File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.82784E+02 0.10311E-09 0.8311 0.00000000E+00 H2O 2 0. -0.71033E+01 0.10000E+01 0.9998 0.00000000E+00 Cl- 3 -1. 0.60982E-03 0.12187E-02 0.8254 0.00000000E+00 SO4-- 4 -2. 0.13897E+00 0.89950E-10 0.4962 0.00000000E+00 HCO3- 5 -1. 0.57963E-02 0.18926E-03 0.8268 0.00000000E+00 HS- 6 -1. -0.13701E+00 0.39551E-02 0.8255 0.00000000E+00 Al+++ 7 3. 0.16304E+02 0.16580E-28 0.2082 0.00000000E+00 H4SiO4 8 0. 0.52064E+02 0.69582E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.57507E+01 0.18870E-06 0.4920 0.00000000E+00 Mg++ 10 2. 0.39683E+01 0.29539E-10 0.4895 0.00000000E+00 Fe++ 11 2. 0.35650E+01 0.81415E-13 0.4901 0.00000000E+00 K+ 12 1. 0.10616E+01 0.18279E-03 0.8270 0.00000000E+00 Na+ 13 1. 0.62764E+01 0.23201E-01 0.8252 0.00000000E+00 Mn++ 14 2. 0.86693E-01 0.26319E-10 0.4905 0.00000000E+00 F- 15 -1. 0.32096E-04 0.10088E-05 0.8234 0.00000000E+00 HPO4-- 16 -2. 0.29588E-01 0.35549E-07 0.4963 0.00000000E+00 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.6098E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E+00 TEMP = 100.0000 SINC = 0.4000E-02 TEMPC = 0.0000 TOTMIX = 0.799900E-01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 2000.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.6252E+01 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.5781E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.1400E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.9831E-02 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.3159E-04 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.3225E+01 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.2489E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.7047E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.2040E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.1734E-01 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.1086E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.2817E-01 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.9370E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.9274E-01 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.0799900 moles log = -1.0970 Original solution: 1000.0103000 g Original solution / Rock added: 12501.69 (Water/Rock Ratio), log = 4.0970 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0799900 Water: Moles liquid = 0.2763E+02 kg liquid = 0.4978E+00 Moles total = -.7103E+01 kg total = -.1280E+00 Activity = 0.9998 Stoichiometric ionic strength = .4649119E-02 Osmotic coef. = 0.9435 True ionic strength = .2370686E-01 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.6098E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10311E-09 -9.9867 0.85696E-10 -10.0670 0.83107E+00 -0.0804 2 H2O 0.99980E+00 -0.0001 0.99980E+00 -0.0001 3 Cl- 0.12187E-02 -2.9141 0.10058E-02 -2.9975 0.82538E+00 -0.0833 4 SO4-- 0.89950E-10 -10.0460 0.44633E-10 -10.3503 0.49620E+00 -0.3043 5 HCO3- 0.18926E-03 -3.7229 0.15647E-03 -3.8056 0.82676E+00 -0.0826 6 HS- 0.39551E-02 -2.4028 0.32650E-02 -2.4861 0.82552E+00 -0.0833 7 Al+++ 0.16580E-28 -28.7804 0.34519E-29 -29.4619 0.20820E+00 -0.6815 8 H4SiO4 0.69582E-03 -3.1575 0.69582E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.18870E-06 -6.7242 0.92845E-07 -7.0322 0.49204E+00 -0.3080 10 Mg++ 0.29539E-10 -10.5296 0.14458E-10 -10.8399 0.48947E+00 -0.3103 11 Fe++ 0.81415E-13 -13.0893 0.39900E-13 -13.3990 0.49008E+00 -0.3097 12 K+ 0.18279E-03 -3.7381 0.15116E-03 -3.8206 0.82697E+00 -0.0825 13 Na+ 0.23201E-01 -1.6345 0.19146E-01 -1.7179 0.82520E+00 -0.0834 14 Mn++ 0.26319E-10 -10.5797 0.12910E-10 -10.8891 0.49054E+00 -0.3093 15 F- 0.10088E-05 -5.9962 0.83072E-06 -6.0805 0.82344E+00 -0.0844 16 HPO4-- 0.35549E-07 -7.4492 0.17642E-07 -7.7534 0.49628E+00 -0.3043 18 HSiO3- 0.91875E-02 -2.0368 0.75832E-02 -2.1201 0.82538E+00 -0.0833 19 Ca(HSiO3)+ 0.19384E-07 -7.7126 0.16034E-07 -7.7950 0.82718E+00 -0.0824 20 Mg(HSiO3)+ 0.37567E-11 -11.4252 0.31074E-11 -11.5076 0.82718E+00 -0.0824 21 NaHSiO3,aq 0.23482E-02 -2.6293 0.23482E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.77291E-16 -16.1119 0.63933E-16 -16.1943 0.82718E+00 -0.0824 24 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.46584E-05 -5.3318 0.38370E-05 -5.4160 0.82368E+00 -0.0842 26 CH4,aq 0.11132E-01 -1.9534 0.11116E-01 -1.9540 0.99857E+00 -0.0006 27 C2H6,aq 0.18269E-08 -8.7383 0.18243E-08 -8.7389 0.99857E+00 -0.0006 28 C3H8,aq 0.69221E-14 -14.1598 0.69122E-14 -14.1604 0.99857E+00 -0.0006 29 C4H10,aq 0.25765E-19 -19.5890 0.25728E-19 -19.5896 0.99857E+00 -0.0006 30 ethanol,aq 0.67057E-16 -16.1736 0.66961E-16 -16.1742 0.99857E+00 -0.0006 31 CO,aq 0.83383E-14 -14.0789 0.83383E-14 -14.0789 0.10000E+01 0.0000 32 CO2,aq 0.28699E-07 -7.5421 0.28658E-07 -7.5428 0.99857E+00 -0.0006 33 CO3-2 0.32219E-03 -3.4919 0.15949E-03 -3.7973 0.49500E+00 -0.3054 34 CaCO3,aq 0.18567E-06 -6.7313 0.18567E-06 -6.7313 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.44831E-09 -9.3484 0.37083E-09 -9.4308 0.82718E+00 -0.0824 36 CaCl+ 0.18271E-09 -9.7382 0.15113E-09 -9.8206 0.82718E+00 -0.0824 37 CaCl2,aq 0.36115E-13 -13.4423 0.36115E-13 -13.4423 0.10000E+01 0.0000 38 CaF+ 0.13613E-11 -11.8660 0.11261E-11 -11.9484 0.82718E+00 -0.0824 39 CaOH+ 0.93328E-07 -7.0300 0.77199E-07 -7.1124 0.82718E+00 -0.0824 40 CaSO4,aq 0.13159E-14 -14.8808 0.13159E-14 -14.8808 0.10000E+01 0.0000 41 HCl,aq 0.15795E-13 -13.8015 0.15795E-13 -13.8015 0.10000E+01 0.0000 45 HF,aq 0.48734E-12 -12.3122 0.48734E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16560E-18 -18.7809 0.13669E-18 -18.8643 0.82538E+00 -0.0833 48 FeCl+ 0.76796E-16 -16.1147 0.63524E-16 -16.1971 0.82718E+00 -0.0824 51 FeF+ 0.20477E-17 -17.6887 0.16938E-17 -17.7711 0.82718E+00 -0.0824 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.18318E-10 -10.7371 0.15153E-10 -10.8195 0.82718E+00 -0.0824 55 HFeO2- 0.31224E-07 -7.5055 0.25772E-07 -7.5889 0.82538E+00 -0.0833 56 FeO+ 0.12840E-16 -16.8914 0.10621E-16 -16.9738 0.82718E+00 -0.0824 58 FeO2- 0.35846E-09 -9.4456 0.29587E-09 -9.5289 0.82538E+00 -0.0833 59 HFeO2,aq 0.32247E-11 -11.4915 0.32247E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11597E-04 -4.9357 0.11580E-04 -4.9363 0.99857E+00 -0.0006 61 KCl,aq 0.27557E-08 -8.5598 0.27557E-08 -8.5598 0.10000E+01 0.0000 63 KOH,aq 0.75315E-06 -6.1231 0.75315E-06 -6.1231 0.10000E+01 0.0000 64 KSO4- 0.12684E-12 -12.8967 0.10469E-12 -12.9801 0.82538E+00 -0.0833 65 MgCO3,aq 0.72473E-11 -11.1398 0.72473E-11 -11.1398 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.71336E-13 -13.1467 0.59008E-13 -13.2291 0.82718E+00 -0.0824 67 MgCl+ 0.25787E-13 -13.5886 0.21331E-13 -13.6710 0.82718E+00 -0.0824 68 MgF+ 0.78529E-15 -15.1050 0.64958E-15 -15.1874 0.82718E+00 -0.0824 69 MgOH+ 0.80421E-10 -10.0946 0.66523E-10 -10.1770 0.82718E+00 -0.0824 71 MnF+ 0.21839E-15 -15.6608 0.18065E-15 -15.7432 0.82718E+00 -0.0824 72 MnO,aq 0.18202E-08 -8.7399 0.18202E-08 -8.7399 0.10000E+01 0.0000 73 MnOH+ 0.55063E-09 -9.2591 0.45547E-09 -9.3415 0.82718E+00 -0.0824 74 MnO2-2 0.16614E-10 -10.7795 0.82240E-11 -11.0849 0.49500E+00 -0.3054 75 HMnO2- 0.18707E-09 -9.7280 0.15440E-09 -9.8113 0.82538E+00 -0.0833 78 MnCl+ 0.96673E-13 -13.0147 0.79966E-13 -13.0971 0.82718E+00 -0.0824 79 MnSO4,aq 0.16635E-18 -18.7790 0.16635E-18 -18.7790 0.10000E+01 0.0000 80 NaCl,aq 0.63820E-05 -5.1950 0.63820E-05 -5.1950 0.10000E+01 0.0000 81 NaF,aq 0.37236E-08 -8.4290 0.37236E-08 -8.4290 0.10000E+01 0.0000 82 NaOH,aq 0.95970E-04 -4.0179 0.95970E-04 -4.0179 0.10000E+01 0.0000 84 OH- 0.81837E-02 -2.0870 0.67408E-02 -2.1713 0.82368E+00 -0.0842 89 HPO3-2 0.12864E-14 -14.8906 0.63679E-15 -15.1960 0.49500E+00 -0.3054 91 H2PO3- 0.13258E-18 -18.8775 0.10943E-18 -18.9609 0.82538E+00 -0.0833 92 H3PO4,aq 0.90614E-18 -18.0428 0.90614E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.33754E-10 -10.4717 0.27890E-10 -10.5546 0.82627E+00 -0.0829 94 PO4-3 0.76285E-09 -9.1176 0.16797E-09 -9.7748 0.22018E+00 -0.6572 98 HP2O7-3 0.68189E-18 -18.1663 0.14214E-18 -18.8473 0.20845E+00 -0.6810 99 P2O7-4 0.61566E-17 -17.2107 0.39625E-18 -18.4020 0.64362E-01 -1.1914 100 H2S,aq 0.86599E-06 -6.0625 0.86475E-06 -6.0631 0.99857E+00 -0.0006 101 S2-2 0.41208E-10 -10.3850 0.20398E-10 -10.6904 0.49500E+00 -0.3054 102 S3-2 0.41458E-17 -17.3824 0.20522E-17 -17.6878 0.49500E+00 -0.3054 107 SO3-2 0.13351E-15 -15.8745 0.67179E-16 -16.1728 0.50317E+00 -0.2983 108 HSO3- 0.43672E-18 -18.3598 0.36046E-18 -18.4431 0.82538E+00 -0.0833 109 HSO4- 0.44513E-17 -17.3515 0.36861E-17 -17.4334 0.82810E+00 -0.0819 111 S2O3-2 0.91612E-18 -18.0380 0.45348E-18 -18.3434 0.49500E+00 -0.3054 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1031149E-09 -.2015937E-01 -.2027734E+02 0.0000 2 H2O 0.1000000E+01 0.5551615E+02 0.9980683E+06 0.0000 3 Cl- 0.1218652E-02 0.1225037E-02 0.4334127E+02 7.0696 4 SO4-- 0.8995011E-10 -.1113531E-01 -.1067460E+04 9.7837 5 HCO3- 0.1892612E-03 0.1164408E-01 0.7090176E+03 6.2615 6 HS- 0.3955116E-02 0.1509130E-01 0.4980654E+03 7.5809 7 Al+++ 0.1658008E-28 0.4658501E-05 0.1254330E+00 0.7392 8 H4SiO4 0.6958232E-03 0.1223155E-01 0.1173205E+04 -3.1575 9 Ca++ 0.1886951E-06 0.4877079E-06 0.1950587E-01 13.1018 10 Mg++ 0.2953857E-10 0.1210628E-09 0.2937181E-05 9.2942 11 Fe++ 0.8141491E-13 0.3181516E-07 0.1773101E-02 6.7350 12 K+ 0.1827885E-03 0.1835444E-03 0.7162086E+01 6.2465 13 Na+ 0.2320116E-01 0.2565168E-01 0.5885053E+03 8.3491 14 Mn++ 0.2631851E-10 0.2600941E-08 0.1425945E-03 9.2450 15 F- 0.1008836E-05 0.1012561E-05 0.1919678E-01 3.9865 16 HPO4-- 0.3554884E-07 0.3634544E-07 0.3481173E-02 12.3806 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278393E+02 -.1003520E-01 -.8277390E+02 0.0000000E+00 2 H2O -.7103301E+01 0.2763557E+02 -.3473887E+02 0.0000000E+00 3 Cl- 0.6098152E-03 0.6098152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1389745E+00 -.5543084E-02 0.1445176E+00 0.0000000E+00 5 HCO3- 0.5796347E-02 0.5796347E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1370052E+00 0.7512346E-02 -.1445176E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2318971E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6088782E-02 0.5205782E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2427777E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6026424E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1583737E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9136717E-04 0.1061480E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1276923E-01 0.6263608E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1294731E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3209600E-04 0.5040461E-06 0.3159195E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1809252E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1936E-14 Mass of aqueous solution: 0.498827E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0799900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.252 0.796 1639. 3.215 30.01 629.3 andradite 0.5781 -0.238 293.8 2.468 5.378 76.32 grossular 0.1400 -0.854 63.06 1.800 1.155 17.55 apatite-OH 0.9831E-02 -2.007 4.938 0.694 0.9041E-01 1.569 apatite-F 0.3159E-04 -4.500 0.1593E-01 -1.798 0.2917E-03 0.4977E-02 clinochlore 0.7047 -0.152 391.7 2.593 7.171 149.0 daphnite 0.2040 -0.690 145.6 2.163 2.665 44.12 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1086 -0.964 23.52 1.371 0.4306 7.188 hedenbergite 0.2817E-01 -1.550 6.989 0.844 0.1279 1.914 microcline 0.9370 -0.028 260.8 2.416 4.775 101.9 stilbite 3.225 0.509 2273. 3.357 41.61 1060. stilpnomelane-Fe 0.2489 -0.604 268.3 2.429 4.912 92.69 tr.625ac.25prg.125 0.9274E-01 -1.033 79.27 1.899 1.451 25.51 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7610E+00 0.7610E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1872E-01 0.1872E-01 1.0000 -1.728 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.359398 g Volume = 2210.999222 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0799900 moles log = -1.0970 Original solution: 1000.0103000 g Original solution / Rock added: 12501.69 (Water/Rock Ratio), log = 4.0970 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 17.5967 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.5984E-01 0.9552 0.1006E+01 0.1053E+01 CO2,gas 0.1800E-06 0.9680 0.3066E-05 0.3167E-05 CH4,gas 0.9393E+00 0.9900 0.1636E+02 0.1653E+02 H2,gas 0.8559E-03 1.0094 0.1520E-01 0.1506E-01 H2S,gas 0.1445E-05 0.9346 0.2377E-04 0.2543E-04 S2,gas 0.5215E-26 1.0000 0.9177E-25 0.9177E-25 CO,gas 0.7061E-12 1.0000 0.1243E-10 0.1243E-10 SO3,gas 0.7044E-47 1.0000 0.1240E-45 0.1240E-45 SO2,gas 0.4168E-26 1.0000 0.7333E-25 0.7333E-25 HF,gas 0.6800E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1584E-17 1.0000 0.2787E-16 0.2787E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.002 2 CO2,gas -6.66 -13.87 -7.21 -2.404 0.12315E+05 -5.513 3 CH4,gas 4.54 4.06 -0.49 -0.121 0.82832E+03 1.214 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.55 -6.32 -3.161 0.10796E+05 -4.624 6 S2,gas -7.34 -34.07 -26.74 -4.113 0.45651E+05 -25.037 7 CO,gas 3.21 -9.39 -12.60 -3.878 0.21522E+05 -10.906 8 SO3,gas 17.12 -30.48 -47.61 -11.901 0.81285E+05 -45.907 9 SO2,gas 0.83 -26.00 -26.83 -7.156 0.45818E+05 -25.135 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.06 -18.25 -9.127 0.31168E+05 -16.555 12 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80532E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93653E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28495E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 38 aragonite 0.97 -0.77 -1.74 -0.579 0.29664E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55912E+04 40 calcite 0.81 -0.77 -1.58 -0.528 0.27021E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52804E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71074E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39697E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68946E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 55 chloritoid-Mn 11.40 7.57 -3.84 -0.256 0.65489E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.91 -1.80 -0.516 0.30811E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68200E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37137E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.91 -1.36 -0.389 0.23234E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64128E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28623E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48025E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82184E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36683E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91150E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -22.85 -1.61 -0.378 0.27440E+04 146 pyrrhotite -4.26 -5.82 -1.56 -0.519 0.26599E+04 147 pyrrhotiteFe0.875 -6.02 -7.22 -1.20 -0.441 0.20471E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22386E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28667E+03 154 rhodochrosite -0.98 -4.63 -3.65 -1.217 0.62344E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23189E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.14 -4.53 -1.510 0.77338E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27810E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47011E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90665E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77507E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65443E+04 184 troilite-low -4.41 -5.82 -1.41 -0.469 0.24027E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60597E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66175E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68813E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73673E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60362E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58212E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66550E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.31 -2.33 -0.777 0.39789E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.0799900 MOLES New total amount of reactant added: 0.0839900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8660E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0839900 Water: Moles liquid = 0.2764E+02 kg liquid = 0.4979E+00 Moles total = -.7100E+01 kg total = -.1279E+00 Activity = 0.9998 Stoichiometric ionic strength = .4306333E-02 Osmotic coef. = 0.9453 True ionic strength = .2388797E-01 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.6334E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10386E-09 -9.9836 0.86269E-10 -10.0641 0.83065E+00 -0.0806 2 H2O 0.99979E+00 -0.0001 0.99979E+00 -0.0001 3 Cl- 0.12656E-02 -2.8977 0.10440E-02 -2.9813 0.82493E+00 -0.0836 4 SO4-- 0.93895E-10 -10.0274 0.46493E-10 -10.3326 0.49516E+00 -0.3053 5 HCO3- 0.19756E-03 -3.7043 0.16325E-03 -3.7871 0.82631E+00 -0.0829 6 HS- 0.41497E-02 -2.3820 0.34238E-02 -2.4655 0.82506E+00 -0.0835 7 Al+++ 0.16997E-28 -28.7696 0.35217E-29 -29.4532 0.20720E+00 -0.6836 8 H4SiO4 0.69582E-03 -3.1575 0.69582E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.19164E-06 -6.7175 0.94091E-07 -7.0265 0.49098E+00 -0.3089 10 Mg++ 0.30001E-10 -10.5229 0.14652E-10 -10.8341 0.48840E+00 -0.3112 11 Fe++ 0.82689E-13 -13.0826 0.40436E-13 -13.3932 0.48901E+00 -0.3107 12 K+ 0.18410E-03 -3.7349 0.15217E-03 -3.8177 0.82653E+00 -0.0827 13 Na+ 0.23369E-01 -1.6314 0.19273E-01 -1.7150 0.82475E+00 -0.0837 14 Mn++ 0.26741E-10 -10.5728 0.13089E-10 -10.8831 0.48948E+00 -0.3103 15 F- 0.10027E-05 -5.9988 0.82519E-06 -6.0834 0.82298E+00 -0.0846 16 HPO4-- 0.35152E-07 -7.4541 0.17408E-07 -7.7592 0.49524E+00 -0.3052 18 HSiO3- 0.91315E-02 -2.0395 0.75328E-02 -2.1230 0.82493E+00 -0.0836 19 Ca(HSiO3)+ 0.19524E-07 -7.7094 0.16141E-07 -7.7921 0.82674E+00 -0.0826 20 Mg(HSiO3)+ 0.37838E-11 -11.4221 0.31282E-11 -11.5047 0.82674E+00 -0.0826 21 NaHSiO3,aq 0.23481E-02 -2.6293 0.23481E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.77851E-16 -16.1087 0.64362E-16 -16.1914 0.82674E+00 -0.0826 24 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.46300E-05 -5.3344 0.38115E-05 -5.4189 0.82322E+00 -0.0845 26 CH4,aq 0.11691E-01 -1.9322 0.11675E-01 -1.9327 0.99867E+00 -0.0006 27 C2H6,aq 0.20151E-08 -8.6957 0.20124E-08 -8.6963 0.99867E+00 -0.0006 28 C3H8,aq 0.80188E-14 -14.0959 0.80081E-14 -14.0965 0.99867E+00 -0.0006 29 C4H10,aq 0.31347E-19 -19.5038 0.31306E-19 -19.5044 0.99867E+00 -0.0006 30 ethanol,aq 0.73961E-16 -16.1310 0.73863E-16 -16.1316 0.99867E+00 -0.0006 31 CO,aq 0.87577E-14 -14.0576 0.87577E-14 -14.0576 0.10000E+01 0.0000 32 CO2,aq 0.30139E-07 -7.5209 0.30099E-07 -7.5214 0.99867E+00 -0.0006 33 CO3-2 0.33462E-03 -3.4754 0.16529E-03 -3.7818 0.49395E+00 -0.3063 34 CaCO3,aq 0.19500E-06 -6.7100 0.19500E-06 -6.7100 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.47426E-09 -9.3240 0.39209E-09 -9.4066 0.82674E+00 -0.0826 36 CaCl+ 0.19229E-09 -9.7160 0.15897E-09 -9.7987 0.82674E+00 -0.0826 37 CaCl2,aq 0.39431E-13 -13.4042 0.39431E-13 -13.4042 0.10000E+01 0.0000 38 CaF+ 0.13712E-11 -11.8629 0.11336E-11 -11.9455 0.82674E+00 -0.0826 39 CaOH+ 0.94002E-07 -7.0269 0.77715E-07 -7.1095 0.82674E+00 -0.0826 40 CaSO4,aq 0.13891E-14 -14.8573 0.13891E-14 -14.8573 0.10000E+01 0.0000 41 HCl,aq 0.16504E-13 -13.7824 0.16504E-13 -13.7824 0.10000E+01 0.0000 45 HF,aq 0.48734E-12 -12.3122 0.48734E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16459E-18 -18.7836 0.13577E-18 -18.8672 0.82493E+00 -0.0836 48 FeCl+ 0.80824E-16 -16.0925 0.66820E-16 -16.1751 0.82674E+00 -0.0826 51 FeF+ 0.20625E-17 -17.6856 0.17051E-17 -17.7682 0.82674E+00 -0.0826 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.18451E-10 -10.7340 0.15254E-10 -10.8166 0.82674E+00 -0.0826 55 HFeO2- 0.31033E-07 -7.5082 0.25600E-07 -7.5918 0.82493E+00 -0.0836 56 FeO+ 0.12933E-16 -16.8883 0.10692E-16 -16.9709 0.82674E+00 -0.0826 58 FeO2- 0.35627E-09 -9.4482 0.29390E-09 -9.5318 0.82493E+00 -0.0836 59 HFeO2,aq 0.32247E-11 -11.4915 0.32247E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11595E-04 -4.9357 0.11580E-04 -4.9363 0.99867E+00 -0.0006 61 KCl,aq 0.28793E-08 -8.5407 0.28793E-08 -8.5407 0.10000E+01 0.0000 63 KOH,aq 0.75312E-06 -6.1231 0.75312E-06 -6.1231 0.10000E+01 0.0000 64 KSO4- 0.13308E-12 -12.8759 0.10978E-12 -12.9595 0.82493E+00 -0.0836 65 MgCO3,aq 0.76117E-11 -11.1185 0.76117E-11 -11.1185 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.75465E-13 -13.1223 0.62389E-13 -13.2049 0.82674E+00 -0.0826 67 MgCl+ 0.27139E-13 -13.5664 0.22437E-13 -13.6490 0.82674E+00 -0.0826 68 MgF+ 0.79096E-15 -15.1018 0.65392E-15 -15.1845 0.82674E+00 -0.0826 69 MgOH+ 0.81002E-10 -10.0915 0.66967E-10 -10.1741 0.82674E+00 -0.0826 71 MnF+ 0.22005E-15 -15.6575 0.18193E-15 -15.7401 0.82674E+00 -0.0826 72 MnO,aq 0.18209E-08 -8.7397 0.18209E-08 -8.7397 0.10000E+01 0.0000 73 MnOH+ 0.55482E-09 -9.2558 0.45869E-09 -9.3385 0.82674E+00 -0.0826 74 MnO2-2 0.16435E-10 -10.7842 0.81182E-11 -11.0905 0.49395E+00 -0.3063 75 HMnO2- 0.18600E-09 -9.7305 0.15344E-09 -9.8141 0.82493E+00 -0.0836 78 MnCl+ 0.10178E-12 -12.9923 0.84149E-13 -13.0750 0.82674E+00 -0.0826 79 MnSO4,aq 0.17568E-18 -18.7553 0.17568E-18 -18.7553 0.10000E+01 0.0000 80 NaCl,aq 0.66683E-05 -5.1760 0.66683E-05 -5.1760 0.10000E+01 0.0000 81 NaF,aq 0.37234E-08 -8.4291 0.37234E-08 -8.4291 0.10000E+01 0.0000 82 NaOH,aq 0.95966E-04 -4.0179 0.95966E-04 -4.0179 0.10000E+01 0.0000 84 OH- 0.81338E-02 -2.0897 0.66959E-02 -2.1742 0.82322E+00 -0.0845 89 HPO3-2 0.12721E-14 -14.8955 0.62836E-15 -15.2018 0.49395E+00 -0.3063 91 H2PO3- 0.13177E-18 -18.8802 0.10870E-18 -18.9638 0.82493E+00 -0.0836 92 H3PO4,aq 0.90614E-18 -18.0428 0.90614E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.33548E-10 -10.4743 0.27705E-10 -10.5574 0.82582E+00 -0.0831 94 PO4-3 0.75110E-09 -9.1243 0.16464E-09 -9.7835 0.21920E+00 -0.6592 98 HP2O7-3 0.67162E-18 -18.1729 0.13933E-18 -18.8560 0.20745E+00 -0.6831 99 P2O7-4 0.60449E-17 -17.2186 0.38582E-18 -18.4136 0.63826E-01 -1.1950 100 H2S,aq 0.91408E-06 -6.0390 0.91287E-06 -6.0396 0.99867E+00 -0.0006 101 S2-2 0.45410E-10 -10.3428 0.22430E-10 -10.6492 0.49395E+00 -0.3063 102 S3-2 0.48229E-17 -17.3167 0.23823E-17 -17.6230 0.49395E+00 -0.3063 107 SO3-2 0.13936E-15 -15.8559 0.69978E-16 -16.1550 0.50215E+00 -0.2992 108 HSO3- 0.45821E-18 -18.3389 0.37799E-18 -18.4225 0.82493E+00 -0.0836 109 HSO4- 0.46702E-17 -17.3307 0.38654E-17 -17.4128 0.82766E+00 -0.0821 111 S2O3-2 0.10095E-17 -17.9959 0.49866E-18 -18.3022 0.49395E+00 -0.3063 Charge balance for all species = -.1740E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1038575E-09 -.2006558E-01 -.2018266E+02 0.0000 2 H2O 0.1000000E+01 0.5551671E+02 0.9980614E+06 0.0000 3 Cl- 0.1265589E-02 0.1272260E-02 0.4501123E+02 7.0829 4 SO4-- 0.9389531E-10 -.1169375E-01 -.1120974E+04 9.7957 5 HCO3- 0.1975637E-03 0.1222326E-01 0.7442714E+03 6.2770 6 HS- 0.4149722E-02 0.1584438E-01 0.5229111E+03 7.5986 7 Al+++ 0.1699718E-28 0.4630150E-05 0.1246675E+00 0.7392 8 H4SiO4 0.6958154E-03 0.1217540E-01 0.1167799E+04 -3.1575 9 Ca++ 0.1916415E-06 0.5008405E-06 0.2003076E-01 13.1018 10 Mg++ 0.3000070E-10 0.1225008E-09 0.2972019E-05 9.2942 11 Fe++ 0.8268874E-13 0.3162223E-07 0.1762318E-02 6.7351 12 K+ 0.1841046E-03 0.1848606E-03 0.7213324E+01 6.2465 13 Na+ 0.2336852E-01 0.2581924E-01 0.5923395E+03 8.3491 14 Mn++ 0.2674065E-10 0.2605029E-08 0.1428162E-03 9.2452 15 F- 0.1002683E-05 0.1006409E-05 0.1907982E-01 3.9807 16 HPO4-- 0.3515190E-07 0.3593655E-07 0.3441951E-02 12.3690 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278350E+02 -.9989971E-02 -.8277351E+02 0.0000000E+00 2 H2O -.7100026E+01 0.2763989E+02 -.3473992E+02 0.0000000E+00 3 Cl- 0.6334152E-03 0.6334152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1389936E+00 -.5821921E-02 0.1448155E+00 0.0000000E+00 5 HCO3- 0.6085547E-02 0.6085547E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1369271E+00 0.7888382E-02 -.1448155E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2305195E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6061717E-02 0.5205784E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2493515E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6098899E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1574364E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9203585E-04 0.1061479E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1285453E-01 0.6263522E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1296956E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3369600E-04 0.5010568E-06 0.3319494E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1789159E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.9118E-14 Mass of aqueous solution: 0.498908E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0839900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.252 0.796 1639. 3.215 30.01 629.3 andradite 0.5793 -0.237 294.4 2.469 5.389 76.48 grossular 0.1403 -0.853 63.19 1.801 1.157 17.58 apatite-OH 0.9829E-02 -2.007 4.938 0.694 0.9039E-01 1.569 apatite-F 0.3319E-04 -4.479 0.1674E-01 -1.776 0.3065E-03 0.5230E-02 clinochlore 0.7044 -0.152 391.5 2.593 7.168 148.9 daphnite 0.2040 -0.690 145.5 2.163 2.664 44.10 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1008 -0.996 21.84 1.339 0.3998 6.674 hedenbergite 0.2616E-01 -1.582 6.489 0.812 0.1188 1.777 microcline 0.9373 -0.028 260.9 2.416 4.776 101.9 stilbite 3.225 0.509 2273. 3.357 41.61 1060. stilpnomelane-Fe 0.2483 -0.605 267.7 2.428 4.900 92.46 tr.625ac.25prg.125 0.9527E-01 -1.021 81.43 1.911 1.491 26.21 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1873E-01 0.1873E-01 1.0000 -1.727 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.360290 g Volume = 2211.010341 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0839900 moles log = -1.0758 Original solution: 1000.0103000 g Original solution / Rock added: 11906.30 (Water/Rock Ratio), log = 4.0758 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 18.4381 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.5717E-01 0.9542 0.1006E+01 0.1054E+01 CO2,gas 0.1807E-06 0.9667 0.3220E-05 0.3331E-05 CH4,gas 0.9420E+00 0.9894 0.1719E+02 0.1737E+02 H2,gas 0.8165E-03 1.0099 0.1520E-01 0.1505E-01 H2S,gas 0.1461E-05 0.9317 0.2509E-04 0.2694E-04 S2,gas 0.5546E-26 1.0000 0.1023E-24 0.1023E-24 CO,gas 0.7078E-12 1.0000 0.1305E-10 0.1305E-10 SO3,gas 0.7097E-47 1.0000 0.1309E-45 0.1309E-45 SO2,gas 0.4199E-26 1.0000 0.7742E-25 0.7742E-25 HF,gas 0.6490E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1579E-17 1.0000 0.2912E-16 0.2912E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.90992E-11 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.002 2 CO2,gas -6.66 -13.85 -7.19 -2.397 0.12279E+05 -5.492 3 CH4,gas 4.54 4.08 -0.46 -0.116 0.79195E+03 1.235 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60052E+04 -1.818 5 H2S,gas -6.23 -12.53 -6.30 -3.150 0.10756E+05 -4.600 6 S2,gas -7.34 -34.02 -26.69 -4.106 0.45571E+05 -24.990 7 CO,gas 3.21 -9.37 -12.58 -3.872 0.21486E+05 -10.884 8 SO3,gas 17.12 -30.46 -47.58 -11.896 0.81245E+05 -45.883 9 SO2,gas 0.83 -25.98 -26.81 -7.149 0.45778E+05 -25.111 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.05 -18.23 -9.117 0.31135E+05 -16.536 12 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80523E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93654E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28496E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 38 aragonite 0.97 -0.75 -1.72 -0.572 0.29300E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55912E+04 40 calcite 0.81 -0.75 -1.56 -0.520 0.26658E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52804E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71074E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82205E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39697E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68946E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 55 chloritoid-Mn 11.40 7.57 -3.84 -0.256 0.65486E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.89 -1.78 -0.509 0.30447E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68199E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37137E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.89 -1.34 -0.383 0.22870E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64129E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28624E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48024E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82181E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41127E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36684E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91150E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 145 pyrite -21.25 -22.81 -1.56 -0.367 0.26637E+04 146 pyrrhotite -4.26 -5.79 -1.53 -0.511 0.26197E+04 147 pyrrhotiteFe0.875 -6.02 -7.19 -1.18 -0.432 0.20069E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22383E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28666E+03 154 rhodochrosite -0.98 -4.61 -3.63 -1.210 0.61978E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23186E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.12 -4.51 -1.503 0.76974E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27810E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.47005E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90664E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77508E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65443E+04 184 troilite-low -4.41 -5.79 -1.38 -0.461 0.23625E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66605E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60596E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66175E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68812E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73672E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60361E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58212E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83482E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66550E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.28 -2.31 -0.769 0.39384E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.0839900 MOLES New total amount of reactant added: 0.0879900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0879900 Water: Moles liquid = 0.2764E+02 kg liquid = 0.4979E+00 Moles total = -.7097E+01 kg total = -.1279E+00 Activity = 0.9998 Stoichiometric ionic strength = .3963315E-02 Osmotic coef. = 0.9473 True ionic strength = .2406919E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.6570E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10460E-09 -9.9805 0.86844E-10 -10.0613 0.83023E+00 -0.0808 2 H2O 0.99978E+00 -0.0001 0.99978E+00 -0.0001 3 Cl- 0.13125E-02 -2.8819 0.10821E-02 -2.9657 0.82448E+00 -0.0838 4 SO4-- 0.97799E-10 -10.0097 0.48324E-10 -10.3158 0.49412E+00 -0.3062 5 HCO3- 0.20577E-03 -3.6866 0.16994E-03 -3.7697 0.82587E+00 -0.0831 6 HS- 0.43443E-02 -2.3621 0.35824E-02 -2.4458 0.82461E+00 -0.0837 7 Al+++ 0.17423E-28 -28.7589 0.35926E-29 -29.4446 0.20620E+00 -0.6857 8 H4SiO4 0.69581E-03 -3.1575 0.69581E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.19462E-06 -6.7108 0.95348E-07 -7.0207 0.48992E+00 -0.3099 10 Mg++ 0.30468E-10 -10.5162 0.14848E-10 -10.8283 0.48734E+00 -0.3122 11 Fe++ 0.83976E-13 -13.0758 0.40976E-13 -13.3875 0.48795E+00 -0.3116 12 K+ 0.18542E-03 -3.7318 0.15318E-03 -3.8148 0.82609E+00 -0.0830 13 Na+ 0.23536E-01 -1.6283 0.19401E-01 -1.7122 0.82430E+00 -0.0839 14 Mn++ 0.27168E-10 -10.5659 0.13269E-10 -10.8772 0.48842E+00 -0.3112 15 F- 0.99660E-06 -6.0015 0.81972E-06 -6.0863 0.82252E+00 -0.0849 16 HPO4-- 0.34761E-07 -7.4589 0.17179E-07 -7.7650 0.49420E+00 -0.3061 18 HSiO3- 0.90760E-02 -2.0421 0.74829E-02 -2.1259 0.82448E+00 -0.0838 19 Ca(HSiO3)+ 0.19665E-07 -7.7063 0.16249E-07 -7.7892 0.82629E+00 -0.0829 20 Mg(HSiO3)+ 0.38110E-11 -11.4190 0.31490E-11 -11.5018 0.82629E+00 -0.0829 21 NaHSiO3,aq 0.23480E-02 -2.6293 0.23480E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.78412E-16 -16.1056 0.64792E-16 -16.1885 0.82629E+00 -0.0829 24 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.46020E-05 -5.3371 0.37863E-05 -5.4218 0.82276E+00 -0.0847 26 CH4,aq 0.12249E-01 -1.9119 0.12235E-01 -1.9124 0.99878E+00 -0.0005 27 C2H6,aq 0.22125E-08 -8.6551 0.22098E-08 -8.6556 0.99878E+00 -0.0005 28 C3H8,aq 0.92262E-14 -14.0350 0.92150E-14 -14.0355 0.99878E+00 -0.0005 29 C4H10,aq 0.37795E-19 -19.4226 0.37749E-19 -19.4231 0.99878E+00 -0.0005 30 ethanol,aq 0.81208E-16 -16.0904 0.81109E-16 -16.0909 0.99878E+00 -0.0005 31 CO,aq 0.91773E-14 -14.0373 0.91773E-14 -14.0373 0.10000E+01 0.0000 32 CO2,aq 0.31580E-07 -7.5006 0.31542E-07 -7.5011 0.99878E+00 -0.0005 33 CO3-2 0.34676E-03 -3.4600 0.17092E-03 -3.7672 0.49291E+00 -0.3072 34 CaCO3,aq 0.20435E-06 -6.6896 0.20435E-06 -6.6896 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.50056E-09 -9.3005 0.41361E-09 -9.3834 0.82629E+00 -0.0829 36 CaCl+ 0.20208E-09 -9.6945 0.16698E-09 -9.7773 0.82629E+00 -0.0829 37 CaCl2,aq 0.42928E-13 -13.3673 0.42928E-13 -13.3673 0.10000E+01 0.0000 38 CaF+ 0.13810E-11 -11.8598 0.11411E-11 -11.9427 0.82629E+00 -0.0829 39 CaOH+ 0.94678E-07 -7.0238 0.78232E-07 -7.1066 0.82629E+00 -0.0829 40 CaSO4,aq 0.14631E-14 -14.8347 0.14631E-14 -14.8347 0.10000E+01 0.0000 41 HCl,aq 0.17221E-13 -13.7639 0.17221E-13 -13.7639 0.10000E+01 0.0000 45 HF,aq 0.48733E-12 -12.3122 0.48733E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16359E-18 -18.7863 0.13487E-18 -18.8701 0.82448E+00 -0.0838 48 FeCl+ 0.84940E-16 -16.0709 0.70186E-16 -16.1538 0.82629E+00 -0.0829 51 FeF+ 0.20773E-17 -17.6825 0.17165E-17 -17.7654 0.82629E+00 -0.0829 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.18584E-10 -10.7309 0.15356E-10 -10.8137 0.82629E+00 -0.0829 55 HFeO2- 0.30844E-07 -7.5108 0.25430E-07 -7.5946 0.82448E+00 -0.0838 56 FeO+ 0.13026E-16 -16.8852 0.10763E-16 -16.9681 0.82629E+00 -0.0829 58 FeO2- 0.35411E-09 -9.4509 0.29195E-09 -9.5347 0.82448E+00 -0.0838 59 HFeO2,aq 0.32247E-11 -11.4915 0.32247E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11594E-04 -4.9358 0.11580E-04 -4.9363 0.99878E+00 -0.0005 61 KCl,aq 0.30042E-08 -8.5223 0.30042E-08 -8.5223 0.10000E+01 0.0000 63 KOH,aq 0.75308E-06 -6.1232 0.75308E-06 -6.1232 0.10000E+01 0.0000 64 KSO4- 0.13932E-12 -12.8560 0.11486E-12 -12.9398 0.82448E+00 -0.0838 65 MgCO3,aq 0.79764E-11 -11.0982 0.79764E-11 -11.0982 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.79649E-13 -13.0988 0.65814E-13 -13.1817 0.82629E+00 -0.0829 67 MgCl+ 0.28521E-13 -13.5448 0.23567E-13 -13.6277 0.82629E+00 -0.0829 68 MgF+ 0.79665E-15 -15.0987 0.65826E-15 -15.1816 0.82629E+00 -0.0829 69 MgOH+ 0.81584E-10 -10.0884 0.67412E-10 -10.1713 0.82629E+00 -0.0829 71 MnF+ 0.22172E-15 -15.6542 0.18321E-15 -15.7371 0.82629E+00 -0.0829 72 MnO,aq 0.18216E-08 -8.7395 0.18216E-08 -8.7395 0.10000E+01 0.0000 73 MnOH+ 0.55903E-09 -9.2526 0.46193E-09 -9.3354 0.82629E+00 -0.0829 74 MnO2-2 0.16259E-10 -10.7889 0.80142E-11 -11.0961 0.49291E+00 -0.3072 75 HMnO2- 0.18494E-09 -9.7330 0.15248E-09 -9.8168 0.82448E+00 -0.0838 78 MnCl+ 0.10701E-12 -12.9706 0.88422E-13 -13.0534 0.82629E+00 -0.0829 79 MnSO4,aq 0.18512E-18 -18.7326 0.18512E-18 -18.7326 0.10000E+01 0.0000 80 NaCl,aq 0.69575E-05 -5.1575 0.69575E-05 -5.1575 0.10000E+01 0.0000 81 NaF,aq 0.37233E-08 -8.4291 0.37233E-08 -8.4291 0.10000E+01 0.0000 82 NaOH,aq 0.95962E-04 -4.0179 0.95962E-04 -4.0179 0.10000E+01 0.0000 84 OH- 0.80844E-02 -2.0924 0.66516E-02 -2.1771 0.82276E+00 -0.0847 89 HPO3-2 0.12580E-14 -14.9003 0.62007E-15 -15.2076 0.49291E+00 -0.3072 91 H2PO3- 0.13097E-18 -18.8828 0.10798E-18 -18.9666 0.82448E+00 -0.0838 92 H3PO4,aq 0.90615E-18 -18.0428 0.90615E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.33344E-10 -10.4770 0.27521E-10 -10.5603 0.82538E+00 -0.0833 94 PO4-3 0.73960E-09 -9.1310 0.16140E-09 -9.7921 0.21822E+00 -0.6611 98 HP2O7-3 0.66154E-18 -18.1794 0.13658E-18 -18.8646 0.20646E+00 -0.6852 99 P2O7-4 0.59358E-17 -17.2265 0.37572E-18 -18.4251 0.63297E-01 -1.1986 100 H2S,aq 0.96268E-06 -6.0165 0.96151E-06 -6.0170 0.99878E+00 -0.0005 101 S2-2 0.49819E-10 -10.3026 0.24556E-10 -10.6098 0.49291E+00 -0.3072 102 S3-2 0.55731E-17 -17.2539 0.27470E-17 -17.5611 0.49291E+00 -0.3072 107 SO3-2 0.14514E-15 -15.8382 0.72734E-16 -16.1383 0.50114E+00 -0.3000 108 HSO3- 0.47969E-18 -18.3190 0.39549E-18 -18.4029 0.82448E+00 -0.0838 109 HSO4- 0.48891E-17 -17.3108 0.40444E-17 -17.3931 0.82723E+00 -0.0824 111 S2O3-2 0.11076E-17 -17.9556 0.54593E-18 -18.2629 0.49291E+00 -0.3072 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1046019E-09 -.1997265E-01 -.2008884E+02 0.0000 2 H2O 0.1000000E+01 0.5551728E+02 0.9980546E+06 0.0000 3 Cl- 0.1312509E-02 0.1319469E-02 0.4668065E+02 7.0955 4 SO4-- 0.9779912E-10 -.1225240E-01 -.1174507E+04 9.8067 5 HCO3- 0.2057696E-03 0.1280227E-01 0.7795137E+03 6.2916 6 HS- 0.4344271E-02 0.1659763E-01 0.5477611E+03 7.6154 7 Al+++ 0.1742273E-28 0.4602106E-05 0.1239103E+00 0.7392 8 H4SiO4 0.6958076E-03 0.1211985E-01 0.1162452E+04 -3.1575 9 Ca++ 0.1946196E-06 0.5140133E-06 0.2055725E-01 13.1018 10 Mg++ 0.3046782E-10 0.1239482E-09 0.3007084E-05 9.2942 11 Fe++ 0.8397634E-13 0.3143139E-07 0.1751653E-02 6.7351 12 K+ 0.1854239E-03 0.1861800E-03 0.7264681E+01 6.2465 13 Na+ 0.2353627E-01 0.2598721E-01 0.5961828E+03 8.3491 14 Mn++ 0.2716757E-10 0.2609149E-08 0.1430396E-03 9.2454 15 F- 0.9965980E-06 0.1000323E-05 0.1896413E-01 3.9749 16 HPO4-- 0.3476127E-07 0.3553421E-07 0.3403357E-02 12.3575 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278307E+02 -.9945159E-02 -.8277313E+02 0.0000000E+00 2 H2O -.7096751E+01 0.2764422E+02 -.3474097E+02 0.0000000E+00 3 Cl- 0.6570152E-03 0.6570152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1390127E+00 -.6100946E-02 0.1451136E+00 0.0000000E+00 5 HCO3- 0.6374747E-02 0.6374747E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1368490E+00 0.8264608E-02 -.1451136E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2291568E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6034947E-02 0.5205787E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2559472E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6171863E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1565091E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9270626E-04 0.1061478E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1294004E-01 0.6263437E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1299197E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3529600E-04 0.4980999E-06 0.3479790E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1769387E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.2165E-14 Mass of aqueous solution: 0.498990E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0879900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.251 0.796 1639. 3.215 30.01 629.2 andradite 0.5805 -0.236 295.0 2.470 5.400 76.64 grossular 0.1406 -0.852 63.33 1.802 1.159 17.62 apatite-OH 0.9828E-02 -2.008 4.937 0.693 0.9038E-01 1.569 apatite-F 0.3480E-04 -4.458 0.1755E-01 -1.756 0.3213E-03 0.5482E-02 clinochlore 0.7041 -0.152 391.4 2.593 7.165 148.9 daphnite 0.2039 -0.691 145.5 2.163 2.663 44.08 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.9307E-01 -1.031 20.16 1.304 0.3690 6.160 hedenbergite 0.2414E-01 -1.617 5.989 0.777 0.1096 1.640 microcline 0.9376 -0.028 261.0 2.417 4.778 101.9 stilbite 3.225 0.509 2273. 3.357 41.61 1060. stilpnomelane-Fe 0.2477 -0.606 267.0 2.426 4.888 92.22 tr.625ac.25prg.125 0.9780E-01 -1.010 83.60 1.922 1.530 26.91 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1874E-01 0.1874E-01 1.0000 -1.727 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.361166 g Volume = 2211.021466 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0879900 moles log = -1.0556 Original solution: 1000.0103000 g Original solution / Rock added: 11365.04 (Water/Rock Ratio), log = 4.0556 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 19.2809 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.5472E-01 0.9532 0.1006E+01 0.1055E+01 CO2,gas 0.1813E-06 0.9653 0.3375E-05 0.3496E-05 CH4,gas 0.9445E+00 0.9889 0.1801E+02 0.1821E+02 H2,gas 0.7804E-03 1.0103 0.1520E-01 0.1505E-01 H2S,gas 0.1476E-05 0.9287 0.2643E-04 0.2846E-04 S2,gas 0.5884E-26 1.0000 0.1135E-24 0.1135E-24 CO,gas 0.7093E-12 1.0000 0.1368E-10 0.1368E-10 SO3,gas 0.7149E-47 1.0000 0.1378E-45 0.1378E-45 SO2,gas 0.4229E-26 1.0000 0.8154E-25 0.8154E-25 HF,gas 0.6206E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1576E-17 1.0000 0.3039E-16 0.3039E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.002 2 CO2,gas -6.66 -13.83 -7.17 -2.390 0.12244E+05 -5.472 3 CH4,gas 4.54 4.10 -0.44 -0.111 0.75726E+03 1.255 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60053E+04 -1.818 5 H2S,gas -6.23 -12.51 -6.28 -3.138 0.10718E+05 -4.578 6 S2,gas -7.34 -33.98 -26.64 -4.099 0.45494E+05 -24.945 7 CO,gas 3.21 -9.35 -12.56 -3.866 0.21451E+05 -10.864 8 SO3,gas 17.12 -30.44 -47.56 -11.890 0.81207E+05 -45.861 9 SO2,gas 0.83 -25.96 -26.79 -7.143 0.45739E+05 -25.089 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.03 -18.22 -9.108 0.31104E+05 -16.517 12 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80514E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93656E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41066E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28496E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 38 aragonite 0.97 -0.73 -1.70 -0.565 0.28953E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55912E+04 40 calcite 0.81 -0.73 -1.54 -0.514 0.26311E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52804E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71074E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28880E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39698E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68947E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 55 chloritoid-Mn 11.40 7.57 -3.84 -0.256 0.65483E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71235E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.87 -1.76 -0.504 0.30100E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68199E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37137E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.87 -1.32 -0.377 0.22523E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64129E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28624E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48024E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82178E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41128E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36684E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91149E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 145 pyrite -21.25 -22.76 -1.51 -0.356 0.25867E+04 146 pyrrhotite -4.26 -5.77 -1.51 -0.504 0.25812E+04 147 pyrrhotiteFe0.875 -6.02 -7.17 -1.15 -0.424 0.19684E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22380E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84955E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28666E+03 154 rhodochrosite -0.98 -4.59 -3.61 -1.203 0.61628E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23183E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.10 -4.49 -1.496 0.76627E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27811E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.46999E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90663E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77509E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65443E+04 184 troilite-low -4.41 -5.77 -1.36 -0.454 0.23240E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66604E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60595E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66175E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68812E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73672E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60361E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58211E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83481E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66550E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.26 -2.28 -0.761 0.38996E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.0879900 MOLES New total amount of reactant added: 0.0919900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0919900 Water: Moles liquid = 0.2764E+02 kg liquid = 0.4980E+00 Moles total = -.7093E+01 kg total = -.1278E+00 Activity = 0.9998 Stoichiometric ionic strength = .3620075E-02 Osmotic coef. = 0.9494 True ionic strength = .2425053E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.6806E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10535E-09 -9.9774 0.87419E-10 -10.0584 0.82981E+00 -0.0810 2 H2O 0.99977E+00 -0.0001 0.99977E+00 -0.0001 3 Cl- 0.13594E-02 -2.8666 0.11202E-02 -2.9507 0.82403E+00 -0.0841 4 SO4-- 0.10166E-09 -9.9928 0.50128E-10 -10.2999 0.49309E+00 -0.3071 5 HCO3- 0.21388E-03 -3.6698 0.17654E-03 -3.7532 0.82543E+00 -0.0833 6 HS- 0.45388E-02 -2.3431 0.37407E-02 -2.4270 0.82417E+00 -0.0840 7 Al+++ 0.17857E-28 -28.7482 0.36646E-29 -29.4360 0.20522E+00 -0.6878 8 H4SiO4 0.69580E-03 -3.1575 0.69580E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.19763E-06 -6.7041 0.96616E-07 -7.0149 0.48888E+00 -0.3108 10 Mg++ 0.30940E-10 -10.5095 0.15045E-10 -10.8226 0.48628E+00 -0.3131 11 Fe++ 0.85278E-13 -13.0692 0.41522E-13 -13.3817 0.48690E+00 -0.3126 12 K+ 0.18675E-03 -3.7287 0.15419E-03 -3.8120 0.82565E+00 -0.0832 13 Na+ 0.23704E-01 -1.6252 0.19529E-01 -1.7093 0.82385E+00 -0.0842 14 Mn++ 0.27599E-10 -10.5591 0.13451E-10 -10.8712 0.48737E+00 -0.3121 15 F- 0.99058E-06 -6.0041 0.81432E-06 -6.0892 0.82206E+00 -0.0851 16 HPO4-- 0.34377E-07 -7.4637 0.16954E-07 -7.7707 0.49317E+00 -0.3070 18 HSiO3- 0.90212E-02 -2.0447 0.74337E-02 -2.1288 0.82403E+00 -0.0841 19 Ca(HSiO3)+ 0.19805E-07 -7.7032 0.16356E-07 -7.7863 0.82586E+00 -0.0831 20 Mg(HSiO3)+ 0.38383E-11 -11.4159 0.31699E-11 -11.4990 0.82586E+00 -0.0831 21 NaHSiO3,aq 0.23479E-02 -2.6293 0.23479E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.78975E-16 -16.1025 0.65222E-16 -16.1856 0.82586E+00 -0.0831 24 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.45742E-05 -5.3397 0.37614E-05 -5.4246 0.82231E+00 -0.0850 26 CH4,aq 0.12808E-01 -1.8925 0.12794E-01 -1.8930 0.99888E+00 -0.0005 27 C2H6,aq 0.24193E-08 -8.6163 0.24166E-08 -8.6168 0.99888E+00 -0.0005 28 C3H8,aq 0.10550E-13 -13.9767 0.10538E-13 -13.9772 0.99888E+00 -0.0005 29 C4H10,aq 0.45195E-19 -19.3449 0.45145E-19 -19.3454 0.99888E+00 -0.0005 30 ethanol,aq 0.88798E-16 -16.0516 0.88698E-16 -16.0521 0.99888E+00 -0.0005 31 CO,aq 0.95972E-14 -14.0179 0.95972E-14 -14.0179 0.10000E+01 0.0000 32 CO2,aq 0.33022E-07 -7.4812 0.32985E-07 -7.4817 0.99888E+00 -0.0005 33 CO3-2 0.35862E-03 -3.4454 0.17639E-03 -3.7535 0.49187E+00 -0.3081 34 CaCO3,aq 0.21370E-06 -6.6702 0.21370E-06 -6.6702 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.52720E-09 -9.2780 0.43540E-09 -9.3611 0.82586E+00 -0.0831 36 CaCl+ 0.21208E-09 -9.6735 0.17515E-09 -9.7566 0.82586E+00 -0.0831 37 CaCl2,aq 0.46613E-13 -13.3315 0.46613E-13 -13.3315 0.10000E+01 0.0000 38 CaF+ 0.13909E-11 -11.8567 0.11487E-11 -11.9398 0.82586E+00 -0.0831 39 CaOH+ 0.95355E-07 -7.0207 0.78749E-07 -7.1038 0.82586E+00 -0.0831 40 CaSO4,aq 0.15379E-14 -14.8131 0.15379E-14 -14.8131 0.10000E+01 0.0000 41 HCl,aq 0.17945E-13 -13.7461 0.17945E-13 -13.7461 0.10000E+01 0.0000 45 HF,aq 0.48733E-12 -12.3122 0.48733E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16260E-18 -18.7889 0.13398E-18 -18.8729 0.82403E+00 -0.0841 48 FeCl+ 0.89145E-16 -16.0499 0.73621E-16 -16.1330 0.82586E+00 -0.0831 51 FeF+ 0.20922E-17 -17.6794 0.17278E-17 -17.7625 0.82586E+00 -0.0831 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.18717E-10 -10.7278 0.15457E-10 -10.8109 0.82586E+00 -0.0831 55 HFeO2- 0.30658E-07 -7.5135 0.25263E-07 -7.5975 0.82403E+00 -0.0841 56 FeO+ 0.13119E-16 -16.8821 0.10834E-16 -16.9652 0.82586E+00 -0.0831 58 FeO2- 0.35197E-09 -9.4535 0.29003E-09 -9.5376 0.82403E+00 -0.0841 59 HFeO2,aq 0.32247E-11 -11.4915 0.32247E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11593E-04 -4.9358 0.11580E-04 -4.9363 0.99888E+00 -0.0005 61 KCl,aq 0.31304E-08 -8.5044 0.31304E-08 -8.5044 0.10000E+01 0.0000 63 KOH,aq 0.75305E-06 -6.1232 0.75305E-06 -6.1232 0.10000E+01 0.0000 64 KSO4- 0.14555E-12 -12.8370 0.11994E-12 -12.9210 0.82403E+00 -0.0841 65 MgCO3,aq 0.83412E-11 -11.0788 0.83412E-11 -11.0788 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.83889E-13 -13.0763 0.69281E-13 -13.1594 0.82586E+00 -0.0831 67 MgCl+ 0.29933E-13 -13.5238 0.24720E-13 -13.6069 0.82586E+00 -0.0831 68 MgF+ 0.80234E-15 -15.0956 0.66262E-15 -15.1787 0.82586E+00 -0.0831 69 MgOH+ 0.82167E-10 -10.0853 0.67858E-10 -10.1684 0.82586E+00 -0.0831 71 MnF+ 0.22340E-15 -15.6509 0.18450E-15 -15.7340 0.82586E+00 -0.0831 72 MnO,aq 0.18224E-08 -8.7394 0.18224E-08 -8.7394 0.10000E+01 0.0000 73 MnOH+ 0.56326E-09 -9.2493 0.46517E-09 -9.3324 0.82586E+00 -0.0831 74 MnO2-2 0.16086E-10 -10.7936 0.79121E-11 -11.1017 0.49187E+00 -0.3081 75 HMnO2- 0.18389E-09 -9.7354 0.15153E-09 -9.8195 0.82403E+00 -0.0841 78 MnCl+ 0.11235E-12 -12.9494 0.92786E-13 -13.0325 0.82586E+00 -0.0831 79 MnSO4,aq 0.19466E-18 -18.7107 0.19466E-18 -18.7107 0.10000E+01 0.0000 80 NaCl,aq 0.72498E-05 -5.1397 0.72498E-05 -5.1397 0.10000E+01 0.0000 81 NaF,aq 0.37231E-08 -8.4291 0.37231E-08 -8.4291 0.10000E+01 0.0000 82 NaOH,aq 0.95958E-04 -4.0179 0.95958E-04 -4.0179 0.10000E+01 0.0000 84 OH- 0.80356E-02 -2.0950 0.66077E-02 -2.1799 0.82231E+00 -0.0850 89 HPO3-2 0.12441E-14 -14.9051 0.61194E-15 -15.2133 0.49187E+00 -0.3081 91 H2PO3- 0.13018E-18 -18.8854 0.10727E-18 -18.9695 0.82403E+00 -0.0841 92 H3PO4,aq 0.90615E-18 -18.0428 0.90615E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.33142E-10 -10.4796 0.27340E-10 -10.5632 0.82493E+00 -0.0836 94 PO4-3 0.72832E-09 -9.1377 0.15823E-09 -9.8007 0.21725E+00 -0.6630 98 HP2O7-3 0.65167E-18 -18.1860 0.13390E-18 -18.8732 0.20548E+00 -0.6872 99 P2O7-4 0.58292E-17 -17.2344 0.36593E-18 -18.4366 0.62775E-01 -1.2022 100 H2S,aq 0.10118E-05 -5.9949 0.10107E-05 -5.9954 0.99888E+00 -0.0005 101 S2-2 0.54436E-10 -10.2641 0.26776E-10 -10.5723 0.49187E+00 -0.3081 102 S3-2 0.64010E-17 -17.1938 0.31485E-17 -17.5019 0.49187E+00 -0.3081 107 SO3-2 0.15086E-15 -15.8214 0.75450E-16 -16.1223 0.50013E+00 -0.3009 108 HSO3- 0.50117E-18 -18.3000 0.41298E-18 -18.3841 0.82403E+00 -0.0841 109 HSO4- 0.51079E-17 -17.2918 0.42232E-17 -17.3744 0.82680E+00 -0.0826 111 S2O3-2 0.12102E-17 -17.9171 0.59527E-18 -18.2253 0.49187E+00 -0.3081 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1053480E-09 -.1988057E-01 -.1999589E+02 0.0000 2 H2O 0.1000000E+01 0.5551784E+02 0.9980477E+06 0.0000 3 Cl- 0.1359412E-02 0.1366665E-02 0.4834953E+02 7.1077 4 SO4-- 0.1016622E-09 -.1281126E-01 -.1228058E+04 9.8169 5 HCO3- 0.2138803E-03 0.1338110E-01 0.8147444E+03 6.3052 6 HS- 0.4538763E-02 0.1735103E-01 0.5726153E+03 7.6313 7 Al+++ 0.1785686E-28 0.4574366E-05 0.1231613E+00 0.7392 8 H4SiO4 0.6957997E-03 0.1206491E-01 0.1157162E+04 -3.1575 9 Ca++ 0.1976296E-06 0.5272261E-06 0.2108532E-01 13.1018 10 Mg++ 0.3093996E-10 0.1254005E-09 0.3042266E-05 9.2942 11 Fe++ 0.8527777E-13 0.3124262E-07 0.1741103E-02 6.7351 12 K+ 0.1867462E-03 0.1875024E-03 0.7316158E+01 6.2464 13 Na+ 0.2370442E-01 0.2615557E-01 0.6000351E+03 8.3491 14 Mn++ 0.2759931E-10 0.2613303E-08 0.1432649E-03 9.2455 15 F- 0.9905784E-06 0.9943033E-06 0.1884968E-01 3.9692 16 HPO4-- 0.3437682E-07 0.3513828E-07 0.3365379E-02 12.3460 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278264E+02 -.9900757E-02 -.8277274E+02 0.0000000E+00 2 H2O -.7093477E+01 0.2764854E+02 -.3474202E+02 0.0000000E+00 3 Cl- 0.6806152E-03 0.6806152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1390318E+00 -.6380156E-02 0.1454119E+00 0.0000000E+00 5 HCO3- 0.6663947E-02 0.6663947E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1367709E+00 0.8641018E-02 -.1454119E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2278088E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6008468E-02 0.5205790E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2625648E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6245093E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1555919E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9337841E-04 0.1061478E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1302578E-01 0.6263351E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1301456E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3689600E-04 0.4951748E-06 0.3640083E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1749928E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1481E-13 Mass of aqueous solution: 0.499071E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0919900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.251 0.796 1639. 3.215 30.01 629.2 andradite 0.5816 -0.235 295.6 2.471 5.411 76.79 grossular 0.1409 -0.851 63.46 1.802 1.162 17.66 apatite-OH 0.9826E-02 -2.008 4.936 0.693 0.9036E-01 1.568 apatite-F 0.3640E-04 -4.439 0.1836E-01 -1.736 0.3361E-03 0.5735E-02 clinochlore 0.7038 -0.153 391.2 2.592 7.162 148.8 daphnite 0.2038 -0.691 145.4 2.163 2.662 44.06 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.8530E-01 -1.069 18.47 1.267 0.3382 5.645 hedenbergite 0.2212E-01 -1.655 5.489 0.739 0.1005 1.503 microcline 0.9380 -0.028 261.1 2.417 4.779 102.0 stilbite 3.226 0.509 2273. 3.357 41.62 1060. stilpnomelane-Fe 0.2470 -0.607 266.3 2.425 4.875 91.99 tr.625ac.25prg.125 0.1003 -0.999 85.76 1.933 1.570 27.60 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1874E-01 0.1874E-01 1.0000 -1.727 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.362029 g Volume = 2211.032595 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0919900 moles log = -1.0363 Original solution: 1000.0103000 g Original solution / Rock added: 10870.86 (Water/Rock Ratio), log = 4.0363 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 20.1249 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.5248E-01 0.9522 0.1006E+01 0.1056E+01 CO2,gas 0.1819E-06 0.9640 0.3529E-05 0.3661E-05 CH4,gas 0.9468E+00 0.9884 0.1883E+02 0.1905E+02 H2,gas 0.7474E-03 1.0108 0.1520E-01 0.1504E-01 H2S,gas 0.1491E-05 0.9257 0.2778E-04 0.3001E-04 S2,gas 0.6229E-26 1.0000 0.1254E-24 0.1254E-24 CO,gas 0.7106E-12 1.0000 0.1430E-10 0.1430E-10 SO3,gas 0.7199E-47 1.0000 0.1449E-45 0.1449E-45 SO2,gas 0.4259E-26 1.0000 0.8571E-25 0.8571E-25 HF,gas 0.5946E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1573E-17 1.0000 0.3166E-16 0.3166E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.002 2 CO2,gas -6.66 -13.81 -7.15 -2.384 0.12211E+05 -5.452 3 CH4,gas 4.54 4.12 -0.42 -0.106 0.72410E+03 1.275 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60053E+04 -1.818 5 H2S,gas -6.23 -12.49 -6.26 -3.128 0.10681E+05 -4.556 6 S2,gas -7.34 -33.94 -26.60 -4.092 0.45420E+05 -24.902 7 CO,gas 3.21 -9.33 -12.54 -3.860 0.21418E+05 -10.845 8 SO3,gas 17.12 -30.42 -47.54 -11.884 0.81170E+05 -45.839 9 SO2,gas 0.83 -25.93 -26.77 -7.138 0.45702E+05 -25.067 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -13.01 -18.20 -9.099 0.31073E+05 -16.499 12 acmite 7.71 6.53 -1.18 -0.123 0.20178E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.71 -0.236 0.80505E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93657E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41067E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28496E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 38 aragonite 0.97 -0.71 -1.68 -0.559 0.28621E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55912E+04 40 calcite 0.81 -0.71 -1.52 -0.507 0.25979E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52804E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71074E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39698E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68947E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65480E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.85 -1.74 -0.498 0.29768E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65864E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57767E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68199E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.17 -0.059 0.37137E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.85 -1.30 -0.371 0.22191E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64129E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28624E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48024E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82175E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41128E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36684E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19847E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91149E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40577E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 145 pyrite -21.25 -22.72 -1.47 -0.346 0.25127E+04 146 pyrrhotite -4.26 -5.75 -1.49 -0.497 0.25442E+04 147 pyrrhotiteFe0.875 -6.02 -7.15 -1.13 -0.416 0.19314E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22377E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28665E+03 154 rhodochrosite -0.98 -4.57 -3.59 -1.197 0.61293E+04 155 rhodonite 7.45 6.09 -1.36 -0.272 0.23180E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.08 -4.47 -1.489 0.76296E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27811E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.46994E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90663E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77509E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65443E+04 184 troilite-low -4.41 -5.75 -1.34 -0.446 0.22870E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34151E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66604E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60595E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66174E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68812E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73672E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60361E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58211E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83481E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66550E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.24 -2.26 -0.754 0.38624E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.0919900 MOLES New total amount of reactant added: 0.0959900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0959900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4981E+00 Moles total = -.7090E+01 kg total = -.1277E+00 Activity = 0.9998 Stoichiometric ionic strength = .3276625E-02 Osmotic coef. = 0.9516 True ionic strength = .2443200E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.7042E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10610E-09 -9.9743 0.87996E-10 -10.0555 0.82940E+00 -0.0812 2 H2O 0.99976E+00 -0.0001 0.99976E+00 -0.0001 3 Cl- 0.14063E-02 -2.8519 0.11582E-02 -2.9362 0.82358E+00 -0.0843 4 SO4-- 0.10549E-09 -9.9768 0.51905E-10 -10.2848 0.49207E+00 -0.3080 5 HCO3- 0.22190E-03 -3.6538 0.18306E-03 -3.7374 0.82499E+00 -0.0836 6 HS- 0.47332E-02 -2.3248 0.38988E-02 -2.4091 0.82372E+00 -0.0842 7 Al+++ 0.18300E-28 -28.7376 0.37377E-29 -29.4274 0.20425E+00 -0.6898 8 H4SiO4 0.69579E-03 -3.1575 0.69579E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.20067E-06 -6.6975 0.97895E-07 -7.0092 0.48784E+00 -0.3117 10 Mg++ 0.31417E-10 -10.5028 0.15245E-10 -10.8169 0.48523E+00 -0.3141 11 Fe++ 0.86593E-13 -13.0625 0.42071E-13 -13.3760 0.48585E+00 -0.3135 12 K+ 0.18807E-03 -3.7257 0.15520E-03 -3.8091 0.82521E+00 -0.0834 13 Na+ 0.23873E-01 -1.6221 0.19657E-01 -1.7065 0.82340E+00 -0.0844 14 Mn++ 0.28036E-10 -10.5523 0.13634E-10 -10.8654 0.48632E+00 -0.3131 15 F- 0.98462E-06 -6.0067 0.80898E-06 -6.0921 0.82161E+00 -0.0853 16 HPO4-- 0.33998E-07 -7.4685 0.16732E-07 -7.7764 0.49215E+00 -0.3079 18 HSiO3- 0.89669E-02 -2.0474 0.73850E-02 -2.1317 0.82358E+00 -0.0843 19 Ca(HSiO3)+ 0.19947E-07 -7.7001 0.16464E-07 -7.7835 0.82542E+00 -0.0833 20 Mg(HSiO3)+ 0.38657E-11 -11.4128 0.31908E-11 -11.4961 0.82542E+00 -0.0833 21 NaHSiO3,aq 0.23479E-02 -2.6293 0.23479E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.79539E-16 -16.0994 0.65653E-16 -16.1827 0.82542E+00 -0.0833 24 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.45468E-05 -5.3423 0.37368E-05 -5.4275 0.82185E+00 -0.0852 26 CH4,aq 0.13367E-01 -1.8740 0.13354E-01 -1.8744 0.99899E+00 -0.0004 27 C2H6,aq 0.26354E-08 -8.5792 0.26327E-08 -8.5796 0.99899E+00 -0.0004 28 C3H8,aq 0.11995E-13 -13.9210 0.11983E-13 -13.9214 0.99899E+00 -0.0004 29 C4H10,aq 0.53636E-19 -19.2705 0.53582E-19 -19.2710 0.99899E+00 -0.0004 30 ethanol,aq 0.96730E-16 -16.0144 0.96632E-16 -16.0149 0.99899E+00 -0.0004 31 CO,aq 0.10017E-13 -13.9992 0.10017E-13 -13.9992 0.10000E+01 0.0000 32 CO2,aq 0.34464E-07 -7.4626 0.34429E-07 -7.4631 0.99899E+00 -0.0004 33 CO3-2 0.37020E-03 -3.4316 0.18171E-03 -3.7406 0.49085E+00 -0.3091 34 CaCO3,aq 0.22305E-06 -6.6516 0.22305E-06 -6.6516 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.55420E-09 -9.2563 0.45745E-09 -9.3397 0.82542E+00 -0.0833 36 CaCl+ 0.22230E-09 -9.6531 0.18349E-09 -9.7364 0.82542E+00 -0.0833 37 CaCl2,aq 0.50489E-13 -13.2968 0.50489E-13 -13.2968 0.10000E+01 0.0000 38 CaF+ 0.14008E-11 -11.8536 0.11563E-11 -11.9369 0.82542E+00 -0.0833 39 CaOH+ 0.96033E-07 -7.0176 0.79268E-07 -7.1009 0.82542E+00 -0.0833 40 CaSO4,aq 0.16135E-14 -14.7922 0.16135E-14 -14.7922 0.10000E+01 0.0000 41 HCl,aq 0.18676E-13 -13.7287 0.18676E-13 -13.7287 0.10000E+01 0.0000 45 HF,aq 0.48732E-12 -12.3122 0.48732E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16161E-18 -18.7915 0.13310E-18 -18.8758 0.82358E+00 -0.0843 48 FeCl+ 0.93440E-16 -16.0295 0.77127E-16 -16.1128 0.82542E+00 -0.0833 51 FeF+ 0.21071E-17 -17.6763 0.17392E-17 -17.7596 0.82542E+00 -0.0833 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.18850E-10 -10.7247 0.15559E-10 -10.8080 0.82542E+00 -0.0833 55 HFeO2- 0.30473E-07 -7.5161 0.25097E-07 -7.6004 0.82358E+00 -0.0843 56 FeO+ 0.13213E-16 -16.8790 0.10906E-16 -16.9623 0.82542E+00 -0.0833 58 FeO2- 0.34985E-09 -9.4561 0.28813E-09 -9.5404 0.82358E+00 -0.0843 59 HFeO2,aq 0.32246E-11 -11.4915 0.32246E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11591E-04 -4.9359 0.11580E-04 -4.9363 0.99899E+00 -0.0004 61 KCl,aq 0.32579E-08 -8.4871 0.32579E-08 -8.4871 0.10000E+01 0.0000 63 KOH,aq 0.75302E-06 -6.1232 0.75302E-06 -6.1232 0.10000E+01 0.0000 64 KSO4- 0.15178E-12 -12.8188 0.12500E-12 -12.9031 0.82358E+00 -0.0843 65 MgCO3,aq 0.87064E-11 -11.0602 0.87064E-11 -11.0602 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.88185E-13 -13.0546 0.72790E-13 -13.1379 0.82542E+00 -0.0833 67 MgCl+ 0.31375E-13 -13.5034 0.25897E-13 -13.5867 0.82542E+00 -0.0833 68 MgF+ 0.80805E-15 -15.0926 0.66698E-15 -15.1759 0.82542E+00 -0.0833 69 MgOH+ 0.82752E-10 -10.0822 0.68305E-10 -10.1655 0.82542E+00 -0.0833 71 MnF+ 0.22508E-15 -15.6477 0.18578E-15 -15.7310 0.82542E+00 -0.0833 72 MnO,aq 0.18231E-08 -8.7392 0.18231E-08 -8.7392 0.10000E+01 0.0000 73 MnOH+ 0.56750E-09 -9.2460 0.46842E-09 -9.3294 0.82542E+00 -0.0833 74 MnO2-2 0.15915E-10 -10.7982 0.78117E-11 -11.1073 0.49085E+00 -0.3091 75 HMnO2- 0.18286E-09 -9.7379 0.15060E-09 -9.8222 0.82358E+00 -0.0843 78 MnCl+ 0.11781E-12 -12.9288 0.97243E-13 -13.0121 0.82542E+00 -0.0833 79 MnSO4,aq 0.20431E-18 -18.6897 0.20431E-18 -18.6897 0.10000E+01 0.0000 80 NaCl,aq 0.75450E-05 -5.1223 0.75450E-05 -5.1223 0.10000E+01 0.0000 81 NaF,aq 0.37230E-08 -8.4291 0.37230E-08 -8.4291 0.10000E+01 0.0000 82 NaOH,aq 0.95954E-04 -4.0179 0.95954E-04 -4.0179 0.10000E+01 0.0000 84 OH- 0.79873E-02 -2.0976 0.65643E-02 -2.1828 0.82185E+00 -0.0852 89 HPO3-2 0.12304E-14 -14.9099 0.60394E-15 -15.2190 0.49085E+00 -0.3091 91 H2PO3- 0.12940E-18 -18.8881 0.10657E-18 -18.9724 0.82358E+00 -0.0843 92 H3PO4,aq 0.90615E-18 -18.0428 0.90615E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.32943E-10 -10.4822 0.27161E-10 -10.5661 0.82449E+00 -0.0838 94 PO4-3 0.71726E-09 -9.1443 0.15514E-09 -9.8093 0.21629E+00 -0.6650 98 HP2O7-3 0.64199E-18 -18.1925 0.13129E-18 -18.8818 0.20451E+00 -0.6893 99 P2O7-4 0.57250E-17 -17.2422 0.35644E-18 -18.4480 0.62260E-01 -1.2058 100 H2S,aq 0.10614E-05 -5.9741 0.10603E-05 -5.9746 0.99899E+00 -0.0004 101 S2-2 0.59260E-10 -10.2272 0.29088E-10 -10.5363 0.49085E+00 -0.3091 102 S3-2 0.73108E-17 -17.1360 0.35885E-17 -17.4451 0.49085E+00 -0.3091 107 SO3-2 0.15652E-15 -15.8054 0.78124E-16 -16.1072 0.49914E+00 -0.3018 108 HSO3- 0.52264E-18 -18.2818 0.43044E-18 -18.3661 0.82358E+00 -0.0843 109 HSO4- 0.53266E-17 -17.2735 0.44017E-17 -17.3564 0.82636E+00 -0.0828 111 S2O3-2 0.13175E-17 -17.8803 0.64667E-18 -18.1893 0.49085E+00 -0.3091 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1060959E-09 -.1978933E-01 -.1990378E+02 0.0000 2 H2O 0.1000000E+01 0.5551841E+02 0.9980407E+06 0.0000 3 Cl- 0.1406298E-02 0.1413847E-02 0.5001785E+02 7.1193 4 SO4-- 0.1054850E-09 -.1337031E-01 -.1281626E+04 9.8263 5 HCO3- 0.2218973E-03 0.1395977E-01 0.8499636E+03 6.3181 6 HS- 0.4733198E-02 0.1810457E-01 0.5974733E+03 7.6465 7 Al+++ 0.1829969E-28 0.4546923E-05 0.1224203E+00 0.7392 8 H4SiO4 0.6957919E-03 0.1201056E-01 0.1151930E+04 -3.1575 9 Ca++ 0.2006716E-06 0.5404792E-06 0.2161498E-01 13.1018 10 Mg++ 0.3141715E-10 0.1268613E-09 0.3077654E-05 9.2942 11 Fe++ 0.8659313E-13 0.3105588E-07 0.1730667E-02 6.7351 12 K+ 0.1880717E-03 0.1888280E-03 0.7367753E+01 6.2464 13 Na+ 0.2387297E-01 0.2632434E-01 0.6038963E+03 8.3491 14 Mn++ 0.2803590E-10 0.2617490E-08 0.1434920E-03 9.2457 15 F- 0.9846235E-06 0.9883484E-06 0.1873647E-01 3.9635 16 HPO4-- 0.3399844E-07 0.3474865E-07 0.3328004E-02 12.3346 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278221E+02 -.9856762E-02 -.8277235E+02 0.0000000E+00 2 H2O -.7090202E+01 0.2765286E+02 -.3474306E+02 0.0000000E+00 3 Cl- 0.7042152E-03 0.7042152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1390509E+00 -.6659547E-02 0.1457104E+00 0.0000000E+00 5 HCO3- 0.6953147E-02 0.6953147E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1366928E+00 0.9017609E-02 -.1457104E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2264752E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5982275E-02 0.5205792E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2692044E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6318768E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1546846E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9405230E-04 0.1061477E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1311175E-01 0.6263265E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1303731E-08 0.8669296E-01 0.0000000E+00 15 F- 0.3849600E-04 0.4922811E-06 0.3800372E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1730776E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.8056E-14 Mass of aqueous solution: 0.499153E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0959900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.250 0.796 1639. 3.215 30.00 629.2 andradite 0.5828 -0.234 296.2 2.472 5.422 76.95 grossular 0.1412 -0.850 63.59 1.803 1.164 17.69 apatite-OH 0.9825E-02 -2.008 4.935 0.693 0.9035E-01 1.568 apatite-F 0.3800E-04 -4.420 0.1917E-01 -1.717 0.3509E-03 0.5987E-02 clinochlore 0.7036 -0.153 391.1 2.592 7.159 148.7 daphnite 0.2037 -0.691 145.4 2.162 2.661 44.05 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.7752E-01 -1.111 16.79 1.225 0.3073 5.130 hedenbergite 0.2011E-01 -1.697 4.988 0.698 0.9132E-01 1.366 microcline 0.9383 -0.028 261.2 2.417 4.781 102.0 stilbite 3.226 0.509 2273. 3.357 41.62 1060. stilpnomelane-Fe 0.2464 -0.608 265.6 2.424 4.863 91.75 tr.625ac.25prg.125 0.1029 -0.988 87.93 1.944 1.610 28.30 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1875E-01 0.1875E-01 1.0000 -1.727 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.362877 g Volume = 2211.043730 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0959900 moles log = -1.0178 Original solution: 1000.0103000 g Original solution / Rock added: 10417.86 (Water/Rock Ratio), log = 4.0178 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 20.9703 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.5042E-01 0.9512 0.1006E+01 0.1057E+01 CO2,gas 0.1825E-06 0.9627 0.3684E-05 0.3826E-05 CH4,gas 0.9489E+00 0.9878 0.1966E+02 0.1990E+02 H2,gas 0.7169E-03 1.0112 0.1520E-01 0.1503E-01 H2S,gas 0.1506E-05 0.9228 0.2915E-04 0.3159E-04 S2,gas 0.6580E-26 1.0000 0.1380E-24 0.1380E-24 CO,gas 0.7119E-12 1.0000 0.1493E-10 0.1493E-10 SO3,gas 0.7248E-47 1.0000 0.1520E-45 0.1520E-45 SO2,gas 0.4288E-26 1.0000 0.8993E-25 0.8993E-25 HF,gas 0.5706E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1571E-17 1.0000 0.3295E-16 0.3295E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.002 2 CO2,gas -6.66 -13.79 -7.13 -2.378 0.12179E+05 -5.434 3 CH4,gas 4.54 4.14 -0.41 -0.101 0.69234E+03 1.293 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60053E+04 -1.818 5 H2S,gas -6.23 -12.46 -6.23 -3.117 0.10645E+05 -4.535 6 S2,gas -7.34 -33.89 -26.56 -4.086 0.45349E+05 -24.860 7 CO,gas 3.21 -9.31 -12.52 -3.854 0.21386E+05 -10.826 8 SO3,gas 17.12 -30.40 -47.52 -11.879 0.81134E+05 -45.818 9 SO2,gas 0.83 -25.91 -26.75 -7.132 0.45667E+05 -25.046 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.99 -18.18 -9.091 0.31044E+05 -16.482 12 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.71 -0.236 0.80496E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93658E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41067E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28496E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 38 aragonite 0.97 -0.69 -1.66 -0.553 0.28303E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55913E+04 40 calcite 0.81 -0.69 -1.50 -0.501 0.25661E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52804E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71074E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39698E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68948E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65477E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.83 -1.72 -0.493 0.29451E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65863E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68199E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37138E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.83 -1.28 -0.366 0.21873E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28937E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64129E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28624E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48024E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82172E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41128E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36685E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91149E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40577E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 145 pyrite -21.25 -22.68 -1.43 -0.336 0.24415E+04 146 pyrrhotite -4.26 -5.73 -1.47 -0.490 0.25086E+04 147 pyrrhotiteFe0.875 -6.02 -7.13 -1.11 -0.408 0.18959E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22374E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28664E+03 154 rhodochrosite -0.98 -4.55 -3.57 -1.190 0.60972E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23177E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.06 -4.45 -1.483 0.75978E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27811E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.46988E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90662E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77510E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65442E+04 184 troilite-low -4.41 -5.73 -1.32 -0.440 0.22515E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34150E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66604E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60594E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66174E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68812E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73672E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60361E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58211E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83481E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66549E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.22 -2.24 -0.747 0.38265E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52533E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.0959900 MOLES New total amount of reactant added: 0.0999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0999900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4982E+00 Moles total = -.7087E+01 kg total = -.1277E+00 Activity = 0.9997 Stoichiometric ionic strength = .2932975E-02 Osmotic coef. = 0.9539 True ionic strength = .2461359E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.7278E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10685E-09 -9.9712 0.88573E-10 -10.0527 0.82899E+00 -0.0815 2 H2O 0.99975E+00 -0.0001 0.99975E+00 -0.0001 3 Cl- 0.14532E-02 -2.8377 0.11962E-02 -2.9222 0.82314E+00 -0.0845 4 SO4-- 0.10927E-09 -9.9615 0.53656E-10 -10.2704 0.49105E+00 -0.3089 5 HCO3- 0.22982E-03 -3.6386 0.18950E-03 -3.7224 0.82455E+00 -0.0838 6 HS- 0.49276E-02 -2.3074 0.40568E-02 -2.3918 0.82328E+00 -0.0845 7 Al+++ 0.18751E-28 -28.7270 0.38119E-29 -29.4189 0.20329E+00 -0.6919 8 H4SiO4 0.69578E-03 -3.1575 0.69578E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.20375E-06 -6.6909 0.99184E-07 -7.0036 0.48680E+00 -0.3126 10 Mg++ 0.31899E-10 -10.4962 0.15445E-10 -10.8112 0.48419E+00 -0.3150 11 Fe++ 0.87922E-13 -13.0559 0.42626E-13 -13.3703 0.48481E+00 -0.3144 12 K+ 0.18940E-03 -3.7226 0.15621E-03 -3.8063 0.82478E+00 -0.0837 13 Na+ 0.24042E-01 -1.6190 0.19785E-01 -1.7037 0.82296E+00 -0.0846 14 Mn++ 0.28477E-10 -10.5455 0.13820E-10 -10.8595 0.48528E+00 -0.3140 15 F- 0.97873E-06 -6.0093 0.80369E-06 -6.0949 0.82116E+00 -0.0856 16 HPO4-- 0.33626E-07 -7.4733 0.16515E-07 -7.7821 0.49113E+00 -0.3088 18 HSiO3- 0.89132E-02 -2.0500 0.73368E-02 -2.1345 0.82314E+00 -0.0845 19 Ca(HSiO3)+ 0.20088E-07 -7.6971 0.16572E-07 -7.7806 0.82499E+00 -0.0836 20 Mg(HSiO3)+ 0.38931E-11 -11.4097 0.32117E-11 -11.4933 0.82499E+00 -0.0836 21 NaHSiO3,aq 0.23478E-02 -2.6293 0.23478E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.80104E-16 -16.0963 0.66085E-16 -16.1799 0.82499E+00 -0.0836 24 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.45196E-05 -5.3449 0.37124E-05 -5.4303 0.82140E+00 -0.0854 26 CH4,aq 0.13927E-01 -1.8562 0.13914E-01 -1.8565 0.99909E+00 -0.0004 27 C2H6,aq 0.28608E-08 -8.5435 0.28583E-08 -8.5439 0.99909E+00 -0.0004 28 C3H8,aq 0.13568E-13 -13.8675 0.13556E-13 -13.8679 0.99909E+00 -0.0004 29 C4H10,aq 0.63213E-19 -19.1992 0.63156E-19 -19.1996 0.99909E+00 -0.0004 30 ethanol,aq 0.10501E-15 -15.9788 0.10491E-15 -15.9792 0.99909E+00 -0.0004 31 CO,aq 0.10438E-13 -13.9814 0.10438E-13 -13.9814 0.10000E+01 0.0000 32 CO2,aq 0.35907E-07 -7.4448 0.35874E-07 -7.4452 0.99909E+00 -0.0004 33 CO3-2 0.38151E-03 -3.4185 0.18687E-03 -3.7284 0.48983E+00 -0.3100 34 CaCO3,aq 0.23241E-06 -6.6337 0.23241E-06 -6.6337 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.58155E-09 -9.2354 0.47977E-09 -9.3190 0.82499E+00 -0.0836 36 CaCl+ 0.23273E-09 -9.6332 0.19200E-09 -9.7167 0.82499E+00 -0.0836 37 CaCl2,aq 0.54562E-13 -13.2631 0.54562E-13 -13.2631 0.10000E+01 0.0000 38 CaF+ 0.14107E-11 -11.8506 0.11638E-11 -11.9341 0.82499E+00 -0.0836 39 CaOH+ 0.96714E-07 -7.0145 0.79787E-07 -7.0981 0.82499E+00 -0.0836 40 CaSO4,aq 0.16899E-14 -14.7721 0.16899E-14 -14.7721 0.10000E+01 0.0000 41 HCl,aq 0.19414E-13 -13.7119 0.19414E-13 -13.7119 0.10000E+01 0.0000 45 HF,aq 0.48732E-12 -12.3122 0.48732E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.16064E-18 -18.7941 0.13223E-18 -18.8787 0.82314E+00 -0.0845 48 FeCl+ 0.97825E-16 -16.0095 0.80705E-16 -16.0931 0.82499E+00 -0.0836 51 FeF+ 0.21220E-17 -17.6732 0.17506E-17 -17.7568 0.82499E+00 -0.0836 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.18984E-10 -10.7216 0.15661E-10 -10.8052 0.82499E+00 -0.0836 55 HFeO2- 0.30290E-07 -7.5187 0.24933E-07 -7.6032 0.82314E+00 -0.0845 56 FeO+ 0.13306E-16 -16.8759 0.10978E-16 -16.9595 0.82499E+00 -0.0836 58 FeO2- 0.34775E-09 -9.4587 0.28625E-09 -9.5433 0.82314E+00 -0.0845 59 HFeO2,aq 0.32246E-11 -11.4915 0.32246E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11590E-04 -4.9359 0.11579E-04 -4.9363 0.99909E+00 -0.0004 61 KCl,aq 0.33866E-08 -8.4702 0.33866E-08 -8.4702 0.10000E+01 0.0000 63 KOH,aq 0.75299E-06 -6.1232 0.75299E-06 -6.1232 0.10000E+01 0.0000 64 KSO4- 0.15801E-12 -12.8013 0.13006E-12 -12.8858 0.82314E+00 -0.0845 65 MgCO3,aq 0.90717E-11 -11.0423 0.90717E-11 -11.0423 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.92537E-13 -13.0337 0.76342E-13 -13.1172 0.82499E+00 -0.0836 67 MgCl+ 0.32847E-13 -13.4835 0.27098E-13 -13.5671 0.82499E+00 -0.0836 68 MgF+ 0.81378E-15 -15.0895 0.67135E-15 -15.1730 0.82499E+00 -0.0836 69 MgOH+ 0.83338E-10 -10.0792 0.68753E-10 -10.1627 0.82499E+00 -0.0836 71 MnF+ 0.22676E-15 -15.6444 0.18708E-15 -15.7280 0.82499E+00 -0.0836 72 MnO,aq 0.18238E-08 -8.7390 0.18238E-08 -8.7390 0.10000E+01 0.0000 73 MnOH+ 0.57174E-09 -9.2428 0.47168E-09 -9.3264 0.82499E+00 -0.0836 74 MnO2-2 0.15747E-10 -10.8028 0.77131E-11 -11.1128 0.48983E+00 -0.3100 75 HMnO2- 0.18183E-09 -9.7403 0.14967E-09 -9.8249 0.82314E+00 -0.0845 78 MnCl+ 0.12339E-12 -12.9087 0.10179E-12 -12.9923 0.82499E+00 -0.0836 79 MnSO4,aq 0.21407E-18 -18.6695 0.21407E-18 -18.6695 0.10000E+01 0.0000 80 NaCl,aq 0.78431E-05 -5.1055 0.78431E-05 -5.1055 0.10000E+01 0.0000 81 NaF,aq 0.37228E-08 -8.4291 0.37228E-08 -8.4291 0.10000E+01 0.0000 82 NaOH,aq 0.95950E-04 -4.0180 0.95950E-04 -4.0180 0.10000E+01 0.0000 84 OH- 0.79395E-02 -2.1002 0.65215E-02 -2.1857 0.82140E+00 -0.0854 89 HPO3-2 0.12170E-14 -14.9147 0.59609E-15 -15.2247 0.48983E+00 -0.3100 91 H2PO3- 0.12862E-18 -18.8907 0.10588E-18 -18.9752 0.82314E+00 -0.0845 92 H3PO4,aq 0.90615E-18 -18.0428 0.90615E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.32745E-10 -10.4848 0.26984E-10 -10.5689 0.82406E+00 -0.0840 94 PO4-3 0.70643E-09 -9.1509 0.15213E-09 -9.8178 0.21534E+00 -0.6669 98 HP2O7-3 0.63250E-18 -18.1989 0.12874E-18 -18.8903 0.20354E+00 -0.6913 99 P2O7-4 0.56231E-17 -17.2500 0.34724E-18 -18.4594 0.61751E-01 -1.2094 100 H2S,aq 0.11115E-05 -5.9541 0.11105E-05 -5.9545 0.99909E+00 -0.0004 101 S2-2 0.64293E-10 -10.1918 0.31492E-10 -10.5018 0.48983E+00 -0.3100 102 S3-2 0.83072E-17 -17.0805 0.40691E-17 -17.3905 0.48983E+00 -0.3100 107 SO3-2 0.16212E-15 -15.7902 0.80759E-16 -16.0928 0.49814E+00 -0.3026 108 HSO3- 0.54410E-18 -18.2643 0.44787E-18 -18.3488 0.82314E+00 -0.0845 109 HSO4- 0.55453E-17 -17.2561 0.45801E-17 -17.3391 0.82594E+00 -0.0831 111 S2O3-2 0.14293E-17 -17.8449 0.70013E-18 -18.1548 0.48983E+00 -0.3100 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1068455E-09 -.1969893E-01 -.1981252E+02 0.0000 2 H2O 0.1000000E+01 0.5551897E+02 0.9980337E+06 0.0000 3 Cl- 0.1453168E-02 0.1461015E-02 0.5168563E+02 7.1305 4 SO4-- 0.1092683E-09 -.1392956E-01 -.1335210E+04 9.8350 5 HCO3- 0.2298219E-03 0.1453827E-01 0.8851713E+03 6.3303 6 HS- 0.4927575E-02 0.1885825E-01 0.6223349E+03 7.6609 7 Al+++ 0.1875137E-28 0.4519775E-05 0.1216873E+00 0.7392 8 H4SiO4 0.6957841E-03 0.1195679E-01 0.1146753E+04 -3.1575 9 Ca++ 0.2037460E-06 0.5537726E-06 0.2214623E-01 13.1018 10 Mg++ 0.3189942E-10 0.1283289E-09 0.3113202E-05 9.2942 11 Fe++ 0.8792250E-13 0.3087116E-07 0.1720343E-02 6.7351 12 K+ 0.1894002E-03 0.1901566E-03 0.7419466E+01 6.2464 13 Na+ 0.2404191E-01 0.2649350E-01 0.6077666E+03 8.3490 14 Mn++ 0.2847737E-10 0.2621710E-08 0.1437208E-03 9.2459 15 F- 0.9787326E-06 0.9824573E-06 0.1862447E-01 3.9578 16 HPO4-- 0.3362600E-07 0.3436518E-07 0.3291222E-02 12.3233 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278178E+02 -.9813168E-02 -.8277197E+02 0.0000000E+00 2 H2O -.7086927E+01 0.2765719E+02 -.3474411E+02 0.0000000E+00 3 Cl- 0.7278152E-03 0.7278152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1390700E+00 -.6939115E-02 0.1460091E+00 0.0000000E+00 5 HCO3- 0.7242347E-02 0.7242347E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1366147E+00 0.9394377E-02 -.1460091E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2251559E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5956364E-02 0.5205795E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2758659E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6392797E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1537869E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9472790E-04 0.1061476E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1319793E-01 0.6263179E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1306024E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4009600E-04 0.4894183E-06 0.3960658E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1711927E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.5863E-14 Mass of aqueous solution: 0.499234E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.250 0.796 1639. 3.215 30.00 629.1 andradite 0.5840 -0.234 296.8 2.472 5.433 77.11 grossular 0.1415 -0.849 63.72 1.804 1.166 17.73 apatite-OH 0.9823E-02 -2.008 4.934 0.693 0.9033E-01 1.568 apatite-F 0.3961E-04 -4.402 0.1997E-01 -1.700 0.3657E-03 0.6240E-02 clinochlore 0.7033 -0.153 390.9 2.592 7.156 148.7 daphnite 0.2036 -0.691 145.3 2.162 2.660 44.03 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.6973E-01 -1.157 15.10 1.179 0.2765 4.615 hedenbergite 0.1809E-01 -1.743 4.488 0.652 0.8215E-01 1.229 microcline 0.9386 -0.028 261.2 2.417 4.783 102.0 stilbite 3.226 0.509 2274. 3.357 41.62 1060. stilpnomelane-Fe 0.2458 -0.609 265.0 2.423 4.851 91.52 tr.625ac.25prg.125 0.1054 -0.977 90.10 1.955 1.650 29.00 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1876E-01 0.1876E-01 1.0000 -1.727 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.363711 g Volume = 2211.054870 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0999900 moles log = -1.0000 Original solution: 1000.0103000 g Original solution / Rock added: 10001.10 (Water/Rock Ratio), log = 4.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 21.8170 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4851E-01 0.9502 0.1006E+01 0.1058E+01 CO2,gas 0.1830E-06 0.9613 0.3838E-05 0.3993E-05 CH4,gas 0.9508E+00 0.9873 0.2048E+02 0.2074E+02 H2,gas 0.6888E-03 1.0117 0.1520E-01 0.1503E-01 H2S,gas 0.1521E-05 0.9199 0.3053E-04 0.3319E-04 S2,gas 0.6938E-26 1.0000 0.1514E-24 0.1514E-24 CO,gas 0.7130E-12 1.0000 0.1555E-10 0.1555E-10 SO3,gas 0.7297E-47 1.0000 0.1592E-45 0.1592E-45 SO2,gas 0.4317E-26 1.0000 0.9418E-25 0.9418E-25 HF,gas 0.5484E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1570E-17 1.0000 0.3426E-16 0.3426E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28967E+04 0.002 2 CO2,gas -6.66 -13.77 -7.11 -2.372 0.12148E+05 -5.416 3 CH4,gas 4.54 4.16 -0.39 -0.097 0.66187E+03 1.311 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60053E+04 -1.818 5 H2S,gas -6.23 -12.44 -6.21 -3.107 0.10611E+05 -4.515 6 S2,gas -7.34 -33.85 -26.52 -4.080 0.45280E+05 -24.820 7 CO,gas 3.21 -9.29 -12.51 -3.848 0.21356E+05 -10.808 8 SO3,gas 17.12 -30.38 -47.50 -11.874 0.81100E+05 -45.798 9 SO2,gas 0.83 -25.89 -26.72 -7.127 0.45632E+05 -25.026 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.97 -18.16 -9.082 0.31015E+05 -16.465 12 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.71 -0.236 0.80486E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93660E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41067E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28497E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75898E+04 38 aragonite 0.97 -0.67 -1.64 -0.547 0.27999E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55913E+04 40 calcite 0.81 -0.67 -1.49 -0.495 0.25356E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52804E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71074E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39698E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68948E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65474E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13340E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.81 -1.71 -0.488 0.29146E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65863E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68199E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57036E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37138E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.81 -1.26 -0.361 0.21568E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64129E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58874E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28625E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48024E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82169E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41128E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36685E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91148E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40577E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 145 pyrite -21.25 -22.64 -1.39 -0.327 0.23729E+04 146 pyrrhotite -4.26 -5.71 -1.45 -0.483 0.24743E+04 147 pyrrhotiteFe0.875 -6.02 -7.11 -1.09 -0.401 0.18616E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22371E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84954E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28664E+03 154 rhodochrosite -0.98 -4.53 -3.55 -1.184 0.60664E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23174E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.04 -4.43 -1.477 0.75673E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27812E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.46982E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90661E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77510E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65442E+04 184 troilite-low -4.41 -5.71 -1.30 -0.433 0.22172E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34150E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66604E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60594E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66174E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68812E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73671E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60361E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58211E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83481E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66549E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35289E+04 234 alabandite -0.98 -3.20 -2.22 -0.740 0.37919E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52533E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.0999900 MOLES New total amount of reactant added: 0.1039900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1039900 Water: Moles liquid = 0.2766E+02 kg liquid = 0.4982E+00 Moles total = -.7084E+01 kg total = -.1276E+00 Activity = 0.9997 Stoichiometric ionic strength = .2589136E-02 Osmotic coef. = 0.9564 True ionic strength = .2479532E-01 Chg. balance for total moles = -.8663E-10 Max. difference allowed = 0.7514E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10760E-09 -9.9682 0.89152E-10 -10.0499 0.82857E+00 -0.0817 2 H2O 0.99974E+00 -0.0001 0.99974E+00 -0.0001 3 Cl- 0.15000E-02 -2.8239 0.12341E-02 -2.9087 0.82270E+00 -0.0848 4 SO4-- 0.11301E-09 -9.9469 0.55381E-10 -10.2566 0.49004E+00 -0.3098 5 HCO3- 0.23766E-03 -3.6241 0.19586E-03 -3.7081 0.82412E+00 -0.0840 6 HS- 0.51219E-02 -2.2906 0.42145E-02 -2.3753 0.82284E+00 -0.0847 7 Al+++ 0.19212E-28 -28.7164 0.38872E-29 -29.4104 0.20233E+00 -0.6939 8 H4SiO4 0.69578E-03 -3.1575 0.69578E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.20685E-06 -6.6843 0.10048E-06 -6.9979 0.48578E+00 -0.3136 10 Mg++ 0.32387E-10 -10.4896 0.15648E-10 -10.8055 0.48315E+00 -0.3159 11 Fe++ 0.89266E-13 -13.0493 0.43185E-13 -13.3647 0.48378E+00 -0.3154 12 K+ 0.19073E-03 -3.7196 0.15723E-03 -3.8035 0.82435E+00 -0.0839 13 Na+ 0.24211E-01 -1.6160 0.19914E-01 -1.7008 0.82251E+00 -0.0849 14 Mn++ 0.28924E-10 -10.5387 0.14006E-10 -10.8537 0.48425E+00 -0.3149 15 F- 0.97290E-06 -6.0119 0.79847E-06 -6.0977 0.82071E+00 -0.0858 16 HPO4-- 0.33259E-07 -7.4781 0.16301E-07 -7.7878 0.49012E+00 -0.3097 18 HSiO3- 0.88601E-02 -2.0526 0.72892E-02 -2.1373 0.82270E+00 -0.0848 19 Ca(HSiO3)+ 0.20230E-07 -7.6940 0.16681E-07 -7.7778 0.82455E+00 -0.0838 20 Mg(HSiO3)+ 0.39206E-11 -11.4067 0.32327E-11 -11.4904 0.82455E+00 -0.0838 21 NaHSiO3,aq 0.23477E-02 -2.6294 0.23477E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.80671E-16 -16.0933 0.66517E-16 -16.1771 0.82455E+00 -0.0838 24 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.44928E-05 -5.3475 0.36883E-05 -5.4332 0.82095E+00 -0.0857 26 CH4,aq 0.14486E-01 -1.8390 0.14475E-01 -1.8394 0.99920E+00 -0.0003 27 C2H6,aq 0.30957E-08 -8.5092 0.30932E-08 -8.5096 0.99920E+00 -0.0003 28 C3H8,aq 0.15273E-13 -13.8161 0.15261E-13 -13.8164 0.99920E+00 -0.0003 29 C4H10,aq 0.74025E-19 -19.1306 0.73966E-19 -19.1310 0.99920E+00 -0.0003 30 ethanol,aq 0.11362E-15 -15.9445 0.11353E-15 -15.9449 0.99920E+00 -0.0003 31 CO,aq 0.10859E-13 -13.9642 0.10859E-13 -13.9642 0.10000E+01 0.0000 32 CO2,aq 0.37350E-07 -7.4277 0.37320E-07 -7.4281 0.99920E+00 -0.0003 33 CO3-2 0.39256E-03 -3.4061 0.19189E-03 -3.7169 0.48881E+00 -0.3109 34 CaCO3,aq 0.24177E-06 -6.6166 0.24177E-06 -6.6166 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.60926E-09 -9.2152 0.50237E-09 -9.2990 0.82455E+00 -0.0838 36 CaCl+ 0.24338E-09 -9.6137 0.20068E-09 -9.6975 0.82455E+00 -0.0838 37 CaCl2,aq 0.58836E-13 -13.2304 0.58836E-13 -13.2304 0.10000E+01 0.0000 38 CaF+ 0.14207E-11 -11.8475 0.11714E-11 -11.9313 0.82455E+00 -0.0838 39 CaOH+ 0.97396E-07 -7.0115 0.80308E-07 -7.0952 0.82455E+00 -0.0838 40 CaSO4,aq 0.17671E-14 -14.7527 0.17671E-14 -14.7527 0.10000E+01 0.0000 41 HCl,aq 0.20161E-13 -13.6955 0.20161E-13 -13.6955 0.10000E+01 0.0000 45 HF,aq 0.48731E-12 -12.3122 0.48731E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.15968E-18 -18.7967 0.13137E-18 -18.8815 0.82270E+00 -0.0848 48 FeCl+ 0.10230E-15 -15.9901 0.84354E-16 -16.0739 0.82455E+00 -0.0838 51 FeF+ 0.21370E-17 -17.6702 0.17621E-17 -17.7540 0.82455E+00 -0.0838 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.19118E-10 -10.7186 0.15764E-10 -10.8023 0.82455E+00 -0.0838 55 HFeO2- 0.30109E-07 -7.5213 0.24771E-07 -7.6061 0.82270E+00 -0.0848 56 FeO+ 0.13400E-16 -16.8729 0.11049E-16 -16.9567 0.82455E+00 -0.0838 58 FeO2- 0.34568E-09 -9.4613 0.28439E-09 -9.5461 0.82270E+00 -0.0848 59 HFeO2,aq 0.32246E-11 -11.4915 0.32246E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11589E-04 -4.9360 0.11579E-04 -4.9363 0.99920E+00 -0.0003 61 KCl,aq 0.35167E-08 -8.4539 0.35167E-08 -8.4539 0.10000E+01 0.0000 63 KOH,aq 0.75296E-06 -6.1232 0.75296E-06 -6.1232 0.10000E+01 0.0000 64 KSO4- 0.16424E-12 -12.7845 0.13512E-12 -12.8693 0.82270E+00 -0.0848 65 MgCO3,aq 0.94372E-11 -11.0252 0.94372E-11 -11.0252 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.96946E-13 -13.0135 0.79937E-13 -13.0973 0.82455E+00 -0.0838 67 MgCl+ 0.34350E-13 -13.4641 0.28324E-13 -13.5479 0.82455E+00 -0.0838 68 MgF+ 0.81951E-15 -15.0864 0.67573E-15 -15.1702 0.82455E+00 -0.0838 69 MgOH+ 0.83925E-10 -10.0761 0.69201E-10 -10.1599 0.82455E+00 -0.0838 71 MnF+ 0.22845E-15 -15.6412 0.18837E-15 -15.7250 0.82455E+00 -0.0838 72 MnO,aq 0.18245E-08 -8.7389 0.18245E-08 -8.7389 0.10000E+01 0.0000 73 MnOH+ 0.57601E-09 -9.2396 0.47495E-09 -9.3234 0.82455E+00 -0.0838 74 MnO2-2 0.15581E-10 -10.8074 0.76162E-11 -11.1183 0.48881E+00 -0.3109 75 HMnO2- 0.18082E-09 -9.7428 0.14876E-09 -9.8275 0.82270E+00 -0.0848 78 MnCl+ 0.12909E-12 -12.8891 0.10644E-12 -12.9729 0.82455E+00 -0.0838 79 MnSO4,aq 0.22393E-18 -18.6499 0.22393E-18 -18.6499 0.10000E+01 0.0000 80 NaCl,aq 0.81443E-05 -5.0891 0.81443E-05 -5.0891 0.10000E+01 0.0000 81 NaF,aq 0.37227E-08 -8.4291 0.37227E-08 -8.4291 0.10000E+01 0.0000 82 NaOH,aq 0.95946E-04 -4.0180 0.95946E-04 -4.0180 0.10000E+01 0.0000 84 OH- 0.78922E-02 -2.1028 0.64791E-02 -2.1885 0.82095E+00 -0.0857 89 HPO3-2 0.12037E-14 -14.9195 0.58838E-15 -15.2303 0.48881E+00 -0.3109 91 H2PO3- 0.12786E-18 -18.8933 0.10519E-18 -18.9780 0.82270E+00 -0.0848 92 H3PO4,aq 0.90615E-18 -18.0428 0.90615E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.32550E-10 -10.4874 0.26809E-10 -10.5717 0.82362E+00 -0.0843 94 PO4-3 0.69581E-09 -9.1575 0.14918E-09 -9.8263 0.21440E+00 -0.6688 98 HP2O7-3 0.62320E-18 -18.2054 0.12625E-18 -18.8988 0.20259E+00 -0.6934 99 P2O7-4 0.55236E-17 -17.2578 0.33831E-18 -18.4707 0.61249E-01 -1.2129 100 H2S,aq 0.11622E-05 -5.9347 0.11612E-05 -5.9351 0.99920E+00 -0.0003 101 S2-2 0.69534E-10 -10.1578 0.33989E-10 -10.4687 0.48881E+00 -0.3109 102 S3-2 0.93948E-17 -17.0271 0.45923E-17 -17.3380 0.48881E+00 -0.3109 107 SO3-2 0.16766E-15 -15.7756 0.83355E-16 -16.0791 0.49716E+00 -0.3035 108 HSO3- 0.56556E-18 -18.2475 0.46529E-18 -18.3323 0.82270E+00 -0.0848 109 HSO4- 0.57639E-17 -17.2393 0.47581E-17 -17.3226 0.82551E+00 -0.0833 111 S2O3-2 0.15459E-17 -17.8108 0.75564E-18 -18.1217 0.48881E+00 -0.3109 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1075969E-09 -.1960935E-01 -.1972208E+02 0.0000 2 H2O 0.1000000E+01 0.5551954E+02 0.9980267E+06 0.0000 3 Cl- 0.1500021E-02 0.1508169E-02 0.5335287E+02 7.1412 4 SO4-- 0.1130127E-09 -.1448900E-01 -.1388811E+04 9.8431 5 HCO3- 0.2376556E-03 0.1511660E-01 0.9203675E+03 6.3418 6 HS- 0.5121895E-02 0.1961206E-01 0.6471999E+03 7.6746 7 Al+++ 0.1921202E-28 0.4492918E-05 0.1209621E+00 0.7392 8 H4SiO4 0.6957763E-03 0.1190360E-01 0.1141632E+04 -3.1575 9 Ca++ 0.2068528E-06 0.5671062E-06 0.2267907E-01 13.1018 10 Mg++ 0.3238679E-10 0.1298031E-09 0.3148913E-05 9.2942 11 Fe++ 0.8926594E-13 0.3068840E-07 0.1710129E-02 6.7351 12 K+ 0.1907318E-03 0.1914883E-03 0.7471296E+01 6.2464 13 Na+ 0.2421125E-01 0.2666306E-01 0.6116457E+03 8.3490 14 Mn++ 0.2892375E-10 0.2625962E-08 0.1439514E-03 9.2461 15 F- 0.9729046E-06 0.9766291E-06 0.1851366E-01 3.9521 16 HPO4-- 0.3325940E-07 0.3398776E-07 0.3255020E-02 12.3120 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278135E+02 -.9769970E-02 -.8277158E+02 0.0000000E+00 2 H2O -.7083652E+01 0.2766151E+02 -.3474516E+02 0.0000000E+00 3 Cl- 0.7514152E-03 0.7514152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1390891E+00 -.7218857E-02 0.1463079E+00 0.0000000E+00 5 HCO3- 0.7531547E-02 0.7531547E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1365366E+00 0.9771318E-02 -.1463079E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2238507E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5930731E-02 0.5205797E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2825494E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6467182E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1528989E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9540523E-04 0.1061476E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1328434E-01 0.6263093E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1308333E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4169600E-04 0.4865861E-06 0.4120941E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1693373E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1998E-13 Mass of aqueous solution: 0.499316E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1039900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.250 0.796 1639. 3.215 30.00 629.1 andradite 0.5852 -0.233 297.4 2.473 5.445 77.27 grossular 0.1417 -0.848 63.85 1.805 1.169 17.77 apatite-OH 0.9821E-02 -2.008 4.933 0.693 0.9032E-01 1.568 apatite-F 0.4121E-04 -4.385 0.2078E-01 -1.682 0.3805E-03 0.6492E-02 clinochlore 0.7030 -0.153 390.7 2.592 7.153 148.6 daphnite 0.2036 -0.691 145.2 2.162 2.659 44.01 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.6194E-01 -1.208 13.41 1.128 0.2456 4.100 hedenbergite 0.1607E-01 -1.794 3.986 0.601 0.7298E-01 1.092 microcline 0.9389 -0.027 261.3 2.417 4.784 102.1 stilbite 3.227 0.509 2274. 3.357 41.63 1061. stilpnomelane-Fe 0.2452 -0.611 264.3 2.422 4.838 91.29 tr.625ac.25prg.125 0.1080 -0.967 92.27 1.965 1.689 29.70 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1877E-01 0.1877E-01 1.0000 -1.727 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.364531 g Volume = 2211.066015 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1039900 moles log = -0.9830 Original solution: 1000.0103000 g Original solution / Rock added: 9616.41 (Water/Rock Ratio), log = 3.9830 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 22.6650 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4675E-01 0.9492 0.1006E+01 0.1060E+01 CO2,gas 0.1835E-06 0.9600 0.3993E-05 0.4159E-05 CH4,gas 0.9526E+00 0.9868 0.2131E+02 0.2159E+02 H2,gas 0.6627E-03 1.0122 0.1520E-01 0.1502E-01 H2S,gas 0.1536E-05 0.9169 0.3192E-04 0.3481E-04 S2,gas 0.7302E-26 1.0000 0.1655E-24 0.1655E-24 CO,gas 0.7139E-12 1.0000 0.1618E-10 0.1618E-10 SO3,gas 0.7345E-47 1.0000 0.1665E-45 0.1665E-45 SO2,gas 0.4345E-26 1.0000 0.9849E-25 0.9849E-25 HF,gas 0.5279E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1570E-17 1.0000 0.3557E-16 0.3557E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28967E+04 0.002 2 CO2,gas -6.66 -13.76 -7.10 -2.366 0.12119E+05 -5.399 3 CH4,gas 4.54 4.17 -0.37 -0.093 0.63258E+03 1.328 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60053E+04 -1.818 5 H2S,gas -6.23 -12.43 -6.19 -3.097 0.10578E+05 -4.496 6 S2,gas -7.34 -33.82 -26.48 -4.074 0.45214E+05 -24.781 7 CO,gas 3.21 -9.28 -12.49 -3.843 0.21326E+05 -10.791 8 SO3,gas 17.12 -30.36 -47.48 -11.869 0.81067E+05 -45.779 9 SO2,gas 0.83 -25.87 -26.71 -7.121 0.45599E+05 -25.007 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.96 -18.15 -9.074 0.30987E+05 -16.449 12 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.71 -0.236 0.80477E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93661E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41067E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28497E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75898E+04 38 aragonite 0.97 -0.66 -1.62 -0.541 0.27706E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55913E+04 40 calcite 0.81 -0.66 -1.47 -0.489 0.25063E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52805E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71075E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39699E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68949E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65471E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13339E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.79 -1.69 -0.483 0.28853E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65863E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68199E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57037E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37138E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.79 -1.25 -0.356 0.21275E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64129E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59829E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58875E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28625E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48024E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82166E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41128E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36685E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91148E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40577E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 145 pyrite -21.25 -22.60 -1.35 -0.318 0.23067E+04 146 pyrrhotite -4.26 -5.69 -1.43 -0.477 0.24412E+04 147 pyrrhotiteFe0.875 -6.02 -7.09 -1.07 -0.394 0.18284E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22368E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84953E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28663E+03 154 rhodochrosite -0.98 -4.51 -3.54 -1.179 0.60368E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23171E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.02 -4.41 -1.472 0.75380E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27812E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.46976E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90661E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77511E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65442E+04 184 troilite-low -4.41 -5.69 -1.28 -0.426 0.21840E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34150E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66604E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60593E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66174E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73671E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58211E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83481E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66549E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53290E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35290E+04 234 alabandite -0.98 -3.18 -2.20 -0.734 0.37585E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52533E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1039900 MOLES New total amount of reactant added: 0.1079900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1079900 Water: Moles liquid = 0.2766E+02 kg liquid = 0.4983E+00 Moles total = -.7080E+01 kg total = -.1276E+00 Activity = 0.9997 Stoichiometric ionic strength = .2245118E-02 Osmotic coef. = 0.9592 True ionic strength = .2497718E-01 Chg. balance for total moles = -.8663E-10 Max. difference allowed = 0.7750E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10835E-09 -9.9652 0.89732E-10 -10.0471 0.82817E+00 -0.0819 2 H2O 0.99973E+00 -0.0001 0.99973E+00 -0.0001 3 Cl- 0.15469E-02 -2.8105 0.12719E-02 -2.8955 0.82226E+00 -0.0850 4 SO4-- 0.11672E-09 -9.9329 0.57079E-10 -10.2435 0.48903E+00 -0.3107 5 HCO3- 0.24540E-03 -3.6101 0.20213E-03 -3.6944 0.82369E+00 -0.0842 6 HS- 0.53162E-02 -2.2744 0.43720E-02 -2.3593 0.82240E+00 -0.0849 7 Al+++ 0.19682E-28 -28.7059 0.39636E-29 -29.4019 0.20138E+00 -0.6960 8 H4SiO4 0.69577E-03 -3.1575 0.69577E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.20999E-06 -6.6778 0.10180E-06 -6.9923 0.48476E+00 -0.3145 10 Mg++ 0.32879E-10 -10.4831 0.15852E-10 -10.7999 0.48213E+00 -0.3168 11 Fe++ 0.90624E-13 -13.0428 0.43749E-13 -13.3590 0.48275E+00 -0.3163 12 K+ 0.19207E-03 -3.7165 0.15825E-03 -3.8007 0.82391E+00 -0.0841 13 Na+ 0.24381E-01 -1.6129 0.20043E-01 -1.6980 0.82207E+00 -0.0851 14 Mn++ 0.29375E-10 -10.5320 0.14195E-10 -10.8479 0.48323E+00 -0.3158 15 F- 0.96714E-06 -6.0145 0.79330E-06 -6.1006 0.82026E+00 -0.0860 16 HPO4-- 0.32899E-07 -7.4828 0.16091E-07 -7.7934 0.48912E+00 -0.3106 18 HSiO3- 0.88075E-02 -2.0551 0.72421E-02 -2.1401 0.82226E+00 -0.0850 19 Ca(HSiO3)+ 0.20372E-07 -7.6910 0.16789E-07 -7.7750 0.82413E+00 -0.0840 20 Mg(HSiO3)+ 0.39481E-11 -11.4036 0.32537E-11 -11.4876 0.82413E+00 -0.0840 21 NaHSiO3,aq 0.23476E-02 -2.6294 0.23476E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.81239E-16 -16.0902 0.66951E-16 -16.1742 0.82413E+00 -0.0840 24 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.44662E-05 -5.3501 0.36645E-05 -5.4360 0.82050E+00 -0.0859 26 CH4,aq 0.15046E-01 -1.8226 0.15035E-01 -1.8229 0.99931E+00 -0.0003 27 C2H6,aq 0.33399E-08 -8.4763 0.33375E-08 -8.4766 0.99931E+00 -0.0003 28 C3H8,aq 0.17116E-13 -13.7666 0.17105E-13 -13.7669 0.99931E+00 -0.0003 29 C4H10,aq 0.86174E-19 -19.0646 0.86114E-19 -19.0649 0.99931E+00 -0.0003 30 ethanol,aq 0.12259E-15 -15.9116 0.12250E-15 -15.9119 0.99931E+00 -0.0003 31 CO,aq 0.11279E-13 -13.9477 0.11279E-13 -13.9477 0.10000E+01 0.0000 32 CO2,aq 0.38793E-07 -7.4112 0.38767E-07 -7.4115 0.99931E+00 -0.0003 33 CO3-2 0.40336E-03 -3.3943 0.19676E-03 -3.7061 0.48780E+00 -0.3118 34 CaCO3,aq 0.25114E-06 -6.6001 0.25114E-06 -6.6001 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.63732E-09 -9.1956 0.52523E-09 -9.2797 0.82413E+00 -0.0840 36 CaCl+ 0.25425E-09 -9.5947 0.20953E-09 -9.6787 0.82413E+00 -0.0840 37 CaCl2,aq 0.63317E-13 -13.1985 0.63317E-13 -13.1985 0.10000E+01 0.0000 38 CaF+ 0.14306E-11 -11.8445 0.11790E-11 -11.9285 0.82413E+00 -0.0840 39 CaOH+ 0.98079E-07 -7.0084 0.80829E-07 -7.0924 0.82413E+00 -0.0840 40 CaSO4,aq 0.18451E-14 -14.7340 0.18451E-14 -14.7340 0.10000E+01 0.0000 41 HCl,aq 0.20914E-13 -13.6796 0.20914E-13 -13.6796 0.10000E+01 0.0000 45 HF,aq 0.48731E-12 -12.3122 0.48731E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.15873E-18 -18.7993 0.13052E-18 -18.8843 0.82226E+00 -0.0850 48 FeCl+ 0.10687E-15 -15.9711 0.88077E-16 -16.0551 0.82413E+00 -0.0840 51 FeF+ 0.21520E-17 -17.6672 0.17735E-17 -17.7512 0.82413E+00 -0.0840 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.19252E-10 -10.7155 0.15866E-10 -10.7995 0.82413E+00 -0.0840 55 HFeO2- 0.29930E-07 -7.5239 0.24610E-07 -7.6089 0.82226E+00 -0.0850 56 FeO+ 0.13495E-16 -16.8698 0.11121E-16 -16.9538 0.82413E+00 -0.0840 58 FeO2- 0.34362E-09 -9.4639 0.28255E-09 -9.5489 0.82226E+00 -0.0850 59 HFeO2,aq 0.32246E-11 -11.4915 0.32246E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11587E-04 -4.9360 0.11579E-04 -4.9363 0.99931E+00 -0.0003 61 KCl,aq 0.36480E-08 -8.4379 0.36480E-08 -8.4379 0.10000E+01 0.0000 63 KOH,aq 0.75293E-06 -6.1232 0.75293E-06 -6.1232 0.10000E+01 0.0000 64 KSO4- 0.17046E-12 -12.7684 0.14016E-12 -12.8534 0.82226E+00 -0.0850 65 MgCO3,aq 0.98029E-11 -11.0086 0.98029E-11 -11.0086 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10141E-12 -12.9939 0.83575E-13 -13.0779 0.82413E+00 -0.0840 67 MgCl+ 0.35884E-13 -13.4451 0.29573E-13 -13.5291 0.82413E+00 -0.0840 68 MgF+ 0.82526E-15 -15.0834 0.68012E-15 -15.1674 0.82413E+00 -0.0840 69 MgOH+ 0.84514E-10 -10.0731 0.69650E-10 -10.1571 0.82413E+00 -0.0840 71 MnF+ 0.23015E-15 -15.6380 0.18967E-15 -15.7220 0.82413E+00 -0.0840 72 MnO,aq 0.18252E-08 -8.7387 0.18252E-08 -8.7387 0.10000E+01 0.0000 73 MnOH+ 0.58028E-09 -9.2364 0.47823E-09 -9.3204 0.82413E+00 -0.0840 74 MnO2-2 0.15418E-10 -10.8120 0.75210E-11 -11.1237 0.48780E+00 -0.3118 75 HMnO2- 0.17981E-09 -9.7452 0.14785E-09 -9.8302 0.82226E+00 -0.0850 78 MnCl+ 0.13491E-12 -12.8700 0.11118E-12 -12.9540 0.82413E+00 -0.0840 79 MnSO4,aq 0.23391E-18 -18.6310 0.23391E-18 -18.6310 0.10000E+01 0.0000 80 NaCl,aq 0.84484E-05 -5.0732 0.84484E-05 -5.0732 0.10000E+01 0.0000 81 NaF,aq 0.37225E-08 -8.4292 0.37225E-08 -8.4292 0.10000E+01 0.0000 82 NaOH,aq 0.95943E-04 -4.0180 0.95943E-04 -4.0180 0.10000E+01 0.0000 84 OH- 0.78454E-02 -2.1054 0.64372E-02 -2.1913 0.82050E+00 -0.0859 89 HPO3-2 0.11907E-14 -14.9242 0.58081E-15 -15.2360 0.48780E+00 -0.3118 91 H2PO3- 0.12710E-18 -18.8959 0.10451E-18 -18.9808 0.82226E+00 -0.0850 92 H3PO4,aq 0.90616E-18 -18.0428 0.90616E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.32357E-10 -10.4900 0.26636E-10 -10.5745 0.82318E+00 -0.0845 94 PO4-3 0.68540E-09 -9.1641 0.14631E-09 -9.8347 0.21347E+00 -0.6707 98 HP2O7-3 0.61408E-18 -18.2118 0.12382E-18 -18.9072 0.20164E+00 -0.6954 99 P2O7-4 0.54263E-17 -17.2655 0.32966E-18 -18.4819 0.60753E-01 -1.2164 100 H2S,aq 0.12133E-05 -5.9160 0.12125E-05 -5.9163 0.99931E+00 -0.0003 101 S2-2 0.74985E-10 -10.1250 0.36578E-10 -10.4368 0.48780E+00 -0.3118 102 S3-2 0.10578E-16 -16.9756 0.51601E-17 -17.2873 0.48780E+00 -0.3118 107 SO3-2 0.17315E-15 -15.7616 0.85912E-16 -16.0659 0.49618E+00 -0.3044 108 HSO3- 0.58701E-18 -18.2314 0.48268E-18 -18.3163 0.82226E+00 -0.0850 109 HSO4- 0.59824E-17 -17.2231 0.49360E-17 -17.3066 0.82509E+00 -0.0835 111 S2O3-2 0.16670E-17 -17.7781 0.81319E-18 -18.0898 0.48780E+00 -0.3118 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1083500E-09 -.1952059E-01 -.1963247E+02 0.0000 2 H2O 0.1000000E+01 0.5552010E+02 0.9980196E+06 0.0000 3 Cl- 0.1546857E-02 0.1555309E-02 0.5501956E+02 7.1515 4 SO4-- 0.1167187E-09 -.1504861E-01 -.1442426E+04 9.8506 5 HCO3- 0.2453997E-03 0.1569476E-01 0.9555521E+03 6.3527 6 HS- 0.5316157E-02 0.2036598E-01 0.6720679E+03 7.6877 7 Al+++ 0.1968179E-28 0.4466346E-05 0.1202446E+00 0.7393 8 H4SiO4 0.6957685E-03 0.1185097E-01 0.1136565E+04 -3.1575 9 Ca++ 0.2099923E-06 0.5804803E-06 0.2321351E-01 13.1018 10 Mg++ 0.3287931E-10 0.1312832E-09 0.3184762E-05 9.2942 11 Fe++ 0.9062355E-13 0.3050760E-07 0.1700025E-02 6.7351 12 K+ 0.1920664E-03 0.1928230E-03 0.7523244E+01 6.2464 13 Na+ 0.2438097E-01 0.2683301E-01 0.6155337E+03 8.3490 14 Mn++ 0.2937508E-10 0.2630246E-08 0.1441838E-03 9.2462 15 F- 0.9671386E-06 0.9708630E-06 0.1840404E-01 3.9465 16 HPO4-- 0.3289852E-07 0.3361628E-07 0.3219387E-02 12.3007 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278092E+02 -.9727165E-02 -.8277119E+02 0.0000000E+00 2 H2O -.7080377E+01 0.2766583E+02 -.3474621E+02 0.0000000E+00 3 Cl- 0.7750152E-03 0.7750152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1391082E+00 -.7498768E-02 0.1466069E+00 0.0000000E+00 5 HCO3- 0.7820747E-02 0.7820747E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1364585E+00 0.1014843E-01 -.1466069E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2225593E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5905372E-02 0.5205800E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2892550E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6541878E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1520203E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9608426E-04 0.1061475E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1337097E-01 0.6263006E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1310659E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4329600E-04 0.4837839E-06 0.4281222E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1675109E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1153E-13 Mass of aqueous solution: 0.499397E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1079900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.249 0.796 1639. 3.214 30.00 629.0 andradite 0.5864 -0.232 298.0 2.474 5.456 77.43 grossular 0.1420 -0.848 63.98 1.806 1.171 17.80 apatite-OH 0.9820E-02 -2.008 4.933 0.693 0.9030E-01 1.567 apatite-F 0.4281E-04 -4.368 0.2159E-01 -1.666 0.3953E-03 0.6745E-02 clinochlore 0.7027 -0.153 390.6 2.592 7.151 148.6 daphnite 0.2035 -0.691 145.2 2.162 2.658 43.99 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.5415E-01 -1.266 11.73 1.069 0.2147 3.584 hedenbergite 0.1405E-01 -1.852 3.485 0.542 0.6380E-01 0.9545 microcline 0.9392 -0.027 261.4 2.417 4.786 102.1 stilbite 3.227 0.509 2274. 3.357 41.63 1061. stilpnomelane-Fe 0.2445 -0.612 263.6 2.421 4.826 91.05 tr.625ac.25prg.125 0.1105 -0.957 94.44 1.975 1.729 30.40 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1877E-01 0.1877E-01 1.0000 -1.726 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.365339 g Volume = 2211.077165 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1079900 moles log = -0.9666 Original solution: 1000.0103000 g Original solution / Rock added: 9260.21 (Water/Rock Ratio), log = 3.9666 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 23.5142 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4511E-01 0.9482 0.1006E+01 0.1061E+01 CO2,gas 0.1840E-06 0.9587 0.4148E-05 0.4326E-05 CH4,gas 0.9543E+00 0.9863 0.2213E+02 0.2244E+02 H2,gas 0.6385E-03 1.0126 0.1520E-01 0.1501E-01 H2S,gas 0.1551E-05 0.9140 0.3333E-04 0.3647E-04 S2,gas 0.7673E-26 1.0000 0.1804E-24 0.1804E-24 CO,gas 0.7148E-12 1.0000 0.1681E-10 0.1681E-10 SO3,gas 0.7392E-47 1.0000 0.1738E-45 0.1738E-45 SO2,gas 0.4373E-26 1.0000 0.1028E-24 0.1028E-24 HF,gas 0.5088E-16 1.0000 0.1197E-14 0.1197E-14 HCl,gas 0.1569E-17 1.0000 0.3690E-16 0.3690E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.00000E+00 71 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28967E+04 0.002 2 CO2,gas -6.66 -13.74 -7.08 -2.360 0.12091E+05 -5.382 3 CH4,gas 4.54 4.19 -0.35 -0.088 0.60440E+03 1.345 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60053E+04 -1.818 5 H2S,gas -6.23 -12.41 -6.18 -3.088 0.10546E+05 -4.477 6 S2,gas -7.34 -33.78 -26.44 -4.068 0.45150E+05 -24.744 7 CO,gas 3.21 -9.26 -12.47 -3.838 0.21298E+05 -10.774 8 SO3,gas 17.12 -30.34 -47.46 -11.865 0.81035E+05 -45.760 9 SO2,gas 0.83 -25.85 -26.69 -7.116 0.45567E+05 -24.988 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.94 -18.13 -9.066 0.30960E+05 -16.433 12 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.71 -0.236 0.80468E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93663E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41067E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28497E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75898E+04 38 aragonite 0.97 -0.64 -1.61 -0.535 0.27424E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55913E+04 40 calcite 0.81 -0.64 -1.45 -0.484 0.24781E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52805E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71075E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39699E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68949E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70313E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65468E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13339E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.78 -1.67 -0.478 0.28571E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65863E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68199E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57037E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37138E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.78 -1.23 -0.351 0.20993E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64129E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58875E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28625E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48023E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82163E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41128E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36686E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91147E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40577E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 145 pyrite -21.25 -22.56 -1.31 -0.309 0.22427E+04 146 pyrrhotite -4.26 -5.67 -1.41 -0.470 0.24092E+04 147 pyrrhotiteFe0.875 -6.02 -7.07 -1.05 -0.387 0.17964E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22365E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84953E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28662E+03 154 rhodochrosite -0.98 -4.50 -3.52 -1.173 0.60084E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23168E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -7.01 -4.40 -1.466 0.75098E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27812E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.33 -2.75 -0.393 0.46970E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90660E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77512E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65442E+04 184 troilite-low -4.41 -5.67 -1.26 -0.420 0.21520E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34150E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66603E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60592E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66173E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73671E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58211E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83481E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66549E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53289E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35290E+04 234 alabandite -0.98 -3.16 -2.18 -0.727 0.37262E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52533E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1079900 MOLES New total amount of reactant added: 0.1119900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1119900 Water: Moles liquid = 0.2766E+02 kg liquid = 0.4984E+00 Moles total = -.7077E+01 kg total = -.1275E+00 Activity = 0.9997 Stoichiometric ionic strength = .1900932E-02 Osmotic coef. = 0.9621 True ionic strength = .2515918E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.7986E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10910E-09 -9.9622 0.90312E-10 -10.0443 0.82776E+00 -0.0821 2 H2O 0.99972E+00 -0.0001 0.99972E+00 -0.0001 3 Cl- 0.15937E-02 -2.7976 0.13097E-02 -2.8828 0.82182E+00 -0.0852 4 SO4-- 0.12039E-09 -9.9194 0.58753E-10 -10.2310 0.48804E+00 -0.3115 5 HCO3- 0.25306E-03 -3.5968 0.20833E-03 -3.6812 0.82326E+00 -0.0845 6 HS- 0.55104E-02 -2.2588 0.45293E-02 -2.3440 0.82197E+00 -0.0851 7 Al+++ 0.20161E-28 -28.6955 0.40411E-29 -29.3935 0.20044E+00 -0.6980 8 H4SiO4 0.69576E-03 -3.1575 0.69576E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.21316E-06 -6.6713 0.10312E-06 -6.9867 0.48375E+00 -0.3154 10 Mg++ 0.33377E-10 -10.4766 0.16058E-10 -10.7943 0.48110E+00 -0.3178 11 Fe++ 0.91995E-13 -13.0362 0.44317E-13 -13.3534 0.48173E+00 -0.3172 12 K+ 0.19340E-03 -3.7135 0.15927E-03 -3.7979 0.82349E+00 -0.0843 13 Na+ 0.24551E-01 -1.6099 0.20172E-01 -1.6953 0.82164E+00 -0.0853 14 Mn++ 0.29831E-10 -10.5253 0.14385E-10 -10.8421 0.48221E+00 -0.3168 15 F- 0.96143E-06 -6.0171 0.78819E-06 -6.1034 0.81981E+00 -0.0863 16 HPO4-- 0.32543E-07 -7.4875 0.15885E-07 -7.7990 0.48812E+00 -0.3115 18 HSiO3- 0.87555E-02 -2.0577 0.71955E-02 -2.1429 0.82182E+00 -0.0852 19 Ca(HSiO3)+ 0.20514E-07 -7.6879 0.16898E-07 -7.7722 0.82370E+00 -0.0842 20 Mg(HSiO3)+ 0.39757E-11 -11.4006 0.32748E-11 -11.4848 0.82370E+00 -0.0842 21 NaHSiO3,aq 0.23476E-02 -2.6294 0.23476E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.81808E-16 -16.0872 0.67385E-16 -16.1714 0.82370E+00 -0.0842 24 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.44399E-05 -5.3526 0.36410E-05 -5.4388 0.82006E+00 -0.0862 26 CH4,aq 0.15605E-01 -1.8067 0.15596E-01 -1.8070 0.99941E+00 -0.0003 27 C2H6,aq 0.35934E-08 -8.4445 0.35913E-08 -8.4447 0.99941E+00 -0.0003 28 C3H8,aq 0.19103E-13 -13.7189 0.19092E-13 -13.7191 0.99941E+00 -0.0003 29 C4H10,aq 0.99767E-19 -19.0010 0.99709E-19 -19.0013 0.99941E+00 -0.0003 30 ethanol,aq 0.13189E-15 -15.8798 0.13182E-15 -15.8800 0.99941E+00 -0.0003 31 CO,aq 0.11701E-13 -13.9318 0.11701E-13 -13.9318 0.10000E+01 0.0000 32 CO2,aq 0.40238E-07 -7.3954 0.40214E-07 -7.3956 0.99941E+00 -0.0003 33 CO3-2 0.41390E-03 -3.3831 0.20149E-03 -3.6958 0.48680E+00 -0.3126 34 CaCO3,aq 0.26052E-06 -6.5842 0.26052E-06 -6.5842 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.66573E-09 -9.1767 0.54836E-09 -9.2609 0.82370E+00 -0.0842 36 CaCl+ 0.26534E-09 -9.5762 0.21856E-09 -9.6604 0.82370E+00 -0.0842 37 CaCl2,aq 0.68008E-13 -13.1674 0.68008E-13 -13.1674 0.10000E+01 0.0000 38 CaF+ 0.14406E-11 -11.8414 0.11866E-11 -11.9257 0.82370E+00 -0.0842 39 CaOH+ 0.98764E-07 -7.0054 0.81352E-07 -7.0896 0.82370E+00 -0.0842 40 CaSO4,aq 0.19238E-14 -14.7158 0.19238E-14 -14.7158 0.10000E+01 0.0000 41 HCl,aq 0.21675E-13 -13.6640 0.21675E-13 -13.6640 0.10000E+01 0.0000 45 HF,aq 0.48730E-12 -12.3122 0.48730E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.15779E-18 -18.8019 0.12968E-18 -18.8871 0.82182E+00 -0.0852 48 FeCl+ 0.11154E-15 -15.9526 0.91873E-16 -16.0368 0.82370E+00 -0.0842 51 FeF+ 0.21671E-17 -17.6641 0.17850E-17 -17.7484 0.82370E+00 -0.0842 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.19387E-10 -10.7125 0.15969E-10 -10.7967 0.82370E+00 -0.0842 55 HFeO2- 0.29753E-07 -7.5265 0.24452E-07 -7.6117 0.82182E+00 -0.0852 56 FeO+ 0.13589E-16 -16.8668 0.11193E-16 -16.9510 0.82370E+00 -0.0842 58 FeO2- 0.34159E-09 -9.4665 0.28073E-09 -9.5517 0.82182E+00 -0.0852 59 HFeO2,aq 0.32246E-11 -11.4915 0.32246E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11586E-04 -4.9361 0.11579E-04 -4.9363 0.99941E+00 -0.0003 61 KCl,aq 0.37806E-08 -8.4224 0.37806E-08 -8.4224 0.10000E+01 0.0000 63 KOH,aq 0.75290E-06 -6.1233 0.75290E-06 -6.1233 0.10000E+01 0.0000 64 KSO4- 0.17668E-12 -12.7528 0.14520E-12 -12.8380 0.82182E+00 -0.0852 65 MgCO3,aq 0.10169E-10 -10.9927 0.10169E-10 -10.9927 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.10593E-12 -12.9750 0.87256E-13 -13.0592 0.82370E+00 -0.0842 67 MgCl+ 0.37450E-13 -13.4265 0.30847E-13 -13.5108 0.82370E+00 -0.0842 68 MgF+ 0.83102E-15 -15.0804 0.68451E-15 -15.1646 0.82370E+00 -0.0842 69 MgOH+ 0.85105E-10 -10.0700 0.70100E-10 -10.1543 0.82370E+00 -0.0842 71 MnF+ 0.23185E-15 -15.6348 0.19098E-15 -15.7190 0.82370E+00 -0.0842 72 MnO,aq 0.18259E-08 -8.7385 0.18259E-08 -8.7385 0.10000E+01 0.0000 73 MnOH+ 0.58457E-09 -9.2332 0.48151E-09 -9.3174 0.82370E+00 -0.0842 74 MnO2-2 0.15258E-10 -10.8165 0.74275E-11 -11.1292 0.48680E+00 -0.3126 75 HMnO2- 0.17882E-09 -9.7476 0.14696E-09 -9.8328 0.82182E+00 -0.0852 78 MnCl+ 0.14085E-12 -12.8512 0.11602E-12 -12.9355 0.82370E+00 -0.0842 79 MnSO4,aq 0.24399E-18 -18.6126 0.24399E-18 -18.6126 0.10000E+01 0.0000 80 NaCl,aq 0.87555E-05 -5.0577 0.87555E-05 -5.0577 0.10000E+01 0.0000 81 NaF,aq 0.37224E-08 -8.4292 0.37224E-08 -8.4292 0.10000E+01 0.0000 82 NaOH,aq 0.95939E-04 -4.0180 0.95939E-04 -4.0180 0.10000E+01 0.0000 84 OH- 0.77991E-02 -2.1080 0.63957E-02 -2.1941 0.82006E+00 -0.0862 89 HPO3-2 0.11778E-14 -14.9289 0.57336E-15 -15.2416 0.48680E+00 -0.3126 91 H2PO3- 0.12635E-18 -18.8984 0.10384E-18 -18.9836 0.82182E+00 -0.0852 92 H3PO4,aq 0.90616E-18 -18.0428 0.90616E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.32166E-10 -10.4926 0.26465E-10 -10.5773 0.82275E+00 -0.0847 94 PO4-3 0.67519E-09 -9.1706 0.14351E-09 -9.8431 0.21254E+00 -0.6726 98 HP2O7-3 0.60513E-18 -18.2182 0.12145E-18 -18.9156 0.20071E+00 -0.6974 99 P2O7-4 0.53311E-17 -17.2732 0.32127E-18 -18.4931 0.60263E-01 -1.2200 100 H2S,aq 0.12650E-05 -5.8979 0.12642E-05 -5.8982 0.99941E+00 -0.0003 101 S2-2 0.80644E-10 -10.0934 0.39258E-10 -10.4061 0.48680E+00 -0.3126 102 S3-2 0.11863E-16 -16.9258 0.57747E-17 -17.2385 0.48680E+00 -0.3126 107 SO3-2 0.17857E-15 -15.7482 0.88431E-16 -16.0534 0.49521E+00 -0.3052 108 HSO3- 0.60846E-18 -18.2158 0.50005E-18 -18.3010 0.82182E+00 -0.0852 109 HSO4- 0.62009E-17 -17.2075 0.51136E-17 -17.2913 0.82466E+00 -0.0837 111 S2O3-2 0.17929E-17 -17.7465 0.87277E-18 -18.0591 0.48680E+00 -0.3126 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1091048E-09 -.1943263E-01 -.1954366E+02 0.0000 2 H2O 0.1000000E+01 0.5552067E+02 0.9980125E+06 0.0000 3 Cl- 0.1593676E-02 0.1602436E-02 0.5668570E+02 7.1614 4 SO4-- 0.1203868E-09 -.1560840E-01 -.1496056E+04 9.8575 5 HCO3- 0.2530555E-03 0.1627276E-01 0.9907253E+03 6.3630 6 HS- 0.5510363E-02 0.2112002E-01 0.6969388E+03 7.7003 7 Al+++ 0.2016080E-28 0.4440056E-05 0.1195348E+00 0.7393 8 H4SiO4 0.6957607E-03 0.1179890E-01 0.1131551E+04 -3.1575 9 Ca++ 0.2131645E-06 0.5938947E-06 0.2374955E-01 13.1018 10 Mg++ 0.3337698E-10 0.1327717E-09 0.3220816E-05 9.2942 11 Fe++ 0.9199541E-13 0.3032872E-07 0.1690027E-02 6.7351 12 K+ 0.1934041E-03 0.1941608E-03 0.7575307E+01 6.2464 13 Na+ 0.2455108E-01 0.2700335E-01 0.6194306E+03 8.3490 14 Mn++ 0.2983139E-10 0.2634562E-08 0.1444179E-03 9.2464 15 F- 0.9614339E-06 0.9651581E-06 0.1829558E-01 3.9409 16 HPO4-- 0.3254324E-07 0.3325060E-07 0.3184312E-02 12.2895 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278049E+02 -.9684748E-02 -.8277080E+02 0.0000000E+00 2 H2O -.7077103E+01 0.2767015E+02 -.3474725E+02 0.0000000E+00 3 Cl- 0.7986152E-03 0.7986152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1391273E+00 -.7778845E-02 0.1469061E+00 0.0000000E+00 5 HCO3- 0.8109947E-02 0.8109947E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1363804E+00 0.1052571E-01 -.1469061E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2212816E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5880284E-02 0.5205802E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2959827E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6617018E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1511510E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9676500E-04 0.1061474E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1345781E-01 0.6262919E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1313002E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4489600E-04 0.4810114E-06 0.4441499E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1657129E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1472E-13 Mass of aqueous solution: 0.499479E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1119900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.249 0.796 1639. 3.214 30.00 629.0 andradite 0.5876 -0.231 298.6 2.475 5.467 77.58 grossular 0.1423 -0.847 64.11 1.807 1.174 17.84 apatite-OH 0.9818E-02 -2.008 4.932 0.693 0.9029E-01 1.567 apatite-F 0.4441E-04 -4.352 0.2240E-01 -1.650 0.4101E-03 0.6997E-02 clinochlore 0.7024 -0.153 390.4 2.592 7.148 148.5 daphnite 0.2034 -0.692 145.1 2.162 2.657 43.98 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.4635E-01 -1.334 10.04 1.002 0.1838 3.068 hedenbergite 0.1202E-01 -1.920 2.983 0.475 0.5461E-01 0.8171 microcline 0.9395 -0.027 261.5 2.417 4.787 102.2 stilbite 3.227 0.509 2274. 3.357 41.63 1061. stilpnomelane-Fe 0.2439 -0.613 262.9 2.420 4.813 90.82 tr.625ac.25prg.125 0.1130 -0.947 96.62 1.985 1.769 31.10 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1878E-01 0.1878E-01 1.0000 -1.726 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.366132 g Volume = 2211.088321 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1119900 moles log = -0.9508 Original solution: 1000.0103000 g Original solution / Rock added: 8929.46 (Water/Rock Ratio), log = 3.9508 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 24.3648 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4358E-01 0.9472 0.1006E+01 0.1062E+01 CO2,gas 0.1844E-06 0.9574 0.4302E-05 0.4494E-05 CH4,gas 0.9558E+00 0.9858 0.2296E+02 0.2329E+02 H2,gas 0.6159E-03 1.0131 0.1520E-01 0.1501E-01 H2S,gas 0.1566E-05 0.9111 0.3475E-04 0.3814E-04 S2,gas 0.8051E-26 1.0000 0.1962E-24 0.1962E-24 CO,gas 0.7156E-12 1.0000 0.1744E-10 0.1744E-10 SO3,gas 0.7439E-47 1.0000 0.1812E-45 0.1812E-45 SO2,gas 0.4401E-26 1.0000 0.1072E-24 0.1072E-24 HF,gas 0.4911E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1570E-17 1.0000 0.3825E-16 0.3825E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.54595E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28967E+04 0.002 2 CO2,gas -6.66 -13.73 -7.07 -2.355 0.12064E+05 -5.366 3 CH4,gas 4.54 4.21 -0.34 -0.085 0.57723E+03 1.361 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60053E+04 -1.818 5 H2S,gas -6.23 -12.39 -6.16 -3.079 0.10515E+05 -4.459 6 S2,gas -7.34 -33.74 -26.41 -4.063 0.45088E+05 -24.707 7 CO,gas 3.21 -9.24 -12.46 -3.833 0.21271E+05 -10.759 8 SO3,gas 17.12 -30.32 -47.44 -11.860 0.81004E+05 -45.742 9 SO2,gas 0.83 -25.84 -26.67 -7.112 0.45536E+05 -24.970 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.93 -18.12 -9.058 0.30933E+05 -16.417 12 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.75 -4.71 -0.236 0.80459E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93664E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41067E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28498E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75898E+04 38 aragonite 0.97 -0.62 -1.59 -0.530 0.27152E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55913E+04 40 calcite 0.81 -0.62 -1.44 -0.478 0.24510E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52805E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71075E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39699E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68950E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65465E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13339E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.76 -1.66 -0.474 0.28299E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65863E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68199E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57037E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37138E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.76 -1.21 -0.347 0.20721E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64129E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58875E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28625E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48023E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82161E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41128E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36686E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91147E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40577E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 145 pyrite -21.25 -22.52 -1.28 -0.300 0.21806E+04 146 pyrrhotite -4.26 -5.65 -1.39 -0.464 0.23782E+04 147 pyrrhotiteFe0.875 -6.02 -7.05 -1.03 -0.380 0.17654E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22362E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84953E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28662E+03 154 rhodochrosite -0.98 -4.48 -3.50 -1.168 0.59809E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23165E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.99 -4.38 -1.461 0.74826E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27812E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.34 -2.75 -0.393 0.46964E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90660E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77512E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65441E+04 184 troilite-low -4.41 -5.65 -1.24 -0.414 0.21210E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34150E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66603E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60592E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66173E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73671E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58210E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83480E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62081E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66549E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53289E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35290E+04 234 alabandite -0.98 -3.14 -2.16 -0.721 0.36949E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52533E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1119900 MOLES New total amount of reactant added: 0.1159900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1159900 Water: Moles liquid = 0.2767E+02 kg liquid = 0.4984E+00 Moles total = -.7074E+01 kg total = -.1274E+00 Activity = 0.9997 Stoichiometric ionic strength = .1556586E-02 Osmotic coef. = 0.9655 True ionic strength = .2534133E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.8222E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10986E-09 -9.9592 0.90894E-10 -10.0415 0.82735E+00 -0.0823 2 H2O 0.99971E+00 -0.0001 0.99971E+00 -0.0001 3 Cl- 0.16405E-02 -2.7850 0.13475E-02 -2.8705 0.82139E+00 -0.0855 4 SO4-- 0.12402E-09 -9.9065 0.60402E-10 -10.2189 0.48705E+00 -0.3124 5 HCO3- 0.26062E-03 -3.5840 0.21445E-03 -3.6687 0.82283E+00 -0.0847 6 HS- 0.57045E-02 -2.2438 0.46864E-02 -2.3292 0.82153E+00 -0.0854 7 Al+++ 0.20649E-28 -28.6851 0.41198E-29 -29.3851 0.19951E+00 -0.7000 8 H4SiO4 0.69575E-03 -3.1575 0.69575E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.21637E-06 -6.6648 0.10445E-06 -6.9811 0.48274E+00 -0.3163 10 Mg++ 0.33880E-10 -10.4701 0.16265E-10 -10.7887 0.48009E+00 -0.3187 11 Fe++ 0.93382E-13 -13.0297 0.44890E-13 -13.3478 0.48072E+00 -0.3181 12 K+ 0.19474E-03 -3.7105 0.16029E-03 -3.7951 0.82306E+00 -0.0846 13 Na+ 0.24722E-01 -1.6069 0.20301E-01 -1.6925 0.82120E+00 -0.0856 14 Mn++ 0.30293E-10 -10.5187 0.14577E-10 -10.8363 0.48120E+00 -0.3177 15 F- 0.95579E-06 -6.0196 0.78314E-06 -6.1062 0.81937E+00 -0.0865 16 HPO4-- 0.32193E-07 -7.4922 0.15682E-07 -7.8046 0.48713E+00 -0.3124 18 HSiO3- 0.87041E-02 -2.0603 0.71494E-02 -2.1457 0.82139E+00 -0.0855 19 Ca(HSiO3)+ 0.20657E-07 -7.6849 0.17007E-07 -7.7694 0.82327E+00 -0.0845 20 Mg(HSiO3)+ 0.40034E-11 -11.3976 0.32959E-11 -11.4820 0.82327E+00 -0.0845 21 NaHSiO3,aq 0.23475E-02 -2.6294 0.23475E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.82378E-16 -16.0842 0.67820E-16 -16.1686 0.82327E+00 -0.0845 24 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.44139E-05 -5.3552 0.36177E-05 -5.4416 0.81961E+00 -0.0864 26 CH4,aq 0.16165E-01 -1.7914 0.16158E-01 -1.7916 0.99952E+00 -0.0002 27 C2H6,aq 0.38564E-08 -8.4138 0.38545E-08 -8.4140 0.99952E+00 -0.0002 28 C3H8,aq 0.21239E-13 -13.6729 0.21229E-13 -13.6731 0.99952E+00 -0.0002 29 C4H10,aq 0.11492E-18 -18.9396 0.11486E-18 -18.9398 0.99952E+00 -0.0002 30 ethanol,aq 0.14155E-15 -15.8491 0.14148E-15 -15.8493 0.99952E+00 -0.0002 31 CO,aq 0.12122E-13 -13.9164 0.12122E-13 -13.9164 0.10000E+01 0.0000 32 CO2,aq 0.41683E-07 -7.3800 0.41662E-07 -7.3803 0.99952E+00 -0.0002 33 CO3-2 0.42420E-03 -3.3724 0.20608E-03 -3.6860 0.48581E+00 -0.3135 34 CaCO3,aq 0.26990E-06 -6.5688 0.26990E-06 -6.5688 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.69450E-09 -9.1583 0.57177E-09 -9.2428 0.82327E+00 -0.0845 36 CaCl+ 0.27666E-09 -9.5581 0.22777E-09 -9.6425 0.82327E+00 -0.0845 37 CaCl2,aq 0.72915E-13 -13.1372 0.72915E-13 -13.1372 0.10000E+01 0.0000 38 CaF+ 0.14506E-11 -11.8384 0.11943E-11 -11.9229 0.82327E+00 -0.0845 39 CaOH+ 0.99451E-07 -7.0024 0.81875E-07 -7.0868 0.82327E+00 -0.0845 40 CaSO4,aq 0.20034E-14 -14.6982 0.20034E-14 -14.6982 0.10000E+01 0.0000 41 HCl,aq 0.22443E-13 -13.6489 0.22443E-13 -13.6489 0.10000E+01 0.0000 45 HF,aq 0.48730E-12 -12.3122 0.48730E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.15686E-18 -18.8045 0.12885E-18 -18.8899 0.82139E+00 -0.0855 48 FeCl+ 0.11630E-15 -15.9344 0.95743E-16 -16.0189 0.82327E+00 -0.0845 51 FeF+ 0.21822E-17 -17.6611 0.17965E-17 -17.7456 0.82327E+00 -0.0845 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.19521E-10 -10.7095 0.16071E-10 -10.7939 0.82327E+00 -0.0845 55 HFeO2- 0.29578E-07 -7.5290 0.24295E-07 -7.6145 0.82139E+00 -0.0855 56 FeO+ 0.13684E-16 -16.8638 0.11265E-16 -16.9483 0.82327E+00 -0.0845 58 FeO2- 0.33959E-09 -9.4691 0.27893E-09 -9.5545 0.82139E+00 -0.0855 59 HFeO2,aq 0.32245E-11 -11.4915 0.32245E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11585E-04 -4.9361 0.11579E-04 -4.9363 0.99952E+00 -0.0002 61 KCl,aq 0.39145E-08 -8.4073 0.39145E-08 -8.4073 0.10000E+01 0.0000 63 KOH,aq 0.75287E-06 -6.1233 0.75287E-06 -6.1233 0.10000E+01 0.0000 64 KSO4- 0.18291E-12 -12.7378 0.15024E-12 -12.8232 0.82139E+00 -0.0855 65 MgCO3,aq 0.10535E-10 -10.9774 0.10535E-10 -10.9774 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11051E-12 -12.9566 0.90980E-13 -13.0411 0.82327E+00 -0.0845 67 MgCl+ 0.39048E-13 -13.4084 0.32147E-13 -13.4929 0.82327E+00 -0.0845 68 MgF+ 0.83680E-15 -15.0774 0.68892E-15 -15.1618 0.82327E+00 -0.0845 69 MgOH+ 0.85696E-10 -10.0670 0.70551E-10 -10.1515 0.82327E+00 -0.0845 71 MnF+ 0.23356E-15 -15.6316 0.19228E-15 -15.7161 0.82327E+00 -0.0845 72 MnO,aq 0.18267E-08 -8.7383 0.18267E-08 -8.7383 0.10000E+01 0.0000 73 MnOH+ 0.58887E-09 -9.2300 0.48480E-09 -9.3144 0.82327E+00 -0.0845 74 MnO2-2 0.15100E-10 -10.8210 0.73355E-11 -11.1346 0.48581E+00 -0.3135 75 HMnO2- 0.17784E-09 -9.7500 0.14608E-09 -9.8354 0.82139E+00 -0.0855 78 MnCl+ 0.14692E-12 -12.8329 0.12095E-12 -12.9174 0.82327E+00 -0.0845 79 MnSO4,aq 0.25419E-18 -18.5948 0.25419E-18 -18.5948 0.10000E+01 0.0000 80 NaCl,aq 0.90657E-05 -5.0426 0.90657E-05 -5.0426 0.10000E+01 0.0000 81 NaF,aq 0.37222E-08 -8.4292 0.37222E-08 -8.4292 0.10000E+01 0.0000 82 NaOH,aq 0.95935E-04 -4.0180 0.95935E-04 -4.0180 0.10000E+01 0.0000 84 OH- 0.77533E-02 -2.1105 0.63547E-02 -2.1969 0.81961E+00 -0.0864 89 HPO3-2 0.11652E-14 -14.9336 0.56605E-15 -15.2471 0.48581E+00 -0.3135 91 H2PO3- 0.12561E-18 -18.9010 0.10317E-18 -18.9864 0.82139E+00 -0.0855 92 H3PO4,aq 0.90616E-18 -18.0428 0.90616E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.31977E-10 -10.4952 0.26295E-10 -10.5801 0.82232E+00 -0.0850 94 PO4-3 0.66519E-09 -9.1771 0.14077E-09 -9.8515 0.21162E+00 -0.6744 98 HP2O7-3 0.59635E-18 -18.2245 0.11914E-18 -18.9240 0.19978E+00 -0.6995 99 P2O7-4 0.52381E-17 -17.2808 0.31313E-18 -18.5043 0.59779E-01 -1.2235 100 H2S,aq 0.13171E-05 -5.8804 0.13165E-05 -5.8806 0.99952E+00 -0.0002 101 S2-2 0.86514E-10 -10.0629 0.42029E-10 -10.3765 0.48581E+00 -0.3135 102 S3-2 0.13252E-16 -16.8777 0.64380E-17 -17.1912 0.48581E+00 -0.3135 107 SO3-2 0.18394E-15 -15.7353 0.90913E-16 -16.0414 0.49424E+00 -0.3061 108 HSO3- 0.62990E-18 -18.2007 0.51739E-18 -18.2862 0.82139E+00 -0.0855 109 HSO4- 0.64192E-17 -17.1925 0.52910E-17 -17.2765 0.82424E+00 -0.0839 111 S2O3-2 0.19234E-17 -17.7159 0.93438E-18 -18.0295 0.48581E+00 -0.3135 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1098613E-09 -.1934546E-01 -.1945566E+02 0.0000 2 H2O 0.1000000E+01 0.5552123E+02 0.9980054E+06 0.0000 3 Cl- 0.1640479E-02 0.1649549E-02 0.5835130E+02 7.1710 4 SO4-- 0.1240178E-09 -.1616834E-01 -.1549700E+04 9.8640 5 HCO3- 0.2606244E-03 0.1685058E-01 0.1025887E+04 6.3728 6 HS- 0.5704511E-02 0.2187417E-01 0.7218123E+03 7.7123 7 Al+++ 0.2064921E-28 0.4414043E-05 0.1188324E+00 0.7393 8 H4SiO4 0.6957529E-03 0.1174738E-01 0.1126591E+04 -3.1575 9 Ca++ 0.2163698E-06 0.6073497E-06 0.2428718E-01 13.1018 10 Mg++ 0.3387986E-10 0.1342651E-09 0.3256988E-05 9.2942 11 Fe++ 0.9338159E-13 0.3015174E-07 0.1680136E-02 6.7351 12 K+ 0.1947448E-03 0.1955015E-03 0.7627486E+01 6.2464 13 Na+ 0.2472158E-01 0.2717408E-01 0.6233362E+03 8.3490 14 Mn++ 0.3029270E-10 0.2638910E-08 0.1446538E-03 9.2466 15 F- 0.9557894E-06 0.9595136E-06 0.1818826E-01 3.9353 16 HPO4-- 0.3219347E-07 0.3289063E-07 0.3149784E-02 12.2783 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278006E+02 -.9642715E-02 -.8277042E+02 0.0000000E+00 2 H2O -.7073828E+01 0.2767447E+02 -.3474830E+02 0.0000000E+00 3 Cl- 0.8222152E-03 0.8222152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1391464E+00 -.8059084E-02 0.1472055E+00 0.0000000E+00 5 HCO3- 0.8399147E-02 0.8399147E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1363023E+00 0.1090315E-01 -.1472055E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2200173E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5855462E-02 0.5205805E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.3027325E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6692424E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1502909E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9744744E-04 0.1061473E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1354488E-01 0.6262832E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1315361E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4649600E-04 0.4782680E-06 0.4601773E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1639429E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1060E-13 Mass of aqueous solution: 0.499560E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1159900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.248 0.796 1638. 3.214 30.00 629.0 andradite 0.5888 -0.230 299.2 2.476 5.478 77.74 grossular 0.1426 -0.846 64.24 1.808 1.176 17.87 apatite-OH 0.9817E-02 -2.008 4.931 0.693 0.9027E-01 1.567 apatite-F 0.4602E-04 -4.337 0.2321E-01 -1.634 0.4249E-03 0.7250E-02 clinochlore 0.7021 -0.154 390.3 2.591 7.145 148.4 daphnite 0.2033 -0.692 145.1 2.162 2.656 43.96 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.3855E-01 -1.414 8.349 0.922 0.1528 2.552 hedenbergite 0.1000E-01 -2.000 2.481 0.395 0.4542E-01 0.6796 microcline 0.9398 -0.027 261.6 2.418 4.789 102.2 stilbite 3.227 0.509 2274. 3.357 41.64 1061. stilpnomelane-Fe 0.2433 -0.614 262.2 2.419 4.801 90.58 tr.625ac.25prg.125 0.1156 -0.937 98.79 1.995 1.809 31.80 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1879E-01 0.1879E-01 1.0000 -1.726 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.366914 g Volume = 2211.099481 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1159900 moles log = -0.9356 Original solution: 1000.0103000 g Original solution / Rock added: 8621.52 (Water/Rock Ratio), log = 3.9356 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 25.2165 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4215E-01 0.9462 0.1006E+01 0.1063E+01 CO2,gas 0.1849E-06 0.9561 0.4457E-05 0.4662E-05 CH4,gas 0.9573E+00 0.9853 0.2378E+02 0.2414E+02 H2,gas 0.5948E-03 1.0135 0.1520E-01 0.1500E-01 H2S,gas 0.1580E-05 0.9082 0.3619E-04 0.3985E-04 S2,gas 0.8436E-26 1.0000 0.2127E-24 0.2127E-24 CO,gas 0.7164E-12 1.0000 0.1806E-10 0.1806E-10 SO3,gas 0.7485E-47 1.0000 0.1887E-45 0.1887E-45 SO2,gas 0.4428E-26 1.0000 0.1117E-24 0.1117E-24 HF,gas 0.4745E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1570E-17 1.0000 0.3960E-16 0.3960E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.71 -7.05 -2.350 0.12037E+05 -5.351 3 CH4,gas 4.54 4.22 -0.32 -0.081 0.55101E+03 1.376 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60053E+04 -1.818 5 H2S,gas -6.23 -12.37 -6.14 -3.070 0.10485E+05 -4.441 6 S2,gas -7.34 -33.71 -26.37 -4.057 0.45028E+05 -24.672 7 CO,gas 3.21 -9.23 -12.44 -3.828 0.21245E+05 -10.743 8 SO3,gas 17.12 -30.30 -47.42 -11.856 0.80974E+05 -45.724 9 SO2,gas 0.83 -25.82 -26.65 -7.107 0.45506E+05 -24.952 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.91 -18.10 -9.051 0.30907E+05 -16.402 12 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.75 -4.71 -0.236 0.80450E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93666E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41067E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28498E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75898E+04 38 aragonite 0.97 -0.61 -1.57 -0.525 0.26890E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55913E+04 40 calcite 0.81 -0.61 -1.42 -0.473 0.24247E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52805E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71075E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39699E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68950E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65462E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13339E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.74 -1.64 -0.469 0.28037E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65862E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68199E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57037E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37138E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.74 -1.20 -0.342 0.20459E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64130E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58875E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28626E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48023E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82158E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41129E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36686E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91147E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40576E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 145 pyrite -21.25 -22.49 -1.24 -0.292 0.21205E+04 146 pyrrhotite -4.26 -5.64 -1.38 -0.458 0.23481E+04 147 pyrrhotiteFe0.875 -6.02 -7.03 -1.02 -0.374 0.17354E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22359E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84952E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28661E+03 154 rhodochrosite -0.98 -4.46 -3.49 -1.162 0.59543E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23162E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.98 -4.37 -1.456 0.74564E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27813E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.34 -2.75 -0.393 0.46958E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90659E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77513E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65441E+04 184 troilite-low -4.41 -5.64 -1.22 -0.408 0.20910E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79435E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34150E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66603E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60591E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66173E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73670E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58210E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83480E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62080E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66549E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53289E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35290E+04 234 alabandite -0.98 -3.12 -2.15 -0.715 0.36645E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52533E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1159900 MOLES New total amount of reactant added: 0.1199900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8664E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1199900 Water: Moles liquid = 0.2767E+02 kg liquid = 0.4985E+00 Moles total = -.7071E+01 kg total = -.1274E+00 Activity = 0.9997 Stoichiometric ionic strength = .1212090E-02 Osmotic coef. = 0.9692 True ionic strength = .2552363E-01 Chg. balance for total moles = -.8664E-10 Max. difference allowed = 0.8458E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11062E-09 -9.9562 0.91477E-10 -10.0387 0.82695E+00 -0.0825 2 H2O 0.99970E+00 -0.0001 0.99970E+00 -0.0001 3 Cl- 0.16873E-02 -2.7728 0.13852E-02 -2.8585 0.82096E+00 -0.0857 4 SO4-- 0.12761E-09 -9.8941 0.62027E-10 -10.2074 0.48606E+00 -0.3133 5 HCO3- 0.26811E-03 -3.5717 0.22049E-03 -3.6566 0.82241E+00 -0.0849 6 HS- 0.58986E-02 -2.2293 0.48433E-02 -2.3149 0.82110E+00 -0.0856 7 Al+++ 0.21147E-28 -28.6747 0.41997E-29 -29.3768 0.19859E+00 -0.7020 8 H4SiO4 0.69575E-03 -3.1575 0.69575E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.21961E-06 -6.6584 0.10579E-06 -6.9755 0.48174E+00 -0.3172 10 Mg++ 0.34388E-10 -10.4636 0.16475E-10 -10.7832 0.47908E+00 -0.3196 11 Fe++ 0.94782E-13 -13.0233 0.45468E-13 -13.3423 0.47971E+00 -0.3190 12 K+ 0.19609E-03 -3.7075 0.16131E-03 -3.7923 0.82263E+00 -0.0848 13 Na+ 0.24892E-01 -1.6039 0.20431E-01 -1.6897 0.82077E+00 -0.0858 14 Mn++ 0.30759E-10 -10.5120 0.14770E-10 -10.8306 0.48019E+00 -0.3186 15 F- 0.95020E-06 -6.0222 0.77815E-06 -6.1089 0.81892E+00 -0.0868 16 HPO4-- 0.31849E-07 -7.4969 0.15483E-07 -7.8101 0.48614E+00 -0.3132 18 HSiO3- 0.86532E-02 -2.0628 0.71039E-02 -2.1485 0.82096E+00 -0.0857 19 Ca(HSiO3)+ 0.20800E-07 -7.6819 0.17116E-07 -7.7666 0.82285E+00 -0.0847 20 Mg(HSiO3)+ 0.40311E-11 -11.3946 0.33170E-11 -11.4793 0.82285E+00 -0.0847 21 NaHSiO3,aq 0.23474E-02 -2.6294 0.23474E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.82950E-16 -16.0812 0.68256E-16 -16.1659 0.82285E+00 -0.0847 24 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.43882E-05 -5.3577 0.35947E-05 -5.4443 0.81917E+00 -0.0866 26 CH4,aq 0.16726E-01 -1.7766 0.16719E-01 -1.7768 0.99962E+00 -0.0002 27 C2H6,aq 0.41287E-08 -8.3842 0.41272E-08 -8.3843 0.99962E+00 -0.0002 28 C3H8,aq 0.23530E-13 -13.6284 0.23521E-13 -13.6285 0.99962E+00 -0.0002 29 C4H10,aq 0.13174E-18 -18.8803 0.13169E-18 -18.8805 0.99962E+00 -0.0002 30 ethanol,aq 0.15154E-15 -15.8195 0.15149E-15 -15.8196 0.99962E+00 -0.0002 31 CO,aq 0.12544E-13 -13.9016 0.12544E-13 -13.9016 0.10000E+01 0.0000 32 CO2,aq 0.43128E-07 -7.3652 0.43112E-07 -7.3654 0.99962E+00 -0.0002 33 CO3-2 0.43426E-03 -3.3622 0.21054E-03 -3.6767 0.48482E+00 -0.3144 34 CaCO3,aq 0.27928E-06 -6.5540 0.27928E-06 -6.5540 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.72363E-09 -9.1405 0.59544E-09 -9.2252 0.82285E+00 -0.0847 36 CaCl+ 0.28821E-09 -9.5403 0.23715E-09 -9.6250 0.82285E+00 -0.0847 37 CaCl2,aq 0.78043E-13 -13.1077 0.78043E-13 -13.1077 0.10000E+01 0.0000 38 CaF+ 0.14607E-11 -11.8354 0.12019E-11 -11.9201 0.82285E+00 -0.0847 39 CaOH+ 0.10014E-06 -6.9994 0.82399E-07 -7.0841 0.82285E+00 -0.0847 40 CaSO4,aq 0.20838E-14 -14.6812 0.20838E-14 -14.6812 0.10000E+01 0.0000 41 HCl,aq 0.23219E-13 -13.6342 0.23219E-13 -13.6342 0.10000E+01 0.0000 45 HF,aq 0.48729E-12 -12.3122 0.48729E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.15594E-18 -18.8070 0.12802E-18 -18.8927 0.82096E+00 -0.0857 48 FeCl+ 0.12115E-15 -15.9167 0.99689E-16 -16.0014 0.82285E+00 -0.0847 51 FeF+ 0.21973E-17 -17.6581 0.18080E-17 -17.7428 0.82285E+00 -0.0847 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.19657E-10 -10.7065 0.16174E-10 -10.7912 0.82285E+00 -0.0847 55 HFeO2- 0.29405E-07 -7.5316 0.24140E-07 -7.6173 0.82096E+00 -0.0857 56 FeO+ 0.13779E-16 -16.8608 0.11338E-16 -16.9455 0.82285E+00 -0.0847 58 FeO2- 0.33760E-09 -9.4716 0.27715E-09 -9.5573 0.82096E+00 -0.0857 59 HFeO2,aq 0.32245E-11 -11.4915 0.32245E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11583E-04 -4.9362 0.11579E-04 -4.9363 0.99962E+00 -0.0002 61 KCl,aq 0.40497E-08 -8.3926 0.40497E-08 -8.3926 0.10000E+01 0.0000 63 KOH,aq 0.75284E-06 -6.1233 0.75284E-06 -6.1233 0.10000E+01 0.0000 64 KSO4- 0.18912E-12 -12.7233 0.15526E-12 -12.8089 0.82096E+00 -0.0857 65 MgCO3,aq 0.10901E-10 -10.9625 0.10901E-10 -10.9625 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11514E-12 -12.9388 0.94747E-13 -13.0234 0.82285E+00 -0.0847 67 MgCl+ 0.40677E-13 -13.3906 0.33471E-13 -13.4753 0.82285E+00 -0.0847 68 MgF+ 0.84259E-15 -15.0744 0.69332E-15 -15.1591 0.82285E+00 -0.0847 69 MgOH+ 0.86289E-10 -10.0640 0.71003E-10 -10.1487 0.82285E+00 -0.0847 71 MnF+ 0.23527E-15 -15.6284 0.19359E-15 -15.7131 0.82285E+00 -0.0847 72 MnO,aq 0.18274E-08 -8.7382 0.18274E-08 -8.7382 0.10000E+01 0.0000 73 MnOH+ 0.59319E-09 -9.2268 0.48810E-09 -9.3115 0.82285E+00 -0.0847 74 MnO2-2 0.14944E-10 -10.8255 0.72451E-11 -11.1400 0.48482E+00 -0.3144 75 HMnO2- 0.17687E-09 -9.7524 0.14520E-09 -9.8380 0.82096E+00 -0.0857 78 MnCl+ 0.15311E-12 -12.8150 0.12599E-12 -12.8997 0.82285E+00 -0.0847 79 MnSO4,aq 0.26449E-18 -18.5776 0.26449E-18 -18.5776 0.10000E+01 0.0000 80 NaCl,aq 0.93788E-05 -5.0279 0.93788E-05 -5.0279 0.10000E+01 0.0000 81 NaF,aq 0.37221E-08 -8.4292 0.37221E-08 -8.4292 0.10000E+01 0.0000 82 NaOH,aq 0.95931E-04 -4.0180 0.95931E-04 -4.0180 0.10000E+01 0.0000 84 OH- 0.77080E-02 -2.1131 0.63142E-02 -2.1997 0.81917E+00 -0.0866 89 HPO3-2 0.11527E-14 -14.9383 0.55886E-15 -15.2527 0.48482E+00 -0.3144 91 H2PO3- 0.12487E-18 -18.9035 0.10252E-18 -18.9892 0.82096E+00 -0.0857 92 H3PO4,aq 0.90616E-18 -18.0428 0.90616E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.31790E-10 -10.4977 0.26128E-10 -10.5829 0.82189E+00 -0.0852 94 PO4-3 0.65537E-09 -9.1835 0.13810E-09 -9.8598 0.21071E+00 -0.6763 98 HP2O7-3 0.58775E-18 -18.2308 0.11688E-18 -18.9323 0.19886E+00 -0.7015 99 P2O7-4 0.51472E-17 -17.2884 0.30523E-18 -18.5154 0.59301E-01 -1.2269 100 H2S,aq 0.13698E-05 -5.8633 0.13693E-05 -5.8635 0.99962E+00 -0.0002 101 S2-2 0.92593E-10 -10.0334 0.44891E-10 -10.3478 0.48482E+00 -0.3144 102 S3-2 0.14753E-16 -16.8311 0.71523E-17 -17.1456 0.48482E+00 -0.3144 107 SO3-2 0.18926E-15 -15.7229 0.93358E-16 -16.0298 0.49328E+00 -0.3069 108 HSO3- 0.65133E-18 -18.1862 0.53472E-18 -18.2719 0.82096E+00 -0.0857 109 HSO4- 0.66375E-17 -17.1780 0.54682E-17 -17.2622 0.82382E+00 -0.0842 111 S2O3-2 0.20585E-17 -17.6864 0.99801E-18 -18.0009 0.48482E+00 -0.3144 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1106195E-09 -.1925908E-01 -.1936846E+02 0.0000 2 H2O 0.1000000E+01 0.5552180E+02 0.9979982E+06 0.0000 3 Cl- 0.1687265E-02 0.1696648E-02 0.6001635E+02 7.1802 4 SO4-- 0.1276120E-09 -.1672844E-01 -.1603356E+04 9.8700 5 HCO3- 0.2681075E-03 0.1742824E-01 0.1061037E+04 6.3821 6 HS- 0.5898603E-02 0.2262842E-01 0.7466883E+03 7.7238 7 Al+++ 0.2114714E-28 0.4388305E-05 0.1181375E+00 0.7393 8 H4SiO4 0.6957451E-03 0.1169640E-01 0.1121682E+04 -3.1575 9 Ca++ 0.2196082E-06 0.6208452E-06 0.2482642E-01 13.1018 10 Mg++ 0.3438795E-10 0.1357670E-09 0.3293364E-05 9.2942 11 Fe++ 0.9478216E-13 0.2997662E-07 0.1670349E-02 6.7351 12 K+ 0.1960884E-03 0.1968453E-03 0.7679781E+01 6.2463 13 Na+ 0.2489247E-01 0.2734520E-01 0.6272505E+03 8.3490 14 Mn++ 0.3075905E-10 0.2643290E-08 0.1448913E-03 9.2468 15 F- 0.9502044E-06 0.9539284E-06 0.1808208E-01 3.9297 16 HPO4-- 0.3184909E-07 0.3253626E-07 0.3115793E-02 12.2672 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277963E+02 -.9601061E-02 -.8277003E+02 0.0000000E+00 2 H2O -.7070553E+01 0.2767879E+02 -.3474935E+02 0.0000000E+00 3 Cl- 0.8458152E-03 0.8458152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1391655E+00 -.8339483E-02 0.1475050E+00 0.0000000E+00 5 HCO3- 0.8688347E-02 0.8688347E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1362242E+00 0.1128074E-01 -.1475050E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2187663E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5830902E-02 0.5205807E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.3095045E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6768275E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1494398E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9813157E-04 0.1061473E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1363216E-01 0.6262745E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1317736E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4809600E-04 0.4755536E-06 0.4762045E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1622001E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.3948E-14 Mass of aqueous solution: 0.499642E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1199900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.248 0.796 1638. 3.214 29.99 628.9 andradite 0.5900 -0.229 299.8 2.477 5.489 77.90 grossular 0.1429 -0.845 64.37 1.809 1.179 17.91 apatite-OH 0.9815E-02 -2.008 4.930 0.693 0.9026E-01 1.567 apatite-F 0.4762E-04 -4.322 0.2402E-01 -1.620 0.4397E-03 0.7502E-02 clinochlore 0.7019 -0.154 390.1 2.591 7.142 148.4 daphnite 0.2032 -0.692 145.0 2.161 2.655 43.94 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.3075E-01 -1.512 6.658 0.823 0.1219 2.035 hedenbergite 0.7976E-02 -2.098 1.979 0.296 0.3623E-01 0.5420 microcline 0.9402 -0.027 261.7 2.418 4.791 102.2 stilbite 3.228 0.509 2275. 3.357 41.64 1061. stilpnomelane-Fe 0.2426 -0.615 261.6 2.418 4.788 90.35 tr.625ac.25prg.125 0.1181 -0.928 101.0 2.004 1.848 32.50 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1880E-01 0.1880E-01 1.0000 -1.726 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.367682 g Volume = 2211.110647 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1199900 moles log = -0.9209 Original solution: 1000.0103000 g Original solution / Rock added: 8334.11 (Water/Rock Ratio), log = 3.9209 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 26.0696 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.4081E-01 0.9452 0.1006E+01 0.1064E+01 CO2,gas 0.1853E-06 0.9547 0.4612E-05 0.4831E-05 CH4,gas 0.9586E+00 0.9848 0.2461E+02 0.2499E+02 H2,gas 0.5751E-03 1.0140 0.1520E-01 0.1499E-01 H2S,gas 0.1595E-05 0.9053 0.3764E-04 0.4158E-04 S2,gas 0.8828E-26 1.0000 0.2301E-24 0.2301E-24 CO,gas 0.7170E-12 1.0000 0.1869E-10 0.1869E-10 SO3,gas 0.7530E-47 1.0000 0.1963E-45 0.1963E-45 SO2,gas 0.4455E-26 1.0000 0.1161E-24 0.1161E-24 HF,gas 0.4590E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1572E-17 1.0000 0.4097E-16 0.4097E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.70 -7.04 -2.345 0.12012E+05 -5.336 3 CH4,gas 4.54 4.24 -0.31 -0.077 0.52567E+03 1.391 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60053E+04 -1.818 5 H2S,gas -6.23 -12.35 -6.12 -3.062 0.10455E+05 -4.424 6 S2,gas -7.34 -33.67 -26.34 -4.052 0.44970E+05 -24.638 7 CO,gas 3.21 -9.21 -12.43 -3.824 0.21219E+05 -10.728 8 SO3,gas 17.12 -30.28 -47.41 -11.852 0.80945E+05 -45.707 9 SO2,gas 0.83 -25.80 -26.63 -7.102 0.45477E+05 -24.935 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.90 -18.09 -9.043 0.30882E+05 -16.388 12 acmite 7.71 6.53 -1.18 -0.123 0.20179E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.75 -4.71 -0.236 0.80441E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93667E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41067E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28498E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75897E+04 38 aragonite 0.97 -0.59 -1.56 -0.520 0.26636E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55914E+04 40 calcite 0.81 -0.59 -1.41 -0.468 0.23994E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52805E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71075E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39700E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68951E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65459E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13339E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.73 -1.63 -0.465 0.27783E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65862E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68199E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57037E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37139E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.73 -1.18 -0.338 0.20206E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64130E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58875E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28626E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48023E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82155E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41129E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36686E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91146E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40576E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 145 pyrite -21.25 -22.45 -1.21 -0.284 0.20622E+04 146 pyrrhotite -4.26 -5.62 -1.36 -0.453 0.23190E+04 147 pyrrhotiteFe0.875 -6.02 -7.02 -1.00 -0.368 0.17062E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22356E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84952E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28660E+03 154 rhodochrosite -0.98 -4.45 -3.47 -1.157 0.59287E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23159E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.96 -4.35 -1.451 0.74310E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27813E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.34 -2.75 -0.393 0.46952E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90658E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77514E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65441E+04 184 troilite-low -4.41 -5.62 -1.21 -0.403 0.20618E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79435E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34149E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66603E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60590E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66173E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73670E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60360E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58210E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83480E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62080E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66548E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53289E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35290E+04 234 alabandite -0.98 -3.11 -2.13 -0.710 0.36351E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52533E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1199900 MOLES New total amount of reactant added: 0.1239900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1239900 Water: Moles liquid = 0.2768E+02 kg liquid = 0.4986E+00 Moles total = -.7067E+01 kg total = -.1273E+00 Activity = 0.9997 Stoichiometric ionic strength = .8674535E-03 Osmotic coef. = 0.9737 True ionic strength = .2570608E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.8694E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11138E-09 -9.9532 0.92060E-10 -10.0359 0.82655E+00 -0.0827 2 H2O 0.99969E+00 -0.0001 0.99969E+00 -0.0001 3 Cl- 0.17340E-02 -2.7609 0.14228E-02 -2.8469 0.82052E+00 -0.0859 4 SO4-- 0.13117E-09 -9.8822 0.63628E-10 -10.1964 0.48508E+00 -0.3142 5 HCO3- 0.27551E-03 -3.5599 0.22646E-03 -3.6450 0.82198E+00 -0.0851 6 HS- 0.60926E-02 -2.2152 0.50000E-02 -2.3010 0.82067E+00 -0.0858 7 Al+++ 0.21655E-28 -28.6644 0.42807E-29 -29.3685 0.19768E+00 -0.7040 8 H4SiO4 0.69574E-03 -3.1576 0.69574E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.22288E-06 -6.6519 0.10715E-06 -6.9700 0.48074E+00 -0.3181 10 Mg++ 0.34901E-10 -10.4572 0.16685E-10 -10.7777 0.47808E+00 -0.3205 11 Fe++ 0.96197E-13 -13.0168 0.46051E-13 -13.3368 0.47871E+00 -0.3199 12 K+ 0.19744E-03 -3.7046 0.16233E-03 -3.7896 0.82221E+00 -0.0850 13 Na+ 0.25064E-01 -1.6010 0.20561E-01 -1.6870 0.82033E+00 -0.0860 14 Mn++ 0.31230E-10 -10.5054 0.14965E-10 -10.8249 0.47919E+00 -0.3195 15 F- 0.94468E-06 -6.0247 0.77320E-06 -6.1117 0.81848E+00 -0.0870 16 HPO4-- 0.31510E-07 -7.5016 0.15288E-07 -7.8157 0.48516E+00 -0.3141 18 HSiO3- 0.86029E-02 -2.0654 0.70588E-02 -2.1513 0.82052E+00 -0.0859 19 Ca(HSiO3)+ 0.20944E-07 -7.6789 0.17225E-07 -7.7638 0.82243E+00 -0.0849 20 Mg(HSiO3)+ 0.40589E-11 -11.3916 0.33382E-11 -11.4765 0.82243E+00 -0.0849 21 NaHSiO3,aq 0.23473E-02 -2.6294 0.23473E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.83524E-16 -16.0782 0.68692E-16 -16.1631 0.82243E+00 -0.0849 24 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.43627E-05 -5.3602 0.35719E-05 -5.4471 0.81873E+00 -0.0869 26 CH4,aq 0.17286E-01 -1.7623 0.17281E-01 -1.7624 0.99973E+00 -0.0001 27 C2H6,aq 0.44105E-08 -8.3555 0.44093E-08 -8.3556 0.99973E+00 -0.0001 28 C3H8,aq 0.25981E-13 -13.5853 0.25974E-13 -13.5855 0.99973E+00 -0.0001 29 C4H10,aq 0.15035E-18 -18.8229 0.15031E-18 -18.8230 0.99973E+00 -0.0001 30 ethanol,aq 0.16188E-15 -15.7908 0.16184E-15 -15.7909 0.99973E+00 -0.0001 31 CO,aq 0.12965E-13 -13.8872 0.12965E-13 -13.8872 0.10000E+01 0.0000 32 CO2,aq 0.44573E-07 -7.3509 0.44561E-07 -7.3510 0.99973E+00 -0.0001 33 CO3-2 0.44409E-03 -3.3525 0.21486E-03 -3.6678 0.48383E+00 -0.3153 34 CaCO3,aq 0.28867E-06 -6.5396 0.28867E-06 -6.5396 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.75312E-09 -9.1231 0.61939E-09 -9.2080 0.82243E+00 -0.0849 36 CaCl+ 0.29999E-09 -9.5229 0.24672E-09 -9.6078 0.82243E+00 -0.0849 37 CaCl2,aq 0.83398E-13 -13.0788 0.83398E-13 -13.0788 0.10000E+01 0.0000 38 CaF+ 0.14707E-11 -11.8325 0.12096E-11 -11.9174 0.82243E+00 -0.0849 39 CaOH+ 0.10083E-06 -6.9964 0.82924E-07 -7.0813 0.82243E+00 -0.0849 40 CaSO4,aq 0.21649E-14 -14.6646 0.21649E-14 -14.6646 0.10000E+01 0.0000 41 HCl,aq 0.24002E-13 -13.6197 0.24002E-13 -13.6197 0.10000E+01 0.0000 45 HF,aq 0.48729E-12 -12.3122 0.48729E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.15503E-18 -18.8096 0.12721E-18 -18.8955 0.82052E+00 -0.0859 48 FeCl+ 0.12610E-15 -15.8993 0.10371E-15 -15.9842 0.82243E+00 -0.0849 51 FeF+ 0.22124E-17 -17.6551 0.18196E-17 -17.7400 0.82243E+00 -0.0849 53 FeO,aq 0.21112E-09 -9.6755 0.21112E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.19792E-10 -10.7035 0.16278E-10 -10.7884 0.82243E+00 -0.0849 55 HFeO2- 0.29233E-07 -7.5341 0.23987E-07 -7.6200 0.82052E+00 -0.0859 56 FeO+ 0.13874E-16 -16.8578 0.11410E-16 -16.9427 0.82243E+00 -0.0849 58 FeO2- 0.33563E-09 -9.4741 0.27539E-09 -9.5600 0.82052E+00 -0.0859 59 HFeO2,aq 0.32245E-11 -11.4915 0.32245E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11582E-04 -4.9362 0.11579E-04 -4.9363 0.99973E+00 -0.0001 61 KCl,aq 0.41862E-08 -8.3782 0.41862E-08 -8.3782 0.10000E+01 0.0000 63 KOH,aq 0.75281E-06 -6.1233 0.75281E-06 -6.1233 0.10000E+01 0.0000 64 KSO4- 0.19534E-12 -12.7092 0.16028E-12 -12.7951 0.82052E+00 -0.0859 65 MgCO3,aq 0.11268E-10 -10.9482 0.11268E-10 -10.9482 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11984E-12 -12.9214 0.98557E-13 -13.0063 0.82243E+00 -0.0849 67 MgCl+ 0.42339E-13 -13.3733 0.34821E-13 -13.4582 0.82243E+00 -0.0849 68 MgF+ 0.84839E-15 -15.0714 0.69774E-15 -15.1563 0.82243E+00 -0.0849 69 MgOH+ 0.86883E-10 -10.0611 0.71455E-10 -10.1460 0.82243E+00 -0.0849 71 MnF+ 0.23698E-15 -15.6253 0.19490E-15 -15.7102 0.82243E+00 -0.0849 72 MnO,aq 0.18281E-08 -8.7380 0.18281E-08 -8.7380 0.10000E+01 0.0000 73 MnOH+ 0.59751E-09 -9.2237 0.49141E-09 -9.3086 0.82243E+00 -0.0849 74 MnO2-2 0.14791E-10 -10.8300 0.71563E-11 -11.1453 0.48383E+00 -0.3153 75 HMnO2- 0.17591E-09 -9.7547 0.14434E-09 -9.8406 0.82052E+00 -0.0859 78 MnCl+ 0.15943E-12 -12.7974 0.13112E-12 -12.8823 0.82243E+00 -0.0849 79 MnSO4,aq 0.27490E-18 -18.5608 0.27490E-18 -18.5608 0.10000E+01 0.0000 80 NaCl,aq 0.96948E-05 -5.0135 0.96948E-05 -5.0135 0.10000E+01 0.0000 81 NaF,aq 0.37219E-08 -8.4292 0.37219E-08 -8.4292 0.10000E+01 0.0000 82 NaOH,aq 0.95927E-04 -4.0181 0.95927E-04 -4.0181 0.10000E+01 0.0000 84 OH- 0.76631E-02 -2.1156 0.62741E-02 -2.2025 0.81873E+00 -0.0869 89 HPO3-2 0.11405E-14 -14.9429 0.55180E-15 -15.2582 0.48383E+00 -0.3153 91 H2PO3- 0.12415E-18 -18.9061 0.10187E-18 -18.9920 0.82052E+00 -0.0859 92 H3PO4,aq 0.90616E-18 -18.0428 0.90616E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.31605E-10 -10.5002 0.25962E-10 -10.5857 0.82147E+00 -0.0854 94 PO4-3 0.64575E-09 -9.1899 0.13549E-09 -9.8681 0.20981E+00 -0.6782 98 HP2O7-3 0.57931E-18 -18.2371 0.11467E-18 -18.9406 0.19794E+00 -0.7035 99 P2O7-4 0.50582E-17 -17.2960 0.29757E-18 -18.5264 0.58828E-01 -1.2304 100 H2S,aq 0.14230E-05 -5.8468 0.14226E-05 -5.8469 0.99973E+00 -0.0001 101 S2-2 0.98883E-10 -10.0049 0.47843E-10 -10.3202 0.48383E+00 -0.3153 102 S3-2 0.16368E-16 -16.7860 0.79196E-17 -17.1013 0.48383E+00 -0.3153 107 SO3-2 0.19452E-15 -15.7110 0.95768E-16 -16.0188 0.49233E+00 -0.3077 108 HSO3- 0.67276E-18 -18.1721 0.55202E-18 -18.2580 0.82052E+00 -0.0859 109 HSO4- 0.68558E-17 -17.1639 0.56451E-17 -17.2483 0.82341E+00 -0.0844 111 S2O3-2 0.21984E-17 -17.6579 0.10636E-17 -17.9732 0.48383E+00 -0.3153 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1113794E-09 -.1917348E-01 -.1928203E+02 0.0000 2 H2O 0.1000000E+01 0.5552237E+02 0.9979910E+06 0.0000 3 Cl- 0.1734035E-02 0.1743734E-02 0.6168085E+02 7.1891 4 SO4-- 0.1311701E-09 -.1728869E-01 -.1657025E+04 9.8755 5 HCO3- 0.2755063E-03 0.1800573E-01 0.1096176E+04 6.3909 6 HS- 0.6092637E-02 0.2338275E-01 0.7715664E+03 7.7349 7 Al+++ 0.2165473E-28 0.4362837E-05 0.1174498E+00 0.7393 8 H4SiO4 0.6957373E-03 0.1164595E-01 0.1116825E+04 -3.1576 9 Ca++ 0.2228800E-06 0.6343814E-06 0.2536726E-01 13.1018 10 Mg++ 0.3490130E-10 0.1372756E-09 0.3329901E-05 9.2942 11 Fe++ 0.9619722E-13 0.2980334E-07 0.1660665E-02 6.7351 12 K+ 0.1974351E-03 0.1981921E-03 0.7732189E+01 6.2463 13 Na+ 0.2506374E-01 0.2751671E-01 0.6311736E+03 8.3490 14 Mn++ 0.3123047E-10 0.2647701E-08 0.1451306E-03 9.2469 15 F- 0.9446781E-06 0.9484020E-06 0.1797701E-01 3.9242 16 HPO4-- 0.3151001E-07 0.3218737E-07 0.3082328E-02 12.2562 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277920E+02 -.9559781E-02 -.8276964E+02 0.0000000E+00 2 H2O -.7067278E+01 0.2768311E+02 -.3475039E+02 0.0000000E+00 3 Cl- 0.8694152E-03 0.8694152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1391846E+00 -.8620038E-02 0.1478046E+00 0.0000000E+00 5 HCO3- 0.8977547E-02 0.8977547E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1361461E+00 0.1165850E-01 -.1478046E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2175284E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5806602E-02 0.5205810E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.3162987E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6844481E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1485977E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9881738E-04 0.1061472E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1371966E-01 0.6262657E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1320128E-08 0.8669296E-01 0.0000000E+00 15 F- 0.4969600E-04 0.4728675E-06 0.4922313E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1604843E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.2433E-13 Mass of aqueous solution: 0.499724E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1239900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.248 0.796 1638. 3.214 29.99 628.9 andradite 0.5912 -0.228 300.4 2.478 5.500 78.06 grossular 0.1432 -0.844 64.51 1.810 1.181 17.95 apatite-OH 0.9813E-02 -2.008 4.929 0.693 0.9024E-01 1.566 apatite-F 0.4922E-04 -4.308 0.2482E-01 -1.605 0.4544E-03 0.7755E-02 clinochlore 0.7016 -0.154 390.0 2.591 7.139 148.3 daphnite 0.2032 -0.692 145.0 2.161 2.654 43.93 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2294E-01 -1.639 4.967 0.696 0.9094E-01 1.518 hedenbergite 0.5950E-02 -2.225 1.476 0.169 0.2702E-01 0.4043 microcline 0.9405 -0.027 261.8 2.418 4.792 102.3 stilbite 3.228 0.509 2275. 3.357 41.64 1061. stilpnomelane-Fe 0.2420 -0.616 260.9 2.416 4.776 90.11 tr.625ac.25prg.125 0.1207 -0.918 103.1 2.013 1.888 33.20 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1880E-01 0.1880E-01 1.0000 -1.726 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.368438 g Volume = 2211.121818 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1239900 moles log = -0.9066 Original solution: 1000.0103000 g Original solution / Rock added: 8065.25 (Water/Rock Ratio), log = 3.9066 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 26.9238 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3956E-01 0.9442 0.1006E+01 0.1065E+01 CO2,gas 0.1857E-06 0.9534 0.4768E-05 0.5000E-05 CH4,gas 0.9599E+00 0.9842 0.2544E+02 0.2584E+02 H2,gas 0.5566E-03 1.0145 0.1520E-01 0.1498E-01 H2S,gas 0.1610E-05 0.9024 0.3911E-04 0.4334E-04 S2,gas 0.9227E-26 1.0000 0.2484E-24 0.2484E-24 CO,gas 0.7176E-12 1.0000 0.1932E-10 0.1932E-10 SO3,gas 0.7575E-47 1.0000 0.2040E-45 0.2040E-45 SO2,gas 0.4482E-26 1.0000 0.1207E-24 0.1207E-24 HF,gas 0.4444E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1573E-17 1.0000 0.4235E-16 0.4235E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 70 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.68 -7.02 -2.340 0.11988E+05 -5.322 3 CH4,gas 4.54 4.25 -0.29 -0.073 0.50116E+03 1.405 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60053E+04 -1.818 5 H2S,gas -6.23 -12.34 -6.11 -3.053 0.10427E+05 -4.408 6 S2,gas -7.34 -33.64 -26.30 -4.047 0.44913E+05 -24.605 7 CO,gas 3.21 -9.20 -12.41 -3.819 0.21195E+05 -10.714 8 SO3,gas 17.12 -30.27 -47.39 -11.847 0.80916E+05 -45.690 9 SO2,gas 0.83 -25.79 -26.62 -7.098 0.45448E+05 -24.918 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.88 -18.07 -9.036 0.30858E+05 -16.373 12 acmite 7.71 6.53 -1.18 -0.123 0.20180E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.75 -4.71 -0.236 0.80432E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93668E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41067E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28499E+04 30 anorthite 12.71 8.27 -4.44 -0.342 0.75897E+04 38 aragonite 0.97 -0.58 -1.55 -0.515 0.26391E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55914E+04 40 calcite 0.81 -0.58 -1.39 -0.464 0.23749E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52805E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71075E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39700E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68951E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65456E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13339E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.72 -1.61 -0.461 0.27538E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65862E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68198E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57037E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37139E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.72 -1.17 -0.334 0.19960E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64130E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58875E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28626E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48023E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82152E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41129E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36687E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91146E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40576E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 145 pyrite -21.25 -22.42 -1.17 -0.276 0.20055E+04 146 pyrrhotite -4.26 -5.60 -1.34 -0.447 0.22906E+04 147 pyrrhotiteFe0.875 -6.02 -7.00 -0.98 -0.361 0.16779E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22353E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84952E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28660E+03 154 rhodochrosite -0.98 -4.43 -3.46 -1.153 0.59039E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23156E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.95 -4.34 -1.446 0.74065E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27813E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.34 -2.75 -0.393 0.46946E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90658E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77514E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65441E+04 184 troilite-low -4.41 -5.60 -1.19 -0.397 0.20335E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79435E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34149E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66602E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60590E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66172E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68811E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73670E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60359E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58210E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83480E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62080E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66548E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53289E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35290E+04 234 alabandite -0.98 -3.09 -2.11 -0.704 0.36064E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52533E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1239900 MOLES New total amount of reactant added: 0.1279900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1279900 Water: Moles liquid = 0.2768E+02 kg liquid = 0.4987E+00 Moles total = -.7064E+01 kg total = -.1273E+00 Activity = 0.9997 Stoichiometric ionic strength = .5226852E-03 Osmotic coef. = 0.9793 True ionic strength = .2588869E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.8930E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11214E-09 -9.9502 0.92645E-10 -10.0332 0.82615E+00 -0.0829 2 H2O 0.99968E+00 -0.0001 0.99968E+00 -0.0001 3 Cl- 0.17808E-02 -2.7494 0.14604E-02 -2.8355 0.82010E+00 -0.0861 4 SO4-- 0.13469E-09 -9.8707 0.65206E-10 -10.1857 0.48411E+00 -0.3151 5 HCO3- 0.28282E-03 -3.5485 0.23236E-03 -3.6338 0.82156E+00 -0.0854 6 HS- 0.62866E-02 -2.2016 0.51565E-02 -2.2876 0.82024E+00 -0.0861 7 Al+++ 0.22172E-28 -28.6542 0.43629E-29 -29.3602 0.19677E+00 -0.7060 8 H4SiO4 0.69573E-03 -3.1576 0.69573E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.22619E-06 -6.6455 0.10851E-06 -6.9645 0.47976E+00 -0.3190 10 Mg++ 0.35420E-10 -10.4508 0.16898E-10 -10.7722 0.47708E+00 -0.3214 11 Fe++ 0.97627E-13 -13.0104 0.46638E-13 -13.3313 0.47772E+00 -0.3208 12 K+ 0.19878E-03 -3.7016 0.16336E-03 -3.7869 0.82179E+00 -0.0852 13 Na+ 0.25235E-01 -1.5980 0.20691E-01 -1.6842 0.81990E+00 -0.0862 14 Mn++ 0.31707E-10 -10.4988 0.15162E-10 -10.8192 0.47820E+00 -0.3204 15 F- 0.93921E-06 -6.0272 0.76832E-06 -6.1145 0.81805E+00 -0.0872 16 HPO4-- 0.31176E-07 -7.5062 0.15095E-07 -7.8212 0.48419E+00 -0.3150 18 HSiO3- 0.85530E-02 -2.0679 0.70143E-02 -2.1540 0.82010E+00 -0.0861 19 Ca(HSiO3)+ 0.21088E-07 -7.6760 0.17334E-07 -7.7611 0.82201E+00 -0.0851 20 Mg(HSiO3)+ 0.40868E-11 -11.3886 0.33594E-11 -11.4737 0.82201E+00 -0.0851 21 NaHSiO3,aq 0.23473E-02 -2.6294 0.23473E-02 -2.6294 0.10000E+01 0.0000 22 AlO+ 0.84098E-16 -16.0752 0.69129E-16 -16.1603 0.82201E+00 -0.0851 24 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.43375E-05 -5.3628 0.35494E-05 -5.4499 0.81830E+00 -0.0871 26 CH4,aq 0.17846E-01 -1.7485 0.17843E-01 -1.7485 0.99984E+00 -0.0001 27 C2H6,aq 0.47016E-08 -8.3278 0.47009E-08 -8.3278 0.99984E+00 -0.0001 28 C3H8,aq 0.28597E-13 -13.5437 0.28592E-13 -13.5437 0.99984E+00 -0.0001 29 C4H10,aq 0.17087E-18 -18.7673 0.17084E-18 -18.7674 0.99984E+00 -0.0001 30 ethanol,aq 0.17257E-15 -15.7630 0.17254E-15 -15.7631 0.99984E+00 -0.0001 31 CO,aq 0.13388E-13 -13.8733 0.13388E-13 -13.8733 0.10000E+01 0.0000 32 CO2,aq 0.46020E-07 -7.3371 0.46012E-07 -7.3371 0.99984E+00 -0.0001 33 CO3-2 0.45369E-03 -3.3432 0.21907E-03 -3.6594 0.48286E+00 -0.3162 34 CaCO3,aq 0.29807E-06 -6.5257 0.29807E-06 -6.5257 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.78297E-09 -9.1063 0.64361E-09 -9.1914 0.82201E+00 -0.0851 36 CaCl+ 0.31200E-09 -9.5059 0.25646E-09 -9.5910 0.82201E+00 -0.0851 37 CaCl2,aq 0.88983E-13 -13.0507 0.88983E-13 -13.0507 0.10000E+01 0.0000 38 CaF+ 0.14808E-11 -11.8295 0.12173E-11 -11.9146 0.82201E+00 -0.0851 39 CaOH+ 0.10152E-06 -6.9934 0.83450E-07 -7.0786 0.82201E+00 -0.0851 40 CaSO4,aq 0.22469E-14 -14.6484 0.22469E-14 -14.6484 0.10000E+01 0.0000 41 HCl,aq 0.24793E-13 -13.6057 0.24793E-13 -13.6057 0.10000E+01 0.0000 45 HF,aq 0.48728E-12 -12.3122 0.48728E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.15413E-18 -18.8121 0.12640E-18 -18.8982 0.82010E+00 -0.0861 48 FeCl+ 0.13115E-15 -15.8822 0.10781E-15 -15.9673 0.82201E+00 -0.0851 51 FeF+ 0.22276E-17 -17.6522 0.18311E-17 -17.7373 0.82201E+00 -0.0851 53 FeO,aq 0.21111E-09 -9.6755 0.21111E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.19928E-10 -10.7005 0.16381E-10 -10.7857 0.82201E+00 -0.0851 55 HFeO2- 0.29064E-07 -7.5366 0.23835E-07 -7.6228 0.82010E+00 -0.0861 56 FeO+ 0.13969E-16 -16.8548 0.11483E-16 -16.9400 0.82201E+00 -0.0851 58 FeO2- 0.33369E-09 -9.4767 0.27365E-09 -9.5628 0.82010E+00 -0.0861 59 HFeO2,aq 0.32245E-11 -11.4915 0.32245E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11580E-04 -4.9363 0.11579E-04 -4.9363 0.99984E+00 -0.0001 61 KCl,aq 0.43239E-08 -8.3641 0.43239E-08 -8.3641 0.10000E+01 0.0000 63 KOH,aq 0.75278E-06 -6.1233 0.75278E-06 -6.1233 0.10000E+01 0.0000 64 KSO4- 0.20155E-12 -12.6956 0.16529E-12 -12.7817 0.82010E+00 -0.0861 65 MgCO3,aq 0.11635E-10 -10.9343 0.11635E-10 -10.9343 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12459E-12 -12.9045 0.10241E-12 -12.9897 0.82201E+00 -0.0851 67 MgCl+ 0.44035E-13 -13.3562 0.36197E-13 -13.4413 0.82201E+00 -0.0851 68 MgF+ 0.85421E-15 -15.0684 0.70217E-15 -15.1536 0.82201E+00 -0.0851 69 MgOH+ 0.87479E-10 -10.0581 0.71908E-10 -10.1432 0.82201E+00 -0.0851 71 MnF+ 0.23871E-15 -15.6221 0.19622E-15 -15.7073 0.82201E+00 -0.0851 72 MnO,aq 0.18288E-08 -8.7378 0.18288E-08 -8.7378 0.10000E+01 0.0000 73 MnOH+ 0.60185E-09 -9.2205 0.49473E-09 -9.3056 0.82201E+00 -0.0851 74 MnO2-2 0.14640E-10 -10.8345 0.70690E-11 -11.1506 0.48286E+00 -0.3162 75 HMnO2- 0.17495E-09 -9.7571 0.14348E-09 -9.8432 0.82010E+00 -0.0861 78 MnCl+ 0.16588E-12 -12.7802 0.13636E-12 -12.8653 0.82201E+00 -0.0851 79 MnSO4,aq 0.28542E-18 -18.5445 0.28542E-18 -18.5445 0.10000E+01 0.0000 80 NaCl,aq 0.10014E-04 -4.9994 0.10014E-04 -4.9994 0.10000E+01 0.0000 81 NaF,aq 0.37217E-08 -8.4293 0.37217E-08 -8.4293 0.10000E+01 0.0000 82 NaOH,aq 0.95923E-04 -4.0181 0.95923E-04 -4.0181 0.10000E+01 0.0000 84 OH- 0.76188E-02 -2.1181 0.62344E-02 -2.2052 0.81830E+00 -0.0871 89 HPO3-2 0.11284E-14 -14.9475 0.54485E-15 -15.2637 0.48286E+00 -0.3162 91 H2PO3- 0.12343E-18 -18.9086 0.10122E-18 -18.9947 0.82010E+00 -0.0861 92 H3PO4,aq 0.90617E-18 -18.0428 0.90617E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.31422E-10 -10.5028 0.25799E-10 -10.5884 0.82104E+00 -0.0856 94 PO4-3 0.63632E-09 -9.1963 0.13294E-09 -9.8764 0.20892E+00 -0.6800 98 HP2O7-3 0.57103E-18 -18.2433 0.11251E-18 -18.9488 0.19704E+00 -0.7055 99 P2O7-4 0.49712E-17 -17.3035 0.29013E-18 -18.5374 0.58362E-01 -1.2339 100 H2S,aq 0.14767E-05 -5.8307 0.14765E-05 -5.8308 0.99984E+00 -0.0001 101 S2-2 0.10538E-09 -9.9772 0.50885E-10 -10.2934 0.48286E+00 -0.3162 102 S3-2 0.18105E-16 -16.7422 0.87421E-17 -17.0584 0.48286E+00 -0.3162 107 SO3-2 0.19973E-15 -15.6996 0.98142E-16 -16.0081 0.49138E+00 -0.3086 108 HSO3- 0.69418E-18 -18.1585 0.56930E-18 -18.2447 0.82010E+00 -0.0861 109 HSO4- 0.70740E-17 -17.1503 0.58218E-17 -17.2349 0.82299E+00 -0.0846 111 S2O3-2 0.23429E-17 -17.6302 0.11313E-17 -17.9464 0.48286E+00 -0.3162 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1121410E-09 -.1908865E-01 -.1919638E+02 0.0000 2 H2O 0.1000000E+01 0.5552293E+02 0.9979837E+06 0.0000 3 Cl- 0.1780787E-02 0.1790806E-02 0.6334481E+02 7.1977 4 SO4-- 0.1346926E-09 -.1784909E-01 -.1710706E+04 9.8806 5 HCO3- 0.2828219E-03 0.1858305E-01 0.1131303E+04 6.3993 6 HS- 0.6286614E-02 0.2413718E-01 0.7964464E+03 7.7455 7 Al+++ 0.2217214E-28 0.4337635E-05 0.1167693E+00 0.7393 8 H4SiO4 0.6957295E-03 0.1159604E-01 0.1112019E+04 -3.1576 9 Ca++ 0.2261854E-06 0.6479582E-06 0.2590971E-01 13.1018 10 Mg++ 0.3541992E-10 0.1387892E-09 0.3366556E-05 9.2942 11 Fe++ 0.9762683E-13 0.2963188E-07 0.1651082E-02 6.7351 12 K+ 0.1987848E-03 0.1995419E-03 0.7784712E+01 6.2463 13 Na+ 0.2523538E-01 0.2768860E-01 0.6351053E+03 8.3489 14 Mn++ 0.3170700E-10 0.2652144E-08 0.1453716E-03 9.2471 15 F- 0.9392096E-06 0.9429333E-06 0.1787304E-01 3.9187 16 HPO4-- 0.3117612E-07 0.3184386E-07 0.3049379E-02 12.2452 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277877E+02 -.9518873E-02 -.8276925E+02 0.0000000E+00 2 H2O -.7064003E+01 0.2768744E+02 -.3475144E+02 0.0000000E+00 3 Cl- 0.8930152E-03 0.8930152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1392037E+00 -.8900746E-02 0.1481044E+00 0.0000000E+00 5 HCO3- 0.9266747E-02 0.9266747E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1360680E+00 0.1203641E-01 -.1481044E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2163034E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5782558E-02 0.5205812E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.3231152E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6920953E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1477643E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9950487E-04 0.1061471E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1380738E-01 0.6262570E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1322536E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5129600E-04 0.4702094E-06 0.5082579E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1587947E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.2057E-13 Mass of aqueous solution: 0.499805E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1279900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.247 0.796 1638. 3.214 29.99 628.8 andradite 0.5924 -0.227 301.1 2.479 5.511 78.22 grossular 0.1435 -0.843 64.64 1.810 1.183 17.98 apatite-OH 0.9812E-02 -2.008 4.929 0.693 0.9023E-01 1.566 apatite-F 0.5083E-04 -4.294 0.2563E-01 -1.591 0.4692E-03 0.8007E-02 clinochlore 0.7013 -0.154 389.8 2.591 7.136 148.3 daphnite 0.2031 -0.692 144.9 2.161 2.653 43.91 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1512E-01 -1.820 3.275 0.515 0.5996E-01 1.001 hedenbergite 0.3923E-02 -2.406 0.9733 -0.012 0.1782E-01 0.2666 microcline 0.9408 -0.027 261.9 2.418 4.794 102.3 stilbite 3.228 0.509 2275. 3.357 41.65 1061. stilpnomelane-Fe 0.2414 -0.617 260.2 2.415 4.764 89.88 tr.625ac.25prg.125 0.1232 -0.909 105.3 2.023 1.928 33.90 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1881E-01 0.1881E-01 1.0000 -1.726 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.369183 g Volume = 2211.132994 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1279900 moles log = -0.8928 Original solution: 1000.0103000 g Original solution / Rock added: 7813.19 (Water/Rock Ratio), log = 3.8928 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 27.7793 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3838E-01 0.9432 0.1006E+01 0.1066E+01 CO2,gas 0.1861E-06 0.9521 0.4923E-05 0.5170E-05 CH4,gas 0.9611E+00 0.9837 0.2626E+02 0.2670E+02 H2,gas 0.5392E-03 1.0149 0.1520E-01 0.1498E-01 H2S,gas 0.1624E-05 0.8995 0.4059E-04 0.4512E-04 S2,gas 0.9633E-26 1.0000 0.2676E-24 0.2676E-24 CO,gas 0.7182E-12 1.0000 0.1995E-10 0.1995E-10 SO3,gas 0.7620E-47 1.0000 0.2117E-45 0.2117E-45 SO2,gas 0.4508E-26 1.0000 0.1252E-24 0.1252E-24 HF,gas 0.4307E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1575E-17 1.0000 0.4375E-16 0.4375E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 70 diopside 16.18 16.18 0.00 0.000 0.60662E-11 71 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.67 -7.01 -2.336 0.11964E+05 -5.308 3 CH4,gas 4.54 4.26 -0.28 -0.070 0.47742E+03 1.419 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60053E+04 -1.818 5 H2S,gas -6.23 -12.32 -6.09 -3.045 0.10399E+05 -4.392 6 S2,gas -7.34 -33.61 -26.27 -4.042 0.44858E+05 -24.573 7 CO,gas 3.21 -9.18 -12.40 -3.815 0.21171E+05 -10.700 8 SO3,gas 17.12 -30.25 -47.37 -11.843 0.80889E+05 -45.674 9 SO2,gas 0.83 -25.77 -26.60 -7.094 0.45421E+05 -24.902 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.87 -18.06 -9.029 0.30834E+05 -16.359 12 acmite 7.71 6.53 -1.18 -0.123 0.20180E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.75 -4.71 -0.236 0.80423E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93670E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41068E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28499E+04 30 anorthite 12.71 8.27 -4.44 -0.342 0.75897E+04 38 aragonite 0.97 -0.57 -1.53 -0.511 0.26153E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55914E+04 40 calcite 0.81 -0.57 -1.38 -0.459 0.23511E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52805E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71075E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82203E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39700E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68952E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65453E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13339E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.70 -1.60 -0.457 0.27300E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65862E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68198E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57037E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37139E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.70 -1.16 -0.330 0.19723E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24619E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64130E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58875E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28626E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48023E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82149E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41129E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36687E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19846E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91145E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40576E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 145 pyrite -21.25 -22.39 -1.14 -0.269 0.19504E+04 146 pyrrhotite -4.26 -5.59 -1.33 -0.442 0.22631E+04 147 pyrrhotiteFe0.875 -6.02 -6.98 -0.97 -0.355 0.16503E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22350E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84951E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28659E+03 154 rhodochrosite -0.98 -4.42 -3.44 -1.148 0.58798E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23153E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.93 -4.32 -1.441 0.73827E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27814E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21141E+04 177 tephroite 18.09 15.34 -2.75 -0.393 0.46940E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90657E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77515E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65440E+04 184 troilite-low -4.41 -5.59 -1.17 -0.392 0.20059E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79435E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34149E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66602E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55682E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60589E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66172E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68810E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73670E+04 207 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60359E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58210E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83480E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62080E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66548E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53289E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35290E+04 234 alabandite -0.98 -3.07 -2.10 -0.699 0.35786E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52533E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1279900 MOLES New total amount of reactant added: 0.1319900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8666E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1319900 Water: Moles liquid = 0.2768E+02 kg liquid = 0.4987E+00 Moles total = -.7061E+01 kg total = -.1272E+00 Activity = 0.9997 Stoichiometric ionic strength = .1777937E-03 Osmotic coef. = 0.9877 True ionic strength = .2607146E-01 Chg. balance for total moles = -.8666E-10 Max. difference allowed = 0.9166E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11290E-09 -9.9473 0.93231E-10 -10.0304 0.82575E+00 -0.0832 2 H2O 0.99967E+00 -0.0001 0.99967E+00 -0.0001 3 Cl- 0.18275E-02 -2.7381 0.14980E-02 -2.8245 0.81967E+00 -0.0864 4 SO4-- 0.13818E-09 -9.8596 0.66760E-10 -10.1755 0.48314E+00 -0.3159 5 HCO3- 0.29006E-03 -3.5375 0.23818E-03 -3.6231 0.82114E+00 -0.0856 6 HS- 0.64805E-02 -2.1884 0.53128E-02 -2.2747 0.81982E+00 -0.0863 7 Al+++ 0.22699E-28 -28.6440 0.44462E-29 -29.3520 0.19587E+00 -0.7080 8 H4SiO4 0.69572E-03 -3.1576 0.69572E-03 -3.1576 0.10000E+01 0.0000 9 Ca++ 0.22952E-06 -6.6392 0.10989E-06 -6.9590 0.47877E+00 -0.3199 10 Mg++ 0.35944E-10 -10.4444 0.17112E-10 -10.7667 0.47609E+00 -0.3223 11 Fe++ 0.99071E-13 -13.0041 0.47230E-13 -13.3258 0.47673E+00 -0.3217 12 K+ 0.20014E-03 -3.6987 0.16439E-03 -3.7841 0.82137E+00 -0.0855 13 Na+ 0.25407E-01 -1.5950 0.20821E-01 -1.6815 0.81947E+00 -0.0865 14 Mn++ 0.32189E-10 -10.4923 0.15361E-10 -10.8136 0.47721E+00 -0.3213 15 F- 0.93380E-06 -6.0297 0.76348E-06 -6.1172 0.81761E+00 -0.0875 16 HPO4-- 0.30847E-07 -7.5108 0.14906E-07 -7.8266 0.48322E+00 -0.3159 18 HSiO3- 0.85037E-02 -2.0704 0.69702E-02 -2.1568 0.81967E+00 -0.0864 19 Ca(HSiO3)+ 0.21232E-07 -7.6730 0.17444E-07 -7.7584 0.82159E+00 -0.0853 20 Mg(HSiO3)+ 0.41147E-11 -11.3857 0.33806E-11 -11.4710 0.82159E+00 -0.0853 21 NaHSiO3,aq 0.23472E-02 -2.6295 0.23472E-02 -2.6295 0.10000E+01 0.0000 22 AlO+ 0.84674E-16 -16.0722 0.69567E-16 -16.1576 0.82159E+00 -0.0853 24 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 25 AlO2- 0.43125E-05 -5.3653 0.35271E-05 -5.4526 0.81786E+00 -0.0873 26 CH4,aq 0.18407E-01 -1.7350 0.18406E-01 -1.7350 0.99994E+00 0.0000 27 C2H6,aq 0.50022E-08 -8.3008 0.50019E-08 -8.3009 0.99994E+00 0.0000 28 C3H8,aq 0.31385E-13 -13.5033 0.31383E-13 -13.5033 0.99994E+00 0.0000 29 C4H10,aq 0.19344E-18 -18.7135 0.19343E-18 -18.7135 0.99994E+00 0.0000 30 ethanol,aq 0.18360E-15 -15.7361 0.18359E-15 -15.7361 0.99994E+00 0.0000 31 CO,aq 0.13810E-13 -13.8598 0.13810E-13 -13.8598 0.10000E+01 0.0000 32 CO2,aq 0.47466E-07 -7.3236 0.47463E-07 -7.3236 0.99994E+00 0.0000 33 CO3-2 0.46306E-03 -3.3344 0.22314E-03 -3.6514 0.48188E+00 -0.3171 34 CaCO3,aq 0.30747E-06 -6.5122 0.30747E-06 -6.5122 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.81318E-09 -9.0898 0.66810E-09 -9.1752 0.82159E+00 -0.0853 36 CaCl+ 0.32424E-09 -9.4891 0.26639E-09 -9.5745 0.82159E+00 -0.0853 37 CaCl2,aq 0.94805E-13 -13.0232 0.94805E-13 -13.0232 0.10000E+01 0.0000 38 CaF+ 0.14909E-11 -11.8265 0.12249E-11 -11.9119 0.82159E+00 -0.0853 39 CaOH+ 0.10221E-06 -6.9905 0.83977E-07 -7.0758 0.82159E+00 -0.0853 40 CaSO4,aq 0.23296E-14 -14.6327 0.23296E-14 -14.6327 0.10000E+01 0.0000 41 HCl,aq 0.25591E-13 -13.5919 0.25591E-13 -13.5919 0.10000E+01 0.0000 45 HF,aq 0.48728E-12 -12.3122 0.48728E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.15324E-18 -18.8146 0.12561E-18 -18.9010 0.81967E+00 -0.0864 48 FeCl+ 0.13630E-15 -15.8655 0.11198E-15 -15.9508 0.82159E+00 -0.0853 51 FeF+ 0.22428E-17 -17.6492 0.18427E-17 -17.7346 0.82159E+00 -0.0853 53 FeO,aq 0.21111E-09 -9.6755 0.21111E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.20064E-10 -10.6976 0.16485E-10 -10.7829 0.82159E+00 -0.0853 55 HFeO2- 0.28896E-07 -7.5392 0.23685E-07 -7.6255 0.81967E+00 -0.0864 56 FeO+ 0.14064E-16 -16.8519 0.11555E-16 -16.9372 0.82159E+00 -0.0853 58 FeO2- 0.33176E-09 -9.4792 0.27193E-09 -9.5655 0.81967E+00 -0.0864 59 HFeO2,aq 0.32245E-11 -11.4915 0.32245E-11 -11.4915 0.10000E+01 0.0000 60 H2,aq 0.11579E-04 -4.9363 0.11578E-04 -4.9363 0.99994E+00 0.0000 61 KCl,aq 0.44630E-08 -8.3504 0.44630E-08 -8.3504 0.10000E+01 0.0000 63 KOH,aq 0.75275E-06 -6.1234 0.75275E-06 -6.1234 0.10000E+01 0.0000 64 KSO4- 0.20777E-12 -12.6824 0.17030E-12 -12.7688 0.81967E+00 -0.0864 65 MgCO3,aq 0.12001E-10 -10.9208 0.12001E-10 -10.9208 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12939E-12 -12.8881 0.10631E-12 -12.9734 0.82159E+00 -0.0853 67 MgCl+ 0.45763E-13 -13.3395 0.37598E-13 -13.4248 0.82159E+00 -0.0853 68 MgF+ 0.86004E-15 -15.0655 0.70660E-15 -15.1508 0.82159E+00 -0.0853 69 MgOH+ 0.88076E-10 -10.0551 0.72362E-10 -10.1405 0.82159E+00 -0.0853 71 MnF+ 0.24043E-15 -15.6190 0.19754E-15 -15.7044 0.82159E+00 -0.0853 72 MnO,aq 0.18295E-08 -8.7377 0.18295E-08 -8.7377 0.10000E+01 0.0000 73 MnOH+ 0.60621E-09 -9.2174 0.49805E-09 -9.3027 0.82159E+00 -0.0853 74 MnO2-2 0.14491E-10 -10.8389 0.69831E-11 -11.1559 0.48188E+00 -0.3171 75 HMnO2- 0.17401E-09 -9.7594 0.14263E-09 -9.8458 0.81967E+00 -0.0864 78 MnCl+ 0.17246E-12 -12.7633 0.14169E-12 -12.8486 0.82159E+00 -0.0853 79 MnSO4,aq 0.29605E-18 -18.5286 0.29605E-18 -18.5286 0.10000E+01 0.0000 80 NaCl,aq 0.10336E-04 -4.9856 0.10336E-04 -4.9856 0.10000E+01 0.0000 81 NaF,aq 0.37216E-08 -8.4293 0.37216E-08 -8.4293 0.10000E+01 0.0000 82 NaOH,aq 0.95919E-04 -4.0181 0.95919E-04 -4.0181 0.10000E+01 0.0000 84 OH- 0.75749E-02 -2.1206 0.61952E-02 -2.2079 0.81786E+00 -0.0873 89 HPO3-2 0.11165E-14 -14.9521 0.53803E-15 -15.2692 0.48188E+00 -0.3171 91 H2PO3- 0.12272E-18 -18.9111 0.10059E-18 -18.9975 0.81967E+00 -0.0864 92 H3PO4,aq 0.90617E-18 -18.0428 0.90617E-18 -18.0428 0.10000E+01 0.0000 93 H2PO4- 0.31240E-10 -10.5053 0.25637E-10 -10.5911 0.82062E+00 -0.0859 94 PO4-3 0.62706E-09 -9.2027 0.13045E-09 -9.8846 0.20803E+00 -0.6819 98 HP2O7-3 0.56291E-18 -18.2496 0.11041E-18 -18.9570 0.19614E+00 -0.7074 99 P2O7-4 0.48861E-17 -17.3110 0.28291E-18 -18.5483 0.57901E-01 -1.2373 100 H2S,aq 0.15309E-05 -5.8150 0.15309E-05 -5.8151 0.99994E+00 0.0000 101 S2-2 0.11210E-09 -9.9504 0.54017E-10 -10.2675 0.48188E+00 -0.3171 102 S3-2 0.19968E-16 -16.6997 0.96220E-17 -17.0167 0.48188E+00 -0.3171 107 SO3-2 0.20488E-15 -15.6885 0.10048E-15 -15.9979 0.49044E+00 -0.3094 108 HSO3- 0.71560E-18 -18.1453 0.58655E-18 -18.2317 0.81967E+00 -0.0864 109 HSO4- 0.72921E-17 -17.1372 0.59983E-17 -17.2220 0.82258E+00 -0.0848 111 S2O3-2 0.24921E-17 -17.6034 0.12009E-17 -17.9205 0.48188E+00 -0.3171 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1129043E-09 -.1900458E-01 -.1911150E+02 0.0000 2 H2O 0.1000000E+01 0.5552350E+02 0.9979764E+06 0.0000 3 Cl- 0.1827523E-02 0.1837864E-02 0.6500823E+02 7.2059 4 SO4-- 0.1381800E-09 -.1840962E-01 -.1764398E+04 9.8854 5 HCO3- 0.2900556E-03 0.1916020E-01 0.1166418E+04 6.4073 6 HS- 0.6480535E-02 0.2489169E-01 0.8213282E+03 7.7558 7 Al+++ 0.2269950E-28 0.4312696E-05 0.1160959E+00 0.7393 8 H4SiO4 0.6957217E-03 0.1154664E-01 0.1107263E+04 -3.1576 9 Ca++ 0.2295244E-06 0.6615758E-06 0.2645377E-01 13.1018 10 Mg++ 0.3594385E-10 0.1403102E-09 0.3403393E-05 9.2942 11 Fe++ 0.9907108E-13 0.2946221E-07 0.1641599E-02 6.7351 12 K+ 0.2001373E-03 0.2008946E-03 0.7837348E+01 6.2463 13 Na+ 0.2540741E-01 0.2786087E-01 0.6390455E+03 8.3489 14 Mn++ 0.3218866E-10 0.2656617E-08 0.1456142E-03 9.2473 15 F- 0.9337980E-06 0.9375216E-06 0.1777015E-01 3.9132 16 HPO4-- 0.3084732E-07 0.3150563E-07 0.3016937E-02 12.2342 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277834E+02 -.9478331E-02 -.8276886E+02 0.0000000E+00 2 H2O -.7060729E+01 0.2769175E+02 -.3475248E+02 0.0000000E+00 3 Cl- 0.9166152E-03 0.9166152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1392228E+00 -.9181603E-02 0.1484044E+00 0.0000000E+00 5 HCO3- 0.9555947E-02 0.9555947E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1359899E+00 0.1241446E-01 -.1484044E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2150911E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5758765E-02 0.5205815E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.3299539E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6997825E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1469396E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1001940E-03 0.1061471E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1389531E-01 0.6262482E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1324960E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5289600E-04 0.4675790E-06 0.5242842E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1571310E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1027E-13 Mass of aqueous solution: 0.499887E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1319900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.247 0.796 1638. 3.214 29.99 628.8 andradite 0.5936 -0.226 301.7 2.480 5.523 78.37 grossular 0.1438 -0.842 64.77 1.811 1.186 18.02 apatite-OH 0.9810E-02 -2.008 4.928 0.693 0.9021E-01 1.566 apatite-F 0.5243E-04 -4.280 0.2644E-01 -1.578 0.4840E-03 0.8260E-02 clinochlore 0.7010 -0.154 389.6 2.591 7.133 148.2 daphnite 0.2030 -0.693 144.8 2.161 2.652 43.89 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.7306E-02 -2.136 1.582 0.199 0.2897E-01 0.4836 hedenbergite 0.1895E-02 -2.722 0.4702 -0.328 0.8609E-02 0.1288 microcline 0.9411 -0.026 261.9 2.418 4.795 102.3 stilbite 3.228 0.509 2275. 3.357 41.65 1061. stilpnomelane-Fe 0.2407 -0.618 259.5 2.414 4.751 89.64 tr.625ac.25prg.125 0.1258 -0.900 107.5 2.031 1.968 34.60 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1882E-01 0.1882E-01 1.0000 -1.725 diopside 0.7940E+00 0.7940E+00 1.0000 -0.100 hedenbergite 0.2060E+00 0.2060E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.369915 g Volume = 2211.144175 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1319900 moles log = -0.8795 Original solution: 1000.0103000 g Original solution / Rock added: 7576.41 (Water/Rock Ratio), log = 3.8795 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 28.6360 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3727E-01 0.9422 0.1006E+01 0.1067E+01 CO2,gas 0.1865E-06 0.9508 0.5078E-05 0.5341E-05 CH4,gas 0.9622E+00 0.9832 0.2709E+02 0.2755E+02 H2,gas 0.5228E-03 1.0154 0.1520E-01 0.1497E-01 H2S,gas 0.1639E-05 0.8967 0.4208E-04 0.4693E-04 S2,gas 0.1005E-25 1.0000 0.2877E-24 0.2877E-24 CO,gas 0.7187E-12 1.0000 0.2058E-10 0.2058E-10 SO3,gas 0.7664E-47 1.0000 0.2195E-45 0.2195E-45 SO2,gas 0.4534E-26 1.0000 0.1298E-24 0.1298E-24 HF,gas 0.4178E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1577E-17 1.0000 0.4516E-16 0.4516E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 70 diopside 16.18 16.18 0.00 0.000 0.12132E-10 71 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.65 -6.99 -2.331 0.11941E+05 -5.294 3 CH4,gas 4.54 4.28 -0.27 -0.067 0.45441E+03 1.433 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60053E+04 -1.818 5 H2S,gas -6.23 -12.31 -6.07 -3.037 0.10373E+05 -4.376 6 S2,gas -7.34 -33.58 -26.24 -4.037 0.44804E+05 -24.541 7 CO,gas 3.21 -9.17 -12.39 -3.811 0.21148E+05 -10.687 8 SO3,gas 17.12 -30.24 -47.36 -11.839 0.80862E+05 -45.659 9 SO2,gas 0.83 -25.75 -26.59 -7.089 0.45394E+05 -24.887 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.85 -18.04 -9.022 0.30810E+05 -16.345 12 acmite 7.71 6.53 -1.18 -0.123 0.20180E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.75 -4.71 -0.235 0.80414E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93671E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41068E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28499E+04 30 anorthite 12.71 8.27 -4.44 -0.342 0.75897E+04 38 aragonite 0.97 -0.55 -1.52 -0.506 0.25923E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55914E+04 40 calcite 0.81 -0.55 -1.36 -0.454 0.23281E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52805E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71075E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82203E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39700E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68952E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70312E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65450E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13339E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10193E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 69 diamond -3.10 -4.69 -1.59 -0.453 0.27070E+04 74 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 76 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83542E+04 78 epidote 24.67 22.70 -1.97 -0.095 0.33581E+04 79 clinozoisite 22.81 18.95 -3.86 -0.175 0.65861E+04 80 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57766E+04 81 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68198E+04 86 gibbsite 4.08 0.74 -3.34 -0.477 0.57037E+04 87 glaucophane 22.97 20.80 -2.18 -0.059 0.37139E+04 88 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 89 graphite -3.55 -4.69 -1.14 -0.326 0.19492E+04 90 greenalite 16.14 13.89 -2.25 -0.187 0.38409E+04 93 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 98 jadeite 4.22 2.77 -1.44 -0.144 0.24620E+04 100 kalsilite 7.58 3.83 -3.76 -0.537 0.64130E+04 101 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 104 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 105 lawsonite 9.62 8.27 -1.35 -0.090 0.23068E+04 106 leucite 4.12 0.67 -3.45 -0.345 0.58875E+04 108 lizardite 23.24 21.57 -1.68 -0.140 0.28626E+04 110 magnetite 20.09 15.72 -4.37 -0.356 0.74537E+04 111 minnesotaite 10.39 7.58 -2.81 -0.165 0.48023E+04 115 manganosite 14.06 9.25 -4.81 -1.203 0.82146E+04 123 muscovite 2.58 -1.01 -3.59 -0.211 0.61313E+04 124 paragonite 4.24 1.09 -3.15 -0.185 0.53704E+04 125 nepheline 8.34 5.93 -2.41 -0.344 0.41129E+04 131 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 137 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36687E+04 139 prehnite 19.37 18.21 -1.16 -0.068 0.19845E+04 140 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91145E+03 141 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40576E+04 142 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 145 pyrite -21.25 -22.36 -1.11 -0.261 0.18968E+04 146 pyrrhotite -4.26 -5.57 -1.31 -0.437 0.22363E+04 147 pyrrhotiteFe0.875 -6.02 -6.97 -0.95 -0.350 0.16235E+04 148 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22347E+04 149 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84951E+04 150 quartz -2.99 -3.16 -0.17 -0.056 0.28658E+03 154 rhodochrosite -0.98 -4.41 -3.43 -1.143 0.58565E+04 155 rhodonite 7.45 6.09 -1.36 -0.271 0.23150E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.92 -4.31 -1.437 0.73597E+04 168 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27814E+04 174 talc 16.49 15.25 -1.24 -0.073 0.21142E+04 177 tephroite 18.09 15.34 -2.75 -0.393 0.46934E+04 181 tridymite -2.63 -3.16 -0.53 -0.177 0.90656E+03 182 tremolite 47.87 47.42 -0.45 -0.012 0.77516E+03 183 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65440E+04 184 troilite-low -4.41 -5.57 -1.16 -0.386 0.19791E+04 186 vesuvianite 223.47 218.82 -4.65 -0.036 0.79435E+04 190 wairakite 3.95 1.95 -2.00 -0.118 0.34149E+04 191 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 192 wollastonite 10.46 9.94 -0.52 -0.103 0.88230E+03 193 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 194 zoisite 22.85 18.95 -3.90 -0.177 0.66602E+04 195 akaganeite 7.75 4.49 -3.26 -0.705 0.55683E+04 202 chalcedony -2.80 -3.16 -0.35 -0.118 0.60588E+03 204 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66172E+04 205 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68810E+04 206 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73669E+04 207 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60359E+04 208 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58210E+04 209 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83480E+04 210 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62080E+04 211 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66548E+04 212 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53289E+04 228 tobermorite 9.82 7.76 -2.07 -0.564 0.35290E+04 234 alabandite -0.98 -3.06 -2.08 -0.693 0.35515E+04 237 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52533E+04 245 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18201E+04 247 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 248 an25ab75 2.65 1.78 -0.87 -0.067 0.14808E+04 249 an30ab70 3.28 2.21 -1.07 -0.082 0.18242E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1319900 MOLES New total amount of reactant added: 0.1359900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 400 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1359900 Water: Moles liquid = 0.2769E+02 kg liquid = 0.4988E+00 Moles total = -.7057E+01 kg total = -.1271E+00 Activity = 0.9996 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2597690E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.9402E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10778E-09 -9.9674 0.77752E-10 -10.1093 0.82592E+00 -0.0831 2 H2O 0.99964E+00 -0.0002 0.99965E+00 -0.0002 3 Cl- 0.18741E-02 -2.7272 0.15137E-02 -2.8199 0.81985E+00 -0.0863 4 SO4-- 0.44558E-10 -10.3511 0.10113E-10 -10.9951 0.48362E+00 -0.3155 5 HCO3- 0.97382E-04 -4.0115 0.37867E-04 -4.4217 0.82132E+00 -0.0855 6 HS- 0.66733E-02 -2.1757 0.53910E-02 -2.2683 0.82000E+00 -0.0862 7 Al+++ 0.20353E-28 -28.6914 0.31199E-29 -29.5059 0.19633E+00 -0.7070 8 H4SiO4 0.67774E-03 -3.1689 0.61755E-03 -3.2093 0.10000E+01 0.0000 9 Ca++ 0.22930E-06 -6.6396 0.11779E-06 -6.9289 0.47926E+00 -0.3194 10 Mg++ 0.31550E-10 -10.5010 0.11156E-10 -10.9525 0.47658E+00 -0.3219 11 Fe++ 0.91591E-13 -13.0381 0.35960E-13 -13.4442 0.47722E+00 -0.3213 12 K+ 0.19812E-03 -3.7031 0.16083E-03 -3.7936 0.82155E+00 -0.0854 13 Na+ 0.25151E-01 -1.5994 0.20371E-01 -1.6910 0.81966E+00 -0.0864 14 Mn++ 0.29050E-10 -10.5368 0.11866E-10 -10.9257 0.47770E+00 -0.3208 15 F- 0.95994E-06 -6.0178 0.89883E-06 -6.0463 0.81780E+00 -0.0874 16 HPO4-- 0.27897E-07 -7.5544 0.10107E-07 -7.9954 0.48370E+00 -0.3154 18 HSiO3- 0.86739E-02 -2.0618 0.74189E-02 -2.1297 0.81985E+00 -0.0863 19 Ca(HSiO3)+ 0.21658E-07 -7.6644 0.19901E-07 -7.7011 0.82177E+00 -0.0853 20 Mg(HSiO3)+ 0.36878E-11 -11.4332 0.23458E-11 -11.6297 0.82177E+00 -0.0853 21 NaHSiO3,aq 0.23711E-02 -2.6251 0.24443E-02 -2.6118 0.10000E+01 0.0000 22 AlO+ 0.83444E-16 -16.0786 0.70184E-16 -16.1538 0.82177E+00 -0.0853 24 HAlO2,aq 0.15335E-09 -9.8143 0.17970E-09 -9.7455 0.10000E+01 0.0000 25 AlO2- 0.46613E-05 -5.3315 0.51160E-05 -5.2911 0.81805E+00 -0.0872 26 CH4,aq 0.19722E-01 -1.7050 0.19600E-01 -1.7077 0.10000E+01 0.0000 27 C2H6,aq 0.42477E-08 -8.3718 0.33694E-08 -8.4724 0.10000E+01 0.0000 28 C3H8,aq 0.21122E-13 -13.6753 0.13373E-13 -13.8738 0.10000E+01 0.0000 29 C4H10,aq 0.10317E-18 -18.9864 0.52141E-19 -19.2828 0.10000E+01 0.0000 30 ethanol,aq 0.11531E-15 -15.9381 0.73464E-16 -16.1339 0.10000E+01 0.0000 31 CO,aq 0.59871E-14 -14.2228 0.30826E-14 -14.5111 0.10000E+01 0.0000 32 CO2,aq 0.15219E-07 -7.8176 0.62933E-08 -8.2011 0.10000E+01 0.0000 33 CO3-2 0.16269E-03 -3.7886 0.42539E-04 -4.3712 0.48236E+00 -0.3166 34 CaCO3,aq 0.10814E-06 -6.9660 0.62827E-07 -7.2019 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.27302E-09 -9.5638 0.11385E-09 -9.9437 0.82177E+00 -0.0853 36 CaCl+ 0.33251E-09 -9.4782 0.28854E-09 -9.5398 0.82177E+00 -0.0853 37 CaCl2,aq 0.99745E-13 -13.0011 0.10377E-12 -12.9839 0.10000E+01 0.0000 38 CaF+ 0.15327E-11 -11.8145 0.15457E-11 -11.8109 0.82177E+00 -0.0853 39 CaOH+ 0.10702E-06 -6.9705 0.10793E-06 -6.9669 0.82177E+00 -0.0853 40 CaSO4,aq 0.75198E-15 -15.1238 0.37827E-15 -15.4222 0.10000E+01 0.0000 41 HCl,aq 0.25064E-13 -13.6010 0.21567E-13 -13.6662 0.10000E+01 0.0000 45 HF,aq 0.47841E-12 -12.3202 0.47842E-12 -12.3202 0.10000E+01 0.0000 46 HF2- 0.15466E-18 -18.8106 0.14518E-18 -18.8381 0.81985E+00 -0.0863 48 FeCl+ 0.12935E-15 -15.8882 0.86160E-16 -16.0647 0.82177E+00 -0.0853 51 FeF+ 0.21337E-17 -17.6709 0.16517E-17 -17.7821 0.82177E+00 -0.0853 53 FeO,aq 0.21429E-09 -9.6690 0.23110E-09 -9.6362 0.10000E+01 0.0000 54 FeOH+ 0.19442E-10 -10.7113 0.15049E-10 -10.8225 0.82177E+00 -0.0853 55 HFeO2- 0.30710E-07 -7.5127 0.31089E-07 -7.5074 0.81985E+00 -0.0863 56 FeO+ 0.11720E-16 -16.9311 0.81306E-17 -17.0899 0.82177E+00 -0.0853 58 FeO2- 0.30323E-09 -9.5182 0.27510E-09 -9.5605 0.81985E+00 -0.0863 59 HFeO2,aq 0.28147E-11 -11.5506 0.27204E-11 -11.5654 0.10000E+01 0.0000 60 H2,aq 0.15655E-04 -4.8054 0.19491E-04 -4.7102 0.10000E+01 0.0000 61 KCl,aq 0.45325E-08 -8.3437 0.44125E-08 -8.3553 0.10000E+01 0.0000 63 KOH,aq 0.78055E-06 -6.1076 0.88307E-06 -6.0540 0.10000E+01 0.0000 64 KSO4- 0.66385E-13 -13.1779 0.25241E-13 -13.5979 0.81985E+00 -0.0863 65 MgCO3,aq 0.37086E-11 -11.4308 0.14916E-11 -11.8264 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.38170E-13 -13.4183 0.11019E-13 -13.9579 0.82177E+00 -0.0853 67 MgCl+ 0.41234E-13 -13.3847 0.24770E-13 -13.6061 0.82177E+00 -0.0853 68 MgF+ 0.77684E-15 -15.1097 0.54232E-15 -15.2657 0.82177E+00 -0.0853 69 MgOH+ 0.81029E-10 -10.0914 0.56566E-10 -10.2474 0.82177E+00 -0.0853 71 MnF+ 0.22330E-15 -15.6511 0.17965E-15 -15.7456 0.82177E+00 -0.0853 72 MnO,aq 0.18129E-08 -8.7416 0.20320E-08 -8.6921 0.10000E+01 0.0000 73 MnOH+ 0.57343E-09 -9.2415 0.46133E-09 -9.3360 0.82177E+00 -0.0853 74 MnO2-2 0.15734E-10 -10.8032 0.11151E-10 -10.9527 0.48236E+00 -0.3166 75 HMnO2- 0.18054E-09 -9.7434 0.18995E-09 -9.7214 0.81985E+00 -0.0863 78 MnCl+ 0.15978E-12 -12.7965 0.11061E-12 -12.9562 0.82177E+00 -0.0853 79 MnSO4,aq 0.86331E-19 -19.0638 0.34646E-19 -19.4603 0.10000E+01 0.0000 80 NaCl,aq 0.10497E-04 -4.9789 0.10219E-04 -4.9906 0.10000E+01 0.0000 81 NaF,aq 0.37889E-08 -8.4215 0.42866E-08 -8.3679 0.10000E+01 0.0000 82 NaOH,aq 0.99461E-04 -4.0023 0.11253E-03 -3.9488 0.10000E+01 0.0000 84 OH- 0.79311E-02 -2.1007 0.74283E-02 -2.1291 0.81805E+00 -0.0872 89 HPO3-2 0.13652E-14 -14.8648 0.61416E-15 -15.2117 0.48236E+00 -0.3166 91 H2PO3- 0.14338E-18 -18.8435 0.95758E-19 -19.0188 0.81985E+00 -0.0863 92 H3PO4,aq 0.74788E-18 -18.1262 0.42735E-18 -18.3692 0.10000E+01 0.0000 93 H2PO4- 0.26997E-10 -10.5687 0.14497E-10 -10.8387 0.82080E+00 -0.0858 94 PO4-3 0.59321E-09 -9.2268 0.10606E-09 -9.9744 0.20848E+00 -0.6809 98 HP2O7-3 0.43943E-18 -18.3571 0.42336E-19 -19.3733 0.19659E+00 -0.7064 99 P2O7-4 0.39878E-17 -17.3993 0.13008E-18 -18.8858 0.58136E-01 -1.2356 100 H2S,aq 0.15055E-05 -5.8223 0.12955E-05 -5.8876 0.10000E+01 0.0000 101 S2-2 0.87867E-10 -10.0562 0.33039E-10 -10.4810 0.48236E+00 -0.3166 102 S3-2 0.11385E-16 -16.9437 0.29584E-17 -17.5289 0.48236E+00 -0.3166 107 SO3-2 0.89331E-16 -16.0490 0.25626E-16 -16.5913 0.49090E+00 -0.3090 108 HSO3- 0.29813E-18 -18.5256 0.12475E-18 -18.9040 0.81985E+00 -0.0863 109 HSO4- 0.22470E-17 -17.6484 0.75781E-18 -18.1204 0.82275E+00 -0.0847 111 S2O3-2 0.79035E-18 -18.1022 0.15396E-18 -18.8126 0.48236E+00 -0.3166 Charge balance for all species = -.2314E-03 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1077837E-09 -.1900026E-01 -.1910715E+02 0.0000 2 H2O 0.1000000E+01 0.5552461E+02 0.9979958E+06 0.0000 3 Cl- 0.1874082E-02 0.1885061E-02 0.6667763E+02 7.2893 4 SO4-- 0.4455785E-10 -.1946880E-01 -.1865910E+04 9.2235 5 HCO3- 0.9738203E-04 0.1973878E-01 0.1201640E+04 5.6875 6 HS- 0.6673324E-02 0.2614533E-01 0.8626930E+03 7.8410 7 Al+++ 0.2035262E-28 0.4377010E-05 0.1178271E+00 0.8220 8 H4SiO4 0.6777352E-03 0.1164551E-01 0.1116743E+04 -3.2093 9 Ca++ 0.2292995E-06 0.4742779E-06 0.1896447E-01 13.2897 10 Mg++ 0.3154966E-10 0.1220317E-09 0.2960024E-05 9.2661 11 Fe++ 0.9159085E-13 0.3005071E-07 0.1674389E-02 6.7744 12 K+ 0.1981178E-03 0.1989268E-03 0.7760577E+01 6.3157 13 Na+ 0.2515086E-01 0.2761977E-01 0.6335152E+03 8.4183 14 Mn++ 0.2905034E-10 0.2572764E-08 0.1410180E-03 9.2929 15 F- 0.9599430E-06 0.9615140E-06 0.1822490E-01 4.0630 16 HPO4-- 0.2789652E-07 0.2864394E-07 0.2742904E-02 12.2232 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277790E+02 -.9476793E-02 -.8587394E+02 0.0000000E+00 2 H2O -.7057454E+01 0.2769411E+02 -.3675060E+02 0.0000000E+00 3 Cl- 0.9402152E-03 0.9402152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1392419E+00 -.9710489E-02 0.1494951E+00 0.0000000E+00 5 HCO3- 0.9845147E-02 0.9845147E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1359118E+00 0.1304055E-01 -.1494951E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2183129E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5808452E-02 0.5361088E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.2365564E-06 0.6527266E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6086598E-10 0.4356512E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1498845E-07 0.3953323E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.9921907E-04 0.1061471E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1377596E-01 0.6262498E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1283222E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5449600E-04 0.4795760E-06 0.5393849E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1428679E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: -.2665E-14 Mass of aqueous solution: 0.499920E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1359900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.99 628.8 andradite 0.5958 -0.225 302.8 2.481 5.543 78.66 grossular 0.1405 -0.852 63.30 1.801 1.159 17.61 apatite-OH 0.9809E-02 -2.008 4.927 0.693 0.9020E-01 1.566 apatite-F 0.5402E-04 -4.267 0.2724E-01 -1.565 0.4987E-03 0.8510E-02 clinochlore 0.6994 -0.155 388.7 2.590 7.117 147.9 daphnite 0.2094 -0.679 149.4 2.174 2.735 45.27 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.1855E-04 -4.732 0.4018E-02 -2.396 0.7355E-04 0.1228E-02 hedenbergite 0.1855E-04 -4.732 0.4603E-02 -2.337 0.8427E-04 0.1261E-02 microcline 0.9451 -0.025 263.0 2.420 4.816 102.8 stilbite 3.232 0.510 2278. 3.358 41.70 1062. stilpnomelane-Fe 0.2328 -0.633 251.0 2.400 4.595 86.69 tr.625ac.25prg.125 0.1300 -0.886 111.1 2.046 2.034 35.77 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8092E+00 0.8092E+00 1.0000 -0.092 grossular 0.1908E+00 0.1908E+00 1.0000 -0.719 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7552E+00 0.7552E+00 1.0000 -0.122 daphnite 0.2261E+00 0.2261E+00 1.0000 -0.646 chlorite-Mn 0.1872E-01 0.1872E-01 1.0000 -1.728 diopside 0.5000E+00 0.5000E+00 1.0000 -0.301 hedenbergite 0.5000E+00 0.5000E+00 1.0000 -0.301 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.419740 g Volume = 2211.327017 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1359900 moles log = -0.8665 Original solution: 1000.0103000 g Original solution / Rock added: 7353.56 (Water/Rock Ratio), log = 3.8665 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 30.4685 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3511E-01 0.9400 0.1006E+01 0.1070E+01 CO2,gas 0.2331E-07 0.9481 0.6733E-06 0.7102E-06 CH4,gas 0.9641E+00 0.9822 0.2885E+02 0.2937E+02 H2,gas 0.8264E-03 1.0164 0.2559E-01 0.2518E-01 H2S,gas 0.1312E-05 0.8906 0.3561E-04 0.3999E-04 S2,gas 0.2386E-26 1.0000 0.7269E-25 0.7269E-25 CO,gas 0.1508E-12 1.0000 0.4594E-11 0.4594E-11 SO3,gas 0.7590E-48 1.0000 0.2313E-46 0.2313E-46 SO2,gas 0.7559E-27 1.0000 0.2303E-25 0.2303E-25 HF,gas 0.3855E-16 1.0000 0.1175E-14 0.1175E-14 HCl,gas 0.1249E-17 1.0000 0.3806E-16 0.3806E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases albite does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.5470E+01 andradite does not satisfy anymore the mass action equation We remove it from matrix. affinity =-.4374E+03 grossular does not satisfy anymore the mass action equation We remove it from matrix. affinity =-.1011E+04 apatite-OH does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.6847E+02 apatite-F does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.8205E+02 clinochlore does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.1951E+03 daphnite does not satisfy anymore the mass action equation We remove it from matrix. affinity =-.2572E+03 chlorite-Mn does not satisfy anymore the mass action equation We remove it from matrix. affinity =-.4254E+03 diopside does not satisfy anymore the mass action equation We remove it from matrix. affinity =-.4390E+03 hedenbergite does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.4465E+03 microcline does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.5469E+01 stilbite does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.1553E+02 stilpnomelane-Fe does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.2994E+02 tr.625ac.25prg.125 does not satisfy anymore the mass action equation We remove it from matrix. affinity =0.6568E+02 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -14.53 -7.87 -2.624 0.13439E+05 -6.172 3 CH4,gas 4.54 4.30 -0.24 -0.060 0.40778E+03 1.460 4 H2,gas 8.00 4.71 -3.29 -1.881 0.56191E+04 -1.592 5 H2S,gas -6.23 -12.38 -6.15 -3.074 0.10496E+05 -4.448 6 S2,gas -7.34 -34.17 -26.84 -4.129 0.45824E+05 -25.139 7 CO,gas 3.21 -9.82 -13.04 -4.011 0.22260E+05 -11.338 8 SO3,gas 17.12 -31.21 -48.33 -12.084 0.82530E+05 -46.636 9 SO2,gas 0.83 -26.50 -27.34 -7.290 0.46677E+05 -25.638 10 HF,gas 0.47 -16.16 -16.63 -8.315 0.28394E+05 -14.930 11 HCl,gas 5.19 -12.93 -18.12 -9.059 0.30937E+05 -16.420 12 acmite 7.71 6.42 -1.29 -0.134 0.22023E+04 16 albite-high 0.69 -0.39 -1.08 -0.083 0.18443E+04 17 albite -0.38 -0.39 0.00 0.000 0.54696E+01 20 spessartine 24.46 19.89 -4.56 -0.228 0.77906E+04 21 analcite 3.32 2.82 -0.50 -0.056 0.85385E+03 23 andradite 39.01 39.26 0.26 0.013 -0.43739E+03 24 grossular 32.73 33.32 0.59 0.030 -0.10113E+04 27 annite 20.12 17.83 -2.29 -0.127 0.39110E+04 28 phlogopite 27.06 25.31 -1.76 -0.098 0.29994E+04 30 anorthite 12.71 8.52 -4.20 -0.323 0.71633E+04 33 apatite-OH -18.15 -18.19 -0.04 -0.003 0.68465E+02 34 apatite-F -34.30 -34.35 -0.05 -0.004 0.82054E+02 38 aragonite 0.97 -1.24 -2.21 -0.736 0.37699E+04 39 brucite 12.57 9.27 -3.30 -0.661 0.56394E+04 40 calcite 0.81 -1.24 -2.05 -0.684 0.35057E+04 41 carnegieite-low 9.02 6.03 -2.99 -0.427 0.51093E+04 42 carnegieite-high 10.09 6.03 -4.06 -0.580 0.69363E+04 43 carpholite-Mg 8.58 4.49 -4.09 -0.273 0.69852E+04 44 carpholite-Fe 6.71 2.00 -4.71 -0.314 0.80477E+04 45 celadonite 5.34 3.57 -1.77 -0.104 0.30300E+04 46 celadonite-Fe 3.88 1.08 -2.80 -0.165 0.47829E+04 47 chrysotile 23.89 21.38 -2.51 -0.209 0.42907E+04 49 clinochlore 39.07 38.96 -0.11 -0.004 0.19511E+03 50 daphnite 28.97 29.12 0.15 0.005 -0.25717E+03 51 chlorite-Mn 46.87 47.12 0.25 0.008 -0.42545E+03 52 chlorite-Al-free 47.17 42.76 -4.41 -0.184 0.75366E+04 54 chloritoid-Fe 9.17 5.21 -3.97 -0.264 0.67701E+04 55 chloritoid-Mn 11.40 7.73 -3.67 -0.245 0.62732E+04 57 coesite -2.38 -3.21 -0.83 -0.278 0.14222E+04 64 cristobalite -2.56 -3.21 -0.65 -0.216 0.11076E+04 66 cymrite-K 1.69 -2.49 -4.18 -0.348 0.71291E+04 68 diaspore 2.87 0.82 -2.05 -0.342 0.35037E+04 69 diamond -3.10 -5.11 -2.01 -0.574 0.34328E+04 70 diopside 16.18 16.44 0.26 0.026 -0.43899E+03 71 hedenbergite 14.21 13.95 -0.26 -0.026 0.44654E+03 78 epidote 24.67 23.02 -1.65 -0.080 0.28254E+04 79 clinozoisite 22.81 19.42 -3.39 -0.154 0.57863E+04 80 epidote-Fe 29.84 26.61 -3.23 -0.168 0.55111E+04 81 fayalite 14.05 10.34 -3.71 -0.529 0.63283E+04 82 ferrosilite 11.15 7.13 -4.02 -0.402 0.68623E+04 86 gibbsite 4.08 0.82 -3.26 -0.465 0.55625E+04 87 glaucophane 22.97 20.61 -2.37 -0.064 0.40455E+04 88 glaucophane-Fe 17.28 13.13 -4.15 -0.112 0.70782E+04 89 graphite -3.55 -5.11 -1.57 -0.448 0.26751E+04 90 greenalite 16.14 13.90 -2.24 -0.186 0.38164E+04 93 hematite 12.57 8.84 -3.73 -0.452 0.63633E+04 94 heulandite -5.83 -7.53 -1.70 -0.077 0.29091E+04 98 jadeite 4.22 2.82 -1.39 -0.139 0.23791E+04 100 kalsilite 7.58 3.93 -3.66 -0.522 0.62418E+04 101 kaolinite -1.33 -4.77 -3.44 -0.313 0.58772E+04 104 laumontite 2.88 2.10 -0.79 -0.052 0.13438E+04 105 lawsonite 9.62 8.51 -1.10 -0.073 0.18805E+04 106 leucite 4.12 0.72 -3.40 -0.340 0.58046E+04 108 lizardite 23.24 21.38 -1.86 -0.155 0.31834E+04 110 magnetite 20.09 15.61 -4.47 -0.365 0.76387E+04 111 minnesotaite 10.39 7.49 -2.90 -0.171 0.49544E+04 115 manganosite 14.06 9.29 -4.77 -1.191 0.81368E+04 119 microcline -2.49 -2.49 0.00 0.000 0.54694E+01 120 monticellite 24.34 19.35 -4.99 -0.713 0.85250E+04 123 muscovite 2.58 -0.85 -3.43 -0.202 0.58545E+04 124 paragonite 4.24 1.26 -2.98 -0.175 0.50936E+04 125 nepheline 8.34 6.03 -2.31 -0.330 0.39417E+04 131 periclase-Fe 11.63 6.77 -4.85 -1.213 0.82852E+04 137 phlogopite-Na 29.65 27.41 -2.24 -0.124 0.38182E+04 139 prehnite 19.37 18.60 -0.78 -0.046 0.13259E+04 140 prehnite-Fe 22.50 22.19 -0.30 -0.018 0.51997E+03 141 pumpellyite-Fe 46.27 44.79 -1.48 -0.033 0.25320E+04 142 pumpellyite-Mg 48.99 47.28 -1.72 -0.038 0.29311E+04 145 pyrite -21.25 -22.69 -1.44 -0.339 0.24635E+04 146 pyrrhotite -4.26 -5.60 -1.34 -0.448 0.22930E+04 147 pyrrhotiteFe0.875 -6.02 -7.03 -1.02 -0.374 0.17365E+04 148 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22453E+04 150 quartz -2.99 -3.21 -0.22 -0.073 0.37493E+03 154 rhodochrosite -0.98 -5.24 -4.26 -1.421 0.72769E+04 155 rhodonite 7.45 6.08 -1.36 -0.272 0.23255E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20732E+04 166 stilbite -7.52 -7.53 -0.01 0.000 0.15528E+02 167 stilpnomelane-Fe 13.02 13.00 -0.02 -0.001 0.29944E+02 168 stilpnomelane-Mg 27.44 25.46 -1.98 -0.059 0.33867E+04 174 talc 16.49 14.96 -1.53 -0.090 0.26115E+04 177 tephroite 18.09 15.38 -2.71 -0.387 0.46261E+04 181 tridymite -2.63 -3.21 -0.58 -0.194 0.99491E+03 182 tremolite 47.87 47.24 -0.63 -0.017 0.10805E+04 183 ferroactinolite 38.45 34.78 -3.67 -0.099 0.62740E+04 184 troilite-low -4.41 -5.60 -1.19 -0.397 0.20358E+04 186 vesuvianite 223.47 222.31 -1.16 -0.009 0.19836E+04 190 wairakite 3.95 2.10 -1.85 -0.109 0.31653E+04 191 walstromite 11.51 10.08 -1.43 -0.286 0.24395E+04 192 wollastonite 10.46 10.08 -0.38 -0.076 0.64994E+03 193 pseudo-wollastonite 11.00 10.08 -0.92 -0.184 0.15698E+04 194 zoisite 22.85 19.42 -3.43 -0.156 0.58603E+04 195 akaganeite 7.75 4.42 -3.33 -0.721 0.56943E+04 202 chalcedony -2.80 -3.21 -0.41 -0.136 0.69423E+03 204 montmorillonite-Ca -2.29 -6.21 -3.92 -0.243 0.66978E+04 205 montmorillonite-K -2.24 -6.32 -4.09 -0.250 0.69754E+04 206 montmorillonite-Mg -2.48 -6.88 -4.40 -0.272 0.75084E+04 207 montmorillonite-Na -2.04 -5.63 -3.59 -0.220 0.61303E+04 208 nontronite-Ca 3.21 -0.47 -3.69 -0.239 0.62978E+04 210 nontronite-K 3.34 -0.58 -3.92 -0.252 0.66987E+04 211 nontronite-Mg 3.07 -1.14 -4.21 -0.273 0.71925E+04 212 nontronite-Na 3.52 0.11 -3.41 -0.219 0.58196E+04 225 portlandite 18.27 13.29 -4.98 -0.997 0.85079E+04 228 tobermorite 9.82 7.86 -1.96 -0.535 0.33502E+04 234 alabandite -0.98 -3.08 -2.11 -0.702 0.35974E+04 237 boehmite 4.41 0.82 -3.58 -0.597 0.61207E+04 239 ferrous-oxide 9.81 6.77 -3.04 -0.759 0.51862E+04 245 silica-amorphous -2.09 -3.21 -1.12 -0.373 0.19084E+04 247 an20ab80 2.02 1.39 -0.62 -0.048 0.10662E+04 248 an25ab75 2.65 1.84 -0.81 -0.062 0.13783E+04 249 an30ab70 3.28 2.28 -1.00 -0.077 0.17001E+04 250 tr.625ac.25prg.125 45.16 45.13 -0.04 -0.001 0.65683E+02 Number of iterations reached the given limit ( 400) Non-Convergence assumed. Execution aborted. Check "convergence problems" in manual. Cut step size to one tenth of previous value and try again.