File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.82771E+02 0.13415E-09 0.8160 0.00000000E+00 H2O 2 0. -0.70051E+01 0.10000E+01 0.9995 0.00000000E+00 Cl- 3 -1. 0.13178E-02 0.26274E-02 0.8091 0.00000000E+00 SO4-- 4 -2. 0.13955E+00 0.43554E-09 0.4595 0.00000000E+00 HCO3- 5 -1. 0.14472E-01 0.86410E-03 0.8108 0.00000000E+00 HS- 6 -1. -0.13466E+00 0.97996E-02 0.8093 0.00000000E+00 Al+++ 7 3. 0.16304E+02 0.39990E-28 0.1746 0.00000000E+00 H4SiO4 8 0. 0.52064E+02 0.70819E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.57507E+01 0.31222E-06 0.4548 0.00000000E+00 Mg++ 10 2. 0.39683E+01 0.52526E-10 0.4519 0.00000000E+00 Fe++ 11 2. 0.35650E+01 0.14185E-12 0.4526 0.00000000E+00 K+ 12 1. 0.10616E+01 0.23237E-03 0.8110 0.00000000E+00 Na+ 13 1. 0.62764E+01 0.29509E-01 0.8089 0.00000000E+00 Mn++ 14 2. 0.86693E-01 0.46488E-10 0.4531 0.00000000E+00 F- 15 -1. 0.80096E-04 0.80582E-06 0.8068 0.00000000E+00 HPO4-- 16 -2. 0.29588E-01 0.26204E-07 0.4596 0.00000000E+00 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.1318E-06 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.400000E+00 TEMP = 100.0000 SINC = 0.1000E-01 TEMPC = 0.0000 TOTMIX = 0.199990E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 2000.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.6246E+01 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.6119E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.1310E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.9783E-02 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.7969E-04 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.3239E+01 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.2379E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.7091E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.2012E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.1734E-01 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.0000E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.0000E+00 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.9425E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.1166E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.1999900 moles log = -0.6990 Original solution: 1000.0103000 g Original solution / Rock added: 5000.30 (Water/Rock Ratio), log = 3.6990 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1999900 Water: Moles liquid = 0.2766E+02 kg liquid = 0.4984E+00 Moles total = -.7005E+01 kg total = -.1262E+00 Activity = 0.9995 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3096242E-01 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.1318E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13415E-09 -9.8724 0.10946E-09 -9.9607 0.81597E+00 -0.0883 2 H2O 0.99951E+00 -0.0002 0.99951E+00 -0.0002 3 Cl- 0.26274E-02 -2.5805 0.21259E-02 -2.6725 0.80913E+00 -0.0920 4 SO4-- 0.43554E-09 -9.3610 0.20015E-09 -9.6986 0.45954E+00 -0.3377 5 HCO3- 0.86410E-03 -3.0634 0.70060E-03 -3.1545 0.81079E+00 -0.0911 6 HS- 0.97996E-02 -2.0088 0.79308E-02 -2.1007 0.80930E+00 -0.0919 7 Al+++ 0.39990E-28 -28.3981 0.69834E-29 -29.1559 0.17463E+00 -0.7579 8 H4SiO4 0.70819E-03 -3.1499 0.70819E-03 -3.1499 0.10000E+01 0.0000 9 Ca++ 0.31222E-06 -6.5055 0.14200E-06 -6.8477 0.45480E+00 -0.3422 10 Mg++ 0.52526E-10 -10.2796 0.23737E-10 -10.6246 0.45190E+00 -0.3450 11 Fe++ 0.14185E-12 -12.8482 0.64199E-13 -13.1925 0.45259E+00 -0.3443 12 K+ 0.23237E-03 -3.6338 0.18846E-03 -3.7248 0.81104E+00 -0.0910 13 Na+ 0.29509E-01 -1.5300 0.23870E-01 -1.6221 0.80891E+00 -0.0921 14 Mn++ 0.46488E-10 -10.3327 0.21064E-10 -10.6765 0.45311E+00 -0.3438 15 F- 0.80582E-06 -6.0938 0.65016E-06 -6.1870 0.80683E+00 -0.0932 16 HPO4-- 0.26204E-07 -7.5816 0.12044E-07 -7.9192 0.45963E+00 -0.3376 18 HSiO3- 0.74696E-02 -2.1267 0.60439E-02 -2.2187 0.80913E+00 -0.0920 19 Ca(HSiO3)+ 0.24092E-07 -7.6181 0.19545E-07 -7.7090 0.81129E+00 -0.0908 20 Mg(HSiO3)+ 0.50118E-11 -11.3000 0.40660E-11 -11.3908 0.81129E+00 -0.0908 21 NaHSiO3,aq 0.23333E-02 -2.6320 0.23333E-02 -2.6320 0.10000E+01 0.0000 22 AlO+ 0.97683E-16 -16.0102 0.79249E-16 -16.1010 0.81129E+00 -0.0908 24 HAlO2,aq 0.14411E-09 -9.8413 0.14411E-09 -9.8413 0.10000E+01 0.0000 25 AlO2- 0.36106E-05 -5.4424 0.29142E-05 -5.5355 0.80711E+00 -0.0931 26 CH4,aq 0.26953E-01 -1.5694 0.26953E-01 -1.5694 0.10000E+01 0.0000 27 C2H6,aq 0.13294E-07 -7.8763 0.13294E-07 -7.8763 0.10000E+01 0.0000 28 C3H8,aq 0.15139E-12 -12.8199 0.15139E-12 -12.8199 0.10000E+01 0.0000 29 C4H10,aq 0.16935E-17 -17.7712 0.16935E-17 -17.7712 0.10000E+01 0.0000 30 ethanol,aq 0.60468E-15 -15.2185 0.60468E-15 -15.2185 0.10000E+01 0.0000 31 CO,aq 0.38494E-13 -13.4146 0.38494E-13 -13.4146 0.10000E+01 0.0000 32 CO2,aq 0.16395E-06 -6.7853 0.16395E-06 -6.7853 0.10000E+01 0.0000 33 CO3-2 0.12201E-02 -2.9136 0.55904E-03 -3.2526 0.45818E+00 -0.3390 34 CaCO3,aq 0.99539E-06 -6.0020 0.99539E-06 -6.0020 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.31302E-08 -8.5044 0.25395E-08 -8.5953 0.81129E+00 -0.0908 36 CaCl+ 0.60217E-09 -9.2203 0.48853E-09 -9.3111 0.81129E+00 -0.0908 37 CaCl2,aq 0.24674E-12 -12.6078 0.24674E-12 -12.6078 0.10000E+01 0.0000 38 CaF+ 0.16615E-11 -11.7795 0.13479E-11 -11.8703 0.81129E+00 -0.0908 39 CaOH+ 0.11390E-06 -6.9435 0.92409E-07 -7.0343 0.81129E+00 -0.0908 40 CaSO4,aq 0.90250E-14 -14.0446 0.90250E-14 -14.0446 0.10000E+01 0.0000 41 HCl,aq 0.42643E-13 -13.3702 0.42643E-13 -13.3702 0.10000E+01 0.0000 45 HF,aq 0.48720E-12 -12.3123 0.48720E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.13217E-18 -18.8789 0.10695E-18 -18.9708 0.80913E+00 -0.0920 48 FeCl+ 0.26628E-15 -15.5747 0.21603E-15 -15.6655 0.81129E+00 -0.0908 51 FeF+ 0.26291E-17 -17.5802 0.21330E-17 -17.6710 0.81129E+00 -0.0908 53 FeO,aq 0.20814E-09 -9.6817 0.20814E-09 -9.6817 0.10000E+01 0.0000 54 FeOH+ 0.23520E-10 -10.6286 0.19082E-10 -10.7194 0.81129E+00 -0.0908 55 HFeO2- 0.24576E-07 -7.6095 0.19885E-07 -7.7015 0.80913E+00 -0.0920 56 FeO+ 0.18354E-16 -16.7363 0.14891E-16 -16.8271 0.81129E+00 -0.0908 58 FeO2- 0.31412E-09 -9.5029 0.25417E-09 -9.5949 0.80913E+00 -0.0920 59 HFeO2,aq 0.35385E-11 -11.4512 0.35385E-11 -11.4512 0.10000E+01 0.0000 60 H2,aq 0.93422E-05 -5.0296 0.93422E-05 -5.0296 0.10000E+01 0.0000 61 KCl,aq 0.72615E-08 -8.1390 0.72615E-08 -8.1390 0.10000E+01 0.0000 63 KOH,aq 0.73490E-06 -6.1338 0.73490E-06 -6.1338 0.10000E+01 0.0000 64 KSO4- 0.72340E-12 -12.1406 0.58533E-12 -12.2326 0.80913E+00 -0.0920 65 MgCO3,aq 0.41706E-10 -10.3798 0.41706E-10 -10.3798 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.53465E-12 -12.2719 0.43375E-12 -12.3628 0.81129E+00 -0.0908 67 MgCl+ 0.91231E-13 -13.0399 0.74014E-13 -13.1307 0.81129E+00 -0.0908 68 MgF+ 0.10288E-14 -14.9877 0.83465E-15 -15.0785 0.81129E+00 -0.0908 69 MgOH+ 0.10536E-09 -9.9773 0.85475E-10 -10.0682 0.81129E+00 -0.0908 71 MnF+ 0.28434E-15 -15.5462 0.23068E-15 -15.6370 0.81129E+00 -0.0908 72 MnO,aq 0.18197E-08 -8.7400 0.18197E-08 -8.7400 0.10000E+01 0.0000 73 MnOH+ 0.71690E-09 -9.1445 0.58161E-09 -9.2354 0.81129E+00 -0.0908 74 MnO2-2 0.10995E-10 -10.9588 0.50375E-11 -11.2978 0.45818E+00 -0.3390 75 HMnO2- 0.14931E-09 -9.8259 0.12081E-09 -9.9179 0.80913E+00 -0.0920 78 MnCl+ 0.33990E-12 -12.4686 0.27576E-12 -12.5595 0.81129E+00 -0.0908 79 MnSO4,aq 0.12171E-17 -17.9147 0.12171E-17 -17.9147 0.10000E+01 0.0000 80 NaCl,aq 0.16817E-04 -4.7743 0.16817E-04 -4.7743 0.10000E+01 0.0000 81 NaF,aq 0.36334E-08 -8.4397 0.36334E-08 -8.4397 0.10000E+01 0.0000 82 NaOH,aq 0.93645E-04 -4.0285 0.93645E-04 -4.0285 0.10000E+01 0.0000 84 OH- 0.65365E-02 -2.1847 0.52757E-02 -2.2777 0.80711E+00 -0.0931 89 HPO3-2 0.76568E-15 -15.1160 0.35082E-15 -15.4549 0.45818E+00 -0.3390 91 H2PO3- 0.95173E-19 -19.0215 0.77008E-19 -19.1135 0.80913E+00 -0.0920 92 H3PO4,aq 0.10094E-17 -17.9960 0.10094E-17 -17.9960 0.10000E+01 0.0000 93 H2PO4- 0.30019E-10 -10.5226 0.24321E-10 -10.6140 0.81021E+00 -0.0914 94 PO4-3 0.48002E-09 -9.3187 0.89774E-10 -10.0469 0.18702E+00 -0.7281 98 HP2O7-3 0.48392E-18 -18.3152 0.84647E-19 -19.0724 0.17492E+00 -0.7572 99 P2O7-4 0.38926E-17 -17.4098 0.18474E-18 -18.7334 0.47459E-01 -1.3237 100 H2S,aq 0.26831E-05 -5.5714 0.26831E-05 -5.5714 0.10000E+01 0.0000 101 S2-2 0.32560E-09 -9.4873 0.14918E-09 -9.8263 0.45818E+00 -0.3390 102 S3-2 0.12599E-15 -15.8997 0.57725E-16 -16.2386 0.45818E+00 -0.3390 107 SO3-2 0.52007E-15 -15.2839 0.24310E-15 -15.6142 0.46744E+00 -0.3303 108 HSO3- 0.20592E-17 -17.6863 0.16661E-17 -17.7783 0.80913E+00 -0.0920 109 HSO4- 0.25989E-16 -16.5852 0.21114E-16 -16.6754 0.81241E+00 -0.0902 111 S2O3-2 0.13775E-16 -16.8609 0.63113E-17 -17.1999 0.45818E+00 -0.3390 Charge balance for all species = -.1737E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1341518E-09 -.1766906E-01 -.1776220E+02 0.0000 2 H2O 0.1000000E+01 0.5553205E+02 0.9977777E+06 0.0000 3 Cl- 0.2627383E-02 0.2644208E-02 0.9349691E+02 7.2883 4 SO4-- 0.4355383E-09 -.2695584E-01 -.2582565E+04 10.2228 5 HCO3- 0.8640955E-03 0.2903890E-01 0.1767181E+04 6.8062 6 HS- 0.9799638E-02 0.3675816E-01 0.1212447E+04 7.8601 7 Al+++ 0.3998977E-28 0.3610782E-05 0.9716638E-01 0.7263 8 H4SiO4 0.7081885E-03 0.1051114E-01 0.1007607E+04 -3.1499 9 Ca++ 0.3122234E-06 0.1449340E-05 0.5793287E-01 13.0738 10 Mg++ 0.5252608E-10 0.2052292E-09 0.4976323E-05 9.2969 11 Fe++ 0.1418480E-12 0.2512527E-07 0.1399456E-02 6.7290 12 K+ 0.2323694E-03 0.2331116E-03 0.9090995E+01 6.2360 13 Na+ 0.2950882E-01 0.3195261E-01 0.7326391E+03 8.3386 14 Mn++ 0.4648782E-10 0.2743698E-08 0.1503342E-03 9.2450 15 F- 0.8058231E-06 0.8094586E-06 0.1533738E-01 3.7738 16 HPO4-- 0.2620428E-07 0.2671433E-07 0.2557226E-02 12.0022 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8277101E+02 -.8805872E-02 -.8276221E+02 0.0000000E+00 2 H2O -.7005057E+01 0.2767595E+02 -.3468101E+02 0.0000000E+00 3 Cl- 0.1317815E-02 0.1317815E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1395475E+00 -.1343420E-01 0.1529817E+00 0.0000000E+00 5 HCO3- 0.1447235E-01 0.1447235E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1346622E+00 0.1831946E-01 -.1529817E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1799535E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5238520E-02 0.5205867E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.7223194E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1022817E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1252188E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1161777E-03 0.1061455E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1592448E-01 0.6260452E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1367399E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8009600E-04 0.4034164E-06 0.7969258E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1331383E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.4947E-14 Mass of aqueous solution: 0.499701E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.97 628.7 andradite 0.6119 -0.213 311.0 2.493 5.691 80.79 grossular 0.1310 -0.883 59.02 1.771 1.080 16.42 apatite-OH 0.9783E-02 -2.010 4.914 0.691 0.8994E-01 1.562 apatite-F 0.7969E-04 -4.099 0.4019E-01 -1.396 0.7355E-03 0.1256E-01 clinochlore 0.7091 -0.149 394.1 2.596 7.213 149.9 daphnite 0.2012 -0.696 143.6 2.157 2.628 43.51 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9425 -0.026 262.3 2.419 4.801 102.5 stilbite 3.239 0.510 2283. 3.358 41.78 1065. stilpnomelane-Fe 0.2379 -0.624 256.4 2.409 4.693 88.57 tr.625ac.25prg.125 0.1166 -0.933 99.70 1.999 1.825 32.09 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8236E+00 0.8236E+00 1.0000 -0.084 grossular 0.1764E+00 0.1764E+00 1.0000 -0.754 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7644E+00 0.7644E+00 1.0000 -0.117 daphnite 0.2169E+00 0.2169E+00 1.0000 -0.664 chlorite-Mn 0.1869E-01 0.1869E-01 1.0000 -1.728 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5463.955636 g Volume = 2212.701554 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1999900 moles log = -0.6990 Original solution: 1000.0103000 g Original solution / Rock added: 5000.30 (Water/Rock Ratio), log = 3.6990 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 41.7530 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2599E-01 0.9266 0.1005E+01 0.1085E+01 CO2,gas 0.4510E-06 0.9315 0.1754E-04 0.1883E-04 CH4,gas 0.9737E+00 0.9758 0.3967E+02 0.4066E+02 H2,gas 0.2873E-03 1.0225 0.1227E-01 0.1200E-01 H2S,gas 0.2067E-05 0.8544 0.7376E-04 0.8632E-04 S2,gas 0.3251E-25 1.0000 0.1357E-23 0.1357E-23 CO,gas 0.1374E-11 1.0000 0.5736E-10 0.5736E-10 SO3,gas 0.2173E-46 1.0000 0.9072E-45 0.9072E-45 SO2,gas 0.1037E-25 1.0000 0.4331E-24 0.4331E-24 HF,gas 0.2865E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1802E-17 1.0000 0.7524E-16 0.7524E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28969E+04 0.002 2 CO2,gas -6.66 -13.12 -6.45 -2.152 0.11022E+05 -4.756 3 CH4,gas 4.54 4.44 -0.10 -0.025 0.17154E+03 1.599 4 H2,gas 8.00 4.39 -3.61 -2.063 0.61645E+04 -1.911 5 H2S,gas -6.23 -12.06 -5.83 -2.916 0.99566E+04 -4.132 6 S2,gas -7.34 -32.90 -25.57 -3.933 0.43654E+05 -23.867 7 CO,gas 3.21 -8.73 -11.94 -3.674 0.20388E+05 -10.241 8 SO3,gas 17.12 -29.62 -46.74 -11.685 0.79809E+05 -45.042 9 SO2,gas 0.83 -25.23 -26.06 -6.950 0.44501E+05 -24.363 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.63 -17.82 -8.911 0.30431E+05 -16.124 12 acmite 7.71 6.57 -1.14 -0.118 0.19399E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80581E+04 21 analcite 3.32 2.77 -0.56 -0.062 0.95022E+03 26 ankerite -2.14 -6.43 -4.29 -0.715 0.73297E+04 27 annite 20.12 17.70 -2.42 -0.135 0.41385E+04 28 phlogopite 27.06 25.40 -1.66 -0.092 0.28366E+04 30 anorthite 12.71 8.23 -4.48 -0.345 0.76559E+04 38 aragonite 0.97 -0.04 -1.01 -0.336 0.17212E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55870E+04 40 calcite 0.81 -0.04 -0.85 -0.284 0.14570E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.444 0.53073E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71343E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70567E+04 44 carpholite-Fe 6.71 1.88 -4.83 -0.322 0.82492E+04 45 celadonite 5.34 3.66 -1.68 -0.099 0.28704E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47534E+04 47 chrysotile 23.89 21.59 -2.30 -0.192 0.39300E+04 52 chlorite-Al-free 47.17 43.18 -3.99 -0.166 0.68152E+04 54 chloritoid-Fe 9.17 5.03 -4.14 -0.276 0.70734E+04 55 chloritoid-Mn 11.40 7.55 -3.85 -0.257 0.65806E+04 57 coesite -2.38 -3.15 -0.77 -0.258 0.13205E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10059E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71237E+04 68 diaspore 2.87 0.73 -2.15 -0.358 0.36674E+04 69 diamond -3.10 -4.34 -1.23 -0.352 0.21058E+04 70 diopside 16.18 16.07 -0.11 -0.011 0.18783E+03 71 hedenbergite 14.21 13.50 -0.70 -0.070 0.12034E+04 72 dolomite,ordered 0.55 -3.86 -4.41 -0.734 0.75236E+04 74 enstatite 17.26 12.29 -4.97 -0.497 0.84869E+04 76 clinoenstatite 17.17 12.29 -4.87 -0.487 0.83185E+04 78 epidote 24.67 22.68 -1.99 -0.096 0.33900E+04 79 clinozoisite 22.81 18.88 -3.93 -0.179 0.67095E+04 80 epidote-Fe 29.84 26.49 -3.35 -0.174 0.57171E+04 81 fayalite 14.05 10.31 -3.74 -0.534 0.63818E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68141E+04 86 gibbsite 4.08 0.73 -3.35 -0.479 0.57263E+04 87 glaucophane 22.97 20.82 -2.15 -0.058 0.36738E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70967E+04 89 graphite -3.55 -4.34 -0.79 -0.226 0.13481E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38460E+04 93 hematite 12.57 9.07 -3.50 -0.424 0.59732E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 98 jadeite 4.22 2.77 -1.45 -0.145 0.24754E+04 100 kalsilite 7.58 3.81 -3.77 -0.539 0.64398E+04 101 kaolinite -1.33 -4.85 -3.51 -0.320 0.60011E+04 104 laumontite 2.88 1.93 -0.96 -0.064 0.16333E+04 105 lawsonite 9.62 8.23 -1.39 -0.093 0.23733E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59009E+04 108 lizardite 23.24 21.59 -1.65 -0.138 0.28226E+04 109 magnesite 0.69 -3.82 -4.51 -1.503 0.76990E+04 110 magnetite 20.09 15.80 -4.29 -0.350 0.73263E+04 111 minnesotaite 10.39 7.59 -2.80 -0.165 0.47804E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82186E+04 123 muscovite 2.58 -1.03 -3.62 -0.213 0.61764E+04 124 paragonite 4.24 1.07 -3.17 -0.187 0.54155E+04 125 nepheline 8.34 5.91 -2.42 -0.346 0.41397E+04 131 periclase-Fe 11.63 6.73 -4.90 -1.224 0.83629E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36554E+04 139 prehnite 19.37 18.15 -1.22 -0.072 0.20855E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.032 0.92099E+03 141 pumpellyite-Fe 46.27 43.76 -2.51 -0.056 0.42927E+04 142 pumpellyite-Mg 48.99 46.32 -2.67 -0.059 0.45617E+04 145 pyrite -21.25 -21.78 -0.54 -0.126 0.91583E+03 146 pyrrhotite -4.26 -5.33 -1.07 -0.357 0.18306E+04 147 pyrrhotiteFe0.875 -6.02 -6.72 -0.70 -0.258 0.11967E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.261 0.22254E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84866E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.27319E+03 154 rhodochrosite -0.98 -3.87 -2.89 -0.965 0.49413E+04 155 rhodonite 7.45 6.10 -1.35 -0.270 0.23056E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.39 -3.78 -1.259 0.64510E+04 168 stilpnomelane-Mg 27.44 25.86 -1.58 -0.047 0.27063E+04 174 talc 16.49 15.29 -1.20 -0.071 0.20472E+04 177 tephroite 18.09 15.34 -2.75 -0.392 0.46881E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.89316E+03 182 tremolite 47.87 47.43 -0.43 -0.012 0.74184E+03 183 ferroactinolite 38.45 34.60 -3.86 -0.104 0.65858E+04 184 troilite-low -4.41 -5.33 -0.92 -0.307 0.15734E+04 190 wairakite 3.95 1.93 -2.02 -0.119 0.34545E+04 191 walstromite 11.51 9.92 -1.59 -0.317 0.27065E+04 192 wollastonite 10.46 9.92 -0.54 -0.107 0.91697E+03 193 pseudo-wollastonite 11.00 9.92 -1.08 -0.215 0.18368E+04 194 zoisite 22.85 18.88 -3.97 -0.181 0.67836E+04 195 akaganeite 7.75 4.53 -3.22 -0.696 0.54993E+04 202 chalcedony -2.80 -3.15 -0.35 -0.116 0.59248E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66077E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68694E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73487E+04 207 montmorillonite-Na -2.04 -5.57 -3.53 -0.216 0.60243E+04 208 nontronite-Ca 3.21 -0.09 -3.31 -0.215 0.56493E+04 209 nontronite-H 2.53 -2.25 -4.78 -0.321 0.81684E+04 210 nontronite-K 3.34 -0.19 -3.53 -0.227 0.60343E+04 211 nontronite-Mg 3.07 -0.72 -3.79 -0.246 0.64745E+04 212 nontronite-Na 3.52 0.50 -3.02 -0.194 0.51551E+04 228 tobermorite 9.82 7.74 -2.08 -0.568 0.35558E+04 234 alabandite -0.98 -2.82 -1.84 -0.613 0.31392E+04 237 boehmite 4.41 0.73 -3.68 -0.613 0.62843E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.771 0.52638E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.353 0.18067E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11603E+04 248 an25ab75 2.65 1.77 -0.88 -0.067 0.14974E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18440E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0100000 MOLES Current total amount of reactant added: 0.1999900 MOLES New total amount of reactant added: 0.2099900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2099900 Water: Moles liquid = 0.2766E+02 kg liquid = 0.4983E+00 Moles total = -.6997E+01 kg total = -.1261E+00 Activity = 0.9995 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3188293E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1377E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13803E-09 -9.8600 0.11240E-09 -9.9492 0.81427E+00 -0.0892 2 H2O 0.99949E+00 -0.0002 0.99949E+00 -0.0002 3 Cl- 0.27450E-02 -2.5615 0.22160E-02 -2.6544 0.80731E+00 -0.0930 4 SO4-- 0.50970E-09 -9.2927 0.23218E-09 -9.6342 0.45553E+00 -0.3415 5 HCO3- 0.10001E-02 -2.9999 0.80910E-03 -3.0920 0.80899E+00 -0.0921 6 HS- 0.10288E-01 -1.9877 0.83075E-02 -2.0805 0.80748E+00 -0.0929 7 Al+++ 0.43971E-28 -28.3568 0.75255E-29 -29.1235 0.17115E+00 -0.7666 8 H4SiO4 0.71011E-03 -3.1487 0.71011E-03 -3.1487 0.10000E+01 0.0000 9 Ca++ 0.32892E-06 -6.4829 0.14825E-06 -6.8290 0.45072E+00 -0.3461 10 Mg++ 0.55941E-10 -10.2523 0.25050E-10 -10.6012 0.44778E+00 -0.3489 11 Fe++ 0.15060E-12 -12.8222 0.67542E-13 -13.1704 0.44848E+00 -0.3483 12 K+ 0.23826E-03 -3.6229 0.19282E-03 -3.7149 0.80925E+00 -0.0919 13 Na+ 0.30259E-01 -1.5191 0.24421E-01 -1.6122 0.80707E+00 -0.0931 14 Mn++ 0.49423E-10 -10.3061 0.22191E-10 -10.6538 0.44901E+00 -0.3477 15 F- 0.78659E-06 -6.1043 0.63318E-06 -6.1985 0.80496E+00 -0.0942 16 HPO4-- 0.25488E-07 -7.5937 0.11613E-07 -7.9351 0.45562E+00 -0.3414 18 HSiO3- 0.73110E-02 -2.1360 0.59022E-02 -2.2290 0.80731E+00 -0.0930 19 Ca(HSiO3)+ 0.24616E-07 -7.6088 0.19927E-07 -7.7006 0.80950E+00 -0.0918 20 Mg(HSiO3)+ 0.51764E-11 -11.2860 0.41903E-11 -11.3778 0.80950E+00 -0.0918 21 NaHSiO3,aq 0.23313E-02 -2.6324 0.23313E-02 -2.6324 0.10000E+01 0.0000 22 AlO+ 0.10006E-15 -15.9997 0.80999E-16 -16.0915 0.80950E+00 -0.0918 24 HAlO2,aq 0.14344E-09 -9.8433 0.14344E-09 -9.8433 0.10000E+01 0.0000 25 AlO2- 0.35082E-05 -5.4549 0.28250E-05 -5.5490 0.80525E+00 -0.0941 26 CH4,aq 0.28107E-01 -1.5512 0.28107E-01 -1.5512 0.10000E+01 0.0000 27 C2H6,aq 0.14929E-07 -7.8260 0.14929E-07 -7.8260 0.10000E+01 0.0000 28 C3H8,aq 0.18307E-12 -12.7374 0.18307E-12 -12.7374 0.10000E+01 0.0000 29 C4H10,aq 0.22054E-17 -17.6565 0.22054E-17 -17.6565 0.10000E+01 0.0000 30 ethanol,aq 0.70120E-15 -15.1542 0.70120E-15 -15.1542 0.10000E+01 0.0000 31 CO,aq 0.44205E-13 -13.3545 0.44205E-13 -13.3545 0.10000E+01 0.0000 32 CO2,aq 0.19442E-06 -6.7113 0.19442E-06 -6.7113 0.10000E+01 0.0000 33 CO3-2 0.13845E-02 -2.8587 0.62877E-03 -3.2015 0.45415E+00 -0.3428 34 CaCO3,aq 0.11688E-05 -5.9323 0.11688E-05 -5.9323 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.37824E-08 -8.4222 0.30618E-08 -8.5140 0.80950E+00 -0.0918 36 CaCl+ 0.65677E-09 -9.1826 0.53166E-09 -9.2744 0.80950E+00 -0.0918 37 CaCl2,aq 0.27991E-12 -12.5530 0.27991E-12 -12.5530 0.10000E+01 0.0000 38 CaF+ 0.16930E-11 -11.7713 0.13705E-11 -11.8631 0.80950E+00 -0.0918 39 CaOH+ 0.11607E-06 -6.9353 0.93955E-07 -7.0271 0.80950E+00 -0.0918 40 CaSO4,aq 0.10930E-13 -13.9614 0.10930E-13 -13.9614 0.10000E+01 0.0000 41 HCl,aq 0.45642E-13 -13.3406 0.45642E-13 -13.3406 0.10000E+01 0.0000 45 HF,aq 0.48719E-12 -12.3123 0.48719E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.12901E-18 -18.8894 0.10415E-18 -18.9823 0.80731E+00 -0.0930 48 FeCl+ 0.29266E-15 -15.5336 0.23691E-15 -15.6254 0.80950E+00 -0.0918 51 FeF+ 0.26997E-17 -17.5687 0.21854E-17 -17.6605 0.80950E+00 -0.0918 53 FeO,aq 0.20769E-09 -9.6826 0.20769E-09 -9.6826 0.10000E+01 0.0000 54 FeOH+ 0.24152E-10 -10.6171 0.19551E-10 -10.7088 0.80950E+00 -0.0918 55 HFeO2- 0.23936E-07 -7.6209 0.19324E-07 -7.7139 0.80731E+00 -0.0930 56 FeO+ 0.19153E-16 -16.7178 0.15504E-16 -16.8096 0.80950E+00 -0.0918 58 FeO2- 0.31090E-09 -9.5074 0.25099E-09 -9.6003 0.80731E+00 -0.0930 59 HFeO2,aq 0.35880E-11 -11.4451 0.35880E-11 -11.4451 0.10000E+01 0.0000 60 H2,aq 0.90466E-05 -5.0435 0.90466E-05 -5.0435 0.10000E+01 0.0000 61 KCl,aq 0.77442E-08 -8.1110 0.77442E-08 -8.1110 0.10000E+01 0.0000 63 KOH,aq 0.73223E-06 -6.1354 0.73223E-06 -6.1354 0.10000E+01 0.0000 64 KSO4- 0.86050E-12 -12.0652 0.69469E-12 -12.1582 0.80731E+00 -0.0930 65 MgCO3,aq 0.49503E-10 -10.3054 0.49503E-10 -10.3054 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.65304E-12 -12.1851 0.52864E-12 -12.2768 0.80950E+00 -0.0918 67 MgCl+ 0.10058E-12 -12.9975 0.81420E-13 -13.0893 0.80950E+00 -0.0918 68 MgF+ 0.10597E-14 -14.9748 0.85780E-15 -15.0666 0.80950E+00 -0.0918 69 MgOH+ 0.10852E-09 -9.9645 0.87847E-10 -10.0563 0.80950E+00 -0.0918 71 MnF+ 0.29237E-15 -15.5341 0.23667E-15 -15.6259 0.80950E+00 -0.0918 72 MnO,aq 0.18182E-08 -8.7404 0.18182E-08 -8.7404 0.10000E+01 0.0000 73 MnOH+ 0.73715E-09 -9.1324 0.59672E-09 -9.2242 0.80950E+00 -0.0918 74 MnO2-2 0.10512E-10 -10.9783 0.47740E-11 -11.3211 0.45415E+00 -0.3428 75 HMnO2- 0.14562E-09 -9.8368 0.11756E-09 -9.9298 0.80731E+00 -0.0930 78 MnCl+ 0.37409E-12 -12.4270 0.30283E-12 -12.5188 0.80950E+00 -0.0918 79 MnSO4,aq 0.14875E-17 -17.8276 0.14875E-17 -17.8276 0.10000E+01 0.0000 80 NaCl,aq 0.17935E-04 -4.7463 0.17935E-04 -4.7463 0.10000E+01 0.0000 81 NaF,aq 0.36202E-08 -8.4413 0.36202E-08 -8.4413 0.10000E+01 0.0000 82 NaOH,aq 0.93305E-04 -4.0301 0.93305E-04 -4.0301 0.10000E+01 0.0000 84 OH- 0.63804E-02 -2.1951 0.51378E-02 -2.2892 0.80525E+00 -0.0941 89 HPO3-2 0.72124E-15 -15.1419 0.32755E-15 -15.4847 0.45415E+00 -0.3428 91 H2PO3- 0.91448E-19 -19.0388 0.73827E-19 -19.1318 0.80731E+00 -0.0930 92 H3PO4,aq 0.10260E-17 -17.9888 0.10260E-17 -17.9888 0.10000E+01 0.0000 93 H2PO4- 0.29785E-10 -10.5260 0.24078E-10 -10.6184 0.80840E+00 -0.0924 94 PO4-3 0.45921E-09 -9.3380 0.84296E-10 -10.0742 0.18357E+00 -0.7362 98 HP2O7-3 0.47129E-18 -18.3267 0.80798E-19 -19.0926 0.17144E+00 -0.7659 99 P2O7-4 0.37470E-17 -17.4263 0.17173E-18 -18.7651 0.45832E-01 -1.3388 100 H2S,aq 0.28858E-05 -5.5397 0.28858E-05 -5.5397 0.10000E+01 0.0000 101 S2-2 0.37221E-09 -9.4292 0.16904E-09 -9.7720 0.45415E+00 -0.3428 102 S3-2 0.15996E-15 -15.7960 0.72648E-16 -16.1388 0.45415E+00 -0.3428 107 SO3-2 0.58916E-15 -15.2298 0.27309E-15 -15.5637 0.46352E+00 -0.3339 108 HSO3- 0.23806E-17 -17.6233 0.19219E-17 -17.7163 0.80731E+00 -0.0930 109 HSO4- 0.31024E-16 -16.5083 0.25150E-16 -16.5995 0.81065E+00 -0.0912 111 S2O3-2 0.17340E-16 -16.7610 0.78748E-17 -17.1038 0.45415E+00 -0.3428 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1380342E-09 -.1751581E-01 -.1760710E+02 0.0000 2 H2O 0.1000000E+01 0.5553321E+02 0.9977391E+06 0.0000 3 Cl- 0.2744966E-02 0.2762910E-02 0.9768827E+02 7.2948 4 SO4-- 0.5096976E-09 -.2810937E-01 -.2692921E+04 10.2643 5 HCO3- 0.1000133E-02 0.3049311E-01 0.1855567E+04 6.8572 6 HS- 0.1028820E-01 0.3840045E-01 0.1266542E+04 7.8687 7 Al+++ 0.4397133E-28 0.3508374E-05 0.9440494E-01 0.7243 8 H4SiO4 0.7101087E-03 0.1035237E-01 0.9923283E+03 -3.1487 9 Ca++ 0.3289153E-06 0.1642846E-05 0.6566377E-01 13.0695 10 Mg++ 0.5594125E-10 0.2198957E-09 0.5331631E-05 9.2973 11 Fe++ 0.1506017E-12 0.2448255E-07 0.1363576E-02 6.7281 12 K+ 0.2382630E-03 0.2390030E-03 0.9320195E+01 6.2344 13 Na+ 0.3025902E-01 0.3270152E-01 0.7497662E+03 8.3370 14 Mn++ 0.4942250E-10 0.2761281E-08 0.1512886E-03 9.2447 15 F- 0.7865921E-06 0.7902145E-06 0.1497186E-01 3.7508 16 HPO4-- 0.2548753E-07 0.2597653E-07 0.2486452E-02 11.9634 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276994E+02 -.8728493E-02 -.8276121E+02 0.0000000E+00 2 H2O -.6996870E+01 0.2767335E+02 -.3467022E+02 0.0000000E+00 3 Cl- 0.1376815E-02 0.1376815E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1395952E+00 -.1400748E-01 0.1536027E+00 0.0000000E+00 5 HCO3- 0.1519535E-01 0.1519535E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1344670E+00 0.1913574E-01 -.1536027E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1748296E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5158799E-02 0.5205875E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.8186645E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1095786E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1220016E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1191001E-03 0.1061452E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1629584E-01 0.6260081E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1376004E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8409600E-04 0.3937803E-06 0.8370222E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1294464E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.1128E-13 Mass of aqueous solution: 0.499673E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2099900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.97 628.7 andradite 0.6144 -0.212 312.2 2.494 5.714 81.12 grossular 0.1291 -0.889 58.17 1.765 1.065 16.19 apatite-OH 0.9779E-02 -2.010 4.912 0.691 0.8990E-01 1.561 apatite-F 0.8370E-04 -4.077 0.4221E-01 -1.375 0.7725E-03 0.1319E-01 clinochlore 0.7103 -0.149 394.8 2.596 7.225 150.2 daphnite 0.2009 -0.697 143.4 2.156 2.624 43.45 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9427 -0.026 262.4 2.419 4.802 102.5 stilbite 3.241 0.511 2284. 3.359 41.80 1065. stilpnomelane-Fe 0.2376 -0.624 256.1 2.408 4.687 88.46 tr.625ac.25prg.125 0.1150 -0.939 98.27 1.992 1.798 31.63 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8263E+00 0.8263E+00 1.0000 -0.083 grossular 0.1737E+00 0.1737E+00 1.0000 -0.760 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7649E+00 0.7649E+00 1.0000 -0.116 daphnite 0.2164E+00 0.2164E+00 1.0000 -0.665 chlorite-Mn 0.1867E-01 0.1867E-01 1.0000 -1.729 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5464.189197 g Volume = 2212.930103 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2099900 moles log = -0.6778 Original solution: 1000.0103000 g Original solution / Rock added: 4762.18 (Water/Rock Ratio), log = 3.6778 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 43.5373 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2498E-01 0.9244 0.1005E+01 0.1088E+01 CO2,gas 0.5143E-06 0.9289 0.2080E-04 0.2239E-04 CH4,gas 0.9747E+00 0.9749 0.4137E+02 0.4244E+02 H2,gas 0.2665E-03 1.0235 0.1188E-01 0.1160E-01 H2S,gas 0.2146E-05 0.8489 0.7933E-04 0.9345E-04 S2,gas 0.3846E-25 1.0000 0.1675E-23 0.1675E-23 CO,gas 0.1513E-11 1.0000 0.6587E-10 0.6587E-10 SO3,gas 0.2549E-46 1.0000 0.1110E-44 0.1110E-44 SO2,gas 0.1178E-25 1.0000 0.5130E-24 0.5130E-24 HF,gas 0.2748E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1850E-17 1.0000 0.8054E-16 0.8054E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 50 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28969E+04 0.002 2 CO2,gas -6.66 -13.04 -6.38 -2.127 0.10895E+05 -4.682 3 CH4,gas 4.54 4.46 -0.08 -0.021 0.14047E+03 1.617 4 H2,gas 8.00 4.38 -3.62 -2.071 0.61883E+04 -1.925 5 H2S,gas -6.23 -12.03 -5.80 -2.900 0.99025E+04 -4.101 6 S2,gas -7.34 -32.81 -25.48 -3.919 0.43498E+05 -23.776 7 CO,gas 3.21 -8.67 -11.88 -3.655 0.20285E+05 -10.181 8 SO3,gas 17.12 -29.53 -46.65 -11.663 0.79660E+05 -44.955 9 SO2,gas 0.83 -25.16 -25.99 -6.930 0.44375E+05 -24.290 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.60 -17.79 -8.896 0.30381E+05 -16.094 12 acmite 7.71 6.58 -1.13 -0.117 0.19282E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80607E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95228E+03 26 ankerite -2.14 -6.28 -4.15 -0.692 0.70858E+04 27 annite 20.12 17.70 -2.43 -0.135 0.41433E+04 28 phlogopite 27.06 25.40 -1.66 -0.092 0.28346E+04 30 anorthite 12.71 8.22 -4.49 -0.345 0.76660E+04 38 aragonite 0.97 0.03 -0.94 -0.313 0.16021E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55864E+04 40 calcite 0.81 0.03 -0.78 -0.261 0.13379E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.444 0.53114E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.597 0.71384E+04 43 carpholite-Mg 8.58 4.45 -4.13 -0.276 0.70588E+04 44 carpholite-Fe 6.71 1.88 -4.83 -0.322 0.82536E+04 45 celadonite 5.34 3.66 -1.68 -0.099 0.28677E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47530E+04 47 chrysotile 23.89 21.59 -2.30 -0.192 0.39239E+04 52 chlorite-Al-free 47.17 43.19 -3.98 -0.166 0.68031E+04 54 chloritoid-Fe 9.17 5.03 -4.15 -0.276 0.70798E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65861E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13185E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10038E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.15 -0.358 0.36708E+04 69 diamond -3.10 -4.29 -1.19 -0.339 0.20271E+04 70 diopside 16.18 16.07 -0.11 -0.011 0.19038E+03 71 hedenbergite 14.21 13.50 -0.71 -0.071 0.12083E+04 72 dolomite,ordered 0.55 -3.72 -4.26 -0.710 0.72774E+04 74 enstatite 17.26 12.30 -4.97 -0.497 0.84814E+04 76 clinoenstatite 17.17 12.30 -4.87 -0.487 0.83130E+04 78 epidote 24.67 22.68 -1.99 -0.096 0.33951E+04 79 clinozoisite 22.81 18.87 -3.94 -0.179 0.67283E+04 80 epidote-Fe 29.84 26.50 -3.34 -0.174 0.57084E+04 81 fayalite 14.05 10.31 -3.74 -0.534 0.63830E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68132E+04 86 gibbsite 4.08 0.72 -3.36 -0.479 0.57298E+04 87 glaucophane 22.97 20.83 -2.15 -0.058 0.36677E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70975E+04 89 graphite -3.55 -4.29 -0.74 -0.212 0.12693E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38467E+04 93 hematite 12.57 9.08 -3.49 -0.423 0.59526E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28935E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24774E+04 100 kalsilite 7.58 3.81 -3.77 -0.539 0.64439E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60039E+04 104 laumontite 2.88 1.92 -0.96 -0.064 0.16393E+04 105 lawsonite 9.62 8.22 -1.40 -0.093 0.23834E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59029E+04 108 lizardite 23.24 21.59 -1.65 -0.137 0.28166E+04 109 magnesite 0.69 -3.74 -4.43 -1.478 0.75719E+04 110 magnetite 20.09 15.81 -4.28 -0.349 0.73073E+04 111 minnesotaite 10.39 7.59 -2.80 -0.165 0.47771E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82192E+04 123 muscovite 2.58 -1.04 -3.62 -0.213 0.61832E+04 124 paragonite 4.24 1.06 -3.18 -0.187 0.54223E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41438E+04 131 periclase-Fe 11.63 6.73 -4.90 -1.225 0.83645E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36534E+04 139 prehnite 19.37 18.14 -1.23 -0.072 0.21009E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92263E+03 141 pumpellyite-Fe 46.27 43.73 -2.54 -0.056 0.43285E+04 142 pumpellyite-Mg 48.99 46.30 -2.69 -0.060 0.45953E+04 145 pyrite -21.25 -21.71 -0.46 -0.108 0.78553E+03 146 pyrrhotite -4.26 -5.30 -1.04 -0.347 0.17781E+04 147 pyrrhotiteFe0.875 -6.02 -6.69 -0.67 -0.246 0.11412E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22239E+04 149 pyrophyllite -6.18 -11.15 -4.97 -0.311 0.84853E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.27115E+03 154 rhodochrosite -0.98 -3.80 -2.82 -0.940 0.48155E+04 155 rhodonite 7.45 6.10 -1.35 -0.270 0.23042E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.31 -3.71 -1.235 0.63262E+04 168 stilpnomelane-Mg 27.44 25.86 -1.58 -0.047 0.26949E+04 174 talc 16.49 15.30 -1.19 -0.070 0.20371E+04 177 tephroite 18.09 15.34 -2.75 -0.392 0.46872E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.89112E+03 182 tremolite 47.87 47.44 -0.43 -0.012 0.73677E+03 183 ferroactinolite 38.45 34.59 -3.86 -0.104 0.65921E+04 184 troilite-low -4.41 -5.30 -0.89 -0.297 0.15210E+04 190 wairakite 3.95 1.92 -2.03 -0.119 0.34606E+04 191 walstromite 11.51 9.92 -1.59 -0.318 0.27118E+04 192 wollastonite 10.46 9.92 -0.54 -0.108 0.92224E+03 193 pseudo-wollastonite 11.00 9.92 -1.08 -0.216 0.18421E+04 194 zoisite 22.85 18.87 -3.98 -0.181 0.68024E+04 195 akaganeite 7.75 4.54 -3.21 -0.695 0.54890E+04 202 chalcedony -2.80 -3.15 -0.35 -0.115 0.59044E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66062E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68677E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73460E+04 207 montmorillonite-Na -2.04 -5.56 -3.53 -0.216 0.60226E+04 208 nontronite-Ca 3.21 -0.08 -3.29 -0.214 0.56235E+04 209 nontronite-H 2.53 -2.24 -4.77 -0.320 0.81414E+04 210 nontronite-K 3.34 -0.18 -3.52 -0.226 0.60082E+04 211 nontronite-Mg 3.07 -0.70 -3.78 -0.245 0.64474E+04 212 nontronite-Na 3.52 0.52 -3.00 -0.193 0.51291E+04 228 tobermorite 9.82 7.74 -2.08 -0.569 0.35599E+04 234 alabandite -0.98 -2.79 -1.81 -0.602 0.30858E+04 237 boehmite 4.41 0.72 -3.68 -0.614 0.62878E+04 238 dolomite,disordered 1.25 -3.72 -4.96 -0.827 0.84743E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.771 0.52654E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18046E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11623E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.14999E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18471E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0100000 MOLES Current total amount of reactant added: 0.2099900 MOLES New total amount of reactant added: 0.2199900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2199900 Water: Moles liquid = 0.2766E+02 kg liquid = 0.4983E+00 Moles total = -.6989E+01 kg total = -.1259E+00 Activity = 0.9995 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3285993E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.1436E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14213E-09 -9.8473 0.11548E-09 -9.9375 0.81252E+00 -0.0902 2 H2O 0.99947E+00 -0.0002 0.99947E+00 -0.0002 3 Cl- 0.28625E-02 -2.5433 0.23055E-02 -2.6372 0.80542E+00 -0.0940 4 SO4-- 0.59386E-09 -9.2263 0.26807E-09 -9.5718 0.45139E+00 -0.3454 5 HCO3- 0.11518E-02 -2.9386 0.92967E-03 -3.0317 0.80714E+00 -0.0931 6 HS- 0.10777E-01 -1.9675 0.86817E-02 -2.0614 0.80559E+00 -0.0939 7 Al+++ 0.48481E-28 -28.3144 0.81254E-29 -29.0902 0.16760E+00 -0.7757 8 H4SiO4 0.71202E-03 -3.1475 0.71202E-03 -3.1475 0.10000E+01 0.0000 9 Ca++ 0.34709E-06 -6.4596 0.15498E-06 -6.8097 0.44652E+00 -0.3502 10 Mg++ 0.59674E-10 -10.2242 0.26468E-10 -10.5773 0.44354E+00 -0.3531 11 Fe++ 0.16016E-12 -12.7955 0.71150E-13 -13.1478 0.44425E+00 -0.3524 12 K+ 0.24449E-03 -3.6117 0.19740E-03 -3.7047 0.80740E+00 -0.0929 13 Na+ 0.31052E-01 -1.5079 0.25002E-01 -1.6020 0.80518E+00 -0.0941 14 Mn++ 0.52629E-10 -10.2788 0.23409E-10 -10.6306 0.44479E+00 -0.3518 15 F- 0.76741E-06 -6.1150 0.61625E-06 -6.2102 0.80303E+00 -0.0953 16 HPO4-- 0.24764E-07 -7.6062 0.11180E-07 -7.9515 0.45149E+00 -0.3454 18 HSiO3- 0.71517E-02 -2.1456 0.57601E-02 -2.2396 0.80542E+00 -0.0940 19 Ca(HSiO3)+ 0.25172E-07 -7.5991 0.20331E-07 -7.6919 0.80765E+00 -0.0928 20 Mg(HSiO3)+ 0.53501E-11 -11.2716 0.43210E-11 -11.3644 0.80765E+00 -0.0928 21 NaHSiO3,aq 0.23292E-02 -2.6328 0.23292E-02 -2.6328 0.10000E+01 0.0000 22 AlO+ 0.10257E-15 -15.9890 0.82843E-16 -16.0817 0.80765E+00 -0.0928 24 HAlO2,aq 0.14279E-09 -9.8453 0.14279E-09 -9.8453 0.10000E+01 0.0000 25 AlO2- 0.34070E-05 -5.4676 0.27369E-05 -5.5627 0.80332E+00 -0.0951 26 CH4,aq 0.29231E-01 -1.5341 0.29231E-01 -1.5341 0.10000E+01 0.0000 27 C2H6,aq 0.16667E-07 -7.7781 0.16667E-07 -7.7781 0.10000E+01 0.0000 28 C3H8,aq 0.21941E-12 -12.6587 0.21941E-12 -12.6587 0.10000E+01 0.0000 29 C4H10,aq 0.28374E-17 -17.5471 0.28374E-17 -17.5471 0.10000E+01 0.0000 30 ethanol,aq 0.80805E-15 -15.0926 0.80805E-15 -15.0926 0.10000E+01 0.0000 31 CO,aq 0.50560E-13 -13.2962 0.50560E-13 -13.2962 0.10000E+01 0.0000 32 CO2,aq 0.22953E-06 -6.6392 0.22953E-06 -6.6392 0.10000E+01 0.0000 33 CO3-2 0.15626E-02 -2.8062 0.70316E-03 -3.1529 0.45000E+00 -0.3468 34 CaCO3,aq 0.13665E-05 -5.8644 0.13665E-05 -5.8644 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.45538E-08 -8.3416 0.36779E-08 -8.4344 0.80765E+00 -0.0928 36 CaCl+ 0.71597E-09 -9.1451 0.57825E-09 -9.2379 0.80765E+00 -0.0928 37 CaCl2,aq 0.31673E-12 -12.4993 0.31673E-12 -12.4993 0.10000E+01 0.0000 38 CaF+ 0.17265E-11 -11.7628 0.13944E-11 -11.8556 0.80765E+00 -0.0928 39 CaOH+ 0.11836E-06 -6.9268 0.95597E-07 -7.0196 0.80765E+00 -0.0928 40 CaSO4,aq 0.13193E-13 -13.8797 0.13193E-13 -13.8797 0.10000E+01 0.0000 41 HCl,aq 0.48789E-13 -13.3117 0.48789E-13 -13.3117 0.10000E+01 0.0000 45 HF,aq 0.48718E-12 -12.3123 0.48718E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.12585E-18 -18.9001 0.10136E-18 -18.9941 0.80542E+00 -0.0940 48 FeCl+ 0.32148E-15 -15.4928 0.25964E-15 -15.5856 0.80765E+00 -0.0928 51 FeF+ 0.27742E-17 -17.5569 0.22406E-17 -17.6496 0.80765E+00 -0.0928 53 FeO,aq 0.20724E-09 -9.6835 0.20724E-09 -9.6835 0.10000E+01 0.0000 54 FeOH+ 0.24818E-10 -10.6052 0.20045E-10 -10.6980 0.80765E+00 -0.0928 55 HFeO2- 0.23301E-07 -7.6326 0.18767E-07 -7.7266 0.80542E+00 -0.0940 56 FeO+ 0.19996E-16 -16.6991 0.16150E-16 -16.7918 0.80765E+00 -0.0928 58 FeO2- 0.30749E-09 -9.5122 0.24766E-09 -9.6062 0.80542E+00 -0.0940 59 HFeO2,aq 0.36375E-11 -11.4392 0.36375E-11 -11.4392 0.10000E+01 0.0000 60 H2,aq 0.87643E-05 -5.0573 0.87643E-05 -5.0573 0.10000E+01 0.0000 61 KCl,aq 0.82485E-08 -8.0836 0.82485E-08 -8.0836 0.10000E+01 0.0000 63 KOH,aq 0.72960E-06 -6.1369 0.72960E-06 -6.1369 0.10000E+01 0.0000 64 KSO4- 0.10195E-11 -11.9916 0.82113E-12 -12.0856 0.80542E+00 -0.0940 65 MgCO3,aq 0.58495E-10 -10.2329 0.58495E-10 -10.2329 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.79466E-12 -12.0998 0.64181E-12 -12.1926 0.80765E+00 -0.0928 67 MgCl+ 0.11082E-12 -12.9554 0.89505E-13 -13.0482 0.80765E+00 -0.0928 68 MgF+ 0.10922E-14 -14.9617 0.88215E-15 -15.0545 0.80765E+00 -0.0928 69 MgOH+ 0.11185E-09 -9.9513 0.90340E-10 -10.0441 0.80765E+00 -0.0928 71 MnF+ 0.30085E-15 -15.5217 0.24298E-15 -15.6144 0.80765E+00 -0.0928 72 MnO,aq 0.18168E-08 -8.7407 0.18168E-08 -8.7407 0.10000E+01 0.0000 73 MnOH+ 0.75853E-09 -9.1200 0.61263E-09 -9.2128 0.80765E+00 -0.0928 74 MnO2-2 0.10042E-10 -10.9982 0.45187E-11 -11.3450 0.45000E+00 -0.3468 75 HMnO2- 0.14195E-09 -9.8479 0.11433E-09 -9.9419 0.80542E+00 -0.0940 78 MnCl+ 0.41149E-12 -12.3856 0.33234E-12 -12.4784 0.80765E+00 -0.0928 79 MnSO4,aq 0.18116E-17 -17.7419 0.18116E-17 -17.7419 0.10000E+01 0.0000 80 NaCl,aq 0.19103E-04 -4.7189 0.19103E-04 -4.7189 0.10000E+01 0.0000 81 NaF,aq 0.36072E-08 -8.4428 0.36072E-08 -8.4428 0.10000E+01 0.0000 82 NaOH,aq 0.92970E-04 -4.0317 0.92970E-04 -4.0317 0.10000E+01 0.0000 84 OH- 0.62248E-02 -2.2059 0.50005E-02 -2.3010 0.80332E+00 -0.0951 89 HPO3-2 0.67895E-15 -15.1682 0.30552E-15 -15.5150 0.45000E+00 -0.3468 91 H2PO3- 0.87846E-19 -19.0563 0.70753E-19 -19.1503 0.80542E+00 -0.0940 92 H3PO4,aq 0.10428E-17 -17.9818 0.10428E-17 -17.9818 0.10000E+01 0.0000 93 H2PO4- 0.29532E-10 -10.5297 0.23818E-10 -10.6231 0.80653E+00 -0.0934 94 PO4-3 0.43872E-09 -9.3578 0.78990E-10 -10.1024 0.18005E+00 -0.7446 98 HP2O7-3 0.45833E-18 -18.3388 0.76953E-19 -19.1138 0.16790E+00 -0.7750 99 P2O7-4 0.36014E-17 -17.4435 0.15919E-18 -18.7981 0.44202E-01 -1.3546 100 H2S,aq 0.30986E-05 -5.5088 0.30986E-05 -5.5088 0.10000E+01 0.0000 101 S2-2 0.42346E-09 -9.3732 0.19056E-09 -9.7200 0.45000E+00 -0.3468 102 S3-2 0.20170E-15 -15.6953 0.90766E-16 -16.0421 0.45000E+00 -0.3468 107 SO3-2 0.66478E-15 -15.1773 0.30546E-15 -15.5150 0.45950E+00 -0.3377 108 HSO3- 0.27423E-17 -17.5619 0.22087E-17 -17.6559 0.80542E+00 -0.0940 109 HSO4- 0.36885E-16 -16.4331 0.29834E-16 -16.5253 0.80882E+00 -0.0921 111 S2O3-2 0.21694E-16 -16.6637 0.97624E-17 -17.0104 0.45000E+00 -0.3468 Charge balance for all species = -.1738E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1421291E-09 -.1737601E-01 -.1746548E+02 0.0000 2 H2O 0.1000000E+01 0.5553433E+02 0.9976978E+06 0.0000 3 Cl- 0.2862510E-02 0.2881621E-02 0.1018793E+03 7.3002 4 SO4-- 0.5938647E-09 -.2923365E-01 -.2800457E+04 10.3032 5 HCO3- 0.1151809E-02 0.3194746E-01 0.1943948E+04 6.9058 6 HS- 0.1077680E-01 0.4001355E-01 0.1319664E+04 7.8761 7 Al+++ 0.4848071E-28 0.3407178E-05 0.9167626E-01 0.7223 8 H4SiO4 0.7120157E-03 0.1019291E-01 0.9769833E+03 -3.1475 9 Ca++ 0.3470916E-06 0.1862370E-05 0.7443344E-01 13.0653 10 Mg++ 0.5967409E-10 0.2362807E-09 0.5728551E-05 9.2977 11 Fe++ 0.1601572E-12 0.2384423E-07 0.1327942E-02 6.7271 12 K+ 0.2444891E-03 0.2452270E-03 0.9562318E+01 6.2328 13 Na+ 0.3105164E-01 0.3349293E-01 0.7678640E+03 8.3355 14 Mn++ 0.5262859E-10 0.2780350E-08 0.1523240E-03 9.2443 15 F- 0.7674064E-06 0.7710157E-06 0.1460720E-01 3.7272 16 HPO4-- 0.2476359E-07 0.2523184E-07 0.2415023E-02 11.9234 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276886E+02 -.8657881E-02 -.8276020E+02 0.0000000E+00 2 H2O -.6988683E+01 0.2767089E+02 -.3465958E+02 0.0000000E+00 3 Cl- 0.1435815E-02 0.1435815E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1396430E+00 -.1456615E-01 0.1542091E+00 0.0000000E+00 5 HCO3- 0.1591835E-01 0.1591835E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1342717E+00 0.1993741E-01 -.1542091E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1697682E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.5078785E-02 0.5205883E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.9279567E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1177307E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1188078E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1221884E-03 0.1061449E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1668840E-01 0.6259689E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1385355E-08 0.8669296E-01 0.0000000E+00 15 F- 0.8809600E-04 0.3841712E-06 0.8771183E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1257218E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: 0.1030E-13 Mass of aqueous solution: 0.499650E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2199900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.246 0.796 1638. 3.214 29.97 628.7 andradite 0.6168 -0.210 313.5 2.496 5.736 81.44 grossular 0.1273 -0.895 57.34 1.758 1.049 15.96 apatite-OH 0.9775E-02 -2.010 4.910 0.691 0.8986E-01 1.560 apatite-F 0.8771E-04 -4.057 0.4423E-01 -1.354 0.8095E-03 0.1382E-01 clinochlore 0.7115 -0.148 395.5 2.597 7.237 150.4 daphnite 0.2007 -0.698 143.2 2.156 2.620 43.39 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 microcline 0.9428 -0.026 262.4 2.419 4.802 102.5 stilbite 3.242 0.511 2285. 3.359 41.82 1066. stilpnomelane-Fe 0.2373 -0.625 255.8 2.408 4.681 88.35 tr.625ac.25prg.125 0.1133 -0.946 96.86 1.986 1.773 31.17 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8289E+00 0.8289E+00 1.0000 -0.081 grossular 0.1711E+00 0.1711E+00 1.0000 -0.767 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7655E+00 0.7655E+00 1.0000 -0.116 daphnite 0.2159E+00 0.2159E+00 1.0000 -0.666 chlorite-Mn 0.1865E-01 0.1865E-01 1.0000 -1.729 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5464.418711 g Volume = 2213.154939 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2199900 moles log = -0.6576 Original solution: 1000.0103000 g Original solution / Rock added: 4545.71 (Water/Rock Ratio), log = 3.6576 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 45.2795 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2408E-01 0.9223 0.1005E+01 0.1090E+01 CO2,gas 0.5854E-06 0.9264 0.2456E-04 0.2651E-04 CH4,gas 0.9757E+00 0.9739 0.4303E+02 0.4418E+02 H2,gas 0.2481E-03 1.0244 0.1151E-01 0.1123E-01 H2S,gas 0.2230E-05 0.8435 0.8518E-04 0.1010E-03 S2,gas 0.4543E-25 1.0000 0.2057E-23 0.2057E-23 CO,gas 0.1664E-11 1.0000 0.7534E-10 0.7534E-10 SO3,gas 0.2987E-46 1.0000 0.1352E-44 0.1352E-44 SO2,gas 0.1338E-25 1.0000 0.6057E-24 0.6057E-24 HF,gas 0.2642E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1901E-17 1.0000 0.8609E-16 0.8609E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28969E+04 0.002 2 CO2,gas -6.66 -12.97 -6.31 -2.103 0.10772E+05 -4.610 3 CH4,gas 4.54 4.48 -0.07 -0.016 0.11138E+03 1.634 4 H2,gas 8.00 4.36 -3.64 -2.079 0.62118E+04 -1.939 5 H2S,gas -6.23 -12.00 -5.77 -2.884 0.98498E+04 -4.070 6 S2,gas -7.34 -32.72 -25.39 -3.905 0.43345E+05 -23.687 7 CO,gas 3.21 -8.61 -11.82 -3.638 0.20186E+05 -10.123 8 SO3,gas 17.12 -29.45 -46.57 -11.642 0.79513E+05 -44.869 9 SO2,gas 0.83 -25.08 -25.92 -6.911 0.44252E+05 -24.218 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.57 -17.76 -8.882 0.30332E+05 -16.065 12 acmite 7.71 6.59 -1.12 -0.117 0.19167E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.74 -4.72 -0.236 0.80631E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95431E+03 26 ankerite -2.14 -6.15 -4.01 -0.668 0.68484E+04 27 annite 20.12 17.69 -2.43 -0.135 0.41481E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28326E+04 30 anorthite 12.71 8.21 -4.50 -0.346 0.76759E+04 38 aragonite 0.97 0.10 -0.87 -0.290 0.14862E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55857E+04 40 calcite 0.81 0.10 -0.72 -0.239 0.12220E+04 41 carnegieite-low 9.02 5.91 -3.11 -0.445 0.53155E+04 42 carnegieite-high 10.09 5.91 -4.18 -0.598 0.71425E+04 43 carpholite-Mg 8.58 4.45 -4.14 -0.276 0.70609E+04 44 carpholite-Fe 6.71 1.88 -4.84 -0.322 0.82580E+04 45 celadonite 5.34 3.66 -1.68 -0.099 0.28650E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47526E+04 47 chrysotile 23.89 21.60 -2.29 -0.191 0.39179E+04 52 chlorite-Al-free 47.17 43.20 -3.98 -0.166 0.67910E+04 54 chloritoid-Fe 9.17 5.02 -4.15 -0.277 0.70862E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.257 0.65914E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13164E+04 64 cristobalite -2.56 -3.15 -0.59 -0.196 0.10018E+04 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.15 -0.359 0.36742E+04 69 diamond -3.10 -4.25 -1.14 -0.326 0.19510E+04 70 diopside 16.18 16.07 -0.11 -0.011 0.19291E+03 71 hedenbergite 14.21 13.50 -0.71 -0.071 0.12131E+04 72 dolomite,ordered 0.55 -3.58 -4.12 -0.687 0.70378E+04 74 enstatite 17.26 12.30 -4.96 -0.496 0.84761E+04 76 clinoenstatite 17.17 12.30 -4.87 -0.487 0.83076E+04 78 epidote 24.67 22.68 -1.99 -0.097 0.34001E+04 79 clinozoisite 22.81 18.85 -3.95 -0.180 0.67469E+04 80 epidote-Fe 29.84 26.50 -3.34 -0.173 0.56999E+04 81 fayalite 14.05 10.31 -3.74 -0.534 0.63842E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68124E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57332E+04 87 glaucophane 22.97 20.83 -2.14 -0.058 0.36617E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70982E+04 89 graphite -3.55 -4.25 -0.70 -0.200 0.11932E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38475E+04 93 hematite 12.57 9.09 -3.47 -0.421 0.59323E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24794E+04 100 kalsilite 7.58 3.81 -3.78 -0.539 0.64479E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60067E+04 104 laumontite 2.88 1.92 -0.96 -0.064 0.16454E+04 105 lawsonite 9.62 8.21 -1.40 -0.093 0.23934E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59050E+04 108 lizardite 23.24 21.60 -1.65 -0.137 0.28105E+04 109 magnesite 0.69 -3.67 -4.36 -1.454 0.74481E+04 110 magnetite 20.09 15.82 -4.27 -0.348 0.72885E+04 111 minnesotaite 10.39 7.59 -2.80 -0.164 0.47738E+04 115 manganosite 14.06 9.24 -4.81 -1.203 0.82198E+04 123 muscovite 2.58 -1.04 -3.63 -0.213 0.61900E+04 124 paragonite 4.24 1.06 -3.18 -0.187 0.54291E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41478E+04 131 periclase-Fe 11.63 6.73 -4.90 -1.225 0.83661E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36514E+04 139 prehnite 19.37 18.13 -1.24 -0.073 0.21161E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92429E+03 141 pumpellyite-Fe 46.27 43.71 -2.56 -0.057 0.43639E+04 142 pumpellyite-Mg 48.99 46.28 -2.71 -0.060 0.46284E+04 145 pyrite -21.25 -21.63 -0.39 -0.091 0.65809E+03 146 pyrrhotite -4.26 -5.27 -1.01 -0.337 0.17270E+04 147 pyrrhotiteFe0.875 -6.02 -6.65 -0.64 -0.234 0.10869E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22225E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.311 0.84840E+04 150 quartz -2.99 -3.15 -0.16 -0.053 0.26913E+03 154 rhodochrosite -0.98 -3.72 -2.75 -0.916 0.46930E+04 155 rhodonite 7.45 6.10 -1.35 -0.270 0.23027E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.24 -3.63 -1.211 0.62047E+04 168 stilpnomelane-Mg 27.44 25.87 -1.57 -0.047 0.26836E+04 174 talc 16.49 15.30 -1.19 -0.070 0.20270E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46864E+04 181 tridymite -2.63 -3.15 -0.52 -0.174 0.88911E+03 182 tremolite 47.87 47.44 -0.43 -0.012 0.73176E+03 183 ferroactinolite 38.45 34.59 -3.86 -0.104 0.65984E+04 184 troilite-low -4.41 -5.27 -0.86 -0.287 0.14698E+04 190 wairakite 3.95 1.92 -2.03 -0.119 0.34665E+04 191 walstromite 11.51 9.92 -1.59 -0.318 0.27170E+04 192 wollastonite 10.46 9.92 -0.54 -0.109 0.92746E+03 193 pseudo-wollastonite 11.00 9.92 -1.08 -0.216 0.18473E+04 194 zoisite 22.85 18.85 -3.99 -0.182 0.68210E+04 195 akaganeite 7.75 4.55 -3.21 -0.694 0.54789E+04 202 chalcedony -2.80 -3.15 -0.34 -0.115 0.58843E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66048E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68659E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73433E+04 207 montmorillonite-Na -2.04 -5.56 -3.53 -0.216 0.60208E+04 208 nontronite-Ca 3.21 -0.06 -3.28 -0.213 0.55981E+04 209 nontronite-H 2.53 -2.22 -4.75 -0.319 0.81148E+04 210 nontronite-K 3.34 -0.16 -3.50 -0.225 0.59825E+04 211 nontronite-Mg 3.07 -0.69 -3.76 -0.244 0.64207E+04 212 nontronite-Na 3.52 0.53 -2.99 -0.192 0.51034E+04 228 tobermorite 9.82 7.74 -2.09 -0.570 0.35639E+04 234 alabandite -0.98 -2.75 -1.78 -0.592 0.30336E+04 237 boehmite 4.41 0.72 -3.68 -0.614 0.62912E+04 238 dolomite,disordered 1.25 -3.58 -4.82 -0.804 0.82347E+04 239 ferrous-oxide 9.81 6.73 -3.08 -0.771 0.52670E+04 245 silica-amorphous -2.09 -3.15 -1.06 -0.352 0.18026E+04 247 an20ab80 2.02 1.34 -0.68 -0.052 0.11643E+04 248 an25ab75 2.65 1.77 -0.88 -0.068 0.15024E+04 249 an30ab70 3.28 2.20 -1.08 -0.083 0.18501E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0100000 MOLES Current total amount of reactant added: 0.2199900 MOLES New total amount of reactant added: 0.2299900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2299900 Water: Moles liquid = 0.2766E+02 kg liquid = 0.4982E+00 Moles total = -.6980E+01 kg total = -.1258E+00 Activity = 0.9995 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3389483E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1495E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14644E-09 -9.8343 0.11872E-09 -9.9255 0.81071E+00 -0.0911 2 H2O 0.99945E+00 -0.0002 0.99945E+00 -0.0002 3 Cl- 0.29800E-02 -2.5258 0.23943E-02 -2.6208 0.80346E+00 -0.0950 4 SO4-- 0.68896E-09 -9.1618 0.30807E-09 -9.5114 0.44715E+00 -0.3495 5 HCO3- 0.13200E-02 -2.8794 0.10629E-02 -2.9735 0.80522E+00 -0.0941 6 HS- 0.11265E-01 -1.9483 0.90533E-02 -2.0432 0.80364E+00 -0.0949 7 Al+++ 0.53592E-28 -28.2709 0.87893E-29 -29.0560 0.16400E+00 -0.7851 8 H4SiO4 0.71391E-03 -3.1464 0.71391E-03 -3.1464 0.10000E+01 0.0000 9 Ca++ 0.36688E-06 -6.4355 0.16224E-06 -6.7898 0.44221E+00 -0.3544 10 Mg++ 0.63754E-10 -10.1955 0.28000E-10 -10.5528 0.43919E+00 -0.3573 11 Fe++ 0.17059E-12 -12.7681 0.75043E-13 -13.1247 0.43991E+00 -0.3566 12 K+ 0.25106E-03 -3.6002 0.20222E-03 -3.6942 0.80549E+00 -0.0939 13 Na+ 0.31888E-01 -1.4964 0.25613E-01 -1.5915 0.80322E+00 -0.0952 14 Mn++ 0.56131E-10 -10.2508 0.24723E-10 -10.6069 0.44046E+00 -0.3561 15 F- 0.74830E-06 -6.1259 0.59941E-06 -6.2223 0.80103E+00 -0.0964 16 HPO4-- 0.24035E-07 -7.6192 0.10749E-07 -7.9686 0.44724E+00 -0.3495 18 HSiO3- 0.69920E-02 -2.1554 0.56178E-02 -2.2504 0.80346E+00 -0.0950 19 Ca(HSiO3)+ 0.25760E-07 -7.5890 0.20756E-07 -7.6828 0.80575E+00 -0.0938 20 Mg(HSiO3)+ 0.55331E-11 -11.2570 0.44582E-11 -11.3508 0.80575E+00 -0.0938 21 NaHSiO3,aq 0.23272E-02 -2.6332 0.23272E-02 -2.6332 0.10000E+01 0.0000 22 AlO+ 0.10522E-15 -15.9779 0.84784E-16 -16.0717 0.80575E+00 -0.0938 24 HAlO2,aq 0.14214E-09 -9.8473 0.14214E-09 -9.8473 0.10000E+01 0.0000 25 AlO2- 0.33072E-05 -5.4805 0.26502E-05 -5.5767 0.80132E+00 -0.0962 26 CH4,aq 0.30326E-01 -1.5182 0.30326E-01 -1.5182 0.10000E+01 0.0000 27 C2H6,aq 0.18508E-07 -7.7326 0.18508E-07 -7.7326 0.10000E+01 0.0000 28 C3H8,aq 0.26077E-12 -12.5837 0.26077E-12 -12.5837 0.10000E+01 0.0000 29 C4H10,aq 0.36095E-17 -17.4425 0.36095E-17 -17.4425 0.10000E+01 0.0000 30 ethanol,aq 0.92571E-15 -15.0335 0.92571E-15 -15.0335 0.10000E+01 0.0000 31 CO,aq 0.57604E-13 -13.2396 0.57604E-13 -13.2396 0.10000E+01 0.0000 32 CO2,aq 0.26979E-06 -6.5690 0.26979E-06 -6.5690 0.10000E+01 0.0000 33 CO3-2 0.17544E-02 -2.7559 0.78198E-03 -3.1068 0.44574E+00 -0.3509 34 CaCO3,aq 0.15908E-05 -5.7984 0.15908E-05 -5.7984 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.54630E-08 -8.2626 0.44018E-08 -8.3564 0.80575E+00 -0.0938 36 CaCl+ 0.78019E-09 -9.1078 0.62863E-09 -9.2016 0.80575E+00 -0.0938 37 CaCl2,aq 0.35759E-12 -12.4466 0.35759E-12 -12.4466 0.10000E+01 0.0000 38 CaF+ 0.17621E-11 -11.7540 0.14198E-11 -11.8478 0.80575E+00 -0.0938 39 CaOH+ 0.12080E-06 -6.9179 0.97337E-07 -7.0117 0.80575E+00 -0.0938 40 CaSO4,aq 0.15871E-13 -13.7994 0.15871E-13 -13.7994 0.10000E+01 0.0000 41 HCl,aq 0.52090E-13 -13.2832 0.52090E-13 -13.2832 0.10000E+01 0.0000 45 HF,aq 0.48717E-12 -12.3123 0.48717E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.12271E-18 -18.9111 0.98593E-19 -19.0062 0.80346E+00 -0.0950 48 FeCl+ 0.35296E-15 -15.4523 0.28440E-15 -15.5461 0.80575E+00 -0.0938 51 FeF+ 0.28528E-17 -17.5447 0.22986E-17 -17.6385 0.80575E+00 -0.0938 53 FeO,aq 0.20680E-09 -9.6844 0.20680E-09 -9.6844 0.10000E+01 0.0000 54 FeOH+ 0.25521E-10 -10.5931 0.20564E-10 -10.6869 0.80575E+00 -0.0938 55 HFeO2- 0.22671E-07 -7.6445 0.18216E-07 -7.7396 0.80346E+00 -0.0950 56 FeO+ 0.20886E-16 -16.6802 0.16829E-16 -16.7740 0.80575E+00 -0.0938 58 FeO2- 0.30389E-09 -9.5173 0.24416E-09 -9.6123 0.80346E+00 -0.0950 59 HFeO2,aq 0.36868E-11 -11.4333 0.36868E-11 -11.4333 0.10000E+01 0.0000 60 H2,aq 0.84948E-05 -5.0708 0.84948E-05 -5.0708 0.10000E+01 0.0000 61 KCl,aq 0.87756E-08 -8.0567 0.87756E-08 -8.0567 0.10000E+01 0.0000 63 KOH,aq 0.72701E-06 -6.1385 0.72701E-06 -6.1385 0.10000E+01 0.0000 64 KSO4- 0.12032E-11 -11.9197 0.96672E-12 -12.0147 0.80346E+00 -0.0950 65 MgCO3,aq 0.68817E-10 -10.1623 0.68817E-10 -10.1623 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.96341E-12 -12.0162 0.77626E-12 -12.1100 0.80575E+00 -0.0938 67 MgCl+ 0.12204E-12 -12.9135 0.98333E-13 -13.0073 0.80575E+00 -0.0938 68 MgF+ 0.11266E-14 -14.9482 0.90772E-15 -15.0420 0.80575E+00 -0.0938 69 MgOH+ 0.11537E-09 -9.9379 0.92959E-10 -10.0317 0.80575E+00 -0.0938 71 MnF+ 0.30979E-15 -15.5089 0.24961E-15 -15.6027 0.80575E+00 -0.0938 72 MnO,aq 0.18154E-08 -8.7410 0.18154E-08 -8.7410 0.10000E+01 0.0000 73 MnOH+ 0.78108E-09 -9.1073 0.62935E-09 -9.2011 0.80575E+00 -0.0938 74 MnO2-2 0.95843E-11 -11.0184 0.42720E-11 -11.3694 0.44574E+00 -0.3509 75 HMnO2- 0.13830E-09 -9.8592 0.11112E-09 -9.9542 0.80346E+00 -0.0950 78 MnCl+ 0.45240E-12 -12.3445 0.36452E-12 -12.4383 0.80575E+00 -0.0938 79 MnSO4,aq 0.21988E-17 -17.6578 0.21988E-17 -17.6578 0.10000E+01 0.0000 80 NaCl,aq 0.20324E-04 -4.6920 0.20324E-04 -4.6920 0.10000E+01 0.0000 81 NaF,aq 0.35944E-08 -8.4444 0.35944E-08 -8.4444 0.10000E+01 0.0000 82 NaOH,aq 0.92640E-04 -4.0332 0.92640E-04 -4.0332 0.10000E+01 0.0000 84 OH- 0.60698E-02 -2.2168 0.48639E-02 -2.3130 0.80132E+00 -0.0962 89 HPO3-2 0.63877E-15 -15.1947 0.28472E-15 -15.5456 0.44574E+00 -0.3509 91 H2PO3- 0.84367E-19 -19.0738 0.67786E-19 -19.1689 0.80346E+00 -0.0950 92 H3PO4,aq 0.10597E-17 -17.9748 0.10597E-17 -17.9748 0.10000E+01 0.0000 93 H2PO4- 0.29260E-10 -10.5337 0.23543E-10 -10.6281 0.80460E+00 -0.0944 94 PO4-3 0.41860E-09 -9.3782 0.73872E-10 -10.1315 0.17648E+00 -0.7533 98 HP2O7-3 0.44510E-18 -18.3515 0.73132E-19 -19.1359 0.16430E+00 -0.7844 99 P2O7-4 0.34565E-17 -17.4614 0.14716E-18 -18.8322 0.42574E-01 -1.3709 100 H2S,aq 0.33220E-05 -5.4786 0.33220E-05 -5.4786 0.10000E+01 0.0000 101 S2-2 0.47964E-09 -9.3191 0.21379E-09 -9.6700 0.44574E+00 -0.3509 102 S3-2 0.25270E-15 -15.5974 0.11264E-15 -15.9483 0.44574E+00 -0.3509 107 SO3-2 0.74723E-15 -15.1265 0.34026E-15 -15.4682 0.45536E+00 -0.3416 108 HSO3- 0.31480E-17 -17.5020 0.25293E-17 -17.5970 0.80346E+00 -0.0950 109 HSO4- 0.43681E-16 -16.3597 0.35248E-16 -16.4529 0.80694E+00 -0.0932 111 S2O3-2 0.26985E-16 -16.5689 0.12028E-16 -16.9198 0.44574E+00 -0.3509 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1464441E-09 -.1725027E-01 -.1733799E+02 0.0000 2 H2O 0.1000000E+01 0.5553543E+02 0.9976537E+06 0.0000 3 Cl- 0.2980008E-02 0.3000341E-02 0.1060698E+03 7.3046 4 SO4-- 0.6889558E-09 -.3032781E-01 -.2905086E+04 10.3396 5 HCO3- 0.1320012E-02 0.3340193E-01 0.2032320E+04 6.9520 6 HS- 0.1126543E-01 0.4159656E-01 0.1371785E+04 7.8823 7 Al+++ 0.5359211E-28 0.3307360E-05 0.8898478E-01 0.7203 8 H4SiO4 0.7139068E-03 0.1003312E-01 0.9616055E+03 -3.1464 9 Ca++ 0.3668775E-06 0.2110451E-05 0.8434309E-01 13.0611 10 Mg++ 0.6375373E-10 0.2545601E-09 0.6171335E-05 9.2981 11 Fe++ 0.1705863E-12 0.2321145E-07 0.1292618E-02 6.7262 12 K+ 0.2510592E-03 0.2517950E-03 0.9817800E+01 6.2313 13 Na+ 0.3188812E-01 0.3432830E-01 0.7869653E+03 8.3339 14 Mn++ 0.5613070E-10 0.2800978E-08 0.1534443E-03 9.2440 15 F- 0.7483040E-06 0.7519006E-06 0.1424415E-01 3.7032 16 HPO4-- 0.2403484E-07 0.2448269E-07 0.2343169E-02 11.8823 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276778E+02 -.8594345E-02 -.8275919E+02 0.0000000E+00 2 H2O -.6980496E+01 0.2766859E+02 -.3464909E+02 0.0000000E+00 3 Cl- 0.1494815E-02 0.1494815E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1396907E+00 -.1510977E-01 0.1548005E+00 0.0000000E+00 5 HCO3- 0.1664135E-01 0.1664135E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1340765E+00 0.2072403E-01 -.1548005E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1647777E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4998650E-02 0.5205891E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1051459E-05 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1268257E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1156429E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1254481E-03 0.1061445E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1710288E-01 0.6259274E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1395490E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9209600E-04 0.3746082E-06 0.9172139E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1219765E-07 0.2958786E-01 0.0000000E+00 Chg. balance for solid moles: -.6245E-15 Mass of aqueous solution: 0.499630E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2299900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.97 628.7 andradite 0.6192 -0.208 314.7 2.498 5.758 81.75 grossular 0.1255 -0.901 56.54 1.752 1.035 15.73 apatite-OH 0.9771E-02 -2.010 4.908 0.691 0.8982E-01 1.560 apatite-F 0.9172E-04 -4.038 0.4626E-01 -1.335 0.8465E-03 0.1445E-01 clinochlore 0.7127 -0.147 396.1 2.598 7.249 150.7 daphnite 0.2004 -0.698 143.0 2.155 2.617 43.33 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9429 -0.026 262.5 2.419 4.803 102.5 stilbite 3.244 0.511 2286. 3.359 41.83 1066. stilpnomelane-Fe 0.2370 -0.625 255.5 2.407 4.675 88.25 tr.625ac.25prg.125 0.1117 -0.952 95.48 1.980 1.747 30.73 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8315E+00 0.8315E+00 1.0000 -0.080 grossular 0.1685E+00 0.1685E+00 1.0000 -0.773 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7660E+00 0.7660E+00 1.0000 -0.116 daphnite 0.2154E+00 0.2154E+00 1.0000 -0.667 chlorite-Mn 0.1864E-01 0.1864E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5464.644050 g Volume = 2213.375962 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2299900 moles log = -0.6383 Original solution: 1000.0103000 g Original solution / Rock added: 4348.06 (Water/Rock Ratio), log = 3.6383 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 46.9779 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2326E-01 0.9203 0.1005E+01 0.1093E+01 CO2,gas 0.6650E-06 0.9240 0.2886E-04 0.3124E-04 CH4,gas 0.9765E+00 0.9730 0.4464E+02 0.4587E+02 H2,gas 0.2315E-03 1.0254 0.1115E-01 0.1088E-01 H2S,gas 0.2319E-05 0.8384 0.9132E-04 0.1089E-03 S2,gas 0.5357E-25 1.0000 0.2517E-23 0.2517E-23 CO,gas 0.1827E-11 1.0000 0.8584E-10 0.8584E-10 SO3,gas 0.3497E-46 1.0000 0.1643E-44 0.1643E-44 SO2,gas 0.1518E-25 1.0000 0.7132E-24 0.7132E-24 HF,gas 0.2546E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.1957E-17 1.0000 0.9191E-16 0.9191E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 0.54595E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.39430E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28969E+04 0.002 2 CO2,gas -6.66 -12.90 -6.24 -2.080 0.10652E+05 -4.540 3 CH4,gas 4.54 4.49 -0.05 -0.012 0.84130E+02 1.650 4 H2,gas 8.00 4.35 -3.65 -2.087 0.62350E+04 -1.953 5 H2S,gas -6.23 -11.97 -5.74 -2.869 0.97982E+04 -4.039 6 S2,gas -7.34 -32.63 -25.30 -3.892 0.43196E+05 -23.599 7 CO,gas 3.21 -8.55 -11.77 -3.620 0.20089E+05 -10.066 8 SO3,gas 17.12 -29.36 -46.48 -11.621 0.79369E+05 -44.784 9 SO2,gas 0.83 -25.01 -25.85 -6.892 0.44131E+05 -24.147 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.55 -17.74 -8.868 0.30283E+05 -16.037 12 acmite 7.71 6.59 -1.12 -0.116 0.19053E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.72 -0.236 0.80655E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95632E+03 26 ankerite -2.14 -6.01 -3.88 -0.646 0.66174E+04 27 annite 20.12 17.69 -2.43 -0.135 0.41528E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28306E+04 30 anorthite 12.71 8.21 -4.50 -0.346 0.76858E+04 38 aragonite 0.97 0.16 -0.80 -0.268 0.13735E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55851E+04 40 calcite 0.81 0.16 -0.65 -0.217 0.11093E+04 41 carnegieite-low 9.02 5.91 -3.12 -0.445 0.53195E+04 42 carnegieite-high 10.09 5.91 -4.19 -0.598 0.71464E+04 43 carpholite-Mg 8.58 4.45 -4.14 -0.276 0.70630E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82623E+04 45 celadonite 5.34 3.67 -1.68 -0.099 0.28624E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47521E+04 47 chrysotile 23.89 21.60 -2.29 -0.191 0.39120E+04 52 chlorite-Al-free 47.17 43.20 -3.97 -0.165 0.67791E+04 54 chloritoid-Fe 9.17 5.02 -4.15 -0.277 0.70925E+04 55 chloritoid-Mn 11.40 7.54 -3.86 -0.258 0.65967E+04 57 coesite -2.38 -3.15 -0.77 -0.257 0.13144E+04 64 cristobalite -2.56 -3.15 -0.59 -0.195 0.99980E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.15 -0.359 0.36776E+04 69 diamond -3.10 -4.20 -1.10 -0.314 0.18774E+04 70 diopside 16.18 16.07 -0.11 -0.011 0.19541E+03 71 hedenbergite 14.21 13.50 -0.71 -0.071 0.12178E+04 72 dolomite,ordered 0.55 -3.44 -3.99 -0.664 0.68045E+04 74 enstatite 17.26 12.30 -4.96 -0.496 0.84707E+04 76 clinoenstatite 17.17 12.30 -4.86 -0.486 0.83023E+04 78 epidote 24.67 22.68 -1.99 -0.097 0.34051E+04 79 clinozoisite 22.81 18.84 -3.96 -0.180 0.67653E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56916E+04 81 fayalite 14.05 10.31 -3.74 -0.534 0.63853E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68115E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57366E+04 87 glaucophane 22.97 20.83 -2.14 -0.058 0.36557E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70989E+04 89 graphite -3.55 -4.20 -0.66 -0.187 0.11197E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38482E+04 93 hematite 12.57 9.10 -3.46 -0.420 0.59123E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24814E+04 100 kalsilite 7.58 3.81 -3.78 -0.540 0.64519E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60095E+04 104 laumontite 2.88 1.92 -0.97 -0.064 0.16513E+04 105 lawsonite 9.62 8.21 -1.41 -0.094 0.24033E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59070E+04 108 lizardite 23.24 21.60 -1.64 -0.137 0.28046E+04 109 magnesite 0.69 -3.60 -4.29 -1.430 0.73276E+04 110 magnetite 20.09 15.83 -4.26 -0.348 0.72701E+04 111 minnesotaite 10.39 7.59 -2.79 -0.164 0.47705E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82203E+04 123 muscovite 2.58 -1.05 -3.63 -0.213 0.61968E+04 124 paragonite 4.24 1.06 -3.18 -0.187 0.54359E+04 125 nepheline 8.34 5.91 -2.43 -0.347 0.41518E+04 131 periclase-Fe 11.63 6.73 -4.90 -1.225 0.83676E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36494E+04 139 prehnite 19.37 18.12 -1.25 -0.073 0.21312E+04 140 prehnite-Fe 22.50 21.96 -0.54 -0.033 0.92598E+03 141 pumpellyite-Fe 46.27 43.69 -2.58 -0.057 0.43990E+04 142 pumpellyite-Mg 48.99 46.26 -2.73 -0.061 0.46613E+04 145 pyrite -21.25 -21.56 -0.31 -0.073 0.53326E+03 146 pyrrhotite -4.26 -5.24 -0.98 -0.327 0.16769E+04 147 pyrrhotiteFe0.875 -6.02 -6.62 -0.61 -0.223 0.10337E+04 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22210E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.311 0.84827E+04 150 quartz -2.99 -3.15 -0.16 -0.052 0.26713E+03 154 rhodochrosite -0.98 -3.65 -2.68 -0.893 0.45737E+04 155 rhodonite 7.45 6.10 -1.35 -0.270 0.23013E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.17 -3.56 -1.188 0.60864E+04 168 stilpnomelane-Mg 27.44 25.88 -1.57 -0.047 0.26725E+04 174 talc 16.49 15.31 -1.18 -0.069 0.20170E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46855E+04 181 tridymite -2.63 -3.15 -0.52 -0.173 0.88711E+03 182 tremolite 47.87 47.44 -0.43 -0.012 0.72680E+03 183 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66046E+04 184 troilite-low -4.41 -5.24 -0.83 -0.277 0.14197E+04 190 wairakite 3.95 1.92 -2.03 -0.120 0.34724E+04 191 walstromite 11.51 9.91 -1.59 -0.319 0.27222E+04 192 wollastonite 10.46 9.91 -0.55 -0.109 0.93262E+03 193 pseudo-wollastonite 11.00 9.91 -1.08 -0.217 0.18524E+04 194 zoisite 22.85 18.84 -4.01 -0.182 0.68394E+04 195 akaganeite 7.75 4.55 -3.20 -0.693 0.54689E+04 202 chalcedony -2.80 -3.15 -0.34 -0.114 0.58643E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66034E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68642E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73406E+04 207 montmorillonite-Na -2.04 -5.56 -3.53 -0.216 0.60191E+04 208 nontronite-Ca 3.21 -0.05 -3.26 -0.212 0.55731E+04 209 nontronite-H 2.53 -2.20 -4.74 -0.318 0.80886E+04 210 nontronite-K 3.34 -0.15 -3.49 -0.224 0.59571E+04 211 nontronite-Mg 3.07 -0.67 -3.74 -0.243 0.63944E+04 212 nontronite-Na 3.52 0.55 -2.97 -0.191 0.50780E+04 228 tobermorite 9.82 7.73 -2.09 -0.570 0.35679E+04 234 alabandite -0.98 -2.72 -1.75 -0.582 0.29825E+04 237 boehmite 4.41 0.72 -3.69 -0.614 0.62945E+04 238 dolomite,disordered 1.25 -3.44 -4.69 -0.781 0.80015E+04 239 ferrous-oxide 9.81 6.73 -3.09 -0.771 0.52686E+04 245 silica-amorphous -2.09 -3.15 -1.05 -0.352 0.18006E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11663E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15049E+04 249 an30ab70 3.28 2.19 -1.09 -0.083 0.18530E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0100000 MOLES Current total amount of reactant added: 0.2299900 MOLES New total amount of reactant added: 0.2399900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2399900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4982E+00 Moles total = -.6972E+01 kg total = -.1256E+00 Activity = 0.9994 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3498864E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.1554E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15099E-09 -9.8211 0.12213E-09 -9.9132 0.80885E+00 -0.0921 2 H2O 0.99943E+00 -0.0002 0.99943E+00 -0.0002 3 Cl- 0.30975E-02 -2.5090 0.24825E-02 -2.6051 0.80145E+00 -0.0961 4 SO4-- 0.79591E-09 -9.0991 0.35243E-09 -9.4529 0.44281E+00 -0.3538 5 HCO3- 0.15056E-02 -2.8223 0.12093E-02 -2.9175 0.80325E+00 -0.0952 6 HS- 0.11754E-01 -1.9298 0.94224E-02 -2.0258 0.80163E+00 -0.0960 7 Al+++ 0.59389E-28 -28.2263 0.95240E-29 -29.0212 0.16037E+00 -0.7949 8 H4SiO4 0.71578E-03 -3.1452 0.71578E-03 -3.1452 0.10000E+01 0.0000 9 Ca++ 0.38840E-06 -6.4107 0.17004E-06 -6.7694 0.43780E+00 -0.3587 10 Mg++ 0.68211E-10 -10.1661 0.29654E-10 -10.5279 0.43474E+00 -0.3618 11 Fe++ 0.18196E-12 -12.7400 0.79240E-13 -13.1011 0.43547E+00 -0.3610 12 K+ 0.25798E-03 -3.5884 0.20729E-03 -3.6834 0.80352E+00 -0.0950 13 Na+ 0.32770E-01 -1.4845 0.26255E-01 -1.5808 0.80120E+00 -0.0963 14 Mn++ 0.59954E-10 -10.2222 0.26141E-10 -10.5827 0.43602E+00 -0.3605 15 F- 0.72933E-06 -6.1371 0.58271E-06 -6.2345 0.79897E+00 -0.0975 16 HPO4-- 0.23304E-07 -7.6326 0.10321E-07 -7.9863 0.44290E+00 -0.3537 18 HSiO3- 0.68323E-02 -2.1654 0.54758E-02 -2.2616 0.80145E+00 -0.0961 19 Ca(HSiO3)+ 0.26381E-07 -7.5787 0.21205E-07 -7.6736 0.80378E+00 -0.0949 20 Mg(HSiO3)+ 0.57257E-11 -11.2422 0.46022E-11 -11.3370 0.80378E+00 -0.0949 21 NaHSiO3,aq 0.23252E-02 -2.6335 0.23252E-02 -2.6335 0.10000E+01 0.0000 22 AlO+ 0.10802E-15 -15.9665 0.86824E-16 -16.0614 0.80378E+00 -0.0949 24 HAlO2,aq 0.14150E-09 -9.8492 0.14150E-09 -9.8492 0.10000E+01 0.0000 25 AlO2- 0.32090E-05 -5.4936 0.25648E-05 -5.5909 0.79927E+00 -0.0973 26 CH4,aq 0.31389E-01 -1.5032 0.31389E-01 -1.5032 0.10000E+01 0.0000 27 C2H6,aq 0.20447E-07 -7.6894 0.20447E-07 -7.6894 0.10000E+01 0.0000 28 C3H8,aq 0.30751E-12 -12.5121 0.30751E-12 -12.5121 0.10000E+01 0.0000 29 C4H10,aq 0.45432E-17 -17.3426 0.45432E-17 -17.3426 0.10000E+01 0.0000 30 ethanol,aq 0.10546E-14 -14.9769 0.10546E-14 -14.9769 0.10000E+01 0.0000 31 CO,aq 0.65380E-13 -13.1846 0.65380E-13 -13.1846 0.10000E+01 0.0000 32 CO2,aq 0.31576E-06 -6.5006 0.31576E-06 -6.5006 0.10000E+01 0.0000 33 CO3-2 0.19597E-02 -2.7078 0.86494E-03 -3.0630 0.44137E+00 -0.3552 34 CaCO3,aq 0.18442E-05 -5.7342 0.18442E-05 -5.7342 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.65305E-08 -8.1851 0.52491E-08 -8.2799 0.80378E+00 -0.0949 36 CaCl+ 0.84989E-09 -9.0706 0.68312E-09 -9.1655 0.80378E+00 -0.0949 37 CaCl2,aq 0.40289E-12 -12.3948 0.40289E-12 -12.3948 0.10000E+01 0.0000 38 CaF+ 0.17998E-11 -11.7448 0.14466E-11 -11.8396 0.80378E+00 -0.0949 39 CaOH+ 0.12339E-06 -6.9087 0.99176E-07 -7.0036 0.80378E+00 -0.0949 40 CaSO4,aq 0.19030E-13 -13.7206 0.19030E-13 -13.7206 0.10000E+01 0.0000 41 HCl,aq 0.55555E-13 -13.2553 0.55555E-13 -13.2553 0.10000E+01 0.0000 45 HF,aq 0.48716E-12 -12.3123 0.48716E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.11959E-18 -18.9223 0.95843E-19 -19.0184 0.80145E+00 -0.0961 48 FeCl+ 0.38737E-15 -15.4119 0.31136E-15 -15.5067 0.80378E+00 -0.0949 51 FeF+ 0.29356E-17 -17.5323 0.23595E-17 -17.6272 0.80378E+00 -0.0949 53 FeO,aq 0.20637E-09 -9.6853 0.20637E-09 -9.6853 0.10000E+01 0.0000 54 FeOH+ 0.26261E-10 -10.5807 0.21108E-10 -10.6755 0.80378E+00 -0.0949 55 HFeO2- 0.22049E-07 -7.6566 0.17671E-07 -7.7527 0.80145E+00 -0.0961 56 FeO+ 0.21824E-16 -16.6611 0.17542E-16 -16.7559 0.80378E+00 -0.0949 58 FeO2- 0.30012E-09 -9.5227 0.24053E-09 -9.6188 0.80145E+00 -0.0961 59 HFeO2,aq 0.37360E-11 -11.4276 0.37360E-11 -11.4276 0.10000E+01 0.0000 60 H2,aq 0.82377E-05 -5.0842 0.82377E-05 -5.0842 0.10000E+01 0.0000 61 KCl,aq 0.93267E-08 -8.0303 0.93267E-08 -8.0303 0.10000E+01 0.0000 63 KOH,aq 0.72447E-06 -6.1400 0.72447E-06 -6.1400 0.10000E+01 0.0000 64 KSO4- 0.14145E-11 -11.8494 0.11337E-11 -11.9455 0.80145E+00 -0.0961 65 MgCO3,aq 0.80614E-10 -10.0936 0.80614E-10 -10.0936 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11637E-11 -11.9342 0.93538E-12 -12.0290 0.80378E+00 -0.0949 67 MgCl+ 0.13433E-12 -12.8718 0.10797E-12 -12.9667 0.80378E+00 -0.0949 68 MgF+ 0.11627E-14 -14.9345 0.93454E-15 -15.0294 0.80378E+00 -0.0949 69 MgOH+ 0.11907E-09 -9.9242 0.95705E-10 -10.0191 0.80378E+00 -0.0949 71 MnF+ 0.31921E-15 -15.4959 0.25658E-15 -15.5908 0.80378E+00 -0.0949 72 MnO,aq 0.18141E-08 -8.7413 0.18141E-08 -8.7413 0.10000E+01 0.0000 73 MnOH+ 0.80483E-09 -9.0943 0.64691E-09 -9.1892 0.80378E+00 -0.0949 74 MnO2-2 0.91406E-11 -11.0390 0.40344E-11 -11.3942 0.44137E+00 -0.3552 75 HMnO2- 0.13469E-09 -9.8707 0.10794E-09 -9.9668 0.80145E+00 -0.0961 78 MnCl+ 0.49717E-12 -12.3035 0.39962E-12 -12.3984 0.80378E+00 -0.0949 79 MnSO4,aq 0.26597E-17 -17.5752 0.26597E-17 -17.5752 0.10000E+01 0.0000 80 NaCl,aq 0.21600E-04 -4.6655 0.21600E-04 -4.6655 0.10000E+01 0.0000 81 NaF,aq 0.35818E-08 -8.4459 0.35818E-08 -8.4459 0.10000E+01 0.0000 82 NaOH,aq 0.92316E-04 -4.0347 0.92316E-04 -4.0347 0.10000E+01 0.0000 84 OH- 0.59158E-02 -2.2280 0.47283E-02 -2.3253 0.79927E+00 -0.0973 89 HPO3-2 0.60066E-15 -15.2214 0.26511E-15 -15.5766 0.44137E+00 -0.3552 91 H2PO3- 0.81010E-19 -19.0915 0.64926E-19 -19.1876 0.80145E+00 -0.0961 92 H3PO4,aq 0.10766E-17 -17.9679 0.10766E-17 -17.9679 0.10000E+01 0.0000 93 H2PO4- 0.28971E-10 -10.5380 0.23253E-10 -10.6335 0.80261E+00 -0.0955 94 PO4-3 0.39890E-09 -9.3991 0.68955E-10 -10.1614 0.17286E+00 -0.7623 98 HP2O7-3 0.43166E-18 -18.3649 0.69356E-19 -19.1589 0.16067E+00 -0.7941 99 P2O7-4 0.33127E-17 -17.4798 0.13567E-18 -18.8675 0.40955E-01 -1.3877 100 H2S,aq 0.35564E-05 -5.4490 0.35564E-05 -5.4490 0.10000E+01 0.0000 101 S2-2 0.54106E-09 -9.2668 0.23881E-09 -9.6220 0.44137E+00 -0.3552 102 S3-2 0.31470E-15 -15.5021 0.13890E-15 -15.8573 0.44137E+00 -0.3552 107 SO3-2 0.83676E-15 -15.0774 0.37749E-15 -15.4231 0.45113E+00 -0.3457 108 HSO3- 0.36016E-17 -17.4435 0.28865E-17 -17.5396 0.80145E+00 -0.0961 109 HSO4- 0.51527E-16 -16.2880 0.41479E-16 -16.3822 0.80500E+00 -0.0942 111 S2O3-2 0.33377E-16 -16.4766 0.14732E-16 -16.8317 0.44137E+00 -0.3552 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1509855E-09 -.1713916E-01 -.1722517E+02 0.0000 2 H2O 0.1000000E+01 0.5553651E+02 0.9976065E+06 0.0000 3 Cl- 0.3097456E-02 0.3119066E-02 0.1102597E+03 7.3081 4 SO4-- 0.7959087E-09 -.3139116E-01 -.3006743E+04 10.3735 5 HCO3- 0.1505566E-02 0.3485649E-01 0.2120680E+04 6.9957 6 HS- 0.1175407E-01 0.4314879E-01 0.1422880E+04 7.8874 7 Al+++ 0.5938857E-28 0.3209094E-05 0.8633517E-01 0.7184 8 H4SiO4 0.7157800E-03 0.9873373E-02 0.9462323E+03 -3.1452 9 Ca++ 0.3884004E-06 0.2389715E-05 0.9549737E-01 13.0569 10 Mg++ 0.6821055E-10 0.2749177E-09 0.6664425E-05 9.2985 11 Fe++ 0.1819635E-12 0.2258548E-07 0.1257675E-02 6.7253 12 K+ 0.2579823E-03 0.2587161E-03 0.1008699E+02 6.2298 13 Na+ 0.3276965E-01 0.3520880E-01 0.8070968E+03 8.3324 14 Mn++ 0.5995442E-10 0.2823232E-08 0.1546531E-03 9.2437 15 F- 0.7293265E-06 0.7329106E-06 0.1388347E-01 3.6786 16 HPO4-- 0.2330388E-07 0.2373176E-07 0.2271147E-02 11.8401 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276671E+02 -.8538159E-02 -.8275817E+02 0.0000000E+00 2 H2O -.6972309E+01 0.2766644E+02 -.3463875E+02 0.0000000E+00 3 Cl- 0.1553815E-02 0.1553815E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1397385E+00 -.1563803E-01 0.1553765E+00 0.0000000E+00 5 HCO3- 0.1736435E-01 0.1736435E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1338812E+00 0.2149529E-01 -.1553765E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1598664E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4918586E-02 0.5205899E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1190477E-05 0.5750725E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1369549E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1125134E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1288837E-03 0.1061442E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1753985E-01 0.6258837E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1406440E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9609600E-04 0.3651117E-06 0.9573089E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1182237E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: -.4434E-14 Mass of aqueous solution: 0.499615E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2399900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.97 628.6 andradite 0.6215 -0.207 315.8 2.499 5.779 82.06 grossular 0.1238 -0.907 55.75 1.746 1.020 15.51 apatite-OH 0.9767E-02 -2.010 4.906 0.691 0.8978E-01 1.559 apatite-F 0.9573E-04 -4.019 0.4828E-01 -1.316 0.8834E-03 0.1508E-01 clinochlore 0.7138 -0.146 396.8 2.599 7.260 150.9 daphnite 0.2001 -0.699 142.8 2.155 2.613 43.27 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9431 -0.025 262.5 2.419 4.803 102.5 stilbite 3.245 0.511 2287. 3.359 41.85 1067. stilpnomelane-Fe 0.2368 -0.626 255.2 2.407 4.670 88.16 tr.625ac.25prg.125 0.1101 -0.958 94.13 1.974 1.723 30.30 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8339E+00 0.8339E+00 1.0000 -0.079 grossular 0.1661E+00 0.1661E+00 1.0000 -0.780 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7665E+00 0.7665E+00 1.0000 -0.115 daphnite 0.2149E+00 0.2149E+00 1.0000 -0.668 chlorite-Mn 0.1862E-01 0.1862E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5464.865113 g Volume = 2213.593096 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2399900 moles log = -0.6198 Original solution: 1000.0103000 g Original solution / Rock added: 4166.88 (Water/Rock Ratio), log = 3.6198 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 48.6314 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2251E-01 0.9183 0.1005E+01 0.1095E+01 CO2,gas 0.7537E-06 0.9217 0.3378E-04 0.3665E-04 CH4,gas 0.9773E+00 0.9722 0.4620E+02 0.4753E+02 H2,gas 0.2167E-03 1.0263 0.1082E-01 0.1054E-01 H2S,gas 0.2412E-05 0.8334 0.9776E-04 0.1173E-03 S2,gas 0.6307E-25 1.0000 0.3067E-23 0.3067E-23 CO,gas 0.2003E-11 1.0000 0.9743E-10 0.9743E-10 SO3,gas 0.4089E-46 1.0000 0.1989E-44 0.1989E-44 SO2,gas 0.1722E-25 1.0000 0.8372E-24 0.8372E-24 HF,gas 0.2460E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.2016E-17 1.0000 0.9803E-16 0.9803E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28970E+04 0.002 2 CO2,gas -6.66 -12.83 -6.17 -2.057 0.10536E+05 -4.471 3 CH4,gas 4.54 4.51 -0.03 -0.009 0.58573E+02 1.665 4 H2,gas 8.00 4.33 -3.66 -2.094 0.62578E+04 -1.966 5 H2S,gas -6.23 -11.94 -5.71 -2.854 0.97476E+04 -4.010 6 S2,gas -7.34 -32.55 -25.21 -3.879 0.43049E+05 -23.513 7 CO,gas 3.21 -8.50 -11.71 -3.603 0.19995E+05 -10.011 8 SO3,gas 17.12 -29.28 -46.40 -11.600 0.79227E+05 -44.701 9 SO2,gas 0.83 -24.94 -25.78 -6.874 0.44012E+05 -24.077 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.52 -17.71 -8.854 0.30235E+05 -16.009 12 acmite 7.71 6.60 -1.11 -0.115 0.18942E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80679E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95831E+03 26 ankerite -2.14 -5.88 -3.74 -0.624 0.63927E+04 27 annite 20.12 17.69 -2.43 -0.135 0.41575E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28287E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.76956E+04 38 aragonite 0.97 0.23 -0.74 -0.247 0.12639E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55844E+04 40 calcite 0.81 0.23 -0.59 -0.195 0.99969E+03 41 carnegieite-low 9.02 5.91 -3.12 -0.445 0.53234E+04 42 carnegieite-high 10.09 5.91 -4.19 -0.598 0.71504E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70651E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82666E+04 45 celadonite 5.34 3.67 -1.67 -0.099 0.28597E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47517E+04 47 chrysotile 23.89 21.60 -2.29 -0.191 0.39061E+04 52 chlorite-Al-free 47.17 43.21 -3.96 -0.165 0.67674E+04 54 chloritoid-Fe 9.17 5.02 -4.16 -0.277 0.70987E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66019E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13125E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99783E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.16 -0.359 0.36809E+04 69 diamond -3.10 -4.16 -1.06 -0.302 0.18063E+04 70 diopside 16.18 16.07 -0.12 -0.012 0.19787E+03 71 hedenbergite 14.21 13.49 -0.72 -0.072 0.12225E+04 72 dolomite,ordered 0.55 -3.31 -3.85 -0.642 0.65776E+04 74 enstatite 17.26 12.31 -4.96 -0.496 0.84655E+04 76 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82971E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34102E+04 79 clinozoisite 22.81 18.83 -3.97 -0.181 0.67835E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56834E+04 81 fayalite 14.05 10.31 -3.74 -0.534 0.63864E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68107E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57399E+04 87 glaucophane 22.97 20.84 -2.14 -0.058 0.36498E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70997E+04 89 graphite -3.55 -4.16 -0.61 -0.175 0.10485E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38490E+04 93 hematite 12.57 9.12 -3.45 -0.418 0.58926E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24834E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64559E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60122E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16572E+04 105 lawsonite 9.62 8.20 -1.41 -0.094 0.24131E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59089E+04 108 lizardite 23.24 21.60 -1.64 -0.137 0.27987E+04 109 magnesite 0.69 -3.53 -4.22 -1.408 0.72103E+04 110 magnetite 20.09 15.84 -4.25 -0.347 0.72520E+04 111 minnesotaite 10.39 7.60 -2.79 -0.164 0.47673E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82209E+04 123 muscovite 2.58 -1.05 -3.63 -0.214 0.62034E+04 124 paragonite 4.24 1.05 -3.19 -0.187 0.54425E+04 125 nepheline 8.34 5.91 -2.43 -0.348 0.41558E+04 131 periclase-Fe 11.63 6.73 -4.90 -1.225 0.83692E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36475E+04 139 prehnite 19.37 18.12 -1.26 -0.074 0.21460E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92769E+03 141 pumpellyite-Fe 46.27 43.67 -2.60 -0.058 0.44336E+04 142 pumpellyite-Mg 48.99 46.25 -2.75 -0.061 0.46937E+04 145 pyrite -21.25 -21.49 -0.24 -0.057 0.41086E+03 146 pyrrhotite -4.26 -5.21 -0.95 -0.318 0.16279E+04 147 pyrrhotiteFe0.875 -6.02 -6.59 -0.57 -0.211 0.98169E+03 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22196E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84815E+04 150 quartz -2.99 -3.14 -0.16 -0.052 0.26516E+03 154 rhodochrosite -0.98 -3.59 -2.61 -0.870 0.44575E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22999E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.11 -3.50 -1.166 0.59713E+04 168 stilpnomelane-Mg 27.44 25.88 -1.56 -0.047 0.26615E+04 174 talc 16.49 15.32 -1.18 -0.069 0.20072E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46846E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88514E+03 182 tremolite 47.87 47.45 -0.42 -0.011 0.72190E+03 183 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66107E+04 184 troilite-low -4.41 -5.21 -0.80 -0.268 0.13707E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34783E+04 191 walstromite 11.51 9.91 -1.60 -0.319 0.27273E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.93771E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18575E+04 194 zoisite 22.85 18.83 -4.02 -0.183 0.68576E+04 195 akaganeite 7.75 4.56 -3.20 -0.691 0.54591E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58446E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66020E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68625E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73379E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60174E+04 208 nontronite-Ca 3.21 -0.03 -3.25 -0.211 0.55485E+04 209 nontronite-H 2.53 -2.19 -4.72 -0.316 0.80628E+04 210 nontronite-K 3.34 -0.13 -3.47 -0.223 0.59322E+04 211 nontronite-Mg 3.07 -0.66 -3.73 -0.242 0.63685E+04 212 nontronite-Na 3.52 0.56 -2.96 -0.190 0.50531E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35718E+04 234 alabandite -0.98 -2.70 -1.72 -0.572 0.29325E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62979E+04 238 dolomite,disordered 1.25 -3.31 -4.55 -0.759 0.77746E+04 239 ferrous-oxide 9.81 6.73 -3.09 -0.772 0.52701E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17986E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11683E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15073E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18560E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0100000 MOLES Current total amount of reactant added: 0.2399900 MOLES New total amount of reactant added: 0.2499900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2499900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4981E+00 Moles total = -.6964E+01 kg total = -.1255E+00 Activity = 0.9994 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3614194E-01 Chg. balance for total moles = -.8663E-10 Max. difference allowed = 0.1613E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15576E-09 -9.8075 0.12569E-09 -9.9007 0.80694E+00 -0.0932 2 H2O 0.99942E+00 -0.0003 0.99942E+00 -0.0003 3 Cl- 0.32148E-02 -2.4928 0.25699E-02 -2.5901 0.79939E+00 -0.0972 4 SO4-- 0.91568E-09 -9.0383 0.40141E-09 -9.3964 0.43838E+00 -0.3582 5 HCO3- 0.17092E-02 -2.7672 0.13695E-02 -2.8635 0.80122E+00 -0.0962 6 HS- 0.12243E-01 -1.9121 0.97889E-02 -2.0093 0.79957E+00 -0.0971 7 Al+++ 0.65963E-28 -28.1807 0.10337E-28 -28.9856 0.15670E+00 -0.8049 8 H4SiO4 0.71763E-03 -3.1441 0.71763E-03 -3.1441 0.10000E+01 0.0000 9 Ca++ 0.41179E-06 -6.3853 0.17843E-06 -6.7485 0.43330E+00 -0.3632 10 Mg++ 0.73076E-10 -10.1362 0.31437E-10 -10.5026 0.43020E+00 -0.3663 11 Fe++ 0.19437E-12 -12.7114 0.83760E-13 -13.0770 0.43094E+00 -0.3656 12 K+ 0.26527E-03 -3.5763 0.21261E-03 -3.6724 0.80149E+00 -0.0961 13 Na+ 0.33697E-01 -1.4724 0.26928E-01 -1.5698 0.79913E+00 -0.0974 14 Mn++ 0.64126E-10 -10.1930 0.27670E-10 -10.5580 0.43150E+00 -0.3650 15 F- 0.71052E-06 -6.1484 0.56618E-06 -6.2470 0.79686E+00 -0.0986 16 HPO4-- 0.22574E-07 -7.6464 0.98979E-08 -8.0045 0.43847E+00 -0.3581 18 HSiO3- 0.66731E-02 -2.1757 0.53344E-02 -2.2729 0.79939E+00 -0.0972 19 Ca(HSiO3)+ 0.27036E-07 -7.5681 0.21676E-07 -7.6640 0.80176E+00 -0.0960 20 Mg(HSiO3)+ 0.59282E-11 -11.2271 0.47530E-11 -11.3230 0.80176E+00 -0.0960 21 NaHSiO3,aq 0.23233E-02 -2.6339 0.23233E-02 -2.6339 0.10000E+01 0.0000 22 AlO+ 0.11096E-15 -15.9548 0.88964E-16 -16.0508 0.80176E+00 -0.0960 24 HAlO2,aq 0.14088E-09 -9.8512 0.14088E-09 -9.8512 0.10000E+01 0.0000 25 AlO2- 0.31124E-05 -5.5069 0.24811E-05 -5.6054 0.79716E+00 -0.0985 26 CH4,aq 0.32421E-01 -1.4892 0.32421E-01 -1.4892 0.10000E+01 0.0000 27 C2H6,aq 0.22483E-07 -7.6482 0.22483E-07 -7.6482 0.10000E+01 0.0000 28 C3H8,aq 0.35995E-12 -12.4438 0.35995E-12 -12.4438 0.10000E+01 0.0000 29 C4H10,aq 0.56612E-17 -17.2471 0.56612E-17 -17.2471 0.10000E+01 0.0000 30 ethanol,aq 0.11951E-14 -14.9226 0.11951E-14 -14.9226 0.10000E+01 0.0000 31 CO,aq 0.73932E-13 -13.1312 0.73932E-13 -13.1312 0.10000E+01 0.0000 32 CO2,aq 0.36800E-06 -6.4341 0.36800E-06 -6.4341 0.10000E+01 0.0000 33 CO3-2 0.21782E-02 -2.6619 0.95169E-03 -3.0215 0.43693E+00 -0.3596 34 CaCO3,aq 0.21292E-05 -5.6718 0.21292E-05 -5.6718 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.77794E-08 -8.1091 0.62373E-08 -8.2050 0.80176E+00 -0.0960 36 CaCl+ 0.92554E-09 -9.0336 0.74207E-09 -9.1296 0.80176E+00 -0.0960 37 CaCl2,aq 0.45307E-12 -12.3438 0.45307E-12 -12.3438 0.10000E+01 0.0000 38 CaF+ 0.18396E-11 -11.7353 0.14749E-11 -11.8312 0.80176E+00 -0.0960 39 CaOH+ 0.12612E-06 -6.8992 0.10112E-06 -6.9952 0.80176E+00 -0.0960 40 CaSO4,aq 0.22744E-13 -13.6431 0.22744E-13 -13.6431 0.10000E+01 0.0000 41 HCl,aq 0.59190E-13 -13.2278 0.59190E-13 -13.2278 0.10000E+01 0.0000 45 HF,aq 0.48715E-12 -12.3123 0.48715E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.11649E-18 -18.9337 0.93123E-19 -19.0309 0.79939E+00 -0.0972 48 FeCl+ 0.42495E-15 -15.3717 0.34071E-15 -15.4676 0.80176E+00 -0.0960 51 FeF+ 0.30226E-17 -17.5196 0.24234E-17 -17.6156 0.80176E+00 -0.0960 53 FeO,aq 0.20595E-09 -9.6862 0.20595E-09 -9.6862 0.10000E+01 0.0000 54 FeOH+ 0.27040E-10 -10.5680 0.21680E-10 -10.6639 0.80176E+00 -0.0960 55 HFeO2- 0.21434E-07 -7.6689 0.17134E-07 -7.7661 0.79939E+00 -0.0972 56 FeO+ 0.22813E-16 -16.6418 0.18291E-16 -16.7378 0.80176E+00 -0.0960 58 FeO2- 0.29620E-09 -9.5284 0.23678E-09 -9.6257 0.79939E+00 -0.0972 59 HFeO2,aq 0.37850E-11 -11.4219 0.37850E-11 -11.4219 0.10000E+01 0.0000 60 H2,aq 0.79927E-05 -5.0973 0.79927E-05 -5.0973 0.10000E+01 0.0000 61 KCl,aq 0.99028E-08 -8.0042 0.99028E-08 -8.0042 0.10000E+01 0.0000 63 KOH,aq 0.72197E-06 -6.1415 0.72197E-06 -6.1415 0.10000E+01 0.0000 64 KSO4- 0.16567E-11 -11.7808 0.13243E-11 -11.8780 0.79939E+00 -0.0972 65 MgCO3,aq 0.94034E-10 -10.0267 0.94034E-10 -10.0267 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.14006E-11 -11.8537 0.11229E-11 -11.9496 0.80176E+00 -0.0960 67 MgCl+ 0.14780E-12 -12.8303 0.11850E-12 -12.9263 0.80176E+00 -0.0960 68 MgF+ 0.12007E-14 -14.9206 0.96264E-15 -15.0165 0.80176E+00 -0.0960 69 MgOH+ 0.12296E-09 -9.9102 0.98583E-10 -10.0062 0.80176E+00 -0.0960 71 MnF+ 0.32912E-15 -15.4826 0.26388E-15 -15.5786 0.80176E+00 -0.0960 72 MnO,aq 0.18129E-08 -8.7416 0.18129E-08 -8.7416 0.10000E+01 0.0000 73 MnOH+ 0.82982E-09 -9.0810 0.66532E-09 -9.1770 0.80176E+00 -0.0960 74 MnO2-2 0.87113E-11 -11.0599 0.38062E-11 -11.4195 0.43693E+00 -0.3596 75 HMnO2- 0.13111E-09 -9.8824 0.10481E-09 -9.9796 0.79939E+00 -0.0972 78 MnCl+ 0.54616E-12 -12.2627 0.43789E-12 -12.3586 0.80176E+00 -0.0960 79 MnSO4,aq 0.32066E-17 -17.4940 0.32066E-17 -17.4940 0.10000E+01 0.0000 80 NaCl,aq 0.22934E-04 -4.6395 0.22934E-04 -4.6395 0.10000E+01 0.0000 81 NaF,aq 0.35694E-08 -8.4474 0.35694E-08 -8.4474 0.10000E+01 0.0000 82 NaOH,aq 0.91997E-04 -4.0362 0.91997E-04 -4.0362 0.10000E+01 0.0000 84 OH- 0.57632E-02 -2.2393 0.45942E-02 -2.3378 0.79716E+00 -0.0985 89 HPO3-2 0.56458E-15 -15.2483 0.24668E-15 -15.6079 0.43693E+00 -0.3596 91 H2PO3- 0.77777E-19 -19.1092 0.62174E-19 -19.2064 0.79939E+00 -0.0972 92 H3PO4,aq 0.10936E-17 -17.9611 0.10936E-17 -17.9611 0.10000E+01 0.0000 93 H2PO4- 0.28666E-10 -10.5426 0.22949E-10 -10.6392 0.80057E+00 -0.0966 94 PO4-3 0.37970E-09 -9.4206 0.64251E-10 -10.1921 0.16922E+00 -0.7716 98 HP2O7-3 0.41808E-18 -18.3787 0.65644E-19 -19.1828 0.15701E+00 -0.8041 99 P2O7-4 0.31707E-17 -17.4989 0.12477E-18 -18.9039 0.39352E-01 -1.4050 100 H2S,aq 0.38026E-05 -5.4199 0.38026E-05 -5.4199 0.10000E+01 0.0000 101 S2-2 0.60800E-09 -9.2161 0.26565E-09 -9.5757 0.43693E+00 -0.3596 102 S3-2 0.38971E-15 -15.4093 0.17027E-15 -15.7689 0.43693E+00 -0.3596 107 SO3-2 0.93365E-15 -15.0298 0.41717E-15 -15.3797 0.44681E+00 -0.3499 108 HSO3- 0.41068E-17 -17.3865 0.32830E-17 -17.4837 0.79939E+00 -0.0972 109 HSO4- 0.60550E-16 -16.2179 0.48622E-16 -16.3132 0.80301E+00 -0.0953 111 S2O3-2 0.41061E-16 -16.3866 0.17941E-16 -16.7462 0.43693E+00 -0.3596 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1557582E-09 -.1704313E-01 -.1712747E+02 0.0000 2 H2O 0.1000000E+01 0.5553754E+02 0.9975563E+06 0.0000 3 Cl- 0.3214849E-02 0.3237794E-02 0.1144489E+03 7.3106 4 SO4-- 0.9156778E-09 -.3242322E-01 -.3105383E+04 10.4050 5 HCO3- 0.1709217E-02 0.3631111E-01 0.2209027E+04 7.0373 6 HS- 0.1224273E-01 0.4466975E-01 0.1472934E+04 7.8914 7 Al+++ 0.6596270E-28 0.3112555E-05 0.8373217E-01 0.7165 8 H4SiO4 0.7176332E-03 0.9714091E-02 0.9309030E+03 -3.1441 9 Ca++ 0.4117901E-06 0.2702862E-05 0.1080039E+00 13.0529 10 Mg++ 0.7307608E-10 0.2975456E-09 0.7212461E-05 9.2989 11 Fe++ 0.1943657E-12 0.2196761E-07 0.1223185E-02 6.7244 12 K+ 0.2652652E-03 0.2659970E-03 0.1037015E+02 6.2283 13 Na+ 0.3369709E-01 0.3613531E-01 0.8282783E+03 8.3309 14 Mn++ 0.6412624E-10 0.2847172E-08 0.1559538E-03 9.2434 15 F- 0.7105171E-06 0.7140889E-06 0.1352600E-01 3.6537 16 HPO4-- 0.2257351E-07 0.2298188E-07 0.2199232E-02 11.7970 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276563E+02 -.8489551E-02 -.8275714E+02 0.0000000E+00 2 H2O -.6964122E+01 0.2766445E+02 -.3462857E+02 0.0000000E+00 3 Cl- 0.1612815E-02 0.1612815E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1397862E+00 -.1615071E-01 0.1559369E+00 0.0000000E+00 5 HCO3- 0.1808735E-01 0.1808735E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1336860E+00 0.2225097E-01 -.1559369E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1550431E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4838799E-02 0.5205907E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1346354E-05 0.5750725E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1482139E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1094254E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1324989E-03 0.1061438E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1799978E-01 0.6258377E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1418238E-08 0.8669296E-01 0.0000000E+00 15 F- 0.1000960E-03 0.3557031E-06 0.9974030E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1144777E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: -.2026E-14 Mass of aqueous solution: 0.499604E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2499900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.96 628.6 andradite 0.6237 -0.205 317.0 2.501 5.800 82.35 grossular 0.1221 -0.913 54.98 1.740 1.006 15.30 apatite-OH 0.9763E-02 -2.010 4.904 0.691 0.8973E-01 1.558 apatite-F 0.9974E-04 -4.001 0.5030E-01 -1.298 0.9204E-03 0.1571E-01 clinochlore 0.7149 -0.146 397.4 2.599 7.271 151.2 daphnite 0.1998 -0.699 142.6 2.154 2.609 43.21 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9432 -0.025 262.5 2.419 4.804 102.5 stilbite 3.247 0.511 2288. 3.359 41.87 1067. stilpnomelane-Fe 0.2365 -0.626 255.0 2.406 4.665 88.07 tr.625ac.25prg.125 0.1086 -0.964 92.82 1.968 1.698 29.87 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8363E+00 0.8363E+00 1.0000 -0.078 grossular 0.1637E+00 0.1637E+00 1.0000 -0.786 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7670E+00 0.7670E+00 1.0000 -0.115 daphnite 0.2144E+00 0.2144E+00 1.0000 -0.669 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5465.081825 g Volume = 2213.806291 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2499900 moles log = -0.6021 Original solution: 1000.0103000 g Original solution / Rock added: 4000.20 (Water/Rock Ratio), log = 3.6021 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 50.2388 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2184E-01 0.9163 0.1005E+01 0.1097E+01 CO2,gas 0.8524E-06 0.9195 0.3937E-04 0.4282E-04 CH4,gas 0.9780E+00 0.9713 0.4772E+02 0.4913E+02 H2,gas 0.2034E-03 1.0271 0.1049E-01 0.1022E-01 H2S,gas 0.2511E-05 0.8286 0.1045E-03 0.1262E-03 S2,gas 0.7414E-25 1.0000 0.3725E-23 0.3725E-23 CO,gas 0.2193E-11 1.0000 0.1102E-09 0.1102E-09 SO3,gas 0.4775E-46 1.0000 0.2399E-44 0.2399E-44 SO2,gas 0.1951E-25 1.0000 0.9800E-24 0.9800E-24 HF,gas 0.2381E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.2079E-17 1.0000 0.1044E-15 0.1044E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.00000E+00 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28970E+04 2 CO2,gas -6.66 -12.76 -6.10 -2.035 0.10422E+05 3 CH4,gas 4.54 4.52 -0.02 -0.005 0.34582E+02 4 H2,gas 8.00 4.32 -3.68 -2.102 0.62802E+04 5 H2S,gas -6.23 -11.91 -5.68 -2.840 0.96980E+04 6 S2,gas -7.34 -32.46 -25.13 -3.866 0.42905E+05 7 CO,gas 3.21 -8.44 -11.66 -3.587 0.19904E+05 8 SO3,gas 17.12 -29.20 -46.32 -11.580 0.79088E+05 9 SO2,gas 0.83 -24.88 -25.71 -6.855 0.43895E+05 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 11 HCl,gas 5.19 -12.49 -17.68 -8.840 0.30188E+05 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 12 acmite 7.71 6.61 -1.10 -0.115 0.18832E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80701E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.96027E+03 26 ankerite -2.14 -5.75 -3.62 -0.603 0.61741E+04 27 annite 20.12 17.69 -2.44 -0.135 0.41621E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28268E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.77052E+04 38 aragonite 0.97 0.29 -0.68 -0.226 0.11573E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55838E+04 40 calcite 0.81 0.29 -0.52 -0.174 0.89311E+03 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53273E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.599 0.71543E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70671E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82708E+04 45 celadonite 5.34 3.67 -1.67 -0.098 0.28572E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47513E+04 47 chrysotile 23.89 21.61 -2.28 -0.190 0.39003E+04 52 chlorite-Al-free 47.17 43.22 -3.96 -0.165 0.67558E+04 54 chloritoid-Fe 9.17 5.01 -4.16 -0.277 0.71049E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66071E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13105E+04 64 cristobalite -2.56 -3.14 -0.58 -0.194 0.99589E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.16 -0.360 0.36842E+04 69 diamond -3.10 -4.12 -1.02 -0.291 0.17375E+04 70 diopside 16.18 16.06 -0.12 -0.012 0.20031E+03 71 hedenbergite 14.21 13.49 -0.72 -0.072 0.12271E+04 72 dolomite,ordered 0.55 -3.18 -3.72 -0.620 0.63568E+04 74 enstatite 17.26 12.31 -4.95 -0.495 0.84603E+04 76 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82919E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34152E+04 79 clinozoisite 22.81 18.82 -3.98 -0.181 0.68014E+04 80 epidote-Fe 29.84 26.52 -3.32 -0.173 0.56755E+04 81 fayalite 14.05 10.30 -3.74 -0.534 0.63875E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68098E+04 86 gibbsite 4.08 0.72 -3.36 -0.481 0.57432E+04 87 glaucophane 22.97 20.84 -2.13 -0.058 0.36440E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.71004E+04 89 graphite -3.55 -4.12 -0.57 -0.164 0.97975E+03 90 greenalite 16.14 13.88 -2.25 -0.188 0.38497E+04 93 hematite 12.57 9.13 -3.44 -0.417 0.58733E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24853E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64597E+04 101 kaolinite -1.33 -4.86 -3.52 -0.320 0.60149E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16630E+04 105 lawsonite 9.62 8.20 -1.42 -0.095 0.24227E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59109E+04 108 lizardite 23.24 21.61 -1.64 -0.136 0.27929E+04 109 magnesite 0.69 -3.47 -4.16 -1.385 0.70961E+04 110 magnetite 20.09 15.85 -4.24 -0.346 0.72342E+04 111 minnesotaite 10.39 7.60 -2.79 -0.164 0.47641E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82214E+04 123 muscovite 2.58 -1.05 -3.64 -0.214 0.62100E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54491E+04 125 nepheline 8.34 5.90 -2.44 -0.348 0.41596E+04 131 periclase-Fe 11.63 6.72 -4.90 -1.226 0.83707E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36456E+04 139 prehnite 19.37 18.11 -1.27 -0.074 0.21607E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92941E+03 141 pumpellyite-Fe 46.27 43.65 -2.62 -0.058 0.44678E+04 142 pumpellyite-Mg 48.99 46.23 -2.77 -0.062 0.47257E+04 145 pyrite -21.25 -21.42 -0.17 -0.040 0.29073E+03 146 pyrrhotite -4.26 -5.19 -0.93 -0.308 0.15798E+04 147 pyrrhotiteFe0.875 -6.02 -6.56 -0.55 -0.200 0.93061E+03 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22182E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84803E+04 150 quartz -2.99 -3.14 -0.15 -0.051 0.26322E+03 154 rhodochrosite -0.98 -3.52 -2.54 -0.848 0.43445E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22984E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.04 -3.43 -1.144 0.58593E+04 168 stilpnomelane-Mg 27.44 25.89 -1.55 -0.046 0.26506E+04 174 talc 16.49 15.32 -1.17 -0.069 0.19975E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46837E+04 181 tridymite -2.63 -3.14 -0.52 -0.172 0.88319E+03 182 tremolite 47.87 47.45 -0.42 -0.011 0.71707E+03 183 ferroactinolite 38.45 34.58 -3.88 -0.105 0.66167E+04 184 troilite-low -4.41 -5.19 -0.77 -0.258 0.13226E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34841E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27323E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.94272E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18626E+04 194 zoisite 22.85 18.82 -4.03 -0.183 0.68755E+04 195 akaganeite 7.75 4.56 -3.19 -0.690 0.54494E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58251E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66007E+04 205 montmorillonite-K -2.24 -6.25 -4.02 -0.246 0.68609E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73353E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60158E+04 208 nontronite-Ca 3.21 -0.02 -3.24 -0.210 0.55243E+04 209 nontronite-H 2.53 -2.17 -4.71 -0.315 0.80375E+04 210 nontronite-K 3.34 -0.12 -3.46 -0.222 0.59077E+04 211 nontronite-Mg 3.07 -0.64 -3.71 -0.241 0.63430E+04 212 nontronite-Na 3.52 0.57 -2.95 -0.189 0.50286E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35757E+04 234 alabandite -0.98 -2.67 -1.69 -0.563 0.28834E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.63011E+04 238 dolomite,disordered 1.25 -3.18 -4.42 -0.737 0.75538E+04 239 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52716E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17967E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11702E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15097E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18588E+04 ******** WARNING ******** Computational singularity, IV(N) = 0.0