File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.33117E+02 0.88347E-10 0.8402 0.00000000E+00 H2O 2 0. 0.30437E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.17219E-03 0.8352 0.00000000E+00 SO4-- 4 -2. 0.55452E-01 0.81138E-12 0.5192 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.30024E-06 0.8364 0.00000000E+00 HS- 6 -1. -0.55427E-01 0.31970E-04 0.8353 0.00000000E+00 Al+++ 7 3. 0.65215E+01 0.97106E-29 0.2309 0.00000000E+00 H4SiO4 8 0. 0.20826E+02 0.69596E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.23003E+01 0.13516E-06 0.5154 0.00000000E+00 Mg++ 10 2. 0.15873E+01 0.21145E-10 0.5131 0.00000000E+00 Fe++ 11 2. 0.14260E+01 0.58279E-13 0.5136 0.00000000E+00 K+ 12 1. 0.42463E+00 0.15661E-03 0.8366 0.00000000E+00 Na+ 13 1. 0.25106E+01 0.19873E-01 0.8350 0.00000000E+00 Mn++ 14 2. 0.34677E-01 0.18646E-10 0.5140 0.00000000E+00 HPO4-- 15 -2. 0.11835E-01 0.45274E-07 0.5193 0.00000000E+00 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.500000E+04 TEMP = 100.0000 SINC = 0.1000E+03 TEMPC = 0.0000 TOTMIX = 0.200000E+04 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 800.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.2491E+01 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.2219E+00 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.5373E-01 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.3945E-02 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.1294E+01 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.1045E+00 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.2849E+00 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.8247E-01 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.6935E-02 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.9952E-01 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.2581E-01 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.0000E+00 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.0000E+00 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.3723E+00 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.1747E-01 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 1999.9990000 g log = 3.3010 Original solution: 1000.0103000 g Original solution / Rock added: 0.50 (Water/Rock Ratio), log = -0.3010 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 1999.9990000 Water: Moles liquid = 0.4427E+02 kg liquid = 0.7976E+00 Moles total = 0.3044E+02 kg total = 0.5483E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134661E-01 Osmotic coef. = 0.9692 True ionic strength = .2003063E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88347E-10 -10.0538 0.74231E-10 -10.1294 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17219E-03 -3.7640 0.14381E-03 -3.8422 0.83516E+00 -0.0782 4 SO4-- 0.81138E-12 -12.0908 0.42129E-12 -12.3754 0.51922E+00 -0.2846 5 HCO3- 0.30024E-06 -6.5225 0.25112E-06 -6.6001 0.83639E+00 -0.0776 6 HS- 0.31970E-04 -4.4953 0.26704E-04 -4.5734 0.83529E+00 -0.0782 7 Al+++ 0.97106E-29 -29.0128 0.22426E-29 -29.6492 0.23095E+00 -0.6365 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13516E-06 -6.8691 0.69664E-07 -7.1570 0.51541E+00 -0.2878 10 Mg++ 0.21145E-10 -10.6748 0.10849E-10 -10.9646 0.51305E+00 -0.2898 11 Fe++ 0.58279E-13 -13.2345 0.29933E-13 -13.5239 0.51361E+00 -0.2894 12 K+ 0.15661E-03 -3.8052 0.13102E-03 -3.8827 0.83658E+00 -0.0775 13 Na+ 0.19873E-01 -1.7017 0.16594E-01 -1.7800 0.83501E+00 -0.0783 14 Mn++ 0.18646E-10 -10.7294 0.95848E-11 -11.0184 0.51404E+00 -0.2890 15 HPO4-- 0.45274E-07 -7.3442 0.23511E-07 -7.6287 0.51930E+00 -0.2846 16 HSiO3- 0.10482E-01 -1.9795 0.87544E-02 -2.0578 0.83516E+00 -0.0782 17 Ca(HSiO3)+ 0.16598E-07 -7.7799 0.13889E-07 -7.8573 0.83676E+00 -0.0774 18 Mg(HSiO3)+ 0.32169E-11 -11.4926 0.26918E-11 -11.5700 0.83676E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66171E-16 -16.1793 0.55370E-16 -16.2567 0.83676E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53136E-05 -5.2746 0.44297E-05 -5.3536 0.83366E+00 -0.0790 24 CH4,aq 0.15516E-04 -4.8092 0.15462E-04 -4.8107 0.99654E+00 -0.0015 25 C2H6,aq 0.35406E-14 -14.4509 0.35283E-14 -14.4524 0.99654E+00 -0.0015 29 CO,aq 0.11590E-16 -16.9359 0.11590E-16 -16.9359 0.10000E+01 0.0000 30 CO2,aq 0.39969E-10 -10.3983 0.39830E-10 -10.3998 0.99654E+00 -0.0015 31 CO3-2 0.57030E-06 -6.2439 0.29548E-06 -6.5295 0.51812E+00 -0.2856 32 CaCO3,aq 0.25811E-09 -9.5882 0.25811E-09 -9.5882 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53366E-12 -12.2727 0.44655E-12 -12.3501 0.83676E+00 -0.0774 34 CaCl+ 0.19376E-10 -10.7127 0.16213E-10 -10.7901 0.83676E+00 -0.0774 35 CaCl2,aq 0.55392E-15 -15.2565 0.55392E-15 -15.2565 0.10000E+01 0.0000 36 CaOH+ 0.79933E-07 -7.0973 0.66885E-07 -7.1747 0.83676E+00 -0.0774 37 CaSO4,aq 0.93195E-17 -17.0306 0.93195E-17 -17.0306 0.10000E+01 0.0000 38 HCl,aq 0.19562E-14 -14.7086 0.19562E-14 -14.7086 0.10000E+01 0.0000 43 FeCl+ 0.81426E-17 -17.0892 0.68135E-17 -17.1666 0.83676E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15686E-10 -10.8045 0.13126E-10 -10.8819 0.83676E+00 -0.0774 48 HFeO2- 0.35633E-07 -7.4481 0.29759E-07 -7.5264 0.83516E+00 -0.0782 49 FeO+ 0.10993E-16 -16.9589 0.91989E-17 -17.0363 0.83676E+00 -0.0774 51 FeO2- 0.40902E-09 -9.3883 0.34160E-09 -9.4665 0.83516E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.34148E-09 -9.4666 0.34148E-09 -9.4666 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10255E-14 -14.9890 0.85650E-15 -15.0673 0.83516E+00 -0.0782 58 MgCO3,aq 0.10075E-13 -13.9968 0.10075E-13 -13.9968 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.84918E-16 -16.0710 0.71057E-16 -16.1484 0.83676E+00 -0.0774 60 MgCl+ 0.27347E-14 -14.5631 0.22883E-14 -14.6405 0.83676E+00 -0.0774 61 MgOH+ 0.68880E-10 -10.1619 0.57636E-10 -10.2393 0.83676E+00 -0.0774 63 MnO,aq 0.18014E-08 -8.7444 0.18014E-08 -8.7444 0.10000E+01 0.0000 64 MnOH+ 0.46662E-09 -9.3310 0.39045E-09 -9.4084 0.83676E+00 -0.0774 65 MnO2-2 0.20940E-10 -10.6790 0.10850E-10 -10.9646 0.51812E+00 -0.2856 66 HMnO2- 0.21127E-09 -9.6752 0.17644E-09 -9.7534 0.83516E+00 -0.0782 69 MnCl+ 0.10144E-13 -13.9938 0.84880E-14 -14.0712 0.83676E+00 -0.0774 71 NaCl,aq 0.79085E-06 -6.1019 0.79085E-06 -6.1019 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93366E-02 -2.0298 0.77835E-02 -2.1088 0.83366E+00 -0.0790 79 HPO3-2 0.16380E-14 -14.7857 0.84869E-15 -15.0713 0.51812E+00 -0.2856 81 H2PO3- 0.15126E-18 -18.8203 0.12633E-18 -18.8985 0.83516E+00 -0.0782 82 H3PO4,aq 0.90606E-18 -18.0428 0.90606E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38512E-10 -10.4144 0.32194E-10 -10.4922 0.83596E+00 -0.0778 84 PO4-3 0.10653E-08 -8.9725 0.25841E-09 -9.5877 0.24257E+00 -0.6152 88 HP2O7-3 0.94565E-18 -18.0243 0.21861E-18 -18.6603 0.23118E+00 -0.6361 89 P2O7-4 0.91303E-17 -17.0395 0.70357E-18 -18.1527 0.77059E-01 -1.1132 90 H2S,aq 0.61477E-08 -8.2113 0.61264E-08 -8.2128 0.99654E+00 -0.0015 91 S2-2 0.26328E-14 -14.5796 0.13641E-14 -14.8652 0.51812E+00 -0.2856 97 SO3-2 0.12065E-17 -17.9185 0.63415E-18 -18.1978 0.52562E+00 -0.2793 99 HSO4- 0.35982E-19 -19.4439 0.30138E-19 -19.5209 0.83758E+00 -0.0770 Charge balance for all species = 0.6546E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8834674E-10 -.2229013E-01 -.2242806E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981989E+06 0.0000 3 Cl- 0.1721924E-03 0.1729836E-03 0.6122127E+01 6.2872 4 SO4-- 0.8113774E-12 -.1842139E-04 -.1766512E+01 7.8834 5 HCO3- 0.3002393E-06 0.1638637E-04 0.9981123E+00 3.5293 6 HS- 0.3196980E-04 0.5039734E-04 0.1663843E+01 5.5560 7 Al+++ 0.9710648E-29 0.5313773E-05 0.1431243E+00 0.7390 8 H4SiO4 0.6959572E-03 0.1352779E-01 0.1297968E+04 -3.1574 9 Ca++ 0.1351622E-06 0.2319717E-06 0.9280798E-02 13.1018 10 Mg++ 0.2114527E-10 0.9325458E-10 0.2263264E-05 9.2942 11 Fe++ 0.5827877E-13 0.3627213E-07 0.2022168E-02 6.7350 12 K+ 0.1566089E-03 0.1573630E-03 0.6142512E+01 6.2467 13 Na+ 0.1987290E-01 0.2231930E-01 0.5122243E+03 8.3494 14 Mn++ 0.1864599E-10 0.2518880E-08 0.1381416E-03 9.2404 15 HPO4-- 0.4527408E-07 0.4637792E-07 0.4443568E-02 12.6301 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311700E+02 -.1777892E-01 -.3309922E+02 0.0000000E+00 2 H2O 0.3043744E+02 0.4427148E+02 -.1383404E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5545229E-01 -.1469316E-04 0.5546699E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542679E-01 0.4019763E-04 -.5546699E-01 0.0000000E+00 7 Al+++ 0.6521480E+01 0.4238340E-05 0.6521476E+01 0.0000000E+00 8 H4SiO4 0.2082556E+02 0.1078995E-01 0.2081477E+02 0.0000000E+00 9 Ca++ 0.2300299E+01 0.1850239E-06 0.2300298E+01 0.0000000E+00 10 Mg++ 0.1587301E+01 0.7438117E-10 0.1587301E+01 0.0000000E+00 11 Fe++ 0.1426016E+01 0.2893117E-07 0.1426016E+01 0.0000000E+00 12 K+ 0.4246282E+00 0.1255150E-03 0.4245027E+00 0.0000000E+00 13 Na+ 0.2510646E+01 0.1780219E-01 0.2492844E+01 0.0000000E+00 14 Mn++ 0.3467717E-01 0.2009094E-08 0.3467717E-01 0.0000000E+00 15 HPO4-- 0.1183515E-01 0.3699168E-07 0.1183511E-01 0.0000000E+00 Chg. balance for solid moles: -.9374E-14 Mass of aqueous solution: 0.799003E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 1999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.491 0.396 653.1 2.815 29.89 250.7 andradite 0.2219 -0.654 112.7 2.052 5.161 29.29 grossular 0.5373E-01 -1.270 24.20 1.384 1.108 6.734 apatite-OH 0.3945E-02 -2.404 1.982 0.297 0.9070E-01 0.6297 clinochlore 0.2849 -0.545 158.4 2.200 7.248 60.23 daphnite 0.8247E-01 -1.084 58.84 1.770 2.693 17.83 chlorite-Mn 0.6935E-02 -2.159 4.917 0.692 0.2251 1.567 diopside 0.9952E-01 -1.002 21.55 1.333 0.9865 6.587 hedenbergite 0.2581E-01 -1.588 6.403 0.806 0.2931 1.754 microcline 0.3723 -0.429 103.6 2.015 4.743 40.48 stilbite 1.294 0.112 911.6 2.960 41.72 425.2 stilpnomelane-Fe 0.1045 -0.981 112.6 2.052 5.154 38.90 tr.625ac.25prg.125 0.1747E-01 -1.758 14.93 1.174 0.6834 4.806 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1853E-01 0.1853E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2184.817926 g Volume = 884.685933 cm3 Porosity: -10.4477% V(tot) - V(min): -.83686E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1999.9990000 g log = 3.3010 Original solution: 1000.0103000 g Original solution / Rock added: 0.50 (Water/Rock Ratio), log = -0.3010 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0585 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9644E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.3998E-08 1.0069 0.4261E-08 0.4232E-08 CH4,gas 0.2124E-01 1.0124 0.2276E-01 0.2248E-01 H2,gas 0.1436E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1598E-06 0.9959 0.1684E-06 0.1691E-06 S2,gas 0.4349E-29 1.0000 0.4603E-29 0.4603E-29 CO,gas 0.1632E-13 1.0000 0.1727E-13 0.1727E-13 SO3,gas 0.8292E-48 1.0000 0.8777E-48 0.8777E-48 SO2,gas 0.4906E-27 1.0000 0.5193E-27 0.5193E-27 HCl,gas 0.3261E-17 1.0000 0.3452E-17 0.3452E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.73 -10.07 -3.356 0.17193E+05 -8.370 3 CH4,gas 4.54 1.20 -3.34 -0.835 0.57061E+04 -1.643 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.70 -8.47 -4.236 0.14467E+05 -6.774 6 S2,gas -7.34 -38.37 -31.04 -4.775 0.52993E+05 -29.337 7 CO,gas 3.21 -12.25 -15.46 -4.757 0.26400E+05 -13.763 8 SO3,gas 17.12 -32.63 -49.76 -12.439 0.84956E+05 -48.057 9 SO2,gas 0.83 -28.15 -28.98 -7.729 0.49489E+05 -27.285 10 HCl,gas 5.19 -13.97 -19.16 -9.580 0.32717E+05 -17.462 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80769E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28488E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.63 -4.59 -1.531 0.78445E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.63 -4.44 -1.480 0.75803E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65568E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.76 -4.66 -1.332 0.79593E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.76 -4.22 -1.205 0.72015E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82261E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40578E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43416E+04 143 pyrrhotite -4.26 -7.97 -3.71 -1.236 0.63305E+04 144 pyrrhotiteFe0.875 -6.02 -9.37 -3.35 -1.232 0.57177E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22465E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23267E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47167E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.97 -3.56 -1.186 0.60733E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79430E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.46 -4.48 -1.495 0.76573E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 1999.9990000 g New total amount of reactant added: 2099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2099.9990000 Water: Moles liquid = 0.4372E+02 kg liquid = 0.7876E+00 Moles total = 0.2918E+02 kg total = 0.5258E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134844E-01 Osmotic coef. = 0.9691 True ionic strength = .2003206E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88353E-10 -10.0538 0.74236E-10 -10.1294 0.84022E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17439E-03 -3.7585 0.14564E-03 -3.8367 0.83516E+00 -0.0782 4 SO4-- 0.82170E-12 -12.0853 0.42664E-12 -12.3699 0.51921E+00 -0.2847 5 HCO3- 0.30406E-06 -6.5170 0.25431E-06 -6.5946 0.83638E+00 -0.0776 6 HS- 0.32377E-04 -4.4898 0.27044E-04 -4.5679 0.83528E+00 -0.0782 7 Al+++ 0.97129E-29 -29.0126 0.22431E-29 -29.6492 0.23094E+00 -0.6365 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13518E-06 -6.8691 0.69673E-07 -7.1569 0.51540E+00 -0.2879 10 Mg++ 0.21148E-10 -10.6747 0.10850E-10 -10.9646 0.51304E+00 -0.2898 11 Fe++ 0.58288E-13 -13.2344 0.29937E-13 -13.5238 0.51360E+00 -0.2894 12 K+ 0.15662E-03 -3.8052 0.13103E-03 -3.8826 0.83658E+00 -0.0775 13 Na+ 0.19874E-01 -1.7017 0.16595E-01 -1.7800 0.83501E+00 -0.0783 14 Mn++ 0.18653E-10 -10.7293 0.95881E-11 -11.0183 0.51403E+00 -0.2890 15 HPO4-- 0.45269E-07 -7.3442 0.23508E-07 -7.6288 0.51929E+00 -0.2846 16 HSiO3- 0.10482E-01 -1.9796 0.87538E-02 -2.0578 0.83516E+00 -0.0782 17 Ca(HSiO3)+ 0.16600E-07 -7.7799 0.13890E-07 -7.8573 0.83676E+00 -0.0774 18 Mg(HSiO3)+ 0.32171E-11 -11.4925 0.26919E-11 -11.5699 0.83676E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66175E-16 -16.1793 0.55373E-16 -16.2567 0.83676E+00 -0.0774 22 HAlO2,aq 0.14855E-09 -9.8281 0.14855E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53133E-05 -5.2746 0.44294E-05 -5.3537 0.83365E+00 -0.0790 24 CH4,aq 0.15713E-04 -4.8037 0.15659E-04 -4.8052 0.99654E+00 -0.0015 25 C2H6,aq 0.36315E-14 -14.4399 0.36189E-14 -14.4414 0.99654E+00 -0.0015 29 CO,aq 0.11738E-16 -16.9304 0.11738E-16 -16.9304 0.10000E+01 0.0000 30 CO2,aq 0.40479E-10 -10.3928 0.40339E-10 -10.3943 0.99654E+00 -0.0015 31 CO3-2 0.57752E-06 -6.2384 0.29922E-06 -6.5240 0.51811E+00 -0.2856 32 CaCO3,aq 0.26141E-09 -9.5827 0.26141E-09 -9.5827 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54051E-12 -12.2672 0.45228E-12 -12.3446 0.83676E+00 -0.0774 34 CaCl+ 0.19625E-10 -10.7072 0.16422E-10 -10.7846 0.83676E+00 -0.0774 35 CaCl2,aq 0.56821E-15 -15.2455 0.56821E-15 -15.2455 0.10000E+01 0.0000 36 CaOH+ 0.79938E-07 -7.0972 0.66889E-07 -7.1746 0.83676E+00 -0.0774 37 CaSO4,aq 0.94391E-17 -17.0251 0.94391E-17 -17.0251 0.10000E+01 0.0000 38 HCl,aq 0.19812E-14 -14.7031 0.19812E-14 -14.7031 0.10000E+01 0.0000 43 FeCl+ 0.82476E-17 -17.0837 0.69012E-17 -17.1611 0.83676E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15688E-10 -10.8044 0.13127E-10 -10.8818 0.83676E+00 -0.0774 48 HFeO2- 0.35631E-07 -7.4482 0.29757E-07 -7.5264 0.83516E+00 -0.0782 49 FeO+ 0.10994E-16 -16.9588 0.91995E-17 -17.0362 0.83676E+00 -0.0774 51 FeO2- 0.40900E-09 -9.3883 0.34158E-09 -9.4665 0.83516E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.34586E-09 -9.4611 0.34586E-09 -9.4611 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10387E-14 -14.9835 0.86744E-15 -15.0618 0.83516E+00 -0.0782 58 MgCO3,aq 0.10204E-13 -13.9912 0.10204E-13 -13.9912 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86009E-16 -16.0655 0.71969E-16 -16.1429 0.83676E+00 -0.0774 60 MgCl+ 0.27700E-14 -14.5575 0.23178E-14 -14.6349 0.83676E+00 -0.0774 61 MgOH+ 0.68884E-10 -10.1619 0.57640E-10 -10.2393 0.83676E+00 -0.0774 63 MnO,aq 0.18018E-08 -8.7443 0.18018E-08 -8.7443 0.10000E+01 0.0000 64 MnOH+ 0.46675E-09 -9.3309 0.39056E-09 -9.4083 0.83676E+00 -0.0774 65 MnO2-2 0.20942E-10 -10.6790 0.10850E-10 -10.9646 0.51811E+00 -0.2856 66 HMnO2- 0.21130E-09 -9.6751 0.17647E-09 -9.7533 0.83516E+00 -0.0782 69 MnCl+ 0.10277E-13 -13.9881 0.85991E-14 -14.0655 0.83676E+00 -0.0774 71 NaCl,aq 0.80099E-06 -6.0964 0.80099E-06 -6.0964 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93360E-02 -2.0298 0.77830E-02 -2.1089 0.83365E+00 -0.0790 79 HPO3-2 0.16378E-14 -14.7857 0.84857E-15 -15.0713 0.51811E+00 -0.2856 81 H2PO3- 0.15126E-18 -18.8203 0.12632E-18 -18.8985 0.83516E+00 -0.0782 82 H3PO4,aq 0.90606E-18 -18.0428 0.90606E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38510E-10 -10.4144 0.32192E-10 -10.4922 0.83595E+00 -0.0778 84 PO4-3 0.10652E-08 -8.9726 0.25836E-09 -9.5878 0.24256E+00 -0.6152 88 HP2O7-3 0.94551E-18 -18.0243 0.21857E-18 -18.6604 0.23117E+00 -0.6361 89 P2O7-4 0.91286E-17 -17.0396 0.70339E-18 -18.1528 0.77053E-01 -1.1132 90 H2S,aq 0.62264E-08 -8.2058 0.62049E-08 -8.2073 0.99654E+00 -0.0015 91 S2-2 0.27004E-14 -14.5686 0.13991E-14 -14.8542 0.51811E+00 -0.2856 97 SO3-2 0.12218E-17 -17.9130 0.64220E-18 -18.1923 0.52561E+00 -0.2793 99 HSO4- 0.36442E-19 -19.4384 0.30523E-19 -19.5154 0.83758E+00 -0.0770 Charge balance for all species = 0.6629E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8835301E-10 -.2228895E-01 -.2242686E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981988E+06 0.0000 3 Cl- 0.1743881E-03 0.1751894E-03 0.6200192E+01 6.2927 4 SO4-- 0.8216999E-12 -.1861928E-04 -.1785488E+01 7.8888 5 HCO3- 0.3040572E-06 0.1659532E-04 0.1010840E+01 3.5347 6 HS- 0.3237746E-04 0.5100297E-04 0.1683838E+01 5.5615 7 Al+++ 0.9712926E-29 0.5313406E-05 0.1431144E+00 0.7390 8 H4SiO4 0.6959590E-03 0.1352717E-01 0.1297909E+04 -3.1574 9 Ca++ 0.1351824E-06 0.2320021E-06 0.9282015E-02 13.1018 10 Mg++ 0.2114843E-10 0.9326324E-10 0.2263474E-05 9.2942 11 Fe++ 0.5828758E-13 0.3626988E-07 0.2022042E-02 6.7350 12 K+ 0.1566201E-03 0.1573742E-03 0.6142946E+01 6.2467 13 Na+ 0.1987431E-01 0.2232073E-01 0.5122571E+03 8.3494 14 Mn++ 0.1865276E-10 0.2519431E-08 0.1381718E-03 9.2405 15 HPO4-- 0.4526910E-07 0.4637278E-07 0.4443075E-02 12.6300 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3477285E+02 -.1755414E-01 -.3475530E+02 0.0000000E+00 2 H2O 0.2918390E+02 0.4371407E+02 -.1453017E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5822364E-01 -.1466401E-04 0.5823830E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5819813E-01 0.4016848E-04 -.5823830E-01 0.0000000E+00 7 Al+++ 0.6847554E+01 0.4184687E-05 0.6847550E+01 0.0000000E+00 8 H4SiO4 0.2186683E+02 0.1065362E-01 0.2185618E+02 0.0000000E+00 9 Ca++ 0.2415313E+01 0.1827182E-06 0.2415313E+01 0.0000000E+00 10 Mg++ 0.1666666E+01 0.7345147E-10 0.1666666E+01 0.0000000E+00 11 Fe++ 0.1497317E+01 0.2856512E-07 0.1497317E+01 0.0000000E+00 12 K+ 0.4458597E+00 0.1239434E-03 0.4457357E+00 0.0000000E+00 13 Na+ 0.2636170E+01 0.1757917E-01 0.2618591E+01 0.0000000E+00 14 Mn++ 0.3641103E-01 0.1984232E-08 0.3641103E-01 0.0000000E+00 15 HPO4-- 0.1242690E-01 0.3652188E-07 0.1242687E-01 0.0000000E+00 Chg. balance for solid moles: -.2335E-14 Mass of aqueous solution: 0.788943E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.616 0.418 686.0 2.836 29.91 263.4 andradite 0.2330 -0.633 118.4 2.073 5.160 30.76 grossular 0.5641E-01 -1.249 25.41 1.405 1.108 7.071 apatite-OH 0.4142E-02 -2.383 2.081 0.318 0.9070E-01 0.6612 clinochlore 0.2991 -0.524 166.2 2.221 7.246 63.23 daphnite 0.8658E-01 -1.063 61.77 1.791 2.693 18.72 chlorite-Mn 0.7282E-02 -2.138 5.163 0.713 0.2251 1.645 diopside 0.1050 -0.979 22.73 1.357 0.9908 6.947 hedenbergite 0.2722E-01 -1.565 6.753 0.830 0.2944 1.850 microcline 0.3909 -0.408 108.8 2.037 4.743 42.50 stilbite 1.358 0.133 956.8 2.981 41.71 446.3 stilpnomelane-Fe 0.1097 -0.960 118.2 2.073 5.154 40.84 tr.625ac.25prg.125 0.1830E-01 -1.737 15.64 1.194 0.6820 5.035 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1853E-01 0.1853E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2294.068590 g Volume = 928.888997 cm3 Porosity: -10.4506% V(tot) - V(min): -.87889E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2099.9990000 g log = 3.3222 Original solution: 1000.0103000 g Original solution / Rock added: 0.48 (Water/Rock Ratio), log = -0.3222 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0588 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9641E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4048E-08 1.0069 0.4316E-08 0.4286E-08 CH4,gas 0.2150E-01 1.0124 0.2305E-01 0.2277E-01 H2,gas 0.1435E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1618E-06 0.9959 0.1706E-06 0.1713E-06 S2,gas 0.4460E-29 1.0000 0.4722E-29 0.4722E-29 CO,gas 0.1652E-13 1.0000 0.1749E-13 0.1749E-13 SO3,gas 0.8396E-48 1.0000 0.8890E-48 0.8890E-48 SO2,gas 0.4968E-27 1.0000 0.5260E-27 0.5260E-27 HCl,gas 0.3302E-17 1.0000 0.3496E-17 0.3496E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.72 -10.06 -3.355 0.17184E+05 -8.365 3 CH4,gas 4.54 1.21 -3.34 -0.834 0.56967E+04 -1.637 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.70 -8.47 -4.234 0.14457E+05 -6.768 6 S2,gas -7.34 -38.36 -31.02 -4.773 0.52974E+05 -29.326 7 CO,gas 3.21 -12.24 -15.46 -4.756 0.26391E+05 -13.757 8 SO3,gas 17.12 -32.63 -49.75 -12.438 0.84947E+05 -48.051 9 SO2,gas 0.83 -28.15 -28.98 -7.727 0.49479E+05 -27.279 10 HCl,gas 5.19 -13.97 -19.16 -9.578 0.32707E+05 -17.456 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.237 0.80764E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.62 -4.59 -1.530 0.78351E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.62 -4.43 -1.478 0.75709E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68935E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65566E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.76 -4.66 -1.330 0.79499E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.76 -4.21 -1.203 0.71921E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82259E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91155E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 143 pyrrhotite -4.26 -7.96 -3.70 -1.234 0.63211E+04 144 pyrrhotiteFe0.875 -6.02 -9.36 -3.34 -1.230 0.57083E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22463E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23266E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47164E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.96 -3.55 -1.184 0.60639E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79431E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66607E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.46 -4.48 -1.493 0.76477E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2099.9990000 g New total amount of reactant added: 2199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2199.9990000 Water: Moles liquid = 0.4316E+02 kg liquid = 0.7775E+00 Moles total = 0.2793E+02 kg total = 0.5032E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135032E-01 Osmotic coef. = 0.9691 True ionic strength = .2003353E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88359E-10 -10.0537 0.74241E-10 -10.1294 0.84021E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17664E-03 -3.7529 0.14752E-03 -3.8311 0.83516E+00 -0.0782 4 SO4-- 0.83229E-12 -12.0797 0.43213E-12 -12.3644 0.51920E+00 -0.2847 5 HCO3- 0.30797E-06 -6.5115 0.25758E-06 -6.5891 0.83638E+00 -0.0776 6 HS- 0.32796E-04 -4.4842 0.27394E-04 -4.5624 0.83528E+00 -0.0782 7 Al+++ 0.97153E-29 -29.0125 0.22435E-29 -29.6491 0.23093E+00 -0.6365 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13520E-06 -6.8690 0.69682E-07 -7.1569 0.51539E+00 -0.2879 10 Mg++ 0.21152E-10 -10.6747 0.10851E-10 -10.9645 0.51303E+00 -0.2899 11 Fe++ 0.58297E-13 -13.2344 0.29941E-13 -13.5237 0.51359E+00 -0.2894 12 K+ 0.15663E-03 -3.8051 0.13103E-03 -3.8826 0.83658E+00 -0.0775 13 Na+ 0.19876E-01 -1.7017 0.16596E-01 -1.7800 0.83500E+00 -0.0783 14 Mn++ 0.18659E-10 -10.7291 0.95912E-11 -11.0181 0.51402E+00 -0.2890 15 HPO4-- 0.45264E-07 -7.3442 0.23505E-07 -7.6288 0.51928E+00 -0.2846 16 HSiO3- 0.10481E-01 -1.9796 0.87533E-02 -2.0578 0.83516E+00 -0.0782 17 Ca(HSiO3)+ 0.16601E-07 -7.7799 0.13891E-07 -7.8573 0.83676E+00 -0.0774 18 Mg(HSiO3)+ 0.32173E-11 -11.4925 0.26921E-11 -11.5699 0.83676E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66180E-16 -16.1793 0.55376E-16 -16.2567 0.83676E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53129E-05 -5.2747 0.44291E-05 -5.3537 0.83365E+00 -0.0790 24 CH4,aq 0.15916E-04 -4.7982 0.15861E-04 -4.7997 0.99654E+00 -0.0015 25 C2H6,aq 0.37260E-14 -14.4288 0.37131E-14 -14.4303 0.99654E+00 -0.0015 29 CO,aq 0.11890E-16 -16.9248 0.11890E-16 -16.9248 0.10000E+01 0.0000 30 CO2,aq 0.41003E-10 -10.3872 0.40861E-10 -10.3887 0.99654E+00 -0.0015 31 CO3-2 0.58493E-06 -6.2329 0.30305E-06 -6.5185 0.51810E+00 -0.2856 32 CaCO3,aq 0.26479E-09 -9.5771 0.26479E-09 -9.5771 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54755E-12 -12.2616 0.45816E-12 -12.3390 0.83676E+00 -0.0774 34 CaCl+ 0.19881E-10 -10.7016 0.16636E-10 -10.7790 0.83676E+00 -0.0774 35 CaCl2,aq 0.58305E-15 -15.2343 0.58305E-15 -15.2343 0.10000E+01 0.0000 36 CaOH+ 0.79944E-07 -7.0972 0.66894E-07 -7.1746 0.83676E+00 -0.0774 37 CaSO4,aq 0.95618E-17 -17.0195 0.95618E-17 -17.0195 0.10000E+01 0.0000 38 HCl,aq 0.20069E-14 -14.6975 0.20069E-14 -14.6975 0.10000E+01 0.0000 43 FeCl+ 0.83552E-17 -17.0780 0.69913E-17 -17.1554 0.83676E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15689E-10 -10.8044 0.13128E-10 -10.8818 0.83676E+00 -0.0774 48 HFeO2- 0.35628E-07 -7.4482 0.29755E-07 -7.5264 0.83516E+00 -0.0782 49 FeO+ 0.10995E-16 -16.9588 0.92002E-17 -17.0362 0.83676E+00 -0.0774 51 FeO2- 0.40897E-09 -9.3883 0.34156E-09 -9.4665 0.83516E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11624E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.35035E-09 -9.4555 0.35035E-09 -9.4555 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10521E-14 -14.9779 0.87866E-15 -15.0562 0.83516E+00 -0.0782 58 MgCO3,aq 0.10336E-13 -13.9857 0.10336E-13 -13.9857 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.87129E-16 -16.0598 0.72905E-16 -16.1372 0.83676E+00 -0.0774 60 MgCl+ 0.28061E-14 -14.5519 0.23480E-14 -14.6293 0.83676E+00 -0.0774 61 MgOH+ 0.68889E-10 -10.1618 0.57644E-10 -10.2392 0.83676E+00 -0.0774 63 MnO,aq 0.18021E-08 -8.7442 0.18021E-08 -8.7442 0.10000E+01 0.0000 64 MnOH+ 0.46687E-09 -9.3308 0.39066E-09 -9.4082 0.83676E+00 -0.0774 65 MnO2-2 0.20944E-10 -10.6789 0.10851E-10 -10.9645 0.51810E+00 -0.2856 66 HMnO2- 0.21133E-09 -9.6750 0.17649E-09 -9.7533 0.83516E+00 -0.0782 69 MnCl+ 0.10413E-13 -13.9824 0.87130E-14 -14.0598 0.83676E+00 -0.0774 71 NaCl,aq 0.81138E-06 -6.0908 0.81138E-06 -6.0908 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93354E-02 -2.0299 0.77824E-02 -2.1089 0.83365E+00 -0.0790 79 HPO3-2 0.16376E-14 -14.7858 0.84846E-15 -15.0714 0.51810E+00 -0.2856 81 H2PO3- 0.15125E-18 -18.8203 0.12631E-18 -18.8985 0.83516E+00 -0.0782 82 H3PO4,aq 0.90606E-18 -18.0428 0.90606E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38508E-10 -10.4145 0.32190E-10 -10.4923 0.83595E+00 -0.0778 84 PO4-3 0.10650E-08 -8.9727 0.25831E-09 -9.5879 0.24255E+00 -0.6152 88 HP2O7-3 0.94537E-18 -18.0244 0.21853E-18 -18.6605 0.23116E+00 -0.6361 89 P2O7-4 0.91269E-17 -17.0397 0.70320E-18 -18.1529 0.77047E-01 -1.1132 90 H2S,aq 0.63073E-08 -8.2002 0.62854E-08 -8.2017 0.99654E+00 -0.0015 91 S2-2 0.27706E-14 -14.5574 0.14355E-14 -14.8430 0.51810E+00 -0.2856 97 SO3-2 0.12375E-17 -17.9074 0.65046E-18 -18.1868 0.52560E+00 -0.2793 99 HSO4- 0.36913E-19 -19.4328 0.30917E-19 -19.5098 0.83757E+00 -0.0770 Charge balance for all species = 0.6714E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8835943E-10 -.2228773E-01 -.2242564E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981988E+06 0.0000 3 Cl- 0.1766404E-03 0.1774522E-03 0.6280274E+01 6.2982 4 SO4-- 0.8322861E-12 -.1882229E-04 -.1804955E+01 7.8943 5 HCO3- 0.3079727E-06 0.1680967E-04 0.1023896E+01 3.5403 6 HS- 0.3279565E-04 0.5162425E-04 0.1704349E+01 5.5670 7 Al+++ 0.9715270E-29 0.5313034E-05 0.1431044E+00 0.7390 8 H4SiO4 0.6959606E-03 0.1352654E-01 0.1297849E+04 -3.1574 9 Ca++ 0.1352032E-06 0.2320333E-06 0.9283264E-02 13.1018 10 Mg++ 0.2115167E-10 0.9327155E-10 0.2263676E-05 9.2942 11 Fe++ 0.5829662E-13 0.3626757E-07 0.2021914E-02 6.7350 12 K+ 0.1566315E-03 0.1573856E-03 0.6143391E+01 6.2467 13 Na+ 0.1987576E-01 0.2232220E-01 0.5122907E+03 8.3494 14 Mn++ 0.1865924E-10 0.2519934E-08 0.1381994E-03 9.2406 15 HPO4-- 0.4526398E-07 0.4636749E-07 0.4442568E-02 12.6299 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3642870E+02 -.1732935E-01 -.3641137E+02 0.0000000E+00 2 H2O 0.2793036E+02 0.4315665E+02 -.1522629E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6099498E-01 -.1463487E-04 0.6100961E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6096947E-01 0.4013934E-04 -.6100961E-01 0.0000000E+00 7 Al+++ 0.7173628E+01 0.4131037E-05 0.7173624E+01 0.0000000E+00 8 H4SiO4 0.2290811E+02 0.1051728E-01 0.2289759E+02 0.0000000E+00 9 Ca++ 0.2530327E+01 0.1804126E-06 0.2530327E+01 0.0000000E+00 10 Mg++ 0.1746031E+01 0.7252132E-10 0.1746031E+01 0.0000000E+00 11 Fe++ 0.1568618E+01 0.2819908E-07 0.1568618E+01 0.0000000E+00 12 K+ 0.4670911E+00 0.1223718E-03 0.4669687E+00 0.0000000E+00 13 Na+ 0.2761695E+01 0.1735615E-01 0.2744339E+01 0.0000000E+00 14 Mn++ 0.3814489E-01 0.1959321E-08 0.3814489E-01 0.0000000E+00 15 HPO4-- 0.1301866E-01 0.3605206E-07 0.1301863E-01 0.0000000E+00 Chg. balance for solid moles: -.9843E-14 Mass of aqueous solution: 0.778883E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.742 0.438 719.0 2.857 29.92 276.0 andradite 0.2440 -0.613 124.0 2.093 5.160 32.22 grossular 0.5910E-01 -1.228 26.62 1.425 1.108 7.407 apatite-OH 0.4340E-02 -2.363 2.180 0.338 0.9070E-01 0.6927 clinochlore 0.3133 -0.504 174.1 2.241 7.245 66.23 daphnite 0.9068E-01 -1.042 64.70 1.811 2.692 19.61 chlorite-Mn 0.7629E-02 -2.118 5.409 0.733 0.2251 1.724 diopside 0.1104 -0.957 23.91 1.379 0.9948 7.307 hedenbergite 0.2863E-01 -1.543 7.103 0.851 0.2956 1.946 microcline 0.4095 -0.388 114.0 2.057 4.743 44.52 stilbite 1.422 0.153 1002. 3.001 41.69 467.4 stilpnomelane-Fe 0.1149 -0.940 123.9 2.093 5.154 42.79 tr.625ac.25prg.125 0.1914E-01 -1.718 16.36 1.214 0.6806 5.265 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1854E-01 0.1854E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2403.319254 g Volume = 973.092061 cm3 Porosity: -10.4532% V(tot) - V(min): -.92092E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2199.9990000 g log = 3.3424 Original solution: 1000.0103000 g Original solution / Rock added: 0.45 (Water/Rock Ratio), log = -0.3424 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0591 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9639E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4100E-08 1.0069 0.4372E-08 0.4342E-08 CH4,gas 0.2177E-01 1.0124 0.2335E-01 0.2306E-01 H2,gas 0.1435E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1638E-06 0.9959 0.1728E-06 0.1735E-06 S2,gas 0.4575E-29 1.0000 0.4845E-29 0.4845E-29 CO,gas 0.1673E-13 1.0000 0.1772E-13 0.1772E-13 SO3,gas 0.8503E-48 1.0000 0.9005E-48 0.9005E-48 SO2,gas 0.5031E-27 1.0000 0.5328E-27 0.5328E-27 HCl,gas 0.3344E-17 1.0000 0.3541E-17 0.3541E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.72 -10.06 -3.353 0.17174E+05 -8.359 3 CH4,gas 4.54 1.21 -3.33 -0.833 0.56872E+04 -1.632 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.69 -8.46 -4.231 0.14448E+05 -6.763 6 S2,gas -7.34 -38.35 -31.01 -4.771 0.52955E+05 -29.315 7 CO,gas 3.21 -12.24 -15.45 -4.754 0.26381E+05 -13.752 8 SO3,gas 17.12 -32.62 -49.74 -12.436 0.84937E+05 -48.045 9 SO2,gas 0.83 -28.14 -28.97 -7.726 0.49470E+05 -27.273 10 HCl,gas 5.19 -13.96 -19.15 -9.575 0.32698E+05 -17.451 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80760E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.62 -4.58 -1.528 0.78256E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.62 -4.43 -1.476 0.75613E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70314E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65565E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.75 -4.65 -1.329 0.79404E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.75 -4.21 -1.202 0.71826E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82258E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 143 pyrrhotite -4.26 -7.96 -3.70 -1.232 0.63115E+04 144 pyrrhotiteFe0.875 -6.02 -9.35 -3.34 -1.227 0.56987E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22462E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.273 0.23264E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47161E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.96 -3.55 -1.182 0.60543E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79431E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53293E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.45 -4.47 -1.491 0.76380E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62618E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2199.9990000 g New total amount of reactant added: 2299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2299.9990000 Water: Moles liquid = 0.4260E+02 kg liquid = 0.7675E+00 Moles total = 0.2668E+02 kg total = 0.4806E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135225E-01 Osmotic coef. = 0.9691 True ionic strength = .2003504E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88366E-10 -10.0537 0.74246E-10 -10.1293 0.84021E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17895E-03 -3.7473 0.14945E-03 -3.8255 0.83515E+00 -0.0782 4 SO4-- 0.84315E-12 -12.0741 0.43776E-12 -12.3588 0.51919E+00 -0.2847 5 HCO3- 0.31199E-06 -6.5059 0.26094E-06 -6.5835 0.83637E+00 -0.0776 6 HS- 0.33225E-04 -4.4785 0.27752E-04 -4.5567 0.83527E+00 -0.0782 7 Al+++ 0.97177E-29 -29.0124 0.22440E-29 -29.6490 0.23092E+00 -0.6365 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13522E-06 -6.8689 0.69692E-07 -7.1568 0.51538E+00 -0.2879 10 Mg++ 0.21155E-10 -10.6746 0.10853E-10 -10.9645 0.51302E+00 -0.2899 11 Fe++ 0.58306E-13 -13.2343 0.29945E-13 -13.5237 0.51358E+00 -0.2894 12 K+ 0.15664E-03 -3.8051 0.13104E-03 -3.8826 0.83657E+00 -0.0775 13 Na+ 0.19877E-01 -1.7016 0.16598E-01 -1.7800 0.83500E+00 -0.0783 14 Mn++ 0.18665E-10 -10.7290 0.95942E-11 -11.0180 0.51401E+00 -0.2890 15 HPO4-- 0.45259E-07 -7.3443 0.23501E-07 -7.6289 0.51927E+00 -0.2846 16 HSiO3- 0.10480E-01 -1.9796 0.87527E-02 -2.0579 0.83515E+00 -0.0782 17 Ca(HSiO3)+ 0.16602E-07 -7.7798 0.13892E-07 -7.8572 0.83675E+00 -0.0774 18 Mg(HSiO3)+ 0.32176E-11 -11.4925 0.26923E-11 -11.5699 0.83675E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66184E-16 -16.1792 0.55380E-16 -16.2566 0.83675E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53125E-05 -5.2747 0.44287E-05 -5.3537 0.83364E+00 -0.0790 24 CH4,aq 0.16125E-04 -4.7925 0.16069E-04 -4.7940 0.99654E+00 -0.0015 25 C2H6,aq 0.38242E-14 -14.4175 0.38109E-14 -14.4190 0.99654E+00 -0.0015 29 CO,aq 0.12046E-16 -16.9192 0.12046E-16 -16.9192 0.10000E+01 0.0000 30 CO2,aq 0.41541E-10 -10.3815 0.41397E-10 -10.3830 0.99654E+00 -0.0015 31 CO3-2 0.59252E-06 -6.2273 0.30698E-06 -6.5129 0.51809E+00 -0.2856 32 CaCO3,aq 0.26826E-09 -9.5714 0.26826E-09 -9.5714 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.55477E-12 -12.2559 0.46420E-12 -12.3333 0.83675E+00 -0.0774 34 CaCl+ 0.20144E-10 -10.6958 0.16856E-10 -10.7733 0.83675E+00 -0.0774 35 CaCl2,aq 0.59849E-15 -15.2229 0.59849E-15 -15.2229 0.10000E+01 0.0000 36 CaOH+ 0.79950E-07 -7.0972 0.66898E-07 -7.1746 0.83675E+00 -0.0774 37 CaSO4,aq 0.96878E-17 -17.0138 0.96878E-17 -17.0138 0.10000E+01 0.0000 38 HCl,aq 0.20333E-14 -14.6918 0.20333E-14 -14.6918 0.10000E+01 0.0000 43 FeCl+ 0.84657E-17 -17.0723 0.70837E-17 -17.1497 0.83675E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15690E-10 -10.8044 0.13129E-10 -10.8818 0.83675E+00 -0.0774 48 HFeO2- 0.35626E-07 -7.4482 0.29753E-07 -7.5265 0.83515E+00 -0.0782 49 FeO+ 0.10996E-16 -16.9588 0.92008E-17 -17.0362 0.83675E+00 -0.0774 51 FeO2- 0.40895E-09 -9.3883 0.34153E-09 -9.4666 0.83515E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.35496E-09 -9.4498 0.35496E-09 -9.4498 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10659E-14 -14.9723 0.89017E-15 -15.0505 0.83515E+00 -0.0782 58 MgCO3,aq 0.10471E-13 -13.9800 0.10471E-13 -13.9800 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.88277E-16 -16.0542 0.73866E-16 -16.1316 0.83675E+00 -0.0774 60 MgCl+ 0.28432E-14 -14.5462 0.23791E-14 -14.6236 0.83675E+00 -0.0774 61 MgOH+ 0.68894E-10 -10.1618 0.57647E-10 -10.2392 0.83675E+00 -0.0774 63 MnO,aq 0.18024E-08 -8.7441 0.18024E-08 -8.7441 0.10000E+01 0.0000 64 MnOH+ 0.46699E-09 -9.3307 0.39075E-09 -9.4081 0.83675E+00 -0.0774 65 MnO2-2 0.20945E-10 -10.6789 0.10851E-10 -10.9645 0.51809E+00 -0.2856 66 HMnO2- 0.21135E-09 -9.6750 0.17651E-09 -9.7532 0.83515E+00 -0.0782 69 MnCl+ 0.10552E-13 -13.9767 0.88297E-14 -14.0541 0.83675E+00 -0.0774 71 NaCl,aq 0.82205E-06 -6.0851 0.82205E-06 -6.0851 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93348E-02 -2.0299 0.77819E-02 -2.1089 0.83364E+00 -0.0790 79 HPO3-2 0.16374E-14 -14.7858 0.84834E-15 -15.0714 0.51809E+00 -0.2856 81 H2PO3- 0.15124E-18 -18.8203 0.12630E-18 -18.8986 0.83515E+00 -0.0782 82 H3PO4,aq 0.90607E-18 -18.0428 0.90607E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38505E-10 -10.4145 0.32188E-10 -10.4923 0.83594E+00 -0.0778 84 PO4-3 0.10648E-08 -8.9727 0.25826E-09 -9.5879 0.24254E+00 -0.6152 88 HP2O7-3 0.94522E-18 -18.0245 0.21849E-18 -18.6606 0.23115E+00 -0.6361 89 P2O7-4 0.91251E-17 -17.0398 0.70301E-18 -18.1530 0.77041E-01 -1.1133 90 H2S,aq 0.63902E-08 -8.1945 0.63681E-08 -8.1960 0.99654E+00 -0.0015 91 S2-2 0.28437E-14 -14.5461 0.14733E-14 -14.8317 0.51809E+00 -0.2856 97 SO3-2 0.12537E-17 -17.9018 0.65893E-18 -18.1812 0.52559E+00 -0.2794 99 HSO4- 0.37397E-19 -19.4272 0.31322E-19 -19.5041 0.83757E+00 -0.0770 Charge balance for all species = 0.6807E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8836601E-10 -.2228648E-01 -.2242438E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981987E+06 0.0000 3 Cl- 0.1789517E-03 0.1797741E-03 0.6362452E+01 6.3038 4 SO4-- 0.8431468E-12 -.1903061E-04 -.1824933E+01 7.8999 5 HCO3- 0.3119897E-06 0.1702962E-04 0.1037293E+01 3.5459 6 HS- 0.3322479E-04 0.5226179E-04 0.1725397E+01 5.5726 7 Al+++ 0.9717681E-29 0.5312658E-05 0.1430942E+00 0.7390 8 H4SiO4 0.6959620E-03 0.1352589E-01 0.1297786E+04 -3.1574 9 Ca++ 0.1352245E-06 0.2320654E-06 0.9284547E-02 13.1018 10 Mg++ 0.2115501E-10 0.9328008E-10 0.2263882E-05 9.2942 11 Fe++ 0.5830589E-13 0.3626521E-07 0.2021782E-02 6.7350 12 K+ 0.1566432E-03 0.1573973E-03 0.6143848E+01 6.2467 13 Na+ 0.1987725E-01 0.2232370E-01 0.5123251E+03 8.3494 14 Mn++ 0.1866548E-10 0.2520396E-08 0.1382248E-03 9.2407 15 HPO4-- 0.4525872E-07 0.4636204E-07 0.4442046E-02 12.6298 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3808456E+02 -.1710457E-01 -.3806745E+02 0.0000000E+00 2 H2O 0.2667682E+02 0.4259924E+02 -.1592242E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6376632E-01 -.1460573E-04 0.6378092E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6374081E-01 0.4011020E-04 -.6378092E-01 0.0000000E+00 7 Al+++ 0.7499702E+01 0.4077391E-05 0.7499698E+01 0.0000000E+00 8 H4SiO4 0.2394939E+02 0.1038094E-01 0.2393901E+02 0.0000000E+00 9 Ca++ 0.2645341E+01 0.1781070E-06 0.2645341E+01 0.0000000E+00 10 Mg++ 0.1825396E+01 0.7159118E-10 0.1825396E+01 0.0000000E+00 11 Fe++ 0.1639919E+01 0.2783305E-07 0.1639919E+01 0.0000000E+00 12 K+ 0.4883225E+00 0.1208002E-03 0.4882017E+00 0.0000000E+00 13 Na+ 0.2887219E+01 0.1713313E-01 0.2870086E+01 0.0000000E+00 14 Mn++ 0.3987875E-01 0.1934369E-08 0.3987875E-01 0.0000000E+00 15 HPO4-- 0.1361042E-01 0.3558223E-07 0.1361038E-01 0.0000000E+00 Chg. balance for solid moles: -.7980E-14 Mass of aqueous solution: 0.768823E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.868 0.458 751.9 2.876 29.93 288.7 andradite 0.2551 -0.593 129.6 2.113 5.160 33.68 grossular 0.6178E-01 -1.209 27.83 1.445 1.108 7.743 apatite-OH 0.4537E-02 -2.343 2.279 0.358 0.9070E-01 0.7242 clinochlore 0.3274 -0.485 182.0 2.260 7.243 69.23 daphnite 0.9479E-01 -1.023 67.63 1.830 2.692 20.49 chlorite-Mn 0.7976E-02 -2.098 5.655 0.752 0.2251 1.802 diopside 0.1158 -0.936 25.09 1.399 0.9984 7.667 hedenbergite 0.3004E-01 -1.522 7.453 0.872 0.2966 2.041 microcline 0.4281 -0.368 119.2 2.076 4.743 46.55 stilbite 1.486 0.172 1047. 3.020 41.68 488.5 stilpnomelane-Fe 0.1201 -0.920 129.5 2.112 5.155 44.74 tr.625ac.25prg.125 0.1997E-01 -1.700 17.07 1.232 0.6794 5.494 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1854E-01 0.1854E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2512.569918 g Volume = 1017.295125 cm3 Porosity: -10.4555% V(tot) - V(min): -.96296E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2299.9990000 g log = 3.3617 Original solution: 1000.0103000 g Original solution / Rock added: 0.43 (Water/Rock Ratio), log = -0.3617 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0594 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9636E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4152E-08 1.0069 0.4429E-08 0.4399E-08 CH4,gas 0.2205E-01 1.0124 0.2365E-01 0.2336E-01 H2,gas 0.1435E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1659E-06 0.9959 0.1751E-06 0.1758E-06 S2,gas 0.4695E-29 1.0000 0.4974E-29 0.4974E-29 CO,gas 0.1694E-13 1.0000 0.1795E-13 0.1795E-13 SO3,gas 0.8612E-48 1.0000 0.9124E-48 0.9124E-48 SO2,gas 0.5095E-27 1.0000 0.5398E-27 0.5398E-27 HCl,gas 0.3387E-17 1.0000 0.3588E-17 0.3588E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.71 -10.05 -3.351 0.17165E+05 -8.354 3 CH4,gas 4.54 1.22 -3.33 -0.831 0.56775E+04 -1.626 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.69 -8.46 -4.228 0.14438E+05 -6.757 6 S2,gas -7.34 -38.34 -31.00 -4.770 0.52936E+05 -29.303 7 CO,gas 3.21 -12.23 -15.44 -4.752 0.26372E+05 -13.746 8 SO3,gas 17.12 -32.62 -49.74 -12.435 0.84928E+05 -48.040 9 SO2,gas 0.83 -28.13 -28.97 -7.724 0.49460E+05 -27.268 10 HCl,gas 5.19 -13.95 -19.14 -9.572 0.32688E+05 -17.445 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80756E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.61 -4.58 -1.526 0.78159E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.61 -4.42 -1.474 0.75517E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65564E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.75 -4.64 -1.327 0.79307E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33584E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.75 -4.20 -1.200 0.71730E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15934E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82257E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 143 pyrrhotite -4.26 -7.95 -3.69 -1.230 0.63018E+04 144 pyrrhotiteFe0.875 -6.02 -9.35 -3.33 -1.225 0.56890E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22461E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23263E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47158E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.95 -3.54 -1.180 0.60446E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79432E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83486E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.45 -4.47 -1.489 0.76281E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2299.9990000 g New total amount of reactant added: 2399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2399.9990000 Water: Moles liquid = 0.4204E+02 kg liquid = 0.7574E+00 Moles total = 0.2542E+02 kg total = 0.4580E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135423E-01 Osmotic coef. = 0.9691 True ionic strength = .2003658E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88373E-10 -10.0537 0.74251E-10 -10.1293 0.84020E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18132E-03 -3.7415 0.15143E-03 -3.8198 0.83515E+00 -0.0782 4 SO4-- 0.85429E-12 -12.0684 0.44353E-12 -12.3531 0.51918E+00 -0.2847 5 HCO3- 0.31611E-06 -6.5002 0.26439E-06 -6.5778 0.83637E+00 -0.0776 6 HS- 0.33665E-04 -4.4728 0.28120E-04 -4.5510 0.83527E+00 -0.0782 7 Al+++ 0.97202E-29 -29.0123 0.22444E-29 -29.6489 0.23091E+00 -0.6366 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13525E-06 -6.8689 0.69702E-07 -7.1568 0.51537E+00 -0.2879 10 Mg++ 0.21158E-10 -10.6745 0.10855E-10 -10.9644 0.51301E+00 -0.2899 11 Fe++ 0.58315E-13 -13.2342 0.29949E-13 -13.5236 0.51357E+00 -0.2894 12 K+ 0.15666E-03 -3.8051 0.13105E-03 -3.8826 0.83657E+00 -0.0775 13 Na+ 0.19879E-01 -1.7016 0.16599E-01 -1.7799 0.83500E+00 -0.0783 14 Mn++ 0.18672E-10 -10.7288 0.95972E-11 -11.0179 0.51400E+00 -0.2890 15 HPO4-- 0.45253E-07 -7.3443 0.23498E-07 -7.6290 0.51926E+00 -0.2846 16 HSiO3- 0.10480E-01 -1.9797 0.87521E-02 -2.0579 0.83515E+00 -0.0782 17 Ca(HSiO3)+ 0.16603E-07 -7.7798 0.13893E-07 -7.8572 0.83675E+00 -0.0774 18 Mg(HSiO3)+ 0.32178E-11 -11.4924 0.26925E-11 -11.5698 0.83675E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66189E-16 -16.1792 0.55383E-16 -16.2566 0.83675E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53121E-05 -5.2747 0.44284E-05 -5.3538 0.83364E+00 -0.0790 24 CH4,aq 0.16339E-04 -4.7868 0.16282E-04 -4.7883 0.99654E+00 -0.0015 25 C2H6,aq 0.39263E-14 -14.4060 0.39127E-14 -14.4075 0.99654E+00 -0.0015 29 CO,aq 0.12206E-16 -16.9134 0.12206E-16 -16.9134 0.10000E+01 0.0000 30 CO2,aq 0.42093E-10 -10.3758 0.41947E-10 -10.3773 0.99654E+00 -0.0015 31 CO3-2 0.60032E-06 -6.2216 0.31101E-06 -6.5072 0.51808E+00 -0.2856 32 CaCO3,aq 0.27182E-09 -9.5657 0.27182E-09 -9.5657 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56218E-12 -12.2501 0.47040E-12 -12.3275 0.83675E+00 -0.0774 34 CaCl+ 0.20414E-10 -10.6901 0.17082E-10 -10.7675 0.83675E+00 -0.0774 35 CaCl2,aq 0.61454E-15 -15.2114 0.61454E-15 -15.2114 0.10000E+01 0.0000 36 CaOH+ 0.79956E-07 -7.0971 0.66903E-07 -7.1746 0.83675E+00 -0.0774 37 CaSO4,aq 0.98170E-17 -17.0080 0.98170E-17 -17.0080 0.10000E+01 0.0000 38 HCl,aq 0.20604E-14 -14.6860 0.20604E-14 -14.6860 0.10000E+01 0.0000 43 FeCl+ 0.85792E-17 -17.0666 0.71786E-17 -17.1440 0.83675E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15691E-10 -10.8043 0.13129E-10 -10.8818 0.83675E+00 -0.0774 48 HFeO2- 0.35624E-07 -7.4483 0.29751E-07 -7.5265 0.83515E+00 -0.0782 49 FeO+ 0.10997E-16 -16.9587 0.92015E-17 -17.0361 0.83675E+00 -0.0774 51 FeO2- 0.40892E-09 -9.3884 0.34151E-09 -9.4666 0.83515E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.35969E-09 -9.4441 0.35969E-09 -9.4441 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10800E-14 -14.9666 0.90198E-15 -15.0448 0.83515E+00 -0.0782 58 MgCO3,aq 0.10610E-13 -13.9743 0.10610E-13 -13.9743 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.89456E-16 -16.0484 0.74852E-16 -16.1258 0.83675E+00 -0.0774 60 MgCl+ 0.28813E-14 -14.5404 0.24109E-14 -14.6178 0.83675E+00 -0.0774 61 MgOH+ 0.68899E-10 -10.1618 0.57651E-10 -10.2392 0.83675E+00 -0.0774 63 MnO,aq 0.18027E-08 -8.7441 0.18027E-08 -8.7441 0.10000E+01 0.0000 64 MnOH+ 0.46710E-09 -9.3306 0.39084E-09 -9.4080 0.83675E+00 -0.0774 65 MnO2-2 0.20946E-10 -10.6789 0.10852E-10 -10.9645 0.51808E+00 -0.2856 66 HMnO2- 0.21137E-09 -9.6750 0.17653E-09 -9.7532 0.83515E+00 -0.0782 69 MnCl+ 0.10696E-13 -13.9708 0.89495E-14 -14.0482 0.83675E+00 -0.0774 71 NaCl,aq 0.83301E-06 -6.0794 0.83301E-06 -6.0794 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93342E-02 -2.0299 0.77813E-02 -2.1089 0.83364E+00 -0.0790 79 HPO3-2 0.16372E-14 -14.7859 0.84821E-15 -15.0715 0.51808E+00 -0.2856 81 H2PO3- 0.15123E-18 -18.8204 0.12630E-18 -18.8986 0.83515E+00 -0.0782 82 H3PO4,aq 0.90607E-18 -18.0428 0.90607E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38503E-10 -10.4145 0.32186E-10 -10.4923 0.83594E+00 -0.0778 84 PO4-3 0.10646E-08 -8.9728 0.25820E-09 -9.5880 0.24253E+00 -0.6152 88 HP2O7-3 0.94507E-18 -18.0245 0.21844E-18 -18.6607 0.23114E+00 -0.6361 89 P2O7-4 0.91233E-17 -17.0398 0.70281E-18 -18.1532 0.77035E-01 -1.1133 90 H2S,aq 0.64754E-08 -8.1887 0.64529E-08 -8.1902 0.99654E+00 -0.0015 91 S2-2 0.29196E-14 -14.5347 0.15126E-14 -14.8203 0.51808E+00 -0.2856 97 SO3-2 0.12703E-17 -17.8961 0.66762E-18 -18.1755 0.52558E+00 -0.2794 99 HSO4- 0.37893E-19 -19.4214 0.31738E-19 -19.4984 0.83756E+00 -0.0770 Charge balance for all species = 0.6891E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8837276E-10 -.2228520E-01 -.2242309E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981986E+06 0.0000 3 Cl- 0.1813243E-03 0.1821577E-03 0.6446808E+01 6.3095 4 SO4-- 0.8542928E-12 -.1924447E-04 -.1845440E+01 7.9055 5 HCO3- 0.3161122E-06 0.1725541E-04 0.1051046E+01 3.5515 6 HS- 0.3366530E-04 0.5291624E-04 0.1747003E+01 5.5783 7 Al+++ 0.9720161E-29 0.5312275E-05 0.1430839E+00 0.7390 8 H4SiO4 0.6959634E-03 0.1352522E-01 0.1297722E+04 -3.1574 9 Ca++ 0.1352464E-06 0.2320984E-06 0.9285865E-02 13.1018 10 Mg++ 0.2115843E-10 0.9328913E-10 0.2264102E-05 9.2942 11 Fe++ 0.5831541E-13 0.3626279E-07 0.2021647E-02 6.7350 12 K+ 0.1566552E-03 0.1574093E-03 0.6144316E+01 6.2467 13 Na+ 0.1987878E-01 0.2232524E-01 0.5123605E+03 8.3494 14 Mn++ 0.1867153E-10 0.2520823E-08 0.1382482E-03 9.2407 15 HPO4-- 0.4525330E-07 0.4635644E-07 0.4441509E-02 12.6296 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3974041E+02 -.1687978E-01 -.3972353E+02 0.0000000E+00 2 H2O 0.2542328E+02 0.4204182E+02 -.1661854E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6653766E-01 -.1457660E-04 0.6655223E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6651215E-01 0.4008107E-04 -.6655223E-01 0.0000000E+00 7 Al+++ 0.7825777E+01 0.4023748E-05 0.7825773E+01 0.0000000E+00 8 H4SiO4 0.2499067E+02 0.1024459E-01 0.2498042E+02 0.0000000E+00 9 Ca++ 0.2760356E+01 0.1758014E-06 0.2760356E+01 0.0000000E+00 10 Mg++ 0.1904761E+01 0.7066125E-10 0.1904761E+01 0.0000000E+00 11 Fe++ 0.1711220E+01 0.2746702E-07 0.1711220E+01 0.0000000E+00 12 K+ 0.5095539E+00 0.1192287E-03 0.5094347E+00 0.0000000E+00 13 Na+ 0.3012744E+01 0.1691011E-01 0.2995833E+01 0.0000000E+00 14 Mn++ 0.4161261E-01 0.1909381E-08 0.4161261E-01 0.0000000E+00 15 HPO4-- 0.1420218E-01 0.3511239E-07 0.1420214E-01 0.0000000E+00 Chg. balance for solid moles: -.1634E-14 Mass of aqueous solution: 0.758763E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.993 0.476 784.9 2.895 29.94 301.3 andradite 0.2662 -0.575 135.3 2.131 5.160 35.15 grossular 0.6447E-01 -1.191 29.04 1.463 1.108 8.080 apatite-OH 0.4734E-02 -2.325 2.378 0.376 0.9070E-01 0.7556 clinochlore 0.3416 -0.466 189.9 2.278 7.242 72.22 daphnite 0.9889E-01 -1.005 70.56 1.849 2.691 21.38 chlorite-Mn 0.8323E-02 -2.080 5.900 0.771 0.2251 1.880 diopside 0.1213 -0.916 26.26 1.419 1.002 8.027 hedenbergite 0.3145E-01 -1.502 7.803 0.892 0.2976 2.137 microcline 0.4467 -0.350 124.3 2.095 4.743 48.57 stilbite 1.550 0.190 1093. 3.038 41.67 509.6 stilpnomelane-Fe 0.1254 -0.902 135.2 2.131 5.155 46.69 tr.625ac.25prg.125 0.2080E-01 -1.682 17.78 1.250 0.6783 5.723 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1854E-01 0.1854E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2621.820582 g Volume = 1061.498190 cm3 Porosity: -10.4577% V(tot) - V(min): -.10050E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2399.9990000 g log = 3.3802 Original solution: 1000.0103000 g Original solution / Rock added: 0.42 (Water/Rock Ratio), log = -0.3802 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0597 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9633E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4206E-08 1.0069 0.4488E-08 0.4457E-08 CH4,gas 0.2234E-01 1.0124 0.2397E-01 0.2367E-01 H2,gas 0.1434E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1681E-06 0.9959 0.1774E-06 0.1781E-06 S2,gas 0.4819E-29 1.0000 0.5107E-29 0.5107E-29 CO,gas 0.1716E-13 1.0000 0.1819E-13 0.1819E-13 SO3,gas 0.8725E-48 1.0000 0.9246E-48 0.9246E-48 SO2,gas 0.5162E-27 1.0000 0.5470E-27 0.5470E-27 HCl,gas 0.3431E-17 1.0000 0.3636E-17 0.3636E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.71 -10.05 -3.349 0.17155E+05 -8.348 3 CH4,gas 4.54 1.22 -3.32 -0.830 0.56677E+04 -1.620 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.68 -8.45 -4.225 0.14428E+05 -6.751 6 S2,gas -7.34 -38.33 -30.99 -4.768 0.52916E+05 -29.292 7 CO,gas 3.21 -12.22 -15.44 -4.751 0.26362E+05 -13.740 8 SO3,gas 17.12 -32.61 -49.73 -12.433 0.84918E+05 -48.034 9 SO2,gas 0.83 -28.13 -28.96 -7.723 0.49450E+05 -27.262 10 HCl,gas 5.19 -13.95 -19.14 -9.569 0.32678E+05 -17.439 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80753E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.61 -4.57 -1.524 0.78061E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.61 -4.42 -1.472 0.75419E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65563E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.74 -4.64 -1.325 0.79209E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.74 -4.20 -1.199 0.71632E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82255E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43417E+04 143 pyrrhotite -4.26 -7.95 -3.68 -1.228 0.62920E+04 144 pyrrhotiteFe0.875 -6.02 -9.34 -3.33 -1.223 0.56792E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22459E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23262E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47156E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90680E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.95 -3.53 -1.178 0.60348E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79432E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60612E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58216E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.44 -4.46 -1.487 0.76182E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2399.9990000 g New total amount of reactant added: 2499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2499.9990000 Water: Moles liquid = 0.4149E+02 kg liquid = 0.7474E+00 Moles total = 0.2417E+02 kg total = 0.4354E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135626E-01 Osmotic coef. = 0.9691 True ionic strength = .2003817E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88380E-10 -10.0536 0.74257E-10 -10.1293 0.84020E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18376E-03 -3.7357 0.15347E-03 -3.8140 0.83514E+00 -0.0782 4 SO4-- 0.86574E-12 -12.0626 0.44947E-12 -12.3473 0.51917E+00 -0.2847 5 HCO3- 0.32034E-06 -6.4944 0.26793E-06 -6.5720 0.83637E+00 -0.0776 6 HS- 0.34118E-04 -4.4670 0.28497E-04 -4.5452 0.83527E+00 -0.0782 7 Al+++ 0.97227E-29 -29.0122 0.22449E-29 -29.6488 0.23090E+00 -0.6366 8 H4SiO4 0.69596E-03 -3.1574 0.69596E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13527E-06 -6.8688 0.69712E-07 -7.1567 0.51536E+00 -0.2879 10 Mg++ 0.21162E-10 -10.6744 0.10856E-10 -10.9643 0.51300E+00 -0.2899 11 Fe++ 0.58325E-13 -13.2341 0.29954E-13 -13.5236 0.51356E+00 -0.2894 12 K+ 0.15667E-03 -3.8050 0.13106E-03 -3.8825 0.83656E+00 -0.0775 13 Na+ 0.19880E-01 -1.7016 0.16600E-01 -1.7799 0.83499E+00 -0.0783 14 Mn++ 0.18677E-10 -10.7287 0.96000E-11 -11.0177 0.51399E+00 -0.2890 15 HPO4-- 0.45248E-07 -7.3444 0.23495E-07 -7.6290 0.51925E+00 -0.2846 16 HSiO3- 0.10479E-01 -1.9797 0.87514E-02 -2.0579 0.83514E+00 -0.0782 17 Ca(HSiO3)+ 0.16605E-07 -7.7798 0.13894E-07 -7.8572 0.83674E+00 -0.0774 18 Mg(HSiO3)+ 0.32181E-11 -11.4924 0.26927E-11 -11.5698 0.83674E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66194E-16 -16.1792 0.55387E-16 -16.2566 0.83674E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8281 0.14854E-09 -9.8281 0.10000E+01 0.0000 23 AlO2- 0.53117E-05 -5.2748 0.44280E-05 -5.3538 0.83363E+00 -0.0790 24 CH4,aq 0.16558E-04 -4.7810 0.16501E-04 -4.7825 0.99654E+00 -0.0015 25 C2H6,aq 0.40326E-14 -14.3944 0.40186E-14 -14.3959 0.99654E+00 -0.0015 29 CO,aq 0.12370E-16 -16.9076 0.12370E-16 -16.9076 0.10000E+01 0.0000 30 CO2,aq 0.42659E-10 -10.3700 0.42511E-10 -10.3715 0.99654E+00 -0.0015 31 CO3-2 0.60832E-06 -6.2159 0.31515E-06 -6.5015 0.51807E+00 -0.2856 32 CaCO3,aq 0.27548E-09 -9.5599 0.27548E-09 -9.5599 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56979E-12 -12.2443 0.47676E-12 -12.3217 0.83674E+00 -0.0774 34 CaCl+ 0.20691E-10 -10.6842 0.17313E-10 -10.7616 0.83674E+00 -0.0774 35 CaCl2,aq 0.63125E-15 -15.1998 0.63125E-15 -15.1998 0.10000E+01 0.0000 36 CaOH+ 0.79962E-07 -7.0971 0.66908E-07 -7.1745 0.83674E+00 -0.0774 37 CaSO4,aq 0.99498E-17 -17.0022 0.99498E-17 -17.0022 0.10000E+01 0.0000 38 HCl,aq 0.20882E-14 -14.6802 0.20882E-14 -14.6802 0.10000E+01 0.0000 43 FeCl+ 0.86957E-17 -17.0607 0.72761E-17 -17.1381 0.83674E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15692E-10 -10.8043 0.13130E-10 -10.8817 0.83674E+00 -0.0774 48 HFeO2- 0.35621E-07 -7.4483 0.29749E-07 -7.5265 0.83514E+00 -0.0782 49 FeO+ 0.10998E-16 -16.9587 0.92022E-17 -17.0361 0.83674E+00 -0.0774 51 FeO2- 0.40889E-09 -9.3884 0.34148E-09 -9.4666 0.83514E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.36454E-09 -9.4382 0.36454E-09 -9.4382 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.10946E-14 -14.9608 0.91411E-15 -15.0390 0.83514E+00 -0.0782 58 MgCO3,aq 0.10753E-13 -13.9685 0.10753E-13 -13.9685 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.90667E-16 -16.0426 0.75865E-16 -16.1200 0.83674E+00 -0.0774 60 MgCl+ 0.29204E-14 -14.5346 0.24437E-14 -14.6120 0.83674E+00 -0.0774 61 MgOH+ 0.68905E-10 -10.1618 0.57656E-10 -10.2392 0.83674E+00 -0.0774 63 MnO,aq 0.18030E-08 -8.7440 0.18030E-08 -8.7440 0.10000E+01 0.0000 64 MnOH+ 0.46721E-09 -9.3305 0.39093E-09 -9.4079 0.83674E+00 -0.0774 65 MnO2-2 0.20946E-10 -10.6789 0.10852E-10 -10.9645 0.51807E+00 -0.2856 66 HMnO2- 0.21139E-09 -9.6749 0.17654E-09 -9.7532 0.83514E+00 -0.0782 69 MnCl+ 0.10842E-13 -13.9649 0.90723E-14 -14.0423 0.83674E+00 -0.0774 71 NaCl,aq 0.84426E-06 -6.0735 0.84426E-06 -6.0735 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93336E-02 -2.0300 0.77808E-02 -2.1090 0.83363E+00 -0.0790 79 HPO3-2 0.16370E-14 -14.7859 0.84809E-15 -15.0716 0.51807E+00 -0.2856 81 H2PO3- 0.15121E-18 -18.8204 0.12629E-18 -18.8986 0.83514E+00 -0.0782 82 H3PO4,aq 0.90607E-18 -18.0428 0.90607E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38500E-10 -10.4145 0.32184E-10 -10.4924 0.83593E+00 -0.0778 84 PO4-3 0.10645E-08 -8.9729 0.25815E-09 -9.5881 0.24252E+00 -0.6153 88 HP2O7-3 0.94491E-18 -18.0246 0.21839E-18 -18.6608 0.23113E+00 -0.6362 89 P2O7-4 0.91214E-17 -17.0399 0.70261E-18 -18.1533 0.77028E-01 -1.1133 90 H2S,aq 0.65628E-08 -8.1829 0.65401E-08 -8.1844 0.99654E+00 -0.0015 91 S2-2 0.29986E-14 -14.5231 0.15535E-14 -14.8087 0.51807E+00 -0.2856 97 SO3-2 0.12873E-17 -17.8903 0.67655E-18 -18.1697 0.52557E+00 -0.2794 99 HSO4- 0.38403E-19 -19.4156 0.32165E-19 -19.4926 0.83756E+00 -0.0770 Charge balance for all species = 0.6985E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8837969E-10 -.2228388E-01 -.2242176E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981986E+06 0.0000 3 Cl- 0.1837607E-03 0.1846053E-03 0.6533432E+01 6.3153 4 SO4-- 0.8657358E-12 -.1946407E-04 -.1866499E+01 7.9112 5 HCO3- 0.3203445E-06 0.1748727E-04 0.1065169E+01 3.5573 6 HS- 0.3411765E-04 0.5358829E-04 0.1769190E+01 5.5841 7 Al+++ 0.9722712E-29 0.5311885E-05 0.1430734E+00 0.7390 8 H4SiO4 0.6959646E-03 0.1352453E-01 0.1297655E+04 -3.1574 9 Ca++ 0.1352688E-06 0.2321322E-06 0.9287219E-02 13.1018 10 Mg++ 0.2116195E-10 0.9329843E-10 0.2264327E-05 9.2942 11 Fe++ 0.5832518E-13 0.3626031E-07 0.2021508E-02 6.7350 12 K+ 0.1566675E-03 0.1574216E-03 0.6144797E+01 6.2467 13 Na+ 0.1988034E-01 0.2232682E-01 0.5123967E+03 8.3494 14 Mn++ 0.1867743E-10 0.2521217E-08 0.1382698E-03 9.2408 15 HPO4-- 0.4524772E-07 0.4635068E-07 0.4440956E-02 12.6295 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4139626E+02 -.1665499E-01 -.4137960E+02 0.0000000E+00 2 H2O 0.2416974E+02 0.4148441E+02 -.1731467E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6930900E-01 -.1454747E-04 0.6932355E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6928349E-01 0.4005194E-04 -.6932355E-01 0.0000000E+00 7 Al+++ 0.8151851E+01 0.3970108E-05 0.8151847E+01 0.0000000E+00 8 H4SiO4 0.2603195E+02 0.1010825E-01 0.2602184E+02 0.0000000E+00 9 Ca++ 0.2875370E+01 0.1734959E-06 0.2875370E+01 0.0000000E+00 10 Mg++ 0.1984126E+01 0.6973133E-10 0.1984126E+01 0.0000000E+00 11 Fe++ 0.1782521E+01 0.2710099E-07 0.1782521E+01 0.0000000E+00 12 K+ 0.5307854E+00 0.1176571E-03 0.5306677E+00 0.0000000E+00 13 Na+ 0.3138268E+01 0.1668709E-01 0.3121581E+01 0.0000000E+00 14 Mn++ 0.4334647E-01 0.1884360E-08 0.4334647E-01 0.0000000E+00 15 HPO4-- 0.1479394E-01 0.3464254E-07 0.1479390E-01 0.0000000E+00 Chg. balance for solid moles: -.1261E-13 Mass of aqueous solution: 0.748703E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.119 0.494 817.8 2.913 29.95 313.9 andradite 0.2773 -0.557 140.9 2.149 5.160 36.61 grossular 0.6715E-01 -1.173 30.25 1.481 1.108 8.416 apatite-OH 0.4931E-02 -2.307 2.477 0.394 0.9070E-01 0.7871 clinochlore 0.3558 -0.449 197.8 2.296 7.241 75.22 daphnite 0.1030 -0.987 73.49 1.866 2.691 22.27 chlorite-Mn 0.8669E-02 -2.062 6.146 0.789 0.2250 1.959 diopside 0.1267 -0.897 27.44 1.438 1.005 8.387 hedenbergite 0.3286E-01 -1.483 8.153 0.911 0.2985 2.233 microcline 0.4654 -0.332 129.5 2.112 4.743 50.60 stilbite 1.615 0.208 1138. 3.056 41.66 530.7 stilpnomelane-Fe 0.1306 -0.884 140.8 2.149 5.155 48.63 tr.625ac.25prg.125 0.2164E-01 -1.665 18.50 1.267 0.6772 5.953 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8050E+00 0.8050E+00 1.0000 -0.094 grossular 0.1950E+00 0.1950E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2731.071247 g Volume = 1105.701254 cm3 Porosity: -10.4597% V(tot) - V(min): -.10470E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2499.9990000 g log = 3.3979 Original solution: 1000.0103000 g Original solution / Rock added: 0.40 (Water/Rock Ratio), log = -0.3979 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0600 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9630E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4261E-08 1.0069 0.4548E-08 0.4517E-08 CH4,gas 0.2263E-01 1.0124 0.2429E-01 0.2399E-01 H2,gas 0.1434E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1703E-06 0.9959 0.1798E-06 0.1805E-06 S2,gas 0.4949E-29 1.0000 0.5246E-29 0.5246E-29 CO,gas 0.1739E-13 1.0000 0.1843E-13 0.1843E-13 SO3,gas 0.8840E-48 1.0000 0.9371E-48 0.9371E-48 SO2,gas 0.5230E-27 1.0000 0.5544E-27 0.5544E-27 HCl,gas 0.3476E-17 1.0000 0.3685E-17 0.3685E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.70 -10.04 -3.347 0.17145E+05 -8.342 3 CH4,gas 4.54 1.23 -3.31 -0.828 0.56578E+04 -1.615 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.67 -8.44 -4.222 0.14418E+05 -6.745 6 S2,gas -7.34 -38.31 -30.98 -4.766 0.52896E+05 -29.280 7 CO,gas 3.21 -12.22 -15.43 -4.749 0.26352E+05 -13.734 8 SO3,gas 17.12 -32.61 -49.73 -12.432 0.84908E+05 -48.028 9 SO2,gas 0.83 -28.12 -28.96 -7.721 0.49440E+05 -27.256 10 HCl,gas 5.19 -13.94 -19.13 -9.566 0.32668E+05 -17.434 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80749E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93623E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.60 -4.57 -1.522 0.77962E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.60 -4.41 -1.470 0.75320E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65562E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.74 -4.63 -1.324 0.79110E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.74 -4.19 -1.197 0.71533E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82254E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.94 -3.68 -1.226 0.62821E+04 144 pyrrhotiteFe0.875 -6.02 -9.34 -3.32 -1.221 0.56693E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22458E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23261E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.395 0.47154E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.94 -3.53 -1.176 0.60249E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79433E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62084E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.43 -4.46 -1.485 0.76081E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18243E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2499.9990000 g New total amount of reactant added: 2599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2599.9990000 Water: Moles liquid = 0.4093E+02 kg liquid = 0.7374E+00 Moles total = 0.2292E+02 kg total = 0.4128E+00 Activity = 1.0000 Stoichiometric ionic strength = .1135835E-01 Osmotic coef. = 0.9690 True ionic strength = .2003980E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88387E-10 -10.0536 0.74262E-10 -10.1292 0.84019E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18626E-03 -3.7299 0.15556E-03 -3.8081 0.83514E+00 -0.0782 4 SO4-- 0.87749E-12 -12.0568 0.45556E-12 -12.3415 0.51916E+00 -0.2847 5 HCO3- 0.32469E-06 -6.4885 0.27156E-06 -6.5661 0.83636E+00 -0.0776 6 HS- 0.34582E-04 -4.4611 0.28885E-04 -4.5393 0.83526E+00 -0.0782 7 Al+++ 0.97253E-29 -29.0121 0.22454E-29 -29.6487 0.23088E+00 -0.6366 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13529E-06 -6.8687 0.69722E-07 -7.1566 0.51535E+00 -0.2879 10 Mg++ 0.21166E-10 -10.6744 0.10858E-10 -10.9643 0.51299E+00 -0.2899 11 Fe++ 0.58335E-13 -13.2341 0.29958E-13 -13.5235 0.51355E+00 -0.2894 12 K+ 0.15668E-03 -3.8050 0.13107E-03 -3.8825 0.83656E+00 -0.0775 13 Na+ 0.19882E-01 -1.7015 0.16601E-01 -1.7799 0.83499E+00 -0.0783 14 Mn++ 0.18683E-10 -10.7285 0.96027E-11 -11.0176 0.51398E+00 -0.2891 15 HPO4-- 0.45242E-07 -7.3445 0.23491E-07 -7.6291 0.51924E+00 -0.2846 16 HSiO3- 0.10478E-01 -1.9797 0.87508E-02 -2.0580 0.83514E+00 -0.0782 17 Ca(HSiO3)+ 0.16606E-07 -7.7797 0.13895E-07 -7.8571 0.83674E+00 -0.0774 18 Mg(HSiO3)+ 0.32183E-11 -11.4924 0.26929E-11 -11.5698 0.83674E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66199E-16 -16.1792 0.55391E-16 -16.2566 0.83674E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53113E-05 -5.2748 0.44277E-05 -5.3538 0.83363E+00 -0.0790 24 CH4,aq 0.16784E-04 -4.7751 0.16726E-04 -4.7766 0.99654E+00 -0.0015 25 C2H6,aq 0.41432E-14 -14.3827 0.41289E-14 -14.3842 0.99654E+00 -0.0015 29 CO,aq 0.12539E-16 -16.9018 0.12539E-16 -16.9018 0.10000E+01 0.0000 30 CO2,aq 0.43241E-10 -10.3641 0.43091E-10 -10.3656 0.99654E+00 -0.0015 31 CO3-2 0.61654E-06 -6.2100 0.31940E-06 -6.4957 0.51806E+00 -0.2856 32 CaCO3,aq 0.27924E-09 -9.5540 0.27924E-09 -9.5540 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57760E-12 -12.2384 0.48330E-12 -12.3158 0.83674E+00 -0.0774 34 CaCl+ 0.20976E-10 -10.6783 0.17552E-10 -10.7557 0.83674E+00 -0.0774 35 CaCl2,aq 0.64866E-15 -15.1880 0.64866E-15 -15.1880 0.10000E+01 0.0000 36 CaOH+ 0.79968E-07 -7.0971 0.66913E-07 -7.1745 0.83674E+00 -0.0774 37 CaSO4,aq 0.10086E-16 -16.9963 0.10086E-16 -16.9963 0.10000E+01 0.0000 38 HCl,aq 0.21168E-14 -14.6743 0.21168E-14 -14.6743 0.10000E+01 0.0000 43 FeCl+ 0.88155E-17 -17.0548 0.73762E-17 -17.1322 0.83674E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15694E-10 -10.8043 0.13131E-10 -10.8817 0.83674E+00 -0.0774 48 HFeO2- 0.35619E-07 -7.4483 0.29747E-07 -7.5266 0.83514E+00 -0.0782 49 FeO+ 0.10999E-16 -16.9587 0.92029E-17 -17.0361 0.83674E+00 -0.0774 51 FeO2- 0.40887E-09 -9.3884 0.34146E-09 -9.4667 0.83514E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.36954E-09 -9.4323 0.36954E-09 -9.4323 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.11095E-14 -14.9549 0.92657E-15 -15.0331 0.83514E+00 -0.0782 58 MgCO3,aq 0.10900E-13 -13.9626 0.10900E-13 -13.9626 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.91911E-16 -16.0366 0.76905E-16 -16.1140 0.83674E+00 -0.0774 60 MgCl+ 0.29607E-14 -14.5286 0.24773E-14 -14.6060 0.83674E+00 -0.0774 61 MgOH+ 0.68910E-10 -10.1617 0.57660E-10 -10.2391 0.83674E+00 -0.0774 63 MnO,aq 0.18032E-08 -8.7439 0.18032E-08 -8.7439 0.10000E+01 0.0000 64 MnOH+ 0.46731E-09 -9.3304 0.39101E-09 -9.4078 0.83674E+00 -0.0774 65 MnO2-2 0.20946E-10 -10.6789 0.10851E-10 -10.9645 0.51806E+00 -0.2856 66 HMnO2- 0.21140E-09 -9.6749 0.17655E-09 -9.7531 0.83514E+00 -0.0782 69 MnCl+ 0.10993E-13 -13.9589 0.91985E-14 -14.0363 0.83674E+00 -0.0774 71 NaCl,aq 0.85582E-06 -6.0676 0.85582E-06 -6.0676 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93329E-02 -2.0300 0.77802E-02 -2.1090 0.83363E+00 -0.0790 79 HPO3-2 0.16368E-14 -14.7860 0.84796E-15 -15.0716 0.51806E+00 -0.2856 81 H2PO3- 0.15120E-18 -18.8204 0.12628E-18 -18.8987 0.83514E+00 -0.0782 82 H3PO4,aq 0.90607E-18 -18.0428 0.90607E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38498E-10 -10.4146 0.32181E-10 -10.4924 0.83593E+00 -0.0778 84 PO4-3 0.10643E-08 -8.9730 0.25809E-09 -9.5882 0.24251E+00 -0.6153 88 HP2O7-3 0.94475E-18 -18.0247 0.21835E-18 -18.6609 0.23111E+00 -0.6362 89 P2O7-4 0.91195E-17 -17.0400 0.70240E-18 -18.1534 0.77022E-01 -1.1134 90 H2S,aq 0.66527E-08 -8.1770 0.66296E-08 -8.1785 0.99654E+00 -0.0015 91 S2-2 0.30809E-14 -14.5113 0.15961E-14 -14.7969 0.51806E+00 -0.2856 97 SO3-2 0.13047E-17 -17.8845 0.68571E-18 -18.1639 0.52556E+00 -0.2794 99 HSO4- 0.38927E-19 -19.4098 0.32603E-19 -19.4867 0.83755E+00 -0.0770 Charge balance for all species = 0.7080E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8838680E-10 -.2228252E-01 -.2242039E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981985E+06 0.0000 3 Cl- 0.1862634E-03 0.1871196E-03 0.6622415E+01 6.3211 4 SO4-- 0.8774880E-12 -.1968967E-04 -.1888132E+01 7.9170 5 HCO3- 0.3246912E-06 0.1772544E-04 0.1079676E+01 3.5631 6 HS- 0.3458232E-04 0.5427865E-04 0.1791982E+01 5.5899 7 Al+++ 0.9725336E-29 0.5311488E-05 0.1430627E+00 0.7390 8 H4SiO4 0.6959657E-03 0.1352382E-01 0.1297587E+04 -3.1574 9 Ca++ 0.1352919E-06 0.2321671E-06 0.9288612E-02 13.1018 10 Mg++ 0.2116557E-10 0.9330797E-10 0.2264559E-05 9.2942 11 Fe++ 0.5833522E-13 0.3625777E-07 0.2021367E-02 6.7350 12 K+ 0.1566801E-03 0.1574343E-03 0.6145290E+01 6.2467 13 Na+ 0.1988195E-01 0.2232845E-01 0.5124339E+03 8.3494 14 Mn++ 0.1868319E-10 0.2521584E-08 0.1382899E-03 9.2409 15 HPO4-- 0.4524198E-07 0.4634475E-07 0.4440388E-02 12.6294 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4305211E+02 -.1643020E-01 -.4303568E+02 0.0000000E+00 2 H2O 0.2291620E+02 0.4092699E+02 -.1801080E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7208034E-01 -.1451834E-04 0.7209486E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7205484E-01 0.4002281E-04 -.7209486E-01 0.0000000E+00 7 Al+++ 0.8477925E+01 0.3916470E-05 0.8477921E+01 0.0000000E+00 8 H4SiO4 0.2707323E+02 0.9971902E-02 0.2706325E+02 0.0000000E+00 9 Ca++ 0.2990384E+01 0.1711903E-06 0.2990384E+01 0.0000000E+00 10 Mg++ 0.2063491E+01 0.6880141E-10 0.2063491E+01 0.0000000E+00 11 Fe++ 0.1853822E+01 0.2673497E-07 0.1853822E+01 0.0000000E+00 12 K+ 0.5520168E+00 0.1160855E-03 0.5519007E+00 0.0000000E+00 13 Na+ 0.3263792E+01 0.1646407E-01 0.3247328E+01 0.0000000E+00 14 Mn++ 0.4508033E-01 0.1859311E-08 0.4508033E-01 0.0000000E+00 15 HPO4-- 0.1538569E-01 0.3417268E-07 0.1538566E-01 0.0000000E+00 Chg. balance for solid moles: 0.5287E-14 Mass of aqueous solution: 0.738643E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.245 0.511 850.8 2.930 29.95 326.6 andradite 0.2884 -0.540 146.5 2.166 5.160 38.07 grossular 0.6983E-01 -1.156 31.46 1.498 1.107 8.752 apatite-OH 0.5129E-02 -2.290 2.576 0.411 0.9070E-01 0.8186 clinochlore 0.3700 -0.432 205.6 2.313 7.240 78.22 daphnite 0.1071 -0.970 76.42 1.883 2.691 23.16 chlorite-Mn 0.9016E-02 -2.045 6.392 0.806 0.2250 2.037 diopside 0.1322 -0.879 28.62 1.457 1.008 8.747 hedenbergite 0.3427E-01 -1.465 8.503 0.930 0.2994 2.329 microcline 0.4840 -0.315 134.7 2.129 4.743 52.62 stilbite 1.679 0.225 1183. 3.073 41.65 551.8 stilpnomelane-Fe 0.1358 -0.867 146.4 2.166 5.155 50.58 tr.625ac.25prg.125 0.2247E-01 -1.648 19.21 1.283 0.6763 6.182 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2840.321911 g Volume = 1149.904318 cm3 Porosity: -10.4616% V(tot) - V(min): -.10890E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2599.9990000 g log = 3.4150 Original solution: 1000.0103000 g Original solution / Rock added: 0.38 (Water/Rock Ratio), log = -0.4150 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0604 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9627E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4318E-08 1.0069 0.4610E-08 0.4579E-08 CH4,gas 0.2293E-01 1.0124 0.2462E-01 0.2432E-01 H2,gas 0.1433E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1726E-06 0.9959 0.1822E-06 0.1830E-06 S2,gas 0.5084E-29 1.0000 0.5391E-29 0.5391E-29 CO,gas 0.1762E-13 1.0000 0.1868E-13 0.1868E-13 SO3,gas 0.8958E-48 1.0000 0.9499E-48 0.9499E-48 SO2,gas 0.5300E-27 1.0000 0.5620E-27 0.5620E-27 HCl,gas 0.3523E-17 1.0000 0.3735E-17 0.3735E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.70 -10.04 -3.345 0.17135E+05 -8.336 3 CH4,gas 4.54 1.24 -3.31 -0.827 0.56478E+04 -1.609 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.67 -8.44 -4.219 0.14408E+05 -6.739 6 S2,gas -7.34 -38.30 -30.97 -4.764 0.52876E+05 -29.268 7 CO,gas 3.21 -12.21 -15.43 -4.747 0.26342E+05 -13.729 8 SO3,gas 17.12 -32.60 -49.72 -12.430 0.84898E+05 -48.022 9 SO2,gas 0.83 -28.12 -28.95 -7.720 0.49430E+05 -27.250 10 HCl,gas 5.19 -13.94 -19.13 -9.563 0.32658E+05 -17.428 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80746E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.59 -4.56 -1.520 0.77862E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.59 -4.41 -1.468 0.75219E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65561E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.73 -4.63 -1.322 0.79010E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65867E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.73 -4.18 -1.195 0.71432E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82253E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19848E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91156E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40579E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.93 -3.67 -1.224 0.62720E+04 144 pyrrhotiteFe0.875 -6.02 -9.33 -3.31 -1.219 0.56592E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22457E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28682E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23260E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47152E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.93 -3.52 -1.174 0.60148E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79433E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.43 -4.45 -1.483 0.75980E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2599.9990000 g New total amount of reactant added: 2699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2699.9990000 Water: Moles liquid = 0.4037E+02 kg liquid = 0.7273E+00 Moles total = 0.2166E+02 kg total = 0.3903E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136049E-01 Osmotic coef. = 0.9690 True ionic strength = .2004147E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88394E-10 -10.0536 0.74268E-10 -10.1292 0.84019E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18884E-03 -3.7239 0.15770E-03 -3.8022 0.83513E+00 -0.0782 4 SO4-- 0.88956E-12 -12.0508 0.46182E-12 -12.3355 0.51915E+00 -0.2847 5 HCO3- 0.32916E-06 -6.4826 0.27529E-06 -6.5602 0.83636E+00 -0.0776 6 HS- 0.35060E-04 -4.4552 0.29284E-04 -4.5334 0.83526E+00 -0.0782 7 Al+++ 0.97280E-29 -29.0120 0.22459E-29 -29.6486 0.23087E+00 -0.6366 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13532E-06 -6.8687 0.69733E-07 -7.1566 0.51534E+00 -0.2879 10 Mg++ 0.21169E-10 -10.6743 0.10859E-10 -10.9642 0.51298E+00 -0.2899 11 Fe++ 0.58346E-13 -13.2340 0.29963E-13 -13.5234 0.51354E+00 -0.2894 12 K+ 0.15669E-03 -3.8050 0.13108E-03 -3.8825 0.83656E+00 -0.0775 13 Na+ 0.19884E-01 -1.7015 0.16602E-01 -1.7798 0.83498E+00 -0.0783 14 Mn++ 0.18689E-10 -10.7284 0.96054E-11 -11.0175 0.51397E+00 -0.2891 15 HPO4-- 0.45236E-07 -7.3445 0.23488E-07 -7.6292 0.51922E+00 -0.2846 16 HSiO3- 0.10478E-01 -1.9797 0.87501E-02 -2.0580 0.83513E+00 -0.0782 17 Ca(HSiO3)+ 0.16607E-07 -7.7797 0.13896E-07 -7.8571 0.83673E+00 -0.0774 18 Mg(HSiO3)+ 0.32186E-11 -11.4923 0.26931E-11 -11.5697 0.83673E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66204E-16 -16.1791 0.55395E-16 -16.2565 0.83673E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53109E-05 -5.2748 0.44273E-05 -5.3539 0.83362E+00 -0.0790 24 CH4,aq 0.17016E-04 -4.7691 0.16957E-04 -4.7707 0.99654E+00 -0.0015 25 C2H6,aq 0.42585E-14 -14.3707 0.42437E-14 -14.3723 0.99654E+00 -0.0015 29 CO,aq 0.12712E-16 -16.8958 0.12712E-16 -16.8958 0.10000E+01 0.0000 30 CO2,aq 0.43839E-10 -10.3581 0.43687E-10 -10.3596 0.99654E+00 -0.0015 31 CO3-2 0.62498E-06 -6.2041 0.32377E-06 -6.4898 0.51805E+00 -0.2856 32 CaCO3,aq 0.28310E-09 -9.5481 0.28310E-09 -9.5481 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58564E-12 -12.2324 0.49002E-12 -12.3098 0.83673E+00 -0.0774 34 CaCl+ 0.21269E-10 -10.6722 0.17797E-10 -10.7497 0.83673E+00 -0.0774 35 CaCl2,aq 0.66679E-15 -15.1760 0.66679E-15 -15.1760 0.10000E+01 0.0000 36 CaOH+ 0.79975E-07 -7.0970 0.66918E-07 -7.1745 0.83673E+00 -0.0774 37 CaSO4,aq 0.10226E-16 -16.9903 0.10226E-16 -16.9903 0.10000E+01 0.0000 38 HCl,aq 0.21462E-14 -14.6683 0.21462E-14 -14.6683 0.10000E+01 0.0000 43 FeCl+ 0.89386E-17 -17.0487 0.74792E-17 -17.1261 0.83673E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15695E-10 -10.8042 0.13132E-10 -10.8817 0.83673E+00 -0.0774 48 HFeO2- 0.35616E-07 -7.4484 0.29744E-07 -7.5266 0.83513E+00 -0.0782 49 FeO+ 0.10999E-16 -16.9586 0.92036E-17 -17.0360 0.83673E+00 -0.0774 51 FeO2- 0.40884E-09 -9.3885 0.34143E-09 -9.4667 0.83513E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99654E+00 -0.0015 54 KCl,aq 0.37466E-09 -9.4264 0.37466E-09 -9.4264 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.11248E-14 -14.9489 0.93937E-15 -15.0272 0.83513E+00 -0.0782 58 MgCO3,aq 0.11050E-13 -13.9566 0.11050E-13 -13.9566 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.93189E-16 -16.0306 0.77975E-16 -16.1080 0.83673E+00 -0.0774 60 MgCl+ 0.30020E-14 -14.5226 0.25119E-14 -14.6000 0.83673E+00 -0.0774 61 MgOH+ 0.68916E-10 -10.1617 0.57664E-10 -10.2391 0.83673E+00 -0.0774 63 MnO,aq 0.18035E-08 -8.7439 0.18035E-08 -8.7439 0.10000E+01 0.0000 64 MnOH+ 0.46740E-09 -9.3303 0.39109E-09 -9.4077 0.83673E+00 -0.0774 65 MnO2-2 0.20946E-10 -10.6789 0.10851E-10 -10.9645 0.51805E+00 -0.2856 66 HMnO2- 0.21141E-09 -9.6749 0.17656E-09 -9.7531 0.83513E+00 -0.0782 69 MnCl+ 0.11148E-13 -13.9528 0.93281E-14 -14.0302 0.83673E+00 -0.0774 71 NaCl,aq 0.86769E-06 -6.0616 0.86769E-06 -6.0616 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93322E-02 -2.0300 0.77796E-02 -2.1090 0.83362E+00 -0.0790 79 HPO3-2 0.16366E-14 -14.7861 0.84783E-15 -15.0717 0.51805E+00 -0.2856 81 H2PO3- 0.15119E-18 -18.8205 0.12627E-18 -18.8987 0.83513E+00 -0.0782 82 H3PO4,aq 0.90608E-18 -18.0428 0.90608E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38495E-10 -10.4146 0.32179E-10 -10.4924 0.83593E+00 -0.0778 84 PO4-3 0.10641E-08 -8.9730 0.25803E-09 -9.5883 0.24249E+00 -0.6153 88 HP2O7-3 0.94458E-18 -18.0248 0.21830E-18 -18.6610 0.23110E+00 -0.6362 89 P2O7-4 0.91175E-17 -17.0401 0.70219E-18 -18.1535 0.77015E-01 -1.1134 90 H2S,aq 0.67450E-08 -8.1710 0.67217E-08 -8.1725 0.99654E+00 -0.0015 91 S2-2 0.31666E-14 -14.4994 0.16405E-14 -14.7850 0.51805E+00 -0.2856 97 SO3-2 0.13227E-17 -17.8785 0.69513E-18 -18.1579 0.52555E+00 -0.2794 99 HSO4- 0.39465E-19 -19.4038 0.33054E-19 -19.4808 0.83755E+00 -0.0770 Charge balance for all species = 0.7178E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8839411E-10 -.2228112E-01 -.2241898E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981984E+06 0.0000 3 Cl- 0.1888352E-03 0.1897033E-03 0.6713855E+01 6.3270 4 SO4-- 0.8895623E-12 -.1992150E-04 -.1910363E+01 7.9229 5 HCO3- 0.3291570E-06 0.1797019E-04 0.1094584E+01 3.5690 6 HS- 0.3505983E-04 0.5498807E-04 0.1815403E+01 5.5958 7 Al+++ 0.9728038E-29 0.5311083E-05 0.1430518E+00 0.7390 8 H4SiO4 0.6959668E-03 0.1352309E-01 0.1297517E+04 -3.1574 9 Ca++ 0.1353157E-06 0.2322029E-06 0.9290043E-02 13.1018 10 Mg++ 0.2116929E-10 0.9331778E-10 0.2264797E-05 9.2942 11 Fe++ 0.5834553E-13 0.3625516E-07 0.2021221E-02 6.7350 12 K+ 0.1566931E-03 0.1574473E-03 0.6145797E+01 6.2467 13 Na+ 0.1988360E-01 0.2233011E-01 0.5124721E+03 8.3494 14 Mn++ 0.1868886E-10 0.2521926E-08 0.1383086E-03 9.2409 15 HPO4-- 0.4523608E-07 0.4633864E-07 0.4439803E-02 12.6292 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4470796E+02 -.1620541E-01 -.4469176E+02 0.0000000E+00 2 H2O 0.2166265E+02 0.4036958E+02 -.1870692E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7485168E-01 -.1448922E-04 0.7486617E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7482618E-01 0.3999369E-04 -.7486617E-01 0.0000000E+00 7 Al+++ 0.8803999E+01 0.3862834E-05 0.8803995E+01 0.0000000E+00 8 H4SiO4 0.2811450E+02 0.9835554E-02 0.2810467E+02 0.0000000E+00 9 Ca++ 0.3105398E+01 0.1688848E-06 0.3105398E+01 0.0000000E+00 10 Mg++ 0.2142856E+01 0.6787149E-10 0.2142856E+01 0.0000000E+00 11 Fe++ 0.1925122E+01 0.2636895E-07 0.1925122E+01 0.0000000E+00 12 K+ 0.5732482E+00 0.1145139E-03 0.5731337E+00 0.0000000E+00 13 Na+ 0.3389317E+01 0.1624104E-01 0.3373076E+01 0.0000000E+00 14 Mn++ 0.4681419E-01 0.1834236E-08 0.4681419E-01 0.0000000E+00 15 HPO4-- 0.1597745E-01 0.3370282E-07 0.1597742E-01 0.0000000E+00 Chg. balance for solid moles: 0.5732E-14 Mass of aqueous solution: 0.728583E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.370 0.528 883.7 2.946 29.96 339.2 andradite 0.2995 -0.524 152.2 2.182 5.159 39.54 grossular 0.7252E-01 -1.140 32.67 1.514 1.107 9.089 apatite-OH 0.5326E-02 -2.274 2.675 0.427 0.9070E-01 0.8501 clinochlore 0.3842 -0.415 213.5 2.329 7.239 81.22 daphnite 0.1112 -0.954 79.35 1.900 2.690 24.05 chlorite-Mn 0.9363E-02 -2.029 6.638 0.822 0.2250 2.115 diopside 0.1376 -0.861 29.80 1.474 1.010 9.107 hedenbergite 0.3568E-01 -1.448 8.853 0.947 0.3001 2.425 microcline 0.5026 -0.299 139.9 2.146 4.743 54.65 stilbite 1.743 0.241 1228. 3.089 41.64 572.9 stilpnomelane-Fe 0.1411 -0.851 152.1 2.182 5.156 52.53 tr.625ac.25prg.125 0.2331E-01 -1.633 19.92 1.299 0.6754 6.411 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2949.572575 g Volume = 1194.107382 cm3 Porosity: -10.4633% V(tot) - V(min): -.11311E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2699.9990000 g log = 3.4314 Original solution: 1000.0103000 g Original solution / Rock added: 0.37 (Water/Rock Ratio), log = -0.4314 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0607 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9624E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4377E-08 1.0068 0.4674E-08 0.4642E-08 CH4,gas 0.2324E-01 1.0124 0.2496E-01 0.2465E-01 H2,gas 0.1433E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1749E-06 0.9959 0.1848E-06 0.1855E-06 S2,gas 0.5224E-29 1.0000 0.5542E-29 0.5542E-29 CO,gas 0.1786E-13 1.0000 0.1894E-13 0.1894E-13 SO3,gas 0.9080E-48 1.0000 0.9631E-48 0.9631E-48 SO2,gas 0.5372E-27 1.0000 0.5698E-27 0.5698E-27 HCl,gas 0.3570E-17 1.0000 0.3787E-17 0.3787E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.69 -10.03 -3.343 0.17125E+05 -8.330 3 CH4,gas 4.54 1.24 -3.30 -0.825 0.56376E+04 -1.603 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.66 -8.43 -4.216 0.14398E+05 -6.733 6 S2,gas -7.34 -38.29 -30.96 -4.762 0.52855E+05 -29.256 7 CO,gas 3.21 -12.21 -15.42 -4.745 0.26332E+05 -13.723 8 SO3,gas 17.12 -32.59 -49.72 -12.429 0.84888E+05 -48.016 9 SO2,gas 0.83 -28.11 -28.94 -7.718 0.49420E+05 -27.244 10 HCl,gas 5.19 -13.93 -19.12 -9.560 0.32648E+05 -17.422 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80744E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.27 -4.45 -0.342 0.75902E+04 35 aragonite 0.97 -3.59 -4.55 -1.518 0.77760E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.59 -4.40 -1.466 0.75118E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70428E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65560E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.72 -4.62 -1.320 0.78908E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.72 -4.18 -1.194 0.71331E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64125E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.27 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82252E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.93 -3.67 -1.222 0.62618E+04 144 pyrrhotiteFe0.875 -6.02 -9.33 -3.31 -1.217 0.56490E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22456E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23259E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47150E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.93 -3.52 -1.172 0.60046E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79434E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.42 -4.44 -1.481 0.75876E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2699.9990000 g New total amount of reactant added: 2799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2799.9990000 Water: Moles liquid = 0.3981E+02 kg liquid = 0.7173E+00 Moles total = 0.2041E+02 kg total = 0.3677E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136269E-01 Osmotic coef. = 0.9690 True ionic strength = .2004319E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88402E-10 -10.0535 0.74274E-10 -10.1292 0.84019E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19148E-03 -3.7179 0.15991E-03 -3.7961 0.83513E+00 -0.0782 4 SO4-- 0.90197E-12 -12.0448 0.46825E-12 -12.3295 0.51914E+00 -0.2847 5 HCO3- 0.33375E-06 -6.4766 0.27913E-06 -6.5542 0.83635E+00 -0.0776 6 HS- 0.35551E-04 -4.4492 0.29694E-04 -4.5273 0.83525E+00 -0.0782 7 Al+++ 0.97308E-29 -29.0119 0.22465E-29 -29.6485 0.23086E+00 -0.6367 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13534E-06 -6.8686 0.69744E-07 -7.1565 0.51532E+00 -0.2879 10 Mg++ 0.21173E-10 -10.6742 0.10861E-10 -10.9641 0.51297E+00 -0.2899 11 Fe++ 0.58356E-13 -13.2339 0.29967E-13 -13.5233 0.51353E+00 -0.2894 12 K+ 0.15671E-03 -3.8049 0.13109E-03 -3.8824 0.83655E+00 -0.0775 13 Na+ 0.19885E-01 -1.7015 0.16604E-01 -1.7798 0.83498E+00 -0.0783 14 Mn++ 0.18694E-10 -10.7283 0.96081E-11 -11.0174 0.51395E+00 -0.2891 15 HPO4-- 0.45230E-07 -7.3446 0.23484E-07 -7.6292 0.51921E+00 -0.2847 16 HSiO3- 0.10477E-01 -1.9798 0.87494E-02 -2.0580 0.83513E+00 -0.0782 17 Ca(HSiO3)+ 0.16609E-07 -7.7797 0.13897E-07 -7.8571 0.83673E+00 -0.0774 18 Mg(HSiO3)+ 0.32189E-11 -11.4923 0.26933E-11 -11.5697 0.83673E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66209E-16 -16.1791 0.55399E-16 -16.2565 0.83673E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53105E-05 -5.2749 0.44270E-05 -5.3539 0.83362E+00 -0.0790 24 CH4,aq 0.17254E-04 -4.7631 0.17194E-04 -4.7646 0.99653E+00 -0.0015 25 C2H6,aq 0.43786E-14 -14.3587 0.43634E-14 -14.3602 0.99653E+00 -0.0015 29 CO,aq 0.12890E-16 -16.8897 0.12890E-16 -16.8897 0.10000E+01 0.0000 30 CO2,aq 0.44454E-10 -10.3521 0.44299E-10 -10.3536 0.99653E+00 -0.0015 31 CO3-2 0.63366E-06 -6.1981 0.32826E-06 -6.4838 0.51804E+00 -0.2856 32 CaCO3,aq 0.28707E-09 -9.5420 0.28707E-09 -9.5420 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.59390E-12 -12.2263 0.49693E-12 -12.3037 0.83673E+00 -0.0774 34 CaCl+ 0.21570E-10 -10.6661 0.18049E-10 -10.7436 0.83673E+00 -0.0774 35 CaCl2,aq 0.68569E-15 -15.1639 0.68569E-15 -15.1639 0.10000E+01 0.0000 36 CaOH+ 0.79982E-07 -7.0970 0.66923E-07 -7.1744 0.83673E+00 -0.0774 37 CaSO4,aq 0.10370E-16 -16.9842 0.10370E-16 -16.9842 0.10000E+01 0.0000 38 HCl,aq 0.21764E-14 -14.6623 0.21764E-14 -14.6623 0.10000E+01 0.0000 43 FeCl+ 0.90651E-17 -17.0426 0.75851E-17 -17.1200 0.83673E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15696E-10 -10.8042 0.13133E-10 -10.8816 0.83673E+00 -0.0774 48 HFeO2- 0.35614E-07 -7.4484 0.29742E-07 -7.5266 0.83513E+00 -0.0782 49 FeO+ 0.11000E-16 -16.9586 0.92044E-17 -17.0360 0.83673E+00 -0.0774 51 FeO2- 0.40881E-09 -9.3885 0.34141E-09 -9.4667 0.83513E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.37994E-09 -9.4203 0.37994E-09 -9.4203 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.11406E-14 -14.9429 0.95253E-15 -15.0211 0.83513E+00 -0.0782 58 MgCO3,aq 0.11205E-13 -13.9506 0.11205E-13 -13.9506 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.94504E-16 -16.0246 0.79074E-16 -16.1020 0.83673E+00 -0.0774 60 MgCl+ 0.30445E-14 -14.5165 0.25474E-14 -14.5939 0.83673E+00 -0.0774 61 MgOH+ 0.68922E-10 -10.1616 0.57669E-10 -10.2391 0.83673E+00 -0.0774 63 MnO,aq 0.18037E-08 -8.7438 0.18037E-08 -8.7438 0.10000E+01 0.0000 64 MnOH+ 0.46750E-09 -9.3302 0.39117E-09 -9.4076 0.83673E+00 -0.0774 65 MnO2-2 0.20946E-10 -10.6789 0.10851E-10 -10.9645 0.51804E+00 -0.2856 66 HMnO2- 0.21142E-09 -9.6748 0.17656E-09 -9.7531 0.83513E+00 -0.0782 69 MnCl+ 0.11307E-13 -13.9466 0.94612E-14 -14.0241 0.83673E+00 -0.0774 71 NaCl,aq 0.87991E-06 -6.0556 0.87991E-06 -6.0556 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93316E-02 -2.0300 0.77790E-02 -2.1091 0.83362E+00 -0.0790 79 HPO3-2 0.16364E-14 -14.7861 0.84769E-15 -15.0718 0.51804E+00 -0.2856 81 H2PO3- 0.15118E-18 -18.8205 0.12626E-18 -18.8987 0.83513E+00 -0.0782 82 H3PO4,aq 0.90608E-18 -18.0428 0.90608E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38492E-10 -10.4146 0.32177E-10 -10.4925 0.83592E+00 -0.0778 84 PO4-3 0.10639E-08 -8.9731 0.25797E-09 -9.5884 0.24248E+00 -0.6153 88 HP2O7-3 0.94441E-18 -18.0248 0.21824E-18 -18.6611 0.23109E+00 -0.6362 89 P2O7-4 0.91155E-17 -17.0402 0.70197E-18 -18.1537 0.77008E-01 -1.1135 90 H2S,aq 0.68400E-08 -8.1649 0.68163E-08 -8.1665 0.99653E+00 -0.0015 91 S2-2 0.32560E-14 -14.4873 0.16867E-14 -14.7730 0.51804E+00 -0.2856 97 SO3-2 0.13411E-17 -17.8725 0.70481E-18 -18.1519 0.52554E+00 -0.2794 99 HSO4- 0.40018E-19 -19.3977 0.33517E-19 -19.4747 0.83755E+00 -0.0770 Charge balance for all species = 0.7278E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8840161E-10 -.2227969E-01 -.2241754E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981983E+06 0.0000 3 Cl- 0.1914790E-03 0.1923594E-03 0.6807856E+01 6.3330 4 SO4-- 0.9019724E-12 -.2015982E-04 -.1933217E+01 7.9288 5 HCO3- 0.3337469E-06 0.1822179E-04 0.1109909E+01 3.5750 6 HS- 0.3555071E-04 0.5571737E-04 0.1839480E+01 5.6018 7 Al+++ 0.9730818E-29 0.5310670E-05 0.1430406E+00 0.7390 8 H4SiO4 0.6959678E-03 0.1352233E-01 0.1297444E+04 -3.1574 9 Ca++ 0.1353402E-06 0.2322397E-06 0.9291516E-02 13.1018 10 Mg++ 0.2117312E-10 0.9332787E-10 0.2265041E-05 9.2942 11 Fe++ 0.5835613E-13 0.3625248E-07 0.2021071E-02 6.7350 12 K+ 0.1567065E-03 0.1574606E-03 0.6146318E+01 6.2467 13 Na+ 0.1988530E-01 0.2233182E-01 0.5125114E+03 8.3494 14 Mn++ 0.1869446E-10 0.2522246E-08 0.1383262E-03 9.2410 15 HPO4-- 0.4523000E-07 0.4633236E-07 0.4439200E-02 12.6291 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4636381E+02 -.1598062E-01 -.4634783E+02 0.0000000E+00 2 H2O 0.2040911E+02 0.3981216E+02 -.1940305E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7762302E-01 -.1446010E-04 0.7763748E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7759752E-01 0.3996457E-04 -.7763748E-01 0.0000000E+00 7 Al+++ 0.9130073E+01 0.3809200E-05 0.9130069E+01 0.0000000E+00 8 H4SiO4 0.2915578E+02 0.9699206E-02 0.2914608E+02 0.0000000E+00 9 Ca++ 0.3220413E+01 0.1665793E-06 0.3220413E+01 0.0000000E+00 10 Mg++ 0.2222221E+01 0.6694156E-10 0.2222221E+01 0.0000000E+00 11 Fe++ 0.1996423E+01 0.2600293E-07 0.1996423E+01 0.0000000E+00 12 K+ 0.5944796E+00 0.1129423E-03 0.5943667E+00 0.0000000E+00 13 Na+ 0.3514841E+01 0.1601802E-01 0.3498823E+01 0.0000000E+00 14 Mn++ 0.4854805E-01 0.1809139E-08 0.4854805E-01 0.0000000E+00 15 HPO4-- 0.1656921E-01 0.3323296E-07 0.1656918E-01 0.0000000E+00 Chg. balance for solid moles: -.1374E-13 Mass of aqueous solution: 0.718523E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.496 0.544 916.7 2.962 29.97 351.9 andradite 0.3105 -0.508 157.8 2.198 5.159 41.00 grossular 0.7520E-01 -1.124 33.87 1.530 1.107 9.425 apatite-OH 0.5523E-02 -2.258 2.774 0.443 0.9070E-01 0.8816 clinochlore 0.3983 -0.400 221.4 2.345 7.238 84.22 daphnite 0.1153 -0.938 82.28 1.915 2.690 24.93 chlorite-Mn 0.9710E-02 -2.013 6.884 0.838 0.2250 2.194 diopside 0.1430 -0.845 30.98 1.491 1.013 9.467 hedenbergite 0.3709E-01 -1.431 9.203 0.964 0.3009 2.521 microcline 0.5212 -0.283 145.1 2.162 4.743 56.67 stilbite 1.807 0.257 1274. 3.105 41.63 594.0 stilpnomelane-Fe 0.1463 -0.835 157.7 2.198 5.156 54.48 tr.625ac.25prg.125 0.2414E-01 -1.617 20.63 1.315 0.6745 6.641 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3058.823240 g Volume = 1238.310446 cm3 Porosity: -10.4648% V(tot) - V(min): -.11731E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2799.9990000 g log = 3.4472 Original solution: 1000.0103000 g Original solution / Rock added: 0.36 (Water/Rock Ratio), log = -0.4472 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0611 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9621E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4436E-08 1.0068 0.4740E-08 0.4707E-08 CH4,gas 0.2356E-01 1.0124 0.2531E-01 0.2500E-01 H2,gas 0.1432E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1773E-06 0.9959 0.1874E-06 0.1882E-06 S2,gas 0.5371E-29 1.0000 0.5699E-29 0.5699E-29 CO,gas 0.1810E-13 1.0000 0.1921E-13 0.1921E-13 SO3,gas 0.9205E-48 1.0000 0.9767E-48 0.9767E-48 SO2,gas 0.5446E-27 1.0000 0.5778E-27 0.5778E-27 HCl,gas 0.3619E-17 1.0000 0.3840E-17 0.3840E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.68 -10.02 -3.341 0.17114E+05 -8.324 3 CH4,gas 4.54 1.25 -3.30 -0.824 0.56273E+04 -1.597 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60050E+04 -1.818 5 H2S,gas -6.23 -14.66 -8.43 -4.213 0.14388E+05 -6.727 6 S2,gas -7.34 -38.28 -30.94 -4.760 0.52835E+05 -29.244 7 CO,gas 3.21 -12.20 -15.42 -4.743 0.26322E+05 -13.717 8 SO3,gas 17.12 -32.59 -49.71 -12.427 0.84877E+05 -48.010 9 SO2,gas 0.83 -28.11 -28.94 -7.717 0.49409E+05 -27.238 10 HCl,gas 5.19 -13.93 -19.11 -9.557 0.32638E+05 -17.416 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80741E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.58 -4.55 -1.516 0.77657E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.58 -4.39 -1.464 0.75014E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65559E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36449E+04 66 diamond -3.10 -7.72 -4.62 -1.319 0.78805E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.72 -4.17 -1.192 0.71227E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61112E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82251E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41124E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.92 -3.66 -1.220 0.62514E+04 144 pyrrhotiteFe0.875 -6.02 -9.32 -3.30 -1.215 0.56386E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22455E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23258E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47148E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.92 -3.51 -1.170 0.59942E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79434E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.42 -4.44 -1.479 0.75772E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2799.9990000 g New total amount of reactant added: 2899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2899.9990000 Water: Moles liquid = 0.3926E+02 kg liquid = 0.7072E+00 Moles total = 0.1916E+02 kg total = 0.3451E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136496E-01 Osmotic coef. = 0.9690 True ionic strength = .2004495E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88409E-10 -10.0535 0.74280E-10 -10.1291 0.84018E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19420E-03 -3.7118 0.16218E-03 -3.7900 0.83512E+00 -0.0782 4 SO4-- 0.91473E-12 -12.0387 0.47486E-12 -12.3234 0.51913E+00 -0.2847 5 HCO3- 0.33847E-06 -6.4705 0.28308E-06 -6.5481 0.83635E+00 -0.0776 6 HS- 0.36056E-04 -4.4430 0.30115E-04 -4.5212 0.83525E+00 -0.0782 7 Al+++ 0.97337E-29 -29.0117 0.22470E-29 -29.6484 0.23085E+00 -0.6367 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13537E-06 -6.8685 0.69755E-07 -7.1564 0.51531E+00 -0.2879 10 Mg++ 0.21177E-10 -10.6741 0.10863E-10 -10.9641 0.51295E+00 -0.2899 11 Fe++ 0.58367E-13 -13.2338 0.29972E-13 -13.5233 0.51352E+00 -0.2894 12 K+ 0.15672E-03 -3.8049 0.13110E-03 -3.8824 0.83655E+00 -0.0775 13 Na+ 0.19887E-01 -1.7014 0.16605E-01 -1.7798 0.83497E+00 -0.0783 14 Mn++ 0.18700E-10 -10.7282 0.96107E-11 -11.0172 0.51394E+00 -0.2891 15 HPO4-- 0.45224E-07 -7.3446 0.23480E-07 -7.6293 0.51920E+00 -0.2847 16 HSiO3- 0.10476E-01 -1.9798 0.87487E-02 -2.0581 0.83512E+00 -0.0782 17 Ca(HSiO3)+ 0.16610E-07 -7.7796 0.13898E-07 -7.8570 0.83673E+00 -0.0774 18 Mg(HSiO3)+ 0.32191E-11 -11.4923 0.26935E-11 -11.5697 0.83673E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66215E-16 -16.1790 0.55404E-16 -16.2565 0.83673E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53101E-05 -5.2749 0.44266E-05 -5.3539 0.83361E+00 -0.0790 24 CH4,aq 0.17499E-04 -4.7570 0.17439E-04 -4.7585 0.99653E+00 -0.0015 25 C2H6,aq 0.45039E-14 -14.3464 0.44883E-14 -14.3479 0.99653E+00 -0.0015 29 CO,aq 0.13073E-16 -16.8836 0.13073E-16 -16.8836 0.10000E+01 0.0000 30 CO2,aq 0.45086E-10 -10.3460 0.44929E-10 -10.3475 0.99653E+00 -0.0015 31 CO3-2 0.64258E-06 -6.1921 0.33287E-06 -6.4777 0.51802E+00 -0.2857 32 CaCO3,aq 0.29115E-09 -9.5359 0.29115E-09 -9.5359 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60239E-12 -12.2201 0.50404E-12 -12.2975 0.83673E+00 -0.0774 34 CaCl+ 0.21880E-10 -10.6599 0.18308E-10 -10.7374 0.83673E+00 -0.0774 35 CaCl2,aq 0.70541E-15 -15.1516 0.70541E-15 -15.1516 0.10000E+01 0.0000 36 CaOH+ 0.79988E-07 -7.0970 0.66928E-07 -7.1744 0.83673E+00 -0.0774 37 CaSO4,aq 0.10518E-16 -16.9780 0.10518E-16 -16.9780 0.10000E+01 0.0000 38 HCl,aq 0.22075E-14 -14.6561 0.22075E-14 -14.6561 0.10000E+01 0.0000 43 FeCl+ 0.91954E-17 -17.0364 0.76940E-17 -17.1138 0.83673E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15698E-10 -10.8042 0.13135E-10 -10.8816 0.83673E+00 -0.0774 48 HFeO2- 0.35611E-07 -7.4484 0.29739E-07 -7.5267 0.83512E+00 -0.0782 49 FeO+ 0.11001E-16 -16.9586 0.92051E-17 -17.0360 0.83673E+00 -0.0774 51 FeO2- 0.40878E-09 -9.3885 0.34138E-09 -9.4668 0.83512E+00 -0.0782 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.38536E-09 -9.4141 0.38536E-09 -9.4141 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.11568E-14 -14.9367 0.96606E-15 -15.0150 0.83512E+00 -0.0782 58 MgCO3,aq 0.11365E-13 -13.9444 0.11365E-13 -13.9444 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.95856E-16 -16.0184 0.80205E-16 -16.0958 0.83673E+00 -0.0774 60 MgCl+ 0.30882E-14 -14.5103 0.25840E-14 -14.5877 0.83673E+00 -0.0774 61 MgOH+ 0.68927E-10 -10.1616 0.57673E-10 -10.2390 0.83673E+00 -0.0774 63 MnO,aq 0.18039E-08 -8.7438 0.18039E-08 -8.7438 0.10000E+01 0.0000 64 MnOH+ 0.46759E-09 -9.3301 0.39124E-09 -9.4076 0.83673E+00 -0.0774 65 MnO2-2 0.20945E-10 -10.6789 0.10850E-10 -10.9646 0.51802E+00 -0.2857 66 HMnO2- 0.21143E-09 -9.6748 0.17657E-09 -9.7531 0.83512E+00 -0.0782 69 MnCl+ 0.11471E-13 -13.9404 0.95981E-14 -14.0178 0.83673E+00 -0.0774 71 NaCl,aq 0.89247E-06 -6.0494 0.89247E-06 -6.0494 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93308E-02 -2.0301 0.77783E-02 -2.1091 0.83361E+00 -0.0790 79 HPO3-2 0.16361E-14 -14.7862 0.84755E-15 -15.0718 0.51802E+00 -0.2857 81 H2PO3- 0.15117E-18 -18.8205 0.12625E-18 -18.8988 0.83512E+00 -0.0782 82 H3PO4,aq 0.90608E-18 -18.0428 0.90608E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38490E-10 -10.4147 0.32174E-10 -10.4925 0.83592E+00 -0.0778 84 PO4-3 0.10637E-08 -8.9732 0.25791E-09 -9.5885 0.24247E+00 -0.6153 88 HP2O7-3 0.94423E-18 -18.0249 0.21819E-18 -18.6612 0.23108E+00 -0.6362 89 P2O7-4 0.91134E-17 -17.0403 0.70174E-18 -18.1538 0.77001E-01 -1.1135 90 H2S,aq 0.69376E-08 -8.1588 0.69136E-08 -8.1603 0.99653E+00 -0.0015 91 S2-2 0.33492E-14 -14.4751 0.17349E-14 -14.7607 0.51802E+00 -0.2857 97 SO3-2 0.13601E-17 -17.8664 0.71476E-18 -18.1458 0.52552E+00 -0.2794 99 HSO4- 0.40587E-19 -19.3916 0.33993E-19 -19.4686 0.83754E+00 -0.0770 Charge balance for all species = 0.7384E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8840933E-10 -.2227821E-01 -.2241605E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981983E+06 0.0000 3 Cl- 0.1941980E-03 0.1950908E-03 0.6904527E+01 6.3391 4 SO4-- 0.9147324E-12 -.2040492E-04 -.1956721E+01 7.9348 5 HCO3- 0.3384662E-06 0.1848054E-04 0.1125670E+01 3.5810 6 HS- 0.3605552E-04 0.5646738E-04 0.1864242E+01 5.6079 7 Al+++ 0.9733682E-29 0.5310246E-05 0.1430292E+00 0.7390 8 H4SiO4 0.6959687E-03 0.1352156E-01 0.1297370E+04 -3.1574 9 Ca++ 0.1353653E-06 0.2322776E-06 0.9293032E-02 13.1018 10 Mg++ 0.2117706E-10 0.9333824E-10 0.2265293E-05 9.2942 11 Fe++ 0.5836704E-13 0.3624973E-07 0.2020918E-02 6.7350 12 K+ 0.1567202E-03 0.1574743E-03 0.6146853E+01 6.2467 13 Na+ 0.1988704E-01 0.2233358E-01 0.5125517E+03 8.3494 14 Mn++ 0.1870000E-10 0.2522547E-08 0.1383427E-03 9.2410 15 HPO4-- 0.4522374E-07 0.4632590E-07 0.4438581E-02 12.6290 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4801967E+02 -.1575583E-01 -.4800391E+02 0.0000000E+00 2 H2O 0.1915557E+02 0.3925475E+02 -.2009917E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8039436E-01 -.1443098E-04 0.8040879E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8036886E-01 0.3993545E-04 -.8040879E-01 0.0000000E+00 7 Al+++ 0.9456147E+01 0.3755568E-05 0.9456144E+01 0.0000000E+00 8 H4SiO4 0.3019706E+02 0.9562856E-02 0.3018750E+02 0.0000000E+00 9 Ca++ 0.3335427E+01 0.1642738E-06 0.3335427E+01 0.0000000E+00 10 Mg++ 0.2301587E+01 0.6601164E-10 0.2301587E+01 0.0000000E+00 11 Fe++ 0.2067724E+01 0.2563691E-07 0.2067724E+01 0.0000000E+00 12 K+ 0.6157110E+00 0.1113706E-03 0.6155997E+00 0.0000000E+00 13 Na+ 0.3640365E+01 0.1579499E-01 0.3624570E+01 0.0000000E+00 14 Mn++ 0.5028191E-01 0.1784022E-08 0.5028191E-01 0.0000000E+00 15 HPO4-- 0.1716097E-01 0.3276308E-07 0.1716093E-01 0.0000000E+00 Chg. balance for solid moles: -.5135E-15 Mass of aqueous solution: 0.708463E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.621 0.559 949.6 2.978 29.97 364.5 andradite 0.3216 -0.493 163.4 2.213 5.159 42.47 grossular 0.7789E-01 -1.109 35.08 1.545 1.107 9.762 apatite-OH 0.5720E-02 -2.243 2.873 0.458 0.9070E-01 0.9131 clinochlore 0.4125 -0.385 229.3 2.360 7.238 87.22 daphnite 0.1194 -0.923 85.21 1.930 2.690 25.82 chlorite-Mn 0.1006E-01 -1.998 7.130 0.853 0.2250 2.272 diopside 0.1485 -0.828 32.15 1.507 1.015 9.827 hedenbergite 0.3850E-01 -1.414 9.553 0.980 0.3015 2.616 microcline 0.5398 -0.268 150.3 2.177 4.743 58.69 stilbite 1.871 0.272 1319. 3.120 41.63 615.1 stilpnomelane-Fe 0.1515 -0.820 163.3 2.213 5.156 56.42 tr.625ac.25prg.125 0.2497E-01 -1.603 21.35 1.329 0.6738 6.870 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3168.073904 g Volume = 1282.513511 cm3 Porosity: -10.4663% V(tot) - V(min): -.12151E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2899.9990000 g log = 3.4624 Original solution: 1000.0103000 g Original solution / Rock added: 0.34 (Water/Rock Ratio), log = -0.4624 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0614 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9618E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4498E-08 1.0068 0.4807E-08 0.4774E-08 CH4,gas 0.2389E-01 1.0124 0.2567E-01 0.2535E-01 H2,gas 0.1432E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1798E-06 0.9959 0.1900E-06 0.1908E-06 S2,gas 0.5523E-29 1.0000 0.5863E-29 0.5863E-29 CO,gas 0.1835E-13 1.0000 0.1948E-13 0.1948E-13 SO3,gas 0.9333E-48 1.0000 0.9907E-48 0.9907E-48 SO2,gas 0.5522E-27 1.0000 0.5861E-27 0.5861E-27 HCl,gas 0.3670E-17 1.0000 0.3895E-17 0.3895E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.66728E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.68 -10.02 -3.339 0.17104E+05 -8.318 3 CH4,gas 4.54 1.25 -3.29 -0.822 0.56169E+04 -1.591 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.65 -8.42 -4.210 0.14377E+05 -6.721 6 S2,gas -7.34 -38.27 -30.93 -4.759 0.52814E+05 -29.232 7 CO,gas 3.21 -12.19 -15.41 -4.741 0.26311E+05 -13.710 8 SO3,gas 17.12 -32.58 -49.70 -12.426 0.84867E+05 -48.004 9 SO2,gas 0.83 -28.10 -28.93 -7.715 0.49399E+05 -27.232 10 HCl,gas 5.19 -13.92 -19.11 -9.554 0.32627E+05 -17.409 11 acmite 7.71 6.53 -1.18 -0.123 0.20176E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80739E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.58 -4.54 -1.514 0.77552E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.58 -4.39 -1.462 0.74910E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65558E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.71 -4.61 -1.317 0.78700E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85225E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.71 -4.17 -1.190 0.71123E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82251E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.92 -3.66 -1.218 0.62409E+04 144 pyrrhotiteFe0.875 -6.02 -9.31 -3.30 -1.212 0.56281E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22455E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23257E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47146E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.92 -3.50 -1.168 0.59837E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79434E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.41 -4.43 -1.477 0.75666E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2899.9990000 g New total amount of reactant added: 2999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 2999.9990000 Water: Moles liquid = 0.3870E+02 kg liquid = 0.6972E+00 Moles total = 0.1790E+02 kg total = 0.3225E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136729E-01 Osmotic coef. = 0.9689 True ionic strength = .2004677E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88417E-10 -10.0535 0.74286E-10 -10.1291 0.84018E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19700E-03 -3.7055 0.16451E-03 -3.7838 0.83512E+00 -0.0783 4 SO4-- 0.92786E-12 -12.0325 0.48166E-12 -12.3173 0.51911E+00 -0.2847 5 HCO3- 0.34332E-06 -6.4643 0.28713E-06 -6.5419 0.83634E+00 -0.0776 6 HS- 0.36575E-04 -4.4368 0.30549E-04 -4.5150 0.83524E+00 -0.0782 7 Al+++ 0.97366E-29 -29.0116 0.22476E-29 -29.6483 0.23084E+00 -0.6367 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13539E-06 -6.8684 0.69767E-07 -7.1563 0.51530E+00 -0.2879 10 Mg++ 0.21181E-10 -10.6741 0.10865E-10 -10.9640 0.51294E+00 -0.2899 11 Fe++ 0.58378E-13 -13.2337 0.29977E-13 -13.5232 0.51350E+00 -0.2895 12 K+ 0.15673E-03 -3.8048 0.13111E-03 -3.8823 0.83654E+00 -0.0775 13 Na+ 0.19889E-01 -1.7014 0.16607E-01 -1.7797 0.83497E+00 -0.0783 14 Mn++ 0.18706E-10 -10.7280 0.96133E-11 -11.0171 0.51393E+00 -0.2891 15 HPO4-- 0.45217E-07 -7.3447 0.23476E-07 -7.6294 0.51919E+00 -0.2847 16 HSiO3- 0.10475E-01 -1.9798 0.87480E-02 -2.0581 0.83512E+00 -0.0783 17 Ca(HSiO3)+ 0.16612E-07 -7.7796 0.13899E-07 -7.8570 0.83672E+00 -0.0774 18 Mg(HSiO3)+ 0.32194E-11 -11.4922 0.26938E-11 -11.5696 0.83672E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66221E-16 -16.1790 0.55408E-16 -16.2564 0.83672E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53097E-05 -5.2749 0.44262E-05 -5.3540 0.83361E+00 -0.0790 24 CH4,aq 0.17751E-04 -4.7508 0.17690E-04 -4.7523 0.99653E+00 -0.0015 25 C2H6,aq 0.46347E-14 -14.3340 0.46186E-14 -14.3355 0.99653E+00 -0.0015 29 CO,aq 0.13262E-16 -16.8774 0.13262E-16 -16.8774 0.10000E+01 0.0000 30 CO2,aq 0.45736E-10 -10.3397 0.45577E-10 -10.3413 0.99653E+00 -0.0015 31 CO3-2 0.65175E-06 -6.1859 0.33761E-06 -6.4716 0.51801E+00 -0.2857 32 CaCO3,aq 0.29534E-09 -9.5297 0.29534E-09 -9.5297 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61113E-12 -12.2139 0.51135E-12 -12.2913 0.83672E+00 -0.0774 34 CaCl+ 0.22199E-10 -10.6537 0.18575E-10 -10.7311 0.83672E+00 -0.0774 35 CaCl2,aq 0.72599E-15 -15.1391 0.72599E-15 -15.1391 0.10000E+01 0.0000 36 CaOH+ 0.79996E-07 -7.0969 0.66934E-07 -7.1744 0.83672E+00 -0.0774 37 CaSO4,aq 0.10671E-16 -16.9718 0.10671E-16 -16.9718 0.10000E+01 0.0000 38 HCl,aq 0.22395E-14 -14.6499 0.22395E-14 -14.6499 0.10000E+01 0.0000 43 FeCl+ 0.93294E-17 -17.0301 0.78061E-17 -17.1076 0.83672E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15699E-10 -10.8041 0.13136E-10 -10.8815 0.83672E+00 -0.0774 48 HFeO2- 0.35608E-07 -7.4485 0.29737E-07 -7.5267 0.83512E+00 -0.0783 49 FeO+ 0.11002E-16 -16.9585 0.92059E-17 -17.0359 0.83672E+00 -0.0774 51 FeO2- 0.40874E-09 -9.3885 0.34135E-09 -9.4668 0.83512E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.39094E-09 -9.4079 0.39094E-09 -9.4079 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.11735E-14 -14.9305 0.97999E-15 -15.0088 0.83512E+00 -0.0783 58 MgCO3,aq 0.11529E-13 -13.9382 0.11529E-13 -13.9382 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.97247E-16 -16.0121 0.81368E-16 -16.0895 0.83672E+00 -0.0774 60 MgCl+ 0.31332E-14 -14.5040 0.26217E-14 -14.5814 0.83672E+00 -0.0774 61 MgOH+ 0.68934E-10 -10.1616 0.57678E-10 -10.2390 0.83672E+00 -0.0774 63 MnO,aq 0.18041E-08 -8.7438 0.18041E-08 -8.7438 0.10000E+01 0.0000 64 MnOH+ 0.46768E-09 -9.3301 0.39132E-09 -9.4075 0.83672E+00 -0.0774 65 MnO2-2 0.20944E-10 -10.6789 0.10849E-10 -10.9646 0.51801E+00 -0.2857 66 HMnO2- 0.21143E-09 -9.6748 0.17657E-09 -9.7531 0.83512E+00 -0.0783 69 MnCl+ 0.11639E-13 -13.9341 0.97389E-14 -14.0115 0.83672E+00 -0.0774 71 NaCl,aq 0.90540E-06 -6.0432 0.90540E-06 -6.0432 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93301E-02 -2.0301 0.77777E-02 -2.1092 0.83361E+00 -0.0790 79 HPO3-2 0.16359E-14 -14.7862 0.84741E-15 -15.0719 0.51801E+00 -0.2857 81 H2PO3- 0.15116E-18 -18.8206 0.12624E-18 -18.8988 0.83512E+00 -0.0783 82 H3PO4,aq 0.90608E-18 -18.0428 0.90608E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38487E-10 -10.4147 0.32171E-10 -10.4925 0.83591E+00 -0.0778 84 PO4-3 0.10635E-08 -8.9733 0.25784E-09 -9.5886 0.24246E+00 -0.6154 88 HP2O7-3 0.94405E-18 -18.0250 0.21814E-18 -18.6613 0.23107E+00 -0.6363 89 P2O7-4 0.91112E-17 -17.0404 0.70151E-18 -18.1540 0.76994E-01 -1.1135 90 H2S,aq 0.70381E-08 -8.1525 0.70137E-08 -8.1541 0.99653E+00 -0.0015 91 S2-2 0.34464E-14 -14.4626 0.17853E-14 -14.7483 0.51801E+00 -0.2857 97 SO3-2 0.13796E-17 -17.8602 0.72500E-18 -18.1397 0.52551E+00 -0.2794 99 HSO4- 0.41172E-19 -19.3854 0.34483E-19 -19.4624 0.83754E+00 -0.0770 Charge balance for all species = 0.7486E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8841727E-10 -.2227669E-01 -.2241451E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981982E+06 0.0000 3 Cl- 0.1969952E-03 0.1979010E-03 0.7003983E+01 6.3453 4 SO4-- 0.9278576E-12 -.2065709E-04 -.1980902E+01 7.9409 5 HCO3- 0.3433205E-06 0.1874674E-04 0.1141884E+01 3.5872 6 HS- 0.3657488E-04 0.5723901E-04 0.1889716E+01 5.6141 7 Al+++ 0.9736630E-29 0.5309813E-05 0.1430176E+00 0.7390 8 H4SiO4 0.6959695E-03 0.1352076E-01 0.1297293E+04 -3.1574 9 Ca++ 0.1353912E-06 0.2323166E-06 0.9294591E-02 13.1018 10 Mg++ 0.2118111E-10 0.9334891E-10 0.2265551E-05 9.2942 11 Fe++ 0.5837826E-13 0.3624690E-07 0.2020760E-02 6.7350 12 K+ 0.1567343E-03 0.1574885E-03 0.6147404E+01 6.2467 13 Na+ 0.1988883E-01 0.2233539E-01 0.5125932E+03 8.3494 14 Mn++ 0.1870550E-10 0.2522830E-08 0.1383582E-03 9.2411 15 HPO4-- 0.4521730E-07 0.4631924E-07 0.4437942E-02 12.6288 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4967552E+02 -.1553104E-01 -.4965999E+02 0.0000000E+00 2 H2O 0.1790203E+02 0.3869733E+02 -.2079530E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8316570E-01 -.1440187E-04 0.8318011E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8314020E-01 0.3990634E-04 -.8318011E-01 0.0000000E+00 7 Al+++ 0.9782222E+01 0.3701937E-05 0.9782218E+01 0.0000000E+00 8 H4SiO4 0.3123834E+02 0.9426506E-02 0.3122891E+02 0.0000000E+00 9 Ca++ 0.3450441E+01 0.1619683E-06 0.3450441E+01 0.0000000E+00 10 Mg++ 0.2380952E+01 0.6508172E-10 0.2380952E+01 0.0000000E+00 11 Fe++ 0.2139025E+01 0.2527090E-07 0.2139025E+01 0.0000000E+00 12 K+ 0.6369425E+00 0.1097990E-03 0.6368327E+00 0.0000000E+00 13 Na+ 0.3765890E+01 0.1557196E-01 0.3750318E+01 0.0000000E+00 14 Mn++ 0.5201577E-01 0.1758886E-08 0.5201577E-01 0.0000000E+00 15 HPO4-- 0.1775272E-01 0.3229321E-07 0.1775269E-01 0.0000000E+00 Chg. balance for solid moles: 0.4337E-14 Mass of aqueous solution: 0.698402E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 2999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.747 0.574 982.6 2.992 29.98 377.2 andradite 0.3327 -0.478 169.1 2.228 5.159 43.93 grossular 0.8057E-01 -1.094 36.29 1.560 1.107 10.10 apatite-OH 0.5918E-02 -2.228 2.973 0.473 0.9070E-01 0.9446 clinochlore 0.4267 -0.370 237.2 2.375 7.237 90.21 daphnite 0.1235 -0.908 88.14 1.945 2.689 26.71 chlorite-Mn 0.1040E-01 -1.983 7.376 0.868 0.2250 2.350 diopside 0.1539 -0.813 33.33 1.523 1.017 10.19 hedenbergite 0.3991E-01 -1.399 9.903 0.996 0.3022 2.712 microcline 0.5585 -0.253 155.4 2.192 4.743 60.72 stilbite 1.936 0.287 1364. 3.135 41.62 636.2 stilpnomelane-Fe 0.1568 -0.805 169.0 2.228 5.156 58.37 tr.625ac.25prg.125 0.2581E-01 -1.588 22.06 1.344 0.6731 7.100 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.732 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3277.324569 g Volume = 1326.716575 cm3 Porosity: -10.4677% V(tot) - V(min): -.12572E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2999.9990000 g log = 3.4771 Original solution: 1000.0103000 g Original solution / Rock added: 0.33 (Water/Rock Ratio), log = -0.4771 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0618 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9615E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4561E-08 1.0068 0.4876E-08 0.4843E-08 CH4,gas 0.2422E-01 1.0124 0.2604E-01 0.2572E-01 H2,gas 0.1431E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1823E-06 0.9959 0.1928E-06 0.1936E-06 S2,gas 0.5683E-29 1.0000 0.6034E-29 0.6034E-29 CO,gas 0.1861E-13 1.0000 0.1976E-13 0.1976E-13 SO3,gas 0.9465E-48 1.0000 0.1005E-47 0.1005E-47 SO2,gas 0.5600E-27 1.0000 0.5946E-27 0.5946E-27 HCl,gas 0.3722E-17 1.0000 0.3952E-17 0.3952E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.67 -10.01 -3.337 0.17093E+05 -8.312 3 CH4,gas 4.54 1.26 -3.28 -0.821 0.56062E+04 -1.584 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.64 -8.41 -4.207 0.14366E+05 -6.715 6 S2,gas -7.34 -38.25 -30.92 -4.757 0.52792E+05 -29.219 7 CO,gas 3.21 -12.19 -15.40 -4.739 0.26300E+05 -13.704 8 SO3,gas 17.12 -32.58 -49.70 -12.424 0.84856E+05 -47.998 9 SO2,gas 0.83 -28.09 -28.92 -7.713 0.49388E+05 -27.226 10 HCl,gas 5.19 -13.91 -19.10 -9.551 0.32616E+05 -17.403 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80736E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.57 -4.54 -1.512 0.77446E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.57 -4.38 -1.460 0.74804E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65557E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.71 -4.60 -1.315 0.78594E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.71 -4.16 -1.188 0.71017E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82250E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.91 -3.65 -1.216 0.62302E+04 144 pyrrhotiteFe0.875 -6.02 -9.31 -3.29 -1.210 0.56174E+04 145 pyroxmangite 7.40 6.08 -1.32 -0.263 0.22454E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23256E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47145E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.91 -3.50 -1.166 0.59730E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79435E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66554E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.40 -4.43 -1.475 0.75559E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2999.9990000 g New total amount of reactant added: 3099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3099.9990000 Water: Moles liquid = 0.3814E+02 kg liquid = 0.6871E+00 Moles total = 0.1665E+02 kg total = 0.2999E+00 Activity = 1.0000 Stoichiometric ionic strength = .1136968E-01 Osmotic coef. = 0.9689 True ionic strength = .2004864E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88425E-10 -10.0534 0.74293E-10 -10.1291 0.84017E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19987E-03 -3.6992 0.16692E-03 -3.7775 0.83511E+00 -0.0783 4 SO4-- 0.94136E-12 -12.0262 0.48866E-12 -12.3110 0.51910E+00 -0.2847 5 HCO3- 0.34832E-06 -6.4580 0.29131E-06 -6.5356 0.83634E+00 -0.0776 6 HS- 0.37109E-04 -4.4305 0.30995E-04 -4.5087 0.83524E+00 -0.0782 7 Al+++ 0.97397E-29 -29.0115 0.22481E-29 -29.6482 0.23082E+00 -0.6367 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13542E-06 -6.8683 0.69779E-07 -7.1563 0.51529E+00 -0.2880 10 Mg++ 0.21185E-10 -10.6740 0.10867E-10 -10.9639 0.51293E+00 -0.2899 11 Fe++ 0.58390E-13 -13.2337 0.29983E-13 -13.5231 0.51349E+00 -0.2895 12 K+ 0.15675E-03 -3.8048 0.13113E-03 -3.8823 0.83654E+00 -0.0775 13 Na+ 0.19891E-01 -1.7014 0.16608E-01 -1.7797 0.83496E+00 -0.0783 14 Mn++ 0.18711E-10 -10.7279 0.96159E-11 -11.0170 0.51392E+00 -0.2891 15 HPO4-- 0.45211E-07 -7.3448 0.23472E-07 -7.6294 0.51918E+00 -0.2847 16 HSiO3- 0.10474E-01 -1.9799 0.87473E-02 -2.0581 0.83511E+00 -0.0783 17 Ca(HSiO3)+ 0.16613E-07 -7.7795 0.13901E-07 -7.8570 0.83672E+00 -0.0774 18 Mg(HSiO3)+ 0.32197E-11 -11.4922 0.26940E-11 -11.5696 0.83672E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66226E-16 -16.1790 0.55413E-16 -16.2564 0.83672E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53092E-05 -5.2750 0.44258E-05 -5.3540 0.83360E+00 -0.0790 24 CH4,aq 0.18011E-04 -4.7445 0.17948E-04 -4.7460 0.99653E+00 -0.0015 25 C2H6,aq 0.47712E-14 -14.3214 0.47547E-14 -14.3229 0.99653E+00 -0.0015 29 CO,aq 0.13456E-16 -16.8711 0.13456E-16 -16.8711 0.10000E+01 0.0000 30 CO2,aq 0.46405E-10 -10.3334 0.46244E-10 -10.3349 0.99653E+00 -0.0015 31 CO3-2 0.66119E-06 -6.1797 0.34249E-06 -6.4653 0.51800E+00 -0.2857 32 CaCO3,aq 0.29967E-09 -9.5234 0.29967E-09 -9.5234 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62013E-12 -12.2075 0.51887E-12 -12.2849 0.83672E+00 -0.0774 34 CaCl+ 0.22527E-10 -10.6473 0.18849E-10 -10.7247 0.83672E+00 -0.0774 35 CaCl2,aq 0.74748E-15 -15.1264 0.74748E-15 -15.1264 0.10000E+01 0.0000 36 CaOH+ 0.80003E-07 -7.0969 0.66940E-07 -7.1743 0.83672E+00 -0.0774 37 CaSO4,aq 0.10828E-16 -16.9655 0.10828E-16 -16.9655 0.10000E+01 0.0000 38 HCl,aq 0.22724E-14 -14.6435 0.22724E-14 -14.6435 0.10000E+01 0.0000 43 FeCl+ 0.94674E-17 -17.0238 0.79215E-17 -17.1012 0.83672E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15700E-10 -10.8041 0.13137E-10 -10.8815 0.83672E+00 -0.0774 48 HFeO2- 0.35605E-07 -7.4485 0.29734E-07 -7.5267 0.83511E+00 -0.0783 49 FeO+ 0.11003E-16 -16.9585 0.92067E-17 -17.0359 0.83672E+00 -0.0774 51 FeO2- 0.40871E-09 -9.3886 0.34132E-09 -9.4668 0.83511E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.39669E-09 -9.4015 0.39669E-09 -9.4015 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.11906E-14 -14.9242 0.99431E-15 -15.0025 0.83511E+00 -0.0783 58 MgCO3,aq 0.11697E-13 -13.9319 0.11697E-13 -13.9319 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.98678E-16 -16.0058 0.82566E-16 -16.0832 0.83672E+00 -0.0774 60 MgCl+ 0.31796E-14 -14.4976 0.26604E-14 -14.5751 0.83672E+00 -0.0774 61 MgOH+ 0.68940E-10 -10.1615 0.57683E-10 -10.2390 0.83672E+00 -0.0774 63 MnO,aq 0.18042E-08 -8.7437 0.18042E-08 -8.7437 0.10000E+01 0.0000 64 MnOH+ 0.46777E-09 -9.3300 0.39139E-09 -9.4074 0.83672E+00 -0.0774 65 MnO2-2 0.20943E-10 -10.6790 0.10849E-10 -10.9646 0.51800E+00 -0.2857 66 HMnO2- 0.21144E-09 -9.6748 0.17657E-09 -9.7531 0.83511E+00 -0.0783 69 MnCl+ 0.11813E-13 -13.9277 0.98839E-14 -14.0051 0.83672E+00 -0.0774 71 NaCl,aq 0.91870E-06 -6.0368 0.91870E-06 -6.0368 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93294E-02 -2.0301 0.77770E-02 -2.1092 0.83360E+00 -0.0790 79 HPO3-2 0.16356E-14 -14.7863 0.84726E-15 -15.0720 0.51800E+00 -0.2857 81 H2PO3- 0.15115E-18 -18.8206 0.12622E-18 -18.8989 0.83511E+00 -0.0783 82 H3PO4,aq 0.90608E-18 -18.0428 0.90608E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38484E-10 -10.4147 0.32169E-10 -10.4926 0.83591E+00 -0.0778 84 PO4-3 0.10632E-08 -8.9734 0.25778E-09 -9.5888 0.24245E+00 -0.6154 88 HP2O7-3 0.94386E-18 -18.0251 0.21808E-18 -18.6614 0.23105E+00 -0.6363 89 P2O7-4 0.91090E-17 -17.0405 0.70127E-18 -18.1541 0.76987E-01 -1.1136 90 H2S,aq 0.71416E-08 -8.1462 0.71168E-08 -8.1477 0.99653E+00 -0.0015 91 S2-2 0.35479E-14 -14.4500 0.18378E-14 -14.7357 0.51800E+00 -0.2857 97 SO3-2 0.13997E-17 -17.8540 0.73553E-18 -18.1334 0.52550E+00 -0.2794 99 HSO4- 0.41774E-19 -19.3791 0.34987E-19 -19.4561 0.83753E+00 -0.0770 Charge balance for all species = 0.7599E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8842544E-10 -.2227512E-01 -.2241294E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981981E+06 0.0000 3 Cl- 0.1998742E-03 0.2007934E-03 0.7106345E+01 6.3516 4 SO4-- 0.9413639E-12 -.2091663E-04 -.2005790E+01 7.9471 5 HCO3- 0.3483158E-06 0.1902073E-04 0.1158573E+01 3.5934 6 HS- 0.3710943E-04 0.5803320E-04 0.1915936E+01 5.6203 7 Al+++ 0.9739669E-29 0.5309370E-05 0.1430056E+00 0.7390 8 H4SiO4 0.6959703E-03 0.1351993E-01 0.1297213E+04 -3.1574 9 Ca++ 0.1354178E-06 0.2323568E-06 0.9296198E-02 13.1018 10 Mg++ 0.2118528E-10 0.9335989E-10 0.2265818E-05 9.2942 11 Fe++ 0.5838981E-13 0.3624400E-07 0.2020598E-02 6.7350 12 K+ 0.1567488E-03 0.1575030E-03 0.6147970E+01 6.2467 13 Na+ 0.1989068E-01 0.2233726E-01 0.5126358E+03 8.3494 14 Mn++ 0.1871099E-10 0.2523097E-08 0.1383728E-03 9.2411 15 HPO4-- 0.4521066E-07 0.4631238E-07 0.4437285E-02 12.6287 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5133137E+02 -.1530624E-01 -.5131606E+02 0.0000000E+00 2 H2O 0.1664849E+02 0.3813992E+02 -.2149143E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8593704E-01 -.1437276E-04 0.8595142E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8591154E-01 0.3987723E-04 -.8595142E-01 0.0000000E+00 7 Al+++ 0.1010830E+02 0.3648308E-05 0.1010829E+02 0.0000000E+00 8 H4SiO4 0.3227962E+02 0.9290154E-02 0.3227033E+02 0.0000000E+00 9 Ca++ 0.3565456E+01 0.1596628E-06 0.3565455E+01 0.0000000E+00 10 Mg++ 0.2460317E+01 0.6415179E-10 0.2460317E+01 0.0000000E+00 11 Fe++ 0.2210326E+01 0.2490489E-07 0.2210326E+01 0.0000000E+00 12 K+ 0.6581739E+00 0.1082274E-03 0.6580657E+00 0.0000000E+00 13 Na+ 0.3891414E+01 0.1534894E-01 0.3876065E+01 0.0000000E+00 14 Mn++ 0.5374963E-01 0.1733734E-08 0.5374963E-01 0.0000000E+00 15 HPO4-- 0.1834448E-01 0.3182333E-07 0.1834445E-01 0.0000000E+00 Chg. balance for solid moles: 0.2269E-14 Mass of aqueous solution: 0.688342E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.873 0.588 1016. 3.007 29.99 389.8 andradite 0.3438 -0.464 174.7 2.242 5.159 45.39 grossular 0.8325E-01 -1.080 37.50 1.574 1.107 10.43 apatite-OH 0.6115E-02 -2.214 3.072 0.487 0.9070E-01 0.9760 clinochlore 0.4409 -0.356 245.1 2.389 7.236 93.21 daphnite 0.1276 -0.894 91.07 1.959 2.689 27.60 chlorite-Mn 0.1075E-01 -1.969 7.621 0.882 0.2250 2.429 diopside 0.1594 -0.798 34.51 1.538 1.019 10.55 hedenbergite 0.4133E-01 -1.384 10.25 1.011 0.3027 2.808 microcline 0.5771 -0.239 160.6 2.206 4.743 62.74 stilbite 2.000 0.301 1409. 3.149 41.61 657.3 stilpnomelane-Fe 0.1620 -0.791 174.6 2.242 5.156 60.32 tr.625ac.25prg.125 0.2664E-01 -1.574 22.77 1.357 0.6724 7.329 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3386.575233 g Volume = 1370.919639 cm3 Porosity: -10.4690% V(tot) - V(min): -.12992E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3099.9990000 g log = 3.4914 Original solution: 1000.0103000 g Original solution / Rock added: 0.32 (Water/Rock Ratio), log = -0.4914 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0622 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9611E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4626E-08 1.0068 0.4948E-08 0.4914E-08 CH4,gas 0.2457E-01 1.0124 0.2642E-01 0.2610E-01 H2,gas 0.1431E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1849E-06 0.9959 0.1956E-06 0.1964E-06 S2,gas 0.5849E-29 1.0000 0.6212E-29 0.6212E-29 CO,gas 0.1888E-13 1.0000 0.2005E-13 0.2005E-13 SO3,gas 0.9601E-48 1.0000 0.1020E-47 0.1020E-47 SO2,gas 0.5680E-27 1.0000 0.6033E-27 0.6033E-27 HCl,gas 0.3775E-17 1.0000 0.4010E-17 0.4010E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.66 -10.00 -3.335 0.17083E+05 -8.306 3 CH4,gas 4.54 1.27 -3.28 -0.819 0.55955E+04 -1.578 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.64 -8.41 -4.204 0.14356E+05 -6.709 6 S2,gas -7.34 -38.24 -30.91 -4.755 0.52771E+05 -29.207 7 CO,gas 3.21 -12.18 -15.40 -4.737 0.26290E+05 -13.698 8 SO3,gas 17.12 -32.57 -49.69 -12.423 0.84845E+05 -47.991 9 SO2,gas 0.83 -28.09 -28.92 -7.712 0.49377E+05 -27.219 10 HCl,gas 5.19 -13.91 -19.10 -9.548 0.32606E+05 -17.397 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80734E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.56 -4.53 -1.510 0.77338E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.56 -4.37 -1.458 0.74696E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65557E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.70 -4.60 -1.313 0.78486E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.70 -4.15 -1.187 0.70909E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82249E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61314E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53705E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.26 -7.90 -3.64 -1.214 0.62194E+04 144 pyrrhotiteFe0.875 -6.02 -9.30 -3.28 -1.208 0.56066E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22453E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23256E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47143E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.90 -3.49 -1.164 0.59622E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79435E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.40 -4.42 -1.473 0.75450E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3099.9990000 g New total amount of reactant added: 3199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3199.9990000 Water: Moles liquid = 0.3758E+02 kg liquid = 0.6771E+00 Moles total = 0.1539E+02 kg total = 0.2773E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137215E-01 Osmotic coef. = 0.9689 True ionic strength = .2005057E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88434E-10 -10.0534 0.74299E-10 -10.1290 0.84017E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20284E-03 -3.6928 0.16939E-03 -3.7711 0.83511E+00 -0.0783 4 SO4-- 0.95527E-12 -12.0199 0.49587E-12 -12.3046 0.51909E+00 -0.2848 5 HCO3- 0.35346E-06 -6.4517 0.29561E-06 -6.5293 0.83633E+00 -0.0776 6 HS- 0.37660E-04 -4.4241 0.31455E-04 -4.5023 0.83523E+00 -0.0782 7 Al+++ 0.97428E-29 -29.0113 0.22487E-29 -29.6481 0.23081E+00 -0.6367 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13545E-06 -6.8682 0.69791E-07 -7.1562 0.51527E+00 -0.2880 10 Mg++ 0.21190E-10 -10.6739 0.10868E-10 -10.9638 0.51291E+00 -0.2900 11 Fe++ 0.58402E-13 -13.2336 0.29988E-13 -13.5231 0.51348E+00 -0.2895 12 K+ 0.15676E-03 -3.8048 0.13114E-03 -3.8823 0.83653E+00 -0.0775 13 Na+ 0.19893E-01 -1.7013 0.16609E-01 -1.7796 0.83496E+00 -0.0783 14 Mn++ 0.18716E-10 -10.7278 0.96184E-11 -11.0169 0.51390E+00 -0.2891 15 HPO4-- 0.45204E-07 -7.3448 0.23468E-07 -7.6295 0.51916E+00 -0.2847 16 HSiO3- 0.10473E-01 -1.9799 0.87465E-02 -2.0582 0.83511E+00 -0.0783 17 Ca(HSiO3)+ 0.16615E-07 -7.7795 0.13902E-07 -7.8569 0.83671E+00 -0.0774 18 Mg(HSiO3)+ 0.32200E-11 -11.4921 0.26942E-11 -11.5696 0.83671E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66233E-16 -16.1789 0.55417E-16 -16.2564 0.83671E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53088E-05 -5.2750 0.44254E-05 -5.3540 0.83360E+00 -0.0790 24 CH4,aq 0.18278E-04 -4.7381 0.18215E-04 -4.7396 0.99653E+00 -0.0015 25 C2H6,aq 0.49138E-14 -14.3086 0.48968E-14 -14.3101 0.99653E+00 -0.0015 29 CO,aq 0.13655E-16 -16.8647 0.13655E-16 -16.8647 0.10000E+01 0.0000 30 CO2,aq 0.47094E-10 -10.3270 0.46931E-10 -10.3285 0.99653E+00 -0.0015 31 CO3-2 0.67090E-06 -6.1733 0.34752E-06 -6.4590 0.51799E+00 -0.2857 32 CaCO3,aq 0.30411E-09 -9.5170 0.30411E-09 -9.5170 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62940E-12 -12.2011 0.52663E-12 -12.2785 0.83671E+00 -0.0774 34 CaCl+ 0.22866E-10 -10.6408 0.19132E-10 -10.7182 0.83671E+00 -0.0774 35 CaCl2,aq 0.76994E-15 -15.1135 0.76994E-15 -15.1135 0.10000E+01 0.0000 36 CaOH+ 0.80010E-07 -7.0969 0.66946E-07 -7.1743 0.83671E+00 -0.0774 37 CaSO4,aq 0.10989E-16 -16.9590 0.10989E-16 -16.9590 0.10000E+01 0.0000 38 HCl,aq 0.23063E-14 -14.6371 0.23063E-14 -14.6371 0.10000E+01 0.0000 43 FeCl+ 0.96095E-17 -17.0173 0.80403E-17 -17.0947 0.83671E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15702E-10 -10.8040 0.13138E-10 -10.8815 0.83671E+00 -0.0774 48 HFeO2- 0.35602E-07 -7.4485 0.29732E-07 -7.5268 0.83511E+00 -0.0783 49 FeO+ 0.11004E-16 -16.9584 0.92075E-17 -17.0359 0.83671E+00 -0.0774 51 FeO2- 0.40868E-09 -9.3886 0.34129E-09 -9.4669 0.83511E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.40261E-09 -9.3951 0.40261E-09 -9.3951 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.12083E-14 -14.9178 0.10091E-14 -14.9961 0.83511E+00 -0.0783 58 MgCO3,aq 0.11871E-13 -13.9255 0.11871E-13 -13.9255 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10015E-15 -15.9993 0.83799E-16 -16.0768 0.83671E+00 -0.0774 60 MgCl+ 0.32273E-14 -14.4912 0.27003E-14 -14.5686 0.83671E+00 -0.0774 61 MgOH+ 0.68946E-10 -10.1615 0.57688E-10 -10.2389 0.83671E+00 -0.0774 63 MnO,aq 0.18044E-08 -8.7437 0.18044E-08 -8.7437 0.10000E+01 0.0000 64 MnOH+ 0.46785E-09 -9.3299 0.39146E-09 -9.4073 0.83671E+00 -0.0774 65 MnO2-2 0.20942E-10 -10.6790 0.10848E-10 -10.9647 0.51799E+00 -0.2857 66 HMnO2- 0.21144E-09 -9.6748 0.17657E-09 -9.7531 0.83511E+00 -0.0783 69 MnCl+ 0.11991E-13 -13.9211 0.10033E-13 -13.9986 0.83671E+00 -0.0774 71 NaCl,aq 0.93240E-06 -6.0304 0.93240E-06 -6.0304 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93286E-02 -2.0302 0.77763E-02 -2.1092 0.83360E+00 -0.0790 79 HPO3-2 0.16354E-14 -14.7864 0.84711E-15 -15.0721 0.51799E+00 -0.2857 81 H2PO3- 0.15113E-18 -18.8206 0.12621E-18 -18.8989 0.83511E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38480E-10 -10.4148 0.32166E-10 -10.4926 0.83590E+00 -0.0778 84 PO4-3 0.10630E-08 -8.9735 0.25771E-09 -9.5889 0.24243E+00 -0.6154 88 HP2O7-3 0.94366E-18 -18.0252 0.21802E-18 -18.6615 0.23104E+00 -0.6363 89 P2O7-4 0.91067E-17 -17.0406 0.70102E-18 -18.1543 0.76979E-01 -1.1136 90 H2S,aq 0.72481E-08 -8.1398 0.72230E-08 -8.1413 0.99653E+00 -0.0015 91 S2-2 0.36540E-14 -14.4372 0.18927E-14 -14.7229 0.51799E+00 -0.2857 97 SO3-2 0.14204E-17 -17.8476 0.74638E-18 -18.1270 0.52549E+00 -0.2794 99 HSO4- 0.42394E-19 -19.3727 0.35506E-19 -19.4497 0.83753E+00 -0.0770 Charge balance for all species = 0.7708E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8843384E-10 -.2227351E-01 -.2241131E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981980E+06 0.0000 3 Cl- 0.2028386E-03 0.2037715E-03 0.7211744E+01 6.3579 4 SO4-- 0.9552683E-12 -.2118387E-04 -.2031417E+01 7.9534 5 HCO3- 0.3534582E-06 0.1930284E-04 0.1175756E+01 3.5997 6 HS- 0.3765982E-04 0.5885094E-04 0.1942933E+01 5.6267 7 Al+++ 0.9742800E-29 0.5308915E-05 0.1429933E+00 0.7390 8 H4SiO4 0.6959711E-03 0.1351908E-01 0.1297132E+04 -3.1574 9 Ca++ 0.1354453E-06 0.2323982E-06 0.9297852E-02 13.1018 10 Mg++ 0.2118958E-10 0.9337120E-10 0.2266092E-05 9.2942 11 Fe++ 0.5840170E-13 0.3624101E-07 0.2020431E-02 6.7350 12 K+ 0.1567638E-03 0.1575179E-03 0.6148553E+01 6.2467 13 Na+ 0.1989258E-01 0.2233917E-01 0.5126798E+03 8.3494 14 Mn++ 0.1871648E-10 0.2523350E-08 0.1383867E-03 9.2411 15 HPO4-- 0.4520383E-07 0.4630532E-07 0.4436607E-02 12.6285 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5298722E+02 -.1508145E-01 -.5297214E+02 0.0000000E+00 2 H2O 0.1539495E+02 0.3758250E+02 -.2218755E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8870839E-01 -.1434365E-04 0.8872273E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8868288E-01 0.3984812E-04 -.8872273E-01 0.0000000E+00 7 Al+++ 0.1043437E+02 0.3594679E-05 0.1043437E+02 0.0000000E+00 8 H4SiO4 0.3332090E+02 0.9153803E-02 0.3331174E+02 0.0000000E+00 9 Ca++ 0.3680470E+01 0.1573574E-06 0.3680470E+01 0.0000000E+00 10 Mg++ 0.2539682E+01 0.6322187E-10 0.2539682E+01 0.0000000E+00 11 Fe++ 0.2281627E+01 0.2453888E-07 0.2281627E+01 0.0000000E+00 12 K+ 0.6794053E+00 0.1066558E-03 0.6792987E+00 0.0000000E+00 13 Na+ 0.4016938E+01 0.1512591E-01 0.4001813E+01 0.0000000E+00 14 Mn++ 0.5548349E-01 0.1708567E-08 0.5548349E-01 0.0000000E+00 15 HPO4-- 0.1893624E-01 0.3135345E-07 0.1893621E-01 0.0000000E+00 Chg. balance for solid moles: 0.5405E-14 Mass of aqueous solution: 0.678282E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.998 0.602 1048. 3.021 29.99 402.5 andradite 0.3549 -0.450 180.3 2.256 5.159 46.86 grossular 0.8594E-01 -1.066 38.71 1.588 1.107 10.77 apatite-OH 0.6312E-02 -2.200 3.171 0.501 0.9070E-01 1.008 clinochlore 0.4551 -0.342 252.9 2.403 7.235 96.21 daphnite 0.1317 -0.880 93.99 1.973 2.689 28.48 chlorite-Mn 0.1110E-01 -1.955 7.867 0.896 0.2250 2.507 diopside 0.1648 -0.783 35.69 1.553 1.021 10.91 hedenbergite 0.4274E-01 -1.369 10.60 1.025 0.3033 2.904 microcline 0.5957 -0.225 165.8 2.220 4.743 64.77 stilbite 2.064 0.315 1455. 3.163 41.61 678.4 stilpnomelane-Fe 0.1672 -0.777 180.3 2.256 5.156 62.27 tr.625ac.25prg.125 0.2747E-01 -1.561 23.48 1.371 0.6718 7.558 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3495.825898 g Volume = 1415.122703 cm3 Porosity: -10.4702% V(tot) - V(min): -.13412E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3199.9990000 g log = 3.5051 Original solution: 1000.0103000 g Original solution / Rock added: 0.31 (Water/Rock Ratio), log = -0.5051 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0626 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9608E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4693E-08 1.0068 0.5021E-08 0.4987E-08 CH4,gas 0.2492E-01 1.0124 0.2681E-01 0.2648E-01 H2,gas 0.1430E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1876E-06 0.9959 0.1986E-06 0.1994E-06 S2,gas 0.6022E-29 1.0000 0.6399E-29 0.6399E-29 CO,gas 0.1915E-13 1.0000 0.2035E-13 0.2035E-13 SO3,gas 0.9741E-48 1.0000 0.1035E-47 0.1035E-47 SO2,gas 0.5763E-27 1.0000 0.6123E-27 0.6123E-27 HCl,gas 0.3830E-17 1.0000 0.4069E-17 0.4069E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.66 -10.00 -3.333 0.17072E+05 -8.299 3 CH4,gas 4.54 1.27 -3.27 -0.818 0.55846E+04 -1.572 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.63 -8.40 -4.201 0.14345E+05 -6.702 6 S2,gas -7.34 -38.23 -30.89 -4.753 0.52749E+05 -29.194 7 CO,gas 3.21 -12.18 -15.39 -4.736 0.26279E+05 -13.691 8 SO3,gas 17.12 -32.56 -49.68 -12.421 0.84834E+05 -47.985 9 SO2,gas 0.83 -28.08 -28.91 -7.710 0.49366E+05 -27.213 10 HCl,gas 5.19 -13.90 -19.09 -9.545 0.32595E+05 -17.390 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80732E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.56 -4.52 -1.508 0.77229E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.56 -4.37 -1.456 0.74587E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65556E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.69 -4.59 -1.311 0.78377E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.69 -4.15 -1.185 0.70800E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82249E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.90 -3.64 -1.212 0.62084E+04 144 pyrrhotiteFe0.875 -6.02 -9.29 -3.28 -1.205 0.55956E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22452E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84961E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23255E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47142E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.90 -3.49 -1.162 0.59512E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79435E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66608E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.39 -4.41 -1.471 0.75339E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3199.9990000 g New total amount of reactant added: 3299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3299.9990000 Water: Moles liquid = 0.3703E+02 kg liquid = 0.6671E+00 Moles total = 0.1414E+02 kg total = 0.2548E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137469E-01 Osmotic coef. = 0.9689 True ionic strength = .2005255E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88443E-10 -10.0533 0.74306E-10 -10.1290 0.84016E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20589E-03 -3.6864 0.17194E-03 -3.7646 0.83510E+00 -0.0783 4 SO4-- 0.96959E-12 -12.0134 0.50329E-12 -12.2982 0.51908E+00 -0.2848 5 HCO3- 0.35875E-06 -6.4452 0.30004E-06 -6.5228 0.83633E+00 -0.0776 6 HS- 0.38227E-04 -4.4176 0.31928E-04 -4.4958 0.83523E+00 -0.0782 7 Al+++ 0.97460E-29 -29.0112 0.22493E-29 -29.6479 0.23080E+00 -0.6368 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13547E-06 -6.8681 0.69804E-07 -7.1561 0.51526E+00 -0.2880 10 Mg++ 0.21194E-10 -10.6738 0.10870E-10 -10.9638 0.51290E+00 -0.2900 11 Fe++ 0.58414E-13 -13.2335 0.29993E-13 -13.5230 0.51346E+00 -0.2895 12 K+ 0.15678E-03 -3.8047 0.13115E-03 -3.8822 0.83652E+00 -0.0775 13 Na+ 0.19895E-01 -1.7013 0.16611E-01 -1.7796 0.83495E+00 -0.0783 14 Mn++ 0.18722E-10 -10.7276 0.96210E-11 -11.0168 0.51389E+00 -0.2891 15 HPO4-- 0.45197E-07 -7.3449 0.23464E-07 -7.6296 0.51915E+00 -0.2847 16 HSiO3- 0.10473E-01 -1.9799 0.87457E-02 -2.0582 0.83510E+00 -0.0783 17 Ca(HSiO3)+ 0.16616E-07 -7.7795 0.13903E-07 -7.8569 0.83670E+00 -0.0774 18 Mg(HSiO3)+ 0.32204E-11 -11.4921 0.26945E-11 -11.5695 0.83670E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66239E-16 -16.1789 0.55422E-16 -16.2563 0.83670E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53083E-05 -5.2750 0.44250E-05 -5.3541 0.83359E+00 -0.0790 24 CH4,aq 0.18553E-04 -4.7316 0.18489E-04 -4.7331 0.99653E+00 -0.0015 25 C2H6,aq 0.50630E-14 -14.2956 0.50454E-14 -14.2971 0.99653E+00 -0.0015 29 CO,aq 0.13861E-16 -16.8582 0.13861E-16 -16.8582 0.10000E+01 0.0000 30 CO2,aq 0.47804E-10 -10.3205 0.47638E-10 -10.3220 0.99653E+00 -0.0015 31 CO3-2 0.68090E-06 -6.1669 0.35269E-06 -6.4526 0.51797E+00 -0.2857 32 CaCO3,aq 0.30870E-09 -9.5105 0.30870E-09 -9.5105 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63895E-12 -12.1945 0.53461E-12 -12.2720 0.83670E+00 -0.0774 34 CaCl+ 0.23214E-10 -10.6342 0.19423E-10 -10.7117 0.83670E+00 -0.0774 35 CaCl2,aq 0.79344E-15 -15.1005 0.79344E-15 -15.1005 0.10000E+01 0.0000 36 CaOH+ 0.80018E-07 -7.0968 0.66952E-07 -7.1742 0.83670E+00 -0.0774 37 CaSO4,aq 0.11156E-16 -16.9525 0.11156E-16 -16.9525 0.10000E+01 0.0000 38 HCl,aq 0.23412E-14 -14.6306 0.23412E-14 -14.6306 0.10000E+01 0.0000 43 FeCl+ 0.97559E-17 -17.0107 0.81628E-17 -17.0882 0.83670E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15703E-10 -10.8040 0.13139E-10 -10.8814 0.83670E+00 -0.0774 48 HFeO2- 0.35599E-07 -7.4486 0.29729E-07 -7.5268 0.83510E+00 -0.0783 49 FeO+ 0.11006E-16 -16.9584 0.92084E-17 -17.0358 0.83670E+00 -0.0774 51 FeO2- 0.40864E-09 -9.3887 0.34126E-09 -9.4669 0.83510E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.40870E-09 -9.3886 0.40870E-09 -9.3886 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.12265E-14 -14.9113 0.10243E-14 -14.9896 0.83510E+00 -0.0783 58 MgCO3,aq 0.12050E-13 -13.9190 0.12050E-13 -13.9190 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10167E-15 -15.9928 0.85070E-16 -16.0702 0.83670E+00 -0.0774 60 MgCl+ 0.32765E-14 -14.4846 0.27415E-14 -14.5620 0.83670E+00 -0.0774 61 MgOH+ 0.68953E-10 -10.1614 0.57693E-10 -10.2389 0.83670E+00 -0.0774 63 MnO,aq 0.18045E-08 -8.7436 0.18045E-08 -8.7436 0.10000E+01 0.0000 64 MnOH+ 0.46794E-09 -9.3298 0.39153E-09 -9.4072 0.83670E+00 -0.0774 65 MnO2-2 0.20940E-10 -10.6790 0.10846E-10 -10.9647 0.51797E+00 -0.2857 66 HMnO2- 0.21144E-09 -9.6748 0.17657E-09 -9.7531 0.83510E+00 -0.0783 69 MnCl+ 0.12175E-13 -13.9145 0.10187E-13 -13.9920 0.83670E+00 -0.0774 71 NaCl,aq 0.94652E-06 -6.0239 0.94652E-06 -6.0239 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93278E-02 -2.0302 0.77756E-02 -2.1093 0.83359E+00 -0.0790 79 HPO3-2 0.16351E-14 -14.7864 0.84695E-15 -15.0721 0.51797E+00 -0.2857 81 H2PO3- 0.15112E-18 -18.8207 0.12620E-18 -18.8989 0.83510E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38477E-10 -10.4148 0.32163E-10 -10.4926 0.83590E+00 -0.0778 84 PO4-3 0.10628E-08 -8.9736 0.25764E-09 -9.5890 0.24242E+00 -0.6154 88 HP2O7-3 0.94346E-18 -18.0253 0.21797E-18 -18.6616 0.23103E+00 -0.6363 89 P2O7-4 0.91043E-17 -17.0408 0.70077E-18 -18.1544 0.76971E-01 -1.1137 90 H2S,aq 0.73578E-08 -8.1332 0.73323E-08 -8.1348 0.99653E+00 -0.0015 91 S2-2 0.37649E-14 -14.4242 0.19501E-14 -14.7099 0.51797E+00 -0.2857 97 SO3-2 0.14416E-17 -17.8411 0.75754E-18 -18.1206 0.52547E+00 -0.2794 99 HSO4- 0.43032E-19 -19.3662 0.36041E-19 -19.4432 0.83752E+00 -0.0770 Charge balance for all species = 0.7828E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8844250E-10 -.2227185E-01 -.2240963E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981979E+06 0.0000 3 Cl- 0.2058923E-03 0.2068393E-03 0.7320317E+01 6.3644 4 SO4-- 0.9695887E-12 -.2145917E-04 -.2057816E+01 7.9598 5 HCO3- 0.3587544E-06 0.1959344E-04 0.1193457E+01 3.6061 6 HS- 0.3822680E-04 0.5969332E-04 0.1970743E+01 5.6331 7 Al+++ 0.9746029E-29 0.5308448E-05 0.1429807E+00 0.7390 8 H4SiO4 0.6959717E-03 0.1351820E-01 0.1297047E+04 -3.1574 9 Ca++ 0.1354736E-06 0.2324408E-06 0.9299557E-02 13.1018 10 Mg++ 0.2119402E-10 0.9338218E-10 0.2266358E-05 9.2942 11 Fe++ 0.5841395E-13 0.3623793E-07 0.2020259E-02 6.7350 12 K+ 0.1567792E-03 0.1575334E-03 0.6149154E+01 6.2467 13 Na+ 0.1989454E-01 0.2234114E-01 0.5127250E+03 8.3494 14 Mn++ 0.1872198E-10 0.2523590E-08 0.1383998E-03 9.2412 15 HPO4-- 0.4519678E-07 0.4629803E-07 0.4435909E-02 12.6284 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5464307E+02 -.1485665E-01 -.5462821E+02 0.0000000E+00 2 H2O 0.1414141E+02 0.3702509E+02 -.2288368E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9147973E-01 -.1431455E-04 0.9149404E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9145422E-01 0.3981902E-04 -.9149404E-01 0.0000000E+00 7 Al+++ 0.1076044E+02 0.3541052E-05 0.1076044E+02 0.0000000E+00 8 H4SiO4 0.3436217E+02 0.9017450E-02 0.3435316E+02 0.0000000E+00 9 Ca++ 0.3795484E+01 0.1550519E-06 0.3795484E+01 0.0000000E+00 10 Mg++ 0.2619047E+01 0.6229151E-10 0.2619047E+01 0.0000000E+00 11 Fe++ 0.2352928E+01 0.2417287E-07 0.2352928E+01 0.0000000E+00 12 K+ 0.7006367E+00 0.1050842E-03 0.7005316E+00 0.0000000E+00 13 Na+ 0.4142463E+01 0.1490288E-01 0.4127560E+01 0.0000000E+00 14 Mn++ 0.5721735E-01 0.1683386E-08 0.5721735E-01 0.0000000E+00 15 HPO4-- 0.1952800E-01 0.3088356E-07 0.1952797E-01 0.0000000E+00 Chg. balance for solid moles: -.8625E-14 Mass of aqueous solution: 0.668222E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.124 0.615 1081. 3.034 30.00 415.1 andradite 0.3660 -0.437 186.0 2.269 5.159 48.32 grossular 0.8862E-01 -1.052 39.92 1.601 1.107 11.11 apatite-OH 0.6509E-02 -2.186 3.270 0.515 0.9070E-01 1.039 clinochlore 0.4692 -0.329 260.8 2.416 7.235 99.21 daphnite 0.1358 -0.867 96.92 1.986 2.689 29.37 chlorite-Mn 0.1144E-01 -1.941 8.113 0.909 0.2250 2.585 diopside 0.1702 -0.769 36.86 1.567 1.023 11.27 hedenbergite 0.4415E-01 -1.355 10.95 1.040 0.3038 3.000 microcline 0.6143 -0.212 171.0 2.233 4.743 66.79 stilbite 2.128 0.328 1500. 3.176 41.60 699.5 stilpnomelane-Fe 0.1724 -0.763 185.9 2.269 5.157 64.21 tr.625ac.25prg.125 0.2831E-01 -1.548 24.20 1.384 0.6712 7.788 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3605.076562 g Volume = 1459.325767 cm3 Porosity: -10.4713% V(tot) - V(min): -.13833E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3299.9990000 g log = 3.5185 Original solution: 1000.0103000 g Original solution / Rock added: 0.30 (Water/Rock Ratio), log = -0.5185 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0630 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9604E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4762E-08 1.0068 0.5097E-08 0.5062E-08 CH4,gas 0.2529E-01 1.0124 0.2721E-01 0.2688E-01 H2,gas 0.1430E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1904E-06 0.9959 0.2016E-06 0.2024E-06 S2,gas 0.6204E-29 1.0000 0.6594E-29 0.6594E-29 CO,gas 0.1943E-13 1.0000 0.2066E-13 0.2066E-13 SO3,gas 0.9885E-48 1.0000 0.1051E-47 0.1051E-47 SO2,gas 0.5848E-27 1.0000 0.6216E-27 0.6216E-27 HCl,gas 0.3886E-17 1.0000 0.4131E-17 0.4131E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.65 -9.99 -3.331 0.17061E+05 -8.293 3 CH4,gas 4.54 1.28 -3.26 -0.816 0.55735E+04 -1.565 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.62 -8.39 -4.197 0.14333E+05 -6.696 6 S2,gas -7.34 -38.22 -30.88 -4.751 0.52726E+05 -29.181 7 CO,gas 3.21 -12.17 -15.38 -4.734 0.26268E+05 -13.685 8 SO3,gas 17.12 -32.56 -49.68 -12.419 0.84823E+05 -47.979 9 SO2,gas 0.83 -28.07 -28.91 -7.708 0.49355E+05 -27.206 10 HCl,gas 5.19 -13.89 -19.08 -9.541 0.32584E+05 -17.384 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80730E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.55 -4.52 -1.505 0.77118E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.55 -4.36 -1.454 0.74476E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65556E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.69 -4.58 -1.310 0.78266E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.69 -4.14 -1.183 0.70689E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82248E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.89 -3.63 -1.210 0.61973E+04 144 pyrrhotiteFe0.875 -6.02 -9.29 -3.27 -1.203 0.55845E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22452E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23254E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.32 -2.76 -0.394 0.47141E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.89 -3.48 -1.160 0.59401E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.38 -4.41 -1.469 0.75227E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3299.9990000 g New total amount of reactant added: 3399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3399.9990000 Water: Moles liquid = 0.3647E+02 kg liquid = 0.6570E+00 Moles total = 0.1289E+02 kg total = 0.2322E+00 Activity = 1.0000 Stoichiometric ionic strength = .1137731E-01 Osmotic coef. = 0.9689 True ionic strength = .2005459E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88451E-10 -10.0533 0.74313E-10 -10.1289 0.84016E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20904E-03 -3.6798 0.17457E-03 -3.7580 0.83510E+00 -0.0783 4 SO4-- 0.98434E-12 -12.0069 0.51094E-12 -12.2916 0.51906E+00 -0.2848 5 HCO3- 0.36421E-06 -6.4386 0.30460E-06 -6.5163 0.83632E+00 -0.0776 6 HS- 0.38811E-04 -4.4110 0.32416E-04 -4.4892 0.83522E+00 -0.0782 7 Al+++ 0.97494E-29 -29.0110 0.22500E-29 -29.6478 0.23078E+00 -0.6368 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13550E-06 -6.8681 0.69817E-07 -7.1560 0.51525E+00 -0.2880 10 Mg++ 0.21199E-10 -10.6737 0.10872E-10 -10.9637 0.51289E+00 -0.2900 11 Fe++ 0.58427E-13 -13.2334 0.29999E-13 -13.5229 0.51345E+00 -0.2895 12 K+ 0.15680E-03 -3.8047 0.13116E-03 -3.8822 0.83652E+00 -0.0775 13 Na+ 0.19897E-01 -1.7012 0.16613E-01 -1.7796 0.83495E+00 -0.0783 14 Mn++ 0.18728E-10 -10.7275 0.96236E-11 -11.0167 0.51387E+00 -0.2891 15 HPO4-- 0.45190E-07 -7.3450 0.23459E-07 -7.6297 0.51914E+00 -0.2847 16 HSiO3- 0.10472E-01 -1.9800 0.87449E-02 -2.0582 0.83510E+00 -0.0783 17 Ca(HSiO3)+ 0.16618E-07 -7.7794 0.13904E-07 -7.8568 0.83670E+00 -0.0774 18 Mg(HSiO3)+ 0.32207E-11 -11.4921 0.26947E-11 -11.5695 0.83670E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66245E-16 -16.1788 0.55427E-16 -16.2563 0.83670E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53078E-05 -5.2751 0.44245E-05 -5.3541 0.83359E+00 -0.0790 24 CH4,aq 0.18837E-04 -4.7250 0.18772E-04 -4.7265 0.99653E+00 -0.0015 25 C2H6,aq 0.52190E-14 -14.2824 0.52009E-14 -14.2839 0.99653E+00 -0.0015 29 CO,aq 0.14073E-16 -16.8516 0.14073E-16 -16.8516 0.10000E+01 0.0000 30 CO2,aq 0.48535E-10 -10.3139 0.48367E-10 -10.3155 0.99653E+00 -0.0015 31 CO3-2 0.69121E-06 -6.1604 0.35802E-06 -6.4461 0.51796E+00 -0.2857 32 CaCO3,aq 0.31342E-09 -9.5039 0.31342E-09 -9.5039 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64879E-12 -12.1879 0.54284E-12 -12.2653 0.83670E+00 -0.0774 34 CaCl+ 0.23573E-10 -10.6276 0.19724E-10 -10.7050 0.83670E+00 -0.0774 35 CaCl2,aq 0.81802E-15 -15.0872 0.81802E-15 -15.0872 0.10000E+01 0.0000 36 CaOH+ 0.80026E-07 -7.0968 0.66958E-07 -7.1742 0.83670E+00 -0.0774 37 CaSO4,aq 0.11328E-16 -16.9459 0.11328E-16 -16.9459 0.10000E+01 0.0000 38 HCl,aq 0.23772E-14 -14.6239 0.23772E-14 -14.6239 0.10000E+01 0.0000 43 FeCl+ 0.99069E-17 -17.0041 0.82891E-17 -17.0815 0.83670E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15705E-10 -10.8040 0.13140E-10 -10.8814 0.83670E+00 -0.0774 48 HFeO2- 0.35596E-07 -7.4486 0.29726E-07 -7.5269 0.83510E+00 -0.0783 49 FeO+ 0.11007E-16 -16.9583 0.92093E-17 -17.0358 0.83670E+00 -0.0774 51 FeO2- 0.40861E-09 -9.3887 0.34123E-09 -9.4670 0.83510E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.41499E-09 -9.3820 0.41499E-09 -9.3820 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.12453E-14 -14.9047 0.10399E-14 -14.9830 0.83510E+00 -0.0783 58 MgCO3,aq 0.12234E-13 -13.9124 0.12234E-13 -13.9124 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10324E-15 -15.9862 0.86379E-16 -16.0636 0.83670E+00 -0.0774 60 MgCl+ 0.33272E-14 -14.4779 0.27839E-14 -14.5554 0.83670E+00 -0.0774 61 MgOH+ 0.68960E-10 -10.1614 0.57699E-10 -10.2388 0.83670E+00 -0.0774 63 MnO,aq 0.18047E-08 -8.7436 0.18047E-08 -8.7436 0.10000E+01 0.0000 64 MnOH+ 0.46802E-09 -9.3297 0.39160E-09 -9.4072 0.83670E+00 -0.0774 65 MnO2-2 0.20939E-10 -10.6791 0.10845E-10 -10.9648 0.51796E+00 -0.2857 66 HMnO2- 0.21144E-09 -9.6748 0.17657E-09 -9.7531 0.83510E+00 -0.0783 69 MnCl+ 0.12364E-13 -13.9078 0.10345E-13 -13.9853 0.83670E+00 -0.0774 71 NaCl,aq 0.96107E-06 -6.0172 0.96107E-06 -6.0172 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93270E-02 -2.0303 0.77749E-02 -2.1093 0.83359E+00 -0.0790 79 HPO3-2 0.16349E-14 -14.7865 0.84679E-15 -15.0722 0.51796E+00 -0.2857 81 H2PO3- 0.15111E-18 -18.8207 0.12619E-18 -18.8990 0.83510E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38474E-10 -10.4148 0.32160E-10 -10.4927 0.83589E+00 -0.0779 84 PO4-3 0.10625E-08 -8.9737 0.25756E-09 -9.5891 0.24241E+00 -0.6155 88 HP2O7-3 0.94326E-18 -18.0254 0.21790E-18 -18.6617 0.23101E+00 -0.6364 89 P2O7-4 0.91018E-17 -17.0409 0.70050E-18 -18.1546 0.76963E-01 -1.1137 90 H2S,aq 0.74710E-08 -8.1266 0.74450E-08 -8.1281 0.99653E+00 -0.0015 91 S2-2 0.38809E-14 -14.4111 0.20102E-14 -14.6968 0.51796E+00 -0.2857 97 SO3-2 0.14636E-17 -17.8346 0.76905E-18 -18.1140 0.52546E+00 -0.2795 99 HSO4- 0.43691E-19 -19.3596 0.36592E-19 -19.4366 0.83751E+00 -0.0770 Charge balance for all species = 0.7949E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8845142E-10 -.2227013E-01 -.2240791E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981978E+06 0.0000 3 Cl- 0.2090393E-03 0.2100009E-03 0.7432208E+01 6.3709 4 SO4-- 0.9843442E-12 -.2174288E-04 -.2085023E+01 7.9662 5 HCO3- 0.3642115E-06 0.1989293E-04 0.1211700E+01 3.6127 6 HS- 0.3881110E-04 0.6056145E-04 0.1999404E+01 5.6397 7 Al+++ 0.9749359E-29 0.5307968E-05 0.1429678E+00 0.7390 8 H4SiO4 0.6959724E-03 0.1351730E-01 0.1296960E+04 -3.1574 9 Ca++ 0.1355027E-06 0.2324847E-06 0.9301315E-02 13.1018 10 Mg++ 0.2119858E-10 0.9339485E-10 0.2266666E-05 9.2942 11 Fe++ 0.5842657E-13 0.3623476E-07 0.2020082E-02 6.7350 12 K+ 0.1567951E-03 0.1575492E-03 0.6149773E+01 6.2467 13 Na+ 0.1989655E-01 0.2234318E-01 0.5127716E+03 8.3494 14 Mn++ 0.1872751E-10 0.2523819E-08 0.1384124E-03 9.2412 15 HPO4-- 0.4518951E-07 0.4629052E-07 0.4435189E-02 12.6282 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5629892E+02 -.1463186E-01 -.5628429E+02 0.0000000E+00 2 H2O 0.1288787E+02 0.3646767E+02 -.2357980E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9425107E-01 -.1428545E-04 0.9426535E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9422556E-01 0.3978992E-04 -.9426535E-01 0.0000000E+00 7 Al+++ 0.1108652E+02 0.3487427E-05 0.1108651E+02 0.0000000E+00 8 H4SiO4 0.3540345E+02 0.8881097E-02 0.3539457E+02 0.0000000E+00 9 Ca++ 0.3910498E+01 0.1527465E-06 0.3910498E+01 0.0000000E+00 10 Mg++ 0.2698412E+01 0.6136203E-10 0.2698412E+01 0.0000000E+00 11 Fe++ 0.2424229E+01 0.2380686E-07 0.2424228E+01 0.0000000E+00 12 K+ 0.7218682E+00 0.1035126E-03 0.7217646E+00 0.0000000E+00 13 Na+ 0.4267987E+01 0.1467985E-01 0.4253307E+01 0.0000000E+00 14 Mn++ 0.5895121E-01 0.1658193E-08 0.5895121E-01 0.0000000E+00 15 HPO4-- 0.2011975E-01 0.3041367E-07 0.2011972E-01 0.0000000E+00 Chg. balance for solid moles: -.1971E-14 Mass of aqueous solution: 0.658162E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.250 0.628 1114. 3.047 30.00 427.8 andradite 0.3771 -0.424 191.6 2.282 5.159 49.78 grossular 0.9130E-01 -1.040 41.13 1.614 1.107 11.44 apatite-OH 0.6707E-02 -2.173 3.369 0.527 0.9070E-01 1.070 clinochlore 0.4834 -0.316 268.7 2.429 7.234 102.2 daphnite 0.1399 -0.854 99.85 1.999 2.688 30.26 chlorite-Mn 0.1179E-01 -1.928 8.359 0.922 0.2250 2.664 diopside 0.1757 -0.755 38.04 1.580 1.024 11.63 hedenbergite 0.4556E-01 -1.341 11.30 1.053 0.3043 3.096 microcline 0.6329 -0.199 176.2 2.246 4.743 68.82 stilbite 2.192 0.341 1545. 3.189 41.60 720.6 stilpnomelane-Fe 0.1777 -0.750 191.5 2.282 5.157 66.16 tr.625ac.25prg.125 0.2914E-01 -1.535 24.91 1.396 0.6706 8.017 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3714.327227 g Volume = 1503.528832 cm3 Porosity: -10.4724% V(tot) - V(min): -.14253E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3399.9990000 g log = 3.5315 Original solution: 1000.0103000 g Original solution / Rock added: 0.29 (Water/Rock Ratio), log = -0.5315 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0634 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9600E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4833E-08 1.0068 0.5175E-08 0.5140E-08 CH4,gas 0.2567E-01 1.0123 0.2763E-01 0.2729E-01 H2,gas 0.1429E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1933E-06 0.9959 0.2047E-06 0.2055E-06 S2,gas 0.6394E-29 1.0000 0.6799E-29 0.6799E-29 CO,gas 0.1972E-13 1.0000 0.2097E-13 0.2097E-13 SO3,gas 0.1003E-47 1.0000 0.1067E-47 0.1067E-47 SO2,gas 0.5936E-27 1.0000 0.6312E-27 0.6312E-27 HCl,gas 0.3945E-17 1.0000 0.4195E-17 0.4195E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.65 -9.99 -3.328 0.17049E+05 -8.286 3 CH4,gas 4.54 1.29 -3.26 -0.814 0.55622E+04 -1.559 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.62 -8.39 -4.194 0.14322E+05 -6.689 6 S2,gas -7.34 -38.20 -30.87 -4.749 0.52704E+05 -29.168 7 CO,gas 3.21 -12.16 -15.38 -4.731 0.26256E+05 -13.678 8 SO3,gas 17.12 -32.55 -49.67 -12.418 0.84812E+05 -47.972 9 SO2,gas 0.83 -28.07 -28.90 -7.706 0.49344E+05 -27.200 10 HCl,gas 5.19 -13.89 -19.08 -9.538 0.32572E+05 -17.377 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80729E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.54 -4.51 -1.503 0.77005E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.54 -4.36 -1.452 0.74363E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65555E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.68 -4.58 -1.308 0.78154E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.68 -4.13 -1.181 0.70576E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82247E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40580E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.88 -3.62 -1.208 0.61860E+04 144 pyrrhotiteFe0.875 -6.02 -9.28 -3.26 -1.200 0.55732E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22451E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23254E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47140E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.88 -3.47 -1.157 0.59288E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.38 -4.40 -1.466 0.75113E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3399.9990000 g New total amount of reactant added: 3499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3499.9990000 Water: Moles liquid = 0.3591E+02 kg liquid = 0.6470E+00 Moles total = 0.1163E+02 kg total = 0.2096E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138002E-01 Osmotic coef. = 0.9688 True ionic strength = .2005670E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88461E-10 -10.0533 0.74320E-10 -10.1289 0.84015E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21228E-03 -3.6731 0.17728E-03 -3.7513 0.83509E+00 -0.0783 4 SO4-- 0.99956E-12 -12.0002 0.51882E-12 -12.2850 0.51905E+00 -0.2848 5 HCO3- 0.36984E-06 -6.4320 0.30930E-06 -6.5096 0.83631E+00 -0.0776 6 HS- 0.39414E-04 -4.4044 0.32919E-04 -4.4826 0.83521E+00 -0.0782 7 Al+++ 0.97528E-29 -29.0109 0.22506E-29 -29.6477 0.23077E+00 -0.6368 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13553E-06 -6.8680 0.69831E-07 -7.1560 0.51523E+00 -0.2880 10 Mg++ 0.21203E-10 -10.6736 0.10875E-10 -10.9636 0.51287E+00 -0.2900 11 Fe++ 0.58440E-13 -13.2333 0.30005E-13 -13.5228 0.51343E+00 -0.2895 12 K+ 0.15681E-03 -3.8046 0.13117E-03 -3.8821 0.83651E+00 -0.0775 13 Na+ 0.19899E-01 -1.7012 0.16614E-01 -1.7795 0.83494E+00 -0.0783 14 Mn++ 0.18733E-10 -10.7274 0.96262E-11 -11.0165 0.51386E+00 -0.2892 15 HPO4-- 0.45182E-07 -7.3450 0.23455E-07 -7.6298 0.51912E+00 -0.2847 16 HSiO3- 0.10471E-01 -1.9800 0.87440E-02 -2.0583 0.83509E+00 -0.0783 17 Ca(HSiO3)+ 0.16620E-07 -7.7794 0.13906E-07 -7.8568 0.83669E+00 -0.0774 18 Mg(HSiO3)+ 0.32210E-11 -11.4920 0.26950E-11 -11.5694 0.83669E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66252E-16 -16.1788 0.55433E-16 -16.2562 0.83669E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53073E-05 -5.2751 0.44241E-05 -5.3542 0.83358E+00 -0.0791 24 CH4,aq 0.19130E-04 -4.7183 0.19063E-04 -4.7198 0.99653E+00 -0.0015 25 C2H6,aq 0.53824E-14 -14.2690 0.53637E-14 -14.2705 0.99653E+00 -0.0015 29 CO,aq 0.14292E-16 -16.8449 0.14292E-16 -16.8449 0.10000E+01 0.0000 30 CO2,aq 0.49289E-10 -10.3072 0.49118E-10 -10.3088 0.99653E+00 -0.0015 31 CO3-2 0.70183E-06 -6.1538 0.36351E-06 -6.4395 0.51794E+00 -0.2857 32 CaCO3,aq 0.31829E-09 -9.4972 0.31829E-09 -9.4972 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65894E-12 -12.1812 0.55133E-12 -12.2586 0.83669E+00 -0.0774 34 CaCl+ 0.23944E-10 -10.6208 0.20034E-10 -10.6982 0.83669E+00 -0.0774 35 CaCl2,aq 0.84376E-15 -15.0738 0.84376E-15 -15.0738 0.10000E+01 0.0000 36 CaOH+ 0.80034E-07 -7.0967 0.66964E-07 -7.1742 0.83669E+00 -0.0774 37 CaSO4,aq 0.11505E-16 -16.9391 0.11505E-16 -16.9391 0.10000E+01 0.0000 38 HCl,aq 0.24143E-14 -14.6172 0.24143E-14 -14.6172 0.10000E+01 0.0000 43 FeCl+ 0.10063E-16 -16.9973 0.84193E-17 -17.0747 0.83669E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15707E-10 -10.8039 0.13142E-10 -10.8814 0.83669E+00 -0.0774 48 HFeO2- 0.35593E-07 -7.4486 0.29723E-07 -7.5269 0.83509E+00 -0.0783 49 FeO+ 0.11008E-16 -16.9583 0.92102E-17 -17.0357 0.83669E+00 -0.0774 51 FeO2- 0.40857E-09 -9.3887 0.34120E-09 -9.4670 0.83509E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.42146E-09 -9.3752 0.42146E-09 -9.3752 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.12646E-14 -14.8980 0.10561E-14 -14.9763 0.83509E+00 -0.0783 58 MgCO3,aq 0.12424E-13 -13.9057 0.12424E-13 -13.9057 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10485E-15 -15.9794 0.87730E-16 -16.0569 0.83669E+00 -0.0774 60 MgCl+ 0.33795E-14 -14.4711 0.28276E-14 -14.5486 0.83669E+00 -0.0774 61 MgOH+ 0.68967E-10 -10.1614 0.57704E-10 -10.2388 0.83669E+00 -0.0774 63 MnO,aq 0.18048E-08 -8.7436 0.18048E-08 -8.7436 0.10000E+01 0.0000 64 MnOH+ 0.46811E-09 -9.3297 0.39166E-09 -9.4071 0.83669E+00 -0.0774 65 MnO2-2 0.20937E-10 -10.6791 0.10844E-10 -10.9648 0.51794E+00 -0.2857 66 HMnO2- 0.21143E-09 -9.6748 0.17657E-09 -9.7531 0.83509E+00 -0.0783 69 MnCl+ 0.12560E-13 -13.9010 0.10509E-13 -13.9785 0.83669E+00 -0.0774 71 NaCl,aq 0.97608E-06 -6.0105 0.97608E-06 -6.0105 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93261E-02 -2.0303 0.77741E-02 -2.1093 0.83358E+00 -0.0791 79 HPO3-2 0.16346E-14 -14.7866 0.84663E-15 -15.0723 0.51794E+00 -0.2857 81 H2PO3- 0.15109E-18 -18.8208 0.12618E-18 -18.8990 0.83509E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38471E-10 -10.4149 0.32157E-10 -10.4927 0.83588E+00 -0.0779 84 PO4-3 0.10623E-08 -8.9738 0.25749E-09 -9.5892 0.24239E+00 -0.6155 88 HP2O7-3 0.94304E-18 -18.0255 0.21784E-18 -18.6619 0.23100E+00 -0.6364 89 P2O7-4 0.90993E-17 -17.0410 0.70023E-18 -18.1548 0.76954E-01 -1.1138 90 H2S,aq 0.75876E-08 -8.1199 0.75613E-08 -8.1214 0.99653E+00 -0.0015 91 S2-2 0.40024E-14 -14.3977 0.20730E-14 -14.6834 0.51794E+00 -0.2857 97 SO3-2 0.14862E-17 -17.8279 0.78091E-18 -18.1074 0.52545E+00 -0.2795 99 HSO4- 0.44369E-19 -19.3529 0.37160E-19 -19.4299 0.83751E+00 -0.0770 Charge balance for all species = 0.8072E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8846062E-10 -.2226836E-01 -.2240613E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981977E+06 0.0000 3 Cl- 0.2122841E-03 0.2132606E-03 0.7547574E+01 6.3775 4 SO4-- 0.9995550E-12 -.2203541E-04 -.2113075E+01 7.9728 5 HCO3- 0.3698369E-06 0.2020172E-04 0.1230508E+01 3.6193 6 HS- 0.3941354E-04 0.6145654E-04 0.2028955E+01 5.6463 7 Al+++ 0.9752795E-29 0.5307475E-05 0.1429545E+00 0.7390 8 H4SiO4 0.6959730E-03 0.1351636E-01 0.1296870E+04 -3.1574 9 Ca++ 0.1355328E-06 0.2325301E-06 0.9303128E-02 13.1018 10 Mg++ 0.2120330E-10 0.9340723E-10 0.2266966E-05 9.2942 11 Fe++ 0.5843959E-13 0.3623150E-07 0.2019900E-02 6.7350 12 K+ 0.1568114E-03 0.1575656E-03 0.6150411E+01 6.2467 13 Na+ 0.1989863E-01 0.2234527E-01 0.5128197E+03 8.3494 14 Mn++ 0.1873308E-10 0.2524038E-08 0.1384243E-03 9.2412 15 HPO4-- 0.4518201E-07 0.4628278E-07 0.4434446E-02 12.6280 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5795477E+02 -.1440707E-01 -.5794037E+02 0.0000000E+00 2 H2O 0.1163433E+02 0.3591026E+02 -.2427593E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9702241E-01 -.1425635E-04 0.9703666E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9699690E-01 0.3976082E-04 -.9703666E-01 0.0000000E+00 7 Al+++ 0.1141259E+02 0.3433802E-05 0.1141259E+02 0.0000000E+00 8 H4SiO4 0.3644473E+02 0.8744743E-02 0.3643599E+02 0.0000000E+00 9 Ca++ 0.4025513E+01 0.1504411E-06 0.4025512E+01 0.0000000E+00 10 Mg++ 0.2777777E+01 0.6043210E-10 0.2777777E+01 0.0000000E+00 11 Fe++ 0.2495529E+01 0.2344086E-07 0.2495529E+01 0.0000000E+00 12 K+ 0.7430996E+00 0.1019409E-03 0.7429976E+00 0.0000000E+00 13 Na+ 0.4393512E+01 0.1445682E-01 0.4379055E+01 0.0000000E+00 14 Mn++ 0.6068507E-01 0.1632988E-08 0.6068507E-01 0.0000000E+00 15 HPO4-- 0.2071151E-01 0.2994378E-07 0.2071148E-01 0.0000000E+00 Chg. balance for solid moles: 0.8604E-15 Mass of aqueous solution: 0.648102E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.375 0.641 1147. 3.060 30.01 440.4 andradite 0.3881 -0.411 197.2 2.295 5.159 51.25 grossular 0.9399E-01 -1.027 42.34 1.627 1.107 11.78 apatite-OH 0.6904E-02 -2.161 3.468 0.540 0.9070E-01 1.102 clinochlore 0.4976 -0.303 276.6 2.442 7.234 105.2 daphnite 0.1441 -0.841 102.8 2.012 2.688 31.15 chlorite-Mn 0.1214E-01 -1.916 8.605 0.935 0.2250 2.742 diopside 0.1811 -0.742 39.22 1.594 1.026 11.99 hedenbergite 0.4697E-01 -1.328 11.65 1.066 0.3048 3.192 microcline 0.6515 -0.186 181.4 2.259 4.743 70.84 stilbite 2.257 0.353 1590. 3.201 41.59 741.7 stilpnomelane-Fe 0.1829 -0.738 197.2 2.295 5.157 68.11 tr.625ac.25prg.125 0.2998E-01 -1.523 25.62 1.409 0.6701 8.246 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3823.577892 g Volume = 1547.731896 cm3 Porosity: -10.4734% V(tot) - V(min): -.14673E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3499.9990000 g log = 3.5441 Original solution: 1000.0103000 g Original solution / Rock added: 0.29 (Water/Rock Ratio), log = -0.5441 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0638 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9597E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4906E-08 1.0068 0.5255E-08 0.5220E-08 CH4,gas 0.2605E-01 1.0123 0.2806E-01 0.2772E-01 H2,gas 0.1429E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1962E-06 0.9959 0.2079E-06 0.2087E-06 S2,gas 0.6592E-29 1.0000 0.7013E-29 0.7013E-29 CO,gas 0.2002E-13 1.0000 0.2130E-13 0.2130E-13 SO3,gas 0.1019E-47 1.0000 0.1084E-47 0.1084E-47 SO2,gas 0.6026E-27 1.0000 0.6410E-27 0.6410E-27 HCl,gas 0.4005E-17 1.0000 0.4260E-17 0.4260E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.64 -9.98 -3.326 0.17038E+05 -8.279 3 CH4,gas 4.54 1.29 -3.25 -0.813 0.55508E+04 -1.552 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.61 -8.38 -4.191 0.14311E+05 -6.682 6 S2,gas -7.34 -38.19 -30.85 -4.747 0.52681E+05 -29.154 7 CO,gas 3.21 -12.16 -15.37 -4.729 0.26245E+05 -13.672 8 SO3,gas 17.12 -32.54 -49.66 -12.416 0.84800E+05 -47.965 9 SO2,gas 0.83 -28.06 -28.89 -7.705 0.49332E+05 -27.193 10 HCl,gas 5.19 -13.88 -19.07 -9.535 0.32561E+05 -17.371 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80727E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.54 -4.50 -1.501 0.76891E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.54 -4.35 -1.449 0.74249E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65555E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.67 -4.57 -1.306 0.78039E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.67 -4.13 -1.179 0.70462E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82247E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.88 -3.62 -1.205 0.61745E+04 144 pyrrhotiteFe0.875 -6.02 -9.27 -3.26 -1.198 0.55617E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22451E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23253E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47139E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90679E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.88 -3.47 -1.155 0.59173E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60611E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.37 -4.39 -1.464 0.74998E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3499.9990000 g New total amount of reactant added: 3599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3599.9990000 Water: Moles liquid = 0.3535E+02 kg liquid = 0.6369E+00 Moles total = 0.1038E+02 kg total = 0.1870E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138280E-01 Osmotic coef. = 0.9688 True ionic strength = .2005887E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88470E-10 -10.0532 0.74328E-10 -10.1288 0.84015E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21563E-03 -3.6663 0.18007E-03 -3.7446 0.83509E+00 -0.0783 4 SO4-- 0.10152E-11 -11.9934 0.52694E-12 -12.2782 0.51903E+00 -0.2848 5 HCO3- 0.37564E-06 -6.4252 0.31415E-06 -6.5029 0.83631E+00 -0.0776 6 HS- 0.40035E-04 -4.3976 0.33438E-04 -4.4758 0.83521E+00 -0.0782 7 Al+++ 0.97563E-29 -29.0107 0.22513E-29 -29.6476 0.23075E+00 -0.6369 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13556E-06 -6.8679 0.69845E-07 -7.1559 0.51522E+00 -0.2880 10 Mg++ 0.21208E-10 -10.6735 0.10877E-10 -10.9635 0.51286E+00 -0.2900 11 Fe++ 0.58453E-13 -13.2332 0.30011E-13 -13.5227 0.51342E+00 -0.2895 12 K+ 0.15683E-03 -3.8046 0.13119E-03 -3.8821 0.83651E+00 -0.0775 13 Na+ 0.19901E-01 -1.7011 0.16616E-01 -1.7795 0.83493E+00 -0.0783 14 Mn++ 0.18739E-10 -10.7273 0.96288E-11 -11.0164 0.51385E+00 -0.2892 15 HPO4-- 0.45174E-07 -7.3451 0.23450E-07 -7.6299 0.51911E+00 -0.2847 16 HSiO3- 0.10470E-01 -1.9801 0.87432E-02 -2.0583 0.83509E+00 -0.0783 17 Ca(HSiO3)+ 0.16622E-07 -7.7793 0.13907E-07 -7.8568 0.83669E+00 -0.0774 18 Mg(HSiO3)+ 0.32214E-11 -11.4920 0.26953E-11 -11.5694 0.83669E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66259E-16 -16.1788 0.55438E-16 -16.2562 0.83669E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53068E-05 -5.2752 0.44236E-05 -5.3542 0.83358E+00 -0.0791 24 CH4,aq 0.19431E-04 -4.7115 0.19364E-04 -4.7130 0.99653E+00 -0.0015 25 C2H6,aq 0.55536E-14 -14.2554 0.55343E-14 -14.2569 0.99653E+00 -0.0015 29 CO,aq 0.14517E-16 -16.8381 0.14517E-16 -16.8381 0.10000E+01 0.0000 30 CO2,aq 0.50067E-10 -10.3004 0.49894E-10 -10.3020 0.99653E+00 -0.0015 31 CO3-2 0.71278E-06 -6.1470 0.36917E-06 -6.4328 0.51793E+00 -0.2857 32 CaCO3,aq 0.32331E-09 -9.4904 0.32331E-09 -9.4904 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.66941E-12 -12.1743 0.56008E-12 -12.2517 0.83669E+00 -0.0774 34 CaCl+ 0.24326E-10 -10.6139 0.20353E-10 -10.6914 0.83669E+00 -0.0774 35 CaCl2,aq 0.87074E-15 -15.0601 0.87074E-15 -15.0601 0.10000E+01 0.0000 36 CaOH+ 0.80043E-07 -7.0967 0.66971E-07 -7.1741 0.83669E+00 -0.0774 37 CaSO4,aq 0.11687E-16 -16.9323 0.11687E-16 -16.9323 0.10000E+01 0.0000 38 HCl,aq 0.24526E-14 -14.6104 0.24526E-14 -14.6104 0.10000E+01 0.0000 43 FeCl+ 0.10223E-16 -16.9904 0.85537E-17 -17.0678 0.83669E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15708E-10 -10.8039 0.13143E-10 -10.8813 0.83669E+00 -0.0774 48 HFeO2- 0.35589E-07 -7.4487 0.29720E-07 -7.5269 0.83509E+00 -0.0783 49 FeO+ 0.11009E-16 -16.9583 0.92111E-17 -17.0357 0.83669E+00 -0.0774 51 FeO2- 0.40853E-09 -9.3888 0.34116E-09 -9.4670 0.83509E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.42815E-09 -9.3684 0.42815E-09 -9.3684 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.12846E-14 -14.8912 0.10727E-14 -14.9695 0.83509E+00 -0.0783 58 MgCO3,aq 0.12620E-13 -13.8989 0.12620E-13 -13.8989 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10652E-15 -15.9726 0.89123E-16 -16.0500 0.83669E+00 -0.0774 60 MgCl+ 0.34335E-14 -14.4643 0.28727E-14 -14.5417 0.83669E+00 -0.0774 61 MgOH+ 0.68974E-10 -10.1613 0.57710E-10 -10.2387 0.83669E+00 -0.0774 63 MnO,aq 0.18049E-08 -8.7435 0.18049E-08 -8.7435 0.10000E+01 0.0000 64 MnOH+ 0.46819E-09 -9.3296 0.39173E-09 -9.4070 0.83669E+00 -0.0774 65 MnO2-2 0.20934E-10 -10.6791 0.10843E-10 -10.9649 0.51793E+00 -0.2857 66 HMnO2- 0.21143E-09 -9.6748 0.17656E-09 -9.7531 0.83509E+00 -0.0783 69 MnCl+ 0.12761E-13 -13.8941 0.10677E-13 -13.9716 0.83669E+00 -0.0774 71 NaCl,aq 0.99156E-06 -6.0037 0.99156E-06 -6.0037 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93253E-02 -2.0303 0.77733E-02 -2.1094 0.83358E+00 -0.0791 79 HPO3-2 0.16343E-14 -14.7867 0.84646E-15 -15.0724 0.51793E+00 -0.2857 81 H2PO3- 0.15108E-18 -18.8208 0.12616E-18 -18.8991 0.83509E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38467E-10 -10.4149 0.32154E-10 -10.4928 0.83588E+00 -0.0779 84 PO4-3 0.10620E-08 -8.9739 0.25741E-09 -9.5894 0.24238E+00 -0.6155 88 HP2O7-3 0.94282E-18 -18.0256 0.21778E-18 -18.6620 0.23098E+00 -0.6364 89 P2O7-4 0.90967E-17 -17.0411 0.69995E-18 -18.1549 0.76946E-01 -1.1138 90 H2S,aq 0.77080E-08 -8.1131 0.76812E-08 -8.1146 0.99653E+00 -0.0015 91 S2-2 0.41297E-14 -14.3841 0.21389E-14 -14.6698 0.51793E+00 -0.2857 97 SO3-2 0.15095E-17 -17.8212 0.79314E-18 -18.1006 0.52543E+00 -0.2795 99 HSO4- 0.45069E-19 -19.3461 0.37745E-19 -19.4231 0.83750E+00 -0.0770 Charge balance for all species = 0.8201E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8847011E-10 -.2226654E-01 -.2240429E+02 0.0000 2 H2O 0.1000000E+01 0.5550489E+02 0.9981976E+06 0.0000 3 Cl- 0.2156311E-03 0.2166231E-03 0.7666577E+01 6.3843 4 SO4-- 0.1015243E-11 -.2233717E-04 -.2142011E+01 7.9795 5 HCO3- 0.3756386E-06 0.2052024E-04 0.1249909E+01 3.6260 6 HS- 0.4003498E-04 0.6237986E-04 0.2059438E+01 5.6531 7 Al+++ 0.9756343E-29 0.5306968E-05 0.1429408E+00 0.7390 8 H4SiO4 0.6959736E-03 0.1351540E-01 0.1296778E+04 -3.1574 9 Ca++ 0.1355639E-06 0.2325769E-06 0.9304999E-02 13.1018 10 Mg++ 0.2120816E-10 0.9341999E-10 0.2267275E-05 9.2942 11 Fe++ 0.5845303E-13 0.3622813E-07 0.2019712E-02 6.7350 12 K+ 0.1568283E-03 0.1575825E-03 0.6151069E+01 6.2467 13 Na+ 0.1990078E-01 0.2234743E-01 0.5128692E+03 8.3494 14 Mn++ 0.1873871E-10 0.2524247E-08 0.1384358E-03 9.2413 15 HPO4-- 0.4517428E-07 0.4627478E-07 0.4433680E-02 12.6278 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5961063E+02 -.1418227E-01 -.5959644E+02 0.0000000E+00 2 H2O 0.1038079E+02 0.3535284E+02 -.2497206E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9979375E-01 -.1422726E-04 0.9980798E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9976824E-01 0.3973173E-04 -.9980798E-01 0.0000000E+00 7 Al+++ 0.1173867E+02 0.3380177E-05 0.1173866E+02 0.0000000E+00 8 H4SiO4 0.3748601E+02 0.8608389E-02 0.3747740E+02 0.0000000E+00 9 Ca++ 0.4140527E+01 0.1481356E-06 0.4140527E+01 0.0000000E+00 10 Mg++ 0.2857142E+01 0.5950218E-10 0.2857142E+01 0.0000000E+00 11 Fe++ 0.2566830E+01 0.2307486E-07 0.2566830E+01 0.0000000E+00 12 K+ 0.7643310E+00 0.1003693E-03 0.7642306E+00 0.0000000E+00 13 Na+ 0.4519036E+01 0.1423380E-01 0.4504802E+01 0.0000000E+00 14 Mn++ 0.6241893E-01 0.1607773E-08 0.6241893E-01 0.0000000E+00 15 HPO4-- 0.2130327E-01 0.2947389E-07 0.2130324E-01 0.0000000E+00 Chg. balance for solid moles: 0.4802E-14 Mass of aqueous solution: 0.638042E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.501 0.653 1180. 3.072 30.01 453.1 andradite 0.3992 -0.399 202.9 2.307 5.159 52.71 grossular 0.9667E-01 -1.015 43.55 1.639 1.107 12.12 apatite-OH 0.7101E-02 -2.149 3.567 0.552 0.9070E-01 1.133 clinochlore 0.5118 -0.291 284.5 2.454 7.233 108.2 daphnite 0.1482 -0.829 105.7 2.024 2.688 32.03 chlorite-Mn 0.1248E-01 -1.904 8.851 0.947 0.2250 2.820 diopside 0.1865 -0.729 40.40 1.606 1.027 12.35 hedenbergite 0.4838E-01 -1.315 12.00 1.079 0.3052 3.287 microcline 0.6702 -0.174 186.5 2.271 4.743 72.86 stilbite 2.321 0.366 1635. 3.214 41.59 762.8 stilpnomelane-Fe 0.1881 -0.726 202.8 2.307 5.157 70.06 tr.625ac.25prg.125 0.3081E-01 -1.511 26.33 1.421 0.6696 8.476 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3932.828556 g Volume = 1591.934960 cm3 Porosity: -10.4744% V(tot) - V(min): -.15094E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3599.9990000 g log = 3.5563 Original solution: 1000.0103000 g Original solution / Rock added: 0.28 (Water/Rock Ratio), log = -0.5563 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0643 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9593E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.4982E-08 1.0068 0.5338E-08 0.5302E-08 CH4,gas 0.2646E-01 1.0123 0.2850E-01 0.2816E-01 H2,gas 0.1428E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.1992E-06 0.9959 0.2112E-06 0.2120E-06 S2,gas 0.6800E-29 1.0000 0.7237E-29 0.7237E-29 CO,gas 0.2033E-13 1.0000 0.2163E-13 0.2163E-13 SO3,gas 0.1034E-47 1.0000 0.1101E-47 0.1101E-47 SO2,gas 0.6119E-27 1.0000 0.6512E-27 0.6512E-27 HCl,gas 0.4066E-17 1.0000 0.4328E-17 0.4328E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.15165E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.63 -9.97 -3.324 0.17026E+05 -8.273 3 CH4,gas 4.54 1.30 -3.24 -0.811 0.55392E+04 -1.545 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.60 -8.37 -4.187 0.14299E+05 -6.675 6 S2,gas -7.34 -38.17 -30.84 -4.745 0.52657E+05 -29.140 7 CO,gas 3.21 -12.15 -15.36 -4.727 0.26233E+05 -13.665 8 SO3,gas 17.12 -32.54 -49.66 -12.414 0.84788E+05 -47.958 9 SO2,gas 0.83 -28.05 -28.89 -7.703 0.49321E+05 -27.186 10 HCl,gas 5.19 -13.87 -19.06 -9.531 0.32549E+05 -17.364 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80726E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.53 -4.50 -1.499 0.76775E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.53 -4.34 -1.447 0.74133E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65554E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.67 -4.56 -1.304 0.77923E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.67 -4.12 -1.177 0.70346E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23069E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82246E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91157E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.87 -3.61 -1.203 0.61628E+04 144 pyrrhotiteFe0.875 -6.02 -9.27 -3.25 -1.195 0.55500E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22450E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23253E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47137E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.87 -3.46 -1.153 0.59056E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.36 -4.39 -1.462 0.74881E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3599.9990000 g New total amount of reactant added: 3699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3699.9990000 Water: Moles liquid = 0.3480E+02 kg liquid = 0.6269E+00 Moles total = 0.9127E+01 kg total = 0.1644E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138568E-01 Osmotic coef. = 0.9688 True ionic strength = .2006111E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88480E-10 -10.0532 0.74335E-10 -10.1288 0.84014E+00 -0.0756 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21909E-03 -3.6594 0.18295E-03 -3.7377 0.83508E+00 -0.0783 4 SO4-- 0.10314E-11 -11.9866 0.53533E-12 -12.2714 0.51902E+00 -0.2848 5 HCO3- 0.38162E-06 -6.4184 0.31915E-06 -6.4960 0.83630E+00 -0.0776 6 HS- 0.40676E-04 -4.3907 0.33973E-04 -4.4689 0.83520E+00 -0.0782 7 Al+++ 0.97600E-29 -29.0105 0.22520E-29 -29.6474 0.23074E+00 -0.6369 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13560E-06 -6.8678 0.69859E-07 -7.1558 0.51520E+00 -0.2880 10 Mg++ 0.21213E-10 -10.6734 0.10879E-10 -10.9634 0.51284E+00 -0.2900 11 Fe++ 0.58467E-13 -13.2331 0.30017E-13 -13.5226 0.51340E+00 -0.2895 12 K+ 0.15685E-03 -3.8045 0.13120E-03 -3.8821 0.83650E+00 -0.0775 13 Na+ 0.19903E-01 -1.7011 0.16618E-01 -1.7794 0.83493E+00 -0.0784 14 Mn++ 0.18744E-10 -10.7271 0.96314E-11 -11.0163 0.51383E+00 -0.2892 15 HPO4-- 0.45166E-07 -7.3452 0.23445E-07 -7.6299 0.51909E+00 -0.2848 16 HSiO3- 0.10469E-01 -1.9801 0.87423E-02 -2.0584 0.83508E+00 -0.0783 17 Ca(HSiO3)+ 0.16624E-07 -7.7793 0.13909E-07 -7.8567 0.83668E+00 -0.0774 18 Mg(HSiO3)+ 0.32217E-11 -11.4919 0.26956E-11 -11.5694 0.83668E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66266E-16 -16.1787 0.55444E-16 -16.2561 0.83668E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53063E-05 -5.2752 0.44232E-05 -5.3543 0.83357E+00 -0.0791 24 CH4,aq 0.19743E-04 -4.7046 0.19674E-04 -4.7061 0.99653E+00 -0.0015 25 C2H6,aq 0.57330E-14 -14.2416 0.57131E-14 -14.2431 0.99653E+00 -0.0015 29 CO,aq 0.14750E-16 -16.8312 0.14750E-16 -16.8312 0.10000E+01 0.0000 30 CO2,aq 0.50870E-10 -10.2935 0.50694E-10 -10.2950 0.99653E+00 -0.0015 31 CO3-2 0.72408E-06 -6.1402 0.37501E-06 -6.4260 0.51791E+00 -0.2857 32 CaCO3,aq 0.32850E-09 -9.4835 0.32850E-09 -9.4835 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.68022E-12 -12.1674 0.56912E-12 -12.2448 0.83668E+00 -0.0774 34 CaCl+ 0.24721E-10 -10.6069 0.20684E-10 -10.6844 0.83668E+00 -0.0774 35 CaCl2,aq 0.89903E-15 -15.0462 0.89903E-15 -15.0462 0.10000E+01 0.0000 36 CaOH+ 0.80052E-07 -7.0966 0.66978E-07 -7.1741 0.83668E+00 -0.0774 37 CaSO4,aq 0.11876E-16 -16.9253 0.11876E-16 -16.9253 0.10000E+01 0.0000 38 HCl,aq 0.24921E-14 -14.6034 0.24921E-14 -14.6034 0.10000E+01 0.0000 43 FeCl+ 0.10389E-16 -16.9834 0.86925E-17 -17.0609 0.83668E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15710E-10 -10.8038 0.13144E-10 -10.8813 0.83668E+00 -0.0774 48 HFeO2- 0.35586E-07 -7.4487 0.29717E-07 -7.5270 0.83508E+00 -0.0783 49 FeO+ 0.11010E-16 -16.9582 0.92121E-17 -17.0356 0.83668E+00 -0.0774 51 FeO2- 0.40850E-09 -9.3888 0.34113E-09 -9.4671 0.83508E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.43505E-09 -9.3615 0.43505E-09 -9.3615 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.13051E-14 -14.8843 0.10899E-14 -14.9626 0.83508E+00 -0.0783 58 MgCO3,aq 0.12823E-13 -13.8920 0.12823E-13 -13.8920 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10824E-15 -15.9656 0.90562E-16 -16.0431 0.83668E+00 -0.0774 60 MgCl+ 0.34892E-14 -14.4573 0.29193E-14 -14.5347 0.83668E+00 -0.0774 61 MgOH+ 0.68982E-10 -10.1613 0.57716E-10 -10.2387 0.83668E+00 -0.0774 63 MnO,aq 0.18051E-08 -8.7435 0.18051E-08 -8.7435 0.10000E+01 0.0000 64 MnOH+ 0.46827E-09 -9.3295 0.39180E-09 -9.4069 0.83668E+00 -0.0774 65 MnO2-2 0.20932E-10 -10.6792 0.10841E-10 -10.9649 0.51791E+00 -0.2857 66 HMnO2- 0.21142E-09 -9.6748 0.17655E-09 -9.7531 0.83508E+00 -0.0783 69 MnCl+ 0.12969E-13 -13.8871 0.10851E-13 -13.9645 0.83668E+00 -0.0774 71 NaCl,aq 0.10075E-05 -5.9967 0.10075E-05 -5.9967 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93244E-02 -2.0304 0.77725E-02 -2.1094 0.83357E+00 -0.0791 79 HPO3-2 0.16340E-14 -14.7867 0.84628E-15 -15.0725 0.51791E+00 -0.2857 81 H2PO3- 0.15106E-18 -18.8208 0.12615E-18 -18.8991 0.83508E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38463E-10 -10.4150 0.32150E-10 -10.4928 0.83587E+00 -0.0779 84 PO4-3 0.10618E-08 -8.9740 0.25733E-09 -9.5895 0.24236E+00 -0.6155 88 HP2O7-3 0.94259E-18 -18.0257 0.21771E-18 -18.6621 0.23097E+00 -0.6364 89 P2O7-4 0.90940E-17 -17.0412 0.69967E-18 -18.1551 0.76937E-01 -1.1139 90 H2S,aq 0.78322E-08 -8.1061 0.78050E-08 -8.1076 0.99653E+00 -0.0015 91 S2-2 0.42631E-14 -14.3703 0.22079E-14 -14.6560 0.51791E+00 -0.2857 97 SO3-2 0.15336E-17 -17.8143 0.80577E-18 -18.0938 0.52542E+00 -0.2795 99 HSO4- 0.45791E-19 -19.3392 0.38350E-19 -19.4162 0.83750E+00 -0.0770 Charge balance for all species = 0.8330E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8847990E-10 -.2226466E-01 -.2240239E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981975E+06 0.0000 3 Cl- 0.2190854E-03 0.2200934E-03 0.7789393E+01 6.3911 4 SO4-- 0.1031430E-11 -.2264861E-04 -.2171876E+01 7.9862 5 HCO3- 0.3816249E-06 0.2084897E-04 0.1269933E+01 3.6328 6 HS- 0.4067633E-04 0.6333277E-04 0.2090897E+01 5.6599 7 Al+++ 0.9760007E-29 0.5306446E-05 0.1429267E+00 0.7390 8 H4SiO4 0.6959742E-03 0.1351440E-01 0.1296682E+04 -3.1574 9 Ca++ 0.1355959E-06 0.2326252E-06 0.9306930E-02 13.1018 10 Mg++ 0.2121318E-10 0.9343246E-10 0.2267578E-05 9.2942 11 Fe++ 0.5846689E-13 0.3622466E-07 0.2019519E-02 6.7350 12 K+ 0.1568457E-03 0.1575999E-03 0.6151748E+01 6.2467 13 Na+ 0.1990299E-01 0.2234967E-01 0.5129203E+03 8.3494 14 Mn++ 0.1874441E-10 0.2524447E-08 0.1384468E-03 9.2413 15 HPO4-- 0.4516629E-07 0.4626653E-07 0.4432889E-02 12.6277 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6126648E+02 -.1395748E-01 -.6125252E+02 0.0000000E+00 2 H2O 0.9127245E+01 0.3479543E+02 -.2566818E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1025651E+00 -.1419817E-04 0.1025793E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1025396E+00 0.3970264E-04 -.1025793E+00 0.0000000E+00 7 Al+++ 0.1206474E+02 0.3326554E-05 0.1206474E+02 0.0000000E+00 8 H4SiO4 0.3852729E+02 0.8472034E-02 0.3851881E+02 0.0000000E+00 9 Ca++ 0.4255541E+01 0.1458302E-06 0.4255541E+01 0.0000000E+00 10 Mg++ 0.2936507E+01 0.5857181E-10 0.2936507E+01 0.0000000E+00 11 Fe++ 0.2638131E+01 0.2270885E-07 0.2638131E+01 0.0000000E+00 12 K+ 0.7855624E+00 0.9879768E-04 0.7854636E+00 0.0000000E+00 13 Na+ 0.4644560E+01 0.1401077E-01 0.4630549E+01 0.0000000E+00 14 Mn++ 0.6415279E-01 0.1582549E-08 0.6415279E-01 0.0000000E+00 15 HPO4-- 0.2189503E-01 0.2900399E-07 0.2189500E-01 0.0000000E+00 Chg. balance for solid moles: -.7279E-14 Mass of aqueous solution: 0.627982E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.627 0.665 1213. 3.084 30.01 465.7 andradite 0.4103 -0.387 208.5 2.319 5.159 54.17 grossular 0.9936E-01 -1.003 44.76 1.651 1.107 12.45 apatite-OH 0.7298E-02 -2.137 3.666 0.564 0.9070E-01 1.165 clinochlore 0.5260 -0.279 292.3 2.466 7.233 111.2 daphnite 0.1523 -0.817 108.6 2.036 2.688 32.92 chlorite-Mn 0.1283E-01 -1.892 9.096 0.959 0.2250 2.899 diopside 0.1920 -0.717 41.58 1.619 1.029 12.71 hedenbergite 0.4979E-01 -1.303 12.35 1.092 0.3056 3.383 microcline 0.6888 -0.162 191.7 2.283 4.743 74.89 stilbite 2.385 0.377 1681. 3.225 41.58 783.9 stilpnomelane-Fe 0.1934 -0.714 208.4 2.319 5.157 72.00 tr.625ac.25prg.125 0.3164E-01 -1.500 27.05 1.432 0.6691 8.705 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4042.079221 g Volume = 1636.138024 cm3 Porosity: -10.4753% V(tot) - V(min): -.15514E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3699.9990000 g log = 3.5682 Original solution: 1000.0103000 g Original solution / Rock added: 0.27 (Water/Rock Ratio), log = -0.5682 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0647 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9589E+00 0.9854 0.1006E+01 0.1021E+01 CO2,gas 0.5060E-08 1.0068 0.5424E-08 0.5387E-08 CH4,gas 0.2687E-01 1.0123 0.2896E-01 0.2861E-01 H2,gas 0.1427E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2023E-06 0.9959 0.2146E-06 0.2154E-06 S2,gas 0.7018E-29 1.0000 0.7472E-29 0.7472E-29 CO,gas 0.2064E-13 1.0000 0.2198E-13 0.2198E-13 SO3,gas 0.1050E-47 1.0000 0.1118E-47 0.1118E-47 SO2,gas 0.6215E-27 1.0000 0.6617E-27 0.6617E-27 HCl,gas 0.4130E-17 1.0000 0.4397E-17 0.4397E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.90992E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.62 -9.96 -3.322 0.17014E+05 -8.266 3 CH4,gas 4.54 1.31 -3.24 -0.809 0.55274E+04 -1.538 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.60 -8.37 -4.184 0.14287E+05 -6.668 6 S2,gas -7.34 -38.16 -30.83 -4.742 0.52634E+05 -29.127 7 CO,gas 3.21 -12.14 -15.36 -4.725 0.26222E+05 -13.658 8 SO3,gas 17.12 -32.53 -49.65 -12.413 0.84777E+05 -47.951 9 SO2,gas 0.83 -28.05 -28.88 -7.701 0.49309E+05 -27.179 10 HCl,gas 5.19 -13.87 -19.06 -9.528 0.32537E+05 -17.357 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80724E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.52 -4.49 -1.496 0.76657E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.52 -4.33 -1.445 0.74015E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65554E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.66 -4.56 -1.302 0.77805E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.66 -4.11 -1.175 0.70228E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82246E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.86 -3.60 -1.201 0.61510E+04 144 pyrrhotiteFe0.875 -6.02 -9.26 -3.24 -1.193 0.55382E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22450E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23252E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47136E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.86 -3.45 -1.151 0.58938E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79436E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.36 -4.38 -1.460 0.74762E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3699.9990000 g New total amount of reactant added: 3799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3799.9990000 Water: Moles liquid = 0.3424E+02 kg liquid = 0.6168E+00 Moles total = 0.7874E+01 kg total = 0.1418E+00 Activity = 1.0000 Stoichiometric ionic strength = .1138864E-01 Osmotic coef. = 0.9688 True ionic strength = .2006342E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88490E-10 -10.0531 0.74343E-10 -10.1288 0.84013E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.22265E-03 -3.6524 0.18593E-03 -3.7306 0.83507E+00 -0.0783 4 SO4-- 0.10481E-11 -11.9796 0.54399E-12 -12.2644 0.51900E+00 -0.2848 5 HCO3- 0.38780E-06 -6.4114 0.32432E-06 -6.4890 0.83630E+00 -0.0776 6 HS- 0.41339E-04 -4.3836 0.34526E-04 -4.4619 0.83520E+00 -0.0782 7 Al+++ 0.97638E-29 -29.0104 0.22527E-29 -29.6473 0.23072E+00 -0.6369 8 H4SiO4 0.69597E-03 -3.1574 0.69597E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13563E-06 -6.8676 0.69874E-07 -7.1557 0.51519E+00 -0.2880 10 Mg++ 0.21218E-10 -10.6733 0.10881E-10 -10.9633 0.51282E+00 -0.2900 11 Fe++ 0.58481E-13 -13.2330 0.30024E-13 -13.5225 0.51339E+00 -0.2896 12 K+ 0.15686E-03 -3.8045 0.13122E-03 -3.8820 0.83649E+00 -0.0775 13 Na+ 0.19905E-01 -1.7010 0.16619E-01 -1.7794 0.83492E+00 -0.0784 14 Mn++ 0.18750E-10 -10.7270 0.96341E-11 -11.0162 0.51381E+00 -0.2892 15 HPO4-- 0.45158E-07 -7.3453 0.23440E-07 -7.6300 0.51908E+00 -0.2848 16 HSiO3- 0.10468E-01 -1.9801 0.87413E-02 -2.0584 0.83507E+00 -0.0783 17 Ca(HSiO3)+ 0.16625E-07 -7.7792 0.13910E-07 -7.8567 0.83667E+00 -0.0774 18 Mg(HSiO3)+ 0.32221E-11 -11.4919 0.26958E-11 -11.5693 0.83667E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66274E-16 -16.1787 0.55450E-16 -16.2561 0.83667E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53058E-05 -5.2753 0.44227E-05 -5.3543 0.83356E+00 -0.0791 24 CH4,aq 0.20064E-04 -4.6976 0.19995E-04 -4.6991 0.99653E+00 -0.0015 25 C2H6,aq 0.59213E-14 -14.2276 0.59007E-14 -14.2291 0.99653E+00 -0.0015 29 CO,aq 0.14991E-16 -16.8242 0.14991E-16 -16.8242 0.10000E+01 0.0000 30 CO2,aq 0.51699E-10 -10.2865 0.51520E-10 -10.2880 0.99653E+00 -0.0015 31 CO3-2 0.73575E-06 -6.1333 0.38104E-06 -6.4190 0.51790E+00 -0.2858 32 CaCO3,aq 0.33385E-09 -9.4765 0.33385E-09 -9.4765 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69138E-12 -12.1603 0.57846E-12 -12.2377 0.83667E+00 -0.0774 34 CaCl+ 0.25129E-10 -10.5998 0.21025E-10 -10.6773 0.83667E+00 -0.0774 35 CaCl2,aq 0.92873E-15 -15.0321 0.92873E-15 -15.0321 0.10000E+01 0.0000 36 CaOH+ 0.80061E-07 -7.0966 0.66985E-07 -7.1740 0.83667E+00 -0.0774 37 CaSO4,aq 0.12070E-16 -16.9183 0.12070E-16 -16.9183 0.10000E+01 0.0000 38 HCl,aq 0.25330E-14 -14.5964 0.25330E-14 -14.5964 0.10000E+01 0.0000 43 FeCl+ 0.10561E-16 -16.9763 0.88358E-17 -17.0538 0.83667E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15712E-10 -10.8038 0.13146E-10 -10.8812 0.83667E+00 -0.0774 48 HFeO2- 0.35583E-07 -7.4488 0.29714E-07 -7.5270 0.83507E+00 -0.0783 49 FeO+ 0.11012E-16 -16.9582 0.92131E-17 -17.0356 0.83667E+00 -0.0774 51 FeO2- 0.40845E-09 -9.3889 0.34109E-09 -9.4671 0.83507E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.44218E-09 -9.3544 0.44218E-09 -9.3544 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.13264E-14 -14.8773 0.11076E-14 -14.9556 0.83507E+00 -0.0783 58 MgCO3,aq 0.13031E-13 -13.8850 0.13031E-13 -13.8850 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11002E-15 -15.9585 0.92047E-16 -16.0360 0.83667E+00 -0.0774 60 MgCl+ 0.35468E-14 -14.4502 0.29675E-14 -14.5276 0.83667E+00 -0.0774 61 MgOH+ 0.68990E-10 -10.1612 0.57722E-10 -10.2387 0.83667E+00 -0.0774 63 MnO,aq 0.18052E-08 -8.7435 0.18052E-08 -8.7435 0.10000E+01 0.0000 64 MnOH+ 0.46836E-09 -9.3294 0.39186E-09 -9.4069 0.83667E+00 -0.0774 65 MnO2-2 0.20930E-10 -10.6792 0.10839E-10 -10.9650 0.51790E+00 -0.2858 66 HMnO2- 0.21141E-09 -9.6749 0.17655E-09 -9.7531 0.83507E+00 -0.0783 69 MnCl+ 0.13184E-13 -13.8800 0.11031E-13 -13.9574 0.83667E+00 -0.0774 71 NaCl,aq 0.10240E-05 -5.9897 0.10240E-05 -5.9897 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93235E-02 -2.0304 0.77717E-02 -2.1095 0.83356E+00 -0.0791 79 HPO3-2 0.16337E-14 -14.7868 0.84610E-15 -15.0726 0.51790E+00 -0.2858 81 H2PO3- 0.15105E-18 -18.8209 0.12614E-18 -18.8992 0.83507E+00 -0.0783 82 H3PO4,aq 0.90609E-18 -18.0428 0.90609E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38460E-10 -10.4150 0.32147E-10 -10.4929 0.83587E+00 -0.0779 84 PO4-3 0.10615E-08 -8.9741 0.25725E-09 -9.5896 0.24235E+00 -0.6156 88 HP2O7-3 0.94236E-18 -18.0258 0.21764E-18 -18.6623 0.23095E+00 -0.6365 89 P2O7-4 0.90912E-17 -17.0414 0.69937E-18 -18.1553 0.76928E-01 -1.1139 90 H2S,aq 0.79605E-08 -8.0991 0.79329E-08 -8.1006 0.99653E+00 -0.0015 91 S2-2 0.44031E-14 -14.3562 0.22804E-14 -14.6420 0.51790E+00 -0.2858 97 SO3-2 0.15584E-17 -17.8073 0.81879E-18 -18.0868 0.52540E+00 -0.2795 99 HSO4- 0.46537E-19 -19.3322 0.38974E-19 -19.4092 0.83749E+00 -0.0770 Charge balance for all species = 0.8466E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8849000E-10 -.2226271E-01 -.2240043E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981974E+06 0.0000 3 Cl- 0.2226521E-03 0.2236766E-03 0.7916208E+01 6.3981 4 SO4-- 0.1048141E-11 -.2297019E-04 -.2202714E+01 7.9931 5 HCO3- 0.3878049E-06 0.2118841E-04 0.1290608E+01 3.6397 6 HS- 0.4133857E-04 0.6431672E-04 0.2123381E+01 5.6669 7 Al+++ 0.9763793E-29 0.5305908E-05 0.1429122E+00 0.7390 8 H4SiO4 0.6959747E-03 0.1351337E-01 0.1296583E+04 -3.1574 9 Ca++ 0.1356290E-06 0.2326751E-06 0.9308925E-02 13.1018 10 Mg++ 0.2121836E-10 0.9344749E-10 0.2267942E-05 9.2942 11 Fe++ 0.5848121E-13 0.3622108E-07 0.2019319E-02 6.7350 12 K+ 0.1568637E-03 0.1576179E-03 0.6152449E+01 6.2467 13 Na+ 0.1990527E-01 0.2235197E-01 0.5129731E+03 8.3494 14 Mn++ 0.1875018E-10 0.2524640E-08 0.1384573E-03 9.2413 15 HPO4-- 0.4515804E-07 0.4625801E-07 0.4432072E-02 12.6275 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6292233E+02 -.1373268E-01 -.6290860E+02 0.0000000E+00 2 H2O 0.7873704E+01 0.3423801E+02 -.2636431E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1053364E+00 -.1416909E-04 0.1053506E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1053109E+00 0.3967356E-04 -.1053506E+00 0.0000000E+00 7 Al+++ 0.1239081E+02 0.3272932E-05 0.1239081E+02 0.0000000E+00 8 H4SiO4 0.3956856E+02 0.8335679E-02 0.3956023E+02 0.0000000E+00 9 Ca++ 0.4370555E+01 0.1435248E-06 0.4370555E+01 0.0000000E+00 10 Mg++ 0.3015872E+01 0.5764278E-10 0.3015872E+01 0.0000000E+00 11 Fe++ 0.2709432E+01 0.2234285E-07 0.2709432E+01 0.0000000E+00 12 K+ 0.8067938E+00 0.9722606E-04 0.8066966E+00 0.0000000E+00 13 Na+ 0.4770085E+01 0.1378774E-01 0.4756297E+01 0.0000000E+00 14 Mn++ 0.6588665E-01 0.1557316E-08 0.6588665E-01 0.0000000E+00 15 HPO4-- 0.2248679E-01 0.2853410E-07 0.2248676E-01 0.0000000E+00 Chg. balance for solid moles: -.1953E-13 Mass of aqueous solution: 0.617922E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.752 0.677 1246. 3.096 30.02 478.4 andradite 0.4214 -0.375 214.1 2.331 5.159 55.64 grossular 0.1020 -0.991 45.96 1.662 1.107 12.79 apatite-OH 0.7496E-02 -2.125 3.765 0.576 0.9070E-01 1.196 clinochlore 0.5401 -0.267 300.2 2.477 7.232 114.2 daphnite 0.1564 -0.806 111.6 2.048 2.688 33.81 chlorite-Mn 0.1318E-01 -1.880 9.342 0.970 0.2250 2.977 diopside 0.1974 -0.705 42.75 1.631 1.030 13.07 hedenbergite 0.5120E-01 -1.291 12.70 1.104 0.3060 3.479 microcline 0.7074 -0.150 196.9 2.294 4.743 76.91 stilbite 2.449 0.389 1726. 3.237 41.58 805.0 stilpnomelane-Fe 0.1986 -0.702 214.1 2.331 5.157 73.95 tr.625ac.25prg.125 0.3248E-01 -1.488 27.76 1.443 0.6687 8.935 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4151.329885 g Volume = 1680.341088 cm3 Porosity: -10.4761% V(tot) - V(min): -.15934E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3799.9990000 g log = 3.5798 Original solution: 1000.0103000 g Original solution / Rock added: 0.26 (Water/Rock Ratio), log = -0.5798 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0652 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9584E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5140E-08 1.0068 0.5512E-08 0.5475E-08 CH4,gas 0.2729E-01 1.0123 0.2943E-01 0.2907E-01 H2,gas 0.1427E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2056E-06 0.9959 0.2181E-06 0.2190E-06 S2,gas 0.7247E-29 1.0000 0.7719E-29 0.7719E-29 CO,gas 0.2097E-13 1.0000 0.2234E-13 0.2234E-13 SO3,gas 0.1067E-47 1.0000 0.1137E-47 0.1137E-47 SO2,gas 0.6314E-27 1.0000 0.6726E-27 0.6726E-27 HCl,gas 0.4196E-17 1.0000 0.4469E-17 0.4469E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.62 -9.96 -3.319 0.17002E+05 -8.259 3 CH4,gas 4.54 1.31 -3.23 -0.808 0.55154E+04 -1.531 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.59 -8.36 -4.180 0.14275E+05 -6.661 6 S2,gas -7.34 -38.15 -30.81 -4.740 0.52610E+05 -29.112 7 CO,gas 3.21 -12.13 -15.35 -4.723 0.26210E+05 -13.651 8 SO3,gas 17.12 -32.52 -49.64 -12.411 0.84765E+05 -47.944 9 SO2,gas 0.83 -28.04 -28.87 -7.699 0.49297E+05 -27.172 10 HCl,gas 5.19 -13.86 -19.05 -9.524 0.32525E+05 -17.350 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80723E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93624E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.52 -4.48 -1.494 0.76537E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.52 -4.33 -1.443 0.73895E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82206E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65553E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.65 -4.55 -1.300 0.77686E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.65 -4.11 -1.173 0.70108E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82245E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.86 -3.60 -1.198 0.61389E+04 144 pyrrhotiteFe0.875 -6.02 -9.25 -3.24 -1.190 0.55261E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22449E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23252E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47136E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.86 -3.44 -1.148 0.58817E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34154E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.35 -4.37 -1.457 0.74641E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3799.9990000 g New total amount of reactant added: 3899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3899.9990000 Water: Moles liquid = 0.3368E+02 kg liquid = 0.6068E+00 Moles total = 0.6620E+01 kg total = 0.1193E+00 Activity = 1.0000 Stoichiometric ionic strength = .1139171E-01 Osmotic coef. = 0.9688 True ionic strength = .2006581E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88500E-10 -10.0531 0.74352E-10 -10.1287 0.84013E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.22634E-03 -3.6452 0.18901E-03 -3.7235 0.83507E+00 -0.0783 4 SO4-- 0.10654E-11 -11.9725 0.55293E-12 -12.2573 0.51899E+00 -0.2848 5 HCO3- 0.39419E-06 -6.4043 0.32966E-06 -6.4819 0.83629E+00 -0.0776 6 HS- 0.42023E-04 -4.3765 0.35097E-04 -4.4547 0.83519E+00 -0.0782 7 Al+++ 0.97677E-29 -29.0102 0.22535E-29 -29.6472 0.23070E+00 -0.6369 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13566E-06 -6.8675 0.69890E-07 -7.1556 0.51517E+00 -0.2880 10 Mg++ 0.21224E-10 -10.6732 0.10884E-10 -10.9632 0.51281E+00 -0.2900 11 Fe++ 0.58496E-13 -13.2329 0.30030E-13 -13.5224 0.51337E+00 -0.2896 12 K+ 0.15688E-03 -3.8044 0.13123E-03 -3.8820 0.83649E+00 -0.0775 13 Na+ 0.19908E-01 -1.7010 0.16621E-01 -1.7793 0.83491E+00 -0.0784 14 Mn++ 0.18756E-10 -10.7269 0.96368E-11 -11.0161 0.51380E+00 -0.2892 15 HPO4-- 0.45150E-07 -7.3453 0.23435E-07 -7.6301 0.51906E+00 -0.2848 16 HSiO3- 0.10467E-01 -1.9802 0.87404E-02 -2.0585 0.83507E+00 -0.0783 17 Ca(HSiO3)+ 0.16627E-07 -7.7792 0.13912E-07 -7.8566 0.83667E+00 -0.0774 18 Mg(HSiO3)+ 0.32225E-11 -11.4918 0.26961E-11 -11.5693 0.83667E+00 -0.0774 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66281E-16 -16.1786 0.55456E-16 -16.2561 0.83667E+00 -0.0774 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53052E-05 -5.2753 0.44222E-05 -5.3544 0.83356E+00 -0.0791 24 CH4,aq 0.20397E-04 -4.6904 0.20326E-04 -4.6920 0.99653E+00 -0.0015 25 C2H6,aq 0.61190E-14 -14.2133 0.60978E-14 -14.2148 0.99653E+00 -0.0015 29 CO,aq 0.15239E-16 -16.8170 0.15239E-16 -16.8170 0.10000E+01 0.0000 30 CO2,aq 0.52556E-10 -10.2794 0.52373E-10 -10.2809 0.99653E+00 -0.0015 31 CO3-2 0.74779E-06 -6.1262 0.38727E-06 -6.4120 0.51788E+00 -0.2858 32 CaCO3,aq 0.33938E-09 -9.4693 0.33938E-09 -9.4693 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.70291E-12 -12.1531 0.58811E-12 -12.2305 0.83667E+00 -0.0774 34 CaCl+ 0.25550E-10 -10.5926 0.21377E-10 -10.6700 0.83667E+00 -0.0774 35 CaCl2,aq 0.95992E-15 -15.0178 0.95992E-15 -15.0178 0.10000E+01 0.0000 36 CaOH+ 0.80070E-07 -7.0965 0.66992E-07 -7.1740 0.83667E+00 -0.0774 37 CaSO4,aq 0.12271E-16 -16.9111 0.12271E-16 -16.9111 0.10000E+01 0.0000 38 HCl,aq 0.25751E-14 -14.5892 0.25751E-14 -14.5892 0.10000E+01 0.0000 43 FeCl+ 0.10738E-16 -16.9691 0.89840E-17 -17.0465 0.83667E+00 -0.0774 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15714E-10 -10.8037 0.13147E-10 -10.8812 0.83667E+00 -0.0774 48 HFeO2- 0.35579E-07 -7.4488 0.29711E-07 -7.5271 0.83507E+00 -0.0783 49 FeO+ 0.11013E-16 -16.9581 0.92141E-17 -17.0355 0.83667E+00 -0.0774 51 FeO2- 0.40841E-09 -9.3889 0.34105E-09 -9.4672 0.83507E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.44954E-09 -9.3472 0.44954E-09 -9.3472 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.13484E-14 -14.8702 0.11260E-14 -14.9485 0.83507E+00 -0.0783 58 MgCO3,aq 0.13247E-13 -13.8779 0.13247E-13 -13.8779 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11185E-15 -15.9514 0.93582E-16 -16.0288 0.83667E+00 -0.0774 60 MgCl+ 0.36062E-14 -14.4429 0.30172E-14 -14.5204 0.83667E+00 -0.0774 61 MgOH+ 0.68998E-10 -10.1612 0.57728E-10 -10.2386 0.83667E+00 -0.0774 63 MnO,aq 0.18053E-08 -8.7435 0.18053E-08 -8.7435 0.10000E+01 0.0000 64 MnOH+ 0.46844E-09 -9.3293 0.39193E-09 -9.4068 0.83667E+00 -0.0774 65 MnO2-2 0.20927E-10 -10.6793 0.10838E-10 -10.9651 0.51788E+00 -0.2858 66 HMnO2- 0.21141E-09 -9.6749 0.17654E-09 -9.7532 0.83507E+00 -0.0783 69 MnCl+ 0.13406E-13 -13.8727 0.11216E-13 -13.9502 0.83667E+00 -0.0774 71 NaCl,aq 0.10411E-05 -5.9825 0.10411E-05 -5.9825 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93225E-02 -2.0305 0.77708E-02 -2.1095 0.83356E+00 -0.0791 79 HPO3-2 0.16334E-14 -14.7869 0.84591E-15 -15.0727 0.51788E+00 -0.2858 81 H2PO3- 0.15103E-18 -18.8209 0.12612E-18 -18.8992 0.83507E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38456E-10 -10.4150 0.32144E-10 -10.4929 0.83586E+00 -0.0779 84 PO4-3 0.10612E-08 -8.9742 0.25717E-09 -9.5898 0.24233E+00 -0.6156 88 HP2O7-3 0.94211E-18 -18.0259 0.21757E-18 -18.6624 0.23094E+00 -0.6365 89 P2O7-4 0.90884E-17 -17.0415 0.69906E-18 -18.1555 0.76918E-01 -1.1140 90 H2S,aq 0.80931E-08 -8.0919 0.80650E-08 -8.0934 0.99653E+00 -0.0015 91 S2-2 0.45502E-14 -14.3420 0.23565E-14 -14.6277 0.51788E+00 -0.2858 97 SO3-2 0.15841E-17 -17.8002 0.83225E-18 -18.0797 0.52539E+00 -0.2795 99 HSO4- 0.47308E-19 -19.3251 0.39619E-19 -19.4021 0.83748E+00 -0.0770 Charge balance for all species = 0.8600E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8850044E-10 -.2226070E-01 -.2239841E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981973E+06 0.0000 3 Cl- 0.2263369E-03 0.2273785E-03 0.8047221E+01 6.4052 4 SO4-- 0.1065402E-11 -.2330242E-04 -.2234573E+01 8.0001 5 HCO3- 0.3941881E-06 0.2153908E-04 0.1311967E+01 3.6468 6 HS- 0.4202272E-04 0.6533324E-04 0.2156941E+01 5.6740 7 Al+++ 0.9767706E-29 0.5305353E-05 0.1428973E+00 0.7390 8 H4SiO4 0.6959752E-03 0.1351231E-01 0.1296481E+04 -3.1574 9 Ca++ 0.1356632E-06 0.2327266E-06 0.9310987E-02 13.1018 10 Mg++ 0.2122372E-10 0.9346083E-10 0.2268266E-05 9.2942 11 Fe++ 0.5849601E-13 0.3621738E-07 0.2019112E-02 6.7350 12 K+ 0.1568822E-03 0.1576364E-03 0.6153174E+01 6.2467 13 Na+ 0.1990763E-01 0.2235435E-01 0.5130276E+03 8.3494 14 Mn++ 0.1875605E-10 0.2524825E-08 0.1384675E-03 9.2414 15 HPO4-- 0.4514952E-07 0.4624920E-07 0.4431227E-02 12.6273 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6457818E+02 -.1350789E-01 -.6456467E+02 0.0000000E+00 2 H2O 0.6620163E+01 0.3368060E+02 -.2706043E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1081078E+00 -.1414000E-04 0.1081219E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1080823E+00 0.3964447E-04 -.1081219E+00 0.0000000E+00 7 Al+++ 0.1271689E+02 0.3219310E-05 0.1271689E+02 0.0000000E+00 8 H4SiO4 0.4060984E+02 0.8199324E-02 0.4060164E+02 0.0000000E+00 9 Ca++ 0.4485570E+01 0.1412195E-06 0.4485570E+01 0.0000000E+00 10 Mg++ 0.3095237E+01 0.5671241E-10 0.3095237E+01 0.0000000E+00 11 Fe++ 0.2780733E+01 0.2197685E-07 0.2780733E+01 0.0000000E+00 12 K+ 0.8280253E+00 0.9565443E-04 0.8279296E+00 0.0000000E+00 13 Na+ 0.4895609E+01 0.1356471E-01 0.4882044E+01 0.0000000E+00 14 Mn++ 0.6762051E-01 0.1532074E-08 0.6762051E-01 0.0000000E+00 15 HPO4-- 0.2307854E-01 0.2806420E-07 0.2307851E-01 0.0000000E+00 Chg. balance for solid moles: 0.1665E-15 Mass of aqueous solution: 0.607862E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.878 0.688 1279. 3.107 30.02 491.0 andradite 0.4325 -0.364 219.8 2.342 5.158 57.10 grossular 0.1047 -0.980 47.17 1.674 1.107 13.13 apatite-OH 0.7693E-02 -2.114 3.864 0.587 0.9070E-01 1.228 clinochlore 0.5543 -0.256 308.1 2.489 7.232 117.2 daphnite 0.1605 -0.795 114.5 2.059 2.687 34.70 chlorite-Mn 0.1352E-01 -1.869 9.588 0.982 0.2250 3.056 diopside 0.2029 -0.693 43.93 1.643 1.031 13.43 hedenbergite 0.5261E-01 -1.279 13.05 1.116 0.3064 3.575 microcline 0.7260 -0.139 202.1 2.306 4.743 78.94 stilbite 2.513 0.400 1771. 3.248 41.57 826.1 stilpnomelane-Fe 0.2038 -0.691 219.7 2.342 5.157 75.90 tr.625ac.25prg.125 0.3331E-01 -1.477 28.47 1.454 0.6683 9.164 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4260.580550 g Volume = 1724.544153 cm3 Porosity: -10.4769% V(tot) - V(min): -.16354E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3899.9990000 g log = 3.5911 Original solution: 1000.0103000 g Original solution / Rock added: 0.26 (Water/Rock Ratio), log = -0.5911 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0657 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9580E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5223E-08 1.0068 0.5603E-08 0.5566E-08 CH4,gas 0.2773E-01 1.0123 0.2992E-01 0.2955E-01 H2,gas 0.1426E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2089E-06 0.9959 0.2217E-06 0.2226E-06 S2,gas 0.7487E-29 1.0000 0.7978E-29 0.7978E-29 CO,gas 0.2131E-13 1.0000 0.2271E-13 0.2271E-13 SO3,gas 0.1085E-47 1.0000 0.1156E-47 0.1156E-47 SO2,gas 0.6416E-27 1.0000 0.6838E-27 0.6838E-27 HCl,gas 0.4264E-17 1.0000 0.4544E-17 0.4544E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.61 -9.95 -3.317 0.16990E+05 -8.252 3 CH4,gas 4.54 1.32 -3.22 -0.806 0.55032E+04 -1.524 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.58 -8.35 -4.177 0.14263E+05 -6.654 6 S2,gas -7.34 -38.13 -30.80 -4.738 0.52585E+05 -29.098 7 CO,gas 3.21 -12.13 -15.34 -4.721 0.26197E+05 -13.644 8 SO3,gas 17.12 -32.51 -49.64 -12.409 0.84752E+05 -47.937 9 SO2,gas 0.83 -28.03 -28.86 -7.697 0.49285E+05 -27.165 10 HCl,gas 5.19 -13.85 -19.04 -9.521 0.32513E+05 -17.343 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80721E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.51 -4.48 -1.492 0.76415E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.51 -4.32 -1.440 0.73773E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65553E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.64 -4.54 -1.298 0.77564E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.64 -4.10 -1.171 0.69986E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82245E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.85 -3.59 -1.196 0.61267E+04 144 pyrrhotiteFe0.875 -6.02 -9.25 -3.23 -1.188 0.55139E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22449E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23251E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47135E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.85 -3.44 -1.146 0.58695E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.34 -4.36 -1.455 0.74518E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3899.9990000 g New total amount of reactant added: 3999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 3999.9990000 Water: Moles liquid = 0.3313E+02 kg liquid = 0.5968E+00 Moles total = 0.5367E+01 kg total = 0.9668E-01 Activity = 1.0000 Stoichiometric ionic strength = .1139488E-01 Osmotic coef. = 0.9687 True ionic strength = .2006829E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88511E-10 -10.0530 0.74360E-10 -10.1287 0.84012E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23015E-03 -3.6380 0.19219E-03 -3.7163 0.83506E+00 -0.0783 4 SO4-- 0.10832E-11 -11.9653 0.56217E-12 -12.2501 0.51897E+00 -0.2849 5 HCO3- 0.40078E-06 -6.3971 0.33517E-06 -6.4747 0.83628E+00 -0.0776 6 HS- 0.42730E-04 -4.3693 0.35687E-04 -4.4475 0.83518E+00 -0.0782 7 Al+++ 0.97718E-29 -29.0100 0.22542E-29 -29.6470 0.23069E+00 -0.6370 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13570E-06 -6.8674 0.69905E-07 -7.1555 0.51515E+00 -0.2881 10 Mg++ 0.21229E-10 -10.6731 0.10886E-10 -10.9631 0.51279E+00 -0.2901 11 Fe++ 0.58511E-13 -13.2328 0.30037E-13 -13.5223 0.51335E+00 -0.2896 12 K+ 0.15690E-03 -3.8044 0.13125E-03 -3.8819 0.83648E+00 -0.0775 13 Na+ 0.19910E-01 -1.7009 0.16623E-01 -1.7793 0.83491E+00 -0.0784 14 Mn++ 0.18762E-10 -10.7267 0.96396E-11 -11.0159 0.51378E+00 -0.2892 15 HPO4-- 0.45141E-07 -7.3454 0.23430E-07 -7.6302 0.51904E+00 -0.2848 16 HSiO3- 0.10466E-01 -1.9802 0.87394E-02 -2.0585 0.83506E+00 -0.0783 17 Ca(HSiO3)+ 0.16629E-07 -7.7791 0.13913E-07 -7.8566 0.83666E+00 -0.0775 18 Mg(HSiO3)+ 0.32229E-11 -11.4918 0.26964E-11 -11.5692 0.83666E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66289E-16 -16.1786 0.55462E-16 -16.2560 0.83666E+00 -0.0775 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53046E-05 -5.2753 0.44217E-05 -5.3544 0.83355E+00 -0.0791 24 CH4,aq 0.20740E-04 -4.6832 0.20668E-04 -4.6847 0.99653E+00 -0.0015 25 C2H6,aq 0.63268E-14 -14.1988 0.63048E-14 -14.2003 0.99653E+00 -0.0015 29 CO,aq 0.15495E-16 -16.8098 0.15495E-16 -16.8098 0.10000E+01 0.0000 30 CO2,aq 0.53441E-10 -10.2721 0.53255E-10 -10.2736 0.99653E+00 -0.0015 31 CO3-2 0.76024E-06 -6.1190 0.39370E-06 -6.4048 0.51787E+00 -0.2858 32 CaCO3,aq 0.34509E-09 -9.4621 0.34509E-09 -9.4621 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.71484E-12 -12.1458 0.59808E-12 -12.2232 0.83666E+00 -0.0775 34 CaCl+ 0.25986E-10 -10.5853 0.21742E-10 -10.6627 0.83666E+00 -0.0775 35 CaCl2,aq 0.99271E-15 -15.0032 0.99271E-15 -15.0032 0.10000E+01 0.0000 36 CaOH+ 0.80080E-07 -7.0965 0.67000E-07 -7.1739 0.83666E+00 -0.0775 37 CaSO4,aq 0.12479E-16 -16.9038 0.12479E-16 -16.9038 0.10000E+01 0.0000 38 HCl,aq 0.26187E-14 -14.5819 0.26187E-14 -14.5819 0.10000E+01 0.0000 43 FeCl+ 0.10921E-16 -16.9617 0.91372E-17 -17.0392 0.83666E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15716E-10 -10.8037 0.13149E-10 -10.8811 0.83666E+00 -0.0775 48 HFeO2- 0.35575E-07 -7.4489 0.29707E-07 -7.5271 0.83506E+00 -0.0783 49 FeO+ 0.11014E-16 -16.9580 0.92151E-17 -17.0355 0.83666E+00 -0.0775 51 FeO2- 0.40837E-09 -9.3889 0.34101E-09 -9.4672 0.83506E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99653E+00 -0.0015 54 KCl,aq 0.45715E-09 -9.3399 0.45715E-09 -9.3399 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.13711E-14 -14.8629 0.11449E-14 -14.9412 0.83506E+00 -0.0783 58 MgCO3,aq 0.13470E-13 -13.8706 0.13470E-13 -13.8706 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11375E-15 -15.9441 0.95169E-16 -16.0215 0.83666E+00 -0.0775 60 MgCl+ 0.36678E-14 -14.4356 0.30687E-14 -14.5130 0.83666E+00 -0.0775 61 MgOH+ 0.69006E-10 -10.1611 0.57735E-10 -10.2386 0.83666E+00 -0.0775 63 MnO,aq 0.18054E-08 -8.7434 0.18054E-08 -8.7434 0.10000E+01 0.0000 64 MnOH+ 0.46852E-09 -9.3293 0.39200E-09 -9.4067 0.83666E+00 -0.0775 65 MnO2-2 0.20924E-10 -10.6794 0.10836E-10 -10.9651 0.51787E+00 -0.2858 66 HMnO2- 0.21139E-09 -9.6749 0.17653E-09 -9.7532 0.83506E+00 -0.0783 69 MnCl+ 0.13635E-13 -13.8653 0.11408E-13 -13.9428 0.83666E+00 -0.0775 71 NaCl,aq 0.10587E-05 -5.9752 0.10587E-05 -5.9752 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93215E-02 -2.0305 0.77699E-02 -2.1096 0.83355E+00 -0.0791 79 HPO3-2 0.16331E-14 -14.7870 0.84572E-15 -15.0728 0.51787E+00 -0.2858 81 H2PO3- 0.15102E-18 -18.8210 0.12611E-18 -18.8993 0.83506E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38452E-10 -10.4151 0.32140E-10 -10.4930 0.83585E+00 -0.0779 84 PO4-3 0.10609E-08 -8.9743 0.25708E-09 -9.5899 0.24231E+00 -0.6156 88 HP2O7-3 0.94186E-18 -18.0260 0.21749E-18 -18.6626 0.23092E+00 -0.6365 89 P2O7-4 0.90854E-17 -17.0417 0.69874E-18 -18.1557 0.76908E-01 -1.1140 90 H2S,aq 0.82302E-08 -8.0846 0.82016E-08 -8.0861 0.99653E+00 -0.0015 91 S2-2 0.47047E-14 -14.3275 0.24364E-14 -14.6133 0.51787E+00 -0.2858 97 SO3-2 0.16106E-17 -17.7930 0.84616E-18 -18.0725 0.52537E+00 -0.2795 99 HSO4- 0.48104E-19 -19.3178 0.40286E-19 -19.3948 0.83748E+00 -0.0770 Charge balance for all species = 0.8749E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8851124E-10 -.2225863E-01 -.2239632E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981972E+06 0.0000 3 Cl- 0.2301457E-03 0.2312049E-03 0.8182643E+01 6.4124 4 SO4-- 0.1083240E-11 -.2364584E-04 -.2267504E+01 8.0072 5 HCO3- 0.4007848E-06 0.2190155E-04 0.1334046E+01 3.6539 6 HS- 0.4272990E-04 0.6638398E-04 0.2191630E+01 5.6812 7 Al+++ 0.9771755E-29 0.5304781E-05 0.1428819E+00 0.7390 8 H4SiO4 0.6959756E-03 0.1351121E-01 0.1296375E+04 -3.1574 9 Ca++ 0.1356986E-06 0.2327799E-06 0.9313118E-02 13.1018 10 Mg++ 0.2122927E-10 0.9347610E-10 0.2268636E-05 9.2942 11 Fe++ 0.5851130E-13 0.3621356E-07 0.2018899E-02 6.7350 12 K+ 0.1569014E-03 0.1576556E-03 0.6153922E+01 6.2467 13 Na+ 0.1991007E-01 0.2235680E-01 0.5130840E+03 8.3494 14 Mn++ 0.1876203E-10 0.2525005E-08 0.1384773E-03 9.2414 15 HPO4-- 0.4514071E-07 0.4624009E-07 0.4430354E-02 12.6271 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6623403E+02 -.1328309E-01 -.6622075E+02 0.0000000E+00 2 H2O 0.5366622E+01 0.3312318E+02 -.2775656E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1108791E+00 -.1411093E-04 0.1108932E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108536E+00 0.3961540E-04 -.1108932E+00 0.0000000E+00 7 Al+++ 0.1304296E+02 0.3165689E-05 0.1304296E+02 0.0000000E+00 8 H4SiO4 0.4165112E+02 0.8062968E-02 0.4164306E+02 0.0000000E+00 9 Ca++ 0.4600584E+01 0.1389141E-06 0.4600584E+01 0.0000000E+00 10 Mg++ 0.3174602E+01 0.5578293E-10 0.3174602E+01 0.0000000E+00 11 Fe++ 0.2852034E+01 0.2161085E-07 0.2852034E+01 0.0000000E+00 12 K+ 0.8492567E+00 0.9408281E-04 0.8491626E+00 0.0000000E+00 13 Na+ 0.5021133E+01 0.1334168E-01 0.5007792E+01 0.0000000E+00 14 Mn++ 0.6935437E-01 0.1506825E-08 0.6935437E-01 0.0000000E+00 15 HPO4-- 0.2367030E-01 0.2759431E-07 0.2367027E-01 0.0000000E+00 Chg. balance for solid moles: 0.1098E-13 Mass of aqueous solution: 0.597802E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 3999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.004 0.699 1312. 3.118 30.02 503.7 andradite 0.4436 -0.353 225.4 2.353 5.158 58.56 grossular 0.1074 -0.969 48.38 1.685 1.107 13.46 apatite-OH 0.7890E-02 -2.103 3.963 0.598 0.9070E-01 1.259 clinochlore 0.5685 -0.245 316.0 2.500 7.231 120.2 daphnite 0.1646 -0.784 117.4 2.070 2.687 35.58 chlorite-Mn 0.1387E-01 -1.858 9.834 0.993 0.2250 3.134 diopside 0.2083 -0.681 45.11 1.654 1.032 13.79 hedenbergite 0.5402E-01 -1.267 13.40 1.127 0.3067 3.671 microcline 0.7446 -0.128 207.3 2.317 4.743 80.96 stilbite 2.578 0.411 1816. 3.259 41.57 847.2 stilpnomelane-Fe 0.2091 -0.680 225.4 2.353 5.157 77.85 tr.625ac.25prg.125 0.3414E-01 -1.467 29.18 1.465 0.6679 9.393 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4369.831215 g Volume = 1768.747217 cm3 Porosity: -10.4777% V(tot) - V(min): -.16775E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3999.9990000 g log = 3.6021 Original solution: 1000.0103000 g Original solution / Rock added: 0.25 (Water/Rock Ratio), log = -0.6021 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0662 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9576E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5308E-08 1.0068 0.5698E-08 0.5659E-08 CH4,gas 0.2819E-01 1.0123 0.3042E-01 0.3005E-01 H2,gas 0.1425E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2123E-06 0.9959 0.2255E-06 0.2264E-06 S2,gas 0.7739E-29 1.0000 0.8251E-29 0.8251E-29 CO,gas 0.2166E-13 1.0000 0.2309E-13 0.2309E-13 SO3,gas 0.1102E-47 1.0000 0.1175E-47 0.1175E-47 SO2,gas 0.6522E-27 1.0000 0.6953E-27 0.6953E-27 HCl,gas 0.4334E-17 1.0000 0.4621E-17 0.4621E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.36397E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.00000E+00 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.60 -9.94 -3.314 0.16978E+05 -8.244 3 CH4,gas 4.54 1.33 -3.22 -0.804 0.54909E+04 -1.517 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.58 -8.35 -4.173 0.14250E+05 -6.647 6 S2,gas -7.34 -38.12 -30.78 -4.736 0.52560E+05 -29.083 7 CO,gas 3.21 -12.12 -15.34 -4.719 0.26185E+05 -13.637 8 SO3,gas 17.12 -32.51 -49.63 -12.407 0.84740E+05 -47.930 9 SO2,gas 0.83 -28.02 -28.86 -7.695 0.49272E+05 -27.158 10 HCl,gas 5.19 -13.84 -19.03 -9.517 0.32500E+05 -17.335 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80720E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.50 -4.47 -1.489 0.76291E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.50 -4.31 -1.438 0.73649E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65552E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.64 -4.54 -1.296 0.77440E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.64 -4.09 -1.169 0.69862E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82244E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.84 -3.58 -1.194 0.61142E+04 144 pyrrhotiteFe0.875 -6.02 -9.24 -3.22 -1.185 0.55014E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22448E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28681E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23251E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47134E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65449E+04 181 troilite-low -4.41 -7.84 -3.43 -1.143 0.58570E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.33 -4.36 -1.452 0.74393E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3999.9990000 g New total amount of reactant added: 4099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4099.9990000 Water: Moles liquid = 0.3257E+02 kg liquid = 0.5867E+00 Moles total = 0.4113E+01 kg total = 0.7410E-01 Activity = 1.0000 Stoichiometric ionic strength = .1139816E-01 Osmotic coef. = 0.9687 True ionic strength = .2007084E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88522E-10 -10.0529 0.74369E-10 -10.1286 0.84011E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23408E-03 -3.6306 0.19547E-03 -3.7089 0.83505E+00 -0.0783 4 SO4-- 0.11017E-11 -11.9579 0.57172E-12 -12.2428 0.51895E+00 -0.2849 5 HCO3- 0.40761E-06 -6.3898 0.34087E-06 -6.4674 0.83628E+00 -0.0777 6 HS- 0.43461E-04 -4.3619 0.36298E-04 -4.4401 0.83517E+00 -0.0782 7 Al+++ 0.97759E-29 -29.0098 0.22550E-29 -29.6468 0.23067E+00 -0.6370 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13574E-06 -6.8673 0.69922E-07 -7.1554 0.51513E+00 -0.2881 10 Mg++ 0.21235E-10 -10.6729 0.10889E-10 -10.9630 0.51277E+00 -0.2901 11 Fe++ 0.58527E-13 -13.2326 0.30044E-13 -13.5222 0.51334E+00 -0.2896 12 K+ 0.15692E-03 -3.8043 0.13126E-03 -3.8819 0.83647E+00 -0.0775 13 Na+ 0.19913E-01 -1.7009 0.16625E-01 -1.7792 0.83490E+00 -0.0784 14 Mn++ 0.18768E-10 -10.7266 0.96424E-11 -11.0158 0.51376E+00 -0.2892 15 HPO4-- 0.45132E-07 -7.3455 0.23424E-07 -7.6303 0.51903E+00 -0.2848 16 HSiO3- 0.10464E-01 -1.9803 0.87384E-02 -2.0586 0.83505E+00 -0.0783 17 Ca(HSiO3)+ 0.16632E-07 -7.7791 0.13915E-07 -7.8565 0.83665E+00 -0.0775 18 Mg(HSiO3)+ 0.32233E-11 -11.4917 0.26968E-11 -11.5692 0.83665E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66298E-16 -16.1785 0.55468E-16 -16.2560 0.83665E+00 -0.0775 22 HAlO2,aq 0.14854E-09 -9.8282 0.14854E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53040E-05 -5.2754 0.44211E-05 -5.3545 0.83354E+00 -0.0791 24 CH4,aq 0.21095E-04 -4.6758 0.21022E-04 -4.6773 0.99652E+00 -0.0015 25 C2H6,aq 0.65454E-14 -14.1841 0.65226E-14 -14.1856 0.99652E+00 -0.0015 29 CO,aq 0.15761E-16 -16.8024 0.15761E-16 -16.8024 0.10000E+01 0.0000 30 CO2,aq 0.54356E-10 -10.2648 0.54167E-10 -10.2663 0.99652E+00 -0.0015 31 CO3-2 0.77311E-06 -6.1118 0.40035E-06 -6.3976 0.51785E+00 -0.2858 32 CaCO3,aq 0.35101E-09 -9.4547 0.35101E-09 -9.4547 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.72718E-12 -12.1384 0.60840E-12 -12.2158 0.83665E+00 -0.0775 34 CaCl+ 0.26437E-10 -10.5778 0.22119E-10 -10.6552 0.83665E+00 -0.0775 35 CaCl2,aq 0.10272E-14 -14.9883 0.10272E-14 -14.9883 0.10000E+01 0.0000 36 CaOH+ 0.80090E-07 -7.0964 0.67008E-07 -7.1739 0.83665E+00 -0.0775 37 CaSO4,aq 0.12694E-16 -16.8964 0.12694E-16 -16.8964 0.10000E+01 0.0000 38 HCl,aq 0.26639E-14 -14.5745 0.26639E-14 -14.5745 0.10000E+01 0.0000 43 FeCl+ 0.11111E-16 -16.9543 0.92957E-17 -17.0317 0.83665E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15718E-10 -10.8036 0.13150E-10 -10.8811 0.83665E+00 -0.0775 48 HFeO2- 0.35571E-07 -7.4489 0.29704E-07 -7.5272 0.83505E+00 -0.0783 49 FeO+ 0.11016E-16 -16.9580 0.92162E-17 -17.0354 0.83665E+00 -0.0775 51 FeO2- 0.40833E-09 -9.3890 0.34097E-09 -9.4673 0.83505E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.46503E-09 -9.3325 0.46503E-09 -9.3325 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.13945E-14 -14.8556 0.11645E-14 -14.9339 0.83505E+00 -0.0783 58 MgCO3,aq 0.13701E-13 -13.8632 0.13701E-13 -13.8632 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11571E-15 -15.9366 0.96811E-16 -16.0141 0.83665E+00 -0.0775 60 MgCl+ 0.37314E-14 -14.4281 0.31219E-14 -14.5056 0.83665E+00 -0.0775 61 MgOH+ 0.69015E-10 -10.1611 0.57742E-10 -10.2385 0.83665E+00 -0.0775 63 MnO,aq 0.18055E-08 -8.7434 0.18055E-08 -8.7434 0.10000E+01 0.0000 64 MnOH+ 0.46861E-09 -9.3292 0.39206E-09 -9.4066 0.83665E+00 -0.0775 65 MnO2-2 0.20921E-10 -10.6794 0.10834E-10 -10.9652 0.51785E+00 -0.2858 66 HMnO2- 0.21138E-09 -9.6749 0.17652E-09 -9.7532 0.83505E+00 -0.0783 69 MnCl+ 0.13873E-13 -13.8578 0.11607E-13 -13.9353 0.83665E+00 -0.0775 71 NaCl,aq 0.10770E-05 -5.9678 0.10770E-05 -5.9678 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93205E-02 -2.0306 0.77690E-02 -2.1096 0.83354E+00 -0.0791 79 HPO3-2 0.16328E-14 -14.7871 0.84552E-15 -15.0729 0.51785E+00 -0.2858 81 H2PO3- 0.15100E-18 -18.8210 0.12609E-18 -18.8993 0.83505E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38447E-10 -10.4151 0.32136E-10 -10.4930 0.83584E+00 -0.0779 84 PO4-3 0.10606E-08 -8.9744 0.25699E-09 -9.5901 0.24230E+00 -0.6157 88 HP2O7-3 0.94160E-18 -18.0261 0.21742E-18 -18.6627 0.23090E+00 -0.6366 89 P2O7-4 0.90823E-17 -17.0418 0.69841E-18 -18.1559 0.76898E-01 -1.1141 90 H2S,aq 0.83720E-08 -8.0772 0.83429E-08 -8.0787 0.99652E+00 -0.0015 91 S2-2 0.48672E-14 -14.3127 0.25205E-14 -14.5985 0.51785E+00 -0.2858 97 SO3-2 0.16380E-17 -17.7857 0.86053E-18 -18.0652 0.52535E+00 -0.2795 99 HSO4- 0.48928E-19 -19.3104 0.40976E-19 -19.3875 0.83747E+00 -0.0770 Charge balance for all species = 0.8902E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8852240E-10 -.2225648E-01 -.2239415E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981971E+06 0.0000 3 Cl- 0.2340849E-03 0.2351624E-03 0.8322701E+01 6.4197 4 SO4-- 0.1101685E-11 -.2400103E-04 -.2301564E+01 8.0144 5 HCO3- 0.4076058E-06 0.2227643E-04 0.1356880E+01 3.6612 6 HS- 0.4346129E-04 0.6747069E-04 0.2227507E+01 5.6885 7 Al+++ 0.9775945E-29 0.5304190E-05 0.1428659E+00 0.7390 8 H4SiO4 0.6959761E-03 0.1351007E-01 0.1296266E+04 -3.1574 9 Ca++ 0.1357352E-06 0.2328351E-06 0.9315324E-02 13.1018 10 Mg++ 0.2123500E-10 0.9349038E-10 0.2268982E-05 9.2942 11 Fe++ 0.5852713E-13 0.3620961E-07 0.2018678E-02 6.7350 12 K+ 0.1569213E-03 0.1576755E-03 0.6154697E+01 6.2467 13 Na+ 0.1991259E-01 0.2235935E-01 0.5131423E+03 8.3494 14 Mn++ 0.1876812E-10 0.2525178E-08 0.1384868E-03 9.2414 15 HPO4-- 0.4513159E-07 0.4623068E-07 0.4429452E-02 12.6269 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6788988E+02 -.1305829E-01 -.6787683E+02 0.0000000E+00 2 H2O 0.4113081E+01 0.3256577E+02 -.2845269E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1136505E+00 -.1408185E-04 0.1136645E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1136249E+00 0.3958632E-04 -.1136645E+00 0.0000000E+00 7 Al+++ 0.1336904E+02 0.3112068E-05 0.1336903E+02 0.0000000E+00 8 H4SiO4 0.4269240E+02 0.7926612E-02 0.4268447E+02 0.0000000E+00 9 Ca++ 0.4715598E+01 0.1366087E-06 0.4715598E+01 0.0000000E+00 10 Mg++ 0.3253967E+01 0.5485257E-10 0.3253967E+01 0.0000000E+00 11 Fe++ 0.2923335E+01 0.2124486E-07 0.2923334E+01 0.0000000E+00 12 K+ 0.8704881E+00 0.9251118E-04 0.8703956E+00 0.0000000E+00 13 Na+ 0.5146658E+01 0.1311865E-01 0.5133539E+01 0.0000000E+00 14 Mn++ 0.7108823E-01 0.1481570E-08 0.7108822E-01 0.0000000E+00 15 HPO4-- 0.2426206E-01 0.2712441E-07 0.2426203E-01 0.0000000E+00 Chg. balance for solid moles: 0.2368E-13 Mass of aqueous solution: 0.587742E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.129 0.710 1345. 3.129 30.03 516.3 andradite 0.4547 -0.342 231.0 2.364 5.158 60.03 grossular 0.1101 -0.958 49.59 1.695 1.107 13.80 apatite-OH 0.8087E-02 -2.092 4.062 0.609 0.9070E-01 1.291 clinochlore 0.5827 -0.235 323.9 2.510 7.231 123.2 daphnite 0.1687 -0.773 120.4 2.080 2.687 36.47 chlorite-Mn 0.1422E-01 -1.847 10.08 1.003 0.2250 3.212 diopside 0.2137 -0.670 46.29 1.665 1.033 14.15 hedenbergite 0.5543E-01 -1.256 13.75 1.138 0.3070 3.767 microcline 0.7633 -0.117 212.4 2.327 4.743 82.99 stilbite 2.642 0.422 1862. 3.270 41.56 868.3 stilpnomelane-Fe 0.2143 -0.669 231.0 2.364 5.157 79.79 tr.625ac.25prg.125 0.3498E-01 -1.456 29.90 1.476 0.6675 9.623 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4479.081879 g Volume = 1812.950281 cm3 Porosity: -10.4784% V(tot) - V(min): -.17195E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4099.9990000 g log = 3.6128 Original solution: 1000.0103000 g Original solution / Rock added: 0.24 (Water/Rock Ratio), log = -0.6128 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0667 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9571E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5396E-08 1.0068 0.5795E-08 0.5756E-08 CH4,gas 0.2866E-01 1.0123 0.3094E-01 0.3057E-01 H2,gas 0.1425E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2159E-06 0.9959 0.2293E-06 0.2303E-06 S2,gas 0.8004E-29 1.0000 0.8538E-29 0.8538E-29 CO,gas 0.2202E-13 1.0000 0.2349E-13 0.2349E-13 SO3,gas 0.1121E-47 1.0000 0.1196E-47 0.1196E-47 SO2,gas 0.6631E-27 1.0000 0.7073E-27 0.7073E-27 HCl,gas 0.4407E-17 1.0000 0.4700E-17 0.4700E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 -0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.60 -9.94 -3.312 0.16965E+05 -8.237 3 CH4,gas 4.54 1.34 -3.21 -0.802 0.54783E+04 -1.509 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.57 -8.34 -4.169 0.14238E+05 -6.640 6 S2,gas -7.34 -38.10 -30.77 -4.733 0.52535E+05 -29.069 7 CO,gas 3.21 -12.11 -15.33 -4.716 0.26172E+05 -13.629 8 SO3,gas 17.12 -32.50 -49.62 -12.405 0.84727E+05 -47.922 9 SO2,gas 0.83 -28.02 -28.85 -7.693 0.49259E+05 -27.150 10 HCl,gas 5.19 -13.84 -19.03 -9.513 0.32488E+05 -17.328 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80719E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.49 -4.46 -1.487 0.76165E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.49 -4.31 -1.435 0.73523E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65552E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.63 -4.53 -1.294 0.77314E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.63 -4.08 -1.167 0.69736E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82244E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.83 -3.57 -1.191 0.61015E+04 144 pyrrhotiteFe0.875 -6.02 -9.23 -3.21 -1.182 0.54887E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22448E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23250E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27803E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47133E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.83 -3.42 -1.141 0.58443E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.33 -4.35 -1.450 0.74266E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4099.9990000 g New total amount of reactant added: 4199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5220E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4199.9990000 Water: Moles liquid = 0.3201E+02 kg liquid = 0.5767E+00 Moles total = 0.2860E+01 kg total = 0.5152E-01 Activity = 1.0000 Stoichiometric ionic strength = .1140155E-01 Osmotic coef. = 0.9687 True ionic strength = .2007349E-01 Chg. balance for total moles = 0.5220E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88534E-10 -10.0529 0.74378E-10 -10.1286 0.84011E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23816E-03 -3.6231 0.19888E-03 -3.7014 0.83504E+00 -0.0783 4 SO4-- 0.11208E-11 -11.9505 0.58160E-12 -12.2354 0.51893E+00 -0.2849 5 HCO3- 0.41466E-06 -6.3823 0.34677E-06 -6.4600 0.83627E+00 -0.0777 6 HS- 0.44218E-04 -4.3544 0.36930E-04 -4.4326 0.83517E+00 -0.0782 7 Al+++ 0.97803E-29 -29.0096 0.22558E-29 -29.6467 0.23065E+00 -0.6370 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13577E-06 -6.8672 0.69939E-07 -7.1553 0.51512E+00 -0.2881 10 Mg++ 0.21241E-10 -10.6728 0.10891E-10 -10.9629 0.51276E+00 -0.2901 11 Fe++ 0.58544E-13 -13.2325 0.30051E-13 -13.5221 0.51332E+00 -0.2896 12 K+ 0.15694E-03 -3.8043 0.13128E-03 -3.8818 0.83647E+00 -0.0776 13 Na+ 0.19915E-01 -1.7008 0.16627E-01 -1.7792 0.83489E+00 -0.0784 14 Mn++ 0.18774E-10 -10.7264 0.96452E-11 -11.0157 0.51374E+00 -0.2893 15 HPO4-- 0.45122E-07 -7.3456 0.23419E-07 -7.6304 0.51901E+00 -0.2848 16 HSiO3- 0.10463E-01 -1.9803 0.87373E-02 -2.0586 0.83504E+00 -0.0783 17 Ca(HSiO3)+ 0.16634E-07 -7.7790 0.13917E-07 -7.8565 0.83665E+00 -0.0775 18 Mg(HSiO3)+ 0.32237E-11 -11.4916 0.26971E-11 -11.5691 0.83665E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66306E-16 -16.1784 0.55475E-16 -16.2559 0.83665E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53034E-05 -5.2754 0.44206E-05 -5.3545 0.83353E+00 -0.0791 24 CH4,aq 0.21463E-04 -4.6683 0.21388E-04 -4.6698 0.99652E+00 -0.0015 25 C2H6,aq 0.67754E-14 -14.1691 0.67519E-14 -14.1706 0.99652E+00 -0.0015 29 CO,aq 0.16036E-16 -16.7949 0.16036E-16 -16.7949 0.10000E+01 0.0000 30 CO2,aq 0.55304E-10 -10.2572 0.55111E-10 -10.2588 0.99652E+00 -0.0015 31 CO3-2 0.78642E-06 -6.1043 0.40723E-06 -6.3902 0.51783E+00 -0.2858 32 CaCO3,aq 0.35712E-09 -9.4472 0.35712E-09 -9.4472 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.73995E-12 -12.1308 0.61907E-12 -12.2083 0.83665E+00 -0.0775 34 CaCl+ 0.26904E-10 -10.5702 0.22509E-10 -10.6476 0.83665E+00 -0.0775 35 CaCl2,aq 0.10635E-14 -14.9732 0.10635E-14 -14.9732 0.10000E+01 0.0000 36 CaOH+ 0.80101E-07 -7.0964 0.67016E-07 -7.1738 0.83665E+00 -0.0775 37 CaSO4,aq 0.12917E-16 -16.8888 0.12917E-16 -16.8888 0.10000E+01 0.0000 38 HCl,aq 0.27106E-14 -14.5669 0.27106E-14 -14.5669 0.10000E+01 0.0000 43 FeCl+ 0.11307E-16 -16.9467 0.94598E-17 -17.0241 0.83665E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15720E-10 -10.8036 0.13152E-10 -10.8810 0.83665E+00 -0.0775 48 HFeO2- 0.35567E-07 -7.4490 0.29700E-07 -7.5272 0.83504E+00 -0.0783 49 FeO+ 0.11017E-16 -16.9579 0.92174E-17 -17.0354 0.83665E+00 -0.0775 51 FeO2- 0.40828E-09 -9.3890 0.34093E-09 -9.4673 0.83504E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.47318E-09 -9.3250 0.47318E-09 -9.3250 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.14188E-14 -14.8481 0.11848E-14 -14.9264 0.83504E+00 -0.0783 58 MgCO3,aq 0.13940E-13 -13.8557 0.13940E-13 -13.8557 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11774E-15 -15.9291 0.98510E-16 -16.0065 0.83665E+00 -0.0775 60 MgCl+ 0.37973E-14 -14.4205 0.31770E-14 -14.4980 0.83665E+00 -0.0775 61 MgOH+ 0.69024E-10 -10.1610 0.57749E-10 -10.2385 0.83665E+00 -0.0775 63 MnO,aq 0.18056E-08 -8.7434 0.18056E-08 -8.7434 0.10000E+01 0.0000 64 MnOH+ 0.46869E-09 -9.3291 0.39213E-09 -9.4066 0.83665E+00 -0.0775 65 MnO2-2 0.20918E-10 -10.6795 0.10832E-10 -10.9653 0.51783E+00 -0.2858 66 HMnO2- 0.21137E-09 -9.6750 0.17650E-09 -9.7532 0.83504E+00 -0.0783 69 MnCl+ 0.14118E-13 -13.8502 0.11812E-13 -13.9277 0.83665E+00 -0.0775 71 NaCl,aq 0.10959E-05 -5.9602 0.10959E-05 -5.9602 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93194E-02 -2.0306 0.77681E-02 -2.1097 0.83353E+00 -0.0791 79 HPO3-2 0.16324E-14 -14.7872 0.84531E-15 -15.0730 0.51783E+00 -0.2858 81 H2PO3- 0.15098E-18 -18.8211 0.12608E-18 -18.8994 0.83504E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38443E-10 -10.4152 0.32132E-10 -10.4931 0.83584E+00 -0.0779 84 PO4-3 0.10603E-08 -8.9746 0.25689E-09 -9.5902 0.24228E+00 -0.6157 88 HP2O7-3 0.94133E-18 -18.0263 0.21734E-18 -18.6629 0.23088E+00 -0.6366 89 P2O7-4 0.90792E-17 -17.0420 0.69807E-18 -18.1561 0.76888E-01 -1.1141 90 H2S,aq 0.85188E-08 -8.0696 0.84891E-08 -8.0711 0.99652E+00 -0.0015 91 S2-2 0.50383E-14 -14.2977 0.26090E-14 -14.5835 0.51783E+00 -0.2858 97 SO3-2 0.16664E-17 -17.7782 0.87541E-18 -18.0578 0.52534E+00 -0.2796 99 HSO4- 0.49780E-19 -19.3029 0.41689E-19 -19.3800 0.83746E+00 -0.0770 Charge balance for all species = 0.9053E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8853395E-10 -.2225425E-01 -.2239191E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981969E+06 0.0000 3 Cl- 0.2381613E-03 0.2392576E-03 0.8467637E+01 6.4271 4 SO4-- 0.1120768E-11 -.2436859E-04 -.2336811E+01 8.0217 5 HCO3- 0.4146628E-06 0.2266437E-04 0.1380509E+01 3.6686 6 HS- 0.4421816E-04 0.6859526E-04 0.2264634E+01 5.6959 7 Al+++ 0.9780284E-29 0.5303580E-05 0.1428495E+00 0.7390 8 H4SiO4 0.6959765E-03 0.1350889E-01 0.1296153E+04 -3.1574 9 Ca++ 0.1357731E-06 0.2328922E-06 0.9317606E-02 13.1018 10 Mg++ 0.2124093E-10 0.9350747E-10 0.2269397E-05 9.2942 11 Fe++ 0.5854351E-13 0.3620552E-07 0.2018450E-02 6.7350 12 K+ 0.1569418E-03 0.1576960E-03 0.6155498E+01 6.2467 13 Na+ 0.1991520E-01 0.2236198E-01 0.5132026E+03 8.3494 14 Mn++ 0.1877434E-10 0.2525347E-08 0.1384960E-03 9.2414 15 HPO4-- 0.4512216E-07 0.4622093E-07 0.4428517E-02 12.6267 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6954574E+02 -.1283350E-01 -.6953290E+02 0.0000000E+00 2 H2O 0.2859539E+01 0.3200835E+02 -.2914881E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1164218E+00 -.1405278E-04 0.1164358E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1163963E+00 0.3955725E-04 -.1164358E+00 0.0000000E+00 7 Al+++ 0.1369511E+02 0.3058448E-05 0.1369511E+02 0.0000000E+00 8 H4SiO4 0.4373368E+02 0.7790256E-02 0.4372589E+02 0.0000000E+00 9 Ca++ 0.4830612E+01 0.1343034E-06 0.4830612E+01 0.0000000E+00 10 Mg++ 0.3333333E+01 0.5392353E-10 0.3333333E+01 0.0000000E+00 11 Fe++ 0.2994635E+01 0.2087886E-07 0.2994635E+01 0.0000000E+00 12 K+ 0.8917195E+00 0.9093955E-04 0.8916286E+00 0.0000000E+00 13 Na+ 0.5272182E+01 0.1289562E-01 0.5259286E+01 0.0000000E+00 14 Mn++ 0.7282209E-01 0.1456307E-08 0.7282208E-01 0.0000000E+00 15 HPO4-- 0.2485382E-01 0.2665451E-07 0.2485379E-01 0.0000000E+00 Chg. balance for solid moles: -.1629E-13 Mass of aqueous solution: 0.577682E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.255 0.721 1378. 3.139 30.03 529.0 andradite 0.4657 -0.332 236.7 2.374 5.158 61.49 grossular 0.1128 -0.948 50.80 1.706 1.107 14.13 apatite-OH 0.8285E-02 -2.082 4.162 0.619 0.9070E-01 1.322 clinochlore 0.5969 -0.224 331.8 2.521 7.230 126.2 daphnite 0.1728 -0.762 123.3 2.091 2.687 37.36 chlorite-Mn 0.1456E-01 -1.837 10.33 1.014 0.2250 3.291 diopside 0.2192 -0.659 47.47 1.676 1.034 14.51 hedenbergite 0.5684E-01 -1.245 14.10 1.149 0.3074 3.863 microcline 0.7819 -0.107 217.6 2.338 4.743 85.01 stilbite 2.706 0.432 1907. 3.280 41.56 889.4 stilpnomelane-Fe 0.2195 -0.659 236.6 2.374 5.157 81.74 tr.625ac.25prg.125 0.3581E-01 -1.446 30.61 1.486 0.6671 9.852 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4588.332544 g Volume = 1857.153345 cm3 Porosity: -10.4791% V(tot) - V(min): -.17615E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4199.9990000 g log = 3.6232 Original solution: 1000.0103000 g Original solution / Rock added: 0.24 (Water/Rock Ratio), log = -0.6232 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0672 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9566E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5488E-08 1.0068 0.5896E-08 0.5857E-08 CH4,gas 0.2914E-01 1.0123 0.3148E-01 0.3110E-01 H2,gas 0.1424E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2196E-06 0.9959 0.2334E-06 0.2343E-06 S2,gas 0.8283E-29 1.0000 0.8840E-29 0.8840E-29 CO,gas 0.2239E-13 1.0000 0.2390E-13 0.2390E-13 SO3,gas 0.1140E-47 1.0000 0.1217E-47 0.1217E-47 SO2,gas 0.6744E-27 1.0000 0.7197E-27 0.7197E-27 HCl,gas 0.4481E-17 1.0000 0.4783E-17 0.4783E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.60662E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.84926E-10 67 diopside 16.18 16.18 0.00 0.000 0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 0.18198E-10 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.59 -9.93 -3.309 0.16952E+05 -8.229 3 CH4,gas 4.54 1.34 -3.20 -0.800 0.54655E+04 -1.502 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.56 -8.33 -4.165 0.14225E+05 -6.632 6 S2,gas -7.34 -38.09 -30.75 -4.731 0.52509E+05 -29.054 7 CO,gas 3.21 -12.11 -15.32 -4.714 0.26160E+05 -13.622 8 SO3,gas 17.12 -32.49 -49.61 -12.403 0.84714E+05 -47.915 9 SO2,gas 0.83 -28.01 -28.84 -7.691 0.49247E+05 -27.143 10 HCl,gas 5.19 -13.83 -19.02 -9.510 0.32475E+05 -17.320 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80718E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.49 -4.45 -1.484 0.76037E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.49 -4.30 -1.433 0.73395E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65552E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.62 -4.52 -1.292 0.77186E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.62 -4.08 -1.165 0.69608E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82244E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.83 -3.57 -1.189 0.60886E+04 144 pyrrhotiteFe0.875 -6.02 -9.22 -3.21 -1.179 0.54759E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22447E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23250E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47132E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.83 -3.42 -1.138 0.58315E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79437E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.32 -4.34 -1.447 0.74137E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4199.9990000 g New total amount of reactant added: 4299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4299.9990000 Water: Moles liquid = 0.3145E+02 kg liquid = 0.5666E+00 Moles total = 0.1606E+01 kg total = 0.2893E-01 Activity = 1.0000 Stoichiometric ionic strength = .1140506E-01 Osmotic coef. = 0.9687 True ionic strength = .2007622E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88546E-10 -10.0528 0.74387E-10 -10.1285 0.84010E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.24238E-03 -3.6155 0.20240E-03 -3.6938 0.83504E+00 -0.0783 4 SO4-- 0.11405E-11 -11.9429 0.59184E-12 -12.2278 0.51892E+00 -0.2849 5 HCO3- 0.42197E-06 -6.3747 0.35288E-06 -6.4524 0.83626E+00 -0.0777 6 HS- 0.45002E-04 -4.3468 0.37584E-04 -4.4250 0.83516E+00 -0.0782 7 Al+++ 0.97848E-29 -29.0094 0.22567E-29 -29.6465 0.23063E+00 -0.6371 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13581E-06 -6.8671 0.69957E-07 -7.1552 0.51510E+00 -0.2881 10 Mg++ 0.21247E-10 -10.6727 0.10894E-10 -10.9628 0.51274E+00 -0.2901 11 Fe++ 0.58560E-13 -13.2324 0.30059E-13 -13.5220 0.51330E+00 -0.2896 12 K+ 0.15696E-03 -3.8042 0.13129E-03 -3.8818 0.83646E+00 -0.0776 13 Na+ 0.19918E-01 -1.7008 0.16629E-01 -1.7791 0.83488E+00 -0.0784 14 Mn++ 0.18781E-10 -10.7263 0.96481E-11 -11.0156 0.51373E+00 -0.2893 15 HPO4-- 0.45112E-07 -7.3457 0.23413E-07 -7.6305 0.51899E+00 -0.2848 16 HSiO3- 0.10462E-01 -1.9804 0.87362E-02 -2.0587 0.83504E+00 -0.0783 17 Ca(HSiO3)+ 0.16636E-07 -7.7790 0.13918E-07 -7.8564 0.83664E+00 -0.0775 18 Mg(HSiO3)+ 0.32241E-11 -11.4916 0.26974E-11 -11.5690 0.83664E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66315E-16 -16.1784 0.55482E-16 -16.2558 0.83664E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53028E-05 -5.2755 0.44200E-05 -5.3546 0.83353E+00 -0.0791 24 CH4,aq 0.21843E-04 -4.6607 0.21768E-04 -4.6622 0.99652E+00 -0.0015 25 C2H6,aq 0.70179E-14 -14.1538 0.69935E-14 -14.1553 0.99652E+00 -0.0015 29 CO,aq 0.16320E-16 -16.7873 0.16320E-16 -16.7873 0.10000E+01 0.0000 30 CO2,aq 0.56285E-10 -10.2496 0.56089E-10 -10.2511 0.99652E+00 -0.0015 31 CO3-2 0.80019E-06 -6.0968 0.41435E-06 -6.3826 0.51781E+00 -0.2858 32 CaCO3,aq 0.36346E-09 -9.4395 0.36346E-09 -9.4395 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.75317E-12 -12.1231 0.63013E-12 -12.2006 0.83664E+00 -0.0775 34 CaCl+ 0.27388E-10 -10.5624 0.22914E-10 -10.6399 0.83664E+00 -0.0775 35 CaCl2,aq 0.11018E-14 -14.9579 0.11018E-14 -14.9579 0.10000E+01 0.0000 36 CaOH+ 0.80111E-07 -7.0963 0.67024E-07 -7.1738 0.83664E+00 -0.0775 37 CaSO4,aq 0.13147E-16 -16.8812 0.13147E-16 -16.8812 0.10000E+01 0.0000 38 HCl,aq 0.27589E-14 -14.5593 0.27589E-14 -14.5593 0.10000E+01 0.0000 43 FeCl+ 0.11510E-16 -16.9389 0.96298E-17 -17.0164 0.83664E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15722E-10 -10.8035 0.13153E-10 -10.8810 0.83664E+00 -0.0775 48 HFeO2- 0.35563E-07 -7.4490 0.29696E-07 -7.5273 0.83504E+00 -0.0783 49 FeO+ 0.11019E-16 -16.9579 0.92185E-17 -17.0353 0.83664E+00 -0.0775 51 FeO2- 0.40823E-09 -9.3891 0.34089E-09 -9.4674 0.83504E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.48162E-09 -9.3173 0.48162E-09 -9.3173 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.14440E-14 -14.8404 0.12058E-14 -14.9187 0.83504E+00 -0.0783 58 MgCO3,aq 0.14187E-13 -13.8481 0.14187E-13 -13.8481 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11985E-15 -15.9214 0.10027E-15 -15.9988 0.83664E+00 -0.0775 60 MgCl+ 0.38656E-14 -14.4128 0.32341E-14 -14.4902 0.83664E+00 -0.0775 61 MgOH+ 0.69033E-10 -10.1609 0.57756E-10 -10.2384 0.83664E+00 -0.0775 63 MnO,aq 0.18057E-08 -8.7434 0.18057E-08 -8.7434 0.10000E+01 0.0000 64 MnOH+ 0.46878E-09 -9.3290 0.39220E-09 -9.4065 0.83664E+00 -0.0775 65 MnO2-2 0.20914E-10 -10.6796 0.10830E-10 -10.9654 0.51781E+00 -0.2858 66 HMnO2- 0.21136E-09 -9.6750 0.17649E-09 -9.7533 0.83504E+00 -0.0783 69 MnCl+ 0.14373E-13 -13.8425 0.12025E-13 -13.9199 0.83664E+00 -0.0775 71 NaCl,aq 0.11154E-05 -5.9526 0.11154E-05 -5.9526 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93184E-02 -2.0307 0.77671E-02 -2.1097 0.83353E+00 -0.0791 79 HPO3-2 0.16321E-14 -14.7873 0.84510E-15 -15.0731 0.51781E+00 -0.2858 81 H2PO3- 0.15097E-18 -18.8211 0.12606E-18 -18.8994 0.83504E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38439E-10 -10.4152 0.32128E-10 -10.4931 0.83583E+00 -0.0779 84 PO4-3 0.10600E-08 -8.9747 0.25680E-09 -9.5904 0.24226E+00 -0.6157 88 HP2O7-3 0.94106E-18 -18.0264 0.21726E-18 -18.6630 0.23086E+00 -0.6366 89 P2O7-4 0.90759E-17 -17.0421 0.69772E-18 -18.1563 0.76877E-01 -1.1142 90 H2S,aq 0.86708E-08 -8.0619 0.86406E-08 -8.0635 0.99652E+00 -0.0015 91 S2-2 0.52186E-14 -14.2824 0.27022E-14 -14.5683 0.51781E+00 -0.2858 97 SO3-2 0.16957E-17 -17.7706 0.89081E-18 -18.0502 0.52532E+00 -0.2796 99 HSO4- 0.50663E-19 -19.2953 0.42428E-19 -19.3723 0.83746E+00 -0.0770 Charge balance for all species = 0.9224E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8854591E-10 -.2225195E-01 -.2238959E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981968E+06 0.0000 3 Cl- 0.2423822E-03 0.2434981E-03 0.8617711E+01 6.4347 4 SO4-- 0.1140524E-11 -.2474919E-04 -.2373308E+01 8.0292 5 HCO3- 0.4219683E-06 0.2306605E-04 0.1404976E+01 3.6761 6 HS- 0.4500185E-04 0.6975971E-04 0.2303077E+01 5.7035 7 Al+++ 0.9784779E-29 0.5302949E-05 0.1428325E+00 0.7390 8 H4SiO4 0.6959769E-03 0.1350767E-01 0.1296035E+04 -3.1574 9 Ca++ 0.1358123E-06 0.2329513E-06 0.9319971E-02 13.1018 10 Mg++ 0.2124708E-10 0.9352282E-10 0.2269769E-05 9.2942 11 Fe++ 0.5856047E-13 0.3620129E-07 0.2018214E-02 6.7350 12 K+ 0.1569631E-03 0.1577173E-03 0.6156328E+01 6.2467 13 Na+ 0.1991791E-01 0.2236470E-01 0.5132650E+03 8.3494 14 Mn++ 0.1878070E-10 0.2525510E-08 0.1385050E-03 9.2414 15 HPO4-- 0.4511239E-07 0.4621084E-07 0.4427550E-02 12.6265 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7120159E+02 -.1260870E-01 -.7118898E+02 0.0000000E+00 2 H2O 0.1605998E+01 0.3145094E+02 -.2984494E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1191931E+00 -.1402372E-04 0.1192072E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1191676E+00 0.3952819E-04 -.1192072E+00 0.0000000E+00 7 Al+++ 0.1402119E+02 0.3004829E-05 0.1402118E+02 0.0000000E+00 8 H4SiO4 0.4477496E+02 0.7653900E-02 0.4476730E+02 0.0000000E+00 9 Ca++ 0.4945627E+01 0.1319980E-06 0.4945627E+01 0.0000000E+00 10 Mg++ 0.3412698E+01 0.5299317E-10 0.3412698E+01 0.0000000E+00 11 Fe++ 0.3065936E+01 0.2051287E-07 0.3065936E+01 0.0000000E+00 12 K+ 0.9129510E+00 0.8936792E-04 0.9128616E+00 0.0000000E+00 13 Na+ 0.5397706E+01 0.1267259E-01 0.5385034E+01 0.0000000E+00 14 Mn++ 0.7455595E-01 0.1431039E-08 0.7455594E-01 0.0000000E+00 15 HPO4-- 0.2544557E-01 0.2618461E-07 0.2544555E-01 0.0000000E+00 Chg. balance for solid moles: 0.4982E-14 Mass of aqueous solution: 0.567622E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.380 0.731 1411. 3.149 30.03 541.6 andradite 0.4768 -0.322 242.3 2.384 5.158 62.96 grossular 0.1155 -0.938 52.01 1.716 1.107 14.47 apatite-OH 0.8482E-02 -2.072 4.261 0.629 0.9070E-01 1.354 clinochlore 0.6110 -0.214 339.6 2.531 7.230 129.2 daphnite 0.1769 -0.752 126.2 2.101 2.687 38.25 chlorite-Mn 0.1491E-01 -1.826 10.57 1.024 0.2250 3.369 diopside 0.2246 -0.649 48.64 1.687 1.036 14.87 hedenbergite 0.5825E-01 -1.235 14.45 1.160 0.3077 3.958 microcline 0.8005 -0.097 222.8 2.348 4.743 87.03 stilbite 2.770 0.443 1952. 3.291 41.56 910.5 stilpnomelane-Fe 0.2248 -0.648 242.3 2.384 5.158 83.69 tr.625ac.25prg.125 0.3665E-01 -1.436 31.32 1.496 0.6668 10.08 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4697.583209 g Volume = 1901.356409 cm3 Porosity: -10.4798% V(tot) - V(min): -.18036E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4299.9990000 g log = 3.6335 Original solution: 1000.0103000 g Original solution / Rock added: 0.23 (Water/Rock Ratio), log = -0.6335 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0678 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9561E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5582E-08 1.0067 0.6001E-08 0.5961E-08 CH4,gas 0.2964E-01 1.0123 0.3204E-01 0.3165E-01 H2,gas 0.1423E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2234E-06 0.9959 0.2375E-06 0.2385E-06 S2,gas 0.8576E-29 1.0000 0.9158E-29 0.9158E-29 CO,gas 0.2278E-13 1.0000 0.2432E-13 0.2432E-13 SO3,gas 0.1160E-47 1.0000 0.1238E-47 0.1238E-47 SO2,gas 0.6861E-27 1.0000 0.7326E-27 0.7326E-27 HCl,gas 0.4559E-17 1.0000 0.4868E-17 0.4868E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.58 -9.92 -3.307 0.16939E+05 -8.222 3 CH4,gas 4.54 1.35 -3.19 -0.798 0.54524E+04 -1.494 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.55 -8.32 -4.162 0.14212E+05 -6.624 6 S2,gas -7.34 -38.07 -30.74 -4.729 0.52483E+05 -29.038 7 CO,gas 3.21 -12.10 -15.31 -4.712 0.26147E+05 -13.614 8 SO3,gas 17.12 -32.48 -49.61 -12.402 0.84701E+05 -47.907 9 SO2,gas 0.83 -28.00 -28.83 -7.689 0.49233E+05 -27.135 10 HCl,gas 5.19 -13.82 -19.01 -9.506 0.32462E+05 -17.313 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80717E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.48 -4.45 -1.482 0.75907E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.48 -4.29 -1.430 0.73265E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65551E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.62 -4.51 -1.289 0.77056E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.62 -4.07 -1.163 0.69478E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82243E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.26 -7.82 -3.56 -1.186 0.60755E+04 144 pyrrhotiteFe0.875 -6.02 -9.22 -3.20 -1.177 0.54627E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22447E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23250E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47132E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.82 -3.41 -1.136 0.58183E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.31 -4.33 -1.445 0.74005E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4299.9990000 g New total amount of reactant added: 4399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4399.9990000 Water: Moles liquid = 0.3090E+02 kg liquid = 0.5566E+00 Moles total = 0.3525E+00 kg total = 0.6350E-02 Activity = 1.0000 Stoichiometric ionic strength = .1140870E-01 Osmotic coef. = 0.9687 True ionic strength = .2007906E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88558E-10 -10.0528 0.74397E-10 -10.1284 0.84009E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.24676E-03 -3.6077 0.20605E-03 -3.6860 0.83503E+00 -0.0783 4 SO4-- 0.11610E-11 -11.9352 0.60243E-12 -12.2201 0.51890E+00 -0.2849 5 HCO3- 0.42954E-06 -6.3670 0.35920E-06 -6.4447 0.83625E+00 -0.0777 6 HS- 0.45814E-04 -4.3390 0.38261E-04 -4.4172 0.83515E+00 -0.0782 7 Al+++ 0.97894E-29 -29.0092 0.22576E-29 -29.6464 0.23061E+00 -0.6371 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13585E-06 -6.8669 0.69975E-07 -7.1551 0.51508E+00 -0.2881 10 Mg++ 0.21253E-10 -10.6726 0.10897E-10 -10.9627 0.51272E+00 -0.2901 11 Fe++ 0.58578E-13 -13.2323 0.30067E-13 -13.5219 0.51328E+00 -0.2896 12 K+ 0.15699E-03 -3.8041 0.13131E-03 -3.8817 0.83645E+00 -0.0776 13 Na+ 0.19921E-01 -1.7007 0.16631E-01 -1.7791 0.83488E+00 -0.0784 14 Mn++ 0.18787E-10 -10.7261 0.96511E-11 -11.0154 0.51371E+00 -0.2893 15 HPO4-- 0.45102E-07 -7.3458 0.23407E-07 -7.6307 0.51897E+00 -0.2849 16 HSiO3- 0.10461E-01 -1.9804 0.87351E-02 -2.0587 0.83503E+00 -0.0783 17 Ca(HSiO3)+ 0.16638E-07 -7.7789 0.13920E-07 -7.8564 0.83663E+00 -0.0775 18 Mg(HSiO3)+ 0.32246E-11 -11.4915 0.26978E-11 -11.5690 0.83663E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66324E-16 -16.1783 0.55489E-16 -16.2558 0.83663E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53021E-05 -5.2755 0.44194E-05 -5.3546 0.83352E+00 -0.0791 24 CH4,aq 0.22238E-04 -4.6529 0.22160E-04 -4.6544 0.99652E+00 -0.0015 25 C2H6,aq 0.72736E-14 -14.1383 0.72483E-14 -14.1398 0.99652E+00 -0.0015 29 CO,aq 0.16615E-16 -16.7795 0.16615E-16 -16.7795 0.10000E+01 0.0000 30 CO2,aq 0.57301E-10 -10.2418 0.57102E-10 -10.2434 0.99652E+00 -0.0015 31 CO3-2 0.81446E-06 -6.0891 0.42172E-06 -6.3750 0.51779E+00 -0.2858 32 CaCO3,aq 0.37002E-09 -9.4318 0.37002E-09 -9.4318 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.76688E-12 -12.1153 0.64160E-12 -12.1927 0.83663E+00 -0.0775 34 CaCl+ 0.27889E-10 -10.5546 0.23333E-10 -10.6320 0.83663E+00 -0.0775 35 CaCl2,aq 0.11422E-14 -14.9423 0.11422E-14 -14.9423 0.10000E+01 0.0000 36 CaOH+ 0.80123E-07 -7.0962 0.67033E-07 -7.1737 0.83663E+00 -0.0775 37 CaSO4,aq 0.13386E-16 -16.8733 0.13386E-16 -16.8733 0.10000E+01 0.0000 38 HCl,aq 0.28090E-14 -14.5514 0.28090E-14 -14.5514 0.10000E+01 0.0000 43 FeCl+ 0.11721E-16 -16.9310 0.98060E-17 -17.0085 0.83663E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15724E-10 -10.8034 0.13155E-10 -10.8809 0.83663E+00 -0.0775 48 HFeO2- 0.35559E-07 -7.4491 0.29692E-07 -7.5274 0.83503E+00 -0.0783 49 FeO+ 0.11020E-16 -16.9578 0.92198E-17 -17.0353 0.83663E+00 -0.0775 51 FeO2- 0.40818E-09 -9.3891 0.34084E-09 -9.4674 0.83503E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.49037E-09 -9.3095 0.49037E-09 -9.3095 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.14700E-14 -14.8327 0.12275E-14 -14.9110 0.83503E+00 -0.0783 58 MgCO3,aq 0.14443E-13 -13.8403 0.14443E-13 -13.8403 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12203E-15 -15.9135 0.10209E-15 -15.9910 0.83663E+00 -0.0775 60 MgCl+ 0.39364E-14 -14.4049 0.32933E-14 -14.4824 0.83663E+00 -0.0775 61 MgOH+ 0.69043E-10 -10.1609 0.57764E-10 -10.2383 0.83663E+00 -0.0775 63 MnO,aq 0.18057E-08 -8.7433 0.18057E-08 -8.7433 0.10000E+01 0.0000 64 MnOH+ 0.46887E-09 -9.3289 0.39227E-09 -9.4064 0.83663E+00 -0.0775 65 MnO2-2 0.20910E-10 -10.6796 0.10827E-10 -10.9655 0.51779E+00 -0.2858 66 HMnO2- 0.21134E-09 -9.6750 0.17647E-09 -9.7533 0.83503E+00 -0.0783 69 MnCl+ 0.14637E-13 -13.8346 0.12246E-13 -13.9120 0.83663E+00 -0.0775 71 NaCl,aq 0.11357E-05 -5.9447 0.11357E-05 -5.9447 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93172E-02 -2.0307 0.77661E-02 -2.1098 0.83352E+00 -0.0791 79 HPO3-2 0.16317E-14 -14.7874 0.84488E-15 -15.0732 0.51779E+00 -0.2858 81 H2PO3- 0.15095E-18 -18.8212 0.12605E-18 -18.8995 0.83503E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38434E-10 -10.4153 0.32124E-10 -10.4932 0.83582E+00 -0.0779 84 PO4-3 0.10597E-08 -8.9748 0.25669E-09 -9.5906 0.24224E+00 -0.6158 88 HP2O7-3 0.94077E-18 -18.0265 0.21717E-18 -18.6632 0.23085E+00 -0.6367 89 P2O7-4 0.90725E-17 -17.0423 0.69736E-18 -18.1565 0.76865E-01 -1.1143 90 H2S,aq 0.88283E-08 -8.0541 0.87976E-08 -8.0556 0.99652E+00 -0.0015 91 S2-2 0.54087E-14 -14.2669 0.28006E-14 -14.5528 0.51779E+00 -0.2858 97 SO3-2 0.17262E-17 -17.7629 0.90676E-18 -18.0425 0.52530E+00 -0.2796 99 HSO4- 0.51577E-19 -19.2875 0.43193E-19 -19.3646 0.83745E+00 -0.0770 Charge balance for all species = 0.9383E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8855830E-10 -.2224957E-01 -.2238719E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981967E+06 0.0000 3 Cl- 0.2467554E-03 0.2478915E-03 0.8773200E+01 6.4424 4 SO4-- 0.1160989E-11 -.2514353E-04 -.2411123E+01 8.0368 5 HCO3- 0.4295356E-06 0.2348224E-04 0.1430326E+01 3.6838 6 HS- 0.4581382E-04 0.7096618E-04 0.2342908E+01 5.7112 7 Al+++ 0.9789440E-29 0.5302297E-05 0.1428149E+00 0.7390 8 H4SiO4 0.6959773E-03 0.1350641E-01 0.1295914E+04 -3.1574 9 Ca++ 0.1358530E-06 0.2330126E-06 0.9322422E-02 13.1018 10 Mg++ 0.2125345E-10 0.9353871E-10 0.2270154E-05 9.2942 11 Fe++ 0.5857805E-13 0.3619691E-07 0.2017970E-02 6.7350 12 K+ 0.1569851E-03 0.1577394E-03 0.6157187E+01 6.2467 13 Na+ 0.1992071E-01 0.2236752E-01 0.5133297E+03 8.3494 14 Mn++ 0.1878722E-10 0.2525670E-08 0.1385137E-03 9.2415 15 HPO4-- 0.4510227E-07 0.4620038E-07 0.4426547E-02 12.6262 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7285744E+02 -.1238391E-01 -.7284505E+02 0.0000000E+00 2 H2O 0.3524574E+00 0.3089352E+02 -.3054106E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1219645E+00 -.1399466E-04 0.1219785E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1219390E+00 0.3949913E-04 -.1219785E+00 0.0000000E+00 7 Al+++ 0.1434726E+02 0.2951210E-05 0.1434726E+02 0.0000000E+00 8 H4SiO4 0.4581623E+02 0.7517543E-02 0.4580872E+02 0.0000000E+00 9 Ca++ 0.5060641E+01 0.1296927E-06 0.5060641E+01 0.0000000E+00 10 Mg++ 0.3492063E+01 0.5206280E-10 0.3492063E+01 0.0000000E+00 11 Fe++ 0.3137237E+01 0.2014687E-07 0.3137237E+01 0.0000000E+00 12 K+ 0.9341824E+00 0.8779630E-04 0.9340946E+00 0.0000000E+00 13 Na+ 0.5523231E+01 0.1244956E-01 0.5510781E+01 0.0000000E+00 14 Mn++ 0.7628981E-01 0.1405765E-08 0.7628980E-01 0.0000000E+00 15 HPO4-- 0.2603733E-01 0.2571471E-07 0.2603731E-01 0.0000000E+00 Chg. balance for solid moles: -.2623E-14 Mass of aqueous solution: 0.557562E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.506 0.741 1444. 3.160 30.04 554.2 andradite 0.4879 -0.312 247.9 2.394 5.158 64.42 grossular 0.1181 -0.928 53.22 1.726 1.107 14.81 apatite-OH 0.8679E-02 -2.062 4.360 0.639 0.9070E-01 1.385 clinochlore 0.6252 -0.204 347.5 2.541 7.230 132.2 daphnite 0.1810 -0.742 129.1 2.111 2.687 39.13 chlorite-Mn 0.1526E-01 -1.817 10.82 1.034 0.2250 3.447 diopside 0.2301 -0.638 49.82 1.697 1.036 15.23 hedenbergite 0.5966E-01 -1.224 14.80 1.170 0.3079 4.054 microcline 0.8191 -0.087 228.0 2.358 4.743 89.06 stilbite 2.834 0.452 1997. 3.300 41.55 931.6 stilpnomelane-Fe 0.2300 -0.638 247.9 2.394 5.158 85.64 tr.625ac.25prg.125 0.3748E-01 -1.426 32.04 1.506 0.6665 10.31 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4806.833873 g Volume = 1945.559473 cm3 Porosity: -10.4804% V(tot) - V(min): -.18456E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4399.9990000 g log = 3.6435 Original solution: 1000.0103000 g Original solution / Rock added: 0.23 (Water/Rock Ratio), log = -0.6434 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0684 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9556E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5680E-08 1.0067 0.6109E-08 0.6068E-08 CH4,gas 0.3016E-01 1.0123 0.3262E-01 0.3222E-01 H2,gas 0.1423E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2273E-06 0.9958 0.2418E-06 0.2428E-06 S2,gas 0.8886E-29 1.0000 0.9494E-29 0.9494E-29 CO,gas 0.2317E-13 1.0000 0.2476E-13 0.2476E-13 SO3,gas 0.1180E-47 1.0000 0.1261E-47 0.1261E-47 SO2,gas 0.6981E-27 1.0000 0.7459E-27 0.7459E-27 HCl,gas 0.4639E-17 1.0000 0.4957E-17 0.4957E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.00000E+00 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 -0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.75827E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.57 -9.91 -3.304 0.16926E+05 -8.214 3 CH4,gas 4.54 1.36 -3.19 -0.796 0.54392E+04 -1.487 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.55 -8.32 -4.158 0.14198E+05 -6.616 6 S2,gas -7.34 -38.06 -30.72 -4.726 0.52456E+05 -29.023 7 CO,gas 3.21 -12.09 -15.31 -4.709 0.26133E+05 -13.606 8 SO3,gas 17.12 -32.48 -49.60 -12.400 0.84688E+05 -47.899 9 SO2,gas 0.83 -27.99 -28.83 -7.687 0.49220E+05 -27.127 10 HCl,gas 5.19 -13.81 -19.00 -9.502 0.32448E+05 -17.305 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80716E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.47 -4.44 -1.479 0.75774E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.47 -4.28 -1.428 0.73132E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65551E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.61 -4.51 -1.287 0.76923E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.61 -4.06 -1.160 0.69345E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82243E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.81 -3.55 -1.183 0.60622E+04 144 pyrrhotiteFe0.875 -6.02 -9.21 -3.19 -1.174 0.54494E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22447E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23249E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47131E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.81 -3.40 -1.133 0.58050E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.30 -4.33 -1.442 0.73871E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4399.9990000 g New total amount of reactant added: 4499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4499.9990000 Water: Moles liquid = 0.3034E+02 kg liquid = 0.5465E+00 Moles total = -.9011E+00 kg total = -.1623E-01 Activity = 1.0000 Stoichiometric ionic strength = .1141247E-01 Osmotic coef. = 0.9686 True ionic strength = .2008200E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88571E-10 -10.0527 0.74407E-10 -10.1284 0.84008E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.25129E-03 -3.5998 0.20983E-03 -3.6781 0.83502E+00 -0.0783 4 SO4-- 0.11822E-11 -11.9273 0.61342E-12 -12.2122 0.51888E+00 -0.2849 5 HCO3- 0.43738E-06 -6.3591 0.36576E-06 -6.4368 0.83624E+00 -0.0777 6 HS- 0.46656E-04 -4.3311 0.38964E-04 -4.4093 0.83514E+00 -0.0782 7 Al+++ 0.97943E-29 -29.0090 0.22585E-29 -29.6462 0.23059E+00 -0.6372 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13590E-06 -6.8668 0.69994E-07 -7.1549 0.51506E+00 -0.2881 10 Mg++ 0.21260E-10 -10.6724 0.10900E-10 -10.9626 0.51270E+00 -0.2901 11 Fe++ 0.58596E-13 -13.2321 0.30075E-13 -13.5218 0.51326E+00 -0.2897 12 K+ 0.15701E-03 -3.8041 0.13133E-03 -3.8816 0.83644E+00 -0.0776 13 Na+ 0.19924E-01 -1.7006 0.16634E-01 -1.7790 0.83487E+00 -0.0784 14 Mn++ 0.18794E-10 -10.7260 0.96542E-11 -11.0153 0.51369E+00 -0.2893 15 HPO4-- 0.45092E-07 -7.3459 0.23400E-07 -7.6308 0.51895E+00 -0.2849 16 HSiO3- 0.10459E-01 -1.9805 0.87339E-02 -2.0588 0.83502E+00 -0.0783 17 Ca(HSiO3)+ 0.16641E-07 -7.7788 0.13922E-07 -7.8563 0.83662E+00 -0.0775 18 Mg(HSiO3)+ 0.32250E-11 -11.4915 0.26982E-11 -11.5689 0.83662E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66334E-16 -16.1783 0.55496E-16 -16.2557 0.83662E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53015E-05 -5.2756 0.44188E-05 -5.3547 0.83351E+00 -0.0791 24 CH4,aq 0.22647E-04 -4.6450 0.22568E-04 -4.6465 0.99652E+00 -0.0015 25 C2H6,aq 0.75435E-14 -14.1224 0.75172E-14 -14.1239 0.99652E+00 -0.0015 29 CO,aq 0.16920E-16 -16.7716 0.16920E-16 -16.7716 0.10000E+01 0.0000 30 CO2,aq 0.58355E-10 -10.2339 0.58152E-10 -10.2354 0.99652E+00 -0.0015 31 CO3-2 0.82924E-06 -6.0813 0.42936E-06 -6.3672 0.51777E+00 -0.2859 32 CaCO3,aq 0.37682E-09 -9.4239 0.37682E-09 -9.4239 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.78110E-12 -12.1073 0.65348E-12 -12.1848 0.83662E+00 -0.0775 34 CaCl+ 0.28410E-10 -10.5465 0.23768E-10 -10.6240 0.83662E+00 -0.0775 35 CaCl2,aq 0.11849E-14 -14.9263 0.11849E-14 -14.9263 0.10000E+01 0.0000 36 CaOH+ 0.80134E-07 -7.0962 0.67042E-07 -7.1737 0.83662E+00 -0.0775 37 CaSO4,aq 0.13634E-16 -16.8654 0.13634E-16 -16.8654 0.10000E+01 0.0000 38 HCl,aq 0.28610E-14 -14.5435 0.28610E-14 -14.5435 0.10000E+01 0.0000 43 FeCl+ 0.11939E-16 -16.9230 0.99888E-17 -17.0005 0.83662E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15726E-10 -10.8034 0.13157E-10 -10.8808 0.83662E+00 -0.0775 48 HFeO2- 0.35554E-07 -7.4491 0.29688E-07 -7.5274 0.83502E+00 -0.0783 49 FeO+ 0.11022E-16 -16.9578 0.92210E-17 -17.0352 0.83662E+00 -0.0775 51 FeO2- 0.40813E-09 -9.3892 0.34080E-09 -9.4675 0.83502E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.49945E-09 -9.3015 0.49945E-09 -9.3015 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.14971E-14 -14.8248 0.12501E-14 -14.9031 0.83502E+00 -0.0783 58 MgCO3,aq 0.14709E-13 -13.8324 0.14709E-13 -13.8324 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12429E-15 -15.9056 0.10399E-15 -15.9830 0.83662E+00 -0.0775 60 MgCl+ 0.40098E-14 -14.3969 0.33547E-14 -14.4743 0.83662E+00 -0.0775 61 MgOH+ 0.69053E-10 -10.1608 0.57771E-10 -10.2383 0.83662E+00 -0.0775 63 MnO,aq 0.18058E-08 -8.7433 0.18058E-08 -8.7433 0.10000E+01 0.0000 64 MnOH+ 0.46896E-09 -9.3289 0.39234E-09 -9.4063 0.83662E+00 -0.0775 65 MnO2-2 0.20906E-10 -10.6797 0.10825E-10 -10.9656 0.51777E+00 -0.2859 66 HMnO2- 0.21132E-09 -9.6751 0.17646E-09 -9.7534 0.83502E+00 -0.0783 69 MnCl+ 0.14910E-13 -13.8265 0.12474E-13 -13.9040 0.83662E+00 -0.0775 71 NaCl,aq 0.11567E-05 -5.9368 0.11567E-05 -5.9368 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93160E-02 -2.0308 0.77650E-02 -2.1099 0.83351E+00 -0.0791 79 HPO3-2 0.16313E-14 -14.7875 0.84465E-15 -15.0733 0.51777E+00 -0.2859 81 H2PO3- 0.15093E-18 -18.8212 0.12603E-18 -18.8995 0.83502E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38429E-10 -10.4153 0.32120E-10 -10.4932 0.83581E+00 -0.0779 84 PO4-3 0.10593E-08 -8.9750 0.25659E-09 -9.5908 0.24222E+00 -0.6158 88 HP2O7-3 0.94047E-18 -18.0267 0.21708E-18 -18.6634 0.23082E+00 -0.6367 89 P2O7-4 0.90689E-17 -17.0424 0.69698E-18 -18.1568 0.76854E-01 -1.1143 90 H2S,aq 0.89917E-08 -8.0462 0.89604E-08 -8.0477 0.99652E+00 -0.0015 91 S2-2 0.56094E-14 -14.2511 0.29044E-14 -14.5369 0.51777E+00 -0.2859 97 SO3-2 0.17577E-17 -17.7551 0.92329E-18 -18.0347 0.52528E+00 -0.2796 99 HSO4- 0.52525E-19 -19.2796 0.43987E-19 -19.3567 0.83744E+00 -0.0770 Charge balance for all species = 0.9551E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8857115E-10 -.2224710E-01 -.2238470E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981966E+06 0.0000 3 Cl- 0.2512893E-03 0.2524465E-03 0.8934403E+01 6.4503 4 SO4-- 0.1182200E-11 -.2555237E-04 -.2450328E+01 8.0445 5 HCO3- 0.4373791E-06 0.2391372E-04 0.1456608E+01 3.6916 6 HS- 0.4665563E-04 0.7221700E-04 0.2384202E+01 5.7190 7 Al+++ 0.9794275E-29 0.5301621E-05 0.1427966E+00 0.7390 8 H4SiO4 0.6959777E-03 0.1350510E-01 0.1295788E+04 -3.1574 9 Ca++ 0.1358952E-06 0.2330761E-06 0.9324963E-02 13.1018 10 Mg++ 0.2126006E-10 0.9355601E-10 0.2270574E-05 9.2942 11 Fe++ 0.5859628E-13 0.3619237E-07 0.2017716E-02 6.7350 12 K+ 0.1570080E-03 0.1577622E-03 0.6158079E+01 6.2467 13 Na+ 0.1992361E-01 0.2237045E-01 0.5133968E+03 8.3494 14 Mn++ 0.1879391E-10 0.2525826E-08 0.1385222E-03 9.2415 15 HPO4-- 0.4509178E-07 0.4618954E-07 0.4425508E-02 12.6260 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7451329E+02 -.1215911E-01 -.7450113E+02 0.0000000E+00 2 H2O -.9010836E+00 0.3033611E+02 -.3123719E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1247358E+00 -.1396561E-04 0.1247498E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1247103E+00 0.3947008E-04 -.1247498E+00 0.0000000E+00 7 Al+++ 0.1467333E+02 0.2897592E-05 0.1467333E+02 0.0000000E+00 8 H4SiO4 0.4685751E+02 0.7381187E-02 0.4685013E+02 0.0000000E+00 9 Ca++ 0.5175655E+01 0.1273874E-06 0.5175655E+01 0.0000000E+00 10 Mg++ 0.3571428E+01 0.5113288E-10 0.3571428E+01 0.0000000E+00 11 Fe++ 0.3208538E+01 0.1978088E-07 0.3208538E+01 0.0000000E+00 12 K+ 0.9554138E+00 0.8622467E-04 0.9553276E+00 0.0000000E+00 13 Na+ 0.5648755E+01 0.1222653E-01 0.5636529E+01 0.0000000E+00 14 Mn++ 0.7802366E-01 0.1380486E-08 0.7802366E-01 0.0000000E+00 15 HPO4-- 0.2662909E-01 0.2524481E-07 0.2662906E-01 0.0000000E+00 Chg. balance for solid moles: 0.2630E-13 Mass of aqueous solution: 0.547501E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.632 0.751 1477. 3.169 30.04 566.9 andradite 0.4990 -0.302 253.6 2.404 5.158 65.88 grossular 0.1208 -0.918 54.43 1.736 1.107 15.14 apatite-OH 0.8876E-02 -2.052 4.459 0.649 0.9070E-01 1.417 clinochlore 0.6394 -0.194 355.4 2.551 7.229 135.2 daphnite 0.1851 -0.733 132.1 2.121 2.687 40.02 chlorite-Mn 0.1560E-01 -1.807 11.06 1.044 0.2250 3.526 diopside 0.2355 -0.628 51.00 1.708 1.037 15.59 hedenbergite 0.6107E-01 -1.214 15.15 1.180 0.3082 4.150 microcline 0.8377 -0.077 233.2 2.368 4.743 91.08 stilbite 2.899 0.462 2043. 3.310 41.55 952.8 stilpnomelane-Fe 0.2352 -0.629 253.6 2.404 5.158 87.58 tr.625ac.25prg.125 0.3831E-01 -1.417 32.75 1.515 0.6661 10.54 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4916.084538 g Volume = 1989.762537 cm3 Porosity: -10.4810% V(tot) - V(min): -.18876E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4499.9990000 g log = 3.6532 Original solution: 1000.0103000 g Original solution / Rock added: 0.22 (Water/Rock Ratio), log = -0.6532 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0690 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9551E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5781E-08 1.0067 0.6222E-08 0.6180E-08 CH4,gas 0.3070E-01 1.0123 0.3322E-01 0.3282E-01 H2,gas 0.1422E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2314E-06 0.9958 0.2463E-06 0.2473E-06 S2,gas 0.9213E-29 1.0000 0.9848E-29 0.9848E-29 CO,gas 0.2359E-13 1.0000 0.2521E-13 0.2521E-13 SO3,gas 0.1201E-47 1.0000 0.1284E-47 0.1284E-47 SO2,gas 0.7107E-27 1.0000 0.7597E-27 0.7597E-27 HCl,gas 0.4723E-17 1.0000 0.5048E-17 0.5048E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.66728E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 -0.12132E-10 68 hedenbergite 14.21 14.21 0.00 0.000 -0.12132E-10 116 microcline -2.49 -2.49 0.00 0.000 -0.10616E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.57 -9.91 -3.302 0.16913E+05 -8.206 3 CH4,gas 4.54 1.37 -3.18 -0.794 0.54257E+04 -1.479 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.54 -8.31 -4.154 0.14185E+05 -6.609 6 S2,gas -7.34 -38.04 -30.71 -4.724 0.52429E+05 -29.007 7 CO,gas 3.21 -12.08 -15.30 -4.707 0.26120E+05 -13.598 8 SO3,gas 17.12 -32.47 -49.59 -12.398 0.84674E+05 -47.891 9 SO2,gas 0.83 -27.99 -28.82 -7.685 0.49207E+05 -27.119 10 HCl,gas 5.19 -13.81 -19.00 -9.498 0.32435E+05 -17.297 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80715E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.46 -4.43 -1.477 0.75639E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.46 -4.28 -1.425 0.72997E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65551E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.60 -4.50 -1.285 0.76788E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65868E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.60 -4.05 -1.158 0.69210E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82243E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.80 -3.54 -1.181 0.60486E+04 144 pyrrhotiteFe0.875 -6.02 -9.20 -3.18 -1.171 0.54358E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22446E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23249E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47130E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77495E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.80 -3.39 -1.131 0.57914E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.30 -4.32 -1.439 0.73735E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4499.9990000 g New total amount of reactant added: 4599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4599.9990000 Water: Moles liquid = 0.2978E+02 kg liquid = 0.5365E+00 Moles total = -.2155E+01 kg total = -.3882E-01 Activity = 1.0000 Stoichiometric ionic strength = .1141639E-01 Osmotic coef. = 0.9686 True ionic strength = .2008505E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88584E-10 -10.0526 0.74418E-10 -10.1283 0.84008E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.25599E-03 -3.5918 0.21376E-03 -3.6701 0.83501E+00 -0.0783 4 SO4-- 0.12042E-11 -11.9193 0.62481E-12 -12.2043 0.51886E+00 -0.2850 5 HCO3- 0.44551E-06 -6.3511 0.37256E-06 -6.4288 0.83624E+00 -0.0777 6 HS- 0.47529E-04 -4.3230 0.39693E-04 -4.4013 0.83513E+00 -0.0782 7 Al+++ 0.97993E-29 -29.0088 0.22594E-29 -29.6460 0.23057E+00 -0.6372 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13594E-06 -6.8667 0.70014E-07 -7.1548 0.51504E+00 -0.2882 10 Mg++ 0.21267E-10 -10.6723 0.10903E-10 -10.9625 0.51268E+00 -0.2902 11 Fe++ 0.58615E-13 -13.2320 0.30084E-13 -13.5217 0.51324E+00 -0.2897 12 K+ 0.15703E-03 -3.8040 0.13135E-03 -3.8816 0.83644E+00 -0.0776 13 Na+ 0.19927E-01 -1.7006 0.16636E-01 -1.7790 0.83486E+00 -0.0784 14 Mn++ 0.18801E-10 -10.7258 0.96573E-11 -11.0151 0.51366E+00 -0.2893 15 HPO4-- 0.45081E-07 -7.3460 0.23394E-07 -7.6309 0.51893E+00 -0.2849 16 HSiO3- 0.10458E-01 -1.9805 0.87326E-02 -2.0589 0.83501E+00 -0.0783 17 Ca(HSiO3)+ 0.16643E-07 -7.7788 0.13924E-07 -7.8562 0.83662E+00 -0.0775 18 Mg(HSiO3)+ 0.32255E-11 -11.4914 0.26985E-11 -11.5689 0.83662E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66344E-16 -16.1782 0.55504E-16 -16.2557 0.83662E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53008E-05 -5.2757 0.44182E-05 -5.3548 0.83350E+00 -0.0791 24 CH4,aq 0.23071E-04 -4.6369 0.22991E-04 -4.6385 0.99652E+00 -0.0015 25 C2H6,aq 0.78287E-14 -14.1063 0.78014E-14 -14.1078 0.99652E+00 -0.0015 29 CO,aq 0.17237E-16 -16.7635 0.17237E-16 -16.7635 0.10000E+01 0.0000 30 CO2,aq 0.59448E-10 -10.2259 0.59241E-10 -10.2274 0.99652E+00 -0.0015 31 CO3-2 0.84457E-06 -6.0734 0.43728E-06 -6.3592 0.51775E+00 -0.2859 32 CaCO3,aq 0.38388E-09 -9.4158 0.38388E-09 -9.4158 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.79585E-12 -12.0992 0.66582E-12 -12.1766 0.83662E+00 -0.0775 34 CaCl+ 0.28949E-10 -10.5384 0.24220E-10 -10.6158 0.83662E+00 -0.0775 35 CaCl2,aq 0.12300E-14 -14.9101 0.12300E-14 -14.9101 0.10000E+01 0.0000 36 CaOH+ 0.80146E-07 -7.0961 0.67052E-07 -7.1736 0.83662E+00 -0.0775 37 CaSO4,aq 0.13891E-16 -16.8573 0.13891E-16 -16.8573 0.10000E+01 0.0000 38 HCl,aq 0.29149E-14 -14.5354 0.29149E-14 -14.5354 0.10000E+01 0.0000 43 FeCl+ 0.12166E-16 -16.9148 0.10179E-16 -16.9923 0.83662E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15729E-10 -10.8033 0.13159E-10 -10.8808 0.83662E+00 -0.0775 48 HFeO2- 0.35549E-07 -7.4492 0.29684E-07 -7.5275 0.83501E+00 -0.0783 49 FeO+ 0.11023E-16 -16.9577 0.92223E-17 -17.0352 0.83662E+00 -0.0775 51 FeO2- 0.40808E-09 -9.3893 0.34075E-09 -9.4676 0.83501E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.50886E-09 -9.2934 0.50886E-09 -9.2934 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.15251E-14 -14.8167 0.12735E-14 -14.8950 0.83501E+00 -0.0783 58 MgCO3,aq 0.14985E-13 -13.8244 0.14985E-13 -13.8244 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12664E-15 -15.8974 0.10595E-15 -15.9749 0.83662E+00 -0.0775 60 MgCl+ 0.40860E-14 -14.3887 0.34184E-14 -14.4662 0.83662E+00 -0.0775 61 MgOH+ 0.69063E-10 -10.1608 0.57780E-10 -10.2382 0.83662E+00 -0.0775 63 MnO,aq 0.18059E-08 -8.7433 0.18059E-08 -8.7433 0.10000E+01 0.0000 64 MnOH+ 0.46905E-09 -9.3288 0.39241E-09 -9.4063 0.83662E+00 -0.0775 65 MnO2-2 0.20902E-10 -10.6798 0.10822E-10 -10.9657 0.51775E+00 -0.2859 66 HMnO2- 0.21130E-09 -9.6751 0.17644E-09 -9.7534 0.83501E+00 -0.0783 69 MnCl+ 0.15194E-13 -13.8183 0.12712E-13 -13.8958 0.83662E+00 -0.0775 71 NaCl,aq 0.11785E-05 -5.9287 0.11785E-05 -5.9287 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93148E-02 -2.0308 0.77639E-02 -2.1099 0.83350E+00 -0.0791 79 HPO3-2 0.16309E-14 -14.7876 0.84441E-15 -15.0734 0.51775E+00 -0.2859 81 H2PO3- 0.15091E-18 -18.8213 0.12601E-18 -18.8996 0.83501E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38424E-10 -10.4154 0.32115E-10 -10.4933 0.83581E+00 -0.0779 84 PO4-3 0.10590E-08 -8.9751 0.25648E-09 -9.5909 0.24220E+00 -0.6158 88 HP2O7-3 0.94016E-18 -18.0268 0.21699E-18 -18.6636 0.23080E+00 -0.6368 89 P2O7-4 0.90653E-17 -17.0426 0.69659E-18 -18.1570 0.76841E-01 -1.1144 90 H2S,aq 0.91612E-08 -8.0380 0.91293E-08 -8.0396 0.99652E+00 -0.0015 91 S2-2 0.58215E-14 -14.2350 0.30141E-14 -14.5208 0.51775E+00 -0.2859 97 SO3-2 0.17904E-17 -17.7470 0.94043E-18 -18.0267 0.52526E+00 -0.2796 99 HSO4- 0.53508E-19 -19.2716 0.44810E-19 -19.3486 0.83743E+00 -0.0771 Charge balance for all species = 0.9734E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8858447E-10 -.2224453E-01 -.2238211E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981964E+06 0.0000 3 Cl- 0.2559929E-03 0.2571719E-03 0.9101641E+01 6.4582 4 SO4-- 0.1204201E-11 -.2597653E-04 -.2491002E+01 8.0524 5 HCO3- 0.4455142E-06 0.2436135E-04 0.1483873E+01 3.6995 6 HS- 0.4752896E-04 0.7351465E-04 0.2427043E+01 5.7270 7 Al+++ 0.9799295E-29 0.5300921E-05 0.1427778E+00 0.7390 8 H4SiO4 0.6959780E-03 0.1350373E-01 0.1295657E+04 -3.1574 9 Ca++ 0.1359389E-06 0.2331421E-06 0.9327600E-02 13.1018 10 Mg++ 0.2126692E-10 0.9357561E-10 0.2271049E-05 9.2942 11 Fe++ 0.5861519E-13 0.3618766E-07 0.2017454E-02 6.7350 12 K+ 0.1570317E-03 0.1577859E-03 0.6159003E+01 6.2467 13 Na+ 0.1992662E-01 0.2237348E-01 0.5134664E+03 8.3494 14 Mn++ 0.1880079E-10 0.2525978E-08 0.1385306E-03 9.2415 15 HPO4-- 0.4508090E-07 0.4617829E-07 0.4424430E-02 12.6257 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7616914E+02 -.1193432E-01 -.7615721E+02 0.0000000E+00 2 H2O -.2154625E+01 0.2977869E+02 -.3193332E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1275072E+00 -.1393656E-04 0.1275211E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1274817E+00 0.3944103E-04 -.1275211E+00 0.0000000E+00 7 Al+++ 0.1499941E+02 0.2843974E-05 0.1499941E+02 0.0000000E+00 8 H4SiO4 0.4789879E+02 0.7244830E-02 0.4789155E+02 0.0000000E+00 9 Ca++ 0.5290670E+01 0.1250821E-06 0.5290669E+01 0.0000000E+00 10 Mg++ 0.3650793E+01 0.5020384E-10 0.3650793E+01 0.0000000E+00 11 Fe++ 0.3279839E+01 0.1941489E-07 0.3279839E+01 0.0000000E+00 12 K+ 0.9766452E+00 0.8465305E-04 0.9765606E+00 0.0000000E+00 13 Na+ 0.5774279E+01 0.1200350E-01 0.5762276E+01 0.0000000E+00 14 Mn++ 0.7975752E-01 0.1355202E-08 0.7975752E-01 0.0000000E+00 15 HPO4-- 0.2722085E-01 0.2477492E-07 0.2722082E-01 0.0000000E+00 Chg. balance for solid moles: -.1522E-13 Mass of aqueous solution: 0.537441E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.757 0.760 1510. 3.179 30.04 579.5 andradite 0.5101 -0.292 259.2 2.414 5.158 67.35 grossular 0.1235 -0.908 55.64 1.745 1.107 15.48 apatite-OH 0.9074E-02 -2.042 4.558 0.659 0.9070E-01 1.448 clinochlore 0.6536 -0.185 363.3 2.560 7.229 138.2 daphnite 0.1892 -0.723 135.0 2.130 2.686 40.91 chlorite-Mn 0.1595E-01 -1.797 11.31 1.053 0.2250 3.604 diopside 0.2409 -0.618 52.18 1.717 1.038 15.95 hedenbergite 0.6248E-01 -1.204 15.50 1.190 0.3085 4.246 microcline 0.8563 -0.067 238.4 2.377 4.743 93.11 stilbite 2.963 0.472 2088. 3.320 41.55 973.9 stilpnomelane-Fe 0.2404 -0.619 259.2 2.414 5.158 89.53 tr.625ac.25prg.125 0.3915E-01 -1.407 33.46 1.525 0.6658 10.77 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5025.335203 g Volume = 2033.965602 cm3 Porosity: -10.4816% V(tot) - V(min): -.19297E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4599.9990000 g log = 3.6628 Original solution: 1000.0103000 g Original solution / Rock added: 0.22 (Water/Rock Ratio), log = -0.6628 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0696 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9545E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5886E-08 1.0067 0.6338E-08 0.6296E-08 CH4,gas 0.3125E-01 1.0123 0.3384E-01 0.3343E-01 H2,gas 0.1421E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2356E-06 0.9958 0.2510E-06 0.2520E-06 S2,gas 0.9558E-29 1.0000 0.1022E-28 0.1022E-28 CO,gas 0.2401E-13 1.0000 0.2569E-13 0.2569E-13 SO3,gas 0.1223E-47 1.0000 0.1308E-47 0.1308E-47 SO2,gas 0.7236E-27 1.0000 0.7740E-27 0.7740E-27 HCl,gas 0.4809E-17 1.0000 0.5143E-17 0.5143E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 0.24265E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.21232E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.56 -9.90 -3.299 0.16899E+05 -8.198 3 CH4,gas 4.54 1.37 -3.17 -0.792 0.54119E+04 -1.471 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.53 -8.30 -4.150 0.14171E+05 -6.600 6 S2,gas -7.34 -38.02 -30.69 -4.721 0.52401E+05 -28.990 7 CO,gas 3.21 -12.07 -15.29 -4.704 0.26106E+05 -13.590 8 SO3,gas 17.12 -32.46 -49.58 -12.396 0.84660E+05 -47.883 9 SO2,gas 0.83 -27.98 -28.81 -7.683 0.49193E+05 -27.111 10 HCl,gas 5.19 -13.80 -18.99 -9.494 0.32421E+05 -17.289 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80714E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.46 -4.42 -1.474 0.75501E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.46 -4.27 -1.422 0.72859E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65550E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.59 -4.49 -1.283 0.76650E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.59 -4.05 -1.156 0.69073E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82242E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.79 -3.53 -1.178 0.60347E+04 144 pyrrhotiteFe0.875 -6.02 -9.19 -3.18 -1.168 0.54220E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22446E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23249E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47129E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.79 -3.38 -1.128 0.57775E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.29 -4.31 -1.437 0.73596E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4599.9990000 g New total amount of reactant added: 4699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4699.9990000 Water: Moles liquid = 0.2922E+02 kg liquid = 0.5265E+00 Moles total = -.3408E+01 kg total = -.6140E-01 Activity = 1.0000 Stoichiometric ionic strength = .1142045E-01 Osmotic coef. = 0.9686 True ionic strength = .2008822E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88598E-10 -10.0526 0.74429E-10 -10.1283 0.84007E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.26088E-03 -3.5836 0.21783E-03 -3.6619 0.83500E+00 -0.0783 4 SO4-- 0.12270E-11 -11.9111 0.63663E-12 -12.1961 0.51883E+00 -0.2850 5 HCO3- 0.45396E-06 -6.3430 0.37961E-06 -6.4207 0.83623E+00 -0.0777 6 HS- 0.48436E-04 -4.3148 0.40450E-04 -4.3931 0.83513E+00 -0.0782 7 Al+++ 0.98045E-29 -29.0086 0.22604E-29 -29.6458 0.23055E+00 -0.6372 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13598E-06 -6.8665 0.70034E-07 -7.1547 0.51502E+00 -0.2882 10 Mg++ 0.21274E-10 -10.6721 0.10906E-10 -10.9623 0.51265E+00 -0.2902 11 Fe++ 0.58635E-13 -13.2318 0.30092E-13 -13.5215 0.51322E+00 -0.2897 12 K+ 0.15706E-03 -3.8039 0.13137E-03 -3.8815 0.83643E+00 -0.0776 13 Na+ 0.19930E-01 -1.7005 0.16638E-01 -1.7789 0.83485E+00 -0.0784 14 Mn++ 0.18808E-10 -10.7257 0.96605E-11 -11.0150 0.51364E+00 -0.2893 15 HPO4-- 0.45070E-07 -7.3461 0.23387E-07 -7.6310 0.51891E+00 -0.2849 16 HSiO3- 0.10457E-01 -1.9806 0.87314E-02 -2.0589 0.83500E+00 -0.0783 17 Ca(HSiO3)+ 0.16646E-07 -7.7787 0.13926E-07 -7.8562 0.83661E+00 -0.0775 18 Mg(HSiO3)+ 0.32260E-11 -11.4913 0.26989E-11 -11.5688 0.83661E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66354E-16 -16.1781 0.55512E-16 -16.2556 0.83661E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.53000E-05 -5.2757 0.44175E-05 -5.3548 0.83349E+00 -0.0791 24 CH4,aq 0.23511E-04 -4.6287 0.23429E-04 -4.6302 0.99652E+00 -0.0015 25 C2H6,aq 0.81304E-14 -14.0899 0.81021E-14 -14.0914 0.99652E+00 -0.0015 29 CO,aq 0.17566E-16 -16.7553 0.17566E-16 -16.7553 0.10000E+01 0.0000 30 CO2,aq 0.60583E-10 -10.2176 0.60372E-10 -10.2192 0.99652E+00 -0.0015 31 CO3-2 0.86048E-06 -6.0653 0.44550E-06 -6.3512 0.51773E+00 -0.2859 32 CaCO3,aq 0.39121E-09 -9.4076 0.39121E-09 -9.4076 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.81117E-12 -12.0909 0.67863E-12 -12.1684 0.83661E+00 -0.0775 34 CaCl+ 0.29510E-10 -10.5300 0.24688E-10 -10.6075 0.83661E+00 -0.0775 35 CaCl2,aq 0.12777E-14 -14.8936 0.12777E-14 -14.8936 0.10000E+01 0.0000 36 CaOH+ 0.80159E-07 -7.0960 0.67061E-07 -7.1735 0.83661E+00 -0.0775 37 CaSO4,aq 0.14158E-16 -16.8490 0.14158E-16 -16.8490 0.10000E+01 0.0000 38 HCl,aq 0.29710E-14 -14.5271 0.29710E-14 -14.5271 0.10000E+01 0.0000 43 FeCl+ 0.12402E-16 -16.9065 0.10376E-16 -16.9840 0.83661E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15731E-10 -10.8032 0.13161E-10 -10.8807 0.83661E+00 -0.0775 48 HFeO2- 0.35545E-07 -7.4492 0.29680E-07 -7.5275 0.83500E+00 -0.0783 49 FeO+ 0.11025E-16 -16.9576 0.92237E-17 -17.0351 0.83661E+00 -0.0775 51 FeO2- 0.40802E-09 -9.3893 0.34070E-09 -9.4676 0.83500E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.51864E-09 -9.2851 0.51864E-09 -9.2851 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.15542E-14 -14.8085 0.12978E-14 -14.8868 0.83500E+00 -0.0783 58 MgCO3,aq 0.15271E-13 -13.8161 0.15271E-13 -13.8161 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12908E-15 -15.8892 0.10799E-15 -15.9666 0.83661E+00 -0.0775 60 MgCl+ 0.41651E-14 -14.3804 0.34846E-14 -14.4578 0.83661E+00 -0.0775 61 MgOH+ 0.69074E-10 -10.1607 0.57788E-10 -10.2382 0.83661E+00 -0.0775 63 MnO,aq 0.18060E-08 -8.7433 0.18060E-08 -8.7433 0.10000E+01 0.0000 64 MnOH+ 0.46914E-09 -9.3287 0.39249E-09 -9.4062 0.83661E+00 -0.0775 65 MnO2-2 0.20898E-10 -10.6799 0.10819E-10 -10.9658 0.51773E+00 -0.2859 66 HMnO2- 0.21128E-09 -9.6751 0.17642E-09 -9.7534 0.83500E+00 -0.0783 69 MnCl+ 0.15489E-13 -13.8100 0.12959E-13 -13.8874 0.83661E+00 -0.0775 71 NaCl,aq 0.12011E-05 -5.9204 0.12011E-05 -5.9204 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93136E-02 -2.0309 0.77628E-02 -2.1100 0.83349E+00 -0.0791 79 HPO3-2 0.16305E-14 -14.7877 0.84416E-15 -15.0736 0.51773E+00 -0.2859 81 H2PO3- 0.15089E-18 -18.8213 0.12599E-18 -18.8997 0.83500E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38419E-10 -10.4155 0.32111E-10 -10.4934 0.83580E+00 -0.0779 84 PO4-3 0.10586E-08 -8.9753 0.25637E-09 -9.5911 0.24218E+00 -0.6159 88 HP2O7-3 0.93983E-18 -18.0269 0.21690E-18 -18.6637 0.23078E+00 -0.6368 89 P2O7-4 0.90615E-17 -17.0428 0.69618E-18 -18.1573 0.76829E-01 -1.1145 90 H2S,aq 0.93372E-08 -8.0298 0.93047E-08 -8.0313 0.99652E+00 -0.0015 91 S2-2 0.60458E-14 -14.2185 0.31301E-14 -14.5044 0.51773E+00 -0.2859 97 SO3-2 0.18244E-17 -17.7389 0.95822E-18 -18.0185 0.52524E+00 -0.2796 99 HSO4- 0.54529E-19 -19.2634 0.45664E-19 -19.3404 0.83742E+00 -0.0771 Charge balance for all species = 0.9925E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8859831E-10 -.2224187E-01 -.2237943E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981963E+06 0.0000 3 Cl- 0.2608760E-03 0.2620776E-03 0.9275259E+01 6.4664 4 SO4-- 0.1227036E-11 -.2641688E-04 -.2533229E+01 8.0604 5 HCO3- 0.4539575E-06 0.2482606E-04 0.1512179E+01 3.7076 6 HS- 0.4843560E-04 0.7486182E-04 0.2471519E+01 5.7352 7 Al+++ 0.9804509E-29 0.5300195E-05 0.1427582E+00 0.7390 8 H4SiO4 0.6959784E-03 0.1350232E-01 0.1295521E+04 -3.1574 9 Ca++ 0.1359844E-06 0.2332106E-06 0.9330339E-02 13.1018 10 Mg++ 0.2127404E-10 0.9359342E-10 0.2271481E-05 9.2942 11 Fe++ 0.5863484E-13 0.3618278E-07 0.2017181E-02 6.7350 12 K+ 0.1570563E-03 0.1578106E-03 0.6159964E+01 6.2467 13 Na+ 0.1992975E-01 0.2237664E-01 0.5135386E+03 8.3494 14 Mn++ 0.1880786E-10 0.2526128E-08 0.1385388E-03 9.2415 15 HPO4-- 0.4506960E-07 0.4616662E-07 0.4423311E-02 12.6255 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7782499E+02 -.1170952E-01 -.7781328E+02 0.0000000E+00 2 H2O -.3408166E+01 0.2922128E+02 -.3262944E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1302785E+00 -.1390751E-04 0.1302924E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1302530E+00 0.3941198E-04 -.1302924E+00 0.0000000E+00 7 Al+++ 0.1532548E+02 0.2790356E-05 0.1532548E+02 0.0000000E+00 8 H4SiO4 0.4894007E+02 0.7108473E-02 0.4893296E+02 0.0000000E+00 9 Ca++ 0.5405684E+01 0.1227767E-06 0.5405684E+01 0.0000000E+00 10 Mg++ 0.3730158E+01 0.4927347E-10 0.3730158E+01 0.0000000E+00 11 Fe++ 0.3351140E+01 0.1904889E-07 0.3351140E+01 0.0000000E+00 12 K+ 0.9978766E+00 0.8308142E-04 0.9977936E+00 0.0000000E+00 13 Na+ 0.5899804E+01 0.1178047E-01 0.5888023E+01 0.0000000E+00 14 Mn++ 0.8149138E-01 0.1329913E-08 0.8149138E-01 0.0000000E+00 15 HPO4-- 0.2781260E-01 0.2430502E-07 0.2781258E-01 0.0000000E+00 Chg. balance for solid moles: -.4441E-15 Mass of aqueous solution: 0.527381E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.883 0.770 1543. 3.188 30.04 592.2 andradite 0.5212 -0.283 264.8 2.423 5.158 68.81 grossular 0.1262 -0.899 56.85 1.755 1.107 15.82 apatite-OH 0.9271E-02 -2.033 4.657 0.668 0.9070E-01 1.480 clinochlore 0.6678 -0.175 371.2 2.570 7.229 141.2 daphnite 0.1933 -0.714 137.9 2.140 2.686 41.80 chlorite-Mn 0.1630E-01 -1.788 11.55 1.063 0.2250 3.682 diopside 0.2464 -0.608 53.36 1.727 1.039 16.31 hedenbergite 0.6389E-01 -1.195 15.85 1.200 0.3087 4.342 microcline 0.8750 -0.058 243.5 2.387 4.743 95.13 stilbite 3.027 0.481 2133. 3.329 41.55 995.0 stilpnomelane-Fe 0.2457 -0.610 264.8 2.423 5.158 91.48 tr.625ac.25prg.125 0.3998E-01 -1.398 34.17 1.534 0.6656 11.00 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5134.585867 g Volume = 2078.168666 cm3 Porosity: -10.4821% V(tot) - V(min): -.19717E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4699.9990000 g log = 3.6721 Original solution: 1000.0103000 g Original solution / Rock added: 0.21 (Water/Rock Ratio), log = -0.6721 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0703 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9540E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.5995E-08 1.0067 0.6459E-08 0.6416E-08 CH4,gas 0.3183E-01 1.0123 0.3449E-01 0.3407E-01 H2,gas 0.1420E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2400E-06 0.9958 0.2558E-06 0.2568E-06 S2,gas 0.9923E-29 1.0000 0.1062E-28 0.1062E-28 CO,gas 0.2446E-13 1.0000 0.2618E-13 0.2618E-13 SO3,gas 0.1246E-47 1.0000 0.1333E-47 0.1333E-47 SO2,gas 0.7371E-27 1.0000 0.7889E-27 0.7889E-27 HCl,gas 0.4898E-17 1.0000 0.5242E-17 0.5242E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.13080E-10 22 andradite 39.01 39.01 0.00 0.000 0.00000E+00 23 grossular 32.73 32.73 0.00 0.000 -0.36397E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 -0.30331E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 0.69761E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.55 -9.89 -3.296 0.16885E+05 -8.190 3 CH4,gas 4.54 1.38 -3.16 -0.790 0.53979E+04 -1.462 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.52 -8.29 -4.146 0.14157E+05 -6.592 6 S2,gas -7.34 -38.01 -30.67 -4.719 0.52373E+05 -28.974 7 CO,gas 3.21 -12.07 -15.28 -4.702 0.26092E+05 -13.582 8 SO3,gas 17.12 -32.45 -49.57 -12.393 0.84646E+05 -47.875 9 SO2,gas 0.83 -27.97 -28.80 -7.681 0.49179E+05 -27.103 10 HCl,gas 5.19 -13.79 -18.98 -9.490 0.32407E+05 -17.280 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80713E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.45 -4.41 -1.471 0.75361E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.45 -4.26 -1.420 0.72719E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65550E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.58 -4.48 -1.280 0.76510E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.58 -4.04 -1.153 0.68932E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82242E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.79 -3.53 -1.175 0.60206E+04 144 pyrrhotiteFe0.875 -6.02 -9.18 -3.17 -1.165 0.54078E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22446E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23248E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47129E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.79 -3.38 -1.125 0.57634E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.28 -4.30 -1.434 0.73455E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4699.9990000 g New total amount of reactant added: 4799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4799.9990000 Water: Moles liquid = 0.2867E+02 kg liquid = 0.5164E+00 Moles total = -.4662E+01 kg total = -.8398E-01 Activity = 1.0000 Stoichiometric ionic strength = .1142467E-01 Osmotic coef. = 0.9686 True ionic strength = .2009151E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88613E-10 -10.0525 0.74440E-10 -10.1282 0.84006E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.26595E-03 -3.5752 0.22207E-03 -3.6535 0.83499E+00 -0.0783 4 SO4-- 0.12508E-11 -11.9028 0.64891E-12 -12.1878 0.51881E+00 -0.2850 5 HCO3- 0.46273E-06 -6.3347 0.38694E-06 -6.4124 0.83622E+00 -0.0777 6 HS- 0.49378E-04 -4.3065 0.41236E-04 -4.3847 0.83512E+00 -0.0783 7 Al+++ 0.98099E-29 -29.0083 0.22615E-29 -29.6456 0.23053E+00 -0.6373 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13603E-06 -6.8664 0.70055E-07 -7.1546 0.51499E+00 -0.2882 10 Mg++ 0.21281E-10 -10.6720 0.10910E-10 -10.9622 0.51263E+00 -0.2902 11 Fe++ 0.58655E-13 -13.2317 0.30102E-13 -13.5214 0.51319E+00 -0.2897 12 K+ 0.15708E-03 -3.8039 0.13139E-03 -3.8815 0.83642E+00 -0.0776 13 Na+ 0.19933E-01 -1.7004 0.16641E-01 -1.7788 0.83484E+00 -0.0784 14 Mn++ 0.18815E-10 -10.7255 0.96638E-11 -11.0149 0.51362E+00 -0.2894 15 HPO4-- 0.45058E-07 -7.3462 0.23380E-07 -7.6312 0.51889E+00 -0.2849 16 HSiO3- 0.10455E-01 -1.9807 0.87300E-02 -2.0590 0.83499E+00 -0.0783 17 Ca(HSiO3)+ 0.16649E-07 -7.7786 0.13928E-07 -7.8561 0.83660E+00 -0.0775 18 Mg(HSiO3)+ 0.32266E-11 -11.4913 0.26993E-11 -11.5687 0.83660E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66365E-16 -16.1781 0.55521E-16 -16.2555 0.83660E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52993E-05 -5.2758 0.44169E-05 -5.3549 0.83348E+00 -0.0791 24 CH4,aq 0.23969E-04 -4.6204 0.23885E-04 -4.6219 0.99652E+00 -0.0015 25 C2H6,aq 0.84499E-14 -14.0732 0.84204E-14 -14.0747 0.99652E+00 -0.0015 29 CO,aq 0.17908E-16 -16.7470 0.17908E-16 -16.7470 0.10000E+01 0.0000 30 CO2,aq 0.61762E-10 -10.2093 0.61547E-10 -10.2108 0.99652E+00 -0.0015 31 CO3-2 0.87699E-06 -6.0570 0.45403E-06 -6.3429 0.51771E+00 -0.2859 32 CaCO3,aq 0.39882E-09 -9.3992 0.39882E-09 -9.3992 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.82709E-12 -12.0824 0.69194E-12 -12.1599 0.83660E+00 -0.0775 34 CaCl+ 0.30093E-10 -10.5215 0.25176E-10 -10.5990 0.83660E+00 -0.0775 35 CaCl2,aq 0.13282E-14 -14.8767 0.13282E-14 -14.8767 0.10000E+01 0.0000 36 CaOH+ 0.80172E-07 -7.0960 0.67072E-07 -7.1735 0.83660E+00 -0.0775 37 CaSO4,aq 0.14435E-16 -16.8406 0.14435E-16 -16.8406 0.10000E+01 0.0000 38 HCl,aq 0.30292E-14 -14.5187 0.30292E-14 -14.5187 0.10000E+01 0.0000 43 FeCl+ 0.12647E-16 -16.8980 0.10580E-16 -16.9755 0.83660E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15734E-10 -10.8032 0.13163E-10 -10.8807 0.83660E+00 -0.0775 48 HFeO2- 0.35540E-07 -7.4493 0.29675E-07 -7.5276 0.83499E+00 -0.0783 49 FeO+ 0.11027E-16 -16.9575 0.92251E-17 -17.0350 0.83660E+00 -0.0775 51 FeO2- 0.40797E-09 -9.3894 0.34065E-09 -9.4677 0.83499E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.52880E-09 -9.2767 0.52880E-09 -9.2767 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.15844E-14 -14.8001 0.13230E-14 -14.8784 0.83499E+00 -0.0783 58 MgCO3,aq 0.15568E-13 -13.8078 0.15568E-13 -13.8078 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13161E-15 -15.8807 0.11010E-15 -15.9582 0.83660E+00 -0.0775 60 MgCl+ 0.42474E-14 -14.3719 0.35534E-14 -14.4494 0.83660E+00 -0.0775 61 MgOH+ 0.69085E-10 -10.1606 0.57797E-10 -10.2381 0.83660E+00 -0.0775 63 MnO,aq 0.18061E-08 -8.7433 0.18061E-08 -8.7433 0.10000E+01 0.0000 64 MnOH+ 0.46924E-09 -9.3286 0.39256E-09 -9.4061 0.83660E+00 -0.0775 65 MnO2-2 0.20893E-10 -10.6800 0.10817E-10 -10.9659 0.51771E+00 -0.2859 66 HMnO2- 0.21126E-09 -9.6752 0.17640E-09 -9.7535 0.83499E+00 -0.0783 69 MnCl+ 0.15796E-13 -13.8015 0.13215E-13 -13.8789 0.83660E+00 -0.0775 71 NaCl,aq 0.12247E-05 -5.9120 0.12247E-05 -5.9120 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93123E-02 -2.0309 0.77616E-02 -2.1100 0.83348E+00 -0.0791 79 HPO3-2 0.16301E-14 -14.7878 0.84390E-15 -15.0737 0.51771E+00 -0.2859 81 H2PO3- 0.15087E-18 -18.8214 0.12597E-18 -18.8997 0.83499E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38414E-10 -10.4155 0.32106E-10 -10.4934 0.83579E+00 -0.0779 84 PO4-3 0.10582E-08 -8.9754 0.25625E-09 -9.5913 0.24216E+00 -0.6159 88 HP2O7-3 0.93950E-18 -18.0271 0.21680E-18 -18.6639 0.23076E+00 -0.6368 89 P2O7-4 0.90575E-17 -17.0430 0.69576E-18 -18.1575 0.76816E-01 -1.1145 90 H2S,aq 0.95201E-08 -8.0214 0.94870E-08 -8.0229 0.99652E+00 -0.0015 91 S2-2 0.62834E-14 -14.2018 0.32530E-14 -14.4877 0.51771E+00 -0.2859 97 SO3-2 0.18596E-17 -17.7306 0.97670E-18 -18.0102 0.52522E+00 -0.2797 99 HSO4- 0.55590E-19 -19.2550 0.46552E-19 -19.3321 0.83741E+00 -0.0771 Charge balance for all species = 0.1012E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8861269E-10 -.2223910E-01 -.2237664E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981961E+06 0.0000 3 Cl- 0.2659489E-03 0.2671742E-03 0.9455630E+01 6.4747 4 SO4-- 0.1250752E-11 -.2687437E-04 -.2577099E+01 8.0686 5 HCO3- 0.4627269E-06 0.2530884E-04 0.1541585E+01 3.7158 6 HS- 0.4937751E-04 0.7626140E-04 0.2517725E+01 5.7435 7 Al+++ 0.9809930E-29 0.5299441E-05 0.1427379E+00 0.7390 8 H4SiO4 0.6959787E-03 0.1350085E-01 0.1295380E+04 -3.1574 9 Ca++ 0.1360316E-06 0.2332818E-06 0.9333185E-02 13.1018 10 Mg++ 0.2128145E-10 0.9361365E-10 0.2271972E-05 9.2942 11 Fe++ 0.5865525E-13 0.3617770E-07 0.2016898E-02 6.7350 12 K+ 0.1570819E-03 0.1578361E-03 0.6160961E+01 6.2467 13 Na+ 0.1993300E-01 0.2237991E-01 0.5136137E+03 8.3494 14 Mn++ 0.1881515E-10 0.2526275E-08 0.1385468E-03 9.2415 15 HPO4-- 0.4505786E-07 0.4615449E-07 0.4422148E-02 12.6252 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7948084E+02 -.1148472E-01 -.7946936E+02 0.0000000E+00 2 H2O -.4661707E+01 0.2866386E+02 -.3332557E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1330498E+00 -.1387847E-04 0.1330637E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1330243E+00 0.3938294E-04 -.1330637E+00 0.0000000E+00 7 Al+++ 0.1565156E+02 0.2736739E-05 0.1565155E+02 0.0000000E+00 8 H4SiO4 0.4998135E+02 0.6972116E-02 0.4997438E+02 0.0000000E+00 9 Ca++ 0.5520698E+01 0.1204715E-06 0.5520698E+01 0.0000000E+00 10 Mg++ 0.3809523E+01 0.4834400E-10 0.3809523E+01 0.0000000E+00 11 Fe++ 0.3422441E+01 0.1868290E-07 0.3422441E+01 0.0000000E+00 12 K+ 0.1019108E+01 0.8150980E-04 0.1019027E+01 0.0000000E+00 13 Na+ 0.6025328E+01 0.1155744E-01 0.6013771E+01 0.0000000E+00 14 Mn++ 0.8322524E-01 0.1304620E-08 0.8322524E-01 0.0000000E+00 15 HPO4-- 0.2840436E-01 0.2383512E-07 0.2840434E-01 0.0000000E+00 Chg. balance for solid moles: -.8583E-14 Mass of aqueous solution: 0.517321E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.009 0.779 1576. 3.197 30.05 604.8 andradite 0.5323 -0.274 270.5 2.432 5.158 70.27 grossular 0.1289 -0.890 58.05 1.764 1.107 16.15 apatite-OH 0.9468E-02 -2.024 4.756 0.677 0.9070E-01 1.511 clinochlore 0.6820 -0.166 379.0 2.579 7.228 144.2 daphnite 0.1974 -0.705 140.9 2.149 2.686 42.69 chlorite-Mn 0.1665E-01 -1.779 11.80 1.072 0.2250 3.761 diopside 0.2518 -0.599 54.53 1.737 1.040 16.67 hedenbergite 0.6530E-01 -1.185 16.20 1.210 0.3090 4.438 microcline 0.8936 -0.049 248.7 2.396 4.743 97.16 stilbite 3.091 0.490 2178. 3.338 41.54 1016. stilpnomelane-Fe 0.2509 -0.600 270.5 2.432 5.158 93.43 tr.625ac.25prg.125 0.4081E-01 -1.389 34.89 1.543 0.6653 11.23 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5243.836532 g Volume = 2122.371730 cm3 Porosity: -10.4827% V(tot) - V(min): -.20137E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4799.9990000 g log = 3.6812 Original solution: 1000.0103000 g Original solution / Rock added: 0.21 (Water/Rock Ratio), log = -0.6812 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0709 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9534E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.6108E-08 1.0067 0.6585E-08 0.6541E-08 CH4,gas 0.3243E-01 1.0123 0.3516E-01 0.3473E-01 H2,gas 0.1419E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2445E-06 0.9958 0.2608E-06 0.2619E-06 S2,gas 0.1031E-28 1.0000 0.1104E-28 0.1104E-28 CO,gas 0.2492E-13 1.0000 0.2669E-13 0.2669E-13 SO3,gas 0.1270E-47 1.0000 0.1360E-47 0.1360E-47 SO2,gas 0.7511E-27 1.0000 0.8043E-27 0.8043E-27 HCl,gas 0.4991E-17 1.0000 0.5345E-17 0.5345E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.84926E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.54 -9.88 -3.293 0.16871E+05 -8.181 3 CH4,gas 4.54 1.39 -3.15 -0.788 0.53836E+04 -1.454 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.51 -8.28 -4.141 0.14142E+05 -6.584 6 S2,gas -7.34 -37.99 -30.66 -4.716 0.52344E+05 -28.957 7 CO,gas 3.21 -12.06 -15.27 -4.699 0.26078E+05 -13.574 8 SO3,gas 17.12 -32.44 -49.57 -12.391 0.84632E+05 -47.867 9 SO2,gas 0.83 -27.96 -28.79 -7.678 0.49164E+05 -27.095 10 HCl,gas 5.19 -13.78 -18.97 -9.486 0.32393E+05 -17.272 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80712E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.44 -4.41 -1.468 0.75218E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.44 -4.25 -1.417 0.72576E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70315E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65550E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.57 -4.47 -1.278 0.76367E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37133E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.57 -4.03 -1.151 0.68789E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82242E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.78 -3.52 -1.173 0.60062E+04 144 pyrrhotiteFe0.875 -6.02 -9.18 -3.16 -1.162 0.53935E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23248E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47128E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.78 -3.37 -1.122 0.57490E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.27 -4.29 -1.431 0.73311E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4799.9990000 g New total amount of reactant added: 4899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5222E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4899.9990000 Water: Moles liquid = 0.2811E+02 kg liquid = 0.5064E+00 Moles total = -.5915E+01 kg total = -.1066E+00 Activity = 1.0000 Stoichiometric ionic strength = .1142906E-01 Osmotic coef. = 0.9685 True ionic strength = .2009494E-01 Chg. balance for total moles = 0.5222E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88628E-10 -10.0524 0.74452E-10 -10.1281 0.84005E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27122E-03 -3.5667 0.22647E-03 -3.6450 0.83498E+00 -0.0783 4 SO4-- 0.12754E-11 -11.8944 0.66167E-12 -12.1794 0.51879E+00 -0.2850 5 HCO3- 0.47184E-06 -6.3262 0.39456E-06 -6.4039 0.83621E+00 -0.0777 6 HS- 0.50357E-04 -4.2979 0.42053E-04 -4.3762 0.83511E+00 -0.0783 7 Al+++ 0.98156E-29 -29.0081 0.22625E-29 -29.6454 0.23050E+00 -0.6373 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13608E-06 -6.8662 0.70077E-07 -7.1544 0.51497E+00 -0.2882 10 Mg++ 0.21289E-10 -10.6718 0.10913E-10 -10.9621 0.51261E+00 -0.2902 11 Fe++ 0.58676E-13 -13.2315 0.30111E-13 -13.5213 0.51317E+00 -0.2897 12 K+ 0.15711E-03 -3.8038 0.13141E-03 -3.8814 0.83641E+00 -0.0776 13 Na+ 0.19936E-01 -1.7004 0.16644E-01 -1.7788 0.83483E+00 -0.0784 14 Mn++ 0.18823E-10 -10.7253 0.96673E-11 -11.0147 0.51360E+00 -0.2894 15 HPO4-- 0.45046E-07 -7.3463 0.23373E-07 -7.6313 0.51886E+00 -0.2849 16 HSiO3- 0.10454E-01 -1.9807 0.87287E-02 -2.0591 0.83498E+00 -0.0783 17 Ca(HSiO3)+ 0.16651E-07 -7.7786 0.13930E-07 -7.8560 0.83659E+00 -0.0775 18 Mg(HSiO3)+ 0.32271E-11 -11.4912 0.26998E-11 -11.5687 0.83659E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66376E-16 -16.1780 0.55529E-16 -16.2555 0.83659E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52985E-05 -5.2758 0.44162E-05 -5.3550 0.83347E+00 -0.0791 24 CH4,aq 0.24444E-04 -4.6118 0.24359E-04 -4.6133 0.99652E+00 -0.0015 25 C2H6,aq 0.87886E-14 -14.0561 0.87579E-14 -14.0576 0.99652E+00 -0.0015 29 CO,aq 0.18263E-16 -16.7384 0.18263E-16 -16.7384 0.10000E+01 0.0000 30 CO2,aq 0.62988E-10 -10.2007 0.62769E-10 -10.2023 0.99652E+00 -0.0015 31 CO3-2 0.89416E-06 -6.0486 0.46289E-06 -6.3345 0.51769E+00 -0.2859 32 CaCO3,aq 0.40674E-09 -9.3907 0.40674E-09 -9.3907 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.84365E-12 -12.0738 0.70579E-12 -12.1513 0.83659E+00 -0.0775 34 CaCl+ 0.30700E-10 -10.5129 0.25683E-10 -10.5904 0.83659E+00 -0.0775 35 CaCl2,aq 0.13818E-14 -14.8595 0.13818E-14 -14.8595 0.10000E+01 0.0000 36 CaOH+ 0.80185E-07 -7.0959 0.67082E-07 -7.1734 0.83659E+00 -0.0775 37 CaSO4,aq 0.14724E-16 -16.8320 0.14724E-16 -16.8320 0.10000E+01 0.0000 38 HCl,aq 0.30897E-14 -14.5101 0.30897E-14 -14.5101 0.10000E+01 0.0000 43 FeCl+ 0.12902E-16 -16.8893 0.10794E-16 -16.9668 0.83659E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15736E-10 -10.8031 0.13165E-10 -10.8806 0.83659E+00 -0.0775 48 HFeO2- 0.35534E-07 -7.4494 0.29671E-07 -7.5277 0.83498E+00 -0.0783 49 FeO+ 0.11029E-16 -16.9575 0.92265E-17 -17.0350 0.83659E+00 -0.0775 51 FeO2- 0.40791E-09 -9.3894 0.34059E-09 -9.4678 0.83498E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99652E+00 -0.0015 54 KCl,aq 0.53936E-09 -9.2681 0.53936E-09 -9.2681 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.16159E-14 -14.7916 0.13492E-14 -14.8699 0.83498E+00 -0.0783 58 MgCO3,aq 0.15877E-13 -13.7992 0.15877E-13 -13.7992 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13424E-15 -15.8721 0.11231E-15 -15.9496 0.83659E+00 -0.0775 60 MgCl+ 0.43330E-14 -14.3632 0.36250E-14 -14.4407 0.83659E+00 -0.0775 61 MgOH+ 0.69097E-10 -10.1605 0.57806E-10 -10.2380 0.83659E+00 -0.0775 63 MnO,aq 0.18061E-08 -8.7433 0.18061E-08 -8.7433 0.10000E+01 0.0000 64 MnOH+ 0.46933E-09 -9.3285 0.39264E-09 -9.4060 0.83659E+00 -0.0775 65 MnO2-2 0.20888E-10 -10.6801 0.10814E-10 -10.9660 0.51769E+00 -0.2859 66 HMnO2- 0.21124E-09 -9.6752 0.17638E-09 -9.7535 0.83498E+00 -0.0783 69 MnCl+ 0.16115E-13 -13.7928 0.13482E-13 -13.8703 0.83659E+00 -0.0775 71 NaCl,aq 0.12491E-05 -5.9034 0.12491E-05 -5.9034 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93109E-02 -2.0310 0.77604E-02 -2.1101 0.83347E+00 -0.0791 79 HPO3-2 0.16296E-14 -14.7879 0.84364E-15 -15.0738 0.51769E+00 -0.2859 81 H2PO3- 0.15085E-18 -18.8215 0.12595E-18 -18.8998 0.83498E+00 -0.0783 82 H3PO4,aq 0.90610E-18 -18.0428 0.90610E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38408E-10 -10.4156 0.32101E-10 -10.4935 0.83578E+00 -0.0779 84 PO4-3 0.10578E-08 -8.9756 0.25613E-09 -9.5915 0.24213E+00 -0.6159 88 HP2O7-3 0.93915E-18 -18.0273 0.21670E-18 -18.6641 0.23074E+00 -0.6369 89 P2O7-4 0.90534E-17 -17.0432 0.69532E-18 -18.1578 0.76802E-01 -1.1146 90 H2S,aq 0.97104E-08 -8.0128 0.96766E-08 -8.0143 0.99652E+00 -0.0015 91 S2-2 0.65352E-14 -14.1847 0.33832E-14 -14.4707 0.51769E+00 -0.2859 97 SO3-2 0.18963E-17 -17.7221 0.99591E-18 -18.0018 0.52519E+00 -0.2797 99 HSO4- 0.56693E-19 -19.2465 0.47475E-19 -19.3235 0.83741E+00 -0.0771 Charge balance for all species = 0.1031E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8862764E-10 -.2223622E-01 -.2237375E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981960E+06 0.0000 3 Cl- 0.2712231E-03 0.2724728E-03 0.9643156E+01 6.4831 4 SO4-- 0.1275404E-11 -.2735001E-04 -.2622710E+01 8.0769 5 HCO3- 0.4718416E-06 0.2581077E-04 0.1572158E+01 3.7242 6 HS- 0.5035678E-04 0.7771650E-04 0.2565764E+01 5.7519 7 Al+++ 0.9815570E-29 0.5298658E-05 0.1427168E+00 0.7390 8 H4SiO4 0.6959790E-03 0.1349933E-01 0.1295233E+04 -3.1574 9 Ca++ 0.1360808E-06 0.2333558E-06 0.9336145E-02 13.1018 10 Mg++ 0.2128915E-10 0.9363292E-10 0.2272439E-05 9.2942 11 Fe++ 0.5867649E-13 0.3617243E-07 0.2016603E-02 6.7350 12 K+ 0.1571084E-03 0.1578627E-03 0.6161998E+01 6.2467 13 Na+ 0.1993638E-01 0.2238331E-01 0.5136917E+03 8.3494 14 Mn++ 0.1882267E-10 0.2526420E-08 0.1385548E-03 9.2416 15 HPO4-- 0.4504566E-07 0.4614189E-07 0.4420939E-02 12.6250 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8113670E+02 -.1125993E-01 -.8112544E+02 0.0000000E+00 2 H2O -.5915248E+01 0.2810645E+02 -.3402169E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1358212E+00 -.1384944E-04 0.1358350E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1357957E+00 0.3935391E-04 -.1358350E+00 0.0000000E+00 7 Al+++ 0.1597763E+02 0.2683123E-05 0.1597763E+02 0.0000000E+00 8 H4SiO4 0.5102263E+02 0.6835759E-02 0.5101579E+02 0.0000000E+00 9 Ca++ 0.5635712E+01 0.1181662E-06 0.5635712E+01 0.0000000E+00 10 Mg++ 0.3888888E+01 0.4741363E-10 0.3888888E+01 0.0000000E+00 11 Fe++ 0.3493741E+01 0.1831691E-07 0.3493741E+01 0.0000000E+00 12 K+ 0.1040339E+01 0.7993817E-04 0.1040260E+01 0.0000000E+00 13 Na+ 0.6150853E+01 0.1133441E-01 0.6139518E+01 0.0000000E+00 14 Mn++ 0.8495910E-01 0.1279323E-08 0.8495910E-01 0.0000000E+00 15 HPO4-- 0.2899612E-01 0.2336523E-07 0.2899610E-01 0.0000000E+00 Chg. balance for solid moles: 0.2887E-14 Mass of aqueous solution: 0.507261E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.134 0.788 1609. 3.206 30.05 617.5 andradite 0.5433 -0.265 276.1 2.441 5.158 71.74 grossular 0.1316 -0.881 59.26 1.773 1.107 16.49 apatite-OH 0.9665E-02 -2.015 4.855 0.686 0.9070E-01 1.543 clinochlore 0.6961 -0.157 386.9 2.588 7.228 147.2 daphnite 0.2015 -0.696 143.8 2.158 2.686 43.57 chlorite-Mn 0.1699E-01 -1.770 12.05 1.081 0.2250 3.839 diopside 0.2573 -0.590 55.71 1.746 1.041 17.03 hedenbergite 0.6672E-01 -1.176 16.55 1.219 0.3092 4.534 microcline 0.9122 -0.040 253.9 2.405 4.743 99.18 stilbite 3.155 0.499 2224. 3.347 41.54 1037. stilpnomelane-Fe 0.2561 -0.592 276.1 2.441 5.158 95.37 tr.625ac.25prg.125 0.4165E-01 -1.380 35.60 1.551 0.6650 11.46 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5353.087197 g Volume = 2166.574794 cm3 Porosity: -10.4832% V(tot) - V(min): -.20558E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4899.9990000 g log = 3.6902 Original solution: 1000.0103000 g Original solution / Rock added: 0.20 (Water/Rock Ratio), log = -0.6902 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0716 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9528E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.6225E-08 1.0067 0.6716E-08 0.6671E-08 CH4,gas 0.3305E-01 1.0122 0.3585E-01 0.3542E-01 H2,gas 0.1418E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2493E-06 0.9958 0.2660E-06 0.2671E-06 S2,gas 0.1072E-28 1.0000 0.1149E-28 0.1149E-28 CO,gas 0.2540E-13 1.0000 0.2722E-13 0.2722E-13 SO3,gas 0.1294E-47 1.0000 0.1387E-47 0.1387E-47 SO2,gas 0.7656E-27 1.0000 0.8204E-27 0.8204E-27 HCl,gas 0.5087E-17 1.0000 0.5452E-17 0.5452E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 -0.94784E-12 22 andradite 39.01 39.01 0.00 0.000 0.12132E-10 23 grossular 32.73 32.73 0.00 0.000 -0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 67 diopside 16.18 16.18 0.00 0.000 0.60662E-11 68 hedenbergite 14.21 14.21 0.00 0.000 -0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.13649E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.53 -9.87 -3.291 0.16856E+05 -8.173 3 CH4,gas 4.54 1.40 -3.14 -0.786 0.53690E+04 -1.445 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.50 -8.27 -4.137 0.14128E+05 -6.575 6 S2,gas -7.34 -37.97 -30.64 -4.714 0.52315E+05 -28.940 7 CO,gas 3.21 -12.05 -15.26 -4.697 0.26063E+05 -13.565 8 SO3,gas 17.12 -32.44 -49.56 -12.389 0.84617E+05 -47.858 9 SO2,gas 0.83 -27.95 -28.78 -7.676 0.49149E+05 -27.086 10 HCl,gas 5.19 -13.77 -18.96 -9.481 0.32378E+05 -17.263 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80711E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.43 -4.40 -1.466 0.75073E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.43 -4.24 -1.414 0.72430E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.57 -4.46 -1.275 0.76221E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.57 -4.02 -1.149 0.68644E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.77 -3.51 -1.170 0.59916E+04 144 pyrrhotiteFe0.875 -6.02 -9.17 -3.15 -1.159 0.53788E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23248E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47128E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.77 -3.36 -1.119 0.57344E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.26 -4.28 -1.428 0.73164E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4899.9990000 g New total amount of reactant added: 4999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.5221E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 4999.9990000 Water: Moles liquid = 0.2755E+02 kg liquid = 0.4963E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1143362E-01 Osmotic coef. = 0.9685 True ionic strength = .2009850E-01 Chg. balance for total moles = 0.5221E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88643E-10 -10.0524 0.74464E-10 -10.1281 0.84004E+00 -0.0757 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27671E-03 -3.5580 0.23105E-03 -3.6363 0.83497E+00 -0.0783 4 SO4-- 0.13010E-11 -11.8857 0.67494E-12 -12.1707 0.51877E+00 -0.2850 5 HCO3- 0.48132E-06 -6.3176 0.40248E-06 -6.3953 0.83620E+00 -0.0777 6 HS- 0.51376E-04 -4.2892 0.42904E-04 -4.3675 0.83510E+00 -0.0783 7 Al+++ 0.98214E-29 -29.0078 0.22636E-29 -29.6452 0.23048E+00 -0.6374 8 H4SiO4 0.69598E-03 -3.1574 0.69598E-03 -3.1574 0.10000E+01 0.0000 9 Ca++ 0.13613E-06 -6.8660 0.70100E-07 -7.1543 0.51495E+00 -0.2882 10 Mg++ 0.21297E-10 -10.6717 0.10917E-10 -10.9619 0.51258E+00 -0.2902 11 Fe++ 0.58699E-13 -13.2314 0.30121E-13 -13.5211 0.51315E+00 -0.2898 12 K+ 0.15714E-03 -3.8037 0.13143E-03 -3.8813 0.83640E+00 -0.0776 13 Na+ 0.19940E-01 -1.7003 0.16646E-01 -1.7787 0.83482E+00 -0.0784 14 Mn++ 0.18830E-10 -10.7251 0.96708E-11 -11.0145 0.51357E+00 -0.2894 15 HPO4-- 0.45033E-07 -7.3465 0.23365E-07 -7.6314 0.51884E+00 -0.2850 16 HSiO3- 0.10452E-01 -1.9808 0.87272E-02 -2.0591 0.83497E+00 -0.0783 17 Ca(HSiO3)+ 0.16654E-07 -7.7785 0.13933E-07 -7.8560 0.83658E+00 -0.0775 18 Mg(HSiO3)+ 0.32277E-11 -11.4911 0.27002E-11 -11.5686 0.83658E+00 -0.0775 19 NaHSiO3,aq 0.23496E-02 -2.6290 0.23496E-02 -2.6290 0.10000E+01 0.0000 20 AlO+ 0.66388E-16 -16.1779 0.55538E-16 -16.2554 0.83658E+00 -0.0775 22 HAlO2,aq 0.14853E-09 -9.8282 0.14853E-09 -9.8282 0.10000E+01 0.0000 23 AlO2- 0.52977E-05 -5.2759 0.44154E-05 -5.3550 0.83346E+00 -0.0791 24 CH4,aq 0.24939E-04 -4.6031 0.24852E-04 -4.6046 0.99651E+00 -0.0015 25 C2H6,aq 0.91480E-14 -14.0387 0.91161E-14 -14.0402 0.99651E+00 -0.0015 29 CO,aq 0.18633E-16 -16.7297 0.18633E-16 -16.7297 0.10000E+01 0.0000 30 CO2,aq 0.64264E-10 -10.1920 0.64040E-10 -10.1936 0.99651E+00 -0.0015 31 CO3-2 0.91201E-06 -6.0400 0.47211E-06 -6.3260 0.51766E+00 -0.2860 32 CaCO3,aq 0.41498E-09 -9.3820 0.41498E-09 -9.3820 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.86088E-12 -12.0651 0.72020E-12 -12.1425 0.83658E+00 -0.0775 34 CaCl+ 0.31331E-10 -10.5040 0.26211E-10 -10.5815 0.83658E+00 -0.0775 35 CaCl2,aq 0.14388E-14 -14.8420 0.14388E-14 -14.8420 0.10000E+01 0.0000 36 CaOH+ 0.80199E-07 -7.0958 0.67093E-07 -7.1733 0.83658E+00 -0.0775 37 CaSO4,aq 0.15024E-16 -16.8232 0.15024E-16 -16.8232 0.10000E+01 0.0000 38 HCl,aq 0.31527E-14 -14.5013 0.31527E-14 -14.5013 0.10000E+01 0.0000 43 FeCl+ 0.13167E-16 -16.8805 0.11015E-16 -16.9580 0.83658E+00 -0.0775 46 FeO,aq 0.21113E-09 -9.6755 0.21113E-09 -9.6755 0.10000E+01 0.0000 47 FeOH+ 0.15739E-10 -10.8030 0.13167E-10 -10.8805 0.83658E+00 -0.0775 48 HFeO2- 0.35529E-07 -7.4494 0.29666E-07 -7.5277 0.83497E+00 -0.0783 49 FeO+ 0.11031E-16 -16.9574 0.92281E-17 -17.0349 0.83658E+00 -0.0775 51 FeO2- 0.40784E-09 -9.3895 0.34054E-09 -9.4678 0.83497E+00 -0.0783 52 HFeO2,aq 0.32251E-11 -11.4915 0.32251E-11 -11.4915 0.10000E+01 0.0000 53 H2,aq 0.11623E-04 -4.9347 0.11583E-04 -4.9362 0.99651E+00 -0.0015 54 KCl,aq 0.55036E-09 -9.2594 0.55036E-09 -9.2594 0.10000E+01 0.0000 56 KOH,aq 0.75375E-06 -6.1228 0.75375E-06 -6.1228 0.10000E+01 0.0000 57 KSO4- 0.16486E-14 -14.7829 0.13765E-14 -14.8612 0.83497E+00 -0.0783 58 MgCO3,aq 0.16198E-13 -13.7905 0.16198E-13 -13.7905 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13699E-15 -15.8633 0.11460E-15 -15.9408 0.83658E+00 -0.0775 60 MgCl+ 0.44221E-14 -14.3544 0.36995E-14 -14.4319 0.83658E+00 -0.0775 61 MgOH+ 0.69109E-10 -10.1605 0.57815E-10 -10.2380 0.83658E+00 -0.0775 63 MnO,aq 0.18062E-08 -8.7432 0.18062E-08 -8.7432 0.10000E+01 0.0000 64 MnOH+ 0.46943E-09 -9.3284 0.39272E-09 -9.4059 0.83658E+00 -0.0775 65 MnO2-2 0.20883E-10 -10.6802 0.10810E-10 -10.9662 0.51766E+00 -0.2860 66 HMnO2- 0.21121E-09 -9.6753 0.17636E-09 -9.7536 0.83497E+00 -0.0783 69 MnCl+ 0.16447E-13 -13.7839 0.13759E-13 -13.8614 0.83658E+00 -0.0775 71 NaCl,aq 0.12746E-05 -5.8946 0.12746E-05 -5.8946 0.10000E+01 0.0000 72 NaOH,aq 0.96047E-04 -4.0175 0.96047E-04 -4.0175 0.10000E+01 0.0000 74 OH- 0.93095E-02 -2.0311 0.77591E-02 -2.1102 0.83346E+00 -0.0791 79 HPO3-2 0.16292E-14 -14.7880 0.84336E-15 -15.0740 0.51766E+00 -0.2860 81 H2PO3- 0.15082E-18 -18.8215 0.12593E-18 -18.8999 0.83497E+00 -0.0783 82 H3PO4,aq 0.90611E-18 -18.0428 0.90611E-18 -18.0428 0.10000E+01 0.0000 83 H2PO4- 0.38402E-10 -10.4156 0.32095E-10 -10.4936 0.83577E+00 -0.0779 84 PO4-3 0.10574E-08 -8.9758 0.25601E-09 -9.5918 0.24211E+00 -0.6160 88 HP2O7-3 0.93879E-18 -18.0274 0.21659E-18 -18.6644 0.23071E+00 -0.6369 89 P2O7-4 0.90491E-17 -17.0434 0.69487E-18 -18.1581 0.76788E-01 -1.1147 90 H2S,aq 0.99084E-08 -8.0040 0.98738E-08 -8.0055 0.99651E+00 -0.0015 91 S2-2 0.68025E-14 -14.1673 0.35214E-14 -14.4533 0.51766E+00 -0.2860 97 SO3-2 0.19344E-17 -17.7135 0.10159E-17 -17.9932 0.52517E+00 -0.2797 99 HSO4- 0.57840E-19 -19.2378 0.48435E-19 -19.3148 0.83740E+00 -0.0771 Charge balance for all species = 0.1053E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8864319E-10 -.2223323E-01 -.2237073E+02 0.0000 2 H2O 0.1000000E+01 0.5550490E+02 0.9981958E+06 0.0000 3 Cl- 0.2767108E-03 0.2779859E-03 0.9838269E+01 6.4918 4 SO4-- 0.1301046E-11 -.2784492E-04 -.2670169E+01 8.0854 5 HCO3- 0.4813224E-06 0.2633301E-04 0.1603968E+01 3.7328 6 HS- 0.5137567E-04 0.7923050E-04 0.2615747E+01 5.7605 7 Al+++ 0.9821442E-29 0.5297845E-05 0.1426948E+00 0.7390 8 H4SiO4 0.6959793E-03 0.1349774E-01 0.1295081E+04 -3.1574 9 Ca++ 0.1361319E-06 0.2334328E-06 0.9339226E-02 13.1018 10 Mg++ 0.2129716E-10 0.9365477E-10 0.2272969E-05 9.2942 11 Fe++ 0.5869858E-13 0.3616694E-07 0.2016297E-02 6.7350 12 K+ 0.1571361E-03 0.1578904E-03 0.6163077E+01 6.2467 13 Na+ 0.1993990E-01 0.2238686E-01 0.5137729E+03 8.3494 14 Mn++ 0.1883044E-10 0.2526564E-08 0.1385626E-03 9.2416 15 HPO4-- 0.4503297E-07 0.4612877E-07 0.4419682E-02 12.6247 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279255E+02 -.1103513E-01 -.8278151E+02 0.0000000E+00 2 H2O -.7168789E+01 0.2754903E+02 -.3471782E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385925E+00 -.1382041E-04 0.1386063E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385670E+00 0.3932488E-04 -.1386063E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2629506E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.6699401E-02 0.5205720E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1158609E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4648415E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1795092E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.7836655E-04 0.1061493E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1111138E-01 0.6265266E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1254022E-08 0.8669296E-01 0.0000000E+00 15 HPO4-- 0.2958788E-01 0.2289533E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: -.2734E-14 Mass of aqueous solution: 0.497201E+03 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 4999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.260 0.797 1641. 3.215 30.05 630.1 andradite 0.5544 -0.256 281.7 2.450 5.158 73.20 grossular 0.1342 -0.872 60.47 1.782 1.107 16.83 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9070E-01 1.574 clinochlore 0.7103 -0.149 394.8 2.596 7.228 150.2 daphnite 0.2056 -0.687 146.7 2.166 2.686 44.46 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2627 -0.581 56.89 1.755 1.041 17.39 hedenbergite 0.6813E-01 -1.167 16.90 1.228 0.3094 4.629 microcline 0.9308 -0.031 259.1 2.413 4.743 101.2 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2614 -0.583 281.7 2.450 5.158 97.32 tr.625ac.25prg.125 0.4248E-01 -1.372 36.31 1.560 0.6648 11.69 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8051E+00 0.8051E+00 1.0000 -0.094 grossular 0.1949E+00 0.1949E+00 1.0000 -0.710 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7611E+00 0.7611E+00 1.0000 -0.119 daphnite 0.2203E+00 0.2203E+00 1.0000 -0.657 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7941E+00 0.7941E+00 1.0000 -0.100 hedenbergite 0.2059E+00 0.2059E+00 1.0000 -0.686 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.337861 g Volume = 2210.777858 cm3 Porosity: -10.4837% V(tot) - V(min): -.20978E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4999.9990000 g log = 3.6990 Original solution: 1000.0103000 g Original solution / Rock added: 0.20 (Water/Rock Ratio), log = -0.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0724 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9521E+00 0.9853 0.1006E+01 0.1021E+01 CO2,gas 0.6347E-08 1.0067 0.6852E-08 0.6806E-08 CH4,gas 0.3370E-01 1.0122 0.3658E-01 0.3614E-01 H2,gas 0.1417E-01 1.0006 0.1521E-01 0.1520E-01 H2S,gas 0.2542E-06 0.9958 0.2714E-06 0.2726E-06 S2,gas 0.1115E-28 1.0000 0.1196E-28 0.1196E-28 CO,gas 0.2589E-13 1.0000 0.2777E-13 0.2777E-13 SO3,gas 0.1320E-47 1.0000 0.1415E-47 0.1415E-47 SO2,gas 0.7807E-27 1.0000 0.8371E-27 0.8371E-27 HCl,gas 0.5188E-17 1.0000 0.5563E-17 0.5563E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.38 -0.38 0.00 0.000 0.11184E-10 22 andradite 39.01 39.01 0.00 0.000 -0.24265E-10 23 grossular 32.73 32.73 0.00 0.000 0.12132E-10 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 67 diopside 16.18 16.18 0.00 0.000 0.00000E+00 68 hedenbergite 14.21 14.21 0.00 0.000 0.60662E-11 116 microcline -2.49 -2.49 0.00 0.000 0.15165E-11 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 164 stilpnomelane-Fe 13.02 13.02 0.00 0.000 -0.27298E-10 245 tr.625ac.25prg.125 45.16 45.16 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -16.52 -9.86 -3.288 0.16841E+05 -8.164 3 CH4,gas 4.54 1.41 -3.14 -0.784 0.53542E+04 -1.437 4 H2,gas 8.00 4.48 -3.52 -2.010 0.60051E+04 -1.818 5 H2S,gas -6.23 -14.50 -8.27 -4.133 0.14113E+05 -6.566 6 S2,gas -7.34 -37.96 -30.62 -4.711 0.52285E+05 -28.922 7 CO,gas 3.21 -12.04 -15.26 -4.694 0.26048E+05 -13.556 8 SO3,gas 17.12 -32.43 -49.55 -12.387 0.84602E+05 -47.849 9 SO2,gas 0.83 -27.94 -28.78 -7.674 0.49135E+05 -27.077 10 HCl,gas 5.19 -13.76 -18.95 -9.477 0.32363E+05 -17.255 11 acmite 7.71 6.53 -1.18 -0.123 0.20175E+04 15 albite-high 0.69 -0.38 -1.08 -0.083 0.18388E+04 19 spessartine 24.46 19.73 -4.73 -0.236 0.80710E+04 20 analcite 3.32 2.77 -0.55 -0.061 0.93625E+03 26 annite 20.12 17.72 -2.40 -0.134 0.41064E+04 27 phlogopite 27.06 25.40 -1.67 -0.093 0.28489E+04 29 anorthite 12.71 8.26 -4.45 -0.342 0.75903E+04 35 aragonite 0.97 -3.42 -4.39 -1.463 0.74924E+04 36 brucite 12.57 9.29 -3.27 -0.655 0.55909E+04 37 calcite 0.81 -3.42 -4.23 -1.411 0.72282E+04 38 carnegieite-low 9.02 5.93 -3.09 -0.442 0.52801E+04 39 carnegieite-high 10.09 5.93 -4.16 -0.595 0.71071E+04 40 carpholite-Mg 8.58 4.46 -4.12 -0.275 0.70429E+04 41 carpholite-Fe 6.71 1.90 -4.81 -0.321 0.82207E+04 42 celadonite 5.34 3.65 -1.69 -0.099 0.28879E+04 43 celadonite-Fe 3.88 1.09 -2.79 -0.164 0.47561E+04 44 chrysotile 23.89 21.57 -2.32 -0.194 0.39692E+04 49 chlorite-Al-free 47.17 43.14 -4.04 -0.168 0.68936E+04 51 chloritoid-Fe 9.17 5.06 -4.12 -0.275 0.70316E+04 52 chloritoid-Mn 11.40 7.56 -3.84 -0.256 0.65549E+04 54 coesite -2.38 -3.16 -0.78 -0.260 0.13341E+04 61 cristobalite -2.56 -3.16 -0.60 -0.199 0.10195E+04 63 cymrite-K 1.69 -2.49 -4.17 -0.348 0.71234E+04 65 diaspore 2.87 0.74 -2.13 -0.356 0.36450E+04 66 diamond -3.10 -7.56 -4.46 -1.273 0.76073E+04 71 enstatite 17.26 12.27 -4.99 -0.499 0.85226E+04 73 clinoenstatite 17.17 12.27 -4.89 -0.489 0.83541E+04 75 epidote 24.67 22.70 -1.97 -0.095 0.33585E+04 76 clinozoisite 22.81 18.95 -3.86 -0.175 0.65869E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57768E+04 78 fayalite 14.05 10.31 -3.73 -0.533 0.63743E+04 79 ferrosilite 11.15 7.16 -3.99 -0.399 0.68202E+04 83 gibbsite 4.08 0.74 -3.34 -0.477 0.57035E+04 84 glaucophane 22.97 20.80 -2.17 -0.059 0.37134E+04 85 glaucophane-Fe 17.28 13.12 -4.15 -0.112 0.70919E+04 86 graphite -3.55 -7.56 -4.01 -1.146 0.68495E+04 87 greenalite 16.14 13.89 -2.25 -0.187 0.38408E+04 90 hematite 12.57 8.99 -3.58 -0.434 0.61111E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 2.77 -1.44 -0.144 0.24617E+04 97 kalsilite 7.58 3.83 -3.76 -0.537 0.64126E+04 98 kaolinite -1.33 -4.84 -3.50 -0.319 0.59831E+04 101 laumontite 2.88 1.95 -0.93 -0.062 0.15935E+04 102 lawsonite 9.62 8.26 -1.35 -0.090 0.23070E+04 103 leucite 4.12 0.67 -3.45 -0.345 0.58873E+04 105 lizardite 23.24 21.57 -1.68 -0.140 0.28618E+04 107 magnetite 20.09 15.72 -4.37 -0.356 0.74536E+04 108 minnesotaite 10.39 7.58 -2.81 -0.165 0.48028E+04 112 manganosite 14.06 9.24 -4.82 -1.204 0.82241E+04 120 muscovite 2.58 -1.01 -3.59 -0.211 0.61315E+04 121 paragonite 4.24 1.09 -3.15 -0.185 0.53706E+04 122 nepheline 8.34 5.93 -2.41 -0.344 0.41125E+04 128 periclase-Fe 11.63 6.73 -4.89 -1.223 0.83523E+04 134 phlogopite-Na 29.65 27.50 -2.15 -0.119 0.36677E+04 136 prehnite 19.37 18.21 -1.16 -0.068 0.19849E+04 137 prehnite-Fe 22.50 21.96 -0.53 -0.032 0.91158E+03 138 pumpellyite-Fe 46.27 43.89 -2.38 -0.053 0.40581E+04 139 pumpellyite-Mg 48.99 46.45 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.26 -7.76 -3.50 -1.167 0.59766E+04 144 pyrrhotiteFe0.875 -6.02 -9.16 -3.14 -1.155 0.53638E+04 145 pyroxmangite 7.40 6.08 -1.31 -0.263 0.22445E+04 146 pyrophyllite -6.18 -11.15 -4.98 -0.311 0.84962E+04 147 quartz -2.99 -3.16 -0.17 -0.056 0.28680E+03 152 rhodonite 7.45 6.08 -1.36 -0.272 0.23247E+04 153 sanidine -1.28 -2.49 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.44 25.81 -1.63 -0.049 0.27804E+04 171 talc 16.49 15.25 -1.24 -0.073 0.21140E+04 174 tephroite 18.09 15.33 -2.76 -0.394 0.47127E+04 178 tridymite -2.63 -3.16 -0.53 -0.177 0.90678E+03 179 tremolite 47.87 47.42 -0.45 -0.012 0.77494E+03 180 ferroactinolite 38.45 34.62 -3.83 -0.104 0.65448E+04 181 troilite-low -4.41 -7.76 -3.35 -1.117 0.57194E+04 183 vesuvianite 223.47 218.82 -4.65 -0.036 0.79438E+04 187 wairakite 3.95 1.95 -2.00 -0.118 0.34155E+04 188 walstromite 11.51 9.94 -1.56 -0.313 0.26719E+04 189 wollastonite 10.46 9.94 -0.52 -0.103 0.88229E+03 190 pseudo-wollastonite 11.00 9.94 -1.06 -0.211 0.18021E+04 191 zoisite 22.85 18.95 -3.90 -0.177 0.66609E+04 192 akaganeite 7.75 4.49 -3.26 -0.705 0.55681E+04 199 chalcedony -2.80 -3.16 -0.35 -0.118 0.60610E+03 201 montmorillonite-Ca -2.29 -6.17 -3.88 -0.240 0.66180E+04 202 montmorillonite-K -2.24 -6.27 -4.03 -0.247 0.68816E+04 203 montmorillonite-Mg -2.48 -6.79 -4.32 -0.267 0.73678E+04 204 montmorillonite-Na -2.04 -5.57 -3.54 -0.216 0.60365E+04 205 nontronite-Ca 3.21 -0.19 -3.41 -0.221 0.58215E+04 206 nontronite-H 2.53 -2.36 -4.89 -0.328 0.83485E+04 207 nontronite-K 3.34 -0.30 -3.64 -0.233 0.62083E+04 208 nontronite-Mg 3.07 -0.82 -3.90 -0.253 0.66553E+04 209 nontronite-Na 3.52 0.40 -3.12 -0.200 0.53292E+04 224 tobermorite 9.82 7.76 -2.07 -0.564 0.35287E+04 230 alabandite -0.98 -5.25 -4.28 -1.425 0.73014E+04 233 boehmite 4.41 0.74 -3.67 -0.611 0.62619E+04 235 ferrous-oxide 9.81 6.73 -3.08 -0.769 0.52532E+04 240 silica-amorphous -2.09 -3.16 -1.07 -0.355 0.18203E+04 242 an20ab80 2.02 1.35 -0.67 -0.052 0.11472E+04 243 an25ab75 2.65 1.78 -0.87 -0.067 0.14810E+04 244 an30ab70 3.28 2.21 -1.07 -0.082 0.18244E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 4999.9990000 g New total amount of reactant added: 5099.9990000 g Mixing fraction reached given limit of 0.5000E+04 TOTMIX = 0.5100E+04 Execution stopped.