File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.82767E+02 0.15099E-09 0.8089 0.00000000E+00 H2O 2 0. -0.69723E+01 0.10000E+01 0.9994 0.00000000E+00 Cl- 3 -1. 0.15538E-02 0.30975E-02 0.8015 0.00000000E+00 SO4-- 4 -2. 0.13974E+00 0.79591E-09 0.4428 0.00000000E+00 HCO3- 5 -1. 0.17364E-01 0.15056E-02 0.8032 0.00000000E+00 HS- 6 -1. -0.13388E+00 0.11754E-01 0.8016 0.00000000E+00 Al+++ 7 3. 0.16304E+02 0.59389E-28 0.1604 0.00000000E+00 H4SiO4 8 0. 0.52064E+02 0.71578E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.57507E+01 0.38840E-06 0.4378 0.00000000E+00 Mg++ 10 2. 0.39683E+01 0.68211E-10 0.4347 0.00000000E+00 Fe++ 11 2. 0.35650E+01 0.18196E-12 0.4355 0.00000000E+00 K+ 12 1. 0.10616E+01 0.25798E-03 0.8035 0.00000000E+00 Na+ 13 1. 0.62764E+01 0.32770E-01 0.8012 0.00000000E+00 Mn++ 14 2. 0.86693E-01 0.59954E-10 0.4360 0.00000000E+00 F- 15 -1. 0.96096E-04 0.72933E-06 0.7990 0.00000000E+00 HPO4-- 16 -2. 0.29588E-01 0.23304E-07 0.4429 0.00000000E+00 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1554E-06 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.400000E+00 TEMP = 100.0000 SINC = 0.1000E-02 TEMPC = 0.0000 TOTMIX = 0.239990E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 2000.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.0000E+00 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.0000E+00 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.0000E+00 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.6245E+01 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.6215E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.1238E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.0000E+00 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.9767E-02 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.9573E-04 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.3245E+01 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.2368E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.0000E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.7138E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.2001E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.1734E-01 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.0000E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.0000E+00 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.9431E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.1101E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 0.2399900 moles log = -0.6198 Original solution: 1000.0103000 g Original solution / Rock added: 4166.88 (Water/Rock Ratio), log = 3.6198 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2399900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4982E+00 Moles total = -.6972E+01 kg total = -.1256E+00 Activity = 0.9994 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3498864E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1554E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15099E-09 -9.8211 0.12213E-09 -9.9132 0.80885E+00 -0.0921 2 H2O 0.99943E+00 -0.0002 0.99943E+00 -0.0002 3 Cl- 0.30975E-02 -2.5090 0.24825E-02 -2.6051 0.80145E+00 -0.0961 4 SO4-- 0.79591E-09 -9.0991 0.35243E-09 -9.4529 0.44281E+00 -0.3538 5 HCO3- 0.15056E-02 -2.8223 0.12093E-02 -2.9175 0.80325E+00 -0.0952 6 HS- 0.11754E-01 -1.9298 0.94224E-02 -2.0258 0.80163E+00 -0.0960 7 Al+++ 0.59389E-28 -28.2263 0.95240E-29 -29.0212 0.16037E+00 -0.7949 8 H4SiO4 0.71578E-03 -3.1452 0.71578E-03 -3.1452 0.10000E+01 0.0000 9 Ca++ 0.38840E-06 -6.4107 0.17004E-06 -6.7694 0.43780E+00 -0.3587 10 Mg++ 0.68211E-10 -10.1661 0.29654E-10 -10.5279 0.43474E+00 -0.3618 11 Fe++ 0.18196E-12 -12.7400 0.79240E-13 -13.1011 0.43547E+00 -0.3610 12 K+ 0.25798E-03 -3.5884 0.20729E-03 -3.6834 0.80352E+00 -0.0950 13 Na+ 0.32770E-01 -1.4845 0.26255E-01 -1.5808 0.80120E+00 -0.0963 14 Mn++ 0.59954E-10 -10.2222 0.26141E-10 -10.5827 0.43602E+00 -0.3605 15 F- 0.72933E-06 -6.1371 0.58271E-06 -6.2345 0.79897E+00 -0.0975 16 HPO4-- 0.23304E-07 -7.6326 0.10321E-07 -7.9863 0.44290E+00 -0.3537 18 HSiO3- 0.68323E-02 -2.1654 0.54758E-02 -2.2616 0.80145E+00 -0.0961 19 Ca(HSiO3)+ 0.26381E-07 -7.5787 0.21205E-07 -7.6736 0.80378E+00 -0.0949 20 Mg(HSiO3)+ 0.57257E-11 -11.2422 0.46022E-11 -11.3370 0.80378E+00 -0.0949 21 NaHSiO3,aq 0.23252E-02 -2.6335 0.23252E-02 -2.6335 0.10000E+01 0.0000 22 AlO+ 0.10802E-15 -15.9665 0.86824E-16 -16.0614 0.80378E+00 -0.0949 24 HAlO2,aq 0.14150E-09 -9.8492 0.14150E-09 -9.8492 0.10000E+01 0.0000 25 AlO2- 0.32090E-05 -5.4936 0.25648E-05 -5.5909 0.79927E+00 -0.0973 26 CH4,aq 0.31389E-01 -1.5032 0.31389E-01 -1.5032 0.10000E+01 0.0000 27 C2H6,aq 0.20447E-07 -7.6894 0.20447E-07 -7.6894 0.10000E+01 0.0000 28 C3H8,aq 0.30751E-12 -12.5121 0.30751E-12 -12.5121 0.10000E+01 0.0000 29 C4H10,aq 0.45432E-17 -17.3426 0.45432E-17 -17.3426 0.10000E+01 0.0000 30 ethanol,aq 0.10546E-14 -14.9769 0.10546E-14 -14.9769 0.10000E+01 0.0000 31 CO,aq 0.65380E-13 -13.1846 0.65380E-13 -13.1846 0.10000E+01 0.0000 32 CO2,aq 0.31576E-06 -6.5006 0.31576E-06 -6.5006 0.10000E+01 0.0000 33 CO3-2 0.19597E-02 -2.7078 0.86494E-03 -3.0630 0.44137E+00 -0.3552 34 CaCO3,aq 0.18442E-05 -5.7342 0.18442E-05 -5.7342 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.65305E-08 -8.1851 0.52491E-08 -8.2799 0.80378E+00 -0.0949 36 CaCl+ 0.84989E-09 -9.0706 0.68312E-09 -9.1655 0.80378E+00 -0.0949 37 CaCl2,aq 0.40289E-12 -12.3948 0.40289E-12 -12.3948 0.10000E+01 0.0000 38 CaF+ 0.17998E-11 -11.7448 0.14466E-11 -11.8396 0.80378E+00 -0.0949 39 CaOH+ 0.12339E-06 -6.9087 0.99176E-07 -7.0036 0.80378E+00 -0.0949 40 CaSO4,aq 0.19030E-13 -13.7206 0.19030E-13 -13.7206 0.10000E+01 0.0000 41 HCl,aq 0.55555E-13 -13.2553 0.55555E-13 -13.2553 0.10000E+01 0.0000 45 HF,aq 0.48716E-12 -12.3123 0.48716E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.11959E-18 -18.9223 0.95843E-19 -19.0184 0.80145E+00 -0.0961 48 FeCl+ 0.38737E-15 -15.4119 0.31136E-15 -15.5067 0.80378E+00 -0.0949 51 FeF+ 0.29356E-17 -17.5323 0.23595E-17 -17.6272 0.80378E+00 -0.0949 53 FeO,aq 0.20637E-09 -9.6853 0.20637E-09 -9.6853 0.10000E+01 0.0000 54 FeOH+ 0.26261E-10 -10.5807 0.21108E-10 -10.6755 0.80378E+00 -0.0949 55 HFeO2- 0.22049E-07 -7.6566 0.17671E-07 -7.7527 0.80145E+00 -0.0961 56 FeO+ 0.21824E-16 -16.6611 0.17542E-16 -16.7559 0.80378E+00 -0.0949 58 FeO2- 0.30012E-09 -9.5227 0.24053E-09 -9.6188 0.80145E+00 -0.0961 59 HFeO2,aq 0.37360E-11 -11.4276 0.37360E-11 -11.4276 0.10000E+01 0.0000 60 H2,aq 0.82377E-05 -5.0842 0.82377E-05 -5.0842 0.10000E+01 0.0000 61 KCl,aq 0.93267E-08 -8.0303 0.93267E-08 -8.0303 0.10000E+01 0.0000 63 KOH,aq 0.72447E-06 -6.1400 0.72447E-06 -6.1400 0.10000E+01 0.0000 64 KSO4- 0.14145E-11 -11.8494 0.11337E-11 -11.9455 0.80145E+00 -0.0961 65 MgCO3,aq 0.80614E-10 -10.0936 0.80614E-10 -10.0936 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11637E-11 -11.9342 0.93538E-12 -12.0290 0.80378E+00 -0.0949 67 MgCl+ 0.13433E-12 -12.8718 0.10797E-12 -12.9667 0.80378E+00 -0.0949 68 MgF+ 0.11627E-14 -14.9345 0.93454E-15 -15.0294 0.80378E+00 -0.0949 69 MgOH+ 0.11907E-09 -9.9242 0.95705E-10 -10.0191 0.80378E+00 -0.0949 71 MnF+ 0.31921E-15 -15.4959 0.25658E-15 -15.5908 0.80378E+00 -0.0949 72 MnO,aq 0.18141E-08 -8.7413 0.18141E-08 -8.7413 0.10000E+01 0.0000 73 MnOH+ 0.80483E-09 -9.0943 0.64691E-09 -9.1892 0.80378E+00 -0.0949 74 MnO2-2 0.91406E-11 -11.0390 0.40344E-11 -11.3942 0.44137E+00 -0.3552 75 HMnO2- 0.13469E-09 -9.8707 0.10794E-09 -9.9668 0.80145E+00 -0.0961 78 MnCl+ 0.49717E-12 -12.3035 0.39962E-12 -12.3984 0.80378E+00 -0.0949 79 MnSO4,aq 0.26597E-17 -17.5752 0.26597E-17 -17.5752 0.10000E+01 0.0000 80 NaCl,aq 0.21600E-04 -4.6655 0.21600E-04 -4.6655 0.10000E+01 0.0000 81 NaF,aq 0.35818E-08 -8.4459 0.35818E-08 -8.4459 0.10000E+01 0.0000 82 NaOH,aq 0.92316E-04 -4.0347 0.92316E-04 -4.0347 0.10000E+01 0.0000 84 OH- 0.59158E-02 -2.2280 0.47283E-02 -2.3253 0.79927E+00 -0.0973 89 HPO3-2 0.60066E-15 -15.2214 0.26511E-15 -15.5766 0.44137E+00 -0.3552 91 H2PO3- 0.81010E-19 -19.0915 0.64926E-19 -19.1876 0.80145E+00 -0.0961 92 H3PO4,aq 0.10766E-17 -17.9679 0.10766E-17 -17.9679 0.10000E+01 0.0000 93 H2PO4- 0.28971E-10 -10.5380 0.23253E-10 -10.6335 0.80261E+00 -0.0955 94 PO4-3 0.39890E-09 -9.3991 0.68955E-10 -10.1614 0.17286E+00 -0.7623 98 HP2O7-3 0.43166E-18 -18.3649 0.69356E-19 -19.1589 0.16067E+00 -0.7941 99 P2O7-4 0.33127E-17 -17.4798 0.13567E-18 -18.8675 0.40955E-01 -1.3877 100 H2S,aq 0.35564E-05 -5.4490 0.35564E-05 -5.4490 0.10000E+01 0.0000 101 S2-2 0.54106E-09 -9.2668 0.23881E-09 -9.6220 0.44137E+00 -0.3552 102 S3-2 0.31470E-15 -15.5021 0.13890E-15 -15.8573 0.44137E+00 -0.3552 107 SO3-2 0.83676E-15 -15.0774 0.37749E-15 -15.4231 0.45113E+00 -0.3457 108 HSO3- 0.36016E-17 -17.4435 0.28865E-17 -17.5396 0.80145E+00 -0.0961 109 HSO4- 0.51527E-16 -16.2880 0.41479E-16 -16.3822 0.80500E+00 -0.0942 111 S2O3-2 0.33377E-16 -16.4766 0.14732E-16 -16.8317 0.44137E+00 -0.3552 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1509855E-09 -.1713916E-01 -.1722517E+02 0.0000 2 H2O 0.1000000E+01 0.5553651E+02 0.9976065E+06 0.0000 3 Cl- 0.3097456E-02 0.3119066E-02 0.1102597E+03 7.3081 4 SO4-- 0.7959087E-09 -.3139116E-01 -.3006743E+04 10.3735 5 HCO3- 0.1505566E-02 0.3485649E-01 0.2120680E+04 6.9957 6 HS- 0.1175407E-01 0.4314879E-01 0.1422880E+04 7.8874 7 Al+++ 0.5938857E-28 0.3209094E-05 0.8633517E-01 0.7184 8 H4SiO4 0.7157800E-03 0.9873373E-02 0.9462323E+03 -3.1452 9 Ca++ 0.3884004E-06 0.2389715E-05 0.9549737E-01 13.0569 10 Mg++ 0.6821055E-10 0.2749186E-09 0.6664447E-05 9.2985 11 Fe++ 0.1819635E-12 0.2258548E-07 0.1257675E-02 6.7253 12 K+ 0.2579823E-03 0.2587161E-03 0.1008699E+02 6.2298 13 Na+ 0.3276965E-01 0.3520880E-01 0.8070968E+03 8.3324 14 Mn++ 0.5995442E-10 0.2823232E-08 0.1546531E-03 9.2437 15 F- 0.7293265E-06 0.7329106E-06 0.1388347E-01 3.6786 16 HPO4-- 0.2330388E-07 0.2373176E-07 0.2271147E-02 11.8401 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276671E+02 -.8538159E-02 -.8275817E+02 0.0000000E+00 2 H2O -.6972309E+01 0.2766644E+02 -.3463875E+02 0.0000000E+00 3 Cl- 0.1553815E-02 0.1553815E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1397385E+00 -.1563803E-01 0.1553765E+00 0.0000000E+00 5 HCO3- 0.1736435E-01 0.1736435E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1338812E+00 0.2149529E-01 -.1553765E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1598664E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4918586E-02 0.5205899E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1190477E-05 0.5750725E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1369553E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1125134E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1288837E-03 0.1061442E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1753985E-01 0.6258837E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1406440E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9609600E-04 0.3651117E-06 0.9573089E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1182237E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: 0.8951E-15 Mass of aqueous solution: 0.499615E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2399900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.97 628.6 andradite 0.6215 -0.207 315.8 2.499 5.779 82.06 grossular 0.1238 -0.907 55.75 1.746 1.020 15.51 apatite-OH 0.9767E-02 -2.010 4.906 0.691 0.8978E-01 1.559 apatite-F 0.9573E-04 -4.019 0.4828E-01 -1.316 0.8834E-03 0.1508E-01 clinochlore 0.7138 -0.146 396.8 2.599 7.260 150.9 daphnite 0.2001 -0.699 142.8 2.155 2.613 43.27 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9431 -0.025 262.5 2.419 4.803 102.5 stilbite 3.245 0.511 2287. 3.359 41.85 1067. stilpnomelane-Fe 0.2368 -0.626 255.2 2.407 4.670 88.16 tr.625ac.25prg.125 0.1101 -0.958 94.13 1.974 1.723 30.30 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8339E+00 0.8339E+00 1.0000 -0.079 grossular 0.1661E+00 0.1661E+00 1.0000 -0.780 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7665E+00 0.7665E+00 1.0000 -0.115 daphnite 0.2149E+00 0.2149E+00 1.0000 -0.668 chlorite-Mn 0.1862E-01 0.1862E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5464.865113 g Volume = 2213.593096 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2399900 moles log = -0.6198 Original solution: 1000.0103000 g Original solution / Rock added: 4166.88 (Water/Rock Ratio), log = 3.6198 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 48.6314 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2251E-01 0.9183 0.1005E+01 0.1095E+01 CO2,gas 0.7537E-06 0.9217 0.3378E-04 0.3665E-04 CH4,gas 0.9773E+00 0.9722 0.4620E+02 0.4753E+02 H2,gas 0.2167E-03 1.0263 0.1082E-01 0.1054E-01 H2S,gas 0.2412E-05 0.8334 0.9776E-04 0.1173E-03 S2,gas 0.6307E-25 1.0000 0.3067E-23 0.3067E-23 CO,gas 0.2003E-11 1.0000 0.9743E-10 0.9743E-10 SO3,gas 0.4089E-46 1.0000 0.1989E-44 0.1989E-44 SO2,gas 0.1722E-25 1.0000 0.8372E-24 0.8372E-24 HF,gas 0.2460E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.2016E-17 1.0000 0.9803E-16 0.9803E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28970E+04 0.002 2 CO2,gas -6.66 -12.83 -6.17 -2.057 0.10536E+05 -4.471 3 CH4,gas 4.54 4.51 -0.03 -0.009 0.58573E+02 1.665 4 H2,gas 8.00 4.33 -3.66 -2.094 0.62578E+04 -1.966 5 H2S,gas -6.23 -11.94 -5.71 -2.854 0.97476E+04 -4.010 6 S2,gas -7.34 -32.55 -25.21 -3.879 0.43049E+05 -23.513 7 CO,gas 3.21 -8.50 -11.71 -3.603 0.19995E+05 -10.011 8 SO3,gas 17.12 -29.28 -46.40 -11.600 0.79227E+05 -44.701 9 SO2,gas 0.83 -24.94 -25.78 -6.874 0.44012E+05 -24.077 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.52 -17.71 -8.854 0.30235E+05 -16.009 12 acmite 7.71 6.60 -1.11 -0.115 0.18942E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80679E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95831E+03 26 ankerite -2.14 -5.88 -3.74 -0.624 0.63927E+04 27 annite 20.12 17.69 -2.43 -0.135 0.41575E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28287E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.76956E+04 38 aragonite 0.97 0.23 -0.74 -0.247 0.12639E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55844E+04 40 calcite 0.81 0.23 -0.59 -0.195 0.99969E+03 41 carnegieite-low 9.02 5.91 -3.12 -0.445 0.53234E+04 42 carnegieite-high 10.09 5.91 -4.19 -0.598 0.71504E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70651E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82666E+04 45 celadonite 5.34 3.67 -1.67 -0.099 0.28597E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47517E+04 47 chrysotile 23.89 21.60 -2.29 -0.191 0.39061E+04 52 chlorite-Al-free 47.17 43.21 -3.96 -0.165 0.67674E+04 54 chloritoid-Fe 9.17 5.02 -4.16 -0.277 0.70987E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66019E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13125E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99783E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.16 -0.359 0.36809E+04 69 diamond -3.10 -4.16 -1.06 -0.302 0.18063E+04 70 diopside 16.18 16.07 -0.12 -0.012 0.19787E+03 71 hedenbergite 14.21 13.49 -0.72 -0.072 0.12225E+04 72 dolomite,ordered 0.55 -3.31 -3.85 -0.642 0.65776E+04 74 enstatite 17.26 12.31 -4.96 -0.496 0.84655E+04 76 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82971E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34102E+04 79 clinozoisite 22.81 18.83 -3.97 -0.181 0.67835E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56834E+04 81 fayalite 14.05 10.31 -3.74 -0.534 0.63864E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68107E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57399E+04 87 glaucophane 22.97 20.84 -2.14 -0.058 0.36498E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70997E+04 89 graphite -3.55 -4.16 -0.61 -0.175 0.10485E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38490E+04 93 hematite 12.57 9.12 -3.45 -0.418 0.58926E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24834E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64559E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60122E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16572E+04 105 lawsonite 9.62 8.20 -1.41 -0.094 0.24131E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59089E+04 108 lizardite 23.24 21.60 -1.64 -0.137 0.27987E+04 109 magnesite 0.69 -3.53 -4.22 -1.408 0.72103E+04 110 magnetite 20.09 15.84 -4.25 -0.347 0.72520E+04 111 minnesotaite 10.39 7.60 -2.79 -0.164 0.47673E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82209E+04 123 muscovite 2.58 -1.05 -3.63 -0.214 0.62034E+04 124 paragonite 4.24 1.05 -3.19 -0.187 0.54425E+04 125 nepheline 8.34 5.91 -2.43 -0.348 0.41558E+04 131 periclase-Fe 11.63 6.73 -4.90 -1.225 0.83692E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36475E+04 139 prehnite 19.37 18.12 -1.26 -0.074 0.21460E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92769E+03 141 pumpellyite-Fe 46.27 43.67 -2.60 -0.058 0.44336E+04 142 pumpellyite-Mg 48.99 46.25 -2.75 -0.061 0.46937E+04 145 pyrite -21.25 -21.49 -0.24 -0.057 0.41086E+03 146 pyrrhotite -4.26 -5.21 -0.95 -0.318 0.16279E+04 147 pyrrhotiteFe0.875 -6.02 -6.59 -0.57 -0.211 0.98169E+03 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22196E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84815E+04 150 quartz -2.99 -3.14 -0.16 -0.052 0.26516E+03 154 rhodochrosite -0.98 -3.59 -2.61 -0.870 0.44575E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22999E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.11 -3.50 -1.166 0.59713E+04 168 stilpnomelane-Mg 27.44 25.88 -1.56 -0.047 0.26615E+04 174 talc 16.49 15.32 -1.18 -0.069 0.20072E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46846E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88514E+03 182 tremolite 47.87 47.45 -0.42 -0.011 0.72190E+03 183 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66107E+04 184 troilite-low -4.41 -5.21 -0.80 -0.268 0.13707E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34783E+04 191 walstromite 11.51 9.91 -1.60 -0.319 0.27273E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.93771E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18575E+04 194 zoisite 22.85 18.83 -4.02 -0.183 0.68576E+04 195 akaganeite 7.75 4.56 -3.20 -0.691 0.54591E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58446E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66020E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68625E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73379E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60174E+04 208 nontronite-Ca 3.21 -0.03 -3.25 -0.211 0.55485E+04 209 nontronite-H 2.53 -2.19 -4.72 -0.316 0.80628E+04 210 nontronite-K 3.34 -0.13 -3.47 -0.223 0.59322E+04 211 nontronite-Mg 3.07 -0.66 -3.73 -0.242 0.63685E+04 212 nontronite-Na 3.52 0.56 -2.96 -0.190 0.50531E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35718E+04 234 alabandite -0.98 -2.70 -1.72 -0.572 0.29325E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62979E+04 238 dolomite,disordered 1.25 -3.31 -4.55 -0.759 0.77746E+04 239 ferrous-oxide 9.81 6.73 -3.09 -0.772 0.52701E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17986E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11683E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15073E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18560E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.2399900 MOLES New total amount of reactant added: 0.2409900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8660E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2409900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4982E+00 Moles total = -.6971E+01 kg total = -.1256E+00 Activity = 0.9994 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3510128E-01 Chg. balance for total moles = -.8660E-10 Max. difference allowed = 0.1560E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15145E-09 -9.8197 0.12247E-09 -9.9120 0.80866E+00 -0.0922 2 H2O 0.99943E+00 -0.0002 0.99943E+00 -0.0002 3 Cl- 0.31092E-02 -2.5074 0.24912E-02 -2.6036 0.80125E+00 -0.0962 4 SO4-- 0.80729E-09 -9.0930 0.35712E-09 -9.4472 0.44237E+00 -0.3542 5 HCO3- 0.15251E-02 -2.8167 0.12247E-02 -2.9120 0.80304E+00 -0.0953 6 HS- 0.11803E-01 -1.9280 0.94592E-02 -2.0241 0.80143E+00 -0.0961 7 Al+++ 0.60009E-28 -28.2218 0.96016E-29 -29.0177 0.16000E+00 -0.7959 8 H4SiO4 0.71597E-03 -3.1451 0.71597E-03 -3.1451 0.10000E+01 0.0000 9 Ca++ 0.39065E-06 -6.4082 0.17085E-06 -6.7674 0.43735E+00 -0.3592 10 Mg++ 0.68678E-10 -10.1632 0.29826E-10 -10.5254 0.43429E+00 -0.3622 11 Fe++ 0.18316E-12 -12.7372 0.79677E-13 -13.0987 0.43502E+00 -0.3615 12 K+ 0.25869E-03 -3.5872 0.20781E-03 -3.6823 0.80332E+00 -0.0951 13 Na+ 0.32860E-01 -1.4833 0.26321E-01 -1.5797 0.80099E+00 -0.0964 14 Mn++ 0.60355E-10 -10.2193 0.26289E-10 -10.5802 0.43557E+00 -0.3609 15 F- 0.72744E-06 -6.1382 0.58105E-06 -6.2358 0.79876E+00 -0.0976 16 HPO4-- 0.23231E-07 -7.6339 0.10279E-07 -7.9881 0.44246E+00 -0.3541 18 HSiO3- 0.68164E-02 -2.1664 0.54616E-02 -2.2627 0.80125E+00 -0.0962 19 Ca(HSiO3)+ 0.26445E-07 -7.5777 0.21251E-07 -7.6726 0.80358E+00 -0.0950 20 Mg(HSiO3)+ 0.57455E-11 -11.2407 0.46170E-11 -11.3356 0.80358E+00 -0.0950 21 NaHSiO3,aq 0.23250E-02 -2.6336 0.23250E-02 -2.6336 0.10000E+01 0.0000 22 AlO+ 0.10831E-15 -15.9653 0.87033E-16 -16.0603 0.80358E+00 -0.0950 24 HAlO2,aq 0.14144E-09 -9.8494 0.14144E-09 -9.8494 0.10000E+01 0.0000 25 AlO2- 0.31992E-05 -5.4950 0.25564E-05 -5.5924 0.79906E+00 -0.0974 26 CH4,aq 0.31494E-01 -1.5018 0.31494E-01 -1.5018 0.10000E+01 0.0000 27 C2H6,aq 0.20646E-07 -7.6852 0.20646E-07 -7.6852 0.10000E+01 0.0000 28 C3H8,aq 0.31249E-12 -12.5052 0.31249E-12 -12.5052 0.10000E+01 0.0000 29 C4H10,aq 0.46463E-17 -17.3329 0.46463E-17 -17.3329 0.10000E+01 0.0000 30 ethanol,aq 0.10681E-14 -14.9714 0.10681E-14 -14.9714 0.10000E+01 0.0000 31 CO,aq 0.66199E-13 -13.1791 0.66199E-13 -13.1791 0.10000E+01 0.0000 32 CO2,aq 0.32069E-06 -6.4939 0.32069E-06 -6.4939 0.10000E+01 0.0000 33 CO3-2 0.19809E-02 -2.7031 0.87345E-03 -3.0588 0.44093E+00 -0.3556 34 CaCO3,aq 0.18712E-05 -5.7279 0.18712E-05 -5.7279 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.66468E-08 -8.1774 0.53413E-08 -8.2724 0.80358E+00 -0.0950 36 CaCl+ 0.85718E-09 -9.0669 0.68881E-09 -9.1619 0.80358E+00 -0.0950 37 CaCl2,aq 0.40768E-12 -12.3897 0.40768E-12 -12.3897 0.10000E+01 0.0000 38 CaF+ 0.18037E-11 -11.7438 0.14494E-11 -11.8388 0.80358E+00 -0.0950 39 CaOH+ 0.12365E-06 -6.9078 0.99366E-07 -7.0028 0.80358E+00 -0.0950 40 CaSO4,aq 0.19375E-13 -13.7128 0.19375E-13 -13.7128 0.10000E+01 0.0000 41 HCl,aq 0.55910E-13 -13.2525 0.55910E-13 -13.2525 0.10000E+01 0.0000 45 HF,aq 0.48716E-12 -12.3123 0.48716E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.11928E-18 -18.9234 0.95570E-19 -19.0197 0.80125E+00 -0.0962 48 FeCl+ 0.39098E-15 -15.4078 0.31418E-15 -15.5028 0.80358E+00 -0.0950 51 FeF+ 0.29441E-17 -17.5311 0.23658E-17 -17.6260 0.80358E+00 -0.0950 53 FeO,aq 0.20633E-09 -9.6854 0.20633E-09 -9.6854 0.10000E+01 0.0000 54 FeOH+ 0.26338E-10 -10.5794 0.21164E-10 -10.6744 0.80358E+00 -0.0950 55 HFeO2- 0.21987E-07 -7.6578 0.17617E-07 -7.7541 0.80125E+00 -0.0962 56 FeO+ 0.21921E-16 -16.6591 0.17615E-16 -16.7541 0.80358E+00 -0.0950 58 FeO2- 0.29973E-09 -9.5233 0.24016E-09 -9.6195 0.80125E+00 -0.0962 59 HFeO2,aq 0.37410E-11 -11.4270 0.37410E-11 -11.4270 0.10000E+01 0.0000 60 H2,aq 0.82127E-05 -5.0855 0.82127E-05 -5.0855 0.10000E+01 0.0000 61 KCl,aq 0.93831E-08 -8.0277 0.93831E-08 -8.0277 0.10000E+01 0.0000 63 KOH,aq 0.72422E-06 -6.1401 0.72422E-06 -6.1401 0.10000E+01 0.0000 64 KSO4- 0.14373E-11 -11.8425 0.11516E-11 -11.9387 0.80125E+00 -0.0962 65 MgCO3,aq 0.81880E-10 -10.0868 0.81880E-10 -10.0868 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.11857E-11 -11.9260 0.95279E-12 -12.0210 0.80358E+00 -0.0950 67 MgCl+ 0.13563E-12 -12.8677 0.10899E-12 -12.9626 0.80358E+00 -0.0950 68 MgF+ 0.11664E-14 -14.9332 0.93729E-15 -15.0281 0.80358E+00 -0.0950 69 MgOH+ 0.11945E-09 -9.9228 0.95987E-10 -10.0178 0.80358E+00 -0.0950 71 MnF+ 0.32018E-15 -15.4946 0.25729E-15 -15.5896 0.80358E+00 -0.0950 72 MnO,aq 0.18140E-08 -8.7414 0.18140E-08 -8.7414 0.10000E+01 0.0000 73 MnOH+ 0.80728E-09 -9.0930 0.64871E-09 -9.1879 0.80358E+00 -0.0950 74 MnO2-2 0.90970E-11 -11.0411 0.40112E-11 -11.3967 0.44093E+00 -0.3556 75 HMnO2- 0.13433E-09 -9.8718 0.10763E-09 -9.9681 0.80125E+00 -0.0962 78 MnCl+ 0.50188E-12 -12.2994 0.40330E-12 -12.3944 0.80358E+00 -0.0950 79 MnSO4,aq 0.27103E-17 -17.5670 0.27103E-17 -17.5670 0.10000E+01 0.0000 80 NaCl,aq 0.21731E-04 -4.6629 0.21731E-04 -4.6629 0.10000E+01 0.0000 81 NaF,aq 0.35805E-08 -8.4461 0.35805E-08 -8.4461 0.10000E+01 0.0000 82 NaOH,aq 0.92283E-04 -4.0349 0.92283E-04 -4.0349 0.10000E+01 0.0000 84 OH- 0.59005E-02 -2.2291 0.47148E-02 -2.3265 0.79906E+00 -0.0974 89 HPO3-2 0.59696E-15 -15.2241 0.26322E-15 -15.5797 0.44093E+00 -0.3556 91 H2PO3- 0.80681E-19 -19.0932 0.64646E-19 -19.1895 0.80125E+00 -0.0962 92 H3PO4,aq 0.10783E-17 -17.9672 0.10783E-17 -17.9672 0.10000E+01 0.0000 93 H2PO4- 0.28941E-10 -10.5385 0.23223E-10 -10.6341 0.80241E+00 -0.0956 94 PO4-3 0.39696E-09 -9.4013 0.68474E-10 -10.1645 0.17250E+00 -0.7632 98 HP2O7-3 0.43031E-18 -18.3662 0.68982E-19 -19.1613 0.16031E+00 -0.7950 99 P2O7-4 0.32984E-17 -17.4817 0.13455E-18 -18.8711 0.40794E-01 -1.3894 100 H2S,aq 0.35805E-05 -5.4461 0.35805E-05 -5.4461 0.10000E+01 0.0000 101 S2-2 0.54750E-09 -9.2616 0.24141E-09 -9.6172 0.44093E+00 -0.3556 102 S3-2 0.32158E-15 -15.4927 0.14180E-15 -15.8483 0.44093E+00 -0.3556 107 SO3-2 0.84612E-15 -15.0726 0.38135E-15 -15.4187 0.45070E+00 -0.3461 108 HSO3- 0.36497E-17 -17.4377 0.29243E-17 -17.5340 0.80125E+00 -0.0962 109 HSO4- 0.52374E-16 -16.2809 0.42151E-16 -16.3752 0.80480E+00 -0.0943 111 S2O3-2 0.34084E-16 -16.4674 0.15029E-16 -16.8231 0.44093E+00 -0.3556 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1514523E-09 -.1712887E-01 -.1721471E+02 0.0000 2 H2O 0.1000000E+01 0.5553661E+02 0.9976017E+06 0.0000 3 Cl- 0.3109198E-02 0.3130939E-02 0.1106787E+03 7.3084 4 SO4-- 0.8072930E-09 -.3149578E-01 -.3016744E+04 10.3767 5 HCO3- 0.1525105E-02 0.3500195E-01 0.2129516E+04 7.0000 6 HS- 0.1180294E-01 0.4330230E-01 0.1427933E+04 7.8878 7 Al+++ 0.6000937E-28 0.3199359E-05 0.8607270E-01 0.7182 8 H4SiO4 0.7159663E-03 0.9857417E-02 0.9446967E+03 -3.1451 9 Ca++ 0.3906532E-06 0.2419460E-05 0.9668538E-01 13.0565 10 Mg++ 0.6867819E-10 0.2770768E-09 0.6716717E-05 9.2985 11 Fe++ 0.1831563E-12 0.2252331E-07 0.1254204E-02 6.7252 12 K+ 0.2586943E-03 0.2594279E-03 0.1011467E+02 6.2296 13 Na+ 0.3286031E-01 0.3529937E-01 0.8091674E+03 8.3323 14 Mn++ 0.6035549E-10 0.2825549E-08 0.1547790E-03 9.2437 15 F- 0.7274373E-06 0.7310201E-06 0.1384757E-01 3.6762 16 HPO4-- 0.2323077E-07 0.2365667E-07 0.2263947E-02 11.8359 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276660E+02 -.8532954E-02 -.8275807E+02 0.0000000E+00 2 H2O -.6971490E+01 0.2766624E+02 -.3463773E+02 0.0000000E+00 3 Cl- 0.1559715E-02 0.1559715E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1397432E+00 -.1569000E-01 0.1554333E+00 0.0000000E+00 5 HCO3- 0.1743665E-01 0.1743665E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1338617E+00 0.2157156E-01 -.1554333E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1593800E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4910592E-02 0.5205899E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1205283E-05 0.5750725E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1380291E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1122026E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1292371E-03 0.1061442E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1758481E-01 0.6258792E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1407582E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9649600E-04 0.3641665E-06 0.9613183E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1178486E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: 0.1568E-14 Mass of aqueous solution: 0.499614E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2409900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.97 628.6 andradite 0.6217 -0.206 316.0 2.500 5.781 82.09 grossular 0.1236 -0.908 55.67 1.746 1.019 15.49 apatite-OH 0.9766E-02 -2.010 4.906 0.691 0.8977E-01 1.559 apatite-F 0.9613E-04 -4.017 0.4848E-01 -1.314 0.8871E-03 0.1515E-01 clinochlore 0.7139 -0.146 396.8 2.599 7.261 150.9 daphnite 0.2001 -0.699 142.8 2.155 2.612 43.26 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9431 -0.025 262.5 2.419 4.803 102.5 stilbite 3.245 0.511 2287. 3.359 41.85 1067. stilpnomelane-Fe 0.2367 -0.626 255.2 2.407 4.670 88.15 tr.625ac.25prg.125 0.1100 -0.959 94.00 1.973 1.720 30.25 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8342E+00 0.8342E+00 1.0000 -0.079 grossular 0.1658E+00 0.1658E+00 1.0000 -0.780 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7665E+00 0.7665E+00 1.0000 -0.115 daphnite 0.2148E+00 0.2148E+00 1.0000 -0.668 chlorite-Mn 0.1862E-01 0.1862E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5464.886981 g Volume = 2213.614593 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2409900 moles log = -0.6180 Original solution: 1000.0103000 g Original solution / Rock added: 4149.59 (Water/Rock Ratio), log = 3.6180 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 48.7942 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2244E-01 0.9181 0.1005E+01 0.1095E+01 CO2,gas 0.7631E-06 0.9215 0.3431E-04 0.3723E-04 CH4,gas 0.9773E+00 0.9721 0.4636E+02 0.4769E+02 H2,gas 0.2153E-03 1.0263 0.1078E-01 0.1051E-01 H2S,gas 0.2422E-05 0.8329 0.9843E-04 0.1182E-03 S2,gas 0.6410E-25 1.0000 0.3128E-23 0.3128E-23 CO,gas 0.2022E-11 1.0000 0.9865E-10 0.9865E-10 SO3,gas 0.4153E-46 1.0000 0.2027E-44 0.2027E-44 SO2,gas 0.1743E-25 1.0000 0.8506E-24 0.8506E-24 HF,gas 0.2451E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.2022E-17 1.0000 0.9866E-16 0.9866E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28970E+04 0.002 2 CO2,gas -6.66 -12.82 -6.16 -2.055 0.10524E+05 -4.465 3 CH4,gas 4.54 4.51 -0.03 -0.008 0.56105E+02 1.666 4 H2,gas 8.00 4.33 -3.67 -2.095 0.62600E+04 -1.967 5 H2S,gas -6.23 -11.94 -5.71 -2.853 0.97426E+04 -4.007 6 S2,gas -7.34 -32.54 -25.20 -3.877 0.43035E+05 -23.505 7 CO,gas 3.21 -8.49 -11.70 -3.601 0.19986E+05 -10.006 8 SO3,gas 17.12 -29.27 -46.39 -11.598 0.79213E+05 -44.693 9 SO2,gas 0.83 -24.94 -25.77 -6.872 0.44000E+05 -24.070 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.52 -17.70 -8.852 0.30231E+05 -16.006 12 acmite 7.71 6.60 -1.11 -0.115 0.18931E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80681E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95851E+03 26 ankerite -2.14 -5.87 -3.73 -0.622 0.63705E+04 27 annite 20.12 17.69 -2.44 -0.135 0.41579E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28285E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.76966E+04 38 aragonite 0.97 0.23 -0.73 -0.245 0.12531E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55844E+04 40 calcite 0.81 0.23 -0.58 -0.193 0.98889E+03 41 carnegieite-low 9.02 5.91 -3.12 -0.445 0.53238E+04 42 carnegieite-high 10.09 5.91 -4.19 -0.598 0.71508E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70653E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82670E+04 45 celadonite 5.34 3.67 -1.67 -0.099 0.28595E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47517E+04 47 chrysotile 23.89 21.61 -2.29 -0.191 0.39055E+04 52 chlorite-Al-free 47.17 43.21 -3.96 -0.165 0.67662E+04 54 chloritoid-Fe 9.17 5.02 -4.16 -0.277 0.70993E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66025E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13123E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99764E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.16 -0.359 0.36813E+04 69 diamond -3.10 -4.16 -1.05 -0.301 0.17993E+04 70 diopside 16.18 16.07 -0.12 -0.012 0.19812E+03 71 hedenbergite 14.21 13.49 -0.72 -0.072 0.12229E+04 72 dolomite,ordered 0.55 -3.29 -3.84 -0.640 0.65553E+04 74 enstatite 17.26 12.31 -4.96 -0.496 0.84650E+04 76 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82966E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34107E+04 79 clinozoisite 22.81 18.83 -3.97 -0.181 0.67853E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56826E+04 81 fayalite 14.05 10.31 -3.74 -0.534 0.63865E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68106E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57402E+04 87 glaucophane 22.97 20.84 -2.14 -0.058 0.36492E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70997E+04 89 graphite -3.55 -4.16 -0.61 -0.174 0.10416E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38490E+04 93 hematite 12.57 9.12 -3.45 -0.418 0.58907E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24836E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64562E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60125E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16578E+04 105 lawsonite 9.62 8.20 -1.41 -0.094 0.24141E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59091E+04 108 lizardite 23.24 21.61 -1.64 -0.137 0.27981E+04 109 magnesite 0.69 -3.53 -4.22 -1.405 0.71987E+04 110 magnetite 20.09 15.84 -4.25 -0.347 0.72502E+04 111 minnesotaite 10.39 7.60 -2.79 -0.164 0.47670E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82209E+04 123 muscovite 2.58 -1.05 -3.63 -0.214 0.62041E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54432E+04 125 nepheline 8.34 5.91 -2.43 -0.348 0.41561E+04 131 periclase-Fe 11.63 6.72 -4.90 -1.225 0.83693E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36473E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21475E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92786E+03 141 pumpellyite-Fe 46.27 43.67 -2.60 -0.058 0.44371E+04 142 pumpellyite-Mg 48.99 46.24 -2.75 -0.061 0.46969E+04 145 pyrite -21.25 -21.48 -0.23 -0.055 0.39875E+03 146 pyrrhotite -4.26 -5.21 -0.95 -0.317 0.16230E+04 147 pyrrhotiteFe0.875 -6.02 -6.59 -0.57 -0.210 0.97654E+03 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22195E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84814E+04 150 quartz -2.99 -3.14 -0.16 -0.052 0.26497E+03 154 rhodochrosite -0.98 -3.58 -2.60 -0.868 0.44461E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22997E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.10 -3.49 -1.164 0.59600E+04 168 stilpnomelane-Mg 27.44 25.88 -1.56 -0.047 0.26604E+04 174 talc 16.49 15.32 -1.17 -0.069 0.20062E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46845E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88494E+03 182 tremolite 47.87 47.45 -0.42 -0.011 0.72142E+03 183 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66113E+04 184 troilite-low -4.41 -5.21 -0.80 -0.267 0.13658E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34789E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27278E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.93821E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18580E+04 194 zoisite 22.85 18.83 -4.02 -0.183 0.68594E+04 195 akaganeite 7.75 4.56 -3.20 -0.691 0.54581E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58426E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66019E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68624E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73377E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60173E+04 208 nontronite-Ca 3.21 -0.03 -3.25 -0.211 0.55460E+04 209 nontronite-H 2.53 -2.19 -4.72 -0.316 0.80603E+04 210 nontronite-K 3.34 -0.13 -3.47 -0.223 0.59297E+04 211 nontronite-Mg 3.07 -0.65 -3.73 -0.242 0.63659E+04 212 nontronite-Na 3.52 0.56 -2.96 -0.190 0.50506E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35722E+04 234 alabandite -0.98 -2.69 -1.71 -0.572 0.29275E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62982E+04 238 dolomite,disordered 1.25 -3.29 -4.54 -0.757 0.77522E+04 239 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52703E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17984E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11685E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15075E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18562E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.2409900 MOLES New total amount of reactant added: 0.2419900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8661E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2419900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4982E+00 Moles total = -.6971E+01 kg total = -.1256E+00 Activity = 0.9994 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3521453E-01 Chg. balance for total moles = -.8661E-10 Max. difference allowed = 0.1566E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15192E-09 -9.8184 0.12282E-09 -9.9107 0.80847E+00 -0.0923 2 H2O 0.99943E+00 -0.0002 0.99943E+00 -0.0002 3 Cl- 0.31209E-02 -2.5057 0.25000E-02 -2.6021 0.80104E+00 -0.0963 4 SO4-- 0.81881E-09 -9.0868 0.36185E-09 -9.4415 0.44193E+00 -0.3547 5 HCO3- 0.15448E-02 -2.8111 0.12403E-02 -2.9065 0.80284E+00 -0.0954 6 HS- 0.11852E-01 -1.9262 0.94959E-02 -2.0225 0.80122E+00 -0.0962 7 Al+++ 0.60638E-28 -28.2173 0.96800E-29 -29.0141 0.15964E+00 -0.7969 8 H4SiO4 0.71615E-03 -3.1450 0.71615E-03 -3.1450 0.10000E+01 0.0000 9 Ca++ 0.39292E-06 -6.4057 0.17167E-06 -6.7653 0.43691E+00 -0.3596 10 Mg++ 0.69150E-10 -10.1602 0.30000E-10 -10.5229 0.43384E+00 -0.3627 11 Fe++ 0.18436E-12 -12.7343 0.80117E-13 -13.0963 0.43457E+00 -0.3619 12 K+ 0.25941E-03 -3.5860 0.20834E-03 -3.6812 0.80311E+00 -0.0952 13 Na+ 0.32951E-01 -1.4821 0.26387E-01 -1.5786 0.80079E+00 -0.0965 14 Mn++ 0.60760E-10 -10.2164 0.26438E-10 -10.5778 0.43512E+00 -0.3614 15 F- 0.72555E-06 -6.1393 0.57939E-06 -6.2370 0.79855E+00 -0.0977 16 HPO4-- 0.23158E-07 -7.6353 0.10236E-07 -7.9899 0.44202E+00 -0.3546 18 HSiO3- 0.68004E-02 -2.1675 0.54475E-02 -2.2638 0.80104E+00 -0.0963 19 Ca(HSiO3)+ 0.26510E-07 -7.5766 0.21297E-07 -7.6717 0.80338E+00 -0.0951 20 Mg(HSiO3)+ 0.57654E-11 -11.2392 0.46318E-11 -11.3342 0.80338E+00 -0.0951 21 NaHSiO3,aq 0.23248E-02 -2.6336 0.23248E-02 -2.6336 0.10000E+01 0.0000 22 AlO+ 0.10860E-15 -15.9642 0.87244E-16 -16.0593 0.80338E+00 -0.0951 24 HAlO2,aq 0.14138E-09 -9.8496 0.14138E-09 -9.8496 0.10000E+01 0.0000 25 AlO2- 0.31895E-05 -5.4963 0.25479E-05 -5.5938 0.79885E+00 -0.0975 26 CH4,aq 0.31598E-01 -1.5003 0.31598E-01 -1.5003 0.10000E+01 0.0000 27 C2H6,aq 0.20847E-07 -7.6810 0.20847E-07 -7.6810 0.10000E+01 0.0000 28 C3H8,aq 0.31753E-12 -12.4982 0.31753E-12 -12.4982 0.10000E+01 0.0000 29 C4H10,aq 0.47513E-17 -17.3232 0.47513E-17 -17.3232 0.10000E+01 0.0000 30 ethanol,aq 0.10818E-14 -14.9659 0.10818E-14 -14.9659 0.10000E+01 0.0000 31 CO,aq 0.67027E-13 -13.1738 0.67027E-13 -13.1738 0.10000E+01 0.0000 32 CO2,aq 0.32569E-06 -6.4872 0.32569E-06 -6.4872 0.10000E+01 0.0000 33 CO3-2 0.20023E-02 -2.6985 0.88200E-03 -3.0545 0.44049E+00 -0.3561 34 CaCO3,aq 0.18986E-05 -5.7216 0.18986E-05 -5.7216 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.67650E-08 -8.1697 0.54349E-08 -8.2648 0.80338E+00 -0.0951 36 CaCl+ 0.86453E-09 -9.0632 0.69455E-09 -9.1583 0.80338E+00 -0.0951 37 CaCl2,aq 0.41252E-12 -12.3846 0.41252E-12 -12.3846 0.10000E+01 0.0000 38 CaF+ 0.18076E-11 -11.7429 0.14522E-11 -11.8380 0.80338E+00 -0.0951 39 CaOH+ 0.12392E-06 -6.9069 0.99556E-07 -7.0019 0.80338E+00 -0.0951 40 CaSO4,aq 0.19726E-13 -13.7050 0.19726E-13 -13.7050 0.10000E+01 0.0000 41 HCl,aq 0.56268E-13 -13.2497 0.56268E-13 -13.2497 0.10000E+01 0.0000 45 HF,aq 0.48716E-12 -12.3123 0.48716E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.11897E-18 -18.9246 0.95297E-19 -19.0209 0.80104E+00 -0.0963 48 FeCl+ 0.39462E-15 -15.4038 0.31703E-15 -15.4989 0.80338E+00 -0.0951 51 FeF+ 0.29526E-17 -17.5298 0.23721E-17 -17.6249 0.80338E+00 -0.0951 53 FeO,aq 0.20629E-09 -9.6855 0.20629E-09 -9.6855 0.10000E+01 0.0000 54 FeOH+ 0.26414E-10 -10.5782 0.21221E-10 -10.6732 0.80338E+00 -0.0951 55 HFeO2- 0.21925E-07 -7.6591 0.17563E-07 -7.7554 0.80104E+00 -0.0963 56 FeO+ 0.22018E-16 -16.6572 0.17689E-16 -16.7523 0.80338E+00 -0.0951 58 FeO2- 0.29935E-09 -9.5238 0.23979E-09 -9.6202 0.80104E+00 -0.0963 59 HFeO2,aq 0.37459E-11 -11.4264 0.37459E-11 -11.4264 0.10000E+01 0.0000 60 H2,aq 0.81878E-05 -5.0868 0.81878E-05 -5.0868 0.10000E+01 0.0000 61 KCl,aq 0.94398E-08 -8.0250 0.94398E-08 -8.0250 0.10000E+01 0.0000 63 KOH,aq 0.72396E-06 -6.1403 0.72396E-06 -6.1403 0.10000E+01 0.0000 64 KSO4- 0.14604E-11 -11.8355 0.11698E-11 -11.9319 0.80104E+00 -0.0963 65 MgCO3,aq 0.83163E-10 -10.0801 0.83163E-10 -10.0801 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12080E-11 -11.9179 0.97048E-12 -12.0130 0.80338E+00 -0.0951 67 MgCl+ 0.13693E-12 -12.8635 0.11001E-12 -12.9586 0.80338E+00 -0.0951 68 MgF+ 0.11701E-14 -14.9318 0.94006E-15 -15.0268 0.80338E+00 -0.0951 69 MgOH+ 0.11983E-09 -9.9214 0.96271E-10 -10.0165 0.80338E+00 -0.0951 71 MnF+ 0.32115E-15 -15.4933 0.25801E-15 -15.5884 0.80338E+00 -0.0951 72 MnO,aq 0.18139E-08 -8.7414 0.18139E-08 -8.7414 0.10000E+01 0.0000 73 MnOH+ 0.80973E-09 -9.0917 0.65052E-09 -9.1867 0.80338E+00 -0.0951 74 MnO2-2 0.90536E-11 -11.0432 0.39880E-11 -11.3992 0.44049E+00 -0.3561 75 HMnO2- 0.13397E-09 -9.8730 0.10731E-09 -9.9693 0.80104E+00 -0.0963 78 MnCl+ 0.50662E-12 -12.2953 0.40701E-12 -12.3904 0.80338E+00 -0.0951 79 MnSO4,aq 0.27618E-17 -17.5588 0.27618E-17 -17.5588 0.10000E+01 0.0000 80 NaCl,aq 0.21862E-04 -4.6603 0.21862E-04 -4.6603 0.10000E+01 0.0000 81 NaF,aq 0.35793E-08 -8.4462 0.35793E-08 -8.4462 0.10000E+01 0.0000 82 NaOH,aq 0.92251E-04 -4.0350 0.92251E-04 -4.0350 0.10000E+01 0.0000 84 OH- 0.58852E-02 -2.2302 0.47014E-02 -2.3278 0.79885E+00 -0.0975 89 HPO3-2 0.59328E-15 -15.2267 0.26133E-15 -15.5828 0.44049E+00 -0.3561 91 H2PO3- 0.80354E-19 -19.0950 0.64367E-19 -19.1913 0.80104E+00 -0.0963 92 H3PO4,aq 0.10800E-17 -17.9666 0.10800E-17 -17.9666 0.10000E+01 0.0000 93 H2PO4- 0.28911E-10 -10.5389 0.23193E-10 -10.6346 0.80221E+00 -0.0957 94 PO4-3 0.39502E-09 -9.4034 0.67996E-10 -10.1675 0.17213E+00 -0.7641 98 HP2O7-3 0.42895E-18 -18.3676 0.68608E-19 -19.1636 0.15994E+00 -0.7960 99 P2O7-4 0.32841E-17 -17.4836 0.13344E-18 -18.8747 0.40633E-01 -1.3911 100 H2S,aq 0.36047E-05 -5.4431 0.36047E-05 -5.4431 0.10000E+01 0.0000 101 S2-2 0.55399E-09 -9.2565 0.24403E-09 -9.6126 0.44049E+00 -0.3561 102 S3-2 0.32859E-15 -15.4833 0.14474E-15 -15.8394 0.44049E+00 -0.3561 107 SO3-2 0.85555E-15 -15.0678 0.38523E-15 -15.4143 0.45027E+00 -0.3465 108 HSO3- 0.36984E-17 -17.4320 0.29625E-17 -17.5283 0.80104E+00 -0.0963 109 HSO4- 0.53233E-16 -16.2738 0.42832E-16 -16.3682 0.80461E+00 -0.0944 111 S2O3-2 0.34804E-16 -16.4584 0.15331E-16 -16.8144 0.44049E+00 -0.3561 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1519214E-09 -.1711873E-01 -.1720440E+02 0.0000 2 H2O 0.1000000E+01 0.5553672E+02 0.9975967E+06 0.0000 3 Cl- 0.3120939E-02 0.3142812E-02 0.1110976E+03 7.3087 4 SO4-- 0.8188065E-09 -.3160008E-01 -.3026714E+04 10.3800 5 HCO3- 0.1544826E-02 0.3514741E-01 0.2138351E+04 7.0042 6 HS- 0.1185180E-01 0.4345549E-01 0.1432975E+04 7.8883 7 Al+++ 0.6063804E-28 0.3189642E-05 0.8581069E-01 0.7180 8 H4SiO4 0.7161523E-03 0.9841466E-02 0.9431616E+03 -3.1450 9 Ca++ 0.3929248E-06 0.2449546E-05 0.9788701E-01 13.0561 10 Mg++ 0.6914994E-10 0.2792554E-09 0.6769484E-05 9.2986 11 Fe++ 0.1843594E-12 0.2246122E-07 0.1250738E-02 6.7252 12 K+ 0.2594099E-03 0.2601433E-03 0.1014250E+02 6.2295 13 Na+ 0.3295144E-01 0.3539040E-01 0.8112486E+03 8.3321 14 Mn++ 0.6076008E-10 0.2827883E-08 0.1549058E-03 9.2437 15 F- 0.7255498E-06 0.7291314E-06 0.1381170E-01 3.6737 16 HPO4-- 0.2315767E-07 0.2358160E-07 0.2256747E-02 11.8316 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276649E+02 -.8527825E-02 -.8275796E+02 0.0000000E+00 2 H2O -.6970672E+01 0.2766603E+02 -.3463670E+02 0.0000000E+00 3 Cl- 0.1565615E-02 0.1565615E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1397480E+00 -.1574182E-01 0.1554898E+00 0.0000000E+00 5 HCO3- 0.1750895E-01 0.1750895E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1338422E+00 0.2164768E-01 -.1554898E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1588944E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4902600E-02 0.5205900E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1220260E-05 0.5750725E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1391132E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1118922E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1295923E-03 0.1061441E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1762999E-01 0.6258747E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1408731E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9689600E-04 0.3632223E-06 0.9653278E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1174735E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: 0.1388E-14 Mass of aqueous solution: 0.499613E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2419900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.97 628.6 andradite 0.6220 -0.206 316.1 2.500 5.784 82.12 grossular 0.1234 -0.909 55.59 1.745 1.017 15.47 apatite-OH 0.9766E-02 -2.010 4.906 0.691 0.8977E-01 1.559 apatite-F 0.9653E-04 -4.015 0.4868E-01 -1.313 0.8908E-03 0.1521E-01 clinochlore 0.7140 -0.146 396.9 2.599 7.262 151.0 daphnite 0.2001 -0.699 142.8 2.155 2.612 43.26 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9431 -0.025 262.5 2.419 4.803 102.5 stilbite 3.246 0.511 2287. 3.359 41.85 1067. stilpnomelane-Fe 0.2367 -0.626 255.2 2.407 4.669 88.14 tr.625ac.25prg.125 0.1098 -0.959 93.87 1.973 1.718 30.21 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8344E+00 0.8344E+00 1.0000 -0.079 grossular 0.1656E+00 0.1656E+00 1.0000 -0.781 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7666E+00 0.7666E+00 1.0000 -0.115 daphnite 0.2148E+00 0.2148E+00 1.0000 -0.668 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5464.908805 g Volume = 2213.636051 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2419900 moles log = -0.6162 Original solution: 1000.0103000 g Original solution / Rock added: 4132.44 (Water/Rock Ratio), log = 3.6162 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 48.9566 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2237E-01 0.9179 0.1005E+01 0.1095E+01 CO2,gas 0.7726E-06 0.9212 0.3484E-04 0.3782E-04 CH4,gas 0.9774E+00 0.9720 0.4651E+02 0.4785E+02 H2,gas 0.2139E-03 1.0264 0.1075E-01 0.1047E-01 H2S,gas 0.2432E-05 0.8324 0.9909E-04 0.1190E-03 S2,gas 0.6515E-25 1.0000 0.3190E-23 0.3190E-23 CO,gas 0.2040E-11 1.0000 0.9988E-10 0.9988E-10 SO3,gas 0.4218E-46 1.0000 0.2065E-44 0.2065E-44 SO2,gas 0.1765E-25 1.0000 0.8642E-24 0.8642E-24 HF,gas 0.2443E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.2028E-17 1.0000 0.9929E-16 0.9929E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.36397E-10 24 grossular 32.73 32.73 0.00 0.000 -0.48529E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28970E+04 0.002 2 CO2,gas -6.66 -12.82 -6.16 -2.052 0.10513E+05 -4.458 3 CH4,gas 4.54 4.51 -0.03 -0.008 0.53653E+02 1.668 4 H2,gas 8.00 4.33 -3.67 -2.096 0.62623E+04 -1.969 5 H2S,gas -6.23 -11.93 -5.70 -2.851 0.97376E+04 -4.004 6 S2,gas -7.34 -32.53 -25.20 -3.876 0.43020E+05 -23.496 7 CO,gas 3.21 -8.48 -11.70 -3.600 0.19977E+05 -10.001 8 SO3,gas 17.12 -29.26 -46.38 -11.596 0.79199E+05 -44.685 9 SO2,gas 0.83 -24.93 -25.76 -6.870 0.43989E+05 -24.063 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.51 -17.70 -8.851 0.30226E+05 -16.003 12 acmite 7.71 6.60 -1.11 -0.115 0.18919E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80683E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95870E+03 26 ankerite -2.14 -5.85 -3.72 -0.620 0.63485E+04 27 annite 20.12 17.69 -2.44 -0.135 0.41584E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28283E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.76975E+04 38 aragonite 0.97 0.24 -0.73 -0.243 0.12424E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55843E+04 40 calcite 0.81 0.24 -0.57 -0.191 0.97813E+03 41 carnegieite-low 9.02 5.91 -3.12 -0.445 0.53242E+04 42 carnegieite-high 10.09 5.91 -4.19 -0.598 0.71512E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70655E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82675E+04 45 celadonite 5.34 3.67 -1.67 -0.099 0.28592E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47517E+04 47 chrysotile 23.89 21.61 -2.29 -0.191 0.39049E+04 52 chlorite-Al-free 47.17 43.21 -3.96 -0.165 0.67650E+04 54 chloritoid-Fe 9.17 5.02 -4.16 -0.277 0.70999E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66030E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13121E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99744E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.16 -0.359 0.36816E+04 69 diamond -3.10 -4.15 -1.05 -0.300 0.17923E+04 70 diopside 16.18 16.07 -0.12 -0.012 0.19836E+03 71 hedenbergite 14.21 13.49 -0.72 -0.072 0.12234E+04 72 dolomite,ordered 0.55 -3.28 -3.83 -0.638 0.65330E+04 74 enstatite 17.26 12.31 -4.96 -0.496 0.84644E+04 76 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82960E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34112E+04 79 clinozoisite 22.81 18.83 -3.97 -0.181 0.67871E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56818E+04 81 fayalite 14.05 10.31 -3.74 -0.534 0.63867E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68105E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57406E+04 87 glaucophane 22.97 20.84 -2.14 -0.058 0.36486E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70998E+04 89 graphite -3.55 -4.15 -0.61 -0.173 0.10346E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38491E+04 93 hematite 12.57 9.12 -3.45 -0.418 0.58887E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24838E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64566E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60127E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16583E+04 105 lawsonite 9.62 8.20 -1.41 -0.094 0.24150E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59093E+04 108 lizardite 23.24 21.61 -1.64 -0.137 0.27976E+04 109 magnesite 0.69 -3.52 -4.21 -1.403 0.71872E+04 110 magnetite 20.09 15.84 -4.25 -0.347 0.72484E+04 111 minnesotaite 10.39 7.60 -2.79 -0.164 0.47666E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82210E+04 123 muscovite 2.58 -1.05 -3.63 -0.214 0.62047E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54438E+04 125 nepheline 8.34 5.91 -2.43 -0.348 0.41565E+04 131 periclase-Fe 11.63 6.72 -4.90 -1.225 0.83695E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36471E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21490E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92803E+03 141 pumpellyite-Fe 46.27 43.67 -2.60 -0.058 0.44405E+04 142 pumpellyite-Mg 48.99 46.24 -2.75 -0.061 0.47001E+04 145 pyrite -21.25 -21.47 -0.23 -0.053 0.38666E+03 146 pyrrhotite -4.26 -5.21 -0.95 -0.316 0.16182E+04 147 pyrrhotiteFe0.875 -6.02 -6.59 -0.57 -0.209 0.97139E+03 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22193E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84813E+04 150 quartz -2.99 -3.14 -0.16 -0.052 0.26477E+03 154 rhodochrosite -0.98 -3.57 -2.60 -0.866 0.44347E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22996E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.09 -3.48 -1.161 0.59487E+04 168 stilpnomelane-Mg 27.44 25.88 -1.56 -0.046 0.26593E+04 174 talc 16.49 15.32 -1.17 -0.069 0.20053E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46844E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88475E+03 182 tremolite 47.87 47.45 -0.42 -0.011 0.72093E+03 183 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66119E+04 184 troilite-low -4.41 -5.21 -0.80 -0.266 0.13610E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34795E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27283E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.93872E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18585E+04 194 zoisite 22.85 18.83 -4.02 -0.183 0.68612E+04 195 akaganeite 7.75 4.56 -3.20 -0.691 0.54571E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58407E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66018E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68622E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73374E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60171E+04 208 nontronite-Ca 3.21 -0.03 -3.25 -0.211 0.55436E+04 209 nontronite-H 2.53 -2.19 -4.72 -0.316 0.80577E+04 210 nontronite-K 3.34 -0.13 -3.47 -0.223 0.59273E+04 211 nontronite-Mg 3.07 -0.65 -3.73 -0.242 0.63633E+04 212 nontronite-Na 3.52 0.56 -2.96 -0.190 0.50481E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35726E+04 234 alabandite -0.98 -2.69 -1.71 -0.571 0.29226E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62985E+04 238 dolomite,disordered 1.25 -3.28 -4.53 -0.755 0.77299E+04 239 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52704E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17982E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11687E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15078E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18565E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.2419900 MOLES New total amount of reactant added: 0.2429900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2429900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4982E+00 Moles total = -.6970E+01 kg total = -.1256E+00 Activity = 0.9994 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3532837E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.1572E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15239E-09 -9.8170 0.12318E-09 -9.9095 0.80829E+00 -0.0924 2 H2O 0.99943E+00 -0.0002 0.99943E+00 -0.0002 3 Cl- 0.31327E-02 -2.5041 0.25088E-02 -2.6005 0.80084E+00 -0.0965 4 SO4-- 0.83045E-09 -9.0807 0.36663E-09 -9.4358 0.44149E+00 -0.3551 5 HCO3- 0.15647E-02 -2.8056 0.12559E-02 -2.9010 0.80264E+00 -0.0955 6 HS- 0.11901E-01 -1.9244 0.95327E-02 -2.0208 0.80102E+00 -0.0964 7 Al+++ 0.61275E-28 -28.2127 0.97592E-29 -29.0106 0.15927E+00 -0.7979 8 H4SiO4 0.71634E-03 -3.1449 0.71634E-03 -3.1449 0.10000E+01 0.0000 9 Ca++ 0.39522E-06 -6.4032 0.17249E-06 -6.7632 0.43646E+00 -0.3601 10 Mg++ 0.69626E-10 -10.1572 0.30175E-10 -10.5204 0.43339E+00 -0.3631 11 Fe++ 0.18557E-12 -12.7315 0.80561E-13 -13.0939 0.43412E+00 -0.3624 12 K+ 0.26013E-03 -3.5848 0.20886E-03 -3.6801 0.80291E+00 -0.0953 13 Na+ 0.33043E-01 -1.4809 0.26454E-01 -1.5775 0.80058E+00 -0.0966 14 Mn++ 0.61168E-10 -10.2135 0.26588E-10 -10.5753 0.43467E+00 -0.3618 15 F- 0.72366E-06 -6.1405 0.57773E-06 -6.2383 0.79834E+00 -0.0978 16 HPO4-- 0.23085E-07 -7.6367 0.10194E-07 -7.9917 0.44158E+00 -0.3550 18 HSiO3- 0.67845E-02 -2.1685 0.54333E-02 -2.2649 0.80084E+00 -0.0965 19 Ca(HSiO3)+ 0.26574E-07 -7.5755 0.21344E-07 -7.6707 0.80318E+00 -0.0952 20 Mg(HSiO3)+ 0.57854E-11 -11.2377 0.46467E-11 -11.3329 0.80318E+00 -0.0952 21 NaHSiO3,aq 0.23246E-02 -2.6336 0.23246E-02 -2.6336 0.10000E+01 0.0000 22 AlO+ 0.10889E-15 -15.9630 0.87455E-16 -16.0582 0.80318E+00 -0.0952 24 HAlO2,aq 0.14131E-09 -9.8498 0.14131E-09 -9.8498 0.10000E+01 0.0000 25 AlO2- 0.31798E-05 -5.4976 0.25395E-05 -5.5952 0.79864E+00 -0.0976 26 CH4,aq 0.31702E-01 -1.4989 0.31702E-01 -1.4989 0.10000E+01 0.0000 27 C2H6,aq 0.21048E-07 -7.6768 0.21048E-07 -7.6768 0.10000E+01 0.0000 28 C3H8,aq 0.32263E-12 -12.4913 0.32263E-12 -12.4913 0.10000E+01 0.0000 29 C4H10,aq 0.48581E-17 -17.3135 0.48581E-17 -17.3135 0.10000E+01 0.0000 30 ethanol,aq 0.10955E-14 -14.9604 0.10955E-14 -14.9604 0.10000E+01 0.0000 31 CO,aq 0.67862E-13 -13.1684 0.67862E-13 -13.1684 0.10000E+01 0.0000 32 CO2,aq 0.33075E-06 -6.4805 0.33075E-06 -6.4805 0.10000E+01 0.0000 33 CO3-2 0.20238E-02 -2.6938 0.89059E-03 -3.0503 0.44005E+00 -0.3565 34 CaCO3,aq 0.19262E-05 -5.7153 0.19262E-05 -5.7153 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.68850E-08 -8.1621 0.55299E-08 -8.2573 0.80318E+00 -0.0952 36 CaCl+ 0.87194E-09 -9.0595 0.70032E-09 -9.1547 0.80318E+00 -0.0952 37 CaCl2,aq 0.41741E-12 -12.3794 0.41741E-12 -12.3794 0.10000E+01 0.0000 38 CaF+ 0.18115E-11 -11.7420 0.14550E-11 -11.8371 0.80318E+00 -0.0952 39 CaOH+ 0.12419E-06 -6.9059 0.99747E-07 -7.0011 0.80318E+00 -0.0952 40 CaSO4,aq 0.20082E-13 -13.6972 0.20082E-13 -13.6972 0.10000E+01 0.0000 41 HCl,aq 0.56627E-13 -13.2470 0.56627E-13 -13.2470 0.10000E+01 0.0000 45 HF,aq 0.48716E-12 -12.3123 0.48716E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.11866E-18 -18.9257 0.95024E-19 -19.0222 0.80084E+00 -0.0965 48 FeCl+ 0.39830E-15 -15.3998 0.31990E-15 -15.4950 0.80318E+00 -0.0952 51 FeF+ 0.29612E-17 -17.5285 0.23784E-17 -17.6237 0.80318E+00 -0.0952 53 FeO,aq 0.20624E-09 -9.6856 0.20624E-09 -9.6856 0.10000E+01 0.0000 54 FeOH+ 0.26491E-10 -10.5769 0.21277E-10 -10.6721 0.80318E+00 -0.0952 55 HFeO2- 0.21864E-07 -7.6603 0.17509E-07 -7.7567 0.80084E+00 -0.0965 56 FeO+ 0.22116E-16 -16.6553 0.17763E-16 -16.7505 0.80318E+00 -0.0952 58 FeO2- 0.29896E-09 -9.5244 0.23942E-09 -9.6208 0.80084E+00 -0.0965 59 HFeO2,aq 0.37508E-11 -11.4259 0.37508E-11 -11.4259 0.10000E+01 0.0000 60 H2,aq 0.81630E-05 -5.0882 0.81630E-05 -5.0882 0.10000E+01 0.0000 61 KCl,aq 0.94968E-08 -8.0224 0.94968E-08 -8.0224 0.10000E+01 0.0000 63 KOH,aq 0.72371E-06 -6.1404 0.72371E-06 -6.1404 0.10000E+01 0.0000 64 KSO4- 0.14838E-11 -11.8286 0.11883E-11 -11.9251 0.80084E+00 -0.0965 65 MgCO3,aq 0.84462E-10 -10.0733 0.84462E-10 -10.0733 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12307E-11 -11.9098 0.98847E-12 -12.0050 0.80318E+00 -0.0952 67 MgCl+ 0.13825E-12 -12.8593 0.11104E-12 -12.9545 0.80318E+00 -0.0952 68 MgF+ 0.11739E-14 -14.9304 0.94284E-15 -15.0256 0.80318E+00 -0.0952 69 MgOH+ 0.12022E-09 -9.9200 0.96555E-10 -10.0152 0.80318E+00 -0.0952 71 MnF+ 0.32213E-15 -15.4920 0.25873E-15 -15.5872 0.80318E+00 -0.0952 72 MnO,aq 0.18137E-08 -8.7414 0.18137E-08 -8.7414 0.10000E+01 0.0000 73 MnOH+ 0.81220E-09 -9.0903 0.65234E-09 -9.1855 0.80318E+00 -0.0952 74 MnO2-2 0.90103E-11 -11.0453 0.39650E-11 -11.4018 0.44005E+00 -0.3565 75 HMnO2- 0.13361E-09 -9.8742 0.10700E-09 -9.9706 0.80084E+00 -0.0965 78 MnCl+ 0.51141E-12 -12.2912 0.41076E-12 -12.3864 0.80318E+00 -0.0952 79 MnSO4,aq 0.28142E-17 -17.5506 0.28142E-17 -17.5506 0.10000E+01 0.0000 80 NaCl,aq 0.21994E-04 -4.6577 0.21994E-04 -4.6577 0.10000E+01 0.0000 81 NaF,aq 0.35780E-08 -8.4464 0.35780E-08 -8.4464 0.10000E+01 0.0000 82 NaOH,aq 0.92219E-04 -4.0352 0.92219E-04 -4.0352 0.10000E+01 0.0000 84 OH- 0.58699E-02 -2.2314 0.46879E-02 -2.3290 0.79864E+00 -0.0976 89 HPO3-2 0.58962E-15 -15.2294 0.25946E-15 -15.5859 0.44005E+00 -0.3565 91 H2PO3- 0.80027E-19 -19.0968 0.64089E-19 -19.1932 0.80084E+00 -0.0965 92 H3PO4,aq 0.10817E-17 -17.9659 0.10817E-17 -17.9659 0.10000E+01 0.0000 93 H2PO4- 0.28881E-10 -10.5394 0.23163E-10 -10.6352 0.80201E+00 -0.0958 94 PO4-3 0.39309E-09 -9.4055 0.67521E-10 -10.1706 0.17177E+00 -0.7651 98 HP2O7-3 0.42760E-18 -18.3690 0.68235E-19 -19.1660 0.15958E+00 -0.7970 99 P2O7-4 0.32699E-17 -17.4855 0.13234E-18 -18.8783 0.40472E-01 -1.3928 100 H2S,aq 0.36290E-05 -5.4402 0.36290E-05 -5.4402 0.10000E+01 0.0000 101 S2-2 0.56054E-09 -9.2514 0.24667E-09 -9.6079 0.44005E+00 -0.3565 102 S3-2 0.33574E-15 -15.4740 0.14774E-15 -15.8305 0.44005E+00 -0.3565 107 SO3-2 0.86505E-15 -15.0630 0.38914E-15 -15.4099 0.44984E+00 -0.3469 108 HSO3- 0.37475E-17 -17.4263 0.30012E-17 -17.5227 0.80084E+00 -0.0965 109 HSO4- 0.54104E-16 -16.2668 0.43522E-16 -16.3613 0.80441E+00 -0.0945 111 S2O3-2 0.35538E-16 -16.4493 0.15638E-16 -16.8058 0.44005E+00 -0.3565 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1523928E-09 -.1710875E-01 -.1719425E+02 0.0000 2 H2O 0.1000000E+01 0.5553682E+02 0.9975918E+06 0.0000 3 Cl- 0.3132680E-02 0.3154684E-02 0.1115165E+03 7.3089 4 SO4-- 0.8304500E-09 -.3170408E-01 -.3036654E+04 10.3832 5 HCO3- 0.1564729E-02 0.3529287E-01 0.2147186E+04 7.0084 6 HS- 0.1190067E-01 0.4360838E-01 0.1438006E+04 7.8887 7 Al+++ 0.6127468E-28 0.3179943E-05 0.8554917E-01 0.7178 8 H4SiO4 0.7163382E-03 0.9825520E-02 0.9416270E+03 -3.1449 9 Ca++ 0.3952154E-06 0.2479977E-05 0.9910238E-01 13.0557 10 Mg++ 0.6962584E-10 0.2814590E-09 0.6822856E-05 9.2986 11 Fe++ 0.1855730E-12 0.2239921E-07 0.1247277E-02 6.7251 12 K+ 0.2601291E-03 0.2608623E-03 0.1017046E+02 6.2293 13 Na+ 0.3304303E-01 0.3548189E-01 0.8133403E+03 8.3320 14 Mn++ 0.6116819E-10 0.2830234E-08 0.1550335E-03 9.2436 15 F- 0.7236640E-06 0.7272444E-06 0.1377586E-01 3.6712 16 HPO4-- 0.2308458E-07 0.2350655E-07 0.2249549E-02 11.8273 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276638E+02 -.8522772E-02 -.8275786E+02 0.0000000E+00 2 H2O -.6969853E+01 0.2766583E+02 -.3463568E+02 0.0000000E+00 3 Cl- 0.1571515E-02 0.1571515E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1397528E+00 -.1579348E-01 0.1555463E+00 0.0000000E+00 5 HCO3- 0.1758125E-01 0.1758125E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1338226E+00 0.2172364E-01 -.1555463E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1584098E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4894612E-02 0.5205901E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1235408E-05 0.5750725E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1402096E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1115823E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1299493E-03 0.1061441E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1767541E-01 0.6258702E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1409889E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9729600E-04 0.3622789E-06 0.9693372E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1170986E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: 0.2050E-13 Mass of aqueous solution: 0.499611E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2429900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.96 628.6 andradite 0.6222 -0.206 316.2 2.500 5.786 82.15 grossular 0.1232 -0.909 55.52 1.744 1.016 15.45 apatite-OH 0.9766E-02 -2.010 4.906 0.691 0.8976E-01 1.559 apatite-F 0.9693E-04 -4.014 0.4888E-01 -1.311 0.8945E-03 0.1527E-01 clinochlore 0.7141 -0.146 396.9 2.599 7.263 151.0 daphnite 0.2000 -0.699 142.7 2.155 2.612 43.25 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9431 -0.025 262.5 2.419 4.803 102.5 stilbite 3.246 0.511 2287. 3.359 41.86 1067. stilpnomelane-Fe 0.2367 -0.626 255.1 2.407 4.669 88.13 tr.625ac.25prg.125 0.1097 -0.960 93.73 1.972 1.715 30.17 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8347E+00 0.8347E+00 1.0000 -0.078 grossular 0.1653E+00 0.1653E+00 1.0000 -0.782 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7666E+00 0.7666E+00 1.0000 -0.115 daphnite 0.2147E+00 0.2147E+00 1.0000 -0.668 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5464.930586 g Volume = 2213.657470 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2429900 moles log = -0.6144 Original solution: 1000.0103000 g Original solution / Rock added: 4115.44 (Water/Rock Ratio), log = 3.6144 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 49.1185 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2231E-01 0.9177 0.1005E+01 0.1096E+01 CO2,gas 0.7822E-06 0.9210 0.3539E-04 0.3842E-04 CH4,gas 0.9775E+00 0.9719 0.4666E+02 0.4801E+02 H2,gas 0.2126E-03 1.0265 0.1072E-01 0.1044E-01 H2S,gas 0.2441E-05 0.8319 0.9976E-04 0.1199E-03 S2,gas 0.6622E-25 1.0000 0.3252E-23 0.3252E-23 CO,gas 0.2059E-11 1.0000 0.1011E-09 0.1011E-09 SO3,gas 0.4285E-46 1.0000 0.2104E-44 0.2104E-44 SO2,gas 0.1787E-25 1.0000 0.8780E-24 0.8780E-24 HF,gas 0.2435E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.2034E-17 1.0000 0.9992E-16 0.9992E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28970E+04 0.002 2 CO2,gas -6.66 -12.81 -6.15 -2.050 0.10501E+05 -4.451 3 CH4,gas 4.54 4.51 -0.03 -0.007 0.51216E+02 1.669 4 H2,gas 8.00 4.33 -3.67 -2.097 0.62645E+04 -1.970 5 H2S,gas -6.23 -11.93 -5.70 -2.850 0.97326E+04 -4.001 6 S2,gas -7.34 -32.52 -25.19 -3.875 0.43006E+05 -23.488 7 CO,gas 3.21 -8.48 -11.69 -3.598 0.19967E+05 -9.995 8 SO3,gas 17.12 -29.25 -46.38 -11.594 0.79185E+05 -44.677 9 SO2,gas 0.83 -24.92 -25.76 -6.868 0.43977E+05 -24.057 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.51 -17.70 -8.850 0.30221E+05 -16.000 12 acmite 7.71 6.60 -1.11 -0.115 0.18908E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80685E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95890E+03 26 ankerite -2.14 -5.84 -3.71 -0.618 0.63265E+04 27 annite 20.12 17.69 -2.44 -0.135 0.41589E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28281E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.76985E+04 38 aragonite 0.97 0.25 -0.72 -0.240 0.12316E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55842E+04 40 calcite 0.81 0.25 -0.57 -0.189 0.96740E+03 41 carnegieite-low 9.02 5.90 -3.12 -0.445 0.53246E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.598 0.71516E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70657E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82679E+04 45 celadonite 5.34 3.67 -1.67 -0.098 0.28590E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47516E+04 47 chrysotile 23.89 21.61 -2.29 -0.191 0.39044E+04 52 chlorite-Al-free 47.17 43.21 -3.96 -0.165 0.67639E+04 54 chloritoid-Fe 9.17 5.02 -4.16 -0.277 0.71006E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66035E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13119E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99724E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.16 -0.359 0.36819E+04 69 diamond -3.10 -4.15 -1.05 -0.299 0.17854E+04 70 diopside 16.18 16.07 -0.12 -0.012 0.19861E+03 71 hedenbergite 14.21 13.49 -0.72 -0.072 0.12239E+04 72 dolomite,ordered 0.55 -3.27 -3.81 -0.636 0.65107E+04 74 enstatite 17.26 12.31 -4.96 -0.496 0.84639E+04 76 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82955E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34117E+04 79 clinozoisite 22.81 18.83 -3.98 -0.181 0.67889E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56810E+04 81 fayalite 14.05 10.31 -3.74 -0.534 0.63868E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68104E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57409E+04 87 glaucophane 22.97 20.84 -2.14 -0.058 0.36481E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.70999E+04 89 graphite -3.55 -4.15 -0.60 -0.172 0.10277E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38492E+04 93 hematite 12.57 9.12 -3.45 -0.418 0.58868E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24840E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64570E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60130E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16589E+04 105 lawsonite 9.62 8.20 -1.41 -0.094 0.24160E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59095E+04 108 lizardite 23.24 21.61 -1.64 -0.137 0.27970E+04 109 magnesite 0.69 -3.51 -4.20 -1.401 0.71757E+04 110 magnetite 20.09 15.84 -4.24 -0.346 0.72466E+04 111 minnesotaite 10.39 7.60 -2.79 -0.164 0.47663E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82210E+04 123 muscovite 2.58 -1.05 -3.63 -0.214 0.62054E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54445E+04 125 nepheline 8.34 5.90 -2.43 -0.348 0.41569E+04 131 periclase-Fe 11.63 6.72 -4.90 -1.225 0.83696E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36469E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21504E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92820E+03 141 pumpellyite-Fe 46.27 43.67 -2.60 -0.058 0.44439E+04 142 pumpellyite-Mg 48.99 46.24 -2.75 -0.061 0.47033E+04 145 pyrite -21.25 -21.47 -0.22 -0.052 0.37459E+03 146 pyrrhotite -4.26 -5.21 -0.94 -0.315 0.16133E+04 147 pyrrhotiteFe0.875 -6.02 -6.58 -0.57 -0.208 0.96626E+03 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22192E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84812E+04 150 quartz -2.99 -3.14 -0.15 -0.052 0.26457E+03 154 rhodochrosite -0.98 -3.57 -2.59 -0.864 0.44233E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22994E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.09 -3.48 -1.159 0.59374E+04 168 stilpnomelane-Mg 27.44 25.88 -1.56 -0.046 0.26582E+04 174 talc 16.49 15.32 -1.17 -0.069 0.20043E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46843E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88455E+03 182 tremolite 47.87 47.45 -0.42 -0.011 0.72045E+03 183 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66125E+04 184 troilite-low -4.41 -5.21 -0.79 -0.265 0.13561E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34800E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27288E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.93922E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18590E+04 194 zoisite 22.85 18.83 -4.02 -0.183 0.68630E+04 195 akaganeite 7.75 4.56 -3.20 -0.691 0.54561E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58387E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66016E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68620E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73371E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60169E+04 208 nontronite-Ca 3.21 -0.03 -3.25 -0.211 0.55412E+04 209 nontronite-H 2.53 -2.18 -4.72 -0.316 0.80552E+04 210 nontronite-K 3.34 -0.13 -3.47 -0.223 0.59248E+04 211 nontronite-Mg 3.07 -0.65 -3.73 -0.242 0.63608E+04 212 nontronite-Na 3.52 0.56 -2.96 -0.190 0.50457E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35730E+04 234 alabandite -0.98 -2.69 -1.71 -0.570 0.29177E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62989E+04 238 dolomite,disordered 1.25 -3.27 -4.51 -0.752 0.77077E+04 239 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52706E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17980E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11688E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15080E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18568E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.2429900 MOLES New total amount of reactant added: 0.2439900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8662E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2439900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4981E+00 Moles total = -.6969E+01 kg total = -.1255E+00 Activity = 0.9994 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3544280E-01 Chg. balance for total moles = -.8662E-10 Max. difference allowed = 0.1577E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15287E-09 -9.8157 0.12353E-09 -9.9082 0.80810E+00 -0.0925 2 H2O 0.99943E+00 -0.0002 0.99943E+00 -0.0002 3 Cl- 0.31444E-02 -2.5025 0.25175E-02 -2.5990 0.80063E+00 -0.0966 4 SO4-- 0.84222E-09 -9.0746 0.37146E-09 -9.4301 0.44104E+00 -0.3555 5 HCO3- 0.15848E-02 -2.8000 0.12717E-02 -2.8956 0.80244E+00 -0.0956 6 HS- 0.11950E-01 -1.9226 0.95693E-02 -2.0191 0.80081E+00 -0.0965 7 Al+++ 0.61919E-28 -28.2082 0.98393E-29 -29.0070 0.15890E+00 -0.7989 8 H4SiO4 0.71652E-03 -3.1448 0.71652E-03 -3.1448 0.10000E+01 0.0000 9 Ca++ 0.39752E-06 -6.4006 0.17332E-06 -6.7611 0.43601E+00 -0.3605 10 Mg++ 0.70106E-10 -10.1542 0.30351E-10 -10.5178 0.43294E+00 -0.3636 11 Fe++ 0.18680E-12 -12.7286 0.81008E-13 -13.0915 0.43367E+00 -0.3628 12 K+ 0.26085E-03 -3.5836 0.20939E-03 -3.6790 0.80271E+00 -0.0954 13 Na+ 0.33135E-01 -1.4797 0.26521E-01 -1.5764 0.80038E+00 -0.0967 14 Mn++ 0.61580E-10 -10.2106 0.26739E-10 -10.5729 0.43422E+00 -0.3623 15 F- 0.72178E-06 -6.1416 0.57607E-06 -6.2395 0.79813E+00 -0.0979 16 HPO4-- 0.23012E-07 -7.6381 0.10151E-07 -7.9935 0.44114E+00 -0.3554 18 HSiO3- 0.67686E-02 -2.1695 0.54191E-02 -2.2661 0.80063E+00 -0.0966 19 Ca(HSiO3)+ 0.26639E-07 -7.5745 0.21391E-07 -7.6698 0.80298E+00 -0.0953 20 Mg(HSiO3)+ 0.58055E-11 -11.2362 0.46617E-11 -11.3315 0.80298E+00 -0.0953 21 NaHSiO3,aq 0.23244E-02 -2.6337 0.23244E-02 -2.6337 0.10000E+01 0.0000 22 AlO+ 0.10918E-15 -15.9619 0.87668E-16 -16.0572 0.80298E+00 -0.0953 24 HAlO2,aq 0.14125E-09 -9.8500 0.14125E-09 -9.8500 0.10000E+01 0.0000 25 AlO2- 0.31701E-05 -5.4989 0.25311E-05 -5.5967 0.79843E+00 -0.0978 26 CH4,aq 0.31806E-01 -1.4975 0.31806E-01 -1.4975 0.10000E+01 0.0000 27 C2H6,aq 0.21250E-07 -7.6726 0.21250E-07 -7.6726 0.10000E+01 0.0000 28 C3H8,aq 0.32778E-12 -12.4844 0.32778E-12 -12.4844 0.10000E+01 0.0000 29 C4H10,aq 0.49669E-17 -17.3039 0.49669E-17 -17.3039 0.10000E+01 0.0000 30 ethanol,aq 0.11094E-14 -14.9549 0.11094E-14 -14.9549 0.10000E+01 0.0000 31 CO,aq 0.68705E-13 -13.1630 0.68705E-13 -13.1630 0.10000E+01 0.0000 32 CO2,aq 0.33587E-06 -6.4738 0.33587E-06 -6.4738 0.10000E+01 0.0000 33 CO3-2 0.20455E-02 -2.6892 0.89921E-03 -3.0461 0.43960E+00 -0.3569 34 CaCO3,aq 0.19542E-05 -5.7090 0.19542E-05 -5.7090 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.70070E-08 -8.1545 0.56264E-08 -8.2498 0.80298E+00 -0.0953 36 CaCl+ 0.87941E-09 -9.0558 0.70615E-09 -9.1511 0.80298E+00 -0.0953 37 CaCl2,aq 0.42235E-12 -12.3743 0.42235E-12 -12.3743 0.10000E+01 0.0000 38 CaF+ 0.18155E-11 -11.7410 0.14578E-11 -11.8363 0.80298E+00 -0.0953 39 CaOH+ 0.12446E-06 -6.9050 0.99940E-07 -7.0003 0.80298E+00 -0.0953 40 CaSO4,aq 0.20444E-13 -13.6894 0.20444E-13 -13.6894 0.10000E+01 0.0000 41 HCl,aq 0.56988E-13 -13.2442 0.56988E-13 -13.2442 0.10000E+01 0.0000 45 HF,aq 0.48716E-12 -12.3123 0.48716E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.11835E-18 -18.9268 0.94751E-19 -19.0234 0.80063E+00 -0.0966 48 FeCl+ 0.40200E-15 -15.3958 0.32280E-15 -15.4911 0.80298E+00 -0.0953 51 FeF+ 0.29699E-17 -17.5273 0.23847E-17 -17.6226 0.80298E+00 -0.0953 53 FeO,aq 0.20620E-09 -9.6857 0.20620E-09 -9.6857 0.10000E+01 0.0000 54 FeOH+ 0.26568E-10 -10.5756 0.21334E-10 -10.6709 0.80298E+00 -0.0953 55 HFeO2- 0.21802E-07 -7.6615 0.17455E-07 -7.7581 0.80063E+00 -0.0966 56 FeO+ 0.22214E-16 -16.6534 0.17837E-16 -16.7487 0.80298E+00 -0.0953 58 FeO2- 0.29857E-09 -9.5250 0.23904E-09 -9.6215 0.80063E+00 -0.0966 59 HFeO2,aq 0.37557E-11 -11.4253 0.37557E-11 -11.4253 0.10000E+01 0.0000 60 H2,aq 0.81383E-05 -5.0895 0.81383E-05 -5.0895 0.10000E+01 0.0000 61 KCl,aq 0.95540E-08 -8.0198 0.95540E-08 -8.0198 0.10000E+01 0.0000 63 KOH,aq 0.72346E-06 -6.1406 0.72346E-06 -6.1406 0.10000E+01 0.0000 64 KSO4- 0.15075E-11 -11.8217 0.12069E-11 -11.9183 0.80063E+00 -0.0966 65 MgCO3,aq 0.85778E-10 -10.0666 0.85778E-10 -10.0666 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12538E-11 -11.9018 0.10068E-11 -11.9971 0.80298E+00 -0.0953 67 MgCl+ 0.13957E-12 -12.8552 0.11207E-12 -12.9505 0.80298E+00 -0.0953 68 MgF+ 0.11776E-14 -14.9290 0.94563E-15 -15.0243 0.80298E+00 -0.0953 69 MgOH+ 0.12060E-09 -9.9186 0.96841E-10 -10.0139 0.80298E+00 -0.0953 71 MnF+ 0.32312E-15 -15.4906 0.25946E-15 -15.5859 0.80298E+00 -0.0953 72 MnO,aq 0.18136E-08 -8.7415 0.18136E-08 -8.7415 0.10000E+01 0.0000 73 MnOH+ 0.81468E-09 -9.0890 0.65417E-09 -9.1843 0.80298E+00 -0.0953 74 MnO2-2 0.89671E-11 -11.0473 0.39420E-11 -11.4043 0.43960E+00 -0.3569 75 HMnO2- 0.13325E-09 -9.8753 0.10668E-09 -9.9719 0.80063E+00 -0.0966 78 MnCl+ 0.51624E-12 -12.2871 0.41453E-12 -12.3824 0.80298E+00 -0.0953 79 MnSO4,aq 0.28674E-17 -17.5425 0.28674E-17 -17.5425 0.10000E+01 0.0000 80 NaCl,aq 0.22126E-04 -4.6551 0.22126E-04 -4.6551 0.10000E+01 0.0000 81 NaF,aq 0.35768E-08 -8.4465 0.35768E-08 -8.4465 0.10000E+01 0.0000 82 NaOH,aq 0.92187E-04 -4.0353 0.92187E-04 -4.0353 0.10000E+01 0.0000 84 OH- 0.58546E-02 -2.2325 0.46745E-02 -2.3303 0.79843E+00 -0.0978 89 HPO3-2 0.58599E-15 -15.2321 0.25760E-15 -15.5891 0.43960E+00 -0.3569 91 H2PO3- 0.79702E-19 -19.0985 0.63812E-19 -19.1951 0.80063E+00 -0.0966 92 H3PO4,aq 0.10834E-17 -17.9652 0.10834E-17 -17.9652 0.10000E+01 0.0000 93 H2PO4- 0.28851E-10 -10.5398 0.23133E-10 -10.6358 0.80180E+00 -0.0959 94 PO4-3 0.39116E-09 -9.4076 0.67047E-10 -10.1736 0.17141E+00 -0.7660 98 HP2O7-3 0.42624E-18 -18.3703 0.67863E-19 -19.1684 0.15921E+00 -0.7980 99 P2O7-4 0.32556E-17 -17.4874 0.13124E-18 -18.8819 0.40311E-01 -1.3946 100 H2S,aq 0.36534E-05 -5.4373 0.36534E-05 -5.4373 0.10000E+01 0.0000 101 S2-2 0.56715E-09 -9.2463 0.24932E-09 -9.6032 0.43960E+00 -0.3569 102 S3-2 0.34302E-15 -15.4647 0.15079E-15 -15.8216 0.43960E+00 -0.3569 107 SO3-2 0.87462E-15 -15.0582 0.39307E-15 -15.4055 0.44941E+00 -0.3474 108 HSO3- 0.37972E-17 -17.4205 0.30402E-17 -17.5171 0.80063E+00 -0.0966 109 HSO4- 0.54987E-16 -16.2597 0.44222E-16 -16.3544 0.80421E+00 -0.0946 111 S2O3-2 0.36284E-16 -16.4403 0.15951E-16 -16.7972 0.43960E+00 -0.3569 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1528666E-09 -.1709891E-01 -.1718425E+02 0.0000 2 H2O 0.1000000E+01 0.5553692E+02 0.9975868E+06 0.0000 3 Cl- 0.3144420E-02 0.3166557E-02 0.1119355E+03 7.3092 4 SO4-- 0.8422245E-09 -.3180776E-01 -.3046563E+04 10.3864 5 HCO3- 0.1584815E-02 0.3543833E-01 0.2156021E+04 7.0126 6 HS- 0.1194953E-01 0.4376095E-01 0.1443027E+04 7.8891 7 Al+++ 0.6191938E-28 0.3170261E-05 0.8528812E-01 0.7176 8 H4SiO4 0.7165238E-03 0.9809581E-02 0.9400930E+03 -3.1448 9 Ca++ 0.3975250E-06 0.2510755E-05 0.1003316E+00 13.0553 10 Mg++ 0.7010592E-10 0.2836858E-09 0.6876789E-05 9.2986 11 Fe++ 0.1867970E-12 0.2233729E-07 0.1243821E-02 6.7250 12 K+ 0.2608519E-03 0.2615849E-03 0.1019857E+02 6.2292 13 Na+ 0.3313508E-01 0.3557384E-01 0.8154425E+03 8.3318 14 Mn++ 0.6157987E-10 0.2832603E-08 0.1551622E-03 9.2436 15 F- 0.7217801E-06 0.7253592E-06 0.1374005E-01 3.6687 16 HPO4-- 0.2301150E-07 0.2343151E-07 0.2242353E-02 11.8230 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276628E+02 -.8517795E-02 -.8275776E+02 0.0000000E+00 2 H2O -.6969034E+01 0.2766563E+02 -.3463466E+02 0.0000000E+00 3 Cl- 0.1577415E-02 0.1577415E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1397576E+00 -.1584498E-01 0.1556026E+00 0.0000000E+00 5 HCO3- 0.1765355E-01 0.1765355E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1338031E+00 0.2179944E-01 -.1556026E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1579260E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4886626E-02 0.5205902E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1250728E-05 0.5750725E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1413176E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1112728E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1303081E-03 0.1061441E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1772105E-01 0.6258656E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1411056E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9769600E-04 0.3613365E-06 0.9733466E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1167237E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: 0.5163E-14 Mass of aqueous solution: 0.499610E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2439900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.96 628.6 andradite 0.6224 -0.206 316.3 2.500 5.788 82.18 grossular 0.1231 -0.910 55.44 1.744 1.014 15.43 apatite-OH 0.9765E-02 -2.010 4.905 0.691 0.8976E-01 1.559 apatite-F 0.9733E-04 -4.012 0.4909E-01 -1.309 0.8982E-03 0.1533E-01 clinochlore 0.7143 -0.146 397.0 2.599 7.265 151.0 daphnite 0.2000 -0.699 142.7 2.154 2.611 43.25 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9431 -0.025 262.5 2.419 4.803 102.5 stilbite 3.246 0.511 2287. 3.359 41.86 1067. stilpnomelane-Fe 0.2367 -0.626 255.1 2.407 4.668 88.12 tr.625ac.25prg.125 0.1095 -0.961 93.60 1.971 1.713 30.13 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8349E+00 0.8349E+00 1.0000 -0.078 grossular 0.1651E+00 0.1651E+00 1.0000 -0.782 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7667E+00 0.7667E+00 1.0000 -0.115 daphnite 0.2147E+00 0.2147E+00 1.0000 -0.668 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5464.952323 g Volume = 2213.678849 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2439900 moles log = -0.6126 Original solution: 1000.0103000 g Original solution / Rock added: 4098.57 (Water/Rock Ratio), log = 3.6126 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 49.2799 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2224E-01 0.9175 0.1005E+01 0.1096E+01 CO2,gas 0.7919E-06 0.9208 0.3593E-04 0.3903E-04 CH4,gas 0.9775E+00 0.9718 0.4682E+02 0.4817E+02 H2,gas 0.2112E-03 1.0266 0.1068E-01 0.1041E-01 H2S,gas 0.2451E-05 0.8315 0.1004E-03 0.1208E-03 S2,gas 0.6730E-25 1.0000 0.3316E-23 0.3316E-23 CO,gas 0.2078E-11 1.0000 0.1024E-09 0.1024E-09 SO3,gas 0.4352E-46 1.0000 0.2144E-44 0.2144E-44 SO2,gas 0.1810E-25 1.0000 0.8919E-24 0.8919E-24 HF,gas 0.2427E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.2041E-17 1.0000 0.1006E-15 0.1006E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 119 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28970E+04 0.002 2 CO2,gas -6.66 -12.80 -6.14 -2.048 0.10490E+05 -4.444 3 CH4,gas 4.54 4.52 -0.03 -0.007 0.48795E+02 1.670 4 H2,gas 8.00 4.33 -3.67 -2.097 0.62668E+04 -1.971 5 H2S,gas -6.23 -11.93 -5.70 -2.849 0.97276E+04 -3.998 6 S2,gas -7.34 -32.51 -25.18 -3.874 0.42991E+05 -23.479 7 CO,gas 3.21 -8.47 -11.69 -3.597 0.19958E+05 -9.990 8 SO3,gas 17.12 -29.25 -46.37 -11.592 0.79172E+05 -44.669 9 SO2,gas 0.83 -24.92 -25.75 -6.866 0.43965E+05 -24.050 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.51 -17.70 -8.848 0.30216E+05 -15.998 12 acmite 7.71 6.60 -1.11 -0.115 0.18897E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80688E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95910E+03 26 ankerite -2.14 -5.83 -3.69 -0.615 0.63045E+04 27 annite 20.12 17.69 -2.44 -0.135 0.41593E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28279E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.76995E+04 38 aragonite 0.97 0.25 -0.72 -0.238 0.12209E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55842E+04 40 calcite 0.81 0.25 -0.56 -0.187 0.95670E+03 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53250E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.598 0.71520E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70659E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82683E+04 45 celadonite 5.34 3.67 -1.67 -0.098 0.28587E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47516E+04 47 chrysotile 23.89 21.61 -2.29 -0.191 0.39038E+04 52 chlorite-Al-free 47.17 43.21 -3.96 -0.165 0.67627E+04 54 chloritoid-Fe 9.17 5.01 -4.16 -0.277 0.71012E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66040E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13117E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99705E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.16 -0.359 0.36823E+04 69 diamond -3.10 -4.14 -1.04 -0.298 0.17785E+04 70 diopside 16.18 16.06 -0.12 -0.012 0.19885E+03 71 hedenbergite 14.21 13.49 -0.72 -0.072 0.12243E+04 72 dolomite,ordered 0.55 -3.25 -3.80 -0.633 0.64886E+04 74 enstatite 17.26 12.31 -4.96 -0.496 0.84634E+04 76 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82950E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34122E+04 79 clinozoisite 22.81 18.83 -3.98 -0.181 0.67907E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56802E+04 81 fayalite 14.05 10.31 -3.74 -0.534 0.63869E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68103E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57412E+04 87 glaucophane 22.97 20.84 -2.14 -0.058 0.36475E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.71000E+04 89 graphite -3.55 -4.14 -0.60 -0.171 0.10207E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38493E+04 93 hematite 12.57 9.12 -3.45 -0.418 0.58848E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24842E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64574E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60133E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16595E+04 105 lawsonite 9.62 8.20 -1.42 -0.094 0.24170E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59097E+04 108 lizardite 23.24 21.61 -1.64 -0.136 0.27964E+04 109 magnesite 0.69 -3.51 -4.20 -1.399 0.71642E+04 110 magnetite 20.09 15.84 -4.24 -0.346 0.72448E+04 111 minnesotaite 10.39 7.60 -2.79 -0.164 0.47660E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82211E+04 123 muscovite 2.58 -1.05 -3.63 -0.214 0.62061E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54452E+04 125 nepheline 8.34 5.90 -2.43 -0.348 0.41573E+04 131 periclase-Fe 11.63 6.72 -4.90 -1.225 0.83698E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36467E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21519E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92837E+03 141 pumpellyite-Fe 46.27 43.66 -2.60 -0.058 0.44473E+04 142 pumpellyite-Mg 48.99 46.24 -2.76 -0.061 0.47065E+04 145 pyrite -21.25 -21.46 -0.21 -0.050 0.36254E+03 146 pyrrhotite -4.26 -5.20 -0.94 -0.314 0.16085E+04 147 pyrrhotiteFe0.875 -6.02 -6.58 -0.56 -0.207 0.96114E+03 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22190E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84810E+04 150 quartz -2.99 -3.14 -0.15 -0.052 0.26438E+03 154 rhodochrosite -0.98 -3.56 -2.58 -0.861 0.44120E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22993E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.08 -3.47 -1.157 0.59261E+04 168 stilpnomelane-Mg 27.44 25.89 -1.56 -0.046 0.26571E+04 174 talc 16.49 15.32 -1.17 -0.069 0.20033E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46842E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88436E+03 182 tremolite 47.87 47.45 -0.42 -0.011 0.71996E+03 183 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66131E+04 184 troilite-low -4.41 -5.20 -0.79 -0.264 0.13513E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34806E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27293E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.93972E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18595E+04 194 zoisite 22.85 18.83 -4.02 -0.183 0.68648E+04 195 akaganeite 7.75 4.56 -3.19 -0.691 0.54552E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58368E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66015E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68619E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73369E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60168E+04 208 nontronite-Ca 3.21 -0.03 -3.24 -0.210 0.55387E+04 209 nontronite-H 2.53 -2.18 -4.72 -0.316 0.80526E+04 210 nontronite-K 3.34 -0.13 -3.47 -0.223 0.59223E+04 211 nontronite-Mg 3.07 -0.65 -3.72 -0.242 0.63582E+04 212 nontronite-Na 3.52 0.57 -2.95 -0.190 0.50432E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35734E+04 234 alabandite -0.98 -2.68 -1.71 -0.569 0.29127E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62992E+04 238 dolomite,disordered 1.25 -3.25 -4.50 -0.750 0.76855E+04 239 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52707E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17979E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11690E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15083E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18571E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.2439900 MOLES New total amount of reactant added: 0.2449900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8663E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2449900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4981E+00 Moles total = -.6968E+01 kg total = -.1255E+00 Activity = 0.9994 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3555783E-01 Chg. balance for total moles = -.8663E-10 Max. difference allowed = 0.1583E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15334E-09 -9.8143 0.12389E-09 -9.9070 0.80790E+00 -0.0926 2 H2O 0.99943E+00 -0.0002 0.99943E+00 -0.0002 3 Cl- 0.31562E-02 -2.5008 0.25263E-02 -2.5975 0.80043E+00 -0.0967 4 SO4-- 0.85413E-09 -9.0685 0.37633E-09 -9.4244 0.44060E+00 -0.3560 5 HCO3- 0.16051E-02 -2.7945 0.12877E-02 -2.8902 0.80224E+00 -0.0957 6 HS- 0.11998E-01 -1.9209 0.96060E-02 -2.0175 0.80061E+00 -0.0966 7 Al+++ 0.62572E-28 -28.2036 0.99201E-29 -29.0035 0.15854E+00 -0.7999 8 H4SiO4 0.71671E-03 -3.1447 0.71671E-03 -3.1447 0.10000E+01 0.0000 9 Ca++ 0.39985E-06 -6.3981 0.17416E-06 -6.7591 0.43556E+00 -0.3610 10 Mg++ 0.70590E-10 -10.1513 0.30529E-10 -10.5153 0.43248E+00 -0.3640 11 Fe++ 0.18803E-12 -12.7258 0.81458E-13 -13.0891 0.43321E+00 -0.3633 12 K+ 0.26158E-03 -3.5824 0.20992E-03 -3.6779 0.80251E+00 -0.0955 13 Na+ 0.33228E-01 -1.4785 0.26588E-01 -1.5753 0.80017E+00 -0.0968 14 Mn++ 0.61995E-10 -10.2076 0.26892E-10 -10.5704 0.43377E+00 -0.3627 15 F- 0.71990E-06 -6.1427 0.57442E-06 -6.2408 0.79792E+00 -0.0980 16 HPO4-- 0.22938E-07 -7.6394 0.10109E-07 -7.9953 0.44070E+00 -0.3559 18 HSiO3- 0.67527E-02 -2.1705 0.54050E-02 -2.2672 0.80043E+00 -0.0967 19 Ca(HSiO3)+ 0.26704E-07 -7.5734 0.21438E-07 -7.6688 0.80278E+00 -0.0954 20 Mg(HSiO3)+ 0.58257E-11 -11.2347 0.46767E-11 -11.3301 0.80278E+00 -0.0954 21 NaHSiO3,aq 0.23243E-02 -2.6337 0.23243E-02 -2.6337 0.10000E+01 0.0000 22 AlO+ 0.10947E-15 -15.9607 0.87881E-16 -16.0561 0.80278E+00 -0.0954 24 HAlO2,aq 0.14119E-09 -9.8502 0.14119E-09 -9.8502 0.10000E+01 0.0000 25 AlO2- 0.31605E-05 -5.5003 0.25227E-05 -5.5981 0.79822E+00 -0.0979 26 CH4,aq 0.31909E-01 -1.4961 0.31909E-01 -1.4961 0.10000E+01 0.0000 27 C2H6,aq 0.21453E-07 -7.6685 0.21453E-07 -7.6685 0.10000E+01 0.0000 28 C3H8,aq 0.33300E-12 -12.4776 0.33300E-12 -12.4776 0.10000E+01 0.0000 29 C4H10,aq 0.50776E-17 -17.2943 0.50776E-17 -17.2943 0.10000E+01 0.0000 30 ethanol,aq 0.11234E-14 -14.9495 0.11234E-14 -14.9495 0.10000E+01 0.0000 31 CO,aq 0.69556E-13 -13.1577 0.69556E-13 -13.1577 0.10000E+01 0.0000 32 CO2,aq 0.34106E-06 -6.4672 0.34106E-06 -6.4672 0.10000E+01 0.0000 33 CO3-2 0.20673E-02 -2.6846 0.90787E-03 -3.0420 0.43916E+00 -0.3574 34 CaCO3,aq 0.19826E-05 -5.7028 0.19826E-05 -5.7028 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.71308E-08 -8.1469 0.57244E-08 -8.2423 0.80278E+00 -0.0954 36 CaCl+ 0.88694E-09 -9.0521 0.71202E-09 -9.1475 0.80278E+00 -0.0954 37 CaCl2,aq 0.42735E-12 -12.3692 0.42735E-12 -12.3692 0.10000E+01 0.0000 38 CaF+ 0.18194E-11 -11.7401 0.14606E-11 -11.8355 0.80278E+00 -0.0954 39 CaOH+ 0.12473E-06 -6.9040 0.10013E-06 -6.9994 0.80278E+00 -0.0954 40 CaSO4,aq 0.20813E-13 -13.6817 0.20813E-13 -13.6817 0.10000E+01 0.0000 41 HCl,aq 0.57351E-13 -13.2415 0.57351E-13 -13.2415 0.10000E+01 0.0000 45 HF,aq 0.48716E-12 -12.3123 0.48716E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.11804E-18 -18.9280 0.94479E-19 -19.0247 0.80043E+00 -0.0967 48 FeCl+ 0.40574E-15 -15.3917 0.32572E-15 -15.4872 0.80278E+00 -0.0954 51 FeF+ 0.29785E-17 -17.5260 0.23911E-17 -17.6214 0.80278E+00 -0.0954 53 FeO,aq 0.20616E-09 -9.6858 0.20616E-09 -9.6858 0.10000E+01 0.0000 54 FeOH+ 0.26646E-10 -10.5744 0.21391E-10 -10.6698 0.80278E+00 -0.0954 55 HFeO2- 0.21741E-07 -7.6627 0.17402E-07 -7.7594 0.80043E+00 -0.0967 56 FeO+ 0.22312E-16 -16.6515 0.17912E-16 -16.7469 0.80278E+00 -0.0954 58 FeO2- 0.29818E-09 -9.5255 0.23867E-09 -9.6222 0.80043E+00 -0.0967 59 HFeO2,aq 0.37606E-11 -11.4247 0.37606E-11 -11.4247 0.10000E+01 0.0000 60 H2,aq 0.81137E-05 -5.0908 0.81137E-05 -5.0908 0.10000E+01 0.0000 61 KCl,aq 0.96115E-08 -8.0172 0.96115E-08 -8.0172 0.10000E+01 0.0000 63 KOH,aq 0.72321E-06 -6.1407 0.72321E-06 -6.1407 0.10000E+01 0.0000 64 KSO4- 0.15315E-11 -11.8149 0.12259E-11 -11.9116 0.80043E+00 -0.0967 65 MgCO3,aq 0.87111E-10 -10.0599 0.87111E-10 -10.0599 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.12772E-11 -11.8937 0.10253E-11 -11.9891 0.80278E+00 -0.0954 67 MgCl+ 0.14091E-12 -12.8510 0.11312E-12 -12.9465 0.80278E+00 -0.0954 68 MgF+ 0.11814E-14 -14.9276 0.94843E-15 -15.0230 0.80278E+00 -0.0954 69 MgOH+ 0.12099E-09 -9.9173 0.97128E-10 -10.0127 0.80278E+00 -0.0954 71 MnF+ 0.32410E-15 -15.4893 0.26018E-15 -15.5847 0.80278E+00 -0.0954 72 MnO,aq 0.18135E-08 -8.7415 0.18135E-08 -8.7415 0.10000E+01 0.0000 73 MnOH+ 0.81717E-09 -9.0877 0.65601E-09 -9.1831 0.80278E+00 -0.0954 74 MnO2-2 0.89241E-11 -11.0494 0.39191E-11 -11.4068 0.43916E+00 -0.3574 75 HMnO2- 0.13289E-09 -9.8765 0.10637E-09 -9.9732 0.80043E+00 -0.0967 78 MnCl+ 0.52112E-12 -12.2831 0.41834E-12 -12.3785 0.80278E+00 -0.0954 79 MnSO4,aq 0.29216E-17 -17.5344 0.29216E-17 -17.5344 0.10000E+01 0.0000 80 NaCl,aq 0.22260E-04 -4.6525 0.22260E-04 -4.6525 0.10000E+01 0.0000 81 NaF,aq 0.35756E-08 -8.4467 0.35756E-08 -8.4467 0.10000E+01 0.0000 82 NaOH,aq 0.92155E-04 -4.0355 0.92155E-04 -4.0355 0.10000E+01 0.0000 84 OH- 0.58393E-02 -2.2336 0.46611E-02 -2.3315 0.79822E+00 -0.0979 89 HPO3-2 0.58237E-15 -15.2348 0.25575E-15 -15.5922 0.43916E+00 -0.3574 91 H2PO3- 0.79378E-19 -19.1003 0.63536E-19 -19.1970 0.80043E+00 -0.0967 92 H3PO4,aq 0.10851E-17 -17.9645 0.10851E-17 -17.9645 0.10000E+01 0.0000 93 H2PO4- 0.28821E-10 -10.5403 0.23103E-10 -10.6363 0.80160E+00 -0.0960 94 PO4-3 0.38924E-09 -9.4098 0.66575E-10 -10.1767 0.17104E+00 -0.7669 98 HP2O7-3 0.42488E-18 -18.3717 0.67491E-19 -19.1708 0.15885E+00 -0.7990 99 P2O7-4 0.32414E-17 -17.4893 0.13015E-18 -18.8856 0.40151E-01 -1.3963 100 H2S,aq 0.36780E-05 -5.4344 0.36780E-05 -5.4344 0.10000E+01 0.0000 101 S2-2 0.57382E-09 -9.2412 0.25200E-09 -9.5986 0.43916E+00 -0.3574 102 S3-2 0.35044E-15 -15.4554 0.15390E-15 -15.8128 0.43916E+00 -0.3574 107 SO3-2 0.88427E-15 -15.0534 0.39702E-15 -15.4012 0.44898E+00 -0.3478 108 HSO3- 0.38475E-17 -17.4148 0.30796E-17 -17.5115 0.80043E+00 -0.0967 109 HSO4- 0.55883E-16 -16.2527 0.44931E-16 -16.3475 0.80401E+00 -0.0947 111 S2O3-2 0.37045E-16 -16.4313 0.16269E-16 -16.7886 0.43916E+00 -0.3574 Charge balance for all species = -.1740E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1533427E-09 -.1708923E-01 -.1717440E+02 0.0000 2 H2O 0.1000000E+01 0.5553703E+02 0.9975818E+06 0.0000 3 Cl- 0.3156160E-02 0.3178430E-02 0.1123544E+03 7.3095 4 SO4-- 0.8541310E-09 -.3191112E-01 -.3056443E+04 10.3895 5 HCO3- 0.1605086E-02 0.3558380E-01 0.2164856E+04 7.0168 6 HS- 0.1199840E-01 0.4391320E-01 0.1448038E+04 7.8895 7 Al+++ 0.6257225E-28 0.3160598E-05 0.8502755E-01 0.7174 8 H4SiO4 0.7167092E-03 0.9793648E-02 0.9385596E+03 -3.1447 9 Ca++ 0.3998537E-06 0.2541882E-05 0.1015748E+00 13.0549 10 Mg++ 0.7059022E-10 0.2859359E-09 0.6931284E-05 9.2987 11 Fe++ 0.1880316E-12 0.2227545E-07 0.1240369E-02 6.7249 12 K+ 0.2615784E-03 0.2623112E-03 0.1022681E+02 6.2290 13 Na+ 0.3322759E-01 0.3566626E-01 0.8175553E+03 8.3317 14 Mn++ 0.6199513E-10 0.2834988E-08 0.1552918E-03 9.2436 15 F- 0.7198980E-06 0.7234759E-06 0.1370428E-01 3.6662 16 HPO4-- 0.2293845E-07 0.2335650E-07 0.2235159E-02 11.8187 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276617E+02 -.8512895E-02 -.8275766E+02 0.0000000E+00 2 H2O -.6968215E+01 0.2766543E+02 -.3463364E+02 0.0000000E+00 3 Cl- 0.1583315E-02 0.1583315E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1397623E+00 -.1589633E-01 0.1556587E+00 0.0000000E+00 5 HCO3- 0.1772585E-01 0.1772585E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1337836E+00 0.2187509E-01 -.1556587E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1574432E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4878645E-02 0.5205903E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1266223E-05 0.5750725E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1424372E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1109638E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1306687E-03 0.1061440E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1776693E-01 0.6258610E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1412232E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9809600E-04 0.3603950E-06 0.9773560E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1163490E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: 0.1471E-13 Mass of aqueous solution: 0.499609E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2449900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.96 628.6 andradite 0.6226 -0.206 316.4 2.500 5.790 82.21 grossular 0.1229 -0.910 55.36 1.743 1.013 15.40 apatite-OH 0.9765E-02 -2.010 4.905 0.691 0.8976E-01 1.559 apatite-F 0.9774E-04 -4.010 0.4929E-01 -1.307 0.9019E-03 0.1540E-01 clinochlore 0.7144 -0.146 397.1 2.599 7.266 151.0 daphnite 0.2000 -0.699 142.7 2.154 2.611 43.24 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9431 -0.025 262.5 2.419 4.803 102.5 stilbite 3.246 0.511 2288. 3.359 41.86 1067. stilpnomelane-Fe 0.2366 -0.626 255.1 2.407 4.668 88.11 tr.625ac.25prg.125 0.1094 -0.961 93.47 1.971 1.710 30.08 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8351E+00 0.8351E+00 1.0000 -0.078 grossular 0.1649E+00 0.1649E+00 1.0000 -0.783 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7667E+00 0.7667E+00 1.0000 -0.115 daphnite 0.2146E+00 0.2146E+00 1.0000 -0.668 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5464.974016 g Volume = 2213.700188 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2449900 moles log = -0.6109 Original solution: 1000.0103000 g Original solution / Rock added: 4081.84 (Water/Rock Ratio), log = 3.6109 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 49.4409 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2217E-01 0.9173 0.1005E+01 0.1096E+01 CO2,gas 0.8017E-06 0.9206 0.3649E-04 0.3964E-04 CH4,gas 0.9776E+00 0.9717 0.4697E+02 0.4833E+02 H2,gas 0.2099E-03 1.0267 0.1065E-01 0.1038E-01 H2S,gas 0.2461E-05 0.8310 0.1011E-03 0.1217E-03 S2,gas 0.6839E-25 1.0000 0.3381E-23 0.3381E-23 CO,gas 0.2096E-11 1.0000 0.1037E-09 0.1037E-09 SO3,gas 0.4420E-46 1.0000 0.2185E-44 0.2185E-44 SO2,gas 0.1833E-25 1.0000 0.9061E-24 0.9061E-24 HF,gas 0.2419E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.2047E-17 1.0000 0.1012E-15 0.1012E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.00000E+00 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28970E+04 0.002 2 CO2,gas -6.66 -12.80 -6.14 -2.046 0.10478E+05 -4.438 3 CH4,gas 4.54 4.52 -0.03 -0.007 0.46389E+02 1.672 4 H2,gas 8.00 4.33 -3.67 -2.098 0.62690E+04 -1.973 5 H2S,gas -6.23 -11.92 -5.69 -2.847 0.97227E+04 -3.995 6 S2,gas -7.34 -32.51 -25.17 -3.872 0.42977E+05 -23.471 7 CO,gas 3.21 -8.47 -11.68 -3.595 0.19949E+05 -9.984 8 SO3,gas 17.12 -29.24 -46.36 -11.590 0.79158E+05 -44.661 9 SO2,gas 0.83 -24.91 -25.74 -6.864 0.43953E+05 -24.043 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.50 -17.69 -8.847 0.30212E+05 -15.995 12 acmite 7.71 6.60 -1.11 -0.115 0.18886E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80690E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95929E+03 26 ankerite -2.14 -5.81 -3.68 -0.613 0.62826E+04 27 annite 20.12 17.69 -2.44 -0.135 0.41598E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28277E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.77004E+04 38 aragonite 0.97 0.26 -0.71 -0.236 0.12102E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55841E+04 40 calcite 0.81 0.26 -0.55 -0.185 0.94602E+03 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53253E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.598 0.71523E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70661E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82687E+04 45 celadonite 5.34 3.67 -1.67 -0.098 0.28585E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47515E+04 47 chrysotile 23.89 21.61 -2.29 -0.190 0.39032E+04 52 chlorite-Al-free 47.17 43.21 -3.96 -0.165 0.67616E+04 54 chloritoid-Fe 9.17 5.01 -4.16 -0.277 0.71018E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66045E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13115E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99686E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.16 -0.359 0.36826E+04 69 diamond -3.10 -4.14 -1.04 -0.296 0.17716E+04 70 diopside 16.18 16.06 -0.12 -0.012 0.19910E+03 71 hedenbergite 14.21 13.49 -0.72 -0.072 0.12248E+04 72 dolomite,ordered 0.55 -3.24 -3.79 -0.631 0.64665E+04 74 enstatite 17.26 12.31 -4.96 -0.496 0.84629E+04 76 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82945E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34127E+04 79 clinozoisite 22.81 18.83 -3.98 -0.181 0.67925E+04 80 epidote-Fe 29.84 26.51 -3.33 -0.173 0.56794E+04 81 fayalite 14.05 10.31 -3.74 -0.534 0.63870E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68102E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57416E+04 87 glaucophane 22.97 20.84 -2.14 -0.058 0.36469E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.71000E+04 89 graphite -3.55 -4.14 -0.59 -0.170 0.10139E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38493E+04 93 hematite 12.57 9.12 -3.45 -0.418 0.58829E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.45 -0.145 0.24844E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64578E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60135E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16601E+04 105 lawsonite 9.62 8.20 -1.42 -0.094 0.24179E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59099E+04 108 lizardite 23.24 21.61 -1.64 -0.136 0.27958E+04 109 magnesite 0.69 -3.50 -4.19 -1.396 0.71528E+04 110 magnetite 20.09 15.85 -4.24 -0.346 0.72430E+04 111 minnesotaite 10.39 7.60 -2.79 -0.164 0.47657E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82211E+04 123 muscovite 2.58 -1.05 -3.64 -0.214 0.62067E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54458E+04 125 nepheline 8.34 5.90 -2.44 -0.348 0.41577E+04 131 periclase-Fe 11.63 6.72 -4.90 -1.225 0.83699E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36465E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21534E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92855E+03 141 pumpellyite-Fe 46.27 43.66 -2.61 -0.058 0.44507E+04 142 pumpellyite-Mg 48.99 46.24 -2.76 -0.061 0.47097E+04 145 pyrite -21.25 -21.45 -0.21 -0.048 0.35052E+03 146 pyrrhotite -4.26 -5.20 -0.94 -0.313 0.16037E+04 147 pyrrhotiteFe0.875 -6.02 -6.58 -0.56 -0.206 0.95603E+03 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22189E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84809E+04 150 quartz -2.99 -3.14 -0.15 -0.052 0.26418E+03 154 rhodochrosite -0.98 -3.55 -2.58 -0.859 0.44006E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22991E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.07 -3.46 -1.155 0.59149E+04 168 stilpnomelane-Mg 27.44 25.89 -1.56 -0.046 0.26560E+04 174 talc 16.49 15.32 -1.17 -0.069 0.20023E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46841E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88416E+03 182 tremolite 47.87 47.45 -0.42 -0.011 0.71948E+03 183 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66137E+04 184 troilite-low -4.41 -5.20 -0.79 -0.263 0.13465E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34812E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27298E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.94022E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18601E+04 194 zoisite 22.85 18.83 -4.02 -0.183 0.68666E+04 195 akaganeite 7.75 4.56 -3.19 -0.691 0.54542E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58348E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66014E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68617E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73366E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60166E+04 208 nontronite-Ca 3.21 -0.03 -3.24 -0.210 0.55363E+04 209 nontronite-H 2.53 -2.18 -4.71 -0.316 0.80501E+04 210 nontronite-K 3.34 -0.13 -3.47 -0.223 0.59199E+04 211 nontronite-Mg 3.07 -0.65 -3.72 -0.241 0.63557E+04 212 nontronite-Na 3.52 0.57 -2.95 -0.189 0.50408E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35738E+04 234 alabandite -0.98 -2.68 -1.70 -0.568 0.29078E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62995E+04 238 dolomite,disordered 1.25 -3.24 -4.49 -0.748 0.76634E+04 239 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52709E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17977E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11692E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15085E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18574E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.2449900 MOLES New total amount of reactant added: 0.2459900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8664E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2459900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4981E+00 Moles total = -.6967E+01 kg total = -.1255E+00 Activity = 0.9994 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3567346E-01 Chg. balance for total moles = -.8664E-10 Max. difference allowed = 0.1589E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15382E-09 -9.8130 0.12424E-09 -9.9057 0.80771E+00 -0.0927 2 H2O 0.99942E+00 -0.0003 0.99942E+00 -0.0003 3 Cl- 0.31679E-02 -2.4992 0.25350E-02 -2.5960 0.80022E+00 -0.0968 4 SO4-- 0.86617E-09 -9.0624 0.38125E-09 -9.4188 0.44016E+00 -0.3564 5 HCO3- 0.16255E-02 -2.7890 0.13037E-02 -2.8848 0.80204E+00 -0.0958 6 HS- 0.12047E-01 -1.9191 0.96426E-02 -2.0158 0.80040E+00 -0.0967 7 Al+++ 0.63233E-28 -28.1991 0.10002E-28 -28.9999 0.15817E+00 -0.8009 8 H4SiO4 0.71689E-03 -3.1445 0.71689E-03 -3.1445 0.10000E+01 0.0000 9 Ca++ 0.40220E-06 -6.3956 0.17500E-06 -6.7570 0.43511E+00 -0.3614 10 Mg++ 0.71079E-10 -10.1483 0.30708E-10 -10.5127 0.43203E+00 -0.3645 11 Fe++ 0.18928E-12 -12.7229 0.81912E-13 -13.0867 0.43276E+00 -0.3638 12 K+ 0.26231E-03 -3.5812 0.21045E-03 -3.6768 0.80231E+00 -0.0957 13 Na+ 0.33321E-01 -1.4773 0.26655E-01 -1.5742 0.79996E+00 -0.0969 14 Mn++ 0.62414E-10 -10.2047 0.27045E-10 -10.5679 0.43332E+00 -0.3632 15 F- 0.71802E-06 -6.1439 0.57277E-06 -6.2420 0.79771E+00 -0.0982 16 HPO4-- 0.22865E-07 -7.6408 0.10067E-07 -7.9971 0.44025E+00 -0.3563 18 HSiO3- 0.67367E-02 -2.1716 0.53909E-02 -2.2683 0.80022E+00 -0.0968 19 Ca(HSiO3)+ 0.26770E-07 -7.5724 0.21485E-07 -7.6679 0.80258E+00 -0.0955 20 Mg(HSiO3)+ 0.58460E-11 -11.2331 0.46919E-11 -11.3287 0.80258E+00 -0.0955 21 NaHSiO3,aq 0.23241E-02 -2.6338 0.23241E-02 -2.6338 0.10000E+01 0.0000 22 AlO+ 0.10977E-15 -15.9595 0.88096E-16 -16.0550 0.80258E+00 -0.0955 24 HAlO2,aq 0.14113E-09 -9.8504 0.14113E-09 -9.8504 0.10000E+01 0.0000 25 AlO2- 0.31508E-05 -5.5016 0.25144E-05 -5.5996 0.79801E+00 -0.0980 26 CH4,aq 0.32012E-01 -1.4947 0.32012E-01 -1.4947 0.10000E+01 0.0000 27 C2H6,aq 0.21657E-07 -7.6644 0.21657E-07 -7.6644 0.10000E+01 0.0000 28 C3H8,aq 0.33827E-12 -12.4707 0.33827E-12 -12.4707 0.10000E+01 0.0000 29 C4H10,aq 0.51903E-17 -17.2848 0.51903E-17 -17.2848 0.10000E+01 0.0000 30 ethanol,aq 0.11375E-14 -14.9440 0.11375E-14 -14.9440 0.10000E+01 0.0000 31 CO,aq 0.70415E-13 -13.1523 0.70415E-13 -13.1523 0.10000E+01 0.0000 32 CO2,aq 0.34631E-06 -6.4605 0.34631E-06 -6.4605 0.10000E+01 0.0000 33 CO3-2 0.20892E-02 -2.6800 0.91656E-03 -3.0378 0.43871E+00 -0.3578 34 CaCO3,aq 0.20112E-05 -5.6965 0.20112E-05 -5.6965 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.72565E-08 -8.1393 0.58239E-08 -8.2348 0.80258E+00 -0.0955 36 CaCl+ 0.89454E-09 -9.0484 0.71793E-09 -9.1439 0.80258E+00 -0.0955 37 CaCl2,aq 0.43239E-12 -12.3641 0.43239E-12 -12.3641 0.10000E+01 0.0000 38 CaF+ 0.18234E-11 -11.7391 0.14634E-11 -11.8346 0.80258E+00 -0.0955 39 CaOH+ 0.12501E-06 -6.9031 0.10033E-06 -6.9986 0.80258E+00 -0.0955 40 CaSO4,aq 0.21187E-13 -13.6739 0.21187E-13 -13.6739 0.10000E+01 0.0000 41 HCl,aq 0.57715E-13 -13.2387 0.57715E-13 -13.2387 0.10000E+01 0.0000 45 HF,aq 0.48716E-12 -12.3123 0.48716E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.11773E-18 -18.9291 0.94207E-19 -19.0259 0.80022E+00 -0.0968 48 FeCl+ 0.40952E-15 -15.3877 0.32867E-15 -15.4832 0.80258E+00 -0.0955 51 FeF+ 0.29873E-17 -17.5247 0.23975E-17 -17.6202 0.80258E+00 -0.0955 53 FeO,aq 0.20612E-09 -9.6859 0.20612E-09 -9.6859 0.10000E+01 0.0000 54 FeOH+ 0.26724E-10 -10.5731 0.21448E-10 -10.6686 0.80258E+00 -0.0955 55 HFeO2- 0.21679E-07 -7.6640 0.17348E-07 -7.7607 0.80022E+00 -0.0968 56 FeO+ 0.22411E-16 -16.6495 0.17987E-16 -16.7450 0.80258E+00 -0.0955 58 FeO2- 0.29778E-09 -9.5261 0.23829E-09 -9.6229 0.80022E+00 -0.0968 59 HFeO2,aq 0.37655E-11 -11.4242 0.37655E-11 -11.4242 0.10000E+01 0.0000 60 H2,aq 0.80893E-05 -5.0921 0.80893E-05 -5.0921 0.10000E+01 0.0000 61 KCl,aq 0.96693E-08 -8.0146 0.96693E-08 -8.0146 0.10000E+01 0.0000 63 KOH,aq 0.72296E-06 -6.1409 0.72296E-06 -6.1409 0.10000E+01 0.0000 64 KSO4- 0.15559E-11 -11.8080 0.12451E-11 -11.9048 0.80022E+00 -0.0968 65 MgCO3,aq 0.88461E-10 -10.0532 0.88461E-10 -10.0532 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13011E-11 -11.8857 0.10442E-11 -11.9812 0.80258E+00 -0.0955 67 MgCl+ 0.14227E-12 -12.8469 0.11418E-12 -12.9424 0.80258E+00 -0.0955 68 MgF+ 0.11852E-14 -14.9262 0.95125E-15 -15.0217 0.80258E+00 -0.0955 69 MgOH+ 0.12138E-09 -9.9159 0.97416E-10 -10.0114 0.80258E+00 -0.0955 71 MnF+ 0.32510E-15 -15.4880 0.26092E-15 -15.5835 0.80258E+00 -0.0955 72 MnO,aq 0.18134E-08 -8.7415 0.18134E-08 -8.7415 0.10000E+01 0.0000 73 MnOH+ 0.81968E-09 -9.0864 0.65785E-09 -9.1819 0.80258E+00 -0.0955 74 MnO2-2 0.88813E-11 -11.0515 0.38963E-11 -11.4093 0.43871E+00 -0.3578 75 HMnO2- 0.13254E-09 -9.8777 0.10606E-09 -9.9745 0.80022E+00 -0.0968 78 MnCl+ 0.52604E-12 -12.2790 0.42219E-12 -12.3745 0.80258E+00 -0.0955 79 MnSO4,aq 0.29767E-17 -17.5263 0.29767E-17 -17.5263 0.10000E+01 0.0000 80 NaCl,aq 0.22393E-04 -4.6499 0.22393E-04 -4.6499 0.10000E+01 0.0000 81 NaF,aq 0.35743E-08 -8.4468 0.35743E-08 -8.4468 0.10000E+01 0.0000 82 NaOH,aq 0.92124E-04 -4.0356 0.92124E-04 -4.0356 0.10000E+01 0.0000 84 OH- 0.58241E-02 -2.2348 0.46477E-02 -2.3328 0.79801E+00 -0.0980 89 HPO3-2 0.57877E-15 -15.2375 0.25391E-15 -15.5953 0.43871E+00 -0.3578 91 H2PO3- 0.79055E-19 -19.1021 0.63262E-19 -19.1989 0.80022E+00 -0.0968 92 H3PO4,aq 0.10868E-17 -17.9638 0.10868E-17 -17.9638 0.10000E+01 0.0000 93 H2PO4- 0.28790E-10 -10.5408 0.23072E-10 -10.6369 0.80139E+00 -0.0962 94 PO4-3 0.38732E-09 -9.4119 0.66106E-10 -10.1798 0.17068E+00 -0.7678 98 HP2O7-3 0.42352E-18 -18.3731 0.67120E-19 -19.1731 0.15848E+00 -0.8000 99 P2O7-4 0.32272E-17 -17.4912 0.12906E-18 -18.8892 0.39991E-01 -1.3980 100 H2S,aq 0.37027E-05 -5.4315 0.37027E-05 -5.4315 0.10000E+01 0.0000 101 S2-2 0.58054E-09 -9.2362 0.25469E-09 -9.5940 0.43871E+00 -0.3578 102 S3-2 0.35800E-15 -15.4461 0.15706E-15 -15.8039 0.43871E+00 -0.3578 107 SO3-2 0.89400E-15 -15.0487 0.40100E-15 -15.3969 0.44855E+00 -0.3482 108 HSO3- 0.38983E-17 -17.4091 0.31195E-17 -17.5059 0.80022E+00 -0.0968 109 HSO4- 0.56791E-16 -16.2457 0.45649E-16 -16.3406 0.80381E+00 -0.0948 111 S2O3-2 0.37819E-16 -16.4223 0.16592E-16 -16.7801 0.43871E+00 -0.3578 Charge balance for all species = -.1739E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1538211E-09 -.1707970E-01 -.1716471E+02 0.0000 2 H2O 0.1000000E+01 0.5553713E+02 0.9975768E+06 0.0000 3 Cl- 0.3167899E-02 0.3190303E-02 0.1127733E+03 7.3097 4 SO4-- 0.8661706E-09 -.3201417E-01 -.3066292E+04 10.3927 5 HCO3- 0.1625540E-02 0.3572926E-01 0.2173690E+04 7.0209 6 HS- 0.1204726E-01 0.4406514E-01 0.1453038E+04 7.8899 7 Al+++ 0.6323338E-28 0.3150952E-05 0.8476748E-01 0.7173 8 H4SiO4 0.7168945E-03 0.9777721E-02 0.9370268E+03 -3.1445 9 Ca++ 0.4022019E-06 0.2573362E-05 0.1028320E+00 13.0545 10 Mg++ 0.7107877E-10 0.2882118E-09 0.6986405E-05 9.2987 11 Fe++ 0.1892768E-12 0.2221371E-07 0.1236922E-02 6.7248 12 K+ 0.2623085E-03 0.2630411E-03 0.1025520E+02 6.2289 13 Na+ 0.3332056E-01 0.3575914E-01 0.8196787E+03 8.3315 14 Mn++ 0.6241401E-10 0.2837390E-08 0.1554223E-03 9.2435 15 F- 0.7180179E-06 0.7215945E-06 0.1366855E-01 3.6637 16 HPO4-- 0.2286541E-07 0.2328152E-07 0.2227968E-02 11.8143 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276606E+02 -.8508072E-02 -.8275755E+02 0.0000000E+00 2 H2O -.6967397E+01 0.2766523E+02 -.3463263E+02 0.0000000E+00 3 Cl- 0.1589215E-02 0.1589215E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1397671E+00 -.1594752E-01 0.1557146E+00 0.0000000E+00 5 HCO3- 0.1779815E-01 0.1779815E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1337641E+00 0.2195058E-01 -.1557146E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1569613E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4870667E-02 0.5205903E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1281893E-05 0.5750725E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1435696E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1106552E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1310311E-03 0.1061440E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1781303E-01 0.6258564E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1413416E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9849600E-04 0.3594546E-06 0.9813655E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1159744E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: -.1603E-13 Mass of aqueous solution: 0.499608E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2459900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.96 628.6 andradite 0.6229 -0.206 316.5 2.500 5.792 82.24 grossular 0.1227 -0.911 55.29 1.743 1.012 15.38 apatite-OH 0.9764E-02 -2.010 4.905 0.691 0.8975E-01 1.559 apatite-F 0.9814E-04 -4.008 0.4949E-01 -1.305 0.9056E-03 0.1546E-01 clinochlore 0.7145 -0.146 397.1 2.599 7.267 151.1 daphnite 0.2000 -0.699 142.7 2.154 2.611 43.23 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9431 -0.025 262.5 2.419 4.804 102.5 stilbite 3.246 0.511 2288. 3.359 41.86 1067. stilpnomelane-Fe 0.2366 -0.626 255.1 2.407 4.667 88.10 tr.625ac.25prg.125 0.1092 -0.962 93.34 1.970 1.708 30.04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8354E+00 0.8354E+00 1.0000 -0.078 grossular 0.1646E+00 0.1646E+00 1.0000 -0.784 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7668E+00 0.7668E+00 1.0000 -0.115 daphnite 0.2146E+00 0.2146E+00 1.0000 -0.668 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5464.995666 g Volume = 2213.721488 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2459900 moles log = -0.6091 Original solution: 1000.0103000 g Original solution / Rock added: 4065.25 (Water/Rock Ratio), log = 3.6091 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 49.6014 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2210E-01 0.9171 0.1005E+01 0.1096E+01 CO2,gas 0.8116E-06 0.9203 0.3705E-04 0.4026E-04 CH4,gas 0.9777E+00 0.9716 0.4712E+02 0.4849E+02 H2,gas 0.2085E-03 1.0268 0.1062E-01 0.1034E-01 H2S,gas 0.2471E-05 0.8305 0.1018E-03 0.1226E-03 S2,gas 0.6951E-25 1.0000 0.3448E-23 0.3448E-23 CO,gas 0.2116E-11 1.0000 0.1049E-09 0.1049E-09 SO3,gas 0.4489E-46 1.0000 0.2226E-44 0.2226E-44 SO2,gas 0.1856E-25 1.0000 0.9205E-24 0.9205E-24 HF,gas 0.2412E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.2053E-17 1.0000 0.1018E-15 0.1018E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.00000E+00 24 grossular 32.73 32.73 0.00 0.000 0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.18198E-10 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 51 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28970E+04 0.002 2 CO2,gas -6.66 -12.79 -6.13 -2.043 0.10467E+05 -4.431 3 CH4,gas 4.54 4.52 -0.03 -0.006 0.43998E+02 1.673 4 H2,gas 8.00 4.33 -3.67 -2.099 0.62713E+04 -1.974 5 H2S,gas -6.23 -11.92 -5.69 -2.846 0.97177E+04 -3.992 6 S2,gas -7.34 -32.50 -25.16 -3.871 0.42962E+05 -23.462 7 CO,gas 3.21 -8.46 -11.68 -3.593 0.19940E+05 -9.979 8 SO3,gas 17.12 -29.23 -46.35 -11.588 0.79144E+05 -44.652 9 SO2,gas 0.83 -24.90 -25.73 -6.863 0.43942E+05 -24.036 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.50 -17.69 -8.846 0.30207E+05 -15.992 12 acmite 7.71 6.60 -1.11 -0.115 0.18875E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80692E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95949E+03 26 ankerite -2.14 -5.80 -3.67 -0.611 0.62608E+04 27 annite 20.12 17.69 -2.44 -0.135 0.41602E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28275E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.77014E+04 38 aragonite 0.97 0.26 -0.70 -0.234 0.11996E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55841E+04 40 calcite 0.81 0.26 -0.55 -0.183 0.93538E+03 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53257E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.598 0.71527E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70663E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82691E+04 45 celadonite 5.34 3.67 -1.67 -0.098 0.28582E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47515E+04 47 chrysotile 23.89 21.61 -2.29 -0.190 0.39026E+04 52 chlorite-Al-free 47.17 43.21 -3.96 -0.165 0.67604E+04 54 chloritoid-Fe 9.17 5.01 -4.16 -0.277 0.71024E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66050E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13113E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99666E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.16 -0.359 0.36829E+04 69 diamond -3.10 -4.14 -1.03 -0.295 0.17647E+04 70 diopside 16.18 16.06 -0.12 -0.012 0.19934E+03 71 hedenbergite 14.21 13.49 -0.72 -0.072 0.12252E+04 72 dolomite,ordered 0.55 -3.23 -3.77 -0.629 0.64444E+04 74 enstatite 17.26 12.31 -4.96 -0.496 0.84624E+04 76 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82940E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34132E+04 79 clinozoisite 22.81 18.83 -3.98 -0.181 0.67943E+04 80 epidote-Fe 29.84 26.52 -3.33 -0.173 0.56787E+04 81 fayalite 14.05 10.31 -3.74 -0.534 0.63871E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68102E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57419E+04 87 glaucophane 22.97 20.84 -2.14 -0.058 0.36463E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.71001E+04 89 graphite -3.55 -4.14 -0.59 -0.169 0.10070E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38494E+04 93 hematite 12.57 9.12 -3.44 -0.417 0.58810E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24845E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64582E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60138E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16607E+04 105 lawsonite 9.62 8.20 -1.42 -0.094 0.24189E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59101E+04 108 lizardite 23.24 21.61 -1.64 -0.136 0.27952E+04 109 magnesite 0.69 -3.49 -4.18 -1.394 0.71414E+04 110 magnetite 20.09 15.85 -4.24 -0.346 0.72413E+04 111 minnesotaite 10.39 7.60 -2.79 -0.164 0.47654E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82212E+04 123 muscovite 2.58 -1.05 -3.64 -0.214 0.62074E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54465E+04 125 nepheline 8.34 5.90 -2.44 -0.348 0.41581E+04 131 periclase-Fe 11.63 6.72 -4.90 -1.226 0.83701E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36463E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21548E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92872E+03 141 pumpellyite-Fe 46.27 43.66 -2.61 -0.058 0.44542E+04 142 pumpellyite-Mg 48.99 46.23 -2.76 -0.061 0.47129E+04 145 pyrite -21.25 -21.45 -0.20 -0.047 0.33852E+03 146 pyrrhotite -4.26 -5.20 -0.94 -0.312 0.15989E+04 147 pyrrhotiteFe0.875 -6.02 -6.57 -0.56 -0.205 0.95093E+03 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22187E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84808E+04 150 quartz -2.99 -3.14 -0.15 -0.052 0.26399E+03 154 rhodochrosite -0.98 -3.55 -2.57 -0.857 0.43894E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22990E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.07 -3.46 -1.153 0.59037E+04 168 stilpnomelane-Mg 27.44 25.89 -1.55 -0.046 0.26550E+04 174 talc 16.49 15.32 -1.17 -0.069 0.20014E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46840E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88397E+03 182 tremolite 47.87 47.45 -0.42 -0.011 0.71900E+03 183 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66143E+04 184 troilite-low -4.41 -5.20 -0.79 -0.262 0.13417E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34818E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27303E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.94073E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18606E+04 194 zoisite 22.85 18.83 -4.02 -0.183 0.68684E+04 195 akaganeite 7.75 4.56 -3.19 -0.691 0.54532E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58329E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66012E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68615E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73364E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60164E+04 208 nontronite-Ca 3.21 -0.03 -3.24 -0.210 0.55339E+04 209 nontronite-H 2.53 -2.18 -4.71 -0.316 0.80476E+04 210 nontronite-K 3.34 -0.12 -3.47 -0.222 0.59174E+04 211 nontronite-Mg 3.07 -0.65 -3.72 -0.241 0.63531E+04 212 nontronite-Na 3.52 0.57 -2.95 -0.189 0.50383E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35742E+04 234 alabandite -0.98 -2.68 -1.70 -0.567 0.29029E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.62998E+04 238 dolomite,disordered 1.25 -3.23 -4.48 -0.746 0.76414E+04 239 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52710E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17975E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11694E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15088E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18577E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.2459900 MOLES New total amount of reactant added: 0.2469900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8665E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2469900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4981E+00 Moles total = -.6967E+01 kg total = -.1255E+00 Activity = 0.9994 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3578968E-01 Chg. balance for total moles = -.8665E-10 Max. difference allowed = 0.1595E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15430E-09 -9.8116 0.12460E-09 -9.9045 0.80752E+00 -0.0928 2 H2O 0.99942E+00 -0.0003 0.99942E+00 -0.0003 3 Cl- 0.31796E-02 -2.4976 0.25438E-02 -2.5945 0.80001E+00 -0.0969 4 SO4-- 0.87834E-09 -9.0563 0.38622E-09 -9.4132 0.43971E+00 -0.3568 5 HCO3- 0.16462E-02 -2.7835 0.13200E-02 -2.8794 0.80183E+00 -0.0959 6 HS- 0.12096E-01 -1.9174 0.96793E-02 -2.0142 0.80019E+00 -0.0968 7 Al+++ 0.63903E-28 -28.1945 0.10084E-28 -28.9964 0.15781E+00 -0.8019 8 H4SiO4 0.71708E-03 -3.1444 0.71708E-03 -3.1444 0.10000E+01 0.0000 9 Ca++ 0.40457E-06 -6.3930 0.17585E-06 -6.7549 0.43466E+00 -0.3619 10 Mg++ 0.71572E-10 -10.1453 0.30888E-10 -10.5102 0.43157E+00 -0.3649 11 Fe++ 0.19053E-12 -12.7200 0.82368E-13 -13.0842 0.43231E+00 -0.3642 12 K+ 0.26304E-03 -3.5800 0.21099E-03 -3.6757 0.80210E+00 -0.0958 13 Na+ 0.33414E-01 -1.4761 0.26723E-01 -1.5731 0.79975E+00 -0.0970 14 Mn++ 0.62837E-10 -10.2018 0.27200E-10 -10.5654 0.43286E+00 -0.3636 15 F- 0.71614E-06 -6.1450 0.57112E-06 -6.2433 0.79750E+00 -0.0983 16 HPO4-- 0.22792E-07 -7.6422 0.10024E-07 -7.9989 0.43981E+00 -0.3567 18 HSiO3- 0.67208E-02 -2.1726 0.53767E-02 -2.2695 0.80001E+00 -0.0969 19 Ca(HSiO3)+ 0.26836E-07 -7.5713 0.21532E-07 -7.6669 0.80237E+00 -0.0956 20 Mg(HSiO3)+ 0.58664E-11 -11.2316 0.47071E-11 -11.3273 0.80237E+00 -0.0956 21 NaHSiO3,aq 0.23239E-02 -2.6338 0.23239E-02 -2.6338 0.10000E+01 0.0000 22 AlO+ 0.11006E-15 -15.9584 0.88311E-16 -16.0540 0.80237E+00 -0.0956 24 HAlO2,aq 0.14106E-09 -9.8506 0.14106E-09 -9.8506 0.10000E+01 0.0000 25 AlO2- 0.31412E-05 -5.5029 0.25060E-05 -5.6010 0.79780E+00 -0.0981 26 CH4,aq 0.32115E-01 -1.4933 0.32115E-01 -1.4933 0.10000E+01 0.0000 27 C2H6,aq 0.21862E-07 -7.6603 0.21862E-07 -7.6603 0.10000E+01 0.0000 28 C3H8,aq 0.34360E-12 -12.4639 0.34360E-12 -12.4639 0.10000E+01 0.0000 29 C4H10,aq 0.53050E-17 -17.2753 0.53050E-17 -17.2753 0.10000E+01 0.0000 30 ethanol,aq 0.11517E-14 -14.9386 0.11517E-14 -14.9386 0.10000E+01 0.0000 31 CO,aq 0.71282E-13 -13.1470 0.71282E-13 -13.1470 0.10000E+01 0.0000 32 CO2,aq 0.35164E-06 -6.4539 0.35164E-06 -6.4539 0.10000E+01 0.0000 33 CO3-2 0.21112E-02 -2.6755 0.92529E-03 -3.0337 0.43827E+00 -0.3583 34 CaCO3,aq 0.20402E-05 -5.6903 0.20402E-05 -5.6903 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.73843E-08 -8.1317 0.59249E-08 -8.2273 0.80237E+00 -0.0956 36 CaCl+ 0.90219E-09 -9.0447 0.72390E-09 -9.1403 0.80237E+00 -0.0956 37 CaCl2,aq 0.43748E-12 -12.3590 0.43748E-12 -12.3590 0.10000E+01 0.0000 38 CaF+ 0.18274E-11 -11.7382 0.14663E-11 -11.8338 0.80237E+00 -0.0956 39 CaOH+ 0.12528E-06 -6.9021 0.10052E-06 -6.9977 0.80237E+00 -0.0956 40 CaSO4,aq 0.21567E-13 -13.6662 0.21567E-13 -13.6662 0.10000E+01 0.0000 41 HCl,aq 0.58081E-13 -13.2360 0.58081E-13 -13.2360 0.10000E+01 0.0000 45 HF,aq 0.48716E-12 -12.3123 0.48716E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.11742E-18 -18.9303 0.93936E-19 -19.0272 0.80001E+00 -0.0969 48 FeCl+ 0.41333E-15 -15.3837 0.33164E-15 -15.4793 0.80237E+00 -0.0956 51 FeF+ 0.29960E-17 -17.5235 0.24039E-17 -17.6191 0.80237E+00 -0.0956 53 FeO,aq 0.20607E-09 -9.6860 0.20607E-09 -9.6860 0.10000E+01 0.0000 54 FeOH+ 0.26802E-10 -10.5718 0.21505E-10 -10.6675 0.80237E+00 -0.0956 55 HFeO2- 0.21618E-07 -7.6652 0.17295E-07 -7.7621 0.80001E+00 -0.0969 56 FeO+ 0.22511E-16 -16.6476 0.18062E-16 -16.7432 0.80237E+00 -0.0956 58 FeO2- 0.29739E-09 -9.5267 0.23791E-09 -9.6236 0.80001E+00 -0.0969 59 HFeO2,aq 0.37703E-11 -11.4236 0.37703E-11 -11.4236 0.10000E+01 0.0000 60 H2,aq 0.80650E-05 -5.0934 0.80650E-05 -5.0934 0.10000E+01 0.0000 61 KCl,aq 0.97272E-08 -8.0120 0.97272E-08 -8.0120 0.10000E+01 0.0000 63 KOH,aq 0.72271E-06 -6.1410 0.72271E-06 -6.1410 0.10000E+01 0.0000 64 KSO4- 0.15806E-11 -11.8012 0.12645E-11 -11.8981 0.80001E+00 -0.0969 65 MgCO3,aq 0.89828E-10 -10.0466 0.89828E-10 -10.0466 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13254E-11 -11.8777 0.10634E-11 -11.9733 0.80237E+00 -0.0956 67 MgCl+ 0.14363E-12 -12.8428 0.11525E-12 -12.9384 0.80237E+00 -0.0956 68 MgF+ 0.11891E-14 -14.9248 0.95408E-15 -15.0204 0.80237E+00 -0.0956 69 MgOH+ 0.12177E-09 -9.9145 0.97706E-10 -10.0101 0.80237E+00 -0.0956 71 MnF+ 0.32610E-15 -15.4867 0.26165E-15 -15.5823 0.80237E+00 -0.0956 72 MnO,aq 0.18132E-08 -8.7415 0.18132E-08 -8.7415 0.10000E+01 0.0000 73 MnOH+ 0.82219E-09 -9.0850 0.65971E-09 -9.1806 0.80237E+00 -0.0956 74 MnO2-2 0.88386E-11 -11.0536 0.38737E-11 -11.4119 0.43827E+00 -0.3583 75 HMnO2- 0.13218E-09 -9.8788 0.10574E-09 -9.9757 0.80001E+00 -0.0969 78 MnCl+ 0.53100E-12 -12.2749 0.42606E-12 -12.3705 0.80237E+00 -0.0956 79 MnSO4,aq 0.30327E-17 -17.5182 0.30327E-17 -17.5182 0.10000E+01 0.0000 80 NaCl,aq 0.22528E-04 -4.6473 0.22528E-04 -4.6473 0.10000E+01 0.0000 81 NaF,aq 0.35731E-08 -8.4470 0.35731E-08 -8.4470 0.10000E+01 0.0000 82 NaOH,aq 0.92092E-04 -4.0358 0.92092E-04 -4.0358 0.10000E+01 0.0000 84 OH- 0.58088E-02 -2.2359 0.46343E-02 -2.3340 0.79780E+00 -0.0981 89 HPO3-2 0.57519E-15 -15.2402 0.25209E-15 -15.5984 0.43827E+00 -0.3583 91 H2PO3- 0.78734E-19 -19.1038 0.62988E-19 -19.2007 0.80001E+00 -0.0969 92 H3PO4,aq 0.10885E-17 -17.9632 0.10885E-17 -17.9632 0.10000E+01 0.0000 93 H2PO4- 0.28759E-10 -10.5412 0.23042E-10 -10.6375 0.80119E+00 -0.0963 94 PO4-3 0.38540E-09 -9.4141 0.65639E-10 -10.1828 0.17031E+00 -0.7688 98 HP2O7-3 0.42216E-18 -18.3745 0.66750E-19 -19.1755 0.15811E+00 -0.8010 99 P2O7-4 0.32131E-17 -17.4931 0.12798E-18 -18.8929 0.39831E-01 -1.3998 100 H2S,aq 0.37275E-05 -5.4286 0.37275E-05 -5.4286 0.10000E+01 0.0000 101 S2-2 0.58732E-09 -9.2311 0.25740E-09 -9.5894 0.43827E+00 -0.3583 102 S3-2 0.36571E-15 -15.4369 0.16028E-15 -15.7951 0.43827E+00 -0.3583 107 SO3-2 0.90380E-15 -15.0439 0.40501E-15 -15.3925 0.44812E+00 -0.3486 108 HSO3- 0.39496E-17 -17.4034 0.31597E-17 -17.5004 0.80001E+00 -0.0969 109 HSO4- 0.57711E-16 -16.2387 0.46378E-16 -16.3337 0.80361E+00 -0.0950 111 S2O3-2 0.38608E-16 -16.4133 0.16921E-16 -16.7716 0.43827E+00 -0.3583 Charge balance for all species = -.1740E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1543019E-09 -.1707033E-01 -.1715517E+02 0.0000 2 H2O 0.1000000E+01 0.5553724E+02 0.9975717E+06 0.0000 3 Cl- 0.3179637E-02 0.3202176E-02 0.1131922E+03 7.3099 4 SO4-- 0.8783440E-09 -.3211691E-01 -.3076110E+04 10.3958 5 HCO3- 0.1646180E-02 0.3587472E-01 0.2182525E+04 7.0250 6 HS- 0.1209613E-01 0.4421676E-01 0.1458028E+04 7.8903 7 Al+++ 0.6390289E-28 0.3141325E-05 0.8450790E-01 0.7171 8 H4SiO4 0.7170795E-03 0.9761802E-02 0.9354947E+03 -3.1444 9 Ca++ 0.4045694E-06 0.2605197E-05 0.1041034E+00 13.0541 10 Mg++ 0.7157159E-10 0.2905064E-09 0.7041980E-05 9.2987 11 Fe++ 0.1905327E-12 0.2215205E-07 0.1233480E-02 6.7247 12 K+ 0.2630422E-03 0.2637746E-03 0.1028372E+02 6.2287 13 Na+ 0.3341400E-01 0.3585249E-01 0.8218127E+03 8.3314 14 Mn++ 0.6283653E-10 0.2839810E-08 0.1555537E-03 9.2435 15 F- 0.7161397E-06 0.7197151E-06 0.1363286E-01 3.6612 16 HPO4-- 0.2279239E-07 0.2320656E-07 0.2220779E-02 11.8100 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276595E+02 -.8503326E-02 -.8275745E+02 0.0000000E+00 2 H2O -.6966578E+01 0.2766503E+02 -.3463161E+02 0.0000000E+00 3 Cl- 0.1595115E-02 0.1595115E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1397719E+00 -.1599855E-01 0.1557704E+00 0.0000000E+00 5 HCO3- 0.1787045E-01 0.1787045E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1337445E+00 0.2202591E-01 -.1557704E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1564803E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4862694E-02 0.5205904E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1297740E-05 0.5750725E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1447114E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1103471E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1313953E-03 0.1061440E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1785937E-01 0.6258518E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1414608E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9889600E-04 0.3585151E-06 0.9853748E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1155999E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: 0.1026E-13 Mass of aqueous solution: 0.499607E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2469900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.96 628.6 andradite 0.6231 -0.205 316.6 2.501 5.794 82.26 grossular 0.1226 -0.912 55.21 1.742 1.010 15.36 apatite-OH 0.9764E-02 -2.010 4.905 0.691 0.8975E-01 1.559 apatite-F 0.9854E-04 -4.006 0.4969E-01 -1.304 0.9093E-03 0.1552E-01 clinochlore 0.7146 -0.146 397.2 2.599 7.268 151.1 daphnite 0.1999 -0.699 142.7 2.154 2.610 43.23 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9431 -0.025 262.5 2.419 4.804 102.5 stilbite 3.246 0.511 2288. 3.359 41.86 1067. stilpnomelane-Fe 0.2366 -0.626 255.0 2.407 4.667 88.09 tr.625ac.25prg.125 0.1090 -0.962 93.21 1.969 1.706 30.00 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8356E+00 0.8356E+00 1.0000 -0.078 grossular 0.1644E+00 0.1644E+00 1.0000 -0.784 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7668E+00 0.7668E+00 1.0000 -0.115 daphnite 0.2145E+00 0.2145E+00 1.0000 -0.668 chlorite-Mn 0.1861E-01 0.1861E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5465.017271 g Volume = 2213.742748 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2469900 moles log = -0.6073 Original solution: 1000.0103000 g Original solution / Rock added: 4048.79 (Water/Rock Ratio), log = 3.6073 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 49.7614 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2204E-01 0.9169 0.1005E+01 0.1097E+01 CO2,gas 0.8217E-06 0.9201 0.3762E-04 0.4089E-04 CH4,gas 0.9778E+00 0.9716 0.4727E+02 0.4865E+02 H2,gas 0.2072E-03 1.0269 0.1059E-01 0.1031E-01 H2S,gas 0.2481E-05 0.8300 0.1025E-03 0.1234E-03 S2,gas 0.7064E-25 1.0000 0.3515E-23 0.3515E-23 CO,gas 0.2135E-11 1.0000 0.1062E-09 0.1062E-09 SO3,gas 0.4559E-46 1.0000 0.2269E-44 0.2269E-44 SO2,gas 0.1879E-25 1.0000 0.9350E-24 0.9350E-24 HF,gas 0.2404E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.2060E-17 1.0000 0.1025E-15 0.1025E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 23 andradite 39.01 39.01 0.00 0.000 0.24265E-10 24 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 -0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28970E+04 0.002 2 CO2,gas -6.66 -12.78 -6.12 -2.041 0.10456E+05 -4.425 3 CH4,gas 4.54 4.52 -0.02 -0.006 0.41622E+02 1.675 4 H2,gas 8.00 4.33 -3.67 -2.100 0.62735E+04 -1.975 5 H2S,gas -6.23 -11.92 -5.69 -2.844 0.97128E+04 -3.989 6 S2,gas -7.34 -32.49 -25.15 -3.870 0.42948E+05 -23.454 7 CO,gas 3.21 -8.46 -11.67 -3.592 0.19931E+05 -9.974 8 SO3,gas 17.12 -29.22 -46.34 -11.586 0.79130E+05 -44.644 9 SO2,gas 0.83 -24.90 -25.73 -6.861 0.43930E+05 -24.029 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.50 -17.69 -8.844 0.30202E+05 -15.989 12 acmite 7.71 6.60 -1.10 -0.115 0.18864E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80695E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95968E+03 26 ankerite -2.14 -5.79 -3.65 -0.609 0.62390E+04 27 annite 20.12 17.69 -2.44 -0.135 0.41607E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28273E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.77023E+04 38 aragonite 0.97 0.27 -0.70 -0.232 0.11890E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55840E+04 40 calcite 0.81 0.27 -0.54 -0.181 0.92477E+03 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53261E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.598 0.71531E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70665E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82696E+04 45 celadonite 5.34 3.67 -1.67 -0.098 0.28579E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47515E+04 47 chrysotile 23.89 21.61 -2.29 -0.190 0.39020E+04 52 chlorite-Al-free 47.17 43.21 -3.96 -0.165 0.67593E+04 54 chloritoid-Fe 9.17 5.01 -4.16 -0.277 0.71030E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66056E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13111E+04 64 cristobalite -2.56 -3.14 -0.58 -0.195 0.99647E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.16 -0.360 0.36832E+04 69 diamond -3.10 -4.13 -1.03 -0.294 0.17579E+04 70 diopside 16.18 16.06 -0.12 -0.012 0.19958E+03 71 hedenbergite 14.21 13.49 -0.72 -0.072 0.12257E+04 72 dolomite,ordered 0.55 -3.21 -3.76 -0.627 0.64224E+04 74 enstatite 17.26 12.31 -4.96 -0.496 0.84619E+04 76 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82935E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34137E+04 79 clinozoisite 22.81 18.83 -3.98 -0.181 0.67961E+04 80 epidote-Fe 29.84 26.52 -3.33 -0.173 0.56779E+04 81 fayalite 14.05 10.30 -3.74 -0.534 0.63872E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68101E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57422E+04 87 glaucophane 22.97 20.84 -2.14 -0.058 0.36457E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.71002E+04 89 graphite -3.55 -4.13 -0.59 -0.167 0.10001E+04 90 greenalite 16.14 13.89 -2.25 -0.188 0.38495E+04 93 hematite 12.57 9.12 -3.44 -0.417 0.58791E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24847E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64586E+04 101 kaolinite -1.33 -4.85 -3.52 -0.320 0.60141E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16612E+04 105 lawsonite 9.62 8.20 -1.42 -0.094 0.24199E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59103E+04 108 lizardite 23.24 21.61 -1.64 -0.136 0.27947E+04 109 magnesite 0.69 -3.49 -4.18 -1.392 0.71300E+04 110 magnetite 20.09 15.85 -4.24 -0.346 0.72395E+04 111 minnesotaite 10.39 7.60 -2.79 -0.164 0.47650E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82212E+04 123 muscovite 2.58 -1.05 -3.64 -0.214 0.62080E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54471E+04 125 nepheline 8.34 5.90 -2.44 -0.348 0.41585E+04 131 periclase-Fe 11.63 6.72 -4.90 -1.226 0.83702E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36461E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21563E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92889E+03 141 pumpellyite-Fe 46.27 43.66 -2.61 -0.058 0.44576E+04 142 pumpellyite-Mg 48.99 46.23 -2.76 -0.061 0.47161E+04 145 pyrite -21.25 -21.44 -0.19 -0.045 0.32654E+03 146 pyrrhotite -4.26 -5.19 -0.93 -0.311 0.15941E+04 147 pyrrhotiteFe0.875 -6.02 -6.57 -0.55 -0.204 0.94584E+03 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22186E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84807E+04 150 quartz -2.99 -3.14 -0.15 -0.051 0.26380E+03 154 rhodochrosite -0.98 -3.54 -2.56 -0.855 0.43781E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22989E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.06 -3.45 -1.150 0.58926E+04 168 stilpnomelane-Mg 27.44 25.89 -1.55 -0.046 0.26539E+04 174 talc 16.49 15.32 -1.17 -0.069 0.20004E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46839E+04 181 tridymite -2.63 -3.14 -0.52 -0.173 0.88377E+03 182 tremolite 47.87 47.45 -0.42 -0.011 0.71851E+03 183 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66149E+04 184 troilite-low -4.41 -5.19 -0.78 -0.261 0.13369E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34823E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27308E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.94123E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18611E+04 194 zoisite 22.85 18.83 -4.02 -0.183 0.68701E+04 195 akaganeite 7.75 4.56 -3.19 -0.690 0.54523E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58309E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66011E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68614E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73361E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60163E+04 208 nontronite-Ca 3.21 -0.03 -3.24 -0.210 0.55315E+04 209 nontronite-H 2.53 -2.18 -4.71 -0.316 0.80450E+04 210 nontronite-K 3.34 -0.12 -3.46 -0.222 0.59150E+04 211 nontronite-Mg 3.07 -0.64 -3.72 -0.241 0.63506E+04 212 nontronite-Na 3.52 0.57 -2.95 -0.189 0.50359E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35745E+04 234 alabandite -0.98 -2.68 -1.70 -0.566 0.28980E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.63002E+04 238 dolomite,disordered 1.25 -3.21 -4.46 -0.744 0.76194E+04 239 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52712E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17973E+04 247 an20ab80 2.02 1.33 -0.68 -0.053 0.11696E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15090E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18580E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.2469900 MOLES New total amount of reactant added: 0.2479900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8666E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2479900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4981E+00 Moles total = -.6966E+01 kg total = -.1255E+00 Activity = 0.9994 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3590651E-01 Chg. balance for total moles = -.8666E-10 Max. difference allowed = 0.1601E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15478E-09 -9.8103 0.12496E-09 -9.9032 0.80733E+00 -0.0929 2 H2O 0.99942E+00 -0.0003 0.99942E+00 -0.0003 3 Cl- 0.31914E-02 -2.4960 0.25525E-02 -2.5930 0.79980E+00 -0.0970 4 SO4-- 0.89065E-09 -9.0503 0.39124E-09 -9.4076 0.43927E+00 -0.3573 5 HCO3- 0.16670E-02 -2.7781 0.13363E-02 -2.8741 0.80163E+00 -0.0960 6 HS- 0.12145E-01 -1.9156 0.97158E-02 -2.0125 0.79999E+00 -0.0969 7 Al+++ 0.64581E-28 -28.1899 0.10168E-28 -28.9928 0.15744E+00 -0.8029 8 H4SiO4 0.71726E-03 -3.1443 0.71726E-03 -3.1443 0.10000E+01 0.0000 9 Ca++ 0.40696E-06 -6.3905 0.17670E-06 -6.7528 0.43420E+00 -0.3623 10 Mg++ 0.72069E-10 -10.1423 0.31070E-10 -10.5077 0.43112E+00 -0.3654 11 Fe++ 0.19180E-12 -12.7172 0.82829E-13 -13.0818 0.43185E+00 -0.3647 12 K+ 0.26378E-03 -3.5788 0.21153E-03 -3.6746 0.80190E+00 -0.0959 13 Na+ 0.33508E-01 -1.4749 0.26791E-01 -1.5720 0.79954E+00 -0.0972 14 Mn++ 0.63263E-10 -10.1989 0.27355E-10 -10.5630 0.43241E+00 -0.3641 15 F- 0.71426E-06 -6.1461 0.56947E-06 -6.2445 0.79728E+00 -0.0984 16 HPO4-- 0.22719E-07 -7.6436 0.99821E-08 -8.0008 0.43937E+00 -0.3572 18 HSiO3- 0.67049E-02 -2.1736 0.53626E-02 -2.2706 0.79980E+00 -0.0970 19 Ca(HSiO3)+ 0.26902E-07 -7.5702 0.21580E-07 -7.6659 0.80217E+00 -0.0957 20 Mg(HSiO3)+ 0.58869E-11 -11.2301 0.47223E-11 -11.3258 0.80217E+00 -0.0957 21 NaHSiO3,aq 0.23237E-02 -2.6338 0.23237E-02 -2.6338 0.10000E+01 0.0000 22 AlO+ 0.11036E-15 -15.9572 0.88528E-16 -16.0529 0.80217E+00 -0.0957 24 HAlO2,aq 0.14100E-09 -9.8508 0.14100E-09 -9.8508 0.10000E+01 0.0000 25 AlO2- 0.31316E-05 -5.5042 0.24977E-05 -5.6025 0.79759E+00 -0.0982 26 CH4,aq 0.32217E-01 -1.4919 0.32217E-01 -1.4919 0.10000E+01 0.0000 27 C2H6,aq 0.22068E-07 -7.6562 0.22068E-07 -7.6562 0.10000E+01 0.0000 28 C3H8,aq 0.34899E-12 -12.4572 0.34899E-12 -12.4572 0.10000E+01 0.0000 29 C4H10,aq 0.54217E-17 -17.2659 0.54217E-17 -17.2659 0.10000E+01 0.0000 30 ethanol,aq 0.11661E-14 -14.9333 0.11661E-14 -14.9333 0.10000E+01 0.0000 31 CO,aq 0.72157E-13 -13.1417 0.72157E-13 -13.1417 0.10000E+01 0.0000 32 CO2,aq 0.35702E-06 -6.4473 0.35702E-06 -6.4473 0.10000E+01 0.0000 33 CO3-2 0.21334E-02 -2.6709 0.93406E-03 -3.0296 0.43782E+00 -0.3587 34 CaCO3,aq 0.20695E-05 -5.6841 0.20695E-05 -5.6841 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.75140E-08 -8.1241 0.60275E-08 -8.2199 0.80217E+00 -0.0957 36 CaCl+ 0.90991E-09 -9.0410 0.72991E-09 -9.1367 0.80217E+00 -0.0957 37 CaCl2,aq 0.44263E-12 -12.3540 0.44263E-12 -12.3540 0.10000E+01 0.0000 38 CaF+ 0.18315E-11 -11.7372 0.14692E-11 -11.8329 0.80217E+00 -0.0957 39 CaOH+ 0.12556E-06 -6.9012 0.10072E-06 -6.9969 0.80217E+00 -0.0957 40 CaSO4,aq 0.21953E-13 -13.6585 0.21953E-13 -13.6585 0.10000E+01 0.0000 41 HCl,aq 0.58449E-13 -13.2332 0.58449E-13 -13.2332 0.10000E+01 0.0000 45 HF,aq 0.48716E-12 -12.3123 0.48716E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.11711E-18 -18.9314 0.93664E-19 -19.0284 0.79980E+00 -0.0970 48 FeCl+ 0.41717E-15 -15.3797 0.33464E-15 -15.4754 0.80217E+00 -0.0957 51 FeF+ 0.30048E-17 -17.5222 0.24104E-17 -17.6179 0.80217E+00 -0.0957 53 FeO,aq 0.20603E-09 -9.6861 0.20603E-09 -9.6861 0.10000E+01 0.0000 54 FeOH+ 0.26881E-10 -10.5706 0.21563E-10 -10.6663 0.80217E+00 -0.0957 55 HFeO2- 0.21557E-07 -7.6664 0.17241E-07 -7.7634 0.79980E+00 -0.0970 56 FeO+ 0.22611E-16 -16.6457 0.18138E-16 -16.7414 0.80217E+00 -0.0957 58 FeO2- 0.29699E-09 -9.5273 0.23754E-09 -9.6243 0.79980E+00 -0.0970 59 HFeO2,aq 0.37752E-11 -11.4231 0.37752E-11 -11.4231 0.10000E+01 0.0000 60 H2,aq 0.80408E-05 -5.0947 0.80408E-05 -5.0947 0.10000E+01 0.0000 61 KCl,aq 0.97855E-08 -8.0094 0.97855E-08 -8.0094 0.10000E+01 0.0000 63 KOH,aq 0.72246E-06 -6.1412 0.72246E-06 -6.1412 0.10000E+01 0.0000 64 KSO4- 0.16056E-11 -11.7944 0.12842E-11 -11.8914 0.79980E+00 -0.0970 65 MgCO3,aq 0.91212E-10 -10.0399 0.91212E-10 -10.0399 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13500E-11 -11.8697 0.10829E-11 -11.9654 0.80217E+00 -0.0957 67 MgCl+ 0.14501E-12 -12.8386 0.11632E-12 -12.9343 0.80217E+00 -0.0957 68 MgF+ 0.11929E-14 -14.9234 0.95692E-15 -15.0191 0.80217E+00 -0.0957 69 MgOH+ 0.12216E-09 -9.9131 0.97997E-10 -10.0088 0.80217E+00 -0.0957 71 MnF+ 0.32710E-15 -15.4853 0.26239E-15 -15.5811 0.80217E+00 -0.0957 72 MnO,aq 0.18131E-08 -8.7416 0.18131E-08 -8.7416 0.10000E+01 0.0000 73 MnOH+ 0.82472E-09 -9.0837 0.66157E-09 -9.1794 0.80217E+00 -0.0957 74 MnO2-2 0.87960E-11 -11.0557 0.38511E-11 -11.4144 0.43782E+00 -0.3587 75 HMnO2- 0.13182E-09 -9.8800 0.10543E-09 -9.9770 0.79980E+00 -0.0970 78 MnCl+ 0.53601E-12 -12.2708 0.42997E-12 -12.3666 0.80217E+00 -0.0957 79 MnSO4,aq 0.30897E-17 -17.5101 0.30897E-17 -17.5101 0.10000E+01 0.0000 80 NaCl,aq 0.22662E-04 -4.6447 0.22662E-04 -4.6447 0.10000E+01 0.0000 81 NaF,aq 0.35719E-08 -8.4471 0.35719E-08 -8.4471 0.10000E+01 0.0000 82 NaOH,aq 0.92060E-04 -4.0359 0.92060E-04 -4.0359 0.10000E+01 0.0000 84 OH- 0.57936E-02 -2.2371 0.46209E-02 -2.3353 0.79759E+00 -0.0982 89 HPO3-2 0.57164E-15 -15.2429 0.25027E-15 -15.6016 0.43782E+00 -0.3587 91 H2PO3- 0.78414E-19 -19.1056 0.62716E-19 -19.2026 0.79980E+00 -0.0970 92 H3PO4,aq 0.10902E-17 -17.9625 0.10902E-17 -17.9625 0.10000E+01 0.0000 93 H2PO4- 0.28728E-10 -10.5417 0.23011E-10 -10.6381 0.80098E+00 -0.0964 94 PO4-3 0.38350E-09 -9.4162 0.65174E-10 -10.1859 0.16995E+00 -0.7697 98 HP2O7-3 0.42080E-18 -18.3759 0.66381E-19 -19.1780 0.15775E+00 -0.8020 99 P2O7-4 0.31989E-17 -17.4950 0.12690E-18 -18.8965 0.39671E-01 -1.4015 100 H2S,aq 0.37524E-05 -5.4257 0.37524E-05 -5.4257 0.10000E+01 0.0000 101 S2-2 0.59415E-09 -9.2261 0.26013E-09 -9.5848 0.43782E+00 -0.3587 102 S3-2 0.37356E-15 -15.4276 0.16355E-15 -15.7863 0.43782E+00 -0.3587 107 SO3-2 0.91367E-15 -15.0392 0.40904E-15 -15.3882 0.44768E+00 -0.3490 108 HSO3- 0.40015E-17 -17.3978 0.32004E-17 -17.4948 0.79980E+00 -0.0970 109 HSO4- 0.58645E-16 -16.2318 0.47116E-16 -16.3268 0.80341E+00 -0.0951 111 S2O3-2 0.39411E-16 -16.4044 0.17255E-16 -16.7631 0.43782E+00 -0.3587 Charge balance for all species = -.1740E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1547850E-09 -.1706111E-01 -.1714578E+02 0.0000 2 H2O 0.1000000E+01 0.5553734E+02 0.9975666E+06 0.0000 3 Cl- 0.3191375E-02 0.3214048E-02 0.1136111E+03 7.3102 4 SO4-- 0.8906524E-09 -.3221933E-01 -.3085898E+04 10.3989 5 HCO3- 0.1667006E-02 0.3602018E-01 0.2191359E+04 7.0291 6 HS- 0.1214500E-01 0.4436807E-01 0.1463007E+04 7.8907 7 Al+++ 0.6458087E-28 0.3131716E-05 0.8424882E-01 0.7169 8 H4SiO4 0.7172643E-03 0.9745890E-02 0.9339634E+03 -3.1443 9 Ca++ 0.4069566E-06 0.2637391E-05 0.1053891E+00 13.0537 10 Mg++ 0.7206873E-10 0.2928287E-09 0.7098224E-05 9.2988 11 Fe++ 0.1917995E-12 0.2209048E-07 0.1230043E-02 6.7246 12 K+ 0.2637795E-03 0.2645118E-03 0.1031239E+02 6.2286 13 Na+ 0.3350790E-01 0.3594630E-01 0.8239573E+03 8.3312 14 Mn++ 0.6326273E-10 0.2842247E-08 0.1556861E-03 9.2435 15 F- 0.7142634E-06 0.7178376E-06 0.1359720E-01 3.6587 16 HPO4-- 0.2271940E-07 0.2313163E-07 0.2213593E-02 11.8057 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276585E+02 -.8498657E-02 -.8275735E+02 0.0000000E+00 2 H2O -.6965759E+01 0.2766484E+02 -.3463060E+02 0.0000000E+00 3 Cl- 0.1601015E-02 0.1601015E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1397767E+00 -.1604942E-01 0.1558261E+00 0.0000000E+00 5 HCO3- 0.1794275E-01 0.1794275E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1337250E+00 0.2210109E-01 -.1558261E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1560003E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4854724E-02 0.5205905E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1313764E-05 0.5750725E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1458669E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1100394E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1317614E-03 0.1061439E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1790594E-01 0.6258471E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1415809E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9929600E-04 0.3575767E-06 0.9893842E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1152257E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: -.8882E-15 Mass of aqueous solution: 0.499606E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2479900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.96 628.6 andradite 0.6233 -0.205 316.8 2.501 5.796 82.29 grossular 0.1224 -0.912 55.13 1.741 1.009 15.34 apatite-OH 0.9764E-02 -2.010 4.904 0.691 0.8974E-01 1.558 apatite-F 0.9894E-04 -4.005 0.4990E-01 -1.302 0.9130E-03 0.1559E-01 clinochlore 0.7147 -0.146 397.3 2.599 7.269 151.1 daphnite 0.1999 -0.699 142.6 2.154 2.610 43.22 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9432 -0.025 262.5 2.419 4.804 102.5 stilbite 3.247 0.511 2288. 3.359 41.86 1067. stilpnomelane-Fe 0.2366 -0.626 255.0 2.407 4.666 88.09 tr.625ac.25prg.125 0.1089 -0.963 93.08 1.969 1.703 29.96 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8359E+00 0.8359E+00 1.0000 -0.078 grossular 0.1641E+00 0.1641E+00 1.0000 -0.785 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7669E+00 0.7669E+00 1.0000 -0.115 daphnite 0.2145E+00 0.2145E+00 1.0000 -0.669 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5465.038833 g Volume = 2213.763968 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2479900 moles log = -0.6056 Original solution: 1000.0103000 g Original solution / Rock added: 4032.46 (Water/Rock Ratio), log = 3.6056 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 49.9210 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2197E-01 0.9167 0.1005E+01 0.1097E+01 CO2,gas 0.8318E-06 0.9199 0.3820E-04 0.4152E-04 CH4,gas 0.9778E+00 0.9715 0.4742E+02 0.4881E+02 H2,gas 0.2059E-03 1.0270 0.1056E-01 0.1028E-01 H2S,gas 0.2491E-05 0.8295 0.1032E-03 0.1243E-03 S2,gas 0.7179E-25 1.0000 0.3584E-23 0.3584E-23 CO,gas 0.2154E-11 1.0000 0.1075E-09 0.1075E-09 SO3,gas 0.4630E-46 1.0000 0.2311E-44 0.2311E-44 SO2,gas 0.1903E-25 1.0000 0.9498E-24 0.9498E-24 HF,gas 0.2396E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.2066E-17 1.0000 0.1031E-15 0.1031E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 0.11184E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 50 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 119 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 166 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28970E+04 0.002 2 CO2,gas -6.66 -12.78 -6.12 -2.039 0.10444E+05 -4.418 3 CH4,gas 4.54 4.52 -0.02 -0.006 0.39260E+02 1.676 4 H2,gas 8.00 4.32 -3.68 -2.100 0.62757E+04 -1.976 5 H2S,gas -6.23 -11.92 -5.69 -2.843 0.97078E+04 -3.987 6 S2,gas -7.34 -32.48 -25.14 -3.868 0.42934E+05 -23.446 7 CO,gas 3.21 -8.45 -11.67 -3.590 0.19922E+05 -9.968 8 SO3,gas 17.12 -29.21 -46.34 -11.584 0.79116E+05 -44.636 9 SO2,gas 0.83 -24.89 -25.72 -6.859 0.43918E+05 -24.022 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 -14.922 11 HCl,gas 5.19 -12.50 -17.69 -8.843 0.30198E+05 -15.987 12 acmite 7.71 6.61 -1.10 -0.115 0.18853E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80697E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.95988E+03 26 ankerite -2.14 -5.78 -3.64 -0.607 0.62173E+04 27 annite 20.12 17.69 -2.44 -0.135 0.41612E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28271E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.77033E+04 38 aragonite 0.97 0.28 -0.69 -0.230 0.11784E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55839E+04 40 calcite 0.81 0.28 -0.54 -0.178 0.91418E+03 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53265E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.599 0.71535E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70667E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82700E+04 45 celadonite 5.34 3.67 -1.67 -0.098 0.28577E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47514E+04 47 chrysotile 23.89 21.61 -2.28 -0.190 0.39015E+04 52 chlorite-Al-free 47.17 43.21 -3.96 -0.165 0.67581E+04 54 chloritoid-Fe 9.17 5.01 -4.16 -0.277 0.71036E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66061E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13109E+04 64 cristobalite -2.56 -3.14 -0.58 -0.194 0.99627E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.16 -0.360 0.36836E+04 69 diamond -3.10 -4.13 -1.03 -0.293 0.17511E+04 70 diopside 16.18 16.06 -0.12 -0.012 0.19982E+03 71 hedenbergite 14.21 13.49 -0.72 -0.072 0.12262E+04 72 dolomite,ordered 0.55 -3.20 -3.75 -0.625 0.64005E+04 74 enstatite 17.26 12.31 -4.96 -0.496 0.84613E+04 76 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82929E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34142E+04 79 clinozoisite 22.81 18.82 -3.98 -0.181 0.67979E+04 80 epidote-Fe 29.84 26.52 -3.32 -0.173 0.56771E+04 81 fayalite 14.05 10.30 -3.74 -0.534 0.63873E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68100E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57426E+04 87 glaucophane 22.97 20.84 -2.13 -0.058 0.36452E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.71002E+04 89 graphite -3.55 -4.13 -0.58 -0.166 0.99332E+03 90 greenalite 16.14 13.88 -2.25 -0.188 0.38496E+04 93 hematite 12.57 9.12 -3.44 -0.417 0.58771E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24849E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64590E+04 101 kaolinite -1.33 -4.86 -3.52 -0.320 0.60144E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16618E+04 105 lawsonite 9.62 8.20 -1.42 -0.095 0.24208E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59105E+04 108 lizardite 23.24 21.61 -1.64 -0.136 0.27941E+04 109 magnesite 0.69 -3.48 -4.17 -1.390 0.71187E+04 110 magnetite 20.09 15.85 -4.24 -0.346 0.72377E+04 111 minnesotaite 10.39 7.60 -2.79 -0.164 0.47647E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82213E+04 123 muscovite 2.58 -1.05 -3.64 -0.214 0.62087E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54478E+04 125 nepheline 8.34 5.90 -2.44 -0.348 0.41589E+04 131 periclase-Fe 11.63 6.72 -4.90 -1.226 0.83704E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36460E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21578E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92906E+03 141 pumpellyite-Fe 46.27 43.66 -2.61 -0.058 0.44610E+04 142 pumpellyite-Mg 48.99 46.23 -2.76 -0.061 0.47193E+04 145 pyrite -21.25 -21.43 -0.18 -0.043 0.31458E+03 146 pyrrhotite -4.26 -5.19 -0.93 -0.310 0.15893E+04 147 pyrrhotiteFe0.875 -6.02 -6.57 -0.55 -0.203 0.94075E+03 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22185E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84805E+04 150 quartz -2.99 -3.14 -0.15 -0.051 0.26360E+03 154 rhodochrosite -0.98 -3.53 -2.56 -0.853 0.43669E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22987E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.05 -3.44 -1.148 0.58815E+04 168 stilpnomelane-Mg 27.44 25.89 -1.55 -0.046 0.26528E+04 174 talc 16.49 15.32 -1.17 -0.069 0.19994E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46838E+04 181 tridymite -2.63 -3.14 -0.52 -0.172 0.88358E+03 182 tremolite 47.87 47.45 -0.42 -0.011 0.71803E+03 183 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66155E+04 184 troilite-low -4.41 -5.19 -0.78 -0.260 0.13321E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34829E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27313E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.94173E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18616E+04 194 zoisite 22.85 18.82 -4.02 -0.183 0.68719E+04 195 akaganeite 7.75 4.56 -3.19 -0.690 0.54513E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58290E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66009E+04 205 montmorillonite-K -2.24 -6.26 -4.02 -0.246 0.68612E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73358E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60161E+04 208 nontronite-Ca 3.21 -0.02 -3.24 -0.210 0.55291E+04 209 nontronite-H 2.53 -2.18 -4.71 -0.316 0.80425E+04 210 nontronite-K 3.34 -0.12 -3.46 -0.222 0.59125E+04 211 nontronite-Mg 3.07 -0.64 -3.72 -0.241 0.63480E+04 212 nontronite-Na 3.52 0.57 -2.95 -0.189 0.50334E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35749E+04 234 alabandite -0.98 -2.67 -1.69 -0.565 0.28931E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.63005E+04 238 dolomite,disordered 1.25 -3.20 -4.45 -0.742 0.75975E+04 239 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52713E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17971E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11698E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15092E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18583E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 MOLES Current total amount of reactant added: 0.2479900 MOLES New total amount of reactant added: 0.2489900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.8667E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.2489900 Water: Moles liquid = 0.2765E+02 kg liquid = 0.4981E+00 Moles total = -.6965E+01 kg total = -.1255E+00 Activity = 0.9994 Stoichiometric ionic strength = .5000000E-10 Osmotic coef. = 1.0000 True ionic strength = .3602392E-01 Chg. balance for total moles = -.8667E-10 Max. difference allowed = 0.1607E-06 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15527E-09 -9.8089 0.12532E-09 -9.9020 0.80714E+00 -0.0931 2 H2O 0.99942E+00 -0.0003 0.99942E+00 -0.0003 3 Cl- 0.32031E-02 -2.4944 0.25612E-02 -2.5916 0.79960E+00 -0.0971 4 SO4-- 0.90310E-09 -9.0443 0.39630E-09 -9.4020 0.43882E+00 -0.3577 5 HCO3- 0.16880E-02 -2.7726 0.13528E-02 -2.8688 0.80142E+00 -0.0961 6 HS- 0.12194E-01 -1.9139 0.97524E-02 -2.0109 0.79978E+00 -0.0970 7 Al+++ 0.65267E-28 -28.1853 0.10252E-28 -28.9892 0.15707E+00 -0.8039 8 H4SiO4 0.71745E-03 -3.1442 0.71745E-03 -3.1442 0.10000E+01 0.0000 9 Ca++ 0.40936E-06 -6.3879 0.17756E-06 -6.7506 0.43375E+00 -0.3628 10 Mg++ 0.72570E-10 -10.1392 0.31253E-10 -10.5051 0.43066E+00 -0.3659 11 Fe++ 0.19308E-12 -12.7143 0.83293E-13 -13.0794 0.43140E+00 -0.3651 12 K+ 0.26452E-03 -3.5775 0.21207E-03 -3.6735 0.80170E+00 -0.0960 13 Na+ 0.33602E-01 -1.4736 0.26859E-01 -1.5709 0.79934E+00 -0.0973 14 Mn++ 0.63693E-10 -10.1959 0.27512E-10 -10.5605 0.43195E+00 -0.3646 15 F- 0.71239E-06 -6.1473 0.56782E-06 -6.2458 0.79707E+00 -0.0985 16 HPO4-- 0.22646E-07 -7.6450 0.99400E-08 -8.0026 0.43892E+00 -0.3576 18 HSiO3- 0.66890E-02 -2.1746 0.53485E-02 -2.2718 0.79960E+00 -0.0971 19 Ca(HSiO3)+ 0.26969E-07 -7.5691 0.21628E-07 -7.6650 0.80197E+00 -0.0958 20 Mg(HSiO3)+ 0.59075E-11 -11.2286 0.47376E-11 -11.3244 0.80197E+00 -0.0958 21 NaHSiO3,aq 0.23235E-02 -2.6339 0.23235E-02 -2.6339 0.10000E+01 0.0000 22 AlO+ 0.11066E-15 -15.9560 0.88745E-16 -16.0519 0.80197E+00 -0.0958 24 HAlO2,aq 0.14094E-09 -9.8510 0.14094E-09 -9.8510 0.10000E+01 0.0000 25 AlO2- 0.31220E-05 -5.5056 0.24894E-05 -5.6039 0.79737E+00 -0.0983 26 CH4,aq 0.32319E-01 -1.4905 0.32319E-01 -1.4905 0.10000E+01 0.0000 27 C2H6,aq 0.22275E-07 -7.6522 0.22275E-07 -7.6522 0.10000E+01 0.0000 28 C3H8,aq 0.35444E-12 -12.4505 0.35444E-12 -12.4505 0.10000E+01 0.0000 29 C4H10,aq 0.55404E-17 -17.2565 0.55404E-17 -17.2565 0.10000E+01 0.0000 30 ethanol,aq 0.11806E-14 -14.9279 0.11806E-14 -14.9279 0.10000E+01 0.0000 31 CO,aq 0.73041E-13 -13.1364 0.73041E-13 -13.1364 0.10000E+01 0.0000 32 CO2,aq 0.36248E-06 -6.4407 0.36248E-06 -6.4407 0.10000E+01 0.0000 33 CO3-2 0.21557E-02 -2.6664 0.94286E-03 -3.0256 0.43737E+00 -0.3591 34 CaCO3,aq 0.20992E-05 -5.6779 0.20992E-05 -5.6779 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.76457E-08 -8.1166 0.61316E-08 -8.2124 0.80197E+00 -0.0958 36 CaCl+ 0.91770E-09 -9.0373 0.73596E-09 -9.1331 0.80197E+00 -0.0958 37 CaCl2,aq 0.44782E-12 -12.3489 0.44782E-12 -12.3489 0.10000E+01 0.0000 38 CaF+ 0.18355E-11 -11.7362 0.14720E-11 -11.8321 0.80197E+00 -0.0958 39 CaOH+ 0.12584E-06 -6.9002 0.10092E-06 -6.9960 0.80197E+00 -0.0958 40 CaSO4,aq 0.22345E-13 -13.6508 0.22345E-13 -13.6508 0.10000E+01 0.0000 41 HCl,aq 0.58818E-13 -13.2305 0.58818E-13 -13.2305 0.10000E+01 0.0000 45 HF,aq 0.48716E-12 -12.3123 0.48716E-12 -12.3123 0.10000E+01 0.0000 46 HF2- 0.11680E-18 -18.9326 0.93393E-19 -19.0297 0.79960E+00 -0.0971 48 FeCl+ 0.42104E-15 -15.3757 0.33766E-15 -15.4715 0.80197E+00 -0.0958 51 FeF+ 0.30137E-17 -17.5209 0.24169E-17 -17.6167 0.80197E+00 -0.0958 53 FeO,aq 0.20599E-09 -9.6862 0.20599E-09 -9.6862 0.10000E+01 0.0000 54 FeOH+ 0.26960E-10 -10.5693 0.21621E-10 -10.6651 0.80197E+00 -0.0958 55 HFeO2- 0.21495E-07 -7.6677 0.17188E-07 -7.7648 0.79960E+00 -0.0971 56 FeO+ 0.22712E-16 -16.6437 0.18214E-16 -16.7396 0.80197E+00 -0.0958 58 FeO2- 0.29659E-09 -9.5278 0.23716E-09 -9.6250 0.79960E+00 -0.0971 59 HFeO2,aq 0.37801E-11 -11.4225 0.37801E-11 -11.4225 0.10000E+01 0.0000 60 H2,aq 0.80167E-05 -5.0960 0.80167E-05 -5.0960 0.10000E+01 0.0000 61 KCl,aq 0.98440E-08 -8.0068 0.98440E-08 -8.0068 0.10000E+01 0.0000 63 KOH,aq 0.72221E-06 -6.1413 0.72221E-06 -6.1413 0.10000E+01 0.0000 64 KSO4- 0.16310E-11 -11.7876 0.13041E-11 -11.8847 0.79960E+00 -0.0971 65 MgCO3,aq 0.92614E-10 -10.0333 0.92614E-10 -10.0333 0.10000E+01 0.0000 66 Mg(HCO3)+ 0.13751E-11 -11.8617 0.11028E-11 -11.9575 0.80197E+00 -0.0958 67 MgCl+ 0.14640E-12 -12.8345 0.11741E-12 -12.9303 0.80197E+00 -0.0958 68 MgF+ 0.11968E-14 -14.9220 0.95977E-15 -15.0178 0.80197E+00 -0.0958 69 MgOH+ 0.12256E-09 -9.9116 0.98290E-10 -10.0075 0.80197E+00 -0.0958 71 MnF+ 0.32811E-15 -15.4840 0.26313E-15 -15.5798 0.80197E+00 -0.0958 72 MnO,aq 0.18130E-08 -8.7416 0.18130E-08 -8.7416 0.10000E+01 0.0000 73 MnOH+ 0.82727E-09 -9.0824 0.66344E-09 -9.1782 0.80197E+00 -0.0958 74 MnO2-2 0.87536E-11 -11.0578 0.38286E-11 -11.4170 0.43737E+00 -0.3591 75 HMnO2- 0.13147E-09 -9.8812 0.10512E-09 -9.9783 0.79960E+00 -0.0971 78 MnCl+ 0.54106E-12 -12.2668 0.43391E-12 -12.3626 0.80197E+00 -0.0958 79 MnSO4,aq 0.31476E-17 -17.5020 0.31476E-17 -17.5020 0.10000E+01 0.0000 80 NaCl,aq 0.22798E-04 -4.6421 0.22798E-04 -4.6421 0.10000E+01 0.0000 81 NaF,aq 0.35706E-08 -8.4473 0.35706E-08 -8.4473 0.10000E+01 0.0000 82 NaOH,aq 0.92028E-04 -4.0361 0.92028E-04 -4.0361 0.10000E+01 0.0000 84 OH- 0.57784E-02 -2.2382 0.46075E-02 -2.3365 0.79737E+00 -0.0983 89 HPO3-2 0.56810E-15 -15.2456 0.24847E-15 -15.6047 0.43737E+00 -0.3591 91 H2PO3- 0.78095E-19 -19.1074 0.62444E-19 -19.2045 0.79960E+00 -0.0971 92 H3PO4,aq 0.10919E-17 -17.9618 0.10919E-17 -17.9618 0.10000E+01 0.0000 93 H2PO4- 0.28697E-10 -10.5422 0.22980E-10 -10.6386 0.80078E+00 -0.0965 94 PO4-3 0.38159E-09 -9.4184 0.64712E-10 -10.1890 0.16958E+00 -0.7706 98 HP2O7-3 0.41944E-18 -18.3773 0.66012E-19 -19.1804 0.15738E+00 -0.8030 99 P2O7-4 0.31848E-17 -17.4969 0.12583E-18 -18.9002 0.39511E-01 -1.4033 100 H2S,aq 0.37774E-05 -5.4228 0.37774E-05 -5.4228 0.10000E+01 0.0000 101 S2-2 0.60105E-09 -9.2211 0.26288E-09 -9.5802 0.43737E+00 -0.3591 102 S3-2 0.38156E-15 -15.4184 0.16688E-15 -15.7776 0.43737E+00 -0.3591 107 SO3-2 0.92362E-15 -15.0345 0.41309E-15 -15.3840 0.44725E+00 -0.3495 108 HSO3- 0.40539E-17 -17.3921 0.32415E-17 -17.4893 0.79960E+00 -0.0971 109 HSO4- 0.59591E-16 -16.2248 0.47864E-16 -16.3200 0.80321E+00 -0.0952 111 S2O3-2 0.40229E-16 -16.3955 0.17595E-16 -16.7546 0.43737E+00 -0.3591 Charge balance for all species = -.1740E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1552704E-09 -.1705204E-01 -.1713655E+02 0.0000 2 H2O 0.1000000E+01 0.5553744E+02 0.9975615E+06 0.0000 3 Cl- 0.3203113E-02 0.3225921E-02 0.1140300E+03 7.3104 4 SO4-- 0.9030967E-09 -.3232143E-01 -.3095656E+04 10.4020 5 HCO3- 0.1688018E-02 0.3616564E-01 0.2200193E+04 7.0332 6 HS- 0.1219386E-01 0.4451907E-01 0.1467976E+04 7.8911 7 Al+++ 0.6526744E-28 0.3122126E-05 0.8399024E-01 0.7167 8 H4SiO4 0.7174488E-03 0.9729987E-02 0.9324328E+03 -3.1442 9 Ca++ 0.4093634E-06 0.2669945E-05 0.1066892E+00 13.0533 10 Mg++ 0.7257022E-10 0.2951733E-09 0.7155007E-05 9.2988 11 Fe++ 0.1930771E-12 0.2202900E-07 0.1226611E-02 6.7245 12 K+ 0.2645205E-03 0.2652526E-03 0.1034120E+02 6.2284 13 Na+ 0.3360226E-01 0.3604057E-01 0.8261125E+03 8.3311 14 Mn++ 0.6369262E-10 0.2844701E-08 0.1558195E-03 9.2435 15 F- 0.7123892E-06 0.7159622E-06 0.1356158E-01 3.6562 16 HPO4-- 0.2264644E-07 0.2305673E-07 0.2206411E-02 11.8013 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276574E+02 -.8494065E-02 -.8275724E+02 0.0000000E+00 2 H2O -.6964941E+01 0.2766464E+02 -.3462958E+02 0.0000000E+00 3 Cl- 0.1606915E-02 0.1606915E-02 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1397814E+00 -.1610014E-01 0.1558816E+00 0.0000000E+00 5 HCO3- 0.1801505E-01 0.1801505E-01 0.0000000E+00 0.0000000E+00 6 HS- -.1337055E+00 0.2217610E-01 -.1558816E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.1555212E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.4846759E-02 0.5205906E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1329969E-05 0.5750725E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.1470335E-09 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1097322E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.1321292E-03 0.1061439E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1795274E-01 0.6258424E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1417019E-08 0.8669296E-01 0.0000000E+00 15 F- 0.9969600E-04 0.3566394E-06 0.9933936E-04 0.0000000E+00 16 HPO4-- 0.2958788E-01 0.1148516E-07 0.2958787E-01 0.0000000E+00 Chg. balance for solid moles: 0.1588E-13 Mass of aqueous solution: 0.499605E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.2489900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.245 0.796 1638. 3.214 29.96 628.6 andradite 0.6235 -0.205 316.9 2.501 5.798 82.32 grossular 0.1222 -0.913 55.06 1.741 1.007 15.32 apatite-OH 0.9763E-02 -2.010 4.904 0.691 0.8974E-01 1.558 apatite-F 0.9934E-04 -4.003 0.5010E-01 -1.300 0.9167E-03 0.1565E-01 clinochlore 0.7148 -0.146 397.3 2.599 7.270 151.1 daphnite 0.1999 -0.699 142.6 2.154 2.610 43.22 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2249 3.917 microcline 0.9432 -0.025 262.5 2.419 4.804 102.5 stilbite 3.247 0.511 2288. 3.359 41.87 1067. stilpnomelane-Fe 0.2365 -0.626 255.0 2.407 4.666 88.08 tr.625ac.25prg.125 0.1087 -0.964 92.95 1.968 1.701 29.92 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8361E+00 0.8361E+00 1.0000 -0.078 grossular 0.1639E+00 0.1639E+00 1.0000 -0.785 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-F 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7669E+00 0.7669E+00 1.0000 -0.115 daphnite 0.2145E+00 0.2145E+00 1.0000 -0.669 chlorite-Mn 0.1860E-01 0.1860E-01 1.0000 -1.730 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5465.060351 g Volume = 2213.785149 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2489900 moles log = -0.6038 Original solution: 1000.0103000 g Original solution / Rock added: 4016.27 (Water/Rock Ratio), log = 3.6038 Gas composition at saturation ( 3 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 50.0801 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.2190E-01 0.9165 0.1005E+01 0.1097E+01 CO2,gas 0.8420E-06 0.9197 0.3878E-04 0.4217E-04 CH4,gas 0.9779E+00 0.9714 0.4757E+02 0.4897E+02 H2,gas 0.2046E-03 1.0270 0.1052E-01 0.1025E-01 H2S,gas 0.2501E-05 0.8291 0.1038E-03 0.1252E-03 S2,gas 0.7296E-25 1.0000 0.3654E-23 0.3654E-23 CO,gas 0.2173E-11 1.0000 0.1088E-09 0.1088E-09 SO3,gas 0.4702E-46 1.0000 0.2355E-44 0.2355E-44 SO2,gas 0.1927E-25 1.0000 0.9648E-24 0.9648E-24 HF,gas 0.2388E-16 1.0000 0.1196E-14 0.1196E-14 HCl,gas 0.2072E-17 1.0000 0.1038E-15 0.1038E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 17 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 23 andradite 39.01 39.01 0.00 0.000 0.12132E-10 24 grossular 32.73 32.73 0.00 0.000 0.24265E-10 33 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 34 apatite-F -34.30 -34.30 0.00 0.000 0.12132E-10 49 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 50 daphnite 28.97 28.97 0.00 0.000 -0.72794E-10 51 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 119 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 166 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 167 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 250 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.72794E-10 1 H2O,gas 1.70 0.00 -1.70 -1.697 0.28970E+04 2 CO2,gas -6.66 -12.77 -6.11 -2.037 0.10433E+05 3 CH4,gas 4.54 4.52 -0.02 -0.005 0.36914E+02 4 H2,gas 8.00 4.32 -3.68 -2.101 0.62780E+04 5 H2S,gas -6.23 -11.91 -5.68 -2.841 0.97029E+04 6 S2,gas -7.34 -32.47 -25.14 -3.867 0.42919E+05 7 CO,gas 3.21 -8.45 -11.66 -3.588 0.19913E+05 8 SO3,gas 17.12 -29.21 -46.33 -11.582 0.79102E+05 9 SO2,gas 0.83 -24.88 -25.71 -6.857 0.43907E+05 10 HF,gas 0.47 -16.15 -16.62 -8.311 0.28380E+05 11 HCl,gas 5.19 -12.49 -17.68 -8.841 0.30193E+05 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 12 acmite 7.71 6.61 -1.10 -0.115 0.18843E+04 16 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 20 spessartine 24.46 19.73 -4.73 -0.236 0.80699E+04 21 analcite 3.32 2.76 -0.56 -0.062 0.96007E+03 26 ankerite -2.14 -5.76 -3.63 -0.605 0.61957E+04 27 annite 20.12 17.69 -2.44 -0.135 0.41616E+04 28 phlogopite 27.06 25.41 -1.66 -0.092 0.28270E+04 30 anorthite 12.71 8.20 -4.51 -0.347 0.77043E+04 38 aragonite 0.97 0.28 -0.68 -0.228 0.11679E+04 39 brucite 12.57 9.30 -3.27 -0.654 0.55839E+04 40 calcite 0.81 0.28 -0.53 -0.176 0.90363E+03 41 carnegieite-low 9.02 5.90 -3.12 -0.446 0.53269E+04 42 carnegieite-high 10.09 5.90 -4.19 -0.599 0.71539E+04 43 carpholite-Mg 8.58 4.44 -4.14 -0.276 0.70669E+04 44 carpholite-Fe 6.71 1.87 -4.84 -0.323 0.82704E+04 45 celadonite 5.34 3.67 -1.67 -0.098 0.28574E+04 46 celadonite-Fe 3.88 1.09 -2.78 -0.164 0.47514E+04 47 chrysotile 23.89 21.61 -2.28 -0.190 0.39009E+04 52 chlorite-Al-free 47.17 43.22 -3.96 -0.165 0.67570E+04 54 chloritoid-Fe 9.17 5.01 -4.16 -0.277 0.71042E+04 55 chloritoid-Mn 11.40 7.53 -3.87 -0.258 0.66066E+04 57 coesite -2.38 -3.14 -0.77 -0.256 0.13107E+04 64 cristobalite -2.56 -3.14 -0.58 -0.194 0.99608E+03 66 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71238E+04 68 diaspore 2.87 0.72 -2.16 -0.360 0.36839E+04 69 diamond -3.10 -4.12 -1.02 -0.292 0.17443E+04 70 diopside 16.18 16.06 -0.12 -0.012 0.20007E+03 71 hedenbergite 14.21 13.49 -0.72 -0.072 0.12266E+04 72 dolomite,ordered 0.55 -3.19 -3.74 -0.623 0.63786E+04 74 enstatite 17.26 12.31 -4.96 -0.496 0.84608E+04 76 clinoenstatite 17.17 12.31 -4.86 -0.486 0.82924E+04 78 epidote 24.67 22.67 -2.00 -0.097 0.34147E+04 79 clinozoisite 22.81 18.82 -3.98 -0.181 0.67997E+04 80 epidote-Fe 29.84 26.52 -3.32 -0.173 0.56763E+04 81 fayalite 14.05 10.30 -3.74 -0.534 0.63874E+04 82 ferrosilite 11.15 7.16 -3.99 -0.399 0.68099E+04 86 gibbsite 4.08 0.72 -3.36 -0.480 0.57429E+04 87 glaucophane 22.97 20.84 -2.13 -0.058 0.36446E+04 88 glaucophane-Fe 17.28 13.12 -4.16 -0.112 0.71003E+04 89 graphite -3.55 -4.12 -0.58 -0.165 0.98653E+03 90 greenalite 16.14 13.88 -2.25 -0.188 0.38496E+04 93 hematite 12.57 9.13 -3.44 -0.417 0.58752E+04 94 heulandite -5.83 -7.52 -1.69 -0.077 0.28934E+04 98 jadeite 4.22 2.76 -1.46 -0.146 0.24851E+04 100 kalsilite 7.58 3.80 -3.78 -0.540 0.64594E+04 101 kaolinite -1.33 -4.86 -3.52 -0.320 0.60146E+04 104 laumontite 2.88 1.91 -0.97 -0.065 0.16624E+04 105 lawsonite 9.62 8.20 -1.42 -0.095 0.24218E+04 106 leucite 4.12 0.66 -3.46 -0.346 0.59107E+04 108 lizardite 23.24 21.61 -1.64 -0.136 0.27935E+04 109 magnesite 0.69 -3.47 -4.16 -1.388 0.71074E+04 110 magnetite 20.09 15.85 -4.24 -0.346 0.72359E+04 111 minnesotaite 10.39 7.60 -2.79 -0.164 0.47644E+04 115 manganosite 14.06 9.24 -4.81 -1.204 0.82213E+04 123 muscovite 2.58 -1.05 -3.64 -0.214 0.62093E+04 124 paragonite 4.24 1.05 -3.19 -0.188 0.54484E+04 125 nepheline 8.34 5.90 -2.44 -0.348 0.41593E+04 131 periclase-Fe 11.63 6.72 -4.90 -1.226 0.83705E+04 137 phlogopite-Na 29.65 27.51 -2.14 -0.119 0.36458E+04 139 prehnite 19.37 18.11 -1.26 -0.074 0.21592E+04 140 prehnite-Fe 22.50 21.95 -0.54 -0.033 0.92924E+03 141 pumpellyite-Fe 46.27 43.65 -2.61 -0.058 0.44644E+04 142 pumpellyite-Mg 48.99 46.23 -2.77 -0.061 0.47225E+04 145 pyrite -21.25 -21.42 -0.18 -0.042 0.30265E+03 146 pyrrhotite -4.26 -5.19 -0.93 -0.309 0.15845E+04 147 pyrrhotiteFe0.875 -6.02 -6.56 -0.55 -0.202 0.93568E+03 148 pyroxmangite 7.40 6.10 -1.30 -0.260 0.22183E+04 149 pyrophyllite -6.18 -11.14 -4.97 -0.310 0.84804E+04 150 quartz -2.99 -3.14 -0.15 -0.051 0.26341E+03 154 rhodochrosite -0.98 -3.53 -2.55 -0.850 0.43557E+04 155 rhodonite 7.45 6.10 -1.35 -0.269 0.22986E+04 156 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 158 siderite -2.61 -6.05 -3.44 -1.146 0.58704E+04 168 stilpnomelane-Mg 27.44 25.89 -1.55 -0.046 0.26517E+04 174 talc 16.49 15.32 -1.17 -0.069 0.19985E+04 177 tephroite 18.09 15.34 -2.74 -0.392 0.46838E+04 181 tridymite -2.63 -3.14 -0.52 -0.172 0.88339E+03 182 tremolite 47.87 47.45 -0.42 -0.011 0.71755E+03 183 ferroactinolite 38.45 34.58 -3.87 -0.105 0.66161E+04 184 troilite-low -4.41 -5.19 -0.78 -0.259 0.13273E+04 190 wairakite 3.95 1.91 -2.04 -0.120 0.34835E+04 191 walstromite 11.51 9.91 -1.60 -0.320 0.27318E+04 192 wollastonite 10.46 9.91 -0.55 -0.110 0.94223E+03 193 pseudo-wollastonite 11.00 9.91 -1.09 -0.218 0.18621E+04 194 zoisite 22.85 18.82 -4.03 -0.183 0.68737E+04 195 akaganeite 7.75 4.56 -3.19 -0.690 0.54504E+04 202 chalcedony -2.80 -3.14 -0.34 -0.114 0.58271E+03 204 montmorillonite-Ca -2.29 -6.16 -3.87 -0.239 0.66008E+04 205 montmorillonite-K -2.24 -6.25 -4.02 -0.246 0.68610E+04 206 montmorillonite-Mg -2.48 -6.78 -4.30 -0.266 0.73356E+04 207 montmorillonite-Na -2.04 -5.56 -3.52 -0.216 0.60159E+04 208 nontronite-Ca 3.21 -0.02 -3.24 -0.210 0.55267E+04 209 nontronite-H 2.53 -2.18 -4.71 -0.316 0.80400E+04 210 nontronite-K 3.34 -0.12 -3.46 -0.222 0.59101E+04 211 nontronite-Mg 3.07 -0.64 -3.72 -0.241 0.63455E+04 212 nontronite-Na 3.52 0.57 -2.95 -0.189 0.50310E+04 228 tobermorite 9.82 7.73 -2.09 -0.571 0.35753E+04 234 alabandite -0.98 -2.67 -1.69 -0.564 0.28882E+04 237 boehmite 4.41 0.72 -3.69 -0.615 0.63008E+04 238 dolomite,disordered 1.25 -3.19 -4.44 -0.739 0.75756E+04 239 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52715E+04 245 silica-amorphous -2.09 -3.14 -1.05 -0.351 0.17969E+04 247 an20ab80 2.02 1.33 -0.69 -0.053 0.11700E+04 248 an25ab75 2.65 1.76 -0.88 -0.068 0.15095E+04 249 an30ab70 3.28 2.19 -1.09 -0.084 0.18586E+04 ******** WARNING ******** Computational singularity, IV(N) = 0.0