 0.9752 0.1006E+01 0.1031E+01 CO2,gas 0.1215E-06 0.9954 0.3556E-06 0.3572E-06 CH4,gas 0.6440E+00 1.0028 0.1898E+01 0.1893E+01 H2,gas 0.5165E-02 1.0016 0.1521E-01 0.1518E-01 H2S,gas 0.9251E-06 0.9886 0.2688E-05 0.2719E-05 S2,gas 0.3991E-27 1.0000 0.1173E-26 0.1173E-26 CO,gas 0.4902E-12 1.0000 0.1441E-11 0.1441E-11 SO3,gas 0.4768E-47 1.0000 0.1402E-46 0.1402E-46 SO2,gas 0.2821E-26 1.0000 0.8292E-26 0.8292E-26 HF,gas 0.4071E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2675E-17 1.0000 0.7863E-17 0.7863E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.81 -8.15 -2.716 0.13913E+05 -6.449 3 CH4,gas 4.54 3.12 -1.42 -0.355 0.24256E+04 0.278 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.50 -7.27 -3.635 0.12412E+05 -5.570 6 S2,gas -7.34 -35.97 -28.63 -4.405 0.48884E+05 -26.931 7 CO,gas 3.21 -10.33 -13.54 -4.166 0.23120E+05 -11.841 8 SO3,gas 17.12 -31.43 -48.55 -12.138 0.82902E+05 -46.853 9 SO2,gas 0.83 -26.95 -27.78 -7.408 0.47434E+05 -26.081 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.61 -18.80 -9.402 0.32106E+05 -17.104 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80690E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93628E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.71 -2.67 -0.891 0.45638E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.71 -2.52 -0.839 0.42996E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65542E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.84 -2.74 -0.783 0.46787E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.84 -2.30 -0.656 0.39209E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82235E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.75 -3.50 -0.824 0.59767E+04 146 pyrrhotite -4.26 -6.76 -2.50 -0.835 0.42762E+04 147 pyrrhotiteFe0.875 -6.02 -8.16 -2.15 -0.789 0.36634E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22438E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.57 -4.59 -1.530 0.78371E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23241E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47114E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.76 -2.35 -0.785 0.40190E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.26 -3.28 -1.093 0.56003E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0091900 MOLES New total amount of reactant added: 0.0095900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8653E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0095900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7161E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1062989E-01 Osmotic coef. = 0.9137 True ionic strength = .2053119E-01 Chg. balance for total moles = -.8653E-10 Max. difference allowed = 0.1945E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90341E-10 -10.0441 0.75788E-10 -10.1204 0.83890E+00 -0.0763 2 H2O 0.99998E+00 0.0000 0.99998E+00 0.0000 3 Cl- 0.38982E-03 -3.4091 0.32501E-03 -3.4881 0.83376E+00 -0.0790 4 SO4-- 0.13008E-10 -10.8858 0.67103E-11 -11.1733 0.51587E+00 -0.2875 5 HCO3- 0.25628E-04 -4.5913 0.21400E-04 -4.6696 0.83500E+00 -0.0783 6 HS- 0.52062E-03 -3.2835 0.43413E-03 -3.3624 0.83388E+00 -0.0789 7 Al+++ 0.10489E-28 -28.9793 0.23867E-29 -29.6222 0.22755E+00 -0.6429 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14183E-06 -6.8482 0.72615E-07 -7.1390 0.51200E+00 -0.2907 10 Mg++ 0.22190E-10 -10.6538 0.11308E-10 -10.9466 0.50961E+00 -0.2928 11 Fe++ 0.61159E-13 -13.2135 0.31202E-13 -13.5058 0.51018E+00 -0.2923 12 K+ 0.16015E-03 -3.7955 0.13376E-03 -3.8737 0.83521E+00 -0.0782 13 Na+ 0.20323E-01 -1.6920 0.16941E-01 -1.7711 0.83360E+00 -0.0790 14 Mn++ 0.19637E-10 -10.7069 0.10027E-10 -10.9988 0.51061E+00 -0.2919 15 F- 0.11292E-05 -5.9472 0.93949E-06 -6.0271 0.83201E+00 -0.0799 16 HPO4-- 0.43718E-07 -7.3593 0.22556E-07 -7.6467 0.51594E+00 -0.2874 18 HSiO3- 0.10284E-01 -1.9878 0.85748E-02 -2.0668 0.83376E+00 -0.0790 19 Ca(HSiO3)+ 0.16974E-07 -7.7702 0.14180E-07 -7.8483 0.83539E+00 -0.0781 20 Mg(HSiO3)+ 0.32897E-11 -11.4828 0.27482E-11 -11.5610 0.83539E+00 -0.0781 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67666E-16 -16.1696 0.56528E-16 -16.2477 0.83539E+00 -0.0781 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52130E-05 -5.2829 0.43383E-05 -5.3627 0.83222E+00 -0.0798 26 CH4,aq 0.13492E-02 -2.8699 0.13448E-02 -2.8713 0.99675E+00 -0.0014 27 C2H6,aq 0.26782E-10 -10.5722 0.26695E-10 -10.5736 0.99675E+00 -0.0014 28 C3H8,aq 0.12274E-16 -16.9110 0.12234E-16 -16.9124 0.99675E+00 -0.0014 30 ethanol,aq 0.98300E-18 -18.0074 0.97981E-18 -18.0089 0.99675E+00 -0.0014 31 CO,aq 0.10084E-14 -14.9964 0.10084E-14 -14.9964 0.10000E+01 0.0000 32 CO2,aq 0.34769E-08 -8.4588 0.34656E-08 -8.4602 0.99675E+00 -0.0014 33 CO3-2 0.47914E-04 -4.3195 0.24663E-04 -4.6079 0.51475E+00 -0.2884 34 CaCO3,aq 0.22456E-07 -7.6487 0.22456E-07 -7.6487 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.47482E-10 -10.3235 0.39666E-10 -10.4016 0.83539E+00 -0.0781 36 CaCl+ 0.45720E-10 -10.3399 0.38194E-10 -10.4180 0.83539E+00 -0.0781 37 CaCl2,aq 0.29492E-14 -14.5303 0.29492E-14 -14.5303 0.10000E+01 0.0000 38 CaF+ 0.11923E-11 -11.9236 0.99604E-12 -12.0017 0.83539E+00 -0.0781 39 CaOH+ 0.81740E-07 -7.0876 0.68284E-07 -7.1657 0.83539E+00 -0.0781 40 CaSO4,aq 0.15473E-15 -15.8104 0.15473E-15 -15.8104 0.10000E+01 0.0000 41 HCl,aq 0.45137E-14 -14.3455 0.45137E-14 -14.3455 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18544E-18 -18.7318 0.15461E-18 -18.8108 0.83376E+00 -0.0790 48 FeCl+ 0.19215E-16 -16.7164 0.16052E-16 -16.7945 0.83539E+00 -0.0781 51 FeF+ 0.17932E-17 -17.7464 0.14980E-17 -17.8245 0.83539E+00 -0.0781 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16042E-10 -10.7948 0.13401E-10 -10.8729 0.83539E+00 -0.0781 55 HFeO2- 0.34958E-07 -7.4564 0.29147E-07 -7.5354 0.83376E+00 -0.0790 56 FeO+ 0.11243E-16 -16.9491 0.93922E-17 -17.0272 0.83539E+00 -0.0781 58 FeO2- 0.40130E-09 -9.3965 0.33459E-09 -9.4755 0.83376E+00 -0.0790 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11620E-04 -4.9348 0.11582E-04 -4.9362 0.99675E+00 -0.0014 61 KCl,aq 0.78790E-09 -9.1035 0.78790E-09 -9.1035 0.10000E+01 0.0000 63 KOH,aq 0.75368E-06 -6.1228 0.75368E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.16705E-13 -13.7772 0.13928E-13 -13.8561 0.83376E+00 -0.0790 65 MgCO3,aq 0.87656E-12 -12.0572 0.87656E-12 -12.0572 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.75556E-14 -14.1217 0.63118E-14 -14.1998 0.83539E+00 -0.0781 67 MgCl+ 0.64530E-14 -14.1902 0.53908E-14 -14.2684 0.83539E+00 -0.0781 68 MgF+ 0.68779E-15 -15.1625 0.57457E-15 -15.2407 0.83539E+00 -0.0781 69 MgOH+ 0.70436E-10 -10.1522 0.58842E-10 -10.2303 0.83539E+00 -0.0781 71 MnF+ 0.18994E-15 -15.7214 0.15867E-15 -15.7995 0.83539E+00 -0.0781 72 MnO,aq 0.18078E-08 -8.7428 0.18078E-08 -8.7428 0.10000E+01 0.0000 73 MnOH+ 0.47890E-09 -9.3198 0.40007E-09 -9.3979 0.83539E+00 -0.0781 74 MnO2-2 0.20292E-10 -10.6927 0.10445E-10 -10.9811 0.51475E+00 -0.2884 75 HMnO2- 0.20801E-09 -9.6819 0.17343E-09 -9.7609 0.83376E+00 -0.0790 78 MnCl+ 0.24023E-13 -13.6194 0.20069E-13 -13.6975 0.83539E+00 -0.0781 79 MnSO4,aq 0.19425E-19 -19.7116 0.19425E-19 -19.7116 0.10000E+01 0.0000 80 NaCl,aq 0.18247E-05 -5.7388 0.18247E-05 -5.7388 0.10000E+01 0.0000 81 NaF,aq 0.37262E-08 -8.4287 0.37262E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96038E-04 -4.0176 0.96038E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91603E-02 -2.0381 0.76234E-02 -2.1179 0.83222E+00 -0.0798 89 HPO3-2 0.15817E-14 -14.8009 0.81416E-15 -15.0893 0.51475E+00 -0.2884 91 H2PO3- 0.14840E-18 -18.8286 0.12373E-18 -18.9075 0.83376E+00 -0.0790 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37786E-10 -10.4227 0.31535E-10 -10.5012 0.83457E+00 -0.0785 94 PO4-3 0.10150E-08 -8.9935 0.24283E-09 -9.6147 0.23922E+00 -0.6212 98 HP2O7-3 0.90194E-18 -18.0448 0.20544E-18 -18.6873 0.22778E+00 -0.6425 99 P2O7-4 0.86234E-17 -17.0643 0.64760E-18 -18.1887 0.75097E-01 -1.1244 100 H2S,aq 0.10202E-06 -6.9913 0.10169E-06 -6.9927 0.99675E+00 -0.0014 101 S2-2 0.70047E-12 -12.1546 0.36057E-12 -12.4430 0.51475E+00 -0.2884 107 SO3-2 0.19336E-16 -16.7136 0.10100E-16 -16.9957 0.52234E+00 -0.2820 108 HSO3- 0.57483E-19 -19.2405 0.47927E-19 -19.3194 0.83376E+00 -0.0790 109 HSO4- 0.58610E-18 -18.2320 0.49010E-18 -18.3097 0.83622E+00 -0.0777 111 S2O3-2 0.15572E-19 -19.8077 0.80157E-20 -20.0961 0.51475E+00 -0.2884 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9034130E-10 -.2196279E-01 -.2209776E+02 0.0000 2 H2O 0.1000000E+01 0.5550624E+02 0.9981815E+06 0.0000 3 Cl- 0.3898184E-03 0.3916440E-03 0.1386024E+02 6.6323 4 SO4-- 0.1300782E-10 -.1352122E-02 -.1296557E+03 9.0675 5 HCO3- 0.2562839E-04 0.1422785E-02 0.8665979E+02 5.4508 6 HS- 0.5206154E-03 0.1872839E-02 0.6182827E+02 6.7580 7 Al+++ 0.1048874E-28 0.5213102E-05 0.1404069E+00 0.7390 8 H4SiO4 0.6959606E-03 0.1332991E-01 0.1278929E+04 -3.1574 9 Ca++ 0.1418261E-06 0.2630912E-06 0.1052540E-01 13.1018 10 Mg++ 0.2218967E-10 0.9680590E-10 0.2349355E-05 9.2942 11 Fe++ 0.6115860E-13 0.3559003E-07 0.1984058E-02 6.7350 12 K+ 0.1601465E-03 0.1609010E-03 0.6280350E+01 6.2467 13 Na+ 0.2032256E-01 0.2276989E-01 0.5225433E+03 8.3493 14 Mn++ 0.1963744E-10 0.2534712E-08 0.1390041E-03 9.2420 15 F- 0.1129186E-05 0.1132914E-05 0.2148478E-01 4.0933 16 HPO4-- 0.4371806E-07 0.4477089E-07 0.4289416E-02 12.5941 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279151E+02 -.1090474E-01 -.8278061E+02 0.0000000E+00 2 H2O -.7160937E+01 0.2755941E+02 -.3472035E+02 0.0000000E+00 3 Cl- 0.1944552E-03 0.1944552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386383E+00 -.6713421E-03 0.1393097E+00 0.0000000E+00 5 HCO3- 0.7064270E-03 0.7064270E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383798E+00 0.9298835E-03 -.1393097E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2588358E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6618437E-02 0.5205729E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1306274E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4806511E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1767081E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7988896E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1130548E-01 0.6265071E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1258510E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3936000E-05 0.5625031E-06 0.3373497E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2222920E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1291E-14 Mass of aqueous solution: 0.497396E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0095900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.0 andradite 0.5572 -0.254 283.2 2.452 5.184 73.57 grossular 0.1349 -0.870 60.78 1.784 1.113 16.91 apatite-OH 0.9859E-02 -2.006 4.952 0.695 0.9067E-01 1.574 apatite-F 0.3373E-05 -5.472 0.1701E-02 -2.769 0.3115E-04 0.5315E-03 clinochlore 0.7096 -0.149 394.4 2.596 7.221 150.0 daphnite 0.2054 -0.687 146.6 2.166 2.684 44.42 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2444 -0.612 52.92 1.724 0.9688 16.17 hedenbergite 0.6337E-01 -1.198 15.72 1.197 0.2878 4.306 microcline 0.9316 -0.031 259.3 2.414 4.747 101.3 stilbite 3.220 0.508 2269. 3.356 41.55 1058. stilpnomelane-Fe 0.2599 -0.585 280.1 2.447 5.129 96.77 tr.625ac.25prg.125 0.4846E-01 -1.315 41.42 1.617 0.7584 13.33 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.340881 g Volume = 2210.804316 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0095900 moles log = -2.0182 Original solution: 1000.0103000 g Original solution / Rock added: 104276.36 (Water/Rock Ratio), log = 5.0182 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 3.0212 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3415E+00 0.9750 0.1006E+01 0.1032E+01 CO2,gas 0.1233E-06 0.9952 0.3708E-06 0.3726E-06 CH4,gas 0.6535E+00 1.0027 0.1980E+01 0.1974E+01 H2,gas 0.5025E-02 1.0016 0.1521E-01 0.1518E-01 H2S,gas 0.9362E-06 0.9883 0.2795E-05 0.2828E-05 S2,gas 0.4199E-27 1.0000 0.1268E-26 0.1268E-26 CO,gas 0.4974E-12 1.0000 0.1503E-11 0.1503E-11 SO3,gas 0.4824E-47 1.0000 0.1457E-46 0.1457E-46 SO2,gas 0.2854E-26 1.0000 0.8622E-26 0.8622E-26 HF,gas 0.3961E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2636E-17 1.0000 0.7965E-17 0.7965E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.79 -8.13 -2.710 0.13882E+05 -6.431 3 CH4,gas 4.54 3.14 -1.40 -0.351 0.23946E+04 0.297 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.48 -7.25 -3.626 0.12384E+05 -5.554 6 S2,gas -7.34 -35.93 -28.60 -4.399 0.48826E+05 -26.897 7 CO,gas 3.21 -10.31 -13.52 -4.161 0.23089E+05 -11.823 8 SO3,gas 17.12 -31.41 -48.54 -12.134 0.82873E+05 -46.836 9 SO2,gas 0.83 -26.93 -27.76 -7.404 0.47405E+05 -26.064 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.61 -18.80 -9.399 0.32097E+05 -17.099 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80689E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93628E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.69 -2.65 -0.885 0.45328E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.69 -2.50 -0.833 0.42686E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65542E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.82 -2.72 -0.778 0.46477E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.82 -2.28 -0.651 0.38899E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82234E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.71 -3.47 -0.816 0.59189E+04 146 pyrrhotite -4.26 -6.75 -2.49 -0.829 0.42473E+04 147 pyrrhotiteFe0.875 -6.02 -8.15 -2.13 -0.783 0.36345E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22438E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28679E+03 154 rhodochrosite -0.98 -5.55 -4.57 -1.524 0.78060E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23240E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47113E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.75 -2.34 -0.779 0.39901E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.24 -3.26 -1.088 0.55714E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0095900 MOLES New total amount of reactant added: 0.0099900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8655E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0099900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7161E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1059627E-01 Osmotic coef. = 0.9141 True ionic strength = .2054921E-01 Chg. balance for total moles = -.8655E-10 Max. difference allowed = 0.1968E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90412E-10 -10.0438 0.75843E-10 -10.1201 0.83886E+00 -0.0763 2 H2O 0.99997E+00 0.0000 0.99997E+00 0.0000 3 Cl- 0.39454E-03 -3.4039 0.32893E-03 -3.4829 0.83371E+00 -0.0790 4 SO4-- 0.13489E-10 -10.8700 0.69570E-11 -11.1576 0.51575E+00 -0.2876 5 HCO3- 0.26661E-04 -4.5741 0.22261E-04 -4.6525 0.83495E+00 -0.0783 6 HS- 0.54018E-03 -3.2675 0.45042E-03 -3.3464 0.83383E+00 -0.0789 7 Al+++ 0.10517E-28 -28.9781 0.23919E-29 -29.6213 0.22743E+00 -0.6432 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14207E-06 -6.8475 0.72721E-07 -7.1383 0.51188E+00 -0.2908 10 Mg++ 0.22227E-10 -10.6531 0.11325E-10 -10.9460 0.50949E+00 -0.2929 11 Fe++ 0.61263E-13 -13.2128 0.31248E-13 -13.5052 0.51006E+00 -0.2924 12 K+ 0.16027E-03 -3.7951 0.13385E-03 -3.8734 0.83516E+00 -0.0782 13 Na+ 0.20339E-01 -1.6917 0.16953E-01 -1.7707 0.83355E+00 -0.0791 14 Mn++ 0.19672E-10 -10.7062 0.10042E-10 -10.9982 0.51049E+00 -0.2920 15 F- 0.11284E-05 -5.9475 0.93881E-06 -6.0274 0.83196E+00 -0.0799 16 HPO4-- 0.43664E-07 -7.3599 0.22523E-07 -7.6474 0.51582E+00 -0.2875 18 HSiO3- 0.10278E-01 -1.9881 0.85685E-02 -2.0671 0.83371E+00 -0.0790 19 Ca(HSiO3)+ 0.16988E-07 -7.7699 0.14191E-07 -7.8480 0.83534E+00 -0.0781 20 Mg(HSiO3)+ 0.32923E-11 -11.4825 0.27502E-11 -11.5606 0.83534E+00 -0.0781 21 NaHSiO3,aq 0.23495E-02 -2.6290 0.23495E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67720E-16 -16.1693 0.56569E-16 -16.2474 0.83534E+00 -0.0781 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52095E-05 -5.2832 0.43352E-05 -5.3630 0.83217E+00 -0.0798 26 CH4,aq 0.14045E-02 -2.8525 0.14000E-02 -2.8539 0.99676E+00 -0.0014 27 C2H6,aq 0.29022E-10 -10.5373 0.28928E-10 -10.5387 0.99676E+00 -0.0014 28 C3H8,aq 0.13845E-16 -16.8587 0.13801E-16 -16.8601 0.99676E+00 -0.0014 30 ethanol,aq 0.10652E-17 -17.9726 0.10618E-17 -17.9740 0.99676E+00 -0.0014 31 CO,aq 0.10497E-14 -14.9789 0.10497E-14 -14.9789 0.10000E+01 0.0000 32 CO2,aq 0.36193E-08 -8.4414 0.36076E-08 -8.4428 0.99676E+00 -0.0014 33 CO3-2 0.49817E-04 -4.3026 0.25637E-04 -4.5911 0.51463E+00 -0.2885 34 CaCO3,aq 0.23377E-07 -7.6312 0.23377E-07 -7.6312 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.49468E-10 -10.3057 0.41322E-10 -10.3838 0.83534E+00 -0.0781 36 CaCl+ 0.46341E-10 -10.3340 0.38711E-10 -10.4122 0.83534E+00 -0.0781 37 CaCl2,aq 0.30252E-14 -14.5193 0.30252E-14 -14.5193 0.10000E+01 0.0000 38 CaF+ 0.11932E-11 -11.9233 0.99676E-12 -12.0014 0.83534E+00 -0.0781 39 CaOH+ 0.81804E-07 -7.0872 0.68334E-07 -7.1654 0.83534E+00 -0.0781 40 CaSO4,aq 0.16065E-15 -15.7941 0.16065E-15 -15.7941 0.10000E+01 0.0000 41 HCl,aq 0.45715E-14 -14.3399 0.45715E-14 -14.3399 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18531E-18 -18.7321 0.15450E-18 -18.8111 0.83371E+00 -0.0790 48 FeCl+ 0.19476E-16 -16.7105 0.16269E-16 -16.7886 0.83534E+00 -0.0781 51 FeF+ 0.17946E-17 -17.7460 0.14991E-17 -17.8242 0.83534E+00 -0.0781 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16054E-10 -10.7944 0.13411E-10 -10.8725 0.83534E+00 -0.0781 55 HFeO2- 0.34935E-07 -7.4567 0.29126E-07 -7.5357 0.83371E+00 -0.0790 56 FeO+ 0.11252E-16 -16.9488 0.93990E-17 -17.0269 0.83534E+00 -0.0781 58 FeO2- 0.40103E-09 -9.3968 0.33434E-09 -9.4758 0.83371E+00 -0.0790 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11620E-04 -4.9348 0.11582E-04 -4.9362 0.99676E+00 -0.0014 61 KCl,aq 0.79798E-09 -9.0980 0.79798E-09 -9.0980 0.10000E+01 0.0000 63 KOH,aq 0.75368E-06 -6.1228 0.75368E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.17332E-13 -13.7611 0.14450E-13 -13.8401 0.83371E+00 -0.0790 65 MgCO3,aq 0.91249E-12 -12.0398 0.91249E-12 -12.0398 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.78715E-14 -14.1039 0.65754E-14 -14.1821 0.83534E+00 -0.0781 67 MgCl+ 0.65407E-14 -14.1844 0.54637E-14 -14.2625 0.83534E+00 -0.0781 68 MgF+ 0.68834E-15 -15.1622 0.57499E-15 -15.2403 0.83534E+00 -0.0781 69 MgOH+ 0.70492E-10 -10.1519 0.58885E-10 -10.2300 0.83534E+00 -0.0781 71 MnF+ 0.19010E-15 -15.7210 0.15880E-15 -15.7992 0.83534E+00 -0.0781 72 MnO,aq 0.18079E-08 -8.7428 0.18079E-08 -8.7428 0.10000E+01 0.0000 73 MnOH+ 0.47930E-09 -9.3194 0.40037E-09 -9.3975 0.83534E+00 -0.0781 74 MnO2-2 0.20268E-10 -10.6932 0.10431E-10 -10.9817 0.51463E+00 -0.2885 75 HMnO2- 0.20788E-09 -9.6822 0.17331E-09 -9.7612 0.83371E+00 -0.0790 78 MnCl+ 0.24351E-13 -13.6135 0.20341E-13 -13.6916 0.83534E+00 -0.0781 79 MnSO4,aq 0.20169E-19 -19.6953 0.20169E-19 -19.6953 0.10000E+01 0.0000 80 NaCl,aq 0.18481E-05 -5.7333 0.18481E-05 -5.7333 0.10000E+01 0.0000 81 NaF,aq 0.37262E-08 -8.4287 0.37262E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96037E-04 -4.0176 0.96037E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91541E-02 -2.0384 0.76178E-02 -2.1182 0.83217E+00 -0.0798 89 HPO3-2 0.15797E-14 -14.8014 0.81297E-15 -15.0899 0.51463E+00 -0.2885 91 H2PO3- 0.14830E-18 -18.8288 0.12364E-18 -18.9078 0.83371E+00 -0.0790 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37761E-10 -10.4230 0.31512E-10 -10.5015 0.83452E+00 -0.0786 94 PO4-3 0.10133E-08 -8.9942 0.24229E-09 -9.6157 0.23911E+00 -0.6214 98 HP2O7-3 0.90045E-18 -18.0455 0.20500E-18 -18.6883 0.22766E+00 -0.6427 99 P2O7-4 0.86062E-17 -17.0652 0.64571E-18 -18.1900 0.75028E-01 -1.1248 100 H2S,aq 0.10592E-06 -6.9750 0.10558E-06 -6.9764 0.99676E+00 -0.0014 101 S2-2 0.75419E-12 -12.1225 0.38813E-12 -12.4110 0.51463E+00 -0.2885 107 SO3-2 0.20051E-16 -16.6979 0.10471E-16 -16.9800 0.52223E+00 -0.2821 108 HSO3- 0.59643E-19 -19.2244 0.49725E-19 -19.3034 0.83371E+00 -0.0790 109 HSO4- 0.60812E-18 -18.2160 0.50849E-18 -18.2937 0.83617E+00 -0.0777 111 S2O3-2 0.16766E-19 -19.7756 0.86284E-20 -20.0641 0.51463E+00 -0.2885 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9041227E-10 -.2195166E-01 -.2208653E+02 0.0000 2 H2O 0.1000000E+01 0.5550630E+02 0.9981809E+06 0.0000 3 Cl- 0.3945424E-03 0.3963913E-03 0.1402822E+02 6.6372 4 SO4-- 0.1348914E-10 -.1407410E-02 -.1349571E+03 9.0826 5 HCO3- 0.2666102E-04 0.1481010E-02 0.9020604E+02 5.4676 6 HS- 0.5401802E-03 0.1947696E-02 0.6429943E+02 6.7737 7 Al+++ 0.1051731E-28 0.5209624E-05 0.1403130E+00 0.7390 8 H4SiO4 0.6959598E-03 0.1332303E-01 0.1278266E+04 -3.1574 9 Ca++ 0.1420668E-06 0.2643327E-06 0.1057505E-01 13.1018 10 Mg++ 0.2222740E-10 0.9693954E-10 0.2352595E-05 9.2942 11 Fe++ 0.6126259E-13 0.3556636E-07 0.1982735E-02 6.7350 12 K+ 0.1602723E-03 0.1610268E-03 0.6285251E+01 6.2467 13 Na+ 0.2033855E-01 0.2278590E-01 0.5229098E+03 8.3493 14 Mn++ 0.1967157E-10 0.2535056E-08 0.1390228E-03 9.2420 15 F- 0.1128431E-05 0.1132159E-05 0.2147043E-01 4.0927 16 HPO4-- 0.4366446E-07 0.4471556E-07 0.4284107E-02 12.5928 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279147E+02 -.1089938E-01 -.8278057E+02 0.0000000E+00 2 H2O -.7160610E+01 0.2755984E+02 -.3472045E+02 0.0000000E+00 3 Cl- 0.1968152E-03 0.1968152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386402E+00 -.6988035E-03 0.1393390E+00 0.0000000E+00 5 HCO3- 0.7353470E-03 0.7353470E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383720E+00 0.9670649E-03 -.1393390E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2586669E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6615114E-02 0.5205729E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1312458E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4813216E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1765931E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7995261E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1131359E-01 0.6265063E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1258700E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4096000E-05 0.5621366E-06 0.3533863E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2220205E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.1552E-13 Mass of aqueous solution: 0.497404E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0099900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.0 andradite 0.5574 -0.254 283.2 2.452 5.185 73.59 grossular 0.1350 -0.870 60.79 1.784 1.113 16.92 apatite-OH 0.9859E-02 -2.006 4.952 0.695 0.9066E-01 1.574 apatite-F 0.3534E-05 -5.452 0.1782E-02 -2.749 0.3263E-04 0.5568E-03 clinochlore 0.7096 -0.149 394.4 2.596 7.221 150.0 daphnite 0.2054 -0.687 146.6 2.166 2.683 44.42 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2436 -0.613 52.75 1.722 0.9657 16.12 hedenbergite 0.6317E-01 -1.199 15.67 1.195 0.2869 4.293 microcline 0.9316 -0.031 259.3 2.414 4.747 101.3 stilbite 3.220 0.508 2269. 3.356 41.55 1058. stilpnomelane-Fe 0.2598 -0.585 280.1 2.447 5.128 96.75 tr.625ac.25prg.125 0.4871E-01 -1.312 41.64 1.619 0.7623 13.40 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.341003 g Volume = 2210.805419 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0099900 moles log = -2.0004 Original solution: 1000.0103000 g Original solution / Rock added: 100101.13 (Water/Rock Ratio), log = 5.0004 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 3.1026 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3326E+00 0.9748 0.1006E+01 0.1032E+01 CO2,gas 0.1250E-06 0.9949 0.3860E-06 0.3880E-06 CH4,gas 0.6625E+00 1.0025 0.2061E+01 0.2056E+01 H2,gas 0.4893E-02 1.0017 0.1521E-01 0.1518E-01 H2S,gas 0.9468E-06 0.9880 0.2902E-05 0.2938E-05 S2,gas 0.4407E-27 1.0000 0.1367E-26 0.1367E-26 CO,gas 0.5042E-12 1.0000 0.1564E-11 0.1564E-11 SO3,gas 0.4877E-47 1.0000 0.1513E-46 0.1513E-46 SO2,gas 0.2885E-26 1.0000 0.8952E-26 0.8952E-26 HF,gas 0.3857E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2600E-17 1.0000 0.8067E-17 0.8067E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.77 -8.11 -2.704 0.13852E+05 -6.413 3 CH4,gas 4.54 3.16 -1.38 -0.346 0.23648E+04 0.314 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.47 -7.24 -3.618 0.12356E+05 -5.537 6 S2,gas -7.34 -35.90 -28.56 -4.394 0.48771E+05 -26.864 7 CO,gas 3.21 -10.29 -13.50 -4.155 0.23059E+05 -11.806 8 SO3,gas 17.12 -31.40 -48.52 -12.130 0.82845E+05 -46.820 9 SO2,gas 0.83 -26.91 -27.75 -7.399 0.47377E+05 -26.048 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.60 -18.79 -9.396 0.32087E+05 -17.093 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80688E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93628E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.67 -2.64 -0.879 0.45030E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.67 -2.48 -0.827 0.42388E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65542E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.81 -2.70 -0.773 0.46179E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.81 -2.26 -0.646 0.38601E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82234E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.68 -3.43 -0.808 0.58632E+04 146 pyrrhotite -4.26 -6.73 -2.47 -0.824 0.42194E+04 147 pyrrhotiteFe0.875 -6.02 -8.13 -2.11 -0.777 0.36066E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22438E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.53 -4.55 -1.518 0.77762E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23240E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47113E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.73 -2.32 -0.774 0.39622E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.22 -3.25 -1.082 0.55435E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0099900 MOLES New total amount of reactant added: 0.0103900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8653E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0103900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7160E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1056264E-01 Osmotic coef. = 0.9145 True ionic strength = .2056724E-01 Chg. balance for total moles = -.8653E-10 Max. difference allowed = 0.1992E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90483E-10 -10.0434 0.75898E-10 -10.1198 0.83881E+00 -0.0763 2 H2O 0.99997E+00 0.0000 0.99997E+00 0.0000 3 Cl- 0.39927E-03 -3.3987 0.33285E-03 -3.4777 0.83366E+00 -0.0790 4 SO4-- 0.13970E-10 -10.8548 0.72032E-11 -11.1425 0.51563E+00 -0.2877 5 HCO3- 0.27692E-04 -4.5576 0.23120E-04 -4.6360 0.83490E+00 -0.0784 6 HS- 0.55974E-03 -3.2520 0.46671E-03 -3.3310 0.83378E+00 -0.0789 7 Al+++ 0.10546E-28 -28.9769 0.23971E-29 -29.6203 0.22730E+00 -0.6434 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14231E-06 -6.8468 0.72827E-07 -7.1377 0.51176E+00 -0.2909 10 Mg++ 0.22265E-10 -10.6524 0.11341E-10 -10.9453 0.50937E+00 -0.2930 11 Fe++ 0.61367E-13 -13.2121 0.31293E-13 -13.5046 0.50994E+00 -0.2925 12 K+ 0.16040E-03 -3.7948 0.13395E-03 -3.8731 0.83511E+00 -0.0783 13 Na+ 0.20355E-01 -1.6913 0.16966E-01 -1.7704 0.83350E+00 -0.0791 14 Mn++ 0.19706E-10 -10.7054 0.10057E-10 -10.9975 0.51037E+00 -0.2921 15 F- 0.11277E-05 -5.9478 0.93812E-06 -6.0277 0.83191E+00 -0.0799 16 HPO4-- 0.43611E-07 -7.3604 0.22490E-07 -7.6480 0.51570E+00 -0.2876 18 HSiO3- 0.10271E-01 -1.9884 0.85623E-02 -2.0674 0.83366E+00 -0.0790 19 Ca(HSiO3)+ 0.17001E-07 -7.7695 0.14201E-07 -7.8477 0.83529E+00 -0.0782 20 Mg(HSiO3)+ 0.32949E-11 -11.4822 0.27522E-11 -11.5603 0.83529E+00 -0.0782 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67773E-16 -16.1689 0.56610E-16 -16.2471 0.83529E+00 -0.0782 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52060E-05 -5.2835 0.43320E-05 -5.3633 0.83212E+00 -0.0798 26 CH4,aq 0.14598E-02 -2.8357 0.14551E-02 -2.8371 0.99677E+00 -0.0014 27 C2H6,aq 0.31353E-10 -10.5037 0.31251E-10 -10.5051 0.99677E+00 -0.0014 28 C3H8,aq 0.15546E-16 -16.8084 0.15496E-16 -16.8098 0.99677E+00 -0.0014 30 ethanol,aq 0.11508E-17 -17.9390 0.11470E-17 -17.9404 0.99677E+00 -0.0014 31 CO,aq 0.10910E-14 -14.9622 0.10910E-14 -14.9622 0.10000E+01 0.0000 32 CO2,aq 0.37618E-08 -8.4246 0.37497E-08 -8.4260 0.99677E+00 -0.0014 33 CO3-2 0.51715E-04 -4.2864 0.26608E-04 -4.5750 0.51451E+00 -0.2886 34 CaCO3,aq 0.24297E-07 -7.6144 0.24297E-07 -7.6144 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.51456E-10 -10.2886 0.42981E-10 -10.3667 0.83529E+00 -0.0782 36 CaCl+ 0.46965E-10 -10.3282 0.39229E-10 -10.4064 0.83529E+00 -0.0782 37 CaCl2,aq 0.31022E-14 -14.5083 0.31022E-14 -14.5083 0.10000E+01 0.0000 38 CaF+ 0.11942E-11 -11.9229 0.99749E-12 -12.0011 0.83529E+00 -0.0782 39 CaOH+ 0.81868E-07 -7.0869 0.68384E-07 -7.1650 0.83529E+00 -0.0782 40 CaSO4,aq 0.16658E-15 -15.7784 0.16658E-15 -15.7784 0.10000E+01 0.0000 41 HCl,aq 0.46293E-14 -14.3345 0.46293E-14 -14.3345 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18519E-18 -18.7324 0.15438E-18 -18.8114 0.83366E+00 -0.0790 48 FeCl+ 0.19738E-16 -16.7047 0.16487E-16 -16.7829 0.83529E+00 -0.0782 51 FeF+ 0.17960E-17 -17.7457 0.15002E-17 -17.8239 0.83529E+00 -0.0782 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16067E-10 -10.7941 0.13421E-10 -10.8722 0.83529E+00 -0.0782 55 HFeO2- 0.34911E-07 -7.4570 0.29104E-07 -7.5360 0.83366E+00 -0.0790 56 FeO+ 0.11261E-16 -16.9484 0.94059E-17 -17.0266 0.83529E+00 -0.0782 58 FeO2- 0.40076E-09 -9.3971 0.33410E-09 -9.4761 0.83366E+00 -0.0790 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11620E-04 -4.9348 0.11582E-04 -4.9362 0.99677E+00 -0.0014 61 KCl,aq 0.80807E-09 -9.0925 0.80807E-09 -9.0925 0.10000E+01 0.0000 63 KOH,aq 0.75367E-06 -6.1228 0.75367E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.17960E-13 -13.7457 0.14972E-13 -13.8247 0.83366E+00 -0.0790 65 MgCO3,aq 0.94843E-12 -12.0230 0.94843E-12 -12.0230 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.81879E-14 -14.0868 0.68393E-14 -14.1650 0.83529E+00 -0.0782 67 MgCl+ 0.66287E-14 -14.1786 0.55369E-14 -14.2567 0.83529E+00 -0.0782 68 MgF+ 0.68888E-15 -15.1619 0.57541E-15 -15.2400 0.83529E+00 -0.0782 69 MgOH+ 0.70547E-10 -10.1515 0.58927E-10 -10.2297 0.83529E+00 -0.0782 71 MnF+ 0.19025E-15 -15.7207 0.15892E-15 -15.7988 0.83529E+00 -0.0782 72 MnO,aq 0.18080E-08 -8.7428 0.18080E-08 -8.7428 0.10000E+01 0.0000 73 MnOH+ 0.47969E-09 -9.3190 0.40068E-09 -9.3972 0.83529E+00 -0.0782 74 MnO2-2 0.20244E-10 -10.6937 0.10416E-10 -10.9823 0.51451E+00 -0.2886 75 HMnO2- 0.20775E-09 -9.6825 0.17319E-09 -9.7615 0.83366E+00 -0.0790 78 MnCl+ 0.24679E-13 -13.6077 0.20614E-13 -13.6858 0.83529E+00 -0.0782 79 MnSO4,aq 0.20914E-19 -19.6796 0.20914E-19 -19.6796 0.10000E+01 0.0000 80 NaCl,aq 0.18714E-05 -5.7278 0.18714E-05 -5.7278 0.10000E+01 0.0000 81 NaF,aq 0.37262E-08 -8.4287 0.37262E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96037E-04 -4.0176 0.96037E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91480E-02 -2.0387 0.76123E-02 -2.1185 0.83212E+00 -0.0798 89 HPO3-2 0.15778E-14 -14.8020 0.81179E-15 -15.0906 0.51451E+00 -0.2886 91 H2PO3- 0.14821E-18 -18.8291 0.12355E-18 -18.9081 0.83366E+00 -0.0790 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37735E-10 -10.4233 0.31489E-10 -10.5018 0.83447E+00 -0.0786 94 PO4-3 0.10116E-08 -8.9950 0.24177E-09 -9.6166 0.23899E+00 -0.6216 98 HP2O7-3 0.89896E-18 -18.0463 0.20455E-18 -18.6892 0.22754E+00 -0.6429 99 P2O7-4 0.85891E-17 -17.0661 0.64383E-18 -18.1912 0.74959E-01 -1.1252 100 H2S,aq 0.10983E-06 -6.9593 0.10948E-06 -6.9607 0.99677E+00 -0.0014 101 S2-2 0.80990E-12 -12.0916 0.41670E-12 -12.3802 0.51451E+00 -0.2886 102 S3-2 0.10314E-19 -19.9866 0.53065E-20 -20.2752 0.51451E+00 -0.2886 107 SO3-2 0.20766E-16 -16.6827 0.10842E-16 -16.9649 0.52211E+00 -0.2822 108 HSO3- 0.61803E-19 -19.2090 0.51523E-19 -19.2880 0.83366E+00 -0.0790 109 HSO4- 0.63015E-18 -18.2006 0.52688E-18 -18.2783 0.83612E+00 -0.0777 111 S2O3-2 0.18005E-19 -19.7446 0.92636E-20 -20.0332 0.51451E+00 -0.2886 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9048326E-10 -.2194054E-01 -.2207531E+02 0.0000 2 H2O 0.1000000E+01 0.5550636E+02 0.9981803E+06 0.0000 3 Cl- 0.3992662E-03 0.4011385E-03 0.1419620E+02 6.6420 4 SO4-- 0.1396990E-10 -.1462702E-02 -.1402589E+03 9.0971 5 HCO3- 0.2769237E-04 0.1539233E-02 0.9375216E+02 5.4838 6 HS- 0.5597444E-03 0.2022556E-02 0.6677069E+02 6.7888 7 Al+++ 0.1054594E-28 0.5206151E-05 0.1402192E+00 0.7390 8 H4SiO4 0.6959590E-03 0.1331615E-01 0.1277604E+04 -3.1574 9 Ca++ 0.1423078E-06 0.2655746E-06 0.1062472E-01 13.1018 10 Mg++ 0.2226517E-10 0.9706959E-10 0.2355747E-05 9.2942 11 Fe++ 0.6136670E-13 0.3554271E-07 0.1981413E-02 6.7350 12 K+ 0.1603982E-03 0.1611527E-03 0.6290153E+01 6.2467 13 Na+ 0.2035455E-01 0.2280191E-01 0.5232764E+03 8.3493 14 Mn++ 0.1970575E-10 0.2535401E-08 0.1390415E-03 9.2420 15 F- 0.1127677E-05 0.1131405E-05 0.2145610E-01 4.0920 16 HPO4-- 0.4361096E-07 0.4466032E-07 0.4278808E-02 12.5915 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279143E+02 -.1089402E-01 -.8278053E+02 0.0000000E+00 2 H2O -.7160282E+01 0.2756028E+02 -.3472056E+02 0.0000000E+00 3 Cl- 0.1991752E-03 0.1991752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386421E+00 -.7262677E-03 0.1393684E+00 0.0000000E+00 5 HCO3- 0.7642670E-03 0.7642670E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383642E+00 0.1004249E-02 -.1393684E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2584982E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6611795E-02 0.5205729E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1318644E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4819745E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1764783E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8001627E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1132171E-01 0.6265055E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1258889E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4256000E-05 0.5617705E-06 0.3694229E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2217495E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.2139E-13 Mass of aqueous solution: 0.497412E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0103900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.797 1641. 3.215 30.05 630.0 andradite 0.5575 -0.254 283.3 2.452 5.186 73.60 grossular 0.1350 -0.870 60.81 1.784 1.113 16.92 apatite-OH 0.9859E-02 -2.006 4.952 0.695 0.9066E-01 1.574 apatite-F 0.3694E-05 -5.432 0.1863E-02 -2.730 0.3411E-04 0.5820E-03 clinochlore 0.7096 -0.149 394.4 2.596 7.221 150.0 daphnite 0.2054 -0.687 146.6 2.166 2.683 44.42 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2428 -0.615 52.59 1.721 0.9627 16.07 hedenbergite 0.6297E-01 -1.201 15.62 1.194 0.2860 4.279 microcline 0.9316 -0.031 259.3 2.414 4.747 101.3 stilbite 3.220 0.508 2269. 3.356 41.55 1058. stilpnomelane-Fe 0.2598 -0.585 280.0 2.447 5.126 96.72 tr.625ac.25prg.125 0.4896E-01 -1.310 41.85 1.622 0.7662 13.47 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.341125 g Volume = 2210.806522 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0103900 moles log = -1.9834 Original solution: 1000.0103000 g Original solution / Rock added: 96247.38 (Water/Rock Ratio), log = 4.9834 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 3.1842 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3241E+00 0.9746 0.1006E+01 0.1032E+01 CO2,gas 0.1267E-06 0.9947 0.4012E-06 0.4033E-06 CH4,gas 0.6711E+00 1.0023 0.2142E+01 0.2137E+01 H2,gas 0.4767E-02 1.0017 0.1521E-01 0.1518E-01 H2S,gas 0.9569E-06 0.9877 0.3009E-05 0.3047E-05 S2,gas 0.4617E-27 1.0000 0.1470E-26 0.1470E-26 CO,gas 0.5106E-12 1.0000 0.1626E-11 0.1626E-11 SO3,gas 0.4927E-47 1.0000 0.1569E-46 0.1569E-46 SO2,gas 0.2915E-26 1.0000 0.9282E-26 0.9282E-26 HF,gas 0.3759E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2565E-17 1.0000 0.8169E-17 0.8169E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.76 -8.10 -2.699 0.13823E+05 -6.397 3 CH4,gas 4.54 3.18 -1.37 -0.342 0.23362E+04 0.331 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.45 -7.22 -3.610 0.12329E+05 -5.522 6 S2,gas -7.34 -35.87 -28.53 -4.389 0.48717E+05 -26.833 7 CO,gas 3.21 -10.27 -13.49 -4.150 0.23030E+05 -11.789 8 SO3,gas 17.12 -31.38 -48.50 -12.126 0.82818E+05 -46.804 9 SO2,gas 0.83 -26.90 -27.73 -7.395 0.47350E+05 -26.032 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.60 -18.79 -9.393 0.32078E+05 -17.088 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80687E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93629E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.65 -2.62 -0.873 0.44744E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.65 -2.47 -0.822 0.42101E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65542E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.79 -2.69 -0.768 0.45892E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.79 -2.24 -0.641 0.38315E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82234E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.65 -3.40 -0.801 0.58094E+04 146 pyrrhotite -4.26 -6.72 -2.46 -0.818 0.41926E+04 147 pyrrhotiteFe0.875 -6.02 -8.11 -2.10 -0.771 0.35798E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22437E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.51 -4.54 -1.512 0.77475E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23240E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47112E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.72 -2.30 -0.768 0.39354E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.21 -3.23 -1.077 0.55166E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0103900 MOLES New total amount of reactant added: 0.0107900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8652E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0107900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7160E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1052901E-01 Osmotic coef. = 0.9149 True ionic strength = .2058526E-01 Chg. balance for total moles = -.8652E-10 Max. difference allowed = 0.2015E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90554E-10 -10.0431 0.75954E-10 -10.1195 0.83876E+00 -0.0764 2 H2O 0.99997E+00 0.0000 0.99997E+00 0.0000 3 Cl- 0.40399E-03 -3.3936 0.33677E-03 -3.4727 0.83361E+00 -0.0790 4 SO4-- 0.14450E-10 -10.8401 0.74491E-11 -11.1279 0.51551E+00 -0.2878 5 HCO3- 0.28722E-04 -4.5418 0.23979E-04 -4.6202 0.83486E+00 -0.0784 6 HS- 0.57931E-03 -3.2371 0.48299E-03 -3.3161 0.83373E+00 -0.0790 7 Al+++ 0.10575E-28 -28.9757 0.24024E-29 -29.6194 0.22718E+00 -0.6436 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14255E-06 -6.8460 0.72933E-07 -7.1371 0.51164E+00 -0.2910 10 Mg++ 0.22303E-10 -10.6516 0.11358E-10 -10.9447 0.50925E+00 -0.2931 11 Fe++ 0.61471E-13 -13.2113 0.31339E-13 -13.5039 0.50982E+00 -0.2926 12 K+ 0.16052E-03 -3.7945 0.13405E-03 -3.8727 0.83506E+00 -0.0783 13 Na+ 0.20371E-01 -1.6910 0.16978E-01 -1.7701 0.83345E+00 -0.0791 14 Mn++ 0.19740E-10 -10.7047 0.10072E-10 -10.9969 0.51025E+00 -0.2922 15 F- 0.11269E-05 -5.9481 0.93744E-06 -6.0281 0.83185E+00 -0.0800 16 HPO4-- 0.43558E-07 -7.3609 0.22457E-07 -7.6486 0.51558E+00 -0.2877 18 HSiO3- 0.10264E-01 -1.9887 0.85560E-02 -2.0677 0.83361E+00 -0.0790 19 Ca(HSiO3)+ 0.17015E-07 -7.7692 0.14211E-07 -7.8474 0.83524E+00 -0.0782 20 Mg(HSiO3)+ 0.32975E-11 -11.4818 0.27542E-11 -11.5600 0.83524E+00 -0.0782 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67827E-16 -16.1686 0.56652E-16 -16.2468 0.83524E+00 -0.0782 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.52025E-05 -5.2838 0.43289E-05 -5.3636 0.83207E+00 -0.0798 26 CH4,aq 0.15151E-02 -2.8196 0.15102E-02 -2.8210 0.99678E+00 -0.0014 27 C2H6,aq 0.33773E-10 -10.4714 0.33665E-10 -10.4728 0.99678E+00 -0.0014 28 C3H8,aq 0.17381E-16 -16.7599 0.17325E-16 -16.7613 0.99678E+00 -0.0014 30 ethanol,aq 0.12396E-17 -17.9067 0.12356E-17 -17.9081 0.99678E+00 -0.0014 31 CO,aq 0.11324E-14 -14.9460 0.11324E-14 -14.9460 0.10000E+01 0.0000 32 CO2,aq 0.39043E-08 -8.4085 0.38918E-08 -8.4099 0.99678E+00 -0.0014 33 CO3-2 0.53609E-04 -4.2708 0.27576E-04 -4.5595 0.51439E+00 -0.2887 34 CaCO3,aq 0.25218E-07 -7.5983 0.25218E-07 -7.5983 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.53448E-10 -10.2721 0.44642E-10 -10.3503 0.83524E+00 -0.0782 36 CaCl+ 0.47589E-10 -10.3225 0.39749E-10 -10.4007 0.83524E+00 -0.0782 37 CaCl2,aq 0.31803E-14 -14.4975 0.31803E-14 -14.4975 0.10000E+01 0.0000 38 CaF+ 0.11951E-11 -11.9226 0.99822E-12 -12.0008 0.83524E+00 -0.0782 39 CaOH+ 0.81933E-07 -7.0865 0.68434E-07 -7.1647 0.83524E+00 -0.0782 40 CaSO4,aq 0.17252E-15 -15.7632 0.17252E-15 -15.7632 0.10000E+01 0.0000 41 HCl,aq 0.46872E-14 -14.3291 0.46872E-14 -14.3291 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18506E-18 -18.7327 0.15427E-18 -18.8117 0.83361E+00 -0.0790 48 FeCl+ 0.20000E-16 -16.6990 0.16705E-16 -16.7771 0.83524E+00 -0.0782 51 FeF+ 0.17974E-17 -17.7454 0.15013E-17 -17.8235 0.83524E+00 -0.0782 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16080E-10 -10.7937 0.13430E-10 -10.8719 0.83524E+00 -0.0782 55 HFeO2- 0.34888E-07 -7.4573 0.29083E-07 -7.5364 0.83361E+00 -0.0790 56 FeO+ 0.11270E-16 -16.9481 0.94128E-17 -17.0263 0.83524E+00 -0.0782 58 FeO2- 0.40049E-09 -9.3974 0.33385E-09 -9.4764 0.83361E+00 -0.0790 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11620E-04 -4.9348 0.11582E-04 -4.9362 0.99678E+00 -0.0014 61 KCl,aq 0.81818E-09 -9.0872 0.81818E-09 -9.0872 0.10000E+01 0.0000 63 KOH,aq 0.75367E-06 -6.1228 0.75367E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.18588E-13 -13.7308 0.15495E-13 -13.8098 0.83361E+00 -0.0790 65 MgCO3,aq 0.98436E-12 -12.0068 0.98436E-12 -12.0068 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.85048E-14 -14.0703 0.71036E-14 -14.1485 0.83524E+00 -0.0782 67 MgCl+ 0.67169E-14 -14.1728 0.56102E-14 -14.2510 0.83524E+00 -0.0782 68 MgF+ 0.68942E-15 -15.1615 0.57583E-15 -15.2397 0.83524E+00 -0.0782 69 MgOH+ 0.70603E-10 -10.1512 0.58970E-10 -10.2294 0.83524E+00 -0.0782 71 MnF+ 0.19041E-15 -15.7203 0.15904E-15 -15.7985 0.83524E+00 -0.0782 72 MnO,aq 0.18081E-08 -8.7428 0.18081E-08 -8.7428 0.10000E+01 0.0000 73 MnOH+ 0.48009E-09 -9.3187 0.40099E-09 -9.3969 0.83524E+00 -0.0782 74 MnO2-2 0.20220E-10 -10.6942 0.10401E-10 -10.9829 0.51439E+00 -0.2887 75 HMnO2- 0.20762E-09 -9.6827 0.17307E-09 -9.7618 0.83361E+00 -0.0790 78 MnCl+ 0.25008E-13 -13.6019 0.20888E-13 -13.6801 0.83524E+00 -0.0782 79 MnSO4,aq 0.21660E-19 -19.6643 0.21660E-19 -19.6643 0.10000E+01 0.0000 80 NaCl,aq 0.18948E-05 -5.7224 0.18948E-05 -5.7224 0.10000E+01 0.0000 81 NaF,aq 0.37262E-08 -8.4287 0.37262E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96037E-04 -4.0176 0.96037E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91419E-02 -2.0390 0.76067E-02 -2.1188 0.83207E+00 -0.0798 89 HPO3-2 0.15759E-14 -14.8025 0.81061E-15 -15.0912 0.51439E+00 -0.2887 91 H2PO3- 0.14811E-18 -18.8294 0.12346E-18 -18.9085 0.83361E+00 -0.0790 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37710E-10 -10.4235 0.31466E-10 -10.5022 0.83442E+00 -0.0786 94 PO4-3 0.10099E-08 -8.9957 0.24124E-09 -9.6176 0.23887E+00 -0.6218 98 HP2O7-3 0.89747E-18 -18.0470 0.20410E-18 -18.6902 0.22742E+00 -0.6432 99 P2O7-4 0.85720E-17 -17.0669 0.64196E-18 -18.1925 0.74890E-01 -1.1256 100 H2S,aq 0.11374E-06 -6.9441 0.11338E-06 -6.9455 0.99678E+00 -0.0014 101 S2-2 0.86761E-12 -12.0617 0.44629E-12 -12.3504 0.51439E+00 -0.2887 102 S3-2 0.11442E-19 -19.9415 0.58858E-20 -20.2302 0.51439E+00 -0.2887 107 SO3-2 0.21479E-16 -16.6680 0.11212E-16 -16.9503 0.52199E+00 -0.2823 108 HSO3- 0.63963E-19 -19.1941 0.53320E-19 -19.2731 0.83361E+00 -0.0790 109 HSO4- 0.65217E-18 -18.1856 0.54526E-18 -18.2634 0.83607E+00 -0.0778 111 S2O3-2 0.19288E-19 -19.7147 0.99213E-20 -20.0034 0.51439E+00 -0.2887 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9055426E-10 -.2192944E-01 -.2206410E+02 0.0000 2 H2O 0.1000000E+01 0.5550641E+02 0.9981797E+06 0.0000 3 Cl- 0.4039899E-03 0.4058856E-03 0.1436418E+02 6.6468 4 SO4-- 0.1445012E-10 -.1517998E-02 -.1455611E+03 9.1110 5 HCO3- 0.2872243E-04 0.1597454E-02 0.9729818E+02 5.4993 6 HS- 0.5793081E-03 0.2097420E-02 0.6924206E+02 6.8034 7 Al+++ 0.1057463E-28 0.5202681E-05 0.1401255E+00 0.7390 8 H4SiO4 0.6959583E-03 0.1330927E-01 0.1276943E+04 -3.1574 9 Ca++ 0.1425490E-06 0.2668170E-06 0.1067440E-01 13.1018 10 Mg++ 0.2230299E-10 0.9720590E-10 0.2359051E-05 9.2942 11 Fe++ 0.6147093E-13 0.3551908E-07 0.1980093E-02 6.7350 12 K+ 0.1605240E-03 0.1612785E-03 0.6295056E+01 6.2467 13 Na+ 0.2037055E-01 0.2281793E-01 0.5236431E+03 8.3493 14 Mn++ 0.1973997E-10 0.2535746E-08 0.1390602E-03 9.2420 15 F- 0.1126924E-05 0.1130652E-05 0.2144178E-01 4.0914 16 HPO4-- 0.4355755E-07 0.4460517E-07 0.4273518E-02 12.5903 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279139E+02 -.1088867E-01 -.8278050E+02 0.0000000E+00 2 H2O -.7159955E+01 0.2756071E+02 -.3472066E+02 0.0000000E+00 3 Cl- 0.2015352E-03 0.2015352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386440E+00 -.7537348E-03 0.1393978E+00 0.0000000E+00 5 HCO3- 0.7931870E-03 0.7931870E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383563E+00 0.1041436E-02 -.1393978E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2583297E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6608480E-02 0.5205730E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1324832E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4826584E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1763636E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8007995E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1132983E-01 0.6265047E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1259079E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4416000E-05 0.5614049E-06 0.3854595E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2214790E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.3206E-14 Mass of aqueous solution: 0.497420E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0107900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.796 1641. 3.215 30.05 630.0 andradite 0.5576 -0.254 283.4 2.452 5.187 73.62 grossular 0.1350 -0.870 60.82 1.784 1.113 16.92 apatite-OH 0.9859E-02 -2.006 4.952 0.695 0.9066E-01 1.574 apatite-F 0.3855E-05 -5.414 0.1944E-02 -2.711 0.3559E-04 0.6073E-03 clinochlore 0.7096 -0.149 394.4 2.596 7.220 150.0 daphnite 0.2054 -0.687 146.6 2.166 2.683 44.41 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2421 -0.616 52.42 1.720 0.9597 16.02 hedenbergite 0.6278E-01 -1.202 15.57 1.192 0.2851 4.266 microcline 0.9316 -0.031 259.3 2.414 4.747 101.3 stilbite 3.220 0.508 2269. 3.356 41.55 1059. stilpnomelane-Fe 0.2597 -0.586 279.9 2.447 5.125 96.70 tr.625ac.25prg.125 0.4921E-01 -1.308 42.06 1.624 0.7701 13.54 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.341247 g Volume = 2210.807626 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0107900 moles log = -1.9670 Original solution: 1000.0103000 g Original solution / Rock added: 92679.36 (Water/Rock Ratio), log = 4.9670 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 3.2657 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3161E+00 0.9744 0.1006E+01 0.1032E+01 CO2,gas 0.1282E-06 0.9944 0.4164E-06 0.4187E-06 CH4,gas 0.6792E+00 1.0022 0.2223E+01 0.2218E+01 H2,gas 0.4648E-02 1.0017 0.1521E-01 0.1518E-01 H2S,gas 0.9666E-06 0.9874 0.3117E-05 0.3157E-05 S2,gas 0.4829E-27 1.0000 0.1577E-26 0.1577E-26 CO,gas 0.5167E-12 1.0000 0.1687E-11 0.1687E-11 SO3,gas 0.4976E-47 1.0000 0.1625E-46 0.1625E-46 SO2,gas 0.2944E-26 1.0000 0.9613E-26 0.9613E-26 HF,gas 0.3665E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2533E-17 1.0000 0.8271E-17 0.8271E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.74 -8.08 -2.693 0.13795E+05 -6.381 3 CH4,gas 4.54 3.19 -1.35 -0.338 0.23086E+04 0.347 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.44 -7.21 -3.603 0.12303E+05 -5.506 6 S2,gas -7.34 -35.84 -28.50 -4.385 0.48665E+05 -26.802 7 CO,gas 3.21 -10.26 -13.47 -4.145 0.23003E+05 -11.773 8 SO3,gas 17.12 -31.37 -48.49 -12.122 0.82792E+05 -46.789 9 SO2,gas 0.83 -26.88 -27.72 -7.391 0.47325E+05 -26.017 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.59 -18.78 -9.391 0.32069E+05 -17.082 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80686E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93629E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.64 -2.60 -0.868 0.44468E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.64 -2.45 -0.817 0.41826E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65541E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.77 -2.67 -0.763 0.45616E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.77 -2.23 -0.637 0.38039E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82234E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.62 -3.37 -0.793 0.57575E+04 146 pyrrhotite -4.26 -6.70 -2.44 -0.813 0.41666E+04 147 pyrrhotiteFe0.875 -6.02 -8.10 -2.08 -0.765 0.35538E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22437E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.50 -4.52 -1.507 0.77199E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23240E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47112E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.70 -2.29 -0.763 0.39094E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.19 -3.22 -1.072 0.54906E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0107900 MOLES New total amount of reactant added: 0.0111900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8652E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0111900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7160E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1049537E-01 Osmotic coef. = 0.9153 True ionic strength = .2060328E-01 Chg. balance for total moles = -.8652E-10 Max. difference allowed = 0.2039E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90625E-10 -10.0428 0.76009E-10 -10.1191 0.83872E+00 -0.0764 2 H2O 0.99997E+00 0.0000 0.99997E+00 0.0000 3 Cl- 0.40871E-03 -3.3886 0.34069E-03 -3.4676 0.83356E+00 -0.0791 4 SO4-- 0.14930E-10 -10.8259 0.76946E-11 -11.1138 0.51539E+00 -0.2879 5 HCO3- 0.29751E-04 -4.5265 0.24836E-04 -4.6049 0.83481E+00 -0.0784 6 HS- 0.59887E-03 -3.2227 0.49927E-03 -3.3017 0.83368E+00 -0.0790 7 Al+++ 0.10603E-28 -28.9746 0.24077E-29 -29.6184 0.22706E+00 -0.6439 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14279E-06 -6.8453 0.73040E-07 -7.1364 0.51152E+00 -0.2911 10 Mg++ 0.22341E-10 -10.6509 0.11374E-10 -10.9441 0.50912E+00 -0.2932 11 Fe++ 0.61575E-13 -13.2106 0.31385E-13 -13.5033 0.50969E+00 -0.2927 12 K+ 0.16065E-03 -3.7941 0.13414E-03 -3.8724 0.83501E+00 -0.0783 13 Na+ 0.20387E-01 -1.6907 0.16990E-01 -1.7698 0.83340E+00 -0.0791 14 Mn++ 0.19774E-10 -10.7039 0.10087E-10 -10.9962 0.51013E+00 -0.2923 15 F- 0.11262E-05 -5.9484 0.93675E-06 -6.0284 0.83180E+00 -0.0800 16 HPO4-- 0.43504E-07 -7.3615 0.22425E-07 -7.6493 0.51546E+00 -0.2878 18 HSiO3- 0.10257E-01 -1.9890 0.85498E-02 -2.0680 0.83356E+00 -0.0791 19 Ca(HSiO3)+ 0.17028E-07 -7.7688 0.14222E-07 -7.8470 0.83519E+00 -0.0782 20 Mg(HSiO3)+ 0.33001E-11 -11.4815 0.27562E-11 -11.5597 0.83519E+00 -0.0782 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67880E-16 -16.1683 0.56693E-16 -16.2465 0.83519E+00 -0.0782 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51991E-05 -5.2841 0.43257E-05 -5.3639 0.83202E+00 -0.0799 26 CH4,aq 0.15704E-02 -2.8040 0.15654E-02 -2.8054 0.99680E+00 -0.0014 27 C2H6,aq 0.36284E-10 -10.4403 0.36168E-10 -10.4417 0.99680E+00 -0.0014 28 C3H8,aq 0.19355E-16 -16.7132 0.19293E-16 -16.7146 0.99680E+00 -0.0014 30 ethanol,aq 0.13318E-17 -17.8756 0.13275E-17 -17.8770 0.99680E+00 -0.0014 31 CO,aq 0.11737E-14 -14.9304 0.11737E-14 -14.9304 0.10000E+01 0.0000 32 CO2,aq 0.40469E-08 -8.3929 0.40339E-08 -8.3943 0.99680E+00 -0.0014 33 CO3-2 0.55498E-04 -4.2557 0.28541E-04 -4.5445 0.51427E+00 -0.2888 34 CaCO3,aq 0.26139E-07 -7.5827 0.26139E-07 -7.5827 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.55443E-10 -10.2562 0.46306E-10 -10.3344 0.83519E+00 -0.0782 36 CaCl+ 0.48216E-10 -10.3168 0.40270E-10 -10.3950 0.83519E+00 -0.0782 37 CaCl2,aq 0.32594E-14 -14.4869 0.32594E-14 -14.4869 0.10000E+01 0.0000 38 CaF+ 0.11961E-11 -11.9222 0.99894E-12 -12.0005 0.83519E+00 -0.0782 39 CaOH+ 0.81997E-07 -7.0862 0.68483E-07 -7.1644 0.83519E+00 -0.0782 40 CaSO4,aq 0.17847E-15 -15.7484 0.17847E-15 -15.7484 0.10000E+01 0.0000 41 HCl,aq 0.47452E-14 -14.3237 0.47452E-14 -14.3237 0.10000E+01 0.0000 45 HF,aq 0.48743E-12 -12.3121 0.48743E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18494E-18 -18.7330 0.15416E-18 -18.8120 0.83356E+00 -0.0791 48 FeCl+ 0.20264E-16 -16.6933 0.16924E-16 -16.7715 0.83519E+00 -0.0782 51 FeF+ 0.17988E-17 -17.7450 0.15024E-17 -17.8232 0.83519E+00 -0.0782 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16092E-10 -10.7934 0.13440E-10 -10.8716 0.83519E+00 -0.0782 55 HFeO2- 0.34865E-07 -7.4576 0.29062E-07 -7.5367 0.83356E+00 -0.0791 56 FeO+ 0.11278E-16 -16.9478 0.94196E-17 -17.0260 0.83519E+00 -0.0782 58 FeO2- 0.40023E-09 -9.3977 0.33361E-09 -9.4768 0.83356E+00 -0.0791 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11619E-04 -4.9348 0.11582E-04 -4.9362 0.99680E+00 -0.0014 61 KCl,aq 0.82830E-09 -9.0818 0.82830E-09 -9.0818 0.10000E+01 0.0000 63 KOH,aq 0.75367E-06 -6.1228 0.75367E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.19215E-13 -13.7164 0.16017E-13 -13.7954 0.83356E+00 -0.0791 65 MgCO3,aq 0.10203E-11 -11.9913 0.10203E-11 -11.9913 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.88223E-14 -14.0544 0.73683E-14 -14.1326 0.83519E+00 -0.0782 67 MgCl+ 0.68053E-14 -14.1672 0.56837E-14 -14.2454 0.83519E+00 -0.0782 68 MgF+ 0.68996E-15 -15.1612 0.57625E-15 -15.2394 0.83519E+00 -0.0782 69 MgOH+ 0.70658E-10 -10.1508 0.59013E-10 -10.2291 0.83519E+00 -0.0782 71 MnF+ 0.19057E-15 -15.7199 0.15916E-15 -15.7982 0.83519E+00 -0.0782 72 MnO,aq 0.18081E-08 -8.7428 0.18081E-08 -8.7428 0.10000E+01 0.0000 73 MnOH+ 0.48048E-09 -9.3183 0.40130E-09 -9.3965 0.83519E+00 -0.0782 74 MnO2-2 0.20196E-10 -10.6947 0.10386E-10 -10.9835 0.51427E+00 -0.2888 75 HMnO2- 0.20749E-09 -9.6830 0.17295E-09 -9.7621 0.83356E+00 -0.0791 78 MnCl+ 0.25339E-13 -13.5962 0.21163E-13 -13.6744 0.83519E+00 -0.0782 79 MnSO4,aq 0.22408E-19 -19.6496 0.22408E-19 -19.6496 0.10000E+01 0.0000 80 NaCl,aq 0.19183E-05 -5.7171 0.19183E-05 -5.7171 0.10000E+01 0.0000 81 NaF,aq 0.37261E-08 -8.4287 0.37261E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96036E-04 -4.0176 0.96036E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91358E-02 -2.0393 0.76012E-02 -2.1191 0.83202E+00 -0.0799 89 HPO3-2 0.15739E-14 -14.8030 0.80943E-15 -15.0918 0.51427E+00 -0.2888 91 H2PO3- 0.14801E-18 -18.8297 0.12337E-18 -18.9088 0.83356E+00 -0.0791 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37685E-10 -10.4238 0.31443E-10 -10.5025 0.83437E+00 -0.0786 94 PO4-3 0.10082E-08 -8.9965 0.24071E-09 -9.6185 0.23875E+00 -0.6221 98 HP2O7-3 0.89598E-18 -18.0477 0.20366E-18 -18.6911 0.22730E+00 -0.6434 99 P2O7-4 0.85549E-17 -17.0678 0.64009E-18 -18.1938 0.74822E-01 -1.1260 100 H2S,aq 0.11766E-06 -6.9294 0.11729E-06 -6.9308 0.99680E+00 -0.0014 101 S2-2 0.92730E-12 -12.0328 0.47688E-12 -12.3216 0.51427E+00 -0.2888 102 S3-2 0.12651E-19 -19.8979 0.65060E-20 -20.1867 0.51427E+00 -0.2888 107 SO3-2 0.22192E-16 -16.6538 0.11582E-16 -16.9362 0.52188E+00 -0.2824 108 HSO3- 0.66123E-19 -19.1796 0.55118E-19 -19.2587 0.83356E+00 -0.0791 109 HSO4- 0.67419E-18 -18.1712 0.56364E-18 -18.2490 0.83602E+00 -0.0778 111 S2O3-2 0.20615E-19 -19.6858 0.10601E-19 -19.9746 0.51427E+00 -0.2888 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9062528E-10 -.2191835E-01 -.2205291E+02 0.0000 2 H2O 0.1000000E+01 0.5550647E+02 0.9981791E+06 0.0000 3 Cl- 0.4087134E-03 0.4106325E-03 0.1453214E+02 6.6515 4 SO4-- 0.1492978E-10 -.1573299E-02 -.1508636E+03 9.1245 5 HCO3- 0.2975122E-04 0.1655674E-02 0.1008441E+03 5.5142 6 HS- 0.5988711E-03 0.2172288E-02 0.7171354E+02 6.8175 7 Al+++ 0.1060339E-28 0.5199215E-05 0.1400320E+00 0.7390 8 H4SiO4 0.6959575E-03 0.1330241E-01 0.1276282E+04 -3.1574 9 Ca++ 0.1427906E-06 0.2680597E-06 0.1072410E-01 13.1018 10 Mg++ 0.2234085E-10 0.9733505E-10 0.2362182E-05 9.2942 11 Fe++ 0.6157528E-13 0.3549549E-07 0.1978775E-02 6.7350 12 K+ 0.1606500E-03 0.1614045E-03 0.6299961E+01 6.2467 13 Na+ 0.2038655E-01 0.2283395E-01 0.5240099E+03 8.3493 14 Mn++ 0.1977423E-10 0.2536092E-08 0.1390789E-03 9.2420 15 F- 0.1126172E-05 0.1129900E-05 0.2142749E-01 4.0908 16 HPO4-- 0.4350423E-07 0.4455013E-07 0.4268237E-02 12.5890 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279134E+02 -.1088332E-01 -.8278046E+02 0.0000000E+00 2 H2O -.7159627E+01 0.2756114E+02 -.3472077E+02 0.0000000E+00 3 Cl- 0.2038952E-03 0.2038952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386460E+00 -.7812047E-03 0.1394272E+00 0.0000000E+00 5 HCO3- 0.8221070E-03 0.8221070E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383485E+00 0.1078626E-02 -.1394272E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2581614E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6605169E-02 0.5205730E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1331022E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4833067E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1762491E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8014365E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1133795E-01 0.6265039E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1259269E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4576000E-05 0.5610397E-06 0.4014960E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2212089E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1198E-13 Mass of aqueous solution: 0.497428E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0111900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.796 1641. 3.215 30.05 630.0 andradite 0.5577 -0.254 283.4 2.452 5.189 73.63 grossular 0.1350 -0.870 60.83 1.784 1.114 16.93 apatite-OH 0.9859E-02 -2.006 4.952 0.695 0.9066E-01 1.574 apatite-F 0.4015E-05 -5.396 0.2025E-02 -2.694 0.3707E-04 0.6325E-03 clinochlore 0.7095 -0.149 394.4 2.596 7.220 150.0 daphnite 0.2054 -0.687 146.6 2.166 2.683 44.41 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2413 -0.617 52.25 1.718 0.9566 15.97 hedenbergite 0.6258E-01 -1.204 15.53 1.191 0.2842 4.252 microcline 0.9317 -0.031 259.3 2.414 4.747 101.3 stilbite 3.220 0.508 2269. 3.356 41.55 1059. stilpnomelane-Fe 0.2596 -0.586 279.9 2.447 5.124 96.68 tr.625ac.25prg.125 0.4946E-01 -1.306 42.28 1.626 0.7740 13.61 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.341369 g Volume = 2210.808729 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0111900 moles log = -1.9512 Original solution: 1000.0103000 g Original solution / Rock added: 89366.43 (Water/Rock Ratio), log = 4.9512 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 3.3472 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3085E+00 0.9742 0.1006E+01 0.1033E+01 CO2,gas 0.1297E-06 0.9942 0.4316E-06 0.4341E-06 CH4,gas 0.6870E+00 1.0020 0.2304E+01 0.2299E+01 H2,gas 0.4535E-02 1.0018 0.1521E-01 0.1518E-01 H2S,gas 0.9758E-06 0.9871 0.3224E-05 0.3266E-05 S2,gas 0.5041E-27 1.0000 0.1687E-26 0.1687E-26 CO,gas 0.5225E-12 1.0000 0.1749E-11 0.1749E-11 SO3,gas 0.5022E-47 1.0000 0.1681E-46 0.1681E-46 SO2,gas 0.2971E-26 1.0000 0.9944E-26 0.9944E-26 HF,gas 0.3576E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2501E-17 1.0000 0.8373E-17 0.8373E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.72 -8.06 -2.688 0.13769E+05 -6.365 3 CH4,gas 4.54 3.21 -1.34 -0.334 0.22820E+04 0.363 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.42 -7.19 -3.595 0.12278E+05 -5.492 6 S2,gas -7.34 -35.81 -28.47 -4.380 0.48615E+05 -26.773 7 CO,gas 3.21 -10.24 -13.46 -4.140 0.22976E+05 -11.757 8 SO3,gas 17.12 -31.35 -48.47 -12.118 0.82767E+05 -46.774 9 SO2,gas 0.83 -26.87 -27.70 -7.387 0.47299E+05 -26.002 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.59 -18.78 -9.388 0.32060E+05 -17.077 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80686E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93629E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.62 -2.59 -0.863 0.44202E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.62 -2.43 -0.811 0.41560E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65541E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.76 -2.66 -0.759 0.45351E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.76 -2.21 -0.632 0.37773E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82233E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.59 -3.34 -0.786 0.57072E+04 146 pyrrhotite -4.26 -6.69 -2.43 -0.808 0.41415E+04 147 pyrrhotiteFe0.875 -6.02 -8.08 -2.07 -0.760 0.35287E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22437E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.48 -4.51 -1.502 0.76933E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23239E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47111E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.69 -2.27 -0.758 0.38843E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.18 -3.20 -1.067 0.54654E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0111900 MOLES New total amount of reactant added: 0.0115900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8652E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0115900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4965E+00 Moles total = -.7159E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1046173E-01 Osmotic coef. = 0.9156 True ionic strength = .2062130E-01 Chg. balance for total moles = -.8652E-10 Max. difference allowed = 0.2063E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90696E-10 -10.0424 0.76064E-10 -10.1188 0.83867E+00 -0.0764 2 H2O 0.99997E+00 0.0000 0.99997E+00 0.0000 3 Cl- 0.41344E-03 -3.3836 0.34460E-03 -3.4627 0.83351E+00 -0.0791 4 SO4-- 0.15409E-10 -10.8122 0.79397E-11 -11.1002 0.51527E+00 -0.2880 5 HCO3- 0.30779E-04 -4.5117 0.25693E-04 -4.5902 0.83476E+00 -0.0784 6 HS- 0.61843E-03 -3.2087 0.51555E-03 -3.2877 0.83363E+00 -0.0790 7 Al+++ 0.10632E-28 -28.9734 0.24129E-29 -29.6175 0.22694E+00 -0.6441 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14303E-06 -6.8446 0.73146E-07 -7.1358 0.51140E+00 -0.2912 10 Mg++ 0.22379E-10 -10.6502 0.11391E-10 -10.9434 0.50900E+00 -0.2933 11 Fe++ 0.61680E-13 -13.2099 0.31430E-13 -13.5027 0.50957E+00 -0.2928 12 K+ 0.16078E-03 -3.7938 0.13424E-03 -3.8721 0.83496E+00 -0.0783 13 Na+ 0.20403E-01 -1.6903 0.17003E-01 -1.7695 0.83335E+00 -0.0792 14 Mn++ 0.19809E-10 -10.7031 0.10102E-10 -10.9956 0.51000E+00 -0.2924 15 F- 0.11254E-05 -5.9487 0.93607E-06 -6.0287 0.83175E+00 -0.0800 16 HPO4-- 0.43451E-07 -7.3620 0.22392E-07 -7.6499 0.51534E+00 -0.2879 18 HSiO3- 0.10250E-01 -1.9893 0.85436E-02 -2.0684 0.83351E+00 -0.0791 19 Ca(HSiO3)+ 0.17041E-07 -7.7685 0.14232E-07 -7.8467 0.83514E+00 -0.0782 20 Mg(HSiO3)+ 0.33027E-11 -11.4811 0.27582E-11 -11.5594 0.83514E+00 -0.0782 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67934E-16 -16.1679 0.56734E-16 -16.2462 0.83514E+00 -0.0782 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51956E-05 -5.2844 0.43226E-05 -5.3643 0.83197E+00 -0.0799 26 CH4,aq 0.16257E-02 -2.7890 0.16205E-02 -2.7903 0.99681E+00 -0.0014 27 C2H6,aq 0.38885E-10 -10.4102 0.38761E-10 -10.4116 0.99681E+00 -0.0014 28 C3H8,aq 0.21473E-16 -16.6681 0.21405E-16 -16.6695 0.99681E+00 -0.0014 30 ethanol,aq 0.14272E-17 -17.8455 0.14227E-17 -17.8469 0.99681E+00 -0.0014 31 CO,aq 0.12151E-14 -14.9154 0.12151E-14 -14.9154 0.10000E+01 0.0000 32 CO2,aq 0.41894E-08 -8.3778 0.41760E-08 -8.3792 0.99681E+00 -0.0014 33 CO3-2 0.57383E-04 -4.2412 0.29503E-04 -4.5301 0.51415E+00 -0.2889 34 CaCO3,aq 0.27060E-07 -7.5677 0.27060E-07 -7.5677 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.57441E-10 -10.2408 0.47972E-10 -10.3190 0.83514E+00 -0.0782 36 CaCl+ 0.48844E-10 -10.3112 0.40792E-10 -10.3894 0.83514E+00 -0.0782 37 CaCl2,aq 0.33396E-14 -14.4763 0.33396E-14 -14.4763 0.10000E+01 0.0000 38 CaF+ 0.11970E-11 -11.9219 0.99967E-12 -12.0001 0.83514E+00 -0.0782 39 CaOH+ 0.82062E-07 -7.0859 0.68533E-07 -7.1641 0.83514E+00 -0.0782 40 CaSO4,aq 0.18442E-15 -15.7342 0.18442E-15 -15.7342 0.10000E+01 0.0000 41 HCl,aq 0.48032E-14 -14.3185 0.48032E-14 -14.3185 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18482E-18 -18.7333 0.15405E-18 -18.8123 0.83351E+00 -0.0791 48 FeCl+ 0.20528E-16 -16.6877 0.17144E-16 -16.7659 0.83514E+00 -0.0782 51 FeF+ 0.18002E-17 -17.7447 0.15035E-17 -17.8229 0.83514E+00 -0.0782 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16105E-10 -10.7930 0.13450E-10 -10.8713 0.83514E+00 -0.0782 55 HFeO2- 0.34841E-07 -7.4579 0.29041E-07 -7.5370 0.83351E+00 -0.0791 56 FeO+ 0.11287E-16 -16.9474 0.94265E-17 -17.0257 0.83514E+00 -0.0782 58 FeO2- 0.39996E-09 -9.3980 0.33337E-09 -9.4771 0.83351E+00 -0.0791 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11619E-04 -4.9348 0.11582E-04 -4.9362 0.99681E+00 -0.0014 61 KCl,aq 0.83843E-09 -9.0765 0.83843E-09 -9.0765 0.10000E+01 0.0000 63 KOH,aq 0.75366E-06 -6.1228 0.75366E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.19843E-13 -13.7024 0.16539E-13 -13.7815 0.83351E+00 -0.0791 65 MgCO3,aq 0.10562E-11 -11.9762 0.10562E-11 -11.9762 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.91403E-14 -14.0390 0.76334E-14 -14.1173 0.83514E+00 -0.0782 67 MgCl+ 0.68940E-14 -14.1615 0.57574E-14 -14.2398 0.83514E+00 -0.0782 68 MgF+ 0.69050E-15 -15.1608 0.57667E-15 -15.2391 0.83514E+00 -0.0782 69 MgOH+ 0.70714E-10 -10.1505 0.59056E-10 -10.2287 0.83514E+00 -0.0782 71 MnF+ 0.19073E-15 -15.7196 0.15928E-15 -15.7978 0.83514E+00 -0.0782 72 MnO,aq 0.18082E-08 -8.7428 0.18082E-08 -8.7428 0.10000E+01 0.0000 73 MnOH+ 0.48088E-09 -9.3180 0.40160E-09 -9.3962 0.83514E+00 -0.0782 74 MnO2-2 0.20172E-10 -10.6952 0.10371E-10 -10.9842 0.51415E+00 -0.2889 75 HMnO2- 0.20736E-09 -9.6833 0.17284E-09 -9.7624 0.83351E+00 -0.0791 78 MnCl+ 0.25670E-13 -13.5906 0.21438E-13 -13.6688 0.83514E+00 -0.0782 79 MnSO4,aq 0.23156E-19 -19.6353 0.23156E-19 -19.6353 0.10000E+01 0.0000 80 NaCl,aq 0.19417E-05 -5.7118 0.19417E-05 -5.7118 0.10000E+01 0.0000 81 NaF,aq 0.37261E-08 -8.4287 0.37261E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96036E-04 -4.0176 0.96036E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91297E-02 -2.0395 0.75956E-02 -2.1194 0.83197E+00 -0.0799 89 HPO3-2 0.15720E-14 -14.8035 0.80825E-15 -15.0925 0.51415E+00 -0.2889 91 H2PO3- 0.14791E-18 -18.8300 0.12328E-18 -18.9091 0.83351E+00 -0.0791 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37660E-10 -10.4241 0.31420E-10 -10.5028 0.83432E+00 -0.0787 94 PO4-3 0.10065E-08 -8.9972 0.24019E-09 -9.6195 0.23863E+00 -0.6223 98 HP2O7-3 0.89450E-18 -18.0484 0.20321E-18 -18.6920 0.22718E+00 -0.6436 99 P2O7-4 0.85379E-17 -17.0686 0.63823E-18 -18.1950 0.74753E-01 -1.1264 100 H2S,aq 0.12159E-06 -6.9151 0.12120E-06 -6.9165 0.99681E+00 -0.0014 101 S2-2 0.98898E-12 -12.0048 0.50848E-12 -12.2937 0.51415E+00 -0.2889 102 S3-2 0.13943E-19 -19.8557 0.71686E-20 -20.1446 0.51415E+00 -0.2889 107 SO3-2 0.22904E-16 -16.6401 0.11950E-16 -16.9226 0.52176E+00 -0.2825 108 HSO3- 0.68283E-19 -19.1657 0.56915E-19 -19.2448 0.83351E+00 -0.0791 109 HSO4- 0.69621E-18 -18.1573 0.58202E-18 -18.2351 0.83598E+00 -0.0778 111 S2O3-2 0.21986E-19 -19.6579 0.11304E-19 -19.9468 0.51415E+00 -0.2889 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9069633E-10 -.2190726E-01 -.2204172E+02 0.0000 2 H2O 0.1000000E+01 0.5550652E+02 0.9981785E+06 0.0000 3 Cl- 0.4134367E-03 0.4153793E-03 0.1470011E+02 6.6561 4 SO4-- 0.1540889E-10 -.1628603E-02 -.1561665E+03 9.1374 5 HCO3- 0.3077872E-04 0.1713892E-02 0.1043899E+03 5.5286 6 HS- 0.6184336E-03 0.2247158E-02 0.7418512E+02 6.8311 7 Al+++ 0.1063220E-28 0.5195753E-05 0.1399385E+00 0.7390 8 H4SiO4 0.6959567E-03 0.1329556E-01 0.1275622E+04 -3.1574 9 Ca++ 0.1430324E-06 0.2693028E-06 0.1077382E-01 13.1018 10 Mg++ 0.2237875E-10 0.9746866E-10 0.2365420E-05 9.2942 11 Fe++ 0.6167976E-13 0.3547192E-07 0.1977458E-02 6.7350 12 K+ 0.1607759E-03 0.1615304E-03 0.6304866E+01 6.2467 13 Na+ 0.2040256E-01 0.2284997E-01 0.5243768E+03 8.3493 14 Mn++ 0.1980853E-10 0.2536438E-08 0.1390976E-03 9.2421 15 F- 0.1125421E-05 0.1129149E-05 0.2141321E-01 4.0901 16 HPO4-- 0.4345101E-07 0.4449517E-07 0.4262965E-02 12.5877 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279130E+02 -.1087798E-01 -.8278042E+02 0.0000000E+00 2 H2O -.7159300E+01 0.2756157E+02 -.3472087E+02 0.0000000E+00 3 Cl- 0.2062552E-03 0.2062552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386479E+00 -.8086774E-03 0.1394565E+00 0.0000000E+00 5 HCO3- 0.8510270E-03 0.8510270E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383407E+00 0.1115819E-02 -.1394565E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2579933E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6601862E-02 0.5205730E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1337214E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4839773E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1761346E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8020736E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1134607E-01 0.6265031E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1259459E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4736000E-05 0.5606749E-06 0.4175325E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2209393E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1682E-13 Mass of aqueous solution: 0.497436E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0115900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.796 1641. 3.215 30.05 630.0 andradite 0.5578 -0.254 283.5 2.453 5.190 73.65 grossular 0.1351 -0.869 60.84 1.784 1.114 16.93 apatite-OH 0.9858E-02 -2.006 4.952 0.695 0.9066E-01 1.574 apatite-F 0.4175E-05 -5.379 0.2106E-02 -2.677 0.3855E-04 0.6578E-03 clinochlore 0.7095 -0.149 394.4 2.596 7.220 150.0 daphnite 0.2054 -0.687 146.6 2.166 2.683 44.41 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2405 -0.619 52.09 1.717 0.9536 15.92 hedenbergite 0.6238E-01 -1.205 15.48 1.190 0.2833 4.239 microcline 0.9317 -0.031 259.3 2.414 4.748 101.3 stilbite 3.220 0.508 2269. 3.356 41.55 1059. stilpnomelane-Fe 0.2596 -0.586 279.8 2.447 5.123 96.65 tr.625ac.25prg.125 0.4971E-01 -1.304 42.49 1.628 0.7779 13.68 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.341491 g Volume = 2210.809833 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0115900 moles log = -1.9359 Original solution: 1000.0103000 g Original solution / Rock added: 86282.17 (Water/Rock Ratio), log = 4.9359 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 3.4288 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3012E+00 0.9741 0.1006E+01 0.1033E+01 CO2,gas 0.1311E-06 0.9939 0.4468E-06 0.4495E-06 CH4,gas 0.6944E+00 1.0019 0.2385E+01 0.2381E+01 H2,gas 0.4427E-02 1.0018 0.1521E-01 0.1518E-01 H2S,gas 0.9847E-06 0.9868 0.3332E-05 0.3376E-05 S2,gas 0.5255E-27 1.0000 0.1802E-26 0.1802E-26 CO,gas 0.5281E-12 1.0000 0.1811E-11 0.1811E-11 SO3,gas 0.5066E-47 1.0000 0.1737E-46 0.1737E-46 SO2,gas 0.2997E-26 1.0000 0.1028E-25 0.1028E-25 HF,gas 0.3490E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2472E-17 1.0000 0.8475E-17 0.8475E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.71 -8.05 -2.683 0.13743E+05 -6.350 3 CH4,gas 4.54 3.22 -1.32 -0.330 0.22563E+04 0.378 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.41 -7.18 -3.588 0.12253E+05 -5.477 6 S2,gas -7.34 -35.78 -28.44 -4.376 0.48566E+05 -26.744 7 CO,gas 3.21 -10.23 -13.44 -4.136 0.22950E+05 -11.742 8 SO3,gas 17.12 -31.34 -48.46 -12.115 0.82743E+05 -46.760 9 SO2,gas 0.83 -26.85 -27.69 -7.383 0.47275E+05 -25.988 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.58 -18.77 -9.385 0.32051E+05 -17.072 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80685E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93629E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.61 -2.57 -0.858 0.43945E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.61 -2.42 -0.806 0.41303E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68937E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65541E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.74 -2.64 -0.755 0.45094E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.74 -2.20 -0.628 0.37516E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82233E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.56 -3.31 -0.780 0.56585E+04 146 pyrrhotite -4.26 -6.67 -2.41 -0.804 0.41171E+04 147 pyrrhotiteFe0.875 -6.02 -8.07 -2.05 -0.755 0.35043E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22437E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.47 -4.49 -1.497 0.76676E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23239E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47111E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.67 -2.26 -0.754 0.38599E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.16 -3.19 -1.062 0.54411E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0115900 MOLES New total amount of reactant added: 0.0119900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8652E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0119900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4966E+00 Moles total = -.7159E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1042809E-01 Osmotic coef. = 0.9159 True ionic strength = .2063932E-01 Chg. balance for total moles = -.8652E-10 Max. difference allowed = 0.2086E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90767E-10 -10.0421 0.76120E-10 -10.1185 0.83862E+00 -0.0764 2 H2O 0.99997E+00 0.0000 0.99997E+00 0.0000 3 Cl- 0.41816E-03 -3.3787 0.34852E-03 -3.4578 0.83346E+00 -0.0791 4 SO4-- 0.15887E-10 -10.7989 0.81844E-11 -11.0870 0.51515E+00 -0.2881 5 HCO3- 0.31805E-04 -4.4975 0.26548E-04 -4.5760 0.83471E+00 -0.0785 6 HS- 0.63800E-03 -3.1952 0.53182E-03 -3.2742 0.83358E+00 -0.0791 7 Al+++ 0.10661E-28 -28.9722 0.24182E-29 -29.6165 0.22682E+00 -0.6443 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14327E-06 -6.8438 0.73253E-07 -7.1352 0.51127E+00 -0.2913 10 Mg++ 0.22417E-10 -10.6494 0.11407E-10 -10.9428 0.50888E+00 -0.2934 11 Fe++ 0.61784E-13 -13.2091 0.31476E-13 -13.5020 0.50945E+00 -0.2929 12 K+ 0.16090E-03 -3.7934 0.13434E-03 -3.8718 0.83491E+00 -0.0784 13 Na+ 0.20419E-01 -1.6900 0.17015E-01 -1.7692 0.83330E+00 -0.0792 14 Mn++ 0.19843E-10 -10.7024 0.10118E-10 -10.9949 0.50988E+00 -0.2925 15 F- 0.11247E-05 -5.9490 0.93539E-06 -6.0290 0.83170E+00 -0.0800 16 HPO4-- 0.43398E-07 -7.3625 0.22360E-07 -7.6505 0.51522E+00 -0.2880 18 HSiO3- 0.10243E-01 -1.9896 0.85374E-02 -2.0687 0.83346E+00 -0.0791 19 Ca(HSiO3)+ 0.17055E-07 -7.7682 0.14242E-07 -7.8464 0.83509E+00 -0.0783 20 Mg(HSiO3)+ 0.33053E-11 -11.4808 0.27602E-11 -11.5591 0.83509E+00 -0.0783 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.67987E-16 -16.1676 0.56776E-16 -16.2458 0.83509E+00 -0.0783 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51921E-05 -5.2847 0.43194E-05 -5.3646 0.83192E+00 -0.0799 26 CH4,aq 0.16810E-02 -2.7744 0.16757E-02 -2.7758 0.99682E+00 -0.0014 27 C2H6,aq 0.41576E-10 -10.3812 0.41444E-10 -10.3825 0.99682E+00 -0.0014 28 C3H8,aq 0.23741E-16 -16.6245 0.23665E-16 -16.6259 0.99682E+00 -0.0014 30 ethanol,aq 0.15260E-17 -17.8164 0.15211E-17 -17.8178 0.99682E+00 -0.0014 31 CO,aq 0.12564E-14 -14.9009 0.12564E-14 -14.9009 0.10000E+01 0.0000 32 CO2,aq 0.43319E-08 -8.3633 0.43181E-08 -8.3647 0.99682E+00 -0.0014 33 CO3-2 0.59264E-04 -4.2272 0.30463E-04 -4.5162 0.51403E+00 -0.2890 34 CaCO3,aq 0.27981E-07 -7.5531 0.27981E-07 -7.5531 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.59443E-10 -10.2259 0.49640E-10 -10.3042 0.83509E+00 -0.0783 36 CaCl+ 0.49474E-10 -10.3056 0.41315E-10 -10.3839 0.83509E+00 -0.0783 37 CaCl2,aq 0.34209E-14 -14.4659 0.34209E-14 -14.4659 0.10000E+01 0.0000 38 CaF+ 0.11979E-11 -11.9216 0.10004E-11 -11.9998 0.83509E+00 -0.0783 39 CaOH+ 0.82126E-07 -7.0855 0.68583E-07 -7.1638 0.83509E+00 -0.0783 40 CaSO4,aq 0.19038E-15 -15.7204 0.19038E-15 -15.7204 0.10000E+01 0.0000 41 HCl,aq 0.48614E-14 -14.3132 0.48614E-14 -14.3132 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18469E-18 -18.7335 0.15393E-18 -18.8127 0.83346E+00 -0.0791 48 FeCl+ 0.20792E-16 -16.6821 0.17364E-16 -16.7604 0.83509E+00 -0.0783 51 FeF+ 0.18017E-17 -17.7443 0.15046E-17 -17.8226 0.83509E+00 -0.0783 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16118E-10 -10.7927 0.13460E-10 -10.8710 0.83509E+00 -0.0783 55 HFeO2- 0.34818E-07 -7.4582 0.29020E-07 -7.5373 0.83346E+00 -0.0791 56 FeO+ 0.11296E-16 -16.9471 0.94333E-17 -17.0253 0.83509E+00 -0.0783 58 FeO2- 0.39969E-09 -9.3983 0.33313E-09 -9.4774 0.83346E+00 -0.0791 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11619E-04 -4.9348 0.11582E-04 -4.9362 0.99682E+00 -0.0014 61 KCl,aq 0.84857E-09 -9.0713 0.84857E-09 -9.0713 0.10000E+01 0.0000 63 KOH,aq 0.75366E-06 -6.1228 0.75366E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.20470E-13 -13.6889 0.17061E-13 -13.7680 0.83346E+00 -0.0791 65 MgCO3,aq 0.10922E-11 -11.9617 0.10922E-11 -11.9617 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.94588E-14 -14.0242 0.78990E-14 -14.1024 0.83509E+00 -0.0783 67 MgCl+ 0.69829E-14 -14.1560 0.58313E-14 -14.2342 0.83509E+00 -0.0783 68 MgF+ 0.69105E-15 -15.1605 0.57709E-15 -15.2388 0.83509E+00 -0.0783 69 MgOH+ 0.70769E-10 -10.1502 0.59099E-10 -10.2284 0.83509E+00 -0.0783 71 MnF+ 0.19088E-15 -15.7192 0.15941E-15 -15.7975 0.83509E+00 -0.0783 72 MnO,aq 0.18083E-08 -8.7427 0.18083E-08 -8.7427 0.10000E+01 0.0000 73 MnOH+ 0.48128E-09 -9.3176 0.40191E-09 -9.3959 0.83509E+00 -0.0783 74 MnO2-2 0.20148E-10 -10.6958 0.10357E-10 -10.9848 0.51403E+00 -0.2890 75 HMnO2- 0.20723E-09 -9.6836 0.17272E-09 -9.7627 0.83346E+00 -0.0791 78 MnCl+ 0.26002E-13 -13.5850 0.21714E-13 -13.6633 0.83509E+00 -0.0783 79 MnSO4,aq 0.23905E-19 -19.6215 0.23905E-19 -19.6215 0.10000E+01 0.0000 80 NaCl,aq 0.19652E-05 -5.7066 0.19652E-05 -5.7066 0.10000E+01 0.0000 81 NaF,aq 0.37261E-08 -8.4287 0.37261E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96035E-04 -4.0176 0.96035E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91236E-02 -2.0398 0.75901E-02 -2.1198 0.83192E+00 -0.0799 89 HPO3-2 0.15701E-14 -14.8041 0.80707E-15 -15.0931 0.51403E+00 -0.2890 91 H2PO3- 0.14781E-18 -18.8303 0.12319E-18 -18.9094 0.83346E+00 -0.0791 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37635E-10 -10.4244 0.31397E-10 -10.5031 0.83427E+00 -0.0787 94 PO4-3 0.10048E-08 -8.9979 0.23966E-09 -9.6204 0.23852E+00 -0.6225 98 HP2O7-3 0.89303E-18 -18.0491 0.20277E-18 -18.6930 0.22706E+00 -0.6439 99 P2O7-4 0.85209E-17 -17.0695 0.63638E-18 -18.1963 0.74684E-01 -1.1268 100 H2S,aq 0.12551E-06 -6.9013 0.12512E-06 -6.9027 0.99682E+00 -0.0014 101 S2-2 0.10527E-11 -11.9777 0.54110E-12 -12.2667 0.51403E+00 -0.2890 102 S3-2 0.15320E-19 -19.8147 0.78749E-20 -20.1038 0.51403E+00 -0.2890 107 SO3-2 0.23615E-16 -16.6268 0.12319E-16 -16.9094 0.52164E+00 -0.2826 108 HSO3- 0.70443E-19 -19.1522 0.58711E-19 -19.2313 0.83346E+00 -0.0791 109 HSO4- 0.71823E-18 -18.1437 0.60039E-18 -18.2216 0.83593E+00 -0.0778 111 S2O3-2 0.23401E-19 -19.6308 0.12029E-19 -19.9198 0.51403E+00 -0.2890 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9076739E-10 -.2189619E-01 -.2203054E+02 0.0000 2 H2O 0.1000000E+01 0.5550658E+02 0.9981778E+06 0.0000 3 Cl- 0.4181599E-03 0.4201260E-03 0.1486807E+02 6.6607 4 SO4-- 0.1588746E-10 -.1683912E-02 -.1614697E+03 9.1500 5 HCO3- 0.3180495E-04 0.1772108E-02 0.1079355E+03 5.5425 6 HS- 0.6379955E-03 0.2322033E-02 0.7665681E+02 6.8443 7 Al+++ 0.1066108E-28 0.5192295E-05 0.1398452E+00 0.7390 8 H4SiO4 0.6959559E-03 0.1328871E-01 0.1274963E+04 -3.1574 9 Ca++ 0.1432745E-06 0.2705463E-06 0.1082355E-01 13.1018 10 Mg++ 0.2241670E-10 0.9760138E-10 0.2368638E-05 9.2942 11 Fe++ 0.6178435E-13 0.3544839E-07 0.1976143E-02 6.7350 12 K+ 0.1609019E-03 0.1616564E-03 0.6309773E+01 6.2467 13 Na+ 0.2041858E-01 0.2286600E-01 0.5247438E+03 8.3493 14 Mn++ 0.1984288E-10 0.2536784E-08 0.1391164E-03 9.2421 15 F- 0.1124671E-05 0.1128398E-05 0.2139894E-01 4.0895 16 HPO4-- 0.4339787E-07 0.4444032E-07 0.4257702E-02 12.5865 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279126E+02 -.1087264E-01 -.8278038E+02 0.0000000E+00 2 H2O -.7158973E+01 0.2756201E+02 -.3472098E+02 0.0000000E+00 3 Cl- 0.2086152E-03 0.2086152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386498E+00 -.8361529E-03 0.1394859E+00 0.0000000E+00 5 HCO3- 0.8799470E-03 0.8799470E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383329E+00 0.1153014E-02 -.1394859E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2578254E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6598559E-02 0.5205731E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1343408E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4846434E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1760203E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8027110E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1135420E-01 0.6265023E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1259650E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4896000E-05 0.5603106E-06 0.4335689E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2206701E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.6564E-14 Mass of aqueous solution: 0.497444E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0119900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.796 1641. 3.215 30.05 630.0 andradite 0.5579 -0.253 283.5 2.453 5.191 73.66 grossular 0.1351 -0.869 60.86 1.784 1.114 16.93 apatite-OH 0.9858E-02 -2.006 4.952 0.695 0.9066E-01 1.574 apatite-F 0.4336E-05 -5.363 0.2187E-02 -2.660 0.4003E-04 0.6831E-03 clinochlore 0.7095 -0.149 394.3 2.596 7.219 150.0 daphnite 0.2054 -0.687 146.6 2.166 2.683 44.41 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2398 -0.620 51.92 1.715 0.9506 15.87 hedenbergite 0.6218E-01 -1.206 15.43 1.188 0.2824 4.225 microcline 0.9317 -0.031 259.3 2.414 4.748 101.3 stilbite 3.220 0.508 2269. 3.356 41.55 1059. stilpnomelane-Fe 0.2595 -0.586 279.7 2.447 5.121 96.63 tr.625ac.25prg.125 0.4996E-01 -1.301 42.71 1.630 0.7818 13.74 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.341612 g Volume = 2210.810937 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0119900 moles log = -1.9212 Original solution: 1000.0103000 g Original solution / Rock added: 83403.69 (Water/Rock Ratio), log = 4.9212 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 3.5103 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2942E+00 0.9739 0.1006E+01 0.1033E+01 CO2,gas 0.1324E-06 0.9937 0.4620E-06 0.4649E-06 CH4,gas 0.7014E+00 1.0017 0.2466E+01 0.2462E+01 H2,gas 0.4324E-02 1.0019 0.1521E-01 0.1518E-01 H2S,gas 0.9932E-06 0.9865 0.3439E-05 0.3487E-05 S2,gas 0.5470E-27 1.0000 0.1920E-26 0.1920E-26 CO,gas 0.5334E-12 1.0000 0.1872E-11 0.1872E-11 SO3,gas 0.5108E-47 1.0000 0.1793E-46 0.1793E-46 SO2,gas 0.3022E-26 1.0000 0.1061E-25 0.1061E-25 HF,gas 0.3409E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2444E-17 1.0000 0.8578E-17 0.8578E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.69 -8.03 -2.678 0.13718E+05 -6.335 3 CH4,gas 4.54 3.24 -1.31 -0.327 0.22315E+04 0.392 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.39 -7.16 -3.581 0.12230E+05 -5.464 6 S2,gas -7.34 -35.75 -28.42 -4.372 0.48519E+05 -26.717 7 CO,gas 3.21 -10.21 -13.43 -4.131 0.22926E+05 -11.728 8 SO3,gas 17.12 -31.32 -48.45 -12.111 0.82719E+05 -46.746 9 SO2,gas 0.83 -26.84 -27.67 -7.380 0.47251E+05 -25.974 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.58 -18.77 -9.383 0.32042E+05 -17.067 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80684E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93629E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.59 -2.56 -0.853 0.43697E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.59 -2.40 -0.801 0.41055E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65540E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.73 -2.63 -0.750 0.44846E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.73 -2.18 -0.624 0.37268E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82233E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 145 pyrite -21.25 -24.53 -3.29 -0.773 0.56114E+04 146 pyrrhotite -4.26 -6.66 -2.40 -0.799 0.40935E+04 147 pyrrhotiteFe0.875 -6.02 -8.06 -2.04 -0.750 0.34808E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22436E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.45 -4.48 -1.492 0.76428E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23239E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47110E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.66 -2.25 -0.749 0.38364E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.15 -3.17 -1.058 0.54174E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0119900 MOLES New total amount of reactant added: 0.0123900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8651E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0123900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4966E+00 Moles total = -.7159E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1039444E-01 Osmotic coef. = 0.9162 True ionic strength = .2065734E-01 Chg. balance for total moles = -.8651E-10 Max. difference allowed = 0.2110E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90838E-10 -10.0417 0.76175E-10 -10.1182 0.83858E+00 -0.0765 2 H2O 0.99997E+00 0.0000 0.99997E+00 0.0000 3 Cl- 0.42288E-03 -3.3738 0.35243E-03 -3.4529 0.83341E+00 -0.0791 4 SO4-- 0.16365E-10 -10.7861 0.84287E-11 -11.0742 0.51503E+00 -0.2882 5 HCO3- 0.32830E-04 -4.4837 0.27402E-04 -4.5622 0.83466E+00 -0.0785 6 HS- 0.65756E-03 -3.1821 0.54810E-03 -3.2611 0.83353E+00 -0.0791 7 Al+++ 0.10690E-28 -28.9710 0.24235E-29 -29.6156 0.22670E+00 -0.6445 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14352E-06 -6.8431 0.73359E-07 -7.1345 0.51115E+00 -0.2914 10 Mg++ 0.22455E-10 -10.6487 0.11424E-10 -10.9422 0.50876E+00 -0.2935 11 Fe++ 0.61889E-13 -13.2084 0.31522E-13 -13.5014 0.50933E+00 -0.2930 12 K+ 0.16103E-03 -3.7931 0.13444E-03 -3.8715 0.83486E+00 -0.0784 13 Na+ 0.20435E-01 -1.6896 0.17027E-01 -1.7689 0.83325E+00 -0.0792 14 Mn++ 0.19877E-10 -10.7016 0.10133E-10 -10.9943 0.50976E+00 -0.2926 15 F- 0.11239E-05 -5.9493 0.93471E-06 -6.0293 0.83165E+00 -0.0801 16 HPO4-- 0.43345E-07 -7.3631 0.22327E-07 -7.6512 0.51511E+00 -0.2881 18 HSiO3- 0.10236E-01 -1.9898 0.85312E-02 -2.0690 0.83341E+00 -0.0791 19 Ca(HSiO3)+ 0.17068E-07 -7.7678 0.14253E-07 -7.8461 0.83504E+00 -0.0783 20 Mg(HSiO3)+ 0.33079E-11 -11.4804 0.27622E-11 -11.5587 0.83504E+00 -0.0783 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.68041E-16 -16.1672 0.56817E-16 -16.2455 0.83504E+00 -0.0783 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51887E-05 -5.2849 0.43163E-05 -5.3649 0.83187E+00 -0.0799 26 CH4,aq 0.17363E-02 -2.7604 0.17308E-02 -2.7618 0.99683E+00 -0.0014 27 C2H6,aq 0.44358E-10 -10.3530 0.44217E-10 -10.3544 0.99683E+00 -0.0014 28 C3H8,aq 0.26163E-16 -16.5823 0.26080E-16 -16.5837 0.99683E+00 -0.0014 30 ethanol,aq 0.16281E-17 -17.7883 0.16229E-17 -17.7897 0.99683E+00 -0.0014 31 CO,aq 0.12978E-14 -14.8868 0.12978E-14 -14.8868 0.10000E+01 0.0000 32 CO2,aq 0.44745E-08 -8.3493 0.44603E-08 -8.3506 0.99683E+00 -0.0014 33 CO3-2 0.61140E-04 -4.2137 0.31420E-04 -4.5028 0.51391E+00 -0.2891 34 CaCO3,aq 0.28902E-07 -7.5391 0.28902E-07 -7.5391 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.61448E-10 -10.2115 0.51312E-10 -10.2898 0.83504E+00 -0.0783 36 CaCl+ 0.50106E-10 -10.3001 0.41840E-10 -10.3784 0.83504E+00 -0.0783 37 CaCl2,aq 0.35033E-14 -14.4555 0.35033E-14 -14.4555 0.10000E+01 0.0000 38 CaF+ 0.11989E-11 -11.9212 0.10011E-11 -11.9995 0.83504E+00 -0.0783 39 CaOH+ 0.82191E-07 -7.0852 0.68633E-07 -7.1635 0.83504E+00 -0.0783 40 CaSO4,aq 0.19635E-15 -15.7070 0.19635E-15 -15.7070 0.10000E+01 0.0000 41 HCl,aq 0.49195E-14 -14.3081 0.49195E-14 -14.3081 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18457E-18 -18.7338 0.15382E-18 -18.8130 0.83341E+00 -0.0791 48 FeCl+ 0.21058E-16 -16.6766 0.17584E-16 -16.7549 0.83504E+00 -0.0783 51 FeF+ 0.18031E-17 -17.7440 0.15056E-17 -17.8223 0.83504E+00 -0.0783 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16130E-10 -10.7924 0.13469E-10 -10.8706 0.83504E+00 -0.0783 55 HFeO2- 0.34795E-07 -7.4585 0.28998E-07 -7.5376 0.83341E+00 -0.0791 56 FeO+ 0.11305E-16 -16.9467 0.94402E-17 -17.0250 0.83504E+00 -0.0783 58 FeO2- 0.39942E-09 -9.3986 0.33288E-09 -9.4777 0.83341E+00 -0.0791 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11619E-04 -4.9348 0.11582E-04 -4.9362 0.99683E+00 -0.0014 61 KCl,aq 0.85872E-09 -9.0661 0.85872E-09 -9.0661 0.10000E+01 0.0000 63 KOH,aq 0.75366E-06 -6.1228 0.75366E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.21098E-13 -13.6758 0.17583E-13 -13.7549 0.83341E+00 -0.0791 65 MgCO3,aq 0.11281E-11 -11.9476 0.11281E-11 -11.9476 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.97778E-14 -14.0098 0.81649E-14 -14.0880 0.83504E+00 -0.0783 67 MgCl+ 0.70720E-14 -14.1505 0.59054E-14 -14.2287 0.83504E+00 -0.0783 68 MgF+ 0.69159E-15 -15.1602 0.57751E-15 -15.2384 0.83504E+00 -0.0783 69 MgOH+ 0.70825E-10 -10.1498 0.59142E-10 -10.2281 0.83504E+00 -0.0783 71 MnF+ 0.19104E-15 -15.7189 0.15953E-15 -15.7972 0.83504E+00 -0.0783 72 MnO,aq 0.18083E-08 -8.7427 0.18083E-08 -8.7427 0.10000E+01 0.0000 73 MnOH+ 0.48167E-09 -9.3172 0.40222E-09 -9.3955 0.83504E+00 -0.0783 74 MnO2-2 0.20124E-10 -10.6963 0.10342E-10 -10.9854 0.51391E+00 -0.2891 75 HMnO2- 0.20710E-09 -9.6838 0.17260E-09 -9.7630 0.83341E+00 -0.0791 78 MnCl+ 0.26335E-13 -13.5795 0.21991E-13 -13.6578 0.83504E+00 -0.0783 79 MnSO4,aq 0.24656E-19 -19.6081 0.24656E-19 -19.6081 0.10000E+01 0.0000 80 NaCl,aq 0.19887E-05 -5.7014 0.19887E-05 -5.7014 0.10000E+01 0.0000 81 NaF,aq 0.37261E-08 -8.4287 0.37261E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96035E-04 -4.0176 0.96035E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91175E-02 -2.0401 0.75846E-02 -2.1201 0.83187E+00 -0.0799 89 HPO3-2 0.15682E-14 -14.8046 0.80590E-15 -15.0937 0.51391E+00 -0.2891 91 H2PO3- 0.14771E-18 -18.8306 0.12310E-18 -18.9097 0.83341E+00 -0.0791 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37610E-10 -10.4247 0.31375E-10 -10.5034 0.83422E+00 -0.0787 94 PO4-3 0.10031E-08 -8.9987 0.23914E-09 -9.6213 0.23840E+00 -0.6227 98 HP2O7-3 0.89155E-18 -18.0499 0.20233E-18 -18.6939 0.22694E+00 -0.6441 99 P2O7-4 0.85040E-17 -17.0704 0.63453E-18 -18.1975 0.74616E-01 -1.1272 100 H2S,aq 0.12945E-06 -6.8879 0.12904E-06 -6.8893 0.99683E+00 -0.0014 101 S2-2 0.11183E-11 -11.9514 0.57472E-12 -12.2405 0.51391E+00 -0.2891 102 S3-2 0.16786E-19 -19.7751 0.86264E-20 -20.0642 0.51391E+00 -0.2891 107 SO3-2 0.24326E-16 -16.6139 0.12686E-16 -16.8967 0.52153E+00 -0.2827 108 HSO3- 0.72603E-19 -19.1390 0.60508E-19 -19.2182 0.83341E+00 -0.0791 109 HSO4- 0.74025E-18 -18.1306 0.61876E-18 -18.2085 0.83588E+00 -0.0779 111 S2O3-2 0.24861E-19 -19.6045 0.12776E-19 -19.8936 0.51391E+00 -0.2891 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9083847E-10 -.2188513E-01 -.2201938E+02 0.0000 2 H2O 0.1000000E+01 0.5550664E+02 0.9981772E+06 0.0000 3 Cl- 0.4228829E-03 0.4248725E-03 0.1503602E+02 6.6653 4 SO4-- 0.1636548E-10 -.1739224E-02 -.1667733E+03 9.1621 5 HCO3- 0.3282991E-04 0.1830322E-02 0.1114811E+03 5.5560 6 HS- 0.6575568E-03 0.2396910E-02 0.7912861E+02 6.8570 7 Al+++ 0.1069003E-28 0.5188842E-05 0.1397519E+00 0.7390 8 H4SiO4 0.6959551E-03 0.1328187E-01 0.1274305E+04 -3.1574 9 Ca++ 0.1435168E-06 0.2717902E-06 0.1087329E-01 13.1018 10 Mg++ 0.2245469E-10 0.9773410E-10 0.2371854E-05 9.2942 11 Fe++ 0.6188907E-13 0.3542488E-07 0.1974829E-02 6.7350 12 K+ 0.1610279E-03 0.1617824E-03 0.6314682E+01 6.2467 13 Na+ 0.2043459E-01 0.2288203E-01 0.5251109E+03 8.3493 14 Mn++ 0.1987727E-10 0.2537131E-08 0.1391352E-03 9.2421 15 F- 0.1123921E-05 0.1127649E-05 0.2138469E-01 4.0889 16 HPO4-- 0.4334483E-07 0.4438555E-07 0.4252449E-02 12.5852 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279121E+02 -.1086731E-01 -.8278035E+02 0.0000000E+00 2 H2O -.7158645E+01 0.2756244E+02 -.3472109E+02 0.0000000E+00 3 Cl- 0.2109752E-03 0.2109752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386517E+00 -.8636312E-03 0.1395153E+00 0.0000000E+00 5 HCO3- 0.9088670E-03 0.9088670E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383251E+00 0.1190213E-02 -.1395153E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2576577E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6595260E-02 0.5205731E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1349605E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4853096E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1759062E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8033485E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1136233E-01 0.6265015E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1259840E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5056000E-05 0.5599467E-06 0.4496053E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2204014E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1018E-13 Mass of aqueous solution: 0.497452E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0123900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.796 1641. 3.215 30.05 630.0 andradite 0.5581 -0.253 283.6 2.453 5.192 73.68 grossular 0.1351 -0.869 60.87 1.784 1.114 16.94 apatite-OH 0.9858E-02 -2.006 4.952 0.695 0.9066E-01 1.574 apatite-F 0.4496E-05 -5.347 0.2267E-02 -2.644 0.4151E-04 0.7083E-03 clinochlore 0.7094 -0.149 394.3 2.596 7.219 150.0 daphnite 0.2054 -0.687 146.5 2.166 2.683 44.41 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2390 -0.622 51.76 1.714 0.9475 15.82 hedenbergite 0.6198E-01 -1.208 15.38 1.187 0.2815 4.212 microcline 0.9318 -0.031 259.3 2.414 4.748 101.3 stilbite 3.220 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2594 -0.586 279.7 2.447 5.120 96.61 tr.625ac.25prg.125 0.5021E-01 -1.299 42.92 1.633 0.7857 13.81 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.341733 g Volume = 2210.812040 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0123900 moles log = -1.9069 Original solution: 1000.0103000 g Original solution / Rock added: 80711.08 (Water/Rock Ratio), log = 4.9069 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 3.5919 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2876E+00 0.9737 0.1006E+01 0.1033E+01 CO2,gas 0.1337E-06 0.9935 0.4772E-06 0.4803E-06 CH4,gas 0.7082E+00 1.0016 0.2548E+01 0.2544E+01 H2,gas 0.4225E-02 1.0019 0.1521E-01 0.1518E-01 H2S,gas 0.1001E-05 0.9861 0.3547E-05 0.3597E-05 S2,gas 0.5687E-27 1.0000 0.2043E-26 0.2043E-26 CO,gas 0.5384E-12 1.0000 0.1934E-11 0.1934E-11 SO3,gas 0.5149E-47 1.0000 0.1849E-46 0.1849E-46 SO2,gas 0.3046E-26 1.0000 0.1094E-25 0.1094E-25 HF,gas 0.3332E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2417E-17 1.0000 0.8681E-17 0.8681E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.68 -8.02 -2.673 0.13694E+05 -6.321 3 CH4,gas 4.54 3.25 -1.29 -0.323 0.22075E+04 0.406 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.38 -7.15 -3.575 0.12207E+05 -5.450 6 S2,gas -7.34 -35.72 -28.39 -4.368 0.48473E+05 -26.690 7 CO,gas 3.21 -10.20 -13.41 -4.127 0.22902E+05 -11.714 8 SO3,gas 17.12 -31.31 -48.43 -12.108 0.82696E+05 -46.733 9 SO2,gas 0.83 -26.83 -27.66 -7.376 0.47229E+05 -25.961 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.57 -18.76 -9.380 0.32033E+05 -17.061 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80683E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93629E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.58 -2.55 -0.848 0.43457E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.58 -2.39 -0.797 0.40815E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65540E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.71 -2.61 -0.746 0.44605E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.71 -2.17 -0.620 0.37028E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82232E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.51 -3.26 -0.767 0.55656E+04 146 pyrrhotite -4.26 -6.64 -2.38 -0.795 0.40707E+04 147 pyrrhotiteFe0.875 -6.02 -8.04 -2.03 -0.745 0.34579E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22436E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.44 -4.46 -1.487 0.76187E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23238E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47109E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.64 -2.23 -0.744 0.38135E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.14 -3.16 -1.053 0.53945E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0123900 MOLES New total amount of reactant added: 0.0127900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8651E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0127900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4966E+00 Moles total = -.7158E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1036078E-01 Osmotic coef. = 0.9165 True ionic strength = .2067536E-01 Chg. balance for total moles = -.8651E-10 Max. difference allowed = 0.2133E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90910E-10 -10.0414 0.76230E-10 -10.1179 0.83853E+00 -0.0765 2 H2O 0.99997E+00 0.0000 0.99997E+00 0.0000 3 Cl- 0.42761E-03 -3.3690 0.35635E-03 -3.4481 0.83336E+00 -0.0792 4 SO4-- 0.16843E-10 -10.7736 0.86726E-11 -11.0618 0.51491E+00 -0.2883 5 HCO3- 0.33854E-04 -4.4704 0.28255E-04 -4.5489 0.83461E+00 -0.0785 6 HS- 0.67712E-03 -3.1693 0.56437E-03 -3.2484 0.83348E+00 -0.0791 7 Al+++ 0.10719E-28 -28.9698 0.24288E-29 -29.6146 0.22659E+00 -0.6448 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14376E-06 -6.8424 0.73466E-07 -7.1339 0.51103E+00 -0.2916 10 Mg++ 0.22493E-10 -10.6480 0.11441E-10 -10.9416 0.50864E+00 -0.2936 11 Fe++ 0.61994E-13 -13.2077 0.31568E-13 -13.5008 0.50921E+00 -0.2931 12 K+ 0.16115E-03 -3.7928 0.13453E-03 -3.8712 0.83481E+00 -0.0784 13 Na+ 0.20451E-01 -1.6893 0.17040E-01 -1.7685 0.83320E+00 -0.0792 14 Mn++ 0.19912E-10 -10.7009 0.10148E-10 -10.9936 0.50964E+00 -0.2927 15 F- 0.11232E-05 -5.9496 0.93403E-06 -6.0296 0.83160E+00 -0.0801 16 HPO4-- 0.43292E-07 -7.3636 0.22295E-07 -7.6518 0.51499E+00 -0.2882 18 HSiO3- 0.10230E-01 -1.9901 0.85250E-02 -2.0693 0.83336E+00 -0.0792 19 Ca(HSiO3)+ 0.17082E-07 -7.7675 0.14263E-07 -7.8458 0.83500E+00 -0.0783 20 Mg(HSiO3)+ 0.33105E-11 -11.4801 0.27643E-11 -11.5584 0.83500E+00 -0.0783 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.68094E-16 -16.1669 0.56858E-16 -16.2452 0.83500E+00 -0.0783 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51852E-05 -5.2852 0.43132E-05 -5.3652 0.83182E+00 -0.0800 26 CH4,aq 0.17916E-02 -2.7468 0.17860E-02 -2.7481 0.99684E+00 -0.0014 27 C2H6,aq 0.47230E-10 -10.3258 0.47080E-10 -10.3272 0.99684E+00 -0.0014 28 C3H8,aq 0.28745E-16 -16.5414 0.28654E-16 -16.5428 0.99684E+00 -0.0014 30 ethanol,aq 0.17335E-17 -17.7611 0.17280E-17 -17.7624 0.99684E+00 -0.0014 31 CO,aq 0.13391E-14 -14.8732 0.13391E-14 -14.8732 0.10000E+01 0.0000 32 CO2,aq 0.46170E-08 -8.3356 0.46024E-08 -8.3370 0.99684E+00 -0.0014 33 CO3-2 0.63011E-04 -4.2006 0.32375E-04 -4.4898 0.51379E+00 -0.2892 34 CaCO3,aq 0.29823E-07 -7.5255 0.29823E-07 -7.5255 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.63456E-10 -10.1975 0.52985E-10 -10.2758 0.83500E+00 -0.0783 36 CaCl+ 0.50739E-10 -10.2947 0.42367E-10 -10.3730 0.83500E+00 -0.0783 37 CaCl2,aq 0.35868E-14 -14.4453 0.35868E-14 -14.4453 0.10000E+01 0.0000 38 CaF+ 0.11998E-11 -11.9209 0.10018E-11 -11.9992 0.83500E+00 -0.0783 39 CaOH+ 0.82255E-07 -7.0848 0.68683E-07 -7.1632 0.83500E+00 -0.0783 40 CaSO4,aq 0.20232E-15 -15.6940 0.20232E-15 -15.6940 0.10000E+01 0.0000 41 HCl,aq 0.49778E-14 -14.3030 0.49778E-14 -14.3030 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18445E-18 -18.7341 0.15371E-18 -18.8133 0.83336E+00 -0.0792 48 FeCl+ 0.21324E-16 -16.6711 0.17805E-16 -16.7494 0.83500E+00 -0.0783 51 FeF+ 0.18045E-17 -17.7436 0.15067E-17 -17.8220 0.83500E+00 -0.0783 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16143E-10 -10.7920 0.13479E-10 -10.8703 0.83500E+00 -0.0783 55 HFeO2- 0.34772E-07 -7.4588 0.28977E-07 -7.5379 0.83336E+00 -0.0792 56 FeO+ 0.11314E-16 -16.9464 0.94471E-17 -17.0247 0.83500E+00 -0.0783 58 FeO2- 0.39916E-09 -9.3989 0.33264E-09 -9.4780 0.83336E+00 -0.0792 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11619E-04 -4.9348 0.11582E-04 -4.9362 0.99684E+00 -0.0014 61 KCl,aq 0.86889E-09 -9.0610 0.86889E-09 -9.0610 0.10000E+01 0.0000 63 KOH,aq 0.75366E-06 -6.1228 0.75366E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.21726E-13 -13.6630 0.18105E-13 -13.7422 0.83336E+00 -0.0792 65 MgCO3,aq 0.11641E-11 -11.9340 0.11641E-11 -11.9340 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10097E-13 -13.9958 0.84313E-14 -14.0741 0.83500E+00 -0.0783 67 MgCl+ 0.71614E-14 -14.1450 0.59797E-14 -14.2233 0.83500E+00 -0.0783 68 MgF+ 0.69213E-15 -15.1598 0.57793E-15 -15.2381 0.83500E+00 -0.0783 69 MgOH+ 0.70880E-10 -10.1495 0.59185E-10 -10.2278 0.83500E+00 -0.0783 71 MnF+ 0.19120E-15 -15.7185 0.15965E-15 -15.7968 0.83500E+00 -0.0783 72 MnO,aq 0.18084E-08 -8.7427 0.18084E-08 -8.7427 0.10000E+01 0.0000 73 MnOH+ 0.48207E-09 -9.3169 0.40253E-09 -9.3952 0.83500E+00 -0.0783 74 MnO2-2 0.20101E-10 -10.6968 0.10328E-10 -10.9860 0.51379E+00 -0.2892 75 HMnO2- 0.20697E-09 -9.6841 0.17248E-09 -9.7633 0.83336E+00 -0.0792 78 MnCl+ 0.26668E-13 -13.5740 0.22268E-13 -13.6523 0.83500E+00 -0.0783 79 MnSO4,aq 0.25407E-19 -19.5950 0.25407E-19 -19.5950 0.10000E+01 0.0000 80 NaCl,aq 0.20123E-05 -5.6963 0.20123E-05 -5.6963 0.10000E+01 0.0000 81 NaF,aq 0.37261E-08 -8.4287 0.37261E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96035E-04 -4.0176 0.96035E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91115E-02 -2.0404 0.75791E-02 -2.1204 0.83182E+00 -0.0800 89 HPO3-2 0.15663E-14 -14.8051 0.80473E-15 -15.0943 0.51379E+00 -0.2892 91 H2PO3- 0.14761E-18 -18.8309 0.12302E-18 -18.9100 0.83336E+00 -0.0792 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37585E-10 -10.4250 0.31352E-10 -10.5037 0.83417E+00 -0.0787 94 PO4-3 0.10014E-08 -8.9994 0.23862E-09 -9.6223 0.23828E+00 -0.6229 98 HP2O7-3 0.89008E-18 -18.0506 0.20189E-18 -18.6949 0.22682E+00 -0.6443 99 P2O7-4 0.84871E-17 -17.0712 0.63269E-18 -18.1988 0.74548E-01 -1.1276 100 H2S,aq 0.13339E-06 -6.8749 0.13296E-06 -6.8763 0.99684E+00 -0.0014 101 S2-2 0.11860E-11 -11.9259 0.60935E-12 -12.2151 0.51379E+00 -0.2892 102 S3-2 0.18343E-19 -19.7365 0.94246E-20 -20.0257 0.51379E+00 -0.2892 107 SO3-2 0.25035E-16 -16.6015 0.13054E-16 -16.8843 0.52141E+00 -0.2828 108 HSO3- 0.74763E-19 -19.1263 0.62304E-19 -19.2055 0.83336E+00 -0.0792 109 HSO4- 0.76227E-18 -18.1179 0.63713E-18 -18.1958 0.83583E+00 -0.0779 111 S2O3-2 0.26365E-19 -19.5790 0.13546E-19 -19.8682 0.51379E+00 -0.2892 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9090956E-10 -.2187408E-01 -.2200822E+02 0.0000 2 H2O 0.1000000E+01 0.5550669E+02 0.9981766E+06 0.0000 3 Cl- 0.4276057E-03 0.4296189E-03 0.1520397E+02 6.6697 4 SO4-- 0.1684296E-10 -.1794541E-02 -.1720773E+03 9.1739 5 HCO3- 0.3385359E-04 0.1888535E-02 0.1150265E+03 5.5690 6 HS- 0.6771176E-03 0.2471792E-02 0.8160051E+02 6.8694 7 Al+++ 0.1071904E-28 0.5185392E-05 0.1396588E+00 0.7390 8 H4SiO4 0.6959544E-03 0.1327504E-01 0.1273647E+04 -3.1574 9 Ca++ 0.1437595E-06 0.2730345E-06 0.1092306E-01 13.1018 10 Mg++ 0.2249273E-10 0.9786860E-10 0.2375115E-05 9.2942 11 Fe++ 0.6199392E-13 0.3540139E-07 0.1973516E-02 6.7350 12 K+ 0.1611539E-03 0.1619084E-03 0.6319591E+01 6.2467 13 Na+ 0.2045062E-01 0.2289807E-01 0.5254781E+03 8.3493 14 Mn++ 0.1991169E-10 0.2537478E-08 0.1391540E-03 9.2421 15 F- 0.1123173E-05 0.1126900E-05 0.2137046E-01 4.0882 16 HPO4-- 0.4329188E-07 0.4433088E-07 0.4247204E-02 12.5839 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279117E+02 -.1086198E-01 -.8278031E+02 0.0000000E+00 2 H2O -.7158318E+01 0.2756287E+02 -.3472119E+02 0.0000000E+00 3 Cl- 0.2133352E-03 0.2133352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386536E+00 -.8911123E-03 0.1395447E+00 0.0000000E+00 5 HCO3- 0.9377870E-03 0.9377870E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383173E+00 0.1227414E-02 -.1395447E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2574902E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6591964E-02 0.5205731E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1355803E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4859846E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1757922E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8039862E-04 0.1061491E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1137046E-01 0.6265006E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1260031E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5216000E-05 0.5595832E-06 0.4656417E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2201332E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.6960E-14 Mass of aqueous solution: 0.497460E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0127900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.796 1641. 3.215 30.04 630.0 andradite 0.5582 -0.253 283.7 2.453 5.193 73.70 grossular 0.1352 -0.869 60.88 1.785 1.115 16.94 apatite-OH 0.9858E-02 -2.006 4.952 0.695 0.9065E-01 1.574 apatite-F 0.4656E-05 -5.332 0.2348E-02 -2.629 0.4299E-04 0.7336E-03 clinochlore 0.7094 -0.149 394.3 2.596 7.219 150.0 daphnite 0.2054 -0.687 146.5 2.166 2.683 44.41 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2382 -0.623 51.59 1.713 0.9445 15.77 hedenbergite 0.6178E-01 -1.209 15.33 1.185 0.2806 4.198 microcline 0.9318 -0.031 259.4 2.414 4.748 101.3 stilbite 3.220 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2594 -0.586 279.6 2.447 5.119 96.59 tr.625ac.25prg.125 0.5046E-01 -1.297 43.13 1.635 0.7896 13.88 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.341854 g Volume = 2210.813144 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0127900 moles log = -1.8931 Original solution: 1000.0103000 g Original solution / Rock added: 78186.89 (Water/Rock Ratio), log = 4.8931 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 3.6735 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2813E+00 0.9735 0.1006E+01 0.1033E+01 CO2,gas 0.1349E-06 0.9933 0.4924E-06 0.4957E-06 CH4,gas 0.7146E+00 1.0014 0.2629E+01 0.2625E+01 H2,gas 0.4131E-02 1.0020 0.1521E-01 0.1518E-01 H2S,gas 0.1009E-05 0.9858 0.3655E-05 0.3708E-05 S2,gas 0.5904E-27 1.0000 0.2169E-26 0.2169E-26 CO,gas 0.5432E-12 1.0000 0.1996E-11 0.1996E-11 SO3,gas 0.5187E-47 1.0000 0.1906E-46 0.1906E-46 SO2,gas 0.3069E-26 1.0000 0.1127E-25 0.1127E-25 HF,gas 0.3258E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2391E-17 1.0000 0.8783E-17 0.8783E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.67 -8.01 -2.669 0.13671E+05 -6.308 3 CH4,gas 4.54 3.26 -1.28 -0.320 0.21842E+04 0.420 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.37 -7.14 -3.568 0.12185E+05 -5.437 6 S2,gas -7.34 -35.70 -28.36 -4.364 0.48429E+05 -26.664 7 CO,gas 3.21 -10.18 -13.40 -4.123 0.22878E+05 -11.700 8 SO3,gas 17.12 -31.30 -48.42 -12.105 0.82674E+05 -46.720 9 SO2,gas 0.83 -26.81 -27.65 -7.373 0.47206E+05 -25.948 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.57 -18.76 -9.378 0.32024E+05 -17.056 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80682E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93629E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.56 -2.53 -0.844 0.43224E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 40 calcite 0.81 -1.56 -2.38 -0.792 0.40582E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65540E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.70 -2.60 -0.742 0.44373E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.70 -2.15 -0.616 0.36795E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82232E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.48 -3.23 -0.761 0.55211E+04 146 pyrrhotite -4.26 -6.63 -2.37 -0.790 0.40484E+04 147 pyrrhotiteFe0.875 -6.02 -8.03 -2.01 -0.740 0.34356E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22436E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.42 -4.45 -1.483 0.75954E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23238E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47109E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77496E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.63 -2.22 -0.740 0.37912E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.12 -3.15 -1.049 0.53723E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0127900 MOLES New total amount of reactant added: 0.0131900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8651E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0131900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4966E+00 Moles total = -.7158E+01 kg total = -.1290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1032712E-01 Osmotic coef. = 0.9168 True ionic strength = .2069338E-01 Chg. balance for total moles = -.8651E-10 Max. difference allowed = 0.2157E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90981E-10 -10.0411 0.76286E-10 -10.1176 0.83848E+00 -0.0765 2 H2O 0.99997E+00 0.0000 0.99997E+00 0.0000 3 Cl- 0.43233E-03 -3.3642 0.36026E-03 -3.4434 0.83331E+00 -0.0792 4 SO4-- 0.17320E-10 -10.7615 0.89162E-11 -11.0498 0.51479E+00 -0.2884 5 HCO3- 0.34876E-04 -4.4575 0.29106E-04 -4.5360 0.83456E+00 -0.0785 6 HS- 0.69668E-03 -3.1570 0.58064E-03 -3.2361 0.83343E+00 -0.0791 7 Al+++ 0.10748E-28 -28.9687 0.24341E-29 -29.6137 0.22647E+00 -0.6450 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14400E-06 -6.8416 0.73573E-07 -7.1333 0.51091E+00 -0.2917 10 Mg++ 0.22531E-10 -10.6472 0.11457E-10 -10.9409 0.50851E+00 -0.2937 11 Fe++ 0.62099E-13 -13.2069 0.31614E-13 -13.5001 0.50909E+00 -0.2932 12 K+ 0.16128E-03 -3.7924 0.13463E-03 -3.8709 0.83476E+00 -0.0784 13 Na+ 0.20467E-01 -1.6890 0.17052E-01 -1.7682 0.83315E+00 -0.0793 14 Mn++ 0.19946E-10 -10.7001 0.10163E-10 -10.9930 0.50952E+00 -0.2928 15 F- 0.11224E-05 -5.9498 0.93335E-06 -6.0300 0.83155E+00 -0.0801 16 HPO4-- 0.43239E-07 -7.3641 0.22262E-07 -7.6524 0.51487E+00 -0.2883 18 HSiO3- 0.10223E-01 -1.9904 0.85188E-02 -2.0696 0.83331E+00 -0.0792 19 Ca(HSiO3)+ 0.17095E-07 -7.7671 0.14273E-07 -7.8455 0.83495E+00 -0.0783 20 Mg(HSiO3)+ 0.33131E-11 -11.4798 0.27663E-11 -11.5581 0.83495E+00 -0.0783 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.68148E-16 -16.1665 0.56900E-16 -16.2449 0.83495E+00 -0.0783 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51818E-05 -5.2855 0.43100E-05 -5.3655 0.83177E+00 -0.0800 26 CH4,aq 0.18470E-02 -2.7335 0.18411E-02 -2.7349 0.99685E+00 -0.0014 27 C2H6,aq 0.50192E-10 -10.2994 0.50034E-10 -10.3007 0.99685E+00 -0.0014 28 C3H8,aq 0.31491E-16 -16.5018 0.31392E-16 -16.5032 0.99685E+00 -0.0014 30 ethanol,aq 0.18422E-17 -17.7347 0.18364E-17 -17.7360 0.99685E+00 -0.0014 31 CO,aq 0.13805E-14 -14.8600 0.13805E-14 -14.8600 0.10000E+01 0.0000 32 CO2,aq 0.47596E-08 -8.3224 0.47446E-08 -8.3238 0.99685E+00 -0.0014 33 CO3-2 0.64878E-04 -4.1879 0.33326E-04 -4.4772 0.51367E+00 -0.2893 34 CaCO3,aq 0.30744E-07 -7.5122 0.30744E-07 -7.5122 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.65467E-10 -10.1840 0.54662E-10 -10.2623 0.83495E+00 -0.0783 36 CaCl+ 0.51374E-10 -10.2893 0.42894E-10 -10.3676 0.83495E+00 -0.0783 37 CaCl2,aq 0.36714E-14 -14.4352 0.36714E-14 -14.4352 0.10000E+01 0.0000 38 CaF+ 0.12008E-11 -11.9205 0.10026E-11 -11.9989 0.83495E+00 -0.0783 39 CaOH+ 0.82320E-07 -7.0845 0.68733E-07 -7.1628 0.83495E+00 -0.0783 40 CaSO4,aq 0.20831E-15 -15.6813 0.20831E-15 -15.6813 0.10000E+01 0.0000 41 HCl,aq 0.50361E-14 -14.2979 0.50361E-14 -14.2979 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18432E-18 -18.7344 0.15360E-18 -18.8136 0.83331E+00 -0.0792 48 FeCl+ 0.21591E-16 -16.6657 0.18027E-16 -16.7441 0.83495E+00 -0.0783 51 FeF+ 0.18059E-17 -17.7433 0.15078E-17 -17.8216 0.83495E+00 -0.0783 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16156E-10 -10.7917 0.13489E-10 -10.8700 0.83495E+00 -0.0783 55 HFeO2- 0.34748E-07 -7.4591 0.28956E-07 -7.5383 0.83331E+00 -0.0792 56 FeO+ 0.11323E-16 -16.9460 0.94539E-17 -17.0244 0.83495E+00 -0.0783 58 FeO2- 0.39889E-09 -9.3991 0.33240E-09 -9.4783 0.83331E+00 -0.0792 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11619E-04 -4.9348 0.11582E-04 -4.9362 0.99685E+00 -0.0014 61 KCl,aq 0.87907E-09 -9.0560 0.87907E-09 -9.0560 0.10000E+01 0.0000 63 KOH,aq 0.75365E-06 -6.1228 0.75365E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.22353E-13 -13.6507 0.18627E-13 -13.7299 0.83331E+00 -0.0792 65 MgCO3,aq 0.12001E-11 -11.9208 0.12001E-11 -11.9208 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10417E-13 -13.9822 0.86980E-14 -14.0606 0.83495E+00 -0.0783 67 MgCl+ 0.72510E-14 -14.1396 0.60542E-14 -14.2179 0.83495E+00 -0.0783 68 MgF+ 0.69267E-15 -15.1595 0.57835E-15 -15.2378 0.83495E+00 -0.0783 69 MgOH+ 0.70936E-10 -10.1491 0.59228E-10 -10.2275 0.83495E+00 -0.0783 71 MnF+ 0.19136E-15 -15.7182 0.15977E-15 -15.7965 0.83495E+00 -0.0783 72 MnO,aq 0.18085E-08 -8.7427 0.18085E-08 -8.7427 0.10000E+01 0.0000 73 MnOH+ 0.48247E-09 -9.3165 0.40283E-09 -9.3949 0.83495E+00 -0.0783 74 MnO2-2 0.20077E-10 -10.6973 0.10313E-10 -10.9866 0.51367E+00 -0.2893 75 HMnO2- 0.20684E-09 -9.6844 0.17236E-09 -9.7636 0.83331E+00 -0.0792 78 MnCl+ 0.27003E-13 -13.5686 0.22546E-13 -13.6469 0.83495E+00 -0.0783 79 MnSO4,aq 0.26160E-19 -19.5824 0.26160E-19 -19.5824 0.10000E+01 0.0000 80 NaCl,aq 0.20359E-05 -5.6913 0.20359E-05 -5.6913 0.10000E+01 0.0000 81 NaF,aq 0.37261E-08 -8.4287 0.37261E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96034E-04 -4.0176 0.96034E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.91054E-02 -2.0407 0.75736E-02 -2.1207 0.83177E+00 -0.0800 89 HPO3-2 0.15644E-14 -14.8057 0.80356E-15 -15.0950 0.51367E+00 -0.2893 91 H2PO3- 0.14752E-18 -18.8312 0.12293E-18 -18.9104 0.83331E+00 -0.0792 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37559E-10 -10.4253 0.31329E-10 -10.5041 0.83412E+00 -0.0788 94 PO4-3 0.99974E-09 -9.0001 0.23810E-09 -9.6232 0.23816E+00 -0.6231 98 HP2O7-3 0.88861E-18 -18.0513 0.20145E-18 -18.6958 0.22670E+00 -0.6445 99 P2O7-4 0.84702E-17 -17.0721 0.63086E-18 -18.2001 0.74479E-01 -1.1280 100 H2S,aq 0.13733E-06 -6.8622 0.13690E-06 -6.8636 0.99685E+00 -0.0014 101 S2-2 0.12556E-11 -11.9011 0.64498E-12 -12.1905 0.51367E+00 -0.2893 102 S3-2 0.19995E-19 -19.6991 0.10271E-19 -19.9884 0.51367E+00 -0.2893 107 SO3-2 0.25744E-16 -16.5893 0.13420E-16 -16.8722 0.52130E+00 -0.2829 108 HSO3- 0.76923E-19 -19.1139 0.64100E-19 -19.1931 0.83331E+00 -0.0792 109 HSO4- 0.78429E-18 -18.1055 0.65550E-18 -18.1834 0.83578E+00 -0.0779 111 S2O3-2 0.27914E-19 -19.5542 0.14339E-19 -19.8435 0.51367E+00 -0.2893 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9098068E-10 -.2186304E-01 -.2199708E+02 0.0000 2 H2O 0.1000000E+01 0.5550675E+02 0.9981760E+06 0.0000 3 Cl- 0.4323283E-03 0.4343651E-03 0.1537191E+02 6.6742 4 SO4-- 0.1731989E-10 -.1849861E-02 -.1773817E+03 9.1853 5 HCO3- 0.3487601E-04 0.1946746E-02 0.1185718E+03 5.5815 6 HS- 0.6966777E-03 0.2546676E-02 0.8407251E+02 6.8815 7 Al+++ 0.1074811E-28 0.5181947E-05 0.1395658E+00 0.7390 8 H4SiO4 0.6959536E-03 0.1326821E-01 0.1272991E+04 -3.1574 9 Ca++ 0.1440025E-06 0.2742792E-06 0.1097283E-01 13.1018 10 Mg++ 0.2253081E-10 0.9799952E-10 0.2378288E-05 9.2942 11 Fe++ 0.6209888E-13 0.3537794E-07 0.1972206E-02 6.7350 12 K+ 0.1612800E-03 0.1620345E-03 0.6324502E+01 6.2467 13 Na+ 0.2046664E-01 0.2291411E-01 0.5258454E+03 8.3493 14 Mn++ 0.1994617E-10 0.2537825E-08 0.1391728E-03 9.2421 15 F- 0.1122425E-05 0.1126153E-05 0.2135625E-01 4.0876 16 HPO4-- 0.4323901E-07 0.4427631E-07 0.4241969E-02 12.5827 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279113E+02 -.1085665E-01 -.8278027E+02 0.0000000E+00 2 H2O -.7157990E+01 0.2756331E+02 -.3472130E+02 0.0000000E+00 3 Cl- 0.2156952E-03 0.2156952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386555E+00 -.9185962E-03 0.1395741E+00 0.0000000E+00 5 HCO3- 0.9667070E-03 0.9667070E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383095E+00 0.1264618E-02 -.1395741E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2573229E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6588673E-02 0.5205732E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1362004E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4866418E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1756783E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8046241E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1137859E-01 0.6264998E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1260222E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5376000E-05 0.5592201E-06 0.4816780E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2198654E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.2354E-13 Mass of aqueous solution: 0.497469E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0131900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.796 1641. 3.215 30.04 630.0 andradite 0.5583 -0.253 283.7 2.453 5.194 73.71 grossular 0.1352 -0.869 60.90 1.785 1.115 16.94 apatite-OH 0.9858E-02 -2.006 4.952 0.695 0.9065E-01 1.573 apatite-F 0.4817E-05 -5.317 0.2429E-02 -2.615 0.4447E-04 0.7589E-03 clinochlore 0.7094 -0.149 394.3 2.596 7.219 150.0 daphnite 0.2054 -0.687 146.5 2.166 2.683 44.40 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2375 -0.624 51.43 1.711 0.9414 15.72 hedenbergite 0.6158E-01 -1.211 15.28 1.184 0.2797 4.185 microcline 0.9318 -0.031 259.4 2.414 4.748 101.3 stilbite 3.220 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2593 -0.586 279.5 2.446 5.118 96.56 tr.625ac.25prg.125 0.5071E-01 -1.295 43.35 1.637 0.7935 13.95 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.341975 g Volume = 2210.814248 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0131900 moles log = -1.8798 Original solution: 1000.0103000 g Original solution / Rock added: 75815.79 (Water/Rock Ratio), log = 4.8798 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 3.7551 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2752E+00 0.9734 0.1006E+01 0.1033E+01 CO2,gas 0.1361E-06 0.9931 0.5076E-06 0.5112E-06 CH4,gas 0.7207E+00 1.0013 0.2710E+01 0.2707E+01 H2,gas 0.4041E-02 1.0020 0.1521E-01 0.1518E-01 H2S,gas 0.1017E-05 0.9855 0.3763E-05 0.3818E-05 S2,gas 0.6122E-27 1.0000 0.2299E-26 0.2299E-26 CO,gas 0.5478E-12 1.0000 0.2057E-11 0.2057E-11 SO3,gas 0.5225E-47 1.0000 0.1962E-46 0.1962E-46 SO2,gas 0.3091E-26 1.0000 0.1161E-25 0.1161E-25 HF,gas 0.3187E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2366E-17 1.0000 0.8886E-17 0.8886E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.78860E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.65 -7.99 -2.664 0.13649E+05 -6.294 3 CH4,gas 4.54 3.28 -1.27 -0.316 0.21617E+04 0.433 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.35 -7.12 -3.562 0.12163E+05 -5.424 6 S2,gas -7.34 -35.67 -28.34 -4.360 0.48385E+05 -26.638 7 CO,gas 3.21 -10.17 -13.39 -4.119 0.22856E+05 -11.687 8 SO3,gas 17.12 -31.28 -48.41 -12.102 0.82652E+05 -46.707 9 SO2,gas 0.83 -26.80 -27.63 -7.369 0.47185E+05 -25.935 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.56 -18.75 -9.375 0.32016E+05 -17.051 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80681E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93630E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 38 aragonite 0.97 -1.55 -2.52 -0.839 0.42999E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.55 -2.36 -0.788 0.40356E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65539E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.69 -2.59 -0.739 0.44147E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.69 -2.14 -0.612 0.36570E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82232E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.46 -3.21 -0.755 0.54779E+04 146 pyrrhotite -4.26 -6.62 -2.36 -0.786 0.40268E+04 147 pyrrhotiteFe0.875 -6.02 -8.02 -2.00 -0.735 0.34140E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22435E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.41 -4.44 -1.478 0.75728E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23238E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47108E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.62 -2.21 -0.736 0.37696E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.11 -3.13 -1.045 0.53506E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0131900 MOLES New total amount of reactant added: 0.0135900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8650E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0135900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4966E+00 Moles total = -.7158E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .1029345E-01 Osmotic coef. = 0.9171 True ionic strength = .2071140E-01 Chg. balance for total moles = -.8650E-10 Max. difference allowed = 0.2181E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91052E-10 -10.0407 0.76341E-10 -10.1172 0.83844E+00 -0.0765 2 H2O 0.99997E+00 0.0000 0.99997E+00 0.0000 3 Cl- 0.43705E-03 -3.3595 0.36418E-03 -3.4387 0.83326E+00 -0.0792 4 SO4-- 0.17796E-10 -10.7497 0.91593E-11 -11.0381 0.51467E+00 -0.2885 5 HCO3- 0.35897E-04 -4.4449 0.29957E-04 -4.5235 0.83451E+00 -0.0786 6 HS- 0.71624E-03 -3.1449 0.59690E-03 -3.2241 0.83338E+00 -0.0792 7 Al+++ 0.10777E-28 -28.9675 0.24394E-29 -29.6127 0.22635E+00 -0.6452 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14425E-06 -6.8409 0.73680E-07 -7.1327 0.51079E+00 -0.2918 10 Mg++ 0.22569E-10 -10.6465 0.11474E-10 -10.9403 0.50839E+00 -0.2938 11 Fe++ 0.62204E-13 -13.2062 0.31660E-13 -13.4995 0.50896E+00 -0.2933 12 K+ 0.16141E-03 -3.7921 0.13473E-03 -3.8705 0.83471E+00 -0.0785 13 Na+ 0.20483E-01 -1.6886 0.17064E-01 -1.7679 0.83310E+00 -0.0793 14 Mn++ 0.19981E-10 -10.6994 0.10178E-10 -10.9923 0.50940E+00 -0.2929 15 F- 0.11217E-05 -5.9501 0.93267E-06 -6.0303 0.83150E+00 -0.0801 16 HPO4-- 0.43186E-07 -7.3647 0.22230E-07 -7.6531 0.51475E+00 -0.2884 18 HSiO3- 0.10216E-01 -1.9907 0.85126E-02 -2.0699 0.83326E+00 -0.0792 19 Ca(HSiO3)+ 0.17108E-07 -7.7668 0.14284E-07 -7.8452 0.83490E+00 -0.0784 20 Mg(HSiO3)+ 0.33157E-11 -11.4794 0.27683E-11 -11.5578 0.83490E+00 -0.0784 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.68201E-16 -16.1662 0.56941E-16 -16.2446 0.83490E+00 -0.0784 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51784E-05 -5.2858 0.43069E-05 -5.3658 0.83171E+00 -0.0800 26 CH4,aq 0.19023E-02 -2.7207 0.18963E-02 -2.7221 0.99686E+00 -0.0014 27 C2H6,aq 0.53245E-10 -10.2737 0.53077E-10 -10.2751 0.99686E+00 -0.0014 28 C3H8,aq 0.34407E-16 -16.4634 0.34299E-16 -16.4647 0.99686E+00 -0.0014 30 ethanol,aq 0.19543E-17 -17.7090 0.19481E-17 -17.7104 0.99686E+00 -0.0014 31 CO,aq 0.14219E-14 -14.8471 0.14219E-14 -14.8471 0.10000E+01 0.0000 32 CO2,aq 0.49022E-08 -8.3096 0.48868E-08 -8.3110 0.99686E+00 -0.0014 33 CO3-2 0.66741E-04 -4.1756 0.34275E-04 -4.4650 0.51355E+00 -0.2894 34 CaCO3,aq 0.31665E-07 -7.4994 0.31665E-07 -7.4994 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.67482E-10 -10.1708 0.56341E-10 -10.2492 0.83490E+00 -0.0784 36 CaCl+ 0.52010E-10 -10.2839 0.43423E-10 -10.3623 0.83490E+00 -0.0784 37 CaCl2,aq 0.37570E-14 -14.4252 0.37570E-14 -14.4252 0.10000E+01 0.0000 38 CaF+ 0.12017E-11 -11.9202 0.10033E-11 -11.9986 0.83490E+00 -0.0784 39 CaOH+ 0.82384E-07 -7.0842 0.68782E-07 -7.1625 0.83490E+00 -0.0784 40 CaSO4,aq 0.21430E-15 -15.6690 0.21430E-15 -15.6690 0.10000E+01 0.0000 41 HCl,aq 0.50945E-14 -14.2929 0.50945E-14 -14.2929 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18420E-18 -18.7347 0.15349E-18 -18.8139 0.83326E+00 -0.0792 48 FeCl+ 0.21858E-16 -16.6604 0.18250E-16 -16.7387 0.83490E+00 -0.0784 51 FeF+ 0.18073E-17 -17.7430 0.15089E-17 -17.8213 0.83490E+00 -0.0784 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16168E-10 -10.7913 0.13499E-10 -10.8697 0.83490E+00 -0.0784 55 HFeO2- 0.34725E-07 -7.4594 0.28935E-07 -7.5386 0.83326E+00 -0.0792 56 FeO+ 0.11332E-16 -16.9457 0.94608E-17 -17.0241 0.83490E+00 -0.0784 58 FeO2- 0.39863E-09 -9.3994 0.33216E-09 -9.4787 0.83326E+00 -0.0792 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11619E-04 -4.9348 0.11582E-04 -4.9362 0.99686E+00 -0.0014 61 KCl,aq 0.88926E-09 -9.0510 0.88926E-09 -9.0510 0.10000E+01 0.0000 63 KOH,aq 0.75365E-06 -6.1228 0.75365E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.22981E-13 -13.6386 0.19149E-13 -13.7179 0.83326E+00 -0.0792 65 MgCO3,aq 0.12360E-11 -11.9080 0.12360E-11 -11.9080 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10738E-13 -13.9691 0.89652E-14 -14.0474 0.83490E+00 -0.0784 67 MgCl+ 0.73408E-14 -14.1343 0.61288E-14 -14.2126 0.83490E+00 -0.0784 68 MgF+ 0.69322E-15 -15.1591 0.57876E-15 -15.2375 0.83490E+00 -0.0784 69 MgOH+ 0.70992E-10 -10.1488 0.59271E-10 -10.2272 0.83490E+00 -0.0784 71 MnF+ 0.19151E-15 -15.7178 0.15989E-15 -15.7962 0.83490E+00 -0.0784 72 MnO,aq 0.18085E-08 -8.7427 0.18085E-08 -8.7427 0.10000E+01 0.0000 73 MnOH+ 0.48286E-09 -9.3162 0.40314E-09 -9.3945 0.83490E+00 -0.0784 74 MnO2-2 0.20053E-10 -10.6978 0.10298E-10 -10.9872 0.51355E+00 -0.2894 75 HMnO2- 0.20671E-09 -9.6846 0.17224E-09 -9.7639 0.83326E+00 -0.0792 78 MnCl+ 0.27339E-13 -13.5632 0.22825E-13 -13.6416 0.83490E+00 -0.0784 79 MnSO4,aq 0.26913E-19 -19.5700 0.26913E-19 -19.5700 0.10000E+01 0.0000 80 NaCl,aq 0.20595E-05 -5.6862 0.20595E-05 -5.6862 0.10000E+01 0.0000 81 NaF,aq 0.37261E-08 -8.4288 0.37261E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96034E-04 -4.0176 0.96034E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90993E-02 -2.0410 0.75681E-02 -2.1210 0.83171E+00 -0.0800 89 HPO3-2 0.15624E-14 -14.8062 0.80240E-15 -15.0956 0.51355E+00 -0.2894 91 H2PO3- 0.14742E-18 -18.8315 0.12284E-18 -18.9107 0.83326E+00 -0.0792 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37534E-10 -10.4256 0.31306E-10 -10.5044 0.83407E+00 -0.0788 94 PO4-3 0.99805E-09 -9.0008 0.23758E-09 -9.6242 0.23805E+00 -0.6233 98 HP2O7-3 0.88715E-18 -18.0520 0.20101E-18 -18.6968 0.22658E+00 -0.6448 99 P2O7-4 0.84534E-17 -17.0730 0.62903E-18 -18.2013 0.74411E-01 -1.1284 100 H2S,aq 0.14128E-06 -6.8499 0.14083E-06 -6.8513 0.99686E+00 -0.0014 101 S2-2 0.13273E-11 -11.8770 0.68163E-12 -12.1665 0.51355E+00 -0.2894 102 S3-2 0.21744E-19 -19.6627 0.11167E-19 -19.9521 0.51355E+00 -0.2894 107 SO3-2 0.26452E-16 -16.5775 0.13786E-16 -16.8606 0.52118E+00 -0.2830 108 HSO3- 0.79082E-19 -19.1019 0.65896E-19 -19.1811 0.83326E+00 -0.0792 109 HSO4- 0.80631E-18 -18.0935 0.67386E-18 -18.1714 0.83573E+00 -0.0779 111 S2O3-2 0.29507E-19 -19.5301 0.15153E-19 -19.8195 0.51355E+00 -0.2894 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9105182E-10 -.2185201E-01 -.2198595E+02 0.0000 2 H2O 0.1000000E+01 0.5550681E+02 0.9981754E+06 0.0000 3 Cl- 0.4370508E-03 0.4391112E-03 0.1553984E+02 6.6786 4 SO4-- 0.1779627E-10 -.1905186E-02 -.1826864E+03 9.1963 5 HCO3- 0.3589715E-04 0.2004956E-02 0.1221170E+03 5.5937 6 HS- 0.7162373E-03 0.2621564E-02 0.8654462E+02 6.8931 7 Al+++ 0.1077724E-28 0.5178505E-05 0.1394728E+00 0.7390 8 H4SiO4 0.6959528E-03 0.1326140E-01 0.1272335E+04 -3.1574 9 Ca++ 0.1442457E-06 0.2755243E-06 0.1102263E-01 13.1018 10 Mg++ 0.2256894E-10 0.9813222E-10 0.2381505E-05 9.2942 11 Fe++ 0.6220397E-13 0.3535451E-07 0.1970896E-02 6.7350 12 K+ 0.1614061E-03 0.1621606E-03 0.6329414E+01 6.2467 13 Na+ 0.2048267E-01 0.2293016E-01 0.5262128E+03 8.3493 14 Mn++ 0.1998068E-10 0.2538173E-08 0.1391916E-03 9.2422 15 F- 0.1121678E-05 0.1125406E-05 0.2134205E-01 4.0870 16 HPO4-- 0.4318624E-07 0.4422183E-07 0.4236743E-02 12.5814 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279108E+02 -.1085134E-01 -.8278023E+02 0.0000000E+00 2 H2O -.7157663E+01 0.2756374E+02 -.3472140E+02 0.0000000E+00 3 Cl- 0.2180552E-03 0.2180552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386574E+00 -.9460829E-03 0.1396035E+00 0.0000000E+00 5 HCO3- 0.9956270E-03 0.9956270E-03 0.0000000E+00 0.0000000E+00 6 HS- -.1383017E+00 0.1301824E-02 -.1396035E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2571558E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6585385E-02 0.5205732E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1368207E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4873080E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1755645E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8052622E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1138673E-01 0.6264990E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1260414E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5536000E-05 0.5588574E-06 0.4977143E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2195981E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.7556E-14 Mass of aqueous solution: 0.497477E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0135900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.796 1641. 3.215 30.04 630.0 andradite 0.5584 -0.253 283.8 2.453 5.195 73.73 grossular 0.1352 -0.869 60.91 1.785 1.115 16.95 apatite-OH 0.9858E-02 -2.006 4.952 0.695 0.9065E-01 1.573 apatite-F 0.4977E-05 -5.303 0.2510E-02 -2.600 0.4595E-04 0.7841E-03 clinochlore 0.7094 -0.149 394.3 2.596 7.218 150.0 daphnite 0.2054 -0.687 146.5 2.166 2.683 44.40 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2367 -0.626 51.26 1.710 0.9384 15.67 hedenbergite 0.6139E-01 -1.212 15.23 1.183 0.2788 4.171 microcline 0.9319 -0.031 259.4 2.414 4.748 101.3 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2593 -0.586 279.5 2.446 5.117 96.54 tr.625ac.25prg.125 0.5096E-01 -1.293 43.56 1.639 0.7975 14.02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.342095 g Volume = 2210.815351 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0135900 moles log = -1.8668 Original solution: 1000.0103000 g Original solution / Rock added: 73584.28 (Water/Rock Ratio), log = 4.8668 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 3.8368 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2694E+00 0.9732 0.1006E+01 0.1034E+01 CO2,gas 0.1372E-06 0.9929 0.5228E-06 0.5266E-06 CH4,gas 0.7266E+00 1.0012 0.2791E+01 0.2788E+01 H2,gas 0.3955E-02 1.0020 0.1521E-01 0.1517E-01 H2S,gas 0.1024E-05 0.9852 0.3871E-05 0.3930E-05 S2,gas 0.6342E-27 1.0000 0.2433E-26 0.2433E-26 CO,gas 0.5523E-12 1.0000 0.2119E-11 0.2119E-11 SO3,gas 0.5261E-47 1.0000 0.2018E-46 0.2018E-46 SO2,gas 0.3112E-26 1.0000 0.1194E-25 0.1194E-25 HF,gas 0.3119E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2343E-17 1.0000 0.8989E-17 0.8989E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.64 -7.98 -2.660 0.13627E+05 -6.282 3 CH4,gas 4.54 3.29 -1.25 -0.313 0.21398E+04 0.446 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.34 -7.11 -3.556 0.12142E+05 -5.412 6 S2,gas -7.34 -35.65 -28.31 -4.356 0.48343E+05 -26.614 7 CO,gas 3.21 -10.16 -13.37 -4.115 0.22834E+05 -11.674 8 SO3,gas 17.12 -31.27 -48.39 -12.098 0.82631E+05 -46.695 9 SO2,gas 0.83 -26.79 -27.62 -7.366 0.47164E+05 -25.923 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.56 -18.75 -9.373 0.32007E+05 -17.046 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80680E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93630E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.54 -2.51 -0.835 0.42780E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.54 -2.35 -0.784 0.40137E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65539E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.68 -2.57 -0.735 0.43928E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.68 -2.13 -0.608 0.36351E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82232E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.43 -3.18 -0.749 0.54358E+04 146 pyrrhotite -4.26 -6.61 -2.35 -0.782 0.40058E+04 147 pyrrhotiteFe0.875 -6.02 -8.00 -1.99 -0.731 0.33930E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22435E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.40 -4.42 -1.474 0.75509E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23238E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47108E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 184 troilite-low -4.41 -6.61 -2.20 -0.732 0.37486E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.10 -3.12 -1.040 0.53296E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0135900 MOLES New total amount of reactant added: 0.0139900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8649E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0139900 Water: Moles liquid = 0.2756E+02 kg liquid = 0.4966E+00 Moles total = -.7157E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .1025978E-01 Osmotic coef. = 0.9173 True ionic strength = .2072942E-01 Chg. balance for total moles = -.8649E-10 Max. difference allowed = 0.2204E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91123E-10 -10.0404 0.76397E-10 -10.1169 0.83839E+00 -0.0766 2 H2O 0.99996E+00 0.0000 0.99996E+00 0.0000 3 Cl- 0.44177E-03 -3.3548 0.36809E-03 -3.4340 0.83321E+00 -0.0792 4 SO4-- 0.18272E-10 -10.7382 0.94020E-11 -11.0268 0.51456E+00 -0.2886 5 HCO3- 0.36917E-04 -4.4328 0.30806E-04 -4.5114 0.83446E+00 -0.0786 6 HS- 0.73580E-03 -3.1332 0.61316E-03 -3.2124 0.83333E+00 -0.0792 7 Al+++ 0.10806E-28 -28.9663 0.24447E-29 -29.6118 0.22623E+00 -0.6455 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14449E-06 -6.8402 0.73787E-07 -7.1320 0.51067E+00 -0.2919 10 Mg++ 0.22607E-10 -10.6458 0.11491E-10 -10.9397 0.50827E+00 -0.2939 11 Fe++ 0.62309E-13 -13.2054 0.31706E-13 -13.4989 0.50884E+00 -0.2934 12 K+ 0.16153E-03 -3.7917 0.13483E-03 -3.8702 0.83466E+00 -0.0785 13 Na+ 0.20499E-01 -1.6883 0.17077E-01 -1.7676 0.83305E+00 -0.0793 14 Mn++ 0.20015E-10 -10.6986 0.10193E-10 -10.9917 0.50928E+00 -0.2930 15 F- 0.11209E-05 -5.9504 0.93199E-06 -6.0306 0.83145E+00 -0.0802 16 HPO4-- 0.43134E-07 -7.3652 0.22198E-07 -7.6537 0.51463E+00 -0.2885 18 HSiO3- 0.10209E-01 -1.9910 0.85064E-02 -2.0703 0.83321E+00 -0.0792 19 Ca(HSiO3)+ 0.17122E-07 -7.7664 0.14294E-07 -7.8448 0.83485E+00 -0.0784 20 Mg(HSiO3)+ 0.33183E-11 -11.4791 0.27703E-11 -11.5575 0.83485E+00 -0.0784 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.68255E-16 -16.1659 0.56983E-16 -16.2443 0.83485E+00 -0.0784 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51749E-05 -5.2861 0.43038E-05 -5.3661 0.83166E+00 -0.0801 26 CH4,aq 0.19576E-02 -2.7083 0.19515E-02 -2.7096 0.99687E+00 -0.0014 27 C2H6,aq 0.56388E-10 -10.2488 0.56211E-10 -10.2502 0.99687E+00 -0.0014 28 C3H8,aq 0.37498E-16 -16.4260 0.37381E-16 -16.4273 0.99687E+00 -0.0014 30 ethanol,aq 0.20696E-17 -17.6841 0.20632E-17 -17.6855 0.99687E+00 -0.0014 31 CO,aq 0.14632E-14 -14.8347 0.14632E-14 -14.8347 0.10000E+01 0.0000 32 CO2,aq 0.50448E-08 -8.2972 0.50290E-08 -8.2985 0.99687E+00 -0.0014 33 CO3-2 0.68599E-04 -4.1637 0.35221E-04 -4.4532 0.51343E+00 -0.2895 34 CaCO3,aq 0.32587E-07 -7.4870 0.32587E-07 -7.4870 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.69500E-10 -10.1580 0.58022E-10 -10.2364 0.83485E+00 -0.0784 36 CaCl+ 0.52648E-10 -10.2786 0.43954E-10 -10.3570 0.83485E+00 -0.0784 37 CaCl2,aq 0.38437E-14 -14.4152 0.38437E-14 -14.4152 0.10000E+01 0.0000 38 CaF+ 0.12026E-11 -11.9199 0.10040E-11 -11.9983 0.83485E+00 -0.0784 39 CaOH+ 0.82449E-07 -7.0838 0.68832E-07 -7.1622 0.83485E+00 -0.0784 40 CaSO4,aq 0.22030E-15 -15.6570 0.22030E-15 -15.6570 0.10000E+01 0.0000 41 HCl,aq 0.51530E-14 -14.2879 0.51530E-14 -14.2879 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18408E-18 -18.7350 0.15337E-18 -18.8142 0.83321E+00 -0.0792 48 FeCl+ 0.22127E-16 -16.6551 0.18472E-16 -16.7335 0.83485E+00 -0.0784 51 FeF+ 0.18087E-17 -17.7426 0.15100E-17 -17.8210 0.83485E+00 -0.0784 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16181E-10 -10.7910 0.13509E-10 -10.8694 0.83485E+00 -0.0784 55 HFeO2- 0.34702E-07 -7.4596 0.28914E-07 -7.5389 0.83321E+00 -0.0792 56 FeO+ 0.11341E-16 -16.9454 0.94677E-17 -17.0238 0.83485E+00 -0.0784 58 FeO2- 0.39836E-09 -9.3997 0.33192E-09 -9.4790 0.83321E+00 -0.0792 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11619E-04 -4.9348 0.11582E-04 -4.9362 0.99687E+00 -0.0014 61 KCl,aq 0.89946E-09 -9.0460 0.89946E-09 -9.0460 0.10000E+01 0.0000 63 KOH,aq 0.75365E-06 -6.1228 0.75365E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.23608E-13 -13.6269 0.19671E-13 -13.7062 0.83321E+00 -0.0792 65 MgCO3,aq 0.12720E-11 -11.8955 0.12720E-11 -11.8955 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11059E-13 -13.9563 0.92327E-14 -14.0347 0.83485E+00 -0.0784 67 MgCl+ 0.74309E-14 -14.1290 0.62037E-14 -14.2074 0.83485E+00 -0.0784 68 MgF+ 0.69376E-15 -15.1588 0.57918E-15 -15.2372 0.83485E+00 -0.0784 69 MgOH+ 0.71047E-10 -10.1485 0.59314E-10 -10.2268 0.83485E+00 -0.0784 71 MnF+ 0.19167E-15 -15.7174 0.16002E-15 -15.7958 0.83485E+00 -0.0784 72 MnO,aq 0.18086E-08 -8.7427 0.18086E-08 -8.7427 0.10000E+01 0.0000 73 MnOH+ 0.48326E-09 -9.3158 0.40345E-09 -9.3942 0.83485E+00 -0.0784 74 MnO2-2 0.20029E-10 -10.6983 0.10284E-10 -10.9878 0.51343E+00 -0.2895 75 HMnO2- 0.20658E-09 -9.6849 0.17212E-09 -9.7642 0.83321E+00 -0.0792 78 MnCl+ 0.27675E-13 -13.5579 0.23105E-13 -13.6363 0.83485E+00 -0.0784 79 MnSO4,aq 0.27668E-19 -19.5580 0.27668E-19 -19.5580 0.10000E+01 0.0000 80 NaCl,aq 0.20831E-05 -5.6813 0.20831E-05 -5.6813 0.10000E+01 0.0000 81 NaF,aq 0.37260E-08 -8.4288 0.37260E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96034E-04 -4.0176 0.96034E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90933E-02 -2.0413 0.75626E-02 -2.1213 0.83166E+00 -0.0801 89 HPO3-2 0.15605E-14 -14.8067 0.80123E-15 -15.0962 0.51343E+00 -0.2895 91 H2PO3- 0.14732E-18 -18.8317 0.12275E-18 -18.9110 0.83321E+00 -0.0792 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37509E-10 -10.4259 0.31284E-10 -10.5047 0.83402E+00 -0.0788 94 PO4-3 0.99637E-09 -9.0016 0.23707E-09 -9.6251 0.23793E+00 -0.6236 98 HP2O7-3 0.88568E-18 -18.0527 0.20057E-18 -18.6977 0.22646E+00 -0.6450 99 P2O7-4 0.84366E-17 -17.0738 0.62721E-18 -18.2026 0.74343E-01 -1.1288 100 H2S,aq 0.14523E-06 -6.8379 0.14478E-06 -6.8393 0.99687E+00 -0.0014 101 S2-2 0.14009E-11 -11.8536 0.71928E-12 -12.1431 0.51343E+00 -0.2895 102 S3-2 0.23592E-19 -19.6272 0.12113E-19 -19.9167 0.51343E+00 -0.2895 107 SO3-2 0.27159E-16 -16.5661 0.14151E-16 -16.8492 0.52107E+00 -0.2831 108 HSO3- 0.81242E-19 -19.0902 0.67691E-19 -19.1695 0.83321E+00 -0.0792 109 HSO4- 0.82833E-18 -18.0818 0.69222E-18 -18.1598 0.83569E+00 -0.0780 111 S2O3-2 0.31144E-19 -19.5066 0.15990E-19 -19.7961 0.51343E+00 -0.2895 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9112297E-10 -.2184099E-01 -.2197483E+02 0.0000 2 H2O 0.1000000E+01 0.5550686E+02 0.9981748E+06 0.0000 3 Cl- 0.4417731E-03 0.4438572E-03 0.1570777E+02 6.6829 4 SO4-- 0.1827211E-10 -.1960514E-02 -.1879915E+03 9.2071 5 HCO3- 0.3691703E-04 0.2063163E-02 0.1256621E+03 5.6056 6 HS- 0.7357963E-03 0.2696456E-02 0.8901684E+02 6.9045 7 Al+++ 0.1080644E-28 0.5175068E-05 0.1393800E+00 0.7390 8 H4SiO4 0.6959520E-03 0.1325459E-01 0.1271680E+04 -3.1574 9 Ca++ 0.1444892E-06 0.2767698E-06 0.1107244E-01 13.1018 10 Mg++ 0.2260711E-10 0.9826402E-10 0.2384700E-05 9.2942 11 Fe++ 0.6230918E-13 0.3533111E-07 0.1969589E-02 6.7350 12 K+ 0.1615322E-03 0.1622868E-03 0.6334328E+01 6.2467 13 Na+ 0.2049871E-01 0.2294621E-01 0.5265803E+03 8.3493 14 Mn++ 0.2001523E-10 0.2538521E-08 0.1392105E-03 9.2422 15 F- 0.1120932E-05 0.1124660E-05 0.2132787E-01 4.0863 16 HPO4-- 0.4313356E-07 0.4416745E-07 0.4231526E-02 12.5802 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279104E+02 -.1084602E-01 -.8278020E+02 0.0000000E+00 2 H2O -.7157335E+01 0.2756417E+02 -.3472151E+02 0.0000000E+00 3 Cl- 0.2204152E-03 0.2204152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386593E+00 -.9735723E-03 0.1396329E+00 0.0000000E+00 5 HCO3- 0.1024547E-02 0.1024547E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382939E+00 0.1339034E-02 -.1396329E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2569889E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6582101E-02 0.5205732E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1374412E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4879697E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1754509E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8059004E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1139487E-01 0.6264982E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1260605E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5696000E-05 0.5584952E-06 0.5137505E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2193313E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.3428E-14 Mass of aqueous solution: 0.497485E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0139900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.796 1641. 3.215 30.04 630.0 andradite 0.5585 -0.253 283.8 2.453 5.196 73.74 grossular 0.1352 -0.869 60.92 1.785 1.115 16.95 apatite-OH 0.9857E-02 -2.006 4.952 0.695 0.9065E-01 1.573 apatite-F 0.5138E-05 -5.289 0.2591E-02 -2.587 0.4743E-04 0.8094E-03 clinochlore 0.7093 -0.149 394.3 2.596 7.218 150.0 daphnite 0.2054 -0.687 146.5 2.166 2.682 44.40 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2359 -0.627 51.09 1.708 0.9354 15.62 hedenbergite 0.6119E-01 -1.213 15.18 1.181 0.2779 4.158 microcline 0.9319 -0.031 259.4 2.414 4.749 101.3 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2592 -0.586 279.4 2.446 5.115 96.52 tr.625ac.25prg.125 0.5121E-01 -1.291 43.77 1.641 0.8014 14.09 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.342216 g Volume = 2210.816455 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0139900 moles log = -1.8542 Original solution: 1000.0103000 g Original solution / Rock added: 71480.36 (Water/Rock Ratio), log = 4.8542 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 3.9184 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2638E+00 0.9730 0.1006E+01 0.1034E+01 CO2,gas 0.1383E-06 0.9926 0.5380E-06 0.5420E-06 CH4,gas 0.7323E+00 1.0010 0.2872E+01 0.2869E+01 H2,gas 0.3873E-02 1.0021 0.1521E-01 0.1517E-01 H2S,gas 0.1031E-05 0.9849 0.3980E-05 0.4041E-05 S2,gas 0.6562E-27 1.0000 0.2571E-26 0.2571E-26 CO,gas 0.5565E-12 1.0000 0.2181E-11 0.2181E-11 SO3,gas 0.5295E-47 1.0000 0.2075E-46 0.2075E-46 SO2,gas 0.3133E-26 1.0000 0.1228E-25 0.1228E-25 HF,gas 0.3054E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2320E-17 1.0000 0.9093E-17 0.9093E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.63 -7.97 -2.656 0.13605E+05 -6.269 3 CH4,gas 4.54 3.30 -1.24 -0.310 0.21185E+04 0.458 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.33 -7.10 -3.550 0.12122E+05 -5.400 6 S2,gas -7.34 -35.62 -28.29 -4.352 0.48302E+05 -26.590 7 CO,gas 3.21 -10.15 -13.36 -4.111 0.22813E+05 -11.661 8 SO3,gas 17.12 -31.26 -48.38 -12.095 0.82611E+05 -46.683 9 SO2,gas 0.83 -26.78 -27.61 -7.363 0.47143E+05 -25.911 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.55 -18.74 -9.370 0.31999E+05 -17.041 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80679E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93630E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.53 -2.49 -0.831 0.42567E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.53 -2.34 -0.779 0.39925E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65539E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.66 -2.56 -0.731 0.43716E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.66 -2.12 -0.605 0.36138E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82231E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36678E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.41 -3.16 -0.743 0.53949E+04 146 pyrrhotite -4.26 -6.59 -2.33 -0.778 0.39853E+04 147 pyrrhotiteFe0.875 -6.02 -7.99 -1.98 -0.726 0.33725E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22435E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.39 -4.41 -1.470 0.75296E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23237E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47107E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.59 -2.18 -0.728 0.37281E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.09 -3.11 -1.036 0.53091E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0139900 MOLES New total amount of reactant added: 0.0143900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8652E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0143900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4966E+00 Moles total = -.7157E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .1022611E-01 Osmotic coef. = 0.9176 True ionic strength = .2074744E-01 Chg. balance for total moles = -.8652E-10 Max. difference allowed = 0.2228E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91194E-10 -10.0400 0.76452E-10 -10.1166 0.83834E+00 -0.0766 2 H2O 0.99996E+00 0.0000 0.99996E+00 0.0000 3 Cl- 0.44650E-03 -3.3502 0.37200E-03 -3.4295 0.83316E+00 -0.0793 4 SO4-- 0.18747E-10 -10.7271 0.96444E-11 -11.0157 0.51444E+00 -0.2887 5 HCO3- 0.37936E-04 -4.4210 0.31654E-04 -4.4996 0.83441E+00 -0.0786 6 HS- 0.75535E-03 -3.1218 0.62943E-03 -3.2011 0.83328E+00 -0.0792 7 Al+++ 0.10836E-28 -28.9651 0.24500E-29 -29.6108 0.22611E+00 -0.6457 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14473E-06 -6.8394 0.73894E-07 -7.1314 0.51055E+00 -0.2920 10 Mg++ 0.22645E-10 -10.6450 0.11507E-10 -10.9390 0.50815E+00 -0.2940 11 Fe++ 0.62415E-13 -13.2047 0.31752E-13 -13.4982 0.50872E+00 -0.2935 12 K+ 0.16166E-03 -3.7914 0.13492E-03 -3.8699 0.83462E+00 -0.0785 13 Na+ 0.20515E-01 -1.6879 0.17089E-01 -1.7673 0.83300E+00 -0.0794 14 Mn++ 0.20050E-10 -10.6979 0.10208E-10 -10.9910 0.50916E+00 -0.2931 15 F- 0.11202E-05 -5.9507 0.93132E-06 -6.0309 0.83139E+00 -0.0802 16 HPO4-- 0.43081E-07 -7.3657 0.22166E-07 -7.6543 0.51451E+00 -0.2886 18 HSiO3- 0.10202E-01 -1.9913 0.85003E-02 -2.0706 0.83316E+00 -0.0793 19 Ca(HSiO3)+ 0.17135E-07 -7.7661 0.14305E-07 -7.8445 0.83480E+00 -0.0784 20 Mg(HSiO3)+ 0.33209E-11 -11.4787 0.27723E-11 -11.5572 0.83480E+00 -0.0784 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.68309E-16 -16.1655 0.57024E-16 -16.2439 0.83480E+00 -0.0784 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51715E-05 -5.2864 0.43007E-05 -5.3665 0.83161E+00 -0.0801 26 CH4,aq 0.20129E-02 -2.6962 0.20067E-02 -2.6975 0.99688E+00 -0.0014 27 C2H6,aq 0.59621E-10 -10.2246 0.59435E-10 -10.2260 0.99688E+00 -0.0014 28 C3H8,aq 0.40770E-16 -16.3897 0.40642E-16 -16.3910 0.99688E+00 -0.0014 30 ethanol,aq 0.21883E-17 -17.6599 0.21815E-17 -17.6612 0.99688E+00 -0.0014 31 CO,aq 0.15046E-14 -14.8226 0.15046E-14 -14.8226 0.10000E+01 0.0000 32 CO2,aq 0.51874E-08 -8.2851 0.51712E-08 -8.2864 0.99688E+00 -0.0014 33 CO3-2 0.70453E-04 -4.1521 0.36165E-04 -4.4417 0.51331E+00 -0.2896 34 CaCO3,aq 0.33508E-07 -7.4749 0.33508E-07 -7.4749 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.71521E-10 -10.1456 0.59706E-10 -10.2240 0.83480E+00 -0.0784 36 CaCl+ 0.53288E-10 -10.2734 0.44485E-10 -10.3518 0.83480E+00 -0.0784 37 CaCl2,aq 0.39316E-14 -14.4054 0.39316E-14 -14.4054 0.10000E+01 0.0000 38 CaF+ 0.12036E-11 -11.9195 0.10048E-11 -11.9979 0.83480E+00 -0.0784 39 CaOH+ 0.82513E-07 -7.0835 0.68882E-07 -7.1619 0.83480E+00 -0.0784 40 CaSO4,aq 0.22630E-15 -15.6453 0.22630E-15 -15.6453 0.10000E+01 0.0000 41 HCl,aq 0.52116E-14 -14.2830 0.52116E-14 -14.2830 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18395E-18 -18.7353 0.15326E-18 -18.8146 0.83316E+00 -0.0793 48 FeCl+ 0.22396E-16 -16.6498 0.18696E-16 -16.7283 0.83480E+00 -0.0784 51 FeF+ 0.18102E-17 -17.7423 0.15111E-17 -17.8207 0.83480E+00 -0.0784 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16194E-10 -10.7907 0.13518E-10 -10.8691 0.83480E+00 -0.0784 55 HFeO2- 0.34679E-07 -7.4599 0.28893E-07 -7.5392 0.83316E+00 -0.0793 56 FeO+ 0.11349E-16 -16.9450 0.94745E-17 -17.0234 0.83480E+00 -0.0784 58 FeO2- 0.39809E-09 -9.4000 0.33168E-09 -9.4793 0.83316E+00 -0.0793 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11618E-04 -4.9349 0.11582E-04 -4.9362 0.99688E+00 -0.0014 61 KCl,aq 0.90968E-09 -9.0411 0.90968E-09 -9.0411 0.10000E+01 0.0000 63 KOH,aq 0.75364E-06 -6.1228 0.75364E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.24236E-13 -13.6155 0.20192E-13 -13.6948 0.83316E+00 -0.0793 65 MgCO3,aq 0.13080E-11 -11.8834 0.13080E-11 -11.8834 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11381E-13 -13.9438 0.95007E-14 -14.0222 0.83480E+00 -0.0784 67 MgCl+ 0.75212E-14 -14.1237 0.62787E-14 -14.2021 0.83480E+00 -0.0784 68 MgF+ 0.69430E-15 -15.1585 0.57960E-15 -15.2369 0.83480E+00 -0.0784 69 MgOH+ 0.71103E-10 -10.1481 0.59357E-10 -10.2265 0.83480E+00 -0.0784 71 MnF+ 0.19183E-15 -15.7171 0.16014E-15 -15.7955 0.83480E+00 -0.0784 72 MnO,aq 0.18087E-08 -8.7426 0.18087E-08 -8.7426 0.10000E+01 0.0000 73 MnOH+ 0.48366E-09 -9.3155 0.40376E-09 -9.3939 0.83480E+00 -0.0784 74 MnO2-2 0.20006E-10 -10.6988 0.10269E-10 -10.9885 0.51331E+00 -0.2896 75 HMnO2- 0.20645E-09 -9.6852 0.17200E-09 -9.7645 0.83316E+00 -0.0793 78 MnCl+ 0.28013E-13 -13.5526 0.23385E-13 -13.6311 0.83480E+00 -0.0784 79 MnSO4,aq 0.28423E-19 -19.5463 0.28423E-19 -19.5463 0.10000E+01 0.0000 80 NaCl,aq 0.21067E-05 -5.6764 0.21067E-05 -5.6764 0.10000E+01 0.0000 81 NaF,aq 0.37260E-08 -8.4288 0.37260E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96033E-04 -4.0176 0.96033E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90872E-02 -2.0416 0.75571E-02 -2.1216 0.83161E+00 -0.0801 89 HPO3-2 0.15586E-14 -14.8073 0.80007E-15 -15.0969 0.51331E+00 -0.2896 91 H2PO3- 0.14722E-18 -18.8320 0.12266E-18 -18.9113 0.83316E+00 -0.0793 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37484E-10 -10.4261 0.31261E-10 -10.5050 0.83397E+00 -0.0788 94 PO4-3 0.99470E-09 -9.0023 0.23655E-09 -9.6261 0.23781E+00 -0.6238 98 HP2O7-3 0.88422E-18 -18.0534 0.20014E-18 -18.6987 0.22634E+00 -0.6452 99 P2O7-4 0.84199E-17 -17.0747 0.62539E-18 -18.2038 0.74275E-01 -1.1292 100 H2S,aq 0.14919E-06 -6.8263 0.14872E-06 -6.8276 0.99688E+00 -0.0014 101 S2-2 0.14766E-11 -11.8308 0.75794E-12 -12.1204 0.51331E+00 -0.2896 102 S3-2 0.25544E-19 -19.5927 0.13112E-19 -19.8823 0.51331E+00 -0.2896 107 SO3-2 0.27865E-16 -16.5549 0.14516E-16 -16.8381 0.52095E+00 -0.2832 108 HSO3- 0.83401E-19 -19.0788 0.69487E-19 -19.1581 0.83316E+00 -0.0793 109 HSO4- 0.85034E-18 -18.0704 0.71058E-18 -18.1484 0.83564E+00 -0.0780 111 S2O3-2 0.32825E-19 -19.4838 0.16850E-19 -19.7734 0.51331E+00 -0.2896 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9119414E-10 -.2182998E-01 -.2196371E+02 0.0000 2 H2O 0.1000000E+01 0.5550692E+02 0.9981742E+06 0.0000 3 Cl- 0.4464953E-03 0.4486030E-03 0.1587570E+02 6.6872 4 SO4-- 0.1874741E-10 -.2015846E-02 -.1932969E+03 9.2175 5 HCO3- 0.3793564E-04 0.2121369E-02 0.1292071E+03 5.6170 6 HS- 0.7553547E-03 0.2771350E-02 0.9148916E+02 6.9156 7 Al+++ 0.1083570E-28 0.5171634E-05 0.1392873E+00 0.7390 8 H4SiO4 0.6959513E-03 0.1324779E-01 0.1271025E+04 -3.1574 9 Ca++ 0.1447330E-06 0.2780157E-06 0.1112226E-01 13.1018 10 Mg++ 0.2264532E-10 0.9839761E-10 0.2387938E-05 9.2942 11 Fe++ 0.6241451E-13 0.3530773E-07 0.1968282E-02 6.7350 12 K+ 0.1616584E-03 0.1624129E-03 0.6339242E+01 6.2467 13 Na+ 0.2051474E-01 0.2296226E-01 0.5269478E+03 8.3493 14 Mn++ 0.2004983E-10 0.2538869E-08 0.1392294E-03 9.2422 15 F- 0.1120187E-05 0.1123915E-05 0.2131371E-01 4.0857 16 HPO4-- 0.4308097E-07 0.4411316E-07 0.4226317E-02 12.5789 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279100E+02 -.1084072E-01 -.8278016E+02 0.0000000E+00 2 H2O -.7157008E+01 0.2756460E+02 -.3472161E+02 0.0000000E+00 3 Cl- 0.2227752E-03 0.2227752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386612E+00 -.1001065E-02 0.1396623E+00 0.0000000E+00 5 HCO3- 0.1053467E-02 0.1053467E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382861E+00 0.1376246E-02 -.1396623E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2568221E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6578821E-02 0.5205733E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1380620E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4886402E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1753374E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8065389E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1140301E-01 0.6264974E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1260797E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5856000E-05 0.5581334E-06 0.5297867E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2190649E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.4920E-14 Mass of aqueous solution: 0.497493E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0143900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.796 1641. 3.215 30.04 630.0 andradite 0.5586 -0.253 283.9 2.453 5.197 73.76 grossular 0.1353 -0.869 60.94 1.785 1.116 16.95 apatite-OH 0.9857E-02 -2.006 4.952 0.695 0.9065E-01 1.573 apatite-F 0.5298E-05 -5.276 0.2672E-02 -2.573 0.4891E-04 0.8347E-03 clinochlore 0.7093 -0.149 394.3 2.596 7.218 150.0 daphnite 0.2053 -0.688 146.5 2.166 2.682 44.40 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2352 -0.629 50.93 1.707 0.9323 15.56 hedenbergite 0.6099E-01 -1.215 15.13 1.180 0.2770 4.144 microcline 0.9319 -0.031 259.4 2.414 4.749 101.3 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2591 -0.586 279.3 2.446 5.114 96.49 tr.625ac.25prg.125 0.5146E-01 -1.289 43.99 1.643 0.8053 14.16 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.342336 g Volume = 2210.817559 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0143900 moles log = -1.8419 Original solution: 1000.0103000 g Original solution / Rock added: 69493.42 (Water/Rock Ratio), log = 4.8419 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.0001 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2585E+00 0.9729 0.1006E+01 0.1034E+01 CO2,gas 0.1394E-06 0.9924 0.5533E-06 0.5575E-06 CH4,gas 0.7377E+00 1.0009 0.2954E+01 0.2951E+01 H2,gas 0.3793E-02 1.0021 0.1521E-01 0.1517E-01 H2S,gas 0.1038E-05 0.9846 0.4088E-05 0.4152E-05 S2,gas 0.6783E-27 1.0000 0.2713E-26 0.2713E-26 CO,gas 0.5605E-12 1.0000 0.2242E-11 0.2242E-11 SO3,gas 0.5329E-47 1.0000 0.2131E-46 0.2131E-46 SO2,gas 0.3152E-26 1.0000 0.1261E-25 0.1261E-25 HF,gas 0.2992E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2299E-17 1.0000 0.9196E-17 0.9196E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.62 -7.96 -2.652 0.13585E+05 -6.257 3 CH4,gas 4.54 3.32 -1.23 -0.307 0.20978E+04 0.470 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.32 -7.09 -3.544 0.12102E+05 -5.388 6 S2,gas -7.34 -35.60 -28.27 -4.349 0.48263E+05 -26.566 7 CO,gas 3.21 -10.13 -13.35 -4.107 0.22792E+05 -11.649 8 SO3,gas 17.12 -31.25 -48.37 -12.093 0.82591E+05 -46.671 9 SO2,gas 0.83 -26.77 -27.60 -7.360 0.47123E+05 -25.899 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.55 -18.74 -9.368 0.31990E+05 -17.036 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80679E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93630E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.51 -2.48 -0.827 0.42360E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.51 -2.33 -0.775 0.39718E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65539E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.65 -2.55 -0.728 0.43509E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.65 -2.10 -0.601 0.35931E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82231E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.38 -3.14 -0.738 0.53550E+04 146 pyrrhotite -4.26 -6.58 -2.32 -0.774 0.39654E+04 147 pyrrhotiteFe0.875 -6.02 -7.98 -1.96 -0.722 0.33526E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22434E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.37 -4.40 -1.466 0.75089E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23237E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47107E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90676E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.58 -2.17 -0.724 0.37082E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60608E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.08 -3.10 -1.033 0.52891E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0143900 MOLES New total amount of reactant added: 0.0147900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8650E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0147900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4966E+00 Moles total = -.7157E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .1019243E-01 Osmotic coef. = 0.9178 True ionic strength = .2076546E-01 Chg. balance for total moles = -.8650E-10 Max. difference allowed = 0.2251E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91265E-10 -10.0397 0.76507E-10 -10.1163 0.83830E+00 -0.0766 2 H2O 0.99996E+00 0.0000 0.99996E+00 0.0000 3 Cl- 0.45122E-03 -3.3456 0.37591E-03 -3.4249 0.83311E+00 -0.0793 4 SO4-- 0.19222E-10 -10.7162 0.98863E-11 -11.0050 0.51432E+00 -0.2888 5 HCO3- 0.38953E-04 -4.4095 0.32501E-04 -4.4881 0.83436E+00 -0.0786 6 HS- 0.77491E-03 -3.1107 0.64568E-03 -3.1900 0.83324E+00 -0.0792 7 Al+++ 0.10865E-28 -28.9640 0.24554E-29 -29.6099 0.22599E+00 -0.6459 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14498E-06 -6.8387 0.74001E-07 -7.1308 0.51043E+00 -0.2921 10 Mg++ 0.22684E-10 -10.6443 0.11524E-10 -10.9384 0.50803E+00 -0.2941 11 Fe++ 0.62520E-13 -13.2040 0.31798E-13 -13.4976 0.50860E+00 -0.2936 12 K+ 0.16178E-03 -3.7911 0.13502E-03 -3.8696 0.83457E+00 -0.0785 13 Na+ 0.20531E-01 -1.6876 0.17101E-01 -1.7670 0.83295E+00 -0.0794 14 Mn++ 0.20084E-10 -10.6971 0.10224E-10 -10.9904 0.50904E+00 -0.2933 15 F- 0.11194E-05 -5.9510 0.93064E-06 -6.0312 0.83134E+00 -0.0802 16 HPO4-- 0.43028E-07 -7.3662 0.22134E-07 -7.6549 0.51439E+00 -0.2887 18 HSiO3- 0.10196E-01 -1.9916 0.84941E-02 -2.0709 0.83311E+00 -0.0793 19 Ca(HSiO3)+ 0.17149E-07 -7.7658 0.14315E-07 -7.8442 0.83475E+00 -0.0784 20 Mg(HSiO3)+ 0.33235E-11 -11.4784 0.27743E-11 -11.5568 0.83475E+00 -0.0784 21 NaHSiO3,aq 0.23494E-02 -2.6290 0.23494E-02 -2.6290 0.10000E+01 0.0000 22 AlO+ 0.68362E-16 -16.1652 0.57065E-16 -16.2436 0.83475E+00 -0.0784 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51681E-05 -5.2867 0.42976E-05 -5.3668 0.83156E+00 -0.0801 26 CH4,aq 0.20683E-02 -2.6844 0.20618E-02 -2.6857 0.99689E+00 -0.0014 27 C2H6,aq 0.62945E-10 -10.2010 0.62749E-10 -10.2024 0.99689E+00 -0.0014 28 C3H8,aq 0.44226E-16 -16.3543 0.44089E-16 -16.3557 0.99689E+00 -0.0014 30 ethanol,aq 0.23103E-17 -17.6363 0.23031E-17 -17.6377 0.99689E+00 -0.0014 31 CO,aq 0.15460E-14 -14.8108 0.15460E-14 -14.8108 0.10000E+01 0.0000 32 CO2,aq 0.53300E-08 -8.2733 0.53134E-08 -8.2746 0.99689E+00 -0.0014 33 CO3-2 0.72302E-04 -4.1408 0.37105E-04 -4.4306 0.51320E+00 -0.2897 34 CaCO3,aq 0.34430E-07 -7.4631 0.34430E-07 -7.4631 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.73546E-10 -10.1334 0.61393E-10 -10.2119 0.83475E+00 -0.0784 36 CaCl+ 0.53930E-10 -10.2682 0.45018E-10 -10.3466 0.83475E+00 -0.0784 37 CaCl2,aq 0.40205E-14 -14.3957 0.40205E-14 -14.3957 0.10000E+01 0.0000 38 CaF+ 0.12045E-11 -11.9192 0.10055E-11 -11.9976 0.83475E+00 -0.0784 39 CaOH+ 0.82578E-07 -7.0831 0.68932E-07 -7.1616 0.83475E+00 -0.0784 40 CaSO4,aq 0.23232E-15 -15.6339 0.23232E-15 -15.6339 0.10000E+01 0.0000 41 HCl,aq 0.52702E-14 -14.2782 0.52702E-14 -14.2782 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18383E-18 -18.7356 0.15315E-18 -18.8149 0.83311E+00 -0.0793 48 FeCl+ 0.22665E-16 -16.6446 0.18920E-16 -16.7231 0.83475E+00 -0.0784 51 FeF+ 0.18116E-17 -17.7419 0.15122E-17 -17.8204 0.83475E+00 -0.0784 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16206E-10 -10.7903 0.13528E-10 -10.8688 0.83475E+00 -0.0784 55 HFeO2- 0.34656E-07 -7.4602 0.28872E-07 -7.5395 0.83311E+00 -0.0793 56 FeO+ 0.11358E-16 -16.9447 0.94814E-17 -17.0231 0.83475E+00 -0.0784 58 FeO2- 0.39783E-09 -9.4003 0.33144E-09 -9.4796 0.83311E+00 -0.0793 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11618E-04 -4.9349 0.11582E-04 -4.9362 0.99689E+00 -0.0014 61 KCl,aq 0.91991E-09 -9.0363 0.91991E-09 -9.0363 0.10000E+01 0.0000 63 KOH,aq 0.75364E-06 -6.1228 0.75364E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.24863E-13 -13.6044 0.20714E-13 -13.6837 0.83311E+00 -0.0793 65 MgCO3,aq 0.13439E-11 -11.8716 0.13439E-11 -11.8716 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11703E-13 -13.9317 0.97690E-14 -14.0101 0.83475E+00 -0.0784 67 MgCl+ 0.76118E-14 -14.1185 0.63539E-14 -14.1970 0.83475E+00 -0.0784 68 MgF+ 0.69485E-15 -15.1581 0.58002E-15 -15.2366 0.83475E+00 -0.0784 69 MgOH+ 0.71158E-10 -10.1478 0.59400E-10 -10.2262 0.83475E+00 -0.0784 71 MnF+ 0.19199E-15 -15.7167 0.16026E-15 -15.7952 0.83475E+00 -0.0784 72 MnO,aq 0.18087E-08 -8.7426 0.18087E-08 -8.7426 0.10000E+01 0.0000 73 MnOH+ 0.48406E-09 -9.3151 0.40407E-09 -9.3935 0.83475E+00 -0.0784 74 MnO2-2 0.19982E-10 -10.6994 0.10255E-10 -10.9891 0.51320E+00 -0.2897 75 HMnO2- 0.20632E-09 -9.6855 0.17189E-09 -9.7648 0.83311E+00 -0.0793 78 MnCl+ 0.28351E-13 -13.5474 0.23666E-13 -13.6259 0.83475E+00 -0.0784 79 MnSO4,aq 0.29180E-19 -19.5349 0.29180E-19 -19.5349 0.10000E+01 0.0000 80 NaCl,aq 0.21304E-05 -5.6715 0.21304E-05 -5.6715 0.10000E+01 0.0000 81 NaF,aq 0.37260E-08 -8.4288 0.37260E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96033E-04 -4.0176 0.96033E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90812E-02 -2.0419 0.75516E-02 -2.1220 0.83156E+00 -0.0801 89 HPO3-2 0.15567E-14 -14.8078 0.79891E-15 -15.0975 0.51320E+00 -0.2897 91 H2PO3- 0.14712E-18 -18.8323 0.12257E-18 -18.9116 0.83311E+00 -0.0793 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37460E-10 -10.4264 0.31238E-10 -10.5053 0.83392E+00 -0.0789 94 PO4-3 0.99303E-09 -9.0030 0.23604E-09 -9.6270 0.23770E+00 -0.6240 98 HP2O7-3 0.88277E-18 -18.0542 0.19970E-18 -18.6996 0.22623E+00 -0.6455 99 P2O7-4 0.84032E-17 -17.0756 0.62358E-18 -18.2051 0.74208E-01 -1.1296 100 H2S,aq 0.15315E-06 -6.8149 0.15268E-06 -6.8162 0.99689E+00 -0.0014 101 S2-2 0.15542E-11 -11.8085 0.79760E-12 -12.0982 0.51320E+00 -0.2897 102 S3-2 0.27602E-19 -19.5591 0.14165E-19 -19.8488 0.51320E+00 -0.2897 107 SO3-2 0.28570E-16 -16.5441 0.14880E-16 -16.8274 0.52083E+00 -0.2833 108 HSO3- 0.85561E-19 -19.0677 0.71282E-19 -19.1470 0.83311E+00 -0.0793 109 HSO4- 0.87236E-18 -18.0593 0.72893E-18 -18.1373 0.83559E+00 -0.0780 111 S2O3-2 0.34551E-19 -19.4615 0.17731E-19 -19.7513 0.51320E+00 -0.2897 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9126533E-10 -.2181898E-01 -.2195261E+02 0.0000 2 H2O 0.1000000E+01 0.5550697E+02 0.9981736E+06 0.0000 3 Cl- 0.4512172E-03 0.4533486E-03 0.1604362E+02 6.6914 4 SO4-- 0.1922217E-10 -.2071183E-02 -.1986028E+03 9.2276 5 HCO3- 0.3895300E-04 0.2179574E-02 0.1327519E+03 5.6282 6 HS- 0.7749125E-03 0.2846248E-02 0.9396158E+02 6.9263 7 Al+++ 0.1086502E-28 0.5168205E-05 0.1391947E+00 0.7390 8 H4SiO4 0.6959505E-03 0.1324100E-01 0.1270371E+04 -3.1574 9 Ca++ 0.1449771E-06 0.2792620E-06 0.1117210E-01 13.1018 10 Mg++ 0.2268358E-10 0.9853031E-10 0.2391154E-05 9.2942 11 Fe++ 0.6251997E-13 0.3528439E-07 0.1966978E-02 6.7350 12 K+ 0.1617846E-03 0.1625392E-03 0.6344158E+01 6.2467 13 Na+ 0.2053079E-01 0.2297832E-01 0.5273155E+03 8.3493 14 Mn++ 0.2008447E-10 0.2539218E-08 0.1392483E-03 9.2422 15 F- 0.1119443E-05 0.1123170E-05 0.2129956E-01 4.0851 16 HPO4-- 0.4302848E-07 0.4405896E-07 0.4221118E-02 12.5776 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279095E+02 -.1083542E-01 -.8278012E+02 0.0000000E+00 2 H2O -.7156680E+01 0.2756504E+02 -.3472172E+02 0.0000000E+00 3 Cl- 0.2251352E-03 0.2251352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386631E+00 -.1028560E-02 0.1396917E+00 0.0000000E+00 5 HCO3- 0.1082387E-02 0.1082387E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382782E+00 0.1413461E-02 -.1396917E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2566556E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6575545E-02 0.5205733E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1386829E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4893064E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1752240E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8071775E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1141115E-01 0.6264966E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1260988E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6016000E-05 0.5577720E-06 0.5458228E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2187990E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1531E-13 Mass of aqueous solution: 0.497501E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0147900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.259 0.796 1641. 3.215 30.04 630.0 andradite 0.5588 -0.253 284.0 2.453 5.198 73.77 grossular 0.1353 -0.869 60.95 1.785 1.116 16.96 apatite-OH 0.9857E-02 -2.006 4.951 0.695 0.9065E-01 1.573 apatite-F 0.5458E-05 -5.263 0.2753E-02 -2.560 0.5039E-04 0.8599E-03 clinochlore 0.7093 -0.149 394.2 2.596 7.217 150.0 daphnite 0.2053 -0.688 146.5 2.166 2.682 44.40 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2344 -0.630 50.76 1.706 0.9293 15.51 hedenbergite 0.6079E-01 -1.216 15.08 1.178 0.2761 4.131 microcline 0.9320 -0.031 259.4 2.414 4.749 101.3 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2591 -0.587 279.3 2.446 5.113 96.47 tr.625ac.25prg.125 0.5171E-01 -1.286 44.20 1.645 0.8092 14.23 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.342456 g Volume = 2210.818663 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0147900 moles log = -1.8300 Original solution: 1000.0103000 g Original solution / Rock added: 67613.95 (Water/Rock Ratio), log = 4.8300 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.0818 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2534E+00 0.9727 0.1006E+01 0.1034E+01 CO2,gas 0.1404E-06 0.9922 0.5685E-06 0.5729E-06 CH4,gas 0.7429E+00 1.0008 0.3035E+01 0.3032E+01 H2,gas 0.3717E-02 1.0022 0.1521E-01 0.1517E-01 H2S,gas 0.1045E-05 0.9843 0.4197E-05 0.4264E-05 S2,gas 0.7006E-27 1.0000 0.2860E-26 0.2860E-26 CO,gas 0.5644E-12 1.0000 0.2304E-11 0.2304E-11 SO3,gas 0.5361E-47 1.0000 0.2188E-46 0.2188E-46 SO2,gas 0.3171E-26 1.0000 0.1295E-25 0.1295E-25 HF,gas 0.2932E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2278E-17 1.0000 0.9299E-17 0.9299E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.60 -7.94 -2.648 0.13565E+05 -6.245 3 CH4,gas 4.54 3.33 -1.22 -0.304 0.20777E+04 0.482 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.31 -7.08 -3.538 0.12082E+05 -5.377 6 S2,gas -7.34 -35.58 -28.24 -4.345 0.48224E+05 -26.544 7 CO,gas 3.21 -10.12 -13.34 -4.104 0.22772E+05 -11.638 8 SO3,gas 17.12 -31.24 -48.36 -12.090 0.82572E+05 -46.660 9 SO2,gas 0.83 -26.75 -27.59 -7.356 0.47104E+05 -25.888 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.54 -18.73 -9.365 0.31982E+05 -17.032 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80678E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93630E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.50 -2.47 -0.823 0.42159E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.50 -2.31 -0.771 0.39517E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65538E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.64 -2.54 -0.725 0.43308E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.64 -2.09 -0.598 0.35730E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82231E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.36 -3.11 -0.733 0.53161E+04 146 pyrrhotite -4.26 -6.57 -2.31 -0.770 0.39459E+04 147 pyrrhotiteFe0.875 -6.02 -7.97 -1.95 -0.718 0.33331E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22434E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.36 -4.39 -1.462 0.74888E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23237E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47106E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.57 -2.16 -0.720 0.36887E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 234 alabandite -0.98 -4.06 -3.09 -1.029 0.52696E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0147900 MOLES New total amount of reactant added: 0.0151900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8650E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0151900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4966E+00 Moles total = -.7156E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .1015874E-01 Osmotic coef. = 0.9180 True ionic strength = .2078348E-01 Chg. balance for total moles = -.8650E-10 Max. difference allowed = 0.2275E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91337E-10 -10.0394 0.76563E-10 -10.1160 0.83825E+00 -0.0766 2 H2O 0.99996E+00 0.0000 0.99996E+00 0.0000 3 Cl- 0.45594E-03 -3.3411 0.37982E-03 -3.4204 0.83306E+00 -0.0793 4 SO4-- 0.19696E-10 -10.7056 0.10128E-10 -10.9945 0.51420E+00 -0.2889 5 HCO3- 0.39969E-04 -4.3983 0.33347E-04 -4.4769 0.83431E+00 -0.0787 6 HS- 0.79447E-03 -3.0999 0.66194E-03 -3.1792 0.83319E+00 -0.0793 7 Al+++ 0.10894E-28 -28.9628 0.24607E-29 -29.6089 0.22587E+00 -0.6461 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14522E-06 -6.8380 0.74108E-07 -7.1301 0.51031E+00 -0.2922 10 Mg++ 0.22722E-10 -10.6436 0.11541E-10 -10.9378 0.50791E+00 -0.2942 11 Fe++ 0.62626E-13 -13.2032 0.31844E-13 -13.4970 0.50848E+00 -0.2937 12 K+ 0.16191E-03 -3.7907 0.13512E-03 -3.8693 0.83452E+00 -0.0786 13 Na+ 0.20547E-01 -1.6873 0.17114E-01 -1.7667 0.83290E+00 -0.0794 14 Mn++ 0.20119E-10 -10.6964 0.10239E-10 -10.9897 0.50891E+00 -0.2934 15 F- 0.11187E-05 -5.9513 0.92997E-06 -6.0315 0.83129E+00 -0.0802 16 HPO4-- 0.42976E-07 -7.3668 0.22102E-07 -7.6556 0.51428E+00 -0.2888 18 HSiO3- 0.10189E-01 -1.9919 0.84880E-02 -2.0712 0.83306E+00 -0.0793 19 Ca(HSiO3)+ 0.17162E-07 -7.7654 0.14325E-07 -7.8439 0.83470E+00 -0.0785 20 Mg(HSiO3)+ 0.33261E-11 -11.4781 0.27763E-11 -11.5565 0.83470E+00 -0.0785 21 NaHSiO3,aq 0.23494E-02 -2.6291 0.23494E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.68416E-16 -16.1648 0.57107E-16 -16.2433 0.83470E+00 -0.0785 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51646E-05 -5.2870 0.42945E-05 -5.3671 0.83151E+00 -0.0801 26 CH4,aq 0.21236E-02 -2.6729 0.21170E-02 -2.6743 0.99690E+00 -0.0014 27 C2H6,aq 0.66359E-10 -10.1781 0.66153E-10 -10.1795 0.99690E+00 -0.0014 28 C3H8,aq 0.47873E-16 -16.3199 0.47725E-16 -16.3213 0.99690E+00 -0.0014 30 ethanol,aq 0.24356E-17 -17.6134 0.24281E-17 -17.6147 0.99690E+00 -0.0014 31 CO,aq 0.15874E-14 -14.7993 0.15874E-14 -14.7993 0.10000E+01 0.0000 32 CO2,aq 0.54726E-08 -8.2618 0.54556E-08 -8.2632 0.99690E+00 -0.0014 33 CO3-2 0.74148E-04 -4.1299 0.38043E-04 -4.4197 0.51308E+00 -0.2898 34 CaCO3,aq 0.35351E-07 -7.4516 0.35351E-07 -7.4516 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.75574E-10 -10.1216 0.63082E-10 -10.2001 0.83470E+00 -0.0785 36 CaCl+ 0.54573E-10 -10.2630 0.45552E-10 -10.3415 0.83470E+00 -0.0785 37 CaCl2,aq 0.41106E-14 -14.3861 0.41106E-14 -14.3861 0.10000E+01 0.0000 38 CaF+ 0.12055E-11 -11.9188 0.10062E-11 -11.9973 0.83470E+00 -0.0785 39 CaOH+ 0.82642E-07 -7.0828 0.68982E-07 -7.1613 0.83470E+00 -0.0785 40 CaSO4,aq 0.23834E-15 -15.6228 0.23834E-15 -15.6228 0.10000E+01 0.0000 41 HCl,aq 0.53289E-14 -14.2734 0.53289E-14 -14.2734 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18371E-18 -18.7359 0.15304E-18 -18.8152 0.83306E+00 -0.0793 48 FeCl+ 0.22936E-16 -16.6395 0.19144E-16 -16.7180 0.83470E+00 -0.0785 51 FeF+ 0.18130E-17 -17.7416 0.15133E-17 -17.8201 0.83470E+00 -0.0785 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16219E-10 -10.7900 0.13538E-10 -10.8684 0.83470E+00 -0.0785 55 HFeO2- 0.34633E-07 -7.4605 0.28851E-07 -7.5398 0.83306E+00 -0.0793 56 FeO+ 0.11367E-16 -16.9443 0.94883E-17 -17.0228 0.83470E+00 -0.0785 58 FeO2- 0.39757E-09 -9.4006 0.33120E-09 -9.4799 0.83306E+00 -0.0793 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11618E-04 -4.9349 0.11582E-04 -4.9362 0.99690E+00 -0.0014 61 KCl,aq 0.93015E-09 -9.0314 0.93015E-09 -9.0314 0.10000E+01 0.0000 63 KOH,aq 0.75364E-06 -6.1228 0.75364E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.25491E-13 -13.5936 0.21235E-13 -13.6729 0.83306E+00 -0.0793 65 MgCO3,aq 0.13799E-11 -11.8602 0.13799E-11 -11.8602 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12026E-13 -13.9199 0.10038E-13 -13.9984 0.83470E+00 -0.0785 67 MgCl+ 0.77026E-14 -14.1134 0.64294E-14 -14.1918 0.83470E+00 -0.0785 68 MgF+ 0.69539E-15 -15.1578 0.58044E-15 -15.2362 0.83470E+00 -0.0785 69 MgOH+ 0.71214E-10 -10.1474 0.59443E-10 -10.2259 0.83470E+00 -0.0785 71 MnF+ 0.19214E-15 -15.7164 0.16038E-15 -15.7948 0.83470E+00 -0.0785 72 MnO,aq 0.18088E-08 -8.7426 0.18088E-08 -8.7426 0.10000E+01 0.0000 73 MnOH+ 0.48445E-09 -9.3147 0.40438E-09 -9.3932 0.83470E+00 -0.0785 74 MnO2-2 0.19959E-10 -10.6999 0.10240E-10 -10.9897 0.51308E+00 -0.2898 75 HMnO2- 0.20619E-09 -9.6857 0.17177E-09 -9.7651 0.83306E+00 -0.0793 78 MnCl+ 0.28691E-13 -13.5423 0.23948E-13 -13.6207 0.83470E+00 -0.0785 79 MnSO4,aq 0.29937E-19 -19.5238 0.29937E-19 -19.5238 0.10000E+01 0.0000 80 NaCl,aq 0.21542E-05 -5.6667 0.21542E-05 -5.6667 0.10000E+01 0.0000 81 NaF,aq 0.37260E-08 -8.4288 0.37260E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96032E-04 -4.0176 0.96032E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90752E-02 -2.0421 0.75461E-02 -2.1223 0.83151E+00 -0.0801 89 HPO3-2 0.15549E-14 -14.8083 0.79776E-15 -15.0981 0.51308E+00 -0.2898 91 H2PO3- 0.14703E-18 -18.8326 0.12248E-18 -18.9119 0.83306E+00 -0.0793 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37435E-10 -10.4267 0.31216E-10 -10.5056 0.83387E+00 -0.0789 94 PO4-3 0.99136E-09 -9.0038 0.23553E-09 -9.6280 0.23758E+00 -0.6242 98 HP2O7-3 0.88131E-18 -18.0549 0.19927E-18 -18.7006 0.22611E+00 -0.6457 99 P2O7-4 0.83866E-17 -17.0764 0.62178E-18 -18.2064 0.74140E-01 -1.1299 100 H2S,aq 0.15712E-06 -6.8038 0.15663E-06 -6.8051 0.99690E+00 -0.0014 101 S2-2 0.16338E-11 -11.7868 0.83827E-12 -12.0766 0.51308E+00 -0.2898 102 S3-2 0.29768E-19 -19.5263 0.15273E-19 -19.8161 0.51308E+00 -0.2898 107 SO3-2 0.29275E-16 -16.5335 0.15244E-16 -16.8169 0.52072E+00 -0.2834 108 HSO3- 0.87720E-19 -19.0569 0.73076E-19 -19.1362 0.83306E+00 -0.0793 109 HSO4- 0.89437E-18 -18.0485 0.74729E-18 -18.1265 0.83554E+00 -0.0780 111 S2O3-2 0.36321E-19 -19.4398 0.18635E-19 -19.7297 0.51308E+00 -0.2898 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9133654E-10 -.2180800E-01 -.2194152E+02 0.0000 2 H2O 0.1000000E+01 0.5550703E+02 0.9981730E+06 0.0000 3 Cl- 0.4559390E-03 0.4580942E-03 0.1621153E+02 6.6956 4 SO4-- 0.1969639E-10 -.2126523E-02 -.2039089E+03 9.2375 5 HCO3- 0.3996909E-04 0.2237776E-02 0.1362967E+03 5.6390 6 HS- 0.7944698E-03 0.2921150E-02 0.9643410E+02 6.9368 7 Al+++ 0.1089441E-28 0.5164780E-05 0.1391023E+00 0.7390 8 H4SiO4 0.6959497E-03 0.1323421E-01 0.1269719E+04 -3.1574 9 Ca++ 0.1452214E-06 0.2805087E-06 0.1122196E-01 13.1018 10 Mg++ 0.2272189E-10 0.9866299E-10 0.2394370E-05 9.2942 11 Fe++ 0.6262555E-13 0.3526107E-07 0.1965675E-02 6.7350 12 K+ 0.1619108E-03 0.1626654E-03 0.6349075E+01 6.2467 13 Na+ 0.2054683E-01 0.2299438E-01 0.5276833E+03 8.3493 14 Mn++ 0.2011915E-10 0.2539568E-08 0.1392672E-03 9.2422 15 F- 0.1118699E-05 0.1122427E-05 0.2128543E-01 4.0844 16 HPO4-- 0.4297607E-07 0.4400486E-07 0.4215928E-02 12.5764 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279091E+02 -.1083012E-01 -.8278008E+02 0.0000000E+00 2 H2O -.7156353E+01 0.2756547E+02 -.3472182E+02 0.0000000E+00 3 Cl- 0.2274952E-03 0.2274952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386651E+00 -.1056057E-02 0.1397211E+00 0.0000000E+00 5 HCO3- 0.1111307E-02 0.1111307E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382704E+00 0.1450679E-02 -.1397211E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2564893E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6572273E-02 0.5205733E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1393040E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4899725E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1751108E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8078163E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1141929E-01 0.6264958E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1261180E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6176000E-05 0.5574110E-06 0.5618589E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2185335E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.2103E-13 Mass of aqueous solution: 0.497509E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0151900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 630.0 andradite 0.5589 -0.253 284.0 2.453 5.199 73.79 grossular 0.1353 -0.869 60.96 1.785 1.116 16.96 apatite-OH 0.9857E-02 -2.006 4.951 0.695 0.9065E-01 1.573 apatite-F 0.5619E-05 -5.250 0.2834E-02 -2.548 0.5187E-04 0.8852E-03 clinochlore 0.7093 -0.149 394.2 2.596 7.217 150.0 daphnite 0.2053 -0.688 146.5 2.166 2.682 44.40 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2336 -0.631 50.60 1.704 0.9263 15.46 hedenbergite 0.6059E-01 -1.218 15.03 1.177 0.2752 4.117 microcline 0.9320 -0.031 259.4 2.414 4.749 101.3 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2590 -0.587 279.2 2.446 5.112 96.45 tr.625ac.25prg.125 0.5196E-01 -1.284 44.41 1.648 0.8131 14.29 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.342575 g Volume = 2210.819767 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0151900 moles log = -1.8184 Original solution: 1000.0103000 g Original solution / Rock added: 65833.46 (Water/Rock Ratio), log = 4.8184 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.1635 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2484E+00 0.9726 0.1006E+01 0.1034E+01 CO2,gas 0.1413E-06 0.9920 0.5837E-06 0.5884E-06 CH4,gas 0.7479E+00 1.0007 0.3116E+01 0.3114E+01 H2,gas 0.3644E-02 1.0022 0.1521E-01 0.1517E-01 H2S,gas 0.1051E-05 0.9840 0.4306E-05 0.4376E-05 S2,gas 0.7229E-27 1.0000 0.3010E-26 0.3010E-26 CO,gas 0.5682E-12 1.0000 0.2366E-11 0.2366E-11 SO3,gas 0.5392E-47 1.0000 0.2245E-46 0.2245E-46 SO2,gas 0.3190E-26 1.0000 0.1328E-25 0.1328E-25 HF,gas 0.2874E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2258E-17 1.0000 0.9403E-17 0.9403E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.59 -7.93 -2.644 0.13545E+05 -6.234 3 CH4,gas 4.54 3.34 -1.21 -0.301 0.20581E+04 0.494 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.30 -7.06 -3.532 0.12063E+05 -5.366 6 S2,gas -7.34 -35.56 -28.22 -4.342 0.48186E+05 -26.521 7 CO,gas 3.21 -10.11 -13.33 -4.100 0.22752E+05 -11.626 8 SO3,gas 17.12 -31.23 -48.35 -12.087 0.82553E+05 -46.649 9 SO2,gas 0.83 -26.74 -27.58 -7.354 0.47085E+05 -25.877 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.54 -18.73 -9.363 0.31974E+05 -17.027 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80677E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93630E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.49 -2.46 -0.819 0.41963E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.49 -2.30 -0.768 0.39321E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65538E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.63 -2.52 -0.721 0.43112E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.63 -2.08 -0.595 0.35534E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82230E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.34 -3.09 -0.727 0.52782E+04 146 pyrrhotite -4.26 -6.56 -2.30 -0.767 0.39269E+04 147 pyrrhotiteFe0.875 -6.02 -7.96 -1.94 -0.714 0.33141E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22434E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.35 -4.37 -1.458 0.74691E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23236E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47105E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.56 -2.15 -0.716 0.36697E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -4.05 -3.08 -1.025 0.52506E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0151900 MOLES New total amount of reactant added: 0.0155900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8648E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0155900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4966E+00 Moles total = -.7156E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .1012505E-01 Osmotic coef. = 0.9183 True ionic strength = .2080149E-01 Chg. balance for total moles = -.8648E-10 Max. difference allowed = 0.2299E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91408E-10 -10.0390 0.76618E-10 -10.1157 0.83820E+00 -0.0767 2 H2O 0.99996E+00 0.0000 0.99996E+00 0.0000 3 Cl- 0.46066E-03 -3.3366 0.38374E-03 -3.4160 0.83301E+00 -0.0793 4 SO4-- 0.20170E-10 -10.6953 0.10369E-10 -10.9843 0.51408E+00 -0.2890 5 HCO3- 0.40984E-04 -4.3874 0.34191E-04 -4.4661 0.83427E+00 -0.0787 6 HS- 0.81403E-03 -3.0894 0.67819E-03 -3.1686 0.83314E+00 -0.0793 7 Al+++ 0.10924E-28 -28.9616 0.24661E-29 -29.6080 0.22575E+00 -0.6464 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14547E-06 -6.8372 0.74216E-07 -7.1295 0.51019E+00 -0.2923 10 Mg++ 0.22760E-10 -10.6428 0.11557E-10 -10.9371 0.50779E+00 -0.2943 11 Fe++ 0.62731E-13 -13.2025 0.31890E-13 -13.4963 0.50836E+00 -0.2938 12 K+ 0.16204E-03 -3.7904 0.13521E-03 -3.8690 0.83447E+00 -0.0786 13 Na+ 0.20563E-01 -1.6869 0.17126E-01 -1.7663 0.83285E+00 -0.0794 14 Mn++ 0.20154E-10 -10.6956 0.10254E-10 -10.9891 0.50879E+00 -0.2935 15 F- 0.11180E-05 -5.9516 0.92929E-06 -6.0318 0.83124E+00 -0.0803 16 HPO4-- 0.42924E-07 -7.3673 0.22070E-07 -7.6562 0.51416E+00 -0.2889 18 HSiO3- 0.10182E-01 -1.9922 0.84818E-02 -2.0715 0.83301E+00 -0.0793 19 Ca(HSiO3)+ 0.17176E-07 -7.7651 0.14336E-07 -7.8436 0.83465E+00 -0.0785 20 Mg(HSiO3)+ 0.33287E-11 -11.4777 0.27783E-11 -11.5562 0.83465E+00 -0.0785 21 NaHSiO3,aq 0.23494E-02 -2.6291 0.23494E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.68469E-16 -16.1645 0.57148E-16 -16.2430 0.83465E+00 -0.0785 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51612E-05 -5.2872 0.42913E-05 -5.3674 0.83146E+00 -0.0802 26 CH4,aq 0.21790E-02 -2.6618 0.21722E-02 -2.6631 0.99691E+00 -0.0013 27 C2H6,aq 0.69864E-10 -10.1557 0.69647E-10 -10.1571 0.99691E+00 -0.0013 28 C3H8,aq 0.51716E-16 -16.2864 0.51556E-16 -16.2877 0.99691E+00 -0.0013 30 ethanol,aq 0.25643E-17 -17.5910 0.25563E-17 -17.5924 0.99691E+00 -0.0013 31 CO,aq 0.16288E-14 -14.7881 0.16288E-14 -14.7881 0.10000E+01 0.0000 32 CO2,aq 0.56153E-08 -8.2506 0.55979E-08 -8.2520 0.99691E+00 -0.0013 33 CO3-2 0.75988E-04 -4.1193 0.38979E-04 -4.4092 0.51296E+00 -0.2899 34 CaCO3,aq 0.36273E-07 -7.4404 0.36273E-07 -7.4404 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.77605E-10 -10.1101 0.64773E-10 -10.1886 0.83465E+00 -0.0785 36 CaCl+ 0.55218E-10 -10.2579 0.46088E-10 -10.3364 0.83465E+00 -0.0785 37 CaCl2,aq 0.42017E-14 -14.3766 0.42017E-14 -14.3766 0.10000E+01 0.0000 38 CaF+ 0.12064E-11 -11.9185 0.10069E-11 -11.9970 0.83465E+00 -0.0785 39 CaOH+ 0.82707E-07 -7.0825 0.69032E-07 -7.1610 0.83465E+00 -0.0785 40 CaSO4,aq 0.24437E-15 -15.6120 0.24437E-15 -15.6120 0.10000E+01 0.0000 41 HCl,aq 0.53876E-14 -14.2686 0.53876E-14 -14.2686 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18359E-18 -18.7362 0.15293E-18 -18.8155 0.83301E+00 -0.0793 48 FeCl+ 0.23207E-16 -16.6344 0.19370E-16 -16.7129 0.83465E+00 -0.0785 51 FeF+ 0.18144E-17 -17.7413 0.15144E-17 -17.8198 0.83465E+00 -0.0785 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16232E-10 -10.7896 0.13548E-10 -10.8681 0.83465E+00 -0.0785 55 HFeO2- 0.34610E-07 -7.4608 0.28830E-07 -7.5402 0.83301E+00 -0.0793 56 FeO+ 0.11376E-16 -16.9440 0.94952E-17 -17.0225 0.83465E+00 -0.0785 58 FeO2- 0.39730E-09 -9.4009 0.33096E-09 -9.4802 0.83301E+00 -0.0793 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11618E-04 -4.9349 0.11582E-04 -4.9362 0.99691E+00 -0.0013 61 KCl,aq 0.94041E-09 -9.0267 0.94041E-09 -9.0267 0.10000E+01 0.0000 63 KOH,aq 0.75363E-06 -6.1228 0.75363E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.26118E-13 -13.5831 0.21756E-13 -13.6624 0.83301E+00 -0.0793 65 MgCO3,aq 0.14159E-11 -11.8490 0.14159E-11 -11.8490 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12349E-13 -13.9084 0.10307E-13 -13.9869 0.83465E+00 -0.0785 67 MgCl+ 0.77936E-14 -14.1083 0.65050E-14 -14.1868 0.83465E+00 -0.0785 68 MgF+ 0.69593E-15 -15.1574 0.58086E-15 -15.2359 0.83465E+00 -0.0785 69 MgOH+ 0.71270E-10 -10.1471 0.59486E-10 -10.2256 0.83465E+00 -0.0785 71 MnF+ 0.19230E-15 -15.7160 0.16050E-15 -15.7945 0.83465E+00 -0.0785 72 MnO,aq 0.18089E-08 -8.7426 0.18089E-08 -8.7426 0.10000E+01 0.0000 73 MnOH+ 0.48485E-09 -9.3144 0.40468E-09 -9.3929 0.83465E+00 -0.0785 74 MnO2-2 0.19935E-10 -10.7004 0.10226E-10 -10.9903 0.51296E+00 -0.2899 75 HMnO2- 0.20606E-09 -9.6860 0.17165E-09 -9.7654 0.83301E+00 -0.0793 78 MnCl+ 0.29031E-13 -13.5371 0.24231E-13 -13.6156 0.83465E+00 -0.0785 79 MnSO4,aq 0.30696E-19 -19.5129 0.30696E-19 -19.5129 0.10000E+01 0.0000 80 NaCl,aq 0.21779E-05 -5.6620 0.21779E-05 -5.6620 0.10000E+01 0.0000 81 NaF,aq 0.37260E-08 -8.4288 0.37260E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96032E-04 -4.0176 0.96032E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90691E-02 -2.0424 0.75406E-02 -2.1226 0.83146E+00 -0.0802 89 HPO3-2 0.15530E-14 -14.8088 0.79660E-15 -15.0988 0.51296E+00 -0.2899 91 H2PO3- 0.14693E-18 -18.8329 0.12239E-18 -18.9122 0.83301E+00 -0.0793 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37410E-10 -10.4270 0.31193E-10 -10.5059 0.83382E+00 -0.0789 94 PO4-3 0.98969E-09 -9.0045 0.23501E-09 -9.6289 0.23746E+00 -0.6244 98 HP2O7-3 0.87986E-18 -18.0556 0.19884E-18 -18.7015 0.22599E+00 -0.6459 99 P2O7-4 0.83700E-17 -17.0773 0.61998E-18 -18.2076 0.74072E-01 -1.1303 100 H2S,aq 0.16109E-06 -6.7929 0.16060E-06 -6.7943 0.99691E+00 -0.0013 101 S2-2 0.17154E-11 -11.7656 0.87994E-12 -12.0555 0.51296E+00 -0.2899 102 S3-2 0.32046E-19 -19.4942 0.16438E-19 -19.7841 0.51296E+00 -0.2899 107 SO3-2 0.29979E-16 -16.5232 0.15607E-16 -16.8067 0.52060E+00 -0.2835 108 HSO3- 0.89880E-19 -19.0463 0.74871E-19 -19.1257 0.83301E+00 -0.0793 109 HSO4- 0.91639E-18 -18.0379 0.76564E-18 -18.1160 0.83549E+00 -0.0781 111 S2O3-2 0.38135E-19 -19.4187 0.19562E-19 -19.7086 0.51296E+00 -0.2899 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9140777E-10 -.2179702E-01 -.2193044E+02 0.0000 2 H2O 0.1000000E+01 0.5550709E+02 0.9981724E+06 0.0000 3 Cl- 0.4606607E-03 0.4628396E-03 0.1637944E+02 6.6997 4 SO4-- 0.2017006E-10 -.2181867E-02 -.2092154E+03 9.2471 5 HCO3- 0.4098392E-04 0.2295977E-02 0.1398413E+03 5.6496 6 HS- 0.8140265E-03 0.2996055E-02 0.9890673E+02 6.9470 7 Al+++ 0.1092386E-28 0.5161358E-05 0.1390099E+00 0.7390 8 H4SiO4 0.6959489E-03 0.1322744E-01 0.1269066E+04 -3.1574 9 Ca++ 0.1454661E-06 0.2817558E-06 0.1127183E-01 13.1018 10 Mg++ 0.2276024E-10 0.9879478E-10 0.2397565E-05 9.2942 11 Fe++ 0.6273125E-13 0.3523778E-07 0.1964373E-02 6.7350 12 K+ 0.1620371E-03 0.1627917E-03 0.6353994E+01 6.2467 13 Na+ 0.2056289E-01 0.2301045E-01 0.5280511E+03 8.3493 14 Mn++ 0.2015388E-10 0.2539917E-08 0.1392862E-03 9.2422 15 F- 0.1117957E-05 0.1121685E-05 0.2127131E-01 4.0838 16 HPO4-- 0.4292375E-07 0.4395085E-07 0.4210747E-02 12.5751 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279087E+02 -.1082483E-01 -.8278004E+02 0.0000000E+00 2 H2O -.7156025E+01 0.2756590E+02 -.3472193E+02 0.0000000E+00 3 Cl- 0.2298552E-03 0.2298552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386670E+00 -.1083558E-02 0.1397505E+00 0.0000000E+00 5 HCO3- 0.1140227E-02 0.1140227E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382626E+00 0.1487899E-02 -.1397505E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2563231E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6569004E-02 0.5205734E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1399254E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4906342E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1749977E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8084553E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1142744E-01 0.6264950E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1261373E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6336000E-05 0.5570505E-06 0.5778950E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2182685E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.2290E-14 Mass of aqueous solution: 0.497517E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0155900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 630.0 andradite 0.5590 -0.253 284.1 2.453 5.201 73.80 grossular 0.1354 -0.869 60.97 1.785 1.116 16.97 apatite-OH 0.9857E-02 -2.006 4.951 0.695 0.9064E-01 1.573 apatite-F 0.5779E-05 -5.238 0.2914E-02 -2.535 0.5335E-04 0.9105E-03 clinochlore 0.7092 -0.149 394.2 2.596 7.217 149.9 daphnite 0.2053 -0.688 146.5 2.166 2.682 44.39 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2329 -0.633 50.43 1.703 0.9232 15.41 hedenbergite 0.6039E-01 -1.219 14.98 1.176 0.2743 4.104 microcline 0.9320 -0.031 259.4 2.414 4.749 101.3 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2590 -0.587 279.1 2.446 5.110 96.42 tr.625ac.25prg.125 0.5221E-01 -1.282 44.63 1.650 0.8170 14.36 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.342695 g Volume = 2210.820871 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0155900 moles log = -1.8072 Original solution: 1000.0103000 g Original solution / Rock added: 64144.34 (Water/Rock Ratio), log = 4.8072 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.2452 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2437E+00 0.9724 0.1006E+01 0.1034E+01 CO2,gas 0.1422E-06 0.9918 0.5989E-06 0.6038E-06 CH4,gas 0.7527E+00 1.0006 0.3197E+01 0.3196E+01 H2,gas 0.3574E-02 1.0023 0.1521E-01 0.1517E-01 H2S,gas 0.1057E-05 0.9837 0.4415E-05 0.4488E-05 S2,gas 0.7453E-27 1.0000 0.3164E-26 0.3164E-26 CO,gas 0.5718E-12 1.0000 0.2427E-11 0.2427E-11 SO3,gas 0.5422E-47 1.0000 0.2302E-46 0.2302E-46 SO2,gas 0.3208E-26 1.0000 0.1362E-25 0.1362E-25 HF,gas 0.2819E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2239E-17 1.0000 0.9507E-17 0.9507E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.66728E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.58 -7.92 -2.641 0.13526E+05 -6.223 3 CH4,gas 4.54 3.35 -1.19 -0.299 0.20390E+04 0.505 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.28 -7.05 -3.527 0.12045E+05 -5.355 6 S2,gas -7.34 -35.53 -28.20 -4.338 0.48149E+05 -26.500 7 CO,gas 3.21 -10.10 -13.31 -4.097 0.22733E+05 -11.615 8 SO3,gas 17.12 -31.22 -48.34 -12.084 0.82534E+05 -46.638 9 SO2,gas 0.83 -26.73 -27.56 -7.351 0.47066E+05 -25.866 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.53 -18.72 -9.360 0.31966E+05 -17.022 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80676E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93630E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.48 -2.45 -0.815 0.41772E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.48 -2.29 -0.764 0.39130E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65538E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.62 -2.51 -0.718 0.42921E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.62 -2.07 -0.591 0.35343E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82230E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.32 -3.07 -0.722 0.52411E+04 146 pyrrhotite -4.26 -6.55 -2.29 -0.763 0.39084E+04 147 pyrrhotiteFe0.875 -6.02 -7.95 -1.93 -0.710 0.32956E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22434E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.34 -4.36 -1.454 0.74500E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23236E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47105E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.55 -2.14 -0.713 0.36512E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -4.04 -3.06 -1.021 0.52321E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0155900 MOLES New total amount of reactant added: 0.0159900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8649E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0159900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4966E+00 Moles total = -.7156E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .1009135E-01 Osmotic coef. = 0.9185 True ionic strength = .2081951E-01 Chg. balance for total moles = -.8649E-10 Max. difference allowed = 0.2322E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91479E-10 -10.0387 0.76674E-10 -10.1154 0.83816E+00 -0.0767 2 H2O 0.99996E+00 0.0000 0.99996E+00 0.0000 3 Cl- 0.46538E-03 -3.3322 0.38764E-03 -3.4116 0.83296E+00 -0.0794 4 SO4-- 0.20643E-10 -10.6852 0.10610E-10 -10.9743 0.51396E+00 -0.2891 5 HCO3- 0.41997E-04 -4.3768 0.35035E-04 -4.4555 0.83422E+00 -0.0787 6 HS- 0.83358E-03 -3.0791 0.69445E-03 -3.1584 0.83309E+00 -0.0793 7 Al+++ 0.10953E-28 -28.9605 0.24715E-29 -29.6070 0.22563E+00 -0.6466 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14571E-06 -6.8365 0.74323E-07 -7.1289 0.51007E+00 -0.2924 10 Mg++ 0.22799E-10 -10.6421 0.11574E-10 -10.9365 0.50767E+00 -0.2944 11 Fe++ 0.62837E-13 -13.2018 0.31936E-13 -13.4957 0.50824E+00 -0.2939 12 K+ 0.16216E-03 -3.7900 0.13531E-03 -3.8687 0.83442E+00 -0.0786 13 Na+ 0.20579E-01 -1.6866 0.17138E-01 -1.7660 0.83280E+00 -0.0795 14 Mn++ 0.20189E-10 -10.6949 0.10269E-10 -10.9885 0.50867E+00 -0.2936 15 F- 0.11172E-05 -5.9519 0.92862E-06 -6.0322 0.83119E+00 -0.0803 16 HPO4-- 0.42872E-07 -7.3678 0.22038E-07 -7.6568 0.51404E+00 -0.2890 18 HSiO3- 0.10175E-01 -1.9925 0.84757E-02 -2.0718 0.83296E+00 -0.0794 19 Ca(HSiO3)+ 0.17189E-07 -7.7647 0.14346E-07 -7.8433 0.83461E+00 -0.0785 20 Mg(HSiO3)+ 0.33313E-11 -11.4774 0.27803E-11 -11.5559 0.83461E+00 -0.0785 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.68523E-16 -16.1642 0.57190E-16 -16.2427 0.83461E+00 -0.0785 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51578E-05 -5.2875 0.42882E-05 -5.3677 0.83141E+00 -0.0802 26 CH4,aq 0.22343E-02 -2.6509 0.22274E-02 -2.6522 0.99692E+00 -0.0013 27 C2H6,aq 0.73459E-10 -10.1340 0.73232E-10 -10.1353 0.99692E+00 -0.0013 28 C3H8,aq 0.55759E-16 -16.2537 0.55587E-16 -16.2550 0.99692E+00 -0.0013 30 ethanol,aq 0.26962E-17 -17.5692 0.26879E-17 -17.5706 0.99692E+00 -0.0013 31 CO,aq 0.16702E-14 -14.7772 0.16702E-14 -14.7772 0.10000E+01 0.0000 32 CO2,aq 0.57579E-08 -8.2397 0.57402E-08 -8.2411 0.99692E+00 -0.0013 33 CO3-2 0.77825E-04 -4.1089 0.39912E-04 -4.3989 0.51284E+00 -0.2900 34 CaCO3,aq 0.37195E-07 -7.4295 0.37195E-07 -7.4295 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.79639E-10 -10.0989 0.66467E-10 -10.1774 0.83461E+00 -0.0785 36 CaCl+ 0.55865E-10 -10.2529 0.46625E-10 -10.3314 0.83461E+00 -0.0785 37 CaCl2,aq 0.42940E-14 -14.3671 0.42940E-14 -14.3671 0.10000E+01 0.0000 38 CaF+ 0.12074E-11 -11.9182 0.10077E-11 -11.9967 0.83461E+00 -0.0785 39 CaOH+ 0.82772E-07 -7.0821 0.69082E-07 -7.1606 0.83461E+00 -0.0785 40 CaSO4,aq 0.25040E-15 -15.6014 0.25040E-15 -15.6014 0.10000E+01 0.0000 41 HCl,aq 0.54465E-14 -14.2639 0.54465E-14 -14.2639 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18346E-18 -18.7364 0.15282E-18 -18.8158 0.83296E+00 -0.0794 48 FeCl+ 0.23479E-16 -16.6293 0.19595E-16 -16.7078 0.83461E+00 -0.0785 51 FeF+ 0.18158E-17 -17.7409 0.15155E-17 -17.8194 0.83461E+00 -0.0785 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16244E-10 -10.7893 0.13558E-10 -10.8678 0.83461E+00 -0.0785 55 HFeO2- 0.34587E-07 -7.4611 0.28809E-07 -7.5405 0.83296E+00 -0.0794 56 FeO+ 0.11385E-16 -16.9437 0.95020E-17 -17.0222 0.83461E+00 -0.0785 58 FeO2- 0.39704E-09 -9.4012 0.33072E-09 -9.4805 0.83296E+00 -0.0794 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11618E-04 -4.9349 0.11582E-04 -4.9362 0.99692E+00 -0.0013 61 KCl,aq 0.95067E-09 -9.0220 0.95067E-09 -9.0220 0.10000E+01 0.0000 63 KOH,aq 0.75363E-06 -6.1228 0.75363E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.26745E-13 -13.5728 0.22278E-13 -13.6521 0.83296E+00 -0.0794 65 MgCO3,aq 0.14519E-11 -11.8381 0.14519E-11 -11.8381 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12673E-13 -13.8971 0.10577E-13 -13.9757 0.83461E+00 -0.0785 67 MgCl+ 0.78849E-14 -14.1032 0.65808E-14 -14.1817 0.83461E+00 -0.0785 68 MgF+ 0.69648E-15 -15.1571 0.58128E-15 -15.2356 0.83461E+00 -0.0785 69 MgOH+ 0.71326E-10 -10.1468 0.59529E-10 -10.2253 0.83461E+00 -0.0785 71 MnF+ 0.19246E-15 -15.7157 0.16063E-15 -15.7942 0.83461E+00 -0.0785 72 MnO,aq 0.18090E-08 -8.7426 0.18090E-08 -8.7426 0.10000E+01 0.0000 73 MnOH+ 0.48525E-09 -9.3140 0.40499E-09 -9.3926 0.83461E+00 -0.0785 74 MnO2-2 0.19912E-10 -10.7009 0.10211E-10 -10.9909 0.51284E+00 -0.2900 75 HMnO2- 0.20593E-09 -9.6863 0.17153E-09 -9.7657 0.83296E+00 -0.0794 78 MnCl+ 0.29372E-13 -13.5321 0.24514E-13 -13.6106 0.83461E+00 -0.0785 79 MnSO4,aq 0.31455E-19 -19.5023 0.31455E-19 -19.5023 0.10000E+01 0.0000 80 NaCl,aq 0.22017E-05 -5.6572 0.22017E-05 -5.6572 0.10000E+01 0.0000 81 NaF,aq 0.37260E-08 -8.4288 0.37260E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96032E-04 -4.0176 0.96032E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90631E-02 -2.0427 0.75352E-02 -2.1229 0.83141E+00 -0.0802 89 HPO3-2 0.15511E-14 -14.8094 0.79545E-15 -15.0994 0.51284E+00 -0.2900 91 H2PO3- 0.14683E-18 -18.8332 0.12230E-18 -18.9126 0.83296E+00 -0.0794 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37385E-10 -10.4273 0.31171E-10 -10.5063 0.83377E+00 -0.0790 94 PO4-3 0.98803E-09 -9.0052 0.23450E-09 -9.6298 0.23735E+00 -0.6246 98 HP2O7-3 0.87842E-18 -18.0563 0.19841E-18 -18.7024 0.22587E+00 -0.6461 99 P2O7-4 0.83534E-17 -17.0781 0.61819E-18 -18.2089 0.74005E-01 -1.1307 100 H2S,aq 0.16507E-06 -6.7823 0.16456E-06 -6.7837 0.99692E+00 -0.0013 101 S2-2 0.17990E-11 -11.7450 0.92262E-12 -12.0350 0.51284E+00 -0.2900 102 S3-2 0.34438E-19 -19.4630 0.17661E-19 -19.7530 0.51284E+00 -0.2900 107 SO3-2 0.30682E-16 -16.5131 0.15969E-16 -16.7967 0.52049E+00 -0.2836 108 HSO3- 0.92039E-19 -19.0360 0.76665E-19 -19.1154 0.83296E+00 -0.0794 109 HSO4- 0.93840E-18 -18.0276 0.78398E-18 -18.1057 0.83544E+00 -0.0781 111 S2O3-2 0.39994E-19 -19.3980 0.20511E-19 -19.6880 0.51284E+00 -0.2900 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9147902E-10 -.2178605E-01 -.2191938E+02 0.0000 2 H2O 0.1000000E+01 0.5550714E+02 0.9981718E+06 0.0000 3 Cl- 0.4653822E-03 0.4675848E-03 0.1654735E+02 6.7038 4 SO4-- 0.2064320E-10 -.2237215E-02 -.2145223E+03 9.2564 5 HCO3- 0.4199750E-04 0.2354176E-02 0.1433858E+03 5.6599 6 HS- 0.8335826E-03 0.3070963E-02 0.1013795E+03 6.9570 7 Al+++ 0.1095338E-28 0.5157941E-05 0.1389176E+00 0.7390 8 H4SiO4 0.6959481E-03 0.1322067E-01 0.1268415E+04 -3.1574 9 Ca++ 0.1457110E-06 0.2830032E-06 0.1132172E-01 13.1018 10 Mg++ 0.2279863E-10 0.9892925E-10 0.2400824E-05 9.2942 11 Fe++ 0.6283708E-13 0.3521452E-07 0.1963073E-02 6.7350 12 K+ 0.1621634E-03 0.1629180E-03 0.6358913E+01 6.2467 13 Na+ 0.2057894E-01 0.2302652E-01 0.5284191E+03 8.3493 14 Mn++ 0.2018864E-10 0.2540267E-08 0.1393052E-03 9.2423 15 F- 0.1117215E-05 0.1120943E-05 0.2125721E-01 4.0832 16 HPO4-- 0.4287152E-07 0.4389693E-07 0.4205574E-02 12.5739 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279083E+02 -.1081954E-01 -.8278001E+02 0.0000000E+00 2 H2O -.7155698E+01 0.2756634E+02 -.3472203E+02 0.0000000E+00 3 Cl- 0.2322152E-03 0.2322152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386689E+00 -.1111061E-02 0.1397799E+00 0.0000000E+00 5 HCO3- 0.1169147E-02 0.1169147E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382548E+00 0.1525123E-02 -.1397799E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2561572E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6565740E-02 0.5205734E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1405470E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4913092E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1748847E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8090944E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1143559E-01 0.6264941E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1261565E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6496000E-05 0.5566904E-06 0.5939310E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2180039E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1756E-14 Mass of aqueous solution: 0.497525E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0159900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 630.0 andradite 0.5591 -0.252 284.1 2.454 5.202 73.82 grossular 0.1354 -0.868 60.99 1.785 1.116 16.97 apatite-OH 0.9857E-02 -2.006 4.951 0.695 0.9064E-01 1.573 apatite-F 0.5939E-05 -5.226 0.2995E-02 -2.524 0.5483E-04 0.9357E-03 clinochlore 0.7092 -0.149 394.2 2.596 7.217 149.9 daphnite 0.2053 -0.688 146.5 2.166 2.682 44.39 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2321 -0.634 50.26 1.701 0.9202 15.36 hedenbergite 0.6019E-01 -1.220 14.93 1.174 0.2734 4.090 microcline 0.9320 -0.031 259.4 2.414 4.749 101.3 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2589 -0.587 279.1 2.446 5.109 96.40 tr.625ac.25prg.125 0.5246E-01 -1.280 44.84 1.652 0.8209 14.43 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.342814 g Volume = 2210.821975 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0159900 moles log = -1.7962 Original solution: 1000.0103000 g Original solution / Rock added: 62539.73 (Water/Rock Ratio), log = 4.7962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.3269 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2391E+00 0.9723 0.1006E+01 0.1035E+01 CO2,gas 0.1431E-06 0.9916 0.6141E-06 0.6193E-06 CH4,gas 0.7574E+00 1.0005 0.3279E+01 0.3277E+01 H2,gas 0.3506E-02 1.0023 0.1521E-01 0.1517E-01 H2S,gas 0.1063E-05 0.9833 0.4524E-05 0.4600E-05 S2,gas 0.7678E-27 1.0000 0.3322E-26 0.3322E-26 CO,gas 0.5752E-12 1.0000 0.2489E-11 0.2489E-11 SO3,gas 0.5451E-47 1.0000 0.2358E-46 0.2358E-46 SO2,gas 0.3225E-26 1.0000 0.1395E-25 0.1395E-25 HF,gas 0.2766E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2221E-17 1.0000 0.9610E-17 0.9610E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.57 -7.91 -2.637 0.13507E+05 -6.212 3 CH4,gas 4.54 3.36 -1.18 -0.296 0.20204E+04 0.516 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.27 -7.04 -3.522 0.12027E+05 -5.345 6 S2,gas -7.34 -35.51 -28.18 -4.335 0.48112E+05 -26.479 7 CO,gas 3.21 -10.09 -13.30 -4.093 0.22714E+05 -11.604 8 SO3,gas 17.12 -31.20 -48.33 -12.082 0.82516E+05 -46.627 9 SO2,gas 0.83 -26.72 -27.55 -7.348 0.47048E+05 -25.855 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.53 -18.72 -9.358 0.31957E+05 -17.017 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80675E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93631E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28490E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.47 -2.44 -0.812 0.41586E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.47 -2.28 -0.760 0.38944E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65537E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.61 -2.50 -0.715 0.42735E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.61 -2.06 -0.588 0.35157E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82230E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.30 -3.05 -0.717 0.52049E+04 146 pyrrhotite -4.26 -6.54 -2.28 -0.759 0.38903E+04 147 pyrrhotiteFe0.875 -6.02 -7.94 -1.92 -0.706 0.32775E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22433E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28678E+03 154 rhodochrosite -0.98 -5.33 -4.35 -1.451 0.74314E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23236E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47104E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.54 -2.13 -0.709 0.36331E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -4.03 -3.05 -1.018 0.52139E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0159900 MOLES New total amount of reactant added: 0.0163900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8649E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0163900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4966E+00 Moles total = -.7155E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .1005765E-01 Osmotic coef. = 0.9187 True ionic strength = .2083753E-01 Chg. balance for total moles = -.8649E-10 Max. difference allowed = 0.2346E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91550E-10 -10.0383 0.76729E-10 -10.1150 0.83811E+00 -0.0767 2 H2O 0.99996E+00 0.0000 0.99996E+00 0.0000 3 Cl- 0.47010E-03 -3.3278 0.39155E-03 -3.4072 0.83291E+00 -0.0794 4 SO4-- 0.21116E-10 -10.6754 0.10850E-10 -10.9646 0.51385E+00 -0.2892 5 HCO3- 0.43010E-04 -4.3664 0.35877E-04 -4.4452 0.83417E+00 -0.0787 6 HS- 0.85314E-03 -3.0690 0.71070E-03 -3.1483 0.83304E+00 -0.0793 7 Al+++ 0.10983E-28 -28.9593 0.24768E-29 -29.6061 0.22552E+00 -0.6468 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14596E-06 -6.8358 0.74431E-07 -7.1282 0.50995E+00 -0.2925 10 Mg++ 0.22837E-10 -10.6414 0.11591E-10 -10.9359 0.50754E+00 -0.2945 11 Fe++ 0.62943E-13 -13.2011 0.31983E-13 -13.4951 0.50812E+00 -0.2940 12 K+ 0.16229E-03 -3.7897 0.13541E-03 -3.8683 0.83437E+00 -0.0786 13 Na+ 0.20595E-01 -1.6862 0.17151E-01 -1.7657 0.83275E+00 -0.0795 14 Mn++ 0.20223E-10 -10.6941 0.10285E-10 -10.9878 0.50855E+00 -0.2937 15 F- 0.11165E-05 -5.9522 0.92795E-06 -6.0325 0.83114E+00 -0.0803 16 HPO4-- 0.42819E-07 -7.3684 0.22006E-07 -7.6575 0.51392E+00 -0.2891 18 HSiO3- 0.10169E-01 -1.9927 0.84695E-02 -2.0721 0.83291E+00 -0.0794 19 Ca(HSiO3)+ 0.17202E-07 -7.7644 0.14356E-07 -7.8430 0.83456E+00 -0.0785 20 Mg(HSiO3)+ 0.33339E-11 -11.4770 0.27823E-11 -11.5556 0.83456E+00 -0.0785 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.68577E-16 -16.1638 0.57231E-16 -16.2424 0.83456E+00 -0.0785 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51544E-05 -5.2878 0.42851E-05 -5.3680 0.83136E+00 -0.0802 26 CH4,aq 0.22897E-02 -2.6402 0.22826E-02 -2.6416 0.99693E+00 -0.0013 27 C2H6,aq 0.77144E-10 -10.1127 0.76907E-10 -10.1140 0.99693E+00 -0.0013 28 C3H8,aq 0.60008E-16 -16.2218 0.59823E-16 -16.2231 0.99693E+00 -0.0013 30 ethanol,aq 0.28315E-17 -17.5480 0.28228E-17 -17.5493 0.99693E+00 -0.0013 31 CO,aq 0.17116E-14 -14.7666 0.17116E-14 -14.7666 0.10000E+01 0.0000 32 CO2,aq 0.59006E-08 -8.2291 0.58824E-08 -8.2304 0.99693E+00 -0.0013 33 CO3-2 0.79657E-04 -4.0988 0.40842E-04 -4.3889 0.51272E+00 -0.2901 34 CaCO3,aq 0.38117E-07 -7.4189 0.38117E-07 -7.4189 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.81677E-10 -10.0879 0.68164E-10 -10.1664 0.83456E+00 -0.0785 36 CaCl+ 0.56513E-10 -10.2478 0.47164E-10 -10.3264 0.83456E+00 -0.0785 37 CaCl2,aq 0.43874E-14 -14.3578 0.43874E-14 -14.3578 0.10000E+01 0.0000 38 CaF+ 0.12083E-11 -11.9178 0.10084E-11 -11.9964 0.83456E+00 -0.0785 39 CaOH+ 0.82836E-07 -7.0818 0.69132E-07 -7.1603 0.83456E+00 -0.0785 40 CaSO4,aq 0.25645E-15 -15.5910 0.25645E-15 -15.5910 0.10000E+01 0.0000 41 HCl,aq 0.55054E-14 -14.2592 0.55054E-14 -14.2592 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18334E-18 -18.7367 0.15271E-18 -18.8161 0.83291E+00 -0.0794 48 FeCl+ 0.23751E-16 -16.6243 0.19822E-16 -16.7029 0.83456E+00 -0.0785 51 FeF+ 0.18173E-17 -17.7406 0.15166E-17 -17.8191 0.83456E+00 -0.0785 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16257E-10 -10.7890 0.13567E-10 -10.8675 0.83456E+00 -0.0785 55 HFeO2- 0.34564E-07 -7.4614 0.28789E-07 -7.5408 0.83291E+00 -0.0794 56 FeO+ 0.11394E-16 -16.9433 0.95089E-17 -17.0219 0.83456E+00 -0.0785 58 FeO2- 0.39677E-09 -9.4015 0.33048E-09 -9.4809 0.83291E+00 -0.0794 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11618E-04 -4.9349 0.11582E-04 -4.9362 0.99693E+00 -0.0013 61 KCl,aq 0.96095E-09 -9.0173 0.96095E-09 -9.0173 0.10000E+01 0.0000 63 KOH,aq 0.75363E-06 -6.1228 0.75363E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.27373E-13 -13.5627 0.22799E-13 -13.6421 0.83291E+00 -0.0794 65 MgCO3,aq 0.14878E-11 -11.8274 0.14878E-11 -11.8274 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12997E-13 -13.8862 0.10847E-13 -13.9647 0.83456E+00 -0.0785 67 MgCl+ 0.79764E-14 -14.0982 0.66567E-14 -14.1767 0.83456E+00 -0.0785 68 MgF+ 0.69702E-15 -15.1568 0.58170E-15 -15.2353 0.83456E+00 -0.0785 69 MgOH+ 0.71381E-10 -10.1464 0.59572E-10 -10.2250 0.83456E+00 -0.0785 71 MnF+ 0.19262E-15 -15.7153 0.16075E-15 -15.7938 0.83456E+00 -0.0785 72 MnO,aq 0.18090E-08 -8.7426 0.18090E-08 -8.7426 0.10000E+01 0.0000 73 MnOH+ 0.48565E-09 -9.3137 0.40530E-09 -9.3922 0.83456E+00 -0.0785 74 MnO2-2 0.19888E-10 -10.7014 0.10197E-10 -10.9915 0.51272E+00 -0.2901 75 HMnO2- 0.20580E-09 -9.6866 0.17141E-09 -9.7660 0.83291E+00 -0.0794 78 MnCl+ 0.29714E-13 -13.5270 0.24798E-13 -13.6056 0.83456E+00 -0.0785 79 MnSO4,aq 0.32216E-19 -19.4919 0.32216E-19 -19.4919 0.10000E+01 0.0000 80 NaCl,aq 0.22255E-05 -5.6526 0.22255E-05 -5.6526 0.10000E+01 0.0000 81 NaF,aq 0.37259E-08 -8.4288 0.37259E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96031E-04 -4.0176 0.96031E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90571E-02 -2.0430 0.75297E-02 -2.1232 0.83136E+00 -0.0802 89 HPO3-2 0.15492E-14 -14.8099 0.79430E-15 -15.1000 0.51272E+00 -0.2901 91 H2PO3- 0.14673E-18 -18.8335 0.12222E-18 -18.9129 0.83291E+00 -0.0794 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37360E-10 -10.4276 0.31148E-10 -10.5066 0.83373E+00 -0.0790 94 PO4-3 0.98637E-09 -9.0060 0.23400E-09 -9.6308 0.23723E+00 -0.6248 98 HP2O7-3 0.87697E-18 -18.0570 0.19798E-18 -18.7034 0.22575E+00 -0.6464 99 P2O7-4 0.83369E-17 -17.0790 0.61641E-18 -18.2101 0.73937E-01 -1.1311 100 H2S,aq 0.16905E-06 -6.7720 0.16853E-06 -6.7733 0.99693E+00 -0.0013 101 S2-2 0.18847E-11 -11.7248 0.96630E-12 -12.0149 0.51272E+00 -0.2901 102 S3-2 0.36948E-19 -19.4324 0.18944E-19 -19.7225 0.51272E+00 -0.2901 107 SO3-2 0.31384E-16 -16.5033 0.16331E-16 -16.7870 0.52037E+00 -0.2837 108 HSO3- 0.94198E-19 -19.0260 0.78459E-19 -19.1054 0.83291E+00 -0.0794 109 HSO4- 0.96041E-18 -18.0175 0.80233E-18 -18.0956 0.83540E+00 -0.0781 111 S2O3-2 0.41898E-19 -19.3778 0.21482E-19 -19.6679 0.51272E+00 -0.2901 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9155028E-10 -.2177510E-01 -.2190832E+02 0.0000 2 H2O 0.1000000E+01 0.5550720E+02 0.9981711E+06 0.0000 3 Cl- 0.4701035E-03 0.4723300E-03 0.1671524E+02 6.7078 4 SO4-- 0.2111580E-10 -.2292567E-02 -.2198296E+03 9.2655 5 HCO3- 0.4300982E-04 0.2412373E-02 0.1469302E+03 5.6699 6 HS- 0.8531381E-03 0.3145874E-02 0.1038523E+03 6.9667 7 Al+++ 0.1098296E-28 0.5154527E-05 0.1388255E+00 0.7390 8 H4SiO4 0.6959474E-03 0.1321391E-01 0.1267764E+04 -3.1574 9 Ca++ 0.1459562E-06 0.2842511E-06 0.1137162E-01 13.1018 10 Mg++ 0.2283707E-10 0.9906103E-10 0.2404018E-05 9.2942 11 Fe++ 0.6294302E-13 0.3519128E-07 0.1961775E-02 6.7350 12 K+ 0.1622897E-03 0.1630443E-03 0.6363834E+01 6.2467 13 Na+ 0.2059500E-01 0.2304260E-01 0.5287871E+03 8.3493 14 Mn++ 0.2022345E-10 0.2540618E-08 0.1393241E-03 9.2423 15 F- 0.1116475E-05 0.1120202E-05 0.2124313E-01 4.0826 16 HPO4-- 0.4281938E-07 0.4384311E-07 0.4200411E-02 12.5726 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279078E+02 -.1081426E-01 -.8277997E+02 0.0000000E+00 2 H2O -.7155370E+01 0.2756677E+02 -.3472214E+02 0.0000000E+00 3 Cl- 0.2345752E-03 0.2345752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386708E+00 -.1138567E-02 0.1398094E+00 0.0000000E+00 5 HCO3- 0.1198067E-02 0.1198067E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382470E+00 0.1562349E-02 -.1398094E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2559914E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6562479E-02 0.5205734E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1411688E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4919709E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1747719E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8097338E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1144374E-01 0.6264933E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1261758E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6656000E-05 0.5563307E-06 0.6099669E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2177398E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.9090E-15 Mass of aqueous solution: 0.497534E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0163900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 630.0 andradite 0.5592 -0.252 284.2 2.454 5.203 73.84 grossular 0.1354 -0.868 61.00 1.785 1.117 16.97 apatite-OH 0.9857E-02 -2.006 4.951 0.695 0.9064E-01 1.573 apatite-F 0.6100E-05 -5.215 0.3076E-02 -2.512 0.5632E-04 0.9610E-03 clinochlore 0.7092 -0.149 394.2 2.596 7.216 149.9 daphnite 0.2053 -0.688 146.5 2.166 2.682 44.39 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2313 -0.636 50.10 1.700 0.9171 15.31 hedenbergite 0.5999E-01 -1.222 14.88 1.173 0.2725 4.077 microcline 0.9321 -0.031 259.4 2.414 4.749 101.3 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2588 -0.587 279.0 2.446 5.108 96.38 tr.625ac.25prg.125 0.5271E-01 -1.278 45.06 1.654 0.8248 14.50 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.342933 g Volume = 2210.823079 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0163900 moles log = -1.7854 Original solution: 1000.0103000 g Original solution / Rock added: 61013.44 (Water/Rock Ratio), log = 4.7854 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.4087 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2347E+00 0.9721 0.1006E+01 0.1035E+01 CO2,gas 0.1440E-06 0.9915 0.6294E-06 0.6348E-06 CH4,gas 0.7618E+00 1.0003 0.3360E+01 0.3359E+01 H2,gas 0.3441E-02 1.0024 0.1521E-01 0.1517E-01 H2S,gas 0.1069E-05 0.9830 0.4633E-05 0.4713E-05 S2,gas 0.7904E-27 1.0000 0.3484E-26 0.3484E-26 CO,gas 0.5785E-12 1.0000 0.2551E-11 0.2551E-11 SO3,gas 0.5479E-47 1.0000 0.2415E-46 0.2415E-46 SO2,gas 0.3241E-26 1.0000 0.1429E-25 0.1429E-25 HF,gas 0.2715E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2203E-17 1.0000 0.9714E-17 0.9714E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.56 -7.90 -2.633 0.13489E+05 -6.201 3 CH4,gas 4.54 3.37 -1.17 -0.293 0.20023E+04 0.526 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.26 -7.03 -3.517 0.12009E+05 -5.334 6 S2,gas -7.34 -35.49 -28.16 -4.332 0.48077E+05 -26.458 7 CO,gas 3.21 -10.08 -13.29 -4.090 0.22696E+05 -11.593 8 SO3,gas 17.12 -31.19 -48.32 -12.079 0.82498E+05 -46.617 9 SO2,gas 0.83 -26.71 -27.54 -7.345 0.47031E+05 -25.845 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.52 -18.71 -9.356 0.31949E+05 -17.013 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80674E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93631E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.46 -2.42 -0.808 0.41405E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.46 -2.27 -0.757 0.38762E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65537E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.59 -2.49 -0.712 0.42553E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.59 -2.05 -0.585 0.34976E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82230E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.27 -3.03 -0.712 0.51695E+04 146 pyrrhotite -4.26 -6.53 -2.27 -0.756 0.38726E+04 147 pyrrhotiteFe0.875 -6.02 -7.93 -1.91 -0.702 0.32598E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22433E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.32 -4.34 -1.447 0.74132E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23236E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47104E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.53 -2.12 -0.706 0.36154E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -4.02 -3.04 -1.014 0.51962E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0163900 MOLES New total amount of reactant added: 0.0167900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8648E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0167900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4966E+00 Moles total = -.7155E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .1002395E-01 Osmotic coef. = 0.9189 True ionic strength = .2085555E-01 Chg. balance for total moles = -.8648E-10 Max. difference allowed = 0.2369E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91622E-10 -10.0380 0.76785E-10 -10.1147 0.83806E+00 -0.0767 2 H2O 0.99996E+00 0.0000 0.99996E+00 0.0000 3 Cl- 0.47482E-03 -3.3235 0.39546E-03 -3.4029 0.83286E+00 -0.0794 4 SO4-- 0.21588E-10 -10.6658 0.11090E-10 -10.9551 0.51373E+00 -0.2893 5 HCO3- 0.44021E-04 -4.3563 0.36719E-04 -4.4351 0.83412E+00 -0.0788 6 HS- 0.87269E-03 -3.0591 0.72694E-03 -3.1385 0.83299E+00 -0.0794 7 Al+++ 0.11013E-28 -28.9581 0.24822E-29 -29.6052 0.22540E+00 -0.6471 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14620E-06 -6.8350 0.74538E-07 -7.1276 0.50983E+00 -0.2926 10 Mg++ 0.22876E-10 -10.6406 0.11608E-10 -10.9353 0.50742E+00 -0.2946 11 Fe++ 0.63049E-13 -13.2003 0.32029E-13 -13.4945 0.50800E+00 -0.2941 12 K+ 0.16242E-03 -3.7894 0.13551E-03 -3.8680 0.83432E+00 -0.0787 13 Na+ 0.20611E-01 -1.6859 0.17163E-01 -1.7654 0.83270E+00 -0.0795 14 Mn++ 0.20258E-10 -10.6934 0.10300E-10 -10.9872 0.50843E+00 -0.2938 15 F- 0.11157E-05 -5.9524 0.92728E-06 -6.0328 0.83109E+00 -0.0804 16 HPO4-- 0.42767E-07 -7.3689 0.21974E-07 -7.6581 0.51380E+00 -0.2892 18 HSiO3- 0.10162E-01 -1.9930 0.84634E-02 -2.0725 0.83286E+00 -0.0794 19 Ca(HSiO3)+ 0.17216E-07 -7.7641 0.14367E-07 -7.8426 0.83451E+00 -0.0786 20 Mg(HSiO3)+ 0.33365E-11 -11.4767 0.27843E-11 -11.5553 0.83451E+00 -0.0786 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.68630E-16 -16.1635 0.57273E-16 -16.2421 0.83451E+00 -0.0786 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51510E-05 -5.2881 0.42820E-05 -5.3683 0.83131E+00 -0.0802 26 CH4,aq 0.23450E-02 -2.6299 0.23378E-02 -2.6312 0.99694E+00 -0.0013 27 C2H6,aq 0.80920E-10 -10.0919 0.80673E-10 -10.0933 0.99694E+00 -0.0013 28 C3H8,aq 0.64468E-16 -16.1907 0.64270E-16 -16.1920 0.99694E+00 -0.0013 30 ethanol,aq 0.29701E-17 -17.5272 0.29610E-17 -17.5286 0.99694E+00 -0.0013 31 CO,aq 0.17530E-14 -14.7562 0.17530E-14 -14.7562 0.10000E+01 0.0000 32 CO2,aq 0.60432E-08 -8.2187 0.60247E-08 -8.2201 0.99694E+00 -0.0013 33 CO3-2 0.81484E-04 -4.0889 0.41769E-04 -4.3791 0.51260E+00 -0.2902 34 CaCO3,aq 0.39039E-07 -7.4085 0.39039E-07 -7.4085 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.83718E-10 -10.0772 0.69863E-10 -10.1558 0.83451E+00 -0.0786 36 CaCl+ 0.57163E-10 -10.2429 0.47703E-10 -10.3215 0.83451E+00 -0.0786 37 CaCl2,aq 0.44819E-14 -14.3485 0.44819E-14 -14.3485 0.10000E+01 0.0000 38 CaF+ 0.12092E-11 -11.9175 0.10091E-11 -11.9961 0.83451E+00 -0.0786 39 CaOH+ 0.82901E-07 -7.0814 0.69182E-07 -7.1600 0.83451E+00 -0.0786 40 CaSO4,aq 0.26250E-15 -15.5809 0.26250E-15 -15.5809 0.10000E+01 0.0000 41 HCl,aq 0.55644E-14 -14.2546 0.55644E-14 -14.2546 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18322E-18 -18.7370 0.15260E-18 -18.8165 0.83286E+00 -0.0794 48 FeCl+ 0.24024E-16 -16.6193 0.20048E-16 -16.6979 0.83451E+00 -0.0786 51 FeF+ 0.18187E-17 -17.7402 0.15177E-17 -17.8188 0.83451E+00 -0.0786 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16270E-10 -10.7886 0.13577E-10 -10.8672 0.83451E+00 -0.0786 55 HFeO2- 0.34541E-07 -7.4617 0.28768E-07 -7.5411 0.83286E+00 -0.0794 56 FeO+ 0.11403E-16 -16.9430 0.95158E-17 -17.0216 0.83451E+00 -0.0786 58 FeO2- 0.39651E-09 -9.4017 0.33024E-09 -9.4812 0.83286E+00 -0.0794 59 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11618E-04 -4.9349 0.11582E-04 -4.9362 0.99694E+00 -0.0013 61 KCl,aq 0.97124E-09 -9.0127 0.97124E-09 -9.0127 0.10000E+01 0.0000 63 KOH,aq 0.75363E-06 -6.1228 0.75363E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.28000E-13 -13.5528 0.23320E-13 -13.6323 0.83286E+00 -0.0794 65 MgCO3,aq 0.15238E-11 -11.8171 0.15238E-11 -11.8171 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13322E-13 -13.8754 0.11117E-13 -13.9540 0.83451E+00 -0.0786 67 MgCl+ 0.80681E-14 -14.0932 0.67329E-14 -14.1718 0.83451E+00 -0.0786 68 MgF+ 0.69756E-15 -15.1564 0.58212E-15 -15.2350 0.83451E+00 -0.0786 69 MgOH+ 0.71437E-10 -10.1461 0.59615E-10 -10.2246 0.83451E+00 -0.0786 71 MnF+ 0.19277E-15 -15.7149 0.16087E-15 -15.7935 0.83451E+00 -0.0786 72 MnO,aq 0.18091E-08 -8.7425 0.18091E-08 -8.7425 0.10000E+01 0.0000 73 MnOH+ 0.48605E-09 -9.3133 0.40561E-09 -9.3919 0.83451E+00 -0.0786 74 MnO2-2 0.19865E-10 -10.7019 0.10183E-10 -10.9921 0.51260E+00 -0.2902 75 HMnO2- 0.20567E-09 -9.6868 0.17130E-09 -9.7662 0.83286E+00 -0.0794 78 MnCl+ 0.30057E-13 -13.5221 0.25083E-13 -13.6006 0.83451E+00 -0.0786 79 MnSO4,aq 0.32977E-19 -19.4818 0.32977E-19 -19.4818 0.10000E+01 0.0000 80 NaCl,aq 0.22493E-05 -5.6479 0.22493E-05 -5.6479 0.10000E+01 0.0000 81 NaF,aq 0.37259E-08 -8.4288 0.37259E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96031E-04 -4.0176 0.96031E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90511E-02 -2.0433 0.75243E-02 -2.1235 0.83131E+00 -0.0802 89 HPO3-2 0.15473E-14 -14.8104 0.79315E-15 -15.1006 0.51260E+00 -0.2902 91 H2PO3- 0.14664E-18 -18.8338 0.12213E-18 -18.9132 0.83286E+00 -0.0794 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37335E-10 -10.4279 0.31126E-10 -10.5069 0.83368E+00 -0.0790 94 PO4-3 0.98472E-09 -9.0067 0.23349E-09 -9.6317 0.23711E+00 -0.6250 98 HP2O7-3 0.87553E-18 -18.0577 0.19755E-18 -18.7043 0.22563E+00 -0.6466 99 P2O7-4 0.83204E-17 -17.0799 0.61463E-18 -18.2114 0.73870E-01 -1.1315 100 H2S,aq 0.17304E-06 -6.7618 0.17251E-06 -6.7632 0.99694E+00 -0.0013 101 S2-2 0.19723E-11 -11.7050 0.10110E-11 -11.9953 0.51260E+00 -0.2902 102 S3-2 0.39578E-19 -19.4025 0.20288E-19 -19.6928 0.51260E+00 -0.2902 107 SO3-2 0.32085E-16 -16.4937 0.16693E-16 -16.7775 0.52026E+00 -0.2838 108 HSO3- 0.96357E-19 -19.0161 0.80252E-19 -19.0955 0.83286E+00 -0.0794 109 HSO4- 0.98243E-18 -18.0077 0.82067E-18 -18.0858 0.83535E+00 -0.0781 111 S2O3-2 0.43845E-19 -19.3581 0.22475E-19 -19.6483 0.51260E+00 -0.2902 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9162157E-10 -.2176416E-01 -.2189727E+02 0.0000 2 H2O 0.1000000E+01 0.5550725E+02 0.9981705E+06 0.0000 3 Cl- 0.4748246E-03 0.4770749E-03 0.1688314E+02 6.7118 4 SO4-- 0.2158786E-10 -.2347923E-02 -.2251372E+03 9.2744 5 HCO3- 0.4402089E-04 0.2470569E-02 0.1504745E+03 5.6796 6 HS- 0.8726930E-03 0.3220789E-02 0.1063252E+03 6.9762 7 Al+++ 0.1101261E-28 0.5151118E-05 0.1387334E+00 0.7390 8 H4SiO4 0.6959466E-03 0.1320716E-01 0.1267115E+04 -3.1574 9 Ca++ 0.1462017E-06 0.2854994E-06 0.1142154E-01 13.1018 10 Mg++ 0.2287555E-10 0.9919728E-10 0.2407321E-05 9.2942 11 Fe++ 0.6304910E-13 0.3516807E-07 0.1960478E-02 6.7350 12 K+ 0.1624161E-03 0.1631707E-03 0.6368756E+01 6.2467 13 Na+ 0.2061106E-01 0.2305868E-01 0.5291553E+03 8.3493 14 Mn++ 0.2025830E-10 0.2540969E-08 0.1393432E-03 9.2423 15 F- 0.1115735E-05 0.1119462E-05 0.2122907E-01 4.0819 16 HPO4-- 0.4276732E-07 0.4378938E-07 0.4195256E-02 12.5714 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279074E+02 -.1080898E-01 -.8277993E+02 0.0000000E+00 2 H2O -.7155043E+01 0.2756720E+02 -.3472224E+02 0.0000000E+00 3 Cl- 0.2369352E-03 0.2369352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386727E+00 -.1166076E-02 0.1398388E+00 0.0000000E+00 5 HCO3- 0.1226987E-02 0.1226987E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382392E+00 0.1599577E-02 -.1398388E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2558258E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6559222E-02 0.5205735E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1417908E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4926548E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1746592E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8103733E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1145190E-01 0.6264925E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1261950E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6816000E-05 0.5559714E-06 0.6260029E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2174762E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1382E-13 Mass of aqueous solution: 0.497542E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0167900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 630.0 andradite 0.5594 -0.252 284.3 2.454 5.204 73.85 grossular 0.1354 -0.868 61.01 1.785 1.117 16.98 apatite-OH 0.9856E-02 -2.006 4.951 0.695 0.9064E-01 1.573 apatite-F 0.6260E-05 -5.203 0.3157E-02 -2.501 0.5780E-04 0.9863E-03 clinochlore 0.7091 -0.149 394.2 2.596 7.216 149.9 daphnite 0.2053 -0.688 146.5 2.166 2.682 44.39 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2306 -0.637 49.93 1.698 0.9141 15.26 hedenbergite 0.5980E-01 -1.223 14.84 1.171 0.2716 4.063 microcline 0.9321 -0.031 259.4 2.414 4.750 101.3 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2588 -0.587 278.9 2.446 5.107 96.36 tr.625ac.25prg.125 0.5296E-01 -1.276 45.27 1.656 0.8288 14.57 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.343051 g Volume = 2210.824183 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0167900 moles log = -1.7749 Original solution: 1000.0103000 g Original solution / Rock added: 59559.87 (Water/Rock Ratio), log = 4.7750 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.4904 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2305E+00 0.9720 0.1006E+01 0.1035E+01 CO2,gas 0.1448E-06 0.9913 0.6446E-06 0.6503E-06 CH4,gas 0.7661E+00 1.0002 0.3441E+01 0.3440E+01 H2,gas 0.3378E-02 1.0024 0.1521E-01 0.1517E-01 H2S,gas 0.1075E-05 0.9827 0.4742E-05 0.4826E-05 S2,gas 0.8130E-27 1.0000 0.3651E-26 0.3651E-26 CO,gas 0.5817E-12 1.0000 0.2612E-11 0.2612E-11 SO3,gas 0.5506E-47 1.0000 0.2472E-46 0.2472E-46 SO2,gas 0.3257E-26 1.0000 0.1463E-25 0.1463E-25 HF,gas 0.2665E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2187E-17 1.0000 0.9818E-17 0.9818E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.55 -7.89 -2.630 0.13471E+05 -6.191 3 CH4,gas 4.54 3.38 -1.16 -0.291 0.19845E+04 0.537 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.25 -7.02 -3.511 0.11992E+05 -5.324 6 S2,gas -7.34 -35.47 -28.14 -4.329 0.48042E+05 -26.438 7 CO,gas 3.21 -10.07 -13.28 -4.087 0.22679E+05 -11.583 8 SO3,gas 17.12 -31.18 -48.31 -12.076 0.82481E+05 -46.607 9 SO2,gas 0.83 -26.70 -27.53 -7.342 0.47013E+05 -25.835 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.52 -18.71 -9.353 0.31942E+05 -17.008 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80673E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93631E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.45 -2.41 -0.805 0.41227E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.45 -2.26 -0.753 0.38585E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65537E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.58 -2.48 -0.709 0.42376E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.58 -2.04 -0.582 0.34798E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82229E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.25 -3.01 -0.708 0.51349E+04 146 pyrrhotite -4.26 -6.52 -2.26 -0.753 0.38553E+04 147 pyrrhotiteFe0.875 -6.02 -7.92 -1.90 -0.698 0.32425E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22433E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.31 -4.33 -1.444 0.73955E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23235E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47103E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.52 -2.11 -0.702 0.35981E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -4.01 -3.03 -1.011 0.51789E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0167900 MOLES New total amount of reactant added: 0.0171900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8648E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0171900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4966E+00 Moles total = -.7155E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .9990239E-02 Osmotic coef. = 0.9191 True ionic strength = .2087357E-01 Chg. balance for total moles = -.8648E-10 Max. difference allowed = 0.2393E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91693E-10 -10.0377 0.76840E-10 -10.1144 0.83802E+00 -0.0767 2 H2O 0.99996E+00 0.0000 0.99996E+00 0.0000 3 Cl- 0.47955E-03 -3.3192 0.39937E-03 -3.3986 0.83281E+00 -0.0795 4 SO4-- 0.22059E-10 -10.6564 0.11330E-10 -10.9458 0.51361E+00 -0.2894 5 HCO3- 0.45031E-04 -4.3465 0.37559E-04 -4.4253 0.83407E+00 -0.0788 6 HS- 0.89225E-03 -3.0495 0.74319E-03 -3.1289 0.83294E+00 -0.0794 7 Al+++ 0.11042E-28 -28.9569 0.24876E-29 -29.6042 0.22528E+00 -0.6473 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14645E-06 -6.8343 0.74646E-07 -7.1270 0.50971E+00 -0.2927 10 Mg++ 0.22914E-10 -10.6399 0.11624E-10 -10.9346 0.50730E+00 -0.2947 11 Fe++ 0.63155E-13 -13.1996 0.32075E-13 -13.4938 0.50788E+00 -0.2942 12 K+ 0.16254E-03 -3.7890 0.13560E-03 -3.8677 0.83427E+00 -0.0787 13 Na+ 0.20627E-01 -1.6856 0.17175E-01 -1.7651 0.83265E+00 -0.0795 14 Mn++ 0.20293E-10 -10.6926 0.10315E-10 -10.9865 0.50831E+00 -0.2939 15 F- 0.11150E-05 -5.9527 0.92661E-06 -6.0331 0.83104E+00 -0.0804 16 HPO4-- 0.42715E-07 -7.3694 0.21942E-07 -7.6587 0.51369E+00 -0.2893 18 HSiO3- 0.10155E-01 -1.9933 0.84573E-02 -2.0728 0.83281E+00 -0.0795 19 Ca(HSiO3)+ 0.17229E-07 -7.7637 0.14377E-07 -7.8423 0.83446E+00 -0.0786 20 Mg(HSiO3)+ 0.33391E-11 -11.4764 0.27864E-11 -11.5550 0.83446E+00 -0.0786 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.68684E-16 -16.1631 0.57314E-16 -16.2417 0.83446E+00 -0.0786 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51476E-05 -5.2884 0.42790E-05 -5.3687 0.83126E+00 -0.0803 26 CH4,aq 0.24004E-02 -2.6197 0.23930E-02 -2.6210 0.99695E+00 -0.0013 27 C2H6,aq 0.84787E-10 -10.0717 0.84528E-10 -10.0730 0.99695E+00 -0.0013 28 C3H8,aq 0.69144E-16 -16.1602 0.68933E-16 -16.1616 0.99695E+00 -0.0013 30 ethanol,aq 0.31120E-17 -17.5070 0.31025E-17 -17.5083 0.99695E+00 -0.0013 31 CO,aq 0.17944E-14 -14.7461 0.17944E-14 -14.7461 0.10000E+01 0.0000 32 CO2,aq 0.61859E-08 -8.2086 0.61670E-08 -8.2099 0.99695E+00 -0.0013 33 CO3-2 0.83308E-04 -4.0793 0.42694E-04 -4.3696 0.51248E+00 -0.2903 34 CaCO3,aq 0.39961E-07 -7.3984 0.39961E-07 -7.3984 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.85762E-10 -10.0667 0.71565E-10 -10.1453 0.83446E+00 -0.0786 36 CaCl+ 0.57815E-10 -10.2380 0.48244E-10 -10.3166 0.83446E+00 -0.0786 37 CaCl2,aq 0.45775E-14 -14.3394 0.45775E-14 -14.3394 0.10000E+01 0.0000 38 CaF+ 0.12102E-11 -11.9171 0.10099E-11 -11.9957 0.83446E+00 -0.0786 39 CaOH+ 0.82966E-07 -7.0811 0.69231E-07 -7.1597 0.83446E+00 -0.0786 40 CaSO4,aq 0.26856E-15 -15.5710 0.26856E-15 -15.5710 0.10000E+01 0.0000 41 HCl,aq 0.56234E-14 -14.2500 0.56234E-14 -14.2500 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18310E-18 -18.7373 0.15249E-18 -18.8168 0.83281E+00 -0.0795 48 FeCl+ 0.24298E-16 -16.6144 0.20276E-16 -16.6930 0.83446E+00 -0.0786 51 FeF+ 0.18201E-17 -17.7399 0.15188E-17 -17.8185 0.83446E+00 -0.0786 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16283E-10 -10.7883 0.13587E-10 -10.8669 0.83446E+00 -0.0786 55 HFeO2- 0.34518E-07 -7.4620 0.28747E-07 -7.5414 0.83281E+00 -0.0795 56 FeO+ 0.11412E-16 -16.9426 0.95227E-17 -17.0212 0.83446E+00 -0.0786 58 FeO2- 0.39625E-09 -9.4020 0.33000E-09 -9.4815 0.83281E+00 -0.0795 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11617E-04 -4.9349 0.11582E-04 -4.9362 0.99695E+00 -0.0013 61 KCl,aq 0.98155E-09 -9.0081 0.98155E-09 -9.0081 0.10000E+01 0.0000 63 KOH,aq 0.75362E-06 -6.1228 0.75362E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.28627E-13 -13.5432 0.23841E-13 -13.6227 0.83281E+00 -0.0795 65 MgCO3,aq 0.15598E-11 -11.8069 0.15598E-11 -11.8069 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13647E-13 -13.8650 0.11388E-13 -13.9436 0.83446E+00 -0.0786 67 MgCl+ 0.81601E-14 -14.0883 0.68093E-14 -14.1669 0.83446E+00 -0.0786 68 MgF+ 0.69811E-15 -15.1561 0.58254E-15 -15.2347 0.83446E+00 -0.0786 69 MgOH+ 0.71493E-10 -10.1457 0.59658E-10 -10.2243 0.83446E+00 -0.0786 71 MnF+ 0.19293E-15 -15.7146 0.16099E-15 -15.7932 0.83446E+00 -0.0786 72 MnO,aq 0.18092E-08 -8.7425 0.18092E-08 -8.7425 0.10000E+01 0.0000 73 MnOH+ 0.48645E-09 -9.3130 0.40592E-09 -9.3916 0.83446E+00 -0.0786 74 MnO2-2 0.19841E-10 -10.7024 0.10168E-10 -10.9927 0.51248E+00 -0.2903 75 HMnO2- 0.20554E-09 -9.6871 0.17118E-09 -9.7665 0.83281E+00 -0.0795 78 MnCl+ 0.30401E-13 -13.5171 0.25368E-13 -13.5957 0.83446E+00 -0.0786 79 MnSO4,aq 0.33740E-19 -19.4719 0.33740E-19 -19.4719 0.10000E+01 0.0000 80 NaCl,aq 0.22732E-05 -5.6434 0.22732E-05 -5.6434 0.10000E+01 0.0000 81 NaF,aq 0.37259E-08 -8.4288 0.37259E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96030E-04 -4.0176 0.96030E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90451E-02 -2.0436 0.75188E-02 -2.1238 0.83126E+00 -0.0803 89 HPO3-2 0.15454E-14 -14.8110 0.79201E-15 -15.1013 0.51248E+00 -0.2903 91 H2PO3- 0.14654E-18 -18.8340 0.12204E-18 -18.9135 0.83281E+00 -0.0795 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37311E-10 -10.4282 0.31103E-10 -10.5072 0.83363E+00 -0.0790 94 PO4-3 0.98307E-09 -9.0074 0.23298E-09 -9.6327 0.23700E+00 -0.6253 98 HP2O7-3 0.87410E-18 -18.0584 0.19712E-18 -18.7053 0.22552E+00 -0.6468 99 P2O7-4 0.83039E-17 -17.0807 0.61285E-18 -18.2126 0.73803E-01 -1.1319 100 H2S,aq 0.17704E-06 -6.7519 0.17649E-06 -6.7533 0.99695E+00 -0.0013 101 S2-2 0.20619E-11 -11.6857 0.10567E-11 -11.9761 0.51248E+00 -0.2903 102 S3-2 0.42331E-19 -19.3733 0.21694E-19 -19.6637 0.51248E+00 -0.2903 107 SO3-2 0.32786E-16 -16.4843 0.17053E-16 -16.7682 0.52014E+00 -0.2839 108 HSO3- 0.98516E-19 -19.0065 0.82045E-19 -19.0859 0.83281E+00 -0.0795 109 HSO4- 0.10044E-17 -17.9981 0.83901E-18 -18.0762 0.83530E+00 -0.0782 111 S2O3-2 0.45837E-19 -19.3388 0.23491E-19 -19.6291 0.51248E+00 -0.2903 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9169287E-10 -.2175322E-01 -.2188623E+02 0.0000 2 H2O 0.1000000E+01 0.5550731E+02 0.9981699E+06 0.0000 3 Cl- 0.4795456E-03 0.4818198E-03 0.1705102E+02 6.7158 4 SO4-- 0.2205939E-10 -.2403283E-02 -.2304451E+03 9.2831 5 HCO3- 0.4503071E-04 0.2528763E-02 0.1540186E+03 5.6891 6 HS- 0.8922474E-03 0.3295707E-02 0.1087982E+03 6.9855 7 Al+++ 0.1104232E-28 0.5147712E-05 0.1386415E+00 0.7390 8 H4SiO4 0.6959458E-03 0.1320041E-01 0.1266465E+04 -3.1574 9 Ca++ 0.1464475E-06 0.2867480E-06 0.1147148E-01 13.1018 10 Mg++ 0.2291408E-10 0.9932727E-10 0.2410471E-05 9.2942 11 Fe++ 0.6315529E-13 0.3514489E-07 0.1959182E-02 6.7350 12 K+ 0.1625425E-03 0.1632971E-03 0.6373680E+01 6.2467 13 Na+ 0.2062713E-01 0.2307476E-01 0.5295235E+03 8.3493 14 Mn++ 0.2029320E-10 0.2541320E-08 0.1393622E-03 9.2423 15 F- 0.1114996E-05 0.1118723E-05 0.2121502E-01 4.0813 16 HPO4-- 0.4271536E-07 0.4373574E-07 0.4190111E-02 12.5701 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279070E+02 -.1080371E-01 -.8277989E+02 0.0000000E+00 2 H2O -.7154715E+01 0.2756763E+02 -.3472235E+02 0.0000000E+00 3 Cl- 0.2392952E-03 0.2392952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386746E+00 -.1193587E-02 0.1398682E+00 0.0000000E+00 5 HCO3- 0.1255907E-02 0.1255907E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382314E+00 0.1636809E-02 -.1398682E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2556605E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6555969E-02 0.5205735E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1424130E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4933076E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1745466E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8110130E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1146005E-01 0.6264917E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1262143E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6976000E-05 0.5556125E-06 0.6420387E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2172130E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.4219E-14 Mass of aqueous solution: 0.497550E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0171900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 630.0 andradite 0.5595 -0.252 284.3 2.454 5.205 73.87 grossular 0.1355 -0.868 61.03 1.786 1.117 16.98 apatite-OH 0.9856E-02 -2.006 4.951 0.695 0.9064E-01 1.573 apatite-F 0.6420E-05 -5.192 0.3238E-02 -2.490 0.5928E-04 0.1012E-02 clinochlore 0.7091 -0.149 394.1 2.596 7.216 149.9 daphnite 0.2053 -0.688 146.5 2.166 2.682 44.39 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2298 -0.639 49.76 1.697 0.9111 15.21 hedenbergite 0.5960E-01 -1.225 14.79 1.170 0.2707 4.050 microcline 0.9321 -0.031 259.5 2.414 4.750 101.3 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2587 -0.587 278.9 2.445 5.106 96.33 tr.625ac.25prg.125 0.5321E-01 -1.274 45.48 1.658 0.8327 14.64 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.343170 g Volume = 2210.825287 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0171900 moles log = -1.7647 Original solution: 1000.0103000 g Original solution / Rock added: 58173.96 (Water/Rock Ratio), log = 4.7647 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.5722 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2264E+00 0.9718 0.1006E+01 0.1035E+01 CO2,gas 0.1456E-06 0.9911 0.6598E-06 0.6657E-06 CH4,gas 0.7703E+00 1.0001 0.3522E+01 0.3522E+01 H2,gas 0.3318E-02 1.0024 0.1521E-01 0.1517E-01 H2S,gas 0.1080E-05 0.9824 0.4852E-05 0.4939E-05 S2,gas 0.8358E-27 1.0000 0.3821E-26 0.3821E-26 CO,gas 0.5848E-12 1.0000 0.2674E-11 0.2674E-11 SO3,gas 0.5532E-47 1.0000 0.2529E-46 0.2529E-46 SO2,gas 0.3273E-26 1.0000 0.1496E-25 0.1496E-25 HF,gas 0.2618E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2170E-17 1.0000 0.9923E-17 0.9923E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.54 -7.88 -2.627 0.13454E+05 -6.181 3 CH4,gas 4.54 3.39 -1.15 -0.288 0.19672E+04 0.547 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.24 -7.01 -3.507 0.11975E+05 -5.314 6 S2,gas -7.34 -35.45 -28.12 -4.326 0.48009E+05 -26.418 7 CO,gas 3.21 -10.06 -13.27 -4.084 0.22661E+05 -11.573 8 SO3,gas 17.12 -31.17 -48.30 -12.074 0.82464E+05 -46.597 9 SO2,gas 0.83 -26.69 -27.52 -7.340 0.46996E+05 -25.825 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.51 -18.70 -9.351 0.31934E+05 -17.003 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80672E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93631E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.44 -2.40 -0.801 0.41054E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.44 -2.25 -0.750 0.38412E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65536E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.57 -2.47 -0.706 0.42203E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.57 -2.03 -0.579 0.34625E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28619E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82229E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.23 -2.99 -0.703 0.51011E+04 146 pyrrhotite -4.26 -6.51 -2.25 -0.749 0.38384E+04 147 pyrrhotiteFe0.875 -6.02 -7.91 -1.89 -0.695 0.32256E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22432E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.30 -4.32 -1.440 0.73781E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23235E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47102E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.51 -2.10 -0.699 0.35812E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -4.00 -3.02 -1.008 0.51619E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0171900 MOLES New total amount of reactant added: 0.0175900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8648E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0175900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4967E+00 Moles total = -.7154E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .9956524E-02 Osmotic coef. = 0.9193 True ionic strength = .2089159E-01 Chg. balance for total moles = -.8648E-10 Max. difference allowed = 0.2417E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91764E-10 -10.0373 0.76896E-10 -10.1141 0.83797E+00 -0.0768 2 H2O 0.99996E+00 0.0000 0.99996E+00 0.0000 3 Cl- 0.48427E-03 -3.3149 0.40328E-03 -3.3944 0.83276E+00 -0.0795 4 SO4-- 0.22530E-10 -10.6472 0.11569E-10 -10.9367 0.51349E+00 -0.2895 5 HCO3- 0.46039E-04 -4.3369 0.38398E-04 -4.4157 0.83402E+00 -0.0788 6 HS- 0.91180E-03 -3.0401 0.75943E-03 -3.1195 0.83289E+00 -0.0794 7 Al+++ 0.11072E-28 -28.9558 0.24930E-29 -29.6033 0.22516E+00 -0.6475 8 H4SiO4 0.69595E-03 -3.1574 0.69595E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14669E-06 -6.8336 0.74754E-07 -7.1264 0.50959E+00 -0.2928 10 Mg++ 0.22953E-10 -10.6392 0.11641E-10 -10.9340 0.50718E+00 -0.2948 11 Fe++ 0.63262E-13 -13.1989 0.32122E-13 -13.4932 0.50776E+00 -0.2943 12 K+ 0.16267E-03 -3.7887 0.13570E-03 -3.8674 0.83423E+00 -0.0787 13 Na+ 0.20643E-01 -1.6852 0.17188E-01 -1.7648 0.83260E+00 -0.0796 14 Mn++ 0.20328E-10 -10.6919 0.10331E-10 -10.9859 0.50819E+00 -0.2940 15 F- 0.11143E-05 -5.9530 0.92594E-06 -6.0334 0.83099E+00 -0.0804 16 HPO4-- 0.42663E-07 -7.3699 0.21911E-07 -7.6593 0.51357E+00 -0.2894 18 HSiO3- 0.10148E-01 -1.9936 0.84512E-02 -2.0731 0.83276E+00 -0.0795 19 Ca(HSiO3)+ 0.17243E-07 -7.7634 0.14388E-07 -7.8420 0.83441E+00 -0.0786 20 Mg(HSiO3)+ 0.33417E-11 -11.4760 0.27884E-11 -11.5546 0.83441E+00 -0.0786 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.68738E-16 -16.1628 0.57356E-16 -16.2414 0.83441E+00 -0.0786 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51442E-05 -5.2887 0.42759E-05 -5.3690 0.83121E+00 -0.0803 26 CH4,aq 0.24557E-02 -2.6098 0.24483E-02 -2.6111 0.99696E+00 -0.0013 27 C2H6,aq 0.88744E-10 -10.0519 0.88474E-10 -10.0532 0.99696E+00 -0.0013 28 C3H8,aq 0.74041E-16 -16.1305 0.73816E-16 -16.1319 0.99696E+00 -0.0013 30 ethanol,aq 0.32573E-17 -17.4871 0.32473E-17 -17.4885 0.99696E+00 -0.0013 31 CO,aq 0.18358E-14 -14.7362 0.18358E-14 -14.7362 0.10000E+01 0.0000 32 CO2,aq 0.63286E-08 -8.1987 0.63093E-08 -8.2000 0.99696E+00 -0.0013 33 CO3-2 0.85127E-04 -4.0699 0.43616E-04 -4.3604 0.51237E+00 -0.2904 34 CaCO3,aq 0.40883E-07 -7.3885 0.40883E-07 -7.3885 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.87810E-10 -10.0565 0.73270E-10 -10.1351 0.83441E+00 -0.0786 36 CaCl+ 0.58469E-10 -10.2331 0.48787E-10 -10.3117 0.83441E+00 -0.0786 37 CaCl2,aq 0.46743E-14 -14.3303 0.46743E-14 -14.3303 0.10000E+01 0.0000 38 CaF+ 0.12111E-11 -11.9168 0.10106E-11 -11.9954 0.83441E+00 -0.0786 39 CaOH+ 0.83030E-07 -7.0808 0.69281E-07 -7.1594 0.83441E+00 -0.0786 40 CaSO4,aq 0.27463E-15 -15.5613 0.27463E-15 -15.5613 0.10000E+01 0.0000 41 HCl,aq 0.56825E-14 -14.2455 0.56825E-14 -14.2455 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18298E-18 -18.7376 0.15238E-18 -18.8171 0.83276E+00 -0.0795 48 FeCl+ 0.24573E-16 -16.6095 0.20504E-16 -16.6882 0.83441E+00 -0.0786 51 FeF+ 0.18215E-17 -17.7396 0.15199E-17 -17.8182 0.83441E+00 -0.0786 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16295E-10 -10.7879 0.13597E-10 -10.8666 0.83441E+00 -0.0786 55 HFeO2- 0.34495E-07 -7.4622 0.28726E-07 -7.5417 0.83276E+00 -0.0795 56 FeO+ 0.11421E-16 -16.9423 0.95296E-17 -17.0209 0.83441E+00 -0.0786 58 FeO2- 0.39598E-09 -9.4023 0.32976E-09 -9.4818 0.83276E+00 -0.0795 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11617E-04 -4.9349 0.11582E-04 -4.9362 0.99696E+00 -0.0013 61 KCl,aq 0.99186E-09 -9.0035 0.99186E-09 -9.0035 0.10000E+01 0.0000 63 KOH,aq 0.75362E-06 -6.1228 0.75362E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.29255E-13 -13.5338 0.24362E-13 -13.6133 0.83276E+00 -0.0795 65 MgCO3,aq 0.15958E-11 -11.7970 0.15958E-11 -11.7970 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13973E-13 -13.8547 0.11659E-13 -13.9333 0.83441E+00 -0.0786 67 MgCl+ 0.82524E-14 -14.0834 0.68859E-14 -14.1620 0.83441E+00 -0.0786 68 MgF+ 0.69865E-15 -15.1557 0.58296E-15 -15.2344 0.83441E+00 -0.0786 69 MgOH+ 0.71548E-10 -10.1454 0.59701E-10 -10.2240 0.83441E+00 -0.0786 71 MnF+ 0.19309E-15 -15.7142 0.16112E-15 -15.7929 0.83441E+00 -0.0786 72 MnO,aq 0.18092E-08 -8.7425 0.18092E-08 -8.7425 0.10000E+01 0.0000 73 MnOH+ 0.48684E-09 -9.3126 0.40623E-09 -9.3912 0.83441E+00 -0.0786 74 MnO2-2 0.19818E-10 -10.7029 0.10154E-10 -10.9934 0.51237E+00 -0.2904 75 HMnO2- 0.20542E-09 -9.6874 0.17106E-09 -9.7668 0.83276E+00 -0.0795 78 MnCl+ 0.30746E-13 -13.5122 0.25655E-13 -13.5908 0.83441E+00 -0.0786 79 MnSO4,aq 0.34504E-19 -19.4621 0.34504E-19 -19.4621 0.10000E+01 0.0000 80 NaCl,aq 0.22971E-05 -5.6388 0.22971E-05 -5.6388 0.10000E+01 0.0000 81 NaF,aq 0.37259E-08 -8.4288 0.37259E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96030E-04 -4.0176 0.96030E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90391E-02 -2.0439 0.75134E-02 -2.1242 0.83121E+00 -0.0803 89 HPO3-2 0.15436E-14 -14.8115 0.79087E-15 -15.1019 0.51237E+00 -0.2904 91 H2PO3- 0.14644E-18 -18.8343 0.12195E-18 -18.9138 0.83276E+00 -0.0795 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37286E-10 -10.4285 0.31081E-10 -10.5075 0.83358E+00 -0.0791 94 PO4-3 0.98142E-09 -9.0081 0.23248E-09 -9.6336 0.23688E+00 -0.6255 98 HP2O7-3 0.87266E-18 -18.0592 0.19670E-18 -18.7062 0.22540E+00 -0.6471 99 P2O7-4 0.82875E-17 -17.0816 0.61109E-18 -18.2139 0.73736E-01 -1.1323 100 H2S,aq 0.18103E-06 -6.7422 0.18048E-06 -6.7436 0.99696E+00 -0.0013 101 S2-2 0.21535E-11 -11.6669 0.11034E-11 -11.9573 0.51237E+00 -0.2904 102 S3-2 0.45211E-19 -19.3448 0.23165E-19 -19.6352 0.51237E+00 -0.2904 107 SO3-2 0.33485E-16 -16.4751 0.17413E-16 -16.7591 0.52003E+00 -0.2840 108 HSO3- 0.10068E-18 -18.9971 0.83839E-19 -19.0766 0.83276E+00 -0.0795 109 HSO4- 0.10264E-17 -17.9887 0.85734E-18 -18.0668 0.83525E+00 -0.0782 111 S2O3-2 0.47874E-19 -19.3199 0.24529E-19 -19.6103 0.51237E+00 -0.2904 Charge balance for all species = -.1740E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9176419E-10 -.2174230E-01 -.2187521E+02 0.0000 2 H2O 0.1000000E+01 0.5550737E+02 0.9981693E+06 0.0000 3 Cl- 0.4842664E-03 0.4865645E-03 0.1721890E+02 6.7197 4 SO4-- 0.2253038E-10 -.2458646E-02 -.2357534E+03 9.2915 5 HCO3- 0.4603928E-04 0.2586955E-02 0.1575627E+03 5.6984 6 HS- 0.9118012E-03 0.3370629E-02 0.1112714E+03 6.9946 7 Al+++ 0.1107209E-28 0.5144311E-05 0.1385496E+00 0.7390 8 H4SiO4 0.6959450E-03 0.1319368E-01 0.1265817E+04 -3.1574 9 Ca++ 0.1466935E-06 0.2879971E-06 0.1152143E-01 13.1018 10 Mg++ 0.2295265E-10 0.9946262E-10 0.2413752E-05 9.2942 11 Fe++ 0.6326161E-13 0.3512173E-07 0.1957888E-02 6.7350 12 K+ 0.1626689E-03 0.1634235E-03 0.6378605E+01 6.2467 13 Na+ 0.2064320E-01 0.2309085E-01 0.5298918E+03 8.3493 14 Mn++ 0.2032813E-10 0.2541671E-08 0.1393812E-03 9.2423 15 F- 0.1114258E-05 0.1117985E-05 0.2120098E-01 4.0807 16 HPO4-- 0.4266349E-07 0.4368220E-07 0.4184974E-02 12.5689 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279065E+02 -.1079844E-01 -.8277985E+02 0.0000000E+00 2 H2O -.7154388E+01 0.2756807E+02 -.3472246E+02 0.0000000E+00 3 Cl- 0.2416552E-03 0.2416552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386765E+00 -.1221102E-02 0.1398976E+00 0.0000000E+00 5 HCO3- 0.1284827E-02 0.1284827E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382236E+00 0.1674043E-02 -.1398976E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2554953E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6552719E-02 0.5205735E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1430355E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4939871E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1744342E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8116529E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1146821E-01 0.6264909E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1262336E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7136000E-05 0.5552541E-06 0.6580746E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2169503E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1909E-13 Mass of aqueous solution: 0.497558E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0175900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 630.0 andradite 0.5596 -0.252 284.4 2.454 5.206 73.88 grossular 0.1355 -0.868 61.04 1.786 1.117 16.98 apatite-OH 0.9856E-02 -2.006 4.951 0.695 0.9064E-01 1.573 apatite-F 0.6581E-05 -5.182 0.3319E-02 -2.479 0.6076E-04 0.1037E-02 clinochlore 0.7091 -0.149 394.1 2.596 7.215 149.9 daphnite 0.2053 -0.688 146.5 2.166 2.681 44.39 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2290 -0.640 49.60 1.695 0.9080 15.16 hedenbergite 0.5940E-01 -1.226 14.74 1.168 0.2698 4.036 microcline 0.9322 -0.031 259.5 2.414 4.750 101.4 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2586 -0.587 278.8 2.445 5.104 96.31 tr.625ac.25prg.125 0.5346E-01 -1.272 45.70 1.660 0.8366 14.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.343288 g Volume = 2210.826392 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0175900 moles log = -1.7547 Original solution: 1000.0103000 g Original solution / Rock added: 56851.07 (Water/Rock Ratio), log = 4.7547 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.6540 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2224E+00 0.9717 0.1006E+01 0.1035E+01 CO2,gas 0.1464E-06 0.9909 0.6750E-06 0.6812E-06 CH4,gas 0.7743E+00 1.0000 0.3604E+01 0.3604E+01 H2,gas 0.3259E-02 1.0025 0.1521E-01 0.1517E-01 H2S,gas 0.1085E-05 0.9821 0.4961E-05 0.5052E-05 S2,gas 0.8586E-27 1.0000 0.3996E-26 0.3996E-26 CO,gas 0.5878E-12 1.0000 0.2736E-11 0.2736E-11 SO3,gas 0.5558E-47 1.0000 0.2587E-46 0.2587E-46 SO2,gas 0.3288E-26 1.0000 0.1530E-25 0.1530E-25 HF,gas 0.2572E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2154E-17 1.0000 0.1003E-16 0.1003E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.72794E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.53 -7.87 -2.623 0.13437E+05 -6.171 3 CH4,gas 4.54 3.40 -1.14 -0.286 0.19503E+04 0.557 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.23 -7.00 -3.502 0.11958E+05 -5.304 6 S2,gas -7.34 -35.43 -28.10 -4.323 0.47975E+05 -26.398 7 CO,gas 3.21 -10.05 -13.26 -4.081 0.22644E+05 -11.563 8 SO3,gas 17.12 -31.16 -48.29 -12.072 0.82447E+05 -46.587 9 SO2,gas 0.83 -26.68 -27.51 -7.337 0.46980E+05 -25.815 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.51 -18.70 -9.349 0.31926E+05 -16.999 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80671E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93631E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.43 -2.39 -0.798 0.40885E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.43 -2.24 -0.747 0.38243E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65536E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.56 -2.46 -0.703 0.42034E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.56 -2.02 -0.577 0.34456E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82229E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.22 -2.97 -0.698 0.50679E+04 146 pyrrhotite -4.26 -6.50 -2.24 -0.746 0.38218E+04 147 pyrrhotiteFe0.875 -6.02 -7.90 -1.88 -0.691 0.32090E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22432E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.29 -4.31 -1.437 0.73612E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23235E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47102E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.50 -2.09 -0.696 0.35646E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.99 -3.01 -1.004 0.51453E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0175900 MOLES New total amount of reactant added: 0.0179900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8647E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0179900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4967E+00 Moles total = -.7154E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .9922805E-02 Osmotic coef. = 0.9195 True ionic strength = .2090960E-01 Chg. balance for total moles = -.8647E-10 Max. difference allowed = 0.2440E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91836E-10 -10.0370 0.76951E-10 -10.1138 0.83792E+00 -0.0768 2 H2O 0.99995E+00 0.0000 0.99995E+00 0.0000 3 Cl- 0.48899E-03 -3.3107 0.40719E-03 -3.3902 0.83271E+00 -0.0795 4 SO4-- 0.23001E-10 -10.6383 0.11808E-10 -10.9278 0.51338E+00 -0.2896 5 HCO3- 0.47047E-04 -4.3275 0.39236E-04 -4.4063 0.83397E+00 -0.0788 6 HS- 0.93135E-03 -3.0309 0.77567E-03 -3.1103 0.83284E+00 -0.0794 7 Al+++ 0.11102E-28 -28.9546 0.24984E-29 -29.6023 0.22504E+00 -0.6477 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14694E-06 -6.8329 0.74862E-07 -7.1257 0.50947E+00 -0.2929 10 Mg++ 0.22991E-10 -10.6384 0.11658E-10 -10.9334 0.50706E+00 -0.2949 11 Fe++ 0.63368E-13 -13.1981 0.32168E-13 -13.4926 0.50764E+00 -0.2944 12 K+ 0.16280E-03 -3.7884 0.13580E-03 -3.8671 0.83418E+00 -0.0787 13 Na+ 0.20659E-01 -1.6849 0.17200E-01 -1.7645 0.83255E+00 -0.0796 14 Mn++ 0.20363E-10 -10.6912 0.10346E-10 -10.9852 0.50807E+00 -0.2941 15 F- 0.11135E-05 -5.9533 0.92527E-06 -6.0337 0.83094E+00 -0.0804 16 HPO4-- 0.42612E-07 -7.3705 0.21879E-07 -7.6600 0.51345E+00 -0.2895 18 HSiO3- 0.10142E-01 -1.9939 0.84451E-02 -2.0734 0.83271E+00 -0.0795 19 Ca(HSiO3)+ 0.17256E-07 -7.7631 0.14398E-07 -7.8417 0.83436E+00 -0.0786 20 Mg(HSiO3)+ 0.33443E-11 -11.4757 0.27904E-11 -11.5543 0.83436E+00 -0.0786 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.68792E-16 -16.1625 0.57397E-16 -16.2411 0.83436E+00 -0.0786 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51408E-05 -5.2890 0.42728E-05 -5.3693 0.83116E+00 -0.0803 26 CH4,aq 0.25111E-02 -2.6001 0.25035E-02 -2.6015 0.99697E+00 -0.0013 27 C2H6,aq 0.92792E-10 -10.0325 0.92511E-10 -10.0338 0.99697E+00 -0.0013 28 C3H8,aq 0.79164E-16 -16.1015 0.78924E-16 -16.1028 0.99697E+00 -0.0013 30 ethanol,aq 0.34058E-17 -17.4678 0.33955E-17 -17.4691 0.99697E+00 -0.0013 31 CO,aq 0.18772E-14 -14.7265 0.18772E-14 -14.7265 0.10000E+01 0.0000 32 CO2,aq 0.64713E-08 -8.1890 0.64517E-08 -8.1903 0.99697E+00 -0.0013 33 CO3-2 0.86941E-04 -4.0608 0.44536E-04 -4.3513 0.51225E+00 -0.2905 34 CaCO3,aq 0.41805E-07 -7.3788 0.41805E-07 -7.3788 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.89861E-10 -10.0464 0.74976E-10 -10.1251 0.83436E+00 -0.0786 36 CaCl+ 0.59124E-10 -10.2282 0.49331E-10 -10.3069 0.83436E+00 -0.0786 37 CaCl2,aq 0.47722E-14 -14.3213 0.47722E-14 -14.3213 0.10000E+01 0.0000 38 CaF+ 0.12121E-11 -11.9165 0.10113E-11 -11.9951 0.83436E+00 -0.0786 39 CaOH+ 0.83095E-07 -7.0804 0.69331E-07 -7.1591 0.83436E+00 -0.0786 40 CaSO4,aq 0.28070E-15 -15.5518 0.28070E-15 -15.5518 0.10000E+01 0.0000 41 HCl,aq 0.57417E-14 -14.2410 0.57417E-14 -14.2410 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18286E-18 -18.7379 0.15227E-18 -18.8174 0.83271E+00 -0.0795 48 FeCl+ 0.24848E-16 -16.6047 0.20732E-16 -16.6833 0.83436E+00 -0.0786 51 FeF+ 0.18229E-17 -17.7392 0.15210E-17 -17.8179 0.83436E+00 -0.0786 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16308E-10 -10.7876 0.13607E-10 -10.8662 0.83436E+00 -0.0786 55 HFeO2- 0.34472E-07 -7.4625 0.28705E-07 -7.5420 0.83271E+00 -0.0795 56 FeO+ 0.11430E-16 -16.9420 0.95365E-17 -17.0206 0.83436E+00 -0.0786 58 FeO2- 0.39572E-09 -9.4026 0.32952E-09 -9.4821 0.83271E+00 -0.0795 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11617E-04 -4.9349 0.11582E-04 -4.9362 0.99697E+00 -0.0013 61 KCl,aq 0.10022E-08 -8.9990 0.10022E-08 -8.9990 0.10000E+01 0.0000 63 KOH,aq 0.75362E-06 -6.1228 0.75362E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.29882E-13 -13.5246 0.24883E-13 -13.6041 0.83271E+00 -0.0795 65 MgCO3,aq 0.16318E-11 -11.7873 0.16318E-11 -11.7873 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14299E-13 -13.8447 0.11931E-13 -13.9233 0.83436E+00 -0.0786 67 MgCl+ 0.83448E-14 -14.0786 0.69626E-14 -14.1572 0.83436E+00 -0.0786 68 MgF+ 0.69920E-15 -15.1554 0.58338E-15 -15.2340 0.83436E+00 -0.0786 69 MgOH+ 0.71604E-10 -10.1451 0.59744E-10 -10.2237 0.83436E+00 -0.0786 71 MnF+ 0.19325E-15 -15.7139 0.16124E-15 -15.7925 0.83436E+00 -0.0786 72 MnO,aq 0.18093E-08 -8.7425 0.18093E-08 -8.7425 0.10000E+01 0.0000 73 MnOH+ 0.48724E-09 -9.3123 0.40654E-09 -9.3909 0.83436E+00 -0.0786 74 MnO2-2 0.19795E-10 -10.7034 0.10140E-10 -10.9940 0.51225E+00 -0.2905 75 HMnO2- 0.20529E-09 -9.6876 0.17095E-09 -9.7671 0.83271E+00 -0.0795 78 MnCl+ 0.31092E-13 -13.5074 0.25942E-13 -13.5860 0.83436E+00 -0.0786 79 MnSO4,aq 0.35268E-19 -19.4526 0.35268E-19 -19.4526 0.10000E+01 0.0000 80 NaCl,aq 0.23210E-05 -5.6343 0.23210E-05 -5.6343 0.10000E+01 0.0000 81 NaF,aq 0.37259E-08 -8.4288 0.37259E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96030E-04 -4.0176 0.96030E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90331E-02 -2.0442 0.75080E-02 -2.1245 0.83116E+00 -0.0803 89 HPO3-2 0.15417E-14 -14.8120 0.78973E-15 -15.1025 0.51225E+00 -0.2905 91 H2PO3- 0.14634E-18 -18.8346 0.12186E-18 -18.9141 0.83271E+00 -0.0795 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37261E-10 -10.4287 0.31058E-10 -10.5078 0.83353E+00 -0.0791 94 PO4-3 0.97978E-09 -9.0089 0.23198E-09 -9.6346 0.23677E+00 -0.6257 98 HP2O7-3 0.87123E-18 -18.0599 0.19627E-18 -18.7071 0.22528E+00 -0.6473 99 P2O7-4 0.82712E-17 -17.0824 0.60933E-18 -18.2152 0.73669E-01 -1.1327 100 H2S,aq 0.18504E-06 -6.7327 0.18447E-06 -6.7341 0.99697E+00 -0.0013 101 S2-2 0.22471E-11 -11.6484 0.11511E-11 -11.9389 0.51225E+00 -0.2905 102 S3-2 0.48220E-19 -19.3168 0.24700E-19 -19.6073 0.51225E+00 -0.2905 107 SO3-2 0.34184E-16 -16.4662 0.17773E-16 -16.7502 0.51991E+00 -0.2841 108 HSO3- 0.10283E-18 -18.9879 0.85631E-19 -19.0674 0.83271E+00 -0.0795 109 HSO4- 0.10485E-17 -17.9794 0.87568E-18 -18.0577 0.83520E+00 -0.0782 111 S2O3-2 0.49955E-19 -19.3014 0.25589E-19 -19.5919 0.51225E+00 -0.2905 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9183553E-10 -.2173138E-01 -.2186419E+02 0.0000 2 H2O 0.1000000E+01 0.5550742E+02 0.9981687E+06 0.0000 3 Cl- 0.4889870E-03 0.4913090E-03 0.1738678E+02 6.7236 4 SO4-- 0.2300083E-10 -.2514014E-02 -.2410621E+03 9.2997 5 HCO3- 0.4704660E-04 0.2645146E-02 0.1611066E+03 5.7075 6 HS- 0.9313544E-03 0.3445553E-02 0.1137446E+03 7.0035 7 Al+++ 0.1110193E-28 0.5140913E-05 0.1384579E+00 0.7390 8 H4SiO4 0.6959442E-03 0.1318695E-01 0.1265169E+04 -3.1574 9 Ca++ 0.1469399E-06 0.2892465E-06 0.1157139E-01 13.1018 10 Mg++ 0.2299127E-10 0.9959528E-10 0.2416968E-05 9.2942 11 Fe++ 0.6336805E-13 0.3509860E-07 0.1956596E-02 6.7350 12 K+ 0.1627954E-03 0.1635500E-03 0.6383531E+01 6.2467 13 Na+ 0.2065928E-01 0.2310694E-01 0.5302603E+03 8.3493 14 Mn++ 0.2036311E-10 0.2542023E-08 0.1394003E-03 9.2423 15 F- 0.1113520E-05 0.1117248E-05 0.2118697E-01 4.0801 16 HPO4-- 0.4261170E-07 0.4362874E-07 0.4179846E-02 12.5676 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279061E+02 -.1079318E-01 -.8277982E+02 0.0000000E+00 2 H2O -.7154060E+01 0.2756850E+02 -.3472256E+02 0.0000000E+00 3 Cl- 0.2440152E-03 0.2440152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386784E+00 -.1248618E-02 0.1399270E+00 0.0000000E+00 5 HCO3- 0.1313747E-02 0.1313747E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382158E+00 0.1711280E-02 -.1399270E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2553303E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6549474E-02 0.5205735E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1436581E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4946532E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1743219E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8122929E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1147637E-01 0.6264901E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1262530E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7296000E-05 0.5548960E-06 0.6741104E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2166880E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.4857E-16 Mass of aqueous solution: 0.497566E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0179900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 630.0 andradite 0.5597 -0.252 284.4 2.454 5.207 73.90 grossular 0.1355 -0.868 61.05 1.786 1.118 16.99 apatite-OH 0.9856E-02 -2.006 4.951 0.695 0.9064E-01 1.573 apatite-F 0.6741E-05 -5.171 0.3400E-02 -2.469 0.6224E-04 0.1062E-02 clinochlore 0.7091 -0.149 394.1 2.596 7.215 149.9 daphnite 0.2053 -0.688 146.5 2.166 2.681 44.38 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2283 -0.642 49.43 1.694 0.9050 15.11 hedenbergite 0.5920E-01 -1.228 14.69 1.167 0.2689 4.023 microcline 0.9322 -0.030 259.5 2.414 4.750 101.4 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2586 -0.587 278.7 2.445 5.103 96.29 tr.625ac.25prg.125 0.5371E-01 -1.270 45.91 1.662 0.8405 14.78 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.343406 g Volume = 2210.827496 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0179900 moles log = -1.7450 Original solution: 1000.0103000 g Original solution / Rock added: 55587.01 (Water/Rock Ratio), log = 4.7450 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.7358 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2186E+00 0.9716 0.1006E+01 0.1035E+01 CO2,gas 0.1471E-06 0.9907 0.6903E-06 0.6967E-06 CH4,gas 0.7782E+00 0.9999 0.3685E+01 0.3685E+01 H2,gas 0.3203E-02 1.0025 0.1521E-01 0.1517E-01 H2S,gas 0.1091E-05 0.9818 0.5071E-05 0.5165E-05 S2,gas 0.8815E-27 1.0000 0.4175E-26 0.4175E-26 CO,gas 0.5907E-12 1.0000 0.2797E-11 0.2797E-11 SO3,gas 0.5583E-47 1.0000 0.2644E-46 0.2644E-46 SO2,gas 0.3303E-26 1.0000 0.1564E-25 0.1564E-25 HF,gas 0.2527E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2139E-17 1.0000 0.1013E-16 0.1013E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.52 -7.86 -2.620 0.13421E+05 -6.161 3 CH4,gas 4.54 3.41 -1.13 -0.283 0.19338E+04 0.566 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.22 -6.99 -3.497 0.11942E+05 -5.295 6 S2,gas -7.34 -35.41 -28.08 -4.320 0.47943E+05 -26.379 7 CO,gas 3.21 -10.04 -13.25 -4.078 0.22628E+05 -11.553 8 SO3,gas 17.12 -31.16 -48.28 -12.069 0.82431E+05 -46.578 9 SO2,gas 0.83 -26.67 -27.50 -7.335 0.46964E+05 -25.806 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.50 -18.69 -9.347 0.31918E+05 -16.994 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80671E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93631E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.42 -2.38 -0.795 0.40720E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.42 -2.23 -0.743 0.38077E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65536E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.55 -2.45 -0.701 0.41868E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.55 -2.01 -0.574 0.34291E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82228E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.20 -2.95 -0.694 0.50355E+04 146 pyrrhotite -4.26 -6.49 -2.23 -0.743 0.38056E+04 147 pyrrhotiteFe0.875 -6.02 -7.89 -1.87 -0.688 0.31928E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22432E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.28 -4.30 -1.434 0.73446E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23234E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47101E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.49 -2.08 -0.693 0.35484E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.98 -3.00 -1.001 0.51291E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0179900 MOLES New total amount of reactant added: 0.0183900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8647E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0183900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4967E+00 Moles total = -.7154E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .9889081E-02 Osmotic coef. = 0.9197 True ionic strength = .2092762E-01 Chg. balance for total moles = -.8647E-10 Max. difference allowed = 0.2464E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91907E-10 -10.0367 0.77007E-10 -10.1135 0.83788E+00 -0.0768 2 H2O 0.99995E+00 0.0000 0.99995E+00 0.0000 3 Cl- 0.49371E-03 -3.3065 0.41109E-03 -3.3861 0.83266E+00 -0.0795 4 SO4-- 0.23471E-10 -10.6295 0.12047E-10 -10.9191 0.51326E+00 -0.2897 5 HCO3- 0.48053E-04 -4.3183 0.40072E-04 -4.3972 0.83392E+00 -0.0789 6 HS- 0.95091E-03 -3.0219 0.79190E-03 -3.1013 0.83279E+00 -0.0795 7 Al+++ 0.11132E-28 -28.9534 0.25038E-29 -29.6014 0.22493E+00 -0.6480 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14719E-06 -6.8321 0.74970E-07 -7.1251 0.50935E+00 -0.2930 10 Mg++ 0.23030E-10 -10.6377 0.11675E-10 -10.9327 0.50694E+00 -0.2950 11 Fe++ 0.63475E-13 -13.1974 0.32214E-13 -13.4919 0.50752E+00 -0.2945 12 K+ 0.16292E-03 -3.7880 0.13590E-03 -3.8668 0.83413E+00 -0.0788 13 Na+ 0.20675E-01 -1.6845 0.17212E-01 -1.7642 0.83250E+00 -0.0796 14 Mn++ 0.20398E-10 -10.6904 0.10361E-10 -10.9846 0.50795E+00 -0.2942 15 F- 0.11128E-05 -5.9536 0.92460E-06 -6.0340 0.83089E+00 -0.0805 16 HPO4-- 0.42560E-07 -7.3710 0.21847E-07 -7.6606 0.51333E+00 -0.2896 18 HSiO3- 0.10135E-01 -1.9942 0.84390E-02 -2.0737 0.83266E+00 -0.0795 19 Ca(HSiO3)+ 0.17270E-07 -7.7627 0.14408E-07 -7.8414 0.83431E+00 -0.0787 20 Mg(HSiO3)+ 0.33469E-11 -11.4754 0.27924E-11 -11.5540 0.83431E+00 -0.0787 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.68845E-16 -16.1621 0.57439E-16 -16.2408 0.83431E+00 -0.0787 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51374E-05 -5.2893 0.42697E-05 -5.3696 0.83111E+00 -0.0803 26 CH4,aq 0.25665E-02 -2.5907 0.25587E-02 -2.5920 0.99698E+00 -0.0013 27 C2H6,aq 0.96931E-10 -10.0135 0.96638E-10 -10.0149 0.99698E+00 -0.0013 28 C3H8,aq 0.84519E-16 -16.0730 0.84264E-16 -16.0744 0.99698E+00 -0.0013 30 ethanol,aq 0.35577E-17 -17.4488 0.35470E-17 -17.4501 0.99698E+00 -0.0013 31 CO,aq 0.19186E-14 -14.7170 0.19186E-14 -14.7170 0.10000E+01 0.0000 32 CO2,aq 0.66140E-08 -8.1795 0.65940E-08 -8.1809 0.99698E+00 -0.0013 33 CO3-2 0.88752E-04 -4.0518 0.45453E-04 -4.3424 0.51213E+00 -0.2906 34 CaCO3,aq 0.42727E-07 -7.3693 0.42727E-07 -7.3693 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.91915E-10 -10.0366 0.76686E-10 -10.1153 0.83431E+00 -0.0787 36 CaCl+ 0.59781E-10 -10.2234 0.49876E-10 -10.3021 0.83431E+00 -0.0787 37 CaCl2,aq 0.48712E-14 -14.3124 0.48712E-14 -14.3124 0.10000E+01 0.0000 38 CaF+ 0.12130E-11 -11.9161 0.10120E-11 -11.9948 0.83431E+00 -0.0787 39 CaOH+ 0.83160E-07 -7.0801 0.69381E-07 -7.1588 0.83431E+00 -0.0787 40 CaSO4,aq 0.28679E-15 -15.5424 0.28679E-15 -15.5424 0.10000E+01 0.0000 41 HCl,aq 0.58010E-14 -14.2365 0.58010E-14 -14.2365 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18273E-18 -18.7382 0.15216E-18 -18.8177 0.83266E+00 -0.0795 48 FeCl+ 0.25124E-16 -16.5999 0.20962E-16 -16.6786 0.83431E+00 -0.0787 51 FeF+ 0.18244E-17 -17.7389 0.15221E-17 -17.8176 0.83431E+00 -0.0787 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16321E-10 -10.7873 0.13617E-10 -10.8659 0.83431E+00 -0.0787 55 HFeO2- 0.34449E-07 -7.4628 0.28685E-07 -7.5424 0.83266E+00 -0.0795 56 FeO+ 0.11439E-16 -16.9416 0.95433E-17 -17.0203 0.83431E+00 -0.0787 58 FeO2- 0.39546E-09 -9.4029 0.32928E-09 -9.4824 0.83266E+00 -0.0795 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11617E-04 -4.9349 0.11582E-04 -4.9362 0.99698E+00 -0.0013 61 KCl,aq 0.10125E-08 -8.9946 0.10125E-08 -8.9946 0.10000E+01 0.0000 63 KOH,aq 0.75361E-06 -6.1229 0.75361E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.30509E-13 -13.5156 0.25404E-13 -13.5951 0.83266E+00 -0.0795 65 MgCO3,aq 0.16678E-11 -11.7779 0.16678E-11 -11.7779 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14626E-13 -13.8349 0.12203E-13 -13.9135 0.83431E+00 -0.0787 67 MgCl+ 0.84375E-14 -14.0738 0.70396E-14 -14.1525 0.83431E+00 -0.0787 68 MgF+ 0.69974E-15 -15.1551 0.58380E-15 -15.2337 0.83431E+00 -0.0787 69 MgOH+ 0.71660E-10 -10.1447 0.59787E-10 -10.2234 0.83431E+00 -0.0787 71 MnF+ 0.19341E-15 -15.7135 0.16136E-15 -15.7922 0.83431E+00 -0.0787 72 MnO,aq 0.18094E-08 -8.7425 0.18094E-08 -8.7425 0.10000E+01 0.0000 73 MnOH+ 0.48764E-09 -9.3119 0.40685E-09 -9.3906 0.83431E+00 -0.0787 74 MnO2-2 0.19772E-10 -10.7040 0.10126E-10 -10.9946 0.51213E+00 -0.2906 75 HMnO2- 0.20516E-09 -9.6879 0.17083E-09 -9.7674 0.83266E+00 -0.0795 78 MnCl+ 0.31438E-13 -13.5025 0.26229E-13 -13.5812 0.83431E+00 -0.0787 79 MnSO4,aq 0.36034E-19 -19.4433 0.36034E-19 -19.4433 0.10000E+01 0.0000 80 NaCl,aq 0.23450E-05 -5.6299 0.23450E-05 -5.6299 0.10000E+01 0.0000 81 NaF,aq 0.37259E-08 -8.4288 0.37259E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96029E-04 -4.0176 0.96029E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90272E-02 -2.0444 0.75025E-02 -2.1248 0.83111E+00 -0.0803 89 HPO3-2 0.15398E-14 -14.8125 0.78859E-15 -15.1032 0.51213E+00 -0.2906 91 H2PO3- 0.14625E-18 -18.8349 0.12177E-18 -18.9144 0.83266E+00 -0.0795 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37236E-10 -10.4290 0.31036E-10 -10.5081 0.83348E+00 -0.0791 94 PO4-3 0.97814E-09 -9.0096 0.23148E-09 -9.6355 0.23665E+00 -0.6259 98 HP2O7-3 0.86980E-18 -18.0606 0.19585E-18 -18.7081 0.22516E+00 -0.6475 99 P2O7-4 0.82548E-17 -17.0833 0.60757E-18 -18.2164 0.73602E-01 -1.1331 100 H2S,aq 0.18904E-06 -6.7234 0.18847E-06 -6.7248 0.99698E+00 -0.0013 101 S2-2 0.23427E-11 -11.6303 0.11998E-11 -11.9209 0.51213E+00 -0.2906 102 S3-2 0.51361E-19 -19.2894 0.26303E-19 -19.5800 0.51213E+00 -0.2906 107 SO3-2 0.34882E-16 -16.4574 0.18132E-16 -16.7416 0.51980E+00 -0.2842 108 HSO3- 0.10499E-18 -18.9788 0.87424E-19 -19.0584 0.83266E+00 -0.0795 109 HSO4- 0.10705E-17 -17.9704 0.89401E-18 -18.0487 0.83516E+00 -0.0782 111 S2O3-2 0.52080E-19 -19.2833 0.26672E-19 -19.5739 0.51213E+00 -0.2906 Charge balance for all species = -.1740E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9190689E-10 -.2172048E-01 -.2185319E+02 0.0000 2 H2O 0.1000000E+01 0.5550748E+02 0.9981681E+06 0.0000 3 Cl- 0.4937074E-03 0.4960535E-03 0.1755465E+02 6.7274 4 SO4-- 0.2347075E-10 -.2569385E-02 -.2463711E+03 9.3078 5 HCO3- 0.4805268E-04 0.2703335E-02 0.1646504E+03 5.7163 6 HS- 0.9509070E-03 0.3520481E-02 0.1162179E+03 7.0121 7 Al+++ 0.1113183E-28 0.5137520E-05 0.1383663E+00 0.7390 8 H4SiO4 0.6959435E-03 0.1318023E-01 0.1264523E+04 -3.1574 9 Ca++ 0.1471865E-06 0.2904964E-06 0.1162137E-01 13.1018 10 Mg++ 0.2302993E-10 0.9972883E-10 0.2420205E-05 9.2942 11 Fe++ 0.6347462E-13 0.3507550E-07 0.1955305E-02 6.7350 12 K+ 0.1629219E-03 0.1636765E-03 0.6388458E+01 6.2467 13 Na+ 0.2067536E-01 0.2312304E-01 0.5306288E+03 8.3493 14 Mn++ 0.2039813E-10 0.2542376E-08 0.1394194E-03 9.2424 15 F- 0.1112784E-05 0.1116511E-05 0.2117297E-01 4.0794 16 HPO4-- 0.4256001E-07 0.4357538E-07 0.4174727E-02 12.5663 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279057E+02 -.1078793E-01 -.8277978E+02 0.0000000E+00 2 H2O -.7153733E+01 0.2756893E+02 -.3472267E+02 0.0000000E+00 3 Cl- 0.2463752E-03 0.2463752E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386803E+00 -.1276138E-02 0.1399565E+00 0.0000000E+00 5 HCO3- 0.1342667E-02 0.1342667E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382080E+00 0.1748520E-02 -.1399565E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2551655E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6546232E-02 0.5205736E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1442810E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4953238E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1742097E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8129332E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1148453E-01 0.6264892E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1262723E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7456000E-05 0.5545384E-06 0.6901462E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2164261E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1607E-13 Mass of aqueous solution: 0.497574E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0183900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 629.9 andradite 0.5598 -0.252 284.5 2.454 5.208 73.91 grossular 0.1356 -0.868 61.06 1.786 1.118 16.99 apatite-OH 0.9856E-02 -2.006 4.951 0.695 0.9063E-01 1.573 apatite-F 0.6901E-05 -5.161 0.3480E-02 -2.458 0.6372E-04 0.1087E-02 clinochlore 0.7090 -0.149 394.1 2.596 7.215 149.9 daphnite 0.2053 -0.688 146.5 2.166 2.681 44.38 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2275 -0.643 49.27 1.693 0.9019 15.06 hedenbergite 0.5900E-01 -1.229 14.64 1.165 0.2680 4.009 microcline 0.9322 -0.030 259.5 2.414 4.750 101.4 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2585 -0.588 278.7 2.445 5.102 96.26 tr.625ac.25prg.125 0.5396E-01 -1.268 46.13 1.664 0.8444 14.85 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.343524 g Volume = 2210.828600 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0183900 moles log = -1.7354 Original solution: 1000.0103000 g Original solution / Rock added: 54377.94 (Water/Rock Ratio), log = 4.7354 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.8176 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2149E+00 0.9714 0.1006E+01 0.1036E+01 CO2,gas 0.1478E-06 0.9905 0.7055E-06 0.7122E-06 CH4,gas 0.7819E+00 0.9998 0.3766E+01 0.3767E+01 H2,gas 0.3148E-02 1.0026 0.1521E-01 0.1517E-01 H2S,gas 0.1096E-05 0.9815 0.5181E-05 0.5279E-05 S2,gas 0.9045E-27 1.0000 0.4358E-26 0.4358E-26 CO,gas 0.5935E-12 1.0000 0.2859E-11 0.2859E-11 SO3,gas 0.5607E-47 1.0000 0.2701E-46 0.2701E-46 SO2,gas 0.3317E-26 1.0000 0.1598E-25 0.1598E-25 HF,gas 0.2484E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2125E-17 1.0000 0.1024E-16 0.1024E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.51 -7.85 -2.617 0.13404E+05 -6.152 3 CH4,gas 4.54 3.42 -1.12 -0.281 0.19176E+04 0.576 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.21 -6.98 -3.492 0.11926E+05 -5.286 6 S2,gas -7.34 -35.40 -28.06 -4.317 0.47911E+05 -26.361 7 CO,gas 3.21 -10.03 -13.24 -4.075 0.22612E+05 -11.544 8 SO3,gas 17.12 -31.15 -48.27 -12.067 0.82415E+05 -46.568 9 SO2,gas 0.83 -26.66 -27.50 -7.332 0.46948E+05 -25.796 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.50 -18.69 -9.344 0.31911E+05 -16.990 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80670E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93631E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.41 -2.38 -0.792 0.40558E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.41 -2.22 -0.740 0.37916E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65536E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.54 -2.44 -0.698 0.41706E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.54 -2.00 -0.571 0.34129E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82228E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.18 -2.93 -0.690 0.50037E+04 146 pyrrhotite -4.26 -6.48 -2.22 -0.740 0.37897E+04 147 pyrrhotiteFe0.875 -6.02 -7.88 -1.86 -0.684 0.31769E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22432E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.27 -4.29 -1.431 0.73284E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23234E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47101E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.48 -2.07 -0.690 0.35325E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.97 -2.99 -0.998 0.51132E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0183900 MOLES New total amount of reactant added: 0.0187900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8646E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0187900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4967E+00 Moles total = -.7153E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .9855352E-02 Osmotic coef. = 0.9199 True ionic strength = .2094564E-01 Chg. balance for total moles = -.8646E-10 Max. difference allowed = 0.2487E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91978E-10 -10.0363 0.77062E-10 -10.1132 0.83783E+00 -0.0768 2 H2O 0.99995E+00 0.0000 0.99995E+00 0.0000 3 Cl- 0.49843E-03 -3.3024 0.41500E-03 -3.3820 0.83261E+00 -0.0796 4 SO4-- 0.23940E-10 -10.6209 0.12285E-10 -10.9106 0.51314E+00 -0.2898 5 HCO3- 0.49058E-04 -4.3093 0.40908E-04 -4.3882 0.83388E+00 -0.0789 6 HS- 0.97046E-03 -3.0130 0.80814E-03 -3.0925 0.83274E+00 -0.0795 7 Al+++ 0.11162E-28 -28.9523 0.25093E-29 -29.6005 0.22481E+00 -0.6482 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14743E-06 -6.8314 0.75078E-07 -7.1245 0.50924E+00 -0.2931 10 Mg++ 0.23069E-10 -10.6370 0.11692E-10 -10.9321 0.50682E+00 -0.2951 11 Fe++ 0.63581E-13 -13.1967 0.32261E-13 -13.4913 0.50740E+00 -0.2947 12 K+ 0.16305E-03 -3.7877 0.13600E-03 -3.8665 0.83408E+00 -0.0788 13 Na+ 0.20691E-01 -1.6842 0.17225E-01 -1.7638 0.83246E+00 -0.0796 14 Mn++ 0.20433E-10 -10.6897 0.10377E-10 -10.9839 0.50783E+00 -0.2943 15 F- 0.11120E-05 -5.9539 0.92393E-06 -6.0344 0.83084E+00 -0.0805 16 HPO4-- 0.42508E-07 -7.3715 0.21816E-07 -7.6612 0.51322E+00 -0.2897 18 HSiO3- 0.10128E-01 -1.9945 0.84329E-02 -2.0740 0.83261E+00 -0.0796 19 Ca(HSiO3)+ 0.17283E-07 -7.7624 0.14419E-07 -7.8411 0.83427E+00 -0.0787 20 Mg(HSiO3)+ 0.33496E-11 -11.4750 0.27944E-11 -11.5537 0.83427E+00 -0.0787 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.68899E-16 -16.1618 0.57480E-16 -16.2405 0.83427E+00 -0.0787 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51340E-05 -5.2895 0.42666E-05 -5.3699 0.83106E+00 -0.0804 26 CH4,aq 0.26219E-02 -2.5814 0.26140E-02 -2.5827 0.99699E+00 -0.0013 27 C2H6,aq 0.10116E-09 -9.9950 0.10085E-09 -9.9963 0.99699E+00 -0.0013 28 C3H8,aq 0.90111E-16 -16.0452 0.89840E-16 -16.0465 0.99699E+00 -0.0013 30 ethanol,aq 0.37129E-17 -17.4303 0.37018E-17 -17.4316 0.99699E+00 -0.0013 31 CO,aq 0.19600E-14 -14.7077 0.19600E-14 -14.7077 0.10000E+01 0.0000 32 CO2,aq 0.67567E-08 -8.1703 0.67364E-08 -8.1716 0.99699E+00 -0.0013 33 CO3-2 0.90558E-04 -4.0431 0.46367E-04 -4.3338 0.51201E+00 -0.2907 34 CaCO3,aq 0.43650E-07 -7.3600 0.43650E-07 -7.3600 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.93972E-10 -10.0270 0.78398E-10 -10.1057 0.83427E+00 -0.0787 36 CaCl+ 0.60439E-10 -10.2187 0.50422E-10 -10.2974 0.83427E+00 -0.0787 37 CaCl2,aq 0.49714E-14 -14.3035 0.49714E-14 -14.3035 0.10000E+01 0.0000 38 CaF+ 0.12140E-11 -11.9158 0.10128E-11 -11.9945 0.83427E+00 -0.0787 39 CaOH+ 0.83225E-07 -7.0797 0.69431E-07 -7.1584 0.83427E+00 -0.0787 40 CaSO4,aq 0.29288E-15 -15.5333 0.29288E-15 -15.5333 0.10000E+01 0.0000 41 HCl,aq 0.58603E-14 -14.2321 0.58603E-14 -14.2321 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18261E-18 -18.7385 0.15205E-18 -18.8180 0.83261E+00 -0.0796 48 FeCl+ 0.25401E-16 -16.5951 0.21191E-16 -16.6738 0.83427E+00 -0.0787 51 FeF+ 0.18258E-17 -17.7386 0.15232E-17 -17.8172 0.83427E+00 -0.0787 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16333E-10 -10.7869 0.13626E-10 -10.8656 0.83427E+00 -0.0787 55 HFeO2- 0.34426E-07 -7.4631 0.28664E-07 -7.5427 0.83261E+00 -0.0796 56 FeO+ 0.11447E-16 -16.9413 0.95502E-17 -17.0200 0.83427E+00 -0.0787 58 FeO2- 0.39520E-09 -9.4032 0.32905E-09 -9.4827 0.83261E+00 -0.0796 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11617E-04 -4.9349 0.11582E-04 -4.9362 0.99699E+00 -0.0013 61 KCl,aq 0.10229E-08 -8.9902 0.10229E-08 -8.9902 0.10000E+01 0.0000 63 KOH,aq 0.75361E-06 -6.1229 0.75361E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.31136E-13 -13.5067 0.25925E-13 -13.5863 0.83261E+00 -0.0796 65 MgCO3,aq 0.17038E-11 -11.7686 0.17038E-11 -11.7686 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14953E-13 -13.8253 0.12475E-13 -13.9040 0.83427E+00 -0.0787 67 MgCl+ 0.85305E-14 -14.0690 0.71167E-14 -14.1477 0.83427E+00 -0.0787 68 MgF+ 0.70029E-15 -15.1547 0.58422E-15 -15.2334 0.83427E+00 -0.0787 69 MgOH+ 0.71716E-10 -10.1444 0.59830E-10 -10.2231 0.83427E+00 -0.0787 71 MnF+ 0.19357E-15 -15.7132 0.16148E-15 -15.7919 0.83427E+00 -0.0787 72 MnO,aq 0.18094E-08 -8.7425 0.18094E-08 -8.7425 0.10000E+01 0.0000 73 MnOH+ 0.48804E-09 -9.3115 0.40715E-09 -9.3902 0.83427E+00 -0.0787 74 MnO2-2 0.19748E-10 -10.7045 0.10111E-10 -10.9952 0.51201E+00 -0.2907 75 HMnO2- 0.20503E-09 -9.6882 0.17071E-09 -9.7677 0.83261E+00 -0.0796 78 MnCl+ 0.31786E-13 -13.4978 0.26518E-13 -13.5765 0.83427E+00 -0.0787 79 MnSO4,aq 0.36801E-19 -19.4341 0.36801E-19 -19.4341 0.10000E+01 0.0000 80 NaCl,aq 0.23689E-05 -5.6254 0.23689E-05 -5.6254 0.10000E+01 0.0000 81 NaF,aq 0.37259E-08 -8.4288 0.37259E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96029E-04 -4.0176 0.96029E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90212E-02 -2.0447 0.74971E-02 -2.1251 0.83106E+00 -0.0804 89 HPO3-2 0.15380E-14 -14.8131 0.78745E-15 -15.1038 0.51201E+00 -0.2907 91 H2PO3- 0.14615E-18 -18.8352 0.12169E-18 -18.9148 0.83261E+00 -0.0796 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37212E-10 -10.4293 0.31013E-10 -10.5084 0.83343E+00 -0.0791 94 PO4-3 0.97650E-09 -9.0103 0.23098E-09 -9.6364 0.23653E+00 -0.6261 98 HP2O7-3 0.86838E-18 -18.0613 0.19542E-18 -18.7090 0.22504E+00 -0.6477 99 P2O7-4 0.82386E-17 -17.0841 0.60582E-18 -18.2177 0.73535E-01 -1.1335 100 H2S,aq 0.19306E-06 -6.7143 0.19248E-06 -6.7156 0.99699E+00 -0.0013 101 S2-2 0.24403E-11 -11.6126 0.12495E-11 -11.9033 0.51201E+00 -0.2907 102 S3-2 0.54637E-19 -19.2625 0.27975E-19 -19.5532 0.51201E+00 -0.2907 107 SO3-2 0.35580E-16 -16.4488 0.18490E-16 -16.7331 0.51969E+00 -0.2843 108 HSO3- 0.10715E-18 -18.9700 0.89216E-19 -19.0496 0.83261E+00 -0.0796 109 HSO4- 0.10925E-17 -17.9616 0.91234E-18 -18.0398 0.83511E+00 -0.0783 111 S2O3-2 0.54250E-19 -19.2656 0.27777E-19 -19.5563 0.51201E+00 -0.2907 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9197826E-10 -.2170959E-01 -.2184220E+02 0.0000 2 H2O 0.1000000E+01 0.5550753E+02 0.9981675E+06 0.0000 3 Cl- 0.4984277E-03 0.5007977E-03 0.1772251E+02 6.7312 4 SO4-- 0.2394014E-10 -.2624760E-02 -.2516804E+03 9.3157 5 HCO3- 0.4905752E-04 0.2761522E-02 0.1681941E+03 5.7250 6 HS- 0.9704590E-03 0.3595412E-02 0.1186914E+03 7.0206 7 Al+++ 0.1116180E-28 0.5134130E-05 0.1382748E+00 0.7390 8 H4SiO4 0.6959427E-03 0.1317352E-01 0.1263876E+04 -3.1574 9 Ca++ 0.1474335E-06 0.2917466E-06 0.1167137E-01 13.1018 10 Mg++ 0.2306864E-10 0.9986237E-10 0.2423442E-05 9.2942 11 Fe++ 0.6358131E-13 0.3505243E-07 0.1954015E-02 6.7350 12 K+ 0.1630484E-03 0.1638031E-03 0.6393386E+01 6.2467 13 Na+ 0.2069145E-01 0.2313914E-01 0.5309974E+03 8.3493 14 Mn++ 0.2043319E-10 0.2542728E-08 0.1394385E-03 9.2424 15 F- 0.1112048E-05 0.1115776E-05 0.2115898E-01 4.0788 16 HPO4-- 0.4250840E-07 0.4352211E-07 0.4169617E-02 12.5651 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279052E+02 -.1078267E-01 -.8277974E+02 0.0000000E+00 2 H2O -.7153405E+01 0.2756937E+02 -.3472277E+02 0.0000000E+00 3 Cl- 0.2487352E-03 0.2487352E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386822E+00 -.1303660E-02 0.1399859E+00 0.0000000E+00 5 HCO3- 0.1371587E-02 0.1371587E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1382001E+00 0.1785762E-02 -.1399859E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2550009E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6542994E-02 0.5205736E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1449041E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4959944E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1740977E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8135736E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1149270E-01 0.6264884E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1262917E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7616000E-05 0.5541812E-06 0.7061819E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2161647E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.5204E-14 Mass of aqueous solution: 0.497582E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0187900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 629.9 andradite 0.5599 -0.252 284.6 2.454 5.209 73.93 grossular 0.1356 -0.868 61.08 1.786 1.118 16.99 apatite-OH 0.9856E-02 -2.006 4.951 0.695 0.9063E-01 1.573 apatite-F 0.7062E-05 -5.151 0.3561E-02 -2.448 0.6520E-04 0.1113E-02 clinochlore 0.7090 -0.149 394.1 2.596 7.215 149.9 daphnite 0.2053 -0.688 146.5 2.166 2.681 44.38 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2267 -0.644 49.10 1.691 0.8989 15.01 hedenbergite 0.5880E-01 -1.231 14.59 1.164 0.2671 3.996 microcline 0.9323 -0.030 259.5 2.414 4.750 101.4 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2585 -0.588 278.6 2.445 5.101 96.24 tr.625ac.25prg.125 0.5421E-01 -1.266 46.34 1.666 0.8483 14.91 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.343642 g Volume = 2210.829705 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0187900 moles log = -1.7261 Original solution: 1000.0103000 g Original solution / Rock added: 53220.35 (Water/Rock Ratio), log = 4.7261 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.8995 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2114E+00 0.9713 0.1006E+01 0.1036E+01 CO2,gas 0.1485E-06 0.9903 0.7207E-06 0.7278E-06 CH4,gas 0.7855E+00 0.9997 0.3848E+01 0.3849E+01 H2,gas 0.3095E-02 1.0026 0.1521E-01 0.1517E-01 H2S,gas 0.1101E-05 0.9812 0.5291E-05 0.5393E-05 S2,gas 0.9276E-27 1.0000 0.4545E-26 0.4545E-26 CO,gas 0.5962E-12 1.0000 0.2921E-11 0.2921E-11 SO3,gas 0.5630E-47 1.0000 0.2759E-46 0.2759E-46 SO2,gas 0.3331E-26 1.0000 0.1632E-25 0.1632E-25 HF,gas 0.2443E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2111E-17 1.0000 0.1034E-16 0.1034E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.50 -7.84 -2.614 0.13389E+05 -6.142 3 CH4,gas 4.54 3.43 -1.11 -0.278 0.19018E+04 0.585 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.21 -6.98 -3.488 0.11910E+05 -5.276 6 S2,gas -7.34 -35.38 -28.04 -4.314 0.47880E+05 -26.342 7 CO,gas 3.21 -10.02 -13.23 -4.072 0.22596E+05 -11.534 8 SO3,gas 17.12 -31.14 -48.26 -12.065 0.82400E+05 -46.559 9 SO2,gas 0.83 -26.65 -27.49 -7.330 0.46932E+05 -25.787 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.50 -18.68 -9.342 0.31903E+05 -16.985 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80669E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93631E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.40 -2.37 -0.789 0.40399E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.40 -2.21 -0.737 0.37757E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65535E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.54 -2.43 -0.695 0.41548E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.54 -1.99 -0.568 0.33970E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82228E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.16 -2.91 -0.685 0.49725E+04 146 pyrrhotite -4.26 -6.47 -2.21 -0.737 0.37741E+04 147 pyrrhotiteFe0.875 -6.02 -7.87 -1.85 -0.681 0.31613E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22431E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.26 -4.28 -1.428 0.73125E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23234E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47100E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77497E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.47 -2.06 -0.687 0.35169E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.96 -2.99 -0.995 0.50975E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0187900 MOLES New total amount of reactant added: 0.0191900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8646E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0191900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4967E+00 Moles total = -.7153E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .9821618E-02 Osmotic coef. = 0.9201 True ionic strength = .2096366E-01 Chg. balance for total moles = -.8646E-10 Max. difference allowed = 0.2511E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92050E-10 -10.0360 0.77118E-10 -10.1128 0.83779E+00 -0.0769 2 H2O 0.99995E+00 0.0000 0.99995E+00 0.0000 3 Cl- 0.50315E-03 -3.2983 0.41890E-03 -3.3779 0.83256E+00 -0.0796 4 SO4-- 0.24409E-10 -10.6125 0.12522E-10 -10.9023 0.51302E+00 -0.2899 5 HCO3- 0.50061E-04 -4.3005 0.41742E-04 -4.3794 0.83383E+00 -0.0789 6 HS- 0.99001E-03 -3.0044 0.82437E-03 -3.0839 0.83269E+00 -0.0795 7 Al+++ 0.11192E-28 -28.9511 0.25147E-29 -29.5995 0.22469E+00 -0.6484 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14768E-06 -6.8307 0.75187E-07 -7.1239 0.50912E+00 -0.2932 10 Mg++ 0.23107E-10 -10.6362 0.11709E-10 -10.9315 0.50670E+00 -0.2952 11 Fe++ 0.63688E-13 -13.1959 0.32308E-13 -13.4907 0.50728E+00 -0.2948 12 K+ 0.16317E-03 -3.7873 0.13609E-03 -3.8662 0.83403E+00 -0.0788 13 Na+ 0.20708E-01 -1.6839 0.17237E-01 -1.7635 0.83241E+00 -0.0797 14 Mn++ 0.20468E-10 -10.6889 0.10392E-10 -10.9833 0.50771E+00 -0.2944 15 F- 0.11113E-05 -5.9542 0.92326E-06 -6.0347 0.83079E+00 -0.0805 16 HPO4-- 0.42457E-07 -7.3721 0.21785E-07 -7.6619 0.51310E+00 -0.2898 18 HSiO3- 0.10122E-01 -1.9948 0.84269E-02 -2.0743 0.83256E+00 -0.0796 19 Ca(HSiO3)+ 0.17297E-07 -7.7620 0.14429E-07 -7.8408 0.83422E+00 -0.0787 20 Mg(HSiO3)+ 0.33522E-11 -11.4747 0.27964E-11 -11.5534 0.83422E+00 -0.0787 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.68953E-16 -16.1614 0.57522E-16 -16.2402 0.83422E+00 -0.0787 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51306E-05 -5.2898 0.42636E-05 -5.3702 0.83101E+00 -0.0804 26 CH4,aq 0.26772E-02 -2.5723 0.26692E-02 -2.5736 0.99700E+00 -0.0013 27 C2H6,aq 0.10548E-09 -9.9768 0.10516E-09 -9.9781 0.99700E+00 -0.0013 28 C3H8,aq 0.95945E-16 -16.0180 0.95657E-16 -16.0193 0.99700E+00 -0.0013 30 ethanol,aq 0.38715E-17 -17.4121 0.38599E-17 -17.4134 0.99700E+00 -0.0013 31 CO,aq 0.20015E-14 -14.6987 0.20015E-14 -14.6987 0.10000E+01 0.0000 32 CO2,aq 0.68995E-08 -8.1612 0.68787E-08 -8.1625 0.99700E+00 -0.0013 33 CO3-2 0.92360E-04 -4.0345 0.47279E-04 -4.3253 0.51189E+00 -0.2908 34 CaCO3,aq 0.44572E-07 -7.3509 0.44572E-07 -7.3509 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.96033E-10 -10.0176 0.80113E-10 -10.0963 0.83422E+00 -0.0787 36 CaCl+ 0.61100E-10 -10.2140 0.50970E-10 -10.2927 0.83422E+00 -0.0787 37 CaCl2,aq 0.50727E-14 -14.2948 0.50727E-14 -14.2948 0.10000E+01 0.0000 38 CaF+ 0.12149E-11 -11.9155 0.10135E-11 -11.9942 0.83422E+00 -0.0787 39 CaOH+ 0.83289E-07 -7.0794 0.69481E-07 -7.1581 0.83422E+00 -0.0787 40 CaSO4,aq 0.29898E-15 -15.5244 0.29898E-15 -15.5244 0.10000E+01 0.0000 41 HCl,aq 0.59197E-14 -14.2277 0.59197E-14 -14.2277 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18249E-18 -18.7388 0.15194E-18 -18.8183 0.83256E+00 -0.0796 48 FeCl+ 0.25679E-16 -16.5904 0.21422E-16 -16.6691 0.83422E+00 -0.0787 51 FeF+ 0.18272E-17 -17.7382 0.15243E-17 -17.8169 0.83422E+00 -0.0787 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16346E-10 -10.7866 0.13636E-10 -10.8653 0.83422E+00 -0.0787 55 HFeO2- 0.34404E-07 -7.4634 0.28643E-07 -7.5430 0.83256E+00 -0.0796 56 FeO+ 0.11456E-16 -16.9410 0.95571E-17 -17.0197 0.83422E+00 -0.0787 58 FeO2- 0.39494E-09 -9.4035 0.32881E-09 -9.4831 0.83256E+00 -0.0796 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11617E-04 -4.9349 0.11582E-04 -4.9362 0.99700E+00 -0.0013 61 KCl,aq 0.10333E-08 -8.9858 0.10333E-08 -8.9858 0.10000E+01 0.0000 63 KOH,aq 0.75361E-06 -6.1229 0.75361E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.31764E-13 -13.4981 0.26445E-13 -13.5777 0.83256E+00 -0.0796 65 MgCO3,aq 0.17398E-11 -11.7595 0.17398E-11 -11.7595 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15281E-13 -13.8158 0.12748E-13 -13.8946 0.83422E+00 -0.0787 67 MgCl+ 0.86237E-14 -14.0643 0.71940E-14 -14.1430 0.83422E+00 -0.0787 68 MgF+ 0.70083E-15 -15.1544 0.58465E-15 -15.2331 0.83422E+00 -0.0787 69 MgOH+ 0.71772E-10 -10.1440 0.59873E-10 -10.2228 0.83422E+00 -0.0787 71 MnF+ 0.19372E-15 -15.7128 0.16161E-15 -15.7915 0.83422E+00 -0.0787 72 MnO,aq 0.18095E-08 -8.7424 0.18095E-08 -8.7424 0.10000E+01 0.0000 73 MnOH+ 0.48844E-09 -9.3112 0.40746E-09 -9.3899 0.83422E+00 -0.0787 74 MnO2-2 0.19725E-10 -10.7050 0.10097E-10 -10.9958 0.51189E+00 -0.2908 75 HMnO2- 0.20490E-09 -9.6885 0.17060E-09 -9.7680 0.83256E+00 -0.0796 78 MnCl+ 0.32134E-13 -13.4930 0.26807E-13 -13.5718 0.83422E+00 -0.0787 79 MnSO4,aq 0.37568E-19 -19.4252 0.37568E-19 -19.4252 0.10000E+01 0.0000 80 NaCl,aq 0.23929E-05 -5.6211 0.23929E-05 -5.6211 0.10000E+01 0.0000 81 NaF,aq 0.37258E-08 -8.4288 0.37258E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96029E-04 -4.0176 0.96029E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90152E-02 -2.0450 0.74917E-02 -2.1254 0.83101E+00 -0.0804 89 HPO3-2 0.15361E-14 -14.8136 0.78632E-15 -15.1044 0.51189E+00 -0.2908 91 H2PO3- 0.14605E-18 -18.8355 0.12160E-18 -18.9151 0.83256E+00 -0.0796 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37187E-10 -10.4296 0.30991E-10 -10.5088 0.83338E+00 -0.0792 94 PO4-3 0.97487E-09 -9.0111 0.23048E-09 -9.6374 0.23642E+00 -0.6263 98 HP2O7-3 0.86695E-18 -18.0620 0.19500E-18 -18.7100 0.22493E+00 -0.6480 99 P2O7-4 0.82223E-17 -17.0850 0.60408E-18 -18.2189 0.73468E-01 -1.1339 100 H2S,aq 0.19707E-06 -6.7054 0.19648E-06 -6.7067 0.99700E+00 -0.0013 101 S2-2 0.25399E-11 -11.5952 0.13002E-11 -11.8860 0.51189E+00 -0.2908 102 S3-2 0.58051E-19 -19.2362 0.29716E-19 -19.5270 0.51189E+00 -0.2908 107 SO3-2 0.36276E-16 -16.4404 0.18848E-16 -16.7247 0.51957E+00 -0.2844 108 HSO3- 0.10931E-18 -18.9613 0.91008E-19 -19.0409 0.83256E+00 -0.0796 109 HSO4- 0.11145E-17 -17.9529 0.93066E-18 -18.0312 0.83506E+00 -0.0783 111 S2O3-2 0.56464E-19 -19.2482 0.28904E-19 -19.5390 0.51189E+00 -0.2908 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9204966E-10 -.2169871E-01 -.2183121E+02 0.0000 2 H2O 0.1000000E+01 0.5550759E+02 0.9981669E+06 0.0000 3 Cl- 0.5031479E-03 0.5055419E-03 0.1789037E+02 6.7350 4 SO4-- 0.2440899E-10 -.2680139E-02 -.2569901E+03 9.3234 5 HCO3- 0.5006112E-04 0.2819707E-02 0.1717377E+03 5.7334 6 HS- 0.9900105E-03 0.3670347E-02 0.1211649E+03 7.0290 7 Al+++ 0.1119183E-28 0.5130744E-05 0.1381834E+00 0.7390 8 H4SiO4 0.6959419E-03 0.1316681E-01 0.1263231E+04 -3.1574 9 Ca++ 0.1476807E-06 0.2929973E-06 0.1172138E-01 13.1018 10 Mg++ 0.2310739E-10 0.9999592E-10 0.2426678E-05 9.2942 11 Fe++ 0.6368812E-13 0.3502938E-07 0.1952727E-02 6.7350 12 K+ 0.1631750E-03 0.1639296E-03 0.6398316E+01 6.2467 13 Na+ 0.2070753E-01 0.2315525E-01 0.5313661E+03 8.3493 14 Mn++ 0.2046830E-10 0.2543081E-08 0.1394577E-03 9.2424 15 F- 0.1111314E-05 0.1115041E-05 0.2114502E-01 4.0782 16 HPO4-- 0.4245688E-07 0.4346893E-07 0.4164516E-02 12.5638 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279048E+02 -.1077743E-01 -.8277970E+02 0.0000000E+00 2 H2O -.7153078E+01 0.2756980E+02 -.3472288E+02 0.0000000E+00 3 Cl- 0.2510952E-03 0.2510952E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386842E+00 -.1331185E-02 0.1400153E+00 0.0000000E+00 5 HCO3- 0.1400507E-02 0.1400507E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1381923E+00 0.1823007E-02 -.1400153E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2548365E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6539760E-02 0.5205736E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1455274E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4966649E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1739857E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8142142E-04 0.1061489E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1150087E-01 0.6264876E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1263111E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7776000E-05 0.5538244E-06 0.7222176E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2159038E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.7556E-14 Mass of aqueous solution: 0.497590E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0191900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 629.9 andradite 0.5601 -0.252 284.6 2.454 5.210 73.94 grossular 0.1356 -0.868 61.09 1.786 1.118 17.00 apatite-OH 0.9855E-02 -2.006 4.951 0.695 0.9063E-01 1.573 apatite-F 0.7222E-05 -5.141 0.3642E-02 -2.439 0.6668E-04 0.1138E-02 clinochlore 0.7090 -0.149 394.1 2.596 7.214 149.9 daphnite 0.2053 -0.688 146.4 2.166 2.681 44.38 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2260 -0.646 48.93 1.690 0.8958 14.96 hedenbergite 0.5860E-01 -1.232 14.54 1.163 0.2662 3.982 microcline 0.9323 -0.030 259.5 2.414 4.751 101.4 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2584 -0.588 278.5 2.445 5.099 96.22 tr.625ac.25prg.125 0.5446E-01 -1.264 46.55 1.668 0.8523 14.98 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.343759 g Volume = 2210.830809 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0191900 moles log = -1.7169 Original solution: 1000.0103000 g Original solution / Rock added: 52111.01 (Water/Rock Ratio), log = 4.7169 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 4.9813 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2079E+00 0.9711 0.1006E+01 0.1036E+01 CO2,gas 0.1492E-06 0.9902 0.7360E-06 0.7433E-06 CH4,gas 0.7890E+00 0.9996 0.3929E+01 0.3930E+01 H2,gas 0.3044E-02 1.0027 0.1521E-01 0.1517E-01 H2S,gas 0.1105E-05 0.9809 0.5401E-05 0.5507E-05 S2,gas 0.9508E-27 1.0000 0.4736E-26 0.4736E-26 CO,gas 0.5988E-12 1.0000 0.2983E-11 0.2983E-11 SO3,gas 0.5653E-47 1.0000 0.2816E-46 0.2816E-46 SO2,gas 0.3344E-26 1.0000 0.1666E-25 0.1666E-25 HF,gas 0.2403E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2097E-17 1.0000 0.1045E-16 0.1045E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.49 -7.83 -2.611 0.13373E+05 -6.133 3 CH4,gas 4.54 3.44 -1.10 -0.276 0.18862E+04 0.594 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.20 -6.97 -3.483 0.11895E+05 -5.268 6 S2,gas -7.34 -35.36 -28.02 -4.311 0.47849E+05 -26.325 7 CO,gas 3.21 -10.01 -13.22 -4.069 0.22580E+05 -11.525 8 SO3,gas 17.12 -31.13 -48.25 -12.062 0.82384E+05 -46.550 9 SO2,gas 0.83 -26.65 -27.48 -7.327 0.46917E+05 -25.778 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.49 -18.68 -9.340 0.31896E+05 -16.981 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80668E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93632E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.39 -2.36 -0.786 0.40244E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.39 -2.20 -0.734 0.37602E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65535E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.53 -2.42 -0.693 0.41393E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.53 -1.98 -0.566 0.33815E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82228E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.14 -2.89 -0.681 0.49420E+04 146 pyrrhotite -4.26 -6.46 -2.20 -0.734 0.37588E+04 147 pyrrhotiteFe0.875 -6.02 -7.86 -1.84 -0.678 0.31461E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22431E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.25 -4.27 -1.425 0.72970E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23233E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47100E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.46 -2.05 -0.684 0.35016E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.95 -2.98 -0.992 0.50822E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0191900 MOLES New total amount of reactant added: 0.0195900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8646E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0195900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4967E+00 Moles total = -.7153E+01 kg total = -.1289E+00 Activity = 1.0000 Stoichiometric ionic strength = .9787880E-02 Osmotic coef. = 0.9203 True ionic strength = .2098168E-01 Chg. balance for total moles = -.8646E-10 Max. difference allowed = 0.2535E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92121E-10 -10.0356 0.77173E-10 -10.1125 0.83774E+00 -0.0769 2 H2O 0.99995E+00 0.0000 0.99995E+00 0.0000 3 Cl- 0.50787E-03 -3.2942 0.42281E-03 -3.3739 0.83251E+00 -0.0796 4 SO4-- 0.24877E-10 -10.6042 0.12760E-10 -10.8942 0.51291E+00 -0.2900 5 HCO3- 0.51063E-04 -4.2919 0.42576E-04 -4.3708 0.83378E+00 -0.0789 6 HS- 0.10096E-02 -2.9959 0.84060E-03 -3.0754 0.83264E+00 -0.0795 7 Al+++ 0.11222E-28 -28.9499 0.25201E-29 -29.5986 0.22457E+00 -0.6486 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14793E-06 -6.8299 0.75295E-07 -7.1232 0.50900E+00 -0.2933 10 Mg++ 0.23146E-10 -10.6355 0.11725E-10 -10.9309 0.50658E+00 -0.2954 11 Fe++ 0.63795E-13 -13.1952 0.32354E-13 -13.4901 0.50716E+00 -0.2949 12 K+ 0.16330E-03 -3.7870 0.13619E-03 -3.8659 0.83398E+00 -0.0788 13 Na+ 0.20724E-01 -1.6835 0.17249E-01 -1.7632 0.83236E+00 -0.0797 14 Mn++ 0.20503E-10 -10.6882 0.10407E-10 -10.9827 0.50759E+00 -0.2945 15 F- 0.11106E-05 -5.9545 0.92260E-06 -6.0350 0.83074E+00 -0.0805 16 HPO4-- 0.42405E-07 -7.3726 0.21753E-07 -7.6625 0.51298E+00 -0.2899 18 HSiO3- 0.10115E-01 -1.9950 0.84208E-02 -2.0746 0.83251E+00 -0.0796 19 Ca(HSiO3)+ 0.17310E-07 -7.7617 0.14440E-07 -7.8404 0.83417E+00 -0.0787 20 Mg(HSiO3)+ 0.33548E-11 -11.4743 0.27984E-11 -11.5531 0.83417E+00 -0.0787 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.69007E-16 -16.1611 0.57563E-16 -16.2399 0.83417E+00 -0.0787 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51272E-05 -5.2901 0.42605E-05 -5.3705 0.83096E+00 -0.0804 26 CH4,aq 0.27326E-02 -2.5634 0.27244E-02 -2.5647 0.99701E+00 -0.0013 27 C2H6,aq 0.10989E-09 -9.9590 0.10956E-09 -9.9603 0.99701E+00 -0.0013 28 C3H8,aq 0.10203E-15 -15.9913 0.10172E-15 -15.9926 0.99701E+00 -0.0013 30 ethanol,aq 0.40334E-17 -17.3943 0.40213E-17 -17.3956 0.99701E+00 -0.0013 31 CO,aq 0.20429E-14 -14.6898 0.20429E-14 -14.6898 0.10000E+01 0.0000 32 CO2,aq 0.70422E-08 -8.1523 0.70211E-08 -8.1536 0.99701E+00 -0.0013 33 CO3-2 0.94158E-04 -4.0261 0.48188E-04 -4.3171 0.51178E+00 -0.2909 34 CaCO3,aq 0.45495E-07 -7.3420 0.45495E-07 -7.3420 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.98097E-10 -10.0083 0.81830E-10 -10.0871 0.83417E+00 -0.0787 36 CaCl+ 0.61762E-10 -10.2093 0.51520E-10 -10.2880 0.83417E+00 -0.0787 37 CaCl2,aq 0.51751E-14 -14.2861 0.51751E-14 -14.2861 0.10000E+01 0.0000 38 CaF+ 0.12159E-11 -11.9151 0.10142E-11 -11.9939 0.83417E+00 -0.0787 39 CaOH+ 0.83354E-07 -7.0791 0.69531E-07 -7.1578 0.83417E+00 -0.0787 40 CaSO4,aq 0.30508E-15 -15.5156 0.30508E-15 -15.5156 0.10000E+01 0.0000 41 HCl,aq 0.59792E-14 -14.2234 0.59792E-14 -14.2234 0.10000E+01 0.0000 45 HF,aq 0.48742E-12 -12.3121 0.48742E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18237E-18 -18.7390 0.15183E-18 -18.8187 0.83251E+00 -0.0796 48 FeCl+ 0.25957E-16 -16.5857 0.21652E-16 -16.6645 0.83417E+00 -0.0787 51 FeF+ 0.18286E-17 -17.7379 0.15254E-17 -17.8166 0.83417E+00 -0.0787 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16359E-10 -10.7862 0.13646E-10 -10.8650 0.83417E+00 -0.0787 55 HFeO2- 0.34381E-07 -7.4637 0.28623E-07 -7.5433 0.83251E+00 -0.0796 56 FeO+ 0.11465E-16 -16.9406 0.95640E-17 -17.0194 0.83417E+00 -0.0787 58 FeO2- 0.39468E-09 -9.4038 0.32857E-09 -9.4834 0.83251E+00 -0.0796 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11617E-04 -4.9349 0.11582E-04 -4.9362 0.99701E+00 -0.0013 61 KCl,aq 0.10436E-08 -8.9815 0.10436E-08 -8.9815 0.10000E+01 0.0000 63 KOH,aq 0.75360E-06 -6.1229 0.75360E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.32391E-13 -13.4896 0.26966E-13 -13.5692 0.83251E+00 -0.0796 65 MgCO3,aq 0.17758E-11 -11.7506 0.17758E-11 -11.7506 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15610E-13 -13.8066 0.13021E-13 -13.8854 0.83417E+00 -0.0787 67 MgCl+ 0.87171E-14 -14.0596 0.72716E-14 -14.1384 0.83417E+00 -0.0787 68 MgF+ 0.70138E-15 -15.1540 0.58507E-15 -15.2328 0.83417E+00 -0.0787 69 MgOH+ 0.71827E-10 -10.1437 0.59916E-10 -10.2225 0.83417E+00 -0.0787 71 MnF+ 0.19388E-15 -15.7125 0.16173E-15 -15.7912 0.83417E+00 -0.0787 72 MnO,aq 0.18096E-08 -8.7424 0.18096E-08 -8.7424 0.10000E+01 0.0000 73 MnOH+ 0.48884E-09 -9.3108 0.40777E-09 -9.3896 0.83417E+00 -0.0787 74 MnO2-2 0.19702E-10 -10.7055 0.10083E-10 -10.9964 0.51178E+00 -0.2909 75 HMnO2- 0.20478E-09 -9.6887 0.17048E-09 -9.7683 0.83251E+00 -0.0796 78 MnCl+ 0.32484E-13 -13.4883 0.27097E-13 -13.5671 0.83417E+00 -0.0787 79 MnSO4,aq 0.38337E-19 -19.4164 0.38337E-19 -19.4164 0.10000E+01 0.0000 80 NaCl,aq 0.24170E-05 -5.6167 0.24170E-05 -5.6167 0.10000E+01 0.0000 81 NaF,aq 0.37258E-08 -8.4288 0.37258E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96028E-04 -4.0176 0.96028E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90093E-02 -2.0453 0.74863E-02 -2.1257 0.83096E+00 -0.0804 89 HPO3-2 0.15342E-14 -14.8141 0.78518E-15 -15.1050 0.51178E+00 -0.2909 91 H2PO3- 0.14596E-18 -18.8358 0.12151E-18 -18.9154 0.83251E+00 -0.0796 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37163E-10 -10.4299 0.30969E-10 -10.5091 0.83333E+00 -0.0792 94 PO4-3 0.97324E-09 -9.0118 0.22998E-09 -9.6383 0.23630E+00 -0.6265 98 HP2O7-3 0.86554E-18 -18.0627 0.19458E-18 -18.7109 0.22481E+00 -0.6482 99 P2O7-4 0.82061E-17 -17.0859 0.60234E-18 -18.2202 0.73402E-01 -1.1343 100 H2S,aq 0.20110E-06 -6.6966 0.20050E-06 -6.6979 0.99701E+00 -0.0013 101 S2-2 0.26415E-11 -11.5782 0.13519E-11 -11.8691 0.51178E+00 -0.2909 102 S3-2 0.61606E-19 -19.2104 0.31529E-19 -19.5013 0.51178E+00 -0.2909 107 SO3-2 0.36972E-16 -16.4321 0.19205E-16 -16.7166 0.51946E+00 -0.2845 108 HSO3- 0.11147E-18 -18.9528 0.92800E-19 -19.0325 0.83251E+00 -0.0796 109 HSO4- 0.11365E-17 -17.9444 0.94898E-18 -18.0227 0.83501E+00 -0.0783 111 S2O3-2 0.58723E-19 -19.2312 0.30053E-19 -19.5221 0.51178E+00 -0.2909 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9212107E-10 -.2168784E-01 -.2182024E+02 0.0000 2 H2O 0.1000000E+01 0.5550765E+02 0.9981662E+06 0.0000 3 Cl- 0.5078678E-03 0.5102859E-03 0.1805823E+02 6.7387 4 SO4-- 0.2487731E-10 -.2735522E-02 -.2623001E+03 9.3309 5 HCO3- 0.5106347E-04 0.2877891E-02 0.1752811E+03 5.7417 6 HS- 0.1009561E-02 0.3745284E-02 0.1236385E+03 7.0371 7 Al+++ 0.1122193E-28 0.5127362E-05 0.1380920E+00 0.7390 8 H4SiO4 0.6959411E-03 0.1316011E-01 0.1262587E+04 -3.1574 9 Ca++ 0.1479282E-06 0.2942483E-06 0.1177141E-01 13.1018 10 Mg++ 0.2314619E-10 0.1001304E-09 0.2429937E-05 9.2942 11 Fe++ 0.6379506E-13 0.3500636E-07 0.1951441E-02 6.7350 12 K+ 0.1633016E-03 0.1640562E-03 0.6403247E+01 6.2467 13 Na+ 0.2072363E-01 0.2317135E-01 0.5317349E+03 8.3493 14 Mn++ 0.2050345E-10 0.2543435E-08 0.1394768E-03 9.2424 15 F- 0.1110580E-05 0.1114307E-05 0.2113106E-01 4.0775 16 HPO4-- 0.4240545E-07 0.4341585E-07 0.4159423E-02 12.5626 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279044E+02 -.1077219E-01 -.8277967E+02 0.0000000E+00 2 H2O -.7152750E+01 0.2757023E+02 -.3472298E+02 0.0000000E+00 3 Cl- 0.2534552E-03 0.2534552E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386861E+00 -.1358713E-02 0.1400448E+00 0.0000000E+00 5 HCO3- 0.1429427E-02 0.1429427E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1381845E+00 0.1860255E-02 -.1400448E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2546722E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6536529E-02 0.5205737E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1461509E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4973399E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1738740E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8148550E-04 0.1061489E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1150904E-01 0.6264868E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1263305E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7936000E-05 0.5534680E-06 0.7382532E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2156433E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1411E-13 Mass of aqueous solution: 0.497598E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0195900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 629.9 andradite 0.5602 -0.252 284.7 2.454 5.212 73.96 grossular 0.1356 -0.868 61.10 1.786 1.119 17.00 apatite-OH 0.9855E-02 -2.006 4.950 0.695 0.9063E-01 1.573 apatite-F 0.7383E-05 -5.132 0.3723E-02 -2.429 0.6816E-04 0.1163E-02 clinochlore 0.7089 -0.149 394.1 2.596 7.214 149.9 daphnite 0.2052 -0.688 146.4 2.166 2.681 44.38 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2252 -0.647 48.77 1.688 0.8928 14.90 hedenbergite 0.5840E-01 -1.234 14.49 1.161 0.2653 3.969 microcline 0.9323 -0.030 259.5 2.414 4.751 101.4 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2583 -0.588 278.5 2.445 5.098 96.19 tr.625ac.25prg.125 0.5471E-01 -1.262 46.77 1.670 0.8562 15.05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.343877 g Volume = 2210.831913 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0195900 moles log = -1.7080 Original solution: 1000.0103000 g Original solution / Rock added: 51046.98 (Water/Rock Ratio), log = 4.7080 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 5.0632 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2046E+00 0.9710 0.1006E+01 0.1036E+01 CO2,gas 0.1499E-06 0.9900 0.7512E-06 0.7588E-06 CH4,gas 0.7924E+00 0.9995 0.4010E+01 0.4012E+01 H2,gas 0.2995E-02 1.0027 0.1521E-01 0.1516E-01 H2S,gas 0.1110E-05 0.9805 0.5511E-05 0.5621E-05 S2,gas 0.9740E-27 1.0000 0.4931E-26 0.4931E-26 CO,gas 0.6013E-12 1.0000 0.3044E-11 0.3044E-11 SO3,gas 0.5675E-47 1.0000 0.2873E-46 0.2873E-46 SO2,gas 0.3358E-26 1.0000 0.1700E-25 0.1700E-25 HF,gas 0.2364E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2084E-17 1.0000 0.1055E-16 0.1055E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.18198E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.60662E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.48 -7.82 -2.608 0.13358E+05 -6.124 3 CH4,gas 4.54 3.45 -1.10 -0.274 0.18711E+04 0.603 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.19 -6.96 -3.479 0.11880E+05 -5.259 6 S2,gas -7.34 -35.34 -28.01 -4.309 0.47819E+05 -26.307 7 CO,gas 3.21 -10.00 -13.22 -4.066 0.22565E+05 -11.517 8 SO3,gas 17.12 -31.12 -48.24 -12.060 0.82369E+05 -46.542 9 SO2,gas 0.83 -26.64 -27.47 -7.325 0.46902E+05 -25.770 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.49 -18.68 -9.338 0.31888E+05 -16.977 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80667E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93632E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.38 -2.35 -0.783 0.40092E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.38 -2.19 -0.731 0.37450E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68938E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65535E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.52 -2.42 -0.690 0.41241E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.52 -1.97 -0.563 0.33663E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82227E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.12 -2.88 -0.677 0.49120E+04 146 pyrrhotite -4.26 -6.45 -2.19 -0.731 0.37438E+04 147 pyrrhotiteFe0.875 -6.02 -7.85 -1.83 -0.674 0.31311E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22431E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.24 -4.26 -1.422 0.72818E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23233E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47099E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.45 -2.04 -0.681 0.34867E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.95 -2.97 -0.989 0.50672E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0195900 MOLES New total amount of reactant added: 0.0199900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8644E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0199900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4967E+00 Moles total = -.7152E+01 kg total = -.1289E+00 Activity = 0.9999 Stoichiometric ionic strength = .9754137E-02 Osmotic coef. = 0.9204 True ionic strength = .2099969E-01 Chg. balance for total moles = -.8644E-10 Max. difference allowed = 0.2558E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92193E-10 -10.0353 0.77229E-10 -10.1122 0.83769E+00 -0.0769 2 H2O 0.99995E+00 0.0000 0.99995E+00 0.0000 3 Cl- 0.51259E-03 -3.2902 0.42671E-03 -3.3699 0.83247E+00 -0.0796 4 SO4-- 0.25345E-10 -10.5961 0.12997E-10 -10.8862 0.51279E+00 -0.2901 5 HCO3- 0.52065E-04 -4.2835 0.43408E-04 -4.3624 0.83373E+00 -0.0790 6 HS- 0.10291E-02 -2.9875 0.85683E-03 -3.0671 0.83259E+00 -0.0796 7 Al+++ 0.11252E-28 -28.9488 0.25256E-29 -29.5976 0.22446E+00 -0.6489 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14818E-06 -6.8292 0.75404E-07 -7.1226 0.50888E+00 -0.2934 10 Mg++ 0.23185E-10 -10.6348 0.11742E-10 -10.9302 0.50646E+00 -0.2955 11 Fe++ 0.63902E-13 -13.1945 0.32401E-13 -13.4894 0.50704E+00 -0.2950 12 K+ 0.16343E-03 -3.7867 0.13629E-03 -3.8655 0.83393E+00 -0.0789 13 Na+ 0.20740E-01 -1.6832 0.17262E-01 -1.7629 0.83231E+00 -0.0797 14 Mn++ 0.20539E-10 -10.6874 0.10423E-10 -10.9820 0.50747E+00 -0.2946 15 F- 0.11098E-05 -5.9547 0.92193E-06 -6.0353 0.83069E+00 -0.0806 16 HPO4-- 0.42354E-07 -7.3731 0.21722E-07 -7.6631 0.51286E+00 -0.2900 18 HSiO3- 0.10108E-01 -1.9953 0.84147E-02 -2.0750 0.83247E+00 -0.0796 19 Ca(HSiO3)+ 0.17324E-07 -7.7614 0.14450E-07 -7.8401 0.83412E+00 -0.0788 20 Mg(HSiO3)+ 0.33574E-11 -11.4740 0.28005E-11 -11.5528 0.83412E+00 -0.0788 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.69061E-16 -16.1608 0.57605E-16 -16.2395 0.83412E+00 -0.0788 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51238E-05 -5.2904 0.42574E-05 -5.3709 0.83091E+00 -0.0804 26 CH4,aq 0.27880E-02 -2.5547 0.27797E-02 -2.5560 0.99702E+00 -0.0013 27 C2H6,aq 0.11439E-09 -9.9416 0.11405E-09 -9.9429 0.99702E+00 -0.0013 28 C3H8,aq 0.10836E-15 -15.9651 0.10804E-15 -15.9664 0.99702E+00 -0.0013 30 ethanol,aq 0.41986E-17 -17.3769 0.41861E-17 -17.3782 0.99702E+00 -0.0013 31 CO,aq 0.20843E-14 -14.6810 0.20843E-14 -14.6810 0.10000E+01 0.0000 32 CO2,aq 0.71850E-08 -8.1436 0.71635E-08 -8.1449 0.99702E+00 -0.0013 33 CO3-2 0.95951E-04 -4.0180 0.49094E-04 -4.3090 0.51166E+00 -0.2910 34 CaCO3,aq 0.46417E-07 -7.3333 0.46417E-07 -7.3333 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10016E-09 -9.9993 0.83549E-10 -10.0781 0.83412E+00 -0.0788 36 CaCl+ 0.62425E-10 -10.2046 0.52070E-10 -10.2834 0.83412E+00 -0.0788 37 CaCl2,aq 0.52787E-14 -14.2775 0.52787E-14 -14.2775 0.10000E+01 0.0000 38 CaF+ 0.12168E-11 -11.9148 0.10150E-11 -11.9936 0.83412E+00 -0.0788 39 CaOH+ 0.83419E-07 -7.0787 0.69581E-07 -7.1575 0.83412E+00 -0.0788 40 CaSO4,aq 0.31119E-15 -15.5070 0.31119E-15 -15.5070 0.10000E+01 0.0000 41 HCl,aq 0.60388E-14 -14.2191 0.60388E-14 -14.2191 0.10000E+01 0.0000 45 HF,aq 0.48741E-12 -12.3121 0.48741E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18225E-18 -18.7393 0.15172E-18 -18.8190 0.83247E+00 -0.0796 48 FeCl+ 0.26236E-16 -16.5811 0.21884E-16 -16.6599 0.83412E+00 -0.0788 51 FeF+ 0.18300E-17 -17.7375 0.15265E-17 -17.8163 0.83412E+00 -0.0788 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16372E-10 -10.7859 0.13656E-10 -10.8647 0.83412E+00 -0.0788 55 HFeO2- 0.34358E-07 -7.4640 0.28602E-07 -7.5436 0.83247E+00 -0.0796 56 FeO+ 0.11474E-16 -16.9403 0.95709E-17 -17.0190 0.83412E+00 -0.0788 58 FeO2- 0.39441E-09 -9.4040 0.32834E-09 -9.4837 0.83247E+00 -0.0796 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11617E-04 -4.9349 0.11582E-04 -4.9362 0.99702E+00 -0.0013 61 KCl,aq 0.10540E-08 -8.9771 0.10540E-08 -8.9771 0.10000E+01 0.0000 63 KOH,aq 0.75360E-06 -6.1229 0.75360E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.33018E-13 -13.4813 0.27486E-13 -13.5609 0.83247E+00 -0.0796 65 MgCO3,aq 0.18119E-11 -11.7419 0.18119E-11 -11.7419 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15939E-13 -13.7976 0.13295E-13 -13.8763 0.83412E+00 -0.0788 67 MgCl+ 0.88108E-14 -14.0550 0.73493E-14 -14.1338 0.83412E+00 -0.0788 68 MgF+ 0.70192E-15 -15.1537 0.58549E-15 -15.2325 0.83412E+00 -0.0788 69 MgOH+ 0.71883E-10 -10.1434 0.59959E-10 -10.2221 0.83412E+00 -0.0788 71 MnF+ 0.19404E-15 -15.7121 0.16185E-15 -15.7909 0.83412E+00 -0.0788 72 MnO,aq 0.18097E-08 -8.7424 0.18097E-08 -8.7424 0.10000E+01 0.0000 73 MnOH+ 0.48924E-09 -9.3105 0.40808E-09 -9.3893 0.83412E+00 -0.0788 74 MnO2-2 0.19679E-10 -10.7060 0.10069E-10 -10.9970 0.51166E+00 -0.2910 75 HMnO2- 0.20465E-09 -9.6890 0.17036E-09 -9.7686 0.83247E+00 -0.0796 78 MnCl+ 0.32834E-13 -13.4837 0.27388E-13 -13.5624 0.83412E+00 -0.0788 79 MnSO4,aq 0.39107E-19 -19.4077 0.39107E-19 -19.4077 0.10000E+01 0.0000 80 NaCl,aq 0.24410E-05 -5.6124 0.24410E-05 -5.6124 0.10000E+01 0.0000 81 NaF,aq 0.37258E-08 -8.4288 0.37258E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96028E-04 -4.0176 0.96028E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90033E-02 -2.0456 0.74809E-02 -2.1260 0.83091E+00 -0.0804 89 HPO3-2 0.15324E-14 -14.8146 0.78405E-15 -15.1057 0.51166E+00 -0.2910 91 H2PO3- 0.14586E-18 -18.8361 0.12142E-18 -18.9157 0.83247E+00 -0.0796 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37138E-10 -10.4302 0.30947E-10 -10.5094 0.83328E+00 -0.0792 94 PO4-3 0.97161E-09 -9.0125 0.22948E-09 -9.6392 0.23619E+00 -0.6267 98 HP2O7-3 0.86412E-18 -18.0634 0.19416E-18 -18.7118 0.22469E+00 -0.6484 99 P2O7-4 0.81899E-17 -17.0867 0.60061E-18 -18.2214 0.73335E-01 -1.1347 100 H2S,aq 0.20512E-06 -6.6880 0.20451E-06 -6.6893 0.99702E+00 -0.0013 101 S2-2 0.27451E-11 -11.5614 0.14046E-11 -11.8525 0.51166E+00 -0.2910 102 S3-2 0.65305E-19 -19.1851 0.33414E-19 -19.4761 0.51166E+00 -0.2910 107 SO3-2 0.37667E-16 -16.4240 0.19562E-16 -16.7086 0.51934E+00 -0.2845 108 HSO3- 0.11363E-18 -18.9445 0.94591E-19 -19.0241 0.83247E+00 -0.0796 109 HSO4- 0.11585E-17 -17.9361 0.96730E-18 -18.0144 0.83496E+00 -0.0783 111 S2O3-2 0.61026E-19 -19.2145 0.31225E-19 -19.5055 0.51166E+00 -0.2910 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9219250E-10 -.2167698E-01 -.2180928E+02 0.0000 2 H2O 0.1000000E+01 0.5550770E+02 0.9981656E+06 0.0000 3 Cl- 0.5125876E-03 0.5150298E-03 0.1822608E+02 6.7424 4 SO4-- 0.2534511E-10 -.2790908E-02 -.2676105E+03 9.3383 5 HCO3- 0.5206459E-04 0.2936073E-02 0.1788245E+03 5.7498 6 HS- 0.1029112E-02 0.3820225E-02 0.1261122E+03 7.0451 7 Al+++ 0.1125209E-28 0.5123985E-05 0.1380008E+00 0.7390 8 H4SiO4 0.6959403E-03 0.1315342E-01 0.1261943E+04 -3.1574 9 Ca++ 0.1481759E-06 0.2954997E-06 0.1182146E-01 13.1018 10 Mg++ 0.2318503E-10 0.1002639E-09 0.2433173E-05 9.2942 11 Fe++ 0.6390212E-13 0.3498336E-07 0.1950156E-02 6.7350 12 K+ 0.1634282E-03 0.1641829E-03 0.6408179E+01 6.2467 13 Na+ 0.2073972E-01 0.2318747E-01 0.5321038E+03 8.3493 14 Mn++ 0.2053864E-10 0.2543788E-08 0.1394960E-03 9.2424 15 F- 0.1109847E-05 0.1113574E-05 0.2111713E-01 4.0769 16 HPO4-- 0.4235410E-07 0.4336285E-07 0.4154339E-02 12.5613 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279039E+02 -.1076695E-01 -.8277963E+02 0.0000000E+00 2 H2O -.7152423E+01 0.2757066E+02 -.3472309E+02 0.0000000E+00 3 Cl- 0.2558152E-03 0.2558152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386880E+00 -.1386243E-02 0.1400742E+00 0.0000000E+00 5 HCO3- 0.1458347E-02 0.1458347E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1381767E+00 0.1897505E-02 -.1400742E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2545082E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6533303E-02 0.5205737E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1467747E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4980105E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1737623E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8154960E-04 0.1061489E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1151721E-01 0.6264860E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1263499E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8096000E-05 0.5531121E-06 0.7542888E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2153832E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.9562E-14 Mass of aqueous solution: 0.497607E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0199900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 629.9 andradite 0.5603 -0.252 284.7 2.454 5.213 73.98 grossular 0.1357 -0.867 61.12 1.786 1.119 17.00 apatite-OH 0.9855E-02 -2.006 4.950 0.695 0.9063E-01 1.573 apatite-F 0.7543E-05 -5.122 0.3804E-02 -2.420 0.6964E-04 0.1188E-02 clinochlore 0.7089 -0.149 394.0 2.596 7.214 149.9 daphnite 0.2052 -0.688 146.4 2.166 2.681 44.37 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2244 -0.649 48.60 1.687 0.8898 14.85 hedenbergite 0.5820E-01 -1.235 14.44 1.160 0.2644 3.955 microcline 0.9324 -0.030 259.5 2.414 4.751 101.4 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2583 -0.588 278.4 2.445 5.097 96.17 tr.625ac.25prg.125 0.5496E-01 -1.260 46.98 1.672 0.8601 15.12 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.343994 g Volume = 2210.833018 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0199900 moles log = -1.6992 Original solution: 1000.0103000 g Original solution / Rock added: 50025.53 (Water/Rock Ratio), log = 4.6992 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 5.1451 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2014E+00 0.9709 0.1006E+01 0.1036E+01 CO2,gas 0.1505E-06 0.9898 0.7664E-06 0.7743E-06 CH4,gas 0.7957E+00 0.9994 0.4092E+01 0.4094E+01 H2,gas 0.2947E-02 1.0027 0.1521E-01 0.1516E-01 H2S,gas 0.1115E-05 0.9802 0.5622E-05 0.5735E-05 S2,gas 0.9973E-27 1.0000 0.5131E-26 0.5131E-26 CO,gas 0.6037E-12 1.0000 0.3106E-11 0.3106E-11 SO3,gas 0.5697E-47 1.0000 0.2931E-46 0.2931E-46 SO2,gas 0.3370E-26 1.0000 0.1734E-25 0.1734E-25 HF,gas 0.2326E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2071E-17 1.0000 0.1066E-16 0.1066E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.36397E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.97059E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.47 -7.81 -2.605 0.13343E+05 -6.116 3 CH4,gas 4.54 3.46 -1.09 -0.272 0.18562E+04 0.612 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.18 -6.95 -3.475 0.11865E+05 -5.250 6 S2,gas -7.34 -35.32 -27.99 -4.306 0.47790E+05 -26.290 7 CO,gas 3.21 -9.99 -13.21 -4.064 0.22550E+05 -11.508 8 SO3,gas 17.12 -31.11 -48.23 -12.058 0.82355E+05 -46.533 9 SO2,gas 0.83 -26.63 -27.46 -7.323 0.46887E+05 -25.761 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.48 -18.67 -9.336 0.31881E+05 -16.972 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80666E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93632E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.37 -2.34 -0.780 0.39944E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.37 -2.18 -0.728 0.37301E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68939E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65534E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.51 -2.41 -0.688 0.41092E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.51 -1.96 -0.561 0.33515E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82227E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.11 -2.86 -0.673 0.48826E+04 146 pyrrhotite -4.26 -6.44 -2.18 -0.728 0.37291E+04 147 pyrrhotiteFe0.875 -6.02 -7.84 -1.83 -0.671 0.31163E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22430E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.23 -4.26 -1.419 0.72668E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23233E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47098E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.44 -2.03 -0.678 0.34719E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.94 -2.96 -0.986 0.50525E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 MOLES Current total amount of reactant added: 0.0199900 MOLES New total amount of reactant added: 0.0203900 MOLES Mixing fraction reached given limit of 0.2000E-01 TOTMIX = 0.2039E-01 Execution stopped.