File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.82788E+02 0.95788E-10 0.8354 0.00000000E+00 H2O 2 0. -0.71360E+01 0.10000E+01 0.9999 0.00000000E+00 Cl- 3 -1. 0.37382E-03 0.74836E-03 0.8300 0.00000000E+00 SO4-- 4 -2. 0.13878E+00 0.48076E-10 0.5071 0.00000000E+00 HCO3- 5 -1. 0.29043E-02 0.10059E-03 0.8313 0.00000000E+00 HS- 6 -1. -0.13779E+00 0.20059E-02 0.8302 0.00000000E+00 Al+++ 7 3. 0.16304E+02 0.12846E-28 0.2188 0.00000000E+00 H4SiO4 8 0. 0.52064E+02 0.69590E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.57507E+01 0.16093E-06 0.5031 0.00000000E+00 Mg++ 10 2. 0.39683E+01 0.25185E-10 0.5006 0.00000000E+00 Fe++ 11 2. 0.35650E+01 0.69415E-13 0.5012 0.00000000E+00 K+ 12 1. 0.10616E+01 0.16980E-03 0.8315 0.00000000E+00 Na+ 13 1. 0.62764E+01 0.21550E-01 0.8299 0.00000000E+00 Mn++ 14 2. 0.86693E-01 0.22353E-10 0.5016 0.00000000E+00 F- 15 -1. 0.16096E-04 0.10743E-05 0.8282 0.00000000E+00 HPO4-- 16 -2. 0.29588E-01 0.39895E-07 0.5071 0.00000000E+00 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.3738E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.800000E-01 TEMP = 100.0000 SINC = 0.2000E-02 TEMPC = 0.0000 TOTMIX = 0.399900E-01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 2000.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.6256E+01 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.5662E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.1371E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.9847E-02 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.1556E-04 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.3222E+01 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.2552E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.7075E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.2048E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.1734E-01 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.1860E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.4823E-01 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.9339E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.6751E-01 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0399900 moles log = -1.3980 Original solution: 1000.0103000 g Original solution / Rock added: 25006.51 (Water/Rock Ratio), log = 4.3981 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0399900 Water: Moles liquid = 0.2759E+02 kg liquid = 0.4971E+00 Moles total = -.7136E+01 kg total = -.1286E+00 Activity = 0.9999 Stoichiometric ionic strength = .8061415E-02 Osmotic coef. = 0.9279 True ionic strength = .2190075E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.3738E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95788E-10 -10.0187 0.80023E-10 -10.0968 0.83542E+00 -0.0781 2 H2O 0.99990E+00 0.0000 0.99990E+00 0.0000 3 Cl- 0.74836E-03 -3.1259 0.62117E-03 -3.2068 0.83003E+00 -0.0809 4 SO4-- 0.48076E-10 -10.3181 0.24377E-10 -10.6130 0.50705E+00 -0.2949 5 HCO3- 0.10059E-03 -3.9975 0.83620E-04 -4.0777 0.83134E+00 -0.0802 6 HS- 0.20059E-02 -2.6977 0.16652E-02 -2.7785 0.83016E+00 -0.0808 7 Al+++ 0.12846E-28 -28.8912 0.28101E-29 -29.5513 0.21876E+00 -0.6600 8 H4SiO4 0.69590E-03 -3.1575 0.69590E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.16093E-06 -6.7934 0.80958E-07 -7.0917 0.50305E+00 -0.2984 10 Mg++ 0.25185E-10 -10.5989 0.12607E-10 -10.8994 0.50059E+00 -0.3005 11 Fe++ 0.69415E-13 -13.1585 0.34789E-13 -13.4586 0.50117E+00 -0.3000 12 K+ 0.16980E-03 -3.7701 0.14120E-03 -3.8502 0.83155E+00 -0.0801 13 Na+ 0.21550E-01 -1.6666 0.17884E-01 -1.7475 0.82987E+00 -0.0810 14 Mn++ 0.22353E-10 -10.6507 0.11213E-10 -10.9503 0.50162E+00 -0.2996 15 F- 0.10743E-05 -5.9689 0.88970E-06 -6.0508 0.82820E+00 -0.0819 16 HPO4-- 0.39895E-07 -7.3991 0.20232E-07 -7.6940 0.50713E+00 -0.2949 18 HSiO3- 0.97838E-02 -2.0095 0.81209E-02 -2.0904 0.83003E+00 -0.0809 19 Ca(HSiO3)+ 0.18002E-07 -7.7447 0.14973E-07 -7.8247 0.83174E+00 -0.0800 20 Mg(HSiO3)+ 0.34888E-11 -11.4573 0.29018E-11 -11.5373 0.83174E+00 -0.0800 21 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.71769E-16 -16.1441 0.59693E-16 -16.2241 0.83174E+00 -0.0800 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.49598E-05 -5.3045 0.41089E-05 -5.3863 0.82843E+00 -0.0817 26 CH4,aq 0.55619E-02 -2.2548 0.55481E-02 -2.2559 0.99753E+00 -0.0011 27 C2H6,aq 0.45551E-09 -9.3415 0.45438E-09 -9.3426 0.99753E+00 -0.0011 28 C3H8,aq 0.86127E-15 -15.0649 0.85914E-15 -15.0659 0.99753E+00 -0.0011 30 ethanol,aq 0.16719E-16 -16.7768 0.16678E-16 -16.7779 0.99753E+00 -0.0011 31 CO,aq 0.41607E-14 -14.3808 0.41607E-14 -14.3808 0.10000E+01 0.0000 32 CO2,aq 0.14335E-07 -7.8436 0.14300E-07 -7.8447 0.99753E+00 -0.0011 33 CO3-2 0.18042E-03 -3.7437 0.91272E-04 -4.0397 0.50590E+00 -0.2959 34 CaCO3,aq 0.92653E-07 -7.0331 0.92653E-07 -7.0331 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.20776E-09 -9.6824 0.17281E-09 -9.7624 0.83174E+00 -0.0800 36 CaCl+ 0.97847E-10 -10.0095 0.81383E-10 -10.0895 0.83174E+00 -0.0800 37 CaCl2,aq 0.12010E-13 -13.9205 0.12010E-13 -13.9205 0.10000E+01 0.0000 38 CaF+ 0.12644E-11 -11.8981 0.10516E-11 -11.9781 0.83174E+00 -0.0800 39 CaOH+ 0.86680E-07 -7.0621 0.72095E-07 -7.1421 0.83174E+00 -0.0800 40 CaSO4,aq 0.62669E-15 -15.2030 0.62669E-15 -15.2030 0.10000E+01 0.0000 41 HCl,aq 0.91087E-14 -14.0405 0.91087E-14 -14.0405 0.10000E+01 0.0000 45 HF,aq 0.48739E-12 -12.3121 0.48739E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17638E-18 -18.7535 0.14640E-18 -18.8344 0.83003E+00 -0.0809 48 FeCl+ 0.41124E-16 -16.3859 0.34205E-16 -16.4659 0.83174E+00 -0.0800 51 FeF+ 0.19017E-17 -17.7209 0.15817E-17 -17.8009 0.83174E+00 -0.0800 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17012E-10 -10.7692 0.14150E-10 -10.8493 0.83174E+00 -0.0800 55 HFeO2- 0.33254E-07 -7.4782 0.27602E-07 -7.5591 0.83003E+00 -0.0809 56 FeO+ 0.11924E-16 -16.9236 0.99173E-17 -17.0036 0.83174E+00 -0.0800 58 FeO2- 0.38175E-09 -9.4182 0.31686E-09 -9.4991 0.83003E+00 -0.0809 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11610E-04 -4.9352 0.11581E-04 -4.9362 0.99753E+00 -0.0011 61 KCl,aq 0.15896E-08 -8.7987 0.15896E-08 -8.7987 0.10000E+01 0.0000 63 KOH,aq 0.75345E-06 -6.1229 0.75345E-06 -6.1229 0.10000E+01 0.0000 64 KSO4- 0.64348E-13 -13.1915 0.53411E-13 -13.2724 0.83003E+00 -0.0809 65 MgCO3,aq 0.36166E-11 -11.4417 0.36166E-11 -11.4417 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.33060E-13 -13.4807 0.27497E-13 -13.5607 0.83174E+00 -0.0800 67 MgCl+ 0.13810E-13 -13.8598 0.11486E-13 -13.9398 0.83174E+00 -0.0800 68 MgF+ 0.72936E-15 -15.1371 0.60664E-15 -15.2171 0.83174E+00 -0.0800 69 MgOH+ 0.74693E-10 -10.1267 0.62125E-10 -10.2067 0.83174E+00 -0.0800 71 MnF+ 0.20203E-15 -15.6946 0.16803E-15 -15.7746 0.83174E+00 -0.0800 72 MnO,aq 0.18131E-08 -8.7416 0.18131E-08 -8.7416 0.10000E+01 0.0000 73 MnOH+ 0.50937E-09 -9.2930 0.42366E-09 -9.3730 0.83174E+00 -0.0800 74 MnO2-2 0.18572E-10 -10.7311 0.93957E-11 -11.0271 0.50590E+00 -0.2959 75 HMnO2- 0.19845E-09 -9.7023 0.16472E-09 -9.7832 0.83003E+00 -0.0809 78 MnCl+ 0.51567E-13 -13.2876 0.42890E-13 -13.3676 0.83174E+00 -0.0800 79 MnSO4,aq 0.78909E-19 -19.1029 0.78909E-19 -19.1029 0.10000E+01 0.0000 80 NaCl,aq 0.36814E-05 -5.4340 0.36814E-05 -5.4340 0.10000E+01 0.0000 81 NaF,aq 0.37251E-08 -8.4289 0.37251E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.96008E-04 -4.0177 0.96008E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.87145E-02 -2.0598 0.72194E-02 -2.1415 0.82843E+00 -0.0817 89 HPO3-2 0.14435E-14 -14.8406 0.73027E-15 -15.1365 0.50590E+00 -0.2959 91 H2PO3- 0.14118E-18 -18.8502 0.11719E-18 -18.9311 0.83003E+00 -0.0809 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.35946E-10 -10.4444 0.29866E-10 -10.5248 0.83088E+00 -0.0805 94 PO4-3 0.89460E-09 -9.0484 0.20628E-09 -9.6855 0.23058E+00 -0.6372 98 HP2O7-3 0.79699E-18 -18.0985 0.17454E-18 -18.7581 0.21900E+00 -0.6596 99 P2O7-4 0.74297E-17 -17.1290 0.52106E-18 -18.2831 0.70131E-01 -1.1541 100 H2S,aq 0.41286E-06 -6.3842 0.41184E-06 -6.3853 0.99753E+00 -0.0011 101 S2-2 0.10487E-10 -10.9793 0.53054E-11 -11.2753 0.50590E+00 -0.2959 102 S3-2 0.50243E-18 -18.2989 0.25418E-18 -18.5949 0.50590E+00 -0.2959 107 SO3-2 0.71418E-16 -16.1462 0.36691E-16 -16.4354 0.51375E+00 -0.2893 108 HSO3- 0.22148E-18 -18.6547 0.18384E-18 -18.7356 0.83003E+00 -0.0809 109 HSO4- 0.22579E-17 -17.6463 0.18799E-17 -17.7259 0.83261E+00 -0.0796 111 S2O3-2 0.23314E-18 -18.6324 0.11794E-18 -18.9283 0.50590E+00 -0.2959 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9578769E-10 -.2114701E-01 -.2127433E+02 0.0000 2 H2O 0.1000000E+01 0.5551051E+02 0.9981343E+06 0.0000 3 Cl- 0.7483625E-03 0.7520456E-03 0.2661150E+02 6.8900 4 SO4-- 0.4807592E-10 -.5564791E-02 -.5335449E+03 9.5805 5 HCO3- 0.1005852E-03 0.5842998E-02 0.3558445E+03 6.0191 6 HS- 0.2005889E-02 0.7571093E-02 0.2499144E+03 7.3183 7 Al+++ 0.1284576E-28 0.4959970E-05 0.1335726E+00 0.7391 8 H4SiO4 0.6959013E-03 0.1282860E-01 0.1230678E+04 -3.1575 9 Ca++ 0.1609340E-06 0.3585762E-06 0.1434365E-01 13.1018 10 Mg++ 0.2518518E-10 0.1070322E-09 0.2597211E-05 9.2942 11 Fe++ 0.6941520E-13 0.3386692E-07 0.1887765E-02 6.7350 12 K+ 0.1698012E-03 0.1705562E-03 0.6656390E+01 6.2466 13 Na+ 0.2154990E-01 0.2399850E-01 0.5506701E+03 8.3492 14 Mn++ 0.2235321E-10 0.2561950E-08 0.1404804E-03 9.2433 15 F- 0.1074254E-05 0.1077981E-05 0.2044049E-01 4.0460 16 HPO4-- 0.3989476E-07 0.4082530E-07 0.3910910E-02 12.4996 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278824E+02 -.1051143E-01 -.8277773E+02 0.0000000E+00 2 H2O -.7136049E+01 0.2759231E+02 -.3472835E+02 0.0000000E+00 3 Cl- 0.3738152E-03 0.3738152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387835E+00 -.2766060E-02 0.1415495E+00 0.0000000E+00 5 HCO3- 0.2904347E-02 0.2904347E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1377862E+00 0.3763322E-02 -.1415495E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2465425E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6376642E-02 0.5205753E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1782355E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5320189E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1683405E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8477744E-04 0.1061486E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1192880E-01 0.6264448E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1273454E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1609600E-04 0.5358262E-06 0.1556017E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2029281E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.3754E-14 Mass of aqueous solution: 0.498013E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0399900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.256 0.796 1640. 3.215 30.03 629.7 andradite 0.5662 -0.247 287.7 2.459 5.268 74.75 grossular 0.1371 -0.863 61.76 1.791 1.131 17.18 apatite-OH 0.9847E-02 -2.007 4.946 0.694 0.9055E-01 1.572 apatite-F 0.1556E-04 -4.808 0.7847E-02 -2.105 0.1437E-03 0.2451E-02 clinochlore 0.7075 -0.150 393.3 2.595 7.199 149.6 daphnite 0.2048 -0.689 146.2 2.165 2.676 44.29 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1860 -0.731 40.27 1.605 0.7373 12.31 hedenbergite 0.4823E-01 -1.317 11.97 1.078 0.2191 3.278 microcline 0.9339 -0.030 259.9 2.415 4.759 101.5 stilbite 3.222 0.508 2271. 3.356 41.57 1059. stilpnomelane-Fe 0.2552 -0.593 275.1 2.439 5.036 95.01 tr.625ac.25prg.125 0.6751E-01 -1.171 57.70 1.761 1.056 18.57 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1865E-01 0.1865E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.349585 g Volume = 2210.888300 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0399900 moles log = -1.3980 Original solution: 1000.0103000 g Original solution / Rock added: 25006.51 (Water/Rock Ratio), log = 4.3981 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 9.2590 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1126E+00 0.9652 0.1006E+01 0.1042E+01 CO2,gas 0.1683E-06 0.9819 0.1530E-05 0.1558E-05 CH4,gas 0.8858E+00 0.9957 0.8166E+01 0.8202E+01 H2,gas 0.1634E-02 1.0049 0.1520E-01 0.1513E-01 H2S,gas 0.1267E-05 0.9648 0.1132E-04 0.1173E-04 S2,gas 0.2248E-26 1.0000 0.2081E-25 0.2081E-25 CO,gas 0.6696E-12 1.0000 0.6200E-11 0.6200E-11 SO3,gas 0.6375E-47 1.0000 0.5903E-46 0.5903E-46 SO2,gas 0.3772E-26 1.0000 0.3492E-25 0.3492E-25 HF,gas 0.1292E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1736E-17 1.0000 0.1607E-16 0.1607E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.18198E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.15165E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.17 -7.51 -2.505 0.12830E+05 -5.815 3 CH4,gas 4.54 3.76 -0.79 -0.197 0.13437E+04 0.912 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.88 -6.65 -3.323 0.11346E+05 -4.946 6 S2,gas -7.34 -34.72 -27.38 -4.212 0.46752E+05 -25.682 7 CO,gas 3.21 -9.69 -12.91 -3.971 0.22038E+05 -11.208 8 SO3,gas 17.12 -30.81 -47.93 -11.982 0.81836E+05 -46.229 9 SO2,gas 0.83 -26.32 -27.16 -7.242 0.46368E+05 -25.457 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.30 -18.49 -9.246 0.31576E+05 -16.794 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80622E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93639E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -1.07 -2.04 -0.680 0.34818E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -1.07 -1.88 -0.628 0.32176E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52802E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68941E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65519E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.21 -2.11 -0.602 0.35966E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.21 -1.66 -0.475 0.28389E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82213E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36680E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.50 -2.25 -0.530 0.38443E+04 146 pyrrhotite -4.26 -6.14 -1.88 -0.627 0.32100E+04 147 pyrrhotiteFe0.875 -6.02 -7.54 -1.52 -0.559 0.25972E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22416E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28674E+03 154 rhodochrosite -0.98 -4.93 -3.95 -1.318 0.67528E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23218E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.44 -4.83 -1.610 0.82493E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27807E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47069E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90671E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77501E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.14 -1.73 -0.576 0.29528E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60603E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66552E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.63 -2.65 -0.885 0.45319E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0399900 MOLES New total amount of reactant added: 0.0419900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8660E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0419900 Water: Moles liquid = 0.2759E+02 kg liquid = 0.4971E+00 Moles total = -.7134E+01 kg total = -.1285E+00 Activity = 0.9999 Stoichiometric ionic strength = .7891585E-02 Osmotic coef. = 0.9286 True ionic strength = .2199090E-01 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.3856E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.96150E-10 -10.0171 0.80304E-10 -10.0953 0.83520E+00 -0.0782 2 H2O 0.99989E+00 0.0000 0.99989E+00 0.0000 3 Cl- 0.77192E-03 -3.1124 0.64053E-03 -3.1935 0.82980E+00 -0.0810 4 SO4-- 0.50280E-10 -10.2986 0.25466E-10 -10.5940 0.50649E+00 -0.2954 5 HCO3- 0.10528E-03 -3.9777 0.87495E-04 -4.0580 0.83110E+00 -0.0803 6 HS- 0.21035E-02 -2.6771 0.17457E-02 -2.7580 0.82993E+00 -0.0810 7 Al+++ 0.13015E-28 -28.8856 0.28398E-29 -29.5467 0.21820E+00 -0.6611 8 H4SiO4 0.69590E-03 -3.1575 0.69590E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.16225E-06 -6.7898 0.81528E-07 -7.0887 0.50248E+00 -0.2989 10 Mg++ 0.25392E-10 -10.5953 0.12696E-10 -10.8963 0.50001E+00 -0.3010 11 Fe++ 0.69984E-13 -13.1550 0.35034E-13 -13.4555 0.50060E+00 -0.3005 12 K+ 0.17044E-03 -3.7684 0.14169E-03 -3.8487 0.83131E+00 -0.0802 13 Na+ 0.21631E-01 -1.6649 0.17946E-01 -1.7460 0.82963E+00 -0.0811 14 Mn++ 0.22541E-10 -10.6470 0.11294E-10 -10.9472 0.50105E+00 -0.3001 15 F- 0.10708E-05 -5.9703 0.88658E-06 -6.0523 0.82796E+00 -0.0820 16 HPO4-- 0.39660E-07 -7.4016 0.20090E-07 -7.6970 0.50657E+00 -0.2954 18 HSiO3- 0.97523E-02 -2.0109 0.80925E-02 -2.0919 0.82980E+00 -0.0810 19 Ca(HSiO3)+ 0.18070E-07 -7.7430 0.15025E-07 -7.8232 0.83150E+00 -0.0801 20 Mg(HSiO3)+ 0.35020E-11 -11.4557 0.29119E-11 -11.5358 0.83150E+00 -0.0801 21 NaHSiO3,aq 0.23489E-02 -2.6291 0.23489E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.72042E-16 -16.1424 0.59903E-16 -16.2226 0.83150E+00 -0.0801 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.49439E-05 -5.3059 0.40945E-05 -5.3878 0.82818E+00 -0.0819 26 CH4,aq 0.58397E-02 -2.2336 0.58256E-02 -2.2347 0.99758E+00 -0.0011 27 C2H6,aq 0.50218E-09 -9.2991 0.50097E-09 -9.3002 0.99758E+00 -0.0011 28 C3H8,aq 0.99702E-15 -15.0013 0.99460E-15 -15.0023 0.99758E+00 -0.0011 30 ethanol,aq 0.18432E-16 -16.7344 0.18387E-16 -16.7355 0.99758E+00 -0.0011 31 CO,aq 0.43688E-14 -14.3596 0.43688E-14 -14.3596 0.10000E+01 0.0000 32 CO2,aq 0.15051E-07 -7.8224 0.15015E-07 -7.8235 0.99758E+00 -0.0011 33 CO3-2 0.18833E-03 -3.7251 0.95168E-04 -4.0215 0.50533E+00 -0.2964 34 CaCO3,aq 0.97288E-07 -7.0119 0.97288E-07 -7.0119 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.21898E-09 -9.6596 0.18209E-09 -9.7397 0.83150E+00 -0.0801 36 CaCl+ 0.10164E-09 -9.9930 0.84511E-10 -10.0731 0.83150E+00 -0.0801 37 CaCl2,aq 0.12861E-13 -13.8907 0.12861E-13 -13.8907 0.10000E+01 0.0000 38 CaF+ 0.12692E-11 -11.8965 0.10553E-11 -11.9766 0.83150E+00 -0.0801 39 CaOH+ 0.87009E-07 -7.0604 0.72348E-07 -7.1406 0.83150E+00 -0.0801 40 CaSO4,aq 0.65930E-15 -15.1809 0.65930E-15 -15.1809 0.10000E+01 0.0000 41 HCl,aq 0.94257E-14 -14.0257 0.94257E-14 -14.0257 0.10000E+01 0.0000 45 HF,aq 0.48739E-12 -12.3121 0.48739E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17582E-18 -18.7549 0.14589E-18 -18.8360 0.82980E+00 -0.0810 48 FeCl+ 0.42717E-16 -16.3694 0.35519E-16 -16.4495 0.83150E+00 -0.0801 51 FeF+ 0.19089E-17 -17.7192 0.15872E-17 -17.7994 0.83150E+00 -0.0801 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17077E-10 -10.7676 0.14199E-10 -10.8477 0.83150E+00 -0.0801 55 HFeO2- 0.33147E-07 -7.4796 0.27505E-07 -7.5606 0.82980E+00 -0.0810 56 FeO+ 0.11969E-16 -16.9219 0.99522E-17 -17.0021 0.83150E+00 -0.0801 58 FeO2- 0.38052E-09 -9.4196 0.31575E-09 -9.5007 0.82980E+00 -0.0810 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11609E-04 -4.9352 0.11581E-04 -4.9362 0.99758E+00 -0.0011 61 KCl,aq 0.16449E-08 -8.7839 0.16449E-08 -8.7839 0.10000E+01 0.0000 63 KOH,aq 0.75343E-06 -6.1230 0.75343E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.67478E-13 -13.1708 0.55993E-13 -13.2519 0.82980E+00 -0.0810 65 MgCO3,aq 0.37975E-11 -11.4205 0.37975E-11 -11.4205 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.34845E-13 -13.4579 0.28974E-13 -13.5380 0.83150E+00 -0.0801 67 MgCl+ 0.14345E-13 -13.8433 0.11928E-13 -13.9234 0.83150E+00 -0.0801 68 MgF+ 0.73212E-15 -15.1354 0.60876E-15 -15.2156 0.83150E+00 -0.0801 69 MgOH+ 0.74976E-10 -10.1251 0.62343E-10 -10.2052 0.83150E+00 -0.0801 71 MnF+ 0.20283E-15 -15.6929 0.16865E-15 -15.7730 0.83150E+00 -0.0801 72 MnO,aq 0.18135E-08 -8.7415 0.18135E-08 -8.7415 0.10000E+01 0.0000 73 MnOH+ 0.51140E-09 -9.2912 0.42523E-09 -9.3714 0.83150E+00 -0.0801 74 MnO2-2 0.18467E-10 -10.7336 0.93319E-11 -11.0300 0.50533E+00 -0.2964 75 HMnO2- 0.19785E-09 -9.7037 0.16418E-09 -9.7847 0.82980E+00 -0.0810 78 MnCl+ 0.53574E-13 -13.2710 0.44547E-13 -13.3512 0.83150E+00 -0.0801 79 MnSO4,aq 0.83032E-19 -19.0808 0.83032E-19 -19.0808 0.10000E+01 0.0000 80 NaCl,aq 0.38095E-05 -5.4191 0.38095E-05 -5.4191 0.10000E+01 0.0000 81 NaF,aq 0.37250E-08 -8.4289 0.37250E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.96007E-04 -4.0177 0.96007E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.86866E-02 -2.0612 0.71941E-02 -2.1430 0.82818E+00 -0.0819 89 HPO3-2 0.14350E-14 -14.8431 0.72517E-15 -15.1396 0.50533E+00 -0.2964 91 H2PO3- 0.14073E-18 -18.8516 0.11678E-18 -18.9326 0.82980E+00 -0.0810 92 H3PO4,aq 0.90612E-18 -18.0428 0.90612E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.35830E-10 -10.4458 0.29762E-10 -10.5263 0.83064E+00 -0.0806 94 PO4-3 0.88734E-09 -9.0519 0.20412E-09 -9.6901 0.23004E+00 -0.6382 98 HP2O7-3 0.79065E-18 -18.1020 0.17271E-18 -18.7627 0.21845E+00 -0.6607 99 P2O7-4 0.73586E-17 -17.1332 0.51381E-18 -18.2892 0.69824E-01 -1.1560 100 H2S,aq 0.43432E-06 -6.3622 0.43327E-06 -6.3632 0.99758E+00 -0.0011 101 S2-2 0.11539E-10 -10.9378 0.58309E-11 -11.2343 0.50533E+00 -0.2964 102 S3-2 0.58158E-18 -18.2354 0.29389E-18 -18.5318 0.50533E+00 -0.2964 107 SO3-2 0.74689E-16 -16.1267 0.38330E-16 -16.4165 0.51320E+00 -0.2897 108 HSO3- 0.23226E-18 -18.6340 0.19273E-18 -18.7151 0.82980E+00 -0.0810 109 HSO4- 0.23677E-17 -17.6257 0.19708E-17 -17.7053 0.83238E+00 -0.0797 111 S2O3-2 0.25652E-18 -18.5909 0.12963E-18 -18.8873 0.50533E+00 -0.2964 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9614974E-10 -.2109539E-01 -.2122222E+02 0.0000 2 H2O 0.1000000E+01 0.5551079E+02 0.9981311E+06 0.0000 3 Cl- 0.7719168E-03 0.7757281E-03 0.2744929E+02 6.9018 4 SO4-- 0.5027999E-10 -.5842642E-02 -.5601802E+03 9.5965 5 HCO3- 0.1052764E-03 0.6133456E-02 0.3735306E+03 6.0372 6 HS- 0.2103487E-02 0.7946564E-02 0.2623062E+03 7.3372 7 Al+++ 0.1301465E-28 0.4944079E-05 0.1331435E+00 0.7391 8 H4SiO4 0.6958974E-03 0.1279713E-01 0.1227649E+04 -3.1575 9 Ca++ 0.1622501E-06 0.3649383E-06 0.1459803E-01 13.1018 10 Mg++ 0.2539153E-10 0.1077167E-09 0.2613799E-05 9.2942 11 Fe++ 0.6998399E-13 0.3375876E-07 0.1881720E-02 6.7350 12 K+ 0.1704429E-03 0.1711980E-03 0.6681383E+01 6.2466 13 Na+ 0.2163149E-01 0.2408018E-01 0.5525397E+03 8.3492 14 Mn++ 0.2254069E-10 0.2563816E-08 0.1405815E-03 9.2434 15 F- 0.1070806E-05 0.1074533E-05 0.2037493E-01 4.0430 16 HPO4-- 0.3966001E-07 0.4058318E-07 0.3887684E-02 12.4935 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278803E+02 -.1048654E-01 -.8277754E+02 0.0000000E+00 2 H2O -.7134412E+01 0.2759447E+02 -.3472888E+02 0.0000000E+00 3 Cl- 0.3856152E-03 0.3856152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1387930E+00 -.2904383E-02 0.1416974E+00 0.0000000E+00 5 HCO3- 0.3048947E-02 0.3048947E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1377472E+00 0.3950245E-02 -.1416974E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2457706E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6361466E-02 0.5205754E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1814112E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5354606E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1678151E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8510270E-04 0.1061486E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1197028E-01 0.6264407E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1274475E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1689600E-04 0.5341513E-06 0.1636185E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2017394E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.8687E-14 Mass of aqueous solution: 0.498053E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0419900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.256 0.796 1640. 3.215 30.03 629.7 andradite 0.5668 -0.247 288.0 2.459 5.273 74.83 grossular 0.1373 -0.862 61.83 1.791 1.132 17.20 apatite-OH 0.9846E-02 -2.007 4.946 0.694 0.9055E-01 1.572 apatite-F 0.1636E-04 -4.786 0.8251E-02 -2.083 0.1511E-03 0.2578E-02 clinochlore 0.7074 -0.150 393.2 2.595 7.198 149.6 daphnite 0.2048 -0.689 146.1 2.165 2.675 44.28 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1821 -0.740 39.44 1.596 0.7220 12.05 hedenbergite 0.4723E-01 -1.326 11.72 1.069 0.2145 3.210 microcline 0.9341 -0.030 260.0 2.415 4.760 101.6 stilbite 3.222 0.508 2271. 3.356 41.57 1059. stilpnomelane-Fe 0.2549 -0.594 274.7 2.439 5.030 94.90 tr.625ac.25prg.125 0.6876E-01 -1.163 58.78 1.769 1.076 18.92 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1865E-01 0.1865E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.350118 g Volume = 2210.893834 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0419900 moles log = -1.3769 Original solution: 1000.0103000 g Original solution / Rock added: 23815.44 (Water/Rock Ratio), log = 4.3769 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 9.6725 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1078E+00 0.9647 0.1006E+01 0.1043E+01 CO2,gas 0.1693E-06 0.9812 0.1606E-05 0.1637E-05 CH4,gas 0.8906E+00 0.9954 0.8575E+01 0.8615E+01 H2,gas 0.1564E-02 1.0052 0.1520E-01 0.1513E-01 H2S,gas 0.1278E-05 0.9633 0.1191E-04 0.1236E-04 S2,gas 0.2381E-26 1.0000 0.2303E-25 0.2303E-25 CO,gas 0.6731E-12 1.0000 0.6510E-11 0.6510E-11 SO3,gas 0.6420E-47 1.0000 0.6210E-46 0.6210E-46 SO2,gas 0.3798E-26 1.0000 0.3674E-25 0.3674E-25 HF,gas 0.1237E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1719E-17 1.0000 0.1663E-16 0.1663E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.15 -7.49 -2.498 0.12794E+05 -5.794 3 CH4,gas 4.54 3.78 -0.77 -0.191 0.13075E+04 0.933 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.85 -6.62 -3.312 0.11309E+05 -4.924 6 S2,gas -7.34 -34.67 -27.34 -4.206 0.46677E+05 -25.638 7 CO,gas 3.21 -9.67 -12.89 -3.965 0.22001E+05 -11.186 8 SO3,gas 17.12 -30.78 -47.91 -11.976 0.81798E+05 -46.207 9 SO2,gas 0.83 -26.30 -27.13 -7.236 0.46330E+05 -25.435 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.29 -18.48 -9.239 0.31551E+05 -16.779 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80617E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93640E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28492E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -1.05 -2.02 -0.673 0.34456E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -1.05 -1.86 -0.621 0.31814E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71072E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68941E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65518E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.19 -2.09 -0.596 0.35604E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.19 -1.64 -0.469 0.28027E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82211E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36681E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.45 -2.21 -0.519 0.37691E+04 146 pyrrhotite -4.26 -6.12 -1.86 -0.619 0.31724E+04 147 pyrrhotiteFe0.875 -6.02 -7.52 -1.50 -0.551 0.25596E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22414E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28673E+03 154 rhodochrosite -0.98 -4.91 -3.93 -1.311 0.67165E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23217E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.42 -4.81 -1.603 0.82131E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27807E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47067E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90671E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77501E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.12 -1.71 -0.569 0.29152E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60603E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.61 -2.63 -0.877 0.44941E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0419900 MOLES New total amount of reactant added: 0.0439900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8660E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0439900 Water: Moles liquid = 0.2760E+02 kg liquid = 0.4971E+00 Moles total = -.7133E+01 kg total = -.1285E+00 Activity = 0.9999 Stoichiometric ionic strength = .7721661E-02 Osmotic coef. = 0.9293 True ionic strength = .2208105E-01 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.3974E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.96512E-10 -10.0154 0.80585E-10 -10.0937 0.83497E+00 -0.0783 2 H2O 0.99989E+00 0.0000 0.99989E+00 0.0000 3 Cl- 0.79547E-03 -3.0994 0.65989E-03 -3.1805 0.82956E+00 -0.0812 4 SO4-- 0.52472E-10 -10.2801 0.26547E-10 -10.5760 0.50593E+00 -0.2959 5 HCO3- 0.10994E-03 -3.9588 0.91345E-04 -4.0393 0.83087E+00 -0.0805 6 HS- 0.22011E-02 -2.6574 0.18262E-02 -2.7385 0.82969E+00 -0.0811 7 Al+++ 0.13185E-28 -28.8799 0.28698E-29 -29.5421 0.21765E+00 -0.6622 8 H4SiO4 0.69589E-03 -3.1575 0.69589E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.16357E-06 -6.7863 0.82100E-07 -7.0857 0.50192E+00 -0.2994 10 Mg++ 0.25599E-10 -10.5918 0.12785E-10 -10.8933 0.49944E+00 -0.3015 11 Fe++ 0.70556E-13 -13.1515 0.35280E-13 -13.4525 0.50003E+00 -0.3010 12 K+ 0.17109E-03 -3.7668 0.14219E-03 -3.8471 0.83108E+00 -0.0804 13 Na+ 0.21713E-01 -1.6633 0.18009E-01 -1.7445 0.82939E+00 -0.0812 14 Mn++ 0.22729E-10 -10.6434 0.11375E-10 -10.9440 0.50048E+00 -0.3006 15 F- 0.10674E-05 -5.9717 0.88348E-06 -6.0538 0.82771E+00 -0.0821 16 HPO4-- 0.39427E-07 -7.4042 0.19950E-07 -7.7000 0.50601E+00 -0.2958 18 HSiO3- 0.97211E-02 -2.0123 0.80642E-02 -2.0934 0.82956E+00 -0.0812 19 Ca(HSiO3)+ 0.18138E-07 -7.7414 0.15078E-07 -7.8217 0.83127E+00 -0.0803 20 Mg(HSiO3)+ 0.35153E-11 -11.4540 0.29221E-11 -11.5343 0.83127E+00 -0.0803 21 NaHSiO3,aq 0.23488E-02 -2.6291 0.23488E-02 -2.6291 0.10000E+01 0.0000 22 AlO+ 0.72315E-16 -16.1408 0.60113E-16 -16.2210 0.83127E+00 -0.0803 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.49281E-05 -5.3073 0.40802E-05 -5.3893 0.82794E+00 -0.0820 26 CH4,aq 0.61177E-02 -2.2134 0.61032E-02 -2.2144 0.99763E+00 -0.0010 27 C2H6,aq 0.55115E-09 -9.2587 0.54985E-09 -9.2598 0.99763E+00 -0.0010 28 C3H8,aq 0.11464E-14 -14.9407 0.11437E-14 -14.9417 0.99763E+00 -0.0010 30 ethanol,aq 0.20229E-16 -16.6940 0.20182E-16 -16.6950 0.99763E+00 -0.0010 31 CO,aq 0.45770E-14 -14.3394 0.45770E-14 -14.3394 0.10000E+01 0.0000 32 CO2,aq 0.15768E-07 -7.8022 0.15731E-07 -7.8033 0.99763E+00 -0.0010 33 CO3-2 0.19614E-03 -3.7074 0.99008E-04 -4.0043 0.50477E+00 -0.2969 34 CaCO3,aq 0.10192E-06 -6.9917 0.10192E-06 -6.9917 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.23029E-09 -9.6377 0.19143E-09 -9.7180 0.83127E+00 -0.0803 36 CaCl+ 0.10547E-09 -9.9769 0.87675E-10 -10.0571 0.83127E+00 -0.0803 37 CaCl2,aq 0.13745E-13 -13.8618 0.13745E-13 -13.8618 0.10000E+01 0.0000 38 CaF+ 0.12740E-11 -11.8948 0.10590E-11 -11.9751 0.83127E+00 -0.0803 39 CaOH+ 0.87338E-07 -7.0588 0.72601E-07 -7.1391 0.83127E+00 -0.0803 40 CaSO4,aq 0.69210E-15 -15.1598 0.69210E-15 -15.1598 0.10000E+01 0.0000 41 HCl,aq 0.97445E-14 -14.0112 0.97445E-14 -14.0112 0.10000E+01 0.0000 45 HF,aq 0.48739E-12 -12.3121 0.48739E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17525E-18 -18.7563 0.14538E-18 -18.8375 0.82956E+00 -0.0812 48 FeCl+ 0.44329E-16 -16.3533 0.36849E-16 -16.4336 0.83127E+00 -0.0803 51 FeF+ 0.19161E-17 -17.7176 0.15928E-17 -17.7978 0.83127E+00 -0.0803 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17141E-10 -10.7660 0.14249E-10 -10.8462 0.83127E+00 -0.0803 55 HFeO2- 0.33040E-07 -7.4810 0.27409E-07 -7.5621 0.82956E+00 -0.0812 56 FeO+ 0.12014E-16 -16.9203 0.99871E-17 -17.0006 0.83127E+00 -0.0803 58 FeO2- 0.37930E-09 -9.4210 0.31465E-09 -9.5022 0.82956E+00 -0.0812 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11609E-04 -4.9352 0.11581E-04 -4.9362 0.99763E+00 -0.0010 61 KCl,aq 0.17005E-08 -8.7694 0.17005E-08 -8.7694 0.10000E+01 0.0000 63 KOH,aq 0.75342E-06 -6.1230 0.75342E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.70607E-13 -13.1511 0.58573E-13 -13.2323 0.82956E+00 -0.0812 65 MgCO3,aq 0.39785E-11 -11.4003 0.39785E-11 -11.4003 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.36644E-13 -13.4360 0.30461E-13 -13.5163 0.83127E+00 -0.0803 67 MgCl+ 0.14886E-13 -13.8272 0.12375E-13 -13.9075 0.83127E+00 -0.0803 68 MgF+ 0.73489E-15 -15.1338 0.61089E-15 -15.2140 0.83127E+00 -0.0803 69 MgOH+ 0.75260E-10 -10.1234 0.62561E-10 -10.2037 0.83127E+00 -0.0803 71 MnF+ 0.20364E-15 -15.6911 0.16928E-15 -15.7714 0.83127E+00 -0.0803 72 MnO,aq 0.18138E-08 -8.7414 0.18138E-08 -8.7414 0.10000E+01 0.0000 73 MnOH+ 0.51344E-09 -9.2895 0.42680E-09 -9.3698 0.83127E+00 -0.0803 74 MnO2-2 0.18362E-10 -10.7361 0.92686E-11 -11.0330 0.50477E+00 -0.2969 75 HMnO2- 0.19726E-09 -9.7050 0.16364E-09 -9.7861 0.82956E+00 -0.0812 78 MnCl+ 0.55607E-13 -13.2549 0.46224E-13 -13.3351 0.83127E+00 -0.0803 79 MnSO4,aq 0.87181E-19 -19.0596 0.87181E-19 -19.0596 0.10000E+01 0.0000 80 NaCl,aq 0.39383E-05 -5.4047 0.39383E-05 -5.4047 0.10000E+01 0.0000 81 NaF,aq 0.37249E-08 -8.4289 0.37249E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.96005E-04 -4.0177 0.96005E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.86587E-02 -2.0625 0.71689E-02 -2.1445 0.82794E+00 -0.0820 89 HPO3-2 0.14266E-14 -14.8457 0.72011E-15 -15.1426 0.50477E+00 -0.2969 91 H2PO3- 0.14028E-18 -18.8530 0.11637E-18 -18.9342 0.82956E+00 -0.0812 92 H3PO4,aq 0.90613E-18 -18.0428 0.90613E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.35715E-10 -10.4471 0.29658E-10 -10.5279 0.83041E+00 -0.0807 94 PO4-3 0.88015E-09 -9.0554 0.20199E-09 -9.6947 0.22949E+00 -0.6392 98 HP2O7-3 0.78438E-18 -18.1055 0.17091E-18 -18.7672 0.21790E+00 -0.6618 99 P2O7-4 0.72884E-17 -17.1374 0.50667E-18 -18.2953 0.69518E-01 -1.1579 100 H2S,aq 0.45591E-06 -6.3411 0.45483E-06 -6.3421 0.99763E+00 -0.0010 101 S2-2 0.12641E-10 -10.8982 0.63808E-11 -11.1951 0.50477E+00 -0.2969 102 S3-2 0.66885E-18 -18.1747 0.33762E-18 -18.4716 0.50477E+00 -0.2969 107 SO3-2 0.77942E-16 -16.1082 0.39957E-16 -16.3984 0.51265E+00 -0.2902 108 HSO3- 0.24303E-18 -18.6143 0.20161E-18 -18.6955 0.82956E+00 -0.0812 109 HSO4- 0.24776E-17 -17.6060 0.20617E-17 -17.6858 0.83215E+00 -0.0798 111 S2O3-2 0.28102E-18 -18.5513 0.14185E-18 -18.8482 0.50477E+00 -0.2969 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9651225E-10 -.2104401E-01 -.2117036E+02 0.0000 2 H2O 0.1000000E+01 0.5551108E+02 0.9981279E+06 0.0000 3 Cl- 0.7954670E-03 0.7994071E-03 0.2828694E+02 6.9132 4 SO4-- 0.5247190E-10 -.6120572E-02 -.5868226E+03 9.6115 5 HCO3- 0.1099392E-03 0.6423872E-02 0.3912138E+03 6.0544 6 HS- 0.2201071E-02 0.8322099E-02 0.2746998E+03 7.3553 7 Al+++ 0.1318531E-28 0.4928278E-05 0.1327169E+00 0.7391 8 H4SiO4 0.6958935E-03 0.1276584E-01 0.1224637E+04 -3.1575 9 Ca++ 0.1635737E-06 0.3713104E-06 0.1485279E-01 13.1018 10 Mg++ 0.2559905E-10 0.1084055E-09 0.2630493E-05 9.2942 11 Fe++ 0.7055599E-13 0.3365121E-07 0.1875710E-02 6.7350 12 K+ 0.1710855E-03 0.1718406E-03 0.6706406E+01 6.2466 13 Na+ 0.2171318E-01 0.2416196E-01 0.5544117E+03 8.3492 14 Mn++ 0.2272928E-10 0.2565691E-08 0.1406832E-03 9.2435 15 F- 0.1067377E-05 0.1071104E-05 0.2030975E-01 4.0399 16 HPO4-- 0.3942722E-07 0.4034309E-07 0.3864652E-02 12.4874 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278781E+02 -.1046177E-01 -.8277735E+02 0.0000000E+00 2 H2O -.7132774E+01 0.2759663E+02 -.3472941E+02 0.0000000E+00 3 Cl- 0.3974152E-03 0.3974152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1388026E+00 -.3042765E-02 0.1418453E+00 0.0000000E+00 5 HCO3- 0.3193547E-02 0.3193547E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1377081E+00 0.4137227E-02 -.1418453E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2450032E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6346376E-02 0.5205756E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1845923E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5389245E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1672928E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8542841E-04 0.1061485E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1201181E-01 0.6264365E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1275501E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1769600E-04 0.5324859E-06 0.1716351E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.2005606E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1491E-13 Mass of aqueous solution: 0.498094E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0439900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.256 0.796 1640. 3.215 30.03 629.7 andradite 0.5674 -0.246 288.3 2.460 5.279 74.91 grossular 0.1374 -0.862 61.89 1.792 1.133 17.22 apatite-OH 0.9845E-02 -2.007 4.946 0.694 0.9054E-01 1.572 apatite-F 0.1716E-04 -4.765 0.8656E-02 -2.063 0.1585E-03 0.2704E-02 clinochlore 0.7072 -0.150 393.1 2.595 7.197 149.5 daphnite 0.2048 -0.689 146.1 2.165 2.675 44.27 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1783 -0.749 38.60 1.587 0.7067 11.80 hedenbergite 0.4623E-01 -1.335 11.47 1.060 0.2100 3.142 microcline 0.9342 -0.030 260.0 2.415 4.760 101.6 stilbite 3.223 0.508 2271. 3.356 41.58 1059. stilpnomelane-Fe 0.2545 -0.594 274.4 2.438 5.023 94.78 tr.625ac.25prg.125 0.7002E-01 -1.155 59.85 1.777 1.096 19.26 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1866E-01 0.1866E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.350645 g Volume = 2210.899370 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0439900 moles log = -1.3566 Original solution: 1000.0103000 g Original solution / Rock added: 22732.67 (Water/Rock Ratio), log = 4.3567 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 10.0863 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1034E+00 0.9642 0.1006E+01 0.1043E+01 CO2,gas 0.1702E-06 0.9805 0.1683E-05 0.1716E-05 CH4,gas 0.8951E+00 0.9951 0.8983E+01 0.9028E+01 H2,gas 0.1499E-02 1.0054 0.1520E-01 0.1512E-01 H2S,gas 0.1289E-05 0.9618 0.1250E-04 0.1300E-04 S2,gas 0.2516E-26 1.0000 0.2538E-25 0.2538E-25 CO,gas 0.6762E-12 1.0000 0.6821E-11 0.6821E-11 SO3,gas 0.6463E-47 1.0000 0.6519E-46 0.6519E-46 SO2,gas 0.3824E-26 1.0000 0.3857E-25 0.3857E-25 HF,gas 0.1186E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1705E-17 1.0000 0.1719E-16 0.1719E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.13 -7.47 -2.491 0.12760E+05 -5.774 3 CH4,gas 4.54 3.80 -0.75 -0.186 0.12730E+04 0.953 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.83 -6.60 -3.301 0.11273E+05 -4.903 6 S2,gas -7.34 -34.63 -27.29 -4.199 0.46605E+05 -25.595 7 CO,gas 3.21 -9.65 -12.87 -3.959 0.21967E+05 -11.166 8 SO3,gas 17.12 -30.76 -47.88 -11.971 0.81762E+05 -46.186 9 SO2,gas 0.83 -26.28 -27.11 -7.230 0.46294E+05 -25.414 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.27 -18.46 -9.232 0.31526E+05 -16.765 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80613E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93640E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28493E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -1.03 -2.00 -0.666 0.34111E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -1.03 -1.84 -0.614 0.31469E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68941E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65516E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.17 -2.06 -0.590 0.35259E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 89 graphite -3.55 -5.17 -1.62 -0.463 0.27682E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82210E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36681E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.41 -2.17 -0.509 0.36970E+04 146 pyrrhotite -4.26 -6.10 -1.84 -0.612 0.31364E+04 147 pyrrhotiteFe0.875 -6.02 -7.49 -1.48 -0.544 0.25236E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22413E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28673E+03 154 rhodochrosite -0.98 -4.89 -3.91 -1.304 0.66818E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23215E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.40 -4.79 -1.597 0.81786E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27807E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47064E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90671E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77501E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65446E+04 184 troilite-low -4.41 -6.10 -1.69 -0.562 0.28792E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60603E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66178E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.59 -2.61 -0.870 0.44580E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0439900 MOLES New total amount of reactant added: 0.0459900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8659E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0459900 Water: Moles liquid = 0.2760E+02 kg liquid = 0.4972E+00 Moles total = -.7131E+01 kg total = -.1285E+00 Activity = 0.9999 Stoichiometric ionic strength = .7551646E-02 Osmotic coef. = 0.9300 True ionic strength = .2217122E-01 Chg. balance for total moles = -.8659E-10 Max. difference allowed = 0.4092E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.96875E-10 -10.0138 0.80867E-10 -10.0922 0.83475E+00 -0.0784 2 H2O 0.99988E+00 -0.0001 0.99988E+00 -0.0001 3 Cl- 0.81901E-03 -3.0867 0.67922E-03 -3.1680 0.82932E+00 -0.0813 4 SO4-- 0.54652E-10 -10.2624 0.27620E-10 -10.5588 0.50537E+00 -0.2964 5 HCO3- 0.11457E-03 -3.9409 0.95169E-04 -4.0215 0.83063E+00 -0.0806 6 HS- 0.22986E-02 -2.6385 0.19066E-02 -2.7197 0.82945E+00 -0.0812 7 Al+++ 0.13358E-28 -28.8743 0.29000E-29 -29.5376 0.21710E+00 -0.6633 8 H4SiO4 0.69589E-03 -3.1575 0.69589E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.16490E-06 -6.7828 0.82675E-07 -7.0826 0.50135E+00 -0.2999 10 Mg++ 0.25808E-10 -10.5882 0.12875E-10 -10.8903 0.49887E+00 -0.3020 11 Fe++ 0.71131E-13 -13.1479 0.35527E-13 -13.4494 0.49946E+00 -0.3015 12 K+ 0.17173E-03 -3.7652 0.14268E-03 -3.8456 0.83084E+00 -0.0805 13 Na+ 0.21795E-01 -1.6616 0.18071E-01 -1.7430 0.82915E+00 -0.0814 14 Mn++ 0.22919E-10 -10.6398 0.11457E-10 -10.9409 0.49991E+00 -0.3011 15 F- 0.10640E-05 -5.9731 0.88040E-06 -6.0553 0.82747E+00 -0.0822 16 HPO4-- 0.39196E-07 -7.4068 0.19812E-07 -7.7031 0.50545E+00 -0.2963 18 HSiO3- 0.96900E-02 -2.0137 0.80361E-02 -2.0950 0.82932E+00 -0.0813 19 Ca(HSiO3)+ 0.18207E-07 -7.7398 0.15131E-07 -7.8201 0.83104E+00 -0.0804 20 Mg(HSiO3)+ 0.35285E-11 -11.4524 0.29323E-11 -11.5328 0.83104E+00 -0.0804 21 NaHSiO3,aq 0.23488E-02 -2.6292 0.23488E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.72588E-16 -16.1391 0.60324E-16 -16.2195 0.83104E+00 -0.0804 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.49124E-05 -5.3087 0.40660E-05 -5.3908 0.82770E+00 -0.0821 26 CH4,aq 0.63957E-02 -2.1941 0.63809E-02 -2.1951 0.99768E+00 -0.0010 27 C2H6,aq 0.60242E-09 -9.2201 0.60102E-09 -9.2211 0.99768E+00 -0.0010 28 C3H8,aq 0.13100E-14 -14.8827 0.13070E-14 -14.8837 0.99768E+00 -0.0010 30 ethanol,aq 0.22111E-16 -16.6554 0.22060E-16 -16.6564 0.99768E+00 -0.0010 31 CO,aq 0.47853E-14 -14.3201 0.47853E-14 -14.3201 0.10000E+01 0.0000 32 CO2,aq 0.16485E-07 -7.7829 0.16446E-07 -7.7839 0.99768E+00 -0.0010 33 CO3-2 0.20387E-03 -3.6906 0.10279E-03 -3.9880 0.50421E+00 -0.2974 34 CaCO3,aq 0.10656E-06 -6.9724 0.10656E-06 -6.9724 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.24167E-09 -9.6168 0.20084E-09 -9.6971 0.83104E+00 -0.0804 36 CaCl+ 0.10935E-09 -9.9612 0.90876E-10 -10.0416 0.83104E+00 -0.0804 37 CaCl2,aq 0.14665E-13 -13.8337 0.14665E-13 -13.8337 0.10000E+01 0.0000 38 CaF+ 0.12788E-11 -11.8932 0.10627E-11 -11.9736 0.83104E+00 -0.0804 39 CaOH+ 0.87667E-07 -7.0572 0.72855E-07 -7.1375 0.83104E+00 -0.0804 40 CaSO4,aq 0.72510E-15 -15.1396 0.72510E-15 -15.1396 0.10000E+01 0.0000 41 HCl,aq 0.10065E-13 -13.9972 0.10065E-13 -13.9972 0.10000E+01 0.0000 45 HF,aq 0.48738E-12 -12.3121 0.48738E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17469E-18 -18.7577 0.14487E-18 -18.8390 0.82932E+00 -0.0813 48 FeCl+ 0.45961E-16 -16.3376 0.38195E-16 -16.4180 0.83104E+00 -0.0804 51 FeF+ 0.19233E-17 -17.7159 0.15984E-17 -17.7963 0.83104E+00 -0.0804 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17206E-10 -10.7643 0.14299E-10 -10.8447 0.83104E+00 -0.0804 55 HFeO2- 0.32935E-07 -7.4823 0.27313E-07 -7.5636 0.82932E+00 -0.0813 56 FeO+ 0.12060E-16 -16.9187 0.10022E-16 -16.9990 0.83104E+00 -0.0804 58 FeO2- 0.37808E-09 -9.4224 0.31355E-09 -9.5037 0.82932E+00 -0.0813 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11608E-04 -4.9352 0.11581E-04 -4.9362 0.99768E+00 -0.0010 61 KCl,aq 0.17564E-08 -8.7554 0.17564E-08 -8.7554 0.10000E+01 0.0000 63 KOH,aq 0.75340E-06 -6.1230 0.75340E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.73736E-13 -13.1323 0.61151E-13 -13.2136 0.82932E+00 -0.0813 65 MgCO3,aq 0.41595E-11 -11.3810 0.41595E-11 -11.3810 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.38456E-13 -13.4150 0.31958E-13 -13.4954 0.83104E+00 -0.0804 67 MgCl+ 0.15434E-13 -13.8115 0.12826E-13 -13.8919 0.83104E+00 -0.0804 68 MgF+ 0.73766E-15 -15.1321 0.61303E-15 -15.2125 0.83104E+00 -0.0804 69 MgOH+ 0.75543E-10 -10.1218 0.62779E-10 -10.2022 0.83104E+00 -0.0804 71 MnF+ 0.20445E-15 -15.6894 0.16990E-15 -15.7698 0.83104E+00 -0.0804 72 MnO,aq 0.18142E-08 -8.7413 0.18142E-08 -8.7413 0.10000E+01 0.0000 73 MnOH+ 0.51547E-09 -9.2878 0.42838E-09 -9.3682 0.83104E+00 -0.0804 74 MnO2-2 0.18258E-10 -10.7385 0.92059E-11 -11.0359 0.50421E+00 -0.2974 75 HMnO2- 0.19666E-09 -9.7063 0.16310E-09 -9.7876 0.82932E+00 -0.0813 78 MnCl+ 0.57665E-13 -13.2391 0.47922E-13 -13.3195 0.83104E+00 -0.0804 79 MnSO4,aq 0.91356E-19 -19.0393 0.91356E-19 -19.0393 0.10000E+01 0.0000 80 NaCl,aq 0.40678E-05 -5.3906 0.40678E-05 -5.3906 0.10000E+01 0.0000 81 NaF,aq 0.37248E-08 -8.4289 0.37248E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.96003E-04 -4.0177 0.96003E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.86311E-02 -2.0639 0.71439E-02 -2.1461 0.82770E+00 -0.0821 89 HPO3-2 0.14183E-14 -14.8482 0.71511E-15 -15.1456 0.50421E+00 -0.2974 91 H2PO3- 0.13983E-18 -18.8544 0.11596E-18 -18.9357 0.82932E+00 -0.0813 92 H3PO4,aq 0.90613E-18 -18.0428 0.90613E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.35601E-10 -10.4485 0.29555E-10 -10.5294 0.83017E+00 -0.0808 94 PO4-3 0.87304E-09 -9.0590 0.19989E-09 -9.6992 0.22896E+00 -0.6402 98 HP2O7-3 0.77818E-18 -18.1089 0.16914E-18 -18.7718 0.21735E+00 -0.6628 99 P2O7-4 0.72190E-17 -17.1415 0.49966E-18 -18.3013 0.69214E-01 -1.1598 100 H2S,aq 0.47762E-06 -6.3209 0.47652E-06 -6.3219 0.99768E+00 -0.0010 101 S2-2 0.13794E-10 -10.8603 0.69551E-11 -11.1577 0.50421E+00 -0.2974 102 S3-2 0.76466E-18 -18.1165 0.38555E-18 -18.4139 0.50421E+00 -0.2974 107 SO3-2 0.81176E-16 -16.0906 0.41571E-16 -16.3812 0.51211E+00 -0.2906 108 HSO3- 0.25381E-18 -18.5955 0.21049E-18 -18.6768 0.82932E+00 -0.0813 109 HSO4- 0.25874E-17 -17.5871 0.21525E-17 -17.6671 0.83192E+00 -0.0799 111 S2O3-2 0.30666E-18 -18.5133 0.15462E-18 -18.8107 0.50421E+00 -0.2974 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9687521E-10 -.2099288E-01 -.2111875E+02 0.0000 2 H2O 0.1000000E+01 0.5551136E+02 0.9981246E+06 0.0000 3 Cl- 0.8190130E-03 0.8230826E-03 0.2912446E+02 6.9242 4 SO4-- 0.5465175E-10 -.6398579E-02 -.6134720E+03 9.6257 5 HCO3- 0.1145739E-03 0.6714245E-02 0.4088941E+03 6.0707 6 HS- 0.2298640E-02 0.8697697E-02 0.2870953E+03 7.3725 7 Al+++ 0.1335778E-28 0.4912567E-05 0.1322927E+00 0.7391 8 H4SiO4 0.6958896E-03 0.1273472E-01 0.1221642E+04 -3.1575 9 Ca++ 0.1649047E-06 0.3776923E-06 0.1510795E-01 13.1018 10 Mg++ 0.2580775E-10 0.1090934E-09 0.2647163E-05 9.2942 11 Fe++ 0.7113123E-13 0.3354428E-07 0.1869733E-02 6.7350 12 K+ 0.1717289E-03 0.1724840E-03 0.6731461E+01 6.2466 13 Na+ 0.2179498E-01 0.2424385E-01 0.5562860E+03 8.3492 14 Mn++ 0.2291898E-10 0.2567575E-08 0.1407853E-03 9.2435 15 F- 0.1063968E-05 0.1067695E-05 0.2024493E-01 4.0369 16 HPO4-- 0.3919635E-07 0.4010500E-07 0.3841813E-02 12.4814 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278760E+02 -.1043711E-01 -.8277716E+02 0.0000000E+00 2 H2O -.7131137E+01 0.2759880E+02 -.3472993E+02 0.0000000E+00 3 Cl- 0.4092152E-03 0.4092152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1388121E+00 -.3181206E-02 0.1419933E+00 0.0000000E+00 5 HCO3- 0.3338147E-02 0.3338147E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1376691E+00 0.4324268E-02 -.1419933E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2442400E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6331371E-02 0.5205757E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1877788E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5423839E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1667734E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8575456E-04 0.1061485E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1205341E-01 0.6264324E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1276531E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1849600E-04 0.5308298E-06 0.1796517E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1993916E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1803E-13 Mass of aqueous solution: 0.498135E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0459900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.255 0.796 1640. 3.215 30.03 629.7 andradite 0.5680 -0.246 288.6 2.460 5.284 74.99 grossular 0.1375 -0.862 61.96 1.792 1.134 17.24 apatite-OH 0.9845E-02 -2.007 4.945 0.694 0.9053E-01 1.571 apatite-F 0.1797E-04 -4.746 0.9060E-02 -2.043 0.1659E-03 0.2830E-02 clinochlore 0.7071 -0.151 393.0 2.594 7.195 149.5 daphnite 0.2047 -0.689 146.1 2.165 2.674 44.26 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1744 -0.758 37.77 1.577 0.6914 11.54 hedenbergite 0.4523E-01 -1.345 11.22 1.050 0.2054 3.074 microcline 0.9344 -0.029 260.1 2.415 4.761 101.6 stilbite 3.223 0.508 2271. 3.356 41.58 1059. stilpnomelane-Fe 0.2542 -0.595 274.1 2.438 5.017 94.67 tr.625ac.25prg.125 0.7128E-01 -1.147 60.93 1.785 1.115 19.61 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1866E-01 0.1866E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.351168 g Volume = 2210.904907 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0459900 moles log = -1.3373 Original solution: 1000.0103000 g Original solution / Rock added: 21744.08 (Water/Rock Ratio), log = 4.3373 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 10.5006 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9940E-01 0.9636 0.1006E+01 0.1044E+01 CO2,gas 0.1710E-06 0.9798 0.1760E-05 0.1796E-05 CH4,gas 0.8992E+00 0.9948 0.9392E+01 0.9442E+01 H2,gas 0.1440E-02 1.0056 0.1520E-01 0.1512E-01 H2S,gas 0.1299E-05 0.9602 0.1310E-04 0.1364E-04 S2,gas 0.2653E-26 1.0000 0.2786E-25 0.2786E-25 CO,gas 0.6791E-12 1.0000 0.7131E-11 0.7131E-11 SO3,gas 0.6504E-47 1.0000 0.6830E-46 0.6830E-46 SO2,gas 0.3848E-26 1.0000 0.4041E-25 0.4041E-25 HF,gas 0.1140E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1691E-17 1.0000 0.1776E-16 0.1776E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.11 -7.45 -2.485 0.12727E+05 -5.755 3 CH4,gas 4.54 3.82 -0.73 -0.182 0.12400E+04 0.973 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.81 -6.58 -3.291 0.11238E+05 -4.883 6 S2,gas -7.34 -34.59 -27.25 -4.193 0.46535E+05 -25.555 7 CO,gas 3.21 -9.63 -12.85 -3.953 0.21934E+05 -11.147 8 SO3,gas 17.12 -30.74 -47.86 -11.966 0.81727E+05 -46.166 9 SO2,gas 0.83 -26.26 -27.09 -7.225 0.46260E+05 -25.394 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.26 -18.45 -9.225 0.31502E+05 -16.751 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80608E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93641E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28493E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -1.01 -1.98 -0.659 0.33781E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -1.01 -1.82 -0.608 0.31139E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68942E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65515E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.15 -2.05 -0.584 0.34929E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37135E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -5.15 -1.60 -0.458 0.27352E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82208E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36681E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91154E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 145 pyrite -21.25 -23.37 -2.12 -0.500 0.36280E+04 146 pyrrhotite -4.26 -6.08 -1.82 -0.606 0.31018E+04 147 pyrrhotiteFe0.875 -6.02 -7.47 -1.46 -0.536 0.24891E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.263 0.22411E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28673E+03 154 rhodochrosite -0.98 -4.87 -3.89 -1.298 0.66487E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23214E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.38 -4.77 -1.590 0.81456E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27807E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47061E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90670E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77502E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65445E+04 184 troilite-low -4.41 -6.08 -1.67 -0.555 0.28447E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60602E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.57 -2.59 -0.864 0.44233E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0459900 MOLES New total amount of reactant added: 0.0479900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8660E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0479900 Water: Moles liquid = 0.2760E+02 kg liquid = 0.4972E+00 Moles total = -.7129E+01 kg total = -.1284E+00 Activity = 0.9999 Stoichiometric ionic strength = .7381541E-02 Osmotic coef. = 0.9307 True ionic strength = .2226141E-01 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.4210E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.97239E-10 -10.0122 0.81149E-10 -10.0907 0.83453E+00 -0.0786 2 H2O 0.99988E+00 -0.0001 0.99988E+00 -0.0001 3 Cl- 0.84255E-03 -3.0744 0.69855E-03 -3.1558 0.82908E+00 -0.0814 4 SO4-- 0.56820E-10 -10.2455 0.28684E-10 -10.5424 0.50482E+00 -0.2969 5 HCO3- 0.11918E-03 -3.9238 0.98968E-04 -4.0045 0.83040E+00 -0.0807 6 HS- 0.23962E-02 -2.6205 0.19870E-02 -2.7018 0.82921E+00 -0.0813 7 Al+++ 0.13532E-28 -28.8686 0.29305E-29 -29.5331 0.21656E+00 -0.6644 8 H4SiO4 0.69589E-03 -3.1575 0.69589E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.16624E-06 -6.7793 0.83252E-07 -7.0796 0.50079E+00 -0.3003 10 Mg++ 0.26018E-10 -10.5847 0.12965E-10 -10.8872 0.49830E+00 -0.3025 11 Fe++ 0.71710E-13 -13.1444 0.35775E-13 -13.4464 0.49889E+00 -0.3020 12 K+ 0.17237E-03 -3.7635 0.14318E-03 -3.8441 0.83061E+00 -0.0806 13 Na+ 0.21877E-01 -1.6600 0.18134E-01 -1.7415 0.82891E+00 -0.0815 14 Mn++ 0.23110E-10 -10.6362 0.11540E-10 -10.9378 0.49934E+00 -0.3016 15 F- 0.10606E-05 -5.9745 0.87734E-06 -6.0568 0.82723E+00 -0.0824 16 HPO4-- 0.38967E-07 -7.4093 0.19674E-07 -7.7061 0.50490E+00 -0.2968 18 HSiO3- 0.96591E-02 -2.0151 0.80082E-02 -2.0965 0.82908E+00 -0.0814 19 Ca(HSiO3)+ 0.18275E-07 -7.7381 0.15183E-07 -7.8186 0.83081E+00 -0.0805 20 Mg(HSiO3)+ 0.35418E-11 -11.4508 0.29426E-11 -11.5313 0.83081E+00 -0.0805 21 NaHSiO3,aq 0.23488E-02 -2.6292 0.23488E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.72862E-16 -16.1375 0.60534E-16 -16.2180 0.83081E+00 -0.0805 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.48968E-05 -5.3101 0.40519E-05 -5.3923 0.82746E+00 -0.0823 26 CH4,aq 0.66738E-02 -2.1756 0.66586E-02 -2.1766 0.99773E+00 -0.0010 27 C2H6,aq 0.65598E-09 -9.1831 0.65449E-09 -9.1841 0.99773E+00 -0.0010 28 C3H8,aq 0.14886E-14 -14.8272 0.14852E-14 -14.8282 0.99773E+00 -0.0010 30 ethanol,aq 0.24077E-16 -16.6184 0.24022E-16 -16.6194 0.99773E+00 -0.0010 31 CO,aq 0.49937E-14 -14.3016 0.49937E-14 -14.3016 0.10000E+01 0.0000 32 CO2,aq 0.17202E-07 -7.7644 0.17163E-07 -7.7654 0.99773E+00 -0.0010 33 CO3-2 0.21151E-03 -3.6747 0.10653E-03 -3.9725 0.50365E+00 -0.2979 34 CaCO3,aq 0.11120E-06 -6.9539 0.11120E-06 -6.9539 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.25315E-09 -9.5966 0.21032E-09 -9.6771 0.83081E+00 -0.0805 36 CaCl+ 0.11328E-09 -9.9458 0.94114E-10 -10.0263 0.83081E+00 -0.0805 37 CaCl2,aq 0.15619E-13 -13.8063 0.15619E-13 -13.8063 0.10000E+01 0.0000 38 CaF+ 0.12836E-11 -11.8916 0.10664E-11 -11.9721 0.83081E+00 -0.0805 39 CaOH+ 0.87997E-07 -7.0555 0.73108E-07 -7.1360 0.83081E+00 -0.0805 40 CaSO4,aq 0.75829E-15 -15.1202 0.75829E-15 -15.1202 0.10000E+01 0.0000 41 HCl,aq 0.10387E-13 -13.9835 0.10387E-13 -13.9835 0.10000E+01 0.0000 45 HF,aq 0.48738E-12 -12.3121 0.48738E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17413E-18 -18.7591 0.14437E-18 -18.8405 0.82908E+00 -0.0814 48 FeCl+ 0.47612E-16 -16.3223 0.39556E-16 -16.4028 0.83081E+00 -0.0805 51 FeF+ 0.19306E-17 -17.7143 0.16039E-17 -17.7948 0.83081E+00 -0.0805 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17271E-10 -10.7627 0.14349E-10 -10.8432 0.83081E+00 -0.0805 55 HFeO2- 0.32829E-07 -7.4837 0.27218E-07 -7.5651 0.82908E+00 -0.0814 56 FeO+ 0.12105E-16 -16.9170 0.10057E-16 -16.9975 0.83081E+00 -0.0805 58 FeO2- 0.37688E-09 -9.4238 0.31246E-09 -9.5052 0.82908E+00 -0.0814 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11607E-04 -4.9353 0.11581E-04 -4.9363 0.99773E+00 -0.0010 61 KCl,aq 0.18127E-08 -8.7417 0.18127E-08 -8.7417 0.10000E+01 0.0000 63 KOH,aq 0.75339E-06 -6.1230 0.75339E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.76865E-13 -13.1143 0.63727E-13 -13.1957 0.82908E+00 -0.0814 65 MgCO3,aq 0.43406E-11 -11.3625 0.43406E-11 -11.3625 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.40281E-13 -13.3949 0.33466E-13 -13.4754 0.83081E+00 -0.0805 67 MgCl+ 0.15988E-13 -13.7962 0.13283E-13 -13.8767 0.83081E+00 -0.0805 68 MgF+ 0.74044E-15 -15.1305 0.61516E-15 -15.2110 0.83081E+00 -0.0805 69 MgOH+ 0.75827E-10 -10.1202 0.62998E-10 -10.2007 0.83081E+00 -0.0805 71 MnF+ 0.20526E-15 -15.6877 0.17053E-15 -15.7682 0.83081E+00 -0.0805 72 MnO,aq 0.18146E-08 -8.7412 0.18146E-08 -8.7412 0.10000E+01 0.0000 73 MnOH+ 0.51752E-09 -9.2861 0.42996E-09 -9.3666 0.83081E+00 -0.0805 74 MnO2-2 0.18155E-10 -10.7410 0.91438E-11 -11.0389 0.50365E+00 -0.2979 75 HMnO2- 0.19607E-09 -9.7076 0.16256E-09 -9.7890 0.82908E+00 -0.0814 78 MnCl+ 0.59748E-13 -13.2237 0.49639E-13 -13.3042 0.83081E+00 -0.0805 79 MnSO4,aq 0.95557E-19 -19.0197 0.95557E-19 -19.0197 0.10000E+01 0.0000 80 NaCl,aq 0.41980E-05 -5.3770 0.41980E-05 -5.3770 0.10000E+01 0.0000 81 NaF,aq 0.37248E-08 -8.4289 0.37248E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.96001E-04 -4.0177 0.96001E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.86036E-02 -2.0653 0.71191E-02 -2.1476 0.82746E+00 -0.0823 89 HPO3-2 0.14100E-14 -14.8508 0.71015E-15 -15.1487 0.50365E+00 -0.2979 91 H2PO3- 0.13938E-18 -18.8558 0.11556E-18 -18.9372 0.82908E+00 -0.0814 92 H3PO4,aq 0.90613E-18 -18.0428 0.90613E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.35487E-10 -10.4499 0.29452E-10 -10.5309 0.82994E+00 -0.0810 94 PO4-3 0.86601E-09 -9.0625 0.19781E-09 -9.7037 0.22842E+00 -0.6413 98 HP2O7-3 0.77204E-18 -18.1124 0.16738E-18 -18.7763 0.21680E+00 -0.6639 99 P2O7-4 0.71504E-17 -17.1457 0.49276E-18 -18.3074 0.68913E-01 -1.1617 100 H2S,aq 0.49946E-06 -6.3015 0.49833E-06 -6.3025 0.99773E+00 -0.0010 101 S2-2 0.14998E-10 -10.8240 0.75537E-11 -11.1218 0.50365E+00 -0.2979 102 S3-2 0.86945E-18 -18.0608 0.43790E-18 -18.3586 0.50365E+00 -0.2979 107 SO3-2 0.84393E-16 -16.0737 0.43173E-16 -16.3648 0.51157E+00 -0.2911 108 HSO3- 0.26458E-18 -18.5774 0.21936E-18 -18.6588 0.82908E+00 -0.0814 109 HSO4- 0.26971E-17 -17.5691 0.22432E-17 -17.6491 0.83169E+00 -0.0800 111 S2O3-2 0.33342E-18 -18.4770 0.16793E-18 -18.7749 0.50365E+00 -0.2979 Charge balance for all species = -.1742E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9723863E-10 -.2094199E-01 -.2106738E+02 0.0000 2 H2O 0.1000000E+01 0.5551164E+02 0.9981214E+06 0.0000 3 Cl- 0.8425547E-03 0.8467547E-03 0.2996184E+02 6.9349 4 SO4-- 0.5681962E-10 -.6676661E-02 -.6401282E+03 9.6391 5 HCO3- 0.1191807E-03 0.7004575E-02 0.4265716E+03 6.0862 6 HS- 0.2396195E-02 0.9073356E-02 0.2994927E+03 7.3889 7 Al+++ 0.1353207E-28 0.4896944E-05 0.1318709E+00 0.7391 8 H4SiO4 0.6958857E-03 0.1270378E-01 0.1218664E+04 -3.1575 9 Ca++ 0.1662431E-06 0.3840842E-06 0.1536351E-01 13.1018 10 Mg++ 0.2601762E-10 0.1097848E-09 0.2663916E-05 9.2942 11 Fe++ 0.7170971E-13 0.3343794E-07 0.1863791E-02 6.7350 12 K+ 0.1723731E-03 0.1731283E-03 0.6756547E+01 6.2466 13 Na+ 0.2187688E-01 0.2432584E-01 0.5581627E+03 8.3492 14 Mn++ 0.2310981E-10 0.2569468E-08 0.1408880E-03 9.2436 15 F- 0.1060578E-05 0.1064304E-05 0.2018048E-01 4.0339 16 HPO4-- 0.3896740E-07 0.3986890E-07 0.3819164E-02 12.4753 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278738E+02 -.1041257E-01 -.8277697E+02 0.0000000E+00 2 H2O -.7129499E+01 0.2760096E+02 -.3473046E+02 0.0000000E+00 3 Cl- 0.4210152E-03 0.4210152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1388217E+00 -.3319705E-02 0.1421414E+00 0.0000000E+00 5 HCO3- 0.3482747E-02 0.3482747E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1376300E+00 0.4511366E-02 -.1421414E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2434811E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6316451E-02 0.5205759E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1909706E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5458611E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1662569E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8608116E-04 0.1061485E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1209506E-01 0.6264282E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1277566E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1929600E-04 0.5291831E-06 0.1876682E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1982323E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.8833E-14 Mass of aqueous solution: 0.498175E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0479900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.255 0.796 1640. 3.215 30.03 629.7 andradite 0.5686 -0.245 288.9 2.461 5.290 75.07 grossular 0.1377 -0.861 62.02 1.793 1.135 17.26 apatite-OH 0.9844E-02 -2.007 4.945 0.694 0.9052E-01 1.571 apatite-F 0.1877E-04 -4.727 0.9464E-02 -2.024 0.1733E-03 0.2957E-02 clinochlore 0.7070 -0.151 392.9 2.594 7.194 149.5 daphnite 0.2047 -0.689 146.0 2.164 2.674 44.25 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1705 -0.768 36.93 1.567 0.6761 11.29 hedenbergite 0.4423E-01 -1.354 10.97 1.040 0.2009 3.006 microcline 0.9345 -0.029 260.1 2.415 4.762 101.6 stilbite 3.223 0.508 2271. 3.356 41.58 1059. stilpnomelane-Fe 0.2539 -0.595 273.7 2.437 5.011 94.55 tr.625ac.25prg.125 0.7254E-01 -1.139 62.00 1.792 1.135 19.96 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1866E-01 0.1866E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.351687 g Volume = 2210.910445 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0479900 moles log = -1.3188 Original solution: 1000.0103000 g Original solution / Rock added: 20837.89 (Water/Rock Ratio), log = 4.3189 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 10.9151 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9568E-01 0.9631 0.1006E+01 0.1044E+01 CO2,gas 0.1718E-06 0.9791 0.1836E-05 0.1875E-05 CH4,gas 0.9029E+00 0.9945 0.9801E+01 0.9856E+01 H2,gas 0.1385E-02 1.0058 0.1520E-01 0.1512E-01 H2S,gas 0.1309E-05 0.9587 0.1370E-04 0.1429E-04 S2,gas 0.2791E-26 1.0000 0.3047E-25 0.3047E-25 CO,gas 0.6818E-12 1.0000 0.7442E-11 0.7442E-11 SO3,gas 0.6544E-47 1.0000 0.7143E-46 0.7143E-46 SO2,gas 0.3871E-26 1.0000 0.4226E-25 0.4226E-25 HF,gas 0.1096E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1679E-17 1.0000 0.1833E-16 0.1833E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 0.42463E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.10 -7.44 -2.478 0.12695E+05 -5.736 3 CH4,gas 4.54 3.84 -0.71 -0.177 0.12084E+04 0.991 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.79 -6.56 -3.281 0.11205E+05 -4.863 6 S2,gas -7.34 -34.55 -27.22 -4.187 0.46469E+05 -25.516 7 CO,gas 3.21 -9.61 -12.83 -3.947 0.21902E+05 -11.128 8 SO3,gas 17.12 -30.72 -47.85 -11.961 0.81694E+05 -46.146 9 SO2,gas 0.83 -26.24 -27.07 -7.219 0.46227E+05 -25.374 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.25 -18.44 -9.218 0.31479E+05 -16.737 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80604E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93642E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28493E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -0.99 -1.96 -0.653 0.33465E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -0.99 -1.81 -0.602 0.30823E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68942E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65513E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -5.13 -2.03 -0.579 0.34613E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37136E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -5.13 -1.58 -0.452 0.27035E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82207E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36681E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91153E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -23.33 -2.09 -0.491 0.35616E+04 146 pyrrhotite -4.26 -6.06 -1.80 -0.599 0.30687E+04 147 pyrrhotiteFe0.875 -6.02 -7.46 -1.44 -0.529 0.24559E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22410E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28672E+03 154 rhodochrosite -0.98 -4.85 -3.88 -1.292 0.66169E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23212E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.36 -4.75 -1.584 0.81140E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27807E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47058E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90670E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77502E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65445E+04 184 troilite-low -4.41 -6.06 -1.65 -0.549 0.28115E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34153E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60602E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.55 -2.57 -0.857 0.43900E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0479900 MOLES New total amount of reactant added: 0.0499900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8660E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0499900 Water: Moles liquid = 0.2760E+02 kg liquid = 0.4972E+00 Moles total = -.7128E+01 kg total = -.1284E+00 Activity = 0.9999 Stoichiometric ionic strength = .7211348E-02 Osmotic coef. = 0.9314 True ionic strength = .2235160E-01 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.4328E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.97603E-10 -10.0105 0.81431E-10 -10.0892 0.83431E+00 -0.0787 2 H2O 0.99987E+00 -0.0001 0.99987E+00 -0.0001 3 Cl- 0.86609E-03 -3.0624 0.71786E-03 -3.1440 0.82885E+00 -0.0815 4 SO4-- 0.58976E-10 -10.2293 0.29739E-10 -10.5267 0.50426E+00 -0.2973 5 HCO3- 0.12376E-03 -3.9074 0.10274E-03 -3.9883 0.83017E+00 -0.0808 6 HS- 0.24937E-02 -2.6031 0.20673E-02 -2.6846 0.82898E+00 -0.0815 7 Al+++ 0.13708E-28 -28.8630 0.29612E-29 -29.5285 0.21602E+00 -0.6655 8 H4SiO4 0.69588E-03 -3.1575 0.69588E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.16759E-06 -6.7758 0.83832E-07 -7.0766 0.50022E+00 -0.3008 10 Mg++ 0.26229E-10 -10.5812 0.13055E-10 -10.8842 0.49773E+00 -0.3030 11 Fe++ 0.72291E-13 -13.1409 0.36025E-13 -13.4434 0.49832E+00 -0.3025 12 K+ 0.17302E-03 -3.7619 0.14367E-03 -3.8426 0.83038E+00 -0.0807 13 Na+ 0.21959E-01 -1.6584 0.18197E-01 -1.7400 0.82868E+00 -0.0816 14 Mn++ 0.23302E-10 -10.6326 0.11622E-10 -10.9347 0.49877E+00 -0.3021 15 F- 0.10572E-05 -5.9758 0.87430E-06 -6.0583 0.82699E+00 -0.0825 16 HPO4-- 0.38740E-07 -7.4118 0.19538E-07 -7.7091 0.50434E+00 -0.2973 18 HSiO3- 0.96284E-02 -2.0164 0.79805E-02 -2.0980 0.82885E+00 -0.0815 19 Ca(HSiO3)+ 0.18344E-07 -7.7365 0.15236E-07 -7.8171 0.83057E+00 -0.0806 20 Mg(HSiO3)+ 0.35551E-11 -11.4491 0.29528E-11 -11.5298 0.83057E+00 -0.0806 21 NaHSiO3,aq 0.23487E-02 -2.6292 0.23487E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.73136E-16 -16.1359 0.60745E-16 -16.2165 0.83057E+00 -0.0806 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.48813E-05 -5.3115 0.40379E-05 -5.3938 0.82722E+00 -0.0824 26 CH4,aq 0.69519E-02 -2.1579 0.69365E-02 -2.1589 0.99779E+00 -0.0010 27 C2H6,aq 0.71184E-09 -9.1476 0.71026E-09 -9.1486 0.99779E+00 -0.0010 28 C3H8,aq 0.16828E-14 -14.7740 0.16791E-14 -14.7749 0.99779E+00 -0.0010 30 ethanol,aq 0.26127E-16 -16.5829 0.26070E-16 -16.5839 0.99779E+00 -0.0010 31 CO,aq 0.52021E-14 -14.2838 0.52021E-14 -14.2838 0.10000E+01 0.0000 32 CO2,aq 0.17919E-07 -7.7467 0.17879E-07 -7.7477 0.99779E+00 -0.0010 33 CO3-2 0.21905E-03 -3.6595 0.11020E-03 -3.9578 0.50310E+00 -0.2983 34 CaCO3,aq 0.11584E-06 -6.9361 0.11584E-06 -6.9361 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.26470E-09 -9.5772 0.21986E-09 -9.6579 0.83057E+00 -0.0806 36 CaCl+ 0.11726E-09 -9.9309 0.97389E-10 -10.0115 0.83057E+00 -0.0806 37 CaCl2,aq 0.16609E-13 -13.7796 0.16609E-13 -13.7796 0.10000E+01 0.0000 38 CaF+ 0.12884E-11 -11.8900 0.10701E-11 -11.9706 0.83057E+00 -0.0806 39 CaOH+ 0.88327E-07 -7.0539 0.73362E-07 -7.1345 0.83057E+00 -0.0806 40 CaSO4,aq 0.79168E-15 -15.1015 0.79168E-15 -15.1015 0.10000E+01 0.0000 41 HCl,aq 0.10712E-13 -13.9701 0.10712E-13 -13.9701 0.10000E+01 0.0000 45 HF,aq 0.48738E-12 -12.3121 0.48738E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17357E-18 -18.7605 0.14387E-18 -18.8420 0.82885E+00 -0.0815 48 FeCl+ 0.49283E-16 -16.3073 0.40933E-16 -16.3879 0.83057E+00 -0.0806 51 FeF+ 0.19378E-17 -17.7127 0.16095E-17 -17.7933 0.83057E+00 -0.0806 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17336E-10 -10.7611 0.14399E-10 -10.8417 0.83057E+00 -0.0806 55 HFeO2- 0.32725E-07 -7.4851 0.27124E-07 -7.5666 0.82885E+00 -0.0815 56 FeO+ 0.12151E-16 -16.9154 0.10092E-16 -16.9960 0.83057E+00 -0.0806 58 FeO2- 0.37568E-09 -9.4252 0.31138E-09 -9.5067 0.82885E+00 -0.0815 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11607E-04 -4.9353 0.11581E-04 -4.9363 0.99779E+00 -0.0010 61 KCl,aq 0.18692E-08 -8.7283 0.18692E-08 -8.7283 0.10000E+01 0.0000 63 KOH,aq 0.75337E-06 -6.1230 0.75337E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.79993E-13 -13.0970 0.66301E-13 -13.1785 0.82885E+00 -0.0815 65 MgCO3,aq 0.45218E-11 -11.3447 0.45218E-11 -11.3447 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.42120E-13 -13.3755 0.34984E-13 -13.4561 0.83057E+00 -0.0806 67 MgCl+ 0.16550E-13 -13.7812 0.13746E-13 -13.8618 0.83057E+00 -0.0806 68 MgF+ 0.74321E-15 -15.1289 0.61729E-15 -15.2095 0.83057E+00 -0.0806 69 MgOH+ 0.76112E-10 -10.1185 0.63217E-10 -10.1992 0.83057E+00 -0.0806 71 MnF+ 0.20607E-15 -15.6860 0.17115E-15 -15.7666 0.83057E+00 -0.0806 72 MnO,aq 0.18149E-08 -8.7411 0.18149E-08 -8.7411 0.10000E+01 0.0000 73 MnOH+ 0.51956E-09 -9.2844 0.43153E-09 -9.3650 0.83057E+00 -0.0806 74 MnO2-2 0.18053E-10 -10.7435 0.90822E-11 -11.0418 0.50310E+00 -0.2983 75 HMnO2- 0.19549E-09 -9.7089 0.16203E-09 -9.7904 0.82885E+00 -0.0815 78 MnCl+ 0.61857E-13 -13.2086 0.51377E-13 -13.2892 0.83057E+00 -0.0806 79 MnSO4,aq 0.99784E-19 -19.0009 0.99784E-19 -19.0009 0.10000E+01 0.0000 80 NaCl,aq 0.43290E-05 -5.3636 0.43290E-05 -5.3636 0.10000E+01 0.0000 81 NaF,aq 0.37247E-08 -8.4289 0.37247E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.95999E-04 -4.0177 0.95999E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.85762E-02 -2.0667 0.70944E-02 -2.1491 0.82722E+00 -0.0824 89 HPO3-2 0.14018E-14 -14.8533 0.70524E-15 -15.1517 0.50310E+00 -0.2983 91 H2PO3- 0.13894E-18 -18.8572 0.11516E-18 -18.9387 0.82885E+00 -0.0815 92 H3PO4,aq 0.90613E-18 -18.0428 0.90613E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.35374E-10 -10.4513 0.29350E-10 -10.5324 0.82970E+00 -0.0811 94 PO4-3 0.85905E-09 -9.0660 0.19576E-09 -9.7083 0.22789E+00 -0.6423 98 HP2O7-3 0.76596E-18 -18.1158 0.16565E-18 -18.7808 0.21626E+00 -0.6650 99 P2O7-4 0.70826E-17 -17.1498 0.48597E-18 -18.3134 0.68614E-01 -1.1636 100 H2S,aq 0.52142E-06 -6.2828 0.52027E-06 -6.2838 0.99779E+00 -0.0010 101 S2-2 0.16252E-10 -10.7891 0.81766E-11 -11.0874 0.50310E+00 -0.2983 102 S3-2 0.98367E-18 -18.0071 0.49488E-18 -18.3055 0.50310E+00 -0.2983 107 SO3-2 0.87591E-16 -16.0575 0.44762E-16 -16.3491 0.51103E+00 -0.2916 108 HSO3- 0.27535E-18 -18.5601 0.22822E-18 -18.6416 0.82885E+00 -0.0815 109 HSO4- 0.28069E-17 -17.5518 0.23338E-17 -17.6319 0.83146E+00 -0.0802 111 S2O3-2 0.36131E-18 -18.4421 0.18177E-18 -18.7405 0.50310E+00 -0.2983 Charge balance for all species = -.1740E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9760251E-10 -.2089134E-01 -.2101624E+02 0.0000 2 H2O 0.1000000E+01 0.5551192E+02 0.9981182E+06 0.0000 3 Cl- 0.8660923E-03 0.8704233E-03 0.3079908E+02 6.9452 4 SO4-- 0.5897561E-10 -.6954819E-02 -.6667912E+03 9.6518 5 HCO3- 0.1237598E-03 0.7294863E-02 0.4442461E+03 6.1010 6 HS- 0.2493736E-02 0.9449076E-02 0.3118918E+03 7.4046 7 Al+++ 0.1370819E-28 0.4881409E-05 0.1314515E+00 0.7391 8 H4SiO4 0.6958818E-03 0.1267302E-01 0.1215702E+04 -3.1575 9 Ca++ 0.1675891E-06 0.3904861E-06 0.1561945E-01 13.1018 10 Mg++ 0.2622867E-10 0.1104769E-09 0.2680689E-05 9.2942 11 Fe++ 0.7229144E-13 0.3333221E-07 0.1857882E-02 6.7350 12 K+ 0.1730181E-03 0.1737733E-03 0.6781663E+01 6.2466 13 Na+ 0.2195888E-01 0.2440793E-01 0.5600417E+03 8.3492 14 Mn++ 0.2330175E-10 0.2571370E-08 0.1409911E-03 9.2437 15 F- 0.1057207E-05 0.1060933E-05 0.2011639E-01 4.0309 16 HPO4-- 0.3874034E-07 0.3963476E-07 0.3796704E-02 12.4693 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278716E+02 -.1038815E-01 -.8277678E+02 0.0000000E+00 2 H2O -.7127862E+01 0.2760312E+02 -.3473099E+02 0.0000000E+00 3 Cl- 0.4328152E-03 0.4328152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1388312E+00 -.3458261E-02 0.1422895E+00 0.0000000E+00 5 HCO3- 0.3627347E-02 0.3627347E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1375910E+00 0.4698523E-02 -.1422895E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2427265E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6301616E-02 0.5205760E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1941679E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5493428E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1657433E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8640821E-04 0.1061485E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1213676E-01 0.6264240E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1278605E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2009600E-04 0.5275456E-06 0.1956845E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1970826E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1119E-13 Mass of aqueous solution: 0.498216E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0499900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.255 0.796 1640. 3.215 30.03 629.6 andradite 0.5692 -0.245 289.2 2.461 5.295 75.15 grossular 0.1378 -0.861 62.09 1.793 1.137 17.28 apatite-OH 0.9843E-02 -2.007 4.944 0.694 0.9052E-01 1.571 apatite-F 0.1957E-04 -4.708 0.9869E-02 -2.006 0.1807E-03 0.3083E-02 clinochlore 0.7068 -0.151 392.9 2.594 7.192 149.4 daphnite 0.2046 -0.689 146.0 2.164 2.673 44.25 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1667 -0.778 36.10 1.557 0.6608 11.03 hedenbergite 0.4323E-01 -1.364 10.73 1.030 0.1964 2.938 microcline 0.9347 -0.029 260.2 2.415 4.763 101.6 stilbite 3.223 0.508 2271. 3.356 41.58 1059. stilpnomelane-Fe 0.2536 -0.596 273.4 2.437 5.005 94.44 tr.625ac.25prg.125 0.7380E-01 -1.132 63.08 1.800 1.155 20.30 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1867E-01 0.1867E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.352201 g Volume = 2210.915985 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0499900 moles log = -1.3011 Original solution: 1000.0103000 g Original solution / Rock added: 20004.21 (Water/Rock Ratio), log = 4.3011 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 11.3301 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9222E-01 0.9626 0.1006E+01 0.1045E+01 CO2,gas 0.1726E-06 0.9784 0.1913E-05 0.1955E-05 CH4,gas 0.9064E+00 0.9942 0.1021E+02 0.1027E+02 H2,gas 0.1334E-02 1.0061 0.1520E-01 0.1511E-01 H2S,gas 0.1319E-05 0.9572 0.1430E-04 0.1494E-04 S2,gas 0.2931E-26 1.0000 0.3321E-25 0.3321E-25 CO,gas 0.6842E-12 1.0000 0.7752E-11 0.7752E-11 SO3,gas 0.6582E-47 1.0000 0.7457E-46 0.7457E-46 SO2,gas 0.3894E-26 1.0000 0.4412E-25 0.4412E-25 HF,gas 0.1056E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1668E-17 1.0000 0.1890E-16 0.1890E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.08 -7.42 -2.472 0.12665E+05 -5.718 3 CH4,gas 4.54 3.85 -0.69 -0.172 0.11781E+04 1.009 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.77 -6.54 -3.272 0.11173E+05 -4.845 6 S2,gas -7.34 -34.51 -27.18 -4.181 0.46405E+05 -25.479 7 CO,gas 3.21 -9.59 -12.81 -3.941 0.21872E+05 -11.111 8 SO3,gas 17.12 -30.71 -47.83 -11.957 0.81662E+05 -46.127 9 SO2,gas 0.83 -26.22 -27.05 -7.214 0.46195E+05 -25.355 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.23 -18.42 -9.211 0.31456E+05 -16.724 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80599E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93642E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28493E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -0.98 -1.94 -0.647 0.33162E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -0.98 -1.79 -0.596 0.30520E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68942E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65512E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -5.11 -2.01 -0.574 0.34310E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37136E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -5.11 -1.57 -0.447 0.26732E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28621E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82205E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36681E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91153E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -23.30 -2.05 -0.482 0.34977E+04 146 pyrrhotite -4.26 -6.04 -1.78 -0.593 0.30367E+04 147 pyrrhotiteFe0.875 -6.02 -7.44 -1.42 -0.522 0.24239E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22408E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28672E+03 154 rhodochrosite -0.98 -4.83 -3.86 -1.286 0.65865E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23211E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.34 -4.73 -1.578 0.80837E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27808E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47055E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90670E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77502E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65445E+04 184 troilite-low -4.41 -6.04 -1.63 -0.543 0.27795E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60602E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.53 -2.55 -0.851 0.43579E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0499900 MOLES New total amount of reactant added: 0.0519900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8659E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0519900 Water: Moles liquid = 0.2760E+02 kg liquid = 0.4973E+00 Moles total = -.7126E+01 kg total = -.1284E+00 Activity = 0.9999 Stoichiometric ionic strength = .7041069E-02 Osmotic coef. = 0.9322 True ionic strength = .2244182E-01 Chg. balance for total moles = -.8659E-10 Max. difference allowed = 0.4446E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.97967E-10 -10.0089 0.81713E-10 -10.0877 0.83409E+00 -0.0788 2 H2O 0.99987E+00 -0.0001 0.99987E+00 -0.0001 3 Cl- 0.88963E-03 -3.0508 0.73715E-03 -3.1324 0.82861E+00 -0.0816 4 SO4-- 0.61120E-10 -10.2138 0.30787E-10 -10.5116 0.50371E+00 -0.2978 5 HCO3- 0.12831E-03 -3.8917 0.10649E-03 -3.9727 0.82994E+00 -0.0810 6 HS- 0.25913E-02 -2.5865 0.21475E-02 -2.6681 0.82874E+00 -0.0816 7 Al+++ 0.13886E-28 -28.8574 0.29921E-29 -29.5240 0.21548E+00 -0.6666 8 H4SiO4 0.69588E-03 -3.1575 0.69588E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.16894E-06 -6.7723 0.84415E-07 -7.0736 0.49966E+00 -0.3013 10 Mg++ 0.26441E-10 -10.5777 0.13146E-10 -10.8812 0.49717E+00 -0.3035 11 Fe++ 0.72876E-13 -13.1374 0.36275E-13 -13.4404 0.49776E+00 -0.3030 12 K+ 0.17366E-03 -3.7603 0.14417E-03 -3.8411 0.83015E+00 -0.0808 13 Na+ 0.22041E-01 -1.6568 0.18260E-01 -1.7385 0.82844E+00 -0.0817 14 Mn++ 0.23495E-10 -10.6290 0.11705E-10 -10.9316 0.49821E+00 -0.3026 15 F- 0.10539E-05 -5.9772 0.87127E-06 -6.0598 0.82675E+00 -0.0826 16 HPO4-- 0.38515E-07 -7.4144 0.19404E-07 -7.7121 0.50379E+00 -0.2977 18 HSiO3- 0.95978E-02 -2.0178 0.79529E-02 -2.0995 0.82861E+00 -0.0816 19 Ca(HSiO3)+ 0.18413E-07 -7.7349 0.15289E-07 -7.8156 0.83034E+00 -0.0807 20 Mg(HSiO3)+ 0.35684E-11 -11.4475 0.29630E-11 -11.5283 0.83034E+00 -0.0807 21 NaHSiO3,aq 0.23487E-02 -2.6292 0.23487E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.73411E-16 -16.1342 0.60956E-16 -16.2150 0.83034E+00 -0.0807 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.48658E-05 -5.3128 0.40239E-05 -5.3954 0.82698E+00 -0.0825 26 CH4,aq 0.72301E-02 -2.1409 0.72145E-02 -2.1418 0.99784E+00 -0.0009 27 C2H6,aq 0.77000E-09 -9.1135 0.76834E-09 -9.1144 0.99784E+00 -0.0009 28 C3H8,aq 0.18933E-14 -14.7228 0.18892E-14 -14.7237 0.99784E+00 -0.0009 30 ethanol,aq 0.28262E-16 -16.5488 0.28201E-16 -16.5497 0.99784E+00 -0.0009 31 CO,aq 0.54107E-14 -14.2667 0.54107E-14 -14.2667 0.10000E+01 0.0000 32 CO2,aq 0.18636E-07 -7.7296 0.18596E-07 -7.7306 0.99784E+00 -0.0009 33 CO3-2 0.22651E-03 -3.6449 0.11383E-03 -3.9437 0.50255E+00 -0.2988 34 CaCO3,aq 0.12049E-06 -6.9191 0.12049E-06 -6.9191 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.27635E-09 -9.5585 0.22946E-09 -9.6393 0.83034E+00 -0.0807 36 CaCl+ 0.12128E-09 -9.9162 0.10070E-09 -9.9970 0.83034E+00 -0.0807 37 CaCl2,aq 0.17636E-13 -13.7536 0.17636E-13 -13.7536 0.10000E+01 0.0000 38 CaF+ 0.12932E-11 -11.8883 0.10738E-11 -11.9691 0.83034E+00 -0.0807 39 CaOH+ 0.88657E-07 -7.0523 0.73616E-07 -7.1330 0.83034E+00 -0.0807 40 CaSO4,aq 0.82526E-15 -15.0834 0.82526E-15 -15.0834 0.10000E+01 0.0000 41 HCl,aq 0.11038E-13 -13.9571 0.11038E-13 -13.9571 0.10000E+01 0.0000 45 HF,aq 0.48738E-12 -12.3121 0.48738E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17302E-18 -18.7619 0.14337E-18 -18.8435 0.82861E+00 -0.0816 48 FeCl+ 0.50973E-16 -16.2927 0.42325E-16 -16.3734 0.83034E+00 -0.0807 51 FeF+ 0.19451E-17 -17.7111 0.16151E-17 -17.7918 0.83034E+00 -0.0807 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17401E-10 -10.7594 0.14449E-10 -10.8402 0.83034E+00 -0.0807 55 HFeO2- 0.32621E-07 -7.4865 0.27030E-07 -7.5682 0.82861E+00 -0.0816 56 FeO+ 0.12196E-16 -16.9138 0.10127E-16 -16.9945 0.83034E+00 -0.0807 58 FeO2- 0.37449E-09 -9.4266 0.31030E-09 -9.5082 0.82861E+00 -0.0816 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11606E-04 -4.9353 0.11581E-04 -4.9363 0.99784E+00 -0.0009 61 KCl,aq 0.19261E-08 -8.7153 0.19261E-08 -8.7153 0.10000E+01 0.0000 63 KOH,aq 0.75336E-06 -6.1230 0.75336E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.83120E-13 -13.0803 0.68874E-13 -13.1619 0.82861E+00 -0.0816 65 MgCO3,aq 0.47030E-11 -11.3276 0.47030E-11 -11.3276 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.43973E-13 -13.3568 0.36513E-13 -13.4376 0.83034E+00 -0.0807 67 MgCl+ 0.17117E-13 -13.7666 0.14213E-13 -13.8473 0.83034E+00 -0.0807 68 MgF+ 0.74599E-15 -15.1273 0.61943E-15 -15.2080 0.83034E+00 -0.0807 69 MgOH+ 0.76397E-10 -10.1169 0.63435E-10 -10.1977 0.83034E+00 -0.0807 71 MnF+ 0.20688E-15 -15.6843 0.17178E-15 -15.7650 0.83034E+00 -0.0807 72 MnO,aq 0.18153E-08 -8.7411 0.18153E-08 -8.7411 0.10000E+01 0.0000 73 MnOH+ 0.52161E-09 -9.2827 0.43311E-09 -9.3634 0.83034E+00 -0.0807 74 MnO2-2 0.17951E-10 -10.7459 0.90213E-11 -11.0447 0.50255E+00 -0.2988 75 HMnO2- 0.19490E-09 -9.7102 0.16150E-09 -9.7918 0.82861E+00 -0.0816 78 MnCl+ 0.63991E-13 -13.1939 0.53135E-13 -13.2746 0.83034E+00 -0.0807 79 MnSO4,aq 0.10404E-18 -18.9828 0.10404E-18 -18.9828 0.10000E+01 0.0000 80 NaCl,aq 0.44607E-05 -5.3506 0.44607E-05 -5.3506 0.10000E+01 0.0000 81 NaF,aq 0.37246E-08 -8.4289 0.37246E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.95997E-04 -4.0177 0.95997E-04 -4.0177 0.10000E+01 0.0000 84 OH- 0.85490E-02 -2.0681 0.70698E-02 -2.1506 0.82698E+00 -0.0825 89 HPO3-2 0.13936E-14 -14.8558 0.70037E-15 -15.1547 0.50255E+00 -0.2988 91 H2PO3- 0.13850E-18 -18.8585 0.11476E-18 -18.9402 0.82861E+00 -0.0816 92 H3PO4,aq 0.90613E-18 -18.0428 0.90613E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.35262E-10 -10.4527 0.29249E-10 -10.5339 0.82947E+00 -0.0812 94 PO4-3 0.85216E-09 -9.0695 0.19374E-09 -9.7128 0.22735E+00 -0.6433 98 HP2O7-3 0.75995E-18 -18.1192 0.16394E-18 -18.7853 0.21572E+00 -0.6661 99 P2O7-4 0.70157E-17 -17.1539 0.47929E-18 -18.3194 0.68317E-01 -1.1655 100 H2S,aq 0.54351E-06 -6.2648 0.54234E-06 -6.2657 0.99784E+00 -0.0009 101 S2-2 0.17558E-10 -10.7555 0.88237E-11 -11.0544 0.50255E+00 -0.2988 102 S3-2 0.11078E-17 -17.9556 0.55670E-18 -18.2544 0.50255E+00 -0.2988 107 SO3-2 0.90772E-16 -16.0420 0.46338E-16 -16.3341 0.51049E+00 -0.2920 108 HSO3- 0.28612E-18 -18.5435 0.23708E-18 -18.6251 0.82861E+00 -0.0816 109 HSO4- 0.29167E-17 -17.5351 0.24244E-17 -17.6154 0.83123E+00 -0.0803 111 S2O3-2 0.39033E-18 -18.4086 0.19616E-18 -18.7074 0.50255E+00 -0.2988 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9796685E-10 -.2084092E-01 -.2096535E+02 0.0000 2 H2O 0.1000000E+01 0.5551220E+02 0.9981149E+06 0.0000 3 Cl- 0.8896256E-03 0.8940884E-03 0.3163618E+02 6.9553 4 SO4-- 0.6111982E-10 -.7233049E-02 -.6934607E+03 9.6638 5 HCO3- 0.1283113E-03 0.7585108E-02 0.4619177E+03 6.1150 6 HS- 0.2591262E-02 0.9824855E-02 0.3242927E+03 7.4196 7 Al+++ 0.1388616E-28 0.4865962E-05 0.1310344E+00 0.7391 8 H4SiO4 0.6958779E-03 0.1264242E-01 0.1212757E+04 -3.1575 9 Ca++ 0.1689426E-06 0.3968978E-06 0.1587579E-01 13.1018 10 Mg++ 0.2644090E-10 0.1111707E-09 0.2697501E-05 9.2942 11 Fe++ 0.7287644E-13 0.3322707E-07 0.1852006E-02 6.7350 12 K+ 0.1736638E-03 0.1744191E-03 0.6806811E+01 6.2466 13 Na+ 0.2204099E-01 0.2449013E-01 0.5619231E+03 8.3492 14 Mn++ 0.2349483E-10 0.2573281E-08 0.1410947E-03 9.2438 15 F- 0.1053854E-05 0.1057581E-05 0.2005266E-01 4.0279 16 HPO4-- 0.3851515E-07 0.3940257E-07 0.3774430E-02 12.4633 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278695E+02 -.1036384E-01 -.8277659E+02 0.0000000E+00 2 H2O -.7126225E+01 0.2760529E+02 -.3473151E+02 0.0000000E+00 3 Cl- 0.4446152E-03 0.4446152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1388408E+00 -.3596874E-02 0.1424376E+00 0.0000000E+00 5 HCO3- 0.3771947E-02 0.3771947E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1375519E+00 0.4885736E-02 -.1424376E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2419761E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6286865E-02 0.5205762E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1973706E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5528333E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1652326E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8673571E-04 0.1061484E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1217853E-01 0.6264198E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1279649E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2089600E-04 0.5259172E-06 0.2037008E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1959424E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1325E-13 Mass of aqueous solution: 0.498257E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0519900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.255 0.796 1640. 3.215 30.03 629.6 andradite 0.5698 -0.244 289.5 2.462 5.301 75.22 grossular 0.1380 -0.860 62.15 1.793 1.138 17.29 apatite-OH 0.9842E-02 -2.007 4.944 0.694 0.9051E-01 1.571 apatite-F 0.2037E-04 -4.691 0.1027E-01 -1.988 0.1881E-03 0.3209E-02 clinochlore 0.7067 -0.151 392.8 2.594 7.191 149.4 daphnite 0.2046 -0.689 146.0 2.164 2.673 44.24 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1628 -0.788 35.26 1.547 0.6455 10.78 hedenbergite 0.4223E-01 -1.374 10.48 1.020 0.1918 2.870 microcline 0.9348 -0.029 260.2 2.415 4.764 101.6 stilbite 3.223 0.508 2271. 3.356 41.58 1059. stilpnomelane-Fe 0.2533 -0.596 273.1 2.436 4.999 94.32 tr.625ac.25prg.125 0.7506E-01 -1.125 64.16 1.807 1.175 20.65 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1867E-01 0.1867E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.352710 g Volume = 2210.921525 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0519900 moles log = -1.2841 Original solution: 1000.0103000 g Original solution / Rock added: 19234.67 (Water/Rock Ratio), log = 4.2841 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 11.7454 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8901E-01 0.9621 0.1006E+01 0.1045E+01 CO2,gas 0.1733E-06 0.9776 0.1990E-05 0.2035E-05 CH4,gas 0.9097E+00 0.9939 0.1062E+02 0.1068E+02 H2,gas 0.1286E-02 1.0063 0.1520E-01 0.1511E-01 H2S,gas 0.1328E-05 0.9557 0.1491E-04 0.1560E-04 S2,gas 0.3073E-26 1.0000 0.3609E-25 0.3609E-25 CO,gas 0.6865E-12 1.0000 0.8063E-11 0.8063E-11 SO3,gas 0.6618E-47 1.0000 0.7774E-46 0.7774E-46 SO2,gas 0.3915E-26 1.0000 0.4599E-25 0.4599E-25 HF,gas 0.1019E-15 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1658E-17 1.0000 0.1948E-16 0.1948E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.72794E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.06 -7.40 -2.467 0.12636E+05 -5.701 3 CH4,gas 4.54 3.87 -0.67 -0.168 0.11489E+04 1.026 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.76 -6.53 -3.263 0.11142E+05 -4.827 6 S2,gas -7.34 -34.48 -27.14 -4.176 0.46344E+05 -25.443 7 CO,gas 3.21 -9.58 -12.79 -3.936 0.21843E+05 -11.094 8 SO3,gas 17.12 -30.69 -47.81 -11.952 0.81631E+05 -46.109 9 SO2,gas 0.83 -26.20 -27.04 -7.210 0.46164E+05 -25.337 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.22 -18.41 -9.205 0.31434E+05 -16.710 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80595E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93643E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41065E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28493E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -0.96 -1.93 -0.642 0.32870E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -0.96 -1.77 -0.590 0.30228E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68942E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65510E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -5.09 -1.99 -0.569 0.34018E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37136E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -5.09 -1.55 -0.442 0.26441E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64127E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28622E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82204E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41126E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36681E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91153E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -23.26 -2.01 -0.473 0.34360E+04 146 pyrrhotite -4.26 -6.02 -1.76 -0.587 0.30059E+04 147 pyrrhotiteFe0.875 -6.02 -7.42 -1.40 -0.515 0.23931E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22407E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84958E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28672E+03 154 rhodochrosite -0.98 -4.82 -3.84 -1.280 0.65572E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23209E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.33 -4.72 -1.572 0.80545E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27808E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47052E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90669E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77503E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65445E+04 184 troilite-low -4.41 -6.02 -1.61 -0.537 0.27487E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60601E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73675E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.51 -2.53 -0.845 0.43269E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0519900 MOLES New total amount of reactant added: 0.0539900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8657E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0539900 Water: Moles liquid = 0.2761E+02 kg liquid = 0.4973E+00 Moles total = -.7125E+01 kg total = -.1284E+00 Activity = 0.9999 Stoichiometric ionic strength = .6870706E-02 Osmotic coef. = 0.9329 True ionic strength = .2253204E-01 Chg. balance for total moles = -.8657E-10 Max. difference allowed = 0.4564E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.98332E-10 -10.0073 0.81996E-10 -10.0862 0.83387E+00 -0.0789 2 H2O 0.99986E+00 -0.0001 0.99986E+00 -0.0001 3 Cl- 0.91315E-03 -3.0395 0.75643E-03 -3.1212 0.82837E+00 -0.0818 4 SO4-- 0.63252E-10 -10.1989 0.31826E-10 -10.4972 0.50316E+00 -0.2983 5 HCO3- 0.13284E-03 -3.8767 0.11021E-03 -3.9578 0.82970E+00 -0.0811 6 HS- 0.26888E-02 -2.5704 0.22277E-02 -2.6521 0.82851E+00 -0.0817 7 Al+++ 0.14066E-28 -28.8518 0.30233E-29 -29.5195 0.21494E+00 -0.6677 8 H4SiO4 0.69587E-03 -3.1575 0.69587E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.17030E-06 -6.7688 0.85000E-07 -7.0706 0.49911E+00 -0.3018 10 Mg++ 0.26654E-10 -10.5742 0.13237E-10 -10.8782 0.49660E+00 -0.3040 11 Fe++ 0.73465E-13 -13.1339 0.36527E-13 -13.4374 0.49720E+00 -0.3035 12 K+ 0.17431E-03 -3.7587 0.14466E-03 -3.8396 0.82992E+00 -0.0810 13 Na+ 0.22123E-01 -1.6552 0.18323E-01 -1.7370 0.82821E+00 -0.0819 14 Mn++ 0.23689E-10 -10.6255 0.11789E-10 -10.9285 0.49765E+00 -0.3031 15 F- 0.10505E-05 -5.9786 0.86826E-06 -6.0613 0.82651E+00 -0.0828 16 HPO4-- 0.38292E-07 -7.4169 0.19270E-07 -7.7151 0.50324E+00 -0.2982 18 HSiO3- 0.95675E-02 -2.0192 0.79254E-02 -2.1010 0.82837E+00 -0.0818 19 Ca(HSiO3)+ 0.18482E-07 -7.7333 0.15342E-07 -7.8141 0.83011E+00 -0.0809 20 Mg(HSiO3)+ 0.35818E-11 -11.4459 0.29733E-11 -11.5268 0.83011E+00 -0.0809 21 NaHSiO3,aq 0.23486E-02 -2.6292 0.23486E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.73686E-16 -16.1326 0.61168E-16 -16.2135 0.83011E+00 -0.0809 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.48505E-05 -5.3142 0.40101E-05 -5.3969 0.82674E+00 -0.0826 26 CH4,aq 0.75084E-02 -2.1244 0.74926E-02 -2.1254 0.99789E+00 -0.0009 27 C2H6,aq 0.83047E-09 -9.0807 0.82872E-09 -9.0816 0.99789E+00 -0.0009 28 C3H8,aq 0.21207E-14 -14.6735 0.21162E-14 -14.6744 0.99789E+00 -0.0009 30 ethanol,aq 0.30482E-16 -16.5160 0.30417E-16 -16.5169 0.99789E+00 -0.0009 31 CO,aq 0.56193E-14 -14.2503 0.56193E-14 -14.2503 0.10000E+01 0.0000 32 CO2,aq 0.19354E-07 -7.7132 0.19313E-07 -7.7142 0.99789E+00 -0.0009 33 CO3-2 0.23388E-03 -3.6310 0.11741E-03 -3.9303 0.50199E+00 -0.2993 34 CaCO3,aq 0.12513E-06 -6.9026 0.12513E-06 -6.9026 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.28807E-09 -9.5405 0.23913E-09 -9.6214 0.83011E+00 -0.0809 36 CaCl+ 0.12535E-09 -9.9019 0.10405E-09 -9.9827 0.83011E+00 -0.0809 37 CaCl2,aq 0.18700E-13 -13.7282 0.18700E-13 -13.7282 0.10000E+01 0.0000 38 CaF+ 0.12980E-11 -11.8867 0.10775E-11 -11.9676 0.83011E+00 -0.0809 39 CaOH+ 0.88988E-07 -7.0507 0.73870E-07 -7.1315 0.83011E+00 -0.0809 40 CaSO4,aq 0.85904E-15 -15.0660 0.85904E-15 -15.0660 0.10000E+01 0.0000 41 HCl,aq 0.11366E-13 -13.9444 0.11366E-13 -13.9444 0.10000E+01 0.0000 45 HF,aq 0.48737E-12 -12.3121 0.48737E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17247E-18 -18.7633 0.14287E-18 -18.8451 0.82837E+00 -0.0818 48 FeCl+ 0.52684E-16 -16.2783 0.43734E-16 -16.3592 0.83011E+00 -0.0809 51 FeF+ 0.19524E-17 -17.7094 0.16207E-17 -17.7903 0.83011E+00 -0.0809 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17466E-10 -10.7578 0.14499E-10 -10.8387 0.83011E+00 -0.0809 55 HFeO2- 0.32517E-07 -7.4879 0.26937E-07 -7.5697 0.82837E+00 -0.0818 56 FeO+ 0.12242E-16 -16.9122 0.10162E-16 -16.9930 0.83011E+00 -0.0809 58 FeO2- 0.37330E-09 -9.4279 0.30923E-09 -9.5097 0.82837E+00 -0.0818 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11605E-04 -4.9353 0.11581E-04 -4.9363 0.99789E+00 -0.0009 61 KCl,aq 0.19833E-08 -8.7026 0.19833E-08 -8.7026 0.10000E+01 0.0000 63 KOH,aq 0.75334E-06 -6.1230 0.75334E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.86247E-13 -13.0643 0.71444E-13 -13.1460 0.82837E+00 -0.0818 65 MgCO3,aq 0.48843E-11 -11.3112 0.48843E-11 -11.3112 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.45839E-13 -13.3388 0.38051E-13 -13.4196 0.83011E+00 -0.0809 67 MgCl+ 0.17692E-13 -13.7522 0.14686E-13 -13.8331 0.83011E+00 -0.0809 68 MgF+ 0.74878E-15 -15.1256 0.62157E-15 -15.2065 0.83011E+00 -0.0809 69 MgOH+ 0.76682E-10 -10.1153 0.63655E-10 -10.1962 0.83011E+00 -0.0809 71 MnF+ 0.20769E-15 -15.6826 0.17241E-15 -15.7634 0.83011E+00 -0.0809 72 MnO,aq 0.18156E-08 -8.7410 0.18156E-08 -8.7410 0.10000E+01 0.0000 73 MnOH+ 0.52366E-09 -9.2810 0.43470E-09 -9.3618 0.83011E+00 -0.0809 74 MnO2-2 0.17851E-10 -10.7483 0.89609E-11 -11.0476 0.50199E+00 -0.2993 75 HMnO2- 0.19432E-09 -9.7115 0.16097E-09 -9.7932 0.82837E+00 -0.0818 78 MnCl+ 0.66152E-13 -13.1795 0.54914E-13 -13.2603 0.83011E+00 -0.0809 79 MnSO4,aq 0.10832E-18 -18.9653 0.10832E-18 -18.9653 0.10000E+01 0.0000 80 NaCl,aq 0.45932E-05 -5.3379 0.45932E-05 -5.3379 0.10000E+01 0.0000 81 NaF,aq 0.37245E-08 -8.4289 0.37245E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.95995E-04 -4.0178 0.95995E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.85220E-02 -2.0695 0.70454E-02 -2.1521 0.82674E+00 -0.0826 89 HPO3-2 0.13856E-14 -14.8584 0.69555E-15 -15.1577 0.50199E+00 -0.2993 91 H2PO3- 0.13806E-18 -18.8599 0.11437E-18 -18.9417 0.82837E+00 -0.0818 92 H3PO4,aq 0.90613E-18 -18.0428 0.90613E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.35150E-10 -10.4541 0.29148E-10 -10.5354 0.82924E+00 -0.0813 94 PO4-3 0.84534E-09 -9.0730 0.19174E-09 -9.7173 0.22683E+00 -0.6443 98 HP2O7-3 0.75399E-18 -18.1226 0.16225E-18 -18.7898 0.21519E+00 -0.6672 99 P2O7-4 0.69495E-17 -17.1580 0.47271E-18 -18.3254 0.68021E-01 -1.1674 100 H2S,aq 0.56573E-06 -6.2474 0.56453E-06 -6.2483 0.99789E+00 -0.0009 101 S2-2 0.18914E-10 -10.7232 0.94949E-11 -11.0225 0.50199E+00 -0.2993 102 S3-2 0.12422E-17 -17.9058 0.62358E-18 -18.2051 0.50199E+00 -0.2993 107 SO3-2 0.93935E-16 -16.0272 0.47903E-16 -16.3196 0.50996E+00 -0.2925 108 HSO3- 0.29688E-18 -18.5274 0.24593E-18 -18.6092 0.82837E+00 -0.0818 109 HSO4- 0.30264E-17 -17.5191 0.25149E-17 -17.5995 0.83100E+00 -0.0804 111 S2O3-2 0.42049E-18 -18.3762 0.21108E-18 -18.6755 0.50199E+00 -0.2993 Charge balance for all species = -.1740E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9833164E-10 -.2079074E-01 -.2091470E+02 0.0000 2 H2O 0.1000000E+01 0.5551248E+02 0.9981117E+06 0.0000 3 Cl- 0.9131548E-03 0.9177501E-03 0.3247315E+02 6.9650 4 SO4-- 0.6325232E-10 -.7511352E-02 -.7201367E+03 9.6752 5 HCO3- 0.1328356E-03 0.7875311E-02 0.4795865E+03 6.1284 6 HS- 0.2688774E-02 0.1020069E-01 0.3366953E+03 7.4341 7 Al+++ 0.1406598E-28 0.4850601E-05 0.1306197E+00 0.7391 8 H4SiO4 0.6958740E-03 0.1261200E-01 0.1209829E+04 -3.1575 9 Ca++ 0.1703036E-06 0.4033195E-06 0.1613252E-01 13.1018 10 Mg++ 0.2665432E-10 0.1118671E-09 0.2714377E-05 9.2942 11 Fe++ 0.7346471E-13 0.3312252E-07 0.1846164E-02 6.7350 12 K+ 0.1743104E-03 0.1750658E-03 0.6831989E+01 6.2466 13 Na+ 0.2212319E-01 0.2457243E-01 0.5638067E+03 8.3492 14 Mn++ 0.2368903E-10 0.2575200E-08 0.1411987E-03 9.2439 15 F- 0.1050521E-05 0.1054247E-05 0.1998929E-01 4.0249 16 HPO4-- 0.3829182E-07 0.3917231E-07 0.3752342E-02 12.4573 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278673E+02 -.1033965E-01 -.8277639E+02 0.0000000E+00 2 H2O -.7124587E+01 0.2760745E+02 -.3473204E+02 0.0000000E+00 3 Cl- 0.4564152E-03 0.4564152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1388503E+00 -.3735543E-02 0.1425859E+00 0.0000000E+00 5 HCO3- 0.3916547E-02 0.3916547E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1375129E+00 0.5073005E-02 -.1425859E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2412299E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6272196E-02 0.5205763E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2005787E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5563372E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1647248E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8706365E-04 0.1061484E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1222035E-01 0.6264157E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1280698E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2169600E-04 0.5242980E-06 0.2117170E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1948116E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1124E-14 Mass of aqueous solution: 0.498297E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0539900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.255 0.796 1640. 3.215 30.03 629.6 andradite 0.5703 -0.244 289.8 2.462 5.306 75.30 grossular 0.1381 -0.860 62.22 1.794 1.139 17.31 apatite-OH 0.9841E-02 -2.007 4.944 0.694 0.9050E-01 1.571 apatite-F 0.2117E-04 -4.674 0.1068E-01 -1.972 0.1955E-03 0.3336E-02 clinochlore 0.7065 -0.151 392.7 2.594 7.189 149.4 daphnite 0.2046 -0.689 146.0 2.164 2.672 44.23 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1590 -0.799 34.42 1.537 0.6302 10.52 hedenbergite 0.4123E-01 -1.385 10.23 1.010 0.1873 2.802 microcline 0.9350 -0.029 260.2 2.415 4.764 101.7 stilbite 3.223 0.508 2271. 3.356 41.58 1059. stilpnomelane-Fe 0.2530 -0.597 272.7 2.436 4.993 94.20 tr.625ac.25prg.125 0.7632E-01 -1.117 65.23 1.814 1.194 21.00 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1868E-01 0.1868E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.353215 g Volume = 2210.927067 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0539900 moles log = -1.2677 Original solution: 1000.0103000 g Original solution / Rock added: 18522.14 (Water/Rock Ratio), log = 4.2677 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 12.1610 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8601E-01 0.9616 0.1006E+01 0.1046E+01 CO2,gas 0.1739E-06 0.9769 0.2066E-05 0.2115E-05 CH4,gas 0.9127E+00 0.9936 0.1103E+02 0.1110E+02 H2,gas 0.1242E-02 1.0065 0.1520E-01 0.1511E-01 H2S,gas 0.1337E-05 0.9542 0.1552E-04 0.1626E-04 S2,gas 0.3216E-26 1.0000 0.3910E-25 0.3910E-25 CO,gas 0.6886E-12 1.0000 0.8374E-11 0.8374E-11 SO3,gas 0.6654E-47 1.0000 0.8092E-46 0.8092E-46 SO2,gas 0.3936E-26 1.0000 0.4787E-25 0.4787E-25 HF,gas 0.9840E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1649E-17 1.0000 0.2006E-16 0.2006E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.04 -7.38 -2.461 0.12608E+05 -5.685 3 CH4,gas 4.54 3.89 -0.66 -0.164 0.11209E+04 1.043 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.74 -6.51 -3.254 0.11112E+05 -4.809 6 S2,gas -7.34 -34.44 -27.11 -4.170 0.46284E+05 -25.408 7 CO,gas 3.21 -9.56 -12.78 -3.931 0.21815E+05 -11.077 8 SO3,gas 17.12 -30.67 -47.79 -11.948 0.81602E+05 -46.092 9 SO2,gas 0.83 -26.19 -27.02 -7.205 0.46134E+05 -25.320 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.21 -18.40 -9.198 0.31412E+05 -16.698 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80590E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93644E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28493E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75901E+04 38 aragonite 0.97 -0.94 -1.91 -0.636 0.32590E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -0.94 -1.75 -0.585 0.29948E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39695E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68943E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65509E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -5.08 -1.98 -0.565 0.33738E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37136E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -5.08 -1.53 -0.438 0.26160E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28622E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48026E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82203E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36681E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91153E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -23.22 -1.98 -0.465 0.33766E+04 146 pyrrhotite -4.26 -6.00 -1.74 -0.581 0.29761E+04 147 pyrrhotiteFe0.875 -6.02 -7.40 -1.38 -0.509 0.23634E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22405E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28671E+03 154 rhodochrosite -0.98 -4.80 -3.82 -1.275 0.65290E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23208E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.31 -4.70 -1.567 0.80265E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27808E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47049E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90669E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77503E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65445E+04 184 troilite-low -4.41 -6.00 -1.59 -0.531 0.27189E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60601E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.49 -2.52 -0.839 0.42970E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0539900 MOLES New total amount of reactant added: 0.0559900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8657E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0559900 Water: Moles liquid = 0.2761E+02 kg liquid = 0.4974E+00 Moles total = -.7123E+01 kg total = -.1283E+00 Activity = 0.9999 Stoichiometric ionic strength = .6700261E-02 Osmotic coef. = 0.9336 True ionic strength = .2262229E-01 Chg. balance for total moles = -.8657E-10 Max. difference allowed = 0.4682E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.98697E-10 -10.0057 0.82279E-10 -10.0847 0.83365E+00 -0.0790 2 H2O 0.99986E+00 -0.0001 0.99986E+00 -0.0001 3 Cl- 0.93668E-03 -3.0284 0.77570E-03 -3.1103 0.82814E+00 -0.0819 4 SO4-- 0.65373E-10 -10.1846 0.32858E-10 -10.4834 0.50262E+00 -0.2988 5 HCO3- 0.13733E-03 -3.8622 0.11391E-03 -3.9434 0.82947E+00 -0.0812 6 HS- 0.27863E-02 -2.5550 0.23078E-02 -2.6368 0.82827E+00 -0.0818 7 Al+++ 0.14248E-28 -28.8463 0.30548E-29 -29.5150 0.21441E+00 -0.6688 8 H4SiO4 0.69587E-03 -3.1575 0.69587E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.17167E-06 -6.7653 0.85587E-07 -7.0676 0.49855E+00 -0.3023 10 Mg++ 0.26869E-10 -10.5707 0.13328E-10 -10.8752 0.49604E+00 -0.3045 11 Fe++ 0.74056E-13 -13.1304 0.36779E-13 -13.4344 0.49664E+00 -0.3040 12 K+ 0.17496E-03 -3.7571 0.14516E-03 -3.8382 0.82969E+00 -0.0811 13 Na+ 0.22206E-01 -1.6535 0.18386E-01 -1.7355 0.82797E+00 -0.0820 14 Mn++ 0.23884E-10 -10.6219 0.11873E-10 -10.9254 0.49709E+00 -0.3036 15 F- 0.10472E-05 -5.9800 0.86527E-06 -6.0628 0.82627E+00 -0.0829 16 HPO4-- 0.38070E-07 -7.4194 0.19138E-07 -7.7181 0.50270E+00 -0.2987 18 HSiO3- 0.95373E-02 -2.0206 0.78982E-02 -2.1025 0.82814E+00 -0.0819 19 Ca(HSiO3)+ 0.18550E-07 -7.7316 0.15395E-07 -7.8126 0.82988E+00 -0.0810 20 Mg(HSiO3)+ 0.35951E-11 -11.4443 0.29835E-11 -11.5253 0.82988E+00 -0.0810 21 NaHSiO3,aq 0.23486E-02 -2.6292 0.23486E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.73961E-16 -16.1310 0.61379E-16 -16.2120 0.82988E+00 -0.0810 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.48352E-05 -5.3156 0.39963E-05 -5.3983 0.82650E+00 -0.0828 26 CH4,aq 0.77868E-02 -2.1086 0.77708E-02 -2.1095 0.99794E+00 -0.0009 27 C2H6,aq 0.89324E-09 -9.0490 0.89140E-09 -9.0499 0.99794E+00 -0.0009 28 C3H8,aq 0.23656E-14 -14.6261 0.23608E-14 -14.6269 0.99794E+00 -0.0009 30 ethanol,aq 0.32786E-16 -16.4843 0.32718E-16 -16.4852 0.99794E+00 -0.0009 31 CO,aq 0.58280E-14 -14.2345 0.58280E-14 -14.2345 0.10000E+01 0.0000 32 CO2,aq 0.20071E-07 -7.6974 0.20030E-07 -7.6983 0.99794E+00 -0.0009 33 CO3-2 0.24116E-03 -3.6177 0.12093E-03 -3.9175 0.50144E+00 -0.2998 34 CaCO3,aq 0.12978E-06 -6.8868 0.12978E-06 -6.8868 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.29988E-09 -9.5230 0.24887E-09 -9.6040 0.82988E+00 -0.0810 36 CaCl+ 0.12946E-09 -9.8878 0.10744E-09 -9.9688 0.82988E+00 -0.0810 37 CaCl2,aq 0.19800E-13 -13.7033 0.19800E-13 -13.7033 0.10000E+01 0.0000 38 CaF+ 0.13029E-11 -11.8851 0.10812E-11 -11.9661 0.82988E+00 -0.0810 39 CaOH+ 0.89320E-07 -7.0491 0.74125E-07 -7.1300 0.82988E+00 -0.0810 40 CaSO4,aq 0.89301E-15 -15.0491 0.89301E-15 -15.0491 0.10000E+01 0.0000 41 HCl,aq 0.11695E-13 -13.9320 0.11695E-13 -13.9320 0.10000E+01 0.0000 45 HF,aq 0.48737E-12 -12.3121 0.48737E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17193E-18 -18.7647 0.14238E-18 -18.8466 0.82814E+00 -0.0819 48 FeCl+ 0.54415E-16 -16.2643 0.45158E-16 -16.3453 0.82988E+00 -0.0810 51 FeF+ 0.19596E-17 -17.7078 0.16263E-17 -17.7888 0.82988E+00 -0.0810 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17531E-10 -10.7562 0.14549E-10 -10.8372 0.82988E+00 -0.0810 55 HFeO2- 0.32414E-07 -7.4893 0.26844E-07 -7.5712 0.82814E+00 -0.0819 56 FeO+ 0.12287E-16 -16.9105 0.10197E-16 -16.9915 0.82988E+00 -0.0810 58 FeO2- 0.37212E-09 -9.4293 0.30817E-09 -9.5112 0.82814E+00 -0.0819 59 HFeO2,aq 0.32249E-11 -11.4915 0.32249E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11605E-04 -4.9354 0.11581E-04 -4.9363 0.99794E+00 -0.0009 61 KCl,aq 0.20408E-08 -8.6902 0.20408E-08 -8.6902 0.10000E+01 0.0000 63 KOH,aq 0.75333E-06 -6.1230 0.75333E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.89373E-13 -13.0488 0.74013E-13 -13.1307 0.82814E+00 -0.0819 65 MgCO3,aq 0.50657E-11 -11.2954 0.50657E-11 -11.2954 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.47718E-13 -13.3213 0.39601E-13 -13.4023 0.82988E+00 -0.0810 67 MgCl+ 0.18273E-13 -13.7382 0.15164E-13 -13.8192 0.82988E+00 -0.0810 68 MgF+ 0.75157E-15 -15.1240 0.62371E-15 -15.2050 0.82988E+00 -0.0810 69 MgOH+ 0.76967E-10 -10.1137 0.63874E-10 -10.1947 0.82988E+00 -0.0810 71 MnF+ 0.20851E-15 -15.6809 0.17304E-15 -15.7619 0.82988E+00 -0.0810 72 MnO,aq 0.18160E-08 -8.7409 0.18160E-08 -8.7409 0.10000E+01 0.0000 73 MnOH+ 0.52571E-09 -9.2792 0.43628E-09 -9.3602 0.82988E+00 -0.0810 74 MnO2-2 0.17751E-10 -10.7508 0.89010E-11 -11.0506 0.50144E+00 -0.2998 75 HMnO2- 0.19375E-09 -9.7128 0.16045E-09 -9.7947 0.82814E+00 -0.0819 78 MnCl+ 0.68338E-13 -13.1653 0.56713E-13 -13.2463 0.82988E+00 -0.0810 79 MnSO4,aq 0.11262E-18 -18.9484 0.11262E-18 -18.9484 0.10000E+01 0.0000 80 NaCl,aq 0.47264E-05 -5.3255 0.47264E-05 -5.3255 0.10000E+01 0.0000 81 NaF,aq 0.37245E-08 -8.4289 0.37245E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.95993E-04 -4.0178 0.95993E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.84951E-02 -2.0708 0.70212E-02 -2.1536 0.82650E+00 -0.0828 89 HPO3-2 0.13776E-14 -14.8609 0.69078E-15 -15.1607 0.50144E+00 -0.2998 91 H2PO3- 0.13763E-18 -18.8613 0.11397E-18 -18.9432 0.82814E+00 -0.0819 92 H3PO4,aq 0.90613E-18 -18.0428 0.90613E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.35039E-10 -10.4554 0.29048E-10 -10.5369 0.82900E+00 -0.0814 94 PO4-3 0.83859E-09 -9.0764 0.18977E-09 -9.7218 0.22630E+00 -0.6453 98 HP2O7-3 0.74810E-18 -18.1260 0.16058E-18 -18.7943 0.21465E+00 -0.6683 99 P2O7-4 0.68841E-17 -17.1622 0.46625E-18 -18.3314 0.67728E-01 -1.1692 100 H2S,aq 0.58807E-06 -6.2306 0.58686E-06 -6.2315 0.99794E+00 -0.0009 101 S2-2 0.20322E-10 -10.6920 0.10190E-10 -10.9918 0.50144E+00 -0.2998 102 S3-2 0.13874E-17 -17.8578 0.69571E-18 -18.1576 0.50144E+00 -0.2998 107 SO3-2 0.97081E-16 -16.0129 0.49455E-16 -16.3058 0.50942E+00 -0.2929 108 HSO3- 0.30765E-18 -18.5119 0.25478E-18 -18.5938 0.82814E+00 -0.0819 109 HSO4- 0.31361E-17 -17.5036 0.26054E-17 -17.5841 0.83078E+00 -0.0805 111 S2O3-2 0.45178E-18 -18.3451 0.22654E-18 -18.6449 0.50144E+00 -0.2998 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9869688E-10 -.2074080E-01 -.2086429E+02 0.0000 2 H2O 0.1000000E+01 0.5551276E+02 0.9981084E+06 0.0000 3 Cl- 0.9366798E-03 0.9414083E-03 0.3330998E+02 6.9744 4 SO4-- 0.6537321E-10 -.7789726E-02 -.7468190E+03 9.6861 5 HCO3- 0.1373329E-03 0.8165471E-02 0.4972524E+03 6.1413 6 HS- 0.2786271E-02 0.1057659E-01 0.3490996E+03 7.4479 7 Al+++ 0.1424769E-28 0.4835326E-05 0.1302073E+00 0.7391 8 H4SiO4 0.6958701E-03 0.1258175E-01 0.1206917E+04 -3.1575 9 Ca++ 0.1716723E-06 0.4097511E-06 0.1638965E-01 13.1018 10 Mg++ 0.2686893E-10 0.1125634E-09 0.2731249E-05 9.2942 11 Fe++ 0.7405626E-13 0.3301856E-07 0.1840354E-02 6.7350 12 K+ 0.1749578E-03 0.1757132E-03 0.6857198E+01 6.2466 13 Na+ 0.2220550E-01 0.2465483E-01 0.5656928E+03 8.3492 14 Mn++ 0.2388437E-10 0.2577128E-08 0.1413033E-03 9.2440 15 F- 0.1047206E-05 0.1050933E-05 0.1992628E-01 4.0219 16 HPO4-- 0.3807032E-07 0.3894395E-07 0.3730436E-02 12.4513 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278652E+02 -.1031557E-01 -.8277620E+02 0.0000000E+00 2 H2O -.7122950E+01 0.2760961E+02 -.3473256E+02 0.0000000E+00 3 Cl- 0.4682152E-03 0.4682152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1388599E+00 -.3874268E-02 0.1427341E+00 0.0000000E+00 5 HCO3- 0.4061147E-02 0.4061147E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1374738E+00 0.5260330E-02 -.1427341E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2404879E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6257610E-02 0.5205765E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2037922E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5598411E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1642198E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8739203E-04 0.1061484E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1226223E-01 0.6264115E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1281751E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2249600E-04 0.5226878E-06 0.2197331E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1936901E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.7563E-15 Mass of aqueous solution: 0.498338E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0559900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.254 0.796 1640. 3.215 30.02 629.6 andradite 0.5709 -0.243 290.1 2.463 5.312 75.38 grossular 0.1383 -0.859 62.28 1.794 1.140 17.33 apatite-OH 0.9841E-02 -2.007 4.943 0.694 0.9049E-01 1.571 apatite-F 0.2197E-04 -4.658 0.1108E-01 -1.955 0.2029E-03 0.3462E-02 clinochlore 0.7064 -0.151 392.6 2.594 7.188 149.3 daphnite 0.2045 -0.689 145.9 2.164 2.671 44.22 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1551 -0.809 33.59 1.526 0.6149 10.26 hedenbergite 0.4022E-01 -1.396 9.980 0.999 0.1827 2.733 microcline 0.9351 -0.029 260.3 2.415 4.765 101.7 stilbite 3.223 0.508 2272. 3.356 41.59 1059. stilpnomelane-Fe 0.2527 -0.597 272.4 2.435 4.987 94.09 tr.625ac.25prg.125 0.7758E-01 -1.110 66.31 1.822 1.214 21.34 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1868E-01 0.1868E-01 1.0000 -1.729 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.353716 g Volume = 2210.932610 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0559900 moles log = -1.2519 Original solution: 1000.0103000 g Original solution / Rock added: 17860.52 (Water/Rock Ratio), log = 4.2519 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 12.5771 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8321E-01 0.9611 0.1006E+01 0.1047E+01 CO2,gas 0.1745E-06 0.9762 0.2143E-05 0.2195E-05 CH4,gas 0.9156E+00 0.9933 0.1144E+02 0.1152E+02 H2,gas 0.1201E-02 1.0067 0.1520E-01 0.1510E-01 H2S,gas 0.1346E-05 0.9526 0.1613E-04 0.1693E-04 S2,gas 0.3360E-26 1.0000 0.4226E-25 0.4226E-25 CO,gas 0.6905E-12 1.0000 0.8685E-11 0.8685E-11 SO3,gas 0.6688E-47 1.0000 0.8412E-46 0.8412E-46 SO2,gas 0.3957E-26 1.0000 0.4976E-25 0.4976E-25 HF,gas 0.9515E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1641E-17 1.0000 0.2064E-16 0.2064E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.15165E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.03 -7.37 -2.456 0.12581E+05 -5.669 3 CH4,gas 4.54 3.90 -0.64 -0.160 0.10938E+04 1.058 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.72 -6.49 -3.246 0.11084E+05 -4.792 6 S2,gas -7.34 -34.41 -27.07 -4.165 0.46227E+05 -25.374 7 CO,gas 3.21 -9.55 -12.76 -3.926 0.21788E+05 -11.061 8 SO3,gas 17.12 -30.65 -47.77 -11.944 0.81573E+05 -46.075 9 SO2,gas 0.83 -26.17 -27.00 -7.201 0.46105E+05 -25.303 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.20 -18.38 -9.192 0.31391E+05 -16.685 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80586E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93644E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28493E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 38 aragonite 0.97 -0.93 -1.89 -0.631 0.32319E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -0.93 -1.74 -0.579 0.29677E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39696E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68943E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65507E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -5.06 -1.96 -0.560 0.33467E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37136E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -5.06 -1.52 -0.433 0.25890E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28622E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82201E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36682E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91153E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -23.19 -1.94 -0.457 0.33190E+04 146 pyrrhotite -4.26 -5.99 -1.73 -0.575 0.29474E+04 147 pyrrhotiteFe0.875 -6.02 -7.38 -1.37 -0.503 0.23346E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22404E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28671E+03 154 rhodochrosite -0.98 -4.78 -3.81 -1.269 0.65018E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23207E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.29 -4.68 -1.562 0.79994E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27808E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47046E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90669E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77503E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65445E+04 184 troilite-low -4.41 -5.99 -1.58 -0.525 0.26902E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60601E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53291E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.48 -2.50 -0.833 0.42681E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0559900 MOLES New total amount of reactant added: 0.0579900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8658E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0579900 Water: Moles liquid = 0.2761E+02 kg liquid = 0.4974E+00 Moles total = -.7121E+01 kg total = -.1283E+00 Activity = 0.9999 Stoichiometric ionic strength = .6529736E-02 Osmotic coef. = 0.9344 True ionic strength = .2271255E-01 Chg. balance for total moles = -.8658E-10 Max. difference allowed = 0.4800E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.99063E-10 -10.0041 0.82562E-10 -10.0832 0.83343E+00 -0.0791 2 H2O 0.99985E+00 -0.0001 0.99985E+00 -0.0001 3 Cl- 0.96020E-03 -3.0176 0.79496E-03 -3.0997 0.82791E+00 -0.0820 4 SO4-- 0.67483E-10 -10.1708 0.33881E-10 -10.4700 0.50207E+00 -0.2992 5 HCO3- 0.14180E-03 -3.8483 0.11759E-03 -3.9296 0.82924E+00 -0.0813 6 HS- 0.28838E-02 -2.5400 0.23879E-02 -2.6220 0.82804E+00 -0.0819 7 Al+++ 0.14431E-28 -28.8407 0.30865E-29 -29.5105 0.21387E+00 -0.6698 8 H4SiO4 0.69587E-03 -3.1575 0.69587E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.17305E-06 -6.7618 0.86178E-07 -7.0646 0.49800E+00 -0.3028 10 Mg++ 0.27085E-10 -10.5673 0.13420E-10 -10.8722 0.49548E+00 -0.3050 11 Fe++ 0.74651E-13 -13.1270 0.37033E-13 -13.4314 0.49608E+00 -0.3044 12 K+ 0.17561E-03 -3.7555 0.14566E-03 -3.8367 0.82946E+00 -0.0812 13 Na+ 0.22288E-01 -1.6519 0.18449E-01 -1.7340 0.82774E+00 -0.0821 14 Mn++ 0.24081E-10 -10.6183 0.11957E-10 -10.9224 0.49654E+00 -0.3040 15 F- 0.10439E-05 -5.9813 0.86230E-06 -6.0643 0.82603E+00 -0.0830 16 HPO4-- 0.37851E-07 -7.4219 0.19007E-07 -7.7211 0.50215E+00 -0.2992 18 HSiO3- 0.95072E-02 -2.0219 0.78711E-02 -2.1040 0.82791E+00 -0.0820 19 Ca(HSiO3)+ 0.18619E-07 -7.7300 0.15448E-07 -7.8111 0.82965E+00 -0.0811 20 Mg(HSiO3)+ 0.36085E-11 -11.4427 0.29938E-11 -11.5238 0.82965E+00 -0.0811 21 NaHSiO3,aq 0.23486E-02 -2.6292 0.23486E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.74237E-16 -16.1294 0.61591E-16 -16.2105 0.82965E+00 -0.0811 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.48200E-05 -5.3170 0.39826E-05 -5.3998 0.82626E+00 -0.0829 26 CH4,aq 0.80653E-02 -2.0934 0.80491E-02 -2.0943 0.99799E+00 -0.0009 27 C2H6,aq 0.95832E-09 -9.0185 0.95640E-09 -9.0194 0.99799E+00 -0.0009 28 C3H8,aq 0.26289E-14 -14.5802 0.26236E-14 -14.5811 0.99799E+00 -0.0009 30 ethanol,aq 0.35174E-16 -16.4538 0.35104E-16 -16.4546 0.99799E+00 -0.0009 31 CO,aq 0.60368E-14 -14.2192 0.60368E-14 -14.2192 0.10000E+01 0.0000 32 CO2,aq 0.20789E-07 -7.6822 0.20748E-07 -7.6830 0.99799E+00 -0.0009 33 CO3-2 0.24836E-03 -3.6049 0.12440E-03 -3.9052 0.50090E+00 -0.3003 34 CaCO3,aq 0.13443E-06 -6.8715 0.13443E-06 -6.8715 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.31178E-09 -9.5062 0.25867E-09 -9.5873 0.82965E+00 -0.0811 36 CaCl+ 0.13363E-09 -9.8741 0.11087E-09 -9.9552 0.82965E+00 -0.0811 37 CaCl2,aq 0.20939E-13 -13.6790 0.20939E-13 -13.6790 0.10000E+01 0.0000 38 CaF+ 0.13077E-11 -11.8835 0.10849E-11 -11.9646 0.82965E+00 -0.0811 39 CaOH+ 0.89651E-07 -7.0474 0.74380E-07 -7.1285 0.82965E+00 -0.0811 40 CaSO4,aq 0.92717E-15 -15.0328 0.92717E-15 -15.0328 0.10000E+01 0.0000 41 HCl,aq 0.12027E-13 -13.9198 0.12027E-13 -13.9198 0.10000E+01 0.0000 45 HF,aq 0.48737E-12 -12.3121 0.48737E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17138E-18 -18.7660 0.14189E-18 -18.8480 0.82791E+00 -0.0820 48 FeCl+ 0.56166E-16 -16.2505 0.46598E-16 -16.3316 0.82965E+00 -0.0811 51 FeF+ 0.19669E-17 -17.7062 0.16319E-17 -17.7873 0.82965E+00 -0.0811 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17596E-10 -10.7546 0.14599E-10 -10.8357 0.82965E+00 -0.0811 55 HFeO2- 0.32312E-07 -7.4906 0.26752E-07 -7.5727 0.82791E+00 -0.0820 56 FeO+ 0.12333E-16 -16.9089 0.10232E-16 -16.9900 0.82965E+00 -0.0811 58 FeO2- 0.37095E-09 -9.4307 0.30711E-09 -9.5127 0.82791E+00 -0.0820 59 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11604E-04 -4.9354 0.11581E-04 -4.9363 0.99799E+00 -0.0009 61 KCl,aq 0.20986E-08 -8.6781 0.20986E-08 -8.6781 0.10000E+01 0.0000 63 KOH,aq 0.75331E-06 -6.1230 0.75331E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.92498E-13 -13.0339 0.76580E-13 -13.1159 0.82791E+00 -0.0820 65 MgCO3,aq 0.52472E-11 -11.2801 0.52472E-11 -11.2801 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.49611E-13 -13.3044 0.41160E-13 -13.3855 0.82965E+00 -0.0811 67 MgCl+ 0.18861E-13 -13.7244 0.15648E-13 -13.8055 0.82965E+00 -0.0811 68 MgF+ 0.75436E-15 -15.1224 0.62586E-15 -15.2035 0.82965E+00 -0.0811 69 MgOH+ 0.77253E-10 -10.1121 0.64093E-10 -10.1932 0.82965E+00 -0.0811 71 MnF+ 0.20932E-15 -15.6792 0.17367E-15 -15.7603 0.82965E+00 -0.0811 72 MnO,aq 0.18163E-08 -8.7408 0.18163E-08 -8.7408 0.10000E+01 0.0000 73 MnOH+ 0.52777E-09 -9.2776 0.43787E-09 -9.3587 0.82965E+00 -0.0811 74 MnO2-2 0.17652E-10 -10.7532 0.88417E-11 -11.0535 0.50090E+00 -0.3003 75 HMnO2- 0.19317E-09 -9.7141 0.15993E-09 -9.7961 0.82791E+00 -0.0820 78 MnCl+ 0.70551E-13 -13.1515 0.58533E-13 -13.2326 0.82965E+00 -0.0811 79 MnSO4,aq 0.11695E-18 -18.9320 0.11695E-18 -18.9320 0.10000E+01 0.0000 80 NaCl,aq 0.48603E-05 -5.3133 0.48603E-05 -5.3133 0.10000E+01 0.0000 81 NaF,aq 0.37244E-08 -8.4289 0.37244E-08 -8.4289 0.10000E+01 0.0000 82 NaOH,aq 0.95991E-04 -4.0178 0.95991E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.84683E-02 -2.0722 0.69970E-02 -2.1551 0.82626E+00 -0.0829 89 HPO3-2 0.13696E-14 -14.8634 0.68605E-15 -15.1636 0.50090E+00 -0.3003 91 H2PO3- 0.13719E-18 -18.8627 0.11358E-18 -18.9447 0.82791E+00 -0.0820 92 H3PO4,aq 0.90613E-18 -18.0428 0.90613E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.34929E-10 -10.4568 0.28948E-10 -10.5384 0.82877E+00 -0.0816 94 PO4-3 0.83192E-09 -9.0799 0.18783E-09 -9.7262 0.22578E+00 -0.6463 98 HP2O7-3 0.74227E-18 -18.1294 0.15894E-18 -18.7988 0.21412E+00 -0.6693 99 P2O7-4 0.68195E-17 -17.1662 0.45989E-18 -18.3373 0.67437E-01 -1.1711 100 H2S,aq 0.61053E-06 -6.2143 0.60931E-06 -6.2152 0.99799E+00 -0.0009 101 S2-2 0.21780E-10 -10.6619 0.10910E-10 -10.9622 0.50090E+00 -0.3003 102 S3-2 0.15439E-17 -17.8114 0.77333E-18 -18.1116 0.50090E+00 -0.3003 107 SO3-2 0.10021E-15 -15.9991 0.50996E-16 -16.2925 0.50889E+00 -0.2934 108 HSO3- 0.31841E-18 -18.4970 0.26362E-18 -18.5790 0.82791E+00 -0.0820 109 HSO4- 0.32458E-17 -17.4887 0.26958E-17 -17.5693 0.83055E+00 -0.0806 111 S2O3-2 0.48421E-18 -18.3150 0.24254E-18 -18.6152 0.50090E+00 -0.3003 Charge balance for all species = -.1741E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9906258E-10 -.2069110E-01 -.2081411E+02 0.0000 2 H2O 0.1000000E+01 0.5551305E+02 0.9981051E+06 0.0000 3 Cl- 0.9602005E-03 0.9650630E-03 0.3414667E+02 6.9836 4 SO4-- 0.6748258E-10 -.8068170E-02 -.7735076E+03 9.6964 5 HCO3- 0.1418032E-03 0.8455589E-02 0.5149154E+03 6.1536 6 HS- 0.2883754E-02 0.1095253E-01 0.3615054E+03 7.4612 7 Al+++ 0.1443128E-28 0.4820136E-05 0.1297971E+00 0.7391 8 H4SiO4 0.6958662E-03 0.1255167E-01 0.1204021E+04 -3.1575 9 Ca++ 0.1730485E-06 0.4161927E-06 0.1664716E-01 13.1018 10 Mg++ 0.2708474E-10 0.1132641E-09 0.2748227E-05 9.2942 11 Fe++ 0.7465111E-13 0.3291518E-07 0.1834576E-02 6.7350 12 K+ 0.1756060E-03 0.1763614E-03 0.6882438E+01 6.2466 13 Na+ 0.2228792E-01 0.2473734E-01 0.5675811E+03 8.3492 14 Mn++ 0.2408085E-10 0.2579065E-08 0.1414083E-03 9.2441 15 F- 0.1043910E-05 0.1047636E-05 0.1986361E-01 4.0189 16 HPO4-- 0.3785063E-07 0.3871748E-07 0.3708711E-02 12.4453 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278630E+02 -.1029160E-01 -.8277601E+02 0.0000000E+00 2 H2O -.7121312E+01 0.2761178E+02 -.3473309E+02 0.0000000E+00 3 Cl- 0.4800152E-03 0.4800152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1388694E+00 -.4013048E-02 0.1428825E+00 0.0000000E+00 5 HCO3- 0.4205747E-02 0.4205747E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1374348E+00 0.5447709E-02 -.1428825E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2397500E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6243105E-02 0.5205766E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2070112E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5633671E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1637176E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8772086E-04 0.1061483E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1230417E-01 0.6264073E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1282808E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2329600E-04 0.5210866E-06 0.2277491E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1925779E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1558E-13 Mass of aqueous solution: 0.498379E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0579900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.254 0.796 1640. 3.215 30.02 629.6 andradite 0.5715 -0.243 290.4 2.463 5.317 75.46 grossular 0.1384 -0.859 62.35 1.795 1.141 17.35 apatite-OH 0.9840E-02 -2.007 4.943 0.694 0.9049E-01 1.571 apatite-F 0.2277E-04 -4.643 0.1149E-01 -1.940 0.2103E-03 0.3588E-02 clinochlore 0.7062 -0.151 392.6 2.594 7.187 149.3 daphnite 0.2045 -0.689 145.9 2.164 2.671 44.21 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1512 -0.820 32.75 1.515 0.5995 10.01 hedenbergite 0.3922E-01 -1.406 9.731 0.988 0.1781 2.665 microcline 0.9353 -0.029 260.3 2.416 4.766 101.7 stilbite 3.223 0.508 2272. 3.356 41.59 1060. stilpnomelane-Fe 0.2524 -0.598 272.0 2.435 4.980 93.97 tr.625ac.25prg.125 0.7884E-01 -1.103 67.39 1.829 1.234 21.69 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1868E-01 0.1868E-01 1.0000 -1.729 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.354212 g Volume = 2210.938154 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0579900 moles log = -1.2366 Original solution: 1000.0103000 g Original solution / Rock added: 17244.53 (Water/Rock Ratio), log = 4.2367 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 12.9934 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8058E-01 0.9606 0.1006E+01 0.1047E+01 CO2,gas 0.1751E-06 0.9755 0.2220E-05 0.2275E-05 CH4,gas 0.9183E+00 0.9930 0.1185E+02 0.1193E+02 H2,gas 0.1162E-02 1.0070 0.1520E-01 0.1510E-01 H2S,gas 0.1355E-05 0.9511 0.1675E-04 0.1761E-04 S2,gas 0.3506E-26 1.0000 0.4555E-25 0.4555E-25 CO,gas 0.6923E-12 1.0000 0.8996E-11 0.8996E-11 SO3,gas 0.6722E-47 1.0000 0.8734E-46 0.8734E-46 SO2,gas 0.3976E-26 1.0000 0.5167E-25 0.5167E-25 HF,gas 0.9210E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1633E-17 1.0000 0.2122E-16 0.2122E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.01 -7.35 -2.451 0.12554E+05 -5.654 3 CH4,gas 4.54 3.92 -0.63 -0.156 0.10677E+04 1.074 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.71 -6.47 -3.237 0.11056E+05 -4.776 6 S2,gas -7.34 -34.38 -27.04 -4.160 0.46171E+05 -25.341 7 CO,gas 3.21 -9.53 -12.74 -3.922 0.21762E+05 -11.046 8 SO3,gas 17.12 -30.64 -47.76 -11.939 0.81545E+05 -46.059 9 SO2,gas 0.83 -26.15 -26.99 -7.196 0.46077E+05 -25.287 10 HF,gas 0.47 -16.15 -16.62 -8.310 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.18 -18.37 -9.186 0.31370E+05 -16.673 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80581E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93645E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28494E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 38 aragonite 0.97 -0.91 -1.88 -0.626 0.32058E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -0.91 -1.72 -0.574 0.29416E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39696E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68943E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65506E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -5.05 -1.94 -0.556 0.33206E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37136E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -5.05 -1.50 -0.429 0.25629E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28622E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82200E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36682E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91152E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -23.16 -1.91 -0.450 0.32633E+04 146 pyrrhotite -4.26 -5.97 -1.71 -0.570 0.29195E+04 147 pyrrhotiteFe0.875 -6.02 -7.37 -1.35 -0.497 0.23067E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22403E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28671E+03 154 rhodochrosite -0.98 -4.77 -3.79 -1.264 0.64755E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23205E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.28 -4.67 -1.557 0.79733E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27808E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.76 -0.394 0.47043E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90668E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77504E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65445E+04 184 troilite-low -4.41 -5.97 -1.56 -0.520 0.26623E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60600E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60363E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83483E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35288E+04 234 alabandite -0.98 -3.46 -2.48 -0.828 0.42401E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0579900 MOLES New total amount of reactant added: 0.0599900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8657E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0599900 Water: Moles liquid = 0.2761E+02 kg liquid = 0.4974E+00 Moles total = -.7120E+01 kg total = -.1283E+00 Activity = 0.9998 Stoichiometric ionic strength = .6359131E-02 Osmotic coef. = 0.9351 True ionic strength = .2280283E-01 Chg. balance for total moles = -.8657E-10 Max. difference allowed = 0.4918E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.99429E-10 -10.0025 0.82846E-10 -10.0817 0.83322E+00 -0.0792 2 H2O 0.99985E+00 -0.0001 0.99985E+00 -0.0001 3 Cl- 0.98372E-03 -3.0071 0.81420E-03 -3.0893 0.82767E+00 -0.0821 4 SO4-- 0.69581E-10 -10.1575 0.34897E-10 -10.4572 0.50153E+00 -0.2997 5 HCO3- 0.14625E-03 -3.8349 0.12124E-03 -3.9164 0.82901E+00 -0.0814 6 HS- 0.29812E-02 -2.5256 0.24679E-02 -2.6077 0.82781E+00 -0.0821 7 Al+++ 0.14617E-28 -28.8351 0.31184E-29 -29.5061 0.21335E+00 -0.6709 8 H4SiO4 0.69586E-03 -3.1575 0.69586E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.17443E-06 -6.7584 0.86771E-07 -7.0616 0.49745E+00 -0.3033 10 Mg++ 0.27302E-10 -10.5638 0.13512E-10 -10.8693 0.49493E+00 -0.3055 11 Fe++ 0.75249E-13 -13.1235 0.37288E-13 -13.4284 0.49553E+00 -0.3049 12 K+ 0.17626E-03 -3.7539 0.14616E-03 -3.8352 0.82923E+00 -0.0813 13 Na+ 0.22370E-01 -1.6503 0.18512E-01 -1.7326 0.82750E+00 -0.0822 14 Mn++ 0.24278E-10 -10.6148 0.12042E-10 -10.9193 0.49598E+00 -0.3045 15 F- 0.10406E-05 -5.9827 0.85934E-06 -6.0658 0.82579E+00 -0.0831 16 HPO4-- 0.37633E-07 -7.4244 0.18877E-07 -7.7241 0.50161E+00 -0.2996 18 HSiO3- 0.94773E-02 -2.0233 0.78441E-02 -2.1055 0.82767E+00 -0.0821 19 Ca(HSiO3)+ 0.18689E-07 -7.7284 0.15501E-07 -7.8096 0.82943E+00 -0.0812 20 Mg(HSiO3)+ 0.36219E-11 -11.4411 0.30041E-11 -11.5223 0.82943E+00 -0.0812 21 NaHSiO3,aq 0.23485E-02 -2.6292 0.23485E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.74513E-16 -16.1278 0.61803E-16 -16.2090 0.82943E+00 -0.0812 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.48049E-05 -5.3183 0.39689E-05 -5.4013 0.82602E+00 -0.0830 26 CH4,aq 0.83438E-02 -2.0786 0.83275E-02 -2.0795 0.99805E+00 -0.0008 27 C2H6,aq 0.10257E-08 -8.9890 0.10237E-08 -8.9898 0.99805E+00 -0.0008 28 C3H8,aq 0.29111E-14 -14.5359 0.29054E-14 -14.5368 0.99805E+00 -0.0008 30 ethanol,aq 0.37648E-16 -16.4243 0.37574E-16 -16.4251 0.99805E+00 -0.0008 31 CO,aq 0.62456E-14 -14.2044 0.62456E-14 -14.2044 0.10000E+01 0.0000 32 CO2,aq 0.21508E-07 -7.6674 0.21465E-07 -7.6683 0.99805E+00 -0.0008 33 CO3-2 0.25547E-03 -3.5927 0.12783E-03 -3.8934 0.50035E+00 -0.3007 34 CaCO3,aq 0.13908E-06 -6.8567 0.13908E-06 -6.8567 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.32376E-09 -9.4898 0.26854E-09 -9.5710 0.82943E+00 -0.0812 36 CaCl+ 0.13784E-09 -9.8606 0.11433E-09 -9.9418 0.82943E+00 -0.0812 37 CaCl2,aq 0.22116E-13 -13.6553 0.22116E-13 -13.6553 0.10000E+01 0.0000 38 CaF+ 0.13126E-11 -11.8819 0.10887E-11 -11.9631 0.82943E+00 -0.0812 39 CaOH+ 0.89984E-07 -7.0458 0.74635E-07 -7.1271 0.82943E+00 -0.0812 40 CaSO4,aq 0.96153E-15 -15.0170 0.96153E-15 -15.0170 0.10000E+01 0.0000 41 HCl,aq 0.12360E-13 -13.9080 0.12360E-13 -13.9080 0.10000E+01 0.0000 45 HF,aq 0.48737E-12 -12.3121 0.48737E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17084E-18 -18.7674 0.14140E-18 -18.8495 0.82767E+00 -0.0821 48 FeCl+ 0.57937E-16 -16.2370 0.48055E-16 -16.3183 0.82943E+00 -0.0812 51 FeF+ 0.19742E-17 -17.7046 0.16375E-17 -17.7858 0.82943E+00 -0.0812 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17661E-10 -10.7530 0.14649E-10 -10.8342 0.82943E+00 -0.0812 55 HFeO2- 0.32211E-07 -7.4920 0.26660E-07 -7.5741 0.82767E+00 -0.0821 56 FeO+ 0.12379E-16 -16.9073 0.10267E-16 -16.9885 0.82943E+00 -0.0812 58 FeO2- 0.36978E-09 -9.4321 0.30606E-09 -9.5142 0.82767E+00 -0.0821 59 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11603E-04 -4.9354 0.11581E-04 -4.9363 0.99805E+00 -0.0008 61 KCl,aq 0.21568E-08 -8.6662 0.21568E-08 -8.6662 0.10000E+01 0.0000 63 KOH,aq 0.75330E-06 -6.1230 0.75330E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.95623E-13 -13.0194 0.79145E-13 -13.1016 0.82767E+00 -0.0821 65 MgCO3,aq 0.54287E-11 -11.2653 0.54287E-11 -11.2653 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.51518E-13 -13.2880 0.42730E-13 -13.3693 0.82943E+00 -0.0812 67 MgCl+ 0.19455E-13 -13.7110 0.16137E-13 -13.7922 0.82943E+00 -0.0812 68 MgF+ 0.75715E-15 -15.1208 0.62800E-15 -15.2020 0.82943E+00 -0.0812 69 MgOH+ 0.77539E-10 -10.1105 0.64313E-10 -10.1917 0.82943E+00 -0.0812 71 MnF+ 0.21014E-15 -15.6775 0.17430E-15 -15.7587 0.82943E+00 -0.0812 72 MnO,aq 0.18167E-08 -8.7407 0.18167E-08 -8.7407 0.10000E+01 0.0000 73 MnOH+ 0.52983E-09 -9.2759 0.43946E-09 -9.3571 0.82943E+00 -0.0812 74 MnO2-2 0.17554E-10 -10.7556 0.87830E-11 -11.0564 0.50035E+00 -0.3007 75 HMnO2- 0.19260E-09 -9.7153 0.15941E-09 -9.7975 0.82767E+00 -0.0821 78 MnCl+ 0.72790E-13 -13.1379 0.60374E-13 -13.2191 0.82943E+00 -0.0812 79 MnSO4,aq 0.12131E-18 -18.9161 0.12131E-18 -18.9161 0.10000E+01 0.0000 80 NaCl,aq 0.49949E-05 -5.3015 0.49949E-05 -5.3015 0.10000E+01 0.0000 81 NaF,aq 0.37243E-08 -8.4290 0.37243E-08 -8.4290 0.10000E+01 0.0000 82 NaOH,aq 0.95989E-04 -4.0178 0.95989E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.84417E-02 -2.0736 0.69731E-02 -2.1566 0.82602E+00 -0.0830 89 HPO3-2 0.13618E-14 -14.8659 0.68136E-15 -15.1666 0.50035E+00 -0.3007 91 H2PO3- 0.13676E-18 -18.8640 0.11319E-18 -18.9462 0.82767E+00 -0.0821 92 H3PO4,aq 0.90613E-18 -18.0428 0.90613E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.34819E-10 -10.4582 0.28849E-10 -10.5399 0.82854E+00 -0.0817 94 PO4-3 0.82531E-09 -9.0834 0.18591E-09 -9.7307 0.22526E+00 -0.6473 98 HP2O7-3 0.73650E-18 -18.1328 0.15731E-18 -18.8032 0.21359E+00 -0.6704 99 P2O7-4 0.67556E-17 -17.1703 0.45363E-18 -18.3433 0.67148E-01 -1.1730 100 H2S,aq 0.63312E-06 -6.1985 0.63189E-06 -6.1994 0.99805E+00 -0.0008 101 S2-2 0.23290E-10 -10.6328 0.11653E-10 -10.9336 0.50035E+00 -0.3007 102 S3-2 0.17121E-17 -17.7665 0.85664E-18 -18.0672 0.50035E+00 -0.3007 107 SO3-2 0.10332E-15 -15.9858 0.52524E-16 -16.2796 0.50836E+00 -0.2938 108 HSO3- 0.32918E-18 -18.4826 0.27245E-18 -18.5647 0.82767E+00 -0.0821 109 HSO4- 0.33555E-17 -17.4742 0.27861E-17 -17.5550 0.83032E+00 -0.0808 111 S2O3-2 0.51777E-18 -18.2859 0.25906E-18 -18.5866 0.50035E+00 -0.3007 Charge balance for all species = -.1740E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9942873E-10 -.2064162E-01 -.2076417E+02 0.0000 2 H2O 0.1000000E+01 0.5551333E+02 0.9981018E+06 0.0000 3 Cl- 0.9837171E-03 0.9887143E-03 0.3498323E+02 6.9925 4 SO4-- 0.6958052E-10 -.8346682E-02 -.8002022E+03 9.7062 5 HCO3- 0.1462469E-03 0.8745664E-02 0.5325754E+03 6.1654 6 HS- 0.2981222E-02 0.1132854E-01 0.3739128E+03 7.4741 7 Al+++ 0.1461678E-28 0.4805031E-05 0.1293893E+00 0.7391 8 H4SiO4 0.6958623E-03 0.1252175E-01 0.1201141E+04 -3.1575 9 Ca++ 0.1744323E-06 0.4226443E-06 0.1690507E-01 13.1018 10 Mg++ 0.2730174E-10 0.1139655E-09 0.2765224E-05 9.2942 11 Fe++ 0.7524927E-13 0.3281237E-07 0.1828831E-02 6.7350 12 K+ 0.1762550E-03 0.1770105E-03 0.6907708E+01 6.2465 13 Na+ 0.2237043E-01 0.2481995E-01 0.5694718E+03 8.3492 14 Mn++ 0.2427848E-10 0.2581011E-08 0.1415138E-03 9.2441 15 F- 0.1040632E-05 0.1044359E-05 0.1980130E-01 4.0159 16 HPO4-- 0.3763274E-07 0.3849288E-07 0.3687166E-02 12.4394 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278609E+02 -.1026774E-01 -.8277582E+02 0.0000000E+00 2 H2O -.7119675E+01 0.2761394E+02 -.3473361E+02 0.0000000E+00 3 Cl- 0.4918152E-03 0.4918152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1388790E+00 -.4151882E-02 0.1430309E+00 0.0000000E+00 5 HCO3- 0.4350347E-02 0.4350347E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1373957E+00 0.5635143E-02 -.1430309E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2390162E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6228682E-02 0.5205768E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2102355E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5668976E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1632183E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8805014E-04 0.1061483E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1234616E-01 0.6264031E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1283870E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2409600E-04 0.5194943E-06 0.2357651E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1914747E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1113E-13 Mass of aqueous solution: 0.498420E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0599900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.254 0.796 1640. 3.215 30.02 629.5 andradite 0.5721 -0.243 290.7 2.464 5.323 75.54 grossular 0.1386 -0.858 62.41 1.795 1.143 17.37 apatite-OH 0.9839E-02 -2.007 4.942 0.694 0.9048E-01 1.570 apatite-F 0.2358E-04 -4.628 0.1189E-01 -1.925 0.2177E-03 0.3714E-02 clinochlore 0.7061 -0.151 392.5 2.594 7.185 149.3 daphnite 0.2044 -0.689 145.9 2.164 2.670 44.20 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1474 -0.832 31.91 1.504 0.5842 9.753 hedenbergite 0.3822E-01 -1.418 9.482 0.977 0.1736 2.597 microcline 0.9355 -0.029 260.4 2.416 4.767 101.7 stilbite 3.224 0.508 2272. 3.356 41.59 1060. stilpnomelane-Fe 0.2521 -0.599 271.7 2.434 4.974 93.85 tr.625ac.25prg.125 0.8010E-01 -1.096 68.47 1.835 1.253 22.04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1869E-01 0.1869E-01 1.0000 -1.728 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.354704 g Volume = 2210.943699 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0599900 moles log = -1.2219 Original solution: 1000.0103000 g Original solution / Rock added: 16669.62 (Water/Rock Ratio), log = 4.2219 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 13.4102 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7812E-01 0.9601 0.1006E+01 0.1048E+01 CO2,gas 0.1757E-06 0.9749 0.2297E-05 0.2356E-05 CH4,gas 0.9208E+00 0.9927 0.1226E+02 0.1235E+02 H2,gas 0.1126E-02 1.0072 0.1520E-01 0.1510E-01 H2S,gas 0.1364E-05 0.9496 0.1737E-04 0.1829E-04 S2,gas 0.3653E-26 1.0000 0.4899E-25 0.4899E-25 CO,gas 0.6940E-12 1.0000 0.9307E-11 0.9307E-11 SO3,gas 0.6754E-47 1.0000 0.9057E-46 0.9057E-46 SO2,gas 0.3996E-26 1.0000 0.5358E-25 0.5358E-25 HF,gas 0.8923E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1626E-17 1.0000 0.2181E-16 0.2181E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28966E+04 0.003 2 CO2,gas -6.66 -14.00 -7.34 -2.446 0.12529E+05 -5.639 3 CH4,gas 4.54 3.93 -0.61 -0.153 0.10425E+04 1.088 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.69 -6.46 -3.230 0.11029E+05 -4.760 6 S2,gas -7.34 -34.34 -27.01 -4.155 0.46117E+05 -25.310 7 CO,gas 3.21 -9.52 -12.73 -3.917 0.21736E+05 -11.031 8 SO3,gas 17.12 -30.62 -47.74 -11.935 0.81518E+05 -46.043 9 SO2,gas 0.83 -26.14 -26.97 -7.192 0.46050E+05 -25.271 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.17 -18.36 -9.180 0.31350E+05 -16.661 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80577E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93646E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28494E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 38 aragonite 0.97 -0.90 -1.86 -0.621 0.31806E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -0.90 -1.71 -0.569 0.29164E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39696E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68943E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65504E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -5.03 -1.93 -0.551 0.32954E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37136E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -5.03 -1.49 -0.425 0.25377E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28622E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82198E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36682E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91152E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -23.13 -1.88 -0.442 0.32094E+04 146 pyrrhotite -4.26 -5.95 -1.69 -0.565 0.28926E+04 147 pyrrhotiteFe0.875 -6.02 -7.35 -1.34 -0.491 0.22798E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22401E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28670E+03 154 rhodochrosite -0.98 -4.75 -3.78 -1.259 0.64502E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23204E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.26 -4.65 -1.552 0.79481E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27808E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.394 0.47040E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90668E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77504E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65445E+04 184 troilite-low -4.41 -5.95 -1.54 -0.514 0.26354E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60600E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68814E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58213E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.45 -2.47 -0.822 0.42130E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0599900 MOLES New total amount of reactant added: 0.0619900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8655E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0619900 Water: Moles liquid = 0.2761E+02 kg liquid = 0.4975E+00 Moles total = -.7118E+01 kg total = -.1282E+00 Activity = 0.9998 Stoichiometric ionic strength = .6188450E-02 Osmotic coef. = 0.9359 True ionic strength = .2289314E-01 Chg. balance for total moles = -.8655E-10 Max. difference allowed = 0.5036E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.99795E-10 -10.0009 0.83129E-10 -10.0802 0.83300E+00 -0.0794 2 H2O 0.99984E+00 -0.0001 0.99984E+00 -0.0001 3 Cl- 0.10072E-02 -2.9969 0.83342E-03 -3.0791 0.82744E+00 -0.0823 4 SO4-- 0.71667E-10 -10.1447 0.35904E-10 -10.4449 0.50099E+00 -0.3002 5 HCO3- 0.15066E-03 -3.8220 0.12487E-03 -3.9035 0.82879E+00 -0.0816 6 HS- 0.30787E-02 -2.5116 0.25478E-02 -2.5938 0.82758E+00 -0.0822 7 Al+++ 0.14804E-28 -28.8296 0.31506E-29 -29.5016 0.21282E+00 -0.6720 8 H4SiO4 0.69586E-03 -3.1575 0.69586E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.17582E-06 -6.7549 0.87366E-07 -7.0587 0.49690E+00 -0.3037 10 Mg++ 0.27520E-10 -10.5604 0.13605E-10 -10.8663 0.49437E+00 -0.3059 11 Fe++ 0.75851E-13 -13.1200 0.37544E-13 -13.4255 0.49497E+00 -0.3054 12 K+ 0.17690E-03 -3.7523 0.14665E-03 -3.8337 0.82900E+00 -0.0814 13 Na+ 0.22453E-01 -1.6487 0.18575E-01 -1.7311 0.82727E+00 -0.0824 14 Mn++ 0.24477E-10 -10.6112 0.12127E-10 -10.9163 0.49543E+00 -0.3050 15 F- 0.10374E-05 -5.9841 0.85641E-06 -6.0673 0.82555E+00 -0.0833 16 HPO4-- 0.37417E-07 -7.4269 0.18748E-07 -7.7270 0.50107E+00 -0.3001 18 HSiO3- 0.94476E-02 -2.0247 0.78174E-02 -2.1069 0.82744E+00 -0.0823 19 Ca(HSiO3)+ 0.18758E-07 -7.7268 0.15554E-07 -7.8082 0.82920E+00 -0.0813 20 Mg(HSiO3)+ 0.36353E-11 -11.4395 0.30144E-11 -11.5208 0.82920E+00 -0.0813 21 NaHSiO3,aq 0.23485E-02 -2.6292 0.23485E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.74789E-16 -16.1262 0.62015E-16 -16.2075 0.82920E+00 -0.0813 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.47899E-05 -5.3197 0.39554E-05 -5.4028 0.82579E+00 -0.0831 26 CH4,aq 0.86224E-02 -2.0644 0.86060E-02 -2.0652 0.99810E+00 -0.0008 27 C2H6,aq 0.10954E-08 -8.9604 0.10933E-08 -8.9613 0.99810E+00 -0.0008 28 C3H8,aq 0.32129E-14 -14.4931 0.32068E-14 -14.4939 0.99810E+00 -0.0008 30 ethanol,aq 0.40206E-16 -16.3957 0.40129E-16 -16.3965 0.99810E+00 -0.0008 31 CO,aq 0.64545E-14 -14.1901 0.64545E-14 -14.1901 0.10000E+01 0.0000 32 CO2,aq 0.22226E-07 -7.6531 0.22184E-07 -7.6540 0.99810E+00 -0.0008 33 CO3-2 0.26251E-03 -3.5809 0.13120E-03 -3.8821 0.49981E+00 -0.3012 34 CaCO3,aq 0.14373E-06 -6.8425 0.14373E-06 -6.8425 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.33583E-09 -9.4739 0.27847E-09 -9.5552 0.82920E+00 -0.0813 36 CaCl+ 0.14211E-09 -9.8474 0.11783E-09 -9.9287 0.82920E+00 -0.0813 37 CaCl2,aq 0.23332E-13 -13.6321 0.23332E-13 -13.6321 0.10000E+01 0.0000 38 CaF+ 0.13174E-11 -11.8803 0.10924E-11 -11.9616 0.82920E+00 -0.0813 39 CaOH+ 0.90316E-07 -7.0442 0.74890E-07 -7.1256 0.82920E+00 -0.0813 40 CaSO4,aq 0.99609E-15 -15.0017 0.99609E-15 -15.0017 0.10000E+01 0.0000 41 HCl,aq 0.12696E-13 -13.8963 0.12696E-13 -13.8963 0.10000E+01 0.0000 45 HF,aq 0.48736E-12 -12.3121 0.48736E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.17031E-18 -18.7688 0.14092E-18 -18.8510 0.82744E+00 -0.0823 48 FeCl+ 0.59729E-16 -16.2238 0.49527E-16 -16.3052 0.82920E+00 -0.0813 51 FeF+ 0.19815E-17 -17.7030 0.16431E-17 -17.7843 0.82920E+00 -0.0813 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17727E-10 -10.7514 0.14699E-10 -10.8327 0.82920E+00 -0.0813 55 HFeO2- 0.32109E-07 -7.4934 0.26569E-07 -7.5756 0.82744E+00 -0.0823 56 FeO+ 0.12425E-16 -16.9057 0.10303E-16 -16.9871 0.82920E+00 -0.0813 58 FeO2- 0.36862E-09 -9.4334 0.30501E-09 -9.5157 0.82744E+00 -0.0823 59 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11603E-04 -4.9354 0.11581E-04 -4.9363 0.99810E+00 -0.0008 61 KCl,aq 0.22152E-08 -8.6546 0.22152E-08 -8.6546 0.10000E+01 0.0000 63 KOH,aq 0.75328E-06 -6.1230 0.75328E-06 -6.1230 0.10000E+01 0.0000 64 KSO4- 0.98748E-13 -13.0055 0.81708E-13 -13.0877 0.82744E+00 -0.0823 65 MgCO3,aq 0.56102E-11 -11.2510 0.56102E-11 -11.2510 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.53438E-13 -13.2721 0.44311E-13 -13.3535 0.82920E+00 -0.0813 67 MgCl+ 0.20057E-13 -13.6977 0.16631E-13 -13.7791 0.82920E+00 -0.0813 68 MgF+ 0.75995E-15 -15.1192 0.63015E-15 -15.2006 0.82920E+00 -0.0813 69 MgOH+ 0.77826E-10 -10.1089 0.64533E-10 -10.1902 0.82920E+00 -0.0813 71 MnF+ 0.21096E-15 -15.6758 0.17493E-15 -15.7571 0.82920E+00 -0.0813 72 MnO,aq 0.18170E-08 -8.7406 0.18170E-08 -8.7406 0.10000E+01 0.0000 73 MnOH+ 0.53190E-09 -9.2742 0.44105E-09 -9.3555 0.82920E+00 -0.0813 74 MnO2-2 0.17456E-10 -10.7580 0.87248E-11 -11.0592 0.49981E+00 -0.3012 75 HMnO2- 0.19204E-09 -9.7166 0.15890E-09 -9.7989 0.82744E+00 -0.0823 78 MnCl+ 0.75056E-13 -13.1246 0.62237E-13 -13.2060 0.82920E+00 -0.0813 79 MnSO4,aq 0.12570E-18 -18.9007 0.12570E-18 -18.9007 0.10000E+01 0.0000 80 NaCl,aq 0.51303E-05 -5.2899 0.51303E-05 -5.2899 0.10000E+01 0.0000 81 NaF,aq 0.37242E-08 -8.4290 0.37242E-08 -8.4290 0.10000E+01 0.0000 82 NaOH,aq 0.95987E-04 -4.0178 0.95987E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.84153E-02 -2.0749 0.69492E-02 -2.1581 0.82579E+00 -0.0831 89 HPO3-2 0.13540E-14 -14.8684 0.67671E-15 -15.1696 0.49981E+00 -0.3012 91 H2PO3- 0.13633E-18 -18.8654 0.11281E-18 -18.9477 0.82744E+00 -0.0823 92 H3PO4,aq 0.90613E-18 -18.0428 0.90613E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.34710E-10 -10.4595 0.28751E-10 -10.5414 0.82831E+00 -0.0818 94 PO4-3 0.81877E-09 -9.0868 0.18401E-09 -9.7352 0.22474E+00 -0.6483 98 HP2O7-3 0.73078E-18 -18.1362 0.15571E-18 -18.8077 0.21307E+00 -0.6715 99 P2O7-4 0.66925E-17 -17.1744 0.44747E-18 -18.3492 0.66861E-01 -1.1748 100 H2S,aq 0.65584E-06 -6.1832 0.65459E-06 -6.1840 0.99810E+00 -0.0008 101 S2-2 0.24851E-10 -10.6047 0.12421E-10 -10.9059 0.49981E+00 -0.3012 102 S3-2 0.18925E-17 -17.7230 0.94587E-18 -18.0242 0.49981E+00 -0.3012 107 SO3-2 0.10641E-15 -15.9730 0.54041E-16 -16.2673 0.50783E+00 -0.2943 108 HSO3- 0.33994E-18 -18.4686 0.28128E-18 -18.5509 0.82744E+00 -0.0823 109 HSO4- 0.34651E-17 -17.4603 0.28764E-17 -17.5411 0.83010E+00 -0.0809 111 S2O3-2 0.55246E-18 -18.2577 0.27613E-18 -18.5589 0.49981E+00 -0.3012 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9979533E-10 -.2059238E-01 -.2071446E+02 0.0000 2 H2O 0.1000000E+01 0.5551361E+02 0.9980985E+06 0.0000 3 Cl- 0.1007229E-02 0.1012362E-02 0.3581965E+02 7.0011 4 SO4-- 0.7166712E-10 -.8625261E-02 -.8269029E+03 9.7156 5 HCO3- 0.1506641E-03 0.9035697E-02 0.5502327E+03 6.1767 6 HS- 0.3078676E-02 0.1170459E-01 0.3863218E+03 7.4864 7 Al+++ 0.1480421E-28 0.4790010E-05 0.1289837E+00 0.7391 8 H4SiO4 0.6958583E-03 0.1249200E-01 0.1198278E+04 -3.1575 9 Ca++ 0.1758238E-06 0.4291057E-06 0.1716338E-01 13.1018 10 Mg++ 0.2751995E-10 0.1146651E-09 0.2782175E-05 9.2942 11 Fe++ 0.7585074E-13 0.3271014E-07 0.1823118E-02 6.7350 12 K+ 0.1769048E-03 0.1776603E-03 0.6933009E+01 6.2465 13 Na+ 0.2245305E-01 0.2490266E-01 0.5713647E+03 8.3492 14 Mn++ 0.2447725E-10 0.2582966E-08 0.1416198E-03 9.2442 15 F- 0.1037373E-05 0.1041099E-05 0.1973933E-01 4.0129 16 HPO4-- 0.3741664E-07 0.3827012E-07 0.3665797E-02 12.4335 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278587E+02 -.1024400E-01 -.8277563E+02 0.0000000E+00 2 H2O -.7118038E+01 0.2761610E+02 -.3473414E+02 0.0000000E+00 3 Cl- 0.5036152E-03 0.5036152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1388885E+00 -.4290770E-02 0.1431793E+00 0.0000000E+00 5 HCO3- 0.4494947E-02 0.4494947E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1373567E+00 0.5822631E-02 -.1431793E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2382865E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6214339E-02 0.5205769E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2134653E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5704193E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1627217E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8837986E-04 0.1061483E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1238822E-01 0.6263989E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1284936E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2489600E-04 0.5179108E-06 0.2437809E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1903806E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.8465E-15 Mass of aqueous solution: 0.498460E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0619900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.254 0.796 1640. 3.215 30.02 629.5 andradite 0.5727 -0.242 291.0 2.464 5.328 75.62 grossular 0.1387 -0.858 62.48 1.796 1.144 17.38 apatite-OH 0.9838E-02 -2.007 4.942 0.694 0.9047E-01 1.570 apatite-F 0.2438E-04 -4.613 0.1229E-01 -1.910 0.2251E-03 0.3841E-02 clinochlore 0.7060 -0.151 392.4 2.594 7.184 149.3 daphnite 0.2044 -0.690 145.8 2.164 2.670 44.19 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1435 -0.843 31.07 1.492 0.5689 9.497 hedenbergite 0.3722E-01 -1.429 9.233 0.965 0.1690 2.529 microcline 0.9356 -0.029 260.4 2.416 4.768 101.7 stilbite 3.224 0.508 2272. 3.356 41.59 1060. stilpnomelane-Fe 0.2517 -0.599 271.4 2.434 4.968 93.74 tr.625ac.25prg.125 0.8136E-01 -1.090 69.54 1.842 1.273 22.38 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1869E-01 0.1869E-01 1.0000 -1.728 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.355191 g Volume = 2210.949246 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0619900 moles log = -1.2077 Original solution: 1000.0103000 g Original solution / Rock added: 16131.80 (Water/Rock Ratio), log = 4.2077 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 13.8273 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7580E-01 0.9596 0.1006E+01 0.1048E+01 CO2,gas 0.1762E-06 0.9742 0.2373E-05 0.2436E-05 CH4,gas 0.9231E+00 0.9924 0.1267E+02 0.1276E+02 H2,gas 0.1091E-02 1.0074 0.1520E-01 0.1509E-01 H2S,gas 0.1373E-05 0.9481 0.1799E-04 0.1898E-04 S2,gas 0.3802E-26 1.0000 0.5258E-25 0.5258E-25 CO,gas 0.6956E-12 1.0000 0.9619E-11 0.9619E-11 SO3,gas 0.6786E-47 1.0000 0.9383E-46 0.9383E-46 SO2,gas 0.4014E-26 1.0000 0.5551E-25 0.5551E-25 HF,gas 0.8654E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1620E-17 1.0000 0.2240E-16 0.2240E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.003 2 CO2,gas -6.66 -13.98 -7.32 -2.441 0.12505E+05 -5.625 3 CH4,gas 4.54 3.95 -0.60 -0.149 0.10181E+04 1.103 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.67 -6.44 -3.222 0.11003E+05 -4.745 6 S2,gas -7.34 -34.31 -26.98 -4.150 0.46064E+05 -25.279 7 CO,gas 3.21 -9.50 -12.72 -3.913 0.21712E+05 -11.017 8 SO3,gas 17.12 -30.61 -47.73 -11.932 0.81492E+05 -46.028 9 SO2,gas 0.83 -26.12 -26.95 -7.188 0.46024E+05 -25.256 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.16 -18.35 -9.174 0.31330E+05 -16.650 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80572E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93647E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28494E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 38 aragonite 0.97 -0.88 -1.85 -0.616 0.31562E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -0.88 -1.69 -0.565 0.28920E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39696E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68944E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65503E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -5.02 -1.92 -0.547 0.32710E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37136E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -5.02 -1.47 -0.421 0.25133E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28622E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82197E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36682E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91152E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -23.10 -1.85 -0.435 0.31570E+04 146 pyrrhotite -4.26 -5.94 -1.68 -0.560 0.28664E+04 147 pyrrhotiteFe0.875 -6.02 -7.34 -1.32 -0.485 0.22536E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22400E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28670E+03 154 rhodochrosite -0.98 -4.74 -3.76 -1.254 0.64256E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23202E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.25 -4.64 -1.547 0.79237E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27808E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.394 0.47037E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90668E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77504E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65444E+04 184 troilite-low -4.41 -5.94 -1.53 -0.509 0.26092E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60600E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58212E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.43 -2.45 -0.817 0.41867E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0619900 MOLES New total amount of reactant added: 0.0639900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8655E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0639900 Water: Moles liquid = 0.2762E+02 kg liquid = 0.4975E+00 Moles total = -.7116E+01 kg total = -.1282E+00 Activity = 0.9998 Stoichiometric ionic strength = .6017693E-02 Osmotic coef. = 0.9367 True ionic strength = .2298346E-01 Chg. balance for total moles = -.8655E-10 Max. difference allowed = 0.5154E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10016E-09 -9.9993 0.83414E-10 -10.0788 0.83278E+00 -0.0795 2 H2O 0.99984E+00 -0.0001 0.99984E+00 -0.0001 3 Cl- 0.10307E-02 -2.9869 0.85264E-03 -3.0692 0.82721E+00 -0.0824 4 SO4-- 0.73742E-10 -10.1323 0.36904E-10 -10.4329 0.50045E+00 -0.3006 5 HCO3- 0.15506E-03 -3.8095 0.12847E-03 -3.8912 0.82856E+00 -0.0817 6 HS- 0.31761E-02 -2.4981 0.26277E-02 -2.5804 0.82734E+00 -0.0823 7 Al+++ 0.14994E-28 -28.8241 0.31831E-29 -29.4972 0.21230E+00 -0.6731 8 H4SiO4 0.69585E-03 -3.1575 0.69585E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.17722E-06 -6.7515 0.87964E-07 -7.0557 0.49635E+00 -0.3042 10 Mg++ 0.27739E-10 -10.5569 0.13698E-10 -10.8633 0.49382E+00 -0.3064 11 Fe++ 0.76456E-13 -13.1166 0.37801E-13 -13.4225 0.49442E+00 -0.3059 12 K+ 0.17756E-03 -3.7507 0.14715E-03 -3.8322 0.82877E+00 -0.0816 13 Na+ 0.22536E-01 -1.6471 0.18638E-01 -1.7296 0.82704E+00 -0.0825 14 Mn++ 0.24677E-10 -10.6077 0.12212E-10 -10.9132 0.49488E+00 -0.3055 15 F- 0.10341E-05 -5.9854 0.85349E-06 -6.0688 0.82532E+00 -0.0834 16 HPO4-- 0.37202E-07 -7.4294 0.18621E-07 -7.7300 0.50053E+00 -0.3006 18 HSiO3- 0.94181E-02 -2.0260 0.77907E-02 -2.1084 0.82721E+00 -0.0824 19 Ca(HSiO3)+ 0.18827E-07 -7.7252 0.15607E-07 -7.8067 0.82897E+00 -0.0815 20 Mg(HSiO3)+ 0.36487E-11 -11.4379 0.30247E-11 -11.5193 0.82897E+00 -0.0815 21 NaHSiO3,aq 0.23485E-02 -2.6292 0.23485E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.75065E-16 -16.1246 0.62227E-16 -16.2060 0.82897E+00 -0.0815 24 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.47749E-05 -5.3210 0.39419E-05 -5.4043 0.82555E+00 -0.0833 26 CH4,aq 0.89010E-02 -2.0506 0.88845E-02 -2.0514 0.99815E+00 -0.0008 27 C2H6,aq 0.11674E-08 -8.9328 0.11653E-08 -8.9336 0.99815E+00 -0.0008 28 C3H8,aq 0.35350E-14 -14.4516 0.35284E-14 -14.4524 0.99815E+00 -0.0008 29 C4H10,aq 0.10515E-19 -19.9782 0.10496E-19 -19.9790 0.99815E+00 -0.0008 30 ethanol,aq 0.42849E-16 -16.3681 0.42770E-16 -16.3689 0.99815E+00 -0.0008 31 CO,aq 0.66636E-14 -14.1763 0.66636E-14 -14.1763 0.10000E+01 0.0000 32 CO2,aq 0.22944E-07 -7.6393 0.22902E-07 -7.6401 0.99815E+00 -0.0008 33 CO3-2 0.26945E-03 -3.5695 0.13453E-03 -3.8712 0.49927E+00 -0.3017 34 CaCO3,aq 0.14838E-06 -6.8286 0.14838E-06 -6.8286 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.34798E-09 -9.4584 0.28847E-09 -9.5399 0.82897E+00 -0.0815 36 CaCl+ 0.14642E-09 -9.8344 0.12138E-09 -9.9159 0.82897E+00 -0.0815 37 CaCl2,aq 0.24587E-13 -13.6093 0.24587E-13 -13.6093 0.10000E+01 0.0000 38 CaF+ 0.13223E-11 -11.8787 0.10961E-11 -11.9601 0.82897E+00 -0.0815 39 CaOH+ 0.90649E-07 -7.0426 0.75146E-07 -7.1241 0.82897E+00 -0.0815 40 CaSO4,aq 0.10308E-14 -14.9868 0.10308E-14 -14.9868 0.10000E+01 0.0000 41 HCl,aq 0.13033E-13 -13.8850 0.13033E-13 -13.8850 0.10000E+01 0.0000 45 HF,aq 0.48736E-12 -12.3121 0.48736E-12 -12.3121 0.10000E+01 0.0000 46 HF2- 0.16977E-18 -18.7701 0.14044E-18 -18.8525 0.82721E+00 -0.0824 48 FeCl+ 0.61541E-16 -16.2108 0.51016E-16 -16.2923 0.82897E+00 -0.0815 51 FeF+ 0.19888E-17 -17.7014 0.16487E-17 -17.7829 0.82897E+00 -0.0815 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17792E-10 -10.7498 0.14749E-10 -10.8312 0.82897E+00 -0.0815 55 HFeO2- 0.32009E-07 -7.4947 0.26478E-07 -7.5771 0.82721E+00 -0.0824 56 FeO+ 0.12471E-16 -16.9041 0.10338E-16 -16.9856 0.82897E+00 -0.0815 58 FeO2- 0.36747E-09 -9.4348 0.30397E-09 -9.5172 0.82721E+00 -0.0824 59 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11602E-04 -4.9355 0.11581E-04 -4.9363 0.99815E+00 -0.0008 61 KCl,aq 0.22740E-08 -8.6432 0.22740E-08 -8.6432 0.10000E+01 0.0000 63 KOH,aq 0.75327E-06 -6.1231 0.75327E-06 -6.1231 0.10000E+01 0.0000 64 KSO4- 0.10187E-12 -12.9919 0.84269E-13 -13.0743 0.82721E+00 -0.0824 65 MgCO3,aq 0.57919E-11 -11.2372 0.57919E-11 -11.2372 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.55372E-13 -13.2567 0.45902E-13 -13.3382 0.82897E+00 -0.0815 67 MgCl+ 0.20665E-13 -13.6848 0.17131E-13 -13.7662 0.82897E+00 -0.0815 68 MgF+ 0.76275E-15 -15.1176 0.63230E-15 -15.1991 0.82897E+00 -0.0815 69 MgOH+ 0.78113E-10 -10.1073 0.64753E-10 -10.1887 0.82897E+00 -0.0815 71 MnF+ 0.21178E-15 -15.6741 0.17556E-15 -15.7556 0.82897E+00 -0.0815 72 MnO,aq 0.18174E-08 -8.7406 0.18174E-08 -8.7406 0.10000E+01 0.0000 73 MnOH+ 0.53397E-09 -9.2725 0.44264E-09 -9.3539 0.82897E+00 -0.0815 74 MnO2-2 0.17360E-10 -10.7605 0.86671E-11 -11.0621 0.49927E+00 -0.3017 75 HMnO2- 0.19147E-09 -9.7179 0.15839E-09 -9.8003 0.82721E+00 -0.0824 78 MnCl+ 0.77349E-13 -13.1115 0.64120E-13 -13.1930 0.82897E+00 -0.0815 79 MnSO4,aq 0.13011E-18 -18.8857 0.13011E-18 -18.8857 0.10000E+01 0.0000 80 NaCl,aq 0.52664E-05 -5.2785 0.52664E-05 -5.2785 0.10000E+01 0.0000 81 NaF,aq 0.37242E-08 -8.4290 0.37242E-08 -8.4290 0.10000E+01 0.0000 82 NaOH,aq 0.95985E-04 -4.0178 0.95985E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.83890E-02 -2.0763 0.69255E-02 -2.1595 0.82555E+00 -0.0833 89 HPO3-2 0.13462E-14 -14.8709 0.67211E-15 -15.1726 0.49927E+00 -0.3017 91 H2PO3- 0.13591E-18 -18.8668 0.11242E-18 -18.9491 0.82721E+00 -0.0824 92 H3PO4,aq 0.90613E-18 -18.0428 0.90613E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.34601E-10 -10.4609 0.28653E-10 -10.5428 0.82808E+00 -0.0819 94 PO4-3 0.81230E-09 -9.0903 0.18213E-09 -9.7396 0.22422E+00 -0.6493 98 HP2O7-3 0.72513E-18 -18.1396 0.15412E-18 -18.8121 0.21254E+00 -0.6726 99 P2O7-4 0.66301E-17 -17.1785 0.44141E-18 -18.3552 0.66576E-01 -1.1767 100 H2S,aq 0.67869E-06 -6.1683 0.67743E-06 -6.1691 0.99815E+00 -0.0008 101 S2-2 0.26463E-10 -10.5774 0.13212E-10 -10.8790 0.49927E+00 -0.3017 102 S3-2 0.20855E-17 -17.6808 0.10412E-17 -17.9824 0.49927E+00 -0.3017 107 SO3-2 0.10949E-15 -15.9606 0.55546E-16 -16.2553 0.50731E+00 -0.2947 108 HSO3- 0.35070E-18 -18.4551 0.29010E-18 -18.5375 0.82721E+00 -0.0824 109 HSO4- 0.35748E-17 -17.4468 0.29666E-17 -17.5277 0.82987E+00 -0.0810 111 S2O3-2 0.58830E-18 -18.2304 0.29372E-18 -18.5321 0.49927E+00 -0.3017 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1001624E-09 -.2054336E-01 -.2066498E+02 0.0000 2 H2O 0.1000000E+01 0.5551389E+02 0.9980952E+06 0.0000 3 Cl- 0.1030738E-02 0.1036006E-02 0.3665593E+02 7.0095 4 SO4-- 0.7374246E-10 -.8903907E-02 -.8536094E+03 9.7246 5 HCO3- 0.1550551E-03 0.9325687E-02 0.5678870E+03 6.1876 6 HS- 0.3176116E-02 0.1208070E-01 0.3987323E+03 7.4983 7 Al+++ 0.1499357E-28 0.4775073E-05 0.1285804E+00 0.7391 8 H4SiO4 0.6958544E-03 0.1246242E-01 0.1195430E+04 -3.1575 9 Ca++ 0.1772229E-06 0.4355772E-06 0.1742208E-01 13.1018 10 Mg++ 0.2773937E-10 0.1153699E-09 0.2799252E-05 9.2942 11 Fe++ 0.7645553E-13 0.3260848E-07 0.1817436E-02 6.7350 12 K+ 0.1775554E-03 0.1783109E-03 0.6958341E+01 6.2465 13 Na+ 0.2253577E-01 0.2498548E-01 0.5732601E+03 8.3492 14 Mn++ 0.2467717E-10 0.2584929E-08 0.1417262E-03 9.2443 15 F- 0.1034131E-05 0.1037857E-05 0.1967770E-01 4.0100 16 HPO4-- 0.3720229E-07 0.3804919E-07 0.3644605E-02 12.4275 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278566E+02 -.1022036E-01 -.8277544E+02 0.0000000E+00 2 H2O -.7116400E+01 0.2761827E+02 -.3473467E+02 0.0000000E+00 3 Cl- 0.5154152E-03 0.5154152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1388981E+00 -.4429710E-02 0.1433278E+00 0.0000000E+00 5 HCO3- 0.4639547E-02 0.4639547E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1373176E+00 0.6010172E-02 -.1433278E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2375608E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6200076E-02 0.5205770E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2167005E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5739675E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1622278E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8871002E-04 0.1061482E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1243032E-01 0.6263947E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1286007E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2569600E-04 0.5163360E-06 0.2517966E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1892954E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.2692E-14 Mass of aqueous solution: 0.498501E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0639900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.254 0.796 1640. 3.215 30.02 629.5 andradite 0.5733 -0.242 291.3 2.464 5.334 75.69 grossular 0.1388 -0.857 62.54 1.796 1.145 17.40 apatite-OH 0.9837E-02 -2.007 4.942 0.694 0.9047E-01 1.570 apatite-F 0.2518E-04 -4.599 0.1270E-01 -1.896 0.2325E-03 0.3967E-02 clinochlore 0.7058 -0.151 392.3 2.594 7.182 149.2 daphnite 0.2044 -0.690 145.8 2.164 2.669 44.19 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1396 -0.855 30.24 1.481 0.5535 9.241 hedenbergite 0.3621E-01 -1.441 8.984 0.953 0.1645 2.461 microcline 0.9358 -0.029 260.5 2.416 4.768 101.7 stilbite 3.224 0.508 2272. 3.356 41.59 1060. stilpnomelane-Fe 0.2514 -0.600 271.0 2.433 4.962 93.62 tr.625ac.25prg.125 0.8262E-01 -1.083 70.62 1.849 1.293 22.73 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1869E-01 0.1869E-01 1.0000 -1.728 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.355675 g Volume = 2210.954794 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0639900 moles log = -1.1939 Original solution: 1000.0103000 g Original solution / Rock added: 15627.60 (Water/Rock Ratio), log = 4.1939 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 14.2447 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7362E-01 0.9591 0.1006E+01 0.1049E+01 CO2,gas 0.1767E-06 0.9735 0.2450E-05 0.2517E-05 CH4,gas 0.9253E+00 0.9921 0.1308E+02 0.1318E+02 H2,gas 0.1059E-02 1.0076 0.1520E-01 0.1509E-01 H2S,gas 0.1381E-05 0.9466 0.1862E-04 0.1967E-04 S2,gas 0.3953E-26 1.0000 0.5631E-25 0.5631E-25 CO,gas 0.6971E-12 1.0000 0.9930E-11 0.9930E-11 SO3,gas 0.6817E-47 1.0000 0.9710E-46 0.9710E-46 SO2,gas 0.4033E-26 1.0000 0.5745E-25 0.5745E-25 HF,gas 0.8401E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1614E-17 1.0000 0.2300E-16 0.2300E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.003 2 CO2,gas -6.66 -13.97 -7.31 -2.437 0.12481E+05 -5.611 3 CH4,gas 4.54 3.96 -0.58 -0.146 0.99451E+03 1.117 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.66 -6.43 -3.214 0.10977E+05 -4.730 6 S2,gas -7.34 -34.28 -26.95 -4.146 0.46014E+05 -25.249 7 CO,gas 3.21 -9.49 -12.70 -3.908 0.21688E+05 -11.003 8 SO3,gas 17.12 -30.59 -47.71 -11.928 0.81467E+05 -46.013 9 SO2,gas 0.83 -26.11 -26.94 -7.184 0.45999E+05 -25.241 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.15 -18.34 -9.169 0.31310E+05 -16.638 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80568E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93647E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28494E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 38 aragonite 0.97 -0.87 -1.83 -0.612 0.31326E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -0.87 -1.68 -0.560 0.28684E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39696E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68944E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65501E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -5.00 -1.90 -0.543 0.32474E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37136E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -5.00 -1.46 -0.417 0.24896E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28622E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82195E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36682E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91152E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -23.07 -1.82 -0.428 0.31061E+04 146 pyrrhotite -4.26 -5.92 -1.66 -0.555 0.28409E+04 147 pyrrhotiteFe0.875 -6.02 -7.32 -1.30 -0.480 0.22281E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22398E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84957E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28670E+03 154 rhodochrosite -0.98 -4.73 -3.75 -1.250 0.64018E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23201E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.23 -4.63 -1.542 0.79001E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27809E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.394 0.47035E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90667E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77505E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65444E+04 184 troilite-low -4.41 -5.92 -1.51 -0.504 0.25837E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60599E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58212E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.41 -2.44 -0.812 0.41611E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0639900 MOLES New total amount of reactant added: 0.0659900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8654E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0659900 Water: Moles liquid = 0.2762E+02 kg liquid = 0.4975E+00 Moles total = -.7115E+01 kg total = -.1282E+00 Activity = 0.9998 Stoichiometric ionic strength = .5846862E-02 Osmotic coef. = 0.9375 True ionic strength = .2307380E-01 Chg. balance for total moles = -.8654E-10 Max. difference allowed = 0.5272E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10053E-09 -9.9977 0.83698E-10 -10.0773 0.83257E+00 -0.0796 2 H2O 0.99983E+00 -0.0001 0.99983E+00 -0.0001 3 Cl- 0.10542E-02 -2.9771 0.87184E-03 -3.0596 0.82698E+00 -0.0825 4 SO4-- 0.75807E-10 -10.1203 0.37897E-10 -10.4214 0.49991E+00 -0.3011 5 HCO3- 0.15942E-03 -3.7975 0.13205E-03 -3.8793 0.82833E+00 -0.0818 6 HS- 0.32735E-02 -2.4850 0.27076E-02 -2.5674 0.82711E+00 -0.0824 7 Al+++ 0.15185E-28 -28.8186 0.32158E-29 -29.4927 0.21177E+00 -0.6741 8 H4SiO4 0.69585E-03 -3.1575 0.69585E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.17863E-06 -6.7480 0.88565E-07 -7.0527 0.49580E+00 -0.3047 10 Mg++ 0.27960E-10 -10.5535 0.13792E-10 -10.8604 0.49327E+00 -0.3069 11 Fe++ 0.77064E-13 -13.1132 0.38060E-13 -13.4195 0.49387E+00 -0.3064 12 K+ 0.17821E-03 -3.7491 0.14765E-03 -3.8308 0.82855E+00 -0.0817 13 Na+ 0.22619E-01 -1.6455 0.18701E-01 -1.7281 0.82681E+00 -0.0826 14 Mn++ 0.24878E-10 -10.6042 0.12298E-10 -10.9102 0.49433E+00 -0.3060 15 F- 0.10309E-05 -5.9868 0.85058E-06 -6.0703 0.82508E+00 -0.0835 16 HPO4-- 0.36990E-07 -7.4319 0.18494E-07 -7.7330 0.49999E+00 -0.3010 18 HSiO3- 0.93887E-02 -2.0274 0.77643E-02 -2.1099 0.82698E+00 -0.0825 19 Ca(HSiO3)+ 0.18896E-07 -7.7236 0.15660E-07 -7.8052 0.82875E+00 -0.0816 20 Mg(HSiO3)+ 0.36621E-11 -11.4363 0.30350E-11 -11.5178 0.82875E+00 -0.0816 21 NaHSiO3,aq 0.23484E-02 -2.6292 0.23484E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.75342E-16 -16.1230 0.62440E-16 -16.2045 0.82875E+00 -0.0816 24 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.47601E-05 -5.3224 0.39286E-05 -5.4058 0.82531E+00 -0.0834 26 CH4,aq 0.91797E-02 -2.0372 0.91632E-02 -2.0380 0.99820E+00 -0.0008 27 C2H6,aq 0.12417E-08 -8.9060 0.12395E-08 -8.9068 0.99820E+00 -0.0008 28 C3H8,aq 0.38780E-14 -14.4114 0.38710E-14 -14.4122 0.99820E+00 -0.0008 29 C4H10,aq 0.11897E-19 -19.9245 0.11876E-19 -19.9253 0.99820E+00 -0.0008 30 ethanol,aq 0.45577E-16 -16.3413 0.45495E-16 -16.3420 0.99820E+00 -0.0008 31 CO,aq 0.68726E-14 -14.1629 0.68726E-14 -14.1629 0.10000E+01 0.0000 32 CO2,aq 0.23663E-07 -7.6259 0.23621E-07 -7.6267 0.99820E+00 -0.0008 33 CO3-2 0.27632E-03 -3.5586 0.13781E-03 -3.8607 0.49873E+00 -0.3021 34 CaCO3,aq 0.15304E-06 -6.8152 0.15304E-06 -6.8152 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.36022E-09 -9.4434 0.29853E-09 -9.5250 0.82875E+00 -0.0816 36 CaCl+ 0.15078E-09 -9.8217 0.12496E-09 -9.9032 0.82875E+00 -0.0816 37 CaCl2,aq 0.25882E-13 -13.5870 0.25882E-13 -13.5870 0.10000E+01 0.0000 38 CaF+ 0.13271E-11 -11.8771 0.10999E-11 -11.9587 0.82875E+00 -0.0816 39 CaOH+ 0.90983E-07 -7.0410 0.75402E-07 -7.1226 0.82875E+00 -0.0816 40 CaSO4,aq 0.10658E-14 -14.9723 0.10658E-14 -14.9723 0.10000E+01 0.0000 41 HCl,aq 0.13372E-13 -13.8738 0.13372E-13 -13.8738 0.10000E+01 0.0000 45 HF,aq 0.48736E-12 -12.3122 0.48736E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16924E-18 -18.7715 0.13996E-18 -18.8540 0.82698E+00 -0.0825 48 FeCl+ 0.63374E-16 -16.1981 0.52521E-16 -16.2797 0.82875E+00 -0.0816 51 FeF+ 0.19962E-17 -17.6998 0.16543E-17 -17.7814 0.82875E+00 -0.0816 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17858E-10 -10.7482 0.14799E-10 -10.8298 0.82875E+00 -0.0816 55 HFeO2- 0.31909E-07 -7.4961 0.26388E-07 -7.5786 0.82698E+00 -0.0825 56 FeO+ 0.12517E-16 -16.9025 0.10373E-16 -16.9841 0.82875E+00 -0.0816 58 FeO2- 0.36632E-09 -9.4361 0.30294E-09 -9.5186 0.82698E+00 -0.0825 59 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11601E-04 -4.9355 0.11581E-04 -4.9363 0.99820E+00 -0.0008 61 KCl,aq 0.23331E-08 -8.6321 0.23331E-08 -8.6321 0.10000E+01 0.0000 63 KOH,aq 0.75325E-06 -6.1231 0.75325E-06 -6.1231 0.10000E+01 0.0000 64 KSO4- 0.10500E-12 -12.9788 0.86829E-13 -13.0613 0.82698E+00 -0.0825 65 MgCO3,aq 0.59736E-11 -11.2238 0.59736E-11 -11.2238 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.57319E-13 -13.2417 0.47503E-13 -13.3233 0.82875E+00 -0.0816 67 MgCl+ 0.21281E-13 -13.6720 0.17636E-13 -13.7536 0.82875E+00 -0.0816 68 MgF+ 0.76556E-15 -15.1160 0.63445E-15 -15.1976 0.82875E+00 -0.0816 69 MgOH+ 0.78400E-10 -10.1057 0.64974E-10 -10.1873 0.82875E+00 -0.0816 71 MnF+ 0.21260E-15 -15.6724 0.17619E-15 -15.7540 0.82875E+00 -0.0816 72 MnO,aq 0.18177E-08 -8.7405 0.18177E-08 -8.7405 0.10000E+01 0.0000 73 MnOH+ 0.53604E-09 -9.2708 0.44424E-09 -9.3524 0.82875E+00 -0.0816 74 MnO2-2 0.17264E-10 -10.7629 0.86099E-11 -11.0650 0.49873E+00 -0.3021 75 HMnO2- 0.19091E-09 -9.7192 0.15788E-09 -9.8017 0.82698E+00 -0.0825 78 MnCl+ 0.79668E-13 -13.0987 0.66025E-13 -13.1803 0.82875E+00 -0.0816 79 MnSO4,aq 0.13455E-18 -18.8711 0.13455E-18 -18.8711 0.10000E+01 0.0000 80 NaCl,aq 0.54033E-05 -5.2673 0.54033E-05 -5.2673 0.10000E+01 0.0000 81 NaF,aq 0.37241E-08 -8.4290 0.37241E-08 -8.4290 0.10000E+01 0.0000 82 NaOH,aq 0.95983E-04 -4.0178 0.95983E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.83628E-02 -2.0776 0.69019E-02 -2.1610 0.82531E+00 -0.0834 89 HPO3-2 0.13385E-14 -14.8734 0.66755E-15 -15.1755 0.49873E+00 -0.3021 91 H2PO3- 0.13548E-18 -18.8681 0.11204E-18 -18.9506 0.82698E+00 -0.0825 92 H3PO4,aq 0.90614E-18 -18.0428 0.90614E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.34493E-10 -10.4623 0.28555E-10 -10.5443 0.82785E+00 -0.0820 94 PO4-3 0.80589E-09 -9.0937 0.18029E-09 -9.7440 0.22371E+00 -0.6503 98 HP2O7-3 0.71953E-18 -18.1430 0.15256E-18 -18.8166 0.21202E+00 -0.6736 99 P2O7-4 0.65685E-17 -17.1825 0.43544E-18 -18.3611 0.66292E-01 -1.1785 100 H2S,aq 0.70166E-06 -6.1539 0.70040E-06 -6.1547 0.99820E+00 -0.0008 101 S2-2 0.28126E-10 -10.5509 0.14027E-10 -10.8530 0.49873E+00 -0.3021 102 S3-2 0.22918E-17 -17.6398 0.11430E-17 -17.9420 0.49873E+00 -0.3021 107 SO3-2 0.11255E-15 -15.9486 0.57039E-16 -16.2438 0.50678E+00 -0.2952 108 HSO3- 0.36146E-18 -18.4419 0.29892E-18 -18.5245 0.82698E+00 -0.0825 109 HSO4- 0.36844E-17 -17.4336 0.30568E-17 -17.5147 0.82965E+00 -0.0811 111 S2O3-2 0.62528E-18 -18.2039 0.31184E-18 -18.5061 0.49873E+00 -0.3021 Charge balance for all species = -.1740E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1005299E-09 -.2049458E-01 -.2061573E+02 0.0000 2 H2O 0.1000000E+01 0.5551417E+02 0.9980919E+06 0.0000 3 Cl- 0.1054242E-02 0.1059647E-02 0.3749208E+02 7.0177 4 SO4-- 0.7580663E-10 -.9182617E-02 -.8803217E+03 9.7332 5 HCO3- 0.1594200E-03 0.9615635E-02 0.5855384E+03 6.1980 6 HS- 0.3273541E-02 0.1245686E-01 0.4111442E+03 7.5099 7 Al+++ 0.1518488E-28 0.4760218E-05 0.1281794E+00 0.7391 8 H4SiO4 0.6958505E-03 0.1243300E-01 0.1192598E+04 -3.1575 9 Ca++ 0.1786298E-06 0.4420586E-06 0.1768117E-01 13.1018 10 Mg++ 0.2795999E-10 0.1160755E-09 0.2816349E-05 9.2942 11 Fe++ 0.7706367E-13 0.3250739E-07 0.1811787E-02 6.7350 12 K+ 0.1782067E-03 0.1789623E-03 0.6983703E+01 6.2465 13 Na+ 0.2261859E-01 0.2506840E-01 0.5751577E+03 8.3492 14 Mn++ 0.2487825E-10 0.2586900E-08 0.1418331E-03 9.2444 15 F- 0.1030908E-05 0.1034634E-05 0.1961642E-01 4.0070 16 HPO4-- 0.3698969E-07 0.3783007E-07 0.3623586E-02 12.4216 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278544E+02 -.1019684E-01 -.8277525E+02 0.0000000E+00 2 H2O -.7114763E+01 0.2762043E+02 -.3473519E+02 0.0000000E+00 3 Cl- 0.5272152E-03 0.5272152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1389076E+00 -.4568704E-02 0.1434763E+00 0.0000000E+00 5 HCO3- 0.4784147E-02 0.4784147E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1372786E+00 0.6197765E-02 -.1434763E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2368391E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6185893E-02 0.5205772E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2199411E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5775203E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1617367E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8904062E-04 0.1061482E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1247249E-01 0.6263904E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1287082E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2649600E-04 0.5147700E-06 0.2598123E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1882191E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1383E-13 Mass of aqueous solution: 0.498542E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0659900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.253 0.796 1640. 3.215 30.02 629.5 andradite 0.5739 -0.241 291.6 2.465 5.339 75.77 grossular 0.1390 -0.857 62.61 1.797 1.146 17.42 apatite-OH 0.9837E-02 -2.007 4.941 0.694 0.9046E-01 1.570 apatite-F 0.2598E-04 -4.585 0.1310E-01 -1.883 0.2399E-03 0.4093E-02 clinochlore 0.7057 -0.151 392.2 2.594 7.181 149.2 daphnite 0.2043 -0.690 145.8 2.164 2.669 44.18 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1357 -0.867 29.40 1.468 0.5382 8.984 hedenbergite 0.3521E-01 -1.453 8.735 0.941 0.1599 2.393 microcline 0.9359 -0.029 260.5 2.416 4.769 101.8 stilbite 3.224 0.508 2272. 3.356 41.59 1060. stilpnomelane-Fe 0.2511 -0.600 270.7 2.432 4.956 93.51 tr.625ac.25prg.125 0.8389E-01 -1.076 71.70 1.856 1.313 23.08 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1870E-01 0.1870E-01 1.0000 -1.728 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.356154 g Volume = 2210.960343 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0659900 moles log = -1.1805 Original solution: 1000.0103000 g Original solution / Rock added: 15153.97 (Water/Rock Ratio), log = 4.1805 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 14.6625 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.7156E-01 0.9586 0.1006E+01 0.1049E+01 CO2,gas 0.1772E-06 0.9728 0.2527E-05 0.2598E-05 CH4,gas 0.9274E+00 0.9919 0.1349E+02 0.1360E+02 H2,gas 0.1029E-02 1.0078 0.1520E-01 0.1509E-01 H2S,gas 0.1389E-05 0.9451 0.1925E-04 0.2037E-04 S2,gas 0.4105E-26 1.0000 0.6019E-25 0.6019E-25 CO,gas 0.6985E-12 1.0000 0.1024E-10 0.1024E-10 SO3,gas 0.6847E-47 1.0000 0.1004E-45 0.1004E-45 SO2,gas 0.4051E-26 1.0000 0.5939E-25 0.5939E-25 HF,gas 0.8161E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1609E-17 1.0000 0.2359E-16 0.2359E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.003 2 CO2,gas -6.66 -13.96 -7.30 -2.432 0.12458E+05 -5.597 3 CH4,gas 4.54 3.97 -0.57 -0.142 0.97161E+03 1.130 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.64 -6.41 -3.207 0.10953E+05 -4.715 6 S2,gas -7.34 -34.25 -26.92 -4.141 0.45964E+05 -25.220 7 CO,gas 3.21 -9.47 -12.69 -3.904 0.21665E+05 -10.990 8 SO3,gas 17.12 -30.58 -47.70 -11.924 0.81442E+05 -45.998 9 SO2,gas 0.83 -26.09 -26.93 -7.180 0.45974E+05 -25.226 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.14 -18.33 -9.163 0.31291E+05 -16.627 12 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80563E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93648E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28494E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 38 aragonite 0.97 -0.85 -1.82 -0.607 0.31097E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -0.85 -1.67 -0.555 0.28455E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39696E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68944E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65500E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.99 -1.89 -0.540 0.32245E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37136E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.99 -1.44 -0.413 0.24667E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28622E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82194E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36682E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91152E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -23.04 -1.79 -0.421 0.30567E+04 146 pyrrhotite -4.26 -5.91 -1.65 -0.550 0.28162E+04 147 pyrrhotiteFe0.875 -6.02 -7.31 -1.29 -0.475 0.22034E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22397E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28669E+03 154 rhodochrosite -0.98 -4.71 -3.74 -1.245 0.63788E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23199E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.22 -4.61 -1.538 0.78772E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27809E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47032E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90667E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77505E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65444E+04 184 troilite-low -4.41 -5.91 -1.50 -0.500 0.25590E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66606E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60599E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58212E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62082E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66551E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.40 -2.42 -0.807 0.41362E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0659900 MOLES New total amount of reactant added: 0.0679900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8653E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0679900 Water: Moles liquid = 0.2762E+02 kg liquid = 0.4976E+00 Moles total = -.7113E+01 kg total = -.1281E+00 Activity = 0.9998 Stoichiometric ionic strength = .5675959E-02 Osmotic coef. = 0.9383 True ionic strength = .2316417E-01 Chg. balance for total moles = -.8653E-10 Max. difference allowed = 0.5390E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10090E-09 -9.9961 0.83982E-10 -10.0758 0.83235E+00 -0.0797 2 H2O 0.99983E+00 -0.0001 0.99983E+00 -0.0001 3 Cl- 0.10777E-02 -2.9675 0.89102E-03 -3.0501 0.82675E+00 -0.0826 4 SO4-- 0.77860E-10 -10.1087 0.38881E-10 -10.4103 0.49937E+00 -0.3016 5 HCO3- 0.16376E-03 -3.7858 0.13561E-03 -3.8677 0.82810E+00 -0.0819 6 HS- 0.33710E-02 -2.4722 0.27874E-02 -2.5548 0.82688E+00 -0.0826 7 Al+++ 0.15378E-28 -28.8131 0.32487E-29 -29.4883 0.21126E+00 -0.6752 8 H4SiO4 0.69585E-03 -3.1575 0.69585E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.18004E-06 -6.7446 0.89169E-07 -7.0498 0.49526E+00 -0.3052 10 Mg++ 0.28182E-10 -10.5500 0.13886E-10 -10.8574 0.49272E+00 -0.3074 11 Fe++ 0.77675E-13 -13.1097 0.38319E-13 -13.4166 0.49333E+00 -0.3069 12 K+ 0.17886E-03 -3.7475 0.14815E-03 -3.8293 0.82832E+00 -0.0818 13 Na+ 0.22702E-01 -1.6439 0.18764E-01 -1.7267 0.82657E+00 -0.0827 14 Mn++ 0.25080E-10 -10.6007 0.12384E-10 -10.9071 0.49378E+00 -0.3065 15 F- 0.10277E-05 -5.9881 0.84769E-06 -6.0718 0.82484E+00 -0.0836 16 HPO4-- 0.36779E-07 -7.4344 0.18369E-07 -7.7359 0.49945E+00 -0.3015 18 HSiO3- 0.93595E-02 -2.0287 0.77379E-02 -2.1114 0.82675E+00 -0.0826 19 Ca(HSiO3)+ 0.18966E-07 -7.7220 0.15713E-07 -7.8037 0.82852E+00 -0.0817 20 Mg(HSiO3)+ 0.36756E-11 -11.4347 0.30453E-11 -11.5164 0.82852E+00 -0.0817 21 NaHSiO3,aq 0.23484E-02 -2.6292 0.23484E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.75620E-16 -16.1214 0.62653E-16 -16.2031 0.82852E+00 -0.0817 24 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.47453E-05 -5.3237 0.39152E-05 -5.4072 0.82508E+00 -0.0835 26 CH4,aq 0.94585E-02 -2.0242 0.94420E-02 -2.0249 0.99825E+00 -0.0008 27 C2H6,aq 0.13184E-08 -8.8800 0.13161E-08 -8.8807 0.99825E+00 -0.0008 28 C3H8,aq 0.42426E-14 -14.3724 0.42352E-14 -14.3731 0.99825E+00 -0.0008 29 C4H10,aq 0.13412E-19 -19.8725 0.13389E-19 -19.8733 0.99825E+00 -0.0008 30 ethanol,aq 0.48390E-16 -16.3152 0.48305E-16 -16.3160 0.99825E+00 -0.0008 31 CO,aq 0.70818E-14 -14.1499 0.70818E-14 -14.1499 0.10000E+01 0.0000 32 CO2,aq 0.24382E-07 -7.6129 0.24339E-07 -7.6137 0.99825E+00 -0.0008 33 CO3-2 0.28311E-03 -3.5480 0.14104E-03 -3.8507 0.49819E+00 -0.3026 34 CaCO3,aq 0.15769E-06 -6.8022 0.15769E-06 -6.8022 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.37255E-09 -9.4288 0.30866E-09 -9.5105 0.82852E+00 -0.0817 36 CaCl+ 0.15519E-09 -9.8091 0.12858E-09 -9.8908 0.82852E+00 -0.0817 37 CaCl2,aq 0.27218E-13 -13.5651 0.27218E-13 -13.5651 0.10000E+01 0.0000 38 CaF+ 0.13320E-11 -11.8755 0.11036E-11 -11.9572 0.82852E+00 -0.0817 39 CaOH+ 0.91317E-07 -7.0395 0.75658E-07 -7.1211 0.82852E+00 -0.0817 40 CaSO4,aq 0.11009E-14 -14.9582 0.11009E-14 -14.9582 0.10000E+01 0.0000 41 HCl,aq 0.13712E-13 -13.8629 0.13712E-13 -13.8629 0.10000E+01 0.0000 45 HF,aq 0.48736E-12 -12.3122 0.48736E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16871E-18 -18.7729 0.13948E-18 -18.8555 0.82675E+00 -0.0826 48 FeCl+ 0.65228E-16 -16.1856 0.54043E-16 -16.2673 0.82852E+00 -0.0817 51 FeF+ 0.20035E-17 -17.6982 0.16599E-17 -17.7799 0.82852E+00 -0.0817 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17923E-10 -10.7466 0.14850E-10 -10.8283 0.82852E+00 -0.0817 55 HFeO2- 0.31809E-07 -7.4974 0.26298E-07 -7.5801 0.82675E+00 -0.0826 56 FeO+ 0.12563E-16 -16.9009 0.10408E-16 -16.9826 0.82852E+00 -0.0817 58 FeO2- 0.36518E-09 -9.4375 0.30191E-09 -9.5201 0.82675E+00 -0.0826 59 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11601E-04 -4.9355 0.11580E-04 -4.9363 0.99825E+00 -0.0008 61 KCl,aq 0.23925E-08 -8.6211 0.23925E-08 -8.6211 0.10000E+01 0.0000 63 KOH,aq 0.75324E-06 -6.1231 0.75324E-06 -6.1231 0.10000E+01 0.0000 64 KSO4- 0.10812E-12 -12.9661 0.89387E-13 -13.0487 0.82675E+00 -0.0826 65 MgCO3,aq 0.61554E-11 -11.2107 0.61554E-11 -11.2107 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.59281E-13 -13.2271 0.49115E-13 -13.3088 0.82852E+00 -0.0817 67 MgCl+ 0.21903E-13 -13.6595 0.18147E-13 -13.7412 0.82852E+00 -0.0817 68 MgF+ 0.76837E-15 -15.1144 0.63661E-15 -15.1961 0.82852E+00 -0.0817 69 MgOH+ 0.78688E-10 -10.1041 0.65194E-10 -10.1858 0.82852E+00 -0.0817 71 MnF+ 0.21342E-15 -15.6708 0.17683E-15 -15.7525 0.82852E+00 -0.0817 72 MnO,aq 0.18181E-08 -8.7404 0.18181E-08 -8.7404 0.10000E+01 0.0000 73 MnOH+ 0.53811E-09 -9.2691 0.44584E-09 -9.3508 0.82852E+00 -0.0817 74 MnO2-2 0.17169E-10 -10.7653 0.85533E-11 -11.0679 0.49819E+00 -0.3026 75 HMnO2- 0.19035E-09 -9.7204 0.15737E-09 -9.8031 0.82675E+00 -0.0826 78 MnCl+ 0.82015E-13 -13.0861 0.67951E-13 -13.1678 0.82852E+00 -0.0817 79 MnSO4,aq 0.13901E-18 -18.8570 0.13901E-18 -18.8570 0.10000E+01 0.0000 80 NaCl,aq 0.55409E-05 -5.2564 0.55409E-05 -5.2564 0.10000E+01 0.0000 81 NaF,aq 0.37240E-08 -8.4290 0.37240E-08 -8.4290 0.10000E+01 0.0000 82 NaOH,aq 0.95981E-04 -4.0178 0.95981E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.83368E-02 -2.0790 0.68785E-02 -2.1625 0.82508E+00 -0.0835 89 HPO3-2 0.13309E-14 -14.8759 0.66304E-15 -15.1785 0.49819E+00 -0.3026 91 H2PO3- 0.13506E-18 -18.8695 0.11166E-18 -18.9521 0.82675E+00 -0.0826 92 H3PO4,aq 0.90614E-18 -18.0428 0.90614E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.34386E-10 -10.4636 0.28459E-10 -10.5458 0.82763E+00 -0.0822 94 PO4-3 0.79955E-09 -9.0972 0.17846E-09 -9.7485 0.22320E+00 -0.6513 98 HP2O7-3 0.71399E-18 -18.1463 0.15101E-18 -18.8210 0.21151E+00 -0.6747 99 P2O7-4 0.65075E-17 -17.1866 0.42957E-18 -18.3670 0.66011E-01 -1.1804 100 H2S,aq 0.72475E-06 -6.1398 0.72349E-06 -6.1406 0.99825E+00 -0.0008 101 S2-2 0.29840E-10 -10.5252 0.14866E-10 -10.8278 0.49819E+00 -0.3026 102 S3-2 0.25117E-17 -17.6000 0.12513E-17 -17.9026 0.49819E+00 -0.3026 107 SO3-2 0.11560E-15 -15.9371 0.58521E-16 -16.2327 0.50626E+00 -0.2956 108 HSO3- 0.37221E-18 -18.4292 0.30773E-18 -18.5118 0.82675E+00 -0.0826 109 HSO4- 0.37940E-17 -17.4209 0.31469E-17 -17.5021 0.82943E+00 -0.0812 111 S2O3-2 0.66340E-18 -18.1782 0.33050E-18 -18.4808 0.49819E+00 -0.3026 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1008978E-09 -.2044602E-01 -.2056671E+02 0.0000 2 H2O 0.1000000E+01 0.5551446E+02 0.9980885E+06 0.0000 3 Cl- 0.1077741E-02 0.1083285E-02 0.3832809E+02 7.0257 4 SO4-- 0.7785972E-10 -.9461391E-02 -.9070397E+03 9.7414 5 HCO3- 0.1637591E-03 0.9905541E-02 0.6031870E+03 6.2081 6 HS- 0.3370952E-02 0.1283307E-01 0.4235576E+03 7.5210 7 Al+++ 0.1537817E-28 0.4745446E-05 0.1277805E+00 0.7391 8 H4SiO4 0.6958466E-03 0.1240374E-01 0.1189781E+04 -3.1575 9 Ca++ 0.1800443E-06 0.4485500E-06 0.1794066E-01 13.1018 10 Mg++ 0.2818183E-10 0.1167837E-09 0.2833508E-05 9.2942 11 Fe++ 0.7767515E-13 0.3240685E-07 0.1806168E-02 6.7350 12 K+ 0.1788589E-03 0.1796145E-03 0.7009095E+01 6.2465 13 Na+ 0.2270151E-01 0.2515142E-01 0.5770576E+03 8.3491 14 Mn++ 0.2508049E-10 0.2588881E-08 0.1419405E-03 9.2445 15 F- 0.1027702E-05 0.1031428E-05 0.1955547E-01 4.0041 16 HPO4-- 0.3677881E-07 0.3761275E-07 0.3602739E-02 12.4157 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278523E+02 -.1017342E-01 -.8277505E+02 0.0000000E+00 2 H2O -.7113125E+01 0.2762259E+02 -.3473572E+02 0.0000000E+00 3 Cl- 0.5390152E-03 0.5390152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1389172E+00 -.4707749E-02 0.1436249E+00 0.0000000E+00 5 HCO3- 0.4928747E-02 0.4928747E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1372395E+00 0.6385411E-02 -.1436249E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2361214E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6171788E-02 0.5205773E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2231871E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5810863E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1612483E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8937166E-04 0.1061482E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1251471E-01 0.6263862E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1288162E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2729600E-04 0.5132126E-06 0.2678279E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1871515E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1021E-13 Mass of aqueous solution: 0.498582E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0679900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.253 0.796 1640. 3.215 30.02 629.5 andradite 0.5745 -0.241 291.9 2.465 5.345 75.85 grossular 0.1391 -0.857 62.67 1.797 1.147 17.44 apatite-OH 0.9836E-02 -2.007 4.941 0.694 0.9045E-01 1.570 apatite-F 0.2678E-04 -4.572 0.1351E-01 -1.869 0.2473E-03 0.4220E-02 clinochlore 0.7055 -0.151 392.2 2.593 7.179 149.2 daphnite 0.2043 -0.690 145.8 2.164 2.668 44.17 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1319 -0.880 28.56 1.456 0.5228 8.728 hedenbergite 0.3420E-01 -1.466 8.486 0.929 0.1554 2.324 microcline 0.9361 -0.029 260.5 2.416 4.770 101.8 stilbite 3.224 0.508 2272. 3.356 41.60 1060. stilpnomelane-Fe 0.2508 -0.601 270.4 2.432 4.950 93.39 tr.625ac.25prg.125 0.8515E-01 -1.070 72.78 1.862 1.332 23.43 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1870E-01 0.1870E-01 1.0000 -1.728 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.356630 g Volume = 2210.965893 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0679900 moles log = -1.1676 Original solution: 1000.0103000 g Original solution / Rock added: 14708.20 (Water/Rock Ratio), log = 4.1676 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 15.0806 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.6961E-01 0.9581 0.1006E+01 0.1050E+01 CO2,gas 0.1776E-06 0.9721 0.2604E-05 0.2679E-05 CH4,gas 0.9294E+00 0.9916 0.1390E+02 0.1402E+02 H2,gas 0.1000E-02 1.0081 0.1520E-01 0.1508E-01 H2S,gas 0.1398E-05 0.9436 0.1989E-04 0.2108E-04 S2,gas 0.4259E-26 1.0000 0.6423E-25 0.6423E-25 CO,gas 0.6998E-12 1.0000 0.1055E-10 0.1055E-10 SO3,gas 0.6877E-47 1.0000 0.1037E-45 0.1037E-45 SO2,gas 0.4068E-26 1.0000 0.6135E-25 0.6135E-25 HF,gas 0.7935E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1604E-17 1.0000 0.2420E-16 0.2420E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.60662E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.15165E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.003 2 CO2,gas -6.66 -13.94 -7.28 -2.428 0.12436E+05 -5.584 3 CH4,gas 4.54 3.99 -0.56 -0.139 0.94939E+03 1.143 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.63 -6.40 -3.200 0.10928E+05 -4.701 6 S2,gas -7.34 -34.23 -26.89 -4.137 0.45916E+05 -25.192 7 CO,gas 3.21 -9.46 -12.68 -3.900 0.21643E+05 -10.977 8 SO3,gas 17.12 -30.56 -47.68 -11.921 0.81418E+05 -45.984 9 SO2,gas 0.83 -26.08 -26.91 -7.176 0.45950E+05 -25.212 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.13 -18.32 -9.158 0.31273E+05 -16.616 12 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80559E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93649E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28494E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 38 aragonite 0.97 -0.84 -1.81 -0.603 0.30875E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55912E+04 40 calcite 0.81 -0.84 -1.65 -0.551 0.28232E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39696E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68944E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.57 -3.84 -0.256 0.65498E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.98 -1.88 -0.536 0.32022E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37136E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.98 -1.43 -0.409 0.24445E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24618E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59830E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28623E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82192E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36683E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91151E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -23.01 -1.76 -0.415 0.30086E+04 146 pyrrhotite -4.26 -5.90 -1.64 -0.545 0.27922E+04 147 pyrrhotiteFe0.875 -6.02 -7.29 -1.28 -0.469 0.21794E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22395E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28669E+03 154 rhodochrosite -0.98 -4.70 -3.72 -1.241 0.63564E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23198E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.21 -4.60 -1.533 0.78550E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27809E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47029E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90667E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77505E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65444E+04 184 troilite-low -4.41 -5.90 -1.48 -0.495 0.25350E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60599E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73674E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58212E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66550E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.39 -2.41 -0.803 0.41120E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0679900 MOLES New total amount of reactant added: 0.0699900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8655E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0699900 Water: Moles liquid = 0.2762E+02 kg liquid = 0.4976E+00 Moles total = -.7111E+01 kg total = -.1281E+00 Activity = 0.9998 Stoichiometric ionic strength = .5504986E-02 Osmotic coef. = 0.9391 True ionic strength = .2325455E-01 Chg. balance for total moles = -.8655E-10 Max. difference allowed = 0.5508E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10127E-09 -9.9945 0.84267E-10 -10.0743 0.83214E+00 -0.0798 2 H2O 0.99982E+00 -0.0001 0.99982E+00 -0.0001 3 Cl- 0.11012E-02 -2.9581 0.91019E-03 -3.0409 0.82652E+00 -0.0827 4 SO4-- 0.79902E-10 -10.0974 0.39858E-10 -10.3995 0.49884E+00 -0.3020 5 HCO3- 0.16807E-03 -3.7745 0.13914E-03 -3.8565 0.82788E+00 -0.0820 6 HS- 0.34683E-02 -2.4599 0.28671E-02 -2.5426 0.82665E+00 -0.0827 7 Al+++ 0.15573E-28 -28.8076 0.32819E-29 -29.4839 0.21074E+00 -0.6763 8 H4SiO4 0.69584E-03 -3.1575 0.69584E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.18147E-06 -6.7412 0.89775E-07 -7.0468 0.49472E+00 -0.3056 10 Mg++ 0.28405E-10 -10.5466 0.13980E-10 -10.8545 0.49217E+00 -0.3079 11 Fe++ 0.78290E-13 -13.1063 0.38580E-13 -13.4136 0.49278E+00 -0.3073 12 K+ 0.17951E-03 -3.7459 0.14865E-03 -3.8278 0.82809E+00 -0.0819 13 Na+ 0.22785E-01 -1.6424 0.18828E-01 -1.7252 0.82634E+00 -0.0828 14 Mn++ 0.25284E-10 -10.5972 0.12471E-10 -10.9041 0.49324E+00 -0.3069 15 F- 0.10245E-05 -5.9895 0.84482E-06 -6.0732 0.82461E+00 -0.0838 16 HPO4-- 0.36570E-07 -7.4369 0.18245E-07 -7.7388 0.49892E+00 -0.3020 18 HSiO3- 0.93304E-02 -2.0301 0.77118E-02 -2.1128 0.82652E+00 -0.0827 19 Ca(HSiO3)+ 0.19035E-07 -7.7204 0.15767E-07 -7.8023 0.82829E+00 -0.0818 20 Mg(HSiO3)+ 0.36891E-11 -11.4331 0.30556E-11 -11.5149 0.82829E+00 -0.0818 21 NaHSiO3,aq 0.23483E-02 -2.6292 0.23483E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.75897E-16 -16.1198 0.62865E-16 -16.2016 0.82829E+00 -0.0818 24 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.47306E-05 -5.3251 0.39020E-05 -5.4087 0.82484E+00 -0.0836 26 CH4,aq 0.97373E-02 -2.0116 0.97208E-02 -2.0123 0.99831E+00 -0.0007 27 C2H6,aq 0.13973E-08 -8.8547 0.13950E-08 -8.8554 0.99831E+00 -0.0007 28 C3H8,aq 0.46295E-14 -14.3345 0.46217E-14 -14.3352 0.99831E+00 -0.0007 29 C4H10,aq 0.15068E-19 -19.8220 0.15042E-19 -19.8227 0.99831E+00 -0.0007 30 ethanol,aq 0.51288E-16 -16.2900 0.51201E-16 -16.2907 0.99831E+00 -0.0007 31 CO,aq 0.72910E-14 -14.1372 0.72910E-14 -14.1372 0.10000E+01 0.0000 32 CO2,aq 0.25101E-07 -7.6003 0.25058E-07 -7.6010 0.99831E+00 -0.0007 33 CO3-2 0.28981E-03 -3.5379 0.14423E-03 -3.8410 0.49765E+00 -0.3031 34 CaCO3,aq 0.16235E-06 -6.7895 0.16235E-06 -6.7895 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.38496E-09 -9.4146 0.31886E-09 -9.4964 0.82829E+00 -0.0818 36 CaCl+ 0.15965E-09 -9.7968 0.13224E-09 -9.8787 0.82829E+00 -0.0818 37 CaCl2,aq 0.28595E-13 -13.5437 0.28595E-13 -13.5437 0.10000E+01 0.0000 38 CaF+ 0.13369E-11 -11.8739 0.11073E-11 -11.9557 0.82829E+00 -0.0818 39 CaOH+ 0.91651E-07 -7.0379 0.75914E-07 -7.1197 0.82829E+00 -0.0818 40 CaSO4,aq 0.11363E-14 -14.9445 0.11363E-14 -14.9445 0.10000E+01 0.0000 41 HCl,aq 0.14055E-13 -13.8522 0.14055E-13 -13.8522 0.10000E+01 0.0000 45 HF,aq 0.48735E-12 -12.3122 0.48735E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16819E-18 -18.7742 0.13901E-18 -18.8570 0.82652E+00 -0.0827 48 FeCl+ 0.67103E-16 -16.1733 0.55581E-16 -16.2551 0.82829E+00 -0.0818 51 FeF+ 0.20108E-17 -17.6966 0.16656E-17 -17.7784 0.82829E+00 -0.0818 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.17989E-10 -10.7450 0.14900E-10 -10.8268 0.82829E+00 -0.0818 55 HFeO2- 0.31710E-07 -7.4988 0.26209E-07 -7.5815 0.82652E+00 -0.0827 56 FeO+ 0.12609E-16 -16.8993 0.10444E-16 -16.9811 0.82829E+00 -0.0818 58 FeO2- 0.36404E-09 -9.4388 0.30089E-09 -9.5216 0.82652E+00 -0.0827 59 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11600E-04 -4.9355 0.11580E-04 -4.9363 0.99831E+00 -0.0007 61 KCl,aq 0.24523E-08 -8.6104 0.24523E-08 -8.6104 0.10000E+01 0.0000 63 KOH,aq 0.75322E-06 -6.1231 0.75322E-06 -6.1231 0.10000E+01 0.0000 64 KSO4- 0.11124E-12 -12.9537 0.91942E-13 -13.0365 0.82652E+00 -0.0827 65 MgCO3,aq 0.63372E-11 -11.1981 0.63372E-11 -11.1981 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.61255E-13 -13.2129 0.50738E-13 -13.2947 0.82829E+00 -0.0818 67 MgCl+ 0.22533E-13 -13.6472 0.18664E-13 -13.7290 0.82829E+00 -0.0818 68 MgF+ 0.77118E-15 -15.1128 0.63876E-15 -15.1947 0.82829E+00 -0.0818 69 MgOH+ 0.78976E-10 -10.1025 0.65415E-10 -10.1843 0.82829E+00 -0.0818 71 MnF+ 0.21425E-15 -15.6691 0.17746E-15 -15.7509 0.82829E+00 -0.0818 72 MnO,aq 0.18184E-08 -8.7403 0.18184E-08 -8.7403 0.10000E+01 0.0000 73 MnOH+ 0.54019E-09 -9.2675 0.44744E-09 -9.3493 0.82829E+00 -0.0818 74 MnO2-2 0.17075E-10 -10.7677 0.84972E-11 -11.0707 0.49765E+00 -0.3031 75 HMnO2- 0.18980E-09 -9.7217 0.15687E-09 -9.8045 0.82652E+00 -0.0827 78 MnCl+ 0.84389E-13 -13.0737 0.69899E-13 -13.1555 0.82829E+00 -0.0818 79 MnSO4,aq 0.14350E-18 -18.8431 0.14350E-18 -18.8431 0.10000E+01 0.0000 80 NaCl,aq 0.56792E-05 -5.2457 0.56792E-05 -5.2457 0.10000E+01 0.0000 81 NaF,aq 0.37239E-08 -8.4290 0.37239E-08 -8.4290 0.10000E+01 0.0000 82 NaOH,aq 0.95979E-04 -4.0178 0.95979E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.83109E-02 -2.0804 0.68552E-02 -2.1640 0.82484E+00 -0.0836 89 HPO3-2 0.13233E-14 -14.8783 0.65856E-15 -15.1814 0.49765E+00 -0.3031 91 H2PO3- 0.13464E-18 -18.8708 0.11128E-18 -18.9536 0.82652E+00 -0.0827 92 H3PO4,aq 0.90614E-18 -18.0428 0.90614E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.34279E-10 -10.4650 0.28362E-10 -10.5473 0.82740E+00 -0.0823 94 PO4-3 0.79328E-09 -9.1006 0.17665E-09 -9.7529 0.22269E+00 -0.6523 98 HP2O7-3 0.70850E-18 -18.1497 0.14949E-18 -18.8254 0.21099E+00 -0.6757 99 P2O7-4 0.64473E-17 -17.1906 0.42379E-18 -18.3728 0.65732E-01 -1.1822 100 H2S,aq 0.74798E-06 -6.1261 0.74671E-06 -6.1268 0.99831E+00 -0.0007 101 S2-2 0.31606E-10 -10.5002 0.15729E-10 -10.8033 0.49765E+00 -0.3031 102 S3-2 0.27457E-17 -17.5613 0.13664E-17 -17.8644 0.49765E+00 -0.3031 107 SO3-2 0.11862E-15 -15.9258 0.59992E-16 -16.2219 0.50574E+00 -0.2961 108 HSO3- 0.38297E-18 -18.4168 0.31653E-18 -18.4996 0.82652E+00 -0.0827 109 HSO4- 0.39036E-17 -17.4085 0.32369E-17 -17.4899 0.82921E+00 -0.0813 111 S2O3-2 0.70265E-18 -18.1533 0.34968E-18 -18.4563 0.49765E+00 -0.3031 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1012662E-09 -.2039769E-01 -.2051792E+02 0.0000 2 H2O 0.1000000E+01 0.5551474E+02 0.9980852E+06 0.0000 3 Cl- 0.1101237E-02 0.1106919E-02 0.3916396E+02 7.0335 4 SO4-- 0.7990180E-10 -.9740228E-02 -.9337632E+03 9.7492 5 HCO3- 0.1680725E-03 0.1019540E-01 0.6208326E+03 6.2178 6 HS- 0.3468349E-02 0.1320933E-01 0.4359723E+03 7.5318 7 Al+++ 0.1557343E-28 0.4730754E-05 0.1273838E+00 0.7392 8 H4SiO4 0.6958427E-03 0.1237465E-01 0.1186980E+04 -3.1575 9 Ca++ 0.1814666E-06 0.4550513E-06 0.1820054E-01 13.1018 10 Mg++ 0.2840489E-10 0.1174918E-09 0.2850664E-05 9.2942 11 Fe++ 0.7828999E-13 0.3230687E-07 0.1800580E-02 6.7350 12 K+ 0.1795119E-03 0.1802676E-03 0.7034518E+01 6.2465 13 Na+ 0.2278453E-01 0.2523454E-01 0.5789598E+03 8.3491 14 Mn++ 0.2528390E-10 0.2590869E-08 0.1420483E-03 9.2446 15 F- 0.1024514E-05 0.1028240E-05 0.1949487E-01 4.0011 16 HPO4-- 0.3656964E-07 0.3739720E-07 0.3582062E-02 12.4098 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278501E+02 -.1015012E-01 -.8277486E+02 0.0000000E+00 2 H2O -.7111488E+01 0.2762475E+02 -.3473624E+02 0.0000000E+00 3 Cl- 0.5508152E-03 0.5508152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1389267E+00 -.4846846E-02 0.1437736E+00 0.0000000E+00 5 HCO3- 0.5073347E-02 0.5073347E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1372005E+00 0.6573108E-02 -.1437736E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2354076E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6157762E-02 0.5205775E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2264386E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5846523E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1607626E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8970315E-04 0.1061481E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1255699E-01 0.6263820E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1289246E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2809600E-04 0.5116638E-06 0.2758434E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1860926E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.6391E-14 Mass of aqueous solution: 0.498623E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0699900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.253 0.796 1640. 3.215 30.02 629.4 andradite 0.5751 -0.240 292.3 2.466 5.350 75.93 grossular 0.1393 -0.856 62.74 1.798 1.149 17.46 apatite-OH 0.9835E-02 -2.007 4.940 0.694 0.9044E-01 1.570 apatite-F 0.2758E-04 -4.559 0.1391E-01 -1.857 0.2547E-03 0.4346E-02 clinochlore 0.7054 -0.152 392.1 2.593 7.178 149.1 daphnite 0.2042 -0.690 145.7 2.164 2.668 44.16 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1280 -0.893 27.72 1.443 0.5075 8.472 hedenbergite 0.3320E-01 -1.479 8.237 0.916 0.1508 2.256 microcline 0.9362 -0.029 260.6 2.416 4.771 101.8 stilbite 3.224 0.508 2272. 3.356 41.60 1060. stilpnomelane-Fe 0.2505 -0.601 270.0 2.431 4.943 93.27 tr.625ac.25prg.125 0.8641E-01 -1.063 73.86 1.868 1.352 23.77 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1870E-01 0.1870E-01 1.0000 -1.728 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.357101 g Volume = 2210.971445 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0699900 moles log = -1.1550 Original solution: 1000.0103000 g Original solution / Rock added: 14287.90 (Water/Rock Ratio), log = 4.1550 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 15.4991 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.6776E-01 0.9576 0.1006E+01 0.1050E+01 CO2,gas 0.1781E-06 0.9714 0.2681E-05 0.2760E-05 CH4,gas 0.9313E+00 0.9913 0.1431E+02 0.1443E+02 H2,gas 0.9729E-03 1.0083 0.1520E-01 0.1508E-01 H2S,gas 0.1406E-05 0.9421 0.2053E-04 0.2179E-04 S2,gas 0.4414E-26 1.0000 0.6842E-25 0.6842E-25 CO,gas 0.7010E-12 1.0000 0.1087E-10 0.1087E-10 SO3,gas 0.6906E-47 1.0000 0.1070E-45 0.1070E-45 SO2,gas 0.4086E-26 1.0000 0.6332E-25 0.6332E-25 HF,gas 0.7721E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1600E-17 1.0000 0.2480E-16 0.2480E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.003 2 CO2,gas -6.66 -13.93 -7.27 -2.424 0.12414E+05 -5.572 3 CH4,gas 4.54 4.00 -0.54 -0.136 0.92780E+03 1.156 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.62 -6.39 -3.193 0.10905E+05 -4.688 6 S2,gas -7.34 -34.20 -26.86 -4.133 0.45869E+05 -25.165 7 CO,gas 3.21 -9.45 -12.66 -3.896 0.21622E+05 -10.964 8 SO3,gas 17.12 -30.55 -47.67 -11.917 0.81394E+05 -45.970 9 SO2,gas 0.83 -26.07 -26.90 -7.173 0.45927E+05 -25.198 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.12 -18.30 -9.152 0.31254E+05 -16.606 12 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80554E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93649E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28495E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 38 aragonite 0.97 -0.83 -1.80 -0.599 0.30659E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55912E+04 40 calcite 0.81 -0.83 -1.64 -0.547 0.28017E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39696E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68945E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.57 -3.84 -0.256 0.65497E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.97 -1.86 -0.532 0.31806E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37136E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.97 -1.42 -0.405 0.24229E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28623E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82191E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36683E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91151E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -22.98 -1.73 -0.408 0.29617E+04 146 pyrrhotite -4.26 -5.88 -1.62 -0.541 0.27687E+04 147 pyrrhotiteFe0.875 -6.02 -7.28 -1.26 -0.464 0.21559E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22394E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28669E+03 154 rhodochrosite -0.98 -4.69 -3.71 -1.237 0.63347E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23196E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.20 -4.59 -1.529 0.78334E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27809E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47026E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90666E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77506E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65444E+04 184 troilite-low -4.41 -5.88 -1.47 -0.490 0.25115E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34152E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60598E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58212E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66550E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.37 -2.39 -0.798 0.40884E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0699900 MOLES New total amount of reactant added: 0.0719900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8654E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0719900 Water: Moles liquid = 0.2762E+02 kg liquid = 0.4976E+00 Moles total = -.7110E+01 kg total = -.1281E+00 Activity = 0.9998 Stoichiometric ionic strength = .5333944E-02 Osmotic coef. = 0.9399 True ionic strength = .2334497E-01 Chg. balance for total moles = -.8654E-10 Max. difference allowed = 0.5626E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10164E-09 -9.9930 0.84553E-10 -10.0729 0.83192E+00 -0.0799 2 H2O 0.99982E+00 -0.0001 0.99982E+00 -0.0001 3 Cl- 0.11247E-02 -2.9490 0.92935E-03 -3.0318 0.82629E+00 -0.0829 4 SO4-- 0.81933E-10 -10.0865 0.40828E-10 -10.3890 0.49831E+00 -0.3025 5 HCO3- 0.17236E-03 -3.7636 0.14265E-03 -3.8457 0.82765E+00 -0.0822 6 HS- 0.35657E-02 -2.4479 0.29468E-02 -2.5306 0.82642E+00 -0.0828 7 Al+++ 0.15771E-28 -28.8021 0.33154E-29 -29.4795 0.21023E+00 -0.6773 8 H4SiO4 0.69584E-03 -3.1575 0.69584E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.18290E-06 -6.7378 0.90383E-07 -7.0439 0.49418E+00 -0.3061 10 Mg++ 0.28629E-10 -10.5432 0.14075E-10 -10.8516 0.49163E+00 -0.3084 11 Fe++ 0.78908E-13 -13.1029 0.38841E-13 -13.4107 0.49224E+00 -0.3078 12 K+ 0.18017E-03 -3.7443 0.14915E-03 -3.8264 0.82787E+00 -0.0820 13 Na+ 0.22868E-01 -1.6408 0.18891E-01 -1.7237 0.82611E+00 -0.0830 14 Mn++ 0.25488E-10 -10.5937 0.12558E-10 -10.9011 0.49270E+00 -0.3074 15 F- 0.10213E-05 -5.9908 0.84197E-06 -6.0747 0.82438E+00 -0.0839 16 HPO4-- 0.36362E-07 -7.4394 0.18122E-07 -7.7418 0.49839E+00 -0.3024 18 HSiO3- 0.93015E-02 -2.0314 0.76858E-02 -2.1143 0.82629E+00 -0.0829 19 Ca(HSiO3)+ 0.19105E-07 -7.7189 0.15820E-07 -7.8008 0.82807E+00 -0.0819 20 Mg(HSiO3)+ 0.37025E-11 -11.4315 0.30660E-11 -11.5134 0.82807E+00 -0.0819 21 NaHSiO3,aq 0.23483E-02 -2.6292 0.23483E-02 -2.6292 0.10000E+01 0.0000 22 AlO+ 0.76176E-16 -16.1182 0.63079E-16 -16.2001 0.82807E+00 -0.0819 24 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.47160E-05 -5.3264 0.38889E-05 -5.4102 0.82461E+00 -0.0838 26 CH4,aq 0.10016E-01 -1.9993 0.99998E-02 -2.0000 0.99836E+00 -0.0007 27 C2H6,aq 0.14786E-08 -8.8301 0.14762E-08 -8.8309 0.99836E+00 -0.0007 28 C3H8,aq 0.50394E-14 -14.2976 0.50311E-14 -14.2983 0.99836E+00 -0.0007 29 C4H10,aq 0.16873E-19 -19.7728 0.16845E-19 -19.7735 0.99836E+00 -0.0007 30 ethanol,aq 0.54271E-16 -16.2654 0.54182E-16 -16.2661 0.99836E+00 -0.0007 31 CO,aq 0.75003E-14 -14.1249 0.75003E-14 -14.1249 0.10000E+01 0.0000 32 CO2,aq 0.25820E-07 -7.5880 0.25778E-07 -7.5888 0.99836E+00 -0.0007 33 CO3-2 0.29644E-03 -3.5281 0.14737E-03 -3.8316 0.49712E+00 -0.3035 34 CaCO3,aq 0.16701E-06 -6.7773 0.16701E-06 -6.7773 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.39746E-09 -9.4007 0.32912E-09 -9.4826 0.82807E+00 -0.0819 36 CaCl+ 0.16416E-09 -9.7847 0.13593E-09 -9.8667 0.82807E+00 -0.0819 37 CaCl2,aq 0.30014E-13 -13.5227 0.30014E-13 -13.5227 0.10000E+01 0.0000 38 CaF+ 0.13418E-11 -11.8723 0.11111E-11 -11.9543 0.82807E+00 -0.0819 39 CaOH+ 0.91986E-07 -7.0363 0.76171E-07 -7.1182 0.82807E+00 -0.0819 40 CaSO4,aq 0.11718E-14 -14.9311 0.11718E-14 -14.9311 0.10000E+01 0.0000 41 HCl,aq 0.14399E-13 -13.8417 0.14399E-13 -13.8417 0.10000E+01 0.0000 45 HF,aq 0.48735E-12 -12.3122 0.48735E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16766E-18 -18.7756 0.13854E-18 -18.8584 0.82629E+00 -0.0829 48 FeCl+ 0.68999E-16 -16.1612 0.57136E-16 -16.2431 0.82807E+00 -0.0819 51 FeF+ 0.20182E-17 -17.6950 0.16712E-17 -17.7770 0.82807E+00 -0.0819 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.18055E-10 -10.7434 0.14950E-10 -10.8253 0.82807E+00 -0.0819 55 HFeO2- 0.31612E-07 -7.5001 0.26121E-07 -7.5830 0.82629E+00 -0.0829 56 FeO+ 0.12655E-16 -16.8977 0.10479E-16 -16.9797 0.82807E+00 -0.0819 58 FeO2- 0.36292E-09 -9.4402 0.29987E-09 -9.5231 0.82629E+00 -0.0829 59 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11599E-04 -4.9356 0.11580E-04 -4.9363 0.99836E+00 -0.0007 61 KCl,aq 0.25123E-08 -8.5999 0.25123E-08 -8.5999 0.10000E+01 0.0000 63 KOH,aq 0.75321E-06 -6.1231 0.75321E-06 -6.1231 0.10000E+01 0.0000 64 KSO4- 0.11436E-12 -12.9417 0.94496E-13 -13.0246 0.82629E+00 -0.0829 65 MgCO3,aq 0.65191E-11 -11.1858 0.65191E-11 -11.1858 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.63244E-13 -13.1990 0.52370E-13 -13.2809 0.82807E+00 -0.0819 67 MgCl+ 0.23169E-13 -13.6351 0.19186E-13 -13.7170 0.82807E+00 -0.0819 68 MgF+ 0.77400E-15 -15.1113 0.64092E-15 -15.1932 0.82807E+00 -0.0819 69 MgOH+ 0.79264E-10 -10.1009 0.65636E-10 -10.1829 0.82807E+00 -0.0819 71 MnF+ 0.21507E-15 -15.6674 0.17810E-15 -15.7493 0.82807E+00 -0.0819 72 MnO,aq 0.18188E-08 -8.7402 0.18188E-08 -8.7402 0.10000E+01 0.0000 73 MnOH+ 0.54227E-09 -9.2658 0.44904E-09 -9.3477 0.82807E+00 -0.0819 74 MnO2-2 0.16981E-10 -10.7700 0.84416E-11 -11.0736 0.49712E+00 -0.3035 75 HMnO2- 0.18925E-09 -9.7230 0.15637E-09 -9.8058 0.82629E+00 -0.0829 78 MnCl+ 0.86790E-13 -13.0615 0.71868E-13 -13.1435 0.82807E+00 -0.0819 79 MnSO4,aq 0.14802E-18 -18.8297 0.14802E-18 -18.8297 0.10000E+01 0.0000 80 NaCl,aq 0.58183E-05 -5.2352 0.58183E-05 -5.2352 0.10000E+01 0.0000 81 NaF,aq 0.37239E-08 -8.4290 0.37239E-08 -8.4290 0.10000E+01 0.0000 82 NaOH,aq 0.95977E-04 -4.0178 0.95977E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.82852E-02 -2.0817 0.68321E-02 -2.1654 0.82461E+00 -0.0838 89 HPO3-2 0.13158E-14 -14.8808 0.65413E-15 -15.1843 0.49712E+00 -0.3035 91 H2PO3- 0.13423E-18 -18.8722 0.11091E-18 -18.9550 0.82629E+00 -0.0829 92 H3PO4,aq 0.90614E-18 -18.0428 0.90614E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.34173E-10 -10.4663 0.28267E-10 -10.5487 0.82717E+00 -0.0824 94 PO4-3 0.78707E-09 -9.1040 0.17487E-09 -9.7573 0.22218E+00 -0.6533 98 HP2O7-3 0.70307E-18 -18.1530 0.14798E-18 -18.8298 0.21048E+00 -0.6768 99 P2O7-4 0.63878E-17 -17.1946 0.41811E-18 -18.3787 0.65454E-01 -1.1841 100 H2S,aq 0.77133E-06 -6.1128 0.77006E-06 -6.1135 0.99836E+00 -0.0007 101 S2-2 0.33424E-10 -10.4759 0.16616E-10 -10.7795 0.49712E+00 -0.3035 102 S3-2 0.29944E-17 -17.5237 0.14886E-17 -17.8272 0.49712E+00 -0.3035 107 SO3-2 0.12163E-15 -15.9150 0.61451E-16 -16.2115 0.50522E+00 -0.2965 108 HSO3- 0.39372E-18 -18.4048 0.32533E-18 -18.4877 0.82629E+00 -0.0829 109 HSO4- 0.40132E-17 -17.3965 0.33269E-17 -17.4780 0.82898E+00 -0.0815 111 S2O3-2 0.74306E-18 -18.1290 0.36939E-18 -18.4325 0.49712E+00 -0.3035 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1016351E-09 -.2034958E-01 -.2046936E+02 0.0000 2 H2O 0.1000000E+01 0.5551502E+02 0.9980818E+06 0.0000 3 Cl- 0.1124728E-02 0.1130549E-02 0.3999969E+02 7.0411 4 SO4-- 0.8193296E-10 -.1001913E-01 -.9604922E+03 9.7567 5 HCO3- 0.1723604E-03 0.1048522E-01 0.6384754E+03 6.2272 6 HS- 0.3565731E-02 0.1358563E-01 0.4483884E+03 7.5422 7 Al+++ 0.1577070E-28 0.4716144E-05 0.1269894E+00 0.7392 8 H4SiO4 0.6958388E-03 0.1234571E-01 0.1184195E+04 -3.1575 9 Ca++ 0.1828967E-06 0.4615626E-06 0.1846081E-01 13.1018 10 Mg++ 0.2862917E-10 0.1182025E-09 0.2867882E-05 9.2942 11 Fe++ 0.7890819E-13 0.3220744E-07 0.1795024E-02 6.7350 12 K+ 0.1801656E-03 0.1809213E-03 0.7059971E+01 6.2465 13 Na+ 0.2286766E-01 0.2531777E-01 0.5808643E+03 8.3491 14 Mn++ 0.2548847E-10 0.2592867E-08 0.1421567E-03 9.2447 15 F- 0.1021344E-05 0.1025070E-05 0.1943459E-01 3.9982 16 HPO4-- 0.3636217E-07 0.3718341E-07 0.3561554E-02 12.4040 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278480E+02 -.1012692E-01 -.8277467E+02 0.0000000E+00 2 H2O -.7109851E+01 0.2762692E+02 -.3473677E+02 0.0000000E+00 3 Cl- 0.5626152E-03 0.5626152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1389363E+00 -.4985994E-02 0.1439223E+00 0.0000000E+00 5 HCO3- 0.5217947E-02 0.5217947E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1371614E+00 0.6760856E-02 -.1439223E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2346978E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6143813E-02 0.5205776E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2296955E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5882317E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1602795E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9003508E-04 0.1061481E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1259933E-01 0.6263778E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1290334E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2889600E-04 0.5101235E-06 0.2838588E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1850423E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1307E-13 Mass of aqueous solution: 0.498664E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0719900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.253 0.796 1640. 3.215 30.02 629.4 andradite 0.5757 -0.240 292.6 2.466 5.356 76.01 grossular 0.1394 -0.856 62.80 1.798 1.150 17.47 apatite-OH 0.9834E-02 -2.007 4.940 0.694 0.9044E-01 1.570 apatite-F 0.2839E-04 -4.547 0.1432E-01 -1.844 0.2621E-03 0.4472E-02 clinochlore 0.7053 -0.152 392.0 2.593 7.176 149.1 daphnite 0.2042 -0.690 145.7 2.163 2.667 44.15 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1241 -0.906 26.88 1.429 0.4921 8.215 hedenbergite 0.3219E-01 -1.492 7.987 0.902 0.1462 2.188 microcline 0.9364 -0.029 260.6 2.416 4.771 101.8 stilbite 3.224 0.508 2272. 3.356 41.60 1060. stilpnomelane-Fe 0.2502 -0.602 269.7 2.431 4.937 93.16 tr.625ac.25prg.125 0.8768E-01 -1.057 74.94 1.875 1.372 24.12 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1871E-01 0.1871E-01 1.0000 -1.728 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.357568 g Volume = 2210.976998 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0719900 moles log = -1.1427 Original solution: 1000.0103000 g Original solution / Rock added: 13890.96 (Water/Rock Ratio), log = 4.1427 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 15.9180 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.6601E-01 0.9571 0.1006E+01 0.1051E+01 CO2,gas 0.1785E-06 0.9707 0.2758E-05 0.2841E-05 CH4,gas 0.9330E+00 0.9910 0.1472E+02 0.1485E+02 H2,gas 0.9471E-03 1.0085 0.1520E-01 0.1508E-01 H2S,gas 0.1414E-05 0.9406 0.2117E-04 0.2251E-04 S2,gas 0.4571E-26 1.0000 0.7277E-25 0.7277E-25 CO,gas 0.7022E-12 1.0000 0.1118E-10 0.1118E-10 SO3,gas 0.6934E-47 1.0000 0.1104E-45 0.1104E-45 SO2,gas 0.4102E-26 1.0000 0.6530E-25 0.6530E-25 HF,gas 0.7517E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1596E-17 1.0000 0.2541E-16 0.2541E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.003 2 CO2,gas -6.66 -13.92 -7.26 -2.419 0.12393E+05 -5.559 3 CH4,gas 4.54 4.01 -0.53 -0.133 0.90682E+03 1.168 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.60 -6.37 -3.187 0.10882E+05 -4.674 6 S2,gas -7.34 -34.17 -26.84 -4.129 0.45824E+05 -25.138 7 CO,gas 3.21 -9.44 -12.65 -3.893 0.21601E+05 -10.952 8 SO3,gas 17.12 -30.53 -47.66 -11.914 0.81371E+05 -45.957 9 SO2,gas 0.83 -26.05 -26.88 -7.169 0.45904E+05 -25.185 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.10 -18.29 -9.147 0.31237E+05 -16.595 12 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80550E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93650E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28495E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 38 aragonite 0.97 -0.82 -1.78 -0.594 0.30449E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55912E+04 40 calcite 0.81 -0.82 -1.63 -0.543 0.27807E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52803E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71073E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39697E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68945E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.57 -3.84 -0.256 0.65495E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.95 -1.85 -0.529 0.31597E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37137E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.95 -1.41 -0.402 0.24019E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28623E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82190E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36683E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91151E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -22.95 -1.71 -0.402 0.29160E+04 146 pyrrhotite -4.26 -5.87 -1.61 -0.536 0.27459E+04 147 pyrrhotiteFe0.875 -6.02 -7.27 -1.25 -0.459 0.21331E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22392E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28668E+03 154 rhodochrosite -0.98 -4.67 -3.70 -1.233 0.63135E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23195E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.18 -4.58 -1.525 0.78124E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27809E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47023E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90666E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77506E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65444E+04 184 troilite-low -4.41 -5.87 -1.46 -0.486 0.24887E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60598E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58212E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66550E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.36 -2.38 -0.794 0.40655E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0719900 MOLES New total amount of reactant added: 0.0739900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8653E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0739900 Water: Moles liquid = 0.2763E+02 kg liquid = 0.4977E+00 Moles total = -.7108E+01 kg total = -.1281E+00 Activity = 0.9998 Stoichiometric ionic strength = .5162835E-02 Osmotic coef. = 0.9408 True ionic strength = .2343540E-01 Chg. balance for total moles = -.8653E-10 Max. difference allowed = 0.5744E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10200E-09 -9.9914 0.84838E-10 -10.0714 0.83171E+00 -0.0800 2 H2O 0.99981E+00 -0.0001 0.99981E+00 -0.0001 3 Cl- 0.11482E-02 -2.9400 0.94849E-03 -3.0230 0.82606E+00 -0.0830 4 SO4-- 0.83953E-10 -10.0760 0.41790E-10 -10.3789 0.49778E+00 -0.3030 5 HCO3- 0.17662E-03 -3.7530 0.14614E-03 -3.8352 0.82743E+00 -0.0823 6 HS- 0.36631E-02 -2.4362 0.30264E-02 -2.5191 0.82620E+00 -0.0829 7 Al+++ 0.15970E-28 -28.7967 0.33491E-29 -29.4751 0.20972E+00 -0.6784 8 H4SiO4 0.69583E-03 -3.1575 0.69583E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.18433E-06 -6.7344 0.90995E-07 -7.0410 0.49364E+00 -0.3066 10 Mg++ 0.28855E-10 -10.5398 0.14170E-10 -10.8486 0.49109E+00 -0.3088 11 Fe++ 0.79530E-13 -13.0995 0.39104E-13 -13.4078 0.49169E+00 -0.3083 12 K+ 0.18082E-03 -3.7428 0.14965E-03 -3.8249 0.82764E+00 -0.0822 13 Na+ 0.22951E-01 -1.6392 0.18955E-01 -1.7223 0.82588E+00 -0.0831 14 Mn++ 0.25694E-10 -10.5902 0.12646E-10 -10.8981 0.49216E+00 -0.3079 15 F- 0.10182E-05 -5.9922 0.83913E-06 -6.0762 0.82414E+00 -0.0840 16 HPO4-- 0.36156E-07 -7.4418 0.18001E-07 -7.7447 0.49786E+00 -0.3029 18 HSiO3- 0.92728E-02 -2.0328 0.76599E-02 -2.1158 0.82606E+00 -0.0830 19 Ca(HSiO3)+ 0.19175E-07 -7.7173 0.15874E-07 -7.7993 0.82785E+00 -0.0821 20 Mg(HSiO3)+ 0.37161E-11 -11.4299 0.30763E-11 -11.5120 0.82785E+00 -0.0821 21 NaHSiO3,aq 0.23483E-02 -2.6293 0.23483E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.76454E-16 -16.1166 0.63292E-16 -16.1987 0.82785E+00 -0.0821 24 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.47015E-05 -5.3278 0.38758E-05 -5.4116 0.82438E+00 -0.0839 26 CH4,aq 0.10295E-01 -1.9874 0.10279E-01 -1.9881 0.99841E+00 -0.0007 27 C2H6,aq 0.15622E-08 -8.8063 0.15597E-08 -8.8070 0.99841E+00 -0.0007 28 C3H8,aq 0.54729E-14 -14.2618 0.54642E-14 -14.2625 0.99841E+00 -0.0007 29 C4H10,aq 0.18835E-19 -19.7250 0.18805E-19 -19.7257 0.99841E+00 -0.0007 30 ethanol,aq 0.57340E-16 -16.2415 0.57249E-16 -16.2422 0.99841E+00 -0.0007 31 CO,aq 0.77097E-14 -14.1130 0.77097E-14 -14.1130 0.10000E+01 0.0000 32 CO2,aq 0.26540E-07 -7.5761 0.26497E-07 -7.5768 0.99841E+00 -0.0007 33 CO3-2 0.30300E-03 -3.5186 0.15046E-03 -3.8226 0.49659E+00 -0.3040 34 CaCO3,aq 0.17167E-06 -6.7653 0.17167E-06 -6.7653 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.41004E-09 -9.3872 0.33945E-09 -9.4692 0.82785E+00 -0.0821 36 CaCl+ 0.16872E-09 -9.7728 0.13967E-09 -9.8549 0.82785E+00 -0.0821 37 CaCl2,aq 0.31474E-13 -13.5020 0.31474E-13 -13.5020 0.10000E+01 0.0000 38 CaF+ 0.13466E-11 -11.8707 0.11148E-11 -11.9528 0.82785E+00 -0.0821 39 CaOH+ 0.92321E-07 -7.0347 0.76427E-07 -7.1168 0.82785E+00 -0.0821 40 CaSO4,aq 0.12075E-14 -14.9181 0.12075E-14 -14.9181 0.10000E+01 0.0000 41 HCl,aq 0.14745E-13 -13.8313 0.14745E-13 -13.8313 0.10000E+01 0.0000 45 HF,aq 0.48735E-12 -12.3122 0.48735E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16715E-18 -18.7769 0.13807E-18 -18.8599 0.82606E+00 -0.0830 48 FeCl+ 0.70916E-16 -16.1493 0.58708E-16 -16.2313 0.82785E+00 -0.0821 51 FeF+ 0.20255E-17 -17.6935 0.16768E-17 -17.7755 0.82785E+00 -0.0821 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.18120E-10 -10.7418 0.15001E-10 -10.8239 0.82785E+00 -0.0821 55 HFeO2- 0.31514E-07 -7.5015 0.26033E-07 -7.5845 0.82606E+00 -0.0830 56 FeO+ 0.12701E-16 -16.8962 0.10514E-16 -16.9782 0.82785E+00 -0.0821 58 FeO2- 0.36179E-09 -9.4415 0.29886E-09 -9.5245 0.82606E+00 -0.0830 59 HFeO2,aq 0.32248E-11 -11.4915 0.32248E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11599E-04 -4.9356 0.11580E-04 -4.9363 0.99841E+00 -0.0007 61 KCl,aq 0.25727E-08 -8.5896 0.25727E-08 -8.5896 0.10000E+01 0.0000 63 KOH,aq 0.75319E-06 -6.1231 0.75319E-06 -6.1231 0.10000E+01 0.0000 64 KSO4- 0.11748E-12 -12.9300 0.97049E-13 -13.0130 0.82606E+00 -0.0830 65 MgCO3,aq 0.67010E-11 -11.1739 0.67010E-11 -11.1739 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.65246E-13 -13.1854 0.54014E-13 -13.2675 0.82785E+00 -0.0821 67 MgCl+ 0.23813E-13 -13.6232 0.19714E-13 -13.7052 0.82785E+00 -0.0821 68 MgF+ 0.77682E-15 -15.1097 0.64308E-15 -15.1917 0.82785E+00 -0.0821 69 MgOH+ 0.79553E-10 -10.0993 0.65858E-10 -10.1814 0.82785E+00 -0.0821 71 MnF+ 0.21590E-15 -15.6657 0.17873E-15 -15.7478 0.82785E+00 -0.0821 72 MnO,aq 0.18191E-08 -8.7401 0.18191E-08 -8.7401 0.10000E+01 0.0000 73 MnOH+ 0.54435E-09 -9.2641 0.45064E-09 -9.3462 0.82785E+00 -0.0821 74 MnO2-2 0.16888E-10 -10.7724 0.83864E-11 -11.0764 0.49659E+00 -0.3040 75 HMnO2- 0.18870E-09 -9.7242 0.15588E-09 -9.8072 0.82606E+00 -0.0830 78 MnCl+ 0.89219E-13 -13.0495 0.73860E-13 -13.1316 0.82785E+00 -0.0821 79 MnSO4,aq 0.15256E-18 -18.8166 0.15256E-18 -18.8166 0.10000E+01 0.0000 80 NaCl,aq 0.59581E-05 -5.2249 0.59581E-05 -5.2249 0.10000E+01 0.0000 81 NaF,aq 0.37238E-08 -8.4290 0.37238E-08 -8.4290 0.10000E+01 0.0000 82 NaOH,aq 0.95976E-04 -4.0178 0.95976E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.82596E-02 -2.0830 0.68091E-02 -2.1669 0.82438E+00 -0.0839 89 HPO3-2 0.13084E-14 -14.8833 0.64973E-15 -15.1873 0.49659E+00 -0.3040 91 H2PO3- 0.13381E-18 -18.8735 0.11054E-18 -18.9565 0.82606E+00 -0.0830 92 H3PO4,aq 0.90614E-18 -18.0428 0.90614E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.34067E-10 -10.4677 0.28172E-10 -10.5502 0.82695E+00 -0.0825 94 PO4-3 0.78092E-09 -9.1074 0.17311E-09 -9.7617 0.22168E+00 -0.6543 98 HP2O7-3 0.69770E-18 -18.1563 0.14649E-18 -18.8342 0.20997E+00 -0.6778 99 P2O7-4 0.63290E-17 -17.1987 0.41251E-18 -18.3846 0.65178E-01 -1.1859 100 H2S,aq 0.79480E-06 -6.0997 0.79354E-06 -6.1004 0.99841E+00 -0.0007 101 S2-2 0.35292E-10 -10.4523 0.17526E-10 -10.7563 0.49659E+00 -0.3040 102 S3-2 0.32582E-17 -17.4870 0.16180E-17 -17.7910 0.49659E+00 -0.3040 107 SO3-2 0.12463E-15 -15.9044 0.62900E-16 -16.2014 0.50471E+00 -0.2970 108 HSO3- 0.40447E-18 -18.3931 0.33412E-18 -18.4761 0.82606E+00 -0.0830 109 HSO4- 0.41227E-17 -17.3848 0.34168E-17 -17.4664 0.82876E+00 -0.0816 111 S2O3-2 0.78460E-18 -18.1053 0.38962E-18 -18.4094 0.49659E+00 -0.3040 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1020044E-09 -.2030169E-01 -.2042102E+02 0.0000 2 H2O 0.1000000E+01 0.5551530E+02 0.9980784E+06 0.0000 3 Cl- 0.1148216E-02 0.1154176E-02 0.4083529E+02 7.0484 4 SO4-- 0.8395330E-10 -.1029809E-01 -.9872264E+03 9.7639 5 HCO3- 0.1766230E-03 0.1077500E-01 0.6561153E+03 6.2362 6 HS- 0.3663099E-02 0.1396198E-01 0.4608058E+03 7.5523 7 Al+++ 0.1596998E-28 0.4701615E-05 0.1265971E+00 0.7392 8 H4SiO4 0.6958349E-03 0.1231693E-01 0.1181425E+04 -3.1575 9 Ca++ 0.1843346E-06 0.4680840E-06 0.1872148E-01 13.1018 10 Mg++ 0.2885467E-10 0.1189157E-09 0.2885163E-05 9.2942 11 Fe++ 0.7952978E-13 0.3210856E-07 0.1789498E-02 6.7350 12 K+ 0.1808202E-03 0.1815759E-03 0.7085455E+01 6.2465 13 Na+ 0.2295088E-01 0.2540109E-01 0.5827712E+03 8.3491 14 Mn++ 0.2569421E-10 0.2594873E-08 0.1422654E-03 9.2448 15 F- 0.1018191E-05 0.1021917E-05 0.1937465E-01 3.9952 16 HPO4-- 0.3615636E-07 0.3697135E-07 0.3541213E-02 12.3981 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278458E+02 -.1010383E-01 -.8277448E+02 0.0000000E+00 2 H2O -.7108213E+01 0.2762908E+02 -.3473729E+02 0.0000000E+00 3 Cl- 0.5744152E-03 0.5744152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1389458E+00 -.5125193E-02 0.1440710E+00 0.0000000E+00 5 HCO3- 0.5362547E-02 0.5362547E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1371224E+00 0.6948654E-02 -.1440710E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2339919E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6129941E-02 0.5205777E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2329579E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5918244E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1597992E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9036744E-04 0.1061481E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1264172E-01 0.6263735E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1291427E-08 0.8669296E-01 0.0000000E+00 15 F- 0.2969600E-04 0.5085916E-06 0.2918741E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1840005E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.2600E-13 Mass of aqueous solution: 0.498704E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0739900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.253 0.796 1640. 3.215 30.02 629.4 andradite 0.5763 -0.239 292.9 2.467 5.361 76.09 grossular 0.1396 -0.855 62.87 1.798 1.151 17.49 apatite-OH 0.9833E-02 -2.007 4.940 0.694 0.9043E-01 1.570 apatite-F 0.2919E-04 -4.535 0.1472E-01 -1.832 0.2695E-03 0.4598E-02 clinochlore 0.7051 -0.152 391.9 2.593 7.175 149.1 daphnite 0.2042 -0.690 145.7 2.163 2.667 44.14 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1202 -0.920 26.04 1.416 0.4767 7.958 hedenbergite 0.3119E-01 -1.506 7.738 0.889 0.1417 2.119 microcline 0.9365 -0.028 260.7 2.416 4.772 101.8 stilbite 3.225 0.508 2272. 3.356 41.60 1060. stilpnomelane-Fe 0.2499 -0.602 269.3 2.430 4.931 93.04 tr.625ac.25prg.125 0.8894E-01 -1.051 76.02 1.881 1.392 24.47 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1871E-01 0.1871E-01 1.0000 -1.728 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.358031 g Volume = 2210.982552 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0739900 moles log = -1.1308 Original solution: 1000.0103000 g Original solution / Rock added: 13515.48 (Water/Rock Ratio), log = 4.1308 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 16.3371 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.6435E-01 0.9566 0.1006E+01 0.1051E+01 CO2,gas 0.1789E-06 0.9701 0.2835E-05 0.2922E-05 CH4,gas 0.9347E+00 0.9908 0.1513E+02 0.1527E+02 H2,gas 0.9225E-03 1.0087 0.1520E-01 0.1507E-01 H2S,gas 0.1422E-05 0.9391 0.2181E-04 0.2323E-04 S2,gas 0.4730E-26 1.0000 0.7727E-25 0.7727E-25 CO,gas 0.7032E-12 1.0000 0.1149E-10 0.1149E-10 SO3,gas 0.6963E-47 1.0000 0.1137E-45 0.1137E-45 SO2,gas 0.4119E-26 1.0000 0.6729E-25 0.6729E-25 HF,gas 0.7324E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1593E-17 1.0000 0.2602E-16 0.2602E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.003 2 CO2,gas -6.66 -13.91 -7.25 -2.415 0.12373E+05 -5.547 3 CH4,gas 4.54 4.02 -0.52 -0.130 0.88642E+03 1.180 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.59 -6.36 -3.180 0.10860E+05 -4.661 6 S2,gas -7.34 -34.15 -26.81 -4.125 0.45779E+05 -25.112 7 CO,gas 3.21 -9.42 -12.64 -3.889 0.21580E+05 -10.940 8 SO3,gas 17.12 -30.52 -47.64 -11.911 0.81349E+05 -45.944 9 SO2,gas 0.83 -26.04 -26.87 -7.166 0.45881E+05 -25.172 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.09 -18.28 -9.142 0.31219E+05 -16.585 12 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80545E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93651E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28495E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75900E+04 38 aragonite 0.97 -0.80 -1.77 -0.590 0.30245E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55912E+04 40 calcite 0.81 -0.80 -1.62 -0.539 0.27603E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52804E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71074E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39697E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68945E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 55 chloritoid-Mn 11.40 7.57 -3.84 -0.256 0.65494E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10194E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.94 -1.84 -0.525 0.31392E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65865E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37137E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.94 -1.39 -0.398 0.23815E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28623E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82188E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36683E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91151E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -22.93 -1.68 -0.396 0.28715E+04 146 pyrrhotite -4.26 -5.86 -1.60 -0.532 0.27236E+04 147 pyrrhotiteFe0.875 -6.02 -7.25 -1.24 -0.455 0.21108E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22391E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28668E+03 154 rhodochrosite -0.98 -4.66 -3.69 -1.229 0.62930E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23193E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.17 -4.56 -1.521 0.77920E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27809E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47020E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90666E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77506E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65444E+04 184 troilite-low -4.41 -5.86 -1.44 -0.481 0.24664E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60598E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66176E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58212E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66550E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.35 -2.37 -0.789 0.40430E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0739900 MOLES New total amount of reactant added: 0.0759900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8652E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0759900 Water: Moles liquid = 0.2763E+02 kg liquid = 0.4977E+00 Moles total = -.7107E+01 kg total = -.1280E+00 Activity = 0.9998 Stoichiometric ionic strength = .4991660E-02 Osmotic coef. = 0.9417 True ionic strength = .2352586E-01 Chg. balance for total moles = -.8652E-10 Max. difference allowed = 0.5862E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10237E-09 -9.9898 0.85124E-10 -10.0699 0.83150E+00 -0.0801 2 H2O 0.99981E+00 -0.0001 0.99981E+00 -0.0001 3 Cl- 0.11717E-02 -2.9312 0.96763E-03 -3.0143 0.82583E+00 -0.0831 4 SO4-- 0.85963E-10 -10.0657 0.42745E-10 -10.3691 0.49725E+00 -0.3034 5 HCO3- 0.18086E-03 -3.7427 0.14961E-03 -3.8250 0.82720E+00 -0.0824 6 HS- 0.37605E-02 -2.4248 0.31060E-02 -2.5078 0.82597E+00 -0.0830 7 Al+++ 0.16171E-28 -28.7913 0.33831E-29 -29.4707 0.20921E+00 -0.6794 8 H4SiO4 0.69583E-03 -3.1575 0.69583E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.18578E-06 -6.7310 0.91609E-07 -7.0381 0.49310E+00 -0.3071 10 Mg++ 0.29081E-10 -10.5364 0.14266E-10 -10.8457 0.49054E+00 -0.3093 11 Fe++ 0.80155E-13 -13.0961 0.39368E-13 -13.4049 0.49115E+00 -0.3088 12 K+ 0.18148E-03 -3.7412 0.15016E-03 -3.8235 0.82742E+00 -0.0823 13 Na+ 0.23034E-01 -1.6376 0.19018E-01 -1.7208 0.82566E+00 -0.0832 14 Mn++ 0.25901E-10 -10.5867 0.12733E-10 -10.8951 0.49162E+00 -0.3084 15 F- 0.10151E-05 -5.9935 0.83631E-06 -6.0776 0.82391E+00 -0.0841 16 HPO4-- 0.35952E-07 -7.4443 0.17880E-07 -7.7476 0.49733E+00 -0.3034 18 HSiO3- 0.92442E-02 -2.0341 0.76342E-02 -2.1172 0.82583E+00 -0.0831 19 Ca(HSiO3)+ 0.19244E-07 -7.7157 0.15927E-07 -7.7979 0.82762E+00 -0.0822 20 Mg(HSiO3)+ 0.37296E-11 -11.4283 0.30867E-11 -11.5105 0.82762E+00 -0.0822 21 NaHSiO3,aq 0.23482E-02 -2.6293 0.23482E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.76733E-16 -16.1150 0.63506E-16 -16.1972 0.82762E+00 -0.0822 24 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.46870E-05 -5.3291 0.38628E-05 -5.4131 0.82415E+00 -0.0840 26 CH4,aq 0.10574E-01 -1.9758 0.10558E-01 -1.9764 0.99846E+00 -0.0007 27 C2H6,aq 0.16481E-08 -8.7830 0.16456E-08 -8.7837 0.99846E+00 -0.0007 28 C3H8,aq 0.59308E-14 -14.2269 0.59216E-14 -14.2276 0.99846E+00 -0.0007 29 C4H10,aq 0.20965E-19 -19.6785 0.20933E-19 -19.6792 0.99846E+00 -0.0007 30 ethanol,aq 0.60493E-16 -16.2183 0.60400E-16 -16.2190 0.99846E+00 -0.0007 31 CO,aq 0.79192E-14 -14.1013 0.79192E-14 -14.1013 0.10000E+01 0.0000 32 CO2,aq 0.27259E-07 -7.5645 0.27217E-07 -7.5652 0.99846E+00 -0.0007 33 CO3-2 0.30947E-03 -3.5094 0.15351E-03 -3.8139 0.49605E+00 -0.3045 34 CaCO3,aq 0.17634E-06 -6.7537 0.17634E-06 -6.7537 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.42271E-09 -9.3740 0.34984E-09 -9.4561 0.82762E+00 -0.0822 36 CaCl+ 0.17333E-09 -9.7611 0.14345E-09 -9.8433 0.82762E+00 -0.0822 37 CaCl2,aq 0.32978E-13 -13.4818 0.32978E-13 -13.4818 0.10000E+01 0.0000 38 CaF+ 0.13515E-11 -11.8692 0.11186E-11 -11.9513 0.82762E+00 -0.0822 39 CaOH+ 0.92656E-07 -7.0331 0.76684E-07 -7.1153 0.82762E+00 -0.0822 40 CaSO4,aq 0.12435E-14 -14.9054 0.12435E-14 -14.9054 0.10000E+01 0.0000 41 HCl,aq 0.15094E-13 -13.8212 0.15094E-13 -13.8212 0.10000E+01 0.0000 45 HF,aq 0.48735E-12 -12.3122 0.48735E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16663E-18 -18.7783 0.13761E-18 -18.8614 0.82583E+00 -0.0831 48 FeCl+ 0.72855E-16 -16.1375 0.60296E-16 -16.2197 0.82762E+00 -0.0822 51 FeF+ 0.20329E-17 -17.6919 0.16825E-17 -17.7740 0.82762E+00 -0.0822 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.18186E-10 -10.7403 0.15051E-10 -10.8224 0.82762E+00 -0.0822 55 HFeO2- 0.31417E-07 -7.5028 0.25945E-07 -7.5859 0.82583E+00 -0.0831 56 FeO+ 0.12747E-16 -16.8946 0.10550E-16 -16.9768 0.82762E+00 -0.0822 58 FeO2- 0.36068E-09 -9.4429 0.29786E-09 -9.5260 0.82583E+00 -0.0831 59 HFeO2,aq 0.32247E-11 -11.4915 0.32247E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11598E-04 -4.9356 0.11580E-04 -4.9363 0.99846E+00 -0.0007 61 KCl,aq 0.26334E-08 -8.5795 0.26334E-08 -8.5795 0.10000E+01 0.0000 63 KOH,aq 0.75318E-06 -6.1231 0.75318E-06 -6.1231 0.10000E+01 0.0000 64 KSO4- 0.12060E-12 -12.9186 0.99599E-13 -13.0017 0.82583E+00 -0.0831 65 MgCO3,aq 0.68830E-11 -11.1622 0.68830E-11 -11.1622 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.67262E-13 -13.1722 0.55668E-13 -13.2544 0.82762E+00 -0.0822 67 MgCl+ 0.24464E-13 -13.6115 0.20247E-13 -13.6936 0.82762E+00 -0.0822 68 MgF+ 0.77964E-15 -15.1081 0.64525E-15 -15.1903 0.82762E+00 -0.0822 69 MgOH+ 0.79842E-10 -10.0978 0.66079E-10 -10.1799 0.82762E+00 -0.0822 71 MnF+ 0.21673E-15 -15.6641 0.17937E-15 -15.7463 0.82762E+00 -0.0822 72 MnO,aq 0.18195E-08 -8.7400 0.18195E-08 -8.7400 0.10000E+01 0.0000 73 MnOH+ 0.54644E-09 -9.2625 0.45225E-09 -9.3446 0.82762E+00 -0.0822 74 MnO2-2 0.16796E-10 -10.7748 0.83318E-11 -11.0793 0.49605E+00 -0.3045 75 HMnO2- 0.18815E-09 -9.7255 0.15538E-09 -9.8086 0.82583E+00 -0.0831 78 MnCl+ 0.91676E-13 -13.0377 0.75873E-13 -13.1199 0.82762E+00 -0.0822 79 MnSO4,aq 0.15713E-18 -18.8037 0.15713E-18 -18.8037 0.10000E+01 0.0000 80 NaCl,aq 0.60987E-05 -5.2148 0.60987E-05 -5.2148 0.10000E+01 0.0000 81 NaF,aq 0.37237E-08 -8.4290 0.37237E-08 -8.4290 0.10000E+01 0.0000 82 NaOH,aq 0.95974E-04 -4.0178 0.95974E-04 -4.0178 0.10000E+01 0.0000 84 OH- 0.82342E-02 -2.0844 0.67862E-02 -2.1684 0.82415E+00 -0.0840 89 HPO3-2 0.13010E-14 -14.8857 0.64538E-15 -15.1902 0.49605E+00 -0.3045 91 H2PO3- 0.13340E-18 -18.8748 0.11017E-18 -18.9580 0.82583E+00 -0.0831 92 H3PO4,aq 0.90614E-18 -18.0428 0.90614E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.33962E-10 -10.4690 0.28077E-10 -10.5516 0.82672E+00 -0.0826 94 PO4-3 0.77483E-09 -9.1108 0.17138E-09 -9.7660 0.22118E+00 -0.6553 98 HP2O7-3 0.69238E-18 -18.1597 0.14502E-18 -18.8386 0.20946E+00 -0.6789 99 P2O7-4 0.62708E-17 -17.2027 0.40700E-18 -18.3904 0.64904E-01 -1.1877 100 H2S,aq 0.81841E-06 -6.0870 0.81715E-06 -6.0877 0.99846E+00 -0.0007 101 S2-2 0.37213E-10 -10.4293 0.18460E-10 -10.7338 0.49605E+00 -0.3045 102 S3-2 0.35378E-17 -17.4513 0.17549E-17 -17.7557 0.49605E+00 -0.3045 107 SO3-2 0.12760E-15 -15.8941 0.64337E-16 -16.1915 0.50419E+00 -0.2974 108 HSO3- 0.41522E-18 -18.3817 0.34290E-18 -18.4648 0.82583E+00 -0.0831 109 HSO4- 0.42323E-17 -17.3734 0.35066E-17 -17.4551 0.82854E+00 -0.0817 111 S2O3-2 0.82729E-18 -18.0823 0.41038E-18 -18.3868 0.49605E+00 -0.3045 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1023741E-09 -.2025403E-01 -.2037291E+02 0.0000 2 H2O 0.1000000E+01 0.5551558E+02 0.9980751E+06 0.0000 3 Cl- 0.1171699E-02 0.1177800E-02 0.4167075E+02 7.0557 4 SO4-- 0.8596288E-10 -.1057710E-01 -.1013966E+04 9.7708 5 HCO3- 0.1808606E-03 0.1106474E-01 0.6737523E+03 6.2449 6 HS- 0.3760452E-02 0.1433837E-01 0.4732244E+03 7.5622 7 Al+++ 0.1617130E-28 0.4687165E-05 0.1262069E+00 0.7392 8 H4SiO4 0.6958310E-03 0.1228831E-01 0.1178670E+04 -3.1575 9 Ca++ 0.1857802E-06 0.4746153E-06 0.1898255E-01 13.1018 10 Mg++ 0.2908140E-10 0.1196270E-09 0.2902397E-05 9.2942 11 Fe++ 0.8015475E-13 0.3201022E-07 0.1784002E-02 6.7350 12 K+ 0.1814755E-03 0.1822313E-03 0.7110968E+01 6.2465 13 Na+ 0.2303421E-01 0.2548452E-01 0.5846803E+03 8.3491 14 Mn++ 0.2590113E-10 0.2596887E-08 0.1423747E-03 9.2448 15 F- 0.1015055E-05 0.1018781E-05 0.1931503E-01 3.9923 16 HPO4-- 0.3595222E-07 0.3676102E-07 0.3521037E-02 12.3923 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278437E+02 -.1008085E-01 -.8277428E+02 0.0000000E+00 2 H2O -.7106576E+01 0.2763124E+02 -.3473782E+02 0.0000000E+00 3 Cl- 0.5862152E-03 0.5862152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1389554E+00 -.5264441E-02 0.1442198E+00 0.0000000E+00 5 HCO3- 0.5507147E-02 0.5507147E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1370833E+00 0.7136502E-02 -.1442198E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2332898E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6116146E-02 0.5205779E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2362257E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5954082E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1593214E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9070025E-04 0.1061480E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1268417E-01 0.6263693E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1292524E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3049600E-04 0.5070681E-06 0.2998893E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1829671E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.9784E-15 Mass of aqueous solution: 0.498745E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0759900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.252 0.796 1640. 3.215 30.01 629.4 andradite 0.5769 -0.239 293.2 2.467 5.367 76.16 grossular 0.1397 -0.855 62.93 1.799 1.152 17.51 apatite-OH 0.9833E-02 -2.007 4.939 0.694 0.9042E-01 1.569 apatite-F 0.2999E-04 -4.523 0.1512E-01 -1.820 0.2769E-03 0.4725E-02 clinochlore 0.7050 -0.152 391.8 2.593 7.174 149.0 daphnite 0.2041 -0.690 145.6 2.163 2.666 44.13 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1164 -0.934 25.20 1.401 0.4613 7.702 hedenbergite 0.3018E-01 -1.520 7.488 0.874 0.1371 2.051 microcline 0.9367 -0.028 260.7 2.416 4.773 101.8 stilbite 3.225 0.508 2272. 3.357 41.60 1060. stilpnomelane-Fe 0.2495 -0.603 269.0 2.430 4.925 92.92 tr.625ac.25prg.125 0.9021E-01 -1.045 77.10 1.887 1.412 24.82 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1872E-01 0.1872E-01 1.0000 -1.728 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.358491 g Volume = 2210.988107 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0759900 moles log = -1.1192 Original solution: 1000.0103000 g Original solution / Rock added: 13159.76 (Water/Rock Ratio), log = 4.1192 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 16.7567 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.6278E-01 0.9561 0.1006E+01 0.1052E+01 CO2,gas 0.1793E-06 0.9694 0.2912E-05 0.3004E-05 CH4,gas 0.9363E+00 0.9905 0.1554E+02 0.1569E+02 H2,gas 0.8992E-03 1.0090 0.1520E-01 0.1507E-01 H2S,gas 0.1430E-05 0.9376 0.2246E-04 0.2396E-04 S2,gas 0.4890E-26 1.0000 0.8194E-25 0.8194E-25 CO,gas 0.7043E-12 1.0000 0.1180E-10 0.1180E-10 SO3,gas 0.6990E-47 1.0000 0.1171E-45 0.1171E-45 SO2,gas 0.4135E-26 1.0000 0.6930E-25 0.6930E-25 HF,gas 0.7141E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1589E-17 1.0000 0.2663E-16 0.2663E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.002 2 CO2,gas -6.66 -13.89 -7.23 -2.412 0.12353E+05 -5.536 3 CH4,gas 4.54 4.04 -0.51 -0.127 0.86655E+03 1.191 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.58 -6.35 -3.174 0.10838E+05 -4.649 6 S2,gas -7.34 -34.12 -26.79 -4.121 0.45735E+05 -25.087 7 CO,gas 3.21 -9.41 -12.63 -3.885 0.21560E+05 -10.928 8 SO3,gas 17.12 -30.51 -47.63 -11.908 0.81327E+05 -45.931 9 SO2,gas 0.83 -26.03 -26.86 -7.162 0.45860E+05 -25.159 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.08 -18.27 -9.137 0.31202E+05 -16.575 12 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80541E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93651E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28495E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 38 aragonite 0.97 -0.79 -1.76 -0.587 0.30046E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55912E+04 40 calcite 0.81 -0.79 -1.60 -0.535 0.27404E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52804E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71074E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39697E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68945E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 55 chloritoid-Mn 11.40 7.57 -3.84 -0.256 0.65492E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.93 -1.83 -0.522 0.31194E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33583E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37137E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.93 -1.38 -0.395 0.23616E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28623E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82187E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36683E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91151E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -22.90 -1.66 -0.390 0.28280E+04 146 pyrrhotite -4.26 -5.84 -1.58 -0.527 0.27019E+04 147 pyrrhotiteFe0.875 -6.02 -7.24 -1.22 -0.450 0.20891E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22389E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28668E+03 154 rhodochrosite -0.98 -4.65 -3.67 -1.225 0.62730E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23192E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.16 -4.55 -1.517 0.77721E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27810E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47017E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90665E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77507E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65444E+04 184 troilite-low -4.41 -5.84 -1.43 -0.477 0.24447E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60597E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66175E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58212E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66550E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.33 -2.36 -0.785 0.40212E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18202E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0759900 MOLES New total amount of reactant added: 0.0779900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8653E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0779900 Water: Moles liquid = 0.2763E+02 kg liquid = 0.4978E+00 Moles total = -.7105E+01 kg total = -.1280E+00 Activity = 0.9998 Stoichiometric ionic strength = .4820420E-02 Osmotic coef. = 0.9426 True ionic strength = .2361635E-01 Chg. balance for total moles = -.8653E-10 Max. difference allowed = 0.5980E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10274E-09 -9.9882 0.85410E-10 -10.0685 0.83128E+00 -0.0803 2 H2O 0.99980E+00 -0.0001 0.99980E+00 -0.0001 3 Cl- 0.11952E-02 -2.9226 0.98674E-03 -3.0058 0.82560E+00 -0.0832 4 SO4-- 0.87962E-10 -10.0557 0.43693E-10 -10.3596 0.49672E+00 -0.3039 5 HCO3- 0.18507E-03 -3.7327 0.15305E-03 -3.8152 0.82698E+00 -0.0825 6 HS- 0.38578E-02 -2.4137 0.31855E-02 -2.4968 0.82574E+00 -0.0832 7 Al+++ 0.16375E-28 -28.7858 0.34174E-29 -29.4663 0.20870E+00 -0.6805 8 H4SiO4 0.69583E-03 -3.1575 0.69583E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.18723E-06 -6.7276 0.92225E-07 -7.0351 0.49257E+00 -0.3075 10 Mg++ 0.29309E-10 -10.5330 0.14362E-10 -10.8428 0.49001E+00 -0.3098 11 Fe++ 0.80783E-13 -13.0927 0.39633E-13 -13.4019 0.49062E+00 -0.3093 12 K+ 0.18213E-03 -3.7396 0.15066E-03 -3.8220 0.82720E+00 -0.0824 13 Na+ 0.23118E-01 -1.6361 0.19082E-01 -1.7194 0.82543E+00 -0.0833 14 Mn++ 0.26109E-10 -10.5832 0.12822E-10 -10.8921 0.49108E+00 -0.3088 15 F- 0.10119E-05 -5.9948 0.83351E-06 -6.0791 0.82368E+00 -0.0842 16 HPO4-- 0.35750E-07 -7.4467 0.17761E-07 -7.7505 0.49680E+00 -0.3038 18 HSiO3- 0.92158E-02 -2.0355 0.76086E-02 -2.1187 0.82560E+00 -0.0832 19 Ca(HSiO3)+ 0.19314E-07 -7.7141 0.15981E-07 -7.7964 0.82740E+00 -0.0823 20 Mg(HSiO3)+ 0.37431E-11 -11.4268 0.30970E-11 -11.5091 0.82740E+00 -0.0823 21 NaHSiO3,aq 0.23482E-02 -2.6293 0.23482E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.77012E-16 -16.1134 0.63719E-16 -16.1957 0.82740E+00 -0.0823 24 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.46726E-05 -5.3304 0.38499E-05 -5.4146 0.82391E+00 -0.0841 26 CH4,aq 0.10853E-01 -1.9644 0.10837E-01 -1.9651 0.99851E+00 -0.0006 27 C2H6,aq 0.17364E-08 -8.7604 0.17338E-08 -8.7610 0.99851E+00 -0.0006 28 C3H8,aq 0.64136E-14 -14.1929 0.64041E-14 -14.1935 0.99851E+00 -0.0006 29 C4H10,aq 0.23272E-19 -19.6332 0.23237E-19 -19.6338 0.99851E+00 -0.0006 30 ethanol,aq 0.63732E-16 -16.1956 0.63638E-16 -16.1963 0.99851E+00 -0.0006 31 CO,aq 0.81287E-14 -14.0900 0.81287E-14 -14.0900 0.10000E+01 0.0000 32 CO2,aq 0.27979E-07 -7.5532 0.27937E-07 -7.5538 0.99851E+00 -0.0006 33 CO3-2 0.31587E-03 -3.5005 0.15652E-03 -3.8054 0.49553E+00 -0.3049 34 CaCO3,aq 0.18100E-06 -6.7423 0.18100E-06 -6.7423 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.43547E-09 -9.3610 0.36031E-09 -9.4433 0.82740E+00 -0.0823 36 CaCl+ 0.17799E-09 -9.7496 0.14727E-09 -9.8319 0.82740E+00 -0.0823 37 CaCl2,aq 0.34525E-13 -13.4619 0.34525E-13 -13.4619 0.10000E+01 0.0000 38 CaF+ 0.13564E-11 -11.8676 0.11223E-11 -11.9499 0.82740E+00 -0.0823 39 CaOH+ 0.92992E-07 -7.0316 0.76942E-07 -7.1138 0.82740E+00 -0.0823 40 CaSO4,aq 0.12796E-14 -14.8929 0.12796E-14 -14.8929 0.10000E+01 0.0000 41 HCl,aq 0.15443E-13 -13.8113 0.15443E-13 -13.8113 0.10000E+01 0.0000 45 HF,aq 0.48734E-12 -12.3122 0.48734E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16611E-18 -18.7796 0.13715E-18 -18.8628 0.82560E+00 -0.0832 48 FeCl+ 0.74815E-16 -16.1260 0.61902E-16 -16.2083 0.82740E+00 -0.0823 51 FeF+ 0.20403E-17 -17.6903 0.16881E-17 -17.7726 0.82740E+00 -0.0823 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.18252E-10 -10.7387 0.15102E-10 -10.8210 0.82740E+00 -0.0823 55 HFeO2- 0.31320E-07 -7.5042 0.25858E-07 -7.5874 0.82560E+00 -0.0832 56 FeO+ 0.12793E-16 -16.8930 0.10585E-16 -16.9753 0.82740E+00 -0.0823 58 FeO2- 0.35957E-09 -9.4442 0.29686E-09 -9.5274 0.82560E+00 -0.0832 59 HFeO2,aq 0.32247E-11 -11.4915 0.32247E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11597E-04 -4.9356 0.11580E-04 -4.9363 0.99851E+00 -0.0006 61 KCl,aq 0.26944E-08 -8.5695 0.26944E-08 -8.5695 0.10000E+01 0.0000 63 KOH,aq 0.75316E-06 -6.1231 0.75316E-06 -6.1231 0.10000E+01 0.0000 64 KSO4- 0.12372E-12 -12.9075 0.10215E-12 -12.9908 0.82560E+00 -0.0832 65 MgCO3,aq 0.70651E-11 -11.1509 0.70651E-11 -11.1509 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.69292E-13 -13.1593 0.57332E-13 -13.2416 0.82740E+00 -0.0823 67 MgCl+ 0.25122E-13 -13.5999 0.20786E-13 -13.6822 0.82740E+00 -0.0823 68 MgF+ 0.78246E-15 -15.1065 0.64741E-15 -15.1888 0.82740E+00 -0.0823 69 MgOH+ 0.80131E-10 -10.0962 0.66301E-10 -10.1785 0.82740E+00 -0.0823 71 MnF+ 0.21756E-15 -15.6624 0.18001E-15 -15.7447 0.82740E+00 -0.0823 72 MnO,aq 0.18199E-08 -8.7400 0.18199E-08 -8.7400 0.10000E+01 0.0000 73 MnOH+ 0.54853E-09 -9.2608 0.45386E-09 -9.3431 0.82740E+00 -0.0823 74 MnO2-2 0.16705E-10 -10.7772 0.82777E-11 -11.0821 0.49553E+00 -0.3049 75 HMnO2- 0.18761E-09 -9.7267 0.15489E-09 -9.8100 0.82560E+00 -0.0832 78 MnCl+ 0.94161E-13 -13.0261 0.77908E-13 -13.1084 0.82740E+00 -0.0823 79 MnSO4,aq 0.16173E-18 -18.7912 0.16173E-18 -18.7912 0.10000E+01 0.0000 80 NaCl,aq 0.62400E-05 -5.2048 0.62400E-05 -5.2048 0.10000E+01 0.0000 81 NaF,aq 0.37236E-08 -8.4290 0.37236E-08 -8.4290 0.10000E+01 0.0000 82 NaOH,aq 0.95972E-04 -4.0179 0.95972E-04 -4.0179 0.10000E+01 0.0000 84 OH- 0.82089E-02 -2.0857 0.67634E-02 -2.1698 0.82391E+00 -0.0841 89 HPO3-2 0.12937E-14 -14.8882 0.64107E-15 -15.1931 0.49553E+00 -0.3049 91 H2PO3- 0.13299E-18 -18.8762 0.10980E-18 -18.9594 0.82560E+00 -0.0832 92 H3PO4,aq 0.90614E-18 -18.0428 0.90614E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.33858E-10 -10.4703 0.27983E-10 -10.5531 0.82649E+00 -0.0828 94 PO4-3 0.76881E-09 -9.1142 0.16966E-09 -9.7704 0.22068E+00 -0.6562 98 HP2O7-3 0.68711E-18 -18.1630 0.14357E-18 -18.8429 0.20895E+00 -0.6800 99 P2O7-4 0.62134E-17 -17.2067 0.40158E-18 -18.3962 0.64632E-01 -1.1896 100 H2S,aq 0.84214E-06 -6.0746 0.84088E-06 -6.0753 0.99851E+00 -0.0006 101 S2-2 0.39185E-10 -10.4069 0.19417E-10 -10.7118 0.49553E+00 -0.3049 102 S3-2 0.38334E-17 -17.4164 0.18996E-17 -17.7213 0.49553E+00 -0.3049 107 SO3-2 0.13057E-15 -15.8842 0.65763E-16 -16.1820 0.50368E+00 -0.2978 108 HSO3- 0.42597E-18 -18.3706 0.35168E-18 -18.4538 0.82560E+00 -0.0832 109 HSO4- 0.43418E-17 -17.3623 0.35964E-17 -17.4441 0.82832E+00 -0.0818 111 S2O3-2 0.87113E-18 -18.0599 0.43167E-18 -18.3648 0.49553E+00 -0.3049 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1027443E-09 -.2020659E-01 -.2032501E+02 0.0000 2 H2O 0.1000000E+01 0.5551587E+02 0.9980717E+06 0.0000 3 Cl- 0.1195177E-02 0.1201420E-02 0.4250608E+02 7.0627 4 SO4-- 0.8796179E-10 -.1085618E-01 -.1040711E+04 9.7774 5 HCO3- 0.1850732E-03 0.1135443E-01 0.6913864E+03 6.2533 6 HS- 0.3857791E-02 0.1471481E-01 0.4856443E+03 7.5717 7 Al+++ 0.1637466E-28 0.4672794E-05 0.1258189E+00 0.7392 8 H4SiO4 0.6958271E-03 0.1225985E-01 0.1175930E+04 -3.1575 9 Ca++ 0.1872337E-06 0.4811566E-06 0.1924401E-01 13.1018 10 Mg++ 0.2930937E-10 0.1203436E-09 0.2919758E-05 9.2942 11 Fe++ 0.8078312E-13 0.3191242E-07 0.1778536E-02 6.7350 12 K+ 0.1821316E-03 0.1828875E-03 0.7136512E+01 6.2465 13 Na+ 0.2311763E-01 0.2556805E-01 0.5865917E+03 8.3491 14 Mn++ 0.2610923E-10 0.2598910E-08 0.1424843E-03 9.2449 15 F- 0.1011937E-05 0.1015662E-05 0.1925575E-01 3.9894 16 HPO4-- 0.3574972E-07 0.3655239E-07 0.3501024E-02 12.3864 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278415E+02 -.1005797E-01 -.8277409E+02 0.0000000E+00 2 H2O -.7104938E+01 0.2763340E+02 -.3473834E+02 0.0000000E+00 3 Cl- 0.5980152E-03 0.5980152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1389649E+00 -.5403738E-02 0.1443687E+00 0.0000000E+00 5 HCO3- 0.5651747E-02 0.5651747E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1370443E+00 0.7324400E-02 -.1443687E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2325915E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6102426E-02 0.5205780E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2394990E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.5990186E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1588463E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9103349E-04 0.1061480E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1272667E-01 0.6263650E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1293625E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3129600E-04 0.5055530E-06 0.3079045E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1819420E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1325E-14 Mass of aqueous solution: 0.498786E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0779900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.252 0.796 1639. 3.215 30.01 629.3 andradite 0.5775 -0.238 293.5 2.468 5.372 76.24 grossular 0.1399 -0.854 63.00 1.799 1.153 17.53 apatite-OH 0.9832E-02 -2.007 4.939 0.694 0.9041E-01 1.569 apatite-F 0.3079E-04 -4.512 0.1553E-01 -1.809 0.2843E-03 0.4851E-02 clinochlore 0.7048 -0.152 391.8 2.593 7.172 149.0 daphnite 0.2041 -0.690 145.6 2.163 2.666 44.13 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1125 -0.949 24.36 1.387 0.4460 7.445 hedenbergite 0.2918E-01 -1.535 7.239 0.860 0.1325 1.983 microcline 0.9369 -0.028 260.8 2.416 4.774 101.9 stilbite 3.225 0.509 2273. 3.357 41.60 1060. stilpnomelane-Fe 0.2492 -0.603 268.7 2.429 4.919 92.81 tr.625ac.25prg.125 0.9147E-01 -1.039 78.19 1.893 1.431 25.16 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1872E-01 0.1872E-01 1.0000 -1.728 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.358946 g Volume = 2210.993664 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0779900 moles log = -1.1080 Original solution: 1000.0103000 g Original solution / Rock added: 12822.29 (Water/Rock Ratio), log = 4.1080 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 17.1765 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.6127E-01 0.9557 0.1006E+01 0.1052E+01 CO2,gas 0.1796E-06 0.9687 0.2989E-05 0.3086E-05 CH4,gas 0.9378E+00 0.9902 0.1595E+02 0.1611E+02 H2,gas 0.8771E-03 1.0092 0.1520E-01 0.1506E-01 H2S,gas 0.1438E-05 0.9361 0.2312E-04 0.2469E-04 S2,gas 0.5052E-26 1.0000 0.8677E-25 0.8677E-25 CO,gas 0.7052E-12 1.0000 0.1211E-10 0.1211E-10 SO3,gas 0.7018E-47 1.0000 0.1205E-45 0.1205E-45 SO2,gas 0.4152E-26 1.0000 0.7131E-25 0.7131E-25 HF,gas 0.6966E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1586E-17 1.0000 0.2725E-16 0.2725E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.002 2 CO2,gas -6.66 -13.88 -7.22 -2.408 0.12334E+05 -5.524 3 CH4,gas 4.54 4.05 -0.50 -0.124 0.84719E+03 1.203 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.57 -6.34 -3.168 0.10817E+05 -4.636 6 S2,gas -7.34 -34.10 -26.76 -4.117 0.45693E+05 -25.062 7 CO,gas 3.21 -9.40 -12.62 -3.882 0.21541E+05 -10.917 8 SO3,gas 17.12 -30.50 -47.62 -11.904 0.81306E+05 -45.919 9 SO2,gas 0.83 -26.01 -26.85 -7.159 0.45839E+05 -25.147 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.07 -18.26 -9.132 0.31185E+05 -16.565 12 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80536E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93652E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28495E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 38 aragonite 0.97 -0.78 -1.75 -0.583 0.29852E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55912E+04 40 calcite 0.81 -0.78 -1.59 -0.531 0.27210E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52804E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71074E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39697E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68946E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 55 chloritoid-Mn 11.40 7.57 -3.84 -0.256 0.65491E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.92 -1.82 -0.519 0.31000E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37137E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.92 -1.37 -0.392 0.23422E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28623E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82185E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36683E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91150E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -22.88 -1.63 -0.384 0.27855E+04 146 pyrrhotite -4.26 -5.83 -1.57 -0.523 0.26806E+04 147 pyrrhotiteFe0.875 -6.02 -7.23 -1.21 -0.445 0.20678E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22388E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28667E+03 154 rhodochrosite -0.98 -4.64 -3.66 -1.221 0.62535E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23190E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.15 -4.54 -1.513 0.77527E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27810E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47014E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90665E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77507E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65443E+04 184 troilite-low -4.41 -5.83 -1.42 -0.473 0.24234E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60597E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66175E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58212E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66550E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.32 -2.34 -0.781 0.39998E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0779900 MOLES New total amount of reactant added: 0.0799900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8652E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0799900 Water: Moles liquid = 0.2763E+02 kg liquid = 0.4978E+00 Moles total = -.7103E+01 kg total = -.1280E+00 Activity = 0.9998 Stoichiometric ionic strength = .4649119E-02 Osmotic coef. = 0.9435 True ionic strength = .2370686E-01 Chg. balance for total moles = -.8652E-10 Max. difference allowed = 0.6098E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10311E-09 -9.9867 0.85696E-10 -10.0670 0.83107E+00 -0.0804 2 H2O 0.99980E+00 -0.0001 0.99980E+00 -0.0001 3 Cl- 0.12187E-02 -2.9141 0.10058E-02 -2.9975 0.82538E+00 -0.0833 4 SO4-- 0.89950E-10 -10.0460 0.44633E-10 -10.3503 0.49620E+00 -0.3043 5 HCO3- 0.18926E-03 -3.7229 0.15647E-03 -3.8056 0.82676E+00 -0.0826 6 HS- 0.39551E-02 -2.4028 0.32650E-02 -2.4861 0.82552E+00 -0.0833 7 Al+++ 0.16580E-28 -28.7804 0.34519E-29 -29.4619 0.20820E+00 -0.6815 8 H4SiO4 0.69582E-03 -3.1575 0.69582E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.18870E-06 -6.7242 0.92845E-07 -7.0322 0.49204E+00 -0.3080 10 Mg++ 0.29539E-10 -10.5296 0.14458E-10 -10.8399 0.48947E+00 -0.3103 11 Fe++ 0.81415E-13 -13.0893 0.39900E-13 -13.3990 0.49008E+00 -0.3097 12 K+ 0.18279E-03 -3.7381 0.15116E-03 -3.8206 0.82697E+00 -0.0825 13 Na+ 0.23201E-01 -1.6345 0.19146E-01 -1.7179 0.82520E+00 -0.0834 14 Mn++ 0.26319E-10 -10.5797 0.12910E-10 -10.8891 0.49054E+00 -0.3093 15 F- 0.10088E-05 -5.9962 0.83072E-06 -6.0805 0.82344E+00 -0.0844 16 HPO4-- 0.35549E-07 -7.4492 0.17642E-07 -7.7534 0.49628E+00 -0.3043 18 HSiO3- 0.91875E-02 -2.0368 0.75832E-02 -2.1201 0.82538E+00 -0.0833 19 Ca(HSiO3)+ 0.19384E-07 -7.7126 0.16034E-07 -7.7950 0.82718E+00 -0.0824 20 Mg(HSiO3)+ 0.37567E-11 -11.4252 0.31074E-11 -11.5076 0.82718E+00 -0.0824 21 NaHSiO3,aq 0.23482E-02 -2.6293 0.23482E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.77291E-16 -16.1119 0.63933E-16 -16.1943 0.82718E+00 -0.0824 24 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.46584E-05 -5.3318 0.38370E-05 -5.4160 0.82368E+00 -0.0842 26 CH4,aq 0.11132E-01 -1.9534 0.11116E-01 -1.9540 0.99857E+00 -0.0006 27 C2H6,aq 0.18269E-08 -8.7383 0.18243E-08 -8.7389 0.99857E+00 -0.0006 28 C3H8,aq 0.69221E-14 -14.1598 0.69122E-14 -14.1604 0.99857E+00 -0.0006 29 C4H10,aq 0.25765E-19 -19.5890 0.25728E-19 -19.5896 0.99857E+00 -0.0006 30 ethanol,aq 0.67057E-16 -16.1736 0.66961E-16 -16.1742 0.99857E+00 -0.0006 31 CO,aq 0.83383E-14 -14.0789 0.83383E-14 -14.0789 0.10000E+01 0.0000 32 CO2,aq 0.28699E-07 -7.5421 0.28658E-07 -7.5428 0.99857E+00 -0.0006 33 CO3-2 0.32219E-03 -3.4919 0.15949E-03 -3.7973 0.49500E+00 -0.3054 34 CaCO3,aq 0.18567E-06 -6.7313 0.18567E-06 -6.7313 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.44831E-09 -9.3484 0.37083E-09 -9.4308 0.82718E+00 -0.0824 36 CaCl+ 0.18271E-09 -9.7382 0.15113E-09 -9.8206 0.82718E+00 -0.0824 37 CaCl2,aq 0.36115E-13 -13.4423 0.36115E-13 -13.4423 0.10000E+01 0.0000 38 CaF+ 0.13613E-11 -11.8660 0.11261E-11 -11.9484 0.82718E+00 -0.0824 39 CaOH+ 0.93328E-07 -7.0300 0.77199E-07 -7.1124 0.82718E+00 -0.0824 40 CaSO4,aq 0.13159E-14 -14.8808 0.13159E-14 -14.8808 0.10000E+01 0.0000 41 HCl,aq 0.15795E-13 -13.8015 0.15795E-13 -13.8015 0.10000E+01 0.0000 45 HF,aq 0.48734E-12 -12.3122 0.48734E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16560E-18 -18.7809 0.13669E-18 -18.8643 0.82538E+00 -0.0833 48 FeCl+ 0.76796E-16 -16.1147 0.63524E-16 -16.1971 0.82718E+00 -0.0824 51 FeF+ 0.20477E-17 -17.6887 0.16938E-17 -17.7711 0.82718E+00 -0.0824 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.18318E-10 -10.7371 0.15153E-10 -10.8195 0.82718E+00 -0.0824 55 HFeO2- 0.31224E-07 -7.5055 0.25772E-07 -7.5889 0.82538E+00 -0.0833 56 FeO+ 0.12840E-16 -16.8914 0.10621E-16 -16.9738 0.82718E+00 -0.0824 58 FeO2- 0.35846E-09 -9.4456 0.29587E-09 -9.5289 0.82538E+00 -0.0833 59 HFeO2,aq 0.32247E-11 -11.4915 0.32247E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11597E-04 -4.9357 0.11580E-04 -4.9363 0.99857E+00 -0.0006 61 KCl,aq 0.27557E-08 -8.5598 0.27557E-08 -8.5598 0.10000E+01 0.0000 63 KOH,aq 0.75315E-06 -6.1231 0.75315E-06 -6.1231 0.10000E+01 0.0000 64 KSO4- 0.12684E-12 -12.8967 0.10469E-12 -12.9801 0.82538E+00 -0.0833 65 MgCO3,aq 0.72473E-11 -11.1398 0.72473E-11 -11.1398 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.71336E-13 -13.1467 0.59008E-13 -13.2291 0.82718E+00 -0.0824 67 MgCl+ 0.25787E-13 -13.5886 0.21331E-13 -13.6710 0.82718E+00 -0.0824 68 MgF+ 0.78529E-15 -15.1050 0.64958E-15 -15.1874 0.82718E+00 -0.0824 69 MgOH+ 0.80421E-10 -10.0946 0.66523E-10 -10.1770 0.82718E+00 -0.0824 71 MnF+ 0.21839E-15 -15.6608 0.18065E-15 -15.7432 0.82718E+00 -0.0824 72 MnO,aq 0.18202E-08 -8.7399 0.18202E-08 -8.7399 0.10000E+01 0.0000 73 MnOH+ 0.55063E-09 -9.2591 0.45547E-09 -9.3415 0.82718E+00 -0.0824 74 MnO2-2 0.16614E-10 -10.7795 0.82240E-11 -11.0849 0.49500E+00 -0.3054 75 HMnO2- 0.18707E-09 -9.7280 0.15440E-09 -9.8113 0.82538E+00 -0.0833 78 MnCl+ 0.96673E-13 -13.0147 0.79966E-13 -13.0971 0.82718E+00 -0.0824 79 MnSO4,aq 0.16635E-18 -18.7790 0.16635E-18 -18.7790 0.10000E+01 0.0000 80 NaCl,aq 0.63820E-05 -5.1950 0.63820E-05 -5.1950 0.10000E+01 0.0000 81 NaF,aq 0.37236E-08 -8.4290 0.37236E-08 -8.4290 0.10000E+01 0.0000 82 NaOH,aq 0.95970E-04 -4.0179 0.95970E-04 -4.0179 0.10000E+01 0.0000 84 OH- 0.81837E-02 -2.0870 0.67408E-02 -2.1713 0.82368E+00 -0.0842 89 HPO3-2 0.12864E-14 -14.8906 0.63679E-15 -15.1960 0.49500E+00 -0.3054 91 H2PO3- 0.13258E-18 -18.8775 0.10943E-18 -18.9609 0.82538E+00 -0.0833 92 H3PO4,aq 0.90614E-18 -18.0428 0.90614E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.33754E-10 -10.4717 0.27890E-10 -10.5546 0.82627E+00 -0.0829 94 PO4-3 0.76285E-09 -9.1176 0.16797E-09 -9.7748 0.22018E+00 -0.6572 98 HP2O7-3 0.68189E-18 -18.1663 0.14214E-18 -18.8473 0.20845E+00 -0.6810 99 P2O7-4 0.61566E-17 -17.2107 0.39625E-18 -18.4020 0.64362E-01 -1.1914 100 H2S,aq 0.86599E-06 -6.0625 0.86475E-06 -6.0631 0.99857E+00 -0.0006 101 S2-2 0.41208E-10 -10.3850 0.20398E-10 -10.6904 0.49500E+00 -0.3054 102 S3-2 0.41458E-17 -17.3824 0.20522E-17 -17.6878 0.49500E+00 -0.3054 107 SO3-2 0.13351E-15 -15.8745 0.67179E-16 -16.1728 0.50317E+00 -0.2983 108 HSO3- 0.43672E-18 -18.3598 0.36046E-18 -18.4431 0.82538E+00 -0.0833 109 HSO4- 0.44513E-17 -17.3515 0.36861E-17 -17.4334 0.82810E+00 -0.0819 111 S2O3-2 0.91612E-18 -18.0380 0.45348E-18 -18.3434 0.49500E+00 -0.3054 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1031149E-09 -.2015937E-01 -.2027734E+02 0.0000 2 H2O 0.1000000E+01 0.5551615E+02 0.9980683E+06 0.0000 3 Cl- 0.1218652E-02 0.1225037E-02 0.4334127E+02 7.0696 4 SO4-- 0.8995011E-10 -.1113531E-01 -.1067460E+04 9.7837 5 HCO3- 0.1892612E-03 0.1164408E-01 0.7090176E+03 6.2615 6 HS- 0.3955116E-02 0.1509130E-01 0.4980654E+03 7.5809 7 Al+++ 0.1658008E-28 0.4658501E-05 0.1254330E+00 0.7392 8 H4SiO4 0.6958232E-03 0.1223155E-01 0.1173205E+04 -3.1575 9 Ca++ 0.1886951E-06 0.4877079E-06 0.1950587E-01 13.1018 10 Mg++ 0.2953857E-10 0.1210637E-09 0.2937203E-05 9.2942 11 Fe++ 0.8141491E-13 0.3181516E-07 0.1773101E-02 6.7350 12 K+ 0.1827885E-03 0.1835444E-03 0.7162086E+01 6.2465 13 Na+ 0.2320116E-01 0.2565168E-01 0.5885053E+03 8.3491 14 Mn++ 0.2631851E-10 0.2600941E-08 0.1425945E-03 9.2450 15 F- 0.1008836E-05 0.1012561E-05 0.1919678E-01 3.9865 16 HPO4-- 0.3554884E-07 0.3634544E-07 0.3481173E-02 12.3806 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278393E+02 -.1003520E-01 -.8277390E+02 0.0000000E+00 2 H2O -.7103301E+01 0.2763557E+02 -.3473887E+02 0.0000000E+00 3 Cl- 0.6098152E-03 0.6098152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1389745E+00 -.5543084E-02 0.1445176E+00 0.0000000E+00 5 HCO3- 0.5796347E-02 0.5796347E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1370052E+00 0.7512346E-02 -.1445176E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2318971E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6088782E-02 0.5205782E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2427777E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6026468E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1583737E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9136717E-04 0.1061480E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1276923E-01 0.6263608E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1294731E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3209600E-04 0.5040461E-06 0.3159195E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1809252E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.2116E-13 Mass of aqueous solution: 0.498827E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0799900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.252 0.796 1639. 3.215 30.01 629.3 andradite 0.5781 -0.238 293.8 2.468 5.378 76.32 grossular 0.1400 -0.854 63.06 1.800 1.155 17.55 apatite-OH 0.9831E-02 -2.007 4.938 0.694 0.9041E-01 1.569 apatite-F 0.3159E-04 -4.500 0.1593E-01 -1.798 0.2917E-03 0.4977E-02 clinochlore 0.7047 -0.152 391.7 2.593 7.171 149.0 daphnite 0.2040 -0.690 145.6 2.163 2.665 44.12 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1086 -0.964 23.52 1.371 0.4306 7.188 hedenbergite 0.2817E-01 -1.550 6.989 0.844 0.1279 1.914 microcline 0.9370 -0.028 260.8 2.416 4.775 101.9 stilbite 3.225 0.509 2273. 3.357 41.61 1060. stilpnomelane-Fe 0.2489 -0.604 268.3 2.429 4.912 92.69 tr.625ac.25prg.125 0.9274E-01 -1.033 79.27 1.899 1.451 25.51 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1872E-01 0.1872E-01 1.0000 -1.728 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.359398 g Volume = 2210.999222 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0799900 moles log = -1.0970 Original solution: 1000.0103000 g Original solution / Rock added: 12501.69 (Water/Rock Ratio), log = 4.0970 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 17.5967 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.5984E-01 0.9552 0.1006E+01 0.1053E+01 CO2,gas 0.1800E-06 0.9680 0.3066E-05 0.3167E-05 CH4,gas 0.9393E+00 0.9900 0.1636E+02 0.1653E+02 H2,gas 0.8559E-03 1.0094 0.1520E-01 0.1506E-01 H2S,gas 0.1445E-05 0.9346 0.2377E-04 0.2543E-04 S2,gas 0.5215E-26 1.0000 0.9177E-25 0.9177E-25 CO,gas 0.7061E-12 1.0000 0.1243E-10 0.1243E-10 SO3,gas 0.7044E-47 1.0000 0.1240E-45 0.1240E-45 SO2,gas 0.4168E-26 1.0000 0.7333E-25 0.7333E-25 HF,gas 0.6800E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1584E-17 1.0000 0.2787E-16 0.2787E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.48529E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.60662E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.60662E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.002 2 CO2,gas -6.66 -13.87 -7.21 -2.404 0.12315E+05 -5.513 3 CH4,gas 4.54 4.06 -0.49 -0.121 0.82832E+03 1.214 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.55 -6.32 -3.161 0.10796E+05 -4.624 6 S2,gas -7.34 -34.07 -26.74 -4.113 0.45651E+05 -25.037 7 CO,gas 3.21 -9.39 -12.60 -3.878 0.21522E+05 -10.906 8 SO3,gas 17.12 -30.48 -47.61 -11.901 0.81285E+05 -45.907 9 SO2,gas 0.83 -26.00 -26.83 -7.156 0.45818E+05 -25.135 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.06 -18.25 -9.127 0.31168E+05 -16.555 12 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80532E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93653E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28495E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 38 aragonite 0.97 -0.77 -1.74 -0.579 0.29664E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55912E+04 40 calcite 0.81 -0.77 -1.58 -0.528 0.27021E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52804E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71074E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39697E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68946E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 55 chloritoid-Mn 11.40 7.57 -3.84 -0.256 0.65489E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.91 -1.80 -0.516 0.30811E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37137E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.91 -1.36 -0.389 0.23234E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28623E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82184E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36683E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91150E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -22.85 -1.61 -0.378 0.27440E+04 146 pyrrhotite -4.26 -5.82 -1.56 -0.519 0.26599E+04 147 pyrrhotiteFe0.875 -6.02 -7.22 -1.20 -0.441 0.20471E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22386E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28667E+03 154 rhodochrosite -0.98 -4.63 -3.65 -1.217 0.62344E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23189E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.14 -4.53 -1.510 0.77338E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27810E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47011E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90665E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77507E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65443E+04 184 troilite-low -4.41 -5.82 -1.41 -0.469 0.24027E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60597E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66175E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58212E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66550E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.31 -2.33 -0.777 0.39789E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 MOLES Current total amount of reactant added: 0.0799900 MOLES New total amount of reactant added: 0.0819900 MOLES Mixing fraction reached given limit of 0.8000E-01 TOTMIX = 0.8199E-01 Execution stopped.