File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. diopside is suppressed in THIS RUN. hedenbergite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.82778E+02 0.11290E-09 0.8258 0.00000000E+00 H2O 2 0. -0.70607E+01 0.10000E+01 0.9997 0.00000000E+00 Cl- 3 -1. 0.91662E-03 0.18275E-02 0.8197 0.00000000E+00 SO4-- 4 -2. 0.13922E+00 0.13818E-09 0.4831 0.00000000E+00 HCO3- 5 -1. 0.95559E-02 0.29006E-03 0.8211 0.00000000E+00 HS- 6 -1. -0.13599E+00 0.64805E-02 0.8198 0.00000000E+00 Al+++ 7 3. 0.16304E+02 0.22699E-28 0.1959 0.00000000E+00 H4SiO4 8 0. 0.52064E+02 0.69572E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.57507E+01 0.22952E-06 0.4788 0.00000000E+00 Mg++ 10 2. 0.39683E+01 0.35944E-10 0.4761 0.00000000E+00 Fe++ 11 2. 0.35650E+01 0.99071E-13 0.4767 0.00000000E+00 K+ 12 1. 0.10616E+01 0.20014E-03 0.8214 0.00000000E+00 Na+ 13 1. 0.62764E+01 0.25407E-01 0.8195 0.00000000E+00 Mn++ 14 2. 0.86693E-01 0.32189E-10 0.4772 0.00000000E+00 F- 15 -1. 0.52896E-04 0.93380E-06 0.8176 0.00000000E+00 HPO4-- 16 -2. 0.29588E-01 0.30847E-07 0.4832 0.00000000E+00 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.9166E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E+00 TEMP = 100.0000 SINC = 0.4000E-02 TEMPC = 0.0000 TOTMIX = 0.131990E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 2000.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 125 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 126 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 127 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 128 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 129 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 130 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 131 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 132 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 133 23.119 0.0000E+00 HF,gas 10 0.473 0.0000E+00 phase_A 134 80.189 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phlogopite-Na 135 29.647 0.0000E+00 acmite 12 7.710 0.0000E+00 piemontite(ordered) 136 33.776 0.0000E+00 akermanite 13 36.442 0.0000E+00 prehnite 137 19.372 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite-Fe 138 22.498 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 pumpellyite-Fe 139 46.269 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Mg 140 48.995 0.0000E+00 albite 17 -0.384 0.6247E+01 px-Mg-tschermaks 141 19.616 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Ca-tschermaks 142 18.610 0.0000E+00 pyrope 19 37.248 0.0000E+00 pyrite 143 -21.247 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrrhotite 144 -4.260 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotiteFe0.875 145 -6.017 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyroxmangite 146 7.399 0.0000E+00 andradite 23 39.009 0.5936E+00 pyrophyllite 147 -6.176 0.0000E+00 grossular 24 32.731 0.1438E+00 quartz 148 -2.989 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 rankinite 149 40.713 0.0000E+00 ankerite 26 -2.135 0.0000E+00 ringwoodite-Fe 150 15.456 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Mg 151 27.575 0.0000E+00 phlogopite 28 27.065 0.0000E+00 rhodochrosite 152 -0.976 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodonite 153 7.446 0.0000E+00 anorthite 30 12.710 0.0000E+00 sanidine 154 -1.275 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sapphirine(351) 155 78.899 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 siderite 156 -2.608 0.0000E+00 apatite-OH 33 -18.153 0.9810E-02 sillimanite 157 5.262 0.0000E+00 apatite-F 34 -34.301 0.5243E-04 sodalite 158 49.976 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 spinel 159 20.870 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spurrite 160 59.482 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 staurolite-Fe 161 73.598 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Mg 162 89.802 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mn 163 83.909 0.0000E+00 calcite 40 0.812 0.0000E+00 stilbite 164 -7.522 0.3228E+01 carnegieite-low 41 9.023 0.0000E+00 stilpnomelane-Fe 165 13.017 0.2407E+00 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Mg 166 27.441 0.0000E+00 carpholite-Mg 43 8.582 0.0000E+00 stishovite 167 2.720 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 sudoite-Fe 168 18.296 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite 169 21.077 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sulfur 170 -9.152 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sylvite 171 1.338 0.0000E+00 chondrodite 48 56.475 0.0000E+00 talc 172 16.491 0.0000E+00 clinochlore 49 39.070 0.7010E+00 talc-Fe 173 13.448 0.0000E+00 daphnite 50 28.965 0.2030E+00 talc-tschermaks 174 19.091 0.0000E+00 chlorite-Mn 51 46.869 0.1734E-01 tephroite 175 18.086 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tilleyite 176 41.377 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 titanite-CaSi 177 15.479 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 topaz-H 178 4.618 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 tridymite 179 -2.626 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tremolite 180 47.869 0.0000E+00 coesite 57 -2.376 0.0000E+00 ferroactinolite 181 38.452 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 troilite-low 182 -4.411 0.0000E+00 cordierite 59 24.049 0.0000E+00 tschermakite 183 48.210 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 vesuvianite 184 223.471 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 wadeite-Si 185 20.216 0.0000E+00 corundum 62 8.383 0.0000E+00 wadsleyite-Fe 186 15.680 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Mg 187 25.850 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wairakite 188 3.950 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 walstromite 189 11.509 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 wollastonite 190 10.461 0.0000E+00 deerite 67 95.671 0.0000E+00 pseudo-wollastonite 191 11.000 0.0000E+00 diaspore 68 2.874 0.0000E+00 zoisite 192 22.849 0.0000E+00 diamond 69 -3.102 0.0000E+00 akaganeite 193 7.755 0.0000E+00 dolomite,ordered 70 0.546 0.0000E+00 beidellite-Ca 194 -1.646 0.0000E+00 eastonite 71 28.489 0.0000E+00 beidellite-H 195 -2.326 0.0000E+00 enstatite 72 17.265 0.0000E+00 beidellite-K 196 -1.520 0.0000E+00 clinoenstatite-HiP 73 18.354 0.0000E+00 beidellite-Mg 197 -1.790 0.0000E+00 clinoenstatite 74 17.166 0.0000E+00 beidellite-Na 198 -1.342 0.0000E+00 protoenstatite 75 17.824 0.0000E+00 calcium 199 84.026 0.0000E+00 epidote 76 24.670 0.0000E+00 chalcedony 200 -2.802 0.0000E+00 clinozoisite 77 22.806 0.0000E+00 dawsonite 201 1.682 0.0000E+00 epidote-Fe 78 29.841 0.0000E+00 montmorillonite-Ca 202 -2.291 0.0000E+00 fayalite 79 14.046 0.0000E+00 montmorillonite-K 203 -2.237 0.0000E+00 ferrosilite 80 11.149 0.0000E+00 montmorillonite-Mg 204 -2.480 0.0000E+00 forsterite 81 21.016 0.0000E+00 montmorillonite-Na 205 -2.038 0.0000E+00 gedrite 82 50.522 0.0000E+00 nontronite-Ca 206 3.215 0.0000E+00 gehlenite 83 36.628 0.0000E+00 nontronite-H 207 2.533 0.0000E+00 gibbsite 84 4.079 0.0000E+00 nontronite-K 208 3.341 0.0000E+00 glaucophane 85 22.975 0.0000E+00 nontronite-Mg 209 3.075 0.0000E+00 glaucophane-Fe 86 17.276 0.0000E+00 nontronite-Na 210 3.520 0.0000E+00 graphite 87 -3.546 0.0000E+00 sepiolite 211 24.118 0.0000E+00 greenalite 88 16.140 0.0000E+00 topaz 212 -16.546 0.0000E+00 grunerite 89 31.215 0.0000E+00 alite 213 57.999 0.0000E+00 halite 90 1.575 0.0000E+00 belite 214 30.433 0.0000E+00 hematite 91 12.566 0.0000E+00 ettringite 215 43.232 0.0000E+00 heulandite 92 -5.827 0.0000E+00 gypsum 216 -4.955 0.0000E+00 hercynite 93 17.279 0.0000E+00 hemicarboaluminate 217 70.954 0.0000E+00 hollandite 94 25.673 0.0000E+00 hydrogarnet 218 60.662 0.0000E+00 iron 95 19.086 0.0000E+00 hydrogarnet-Si 219 50.586 0.0000E+00 jadeite 96 4.215 0.0000E+00 jennite 220 24.367 0.0000E+00 julgoldite 97 70.427 0.0000E+00 monosulfoaluminate 221 53.400 0.0000E+00 kalsilite 98 7.584 0.0000E+00 monocarboaluminate 222 61.898 0.0000E+00 kaolinite 99 -1.333 0.0000E+00 portlandite 223 18.272 0.0000E+00 kyanite 100 4.876 0.0000E+00 stratlingite 224 36.502 0.0000E+00 larnite-bredigite 101 30.686 0.0000E+00 tricarboaluminate 225 70.370 0.0000E+00 laumontite 102 2.883 0.0000E+00 tobermorite 226 9.823 0.0000E+00 lawsonite 103 9.616 0.0000E+00 C4AH13 227 81.816 0.0000E+00 leucite 104 4.119 0.0000E+00 C2AH8 228 45.203 0.0000E+00 lime 105 25.998 0.0000E+00 C3A 229 86.953 0.0000E+00 lizardite 106 23.244 0.0000E+00 C4AF 230 117.416 0.0000E+00 magnesite 107 0.691 0.0000E+00 CAH10 231 28.335 0.0000E+00 magnetite 108 20.087 0.0000E+00 alabandite 232 -0.978 0.0000E+00 minnesotaite 109 10.388 0.0000E+00 alunite 233 -10.435 0.0000E+00 minnesotaite-Mg 110 20.602 0.0000E+00 artinite 234 15.121 0.0000E+00 magnesioferrite 111 26.212 0.0000E+00 boehmite 235 4.406 0.0000E+00 majorite 112 53.251 0.0000E+00 dolomite,disordered 236 1.247 0.0000E+00 manganosite 113 14.058 0.0000E+00 ferrous-oxide 237 9.812 0.0000E+00 margarite 114 17.324 0.0000E+00 fluorite 238 -9.931 0.0000E+00 meionite 115 44.874 0.0000E+00 huntite 239 3.770 0.0000E+00 merwinite 116 55.930 0.0000E+00 hydromagnesite 240 19.995 0.0000E+00 microcline 117 -2.486 0.9411E+00 nesquehonite 241 4.723 0.0000E+00 monticellite 118 24.339 0.0000E+00 potassium-oxide 242 69.038 0.0000E+00 mullite-Al 119 363.148 0.0000E+00 silica-amorphous 243 -2.091 0.0000E+00 mullite-Si 120 7.264 0.0000E+00 sodium-oxide 244 55.169 0.0000E+00 muscovite 121 2.582 0.0000E+00 an20ab80 245 2.018 0.0000E+00 paragonite 122 4.239 0.0000E+00 an25ab75 246 2.646 0.0000E+00 nepheline 123 8.339 0.0000E+00 an30ab70 247 3.279 0.0000E+00 osumilite(1) 124 21.717 0.0000E+00 tr.625ac.25prg.125 248 45.165 0.1258E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.1319900 moles log = -0.8795 Original solution: 1000.0103000 g Original solution / Rock added: 7576.41 (Water/Rock Ratio), log = 3.8795 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1319900 Water: Moles liquid = 0.2769E+02 kg liquid = 0.4988E+00 Moles total = -.7061E+01 kg total = -.1272E+00 Activity = 0.9997 Stoichiometric ionic strength = .1159175E-03 Osmotic coef. = 0.9900 True ionic strength = .2602207E-01 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.9166E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11262E-09 -9.9484 0.93011E-10 -10.0315 0.82586E+00 -0.0831 2 H2O 0.99967E+00 -0.0001 0.99967E+00 -0.0001 3 Cl- 0.18272E-02 -2.7382 0.14979E-02 -2.8245 0.81978E+00 -0.0863 4 SO4-- 0.13154E-09 -9.8809 0.63587E-10 -10.1966 0.48340E+00 -0.3157 5 HCO3- 0.27670E-03 -3.5580 0.22724E-03 -3.6435 0.82125E+00 -0.0855 6 HS- 0.64793E-02 -2.1885 0.53126E-02 -2.2747 0.81993E+00 -0.0862 7 Al+++ 0.22552E-28 -28.6468 0.44227E-29 -29.3543 0.19611E+00 -0.7075 8 H4SiO4 0.69499E-03 -3.1580 0.69499E-03 -3.1580 0.10000E+01 0.0000 9 Ca++ 0.22918E-06 -6.6398 0.10979E-06 -6.9594 0.47904E+00 -0.3196 10 Mg++ 0.35741E-10 -10.4468 0.17025E-10 -10.7689 0.47635E+00 -0.3221 11 Fe++ 0.98631E-13 -13.0060 0.47046E-13 -13.3275 0.47699E+00 -0.3215 12 K+ 0.19991E-03 -3.6992 0.16422E-03 -3.7846 0.82148E+00 -0.0854 13 Na+ 0.25379E-01 -1.5955 0.20800E-01 -1.6819 0.81959E+00 -0.0864 14 Mn++ 0.32043E-10 -10.4943 0.15300E-10 -10.8153 0.47748E+00 -0.3210 15 F- 0.93588E-06 -6.0288 0.76529E-06 -6.1162 0.81772E+00 -0.0874 16 HPO4-- 0.30782E-07 -7.5117 0.14882E-07 -7.8273 0.48348E+00 -0.3156 18 HSiO3- 0.85137E-02 -2.0699 0.69794E-02 -2.1562 0.81978E+00 -0.0863 19 Ca(HSiO3)+ 0.21237E-07 -7.6729 0.17450E-07 -7.7582 0.82170E+00 -0.0853 20 Mg(HSiO3)+ 0.40986E-11 -11.3874 0.33678E-11 -11.4726 0.82170E+00 -0.0853 21 NaHSiO3,aq 0.23479E-02 -2.6293 0.23479E-02 -2.6293 0.10000E+01 0.0000 22 AlO+ 0.84613E-16 -16.0726 0.69527E-16 -16.1578 0.82170E+00 -0.0853 24 HAlO2,aq 0.14882E-09 -9.8274 0.14882E-09 -9.8274 0.10000E+01 0.0000 25 AlO2- 0.43298E-05 -5.3635 0.35417E-05 -5.4508 0.81798E+00 -0.0873 26 CH4,aq 0.18437E-01 -1.7343 0.18436E-01 -1.7343 0.99996E+00 0.0000 27 C2H6,aq 0.49551E-08 -8.3049 0.49549E-08 -8.3050 0.99996E+00 0.0000 28 C3H8,aq 0.30746E-13 -13.5122 0.30745E-13 -13.5122 0.99996E+00 0.0000 29 C4H10,aq 0.18741E-18 -18.7272 0.18741E-18 -18.7272 0.99996E+00 0.0000 30 ethanol,aq 0.17957E-15 -15.7458 0.17956E-15 -15.7458 0.99996E+00 0.0000 31 CO,aq 0.13313E-13 -13.8757 0.13313E-13 -13.8757 0.10000E+01 0.0000 32 CO2,aq 0.45179E-07 -7.3451 0.45178E-07 -7.3451 0.99996E+00 0.0000 33 CO3-2 0.44261E-03 -3.3540 0.21340E-03 -3.6708 0.48214E+00 -0.3168 34 CaCO3,aq 0.29377E-06 -6.5320 0.29377E-06 -6.5320 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.77502E-09 -9.1107 0.63683E-09 -9.1960 0.82170E+00 -0.0853 36 CaCl+ 0.32388E-09 -9.4896 0.26613E-09 -9.5749 0.82170E+00 -0.0853 37 CaCl2,aq 0.94707E-13 -13.0236 0.94707E-13 -13.0236 0.10000E+01 0.0000 38 CaF+ 0.14929E-11 -11.8260 0.12267E-11 -11.9113 0.82170E+00 -0.0853 39 CaOH+ 0.10234E-06 -6.9899 0.84097E-07 -7.0752 0.82170E+00 -0.0853 40 CaSO4,aq 0.22168E-14 -14.6543 0.22168E-14 -14.6543 0.10000E+01 0.0000 41 HCl,aq 0.25530E-13 -13.5930 0.25530E-13 -13.5930 0.10000E+01 0.0000 45 HF,aq 0.48728E-12 -12.3122 0.48728E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.15358E-18 -18.8137 0.12590E-18 -18.9000 0.81978E+00 -0.0863 48 FeCl+ 0.13575E-15 -15.8673 0.11154E-15 -15.9526 0.82170E+00 -0.0853 51 FeF+ 0.22391E-17 -17.6499 0.18399E-17 -17.7352 0.82170E+00 -0.0853 53 FeO,aq 0.21129E-09 -9.6751 0.21129E-09 -9.6751 0.10000E+01 0.0000 54 FeOH+ 0.20031E-10 -10.6983 0.16459E-10 -10.7836 0.82170E+00 -0.0853 55 HFeO2- 0.28984E-07 -7.5378 0.23761E-07 -7.6241 0.81978E+00 -0.0863 56 FeO+ 0.13952E-16 -16.8554 0.11464E-16 -16.9407 0.82170E+00 -0.0853 58 FeO2- 0.33066E-09 -9.4806 0.27107E-09 -9.5669 0.81978E+00 -0.0863 59 HFeO2,aq 0.32066E-11 -11.4940 0.32066E-11 -11.4940 0.10000E+01 0.0000 60 H2,aq 0.11728E-04 -4.9308 0.11727E-04 -4.9308 0.99996E+00 0.0000 61 KCl,aq 0.44584E-08 -8.3508 0.44584E-08 -8.3508 0.10000E+01 0.0000 63 KOH,aq 0.75378E-06 -6.1228 0.75378E-06 -6.1228 0.10000E+01 0.0000 64 KSO4- 0.19766E-12 -12.7041 0.16204E-12 -12.7904 0.81978E+00 -0.0863 65 MgCO3,aq 0.11419E-10 -10.9424 0.11419E-10 -10.9424 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12281E-12 -12.9108 0.10091E-12 -12.9961 0.82170E+00 -0.0853 67 MgCl+ 0.45522E-13 -13.3418 0.37405E-13 -13.4271 0.82170E+00 -0.0853 68 MgF+ 0.85758E-15 -15.0667 0.70467E-15 -15.1520 0.82170E+00 -0.0853 69 MgOH+ 0.87824E-10 -10.0564 0.72165E-10 -10.1417 0.82170E+00 -0.0853 71 MnF+ 0.24001E-15 -15.6198 0.19722E-15 -15.7051 0.82170E+00 -0.0853 72 MnO,aq 0.18309E-08 -8.7373 0.18309E-08 -8.7373 0.10000E+01 0.0000 73 MnOH+ 0.60514E-09 -9.2181 0.49724E-09 -9.3034 0.82170E+00 -0.0853 74 MnO2-2 0.14563E-10 -10.8368 0.70214E-11 -11.1536 0.48214E+00 -0.3168 75 HMnO2- 0.17453E-09 -9.7581 0.14308E-09 -9.8444 0.81978E+00 -0.0863 78 MnCl+ 0.17174E-12 -12.7651 0.14112E-12 -12.8504 0.82170E+00 -0.0853 79 MnSO4,aq 0.28085E-18 -18.5515 0.28085E-18 -18.5515 0.10000E+01 0.0000 80 NaCl,aq 0.10325E-04 -4.9861 0.10325E-04 -4.9861 0.10000E+01 0.0000 81 NaF,aq 0.37267E-08 -8.4287 0.37267E-08 -8.4287 0.10000E+01 0.0000 82 NaOH,aq 0.96051E-04 -4.0175 0.96051E-04 -4.0175 0.10000E+01 0.0000 84 OH- 0.75917E-02 -2.1197 0.62098E-02 -2.2069 0.81798E+00 -0.0873 89 HPO3-2 0.11284E-14 -14.9475 0.54407E-15 -15.2643 0.48214E+00 -0.3168 91 H2PO3- 0.12379E-18 -18.9073 0.10148E-18 -18.9936 0.81978E+00 -0.0863 92 H3PO4,aq 0.90046E-18 -18.0455 0.90046E-18 -18.0455 0.10000E+01 0.0000 93 H2PO4- 0.31113E-10 -10.5071 0.25535E-10 -10.5929 0.82073E+00 -0.0858 94 PO4-3 0.62683E-09 -9.2029 0.13055E-09 -9.8842 0.20827E+00 -0.6814 98 HP2O7-3 0.55911E-18 -18.2525 0.10980E-18 -18.9594 0.19638E+00 -0.7069 99 P2O7-4 0.48602E-17 -17.3133 0.28201E-18 -18.5497 0.58025E-01 -1.2364 100 H2S,aq 0.15272E-05 -5.8161 0.15272E-05 -5.8161 0.99996E+00 0.0000 101 S2-2 0.11060E-09 -9.9562 0.53327E-10 -10.2731 0.48214E+00 -0.3168 102 S3-2 0.19405E-16 -16.7121 0.93560E-17 -17.0289 0.48214E+00 -0.3168 107 SO3-2 0.19755E-15 -15.7043 0.96934E-16 -16.0135 0.49069E+00 -0.3092 108 HSO3- 0.68861E-18 -18.1620 0.56451E-18 -18.2483 0.81978E+00 -0.0863 109 HSO4- 0.69281E-17 -17.1594 0.56996E-17 -17.2442 0.82269E+00 -0.0848 111 S2O3-2 0.23667E-17 -17.6259 0.11411E-17 -17.9427 0.48214E+00 -0.3168 Charge balance for all species = -.1736E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1126236E-09 -.1901199E-01 -.1911898E+02 0.0000 2 H2O 0.1000000E+01 0.5552353E+02 0.9979783E+06 0.0000 3 Cl- 0.1827182E-02 0.1837512E-02 0.6499585E+02 7.2069 4 SO4-- 0.1315405E-09 -.1843981E-01 -.1767293E+04 9.8663 5 HCO3- 0.2767027E-03 0.1915653E-01 0.1166196E+04 6.3880 6 HS- 0.6479296E-02 0.2492063E-01 0.8222842E+03 7.7568 7 Al+++ 0.2255150E-28 0.4329992E-05 0.1165617E+00 0.7401 8 H4SiO4 0.6949912E-03 0.1155668E-01 0.1108226E+04 -3.1580 9 Ca++ 0.2291841E-06 0.6476388E-06 0.2589652E-01 13.1035 10 Mg++ 0.3574136E-10 0.1392515E-09 0.3377717E-05 9.2940 11 Fe++ 0.9863117E-13 0.2954973E-07 0.1646478E-02 6.7355 12 K+ 0.1999118E-03 0.2006701E-03 0.7828600E+01 6.2469 13 Na+ 0.2537870E-01 0.2783303E-01 0.6384077E+03 8.3495 14 Mn++ 0.3204275E-10 0.2657341E-08 0.1456541E-03 9.2476 15 F- 0.9358763E-06 0.9396050E-06 0.1780966E-01 3.9153 16 HPO4-- 0.3078174E-07 0.3143968E-07 0.3010627E-02 12.2356 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277834E+02 -.9483844E-02 -.8276885E+02 0.0000000E+00 2 H2O -.7060729E+01 0.2769708E+02 -.3475781E+02 0.0000000E+00 3 Cl- 0.9166152E-03 0.9166152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1392228E+00 -.9198420E-02 0.1484212E+00 0.0000000E+00 5 HCO3- 0.9555947E-02 0.9555947E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1359899E+00 0.1243128E-01 -.1484212E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2159952E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5764876E-02 0.5205814E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.3230649E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.6946355E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1474044E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1001013E-03 0.1061471E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1388409E-01 0.6262493E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1325575E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5289600E-04 0.4687079E-06 0.5242729E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1568322E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1104E-13 Mass of aqueous solution: 0.499982E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1319900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.99 628.8 andradite 0.5937 -0.226 301.7 2.480 5.523 78.38 grossular 0.1449 -0.839 65.25 1.815 1.195 18.16 apatite-OH 0.9810E-02 -2.008 4.928 0.693 0.9022E-01 1.566 apatite-F 0.5243E-04 -4.280 0.2644E-01 -1.578 0.4840E-03 0.8260E-02 clinochlore 0.7002 -0.155 389.2 2.590 7.125 148.0 daphnite 0.2030 -0.692 144.9 2.161 2.652 43.89 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9413 -0.026 262.0 2.418 4.797 102.3 stilbite 3.228 0.509 2275. 3.357 41.65 1061. stilpnomelane-Fe 0.2403 -0.619 259.1 2.413 4.743 89.48 tr.625ac.25prg.125 0.1288 -0.890 110.1 2.042 2.016 35.45 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8039E+00 0.8039E+00 1.0000 -0.095 grossular 0.1961E+00 0.1961E+00 1.0000 -0.707 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7606E+00 0.7606E+00 1.0000 -0.119 daphnite 0.2205E+00 0.2205E+00 1.0000 -0.657 chlorite-Mn 0.1883E-01 0.1883E-01 1.0000 -1.725 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.274684 g Volume = 2211.061152 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1319900 moles log = -0.8795 Original solution: 1000.0103000 g Original solution / Rock added: 7576.41 (Water/Rock Ratio), log = 3.8795 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 28.6827 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3721E-01 0.9421 0.1006E+01 0.1067E+01 CO2,gas 0.1772E-06 0.9508 0.4834E-05 0.5084E-05 CH4,gas 0.9623E+00 0.9832 0.2714E+02 0.2760E+02 H2,gas 0.5286E-03 1.0154 0.1540E-01 0.1516E-01 H2S,gas 0.1633E-05 0.8965 0.4198E-04 0.4683E-04 S2,gas 0.9730E-26 1.0000 0.2791E-24 0.2791E-24 CO,gas 0.6917E-12 1.0000 0.1984E-10 0.1984E-10 SO3,gas 0.7254E-47 1.0000 0.2081E-45 0.2081E-45 SO2,gas 0.4346E-26 1.0000 0.1247E-24 0.1247E-24 HF,gas 0.4171E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1571E-17 1.0000 0.4505E-16 0.4505E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 117 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 164 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.67 -7.01 -2.338 0.11977E+05 -5.316 3 CH4,gas 4.54 4.28 -0.27 -0.066 0.45318E+03 1.434 4 H2,gas 8.00 4.49 -3.51 -2.007 0.59959E+04 -1.813 5 H2S,gas -6.23 -12.31 -6.08 -3.038 0.10374E+05 -4.377 6 S2,gas -7.34 -33.59 -26.25 -4.039 0.44827E+05 -24.554 7 CO,gas 3.21 -9.19 -12.40 -3.816 0.21175E+05 -10.702 8 SO3,gas 17.12 -30.26 -47.38 -11.845 0.80901E+05 -45.682 9 SO2,gas 0.83 -25.77 -26.60 -7.094 0.45424E+05 -24.904 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.86 -18.05 -9.023 0.30812E+05 -16.346 12 acmite 7.71 6.53 -1.18 -0.123 0.20226E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.75 -4.71 -0.235 0.80394E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93593E+03 27 annite 20.12 17.72 -2.40 -0.134 0.41049E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28507E+04 30 anorthite 12.71 8.27 -4.44 -0.342 0.75858E+04 38 aragonite 0.97 -0.57 -1.54 -0.513 0.26261E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55917E+04 40 calcite 0.81 -0.57 -1.38 -0.461 0.23619E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52790E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71060E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70420E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82186E+04 45 celadonite 5.34 3.65 -1.69 -0.100 0.28892E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47563E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39724E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.69000E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.274 0.70287E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.255 0.65426E+04 57 coesite -2.38 -3.16 -0.78 -0.261 0.13347E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10200E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36436E+04 69 diamond -3.10 -4.70 -1.60 -0.456 0.27247E+04 72 enstatite 17.26 12.27 -4.99 -0.499 0.85247E+04 74 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83563E+04 76 epidote 24.67 22.70 -1.97 -0.095 0.33562E+04 77 clinozoisite 22.81 18.95 -3.85 -0.175 0.65789E+04 78 epidote-Fe 29.84 26.46 -3.39 -0.176 0.57802E+04 79 fayalite 14.05 10.31 -3.73 -0.533 0.63737E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68201E+04 84 gibbsite 4.08 0.74 -3.34 -0.477 0.57024E+04 85 glaucophane 22.97 20.80 -2.18 -0.059 0.37163E+04 86 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70915E+04 87 graphite -3.55 -4.70 -1.15 -0.329 0.19669E+04 88 greenalite 16.14 13.89 -2.25 -0.187 0.38406E+04 91 hematite 12.57 8.98 -3.58 -0.434 0.61194E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 96 jadeite 4.22 2.77 -1.44 -0.144 0.24612E+04 98 kalsilite 7.58 3.83 -3.75 -0.536 0.64115E+04 99 kaolinite -1.33 -4.84 -3.50 -0.318 0.59817E+04 102 laumontite 2.88 1.95 -0.93 -0.062 0.15911E+04 103 lawsonite 9.62 8.27 -1.35 -0.090 0.23029E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58867E+04 106 lizardite 23.24 21.57 -1.68 -0.140 0.28650E+04 108 magnetite 20.09 15.72 -4.37 -0.357 0.74613E+04 109 minnesotaite 10.39 7.57 -2.81 -0.165 0.48035E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82140E+04 121 muscovite 2.58 -1.01 -3.59 -0.211 0.61287E+04 122 paragonite 4.24 1.10 -3.14 -0.185 0.53678E+04 123 nepheline 8.34 5.93 -2.41 -0.344 0.41114E+04 129 periclase-Fe 11.63 6.74 -4.89 -1.223 0.83517E+04 135 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36696E+04 137 prehnite 19.37 18.21 -1.16 -0.068 0.19786E+04 138 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91095E+03 139 pumpellyite-Fe 46.27 43.90 -2.37 -0.053 0.40438E+04 140 pumpellyite-Mg 48.99 46.46 -2.54 -0.056 0.43287E+04 143 pyrite -21.25 -22.37 -1.12 -0.263 0.19092E+04 144 pyrrhotite -4.26 -5.57 -1.31 -0.437 0.22374E+04 145 pyrrhotiteFe0.875 -6.02 -6.97 -0.95 -0.350 0.16259E+04 146 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22350E+04 147 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84956E+04 148 quartz -2.99 -3.16 -0.17 -0.056 0.28736E+03 152 rhodochrosite -0.98 -4.43 -3.45 -1.150 0.58926E+04 153 rhodonite 7.45 6.09 -1.36 -0.271 0.23152E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.94 -4.33 -1.444 0.73957E+04 166 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27858E+04 172 talc 16.49 15.25 -1.24 -0.073 0.21181E+04 175 tephroite 18.09 15.34 -2.75 -0.393 0.46931E+04 179 tridymite -2.63 -3.16 -0.53 -0.177 0.90734E+03 180 tremolite 47.87 47.41 -0.46 -0.012 0.77712E+03 181 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65415E+04 182 troilite-low -4.41 -5.57 -1.16 -0.387 0.19803E+04 184 vesuvianite 223.47 218.85 -4.62 -0.035 0.78901E+04 188 wairakite 3.95 1.95 -2.00 -0.118 0.34125E+04 189 walstromite 11.51 9.95 -1.56 -0.313 0.26698E+04 190 wollastonite 10.46 9.95 -0.52 -0.103 0.88027E+03 191 pseudo-wollastonite 11.00 9.95 -1.05 -0.211 0.18001E+04 192 zoisite 22.85 18.95 -3.90 -0.177 0.66530E+04 193 akaganeite 7.75 4.49 -3.26 -0.706 0.55724E+04 200 chalcedony -2.80 -3.16 -0.36 -0.118 0.60666E+03 202 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66177E+04 203 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68817E+04 204 montmorillonite-Mg -2.48 -6.80 -4.32 -0.267 0.73680E+04 205 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60366E+04 206 nontronite-Ca 3.21 -0.20 -3.42 -0.222 0.58311E+04 207 nontronite-H 2.53 -2.36 -4.90 -0.328 0.83586E+04 208 nontronite-K 3.34 -0.30 -3.64 -0.234 0.62183E+04 209 nontronite-Mg 3.07 -0.83 -3.90 -0.253 0.66655E+04 210 nontronite-Na 3.52 0.39 -3.13 -0.201 0.53392E+04 226 tobermorite 9.82 7.76 -2.07 -0.564 0.35275E+04 232 alabandite -0.98 -3.06 -2.08 -0.694 0.35527E+04 235 boehmite 4.41 0.74 -3.67 -0.611 0.62605E+04 237 ferrous-oxide 9.81 6.74 -3.08 -0.769 0.52526E+04 243 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18208E+04 245 an20ab80 2.02 1.35 -0.67 -0.052 0.11463E+04 246 an25ab75 2.65 1.78 -0.87 -0.067 0.14799E+04 247 an30ab70 3.28 2.21 -1.07 -0.082 0.18230E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1319900 MOLES New total amount of reactant added: 0.1359900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8660E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1359900 Water: Moles liquid = 0.2769E+02 kg liquid = 0.4988E+00 Moles total = -.7057E+01 kg total = -.1271E+00 Activity = 0.9997 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2625799E-01 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.9402E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11369E-09 -9.9443 0.93833E-10 -10.0276 0.82535E+00 -0.0834 2 H2O 0.99966E+00 -0.0001 0.99966E+00 -0.0001 3 Cl- 0.18743E-02 -2.7272 0.15355E-02 -2.8138 0.81924E+00 -0.0866 4 SO4-- 0.14212E-09 -9.8473 0.68527E-10 -10.1641 0.48216E+00 -0.3168 5 HCO3- 0.29818E-03 -3.5255 0.24472E-03 -3.6113 0.82071E+00 -0.0858 6 HS- 0.66745E-02 -2.1756 0.54690E-02 -2.2621 0.81938E+00 -0.0865 7 Al+++ 0.23248E-28 -28.6336 0.45325E-29 -29.3437 0.19497E+00 -0.7100 8 H4SiO4 0.69577E-03 -3.1575 0.69577E-03 -3.1575 0.10000E+01 0.0000 9 Ca++ 0.23292E-06 -6.6328 0.11129E-06 -6.9536 0.47778E+00 -0.3208 10 Mg++ 0.36488E-10 -10.4379 0.17335E-10 -10.7611 0.47508E+00 -0.3232 11 Fe++ 0.10056E-12 -12.9976 0.47840E-13 -13.3202 0.47572E+00 -0.3226 12 K+ 0.20151E-03 -3.6957 0.16543E-03 -3.7814 0.82095E+00 -0.0857 13 Na+ 0.25582E-01 -1.5921 0.20953E-01 -1.6788 0.81904E+00 -0.0867 14 Mn++ 0.32686E-10 -10.4856 0.15566E-10 -10.8078 0.47621E+00 -0.3222 15 F- 0.92830E-06 -6.0323 0.75857E-06 -6.1200 0.81717E+00 -0.0877 16 HPO4-- 0.30528E-07 -7.5153 0.14722E-07 -7.8320 0.48224E+00 -0.3167 18 HSiO3- 0.84542E-02 -2.0729 0.69260E-02 -2.1595 0.81924E+00 -0.0866 19 Ca(HSiO3)+ 0.21376E-07 -7.6701 0.17553E-07 -7.7556 0.82117E+00 -0.0856 20 Mg(HSiO3)+ 0.41438E-11 -11.3826 0.34028E-11 -11.4682 0.82117E+00 -0.0856 21 NaHSiO3,aq 0.23471E-02 -2.6295 0.23471E-02 -2.6295 0.10000E+01 0.0000 22 AlO+ 0.85256E-16 -16.0693 0.70009E-16 -16.1548 0.82117E+00 -0.0856 24 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 25 AlO2- 0.42866E-05 -5.3679 0.35040E-05 -5.4554 0.81742E+00 -0.0876 26 CH4,aq 0.18965E-01 -1.7220 0.18965E-01 -1.7220 0.10000E+01 0.0000 27 C2H6,aq 0.53155E-08 -8.2745 0.53155E-08 -8.2745 0.10000E+01 0.0000 28 C3H8,aq 0.34395E-13 -13.4635 0.34395E-13 -13.4635 0.10000E+01 0.0000 29 C4H10,aq 0.21864E-18 -18.6603 0.21864E-18 -18.6603 0.10000E+01 0.0000 30 ethanol,aq 0.19528E-15 -15.7093 0.19528E-15 -15.7093 0.10000E+01 0.0000 31 CO,aq 0.14268E-13 -13.8456 0.14268E-13 -13.8456 0.10000E+01 0.0000 32 CO2,aq 0.49083E-07 -7.3091 0.49083E-07 -7.3091 0.10000E+01 0.0000 33 CO3-2 0.47370E-03 -3.3245 0.22780E-03 -3.6424 0.48090E+00 -0.3179 34 CaCO3,aq 0.31787E-06 -6.4977 0.31787E-06 -6.4977 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.84657E-09 -9.0723 0.69517E-09 -9.1579 0.82117E+00 -0.0856 36 CaCl+ 0.33675E-09 -9.4727 0.27653E-09 -9.5583 0.82117E+00 -0.0856 37 CaCl2,aq 0.10088E-12 -12.9962 0.10088E-12 -12.9962 0.10000E+01 0.0000 38 CaF+ 0.15009E-11 -11.8236 0.12325E-11 -11.9092 0.82117E+00 -0.0856 39 CaOH+ 0.10290E-06 -6.9876 0.84496E-07 -7.0732 0.82117E+00 -0.0856 40 CaSO4,aq 0.24216E-14 -14.6159 0.24216E-14 -14.6159 0.10000E+01 0.0000 41 HCl,aq 0.26402E-13 -13.5784 0.26402E-13 -13.5784 0.10000E+01 0.0000 45 HF,aq 0.48727E-12 -12.3122 0.48727E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.15233E-18 -18.8172 0.12480E-18 -18.9038 0.81924E+00 -0.0866 48 FeCl+ 0.14159E-15 -15.8490 0.11627E-15 -15.9345 0.82117E+00 -0.0856 51 FeF+ 0.22583E-17 -17.6462 0.18545E-17 -17.7318 0.82117E+00 -0.0856 53 FeO,aq 0.21110E-09 -9.6755 0.21110E-09 -9.6755 0.10000E+01 0.0000 54 FeOH+ 0.20203E-10 -10.6946 0.16590E-10 -10.7802 0.82117E+00 -0.0856 55 HFeO2- 0.28724E-07 -7.5418 0.23531E-07 -7.6284 0.81924E+00 -0.0866 56 FeO+ 0.14168E-16 -16.8487 0.11634E-16 -16.9343 0.82117E+00 -0.0856 58 FeO2- 0.32993E-09 -9.4816 0.27029E-09 -9.5682 0.81924E+00 -0.0866 59 HFeO2,aq 0.32257E-11 -11.4914 0.32257E-11 -11.4914 0.10000E+01 0.0000 60 H2,aq 0.11568E-04 -4.9367 0.11568E-04 -4.9367 0.10000E+01 0.0000 61 KCl,aq 0.46037E-08 -8.3369 0.46037E-08 -8.3369 0.10000E+01 0.0000 63 KOH,aq 0.75265E-06 -6.1234 0.75265E-06 -6.1234 0.10000E+01 0.0000 64 KSO4- 0.21473E-12 -12.6681 0.17591E-12 -12.7547 0.81924E+00 -0.0866 65 MgCO3,aq 0.12411E-10 -10.9062 0.12411E-10 -10.9062 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13475E-12 -12.8705 0.11065E-12 -12.9561 0.82117E+00 -0.0856 67 MgCl+ 0.47543E-13 -13.3229 0.39040E-13 -13.4085 0.82117E+00 -0.0856 68 MgF+ 0.86606E-15 -15.0625 0.71118E-15 -15.1480 0.82117E+00 -0.0856 69 MgOH+ 0.88692E-10 -10.0521 0.72831E-10 -10.1377 0.82117E+00 -0.0856 71 MnF+ 0.24219E-15 -15.6158 0.19888E-15 -15.7014 0.82117E+00 -0.0856 72 MnO,aq 0.18302E-08 -8.7375 0.18302E-08 -8.7375 0.10000E+01 0.0000 73 MnOH+ 0.61065E-09 -9.2142 0.50144E-09 -9.2998 0.82117E+00 -0.0856 74 MnO2-2 0.14340E-10 -10.8435 0.68960E-11 -11.1614 0.48090E+00 -0.3179 75 HMnO2- 0.17305E-09 -9.7618 0.14176E-09 -9.8484 0.81924E+00 -0.0866 78 MnCl+ 0.17923E-12 -12.7466 0.14718E-12 -12.8322 0.82117E+00 -0.0856 79 MnSO4,aq 0.30793E-18 -18.5115 0.30793E-18 -18.5115 0.10000E+01 0.0000 80 NaCl,aq 0.10662E-04 -4.9722 0.10662E-04 -4.9722 0.10000E+01 0.0000 81 NaF,aq 0.37211E-08 -8.4293 0.37211E-08 -8.4293 0.10000E+01 0.0000 82 NaOH,aq 0.95906E-04 -4.0182 0.95906E-04 -4.0182 0.10000E+01 0.0000 84 OH- 0.75302E-02 -2.1232 0.61553E-02 -2.2107 0.81742E+00 -0.0876 89 HPO3-2 0.11040E-14 -14.9570 0.53090E-15 -15.2750 0.48090E+00 -0.3179 91 H2PO3- 0.12194E-18 -18.9139 0.99897E-19 -19.0004 0.81924E+00 -0.0866 92 H3PO4,aq 0.90657E-18 -18.0426 0.90657E-18 -18.0426 0.10000E+01 0.0000 93 H2PO4- 0.31070E-10 -10.5077 0.25483E-10 -10.5937 0.82019E+00 -0.0861 94 PO4-3 0.61800E-09 -9.2090 0.12801E-09 -9.8928 0.20713E+00 -0.6837 98 HP2O7-3 0.55520E-18 -18.2555 0.10839E-18 -18.9650 0.19523E+00 -0.7094 99 P2O7-4 0.48047E-17 -17.3183 0.27596E-18 -18.5591 0.57436E-01 -1.2408 100 H2S,aq 0.15860E-05 -5.7997 0.15860E-05 -5.7997 0.10000E+01 0.0000 101 S2-2 0.11913E-09 -9.9240 0.57291E-10 -10.2419 0.48090E+00 -0.3179 102 S3-2 0.22006E-16 -16.6575 0.10583E-16 -16.9754 0.48090E+00 -0.3179 107 SO3-2 0.21053E-15 -15.6767 0.10305E-15 -15.9870 0.48948E+00 -0.3103 108 HSO3- 0.73901E-18 -18.1314 0.60542E-18 -18.2179 0.81924E+00 -0.0866 109 HSO4- 0.75372E-17 -17.1228 0.61968E-17 -17.2078 0.82216E+00 -0.0850 111 S2O3-2 0.26557E-17 -17.5758 0.12771E-17 -17.8938 0.48090E+00 -0.3179 Charge balance for all species = -.1737E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1136895E-09 -.1892075E-01 -.1902687E+02 0.0000 2 H2O 0.1000000E+01 0.5552406E+02 0.9979690E+06 0.0000 3 Cl- 0.1874267E-02 0.1884934E-02 0.6667200E+02 7.2139 4 SO4-- 0.1421244E-09 -.1896809E-01 -.1817891E+04 9.8911 5 HCO3- 0.2981805E-03 0.1973745E-01 0.1201538E+04 6.4163 6 HS- 0.6674488E-02 0.2564417E-01 0.8461423E+03 7.7655 7 Al+++ 0.2324790E-28 0.4286797E-05 0.1153967E+00 0.7393 8 H4SiO4 0.6957654E-03 0.1149704E-01 0.1102486E+04 -3.1575 9 Ca++ 0.2329231E-06 0.6762555E-06 0.2704028E-01 13.1017 10 Mg++ 0.3648787E-10 0.1419174E-09 0.3442315E-05 9.2942 11 Fe++ 0.1005622E-12 0.2928812E-07 0.1631871E-02 6.7351 12 K+ 0.2015094E-03 0.2022667E-03 0.7890738E+01 6.2463 13 Na+ 0.2558192E-01 0.2803557E-01 0.6430413E+03 8.3489 14 Mn++ 0.3268615E-10 0.2661074E-08 0.1458559E-03 9.2474 15 F- 0.9282953E-06 0.9320184E-06 0.1766553E-01 3.9076 16 HPO4-- 0.3052798E-07 0.3117705E-07 0.2985421E-02 12.2233 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277790E+02 -.9437772E-02 -.8276847E+02 0.0000000E+00 2 H2O -.7057454E+01 0.2769570E+02 -.3475315E+02 0.0000000E+00 3 Cl- 0.9402152E-03 0.9402152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1392419E+00 -.9461387E-02 0.1487033E+00 0.0000000E+00 5 HCO3- 0.9845147E-02 0.9845147E-02 0.0000000E+00 0.0000000E+00 6 HS- -.1359118E+00 0.1279145E-01 -.1487033E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2138277E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5734784E-02 0.5205817E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.3373198E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.7078915E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1460907E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1008917E-03 0.1061470E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1398429E-01 0.6262393E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1327358E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5449600E-04 0.4648958E-06 0.5403110E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1555128E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.4573E-14 Mass of aqueous solution: 0.499962E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1359900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.99 628.8 andradite 0.5948 -0.226 302.3 2.480 5.534 78.53 grossular 0.1440 -0.842 64.87 1.812 1.188 18.05 apatite-OH 0.9809E-02 -2.008 4.927 0.693 0.9020E-01 1.566 apatite-F 0.5403E-04 -4.267 0.2725E-01 -1.565 0.4988E-03 0.8512E-02 clinochlore 0.7008 -0.154 389.5 2.591 7.131 148.2 daphnite 0.2029 -0.693 144.8 2.161 2.650 43.87 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9414 -0.026 262.0 2.418 4.797 102.4 stilbite 3.229 0.509 2275. 3.357 41.66 1061. stilpnomelane-Fe 0.2401 -0.620 258.9 2.413 4.739 89.42 tr.625ac.25prg.125 0.1281 -0.892 109.5 2.039 2.005 35.24 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7609E+00 0.7609E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1883E-01 0.1883E-01 1.0000 -1.725 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.377332 g Volume = 2211.161198 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1359900 moles log = -0.8665 Original solution: 1000.0103000 g Original solution / Rock added: 7353.56 (Water/Rock Ratio), log = 3.8665 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 29.4891 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3623E-01 0.9412 0.1006E+01 0.1068E+01 CO2,gas 0.1875E-06 0.9495 0.5251E-05 0.5531E-05 CH4,gas 0.9633E+00 0.9827 0.2792E+02 0.2841E+02 H2,gas 0.5070E-03 1.0158 0.1519E-01 0.1495E-01 H2S,gas 0.1654E-05 0.8938 0.4360E-04 0.4878E-04 S2,gas 0.1049E-25 1.0000 0.3093E-24 0.3093E-24 CO,gas 0.7210E-12 1.0000 0.2126E-10 0.2126E-10 SO3,gas 0.7739E-47 1.0000 0.2282E-45 0.2282E-45 SO2,gas 0.4574E-26 1.0000 0.1349E-24 0.1349E-24 HF,gas 0.4057E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1580E-17 1.0000 0.4659E-16 0.4659E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 117 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 164 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.64 -6.98 -2.326 0.11916E+05 -5.280 3 CH4,gas 4.54 4.29 -0.25 -0.063 0.43220E+03 1.446 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60060E+04 -1.819 5 H2S,gas -6.23 -12.29 -6.06 -3.030 0.10346E+05 -4.361 6 S2,gas -7.34 -33.54 -26.21 -4.032 0.44750E+05 -24.510 7 CO,gas 3.21 -9.16 -12.37 -3.807 0.21124E+05 -10.672 8 SO3,gas 17.12 -30.22 -47.34 -11.835 0.80833E+05 -45.642 9 SO2,gas 0.83 -25.74 -26.57 -7.085 0.45366E+05 -24.870 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.84 -18.03 -9.015 0.30787E+05 -16.332 12 acmite 7.71 6.53 -1.18 -0.123 0.20177E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.75 -4.71 -0.235 0.80406E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93678E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41069E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28499E+04 30 anorthite 12.71 8.27 -4.45 -0.342 0.75899E+04 38 aragonite 0.97 -0.54 -1.50 -0.501 0.25676E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55914E+04 40 calcite 0.81 -0.54 -1.35 -0.450 0.23034E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52807E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71077E+04 43 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 44 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82204E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28881E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 47 chrysotile 23.89 21.57 -2.33 -0.194 0.39699E+04 52 chlorite-Al-free 47.17 43.13 -4.04 -0.168 0.68949E+04 54 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65449E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13338E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10192E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 69 diamond -3.10 -4.67 -1.57 -0.449 0.26834E+04 72 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 74 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 76 epidote 24.67 22.70 -1.97 -0.095 0.33582E+04 77 clinozoisite 22.81 18.95 -3.86 -0.175 0.65866E+04 78 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57763E+04 79 fayalite 14.05 10.31 -3.73 -0.533 0.63742E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68198E+04 84 gibbsite 4.08 0.74 -3.34 -0.477 0.57038E+04 85 glaucophane 22.97 20.80 -2.18 -0.059 0.37138E+04 86 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70918E+04 87 graphite -3.55 -4.67 -1.13 -0.322 0.19257E+04 88 greenalite 16.14 13.89 -2.25 -0.187 0.38410E+04 91 hematite 12.57 8.99 -3.58 -0.434 0.61106E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 96 jadeite 4.22 2.77 -1.44 -0.144 0.24620E+04 98 kalsilite 7.58 3.83 -3.76 -0.537 0.64131E+04 99 kaolinite -1.33 -4.84 -3.50 -0.319 0.59828E+04 102 laumontite 2.88 1.95 -0.93 -0.062 0.15936E+04 103 lawsonite 9.62 8.26 -1.35 -0.090 0.23071E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58876E+04 106 lizardite 23.24 21.57 -1.68 -0.140 0.28625E+04 108 magnetite 20.09 15.72 -4.37 -0.356 0.74532E+04 109 minnesotaite 10.39 7.58 -2.81 -0.165 0.48022E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82143E+04 121 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 122 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 123 nepheline 8.34 5.93 -2.41 -0.344 0.41130E+04 129 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83524E+04 135 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36687E+04 137 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 138 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91148E+03 139 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40585E+04 140 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43425E+04 143 pyrite -21.25 -22.33 -1.08 -0.254 0.18436E+04 144 pyrrhotite -4.26 -5.55 -1.29 -0.431 0.22101E+04 145 pyrrhotiteFe0.875 -6.02 -6.95 -0.94 -0.344 0.15972E+04 146 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22344E+04 147 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84950E+04 148 quartz -2.99 -3.16 -0.17 -0.056 0.28652E+03 152 rhodochrosite -0.98 -4.39 -3.42 -1.138 0.58314E+04 153 rhodonite 7.45 6.09 -1.36 -0.271 0.23147E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.90 -4.30 -1.432 0.73349E+04 166 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27811E+04 172 talc 16.49 15.25 -1.24 -0.073 0.21139E+04 175 tephroite 18.09 15.34 -2.75 -0.393 0.46929E+04 179 tridymite -2.63 -3.16 -0.53 -0.177 0.90650E+03 180 tremolite 47.87 47.42 -0.45 -0.012 0.77502E+03 181 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65441E+04 182 troilite-low -4.41 -5.55 -1.14 -0.381 0.19529E+04 184 vesuvianite 223.47 218.82 -4.65 -0.036 0.79473E+04 188 wairakite 3.95 1.95 -2.00 -0.118 0.34150E+04 189 walstromite 11.51 9.94 -1.56 -0.313 0.26720E+04 190 wollastonite 10.46 9.94 -0.52 -0.103 0.88244E+03 191 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18023E+04 192 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 193 akaganeite 7.75 4.49 -3.26 -0.705 0.55680E+04 200 chalcedony -2.80 -3.16 -0.35 -0.118 0.60582E+03 202 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66171E+04 203 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68810E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73668E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60358E+04 206 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58202E+04 207 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83472E+04 208 nontronite-K 3.34 -0.29 -3.64 -0.233 0.62073E+04 209 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66540E+04 210 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53282E+04 226 tobermorite 9.82 7.76 -2.07 -0.564 0.35291E+04 232 alabandite -0.98 -3.04 -2.06 -0.688 0.35249E+04 235 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52533E+04 243 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18200E+04 245 an20ab80 2.02 1.35 -0.67 -0.052 0.11471E+04 246 an25ab75 2.65 1.78 -0.87 -0.067 0.14809E+04 247 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1359900 MOLES New total amount of reactant added: 0.1399900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1399900 Water: Moles liquid = 0.2769E+02 kg liquid = 0.4988E+00 Moles total = -.7054E+01 kg total = -.1271E+00 Activity = 0.9996 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2649973E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.9638E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11478E-09 -9.9401 0.94672E-10 -10.0238 0.82483E+00 -0.0836 2 H2O 0.99965E+00 -0.0002 0.99965E+00 -0.0002 3 Cl- 0.19214E-02 -2.7164 0.15730E-02 -2.8033 0.81868E+00 -0.0869 4 SO4-- 0.15341E-09 -9.8142 0.73774E-10 -10.1321 0.48090E+00 -0.3179 5 HCO3- 0.32097E-03 -3.4935 0.26325E-03 -3.5796 0.82017E+00 -0.0861 6 HS- 0.68697E-02 -2.1631 0.56251E-02 -2.2499 0.81883E+00 -0.0868 7 Al+++ 0.23975E-28 -28.6202 0.46463E-29 -29.3329 0.19380E+00 -0.7126 8 H4SiO4 0.69654E-03 -3.1571 0.69654E-03 -3.1571 0.10000E+01 0.0000 9 Ca++ 0.23678E-06 -6.6257 0.11282E-06 -6.9476 0.47650E+00 -0.3219 10 Mg++ 0.37258E-10 -10.4288 0.17653E-10 -10.7532 0.47379E+00 -0.3244 11 Fe++ 0.10255E-12 -12.9890 0.48655E-13 -13.3129 0.47444E+00 -0.3238 12 K+ 0.20314E-03 -3.6922 0.16666E-03 -3.7782 0.82040E+00 -0.0860 13 Na+ 0.25789E-01 -1.5886 0.21108E-01 -1.6755 0.81848E+00 -0.0870 14 Mn++ 0.33350E-10 -10.4769 0.15839E-10 -10.8003 0.47493E+00 -0.3234 15 F- 0.92071E-06 -6.0359 0.75185E-06 -6.1239 0.81660E+00 -0.0880 16 HPO4-- 0.30272E-07 -7.5190 0.14561E-07 -7.8368 0.48099E+00 -0.3179 18 HSiO3- 0.83944E-02 -2.0760 0.68724E-02 -2.1629 0.81868E+00 -0.0869 19 Ca(HSiO3)+ 0.21518E-07 -7.6672 0.17658E-07 -7.7531 0.82062E+00 -0.0859 20 Mg(HSiO3)+ 0.41899E-11 -11.3778 0.34384E-11 -11.4636 0.82062E+00 -0.0859 21 NaHSiO3,aq 0.23462E-02 -2.6296 0.23462E-02 -2.6296 0.10000E+01 0.0000 22 AlO+ 0.85911E-16 -16.0659 0.70501E-16 -16.1518 0.82062E+00 -0.0859 24 HAlO2,aq 0.14825E-09 -9.8290 0.14825E-09 -9.8290 0.10000E+01 0.0000 25 AlO2- 0.42436E-05 -5.3723 0.34664E-05 -5.4601 0.81685E+00 -0.0879 26 CH4,aq 0.19491E-01 -1.7102 0.19491E-01 -1.7102 0.10000E+01 0.0000 27 C2H6,aq 0.56912E-08 -8.2448 0.56912E-08 -8.2448 0.10000E+01 0.0000 28 C3H8,aq 0.38367E-13 -13.4160 0.38367E-13 -13.4160 0.10000E+01 0.0000 29 C4H10,aq 0.25409E-18 -18.5950 0.25409E-18 -18.5950 0.10000E+01 0.0000 30 ethanol,aq 0.21195E-15 -15.6738 0.21195E-15 -15.6738 0.10000E+01 0.0000 31 CO,aq 0.15276E-13 -13.8160 0.15276E-13 -13.8160 0.10000E+01 0.0000 32 CO2,aq 0.53271E-07 -7.2735 0.53271E-07 -7.2735 0.10000E+01 0.0000 33 CO3-2 0.50638E-03 -3.2955 0.24288E-03 -3.6146 0.47964E+00 -0.3191 34 CaCO3,aq 0.34359E-06 -6.4640 0.34359E-06 -6.4640 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.92385E-09 -9.0344 0.75813E-09 -9.1203 0.82062E+00 -0.0859 36 CaCl+ 0.34998E-09 -9.4560 0.28720E-09 -9.5418 0.82062E+00 -0.0859 37 CaCl2,aq 0.10733E-12 -12.9693 0.10733E-12 -12.9693 0.10000E+01 0.0000 38 CaF+ 0.15092E-11 -11.8213 0.12385E-11 -11.9071 0.82062E+00 -0.0859 39 CaOH+ 0.10346E-06 -6.9852 0.84905E-07 -7.0711 0.82062E+00 -0.0859 40 CaSO4,aq 0.26431E-14 -14.5779 0.26431E-14 -14.5779 0.10000E+01 0.0000 41 HCl,aq 0.27288E-13 -13.5640 0.27288E-13 -13.5640 0.10000E+01 0.0000 45 HF,aq 0.48727E-12 -12.3122 0.48727E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.15108E-18 -18.8208 0.12369E-18 -18.9077 0.81868E+00 -0.0869 48 FeCl+ 0.14762E-15 -15.8309 0.12114E-15 -15.9167 0.82062E+00 -0.0859 51 FeF+ 0.22780E-17 -17.6424 0.18694E-17 -17.7283 0.82062E+00 -0.0859 53 FeO,aq 0.21091E-09 -9.6759 0.21091E-09 -9.6759 0.10000E+01 0.0000 54 FeOH+ 0.20379E-10 -10.6908 0.16723E-10 -10.7767 0.82062E+00 -0.0859 55 HFeO2- 0.28463E-07 -7.5457 0.23302E-07 -7.6326 0.81868E+00 -0.0869 56 FeO+ 0.14389E-16 -16.8420 0.11808E-16 -16.9278 0.82062E+00 -0.0859 58 FeO2- 0.32917E-09 -9.4826 0.26949E-09 -9.5695 0.81868E+00 -0.0869 59 HFeO2,aq 0.32449E-11 -11.4888 0.32449E-11 -11.4888 0.10000E+01 0.0000 60 H2,aq 0.11411E-04 -4.9427 0.11411E-04 -4.9427 0.10000E+01 0.0000 61 KCl,aq 0.47512E-08 -8.3232 0.47512E-08 -8.3232 0.10000E+01 0.0000 63 KOH,aq 0.75151E-06 -6.1241 0.75151E-06 -6.1241 0.10000E+01 0.0000 64 KSO4- 0.23304E-12 -12.6326 0.19079E-12 -12.7194 0.81868E+00 -0.0869 65 MgCO3,aq 0.13475E-10 -10.8705 0.13475E-10 -10.8705 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14770E-12 -12.8306 0.12121E-12 -12.9165 0.82062E+00 -0.0859 67 MgCl+ 0.49630E-13 -13.3043 0.40728E-13 -13.3901 0.82062E+00 -0.0859 68 MgF+ 0.87470E-15 -15.0581 0.71780E-15 -15.1440 0.82062E+00 -0.0859 69 MgOH+ 0.89577E-10 -10.0478 0.73509E-10 -10.1337 0.82062E+00 -0.0859 71 MnF+ 0.24442E-15 -15.6119 0.20058E-15 -15.6977 0.82062E+00 -0.0859 72 MnO,aq 0.18295E-08 -8.7377 0.18295E-08 -8.7377 0.10000E+01 0.0000 73 MnOH+ 0.61627E-09 -9.2102 0.50573E-09 -9.2961 0.82062E+00 -0.0859 74 MnO2-2 0.14119E-10 -10.8502 0.67718E-11 -11.1693 0.47964E+00 -0.3191 75 HMnO2- 0.17156E-09 -9.7656 0.14045E-09 -9.8525 0.81868E+00 -0.0869 78 MnCl+ 0.18695E-12 -12.7283 0.15342E-12 -12.8141 0.82062E+00 -0.0859 79 MnSO4,aq 0.33733E-18 -18.4719 0.33733E-18 -18.4719 0.10000E+01 0.0000 80 NaCl,aq 0.11003E-04 -4.9585 0.11003E-04 -4.9585 0.10000E+01 0.0000 81 NaF,aq 0.37155E-08 -8.4300 0.37155E-08 -8.4300 0.10000E+01 0.0000 82 NaOH,aq 0.95762E-04 -4.0188 0.95762E-04 -4.0188 0.10000E+01 0.0000 84 OH- 0.74686E-02 -2.1268 0.61008E-02 -2.2146 0.81685E+00 -0.0879 89 HPO3-2 0.10799E-14 -14.9666 0.51798E-15 -15.2857 0.47964E+00 -0.3191 91 H2PO3- 0.12011E-18 -18.9204 0.98335E-19 -19.0073 0.81868E+00 -0.0869 92 H3PO4,aq 0.91273E-18 -18.0397 0.91273E-18 -18.0397 0.10000E+01 0.0000 93 H2PO4- 0.31025E-10 -10.5083 0.25429E-10 -10.5947 0.81965E+00 -0.0864 94 PO4-3 0.60920E-09 -9.2152 0.12549E-09 -9.9014 0.20599E+00 -0.6862 98 HP2O7-3 0.55124E-18 -18.2587 0.10698E-18 -18.9707 0.19407E+00 -0.7120 99 P2O7-4 0.47490E-17 -17.3234 0.26995E-18 -18.5687 0.56844E-01 -1.2453 100 H2S,aq 0.16459E-05 -5.7836 0.16459E-05 -5.7836 0.10000E+01 0.0000 101 S2-2 0.12810E-09 -9.8924 0.61441E-10 -10.2115 0.47964E+00 -0.3191 102 S3-2 0.24892E-16 -16.6039 0.11939E-16 -16.9230 0.47964E+00 -0.3191 107 SO3-2 0.22414E-15 -15.6495 0.10944E-15 -15.9608 0.48825E+00 -0.3114 108 HSO3- 0.79237E-18 -18.1011 0.64870E-18 -18.1880 0.81868E+00 -0.0869 109 HSO4- 0.81922E-17 -17.0866 0.67309E-17 -17.1719 0.82163E+00 -0.0853 111 S2O3-2 0.29748E-17 -17.5265 0.14268E-17 -17.8456 0.47964E+00 -0.3191 Charge balance for all species = -.1736E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1147768E-09 -.1883082E-01 -.1893608E+02 0.0000 2 H2O 0.1000000E+01 0.5552459E+02 0.9979594E+06 0.0000 3 Cl- 0.1921352E-02 0.1932361E-02 0.6834823E+02 7.2205 4 SO4-- 0.1534076E-09 -.1949354E-01 -.1868214E+04 9.9155 5 HCO3- 0.3209656E-03 0.2031843E-01 0.1236883E+04 6.4441 6 HS- 0.6869698E-02 0.2636489E-01 0.8699062E+03 7.7739 7 Al+++ 0.2397462E-28 0.4243709E-05 0.1142346E+00 0.7385 8 H4SiO4 0.6965407E-03 0.1143718E-01 0.1096726E+04 -3.1571 9 Ca++ 0.2367756E-06 0.7066259E-06 0.2825411E-01 13.1000 10 Mg++ 0.3725828E-10 0.1446992E-09 0.3509723E-05 9.2944 11 Fe++ 0.1025539E-12 0.2902668E-07 0.1617273E-02 6.7347 12 K+ 0.2031399E-03 0.2038962E-03 0.7954155E+01 6.2456 13 Na+ 0.2578934E-01 0.2824230E-01 0.6477707E+03 8.3482 14 Mn++ 0.3335003E-10 0.2664950E-08 0.1460656E-03 9.2473 15 F- 0.9207063E-06 0.9244238E-06 0.1752125E-01 3.8999 16 HPO4-- 0.3027245E-07 0.3091267E-07 0.2960049E-02 12.2107 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277747E+02 -.9392363E-02 -.8276808E+02 0.0000000E+00 2 H2O -.7054179E+01 0.2769433E+02 -.3474851E+02 0.0000000E+00 3 Cl- 0.9638152E-03 0.9638152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1392610E+00 -.9722912E-02 0.1489839E+00 0.0000000E+00 5 HCO3- 0.1013435E-01 0.1013435E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1358337E+00 0.1315017E-01 -.1489839E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2116660E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5704591E-02 0.5205820E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.3524480E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.7217249E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1447781E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1016985E-03 0.1061469E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1408658E-01 0.6262290E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1329213E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5609600E-04 0.4610804E-06 0.5563492E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1541850E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.2075E-14 Mass of aqueous solution: 0.499942E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1399900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.8 andradite 0.5959 -0.225 302.8 2.481 5.544 78.68 grossular 0.1432 -0.844 64.48 1.809 1.180 17.94 apatite-OH 0.9807E-02 -2.008 4.926 0.693 0.9018E-01 1.565 apatite-F 0.5563E-04 -4.255 0.2806E-01 -1.552 0.5136E-03 0.8765E-02 clinochlore 0.7013 -0.154 389.8 2.591 7.136 148.3 daphnite 0.2028 -0.693 144.7 2.160 2.649 43.85 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9415 -0.026 262.1 2.418 4.797 102.4 stilbite 3.229 0.509 2276. 3.357 41.66 1061. stilpnomelane-Fe 0.2400 -0.620 258.7 2.413 4.736 89.36 tr.625ac.25prg.125 0.1274 -0.895 108.9 2.037 1.993 35.04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8063E+00 0.8063E+00 1.0000 -0.093 grossular 0.1937E+00 0.1937E+00 1.0000 -0.713 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2201E+00 0.2201E+00 1.0000 -0.657 chlorite-Mn 0.1882E-01 0.1882E-01 1.0000 -1.725 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.479588 g Volume = 2211.260870 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1399900 moles log = -0.8539 Original solution: 1000.0103000 g Original solution / Rock added: 7143.44 (Water/Rock Ratio), log = 3.8539 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 30.2908 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3531E-01 0.9402 0.1006E+01 0.1070E+01 CO2,gas 0.1984E-06 0.9483 0.5699E-05 0.6010E-05 CH4,gas 0.9642E+00 0.9823 0.2869E+02 0.2921E+02 H2,gas 0.4867E-03 1.0163 0.1498E-01 0.1474E-01 H2S,gas 0.1676E-05 0.8912 0.4524E-04 0.5077E-04 S2,gas 0.1130E-25 1.0000 0.3423E-24 0.3423E-24 CO,gas 0.7515E-12 1.0000 0.2276E-10 0.2276E-10 SO3,gas 0.8256E-47 1.0000 0.2501E-45 0.2501E-45 SO2,gas 0.4814E-26 1.0000 0.1458E-24 0.1458E-24 HF,gas 0.3950E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1590E-17 1.0000 0.4815E-16 0.4815E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.48529E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 117 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 164 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.60 -6.94 -2.314 0.11855E+05 -5.244 3 CH4,gas 4.54 4.30 -0.24 -0.060 0.41194E+03 1.458 4 H2,gas 8.00 4.48 -3.52 -2.013 0.60161E+04 -1.824 5 H2S,gas -6.23 -12.27 -6.04 -3.022 0.10319E+05 -4.344 6 S2,gas -7.34 -33.50 -26.16 -4.025 0.44675E+05 -24.466 7 CO,gas 3.21 -9.13 -12.34 -3.797 0.21073E+05 -10.643 8 SO3,gas 17.12 -30.18 -47.30 -11.825 0.80765E+05 -45.602 9 SO2,gas 0.83 -25.70 -26.54 -7.076 0.45308E+05 -24.836 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.83 -18.02 -9.008 0.30762E+05 -16.317 12 acmite 7.71 6.53 -1.18 -0.122 0.20127E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.75 -4.71 -0.235 0.80418E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93763E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41089E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28491E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75941E+04 38 aragonite 0.97 -0.50 -1.47 -0.490 0.25099E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55911E+04 40 calcite 0.81 -0.50 -1.32 -0.438 0.22457E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52824E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71093E+04 43 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70437E+04 44 carpholite-Fe 6.71 1.90 -4.82 -0.321 0.82223E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28870E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47560E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39674E+04 52 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68899E+04 54 chloritoid-Fe 9.17 5.05 -4.12 -0.275 0.70340E+04 55 chloritoid-Mn 11.40 7.57 -3.83 -0.256 0.65471E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13330E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10184E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71236E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36464E+04 69 diamond -3.10 -4.65 -1.55 -0.442 0.26429E+04 72 enstatite 17.26 12.27 -4.99 -0.499 0.85202E+04 74 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83518E+04 76 epidote 24.67 22.70 -1.97 -0.095 0.33601E+04 77 clinozoisite 22.81 18.94 -3.86 -0.176 0.65944E+04 78 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57725E+04 79 fayalite 14.05 10.31 -3.73 -0.533 0.63747E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68194E+04 84 gibbsite 4.08 0.74 -3.34 -0.477 0.57052E+04 85 glaucophane 22.97 20.80 -2.17 -0.059 0.37112E+04 86 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70921E+04 87 graphite -3.55 -4.65 -1.10 -0.315 0.18852E+04 88 greenalite 16.14 13.89 -2.25 -0.187 0.38413E+04 91 hematite 12.57 8.99 -3.57 -0.433 0.61018E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 96 jadeite 4.22 2.77 -1.44 -0.144 0.24629E+04 98 kalsilite 7.58 3.83 -3.76 -0.537 0.64148E+04 99 kaolinite -1.33 -4.84 -3.50 -0.319 0.59840E+04 102 laumontite 2.88 1.95 -0.93 -0.062 0.15961E+04 103 lawsonite 9.62 8.26 -1.35 -0.090 0.23113E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58884E+04 106 lizardite 23.24 21.57 -1.67 -0.140 0.28600E+04 107 magnesite 0.69 -4.31 -5.00 -1.667 0.85368E+04 108 magnetite 20.09 15.73 -4.36 -0.356 0.74451E+04 109 minnesotaite 10.39 7.58 -2.81 -0.165 0.48008E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82146E+04 121 muscovite 2.58 -1.01 -3.59 -0.211 0.61343E+04 122 paragonite 4.24 1.09 -3.15 -0.185 0.53734E+04 123 nepheline 8.34 5.93 -2.41 -0.344 0.41147E+04 129 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83530E+04 135 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36679E+04 137 prehnite 19.37 18.21 -1.17 -0.069 0.19913E+04 138 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91202E+03 139 pumpellyite-Fe 46.27 43.88 -2.39 -0.053 0.40733E+04 140 pumpellyite-Mg 48.99 46.44 -2.55 -0.057 0.43563E+04 143 pyrite -21.25 -22.29 -1.04 -0.245 0.17792E+04 144 pyrrhotite -4.26 -5.54 -1.28 -0.426 0.21832E+04 145 pyrrhotiteFe0.875 -6.02 -6.94 -0.92 -0.338 0.15690E+04 146 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22339E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84945E+04 148 quartz -2.99 -3.16 -0.17 -0.056 0.28568E+03 152 rhodochrosite -0.98 -4.36 -3.38 -1.127 0.57709E+04 153 rhodonite 7.45 6.09 -1.36 -0.271 0.23141E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.87 -4.26 -1.420 0.72748E+04 166 stilpnomelane-Mg 27.44 25.82 -1.63 -0.049 0.27764E+04 172 talc 16.49 15.26 -1.24 -0.073 0.21097E+04 175 tephroite 18.09 15.34 -2.75 -0.393 0.46926E+04 179 tridymite -2.63 -3.16 -0.53 -0.177 0.90566E+03 180 tremolite 47.87 47.42 -0.45 -0.012 0.77293E+03 181 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65468E+04 182 troilite-low -4.41 -5.54 -1.13 -0.376 0.19260E+04 184 vesuvianite 223.47 218.78 -4.69 -0.036 0.80044E+04 188 wairakite 3.95 1.95 -2.00 -0.118 0.34175E+04 189 walstromite 11.51 9.94 -1.57 -0.313 0.26742E+04 190 wollastonite 10.46 9.94 -0.52 -0.104 0.88462E+03 191 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18044E+04 192 zoisite 22.85 18.94 -3.91 -0.178 0.66684E+04 193 akaganeite 7.75 4.50 -3.26 -0.705 0.55636E+04 200 chalcedony -2.80 -3.16 -0.35 -0.118 0.60498E+03 202 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66165E+04 203 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68802E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73657E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60351E+04 206 nontronite-Ca 3.21 -0.19 -3.40 -0.221 0.58093E+04 207 nontronite-H 2.53 -2.35 -4.88 -0.327 0.83358E+04 208 nontronite-K 3.34 -0.29 -3.63 -0.233 0.61963E+04 209 nontronite-Mg 3.07 -0.82 -3.89 -0.252 0.66426E+04 210 nontronite-Na 3.52 0.41 -3.11 -0.200 0.53171E+04 226 tobermorite 9.82 7.76 -2.07 -0.564 0.35308E+04 232 alabandite -0.98 -3.03 -2.05 -0.683 0.34978E+04 235 boehmite 4.41 0.74 -3.67 -0.611 0.62633E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52540E+04 243 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18192E+04 245 an20ab80 2.02 1.35 -0.67 -0.052 0.11480E+04 246 an25ab75 2.65 1.78 -0.87 -0.067 0.14819E+04 247 an30ab70 3.28 2.21 -1.07 -0.082 0.18255E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1399900 MOLES New total amount of reactant added: 0.1439900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1439900 Water: Moles liquid = 0.2768E+02 kg liquid = 0.4987E+00 Moles total = -.7051E+01 kg total = -.1270E+00 Activity = 0.9996 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2674751E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.9874E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11589E-09 -9.9360 0.95526E-10 -10.0199 0.82431E+00 -0.0839 2 H2O 0.99964E+00 -0.0002 0.99964E+00 -0.0002 3 Cl- 0.19684E-02 -2.7059 0.16104E-02 -2.7931 0.81812E+00 -0.0872 4 SO4-- 0.16543E-09 -9.7814 0.79343E-10 -10.1005 0.47962E+00 -0.3191 5 HCO3- 0.34513E-03 -3.4620 0.28287E-03 -3.5484 0.81962E+00 -0.0864 6 HS- 0.70649E-02 -2.1509 0.57810E-02 -2.2380 0.81827E+00 -0.0871 7 Al+++ 0.24734E-28 -28.6067 0.47643E-29 -29.3220 0.19262E+00 -0.7153 8 H4SiO4 0.69732E-03 -3.1566 0.69732E-03 -3.1566 0.10000E+01 0.0000 9 Ca++ 0.24075E-06 -6.6184 0.11440E-06 -6.9416 0.47520E+00 -0.3231 10 Mg++ 0.38054E-10 -10.4196 0.17980E-10 -10.7452 0.47248E+00 -0.3256 11 Fe++ 0.10461E-12 -12.9804 0.49494E-13 -13.3054 0.47313E+00 -0.3250 12 K+ 0.20480E-03 -3.6887 0.16791E-03 -3.7749 0.81985E+00 -0.0863 13 Na+ 0.26001E-01 -1.5850 0.21267E-01 -1.6723 0.81792E+00 -0.0873 14 Mn++ 0.34035E-10 -10.4681 0.16120E-10 -10.7926 0.47362E+00 -0.3246 15 F- 0.91311E-06 -6.0395 0.74512E-06 -6.1278 0.81602E+00 -0.0883 16 HPO4-- 0.30015E-07 -7.5227 0.14399E-07 -7.8417 0.47971E+00 -0.3190 18 HSiO3- 0.83344E-02 -2.0791 0.68186E-02 -2.1663 0.81812E+00 -0.0872 19 Ca(HSiO3)+ 0.21663E-07 -7.6643 0.17765E-07 -7.7504 0.82007E+00 -0.0861 20 Mg(HSiO3)+ 0.42370E-11 -11.3729 0.34747E-11 -11.4591 0.82007E+00 -0.0861 21 NaHSiO3,aq 0.23453E-02 -2.6298 0.23453E-02 -2.6298 0.10000E+01 0.0000 22 AlO+ 0.86581E-16 -16.0626 0.71003E-16 -16.1487 0.82007E+00 -0.0861 24 HAlO2,aq 0.14797E-09 -9.8298 0.14797E-09 -9.8298 0.10000E+01 0.0000 25 AlO2- 0.42006E-05 -5.3767 0.34288E-05 -5.4649 0.81628E+00 -0.0882 26 CH4,aq 0.20013E-01 -1.6987 0.20013E-01 -1.6987 0.10000E+01 0.0000 27 C2H6,aq 0.60827E-08 -8.2159 0.60827E-08 -8.2159 0.10000E+01 0.0000 28 C3H8,aq 0.42682E-13 -13.3698 0.42682E-13 -13.3698 0.10000E+01 0.0000 29 C4H10,aq 0.29422E-18 -18.5313 0.29422E-18 -18.5313 0.10000E+01 0.0000 30 ethanol,aq 0.22963E-15 -15.6390 0.22963E-15 -15.6390 0.10000E+01 0.0000 31 CO,aq 0.16339E-13 -13.7868 0.16339E-13 -13.7868 0.10000E+01 0.0000 32 CO2,aq 0.57760E-07 -7.2384 0.57760E-07 -7.2384 0.10000E+01 0.0000 33 CO3-2 0.54071E-03 -3.2670 0.25865E-03 -3.5873 0.47835E+00 -0.3203 34 CaCO3,aq 0.37103E-06 -6.4306 0.37103E-06 -6.4306 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10073E-08 -8.9968 0.82606E-09 -9.0830 0.82007E+00 -0.0861 36 CaCl+ 0.36357E-09 -9.4394 0.29815E-09 -9.5256 0.82007E+00 -0.0861 37 CaCl2,aq 0.11407E-12 -12.9428 0.11407E-12 -12.9428 0.10000E+01 0.0000 38 CaF+ 0.15176E-11 -11.8188 0.12446E-11 -11.9050 0.82007E+00 -0.0861 39 CaOH+ 0.10404E-06 -6.9828 0.85323E-07 -7.0689 0.82007E+00 -0.0861 40 CaSO4,aq 0.28824E-14 -14.5402 0.28824E-14 -14.5402 0.10000E+01 0.0000 41 HCl,aq 0.28190E-13 -13.5499 0.28190E-13 -13.5499 0.10000E+01 0.0000 45 HF,aq 0.48726E-12 -12.3122 0.48726E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.14983E-18 -18.8244 0.12258E-18 -18.9116 0.81812E+00 -0.0872 48 FeCl+ 0.15384E-15 -15.8129 0.12616E-15 -15.8991 0.82007E+00 -0.0861 51 FeF+ 0.22980E-17 -17.6386 0.18846E-17 -17.7248 0.82007E+00 -0.0861 53 FeO,aq 0.21073E-09 -9.6763 0.21073E-09 -9.6763 0.10000E+01 0.0000 54 FeOH+ 0.20558E-10 -10.6870 0.16859E-10 -10.7732 0.82007E+00 -0.0861 55 HFeO2- 0.28202E-07 -7.5497 0.23073E-07 -7.6369 0.81812E+00 -0.0872 56 FeO+ 0.14615E-16 -16.8352 0.11985E-16 -16.9213 0.82007E+00 -0.0861 58 FeO2- 0.32839E-09 -9.4836 0.26866E-09 -9.5708 0.81812E+00 -0.0872 59 HFeO2,aq 0.32641E-11 -11.4862 0.32641E-11 -11.4862 0.10000E+01 0.0000 60 H2,aq 0.11257E-04 -4.9486 0.11257E-04 -4.9486 0.10000E+01 0.0000 61 KCl,aq 0.49008E-08 -8.3097 0.49008E-08 -8.3097 0.10000E+01 0.0000 63 KOH,aq 0.75038E-06 -6.1247 0.75038E-06 -6.1247 0.10000E+01 0.0000 64 KSO4- 0.25269E-12 -12.5974 0.20673E-12 -12.6846 0.81812E+00 -0.0872 65 MgCO3,aq 0.14616E-10 -10.8352 0.14616E-10 -10.8352 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.16176E-12 -12.7911 0.13266E-12 -12.8773 0.82007E+00 -0.0861 67 MgCl+ 0.51787E-13 -13.2858 0.42469E-13 -13.3719 0.82007E+00 -0.0861 68 MgF+ 0.88353E-15 -15.0538 0.72456E-15 -15.1399 0.82007E+00 -0.0861 69 MgOH+ 0.90481E-10 -10.0434 0.74201E-10 -10.1296 0.82007E+00 -0.0861 71 MnF+ 0.24670E-15 -15.6078 0.20231E-15 -15.6940 0.82007E+00 -0.0861 72 MnO,aq 0.18288E-08 -8.7378 0.18288E-08 -8.7378 0.10000E+01 0.0000 73 MnOH+ 0.62201E-09 -9.2062 0.51009E-09 -9.2924 0.82007E+00 -0.0861 74 MnO2-2 0.13899E-10 -10.8570 0.66486E-11 -11.1773 0.47835E+00 -0.3203 75 HMnO2- 0.17008E-09 -9.7694 0.13914E-09 -9.8565 0.81812E+00 -0.0872 78 MnCl+ 0.19493E-12 -12.7101 0.15986E-12 -12.7963 0.82007E+00 -0.0861 79 MnSO4,aq 0.36924E-18 -18.4327 0.36924E-18 -18.4327 0.10000E+01 0.0000 80 NaCl,aq 0.11350E-04 -4.9450 0.11350E-04 -4.9450 0.10000E+01 0.0000 81 NaF,aq 0.37099E-08 -8.4306 0.37099E-08 -8.4306 0.10000E+01 0.0000 82 NaOH,aq 0.95618E-04 -4.0195 0.95618E-04 -4.0195 0.10000E+01 0.0000 84 OH- 0.74070E-02 -2.1304 0.60462E-02 -2.2185 0.81628E+00 -0.0882 89 HPO3-2 0.10563E-14 -14.9762 0.50529E-15 -15.2965 0.47835E+00 -0.3203 91 H2PO3- 0.11831E-18 -18.9270 0.96792E-19 -19.0142 0.81812E+00 -0.0872 92 H3PO4,aq 0.91893E-18 -18.0367 0.91893E-18 -18.0367 0.10000E+01 0.0000 93 H2PO4- 0.30977E-10 -10.5090 0.25373E-10 -10.5956 0.81909E+00 -0.0867 94 PO4-3 0.60041E-09 -9.2215 0.12298E-09 -9.9102 0.20482E+00 -0.6886 98 HP2O7-3 0.54722E-18 -18.2618 0.10555E-18 -18.9765 0.19289E+00 -0.7147 99 P2O7-4 0.46932E-17 -17.3285 0.26398E-18 -18.5784 0.56246E-01 -1.2499 100 H2S,aq 0.17067E-05 -5.7678 0.17067E-05 -5.7678 0.10000E+01 0.0000 101 S2-2 0.13752E-09 -9.8616 0.65784E-10 -10.1819 0.47835E+00 -0.3203 102 S3-2 0.28091E-16 -16.5514 0.13438E-16 -16.8717 0.47835E+00 -0.3203 107 SO3-2 0.23841E-15 -15.6227 0.11611E-15 -15.9351 0.48701E+00 -0.3125 108 HSO3- 0.84884E-18 -18.0712 0.69445E-18 -18.1584 0.81812E+00 -0.0872 109 HSO4- 0.88960E-17 -17.0508 0.73043E-17 -17.1364 0.82108E+00 -0.0856 111 S2O3-2 0.33267E-17 -17.4780 0.15913E-17 -17.7982 0.47835E+00 -0.3203 Charge balance for all species = -.1736E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1158862E-09 -.1874225E-01 -.1884665E+02 0.0000 2 H2O 0.1000000E+01 0.5552511E+02 0.9979495E+06 0.0000 3 Cl- 0.1968437E-02 0.1979792E-02 0.7002453E+02 7.2268 4 SO4-- 0.1654277E-09 -.2001602E-01 -.1918250E+04 9.9393 5 HCO3- 0.3451277E-03 0.2089947E-01 0.1272229E+04 6.4715 6 HS- 0.7064926E-02 0.2708265E-01 0.8935714E+03 7.7819 7 Al+++ 0.2473350E-28 0.4200723E-05 0.1130753E+00 0.7376 8 H4SiO4 0.6973169E-03 0.1137710E-01 0.1090943E+04 -3.1566 9 Ca++ 0.2407473E-06 0.7388581E-06 0.2954233E-01 13.0982 10 Mg++ 0.3805374E-10 0.1476015E-09 0.3580050E-05 9.2945 11 Fe++ 0.1046092E-12 0.2876537E-07 0.1602682E-02 6.7343 12 K+ 0.2048046E-03 0.2055599E-03 0.8018904E+01 6.2450 13 Na+ 0.2600112E-01 0.2845341E-01 0.6526001E+03 8.3476 14 Mn++ 0.3403538E-10 0.2668973E-08 0.1462833E-03 9.2471 15 F- 0.9131080E-06 0.9168199E-06 0.1737679E-01 3.8921 16 HPO4-- 0.3001504E-07 0.3064643E-07 0.2934498E-02 12.1981 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277704E+02 -.9347641E-02 -.8276770E+02 0.0000000E+00 2 H2O -.7050904E+01 0.2769298E+02 -.3474388E+02 0.0000000E+00 3 Cl- 0.9874152E-03 0.9874152E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1392801E+00 -.9982926E-02 0.1492630E+00 0.0000000E+00 5 HCO3- 0.1042355E-01 0.1042355E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1357556E+00 0.1350739E-01 -.1492630E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2095097E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5674292E-02 0.5205823E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.3685032E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.7361578E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1434664E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1025224E-03 0.1061468E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1419105E-01 0.6262186E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1331142E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5769600E-04 0.4572611E-06 0.5723874E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1528482E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1299E-13 Mass of aqueous solution: 0.499922E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1439900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.8 andradite 0.5971 -0.224 303.4 2.482 5.554 78.83 grossular 0.1423 -0.847 64.10 1.807 1.173 17.84 apatite-OH 0.9805E-02 -2.009 4.925 0.692 0.9017E-01 1.565 apatite-F 0.5724E-04 -4.242 0.2887E-01 -1.540 0.5284E-03 0.9018E-02 clinochlore 0.7019 -0.154 390.1 2.591 7.142 148.4 daphnite 0.2027 -0.693 144.6 2.160 2.648 43.83 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9416 -0.026 262.1 2.418 4.798 102.4 stilbite 3.230 0.509 2276. 3.357 41.67 1062. stilpnomelane-Fe 0.2398 -0.620 258.5 2.413 4.733 89.30 tr.625ac.25prg.125 0.1266 -0.898 108.2 2.034 1.981 34.83 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8075E+00 0.8075E+00 1.0000 -0.093 grossular 0.1925E+00 0.1925E+00 1.0000 -0.716 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7613E+00 0.7613E+00 1.0000 -0.118 daphnite 0.2199E+00 0.2199E+00 1.0000 -0.658 chlorite-Mn 0.1881E-01 0.1881E-01 1.0000 -1.726 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.581434 g Volume = 2211.360153 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1439900 moles log = -0.8417 Original solution: 1000.0103000 g Original solution / Rock added: 6945.00 (Water/Rock Ratio), log = 3.8417 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 31.0887 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3444E-01 0.9393 0.1006E+01 0.1071E+01 CO2,gas 0.2099E-06 0.9471 0.6180E-05 0.6525E-05 CH4,gas 0.9651E+00 0.9818 0.2946E+02 0.3000E+02 H2,gas 0.4676E-03 1.0167 0.1478E-01 0.1454E-01 H2S,gas 0.1698E-05 0.8885 0.4692E-04 0.5280E-04 S2,gas 0.1217E-25 1.0000 0.3783E-24 0.3783E-24 CO,gas 0.7832E-12 1.0000 0.2435E-10 0.2435E-10 SO3,gas 0.8809E-47 1.0000 0.2739E-45 0.2739E-45 SO2,gas 0.5067E-26 1.0000 0.1575E-24 0.1575E-24 HF,gas 0.3848E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1600E-17 1.0000 0.4974E-16 0.4974E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 117 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 164 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.57 -6.91 -2.303 0.11795E+05 -5.209 3 CH4,gas 4.54 4.31 -0.23 -0.057 0.39232E+03 1.469 4 H2,gas 8.00 4.47 -3.53 -2.017 0.60262E+04 -1.830 5 H2S,gas -6.23 -12.26 -6.03 -3.014 0.10292E+05 -4.329 6 S2,gas -7.34 -33.46 -26.12 -4.019 0.44601E+05 -24.422 7 CO,gas 3.21 -9.10 -12.31 -3.788 0.21023E+05 -10.614 8 SO3,gas 17.12 -30.14 -47.26 -11.815 0.80698E+05 -45.562 9 SO2,gas 0.83 -25.67 -26.50 -7.067 0.45251E+05 -24.803 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.81 -18.00 -9.001 0.30738E+05 -16.303 12 acmite 7.71 6.53 -1.18 -0.122 0.20078E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.75 -4.71 -0.236 0.80429E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93847E+03 27 annite 20.12 17.72 -2.41 -0.134 0.41109E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28482E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.75982E+04 38 aragonite 0.97 -0.47 -1.44 -0.479 0.24530E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55908E+04 40 calcite 0.81 -0.47 -1.28 -0.427 0.21888E+04 41 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52840E+04 42 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71110E+04 43 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70446E+04 44 carpholite-Fe 6.71 1.90 -4.82 -0.321 0.82241E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28858E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47558E+04 47 chrysotile 23.89 21.57 -2.32 -0.194 0.39649E+04 52 chlorite-Al-free 47.17 43.14 -4.03 -0.168 0.68849E+04 54 chloritoid-Fe 9.17 5.05 -4.12 -0.275 0.70366E+04 55 chloritoid-Mn 11.40 7.57 -3.84 -0.256 0.65494E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13322E+04 64 cristobalite -2.56 -3.16 -0.60 -0.199 0.10175E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36478E+04 69 diamond -3.10 -4.63 -1.52 -0.436 0.26031E+04 72 enstatite 17.26 12.28 -4.99 -0.499 0.85180E+04 74 clinoenstatite 17.17 12.28 -4.89 -0.489 0.83496E+04 76 epidote 24.67 22.70 -1.97 -0.095 0.33621E+04 77 clinozoisite 22.81 18.94 -3.87 -0.176 0.66021E+04 78 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57686E+04 79 fayalite 14.05 10.31 -3.73 -0.533 0.63752E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68191E+04 84 gibbsite 4.08 0.74 -3.34 -0.477 0.57066E+04 85 glaucophane 22.97 20.80 -2.17 -0.059 0.37087E+04 86 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70924E+04 87 graphite -3.55 -4.63 -1.08 -0.309 0.18454E+04 88 greenalite 16.14 13.89 -2.25 -0.187 0.38416E+04 91 hematite 12.57 9.00 -3.57 -0.433 0.60931E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 96 jadeite 4.22 2.77 -1.44 -0.144 0.24637E+04 98 kalsilite 7.58 3.83 -3.76 -0.537 0.64165E+04 99 kaolinite -1.33 -4.84 -3.51 -0.319 0.59851E+04 102 laumontite 2.88 1.95 -0.94 -0.062 0.15986E+04 103 lawsonite 9.62 8.26 -1.36 -0.090 0.23154E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58892E+04 106 lizardite 23.24 21.57 -1.67 -0.139 0.28575E+04 107 magnesite 0.69 -4.27 -4.96 -1.655 0.84765E+04 108 magnetite 20.09 15.73 -4.36 -0.356 0.74369E+04 109 minnesotaite 10.39 7.58 -2.81 -0.165 0.47994E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82149E+04 121 muscovite 2.58 -1.01 -3.59 -0.211 0.61371E+04 122 paragonite 4.24 1.09 -3.15 -0.185 0.53762E+04 123 nepheline 8.34 5.93 -2.41 -0.344 0.41164E+04 129 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83537E+04 135 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36670E+04 137 prehnite 19.37 18.20 -1.17 -0.069 0.19976E+04 138 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91256E+03 139 pumpellyite-Fe 46.27 43.88 -2.39 -0.053 0.40880E+04 140 pumpellyite-Mg 48.99 46.44 -2.56 -0.057 0.43701E+04 143 pyrite -21.25 -22.25 -1.00 -0.236 0.17159E+04 144 pyrrhotite -4.26 -5.52 -1.26 -0.421 0.21570E+04 145 pyrrhotiteFe0.875 -6.02 -6.92 -0.90 -0.332 0.15414E+04 146 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22333E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84940E+04 148 quartz -2.99 -3.16 -0.17 -0.056 0.28484E+03 152 rhodochrosite -0.98 -4.32 -3.34 -1.115 0.57112E+04 153 rhodonite 7.45 6.09 -1.35 -0.271 0.23136E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.83 -4.23 -1.409 0.72155E+04 166 stilpnomelane-Mg 27.44 25.82 -1.62 -0.048 0.27717E+04 172 talc 16.49 15.26 -1.23 -0.073 0.21055E+04 175 tephroite 18.09 15.34 -2.75 -0.393 0.46923E+04 179 tridymite -2.63 -3.16 -0.53 -0.177 0.90482E+03 180 tremolite 47.87 47.42 -0.45 -0.012 0.77084E+03 181 ferroactinolite 38.45 34.62 -3.84 -0.104 0.65494E+04 182 troilite-low -4.41 -5.52 -1.11 -0.371 0.18998E+04 184 vesuvianite 223.47 218.75 -4.72 -0.036 0.80616E+04 188 wairakite 3.95 1.95 -2.00 -0.118 0.34200E+04 189 walstromite 11.51 9.94 -1.57 -0.313 0.26764E+04 190 wollastonite 10.46 9.94 -0.52 -0.104 0.88680E+03 191 pseudo-wollastonite 11.00 9.94 -1.06 -0.212 0.18066E+04 192 zoisite 22.85 18.94 -3.91 -0.178 0.66762E+04 193 akaganeite 7.75 4.50 -3.26 -0.704 0.55592E+04 200 chalcedony -2.80 -3.16 -0.35 -0.118 0.60414E+03 202 montmorillonite-Ca -2.29 -6.17 -3.87 -0.240 0.66159E+04 203 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68795E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73645E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60344E+04 206 nontronite-Ca 3.21 -0.18 -3.40 -0.220 0.57985E+04 207 nontronite-H 2.53 -2.34 -4.88 -0.327 0.83244E+04 208 nontronite-K 3.34 -0.28 -3.62 -0.233 0.61852E+04 209 nontronite-Mg 3.07 -0.81 -3.88 -0.252 0.66312E+04 210 nontronite-Na 3.52 0.41 -3.11 -0.199 0.53061E+04 226 tobermorite 9.82 7.75 -2.07 -0.564 0.35325E+04 232 alabandite -0.98 -3.01 -2.03 -0.678 0.34711E+04 235 boehmite 4.41 0.74 -3.67 -0.612 0.62647E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52546E+04 243 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18183E+04 245 an20ab80 2.02 1.34 -0.67 -0.052 0.11488E+04 246 an25ab75 2.65 1.78 -0.87 -0.067 0.14830E+04 247 an30ab70 3.28 2.21 -1.07 -0.082 0.18267E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1439900 MOLES New total amount of reactant added: 0.1479900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1479900 Water: Moles liquid = 0.2768E+02 kg liquid = 0.4987E+00 Moles total = -.7048E+01 kg total = -.1270E+00 Activity = 0.9996 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2700156E-01 Chg. balance for total moles = -.8663E-10 Max. difference allowed = 0.1011E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11702E-09 -9.9317 0.96397E-10 -10.0159 0.82377E+00 -0.0842 2 H2O 0.99963E+00 -0.0002 0.99963E+00 -0.0002 3 Cl- 0.20155E-02 -2.6956 0.16478E-02 -2.7831 0.81754E+00 -0.0875 4 SO4-- 0.17822E-09 -9.7490 0.85249E-10 -10.0693 0.47833E+00 -0.3203 5 HCO3- 0.37073E-03 -3.4309 0.30365E-03 -3.5176 0.81905E+00 -0.0867 6 HS- 0.72602E-02 -2.1391 0.59366E-02 -2.2265 0.81770E+00 -0.0874 7 Al+++ 0.25526E-28 -28.5930 0.48866E-29 -29.3110 0.19143E+00 -0.7180 8 H4SiO4 0.69809E-03 -3.1561 0.69809E-03 -3.1561 0.10000E+01 0.0000 9 Ca++ 0.24484E-06 -6.6111 0.11603E-06 -6.9354 0.47388E+00 -0.3243 10 Mg++ 0.38875E-10 -10.4103 0.18316E-10 -10.7372 0.47115E+00 -0.3268 11 Fe++ 0.10673E-12 -12.9717 0.50356E-13 -13.2979 0.47180E+00 -0.3262 12 K+ 0.20650E-03 -3.6851 0.16919E-03 -3.7716 0.81929E+00 -0.0866 13 Na+ 0.26217E-01 -1.5814 0.21429E-01 -1.6690 0.81734E+00 -0.0876 14 Mn++ 0.34743E-10 -10.4591 0.16409E-10 -10.7849 0.47230E+00 -0.3258 15 F- 0.90550E-06 -6.0431 0.73838E-06 -6.1317 0.81544E+00 -0.0886 16 HPO4-- 0.29756E-07 -7.5264 0.14235E-07 -7.8466 0.47841E+00 -0.3202 18 HSiO3- 0.82742E-02 -2.0823 0.67645E-02 -2.1698 0.81754E+00 -0.0875 19 Ca(HSiO3)+ 0.21811E-07 -7.6613 0.17875E-07 -7.7478 0.81951E+00 -0.0864 20 Mg(HSiO3)+ 0.42850E-11 -11.3680 0.35116E-11 -11.4545 0.81951E+00 -0.0864 21 NaHSiO3,aq 0.23444E-02 -2.6300 0.23444E-02 -2.6300 0.10000E+01 0.0000 22 AlO+ 0.87265E-16 -16.0592 0.71515E-16 -16.1456 0.81951E+00 -0.0864 24 HAlO2,aq 0.14769E-09 -9.8307 0.14769E-09 -9.8307 0.10000E+01 0.0000 25 AlO2- 0.41577E-05 -5.3811 0.33914E-05 -5.4696 0.81569E+00 -0.0885 26 CH4,aq 0.20533E-01 -1.6876 0.20533E-01 -1.6876 0.10000E+01 0.0000 27 C2H6,aq 0.64901E-08 -8.1877 0.64901E-08 -8.1877 0.10000E+01 0.0000 28 C3H8,aq 0.47362E-13 -13.3246 0.47362E-13 -13.3246 0.10000E+01 0.0000 29 C4H10,aq 0.33954E-18 -18.4691 0.33954E-18 -18.4691 0.10000E+01 0.0000 30 ethanol,aq 0.24836E-15 -15.6049 0.24836E-15 -15.6049 0.10000E+01 0.0000 31 CO,aq 0.17461E-13 -13.7579 0.17461E-13 -13.7579 0.10000E+01 0.0000 32 CO2,aq 0.62567E-07 -7.2037 0.62567E-07 -7.2037 0.10000E+01 0.0000 33 CO3-2 0.57675E-03 -3.2390 0.27514E-03 -3.5605 0.47705E+00 -0.3214 34 CaCO3,aq 0.40028E-06 -6.3976 0.40028E-06 -6.3976 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.10974E-08 -8.9596 0.89932E-09 -9.0461 0.81951E+00 -0.0864 36 CaCl+ 0.37754E-09 -9.4230 0.30940E-09 -9.5095 0.81951E+00 -0.0864 37 CaCl2,aq 0.12112E-12 -12.9168 0.12112E-12 -12.9168 0.10000E+01 0.0000 38 CaF+ 0.15263E-11 -11.8164 0.12508E-11 -11.9028 0.81951E+00 -0.0864 39 CaOH+ 0.10464E-06 -6.9803 0.85751E-07 -7.0668 0.81951E+00 -0.0864 40 CaSO4,aq 0.31409E-14 -14.5029 0.31409E-14 -14.5029 0.10000E+01 0.0000 41 HCl,aq 0.29107E-13 -13.5360 0.29107E-13 -13.5360 0.10000E+01 0.0000 45 HF,aq 0.48726E-12 -12.3122 0.48726E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.14858E-18 -18.8280 0.12147E-18 -18.9155 0.81754E+00 -0.0875 48 FeCl+ 0.16026E-15 -15.7952 0.13134E-15 -15.8816 0.81951E+00 -0.0864 51 FeF+ 0.23185E-17 -17.6348 0.19001E-17 -17.7212 0.81951E+00 -0.0864 53 FeO,aq 0.21054E-09 -9.6767 0.21054E-09 -9.6767 0.10000E+01 0.0000 54 FeOH+ 0.20741E-10 -10.6832 0.16998E-10 -10.7696 0.81951E+00 -0.0864 55 HFeO2- 0.27942E-07 -7.5537 0.22844E-07 -7.6412 0.81754E+00 -0.0875 56 FeO+ 0.14846E-16 -16.8284 0.12166E-16 -16.9148 0.81951E+00 -0.0864 58 FeO2- 0.32757E-09 -9.4847 0.26781E-09 -9.5722 0.81754E+00 -0.0875 59 HFeO2,aq 0.32834E-11 -11.4837 0.32834E-11 -11.4837 0.10000E+01 0.0000 60 H2,aq 0.11105E-04 -4.9545 0.11105E-04 -4.9545 0.10000E+01 0.0000 61 KCl,aq 0.50527E-08 -8.2965 0.50527E-08 -8.2965 0.10000E+01 0.0000 63 KOH,aq 0.74925E-06 -6.1254 0.74925E-06 -6.1254 0.10000E+01 0.0000 64 KSO4- 0.27376E-12 -12.5626 0.22381E-12 -12.6501 0.81754E+00 -0.0875 65 MgCO3,aq 0.15839E-10 -10.8003 0.15839E-10 -10.8003 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.17701E-12 -12.7520 0.14506E-12 -12.8384 0.81951E+00 -0.0864 67 MgCl+ 0.54018E-13 -13.2675 0.44268E-13 -13.3539 0.81951E+00 -0.0864 68 MgF+ 0.89253E-15 -15.0494 0.73144E-15 -15.1358 0.81951E+00 -0.0864 69 MgOH+ 0.91403E-10 -10.0390 0.74906E-10 -10.1255 0.81951E+00 -0.0864 71 MnF+ 0.24902E-15 -15.6038 0.20408E-15 -15.6902 0.81951E+00 -0.0864 72 MnO,aq 0.18281E-08 -8.7380 0.18281E-08 -8.7380 0.10000E+01 0.0000 73 MnOH+ 0.62787E-09 -9.2021 0.51455E-09 -9.2886 0.81951E+00 -0.0864 74 MnO2-2 0.13681E-10 -10.8639 0.65264E-11 -11.1853 0.47705E+00 -0.3214 75 HMnO2- 0.16859E-09 -9.7732 0.13783E-09 -9.8607 0.81754E+00 -0.0875 78 MnCl+ 0.20317E-12 -12.6921 0.16650E-12 -12.7786 0.81951E+00 -0.0864 79 MnSO4,aq 0.40384E-18 -18.3938 0.40384E-18 -18.3938 0.10000E+01 0.0000 80 NaCl,aq 0.11702E-04 -4.9318 0.11702E-04 -4.9318 0.10000E+01 0.0000 81 NaF,aq 0.37043E-08 -8.4313 0.37043E-08 -8.4313 0.10000E+01 0.0000 82 NaOH,aq 0.95474E-04 -4.0201 0.95474E-04 -4.0201 0.10000E+01 0.0000 84 OH- 0.73452E-02 -2.1340 0.59915E-02 -2.2225 0.81569E+00 -0.0885 89 HPO3-2 0.10331E-14 -14.9859 0.49283E-15 -15.3073 0.47705E+00 -0.3214 91 H2PO3- 0.11653E-18 -18.9336 0.95266E-19 -19.0211 0.81754E+00 -0.0875 92 H3PO4,aq 0.92517E-18 -18.0338 0.92517E-18 -18.0338 0.10000E+01 0.0000 93 H2PO4- 0.30927E-10 -10.5097 0.25314E-10 -10.5966 0.81852E+00 -0.0870 94 PO4-3 0.59165E-09 -9.2279 0.12049E-09 -9.9191 0.20364E+00 -0.6911 98 HP2O7-3 0.54313E-18 -18.2651 0.10412E-18 -18.9825 0.19170E+00 -0.7174 99 P2O7-4 0.46372E-17 -17.3337 0.25804E-18 -18.5883 0.55644E-01 -1.2546 100 H2S,aq 0.17687E-05 -5.7524 0.17687E-05 -5.7524 0.10000E+01 0.0000 101 S2-2 0.14741E-09 -9.8315 0.70322E-10 -10.1529 0.47705E+00 -0.3214 102 S3-2 0.31631E-16 -16.4999 0.15089E-16 -16.8213 0.47705E+00 -0.3214 107 SO3-2 0.25336E-15 -15.5963 0.12307E-15 -15.9099 0.48574E+00 -0.3136 108 HSO3- 0.90857E-18 -18.0416 0.74279E-18 -18.1291 0.81754E+00 -0.0875 109 HSO4- 0.96518E-17 -17.0154 0.79196E-17 -17.1013 0.82053E+00 -0.0859 111 S2O3-2 0.37141E-17 -17.4301 0.17718E-17 -17.7516 0.47705E+00 -0.3214 Charge balance for all species = -.1737E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1170185E-09 -.1865507E-01 -.1875862E+02 0.0000 2 H2O 0.1000000E+01 0.5552563E+02 0.9979394E+06 0.0000 3 Cl- 0.2015520E-02 0.2027227E-02 0.7170091E+02 7.2328 4 SO4-- 0.1782242E-09 -.2053540E-01 -.1967986E+04 9.9626 5 HCO3- 0.3707292E-03 0.2148056E-01 0.1307577E+04 6.4983 6 HS- 0.7260171E-02 0.2779734E-01 0.9171341E+03 7.7895 7 Al+++ 0.2552638E-28 0.4157839E-05 0.1119188E+00 0.7368 8 H4SiO4 0.6980940E-03 0.1131678E-01 0.1085138E+04 -3.1561 9 Ca++ 0.2448438E-06 0.7730537E-06 0.3090900E-01 13.0964 10 Mg++ 0.3887538E-10 0.1506349E-09 0.3653553E-05 9.2947 11 Fe++ 0.1067309E-12 0.2850418E-07 0.1588099E-02 6.7339 12 K+ 0.2065047E-03 0.2072591E-03 0.8085031E+01 6.2443 13 Na+ 0.2621741E-01 0.2866903E-01 0.6575329E+03 8.3469 14 Mn++ 0.3474315E-10 0.2673150E-08 0.1465094E-03 9.2470 15 F- 0.9055002E-06 0.9092065E-06 0.1723216E-01 3.8842 16 HPO4-- 0.2975570E-07 0.3037829E-07 0.2908765E-02 12.1852 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277661E+02 -.9303624E-02 -.8276731E+02 0.0000000E+00 2 H2O -.7047629E+01 0.2769164E+02 -.3473927E+02 0.0000000E+00 3 Cl- 0.1011015E-02 0.1011015E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1392992E+00 -.1024138E-01 0.1495405E+00 0.0000000E+00 5 HCO3- 0.1071275E-01 0.1071275E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1356775E+00 0.1386304E-01 -.1495405E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2073590E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5643883E-02 0.5205826E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.3855359E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.7512435E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1421555E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1033639E-03 0.1061468E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1429777E-01 0.6262079E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1333149E-08 0.8669296E-01 0.0000000E+00 15 F- 0.5929600E-04 0.4534378E-06 0.5884256E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1515020E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.4316E-14 Mass of aqueous solution: 0.499903E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1479900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.8 andradite 0.5982 -0.223 304.0 2.483 5.565 78.97 grossular 0.1415 -0.849 63.72 1.804 1.166 17.73 apatite-OH 0.9804E-02 -2.009 4.925 0.692 0.9015E-01 1.565 apatite-F 0.5884E-04 -4.230 0.2967E-01 -1.528 0.5432E-03 0.9271E-02 clinochlore 0.7024 -0.153 390.4 2.592 7.147 148.5 daphnite 0.2026 -0.693 144.6 2.160 2.646 43.81 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9416 -0.026 262.1 2.418 4.798 102.4 stilbite 3.231 0.509 2277. 3.357 41.68 1062. stilpnomelane-Fe 0.2397 -0.620 258.4 2.412 4.730 89.24 tr.625ac.25prg.125 0.1259 -0.900 107.6 2.032 1.970 34.63 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8087E+00 0.8087E+00 1.0000 -0.092 grossular 0.1913E+00 0.1913E+00 1.0000 -0.718 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7615E+00 0.7615E+00 1.0000 -0.118 daphnite 0.2197E+00 0.2197E+00 1.0000 -0.658 chlorite-Mn 0.1880E-01 0.1880E-01 1.0000 -1.726 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.682855 g Volume = 2211.459030 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1479900 moles log = -0.8298 Original solution: 1000.0103000 g Original solution / Rock added: 6757.28 (Water/Rock Ratio), log = 3.8298 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 31.8826 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3361E-01 0.9384 0.1006E+01 0.1072E+01 CO2,gas 0.2220E-06 0.9459 0.6694E-05 0.7077E-05 CH4,gas 0.9659E+00 0.9814 0.3022E+02 0.3080E+02 H2,gas 0.4496E-03 1.0171 0.1458E-01 0.1433E-01 H2S,gas 0.1721E-05 0.8859 0.4862E-04 0.5488E-04 S2,gas 0.1309E-25 1.0000 0.4174E-24 0.4174E-24 CO,gas 0.8161E-12 1.0000 0.2602E-10 0.2602E-10 SO3,gas 0.9398E-47 1.0000 0.2996E-45 0.2996E-45 SO2,gas 0.5333E-26 1.0000 0.1700E-24 0.1700E-24 HF,gas 0.3752E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1611E-17 1.0000 0.5136E-16 0.5136E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 117 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 164 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.53 -6.87 -2.291 0.11736E+05 -5.174 3 CH4,gas 4.54 4.33 -0.22 -0.055 0.37332E+03 1.480 4 H2,gas 8.00 4.46 -3.54 -2.020 0.60363E+04 -1.836 5 H2S,gas -6.23 -12.24 -6.01 -3.006 0.10266E+05 -4.313 6 S2,gas -7.34 -33.41 -26.08 -4.012 0.44528E+05 -24.379 7 CO,gas 3.21 -9.07 -12.28 -3.780 0.20974E+05 -10.585 8 SO3,gas 17.12 -30.10 -47.22 -11.806 0.80631E+05 -45.523 9 SO2,gas 0.83 -25.64 -26.47 -7.058 0.45194E+05 -24.770 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.80 -17.99 -8.994 0.30715E+05 -16.289 12 acmite 7.71 6.54 -1.17 -0.122 0.20028E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.75 -4.71 -0.236 0.80440E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.93932E+03 27 annite 20.12 17.71 -2.41 -0.134 0.41129E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28474E+04 30 anorthite 12.71 8.26 -4.45 -0.342 0.76024E+04 38 aragonite 0.97 -0.44 -1.40 -0.468 0.23967E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55906E+04 40 calcite 0.81 -0.44 -1.25 -0.416 0.21325E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52857E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71127E+04 43 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70454E+04 44 carpholite-Fe 6.71 1.90 -4.82 -0.321 0.82259E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28847E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47556E+04 47 chrysotile 23.89 21.57 -2.32 -0.193 0.39623E+04 52 chlorite-Al-free 47.17 43.14 -4.03 -0.168 0.68798E+04 54 chloritoid-Fe 9.17 5.05 -4.12 -0.275 0.70393E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65517E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13313E+04 64 cristobalite -2.56 -3.16 -0.60 -0.198 0.10167E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36492E+04 69 diamond -3.10 -4.60 -1.50 -0.429 0.25640E+04 72 enstatite 17.26 12.28 -4.99 -0.499 0.85157E+04 74 clinoenstatite 17.17 12.28 -4.89 -0.489 0.83473E+04 76 epidote 24.67 22.70 -1.97 -0.096 0.33640E+04 77 clinozoisite 22.81 18.93 -3.87 -0.176 0.66098E+04 78 epidote-Fe 29.84 26.46 -3.38 -0.175 0.57648E+04 79 fayalite 14.05 10.31 -3.73 -0.533 0.63756E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68187E+04 84 gibbsite 4.08 0.74 -3.34 -0.478 0.57080E+04 85 glaucophane 22.97 20.80 -2.17 -0.059 0.37062E+04 86 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70928E+04 87 graphite -3.55 -4.60 -1.06 -0.302 0.18062E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38419E+04 91 hematite 12.57 9.00 -3.56 -0.432 0.60843E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28936E+04 96 jadeite 4.22 2.77 -1.44 -0.144 0.24645E+04 98 kalsilite 7.58 3.83 -3.76 -0.537 0.64182E+04 99 kaolinite -1.33 -4.84 -3.51 -0.319 0.59863E+04 102 laumontite 2.88 1.95 -0.94 -0.063 0.16011E+04 103 lawsonite 9.62 8.26 -1.36 -0.091 0.23196E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58901E+04 106 lizardite 23.24 21.57 -1.67 -0.139 0.28550E+04 107 magnesite 0.69 -4.24 -4.93 -1.643 0.84169E+04 108 magnetite 20.09 15.74 -4.35 -0.355 0.74289E+04 109 minnesotaite 10.39 7.58 -2.81 -0.165 0.47980E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82152E+04 121 muscovite 2.58 -1.01 -3.60 -0.212 0.61400E+04 122 paragonite 4.24 1.09 -3.15 -0.185 0.53791E+04 123 nepheline 8.34 5.93 -2.41 -0.345 0.41181E+04 129 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83544E+04 135 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36662E+04 137 prehnite 19.37 18.20 -1.17 -0.069 0.20039E+04 138 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91311E+03 139 pumpellyite-Fe 46.27 43.87 -2.40 -0.053 0.41028E+04 140 pumpellyite-Mg 48.99 46.43 -2.57 -0.057 0.43839E+04 143 pyrite -21.25 -22.22 -0.97 -0.228 0.16536E+04 144 pyrrhotite -4.26 -5.51 -1.25 -0.416 0.21312E+04 145 pyrrhotiteFe0.875 -6.02 -6.90 -0.89 -0.326 0.15143E+04 146 pyroxmangite 7.40 6.09 -1.31 -0.262 0.22328E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84934E+04 148 quartz -2.99 -3.16 -0.17 -0.055 0.28400E+03 152 rhodochrosite -0.98 -4.29 -3.31 -1.103 0.56522E+04 153 rhodonite 7.45 6.09 -1.35 -0.271 0.23130E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.80 -4.19 -1.397 0.71569E+04 166 stilpnomelane-Mg 27.44 25.82 -1.62 -0.048 0.27670E+04 172 talc 16.49 15.26 -1.23 -0.072 0.21013E+04 175 tephroite 18.09 15.34 -2.75 -0.393 0.46921E+04 179 tridymite -2.63 -3.16 -0.53 -0.176 0.90398E+03 180 tremolite 47.87 47.42 -0.45 -0.012 0.76875E+03 181 ferroactinolite 38.45 34.62 -3.84 -0.104 0.65520E+04 182 troilite-low -4.41 -5.51 -1.10 -0.366 0.18740E+04 184 vesuvianite 223.47 218.72 -4.75 -0.036 0.81187E+04 188 wairakite 3.95 1.95 -2.00 -0.118 0.34225E+04 189 walstromite 11.51 9.94 -1.57 -0.314 0.26785E+04 190 wollastonite 10.46 9.94 -0.52 -0.104 0.88897E+03 191 pseudo-wollastonite 11.00 9.94 -1.06 -0.212 0.18088E+04 192 zoisite 22.85 18.93 -3.91 -0.178 0.66839E+04 193 akaganeite 7.75 4.50 -3.25 -0.703 0.55548E+04 200 chalcedony -2.80 -3.16 -0.35 -0.118 0.60330E+03 202 montmorillonite-Ca -2.29 -6.17 -3.87 -0.240 0.66153E+04 203 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68788E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73634E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60337E+04 206 nontronite-Ca 3.21 -0.18 -3.39 -0.220 0.57876E+04 207 nontronite-H 2.53 -2.34 -4.87 -0.326 0.83131E+04 208 nontronite-K 3.34 -0.28 -3.62 -0.232 0.61742E+04 209 nontronite-Mg 3.07 -0.80 -3.88 -0.252 0.66198E+04 210 nontronite-Na 3.52 0.42 -3.10 -0.199 0.52951E+04 226 tobermorite 9.82 7.75 -2.07 -0.565 0.35342E+04 232 alabandite -0.98 -3.00 -2.02 -0.673 0.34449E+04 235 boehmite 4.41 0.74 -3.67 -0.612 0.62661E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52553E+04 243 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18175E+04 245 an20ab80 2.02 1.34 -0.67 -0.052 0.11496E+04 246 an25ab75 2.65 1.78 -0.87 -0.067 0.14840E+04 247 an30ab70 3.28 2.21 -1.07 -0.082 0.18280E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1479900 MOLES New total amount of reactant added: 0.1519900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1519900 Water: Moles liquid = 0.2768E+02 kg liquid = 0.4987E+00 Moles total = -.7044E+01 kg total = -.1269E+00 Activity = 0.9996 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2726206E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.1035E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11817E-09 -9.9275 0.97285E-10 -10.0120 0.82323E+00 -0.0845 2 H2O 0.99962E+00 -0.0002 0.99962E+00 -0.0002 3 Cl- 0.20626E-02 -2.6856 0.16851E-02 -2.7734 0.81696E+00 -0.0878 4 SO4-- 0.19184E-09 -9.7171 0.91508E-10 -10.0385 0.47701E+00 -0.3215 5 HCO3- 0.39783E-03 -3.4003 0.32562E-03 -3.4873 0.81848E+00 -0.0870 6 HS- 0.74554E-02 -2.1275 0.60919E-02 -2.2152 0.81711E+00 -0.0877 7 Al+++ 0.26355E-28 -28.5791 0.50134E-29 -29.2999 0.19023E+00 -0.7207 8 H4SiO4 0.69887E-03 -3.1556 0.69887E-03 -3.1556 0.10000E+01 0.0000 9 Ca++ 0.24907E-06 -6.6037 0.11770E-06 -6.9292 0.47255E+00 -0.3256 10 Mg++ 0.39724E-10 -10.4009 0.18663E-10 -10.7290 0.46980E+00 -0.3281 11 Fe++ 0.10892E-12 -12.9629 0.51243E-13 -13.2904 0.47046E+00 -0.3275 12 K+ 0.20824E-03 -3.6814 0.17049E-03 -3.7683 0.81872E+00 -0.0869 13 Na+ 0.26438E-01 -1.5778 0.21594E-01 -1.6657 0.81676E+00 -0.0879 14 Mn++ 0.35474E-10 -10.4501 0.16707E-10 -10.7771 0.47095E+00 -0.3270 15 F- 0.89788E-06 -6.0468 0.73163E-06 -6.1357 0.81484E+00 -0.0889 16 HPO4-- 0.29494E-07 -7.5303 0.14072E-07 -7.8517 0.47709E+00 -0.3214 18 HSiO3- 0.82138E-02 -2.0855 0.67103E-02 -2.1733 0.81696E+00 -0.0878 19 Ca(HSiO3)+ 0.21963E-07 -7.6583 0.17986E-07 -7.7451 0.81894E+00 -0.0867 20 Mg(HSiO3)+ 0.43341E-11 -11.3631 0.35494E-11 -11.4498 0.81894E+00 -0.0867 21 NaHSiO3,aq 0.23436E-02 -2.6301 0.23436E-02 -2.6301 0.10000E+01 0.0000 22 AlO+ 0.87964E-16 -16.0557 0.72037E-16 -16.1424 0.81894E+00 -0.0867 24 HAlO2,aq 0.14741E-09 -9.8315 0.14741E-09 -9.8315 0.10000E+01 0.0000 25 AlO2- 0.41149E-05 -5.3856 0.33541E-05 -5.4744 0.81510E+00 -0.0888 26 CH4,aq 0.21049E-01 -1.6768 0.21049E-01 -1.6768 0.10000E+01 0.0000 27 C2H6,aq 0.69137E-08 -8.1603 0.69137E-08 -8.1603 0.10000E+01 0.0000 28 C3H8,aq 0.52428E-13 -13.2804 0.52428E-13 -13.2804 0.10000E+01 0.0000 29 C4H10,aq 0.39056E-18 -18.4083 0.39056E-18 -18.4083 0.10000E+01 0.0000 30 ethanol,aq 0.26818E-15 -15.5716 0.26818E-15 -15.5716 0.10000E+01 0.0000 31 CO,aq 0.18643E-13 -13.7295 0.18643E-13 -13.7295 0.10000E+01 0.0000 32 CO2,aq 0.67714E-07 -7.1693 0.67714E-07 -7.1693 0.10000E+01 0.0000 33 CO3-2 0.61454E-03 -3.2115 0.29235E-03 -3.5341 0.47573E+00 -0.3226 34 CaCO3,aq 0.43145E-06 -6.3651 0.43145E-06 -6.3651 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.11946E-08 -8.9228 0.97827E-09 -9.0095 0.81894E+00 -0.0867 36 CaCl+ 0.39192E-09 -9.4068 0.32096E-09 -9.4936 0.81894E+00 -0.0867 37 CaCl2,aq 0.12849E-12 -12.8911 0.12849E-12 -12.8911 0.10000E+01 0.0000 38 CaF+ 0.15352E-11 -11.8138 0.12572E-11 -11.9006 0.81894E+00 -0.0867 39 CaOH+ 0.10525E-06 -6.9778 0.86190E-07 -7.0645 0.81894E+00 -0.0867 40 CaSO4,aq 0.34201E-14 -14.4660 0.34201E-14 -14.4660 0.10000E+01 0.0000 41 HCl,aq 0.30040E-13 -13.5223 0.30040E-13 -13.5223 0.10000E+01 0.0000 45 HF,aq 0.48725E-12 -12.3122 0.48725E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.14733E-18 -18.8317 0.12036E-18 -18.9195 0.81696E+00 -0.0878 48 FeCl+ 0.16689E-15 -15.7776 0.13667E-15 -15.8643 0.81894E+00 -0.0867 51 FeF+ 0.23394E-17 -17.6309 0.19158E-17 -17.7176 0.81894E+00 -0.0867 53 FeO,aq 0.21035E-09 -9.6771 0.21035E-09 -9.6771 0.10000E+01 0.0000 54 FeOH+ 0.20928E-10 -10.6793 0.17139E-10 -10.7660 0.81894E+00 -0.0867 55 HFeO2- 0.27682E-07 -7.5578 0.22615E-07 -7.6456 0.81696E+00 -0.0878 56 FeO+ 0.15082E-16 -16.8216 0.12351E-16 -16.9083 0.81894E+00 -0.0867 58 FeO2- 0.32673E-09 -9.4858 0.26693E-09 -9.5736 0.81696E+00 -0.0878 59 HFeO2,aq 0.33027E-11 -11.4811 0.33027E-11 -11.4811 0.10000E+01 0.0000 60 H2,aq 0.10955E-04 -4.9604 0.10955E-04 -4.9604 0.10000E+01 0.0000 61 KCl,aq 0.52069E-08 -8.2834 0.52069E-08 -8.2834 0.10000E+01 0.0000 63 KOH,aq 0.74813E-06 -6.1260 0.74813E-06 -6.1260 0.10000E+01 0.0000 64 KSO4- 0.29634E-12 -12.5282 0.24209E-12 -12.6160 0.81696E+00 -0.0878 65 MgCO3,aq 0.17148E-10 -10.7658 0.17148E-10 -10.7658 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.19355E-12 -12.7132 0.15850E-12 -12.8000 0.81894E+00 -0.0867 67 MgCl+ 0.56324E-13 -13.2493 0.46126E-13 -13.3361 0.81894E+00 -0.0867 68 MgF+ 0.90173E-15 -15.0449 0.73846E-15 -15.1317 0.81894E+00 -0.0867 69 MgOH+ 0.92345E-10 -10.0346 0.75625E-10 -10.1213 0.81894E+00 -0.0867 71 MnF+ 0.25140E-15 -15.5996 0.20588E-15 -15.6864 0.81894E+00 -0.0867 72 MnO,aq 0.18274E-08 -8.7382 0.18274E-08 -8.7382 0.10000E+01 0.0000 73 MnOH+ 0.63386E-09 -9.1980 0.51909E-09 -9.2848 0.81894E+00 -0.0867 74 MnO2-2 0.13464E-10 -10.8708 0.64053E-11 -11.1935 0.47573E+00 -0.3226 75 HMnO2- 0.16711E-09 -9.7770 0.13652E-09 -9.8648 0.81696E+00 -0.0878 78 MnCl+ 0.21168E-12 -12.6743 0.17336E-12 -12.7611 0.81894E+00 -0.0867 79 MnSO4,aq 0.44135E-18 -18.3552 0.44135E-18 -18.3552 0.10000E+01 0.0000 80 NaCl,aq 0.12059E-04 -4.9187 0.12059E-04 -4.9187 0.10000E+01 0.0000 81 NaF,aq 0.36988E-08 -8.4319 0.36988E-08 -8.4319 0.10000E+01 0.0000 82 NaOH,aq 0.95330E-04 -4.0208 0.95330E-04 -4.0208 0.10000E+01 0.0000 84 OH- 0.72834E-02 -2.1377 0.59367E-02 -2.2265 0.81510E+00 -0.0888 89 HPO3-2 0.10102E-14 -14.9956 0.48060E-15 -15.3182 0.47573E+00 -0.3226 91 H2PO3- 0.11476E-18 -18.9402 0.93758E-19 -19.0280 0.81696E+00 -0.0878 92 H3PO4,aq 0.93145E-18 -18.0308 0.93145E-18 -18.0308 0.10000E+01 0.0000 93 H2PO4- 0.30874E-10 -10.5104 0.25254E-10 -10.5977 0.81794E+00 -0.0873 94 PO4-3 0.58292E-09 -9.2344 0.11801E-09 -9.9281 0.20245E+00 -0.6937 98 HP2O7-3 0.53898E-18 -18.2684 0.10267E-18 -18.9885 0.19050E+00 -0.7201 99 P2O7-4 0.45810E-17 -17.3390 0.25213E-18 -18.5984 0.55038E-01 -1.2593 100 H2S,aq 0.18317E-05 -5.7372 0.18317E-05 -5.7372 0.10000E+01 0.0000 101 S2-2 0.15778E-09 -9.8019 0.75060E-10 -10.1246 0.47573E+00 -0.3226 102 S3-2 0.35540E-16 -16.4493 0.16907E-16 -16.7719 0.47573E+00 -0.3226 107 SO3-2 0.26901E-15 -15.5702 0.13033E-15 -15.8850 0.48446E+00 -0.3147 108 HSO3- 0.97171E-18 -18.0125 0.79385E-18 -18.1003 0.81696E+00 -0.0878 109 HSO4- 0.10463E-16 -16.9803 0.85794E-17 -17.0665 0.81996E+00 -0.0862 111 S2O3-2 0.41403E-17 -17.3830 0.19697E-17 -17.7056 0.47573E+00 -0.3226 Charge balance for all species = -.1737E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1181744E-09 -.1856933E-01 -.1867203E+02 0.0000 2 H2O 0.1000000E+01 0.5552614E+02 0.9979290E+06 0.0000 3 Cl- 0.2062603E-02 0.2074667E-02 0.7337735E+02 7.2386 4 SO4-- 0.1918378E-09 -.2105157E-01 -.2017414E+04 9.9854 5 HCO3- 0.3978332E-03 0.2206171E-01 0.1342926E+04 6.5247 6 HS- 0.7455432E-02 0.2850883E-01 0.9405904E+03 7.7967 7 Al+++ 0.2635521E-28 0.4115058E-05 0.1107650E+00 0.7360 8 H4SiO4 0.6988717E-03 0.1125622E-01 0.1079310E+04 -3.1556 9 Ca++ 0.2490705E-06 0.8093180E-06 0.3235831E-01 13.0947 10 Mg++ 0.3972435E-10 0.1538012E-09 0.3730277E-05 9.2949 11 Fe++ 0.1089221E-12 0.2824311E-07 0.1573523E-02 6.7335 12 K+ 0.2082415E-03 0.2089948E-03 0.8152583E+01 6.2437 13 Na+ 0.2643837E-01 0.2888934E-01 0.6625725E+03 8.3463 14 Mn++ 0.3547434E-10 0.2677485E-08 0.1467441E-03 9.2468 15 F- 0.8978824E-06 0.9015832E-06 0.1708734E-01 3.8762 16 HPO4-- 0.2949439E-07 0.3010818E-07 0.2882846E-02 12.1723 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277618E+02 -.9260335E-02 -.8276692E+02 0.0000000E+00 2 H2O -.7044355E+01 0.2769032E+02 -.3473467E+02 0.0000000E+00 3 Cl- 0.1034615E-02 0.1034615E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1393183E+00 -.1049820E-01 0.1498165E+00 0.0000000E+00 5 HCO3- 0.1100195E-01 0.1100195E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1355994E+00 0.1421706E-01 -.1498165E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2052138E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5613361E-02 0.5205829E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.4035986E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.7669909E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1408455E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1042236E-03 0.1061467E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1440682E-01 0.6261970E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1335234E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6089600E-04 0.4496103E-06 0.6044639E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1501464E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.6072E-14 Mass of aqueous solution: 0.499885E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1519900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.8 andradite 0.5993 -0.222 304.5 2.484 5.575 79.12 grossular 0.1406 -0.852 63.34 1.802 1.160 17.62 apatite-OH 0.9802E-02 -2.009 4.924 0.692 0.9013E-01 1.565 apatite-F 0.6045E-04 -4.219 0.3048E-01 -1.516 0.5580E-03 0.9523E-02 clinochlore 0.7029 -0.153 390.7 2.592 7.152 148.6 daphnite 0.2025 -0.694 144.5 2.160 2.645 43.78 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9417 -0.026 262.1 2.418 4.798 102.4 stilbite 3.231 0.509 2277. 3.357 41.69 1062. stilpnomelane-Fe 0.2395 -0.621 258.2 2.412 4.726 89.19 tr.625ac.25prg.125 0.1251 -0.903 107.0 2.029 1.958 34.43 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8099E+00 0.8099E+00 1.0000 -0.092 grossular 0.1901E+00 0.1901E+00 1.0000 -0.721 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7618E+00 0.7618E+00 1.0000 -0.118 daphnite 0.2195E+00 0.2195E+00 1.0000 -0.659 chlorite-Mn 0.1879E-01 0.1879E-01 1.0000 -1.726 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.783833 g Volume = 2211.557489 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1519900 moles log = -0.8182 Original solution: 1000.0103000 g Original solution / Rock added: 6579.45 (Water/Rock Ratio), log = 3.8182 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 32.6723 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3283E-01 0.9374 0.1006E+01 0.1073E+01 CO2,gas 0.2347E-06 0.9448 0.7245E-05 0.7668E-05 CH4,gas 0.9667E+00 0.9809 0.3098E+02 0.3159E+02 H2,gas 0.4326E-03 1.0176 0.1438E-01 0.1413E-01 H2S,gas 0.1745E-05 0.8834 0.5035E-04 0.5700E-04 S2,gas 0.1408E-25 1.0000 0.4600E-24 0.4600E-24 CO,gas 0.8503E-12 1.0000 0.2778E-10 0.2778E-10 SO3,gas 0.1003E-46 1.0000 0.3276E-45 0.3276E-45 SO2,gas 0.5613E-26 1.0000 0.1834E-24 0.1834E-24 HF,gas 0.3662E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1622E-17 1.0000 0.5301E-16 0.5301E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 117 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 164 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.50 -6.84 -2.280 0.11677E+05 -5.140 3 CH4,gas 4.54 4.34 -0.21 -0.052 0.35491E+03 1.491 4 H2,gas 8.00 4.46 -3.54 -2.023 0.60464E+04 -1.842 5 H2S,gas -6.23 -12.23 -6.00 -2.998 0.10240E+05 -4.298 6 S2,gas -7.34 -33.37 -26.04 -4.006 0.44456E+05 -24.337 7 CO,gas 3.21 -9.04 -12.26 -3.771 0.20925E+05 -10.556 8 SO3,gas 17.12 -30.06 -47.18 -11.796 0.80565E+05 -45.485 9 SO2,gas 0.83 -25.60 -26.44 -7.049 0.45138E+05 -24.737 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.79 -17.97 -8.987 0.30691E+05 -16.276 12 acmite 7.71 6.54 -1.17 -0.122 0.19979E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.75 -4.71 -0.236 0.80452E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94017E+03 27 annite 20.12 17.71 -2.41 -0.134 0.41149E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28465E+04 30 anorthite 12.71 8.26 -4.45 -0.343 0.76065E+04 38 aragonite 0.97 -0.40 -1.37 -0.457 0.23411E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55903E+04 40 calcite 0.81 -0.40 -1.22 -0.405 0.20769E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.442 0.52874E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71144E+04 43 carpholite-Mg 8.58 4.46 -4.13 -0.275 0.70463E+04 44 carpholite-Fe 6.71 1.89 -4.82 -0.321 0.82277E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28836E+04 46 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47554E+04 47 chrysotile 23.89 21.57 -2.32 -0.193 0.39598E+04 52 chlorite-Al-free 47.17 43.15 -4.03 -0.168 0.68748E+04 54 chloritoid-Fe 9.17 5.05 -4.12 -0.275 0.70419E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65539E+04 57 coesite -2.38 -3.16 -0.78 -0.260 0.13305E+04 64 cristobalite -2.56 -3.16 -0.59 -0.198 0.10158E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.74 -2.14 -0.356 0.36506E+04 69 diamond -3.10 -4.58 -1.48 -0.423 0.25255E+04 72 enstatite 17.26 12.28 -4.99 -0.499 0.85135E+04 74 clinoenstatite 17.17 12.28 -4.89 -0.489 0.83451E+04 76 epidote 24.67 22.70 -1.97 -0.096 0.33660E+04 77 clinozoisite 22.81 18.93 -3.88 -0.176 0.66176E+04 78 epidote-Fe 29.84 26.47 -3.37 -0.175 0.57610E+04 79 fayalite 14.05 10.31 -3.73 -0.533 0.63761E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68184E+04 84 gibbsite 4.08 0.74 -3.34 -0.478 0.57095E+04 85 glaucophane 22.97 20.81 -2.17 -0.059 0.37037E+04 86 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70931E+04 87 graphite -3.55 -4.58 -1.04 -0.296 0.17677E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38422E+04 91 hematite 12.57 9.01 -3.56 -0.431 0.60756E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.44 -0.144 0.24654E+04 98 kalsilite 7.58 3.82 -3.76 -0.537 0.64199E+04 99 kaolinite -1.33 -4.84 -3.51 -0.319 0.59874E+04 102 laumontite 2.88 1.94 -0.94 -0.063 0.16036E+04 103 lawsonite 9.62 8.26 -1.36 -0.091 0.23238E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58909E+04 106 lizardite 23.24 21.57 -1.67 -0.139 0.28525E+04 107 magnesite 0.69 -4.20 -4.89 -1.632 0.83580E+04 108 magnetite 20.09 15.74 -4.35 -0.355 0.74208E+04 109 minnesotaite 10.39 7.58 -2.81 -0.165 0.47967E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82155E+04 121 muscovite 2.58 -1.02 -3.60 -0.212 0.61428E+04 122 paragonite 4.24 1.09 -3.15 -0.185 0.53819E+04 123 nepheline 8.34 5.93 -2.41 -0.345 0.41197E+04 129 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83550E+04 135 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36653E+04 137 prehnite 19.37 18.19 -1.18 -0.069 0.20103E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91368E+03 139 pumpellyite-Fe 46.27 43.86 -2.41 -0.054 0.41175E+04 140 pumpellyite-Mg 48.99 46.42 -2.58 -0.057 0.43977E+04 143 pyrite -21.25 -22.18 -0.93 -0.219 0.15923E+04 144 pyrrhotite -4.26 -5.49 -1.23 -0.411 0.21059E+04 145 pyrrhotiteFe0.875 -6.02 -6.89 -0.87 -0.320 0.14877E+04 146 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22322E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84929E+04 148 quartz -2.99 -3.16 -0.17 -0.055 0.28316E+03 152 rhodochrosite -0.98 -4.25 -3.28 -1.092 0.55939E+04 153 rhodonite 7.45 6.09 -1.35 -0.271 0.23125E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.77 -4.16 -1.386 0.70989E+04 166 stilpnomelane-Mg 27.44 25.82 -1.62 -0.048 0.27623E+04 172 talc 16.49 15.26 -1.23 -0.072 0.20971E+04 175 tephroite 18.09 15.34 -2.75 -0.393 0.46918E+04 179 tridymite -2.63 -3.16 -0.53 -0.176 0.90314E+03 180 tremolite 47.87 47.42 -0.45 -0.012 0.76666E+03 181 ferroactinolite 38.45 34.61 -3.84 -0.104 0.65547E+04 182 troilite-low -4.41 -5.49 -1.08 -0.361 0.18487E+04 184 vesuvianite 223.47 218.68 -4.79 -0.037 0.81758E+04 188 wairakite 3.95 1.94 -2.01 -0.118 0.34250E+04 189 walstromite 11.51 9.94 -1.57 -0.314 0.26807E+04 190 wollastonite 10.46 9.94 -0.52 -0.104 0.89115E+03 191 pseudo-wollastonite 11.00 9.94 -1.06 -0.212 0.18110E+04 192 zoisite 22.85 18.93 -3.92 -0.178 0.66916E+04 193 akaganeite 7.75 4.50 -3.25 -0.703 0.55505E+04 200 chalcedony -2.80 -3.16 -0.35 -0.118 0.60246E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66147E+04 203 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68780E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73623E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60329E+04 206 nontronite-Ca 3.21 -0.17 -3.38 -0.219 0.57768E+04 207 nontronite-H 2.53 -2.33 -4.86 -0.326 0.83017E+04 208 nontronite-K 3.34 -0.27 -3.61 -0.232 0.61633E+04 209 nontronite-Mg 3.07 -0.80 -3.87 -0.251 0.66084E+04 210 nontronite-Na 3.52 0.42 -3.09 -0.199 0.52842E+04 226 tobermorite 9.82 7.75 -2.07 -0.565 0.35359E+04 232 alabandite -0.98 -2.98 -2.00 -0.668 0.34193E+04 235 boehmite 4.41 0.74 -3.67 -0.612 0.62675E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52559E+04 243 silica-amorphous -2.09 -3.16 -1.06 -0.355 0.18166E+04 245 an20ab80 2.02 1.34 -0.67 -0.052 0.11505E+04 246 an25ab75 2.65 1.78 -0.87 -0.067 0.14850E+04 247 an30ab70 3.28 2.21 -1.07 -0.082 0.18292E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1519900 MOLES New total amount of reactant added: 0.1559900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1559900 Water: Moles liquid = 0.2768E+02 kg liquid = 0.4987E+00 Moles total = -.7041E+01 kg total = -.1268E+00 Activity = 0.9996 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2752922E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.1058E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11935E-09 -9.9232 0.98191E-10 -10.0079 0.82268E+00 -0.0848 2 H2O 0.99961E+00 -0.0002 0.99961E+00 -0.0002 3 Cl- 0.21097E-02 -2.6758 0.17223E-02 -2.7639 0.81637E+00 -0.0881 4 SO4-- 0.20631E-09 -9.6855 0.98136E-10 -10.0082 0.47567E+00 -0.3227 5 HCO3- 0.42650E-03 -3.3701 0.34884E-03 -3.4574 0.81790E+00 -0.0873 6 HS- 0.76507E-02 -2.1163 0.62470E-02 -2.2043 0.81652E+00 -0.0880 7 Al+++ 0.27222E-28 -28.5651 0.51451E-29 -29.2886 0.18900E+00 -0.7235 8 H4SiO4 0.69965E-03 -3.1551 0.69965E-03 -3.1551 0.10000E+01 0.0000 9 Ca++ 0.25343E-06 -6.5961 0.11941E-06 -6.9229 0.47119E+00 -0.3268 10 Mg++ 0.40602E-10 -10.3915 0.19019E-10 -10.7208 0.46843E+00 -0.3294 11 Fe++ 0.11119E-12 -12.9540 0.52156E-13 -13.2827 0.46909E+00 -0.3287 12 K+ 0.21002E-03 -3.6777 0.17182E-03 -3.7649 0.81813E+00 -0.0872 13 Na+ 0.26664E-01 -1.5741 0.21762E-01 -1.6623 0.81616E+00 -0.0882 14 Mn++ 0.36230E-10 -10.4409 0.17013E-10 -10.7692 0.46958E+00 -0.3283 15 F- 0.89025E-06 -6.0505 0.72487E-06 -6.1397 0.81423E+00 -0.0893 16 HPO4-- 0.29231E-07 -7.5342 0.13907E-07 -7.8568 0.47576E+00 -0.3226 18 HSiO3- 0.81530E-02 -2.0887 0.66559E-02 -2.1768 0.81637E+00 -0.0881 19 Ca(HSiO3)+ 0.22118E-07 -7.6552 0.18101E-07 -7.7423 0.81836E+00 -0.0871 20 Mg(HSiO3)+ 0.43842E-11 -11.3581 0.35878E-11 -11.4452 0.81836E+00 -0.0871 21 NaHSiO3,aq 0.23427E-02 -2.6303 0.23427E-02 -2.6303 0.10000E+01 0.0000 22 AlO+ 0.88678E-16 -16.0522 0.72570E-16 -16.1392 0.81836E+00 -0.0871 24 HAlO2,aq 0.14713E-09 -9.8323 0.14713E-09 -9.8323 0.10000E+01 0.0000 25 AlO2- 0.40722E-05 -5.3902 0.33168E-05 -5.4793 0.81449E+00 -0.0891 26 CH4,aq 0.21562E-01 -1.6663 0.21562E-01 -1.6663 0.10000E+01 0.0000 27 C2H6,aq 0.73535E-08 -8.1335 0.73535E-08 -8.1335 0.10000E+01 0.0000 28 C3H8,aq 0.57899E-13 -13.2373 0.57899E-13 -13.2373 0.10000E+01 0.0000 29 C4H10,aq 0.44785E-18 -18.3489 0.44785E-18 -18.3489 0.10000E+01 0.0000 30 ethanol,aq 0.28912E-15 -15.5389 0.28912E-15 -15.5389 0.10000E+01 0.0000 31 CO,aq 0.19887E-13 -13.7014 0.19887E-13 -13.7014 0.10000E+01 0.0000 32 CO2,aq 0.73218E-07 -7.1354 0.73218E-07 -7.1354 0.10000E+01 0.0000 33 CO3-2 0.65413E-03 -3.1843 0.31031E-03 -3.5082 0.47438E+00 -0.3239 34 CaCO3,aq 0.46463E-06 -6.3329 0.46463E-06 -6.3329 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.12993E-08 -8.8863 0.10633E-08 -8.9733 0.81836E+00 -0.0871 36 CaCl+ 0.40670E-09 -9.3907 0.33283E-09 -9.4778 0.81836E+00 -0.0871 37 CaCl2,aq 0.13619E-12 -12.8659 0.13619E-12 -12.8659 0.10000E+01 0.0000 38 CaF+ 0.15443E-11 -11.8113 0.12638E-11 -11.8983 0.81836E+00 -0.0871 39 CaOH+ 0.10587E-06 -6.9752 0.86640E-07 -7.0623 0.81836E+00 -0.0871 40 CaSO4,aq 0.37213E-14 -14.4293 0.37213E-14 -14.4293 0.10000E+01 0.0000 41 HCl,aq 0.30989E-13 -13.5088 0.30989E-13 -13.5088 0.10000E+01 0.0000 45 HF,aq 0.48725E-12 -12.3122 0.48725E-12 -12.3122 0.10000E+01 0.0000 46 HF2- 0.14607E-18 -18.8354 0.11925E-18 -18.9236 0.81637E+00 -0.0881 48 FeCl+ 0.17374E-15 -15.7601 0.14218E-15 -15.8472 0.81836E+00 -0.0871 51 FeF+ 0.23608E-17 -17.6269 0.19320E-17 -17.7140 0.81836E+00 -0.0871 53 FeO,aq 0.21016E-09 -9.6774 0.21016E-09 -9.6774 0.10000E+01 0.0000 54 FeOH+ 0.21119E-10 -10.6753 0.17283E-10 -10.7624 0.81836E+00 -0.0871 55 HFeO2- 0.27422E-07 -7.5619 0.22386E-07 -7.6500 0.81637E+00 -0.0881 56 FeO+ 0.15322E-16 -16.8147 0.12539E-16 -16.9017 0.81836E+00 -0.0871 58 FeO2- 0.32586E-09 -9.4870 0.26602E-09 -9.5751 0.81637E+00 -0.0881 59 HFeO2,aq 0.33221E-11 -11.4786 0.33221E-11 -11.4786 0.10000E+01 0.0000 60 H2,aq 0.10808E-04 -4.9662 0.10808E-04 -4.9662 0.10000E+01 0.0000 61 KCl,aq 0.53634E-08 -8.2706 0.53634E-08 -8.2706 0.10000E+01 0.0000 63 KOH,aq 0.74700E-06 -6.1267 0.74700E-06 -6.1267 0.10000E+01 0.0000 64 KSO4- 0.32051E-12 -12.4942 0.26165E-12 -12.5823 0.81637E+00 -0.0881 65 MgCO3,aq 0.18549E-10 -10.7317 0.18549E-10 -10.7317 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.21146E-12 -12.6748 0.17305E-12 -12.7618 0.81836E+00 -0.0871 67 MgCl+ 0.58709E-13 -13.2313 0.48045E-13 -13.3184 0.81836E+00 -0.0871 68 MgF+ 0.91111E-15 -15.0404 0.74562E-15 -15.1275 0.81836E+00 -0.0871 69 MgOH+ 0.93306E-10 -10.0301 0.76358E-10 -10.1171 0.81836E+00 -0.0871 71 MnF+ 0.25383E-15 -15.5955 0.20772E-15 -15.6825 0.81836E+00 -0.0871 72 MnO,aq 0.18267E-08 -8.7383 0.18267E-08 -8.7383 0.10000E+01 0.0000 73 MnOH+ 0.63997E-09 -9.1938 0.52373E-09 -9.2809 0.81836E+00 -0.0871 74 MnO2-2 0.13249E-10 -10.8778 0.62853E-11 -11.2017 0.47438E+00 -0.3239 75 HMnO2- 0.16562E-09 -9.7809 0.13521E-09 -9.8690 0.81637E+00 -0.0881 78 MnCl+ 0.22048E-12 -12.6566 0.18043E-12 -12.7437 0.81836E+00 -0.0871 79 MnSO4,aq 0.48200E-18 -18.3170 0.48200E-18 -18.3170 0.10000E+01 0.0000 80 NaCl,aq 0.12421E-04 -4.9058 0.12421E-04 -4.9058 0.10000E+01 0.0000 81 NaF,aq 0.36932E-08 -8.4326 0.36932E-08 -8.4326 0.10000E+01 0.0000 82 NaOH,aq 0.95187E-04 -4.0214 0.95187E-04 -4.0214 0.10000E+01 0.0000 84 OH- 0.72215E-02 -2.1414 0.58819E-02 -2.2305 0.81449E+00 -0.0891 89 HPO3-2 0.98781E-15 -15.0053 0.46860E-15 -15.3292 0.47438E+00 -0.3239 91 H2PO3- 0.11302E-18 -18.9468 0.92268E-19 -19.0350 0.81637E+00 -0.0881 92 H3PO4,aq 0.93776E-18 -18.0279 0.93776E-18 -18.0279 0.10000E+01 0.0000 93 H2PO4- 0.30819E-10 -10.5112 0.25190E-10 -10.5988 0.81736E+00 -0.0876 94 PO4-3 0.57420E-09 -9.2409 0.11556E-09 -9.9372 0.20125E+00 -0.6963 98 HP2O7-3 0.53477E-18 -18.2718 0.10122E-18 -18.9947 0.18928E+00 -0.7229 99 P2O7-4 0.45247E-17 -17.3444 0.24626E-18 -18.6086 0.54427E-01 -1.2642 100 H2S,aq 0.18958E-05 -5.7222 0.18958E-05 -5.7222 0.10000E+01 0.0000 101 S2-2 0.16865E-09 -9.7730 0.80004E-10 -10.0969 0.47438E+00 -0.3239 102 S3-2 0.39853E-16 -16.3995 0.18906E-16 -16.7234 0.47438E+00 -0.3239 107 SO3-2 0.28539E-15 -15.5446 0.13789E-15 -15.8605 0.48315E+00 -0.3159 108 HSO3- 0.10384E-17 -17.9836 0.84773E-18 -18.0717 0.81637E+00 -0.0881 109 HSO4- 0.11333E-16 -16.9456 0.92864E-17 -17.0322 0.81939E+00 -0.0865 111 S2O3-2 0.46087E-17 -17.3364 0.21863E-17 -17.6603 0.47438E+00 -0.3239 Charge balance for all species = -.1737E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1193547E-09 -.1848507E-01 -.1858693E+02 0.0000 2 H2O 0.1000000E+01 0.5552665E+02 0.9979183E+06 0.0000 3 Cl- 0.2109683E-02 0.2122110E-02 0.7505385E+02 7.2440 4 SO4-- 0.2063106E-09 -.2156442E-01 -.2066520E+04 10.0077 5 HCO3- 0.4265040E-03 0.2264290E-01 0.1378276E+04 6.5506 6 HS- 0.7650710E-02 0.2921703E-01 0.9639367E+03 7.8036 7 Al+++ 0.2722206E-28 0.4072382E-05 0.1096141E+00 0.7352 8 H4SiO4 0.6996499E-03 0.1119542E-01 0.1073458E+04 -3.1551 9 Ca++ 0.2534332E-06 0.8477602E-06 0.3389464E-01 13.0929 10 Mg++ 0.4060186E-10 0.1571130E-09 0.3810524E-05 9.2950 11 Fe++ 0.1111857E-12 0.2798217E-07 0.1558954E-02 6.7332 12 K+ 0.2100161E-03 0.2107685E-03 0.8221605E+01 6.2430 13 Na+ 0.2666415E-01 0.2911447E-01 0.6677226E+03 8.3456 14 Mn++ 0.3622998E-10 0.2681983E-08 0.1469876E-03 9.2466 15 F- 0.8902547E-06 0.8939499E-06 0.1694233E-01 3.8682 16 HPO4-- 0.2923107E-07 0.2983609E-07 0.2856736E-02 12.1591 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277575E+02 -.9217794E-02 -.8276653E+02 0.0000000E+00 2 H2O -.7041080E+01 0.2768901E+02 -.3473009E+02 0.0000000E+00 3 Cl- 0.1058215E-02 0.1058215E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1393374E+00 -.1075335E-01 0.1500907E+00 0.0000000E+00 5 HCO3- 0.1129115E-01 0.1129115E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1355213E+00 0.1456941E-01 -.1500907E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2030741E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5582726E-02 0.5205832E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.4227455E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.7834622E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1395363E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1051022E-03 0.1061466E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1451827E-01 0.6261859E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1337402E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6249600E-04 0.4457786E-06 0.6205022E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1487812E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.4045E-14 Mass of aqueous solution: 0.499866E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1559900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.8 andradite 0.6004 -0.222 305.1 2.484 5.585 79.27 grossular 0.1398 -0.855 62.97 1.799 1.153 17.52 apatite-OH 0.9801E-02 -2.009 4.923 0.692 0.9012E-01 1.564 apatite-F 0.6205E-04 -4.207 0.3129E-01 -1.505 0.5728E-03 0.9776E-02 clinochlore 0.7035 -0.153 391.0 2.592 7.157 148.7 daphnite 0.2024 -0.694 144.4 2.160 2.644 43.76 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9418 -0.026 262.1 2.419 4.798 102.4 stilbite 3.232 0.509 2278. 3.358 41.69 1062. stilpnomelane-Fe 0.2394 -0.621 258.0 2.412 4.723 89.13 tr.625ac.25prg.125 0.1244 -0.905 106.3 2.027 1.947 34.23 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8111E+00 0.8111E+00 1.0000 -0.091 grossular 0.1889E+00 0.1889E+00 1.0000 -0.724 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7620E+00 0.7620E+00 1.0000 -0.118 daphnite 0.2192E+00 0.2192E+00 1.0000 -0.659 chlorite-Mn 0.1878E-01 0.1878E-01 1.0000 -1.726 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.884355 g Volume = 2211.655516 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1559900 moles log = -0.8069 Original solution: 1000.0103000 g Original solution / Rock added: 6410.73 (Water/Rock Ratio), log = 3.8069 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 33.4576 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3209E-01 0.9365 0.1006E+01 0.1074E+01 CO2,gas 0.2481E-06 0.9436 0.7834E-05 0.8302E-05 CH4,gas 0.9675E+00 0.9805 0.3174E+02 0.3237E+02 H2,gas 0.4166E-03 1.0180 0.1419E-01 0.1394E-01 H2S,gas 0.1768E-05 0.8808 0.5211E-04 0.5917E-04 S2,gas 0.1513E-25 1.0000 0.5063E-24 0.5063E-24 CO,gas 0.8858E-12 1.0000 0.2964E-10 0.2964E-10 SO3,gas 0.1070E-46 1.0000 0.3579E-45 0.3579E-45 SO2,gas 0.5908E-26 1.0000 0.1977E-24 0.1977E-24 HF,gas 0.3576E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1634E-17 1.0000 0.5468E-16 0.5468E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 117 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 164 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.47 -6.81 -2.268 0.11619E+05 -5.106 3 CH4,gas 4.54 4.35 -0.20 -0.049 0.33705E+03 1.502 4 H2,gas 8.00 4.45 -3.55 -2.027 0.60564E+04 -1.848 5 H2S,gas -6.23 -12.21 -5.98 -2.991 0.10214E+05 -4.283 6 S2,gas -7.34 -33.33 -25.99 -3.999 0.44385E+05 -24.296 7 CO,gas 3.21 -9.01 -12.23 -3.762 0.20878E+05 -10.528 8 SO3,gas 17.12 -30.02 -47.15 -11.786 0.80499E+05 -45.446 9 SO2,gas 0.83 -25.57 -26.40 -7.041 0.45083E+05 -24.704 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.77 -17.96 -8.981 0.30668E+05 -16.262 12 acmite 7.71 6.54 -1.17 -0.121 0.19930E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.71 -0.236 0.80463E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94101E+03 26 ankerite -2.14 -7.10 -4.97 -0.828 0.84852E+04 27 annite 20.12 17.71 -2.41 -0.134 0.41169E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28457E+04 30 anorthite 12.71 8.25 -4.46 -0.343 0.76107E+04 38 aragonite 0.97 -0.37 -1.34 -0.446 0.22862E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55900E+04 40 calcite 0.81 -0.37 -1.18 -0.395 0.20219E+04 41 carnegieite-low 9.02 5.93 -3.10 -0.443 0.52891E+04 42 carnegieite-high 10.09 5.93 -4.17 -0.595 0.71161E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70472E+04 44 carpholite-Fe 6.71 1.89 -4.82 -0.321 0.82295E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28825E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47553E+04 47 chrysotile 23.89 21.57 -2.32 -0.193 0.39573E+04 52 chlorite-Al-free 47.17 43.15 -4.02 -0.168 0.68698E+04 54 chloritoid-Fe 9.17 5.05 -4.13 -0.275 0.70446E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65562E+04 57 coesite -2.38 -3.15 -0.78 -0.260 0.13296E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10150E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.14 -0.356 0.36520E+04 69 diamond -3.10 -4.56 -1.46 -0.416 0.24876E+04 72 enstatite 17.26 12.28 -4.98 -0.498 0.85113E+04 74 clinoenstatite 17.17 12.28 -4.89 -0.489 0.83428E+04 76 epidote 24.67 22.70 -1.97 -0.096 0.33680E+04 77 clinozoisite 22.81 18.93 -3.88 -0.176 0.66253E+04 78 epidote-Fe 29.84 26.47 -3.37 -0.175 0.57572E+04 79 fayalite 14.05 10.31 -3.73 -0.534 0.63766E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68180E+04 84 gibbsite 4.08 0.73 -3.34 -0.478 0.57109E+04 85 glaucophane 22.97 20.81 -2.17 -0.059 0.37012E+04 86 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70934E+04 87 graphite -3.55 -4.56 -1.01 -0.289 0.17298E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38425E+04 91 hematite 12.57 9.01 -3.55 -0.431 0.60669E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.44 -0.144 0.24662E+04 98 kalsilite 7.58 3.82 -3.76 -0.537 0.64215E+04 99 kaolinite -1.33 -4.84 -3.51 -0.319 0.59886E+04 102 laumontite 2.88 1.94 -0.94 -0.063 0.16061E+04 103 lawsonite 9.62 8.25 -1.36 -0.091 0.23279E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58918E+04 106 lizardite 23.24 21.57 -1.67 -0.139 0.28499E+04 107 magnesite 0.69 -4.17 -4.86 -1.620 0.82998E+04 108 magnetite 20.09 15.75 -4.34 -0.354 0.74128E+04 109 minnesotaite 10.39 7.58 -2.81 -0.165 0.47953E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82157E+04 121 muscovite 2.58 -1.02 -3.60 -0.212 0.61456E+04 122 paragonite 4.24 1.09 -3.15 -0.186 0.53847E+04 123 nepheline 8.34 5.93 -2.41 -0.345 0.41214E+04 129 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83557E+04 135 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36645E+04 137 prehnite 19.37 18.19 -1.18 -0.069 0.20166E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91425E+03 139 pumpellyite-Fe 46.27 43.85 -2.42 -0.054 0.41322E+04 140 pumpellyite-Mg 48.99 46.41 -2.58 -0.057 0.44115E+04 143 pyrite -21.25 -22.14 -0.90 -0.211 0.15319E+04 144 pyrrhotite -4.26 -5.48 -1.22 -0.406 0.20810E+04 145 pyrrhotiteFe0.875 -6.02 -6.87 -0.86 -0.315 0.14615E+04 146 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22316E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84924E+04 148 quartz -2.99 -3.15 -0.17 -0.055 0.28233E+03 152 rhodochrosite -0.98 -4.22 -3.24 -1.081 0.55362E+04 153 rhodonite 7.45 6.09 -1.35 -0.271 0.23119E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.73 -4.12 -1.375 0.70416E+04 166 stilpnomelane-Mg 27.44 25.83 -1.61 -0.048 0.27575E+04 172 talc 16.49 15.27 -1.23 -0.072 0.20929E+04 175 tephroite 18.09 15.34 -2.75 -0.393 0.46915E+04 179 tridymite -2.63 -3.15 -0.53 -0.176 0.90230E+03 180 tremolite 47.87 47.42 -0.45 -0.012 0.76457E+03 181 ferroactinolite 38.45 34.61 -3.84 -0.104 0.65573E+04 182 troilite-low -4.41 -5.48 -1.07 -0.356 0.18238E+04 184 vesuvianite 223.47 218.65 -4.82 -0.037 0.82329E+04 188 wairakite 3.95 1.94 -2.01 -0.118 0.34275E+04 189 walstromite 11.51 9.94 -1.57 -0.314 0.26829E+04 190 wollastonite 10.46 9.94 -0.52 -0.105 0.89332E+03 191 pseudo-wollastonite 11.00 9.94 -1.06 -0.212 0.18131E+04 192 zoisite 22.85 18.93 -3.92 -0.178 0.66994E+04 193 akaganeite 7.75 4.51 -3.25 -0.702 0.55461E+04 200 chalcedony -2.80 -3.15 -0.35 -0.117 0.60162E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66141E+04 203 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68773E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73611E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60322E+04 206 nontronite-Ca 3.21 -0.16 -3.38 -0.219 0.57659E+04 207 nontronite-H 2.53 -2.32 -4.86 -0.325 0.82904E+04 208 nontronite-K 3.34 -0.26 -3.60 -0.231 0.61523E+04 209 nontronite-Mg 3.07 -0.79 -3.86 -0.251 0.65970E+04 210 nontronite-Na 3.52 0.43 -3.09 -0.198 0.52732E+04 226 tobermorite 9.82 7.75 -2.07 -0.565 0.35375E+04 232 alabandite -0.98 -2.97 -1.99 -0.663 0.33940E+04 235 boehmite 4.41 0.73 -3.67 -0.612 0.62690E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52566E+04 243 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18158E+04 245 an20ab80 2.02 1.34 -0.67 -0.052 0.11513E+04 246 an25ab75 2.65 1.78 -0.87 -0.067 0.14861E+04 247 an30ab70 3.28 2.21 -1.07 -0.082 0.18305E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1559900 MOLES New total amount of reactant added: 0.1599900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8664E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1599900 Water: Moles liquid = 0.2768E+02 kg liquid = 0.4986E+00 Moles total = -.7038E+01 kg total = -.1268E+00 Activity = 0.9996 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2780325E-01 Chg. balance for total moles = -.8664E-10 Max. difference allowed = 0.1082E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12056E-09 -9.9188 0.99115E-10 -10.0039 0.82212E+00 -0.0851 2 H2O 0.99960E+00 -0.0002 0.99960E+00 -0.0002 3 Cl- 0.21568E-02 -2.6662 0.17594E-02 -2.7546 0.81576E+00 -0.0884 4 SO4-- 0.22169E-09 -9.6543 0.10515E-09 -9.9782 0.47431E+00 -0.3239 5 HCO3- 0.45681E-03 -3.3403 0.37335E-03 -3.4279 0.81730E+00 -0.0876 6 HS- 0.78460E-02 -2.1054 0.64017E-02 -2.1937 0.81592E+00 -0.0884 7 Al+++ 0.28129E-28 -28.5508 0.52817E-29 -29.2772 0.18777E+00 -0.7264 8 H4SiO4 0.70043E-03 -3.1546 0.70043E-03 -3.1546 0.10000E+01 0.0000 9 Ca++ 0.25794E-06 -6.5885 0.12118E-06 -6.9166 0.46980E+00 -0.3281 10 Mg++ 0.41509E-10 -10.3819 0.19386E-10 -10.7125 0.46704E+00 -0.3306 11 Fe++ 0.11352E-12 -12.9449 0.53095E-13 -13.2749 0.46770E+00 -0.3300 12 K+ 0.21183E-03 -3.6740 0.17318E-03 -3.7615 0.81754E+00 -0.0875 13 Na+ 0.26895E-01 -1.5703 0.21934E-01 -1.6589 0.81556E+00 -0.0885 14 Mn++ 0.37011E-10 -10.4317 0.17328E-10 -10.7612 0.46820E+00 -0.3296 15 F- 0.88262E-06 -6.0542 0.71811E-06 -6.1438 0.81362E+00 -0.0896 16 HPO4-- 0.28966E-07 -7.5381 0.13741E-07 -7.8620 0.47440E+00 -0.3239 18 HSiO3- 0.80921E-02 -2.0919 0.66012E-02 -2.1804 0.81576E+00 -0.0884 19 Ca(HSiO3)+ 0.22277E-07 -7.6521 0.18218E-07 -7.7395 0.81777E+00 -0.0874 20 Mg(HSiO3)+ 0.44353E-11 -11.3531 0.36271E-11 -11.4404 0.81777E+00 -0.0874 21 NaHSiO3,aq 0.23418E-02 -2.6304 0.23418E-02 -2.6304 0.10000E+01 0.0000 22 AlO+ 0.89408E-16 -16.0486 0.73115E-16 -16.1360 0.81777E+00 -0.0874 24 HAlO2,aq 0.14685E-09 -9.8331 0.14685E-09 -9.8331 0.10000E+01 0.0000 25 AlO2- 0.40297E-05 -5.3947 0.32797E-05 -5.4842 0.81388E+00 -0.0894 26 CH4,aq 0.22071E-01 -1.6562 0.22071E-01 -1.6562 0.10000E+01 0.0000 27 C2H6,aq 0.78097E-08 -8.1074 0.78097E-08 -8.1074 0.10000E+01 0.0000 28 C3H8,aq 0.63799E-13 -13.1952 0.63799E-13 -13.1952 0.10000E+01 0.0000 29 C4H10,aq 0.51200E-18 -18.2907 0.51200E-18 -18.2907 0.10000E+01 0.0000 30 ethanol,aq 0.31123E-15 -15.5069 0.31123E-15 -15.5069 0.10000E+01 0.0000 31 CO,aq 0.21198E-13 -13.6737 0.21198E-13 -13.6737 0.10000E+01 0.0000 32 CO2,aq 0.79101E-07 -7.1018 0.79101E-07 -7.1018 0.10000E+01 0.0000 33 CO3-2 0.69558E-03 -3.1577 0.32902E-03 -3.4828 0.47301E+00 -0.3251 34 CaCO3,aq 0.49993E-06 -6.3011 0.49993E-06 -6.3011 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.14122E-08 -8.8501 0.11549E-08 -8.9375 0.81777E+00 -0.0874 36 CaCl+ 0.42192E-09 -9.3748 0.34503E-09 -9.4621 0.81777E+00 -0.0874 37 CaCl2,aq 0.14422E-12 -12.8410 0.14422E-12 -12.8410 0.10000E+01 0.0000 38 CaF+ 0.15536E-11 -11.8087 0.12705E-11 -11.8960 0.81777E+00 -0.0874 39 CaOH+ 0.10651E-06 -6.9726 0.87101E-07 -7.0600 0.81777E+00 -0.0874 40 CaSO4,aq 0.40461E-14 -14.3930 0.40461E-14 -14.3930 0.10000E+01 0.0000 41 HCl,aq 0.31955E-13 -13.4955 0.31955E-13 -13.4955 0.10000E+01 0.0000 45 HF,aq 0.48725E-12 -12.3123 0.48725E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.14481E-18 -18.8392 0.11813E-18 -18.9276 0.81576E+00 -0.0884 48 FeCl+ 0.18081E-15 -15.7428 0.14786E-15 -15.8301 0.81777E+00 -0.0874 51 FeF+ 0.23826E-17 -17.6230 0.19484E-17 -17.7103 0.81777E+00 -0.0874 53 FeO,aq 0.20998E-09 -9.6778 0.20998E-09 -9.6778 0.10000E+01 0.0000 54 FeOH+ 0.21315E-10 -10.6713 0.17430E-10 -10.7587 0.81777E+00 -0.0874 55 HFeO2- 0.27162E-07 -7.5660 0.22157E-07 -7.6545 0.81576E+00 -0.0884 56 FeO+ 0.15569E-16 -16.8077 0.12732E-16 -16.8951 0.81777E+00 -0.0874 58 FeO2- 0.32495E-09 -9.4882 0.26508E-09 -9.5766 0.81576E+00 -0.0884 59 HFeO2,aq 0.33416E-11 -11.4760 0.33416E-11 -11.4760 0.10000E+01 0.0000 60 H2,aq 0.10663E-04 -4.9721 0.10663E-04 -4.9721 0.10000E+01 0.0000 61 KCl,aq 0.55223E-08 -8.2579 0.55223E-08 -8.2579 0.10000E+01 0.0000 63 KOH,aq 0.74588E-06 -6.1273 0.74588E-06 -6.1273 0.10000E+01 0.0000 64 KSO4- 0.34638E-12 -12.4604 0.28257E-12 -12.5489 0.81576E+00 -0.0884 65 MgCO3,aq 0.20047E-10 -10.6979 0.20047E-10 -10.6979 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.23085E-12 -12.6367 0.18878E-12 -12.7240 0.81777E+00 -0.0874 67 MgCl+ 0.61177E-13 -13.2134 0.50028E-13 -13.3008 0.81777E+00 -0.0874 68 MgF+ 0.92070E-15 -15.0359 0.75292E-15 -15.1233 0.81777E+00 -0.0874 69 MgOH+ 0.94288E-10 -10.0255 0.77106E-10 -10.1129 0.81777E+00 -0.0874 71 MnF+ 0.25630E-15 -15.5912 0.20960E-15 -15.6786 0.81777E+00 -0.0874 72 MnO,aq 0.18260E-08 -8.7385 0.18260E-08 -8.7385 0.10000E+01 0.0000 73 MnOH+ 0.64622E-09 -9.1896 0.52846E-09 -9.2770 0.81777E+00 -0.0874 74 MnO2-2 0.13036E-10 -10.8849 0.61663E-11 -11.2100 0.47301E+00 -0.3251 75 HMnO2- 0.16414E-09 -9.7848 0.13390E-09 -9.8732 0.81576E+00 -0.0884 78 MnCl+ 0.22958E-12 -12.6391 0.18774E-12 -12.7264 0.81777E+00 -0.0874 79 MnSO4,aq 0.52601E-18 -18.2790 0.52601E-18 -18.2790 0.10000E+01 0.0000 80 NaCl,aq 0.12789E-04 -4.8932 0.12789E-04 -4.8932 0.10000E+01 0.0000 81 NaF,aq 0.36877E-08 -8.4332 0.36877E-08 -8.4332 0.10000E+01 0.0000 82 NaOH,aq 0.95045E-04 -4.0221 0.95045E-04 -4.0221 0.10000E+01 0.0000 84 OH- 0.71596E-02 -2.1451 0.58270E-02 -2.2346 0.81388E+00 -0.0894 89 HPO3-2 0.96576E-15 -15.0151 0.45682E-15 -15.3403 0.47301E+00 -0.3251 91 H2PO3- 0.11130E-18 -18.9535 0.90795E-19 -19.0419 0.81576E+00 -0.0884 92 H3PO4,aq 0.94412E-18 -18.0250 0.94412E-18 -18.0250 0.10000E+01 0.0000 93 H2PO4- 0.30761E-10 -10.5120 0.25124E-10 -10.5999 0.81676E+00 -0.0879 94 PO4-3 0.56551E-09 -9.2476 0.11311E-09 -9.9465 0.20002E+00 -0.6989 98 HP2O7-3 0.53048E-18 -18.2753 0.99753E-19 -19.0011 0.18804E+00 -0.7257 99 P2O7-4 0.44681E-17 -17.3499 0.24044E-18 -18.6190 0.53812E-01 -1.2691 100 H2S,aq 0.19610E-05 -5.7075 0.19610E-05 -5.7075 0.10000E+01 0.0000 101 S2-2 0.18003E-09 -9.7447 0.85157E-10 -10.0698 0.47301E+00 -0.3251 102 S3-2 0.44604E-16 -16.3506 0.21099E-16 -16.6757 0.47301E+00 -0.3251 107 SO3-2 0.30252E-15 -15.5192 0.14576E-15 -15.8364 0.48183E+00 -0.3171 108 HSO3- 0.11089E-17 -17.9551 0.90458E-18 -18.0436 0.81576E+00 -0.0884 109 HSO4- 0.12266E-16 -16.9113 0.10044E-16 -16.9981 0.81881E+00 -0.0868 111 S2O3-2 0.51227E-17 -17.2905 0.24231E-17 -17.6156 0.47301E+00 -0.3251 Charge balance for all species = -.1737E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1205601E-09 -.1840233E-01 -.1850336E+02 0.0000 2 H2O 0.1000000E+01 0.5552716E+02 0.9979072E+06 0.0000 3 Cl- 0.2156763E-02 0.2169558E-02 0.7673039E+02 7.2492 4 SO4-- 0.2216862E-09 -.2207384E-01 -.2115295E+04 10.0295 5 HCO3- 0.4568064E-03 0.2322414E-01 0.1413628E+04 6.5760 6 HS- 0.7846003E-02 0.2992181E-01 0.9871690E+03 7.8102 7 Al+++ 0.2812914E-28 0.4029811E-05 0.1084661E+00 0.7344 8 H4SiO4 0.7004284E-03 0.1113437E-01 0.1067584E+04 -3.1546 9 Ca++ 0.2579378E-06 0.8884935E-06 0.3552250E-01 13.0912 10 Mg++ 0.4150914E-10 0.1605710E-09 0.3894315E-05 9.2952 11 Fe++ 0.1135249E-12 0.2772135E-07 0.1544392E-02 6.7328 12 K+ 0.2118298E-03 0.2125812E-03 0.8292146E+01 6.2424 13 Na+ 0.2689491E-01 0.2934458E-01 0.6729865E+03 8.3450 14 Mn++ 0.3701115E-10 0.2686648E-08 0.1472404E-03 9.2465 15 F- 0.8826169E-06 0.8863067E-06 0.1679713E-01 3.8601 16 HPO4-- 0.2896572E-07 0.2956199E-07 0.2830435E-02 12.1457 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277532E+02 -.9176024E-02 -.8276614E+02 0.0000000E+00 2 H2O -.7037805E+01 0.2768773E+02 -.3472553E+02 0.0000000E+00 3 Cl- 0.1081815E-02 0.1081815E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1393565E+00 -.1100677E-01 0.1503632E+00 0.0000000E+00 5 HCO3- 0.1158035E-01 0.1158035E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1354432E+00 0.1492003E-01 -.1503632E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2009400E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5551975E-02 0.5205835E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.4430330E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.8006618E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1382281E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1060002E-03 0.1061465E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1463221E-01 0.6261745E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1339654E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6409600E-04 0.4419426E-06 0.6365406E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1474061E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.2324E-13 Mass of aqueous solution: 0.499849E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1599900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.8 andradite 0.6015 -0.221 305.6 2.485 5.595 79.41 grossular 0.1390 -0.857 62.60 1.797 1.146 17.42 apatite-OH 0.9799E-02 -2.009 4.922 0.692 0.9010E-01 1.564 apatite-F 0.6365E-04 -4.196 0.3210E-01 -1.493 0.5876E-03 0.1003E-01 clinochlore 0.7040 -0.152 391.3 2.593 7.163 148.8 daphnite 0.2023 -0.694 144.3 2.159 2.642 43.74 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9419 -0.026 262.2 2.419 4.799 102.4 stilbite 3.233 0.510 2278. 3.358 41.70 1063. stilpnomelane-Fe 0.2392 -0.621 257.9 2.411 4.720 89.07 tr.625ac.25prg.125 0.1237 -0.908 105.7 2.024 1.935 34.03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8123E+00 0.8123E+00 1.0000 -0.090 grossular 0.1877E+00 0.1877E+00 1.0000 -0.727 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7622E+00 0.7622E+00 1.0000 -0.118 daphnite 0.2190E+00 0.2190E+00 1.0000 -0.660 chlorite-Mn 0.1877E-01 0.1877E-01 1.0000 -1.726 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.984404 g Volume = 2211.753097 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1599900 moles log = -0.7959 Original solution: 1000.0103000 g Original solution / Rock added: 6250.46 (Water/Rock Ratio), log = 3.7959 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 34.2382 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3139E-01 0.9356 0.1006E+01 0.1075E+01 CO2,gas 0.2623E-06 0.9424 0.8463E-05 0.8980E-05 CH4,gas 0.9682E+00 0.9800 0.3249E+02 0.3315E+02 H2,gas 0.4015E-03 1.0184 0.1400E-01 0.1375E-01 H2S,gas 0.1793E-05 0.8783 0.5391E-04 0.6138E-04 S2,gas 0.1625E-25 1.0000 0.5565E-24 0.5565E-24 CO,gas 0.9226E-12 1.0000 0.3159E-10 0.3159E-10 SO3,gas 0.1141E-46 1.0000 0.3907E-45 0.3907E-45 SO2,gas 0.6218E-26 1.0000 0.2129E-24 0.2129E-24 HF,gas 0.3494E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1647E-17 1.0000 0.5639E-16 0.5639E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 117 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 164 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.43 -6.77 -2.257 0.11562E+05 -5.072 3 CH4,gas 4.54 4.36 -0.19 -0.047 0.31974E+03 1.512 4 H2,gas 8.00 4.45 -3.55 -2.030 0.60664E+04 -1.854 5 H2S,gas -6.23 -12.20 -5.97 -2.984 0.10189E+05 -4.268 6 S2,gas -7.34 -33.29 -25.95 -3.993 0.44315E+05 -24.255 7 CO,gas 3.21 -8.98 -12.20 -3.754 0.20830E+05 -10.500 8 SO3,gas 17.12 -29.99 -47.11 -11.777 0.80434E+05 -45.408 9 SO2,gas 0.83 -25.54 -26.37 -7.032 0.45027E+05 -24.672 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.76 -17.95 -8.974 0.30645E+05 -16.249 12 acmite 7.71 6.55 -1.16 -0.121 0.19881E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.71 -0.236 0.80474E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94186E+03 26 ankerite -2.14 -7.04 -4.90 -0.817 0.83743E+04 27 annite 20.12 17.71 -2.41 -0.134 0.41188E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28449E+04 30 anorthite 12.71 8.25 -4.46 -0.343 0.76148E+04 38 aragonite 0.97 -0.34 -1.31 -0.436 0.22319E+04 39 brucite 12.57 9.29 -3.27 -0.655 0.55897E+04 40 calcite 0.81 -0.34 -1.15 -0.384 0.19676E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52907E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71177E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70480E+04 44 carpholite-Fe 6.71 1.89 -4.82 -0.321 0.82313E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28814E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47551E+04 47 chrysotile 23.89 21.58 -2.32 -0.193 0.39548E+04 52 chlorite-Al-free 47.17 43.15 -4.02 -0.168 0.68648E+04 54 chloritoid-Fe 9.17 5.05 -4.13 -0.275 0.70472E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65584E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13288E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10142E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36534E+04 69 diamond -3.10 -4.54 -1.44 -0.410 0.24502E+04 72 enstatite 17.26 12.28 -4.98 -0.498 0.85090E+04 74 clinoenstatite 17.17 12.28 -4.88 -0.488 0.83406E+04 76 epidote 24.67 22.70 -1.97 -0.096 0.33699E+04 77 clinozoisite 22.81 18.92 -3.88 -0.177 0.66330E+04 78 epidote-Fe 29.84 26.47 -3.37 -0.175 0.57534E+04 79 fayalite 14.05 10.31 -3.73 -0.534 0.63771E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68176E+04 84 gibbsite 4.08 0.73 -3.35 -0.478 0.57123E+04 85 glaucophane 22.97 20.81 -2.17 -0.059 0.36986E+04 86 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70937E+04 87 graphite -3.55 -4.54 -0.99 -0.283 0.16925E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38429E+04 91 hematite 12.57 9.02 -3.55 -0.430 0.60582E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.44 -0.144 0.24671E+04 98 kalsilite 7.58 3.82 -3.76 -0.537 0.64232E+04 99 kaolinite -1.33 -4.84 -3.51 -0.319 0.59897E+04 102 laumontite 2.88 1.94 -0.94 -0.063 0.16086E+04 103 lawsonite 9.62 8.25 -1.37 -0.091 0.23321E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58926E+04 106 lizardite 23.24 21.58 -1.67 -0.139 0.28474E+04 107 magnesite 0.69 -4.14 -4.83 -1.609 0.82422E+04 108 magnetite 20.09 15.75 -4.34 -0.354 0.74047E+04 109 minnesotaite 10.39 7.58 -2.81 -0.165 0.47939E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82160E+04 121 muscovite 2.58 -1.02 -3.60 -0.212 0.61484E+04 122 paragonite 4.24 1.08 -3.16 -0.186 0.53875E+04 123 nepheline 8.34 5.92 -2.41 -0.345 0.41231E+04 129 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83563E+04 135 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36637E+04 137 prehnite 19.37 18.19 -1.18 -0.070 0.20229E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91482E+03 139 pumpellyite-Fe 46.27 43.84 -2.43 -0.054 0.41470E+04 140 pumpellyite-Mg 48.99 46.40 -2.59 -0.058 0.44253E+04 143 pyrite -21.25 -22.11 -0.86 -0.203 0.14724E+04 144 pyrrhotite -4.26 -5.46 -1.20 -0.401 0.20566E+04 145 pyrrhotiteFe0.875 -6.02 -6.86 -0.84 -0.309 0.14357E+04 146 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22311E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84918E+04 148 quartz -2.99 -3.15 -0.16 -0.055 0.28149E+03 152 rhodochrosite -0.98 -4.19 -3.21 -1.070 0.54792E+04 153 rhodonite 7.45 6.09 -1.35 -0.271 0.23113E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.70 -4.09 -1.364 0.69850E+04 166 stilpnomelane-Mg 27.44 25.83 -1.61 -0.048 0.27528E+04 172 talc 16.49 15.27 -1.22 -0.072 0.20887E+04 175 tephroite 18.09 15.34 -2.75 -0.392 0.46912E+04 179 tridymite -2.63 -3.15 -0.53 -0.176 0.90146E+03 180 tremolite 47.87 47.42 -0.45 -0.012 0.76248E+03 181 ferroactinolite 38.45 34.61 -3.84 -0.104 0.65599E+04 182 troilite-low -4.41 -5.46 -1.05 -0.351 0.17994E+04 184 vesuvianite 223.47 218.62 -4.86 -0.037 0.82899E+04 188 wairakite 3.95 1.94 -2.01 -0.118 0.34299E+04 189 walstromite 11.51 9.94 -1.57 -0.315 0.26851E+04 190 wollastonite 10.46 9.94 -0.52 -0.105 0.89549E+03 191 pseudo-wollastonite 11.00 9.94 -1.06 -0.213 0.18153E+04 192 zoisite 22.85 18.92 -3.93 -0.179 0.67071E+04 193 akaganeite 7.75 4.51 -3.25 -0.702 0.55418E+04 200 chalcedony -2.80 -3.15 -0.35 -0.117 0.60078E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66135E+04 203 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68766E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73600E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60315E+04 206 nontronite-Ca 3.21 -0.16 -3.37 -0.219 0.57552E+04 207 nontronite-H 2.53 -2.32 -4.85 -0.325 0.82791E+04 208 nontronite-K 3.34 -0.26 -3.60 -0.231 0.61414E+04 209 nontronite-Mg 3.07 -0.78 -3.86 -0.250 0.65857E+04 210 nontronite-Na 3.52 0.44 -3.08 -0.198 0.52623E+04 226 tobermorite 9.82 7.75 -2.07 -0.566 0.35392E+04 232 alabandite -0.98 -2.95 -1.97 -0.658 0.33692E+04 235 boehmite 4.41 0.73 -3.67 -0.612 0.62704E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52573E+04 243 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18150E+04 245 an20ab80 2.02 1.34 -0.67 -0.052 0.11521E+04 246 an25ab75 2.65 1.77 -0.87 -0.067 0.14871E+04 247 an30ab70 3.28 2.21 -1.07 -0.083 0.18317E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1599900 MOLES New total amount of reactant added: 0.1639900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1639900 Water: Moles liquid = 0.2768E+02 kg liquid = 0.4986E+00 Moles total = -.7035E+01 kg total = -.1267E+00 Activity = 0.9996 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2808434E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.1105E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12179E-09 -9.9144 0.10006E-09 -9.9998 0.82155E+00 -0.0854 2 H2O 0.99959E+00 -0.0002 0.99959E+00 -0.0002 3 Cl- 0.22038E-02 -2.6568 0.17965E-02 -2.7456 0.81515E+00 -0.0888 4 SO4-- 0.23801E-09 -9.6234 0.11256E-09 -9.9486 0.47293E+00 -0.3252 5 HCO3- 0.48881E-03 -3.3109 0.39921E-03 -3.3988 0.81670E+00 -0.0879 6 HS- 0.80413E-02 -2.0947 0.65561E-02 -2.1834 0.81530E+00 -0.0887 7 Al+++ 0.29079E-28 -28.5364 0.54237E-29 -29.2657 0.18652E+00 -0.7293 8 H4SiO4 0.70121E-03 -3.1542 0.70121E-03 -3.1542 0.10000E+01 0.0000 9 Ca++ 0.26259E-06 -6.5807 0.12300E-06 -6.9101 0.46840E+00 -0.3294 10 Mg++ 0.42448E-10 -10.3721 0.19764E-10 -10.7041 0.46562E+00 -0.3320 11 Fe++ 0.11594E-12 -12.9358 0.54062E-13 -13.2671 0.46628E+00 -0.3314 12 K+ 0.21368E-03 -3.6702 0.17457E-03 -3.7580 0.81694E+00 -0.0878 13 Na+ 0.27131E-01 -1.5665 0.22110E-01 -1.6554 0.81494E+00 -0.0889 14 Mn++ 0.37819E-10 -10.4223 0.17653E-10 -10.7532 0.46679E+00 -0.3309 15 F- 0.87497E-06 -6.0580 0.71134E-06 -6.1479 0.81299E+00 -0.0899 16 HPO4-- 0.28698E-07 -7.5421 0.13575E-07 -7.8673 0.47302E+00 -0.3251 18 HSiO3- 0.80309E-02 -2.0952 0.65464E-02 -2.1840 0.81515E+00 -0.0888 19 Ca(HSiO3)+ 0.22440E-07 -7.6490 0.18337E-07 -7.7367 0.81717E+00 -0.0877 20 Mg(HSiO3)+ 0.44875E-11 -11.3480 0.36671E-11 -11.4357 0.81717E+00 -0.0877 21 NaHSiO3,aq 0.23410E-02 -2.6306 0.23410E-02 -2.6306 0.10000E+01 0.0000 22 AlO+ 0.90154E-16 -16.0450 0.73671E-16 -16.1327 0.81717E+00 -0.0877 24 HAlO2,aq 0.14657E-09 -9.8340 0.14657E-09 -9.8340 0.10000E+01 0.0000 25 AlO2- 0.39872E-05 -5.3993 0.32426E-05 -5.4891 0.81325E+00 -0.0898 26 CH4,aq 0.22577E-01 -1.6463 0.22577E-01 -1.6463 0.10000E+01 0.0000 27 C2H6,aq 0.82825E-08 -8.0818 0.82825E-08 -8.0818 0.10000E+01 0.0000 28 C3H8,aq 0.70150E-13 -13.1540 0.70150E-13 -13.1540 0.10000E+01 0.0000 29 C4H10,aq 0.58367E-18 -18.2338 0.58367E-18 -18.2338 0.10000E+01 0.0000 30 ethanol,aq 0.33453E-15 -15.4756 0.33453E-15 -15.4756 0.10000E+01 0.0000 31 CO,aq 0.22576E-13 -13.6464 0.22576E-13 -13.6464 0.10000E+01 0.0000 32 CO2,aq 0.85385E-07 -7.0686 0.85385E-07 -7.0686 0.10000E+01 0.0000 33 CO3-2 0.73891E-03 -3.1314 0.34849E-03 -3.4578 0.47163E+00 -0.3264 34 CaCO3,aq 0.53746E-06 -6.2697 0.53746E-06 -6.2697 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.15338E-08 -8.8142 0.12534E-08 -8.9019 0.81717E+00 -0.0877 36 CaCl+ 0.43759E-09 -9.3589 0.35758E-09 -9.4466 0.81717E+00 -0.0877 37 CaCl2,aq 0.15262E-12 -12.8164 0.15262E-12 -12.8164 0.10000E+01 0.0000 38 CaF+ 0.15632E-11 -11.8060 0.12774E-11 -11.8937 0.81717E+00 -0.0877 39 CaOH+ 0.10717E-06 -6.9699 0.87574E-07 -7.0576 0.81717E+00 -0.0877 40 CaSO4,aq 0.43964E-14 -14.3569 0.43964E-14 -14.3569 0.10000E+01 0.0000 41 HCl,aq 0.32938E-13 -13.4823 0.32938E-13 -13.4823 0.10000E+01 0.0000 45 HF,aq 0.48724E-12 -12.3123 0.48724E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.14355E-18 -18.8430 0.11702E-18 -18.9317 0.81515E+00 -0.0888 48 FeCl+ 0.18812E-15 -15.7256 0.15373E-15 -15.8133 0.81717E+00 -0.0877 51 FeF+ 0.24049E-17 -17.6189 0.19652E-17 -17.7066 0.81717E+00 -0.0877 53 FeO,aq 0.20979E-09 -9.6782 0.20979E-09 -9.6782 0.10000E+01 0.0000 54 FeOH+ 0.21514E-10 -10.6673 0.17581E-10 -10.7550 0.81717E+00 -0.0877 55 HFeO2- 0.26902E-07 -7.5702 0.21929E-07 -7.6590 0.81515E+00 -0.0888 56 FeO+ 0.15820E-16 -16.8008 0.12928E-16 -16.8885 0.81717E+00 -0.0877 58 FeO2- 0.32402E-09 -9.4894 0.26412E-09 -9.5782 0.81515E+00 -0.0888 59 HFeO2,aq 0.33612E-11 -11.4735 0.33612E-11 -11.4735 0.10000E+01 0.0000 60 H2,aq 0.10521E-04 -4.9779 0.10521E-04 -4.9779 0.10000E+01 0.0000 61 KCl,aq 0.56838E-08 -8.2454 0.56838E-08 -8.2454 0.10000E+01 0.0000 63 KOH,aq 0.74477E-06 -6.1280 0.74477E-06 -6.1280 0.10000E+01 0.0000 64 KSO4- 0.37406E-12 -12.4271 0.30491E-12 -12.5158 0.81515E+00 -0.0888 65 MgCO3,aq 0.21648E-10 -10.6646 0.21648E-10 -10.6646 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.25184E-12 -12.5989 0.20580E-12 -12.6866 0.81717E+00 -0.0877 67 MgCl+ 0.63730E-13 -13.1957 0.52078E-13 -13.2833 0.81717E+00 -0.0877 68 MgF+ 0.93049E-15 -15.0313 0.76037E-15 -15.1190 0.81717E+00 -0.0877 69 MgOH+ 0.95291E-10 -10.0209 0.77869E-10 -10.1086 0.81717E+00 -0.0877 71 MnF+ 0.25884E-15 -15.5870 0.21151E-15 -15.6747 0.81717E+00 -0.0877 72 MnO,aq 0.18253E-08 -8.7387 0.18253E-08 -8.7387 0.10000E+01 0.0000 73 MnOH+ 0.65261E-09 -9.1853 0.53329E-09 -9.2730 0.81717E+00 -0.0877 74 MnO2-2 0.12824E-10 -10.8920 0.60484E-11 -11.2184 0.47163E+00 -0.3264 75 HMnO2- 0.16265E-09 -9.7887 0.13259E-09 -9.8775 0.81515E+00 -0.0888 78 MnCl+ 0.23898E-12 -12.6216 0.19529E-12 -12.7093 0.81717E+00 -0.0877 79 MnSO4,aq 0.57365E-18 -18.2413 0.57365E-18 -18.2413 0.10000E+01 0.0000 80 NaCl,aq 0.13163E-04 -4.8806 0.13163E-04 -4.8806 0.10000E+01 0.0000 81 NaF,aq 0.36821E-08 -8.4339 0.36821E-08 -8.4339 0.10000E+01 0.0000 82 NaOH,aq 0.94902E-04 -4.0227 0.94902E-04 -4.0227 0.10000E+01 0.0000 84 OH- 0.70975E-02 -2.1489 0.57721E-02 -2.2387 0.81325E+00 -0.0898 89 HPO3-2 0.94409E-15 -15.0250 0.44526E-15 -15.3514 0.47163E+00 -0.3264 91 H2PO3- 0.10960E-18 -18.9602 0.89339E-19 -19.0490 0.81515E+00 -0.0888 92 H3PO4,aq 0.95050E-18 -18.0220 0.95050E-18 -18.0220 0.10000E+01 0.0000 93 H2PO4- 0.30700E-10 -10.5129 0.25056E-10 -10.6011 0.81615E+00 -0.0882 94 PO4-3 0.55684E-09 -9.2543 0.11069E-09 -9.9559 0.19879E+00 -0.7016 98 HP2O7-3 0.52613E-18 -18.2789 0.98278E-19 -19.0075 0.18679E+00 -0.7286 99 P2O7-4 0.44113E-17 -17.3554 0.23465E-18 -18.6296 0.53192E-01 -1.2742 100 H2S,aq 0.20274E-05 -5.6931 0.20274E-05 -5.6931 0.10000E+01 0.0000 101 S2-2 0.19194E-09 -9.7168 0.90524E-10 -10.0432 0.47163E+00 -0.3264 102 S3-2 0.49831E-16 -16.3025 0.23502E-16 -16.6289 0.47163E+00 -0.3264 107 SO3-2 0.32042E-15 -15.4943 0.15396E-15 -15.8126 0.48048E+00 -0.3183 108 HSO3- 0.11832E-17 -17.9269 0.96451E-18 -18.0157 0.81515E+00 -0.0888 109 HSO4- 0.13265E-16 -16.8773 0.10854E-16 -16.9644 0.81821E+00 -0.0871 111 S2O3-2 0.56863E-17 -17.2452 0.26818E-17 -17.5716 0.47163E+00 -0.3264 Charge balance for all species = -.1737E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1217913E-09 -.1832116E-01 -.1842137E+02 0.0000 2 H2O 0.1000000E+01 0.5552767E+02 0.9978959E+06 0.0000 3 Cl- 0.2203840E-02 0.2217009E-02 0.7840698E+02 7.2542 4 SO4-- 0.2380092E-09 -.2257972E-01 -.2163728E+04 10.0509 5 HCO3- 0.4888061E-03 0.2380544E-01 0.1448981E+04 6.6009 6 HS- 0.8041311E-02 0.3062306E-01 0.1010284E+04 7.8164 7 Al+++ 0.2907873E-28 0.3987347E-05 0.1073209E+00 0.7335 8 H4SiO4 0.7012069E-03 0.1107308E-01 0.1061685E+04 -3.1542 9 Ca++ 0.2625906E-06 0.9316345E-06 0.3724654E-01 13.0894 10 Mg++ 0.4244751E-10 0.1641906E-09 0.3982019E-05 9.2954 11 Fe++ 0.1159430E-12 0.2746067E-07 0.1529838E-02 6.7324 12 K+ 0.2136836E-03 0.2144341E-03 0.8364252E+01 6.2417 13 Na+ 0.2713079E-01 0.2957984E-01 0.6783679E+03 8.3443 14 Mn++ 0.3781894E-10 0.2691487E-08 0.1475025E-03 9.2463 15 F- 0.8749695E-06 0.8786537E-06 0.1665175E-01 3.8518 16 HPO4-- 0.2869834E-07 0.2928587E-07 0.2803940E-02 12.1322 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277489E+02 -.9135049E-02 -.8276575E+02 0.0000000E+00 2 H2O -.7034530E+01 0.2768646E+02 -.3472099E+02 0.0000000E+00 3 Cl- 0.1105415E-02 0.1105415E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1393756E+00 -.1125840E-01 0.1506340E+00 0.0000000E+00 5 HCO3- 0.1186955E-01 0.1186955E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1353651E+00 0.1526886E-01 -.1506340E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1988118E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5521110E-02 0.5205838E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.4645191E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.8186651E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1369207E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1069182E-03 0.1061464E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1474870E-01 0.6261628E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1341993E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6569600E-04 0.4381025E-06 0.6525790E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1460213E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1685E-13 Mass of aqueous solution: 0.499832E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1639900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.8 andradite 0.6025 -0.220 306.2 2.486 5.605 79.55 grossular 0.1381 -0.860 62.23 1.794 1.139 17.31 apatite-OH 0.9797E-02 -2.009 4.921 0.692 0.9008E-01 1.564 apatite-F 0.6526E-04 -4.185 0.3291E-01 -1.483 0.6024E-03 0.1028E-01 clinochlore 0.7045 -0.152 391.6 2.593 7.168 148.9 daphnite 0.2022 -0.694 144.3 2.159 2.641 43.72 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9419 -0.026 262.2 2.419 4.799 102.4 stilbite 3.233 0.510 2279. 3.358 41.71 1063. stilpnomelane-Fe 0.2391 -0.621 257.7 2.411 4.717 89.02 tr.625ac.25prg.125 0.1230 -0.910 105.1 2.022 1.924 33.83 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8135E+00 0.8135E+00 1.0000 -0.090 grossular 0.1865E+00 0.1865E+00 1.0000 -0.729 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7624E+00 0.7624E+00 1.0000 -0.118 daphnite 0.2188E+00 0.2188E+00 1.0000 -0.660 chlorite-Mn 0.1876E-01 0.1876E-01 1.0000 -1.727 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5463.083964 g Volume = 2211.850218 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1639900 moles log = -0.7852 Original solution: 1000.0103000 g Original solution / Rock added: 6098.00 (Water/Rock Ratio), log = 3.7852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 35.0141 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3073E-01 0.9346 0.1006E+01 0.1076E+01 CO2,gas 0.2772E-06 0.9413 0.9135E-05 0.9705E-05 CH4,gas 0.9689E+00 0.9796 0.3323E+02 0.3392E+02 H2,gas 0.3872E-03 1.0188 0.1381E-01 0.1356E-01 H2S,gas 0.1818E-05 0.8758 0.5573E-04 0.6364E-04 S2,gas 0.1745E-25 1.0000 0.6111E-24 0.6111E-24 CO,gas 0.9608E-12 1.0000 0.3364E-10 0.3364E-10 SO3,gas 0.1217E-46 1.0000 0.4263E-45 0.4263E-45 SO2,gas 0.6545E-26 1.0000 0.2292E-24 0.2292E-24 HF,gas 0.3417E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1660E-17 1.0000 0.5812E-16 0.5812E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 117 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 164 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.40 -6.74 -2.246 0.11505E+05 -5.039 3 CH4,gas 4.54 4.37 -0.18 -0.044 0.30293E+03 1.522 4 H2,gas 8.00 4.44 -3.56 -2.034 0.60764E+04 -1.860 5 H2S,gas -6.23 -12.18 -5.95 -2.976 0.10164E+05 -4.254 6 S2,gas -7.34 -33.25 -25.91 -3.987 0.44246E+05 -24.214 7 CO,gas 3.21 -8.96 -12.17 -3.745 0.20783E+05 -10.473 8 SO3,gas 17.12 -29.95 -47.07 -11.767 0.80370E+05 -45.370 9 SO2,gas 0.83 -25.51 -26.34 -7.024 0.44973E+05 -24.640 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.75 -17.93 -8.967 0.30623E+05 -16.236 12 acmite 7.71 6.55 -1.16 -0.121 0.19832E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.71 -0.236 0.80485E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94270E+03 26 ankerite -2.14 -6.98 -4.84 -0.807 0.82646E+04 27 annite 20.12 17.71 -2.41 -0.134 0.41208E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28440E+04 30 anorthite 12.71 8.25 -4.46 -0.343 0.76190E+04 38 aragonite 0.97 -0.31 -1.28 -0.425 0.21782E+04 39 brucite 12.57 9.30 -3.27 -0.655 0.55895E+04 40 calcite 0.81 -0.31 -1.12 -0.374 0.19140E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52924E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71194E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70489E+04 44 carpholite-Fe 6.71 1.89 -4.82 -0.321 0.82331E+04 45 celadonite 5.34 3.65 -1.69 -0.099 0.28803E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47549E+04 47 chrysotile 23.89 21.58 -2.31 -0.193 0.39523E+04 52 chlorite-Al-free 47.17 43.16 -4.02 -0.167 0.68598E+04 54 chloritoid-Fe 9.17 5.04 -4.13 -0.275 0.70498E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65607E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13280E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10133E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36548E+04 69 diamond -3.10 -4.52 -1.41 -0.404 0.24135E+04 70 dolomite,ordered 0.55 -4.41 -4.96 -0.826 0.84668E+04 72 enstatite 17.26 12.28 -4.98 -0.498 0.85068E+04 74 clinoenstatite 17.17 12.28 -4.88 -0.488 0.83384E+04 76 epidote 24.67 22.70 -1.97 -0.096 0.33719E+04 77 clinozoisite 22.81 18.92 -3.89 -0.177 0.66407E+04 78 epidote-Fe 29.84 26.47 -3.37 -0.175 0.57497E+04 79 fayalite 14.05 10.31 -3.74 -0.534 0.63776E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68173E+04 84 gibbsite 4.08 0.73 -3.35 -0.478 0.57137E+04 85 glaucophane 22.97 20.81 -2.16 -0.059 0.36961E+04 86 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70940E+04 87 graphite -3.55 -4.52 -0.97 -0.277 0.16557E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38432E+04 91 hematite 12.57 9.02 -3.54 -0.429 0.60496E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.45 -0.145 0.24679E+04 98 kalsilite 7.58 3.82 -3.76 -0.538 0.64249E+04 99 kaolinite -1.33 -4.84 -3.51 -0.319 0.59909E+04 102 laumontite 2.88 1.94 -0.94 -0.063 0.16111E+04 103 lawsonite 9.62 8.25 -1.37 -0.091 0.23362E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58934E+04 106 lizardite 23.24 21.58 -1.67 -0.139 0.28449E+04 107 magnesite 0.69 -4.10 -4.79 -1.598 0.81852E+04 108 magnetite 20.09 15.76 -4.33 -0.354 0.73967E+04 109 minnesotaite 10.39 7.58 -2.81 -0.165 0.47926E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82163E+04 121 muscovite 2.58 -1.02 -3.60 -0.212 0.61512E+04 122 paragonite 4.24 1.08 -3.16 -0.186 0.53903E+04 123 nepheline 8.34 5.92 -2.42 -0.345 0.41248E+04 129 periclase-Fe 11.63 6.73 -4.89 -1.224 0.83570E+04 135 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36628E+04 137 prehnite 19.37 18.18 -1.19 -0.070 0.20292E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91541E+03 139 pumpellyite-Fe 46.27 43.83 -2.44 -0.054 0.41617E+04 140 pumpellyite-Mg 48.99 46.40 -2.60 -0.058 0.44391E+04 143 pyrite -21.25 -22.07 -0.83 -0.195 0.14137E+04 144 pyrrhotite -4.26 -5.45 -1.19 -0.397 0.20326E+04 145 pyrrhotiteFe0.875 -6.02 -6.84 -0.83 -0.304 0.14104E+04 146 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22305E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84913E+04 148 quartz -2.99 -3.15 -0.16 -0.055 0.28065E+03 152 rhodochrosite -0.98 -4.15 -3.18 -1.059 0.54228E+04 153 rhodonite 7.45 6.09 -1.35 -0.271 0.23108E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.67 -4.06 -1.353 0.69289E+04 166 stilpnomelane-Mg 27.44 25.83 -1.61 -0.048 0.27481E+04 172 talc 16.49 15.27 -1.22 -0.072 0.20845E+04 175 tephroite 18.09 15.34 -2.75 -0.392 0.46909E+04 179 tridymite -2.63 -3.15 -0.53 -0.176 0.90063E+03 180 tremolite 47.87 47.42 -0.45 -0.012 0.76040E+03 181 ferroactinolite 38.45 34.61 -3.84 -0.104 0.65625E+04 182 troilite-low -4.41 -5.45 -1.04 -0.347 0.17754E+04 184 vesuvianite 223.47 218.58 -4.89 -0.037 0.83468E+04 188 wairakite 3.95 1.94 -2.01 -0.118 0.34324E+04 189 walstromite 11.51 9.94 -1.57 -0.315 0.26872E+04 190 wollastonite 10.46 9.94 -0.53 -0.105 0.89766E+03 191 pseudo-wollastonite 11.00 9.94 -1.06 -0.213 0.18175E+04 192 zoisite 22.85 18.92 -3.93 -0.179 0.67148E+04 193 akaganeite 7.75 4.51 -3.24 -0.701 0.55375E+04 200 chalcedony -2.80 -3.15 -0.35 -0.117 0.59995E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66129E+04 203 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68759E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73588E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60308E+04 206 nontronite-Ca 3.21 -0.15 -3.36 -0.218 0.57444E+04 207 nontronite-H 2.53 -2.31 -4.84 -0.325 0.82679E+04 208 nontronite-K 3.34 -0.25 -3.59 -0.230 0.61305E+04 209 nontronite-Mg 3.07 -0.78 -3.85 -0.250 0.65744E+04 210 nontronite-Na 3.52 0.44 -3.08 -0.197 0.52514E+04 226 tobermorite 9.82 7.75 -2.07 -0.566 0.35409E+04 232 alabandite -0.98 -2.94 -1.96 -0.653 0.33448E+04 235 boehmite 4.41 0.73 -3.67 -0.612 0.62718E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52579E+04 243 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18141E+04 245 an20ab80 2.02 1.34 -0.68 -0.052 0.11529E+04 246 an25ab75 2.65 1.77 -0.87 -0.067 0.14882E+04 247 an30ab70 3.28 2.21 -1.07 -0.083 0.18330E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1639900 MOLES New total amount of reactant added: 0.1679900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1679900 Water: Moles liquid = 0.2768E+02 kg liquid = 0.4986E+00 Moles total = -.7031E+01 kg total = -.1267E+00 Activity = 0.9996 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2837268E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.1129E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12305E-09 -9.9099 0.10102E-09 -9.9956 0.82097E+00 -0.0857 2 H2O 0.99958E+00 -0.0002 0.99958E+00 -0.0002 3 Cl- 0.22509E-02 -2.6476 0.18334E-02 -2.7367 0.81452E+00 -0.0891 4 SO4-- 0.25533E-09 -9.5929 0.12039E-09 -9.9194 0.47153E+00 -0.3265 5 HCO3- 0.52257E-03 -3.2819 0.42646E-03 -3.3701 0.81608E+00 -0.0883 6 HS- 0.82366E-02 -2.0843 0.67102E-02 -2.1733 0.81468E+00 -0.0890 7 Al+++ 0.30073E-28 -28.5218 0.55711E-29 -29.2541 0.18525E+00 -0.7322 8 H4SiO4 0.70199E-03 -3.1537 0.70199E-03 -3.1537 0.10000E+01 0.0000 9 Ca++ 0.26740E-06 -6.5728 0.12487E-06 -6.9035 0.46698E+00 -0.3307 10 Mg++ 0.43418E-10 -10.3623 0.20154E-10 -10.6956 0.46418E+00 -0.3333 11 Fe++ 0.11844E-12 -12.9265 0.55058E-13 -13.2592 0.46485E+00 -0.3327 12 K+ 0.21558E-03 -3.6664 0.17598E-03 -3.7545 0.81633E+00 -0.0881 13 Na+ 0.27372E-01 -1.5627 0.22289E-01 -1.6519 0.81431E+00 -0.0892 14 Mn++ 0.38655E-10 -10.4128 0.17988E-10 -10.7450 0.46535E+00 -0.3322 15 F- 0.86731E-06 -6.0618 0.70456E-06 -6.1521 0.81235E+00 -0.0903 16 HPO4-- 0.28429E-07 -7.5462 0.13407E-07 -7.8727 0.47161E+00 -0.3264 18 HSiO3- 0.79694E-02 -2.0986 0.64913E-02 -2.1877 0.81452E+00 -0.0891 19 Ca(HSiO3)+ 0.22606E-07 -7.6458 0.18459E-07 -7.7338 0.81656E+00 -0.0880 20 Mg(HSiO3)+ 0.45409E-11 -11.3429 0.37079E-11 -11.4309 0.81656E+00 -0.0880 21 NaHSiO3,aq 0.23401E-02 -2.6308 0.23401E-02 -2.6308 0.10000E+01 0.0000 22 AlO+ 0.90917E-16 -16.0414 0.74239E-16 -16.1294 0.81656E+00 -0.0880 24 HAlO2,aq 0.14629E-09 -9.8348 0.14629E-09 -9.8348 0.10000E+01 0.0000 25 AlO2- 0.39448E-05 -5.4040 0.32056E-05 -5.4941 0.81261E+00 -0.0901 26 CH4,aq 0.23079E-01 -1.6368 0.23079E-01 -1.6368 0.10000E+01 0.0000 27 C2H6,aq 0.87719E-08 -8.0569 0.87719E-08 -8.0569 0.10000E+01 0.0000 28 C3H8,aq 0.76973E-13 -13.1137 0.76973E-13 -13.1137 0.10000E+01 0.0000 29 C4H10,aq 0.66352E-18 -18.1781 0.66352E-18 -18.1781 0.10000E+01 0.0000 30 ethanol,aq 0.35908E-15 -15.4448 0.35908E-15 -15.4448 0.10000E+01 0.0000 31 CO,aq 0.24025E-13 -13.6193 0.24025E-13 -13.6193 0.10000E+01 0.0000 32 CO2,aq 0.92092E-07 -7.0358 0.92092E-07 -7.0358 0.10000E+01 0.0000 33 CO3-2 0.78418E-03 -3.1056 0.36874E-03 -3.4333 0.47022E+00 -0.3277 34 CaCO3,aq 0.57734E-06 -6.2386 0.57734E-06 -6.2386 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.16647E-08 -8.7787 0.13593E-08 -8.8667 0.81656E+00 -0.0880 36 CaCl+ 0.45372E-09 -9.3432 0.37049E-09 -9.4312 0.81656E+00 -0.0880 37 CaCl2,aq 0.16138E-12 -12.7922 0.16138E-12 -12.7922 0.10000E+01 0.0000 38 CaF+ 0.15730E-11 -11.8033 0.12845E-11 -11.8913 0.81656E+00 -0.0880 39 CaOH+ 0.10784E-06 -6.9672 0.88059E-07 -7.0552 0.81656E+00 -0.0880 40 CaSO4,aq 0.47738E-14 -14.3211 0.47738E-14 -14.3211 0.10000E+01 0.0000 41 HCl,aq 0.33939E-13 -13.4693 0.33939E-13 -13.4693 0.10000E+01 0.0000 45 HF,aq 0.48724E-12 -12.3123 0.48724E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.14229E-18 -18.8468 0.11590E-18 -18.9359 0.81452E+00 -0.0891 48 FeCl+ 0.19567E-15 -15.7085 0.15978E-15 -15.7965 0.81656E+00 -0.0880 51 FeF+ 0.24277E-17 -17.6148 0.19823E-17 -17.7028 0.81656E+00 -0.0880 53 FeO,aq 0.20960E-09 -9.6786 0.20960E-09 -9.6786 0.10000E+01 0.0000 54 FeOH+ 0.21718E-10 -10.6632 0.17734E-10 -10.7512 0.81656E+00 -0.0880 55 HFeO2- 0.26642E-07 -7.5744 0.21701E-07 -7.6635 0.81452E+00 -0.0891 56 FeO+ 0.16078E-16 -16.7938 0.13128E-16 -16.8818 0.81656E+00 -0.0880 58 FeO2- 0.32305E-09 -9.4907 0.26313E-09 -9.5798 0.81452E+00 -0.0891 59 HFeO2,aq 0.33807E-11 -11.4710 0.33807E-11 -11.4710 0.10000E+01 0.0000 60 H2,aq 0.10381E-04 -4.9838 0.10381E-04 -4.9838 0.10000E+01 0.0000 61 KCl,aq 0.58478E-08 -8.2330 0.58478E-08 -8.2330 0.10000E+01 0.0000 63 KOH,aq 0.74365E-06 -6.1286 0.74365E-06 -6.1286 0.10000E+01 0.0000 64 KSO4- 0.40364E-12 -12.3940 0.32877E-12 -12.4831 0.81452E+00 -0.0891 65 MgCO3,aq 0.23357E-10 -10.6316 0.23357E-10 -10.6316 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.27454E-12 -12.5614 0.22418E-12 -12.6494 0.81656E+00 -0.0880 67 MgCl+ 0.66374E-13 -13.1780 0.54198E-13 -13.2660 0.81656E+00 -0.0880 68 MgF+ 0.94050E-15 -15.0266 0.76797E-15 -15.1147 0.81656E+00 -0.0880 69 MgOH+ 0.96315E-10 -10.0163 0.78647E-10 -10.1043 0.81656E+00 -0.0880 71 MnF+ 0.26143E-15 -15.5827 0.21347E-15 -15.6707 0.81656E+00 -0.0880 72 MnO,aq 0.18247E-08 -8.7388 0.18247E-08 -8.7388 0.10000E+01 0.0000 73 MnOH+ 0.65914E-09 -9.1810 0.53822E-09 -9.2690 0.81656E+00 -0.0880 74 MnO2-2 0.12614E-10 -10.8991 0.59316E-11 -11.2268 0.47022E+00 -0.3277 75 HMnO2- 0.16117E-09 -9.7927 0.13128E-09 -9.8818 0.81452E+00 -0.0891 78 MnCl+ 0.24871E-12 -12.6043 0.20309E-12 -12.6923 0.81656E+00 -0.0880 79 MnSO4,aq 0.62520E-18 -18.2040 0.62520E-18 -18.2040 0.10000E+01 0.0000 80 NaCl,aq 0.13543E-04 -4.8683 0.13543E-04 -4.8683 0.10000E+01 0.0000 81 NaF,aq 0.36766E-08 -8.4345 0.36766E-08 -8.4345 0.10000E+01 0.0000 82 NaOH,aq 0.94760E-04 -4.0234 0.94760E-04 -4.0234 0.10000E+01 0.0000 84 OH- 0.70354E-02 -2.1527 0.57171E-02 -2.2428 0.81261E+00 -0.0901 89 HPO3-2 0.92280E-15 -15.0349 0.43392E-15 -15.3626 0.47022E+00 -0.3277 91 H2PO3- 0.10792E-18 -18.9669 0.87901E-19 -19.0560 0.81452E+00 -0.0891 92 H3PO4,aq 0.95693E-18 -18.0191 0.95693E-18 -18.0191 0.10000E+01 0.0000 93 H2PO4- 0.30637E-10 -10.5138 0.24985E-10 -10.6023 0.81553E+00 -0.0886 94 PO4-3 0.54819E-09 -9.2611 0.10829E-09 -9.9654 0.19754E+00 -0.7044 98 HP2O7-3 0.52171E-18 -18.2826 0.96793E-19 -19.0142 0.18553E+00 -0.7316 99 P2O7-4 0.43543E-17 -17.3611 0.22890E-18 -18.6404 0.52569E-01 -1.2793 100 H2S,aq 0.20950E-05 -5.6788 0.20950E-05 -5.6788 0.10000E+01 0.0000 101 S2-2 0.20439E-09 -9.6895 0.96110E-10 -10.0172 0.47022E+00 -0.3277 102 S3-2 0.55574E-16 -16.2551 0.26132E-16 -16.5828 0.47022E+00 -0.3277 107 SO3-2 0.33912E-15 -15.4696 0.16248E-15 -15.7892 0.47912E+00 -0.3196 108 HSO3- 0.12617E-17 -17.8990 0.10277E-17 -17.9881 0.81452E+00 -0.0891 109 HSO4- 0.14335E-16 -16.8436 0.11721E-16 -16.9310 0.81761E+00 -0.0875 111 S2O3-2 0.63036E-17 -17.2004 0.29641E-17 -17.5281 0.47022E+00 -0.3277 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1230490E-09 -.1824160E-01 -.1834100E+02 0.0000 2 H2O 0.1000000E+01 0.5552817E+02 0.9978842E+06 0.0000 3 Cl- 0.2250914E-02 0.2264463E-02 0.8008360E+02 7.2589 4 SO4-- 0.2553257E-09 -.2308194E-01 -.2211808E+04 10.0718 5 HCO3- 0.5225691E-03 0.2438677E-01 0.1484335E+04 6.6255 6 HS- 0.8236632E-02 0.3132067E-01 0.1033277E+04 7.8223 7 Al+++ 0.3007331E-28 0.3944996E-05 0.1061788E+00 0.7327 8 H4SiO4 0.7019854E-03 0.1101154E-01 0.1055763E+04 -3.1537 9 Ca++ 0.2673978E-06 0.9773039E-06 0.3907158E-01 13.0876 10 Mg++ 0.4341828E-10 0.1679734E-09 0.4073677E-05 9.2956 11 Fe++ 0.1184434E-12 0.2720015E-07 0.1515293E-02 6.7320 12 K+ 0.2155789E-03 0.2163284E-03 0.8437968E+01 6.2411 13 Na+ 0.2737196E-01 0.2982037E-01 0.6838701E+03 8.3437 14 Mn++ 0.3865450E-10 0.2696504E-08 0.1477744E-03 9.2462 15 F- 0.8673127E-06 0.8709914E-06 0.1650620E-01 3.8435 16 HPO4-- 0.2842891E-07 0.2900774E-07 0.2777253E-02 12.1185 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277446E+02 -.9094890E-02 -.8276536E+02 0.0000000E+00 2 H2O -.7031255E+01 0.2768521E+02 -.3471647E+02 0.0000000E+00 3 Cl- 0.1129015E-02 0.1129015E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1393947E+00 -.1150819E-01 0.1509029E+00 0.0000000E+00 5 HCO3- 0.1215875E-01 0.1215875E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1352870E+00 0.1561585E-01 -.1509029E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1966894E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5490130E-02 0.5205841E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.4872637E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.8374812E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1356144E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1078569E-03 0.1061463E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1486783E-01 0.6261509E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1344422E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6729600E-04 0.4342585E-06 0.6686174E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1446267E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1835E-13 Mass of aqueous solution: 0.499815E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1679900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.7 andradite 0.6036 -0.219 306.7 2.487 5.615 79.69 grossular 0.1373 -0.862 61.86 1.791 1.132 17.21 apatite-OH 0.9796E-02 -2.009 4.921 0.692 0.9007E-01 1.564 apatite-F 0.6686E-04 -4.175 0.3372E-01 -1.472 0.6172E-03 0.1053E-01 clinochlore 0.7050 -0.152 391.9 2.593 7.173 149.1 daphnite 0.2021 -0.694 144.2 2.159 2.639 43.69 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9420 -0.026 262.2 2.419 4.799 102.4 stilbite 3.234 0.510 2279. 3.358 41.72 1063. stilpnomelane-Fe 0.2389 -0.622 257.6 2.411 4.714 88.97 tr.625ac.25prg.125 0.1222 -0.913 104.5 2.019 1.913 33.63 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8147E+00 0.8147E+00 1.0000 -0.089 grossular 0.1853E+00 0.1853E+00 1.0000 -0.732 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7626E+00 0.7626E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1876E-01 0.1876E-01 1.0000 -1.727 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5463.183021 g Volume = 2211.946867 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1679900 moles log = -0.7747 Original solution: 1000.0103000 g Original solution / Rock added: 5952.80 (Water/Rock Ratio), log = 3.7747 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 35.7851 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.3009E-01 0.9337 0.1006E+01 0.1077E+01 CO2,gas 0.2929E-06 0.9401 0.9853E-05 0.1048E-04 CH4,gas 0.9695E+00 0.9791 0.3397E+02 0.3469E+02 H2,gas 0.3737E-03 1.0193 0.1363E-01 0.1337E-01 H2S,gas 0.1843E-05 0.8733 0.5759E-04 0.6595E-04 S2,gas 0.1873E-25 1.0000 0.6702E-24 0.6702E-24 CO,gas 0.1000E-11 1.0000 0.3580E-10 0.3580E-10 SO3,gas 0.1299E-46 1.0000 0.4647E-45 0.4647E-45 SO2,gas 0.6889E-26 1.0000 0.2465E-24 0.2465E-24 HF,gas 0.3343E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1674E-17 1.0000 0.5989E-16 0.5989E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 117 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 164 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28968E+04 0.002 2 CO2,gas -6.66 -13.37 -6.71 -2.235 0.11449E+05 -5.006 3 CH4,gas 4.54 4.38 -0.17 -0.042 0.28661E+03 1.531 4 H2,gas 8.00 4.44 -3.56 -2.037 0.60863E+04 -1.866 5 H2S,gas -6.23 -12.17 -5.94 -2.969 0.10140E+05 -4.240 6 S2,gas -7.34 -33.21 -25.87 -3.980 0.44177E+05 -24.174 7 CO,gas 3.21 -8.93 -12.15 -3.737 0.20737E+05 -10.446 8 SO3,gas 17.12 -29.91 -47.03 -11.758 0.80305E+05 -45.333 9 SO2,gas 0.83 -25.47 -26.31 -7.015 0.44919E+05 -24.608 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.73 -17.92 -8.961 0.30601E+05 -16.223 12 acmite 7.71 6.55 -1.16 -0.120 0.19783E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.71 -0.236 0.80496E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94355E+03 26 ankerite -2.14 -6.91 -4.78 -0.796 0.81561E+04 27 annite 20.12 17.71 -2.41 -0.134 0.41228E+04 28 phlogopite 27.06 25.40 -1.67 -0.093 0.28432E+04 30 anorthite 12.71 8.25 -4.46 -0.343 0.76231E+04 38 aragonite 0.97 -0.28 -1.24 -0.415 0.21251E+04 39 brucite 12.57 9.30 -3.27 -0.655 0.55892E+04 40 calcite 0.81 -0.28 -1.09 -0.363 0.18609E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52941E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71211E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70498E+04 44 carpholite-Fe 6.71 1.89 -4.82 -0.322 0.82349E+04 45 celadonite 5.34 3.66 -1.69 -0.099 0.28792E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47548E+04 47 chrysotile 23.89 21.58 -2.31 -0.193 0.39498E+04 52 chlorite-Al-free 47.17 43.16 -4.01 -0.167 0.68548E+04 54 chloritoid-Fe 9.17 5.04 -4.13 -0.275 0.70525E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65629E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13271E+04 64 cristobalite -2.56 -3.15 -0.59 -0.198 0.10125E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36563E+04 69 diamond -3.10 -4.49 -1.39 -0.398 0.23773E+04 70 dolomite,ordered 0.55 -4.35 -4.89 -0.816 0.83574E+04 72 enstatite 17.26 12.28 -4.98 -0.498 0.85045E+04 74 clinoenstatite 17.17 12.28 -4.88 -0.488 0.83361E+04 76 epidote 24.67 22.69 -1.98 -0.096 0.33739E+04 77 clinozoisite 22.81 18.91 -3.89 -0.177 0.66485E+04 78 epidote-Fe 29.84 26.48 -3.37 -0.175 0.57460E+04 79 fayalite 14.05 10.31 -3.74 -0.534 0.63780E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68169E+04 84 gibbsite 4.08 0.73 -3.35 -0.478 0.57151E+04 85 glaucophane 22.97 20.81 -2.16 -0.058 0.36936E+04 86 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70943E+04 87 graphite -3.55 -4.49 -0.95 -0.271 0.16195E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38435E+04 91 hematite 12.57 9.03 -3.54 -0.429 0.60409E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.45 -0.145 0.24687E+04 98 kalsilite 7.58 3.82 -3.76 -0.538 0.64266E+04 99 kaolinite -1.33 -4.84 -3.51 -0.319 0.59920E+04 102 laumontite 2.88 1.94 -0.94 -0.063 0.16135E+04 103 lawsonite 9.62 8.25 -1.37 -0.091 0.23404E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58943E+04 106 lizardite 23.24 21.58 -1.66 -0.139 0.28424E+04 107 magnesite 0.69 -4.07 -4.76 -1.587 0.81289E+04 108 magnetite 20.09 15.76 -4.33 -0.353 0.73888E+04 109 minnesotaite 10.39 7.58 -2.81 -0.165 0.47912E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82166E+04 121 muscovite 2.58 -1.02 -3.60 -0.212 0.61540E+04 122 paragonite 4.24 1.08 -3.16 -0.186 0.53931E+04 123 nepheline 8.34 5.92 -2.42 -0.345 0.41265E+04 129 periclase-Fe 11.63 6.73 -4.89 -1.224 0.83576E+04 135 phlogopite-Na 29.65 27.50 -2.14 -0.119 0.36620E+04 137 prehnite 19.37 18.18 -1.19 -0.070 0.20355E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91600E+03 139 pumpellyite-Fe 46.27 43.82 -2.45 -0.054 0.41763E+04 140 pumpellyite-Mg 48.99 46.39 -2.61 -0.058 0.44528E+04 143 pyrite -21.25 -22.04 -0.79 -0.187 0.13558E+04 144 pyrrhotite -4.26 -5.44 -1.18 -0.392 0.20089E+04 145 pyrrhotiteFe0.875 -6.02 -6.83 -0.81 -0.298 0.13854E+04 146 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22300E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84908E+04 148 quartz -2.99 -3.15 -0.16 -0.055 0.27981E+03 152 rhodochrosite -0.98 -4.12 -3.14 -1.048 0.53670E+04 153 rhodonite 7.45 6.09 -1.35 -0.271 0.23102E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.63 -4.03 -1.342 0.68735E+04 166 stilpnomelane-Mg 27.44 25.83 -1.61 -0.048 0.27435E+04 172 talc 16.49 15.27 -1.22 -0.072 0.20803E+04 175 tephroite 18.09 15.34 -2.75 -0.392 0.46906E+04 179 tridymite -2.63 -3.15 -0.53 -0.176 0.89979E+03 180 tremolite 47.87 47.43 -0.44 -0.012 0.75832E+03 181 ferroactinolite 38.45 34.61 -3.84 -0.104 0.65651E+04 182 troilite-low -4.41 -5.44 -1.03 -0.342 0.17517E+04 184 vesuvianite 223.47 218.55 -4.92 -0.038 0.84037E+04 188 wairakite 3.95 1.94 -2.01 -0.118 0.34349E+04 189 walstromite 11.51 9.93 -1.58 -0.315 0.26894E+04 190 wollastonite 10.46 9.93 -0.53 -0.105 0.89983E+03 191 pseudo-wollastonite 11.00 9.93 -1.07 -0.213 0.18197E+04 192 zoisite 22.85 18.91 -3.94 -0.179 0.67225E+04 193 akaganeite 7.75 4.51 -3.24 -0.701 0.55332E+04 200 chalcedony -2.80 -3.15 -0.35 -0.117 0.59911E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66123E+04 203 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68751E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73577E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60300E+04 206 nontronite-Ca 3.21 -0.14 -3.36 -0.218 0.57337E+04 207 nontronite-H 2.53 -2.30 -4.84 -0.324 0.82567E+04 208 nontronite-K 3.34 -0.24 -3.58 -0.230 0.61197E+04 209 nontronite-Mg 3.07 -0.77 -3.84 -0.249 0.65631E+04 210 nontronite-Na 3.52 0.45 -3.07 -0.197 0.52406E+04 226 tobermorite 9.82 7.75 -2.07 -0.566 0.35426E+04 232 alabandite -0.98 -2.92 -1.94 -0.648 0.33207E+04 235 boehmite 4.41 0.73 -3.67 -0.612 0.62732E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52586E+04 243 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18133E+04 245 an20ab80 2.02 1.34 -0.68 -0.052 0.11538E+04 246 an25ab75 2.65 1.77 -0.87 -0.067 0.14892E+04 247 an30ab70 3.28 2.21 -1.07 -0.083 0.18342E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1679900 MOLES New total amount of reactant added: 0.1719900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8664E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1719900 Water: Moles liquid = 0.2767E+02 kg liquid = 0.4986E+00 Moles total = -.7028E+01 kg total = -.1266E+00 Activity = 0.9996 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2866848E-01 Chg. balance for total moles = -.8664E-10 Max. difference allowed = 0.1153E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12433E-09 -9.9054 0.10200E-09 -9.9914 0.82038E+00 -0.0860 2 H2O 0.99958E+00 -0.0002 0.99958E+00 -0.0002 3 Cl- 0.22980E-02 -2.6387 0.18703E-02 -2.7281 0.81389E+00 -0.0894 4 SO4-- 0.27368E-09 -9.5628 0.12866E-09 -9.8906 0.47010E+00 -0.3278 5 HCO3- 0.55816E-03 -3.2532 0.45516E-03 -3.3418 0.81546E+00 -0.0886 6 HS- 0.84320E-02 -2.0741 0.68640E-02 -2.1634 0.81405E+00 -0.0894 7 Al+++ 0.31115E-28 -28.5070 0.57244E-29 -29.2423 0.18397E+00 -0.7352 8 H4SiO4 0.70276E-03 -3.1532 0.70276E-03 -3.1532 0.10000E+01 0.0000 9 Ca++ 0.27237E-06 -6.5648 0.12679E-06 -6.8969 0.46553E+00 -0.3321 10 Mg++ 0.44423E-10 -10.3524 0.20556E-10 -10.6871 0.46273E+00 -0.3347 11 Fe++ 0.12103E-12 -12.9171 0.56084E-13 -13.2512 0.46339E+00 -0.3341 12 K+ 0.21752E-03 -3.6625 0.17743E-03 -3.7510 0.81570E+00 -0.0885 13 Na+ 0.27619E-01 -1.5588 0.22473E-01 -1.6483 0.81368E+00 -0.0895 14 Mn++ 0.39519E-10 -10.4032 0.18333E-10 -10.7368 0.46390E+00 -0.3336 15 F- 0.85965E-06 -6.0657 0.69777E-06 -6.1563 0.81170E+00 -0.0906 16 HPO4-- 0.28157E-07 -7.5504 0.13239E-07 -7.8781 0.47019E+00 -0.3277 18 HSiO3- 0.79077E-02 -2.1019 0.64360E-02 -2.1914 0.81389E+00 -0.0894 19 Ca(HSiO3)+ 0.22777E-07 -7.6425 0.18585E-07 -7.7308 0.81594E+00 -0.0883 20 Mg(HSiO3)+ 0.45954E-11 -11.3377 0.37496E-11 -11.4260 0.81594E+00 -0.0883 21 NaHSiO3,aq 0.23393E-02 -2.6309 0.23393E-02 -2.6309 0.10000E+01 0.0000 22 AlO+ 0.91697E-16 -16.0376 0.74819E-16 -16.1260 0.81594E+00 -0.0883 24 HAlO2,aq 0.14602E-09 -9.8356 0.14602E-09 -9.8356 0.10000E+01 0.0000 25 AlO2- 0.39026E-05 -5.4086 0.31688E-05 -5.4991 0.81196E+00 -0.0905 26 CH4,aq 0.23578E-01 -1.6275 0.23578E-01 -1.6275 0.10000E+01 0.0000 27 C2H6,aq 0.92781E-08 -8.0325 0.92781E-08 -8.0325 0.10000E+01 0.0000 28 C3H8,aq 0.84292E-13 -13.0742 0.84292E-13 -13.0742 0.10000E+01 0.0000 29 C4H10,aq 0.75230E-18 -18.1236 0.75230E-18 -18.1236 0.10000E+01 0.0000 30 ethanol,aq 0.38491E-15 -15.4146 0.38491E-15 -15.4146 0.10000E+01 0.0000 31 CO,aq 0.25548E-13 -13.5926 0.25548E-13 -13.5926 0.10000E+01 0.0000 32 CO2,aq 0.99245E-07 -7.0033 0.99245E-07 -7.0033 0.10000E+01 0.0000 33 CO3-2 0.83143E-03 -3.0802 0.38976E-03 -3.4092 0.46879E+00 -0.3290 34 CaCO3,aq 0.61967E-06 -6.2078 0.61967E-06 -6.2078 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.18055E-08 -8.7434 0.14731E-08 -8.8318 0.81594E+00 -0.0883 36 CaCl+ 0.47035E-09 -9.3276 0.38377E-09 -9.4159 0.81594E+00 -0.0883 37 CaCl2,aq 0.17053E-12 -12.7682 0.17053E-12 -12.7682 0.10000E+01 0.0000 38 CaF+ 0.15831E-11 -11.8005 0.12917E-11 -11.8888 0.81594E+00 -0.0883 39 CaOH+ 0.10853E-06 -6.9644 0.88556E-07 -7.0528 0.81594E+00 -0.0883 40 CaSO4,aq 0.51802E-14 -14.2857 0.51802E-14 -14.2857 0.10000E+01 0.0000 41 HCl,aq 0.34958E-13 -13.4565 0.34958E-13 -13.4565 0.10000E+01 0.0000 45 HF,aq 0.48723E-12 -12.3123 0.48723E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.14103E-18 -18.8507 0.11478E-18 -18.9401 0.81389E+00 -0.0894 48 FeCl+ 0.20349E-15 -15.6915 0.16603E-15 -15.7798 0.81594E+00 -0.0883 51 FeF+ 0.24509E-17 -17.6107 0.19998E-17 -17.6990 0.81594E+00 -0.0883 53 FeO,aq 0.20942E-09 -9.6790 0.20942E-09 -9.6790 0.10000E+01 0.0000 54 FeOH+ 0.21926E-10 -10.6590 0.17890E-10 -10.7474 0.81594E+00 -0.0883 55 HFeO2- 0.26383E-07 -7.5787 0.21473E-07 -7.6681 0.81389E+00 -0.0894 56 FeO+ 0.16341E-16 -16.7867 0.13333E-16 -16.8751 0.81594E+00 -0.0883 58 FeO2- 0.32205E-09 -9.4921 0.26211E-09 -9.5815 0.81389E+00 -0.0894 59 HFeO2,aq 0.34003E-11 -11.4685 0.34003E-11 -11.4685 0.10000E+01 0.0000 60 H2,aq 0.10243E-04 -4.9896 0.10243E-04 -4.9896 0.10000E+01 0.0000 61 KCl,aq 0.60145E-08 -8.2208 0.60145E-08 -8.2208 0.10000E+01 0.0000 63 KOH,aq 0.74254E-06 -6.1293 0.74254E-06 -6.1293 0.10000E+01 0.0000 64 KSO4- 0.43524E-12 -12.3613 0.35423E-12 -12.4507 0.81389E+00 -0.0894 65 MgCO3,aq 0.25181E-10 -10.5989 0.25181E-10 -10.5989 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.29908E-12 -12.5242 0.24403E-12 -12.6126 0.81594E+00 -0.0883 67 MgCl+ 0.69110E-13 -13.1605 0.56389E-13 -13.2488 0.81594E+00 -0.0883 68 MgF+ 0.95072E-15 -15.0219 0.77572E-15 -15.1103 0.81594E+00 -0.0883 69 MgOH+ 0.97362E-10 -10.0116 0.79441E-10 -10.1000 0.81594E+00 -0.0883 71 MnF+ 0.26407E-15 -15.5783 0.21547E-15 -15.6666 0.81594E+00 -0.0883 72 MnO,aq 0.18240E-08 -8.7390 0.18240E-08 -8.7390 0.10000E+01 0.0000 73 MnOH+ 0.66581E-09 -9.1766 0.54326E-09 -9.2650 0.81594E+00 -0.0883 74 MnO2-2 0.12406E-10 -10.9064 0.58158E-11 -11.2354 0.46879E+00 -0.3290 75 HMnO2- 0.15968E-09 -9.7967 0.12996E-09 -9.8862 0.81389E+00 -0.0894 78 MnCl+ 0.25877E-12 -12.5871 0.21114E-12 -12.6754 0.81594E+00 -0.0883 79 MnSO4,aq 0.68094E-18 -18.1669 0.68094E-18 -18.1669 0.10000E+01 0.0000 80 NaCl,aq 0.13929E-04 -4.8561 0.13929E-04 -4.8561 0.10000E+01 0.0000 81 NaF,aq 0.36712E-08 -8.4352 0.36712E-08 -8.4352 0.10000E+01 0.0000 82 NaOH,aq 0.94619E-04 -4.0240 0.94619E-04 -4.0240 0.10000E+01 0.0000 84 OH- 0.69732E-02 -2.1566 0.56620E-02 -2.2470 0.81196E+00 -0.0905 89 HPO3-2 0.90188E-15 -15.0448 0.42279E-15 -15.3739 0.46879E+00 -0.3290 91 H2PO3- 0.10625E-18 -18.9737 0.86479E-19 -19.0631 0.81389E+00 -0.0894 92 H3PO4,aq 0.96338E-18 -18.0162 0.96338E-18 -18.0162 0.10000E+01 0.0000 93 H2PO4- 0.30570E-10 -10.5147 0.24912E-10 -10.6036 0.81491E+00 -0.0889 94 PO4-3 0.53956E-09 -9.2680 0.10590E-09 -9.9751 0.19627E+00 -0.7071 98 HP2O7-3 0.51723E-18 -18.2863 0.95299E-19 -19.0209 0.18425E+00 -0.7346 99 P2O7-4 0.42972E-17 -17.3668 0.22320E-18 -18.6513 0.51941E-01 -1.2845 100 H2S,aq 0.21638E-05 -5.6648 0.21638E-05 -5.6648 0.10000E+01 0.0000 101 S2-2 0.21741E-09 -9.6627 0.10192E-09 -9.9917 0.46879E+00 -0.3290 102 S3-2 0.61876E-16 -16.2085 0.29007E-16 -16.5375 0.46879E+00 -0.3290 107 SO3-2 0.35863E-15 -15.4453 0.17133E-15 -15.7662 0.47773E+00 -0.3208 108 HSO3- 0.13444E-17 -17.8715 0.10942E-17 -17.9609 0.81389E+00 -0.0894 109 HSO4- 0.15480E-16 -16.8102 0.12647E-16 -16.8980 0.81700E+00 -0.0878 111 S2O3-2 0.69790E-17 -17.1562 0.32717E-17 -17.4852 0.46879E+00 -0.3290 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1243341E-09 -.1816371E-01 -.1826230E+02 0.0000 2 H2O 0.1000000E+01 0.5552867E+02 0.9978722E+06 0.0000 3 Cl- 0.2297986E-02 0.2311921E-02 0.8176025E+02 7.2633 4 SO4-- 0.2736830E-09 -.2358040E-01 -.2259525E+04 10.0922 5 HCO3- 0.5581616E-03 0.2496816E-01 0.1519690E+04 6.6496 6 HS- 0.8431968E-02 0.3201454E-01 0.1056146E+04 7.8280 7 Al+++ 0.3111543E-28 0.3902759E-05 0.1050398E+00 0.7319 8 H4SiO4 0.7027636E-03 0.1094976E-01 0.1049818E+04 -3.1532 9 Ca++ 0.2723658E-06 0.1025626E-05 0.4100258E-01 13.0859 10 Mg++ 0.4442285E-10 0.1719302E-09 0.4169549E-05 9.2957 11 Fe++ 0.1210296E-12 0.2693981E-07 0.1500758E-02 6.7316 12 K+ 0.2175168E-03 0.2182654E-03 0.8513340E+01 6.2404 13 Na+ 0.2761855E-01 0.3006635E-01 0.6894966E+03 8.3430 14 Mn++ 0.3951901E-10 0.2701705E-08 0.1480563E-03 9.2460 15 F- 0.8596470E-06 0.8633202E-06 0.1636048E-01 3.8351 16 HPO4-- 0.2815746E-07 0.2872760E-07 0.2750374E-02 12.1047 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277403E+02 -.9055572E-02 -.8276497E+02 0.0000000E+00 2 H2O -.7027981E+01 0.2768398E+02 -.3471196E+02 0.0000000E+00 3 Cl- 0.1152615E-02 0.1152615E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1394138E+00 -.1175608E-01 0.1511699E+00 0.0000000E+00 5 HCO3- 0.1244795E-01 0.1244795E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1352089E+00 0.1596094E-01 -.1511699E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1945732E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5459037E-02 0.5205845E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.5113288E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.8571632E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1343092E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1088168E-03 0.1061462E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1498967E-01 0.6261387E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1346943E-08 0.8669296E-01 0.0000000E+00 15 F- 0.6889600E-04 0.4304108E-06 0.6846559E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1432223E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1448E-13 Mass of aqueous solution: 0.499799E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1719900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.7 andradite 0.6047 -0.218 307.3 2.488 5.625 79.84 grossular 0.1365 -0.865 61.49 1.789 1.126 17.11 apatite-OH 0.9794E-02 -2.009 4.920 0.692 0.9005E-01 1.563 apatite-F 0.6847E-04 -4.165 0.3453E-01 -1.462 0.6320E-03 0.1079E-01 clinochlore 0.7055 -0.151 392.2 2.593 7.178 149.2 daphnite 0.2020 -0.695 144.1 2.159 2.638 43.67 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9421 -0.026 262.2 2.419 4.800 102.4 stilbite 3.235 0.510 2280. 3.358 41.73 1063. stilpnomelane-Fe 0.2388 -0.622 257.4 2.411 4.712 88.91 tr.625ac.25prg.125 0.1215 -0.915 103.9 2.017 1.901 33.43 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8158E+00 0.8158E+00 1.0000 -0.088 grossular 0.1842E+00 0.1842E+00 1.0000 -0.735 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2184E+00 0.2184E+00 1.0000 -0.661 chlorite-Mn 0.1875E-01 0.1875E-01 1.0000 -1.727 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5463.281560 g Volume = 2212.043029 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1719900 moles log = -0.7645 Original solution: 1000.0103000 g Original solution / Rock added: 5814.35 (Water/Rock Ratio), log = 3.7645 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 36.5509 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2949E-01 0.9328 0.1006E+01 0.1078E+01 CO2,gas 0.3094E-06 0.9390 0.1062E-04 0.1131E-04 CH4,gas 0.9701E+00 0.9787 0.3470E+02 0.3546E+02 H2,gas 0.3608E-03 1.0197 0.1345E-01 0.1319E-01 H2S,gas 0.1869E-05 0.8708 0.5948E-04 0.6831E-04 S2,gas 0.2009E-25 1.0000 0.7344E-24 0.7344E-24 CO,gas 0.1042E-11 1.0000 0.3807E-10 0.3807E-10 SO3,gas 0.1385E-46 1.0000 0.5063E-45 0.5063E-45 SO2,gas 0.7251E-26 1.0000 0.2650E-24 0.2650E-24 HF,gas 0.3273E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1688E-17 1.0000 0.6168E-16 0.6168E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 117 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 164 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28969E+04 0.002 2 CO2,gas -6.66 -13.33 -6.67 -2.224 0.11394E+05 -4.974 3 CH4,gas 4.54 4.39 -0.16 -0.040 0.27077E+03 1.540 4 H2,gas 8.00 4.43 -3.57 -2.040 0.60962E+04 -1.871 5 H2S,gas -6.23 -12.15 -5.92 -2.962 0.10116E+05 -4.226 6 S2,gas -7.34 -33.17 -25.83 -3.974 0.44109E+05 -24.134 7 CO,gas 3.21 -8.90 -12.12 -3.729 0.20692E+05 -10.419 8 SO3,gas 17.12 -29.87 -46.99 -11.749 0.80242E+05 -45.296 9 SO2,gas 0.83 -25.44 -26.28 -7.007 0.44865E+05 -24.577 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.72 -17.91 -8.954 0.30579E+05 -16.210 12 acmite 7.71 6.55 -1.16 -0.120 0.19734E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80507E+04 21 analcite 3.32 2.77 -0.55 -0.061 0.94439E+03 26 ankerite -2.14 -6.85 -4.71 -0.786 0.80488E+04 27 annite 20.12 17.71 -2.42 -0.134 0.41248E+04 28 phlogopite 27.06 25.40 -1.66 -0.092 0.28424E+04 30 anorthite 12.71 8.24 -4.47 -0.344 0.76272E+04 38 aragonite 0.97 -0.25 -1.21 -0.405 0.20726E+04 39 brucite 12.57 9.30 -3.27 -0.655 0.55889E+04 40 calcite 0.81 -0.25 -1.06 -0.353 0.18084E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52958E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71228E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70506E+04 44 carpholite-Fe 6.71 1.89 -4.82 -0.322 0.82367E+04 45 celadonite 5.34 3.66 -1.69 -0.099 0.28781E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47546E+04 47 chrysotile 23.89 21.58 -2.31 -0.193 0.39473E+04 52 chlorite-Al-free 47.17 43.16 -4.01 -0.167 0.68498E+04 54 chloritoid-Fe 9.17 5.04 -4.13 -0.275 0.70551E+04 55 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65652E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13263E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10116E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36577E+04 69 diamond -3.10 -4.47 -1.37 -0.392 0.23416E+04 70 dolomite,ordered 0.55 -4.28 -4.83 -0.805 0.82492E+04 72 enstatite 17.26 12.29 -4.98 -0.498 0.85023E+04 74 clinoenstatite 17.17 12.29 -4.88 -0.488 0.83339E+04 76 epidote 24.67 22.69 -1.98 -0.096 0.33759E+04 77 clinozoisite 22.81 18.91 -3.90 -0.177 0.66561E+04 78 epidote-Fe 29.84 26.48 -3.36 -0.175 0.57423E+04 79 fayalite 14.05 10.31 -3.74 -0.534 0.63785E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68166E+04 84 gibbsite 4.08 0.73 -3.35 -0.478 0.57165E+04 85 glaucophane 22.97 20.81 -2.16 -0.058 0.36911E+04 86 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70946E+04 87 graphite -3.55 -4.47 -0.93 -0.265 0.15839E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38438E+04 91 hematite 12.57 9.03 -3.53 -0.428 0.60324E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.45 -0.145 0.24696E+04 98 kalsilite 7.58 3.82 -3.76 -0.538 0.64282E+04 99 kaolinite -1.33 -4.84 -3.51 -0.319 0.59932E+04 102 laumontite 2.88 1.94 -0.95 -0.063 0.16160E+04 103 lawsonite 9.62 8.24 -1.37 -0.092 0.23445E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58951E+04 106 lizardite 23.24 21.58 -1.66 -0.139 0.28399E+04 107 magnesite 0.69 -4.04 -4.73 -1.576 0.80731E+04 108 magnetite 20.09 15.76 -4.32 -0.353 0.73809E+04 109 minnesotaite 10.39 7.58 -2.81 -0.165 0.47898E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82168E+04 121 muscovite 2.58 -1.02 -3.61 -0.212 0.61569E+04 122 paragonite 4.24 1.08 -3.16 -0.186 0.53960E+04 123 nepheline 8.34 5.92 -2.42 -0.345 0.41281E+04 129 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83583E+04 135 phlogopite-Na 29.65 27.50 -2.14 -0.119 0.36612E+04 137 prehnite 19.37 18.18 -1.20 -0.070 0.20418E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91660E+03 139 pumpellyite-Fe 46.27 43.81 -2.45 -0.055 0.41910E+04 140 pumpellyite-Mg 48.99 46.38 -2.62 -0.058 0.44665E+04 143 pyrite -21.25 -22.01 -0.76 -0.179 0.12986E+04 144 pyrrhotite -4.26 -5.42 -1.16 -0.388 0.19856E+04 145 pyrrhotiteFe0.875 -6.02 -6.81 -0.80 -0.293 0.13608E+04 146 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22294E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84902E+04 148 quartz -2.99 -3.15 -0.16 -0.054 0.27898E+03 152 rhodochrosite -0.98 -4.09 -3.11 -1.037 0.53118E+04 153 rhodonite 7.45 6.09 -1.35 -0.271 0.23096E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.60 -3.99 -1.331 0.68187E+04 166 stilpnomelane-Mg 27.44 25.84 -1.60 -0.048 0.27388E+04 172 talc 16.49 15.28 -1.22 -0.072 0.20762E+04 175 tephroite 18.09 15.34 -2.75 -0.392 0.46903E+04 179 tridymite -2.63 -3.15 -0.53 -0.175 0.89896E+03 180 tremolite 47.87 47.43 -0.44 -0.012 0.75624E+03 181 ferroactinolite 38.45 34.61 -3.85 -0.104 0.65677E+04 182 troilite-low -4.41 -5.42 -1.01 -0.337 0.17284E+04 184 vesuvianite 223.47 218.52 -4.95 -0.038 0.84605E+04 188 wairakite 3.95 1.94 -2.01 -0.118 0.34374E+04 189 walstromite 11.51 9.93 -1.58 -0.315 0.26916E+04 190 wollastonite 10.46 9.93 -0.53 -0.106 0.90199E+03 191 pseudo-wollastonite 11.00 9.93 -1.07 -0.213 0.18218E+04 192 zoisite 22.85 18.91 -3.94 -0.179 0.67302E+04 193 akaganeite 7.75 4.52 -3.24 -0.700 0.55289E+04 200 chalcedony -2.80 -3.15 -0.35 -0.117 0.59828E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66117E+04 203 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68744E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.267 0.73566E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60293E+04 206 nontronite-Ca 3.21 -0.14 -3.35 -0.217 0.57230E+04 207 nontronite-H 2.53 -2.30 -4.83 -0.324 0.82455E+04 208 nontronite-K 3.34 -0.24 -3.58 -0.230 0.61089E+04 209 nontronite-Mg 3.07 -0.76 -3.84 -0.249 0.65519E+04 210 nontronite-Na 3.52 0.46 -3.06 -0.197 0.52297E+04 226 tobermorite 9.82 7.75 -2.08 -0.566 0.35442E+04 232 alabandite -0.98 -2.91 -1.93 -0.644 0.32970E+04 235 boehmite 4.41 0.73 -3.67 -0.612 0.62746E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52592E+04 243 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18125E+04 245 an20ab80 2.02 1.34 -0.68 -0.052 0.11546E+04 246 an25ab75 2.65 1.77 -0.87 -0.067 0.14902E+04 247 an30ab70 3.28 2.20 -1.07 -0.083 0.18354E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1719900 MOLES New total amount of reactant added: 0.1759900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1759900 Water: Moles liquid = 0.2767E+02 kg liquid = 0.4985E+00 Moles total = -.7025E+01 kg total = -.1266E+00 Activity = 0.9996 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2897190E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.1176E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12565E-09 -9.9008 0.10300E-09 -9.9872 0.81978E+00 -0.0863 2 H2O 0.99957E+00 -0.0002 0.99957E+00 -0.0002 3 Cl- 0.23451E-02 -2.6298 0.19071E-02 -2.7196 0.81324E+00 -0.0898 4 SO4-- 0.29313E-09 -9.5329 0.13738E-09 -9.8621 0.46866E+00 -0.3291 5 HCO3- 0.59565E-03 -3.2250 0.48535E-03 -3.3139 0.81482E+00 -0.0889 6 HS- 0.86273E-02 -2.0641 0.70175E-02 -2.1538 0.81340E+00 -0.0897 7 Al+++ 0.32208E-28 -28.4920 0.58836E-29 -29.2304 0.18268E+00 -0.7383 8 H4SiO4 0.70354E-03 -3.1527 0.70354E-03 -3.1527 0.10000E+01 0.0000 9 Ca++ 0.27750E-06 -6.5567 0.12878E-06 -6.8902 0.46406E+00 -0.3334 10 Mg++ 0.45463E-10 -10.3423 0.20969E-10 -10.6784 0.46124E+00 -0.3361 11 Fe++ 0.12371E-12 -12.9076 0.57141E-13 -13.2431 0.46192E+00 -0.3354 12 K+ 0.21950E-03 -3.6586 0.17891E-03 -3.7474 0.81507E+00 -0.0888 13 Na+ 0.27871E-01 -1.5549 0.22660E-01 -1.6447 0.81303E+00 -0.0899 14 Mn++ 0.40414E-10 -10.3935 0.18688E-10 -10.7284 0.46242E+00 -0.3350 15 F- 0.85197E-06 -6.0696 0.69098E-06 -6.1605 0.81104E+00 -0.0910 16 HPO4-- 0.27884E-07 -7.5546 0.13071E-07 -7.8837 0.46875E+00 -0.3291 18 HSiO3- 0.78458E-02 -2.1054 0.63805E-02 -2.1951 0.81324E+00 -0.0898 19 Ca(HSiO3)+ 0.22952E-07 -7.6392 0.18713E-07 -7.7279 0.81530E+00 -0.0887 20 Mg(HSiO3)+ 0.46511E-11 -11.3324 0.37921E-11 -11.4211 0.81530E+00 -0.0887 21 NaHSiO3,aq 0.23384E-02 -2.6311 0.23384E-02 -2.6311 0.10000E+01 0.0000 22 AlO+ 0.92495E-16 -16.0339 0.75412E-16 -16.1226 0.81530E+00 -0.0887 24 HAlO2,aq 0.14574E-09 -9.8364 0.14574E-09 -9.8364 0.10000E+01 0.0000 25 AlO2- 0.38605E-05 -5.4134 0.31320E-05 -5.5042 0.81131E+00 -0.0908 26 CH4,aq 0.24072E-01 -1.6185 0.24072E-01 -1.6185 0.10000E+01 0.0000 27 C2H6,aq 0.98011E-08 -8.0087 0.98011E-08 -8.0087 0.10000E+01 0.0000 28 C3H8,aq 0.92130E-13 -13.0356 0.92130E-13 -13.0356 0.10000E+01 0.0000 29 C4H10,aq 0.85076E-18 -18.0702 0.85076E-18 -18.0702 0.10000E+01 0.0000 30 ethanol,aq 0.41205E-15 -15.3850 0.41205E-15 -15.3850 0.10000E+01 0.0000 31 CO,aq 0.27147E-13 -13.5663 0.27147E-13 -13.5663 0.10000E+01 0.0000 32 CO2,aq 0.10687E-06 -6.9712 0.10687E-06 -6.9712 0.10000E+01 0.0000 33 CO3-2 0.88068E-03 -3.0552 0.41158E-03 -3.3855 0.46734E+00 -0.3304 34 CaCO3,aq 0.66459E-06 -6.1774 0.66459E-06 -6.1774 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.19569E-08 -8.7084 0.15954E-08 -8.7971 0.81530E+00 -0.0887 36 CaCl+ 0.48748E-09 -9.3120 0.39745E-09 -9.4007 0.81530E+00 -0.0887 37 CaCl2,aq 0.18008E-12 -12.7445 0.18008E-12 -12.7445 0.10000E+01 0.0000 38 CaF+ 0.15935E-11 -11.7977 0.12992E-11 -11.8863 0.81530E+00 -0.0887 39 CaOH+ 0.10924E-06 -6.9616 0.89066E-07 -7.0503 0.81530E+00 -0.0887 40 CaSO4,aq 0.56178E-14 -14.2504 0.56178E-14 -14.2504 0.10000E+01 0.0000 41 HCl,aq 0.35996E-13 -13.4437 0.35996E-13 -13.4437 0.10000E+01 0.0000 45 HF,aq 0.48723E-12 -12.3123 0.48723E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.13977E-18 -18.8546 0.11367E-18 -18.9444 0.81324E+00 -0.0898 48 FeCl+ 0.21156E-15 -15.6746 0.17249E-15 -15.7632 0.81530E+00 -0.0887 51 FeF+ 0.24748E-17 -17.6065 0.20177E-17 -17.6951 0.81530E+00 -0.0887 53 FeO,aq 0.20923E-09 -9.6794 0.20923E-09 -9.6794 0.10000E+01 0.0000 54 FeOH+ 0.22139E-10 -10.6548 0.18050E-10 -10.7435 0.81530E+00 -0.0887 55 HFeO2- 0.26124E-07 -7.5830 0.21245E-07 -7.6727 0.81324E+00 -0.0898 56 FeO+ 0.16610E-16 -16.7796 0.13542E-16 -16.8683 0.81530E+00 -0.0887 58 FeO2- 0.32101E-09 -9.4935 0.26106E-09 -9.5833 0.81324E+00 -0.0898 59 HFeO2,aq 0.34200E-11 -11.4660 0.34200E-11 -11.4660 0.10000E+01 0.0000 60 H2,aq 0.10108E-04 -4.9954 0.10108E-04 -4.9954 0.10000E+01 0.0000 61 KCl,aq 0.61838E-08 -8.2087 0.61838E-08 -8.2087 0.10000E+01 0.0000 63 KOH,aq 0.74144E-06 -6.1299 0.74144E-06 -6.1299 0.10000E+01 0.0000 64 KSO4- 0.46897E-12 -12.3289 0.38139E-12 -12.4186 0.81324E+00 -0.0898 65 MgCO3,aq 0.27125E-10 -10.5666 0.27125E-10 -10.5666 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.32559E-12 -12.4873 0.26546E-12 -12.5760 0.81530E+00 -0.0887 67 MgCl+ 0.71944E-13 -13.1430 0.58656E-13 -13.2317 0.81530E+00 -0.0887 68 MgF+ 0.96116E-15 -15.0172 0.78364E-15 -15.1059 0.81530E+00 -0.0887 69 MgOH+ 0.98431E-10 -10.0069 0.80251E-10 -10.0955 0.81530E+00 -0.0887 71 MnF+ 0.26678E-15 -15.5738 0.21751E-15 -15.6625 0.81530E+00 -0.0887 72 MnO,aq 0.18234E-08 -8.7391 0.18234E-08 -8.7391 0.10000E+01 0.0000 73 MnOH+ 0.67263E-09 -9.1722 0.54840E-09 -9.2609 0.81530E+00 -0.0887 74 MnO2-2 0.12199E-10 -10.9137 0.57012E-11 -11.2440 0.46734E+00 -0.3304 75 HMnO2- 0.15820E-09 -9.8008 0.12865E-09 -9.8906 0.81324E+00 -0.0898 78 MnCl+ 0.26919E-12 -12.5699 0.21947E-12 -12.6586 0.81530E+00 -0.0887 79 MnSO4,aq 0.74117E-18 -18.1301 0.74117E-18 -18.1301 0.10000E+01 0.0000 80 NaCl,aq 0.14321E-04 -4.8440 0.14321E-04 -4.8440 0.10000E+01 0.0000 81 NaF,aq 0.36657E-08 -8.4358 0.36657E-08 -8.4358 0.10000E+01 0.0000 82 NaOH,aq 0.94478E-04 -4.0247 0.94478E-04 -4.0247 0.10000E+01 0.0000 84 OH- 0.69109E-02 -2.1605 0.56069E-02 -2.2513 0.81131E+00 -0.0908 89 HPO3-2 0.88134E-15 -15.0549 0.41188E-15 -15.3852 0.46734E+00 -0.3304 91 H2PO3- 0.10461E-18 -18.9804 0.85075E-19 -19.0702 0.81324E+00 -0.0898 92 H3PO4,aq 0.96987E-18 -18.0133 0.96987E-18 -18.0133 0.10000E+01 0.0000 93 H2PO4- 0.30501E-10 -10.5157 0.24836E-10 -10.6049 0.81427E+00 -0.0892 94 PO4-3 0.53097E-09 -9.2749 0.10353E-09 -9.9849 0.19499E+00 -0.7100 98 HP2O7-3 0.51267E-18 -18.2902 0.93797E-19 -19.0278 0.18296E+00 -0.7376 99 P2O7-4 0.42398E-17 -17.3727 0.21754E-18 -18.6625 0.51310E-01 -1.2898 100 H2S,aq 0.22340E-05 -5.6509 0.22340E-05 -5.6509 0.10000E+01 0.0000 101 S2-2 0.23100E-09 -9.6364 0.10795E-09 -9.9668 0.46734E+00 -0.3304 102 S3-2 0.68784E-16 -16.1625 0.32145E-16 -16.4929 0.46734E+00 -0.3304 107 SO3-2 0.37899E-15 -15.4214 0.18052E-15 -15.7435 0.47632E+00 -0.3221 108 HSO3- 0.14316E-17 -17.8442 0.11642E-17 -17.9340 0.81324E+00 -0.0898 109 HSO4- 0.16704E-16 -16.7772 0.13637E-16 -16.8653 0.81637E+00 -0.0881 111 S2O3-2 0.77173E-17 -17.1125 0.36066E-17 -17.4429 0.46734E+00 -0.3304 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1256471E-09 -.1808753E-01 -.1818532E+02 0.0000 2 H2O 0.1000000E+01 0.5552916E+02 0.9978598E+06 0.0000 3 Cl- 0.2345055E-02 0.2359383E-02 0.8343692E+02 7.2675 4 SO4-- 0.2931295E-09 -.2407500E-01 -.2306869E+04 10.1122 5 HCO3- 0.5956502E-03 0.2554958E-01 0.1555045E+04 6.6732 6 HS- 0.8627316E-02 0.3270455E-01 0.1078886E+04 7.8333 7 Al+++ 0.3220783E-28 0.3860641E-05 0.1039040E+00 0.7311 8 H4SiO4 0.7035414E-03 0.1088775E-01 0.1043850E+04 -3.1527 9 Ca++ 0.2775014E-06 0.1076728E-05 0.4304465E-01 13.0841 10 Mg++ 0.4546263E-10 0.1760682E-09 0.4269809E-05 9.2959 11 Fe++ 0.1237051E-12 0.2667968E-07 0.1486234E-02 6.7313 12 K+ 0.2194985E-03 0.2202461E-03 0.8590414E+01 6.2398 13 Na+ 0.2787072E-01 0.3031792E-01 0.6952508E+03 8.3424 14 Mn++ 0.4041369E-10 0.2707095E-08 0.1483485E-03 9.2459 15 F- 0.8519732E-06 0.8556410E-06 0.1621461E-01 3.8266 16 HPO4-- 0.2788401E-07 0.2844548E-07 0.2723306E-02 12.0906 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277360E+02 -.9017118E-02 -.8276458E+02 0.0000000E+00 2 H2O -.7024706E+01 0.2768277E+02 -.3470748E+02 0.0000000E+00 3 Cl- 0.1176215E-02 0.1176215E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1394329E+00 -.1200203E-01 0.1514349E+00 0.0000000E+00 5 HCO3- 0.1273715E-01 0.1273715E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1351308E+00 0.1630409E-01 -.1514349E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1924633E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5427833E-02 0.5205848E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.5367779E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.8777468E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1330053E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1097986E-03 0.1061461E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1511429E-01 0.6261263E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1349559E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7049600E-04 0.4265599E-06 0.7006944E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1418083E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1628E-13 Mass of aqueous solution: 0.499783E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1759900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.7 andradite 0.6057 -0.218 307.8 2.488 5.634 79.98 grossular 0.1357 -0.867 61.13 1.786 1.119 17.01 apatite-OH 0.9793E-02 -2.009 4.919 0.692 0.9004E-01 1.563 apatite-F 0.7007E-04 -4.154 0.3534E-01 -1.452 0.6468E-03 0.1104E-01 clinochlore 0.7061 -0.151 392.5 2.594 7.183 149.3 daphnite 0.2019 -0.695 144.0 2.158 2.636 43.65 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9421 -0.026 262.2 2.419 4.800 102.4 stilbite 3.235 0.510 2280. 3.358 41.73 1063. stilpnomelane-Fe 0.2386 -0.622 257.3 2.410 4.709 88.86 tr.625ac.25prg.125 0.1208 -0.918 103.3 2.014 1.890 33.24 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8170E+00 0.8170E+00 1.0000 -0.088 grossular 0.1830E+00 0.1830E+00 1.0000 -0.737 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7631E+00 0.7631E+00 1.0000 -0.117 daphnite 0.2182E+00 0.2182E+00 1.0000 -0.661 chlorite-Mn 0.1874E-01 0.1874E-01 1.0000 -1.727 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5463.379566 g Volume = 2212.138693 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1759900 moles log = -0.7545 Original solution: 1000.0103000 g Original solution / Rock added: 5682.20 (Water/Rock Ratio), log = 3.7545 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 37.3113 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2892E-01 0.9319 0.1006E+01 0.1079E+01 CO2,gas 0.3267E-06 0.9379 0.1143E-04 0.1219E-04 CH4,gas 0.9707E+00 0.9783 0.3543E+02 0.3622E+02 H2,gas 0.3487E-03 1.0201 0.1327E-01 0.1301E-01 H2S,gas 0.1895E-05 0.8684 0.6141E-04 0.7072E-04 S2,gas 0.2154E-25 1.0000 0.8039E-24 0.8039E-24 CO,gas 0.1084E-11 1.0000 0.4045E-10 0.4045E-10 SO3,gas 0.1478E-46 1.0000 0.5513E-45 0.5513E-45 SO2,gas 0.7632E-26 1.0000 0.2848E-24 0.2848E-24 HF,gas 0.3206E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1702E-17 1.0000 0.6352E-16 0.6352E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 117 microcline -2.49 -2.49 0.00 0.000 -0.22748E-10 164 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28969E+04 0.002 2 CO2,gas -6.66 -13.30 -6.64 -2.214 0.11339E+05 -4.942 3 CH4,gas 4.54 4.39 -0.15 -0.037 0.25537E+03 1.549 4 H2,gas 8.00 4.42 -3.58 -2.043 0.61061E+04 -1.877 5 H2S,gas -6.23 -12.14 -5.91 -2.955 0.10092E+05 -4.212 6 S2,gas -7.34 -33.13 -25.79 -3.968 0.44042E+05 -24.095 7 CO,gas 3.21 -8.88 -12.09 -3.721 0.20647E+05 -10.393 8 SO3,gas 17.12 -29.84 -46.96 -11.739 0.80179E+05 -45.259 9 SO2,gas 0.83 -25.41 -26.24 -6.999 0.44812E+05 -24.546 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.71 -17.90 -8.948 0.30557E+05 -16.197 12 acmite 7.71 6.56 -1.15 -0.120 0.19686E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80518E+04 21 analcite 3.32 2.77 -0.55 -0.062 0.94523E+03 26 ankerite -2.14 -6.79 -4.65 -0.775 0.79427E+04 27 annite 20.12 17.71 -2.42 -0.134 0.41268E+04 28 phlogopite 27.06 25.40 -1.66 -0.092 0.28415E+04 30 anorthite 12.71 8.24 -4.47 -0.344 0.76313E+04 38 aragonite 0.97 -0.22 -1.18 -0.394 0.20207E+04 39 brucite 12.57 9.30 -3.27 -0.655 0.55886E+04 40 calcite 0.81 -0.22 -1.03 -0.343 0.17565E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52974E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71244E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70515E+04 44 carpholite-Fe 6.71 1.89 -4.82 -0.322 0.82385E+04 45 celadonite 5.34 3.66 -1.68 -0.099 0.28770E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47544E+04 47 chrysotile 23.89 21.58 -2.31 -0.193 0.39448E+04 52 chlorite-Al-free 47.17 43.16 -4.01 -0.167 0.68448E+04 54 chloritoid-Fe 9.17 5.04 -4.13 -0.276 0.70577E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.256 0.65674E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13255E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10108E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36591E+04 69 diamond -3.10 -4.45 -1.35 -0.386 0.23065E+04 70 dolomite,ordered 0.55 -4.22 -4.77 -0.795 0.81421E+04 72 enstatite 17.26 12.29 -4.98 -0.498 0.85001E+04 74 clinoenstatite 17.17 12.29 -4.88 -0.488 0.83317E+04 76 epidote 24.67 22.69 -1.98 -0.096 0.33779E+04 77 clinozoisite 22.81 18.90 -3.90 -0.177 0.66638E+04 78 epidote-Fe 29.84 26.48 -3.36 -0.175 0.57386E+04 79 fayalite 14.05 10.31 -3.74 -0.534 0.63790E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68162E+04 84 gibbsite 4.08 0.73 -3.35 -0.478 0.57179E+04 85 glaucophane 22.97 20.81 -2.16 -0.058 0.36886E+04 86 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70949E+04 87 graphite -3.55 -4.45 -0.91 -0.259 0.15487E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38441E+04 91 hematite 12.57 9.04 -3.53 -0.428 0.60238E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.45 -0.145 0.24704E+04 98 kalsilite 7.58 3.82 -3.77 -0.538 0.64299E+04 99 kaolinite -1.33 -4.84 -3.51 -0.319 0.59943E+04 102 laumontite 2.88 1.94 -0.95 -0.063 0.16185E+04 103 lawsonite 9.62 8.24 -1.38 -0.092 0.23487E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58959E+04 106 lizardite 23.24 21.58 -1.66 -0.138 0.28375E+04 107 magnesite 0.69 -4.01 -4.70 -1.565 0.80180E+04 108 magnetite 20.09 15.77 -4.32 -0.352 0.73730E+04 109 minnesotaite 10.39 7.58 -2.80 -0.165 0.47885E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82171E+04 121 muscovite 2.58 -1.03 -3.61 -0.212 0.61597E+04 122 paragonite 4.24 1.08 -3.16 -0.186 0.53988E+04 123 nepheline 8.34 5.92 -2.42 -0.346 0.41298E+04 129 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83590E+04 135 phlogopite-Na 29.65 27.50 -2.14 -0.119 0.36603E+04 137 prehnite 19.37 18.17 -1.20 -0.071 0.20481E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91721E+03 139 pumpellyite-Fe 46.27 43.81 -2.46 -0.055 0.42056E+04 140 pumpellyite-Mg 48.99 46.37 -2.62 -0.058 0.44802E+04 143 pyrite -21.25 -21.97 -0.73 -0.171 0.12421E+04 144 pyrrhotite -4.26 -5.41 -1.15 -0.383 0.19626E+04 145 pyrrhotiteFe0.875 -6.02 -6.80 -0.78 -0.288 0.13365E+04 146 pyroxmangite 7.40 6.09 -1.31 -0.261 0.22288E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84897E+04 148 quartz -2.99 -3.15 -0.16 -0.054 0.27814E+03 152 rhodochrosite -0.98 -4.06 -3.08 -1.026 0.52571E+04 153 rhodonite 7.45 6.09 -1.35 -0.270 0.23091E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.57 -3.96 -1.321 0.67645E+04 166 stilpnomelane-Mg 27.44 25.84 -1.60 -0.048 0.27341E+04 172 talc 16.49 15.28 -1.21 -0.071 0.20720E+04 175 tephroite 18.09 15.34 -2.75 -0.392 0.46900E+04 179 tridymite -2.63 -3.15 -0.53 -0.175 0.89812E+03 180 tremolite 47.87 47.43 -0.44 -0.012 0.75417E+03 181 ferroactinolite 38.45 34.60 -3.85 -0.104 0.65703E+04 182 troilite-low -4.41 -5.41 -1.00 -0.333 0.17054E+04 184 vesuvianite 223.47 218.48 -4.99 -0.038 0.85172E+04 188 wairakite 3.95 1.94 -2.01 -0.119 0.34398E+04 189 walstromite 11.51 9.93 -1.58 -0.316 0.26937E+04 190 wollastonite 10.46 9.93 -0.53 -0.106 0.90415E+03 191 pseudo-wollastonite 11.00 9.93 -1.07 -0.214 0.18240E+04 192 zoisite 22.85 18.90 -3.95 -0.179 0.67379E+04 193 akaganeite 7.75 4.52 -3.24 -0.700 0.55246E+04 200 chalcedony -2.80 -3.15 -0.35 -0.117 0.59744E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66112E+04 203 montmorillonite-K -2.24 -6.26 -4.03 -0.247 0.68737E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.266 0.73555E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60286E+04 206 nontronite-Ca 3.21 -0.13 -3.35 -0.217 0.57123E+04 207 nontronite-H 2.53 -2.29 -4.82 -0.323 0.82343E+04 208 nontronite-K 3.34 -0.23 -3.57 -0.229 0.60981E+04 209 nontronite-Mg 3.07 -0.76 -3.83 -0.249 0.65407E+04 210 nontronite-Na 3.52 0.46 -3.06 -0.196 0.52190E+04 226 tobermorite 9.82 7.75 -2.08 -0.567 0.35459E+04 232 alabandite -0.98 -2.90 -1.92 -0.639 0.32736E+04 235 boehmite 4.41 0.73 -3.68 -0.613 0.62760E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52599E+04 243 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18116E+04 245 an20ab80 2.02 1.34 -0.68 -0.052 0.11554E+04 246 an25ab75 2.65 1.77 -0.87 -0.067 0.14912E+04 247 an30ab70 3.28 2.20 -1.08 -0.083 0.18367E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1759900 MOLES New total amount of reactant added: 0.1799900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1799900 Water: Moles liquid = 0.2767E+02 kg liquid = 0.4985E+00 Moles total = -.7021E+01 kg total = -.1265E+00 Activity = 0.9996 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2928314E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.1200E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12699E-09 -9.8962 0.10402E-09 -9.9829 0.81917E+00 -0.0866 2 H2O 0.99956E+00 -0.0002 0.99956E+00 -0.0002 3 Cl- 0.23921E-02 -2.6212 0.19438E-02 -2.7113 0.81258E+00 -0.0901 4 SO4-- 0.31371E-09 -9.5035 0.14656E-09 -9.8340 0.46719E+00 -0.3305 5 HCO3- 0.63510E-03 -3.1972 0.51709E-03 -3.2864 0.81418E+00 -0.0893 6 HS- 0.88227E-02 -2.0544 0.71706E-02 -2.1444 0.81274E+00 -0.0900 7 Al+++ 0.33353E-28 -28.4769 0.60493E-29 -29.2183 0.18137E+00 -0.7414 8 H4SiO4 0.70432E-03 -3.1522 0.70432E-03 -3.1522 0.10000E+01 0.0000 9 Ca++ 0.28281E-06 -6.5485 0.13082E-06 -6.8833 0.46257E+00 -0.3348 10 Mg++ 0.46539E-10 -10.3322 0.21396E-10 -10.6697 0.45974E+00 -0.3375 11 Fe++ 0.12647E-12 -12.8980 0.58230E-13 -13.2349 0.46042E+00 -0.3369 12 K+ 0.22153E-03 -3.6546 0.18042E-03 -3.7437 0.81443E+00 -0.0891 13 Na+ 0.28129E-01 -1.5509 0.22851E-01 -1.6411 0.81237E+00 -0.0902 14 Mn++ 0.41340E-10 -10.3836 0.19055E-10 -10.7200 0.46093E+00 -0.3364 15 F- 0.84429E-06 -6.0735 0.68418E-06 -6.1648 0.81036E+00 -0.0913 16 HPO4-- 0.27609E-07 -7.5590 0.12901E-07 -7.8894 0.46728E+00 -0.3304 18 HSiO3- 0.77836E-02 -2.1088 0.63249E-02 -2.1989 0.81258E+00 -0.0901 19 Ca(HSiO3)+ 0.23131E-07 -7.6358 0.18844E-07 -7.7248 0.81466E+00 -0.0890 20 Mg(HSiO3)+ 0.47080E-11 -11.3272 0.38355E-11 -11.4162 0.81466E+00 -0.0890 21 NaHSiO3,aq 0.23375E-02 -2.6312 0.23375E-02 -2.6312 0.10000E+01 0.0000 22 AlO+ 0.93312E-16 -16.0301 0.76017E-16 -16.1191 0.81466E+00 -0.0890 24 HAlO2,aq 0.14547E-09 -9.8372 0.14547E-09 -9.8372 0.10000E+01 0.0000 25 AlO2- 0.38185E-05 -5.4181 0.30954E-05 -5.5093 0.81063E+00 -0.0912 26 CH4,aq 0.24563E-01 -1.6097 0.24563E-01 -1.6097 0.10000E+01 0.0000 27 C2H6,aq 0.10341E-07 -7.9854 0.10341E-07 -7.9854 0.10000E+01 0.0000 28 C3H8,aq 0.10051E-12 -12.9978 0.10051E-12 -12.9978 0.10000E+01 0.0000 29 C4H10,aq 0.95971E-18 -18.0179 0.95971E-18 -18.0179 0.10000E+01 0.0000 30 ethanol,aq 0.44055E-15 -15.3560 0.44055E-15 -15.3560 0.10000E+01 0.0000 31 CO,aq 0.28825E-13 -13.5402 0.28825E-13 -13.5402 0.10000E+01 0.0000 32 CO2,aq 0.11499E-06 -6.9394 0.11499E-06 -6.9394 0.10000E+01 0.0000 33 CO3-2 0.93198E-03 -3.0306 0.43418E-03 -3.3623 0.46587E+00 -0.3317 34 CaCO3,aq 0.71220E-06 -6.1474 0.71220E-06 -6.1474 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.21196E-08 -8.6738 0.17267E-08 -8.7628 0.81466E+00 -0.0890 36 CaCl+ 0.50514E-09 -9.2966 0.41152E-09 -9.3856 0.81466E+00 -0.0890 37 CaCl2,aq 0.19004E-12 -12.7211 0.19004E-12 -12.7211 0.10000E+01 0.0000 38 CaF+ 0.16041E-11 -11.7948 0.13068E-11 -11.8838 0.81466E+00 -0.0890 39 CaOH+ 0.10997E-06 -6.9587 0.89588E-07 -7.0477 0.81466E+00 -0.0890 40 CaSO4,aq 0.60886E-14 -14.2155 0.60886E-14 -14.2155 0.10000E+01 0.0000 41 HCl,aq 0.37053E-13 -13.4312 0.37053E-13 -13.4312 0.10000E+01 0.0000 45 HF,aq 0.48722E-12 -12.3123 0.48722E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.13851E-18 -18.8585 0.11255E-18 -18.9487 0.81258E+00 -0.0901 48 FeCl+ 0.21992E-15 -15.6577 0.17916E-15 -15.7468 0.81466E+00 -0.0890 51 FeF+ 0.24991E-17 -17.6022 0.20359E-17 -17.6912 0.81466E+00 -0.0890 53 FeO,aq 0.20905E-09 -9.6798 0.20905E-09 -9.6798 0.10000E+01 0.0000 54 FeOH+ 0.22357E-10 -10.6506 0.18213E-10 -10.7396 0.81466E+00 -0.0890 55 HFeO2- 0.25865E-07 -7.5873 0.21017E-07 -7.6774 0.81258E+00 -0.0901 56 FeO+ 0.16885E-16 -16.7725 0.13755E-16 -16.8615 0.81466E+00 -0.0890 58 FeO2- 0.31995E-09 -9.4949 0.25998E-09 -9.5851 0.81258E+00 -0.0901 59 HFeO2,aq 0.34397E-11 -11.4635 0.34397E-11 -11.4635 0.10000E+01 0.0000 60 H2,aq 0.99744E-05 -5.0011 0.99744E-05 -5.0011 0.10000E+01 0.0000 61 KCl,aq 0.63560E-08 -8.1968 0.63560E-08 -8.1968 0.10000E+01 0.0000 63 KOH,aq 0.74034E-06 -6.1306 0.74034E-06 -6.1306 0.10000E+01 0.0000 64 KSO4- 0.50496E-12 -12.2967 0.41033E-12 -12.3869 0.81258E+00 -0.0901 65 MgCO3,aq 0.29197E-10 -10.5347 0.29197E-10 -10.5347 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.35422E-12 -12.4507 0.28857E-12 -12.5398 0.81466E+00 -0.0890 67 MgCl+ 0.74879E-13 -13.1256 0.61001E-13 -13.2147 0.81466E+00 -0.0890 68 MgF+ 0.97183E-15 -15.0124 0.79171E-15 -15.1014 0.81466E+00 -0.0890 69 MgOH+ 0.99524E-10 -10.0021 0.81078E-10 -10.0911 0.81466E+00 -0.0890 71 MnF+ 0.26954E-15 -15.5694 0.21959E-15 -15.6584 0.81466E+00 -0.0890 72 MnO,aq 0.18227E-08 -8.7393 0.18227E-08 -8.7393 0.10000E+01 0.0000 73 MnOH+ 0.67961E-09 -9.1677 0.55365E-09 -9.2568 0.81466E+00 -0.0890 74 MnO2-2 0.11994E-10 -10.9210 0.55876E-11 -11.2528 0.46587E+00 -0.3317 75 HMnO2- 0.15671E-09 -9.8049 0.12734E-09 -9.8950 0.81258E+00 -0.0901 78 MnCl+ 0.27997E-12 -12.5529 0.22808E-12 -12.6419 0.81466E+00 -0.0890 79 MnSO4,aq 0.80624E-18 -18.0935 0.80624E-18 -18.0935 0.10000E+01 0.0000 80 NaCl,aq 0.14720E-04 -4.8321 0.14720E-04 -4.8321 0.10000E+01 0.0000 81 NaF,aq 0.36602E-08 -8.4365 0.36602E-08 -8.4365 0.10000E+01 0.0000 82 NaOH,aq 0.94338E-04 -4.0253 0.94338E-04 -4.0253 0.10000E+01 0.0000 84 OH- 0.68486E-02 -2.1644 0.55517E-02 -2.2556 0.81063E+00 -0.0912 89 HPO3-2 0.86116E-15 -15.0649 0.40119E-15 -15.3967 0.46587E+00 -0.3317 91 H2PO3- 0.10299E-18 -18.9872 0.83688E-19 -19.0773 0.81258E+00 -0.0901 92 H3PO4,aq 0.97638E-18 -18.0104 0.97638E-18 -18.0104 0.10000E+01 0.0000 93 H2PO4- 0.30428E-10 -10.5167 0.24757E-10 -10.6063 0.81362E+00 -0.0896 94 PO4-3 0.52239E-09 -9.2820 0.10119E-09 -9.9949 0.19370E+00 -0.7129 98 HP2O7-3 0.50804E-18 -18.2941 0.92286E-19 -19.0349 0.18165E+00 -0.7408 99 P2O7-4 0.41823E-17 -17.3786 0.21194E-18 -18.6738 0.50675E-01 -1.2952 100 H2S,aq 0.23054E-05 -5.6373 0.23054E-05 -5.6373 0.10000E+01 0.0000 101 S2-2 0.24518E-09 -9.6105 0.11422E-09 -9.9422 0.46587E+00 -0.3317 102 S3-2 0.76347E-16 -16.1172 0.35568E-16 -16.4489 0.46587E+00 -0.3317 107 SO3-2 0.40021E-15 -15.3977 0.19006E-15 -15.7211 0.47489E+00 -0.3234 108 HSO3- 0.15234E-17 -17.8172 0.12379E-17 -17.9073 0.81258E+00 -0.0901 109 HSO4- 0.18012E-16 -16.7444 0.14693E-16 -16.8329 0.81574E+00 -0.0884 111 S2O3-2 0.85235E-17 -17.0694 0.39708E-17 -17.4011 0.46587E+00 -0.3317 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1269888E-09 -.1801311E-01 -.1811011E+02 0.0000 2 H2O 0.1000000E+01 0.5552965E+02 0.9978471E+06 0.0000 3 Cl- 0.2392120E-02 0.2406847E-02 0.8511360E+02 7.2715 4 SO4-- 0.3137149E-09 -.2456562E-01 -.2353830E+04 10.1318 5 HCO3- 0.6351013E-03 0.2613104E-01 0.1590401E+04 6.6964 6 HS- 0.8822677E-02 0.3339060E-01 0.1101494E+04 7.8384 7 Al+++ 0.3335338E-28 0.3818648E-05 0.1027716E+00 0.7303 8 H4SiO4 0.7043186E-03 0.1082550E-01 0.1037859E+04 -3.1522 9 Ca++ 0.2828112E-06 0.1130743E-05 0.4520303E-01 13.0824 10 Mg++ 0.4653910E-10 0.1803979E-09 0.4374714E-05 9.2961 11 Fe++ 0.1264736E-12 0.2641977E-07 0.1471724E-02 6.7309 12 K+ 0.2215250E-03 0.2222717E-03 0.8669234E+01 6.2391 13 Na+ 0.2812862E-01 0.3057522E-01 0.7011361E+03 8.3418 14 Mn++ 0.4133979E-10 0.2712679E-08 0.1486513E-03 9.2457 15 F- 0.8442922E-06 0.8479546E-06 0.1606860E-01 3.8180 16 HPO4-- 0.2760860E-07 0.2816142E-07 0.2696052E-02 12.0763 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277317E+02 -.8979552E-02 -.8276419E+02 0.0000000E+00 2 H2O -.7021431E+01 0.2768158E+02 -.3470301E+02 0.0000000E+00 3 Cl- 0.1199815E-02 0.1199815E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1394520E+00 -.1224598E-01 0.1516980E+00 0.0000000E+00 5 HCO3- 0.1302635E-01 0.1302635E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1350527E+00 0.1664524E-01 -.1516980E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1903599E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5396522E-02 0.5205851E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.5636764E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.8992851E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1317028E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1108026E-03 0.1061460E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1524177E-01 0.6261135E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1352273E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7209600E-04 0.4227061E-06 0.7167329E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1403849E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1400E-13 Mass of aqueous solution: 0.499768E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1799900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.7 andradite 0.6068 -0.217 308.4 2.489 5.644 80.11 grossular 0.1349 -0.870 60.77 1.784 1.112 16.91 apatite-OH 0.9791E-02 -2.009 4.918 0.692 0.9002E-01 1.563 apatite-F 0.7167E-04 -4.145 0.3615E-01 -1.442 0.6616E-03 0.1129E-01 clinochlore 0.7066 -0.151 392.7 2.594 7.188 149.4 daphnite 0.2018 -0.695 144.0 2.158 2.635 43.62 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9422 -0.026 262.3 2.419 4.800 102.4 stilbite 3.236 0.510 2281. 3.358 41.74 1064. stilpnomelane-Fe 0.2385 -0.622 257.1 2.410 4.706 88.81 tr.625ac.25prg.125 0.1201 -0.920 102.7 2.011 1.879 33.04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8181E+00 0.8181E+00 1.0000 -0.087 grossular 0.1819E+00 0.1819E+00 1.0000 -0.740 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7633E+00 0.7633E+00 1.0000 -0.117 daphnite 0.2180E+00 0.2180E+00 1.0000 -0.662 chlorite-Mn 0.1873E-01 0.1873E-01 1.0000 -1.727 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5463.477024 g Volume = 2212.233846 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1799900 moles log = -0.7448 Original solution: 1000.0103000 g Original solution / Rock added: 5555.92 (Water/Rock Ratio), log = 3.7448 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 38.0663 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2837E-01 0.9310 0.1006E+01 0.1080E+01 CO2,gas 0.3450E-06 0.9368 0.1230E-04 0.1313E-04 CH4,gas 0.9713E+00 0.9779 0.3616E+02 0.3697E+02 H2,gas 0.3371E-03 1.0205 0.1310E-01 0.1283E-01 H2S,gas 0.1922E-05 0.8660 0.6337E-04 0.7318E-04 S2,gas 0.2309E-25 1.0000 0.8791E-24 0.8791E-24 CO,gas 0.1128E-11 1.0000 0.4295E-10 0.4295E-10 SO3,gas 0.1576E-46 1.0000 0.5999E-45 0.5999E-45 SO2,gas 0.8033E-26 1.0000 0.3058E-24 0.3058E-24 HF,gas 0.3143E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1718E-17 1.0000 0.6538E-16 0.6538E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 117 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 164 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28969E+04 0.002 2 CO2,gas -6.66 -13.27 -6.61 -2.203 0.11285E+05 -4.910 3 CH4,gas 4.54 4.40 -0.14 -0.035 0.24041E+03 1.558 4 H2,gas 8.00 4.42 -3.58 -2.047 0.61159E+04 -1.883 5 H2S,gas -6.23 -12.13 -5.90 -2.949 0.10069E+05 -4.198 6 S2,gas -7.34 -33.09 -25.75 -3.962 0.43976E+05 -24.056 7 CO,gas 3.21 -8.85 -12.07 -3.713 0.20602E+05 -10.367 8 SO3,gas 17.12 -29.80 -46.92 -11.730 0.80116E+05 -45.222 9 SO2,gas 0.83 -25.38 -26.21 -6.990 0.44759E+05 -24.515 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.69 -17.88 -8.942 0.30536E+05 -16.185 12 acmite 7.71 6.56 -1.15 -0.119 0.19638E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80529E+04 21 analcite 3.32 2.77 -0.55 -0.062 0.94607E+03 26 ankerite -2.14 -6.73 -4.59 -0.765 0.78377E+04 27 annite 20.12 17.71 -2.42 -0.134 0.41287E+04 28 phlogopite 27.06 25.40 -1.66 -0.092 0.28407E+04 30 anorthite 12.71 8.24 -4.47 -0.344 0.76355E+04 38 aragonite 0.97 -0.19 -1.15 -0.384 0.19694E+04 39 brucite 12.57 9.30 -3.27 -0.655 0.55884E+04 40 calcite 0.81 -0.19 -1.00 -0.333 0.17052E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.52991E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71261E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70524E+04 44 carpholite-Fe 6.71 1.89 -4.83 -0.322 0.82403E+04 45 celadonite 5.34 3.66 -1.68 -0.099 0.28758E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47542E+04 47 chrysotile 23.89 21.58 -2.31 -0.192 0.39423E+04 52 chlorite-Al-free 47.17 43.17 -4.01 -0.167 0.68399E+04 54 chloritoid-Fe 9.17 5.04 -4.13 -0.276 0.70603E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65696E+04 57 coesite -2.38 -3.15 -0.78 -0.259 0.13246E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10100E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36605E+04 69 diamond -3.10 -4.43 -1.33 -0.380 0.22718E+04 70 dolomite,ordered 0.55 -4.16 -4.71 -0.784 0.80362E+04 72 enstatite 17.26 12.29 -4.98 -0.498 0.84979E+04 74 clinoenstatite 17.17 12.29 -4.88 -0.488 0.83295E+04 76 epidote 24.67 22.69 -1.98 -0.096 0.33799E+04 77 clinozoisite 22.81 18.90 -3.91 -0.178 0.66715E+04 78 epidote-Fe 29.84 26.48 -3.36 -0.174 0.57350E+04 79 fayalite 14.05 10.31 -3.74 -0.534 0.63795E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68159E+04 84 gibbsite 4.08 0.73 -3.35 -0.479 0.57193E+04 85 glaucophane 22.97 20.82 -2.16 -0.058 0.36861E+04 86 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70952E+04 87 graphite -3.55 -4.43 -0.89 -0.253 0.15141E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38444E+04 91 hematite 12.57 9.04 -3.52 -0.427 0.60153E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.45 -0.145 0.24712E+04 98 kalsilite 7.58 3.82 -3.77 -0.538 0.64316E+04 99 kaolinite -1.33 -4.84 -3.51 -0.319 0.59954E+04 102 laumontite 2.88 1.93 -0.95 -0.063 0.16210E+04 103 lawsonite 9.62 8.24 -1.38 -0.092 0.23528E+04 104 leucite 4.12 0.67 -3.45 -0.345 0.58968E+04 106 lizardite 23.24 21.58 -1.66 -0.138 0.28350E+04 107 magnesite 0.69 -3.97 -4.66 -1.555 0.79634E+04 108 magnetite 20.09 15.77 -4.31 -0.352 0.73651E+04 109 minnesotaite 10.39 7.58 -2.80 -0.165 0.47871E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82174E+04 121 muscovite 2.58 -1.03 -3.61 -0.212 0.61625E+04 122 paragonite 4.24 1.08 -3.16 -0.186 0.54016E+04 123 nepheline 8.34 5.92 -2.42 -0.346 0.41315E+04 129 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83596E+04 135 phlogopite-Na 29.65 27.50 -2.14 -0.119 0.36595E+04 137 prehnite 19.37 18.17 -1.20 -0.071 0.20544E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91783E+03 139 pumpellyite-Fe 46.27 43.80 -2.47 -0.055 0.42202E+04 140 pumpellyite-Mg 48.99 46.36 -2.63 -0.058 0.44939E+04 143 pyrite -21.25 -21.94 -0.69 -0.163 0.11862E+04 144 pyrrhotite -4.26 -5.40 -1.14 -0.379 0.19399E+04 145 pyrrhotiteFe0.875 -6.02 -6.79 -0.77 -0.283 0.13125E+04 146 pyroxmangite 7.40 6.09 -1.30 -0.261 0.22282E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84892E+04 148 quartz -2.99 -3.15 -0.16 -0.054 0.27731E+03 152 rhodochrosite -0.98 -4.02 -3.05 -1.016 0.52031E+04 153 rhodonite 7.45 6.09 -1.35 -0.270 0.23085E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.54 -3.93 -1.310 0.67108E+04 166 stilpnomelane-Mg 27.44 25.84 -1.60 -0.048 0.27294E+04 172 talc 16.49 15.28 -1.21 -0.071 0.20678E+04 175 tephroite 18.09 15.34 -2.75 -0.392 0.46897E+04 179 tridymite -2.63 -3.15 -0.53 -0.175 0.89729E+03 180 tremolite 47.87 47.43 -0.44 -0.012 0.75210E+03 181 ferroactinolite 38.45 34.60 -3.85 -0.104 0.65729E+04 182 troilite-low -4.41 -5.40 -0.99 -0.328 0.16827E+04 188 wairakite 3.95 1.93 -2.02 -0.119 0.34423E+04 189 walstromite 11.51 9.93 -1.58 -0.316 0.26959E+04 190 wollastonite 10.46 9.93 -0.53 -0.106 0.90630E+03 191 pseudo-wollastonite 11.00 9.93 -1.07 -0.214 0.18261E+04 192 zoisite 22.85 18.90 -3.95 -0.180 0.67455E+04 193 akaganeite 7.75 4.52 -3.23 -0.699 0.55203E+04 200 chalcedony -2.80 -3.15 -0.35 -0.116 0.59661E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.240 0.66106E+04 203 montmorillonite-K -2.24 -6.26 -4.03 -0.246 0.68730E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.266 0.73543E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60279E+04 206 nontronite-Ca 3.21 -0.12 -3.34 -0.217 0.57017E+04 207 nontronite-H 2.53 -2.28 -4.82 -0.323 0.82232E+04 208 nontronite-K 3.34 -0.22 -3.57 -0.229 0.60873E+04 209 nontronite-Mg 3.07 -0.75 -3.82 -0.248 0.65295E+04 210 nontronite-Na 3.52 0.47 -3.05 -0.196 0.52082E+04 226 tobermorite 9.82 7.75 -2.08 -0.567 0.35476E+04 232 alabandite -0.98 -2.88 -1.90 -0.635 0.32505E+04 235 boehmite 4.41 0.73 -3.68 -0.613 0.62774E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52606E+04 243 silica-amorphous -2.09 -3.15 -1.06 -0.354 0.18108E+04 245 an20ab80 2.02 1.34 -0.68 -0.052 0.11562E+04 246 an25ab75 2.65 1.77 -0.87 -0.067 0.14923E+04 247 an30ab70 3.28 2.20 -1.08 -0.083 0.18379E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1799900 MOLES New total amount of reactant added: 0.1839900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8666E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1839900 Water: Moles liquid = 0.2767E+02 kg liquid = 0.4985E+00 Moles total = -.7018E+01 kg total = -.1264E+00 Activity = 0.9995 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2960237E-01 Chg. balance for total moles = -.8666E-10 Max. difference allowed = 0.1223E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12836E-09 -9.8916 0.10507E-09 -9.9785 0.81855E+00 -0.0870 2 H2O 0.99955E+00 -0.0002 0.99955E+00 -0.0002 3 Cl- 0.24392E-02 -2.6128 0.19804E-02 -2.7032 0.81192E+00 -0.0905 4 SO4-- 0.33549E-09 -9.4743 0.15624E-09 -9.8062 0.46570E+00 -0.3319 5 HCO3- 0.67658E-03 -3.1697 0.55041E-03 -3.2593 0.81352E+00 -0.0896 6 HS- 0.90180E-02 -2.0449 0.73233E-02 -2.1353 0.81208E+00 -0.0904 7 Al+++ 0.34555E-28 -28.4615 0.62215E-29 -29.2061 0.18005E+00 -0.7446 8 H4SiO4 0.70509E-03 -3.1518 0.70509E-03 -3.1518 0.10000E+01 0.0000 9 Ca++ 0.28830E-06 -6.5402 0.13293E-06 -6.8764 0.46106E+00 -0.3362 10 Mg++ 0.47654E-10 -10.3219 0.21836E-10 -10.6608 0.45822E+00 -0.3389 11 Fe++ 0.12934E-12 -12.8883 0.59353E-13 -13.2266 0.45889E+00 -0.3383 12 K+ 0.22360E-03 -3.6505 0.18196E-03 -3.7400 0.81377E+00 -0.0895 13 Na+ 0.28392E-01 -1.5468 0.23046E-01 -1.6374 0.81170E+00 -0.0906 14 Mn++ 0.42299E-10 -10.3737 0.19432E-10 -10.7115 0.45941E+00 -0.3378 15 F- 0.83661E-06 -6.0775 0.67738E-06 -6.1692 0.80968E+00 -0.0917 16 HPO4-- 0.27331E-07 -7.5633 0.12731E-07 -7.8951 0.46579E+00 -0.3318 18 HSiO3- 0.77212E-02 -2.1123 0.62690E-02 -2.2028 0.81192E+00 -0.0905 19 Ca(HSiO3)+ 0.23314E-07 -7.6324 0.18978E-07 -7.7218 0.81401E+00 -0.0894 20 Mg(HSiO3)+ 0.47662E-11 -11.3218 0.38797E-11 -11.4112 0.81401E+00 -0.0894 21 NaHSiO3,aq 0.23367E-02 -2.6314 0.23367E-02 -2.6314 0.10000E+01 0.0000 22 AlO+ 0.94147E-16 -16.0262 0.76636E-16 -16.1156 0.81401E+00 -0.0894 24 HAlO2,aq 0.14519E-09 -9.8381 0.14519E-09 -9.8381 0.10000E+01 0.0000 25 AlO2- 0.37766E-05 -5.4229 0.30589E-05 -5.5144 0.80995E+00 -0.0915 26 CH4,aq 0.25050E-01 -1.6012 0.25050E-01 -1.6012 0.10000E+01 0.0000 27 C2H6,aq 0.10898E-07 -7.9627 0.10898E-07 -7.9627 0.10000E+01 0.0000 28 C3H8,aq 0.10946E-12 -12.9608 0.10946E-12 -12.9608 0.10000E+01 0.0000 29 C4H10,aq 0.10800E-17 -17.9666 0.10800E-17 -17.9666 0.10000E+01 0.0000 30 ethanol,aq 0.47044E-15 -15.3275 0.47044E-15 -15.3275 0.10000E+01 0.0000 31 CO,aq 0.30584E-13 -13.5145 0.30584E-13 -13.5145 0.10000E+01 0.0000 32 CO2,aq 0.12363E-06 -6.9079 0.12363E-06 -6.9079 0.10000E+01 0.0000 33 CO3-2 0.98536E-03 -3.0064 0.45757E-03 -3.3395 0.46437E+00 -0.3331 34 CaCO3,aq 0.76265E-06 -6.1177 0.76265E-06 -6.1177 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.22943E-08 -8.6393 0.18676E-08 -8.7287 0.81401E+00 -0.0894 36 CaCl+ 0.52336E-09 -9.2812 0.42602E-09 -9.3706 0.81401E+00 -0.0894 37 CaCl2,aq 0.20044E-12 -12.6980 0.20044E-12 -12.6980 0.10000E+01 0.0000 38 CaF+ 0.16150E-11 -11.7918 0.13146E-11 -11.8812 0.81401E+00 -0.0894 39 CaOH+ 0.11072E-06 -6.9558 0.90124E-07 -7.0452 0.81401E+00 -0.0894 40 CaSO4,aq 0.65948E-14 -14.1808 0.65948E-14 -14.1808 0.10000E+01 0.0000 41 HCl,aq 0.38130E-13 -13.4187 0.38130E-13 -13.4187 0.10000E+01 0.0000 45 HF,aq 0.48722E-12 -12.3123 0.48722E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.13724E-18 -18.8625 0.11143E-18 -18.9530 0.81192E+00 -0.0905 48 FeCl+ 0.22856E-15 -15.6410 0.18605E-15 -15.7304 0.81401E+00 -0.0894 51 FeF+ 0.25240E-17 -17.5979 0.20545E-17 -17.6873 0.81401E+00 -0.0894 53 FeO,aq 0.20886E-09 -9.6801 0.20886E-09 -9.6801 0.10000E+01 0.0000 54 FeOH+ 0.22579E-10 -10.6463 0.18380E-10 -10.7357 0.81401E+00 -0.0894 55 HFeO2- 0.25606E-07 -7.5917 0.20790E-07 -7.6821 0.81192E+00 -0.0905 56 FeO+ 0.17166E-16 -16.7653 0.13973E-16 -16.8547 0.81401E+00 -0.0894 58 FeO2- 0.31885E-09 -9.4964 0.25888E-09 -9.5869 0.81192E+00 -0.0905 59 HFeO2,aq 0.34594E-11 -11.4610 0.34594E-11 -11.4610 0.10000E+01 0.0000 60 H2,aq 0.98435E-05 -5.0069 0.98435E-05 -5.0069 0.10000E+01 0.0000 61 KCl,aq 0.65311E-08 -8.1850 0.65311E-08 -8.1850 0.10000E+01 0.0000 63 KOH,aq 0.73924E-06 -6.1312 0.73924E-06 -6.1312 0.10000E+01 0.0000 64 KSO4- 0.54334E-12 -12.2649 0.44115E-12 -12.3554 0.81192E+00 -0.0905 65 MgCO3,aq 0.31403E-10 -10.5030 0.31403E-10 -10.5030 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.38511E-12 -12.4144 0.31348E-12 -12.5038 0.81401E+00 -0.0894 67 MgCl+ 0.77920E-13 -13.1083 0.63428E-13 -13.1977 0.81401E+00 -0.0894 68 MgF+ 0.98273E-15 -15.0076 0.79995E-15 -15.0969 0.81401E+00 -0.0894 69 MgOH+ 0.10064E-09 -9.9972 0.81922E-10 -10.0866 0.81401E+00 -0.0894 71 MnF+ 0.27237E-15 -15.5648 0.22171E-15 -15.6542 0.81401E+00 -0.0894 72 MnO,aq 0.18221E-08 -8.7394 0.18221E-08 -8.7394 0.10000E+01 0.0000 73 MnOH+ 0.68674E-09 -9.1632 0.55901E-09 -9.2526 0.81401E+00 -0.0894 74 MnO2-2 0.11791E-10 -10.9285 0.54753E-11 -11.2616 0.46437E+00 -0.3331 75 HMnO2- 0.15523E-09 -9.8090 0.12603E-09 -9.8995 0.81192E+00 -0.0905 78 MnCl+ 0.29113E-12 -12.5359 0.23698E-12 -12.6253 0.81401E+00 -0.0894 79 MnSO4,aq 0.87649E-18 -18.0573 0.87649E-18 -18.0573 0.10000E+01 0.0000 80 NaCl,aq 0.15125E-04 -4.8203 0.15125E-04 -4.8203 0.10000E+01 0.0000 81 NaF,aq 0.36548E-08 -8.4371 0.36548E-08 -8.4371 0.10000E+01 0.0000 82 NaOH,aq 0.94198E-04 -4.0260 0.94198E-04 -4.0260 0.10000E+01 0.0000 84 OH- 0.67862E-02 -2.1684 0.54965E-02 -2.2599 0.80995E+00 -0.0915 89 HPO3-2 0.84135E-15 -15.0750 0.39070E-15 -15.4082 0.46437E+00 -0.3331 91 H2PO3- 0.10139E-18 -18.9940 0.82318E-19 -19.0845 0.81192E+00 -0.0905 92 H3PO4,aq 0.98293E-18 -18.0075 0.98293E-18 -18.0075 0.10000E+01 0.0000 93 H2PO4- 0.30352E-10 -10.5178 0.24675E-10 -10.6077 0.81296E+00 -0.0899 94 PO4-3 0.51385E-09 -9.2892 0.98858E-10 -10.0050 0.19239E+00 -0.7158 98 HP2O7-3 0.50335E-18 -18.2981 0.90769E-19 -19.0421 0.18033E+00 -0.7439 99 P2O7-4 0.41246E-17 -17.3846 0.20638E-18 -18.6853 0.50037E-01 -1.3007 100 H2S,aq 0.23781E-05 -5.6238 0.23781E-05 -5.6238 0.10000E+01 0.0000 101 S2-2 0.25998E-09 -9.5851 0.12073E-09 -9.9182 0.46437E+00 -0.3331 102 S3-2 0.84619E-16 -16.0725 0.39295E-16 -16.4057 0.46437E+00 -0.3331 107 SO3-2 0.42232E-15 -15.3744 0.19994E-15 -15.6991 0.47344E+00 -0.3247 108 HSO3- 0.16201E-17 -17.7905 0.13154E-17 -17.8810 0.81192E+00 -0.0905 109 HSO4- 0.19409E-16 -16.7120 0.15820E-16 -16.8008 0.81509E+00 -0.0888 111 S2O3-2 0.94030E-17 -17.0267 0.43665E-17 -17.3599 0.46437E+00 -0.3331 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1283599E-09 -.1794050E-01 -.1803671E+02 0.0000 2 H2O 0.1000000E+01 0.5553014E+02 0.9978340E+06 0.0000 3 Cl- 0.2439181E-02 0.2454314E-02 0.8679029E+02 7.2753 4 SO4-- 0.3354900E-09 -.2505217E-01 -.2400398E+04 10.1508 5 HCO3- 0.6765811E-03 0.2671254E-01 0.1625757E+04 6.7192 6 HS- 0.9018049E-02 0.3407260E-01 0.1123968E+04 7.8432 7 Al+++ 0.3455509E-28 0.3776786E-05 0.1016428E+00 0.7295 8 H4SiO4 0.7050949E-03 0.1076303E-01 0.1031848E+04 -3.1518 9 Ca++ 0.2883024E-06 0.1187805E-05 0.4748311E-01 13.0807 10 Mg++ 0.4765377E-10 0.1849266E-09 0.4484439E-05 9.2962 11 Fe++ 0.1293390E-12 0.2616014E-07 0.1457230E-02 6.7305 12 K+ 0.2235976E-03 0.2243434E-03 0.8749843E+01 6.2385 13 Na+ 0.2839238E-01 0.3083840E-01 0.7071557E+03 8.3411 14 Mn++ 0.4229859E-10 0.2718463E-08 0.1489650E-03 9.2456 15 F- 0.8366051E-06 0.8402621E-06 0.1592248E-01 3.8094 16 HPO4-- 0.2733127E-07 0.2787548E-07 0.2668619E-02 12.0619 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277274E+02 -.8942898E-02 -.8276379E+02 0.0000000E+00 2 H2O -.7018156E+01 0.2768041E+02 -.3469857E+02 0.0000000E+00 3 Cl- 0.1223415E-02 0.1223415E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1394711E+00 -.1248789E-01 0.1519590E+00 0.0000000E+00 5 HCO3- 0.1331555E-01 0.1331555E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1349746E+00 0.1698435E-01 -.1519590E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1882635E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5365107E-02 0.5205854E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.5920915E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.9218137E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1304019E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1118297E-03 0.1061459E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1537218E-01 0.6261005E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1355087E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7369600E-04 0.4188500E-06 0.7327715E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1389524E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.2540E-14 Mass of aqueous solution: 0.499753E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1839900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.7 andradite 0.6078 -0.216 308.9 2.490 5.654 80.25 grossular 0.1341 -0.872 60.42 1.781 1.106 16.81 apatite-OH 0.9789E-02 -2.009 4.917 0.692 0.9000E-01 1.563 apatite-F 0.7328E-04 -4.135 0.3695E-01 -1.432 0.6764E-03 0.1154E-01 clinochlore 0.7071 -0.151 393.0 2.594 7.193 149.5 daphnite 0.2017 -0.695 143.9 2.158 2.633 43.60 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9423 -0.026 262.3 2.419 4.800 102.5 stilbite 3.237 0.510 2281. 3.358 41.75 1064. stilpnomelane-Fe 0.2384 -0.623 257.0 2.410 4.703 88.76 tr.625ac.25prg.125 0.1194 -0.923 102.1 2.009 1.868 32.85 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8192E+00 0.8192E+00 1.0000 -0.087 grossular 0.1808E+00 0.1808E+00 1.0000 -0.743 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7635E+00 0.7635E+00 1.0000 -0.117 daphnite 0.2177E+00 0.2177E+00 1.0000 -0.662 chlorite-Mn 0.1872E-01 0.1872E-01 1.0000 -1.728 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5463.573920 g Volume = 2212.328477 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1839900 moles log = -0.7352 Original solution: 1000.0103000 g Original solution / Rock added: 5435.13 (Water/Rock Ratio), log = 3.7352 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 38.8156 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2785E-01 0.9301 0.1006E+01 0.1081E+01 CO2,gas 0.3642E-06 0.9357 0.1323E-04 0.1414E-04 CH4,gas 0.9718E+00 0.9775 0.3687E+02 0.3772E+02 H2,gas 0.3261E-03 1.0209 0.1292E-01 0.1266E-01 H2S,gas 0.1950E-05 0.8636 0.6537E-04 0.7570E-04 S2,gas 0.2474E-25 1.0000 0.9605E-24 0.9605E-24 CO,gas 0.1174E-11 1.0000 0.4558E-10 0.4558E-10 SO3,gas 0.1681E-46 1.0000 0.6524E-45 0.6524E-45 SO2,gas 0.8455E-26 1.0000 0.3282E-24 0.3282E-24 HF,gas 0.3082E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1733E-17 1.0000 0.6728E-16 0.6728E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 117 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 164 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28969E+04 0.002 2 CO2,gas -6.66 -13.24 -6.58 -2.193 0.11231E+05 -4.879 3 CH4,gas 4.54 4.41 -0.13 -0.033 0.22586E+03 1.567 4 H2,gas 8.00 4.41 -3.59 -2.050 0.61257E+04 -1.889 5 H2S,gas -6.23 -12.11 -5.88 -2.942 0.10046E+05 -4.185 6 S2,gas -7.34 -33.05 -25.72 -3.956 0.43910E+05 -24.018 7 CO,gas 3.21 -8.83 -12.04 -3.705 0.20558E+05 -10.341 8 SO3,gas 17.12 -29.76 -46.88 -11.721 0.80054E+05 -45.185 9 SO2,gas 0.83 -25.35 -26.18 -6.982 0.44707E+05 -24.484 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.68 -17.87 -8.936 0.30514E+05 -16.172 12 acmite 7.71 6.56 -1.15 -0.119 0.19590E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80540E+04 21 analcite 3.32 2.77 -0.55 -0.062 0.94690E+03 26 ankerite -2.14 -6.66 -4.53 -0.755 0.77339E+04 27 annite 20.12 17.70 -2.42 -0.134 0.41307E+04 28 phlogopite 27.06 25.40 -1.66 -0.092 0.28399E+04 30 anorthite 12.71 8.24 -4.47 -0.344 0.76396E+04 38 aragonite 0.97 -0.16 -1.12 -0.375 0.19187E+04 39 brucite 12.57 9.30 -3.27 -0.655 0.55881E+04 40 calcite 0.81 -0.16 -0.97 -0.323 0.16545E+04 41 carnegieite-low 9.02 5.92 -3.10 -0.443 0.53008E+04 42 carnegieite-high 10.09 5.92 -4.17 -0.596 0.71277E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70532E+04 44 carpholite-Fe 6.71 1.89 -4.83 -0.322 0.82421E+04 45 celadonite 5.34 3.66 -1.68 -0.099 0.28747E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47541E+04 47 chrysotile 23.89 21.58 -2.31 -0.192 0.39399E+04 52 chlorite-Al-free 47.17 43.17 -4.00 -0.167 0.68349E+04 54 chloritoid-Fe 9.17 5.04 -4.14 -0.276 0.70630E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65718E+04 57 coesite -2.38 -3.15 -0.78 -0.258 0.13238E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10092E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.14 -0.357 0.36619E+04 69 diamond -3.10 -4.41 -1.31 -0.374 0.22377E+04 70 dolomite,ordered 0.55 -4.10 -4.65 -0.774 0.79315E+04 72 enstatite 17.26 12.29 -4.98 -0.498 0.84957E+04 74 clinoenstatite 17.17 12.29 -4.88 -0.488 0.83273E+04 76 epidote 24.67 22.69 -1.98 -0.096 0.33819E+04 77 clinozoisite 22.81 18.89 -3.91 -0.178 0.66791E+04 78 epidote-Fe 29.84 26.48 -3.36 -0.174 0.57313E+04 79 fayalite 14.05 10.31 -3.74 -0.534 0.63800E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68155E+04 84 gibbsite 4.08 0.73 -3.35 -0.479 0.57207E+04 85 glaucophane 22.97 20.82 -2.16 -0.058 0.36837E+04 86 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70955E+04 87 graphite -3.55 -4.41 -0.87 -0.248 0.14799E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38447E+04 91 hematite 12.57 9.05 -3.52 -0.426 0.60068E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.45 -0.145 0.24721E+04 98 kalsilite 7.58 3.82 -3.77 -0.538 0.64332E+04 99 kaolinite -1.33 -4.84 -3.51 -0.319 0.59966E+04 102 laumontite 2.88 1.93 -0.95 -0.063 0.16235E+04 103 lawsonite 9.62 8.24 -1.38 -0.092 0.23569E+04 104 leucite 4.12 0.66 -3.45 -0.345 0.58976E+04 106 lizardite 23.24 21.58 -1.66 -0.138 0.28325E+04 107 magnesite 0.69 -3.94 -4.63 -1.544 0.79094E+04 108 magnetite 20.09 15.78 -4.31 -0.352 0.73572E+04 109 minnesotaite 10.39 7.59 -2.80 -0.165 0.47858E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82176E+04 121 muscovite 2.58 -1.03 -3.61 -0.212 0.61652E+04 122 paragonite 4.24 1.07 -3.17 -0.186 0.54044E+04 123 nepheline 8.34 5.92 -2.42 -0.346 0.41331E+04 129 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83603E+04 135 phlogopite-Na 29.65 27.50 -2.14 -0.119 0.36587E+04 137 prehnite 19.37 18.17 -1.21 -0.071 0.20607E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91845E+03 139 pumpellyite-Fe 46.27 43.79 -2.48 -0.055 0.42348E+04 140 pumpellyite-Mg 48.99 46.35 -2.64 -0.059 0.45075E+04 143 pyrite -21.25 -21.91 -0.66 -0.156 0.11310E+04 144 pyrrhotite -4.26 -5.38 -1.12 -0.374 0.19175E+04 145 pyrrhotiteFe0.875 -6.02 -6.77 -0.75 -0.278 0.12888E+04 146 pyroxmangite 7.40 6.09 -1.30 -0.261 0.22277E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84886E+04 148 quartz -2.99 -3.15 -0.16 -0.054 0.27648E+03 152 rhodochrosite -0.98 -3.99 -3.02 -1.005 0.51496E+04 153 rhodonite 7.45 6.09 -1.35 -0.270 0.23079E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.51 -3.90 -1.300 0.66578E+04 166 stilpnomelane-Mg 27.44 25.85 -1.60 -0.048 0.27248E+04 172 talc 16.49 15.28 -1.21 -0.071 0.20637E+04 175 tephroite 18.09 15.34 -2.75 -0.392 0.46894E+04 179 tridymite -2.63 -3.15 -0.53 -0.175 0.89646E+03 180 tremolite 47.87 47.43 -0.44 -0.012 0.75004E+03 181 ferroactinolite 38.45 34.60 -3.85 -0.104 0.65755E+04 182 troilite-low -4.41 -5.38 -0.97 -0.324 0.16603E+04 188 wairakite 3.95 1.93 -2.02 -0.119 0.34447E+04 189 walstromite 11.51 9.93 -1.58 -0.316 0.26980E+04 190 wollastonite 10.46 9.93 -0.53 -0.106 0.90845E+03 191 pseudo-wollastonite 11.00 9.93 -1.07 -0.214 0.18283E+04 192 zoisite 22.85 18.89 -3.96 -0.180 0.67532E+04 193 akaganeite 7.75 4.52 -3.23 -0.698 0.55161E+04 200 chalcedony -2.80 -3.15 -0.35 -0.116 0.59578E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66100E+04 203 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68723E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.266 0.73532E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60272E+04 206 nontronite-Ca 3.21 -0.12 -3.33 -0.216 0.56911E+04 207 nontronite-H 2.53 -2.28 -4.81 -0.322 0.82122E+04 208 nontronite-K 3.34 -0.22 -3.56 -0.228 0.60766E+04 209 nontronite-Mg 3.07 -0.74 -3.82 -0.248 0.65184E+04 210 nontronite-Na 3.52 0.48 -3.04 -0.195 0.51975E+04 226 tobermorite 9.82 7.74 -2.08 -0.567 0.35492E+04 232 alabandite -0.98 -2.87 -1.89 -0.630 0.32278E+04 235 boehmite 4.41 0.73 -3.68 -0.613 0.62788E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52612E+04 243 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18100E+04 245 an20ab80 2.02 1.34 -0.68 -0.052 0.11571E+04 246 an25ab75 2.65 1.77 -0.87 -0.067 0.14933E+04 247 an30ab70 3.28 2.20 -1.08 -0.083 0.18391E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1839900 MOLES New total amount of reactant added: 0.1879900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1879900 Water: Moles liquid = 0.2767E+02 kg liquid = 0.4985E+00 Moles total = -.7015E+01 kg total = -.1264E+00 Activity = 0.9995 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .2992975E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.1247E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12976E-09 -9.8869 0.10613E-09 -9.9741 0.81792E+00 -0.0873 2 H2O 0.99954E+00 -0.0002 0.99954E+00 -0.0002 3 Cl- 0.24862E-02 -2.6045 0.20169E-02 -2.6953 0.81124E+00 -0.0909 4 SO4-- 0.35851E-09 -9.4455 0.16642E-09 -9.7788 0.46419E+00 -0.3333 5 HCO3- 0.72016E-03 -3.1426 0.58538E-03 -3.2326 0.81285E+00 -0.0900 6 HS- 0.92134E-02 -2.0356 0.74758E-02 -2.1263 0.81140E+00 -0.0908 7 Al+++ 0.35816E-28 -28.4459 0.64008E-29 -29.1938 0.17871E+00 -0.7478 8 H4SiO4 0.70587E-03 -3.1513 0.70587E-03 -3.1513 0.10000E+01 0.0000 9 Ca++ 0.29398E-06 -6.5317 0.13509E-06 -6.8694 0.45953E+00 -0.3377 10 Mg++ 0.48808E-10 -10.3115 0.22289E-10 -10.6519 0.45667E+00 -0.3404 11 Fe++ 0.13231E-12 -12.8784 0.60510E-13 -13.2182 0.45735E+00 -0.3398 12 K+ 0.22572E-03 -3.6464 0.18353E-03 -3.7363 0.81310E+00 -0.0899 13 Na+ 0.28662E-01 -1.5427 0.23245E-01 -1.6337 0.81102E+00 -0.0910 14 Mn++ 0.43291E-10 -10.3636 0.19822E-10 -10.7029 0.45787E+00 -0.3393 15 F- 0.82891E-06 -6.0815 0.67058E-06 -6.1736 0.80898E+00 -0.0921 16 HPO4-- 0.27052E-07 -7.5678 0.12560E-07 -7.9010 0.46428E+00 -0.3332 18 HSiO3- 0.76586E-02 -2.1159 0.62130E-02 -2.2067 0.81124E+00 -0.0909 19 Ca(HSiO3)+ 0.23501E-07 -7.6289 0.19115E-07 -7.7186 0.81334E+00 -0.0897 20 Mg(HSiO3)+ 0.48256E-11 -11.3164 0.39249E-11 -11.4062 0.81334E+00 -0.0897 21 NaHSiO3,aq 0.23358E-02 -2.6316 0.23358E-02 -2.6316 0.10000E+01 0.0000 22 AlO+ 0.95001E-16 -16.0223 0.77269E-16 -16.1120 0.81334E+00 -0.0897 24 HAlO2,aq 0.14492E-09 -9.8389 0.14492E-09 -9.8389 0.10000E+01 0.0000 25 AlO2- 0.37349E-05 -5.4277 0.30225E-05 -5.5196 0.80926E+00 -0.0919 26 CH4,aq 0.25532E-01 -1.5929 0.25532E-01 -1.5929 0.10000E+01 0.0000 27 C2H6,aq 0.11472E-07 -7.9404 0.11472E-07 -7.9404 0.10000E+01 0.0000 28 C3H8,aq 0.11900E-12 -12.9245 0.11900E-12 -12.9245 0.10000E+01 0.0000 29 C4H10,aq 0.12126E-17 -17.9163 0.12126E-17 -17.9163 0.10000E+01 0.0000 30 ethanol,aq 0.50177E-15 -15.2995 0.50177E-15 -15.2995 0.10000E+01 0.0000 31 CO,aq 0.32428E-13 -13.4891 0.32428E-13 -13.4891 0.10000E+01 0.0000 32 CO2,aq 0.13282E-06 -6.8768 0.13282E-06 -6.8768 0.10000E+01 0.0000 33 CO3-2 0.10408E-02 -2.9826 0.48176E-03 -3.3172 0.46286E+00 -0.3346 34 CaCO3,aq 0.81606E-06 -6.0883 0.81606E-06 -6.0883 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.24819E-08 -8.6052 0.20186E-08 -8.6949 0.81334E+00 -0.0897 36 CaCl+ 0.54214E-09 -9.2659 0.44095E-09 -9.3556 0.81334E+00 -0.0897 37 CaCl2,aq 0.21129E-12 -12.6751 0.21129E-12 -12.6751 0.10000E+01 0.0000 38 CaF+ 0.16262E-11 -11.7888 0.13226E-11 -11.8786 0.81334E+00 -0.0897 39 CaOH+ 0.11148E-06 -6.9528 0.90674E-07 -7.0425 0.81334E+00 -0.0897 40 CaSO4,aq 0.71390E-14 -14.1464 0.71390E-14 -14.1464 0.10000E+01 0.0000 41 HCl,aq 0.39226E-13 -13.4064 0.39226E-13 -13.4064 0.10000E+01 0.0000 45 HF,aq 0.48722E-12 -12.3123 0.48722E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.13597E-18 -18.8665 0.11031E-18 -18.9574 0.81124E+00 -0.0909 48 FeCl+ 0.23751E-15 -15.6243 0.19317E-15 -15.7140 0.81334E+00 -0.0897 51 FeF+ 0.25494E-17 -17.5936 0.20735E-17 -17.6833 0.81334E+00 -0.0897 53 FeO,aq 0.20868E-09 -9.6805 0.20868E-09 -9.6805 0.10000E+01 0.0000 54 FeOH+ 0.22807E-10 -10.6419 0.18550E-10 -10.7317 0.81334E+00 -0.0897 55 HFeO2- 0.25348E-07 -7.5961 0.20563E-07 -7.6869 0.81124E+00 -0.0909 56 FeO+ 0.17453E-16 -16.7581 0.14195E-16 -16.8479 0.81334E+00 -0.0897 58 FeO2- 0.31772E-09 -9.4980 0.25774E-09 -9.5888 0.81124E+00 -0.0909 59 HFeO2,aq 0.34792E-11 -11.4585 0.34792E-11 -11.4585 0.10000E+01 0.0000 60 H2,aq 0.97148E-05 -5.0126 0.97148E-05 -5.0126 0.10000E+01 0.0000 61 KCl,aq 0.67090E-08 -8.1733 0.67090E-08 -8.1733 0.10000E+01 0.0000 63 KOH,aq 0.73815E-06 -6.1319 0.73815E-06 -6.1319 0.10000E+01 0.0000 64 KSO4- 0.58423E-12 -12.2334 0.47395E-12 -12.3243 0.81124E+00 -0.0909 65 MgCO3,aq 0.33749E-10 -10.4717 0.33749E-10 -10.4717 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.41842E-12 -12.3784 0.34032E-12 -12.4681 0.81334E+00 -0.0897 67 MgCl+ 0.81071E-13 -13.0911 0.65939E-13 -13.1809 0.81334E+00 -0.0897 68 MgF+ 0.99388E-15 -15.0027 0.80836E-15 -15.0924 0.81334E+00 -0.0897 69 MgOH+ 0.10178E-09 -9.9923 0.82784E-10 -10.0821 0.81334E+00 -0.0897 71 MnF+ 0.27526E-15 -15.5602 0.22388E-15 -15.6500 0.81334E+00 -0.0897 72 MnO,aq 0.18215E-08 -8.7396 0.18215E-08 -8.7396 0.10000E+01 0.0000 73 MnOH+ 0.69403E-09 -9.1586 0.56448E-09 -9.2483 0.81334E+00 -0.0897 74 MnO2-2 0.11589E-10 -10.9360 0.53640E-11 -11.2705 0.46286E+00 -0.3346 75 HMnO2- 0.15375E-09 -9.8132 0.12473E-09 -9.9040 0.81124E+00 -0.0909 78 MnCl+ 0.30269E-12 -12.5190 0.24619E-12 -12.6087 0.81334E+00 -0.0897 79 MnSO4,aq 0.95230E-18 -18.0212 0.95230E-18 -18.0212 0.10000E+01 0.0000 80 NaCl,aq 0.15538E-04 -4.8086 0.15538E-04 -4.8086 0.10000E+01 0.0000 81 NaF,aq 0.36494E-08 -8.4378 0.36494E-08 -8.4378 0.10000E+01 0.0000 82 NaOH,aq 0.94059E-04 -4.0266 0.94059E-04 -4.0266 0.10000E+01 0.0000 84 OH- 0.67238E-02 -2.1724 0.54413E-02 -2.2643 0.80926E+00 -0.0919 89 HPO3-2 0.82190E-15 -15.0852 0.38042E-15 -15.4197 0.46286E+00 -0.3346 91 H2PO3- 0.99804E-19 -19.0009 0.80965E-19 -19.0917 0.81124E+00 -0.0909 92 H3PO4,aq 0.98950E-18 -18.0046 0.98950E-18 -18.0046 0.10000E+01 0.0000 93 H2PO4- 0.30274E-10 -10.5189 0.24591E-10 -10.6092 0.81228E+00 -0.0903 94 PO4-3 0.50534E-09 -9.2964 0.96553E-10 -10.0152 0.19106E+00 -0.7188 98 HP2O7-3 0.49859E-18 -18.3023 0.89246E-19 -19.0494 0.17900E+00 -0.7472 99 P2O7-4 0.40668E-17 -17.3908 0.20088E-18 -18.6971 0.49396E-01 -1.3063 100 H2S,aq 0.24522E-05 -5.6104 0.24522E-05 -5.6104 0.10000E+01 0.0000 101 S2-2 0.27540E-09 -9.5600 0.12747E-09 -9.8946 0.46286E+00 -0.3346 102 S3-2 0.93656E-16 -16.0285 0.43349E-16 -16.3630 0.46286E+00 -0.3346 107 SO3-2 0.44534E-15 -15.3513 0.21019E-15 -15.6774 0.47197E+00 -0.3261 108 HSO3- 0.17218E-17 -17.7640 0.13968E-17 -17.8549 0.81124E+00 -0.0909 109 HSO4- 0.20900E-16 -16.6799 0.17022E-16 -16.7690 0.81444E+00 -0.0891 111 S2O3-2 0.10362E-16 -16.9846 0.47959E-17 -17.3191 0.46286E+00 -0.3346 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1297611E-09 -.1786974E-01 -.1796517E+02 0.0000 2 H2O 0.1000000E+01 0.5553062E+02 0.9978205E+06 0.0000 3 Cl- 0.2486239E-02 0.2501784E-02 0.8846697E+02 7.2788 4 SO4-- 0.3585065E-09 -.2553456E-01 -.2446564E+04 10.1695 5 HCO3- 0.7201554E-03 0.2729408E-01 0.1661113E+04 6.7416 6 HS- 0.9213431E-02 0.3475045E-01 0.1146303E+04 7.8478 7 Al+++ 0.3581615E-28 0.3735060E-05 0.1005176E+00 0.7287 8 H4SiO4 0.7058703E-03 0.1070035E-01 0.1025816E+04 -3.1513 9 Ca++ 0.2939819E-06 0.1248052E-05 0.4989042E-01 13.0789 10 Mg++ 0.4880819E-10 0.1896650E-09 0.4599242E-05 9.2964 11 Fe++ 0.1323050E-12 0.2590083E-07 0.1442753E-02 6.7301 12 K+ 0.2257173E-03 0.2264622E-03 0.8832283E+01 6.2379 13 Na+ 0.2866215E-01 0.3110759E-01 0.7133127E+03 8.3405 14 Mn++ 0.4329142E-10 0.2724451E-08 0.1492898E-03 9.2454 15 F- 0.8289132E-06 0.8325647E-06 0.1577627E-01 3.8006 16 HPO4-- 0.2705210E-07 0.2758771E-07 0.2641011E-02 12.0473 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277231E+02 -.8907179E-02 -.8276340E+02 0.0000000E+00 2 H2O -.7014881E+01 0.2767926E+02 -.3469414E+02 0.0000000E+00 3 Cl- 0.1247015E-02 0.1247015E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1394902E+00 -.1272771E-01 0.1522179E+00 0.0000000E+00 5 HCO3- 0.1360475E-01 0.1360475E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1348965E+00 0.1732138E-01 -.1522179E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1861742E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5333593E-02 0.5205857E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.6220921E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.9453860E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1291028E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1128802E-03 0.1061458E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1550559E-01 0.6260871E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1358004E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7529600E-04 0.4149922E-06 0.7488101E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1375111E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.9742E-14 Mass of aqueous solution: 0.499739E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1879900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.7 andradite 0.6089 -0.215 309.4 2.491 5.663 80.39 grossular 0.1333 -0.875 60.06 1.779 1.099 16.71 apatite-OH 0.9788E-02 -2.009 4.917 0.692 0.8999E-01 1.562 apatite-F 0.7488E-04 -4.126 0.3776E-01 -1.423 0.6912E-03 0.1180E-01 clinochlore 0.7076 -0.150 393.3 2.595 7.198 149.6 daphnite 0.2015 -0.696 143.8 2.158 2.632 43.58 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9423 -0.026 262.3 2.419 4.801 102.5 stilbite 3.237 0.510 2281. 3.358 41.76 1064. stilpnomelane-Fe 0.2382 -0.623 256.8 2.410 4.701 88.71 tr.625ac.25prg.125 0.1187 -0.926 101.5 2.006 1.857 32.66 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8203E+00 0.8203E+00 1.0000 -0.086 grossular 0.1797E+00 0.1797E+00 1.0000 -0.746 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7637E+00 0.7637E+00 1.0000 -0.117 daphnite 0.2175E+00 0.2175E+00 1.0000 -0.662 chlorite-Mn 0.1871E-01 0.1871E-01 1.0000 -1.728 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5463.670243 g Volume = 2212.422574 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1879900 moles log = -0.7259 Original solution: 1000.0103000 g Original solution / Rock added: 5319.49 (Water/Rock Ratio), log = 3.7259 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 39.5591 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2735E-01 0.9292 0.1006E+01 0.1082E+01 CO2,gas 0.3843E-06 0.9346 0.1421E-04 0.1520E-04 CH4,gas 0.9723E+00 0.9770 0.3758E+02 0.3846E+02 H2,gas 0.3157E-03 1.0213 0.1275E-01 0.1249E-01 H2S,gas 0.1978E-05 0.8613 0.6741E-04 0.7827E-04 S2,gas 0.2650E-25 1.0000 0.1048E-23 0.1048E-23 CO,gas 0.1222E-11 1.0000 0.4832E-10 0.4832E-10 SO3,gas 0.1793E-46 1.0000 0.7091E-45 0.7091E-45 SO2,gas 0.8899E-26 1.0000 0.3520E-24 0.3520E-24 HF,gas 0.3024E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1750E-17 1.0000 0.6922E-16 0.6922E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 117 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 164 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28969E+04 0.002 2 CO2,gas -6.66 -13.21 -6.55 -2.182 0.11178E+05 -4.847 3 CH4,gas 4.54 4.42 -0.12 -0.031 0.21172E+03 1.575 4 H2,gas 8.00 4.41 -3.59 -2.053 0.61355E+04 -1.894 5 H2S,gas -6.23 -12.10 -5.87 -2.935 0.10023E+05 -4.171 6 S2,gas -7.34 -33.01 -25.68 -3.951 0.43845E+05 -23.979 7 CO,gas 3.21 -8.80 -12.01 -3.697 0.20515E+05 -10.316 8 SO3,gas 17.12 -29.73 -46.85 -11.712 0.79992E+05 -45.149 9 SO2,gas 0.83 -25.32 -26.15 -6.974 0.44654E+05 -24.453 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.67 -17.86 -8.929 0.30493E+05 -16.160 12 acmite 7.71 6.57 -1.14 -0.119 0.19542E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80550E+04 21 analcite 3.32 2.77 -0.56 -0.062 0.94774E+03 26 ankerite -2.14 -6.60 -4.47 -0.745 0.76312E+04 27 annite 20.12 17.70 -2.42 -0.134 0.41327E+04 28 phlogopite 27.06 25.40 -1.66 -0.092 0.28391E+04 30 anorthite 12.71 8.23 -4.48 -0.344 0.76437E+04 38 aragonite 0.97 -0.13 -1.09 -0.365 0.18685E+04 39 brucite 12.57 9.30 -3.27 -0.655 0.55878E+04 40 calcite 0.81 -0.13 -0.94 -0.313 0.16043E+04 41 carnegieite-low 9.02 5.92 -3.11 -0.444 0.53024E+04 42 carnegieite-high 10.09 5.92 -4.18 -0.596 0.71294E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70541E+04 44 carpholite-Fe 6.71 1.88 -4.83 -0.322 0.82439E+04 45 celadonite 5.34 3.66 -1.68 -0.099 0.28736E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47539E+04 47 chrysotile 23.89 21.59 -2.31 -0.192 0.39374E+04 52 chlorite-Al-free 47.17 43.17 -4.00 -0.167 0.68300E+04 54 chloritoid-Fe 9.17 5.04 -4.14 -0.276 0.70656E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65741E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13230E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10083E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36633E+04 69 diamond -3.10 -4.39 -1.29 -0.369 0.22040E+04 70 dolomite,ordered 0.55 -4.04 -4.58 -0.764 0.78279E+04 72 enstatite 17.26 12.29 -4.97 -0.497 0.84934E+04 74 clinoenstatite 17.17 12.29 -4.88 -0.488 0.83250E+04 76 epidote 24.67 22.69 -1.98 -0.096 0.33839E+04 77 clinozoisite 22.81 18.89 -3.92 -0.178 0.66868E+04 78 epidote-Fe 29.84 26.49 -3.35 -0.174 0.57277E+04 79 fayalite 14.05 10.31 -3.74 -0.534 0.63804E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68152E+04 84 gibbsite 4.08 0.73 -3.35 -0.479 0.57221E+04 85 glaucophane 22.97 20.82 -2.16 -0.058 0.36812E+04 86 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70958E+04 87 graphite -3.55 -4.39 -0.85 -0.242 0.14463E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38451E+04 91 hematite 12.57 9.05 -3.51 -0.426 0.59983E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.45 -0.145 0.24729E+04 98 kalsilite 7.58 3.82 -3.77 -0.538 0.64349E+04 99 kaolinite -1.33 -4.85 -3.51 -0.319 0.59977E+04 102 laumontite 2.88 1.93 -0.95 -0.063 0.16259E+04 103 lawsonite 9.62 8.23 -1.38 -0.092 0.23610E+04 104 leucite 4.12 0.66 -3.45 -0.345 0.58984E+04 106 lizardite 23.24 21.59 -1.66 -0.138 0.28300E+04 107 magnesite 0.69 -3.91 -4.60 -1.534 0.78559E+04 108 magnetite 20.09 15.78 -4.30 -0.351 0.73495E+04 109 minnesotaite 10.39 7.59 -2.80 -0.165 0.47844E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82179E+04 121 muscovite 2.58 -1.03 -3.61 -0.212 0.61680E+04 122 paragonite 4.24 1.07 -3.17 -0.186 0.54071E+04 123 nepheline 8.34 5.92 -2.42 -0.346 0.41348E+04 129 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83609E+04 135 phlogopite-Na 29.65 27.50 -2.14 -0.119 0.36579E+04 137 prehnite 19.37 18.16 -1.21 -0.071 0.20669E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91908E+03 139 pumpellyite-Fe 46.27 43.78 -2.49 -0.055 0.42494E+04 140 pumpellyite-Mg 48.99 46.35 -2.65 -0.059 0.45212E+04 143 pyrite -21.25 -21.88 -0.63 -0.148 0.10764E+04 144 pyrrhotite -4.26 -5.37 -1.11 -0.370 0.18954E+04 145 pyrrhotiteFe0.875 -6.02 -6.76 -0.74 -0.273 0.12654E+04 146 pyroxmangite 7.40 6.09 -1.30 -0.261 0.22271E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84881E+04 148 quartz -2.99 -3.15 -0.16 -0.054 0.27566E+03 152 rhodochrosite -0.98 -3.96 -2.98 -0.995 0.50967E+04 153 rhodonite 7.45 6.09 -1.35 -0.270 0.23073E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.48 -3.87 -1.289 0.66053E+04 166 stilpnomelane-Mg 27.44 25.85 -1.59 -0.048 0.27202E+04 172 talc 16.49 15.28 -1.21 -0.071 0.20596E+04 175 tephroite 18.09 15.34 -2.75 -0.392 0.46891E+04 179 tridymite -2.63 -3.15 -0.52 -0.175 0.89563E+03 180 tremolite 47.87 47.43 -0.44 -0.012 0.74798E+03 181 ferroactinolite 38.45 34.60 -3.85 -0.104 0.65781E+04 182 troilite-low -4.41 -5.37 -0.96 -0.320 0.16382E+04 188 wairakite 3.95 1.93 -2.02 -0.119 0.34472E+04 189 walstromite 11.51 9.93 -1.58 -0.316 0.27002E+04 190 wollastonite 10.46 9.93 -0.53 -0.107 0.91059E+03 191 pseudo-wollastonite 11.00 9.93 -1.07 -0.214 0.18304E+04 192 zoisite 22.85 18.89 -3.96 -0.180 0.67608E+04 193 akaganeite 7.75 4.53 -3.23 -0.698 0.55119E+04 200 chalcedony -2.80 -3.15 -0.35 -0.116 0.59495E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66094E+04 203 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68715E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.266 0.73521E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60264E+04 206 nontronite-Ca 3.21 -0.11 -3.33 -0.216 0.56806E+04 207 nontronite-H 2.53 -2.27 -4.80 -0.322 0.82012E+04 208 nontronite-K 3.34 -0.21 -3.55 -0.228 0.60660E+04 209 nontronite-Mg 3.07 -0.74 -3.81 -0.247 0.65074E+04 210 nontronite-Na 3.52 0.48 -3.04 -0.195 0.51868E+04 226 tobermorite 9.82 7.74 -2.08 -0.567 0.35509E+04 232 alabandite -0.98 -2.86 -1.88 -0.626 0.32052E+04 235 boehmite 4.41 0.73 -3.68 -0.613 0.62802E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.770 0.52619E+04 243 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18091E+04 245 an20ab80 2.02 1.34 -0.68 -0.052 0.11579E+04 246 an25ab75 2.65 1.77 -0.88 -0.067 0.14943E+04 247 an30ab70 3.28 2.20 -1.08 -0.083 0.18404E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1879900 MOLES New total amount of reactant added: 0.1919900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8668E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1919900 Water: Moles liquid = 0.2767E+02 kg liquid = 0.4984E+00 Moles total = -.7012E+01 kg total = -.1263E+00 Activity = 0.9995 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3026546E-01 Chg. balance for total moles = -.8668E-10 Max. difference allowed = 0.1271E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13119E-09 -9.8821 0.10722E-09 -9.9697 0.81728E+00 -0.0876 2 H2O 0.99953E+00 -0.0002 0.99953E+00 -0.0002 3 Cl- 0.25333E-02 -2.5963 0.20534E-02 -2.6875 0.81055E+00 -0.0912 4 SO4-- 0.38282E-09 -9.4170 0.17712E-09 -9.7517 0.46266E+00 -0.3347 5 HCO3- 0.76589E-03 -3.1158 0.62204E-03 -3.2062 0.81218E+00 -0.0903 6 HS- 0.94088E-02 -2.0265 0.76278E-02 -2.1176 0.81071E+00 -0.0911 7 Al+++ 0.37140E-28 -28.4302 0.65872E-29 -29.1813 0.17736E+00 -0.7511 8 H4SiO4 0.70664E-03 -3.1508 0.70664E-03 -3.1508 0.10000E+01 0.0000 9 Ca++ 0.29986E-06 -6.5231 0.13733E-06 -6.8622 0.45797E+00 -0.3392 10 Mg++ 0.50004E-10 -10.3010 0.22757E-10 -10.6429 0.45510E+00 -0.3419 11 Fe++ 0.13538E-12 -12.8685 0.61702E-13 -13.2097 0.45578E+00 -0.3412 12 K+ 0.22789E-03 -3.6423 0.18514E-03 -3.7325 0.81243E+00 -0.0902 13 Na+ 0.28938E-01 -1.5385 0.23449E-01 -1.6299 0.81032E+00 -0.0913 14 Mn++ 0.44320E-10 -10.3534 0.20223E-10 -10.6941 0.45630E+00 -0.3407 15 F- 0.82122E-06 -6.0855 0.66377E-06 -6.1780 0.80828E+00 -0.0924 16 HPO4-- 0.26771E-07 -7.5723 0.12388E-07 -7.9070 0.46275E+00 -0.3346 18 HSiO3- 0.75958E-02 -2.1194 0.61567E-02 -2.2106 0.81055E+00 -0.0912 19 Ca(HSiO3)+ 0.23693E-07 -7.6254 0.19255E-07 -7.7155 0.81267E+00 -0.0901 20 Mg(HSiO3)+ 0.48864E-11 -11.3110 0.39710E-11 -11.4011 0.81267E+00 -0.0901 21 NaHSiO3,aq 0.23350E-02 -2.6317 0.23350E-02 -2.6317 0.10000E+01 0.0000 22 AlO+ 0.95875E-16 -16.0183 0.77915E-16 -16.1084 0.81267E+00 -0.0901 24 HAlO2,aq 0.14465E-09 -9.8397 0.14465E-09 -9.8397 0.10000E+01 0.0000 25 AlO2- 0.36933E-05 -5.4326 0.29863E-05 -5.5249 0.80855E+00 -0.0923 26 CH4,aq 0.26010E-01 -1.5849 0.26010E-01 -1.5849 0.10000E+01 0.0000 27 C2H6,aq 0.12062E-07 -7.9186 0.12062E-07 -7.9186 0.10000E+01 0.0000 28 C3H8,aq 0.12915E-12 -12.8889 0.12915E-12 -12.8889 0.10000E+01 0.0000 29 C4H10,aq 0.13584E-17 -17.8670 0.13584E-17 -17.8670 0.10000E+01 0.0000 30 ethanol,aq 0.53456E-15 -15.2720 0.53456E-15 -15.2720 0.10000E+01 0.0000 31 CO,aq 0.34359E-13 -13.4640 0.34359E-13 -13.4640 0.10000E+01 0.0000 32 CO2,aq 0.14258E-06 -6.8459 0.14258E-06 -6.8459 0.10000E+01 0.0000 33 CO3-2 0.10984E-02 -2.9592 0.50673E-03 -3.2952 0.46132E+00 -0.3360 34 CaCO3,aq 0.87256E-06 -6.0592 0.87256E-06 -6.0592 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.26831E-08 -8.5714 0.21805E-08 -8.6614 0.81267E+00 -0.0901 36 CaCl+ 0.56152E-09 -9.2506 0.45633E-09 -9.3407 0.81267E+00 -0.0901 37 CaCl2,aq 0.22261E-12 -12.6524 0.22261E-12 -12.6524 0.10000E+01 0.0000 38 CaF+ 0.16376E-11 -11.7858 0.13309E-11 -11.8759 0.81267E+00 -0.0901 39 CaOH+ 0.11227E-06 -6.9497 0.91238E-07 -7.0398 0.81267E+00 -0.0901 40 CaSO4,aq 0.77236E-14 -14.1122 0.77236E-14 -14.1122 0.10000E+01 0.0000 41 HCl,aq 0.40344E-13 -13.3942 0.40344E-13 -13.3942 0.10000E+01 0.0000 45 HF,aq 0.48721E-12 -12.3123 0.48721E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.13471E-18 -18.8706 0.10919E-18 -18.9618 0.81055E+00 -0.0912 48 FeCl+ 0.24677E-15 -15.6077 0.20054E-15 -15.6978 0.81267E+00 -0.0901 51 FeF+ 0.25754E-17 -17.5892 0.20929E-17 -17.6792 0.81267E+00 -0.0901 53 FeO,aq 0.20850E-09 -9.6809 0.20850E-09 -9.6809 0.10000E+01 0.0000 54 FeOH+ 0.23039E-10 -10.6375 0.18723E-10 -10.7276 0.81267E+00 -0.0901 55 HFeO2- 0.25090E-07 -7.6005 0.20337E-07 -7.6917 0.81055E+00 -0.0912 56 FeO+ 0.17747E-16 -16.7509 0.14422E-16 -16.8410 0.81267E+00 -0.0901 58 FeO2- 0.31655E-09 -9.4996 0.25658E-09 -9.5908 0.81055E+00 -0.0912 59 HFeO2,aq 0.34989E-11 -11.4561 0.34989E-11 -11.4561 0.10000E+01 0.0000 60 H2,aq 0.95884E-05 -5.0183 0.95884E-05 -5.0183 0.10000E+01 0.0000 61 KCl,aq 0.68901E-08 -8.1618 0.68901E-08 -8.1618 0.10000E+01 0.0000 63 KOH,aq 0.73706E-06 -6.1325 0.73706E-06 -6.1325 0.10000E+01 0.0000 64 KSO4- 0.62778E-12 -12.2022 0.50884E-12 -12.2934 0.81055E+00 -0.0912 65 MgCO3,aq 0.36244E-10 -10.4408 0.36244E-10 -10.4408 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.45433E-12 -12.3426 0.36922E-12 -12.4327 0.81267E+00 -0.0901 67 MgCl+ 0.84337E-13 -13.0740 0.68538E-13 -13.1641 0.81267E+00 -0.0901 68 MgF+ 0.10053E-14 -14.9977 0.81695E-15 -15.0878 0.81267E+00 -0.0901 69 MgOH+ 0.10295E-09 -9.9874 0.83663E-10 -10.0775 0.81267E+00 -0.0901 71 MnF+ 0.27822E-15 -15.5556 0.22610E-15 -15.6457 0.81267E+00 -0.0901 72 MnO,aq 0.18209E-08 -8.7397 0.18209E-08 -8.7397 0.10000E+01 0.0000 73 MnOH+ 0.70149E-09 -9.1540 0.57008E-09 -9.2441 0.81267E+00 -0.0901 74 MnO2-2 0.11389E-10 -10.9435 0.52540E-11 -11.2795 0.46132E+00 -0.3360 75 HMnO2- 0.15227E-09 -9.8174 0.12342E-09 -9.9086 0.81055E+00 -0.0912 78 MnCl+ 0.31466E-12 -12.5022 0.25571E-12 -12.5923 0.81267E+00 -0.0901 79 MnSO4,aq 0.10341E-17 -17.9855 0.10341E-17 -17.9855 0.10000E+01 0.0000 80 NaCl,aq 0.15957E-04 -4.7971 0.15957E-04 -4.7971 0.10000E+01 0.0000 81 NaF,aq 0.36440E-08 -8.4384 0.36440E-08 -8.4384 0.10000E+01 0.0000 82 NaOH,aq 0.93920E-04 -4.0272 0.93920E-04 -4.0272 0.10000E+01 0.0000 84 OH- 0.66614E-02 -2.1764 0.53861E-02 -2.2687 0.80855E+00 -0.0923 89 HPO3-2 0.80280E-15 -15.0954 0.37035E-15 -15.4314 0.46132E+00 -0.3360 91 H2PO3- 0.98241E-19 -19.0077 0.79629E-19 -19.0989 0.81055E+00 -0.0912 92 H3PO4,aq 0.99609E-18 -18.0017 0.99609E-18 -18.0017 0.10000E+01 0.0000 93 H2PO4- 0.30192E-10 -10.5201 0.24504E-10 -10.6108 0.81160E+00 -0.0907 94 PO4-3 0.49687E-09 -9.3038 0.94269E-10 -10.0256 0.18973E+00 -0.7219 98 HP2O7-3 0.49376E-18 -18.3065 0.87717E-19 -19.0569 0.17765E+00 -0.7504 99 P2O7-4 0.40088E-17 -17.3970 0.19544E-18 -18.7090 0.48753E-01 -1.3120 100 H2S,aq 0.25277E-05 -5.5973 0.25277E-05 -5.5973 0.10000E+01 0.0000 101 S2-2 0.29146E-09 -9.5354 0.13446E-09 -9.8714 0.46132E+00 -0.3360 102 S3-2 0.10352E-15 -15.9850 0.47755E-16 -16.3210 0.46132E+00 -0.3360 107 SO3-2 0.46929E-15 -15.3286 0.22079E-15 -15.6560 0.47048E+00 -0.3275 108 HSO3- 0.18287E-17 -17.7379 0.14822E-17 -17.8291 0.81055E+00 -0.0912 109 HSO4- 0.22490E-16 -16.6480 0.18302E-16 -16.7375 0.81377E+00 -0.0895 111 S2O3-2 0.11405E-16 -16.9429 0.52615E-17 -17.2789 0.46132E+00 -0.3360 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1311931E-09 -.1780088E-01 -.1789554E+02 0.0000 2 H2O 0.1000000E+01 0.5553110E+02 0.9978066E+06 0.0000 3 Cl- 0.2533292E-02 0.2549256E-02 0.9014364E+02 7.2822 4 SO4-- 0.3828174E-09 -.2601270E-01 -.2492320E+04 10.1877 5 HCO3- 0.7658897E-03 0.2787566E-01 0.1696469E+04 6.7635 6 HS- 0.9408824E-02 0.3542405E-01 0.1168496E+04 7.8521 7 Al+++ 0.3713991E-28 0.3693479E-05 0.9939634E-01 0.7279 8 H4SiO4 0.7066444E-03 0.1063746E-01 0.1019764E+04 -3.1508 9 Ca++ 0.2998569E-06 0.1311627E-05 0.5243060E-01 13.0772 10 Mg++ 0.5000395E-10 0.1946211E-09 0.4719317E-05 9.2966 11 Fe++ 0.1353758E-12 0.2564187E-07 0.1428296E-02 6.7297 12 K+ 0.2278852E-03 0.2286291E-03 0.8916596E+01 6.2372 13 Na+ 0.2893806E-01 0.3138294E-01 0.7196104E+03 8.3398 14 Mn++ 0.4431964E-10 0.2730650E-08 0.1496261E-03 9.2453 15 F- 0.8212178E-06 0.8248639E-06 0.1562999E-01 3.7917 16 HPO4-- 0.2677114E-07 0.2729820E-07 0.2613237E-02 12.0325 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277187E+02 -.8872419E-02 -.8276300E+02 0.0000000E+00 2 H2O -.7011607E+01 0.2767814E+02 -.3468974E+02 0.0000000E+00 3 Cl- 0.1270615E-02 0.1270615E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1395093E+00 -.1296540E-01 0.1524747E+00 0.0000000E+00 5 HCO3- 0.1389395E-01 0.1389395E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1348184E+00 0.1765626E-01 -.1524747E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1840926E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5301986E-02 0.5205860E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.6537486E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.9700418E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1278057E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1139547E-03 0.1061457E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1564207E-01 0.6260735E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1361026E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7689600E-04 0.4111335E-06 0.7648487E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1360613E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1243E-13 Mass of aqueous solution: 0.499726E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1919900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.7 andradite 0.6099 -0.215 309.9 2.491 5.673 80.52 grossular 0.1326 -0.878 59.71 1.776 1.093 16.61 apatite-OH 0.9786E-02 -2.009 4.916 0.692 0.8997E-01 1.562 apatite-F 0.7648E-04 -4.116 0.3857E-01 -1.414 0.7060E-03 0.1205E-01 clinochlore 0.7081 -0.150 393.6 2.595 7.203 149.7 daphnite 0.2014 -0.696 143.7 2.158 2.631 43.55 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9424 -0.026 262.3 2.419 4.801 102.5 stilbite 3.238 0.510 2282. 3.358 41.76 1064. stilpnomelane-Fe 0.2381 -0.623 256.7 2.409 4.698 88.66 tr.625ac.25prg.125 0.1180 -0.928 100.9 2.004 1.846 32.47 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8215E+00 0.8215E+00 1.0000 -0.085 grossular 0.1785E+00 0.1785E+00 1.0000 -0.748 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7640E+00 0.7640E+00 1.0000 -0.117 daphnite 0.2173E+00 0.2173E+00 1.0000 -0.663 chlorite-Mn 0.1871E-01 0.1871E-01 1.0000 -1.728 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5463.765977 g Volume = 2212.516126 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1919900 moles log = -0.7167 Original solution: 1000.0103000 g Original solution / Rock added: 5208.66 (Water/Rock Ratio), log = 3.7167 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 40.2966 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2688E-01 0.9283 0.1005E+01 0.1083E+01 CO2,gas 0.4055E-06 0.9336 0.1525E-04 0.1634E-04 CH4,gas 0.9728E+00 0.9766 0.3829E+02 0.3920E+02 H2,gas 0.3058E-03 1.0217 0.1259E-01 0.1232E-01 H2S,gas 0.2007E-05 0.8590 0.6948E-04 0.8089E-04 S2,gas 0.2838E-25 1.0000 0.1144E-23 0.1144E-23 CO,gas 0.1271E-11 1.0000 0.5120E-10 0.5120E-10 SO3,gas 0.1911E-46 1.0000 0.7702E-45 0.7702E-45 SO2,gas 0.9366E-26 1.0000 0.3774E-24 0.3774E-24 HF,gas 0.2969E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1767E-17 1.0000 0.7119E-16 0.7119E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 117 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 164 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28969E+04 0.002 2 CO2,gas -6.66 -13.18 -6.52 -2.172 0.11125E+05 -4.817 3 CH4,gas 4.54 4.43 -0.12 -0.029 0.19796E+03 1.583 4 H2,gas 8.00 4.40 -3.60 -2.057 0.61452E+04 -1.900 5 H2S,gas -6.23 -12.09 -5.86 -2.929 0.10001E+05 -4.158 6 S2,gas -7.34 -32.98 -25.64 -3.945 0.43781E+05 -23.942 7 CO,gas 3.21 -8.77 -11.99 -3.689 0.20472E+05 -10.291 8 SO3,gas 17.12 -29.69 -46.81 -11.703 0.79931E+05 -45.113 9 SO2,gas 0.83 -25.29 -26.12 -6.966 0.44603E+05 -24.423 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.66 -17.85 -8.923 0.30473E+05 -16.148 12 acmite 7.71 6.57 -1.14 -0.119 0.19494E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80561E+04 21 analcite 3.32 2.77 -0.56 -0.062 0.94857E+03 26 ankerite -2.14 -6.54 -4.41 -0.735 0.75296E+04 27 annite 20.12 17.70 -2.42 -0.135 0.41346E+04 28 phlogopite 27.06 25.40 -1.66 -0.092 0.28382E+04 30 anorthite 12.71 8.23 -4.48 -0.345 0.76477E+04 38 aragonite 0.97 -0.10 -1.07 -0.355 0.18188E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55876E+04 40 calcite 0.81 -0.10 -0.91 -0.303 0.15546E+04 41 carnegieite-low 9.02 5.92 -3.11 -0.444 0.53041E+04 42 carnegieite-high 10.09 5.92 -4.18 -0.597 0.71311E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70549E+04 44 carpholite-Fe 6.71 1.88 -4.83 -0.322 0.82457E+04 45 celadonite 5.34 3.66 -1.68 -0.099 0.28726E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47537E+04 47 chrysotile 23.89 21.59 -2.30 -0.192 0.39349E+04 52 chlorite-Al-free 47.17 43.18 -4.00 -0.167 0.68250E+04 54 chloritoid-Fe 9.17 5.03 -4.14 -0.276 0.70682E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65763E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13221E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10075E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36646E+04 69 diamond -3.10 -4.37 -1.27 -0.363 0.21708E+04 70 dolomite,ordered 0.55 -3.98 -4.52 -0.754 0.77253E+04 72 enstatite 17.26 12.29 -4.97 -0.497 0.84912E+04 74 clinoenstatite 17.17 12.29 -4.87 -0.487 0.83228E+04 76 epidote 24.67 22.69 -1.98 -0.096 0.33860E+04 77 clinozoisite 22.81 18.89 -3.92 -0.178 0.66944E+04 78 epidote-Fe 29.84 26.49 -3.35 -0.174 0.57242E+04 79 fayalite 14.05 10.31 -3.74 -0.534 0.63809E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68148E+04 84 gibbsite 4.08 0.73 -3.35 -0.479 0.57235E+04 85 glaucophane 22.97 20.82 -2.15 -0.058 0.36787E+04 86 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70961E+04 87 graphite -3.55 -4.37 -0.83 -0.236 0.14131E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38454E+04 91 hematite 12.57 9.06 -3.51 -0.425 0.59899E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.45 -0.145 0.24737E+04 98 kalsilite 7.58 3.81 -3.77 -0.539 0.64365E+04 99 kaolinite -1.33 -4.85 -3.51 -0.319 0.59989E+04 102 laumontite 2.88 1.93 -0.95 -0.064 0.16284E+04 103 lawsonite 9.62 8.23 -1.39 -0.092 0.23651E+04 104 leucite 4.12 0.66 -3.45 -0.345 0.58993E+04 106 lizardite 23.24 21.59 -1.66 -0.138 0.28276E+04 107 magnesite 0.69 -3.88 -4.57 -1.523 0.78031E+04 108 magnetite 20.09 15.79 -4.30 -0.351 0.73417E+04 109 minnesotaite 10.39 7.59 -2.80 -0.165 0.47831E+04 113 manganosite 14.06 9.25 -4.81 -1.203 0.82181E+04 121 muscovite 2.58 -1.03 -3.61 -0.213 0.61708E+04 122 paragonite 4.24 1.07 -3.17 -0.186 0.54099E+04 123 nepheline 8.34 5.92 -2.42 -0.346 0.41364E+04 129 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83616E+04 135 phlogopite-Na 29.65 27.50 -2.14 -0.119 0.36570E+04 137 prehnite 19.37 18.16 -1.21 -0.071 0.20731E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.91971E+03 139 pumpellyite-Fe 46.27 43.77 -2.50 -0.055 0.42638E+04 140 pumpellyite-Mg 48.99 46.34 -2.66 -0.059 0.45347E+04 143 pyrite -21.25 -21.85 -0.60 -0.141 0.10223E+04 144 pyrrhotite -4.26 -5.36 -1.10 -0.366 0.18735E+04 145 pyrrhotiteFe0.875 -6.02 -6.74 -0.73 -0.268 0.12423E+04 146 pyroxmangite 7.40 6.09 -1.30 -0.261 0.22265E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84876E+04 148 quartz -2.99 -3.15 -0.16 -0.054 0.27483E+03 152 rhodochrosite -0.98 -3.93 -2.95 -0.985 0.50444E+04 153 rhodonite 7.45 6.09 -1.35 -0.270 0.23068E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.45 -3.84 -1.279 0.65533E+04 166 stilpnomelane-Mg 27.44 25.85 -1.59 -0.047 0.27155E+04 172 talc 16.49 15.29 -1.20 -0.071 0.20554E+04 175 tephroite 18.09 15.34 -2.75 -0.392 0.46887E+04 179 tridymite -2.63 -3.15 -0.52 -0.175 0.89481E+03 180 tremolite 47.87 47.43 -0.44 -0.012 0.74592E+03 181 ferroactinolite 38.45 34.60 -3.85 -0.104 0.65806E+04 182 troilite-low -4.41 -5.36 -0.95 -0.316 0.16163E+04 188 wairakite 3.95 1.93 -2.02 -0.119 0.34496E+04 189 walstromite 11.51 9.93 -1.58 -0.317 0.27023E+04 190 wollastonite 10.46 9.93 -0.53 -0.107 0.91272E+03 191 pseudo-wollastonite 11.00 9.93 -1.07 -0.215 0.18326E+04 192 zoisite 22.85 18.89 -3.96 -0.180 0.67684E+04 193 akaganeite 7.75 4.53 -3.23 -0.697 0.55077E+04 200 chalcedony -2.80 -3.15 -0.35 -0.116 0.59413E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66088E+04 203 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68708E+04 204 montmorillonite-Mg -2.48 -6.79 -4.31 -0.266 0.73510E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60257E+04 206 nontronite-Ca 3.21 -0.11 -3.32 -0.215 0.56701E+04 207 nontronite-H 2.53 -2.26 -4.80 -0.321 0.81902E+04 208 nontronite-K 3.34 -0.21 -3.55 -0.228 0.60554E+04 209 nontronite-Mg 3.07 -0.73 -3.80 -0.247 0.64963E+04 210 nontronite-Na 3.52 0.49 -3.03 -0.195 0.51762E+04 226 tobermorite 9.82 7.74 -2.08 -0.568 0.35525E+04 232 alabandite -0.98 -2.84 -1.86 -0.621 0.31830E+04 235 boehmite 4.41 0.73 -3.68 -0.613 0.62816E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.771 0.52625E+04 243 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18083E+04 245 an20ab80 2.02 1.34 -0.68 -0.052 0.11587E+04 246 an25ab75 2.65 1.77 -0.88 -0.067 0.14953E+04 247 an30ab70 3.28 2.20 -1.08 -0.083 0.18416E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1919900 MOLES New total amount of reactant added: 0.1959900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8667E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1959900 Water: Moles liquid = 0.2767E+02 kg liquid = 0.4984E+00 Moles total = -.7008E+01 kg total = -.1263E+00 Activity = 0.9995 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3060963E-01 Chg. balance for total moles = -.8667E-10 Max. difference allowed = 0.1294E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13266E-09 -9.8773 0.10833E-09 -9.9652 0.81663E+00 -0.0880 2 H2O 0.99952E+00 -0.0002 0.99952E+00 -0.0002 3 Cl- 0.25803E-02 -2.5883 0.20897E-02 -2.6799 0.80985E+00 -0.0916 4 SO4-- 0.40848E-09 -9.3888 0.18835E-09 -9.7250 0.46111E+00 -0.3362 5 HCO3- 0.81385E-03 -3.0895 0.66043E-03 -3.1802 0.81149E+00 -0.0907 6 HS- 0.96042E-02 -2.0175 0.77795E-02 -2.1090 0.81001E+00 -0.0915 7 Al+++ 0.38530E-28 -28.4142 0.67813E-29 -29.1687 0.17600E+00 -0.7545 8 H4SiO4 0.70742E-03 -3.1503 0.70742E-03 -3.1503 0.10000E+01 0.0000 9 Ca++ 0.30593E-06 -6.5144 0.13963E-06 -6.8550 0.45640E+00 -0.3407 10 Mg++ 0.51243E-10 -10.2904 0.23239E-10 -10.6338 0.45351E+00 -0.3434 11 Fe++ 0.13856E-12 -12.8584 0.62932E-13 -13.2011 0.45420E+00 -0.3428 12 K+ 0.23010E-03 -3.6381 0.18678E-03 -3.7287 0.81174E+00 -0.0906 13 Na+ 0.29220E-01 -1.5343 0.23657E-01 -1.6260 0.80962E+00 -0.0917 14 Mn++ 0.45385E-10 -10.3431 0.20637E-10 -10.6853 0.45472E+00 -0.3423 15 F- 0.81352E-06 -6.0896 0.65697E-06 -6.1825 0.80756E+00 -0.0928 16 HPO4-- 0.26489E-07 -7.5769 0.12217E-07 -7.9130 0.46120E+00 -0.3361 18 HSiO3- 0.75328E-02 -2.1230 0.61004E-02 -2.2146 0.80985E+00 -0.0916 19 Ca(HSiO3)+ 0.23890E-07 -7.6218 0.19398E-07 -7.7122 0.81198E+00 -0.0905 20 Mg(HSiO3)+ 0.49484E-11 -11.3055 0.40180E-11 -11.3960 0.81198E+00 -0.0905 21 NaHSiO3,aq 0.23342E-02 -2.6319 0.23342E-02 -2.6319 0.10000E+01 0.0000 22 AlO+ 0.96769E-16 -16.0143 0.78575E-16 -16.1047 0.81198E+00 -0.0905 24 HAlO2,aq 0.14438E-09 -9.8405 0.14438E-09 -9.8405 0.10000E+01 0.0000 25 AlO2- 0.36519E-05 -5.4375 0.29502E-05 -5.5302 0.80784E+00 -0.0927 26 CH4,aq 0.26484E-01 -1.5770 0.26484E-01 -1.5770 0.10000E+01 0.0000 27 C2H6,aq 0.12670E-07 -7.8972 0.12670E-07 -7.8972 0.10000E+01 0.0000 28 C3H8,aq 0.13994E-12 -12.8541 0.13994E-12 -12.8541 0.10000E+01 0.0000 29 C4H10,aq 0.15183E-17 -17.8186 0.15183E-17 -17.8186 0.10000E+01 0.0000 30 ethanol,aq 0.56885E-15 -15.2450 0.56885E-15 -15.2450 0.10000E+01 0.0000 31 CO,aq 0.36380E-13 -13.4391 0.36380E-13 -13.4391 0.10000E+01 0.0000 32 CO2,aq 0.15295E-06 -6.8155 0.15295E-06 -6.8155 0.10000E+01 0.0000 33 CO3-2 0.11582E-02 -2.9362 0.53250E-03 -3.2737 0.45976E+00 -0.3375 34 CaCO3,aq 0.93229E-06 -6.0304 0.93229E-06 -6.0304 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.28989E-08 -8.5378 0.23539E-08 -8.6282 0.81198E+00 -0.0905 36 CaCl+ 0.58153E-09 -9.2354 0.47219E-09 -9.3259 0.81198E+00 -0.0905 37 CaCl2,aq 0.23442E-12 -12.6300 0.23442E-12 -12.6300 0.10000E+01 0.0000 38 CaF+ 0.16494E-11 -11.7827 0.13393E-11 -11.8731 0.81198E+00 -0.0905 39 CaOH+ 0.11308E-06 -6.9466 0.91816E-07 -7.0371 0.81198E+00 -0.0905 40 CaSO4,aq 0.83513E-14 -14.0782 0.83513E-14 -14.0782 0.10000E+01 0.0000 41 HCl,aq 0.41482E-13 -13.3821 0.41482E-13 -13.3821 0.10000E+01 0.0000 45 HF,aq 0.48721E-12 -12.3123 0.48721E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.13344E-18 -18.8747 0.10807E-18 -18.9663 0.80985E+00 -0.0916 48 FeCl+ 0.25635E-15 -15.5912 0.20815E-15 -15.6816 0.81198E+00 -0.0905 51 FeF+ 0.26020E-17 -17.5847 0.21127E-17 -17.6752 0.81198E+00 -0.0905 53 FeO,aq 0.20832E-09 -9.6813 0.20832E-09 -9.6813 0.10000E+01 0.0000 54 FeOH+ 0.23277E-10 -10.6331 0.18901E-10 -10.7235 0.81198E+00 -0.0905 55 HFeO2- 0.24833E-07 -7.6050 0.20111E-07 -7.6966 0.80985E+00 -0.0916 56 FeO+ 0.18047E-16 -16.7436 0.14654E-16 -16.8340 0.81198E+00 -0.0905 58 FeO2- 0.31535E-09 -9.5012 0.25539E-09 -9.5928 0.80985E+00 -0.0916 59 HFeO2,aq 0.35187E-11 -11.4536 0.35187E-11 -11.4536 0.10000E+01 0.0000 60 H2,aq 0.94642E-05 -5.0239 0.94642E-05 -5.0239 0.10000E+01 0.0000 61 KCl,aq 0.70742E-08 -8.1503 0.70742E-08 -8.1503 0.10000E+01 0.0000 63 KOH,aq 0.73598E-06 -6.1331 0.73598E-06 -6.1331 0.10000E+01 0.0000 64 KSO4- 0.67412E-12 -12.1713 0.54593E-12 -12.2629 0.80985E+00 -0.0916 65 MgCO3,aq 0.38893E-10 -10.4101 0.38893E-10 -10.4101 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.49301E-12 -12.3071 0.40031E-12 -12.3976 0.81198E+00 -0.0905 67 MgCl+ 0.87722E-13 -13.0569 0.71229E-13 -13.1473 0.81198E+00 -0.0905 68 MgF+ 0.10169E-14 -14.9927 0.82571E-15 -15.0832 0.81198E+00 -0.0905 69 MgOH+ 0.10414E-09 -9.9824 0.84560E-10 -10.0728 0.81198E+00 -0.0905 71 MnF+ 0.28124E-15 -15.5509 0.22837E-15 -15.6414 0.81198E+00 -0.0905 72 MnO,aq 0.18203E-08 -8.7399 0.18203E-08 -8.7399 0.10000E+01 0.0000 73 MnOH+ 0.70911E-09 -9.1493 0.57578E-09 -9.2397 0.81198E+00 -0.0905 74 MnO2-2 0.11191E-10 -10.9511 0.51451E-11 -11.2886 0.45976E+00 -0.3375 75 HMnO2- 0.15078E-09 -9.8216 0.12211E-09 -9.9132 0.80985E+00 -0.0916 78 MnCl+ 0.32705E-12 -12.4854 0.26556E-12 -12.5758 0.81198E+00 -0.0905 79 MnSO4,aq 0.11222E-17 -17.9499 0.11222E-17 -17.9499 0.10000E+01 0.0000 80 NaCl,aq 0.16383E-04 -4.7856 0.16383E-04 -4.7856 0.10000E+01 0.0000 81 NaF,aq 0.36387E-08 -8.4391 0.36387E-08 -8.4391 0.10000E+01 0.0000 82 NaOH,aq 0.93782E-04 -4.0279 0.93782E-04 -4.0279 0.10000E+01 0.0000 84 OH- 0.65989E-02 -2.1805 0.53309E-02 -2.2732 0.80784E+00 -0.0927 89 HPO3-2 0.78407E-15 -15.1056 0.36048E-15 -15.4431 0.45976E+00 -0.3375 91 H2PO3- 0.96697E-19 -19.0146 0.78310E-19 -19.1062 0.80985E+00 -0.0916 92 H3PO4,aq 0.10027E-17 -17.9988 0.10027E-17 -17.9988 0.10000E+01 0.0000 93 H2PO4- 0.30107E-10 -10.5213 0.24414E-10 -10.6124 0.81091E+00 -0.0910 94 PO4-3 0.48842E-09 -9.3112 0.92009E-10 -10.0362 0.18838E+00 -0.7250 98 HP2O7-3 0.48888E-18 -18.3108 0.86184E-19 -19.0646 0.17629E+00 -0.7538 99 P2O7-4 0.39507E-17 -17.4033 0.19006E-18 -18.7211 0.48107E-01 -1.3178 100 H2S,aq 0.26047E-05 -5.5843 0.26047E-05 -5.5843 0.10000E+01 0.0000 101 S2-2 0.30819E-09 -9.5112 0.14170E-09 -9.8486 0.45976E+00 -0.3375 102 S3-2 0.11427E-15 -15.9421 0.52538E-16 -16.2795 0.45976E+00 -0.3375 107 SO3-2 0.49419E-15 -15.3061 0.23176E-15 -15.6350 0.46897E+00 -0.3289 108 HSO3- 0.19411E-17 -17.7120 0.15720E-17 -17.8035 0.80985E+00 -0.0916 109 HSO4- 0.24184E-16 -16.6165 0.19664E-16 -16.7063 0.81309E+00 -0.0899 111 S2O3-2 0.12541E-16 -16.9017 0.57657E-17 -17.2391 0.45976E+00 -0.3375 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1326565E-09 -.1773397E-01 -.1782787E+02 0.0000 2 H2O 0.1000000E+01 0.5553158E+02 0.9977924E+06 0.0000 3 Cl- 0.2580340E-02 0.2596731E-02 0.9182029E+02 7.2853 4 SO4-- 0.4084764E-09 -.2648648E-01 -.2537656E+04 10.2055 5 HCO3- 0.8138484E-03 0.2845726E-01 0.1731825E+04 6.7851 6 HS- 0.9604227E-02 0.3609332E-01 0.1190545E+04 7.8562 7 Al+++ 0.3852988E-28 0.3652051E-05 0.9827919E-01 0.7271 8 H4SiO4 0.7074172E-03 0.1057439E-01 0.1013694E+04 -3.1503 9 Ca++ 0.3059350E-06 0.1378673E-05 0.5510945E-01 13.0755 10 Mg++ 0.5124269E-10 0.1998056E-09 0.4844925E-05 9.2967 11 Fe++ 0.1385554E-12 0.2538333E-07 0.1413863E-02 6.7294 12 K+ 0.2301022E-03 0.2308453E-03 0.9002821E+01 6.2366 13 Na+ 0.2922024E-01 0.3166457E-01 0.7260516E+03 8.3392 14 Mn++ 0.4538463E-10 0.2737064E-08 0.1499741E-03 9.2451 15 F- 0.8135205E-06 0.8171613E-06 0.1548369E-01 3.7828 16 HPO4-- 0.2648851E-07 0.2700704E-07 0.2585306E-02 12.0174 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277144E+02 -.8838643E-02 -.8276261E+02 0.0000000E+00 2 H2O -.7008332E+01 0.2767703E+02 -.3468536E+02 0.0000000E+00 3 Cl- 0.1294215E-02 0.1294215E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1395284E+00 -.1320091E-01 0.1527293E+00 0.0000000E+00 5 HCO3- 0.1418315E-01 0.1418315E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1347403E+00 0.1798897E-01 -.1527293E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1820188E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5270293E-02 0.5205863E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.6871331E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.9958345E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1265110E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1150537E-03 0.1061456E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1578168E-01 0.6260595E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1364157E-08 0.8669296E-01 0.0000000E+00 15 F- 0.7849600E-04 0.4072746E-06 0.7808873E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1346035E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.4927E-14 Mass of aqueous solution: 0.499713E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1959900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.98 628.7 andradite 0.6109 -0.214 310.5 2.492 5.682 80.66 grossular 0.1318 -0.880 59.37 1.774 1.087 16.52 apatite-OH 0.9785E-02 -2.009 4.915 0.692 0.8995E-01 1.562 apatite-F 0.7809E-04 -4.107 0.3938E-01 -1.405 0.7208E-03 0.1230E-01 clinochlore 0.7086 -0.150 393.9 2.595 7.208 149.8 daphnite 0.2013 -0.696 143.6 2.157 2.629 43.53 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9425 -0.026 262.3 2.419 4.801 102.5 stilbite 3.239 0.510 2282. 3.358 41.77 1065. stilpnomelane-Fe 0.2380 -0.623 256.5 2.409 4.695 88.62 tr.625ac.25prg.125 0.1173 -0.931 100.3 2.001 1.835 32.28 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8226E+00 0.8226E+00 1.0000 -0.085 grossular 0.1774E+00 0.1774E+00 1.0000 -0.751 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7642E+00 0.7642E+00 1.0000 -0.117 daphnite 0.2171E+00 0.2171E+00 1.0000 -0.663 chlorite-Mn 0.1870E-01 0.1870E-01 1.0000 -1.728 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5463.861112 g Volume = 2212.609122 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1959900 moles log = -0.7078 Original solution: 1000.0103000 g Original solution / Rock added: 5102.35 (Water/Rock Ratio), log = 3.7078 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 41.0279 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2642E-01 0.9275 0.1005E+01 0.1084E+01 CO2,gas 0.4277E-06 0.9325 0.1636E-04 0.1755E-04 CH4,gas 0.9733E+00 0.9762 0.3898E+02 0.3993E+02 H2,gas 0.2963E-03 1.0221 0.1243E-01 0.1216E-01 H2S,gas 0.2037E-05 0.8567 0.7160E-04 0.8358E-04 S2,gas 0.3038E-25 1.0000 0.1246E-23 0.1246E-23 CO,gas 0.1321E-11 1.0000 0.5421E-10 0.5421E-10 SO3,gas 0.2038E-46 1.0000 0.8362E-45 0.8362E-45 SO2,gas 0.9857E-26 1.0000 0.4044E-24 0.4044E-24 HF,gas 0.2916E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1784E-17 1.0000 0.7320E-16 0.7320E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 117 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 164 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28969E+04 0.002 2 CO2,gas -6.66 -13.15 -6.49 -2.162 0.11073E+05 -4.786 3 CH4,gas 4.54 4.44 -0.11 -0.027 0.18457E+03 1.591 4 H2,gas 8.00 4.40 -3.60 -2.060 0.61549E+04 -1.906 5 H2S,gas -6.23 -12.07 -5.84 -2.922 0.99786E+04 -4.145 6 S2,gas -7.34 -32.94 -25.60 -3.939 0.43717E+05 -23.904 7 CO,gas 3.21 -8.75 -11.96 -3.681 0.20430E+05 -10.266 8 SO3,gas 17.12 -29.66 -46.78 -11.694 0.79870E+05 -45.078 9 SO2,gas 0.83 -25.26 -26.09 -6.958 0.44552E+05 -24.393 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.65 -17.83 -8.917 0.30452E+05 -16.136 12 acmite 7.71 6.57 -1.14 -0.118 0.19447E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80571E+04 21 analcite 3.32 2.77 -0.56 -0.062 0.94940E+03 26 ankerite -2.14 -6.49 -4.35 -0.725 0.74291E+04 27 annite 20.12 17.70 -2.42 -0.135 0.41366E+04 28 phlogopite 27.06 25.40 -1.66 -0.092 0.28374E+04 30 anorthite 12.71 8.23 -4.48 -0.345 0.76518E+04 38 aragonite 0.97 -0.07 -1.04 -0.345 0.17697E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55873E+04 40 calcite 0.81 -0.07 -0.88 -0.294 0.15055E+04 41 carnegieite-low 9.02 5.92 -3.11 -0.444 0.53057E+04 42 carnegieite-high 10.09 5.92 -4.18 -0.597 0.71327E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.275 0.70558E+04 44 carpholite-Fe 6.71 1.88 -4.83 -0.322 0.82475E+04 45 celadonite 5.34 3.66 -1.68 -0.099 0.28715E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47536E+04 47 chrysotile 23.89 21.59 -2.30 -0.192 0.39325E+04 52 chlorite-Al-free 47.17 43.18 -3.99 -0.166 0.68201E+04 54 chloritoid-Fe 9.17 5.03 -4.14 -0.276 0.70708E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65785E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13213E+04 64 cristobalite -2.56 -3.15 -0.59 -0.197 0.10067E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36660E+04 69 diamond -3.10 -4.35 -1.25 -0.358 0.21381E+04 70 dolomite,ordered 0.55 -3.92 -4.47 -0.744 0.76239E+04 72 enstatite 17.26 12.29 -4.97 -0.497 0.84891E+04 74 clinoenstatite 17.17 12.29 -4.87 -0.487 0.83206E+04 76 epidote 24.67 22.69 -1.98 -0.096 0.33880E+04 77 clinozoisite 22.81 18.88 -3.93 -0.178 0.67020E+04 78 epidote-Fe 29.84 26.49 -3.35 -0.174 0.57206E+04 79 fayalite 14.05 10.31 -3.74 -0.534 0.63814E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68144E+04 84 gibbsite 4.08 0.73 -3.35 -0.479 0.57249E+04 85 glaucophane 22.97 20.82 -2.15 -0.058 0.36762E+04 86 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70964E+04 87 graphite -3.55 -4.35 -0.81 -0.231 0.13804E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38457E+04 91 hematite 12.57 9.06 -3.50 -0.425 0.59816E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.45 -0.145 0.24745E+04 98 kalsilite 7.58 3.81 -3.77 -0.539 0.64382E+04 99 kaolinite -1.33 -4.85 -3.51 -0.319 0.60000E+04 102 laumontite 2.88 1.93 -0.96 -0.064 0.16308E+04 103 lawsonite 9.62 8.23 -1.39 -0.093 0.23692E+04 104 leucite 4.12 0.66 -3.46 -0.346 0.59001E+04 106 lizardite 23.24 21.59 -1.65 -0.138 0.28251E+04 107 magnesite 0.69 -3.85 -4.54 -1.513 0.77507E+04 108 magnetite 20.09 15.79 -4.30 -0.351 0.73340E+04 109 minnesotaite 10.39 7.59 -2.80 -0.165 0.47817E+04 113 manganosite 14.06 9.24 -4.81 -1.203 0.82184E+04 121 muscovite 2.58 -1.03 -3.62 -0.213 0.61736E+04 122 paragonite 4.24 1.07 -3.17 -0.186 0.54127E+04 123 nepheline 8.34 5.92 -2.42 -0.346 0.41381E+04 129 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83622E+04 135 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36562E+04 137 prehnite 19.37 18.15 -1.22 -0.072 0.20793E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.92035E+03 139 pumpellyite-Fe 46.27 43.76 -2.51 -0.056 0.42783E+04 140 pumpellyite-Mg 48.99 46.33 -2.66 -0.059 0.45483E+04 143 pyrite -21.25 -21.81 -0.57 -0.134 0.96881E+03 144 pyrrhotite -4.26 -5.34 -1.08 -0.362 0.18519E+04 145 pyrrhotiteFe0.875 -6.02 -6.73 -0.71 -0.263 0.12194E+04 146 pyroxmangite 7.40 6.10 -1.30 -0.261 0.22259E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84871E+04 148 quartz -2.99 -3.15 -0.16 -0.053 0.27401E+03 152 rhodochrosite -0.98 -3.90 -2.92 -0.975 0.49926E+04 153 rhodonite 7.45 6.10 -1.35 -0.270 0.23062E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.42 -3.81 -1.269 0.65019E+04 166 stilpnomelane-Mg 27.44 25.85 -1.59 -0.047 0.27109E+04 172 talc 16.49 15.29 -1.20 -0.071 0.20513E+04 175 tephroite 18.09 15.34 -2.75 -0.392 0.46884E+04 179 tridymite -2.63 -3.15 -0.52 -0.175 0.89398E+03 180 tremolite 47.87 47.43 -0.44 -0.012 0.74388E+03 181 ferroactinolite 38.45 34.60 -3.86 -0.104 0.65832E+04 182 troilite-low -4.41 -5.34 -0.93 -0.311 0.15947E+04 188 wairakite 3.95 1.93 -2.02 -0.119 0.34521E+04 189 walstromite 11.51 9.93 -1.58 -0.317 0.27044E+04 190 wollastonite 10.46 9.93 -0.54 -0.107 0.91485E+03 191 pseudo-wollastonite 11.00 9.93 -1.07 -0.215 0.18347E+04 192 zoisite 22.85 18.88 -3.97 -0.180 0.67760E+04 193 akaganeite 7.75 4.53 -3.22 -0.697 0.55035E+04 200 chalcedony -2.80 -3.15 -0.35 -0.116 0.59330E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66082E+04 203 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68701E+04 204 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73499E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60250E+04 206 nontronite-Ca 3.21 -0.10 -3.31 -0.215 0.56597E+04 207 nontronite-H 2.53 -2.26 -4.79 -0.321 0.81793E+04 208 nontronite-K 3.34 -0.20 -3.54 -0.227 0.60448E+04 209 nontronite-Mg 3.07 -0.72 -3.80 -0.246 0.64854E+04 210 nontronite-Na 3.52 0.49 -3.03 -0.194 0.51657E+04 226 tobermorite 9.82 7.74 -2.08 -0.568 0.35542E+04 232 alabandite -0.98 -2.83 -1.85 -0.617 0.31610E+04 235 boehmite 4.41 0.73 -3.68 -0.613 0.62829E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.771 0.52632E+04 243 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18075E+04 245 an20ab80 2.02 1.34 -0.68 -0.052 0.11595E+04 246 an25ab75 2.65 1.77 -0.88 -0.067 0.14964E+04 247 an30ab70 3.28 2.20 -1.08 -0.083 0.18428E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1959900 MOLES New total amount of reactant added: 0.1999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8667E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1999900 Water: Moles liquid = 0.2766E+02 kg liquid = 0.4984E+00 Moles total = -.7005E+01 kg total = -.1262E+00 Activity = 0.9995 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3096242E-01 Chg. balance for total moles = -.8667E-10 Max. difference allowed = 0.1318E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13415E-09 -9.8724 0.10946E-09 -9.9607 0.81597E+00 -0.0883 2 H2O 0.99951E+00 -0.0002 0.99951E+00 -0.0002 3 Cl- 0.26274E-02 -2.5805 0.21259E-02 -2.6725 0.80913E+00 -0.0920 4 SO4-- 0.43554E-09 -9.3610 0.20015E-09 -9.6986 0.45954E+00 -0.3377 5 HCO3- 0.86410E-03 -3.0634 0.70060E-03 -3.1545 0.81079E+00 -0.0911 6 HS- 0.97996E-02 -2.0088 0.79308E-02 -2.1007 0.80930E+00 -0.0919 7 Al+++ 0.39990E-28 -28.3981 0.69834E-29 -29.1559 0.17463E+00 -0.7579 8 H4SiO4 0.70819E-03 -3.1499 0.70819E-03 -3.1499 0.10000E+01 0.0000 9 Ca++ 0.31222E-06 -6.5055 0.14200E-06 -6.8477 0.45480E+00 -0.3422 10 Mg++ 0.52526E-10 -10.2796 0.23737E-10 -10.6246 0.45190E+00 -0.3450 11 Fe++ 0.14185E-12 -12.8482 0.64199E-13 -13.1925 0.45259E+00 -0.3443 12 K+ 0.23237E-03 -3.6338 0.18846E-03 -3.7248 0.81104E+00 -0.0910 13 Na+ 0.29509E-01 -1.5300 0.23870E-01 -1.6221 0.80891E+00 -0.0921 14 Mn++ 0.46488E-10 -10.3327 0.21064E-10 -10.6765 0.45311E+00 -0.3438 15 F- 0.80582E-06 -6.0938 0.65016E-06 -6.1870 0.80683E+00 -0.0932 16 HPO4-- 0.26204E-07 -7.5816 0.12044E-07 -7.9192 0.45963E+00 -0.3376 18 HSiO3- 0.74696E-02 -2.1267 0.60439E-02 -2.2187 0.80913E+00 -0.0920 19 Ca(HSiO3)+ 0.24092E-07 -7.6181 0.19545E-07 -7.7090 0.81129E+00 -0.0908 20 Mg(HSiO3)+ 0.50118E-11 -11.3000 0.40660E-11 -11.3908 0.81129E+00 -0.0908 21 NaHSiO3,aq 0.23333E-02 -2.6320 0.23333E-02 -2.6320 0.10000E+01 0.0000 22 AlO+ 0.97683E-16 -16.0102 0.79249E-16 -16.1010 0.81129E+00 -0.0908 24 HAlO2,aq 0.14411E-09 -9.8413 0.14411E-09 -9.8413 0.10000E+01 0.0000 25 AlO2- 0.36106E-05 -5.4424 0.29142E-05 -5.5355 0.80711E+00 -0.0931 26 CH4,aq 0.26953E-01 -1.5694 0.26953E-01 -1.5694 0.10000E+01 0.0000 27 C2H6,aq 0.13294E-07 -7.8763 0.13294E-07 -7.8763 0.10000E+01 0.0000 28 C3H8,aq 0.15139E-12 -12.8199 0.15139E-12 -12.8199 0.10000E+01 0.0000 29 C4H10,aq 0.16935E-17 -17.7712 0.16935E-17 -17.7712 0.10000E+01 0.0000 30 ethanol,aq 0.60468E-15 -15.2185 0.60468E-15 -15.2185 0.10000E+01 0.0000 31 CO,aq 0.38494E-13 -13.4146 0.38494E-13 -13.4146 0.10000E+01 0.0000 32 CO2,aq 0.16395E-06 -6.7853 0.16395E-06 -6.7853 0.10000E+01 0.0000 33 CO3-2 0.12201E-02 -2.9136 0.55904E-03 -3.2526 0.45818E+00 -0.3390 34 CaCO3,aq 0.99539E-06 -6.0020 0.99539E-06 -6.0020 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.31302E-08 -8.5044 0.25395E-08 -8.5953 0.81129E+00 -0.0908 36 CaCl+ 0.60217E-09 -9.2203 0.48853E-09 -9.3111 0.81129E+00 -0.0908 37 CaCl2,aq 0.24674E-12 -12.6078 0.24674E-12 -12.6078 0.10000E+01 0.0000 38 CaF+ 0.16615E-11 -11.7795 0.13479E-11 -11.8703 0.81129E+00 -0.0908 39 CaOH+ 0.11390E-06 -6.9435 0.92409E-07 -7.0343 0.81129E+00 -0.0908 40 CaSO4,aq 0.90250E-14 -14.0446 0.90250E-14 -14.0446 0.10000E+01 0.0000 41 HCl,aq 0.42643E-13 -13.3702 0.42643E-13 -13.3702 0.10000E+01 0.0000 45 HF,aq 0.48720E-12 -12.3123 0.48720E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.13217E-18 -18.8789 0.10695E-18 -18.9708 0.80913E+00 -0.0920 48 FeCl+ 0.26628E-15 -15.5747 0.21603E-15 -15.6655 0.81129E+00 -0.0908 51 FeF+ 0.26291E-17 -17.5802 0.21330E-17 -17.6710 0.81129E+00 -0.0908 53 FeO,aq 0.20814E-09 -9.6817 0.20814E-09 -9.6817 0.10000E+01 0.0000 54 FeOH+ 0.23520E-10 -10.6286 0.19082E-10 -10.7194 0.81129E+00 -0.0908 55 HFeO2- 0.24576E-07 -7.6095 0.19885E-07 -7.7015 0.80913E+00 -0.0920 56 FeO+ 0.18354E-16 -16.7363 0.14891E-16 -16.8271 0.81129E+00 -0.0908 58 FeO2- 0.31412E-09 -9.5029 0.25417E-09 -9.5949 0.80913E+00 -0.0920 59 HFeO2,aq 0.35385E-11 -11.4512 0.35385E-11 -11.4512 0.10000E+01 0.0000 60 H2,aq 0.93422E-05 -5.0296 0.93422E-05 -5.0296 0.10000E+01 0.0000 61 KCl,aq 0.72615E-08 -8.1390 0.72615E-08 -8.1390 0.10000E+01 0.0000 63 KOH,aq 0.73490E-06 -6.1338 0.73490E-06 -6.1338 0.10000E+01 0.0000 64 KSO4- 0.72340E-12 -12.1406 0.58533E-12 -12.2326 0.80913E+00 -0.0920 65 MgCO3,aq 0.41706E-10 -10.3798 0.41706E-10 -10.3798 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.53465E-12 -12.2719 0.43375E-12 -12.3628 0.81129E+00 -0.0908 67 MgCl+ 0.91231E-13 -13.0399 0.74014E-13 -13.1307 0.81129E+00 -0.0908 68 MgF+ 0.10288E-14 -14.9877 0.83465E-15 -15.0785 0.81129E+00 -0.0908 69 MgOH+ 0.10536E-09 -9.9773 0.85475E-10 -10.0682 0.81129E+00 -0.0908 71 MnF+ 0.28434E-15 -15.5462 0.23068E-15 -15.6370 0.81129E+00 -0.0908 72 MnO,aq 0.18197E-08 -8.7400 0.18197E-08 -8.7400 0.10000E+01 0.0000 73 MnOH+ 0.71690E-09 -9.1445 0.58161E-09 -9.2354 0.81129E+00 -0.0908 74 MnO2-2 0.10995E-10 -10.9588 0.50375E-11 -11.2978 0.45818E+00 -0.3390 75 HMnO2- 0.14931E-09 -9.8259 0.12081E-09 -9.9179 0.80913E+00 -0.0920 78 MnCl+ 0.33990E-12 -12.4686 0.27576E-12 -12.5595 0.81129E+00 -0.0908 79 MnSO4,aq 0.12171E-17 -17.9147 0.12171E-17 -17.9147 0.10000E+01 0.0000 80 NaCl,aq 0.16817E-04 -4.7743 0.16817E-04 -4.7743 0.10000E+01 0.0000 81 NaF,aq 0.36334E-08 -8.4397 0.36334E-08 -8.4397 0.10000E+01 0.0000 82 NaOH,aq 0.93645E-04 -4.0285 0.93645E-04 -4.0285 0.10000E+01 0.0000 84 OH- 0.65365E-02 -2.1847 0.52757E-02 -2.2777 0.80711E+00 -0.0931 89 HPO3-2 0.76568E-15 -15.1160 0.35082E-15 -15.4549 0.45818E+00 -0.3390 91 H2PO3- 0.95173E-19 -19.0215 0.77008E-19 -19.1135 0.80913E+00 -0.0920 92 H3PO4,aq 0.10094E-17 -17.9960 0.10094E-17 -17.9960 0.10000E+01 0.0000 93 H2PO4- 0.30019E-10 -10.5226 0.24321E-10 -10.6140 0.81021E+00 -0.0914 94 PO4-3 0.48002E-09 -9.3187 0.89774E-10 -10.0469 0.18702E+00 -0.7281 98 HP2O7-3 0.48392E-18 -18.3152 0.84647E-19 -19.0724 0.17492E+00 -0.7572 99 P2O7-4 0.38926E-17 -17.4098 0.18474E-18 -18.7334 0.47459E-01 -1.3237 100 H2S,aq 0.26831E-05 -5.5714 0.26831E-05 -5.5714 0.10000E+01 0.0000 101 S2-2 0.32560E-09 -9.4873 0.14918E-09 -9.8263 0.45818E+00 -0.3390 102 S3-2 0.12599E-15 -15.8997 0.57725E-16 -16.2386 0.45818E+00 -0.3390 107 SO3-2 0.52007E-15 -15.2839 0.24310E-15 -15.6142 0.46744E+00 -0.3303 108 HSO3- 0.20592E-17 -17.6863 0.16661E-17 -17.7783 0.80913E+00 -0.0920 109 HSO4- 0.25989E-16 -16.5852 0.21114E-16 -16.6754 0.81241E+00 -0.0902 111 S2O3-2 0.13775E-16 -16.8609 0.63113E-17 -17.1999 0.45818E+00 -0.3390 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1341518E-09 -.1766906E-01 -.1776220E+02 0.0000 2 H2O 0.1000000E+01 0.5553205E+02 0.9977777E+06 0.0000 3 Cl- 0.2627383E-02 0.2644208E-02 0.9349691E+02 7.2883 4 SO4-- 0.4355383E-09 -.2695584E-01 -.2582565E+04 10.2228 5 HCO3- 0.8640955E-03 0.2903890E-01 0.1767181E+04 6.8062 6 HS- 0.9799638E-02 0.3675816E-01 0.1212447E+04 7.8601 7 Al+++ 0.3998977E-28 0.3610782E-05 0.9716638E-01 0.7263 8 H4SiO4 0.7081885E-03 0.1051114E-01 0.1007607E+04 -3.1499 9 Ca++ 0.3122234E-06 0.1449340E-05 0.5793287E-01 13.0738 10 Mg++ 0.5252608E-10 0.2052292E-09 0.4976323E-05 9.2969 11 Fe++ 0.1418480E-12 0.2512526E-07 0.1399455E-02 6.7290 12 K+ 0.2323694E-03 0.2331116E-03 0.9090995E+01 6.2360 13 Na+ 0.2950882E-01 0.3195261E-01 0.7326391E+03 8.3386 14 Mn++ 0.4648782E-10 0.2743698E-08 0.1503342E-03 9.2450 15 F- 0.8058231E-06 0.8094586E-06 0.1533738E-01 3.7738 16 HPO4-- 0.2620428E-07 0.2671433E-07 0.2557226E-02 12.0022 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277101E+02 -.8805872E-02 -.8276221E+02 0.0000000E+00 2 H2O -.7005057E+01 0.2767595E+02 -.3468101E+02 0.0000000E+00 3 Cl- 0.1317815E-02 0.1317815E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1395475E+00 -.1343420E-01 0.1529817E+00 0.0000000E+00 5 HCO3- 0.1447235E-01 0.1447235E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1346622E+00 0.1831946E-01 -.1529817E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1799535E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5238520E-02 0.5205867E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.7223194E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1022817E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1252188E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1161777E-03 0.1061455E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1592448E-01 0.6260452E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1367399E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8009600E-04 0.4034164E-06 0.7969258E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1331383E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.8507E-14 Mass of aqueous solution: 0.499701E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.97 628.7 andradite 0.6119 -0.213 311.0 2.493 5.691 80.79 grossular 0.1310 -0.883 59.02 1.771 1.080 16.42 apatite-OH 0.9783E-02 -2.010 4.914 0.691 0.8994E-01 1.562 apatite-F 0.7969E-04 -4.099 0.4019E-01 -1.396 0.7355E-03 0.1256E-01 clinochlore 0.7091 -0.149 394.1 2.596 7.213 149.9 daphnite 0.2012 -0.696 143.6 2.157 2.628 43.51 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9425 -0.026 262.3 2.419 4.801 102.5 stilbite 3.239 0.510 2283. 3.358 41.78 1065. stilpnomelane-Fe 0.2379 -0.624 256.4 2.409 4.693 88.57 tr.625ac.25prg.125 0.1166 -0.933 99.70 1.999 1.825 32.09 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8236E+00 0.8236E+00 1.0000 -0.084 grossular 0.1764E+00 0.1764E+00 1.0000 -0.754 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7644E+00 0.7644E+00 1.0000 -0.117 daphnite 0.2169E+00 0.2169E+00 1.0000 -0.664 chlorite-Mn 0.1869E-01 0.1869E-01 1.0000 -1.728 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5463.955636 g Volume = 2212.701554 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1999900 moles log = -0.6990 Original solution: 1000.0103000 g Original solution / Rock added: 5000.30 (Water/Rock Ratio), log = 3.6990 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 41.7530 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2599E-01 0.9266 0.1005E+01 0.1085E+01 CO2,gas 0.4510E-06 0.9315 0.1754E-04 0.1883E-04 CH4,gas 0.9737E+00 0.9758 0.3967E+02 0.4066E+02 H2,gas 0.2873E-03 1.0225 0.1227E-01 0.1200E-01 H2S,gas 0.2067E-05 0.8544 0.7376E-04 0.8632E-04 S2,gas 0.3251E-25 1.0000 0.1357E-23 0.1357E-23 CO,gas 0.1374E-11 1.0000 0.5736E-10 0.5736E-10 SO3,gas 0.2173E-46 1.0000 0.9072E-45 0.9072E-45 SO2,gas 0.1037E-25 1.0000 0.4331E-24 0.4331E-24 HF,gas 0.2865E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1802E-17 1.0000 0.7524E-16 0.7524E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 117 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 164 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 165 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 248 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.97059E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28969E+04 0.002 2 CO2,gas -6.66 -13.12 -6.45 -2.152 0.11022E+05 -4.756 3 CH4,gas 4.54 4.44 -0.10 -0.025 0.17154E+03 1.599 4 H2,gas 8.00 4.39 -3.61 -2.063 0.61645E+04 -1.911 5 H2S,gas -6.23 -12.06 -5.83 -2.916 0.99566E+04 -4.132 6 S2,gas -7.34 -32.90 -25.57 -3.933 0.43654E+05 -23.867 7 CO,gas 3.21 -8.73 -11.94 -3.674 0.20388E+05 -10.241 8 SO3,gas 17.12 -29.62 -46.74 -11.685 0.79809E+05 -45.042 9 SO2,gas 0.83 -25.23 -26.06 -6.950 0.44501E+05 -24.363 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.63 -17.82 -8.911 0.30431E+05 -16.124 12 acmite 7.71 6.57 -1.14 -0.118 0.19399E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80581E+04 21 analcite 3.32 2.77 -0.56 -0.062 0.95022E+03 26 ankerite -2.14 -6.43 -4.29 -0.715 0.73297E+04 27 annite 20.12 17.70 -2.42 -0.135 0.41385E+04 28 phlogopite 27.06 25.40 -1.66 -0.092 0.28366E+04 30 anorthite 12.71 8.23 -4.48 -0.345 0.76559E+04 38 aragonite 0.97 -0.04 -1.01 -0.336 0.17212E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55870E+04 40 calcite 0.81 -0.04 -0.85 -0.284 0.14570E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.444 0.53073E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71343E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70567E+04 44 carpholite-Fe 6.71 1.88 -4.83 -0.322 0.82492E+04 45 celadonite 5.34 3.66 -1.68 -0.099 0.28704E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47534E+04 47 chrysotile 23.89 21.59 -2.30 -0.192 0.39300E+04 52 chlorite-Al-free 47.17 43.18 -3.99 -0.166 0.68152E+04 54 chloritoid-Fe 9.17 5.03 -4.14 -0.276 0.70734E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65806E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13205E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10059E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36674E+04 69 diamond -3.10 -4.34 -1.23 -0.352 0.21058E+04 70 dolomite,ordered 0.55 -3.86 -4.41 -0.734 0.75236E+04 72 enstatite 17.26 12.29 -4.97 -0.497 0.84869E+04 74 clinoenstatite 17.17 12.29 -4.87 -0.487 0.83185E+04 76 epidote 24.67 22.68 -1.99 -0.096 0.33900E+04 77 clinozoisite 22.81 18.88 -3.93 -0.179 0.67095E+04 78 epidote-Fe 29.84 26.49 -3.35 -0.174 0.57171E+04 79 fayalite 14.05 10.31 -3.74 -0.534 0.63818E+04 80 ferrosilite 11.15 7.16 -3.99 -0.399 0.68141E+04 84 gibbsite 4.08 0.73 -3.35 -0.479 0.57263E+04 85 glaucophane 22.97 20.82 -2.15 -0.058 0.36738E+04 86 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70967E+04 87 graphite -3.55 -4.34 -0.79 -0.226 0.13481E+04 88 greenalite 16.14 13.89 -2.25 -0.188 0.38460E+04 91 hematite 12.57 9.07 -3.50 -0.424 0.59732E+04 92 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 96 jadeite 4.22 2.77 -1.45 -0.145 0.24754E+04 98 kalsilite 7.58 3.81 -3.77 -0.539 0.64398E+04 99 kaolinite -1.33 -4.85 -3.51 -0.320 0.60011E+04 102 laumontite 2.88 1.93 -0.96 -0.064 0.16333E+04 103 lawsonite 9.62 8.23 -1.39 -0.093 0.23733E+04 104 leucite 4.12 0.66 -3.46 -0.346 0.59009E+04 106 lizardite 23.24 21.59 -1.65 -0.138 0.28226E+04 107 magnesite 0.69 -3.82 -4.51 -1.503 0.76990E+04 108 magnetite 20.09 15.80 -4.29 -0.350 0.73263E+04 109 minnesotaite 10.39 7.59 -2.80 -0.165 0.47804E+04 113 manganosite 14.06 9.24 -4.81 -1.203 0.82186E+04 121 muscovite 2.58 -1.03 -3.62 -0.213 0.61764E+04 122 paragonite 4.24 1.07 -3.17 -0.187 0.54155E+04 123 nepheline 8.34 5.91 -2.42 -0.346 0.41397E+04 129 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83629E+04 135 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36554E+04 137 prehnite 19.37 18.15 -1.22 -0.072 0.20855E+04 138 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.92099E+03 139 pumpellyite-Fe 46.27 43.76 -2.51 -0.056 0.42927E+04 140 pumpellyite-Mg 48.99 46.32 -2.67 -0.059 0.45617E+04 143 pyrite -21.25 -21.78 -0.54 -0.126 0.91583E+03 144 pyrrhotite -4.26 -5.33 -1.07 -0.357 0.18306E+04 145 pyrrhotiteFe0.875 -6.02 -6.72 -0.70 -0.258 0.11967E+04 146 pyroxmangite 7.40 6.10 -1.30 -0.261 0.22254E+04 147 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84866E+04 148 quartz -2.99 -3.15 -0.16 -0.053 0.27319E+03 152 rhodochrosite -0.98 -3.87 -2.89 -0.965 0.49413E+04 153 rhodonite 7.45 6.10 -1.35 -0.270 0.23056E+04 154 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 156 siderite -2.61 -6.39 -3.78 -1.259 0.64510E+04 166 stilpnomelane-Mg 27.44 25.86 -1.58 -0.047 0.27063E+04 172 talc 16.49 15.29 -1.20 -0.071 0.20472E+04 175 tephroite 18.09 15.34 -2.75 -0.392 0.46881E+04 179 tridymite -2.63 -3.15 -0.52 -0.174 0.89316E+03 180 tremolite 47.87 47.43 -0.43 -0.012 0.74184E+03 181 ferroactinolite 38.45 34.60 -3.86 -0.104 0.65858E+04 182 troilite-low -4.41 -5.33 -0.92 -0.307 0.15734E+04 188 wairakite 3.95 1.93 -2.02 -0.119 0.34545E+04 189 walstromite 11.51 9.92 -1.59 -0.317 0.27065E+04 190 wollastonite 10.46 9.92 -0.54 -0.107 0.91697E+03 191 pseudo-wollastonite 11.00 9.92 -1.08 -0.215 0.18368E+04 192 zoisite 22.85 18.88 -3.97 -0.181 0.67836E+04 193 akaganeite 7.75 4.53 -3.22 -0.696 0.54993E+04 200 chalcedony -2.80 -3.15 -0.35 -0.116 0.59248E+03 202 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66077E+04 203 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68694E+04 204 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73487E+04 205 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60243E+04 206 nontronite-Ca 3.21 -0.09 -3.31 -0.215 0.56493E+04 207 nontronite-H 2.53 -2.25 -4.78 -0.321 0.81684E+04 208 nontronite-K 3.34 -0.19 -3.53 -0.227 0.60343E+04 209 nontronite-Mg 3.07 -0.72 -3.79 -0.246 0.64745E+04 210 nontronite-Na 3.52 0.50 -3.02 -0.194 0.51551E+04 226 tobermorite 9.82 7.74 -2.08 -0.568 0.35558E+04 232 alabandite -0.98 -2.82 -1.84 -0.613 0.31392E+04 235 boehmite 4.41 0.73 -3.68 -0.613 0.62843E+04 237 ferrous-oxide 9.81 6.73 -3.08 -0.771 0.52638E+04 243 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18067E+04 245 an20ab80 2.02 1.34 -0.68 -0.052 0.11603E+04 246 an25ab75 2.65 1.77 -0.88 -0.067 0.14974E+04 247 an30ab70 3.28 2.20 -1.08 -0.083 0.18440E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 MOLES Current total amount of reactant added: 0.1999900 MOLES New total amount of reactant added: 0.2039900 MOLES Mixing fraction reached given limit of 0.2000E+00 TOTMIX = 0.2040E+00 Execution stopped.