File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.82790E+02 0.92193E-10 0.8377 0.00000000E+00 H2O 2 0. -0.71524E+01 0.10000E+01 0.9999 0.00000000E+00 Cl- 3 -1. 0.25582E-03 0.51259E-03 0.8325 0.00000000E+00 SO4-- 4 -2. 0.13869E+00 0.25345E-10 0.5128 0.00000000E+00 HCO3- 5 -1. 0.14583E-02 0.52065E-04 0.8337 0.00000000E+00 HS- 6 -1. -0.13818E+00 0.10291E-02 0.8326 0.00000000E+00 Al+++ 7 3. 0.16304E+02 0.11252E-28 0.2245 0.00000000E+00 H4SiO4 8 0. 0.52064E+02 0.69594E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.57507E+01 0.14818E-06 0.5089 0.00000000E+00 Mg++ 10 2. 0.39683E+01 0.23185E-10 0.5065 0.00000000E+00 Fe++ 11 2. 0.35650E+01 0.63902E-13 0.5070 0.00000000E+00 K+ 12 1. 0.10616E+01 0.16343E-03 0.8339 0.00000000E+00 Na+ 13 1. 0.62764E+01 0.20740E-01 0.8323 0.00000000E+00 Mn++ 14 2. 0.86693E-01 0.20539E-10 0.5075 0.00000000E+00 F- 15 -1. 0.80960E-05 0.11098E-05 0.8307 0.00000000E+00 HPO4-- 16 -2. 0.29588E-01 0.42354E-07 0.5129 0.00000000E+00 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.2558E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.400000E-01 TEMP = 100.0000 SINC = 0.1000E-02 TEMPC = 0.0000 TOTMIX = 0.199900E-01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 2000.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.6258E+01 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.5603E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.1357E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.9855E-02 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.7543E-05 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.3221E+01 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.2583E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.7089E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.2052E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.1734E-01 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.2244E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.5820E-01 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.9324E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.5496E-01 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0199900 moles log = -1.6992 Original solution: 1000.0103000 g Original solution / Rock added: 50025.53 (Water/Rock Ratio), log = 4.6992 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0199900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4967E+00 Moles total = -.7152E+01 kg total = -.1289E+00 Activity = 0.9999 Stoichiometric ionic strength = .9754137E-02 Osmotic coef. = 0.9204 True ionic strength = .2099969E-01 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.2558E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92193E-10 -10.0353 0.77229E-10 -10.1122 0.83769E+00 -0.0769 2 H2O 0.99995E+00 0.0000 0.99995E+00 0.0000 3 Cl- 0.51259E-03 -3.2902 0.42671E-03 -3.3699 0.83247E+00 -0.0796 4 SO4-- 0.25345E-10 -10.5961 0.12997E-10 -10.8862 0.51279E+00 -0.2901 5 HCO3- 0.52065E-04 -4.2835 0.43408E-04 -4.3624 0.83373E+00 -0.0790 6 HS- 0.10291E-02 -2.9875 0.85683E-03 -3.0671 0.83259E+00 -0.0796 7 Al+++ 0.11252E-28 -28.9488 0.25256E-29 -29.5976 0.22446E+00 -0.6489 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14818E-06 -6.8292 0.75404E-07 -7.1226 0.50888E+00 -0.2934 10 Mg++ 0.23185E-10 -10.6348 0.11742E-10 -10.9302 0.50646E+00 -0.2955 11 Fe++ 0.63902E-13 -13.1945 0.32401E-13 -13.4894 0.50704E+00 -0.2950 12 K+ 0.16343E-03 -3.7867 0.13629E-03 -3.8655 0.83393E+00 -0.0789 13 Na+ 0.20740E-01 -1.6832 0.17262E-01 -1.7629 0.83231E+00 -0.0797 14 Mn++ 0.20539E-10 -10.6874 0.10423E-10 -10.9820 0.50747E+00 -0.2946 15 F- 0.11098E-05 -5.9547 0.92193E-06 -6.0353 0.83069E+00 -0.0806 16 HPO4-- 0.42354E-07 -7.3731 0.21722E-07 -7.6631 0.51286E+00 -0.2900 18 HSiO3- 0.10108E-01 -1.9953 0.84147E-02 -2.0750 0.83247E+00 -0.0796 19 Ca(HSiO3)+ 0.17324E-07 -7.7614 0.14450E-07 -7.8401 0.83412E+00 -0.0788 20 Mg(HSiO3)+ 0.33574E-11 -11.4740 0.28005E-11 -11.5528 0.83412E+00 -0.0788 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.69061E-16 -16.1608 0.57605E-16 -16.2395 0.83412E+00 -0.0788 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51238E-05 -5.2904 0.42574E-05 -5.3709 0.83091E+00 -0.0804 26 CH4,aq 0.27880E-02 -2.5547 0.27797E-02 -2.5560 0.99702E+00 -0.0013 27 C2H6,aq 0.11439E-09 -9.9416 0.11405E-09 -9.9429 0.99702E+00 -0.0013 28 C3H8,aq 0.10836E-15 -15.9651 0.10804E-15 -15.9664 0.99702E+00 -0.0013 30 ethanol,aq 0.41986E-17 -17.3769 0.41861E-17 -17.3782 0.99702E+00 -0.0013 31 CO,aq 0.20843E-14 -14.6810 0.20843E-14 -14.6810 0.10000E+01 0.0000 32 CO2,aq 0.71850E-08 -8.1436 0.71635E-08 -8.1449 0.99702E+00 -0.0013 33 CO3-2 0.95951E-04 -4.0180 0.49094E-04 -4.3090 0.51166E+00 -0.2910 34 CaCO3,aq 0.46417E-07 -7.3333 0.46417E-07 -7.3333 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10016E-09 -9.9993 0.83549E-10 -10.0781 0.83412E+00 -0.0788 36 CaCl+ 0.62425E-10 -10.2046 0.52070E-10 -10.2834 0.83412E+00 -0.0788 37 CaCl2,aq 0.52787E-14 -14.2775 0.52787E-14 -14.2775 0.10000E+01 0.0000 38 CaF+ 0.12168E-11 -11.9148 0.10150E-11 -11.9936 0.83412E+00 -0.0788 39 CaOH+ 0.83419E-07 -7.0787 0.69581E-07 -7.1575 0.83412E+00 -0.0788 40 CaSO4,aq 0.31119E-15 -15.5070 0.31119E-15 -15.5070 0.10000E+01 0.0000 41 HCl,aq 0.60388E-14 -14.2191 0.60388E-14 -14.2191 0.10000E+01 0.0000 45 HF,aq 0.48741E-12 -12.3121 0.48741E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18225E-18 -18.7393 0.15172E-18 -18.8190 0.83247E+00 -0.0796 48 FeCl+ 0.26236E-16 -16.5811 0.21884E-16 -16.6599 0.83412E+00 -0.0788 51 FeF+ 0.18300E-17 -17.7375 0.15265E-17 -17.8163 0.83412E+00 -0.0788 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16372E-10 -10.7859 0.13656E-10 -10.8647 0.83412E+00 -0.0788 55 HFeO2- 0.34358E-07 -7.4640 0.28602E-07 -7.5436 0.83247E+00 -0.0796 56 FeO+ 0.11474E-16 -16.9403 0.95709E-17 -17.0190 0.83412E+00 -0.0788 58 FeO2- 0.39441E-09 -9.4040 0.32834E-09 -9.4837 0.83247E+00 -0.0796 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11617E-04 -4.9349 0.11582E-04 -4.9362 0.99702E+00 -0.0013 61 KCl,aq 0.10540E-08 -8.9771 0.10540E-08 -8.9771 0.10000E+01 0.0000 63 KOH,aq 0.75360E-06 -6.1229 0.75360E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.33018E-13 -13.4813 0.27486E-13 -13.5609 0.83247E+00 -0.0796 65 MgCO3,aq 0.18119E-11 -11.7419 0.18119E-11 -11.7419 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.15939E-13 -13.7976 0.13295E-13 -13.8763 0.83412E+00 -0.0788 67 MgCl+ 0.88108E-14 -14.0550 0.73493E-14 -14.1338 0.83412E+00 -0.0788 68 MgF+ 0.70192E-15 -15.1537 0.58549E-15 -15.2325 0.83412E+00 -0.0788 69 MgOH+ 0.71883E-10 -10.1434 0.59959E-10 -10.2221 0.83412E+00 -0.0788 71 MnF+ 0.19404E-15 -15.7121 0.16185E-15 -15.7909 0.83412E+00 -0.0788 72 MnO,aq 0.18097E-08 -8.7424 0.18097E-08 -8.7424 0.10000E+01 0.0000 73 MnOH+ 0.48924E-09 -9.3105 0.40808E-09 -9.3893 0.83412E+00 -0.0788 74 MnO2-2 0.19679E-10 -10.7060 0.10069E-10 -10.9970 0.51166E+00 -0.2910 75 HMnO2- 0.20465E-09 -9.6890 0.17036E-09 -9.7686 0.83247E+00 -0.0796 78 MnCl+ 0.32834E-13 -13.4837 0.27388E-13 -13.5624 0.83412E+00 -0.0788 79 MnSO4,aq 0.39107E-19 -19.4077 0.39107E-19 -19.4077 0.10000E+01 0.0000 80 NaCl,aq 0.24410E-05 -5.6124 0.24410E-05 -5.6124 0.10000E+01 0.0000 81 NaF,aq 0.37258E-08 -8.4288 0.37258E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96028E-04 -4.0176 0.96028E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.90033E-02 -2.0456 0.74809E-02 -2.1260 0.83091E+00 -0.0804 89 HPO3-2 0.15324E-14 -14.8146 0.78405E-15 -15.1057 0.51166E+00 -0.2910 91 H2PO3- 0.14586E-18 -18.8361 0.12142E-18 -18.9157 0.83247E+00 -0.0796 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37138E-10 -10.4302 0.30947E-10 -10.5094 0.83328E+00 -0.0792 94 PO4-3 0.97161E-09 -9.0125 0.22948E-09 -9.6392 0.23619E+00 -0.6267 98 HP2O7-3 0.86412E-18 -18.0634 0.19416E-18 -18.7118 0.22469E+00 -0.6484 99 P2O7-4 0.81899E-17 -17.0867 0.60061E-18 -18.2214 0.73335E-01 -1.1347 100 H2S,aq 0.20512E-06 -6.6880 0.20451E-06 -6.6893 0.99702E+00 -0.0013 101 S2-2 0.27451E-11 -11.5614 0.14046E-11 -11.8525 0.51166E+00 -0.2910 102 S3-2 0.65305E-19 -19.1851 0.33414E-19 -19.4761 0.51166E+00 -0.2910 107 SO3-2 0.37667E-16 -16.4240 0.19562E-16 -16.7086 0.51934E+00 -0.2845 108 HSO3- 0.11363E-18 -18.9445 0.94591E-19 -19.0241 0.83247E+00 -0.0796 109 HSO4- 0.11585E-17 -17.9361 0.96730E-18 -18.0144 0.83496E+00 -0.0783 111 S2O3-2 0.61026E-19 -19.2145 0.31225E-19 -19.5055 0.51166E+00 -0.2910 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9219250E-10 -.2167698E-01 -.2180928E+02 0.0000 2 H2O 0.1000000E+01 0.5550770E+02 0.9981656E+06 0.0000 3 Cl- 0.5125876E-03 0.5150298E-03 0.1822608E+02 6.7424 4 SO4-- 0.2534511E-10 -.2790908E-02 -.2676105E+03 9.3383 5 HCO3- 0.5206459E-04 0.2936073E-02 0.1788245E+03 5.7498 6 HS- 0.1029112E-02 0.3820225E-02 0.1261122E+03 7.0451 7 Al+++ 0.1125209E-28 0.5123985E-05 0.1380008E+00 0.7390 8 H4SiO4 0.6959403E-03 0.1315342E-01 0.1261943E+04 -3.1574 9 Ca++ 0.1481759E-06 0.2954997E-06 0.1182146E-01 13.1018 10 Mg++ 0.2318503E-10 0.1002639E-09 0.2433173E-05 9.2942 11 Fe++ 0.6390212E-13 0.3498336E-07 0.1950156E-02 6.7350 12 K+ 0.1634282E-03 0.1641829E-03 0.6408179E+01 6.2467 13 Na+ 0.2073972E-01 0.2318747E-01 0.5321038E+03 8.3493 14 Mn++ 0.2053864E-10 0.2543788E-08 0.1394960E-03 9.2424 15 F- 0.1109847E-05 0.1113574E-05 0.2111713E-01 4.0769 16 HPO4-- 0.4235410E-07 0.4336285E-07 0.4154339E-02 12.5613 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279039E+02 -.1076695E-01 -.8277963E+02 0.0000000E+00 2 H2O -.7152423E+01 0.2757066E+02 -.3472309E+02 0.0000000E+00 3 Cl- 0.2558152E-03 0.2558152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386880E+00 -.1386243E-02 0.1400742E+00 0.0000000E+00 5 HCO3- 0.1458347E-02 0.1458347E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1381767E+00 0.1897505E-02 -.1400742E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2545082E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6533303E-02 0.5205737E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1467747E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4980105E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1737623E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8154960E-04 0.1061489E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1151721E-01 0.6264860E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1263499E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8096000E-05 0.5531121E-06 0.7542888E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2153832E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1311E-13 Mass of aqueous solution: 0.497607E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0199900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 629.9 andradite 0.5603 -0.252 284.7 2.454 5.213 73.98 grossular 0.1357 -0.867 61.12 1.786 1.119 17.00 apatite-OH 0.9855E-02 -2.006 4.950 0.695 0.9063E-01 1.573 apatite-F 0.7543E-05 -5.122 0.3804E-02 -2.420 0.6964E-04 0.1188E-02 clinochlore 0.7089 -0.149 394.0 2.596 7.214 149.9 daphnite 0.2052 -0.688 146.4 2.166 2.681 44.37 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2244 -0.649 48.60 1.687 0.8898 14.85 hedenbergite 0.5820E-01 -1.235 14.44 1.160 0.2644 3.955 microcline 0.9324 -0.030 259.5 2.414 4.751 101.4 stilbite 3.221 0.508 2270. 3.356 41.55 1059. stilpnomelane-Fe 0.2583 -0.588 278.4 2.445 5.097 96.17 tr.625ac.25prg.125 0.5496E-01 -1.260 46.98 1.672 0.8601 15.12 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.343994 g Volume = 2210.833018 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0199900 moles log = -1.6992 Original solution: 1000.0103000 g Original solution / Rock added: 50025.53 (Water/Rock Ratio), log = 4.6992 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 5.1451 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2014E+00 0.9709 0.1006E+01 0.1036E+01 CO2,gas 0.1505E-06 0.9898 0.7664E-06 0.7743E-06 CH4,gas 0.7957E+00 0.9994 0.4092E+01 0.4094E+01 H2,gas 0.2947E-02 1.0027 0.1521E-01 0.1516E-01 H2S,gas 0.1115E-05 0.9802 0.5622E-05 0.5735E-05 S2,gas 0.9973E-27 1.0000 0.5131E-26 0.5131E-26 CO,gas 0.6037E-12 1.0000 0.3106E-11 0.3106E-11 SO3,gas 0.5697E-47 1.0000 0.2931E-46 0.2931E-46 SO2,gas 0.3370E-26 1.0000 0.1734E-25 0.1734E-25 HF,gas 0.2326E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2071E-17 1.0000 0.1066E-16 0.1066E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.47 -7.81 -2.605 0.13343E+05 -6.116 3 CH4,gas 4.54 3.46 -1.09 -0.272 0.18562E+04 0.612 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.18 -6.95 -3.475 0.11865E+05 -5.250 6 S2,gas -7.34 -35.32 -27.99 -4.306 0.47790E+05 -26.290 7 CO,gas 3.21 -9.99 -13.21 -4.064 0.22550E+05 -11.508 8 SO3,gas 17.12 -31.11 -48.23 -12.058 0.82355E+05 -46.533 9 SO2,gas 0.83 -26.63 -27.46 -7.323 0.46887E+05 -25.761 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.48 -18.67 -9.336 0.31881E+05 -16.972 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80666E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93632E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.37 -2.34 -0.780 0.39944E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.37 -2.18 -0.728 0.37301E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68939E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65534E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.51 -2.41 -0.688 0.41092E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.51 -1.96 -0.561 0.33515E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82227E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.11 -2.86 -0.673 0.48826E+04 146 pyrrhotite -4.26 -6.44 -2.18 -0.728 0.37291E+04 147 pyrrhotiteFe0.875 -6.02 -7.84 -1.83 -0.671 0.31163E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22430E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.23 -4.26 -1.419 0.72668E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23233E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47098E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90675E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.44 -2.03 -0.678 0.34719E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60607E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.94 -2.96 -0.986 0.50525E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0199900 MOLES New total amount of reactant added: 0.0209900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0209900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4967E+00 Moles total = -.7152E+01 kg total = -.1288E+00 Activity = 0.9999 Stoichiometric ionic strength = .9669759E-02 Osmotic coef. = 0.9209 True ionic strength = .2104474E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.2617E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92371E-10 -10.0345 0.77368E-10 -10.1114 0.83758E+00 -0.0770 2 H2O 0.99995E+00 0.0000 0.99995E+00 0.0000 3 Cl- 0.52439E-03 -3.2803 0.43647E-03 -3.3600 0.83234E+00 -0.0797 4 SO4-- 0.26512E-10 -10.5766 0.13587E-10 -10.8669 0.51250E+00 -0.2903 5 HCO3- 0.54562E-04 -4.2631 0.45483E-04 -4.3421 0.83361E+00 -0.0790 6 HS- 0.10780E-02 -2.9674 0.89739E-03 -3.0470 0.83247E+00 -0.0796 7 Al+++ 0.11328E-28 -28.9459 0.25393E-29 -29.5953 0.22416E+00 -0.6494 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14880E-06 -6.8274 0.75675E-07 -7.1210 0.50858E+00 -0.2936 10 Mg++ 0.23282E-10 -10.6330 0.11785E-10 -10.9287 0.50616E+00 -0.2957 11 Fe++ 0.64170E-13 -13.1927 0.32518E-13 -13.4879 0.50674E+00 -0.2952 12 K+ 0.16374E-03 -3.7858 0.13653E-03 -3.8648 0.83381E+00 -0.0789 13 Na+ 0.20780E-01 -1.6824 0.17293E-01 -1.7621 0.83218E+00 -0.0798 14 Mn++ 0.20627E-10 -10.6856 0.10461E-10 -10.9804 0.50718E+00 -0.2948 15 F- 0.11080E-05 -5.9555 0.92028E-06 -6.0361 0.83056E+00 -0.0806 16 HPO4-- 0.42226E-07 -7.3744 0.21644E-07 -7.6647 0.51257E+00 -0.2902 18 HSiO3- 0.10092E-01 -1.9960 0.83996E-02 -2.0757 0.83234E+00 -0.0797 19 Ca(HSiO3)+ 0.17357E-07 -7.7605 0.14476E-07 -7.8394 0.83400E+00 -0.0788 20 Mg(HSiO3)+ 0.33639E-11 -11.4732 0.28055E-11 -11.5520 0.83400E+00 -0.0788 21 NaHSiO3,aq 0.23493E-02 -2.6291 0.23493E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.69195E-16 -16.1599 0.57709E-16 -16.2388 0.83400E+00 -0.0788 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51154E-05 -5.2911 0.42498E-05 -5.3716 0.83078E+00 -0.0805 26 CH4,aq 0.29265E-02 -2.5337 0.29178E-02 -2.5349 0.99704E+00 -0.0013 27 C2H6,aq 0.12604E-09 -9.8995 0.12567E-09 -9.9008 0.99704E+00 -0.0013 28 C3H8,aq 0.12533E-15 -15.9020 0.12496E-15 -15.9032 0.99704E+00 -0.0013 30 ethanol,aq 0.46262E-17 -17.3348 0.46125E-17 -17.3361 0.99704E+00 -0.0013 31 CO,aq 0.21879E-14 -14.6600 0.21879E-14 -14.6600 0.10000E+01 0.0000 32 CO2,aq 0.75419E-08 -8.1225 0.75196E-08 -8.1238 0.99704E+00 -0.0013 33 CO3-2 0.10042E-03 -3.9982 0.51349E-04 -4.2895 0.51137E+00 -0.2913 34 CaCO3,aq 0.48724E-07 -7.3123 0.48724E-07 -7.3123 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10535E-09 -9.9774 0.87860E-10 -10.0562 0.83400E+00 -0.0788 36 CaCl+ 0.64092E-10 -10.1932 0.53453E-10 -10.2720 0.83400E+00 -0.0788 37 CaCl2,aq 0.55428E-14 -14.2563 0.55428E-14 -14.2563 0.10000E+01 0.0000 38 CaF+ 0.12192E-11 -11.9139 0.10168E-11 -11.9928 0.83400E+00 -0.0788 39 CaOH+ 0.83581E-07 -7.0779 0.69706E-07 -7.1567 0.83400E+00 -0.0788 40 CaSO4,aq 0.32651E-15 -15.4861 0.32651E-15 -15.4861 0.10000E+01 0.0000 41 HCl,aq 0.61880E-14 -14.2085 0.61880E-14 -14.2085 0.10000E+01 0.0000 45 HF,aq 0.48741E-12 -12.3121 0.48741E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18195E-18 -18.7401 0.15144E-18 -18.8197 0.83234E+00 -0.0797 48 FeCl+ 0.26936E-16 -16.5697 0.22465E-16 -16.6485 0.83400E+00 -0.0788 51 FeF+ 0.18336E-17 -17.7367 0.15292E-17 -17.8155 0.83400E+00 -0.0788 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16403E-10 -10.7851 0.13680E-10 -10.8639 0.83400E+00 -0.0788 55 HFeO2- 0.34301E-07 -7.4647 0.28551E-07 -7.5444 0.83234E+00 -0.0797 56 FeO+ 0.11497E-16 -16.9394 0.95881E-17 -17.0183 0.83400E+00 -0.0788 58 FeO2- 0.39376E-09 -9.4048 0.32775E-09 -9.4845 0.83234E+00 -0.0797 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11616E-04 -4.9349 0.11582E-04 -4.9362 0.99704E+00 -0.0013 61 KCl,aq 0.10801E-08 -8.9666 0.10801E-08 -8.9666 0.10000E+01 0.0000 63 KOH,aq 0.75359E-06 -6.1229 0.75359E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.34586E-13 -13.4611 0.28787E-13 -13.5408 0.83234E+00 -0.0797 65 MgCO3,aq 0.19019E-11 -11.7208 0.19019E-11 -11.7208 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16763E-13 -13.7756 0.13981E-13 -13.8545 0.83400E+00 -0.0788 67 MgCl+ 0.90461E-14 -14.0435 0.75444E-14 -14.1224 0.83400E+00 -0.0788 68 MgF+ 0.70329E-15 -15.1529 0.58654E-15 -15.2317 0.83400E+00 -0.0788 69 MgOH+ 0.72023E-10 -10.1425 0.60067E-10 -10.2214 0.83400E+00 -0.0788 71 MnF+ 0.19444E-15 -15.7112 0.16216E-15 -15.7901 0.83400E+00 -0.0788 72 MnO,aq 0.18098E-08 -8.7424 0.18098E-08 -8.7424 0.10000E+01 0.0000 73 MnOH+ 0.49024E-09 -9.3096 0.40886E-09 -9.3884 0.83400E+00 -0.0788 74 MnO2-2 0.19621E-10 -10.7073 0.10034E-10 -10.9985 0.51137E+00 -0.2913 75 HMnO2- 0.20433E-09 -9.6897 0.17007E-09 -9.7694 0.83234E+00 -0.0797 78 MnCl+ 0.33714E-13 -13.4722 0.28118E-13 -13.5510 0.83400E+00 -0.0788 79 MnSO4,aq 0.41036E-19 -19.3868 0.41036E-19 -19.3868 0.10000E+01 0.0000 80 NaCl,aq 0.25013E-05 -5.6018 0.25013E-05 -5.6018 0.10000E+01 0.0000 81 NaF,aq 0.37258E-08 -8.4288 0.37258E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96027E-04 -4.0176 0.96027E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.89885E-02 -2.0463 0.74675E-02 -2.1268 0.83078E+00 -0.0805 89 HPO3-2 0.15278E-14 -14.8159 0.78124E-15 -15.1072 0.51137E+00 -0.2913 91 H2PO3- 0.14562E-18 -18.8368 0.12121E-18 -18.9165 0.83234E+00 -0.0797 92 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37077E-10 -10.4309 0.30891E-10 -10.5102 0.83316E+00 -0.0793 94 PO4-3 0.96756E-09 -9.0143 0.22825E-09 -9.6416 0.23590E+00 -0.6273 98 HP2O7-3 0.86059E-18 -18.0652 0.19312E-18 -18.7142 0.22440E+00 -0.6490 99 P2O7-4 0.81497E-17 -17.0889 0.59631E-18 -18.2245 0.73169E-01 -1.1357 100 H2S,aq 0.21522E-06 -6.6671 0.21458E-06 -6.6684 0.99704E+00 -0.0013 101 S2-2 0.30129E-11 -11.5210 0.15407E-11 -11.8123 0.51137E+00 -0.2913 102 S3-2 0.75204E-19 -19.1238 0.38457E-19 -19.4150 0.51137E+00 -0.2913 107 SO3-2 0.39400E-16 -16.4045 0.20451E-16 -16.6893 0.51906E+00 -0.2848 108 HSO3- 0.11902E-18 -18.9244 0.99069E-19 -19.0041 0.83234E+00 -0.0797 109 HSO4- 0.12135E-17 -17.9160 0.10131E-17 -17.9944 0.83484E+00 -0.0784 111 S2O3-2 0.66979E-19 -19.1741 0.34251E-19 -19.4653 0.51137E+00 -0.2913 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9237117E-10 -.2164987E-01 -.2178192E+02 0.0000 2 H2O 0.1000000E+01 0.5550784E+02 0.9981641E+06 0.0000 3 Cl- 0.5243863E-03 0.5268888E-03 0.1864567E+02 6.7514 4 SO4-- 0.2651227E-10 -.2929391E-02 -.2808880E+03 9.3560 5 HCO3- 0.5456200E-04 0.3081521E-02 0.1876824E+03 5.7693 6 HS- 0.1077985E-02 0.4007591E-02 0.1322970E+03 7.0644 7 Al+++ 0.1132779E-28 0.5115557E-05 0.1377733E+00 0.7390 8 H4SiO4 0.6959384E-03 0.1313673E-01 0.1260336E+04 -3.1574 9 Ca++ 0.1487966E-06 0.2986300E-06 0.1194664E-01 13.1018 10 Mg++ 0.2328233E-10 0.1005990E-09 0.2441297E-05 9.2942 11 Fe++ 0.6417032E-13 0.3492599E-07 0.1946950E-02 6.7350 12 K+ 0.1637449E-03 0.1644996E-03 0.6420515E+01 6.2467 13 Na+ 0.2077999E-01 0.2322777E-01 0.5330265E+03 8.3493 14 Mn++ 0.2062680E-10 0.2544675E-08 0.1395440E-03 9.2425 15 F- 0.1108018E-05 0.1111745E-05 0.2108236E-01 4.0754 16 HPO4-- 0.4222612E-07 0.4323076E-07 0.4141667E-02 12.5582 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279029E+02 -.1075388E-01 -.8277953E+02 0.0000000E+00 2 H2O -.7151604E+01 0.2757175E+02 -.3472335E+02 0.0000000E+00 3 Cl- 0.2617152E-03 0.2617152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386927E+00 -.1455081E-02 0.1401478E+00 0.0000000E+00 5 HCO3- 0.1530647E-02 0.1530647E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1381572E+00 0.1990643E-02 -.1401478E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2540990E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6525252E-02 0.5205738E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1483349E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4996936E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1734837E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8170992E-04 0.1061489E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1153765E-01 0.6264839E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1263986E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8496000E-05 0.5522239E-06 0.7943776E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2147350E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.8861E-14 Mass of aqueous solution: 0.497627E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0209900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 629.9 andradite 0.5606 -0.251 284.9 2.455 5.215 74.01 grossular 0.1357 -0.867 61.15 1.786 1.119 17.01 apatite-OH 0.9855E-02 -2.006 4.950 0.695 0.9062E-01 1.573 apatite-F 0.7944E-05 -5.100 0.4006E-02 -2.397 0.7334E-04 0.1252E-02 clinochlore 0.7088 -0.149 394.0 2.595 7.213 149.9 daphnite 0.2052 -0.688 146.4 2.166 2.681 44.37 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2225 -0.653 48.19 1.683 0.8821 14.73 hedenbergite 0.5771E-01 -1.239 14.32 1.156 0.2621 3.921 microcline 0.9324 -0.030 259.5 2.414 4.751 101.4 stilbite 3.221 0.508 2270. 3.356 41.56 1059. stilpnomelane-Fe 0.2581 -0.588 278.2 2.444 5.094 96.11 tr.625ac.25prg.125 0.5559E-01 -1.255 47.52 1.677 0.8699 15.29 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1862E-01 0.1862E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.344285 g Volume = 2210.835779 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0209900 moles log = -1.6780 Original solution: 1000.0103000 g Original solution / Rock added: 47642.22 (Water/Rock Ratio), log = 4.6780 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 5.3499 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1937E+00 0.9706 0.1006E+01 0.1036E+01 CO2,gas 0.1520E-06 0.9894 0.8045E-06 0.8132E-06 CH4,gas 0.8034E+00 0.9992 0.4295E+01 0.4298E+01 H2,gas 0.2834E-02 1.0029 0.1521E-01 0.1516E-01 H2S,gas 0.1126E-05 0.9795 0.5899E-05 0.6022E-05 S2,gas 0.1056E-26 1.0000 0.5649E-26 0.5649E-26 CO,gas 0.6094E-12 1.0000 0.3260E-11 0.3260E-11 SO3,gas 0.5748E-47 1.0000 0.3075E-46 0.3075E-46 SO2,gas 0.3401E-26 1.0000 0.1819E-25 0.1819E-25 HF,gas 0.2237E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2041E-17 1.0000 0.1092E-16 0.1092E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.45 -7.79 -2.598 0.13307E+05 -6.094 3 CH4,gas 4.54 3.48 -1.07 -0.267 0.18202E+04 0.633 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.16 -6.93 -3.464 0.11830E+05 -5.229 6 S2,gas -7.34 -35.28 -27.95 -4.300 0.47719E+05 -26.248 7 CO,gas 3.21 -9.97 -13.19 -4.057 0.22514E+05 -11.487 8 SO3,gas 17.12 -31.09 -48.21 -12.053 0.82319E+05 -46.512 9 SO2,gas 0.83 -26.61 -27.44 -7.317 0.46851E+05 -25.740 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.47 -18.66 -9.330 0.31863E+05 -16.962 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80664E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93632E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.35 -2.32 -0.773 0.39584E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.35 -2.16 -0.721 0.36942E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39693E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68939E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65534E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.49 -2.39 -0.682 0.40732E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.49 -1.94 -0.555 0.33155E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82226E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.06 -2.82 -0.663 0.48113E+04 146 pyrrhotite -4.26 -6.42 -2.16 -0.721 0.36935E+04 147 pyrrhotiteFe0.875 -6.02 -7.82 -1.80 -0.664 0.30807E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22430E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.21 -4.23 -1.412 0.72308E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23232E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47097E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90674E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.42 -2.01 -0.671 0.34363E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60606E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73677E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.92 -2.94 -0.979 0.50168E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0209900 MOLES New total amount of reactant added: 0.0219900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0219900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4967E+00 Moles total = -.7151E+01 kg total = -.1288E+00 Activity = 0.9999 Stoichiometric ionic strength = .9585353E-02 Osmotic coef. = 0.9213 True ionic strength = .2108978E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.2676E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92550E-10 -10.0336 0.77507E-10 -10.1107 0.83746E+00 -0.0770 2 H2O 0.99994E+00 0.0000 0.99994E+00 0.0000 3 Cl- 0.53618E-03 -3.2707 0.44622E-03 -3.3504 0.83222E+00 -0.0798 4 SO4-- 0.27676E-10 -10.5579 0.14176E-10 -10.8485 0.51221E+00 -0.2906 5 HCO3- 0.57052E-04 -4.2437 0.47552E-04 -4.3228 0.83349E+00 -0.0791 6 HS- 0.11269E-02 -2.9481 0.93793E-03 -3.0278 0.83235E+00 -0.0797 7 Al+++ 0.11404E-28 -28.9429 0.25530E-29 -29.5929 0.22387E+00 -0.6500 8 H4SiO4 0.69594E-03 -3.1574 0.69594E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.14942E-06 -6.8256 0.75948E-07 -7.1195 0.50829E+00 -0.2939 10 Mg++ 0.23380E-10 -10.6312 0.11827E-10 -10.9271 0.50586E+00 -0.2960 11 Fe++ 0.64439E-13 -13.1908 0.32635E-13 -13.4863 0.50644E+00 -0.2955 12 K+ 0.16406E-03 -3.7850 0.13678E-03 -3.8640 0.83369E+00 -0.0790 13 Na+ 0.20820E-01 -1.6815 0.17324E-01 -1.7614 0.83206E+00 -0.0798 14 Mn++ 0.20715E-10 -10.6837 0.10500E-10 -10.9788 0.50688E+00 -0.2951 15 F- 0.11062E-05 -5.9562 0.91862E-06 -6.0369 0.83043E+00 -0.0807 16 HPO4-- 0.42099E-07 -7.3757 0.21566E-07 -7.6662 0.51228E+00 -0.2905 18 HSiO3- 0.10075E-01 -1.9968 0.83845E-02 -2.0765 0.83222E+00 -0.0798 19 Ca(HSiO3)+ 0.17391E-07 -7.7597 0.14502E-07 -7.8386 0.83388E+00 -0.0789 20 Mg(HSiO3)+ 0.33704E-11 -11.4723 0.28105E-11 -11.5512 0.83388E+00 -0.0789 21 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.69330E-16 -16.1591 0.57813E-16 -16.2380 0.83388E+00 -0.0789 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.51070E-05 -5.2918 0.42422E-05 -5.3724 0.83065E+00 -0.0806 26 CH4,aq 0.30650E-02 -2.5136 0.30560E-02 -2.5148 0.99707E+00 -0.0013 27 C2H6,aq 0.13826E-09 -9.8593 0.13785E-09 -9.8606 0.99707E+00 -0.0013 28 C3H8,aq 0.14399E-15 -15.8417 0.14356E-15 -15.8430 0.99707E+00 -0.0013 30 ethanol,aq 0.50746E-17 -17.2946 0.50597E-17 -17.2959 0.99707E+00 -0.0013 31 CO,aq 0.22915E-14 -14.6399 0.22915E-14 -14.6399 0.10000E+01 0.0000 32 CO2,aq 0.78989E-08 -8.1024 0.78757E-08 -8.1037 0.99707E+00 -0.0013 33 CO3-2 0.10485E-03 -3.9794 0.53588E-04 -4.2709 0.51107E+00 -0.2915 34 CaCO3,aq 0.51032E-07 -7.2922 0.51032E-07 -7.2922 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11055E-09 -9.9564 0.92186E-10 -10.0353 0.83388E+00 -0.0789 36 CaCl+ 0.65770E-10 -10.1820 0.54844E-10 -10.2609 0.83388E+00 -0.0789 37 CaCl2,aq 0.58142E-14 -14.2355 0.58142E-14 -14.2355 0.10000E+01 0.0000 38 CaF+ 0.12215E-11 -11.9131 0.10186E-11 -11.9920 0.83388E+00 -0.0789 39 CaOH+ 0.83743E-07 -7.0771 0.69832E-07 -7.1559 0.83388E+00 -0.0789 40 CaSO4,aq 0.34188E-15 -15.4661 0.34188E-15 -15.4661 0.10000E+01 0.0000 41 HCl,aq 0.63376E-14 -14.1981 0.63376E-14 -14.1981 0.10000E+01 0.0000 45 HF,aq 0.48741E-12 -12.3121 0.48741E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18165E-18 -18.7408 0.15117E-18 -18.8205 0.83222E+00 -0.0798 48 FeCl+ 0.27642E-16 -16.5584 0.23050E-16 -16.6373 0.83388E+00 -0.0789 51 FeF+ 0.18372E-17 -17.7359 0.15320E-17 -17.8147 0.83388E+00 -0.0789 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16435E-10 -10.7842 0.13705E-10 -10.8631 0.83388E+00 -0.0789 55 HFeO2- 0.34245E-07 -7.4654 0.28499E-07 -7.5452 0.83222E+00 -0.0798 56 FeO+ 0.11519E-16 -16.9386 0.96054E-17 -17.0175 0.83388E+00 -0.0789 58 FeO2- 0.39311E-09 -9.4055 0.32716E-09 -9.4852 0.83222E+00 -0.0798 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11616E-04 -4.9349 0.11582E-04 -4.9362 0.99707E+00 -0.0013 61 KCl,aq 0.11062E-08 -8.9562 0.11062E-08 -8.9562 0.10000E+01 0.0000 63 KOH,aq 0.75359E-06 -6.1229 0.75359E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.36153E-13 -13.4419 0.30088E-13 -13.5216 0.83222E+00 -0.0798 65 MgCO3,aq 0.19920E-11 -11.7007 0.19920E-11 -11.7007 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.17591E-13 -13.7547 0.14669E-13 -13.8336 0.83388E+00 -0.0789 67 MgCl+ 0.92828E-14 -14.0323 0.77408E-14 -14.1112 0.83388E+00 -0.0789 68 MgF+ 0.70465E-15 -15.1520 0.58759E-15 -15.2309 0.83388E+00 -0.0789 69 MgOH+ 0.72163E-10 -10.1417 0.60175E-10 -10.2206 0.83388E+00 -0.0789 71 MnF+ 0.19483E-15 -15.7103 0.16247E-15 -15.7892 0.83388E+00 -0.0789 72 MnO,aq 0.18100E-08 -8.7423 0.18100E-08 -8.7423 0.10000E+01 0.0000 73 MnOH+ 0.49124E-09 -9.3087 0.40963E-09 -9.3876 0.83388E+00 -0.0789 74 MnO2-2 0.19564E-10 -10.7085 0.99987E-11 -11.0001 0.51107E+00 -0.2915 75 HMnO2- 0.20401E-09 -9.6903 0.16978E-09 -9.7701 0.83222E+00 -0.0798 78 MnCl+ 0.34600E-13 -13.4609 0.28852E-13 -13.5398 0.83388E+00 -0.0789 79 MnSO4,aq 0.42971E-19 -19.3668 0.42971E-19 -19.3668 0.10000E+01 0.0000 80 NaCl,aq 0.25618E-05 -5.5915 0.25618E-05 -5.5915 0.10000E+01 0.0000 81 NaF,aq 0.37257E-08 -8.4288 0.37257E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96026E-04 -4.0176 0.96026E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.89737E-02 -2.0470 0.74540E-02 -2.1276 0.83065E+00 -0.0806 89 HPO3-2 0.15231E-14 -14.8173 0.77844E-15 -15.1088 0.51107E+00 -0.2915 91 H2PO3- 0.14538E-18 -18.8375 0.12099E-18 -18.9173 0.83222E+00 -0.0798 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.37016E-10 -10.4316 0.30836E-10 -10.5109 0.83304E+00 -0.0793 94 PO4-3 0.96353E-09 -9.0161 0.22702E-09 -9.6439 0.23561E+00 -0.6278 98 HP2O7-3 0.85708E-18 -18.0670 0.19208E-18 -18.7165 0.22411E+00 -0.6495 99 P2O7-4 0.81097E-17 -17.0910 0.59204E-18 -18.2276 0.73004E-01 -1.1367 100 H2S,aq 0.22534E-06 -6.6472 0.22468E-06 -6.6484 0.99707E+00 -0.0013 101 S2-2 0.32932E-11 -11.4824 0.16830E-11 -11.7739 0.51107E+00 -0.2915 102 S3-2 0.86068E-19 -19.0652 0.43987E-19 -19.3567 0.51107E+00 -0.2915 107 SO3-2 0.41129E-16 -16.3859 0.21337E-16 -16.6709 0.51877E+00 -0.2850 108 HSO3- 0.12442E-18 -18.9051 0.10355E-18 -18.9849 0.83222E+00 -0.0798 109 HSO4- 0.12685E-17 -17.8967 0.10589E-17 -17.9752 0.83473E+00 -0.0785 111 S2O3-2 0.73210E-19 -19.1354 0.37416E-19 -19.4269 0.51107E+00 -0.2915 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9254994E-10 -.2162283E-01 -.2175462E+02 0.0000 2 H2O 0.1000000E+01 0.5550798E+02 0.9981625E+06 0.0000 3 Cl- 0.5361840E-03 0.5387470E-03 0.1906524E+02 6.7602 4 SO4-- 0.2767613E-10 -.3067897E-02 -.2941676E+03 9.3729 5 HCO3- 0.5705171E-04 0.3226958E-02 0.1965395E+03 5.7878 6 HS- 0.1126855E-02 0.4194977E-02 0.1384823E+03 7.0828 7 Al+++ 0.1140389E-28 0.5107154E-05 0.1375464E+00 0.7390 8 H4SiO4 0.6959364E-03 0.1312009E-01 0.1258735E+04 -3.1574 9 Ca++ 0.1494191E-06 0.3017628E-06 0.1207191E-01 13.1018 10 Mg++ 0.2337992E-10 0.1009324E-09 0.2449377E-05 9.2942 11 Fe++ 0.6443929E-13 0.3486879E-07 0.1943753E-02 6.7350 12 K+ 0.1640618E-03 0.1648165E-03 0.6432859E+01 6.2467 13 Na+ 0.2082027E-01 0.2326810E-01 0.5339498E+03 8.3493 14 Mn++ 0.2071523E-10 0.2545563E-08 0.1395922E-03 9.2425 15 F- 0.1106194E-05 0.1109922E-05 0.2104770E-01 4.0738 16 HPO4-- 0.4209869E-07 0.4309924E-07 0.4129050E-02 12.5551 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279018E+02 -.1074084E-01 -.8277944E+02 0.0000000E+00 2 H2O -.7150786E+01 0.2757283E+02 -.3472361E+02 0.0000000E+00 3 Cl- 0.2676152E-03 0.2676152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1386975E+00 -.1523936E-02 0.1402215E+00 0.0000000E+00 5 HCO3- 0.1602947E-02 0.1602947E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1381377E+00 0.2083797E-02 -.1402215E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2536909E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6517225E-02 0.5205739E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1498965E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5013678E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1732060E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8187035E-04 0.1061489E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1155811E-01 0.6264819E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1264474E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8896000E-05 0.5513384E-06 0.8344662E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2140896E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1263E-14 Mass of aqueous solution: 0.497647E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0219900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 629.9 andradite 0.5609 -0.251 285.0 2.455 5.218 74.05 grossular 0.1358 -0.867 61.18 1.787 1.120 17.02 apatite-OH 0.9854E-02 -2.006 4.950 0.695 0.9062E-01 1.573 apatite-F 0.8345E-05 -5.079 0.4208E-02 -2.376 0.7704E-04 0.1315E-02 clinochlore 0.7088 -0.149 394.0 2.595 7.212 149.9 daphnite 0.2052 -0.688 146.4 2.166 2.680 44.37 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2206 -0.656 47.77 1.679 0.8745 14.60 hedenbergite 0.5721E-01 -1.243 14.19 1.152 0.2598 3.888 microcline 0.9325 -0.030 259.6 2.414 4.752 101.4 stilbite 3.221 0.508 2270. 3.356 41.56 1059. stilpnomelane-Fe 0.2580 -0.588 278.1 2.444 5.091 96.06 tr.625ac.25prg.125 0.5622E-01 -1.250 48.05 1.682 0.8797 15.47 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1862E-01 0.1862E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.344576 g Volume = 2210.838541 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0219900 moles log = -1.6578 Original solution: 1000.0103000 g Original solution / Rock added: 45475.68 (Water/Rock Ratio), log = 4.6578 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 5.5547 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1866E+00 0.9702 0.1006E+01 0.1037E+01 CO2,gas 0.1534E-06 0.9889 0.8426E-06 0.8520E-06 CH4,gas 0.8106E+00 0.9990 0.4498E+01 0.4503E+01 H2,gas 0.2729E-02 1.0030 0.1521E-01 0.1516E-01 H2S,gas 0.1136E-05 0.9787 0.6176E-05 0.6311E-05 S2,gas 0.1115E-26 1.0000 0.6193E-26 0.6193E-26 CO,gas 0.6148E-12 1.0000 0.3415E-11 0.3415E-11 SO3,gas 0.5797E-47 1.0000 0.3220E-46 0.3220E-46 SO2,gas 0.3430E-26 1.0000 0.1905E-25 0.1905E-25 HF,gas 0.2154E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.2013E-17 1.0000 0.1118E-16 0.1118E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.43 -7.77 -2.591 0.13273E+05 -6.074 3 CH4,gas 4.54 3.50 -1.05 -0.261 0.17859E+04 0.653 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.14 -6.91 -3.454 0.11796E+05 -5.209 6 S2,gas -7.34 -35.24 -27.91 -4.293 0.47651E+05 -26.208 7 CO,gas 3.21 -9.95 -13.17 -4.051 0.22480E+05 -11.467 8 SO3,gas 17.12 -31.07 -48.19 -12.048 0.82285E+05 -46.492 9 SO2,gas 0.83 -26.59 -27.42 -7.312 0.46817E+05 -25.720 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.46 -18.65 -9.325 0.31845E+05 -16.951 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80662E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93633E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.33 -2.30 -0.766 0.39241E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.33 -2.14 -0.714 0.36599E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68939E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65533E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.47 -2.37 -0.676 0.40389E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.47 -1.92 -0.549 0.32812E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82226E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -24.02 -2.78 -0.654 0.47431E+04 146 pyrrhotite -4.26 -6.40 -2.14 -0.714 0.36594E+04 147 pyrrhotiteFe0.875 -6.02 -7.80 -1.78 -0.656 0.30466E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22429E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28677E+03 154 rhodochrosite -0.98 -5.19 -4.21 -1.405 0.71964E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23231E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47096E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90674E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.40 -1.99 -0.664 0.34022E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60606E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.90 -2.92 -0.973 0.49826E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0219900 MOLES New total amount of reactant added: 0.0229900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0229900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4968E+00 Moles total = -.7150E+01 kg total = -.1288E+00 Activity = 0.9999 Stoichiometric ionic strength = .9500918E-02 Osmotic coef. = 0.9217 True ionic strength = .2113483E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.2735E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92729E-10 -10.0328 0.77646E-10 -10.1099 0.83735E+00 -0.0771 2 H2O 0.99994E+00 0.0000 0.99994E+00 0.0000 3 Cl- 0.54798E-03 -3.2612 0.45597E-03 -3.3411 0.83210E+00 -0.0798 4 SO4-- 0.28837E-10 -10.5401 0.14762E-10 -10.8309 0.51191E+00 -0.2908 5 HCO3- 0.59534E-04 -4.2252 0.49613E-04 -4.3044 0.83337E+00 -0.0792 6 HS- 0.11757E-02 -2.9297 0.97846E-03 -3.0095 0.83222E+00 -0.0798 7 Al+++ 0.11480E-28 -28.9400 0.25668E-29 -29.5906 0.22358E+00 -0.6506 8 H4SiO4 0.69593E-03 -3.1574 0.69593E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15004E-06 -6.8238 0.76221E-07 -7.1179 0.50799E+00 -0.2941 10 Mg++ 0.23478E-10 -10.6293 0.11870E-10 -10.9256 0.50557E+00 -0.2962 11 Fe++ 0.64709E-13 -13.1890 0.32752E-13 -13.4848 0.50614E+00 -0.2957 12 K+ 0.16438E-03 -3.7842 0.13702E-03 -3.8632 0.83357E+00 -0.0791 13 Na+ 0.20861E-01 -1.6807 0.17355E-01 -1.7606 0.83194E+00 -0.0799 14 Mn++ 0.20804E-10 -10.6819 0.10539E-10 -10.9772 0.50658E+00 -0.2954 15 F- 0.11044E-05 -5.9569 0.91697E-06 -6.0376 0.83031E+00 -0.0808 16 HPO4-- 0.41972E-07 -7.3770 0.21489E-07 -7.6678 0.51199E+00 -0.2907 18 HSiO3- 0.10058E-01 -1.9975 0.83695E-02 -2.0773 0.83210E+00 -0.0798 19 Ca(HSiO3)+ 0.17425E-07 -7.7588 0.14528E-07 -7.8378 0.83376E+00 -0.0790 20 Mg(HSiO3)+ 0.33770E-11 -11.4715 0.28156E-11 -11.5504 0.83376E+00 -0.0790 21 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.69464E-16 -16.1582 0.57917E-16 -16.2372 0.83376E+00 -0.0790 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.50986E-05 -5.2925 0.42346E-05 -5.3732 0.83053E+00 -0.0806 26 CH4,aq 0.32035E-02 -2.4944 0.31942E-02 -2.4956 0.99709E+00 -0.0013 27 C2H6,aq 0.15104E-09 -9.8209 0.15060E-09 -9.8222 0.99709E+00 -0.0013 28 C3H8,aq 0.16441E-15 -15.7841 0.16394E-15 -15.7853 0.99709E+00 -0.0013 30 ethanol,aq 0.55438E-17 -17.2562 0.55277E-17 -17.2575 0.99709E+00 -0.0013 31 CO,aq 0.23952E-14 -14.6207 0.23952E-14 -14.6207 0.10000E+01 0.0000 32 CO2,aq 0.82559E-08 -8.0832 0.82319E-08 -8.0845 0.99709E+00 -0.0013 33 CO3-2 0.10927E-03 -3.9615 0.55811E-04 -4.2533 0.51078E+00 -0.2918 34 CaCO3,aq 0.53340E-07 -7.2729 0.53340E-07 -7.2729 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11577E-09 -9.9364 0.96528E-10 -10.0153 0.83376E+00 -0.0790 36 CaCl+ 0.67458E-10 -10.1710 0.56244E-10 -10.2499 0.83376E+00 -0.0790 37 CaCl2,aq 0.60928E-14 -14.2152 0.60928E-14 -14.2152 0.10000E+01 0.0000 38 CaF+ 0.12239E-11 -11.9123 0.10204E-11 -11.9912 0.83376E+00 -0.0790 39 CaOH+ 0.83905E-07 -7.0762 0.69957E-07 -7.1552 0.83376E+00 -0.0790 40 CaSO4,aq 0.35729E-15 -15.4470 0.35729E-15 -15.4470 0.10000E+01 0.0000 41 HCl,aq 0.64877E-14 -14.1879 0.64877E-14 -14.1879 0.10000E+01 0.0000 45 HF,aq 0.48741E-12 -12.3121 0.48741E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18135E-18 -18.7415 0.15090E-18 -18.8213 0.83210E+00 -0.0798 48 FeCl+ 0.28351E-16 -16.5474 0.23638E-16 -16.6264 0.83376E+00 -0.0790 51 FeF+ 0.18407E-17 -17.7350 0.15347E-17 -17.8140 0.83376E+00 -0.0790 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16467E-10 -10.7834 0.13730E-10 -10.8623 0.83376E+00 -0.0790 55 HFeO2- 0.34188E-07 -7.4661 0.28448E-07 -7.5459 0.83210E+00 -0.0798 56 FeO+ 0.11541E-16 -16.9377 0.96226E-17 -17.0167 0.83376E+00 -0.0790 58 FeO2- 0.39247E-09 -9.4062 0.32657E-09 -9.4860 0.83210E+00 -0.0798 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11616E-04 -4.9350 0.11582E-04 -4.9362 0.99709E+00 -0.0013 61 KCl,aq 0.11324E-08 -8.9460 0.11324E-08 -8.9460 0.10000E+01 0.0000 63 KOH,aq 0.75358E-06 -6.1229 0.75358E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.37721E-13 -13.4234 0.31387E-13 -13.5032 0.83210E+00 -0.0798 65 MgCO3,aq 0.20821E-11 -11.6815 0.20821E-11 -11.6815 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.18423E-13 -13.7347 0.15360E-13 -13.8136 0.83376E+00 -0.0790 67 MgCl+ 0.95211E-14 -14.0213 0.79383E-14 -14.1003 0.83376E+00 -0.0790 68 MgF+ 0.70601E-15 -15.1512 0.58865E-15 -15.2301 0.83376E+00 -0.0790 69 MgOH+ 0.72302E-10 -10.1408 0.60283E-10 -10.2198 0.83376E+00 -0.0790 71 MnF+ 0.19523E-15 -15.7095 0.16277E-15 -15.7884 0.83376E+00 -0.0790 72 MnO,aq 0.18102E-08 -8.7423 0.18102E-08 -8.7423 0.10000E+01 0.0000 73 MnOH+ 0.49224E-09 -9.3078 0.41041E-09 -9.3868 0.83376E+00 -0.0790 74 MnO2-2 0.19507E-10 -10.7098 0.99638E-11 -11.0016 0.51078E+00 -0.2918 75 HMnO2- 0.20370E-09 -9.6910 0.16949E-09 -9.7708 0.83210E+00 -0.0798 78 MnCl+ 0.35492E-13 -13.4499 0.29592E-13 -13.5288 0.83376E+00 -0.0790 79 MnSO4,aq 0.44913E-19 -19.3476 0.44913E-19 -19.3476 0.10000E+01 0.0000 80 NaCl,aq 0.26225E-05 -5.5813 0.26225E-05 -5.5813 0.10000E+01 0.0000 81 NaF,aq 0.37257E-08 -8.4288 0.37257E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96025E-04 -4.0176 0.96025E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.89589E-02 -2.0477 0.74407E-02 -2.1284 0.83053E+00 -0.0806 89 HPO3-2 0.15186E-14 -14.8186 0.77565E-15 -15.1103 0.51078E+00 -0.2918 91 H2PO3- 0.14514E-18 -18.8382 0.12077E-18 -18.9180 0.83210E+00 -0.0798 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36955E-10 -10.4323 0.30780E-10 -10.5117 0.83292E+00 -0.0794 94 PO4-3 0.95953E-09 -9.0179 0.22580E-09 -9.6463 0.23533E+00 -0.6283 98 HP2O7-3 0.85359E-18 -18.0687 0.19105E-18 -18.7189 0.22382E+00 -0.6501 99 P2O7-4 0.80699E-17 -17.0931 0.58781E-18 -18.2308 0.72839E-01 -1.1376 100 H2S,aq 0.23549E-06 -6.6280 0.23481E-06 -6.6293 0.99709E+00 -0.0013 101 S2-2 0.35860E-11 -11.4454 0.18316E-11 -11.7372 0.51078E+00 -0.2918 102 S3-2 0.97947E-19 -19.0090 0.50029E-19 -19.3008 0.51078E+00 -0.2918 107 SO3-2 0.42853E-16 -16.3680 0.22219E-16 -16.6533 0.51849E+00 -0.2853 108 HSO3- 0.12982E-18 -18.8867 0.10802E-18 -18.9665 0.83210E+00 -0.0798 109 HSO4- 0.13235E-17 -17.8783 0.11046E-17 -17.9568 0.83461E+00 -0.0785 111 S2O3-2 0.79719E-19 -19.0984 0.40719E-19 -19.3902 0.51078E+00 -0.2918 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9272884E-10 -.2159586E-01 -.2172739E+02 0.0000 2 H2O 0.1000000E+01 0.5550812E+02 0.9981610E+06 0.0000 3 Cl- 0.5479806E-03 0.5506043E-03 0.1948476E+02 6.7688 4 SO4-- 0.2883671E-10 -.3206426E-02 -.3074493E+03 9.3889 5 HCO3- 0.5953376E-04 0.3372384E-02 0.2053959E+03 5.8055 6 HS- 0.1175721E-02 0.4382382E-02 0.1446682E+03 7.1004 7 Al+++ 0.1148040E-28 0.5098775E-05 0.1373202E+00 0.7390 8 H4SiO4 0.6959345E-03 0.1310350E-01 0.1257137E+04 -3.1574 9 Ca++ 0.1500434E-06 0.3048981E-06 0.1219729E-01 13.1018 10 Mg++ 0.2347778E-10 0.1012684E-09 0.2457521E-05 9.2942 11 Fe++ 0.6470904E-13 0.3481176E-07 0.1940566E-02 6.7350 12 K+ 0.1643790E-03 0.1651337E-03 0.6445211E+01 6.2467 13 Na+ 0.2086059E-01 0.2330845E-01 0.5348736E+03 8.3493 14 Mn++ 0.2080393E-10 0.2546454E-08 0.1396404E-03 9.2426 15 F- 0.1104376E-05 0.1108103E-05 0.2101313E-01 4.0722 16 HPO4-- 0.4197180E-07 0.4296828E-07 0.4116487E-02 12.5520 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279007E+02 -.1072784E-01 -.8277934E+02 0.0000000E+00 2 H2O -.7149967E+01 0.2757391E+02 -.3472388E+02 0.0000000E+00 3 Cl- 0.2735152E-03 0.2735152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387023E+00 -.1592807E-02 0.1402951E+00 0.0000000E+00 5 HCO3- 0.1675247E-02 0.1675247E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1381181E+00 0.2176968E-02 -.1402951E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2532840E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6509222E-02 0.5205740E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1514595E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5030554E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1729290E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8203090E-04 0.1061489E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1157858E-01 0.6264798E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1264962E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9296000E-05 0.5504554E-06 0.8745545E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2134469E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.2479E-13 Mass of aqueous solution: 0.497667E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0229900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 629.9 andradite 0.5612 -0.251 285.2 2.455 5.221 74.09 grossular 0.1359 -0.867 61.21 1.787 1.121 17.03 apatite-OH 0.9854E-02 -2.006 4.950 0.695 0.9062E-01 1.573 apatite-F 0.8746E-05 -5.058 0.4410E-02 -2.356 0.8074E-04 0.1378E-02 clinochlore 0.7087 -0.150 393.9 2.595 7.212 149.8 daphnite 0.2052 -0.688 146.4 2.166 2.680 44.36 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2187 -0.660 47.35 1.675 0.8669 14.47 hedenbergite 0.5671E-01 -1.246 14.07 1.148 0.2576 3.854 microcline 0.9326 -0.030 259.6 2.414 4.752 101.4 stilbite 3.221 0.508 2270. 3.356 41.56 1059. stilpnomelane-Fe 0.2578 -0.589 277.9 2.444 5.088 96.00 tr.625ac.25prg.125 0.5684E-01 -1.245 48.59 1.687 0.8895 15.64 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1862E-01 0.1862E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.344865 g Volume = 2210.841303 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0229900 moles log = -1.6385 Original solution: 1000.0103000 g Original solution / Rock added: 43497.62 (Water/Rock Ratio), log = 4.6385 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 5.7597 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1801E+00 0.9699 0.1006E+01 0.1037E+01 CO2,gas 0.1547E-06 0.9885 0.8807E-06 0.8910E-06 CH4,gas 0.8173E+00 0.9988 0.4702E+01 0.4707E+01 H2,gas 0.2632E-02 1.0031 0.1521E-01 0.1516E-01 H2S,gas 0.1146E-05 0.9779 0.6455E-05 0.6600E-05 S2,gas 0.1174E-26 1.0000 0.6764E-26 0.6764E-26 CO,gas 0.6197E-12 1.0000 0.3569E-11 0.3569E-11 SO3,gas 0.5843E-47 1.0000 0.3365E-46 0.3365E-46 SO2,gas 0.3457E-26 1.0000 0.1991E-25 0.1991E-25 HF,gas 0.2078E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1988E-17 1.0000 0.1145E-16 0.1145E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.41 -7.75 -2.585 0.13240E+05 -6.055 3 CH4,gas 4.54 3.52 -1.03 -0.257 0.17531E+04 0.672 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.12 -6.89 -3.445 0.11763E+05 -5.190 6 S2,gas -7.34 -35.20 -27.87 -4.288 0.47585E+05 -26.170 7 CO,gas 3.21 -9.93 -13.15 -4.045 0.22447E+05 -11.447 8 SO3,gas 17.12 -31.05 -48.17 -12.043 0.82252E+05 -46.473 9 SO2,gas 0.83 -26.57 -27.40 -7.307 0.46785E+05 -25.701 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.45 -18.64 -9.320 0.31828E+05 -16.941 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80659E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93633E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.31 -2.28 -0.760 0.38913E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.31 -2.12 -0.708 0.36271E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68939E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65532E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.45 -2.35 -0.670 0.40061E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.45 -1.90 -0.544 0.32484E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82225E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.99 -2.74 -0.645 0.46777E+04 146 pyrrhotite -4.26 -6.38 -2.12 -0.708 0.36267E+04 147 pyrrhotiteFe0.875 -6.02 -7.78 -1.77 -0.649 0.30139E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22428E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28676E+03 154 rhodochrosite -0.98 -5.17 -4.20 -1.398 0.71635E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23231E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47094E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90674E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.38 -1.97 -0.658 0.33695E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60606E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.88 -2.90 -0.966 0.49498E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0229900 MOLES New total amount of reactant added: 0.0239900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0239900 Water: Moles liquid = 0.2757E+02 kg liquid = 0.4968E+00 Moles total = -.7149E+01 kg total = -.1288E+00 Activity = 0.9999 Stoichiometric ionic strength = .9416455E-02 Osmotic coef. = 0.9221 True ionic strength = .2117987E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.2794E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92908E-10 -10.0319 0.77786E-10 -10.1091 0.83723E+00 -0.0772 2 H2O 0.99994E+00 0.0000 0.99994E+00 0.0000 3 Cl- 0.55978E-03 -3.2520 0.46572E-03 -3.3319 0.83197E+00 -0.0799 4 SO4-- 0.29994E-10 -10.5230 0.15346E-10 -10.8140 0.51162E+00 -0.2910 5 HCO3- 0.62008E-04 -4.2076 0.51668E-04 -4.2868 0.83324E+00 -0.0792 6 HS- 0.12246E-02 -2.9120 0.10190E-02 -2.9918 0.83210E+00 -0.0798 7 Al+++ 0.11557E-28 -28.9371 0.25807E-29 -29.5883 0.22329E+00 -0.6511 8 H4SiO4 0.69593E-03 -3.1574 0.69593E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15067E-06 -6.8220 0.76494E-07 -7.1164 0.50770E+00 -0.2944 10 Mg++ 0.23576E-10 -10.6275 0.11912E-10 -10.9240 0.50527E+00 -0.2965 11 Fe++ 0.64980E-13 -13.1872 0.32870E-13 -13.4832 0.50585E+00 -0.2960 12 K+ 0.16470E-03 -3.7833 0.13727E-03 -3.8624 0.83345E+00 -0.0791 13 Na+ 0.20901E-01 -1.6798 0.17386E-01 -1.7598 0.83181E+00 -0.0800 14 Mn++ 0.20893E-10 -10.6800 0.10578E-10 -10.9756 0.50628E+00 -0.2956 15 F- 0.11026E-05 -5.9576 0.91533E-06 -6.0384 0.83018E+00 -0.0808 16 HPO4-- 0.41845E-07 -7.3784 0.21412E-07 -7.6693 0.51170E+00 -0.2910 18 HSiO3- 0.10042E-01 -1.9982 0.83545E-02 -2.0781 0.83197E+00 -0.0799 19 Ca(HSiO3)+ 0.17459E-07 -7.7580 0.14554E-07 -7.8370 0.83364E+00 -0.0790 20 Mg(HSiO3)+ 0.33835E-11 -11.4706 0.28206E-11 -11.5497 0.83364E+00 -0.0790 21 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.69599E-16 -16.1574 0.58021E-16 -16.2364 0.83364E+00 -0.0790 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.50903E-05 -5.2933 0.42270E-05 -5.3740 0.83040E+00 -0.0807 26 CH4,aq 0.33421E-02 -2.4760 0.33324E-02 -2.4772 0.99712E+00 -0.0013 27 C2H6,aq 0.16439E-09 -9.7841 0.16392E-09 -9.7854 0.99712E+00 -0.0013 28 C3H8,aq 0.18669E-15 -15.7289 0.18616E-15 -15.7301 0.99712E+00 -0.0013 30 ethanol,aq 0.60339E-17 -17.2194 0.60165E-17 -17.2207 0.99712E+00 -0.0013 31 CO,aq 0.24989E-14 -14.6023 0.24989E-14 -14.6023 0.10000E+01 0.0000 32 CO2,aq 0.86130E-08 -8.0648 0.85882E-08 -8.0661 0.99712E+00 -0.0013 33 CO3-2 0.11365E-03 -3.9444 0.58018E-04 -4.2364 0.51049E+00 -0.2920 34 CaCO3,aq 0.55649E-07 -7.2545 0.55649E-07 -7.2545 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.12102E-09 -9.9171 0.10089E-09 -9.9962 0.83364E+00 -0.0790 36 CaCl+ 0.69157E-10 -10.1602 0.57652E-10 -10.2392 0.83364E+00 -0.0790 37 CaCl2,aq 0.63789E-14 -14.1953 0.63789E-14 -14.1953 0.10000E+01 0.0000 38 CaF+ 0.12263E-11 -11.9114 0.10223E-11 -11.9904 0.83364E+00 -0.0790 39 CaOH+ 0.84068E-07 -7.0754 0.70082E-07 -7.1544 0.83364E+00 -0.0790 40 CaSO4,aq 0.37275E-15 -15.4286 0.37275E-15 -15.4286 0.10000E+01 0.0000 41 HCl,aq 0.66383E-14 -14.1779 0.66383E-14 -14.1779 0.10000E+01 0.0000 45 HF,aq 0.48741E-12 -12.3121 0.48741E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18105E-18 -18.7422 0.15063E-18 -18.8221 0.83197E+00 -0.0799 48 FeCl+ 0.29065E-16 -16.5366 0.24230E-16 -16.6156 0.83364E+00 -0.0790 51 FeF+ 0.18443E-17 -17.7342 0.15375E-17 -17.8132 0.83364E+00 -0.0790 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16499E-10 -10.7825 0.13754E-10 -10.8616 0.83364E+00 -0.0790 55 HFeO2- 0.34132E-07 -7.4668 0.28397E-07 -7.5467 0.83197E+00 -0.0799 56 FeO+ 0.11564E-16 -16.9369 0.96399E-17 -17.0159 0.83364E+00 -0.0790 58 FeO2- 0.39182E-09 -9.4069 0.32599E-09 -9.4868 0.83197E+00 -0.0799 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11615E-04 -4.9350 0.11582E-04 -4.9362 0.99712E+00 -0.0013 61 KCl,aq 0.11586E-08 -8.9361 0.11586E-08 -8.9361 0.10000E+01 0.0000 63 KOH,aq 0.75357E-06 -6.1229 0.75357E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.39288E-13 -13.4057 0.32687E-13 -13.4856 0.83197E+00 -0.0799 65 MgCO3,aq 0.21722E-11 -11.6631 0.21722E-11 -11.6631 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.19257E-13 -13.7154 0.16053E-13 -13.7944 0.83364E+00 -0.0790 67 MgCl+ 0.97610E-14 -14.0105 0.81371E-14 -14.0895 0.83364E+00 -0.0790 68 MgF+ 0.70738E-15 -15.1503 0.58970E-15 -15.2294 0.83364E+00 -0.0790 69 MgOH+ 0.72442E-10 -10.1400 0.60391E-10 -10.2190 0.83364E+00 -0.0790 71 MnF+ 0.19563E-15 -15.7086 0.16308E-15 -15.7876 0.83364E+00 -0.0790 72 MnO,aq 0.18103E-08 -8.7422 0.18103E-08 -8.7422 0.10000E+01 0.0000 73 MnOH+ 0.49324E-09 -9.3069 0.41118E-09 -9.3860 0.83364E+00 -0.0790 74 MnO2-2 0.19450E-10 -10.7111 0.99291E-11 -11.0031 0.51049E+00 -0.2920 75 HMnO2- 0.20338E-09 -9.6917 0.16921E-09 -9.7716 0.83197E+00 -0.0799 78 MnCl+ 0.36389E-13 -13.4390 0.30336E-13 -13.5180 0.83364E+00 -0.0790 79 MnSO4,aq 0.46861E-19 -19.3292 0.46861E-19 -19.3292 0.10000E+01 0.0000 80 NaCl,aq 0.26833E-05 -5.5713 0.26833E-05 -5.5713 0.10000E+01 0.0000 81 NaF,aq 0.37257E-08 -8.4288 0.37257E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96024E-04 -4.0176 0.96024E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.89442E-02 -2.0485 0.74273E-02 -2.1292 0.83040E+00 -0.0807 89 HPO3-2 0.15140E-14 -14.8199 0.77288E-15 -15.1119 0.51049E+00 -0.2920 91 H2PO3- 0.14490E-18 -18.8389 0.12056E-18 -18.9188 0.83197E+00 -0.0799 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36894E-10 -10.4330 0.30725E-10 -10.5125 0.83280E+00 -0.0795 94 PO4-3 0.95554E-09 -9.0197 0.22459E-09 -9.6486 0.23504E+00 -0.6289 98 HP2O7-3 0.85012E-18 -18.0705 0.19003E-18 -18.7212 0.22353E+00 -0.6507 99 P2O7-4 0.80304E-17 -17.0953 0.58361E-18 -18.2339 0.72675E-01 -1.1386 100 H2S,aq 0.24568E-06 -6.6096 0.24497E-06 -6.6109 0.99712E+00 -0.0013 101 S2-2 0.38913E-11 -11.4099 0.19865E-11 -11.7019 0.51049E+00 -0.2920 102 S3-2 0.11089E-18 -18.9551 0.56606E-19 -19.2471 0.51049E+00 -0.2920 107 SO3-2 0.44572E-16 -16.3509 0.23097E-16 -16.6364 0.51821E+00 -0.2855 108 HSO3- 0.13521E-18 -18.8690 0.11249E-18 -18.9489 0.83197E+00 -0.0799 109 HSO4- 0.13785E-17 -17.8606 0.11504E-17 -17.9392 0.83449E+00 -0.0786 111 S2O3-2 0.86508E-19 -19.0629 0.44161E-19 -19.3550 0.51049E+00 -0.2920 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9290785E-10 -.2156895E-01 -.2170023E+02 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9981594E+06 0.0000 3 Cl- 0.5597762E-03 0.5624608E-03 0.1990426E+02 6.7772 4 SO4-- 0.2999401E-10 -.3344978E-02 -.3207332E+03 9.4042 5 HCO3- 0.6200819E-04 0.3517800E-02 0.2142516E+03 5.8223 6 HS- 0.1224583E-02 0.4569807E-02 0.1508548E+03 7.1173 7 Al+++ 0.1155733E-28 0.5090421E-05 0.1370947E+00 0.7390 8 H4SiO4 0.6959325E-03 0.1308695E-01 0.1255545E+04 -3.1574 9 Ca++ 0.1506695E-06 0.3080358E-06 0.1232276E-01 13.1018 10 Mg++ 0.2357593E-10 0.1016053E-09 0.2465686E-05 9.2942 11 Fe++ 0.6497957E-13 0.3475489E-07 0.1937388E-02 6.7350 12 K+ 0.1646963E-03 0.1654510E-03 0.6457571E+01 6.2467 13 Na+ 0.2090093E-01 0.2334883E-01 0.5357981E+03 8.3493 14 Mn++ 0.2089289E-10 0.2547347E-08 0.1396888E-03 9.2426 15 F- 0.1102563E-05 0.1106290E-05 0.2097866E-01 4.0707 16 HPO4-- 0.4184544E-07 0.4283788E-07 0.4103978E-02 12.5489 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278996E+02 -.1071486E-01 -.8277925E+02 0.0000000E+00 2 H2O -.7149148E+01 0.2757499E+02 -.3472414E+02 0.0000000E+00 3 Cl- 0.2794152E-03 0.2794152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387071E+00 -.1661694E-02 0.1403688E+00 0.0000000E+00 5 HCO3- 0.1747547E-02 0.1747547E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1380986E+00 0.2270155E-02 -.1403688E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2528782E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6501242E-02 0.5205740E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1530238E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5047474E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1726528E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8219156E-04 0.1061489E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1159906E-01 0.6264778E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1265453E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9696000E-05 0.5495750E-06 0.9146425E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2128069E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.3303E-14 Mass of aqueous solution: 0.497688E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0239900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.258 0.796 1641. 3.215 30.04 629.9 andradite 0.5615 -0.251 285.3 2.455 5.224 74.13 grossular 0.1360 -0.867 61.24 1.787 1.121 17.04 apatite-OH 0.9853E-02 -2.006 4.950 0.695 0.9061E-01 1.573 apatite-F 0.9146E-05 -5.039 0.4613E-02 -2.336 0.8444E-04 0.1441E-02 clinochlore 0.7086 -0.150 393.9 2.595 7.211 149.8 daphnite 0.2052 -0.688 146.4 2.165 2.680 44.36 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2167 -0.664 46.94 1.672 0.8593 14.35 hedenbergite 0.5621E-01 -1.250 13.95 1.144 0.2553 3.820 microcline 0.9327 -0.030 259.6 2.414 4.752 101.4 stilbite 3.221 0.508 2270. 3.356 41.56 1059. stilpnomelane-Fe 0.2577 -0.589 277.7 2.444 5.085 95.94 tr.625ac.25prg.125 0.5747E-01 -1.241 49.12 1.691 0.8993 15.81 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1862E-01 0.1862E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.345152 g Volume = 2210.844065 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0239900 moles log = -1.6200 Original solution: 1000.0103000 g Original solution / Rock added: 41684.46 (Water/Rock Ratio), log = 4.6200 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 5.9648 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1739E+00 0.9696 0.1006E+01 0.1037E+01 CO2,gas 0.1559E-06 0.9881 0.9188E-06 0.9299E-06 CH4,gas 0.8235E+00 0.9986 0.4905E+01 0.4912E+01 H2,gas 0.2541E-02 1.0032 0.1521E-01 0.1516E-01 H2S,gas 0.1155E-05 0.9771 0.6734E-05 0.6892E-05 S2,gas 0.1234E-26 1.0000 0.7362E-26 0.7362E-26 CO,gas 0.6243E-12 1.0000 0.3724E-11 0.3724E-11 SO3,gas 0.5886E-47 1.0000 0.3511E-46 0.3511E-46 SO2,gas 0.3482E-26 1.0000 0.2077E-25 0.2077E-25 HF,gas 0.2006E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1964E-17 1.0000 0.1171E-16 0.1171E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.40 -7.74 -2.579 0.13209E+05 -6.037 3 CH4,gas 4.54 3.54 -1.01 -0.252 0.17217E+04 0.691 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.10 -6.87 -3.435 0.11732E+05 -5.172 6 S2,gas -7.34 -35.17 -27.83 -4.282 0.47522E+05 -26.133 7 CO,gas 3.21 -9.91 -13.13 -4.039 0.22416E+05 -11.429 8 SO3,gas 17.12 -31.03 -48.15 -12.038 0.82221E+05 -46.455 9 SO2,gas 0.83 -26.55 -27.38 -7.302 0.46753E+05 -25.683 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.44 -18.63 -9.315 0.31811E+05 -16.931 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80657E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93633E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.29 -2.26 -0.754 0.38599E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.29 -2.11 -0.702 0.35956E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68939E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65531E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.43 -2.33 -0.665 0.39747E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.43 -1.88 -0.538 0.32169E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82224E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.95 -2.70 -0.636 0.46149E+04 146 pyrrhotite -4.26 -6.37 -2.11 -0.702 0.35953E+04 147 pyrrhotiteFe0.875 -6.02 -7.76 -1.75 -0.642 0.29825E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22427E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28676E+03 154 rhodochrosite -0.98 -5.15 -4.18 -1.392 0.71320E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23230E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27805E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47093E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90674E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.37 -1.95 -0.652 0.33381E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60606E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.86 -2.88 -0.960 0.49183E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0239900 MOLES New total amount of reactant added: 0.0249900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0249900 Water: Moles liquid = 0.2758E+02 kg liquid = 0.4968E+00 Moles total = -.7148E+01 kg total = -.1288E+00 Activity = 0.9999 Stoichiometric ionic strength = .9331963E-02 Osmotic coef. = 0.9225 True ionic strength = .2122492E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.2853E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93087E-10 -10.0311 0.77925E-10 -10.1083 0.83712E+00 -0.0772 2 H2O 0.99994E+00 0.0000 0.99994E+00 0.0000 3 Cl- 0.57157E-03 -3.2429 0.47546E-03 -3.3229 0.83185E+00 -0.0800 4 SO4-- 0.31148E-10 -10.5066 0.15927E-10 -10.7979 0.51133E+00 -0.2913 5 HCO3- 0.64475E-04 -4.1906 0.53716E-04 -4.2699 0.83312E+00 -0.0793 6 HS- 0.12734E-02 -2.8950 0.10595E-02 -2.9749 0.83198E+00 -0.0799 7 Al+++ 0.11635E-28 -28.9342 0.25946E-29 -29.5859 0.22300E+00 -0.6517 8 H4SiO4 0.69593E-03 -3.1574 0.69593E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15130E-06 -6.8202 0.76768E-07 -7.1148 0.50740E+00 -0.2946 10 Mg++ 0.23674E-10 -10.6257 0.11955E-10 -10.9225 0.50497E+00 -0.2967 11 Fe++ 0.65251E-13 -13.1854 0.32988E-13 -13.4816 0.50555E+00 -0.2962 12 K+ 0.16501E-03 -3.7825 0.13751E-03 -3.8617 0.83333E+00 -0.0792 13 Na+ 0.20941E-01 -1.6790 0.17417E-01 -1.7590 0.83169E+00 -0.0800 14 Mn++ 0.20982E-10 -10.6782 0.10617E-10 -10.9740 0.50599E+00 -0.2959 15 F- 0.11008E-05 -5.9583 0.91369E-06 -6.0392 0.83006E+00 -0.0809 16 HPO4-- 0.41720E-07 -7.3797 0.21336E-07 -7.6709 0.51141E+00 -0.2912 18 HSiO3- 0.10025E-01 -1.9989 0.83396E-02 -2.0789 0.83185E+00 -0.0800 19 Ca(HSiO3)+ 0.17492E-07 -7.7572 0.14580E-07 -7.8362 0.83352E+00 -0.0791 20 Mg(HSiO3)+ 0.33901E-11 -11.4698 0.28257E-11 -11.5489 0.83352E+00 -0.0791 21 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.69734E-16 -16.1566 0.58125E-16 -16.2356 0.83352E+00 -0.0791 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.50819E-05 -5.2940 0.42194E-05 -5.3747 0.83028E+00 -0.0808 26 CH4,aq 0.34806E-02 -2.4583 0.34707E-02 -2.4596 0.99715E+00 -0.0012 27 C2H6,aq 0.17831E-09 -9.7488 0.17781E-09 -9.7501 0.99715E+00 -0.0012 28 C3H8,aq 0.21090E-15 -15.6759 0.21030E-15 -15.6772 0.99715E+00 -0.0012 30 ethanol,aq 0.65448E-17 -17.1841 0.65261E-17 -17.1853 0.99715E+00 -0.0012 31 CO,aq 0.26025E-14 -14.5846 0.26025E-14 -14.5846 0.10000E+01 0.0000 32 CO2,aq 0.89702E-08 -8.0472 0.89446E-08 -8.0484 0.99715E+00 -0.0012 33 CO3-2 0.11801E-03 -3.9281 0.60210E-04 -4.2203 0.51020E+00 -0.2923 34 CaCO3,aq 0.57958E-07 -7.2369 0.57958E-07 -7.2369 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.12629E-09 -9.8986 0.10526E-09 -9.9777 0.83352E+00 -0.0791 36 CaCl+ 0.70867E-10 -10.1496 0.59069E-10 -10.2286 0.83352E+00 -0.0791 37 CaCl2,aq 0.66724E-14 -14.1757 0.66724E-14 -14.1757 0.10000E+01 0.0000 38 CaF+ 0.12286E-11 -11.9106 0.10241E-11 -11.9897 0.83352E+00 -0.0791 39 CaOH+ 0.84230E-07 -7.0745 0.70207E-07 -7.1536 0.83352E+00 -0.0791 40 CaSO4,aq 0.38826E-15 -15.4109 0.38826E-15 -15.4109 0.10000E+01 0.0000 41 HCl,aq 0.67893E-14 -14.1682 0.67893E-14 -14.1682 0.10000E+01 0.0000 45 HF,aq 0.48741E-12 -12.3121 0.48741E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18075E-18 -18.7429 0.15036E-18 -18.8229 0.83185E+00 -0.0800 48 FeCl+ 0.29784E-16 -16.5260 0.24826E-16 -16.6051 0.83352E+00 -0.0791 51 FeF+ 0.18479E-17 -17.7333 0.15402E-17 -17.8124 0.83352E+00 -0.0791 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16531E-10 -10.7817 0.13779E-10 -10.8608 0.83352E+00 -0.0791 55 HFeO2- 0.34076E-07 -7.4676 0.28346E-07 -7.5475 0.83185E+00 -0.0800 56 FeO+ 0.11586E-16 -16.9361 0.96572E-17 -17.0152 0.83352E+00 -0.0791 58 FeO2- 0.39118E-09 -9.4076 0.32540E-09 -9.4876 0.83185E+00 -0.0800 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11615E-04 -4.9350 0.11582E-04 -4.9362 0.99715E+00 -0.0012 61 KCl,aq 0.11850E-08 -8.9263 0.11850E-08 -8.9263 0.10000E+01 0.0000 63 KOH,aq 0.75356E-06 -6.1229 0.75356E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.40856E-13 -13.3887 0.33986E-13 -13.4687 0.83185E+00 -0.0800 65 MgCO3,aq 0.22623E-11 -11.6454 0.22623E-11 -11.6454 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.20095E-13 -13.6969 0.16749E-13 -13.7760 0.83352E+00 -0.0791 67 MgCl+ 0.10002E-13 -13.9999 0.83371E-14 -14.0790 0.83352E+00 -0.0791 68 MgF+ 0.70875E-15 -15.1495 0.59075E-15 -15.2286 0.83352E+00 -0.0791 69 MgOH+ 0.72582E-10 -10.1392 0.60499E-10 -10.2183 0.83352E+00 -0.0791 71 MnF+ 0.19602E-15 -15.7077 0.16339E-15 -15.7868 0.83352E+00 -0.0791 72 MnO,aq 0.18105E-08 -8.7422 0.18105E-08 -8.7422 0.10000E+01 0.0000 73 MnOH+ 0.49424E-09 -9.3061 0.41196E-09 -9.3851 0.83352E+00 -0.0791 74 MnO2-2 0.19394E-10 -10.7123 0.98945E-11 -11.0046 0.51020E+00 -0.2923 75 HMnO2- 0.20307E-09 -9.6924 0.16892E-09 -9.7723 0.83185E+00 -0.0800 78 MnCl+ 0.37293E-13 -13.4284 0.31084E-13 -13.5075 0.83352E+00 -0.0791 79 MnSO4,aq 0.48816E-19 -19.3114 0.48816E-19 -19.3114 0.10000E+01 0.0000 80 NaCl,aq 0.27443E-05 -5.5616 0.27443E-05 -5.5616 0.10000E+01 0.0000 81 NaF,aq 0.37256E-08 -8.4288 0.37256E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96023E-04 -4.0176 0.96023E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.89296E-02 -2.0492 0.74140E-02 -2.1299 0.83028E+00 -0.0808 89 HPO3-2 0.15094E-14 -14.8212 0.77012E-15 -15.1134 0.51020E+00 -0.2923 91 H2PO3- 0.14467E-18 -18.8396 0.12034E-18 -18.9196 0.83185E+00 -0.0800 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36833E-10 -10.4338 0.30670E-10 -10.5133 0.83268E+00 -0.0795 94 PO4-3 0.95158E-09 -9.0216 0.22339E-09 -9.6509 0.23476E+00 -0.6294 98 HP2O7-3 0.84667E-18 -18.0723 0.18901E-18 -18.7235 0.22324E+00 -0.6512 99 P2O7-4 0.79912E-17 -17.0974 0.57945E-18 -18.2370 0.72512E-01 -1.1396 100 H2S,aq 0.25589E-06 -6.5919 0.25516E-06 -6.5932 0.99715E+00 -0.0012 101 S2-2 0.42092E-11 -11.3758 0.21475E-11 -11.6681 0.51020E+00 -0.2923 102 S3-2 0.12494E-18 -18.9033 0.63742E-19 -19.1956 0.51020E+00 -0.2923 107 SO3-2 0.46286E-16 -16.3346 0.23972E-16 -16.6203 0.51792E+00 -0.2857 108 HSO3- 0.14061E-18 -18.8520 0.11696E-18 -18.9320 0.83185E+00 -0.0800 109 HSO4- 0.14335E-17 -17.8436 0.11961E-17 -17.9222 0.83437E+00 -0.0786 111 S2O3-2 0.93574E-19 -19.0288 0.47741E-19 -19.3211 0.51020E+00 -0.2923 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9308697E-10 -.2154210E-01 -.2167313E+02 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9981579E+06 0.0000 3 Cl- 0.5715707E-03 0.5743163E-03 0.2032372E+02 6.7854 4 SO4-- 0.3114806E-10 -.3483553E-02 -.3340190E+03 9.4188 5 HCO3- 0.6447501E-04 0.3663204E-02 0.2231066E+03 5.8384 6 HS- 0.1273442E-02 0.4757251E-02 0.1570419E+03 7.1334 7 Al+++ 0.1163467E-28 0.5082091E-05 0.1368698E+00 0.7390 8 H4SiO4 0.6959306E-03 0.1307046E-01 0.1253957E+04 -3.1574 9 Ca++ 0.1512974E-06 0.3111760E-06 0.1244833E-01 13.1018 10 Mg++ 0.2367437E-10 0.1019403E-09 0.2473807E-05 9.2942 11 Fe++ 0.6525088E-13 0.3469818E-07 0.1934219E-02 6.7350 12 K+ 0.1650138E-03 0.1657686E-03 0.6469939E+01 6.2467 13 Na+ 0.2094129E-01 0.2338924E-01 0.5367232E+03 8.3493 14 Mn++ 0.2098213E-10 0.2548242E-08 0.1397374E-03 9.2426 15 F- 0.1100755E-05 0.1104483E-05 0.2094430E-01 4.0691 16 HPO4-- 0.4171962E-07 0.4270804E-07 0.4091522E-02 12.5458 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278986E+02 -.1070192E-01 -.8277915E+02 0.0000000E+00 2 H2O -.7148329E+01 0.2757608E+02 -.3472440E+02 0.0000000E+00 3 Cl- 0.2853152E-03 0.2853152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387118E+00 -.1730598E-02 0.1404424E+00 0.0000000E+00 5 HCO3- 0.1819847E-02 0.1819847E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1380791E+00 0.2363359E-02 -.1404424E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2524737E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6493284E-02 0.5205741E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1545894E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5064305E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1723775E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8235233E-04 0.1061489E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1161956E-01 0.6264757E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1265944E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1009600E-04 0.5486971E-06 0.9547303E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2121697E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.8320E-14 Mass of aqueous solution: 0.497708E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0249900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.257 0.796 1641. 3.215 30.04 629.9 andradite 0.5618 -0.250 285.5 2.456 5.226 74.17 grossular 0.1360 -0.866 61.28 1.787 1.122 17.05 apatite-OH 0.9853E-02 -2.006 4.949 0.695 0.9061E-01 1.573 apatite-F 0.9547E-05 -5.020 0.4815E-02 -2.317 0.8815E-04 0.1504E-02 clinochlore 0.7086 -0.150 393.8 2.595 7.210 149.8 daphnite 0.2051 -0.688 146.4 2.165 2.680 44.35 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2148 -0.668 46.52 1.668 0.8517 14.22 hedenbergite 0.5572E-01 -1.254 13.82 1.141 0.2531 3.786 microcline 0.9327 -0.030 259.6 2.414 4.753 101.4 stilbite 3.221 0.508 2270. 3.356 41.56 1059. stilpnomelane-Fe 0.2575 -0.589 277.6 2.443 5.082 95.88 tr.625ac.25prg.125 0.5809E-01 -1.236 49.66 1.696 0.9091 15.98 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1862E-01 0.1862E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.345439 g Volume = 2210.846828 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0249900 moles log = -1.6022 Original solution: 1000.0103000 g Original solution / Rock added: 40016.42 (Water/Rock Ratio), log = 4.6022 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 6.1700 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1682E+00 0.9693 0.1006E+01 0.1038E+01 CO2,gas 0.1570E-06 0.9877 0.9570E-06 0.9689E-06 CH4,gas 0.8294E+00 0.9984 0.5109E+01 0.5117E+01 H2,gas 0.2456E-02 1.0033 0.1521E-01 0.1516E-01 H2S,gas 0.1164E-05 0.9764 0.7014E-05 0.7184E-05 S2,gas 0.1295E-26 1.0000 0.7987E-26 0.7987E-26 CO,gas 0.6286E-12 1.0000 0.3878E-11 0.3878E-11 SO3,gas 0.5927E-47 1.0000 0.3657E-46 0.3657E-46 SO2,gas 0.3507E-26 1.0000 0.2164E-25 0.2164E-25 HF,gas 0.1940E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1942E-17 1.0000 0.1198E-16 0.1198E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.60662E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.38 -7.72 -2.573 0.13178E+05 -6.019 3 CH4,gas 4.54 3.55 -0.99 -0.248 0.16915E+04 0.708 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.08 -6.85 -3.426 0.11701E+05 -5.154 6 S2,gas -7.34 -35.13 -27.80 -4.276 0.47462E+05 -26.098 7 CO,gas 3.21 -9.90 -13.11 -4.034 0.22386E+05 -11.411 8 SO3,gas 17.12 -31.01 -48.14 -12.034 0.82191E+05 -46.437 9 SO2,gas 0.83 -26.53 -27.36 -7.297 0.46723E+05 -25.665 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.43 -18.62 -9.310 0.31794E+05 -16.922 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80655E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93634E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.28 -2.24 -0.748 0.38297E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.28 -2.09 -0.696 0.35655E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68939E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65531E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.41 -2.31 -0.660 0.39445E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.41 -1.87 -0.533 0.31868E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82223E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.91 -2.67 -0.628 0.45544E+04 146 pyrrhotite -4.26 -6.35 -2.09 -0.696 0.35651E+04 147 pyrrhotiteFe0.875 -6.02 -7.75 -1.73 -0.636 0.29523E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22427E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28676E+03 154 rhodochrosite -0.98 -5.14 -4.16 -1.386 0.71018E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23229E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27806E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47091E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90674E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77498E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.35 -1.94 -0.646 0.33079E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60606E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.84 -2.86 -0.954 0.48880E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0249900 MOLES New total amount of reactant added: 0.0259900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0259900 Water: Moles liquid = 0.2758E+02 kg liquid = 0.4968E+00 Moles total = -.7148E+01 kg total = -.1288E+00 Activity = 0.9999 Stoichiometric ionic strength = .9247444E-02 Osmotic coef. = 0.9229 True ionic strength = .2126997E-01 Chg. balance for total moles = -.8663E-10 Max. difference allowed = 0.2912E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93266E-10 -10.0303 0.78064E-10 -10.1075 0.83700E+00 -0.0773 2 H2O 0.99993E+00 0.0000 0.99993E+00 0.0000 3 Cl- 0.58336E-03 -3.2341 0.48520E-03 -3.3141 0.83173E+00 -0.0800 4 SO4-- 0.32299E-10 -10.4908 0.16506E-10 -10.7824 0.51104E+00 -0.2915 5 HCO3- 0.66934E-04 -4.1744 0.55756E-04 -4.2537 0.83300E+00 -0.0794 6 HS- 0.13223E-02 -2.8787 0.11000E-02 -2.9586 0.83186E+00 -0.0800 7 Al+++ 0.11712E-28 -28.9314 0.26085E-29 -29.5836 0.22271E+00 -0.6523 8 H4SiO4 0.69593E-03 -3.1574 0.69593E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15193E-06 -6.8184 0.77043E-07 -7.1133 0.50711E+00 -0.2949 10 Mg++ 0.23773E-10 -10.6239 0.11998E-10 -10.9209 0.50467E+00 -0.2970 11 Fe++ 0.65523E-13 -13.1836 0.33106E-13 -13.4801 0.50525E+00 -0.2965 12 K+ 0.16533E-03 -3.7816 0.13776E-03 -3.8609 0.83321E+00 -0.0792 13 Na+ 0.20982E-01 -1.6782 0.17448E-01 -1.7583 0.83157E+00 -0.0801 14 Mn++ 0.21072E-10 -10.6763 0.10656E-10 -10.9724 0.50569E+00 -0.2961 15 F- 0.10990E-05 -5.9590 0.91206E-06 -6.0400 0.82993E+00 -0.0810 16 HPO4-- 0.41594E-07 -7.3810 0.21260E-07 -7.6724 0.51112E+00 -0.2915 18 HSiO3- 0.10009E-01 -1.9996 0.83247E-02 -2.0796 0.83173E+00 -0.0800 19 Ca(HSiO3)+ 0.17526E-07 -7.7563 0.14606E-07 -7.8355 0.83340E+00 -0.0791 20 Mg(HSiO3)+ 0.33966E-11 -11.4690 0.28307E-11 -11.5481 0.83340E+00 -0.0791 21 NaHSiO3,aq 0.23492E-02 -2.6291 0.23492E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.69869E-16 -16.1557 0.58229E-16 -16.2349 0.83340E+00 -0.0791 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.50736E-05 -5.2947 0.42119E-05 -5.3755 0.83015E+00 -0.0808 26 CH4,aq 0.36192E-02 -2.4414 0.36090E-02 -2.4426 0.99717E+00 -0.0012 27 C2H6,aq 0.19280E-09 -9.7149 0.19226E-09 -9.7161 0.99717E+00 -0.0012 28 C3H8,aq 0.23713E-15 -15.6250 0.23646E-15 -15.6262 0.99717E+00 -0.0012 30 ethanol,aq 0.70766E-17 -17.1502 0.70566E-17 -17.1514 0.99717E+00 -0.0012 31 CO,aq 0.27063E-14 -14.5676 0.27063E-14 -14.5676 0.10000E+01 0.0000 32 CO2,aq 0.93275E-08 -8.0302 0.93011E-08 -8.0315 0.99717E+00 -0.0012 33 CO3-2 0.12235E-03 -3.9124 0.62386E-04 -4.2049 0.50991E+00 -0.2925 34 CaCO3,aq 0.60267E-07 -7.2199 0.60267E-07 -7.2199 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.13157E-09 -9.8808 0.10965E-09 -9.9600 0.83340E+00 -0.0791 36 CaCl+ 0.72588E-10 -10.1391 0.60495E-10 -10.2183 0.83340E+00 -0.0791 37 CaCl2,aq 0.69734E-14 -14.1566 0.69734E-14 -14.1566 0.10000E+01 0.0000 38 CaF+ 0.12310E-11 -11.9097 0.10259E-11 -11.9889 0.83340E+00 -0.0791 39 CaOH+ 0.84393E-07 -7.0737 0.70333E-07 -7.1528 0.83340E+00 -0.0791 40 CaSO4,aq 0.40382E-15 -15.3938 0.40382E-15 -15.3938 0.10000E+01 0.0000 41 HCl,aq 0.69408E-14 -14.1586 0.69408E-14 -14.1586 0.10000E+01 0.0000 45 HF,aq 0.48741E-12 -12.3121 0.48741E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18045E-18 -18.7436 0.15009E-18 -18.8237 0.83173E+00 -0.0800 48 FeCl+ 0.30508E-16 -16.5156 0.25425E-16 -16.5947 0.83340E+00 -0.0791 51 FeF+ 0.18514E-17 -17.7325 0.15430E-17 -17.8116 0.83340E+00 -0.0791 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16563E-10 -10.7809 0.13803E-10 -10.8600 0.83340E+00 -0.0791 55 HFeO2- 0.34020E-07 -7.4683 0.28295E-07 -7.5483 0.83173E+00 -0.0800 56 FeO+ 0.11608E-16 -16.9352 0.96745E-17 -17.0144 0.83340E+00 -0.0791 58 FeO2- 0.39054E-09 -9.4083 0.32482E-09 -9.4884 0.83173E+00 -0.0800 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11615E-04 -4.9350 0.11582E-04 -4.9362 0.99717E+00 -0.0012 61 KCl,aq 0.12114E-08 -8.9167 0.12114E-08 -8.9167 0.10000E+01 0.0000 63 KOH,aq 0.75356E-06 -6.1229 0.75356E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.42423E-13 -13.3724 0.35284E-13 -13.4524 0.83173E+00 -0.0800 65 MgCO3,aq 0.23525E-11 -11.6285 0.23525E-11 -11.6285 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.20936E-13 -13.6791 0.17448E-13 -13.7583 0.83340E+00 -0.0791 67 MgCl+ 0.10245E-13 -13.9895 0.85383E-14 -14.0686 0.83340E+00 -0.0791 68 MgF+ 0.71012E-15 -15.1487 0.59181E-15 -15.2278 0.83340E+00 -0.0791 69 MgOH+ 0.72722E-10 -10.1383 0.60607E-10 -10.2175 0.83340E+00 -0.0791 71 MnF+ 0.19642E-15 -15.7068 0.16370E-15 -15.7860 0.83340E+00 -0.0791 72 MnO,aq 0.18107E-08 -8.7422 0.18107E-08 -8.7422 0.10000E+01 0.0000 73 MnOH+ 0.49524E-09 -9.3052 0.41273E-09 -9.3843 0.83340E+00 -0.0791 74 MnO2-2 0.19337E-10 -10.7136 0.98602E-11 -11.0061 0.50991E+00 -0.2925 75 HMnO2- 0.20275E-09 -9.6930 0.16863E-09 -9.7731 0.83173E+00 -0.0800 78 MnCl+ 0.38202E-13 -13.4179 0.31838E-13 -13.4971 0.83340E+00 -0.0791 79 MnSO4,aq 0.50777E-19 -19.2943 0.50777E-19 -19.2943 0.10000E+01 0.0000 80 NaCl,aq 0.28055E-05 -5.5520 0.28055E-05 -5.5520 0.10000E+01 0.0000 81 NaF,aq 0.37256E-08 -8.4288 0.37256E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96022E-04 -4.0176 0.96022E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.89149E-02 -2.0499 0.74008E-02 -2.1307 0.83015E+00 -0.0808 89 HPO3-2 0.15049E-14 -14.8225 0.76737E-15 -15.1150 0.50991E+00 -0.2925 91 H2PO3- 0.14443E-18 -18.8403 0.12013E-18 -18.9204 0.83173E+00 -0.0800 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36773E-10 -10.4345 0.30616E-10 -10.5141 0.83255E+00 -0.0796 94 PO4-3 0.94764E-09 -9.0234 0.22220E-09 -9.6533 0.23447E+00 -0.6299 98 HP2O7-3 0.84323E-18 -18.0741 0.18800E-18 -18.7258 0.22295E+00 -0.6518 99 P2O7-4 0.79521E-17 -17.0995 0.57533E-18 -18.2401 0.72349E-01 -1.1406 100 H2S,aq 0.26614E-06 -6.5749 0.26538E-06 -6.5761 0.99717E+00 -0.0012 101 S2-2 0.45396E-11 -11.3430 0.23148E-11 -11.6355 0.50991E+00 -0.2925 102 S3-2 0.14014E-18 -18.8534 0.71460E-19 -19.1459 0.50991E+00 -0.2925 107 SO3-2 0.47995E-16 -16.3188 0.24844E-16 -16.6048 0.51764E+00 -0.2860 108 HSO3- 0.14600E-18 -18.8356 0.12143E-18 -18.9157 0.83173E+00 -0.0800 109 HSO4- 0.14885E-17 -17.8272 0.12418E-17 -17.9060 0.83425E+00 -0.0787 111 S2O3-2 0.10092E-18 -18.9960 0.51460E-19 -19.2885 0.50991E+00 -0.2925 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9326621E-10 -.2151532E-01 -.2164610E+02 0.0000 2 H2O 0.1000000E+01 0.5550854E+02 0.9981563E+06 0.0000 3 Cl- 0.5833642E-03 0.5861710E-03 0.2074314E+02 6.7935 4 SO4-- 0.3229885E-10 -.3622151E-02 -.3473070E+03 9.4327 5 HCO3- 0.6693427E-04 0.3808599E-02 0.2319609E+03 5.8538 6 HS- 0.1322297E-02 0.4944713E-02 0.1632296E+03 7.1489 7 Al+++ 0.1171243E-28 0.5073784E-05 0.1366455E+00 0.7390 8 H4SiO4 0.6959286E-03 0.1305401E-01 0.1252374E+04 -3.1574 9 Ca++ 0.1519271E-06 0.3143187E-06 0.1257400E-01 13.1018 10 Mg++ 0.2377308E-10 0.1022772E-09 0.2481971E-05 9.2942 11 Fe++ 0.6552298E-13 0.3464164E-07 0.1931059E-02 6.7350 12 K+ 0.1653316E-03 0.1660863E-03 0.6482314E+01 6.2467 13 Na+ 0.2098168E-01 0.2342968E-01 0.5376488E+03 8.3493 14 Mn++ 0.2107163E-10 0.2549140E-08 0.1397860E-03 9.2427 15 F- 0.1098953E-05 0.1102680E-05 0.2091003E-01 4.0676 16 HPO4-- 0.4159434E-07 0.4257875E-07 0.4079119E-02 12.5427 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278975E+02 -.1068901E-01 -.8277906E+02 0.0000000E+00 2 H2O -.7147511E+01 0.2757716E+02 -.3472467E+02 0.0000000E+00 3 Cl- 0.2912152E-03 0.2912152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387166E+00 -.1799518E-02 0.1405161E+00 0.0000000E+00 5 HCO3- 0.1892147E-02 0.1892147E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1380596E+00 0.2456579E-02 -.1405161E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2520703E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6485350E-02 0.5205742E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1561564E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5081224E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1721029E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8251322E-04 0.1061488E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1164008E-01 0.6264737E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1266436E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1049600E-04 0.5478217E-06 0.9948178E-05 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2115352E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.2991E-14 Mass of aqueous solution: 0.497728E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0259900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.257 0.796 1641. 3.215 30.04 629.9 andradite 0.5621 -0.250 285.6 2.456 5.229 74.21 grossular 0.1361 -0.866 61.31 1.788 1.122 17.06 apatite-OH 0.9853E-02 -2.006 4.949 0.695 0.9061E-01 1.573 apatite-F 0.9948E-05 -5.002 0.5017E-02 -2.300 0.9185E-04 0.1567E-02 clinochlore 0.7085 -0.150 393.8 2.595 7.209 149.8 daphnite 0.2051 -0.688 146.4 2.165 2.679 44.35 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2129 -0.672 46.11 1.664 0.8441 14.09 hedenbergite 0.5522E-01 -1.258 13.70 1.137 0.2508 3.752 microcline 0.9328 -0.030 259.6 2.414 4.753 101.4 stilbite 3.221 0.508 2270. 3.356 41.56 1059. stilpnomelane-Fe 0.2573 -0.589 277.4 2.443 5.079 95.82 tr.625ac.25prg.125 0.5872E-01 -1.231 50.19 1.701 0.9189 16.15 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1862E-01 0.1862E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.345724 g Volume = 2210.849590 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0259900 moles log = -1.5852 Original solution: 1000.0103000 g Original solution / Rock added: 38476.73 (Water/Rock Ratio), log = 4.5852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 6.3752 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1628E+00 0.9690 0.1006E+01 0.1038E+01 CO2,gas 0.1581E-06 0.9873 0.9951E-06 0.1008E-05 CH4,gas 0.8348E+00 0.9982 0.5312E+01 0.5322E+01 H2,gas 0.2377E-02 1.0034 0.1521E-01 0.1515E-01 H2S,gas 0.1173E-05 0.9756 0.7295E-05 0.7478E-05 S2,gas 0.1355E-26 1.0000 0.8640E-26 0.8640E-26 CO,gas 0.6326E-12 1.0000 0.4033E-11 0.4033E-11 SO3,gas 0.5966E-47 1.0000 0.3804E-46 0.3804E-46 SO2,gas 0.3530E-26 1.0000 0.2250E-25 0.2250E-25 HF,gas 0.1877E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1921E-17 1.0000 0.1225E-16 0.1225E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.36 -7.70 -2.567 0.13149E+05 -6.002 3 CH4,gas 4.54 3.57 -0.97 -0.243 0.16626E+04 0.725 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.07 -6.84 -3.418 0.11672E+05 -5.137 6 S2,gas -7.34 -35.10 -27.76 -4.271 0.47404E+05 -26.063 7 CO,gas 3.21 -9.88 -13.09 -4.029 0.22357E+05 -11.394 8 SO3,gas 17.12 -31.00 -48.12 -12.030 0.82162E+05 -46.420 9 SO2,gas 0.83 -26.51 -27.35 -7.292 0.46694E+05 -25.648 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.42 -18.61 -9.305 0.31778E+05 -16.912 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80653E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93634E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.26 -2.23 -0.742 0.38007E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.26 -2.07 -0.690 0.35365E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68939E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65530E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.40 -2.29 -0.655 0.39156E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.40 -1.85 -0.528 0.31578E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82223E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.88 -2.63 -0.620 0.44961E+04 146 pyrrhotite -4.26 -6.33 -2.07 -0.690 0.35359E+04 147 pyrrhotiteFe0.875 -6.02 -7.73 -1.71 -0.630 0.29231E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22426E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28676E+03 154 rhodochrosite -0.98 -5.12 -4.14 -1.381 0.70728E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23229E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27806E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47090E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90674E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77499E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.33 -1.92 -0.640 0.32787E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60606E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.82 -2.85 -0.949 0.48588E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0259900 MOLES New total amount of reactant added: 0.0269900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8664E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0269900 Water: Moles liquid = 0.2758E+02 kg liquid = 0.4968E+00 Moles total = -.7147E+01 kg total = -.1288E+00 Activity = 0.9999 Stoichiometric ionic strength = .9162898E-02 Osmotic coef. = 0.9232 True ionic strength = .2131501E-01 Chg. balance for total moles = -.8664E-10 Max. difference allowed = 0.2971E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93446E-10 -10.0294 0.78204E-10 -10.1068 0.83689E+00 -0.0773 2 H2O 0.99993E+00 0.0000 0.99993E+00 0.0000 3 Cl- 0.59516E-03 -3.2254 0.49494E-03 -3.3055 0.83161E+00 -0.0801 4 SO4-- 0.33446E-10 -10.4757 0.17083E-10 -10.7674 0.51076E+00 -0.2918 5 HCO3- 0.69386E-04 -4.1587 0.57790E-04 -4.2381 0.83288E+00 -0.0794 6 HS- 0.13711E-02 -2.8629 0.11404E-02 -2.9429 0.83173E+00 -0.0800 7 Al+++ 0.11791E-28 -28.9285 0.26225E-29 -29.5813 0.22243E+00 -0.6528 8 H4SiO4 0.69593E-03 -3.1574 0.69593E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15256E-06 -6.8166 0.77319E-07 -7.1117 0.50681E+00 -0.2952 10 Mg++ 0.23872E-10 -10.6221 0.12041E-10 -10.9194 0.50438E+00 -0.2972 11 Fe++ 0.65796E-13 -13.1818 0.33224E-13 -13.4785 0.50496E+00 -0.2967 12 K+ 0.16565E-03 -3.7808 0.13800E-03 -3.8601 0.83309E+00 -0.0793 13 Na+ 0.21022E-01 -1.6773 0.17479E-01 -1.7575 0.83145E+00 -0.0802 14 Mn++ 0.21161E-10 -10.6745 0.10695E-10 -10.9708 0.50540E+00 -0.2964 15 F- 0.10972E-05 -5.9597 0.91043E-06 -6.0408 0.82981E+00 -0.0810 16 HPO4-- 0.41470E-07 -7.3823 0.21184E-07 -7.6740 0.51083E+00 -0.2917 18 HSiO3- 0.99925E-02 -2.0003 0.83098E-02 -2.0804 0.83161E+00 -0.0801 19 Ca(HSiO3)+ 0.17560E-07 -7.7555 0.14632E-07 -7.8347 0.83328E+00 -0.0792 20 Mg(HSiO3)+ 0.34032E-11 -11.4681 0.28358E-11 -11.5473 0.83328E+00 -0.0792 21 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.70004E-16 -16.1549 0.58333E-16 -16.2341 0.83328E+00 -0.0792 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.50654E-05 -5.2954 0.42044E-05 -5.3763 0.83003E+00 -0.0809 26 CH4,aq 0.37579E-02 -2.4251 0.37473E-02 -2.4263 0.99720E+00 -0.0012 27 C2H6,aq 0.20786E-09 -9.6822 0.20728E-09 -9.6834 0.99720E+00 -0.0012 28 C3H8,aq 0.26545E-15 -15.5760 0.26470E-15 -15.5772 0.99720E+00 -0.0012 30 ethanol,aq 0.76293E-17 -17.1175 0.76079E-17 -17.1187 0.99720E+00 -0.0012 31 CO,aq 0.28100E-14 -14.5513 0.28100E-14 -14.5513 0.10000E+01 0.0000 32 CO2,aq 0.96848E-08 -8.0139 0.96576E-08 -8.0151 0.99720E+00 -0.0012 33 CO3-2 0.12666E-03 -3.8974 0.64546E-04 -4.1901 0.50962E+00 -0.2928 34 CaCO3,aq 0.62577E-07 -7.2036 0.62577E-07 -7.2036 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.13688E-09 -9.8637 0.11406E-09 -9.9429 0.83328E+00 -0.0792 36 CaCl+ 0.74320E-10 -10.1289 0.61929E-10 -10.2081 0.83328E+00 -0.0792 37 CaCl2,aq 0.72820E-14 -14.1377 0.72820E-14 -14.1377 0.10000E+01 0.0000 38 CaF+ 0.12334E-11 -11.9089 0.10277E-11 -11.9881 0.83328E+00 -0.0792 39 CaOH+ 0.84556E-07 -7.0729 0.70458E-07 -7.1521 0.83328E+00 -0.0792 40 CaSO4,aq 0.41943E-15 -15.3773 0.41943E-15 -15.3773 0.10000E+01 0.0000 41 HCl,aq 0.70927E-14 -14.1492 0.70927E-14 -14.1492 0.10000E+01 0.0000 45 HF,aq 0.48741E-12 -12.3121 0.48741E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.18016E-18 -18.7443 0.14982E-18 -18.8244 0.83161E+00 -0.0801 48 FeCl+ 0.31236E-16 -16.5054 0.26028E-16 -16.5846 0.83328E+00 -0.0792 51 FeF+ 0.18550E-17 -17.7317 0.15457E-17 -17.8109 0.83328E+00 -0.0792 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16595E-10 -10.7800 0.13828E-10 -10.8592 0.83328E+00 -0.0792 55 HFeO2- 0.33964E-07 -7.4690 0.28245E-07 -7.5491 0.83161E+00 -0.0801 56 FeO+ 0.11631E-16 -16.9344 0.96917E-17 -17.0136 0.83328E+00 -0.0792 58 FeO2- 0.38990E-09 -9.4091 0.32424E-09 -9.4891 0.83161E+00 -0.0801 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11614E-04 -4.9350 0.11582E-04 -4.9362 0.99720E+00 -0.0012 61 KCl,aq 0.12379E-08 -8.9073 0.12379E-08 -8.9073 0.10000E+01 0.0000 63 KOH,aq 0.75355E-06 -6.1229 0.75355E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.43990E-13 -13.3566 0.36582E-13 -13.4367 0.83161E+00 -0.0801 65 MgCO3,aq 0.24426E-11 -11.6121 0.24426E-11 -11.6121 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.21781E-13 -13.6619 0.18149E-13 -13.7411 0.83328E+00 -0.0792 67 MgCl+ 0.10490E-13 -13.9792 0.87408E-14 -14.0584 0.83328E+00 -0.0792 68 MgF+ 0.71149E-15 -15.1478 0.59286E-15 -15.2270 0.83328E+00 -0.0792 69 MgOH+ 0.72863E-10 -10.1375 0.60715E-10 -10.2167 0.83328E+00 -0.0792 71 MnF+ 0.19682E-15 -15.7059 0.16401E-15 -15.7851 0.83328E+00 -0.0792 72 MnO,aq 0.18109E-08 -8.7421 0.18109E-08 -8.7421 0.10000E+01 0.0000 73 MnOH+ 0.49625E-09 -9.3043 0.41351E-09 -9.3835 0.83328E+00 -0.0792 74 MnO2-2 0.19281E-10 -10.7149 0.98260E-11 -11.0076 0.50962E+00 -0.2928 75 HMnO2- 0.20244E-09 -9.6937 0.16835E-09 -9.7738 0.83161E+00 -0.0801 78 MnCl+ 0.39118E-13 -13.4076 0.32596E-13 -13.4868 0.83328E+00 -0.0792 79 MnSO4,aq 0.52744E-19 -19.2778 0.52744E-19 -19.2778 0.10000E+01 0.0000 80 NaCl,aq 0.28669E-05 -5.5426 0.28669E-05 -5.5426 0.10000E+01 0.0000 81 NaF,aq 0.37256E-08 -8.4288 0.37256E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96021E-04 -4.0176 0.96021E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.89004E-02 -2.0506 0.73876E-02 -2.1315 0.83003E+00 -0.0809 89 HPO3-2 0.15004E-14 -14.8238 0.76464E-15 -15.1165 0.50962E+00 -0.2928 91 H2PO3- 0.14419E-18 -18.8411 0.11991E-18 -18.9211 0.83161E+00 -0.0801 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36713E-10 -10.4352 0.30561E-10 -10.5148 0.83243E+00 -0.0797 94 PO4-3 0.94372E-09 -9.0252 0.22101E-09 -9.6556 0.23419E+00 -0.6304 98 HP2O7-3 0.83981E-18 -18.0758 0.18700E-18 -18.7282 0.22267E+00 -0.6523 99 P2O7-4 0.79133E-17 -17.1016 0.57124E-18 -18.2432 0.72187E-01 -1.1415 100 H2S,aq 0.27641E-06 -6.5584 0.27564E-06 -6.5597 0.99720E+00 -0.0012 101 S2-2 0.48826E-11 -11.3113 0.24883E-11 -11.6041 0.50962E+00 -0.2928 102 S3-2 0.15656E-18 -18.8053 0.79784E-19 -19.0981 0.50962E+00 -0.2928 107 SO3-2 0.49699E-16 -16.3037 0.25712E-16 -16.5899 0.51736E+00 -0.2862 108 HSO3- 0.15139E-18 -18.8199 0.12590E-18 -18.9000 0.83161E+00 -0.0801 109 HSO4- 0.15435E-17 -17.8115 0.12875E-17 -17.8903 0.83413E+00 -0.0788 111 S2O3-2 0.10855E-18 -18.9644 0.55316E-19 -19.2571 0.50962E+00 -0.2928 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9344557E-10 -.2148860E-01 -.2161913E+02 0.0000 2 H2O 0.1000000E+01 0.5550869E+02 0.9981548E+06 0.0000 3 Cl- 0.5951566E-03 0.5980249E-03 0.2116253E+02 6.8013 4 SO4-- 0.3344641E-10 -.3760771E-02 -.3605970E+03 9.4461 5 HCO3- 0.6938598E-04 0.3953982E-02 0.2408144E+03 5.8686 6 HS- 0.1371148E-02 0.5132195E-02 0.1694178E+03 7.1638 7 Al+++ 0.1179061E-28 0.5065502E-05 0.1364219E+00 0.7390 8 H4SiO4 0.6959267E-03 0.1303760E-01 0.1250795E+04 -3.1574 9 Ca++ 0.1525586E-06 0.3174639E-06 0.1269977E-01 13.1018 10 Mg++ 0.2387208E-10 0.1026140E-09 0.2490134E-05 9.2942 11 Fe++ 0.6579586E-13 0.3458526E-07 0.1927908E-02 6.7350 12 K+ 0.1656495E-03 0.1664043E-03 0.6494697E+01 6.2467 13 Na+ 0.2102210E-01 0.2347014E-01 0.5385751E+03 8.3493 14 Mn++ 0.2116140E-10 0.2550040E-08 0.1398348E-03 9.2427 15 F- 0.1097156E-05 0.1100883E-05 0.2087586E-01 4.0660 16 HPO4-- 0.4146958E-07 0.4245001E-07 0.4066769E-02 12.5396 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278964E+02 -.1067613E-01 -.8277897E+02 0.0000000E+00 2 H2O -.7146692E+01 0.2757824E+02 -.3472493E+02 0.0000000E+00 3 Cl- 0.2971152E-03 0.2971152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387214E+00 -.1868454E-02 0.1405899E+00 0.0000000E+00 5 HCO3- 0.1964447E-02 0.1964447E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1380400E+00 0.2549816E-02 -.1405899E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2516681E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6477439E-02 0.5205743E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1577248E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5098144E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1718291E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8267421E-04 0.1061488E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1166061E-01 0.6264716E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1266930E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1089600E-04 0.5469488E-06 0.1034905E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2109033E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1828E-13 Mass of aqueous solution: 0.497749E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0269900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.257 0.796 1641. 3.215 30.04 629.9 andradite 0.5624 -0.250 285.8 2.456 5.232 74.25 grossular 0.1362 -0.866 61.34 1.788 1.123 17.07 apatite-OH 0.9852E-02 -2.006 4.949 0.695 0.9060E-01 1.573 apatite-F 0.1035E-04 -4.985 0.5219E-02 -2.282 0.9555E-04 0.1630E-02 clinochlore 0.7084 -0.150 393.8 2.595 7.209 149.8 daphnite 0.2051 -0.688 146.3 2.165 2.679 44.34 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2110 -0.676 45.69 1.660 0.8365 13.96 hedenbergite 0.5472E-01 -1.262 13.58 1.133 0.2485 3.718 microcline 0.9329 -0.030 259.7 2.414 4.754 101.4 stilbite 3.221 0.508 2270. 3.356 41.56 1059. stilpnomelane-Fe 0.2572 -0.590 277.2 2.443 5.076 95.77 tr.625ac.25prg.125 0.5935E-01 -1.227 50.73 1.705 0.9287 16.33 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1863E-01 0.1863E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.346008 g Volume = 2210.852353 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0269900 moles log = -1.5688 Original solution: 1000.0103000 g Original solution / Rock added: 37051.14 (Water/Rock Ratio), log = 4.5688 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 6.5806 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1578E+00 0.9687 0.1006E+01 0.1038E+01 CO2,gas 0.1591E-06 0.9869 0.1033E-05 0.1047E-05 CH4,gas 0.8399E+00 0.9980 0.5516E+01 0.5527E+01 H2,gas 0.2303E-02 1.0035 0.1521E-01 0.1515E-01 H2S,gas 0.1181E-05 0.9748 0.7577E-05 0.7773E-05 S2,gas 0.1416E-26 1.0000 0.9321E-26 0.9321E-26 CO,gas 0.6363E-12 1.0000 0.4187E-11 0.4187E-11 SO3,gas 0.6003E-47 1.0000 0.3951E-46 0.3951E-46 SO2,gas 0.3552E-26 1.0000 0.2337E-25 0.2337E-25 HF,gas 0.1819E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1902E-17 1.0000 0.1252E-16 0.1252E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.34 -7.68 -2.562 0.13122E+05 -5.986 3 CH4,gas 4.54 3.59 -0.96 -0.239 0.16347E+04 0.742 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.05 -6.82 -3.410 0.11644E+05 -5.120 6 S2,gas -7.34 -35.06 -27.73 -4.266 0.47347E+05 -26.031 7 CO,gas 3.21 -9.86 -13.08 -4.024 0.22329E+05 -11.378 8 SO3,gas 17.12 -30.98 -48.10 -12.026 0.82133E+05 -46.403 9 SO2,gas 0.83 -26.50 -27.33 -7.288 0.46666E+05 -25.631 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.41 -18.60 -9.301 0.31762E+05 -16.903 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80651E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93634E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.24 -2.21 -0.737 0.37728E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.24 -2.05 -0.685 0.35086E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68939E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65529E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.38 -2.28 -0.651 0.38877E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.38 -1.83 -0.524 0.31299E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82222E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.85 -2.60 -0.612 0.44399E+04 146 pyrrhotite -4.26 -6.31 -2.05 -0.685 0.35078E+04 147 pyrrhotiteFe0.875 -6.02 -7.71 -1.70 -0.624 0.28950E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22425E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84960E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28676E+03 154 rhodochrosite -0.98 -5.10 -4.13 -1.375 0.70448E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23228E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27806E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47088E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90673E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77499E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.31 -1.90 -0.635 0.32506E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60605E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.81 -2.83 -0.943 0.48306E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0269900 MOLES New total amount of reactant added: 0.0279900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0279900 Water: Moles liquid = 0.2758E+02 kg liquid = 0.4968E+00 Moles total = -.7146E+01 kg total = -.1287E+00 Activity = 0.9999 Stoichiometric ionic strength = .9078324E-02 Osmotic coef. = 0.9236 True ionic strength = .2136006E-01 Chg. balance for total moles = -.8663E-10 Max. difference allowed = 0.3030E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93625E-10 -10.0286 0.78343E-10 -10.1060 0.83678E+00 -0.0774 2 H2O 0.99993E+00 0.0000 0.99993E+00 0.0000 3 Cl- 0.60695E-03 -3.2168 0.50467E-03 -3.2970 0.83148E+00 -0.0801 4 SO4-- 0.34591E-10 -10.4610 0.17657E-10 -10.7531 0.51047E+00 -0.2920 5 HCO3- 0.71830E-04 -4.1437 0.59818E-04 -4.2232 0.83276E+00 -0.0795 6 HS- 0.14200E-02 -2.8477 0.11809E-02 -2.9278 0.83161E+00 -0.0801 7 Al+++ 0.11869E-28 -28.9256 0.26366E-29 -29.5790 0.22214E+00 -0.6534 8 H4SiO4 0.69592E-03 -3.1574 0.69592E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15319E-06 -6.8148 0.77595E-07 -7.1102 0.50652E+00 -0.2954 10 Mg++ 0.23971E-10 -10.6203 0.12084E-10 -10.9178 0.50408E+00 -0.2975 11 Fe++ 0.66070E-13 -13.1800 0.33343E-13 -13.4770 0.50466E+00 -0.2970 12 K+ 0.16597E-03 -3.7800 0.13825E-03 -3.8593 0.83297E+00 -0.0794 13 Na+ 0.21063E-01 -1.6765 0.17510E-01 -1.7567 0.83132E+00 -0.0802 14 Mn++ 0.21251E-10 -10.6726 0.10734E-10 -10.9692 0.50510E+00 -0.2966 15 F- 0.10954E-05 -5.9604 0.90880E-06 -6.0415 0.82968E+00 -0.0811 16 HPO4-- 0.41345E-07 -7.3836 0.21109E-07 -7.6755 0.51054E+00 -0.2920 18 HSiO3- 0.99762E-02 -2.0010 0.82950E-02 -2.0812 0.83148E+00 -0.0801 19 Ca(HSiO3)+ 0.17594E-07 -7.7546 0.14658E-07 -7.8339 0.83316E+00 -0.0793 20 Mg(HSiO3)+ 0.34097E-11 -11.4673 0.28409E-11 -11.5466 0.83316E+00 -0.0793 21 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.70140E-16 -16.1540 0.58437E-16 -16.2333 0.83316E+00 -0.0793 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.50571E-05 -5.2961 0.41969E-05 -5.3771 0.82991E+00 -0.0810 26 CH4,aq 0.38965E-02 -2.4093 0.38857E-02 -2.4105 0.99722E+00 -0.0012 27 C2H6,aq 0.22349E-09 -9.6507 0.22287E-09 -9.6520 0.99722E+00 -0.0012 28 C3H8,aq 0.29594E-15 -15.5288 0.29512E-15 -15.5300 0.99722E+00 -0.0012 30 ethanol,aq 0.82029E-17 -17.0860 0.81801E-17 -17.0872 0.99722E+00 -0.0012 31 CO,aq 0.29138E-14 -14.5355 0.29138E-14 -14.5355 0.10000E+01 0.0000 32 CO2,aq 0.10042E-07 -7.9982 0.10014E-07 -7.9994 0.99722E+00 -0.0012 33 CO3-2 0.13094E-03 -3.8829 0.66692E-04 -4.1759 0.50933E+00 -0.2930 34 CaCO3,aq 0.64888E-07 -7.1878 0.64888E-07 -7.1878 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.14221E-09 -9.8471 0.11848E-09 -9.9264 0.83316E+00 -0.0793 36 CaCl+ 0.76063E-10 -10.1188 0.63373E-10 -10.1981 0.83316E+00 -0.0793 37 CaCl2,aq 0.75983E-14 -14.1193 0.75983E-14 -14.1193 0.10000E+01 0.0000 38 CaF+ 0.12358E-11 -11.9081 0.10296E-11 -11.9873 0.83316E+00 -0.0793 39 CaOH+ 0.84718E-07 -7.0720 0.70584E-07 -7.1513 0.83316E+00 -0.0793 40 CaSO4,aq 0.43508E-15 -15.3614 0.43508E-15 -15.3614 0.10000E+01 0.0000 41 HCl,aq 0.72450E-14 -14.1400 0.72450E-14 -14.1400 0.10000E+01 0.0000 45 HF,aq 0.48740E-12 -12.3121 0.48740E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17986E-18 -18.7451 0.14955E-18 -18.8252 0.83148E+00 -0.0801 48 FeCl+ 0.31968E-16 -16.4953 0.26634E-16 -16.5746 0.83316E+00 -0.0793 51 FeF+ 0.18586E-17 -17.7308 0.15485E-17 -17.8101 0.83316E+00 -0.0793 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16627E-10 -10.7792 0.13853E-10 -10.8585 0.83316E+00 -0.0793 55 HFeO2- 0.33909E-07 -7.4697 0.28195E-07 -7.5498 0.83148E+00 -0.0801 56 FeO+ 0.11653E-16 -16.9336 0.97090E-17 -17.0128 0.83316E+00 -0.0793 58 FeO2- 0.38926E-09 -9.4098 0.32366E-09 -9.4899 0.83148E+00 -0.0801 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11614E-04 -4.9350 0.11582E-04 -4.9362 0.99722E+00 -0.0012 61 KCl,aq 0.12645E-08 -8.8981 0.12645E-08 -8.8981 0.10000E+01 0.0000 63 KOH,aq 0.75354E-06 -6.1229 0.75354E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.45557E-13 -13.3414 0.37880E-13 -13.4216 0.83148E+00 -0.0801 65 MgCO3,aq 0.25328E-11 -11.5964 0.25328E-11 -11.5964 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.22628E-13 -13.6453 0.18853E-13 -13.7246 0.83316E+00 -0.0793 67 MgCl+ 0.10736E-13 -13.9692 0.89445E-14 -14.0484 0.83316E+00 -0.0793 68 MgF+ 0.71285E-15 -15.1470 0.59392E-15 -15.2263 0.83316E+00 -0.0793 69 MgOH+ 0.73003E-10 -10.1367 0.60823E-10 -10.2159 0.83316E+00 -0.0793 71 MnF+ 0.19722E-15 -15.7051 0.16431E-15 -15.7843 0.83316E+00 -0.0793 72 MnO,aq 0.18110E-08 -8.7421 0.18110E-08 -8.7421 0.10000E+01 0.0000 73 MnOH+ 0.49725E-09 -9.3034 0.41429E-09 -9.3827 0.83316E+00 -0.0793 74 MnO2-2 0.19225E-10 -10.7161 0.97919E-11 -11.0091 0.50933E+00 -0.2930 75 HMnO2- 0.20213E-09 -9.6944 0.16807E-09 -9.7745 0.83148E+00 -0.0801 78 MnCl+ 0.40039E-13 -13.3975 0.33359E-13 -13.4768 0.83316E+00 -0.0793 79 MnSO4,aq 0.54718E-19 -19.2619 0.54718E-19 -19.2619 0.10000E+01 0.0000 80 NaCl,aq 0.29285E-05 -5.5334 0.29285E-05 -5.5334 0.10000E+01 0.0000 81 NaF,aq 0.37255E-08 -8.4288 0.37255E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96020E-04 -4.0176 0.96020E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.88858E-02 -2.0513 0.73744E-02 -2.1323 0.82991E+00 -0.0810 89 HPO3-2 0.14959E-14 -14.8251 0.76192E-15 -15.1181 0.50933E+00 -0.2930 91 H2PO3- 0.14396E-18 -18.8418 0.11970E-18 -18.9219 0.83148E+00 -0.0801 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36653E-10 -10.4359 0.30507E-10 -10.5156 0.83231E+00 -0.0797 94 PO4-3 0.93982E-09 -9.0270 0.21983E-09 -9.6579 0.23391E+00 -0.6310 98 HP2O7-3 0.83641E-18 -18.0776 0.18600E-18 -18.7305 0.22238E+00 -0.6529 99 P2O7-4 0.78748E-17 -17.1038 0.56718E-18 -18.2463 0.72025E-01 -1.1425 100 H2S,aq 0.28672E-06 -6.5425 0.28593E-06 -6.5437 0.99722E+00 -0.0012 101 S2-2 0.52381E-11 -11.2808 0.26679E-11 -11.5738 0.50933E+00 -0.2930 102 S3-2 0.17423E-18 -18.7589 0.88738E-19 -19.0519 0.50933E+00 -0.2930 107 SO3-2 0.51398E-16 -16.2891 0.26577E-16 -16.5755 0.51708E+00 -0.2864 108 HSO3- 0.15679E-18 -18.8047 0.13037E-18 -18.8848 0.83148E+00 -0.0801 109 HSO4- 0.15985E-17 -17.7963 0.13331E-17 -17.8751 0.83401E+00 -0.0788 111 S2O3-2 0.11645E-18 -18.9339 0.59311E-19 -19.2269 0.50933E+00 -0.2930 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9362504E-10 -.2146194E-01 -.2159223E+02 0.0000 2 H2O 0.1000000E+01 0.5550883E+02 0.9981532E+06 0.0000 3 Cl- 0.6069480E-03 0.6098778E-03 0.2158189E+02 6.8090 4 SO4-- 0.3459075E-10 -.3899413E-02 -.3738890E+03 9.4589 5 HCO3- 0.7183018E-04 0.4099355E-02 0.2496672E+03 5.8828 6 HS- 0.1419996E-02 0.5319696E-02 0.1756066E+03 7.1782 7 Al+++ 0.1186920E-28 0.5057244E-05 0.1361989E+00 0.7390 8 H4SiO4 0.6959247E-03 0.1302125E-01 0.1249221E+04 -3.1574 9 Ca++ 0.1531919E-06 0.3206115E-06 0.1282563E-01 13.1018 10 Mg++ 0.2397137E-10 0.1029508E-09 0.2498296E-05 9.2942 11 Fe++ 0.6606952E-13 0.3452905E-07 0.1924767E-02 6.7350 12 K+ 0.1659676E-03 0.1667224E-03 0.6507088E+01 6.2467 13 Na+ 0.2106255E-01 0.2351062E-01 0.5395019E+03 8.3493 14 Mn++ 0.2125145E-10 0.2550943E-08 0.1398837E-03 9.2428 15 F- 0.1095363E-05 0.1099091E-05 0.2084179E-01 4.0645 16 HPO4-- 0.4134535E-07 0.4232182E-07 0.4054472E-02 12.5365 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278953E+02 -.1066328E-01 -.8277887E+02 0.0000000E+00 2 H2O -.7145873E+01 0.2757932E+02 -.3472519E+02 0.0000000E+00 3 Cl- 0.3030152E-03 0.3030152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387262E+00 -.1937407E-02 0.1406636E+00 0.0000000E+00 5 HCO3- 0.2036747E-02 0.2036747E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1380205E+00 0.2643068E-02 -.1406636E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2512670E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6469551E-02 0.5205743E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1592944E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5115064E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1715561E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8283533E-04 0.1061488E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1168115E-01 0.6264696E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1267425E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1129600E-04 0.5460785E-06 0.1074992E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2102742E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.3476E-14 Mass of aqueous solution: 0.497769E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0279900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.257 0.796 1641. 3.215 30.04 629.9 andradite 0.5627 -0.250 285.9 2.456 5.235 74.29 grossular 0.1363 -0.866 61.37 1.788 1.124 17.08 apatite-OH 0.9852E-02 -2.006 4.949 0.694 0.9060E-01 1.573 apatite-F 0.1075E-04 -4.969 0.5421E-02 -2.266 0.9925E-04 0.1694E-02 clinochlore 0.7084 -0.150 393.7 2.595 7.208 149.8 daphnite 0.2051 -0.688 146.3 2.165 2.679 44.34 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2091 -0.680 45.27 1.656 0.8288 13.84 hedenbergite 0.5422E-01 -1.266 13.45 1.129 0.2463 3.684 microcline 0.9330 -0.030 259.7 2.414 4.754 101.4 stilbite 3.221 0.508 2270. 3.356 41.56 1059. stilpnomelane-Fe 0.2570 -0.590 277.1 2.443 5.073 95.71 tr.625ac.25prg.125 0.5998E-01 -1.222 51.26 1.710 0.9385 16.50 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1863E-01 0.1863E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.346291 g Volume = 2210.855117 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0279900 moles log = -1.5530 Original solution: 1000.0103000 g Original solution / Rock added: 35727.41 (Water/Rock Ratio), log = 4.5530 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 6.7861 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1531E+00 0.9684 0.1006E+01 0.1039E+01 CO2,gas 0.1600E-06 0.9865 0.1071E-05 0.1086E-05 CH4,gas 0.8447E+00 0.9978 0.5719E+01 0.5732E+01 H2,gas 0.2233E-02 1.0036 0.1521E-01 0.1515E-01 H2S,gas 0.1189E-05 0.9740 0.7860E-05 0.8069E-05 S2,gas 0.1478E-26 1.0000 0.1003E-25 0.1003E-25 CO,gas 0.6399E-12 1.0000 0.4342E-11 0.4342E-11 SO3,gas 0.6039E-47 1.0000 0.4098E-46 0.4098E-46 SO2,gas 0.3573E-26 1.0000 0.2424E-25 0.2424E-25 HF,gas 0.1764E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1884E-17 1.0000 0.1278E-16 0.1278E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.33 -7.67 -2.556 0.13095E+05 -5.970 3 CH4,gas 4.54 3.60 -0.94 -0.235 0.16078E+04 0.757 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.03 -6.80 -3.402 0.11617E+05 -5.105 6 S2,gas -7.34 -35.03 -27.70 -4.261 0.47293E+05 -25.999 7 CO,gas 3.21 -9.85 -13.06 -4.019 0.22302E+05 -11.362 8 SO3,gas 17.12 -30.97 -48.09 -12.022 0.82106E+05 -46.387 9 SO2,gas 0.83 -26.48 -27.31 -7.284 0.46639E+05 -25.615 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.40 -18.59 -9.296 0.31746E+05 -16.893 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80648E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93635E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.23 -2.19 -0.731 0.37460E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.23 -2.04 -0.680 0.34817E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68939E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65528E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.36 -2.26 -0.646 0.38608E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.36 -1.82 -0.519 0.31030E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82221E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.82 -2.57 -0.604 0.43855E+04 146 pyrrhotite -4.26 -6.30 -2.04 -0.679 0.34806E+04 147 pyrrhotiteFe0.875 -6.02 -7.70 -1.68 -0.618 0.28678E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22425E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28676E+03 154 rhodochrosite -0.98 -5.09 -4.11 -1.370 0.70179E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23227E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.59 -4.99 -1.662 0.85135E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27806E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47087E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90673E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77499E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.30 -1.89 -0.629 0.32234E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60605E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.79 -2.81 -0.938 0.48034E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0279900 MOLES New total amount of reactant added: 0.0289900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8666E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0289900 Water: Moles liquid = 0.2758E+02 kg liquid = 0.4969E+00 Moles total = -.7145E+01 kg total = -.1287E+00 Activity = 0.9999 Stoichiometric ionic strength = .8993723E-02 Osmotic coef. = 0.9240 True ionic strength = .2140511E-01 Chg. balance for total moles = -.8666E-10 Max. difference allowed = 0.3089E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93805E-10 -10.0278 0.78483E-10 -10.1052 0.83666E+00 -0.0774 2 H2O 0.99993E+00 0.0000 0.99993E+00 0.0000 3 Cl- 0.61874E-03 -3.2085 0.51440E-03 -3.2887 0.83136E+00 -0.0802 4 SO4-- 0.35732E-10 -10.4469 0.18230E-10 -10.7392 0.51018E+00 -0.2923 5 HCO3- 0.74267E-04 -4.1292 0.61838E-04 -4.2087 0.83264E+00 -0.0795 6 HS- 0.14688E-02 -2.8330 0.12213E-02 -2.9132 0.83149E+00 -0.0801 7 Al+++ 0.11948E-28 -28.9227 0.26507E-29 -29.5766 0.22185E+00 -0.6539 8 H4SiO4 0.69592E-03 -3.1574 0.69592E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15383E-06 -6.8130 0.77872E-07 -7.1086 0.50623E+00 -0.2957 10 Mg++ 0.24071E-10 -10.6185 0.12127E-10 -10.9163 0.50379E+00 -0.2978 11 Fe++ 0.66344E-13 -13.1782 0.33462E-13 -13.4754 0.50437E+00 -0.2973 12 K+ 0.16629E-03 -3.7791 0.13849E-03 -3.8586 0.83285E+00 -0.0794 13 Na+ 0.21103E-01 -1.6757 0.17541E-01 -1.7559 0.83120E+00 -0.0803 14 Mn++ 0.21342E-10 -10.6708 0.10774E-10 -10.9676 0.50481E+00 -0.2969 15 F- 0.10936E-05 -5.9612 0.90719E-06 -6.0423 0.82956E+00 -0.0812 16 HPO4-- 0.41222E-07 -7.3849 0.21034E-07 -7.6771 0.51026E+00 -0.2922 18 HSiO3- 0.99599E-02 -2.0017 0.82803E-02 -2.0820 0.83136E+00 -0.0802 19 Ca(HSiO3)+ 0.17628E-07 -7.7538 0.14685E-07 -7.8331 0.83304E+00 -0.0793 20 Mg(HSiO3)+ 0.34163E-11 -11.4664 0.28459E-11 -11.5458 0.83304E+00 -0.0793 21 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.70275E-16 -16.1532 0.58542E-16 -16.2325 0.83304E+00 -0.0793 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.50489E-05 -5.2968 0.41895E-05 -5.3778 0.82978E+00 -0.0810 26 CH4,aq 0.40352E-02 -2.3941 0.40241E-02 -2.3953 0.99725E+00 -0.0012 27 C2H6,aq 0.23968E-09 -9.6204 0.23902E-09 -9.6216 0.99725E+00 -0.0012 28 C3H8,aq 0.32869E-15 -15.4832 0.32779E-15 -15.4844 0.99725E+00 -0.0012 30 ethanol,aq 0.87973E-17 -17.0556 0.87731E-17 -17.0568 0.99725E+00 -0.0012 31 CO,aq 0.30175E-14 -14.5203 0.30175E-14 -14.5203 0.10000E+01 0.0000 32 CO2,aq 0.10400E-07 -7.9830 0.10371E-07 -7.9842 0.99725E+00 -0.0012 33 CO3-2 0.13520E-03 -3.8690 0.68821E-04 -4.1623 0.50904E+00 -0.2932 34 CaCO3,aq 0.67199E-07 -7.1726 0.67199E-07 -7.1726 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.14755E-09 -9.8310 0.12292E-09 -9.9104 0.83304E+00 -0.0793 36 CaCl+ 0.77817E-10 -10.1089 0.64825E-10 -10.1883 0.83304E+00 -0.0793 37 CaCl2,aq 0.79222E-14 -14.1012 0.79222E-14 -14.1012 0.10000E+01 0.0000 38 CaF+ 0.12381E-11 -11.9072 0.10314E-11 -11.9866 0.83304E+00 -0.0793 39 CaOH+ 0.84881E-07 -7.0712 0.70709E-07 -7.1505 0.83304E+00 -0.0793 40 CaSO4,aq 0.45078E-15 -15.3460 0.45078E-15 -15.3460 0.10000E+01 0.0000 41 HCl,aq 0.73978E-14 -14.1309 0.73978E-14 -14.1309 0.10000E+01 0.0000 45 HF,aq 0.48740E-12 -12.3121 0.48740E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17957E-18 -18.7458 0.14929E-18 -18.8260 0.83136E+00 -0.0802 48 FeCl+ 0.32705E-16 -16.4854 0.27245E-16 -16.5647 0.83304E+00 -0.0793 51 FeF+ 0.18622E-17 -17.7300 0.15513E-17 -17.8093 0.83304E+00 -0.0793 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16659E-10 -10.7784 0.13877E-10 -10.8577 0.83304E+00 -0.0793 55 HFeO2- 0.33853E-07 -7.4704 0.28144E-07 -7.5506 0.83136E+00 -0.0802 56 FeO+ 0.11676E-16 -16.9327 0.97263E-17 -17.0121 0.83304E+00 -0.0793 58 FeO2- 0.38862E-09 -9.4105 0.32309E-09 -9.4907 0.83136E+00 -0.0802 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11614E-04 -4.9350 0.11582E-04 -4.9362 0.99725E+00 -0.0012 61 KCl,aq 0.12912E-08 -8.8890 0.12912E-08 -8.8890 0.10000E+01 0.0000 63 KOH,aq 0.75353E-06 -6.1229 0.75353E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.47123E-13 -13.3268 0.39176E-13 -13.4070 0.83136E+00 -0.0802 65 MgCO3,aq 0.26230E-11 -11.5812 0.26230E-11 -11.5812 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.23479E-13 -13.6293 0.19559E-13 -13.7086 0.83304E+00 -0.0793 67 MgCl+ 0.10983E-13 -13.9593 0.91494E-14 -14.0386 0.83304E+00 -0.0793 68 MgF+ 0.71423E-15 -15.1462 0.59498E-15 -15.2255 0.83304E+00 -0.0793 69 MgOH+ 0.73143E-10 -10.1358 0.60931E-10 -10.2152 0.83304E+00 -0.0793 71 MnF+ 0.19762E-15 -15.7042 0.16462E-15 -15.7835 0.83304E+00 -0.0793 72 MnO,aq 0.18112E-08 -8.7420 0.18112E-08 -8.7420 0.10000E+01 0.0000 73 MnOH+ 0.49826E-09 -9.3025 0.41507E-09 -9.3819 0.83304E+00 -0.0793 74 MnO2-2 0.19170E-10 -10.7174 0.97580E-11 -11.0106 0.50904E+00 -0.2932 75 HMnO2- 0.20182E-09 -9.6950 0.16778E-09 -9.7753 0.83136E+00 -0.0802 78 MnCl+ 0.40966E-13 -13.3876 0.34126E-13 -13.4669 0.83304E+00 -0.0793 79 MnSO4,aq 0.56699E-19 -19.2464 0.56699E-19 -19.2464 0.10000E+01 0.0000 80 NaCl,aq 0.29902E-05 -5.5243 0.29902E-05 -5.5243 0.10000E+01 0.0000 81 NaF,aq 0.37255E-08 -8.4288 0.37255E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96019E-04 -4.0176 0.96019E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.88713E-02 -2.0520 0.73613E-02 -2.1330 0.82978E+00 -0.0810 89 HPO3-2 0.14915E-14 -14.8264 0.75921E-15 -15.1196 0.50904E+00 -0.2932 91 H2PO3- 0.14372E-18 -18.8425 0.11949E-18 -18.9227 0.83136E+00 -0.0802 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36593E-10 -10.4366 0.30452E-10 -10.5164 0.83219E+00 -0.0798 94 PO4-3 0.93594E-09 -9.0288 0.21866E-09 -9.6602 0.23363E+00 -0.6315 98 HP2O7-3 0.83303E-18 -18.0793 0.18501E-18 -18.7328 0.22209E+00 -0.6535 99 P2O7-4 0.78364E-17 -17.1059 0.56316E-18 -18.2494 0.71864E-01 -1.1435 100 H2S,aq 0.29706E-06 -6.5272 0.29625E-06 -6.5283 0.99725E+00 -0.0012 101 S2-2 0.56063E-11 -11.2513 0.28538E-11 -11.5446 0.50904E+00 -0.2932 102 S3-2 0.19320E-18 -18.7140 0.98346E-19 -19.0072 0.50904E+00 -0.2932 107 SO3-2 0.53093E-16 -16.2750 0.27438E-16 -16.5616 0.51680E+00 -0.2867 108 HSO3- 0.16218E-18 -18.7900 0.13483E-18 -18.8702 0.83136E+00 -0.0802 109 HSO4- 0.16534E-17 -17.7816 0.13788E-17 -17.8605 0.83390E+00 -0.0789 111 S2O3-2 0.12463E-18 -18.9044 0.63443E-19 -19.1976 0.50904E+00 -0.2932 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9380463E-10 -.2143535E-01 -.2156539E+02 0.0000 2 H2O 0.1000000E+01 0.5550897E+02 0.9981517E+06 0.0000 3 Cl- 0.6187383E-03 0.6217299E-03 0.2200121E+02 6.8165 4 SO4-- 0.3573187E-10 -.4038077E-02 -.3871830E+03 9.4712 5 HCO3- 0.7426690E-04 0.4244717E-02 0.2585193E+03 5.8965 6 HS- 0.1468840E-02 0.5507215E-02 0.1817960E+03 7.1921 7 Al+++ 0.1194822E-28 0.5049009E-05 0.1359766E+00 0.7390 8 H4SiO4 0.6959228E-03 0.1300494E-01 0.1247651E+04 -3.1574 9 Ca++ 0.1538270E-06 0.3237616E-06 0.1295160E-01 13.1018 10 Mg++ 0.2407094E-10 0.1032875E-09 0.2506458E-05 9.2942 11 Fe++ 0.6634397E-13 0.3447299E-07 0.1921634E-02 6.7350 12 K+ 0.1662860E-03 0.1670408E-03 0.6519487E+01 6.2466 13 Na+ 0.2110302E-01 0.2355113E-01 0.5404293E+03 8.3493 14 Mn++ 0.2134176E-10 0.2551847E-08 0.1399328E-03 9.2428 15 F- 0.1093576E-05 0.1097304E-05 0.2080782E-01 4.0629 16 HPO4-- 0.4122165E-07 0.4219418E-07 0.4042227E-02 12.5334 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278943E+02 -.1065045E-01 -.8277878E+02 0.0000000E+00 2 H2O -.7145055E+01 0.2758040E+02 -.3472546E+02 0.0000000E+00 3 Cl- 0.3089152E-03 0.3089152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387309E+00 -.2006375E-02 0.1407373E+00 0.0000000E+00 5 HCO3- 0.2109047E-02 0.2109047E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1380010E+00 0.2736336E-02 -.1407373E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2508671E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6461685E-02 0.5205744E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1608655E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5131984E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1712839E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8299655E-04 0.1061488E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1170171E-01 0.6264675E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1267921E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1169600E-04 0.5452106E-06 0.1115079E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2096477E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.2019E-14 Mass of aqueous solution: 0.497789E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0289900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.257 0.796 1641. 3.215 30.04 629.8 andradite 0.5629 -0.250 286.1 2.456 5.237 74.33 grossular 0.1363 -0.865 61.41 1.788 1.124 17.09 apatite-OH 0.9851E-02 -2.006 4.949 0.694 0.9059E-01 1.572 apatite-F 0.1115E-04 -4.953 0.5623E-02 -2.250 0.1029E-03 0.1757E-02 clinochlore 0.7083 -0.150 393.7 2.595 7.207 149.7 daphnite 0.2051 -0.688 146.3 2.165 2.679 44.34 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2071 -0.684 44.86 1.652 0.8212 13.71 hedenbergite 0.5372E-01 -1.270 13.33 1.125 0.2440 3.651 microcline 0.9330 -0.030 259.7 2.414 4.754 101.4 stilbite 3.222 0.508 2270. 3.356 41.56 1059. stilpnomelane-Fe 0.2569 -0.590 276.9 2.442 5.069 95.65 tr.625ac.25prg.125 0.6060E-01 -1.218 51.80 1.714 0.9483 16.67 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1863E-01 0.1863E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.346572 g Volume = 2210.857881 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0289900 moles log = -1.5378 Original solution: 1000.0103000 g Original solution / Rock added: 34495.01 (Water/Rock Ratio), log = 4.5378 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 6.9916 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1486E+00 0.9682 0.1006E+01 0.1039E+01 CO2,gas 0.1609E-06 0.9861 0.1110E-05 0.1125E-05 CH4,gas 0.8492E+00 0.9976 0.5923E+01 0.5938E+01 H2,gas 0.2167E-02 1.0037 0.1521E-01 0.1515E-01 H2S,gas 0.1197E-05 0.9733 0.8144E-05 0.8367E-05 S2,gas 0.1540E-26 1.0000 0.1077E-25 0.1077E-25 CO,gas 0.6432E-12 1.0000 0.4497E-11 0.4497E-11 SO3,gas 0.6073E-47 1.0000 0.4246E-46 0.4246E-46 SO2,gas 0.3593E-26 1.0000 0.2512E-25 0.2512E-25 HF,gas 0.1712E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1867E-17 1.0000 0.1305E-16 0.1305E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.60662E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 -0.18198E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.31 -7.65 -2.551 0.13069E+05 -5.955 3 CH4,gas 4.54 3.62 -0.93 -0.232 0.15818E+04 0.773 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.02 -6.79 -3.394 0.11591E+05 -5.089 6 S2,gas -7.34 -35.00 -27.67 -4.256 0.47240E+05 -25.968 7 CO,gas 3.21 -9.83 -13.05 -4.014 0.22276E+05 -11.347 8 SO3,gas 17.12 -30.95 -48.07 -12.018 0.82080E+05 -46.372 9 SO2,gas 0.83 -26.47 -27.30 -7.280 0.46612E+05 -25.600 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.39 -18.58 -9.292 0.31730E+05 -16.884 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80646E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93635E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.21 -2.18 -0.726 0.37200E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.21 -2.02 -0.675 0.34558E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68940E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65528E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.35 -2.25 -0.642 0.38348E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.35 -1.80 -0.515 0.30771E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48027E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82221E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.78 -2.54 -0.597 0.43330E+04 146 pyrrhotite -4.26 -6.28 -2.02 -0.674 0.34543E+04 147 pyrrhotiteFe0.875 -6.02 -7.68 -1.66 -0.612 0.28415E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22424E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28675E+03 154 rhodochrosite -0.98 -5.07 -4.09 -1.365 0.69918E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23226E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.58 -4.97 -1.657 0.84875E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27806E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47085E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90673E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77499E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65447E+04 184 troilite-low -4.41 -6.28 -1.87 -0.624 0.31971E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60605E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66179E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.78 -2.80 -0.933 0.47770E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0289900 MOLES New total amount of reactant added: 0.0299900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8667E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0299900 Water: Moles liquid = 0.2758E+02 kg liquid = 0.4969E+00 Moles total = -.7144E+01 kg total = -.1287E+00 Activity = 0.9999 Stoichiometric ionic strength = .8909096E-02 Osmotic coef. = 0.9244 True ionic strength = .2145016E-01 Chg. balance for total moles = -.8667E-10 Max. difference allowed = 0.3148E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93984E-10 -10.0269 0.78622E-10 -10.1045 0.83655E+00 -0.0775 2 H2O 0.99992E+00 0.0000 0.99992E+00 0.0000 3 Cl- 0.63053E-03 -3.2003 0.52412E-03 -3.2806 0.83124E+00 -0.0803 4 SO4-- 0.36870E-10 -10.4333 0.18800E-10 -10.7259 0.50989E+00 -0.2925 5 HCO3- 0.76696E-04 -4.1152 0.63851E-04 -4.1948 0.83252E+00 -0.0796 6 HS- 0.15177E-02 -2.8188 0.12618E-02 -2.8990 0.83137E+00 -0.0802 7 Al+++ 0.12028E-28 -28.9198 0.26649E-29 -29.5743 0.22157E+00 -0.6545 8 H4SiO4 0.69592E-03 -3.1574 0.69592E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15446E-06 -6.8112 0.78149E-07 -7.1071 0.50594E+00 -0.2959 10 Mg++ 0.24171E-10 -10.6167 0.12170E-10 -10.9147 0.50349E+00 -0.2980 11 Fe++ 0.66619E-13 -13.1764 0.33581E-13 -13.4739 0.50408E+00 -0.2975 12 K+ 0.16660E-03 -3.7783 0.13874E-03 -3.8578 0.83273E+00 -0.0795 13 Na+ 0.21144E-01 -1.6748 0.17572E-01 -1.7552 0.83108E+00 -0.0804 14 Mn++ 0.21432E-10 -10.6689 0.10813E-10 -10.9661 0.50452E+00 -0.2971 15 F- 0.10918E-05 -5.9619 0.90557E-06 -6.0431 0.82943E+00 -0.0812 16 HPO4-- 0.41098E-07 -7.3862 0.20959E-07 -7.6786 0.50997E+00 -0.2925 18 HSiO3- 0.99437E-02 -2.0025 0.82656E-02 -2.0827 0.83124E+00 -0.0803 19 Ca(HSiO3)+ 0.17662E-07 -7.7530 0.14711E-07 -7.8324 0.83292E+00 -0.0794 20 Mg(HSiO3)+ 0.34229E-11 -11.4656 0.28510E-11 -11.5450 0.83292E+00 -0.0794 21 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.70410E-16 -16.1524 0.58646E-16 -16.2318 0.83292E+00 -0.0794 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.50406E-05 -5.2975 0.41820E-05 -5.3786 0.82966E+00 -0.0811 26 CH4,aq 0.41739E-02 -2.3795 0.41625E-02 -2.3806 0.99727E+00 -0.0012 27 C2H6,aq 0.25645E-09 -9.5910 0.25575E-09 -9.5922 0.99727E+00 -0.0012 28 C3H8,aq 0.36378E-15 -15.4392 0.36279E-15 -15.4403 0.99727E+00 -0.0012 30 ethanol,aq 0.94127E-17 -17.0263 0.93870E-17 -17.0275 0.99727E+00 -0.0012 31 CO,aq 0.31214E-14 -14.5057 0.31214E-14 -14.5057 0.10000E+01 0.0000 32 CO2,aq 0.10757E-07 -7.9683 0.10728E-07 -7.9695 0.99727E+00 -0.0012 33 CO3-2 0.13943E-03 -3.8556 0.70936E-04 -4.1491 0.50875E+00 -0.2935 34 CaCO3,aq 0.69511E-07 -7.1579 0.69511E-07 -7.1579 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.15292E-09 -9.8155 0.12737E-09 -9.8949 0.83292E+00 -0.0794 36 CaCl+ 0.79582E-10 -10.0992 0.66285E-10 -10.1786 0.83292E+00 -0.0794 37 CaCl2,aq 0.82538E-14 -14.0833 0.82538E-14 -14.0833 0.10000E+01 0.0000 38 CaF+ 0.12405E-11 -11.9064 0.10332E-11 -11.9858 0.83292E+00 -0.0794 39 CaOH+ 0.85044E-07 -7.0704 0.70835E-07 -7.1498 0.83292E+00 -0.0794 40 CaSO4,aq 0.46653E-15 -15.3311 0.46653E-15 -15.3311 0.10000E+01 0.0000 41 HCl,aq 0.75511E-14 -14.1220 0.75511E-14 -14.1220 0.10000E+01 0.0000 45 HF,aq 0.48740E-12 -12.3121 0.48740E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17927E-18 -18.7465 0.14902E-18 -18.8268 0.83124E+00 -0.0803 48 FeCl+ 0.33447E-16 -16.4756 0.27859E-16 -16.5550 0.83292E+00 -0.0794 51 FeF+ 0.18657E-17 -17.7291 0.15540E-17 -17.8085 0.83292E+00 -0.0794 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16691E-10 -10.7775 0.13902E-10 -10.8569 0.83292E+00 -0.0794 55 HFeO2- 0.33798E-07 -7.4711 0.28094E-07 -7.5514 0.83124E+00 -0.0803 56 FeO+ 0.11698E-16 -16.9319 0.97437E-17 -17.0113 0.83292E+00 -0.0794 58 FeO2- 0.38799E-09 -9.4112 0.32251E-09 -9.4915 0.83124E+00 -0.0803 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11613E-04 -4.9350 0.11582E-04 -4.9362 0.99727E+00 -0.0012 61 KCl,aq 0.13179E-08 -8.8801 0.13179E-08 -8.8801 0.10000E+01 0.0000 63 KOH,aq 0.75353E-06 -6.1229 0.75353E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.48690E-13 -13.3126 0.40473E-13 -13.3928 0.83124E+00 -0.0803 65 MgCO3,aq 0.27133E-11 -11.5665 0.27133E-11 -11.5665 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.24334E-13 -13.6138 0.20268E-13 -13.6932 0.83292E+00 -0.0794 67 MgCl+ 0.11232E-13 -13.9495 0.93556E-14 -14.0289 0.83292E+00 -0.0794 68 MgF+ 0.71560E-15 -15.1453 0.59604E-15 -15.2247 0.83292E+00 -0.0794 69 MgOH+ 0.73284E-10 -10.1350 0.61039E-10 -10.2144 0.83292E+00 -0.0794 71 MnF+ 0.19802E-15 -15.7033 0.16493E-15 -15.7827 0.83292E+00 -0.0794 72 MnO,aq 0.18114E-08 -8.7420 0.18114E-08 -8.7420 0.10000E+01 0.0000 73 MnOH+ 0.49926E-09 -9.3017 0.41585E-09 -9.3811 0.83292E+00 -0.0794 74 MnO2-2 0.19114E-10 -10.7186 0.97243E-11 -11.0121 0.50875E+00 -0.2935 75 HMnO2- 0.20151E-09 -9.6957 0.16750E-09 -9.7760 0.83124E+00 -0.0803 78 MnCl+ 0.41900E-13 -13.3778 0.34899E-13 -13.4572 0.83292E+00 -0.0794 79 MnSO4,aq 0.58685E-19 -19.2315 0.58685E-19 -19.2315 0.10000E+01 0.0000 80 NaCl,aq 0.30521E-05 -5.5154 0.30521E-05 -5.5154 0.10000E+01 0.0000 81 NaF,aq 0.37254E-08 -8.4288 0.37254E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96018E-04 -4.0176 0.96018E-04 -4.0176 0.10000E+01 0.0000 84 OH- 0.88569E-02 -2.0527 0.73482E-02 -2.1338 0.82966E+00 -0.0811 89 HPO3-2 0.14870E-14 -14.8277 0.75651E-15 -15.1212 0.50875E+00 -0.2935 91 H2PO3- 0.14349E-18 -18.8432 0.11927E-18 -18.9235 0.83124E+00 -0.0803 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36533E-10 -10.4373 0.30398E-10 -10.5172 0.83207E+00 -0.0798 94 PO4-3 0.93208E-09 -9.0305 0.21750E-09 -9.6625 0.23335E+00 -0.6320 98 HP2O7-3 0.82967E-18 -18.0811 0.18403E-18 -18.7351 0.22181E+00 -0.6540 99 P2O7-4 0.77983E-17 -17.1080 0.55917E-18 -18.2525 0.71704E-01 -1.1445 100 H2S,aq 0.30743E-06 -6.5122 0.30660E-06 -6.5134 0.99727E+00 -0.0012 101 S2-2 0.59869E-11 -11.2228 0.30459E-11 -11.5163 0.50875E+00 -0.2935 102 S3-2 0.21353E-18 -18.6705 0.10863E-18 -18.9640 0.50875E+00 -0.2935 107 SO3-2 0.54782E-16 -16.2614 0.28296E-16 -16.5483 0.51652E+00 -0.2869 108 HSO3- 0.16757E-18 -18.7758 0.13929E-18 -18.8561 0.83124E+00 -0.0803 109 HSO4- 0.17084E-17 -17.7674 0.14244E-17 -17.8464 0.83378E+00 -0.0789 111 S2O3-2 0.13310E-18 -18.8758 0.67713E-19 -19.1693 0.50875E+00 -0.2935 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9398433E-10 -.2140883E-01 -.2153861E+02 0.0000 2 H2O 0.1000000E+01 0.5550911E+02 0.9981501E+06 0.0000 3 Cl- 0.6305276E-03 0.6335812E-03 0.2242050E+02 6.8239 4 SO4-- 0.3686980E-10 -.4176763E-02 -.4004791E+03 9.4831 5 HCO3- 0.7669617E-04 0.4390069E-02 0.2673706E+03 5.9096 6 HS- 0.1517681E-02 0.5694752E-02 0.1879860E+03 7.2054 7 Al+++ 0.1202766E-28 0.5040798E-05 0.1357549E+00 0.7390 8 H4SiO4 0.6959208E-03 0.1298868E-01 0.1246086E+04 -3.1574 9 Ca++ 0.1544640E-06 0.3269142E-06 0.1307766E-01 13.1018 10 Mg++ 0.2417079E-10 0.1036278E-09 0.2514705E-05 9.2942 11 Fe++ 0.6661921E-13 0.3441710E-07 0.1918511E-02 6.7350 12 K+ 0.1666045E-03 0.1673594E-03 0.6531894E+01 6.2466 13 Na+ 0.2114351E-01 0.2359167E-01 0.5413574E+03 8.3493 14 Mn++ 0.2143235E-10 0.2552754E-08 0.1399819E-03 9.2429 15 F- 0.1091795E-05 0.1095522E-05 0.2077395E-01 4.0614 16 HPO4-- 0.4109847E-07 0.4206708E-07 0.4030034E-02 12.5303 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278932E+02 -.1063766E-01 -.8277868E+02 0.0000000E+00 2 H2O -.7144236E+01 0.2758149E+02 -.3472572E+02 0.0000000E+00 3 Cl- 0.3148152E-03 0.3148152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387357E+00 -.2075359E-02 0.1408111E+00 0.0000000E+00 5 HCO3- 0.2181347E-02 0.2181347E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1379815E+00 0.2829621E-02 -.1408111E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2504683E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6453842E-02 0.5205745E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1624378E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5149081E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1710124E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8315789E-04 0.1061488E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1172228E-01 0.6264655E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1268418E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1209600E-04 0.5443453E-06 0.1155165E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2090238E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1135E-13 Mass of aqueous solution: 0.497810E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0299900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.257 0.796 1641. 3.215 30.04 629.8 andradite 0.5632 -0.249 286.2 2.457 5.240 74.36 grossular 0.1364 -0.865 61.44 1.788 1.125 17.09 apatite-OH 0.9851E-02 -2.007 4.948 0.694 0.9059E-01 1.572 apatite-F 0.1155E-04 -4.937 0.5826E-02 -2.235 0.1067E-03 0.1820E-02 clinochlore 0.7082 -0.150 393.6 2.595 7.207 149.7 daphnite 0.2050 -0.688 146.3 2.165 2.678 44.33 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2052 -0.688 44.44 1.648 0.8136 13.58 hedenbergite 0.5322E-01 -1.274 13.20 1.121 0.2417 3.617 microcline 0.9331 -0.030 259.7 2.415 4.755 101.5 stilbite 3.222 0.508 2270. 3.356 41.56 1059. stilpnomelane-Fe 0.2567 -0.591 276.7 2.442 5.066 95.59 tr.625ac.25prg.125 0.6123E-01 -1.213 52.34 1.719 0.9581 16.84 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1863E-01 0.1863E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.346852 g Volume = 2210.860644 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0299900 moles log = -1.5230 Original solution: 1000.0103000 g Original solution / Rock added: 33344.79 (Water/Rock Ratio), log = 4.5230 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 7.1973 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1444E+00 0.9679 0.1006E+01 0.1039E+01 CO2,gas 0.1618E-06 0.9857 0.1148E-05 0.1164E-05 CH4,gas 0.8535E+00 0.9974 0.6127E+01 0.6143E+01 H2,gas 0.2105E-02 1.0038 0.1521E-01 0.1515E-01 H2S,gas 0.1204E-05 0.9725 0.8428E-05 0.8666E-05 S2,gas 0.1602E-26 1.0000 0.1153E-25 0.1153E-25 CO,gas 0.6463E-12 1.0000 0.4651E-11 0.4651E-11 SO3,gas 0.6105E-47 1.0000 0.4394E-46 0.4394E-46 SO2,gas 0.3612E-26 1.0000 0.2600E-25 0.2600E-25 HF,gas 0.1663E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1851E-17 1.0000 0.1332E-16 0.1332E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.30 -7.64 -2.546 0.13044E+05 -5.940 3 CH4,gas 4.54 3.63 -0.91 -0.228 0.15568E+04 0.787 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -13.00 -6.77 -3.387 0.11565E+05 -5.074 6 S2,gas -7.34 -34.97 -27.64 -4.252 0.47190E+05 -25.938 7 CO,gas 3.21 -9.82 -13.03 -4.010 0.22251E+05 -11.332 8 SO3,gas 17.12 -30.93 -48.06 -12.014 0.82054E+05 -46.357 9 SO2,gas 0.83 -26.45 -27.28 -7.276 0.46587E+05 -25.585 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.39 -18.57 -9.287 0.31715E+05 -16.875 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80644E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93635E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.20 -2.16 -0.721 0.36949E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.20 -2.01 -0.670 0.34307E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68940E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65527E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.33 -2.23 -0.637 0.38098E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.33 -1.79 -0.511 0.30520E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82220E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.75 -2.51 -0.590 0.42820E+04 146 pyrrhotite -4.26 -6.27 -2.01 -0.669 0.34289E+04 147 pyrrhotiteFe0.875 -6.02 -7.67 -1.65 -0.607 0.28161E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22423E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28675E+03 154 rhodochrosite -0.98 -5.06 -4.08 -1.360 0.69667E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23226E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.56 -4.96 -1.652 0.84625E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27806E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47084E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90673E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77499E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.27 -1.86 -0.619 0.31717E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60605E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.76 -2.78 -0.928 0.47515E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0299900 MOLES New total amount of reactant added: 0.0309900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8666E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0309900 Water: Moles liquid = 0.2758E+02 kg liquid = 0.4969E+00 Moles total = -.7143E+01 kg total = -.1287E+00 Activity = 0.9999 Stoichiometric ionic strength = .8824443E-02 Osmotic coef. = 0.9247 True ionic strength = .2149521E-01 Chg. balance for total moles = -.8666E-10 Max. difference allowed = 0.3207E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94164E-10 -10.0261 0.78762E-10 -10.1037 0.83643E+00 -0.0776 2 H2O 0.99992E+00 0.0000 0.99992E+00 0.0000 3 Cl- 0.64232E-03 -3.1923 0.53384E-03 -3.2726 0.83112E+00 -0.0803 4 SO4-- 0.38005E-10 -10.4202 0.19367E-10 -10.7129 0.50961E+00 -0.2928 5 HCO3- 0.79118E-04 -4.1017 0.65858E-04 -4.1814 0.83240E+00 -0.0797 6 HS- 0.15665E-02 -2.8051 0.13022E-02 -2.8853 0.83125E+00 -0.0803 7 Al+++ 0.12108E-28 -28.9169 0.26792E-29 -29.5720 0.22128E+00 -0.6551 8 H4SiO4 0.69592E-03 -3.1574 0.69592E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15510E-06 -6.8094 0.78427E-07 -7.1055 0.50565E+00 -0.2962 10 Mg++ 0.24271E-10 -10.6149 0.12213E-10 -10.9132 0.50320E+00 -0.2983 11 Fe++ 0.66895E-13 -13.1746 0.33701E-13 -13.4724 0.50378E+00 -0.2978 12 K+ 0.16692E-03 -3.7775 0.13898E-03 -3.8570 0.83261E+00 -0.0796 13 Na+ 0.21184E-01 -1.6740 0.17603E-01 -1.7544 0.83096E+00 -0.0804 14 Mn++ 0.21523E-10 -10.6671 0.10853E-10 -10.9645 0.50423E+00 -0.2974 15 F- 0.10900E-05 -5.9626 0.90396E-06 -6.0438 0.82931E+00 -0.0813 16 HPO4-- 0.40976E-07 -7.3875 0.20885E-07 -7.6802 0.50968E+00 -0.2927 18 HSiO3- 0.99275E-02 -2.0032 0.82509E-02 -2.0835 0.83112E+00 -0.0803 19 Ca(HSiO3)+ 0.17695E-07 -7.7521 0.14737E-07 -7.8316 0.83280E+00 -0.0795 20 Mg(HSiO3)+ 0.34294E-11 -11.4648 0.28560E-11 -11.5442 0.83280E+00 -0.0795 21 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.70546E-16 -16.1515 0.58751E-16 -16.2310 0.83280E+00 -0.0795 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.50325E-05 -5.2982 0.41746E-05 -5.3794 0.82953E+00 -0.0812 26 CH4,aq 0.43126E-02 -2.3653 0.43009E-02 -2.3664 0.99730E+00 -0.0012 27 C2H6,aq 0.27379E-09 -9.5626 0.27305E-09 -9.5638 0.99730E+00 -0.0012 28 C3H8,aq 0.40129E-15 -15.3965 0.40021E-15 -15.3977 0.99730E+00 -0.0012 30 ethanol,aq 0.10049E-16 -16.9979 0.10022E-16 -16.9991 0.99730E+00 -0.0012 31 CO,aq 0.32252E-14 -14.4914 0.32252E-14 -14.4914 0.10000E+01 0.0000 32 CO2,aq 0.11115E-07 -7.9541 0.11085E-07 -7.9553 0.99730E+00 -0.0012 33 CO3-2 0.14364E-03 -3.8427 0.73036E-04 -4.1365 0.50846E+00 -0.2937 34 CaCO3,aq 0.71823E-07 -7.1437 0.71823E-07 -7.1437 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.15831E-09 -9.8005 0.13184E-09 -9.8799 0.83280E+00 -0.0795 36 CaCl+ 0.81358E-10 -10.0896 0.67755E-10 -10.1691 0.83280E+00 -0.0795 37 CaCl2,aq 0.85933E-14 -14.0658 0.85933E-14 -14.0658 0.10000E+01 0.0000 38 CaF+ 0.12429E-11 -11.9056 0.10351E-11 -11.9850 0.83280E+00 -0.0795 39 CaOH+ 0.85207E-07 -7.0695 0.70961E-07 -7.1490 0.83280E+00 -0.0795 40 CaSO4,aq 0.48233E-15 -15.3167 0.48233E-15 -15.3167 0.10000E+01 0.0000 41 HCl,aq 0.77048E-14 -14.1132 0.77048E-14 -14.1132 0.10000E+01 0.0000 45 HF,aq 0.48740E-12 -12.3121 0.48740E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17898E-18 -18.7472 0.14876E-18 -18.8275 0.83112E+00 -0.0803 48 FeCl+ 0.34194E-16 -16.4661 0.28476E-16 -16.5455 0.83280E+00 -0.0795 51 FeF+ 0.18693E-17 -17.7283 0.15568E-17 -17.8078 0.83280E+00 -0.0795 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16723E-10 -10.7767 0.13927E-10 -10.8561 0.83280E+00 -0.0795 55 HFeO2- 0.33743E-07 -7.4718 0.28044E-07 -7.5522 0.83112E+00 -0.0803 56 FeO+ 0.11721E-16 -16.9310 0.97610E-17 -17.0105 0.83280E+00 -0.0795 58 FeO2- 0.38736E-09 -9.4119 0.32194E-09 -9.4922 0.83112E+00 -0.0803 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11613E-04 -4.9351 0.11582E-04 -4.9362 0.99730E+00 -0.0012 61 KCl,aq 0.13447E-08 -8.8714 0.13447E-08 -8.8714 0.10000E+01 0.0000 63 KOH,aq 0.75352E-06 -6.1229 0.75352E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.50256E-13 -13.2988 0.41769E-13 -13.3791 0.83112E+00 -0.0803 65 MgCO3,aq 0.28035E-11 -11.5523 0.28035E-11 -11.5523 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.25191E-13 -13.5987 0.20979E-13 -13.6782 0.83280E+00 -0.0795 67 MgCl+ 0.11483E-13 -13.9399 0.95630E-14 -14.0194 0.83280E+00 -0.0795 68 MgF+ 0.71697E-15 -15.1445 0.59709E-15 -15.2240 0.83280E+00 -0.0795 69 MgOH+ 0.73424E-10 -10.1342 0.61148E-10 -10.2136 0.83280E+00 -0.0795 71 MnF+ 0.19842E-15 -15.7024 0.16524E-15 -15.7819 0.83280E+00 -0.0795 72 MnO,aq 0.18116E-08 -8.7419 0.18116E-08 -8.7419 0.10000E+01 0.0000 73 MnOH+ 0.50027E-09 -9.3008 0.41663E-09 -9.3803 0.83280E+00 -0.0795 74 MnO2-2 0.19059E-10 -10.7199 0.96907E-11 -11.0136 0.50846E+00 -0.2937 75 HMnO2- 0.20120E-09 -9.6964 0.16722E-09 -9.7767 0.83112E+00 -0.0803 78 MnCl+ 0.42839E-13 -13.3682 0.35676E-13 -13.4476 0.83280E+00 -0.0795 79 MnSO4,aq 0.60679E-19 -19.2170 0.60679E-19 -19.2170 0.10000E+01 0.0000 80 NaCl,aq 0.31143E-05 -5.5066 0.31143E-05 -5.5066 0.10000E+01 0.0000 81 NaF,aq 0.37254E-08 -8.4288 0.37254E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96017E-04 -4.0177 0.96017E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.88424E-02 -2.0534 0.73351E-02 -2.1346 0.82953E+00 -0.0812 89 HPO3-2 0.14826E-14 -14.8290 0.75383E-15 -15.1227 0.50846E+00 -0.2937 91 H2PO3- 0.14325E-18 -18.8439 0.11906E-18 -18.9242 0.83112E+00 -0.0803 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36474E-10 -10.4380 0.30344E-10 -10.5179 0.83195E+00 -0.0799 94 PO4-3 0.92824E-09 -9.0323 0.21634E-09 -9.6649 0.23307E+00 -0.6325 98 HP2O7-3 0.82632E-18 -18.0828 0.18305E-18 -18.7374 0.22152E+00 -0.6546 99 P2O7-4 0.77605E-17 -17.1101 0.55522E-18 -18.2555 0.71544E-01 -1.1454 100 H2S,aq 0.31784E-06 -6.4978 0.31698E-06 -6.4990 0.99730E+00 -0.0012 101 S2-2 0.63802E-11 -11.1952 0.32441E-11 -11.4889 0.50846E+00 -0.2937 102 S3-2 0.23526E-18 -18.6285 0.11962E-18 -18.9222 0.50846E+00 -0.2937 107 SO3-2 0.56467E-16 -16.2482 0.29151E-16 -16.5354 0.51624E+00 -0.2871 108 HSO3- 0.17297E-18 -18.7620 0.14376E-18 -18.8424 0.83112E+00 -0.0803 109 HSO4- 0.17634E-17 -17.7537 0.14701E-17 -17.8327 0.83366E+00 -0.0790 111 S2O3-2 0.14184E-18 -18.8482 0.72120E-19 -19.1419 0.50846E+00 -0.2937 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9416415E-10 -.2138236E-01 -.2151190E+02 0.0000 2 H2O 0.1000000E+01 0.5550925E+02 0.9981485E+06 0.0000 3 Cl- 0.6423158E-03 0.6454315E-03 0.2283976E+02 6.8311 4 SO4-- 0.3800454E-10 -.4315471E-02 -.4137770E+03 9.4944 5 HCO3- 0.7911801E-04 0.4535410E-02 0.2762213E+03 5.9223 6 HS- 0.1566518E-02 0.5882308E-02 0.1941764E+03 7.2183 7 Al+++ 0.1210753E-28 0.5032611E-05 0.1355338E+00 0.7391 8 H4SiO4 0.6959189E-03 0.1297246E-01 0.1244525E+04 -3.1574 9 Ca++ 0.1551027E-06 0.3300692E-06 0.1320381E-01 13.1018 10 Mg++ 0.2427094E-10 0.1039654E-09 0.2522887E-05 9.2942 11 Fe++ 0.6689523E-13 0.3436137E-07 0.1915396E-02 6.7350 12 K+ 0.1669233E-03 0.1676781E-03 0.6544308E+01 6.2466 13 Na+ 0.2118403E-01 0.2363224E-01 0.5422860E+03 8.3493 14 Mn++ 0.2152320E-10 0.2553664E-08 0.1400312E-03 9.2429 15 F- 0.1090018E-05 0.1093745E-05 0.2074017E-01 4.0598 16 HPO4-- 0.4097580E-07 0.4194052E-07 0.4017893E-02 12.5272 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278921E+02 -.1062491E-01 -.8277859E+02 0.0000000E+00 2 H2O -.7143417E+01 0.2758257E+02 -.3472598E+02 0.0000000E+00 3 Cl- 0.3207152E-03 0.3207152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387405E+00 -.2144360E-02 0.1408849E+00 0.0000000E+00 5 HCO3- 0.2253647E-02 0.2253647E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1379619E+00 0.2922921E-02 -.1408849E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2500706E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6446022E-02 0.5205746E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1640115E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5166045E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1707418E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8331934E-04 0.1061488E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1174287E-01 0.6264634E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1268917E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1249600E-04 0.5434824E-06 0.1195252E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2084026E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.2442E-13 Mass of aqueous solution: 0.497830E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0309900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.257 0.796 1641. 3.215 30.04 629.8 andradite 0.5635 -0.249 286.4 2.457 5.243 74.40 grossular 0.1365 -0.865 61.47 1.789 1.125 17.10 apatite-OH 0.9851E-02 -2.007 4.948 0.694 0.9059E-01 1.572 apatite-F 0.1195E-04 -4.923 0.6028E-02 -2.220 0.1104E-03 0.1883E-02 clinochlore 0.7081 -0.150 393.6 2.595 7.206 149.7 daphnite 0.2050 -0.688 146.3 2.165 2.678 44.33 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2033 -0.692 44.03 1.644 0.8060 13.46 hedenbergite 0.5272E-01 -1.278 13.08 1.117 0.2395 3.583 microcline 0.9332 -0.030 259.7 2.415 4.755 101.5 stilbite 3.222 0.508 2270. 3.356 41.56 1059. stilpnomelane-Fe 0.2566 -0.591 276.6 2.442 5.063 95.54 tr.625ac.25prg.125 0.6186E-01 -1.209 52.87 1.723 0.9679 17.02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1863E-01 0.1863E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.347131 g Volume = 2210.863409 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0309900 moles log = -1.5088 Original solution: 1000.0103000 g Original solution / Rock added: 32268.81 (Water/Rock Ratio), log = 4.5088 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 7.4030 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1404E+00 0.9676 0.1006E+01 0.1040E+01 CO2,gas 0.1626E-06 0.9853 0.1186E-05 0.1204E-05 CH4,gas 0.8575E+00 0.9972 0.6331E+01 0.6348E+01 H2,gas 0.2046E-02 1.0040 0.1521E-01 0.1515E-01 H2S,gas 0.1211E-05 0.9717 0.8714E-05 0.8967E-05 S2,gas 0.1665E-26 1.0000 0.1233E-25 0.1233E-25 CO,gas 0.6492E-12 1.0000 0.4806E-11 0.4806E-11 SO3,gas 0.6137E-47 1.0000 0.4543E-46 0.4543E-46 SO2,gas 0.3631E-26 1.0000 0.2688E-25 0.2688E-25 HF,gas 0.1617E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1836E-17 1.0000 0.1360E-16 0.1360E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.29 -7.62 -2.542 0.13019E+05 -5.926 3 CH4,gas 4.54 3.65 -0.90 -0.224 0.15325E+04 0.801 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -12.99 -6.76 -3.379 0.11540E+05 -5.060 6 S2,gas -7.34 -34.94 -27.61 -4.247 0.47140E+05 -25.909 7 CO,gas 3.21 -9.80 -13.02 -4.005 0.22226E+05 -11.318 8 SO3,gas 17.12 -30.92 -48.04 -12.010 0.82030E+05 -46.343 9 SO2,gas 0.83 -26.44 -27.27 -7.272 0.46562E+05 -25.571 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.38 -18.57 -9.283 0.31700E+05 -16.867 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80642E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93636E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.18 -2.15 -0.717 0.36707E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.18 -2.00 -0.665 0.34064E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68940E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65526E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.32 -2.22 -0.633 0.37855E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.32 -1.77 -0.507 0.30277E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82219E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.73 -2.48 -0.583 0.42326E+04 146 pyrrhotite -4.26 -6.25 -1.99 -0.665 0.34042E+04 147 pyrrhotiteFe0.875 -6.02 -7.65 -1.63 -0.601 0.27914E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22422E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28675E+03 154 rhodochrosite -0.98 -5.04 -4.07 -1.355 0.69423E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23225E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.55 -4.94 -1.647 0.84382E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27806E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47083E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90673E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77499E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.25 -1.84 -0.614 0.31470E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60605E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.75 -2.77 -0.923 0.47267E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0309900 MOLES New total amount of reactant added: 0.0319900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8667E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0319900 Water: Moles liquid = 0.2758E+02 kg liquid = 0.4969E+00 Moles total = -.7143E+01 kg total = -.1287E+00 Activity = 0.9999 Stoichiometric ionic strength = .8739763E-02 Osmotic coef. = 0.9251 True ionic strength = .2154026E-01 Chg. balance for total moles = -.8667E-10 Max. difference allowed = 0.3266E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94344E-10 -10.0253 0.78902E-10 -10.1029 0.83632E+00 -0.0776 2 H2O 0.99992E+00 0.0000 0.99992E+00 0.0000 3 Cl- 0.65410E-03 -3.1844 0.54356E-03 -3.2648 0.83100E+00 -0.0804 4 SO4-- 0.39136E-10 -10.4074 0.19933E-10 -10.7004 0.50932E+00 -0.2930 5 HCO3- 0.81532E-04 -4.0887 0.67858E-04 -4.1684 0.83228E+00 -0.0797 6 HS- 0.16154E-02 -2.7917 0.13426E-02 -2.8721 0.83113E+00 -0.0803 7 Al+++ 0.12188E-28 -28.9141 0.26935E-29 -29.5697 0.22100E+00 -0.6556 8 H4SiO4 0.69592E-03 -3.1574 0.69592E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15574E-06 -6.8076 0.78706E-07 -7.1040 0.50536E+00 -0.2964 10 Mg++ 0.24371E-10 -10.6131 0.12257E-10 -10.9116 0.50291E+00 -0.2985 11 Fe++ 0.67172E-13 -13.1728 0.33821E-13 -13.4708 0.50349E+00 -0.2980 12 K+ 0.16724E-03 -3.7767 0.13923E-03 -3.8563 0.83249E+00 -0.0796 13 Na+ 0.21225E-01 -1.6732 0.17634E-01 -1.7536 0.83084E+00 -0.0805 14 Mn++ 0.21614E-10 -10.6653 0.10892E-10 -10.9629 0.50393E+00 -0.2976 15 F- 0.10882E-05 -5.9633 0.90236E-06 -6.0446 0.82919E+00 -0.0813 16 HPO4-- 0.40854E-07 -7.3888 0.20811E-07 -7.6817 0.50940E+00 -0.2929 18 HSiO3- 0.99113E-02 -2.0039 0.82363E-02 -2.0843 0.83100E+00 -0.0804 19 Ca(HSiO3)+ 0.17729E-07 -7.7513 0.14763E-07 -7.8308 0.83268E+00 -0.0795 20 Mg(HSiO3)+ 0.34360E-11 -11.4639 0.28611E-11 -11.5435 0.83268E+00 -0.0795 21 NaHSiO3,aq 0.23491E-02 -2.6291 0.23491E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.70681E-16 -16.1507 0.58855E-16 -16.2302 0.83268E+00 -0.0795 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.50243E-05 -5.2989 0.41672E-05 -5.3802 0.82941E+00 -0.0812 26 CH4,aq 0.44513E-02 -2.3515 0.44394E-02 -2.3527 0.99732E+00 -0.0012 27 C2H6,aq 0.29169E-09 -9.5351 0.29091E-09 -9.5362 0.99732E+00 -0.0012 28 C3H8,aq 0.44130E-15 -15.3553 0.44012E-15 -15.3564 0.99732E+00 -0.0012 30 ethanol,aq 0.10706E-16 -16.9704 0.10678E-16 -16.9715 0.99732E+00 -0.0012 31 CO,aq 0.33290E-14 -14.4777 0.33290E-14 -14.4777 0.10000E+01 0.0000 32 CO2,aq 0.11472E-07 -7.9404 0.11441E-07 -7.9415 0.99732E+00 -0.0012 33 CO3-2 0.14782E-03 -3.8303 0.75120E-04 -4.1242 0.50818E+00 -0.2940 34 CaCO3,aq 0.74135E-07 -7.1300 0.74135E-07 -7.1300 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.16372E-09 -9.7859 0.13633E-09 -9.8654 0.83268E+00 -0.0795 36 CaCl+ 0.83145E-10 -10.0802 0.69233E-10 -10.1597 0.83268E+00 -0.0795 37 CaCl2,aq 0.89407E-14 -14.0486 0.89407E-14 -14.0486 0.10000E+01 0.0000 38 CaF+ 0.12453E-11 -11.9047 0.10369E-11 -11.9843 0.83268E+00 -0.0795 39 CaOH+ 0.85371E-07 -7.0687 0.71087E-07 -7.1482 0.83268E+00 -0.0795 40 CaSO4,aq 0.49818E-15 -15.3026 0.49818E-15 -15.3026 0.10000E+01 0.0000 41 HCl,aq 0.78590E-14 -14.1046 0.78590E-14 -14.1046 0.10000E+01 0.0000 45 HF,aq 0.48740E-12 -12.3121 0.48740E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17869E-18 -18.7479 0.14849E-18 -18.8283 0.83100E+00 -0.0804 48 FeCl+ 0.34945E-16 -16.4566 0.29098E-16 -16.5361 0.83268E+00 -0.0795 51 FeF+ 0.18729E-17 -17.7275 0.15595E-17 -17.8070 0.83268E+00 -0.0795 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16755E-10 -10.7759 0.13952E-10 -10.8554 0.83268E+00 -0.0795 55 HFeO2- 0.33688E-07 -7.4725 0.27995E-07 -7.5529 0.83100E+00 -0.0804 56 FeO+ 0.11743E-16 -16.9302 0.97783E-17 -17.0097 0.83268E+00 -0.0795 58 FeO2- 0.38673E-09 -9.4126 0.32137E-09 -9.4930 0.83100E+00 -0.0804 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11613E-04 -4.9351 0.11582E-04 -4.9362 0.99732E+00 -0.0012 61 KCl,aq 0.13716E-08 -8.8628 0.13716E-08 -8.8628 0.10000E+01 0.0000 63 KOH,aq 0.75351E-06 -6.1229 0.75351E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.51823E-13 -13.2855 0.43064E-13 -13.3659 0.83100E+00 -0.0804 65 MgCO3,aq 0.28938E-11 -11.5385 0.28938E-11 -11.5385 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.26052E-13 -13.5842 0.21693E-13 -13.6637 0.83268E+00 -0.0795 67 MgCl+ 0.11735E-13 -13.9305 0.97717E-14 -14.0100 0.83268E+00 -0.0795 68 MgF+ 0.71834E-15 -15.1437 0.59815E-15 -15.2232 0.83268E+00 -0.0795 69 MgOH+ 0.73565E-10 -10.1333 0.61256E-10 -10.2129 0.83268E+00 -0.0795 71 MnF+ 0.19882E-15 -15.7015 0.16555E-15 -15.7811 0.83268E+00 -0.0795 72 MnO,aq 0.18117E-08 -8.7419 0.18117E-08 -8.7419 0.10000E+01 0.0000 73 MnOH+ 0.50128E-09 -9.2999 0.41740E-09 -9.3794 0.83268E+00 -0.0795 74 MnO2-2 0.19004E-10 -10.7212 0.96573E-11 -11.0151 0.50818E+00 -0.2940 75 HMnO2- 0.20089E-09 -9.6970 0.16694E-09 -9.7774 0.83100E+00 -0.0804 78 MnCl+ 0.43784E-13 -13.3587 0.36458E-13 -13.4382 0.83268E+00 -0.0795 79 MnSO4,aq 0.62678E-19 -19.2029 0.62678E-19 -19.2029 0.10000E+01 0.0000 80 NaCl,aq 0.31765E-05 -5.4980 0.31765E-05 -5.4980 0.10000E+01 0.0000 81 NaF,aq 0.37254E-08 -8.4288 0.37254E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96016E-04 -4.0177 0.96016E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.88281E-02 -2.0541 0.73221E-02 -2.1354 0.82941E+00 -0.0812 89 HPO3-2 0.14782E-14 -14.8303 0.75116E-15 -15.1243 0.50818E+00 -0.2940 91 H2PO3- 0.14302E-18 -18.8446 0.11885E-18 -18.9250 0.83100E+00 -0.0804 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36414E-10 -10.4387 0.30291E-10 -10.5187 0.83183E+00 -0.0800 94 PO4-3 0.92442E-09 -9.0341 0.21519E-09 -9.6672 0.23279E+00 -0.6330 98 HP2O7-3 0.82299E-18 -18.0846 0.18208E-18 -18.7397 0.22124E+00 -0.6551 99 P2O7-4 0.77228E-17 -17.1122 0.55129E-18 -18.2586 0.71385E-01 -1.1464 100 H2S,aq 0.32827E-06 -6.4838 0.32739E-06 -6.4849 0.99732E+00 -0.0012 101 S2-2 0.67861E-11 -11.1684 0.34485E-11 -11.4624 0.50818E+00 -0.2940 102 S3-2 0.25845E-18 -18.5876 0.13134E-18 -18.8816 0.50818E+00 -0.2940 107 SO3-2 0.58147E-16 -16.2355 0.30002E-16 -16.5229 0.51596E+00 -0.2874 108 HSO3- 0.17836E-18 -18.7487 0.14822E-18 -18.8291 0.83100E+00 -0.0804 109 HSO4- 0.18184E-17 -17.7403 0.15157E-17 -17.8194 0.83354E+00 -0.0791 111 S2O3-2 0.15086E-18 -18.8214 0.76664E-19 -19.1154 0.50818E+00 -0.2940 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9434408E-10 -.2135596E-01 -.2148525E+02 0.0000 2 H2O 0.1000000E+01 0.5550939E+02 0.9981469E+06 0.0000 3 Cl- 0.6541030E-03 0.6572810E-03 0.2325898E+02 6.8382 4 SO4-- 0.3913611E-10 -.4454201E-02 -.4270770E+03 9.5054 5 HCO3- 0.8153245E-04 0.4680740E-02 0.2850712E+03 5.9345 6 HS- 0.1615352E-02 0.6069881E-02 0.2003675E+03 7.2308 7 Al+++ 0.1218782E-28 0.5024447E-05 0.1353134E+00 0.7391 8 H4SiO4 0.6959169E-03 0.1295629E-01 0.1242969E+04 -3.1574 9 Ca++ 0.1557433E-06 0.3332268E-06 0.1333007E-01 13.1018 10 Mg++ 0.2437137E-10 0.1043039E-09 0.2531091E-05 9.2942 11 Fe++ 0.6717205E-13 0.3430580E-07 0.1912291E-02 6.7350 12 K+ 0.1672422E-03 0.1679971E-03 0.6556731E+01 6.2466 13 Na+ 0.2122458E-01 0.2367283E-01 0.5432152E+03 8.3493 14 Mn++ 0.2161433E-10 0.2554575E-08 0.1400806E-03 9.2429 15 F- 0.1088246E-05 0.1091973E-05 0.2070649E-01 4.0583 16 HPO4-- 0.4085366E-07 0.4181449E-07 0.4005803E-02 12.5241 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278910E+02 -.1061218E-01 -.8277849E+02 0.0000000E+00 2 H2O -.7142599E+01 0.2758365E+02 -.3472625E+02 0.0000000E+00 3 Cl- 0.3266152E-03 0.3266152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387453E+00 -.2213376E-02 0.1409586E+00 0.0000000E+00 5 HCO3- 0.2325947E-02 0.2325947E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1379424E+00 0.3016237E-02 -.1409586E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2496741E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6438224E-02 0.5205747E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1655866E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5183054E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1704719E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8348090E-04 0.1061487E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1176347E-01 0.6264613E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1269416E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1289600E-04 0.5426219E-06 0.1235338E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2077840E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.9361E-14 Mass of aqueous solution: 0.497850E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0319900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.257 0.796 1641. 3.215 30.04 629.8 andradite 0.5638 -0.249 286.5 2.457 5.246 74.44 grossular 0.1365 -0.865 61.50 1.789 1.126 17.11 apatite-OH 0.9850E-02 -2.007 4.948 0.694 0.9058E-01 1.572 apatite-F 0.1235E-04 -4.908 0.6230E-02 -2.206 0.1141E-03 0.1946E-02 clinochlore 0.7081 -0.150 393.6 2.595 7.205 149.7 daphnite 0.2050 -0.688 146.3 2.165 2.678 44.32 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2014 -0.696 43.61 1.640 0.7984 13.33 hedenbergite 0.5223E-01 -1.282 12.96 1.113 0.2372 3.549 microcline 0.9333 -0.030 259.8 2.415 4.756 101.5 stilbite 3.222 0.508 2270. 3.356 41.56 1059. stilpnomelane-Fe 0.2564 -0.591 276.4 2.442 5.060 95.48 tr.625ac.25prg.125 0.6248E-01 -1.204 53.41 1.728 0.9778 17.19 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1864E-01 0.1864E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.347408 g Volume = 2210.866173 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0319900 moles log = -1.4950 Original solution: 1000.0103000 g Original solution / Rock added: 31260.09 (Water/Rock Ratio), log = 4.4950 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 7.6089 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1367E+00 0.9673 0.1006E+01 0.1040E+01 CO2,gas 0.1633E-06 0.9849 0.1224E-05 0.1243E-05 CH4,gas 0.8613E+00 0.9970 0.6534E+01 0.6554E+01 H2,gas 0.1990E-02 1.0041 0.1521E-01 0.1514E-01 H2S,gas 0.1218E-05 0.9710 0.9000E-05 0.9269E-05 S2,gas 0.1728E-26 1.0000 0.1315E-25 0.1315E-25 CO,gas 0.6520E-12 1.0000 0.4961E-11 0.4961E-11 SO3,gas 0.6167E-47 1.0000 0.4692E-46 0.4692E-46 SO2,gas 0.3648E-26 1.0000 0.2776E-25 0.2776E-25 HF,gas 0.1573E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1823E-17 1.0000 0.1387E-16 0.1387E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.27 -7.61 -2.537 0.12996E+05 -5.912 3 CH4,gas 4.54 3.66 -0.88 -0.221 0.15090E+04 0.815 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -12.97 -6.74 -3.372 0.11516E+05 -5.046 6 S2,gas -7.34 -34.92 -27.58 -4.243 0.47092E+05 -25.881 7 CO,gas 3.21 -9.79 -13.00 -4.001 0.22203E+05 -11.304 8 SO3,gas 17.12 -30.91 -48.03 -12.007 0.82006E+05 -46.329 9 SO2,gas 0.83 -26.42 -27.26 -7.268 0.46538E+05 -25.557 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.37 -18.56 -9.278 0.31686E+05 -16.858 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80639E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93636E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.17 -2.14 -0.712 0.36472E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.17 -1.98 -0.660 0.33829E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68940E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65525E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.31 -2.20 -0.629 0.37620E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.31 -1.76 -0.503 0.30042E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82218E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.70 -2.45 -0.577 0.41847E+04 146 pyrrhotite -4.26 -6.24 -1.98 -0.660 0.33802E+04 147 pyrrhotiteFe0.875 -6.02 -7.64 -1.62 -0.596 0.27674E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22422E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28675E+03 154 rhodochrosite -0.98 -5.03 -4.05 -1.351 0.69188E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23224E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.54 -4.93 -1.643 0.84147E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27806E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47081E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90673E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77500E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.24 -1.83 -0.610 0.31230E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60605E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.73 -2.75 -0.918 0.47027E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0319900 MOLES New total amount of reactant added: 0.0329900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8668E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0329900 Water: Moles liquid = 0.2758E+02 kg liquid = 0.4969E+00 Moles total = -.7142E+01 kg total = -.1287E+00 Activity = 0.9999 Stoichiometric ionic strength = .8655057E-02 Osmotic coef. = 0.9254 True ionic strength = .2158532E-01 Chg. balance for total moles = -.8668E-10 Max. difference allowed = 0.3325E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94524E-10 -10.0245 0.79042E-10 -10.1021 0.83621E+00 -0.0777 2 H2O 0.99992E+00 0.0000 0.99992E+00 0.0000 3 Cl- 0.66589E-03 -3.1766 0.55327E-03 -3.2571 0.83088E+00 -0.0805 4 SO4-- 0.40265E-10 -10.3951 0.20496E-10 -10.6883 0.50903E+00 -0.2933 5 HCO3- 0.83940E-04 -4.0760 0.69852E-04 -4.1558 0.83217E+00 -0.0798 6 HS- 0.16642E-02 -2.7788 0.13829E-02 -2.8592 0.83101E+00 -0.0804 7 Al+++ 0.12269E-28 -28.9112 0.27079E-29 -29.5674 0.22072E+00 -0.6562 8 H4SiO4 0.69591E-03 -3.1574 0.69591E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15639E-06 -6.8058 0.78985E-07 -7.1025 0.50507E+00 -0.2967 10 Mg++ 0.24472E-10 -10.6113 0.12300E-10 -10.9101 0.50262E+00 -0.2988 11 Fe++ 0.67450E-13 -13.1710 0.33941E-13 -13.4693 0.50320E+00 -0.2983 12 K+ 0.16756E-03 -3.7758 0.13947E-03 -3.8555 0.83237E+00 -0.0797 13 Na+ 0.21265E-01 -1.6723 0.17665E-01 -1.7529 0.83071E+00 -0.0805 14 Mn++ 0.21706E-10 -10.6634 0.10932E-10 -10.9613 0.50364E+00 -0.2979 15 F- 0.10865E-05 -5.9640 0.90076E-06 -6.0454 0.82906E+00 -0.0814 16 HPO4-- 0.40732E-07 -7.3901 0.20737E-07 -7.6833 0.50911E+00 -0.2932 18 HSiO3- 0.98952E-02 -2.0046 0.82217E-02 -2.0850 0.83088E+00 -0.0805 19 Ca(HSiO3)+ 0.17763E-07 -7.7505 0.14789E-07 -7.8301 0.83256E+00 -0.0796 20 Mg(HSiO3)+ 0.34426E-11 -11.4631 0.28662E-11 -11.5427 0.83256E+00 -0.0796 21 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.70817E-16 -16.1499 0.58960E-16 -16.2294 0.83256E+00 -0.0796 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.50162E-05 -5.2996 0.41598E-05 -5.3809 0.82929E+00 -0.0813 26 CH4,aq 0.45900E-02 -2.3382 0.45779E-02 -2.3393 0.99735E+00 -0.0012 27 C2H6,aq 0.31017E-09 -9.5084 0.30935E-09 -9.5096 0.99735E+00 -0.0012 28 C3H8,aq 0.48390E-15 -15.3152 0.48261E-15 -15.3164 0.99735E+00 -0.0012 30 ethanol,aq 0.11384E-16 -16.9437 0.11354E-16 -16.9448 0.99735E+00 -0.0012 31 CO,aq 0.34329E-14 -14.4643 0.34329E-14 -14.4643 0.10000E+01 0.0000 32 CO2,aq 0.11830E-07 -7.9270 0.11798E-07 -7.9282 0.99735E+00 -0.0012 33 CO3-2 0.15198E-03 -3.8182 0.77190E-04 -4.1124 0.50789E+00 -0.2942 34 CaCO3,aq 0.76448E-07 -7.1166 0.76448E-07 -7.1166 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.16916E-09 -9.7717 0.14083E-09 -9.8513 0.83256E+00 -0.0796 36 CaCl+ 0.84943E-10 -10.0709 0.70721E-10 -10.1505 0.83256E+00 -0.0796 37 CaCl2,aq 0.92959E-14 -14.0317 0.92959E-14 -14.0317 0.10000E+01 0.0000 38 CaF+ 0.12477E-11 -11.9039 0.10387E-11 -11.9835 0.83256E+00 -0.0796 39 CaOH+ 0.85534E-07 -7.0679 0.71213E-07 -7.1474 0.83256E+00 -0.0796 40 CaSO4,aq 0.51407E-15 -15.2890 0.51407E-15 -15.2890 0.10000E+01 0.0000 41 HCl,aq 0.80136E-14 -14.0962 0.80136E-14 -14.0962 0.10000E+01 0.0000 45 HF,aq 0.48740E-12 -12.3121 0.48740E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17840E-18 -18.7486 0.14823E-18 -18.8291 0.83088E+00 -0.0805 48 FeCl+ 0.35701E-16 -16.4473 0.29723E-16 -16.5269 0.83256E+00 -0.0796 51 FeF+ 0.18765E-17 -17.7267 0.15623E-17 -17.8062 0.83256E+00 -0.0796 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16787E-10 -10.7750 0.13976E-10 -10.8546 0.83256E+00 -0.0796 55 HFeO2- 0.33633E-07 -7.4732 0.27945E-07 -7.5537 0.83088E+00 -0.0805 56 FeO+ 0.11766E-16 -16.9294 0.97957E-17 -17.0090 0.83256E+00 -0.0796 58 FeO2- 0.38610E-09 -9.4133 0.32080E-09 -9.4938 0.83088E+00 -0.0805 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11612E-04 -4.9351 0.11582E-04 -4.9362 0.99735E+00 -0.0012 61 KCl,aq 0.13986E-08 -8.8543 0.13986E-08 -8.8543 0.10000E+01 0.0000 63 KOH,aq 0.75350E-06 -6.1229 0.75350E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.53389E-13 -13.2726 0.44359E-13 -13.3530 0.83088E+00 -0.0805 65 MgCO3,aq 0.29841E-11 -11.5252 0.29841E-11 -11.5252 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.26917E-13 -13.5700 0.22410E-13 -13.6496 0.83256E+00 -0.0796 67 MgCl+ 0.11989E-13 -13.9212 0.99816E-14 -14.0008 0.83256E+00 -0.0796 68 MgF+ 0.71972E-15 -15.1428 0.59921E-15 -15.2224 0.83256E+00 -0.0796 69 MgOH+ 0.73706E-10 -10.1325 0.61365E-10 -10.2121 0.83256E+00 -0.0796 71 MnF+ 0.19922E-15 -15.7007 0.16586E-15 -15.7803 0.83256E+00 -0.0796 72 MnO,aq 0.18119E-08 -8.7419 0.18119E-08 -8.7419 0.10000E+01 0.0000 73 MnOH+ 0.50229E-09 -9.2990 0.41819E-09 -9.3786 0.83256E+00 -0.0796 74 MnO2-2 0.18949E-10 -10.7224 0.96241E-11 -11.0166 0.50789E+00 -0.2942 75 HMnO2- 0.20058E-09 -9.6977 0.16666E-09 -9.7782 0.83088E+00 -0.0805 78 MnCl+ 0.44736E-13 -13.3493 0.37245E-13 -13.4289 0.83256E+00 -0.0796 79 MnSO4,aq 0.64685E-19 -19.1892 0.64685E-19 -19.1892 0.10000E+01 0.0000 80 NaCl,aq 0.32390E-05 -5.4896 0.32390E-05 -5.4896 0.10000E+01 0.0000 81 NaF,aq 0.37253E-08 -8.4288 0.37253E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96015E-04 -4.0177 0.96015E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.88137E-02 -2.0548 0.73091E-02 -2.1361 0.82929E+00 -0.0813 89 HPO3-2 0.14738E-14 -14.8316 0.74851E-15 -15.1258 0.50789E+00 -0.2942 91 H2PO3- 0.14279E-18 -18.8453 0.11864E-18 -18.9258 0.83088E+00 -0.0805 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36355E-10 -10.4394 0.30237E-10 -10.5195 0.83171E+00 -0.0800 94 PO4-3 0.92062E-09 -9.0359 0.21405E-09 -9.6695 0.23251E+00 -0.6336 98 HP2O7-3 0.81968E-18 -18.0864 0.18111E-18 -18.7420 0.22096E+00 -0.6557 99 P2O7-4 0.76854E-17 -17.1143 0.54740E-18 -18.2617 0.71226E-01 -1.1474 100 H2S,aq 0.33874E-06 -6.4701 0.33784E-06 -6.4713 0.99735E+00 -0.0012 101 S2-2 0.72045E-11 -11.1424 0.36591E-11 -11.4366 0.50789E+00 -0.2942 102 S3-2 0.28314E-18 -18.5480 0.14380E-18 -18.8422 0.50789E+00 -0.2942 107 SO3-2 0.59823E-16 -16.2231 0.30849E-16 -16.5108 0.51568E+00 -0.2876 108 HSO3- 0.18375E-18 -18.7358 0.15267E-18 -18.8162 0.83088E+00 -0.0805 109 HSO4- 0.18733E-17 -17.7274 0.15613E-17 -17.8065 0.83343E+00 -0.0791 111 S2O3-2 0.16016E-18 -18.7954 0.81346E-19 -19.0897 0.50789E+00 -0.2942 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9452413E-10 -.2132963E-01 -.2145866E+02 0.0000 2 H2O 0.1000000E+01 0.5550953E+02 0.9981454E+06 0.0000 3 Cl- 0.6658891E-03 0.6691296E-03 0.2367816E+02 6.8451 4 SO4-- 0.4026452E-10 -.4592952E-02 -.4403789E+03 9.5160 5 HCO3- 0.8393953E-04 0.4826060E-02 0.2939204E+03 5.9463 6 HS- 0.1664181E-02 0.6257472E-02 0.2065590E+03 7.2429 7 Al+++ 0.1226855E-28 0.5016306E-05 0.1350936E+00 0.7391 8 H4SiO4 0.6959150E-03 0.1294017E-01 0.1241417E+04 -3.1574 9 Ca++ 0.1563857E-06 0.3363868E-06 0.1345643E-01 13.1018 10 Mg++ 0.2447208E-10 0.1046441E-09 0.2539336E-05 9.2942 11 Fe++ 0.6744966E-13 0.3425039E-07 0.1909194E-02 6.7350 12 K+ 0.1675614E-03 0.1683163E-03 0.6569161E+01 6.2466 13 Na+ 0.2126516E-01 0.2371345E-01 0.5441450E+03 8.3493 14 Mn++ 0.2170573E-10 0.2555489E-08 0.1401302E-03 9.2430 15 F- 0.1086480E-05 0.1090207E-05 0.2067291E-01 4.0568 16 HPO4-- 0.4073202E-07 0.4168901E-07 0.3993765E-02 12.5210 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278900E+02 -.1059948E-01 -.8277840E+02 0.0000000E+00 2 H2O -.7141780E+01 0.2758473E+02 -.3472651E+02 0.0000000E+00 3 Cl- 0.3325152E-03 0.3325152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387500E+00 -.2282407E-02 0.1410325E+00 0.0000000E+00 5 HCO3- 0.2398247E-02 0.2398247E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1379229E+00 0.3109569E-02 -.1410325E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2492787E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6430449E-02 0.5205747E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1671630E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5200151E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1702028E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8364257E-04 0.1061487E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1178409E-01 0.6264593E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1269917E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1329600E-04 0.5417640E-06 0.1275424E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2071680E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.9756E-14 Mass of aqueous solution: 0.497871E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0329900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.257 0.796 1641. 3.215 30.04 629.8 andradite 0.5641 -0.249 286.7 2.457 5.248 74.48 grossular 0.1366 -0.865 61.54 1.789 1.127 17.12 apatite-OH 0.9850E-02 -2.007 4.948 0.694 0.9058E-01 1.572 apatite-F 0.1275E-04 -4.894 0.6432E-02 -2.192 0.1178E-03 0.2009E-02 clinochlore 0.7080 -0.150 393.5 2.595 7.204 149.7 daphnite 0.2050 -0.688 146.3 2.165 2.677 44.32 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1994 -0.700 43.19 1.635 0.7907 13.20 hedenbergite 0.5173E-01 -1.286 12.83 1.108 0.2349 3.515 microcline 0.9334 -0.030 259.8 2.415 4.756 101.5 stilbite 3.222 0.508 2270. 3.356 41.57 1059. stilpnomelane-Fe 0.2563 -0.591 276.2 2.441 5.057 95.42 tr.625ac.25prg.125 0.6311E-01 -1.200 53.94 1.732 0.9876 17.36 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1864E-01 0.1864E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.347685 g Volume = 2210.868938 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0329900 moles log = -1.4816 Original solution: 1000.0103000 g Original solution / Rock added: 30312.53 (Water/Rock Ratio), log = 4.4816 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 7.8148 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1331E+00 0.9671 0.1006E+01 0.1040E+01 CO2,gas 0.1641E-06 0.9846 0.1262E-05 0.1282E-05 CH4,gas 0.8650E+00 0.9969 0.6738E+01 0.6760E+01 H2,gas 0.1938E-02 1.0042 0.1521E-01 0.1514E-01 H2S,gas 0.1225E-05 0.9702 0.9287E-05 0.9572E-05 S2,gas 0.1792E-26 1.0000 0.1400E-25 0.1400E-25 CO,gas 0.6546E-12 1.0000 0.5116E-11 0.5116E-11 SO3,gas 0.6196E-47 1.0000 0.4842E-46 0.4842E-46 SO2,gas 0.3666E-26 1.0000 0.2865E-25 0.2865E-25 HF,gas 0.1531E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1809E-17 1.0000 0.1414E-16 0.1414E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.26 -7.60 -2.533 0.12973E+05 -5.899 3 CH4,gas 4.54 3.67 -0.87 -0.218 0.14862E+04 0.829 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -12.96 -6.73 -3.366 0.11493E+05 -5.032 6 S2,gas -7.34 -34.89 -27.55 -4.239 0.47046E+05 -25.854 7 CO,gas 3.21 -9.78 -12.99 -3.997 0.22180E+05 -11.291 8 SO3,gas 17.12 -30.89 -48.01 -12.003 0.81982E+05 -46.315 9 SO2,gas 0.83 -26.41 -27.24 -7.265 0.46515E+05 -25.543 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.36 -18.55 -9.274 0.31671E+05 -16.850 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80637E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93636E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 38 aragonite 0.97 -1.16 -2.12 -0.708 0.36244E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.16 -1.97 -0.656 0.33602E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68940E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65525E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.29 -2.19 -0.626 0.37392E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.29 -1.75 -0.499 0.29814E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28620E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82218E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.67 -2.42 -0.570 0.41381E+04 146 pyrrhotite -4.26 -6.23 -1.97 -0.655 0.33569E+04 147 pyrrhotiteFe0.875 -6.02 -7.62 -1.61 -0.591 0.27441E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22421E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28675E+03 154 rhodochrosite -0.98 -5.01 -4.04 -1.346 0.68959E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23223E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.52 -4.91 -1.638 0.83919E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27806E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47080E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90672E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77500E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.23 -1.82 -0.605 0.30997E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60605E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83484E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.72 -2.74 -0.913 0.46793E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0329900 MOLES New total amount of reactant added: 0.0339900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8666E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0339900 Water: Moles liquid = 0.2759E+02 kg liquid = 0.4970E+00 Moles total = -.7141E+01 kg total = -.1286E+00 Activity = 0.9999 Stoichiometric ionic strength = .8570326E-02 Osmotic coef. = 0.9258 True ionic strength = .2163037E-01 Chg. balance for total moles = -.8666E-10 Max. difference allowed = 0.3384E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94704E-10 -10.0236 0.79182E-10 -10.1014 0.83610E+00 -0.0777 2 H2O 0.99991E+00 0.0000 0.99991E+00 0.0000 3 Cl- 0.67767E-03 -3.1690 0.56298E-03 -3.2495 0.83076E+00 -0.0805 4 SO4-- 0.41390E-10 -10.3831 0.21057E-10 -10.6766 0.50875E+00 -0.2935 5 HCO3- 0.86339E-04 -4.0638 0.71838E-04 -4.1436 0.83205E+00 -0.0799 6 HS- 0.17130E-02 -2.7662 0.14233E-02 -2.8467 0.83088E+00 -0.0805 7 Al+++ 0.12350E-28 -28.9083 0.27223E-29 -29.5651 0.22043E+00 -0.6567 8 H4SiO4 0.69591E-03 -3.1574 0.69591E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15703E-06 -6.8040 0.79265E-07 -7.1009 0.50478E+00 -0.2969 10 Mg++ 0.24573E-10 -10.6095 0.12344E-10 -10.9086 0.50232E+00 -0.2990 11 Fe++ 0.67728E-13 -13.1692 0.34061E-13 -13.4677 0.50291E+00 -0.2985 12 K+ 0.16788E-03 -3.7750 0.13972E-03 -3.8547 0.83226E+00 -0.0797 13 Na+ 0.21306E-01 -1.6715 0.17696E-01 -1.7521 0.83059E+00 -0.0806 14 Mn++ 0.21797E-10 -10.6616 0.10972E-10 -10.9597 0.50335E+00 -0.2981 15 F- 0.10847E-05 -5.9647 0.89917E-06 -6.0462 0.82894E+00 -0.0815 16 HPO4-- 0.40611E-07 -7.3914 0.20664E-07 -7.6848 0.50883E+00 -0.2934 18 HSiO3- 0.98792E-02 -2.0053 0.82072E-02 -2.0858 0.83076E+00 -0.0805 19 Ca(HSiO3)+ 0.17797E-07 -7.7496 0.14815E-07 -7.8293 0.83245E+00 -0.0796 20 Mg(HSiO3)+ 0.34492E-11 -11.4623 0.28713E-11 -11.5419 0.83245E+00 -0.0796 21 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.70953E-16 -16.1490 0.59064E-16 -16.2287 0.83245E+00 -0.0796 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.50080E-05 -5.3003 0.41525E-05 -5.3817 0.82916E+00 -0.0814 26 CH4,aq 0.47288E-02 -2.3252 0.47164E-02 -2.3264 0.99738E+00 -0.0011 27 C2H6,aq 0.32922E-09 -9.4825 0.32835E-09 -9.4837 0.99738E+00 -0.0011 28 C3H8,aq 0.52916E-15 -15.2764 0.52777E-15 -15.2776 0.99738E+00 -0.0011 30 ethanol,aq 0.12084E-16 -16.9178 0.12052E-16 -16.9189 0.99738E+00 -0.0011 31 CO,aq 0.35368E-14 -14.4514 0.35368E-14 -14.4514 0.10000E+01 0.0000 32 CO2,aq 0.12188E-07 -7.9141 0.12156E-07 -7.9152 0.99738E+00 -0.0011 33 CO3-2 0.15612E-03 -3.8065 0.79245E-04 -4.1010 0.50760E+00 -0.2945 34 CaCO3,aq 0.78762E-07 -7.1037 0.78762E-07 -7.1037 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.17461E-09 -9.7579 0.14535E-09 -9.8376 0.83245E+00 -0.0796 36 CaCl+ 0.86753E-10 -10.0617 0.72217E-10 -10.1414 0.83245E+00 -0.0796 37 CaCl2,aq 0.96592E-14 -14.0151 0.96592E-14 -14.0151 0.10000E+01 0.0000 38 CaF+ 0.12500E-11 -11.9031 0.10406E-11 -11.9827 0.83245E+00 -0.0796 39 CaOH+ 0.85697E-07 -7.0670 0.71338E-07 -7.1467 0.83245E+00 -0.0796 40 CaSO4,aq 0.53001E-15 -15.2757 0.53001E-15 -15.2757 0.10000E+01 0.0000 41 HCl,aq 0.81687E-14 -14.0878 0.81687E-14 -14.0878 0.10000E+01 0.0000 45 HF,aq 0.48740E-12 -12.3121 0.48740E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17811E-18 -18.7493 0.14796E-18 -18.8298 0.83076E+00 -0.0805 48 FeCl+ 0.36461E-16 -16.4382 0.30352E-16 -16.5178 0.83245E+00 -0.0796 51 FeF+ 0.18801E-17 -17.7258 0.15651E-17 -17.8055 0.83245E+00 -0.0796 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16819E-10 -10.7742 0.14001E-10 -10.8538 0.83245E+00 -0.0796 55 HFeO2- 0.33578E-07 -7.4739 0.27895E-07 -7.5545 0.83076E+00 -0.0805 56 FeO+ 0.11788E-16 -16.9286 0.98130E-17 -17.0082 0.83245E+00 -0.0796 58 FeO2- 0.38547E-09 -9.4140 0.32023E-09 -9.4945 0.83076E+00 -0.0805 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11612E-04 -4.9351 0.11582E-04 -4.9362 0.99738E+00 -0.0011 61 KCl,aq 0.14256E-08 -8.8460 0.14256E-08 -8.8460 0.10000E+01 0.0000 63 KOH,aq 0.75350E-06 -6.1229 0.75350E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.54955E-13 -13.2600 0.45654E-13 -13.3405 0.83076E+00 -0.0805 65 MgCO3,aq 0.30744E-11 -11.5122 0.30744E-11 -11.5122 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.27784E-13 -13.5562 0.23129E-13 -13.6358 0.83245E+00 -0.0796 67 MgCl+ 0.12244E-13 -13.9121 0.10193E-13 -13.9917 0.83245E+00 -0.0796 68 MgF+ 0.72109E-15 -15.1420 0.60027E-15 -15.2217 0.83245E+00 -0.0796 69 MgOH+ 0.73846E-10 -10.1317 0.61473E-10 -10.2113 0.83245E+00 -0.0796 71 MnF+ 0.19962E-15 -15.6998 0.16617E-15 -15.7794 0.83245E+00 -0.0796 72 MnO,aq 0.18121E-08 -8.7418 0.18121E-08 -8.7418 0.10000E+01 0.0000 73 MnOH+ 0.50330E-09 -9.2982 0.41897E-09 -9.3778 0.83245E+00 -0.0796 74 MnO2-2 0.18895E-10 -10.7237 0.95910E-11 -11.0181 0.50760E+00 -0.2945 75 HMnO2- 0.20028E-09 -9.6984 0.16638E-09 -9.7789 0.83076E+00 -0.0805 78 MnCl+ 0.45693E-13 -13.3401 0.38037E-13 -13.4198 0.83245E+00 -0.0796 79 MnSO4,aq 0.66697E-19 -19.1759 0.66697E-19 -19.1759 0.10000E+01 0.0000 80 NaCl,aq 0.33017E-05 -5.4813 0.33017E-05 -5.4813 0.10000E+01 0.0000 81 NaF,aq 0.37253E-08 -8.4288 0.37253E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96014E-04 -4.0177 0.96014E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.87994E-02 -2.0555 0.72962E-02 -2.1369 0.82916E+00 -0.0814 89 HPO3-2 0.14694E-14 -14.8329 0.74586E-15 -15.1273 0.50760E+00 -0.2945 91 H2PO3- 0.14256E-18 -18.8460 0.11843E-18 -18.9265 0.83076E+00 -0.0805 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36296E-10 -10.4401 0.30184E-10 -10.5202 0.83159E+00 -0.0801 94 PO4-3 0.91685E-09 -9.0377 0.21292E-09 -9.6718 0.23223E+00 -0.6341 98 HP2O7-3 0.81639E-18 -18.0881 0.18016E-18 -18.7443 0.22067E+00 -0.6562 99 P2O7-4 0.76482E-17 -17.1164 0.54354E-18 -18.2648 0.71068E-01 -1.1483 100 H2S,aq 0.34923E-06 -6.4569 0.34831E-06 -6.4580 0.99738E+00 -0.0011 101 S2-2 0.76356E-11 -11.1172 0.38758E-11 -11.4116 0.50760E+00 -0.2945 102 S3-2 0.30939E-18 -18.5095 0.15704E-18 -18.8040 0.50760E+00 -0.2945 107 SO3-2 0.61493E-16 -16.2112 0.31694E-16 -16.4990 0.51540E+00 -0.2879 108 HSO3- 0.18914E-18 -18.7232 0.15713E-18 -18.8037 0.83076E+00 -0.0805 109 HSO4- 0.19283E-17 -17.7148 0.16068E-17 -17.7940 0.83331E+00 -0.0792 111 S2O3-2 0.16975E-18 -18.7702 0.86164E-19 -19.0647 0.50760E+00 -0.2945 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9470429E-10 -.2130335E-01 -.2143214E+02 0.0000 2 H2O 0.1000000E+01 0.5550967E+02 0.9981438E+06 0.0000 3 Cl- 0.6776742E-03 0.6809774E-03 0.2409731E+02 6.8519 4 SO4-- 0.4138978E-10 -.4731724E-02 -.4536827E+03 9.5261 5 HCO3- 0.8633927E-04 0.4971369E-02 0.3027689E+03 5.9577 6 HS- 0.1713008E-02 0.6445081E-02 0.2127511E+03 7.2547 7 Al+++ 0.1234970E-28 0.5008189E-05 0.1348745E+00 0.7391 8 H4SiO4 0.6959130E-03 0.1292410E-01 0.1239870E+04 -3.1574 9 Ca++ 0.1570300E-06 0.3395492E-06 0.1358288E-01 13.1018 10 Mg++ 0.2457309E-10 0.1049834E-09 0.2547560E-05 9.2942 11 Fe++ 0.6772806E-13 0.3419513E-07 0.1906106E-02 6.7350 12 K+ 0.1678808E-03 0.1686357E-03 0.6581599E+01 6.2466 13 Na+ 0.2130576E-01 0.2375409E-01 0.5450754E+03 8.3493 14 Mn++ 0.2179740E-10 0.2556405E-08 0.1401798E-03 9.2430 15 F- 0.1084718E-05 0.1088445E-05 0.2063942E-01 4.0552 16 HPO4-- 0.4061090E-07 0.4156405E-07 0.3981778E-02 12.5180 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278889E+02 -.1058681E-01 -.8277830E+02 0.0000000E+00 2 H2O -.7140961E+01 0.2758581E+02 -.3472677E+02 0.0000000E+00 3 Cl- 0.3384152E-03 0.3384152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387548E+00 -.2351454E-02 0.1411063E+00 0.0000000E+00 5 HCO3- 0.2470547E-02 0.2470547E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1379034E+00 0.3202916E-02 -.1411063E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2488845E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6422696E-02 0.5205748E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1687407E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5217204E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1699345E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8380436E-04 0.1061487E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1180472E-01 0.6264572E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1270419E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1369600E-04 0.5409085E-06 0.1315509E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2065547E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1343E-13 Mass of aqueous solution: 0.497891E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0339900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.257 0.796 1641. 3.215 30.03 629.8 andradite 0.5644 -0.248 286.8 2.458 5.251 74.52 grossular 0.1367 -0.864 61.57 1.789 1.127 17.13 apatite-OH 0.9849E-02 -2.007 4.948 0.694 0.9058E-01 1.572 apatite-F 0.1316E-04 -4.881 0.6634E-02 -2.178 0.1215E-03 0.2073E-02 clinochlore 0.7079 -0.150 393.5 2.595 7.204 149.7 daphnite 0.2050 -0.688 146.2 2.165 2.677 44.31 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1975 -0.704 42.78 1.631 0.7831 13.07 hedenbergite 0.5123E-01 -1.290 12.71 1.104 0.2327 3.481 microcline 0.9334 -0.030 259.8 2.415 4.756 101.5 stilbite 3.222 0.508 2271. 3.356 41.57 1059. stilpnomelane-Fe 0.2561 -0.592 276.1 2.441 5.054 95.36 tr.625ac.25prg.125 0.6374E-01 -1.196 54.48 1.736 0.9974 17.54 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1864E-01 0.1864E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.347960 g Volume = 2210.871703 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0339900 moles log = -1.4686 Original solution: 1000.0103000 g Original solution / Rock added: 29420.72 (Water/Rock Ratio), log = 4.4687 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 8.0209 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1297E+00 0.9668 0.1006E+01 0.1040E+01 CO2,gas 0.1647E-06 0.9842 0.1301E-05 0.1321E-05 CH4,gas 0.8684E+00 0.9967 0.6942E+01 0.6965E+01 H2,gas 0.1888E-02 1.0043 0.1521E-01 0.1514E-01 H2S,gas 0.1231E-05 0.9694 0.9575E-05 0.9877E-05 S2,gas 0.1856E-26 1.0000 0.1488E-25 0.1488E-25 CO,gas 0.6571E-12 1.0000 0.5271E-11 0.5271E-11 SO3,gas 0.6224E-47 1.0000 0.4992E-46 0.4992E-46 SO2,gas 0.3682E-26 1.0000 0.2953E-25 0.2953E-25 HF,gas 0.1492E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1797E-17 1.0000 0.1441E-16 0.1441E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.24 -7.58 -2.528 0.12951E+05 -5.886 3 CH4,gas 4.54 3.69 -0.86 -0.214 0.14641E+04 0.841 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -12.95 -6.72 -3.359 0.11471E+05 -5.019 6 S2,gas -7.34 -34.86 -27.53 -4.235 0.47000E+05 -25.827 7 CO,gas 3.21 -9.76 -12.98 -3.993 0.22158E+05 -11.278 8 SO3,gas 17.12 -30.88 -48.00 -12.000 0.81960E+05 -46.302 9 SO2,gas 0.83 -26.40 -27.23 -7.261 0.46492E+05 -25.530 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.35 -18.54 -9.270 0.31657E+05 -16.841 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80635E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93637E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -1.14 -2.11 -0.703 0.36023E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.14 -1.95 -0.652 0.33380E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68940E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65524E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.28 -2.18 -0.622 0.37171E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.28 -1.73 -0.495 0.29593E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82217E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.64 -2.40 -0.564 0.40928E+04 146 pyrrhotite -4.26 -6.21 -1.95 -0.651 0.33343E+04 147 pyrrhotiteFe0.875 -6.02 -7.61 -1.59 -0.586 0.27215E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22420E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28675E+03 154 rhodochrosite -0.98 -5.00 -4.03 -1.342 0.68737E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23223E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.51 -4.90 -1.634 0.83698E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27806E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47078E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90672E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77500E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.21 -1.80 -0.601 0.30771E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60604E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58214E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.71 -2.73 -0.909 0.46566E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0339900 MOLES New total amount of reactant added: 0.0349900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8667E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0349900 Water: Moles liquid = 0.2759E+02 kg liquid = 0.4970E+00 Moles total = -.7140E+01 kg total = -.1286E+00 Activity = 0.9999 Stoichiometric ionic strength = .8485569E-02 Osmotic coef. = 0.9261 True ionic strength = .2167543E-01 Chg. balance for total moles = -.8667E-10 Max. difference allowed = 0.3443E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94885E-10 -10.0228 0.79322E-10 -10.1006 0.83598E+00 -0.0778 2 H2O 0.99991E+00 0.0000 0.99991E+00 0.0000 3 Cl- 0.68946E-03 -3.1615 0.57269E-03 -3.2421 0.83064E+00 -0.0806 4 SO4-- 0.42512E-10 -10.3715 0.21616E-10 -10.6652 0.50847E+00 -0.2937 5 HCO3- 0.88732E-04 -4.0519 0.73818E-04 -4.1318 0.83193E+00 -0.0799 6 HS- 0.17618E-02 -2.7540 0.14637E-02 -2.8346 0.83076E+00 -0.0805 7 Al+++ 0.12431E-28 -28.9055 0.27368E-29 -29.5628 0.22015E+00 -0.6573 8 H4SiO4 0.69591E-03 -3.1574 0.69591E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15768E-06 -6.8022 0.79546E-07 -7.0994 0.50449E+00 -0.2971 10 Mg++ 0.24674E-10 -10.6078 0.12387E-10 -10.9070 0.50203E+00 -0.2993 11 Fe++ 0.68007E-13 -13.1674 0.34182E-13 -13.4662 0.50262E+00 -0.2988 12 K+ 0.16820E-03 -3.7742 0.13997E-03 -3.8540 0.83214E+00 -0.0798 13 Na+ 0.21346E-01 -1.6707 0.17728E-01 -1.7514 0.83047E+00 -0.0807 14 Mn++ 0.21889E-10 -10.6598 0.11012E-10 -10.9581 0.50306E+00 -0.2984 15 F- 0.10830E-05 -5.9654 0.89758E-06 -6.0469 0.82882E+00 -0.0815 16 HPO4-- 0.40490E-07 -7.3926 0.20591E-07 -7.6863 0.50854E+00 -0.2937 18 HSiO3- 0.98631E-02 -2.0060 0.81927E-02 -2.0866 0.83064E+00 -0.0806 19 Ca(HSiO3)+ 0.17831E-07 -7.7488 0.14842E-07 -7.8285 0.83233E+00 -0.0797 20 Mg(HSiO3)+ 0.34558E-11 -11.4615 0.28763E-11 -11.5412 0.83233E+00 -0.0797 21 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.71088E-16 -16.1482 0.59169E-16 -16.2279 0.83233E+00 -0.0797 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.49999E-05 -5.3010 0.41452E-05 -5.3825 0.82904E+00 -0.0814 26 CH4,aq 0.48676E-02 -2.3127 0.48550E-02 -2.3138 0.99740E+00 -0.0011 27 C2H6,aq 0.34884E-09 -9.4574 0.34793E-09 -9.4585 0.99740E+00 -0.0011 28 C3H8,aq 0.57716E-15 -15.2387 0.57566E-15 -15.2398 0.99740E+00 -0.0011 30 ethanol,aq 0.12804E-16 -16.8927 0.12770E-16 -16.8938 0.99740E+00 -0.0011 31 CO,aq 0.36407E-14 -14.4388 0.36407E-14 -14.4388 0.10000E+01 0.0000 32 CO2,aq 0.12545E-07 -7.9015 0.12513E-07 -7.9026 0.99740E+00 -0.0011 33 CO3-2 0.16023E-03 -3.7953 0.81286E-04 -4.0900 0.50732E+00 -0.2947 34 CaCO3,aq 0.81076E-07 -7.0911 0.81076E-07 -7.0911 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.18008E-09 -9.7445 0.14989E-09 -9.8242 0.83233E+00 -0.0797 36 CaCl+ 0.88574E-10 -10.0527 0.73722E-10 -10.1324 0.83233E+00 -0.0797 37 CaCl2,aq 0.10031E-13 -13.9987 0.10031E-13 -13.9987 0.10000E+01 0.0000 38 CaF+ 0.12524E-11 -11.9022 0.10424E-11 -11.9820 0.83233E+00 -0.0797 39 CaOH+ 0.85861E-07 -7.0662 0.71464E-07 -7.1459 0.83233E+00 -0.0797 40 CaSO4,aq 0.54600E-15 -15.2628 0.54600E-15 -15.2628 0.10000E+01 0.0000 41 HCl,aq 0.83242E-14 -14.0797 0.83242E-14 -14.0797 0.10000E+01 0.0000 45 HF,aq 0.48740E-12 -12.3121 0.48740E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17782E-18 -18.7500 0.14770E-18 -18.8306 0.83064E+00 -0.0806 48 FeCl+ 0.37227E-16 -16.4291 0.30985E-16 -16.5089 0.83233E+00 -0.0797 51 FeF+ 0.18837E-17 -17.7250 0.15678E-17 -17.8047 0.83233E+00 -0.0797 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16851E-10 -10.7734 0.14026E-10 -10.8531 0.83233E+00 -0.0797 55 HFeO2- 0.33524E-07 -7.4746 0.27846E-07 -7.5552 0.83064E+00 -0.0806 56 FeO+ 0.11811E-16 -16.9277 0.98304E-17 -17.0074 0.83233E+00 -0.0797 58 FeO2- 0.38485E-09 -9.4147 0.31967E-09 -9.4953 0.83064E+00 -0.0806 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11612E-04 -4.9351 0.11581E-04 -4.9362 0.99740E+00 -0.0011 61 KCl,aq 0.14528E-08 -8.8378 0.14528E-08 -8.8378 0.10000E+01 0.0000 63 KOH,aq 0.75349E-06 -6.1229 0.75349E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.56521E-13 -13.2478 0.46948E-13 -13.3284 0.83064E+00 -0.0806 65 MgCO3,aq 0.31647E-11 -11.4997 0.31647E-11 -11.4997 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.28655E-13 -13.5428 0.23851E-13 -13.6225 0.83233E+00 -0.0797 67 MgCl+ 0.12501E-13 -13.9030 0.10405E-13 -13.9827 0.83233E+00 -0.0797 68 MgF+ 0.72247E-15 -15.1412 0.60133E-15 -15.2209 0.83233E+00 -0.0797 69 MgOH+ 0.73987E-10 -10.1308 0.61582E-10 -10.2105 0.83233E+00 -0.0797 71 MnF+ 0.20002E-15 -15.6989 0.16648E-15 -15.7786 0.83233E+00 -0.0797 72 MnO,aq 0.18123E-08 -8.7418 0.18123E-08 -8.7418 0.10000E+01 0.0000 73 MnOH+ 0.50431E-09 -9.2973 0.41975E-09 -9.3770 0.83233E+00 -0.0797 74 MnO2-2 0.18840E-10 -10.7249 0.95581E-11 -11.0196 0.50732E+00 -0.2947 75 HMnO2- 0.19997E-09 -9.6990 0.16610E-09 -9.7796 0.83064E+00 -0.0806 78 MnCl+ 0.46657E-13 -13.3311 0.38834E-13 -13.4108 0.83233E+00 -0.0797 79 MnSO4,aq 0.68716E-19 -19.1629 0.68716E-19 -19.1629 0.10000E+01 0.0000 80 NaCl,aq 0.33645E-05 -5.4731 0.33645E-05 -5.4731 0.10000E+01 0.0000 81 NaF,aq 0.37253E-08 -8.4288 0.37253E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96013E-04 -4.0177 0.96013E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.87852E-02 -2.0562 0.72833E-02 -2.1377 0.82904E+00 -0.0814 89 HPO3-2 0.14650E-14 -14.8342 0.74323E-15 -15.1289 0.50732E+00 -0.2947 91 H2PO3- 0.14233E-18 -18.8467 0.11822E-18 -18.9273 0.83064E+00 -0.0806 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36237E-10 -10.4408 0.30130E-10 -10.5210 0.83147E+00 -0.0802 94 PO4-3 0.91309E-09 -9.0395 0.21180E-09 -9.6741 0.23196E+00 -0.6346 98 HP2O7-3 0.81311E-18 -18.0898 0.17921E-18 -18.7466 0.22039E+00 -0.6568 99 P2O7-4 0.76112E-17 -17.1185 0.53972E-18 -18.2678 0.70911E-01 -1.1493 100 H2S,aq 0.35976E-06 -6.4440 0.35882E-06 -6.4451 0.99740E+00 -0.0011 101 S2-2 0.80793E-11 -11.0926 0.40987E-11 -11.3873 0.50732E+00 -0.2947 102 S3-2 0.33724E-18 -18.4721 0.17109E-18 -18.7668 0.50732E+00 -0.2947 107 SO3-2 0.63159E-16 -16.1996 0.32535E-16 -16.4877 0.51513E+00 -0.2881 108 HSO3- 0.19453E-18 -18.7110 0.16159E-18 -18.7916 0.83064E+00 -0.0806 109 HSO4- 0.19832E-17 -17.7026 0.16524E-17 -17.7819 0.83319E+00 -0.0793 111 S2O3-2 0.17961E-18 -18.7457 0.91119E-19 -19.0404 0.50732E+00 -0.2947 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9488457E-10 -.2127714E-01 -.2140568E+02 0.0000 2 H2O 0.1000000E+01 0.5550981E+02 0.9981422E+06 0.0000 3 Cl- 0.6894582E-03 0.6928242E-03 0.2451643E+02 6.8585 4 SO4-- 0.4251191E-10 -.4870517E-02 -.4669884E+03 9.5360 5 HCO3- 0.8873170E-04 0.5116667E-02 0.3116166E+03 5.9688 6 HS- 0.1761830E-02 0.6632707E-02 0.2189437E+03 7.2660 7 Al+++ 0.1243129E-28 0.5000095E-05 0.1346559E+00 0.7391 8 H4SiO4 0.6959111E-03 0.1290807E-01 0.1238327E+04 -3.1574 9 Ca++ 0.1576760E-06 0.3427142E-06 0.1370943E-01 13.1018 10 Mg++ 0.2467438E-10 0.1053254E-09 0.2555847E-05 9.2942 11 Fe++ 0.6800725E-13 0.3414004E-07 0.1903028E-02 6.7350 12 K+ 0.1682003E-03 0.1689553E-03 0.6594044E+01 6.2466 13 Na+ 0.2134638E-01 0.2379476E-01 0.5460063E+03 8.3493 14 Mn++ 0.2188935E-10 0.2557324E-08 0.1402296E-03 9.2431 15 F- 0.1082962E-05 0.1086689E-05 0.2060603E-01 4.0537 16 HPO4-- 0.4049029E-07 0.4143962E-07 0.3969841E-02 12.5149 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278878E+02 -.1057417E-01 -.8277821E+02 0.0000000E+00 2 H2O -.7140142E+01 0.2758690E+02 -.3472704E+02 0.0000000E+00 3 Cl- 0.3443152E-03 0.3443152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387596E+00 -.2420517E-02 0.1411801E+00 0.0000000E+00 5 HCO3- 0.2542847E-02 0.2542847E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1378838E+00 0.3296279E-02 -.1411801E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2484914E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6414965E-02 0.5205749E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1703198E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5234391E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1696669E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8396626E-04 0.1061487E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1182536E-01 0.6264552E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1270922E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1409600E-04 0.5400554E-06 0.1355594E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2059439E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.2275E-13 Mass of aqueous solution: 0.497911E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0349900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.257 0.796 1641. 3.215 30.03 629.8 andradite 0.5647 -0.248 287.0 2.458 5.254 74.56 grossular 0.1368 -0.864 61.60 1.790 1.128 17.14 apatite-OH 0.9849E-02 -2.007 4.947 0.694 0.9057E-01 1.572 apatite-F 0.1356E-04 -4.868 0.6836E-02 -2.165 0.1252E-03 0.2136E-02 clinochlore 0.7079 -0.150 393.5 2.595 7.203 149.7 daphnite 0.2049 -0.688 146.2 2.165 2.677 44.31 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1956 -0.709 42.36 1.627 0.7755 12.95 hedenbergite 0.5073E-01 -1.295 12.59 1.100 0.2304 3.447 microcline 0.9335 -0.030 259.8 2.415 4.757 101.5 stilbite 3.222 0.508 2271. 3.356 41.57 1059. stilpnomelane-Fe 0.2559 -0.592 275.9 2.441 5.051 95.30 tr.625ac.25prg.125 0.6437E-01 -1.191 55.02 1.741 1.007 17.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1864E-01 0.1864E-01 1.0000 -1.730 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.348234 g Volume = 2210.874468 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0349900 moles log = -1.4561 Original solution: 1000.0103000 g Original solution / Rock added: 28579.89 (Water/Rock Ratio), log = 4.4561 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 8.2270 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1265E+00 0.9665 0.1006E+01 0.1041E+01 CO2,gas 0.1654E-06 0.9838 0.1339E-05 0.1361E-05 CH4,gas 0.8717E+00 0.9965 0.7146E+01 0.7171E+01 H2,gas 0.1840E-02 1.0044 0.1521E-01 0.1514E-01 H2S,gas 0.1238E-05 0.9687 0.9864E-05 0.1018E-04 S2,gas 0.1920E-26 1.0000 0.1580E-25 0.1580E-25 CO,gas 0.6595E-12 1.0000 0.5425E-11 0.5425E-11 SO3,gas 0.6251E-47 1.0000 0.5143E-46 0.5143E-46 SO2,gas 0.3698E-26 1.0000 0.3043E-25 0.3043E-25 HF,gas 0.1455E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1785E-17 1.0000 0.1469E-16 0.1469E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.23 -7.57 -2.524 0.12929E+05 -5.873 3 CH4,gas 4.54 3.70 -0.84 -0.211 0.14426E+04 0.854 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -12.94 -6.70 -3.352 0.11448E+05 -5.006 6 S2,gas -7.34 -34.84 -27.50 -4.231 0.46956E+05 -25.801 7 CO,gas 3.21 -9.75 -12.96 -3.989 0.22137E+05 -11.266 8 SO3,gas 17.12 -30.87 -47.99 -11.997 0.81938E+05 -46.289 9 SO2,gas 0.83 -26.38 -27.22 -7.258 0.46470E+05 -25.517 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.34 -18.53 -9.266 0.31643E+05 -16.833 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80633E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93637E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -1.13 -2.10 -0.699 0.35808E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.13 -1.94 -0.647 0.33166E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68940E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65523E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.27 -2.16 -0.618 0.36956E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.27 -1.72 -0.492 0.29379E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82216E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.62 -2.37 -0.558 0.40487E+04 146 pyrrhotite -4.26 -6.20 -1.94 -0.647 0.33122E+04 147 pyrrhotiteFe0.875 -6.02 -7.60 -1.58 -0.581 0.26994E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22419E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28674E+03 154 rhodochrosite -0.98 -4.99 -4.01 -1.338 0.68522E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23222E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.50 -4.89 -1.630 0.83483E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27806E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47077E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90672E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77500E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.20 -1.79 -0.596 0.30550E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60604E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.69 -2.71 -0.905 0.46345E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0349900 MOLES New total amount of reactant added: 0.0359900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8668E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0359900 Water: Moles liquid = 0.2759E+02 kg liquid = 0.4970E+00 Moles total = -.7139E+01 kg total = -.1286E+00 Activity = 0.9999 Stoichiometric ionic strength = .8400788E-02 Osmotic coef. = 0.9265 True ionic strength = .2172049E-01 Chg. balance for total moles = -.8668E-10 Max. difference allowed = 0.3502E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95065E-10 -10.0220 0.79462E-10 -10.0998 0.83587E+00 -0.0779 2 H2O 0.99991E+00 0.0000 0.99991E+00 0.0000 3 Cl- 0.70124E-03 -3.1541 0.58239E-03 -3.2348 0.83051E+00 -0.0807 4 SO4-- 0.43631E-10 -10.3602 0.22172E-10 -10.6542 0.50818E+00 -0.2940 5 HCO3- 0.91117E-04 -4.0404 0.75792E-04 -4.1204 0.83181E+00 -0.0800 6 HS- 0.18106E-02 -2.7422 0.15040E-02 -2.8228 0.83064E+00 -0.0806 7 Al+++ 0.12513E-28 -28.9026 0.27513E-29 -29.5605 0.21987E+00 -0.6578 8 H4SiO4 0.69591E-03 -3.1574 0.69591E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15832E-06 -6.8005 0.79827E-07 -7.0978 0.50420E+00 -0.2974 10 Mg++ 0.24776E-10 -10.6060 0.12431E-10 -10.9055 0.50174E+00 -0.2995 11 Fe++ 0.68287E-13 -13.1657 0.34303E-13 -13.4647 0.50233E+00 -0.2990 12 K+ 0.16852E-03 -3.7733 0.14021E-03 -3.8532 0.83202E+00 -0.0799 13 Na+ 0.21387E-01 -1.6698 0.17759E-01 -1.7506 0.83035E+00 -0.0807 14 Mn++ 0.21982E-10 -10.6579 0.11052E-10 -10.9566 0.50277E+00 -0.2986 15 F- 0.10812E-05 -5.9661 0.89599E-06 -6.0477 0.82869E+00 -0.0816 16 HPO4-- 0.40370E-07 -7.3939 0.20518E-07 -7.6879 0.50826E+00 -0.2939 18 HSiO3- 0.98472E-02 -2.0067 0.81782E-02 -2.0873 0.83051E+00 -0.0807 19 Ca(HSiO3)+ 0.17865E-07 -7.7480 0.14868E-07 -7.8278 0.83221E+00 -0.0798 20 Mg(HSiO3)+ 0.34624E-11 -11.4606 0.28814E-11 -11.5404 0.83221E+00 -0.0798 21 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.71224E-16 -16.1474 0.59274E-16 -16.2271 0.83221E+00 -0.0798 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.49919E-05 -5.3017 0.41379E-05 -5.3832 0.82892E+00 -0.0815 26 CH4,aq 0.50064E-02 -2.3005 0.49935E-02 -2.3016 0.99743E+00 -0.0011 27 C2H6,aq 0.36903E-09 -9.4329 0.36808E-09 -9.4341 0.99743E+00 -0.0011 28 C3H8,aq 0.62800E-15 -15.2020 0.62638E-15 -15.2032 0.99743E+00 -0.0011 30 ethanol,aq 0.13545E-16 -16.8682 0.13510E-16 -16.8694 0.99743E+00 -0.0011 31 CO,aq 0.37447E-14 -14.4266 0.37447E-14 -14.4266 0.10000E+01 0.0000 32 CO2,aq 0.12903E-07 -7.8893 0.12870E-07 -7.8904 0.99743E+00 -0.0011 33 CO3-2 0.16431E-03 -3.7843 0.83312E-04 -4.0793 0.50703E+00 -0.2950 34 CaCO3,aq 0.83390E-07 -7.0789 0.83390E-07 -7.0789 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.18558E-09 -9.7315 0.15444E-09 -9.8112 0.83221E+00 -0.0798 36 CaCl+ 0.90406E-10 -10.0438 0.75236E-10 -10.1236 0.83221E+00 -0.0798 37 CaCl2,aq 0.10410E-13 -13.9826 0.10410E-13 -13.9826 0.10000E+01 0.0000 38 CaF+ 0.12548E-11 -11.9014 0.10443E-11 -11.9812 0.83221E+00 -0.0798 39 CaOH+ 0.86025E-07 -7.0654 0.71591E-07 -7.1451 0.83221E+00 -0.0798 40 CaSO4,aq 0.56204E-15 -15.2502 0.56204E-15 -15.2502 0.10000E+01 0.0000 41 HCl,aq 0.84802E-14 -14.0716 0.84802E-14 -14.0716 0.10000E+01 0.0000 45 HF,aq 0.48740E-12 -12.3121 0.48740E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17753E-18 -18.7507 0.14744E-18 -18.8314 0.83051E+00 -0.0807 48 FeCl+ 0.37997E-16 -16.4203 0.31621E-16 -16.5000 0.83221E+00 -0.0798 51 FeF+ 0.18873E-17 -17.7242 0.15706E-17 -17.8039 0.83221E+00 -0.0798 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16883E-10 -10.7725 0.14051E-10 -10.8523 0.83221E+00 -0.0798 55 HFeO2- 0.33470E-07 -7.4753 0.27797E-07 -7.5560 0.83051E+00 -0.0807 56 FeO+ 0.11833E-16 -16.9269 0.98478E-17 -17.0067 0.83221E+00 -0.0798 58 FeO2- 0.38422E-09 -9.4154 0.31910E-09 -9.4961 0.83051E+00 -0.0807 59 HFeO2,aq 0.32250E-11 -11.4915 0.32250E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11611E-04 -4.9351 0.11581E-04 -4.9362 0.99743E+00 -0.0011 61 KCl,aq 0.14800E-08 -8.8297 0.14800E-08 -8.8297 0.10000E+01 0.0000 63 KOH,aq 0.75348E-06 -6.1229 0.75348E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.58086E-13 -13.2359 0.48242E-13 -13.3166 0.83051E+00 -0.0807 65 MgCO3,aq 0.32550E-11 -11.4874 0.32550E-11 -11.4874 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.29530E-13 -13.5297 0.24575E-13 -13.6095 0.83221E+00 -0.0798 67 MgCl+ 0.12760E-13 -13.8942 0.10619E-13 -13.9739 0.83221E+00 -0.0798 68 MgF+ 0.72384E-15 -15.1404 0.60239E-15 -15.2201 0.83221E+00 -0.0798 69 MgOH+ 0.74128E-10 -10.1300 0.61690E-10 -10.2098 0.83221E+00 -0.0798 71 MnF+ 0.20042E-15 -15.6981 0.16679E-15 -15.7778 0.83221E+00 -0.0798 72 MnO,aq 0.18124E-08 -8.7417 0.18124E-08 -8.7417 0.10000E+01 0.0000 73 MnOH+ 0.50532E-09 -9.2964 0.42053E-09 -9.3762 0.83221E+00 -0.0798 74 MnO2-2 0.18786E-10 -10.7262 0.95253E-11 -11.0211 0.50703E+00 -0.2950 75 HMnO2- 0.19966E-09 -9.6997 0.16582E-09 -9.7804 0.83051E+00 -0.0807 78 MnCl+ 0.47626E-13 -13.3222 0.39635E-13 -13.4019 0.83221E+00 -0.0798 79 MnSO4,aq 0.70742E-19 -19.1503 0.70742E-19 -19.1503 0.10000E+01 0.0000 80 NaCl,aq 0.34275E-05 -5.4650 0.34275E-05 -5.4650 0.10000E+01 0.0000 81 NaF,aq 0.37252E-08 -8.4288 0.37252E-08 -8.4288 0.10000E+01 0.0000 82 NaOH,aq 0.96012E-04 -4.0177 0.96012E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.87710E-02 -2.0570 0.72704E-02 -2.1384 0.82892E+00 -0.0815 89 HPO3-2 0.14607E-14 -14.8354 0.74061E-15 -15.1304 0.50703E+00 -0.2950 91 H2PO3- 0.14210E-18 -18.8474 0.11801E-18 -18.9281 0.83051E+00 -0.0807 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36179E-10 -10.4415 0.30077E-10 -10.5218 0.83135E+00 -0.0802 94 PO4-3 0.90935E-09 -9.0413 0.21068E-09 -9.6764 0.23168E+00 -0.6351 98 HP2O7-3 0.80985E-18 -18.0916 0.17826E-18 -18.7489 0.22011E+00 -0.6574 99 P2O7-4 0.75745E-17 -17.1206 0.53592E-18 -18.2709 0.70754E-01 -1.1503 100 H2S,aq 0.37032E-06 -6.4314 0.36936E-06 -6.4325 0.99743E+00 -0.0011 101 S2-2 0.85355E-11 -11.0688 0.43278E-11 -11.3637 0.50703E+00 -0.2950 102 S3-2 0.36675E-18 -18.4356 0.18596E-18 -18.7306 0.50703E+00 -0.2950 107 SO3-2 0.64820E-16 -16.1883 0.33373E-16 -16.4766 0.51485E+00 -0.2883 108 HSO3- 0.19992E-18 -18.6991 0.16604E-18 -18.7798 0.83051E+00 -0.0807 109 HSO4- 0.20382E-17 -17.6908 0.16979E-17 -17.7701 0.83307E+00 -0.0793 111 S2O3-2 0.18975E-18 -18.7218 0.96212E-19 -19.0168 0.50703E+00 -0.2950 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9506496E-10 -.2125099E-01 -.2137929E+02 0.0000 2 H2O 0.1000000E+01 0.5550995E+02 0.9981406E+06 0.0000 3 Cl- 0.7012411E-03 0.7046703E-03 0.2493551E+02 6.8651 4 SO4-- 0.4363091E-10 -.5009331E-02 -.4802960E+03 9.5455 5 HCO3- 0.9111684E-04 0.5261954E-02 0.3204636E+03 5.9795 6 HS- 0.1810649E-02 0.6820350E-02 0.2251368E+03 7.2771 7 Al+++ 0.1251331E-28 0.4992024E-05 0.1344380E+00 0.7391 8 H4SiO4 0.6959091E-03 0.1289208E-01 0.1236789E+04 -3.1574 9 Ca++ 0.1583240E-06 0.3458816E-06 0.1383608E-01 13.1018 10 Mg++ 0.2477596E-10 0.1056664E-09 0.2564113E-05 9.2942 11 Fe++ 0.6828725E-13 0.3408510E-07 0.1899957E-02 6.7350 12 K+ 0.1685201E-03 0.1692750E-03 0.6606498E+01 6.2466 13 Na+ 0.2138703E-01 0.2383545E-01 0.5469379E+03 8.3493 14 Mn++ 0.2198157E-10 0.2558244E-08 0.1402795E-03 9.2431 15 F- 0.1081210E-05 0.1084937E-05 0.2057273E-01 4.0521 16 HPO4-- 0.4037018E-07 0.4131571E-07 0.3957955E-02 12.5118 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278867E+02 -.1056156E-01 -.8277811E+02 0.0000000E+00 2 H2O -.7139324E+01 0.2758798E+02 -.3472730E+02 0.0000000E+00 3 Cl- 0.3502152E-03 0.3502152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387644E+00 -.2489595E-02 0.1412540E+00 0.0000000E+00 5 HCO3- 0.2615147E-02 0.2615147E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1378643E+00 0.3389657E-02 -.1412540E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2480994E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6407257E-02 0.5205750E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1719003E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5251533E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1694001E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8412827E-04 0.1061487E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1184602E-01 0.6264531E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1271426E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1449600E-04 0.5392047E-06 0.1395680E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2053356E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.2776E-15 Mass of aqueous solution: 0.497932E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0359900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.256 0.796 1641. 3.215 30.03 629.8 andradite 0.5650 -0.248 287.1 2.458 5.257 74.60 grossular 0.1368 -0.864 61.63 1.790 1.128 17.15 apatite-OH 0.9849E-02 -2.007 4.947 0.694 0.9057E-01 1.572 apatite-F 0.1396E-04 -4.855 0.7039E-02 -2.153 0.1289E-03 0.2199E-02 clinochlore 0.7078 -0.150 393.4 2.595 7.202 149.6 daphnite 0.2049 -0.688 146.2 2.165 2.677 44.31 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1937 -0.713 41.94 1.623 0.7678 12.82 hedenbergite 0.5023E-01 -1.299 12.46 1.096 0.2281 3.413 microcline 0.9336 -0.030 259.9 2.415 4.757 101.5 stilbite 3.222 0.508 2271. 3.356 41.57 1059. stilpnomelane-Fe 0.2558 -0.592 275.7 2.440 5.048 95.25 tr.625ac.25prg.125 0.6499E-01 -1.187 55.55 1.745 1.017 17.88 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1864E-01 0.1864E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.348507 g Volume = 2210.877234 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0359900 moles log = -1.4438 Original solution: 1000.0103000 g Original solution / Rock added: 27785.78 (Water/Rock Ratio), log = 4.4438 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 8.4332 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1234E+00 0.9662 0.1006E+01 0.1041E+01 CO2,gas 0.1660E-06 0.9834 0.1377E-05 0.1400E-05 CH4,gas 0.8748E+00 0.9964 0.7350E+01 0.7377E+01 H2,gas 0.1795E-02 1.0045 0.1521E-01 0.1514E-01 H2S,gas 0.1244E-05 0.9679 0.1015E-04 0.1049E-04 S2,gas 0.1985E-26 1.0000 0.1674E-25 0.1674E-25 CO,gas 0.6617E-12 1.0000 0.5580E-11 0.5580E-11 SO3,gas 0.6278E-47 1.0000 0.5294E-46 0.5294E-46 SO2,gas 0.3714E-26 1.0000 0.3132E-25 0.3132E-25 HF,gas 0.1419E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1774E-17 1.0000 0.1496E-16 0.1496E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.48529E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.22 -7.56 -2.520 0.12909E+05 -5.861 3 CH4,gas 4.54 3.71 -0.83 -0.208 0.14218E+04 0.866 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -12.92 -6.69 -3.346 0.11427E+05 -4.993 6 S2,gas -7.34 -34.81 -27.48 -4.227 0.46913E+05 -25.776 7 CO,gas 3.21 -9.74 -12.95 -3.985 0.22116E+05 -11.253 8 SO3,gas 17.12 -30.85 -47.98 -11.994 0.81916E+05 -46.276 9 SO2,gas 0.83 -26.37 -27.20 -7.254 0.46449E+05 -25.504 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.33 -18.52 -9.262 0.31629E+05 -16.825 12 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80630E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93637E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -1.12 -2.08 -0.695 0.35599E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.12 -1.93 -0.643 0.32957E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68940E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65522E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.25 -2.15 -0.615 0.36747E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.25 -1.71 -0.488 0.29170E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.82 -1.204 0.82216E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.59 -2.35 -0.552 0.40058E+04 146 pyrrhotite -4.26 -6.19 -1.93 -0.642 0.32907E+04 147 pyrrhotiteFe0.875 -6.02 -7.59 -1.57 -0.577 0.26780E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22419E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28674E+03 154 rhodochrosite -0.98 -4.98 -4.00 -1.334 0.68312E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23221E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.49 -4.88 -1.626 0.83275E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27806E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47075E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90672E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77500E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.19 -1.78 -0.592 0.30336E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60604E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.68 -2.70 -0.901 0.46129E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0359900 MOLES New total amount of reactant added: 0.0369900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8668E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0369900 Water: Moles liquid = 0.2759E+02 kg liquid = 0.4970E+00 Moles total = -.7139E+01 kg total = -.1286E+00 Activity = 0.9999 Stoichiometric ionic strength = .8315981E-02 Osmotic coef. = 0.9268 True ionic strength = .2176555E-01 Chg. balance for total moles = -.8668E-10 Max. difference allowed = 0.3561E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95245E-10 -10.0212 0.79602E-10 -10.0991 0.83576E+00 -0.0779 2 H2O 0.99991E+00 0.0000 0.99991E+00 0.0000 3 Cl- 0.71302E-03 -3.1469 0.59209E-03 -3.2276 0.83039E+00 -0.0807 4 SO4-- 0.44747E-10 -10.3492 0.22727E-10 -10.6435 0.50790E+00 -0.2942 5 HCO3- 0.93495E-04 -4.0292 0.77759E-04 -4.1093 0.83169E+00 -0.0800 6 HS- 0.18595E-02 -2.7306 0.15443E-02 -2.8113 0.83052E+00 -0.0806 7 Al+++ 0.12596E-28 -28.8998 0.27659E-29 -29.5582 0.21959E+00 -0.6584 8 H4SiO4 0.69591E-03 -3.1574 0.69591E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15897E-06 -6.7987 0.80109E-07 -7.0963 0.50391E+00 -0.2976 10 Mg++ 0.24878E-10 -10.6042 0.12475E-10 -10.9040 0.50145E+00 -0.2998 11 Fe++ 0.68568E-13 -13.1639 0.34424E-13 -13.4631 0.50204E+00 -0.2993 12 K+ 0.16884E-03 -3.7725 0.14046E-03 -3.8525 0.83190E+00 -0.0799 13 Na+ 0.21428E-01 -1.6690 0.17790E-01 -1.7498 0.83023E+00 -0.0808 14 Mn++ 0.22074E-10 -10.6561 0.11092E-10 -10.9550 0.50248E+00 -0.2989 15 F- 0.10795E-05 -5.9668 0.89441E-06 -6.0485 0.82857E+00 -0.0817 16 HPO4-- 0.40251E-07 -7.3952 0.20446E-07 -7.6894 0.50798E+00 -0.2942 18 HSiO3- 0.98313E-02 -2.0074 0.81638E-02 -2.0881 0.83039E+00 -0.0807 19 Ca(HSiO3)+ 0.17899E-07 -7.7472 0.14894E-07 -7.8270 0.83209E+00 -0.0798 20 Mg(HSiO3)+ 0.34690E-11 -11.4598 0.28865E-11 -11.5396 0.83209E+00 -0.0798 21 NaHSiO3,aq 0.23490E-02 -2.6291 0.23490E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.71360E-16 -16.1465 0.59378E-16 -16.2264 0.83209E+00 -0.0798 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.49838E-05 -5.3024 0.41306E-05 -5.3840 0.82880E+00 -0.0816 26 CH4,aq 0.51453E-02 -2.2886 0.51322E-02 -2.2897 0.99745E+00 -0.0011 27 C2H6,aq 0.38979E-09 -9.4092 0.38879E-09 -9.4103 0.99745E+00 -0.0011 28 C3H8,aq 0.68174E-15 -15.1664 0.68001E-15 -15.1675 0.99745E+00 -0.0011 30 ethanol,aq 0.14307E-16 -16.8445 0.14270E-16 -16.8456 0.99745E+00 -0.0011 31 CO,aq 0.38486E-14 -14.4147 0.38486E-14 -14.4147 0.10000E+01 0.0000 32 CO2,aq 0.13261E-07 -7.8774 0.13227E-07 -7.8785 0.99745E+00 -0.0011 33 CO3-2 0.16837E-03 -3.7737 0.85323E-04 -4.0689 0.50675E+00 -0.2952 34 CaCO3,aq 0.85705E-07 -7.0670 0.85705E-07 -7.0670 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.19109E-09 -9.7188 0.15901E-09 -9.7986 0.83209E+00 -0.0798 36 CaCl+ 0.92249E-10 -10.0350 0.76759E-10 -10.1149 0.83209E+00 -0.0798 37 CaCl2,aq 0.10798E-13 -13.9667 0.10798E-13 -13.9667 0.10000E+01 0.0000 38 CaF+ 0.12572E-11 -11.9006 0.10461E-11 -11.9804 0.83209E+00 -0.0798 39 CaOH+ 0.86188E-07 -7.0646 0.71717E-07 -7.1444 0.83209E+00 -0.0798 40 CaSO4,aq 0.57813E-15 -15.2380 0.57813E-15 -15.2380 0.10000E+01 0.0000 41 HCl,aq 0.86367E-14 -14.0637 0.86367E-14 -14.0637 0.10000E+01 0.0000 45 HF,aq 0.48739E-12 -12.3121 0.48739E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17724E-18 -18.7514 0.14718E-18 -18.8321 0.83039E+00 -0.0807 48 FeCl+ 0.38771E-16 -16.4115 0.32261E-16 -16.4913 0.83209E+00 -0.0798 51 FeF+ 0.18909E-17 -17.7233 0.15734E-17 -17.8032 0.83209E+00 -0.0798 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16916E-10 -10.7717 0.14075E-10 -10.8515 0.83209E+00 -0.0798 55 HFeO2- 0.33415E-07 -7.4761 0.27748E-07 -7.5568 0.83039E+00 -0.0807 56 FeO+ 0.11856E-16 -16.9261 0.98651E-17 -17.0059 0.83209E+00 -0.0798 58 FeO2- 0.38360E-09 -9.4161 0.31854E-09 -9.4968 0.83039E+00 -0.0807 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11611E-04 -4.9351 0.11581E-04 -4.9362 0.99745E+00 -0.0011 61 KCl,aq 0.15073E-08 -8.8218 0.15073E-08 -8.8218 0.10000E+01 0.0000 63 KOH,aq 0.75347E-06 -6.1229 0.75347E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.59652E-13 -13.2244 0.49535E-13 -13.3051 0.83039E+00 -0.0807 65 MgCO3,aq 0.33454E-11 -11.4756 0.33454E-11 -11.4756 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.30407E-13 -13.5170 0.25302E-13 -13.5969 0.83209E+00 -0.0798 67 MgCl+ 0.13020E-13 -13.8854 0.10834E-13 -13.9652 0.83209E+00 -0.0798 68 MgF+ 0.72522E-15 -15.1395 0.60345E-15 -15.2194 0.83209E+00 -0.0798 69 MgOH+ 0.74269E-10 -10.1292 0.61799E-10 -10.2090 0.83209E+00 -0.0798 71 MnF+ 0.20082E-15 -15.6972 0.16710E-15 -15.7770 0.83209E+00 -0.0798 72 MnO,aq 0.18126E-08 -8.7417 0.18126E-08 -8.7417 0.10000E+01 0.0000 73 MnOH+ 0.50633E-09 -9.2956 0.42131E-09 -9.3754 0.83209E+00 -0.0798 74 MnO2-2 0.18733E-10 -10.7274 0.94927E-11 -11.0226 0.50675E+00 -0.2952 75 HMnO2- 0.19936E-09 -9.7004 0.16555E-09 -9.7811 0.83039E+00 -0.0807 78 MnCl+ 0.48602E-13 -13.3133 0.40441E-13 -13.3932 0.83209E+00 -0.0798 79 MnSO4,aq 0.72774E-19 -19.1380 0.72774E-19 -19.1380 0.10000E+01 0.0000 80 NaCl,aq 0.34907E-05 -5.4571 0.34907E-05 -5.4571 0.10000E+01 0.0000 81 NaF,aq 0.37252E-08 -8.4289 0.37252E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.96011E-04 -4.0177 0.96011E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.87568E-02 -2.0577 0.72576E-02 -2.1392 0.82880E+00 -0.0816 89 HPO3-2 0.14564E-14 -14.8367 0.73801E-15 -15.1319 0.50675E+00 -0.2952 91 H2PO3- 0.14187E-18 -18.8481 0.11781E-18 -18.9288 0.83039E+00 -0.0807 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36120E-10 -10.4423 0.30024E-10 -10.5225 0.83123E+00 -0.0803 94 PO4-3 0.90563E-09 -9.0430 0.20957E-09 -9.6787 0.23140E+00 -0.6356 98 HP2O7-3 0.80661E-18 -18.0933 0.17732E-18 -18.7512 0.21983E+00 -0.6579 99 P2O7-4 0.75380E-17 -17.1227 0.53216E-18 -18.2740 0.70597E-01 -1.1512 100 H2S,aq 0.38091E-06 -6.4192 0.37994E-06 -6.4203 0.99745E+00 -0.0011 101 S2-2 0.90045E-11 -11.0455 0.45630E-11 -11.3408 0.50675E+00 -0.2952 102 S3-2 0.39798E-18 -18.4001 0.20167E-18 -18.6954 0.50675E+00 -0.2952 107 SO3-2 0.66477E-16 -16.1773 0.34207E-16 -16.4659 0.51457E+00 -0.2886 108 HSO3- 0.20531E-18 -18.6876 0.17049E-18 -18.7683 0.83039E+00 -0.0807 109 HSO4- 0.20931E-17 -17.6792 0.17435E-17 -17.7586 0.83296E+00 -0.0794 111 S2O3-2 0.20018E-18 -18.6986 0.10144E-18 -18.9938 0.50675E+00 -0.2952 Charge balance for all species = -.1744E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9524547E-10 -.2122490E-01 -.2135296E+02 0.0000 2 H2O 0.1000000E+01 0.5551009E+02 0.9981390E+06 0.0000 3 Cl- 0.7130231E-03 0.7165154E-03 0.2535456E+02 6.8715 4 SO4-- 0.4474680E-10 -.5148165E-02 -.4936054E+03 9.5547 5 HCO3- 0.9349473E-04 0.5407231E-02 0.3293099E+03 5.9898 6 HS- 0.1859465E-02 0.7008011E-02 0.2313305E+03 7.2878 7 Al+++ 0.1259576E-28 0.4983976E-05 0.1342207E+00 0.7391 8 H4SiO4 0.6959072E-03 0.1287614E-01 0.1235254E+04 -3.1574 9 Ca++ 0.1589737E-06 0.3490516E-06 0.1396282E-01 13.1018 10 Mg++ 0.2487783E-10 0.1060066E-09 0.2572356E-05 9.2942 11 Fe++ 0.6856804E-13 0.3403032E-07 0.1896896E-02 6.7350 12 K+ 0.1688401E-03 0.1695950E-03 0.6618959E+01 6.2466 13 Na+ 0.2142771E-01 0.2387618E-01 0.5478701E+03 8.3492 14 Mn++ 0.2207407E-10 0.2559167E-08 0.1403295E-03 9.2432 15 F- 0.1079464E-05 0.1083191E-05 0.2053953E-01 4.0506 16 HPO4-- 0.4025058E-07 0.4119233E-07 0.3946119E-02 12.5088 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278856E+02 -.1054898E-01 -.8277802E+02 0.0000000E+00 2 H2O -.7138505E+01 0.2758906E+02 -.3472756E+02 0.0000000E+00 3 Cl- 0.3561152E-03 0.3561152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387691E+00 -.2558689E-02 0.1413278E+00 0.0000000E+00 5 HCO3- 0.2687447E-02 0.2687447E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1378448E+00 0.3483050E-02 -.1413278E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2477085E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6399570E-02 0.5205750E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1734821E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5268630E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1691340E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8429040E-04 0.1061487E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1186669E-01 0.6264510E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1271931E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1489600E-04 0.5383565E-06 0.1435764E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2047299E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.2130E-14 Mass of aqueous solution: 0.497952E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0369900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.256 0.796 1641. 3.215 30.03 629.8 andradite 0.5653 -0.248 287.3 2.458 5.259 74.64 grossular 0.1369 -0.864 61.67 1.790 1.129 17.16 apatite-OH 0.9848E-02 -2.007 4.947 0.694 0.9057E-01 1.572 apatite-F 0.1436E-04 -4.843 0.7241E-02 -2.140 0.1326E-03 0.2262E-02 clinochlore 0.7077 -0.150 393.4 2.595 7.202 149.6 daphnite 0.2049 -0.688 146.2 2.165 2.676 44.30 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1917 -0.717 41.52 1.618 0.7602 12.69 hedenbergite 0.4973E-01 -1.303 12.34 1.091 0.2259 3.379 microcline 0.9337 -0.030 259.9 2.415 4.758 101.5 stilbite 3.222 0.508 2271. 3.356 41.57 1059. stilpnomelane-Fe 0.2556 -0.592 275.6 2.440 5.045 95.19 tr.625ac.25prg.125 0.6562E-01 -1.183 56.09 1.749 1.027 18.05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1864E-01 0.1864E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.348778 g Volume = 2210.880000 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0369900 moles log = -1.4319 Original solution: 1000.0103000 g Original solution / Rock added: 27034.61 (Water/Rock Ratio), log = 4.4319 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 8.6395 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1205E+00 0.9660 0.1006E+01 0.1041E+01 CO2,gas 0.1666E-06 0.9831 0.1415E-05 0.1440E-05 CH4,gas 0.8777E+00 0.9962 0.7554E+01 0.7583E+01 H2,gas 0.1752E-02 1.0046 0.1521E-01 0.1514E-01 H2S,gas 0.1250E-05 0.9671 0.1044E-04 0.1080E-04 S2,gas 0.2050E-26 1.0000 0.1771E-25 0.1771E-25 CO,gas 0.6638E-12 1.0000 0.5735E-11 0.5735E-11 SO3,gas 0.6303E-47 1.0000 0.5446E-46 0.5446E-46 SO2,gas 0.3729E-26 1.0000 0.3222E-25 0.3222E-25 HF,gas 0.1385E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1764E-17 1.0000 0.1524E-16 0.1524E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.21 -7.55 -2.516 0.12888E+05 -5.849 3 CH4,gas 4.54 3.72 -0.82 -0.205 0.14015E+04 0.878 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.91 -6.68 -3.340 0.11406E+05 -4.981 6 S2,gas -7.34 -34.79 -27.45 -4.223 0.46871E+05 -25.752 7 CO,gas 3.21 -9.73 -12.94 -3.982 0.22095E+05 -11.241 8 SO3,gas 17.12 -30.84 -47.96 -11.991 0.81895E+05 -46.264 9 SO2,gas 0.83 -26.36 -27.19 -7.251 0.46428E+05 -25.492 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.33 -18.52 -9.258 0.31616E+05 -16.817 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80628E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93638E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -1.11 -2.07 -0.691 0.35396E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.11 -1.92 -0.639 0.32754E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39694E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68941E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65522E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.24 -2.14 -0.612 0.36544E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.24 -1.70 -0.485 0.28967E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82215E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.57 -2.32 -0.546 0.39639E+04 146 pyrrhotite -4.26 -6.18 -1.92 -0.638 0.32698E+04 147 pyrrhotiteFe0.875 -6.02 -7.57 -1.56 -0.572 0.26570E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22418E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28674E+03 154 rhodochrosite -0.98 -4.97 -3.99 -1.330 0.68109E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23220E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.47 -4.87 -1.622 0.83071E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27807E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47074E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90672E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77500E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.18 -1.76 -0.588 0.30126E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60604E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73676E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60364E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.67 -2.69 -0.896 0.45919E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0369900 MOLES New total amount of reactant added: 0.0379900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8669E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0379900 Water: Moles liquid = 0.2759E+02 kg liquid = 0.4970E+00 Moles total = -.7138E+01 kg total = -.1286E+00 Activity = 0.9999 Stoichiometric ionic strength = .8231150E-02 Osmotic coef. = 0.9272 True ionic strength = .2181062E-01 Chg. balance for total moles = -.8669E-10 Max. difference allowed = 0.3620E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95426E-10 -10.0203 0.79742E-10 -10.0983 0.83565E+00 -0.0780 2 H2O 0.99990E+00 0.0000 0.99990E+00 0.0000 3 Cl- 0.72480E-03 -3.1398 0.60179E-03 -3.2206 0.83027E+00 -0.0808 4 SO4-- 0.45860E-10 -10.3386 0.23279E-10 -10.6330 0.50762E+00 -0.2945 5 HCO3- 0.95865E-04 -4.0183 0.79719E-04 -4.0984 0.83157E+00 -0.0801 6 HS- 0.19083E-02 -2.7194 0.15846E-02 -2.8001 0.83040E+00 -0.0807 7 Al+++ 0.12679E-28 -28.8969 0.27806E-29 -29.5559 0.21931E+00 -0.6589 8 H4SiO4 0.69591E-03 -3.1574 0.69591E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.15963E-06 -6.7969 0.80392E-07 -7.0948 0.50363E+00 -0.2979 10 Mg++ 0.24980E-10 -10.6024 0.12519E-10 -10.9024 0.50116E+00 -0.3000 11 Fe++ 0.68850E-13 -13.1621 0.34545E-13 -13.4616 0.50175E+00 -0.2995 12 K+ 0.16916E-03 -3.7717 0.14070E-03 -3.8517 0.83178E+00 -0.0800 13 Na+ 0.21468E-01 -1.6682 0.17821E-01 -1.7491 0.83011E+00 -0.0809 14 Mn++ 0.22167E-10 -10.6543 0.11132E-10 -10.9534 0.50219E+00 -0.2991 15 F- 0.10777E-05 -5.9675 0.89284E-06 -6.0492 0.82845E+00 -0.0817 16 HPO4-- 0.40131E-07 -7.3965 0.20374E-07 -7.6909 0.50769E+00 -0.2944 18 HSiO3- 0.98154E-02 -2.0081 0.81495E-02 -2.0889 0.83027E+00 -0.0808 19 Ca(HSiO3)+ 0.17933E-07 -7.7463 0.14920E-07 -7.8262 0.83197E+00 -0.0799 20 Mg(HSiO3)+ 0.34756E-11 -11.4590 0.28916E-11 -11.5389 0.83197E+00 -0.0799 21 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.71496E-16 -16.1457 0.59483E-16 -16.2256 0.83197E+00 -0.0799 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.49758E-05 -5.3031 0.41233E-05 -5.3848 0.82867E+00 -0.0816 26 CH4,aq 0.52841E-02 -2.2770 0.52708E-02 -2.2781 0.99748E+00 -0.0011 27 C2H6,aq 0.41112E-09 -9.3860 0.41008E-09 -9.3871 0.99748E+00 -0.0011 28 C3H8,aq 0.73848E-15 -15.1317 0.73662E-15 -15.1328 0.99748E+00 -0.0011 30 ethanol,aq 0.15090E-16 -16.8213 0.15052E-16 -16.8224 0.99748E+00 -0.0011 31 CO,aq 0.39526E-14 -14.4031 0.39526E-14 -14.4031 0.10000E+01 0.0000 32 CO2,aq 0.13619E-07 -7.8659 0.13585E-07 -7.8670 0.99748E+00 -0.0011 33 CO3-2 0.17241E-03 -3.7634 0.87321E-04 -4.0589 0.50646E+00 -0.2955 34 CaCO3,aq 0.88021E-07 -7.0554 0.88021E-07 -7.0554 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.19663E-09 -9.7064 0.16359E-09 -9.7862 0.83197E+00 -0.0799 36 CaCl+ 0.94103E-10 -10.0264 0.78292E-10 -10.1063 0.83197E+00 -0.0799 37 CaCl2,aq 0.11193E-13 -13.9510 0.11193E-13 -13.9510 0.10000E+01 0.0000 38 CaF+ 0.12596E-11 -11.8998 0.10479E-11 -11.9797 0.83197E+00 -0.0799 39 CaOH+ 0.86352E-07 -7.0637 0.71843E-07 -7.1436 0.83197E+00 -0.0799 40 CaSO4,aq 0.59427E-15 -15.2260 0.59427E-15 -15.2260 0.10000E+01 0.0000 41 HCl,aq 0.87936E-14 -14.0558 0.87936E-14 -14.0558 0.10000E+01 0.0000 45 HF,aq 0.48739E-12 -12.3121 0.48739E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17696E-18 -18.7521 0.14692E-18 -18.8329 0.83027E+00 -0.0808 48 FeCl+ 0.39551E-16 -16.4028 0.32905E-16 -16.4827 0.83197E+00 -0.0799 51 FeF+ 0.18945E-17 -17.7225 0.15761E-17 -17.8024 0.83197E+00 -0.0799 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16948E-10 -10.7709 0.14100E-10 -10.8508 0.83197E+00 -0.0799 55 HFeO2- 0.33361E-07 -7.4768 0.27699E-07 -7.5575 0.83027E+00 -0.0808 56 FeO+ 0.11878E-16 -16.9252 0.98825E-17 -17.0051 0.83197E+00 -0.0799 58 FeO2- 0.38298E-09 -9.4168 0.31798E-09 -9.4976 0.83027E+00 -0.0808 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11611E-04 -4.9351 0.11581E-04 -4.9362 0.99748E+00 -0.0011 61 KCl,aq 0.15346E-08 -8.8140 0.15346E-08 -8.8140 0.10000E+01 0.0000 63 KOH,aq 0.75346E-06 -6.1229 0.75346E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.61217E-13 -13.2131 0.50827E-13 -13.2939 0.83027E+00 -0.0808 65 MgCO3,aq 0.34358E-11 -11.4640 0.34358E-11 -11.4640 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.31288E-13 -13.5046 0.26031E-13 -13.5845 0.83197E+00 -0.0799 67 MgCl+ 0.13282E-13 -13.8767 0.11050E-13 -13.9566 0.83197E+00 -0.0799 68 MgF+ 0.72660E-15 -15.1387 0.60451E-15 -15.2186 0.83197E+00 -0.0799 69 MgOH+ 0.74411E-10 -10.1284 0.61908E-10 -10.2083 0.83197E+00 -0.0799 71 MnF+ 0.20122E-15 -15.6963 0.16741E-15 -15.7762 0.83197E+00 -0.0799 72 MnO,aq 0.18128E-08 -8.7417 0.18128E-08 -8.7417 0.10000E+01 0.0000 73 MnOH+ 0.50734E-09 -9.2947 0.42210E-09 -9.3746 0.83197E+00 -0.0799 74 MnO2-2 0.18679E-10 -10.7286 0.94602E-11 -11.0241 0.50646E+00 -0.2955 75 HMnO2- 0.19906E-09 -9.7010 0.16527E-09 -9.7818 0.83027E+00 -0.0808 78 MnCl+ 0.49584E-13 -13.3047 0.41253E-13 -13.3845 0.83197E+00 -0.0799 79 MnSO4,aq 0.74813E-19 -19.1260 0.74813E-19 -19.1260 0.10000E+01 0.0000 80 NaCl,aq 0.35541E-05 -5.4493 0.35541E-05 -5.4493 0.10000E+01 0.0000 81 NaF,aq 0.37251E-08 -8.4289 0.37251E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.96010E-04 -4.0177 0.96010E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.87427E-02 -2.0584 0.72448E-02 -2.1400 0.82867E+00 -0.0816 89 HPO3-2 0.14521E-14 -14.8380 0.73542E-15 -15.1335 0.50646E+00 -0.2955 91 H2PO3- 0.14164E-18 -18.8488 0.11760E-18 -18.9296 0.83027E+00 -0.0808 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36062E-10 -10.4430 0.29971E-10 -10.5233 0.83112E+00 -0.0803 94 PO4-3 0.90194E-09 -9.0448 0.20846E-09 -9.6810 0.23113E+00 -0.6361 98 HP2O7-3 0.80339E-18 -18.0951 0.17639E-18 -18.7535 0.21955E+00 -0.6585 99 P2O7-4 0.75017E-17 -17.1248 0.52843E-18 -18.2770 0.70441E-01 -1.1522 100 H2S,aq 0.39153E-06 -6.4072 0.39054E-06 -6.4083 0.99748E+00 -0.0011 101 S2-2 0.94860E-11 -11.0229 0.48043E-11 -11.3184 0.50646E+00 -0.2955 102 S3-2 0.43096E-18 -18.3656 0.21827E-18 -18.6610 0.50646E+00 -0.2955 107 SO3-2 0.68128E-16 -16.1667 0.35038E-16 -16.4555 0.51430E+00 -0.2888 108 HSO3- 0.21070E-18 -18.6763 0.17494E-18 -18.7571 0.83027E+00 -0.0808 109 HSO4- 0.21480E-17 -17.6680 0.17890E-17 -17.7474 0.83284E+00 -0.0794 111 S2O3-2 0.21088E-18 -18.6760 0.10681E-18 -18.9714 0.50646E+00 -0.2955 Charge balance for all species = -.1745E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9542610E-10 -.2119888E-01 -.2132669E+02 0.0000 2 H2O 0.1000000E+01 0.5551023E+02 0.9981375E+06 0.0000 3 Cl- 0.7248039E-03 0.7283597E-03 0.2577358E+02 6.8778 4 SO4-- 0.4585959E-10 -.5287021E-02 -.5069167E+03 9.5636 5 HCO3- 0.9586540E-04 0.5552498E-02 0.3381555E+03 5.9999 6 HS- 0.1908276E-02 0.7195688E-02 0.2375246E+03 7.2982 7 Al+++ 0.1267866E-28 0.4975951E-05 0.1340041E+00 0.7391 8 H4SiO4 0.6959052E-03 0.1286025E-01 0.1233725E+04 -3.1574 9 Ca++ 0.1596253E-06 0.3522240E-06 0.1408967E-01 13.1018 10 Mg++ 0.2497999E-10 0.1063476E-09 0.2580620E-05 9.2942 11 Fe++ 0.6884962E-13 0.3397570E-07 0.1893844E-02 6.7350 12 K+ 0.1691602E-03 0.1699152E-03 0.6631428E+01 6.2466 13 Na+ 0.2146842E-01 0.2391692E-01 0.5488028E+03 8.3492 14 Mn++ 0.2216684E-10 0.2560092E-08 0.1403797E-03 9.2432 15 F- 0.1077723E-05 0.1081449E-05 0.2050642E-01 4.0491 16 HPO4-- 0.4013147E-07 0.4106947E-07 0.3934333E-02 12.5057 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278846E+02 -.1053644E-01 -.8277792E+02 0.0000000E+00 2 H2O -.7137686E+01 0.2759014E+02 -.3472783E+02 0.0000000E+00 3 Cl- 0.3620152E-03 0.3620152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387739E+00 -.2627797E-02 0.1414017E+00 0.0000000E+00 5 HCO3- 0.2759747E-02 0.2759747E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1378253E+00 0.3576459E-02 -.1414017E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2473187E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6391906E-02 0.5205751E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1750652E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5285772E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1688688E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8445263E-04 0.1061486E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1188738E-01 0.6264490E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1272438E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1529600E-04 0.5375107E-06 0.1475849E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2041268E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1313E-13 Mass of aqueous solution: 0.497972E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0379900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.256 0.796 1641. 3.215 30.03 629.8 andradite 0.5656 -0.247 287.4 2.459 5.262 74.68 grossular 0.1370 -0.863 61.70 1.790 1.130 17.17 apatite-OH 0.9848E-02 -2.007 4.947 0.694 0.9056E-01 1.572 apatite-F 0.1476E-04 -4.831 0.7443E-02 -2.128 0.1363E-03 0.2325E-02 clinochlore 0.7077 -0.150 393.3 2.595 7.201 149.6 daphnite 0.2049 -0.689 146.2 2.165 2.676 44.30 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1898 -0.722 41.11 1.614 0.7526 12.56 hedenbergite 0.4923E-01 -1.308 12.21 1.087 0.2236 3.345 microcline 0.9337 -0.030 259.9 2.415 4.758 101.5 stilbite 3.222 0.508 2271. 3.356 41.57 1059. stilpnomelane-Fe 0.2555 -0.593 275.4 2.440 5.042 95.13 tr.625ac.25prg.125 0.6625E-01 -1.179 56.63 1.753 1.037 18.23 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1865E-01 0.1865E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.349048 g Volume = 2210.882766 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0379900 moles log = -1.4203 Original solution: 1000.0103000 g Original solution / Rock added: 26322.99 (Water/Rock Ratio), log = 4.4203 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 8.8459 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1177E+00 0.9657 0.1006E+01 0.1042E+01 CO2,gas 0.1672E-06 0.9827 0.1453E-05 0.1479E-05 CH4,gas 0.8805E+00 0.9960 0.7758E+01 0.7789E+01 H2,gas 0.1711E-02 1.0047 0.1521E-01 0.1513E-01 H2S,gas 0.1256E-05 0.9664 0.1074E-04 0.1111E-04 S2,gas 0.2115E-26 1.0000 0.1871E-25 0.1871E-25 CO,gas 0.6659E-12 1.0000 0.5890E-11 0.5890E-11 SO3,gas 0.6328E-47 1.0000 0.5598E-46 0.5598E-46 SO2,gas 0.3744E-26 1.0000 0.3312E-25 0.3312E-25 HF,gas 0.1353E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1754E-17 1.0000 0.1552E-16 0.1552E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.20 -7.54 -2.512 0.12869E+05 -5.838 3 CH4,gas 4.54 3.73 -0.81 -0.202 0.13817E+04 0.890 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.90 -6.67 -3.334 0.11386E+05 -4.969 6 S2,gas -7.34 -34.76 -27.43 -4.220 0.46831E+05 -25.728 7 CO,gas 3.21 -9.71 -12.93 -3.978 0.22076E+05 -11.230 8 SO3,gas 17.12 -30.83 -47.95 -11.988 0.81875E+05 -46.252 9 SO2,gas 0.83 -26.35 -27.18 -7.248 0.46407E+05 -25.480 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.32 -18.51 -9.254 0.31602E+05 -16.809 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80626E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93638E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -1.09 -2.06 -0.687 0.35198E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.09 -1.91 -0.636 0.32556E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68941E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65521E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.23 -2.13 -0.608 0.36347E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.23 -1.68 -0.481 0.28769E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82214E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.54 -2.30 -0.541 0.39231E+04 146 pyrrhotite -4.26 -6.16 -1.90 -0.634 0.32494E+04 147 pyrrhotiteFe0.875 -6.02 -7.56 -1.54 -0.568 0.26366E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22417E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28674E+03 154 rhodochrosite -0.98 -4.95 -3.98 -1.326 0.67910E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23220E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.46 -4.85 -1.618 0.82874E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27807E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47072E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90672E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77501E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.16 -1.75 -0.584 0.29922E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60604E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.66 -2.68 -0.892 0.45714E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0379900 MOLES New total amount of reactant added: 0.0389900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8668E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0389900 Water: Moles liquid = 0.2759E+02 kg liquid = 0.4970E+00 Moles total = -.7137E+01 kg total = -.1286E+00 Activity = 0.9999 Stoichiometric ionic strength = .8146295E-02 Osmotic coef. = 0.9275 True ionic strength = .2185568E-01 Chg. balance for total moles = -.8668E-10 Max. difference allowed = 0.3679E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95607E-10 -10.0195 0.79883E-10 -10.0975 0.83553E+00 -0.0780 2 H2O 0.99990E+00 0.0000 0.99990E+00 0.0000 3 Cl- 0.73658E-03 -3.1328 0.61148E-03 -3.2136 0.83015E+00 -0.0808 4 SO4-- 0.46969E-10 -10.3282 0.23829E-10 -10.6229 0.50733E+00 -0.2947 5 HCO3- 0.98229E-04 -4.0078 0.81673E-04 -4.0879 0.83145E+00 -0.0802 6 HS- 0.19571E-02 -2.7084 0.16249E-02 -2.7892 0.83028E+00 -0.0808 7 Al+++ 0.12762E-28 -28.8941 0.27953E-29 -29.5536 0.21903E+00 -0.6595 8 H4SiO4 0.69590E-03 -3.1575 0.69590E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.16028E-06 -6.7951 0.80675E-07 -7.0933 0.50334E+00 -0.2981 10 Mg++ 0.25082E-10 -10.6006 0.12563E-10 -10.9009 0.50087E+00 -0.3003 11 Fe++ 0.69132E-13 -13.1603 0.34667E-13 -13.4601 0.50146E+00 -0.2998 12 K+ 0.16948E-03 -3.7709 0.14095E-03 -3.8509 0.83166E+00 -0.0801 13 Na+ 0.21509E-01 -1.6674 0.17852E-01 -1.7483 0.82999E+00 -0.0809 14 Mn++ 0.22260E-10 -10.6525 0.11172E-10 -10.9519 0.50191E+00 -0.2994 15 F- 0.10760E-05 -5.9682 0.89127E-06 -6.0500 0.82832E+00 -0.0818 16 HPO4-- 0.40013E-07 -7.3978 0.20303E-07 -7.6924 0.50741E+00 -0.2946 18 HSiO3- 0.97996E-02 -2.0088 0.81351E-02 -2.0896 0.83015E+00 -0.0808 19 Ca(HSiO3)+ 0.17968E-07 -7.7455 0.14946E-07 -7.8255 0.83186E+00 -0.0800 20 Mg(HSiO3)+ 0.34822E-11 -11.4581 0.28967E-11 -11.5381 0.83186E+00 -0.0800 21 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.71633E-16 -16.1449 0.59588E-16 -16.2248 0.83186E+00 -0.0800 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.49678E-05 -5.3038 0.41161E-05 -5.3855 0.82855E+00 -0.0817 26 CH4,aq 0.54230E-02 -2.2658 0.54095E-02 -2.2668 0.99750E+00 -0.0011 27 C2H6,aq 0.43303E-09 -9.3635 0.43195E-09 -9.3646 0.99750E+00 -0.0011 28 C3H8,aq 0.79830E-15 -15.0978 0.79630E-15 -15.0989 0.99750E+00 -0.0011 30 ethanol,aq 0.15894E-16 -16.7988 0.15854E-16 -16.7999 0.99750E+00 -0.0011 31 CO,aq 0.40566E-14 -14.3918 0.40566E-14 -14.3918 0.10000E+01 0.0000 32 CO2,aq 0.13977E-07 -7.8546 0.13942E-07 -7.8557 0.99750E+00 -0.0011 33 CO3-2 0.17643E-03 -3.7534 0.89304E-04 -4.0491 0.50618E+00 -0.2957 34 CaCO3,aq 0.90337E-07 -7.0441 0.90337E-07 -7.0441 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.20219E-09 -9.6942 0.16819E-09 -9.7742 0.83186E+00 -0.0800 36 CaCl+ 0.95969E-10 -10.0179 0.79833E-10 -10.0978 0.83186E+00 -0.0800 37 CaCl2,aq 0.11598E-13 -13.9356 0.11598E-13 -13.9356 0.10000E+01 0.0000 38 CaF+ 0.12620E-11 -11.8989 0.10498E-11 -11.9789 0.83186E+00 -0.0800 39 CaOH+ 0.86516E-07 -7.0629 0.71969E-07 -7.1429 0.83186E+00 -0.0800 40 CaSO4,aq 0.61045E-15 -15.2143 0.61045E-15 -15.2143 0.10000E+01 0.0000 41 HCl,aq 0.89509E-14 -14.0481 0.89509E-14 -14.0481 0.10000E+01 0.0000 45 HF,aq 0.48739E-12 -12.3121 0.48739E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17667E-18 -18.7528 0.14666E-18 -18.8337 0.83015E+00 -0.0808 48 FeCl+ 0.40335E-16 -16.3943 0.33553E-16 -16.4743 0.83186E+00 -0.0800 51 FeF+ 0.18981E-17 -17.7217 0.15789E-17 -17.8016 0.83186E+00 -0.0800 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.16980E-10 -10.7701 0.14125E-10 -10.8500 0.83186E+00 -0.0800 55 HFeO2- 0.33307E-07 -7.4775 0.27650E-07 -7.5583 0.83015E+00 -0.0808 56 FeO+ 0.11901E-16 -16.9244 0.98999E-17 -17.0044 0.83186E+00 -0.0800 58 FeO2- 0.38236E-09 -9.4175 0.31742E-09 -9.4984 0.83015E+00 -0.0808 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11610E-04 -4.9352 0.11581E-04 -4.9362 0.99750E+00 -0.0011 61 KCl,aq 0.15621E-08 -8.8063 0.15621E-08 -8.8063 0.10000E+01 0.0000 63 KOH,aq 0.75346E-06 -6.1229 0.75346E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.62783E-13 -13.2022 0.52119E-13 -13.2830 0.83015E+00 -0.0808 65 MgCO3,aq 0.35262E-11 -11.4527 0.35262E-11 -11.4527 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.32172E-13 -13.4925 0.26763E-13 -13.5725 0.83186E+00 -0.0800 67 MgCl+ 0.13545E-13 -13.8682 0.11268E-13 -13.9482 0.83186E+00 -0.0800 68 MgF+ 0.72798E-15 -15.1379 0.60558E-15 -15.2178 0.83186E+00 -0.0800 69 MgOH+ 0.74552E-10 -10.1275 0.62016E-10 -10.2075 0.83186E+00 -0.0800 71 MnF+ 0.20162E-15 -15.6955 0.16772E-15 -15.7754 0.83186E+00 -0.0800 72 MnO,aq 0.18130E-08 -8.7416 0.18130E-08 -8.7416 0.10000E+01 0.0000 73 MnOH+ 0.50836E-09 -9.2938 0.42288E-09 -9.3738 0.83186E+00 -0.0800 74 MnO2-2 0.18626E-10 -10.7299 0.94279E-11 -11.0256 0.50618E+00 -0.2957 75 HMnO2- 0.19876E-09 -9.7017 0.16500E-09 -9.7825 0.83015E+00 -0.0808 78 MnCl+ 0.50572E-13 -13.2961 0.42069E-13 -13.3760 0.83186E+00 -0.0800 79 MnSO4,aq 0.76858E-19 -19.1143 0.76858E-19 -19.1143 0.10000E+01 0.0000 80 NaCl,aq 0.36177E-05 -5.4416 0.36177E-05 -5.4416 0.10000E+01 0.0000 81 NaF,aq 0.37251E-08 -8.4289 0.37251E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.96009E-04 -4.0177 0.96009E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.87286E-02 -2.0591 0.72321E-02 -2.1407 0.82855E+00 -0.0817 89 HPO3-2 0.14478E-14 -14.8393 0.73283E-15 -15.1350 0.50618E+00 -0.2957 91 H2PO3- 0.14141E-18 -18.8495 0.11739E-18 -18.9304 0.83015E+00 -0.0808 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.36004E-10 -10.4437 0.29919E-10 -10.5241 0.83100E+00 -0.0804 94 PO4-3 0.89826E-09 -9.0466 0.20737E-09 -9.6833 0.23085E+00 -0.6367 98 HP2O7-3 0.80018E-18 -18.0968 0.17546E-18 -18.7558 0.21928E+00 -0.6590 99 P2O7-4 0.74656E-17 -17.1269 0.52473E-18 -18.2801 0.70286E-01 -1.1531 100 H2S,aq 0.40218E-06 -6.3956 0.40118E-06 -6.3967 0.99750E+00 -0.0011 101 S2-2 0.99802E-11 -11.0009 0.50518E-11 -11.2966 0.50618E+00 -0.2957 102 S3-2 0.46576E-18 -18.3318 0.23576E-18 -18.6275 0.50618E+00 -0.2957 107 SO3-2 0.69775E-16 -16.1563 0.35866E-16 -16.4453 0.51402E+00 -0.2890 108 HSO3- 0.21609E-18 -18.6654 0.17939E-18 -18.7462 0.83015E+00 -0.0808 109 HSO4- 0.22030E-17 -17.6570 0.18345E-17 -17.7365 0.83273E+00 -0.0795 111 S2O3-2 0.22187E-18 -18.6539 0.11231E-18 -18.9496 0.50618E+00 -0.2957 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9560683E-10 -.2117291E-01 -.2130048E+02 0.0000 2 H2O 0.1000000E+01 0.5551037E+02 0.9981359E+06 0.0000 3 Cl- 0.7365837E-03 0.7402031E-03 0.2619256E+02 6.8839 4 SO4-- 0.4696929E-10 -.5425896E-02 -.5202299E+03 9.5722 5 HCO3- 0.9822887E-04 0.5697753E-02 0.3470004E+03 6.0096 6 HS- 0.1957084E-02 0.7383383E-02 0.2437193E+03 7.3084 7 Al+++ 0.1276199E-28 0.4967949E-05 0.1337880E+00 0.7391 8 H4SiO4 0.6959033E-03 0.1284440E-01 0.1232199E+04 -3.1575 9 Ca++ 0.1602787E-06 0.3553988E-06 0.1421661E-01 13.1018 10 Mg++ 0.2508244E-10 0.1066885E-09 0.2588883E-05 9.2942 11 Fe++ 0.6913201E-13 0.3392123E-07 0.1890800E-02 6.7350 12 K+ 0.1694806E-03 0.1702356E-03 0.6643905E+01 6.2466 13 Na+ 0.2150915E-01 0.2395770E-01 0.5497362E+03 8.3492 14 Mn++ 0.2225989E-10 0.2561020E-08 0.1404300E-03 9.2432 15 F- 0.1075986E-05 0.1079713E-05 0.2047341E-01 4.0476 16 HPO4-- 0.4001287E-07 0.4094713E-07 0.3922597E-02 12.5027 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278835E+02 -.1052392E-01 -.8277783E+02 0.0000000E+00 2 H2O -.7136868E+01 0.2759122E+02 -.3472809E+02 0.0000000E+00 3 Cl- 0.3679152E-03 0.3679152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387787E+00 -.2696921E-02 0.1414756E+00 0.0000000E+00 5 HCO3- 0.2832047E-02 0.2832047E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1378057E+00 0.3669883E-02 -.1414756E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2469300E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6384263E-02 0.5205752E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1766497E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5302914E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1686042E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8461498E-04 0.1061486E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1190808E-01 0.6264469E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1272945E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1569600E-04 0.5366673E-06 0.1515933E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2035262E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1374E-14 Mass of aqueous solution: 0.497992E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0389900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.256 0.796 1640. 3.215 30.03 629.7 andradite 0.5659 -0.247 287.6 2.459 5.265 74.72 grossular 0.1370 -0.863 61.73 1.790 1.130 17.18 apatite-OH 0.9847E-02 -2.007 4.947 0.694 0.9056E-01 1.572 apatite-F 0.1516E-04 -4.819 0.7645E-02 -2.117 0.1400E-03 0.2388E-02 clinochlore 0.7076 -0.150 393.3 2.595 7.200 149.6 daphnite 0.2049 -0.689 146.2 2.165 2.676 44.29 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1879 -0.726 40.69 1.609 0.7449 12.44 hedenbergite 0.4873E-01 -1.312 12.09 1.082 0.2213 3.312 microcline 0.9338 -0.030 259.9 2.415 4.758 101.5 stilbite 3.222 0.508 2271. 3.356 41.57 1059. stilpnomelane-Fe 0.2553 -0.593 275.2 2.440 5.039 95.07 tr.625ac.25prg.125 0.6688E-01 -1.175 57.17 1.757 1.047 18.40 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1865E-01 0.1865E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.349318 g Volume = 2210.885533 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0389900 moles log = -1.4090 Original solution: 1000.0103000 g Original solution / Rock added: 25647.87 (Water/Rock Ratio), log = 4.4091 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 9.0524 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1151E+00 0.9654 0.1006E+01 0.1042E+01 CO2,gas 0.1677E-06 0.9823 0.1492E-05 0.1519E-05 CH4,gas 0.8832E+00 0.9959 0.7962E+01 0.7995E+01 H2,gas 0.1672E-02 1.0048 0.1520E-01 0.1513E-01 H2S,gas 0.1262E-05 0.9656 0.1103E-04 0.1142E-04 S2,gas 0.2181E-26 1.0000 0.1975E-25 0.1975E-25 CO,gas 0.6678E-12 1.0000 0.6045E-11 0.6045E-11 SO3,gas 0.6352E-47 1.0000 0.5750E-46 0.5750E-46 SO2,gas 0.3758E-26 1.0000 0.3402E-25 0.3402E-25 HF,gas 0.1322E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1745E-17 1.0000 0.1579E-16 0.1579E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.19 -7.53 -2.508 0.12849E+05 -5.826 3 CH4,gas 4.54 3.75 -0.80 -0.199 0.13624E+04 0.901 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.89 -6.66 -3.328 0.11366E+05 -4.958 6 S2,gas -7.34 -34.74 -27.40 -4.216 0.46791E+05 -25.705 7 CO,gas 3.21 -9.70 -12.92 -3.975 0.22056E+05 -11.219 8 SO3,gas 17.12 -30.82 -47.94 -11.985 0.81855E+05 -46.240 9 SO2,gas 0.83 -26.34 -27.17 -7.245 0.46387E+05 -25.468 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.31 -18.50 -9.250 0.31589E+05 -16.802 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80624E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93639E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -1.08 -2.05 -0.683 0.35006E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55910E+04 40 calcite 0.81 -1.08 -1.90 -0.632 0.32364E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68941E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65520E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.22 -2.12 -0.605 0.36154E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.22 -1.67 -0.478 0.28576E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82213E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.52 -2.27 -0.535 0.38832E+04 146 pyrrhotite -4.26 -6.15 -1.89 -0.630 0.32295E+04 147 pyrrhotiteFe0.875 -6.02 -7.55 -1.53 -0.564 0.26167E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22416E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84959E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28674E+03 154 rhodochrosite -0.98 -4.94 -3.97 -1.322 0.67717E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23219E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.45 -4.84 -1.614 0.82681E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27807E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47071E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90672E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77501E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.15 -1.74 -0.580 0.29723E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60604E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68815E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.64 -2.67 -0.889 0.45514E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0389900 MOLES New total amount of reactant added: 0.0399900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8669E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0399900 Water: Moles liquid = 0.2759E+02 kg liquid = 0.4971E+00 Moles total = -.7136E+01 kg total = -.1286E+00 Activity = 0.9999 Stoichiometric ionic strength = .8061415E-02 Osmotic coef. = 0.9279 True ionic strength = .2190075E-01 Chg. balance for total moles = -.8669E-10 Max. difference allowed = 0.3738E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95788E-10 -10.0187 0.80023E-10 -10.0968 0.83542E+00 -0.0781 2 H2O 0.99990E+00 0.0000 0.99990E+00 0.0000 3 Cl- 0.74836E-03 -3.1259 0.62117E-03 -3.2068 0.83003E+00 -0.0809 4 SO4-- 0.48076E-10 -10.3181 0.24377E-10 -10.6130 0.50705E+00 -0.2949 5 HCO3- 0.10059E-03 -3.9975 0.83620E-04 -4.0777 0.83134E+00 -0.0802 6 HS- 0.20059E-02 -2.6977 0.16652E-02 -2.7785 0.83016E+00 -0.0808 7 Al+++ 0.12846E-28 -28.8912 0.28101E-29 -29.5513 0.21876E+00 -0.6600 8 H4SiO4 0.69590E-03 -3.1575 0.69590E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.16093E-06 -6.7934 0.80958E-07 -7.0917 0.50305E+00 -0.2984 10 Mg++ 0.25185E-10 -10.5989 0.12607E-10 -10.8994 0.50059E+00 -0.3005 11 Fe++ 0.69415E-13 -13.1585 0.34789E-13 -13.4586 0.50117E+00 -0.3000 12 K+ 0.16980E-03 -3.7701 0.14120E-03 -3.8502 0.83155E+00 -0.0801 13 Na+ 0.21550E-01 -1.6666 0.17884E-01 -1.7475 0.82987E+00 -0.0810 14 Mn++ 0.22353E-10 -10.6507 0.11213E-10 -10.9503 0.50162E+00 -0.2996 15 F- 0.10743E-05 -5.9689 0.88970E-06 -6.0508 0.82820E+00 -0.0819 16 HPO4-- 0.39895E-07 -7.3991 0.20232E-07 -7.6940 0.50713E+00 -0.2949 18 HSiO3- 0.97838E-02 -2.0095 0.81209E-02 -2.0904 0.83003E+00 -0.0809 19 Ca(HSiO3)+ 0.18002E-07 -7.7447 0.14973E-07 -7.8247 0.83174E+00 -0.0800 20 Mg(HSiO3)+ 0.34888E-11 -11.4573 0.29018E-11 -11.5373 0.83174E+00 -0.0800 21 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.71769E-16 -16.1441 0.59693E-16 -16.2241 0.83174E+00 -0.0800 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.49598E-05 -5.3045 0.41089E-05 -5.3863 0.82843E+00 -0.0817 26 CH4,aq 0.55619E-02 -2.2548 0.55481E-02 -2.2559 0.99753E+00 -0.0011 27 C2H6,aq 0.45551E-09 -9.3415 0.45438E-09 -9.3426 0.99753E+00 -0.0011 28 C3H8,aq 0.86127E-15 -15.0649 0.85914E-15 -15.0659 0.99753E+00 -0.0011 30 ethanol,aq 0.16719E-16 -16.7768 0.16678E-16 -16.7779 0.99753E+00 -0.0011 31 CO,aq 0.41607E-14 -14.3808 0.41607E-14 -14.3808 0.10000E+01 0.0000 32 CO2,aq 0.14335E-07 -7.8436 0.14300E-07 -7.8447 0.99753E+00 -0.0011 33 CO3-2 0.18042E-03 -3.7437 0.91272E-04 -4.0397 0.50590E+00 -0.2959 34 CaCO3,aq 0.92653E-07 -7.0331 0.92653E-07 -7.0331 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.20776E-09 -9.6824 0.17281E-09 -9.7624 0.83174E+00 -0.0800 36 CaCl+ 0.97847E-10 -10.0095 0.81383E-10 -10.0895 0.83174E+00 -0.0800 37 CaCl2,aq 0.12010E-13 -13.9205 0.12010E-13 -13.9205 0.10000E+01 0.0000 38 CaF+ 0.12644E-11 -11.8981 0.10516E-11 -11.9781 0.83174E+00 -0.0800 39 CaOH+ 0.86680E-07 -7.0621 0.72095E-07 -7.1421 0.83174E+00 -0.0800 40 CaSO4,aq 0.62669E-15 -15.2030 0.62669E-15 -15.2030 0.10000E+01 0.0000 41 HCl,aq 0.91087E-14 -14.0405 0.91087E-14 -14.0405 0.10000E+01 0.0000 45 HF,aq 0.48739E-12 -12.3121 0.48739E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17638E-18 -18.7535 0.14640E-18 -18.8344 0.83003E+00 -0.0809 48 FeCl+ 0.41124E-16 -16.3859 0.34205E-16 -16.4659 0.83174E+00 -0.0800 51 FeF+ 0.19017E-17 -17.7209 0.15817E-17 -17.8009 0.83174E+00 -0.0800 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17012E-10 -10.7692 0.14150E-10 -10.8493 0.83174E+00 -0.0800 55 HFeO2- 0.33254E-07 -7.4782 0.27602E-07 -7.5591 0.83003E+00 -0.0809 56 FeO+ 0.11924E-16 -16.9236 0.99173E-17 -17.0036 0.83174E+00 -0.0800 58 FeO2- 0.38175E-09 -9.4182 0.31686E-09 -9.4991 0.83003E+00 -0.0809 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11610E-04 -4.9352 0.11581E-04 -4.9362 0.99753E+00 -0.0011 61 KCl,aq 0.15896E-08 -8.7987 0.15896E-08 -8.7987 0.10000E+01 0.0000 63 KOH,aq 0.75345E-06 -6.1229 0.75345E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.64348E-13 -13.1915 0.53411E-13 -13.2724 0.83003E+00 -0.0809 65 MgCO3,aq 0.36166E-11 -11.4417 0.36166E-11 -11.4417 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.33060E-13 -13.4807 0.27497E-13 -13.5607 0.83174E+00 -0.0800 67 MgCl+ 0.13810E-13 -13.8598 0.11486E-13 -13.9398 0.83174E+00 -0.0800 68 MgF+ 0.72936E-15 -15.1371 0.60664E-15 -15.2171 0.83174E+00 -0.0800 69 MgOH+ 0.74693E-10 -10.1267 0.62125E-10 -10.2067 0.83174E+00 -0.0800 71 MnF+ 0.20203E-15 -15.6946 0.16803E-15 -15.7746 0.83174E+00 -0.0800 72 MnO,aq 0.18131E-08 -8.7416 0.18131E-08 -8.7416 0.10000E+01 0.0000 73 MnOH+ 0.50937E-09 -9.2930 0.42366E-09 -9.3730 0.83174E+00 -0.0800 74 MnO2-2 0.18572E-10 -10.7311 0.93957E-11 -11.0271 0.50590E+00 -0.2959 75 HMnO2- 0.19845E-09 -9.7023 0.16472E-09 -9.7832 0.83003E+00 -0.0809 78 MnCl+ 0.51567E-13 -13.2876 0.42890E-13 -13.3676 0.83174E+00 -0.0800 79 MnSO4,aq 0.78909E-19 -19.1029 0.78909E-19 -19.1029 0.10000E+01 0.0000 80 NaCl,aq 0.36814E-05 -5.4340 0.36814E-05 -5.4340 0.10000E+01 0.0000 81 NaF,aq 0.37251E-08 -8.4289 0.37251E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.96008E-04 -4.0177 0.96008E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.87145E-02 -2.0598 0.72194E-02 -2.1415 0.82843E+00 -0.0817 89 HPO3-2 0.14435E-14 -14.8406 0.73027E-15 -15.1365 0.50590E+00 -0.2959 91 H2PO3- 0.14118E-18 -18.8502 0.11719E-18 -18.9311 0.83003E+00 -0.0809 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.35946E-10 -10.4444 0.29866E-10 -10.5248 0.83088E+00 -0.0805 94 PO4-3 0.89460E-09 -9.0484 0.20628E-09 -9.6855 0.23058E+00 -0.6372 98 HP2O7-3 0.79699E-18 -18.0985 0.17454E-18 -18.7581 0.21900E+00 -0.6596 99 P2O7-4 0.74297E-17 -17.1290 0.52106E-18 -18.2831 0.70131E-01 -1.1541 100 H2S,aq 0.41286E-06 -6.3842 0.41184E-06 -6.3853 0.99753E+00 -0.0011 101 S2-2 0.10487E-10 -10.9793 0.53054E-11 -11.2753 0.50590E+00 -0.2959 102 S3-2 0.50243E-18 -18.2989 0.25418E-18 -18.5949 0.50590E+00 -0.2959 107 SO3-2 0.71418E-16 -16.1462 0.36691E-16 -16.4354 0.51375E+00 -0.2893 108 HSO3- 0.22148E-18 -18.6547 0.18384E-18 -18.7356 0.83003E+00 -0.0809 109 HSO4- 0.22579E-17 -17.6463 0.18799E-17 -17.7259 0.83261E+00 -0.0796 111 S2O3-2 0.23314E-18 -18.6324 0.11794E-18 -18.9283 0.50590E+00 -0.2959 Charge balance for all species = -.1743E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9578769E-10 -.2114701E-01 -.2127433E+02 0.0000 2 H2O 0.1000000E+01 0.5551051E+02 0.9981343E+06 0.0000 3 Cl- 0.7483625E-03 0.7520456E-03 0.2661150E+02 6.8900 4 SO4-- 0.4807592E-10 -.5564791E-02 -.5335449E+03 9.5805 5 HCO3- 0.1005852E-03 0.5842998E-02 0.3558445E+03 6.0191 6 HS- 0.2005889E-02 0.7571093E-02 0.2499144E+03 7.3183 7 Al+++ 0.1284576E-28 0.4959970E-05 0.1335726E+00 0.7391 8 H4SiO4 0.6959013E-03 0.1282860E-01 0.1230678E+04 -3.1575 9 Ca++ 0.1609340E-06 0.3585762E-06 0.1434365E-01 13.1018 10 Mg++ 0.2518518E-10 0.1070304E-09 0.2597167E-05 9.2942 11 Fe++ 0.6941520E-13 0.3386692E-07 0.1887765E-02 6.7350 12 K+ 0.1698012E-03 0.1705562E-03 0.6656390E+01 6.2466 13 Na+ 0.2154990E-01 0.2399850E-01 0.5506701E+03 8.3492 14 Mn++ 0.2235321E-10 0.2561950E-08 0.1404804E-03 9.2433 15 F- 0.1074254E-05 0.1077981E-05 0.2044049E-01 4.0460 16 HPO4-- 0.3989476E-07 0.4082530E-07 0.3910910E-02 12.4996 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278824E+02 -.1051143E-01 -.8277773E+02 0.0000000E+00 2 H2O -.7136049E+01 0.2759231E+02 -.3472835E+02 0.0000000E+00 3 Cl- 0.3738152E-03 0.3738152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387835E+00 -.2766060E-02 0.1415495E+00 0.0000000E+00 5 HCO3- 0.2904347E-02 0.2904347E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1377862E+00 0.3763322E-02 -.1415495E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2465425E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6376642E-02 0.5205753E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1782355E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5320100E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1683405E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8477744E-04 0.1061486E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1192880E-01 0.6264448E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1273454E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1609600E-04 0.5358262E-06 0.1556017E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2029281E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.6418E-14 Mass of aqueous solution: 0.498013E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0399900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.256 0.796 1640. 3.215 30.03 629.7 andradite 0.5662 -0.247 287.7 2.459 5.268 74.75 grossular 0.1371 -0.863 61.76 1.791 1.131 17.18 apatite-OH 0.9847E-02 -2.007 4.946 0.694 0.9055E-01 1.572 apatite-F 0.1556E-04 -4.808 0.7847E-02 -2.105 0.1437E-03 0.2451E-02 clinochlore 0.7075 -0.150 393.3 2.595 7.199 149.6 daphnite 0.2048 -0.689 146.2 2.165 2.676 44.29 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1860 -0.731 40.27 1.605 0.7373 12.31 hedenbergite 0.4823E-01 -1.317 11.97 1.078 0.2191 3.278 microcline 0.9339 -0.030 259.9 2.415 4.759 101.5 stilbite 3.222 0.508 2271. 3.356 41.57 1059. stilpnomelane-Fe 0.2552 -0.593 275.1 2.439 5.036 95.01 tr.625ac.25prg.125 0.6751E-01 -1.171 57.70 1.761 1.056 18.57 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1865E-01 0.1865E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.349585 g Volume = 2210.888300 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0399900 moles log = -1.3980 Original solution: 1000.0103000 g Original solution / Rock added: 25006.51 (Water/Rock Ratio), log = 4.3981 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 9.2590 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1126E+00 0.9652 0.1006E+01 0.1042E+01 CO2,gas 0.1683E-06 0.9819 0.1530E-05 0.1558E-05 CH4,gas 0.8858E+00 0.9957 0.8166E+01 0.8202E+01 H2,gas 0.1634E-02 1.0049 0.1520E-01 0.1513E-01 H2S,gas 0.1267E-05 0.9648 0.1132E-04 0.1173E-04 S2,gas 0.2248E-26 1.0000 0.2081E-25 0.2081E-25 CO,gas 0.6696E-12 1.0000 0.6200E-11 0.6200E-11 SO3,gas 0.6375E-47 1.0000 0.5903E-46 0.5903E-46 SO2,gas 0.3772E-26 1.0000 0.3492E-25 0.3492E-25 HF,gas 0.1292E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1736E-17 1.0000 0.1607E-16 0.1607E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.17 -7.51 -2.505 0.12830E+05 -5.815 3 CH4,gas 4.54 3.76 -0.79 -0.197 0.13437E+04 0.912 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.88 -6.65 -3.323 0.11346E+05 -4.946 6 S2,gas -7.34 -34.72 -27.38 -4.212 0.46752E+05 -25.682 7 CO,gas 3.21 -9.69 -12.91 -3.971 0.22038E+05 -11.208 8 SO3,gas 17.12 -30.81 -47.93 -11.982 0.81836E+05 -46.229 9 SO2,gas 0.83 -26.32 -27.16 -7.242 0.46368E+05 -25.457 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.30 -18.49 -9.246 0.31576E+05 -16.794 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80622E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93639E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -1.07 -2.04 -0.680 0.34818E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -1.07 -1.88 -0.628 0.32176E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68941E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65519E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.21 -2.11 -0.602 0.35966E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.21 -1.66 -0.475 0.28389E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82213E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.50 -2.25 -0.530 0.38443E+04 146 pyrrhotite -4.26 -6.14 -1.88 -0.627 0.32100E+04 147 pyrrhotiteFe0.875 -6.02 -7.54 -1.52 -0.559 0.25972E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22416E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28674E+03 154 rhodochrosite -0.98 -4.93 -3.95 -1.318 0.67528E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23218E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.44 -4.83 -1.610 0.82493E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27807E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47069E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90671E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77501E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.14 -1.73 -0.576 0.29528E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60603E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.63 -2.65 -0.885 0.45319E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.0399900 MOLES New total amount of reactant added: 0.0409900 MOLES Mixing fraction reached given limit of 0.4000E-01 TOTMIX = 0.4099E-01 Execution stopped.