File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.11943E-03 0.37019E-07 0.9609 0.00000000E+00 H2O 2 0. 0.55508E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13796E-03 0.9608 0.00000000E+00 SO4-- 4 -2. 0.25726E-04 0.25346E-04 0.8992 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.12137E-04 0.9608 0.00000000E+00 HS- 6 -1. -0.22171E-06 0.41093E-08 0.9608 0.00000000E+00 Al+++ 7 3. 0.26086E-04 0.41802E-19 0.8050 0.00000000E+00 H4SiO4 8 0. 0.83302E-04 0.75755E-04 1.0000 0.00000000E+00 Ca++ 9 2. 0.23672E-04 0.23397E-04 0.8991 0.00000000E+00 Mg++ 10 2. 0.63492E-05 0.11062E-05 0.8990 0.00000000E+00 Fe++ 11 2. 0.57041E-05 0.78063E-08 0.8990 0.00000000E+00 K+ 12 1. 0.16985E-05 0.16979E-05 0.9608 0.00000000E+00 Na+ 13 1. 0.17011E-03 0.17010E-03 0.9608 0.00000000E+00 Mn++ 14 2. 0.13871E-06 0.11395E-06 0.8990 0.00000000E+00 HPO4-- 15 -2. 0.47341E-07 0.72137E-08 0.8992 0.00000000E+00 Chg. balance for total moles = 0.1648E-14 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E-01 TEMP = 100.0000 SINC = 0.4000E-03 TEMPC = 0.0000 TOTMIX = 0.800000E-02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.0032 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.0000E+00 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.0000E+00 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.0000E+00 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.1190E-07 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.0000E+00 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.0000E+00 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.1046E-05 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.7746E-06 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.2970E-08 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.2111E-04 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.0000E+00 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.0000E+00 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.9081E-06 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.0000E+00 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.0000E+00 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.0000E+00 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.0080000 g log = -2.0969 Original solution: 1000.0103000 g Original solution / Rock added: 125001.29 (Water/Rock Ratio), log = 5.0969 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0080000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2681880E-03 Osmotic coef. = 0.9902 True ionic strength = .2711774E-03 Chg. balance for total moles = 0.1648E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.37019E-07 -7.4316 0.35571E-07 -7.4489 0.96089E+00 -0.0173 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13255E-03 -3.8776 0.96077E+00 -0.0174 4 SO4-- 0.25346E-04 -4.5961 0.22791E-04 -4.6422 0.89922E+00 -0.0461 5 HCO3- 0.12137E-04 -4.9159 0.11662E-04 -4.9332 0.96080E+00 -0.0174 6 HS- 0.41093E-08 -8.3862 0.39481E-08 -8.4036 0.96078E+00 -0.0174 7 Al+++ 0.41802E-19 -19.3788 0.33650E-19 -19.4730 0.80497E+00 -0.0942 8 H4SiO4 0.75755E-04 -4.1206 0.75755E-04 -4.1206 0.10000E+01 0.0000 9 Ca++ 0.23397E-04 -4.6308 0.21036E-04 -4.6770 0.89909E+00 -0.0462 10 Mg++ 0.11062E-05 -5.9562 0.99451E-06 -6.0024 0.89901E+00 -0.0462 11 Fe++ 0.78063E-08 -8.1076 0.70181E-08 -8.1538 0.89903E+00 -0.0462 12 K+ 0.16979E-05 -5.7701 0.16313E-05 -5.7875 0.96081E+00 -0.0174 13 Na+ 0.17010E-03 -3.7693 0.16343E-03 -3.7867 0.96077E+00 -0.0174 14 Mn++ 0.11395E-06 -6.9433 0.10245E-06 -6.9895 0.89904E+00 -0.0462 15 HPO4-- 0.72137E-08 -8.1418 0.64867E-08 -8.1880 0.89922E+00 -0.0461 16 HSiO3- 0.20698E-05 -5.6841 0.19886E-05 -5.7015 0.96077E+00 -0.0174 17 Ca(HSiO3)+ 0.99153E-09 -9.0037 0.95267E-09 -9.0211 0.96081E+00 -0.0174 18 Mg(HSiO3)+ 0.58338E-10 -10.2341 0.56052E-10 -10.2514 0.96081E+00 -0.0174 19 NaHSiO3,aq 0.52562E-08 -8.2793 0.52562E-08 -8.2793 0.10000E+01 0.0000 20 AlO+ 0.37656E-11 -11.4242 0.36180E-11 -11.4415 0.96081E+00 -0.0174 21 AlOH+2 0.71277E-15 -15.1471 0.64082E-15 -15.1933 0.89906E+00 -0.0462 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.13120E-05 -5.8821 0.12605E-05 -5.8994 0.96074E+00 -0.0174 24 CH4,aq 0.19625E-14 -14.7072 0.19623E-14 -14.7072 0.99992E+00 0.0000 29 CO,aq 0.70877E-16 -16.1495 0.70877E-16 -16.1495 0.10000E+01 0.0000 30 CO2,aq 0.88643E-06 -6.0524 0.88635E-06 -6.0524 0.99992E+00 0.0000 31 CO3-2 0.31846E-07 -7.4969 0.28635E-07 -7.5431 0.89918E+00 -0.0462 32 CaCO3,aq 0.75531E-08 -8.1219 0.75531E-08 -8.1219 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65172E-08 -8.1859 0.62618E-08 -8.2033 0.96081E+00 -0.0174 34 CaCl+ 0.46964E-08 -8.3282 0.45124E-08 -8.3456 0.96081E+00 -0.0174 35 CaCl2,aq 0.14210E-12 -12.8474 0.14210E-12 -12.8474 0.10000E+01 0.0000 36 CaOH+ 0.43867E-07 -7.3579 0.42147E-07 -7.3752 0.96081E+00 -0.0174 37 CaSO4,aq 0.15224E-06 -6.8175 0.15224E-06 -6.8175 0.10000E+01 0.0000 38 HCl,aq 0.86399E-12 -12.0635 0.86399E-12 -12.0635 0.10000E+01 0.0000 43 FeCl+ 0.15325E-11 -11.8146 0.14724E-11 -11.8320 0.96081E+00 -0.0174 46 FeO,aq 0.21557E-09 -9.6664 0.21557E-09 -9.6664 0.10000E+01 0.0000 47 FeOH+ 0.66842E-08 -8.1749 0.64223E-08 -8.1923 0.96081E+00 -0.0174 48 HFeO2- 0.66000E-10 -10.1805 0.63411E-10 -10.1978 0.96077E+00 -0.0174 49 FeO+ 0.28258E-12 -12.5489 0.27151E-12 -12.5662 0.96081E+00 -0.0174 50 FeOH+2 0.20514E-17 -17.6879 0.18444E-17 -17.7342 0.89906E+00 -0.0462 51 FeO2- 0.45701E-10 -10.3401 0.43908E-10 -10.3575 0.96077E+00 -0.0174 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.31835E-08 -8.4971 0.31832E-08 -8.4971 0.99992E+00 0.0000 54 KCl,aq 0.39191E-11 -11.4068 0.39191E-11 -11.4068 0.10000E+01 0.0000 55 KHSO4,aq 0.37394E-17 -17.4272 0.37394E-17 -17.4272 0.10000E+01 0.0000 56 KOH,aq 0.19586E-10 -10.7081 0.19586E-10 -10.7081 0.10000E+01 0.0000 57 KSO4- 0.60051E-09 -9.2215 0.57696E-09 -9.2389 0.96077E+00 -0.0174 58 MgCO3,aq 0.89506E-10 -10.0481 0.89506E-10 -10.0481 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.31483E-09 -9.5019 0.30250E-09 -9.5193 0.96081E+00 -0.0174 60 MgCl+ 0.20124E-09 -9.6963 0.19335E-09 -9.7137 0.96081E+00 -0.0174 61 MgOH+ 0.11476E-07 -7.9402 0.11026E-07 -7.9576 0.96081E+00 -0.0174 63 MnO,aq 0.83851E-10 -10.0765 0.83851E-10 -10.0765 0.10000E+01 0.0000 64 MnOH+ 0.90643E-08 -8.0427 0.87091E-08 -8.0600 0.96081E+00 -0.0174 65 MnO2-2 0.24459E-17 -17.6116 0.21993E-17 -17.6577 0.89918E+00 -0.0462 66 HMnO2- 0.17839E-13 -13.7486 0.17139E-13 -13.7660 0.96077E+00 -0.0174 69 MnCl+ 0.87033E-10 -10.0603 0.83622E-10 -10.0777 0.96081E+00 -0.0174 70 MnSO4,aq 0.67408E-09 -9.1713 0.67408E-09 -9.1713 0.10000E+01 0.0000 71 NaCl,aq 0.71789E-08 -8.1439 0.71789E-08 -8.1439 0.10000E+01 0.0000 72 NaOH,aq 0.19740E-08 -8.7047 0.19740E-08 -8.7047 0.10000E+01 0.0000 74 OH- 0.16907E-04 -4.7719 0.16243E-04 -4.7893 0.96074E+00 -0.0174 79 HPO3-2 0.71563E-19 -19.1453 0.64348E-19 -19.1915 0.89918E+00 -0.0462 82 H3PO4,aq 0.57403E-13 -13.2411 0.57403E-13 -13.2411 0.10000E+01 0.0000 83 H2PO4- 0.44302E-08 -8.3536 0.42565E-08 -8.3709 0.96079E+00 -0.0174 84 PO4-3 0.18465E-12 -12.7336 0.14879E-12 -12.8274 0.80577E+00 -0.0938 87 H2P2O7-2 0.15799E-17 -17.8014 0.14206E-17 -17.8475 0.89918E+00 -0.0462 88 HP2O7-3 0.99067E-17 -17.0041 0.79746E-17 -17.0983 0.80497E+00 -0.0942 89 P2O7-4 0.77636E-19 -19.1099 0.53558E-19 -19.2712 0.68986E+00 -0.1612 90 H2S,aq 0.43408E-09 -9.3624 0.43404E-09 -9.3625 0.99992E+00 0.0000 91 S2-2 0.12067E-18 -18.9184 0.10850E-18 -18.9646 0.89918E+00 -0.0462 96 SO2,aq 0.40996E-18 -18.3873 0.40996E-18 -18.3873 0.10000E+01 0.0000 97 SO3-2 0.10482E-13 -13.9796 0.94278E-14 -14.0256 0.89945E+00 -0.0460 98 HSO3- 0.21855E-13 -13.6605 0.20997E-13 -13.6778 0.96077E+00 -0.0174 99 HSO4- 0.81315E-09 -9.0898 0.78129E-09 -9.1072 0.96083E+00 -0.0174 101 S2O3-2 0.12923E-15 -15.8886 0.11620E-15 -15.9348 0.89918E+00 -0.0462 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3701864E-07 -.2347720E-04 -.2366317E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999794E+06 0.0000 3 Cl- 0.1379624E-03 0.1379746E-03 0.4891522E+01 3.5713 4 SO4-- 0.2534567E-04 0.2549924E-04 0.2449452E+01 10.2556 5 HCO3- 0.1213729E-04 0.1307004E-04 0.7974824E+00 2.5157 6 HS- 0.4109304E-08 0.5308680E-08 0.1755654E-03 -0.9547 7 Al+++ 0.4180237E-19 0.1332292E-05 0.3594657E-01 2.8737 8 H4SiO4 0.7575525E-04 0.7783134E-04 0.7480650E+01 -4.1206 9 Ca++ 0.2339691E-04 0.2361278E-04 0.9463353E+00 10.2208 10 Mg++ 0.1106227E-05 0.1118366E-05 0.2718921E-01 8.8954 11 Fe++ 0.7806322E-08 0.1501830E-07 0.8387115E-03 6.7440 12 K+ 0.1697895E-05 0.1698519E-05 0.6641425E-01 1.6615 13 Na+ 0.1700991E-03 0.1701135E-03 0.3910802E+01 3.6622 14 Mn++ 0.1139523E-06 0.1238616E-06 0.6804581E-02 7.9083 15 HPO4-- 0.7213686E-08 0.1164413E-07 0.1117571E-02 6.7098 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1194281E-03 -.2347713E-04 -.9595100E-04 0.0000000E+00 2 H2O 0.5550815E+02 0.5550809E+02 0.5498276E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2572618E-04 0.2549916E-04 0.2270159E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217073E-06 0.5308664E-08 -.2270159E-06 0.0000000E+00 7 Al+++ 0.2608593E-04 0.1332288E-05 0.2475364E-04 0.0000000E+00 8 H4SiO4 0.8330226E-04 0.7783110E-04 0.5471169E-05 0.0000000E+00 9 Ca++ 0.2367220E-04 0.2361271E-04 0.5949421E-07 0.0000000E+00 10 Mg++ 0.6349206E-05 0.1118363E-05 0.5230844E-05 0.0000000E+00 11 Fe++ 0.5704069E-05 0.1501826E-07 0.5689050E-05 0.0000000E+00 12 K+ 0.1698514E-05 0.1698514E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1701129E-03 0.1701129E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1387088E-06 0.1238612E-06 0.1484755E-07 0.0000000E+00 15 HPO4-- 0.4734061E-07 0.1164409E-07 0.3569652E-07 0.0000000E+00 Chg. balance for solid moles: 0.4368E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0080000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1190E-07 -7.924 0.5977E-05 -5.224 0.2341 0.1899E-05 clinochlore 0.1046E-05 -5.980 0.5815E-03 -3.235 22.77 0.2212E-03 daphnite 0.7746E-06 -6.111 0.5527E-03 -3.258 21.64 0.1675E-03 chlorite-Mn 0.2970E-08 -8.527 0.2105E-05 -5.677 0.8245E-01 0.6709E-06 diaspore 0.2111E-04 -4.676 0.1266E-02 -2.898 49.59 0.3769E-03 hematite 0.9081E-06 -6.042 0.1450E-03 -3.839 5.679 0.2749E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5736E+00 0.5736E+00 1.0000 -0.241 daphnite 0.4247E+00 0.4247E+00 1.0000 -0.372 chlorite-Mn 0.1628E-02 0.1628E-02 1.0000 -2.788 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002553 g Volume = 0.000796 cm3 Porosity: 99.9207% V(tot) - V(min): 0.10024E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0080000 g log = -2.0969 Original solution: 1000.0103000 g Original solution / Rock added: 125001.29 (Water/Rock Ratio), log = 5.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.9228E-04 1.0071 0.9483E-04 0.9416E-04 CH4,gas 0.2796E-11 1.0125 0.2888E-11 0.2853E-11 H2,gas 0.4093E-05 1.0005 0.4179E-05 0.4177E-05 H2S,gas 0.1174E-07 0.9960 0.1193E-07 0.1198E-07 S2,gas 0.2998E-24 1.0000 0.3060E-24 0.3060E-24 CO,gas 0.1035E-12 1.0000 0.1056E-12 0.1056E-12 SO3,gas 0.1069E-34 1.0000 0.1090E-34 0.1090E-34 SO2,gas 0.1737E-17 1.0000 0.1773E-17 0.1773E-17 HCl,gas 0.1494E-14 1.0000 0.1525E-14 0.1525E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.38 -5.72 -1.907 0.97702E+04 -4.023 3 CH4,gas 4.54 -8.69 -13.24 -3.310 0.22604E+05 -11.539 4 H2,gas 8.00 0.92 -7.08 -4.045 0.12085E+05 -5.379 5 H2S,gas -6.23 -15.85 -9.62 -4.811 0.16430E+05 -7.923 6 S2,gas -7.34 -33.55 -26.21 -4.033 0.44759E+05 -24.514 7 CO,gas 3.21 -11.46 -14.68 -4.515 0.25058E+05 -12.976 8 SO3,gas 17.12 -19.54 -36.66 -9.165 0.62598E+05 -34.962 9 SO2,gas 0.83 -18.62 -19.45 -5.187 0.33211E+05 -17.751 10 HCl,gas 5.19 -11.33 -16.52 -8.258 0.28200E+05 -14.817 21 andalusite 5.00 1.63 -3.37 -0.337 0.57622E+04 24 anhydrite -5.32 -9.32 -4.00 -2.001 0.68341E+04 29 anorthite 12.71 7.73 -4.98 -0.383 0.85089E+04 35 aragonite 0.97 -2.16 -3.13 -1.043 0.53408E+04 36 brucite 12.57 8.90 -3.67 -0.735 0.62718E+04 37 calcite 0.81 -2.16 -2.97 -0.991 0.50766E+04 40 carpholite-Mg 8.58 6.40 -2.18 -0.145 0.37231E+04 41 carpholite-Fe 6.71 4.25 -2.46 -0.164 0.42045E+04 50 chloritoid-Mg 13.20 10.52 -2.68 -0.178 0.45683E+04 51 chloritoid-Fe 9.17 8.37 -0.80 -0.054 0.13707E+04 52 chloritoid-Mn 11.40 9.54 -1.87 -0.124 0.31861E+04 54 coesite -2.38 -4.12 -1.74 -0.582 0.29787E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -4.12 -1.56 -0.520 0.26641E+04 75 epidote 24.67 20.11 -4.56 -0.221 0.77855E+04 78 fayalite 14.05 9.37 -4.68 -0.668 0.79880E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.99 -4.15 -0.346 0.70836E+04 92 hercynite 17.28 12.49 -4.79 -0.319 0.81739E+04 98 kaolinite -1.33 -2.49 -1.16 -0.106 0.19824E+04 99 kyanite 4.88 1.63 -3.25 -0.325 0.55481E+04 101 laumontite 2.88 -0.51 -3.40 -0.227 0.58013E+04 102 lawsonite 9.62 7.73 -1.89 -0.126 0.32256E+04 105 lizardite 23.24 18.45 -4.80 -0.400 0.81938E+04 106 magnesite 0.69 -3.49 -4.18 -1.392 0.71327E+04 107 magnetite 20.09 19.31 -0.78 -0.063 0.13270E+04 110 magnesioferrite 26.21 21.46 -4.75 -0.388 0.81118E+04 113 margarite 17.32 13.47 -3.85 -0.154 0.65724E+04 120 muscovite 2.58 -2.08 -4.66 -0.274 0.79596E+04 121 paragonite 4.24 -0.08 -4.32 -0.254 0.73727E+04 128 periclase-Fe 11.63 6.74 -4.88 -1.221 0.83368E+04 142 pyrite -21.25 -25.88 -4.64 -1.091 0.79158E+04 143 pyrrhotite -4.26 -9.11 -4.85 -1.616 0.82781E+04 144 pyrrhotiteFe0.875 -6.02 -10.07 -4.05 -1.489 0.69133E+04 145 pyroxmangite 7.40 3.79 -3.61 -0.722 0.61656E+04 146 pyrophyllite -6.18 -10.73 -4.56 -0.285 0.77846E+04 147 quartz -2.99 -4.12 -1.13 -0.377 0.19314E+04 151 rhodochrosite -0.98 -4.47 -3.50 -1.166 0.59719E+04 152 rhodonite 7.45 3.79 -3.66 -0.732 0.62459E+04 155 siderite -2.61 -5.64 -3.03 -1.010 0.51736E+04 156 sillimanite 5.26 1.63 -3.63 -0.363 0.62062E+04 168 sudoite 21.08 16.92 -4.15 -0.134 0.70920E+04 177 topaz-H 4.62 1.63 -2.99 -0.272 0.51082E+04 178 tridymite -2.63 -4.12 -1.49 -0.498 0.25514E+04 181 troilite-low -4.41 -9.11 -4.70 -1.566 0.80209E+04 187 wairakite 3.95 -0.51 -4.46 -0.263 0.76233E+04 189 wollastonite 10.46 6.10 -4.36 -0.872 0.74462E+04 190 pseudo-wollastonite 11.00 6.10 -4.90 -0.980 0.83661E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 199 chalcedony -2.80 -4.12 -1.32 -0.439 0.22507E+04 201 montmorillonite-Ca -2.29 -7.06 -4.77 -0.295 0.81457E+04 203 montmorillonite-Mg -2.48 -7.28 -4.80 -0.297 0.81962E+04 205 nontronite-Ca 3.21 0.08 -3.14 -0.203 0.53549E+04 206 nontronite-H 2.53 -1.61 -4.14 -0.278 0.70702E+04 207 nontronite-K 3.34 -1.06 -4.40 -0.282 0.75137E+04 208 nontronite-Mg 3.07 -0.14 -3.21 -0.209 0.54894E+04 209 nontronite-Na 3.52 -0.40 -3.92 -0.252 0.66920E+04 214 gypsum -4.96 -9.32 -4.36 -1.091 0.74517E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.74 -3.07 -0.767 0.52378E+04 240 silica-amorphous -2.09 -4.12 -2.03 -0.676 0.34649E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0080000 g New total amount of reactant added: 0.0084000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1648E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0084000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2694577E-03 Osmotic coef. = 0.9901 True ionic strength = .2727331E-03 Chg. balance for total moles = 0.1648E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.35131E-07 -7.4543 0.33755E-07 -7.4717 0.96083E+00 -0.0174 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13254E-03 -3.8776 0.96071E+00 -0.0174 4 SO4-- 0.25344E-04 -4.5961 0.22785E-04 -4.6424 0.89900E+00 -0.0462 5 HCO3- 0.12177E-04 -4.9144 0.11699E-04 -4.9318 0.96074E+00 -0.0174 6 HS- 0.27376E-08 -8.5626 0.26300E-08 -8.5800 0.96072E+00 -0.0174 7 Al+++ 0.35740E-19 -19.4468 0.28754E-19 -19.5413 0.80452E+00 -0.0945 8 H4SiO4 0.79311E-04 -4.1007 0.79311E-04 -4.1007 0.10000E+01 0.0000 9 Ca++ 0.23844E-04 -4.6226 0.21432E-04 -4.6689 0.89887E+00 -0.0463 10 Mg++ 0.98075E-06 -6.0084 0.88149E-06 -6.0548 0.89879E+00 -0.0463 11 Fe++ 0.67273E-08 -8.1722 0.60465E-08 -8.2185 0.89881E+00 -0.0463 12 K+ 0.17828E-05 -5.7489 0.17128E-05 -5.7663 0.96075E+00 -0.0174 13 Na+ 0.17060E-03 -3.7680 0.16390E-03 -3.7854 0.96071E+00 -0.0174 14 Mn++ 0.11645E-06 -6.9339 0.10467E-06 -6.9802 0.89882E+00 -0.0463 15 HPO4-- 0.65223E-08 -8.1856 0.58636E-08 -8.2318 0.89900E+00 -0.0462 16 HSiO3- 0.22837E-05 -5.6414 0.21939E-05 -5.6588 0.96071E+00 -0.0174 17 Ca(HSiO3)+ 0.11146E-08 -8.9529 0.10709E-08 -8.9703 0.96075E+00 -0.0174 18 Mg(HSiO3)+ 0.57051E-10 -10.2437 0.54812E-10 -10.2611 0.96075E+00 -0.0174 19 NaHSiO3,aq 0.58158E-08 -8.2354 0.58158E-08 -8.2354 0.10000E+01 0.0000 20 AlO+ 0.35735E-11 -11.4469 0.34333E-11 -11.4643 0.96075E+00 -0.0174 21 AlOH+2 0.64200E-15 -15.1925 0.57705E-15 -15.2388 0.89884E+00 -0.0463 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.13827E-05 -5.8593 0.13283E-05 -5.8767 0.96068E+00 -0.0174 24 CH4,aq 0.13119E-14 -14.8821 0.13118E-14 -14.8821 0.99992E+00 0.0000 29 CO,aq 0.61768E-16 -16.2092 0.61768E-16 -16.2092 0.10000E+01 0.0000 30 CO2,aq 0.84389E-06 -6.0737 0.84382E-06 -6.0738 0.99992E+00 0.0000 31 CO3-2 0.33677E-07 -7.4727 0.30274E-07 -7.5189 0.89896E+00 -0.0463 32 CaCO3,aq 0.81358E-08 -8.0896 0.81358E-08 -8.0896 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.66620E-08 -8.1764 0.64005E-08 -8.1938 0.96075E+00 -0.0174 34 CaCl+ 0.47850E-08 -8.3201 0.45972E-08 -8.3375 0.96075E+00 -0.0174 35 CaCl2,aq 0.14476E-12 -12.8393 0.14476E-12 -12.8393 0.10000E+01 0.0000 36 CaOH+ 0.47101E-07 -7.3270 0.45253E-07 -7.3444 0.96075E+00 -0.0174 37 CaSO4,aq 0.15507E-06 -6.8095 0.15507E-06 -6.8095 0.10000E+01 0.0000 38 HCl,aq 0.81983E-12 -12.0863 0.81983E-12 -12.0863 0.10000E+01 0.0000 43 FeCl+ 0.13203E-11 -11.8793 0.12685E-11 -11.8967 0.96075E+00 -0.0174 46 FeO,aq 0.20625E-09 -9.6856 0.20625E-09 -9.6856 0.10000E+01 0.0000 47 FeOH+ 0.60691E-08 -8.2169 0.58309E-08 -8.2343 0.96075E+00 -0.0174 48 HFeO2- 0.66548E-10 -10.1769 0.63934E-10 -10.1943 0.96071E+00 -0.0174 49 FeO+ 0.26817E-12 -12.5716 0.25765E-12 -12.5890 0.96075E+00 -0.0174 50 FeOH+2 0.18477E-17 -17.7334 0.16608E-17 -17.7797 0.89884E+00 -0.0463 51 FeO2- 0.48163E-10 -10.3173 0.46271E-10 -10.3347 0.96071E+00 -0.0174 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.29142E-08 -8.5355 0.29139E-08 -8.5355 0.99992E+00 0.0000 54 KCl,aq 0.41146E-11 -11.3857 0.41146E-11 -11.3857 0.10000E+01 0.0000 55 KHSO4,aq 0.37245E-17 -17.4289 0.37245E-17 -17.4289 0.10000E+01 0.0000 56 KOH,aq 0.21670E-10 -10.6641 0.21670E-10 -10.6641 0.10000E+01 0.0000 57 KSO4- 0.63035E-09 -9.2004 0.60558E-09 -9.2178 0.96071E+00 -0.0174 58 MgCO3,aq 0.83873E-10 -10.0764 0.83873E-10 -10.0764 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27997E-09 -9.5529 0.26899E-09 -9.5703 0.96075E+00 -0.0174 60 MgCl+ 0.17837E-09 -9.7487 0.17137E-09 -9.7661 0.96075E+00 -0.0174 61 MgOH+ 0.10720E-07 -7.9698 0.10299E-07 -7.9872 0.96075E+00 -0.0174 63 MnO,aq 0.95132E-10 -10.0217 0.95132E-10 -10.0217 0.10000E+01 0.0000 64 MnOH+ 0.97594E-08 -8.0106 0.93763E-08 -8.0280 0.96075E+00 -0.0174 65 MnO2-2 0.30824E-17 -17.5111 0.27710E-17 -17.5574 0.89896E+00 -0.0463 66 HMnO2- 0.21330E-13 -13.6710 0.20492E-13 -13.6884 0.96071E+00 -0.0174 69 MnCl+ 0.88916E-10 -10.0510 0.85426E-10 -10.0684 0.96075E+00 -0.0174 70 MnSO4,aq 0.68846E-09 -9.1621 0.68846E-09 -9.1621 0.10000E+01 0.0000 71 NaCl,aq 0.71992E-08 -8.1427 0.71992E-08 -8.1427 0.10000E+01 0.0000 72 NaOH,aq 0.20862E-08 -8.6806 0.20862E-08 -8.6806 0.10000E+01 0.0000 74 OH- 0.17817E-04 -4.7492 0.17117E-04 -4.7666 0.96068E+00 -0.0174 79 HPO3-2 0.59230E-19 -19.2275 0.53246E-19 -19.2737 0.89896E+00 -0.0463 82 H3PO4,aq 0.46725E-13 -13.3304 0.46725E-13 -13.3304 0.10000E+01 0.0000 83 H2PO4- 0.38004E-08 -8.4202 0.36511E-08 -8.4376 0.96073E+00 -0.0174 84 PO4-3 0.17599E-12 -12.7545 0.14173E-12 -12.8485 0.80532E+00 -0.0940 87 H2P2O7-2 0.11627E-17 -17.9345 0.10453E-17 -17.9808 0.89896E+00 -0.0463 88 HP2O7-3 0.76856E-17 -17.1143 0.61833E-17 -17.2088 0.80453E+00 -0.0945 89 P2O7-4 0.63499E-19 -19.1972 0.43762E-19 -19.3589 0.68918E+00 -0.1617 90 H2S,aq 0.27439E-09 -9.5616 0.27437E-09 -9.5617 0.99992E+00 0.0000 91 S2-2 0.58510E-19 -19.2328 0.52598E-19 -19.2790 0.89896E+00 -0.0463 96 SO2,aq 0.33783E-18 -18.4713 0.33783E-18 -18.4713 0.10000E+01 0.0000 97 SO3-2 0.95946E-14 -14.0180 0.86277E-14 -14.0641 0.89923E+00 -0.0461 98 HSO3- 0.18980E-13 -13.7217 0.18234E-13 -13.7391 0.96071E+00 -0.0174 99 HSO4- 0.77145E-09 -9.1127 0.74118E-09 -9.1301 0.96077E+00 -0.0174 101 S2O3-2 0.81688E-16 -16.0878 0.73435E-16 -16.1341 0.89896E+00 -0.0463 Charge balance for all species = 0.1648E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3513063E-07 -.2493559E-04 -.2513310E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999790E+06 0.0000 3 Cl- 0.1379624E-03 0.1379746E-03 0.4891521E+01 3.5940 4 SO4-- 0.2534438E-04 0.2550084E-04 0.2449605E+01 10.3010 5 HCO3- 0.1217732E-04 0.1307004E-04 0.7974822E+00 2.5398 6 HS- 0.2737562E-08 0.3709624E-08 0.1226823E-03 -1.1084 7 Al+++ 0.3574037E-19 0.1402975E-05 0.3785365E-01 2.8737 8 H4SiO4 0.7931074E-04 0.8160138E-04 0.7843000E+01 -4.1007 9 Ca++ 0.2384383E-04 0.2406670E-04 0.9645266E+00 10.2744 10 Mg++ 0.9807538E-06 0.9920726E-06 0.2411881E-01 8.8885 11 Fe++ 0.6727275E-08 0.1331759E-07 0.7437334E-03 6.7248 12 K+ 0.1782789E-05 0.1783445E-05 0.6973495E-01 1.7054 13 Na+ 0.1706005E-03 0.1706156E-03 0.3922344E+01 3.6862 14 Mn++ 0.1164471E-06 0.1270791E-06 0.6981336E-02 7.9631 15 HPO4-- 0.6522282E-08 0.1032286E-07 0.9907587E-03 6.7115 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1260515E-03 -.2493551E-04 -.1011160E-03 0.0000000E+00 2 H2O 0.5550814E+02 0.5550809E+02 0.5779050E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2573726E-04 0.2550076E-04 0.2365022E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2327926E-06 0.3709612E-08 -.2365022E-06 0.0000000E+00 7 Al+++ 0.2739023E-04 0.1402971E-05 0.2598726E-04 0.0000000E+00 8 H4SiO4 0.8746738E-04 0.8160112E-04 0.5866260E-05 0.0000000E+00 9 Ca++ 0.2413226E-04 0.2406662E-04 0.6564137E-07 0.0000000E+00 10 Mg++ 0.6666667E-05 0.9920693E-06 0.5674597E-05 0.0000000E+00 11 Fe++ 0.5989272E-05 0.1331755E-07 0.5975955E-05 0.0000000E+00 12 K+ 0.1783439E-05 0.1783439E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1706150E-03 0.1706150E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1456442E-06 0.1270786E-06 0.1856557E-07 0.0000000E+00 15 HPO4-- 0.4970764E-07 0.1032282E-07 0.3938482E-07 0.0000000E+00 Chg. balance for solid moles: -.5042E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0084000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1313E-07 -7.882 0.6595E-05 -5.181 0.2444 0.2096E-05 clinochlore 0.1135E-05 -5.945 0.6308E-03 -3.200 23.38 0.2399E-03 daphnite 0.8168E-06 -6.088 0.5828E-03 -3.234 21.60 0.1766E-03 chlorite-Mn 0.3713E-08 -8.430 0.2632E-05 -5.580 0.9756E-01 0.8389E-06 diaspore 0.2208E-04 -4.656 0.1324E-02 -2.878 49.08 0.3943E-03 hematite 0.9460E-06 -6.024 0.1511E-03 -3.821 5.599 0.2863E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5804E+00 0.5804E+00 1.0000 -0.236 daphnite 0.4177E+00 0.4177E+00 1.0000 -0.379 chlorite-Mn 0.1899E-02 0.1899E-02 1.0000 -2.722 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002698 g Volume = 0.000842 cm3 Porosity: 99.9160% V(tot) - V(min): 0.10025E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0084000 g log = -2.0757 Original solution: 1000.0103000 g Original solution / Rock added: 119048.85 (Water/Rock Ratio), log = 5.0757 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.8785E-04 1.0071 0.9028E-04 0.8964E-04 CH4,gas 0.1869E-11 1.0125 0.1931E-11 0.1907E-11 H2,gas 0.3747E-05 1.0005 0.3826E-05 0.3824E-05 H2S,gas 0.7421E-08 0.9960 0.7542E-08 0.7572E-08 S2,gas 0.1430E-24 1.0000 0.1459E-24 0.1459E-24 CO,gas 0.9021E-13 1.0000 0.9205E-13 0.9205E-13 SO3,gas 0.9620E-35 1.0000 0.9816E-35 0.9816E-35 SO2,gas 0.1432E-17 1.0000 0.1461E-17 0.1461E-17 HCl,gas 0.1418E-14 1.0000 0.1447E-14 0.1447E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.40 -5.74 -1.914 0.98067E+04 -4.044 3 CH4,gas 4.54 -8.87 -13.41 -3.353 0.22903E+05 -11.714 4 H2,gas 8.00 0.88 -7.12 -4.066 0.12151E+05 -5.417 5 H2S,gas -6.23 -16.05 -9.82 -4.911 0.16770E+05 -8.122 6 S2,gas -7.34 -33.87 -26.53 -4.082 0.45308E+05 -24.836 7 CO,gas 3.21 -11.52 -14.73 -4.534 0.25160E+05 -13.036 8 SO3,gas 17.12 -19.59 -36.71 -9.177 0.62676E+05 -35.008 9 SO2,gas 0.83 -18.70 -19.53 -5.209 0.33354E+05 -17.835 10 HCl,gas 5.19 -11.35 -16.54 -8.269 0.28239E+05 -14.840 20 analcite 3.32 -1.64 -4.96 -0.551 0.84746E+04 21 andalusite 5.00 1.65 -3.35 -0.335 0.57282E+04 24 anhydrite -5.32 -9.31 -3.99 -1.997 0.68205E+04 29 anorthite 12.71 7.82 -4.89 -0.376 0.83493E+04 35 aragonite 0.97 -2.13 -3.10 -1.032 0.52857E+04 36 brucite 12.57 8.89 -3.68 -0.736 0.62835E+04 37 calcite 0.81 -2.13 -2.94 -0.980 0.50215E+04 40 carpholite-Mg 8.58 6.43 -2.15 -0.143 0.36668E+04 41 carpholite-Fe 6.71 4.27 -2.44 -0.163 0.41692E+04 50 chloritoid-Mg 13.20 10.54 -2.66 -0.177 0.45460E+04 51 chloritoid-Fe 9.17 8.37 -0.80 -0.053 0.13695E+04 52 chloritoid-Mn 11.40 9.61 -1.79 -0.119 0.30584E+04 54 coesite -2.38 -4.10 -1.72 -0.575 0.29447E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -4.10 -1.54 -0.513 0.26301E+04 75 epidote 24.67 20.28 -4.39 -0.213 0.75003E+04 78 fayalite 14.05 9.35 -4.70 -0.671 0.80195E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.97 -4.17 -0.347 0.71139E+04 92 hercynite 17.28 12.47 -4.81 -0.320 0.82066E+04 98 kaolinite -1.33 -2.45 -1.12 -0.102 0.19144E+04 99 kyanite 4.88 1.65 -3.23 -0.323 0.55141E+04 101 laumontite 2.88 -0.38 -3.26 -0.218 0.55737E+04 102 lawsonite 9.62 7.82 -1.80 -0.120 0.30660E+04 105 lizardite 23.24 18.46 -4.78 -0.398 0.81609E+04 106 magnesite 0.69 -3.51 -4.21 -1.402 0.71809E+04 107 magnetite 20.09 19.29 -0.80 -0.065 0.13598E+04 110 magnesioferrite 26.21 21.45 -4.76 -0.388 0.81236E+04 113 margarite 17.32 13.57 -3.76 -0.150 0.64129E+04 120 muscovite 2.58 -1.98 -4.56 -0.268 0.77826E+04 121 paragonite 4.24 0.01 -4.23 -0.249 0.72296E+04 128 periclase-Fe 11.63 6.72 -4.90 -1.225 0.83696E+04 144 pyrrhotiteFe0.875 -6.02 -10.28 -4.26 -1.567 0.72740E+04 145 pyroxmangite 7.40 3.86 -3.54 -0.707 0.60380E+04 146 pyrophyllite -6.18 -10.66 -4.48 -0.280 0.76486E+04 147 quartz -2.99 -4.10 -1.11 -0.370 0.18974E+04 151 rhodochrosite -0.98 -4.44 -3.46 -1.155 0.59148E+04 152 rhodonite 7.45 3.86 -3.58 -0.717 0.61182E+04 155 siderite -2.61 -5.68 -3.07 -1.024 0.52428E+04 156 sillimanite 5.26 1.65 -3.61 -0.361 0.61722E+04 168 sudoite 21.08 16.97 -4.11 -0.132 0.70134E+04 177 topaz-H 4.62 1.65 -2.97 -0.270 0.50742E+04 178 tridymite -2.63 -4.10 -1.47 -0.491 0.25174E+04 181 troilite-low -4.41 -9.33 -4.92 -1.639 0.83938E+04 187 wairakite 3.95 -0.38 -4.33 -0.255 0.73956E+04 189 wollastonite 10.46 6.17 -4.29 -0.857 0.73206E+04 190 pseudo-wollastonite 11.00 6.17 -4.83 -0.965 0.82405E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 199 chalcedony -2.80 -4.10 -1.30 -0.433 0.22167E+04 201 montmorillonite-Ca -2.29 -6.98 -4.68 -0.290 0.79985E+04 203 montmorillonite-Mg -2.48 -7.20 -4.72 -0.292 0.80659E+04 205 nontronite-Ca 3.21 0.16 -3.05 -0.198 0.52150E+04 206 nontronite-H 2.53 -1.53 -4.07 -0.273 0.69454E+04 207 nontronite-K 3.34 -0.97 -4.31 -0.277 0.73641E+04 208 nontronite-Mg 3.07 -0.07 -3.14 -0.204 0.53665E+04 209 nontronite-Na 3.52 -0.32 -3.84 -0.246 0.65536E+04 214 gypsum -4.96 -9.31 -4.36 -1.089 0.74380E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.72 -3.09 -0.772 0.52705E+04 240 silica-amorphous -2.09 -4.10 -2.01 -0.670 0.34309E+04 243 an25ab75 2.65 -2.35 -5.00 -0.384 0.85325E+04 244 an30ab70 3.28 -1.67 -4.95 -0.381 0.84564E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0084000 g New total amount of reactant added: 0.0088000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1648E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0088000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2707661E-03 Osmotic coef. = 0.9901 True ionic strength = .2743361E-03 Chg. balance for total moles = 0.1648E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.33390E-07 -7.4764 0.32080E-07 -7.4938 0.96077E+00 -0.0174 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13253E-03 -3.8777 0.96065E+00 -0.0174 4 SO4-- 0.25343E-04 -4.5962 0.22777E-04 -4.6425 0.89877E+00 -0.0464 5 HCO3- 0.12214E-04 -4.9131 0.11734E-04 -4.9306 0.96068E+00 -0.0174 6 HS- 0.18841E-08 -8.7249 0.18100E-08 -8.7423 0.96066E+00 -0.0174 7 Al+++ 0.30698E-19 -19.5129 0.24683E-19 -19.6076 0.80406E+00 -0.0947 8 H4SiO4 0.82865E-04 -4.0816 0.82865E-04 -4.0816 0.10000E+01 0.0000 9 Ca++ 0.24291E-04 -4.6146 0.21829E-04 -4.6610 0.89864E+00 -0.0464 10 Mg++ 0.87127E-06 -6.0598 0.78288E-06 -6.1063 0.89856E+00 -0.0465 11 Fe++ 0.58377E-08 -8.2338 0.52456E-08 -8.2802 0.89858E+00 -0.0464 12 K+ 0.18677E-05 -5.7287 0.17943E-05 -5.7461 0.96069E+00 -0.0174 13 Na+ 0.17110E-03 -3.7667 0.16437E-03 -3.7842 0.96065E+00 -0.0174 14 Mn++ 0.11839E-06 -6.9267 0.10639E-06 -6.9731 0.89859E+00 -0.0464 15 HPO4-- 0.59126E-08 -8.2282 0.53141E-08 -8.2746 0.89878E+00 -0.0463 16 HSiO3- 0.25107E-05 -5.6002 0.24119E-05 -5.6176 0.96065E+00 -0.0174 17 Ca(HSiO3)+ 0.12481E-08 -8.9038 0.11990E-08 -8.9212 0.96069E+00 -0.0174 18 Mg(HSiO3)+ 0.55708E-10 -10.2541 0.53518E-10 -10.2715 0.96069E+00 -0.0174 19 NaHSiO3,aq 0.64120E-08 -8.1930 0.64120E-08 -8.1930 0.10000E+01 0.0000 20 AlO+ 0.33964E-11 -11.4690 0.32629E-11 -11.4864 0.96069E+00 -0.0174 21 AlOH+2 0.58002E-15 -15.2366 0.52121E-15 -15.2830 0.89861E+00 -0.0464 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.14550E-05 -5.8371 0.13977E-05 -5.8546 0.96062E+00 -0.0174 24 CH4,aq 0.90581E-15 -15.0430 0.90574E-15 -15.0430 0.99992E+00 0.0000 29 CO,aq 0.54317E-16 -16.2651 0.54317E-16 -16.2651 0.10000E+01 0.0000 30 CO2,aq 0.80440E-06 -6.0945 0.80433E-06 -6.0946 0.99992E+00 0.0000 31 CO3-2 0.35549E-07 -7.4492 0.31949E-07 -7.4955 0.89873E+00 -0.0464 32 CaCO3,aq 0.87447E-08 -8.0583 0.87447E-08 -8.0583 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.68057E-08 -8.1671 0.65382E-08 -8.1845 0.96069E+00 -0.0174 34 CaCl+ 0.48734E-08 -8.3122 0.46819E-08 -8.3296 0.96069E+00 -0.0174 35 CaCl2,aq 0.14742E-12 -12.8314 0.14742E-12 -12.8314 0.10000E+01 0.0000 36 CaOH+ 0.50480E-07 -7.2969 0.48495E-07 -7.3143 0.96069E+00 -0.0174 37 CaSO4,aq 0.15788E-06 -6.8017 0.15788E-06 -6.8017 0.10000E+01 0.0000 38 HCl,aq 0.77910E-12 -12.1084 0.77910E-12 -12.1084 0.10000E+01 0.0000 43 FeCl+ 0.11455E-11 -11.9410 0.11004E-11 -11.9584 0.96069E+00 -0.0174 46 FeO,aq 0.19811E-09 -9.7031 0.19811E-09 -9.7031 0.10000E+01 0.0000 47 FeOH+ 0.55405E-08 -8.2565 0.53227E-08 -8.2739 0.96069E+00 -0.0174 48 HFeO2- 0.67260E-10 -10.1722 0.64614E-10 -10.1897 0.96065E+00 -0.0174 49 FeO+ 0.25488E-12 -12.5937 0.24486E-12 -12.6111 0.96069E+00 -0.0174 50 FeOH+2 0.16694E-17 -17.7774 0.15001E-17 -17.8239 0.89861E+00 -0.0464 51 FeO2- 0.50680E-10 -10.2952 0.48686E-10 -10.3126 0.96065E+00 -0.0174 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.26885E-08 -8.5705 0.26882E-08 -8.5705 0.99992E+00 0.0000 54 KCl,aq 0.43099E-11 -11.3655 0.43099E-11 -11.3655 0.10000E+01 0.0000 55 KHSO4,aq 0.37068E-17 -17.4310 0.37068E-17 -17.4310 0.10000E+01 0.0000 56 KOH,aq 0.23886E-10 -10.6219 0.23886E-10 -10.6219 0.10000E+01 0.0000 57 KSO4- 0.66015E-09 -9.1804 0.63417E-09 -9.1978 0.96065E+00 -0.0174 58 MgCO3,aq 0.78613E-10 -10.1045 0.78613E-10 -10.1045 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24941E-09 -9.6031 0.23961E-09 -9.6205 0.96069E+00 -0.0174 60 MgCl+ 0.15842E-09 -9.8002 0.15219E-09 -9.8176 0.96069E+00 -0.0174 61 MgOH+ 0.10018E-07 -7.9992 0.96243E-08 -8.0166 0.96069E+00 -0.0174 63 MnO,aq 0.10706E-09 -9.9704 0.10706E-09 -9.9704 0.10000E+01 0.0000 64 MnOH+ 0.10439E-07 -7.9814 0.10028E-07 -7.9988 0.96069E+00 -0.0174 65 MnO2-2 0.38415E-17 -17.4155 0.34524E-17 -17.4619 0.89873E+00 -0.0464 66 HMnO2- 0.25258E-13 -13.5976 0.24264E-13 -13.6150 0.96065E+00 -0.0174 69 MnCl+ 0.90380E-10 -10.0439 0.86828E-10 -10.0613 0.96069E+00 -0.0174 70 MnSO4,aq 0.69957E-09 -9.1552 0.69957E-09 -9.1552 0.10000E+01 0.0000 71 NaCl,aq 0.72194E-08 -8.1415 0.72194E-08 -8.1415 0.10000E+01 0.0000 72 NaOH,aq 0.22014E-08 -8.6573 0.22014E-08 -8.6573 0.10000E+01 0.0000 74 OH- 0.18749E-04 -4.7270 0.18010E-04 -4.7445 0.96062E+00 -0.0174 79 HPO3-2 0.49535E-19 -19.3051 0.44519E-19 -19.3515 0.89873E+00 -0.0464 82 H3PO4,aq 0.38249E-13 -13.4174 0.38249E-13 -13.4174 0.10000E+01 0.0000 83 H2PO4- 0.32736E-08 -8.4850 0.31448E-08 -8.5024 0.96067E+00 -0.0174 84 PO4-3 0.16792E-12 -12.7749 0.13515E-12 -12.8692 0.80487E+00 -0.0943 87 H2P2O7-2 0.86285E-18 -18.0641 0.77548E-18 -18.1104 0.89873E+00 -0.0464 88 HP2O7-3 0.60030E-17 -17.2216 0.48268E-17 -17.3163 0.80407E+00 -0.0947 89 P2O7-4 0.52209E-19 -19.2823 0.35945E-19 -19.4444 0.68848E+00 -0.1621 90 H2S,aq 0.17947E-09 -9.7460 0.17945E-09 -9.7461 0.99992E+00 0.0000 91 S2-2 0.30045E-19 -19.5222 0.27002E-19 -19.5686 0.89873E+00 -0.0464 96 SO2,aq 0.28142E-18 -18.5507 0.28142E-18 -18.5507 0.10000E+01 0.0000 97 SO3-2 0.88508E-14 -14.0530 0.79568E-14 -14.0993 0.89900E+00 -0.0462 98 HSO3- 0.16637E-13 -13.7789 0.15982E-13 -13.7964 0.96065E+00 -0.0174 99 HSO4- 0.73298E-09 -9.1349 0.70418E-09 -9.1523 0.96071E+00 -0.0174 101 S2O3-2 0.53424E-16 -16.2723 0.48014E-16 -16.3186 0.89873E+00 -0.0464 Charge balance for all species = 0.1648E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3338974E-07 -.2643112E-04 -.2664047E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999786E+06 0.0000 3 Cl- 0.1379623E-03 0.1379747E-03 0.4891520E+01 3.6161 4 SO4-- 0.2534252E-04 0.2550185E-04 0.2449701E+01 10.3450 5 HCO3- 0.1221422E-04 0.1307004E-04 0.7974820E+00 2.5632 6 HS- 0.1884078E-08 0.2704469E-08 0.8944045E-04 -1.2486 7 Al+++ 0.3069776E-19 0.1475252E-05 0.3980374E-01 2.8737 8 H4SiO4 0.8286529E-04 0.8538374E-04 0.8206532E+01 -4.0816 9 Ca++ 0.2429088E-04 0.2452092E-04 0.9827302E+00 10.3266 10 Mg++ 0.8712687E-06 0.8818289E-06 0.2143861E-01 8.8812 11 Fe++ 0.5837717E-08 0.1189428E-07 0.6642469E-03 6.7073 12 K+ 0.1867683E-05 0.1868372E-05 0.7305564E-01 1.7477 13 Na+ 0.1711019E-03 0.1711177E-03 0.3933886E+01 3.7096 14 Mn++ 0.1183948E-06 0.1297305E-06 0.7126995E-02 8.0144 15 HPO4-- 0.5912637E-08 0.9186423E-08 0.8816865E-03 6.7130 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1326749E-03 -.2643103E-04 -.1062439E-03 0.0000000E+00 2 H2O 0.5550814E+02 0.5550808E+02 0.6059154E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2574835E-04 0.2550177E-04 0.2465825E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2438780E-06 0.2704460E-08 -.2465825E-06 0.0000000E+00 7 Al+++ 0.2869453E-04 0.1475247E-05 0.2721928E-04 0.0000000E+00 8 H4SiO4 0.9163249E-04 0.8538345E-04 0.6249043E-05 0.0000000E+00 9 Ca++ 0.2459232E-04 0.2452083E-04 0.7148047E-07 0.0000000E+00 10 Mg++ 0.6984127E-05 0.8818259E-06 0.6102301E-05 0.0000000E+00 11 Fe++ 0.6274476E-05 0.1189424E-07 0.6262581E-05 0.0000000E+00 12 K+ 0.1868365E-05 0.1868365E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1711171E-03 0.1711171E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1525796E-06 0.1297300E-06 0.2284960E-07 0.0000000E+00 15 HPO4-- 0.5207467E-07 0.9186392E-08 0.4288828E-07 0.0000000E+00 Chg. balance for solid moles: -.3269E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0088000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1430E-07 -7.845 0.7181E-05 -5.144 0.2527 0.2282E-05 clinochlore 0.1220E-05 -5.913 0.6784E-03 -3.169 23.87 0.2580E-03 daphnite 0.8580E-06 -6.067 0.6122E-03 -3.213 21.54 0.1855E-03 chlorite-Mn 0.4570E-08 -8.340 0.3240E-05 -5.489 0.1140 0.1032E-05 diaspore 0.2305E-04 -4.637 0.1383E-02 -2.859 48.67 0.4117E-03 hematite 0.9863E-06 -6.006 0.1575E-03 -3.803 5.544 0.2986E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5859E+00 0.5859E+00 1.0000 -0.232 daphnite 0.4119E+00 0.4119E+00 1.0000 -0.385 chlorite-Mn 0.2194E-02 0.2194E-02 1.0000 -2.659 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002841 g Volume = 0.000888 cm3 Porosity: 99.9115% V(tot) - V(min): 0.10026E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0088000 g log = -2.0555 Original solution: 1000.0103000 g Original solution / Rock added: 113637.53 (Water/Rock Ratio), log = 5.0555 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.8374E-04 1.0071 0.8605E-04 0.8545E-04 CH4,gas 0.1290E-11 1.0125 0.1333E-11 0.1317E-11 H2,gas 0.3457E-05 1.0005 0.3529E-05 0.3527E-05 H2S,gas 0.4854E-08 0.9960 0.4933E-08 0.4953E-08 S2,gas 0.7187E-25 1.0000 0.7333E-25 0.7333E-25 CO,gas 0.7933E-13 1.0000 0.8094E-13 0.8094E-13 SO3,gas 0.8686E-35 1.0000 0.8863E-35 0.8863E-35 SO2,gas 0.1193E-17 1.0000 0.1217E-17 0.1217E-17 HCl,gas 0.1347E-14 1.0000 0.1375E-14 0.1375E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.42 -5.76 -1.921 0.98422E+04 -4.065 3 CH4,gas 4.54 -9.03 -13.57 -3.394 0.23177E+05 -11.875 4 H2,gas 8.00 0.85 -7.15 -4.086 0.12211E+05 -5.452 5 H2S,gas -6.23 -16.24 -10.01 -5.003 0.17085E+05 -8.307 6 S2,gas -7.34 -34.17 -26.83 -4.128 0.45818E+05 -25.135 7 CO,gas 3.21 -11.58 -14.79 -4.551 0.25255E+05 -13.092 8 SO3,gas 17.12 -19.63 -36.75 -9.188 0.62752E+05 -35.052 9 SO2,gas 0.83 -18.78 -19.61 -5.230 0.33490E+05 -17.915 10 HCl,gas 5.19 -11.37 -16.56 -8.280 0.28277E+05 -14.862 20 analcite 3.32 -1.58 -4.90 -0.545 0.83697E+04 21 andalusite 5.00 1.67 -3.34 -0.334 0.56957E+04 24 anhydrite -5.32 -9.30 -3.99 -1.993 0.68071E+04 29 anorthite 12.71 7.91 -4.80 -0.369 0.81952E+04 35 aragonite 0.97 -2.10 -3.06 -1.021 0.52322E+04 36 brucite 12.57 8.88 -3.69 -0.737 0.62960E+04 37 calcite 0.81 -2.10 -2.91 -0.970 0.49679E+04 40 carpholite-Mg 8.58 6.47 -2.12 -0.141 0.36142E+04 41 carpholite-Fe 6.71 4.29 -2.42 -0.161 0.41341E+04 50 chloritoid-Mg 13.20 10.55 -2.65 -0.177 0.45260E+04 51 chloritoid-Fe 9.17 8.37 -0.80 -0.053 0.13669E+04 52 chloritoid-Mn 11.40 9.68 -1.72 -0.115 0.29383E+04 54 coesite -2.38 -4.08 -1.71 -0.569 0.29122E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -4.08 -1.52 -0.507 0.25976E+04 75 epidote 24.67 20.44 -4.23 -0.205 0.72246E+04 78 fayalite 14.05 9.33 -4.71 -0.673 0.80468E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.96 -4.18 -0.348 0.71385E+04 92 hercynite 17.28 12.45 -4.82 -0.322 0.82365E+04 98 kaolinite -1.33 -2.42 -1.08 -0.098 0.18494E+04 99 kyanite 4.88 1.67 -3.21 -0.321 0.54816E+04 101 laumontite 2.88 -0.25 -3.14 -0.209 0.53546E+04 102 lawsonite 9.62 7.91 -1.71 -0.114 0.29119E+04 105 lizardite 23.24 18.48 -4.76 -0.397 0.81334E+04 106 magnesite 0.69 -3.54 -4.23 -1.411 0.72289E+04 107 magnetite 20.09 19.27 -0.81 -0.066 0.13897E+04 110 magnesioferrite 26.21 21.45 -4.76 -0.389 0.81361E+04 113 margarite 17.32 13.66 -3.67 -0.147 0.62588E+04 120 muscovite 2.58 -1.88 -4.46 -0.262 0.76129E+04 121 paragonite 4.24 0.09 -4.15 -0.244 0.70922E+04 128 periclase-Fe 11.63 6.71 -4.92 -1.230 0.83995E+04 137 prehnite-Fe 22.50 17.57 -4.93 -0.297 0.84227E+04 144 pyrrhotiteFe0.875 -6.02 -10.47 -4.46 -1.639 0.76076E+04 145 pyroxmangite 7.40 3.93 -3.47 -0.693 0.59179E+04 146 pyrophyllite -6.18 -10.58 -4.40 -0.275 0.75185E+04 147 quartz -2.99 -4.08 -1.09 -0.364 0.18649E+04 151 rhodochrosite -0.98 -4.41 -3.43 -1.145 0.58627E+04 152 rhodonite 7.45 3.93 -3.51 -0.703 0.59981E+04 155 siderite -2.61 -5.72 -3.11 -1.036 0.53083E+04 156 sillimanite 5.26 1.67 -3.60 -0.360 0.61397E+04 163 stilbite -7.52 -12.50 -4.98 -0.237 0.84953E+04 168 sudoite 21.08 17.01 -4.06 -0.131 0.69409E+04 177 topaz-H 4.62 1.67 -2.95 -0.268 0.50417E+04 178 tridymite -2.63 -4.08 -1.46 -0.485 0.24849E+04 187 wairakite 3.95 -0.25 -4.20 -0.247 0.71765E+04 189 wollastonite 10.46 6.24 -4.22 -0.843 0.71991E+04 190 pseudo-wollastonite 11.00 6.24 -4.75 -0.951 0.81189E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -6.58 -4.93 -0.305 0.84253E+04 199 chalcedony -2.80 -4.08 -1.28 -0.426 0.21842E+04 201 montmorillonite-Ca -2.29 -6.89 -4.60 -0.285 0.78578E+04 203 montmorillonite-Mg -2.48 -7.13 -4.65 -0.288 0.79421E+04 205 nontronite-Ca 3.21 0.24 -2.98 -0.193 0.50810E+04 206 nontronite-H 2.53 -1.47 -4.00 -0.268 0.68261E+04 207 nontronite-K 3.34 -0.89 -4.23 -0.271 0.72210E+04 208 nontronite-Mg 3.07 0.00 -3.07 -0.199 0.52493E+04 209 nontronite-Na 3.52 -0.24 -3.76 -0.241 0.64211E+04 214 gypsum -4.96 -9.30 -4.35 -1.087 0.74247E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.71 -3.10 -0.776 0.53004E+04 240 silica-amorphous -2.09 -4.08 -1.99 -0.663 0.33984E+04 242 an20ab80 2.02 -2.95 -4.96 -0.382 0.84775E+04 243 an25ab75 2.65 -2.27 -4.91 -0.378 0.83909E+04 244 an30ab70 3.28 -1.59 -4.87 -0.375 0.83139E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0088000 g New total amount of reactant added: 0.0092000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1648E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0092000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2721085E-03 Osmotic coef. = 0.9901 True ionic strength = .2759808E-03 Chg. balance for total moles = 0.1648E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.31787E-07 -7.4978 0.30538E-07 -7.5152 0.96071E+00 -0.0174 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13253E-03 -3.8777 0.96059E+00 -0.0175 4 SO4-- 0.25340E-04 -4.5962 0.22769E-04 -4.6427 0.89854E+00 -0.0465 5 HCO3- 0.12248E-04 -4.9119 0.11766E-04 -4.9294 0.96062E+00 -0.0174 6 HS- 0.13347E-08 -8.8746 0.12821E-08 -8.8921 0.96059E+00 -0.0175 7 Al+++ 0.26495E-19 -19.5768 0.21291E-19 -19.6718 0.80359E+00 -0.0950 8 H4SiO4 0.86417E-04 -4.0634 0.86417E-04 -4.0634 0.10000E+01 0.0000 9 Ca++ 0.24738E-04 -4.6066 0.22225E-04 -4.6532 0.89841E+00 -0.0465 10 Mg++ 0.77596E-06 -6.1102 0.69707E-06 -6.1567 0.89832E+00 -0.0466 11 Fe++ 0.50996E-08 -8.2925 0.45812E-08 -8.3390 0.89834E+00 -0.0466 12 K+ 0.19526E-05 -5.7094 0.18757E-05 -5.7268 0.96062E+00 -0.0174 13 Na+ 0.17160E-03 -3.7655 0.16484E-03 -3.7829 0.96059E+00 -0.0175 14 Mn++ 0.11979E-06 -6.9216 0.10761E-06 -6.9681 0.89836E+00 -0.0466 15 HPO4-- 0.53746E-08 -8.2697 0.48293E-08 -8.3161 0.89854E+00 -0.0465 16 HSiO3- 0.27508E-05 -5.5605 0.26423E-05 -5.5780 0.96059E+00 -0.0175 17 Ca(HSiO3)+ 0.13922E-08 -8.8563 0.13374E-08 -8.8737 0.96063E+00 -0.0174 18 Mg(HSiO3)+ 0.54343E-10 -10.2649 0.52203E-10 -10.2823 0.96063E+00 -0.0174 19 NaHSiO3,aq 0.70447E-08 -8.1521 0.70447E-08 -8.1521 0.10000E+01 0.0000 20 AlO+ 0.32333E-11 -11.4903 0.31060E-11 -11.5078 0.96063E+00 -0.0174 21 AlOH+2 0.52573E-15 -15.2792 0.47230E-15 -15.3258 0.89838E+00 -0.0465 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.15286E-05 -5.8157 0.14683E-05 -5.8332 0.96055E+00 -0.0175 24 CH4,aq 0.64362E-15 -15.1914 0.64357E-15 -15.1914 0.99992E+00 0.0000 29 CO,aq 0.48158E-16 -16.3173 0.48158E-16 -16.3173 0.10000E+01 0.0000 30 CO2,aq 0.76780E-06 -6.1147 0.76774E-06 -6.1148 0.99992E+00 0.0000 31 CO3-2 0.37455E-07 -7.4265 0.33654E-07 -7.4730 0.89850E+00 -0.0465 32 CaCO3,aq 0.93784E-08 -8.0279 0.93784E-08 -8.0279 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69485E-08 -8.1581 0.66749E-08 -8.1756 0.96063E+00 -0.0174 34 CaCl+ 0.49619E-08 -8.3044 0.47665E-08 -8.3218 0.96063E+00 -0.0174 35 CaCl2,aq 0.15007E-12 -12.8237 0.15007E-12 -12.8237 0.10000E+01 0.0000 36 CaOH+ 0.53995E-07 -7.2676 0.51869E-07 -7.2851 0.96063E+00 -0.0174 37 CaSO4,aq 0.16069E-06 -6.7940 0.16069E-06 -6.7940 0.10000E+01 0.0000 38 HCl,aq 0.74160E-12 -12.1298 0.74160E-12 -12.1298 0.10000E+01 0.0000 43 FeCl+ 0.10004E-11 -11.9998 0.96097E-12 -12.0173 0.96063E+00 -0.0174 46 FeO,aq 0.19093E-09 -9.7191 0.19093E-09 -9.7191 0.10000E+01 0.0000 47 FeOH+ 0.50834E-08 -8.2938 0.48832E-08 -8.3113 0.96063E+00 -0.0174 48 HFeO2- 0.68102E-10 -10.1668 0.65419E-10 -10.1843 0.96059E+00 -0.0175 49 FeO+ 0.24264E-12 -12.6150 0.23309E-12 -12.6325 0.96063E+00 -0.0174 50 FeOH+2 0.15131E-17 -17.8201 0.13593E-17 -17.8667 0.89838E+00 -0.0465 51 FeO2- 0.53243E-10 -10.2737 0.51145E-10 -10.2912 0.96059E+00 -0.0175 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.24972E-08 -8.6025 0.24970E-08 -8.6026 0.99992E+00 0.0000 54 KCl,aq 0.45053E-11 -11.3463 0.45053E-11 -11.3463 0.10000E+01 0.0000 55 KHSO4,aq 0.36875E-17 -17.4333 0.36875E-17 -17.4333 0.10000E+01 0.0000 56 KOH,aq 0.26231E-10 -10.5812 0.26231E-10 -10.5812 0.10000E+01 0.0000 57 KSO4- 0.68992E-09 -9.1612 0.66273E-09 -9.1787 0.96059E+00 -0.0175 58 MgCO3,aq 0.73730E-10 -10.1324 0.73730E-10 -10.1324 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22269E-09 -9.6523 0.21392E-09 -9.6697 0.96063E+00 -0.0174 60 MgCl+ 0.14105E-09 -9.8506 0.13550E-09 -9.8681 0.96063E+00 -0.0174 61 MgOH+ 0.93710E-08 -8.0282 0.90021E-08 -8.0457 0.96063E+00 -0.0174 63 MnO,aq 0.11950E-09 -9.9226 0.11950E-09 -9.9226 0.10000E+01 0.0000 64 MnOH+ 0.11093E-07 -7.9550 0.10656E-07 -7.9724 0.96063E+00 -0.0174 65 MnO2-2 0.47334E-17 -17.3248 0.42529E-17 -17.3713 0.89850E+00 -0.0465 66 HMnO2- 0.29621E-13 -13.5284 0.28453E-13 -13.5459 0.96059E+00 -0.0175 69 MnCl+ 0.91420E-10 -10.0390 0.87820E-10 -10.0564 0.96063E+00 -0.0174 70 MnSO4,aq 0.70737E-09 -9.1504 0.70737E-09 -9.1504 0.10000E+01 0.0000 71 NaCl,aq 0.72396E-08 -8.1403 0.72396E-08 -8.1403 0.10000E+01 0.0000 72 NaOH,aq 0.23192E-08 -8.6347 0.23192E-08 -8.6347 0.10000E+01 0.0000 74 OH- 0.19697E-04 -4.7056 0.18920E-04 -4.7231 0.96055E+00 -0.0175 79 HPO3-2 0.41825E-19 -19.3786 0.37580E-19 -19.4250 0.89850E+00 -0.0465 82 H3PO4,aq 0.31498E-13 -13.5017 0.31498E-13 -13.5017 0.10000E+01 0.0000 83 H2PO4- 0.28321E-08 -8.5479 0.27205E-08 -8.5653 0.96061E+00 -0.0175 84 PO4-3 0.16040E-12 -12.7948 0.12903E-12 -12.8893 0.80440E+00 -0.0945 87 H2P2O7-2 0.64589E-18 -18.1898 0.58034E-18 -18.2363 0.89850E+00 -0.0465 88 HP2O7-3 0.47221E-17 -17.3259 0.37946E-17 -17.4208 0.80360E+00 -0.0950 89 P2O7-4 0.43162E-19 -19.3649 0.29686E-19 -19.5275 0.68777E+00 -0.1626 90 H2S,aq 0.12102E-09 -9.9171 0.12101E-09 -9.9172 0.99992E+00 0.0000 91 S2-2 0.16235E-19 -19.7895 0.14587E-19 -19.8360 0.89850E+00 -0.0465 96 SO2,aq 0.23679E-18 -18.6256 0.23679E-18 -18.6256 0.10000E+01 0.0000 97 SO3-2 0.82205E-14 -14.0851 0.73883E-14 -14.1315 0.89877E+00 -0.0464 98 HSO3- 0.14706E-13 -13.8325 0.14127E-13 -13.8500 0.96059E+00 -0.0175 99 HSO4- 0.69754E-09 -9.1564 0.67009E-09 -9.1739 0.96065E+00 -0.0174 101 S2O3-2 0.36022E-16 -16.4434 0.32366E-16 -16.4899 0.89850E+00 -0.0465 Charge balance for all species = 0.1648E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3178650E-07 -.2795890E-04 -.2818034E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999782E+06 0.0000 3 Cl- 0.1379622E-03 0.1379747E-03 0.4891519E+01 3.6375 4 SO4-- 0.2534032E-04 0.2550251E-04 0.2449763E+01 10.3877 5 HCO3- 0.1224816E-04 0.1307005E-04 0.7974818E+00 2.5858 6 HS- 0.1334731E-08 0.2048545E-08 0.6774813E-04 -1.3769 7 Al+++ 0.2649510E-19 0.1548837E-05 0.4178913E-01 2.8737 8 H4SiO4 0.8641685E-04 0.8917610E-04 0.8571026E+01 -4.0634 9 Ca++ 0.2473804E-04 0.2497540E-04 0.1000944E+01 10.3772 10 Mg++ 0.7759629E-06 0.7858257E-06 0.1910461E-01 8.8736 11 Fe++ 0.5099603E-08 0.1069516E-07 0.5972805E-03 6.6913 12 K+ 0.1952577E-05 0.1953298E-05 0.7637633E-01 1.7883 13 Na+ 0.1716033E-03 0.1716199E-03 0.3945428E+01 3.7322 14 Mn++ 0.1197878E-06 0.1317988E-06 0.7240621E-02 8.0622 15 HPO4-- 0.5374620E-08 0.8206901E-08 0.7876745E-03 6.7142 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1392983E-03 -.2795880E-04 -.1113395E-03 0.0000000E+00 2 H2O 0.5550813E+02 0.5550807E+02 0.6338604E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2575943E-04 0.2550242E-04 0.2570119E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2549634E-06 0.2048538E-08 -.2570119E-06 0.0000000E+00 7 Al+++ 0.2999882E-04 0.1548832E-05 0.2844999E-04 0.0000000E+00 8 H4SiO4 0.9579760E-04 0.8917578E-04 0.6621822E-05 0.0000000E+00 9 Ca++ 0.2505237E-04 0.2497531E-04 0.7705806E-07 0.0000000E+00 10 Mg++ 0.7301587E-05 0.7858229E-06 0.6515764E-05 0.0000000E+00 11 Fe++ 0.6559679E-05 0.1069512E-07 0.6548984E-05 0.0000000E+00 12 K+ 0.1953291E-05 0.1953291E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1716192E-03 0.1716192E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1595151E-06 0.1317984E-06 0.2771671E-07 0.0000000E+00 15 HPO4-- 0.5444170E-07 0.8206872E-08 0.4623483E-07 0.0000000E+00 Chg. balance for solid moles: 0.3044E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0092000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1541E-07 -7.812 0.7742E-05 -5.111 0.2595 0.2460E-05 clinochlore 0.1303E-05 -5.885 0.7243E-03 -3.140 24.28 0.2755E-03 daphnite 0.8986E-06 -6.046 0.6411E-03 -3.193 21.49 0.1943E-03 chlorite-Mn 0.5543E-08 -8.256 0.3930E-05 -5.406 0.1317 0.1252E-05 diaspore 0.2404E-04 -4.619 0.1442E-02 -2.841 48.33 0.4293E-03 hematite 0.1028E-05 -5.988 0.1642E-03 -3.785 5.503 0.3112E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5904E+00 0.5904E+00 1.0000 -0.229 daphnite 0.4071E+00 0.4071E+00 1.0000 -0.390 chlorite-Mn 0.2511E-02 0.2511E-02 1.0000 -2.600 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002983 g Volume = 0.000934 cm3 Porosity: 99.9070% V(tot) - V(min): 0.10027E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0092000 g log = -2.0362 Original solution: 1000.0103000 g Original solution / Rock added: 108696.77 (Water/Rock Ratio), log = 5.0362 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.7993E-04 1.0071 0.8214E-04 0.8156E-04 CH4,gas 0.9169E-12 1.0125 0.9473E-12 0.9356E-12 H2,gas 0.3211E-05 1.0005 0.3278E-05 0.3277E-05 H2S,gas 0.3273E-08 0.9960 0.3326E-08 0.3340E-08 S2,gas 0.3787E-25 1.0000 0.3865E-25 0.3865E-25 CO,gas 0.7033E-13 1.0000 0.7176E-13 0.7176E-13 SO3,gas 0.7868E-35 1.0000 0.8028E-35 0.8028E-35 SO2,gas 0.1004E-17 1.0000 0.1024E-17 0.1024E-17 HCl,gas 0.1282E-14 1.0000 0.1309E-14 0.1309E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.44 -5.78 -1.928 0.98767E+04 -4.085 3 CH4,gas 4.54 -9.18 -13.72 -3.431 0.23431E+05 -12.024 4 H2,gas 8.00 0.82 -7.18 -4.105 0.12265E+05 -5.484 5 H2S,gas -6.23 -16.41 -10.18 -5.088 0.17377E+05 -8.478 6 S2,gas -7.34 -34.45 -27.11 -4.171 0.46293E+05 -25.413 7 CO,gas 3.21 -11.63 -14.84 -4.567 0.25344E+05 -13.144 8 SO3,gas 17.12 -19.67 -36.79 -9.199 0.62825E+05 -35.095 9 SO2,gas 0.83 -18.86 -19.69 -5.250 0.33618E+05 -17.990 10 HCl,gas 5.19 -11.39 -16.58 -8.291 0.28314E+05 -14.883 20 analcite 3.32 -1.52 -4.84 -0.538 0.82688E+04 21 andalusite 5.00 1.68 -3.32 -0.332 0.56646E+04 24 anhydrite -5.32 -9.30 -3.98 -1.990 0.67941E+04 29 anorthite 12.71 8.00 -4.71 -0.363 0.80466E+04 35 aragonite 0.97 -2.07 -3.03 -1.011 0.51803E+04 36 brucite 12.57 8.87 -3.69 -0.739 0.63090E+04 37 calcite 0.81 -2.07 -2.88 -0.960 0.49161E+04 40 carpholite-Mg 8.58 6.49 -2.09 -0.139 0.35650E+04 41 carpholite-Fe 6.71 4.31 -2.40 -0.160 0.40992E+04 50 chloritoid-Mg 13.20 10.56 -2.64 -0.176 0.45079E+04 51 chloritoid-Fe 9.17 8.38 -0.80 -0.053 0.13631E+04 52 chloritoid-Mn 11.40 9.75 -1.65 -0.110 0.28257E+04 54 coesite -2.38 -4.06 -1.69 -0.562 0.28811E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -4.06 -1.50 -0.501 0.25664E+04 75 epidote 24.67 20.59 -4.08 -0.198 0.69585E+04 78 fayalite 14.05 9.32 -4.73 -0.675 0.80704E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.95 -4.19 -0.349 0.71584E+04 92 hercynite 17.28 12.44 -4.84 -0.323 0.82639E+04 98 kaolinite -1.33 -2.38 -1.05 -0.095 0.17871E+04 99 kyanite 4.88 1.68 -3.19 -0.319 0.54505E+04 101 laumontite 2.88 -0.13 -3.01 -0.201 0.51437E+04 102 lawsonite 9.62 8.00 -1.62 -0.108 0.27632E+04 105 lizardite 23.24 18.49 -4.75 -0.396 0.81102E+04 106 magnesite 0.69 -3.57 -4.26 -1.421 0.72765E+04 107 magnetite 20.09 19.26 -0.83 -0.068 0.14170E+04 110 magnesioferrite 26.21 21.44 -4.77 -0.390 0.81491E+04 113 margarite 17.32 13.75 -3.58 -0.143 0.61101E+04 120 muscovite 2.58 -1.78 -4.36 -0.257 0.74501E+04 121 paragonite 4.24 0.16 -4.08 -0.240 0.69602E+04 128 periclase-Fe 11.63 6.69 -4.94 -1.234 0.84268E+04 137 prehnite-Fe 22.50 17.72 -4.78 -0.287 0.81565E+04 144 pyrrhotiteFe0.875 -6.02 -10.65 -4.64 -1.705 0.79169E+04 145 pyroxmangite 7.40 4.00 -3.40 -0.680 0.58052E+04 146 pyrophyllite -6.18 -10.51 -4.33 -0.271 0.73941E+04 147 quartz -2.99 -4.06 -1.07 -0.358 0.18338E+04 151 rhodochrosite -0.98 -4.38 -3.41 -1.135 0.58157E+04 152 rhodonite 7.45 4.00 -3.45 -0.689 0.58855E+04 155 siderite -2.61 -5.75 -3.15 -1.048 0.53702E+04 156 sillimanite 5.26 1.68 -3.58 -0.358 0.61085E+04 163 stilbite -7.52 -12.32 -4.80 -0.228 0.81911E+04 168 sudoite 21.08 17.05 -4.03 -0.130 0.68735E+04 177 topaz-H 4.62 1.68 -2.93 -0.267 0.50106E+04 178 tridymite -2.63 -4.06 -1.44 -0.479 0.24537E+04 187 wairakite 3.95 -0.13 -4.08 -0.240 0.69656E+04 189 wollastonite 10.46 6.31 -4.15 -0.829 0.70815E+04 190 pseudo-wollastonite 11.00 6.31 -4.69 -0.937 0.80014E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -6.50 -4.86 -0.301 0.82968E+04 196 beidellite-Mg -1.79 -6.75 -4.96 -0.307 0.84743E+04 199 chalcedony -2.80 -4.06 -1.26 -0.420 0.21531E+04 201 montmorillonite-Ca -2.29 -6.81 -4.52 -0.280 0.77234E+04 203 montmorillonite-Mg -2.48 -7.06 -4.58 -0.283 0.78240E+04 205 nontronite-Ca 3.21 0.31 -2.90 -0.188 0.49525E+04 206 nontronite-H 2.53 -1.40 -3.93 -0.263 0.67119E+04 207 nontronite-K 3.34 -0.81 -4.15 -0.266 0.70838E+04 208 nontronite-Mg 3.07 0.07 -3.01 -0.195 0.51372E+04 209 nontronite-Na 3.52 -0.17 -3.69 -0.237 0.62942E+04 214 gypsum -4.96 -9.30 -4.34 -1.085 0.74116E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.69 -3.12 -0.780 0.53278E+04 240 silica-amorphous -2.09 -4.06 -1.97 -0.657 0.33672E+04 242 an20ab80 2.02 -2.87 -4.89 -0.376 0.83421E+04 243 an25ab75 2.65 -2.19 -4.83 -0.372 0.82547E+04 244 an30ab70 3.28 -1.51 -4.79 -0.368 0.81769E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0092000 g New total amount of reactant added: 0.0096000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1648E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0096000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2734802E-03 Osmotic coef. = 0.9901 True ionic strength = .2776619E-03 Chg. balance for total moles = 0.1648E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.30311E-07 -7.5184 0.29118E-07 -7.5358 0.96065E+00 -0.0174 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13252E-03 -3.8777 0.96053E+00 -0.0175 4 SO4-- 0.25338E-04 -4.5962 0.22761E-04 -4.6428 0.89830E+00 -0.0466 5 HCO3- 0.12279E-04 -4.9108 0.11795E-04 -4.9283 0.96056E+00 -0.0175 6 HS- 0.96981E-09 -9.0133 0.93153E-09 -9.0308 0.96053E+00 -0.0175 7 Al+++ 0.22983E-19 -19.6386 0.18458E-19 -19.7338 0.80311E+00 -0.0952 8 H4SiO4 0.89964E-04 -4.0459 0.89964E-04 -4.0459 0.10000E+01 0.0000 9 Ca++ 0.25185E-04 -4.5989 0.22621E-04 -4.6455 0.89817E+00 -0.0466 10 Mg++ 0.69309E-06 -6.1592 0.62246E-06 -6.2059 0.89808E+00 -0.0467 11 Fe++ 0.44830E-08 -8.3484 0.40262E-08 -8.3951 0.89810E+00 -0.0467 12 K+ 0.20375E-05 -5.6909 0.19571E-05 -5.7084 0.96056E+00 -0.0175 13 Na+ 0.17210E-03 -3.7642 0.16531E-03 -3.7817 0.96052E+00 -0.0175 14 Mn++ 0.12063E-06 -6.9185 0.10834E-06 -6.9652 0.89812E+00 -0.0467 15 HPO4-- 0.48992E-08 -8.3099 0.44009E-08 -8.3565 0.89830E+00 -0.0466 16 HSiO3- 0.30035E-05 -5.5224 0.28849E-05 -5.5399 0.96053E+00 -0.0175 17 Ca(HSiO3)+ 0.15472E-08 -8.8105 0.14862E-08 -8.8279 0.96056E+00 -0.0175 18 Mg(HSiO3)+ 0.52985E-10 -10.2758 0.50895E-10 -10.2933 0.96056E+00 -0.0175 19 NaHSiO3,aq 0.77133E-08 -8.1128 0.77133E-08 -8.1128 0.10000E+01 0.0000 20 AlO+ 0.30832E-11 -11.5110 0.29617E-11 -11.5285 0.96056E+00 -0.0175 21 AlOH+2 0.47811E-15 -15.3205 0.42941E-15 -15.3671 0.89814E+00 -0.0467 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.16032E-05 -5.7950 0.15399E-05 -5.8125 0.96049E+00 -0.0175 24 CH4,aq 0.46895E-15 -15.3289 0.46891E-15 -15.3289 0.99992E+00 0.0000 29 CO,aq 0.43012E-16 -16.3664 0.43012E-16 -16.3664 0.10000E+01 0.0000 30 CO2,aq 0.73393E-06 -6.1343 0.73386E-06 -6.1344 0.99992E+00 0.0000 31 CO3-2 0.39389E-07 -7.4046 0.35382E-07 -7.4512 0.89826E+00 -0.0466 32 CaCO3,aq 0.10036E-07 -7.9985 0.10036E-07 -7.9985 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.70902E-08 -8.1493 0.68106E-08 -8.1668 0.96056E+00 -0.0175 34 CaCl+ 0.50502E-08 -8.2967 0.48511E-08 -8.3142 0.96056E+00 -0.0175 35 CaCl2,aq 0.15273E-12 -12.8161 0.15273E-12 -12.8161 0.10000E+01 0.0000 36 CaOH+ 0.57639E-07 -7.2393 0.55366E-07 -7.2568 0.96056E+00 -0.0175 37 CaSO4,aq 0.16350E-06 -6.7865 0.16350E-06 -6.7865 0.10000E+01 0.0000 38 HCl,aq 0.70707E-12 -12.1505 0.70707E-12 -12.1505 0.10000E+01 0.0000 43 FeCl+ 0.87917E-12 -12.0559 0.84450E-12 -12.0734 0.96056E+00 -0.0175 46 FeO,aq 0.18456E-09 -9.7339 0.18456E-09 -9.7339 0.10000E+01 0.0000 47 FeOH+ 0.46857E-08 -8.3292 0.45009E-08 -8.3467 0.96056E+00 -0.0175 48 HFeO2- 0.69044E-10 -10.1609 0.66319E-10 -10.1784 0.96053E+00 -0.0175 49 FeO+ 0.23138E-12 -12.6357 0.22225E-12 -12.6531 0.96056E+00 -0.0175 50 FeOH+2 0.13761E-17 -17.8614 0.12359E-17 -17.9080 0.89814E+00 -0.0467 51 FeO2- 0.55843E-10 -10.2530 0.53639E-10 -10.2705 0.96053E+00 -0.0175 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.23334E-08 -8.6320 0.23332E-08 -8.6321 0.99992E+00 0.0000 54 KCl,aq 0.47005E-11 -11.3279 0.47005E-11 -11.3279 0.10000E+01 0.0000 55 KHSO4,aq 0.36674E-17 -17.4356 0.36674E-17 -17.4356 0.10000E+01 0.0000 56 KOH,aq 0.28704E-10 -10.5421 0.28704E-10 -10.5421 0.10000E+01 0.0000 57 KSO4- 0.71965E-09 -9.1429 0.69125E-09 -9.1604 0.96053E+00 -0.0175 58 MgCO3,aq 0.69219E-10 -10.1598 0.69219E-10 -10.1598 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19936E-09 -9.7004 0.19150E-09 -9.7178 0.96056E+00 -0.0175 60 MgCl+ 0.12595E-09 -9.8998 0.12099E-09 -9.9173 0.96056E+00 -0.0175 61 MgOH+ 0.87766E-08 -8.0567 0.84305E-08 -8.0741 0.96056E+00 -0.0175 63 MnO,aq 0.13233E-09 -9.8783 0.13233E-09 -9.8783 0.10000E+01 0.0000 64 MnOH+ 0.11713E-07 -7.9313 0.11251E-07 -7.9488 0.96056E+00 -0.0175 65 MnO2-2 0.57664E-17 -17.2391 0.51797E-17 -17.2857 0.89826E+00 -0.0466 66 HMnO2- 0.34401E-13 -13.4634 0.33043E-13 -13.4809 0.96053E+00 -0.0175 69 MnCl+ 0.92038E-10 -10.0360 0.88408E-10 -10.0535 0.96056E+00 -0.0175 70 MnSO4,aq 0.71190E-09 -9.1476 0.71190E-09 -9.1476 0.10000E+01 0.0000 71 NaCl,aq 0.72598E-08 -8.1391 0.72598E-08 -8.1391 0.10000E+01 0.0000 72 NaOH,aq 0.24392E-08 -8.6127 0.24392E-08 -8.6127 0.10000E+01 0.0000 74 OH- 0.20659E-04 -4.6849 0.19842E-04 -4.7024 0.96049E+00 -0.0175 79 HPO3-2 0.35623E-19 -19.4483 0.31999E-19 -19.4949 0.89826E+00 -0.0466 82 H3PO4,aq 0.26097E-13 -13.5834 0.26097E-13 -13.5834 0.10000E+01 0.0000 83 H2PO4- 0.24611E-08 -8.6089 0.23640E-08 -8.6264 0.96054E+00 -0.0175 84 PO4-3 0.15339E-12 -12.8142 0.12332E-12 -12.9090 0.80393E+00 -0.0948 87 H2P2O7-2 0.48781E-18 -18.3118 0.43818E-18 -18.3583 0.89826E+00 -0.0466 88 HP2O7-3 0.37414E-17 -17.4270 0.30048E-17 -17.5222 0.80312E+00 -0.0952 89 P2O7-4 0.35882E-19 -19.4451 0.24653E-19 -19.6081 0.68704E+00 -0.1630 90 H2S,aq 0.83838E-10 -10.0766 0.83831E-10 -10.0766 0.99992E+00 0.0000 96 SO2,aq 0.20108E-18 -18.6966 0.20108E-18 -18.6966 0.10000E+01 0.0000 97 SO3-2 0.76803E-14 -14.1146 0.69010E-14 -14.1611 0.89853E+00 -0.0465 98 HSO3- 0.13099E-13 -13.8828 0.12582E-13 -13.9003 0.96053E+00 -0.0175 99 HSO4- 0.66492E-09 -9.1772 0.63871E-09 -9.1947 0.96058E+00 -0.0175 101 S2O3-2 0.24953E-16 -16.6029 0.22414E-16 -16.6495 0.89826E+00 -0.0466 Charge balance for all species = 0.1648E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3031085E-07 -.2951439E-04 -.2974813E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999778E+06 0.0000 3 Cl- 0.1379622E-03 0.1379747E-03 0.4891517E+01 3.6581 4 SO4-- 0.2533792E-04 0.2550296E-04 0.2449805E+01 10.4289 5 HCO3- 0.1227934E-04 0.1307005E-04 0.7974816E+00 2.6075 6 HS- 0.9698089E-09 0.1605151E-08 0.5308448E-04 -1.4950 7 Al+++ 0.2298291E-19 0.1623467E-05 0.4380268E-01 2.8737 8 H4SiO4 0.8996395E-04 0.9297674E-04 0.8936315E+01 -4.0459 9 Ca++ 0.2518525E-04 0.2543011E-04 0.1019167E+01 10.4262 10 Mg++ 0.6930940E-06 0.7023181E-06 0.1707441E-01 8.8658 11 Fe++ 0.4482981E-08 0.9677840E-08 0.5404674E-03 6.6766 12 K+ 0.2037471E-05 0.2038224E-05 0.7969702E-01 1.8275 13 Na+ 0.1721046E-03 0.1721220E-03 0.3956970E+01 3.7541 14 Mn++ 0.1206300E-06 0.1332792E-06 0.7321946E-02 8.1065 15 HPO4-- 0.4899160E-08 0.7360397E-08 0.7064292E-03 6.7152 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1459217E-03 -.2951428E-04 -.1164075E-03 0.0000000E+00 2 H2O 0.5550813E+02 0.5550806E+02 0.6617458E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2577052E-04 0.2550286E-04 0.2676539E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2660487E-06 0.1605145E-08 -.2676539E-06 0.0000000E+00 7 Al+++ 0.3130312E-04 0.1623461E-05 0.2967966E-04 0.0000000E+00 8 H4SiO4 0.9996272E-04 0.9297639E-04 0.6986327E-05 0.0000000E+00 9 Ca++ 0.2551243E-04 0.2543002E-04 0.8241394E-07 0.0000000E+00 10 Mg++ 0.7619048E-05 0.7023155E-06 0.6916732E-05 0.0000000E+00 11 Fe++ 0.6844882E-05 0.9677804E-08 0.6835205E-05 0.0000000E+00 12 K+ 0.2038217E-05 0.2038217E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1721213E-03 0.1721213E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1664505E-06 0.1332787E-06 0.3317177E-07 0.0000000E+00 15 HPO4-- 0.5680874E-07 0.7360369E-08 0.4944837E-07 0.0000000E+00 Chg. balance for solid moles: -.1073E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0096000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1648E-07 -7.783 0.8280E-05 -5.082 0.2651 0.2631E-05 clinochlore 0.1383E-05 -5.859 0.7689E-03 -3.114 24.61 0.2925E-03 daphnite 0.9388E-06 -6.027 0.6698E-03 -3.174 21.44 0.2030E-03 chlorite-Mn 0.6634E-08 -8.178 0.4704E-05 -5.328 0.1506 0.1499E-05 diaspore 0.2502E-04 -4.602 0.1501E-02 -2.824 48.05 0.4469E-03 hematite 0.1071E-05 -5.970 0.1710E-03 -3.767 5.473 0.3241E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5940E+00 0.5940E+00 1.0000 -0.226 daphnite 0.4031E+00 0.4031E+00 1.0000 -0.395 chlorite-Mn 0.2849E-02 0.2849E-02 1.0000 -2.545 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003124 g Volume = 0.000979 cm3 Porosity: 99.9025% V(tot) - V(min): 0.10029E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0096000 g log = -2.0177 Original solution: 1000.0103000 g Original solution / Rock added: 104167.74 (Water/Rock Ratio), log = 5.0177 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.7641E-04 1.0071 0.7852E-04 0.7796E-04 CH4,gas 0.6681E-12 1.0125 0.6902E-12 0.6817E-12 H2,gas 0.3000E-05 1.0005 0.3063E-05 0.3061E-05 H2S,gas 0.2267E-08 0.9960 0.2304E-08 0.2314E-08 S2,gas 0.2082E-25 1.0000 0.2124E-25 0.2124E-25 CO,gas 0.6282E-13 1.0000 0.6410E-13 0.6410E-13 SO3,gas 0.7151E-35 1.0000 0.7297E-35 0.7297E-35 SO2,gas 0.8522E-18 1.0000 0.8696E-18 0.8696E-18 HCl,gas 0.1223E-14 1.0000 0.1248E-14 0.1248E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.60662E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.46 -5.80 -1.935 0.99102E+04 -4.105 3 CH4,gas 4.54 -9.32 -13.86 -3.465 0.23666E+05 -12.161 4 H2,gas 8.00 0.79 -7.21 -4.122 0.12316E+05 -5.514 5 H2S,gas -6.23 -16.57 -10.34 -5.168 0.17649E+05 -8.637 6 S2,gas -7.34 -34.71 -27.37 -4.211 0.46736E+05 -25.673 7 CO,gas 3.21 -11.68 -14.89 -4.582 0.25428E+05 -13.193 8 SO3,gas 17.12 -19.71 -36.84 -9.209 0.62896E+05 -35.137 9 SO2,gas 0.83 -18.93 -19.76 -5.269 0.33739E+05 -18.061 10 HCl,gas 5.19 -11.41 -16.60 -8.301 0.28349E+05 -14.904 20 analcite 3.32 -1.46 -4.79 -0.532 0.81718E+04 21 andalusite 5.00 1.70 -3.30 -0.330 0.56348E+04 24 anhydrite -5.32 -9.29 -3.97 -1.986 0.67812E+04 29 anorthite 12.71 8.08 -4.63 -0.356 0.79032E+04 35 aragonite 0.97 -2.04 -3.00 -1.001 0.51301E+04 36 brucite 12.57 8.87 -3.70 -0.741 0.63224E+04 37 calcite 0.81 -2.04 -2.85 -0.950 0.48658E+04 40 carpholite-Mg 8.58 6.52 -2.06 -0.137 0.35187E+04 41 carpholite-Fe 6.71 4.33 -2.38 -0.159 0.40647E+04 50 chloritoid-Mg 13.20 10.57 -2.63 -0.175 0.44914E+04 51 chloritoid-Fe 9.17 8.38 -0.80 -0.053 0.13584E+04 52 chloritoid-Mn 11.40 9.81 -1.59 -0.106 0.27202E+04 54 coesite -2.38 -4.05 -1.67 -0.557 0.28513E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -4.05 -1.49 -0.495 0.25366E+04 67 diopside 16.18 11.20 -4.98 -0.498 0.85054E+04 75 epidote 24.67 20.75 -3.92 -0.190 0.67016E+04 78 fayalite 14.05 9.31 -4.74 -0.677 0.80909E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.94 -4.20 -0.350 0.71742E+04 92 hercynite 17.28 12.42 -4.85 -0.324 0.82891E+04 98 kaolinite -1.33 -2.34 -1.01 -0.092 0.17275E+04 99 kyanite 4.88 1.70 -3.17 -0.317 0.54207E+04 101 laumontite 2.88 -0.01 -2.89 -0.193 0.49407E+04 102 lawsonite 9.62 8.08 -1.53 -0.102 0.26199E+04 105 lizardite 23.24 18.51 -4.74 -0.395 0.80906E+04 106 magnesite 0.69 -3.60 -4.29 -1.430 0.73233E+04 107 magnetite 20.09 19.24 -0.84 -0.069 0.14422E+04 110 magnesioferrite 26.21 21.43 -4.78 -0.390 0.81624E+04 113 margarite 17.32 13.83 -3.49 -0.140 0.59668E+04 116 microcline -2.49 -7.44 -4.95 -0.381 0.84522E+04 120 muscovite 2.58 -1.69 -4.27 -0.251 0.72938E+04 121 paragonite 4.24 0.24 -4.00 -0.235 0.68333E+04 128 periclase-Fe 11.63 6.68 -4.95 -1.238 0.84520E+04 136 prehnite 19.37 14.46 -4.91 -0.289 0.83836E+04 137 prehnite-Fe 22.50 17.87 -4.63 -0.278 0.78996E+04 144 pyrrhotiteFe0.875 -6.02 -10.82 -4.81 -1.767 0.82049E+04 145 pyroxmangite 7.40 4.06 -3.34 -0.668 0.56998E+04 146 pyrophyllite -6.18 -10.44 -4.26 -0.266 0.72747E+04 147 quartz -2.99 -4.05 -1.06 -0.352 0.18039E+04 151 rhodochrosite -0.98 -4.36 -3.38 -1.127 0.57736E+04 152 rhodonite 7.45 4.06 -3.39 -0.677 0.57800E+04 155 siderite -2.61 -5.79 -3.18 -1.060 0.54288E+04 156 sillimanite 5.26 1.70 -3.56 -0.356 0.60787E+04 163 stilbite -7.52 -12.15 -4.63 -0.220 0.78986E+04 168 sudoite 21.08 17.09 -3.99 -0.129 0.68107E+04 177 topaz-H 4.62 1.70 -2.92 -0.265 0.49807E+04 178 tridymite -2.63 -4.05 -1.42 -0.473 0.24239E+04 187 wairakite 3.95 -0.01 -3.96 -0.233 0.67626E+04 189 wollastonite 10.46 6.38 -4.08 -0.816 0.69680E+04 190 pseudo-wollastonite 11.00 6.38 -4.62 -0.924 0.78878E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -6.43 -4.79 -0.296 0.81736E+04 196 beidellite-Mg -1.79 -6.69 -4.90 -0.303 0.83670E+04 199 chalcedony -2.80 -4.05 -1.24 -0.414 0.21232E+04 201 montmorillonite-Ca -2.29 -6.74 -4.45 -0.275 0.75947E+04 203 montmorillonite-Mg -2.48 -7.00 -4.52 -0.279 0.77113E+04 205 nontronite-Ca 3.21 0.39 -2.83 -0.183 0.48292E+04 206 nontronite-H 2.53 -1.33 -3.87 -0.259 0.66024E+04 207 nontronite-K 3.34 -0.73 -4.07 -0.261 0.69523E+04 208 nontronite-Mg 3.07 0.13 -2.95 -0.191 0.50299E+04 209 nontronite-Na 3.52 -0.10 -3.61 -0.232 0.61723E+04 214 gypsum -4.96 -9.29 -4.33 -1.083 0.73988E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.68 -3.14 -0.784 0.53529E+04 240 silica-amorphous -2.09 -4.05 -1.95 -0.652 0.33374E+04 242 an20ab80 2.02 -2.79 -4.81 -0.370 0.82119E+04 243 an25ab75 2.65 -2.11 -4.76 -0.366 0.81237E+04 244 an30ab70 3.28 -1.43 -4.71 -0.362 0.80451E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0096000 g New total amount of reactant added: 0.0100000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0100000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2748768E-03 Osmotic coef. = 0.9900 True ionic strength = .2793745E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.28953E-07 -7.5383 0.27811E-07 -7.5558 0.96058E+00 -0.0175 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13251E-03 -3.8778 0.96046E+00 -0.0175 4 SO4-- 0.25335E-04 -4.5963 0.22753E-04 -4.6430 0.89806E+00 -0.0467 5 HCO3- 0.12308E-04 -4.9098 0.11822E-04 -4.9273 0.96049E+00 -0.0175 6 HS- 0.72038E-09 -9.1424 0.69190E-09 -9.1600 0.96046E+00 -0.0175 7 Al+++ 0.20038E-19 -19.6981 0.16083E-19 -19.7936 0.80262E+00 -0.0955 8 H4SiO4 0.93505E-04 -4.0292 0.93505E-04 -4.0292 0.10000E+01 0.0000 9 Ca++ 0.25633E-04 -4.5912 0.23016E-04 -4.6380 0.89793E+00 -0.0468 10 Mg++ 0.62104E-06 -6.2069 0.55759E-06 -6.2537 0.89784E+00 -0.0468 11 Fe++ 0.39644E-08 -8.4018 0.35595E-08 -8.4486 0.89786E+00 -0.0468 12 K+ 0.21224E-05 -5.6732 0.20385E-05 -5.6907 0.96050E+00 -0.0175 13 Na+ 0.17261E-03 -3.7629 0.16578E-03 -3.7805 0.96046E+00 -0.0175 14 Mn++ 0.12094E-06 -6.9174 0.10859E-06 -6.9642 0.89788E+00 -0.0468 15 HPO4-- 0.44782E-08 -8.3489 0.40217E-08 -8.3956 0.89806E+00 -0.0467 16 HSiO3- 0.32686E-05 -5.4856 0.31394E-05 -5.5032 0.96046E+00 -0.0175 17 Ca(HSiO3)+ 0.17132E-08 -8.7662 0.16455E-08 -8.7837 0.96050E+00 -0.0175 18 Mg(HSiO3)+ 0.51653E-10 -10.2869 0.49613E-10 -10.3044 0.96050E+00 -0.0175 19 NaHSiO3,aq 0.84175E-08 -8.0748 0.84175E-08 -8.0748 0.10000E+01 0.0000 20 AlO+ 0.29451E-11 -11.5309 0.28288E-11 -11.5484 0.96050E+00 -0.0175 21 AlOH+2 0.43628E-15 -15.3602 0.39174E-15 -15.4070 0.89790E+00 -0.0468 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.16786E-05 -5.7750 0.16122E-05 -5.7926 0.96043E+00 -0.0175 24 CH4,aq 0.34923E-15 -15.4569 0.34920E-15 -15.4569 0.99991E+00 0.0000 29 CO,aq 0.38670E-16 -16.4126 0.38670E-16 -16.4126 0.10000E+01 0.0000 30 CO2,aq 0.70258E-06 -6.1533 0.70252E-06 -6.1533 0.99991E+00 0.0000 31 CO3-2 0.41344E-07 -7.3836 0.37128E-07 -7.4303 0.89802E+00 -0.0467 32 CaCO3,aq 0.10715E-07 -7.9700 0.10715E-07 -7.9700 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.72310E-08 -8.1408 0.69453E-08 -8.1583 0.96050E+00 -0.0175 34 CaCl+ 0.51385E-08 -8.2892 0.49355E-08 -8.3067 0.96050E+00 -0.0175 35 CaCl2,aq 0.15538E-12 -12.8086 0.15538E-12 -12.8086 0.10000E+01 0.0000 36 CaOH+ 0.61407E-07 -7.2118 0.58981E-07 -7.2293 0.96050E+00 -0.0175 37 CaSO4,aq 0.16629E-06 -6.7791 0.16629E-06 -6.7791 0.10000E+01 0.0000 38 HCl,aq 0.67530E-12 -12.1705 0.67530E-12 -12.1705 0.10000E+01 0.0000 43 FeCl+ 0.77725E-12 -12.1094 0.74655E-12 -12.1269 0.96050E+00 -0.0175 46 FeO,aq 0.17886E-09 -9.7475 0.17886E-09 -9.7475 0.10000E+01 0.0000 47 FeOH+ 0.43374E-08 -8.3628 0.41661E-08 -8.3803 0.96050E+00 -0.0175 48 HFeO2- 0.70059E-10 -10.1545 0.67289E-10 -10.1721 0.96046E+00 -0.0175 49 FeO+ 0.22101E-12 -12.6556 0.21228E-12 -12.6731 0.96050E+00 -0.0175 50 FeOH+2 0.12557E-17 -17.9011 0.11275E-17 -17.9479 0.89790E+00 -0.0468 51 FeO2- 0.58470E-10 -10.2331 0.56159E-10 -10.2506 0.96046E+00 -0.0175 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.21914E-08 -8.6593 0.21912E-08 -8.6593 0.99991E+00 0.0000 54 KCl,aq 0.48957E-11 -11.3102 0.48957E-11 -11.3102 0.10000E+01 0.0000 55 KHSO4,aq 0.36472E-17 -17.4380 0.36472E-17 -17.4380 0.10000E+01 0.0000 56 KOH,aq 0.31302E-10 -10.5044 0.31302E-10 -10.5044 0.10000E+01 0.0000 57 KSO4- 0.74936E-09 -9.1253 0.71974E-09 -9.1428 0.96046E+00 -0.0175 58 MgCO3,aq 0.65066E-10 -10.1866 0.65066E-10 -10.1866 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17900E-09 -9.7471 0.17193E-09 -9.7646 0.96050E+00 -0.0175 60 MgCl+ 0.11283E-09 -9.9476 0.10837E-09 -9.9651 0.96050E+00 -0.0175 61 MgOH+ 0.82319E-08 -8.0845 0.79068E-08 -8.1020 0.96050E+00 -0.0175 63 MnO,aq 0.14539E-09 -9.8375 0.14539E-09 -9.8375 0.10000E+01 0.0000 64 MnOH+ 0.12292E-07 -7.9104 0.11806E-07 -7.9279 0.96050E+00 -0.0175 65 MnO2-2 0.69464E-17 -17.1582 0.62380E-17 -17.2050 0.89802E+00 -0.0467 66 HMnO2- 0.39573E-13 -13.4026 0.38008E-13 -13.4201 0.96046E+00 -0.0175 69 MnCl+ 0.92247E-10 -10.0350 0.88603E-10 -10.0526 0.96050E+00 -0.0175 70 MnSO4,aq 0.71325E-09 -9.1468 0.71325E-09 -9.1468 0.10000E+01 0.0000 71 NaCl,aq 0.72800E-08 -8.1379 0.72800E-08 -8.1379 0.10000E+01 0.0000 72 NaOH,aq 0.25611E-08 -8.5916 0.25611E-08 -8.5916 0.10000E+01 0.0000 74 OH- 0.21631E-04 -4.6649 0.20775E-04 -4.6825 0.96043E+00 -0.0175 79 HPO3-2 0.30581E-19 -19.5145 0.27462E-19 -19.5613 0.89802E+00 -0.0467 82 H3PO4,aq 0.21756E-13 -13.6624 0.21756E-13 -13.6624 0.10000E+01 0.0000 83 H2PO4- 0.21482E-08 -8.6679 0.20633E-08 -8.6854 0.96048E+00 -0.0175 84 PO4-3 0.14685E-12 -12.8331 0.11798E-12 -12.9282 0.80345E+00 -0.0950 87 H2P2O7-2 0.37172E-18 -18.4298 0.33382E-18 -18.4765 0.89802E+00 -0.0467 88 HP2O7-3 0.29860E-17 -17.5249 0.23967E-17 -17.6204 0.80263E+00 -0.0955 89 P2O7-4 0.29997E-19 -19.5229 0.20587E-19 -19.6864 0.68630E+00 -0.1635 90 H2S,aq 0.59477E-10 -10.2256 0.59472E-10 -10.2257 0.99991E+00 0.0000 96 SO2,aq 0.17222E-18 -18.7639 0.17222E-18 -18.7639 0.10000E+01 0.0000 97 SO3-2 0.72122E-14 -14.1419 0.64787E-14 -14.1885 0.89829E+00 -0.0466 98 HSO3- 0.11746E-13 -13.9301 0.11282E-13 -13.9476 0.96046E+00 -0.0175 99 HSO4- 0.63489E-09 -9.1973 0.60983E-09 -9.2148 0.96052E+00 -0.0175 101 S2O3-2 0.17700E-16 -16.7520 0.15895E-16 -16.7987 0.89802E+00 -0.0467 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2895262E-07 -.3109344E-04 -.3133968E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999774E+06 0.0000 3 Cl- 0.1379621E-03 0.1379747E-03 0.4891516E+01 3.6780 4 SO4-- 0.2533540E-04 0.2550327E-04 0.2449834E+01 10.4686 5 HCO3- 0.1230794E-04 0.1307005E-04 0.7974814E+00 2.6285 6 HS- 0.7203838E-09 0.1295544E-08 0.4284534E-04 -1.6042 7 Al+++ 0.2003780E-19 0.1698902E-05 0.4583798E-01 2.8737 8 H4SiO4 0.9350550E-04 0.9678428E-04 0.9302267E+01 -4.0292 9 Ca++ 0.2563251E-04 0.2588501E-04 0.1037398E+01 10.4736 10 Mg++ 0.6210381E-06 0.6296786E-06 0.1530843E-01 8.8579 11 Fe++ 0.3964368E-08 0.8808791E-08 0.4919344E-03 6.6629 12 K+ 0.2122365E-05 0.2123150E-05 0.8301771E-01 1.8651 13 Na+ 0.1726058E-03 0.1726241E-03 0.3968511E+01 3.7753 14 Mn++ 0.1209360E-06 0.1341788E-06 0.7371362E-02 8.1473 15 HPO4-- 0.4478225E-08 0.6626618E-08 0.6360030E-03 6.7160 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1525452E-03 -.3109332E-04 -.1214518E-03 0.0000000E+00 2 H2O 0.5550812E+02 0.5550806E+02 0.6895795E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2578160E-04 0.2550317E-04 0.2784296E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2771341E-06 0.1295539E-08 -.2784296E-06 0.0000000E+00 7 Al+++ 0.3260742E-04 0.1698896E-05 0.3090852E-04 0.0000000E+00 8 H4SiO4 0.1041278E-03 0.9678390E-04 0.7343928E-05 0.0000000E+00 9 Ca++ 0.2597249E-04 0.2588490E-04 0.8758196E-07 0.0000000E+00 10 Mg++ 0.7936508E-05 0.6296761E-06 0.7306832E-05 0.0000000E+00 11 Fe++ 0.7130086E-05 0.8808757E-08 0.7121277E-05 0.0000000E+00 12 K+ 0.2123142E-05 0.2123142E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1726234E-03 0.1726234E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1733860E-06 0.1341783E-06 0.3920768E-07 0.0000000E+00 15 HPO4-- 0.5917577E-07 0.6626593E-08 0.5254917E-07 0.0000000E+00 Chg. balance for solid moles: -.2647E-22 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0100000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1752E-07 -7.757 0.8799E-05 -5.056 0.2696 0.2796E-05 clinochlore 0.1461E-05 -5.835 0.8123E-03 -3.090 24.89 0.3090E-03 daphnite 0.9788E-06 -6.009 0.6984E-03 -3.156 21.40 0.2116E-03 chlorite-Mn 0.7842E-08 -8.106 0.5559E-05 -5.255 0.1704 0.1772E-05 diaspore 0.2601E-04 -4.585 0.1560E-02 -2.807 47.82 0.4646E-03 hematite 0.1114E-05 -5.953 0.1779E-03 -3.750 5.450 0.3371E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5970E+00 0.5970E+00 1.0000 -0.224 daphnite 0.3998E+00 0.3998E+00 1.0000 -0.398 chlorite-Mn 0.3203E-02 0.3203E-02 1.0000 -2.494 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003263 g Volume = 0.001023 cm3 Porosity: 99.8981% V(tot) - V(min): 0.10030E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0100000 g log = -2.0000 Original solution: 1000.0103000 g Original solution / Rock added: 100001.03 (Water/Rock Ratio), log = 5.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.7314E-04 1.0071 0.7516E-04 0.7463E-04 CH4,gas 0.4975E-12 1.0125 0.5140E-12 0.5076E-12 H2,gas 0.2818E-05 1.0005 0.2877E-05 0.2875E-05 H2S,gas 0.1609E-08 0.9960 0.1635E-08 0.1641E-08 S2,gas 0.1188E-25 1.0000 0.1212E-25 0.1212E-25 CO,gas 0.5647E-13 1.0000 0.5763E-13 0.5763E-13 SO3,gas 0.6521E-35 1.0000 0.6654E-35 0.6654E-35 SO2,gas 0.7299E-18 1.0000 0.7447E-18 0.7447E-18 HCl,gas 0.1168E-14 1.0000 0.1192E-14 0.1192E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.48 -5.82 -1.941 0.99426E+04 -4.124 3 CH4,gas 4.54 -9.44 -13.99 -3.497 0.23884E+05 -12.289 4 H2,gas 8.00 0.76 -7.24 -4.137 0.12362E+05 -5.541 5 H2S,gas -6.23 -16.72 -10.49 -5.243 0.17904E+05 -8.787 6 S2,gas -7.34 -34.95 -27.62 -4.249 0.47153E+05 -25.916 7 CO,gas 3.21 -11.72 -14.94 -4.596 0.25507E+05 -13.239 8 SO3,gas 17.12 -19.75 -36.88 -9.219 0.62965E+05 -35.177 9 SO2,gas 0.83 -18.99 -19.83 -5.287 0.33854E+05 -18.128 10 HCl,gas 5.19 -11.43 -16.62 -8.311 0.28383E+05 -14.924 20 analcite 3.32 -1.41 -4.73 -0.526 0.80784E+04 21 andalusite 5.00 1.72 -3.28 -0.328 0.56061E+04 24 anhydrite -5.32 -9.28 -3.96 -1.982 0.67686E+04 29 anorthite 12.71 8.16 -4.55 -0.350 0.77650E+04 35 aragonite 0.97 -2.01 -2.98 -0.992 0.50815E+04 36 brucite 12.57 8.86 -3.71 -0.742 0.63359E+04 37 calcite 0.81 -2.01 -2.82 -0.940 0.48173E+04 40 carpholite-Mg 8.58 6.55 -2.04 -0.136 0.34750E+04 41 carpholite-Fe 6.71 4.35 -2.36 -0.157 0.40307E+04 50 chloritoid-Mg 13.20 10.58 -2.62 -0.175 0.44763E+04 51 chloritoid-Fe 9.17 8.38 -0.79 -0.053 0.13531E+04 52 chloritoid-Mn 11.40 9.87 -1.54 -0.102 0.26218E+04 54 coesite -2.38 -4.03 -1.65 -0.551 0.28226E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -4.03 -1.47 -0.490 0.25080E+04 67 diopside 16.18 11.27 -4.91 -0.491 0.83807E+04 75 epidote 24.67 20.89 -3.78 -0.183 0.64538E+04 78 fayalite 14.05 9.30 -4.75 -0.678 0.81088E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.93 -4.21 -0.351 0.71868E+04 92 hercynite 17.28 12.41 -4.87 -0.325 0.83123E+04 98 kaolinite -1.33 -2.31 -0.98 -0.089 0.16702E+04 99 kyanite 4.88 1.72 -3.16 -0.316 0.53920E+04 101 laumontite 2.88 0.10 -2.78 -0.185 0.47452E+04 102 lawsonite 9.62 8.16 -1.45 -0.097 0.24817E+04 105 lizardite 23.24 18.52 -4.73 -0.394 0.80739E+04 106 magnesite 0.69 -3.63 -4.32 -1.439 0.73692E+04 107 magnetite 20.09 19.23 -0.86 -0.070 0.14655E+04 110 magnesioferrite 26.21 21.42 -4.79 -0.391 0.81760E+04 113 margarite 17.32 13.91 -3.41 -0.137 0.58286E+04 116 microcline -2.49 -7.35 -4.86 -0.374 0.83021E+04 120 muscovite 2.58 -1.60 -4.18 -0.246 0.71436E+04 121 paragonite 4.24 0.31 -3.93 -0.231 0.67112E+04 128 periclase-Fe 11.63 6.66 -4.96 -1.241 0.84753E+04 136 prehnite 19.37 14.61 -4.76 -0.280 0.81358E+04 137 prehnite-Fe 22.50 18.02 -4.48 -0.270 0.76518E+04 144 pyrrhotiteFe0.875 -6.02 -10.98 -4.96 -1.825 0.84740E+04 145 pyroxmangite 7.40 4.12 -3.28 -0.656 0.56014E+04 146 pyrophyllite -6.18 -10.37 -4.19 -0.262 0.71602E+04 147 quartz -2.99 -4.03 -1.04 -0.347 0.17753E+04 151 rhodochrosite -0.98 -4.34 -3.36 -1.120 0.57362E+04 152 rhodonite 7.45 4.12 -3.33 -0.666 0.56816E+04 155 siderite -2.61 -5.82 -3.21 -1.071 0.54844E+04 156 sillimanite 5.26 1.72 -3.54 -0.354 0.60501E+04 163 stilbite -7.52 -11.98 -4.46 -0.212 0.76172E+04 168 sudoite 21.08 17.12 -3.95 -0.128 0.67519E+04 177 topaz-H 4.62 1.72 -2.90 -0.264 0.49521E+04 178 tridymite -2.63 -4.03 -1.40 -0.468 0.23953E+04 187 wairakite 3.95 0.10 -3.85 -0.226 0.65672E+04 189 wollastonite 10.46 6.44 -4.02 -0.803 0.68584E+04 190 pseudo-wollastonite 11.00 6.44 -4.56 -0.911 0.77783E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -6.36 -4.72 -0.292 0.80551E+04 196 beidellite-Mg -1.79 -6.63 -4.84 -0.299 0.82641E+04 199 chalcedony -2.80 -4.03 -1.23 -0.409 0.20946E+04 201 montmorillonite-Ca -2.29 -6.67 -4.38 -0.271 0.74712E+04 203 montmorillonite-Mg -2.48 -6.93 -4.45 -0.275 0.76035E+04 205 nontronite-Ca 3.21 0.46 -2.76 -0.179 0.47108E+04 206 nontronite-H 2.53 -1.27 -3.81 -0.255 0.64973E+04 207 nontronite-K 3.34 -0.66 -4.00 -0.257 0.68260E+04 208 nontronite-Mg 3.07 0.19 -2.89 -0.187 0.49271E+04 209 nontronite-Na 3.52 -0.03 -3.55 -0.228 0.60553E+04 214 gypsum -4.96 -9.28 -4.33 -1.081 0.73862E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.66 -3.15 -0.787 0.53762E+04 240 silica-amorphous -2.09 -4.03 -1.94 -0.646 0.33088E+04 242 an20ab80 2.02 -2.72 -4.74 -0.364 0.80866E+04 243 an25ab75 2.65 -2.04 -4.68 -0.360 0.79976E+04 244 an30ab70 3.28 -1.36 -4.64 -0.357 0.79182E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0100000 g New total amount of reactant added: 0.0104000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0104000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2762943E-03 Osmotic coef. = 0.9900 True ionic strength = .2811141E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.27702E-07 -7.5575 0.26608E-07 -7.5750 0.96052E+00 -0.0175 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13250E-03 -3.8778 0.96040E+00 -0.0175 4 SO4-- 0.25333E-04 -4.5963 0.22744E-04 -4.6431 0.89782E+00 -0.0468 5 HCO3- 0.12334E-04 -4.9089 0.11846E-04 -4.9264 0.96042E+00 -0.0175 6 HS- 0.54551E-09 -9.2632 0.52391E-09 -9.2807 0.96040E+00 -0.0175 7 Al+++ 0.17559E-19 -19.7555 0.14084E-19 -19.8513 0.80213E+00 -0.0958 8 H4SiO4 0.97041E-04 -4.0130 0.97041E-04 -4.0130 0.10000E+01 0.0000 9 Ca++ 0.26080E-04 -4.5837 0.23411E-04 -4.6306 0.89768E+00 -0.0469 10 Mg++ 0.55832E-06 -6.2531 0.50115E-06 -6.3000 0.89760E+00 -0.0469 11 Fe++ 0.35253E-08 -8.4528 0.31644E-08 -8.4997 0.89762E+00 -0.0469 12 K+ 0.22073E-05 -5.6561 0.21199E-05 -5.6737 0.96043E+00 -0.0175 13 Na+ 0.17311E-03 -3.7617 0.16625E-03 -3.7792 0.96039E+00 -0.0176 14 Mn++ 0.12073E-06 -6.9182 0.10837E-06 -6.9651 0.89763E+00 -0.0469 15 HPO4-- 0.41048E-08 -8.3867 0.36853E-08 -8.4335 0.89782E+00 -0.0468 16 HSiO3- 0.35458E-05 -5.4503 0.34054E-05 -5.4678 0.96040E+00 -0.0175 17 Ca(HSiO3)+ 0.18904E-08 -8.7234 0.18156E-08 -8.7410 0.96043E+00 -0.0175 18 Mg(HSiO3)+ 0.50362E-10 -10.2979 0.48369E-10 -10.3154 0.96043E+00 -0.0175 19 NaHSiO3,aq 0.91567E-08 -8.0383 0.91567E-08 -8.0383 0.10000E+01 0.0000 20 AlO+ 0.28179E-11 -11.5501 0.27064E-11 -11.5676 0.96043E+00 -0.0175 21 AlOH+2 0.39946E-15 -15.3985 0.35857E-15 -15.4454 0.89765E+00 -0.0469 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.17547E-05 -5.7558 0.16851E-05 -5.7734 0.96036E+00 -0.0176 24 CH4,aq 0.26508E-15 -15.5766 0.26506E-15 -15.5767 0.99991E+00 0.0000 29 CO,aq 0.34971E-16 -16.4563 0.34971E-16 -16.4563 0.10000E+01 0.0000 30 CO2,aq 0.67357E-06 -6.1716 0.67351E-06 -6.1717 0.99991E+00 0.0000 31 CO3-2 0.43315E-07 -7.3634 0.38887E-07 -7.4102 0.89778E+00 -0.0468 32 CaCO3,aq 0.11415E-07 -7.9425 0.11415E-07 -7.9425 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.73708E-08 -8.1325 0.70792E-08 -8.1500 0.96043E+00 -0.0175 34 CaCl+ 0.52267E-08 -8.2818 0.50199E-08 -8.2993 0.96043E+00 -0.0175 35 CaCl2,aq 0.15802E-12 -12.8013 0.15802E-12 -12.8013 0.10000E+01 0.0000 36 CaOH+ 0.65290E-07 -7.1852 0.62707E-07 -7.2027 0.96043E+00 -0.0175 37 CaSO4,aq 0.16909E-06 -6.7719 0.16909E-06 -6.7719 0.10000E+01 0.0000 38 HCl,aq 0.64604E-12 -12.1897 0.64604E-12 -12.1897 0.10000E+01 0.0000 43 FeCl+ 0.69098E-12 -12.1605 0.66364E-12 -12.1781 0.96043E+00 -0.0175 46 FeO,aq 0.17371E-09 -9.7602 0.17371E-09 -9.7602 0.10000E+01 0.0000 47 FeOH+ 0.40306E-08 -8.3946 0.38712E-08 -8.4122 0.96043E+00 -0.0175 48 HFeO2- 0.71125E-10 -10.1480 0.68308E-10 -10.1655 0.96040E+00 -0.0175 49 FeO+ 0.21146E-12 -12.6748 0.20310E-12 -12.6923 0.96043E+00 -0.0175 50 FeOH+2 0.11497E-17 -17.9394 0.10320E-17 -17.9863 0.89765E+00 -0.0469 51 FeO2- 0.61119E-10 -10.2138 0.58698E-10 -10.2314 0.96040E+00 -0.0175 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.20671E-08 -8.6846 0.20669E-08 -8.6847 0.99991E+00 0.0000 54 KCl,aq 0.50908E-11 -11.2932 0.50908E-11 -11.2932 0.10000E+01 0.0000 55 KHSO4,aq 0.36273E-17 -17.4404 0.36273E-17 -17.4404 0.10000E+01 0.0000 56 KOH,aq 0.34024E-10 -10.4682 0.34024E-10 -10.4682 0.10000E+01 0.0000 57 KSO4- 0.77905E-09 -9.1084 0.74819E-09 -9.1260 0.96040E+00 -0.0175 58 MgCO3,aq 0.61250E-10 -10.2129 0.61250E-10 -10.2129 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16122E-09 -9.7926 0.15484E-09 -9.8101 0.96043E+00 -0.0175 60 MgCl+ 0.10141E-09 -9.9939 0.97394E-10 -10.0115 0.96043E+00 -0.0175 61 MgOH+ 0.77337E-08 -8.1116 0.74277E-08 -8.1291 0.96043E+00 -0.0175 63 MnO,aq 0.15852E-09 -9.7999 0.15852E-09 -9.7999 0.10000E+01 0.0000 64 MnOH+ 0.12823E-07 -7.8920 0.12316E-07 -7.9095 0.96043E+00 -0.0175 65 MnO2-2 0.82767E-17 -17.0821 0.74306E-17 -17.1290 0.89778E+00 -0.0468 66 HMnO2- 0.45102E-13 -13.3458 0.43316E-13 -13.3634 0.96040E+00 -0.0175 69 MnCl+ 0.92065E-10 -10.0359 0.88422E-10 -10.0534 0.96043E+00 -0.0175 70 MnSO4,aq 0.71158E-09 -9.1478 0.71158E-09 -9.1478 0.10000E+01 0.0000 71 NaCl,aq 0.73001E-08 -8.1367 0.73001E-08 -8.1367 0.10000E+01 0.0000 72 NaOH,aq 0.26845E-08 -8.5711 0.26845E-08 -8.5711 0.10000E+01 0.0000 74 OH- 0.22610E-04 -4.6457 0.21714E-04 -4.6633 0.96036E+00 -0.0176 79 HPO3-2 0.26441E-19 -19.5777 0.23738E-19 -19.6246 0.89778E+00 -0.0468 82 H3PO4,aq 0.18249E-13 -13.7388 0.18249E-13 -13.7388 0.10000E+01 0.0000 83 H2PO4- 0.18835E-08 -8.7250 0.18089E-08 -8.7426 0.96041E+00 -0.0175 84 PO4-3 0.14074E-12 -12.8516 0.11300E-12 -12.9469 0.80296E+00 -0.0953 87 H2P2O7-2 0.28579E-18 -18.5439 0.25658E-18 -18.5908 0.89778E+00 -0.0468 88 HP2O7-3 0.24004E-17 -17.6197 0.19255E-17 -17.7155 0.80214E+00 -0.0957 89 P2O7-4 0.25216E-19 -19.5983 0.17287E-19 -19.7623 0.68556E+00 -0.1640 90 H2S,aq 0.43087E-10 -10.3656 0.43084E-10 -10.3657 0.99991E+00 0.0000 96 SO2,aq 0.14864E-18 -18.8279 0.14864E-18 -18.8279 0.10000E+01 0.0000 97 SO3-2 0.68025E-14 -14.1673 0.61090E-14 -14.2140 0.89805E+00 -0.0467 98 HSO3- 0.10597E-13 -13.9748 0.10178E-13 -13.9924 0.96040E+00 -0.0175 99 HSO4- 0.60724E-09 -9.2166 0.58322E-09 -9.2342 0.96045E+00 -0.0175 101 S2O3-2 0.12821E-16 -16.8921 0.11511E-16 -16.9389 0.89778E+00 -0.0468 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2770185E-07 -.3269241E-04 -.3295129E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999770E+06 0.0000 3 Cl- 0.1379620E-03 0.1379747E-03 0.4891515E+01 3.6972 4 SO4-- 0.2533280E-04 0.2550350E-04 0.2449855E+01 10.5068 5 HCO3- 0.1233416E-04 0.1307005E-04 0.7974812E+00 2.6486 6 HS- 0.5455088E-09 0.1072880E-08 0.3548155E-04 -1.7058 7 Al+++ 0.1755863E-19 0.1774934E-05 0.4788937E-01 2.8737 8 H4SiO4 0.9704070E-04 0.1005976E-03 0.9668775E+01 -4.0130 9 Ca++ 0.2607978E-04 0.2634006E-04 0.1055635E+01 10.5194 10 Mg++ 0.5583237E-06 0.5664317E-06 0.1377080E-01 8.8499 11 Fe++ 0.3525315E-08 0.8061442E-08 0.4501978E-03 6.6503 12 K+ 0.2207259E-05 0.2208077E-05 0.8633840E-01 1.9013 13 Na+ 0.1731071E-03 0.1731262E-03 0.3980053E+01 3.7958 14 Mn++ 0.1207304E-06 0.1345159E-06 0.7389878E-02 8.1849 15 HPO4-- 0.4104766E-08 0.5988424E-08 0.5747508E-03 6.7164 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1591686E-03 -.3269228E-04 -.1264763E-03 0.0000000E+00 2 H2O 0.5550812E+02 0.5550805E+02 0.7173692E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2579269E-04 0.2550340E-04 0.2892923E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2882195E-06 0.1072876E-08 -.2892923E-06 0.0000000E+00 7 Al+++ 0.3391171E-04 0.1774927E-05 0.3213679E-04 0.0000000E+00 8 H4SiO4 0.1082929E-03 0.1005972E-03 0.7695741E-05 0.0000000E+00 9 Ca++ 0.2643254E-04 0.2633995E-04 0.9259066E-07 0.0000000E+00 10 Mg++ 0.8253968E-05 0.5664294E-06 0.7687539E-05 0.0000000E+00 11 Fe++ 0.7415289E-05 0.8061410E-08 0.7407228E-05 0.0000000E+00 12 K+ 0.2208068E-05 0.2208068E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1731255E-03 0.1731255E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1803214E-06 0.1345154E-06 0.4580604E-07 0.0000000E+00 15 HPO4-- 0.6154280E-07 0.5988400E-08 0.5555440E-07 0.0000000E+00 Chg. balance for solid moles: 0.7584E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0104000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1852E-07 -7.732 0.9302E-05 -5.031 0.2734 0.2956E-05 clinochlore 0.1538E-05 -5.813 0.8546E-03 -3.068 25.12 0.3251E-03 daphnite 0.1019E-05 -5.992 0.7268E-03 -3.139 21.36 0.2202E-03 chlorite-Mn 0.9161E-08 -8.038 0.6495E-05 -5.187 0.1909 0.2070E-05 diaspore 0.2701E-04 -4.569 0.1620E-02 -2.790 47.62 0.4823E-03 hematite 0.1157E-05 -5.937 0.1848E-03 -3.733 5.432 0.3503E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5994E+00 0.5994E+00 1.0000 -0.222 daphnite 0.3971E+00 0.3971E+00 1.0000 -0.401 chlorite-Mn 0.3571E-02 0.3571E-02 1.0000 -2.447 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003402 g Volume = 0.001068 cm3 Porosity: 99.8937% V(tot) - V(min): 0.10031E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0104000 g log = -1.9830 Original solution: 1000.0103000 g Original solution / Rock added: 96154.84 (Water/Rock Ratio), log = 4.9830 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.7012E-04 1.0071 0.7206E-04 0.7155E-04 CH4,gas 0.3776E-12 1.0125 0.3902E-12 0.3853E-12 H2,gas 0.2658E-05 1.0005 0.2714E-05 0.2712E-05 H2S,gas 0.1165E-08 0.9960 0.1184E-08 0.1189E-08 S2,gas 0.7007E-26 1.0000 0.7150E-26 0.7150E-26 CO,gas 0.5107E-13 1.0000 0.5211E-13 0.5211E-13 SO3,gas 0.5967E-35 1.0000 0.6088E-35 0.6088E-35 SO2,gas 0.6300E-18 1.0000 0.6428E-18 0.6428E-18 HCl,gas 0.1117E-14 1.0000 0.1140E-14 0.1140E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.50 -5.84 -1.947 0.99738E+04 -4.142 3 CH4,gas 4.54 -9.56 -14.11 -3.527 0.24089E+05 -12.409 4 H2,gas 8.00 0.73 -7.27 -4.152 0.12406E+05 -5.566 5 H2S,gas -6.23 -16.86 -10.63 -5.313 0.18143E+05 -8.927 6 S2,gas -7.34 -35.18 -27.84 -4.284 0.47544E+05 -26.146 7 CO,gas 3.21 -11.77 -14.98 -4.610 0.25581E+05 -13.283 8 SO3,gas 17.12 -19.79 -36.91 -9.229 0.63030E+05 -35.215 9 SO2,gas 0.83 -19.06 -19.89 -5.304 0.33963E+05 -18.192 10 HCl,gas 5.19 -11.45 -16.64 -8.321 0.28416E+05 -14.943 16 albite -0.38 -5.37 -4.99 -0.384 0.85132E+04 20 analcite 3.32 -1.36 -4.68 -0.520 0.79884E+04 21 andalusite 5.00 1.73 -3.27 -0.327 0.55786E+04 24 anhydrite -5.32 -9.27 -3.96 -1.978 0.67563E+04 29 anorthite 12.71 8.24 -4.47 -0.344 0.76317E+04 35 aragonite 0.97 -1.98 -2.95 -0.983 0.50345E+04 36 brucite 12.57 8.85 -3.72 -0.744 0.63495E+04 37 calcite 0.81 -1.98 -2.79 -0.931 0.47703E+04 40 carpholite-Mg 8.58 6.57 -2.01 -0.134 0.34335E+04 41 carpholite-Fe 6.71 4.37 -2.34 -0.156 0.39973E+04 50 chloritoid-Mg 13.20 10.58 -2.61 -0.174 0.44623E+04 51 chloritoid-Fe 9.17 8.38 -0.79 -0.053 0.13472E+04 52 chloritoid-Mn 11.40 9.92 -1.48 -0.099 0.25302E+04 54 coesite -2.38 -4.01 -1.64 -0.546 0.27951E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -4.01 -1.45 -0.484 0.24805E+04 67 diopside 16.18 11.34 -4.84 -0.484 0.82609E+04 75 epidote 24.67 21.03 -3.64 -0.176 0.62148E+04 78 fayalite 14.05 9.29 -4.76 -0.680 0.81246E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.92 -4.21 -0.351 0.71967E+04 92 hercynite 17.28 12.40 -4.88 -0.325 0.83340E+04 98 kaolinite -1.33 -2.28 -0.95 -0.086 0.16151E+04 99 kyanite 4.88 1.73 -3.14 -0.314 0.53645E+04 101 laumontite 2.88 0.21 -2.67 -0.178 0.45569E+04 102 lawsonite 9.62 8.24 -1.38 -0.092 0.23484E+04 105 lizardite 23.24 18.52 -4.72 -0.393 0.80595E+04 106 magnesite 0.69 -3.65 -4.34 -1.447 0.74140E+04 107 magnetite 20.09 19.22 -0.87 -0.071 0.14871E+04 110 magnesioferrite 26.21 21.42 -4.80 -0.392 0.81895E+04 113 margarite 17.32 13.99 -3.34 -0.133 0.56953E+04 116 microcline -2.49 -7.26 -4.78 -0.368 0.81577E+04 120 muscovite 2.58 -1.52 -4.10 -0.241 0.69992E+04 121 paragonite 4.24 0.38 -3.86 -0.227 0.65938E+04 128 periclase-Fe 11.63 6.65 -4.98 -1.244 0.84969E+04 136 prehnite 19.37 14.75 -4.62 -0.272 0.78968E+04 137 prehnite-Fe 22.50 18.16 -4.34 -0.261 0.74128E+04 145 pyroxmangite 7.40 4.17 -3.23 -0.645 0.55097E+04 146 pyrophyllite -6.18 -10.30 -4.13 -0.258 0.70501E+04 147 quartz -2.99 -4.01 -1.02 -0.341 0.17478E+04 151 rhodochrosite -0.98 -4.32 -3.34 -1.113 0.57033E+04 152 rhodonite 7.45 4.17 -3.27 -0.655 0.55900E+04 155 siderite -2.61 -5.85 -3.24 -1.081 0.55373E+04 156 sillimanite 5.26 1.73 -3.53 -0.353 0.60226E+04 163 stilbite -7.52 -11.82 -4.30 -0.205 0.73464E+04 168 sudoite 21.08 17.16 -3.92 -0.127 0.66964E+04 177 topaz-H 4.62 1.73 -2.88 -0.262 0.49246E+04 178 tridymite -2.63 -4.01 -1.39 -0.462 0.23678E+04 187 wairakite 3.95 0.21 -3.74 -0.220 0.63789E+04 189 wollastonite 10.46 6.51 -3.95 -0.791 0.67527E+04 190 pseudo-wollastonite 11.00 6.51 -4.49 -0.899 0.76725E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -6.30 -4.65 -0.288 0.79412E+04 196 beidellite-Mg -1.79 -6.57 -4.78 -0.296 0.81654E+04 199 chalcedony -2.80 -4.01 -1.21 -0.404 0.20671E+04 201 montmorillonite-Ca -2.29 -6.60 -4.31 -0.266 0.73527E+04 203 montmorillonite-Mg -2.48 -6.87 -4.39 -0.272 0.75001E+04 205 nontronite-Ca 3.21 0.52 -2.69 -0.175 0.45969E+04 206 nontronite-H 2.53 -1.21 -3.75 -0.251 0.63963E+04 207 nontronite-K 3.34 -0.59 -3.93 -0.252 0.67046E+04 208 nontronite-Mg 3.07 0.25 -2.83 -0.183 0.48283E+04 209 nontronite-Na 3.52 0.04 -3.48 -0.223 0.59428E+04 214 gypsum -4.96 -9.27 -4.32 -1.080 0.73739E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.65 -3.16 -0.790 0.53979E+04 240 silica-amorphous -2.09 -4.01 -1.92 -0.641 0.32813E+04 242 an20ab80 2.02 -2.65 -4.67 -0.359 0.79660E+04 243 an25ab75 2.65 -1.97 -4.61 -0.355 0.78762E+04 244 an30ab70 3.28 -1.29 -4.57 -0.351 0.77960E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0104000 g New total amount of reactant added: 0.0108000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0108000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2777293E-03 Osmotic coef. = 0.9900 True ionic strength = .2828768E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.26549E-07 -7.5760 0.25499E-07 -7.5935 0.96045E+00 -0.0175 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13249E-03 -3.8778 0.96033E+00 -0.0176 4 SO4-- 0.25330E-04 -4.5964 0.22736E-04 -4.6433 0.89757E+00 -0.0469 5 HCO3- 0.12358E-04 -4.9080 0.11868E-04 -4.9256 0.96036E+00 -0.0176 6 HS- 0.42010E-09 -9.3766 0.40344E-09 -9.3942 0.96033E+00 -0.0176 7 Al+++ 0.15463E-19 -19.8107 0.12396E-19 -19.9067 0.80164E+00 -0.0960 8 H4SiO4 0.10057E-03 -3.9975 0.10057E-03 -3.9975 0.10000E+01 0.0000 9 Ca++ 0.26527E-04 -4.5763 0.23806E-04 -4.6233 0.89744E+00 -0.0470 10 Mg++ 0.50365E-06 -6.2979 0.45195E-06 -6.3449 0.89735E+00 -0.0470 11 Fe++ 0.31513E-08 -8.5015 0.28279E-08 -8.5485 0.89737E+00 -0.0470 12 K+ 0.22922E-05 -5.6398 0.22013E-05 -5.6573 0.96036E+00 -0.0176 13 Na+ 0.17361E-03 -3.7604 0.16672E-03 -3.7780 0.96033E+00 -0.0176 14 Mn++ 0.12005E-06 -6.9207 0.10773E-06 -6.9677 0.89739E+00 -0.0470 15 HPO4-- 0.37726E-08 -8.4234 0.33862E-08 -8.4703 0.89757E+00 -0.0469 16 HSiO3- 0.38348E-05 -5.4163 0.36827E-05 -5.4338 0.96033E+00 -0.0176 17 Ca(HSiO3)+ 0.20790E-08 -8.6821 0.19966E-08 -8.6997 0.96037E+00 -0.0176 18 Mg(HSiO3)+ 0.49119E-10 -10.3087 0.47172E-10 -10.3263 0.96037E+00 -0.0176 19 NaHSiO3,aq 0.99303E-08 -8.0030 0.99303E-08 -8.0030 0.10000E+01 0.0000 20 AlO+ 0.27006E-11 -11.5685 0.25936E-11 -11.5861 0.96037E+00 -0.0176 21 AlOH+2 0.36695E-15 -15.4354 0.32930E-15 -15.4824 0.89740E+00 -0.0470 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.18311E-05 -5.7373 0.17584E-05 -5.7549 0.96029E+00 -0.0176 24 CH4,aq 0.20459E-15 -15.6891 0.20457E-15 -15.6891 0.99991E+00 0.0000 29 CO,aq 0.31792E-16 -16.4977 0.31792E-16 -16.4977 0.10000E+01 0.0000 30 CO2,aq 0.64671E-06 -6.1893 0.64665E-06 -6.1893 0.99991E+00 0.0000 31 CO3-2 0.45296E-07 -7.3439 0.40654E-07 -7.3909 0.89753E+00 -0.0470 32 CaCO3,aq 0.12136E-07 -7.9159 0.12136E-07 -7.9159 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.75098E-08 -8.1244 0.72121E-08 -8.1419 0.96037E+00 -0.0176 34 CaCl+ 0.53149E-08 -8.2745 0.51043E-08 -8.2921 0.96037E+00 -0.0176 35 CaCl2,aq 0.16067E-12 -12.7941 0.16067E-12 -12.7941 0.10000E+01 0.0000 36 CaOH+ 0.69284E-07 -7.1594 0.66538E-07 -7.1769 0.96037E+00 -0.0176 37 CaSO4,aq 0.17187E-06 -6.7648 0.17187E-06 -6.7648 0.10000E+01 0.0000 38 HCl,aq 0.61907E-12 -12.2083 0.61907E-12 -12.2083 0.10000E+01 0.0000 43 FeCl+ 0.61749E-12 -12.2094 0.59302E-12 -12.2269 0.96037E+00 -0.0176 46 FeO,aq 0.16903E-09 -9.7720 0.16903E-09 -9.7720 0.10000E+01 0.0000 47 FeOH+ 0.37589E-08 -8.4249 0.36099E-08 -8.4425 0.96037E+00 -0.0176 48 HFeO2- 0.72226E-10 -10.1413 0.69360E-10 -10.1589 0.96033E+00 -0.0176 49 FeO+ 0.20266E-12 -12.6932 0.19463E-12 -12.7108 0.96037E+00 -0.0176 50 FeOH+2 0.10561E-17 -17.9763 0.94777E-18 -18.0233 0.89740E+00 -0.0470 51 FeO2- 0.63781E-10 -10.1953 0.61251E-10 -10.2129 0.96033E+00 -0.0176 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.19573E-08 -8.7083 0.19571E-08 -8.7084 0.99991E+00 0.0000 54 KCl,aq 0.52859E-11 -11.2769 0.52859E-11 -11.2769 0.10000E+01 0.0000 55 KHSO4,aq 0.36082E-17 -17.4427 0.36082E-17 -17.4427 0.10000E+01 0.0000 56 KOH,aq 0.36867E-10 -10.4334 0.36867E-10 -10.4334 0.10000E+01 0.0000 57 KSO4- 0.80870E-09 -9.0922 0.77662E-09 -9.1098 0.96033E+00 -0.0176 58 MgCO3,aq 0.57748E-10 -10.2385 0.57748E-10 -10.2385 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14568E-09 -9.8366 0.13990E-09 -9.8542 0.96037E+00 -0.0176 60 MgCl+ 0.91450E-10 -10.0388 0.87826E-10 -10.0564 0.96037E+00 -0.0176 61 MgOH+ 0.72783E-08 -8.1380 0.69898E-08 -8.1555 0.96037E+00 -0.0176 63 MnO,aq 0.17158E-09 -9.7655 0.17158E-09 -9.7655 0.10000E+01 0.0000 64 MnOH+ 0.13302E-07 -7.8761 0.12775E-07 -7.8936 0.96037E+00 -0.0176 65 MnO2-2 0.97577E-17 -17.0107 0.87578E-17 -17.0576 0.89753E+00 -0.0470 66 HMnO2- 0.50946E-13 -13.2929 0.48925E-13 -13.3105 0.96033E+00 -0.0176 69 MnCl+ 0.91518E-10 -10.0385 0.87891E-10 -10.0561 0.96037E+00 -0.0176 70 MnSO4,aq 0.70708E-09 -9.1505 0.70708E-09 -9.1505 0.10000E+01 0.0000 71 NaCl,aq 0.73202E-08 -8.1355 0.73202E-08 -8.1355 0.10000E+01 0.0000 72 NaOH,aq 0.28092E-08 -8.5514 0.28092E-08 -8.5514 0.10000E+01 0.0000 74 OH- 0.23596E-04 -4.6272 0.22659E-04 -4.6448 0.96029E+00 -0.0176 79 HPO3-2 0.23011E-19 -19.6381 0.20653E-19 -19.6850 0.89753E+00 -0.0470 82 H3PO4,aq 0.15399E-13 -13.8125 0.15399E-13 -13.8125 0.10000E+01 0.0000 83 H2PO4- 0.16586E-08 -8.7803 0.15928E-08 -8.7978 0.96035E+00 -0.0176 84 PO4-3 0.13502E-12 -12.8696 0.10835E-12 -12.9652 0.80247E+00 -0.0956 87 H2P2O7-2 0.22165E-18 -18.6543 0.19894E-18 -18.7013 0.89753E+00 -0.0470 88 HP2O7-3 0.19433E-17 -17.7115 0.15578E-17 -17.8075 0.80164E+00 -0.0960 89 P2O7-4 0.21313E-19 -19.6714 0.14595E-19 -19.8358 0.68481E+00 -0.1644 90 H2S,aq 0.31797E-10 -10.4976 0.31794E-10 -10.4977 0.99991E+00 0.0000 96 SO2,aq 0.12921E-18 -18.8887 0.12921E-18 -18.8887 0.10000E+01 0.0000 97 SO3-2 0.64405E-14 -14.1911 0.57823E-14 -14.2379 0.89781E+00 -0.0468 98 HSO3- 0.96131E-14 -14.0171 0.92318E-14 -14.0347 0.96033E+00 -0.0176 99 HSO4- 0.58175E-09 -9.2353 0.55870E-09 -9.2528 0.96039E+00 -0.0176 101 S2O3-2 0.94608E-17 -17.0241 0.84913E-17 -17.0710 0.89753E+00 -0.0470 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2654901E-07 -.3430808E-04 -.3457974E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999766E+06 0.0000 3 Cl- 0.1379619E-03 0.1379748E-03 0.4891514E+01 3.7157 4 SO4-- 0.2533016E-04 0.2550367E-04 0.2449870E+01 10.5437 5 HCO3- 0.1235820E-04 0.1307005E-04 0.7974810E+00 2.6679 6 HS- 0.4201048E-09 0.9084031E-09 0.3004206E-04 -1.8007 7 Al+++ 0.1546283E-19 0.1851379E-05 0.4995192E-01 2.8737 8 H4SiO4 0.1005689E-03 0.1044158E-03 0.1003575E+02 -3.9975 9 Ca++ 0.2652705E-04 0.2679525E-04 0.1073877E+01 10.5636 10 Mg++ 0.5036460E-06 0.5112683E-06 0.1242969E-01 8.8420 11 Fe++ 0.3151265E-08 0.7414662E-08 0.4140777E-03 6.6384 12 K+ 0.2292152E-05 0.2293003E-05 0.8965908E-01 1.9362 13 Na+ 0.1736083E-03 0.1736284E-03 0.3991595E+01 3.8155 14 Mn++ 0.1200462E-06 0.1343189E-06 0.7379052E-02 8.2193 15 HPO4-- 0.3772635E-08 0.5431388E-08 0.5212879E-03 6.7167 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1657920E-03 -.3430794E-04 -.1314840E-03 0.0000000E+00 2 H2O 0.5550811E+02 0.5550804E+02 0.7451226E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2580377E-04 0.2550356E-04 0.3002132E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2993048E-06 0.9083993E-09 -.3002132E-06 0.0000000E+00 7 Al+++ 0.3521601E-04 0.1851372E-05 0.3336464E-04 0.0000000E+00 8 H4SiO4 0.1124581E-03 0.1044154E-03 0.8042684E-05 0.0000000E+00 9 Ca++ 0.2689260E-04 0.2679514E-04 0.9746410E-07 0.0000000E+00 10 Mg++ 0.8571429E-05 0.5112662E-06 0.8060162E-05 0.0000000E+00 11 Fe++ 0.7700493E-05 0.7414630E-08 0.7693078E-05 0.0000000E+00 12 K+ 0.2292994E-05 0.2292994E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1736276E-03 0.1736276E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1872568E-06 0.1343183E-06 0.5293852E-07 0.0000000E+00 15 HPO4-- 0.6390983E-07 0.5431365E-08 0.5847846E-07 0.0000000E+00 Chg. balance for solid moles: -.6631E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0108000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1949E-07 -7.710 0.9792E-05 -5.009 0.2766 0.3111E-05 clinochlore 0.1612E-05 -5.793 0.8960E-03 -3.048 25.31 0.3408E-03 daphnite 0.1058E-05 -5.975 0.7551E-03 -3.122 21.33 0.2288E-03 chlorite-Mn 0.1059E-07 -7.975 0.7506E-05 -5.125 0.2120 0.2392E-05 diaspore 0.2800E-04 -4.553 0.1680E-02 -2.775 47.45 0.5001E-03 hematite 0.1201E-05 -5.921 0.1918E-03 -3.717 5.417 0.3635E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6013E+00 0.6013E+00 1.0000 -0.221 daphnite 0.3947E+00 0.3947E+00 1.0000 -0.404 chlorite-Mn 0.3949E-02 0.3949E-02 1.0000 -2.403 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003540 g Volume = 0.001112 cm3 Porosity: 99.8893% V(tot) - V(min): 0.10032E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0108000 g log = -1.9666 Original solution: 1000.0103000 g Original solution / Rock added: 92593.55 (Water/Rock Ratio), log = 4.9666 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.6733E-04 1.0071 0.6918E-04 0.6870E-04 CH4,gas 0.2915E-12 1.0125 0.3011E-12 0.2974E-12 H2,gas 0.2517E-05 1.0005 0.2569E-05 0.2568E-05 H2S,gas 0.8600E-09 0.9960 0.8740E-09 0.8775E-09 S2,gas 0.4256E-26 1.0000 0.4343E-26 0.4343E-26 CO,gas 0.4643E-13 1.0000 0.4738E-13 0.4738E-13 SO3,gas 0.5478E-35 1.0000 0.5589E-35 0.5589E-35 SO2,gas 0.5476E-18 1.0000 0.5587E-18 0.5587E-18 HCl,gas 0.1071E-14 1.0000 0.1092E-14 0.1092E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.52 -5.86 -1.953 0.10004E+05 -4.160 3 CH4,gas 4.54 -9.68 -14.22 -3.555 0.24281E+05 -12.521 4 H2,gas 8.00 0.71 -7.29 -4.165 0.12446E+05 -5.590 5 H2S,gas -6.23 -16.99 -10.76 -5.379 0.18368E+05 -9.058 6 S2,gas -7.34 -35.40 -28.06 -4.317 0.47914E+05 -26.362 7 CO,gas 3.21 -11.81 -15.02 -4.623 0.25652E+05 -13.324 8 SO3,gas 17.12 -19.83 -36.95 -9.238 0.63094E+05 -35.253 9 SO2,gas 0.83 -19.12 -19.95 -5.320 0.34067E+05 -18.253 10 HCl,gas 5.19 -11.47 -16.66 -8.330 0.28448E+05 -14.962 16 albite -0.38 -5.30 -4.92 -0.378 0.84000E+04 20 analcite 3.32 -1.31 -4.63 -0.514 0.79018E+04 21 andalusite 5.00 1.75 -3.25 -0.325 0.55521E+04 24 anhydrite -5.32 -9.27 -3.95 -1.975 0.67442E+04 29 anorthite 12.71 8.32 -4.39 -0.338 0.75032E+04 35 aragonite 0.97 -1.96 -2.92 -0.974 0.49892E+04 36 brucite 12.57 8.84 -3.73 -0.745 0.63629E+04 37 calcite 0.81 -1.96 -2.77 -0.922 0.47249E+04 40 carpholite-Mg 8.58 6.59 -1.99 -0.133 0.33940E+04 41 carpholite-Fe 6.71 4.39 -2.32 -0.155 0.39646E+04 50 chloritoid-Mg 13.20 10.59 -2.61 -0.174 0.44493E+04 51 chloritoid-Fe 9.17 8.39 -0.79 -0.052 0.13410E+04 52 chloritoid-Mn 11.40 9.97 -1.43 -0.095 0.24450E+04 54 coesite -2.38 -4.00 -1.62 -0.540 0.27686E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -4.00 -1.44 -0.479 0.24540E+04 67 diopside 16.18 11.41 -4.77 -0.477 0.81459E+04 75 epidote 24.67 21.17 -3.50 -0.170 0.59843E+04 78 fayalite 14.05 9.28 -4.77 -0.681 0.81386E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.92 -4.22 -0.352 0.72044E+04 92 hercynite 17.28 12.39 -4.89 -0.326 0.83542E+04 98 kaolinite -1.33 -2.25 -0.91 -0.083 0.15622E+04 99 kyanite 4.88 1.75 -3.13 -0.313 0.53380E+04 101 laumontite 2.88 0.32 -2.56 -0.171 0.43754E+04 102 lawsonite 9.62 8.32 -1.30 -0.087 0.22199E+04 105 lizardite 23.24 18.53 -4.71 -0.393 0.80470E+04 106 magnesite 0.69 -3.68 -4.37 -1.456 0.74576E+04 107 magnetite 20.09 19.20 -0.88 -0.072 0.15074E+04 110 magnesioferrite 26.21 21.41 -4.80 -0.392 0.82030E+04 113 margarite 17.32 14.06 -3.26 -0.130 0.55668E+04 116 microcline -2.49 -7.18 -4.70 -0.361 0.80187E+04 120 muscovite 2.58 -1.44 -4.02 -0.236 0.68603E+04 121 paragonite 4.24 0.44 -3.80 -0.223 0.64807E+04 128 periclase-Fe 11.63 6.64 -4.99 -1.247 0.85172E+04 136 prehnite 19.37 14.88 -4.49 -0.264 0.76662E+04 137 prehnite-Fe 22.50 18.29 -4.21 -0.253 0.71823E+04 145 pyroxmangite 7.40 4.22 -3.18 -0.635 0.54245E+04 146 pyrophyllite -6.18 -10.24 -4.07 -0.254 0.69442E+04 147 quartz -2.99 -4.00 -1.01 -0.336 0.17213E+04 151 rhodochrosite -0.98 -4.30 -3.32 -1.108 0.56748E+04 152 rhodonite 7.45 4.22 -3.22 -0.645 0.55048E+04 155 siderite -2.61 -5.88 -3.27 -1.091 0.55878E+04 156 sillimanite 5.26 1.75 -3.51 -0.351 0.59961E+04 163 stilbite -7.52 -11.67 -4.15 -0.198 0.70854E+04 168 sudoite 21.08 17.19 -3.89 -0.126 0.66439E+04 177 topaz-H 4.62 1.75 -2.87 -0.261 0.48981E+04 178 tridymite -2.63 -4.00 -1.37 -0.457 0.23413E+04 187 wairakite 3.95 0.32 -3.63 -0.214 0.61974E+04 188 walstromite 11.51 6.57 -4.94 -0.989 0.84402E+04 189 wollastonite 10.46 6.57 -3.90 -0.779 0.66507E+04 190 pseudo-wollastonite 11.00 6.57 -4.43 -0.887 0.75705E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -6.23 -4.59 -0.284 0.78316E+04 196 beidellite-Mg -1.79 -6.52 -4.73 -0.292 0.80704E+04 199 chalcedony -2.80 -4.00 -1.20 -0.398 0.20406E+04 201 montmorillonite-Ca -2.29 -6.53 -4.24 -0.262 0.72388E+04 203 montmorillonite-Mg -2.48 -6.81 -4.33 -0.268 0.74008E+04 204 montmorillonite-Na -2.04 -7.01 -4.98 -0.305 0.84969E+04 205 nontronite-Ca 3.21 0.59 -2.63 -0.170 0.44872E+04 206 nontronite-H 2.53 -1.16 -3.69 -0.247 0.62991E+04 207 nontronite-K 3.34 -0.52 -3.86 -0.248 0.65878E+04 208 nontronite-Mg 3.07 0.30 -2.77 -0.180 0.47334E+04 209 nontronite-Na 3.52 0.10 -3.42 -0.219 0.58345E+04 214 gypsum -4.96 -9.27 -4.31 -1.078 0.73618E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.64 -3.17 -0.793 0.54181E+04 240 silica-amorphous -2.09 -4.00 -1.91 -0.635 0.32548E+04 242 an20ab80 2.02 -2.58 -4.60 -0.354 0.78498E+04 243 an25ab75 2.65 -1.90 -4.54 -0.350 0.77593E+04 244 an30ab70 3.28 -1.22 -4.50 -0.346 0.76783E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0108000 g New total amount of reactant added: 0.0112000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0112000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2791789E-03 Osmotic coef. = 0.9900 True ionic strength = .2846592E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.25485E-07 -7.5937 0.24476E-07 -7.6113 0.96039E+00 -0.0176 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13248E-03 -3.8779 0.96026E+00 -0.0176 4 SO4-- 0.25327E-04 -4.5964 0.22727E-04 -4.6435 0.89732E+00 -0.0471 5 HCO3- 0.12380E-04 -4.9073 0.11889E-04 -4.9249 0.96029E+00 -0.0176 6 HS- 0.32836E-09 -9.4836 0.31531E-09 -9.5013 0.96027E+00 -0.0176 7 Al+++ 0.13683E-19 -19.8638 0.10962E-19 -19.9601 0.80114E+00 -0.0963 8 H4SiO4 0.10409E-03 -3.9826 0.10409E-03 -3.9826 0.10000E+01 0.0000 9 Ca++ 0.26974E-04 -4.5690 0.24201E-04 -4.6162 0.89719E+00 -0.0471 10 Mg++ 0.45587E-06 -6.3412 0.40896E-06 -6.3883 0.89710E+00 -0.0472 11 Fe++ 0.28307E-08 -8.5481 0.25394E-08 -8.5953 0.89712E+00 -0.0471 12 K+ 0.23770E-05 -5.6240 0.22827E-05 -5.6416 0.96030E+00 -0.0176 13 Na+ 0.17411E-03 -3.7592 0.16719E-03 -3.7768 0.96026E+00 -0.0176 14 Mn++ 0.11892E-06 -6.9247 0.10669E-06 -6.9719 0.89714E+00 -0.0471 15 HPO4-- 0.34765E-08 -8.4589 0.31195E-08 -8.5059 0.89733E+00 -0.0470 16 HSiO3- 0.41353E-05 -5.3835 0.39710E-05 -5.4011 0.96026E+00 -0.0176 17 Ca(HSiO3)+ 0.22791E-08 -8.6422 0.21886E-08 -8.6598 0.96030E+00 -0.0176 18 Mg(HSiO3)+ 0.47930E-10 -10.3194 0.46027E-10 -10.3370 0.96030E+00 -0.0176 19 NaHSiO3,aq 0.10738E-07 -7.9691 0.10738E-07 -7.9691 0.10000E+01 0.0000 20 AlO+ 0.25924E-11 -11.5863 0.24895E-11 -11.6039 0.96030E+00 -0.0176 21 AlOH+2 0.33818E-15 -15.4709 0.30340E-15 -15.5180 0.89715E+00 -0.0471 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.19078E-05 -5.7195 0.18319E-05 -5.7371 0.96023E+00 -0.0176 24 CH4,aq 0.16024E-15 -15.7952 0.16022E-15 -15.7953 0.99991E+00 0.0000 29 CO,aq 0.29041E-16 -16.5370 0.29041E-16 -16.5370 0.10000E+01 0.0000 30 CO2,aq 0.62181E-06 -6.2063 0.62176E-06 -6.2064 0.99991E+00 0.0000 31 CO3-2 0.47284E-07 -7.3253 0.42427E-07 -7.3724 0.89728E+00 -0.0471 32 CaCO3,aq 0.12875E-07 -7.8903 0.12875E-07 -7.8903 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.76479E-08 -8.1165 0.73443E-08 -8.1341 0.96030E+00 -0.0176 34 CaCl+ 0.54030E-08 -8.2674 0.51885E-08 -8.2850 0.96030E+00 -0.0176 35 CaCl2,aq 0.16331E-12 -12.7870 0.16331E-12 -12.7870 0.10000E+01 0.0000 36 CaOH+ 0.73383E-07 -7.1344 0.70470E-07 -7.1520 0.96030E+00 -0.0176 37 CaSO4,aq 0.17466E-06 -6.7578 0.17466E-06 -6.7578 0.10000E+01 0.0000 38 HCl,aq 0.59418E-12 -12.2261 0.59418E-12 -12.2261 0.10000E+01 0.0000 43 FeCl+ 0.55452E-12 -12.2561 0.53250E-12 -12.2737 0.96030E+00 -0.0176 46 FeO,aq 0.16476E-09 -9.7832 0.16476E-09 -9.7832 0.10000E+01 0.0000 47 FeOH+ 0.35169E-08 -8.4538 0.33773E-08 -8.4714 0.96030E+00 -0.0176 48 HFeO2- 0.73346E-10 -10.1346 0.70432E-10 -10.1522 0.96026E+00 -0.0176 49 FeO+ 0.19454E-12 -12.7110 0.18682E-12 -12.7286 0.96030E+00 -0.0176 50 FeOH+2 0.97331E-18 -18.0117 0.87321E-18 -18.0589 0.89715E+00 -0.0471 51 FeO2- 0.66453E-10 -10.1775 0.63813E-10 -10.1951 0.96026E+00 -0.0176 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.18595E-08 -8.7306 0.18593E-08 -8.7306 0.99991E+00 0.0000 54 KCl,aq 0.54809E-11 -11.2611 0.54809E-11 -11.2611 0.10000E+01 0.0000 55 KHSO4,aq 0.35901E-17 -17.4449 0.35901E-17 -17.4449 0.10000E+01 0.0000 56 KOH,aq 0.39829E-10 -10.3998 0.39829E-10 -10.3998 0.10000E+01 0.0000 57 KSO4- 0.83834E-09 -9.0766 0.80502E-09 -9.0942 0.96026E+00 -0.0176 58 MgCO3,aq 0.54533E-10 -10.2633 0.54533E-10 -10.2633 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13206E-09 -9.8792 0.12681E-09 -9.8968 0.96030E+00 -0.0176 60 MgCl+ 0.82751E-10 -10.0822 0.79466E-10 -10.0998 0.96030E+00 -0.0176 61 MgOH+ 0.68619E-08 -8.1636 0.65895E-08 -8.1811 0.96030E+00 -0.0176 63 MnO,aq 0.18444E-09 -9.7341 0.18444E-09 -9.7341 0.10000E+01 0.0000 64 MnOH+ 0.13726E-07 -7.8625 0.13181E-07 -7.8800 0.96030E+00 -0.0176 65 MnO2-2 0.11388E-16 -16.9436 0.10218E-16 -16.9906 0.89728E+00 -0.0471 66 HMnO2- 0.57057E-13 -13.2437 0.54790E-13 -13.2613 0.96026E+00 -0.0176 69 MnCl+ 0.90636E-10 -10.0427 0.87038E-10 -10.0603 0.96030E+00 -0.0176 70 MnSO4,aq 0.70000E-09 -9.1549 0.70000E-09 -9.1549 0.10000E+01 0.0000 71 NaCl,aq 0.73403E-08 -8.1343 0.73403E-08 -8.1343 0.10000E+01 0.0000 72 NaOH,aq 0.29349E-08 -8.5324 0.29349E-08 -8.5324 0.10000E+01 0.0000 74 OH- 0.24584E-04 -4.6093 0.23606E-04 -4.6270 0.96023E+00 -0.0176 79 HPO3-2 0.20145E-19 -19.6958 0.18075E-19 -19.7429 0.89728E+00 -0.0471 82 H3PO4,aq 0.13070E-13 -13.8837 0.13070E-13 -13.8837 0.10000E+01 0.0000 83 H2PO4- 0.14668E-08 -8.8336 0.14085E-08 -8.8512 0.96028E+00 -0.0176 84 PO4-3 0.12967E-12 -12.8872 0.10399E-12 -12.9830 0.80197E+00 -0.0958 87 H2P2O7-2 0.17336E-18 -18.7610 0.15556E-18 -18.8081 0.89728E+00 -0.0471 88 HP2O7-3 0.15841E-17 -17.8002 0.12691E-17 -17.8965 0.80114E+00 -0.0963 89 P2O7-4 0.18108E-19 -19.7421 0.12387E-19 -19.9070 0.68405E+00 -0.1649 90 H2S,aq 0.23854E-10 -10.6224 0.23852E-10 -10.6225 0.99991E+00 0.0000 96 SO2,aq 0.11305E-18 -18.9467 0.11305E-18 -18.9467 0.10000E+01 0.0000 97 SO3-2 0.61179E-14 -14.2134 0.54912E-14 -14.2603 0.89756E+00 -0.0469 98 HSO3- 0.87633E-14 -14.0573 0.84151E-14 -14.0749 0.96026E+00 -0.0176 99 HSO4- 0.55822E-09 -9.2532 0.53607E-09 -9.2708 0.96032E+00 -0.0176 101 S2O3-2 0.70967E-17 -17.1489 0.63677E-17 -17.1960 0.89728E+00 -0.0471 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2548514E-07 -.3593772E-04 -.3622227E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999762E+06 0.0000 3 Cl- 0.1379619E-03 0.1379748E-03 0.4891512E+01 3.7334 4 SO4-- 0.2532748E-04 0.2550380E-04 0.2449882E+01 10.5791 5 HCO3- 0.1238025E-04 0.1307006E-04 0.7974807E+00 2.6864 6 HS- 0.3283621E-09 0.7839254E-09 0.2592541E-04 -1.8900 7 Al+++ 0.1368315E-19 0.1928083E-05 0.5202144E-01 2.8737 8 H4SiO4 0.1040897E-03 0.1082381E-03 0.1040312E+02 -3.9826 9 Ca++ 0.2697431E-04 0.2725055E-04 0.1092124E+01 10.6064 10 Mg++ 0.4558669E-06 0.4630460E-06 0.1125733E-01 8.8342 11 Fe++ 0.2830665E-08 0.6851545E-08 0.3826298E-03 6.6273 12 K+ 0.2377046E-05 0.2377930E-05 0.9297976E-01 1.9697 13 Na+ 0.1741095E-03 0.1741305E-03 0.4003137E+01 3.8345 14 Mn++ 0.1189231E-06 0.1336244E-06 0.7340895E-02 8.2507 15 HPO4-- 0.3476496E-08 0.4943396E-08 0.4744518E-03 6.7166 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1724154E-03 -.3593756E-04 -.1364778E-03 0.0000000E+00 2 H2O 0.5550811E+02 0.5550803E+02 0.7728465E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2581486E-04 0.2550369E-04 0.3111741E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3103902E-06 0.7839220E-09 -.3111741E-06 0.0000000E+00 7 Al+++ 0.3652031E-04 0.1928075E-05 0.3459223E-04 0.0000000E+00 8 H4SiO4 0.1166232E-03 0.1082376E-03 0.8385519E-05 0.0000000E+00 9 Ca++ 0.2735266E-04 0.2725044E-04 0.1022225E-06 0.0000000E+00 10 Mg++ 0.8888889E-05 0.4630440E-06 0.8425845E-05 0.0000000E+00 11 Fe++ 0.7985696E-05 0.6851515E-08 0.7978845E-05 0.0000000E+00 12 K+ 0.2377919E-05 0.2377919E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1741297E-03 0.1741297E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1941923E-06 0.1336238E-06 0.6056847E-07 0.0000000E+00 15 HPO4-- 0.6627686E-07 0.4943374E-08 0.6133348E-07 0.0000000E+00 Chg. balance for solid moles: -.5294E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0112000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2044E-07 -7.689 0.1027E-04 -4.988 0.2793 0.3263E-05 clinochlore 0.1685E-05 -5.773 0.9367E-03 -3.028 25.47 0.3563E-03 daphnite 0.1098E-05 -5.959 0.7834E-03 -3.106 21.30 0.2374E-03 chlorite-Mn 0.1211E-07 -7.917 0.8588E-05 -5.066 0.2335 0.2737E-05 diaspore 0.2900E-04 -4.538 0.1740E-02 -2.759 47.31 0.5180E-03 hematite 0.1245E-05 -5.905 0.1988E-03 -3.702 5.405 0.3768E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6029E+00 0.6029E+00 1.0000 -0.220 daphnite 0.3928E+00 0.3928E+00 1.0000 -0.406 chlorite-Mn 0.4334E-02 0.4334E-02 1.0000 -2.363 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003677 g Volume = 0.001155 cm3 Porosity: 99.8850% V(tot) - V(min): 0.10033E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0112000 g log = -1.9508 Original solution: 1000.0103000 g Original solution / Rock added: 89286.63 (Water/Rock Ratio), log = 4.9508 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.6473E-04 1.0071 0.6652E-04 0.6605E-04 CH4,gas 0.2283E-12 1.0125 0.2358E-12 0.2329E-12 H2,gas 0.2391E-05 1.0005 0.2441E-05 0.2440E-05 H2S,gas 0.6451E-09 0.9960 0.6557E-09 0.6583E-09 S2,gas 0.2654E-26 1.0000 0.2708E-26 0.2708E-26 CO,gas 0.4241E-13 1.0000 0.4328E-13 0.4328E-13 SO3,gas 0.5045E-35 1.0000 0.5148E-35 0.5148E-35 SO2,gas 0.4791E-18 1.0000 0.4889E-18 0.4889E-18 HCl,gas 0.1028E-14 1.0000 0.1048E-14 0.1048E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.54 -5.88 -1.959 0.10033E+05 -4.177 3 CH4,gas 4.54 -9.78 -14.33 -3.582 0.24462E+05 -12.627 4 H2,gas 8.00 0.69 -7.31 -4.178 0.12484E+05 -5.612 5 H2S,gas -6.23 -17.11 -10.88 -5.441 0.18581E+05 -9.183 6 S2,gas -7.34 -35.60 -28.27 -4.349 0.48264E+05 -26.567 7 CO,gas 3.21 -11.85 -15.06 -4.635 0.25719E+05 -13.364 8 SO3,gas 17.12 -19.87 -36.99 -9.247 0.63155E+05 -35.288 9 SO2,gas 0.83 -19.18 -20.01 -5.336 0.34166E+05 -18.311 10 HCl,gas 5.19 -11.49 -16.68 -8.339 0.28478E+05 -14.979 16 albite -0.38 -5.24 -4.86 -0.374 0.82910E+04 20 analcite 3.32 -1.26 -4.58 -0.509 0.78183E+04 21 andalusite 5.00 1.76 -3.24 -0.324 0.55266E+04 24 anhydrite -5.32 -9.26 -3.94 -1.971 0.67323E+04 29 anorthite 12.71 8.39 -4.32 -0.332 0.73793E+04 35 aragonite 0.97 -1.93 -2.90 -0.965 0.49453E+04 36 brucite 12.57 8.83 -3.73 -0.747 0.63763E+04 37 calcite 0.81 -1.93 -2.74 -0.914 0.46811E+04 40 carpholite-Mg 8.58 6.62 -1.97 -0.131 0.33563E+04 41 carpholite-Fe 6.71 4.41 -2.30 -0.154 0.39326E+04 50 chloritoid-Mg 13.20 10.60 -2.60 -0.173 0.44372E+04 51 chloritoid-Fe 9.17 8.39 -0.78 -0.052 0.13345E+04 52 chloritoid-Mn 11.40 10.02 -1.39 -0.092 0.23659E+04 54 coesite -2.38 -3.98 -1.61 -0.536 0.27431E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.98 -1.42 -0.474 0.24285E+04 67 diopside 16.18 11.48 -4.71 -0.471 0.80353E+04 68 hedenbergite 14.21 9.27 -4.94 -0.494 0.84346E+04 75 epidote 24.67 21.30 -3.37 -0.164 0.57618E+04 76 clinozoisite 22.81 17.89 -4.92 -0.224 0.84007E+04 78 fayalite 14.05 9.27 -4.77 -0.682 0.81511E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.92 -4.22 -0.352 0.72104E+04 92 hercynite 17.28 12.37 -4.90 -0.327 0.83732E+04 98 kaolinite -1.33 -2.22 -0.89 -0.080 0.15112E+04 99 kyanite 4.88 1.76 -3.11 -0.311 0.53125E+04 101 laumontite 2.88 0.42 -2.46 -0.164 0.42004E+04 102 lawsonite 9.62 8.39 -1.23 -0.082 0.20959E+04 105 lizardite 23.24 18.54 -4.71 -0.392 0.80360E+04 106 magnesite 0.69 -3.70 -4.39 -1.464 0.75001E+04 107 magnetite 20.09 19.19 -0.89 -0.073 0.15264E+04 110 magnesioferrite 26.21 21.40 -4.81 -0.393 0.82164E+04 113 margarite 17.32 14.14 -3.19 -0.128 0.54428E+04 116 microcline -2.49 -7.10 -4.62 -0.355 0.78849E+04 120 muscovite 2.58 -1.36 -3.94 -0.232 0.67264E+04 121 paragonite 4.24 0.51 -3.73 -0.220 0.63717E+04 128 periclase-Fe 11.63 6.63 -5.00 -1.250 0.85362E+04 136 prehnite 19.37 15.01 -4.36 -0.256 0.74438E+04 137 prehnite-Fe 22.50 18.42 -4.08 -0.245 0.69599E+04 145 pyroxmangite 7.40 4.27 -3.13 -0.626 0.53454E+04 146 pyrophyllite -6.18 -10.18 -4.01 -0.250 0.68421E+04 147 quartz -2.99 -3.98 -0.99 -0.331 0.16958E+04 151 rhodochrosite -0.98 -4.29 -3.31 -1.103 0.56503E+04 152 rhodonite 7.45 4.27 -3.18 -0.636 0.54257E+04 155 siderite -2.61 -5.91 -3.30 -1.100 0.56359E+04 156 sillimanite 5.26 1.76 -3.50 -0.350 0.59706E+04 163 stilbite -7.52 -11.52 -4.00 -0.191 0.68339E+04 168 sudoite 21.08 17.22 -3.86 -0.125 0.65941E+04 177 topaz-H 4.62 1.76 -2.85 -0.259 0.48726E+04 178 tridymite -2.63 -3.98 -1.36 -0.452 0.23158E+04 187 wairakite 3.95 0.42 -3.53 -0.207 0.60224E+04 188 walstromite 11.51 6.62 -4.89 -0.977 0.83418E+04 189 wollastonite 10.46 6.62 -3.84 -0.767 0.65522E+04 190 pseudo-wollastonite 11.00 6.62 -4.38 -0.875 0.74720E+04 191 zoisite 22.85 17.89 -4.96 -0.226 0.84748E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -6.17 -4.52 -0.280 0.77259E+04 196 beidellite-Mg -1.79 -6.46 -4.67 -0.289 0.79790E+04 199 chalcedony -2.80 -3.98 -1.18 -0.393 0.20151E+04 201 montmorillonite-Ca -2.29 -6.47 -4.18 -0.258 0.71291E+04 203 montmorillonite-Mg -2.48 -6.76 -4.28 -0.265 0.73054E+04 204 montmorillonite-Na -2.04 -6.95 -4.91 -0.301 0.83885E+04 205 nontronite-Ca 3.21 0.65 -2.57 -0.166 0.43815E+04 206 nontronite-H 2.53 -1.10 -3.63 -0.244 0.62055E+04 207 nontronite-K 3.34 -0.45 -3.79 -0.243 0.64753E+04 208 nontronite-Mg 3.07 0.36 -2.72 -0.176 0.46419E+04 209 nontronite-Na 3.52 0.16 -3.36 -0.215 0.57302E+04 214 gypsum -4.96 -9.26 -4.30 -1.076 0.73498E+04 224 tobermorite 9.82 4.85 -4.97 -1.356 0.84871E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.63 -3.18 -0.796 0.54371E+04 240 silica-amorphous -2.09 -3.98 -1.89 -0.630 0.32293E+04 242 an20ab80 2.02 -2.51 -4.53 -0.349 0.77378E+04 243 an25ab75 2.65 -1.83 -4.48 -0.344 0.76465E+04 244 an30ab70 3.28 -1.15 -4.43 -0.341 0.75648E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0112000 g New total amount of reactant added: 0.0116000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0116000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2806405E-03 Osmotic coef. = 0.9900 True ionic strength = .2864584E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.24502E-07 -7.6108 0.23530E-07 -7.6284 0.96032E+00 -0.0176 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13247E-03 -3.8779 0.96020E+00 -0.0176 4 SO4-- 0.25325E-04 -4.5965 0.22718E-04 -4.6436 0.89707E+00 -0.0472 5 HCO3- 0.12400E-04 -4.9066 0.11907E-04 -4.9242 0.96023E+00 -0.0176 6 HS- 0.26005E-09 -9.5850 0.24970E-09 -9.6026 0.96020E+00 -0.0176 7 Al+++ 0.12165E-19 -19.9149 0.97397E-20 -20.0115 0.80063E+00 -0.0966 8 H4SiO4 0.10760E-03 -3.9682 0.10760E-03 -3.9682 0.10000E+01 0.0000 9 Ca++ 0.27422E-04 -4.5619 0.24595E-04 -4.6091 0.89694E+00 -0.0472 10 Mg++ 0.41400E-06 -6.3830 0.37130E-06 -6.4303 0.89685E+00 -0.0473 11 Fe++ 0.25543E-08 -8.5927 0.22909E-08 -8.6400 0.89687E+00 -0.0473 12 K+ 0.24619E-05 -5.6087 0.23640E-05 -5.6263 0.96023E+00 -0.0176 13 Na+ 0.17461E-03 -3.7579 0.16766E-03 -3.7756 0.96019E+00 -0.0176 14 Mn++ 0.11741E-06 -6.9303 0.10530E-06 -6.9776 0.89689E+00 -0.0473 15 HPO4-- 0.32117E-08 -8.4933 0.28812E-08 -8.5404 0.89708E+00 -0.0472 16 HSiO3- 0.44471E-05 -5.3519 0.42701E-05 -5.3696 0.96020E+00 -0.0176 17 Ca(HSiO3)+ 0.24908E-08 -8.6037 0.23918E-08 -8.6213 0.96023E+00 -0.0176 18 Mg(HSiO3)+ 0.46797E-10 -10.3298 0.44936E-10 -10.3474 0.96023E+00 -0.0176 19 NaHSiO3,aq 0.11579E-07 -7.9363 0.11579E-07 -7.9363 0.10000E+01 0.0000 20 AlO+ 0.24924E-11 -11.6034 0.23933E-11 -11.6210 0.96023E+00 -0.0176 21 AlOH+2 0.31263E-15 -15.5050 0.28040E-15 -15.5522 0.89690E+00 -0.0473 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.19847E-05 -5.7023 0.19056E-05 -5.7200 0.96016E+00 -0.0177 24 CH4,aq 0.12714E-15 -15.8957 0.12713E-15 -15.8958 0.99991E+00 0.0000 29 CO,aq 0.26641E-16 -16.5744 0.26641E-16 -16.5744 0.10000E+01 0.0000 30 CO2,aq 0.59872E-06 -6.2228 0.59867E-06 -6.2228 0.99991E+00 0.0000 31 CO3-2 0.49275E-07 -7.3074 0.44202E-07 -7.3546 0.89703E+00 -0.0472 32 CaCO3,aq 0.13632E-07 -7.8654 0.13632E-07 -7.8654 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.77852E-08 -8.1087 0.74756E-08 -8.1264 0.96023E+00 -0.0176 34 CaCl+ 0.54911E-08 -8.2603 0.52727E-08 -8.2780 0.96023E+00 -0.0176 35 CaCl2,aq 0.16594E-12 -12.7800 0.16594E-12 -12.7800 0.10000E+01 0.0000 36 CaOH+ 0.77582E-07 -7.1102 0.74497E-07 -7.1279 0.96023E+00 -0.0176 37 CaSO4,aq 0.17743E-06 -6.7510 0.17743E-06 -6.7510 0.10000E+01 0.0000 38 HCl,aq 0.57117E-12 -12.2432 0.57117E-12 -12.2432 0.10000E+01 0.0000 43 FeCl+ 0.50024E-12 -12.3008 0.48035E-12 -12.3184 0.96023E+00 -0.0176 46 FeO,aq 0.16082E-09 -9.7937 0.16082E-09 -9.7937 0.10000E+01 0.0000 47 FeOH+ 0.33004E-08 -8.4814 0.31692E-08 -8.4991 0.96023E+00 -0.0176 48 HFeO2- 0.74476E-10 -10.1280 0.71512E-10 -10.1456 0.96020E+00 -0.0176 49 FeO+ 0.18704E-12 -12.7281 0.17960E-12 -12.7457 0.96023E+00 -0.0176 50 FeOH+2 0.89979E-18 -18.0459 0.80703E-18 -18.0931 0.89690E+00 -0.0473 51 FeO2- 0.69129E-10 -10.1603 0.66378E-10 -10.1780 0.96020E+00 -0.0176 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.17716E-08 -8.7516 0.17715E-08 -8.7517 0.99991E+00 0.0000 54 KCl,aq 0.56758E-11 -11.2460 0.56758E-11 -11.2460 0.10000E+01 0.0000 55 KHSO4,aq 0.35730E-17 -17.4470 0.35730E-17 -17.4470 0.10000E+01 0.0000 56 KOH,aq 0.42906E-10 -10.3675 0.42906E-10 -10.3675 0.10000E+01 0.0000 57 KSO4- 0.86794E-09 -9.0615 0.83339E-09 -9.0791 0.96020E+00 -0.0176 58 MgCO3,aq 0.51582E-10 -10.2875 0.51582E-10 -10.2875 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12009E-09 -9.9205 0.11532E-09 -9.9381 0.96023E+00 -0.0176 60 MgCl+ 0.75131E-10 -10.1242 0.72144E-10 -10.1418 0.96023E+00 -0.0176 61 MgOH+ 0.64809E-08 -8.1884 0.62232E-08 -8.2060 0.96023E+00 -0.0176 63 MnO,aq 0.19696E-09 -9.7056 0.19696E-09 -9.7056 0.10000E+01 0.0000 64 MnOH+ 0.14093E-07 -7.8510 0.13532E-07 -7.8686 0.96023E+00 -0.0176 65 MnO2-2 0.13162E-16 -16.8807 0.11807E-16 -16.9279 0.89703E+00 -0.0472 66 HMnO2- 0.63386E-13 -13.1980 0.60863E-13 -13.2156 0.96020E+00 -0.0176 69 MnCl+ 0.89454E-10 -10.0484 0.85897E-10 -10.0660 0.96023E+00 -0.0176 70 MnSO4,aq 0.69061E-09 -9.1608 0.69061E-09 -9.1608 0.10000E+01 0.0000 71 NaCl,aq 0.73604E-08 -8.1331 0.73604E-08 -8.1331 0.10000E+01 0.0000 72 NaOH,aq 0.30614E-08 -8.5141 0.30614E-08 -8.5141 0.10000E+01 0.0000 74 OH- 0.25574E-04 -4.5922 0.24555E-04 -4.6099 0.96016E+00 -0.0177 79 HPO3-2 0.17731E-19 -19.7513 0.15906E-19 -19.7984 0.89703E+00 -0.0472 82 H3PO4,aq 0.11156E-13 -13.9525 0.11156E-13 -13.9525 0.10000E+01 0.0000 83 H2PO4- 0.13024E-08 -8.8853 0.12506E-08 -8.9029 0.96021E+00 -0.0176 84 PO4-3 0.12465E-12 -12.9043 0.99905E-13 -13.0004 0.80148E+00 -0.0961 87 H2P2O7-2 0.13671E-18 -18.8642 0.12263E-18 -18.9114 0.89703E+00 -0.0472 88 HP2O7-3 0.12998E-17 -17.8861 0.10407E-17 -17.9827 0.80064E+00 -0.0966 89 P2O7-4 0.15463E-19 -19.8107 0.10566E-19 -19.9761 0.68329E+00 -0.1654 90 H2S,aq 0.18160E-10 -10.7409 0.18158E-10 -10.7409 0.99991E+00 0.0000 96 SO2,aq 0.99508E-19 -19.0021 0.99508E-19 -19.0021 0.10000E+01 0.0000 97 SO3-2 0.58283E-14 -14.2345 0.52298E-14 -14.2815 0.89731E+00 -0.0471 98 HSO3- 0.80242E-14 -14.0956 0.77048E-14 -14.1132 0.96020E+00 -0.0176 99 HSO4- 0.53648E-09 -9.2704 0.51516E-09 -9.2881 0.96025E+00 -0.0176 101 S2O3-2 0.54020E-17 -17.2674 0.48458E-17 -17.3146 0.89703E+00 -0.0472 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2450195E-07 -.3757898E-04 -.3787651E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999758E+06 0.0000 3 Cl- 0.1379618E-03 0.1379748E-03 0.4891511E+01 3.7505 4 SO4-- 0.2532478E-04 0.2550390E-04 0.2449890E+01 10.6131 5 HCO3- 0.1240048E-04 0.1307006E-04 0.7974805E+00 2.7042 6 HS- 0.2600454E-09 0.6876243E-09 0.2274060E-04 -1.9742 7 Al+++ 0.1216493E-19 0.2004915E-05 0.5409440E-01 2.8737 8 H4SiO4 0.1076027E-03 0.1120639E-03 0.1077083E+02 -3.9682 9 Ca++ 0.2742154E-04 0.2770596E-04 0.1110374E+01 10.6476 10 Mg++ 0.4140042E-06 0.4207787E-06 0.1022974E-01 8.8265 11 Fe++ 0.2554293E-08 0.6358485E-08 0.3550944E-03 6.6168 12 K+ 0.2461940E-05 0.2462856E-05 0.9630044E-01 2.0020 13 Na+ 0.1746106E-03 0.1746326E-03 0.4014679E+01 3.8528 14 Mn++ 0.1174055E-06 0.1324754E-06 0.7277771E-02 8.2792 15 HPO4-- 0.3211738E-08 0.4514290E-08 0.4332674E-03 6.7163 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1790388E-03 -.3757881E-04 -.1414600E-03 0.0000000E+00 2 H2O 0.5550810E+02 0.5550802E+02 0.8005466E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2582595E-04 0.2550378E-04 0.3221632E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3214755E-06 0.6876212E-09 -.3221632E-06 0.0000000E+00 7 Al+++ 0.3782460E-04 0.2004906E-05 0.3581970E-04 0.0000000E+00 8 H4SiO4 0.1207883E-03 0.1120634E-03 0.8724877E-05 0.0000000E+00 9 Ca++ 0.2781271E-04 0.2770583E-04 0.1068827E-06 0.0000000E+00 10 Mg++ 0.9206349E-05 0.4207768E-06 0.8785572E-05 0.0000000E+00 11 Fe++ 0.8270900E-05 0.6358457E-08 0.8264541E-05 0.0000000E+00 12 K+ 0.2462845E-05 0.2462845E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1746318E-03 0.1746318E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2011277E-06 0.1324748E-06 0.6865291E-07 0.0000000E+00 15 HPO4-- 0.6864389E-07 0.4514270E-08 0.6412962E-07 0.0000000E+00 Chg. balance for solid moles: -.2753E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0116000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2138E-07 -7.670 0.1074E-04 -4.969 0.2815 0.3412E-05 clinochlore 0.1757E-05 -5.755 0.9767E-03 -3.010 25.60 0.3715E-03 daphnite 0.1137E-05 -5.944 0.8116E-03 -3.091 21.28 0.2459E-03 chlorite-Mn 0.1373E-07 -7.862 0.9735E-05 -5.012 0.2552 0.3102E-05 diaspore 0.3000E-04 -4.523 0.1800E-02 -2.745 47.19 0.5358E-03 hematite 0.1289E-05 -5.890 0.2058E-03 -3.687 5.395 0.3901E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6042E+00 0.6042E+00 1.0000 -0.219 daphnite 0.3911E+00 0.3911E+00 1.0000 -0.408 chlorite-Mn 0.4721E-02 0.4721E-02 1.0000 -2.326 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003814 g Volume = 0.001199 cm3 Porosity: 99.8807% V(tot) - V(min): 0.10034E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0116000 g log = -1.9355 Original solution: 1000.0103000 g Original solution / Rock added: 86207.78 (Water/Rock Ratio), log = 4.9355 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.6233E-04 1.0071 0.6405E-04 0.6360E-04 CH4,gas 0.1811E-12 1.0125 0.1871E-12 0.1848E-12 H2,gas 0.2278E-05 1.0005 0.2326E-05 0.2324E-05 H2S,gas 0.4911E-09 0.9960 0.4992E-09 0.5011E-09 S2,gas 0.1694E-26 1.0000 0.1729E-26 0.1729E-26 CO,gas 0.3891E-13 1.0000 0.3970E-13 0.3970E-13 SO3,gas 0.4661E-35 1.0000 0.4756E-35 0.4756E-35 SO2,gas 0.4217E-18 1.0000 0.4303E-18 0.4303E-18 HCl,gas 0.9877E-15 1.0000 0.1008E-14 0.1008E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.55 -5.89 -1.964 0.10061E+05 -4.193 3 CH4,gas 4.54 -9.88 -14.43 -3.607 0.24633E+05 -12.728 4 H2,gas 8.00 0.67 -7.33 -4.190 0.12520E+05 -5.633 5 H2S,gas -6.23 -17.23 -11.00 -5.500 0.18783E+05 -9.302 6 S2,gas -7.34 -35.80 -28.46 -4.379 0.48597E+05 -26.762 7 CO,gas 3.21 -11.89 -15.10 -4.646 0.25783E+05 -13.401 8 SO3,gas 17.12 -19.90 -37.02 -9.255 0.63214E+05 -35.323 9 SO2,gas 0.83 -19.23 -20.07 -5.351 0.34261E+05 -18.366 10 HCl,gas 5.19 -11.51 -16.70 -8.348 0.28507E+05 -14.997 16 albite -0.38 -5.18 -4.79 -0.369 0.81859E+04 20 analcite 3.32 -1.21 -4.53 -0.504 0.77378E+04 21 andalusite 5.00 1.78 -3.22 -0.322 0.55020E+04 24 anhydrite -5.32 -9.25 -3.94 -1.968 0.67206E+04 29 anorthite 12.71 8.46 -4.25 -0.327 0.72596E+04 35 aragonite 0.97 -1.90 -2.87 -0.957 0.49030E+04 36 brucite 12.57 8.83 -3.74 -0.748 0.63895E+04 37 calcite 0.81 -1.90 -2.72 -0.906 0.46387E+04 40 carpholite-Mg 8.58 6.64 -1.94 -0.130 0.33203E+04 41 carpholite-Fe 6.71 4.43 -2.28 -0.152 0.39013E+04 50 chloritoid-Mg 13.20 10.61 -2.59 -0.173 0.44258E+04 51 chloritoid-Fe 9.17 8.40 -0.78 -0.052 0.13278E+04 52 chloritoid-Mn 11.40 10.06 -1.34 -0.090 0.22926E+04 54 coesite -2.38 -3.97 -1.59 -0.531 0.27185E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.97 -1.41 -0.469 0.24038E+04 67 diopside 16.18 11.54 -4.64 -0.464 0.79288E+04 68 hedenbergite 14.21 9.33 -4.88 -0.488 0.83329E+04 75 epidote 24.67 21.42 -3.25 -0.158 0.55471E+04 76 clinozoisite 22.81 18.01 -4.79 -0.218 0.81860E+04 78 fayalite 14.05 9.27 -4.78 -0.683 0.81624E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.352 0.72150E+04 92 hercynite 17.28 12.36 -4.91 -0.328 0.83912E+04 98 kaolinite -1.33 -2.19 -0.86 -0.078 0.14619E+04 99 kyanite 4.88 1.78 -3.10 -0.310 0.52879E+04 101 laumontite 2.88 0.52 -2.36 -0.157 0.40315E+04 102 lawsonite 9.62 8.46 -1.16 -0.077 0.19762E+04 105 lizardite 23.24 18.54 -4.70 -0.392 0.80264E+04 106 magnesite 0.69 -3.73 -4.42 -1.472 0.75414E+04 107 magnetite 20.09 19.18 -0.90 -0.074 0.15443E+04 110 magnesioferrite 26.21 21.39 -4.82 -0.393 0.82295E+04 113 margarite 17.32 14.21 -3.12 -0.125 0.53231E+04 116 microcline -2.49 -7.03 -4.54 -0.349 0.77559E+04 120 muscovite 2.58 -1.28 -3.86 -0.227 0.65974E+04 121 paragonite 4.24 0.57 -3.67 -0.216 0.62665E+04 136 prehnite 19.37 15.14 -4.23 -0.249 0.72291E+04 137 prehnite-Fe 22.50 18.55 -3.95 -0.238 0.67451E+04 145 pyroxmangite 7.40 4.31 -3.09 -0.618 0.52721E+04 146 pyrophyllite -6.18 -10.13 -3.95 -0.247 0.67437E+04 147 quartz -2.99 -3.97 -0.98 -0.326 0.16712E+04 151 rhodochrosite -0.98 -4.27 -3.30 -1.099 0.56296E+04 152 rhodonite 7.45 4.31 -3.13 -0.627 0.53523E+04 155 siderite -2.61 -5.94 -3.33 -1.109 0.56819E+04 156 sillimanite 5.26 1.78 -3.48 -0.348 0.59459E+04 163 stilbite -7.52 -11.38 -3.86 -0.184 0.65911E+04 164 stilpnomelane-Fe 13.02 8.09 -4.93 -0.147 0.84181E+04 168 sudoite 21.08 17.24 -3.83 -0.124 0.65466E+04 177 topaz-H 4.62 1.78 -2.84 -0.258 0.48480E+04 178 tridymite -2.63 -3.97 -1.34 -0.447 0.22912E+04 187 wairakite 3.95 0.52 -3.43 -0.202 0.58535E+04 188 walstromite 11.51 6.68 -4.83 -0.966 0.82467E+04 189 wollastonite 10.46 6.68 -3.78 -0.756 0.64572E+04 190 pseudo-wollastonite 11.00 6.68 -4.32 -0.864 0.73770E+04 191 zoisite 22.85 18.01 -4.84 -0.220 0.82601E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -6.11 -4.47 -0.276 0.76239E+04 196 beidellite-Mg -1.79 -6.41 -4.62 -0.286 0.78908E+04 199 chalcedony -2.80 -3.97 -1.17 -0.389 0.19905E+04 201 montmorillonite-Ca -2.29 -6.40 -4.11 -0.254 0.70234E+04 203 montmorillonite-Mg -2.48 -6.70 -4.22 -0.261 0.72135E+04 204 montmorillonite-Na -2.04 -6.89 -4.85 -0.297 0.82841E+04 205 nontronite-Ca 3.21 0.71 -2.51 -0.163 0.42796E+04 206 nontronite-H 2.53 -1.05 -3.58 -0.240 0.61152E+04 207 nontronite-K 3.34 -0.39 -3.73 -0.239 0.63667E+04 208 nontronite-Mg 3.07 0.41 -2.67 -0.173 0.45538E+04 209 nontronite-Na 3.52 0.22 -3.30 -0.212 0.56295E+04 214 gypsum -4.96 -9.25 -4.30 -1.074 0.73381E+04 224 tobermorite 9.82 4.90 -4.92 -1.343 0.84038E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.62 -3.19 -0.799 0.54551E+04 240 silica-amorphous -2.09 -3.97 -1.88 -0.626 0.32047E+04 242 an20ab80 2.02 -2.45 -4.47 -0.344 0.76298E+04 243 an25ab75 2.65 -1.77 -4.41 -0.340 0.75377E+04 244 an30ab70 3.28 -1.09 -4.37 -0.336 0.74553E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0116000 g New total amount of reactant added: 0.0120000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0120000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2821119E-03 Osmotic coef. = 0.9899 True ionic strength = .2882719E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.23592E-07 -7.6272 0.22654E-07 -7.6449 0.96025E+00 -0.0176 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13246E-03 -3.8779 0.96013E+00 -0.0177 4 SO4-- 0.25322E-04 -4.5965 0.22709E-04 -4.6438 0.89682E+00 -0.0473 5 HCO3- 0.12419E-04 -4.9059 0.11924E-04 -4.9236 0.96016E+00 -0.0177 6 HS- 0.20836E-09 -9.6812 0.20006E-09 -9.6988 0.96013E+00 -0.0177 7 Al+++ 0.10864E-19 -19.9640 0.86924E-20 -20.0609 0.80013E+00 -0.0968 8 H4SiO4 0.11111E-03 -3.9543 0.11111E-03 -3.9543 0.10000E+01 0.0000 9 Ca++ 0.27869E-04 -4.5549 0.24989E-04 -4.6022 0.89668E+00 -0.0474 10 Mg++ 0.37722E-06 -6.4234 0.33821E-06 -6.4708 0.89660E+00 -0.0474 11 Fe++ 0.23147E-08 -8.6355 0.20754E-08 -8.6829 0.89662E+00 -0.0474 12 K+ 0.25468E-05 -5.5940 0.24454E-05 -5.6117 0.96016E+00 -0.0177 13 Na+ 0.17511E-03 -3.7567 0.16813E-03 -3.7744 0.96013E+00 -0.0177 14 Mn++ 0.11554E-06 -6.9373 0.10360E-06 -6.9846 0.89663E+00 -0.0474 15 HPO4-- 0.29744E-08 -8.5266 0.26675E-08 -8.5739 0.89683E+00 -0.0473 16 HSiO3- 0.47697E-05 -5.3215 0.45796E-05 -5.3392 0.96013E+00 -0.0177 17 Ca(HSiO3)+ 0.27144E-08 -8.5663 0.26062E-08 -8.5840 0.96017E+00 -0.0177 18 Mg(HSiO3)+ 0.45719E-10 -10.3399 0.43898E-10 -10.3576 0.96017E+00 -0.0177 19 NaHSiO3,aq 0.12453E-07 -7.9047 0.12453E-07 -7.9047 0.10000E+01 0.0000 20 AlO+ 0.23998E-11 -11.6198 0.23042E-11 -11.6375 0.96017E+00 -0.0177 21 AlOH+2 0.28988E-15 -15.5378 0.25992E-15 -15.5852 0.89665E+00 -0.0474 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.20615E-05 -5.6858 0.19792E-05 -5.7035 0.96009E+00 -0.0177 24 CH4,aq 0.10205E-15 -15.9912 0.10204E-15 -15.9912 0.99991E+00 0.0000 29 CO,aq 0.24536E-16 -16.6102 0.24536E-16 -16.6102 0.10000E+01 0.0000 30 CO2,aq 0.57726E-06 -6.2386 0.57721E-06 -6.2387 0.99991E+00 0.0000 31 CO3-2 0.51267E-07 -7.2902 0.45976E-07 -7.3375 0.89678E+00 -0.0473 32 CaCO3,aq 0.14406E-07 -7.8415 0.14406E-07 -7.8415 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.79218E-08 -8.1012 0.76063E-08 -8.1188 0.96017E+00 -0.0177 34 CaCl+ 0.55791E-08 -8.2534 0.53568E-08 -8.2711 0.96017E+00 -0.0177 35 CaCl2,aq 0.16858E-12 -12.7732 0.16858E-12 -12.7732 0.10000E+01 0.0000 36 CaOH+ 0.81878E-07 -7.0868 0.78616E-07 -7.1045 0.96017E+00 -0.0177 37 CaSO4,aq 0.18021E-06 -6.7442 0.18021E-06 -6.7442 0.10000E+01 0.0000 38 HCl,aq 0.54988E-12 -12.2597 0.54988E-12 -12.2597 0.10000E+01 0.0000 43 FeCl+ 0.45320E-12 -12.3437 0.43514E-12 -12.3614 0.96017E+00 -0.0177 46 FeO,aq 0.15717E-09 -9.8036 0.15717E-09 -9.8036 0.10000E+01 0.0000 47 FeOH+ 0.31059E-08 -8.5078 0.29821E-08 -8.5255 0.96017E+00 -0.0177 48 HFeO2- 0.75608E-10 -10.1214 0.72593E-10 -10.1391 0.96013E+00 -0.0177 49 FeO+ 0.18009E-12 -12.7445 0.17292E-12 -12.7622 0.96017E+00 -0.0177 50 FeOH+2 0.83431E-18 -18.0787 0.74808E-18 -18.1260 0.89665E+00 -0.0474 51 FeO2- 0.71806E-10 -10.1438 0.68943E-10 -10.1615 0.96013E+00 -0.0177 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.16923E-08 -8.7715 0.16921E-08 -8.7716 0.99991E+00 0.0000 54 KCl,aq 0.58707E-11 -11.2313 0.58707E-11 -11.2313 0.10000E+01 0.0000 55 KHSO4,aq 0.35570E-17 -17.4489 0.35570E-17 -17.4489 0.10000E+01 0.0000 56 KOH,aq 0.46098E-10 -10.3363 0.46098E-10 -10.3363 0.10000E+01 0.0000 57 KSO4- 0.89752E-09 -9.0470 0.86174E-09 -9.0646 0.96013E+00 -0.0177 58 MgCO3,aq 0.48871E-10 -10.3109 0.48871E-10 -10.3109 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10955E-09 -9.9604 0.10519E-09 -9.9780 0.96017E+00 -0.0177 60 MgCl+ 0.68436E-10 -10.1647 0.65710E-10 -10.1824 0.96017E+00 -0.0177 61 MgOH+ 0.61319E-08 -8.2124 0.58877E-08 -8.2301 0.96017E+00 -0.0177 63 MnO,aq 0.20905E-09 -9.6798 0.20905E-09 -9.6798 0.10000E+01 0.0000 64 MnOH+ 0.14402E-07 -7.8416 0.13828E-07 -7.8592 0.96017E+00 -0.0177 65 MnO2-2 0.15074E-16 -16.8218 0.13518E-16 -16.8691 0.89678E+00 -0.0473 66 HMnO2- 0.69880E-13 -13.1556 0.67094E-13 -13.1733 0.96013E+00 -0.0177 69 MnCl+ 0.88009E-10 -10.0555 0.84503E-10 -10.0731 0.96017E+00 -0.0177 70 MnSO4,aq 0.67919E-09 -9.1680 0.67919E-09 -9.1680 0.10000E+01 0.0000 71 NaCl,aq 0.73805E-08 -8.1319 0.73805E-08 -8.1319 0.10000E+01 0.0000 72 NaOH,aq 0.31887E-08 -8.4964 0.31887E-08 -8.4964 0.10000E+01 0.0000 74 OH- 0.26564E-04 -4.5757 0.25504E-04 -4.5934 0.96009E+00 -0.0177 79 HPO3-2 0.15685E-19 -19.8045 0.14066E-19 -19.8518 0.89678E+00 -0.0473 82 H3PO4,aq 0.95746E-14 -14.0189 0.95746E-14 -14.0189 0.10000E+01 0.0000 83 H2PO4- 0.11610E-08 -8.9352 0.11148E-08 -8.9528 0.96015E+00 -0.0177 84 PO4-3 0.11994E-12 -12.9210 0.96071E-13 -13.0174 0.80098E+00 -0.0964 87 H2P2O7-2 0.10866E-18 -18.9639 0.97441E-19 -19.0113 0.89678E+00 -0.0473 88 HP2O7-3 0.10734E-17 -17.9692 0.85886E-18 -18.0661 0.80014E+00 -0.0968 89 P2O7-4 0.13270E-19 -19.8771 0.90570E-20 -20.0430 0.68253E+00 -0.1659 90 H2S,aq 0.14008E-10 -10.8536 0.14007E-10 -10.8537 0.99991E+00 0.0000 96 SO2,aq 0.88074E-19 -19.0552 0.88074E-19 -19.0552 0.10000E+01 0.0000 97 SO3-2 0.55666E-14 -14.2544 0.49936E-14 -14.3016 0.89706E+00 -0.0472 98 HSO3- 0.73772E-14 -14.1321 0.70831E-14 -14.1498 0.96013E+00 -0.0177 99 HSO4- 0.51635E-09 -9.2871 0.49580E-09 -9.3047 0.96019E+00 -0.0176 101 S2O3-2 0.41666E-17 -17.3802 0.37366E-17 -17.4275 0.89678E+00 -0.0473 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2359186E-07 -.3922992E-04 -.3954050E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999754E+06 0.0000 3 Cl- 0.1379617E-03 0.1379748E-03 0.4891510E+01 3.7669 4 SO4-- 0.2532207E-04 0.2550398E-04 0.2449897E+01 10.6459 5 HCO3- 0.1241905E-04 0.1307006E-04 0.7974803E+00 2.7213 6 HS- 0.2083645E-09 0.6116166E-09 0.2022692E-04 -2.0540 7 Al+++ 0.1086369E-19 0.2081765E-05 0.5616786E-01 2.8737 8 H4SiO4 0.1111077E-03 0.1158927E-03 0.1113881E+02 -3.9543 9 Ca++ 0.2786874E-04 0.2816144E-04 0.1128629E+01 10.6875 10 Mg++ 0.3772174E-06 0.3836219E-06 0.9326403E-02 8.8189 11 Fe++ 0.2314743E-08 0.5924461E-08 0.3308558E-03 6.6068 12 K+ 0.2546833E-05 0.2547783E-05 0.9962112E-01 2.0332 13 Na+ 0.1751117E-03 0.1751347E-03 0.4026221E+01 3.8705 14 Mn++ 0.1155410E-06 0.1309193E-06 0.7192280E-02 8.3051 15 HPO4-- 0.2974384E-08 0.4135554E-08 0.3969173E-03 6.7158 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1856622E-03 -.3922973E-04 -.1464325E-03 0.0000000E+00 2 H2O 0.5550810E+02 0.5550802E+02 0.8282281E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2583703E-04 0.2550386E-04 0.3331725E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3325609E-06 0.6116138E-09 -.3331725E-06 0.0000000E+00 7 Al+++ 0.3912890E-04 0.2081755E-05 0.3704714E-04 0.0000000E+00 8 H4SiO4 0.1249534E-03 0.1158921E-03 0.9061279E-05 0.0000000E+00 9 Ca++ 0.2827277E-04 0.2816131E-04 0.1114590E-06 0.0000000E+00 10 Mg++ 0.9523810E-05 0.3836201E-06 0.9140189E-05 0.0000000E+00 11 Fe++ 0.8556103E-05 0.5924433E-08 0.8550179E-05 0.0000000E+00 12 K+ 0.2547771E-05 0.2547771E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1751339E-03 0.1751339E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2080632E-06 0.1309187E-06 0.7714448E-07 0.0000000E+00 15 HPO4-- 0.7101092E-07 0.4135534E-08 0.6687539E-07 0.0000000E+00 Chg. balance for solid moles: 0.3150E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0120000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2229E-07 -7.652 0.1120E-04 -4.951 0.2834 0.3558E-05 clinochlore 0.1828E-05 -5.738 0.1016E-02 -2.993 25.72 0.3865E-03 daphnite 0.1177E-05 -5.929 0.8398E-03 -3.076 21.26 0.2545E-03 chlorite-Mn 0.1543E-07 -7.812 0.1094E-04 -4.961 0.2769 0.3486E-05 diaspore 0.3101E-04 -4.509 0.1860E-02 -2.730 47.08 0.5538E-03 hematite 0.1333E-05 -5.875 0.2128E-03 -3.672 5.387 0.4034E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6052E+00 0.6052E+00 1.0000 -0.218 daphnite 0.3897E+00 0.3897E+00 1.0000 -0.409 chlorite-Mn 0.5108E-02 0.5108E-02 1.0000 -2.292 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003951 g Volume = 0.001242 cm3 Porosity: 99.8764% V(tot) - V(min): 0.10036E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0120000 g log = -1.9208 Original solution: 1000.0103000 g Original solution / Rock added: 83334.19 (Water/Rock Ratio), log = 4.9208 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.6010E-04 1.0071 0.6176E-04 0.6132E-04 CH4,gas 0.1454E-12 1.0125 0.1502E-12 0.1483E-12 H2,gas 0.2176E-05 1.0005 0.2222E-05 0.2220E-05 H2S,gas 0.3789E-09 0.9960 0.3850E-09 0.3866E-09 S2,gas 0.1105E-26 1.0000 0.1128E-26 0.1128E-26 CO,gas 0.3583E-13 1.0000 0.3656E-13 0.3656E-13 SO3,gas 0.4319E-35 1.0000 0.4407E-35 0.4407E-35 SO2,gas 0.3733E-18 1.0000 0.3809E-18 0.3809E-18 HCl,gas 0.9509E-15 1.0000 0.9703E-15 0.9703E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.57 -5.91 -1.969 0.10088E+05 -4.209 3 CH4,gas 4.54 -9.98 -14.52 -3.631 0.24796E+05 -12.823 4 H2,gas 8.00 0.65 -7.35 -4.201 0.12554E+05 -5.653 5 H2S,gas -6.23 -17.34 -11.11 -5.557 0.18976E+05 -9.414 6 S2,gas -7.34 -35.98 -28.65 -4.407 0.48914E+05 -26.948 7 CO,gas 3.21 -11.92 -15.14 -4.657 0.25844E+05 -13.437 8 SO3,gas 17.12 -19.93 -37.05 -9.264 0.63270E+05 -35.356 9 SO2,gas 0.83 -19.29 -20.12 -5.365 0.34351E+05 -18.419 10 HCl,gas 5.19 -11.52 -16.71 -8.356 0.28535E+05 -15.013 16 albite -0.38 -5.12 -4.73 -0.364 0.80844E+04 20 analcite 3.32 -1.16 -4.49 -0.498 0.76600E+04 21 andalusite 5.00 1.79 -3.21 -0.321 0.54782E+04 24 anhydrite -5.32 -9.25 -3.93 -1.965 0.67091E+04 29 anorthite 12.71 8.53 -4.18 -0.322 0.71440E+04 35 aragonite 0.97 -1.88 -2.85 -0.949 0.48620E+04 36 brucite 12.57 8.82 -3.75 -0.750 0.64025E+04 37 calcite 0.81 -1.88 -2.69 -0.898 0.45978E+04 40 carpholite-Mg 8.58 6.66 -1.92 -0.128 0.32857E+04 41 carpholite-Fe 6.71 4.45 -2.27 -0.151 0.38707E+04 50 chloritoid-Mg 13.20 10.61 -2.59 -0.172 0.44150E+04 51 chloritoid-Fe 9.17 8.40 -0.77 -0.052 0.13210E+04 52 chloritoid-Mn 11.40 10.10 -1.30 -0.087 0.22246E+04 54 coesite -2.38 -3.95 -1.58 -0.526 0.26947E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.95 -1.39 -0.465 0.23801E+04 67 diopside 16.18 11.60 -4.58 -0.458 0.78262E+04 68 hedenbergite 14.21 9.39 -4.82 -0.482 0.82343E+04 75 epidote 24.67 21.54 -3.13 -0.152 0.53397E+04 76 clinozoisite 22.81 18.13 -4.67 -0.212 0.79786E+04 77 epidote-Fe 29.84 24.95 -4.89 -0.254 0.83474E+04 78 fayalite 14.05 9.26 -4.79 -0.684 0.81726E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.352 0.72185E+04 92 hercynite 17.28 12.35 -4.92 -0.328 0.84082E+04 98 kaolinite -1.33 -2.16 -0.83 -0.075 0.14144E+04 99 kyanite 4.88 1.79 -3.08 -0.308 0.52641E+04 101 laumontite 2.88 0.62 -2.27 -0.151 0.38684E+04 102 lawsonite 9.62 8.53 -1.09 -0.073 0.18607E+04 105 lizardite 23.24 18.55 -4.70 -0.391 0.80177E+04 106 magnesite 0.69 -3.75 -4.44 -1.480 0.75814E+04 107 magnetite 20.09 19.17 -0.91 -0.075 0.15613E+04 110 magnesioferrite 26.21 21.39 -4.83 -0.394 0.82425E+04 113 margarite 17.32 14.27 -3.05 -0.122 0.52076E+04 116 microcline -2.49 -6.96 -4.47 -0.344 0.76313E+04 120 muscovite 2.58 -1.21 -3.79 -0.223 0.64729E+04 121 paragonite 4.24 0.63 -3.61 -0.212 0.61650E+04 136 prehnite 19.37 15.26 -4.11 -0.242 0.70217E+04 137 prehnite-Fe 22.50 18.67 -3.83 -0.230 0.65378E+04 145 pyroxmangite 7.40 4.35 -3.05 -0.610 0.52042E+04 146 pyrophyllite -6.18 -10.07 -3.89 -0.243 0.66486E+04 147 quartz -2.99 -3.95 -0.96 -0.322 0.16474E+04 151 rhodochrosite -0.98 -4.26 -3.29 -1.096 0.56125E+04 152 rhodonite 7.45 4.35 -3.09 -0.619 0.52844E+04 155 siderite -2.61 -5.96 -3.35 -1.118 0.57259E+04 156 sillimanite 5.26 1.79 -3.47 -0.347 0.59222E+04 163 stilbite -7.52 -11.24 -3.72 -0.177 0.63567E+04 164 stilpnomelane-Fe 13.02 8.16 -4.85 -0.145 0.82863E+04 168 sudoite 21.08 17.27 -3.81 -0.123 0.65013E+04 177 topaz-H 4.62 1.79 -2.83 -0.257 0.48242E+04 178 tridymite -2.63 -3.95 -1.33 -0.443 0.22674E+04 187 wairakite 3.95 0.62 -3.33 -0.196 0.56904E+04 188 walstromite 11.51 6.73 -4.78 -0.955 0.81549E+04 189 wollastonite 10.46 6.73 -3.73 -0.746 0.63654E+04 190 pseudo-wollastonite 11.00 6.73 -4.27 -0.853 0.72852E+04 191 zoisite 22.85 18.13 -4.72 -0.214 0.80527E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -6.05 -4.41 -0.273 0.75255E+04 196 beidellite-Mg -1.79 -6.36 -4.57 -0.283 0.78057E+04 199 chalcedony -2.80 -3.95 -1.15 -0.384 0.19667E+04 201 montmorillonite-Ca -2.29 -6.34 -4.05 -0.251 0.69214E+04 203 montmorillonite-Mg -2.48 -6.65 -4.17 -0.258 0.71248E+04 204 montmorillonite-Na -2.04 -6.83 -4.79 -0.293 0.81833E+04 205 nontronite-Ca 3.21 0.77 -2.45 -0.159 0.41811E+04 206 nontronite-H 2.53 -1.00 -3.53 -0.237 0.60279E+04 207 nontronite-K 3.34 -0.33 -3.67 -0.235 0.62619E+04 208 nontronite-Mg 3.07 0.46 -2.62 -0.170 0.44687E+04 209 nontronite-Na 3.52 0.28 -3.24 -0.208 0.55323E+04 214 gypsum -4.96 -9.25 -4.29 -1.073 0.73266E+04 224 tobermorite 9.82 4.95 -4.87 -1.330 0.83233E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.61 -3.20 -0.801 0.54721E+04 240 silica-amorphous -2.09 -3.95 -1.86 -0.621 0.31809E+04 242 an20ab80 2.02 -2.39 -4.41 -0.339 0.75255E+04 243 an25ab75 2.65 -1.71 -4.35 -0.335 0.74327E+04 244 an30ab70 3.28 -1.03 -4.30 -0.331 0.73496E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0120000 g New total amount of reactant added: 0.0124000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0124000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2835913E-03 Osmotic coef. = 0.9899 True ionic strength = .2900978E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.22748E-07 -7.6431 0.21842E-07 -7.6607 0.96019E+00 -0.0176 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13245E-03 -3.8779 0.96006E+00 -0.0177 4 SO4-- 0.25319E-04 -4.5965 0.22701E-04 -4.6440 0.89657E+00 -0.0474 5 HCO3- 0.12436E-04 -4.9053 0.11940E-04 -4.9230 0.96009E+00 -0.0177 6 HS- 0.16871E-09 -9.7728 0.16198E-09 -9.7905 0.96006E+00 -0.0177 7 Al+++ 0.97432E-20 -20.0113 0.77909E-20 -20.1084 0.79962E+00 -0.0971 8 H4SiO4 0.11460E-03 -3.9408 0.11460E-03 -3.9408 0.10000E+01 0.0000 9 Ca++ 0.28316E-04 -4.5480 0.25383E-04 -4.5955 0.89643E+00 -0.0475 10 Mg++ 0.34479E-06 -6.4624 0.30905E-06 -6.5100 0.89634E+00 -0.0475 11 Fe++ 0.21060E-08 -8.6765 0.18878E-08 -8.7241 0.89637E+00 -0.0475 12 K+ 0.26317E-05 -5.5798 0.25267E-05 -5.5974 0.96010E+00 -0.0177 13 Na+ 0.17561E-03 -3.7554 0.16860E-03 -3.7731 0.96006E+00 -0.0177 14 Mn++ 0.11338E-06 -6.9455 0.10163E-06 -6.9930 0.89638E+00 -0.0475 15 HPO4-- 0.27610E-08 -8.5589 0.24754E-08 -8.6063 0.89657E+00 -0.0474 16 HSiO3- 0.51031E-05 -5.2922 0.48993E-05 -5.3099 0.96006E+00 -0.0177 17 Ca(HSiO3)+ 0.29498E-08 -8.5302 0.28321E-08 -8.5479 0.96010E+00 -0.0177 18 Mg(HSiO3)+ 0.44697E-10 -10.3497 0.42914E-10 -10.3674 0.96010E+00 -0.0177 19 NaHSiO3,aq 0.13360E-07 -7.8742 0.13360E-07 -7.8742 0.10000E+01 0.0000 20 AlO+ 0.23139E-11 -11.6356 0.22216E-11 -11.6533 0.96010E+00 -0.0177 21 AlOH+2 0.26955E-15 -15.5694 0.24163E-15 -15.6169 0.89640E+00 -0.0475 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.21383E-05 -5.6699 0.20528E-05 -5.6877 0.96002E+00 -0.0177 24 CH4,aq 0.82763E-16 -16.0822 0.82756E-16 -16.0822 0.99991E+00 0.0000 29 CO,aq 0.22678E-16 -16.6444 0.22678E-16 -16.6444 0.10000E+01 0.0000 30 CO2,aq 0.55730E-06 -6.2539 0.55725E-06 -6.2539 0.99991E+00 0.0000 31 CO3-2 0.53257E-07 -7.2736 0.47747E-07 -7.3211 0.89653E+00 -0.0474 32 CaCO3,aq 0.15197E-07 -7.8183 0.15197E-07 -7.8183 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.80577E-08 -8.0938 0.77362E-08 -8.1115 0.96010E+00 -0.0177 34 CaCl+ 0.56670E-08 -8.2466 0.54409E-08 -8.2643 0.96010E+00 -0.0177 35 CaCl2,aq 0.17121E-12 -12.7665 0.17121E-12 -12.7665 0.10000E+01 0.0000 36 CaOH+ 0.86266E-07 -7.0642 0.82824E-07 -7.0818 0.96010E+00 -0.0177 37 CaSO4,aq 0.18298E-06 -6.7376 0.18298E-06 -6.7376 0.10000E+01 0.0000 38 HCl,aq 0.53014E-12 -12.2756 0.53014E-12 -12.2756 0.10000E+01 0.0000 43 FeCl+ 0.41222E-12 -12.3849 0.39577E-12 -12.4026 0.96010E+00 -0.0177 46 FeO,aq 0.15379E-09 -9.8131 0.15379E-09 -9.8131 0.10000E+01 0.0000 47 FeOH+ 0.29302E-08 -8.5331 0.28133E-08 -8.5508 0.96010E+00 -0.0177 48 HFeO2- 0.76734E-10 -10.1150 0.73669E-10 -10.1327 0.96006E+00 -0.0177 49 FeO+ 0.17365E-12 -12.7603 0.16672E-12 -12.7780 0.96010E+00 -0.0177 50 FeOH+2 0.77580E-18 -18.1103 0.69543E-18 -18.1577 0.89640E+00 -0.0475 51 FeO2- 0.74480E-10 -10.1280 0.71506E-10 -10.1457 0.96006E+00 -0.0177 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.16201E-08 -8.7904 0.16200E-08 -8.7905 0.99991E+00 0.0000 54 KCl,aq 0.60656E-11 -11.2171 0.60656E-11 -11.2171 0.10000E+01 0.0000 55 KHSO4,aq 0.35422E-17 -17.4507 0.35422E-17 -17.4507 0.10000E+01 0.0000 56 KOH,aq 0.49402E-10 -10.3063 0.49402E-10 -10.3063 0.10000E+01 0.0000 57 KSO4- 0.92708E-09 -9.0329 0.89005E-09 -9.0506 0.96006E+00 -0.0177 58 MgCO3,aq 0.46378E-10 -10.3337 0.46378E-10 -10.3337 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10025E-09 -9.9989 0.96246E-10 -10.0166 0.96010E+00 -0.0177 60 MgCl+ 0.62535E-10 -10.2039 0.60040E-10 -10.2216 0.96010E+00 -0.0177 61 MgOH+ 0.58119E-08 -8.2357 0.55800E-08 -8.2534 0.96010E+00 -0.0177 63 MnO,aq 0.22061E-09 -9.6564 0.22061E-09 -9.6564 0.10000E+01 0.0000 64 MnOH+ 0.14655E-07 -7.8340 0.14070E-07 -7.8517 0.96010E+00 -0.0177 65 MnO2-2 0.17117E-16 -16.7666 0.15346E-16 -16.8140 0.89653E+00 -0.0474 66 HMnO2- 0.76490E-13 -13.1164 0.73435E-13 -13.1341 0.96006E+00 -0.0177 69 MnCl+ 0.86337E-10 -10.0638 0.82892E-10 -10.0815 0.96010E+00 -0.0177 70 MnSO4,aq 0.66603E-09 -9.1765 0.66603E-09 -9.1765 0.10000E+01 0.0000 71 NaCl,aq 0.74006E-08 -8.1307 0.74006E-08 -8.1307 0.10000E+01 0.0000 72 NaOH,aq 0.33164E-08 -8.4793 0.33164E-08 -8.4793 0.10000E+01 0.0000 74 OH- 0.27554E-04 -4.5598 0.26452E-04 -4.5775 0.96002E+00 -0.0177 79 HPO3-2 0.13939E-19 -19.8558 0.12497E-19 -19.9032 0.89653E+00 -0.0474 82 H3PO4,aq 0.82598E-14 -14.0830 0.82598E-14 -14.0830 0.10000E+01 0.0000 83 H2PO4- 0.10389E-08 -8.9834 0.99743E-09 -9.0011 0.96008E+00 -0.0177 84 PO4-3 0.11552E-12 -12.9374 0.92467E-13 -13.0340 0.80047E+00 -0.0967 87 H2P2O7-2 0.87011E-19 -19.0604 0.78008E-19 -19.1079 0.89653E+00 -0.0474 88 HP2O7-3 0.89182E-18 -18.0497 0.71313E-18 -18.1468 0.79963E+00 -0.0971 89 P2O7-4 0.11441E-19 -19.9416 0.77998E-20 -20.1079 0.68176E+00 -0.1664 90 H2S,aq 0.10935E-10 -10.9612 0.10934E-10 -10.9612 0.99991E+00 0.0000 96 SO2,aq 0.78354E-19 -19.1059 0.78354E-19 -19.1059 0.10000E+01 0.0000 97 SO3-2 0.53287E-14 -14.2734 0.47789E-14 -14.3207 0.89681E+00 -0.0473 98 HSO3- 0.68074E-14 -14.1670 0.65355E-14 -14.1847 0.96006E+00 -0.0177 99 HSO4- 0.49769E-09 -9.3030 0.47784E-09 -9.3207 0.96012E+00 -0.0177 101 S2O3-2 0.32523E-17 -17.4878 0.29158E-17 -17.5352 0.89653E+00 -0.0474 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2274796E-07 -.4088887E-04 -.4121257E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999750E+06 0.0000 3 Cl- 0.1379616E-03 0.1379748E-03 0.4891509E+01 3.7828 4 SO4-- 0.2531935E-04 0.2550404E-04 0.2449902E+01 10.6774 5 HCO3- 0.1243611E-04 0.1307006E-04 0.7974801E+00 2.7377 6 HS- 0.1687139E-09 0.5505231E-09 0.1820648E-04 -2.1298 7 Al+++ 0.9743207E-20 0.2158543E-05 0.5823937E-01 2.8737 8 H4SiO4 0.1146045E-03 0.1197239E-03 0.1150705E+02 -3.9408 9 Ca++ 0.2831589E-04 0.2861700E-04 0.1146886E+01 10.7260 10 Mg++ 0.3447903E-06 0.3508561E-06 0.8529815E-02 8.8114 11 Fe++ 0.2106030E-08 0.5540485E-08 0.3094123E-03 6.5974 12 K+ 0.2631727E-05 0.2632709E-05 0.1029418E+00 2.0633 13 Na+ 0.1756128E-03 0.1756369E-03 0.4037763E+01 3.8876 14 Mn++ 0.1133782E-06 0.1290058E-06 0.7087158E-02 8.3284 15 HPO4-- 0.2761008E-08 0.3800038E-08 0.3647154E-03 6.7151 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1922856E-03 -.4088868E-04 -.1513969E-03 0.0000000E+00 2 H2O 0.5550809E+02 0.5550801E+02 0.8558953E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2584812E-04 0.2550392E-04 0.3441968E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3436463E-06 0.5505205E-09 -.3441968E-06 0.0000000E+00 7 Al+++ 0.4043320E-04 0.2158532E-05 0.3827466E-04 0.0000000E+00 8 H4SiO4 0.1291185E-03 0.1197233E-03 0.9395160E-05 0.0000000E+00 9 Ca++ 0.2873283E-04 0.2861687E-04 0.1159632E-06 0.0000000E+00 10 Mg++ 0.9841270E-05 0.3508544E-06 0.9490415E-05 0.0000000E+00 11 Fe++ 0.8841307E-05 0.5540458E-08 0.8835766E-05 0.0000000E+00 12 K+ 0.2632696E-05 0.2632696E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1756360E-03 0.1756360E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2149986E-06 0.1290052E-06 0.8599338E-07 0.0000000E+00 15 HPO4-- 0.7337795E-07 0.3800020E-08 0.6957793E-07 0.0000000E+00 Chg. balance for solid moles: -.5082E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0124000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2319E-07 -7.635 0.1165E-04 -4.934 0.2851 0.3702E-05 clinochlore 0.1898E-05 -5.722 0.1055E-02 -2.977 25.81 0.4013E-03 daphnite 0.1216E-05 -5.915 0.8679E-03 -3.062 21.24 0.2630E-03 chlorite-Mn 0.1720E-07 -7.765 0.1219E-04 -4.914 0.2983 0.3886E-05 diaspore 0.3201E-04 -4.495 0.1920E-02 -2.717 46.99 0.5717E-03 hematite 0.1377E-05 -5.861 0.2199E-03 -3.658 5.380 0.4167E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6061E+00 0.6061E+00 1.0000 -0.217 daphnite 0.3884E+00 0.3884E+00 1.0000 -0.411 chlorite-Mn 0.5492E-02 0.5492E-02 1.0000 -2.260 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004087 g Volume = 0.001285 cm3 Porosity: 99.8721% V(tot) - V(min): 0.10037E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0124000 g log = -1.9066 Original solution: 1000.0103000 g Original solution / Rock added: 80645.99 (Water/Rock Ratio), log = 4.9066 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.5802E-04 1.0071 0.5962E-04 0.5920E-04 CH4,gas 0.1179E-12 1.0125 0.1218E-12 0.1203E-12 H2,gas 0.2083E-05 1.0005 0.2127E-05 0.2126E-05 H2S,gas 0.2958E-09 0.9960 0.3006E-09 0.3018E-09 S2,gas 0.7347E-27 1.0000 0.7497E-27 0.7497E-27 CO,gas 0.3312E-13 1.0000 0.3379E-13 0.3379E-13 SO3,gas 0.4013E-35 1.0000 0.4095E-35 0.4095E-35 SO2,gas 0.3321E-18 1.0000 0.3388E-18 0.3388E-18 HCl,gas 0.9168E-15 1.0000 0.9354E-15 0.9354E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.58 -5.92 -1.975 0.10114E+05 -4.225 3 CH4,gas 4.54 -10.07 -14.61 -3.653 0.24952E+05 -12.914 4 H2,gas 8.00 0.63 -7.37 -4.212 0.12586E+05 -5.672 5 H2S,gas -6.23 -17.45 -11.22 -5.611 0.19160E+05 -9.522 6 S2,gas -7.34 -36.16 -28.82 -4.434 0.49216E+05 -27.125 7 CO,gas 3.21 -11.96 -15.17 -4.668 0.25903E+05 -13.471 8 SO3,gas 17.12 -19.97 -37.09 -9.272 0.63325E+05 -35.388 9 SO2,gas 0.83 -19.34 -20.17 -5.378 0.34438E+05 -18.470 10 HCl,gas 5.19 -11.54 -16.73 -8.364 0.28563E+05 -15.029 16 albite -0.38 -5.06 -4.68 -0.360 0.79863E+04 20 analcite 3.32 -1.12 -4.44 -0.494 0.75849E+04 21 andalusite 5.00 1.81 -3.19 -0.319 0.54553E+04 24 anhydrite -5.32 -9.24 -3.92 -1.961 0.66978E+04 29 anorthite 12.71 8.59 -4.12 -0.317 0.70323E+04 35 aragonite 0.97 -1.86 -2.82 -0.941 0.48224E+04 36 brucite 12.57 8.81 -3.76 -0.751 0.64152E+04 37 calcite 0.81 -1.86 -2.67 -0.890 0.45581E+04 40 carpholite-Mg 8.58 6.68 -1.90 -0.127 0.32525E+04 41 carpholite-Fe 6.71 4.46 -2.25 -0.150 0.38409E+04 50 chloritoid-Mg 13.20 10.62 -2.58 -0.172 0.44047E+04 51 chloritoid-Fe 9.17 8.40 -0.77 -0.051 0.13142E+04 52 chloritoid-Mn 11.40 10.14 -1.27 -0.084 0.21617E+04 54 coesite -2.38 -3.94 -1.56 -0.522 0.26717E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.94 -1.38 -0.460 0.23571E+04 67 diopside 16.18 11.66 -4.53 -0.453 0.77273E+04 68 hedenbergite 14.21 9.44 -4.77 -0.477 0.81388E+04 75 epidote 24.67 21.66 -3.01 -0.146 0.51394E+04 76 clinozoisite 22.81 18.25 -4.56 -0.207 0.77783E+04 77 epidote-Fe 29.84 25.07 -4.77 -0.248 0.81471E+04 78 fayalite 14.05 9.25 -4.79 -0.685 0.81819E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.352 0.72210E+04 92 hercynite 17.28 12.34 -4.93 -0.329 0.84243E+04 98 kaolinite -1.33 -2.13 -0.80 -0.073 0.13684E+04 99 kyanite 4.88 1.81 -3.07 -0.307 0.52412E+04 101 laumontite 2.88 0.71 -2.17 -0.145 0.37108E+04 102 lawsonite 9.62 8.59 -1.02 -0.068 0.17490E+04 105 lizardite 23.24 18.55 -4.69 -0.391 0.80100E+04 106 magnesite 0.69 -3.77 -4.46 -1.488 0.76202E+04 107 magnetite 20.09 19.16 -0.92 -0.075 0.15775E+04 110 magnesioferrite 26.21 21.38 -4.83 -0.395 0.82552E+04 113 margarite 17.32 14.34 -2.98 -0.119 0.50959E+04 116 microcline -2.49 -6.89 -4.40 -0.338 0.75111E+04 120 muscovite 2.58 -1.14 -3.72 -0.219 0.63526E+04 121 paragonite 4.24 0.69 -3.55 -0.209 0.60670E+04 136 prehnite 19.37 15.38 -3.99 -0.235 0.68213E+04 137 prehnite-Fe 22.50 18.79 -3.71 -0.223 0.63374E+04 145 pyroxmangite 7.40 4.39 -3.01 -0.602 0.51413E+04 146 pyrophyllite -6.18 -10.02 -3.84 -0.240 0.65567E+04 147 quartz -2.99 -3.94 -0.95 -0.317 0.16244E+04 151 rhodochrosite -0.98 -4.26 -3.28 -1.093 0.55987E+04 152 rhodonite 7.45 4.39 -3.06 -0.612 0.52215E+04 155 siderite -2.61 -5.99 -3.38 -1.126 0.57682E+04 156 sillimanite 5.26 1.81 -3.45 -0.345 0.58992E+04 163 stilbite -7.52 -11.11 -3.59 -0.171 0.61302E+04 164 stilpnomelane-Fe 13.02 8.24 -4.78 -0.143 0.81575E+04 168 sudoite 21.08 17.30 -3.78 -0.122 0.64578E+04 177 topaz-H 4.62 1.81 -2.81 -0.256 0.48012E+04 178 tridymite -2.63 -3.94 -1.31 -0.438 0.22444E+04 187 wairakite 3.95 0.71 -3.24 -0.191 0.55327E+04 188 walstromite 11.51 6.79 -4.72 -0.945 0.80662E+04 189 wollastonite 10.46 6.79 -3.68 -0.735 0.62767E+04 190 pseudo-wollastonite 11.00 6.79 -4.21 -0.843 0.71965E+04 191 zoisite 22.85 18.25 -4.60 -0.209 0.78523E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -6.00 -4.35 -0.269 0.74303E+04 196 beidellite-Mg -1.79 -6.31 -4.52 -0.280 0.77235E+04 199 chalcedony -2.80 -3.94 -1.14 -0.379 0.19437E+04 201 montmorillonite-Ca -2.29 -6.29 -4.00 -0.247 0.68228E+04 203 montmorillonite-Mg -2.48 -6.60 -4.12 -0.255 0.70392E+04 204 montmorillonite-Na -2.04 -6.77 -4.74 -0.290 0.80860E+04 205 nontronite-Ca 3.21 0.82 -2.39 -0.155 0.40860E+04 206 nontronite-H 2.53 -0.95 -3.48 -0.233 0.59436E+04 207 nontronite-K 3.34 -0.27 -3.61 -0.232 0.61606E+04 208 nontronite-Mg 3.07 0.51 -2.57 -0.167 0.43864E+04 209 nontronite-Na 3.52 0.33 -3.19 -0.204 0.54384E+04 214 gypsum -4.96 -9.24 -4.28 -1.071 0.73153E+04 224 tobermorite 9.82 4.99 -4.83 -1.318 0.82456E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.60 -3.21 -0.804 0.54882E+04 240 silica-amorphous -2.09 -3.94 -1.85 -0.616 0.31579E+04 242 an20ab80 2.02 -2.33 -4.35 -0.334 0.74247E+04 243 an25ab75 2.65 -1.65 -4.29 -0.330 0.73312E+04 244 an30ab70 3.28 -0.97 -4.24 -0.327 0.72474E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0124000 g New total amount of reactant added: 0.0128000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0128000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2850773E-03 Osmotic coef. = 0.9899 True ionic strength = .2919342E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.21964E-07 -7.6583 0.21088E-07 -7.6760 0.96012E+00 -0.0177 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13244E-03 -3.8780 0.95999E+00 -0.0177 4 SO4-- 0.25317E-04 -4.5966 0.22692E-04 -4.6441 0.89632E+00 -0.0475 5 HCO3- 0.12452E-04 -4.9048 0.11954E-04 -4.9225 0.96002E+00 -0.0177 6 HS- 0.13791E-09 -9.8604 0.13239E-09 -9.8781 0.96000E+00 -0.0177 7 Al+++ 0.87739E-20 -20.0568 0.70114E-20 -20.1542 0.79912E+00 -0.0974 8 H4SiO4 0.11809E-03 -3.9278 0.11809E-03 -3.9278 0.10000E+01 0.0000 9 Ca++ 0.28763E-04 -4.5412 0.25777E-04 -4.5888 0.89618E+00 -0.0476 10 Mg++ 0.31611E-06 -6.5002 0.28327E-06 -6.5478 0.89609E+00 -0.0476 11 Fe++ 0.19233E-08 -8.7160 0.17235E-08 -8.7636 0.89611E+00 -0.0476 12 K+ 0.27166E-05 -5.5660 0.26080E-05 -5.5837 0.96003E+00 -0.0177 13 Na+ 0.17611E-03 -3.7542 0.16907E-03 -3.7719 0.95999E+00 -0.0177 14 Mn++ 0.11097E-06 -6.9548 0.99439E-07 -7.0024 0.89613E+00 -0.0476 15 HPO4-- 0.25687E-08 -8.5903 0.23023E-08 -8.6378 0.89632E+00 -0.0475 16 HSiO3- 0.54469E-05 -5.2639 0.52289E-05 -5.2816 0.95999E+00 -0.0177 17 Ca(HSiO3)+ 0.31974E-08 -8.4952 0.30696E-08 -8.5129 0.96003E+00 -0.0177 18 Mg(HSiO3)+ 0.43728E-10 -10.3592 0.41980E-10 -10.3770 0.96003E+00 -0.0177 19 NaHSiO3,aq 0.14298E-07 -7.8447 0.14298E-07 -7.8447 0.10000E+01 0.0000 20 AlO+ 0.22342E-11 -11.6509 0.21449E-11 -11.6686 0.96003E+00 -0.0177 21 AlOH+2 0.25133E-15 -15.5998 0.22523E-15 -15.6474 0.89615E+00 -0.0476 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.22149E-05 -5.6546 0.21262E-05 -5.6724 0.95995E+00 -0.0177 24 CH4,aq 0.67752E-16 -16.1691 0.67747E-16 -16.1691 0.99991E+00 0.0000 29 CO,aq 0.21029E-16 -16.6772 0.21029E-16 -16.6772 0.10000E+01 0.0000 30 CO2,aq 0.53870E-06 -6.2687 0.53865E-06 -6.2687 0.99991E+00 0.0000 31 CO3-2 0.55243E-07 -7.2577 0.49513E-07 -7.3053 0.89628E+00 -0.0476 32 CaCO3,aq 0.16003E-07 -7.7958 0.16003E-07 -7.7958 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.81929E-08 -8.0866 0.78655E-08 -8.1043 0.96003E+00 -0.0177 34 CaCl+ 0.57548E-08 -8.2400 0.55248E-08 -8.2577 0.96003E+00 -0.0177 35 CaCl2,aq 0.17384E-12 -12.7598 0.17384E-12 -12.7598 0.10000E+01 0.0000 36 CaOH+ 0.90742E-07 -7.0422 0.87116E-07 -7.0599 0.96003E+00 -0.0177 37 CaSO4,aq 0.18574E-06 -6.7311 0.18574E-06 -6.7311 0.10000E+01 0.0000 38 HCl,aq 0.51180E-12 -12.2909 0.51180E-12 -12.2909 0.10000E+01 0.0000 43 FeCl+ 0.37634E-12 -12.4244 0.36130E-12 -12.4421 0.96003E+00 -0.0177 46 FeO,aq 0.15063E-09 -9.8221 0.15063E-09 -9.8221 0.10000E+01 0.0000 47 FeOH+ 0.27711E-08 -8.5574 0.26603E-08 -8.5751 0.96003E+00 -0.0177 48 HFeO2- 0.77850E-10 -10.1087 0.74735E-10 -10.1265 0.95999E+00 -0.0177 49 FeO+ 0.16766E-12 -12.7756 0.16096E-12 -12.7933 0.96003E+00 -0.0177 50 FeOH+2 0.72335E-18 -18.1407 0.64823E-18 -18.1883 0.89615E+00 -0.0476 51 FeO2- 0.77150E-10 -10.1127 0.74063E-10 -10.1304 0.95999E+00 -0.0177 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.15542E-08 -8.8085 0.15541E-08 -8.8085 0.99991E+00 0.0000 54 KCl,aq 0.62603E-11 -11.2034 0.62603E-11 -11.2034 0.10000E+01 0.0000 55 KHSO4,aq 0.35286E-17 -17.4524 0.35286E-17 -17.4524 0.10000E+01 0.0000 56 KOH,aq 0.52816E-10 -10.2772 0.52816E-10 -10.2772 0.10000E+01 0.0000 57 KSO4- 0.95662E-09 -9.0193 0.91834E-09 -9.0370 0.95999E+00 -0.0177 58 MgCO3,aq 0.44081E-10 -10.3557 0.44081E-10 -10.3557 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.91998E-10 -10.0362 0.88321E-10 -10.0539 0.96003E+00 -0.0177 60 MgCl+ 0.57318E-10 -10.2417 0.55027E-10 -10.2594 0.96003E+00 -0.0177 61 MgOH+ 0.55180E-08 -8.2582 0.52974E-08 -8.2759 0.96003E+00 -0.0177 63 MnO,aq 0.23157E-09 -9.6353 0.23157E-09 -9.6353 0.10000E+01 0.0000 64 MnOH+ 0.14853E-07 -7.8282 0.14259E-07 -7.8459 0.96003E+00 -0.0177 65 MnO2-2 0.19281E-16 -16.7149 0.17281E-16 -16.7624 0.89628E+00 -0.0476 66 HMnO2- 0.83168E-13 -13.0800 0.79840E-13 -13.0978 0.95999E+00 -0.0177 69 MnCl+ 0.84476E-10 -10.0733 0.81100E-10 -10.0910 0.96003E+00 -0.0177 70 MnSO4,aq 0.65142E-09 -9.1861 0.65142E-09 -9.1861 0.10000E+01 0.0000 71 NaCl,aq 0.74206E-08 -8.1296 0.74206E-08 -8.1296 0.10000E+01 0.0000 72 NaOH,aq 0.34446E-08 -8.4629 0.34446E-08 -8.4629 0.10000E+01 0.0000 74 OH- 0.28541E-04 -4.5445 0.27398E-04 -4.5623 0.95995E+00 -0.0177 79 HPO3-2 0.12441E-19 -19.9052 0.11150E-19 -19.9527 0.89628E+00 -0.0476 82 H3PO4,aq 0.71609E-14 -14.1450 0.71609E-14 -14.1450 0.10000E+01 0.0000 83 H2PO4- 0.93296E-09 -9.0301 0.89565E-09 -9.0479 0.96001E+00 -0.0177 84 PO4-3 0.11135E-12 -12.9533 0.89077E-13 -13.0502 0.79997E+00 -0.0969 87 H2P2O7-2 0.70179E-19 -19.1538 0.62900E-19 -19.2013 0.89628E+00 -0.0476 88 HP2O7-3 0.74529E-18 -18.1277 0.59558E-18 -18.2251 0.79912E+00 -0.0974 90 H2S,aq 0.86293E-11 -11.0640 0.86285E-11 -11.0641 0.99991E+00 0.0000 96 SO2,aq 0.70037E-19 -19.1547 0.70037E-19 -19.1547 0.10000E+01 0.0000 97 SO3-2 0.51113E-14 -14.2915 0.45826E-14 -14.3389 0.89656E+00 -0.0474 98 HSO3- 0.63029E-14 -14.2005 0.60508E-14 -14.2182 0.95999E+00 -0.0177 99 HSO4- 0.48035E-09 -9.3184 0.46116E-09 -9.3361 0.96005E+00 -0.0177 101 S2O3-2 0.25661E-17 -17.5907 0.23000E-17 -17.6383 0.89628E+00 -0.0476 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2196403E-07 -.4255448E-04 -.4289135E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999746E+06 0.0000 3 Cl- 0.1379615E-03 0.1379749E-03 0.4891507E+01 3.7980 4 SO4-- 0.2531662E-04 0.2550410E-04 0.2449906E+01 10.7078 5 HCO3- 0.1245179E-04 0.1307006E-04 0.7974799E+00 2.7535 6 HS- 0.1379062E-09 0.5005948E-09 0.1655528E-04 -2.2022 7 Al+++ 0.8773944E-20 0.2235174E-05 0.6030691E-01 2.8737 8 H4SiO4 0.1180930E-03 0.1235574E-03 0.1187548E+02 -3.9278 9 Ca++ 0.2876299E-04 0.2907263E-04 0.1165145E+01 10.7632 10 Mg++ 0.3161148E-06 0.3218699E-06 0.7825115E-02 8.8041 11 Fe++ 0.1923289E-08 0.5199185E-08 0.2903520E-03 6.5883 12 K+ 0.2716620E-05 0.2717636E-05 0.1062625E+00 2.0923 13 Na+ 0.1761138E-03 0.1761390E-03 0.4049305E+01 3.9040 14 Mn++ 0.1109654E-06 0.1267855E-06 0.6965178E-02 8.3495 15 HPO4-- 0.2568658E-08 0.3501736E-08 0.3360852E-03 6.7141 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1989090E-03 -.4255427E-04 -.1563547E-03 0.0000000E+00 2 H2O 0.5550809E+02 0.5550800E+02 0.8835519E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2585920E-04 0.2550397E-04 0.3552322E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3547316E-06 0.5005923E-09 -.3552322E-06 0.0000000E+00 7 Al+++ 0.4173749E-04 0.2235162E-05 0.3950233E-04 0.0000000E+00 8 H4SiO4 0.1332836E-03 0.1235567E-03 0.9726878E-05 0.0000000E+00 9 Ca++ 0.2919289E-04 0.2907248E-04 0.1204054E-06 0.0000000E+00 10 Mg++ 0.1015873E-04 0.3218683E-06 0.9836862E-05 0.0000000E+00 11 Fe++ 0.9126510E-05 0.5199159E-08 0.9121311E-05 0.0000000E+00 12 K+ 0.2717622E-05 0.2717622E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1761381E-03 0.1761381E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2219340E-06 0.1267849E-06 0.9514915E-07 0.0000000E+00 15 HPO4-- 0.7574498E-07 0.3501719E-08 0.7224326E-07 0.0000000E+00 Chg. balance for solid moles: 0.2610E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0128000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2408E-07 -7.618 0.1210E-04 -4.917 0.2865 0.3844E-05 clinochlore 0.1967E-05 -5.706 0.1094E-02 -2.961 25.90 0.4159E-03 daphnite 0.1256E-05 -5.901 0.8961E-03 -3.048 21.22 0.2715E-03 chlorite-Mn 0.1903E-07 -7.721 0.1349E-04 -4.870 0.3195 0.4299E-05 diaspore 0.3302E-04 -4.481 0.1981E-02 -2.703 46.91 0.5897E-03 hematite 0.1421E-05 -5.847 0.2269E-03 -3.644 5.374 0.4301E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6068E+00 0.6068E+00 1.0000 -0.217 daphnite 0.3873E+00 0.3873E+00 1.0000 -0.412 chlorite-Mn 0.5869E-02 0.5869E-02 1.0000 -2.231 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004223 g Volume = 0.001328 cm3 Porosity: 99.8678% V(tot) - V(min): 0.10038E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0128000 g log = -1.8928 Original solution: 1000.0103000 g Original solution / Rock added: 78125.80 (Water/Rock Ratio), log = 4.8928 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.5608E-04 1.0071 0.5763E-04 0.5722E-04 CH4,gas 0.9652E-13 1.0125 0.9972E-13 0.9848E-13 H2,gas 0.1999E-05 1.0005 0.2040E-05 0.2039E-05 H2S,gas 0.2334E-09 0.9960 0.2372E-09 0.2381E-09 S2,gas 0.4972E-27 1.0000 0.5073E-27 0.5073E-27 CO,gas 0.3071E-13 1.0000 0.3134E-13 0.3134E-13 SO3,gas 0.3739E-35 1.0000 0.3816E-35 0.3816E-35 SO2,gas 0.2968E-18 1.0000 0.3029E-18 0.3029E-18 HCl,gas 0.8851E-15 1.0000 0.9031E-15 0.9031E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.60 -5.94 -1.979 0.10140E+05 -4.239 3 CH4,gas 4.54 -10.16 -14.70 -3.675 0.25100E+05 -13.001 4 H2,gas 8.00 0.61 -7.39 -4.222 0.12617E+05 -5.690 5 H2S,gas -6.23 -17.55 -11.32 -5.662 0.19335E+05 -9.625 6 S2,gas -7.34 -36.33 -28.99 -4.461 0.49506E+05 -27.295 7 CO,gas 3.21 -11.99 -15.20 -4.678 0.25959E+05 -13.504 8 SO3,gas 17.12 -20.00 -37.12 -9.279 0.63377E+05 -35.418 9 SO2,gas 0.83 -19.39 -20.22 -5.391 0.34521E+05 -18.519 10 HCl,gas 5.19 -11.55 -16.74 -8.372 0.28589E+05 -15.044 16 albite -0.38 -5.01 -4.62 -0.356 0.78915E+04 20 analcite 3.32 -1.08 -4.40 -0.489 0.75124E+04 21 andalusite 5.00 1.82 -3.18 -0.318 0.54330E+04 24 anhydrite -5.32 -9.23 -3.92 -1.958 0.66866E+04 29 anorthite 12.71 8.65 -4.06 -0.312 0.69243E+04 35 aragonite 0.97 -1.84 -2.80 -0.934 0.47840E+04 36 brucite 12.57 8.80 -3.76 -0.753 0.64277E+04 37 calcite 0.81 -1.84 -2.65 -0.882 0.45198E+04 40 carpholite-Mg 8.58 6.70 -1.89 -0.126 0.32205E+04 41 carpholite-Fe 6.71 4.48 -2.23 -0.149 0.38119E+04 50 chloritoid-Mg 13.20 10.62 -2.57 -0.172 0.43950E+04 51 chloritoid-Fe 9.17 8.41 -0.77 -0.051 0.13074E+04 52 chloritoid-Mn 11.40 10.17 -1.23 -0.082 0.21036E+04 54 coesite -2.38 -3.93 -1.55 -0.517 0.26495E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.93 -1.37 -0.456 0.23349E+04 67 diopside 16.18 11.71 -4.47 -0.447 0.76318E+04 68 hedenbergite 14.21 9.50 -4.71 -0.471 0.80462E+04 75 epidote 24.67 21.77 -2.90 -0.140 0.49456E+04 76 clinozoisite 22.81 18.36 -4.44 -0.202 0.75845E+04 77 epidote-Fe 29.84 25.18 -4.66 -0.242 0.79533E+04 78 fayalite 14.05 9.25 -4.80 -0.685 0.81905E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.353 0.72227E+04 92 hercynite 17.28 12.34 -4.94 -0.330 0.84397E+04 98 kaolinite -1.33 -2.11 -0.78 -0.070 0.13240E+04 99 kyanite 4.88 1.82 -3.06 -0.306 0.52189E+04 101 laumontite 2.88 0.80 -2.08 -0.139 0.35583E+04 102 lawsonite 9.62 8.65 -0.96 -0.064 0.16410E+04 105 lizardite 23.24 18.56 -4.69 -0.391 0.80030E+04 106 magnesite 0.69 -3.79 -4.48 -1.495 0.76579E+04 107 magnetite 20.09 19.15 -0.93 -0.076 0.15929E+04 110 magnesioferrite 26.21 21.37 -4.84 -0.395 0.82677E+04 113 margarite 17.32 14.40 -2.92 -0.117 0.49879E+04 116 microcline -2.49 -6.82 -4.33 -0.333 0.73948E+04 120 muscovite 2.58 -1.07 -3.65 -0.215 0.62364E+04 121 paragonite 4.24 0.74 -3.50 -0.206 0.59721E+04 136 prehnite 19.37 15.49 -3.88 -0.228 0.66276E+04 137 prehnite-Fe 22.50 18.90 -3.60 -0.216 0.61436E+04 145 pyroxmangite 7.40 4.42 -2.98 -0.595 0.50831E+04 146 pyrophyllite -6.18 -9.96 -3.79 -0.237 0.64678E+04 147 quartz -2.99 -3.93 -0.94 -0.313 0.16022E+04 151 rhodochrosite -0.98 -4.25 -3.27 -1.091 0.55880E+04 152 rhodonite 7.45 4.42 -3.02 -0.605 0.51633E+04 155 siderite -2.61 -6.01 -3.40 -1.134 0.58088E+04 156 sillimanite 5.26 1.82 -3.44 -0.344 0.58770E+04 163 stilbite -7.52 -10.98 -3.46 -0.165 0.59110E+04 164 stilpnomelane-Fe 13.02 8.31 -4.70 -0.140 0.80319E+04 168 sudoite 21.08 17.32 -3.76 -0.121 0.64161E+04 177 topaz-H 4.62 1.82 -2.80 -0.254 0.47790E+04 178 tridymite -2.63 -3.93 -1.30 -0.434 0.22222E+04 187 wairakite 3.95 0.80 -3.15 -0.185 0.53803E+04 188 walstromite 11.51 6.84 -4.67 -0.935 0.79805E+04 189 wollastonite 10.46 6.84 -3.63 -0.725 0.61909E+04 190 pseudo-wollastonite 11.00 6.84 -4.16 -0.833 0.71107E+04 191 zoisite 22.85 18.36 -4.49 -0.204 0.76586E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.94 -4.30 -0.266 0.73382E+04 196 beidellite-Mg -1.79 -6.27 -4.48 -0.277 0.76440E+04 199 chalcedony -2.80 -3.93 -1.13 -0.375 0.19215E+04 201 montmorillonite-Ca -2.29 -6.23 -3.94 -0.244 0.67275E+04 203 montmorillonite-Mg -2.48 -6.55 -4.07 -0.252 0.69564E+04 204 montmorillonite-Na -2.04 -6.72 -4.68 -0.287 0.79919E+04 205 nontronite-Ca 3.21 0.88 -2.34 -0.152 0.39939E+04 206 nontronite-H 2.53 -0.90 -3.43 -0.230 0.58620E+04 207 nontronite-K 3.34 -0.21 -3.55 -0.228 0.60627E+04 208 nontronite-Mg 3.07 0.55 -2.52 -0.164 0.43069E+04 209 nontronite-Na 3.52 0.39 -3.13 -0.201 0.53475E+04 214 gypsum -4.96 -9.23 -4.28 -1.069 0.73042E+04 224 tobermorite 9.82 5.04 -4.79 -1.306 0.81705E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.59 -3.22 -0.806 0.55036E+04 240 silica-amorphous -2.09 -3.93 -1.84 -0.612 0.31357E+04 242 an20ab80 2.02 -2.27 -4.29 -0.330 0.73272E+04 243 an25ab75 2.65 -1.59 -4.24 -0.326 0.72331E+04 244 an30ab70 3.28 -0.91 -4.19 -0.322 0.71486E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0128000 g New total amount of reactant added: 0.0132000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0132000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2865686E-03 Osmotic coef. = 0.9899 True ionic strength = .2937797E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.21234E-07 -7.6730 0.20386E-07 -7.6907 0.96005E+00 -0.0177 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13243E-03 -3.8780 0.95992E+00 -0.0178 4 SO4-- 0.25314E-04 -4.5966 0.22683E-04 -4.6443 0.89607E+00 -0.0477 5 HCO3- 0.12466E-04 -4.9043 0.11967E-04 -4.9220 0.95995E+00 -0.0177 6 HS- 0.11369E-09 -9.9443 0.10914E-09 -9.9620 0.95993E+00 -0.0178 7 Al+++ 0.79317E-20 -20.1006 0.63343E-20 -20.1983 0.79861E+00 -0.0977 8 H4SiO4 0.12157E-03 -3.9152 0.12157E-03 -3.9152 0.10000E+01 0.0000 9 Ca++ 0.29210E-04 -4.5345 0.26170E-04 -4.5822 0.89593E+00 -0.0477 10 Mg++ 0.29067E-06 -6.5366 0.26040E-06 -6.5844 0.89584E+00 -0.0478 11 Fe++ 0.17625E-08 -8.7539 0.15790E-08 -8.8016 0.89586E+00 -0.0478 12 K+ 0.28015E-05 -5.5526 0.26893E-05 -5.5704 0.95996E+00 -0.0177 13 Na+ 0.17661E-03 -3.7530 0.16954E-03 -3.7707 0.95992E+00 -0.0178 14 Mn++ 0.10835E-06 -6.9652 0.97068E-07 -7.0129 0.89588E+00 -0.0478 15 HPO4-- 0.23948E-08 -8.6207 0.21459E-08 -8.6684 0.89607E+00 -0.0477 16 HSiO3- 0.58008E-05 -5.2365 0.55684E-05 -5.2543 0.95992E+00 -0.0178 17 Ca(HSiO3)+ 0.34571E-08 -8.4613 0.33187E-08 -8.4790 0.95996E+00 -0.0177 18 Mg(HSiO3)+ 0.42810E-10 -10.3685 0.41096E-10 -10.3862 0.95996E+00 -0.0177 19 NaHSiO3,aq 0.15269E-07 -7.8162 0.15269E-07 -7.8162 0.10000E+01 0.0000 20 AlO+ 0.21600E-11 -11.6655 0.20735E-11 -11.6833 0.95996E+00 -0.0177 21 AlOH+2 0.23494E-15 -15.6290 0.21048E-15 -15.6768 0.89589E+00 -0.0477 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.22913E-05 -5.6399 0.21994E-05 -5.6577 0.95989E+00 -0.0178 24 CH4,aq 0.55936E-16 -16.2523 0.55931E-16 -16.2523 0.99991E+00 0.0000 29 CO,aq 0.19558E-16 -16.7087 0.19558E-16 -16.7087 0.10000E+01 0.0000 30 CO2,aq 0.52133E-06 -6.2829 0.52129E-06 -6.2829 0.99991E+00 0.0000 31 CO3-2 0.57223E-07 -7.2424 0.51274E-07 -7.2901 0.89603E+00 -0.0477 32 CaCO3,aq 0.16825E-07 -7.7740 0.16825E-07 -7.7740 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.83276E-08 -8.0795 0.79942E-08 -8.0972 0.95996E+00 -0.0177 34 CaCl+ 0.58426E-08 -8.2334 0.56087E-08 -8.2511 0.95996E+00 -0.0177 35 CaCl2,aq 0.17647E-12 -12.7533 0.17647E-12 -12.7533 0.10000E+01 0.0000 36 CaOH+ 0.95305E-07 -7.0209 0.91490E-07 -7.0386 0.95996E+00 -0.0177 37 CaSO4,aq 0.18850E-06 -6.7247 0.18850E-06 -6.7247 0.10000E+01 0.0000 38 HCl,aq 0.49473E-12 -12.3056 0.49473E-12 -12.3056 0.10000E+01 0.0000 43 FeCl+ 0.34479E-12 -12.4624 0.33099E-12 -12.4802 0.95996E+00 -0.0177 46 FeO,aq 0.14766E-09 -9.8307 0.14766E-09 -9.8307 0.10000E+01 0.0000 47 FeOH+ 0.26264E-08 -8.5806 0.25212E-08 -8.5984 0.95996E+00 -0.0177 48 HFeO2- 0.78952E-10 -10.1026 0.75788E-10 -10.1204 0.95992E+00 -0.0178 49 FeO+ 0.16209E-12 -12.7902 0.15561E-12 -12.8080 0.95996E+00 -0.0177 50 FeOH+2 0.67619E-18 -18.1699 0.60580E-18 -18.2177 0.89589E+00 -0.0477 51 FeO2- 0.79812E-10 -10.0979 0.76613E-10 -10.1157 0.95992E+00 -0.0178 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.14937E-08 -8.8257 0.14935E-08 -8.8258 0.99991E+00 0.0000 54 KCl,aq 0.64551E-11 -11.1901 0.64551E-11 -11.1901 0.10000E+01 0.0000 55 KHSO4,aq 0.35161E-17 -17.4539 0.35161E-17 -17.4539 0.10000E+01 0.0000 56 KOH,aq 0.56337E-10 -10.2492 0.56337E-10 -10.2492 0.10000E+01 0.0000 57 KSO4- 0.98613E-09 -9.0061 0.94661E-09 -9.0238 0.95992E+00 -0.0178 58 MgCO3,aq 0.41963E-10 -10.3771 0.41963E-10 -10.3771 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.84669E-10 -10.0723 0.81279E-10 -10.0900 0.95996E+00 -0.0177 60 MgCl+ 0.52690E-10 -10.2783 0.50581E-10 -10.2960 0.95996E+00 -0.0177 61 MgOH+ 0.52475E-08 -8.2801 0.50374E-08 -8.2978 0.95996E+00 -0.0177 63 MnO,aq 0.24188E-09 -9.6164 0.24188E-09 -9.6164 0.10000E+01 0.0000 64 MnOH+ 0.14999E-07 -7.8240 0.14398E-07 -7.8417 0.95996E+00 -0.0177 65 MnO2-2 0.21556E-16 -16.6664 0.19315E-16 -16.7141 0.89603E+00 -0.0477 66 HMnO2- 0.89868E-13 -13.0464 0.86266E-13 -13.0642 0.95992E+00 -0.0178 69 MnCl+ 0.82461E-10 -10.0838 0.79160E-10 -10.1015 0.95996E+00 -0.0177 70 MnSO4,aq 0.63564E-09 -9.1968 0.63564E-09 -9.1968 0.10000E+01 0.0000 71 NaCl,aq 0.74407E-08 -8.1284 0.74407E-08 -8.1284 0.10000E+01 0.0000 72 NaOH,aq 0.35731E-08 -8.4470 0.35731E-08 -8.4470 0.10000E+01 0.0000 74 OH- 0.29526E-04 -4.5298 0.28341E-04 -4.5476 0.95989E+00 -0.0178 79 HPO3-2 0.11147E-19 -19.9528 0.99879E-20 -20.0005 0.89603E+00 -0.0477 82 H3PO4,aq 0.62374E-14 -14.2050 0.62374E-14 -14.2050 0.10000E+01 0.0000 83 H2PO4- 0.84068E-09 -9.0754 0.80701E-09 -9.0931 0.95994E+00 -0.0178 84 PO4-3 0.10742E-12 -12.9689 0.85883E-13 -13.0661 0.79947E+00 -0.0972 87 H2P2O7-2 0.56991E-19 -19.2442 0.51066E-19 -19.2919 0.89603E+00 -0.0477 88 HP2O7-3 0.62630E-18 -18.2032 0.50017E-18 -18.3009 0.79862E+00 -0.0977 90 H2S,aq 0.68770E-11 -11.1626 0.68764E-11 -11.1626 0.99991E+00 0.0000 96 SO2,aq 0.62879E-19 -19.2015 0.62879E-19 -19.2015 0.10000E+01 0.0000 97 SO3-2 0.49117E-14 -14.3088 0.44024E-14 -14.3563 0.89631E+00 -0.0475 98 HSO3- 0.58540E-14 -14.2325 0.56194E-14 -14.2503 0.95992E+00 -0.0178 99 HSO4- 0.46422E-09 -9.3333 0.44564E-09 -9.3510 0.95998E+00 -0.0177 101 S2O3-2 0.20448E-17 -17.6893 0.18322E-17 -17.7370 0.89603E+00 -0.0477 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2123446E-07 -.4422560E-04 -.4457568E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999742E+06 0.0000 3 Cl- 0.1379615E-03 0.1379749E-03 0.4891506E+01 3.8127 4 SO4-- 0.2531389E-04 0.2550414E-04 0.2449910E+01 10.7370 5 HCO3- 0.1246623E-04 0.1307007E-04 0.7974797E+00 2.7687 6 HS- 0.1136949E-09 0.4591678E-09 0.1518523E-04 -2.2714 7 Al+++ 0.7931718E-20 0.2311596E-05 0.6236883E-01 2.8737 8 H4SiO4 0.1215730E-03 0.1273927E-03 0.1224410E+02 -3.9152 9 Ca++ 0.2921004E-04 0.2952830E-04 0.1183407E+01 10.7991 10 Mg++ 0.2906748E-06 0.2961444E-06 0.7199689E-02 8.7970 11 Fe++ 0.1762543E-08 0.4894478E-08 0.2733353E-03 6.5797 12 K+ 0.2801513E-05 0.2802562E-05 0.1095831E+00 2.1203 13 Na+ 0.1766148E-03 0.1766411E-03 0.4060846E+01 3.9199 14 Mn++ 0.1083494E-06 0.1243080E-06 0.6829067E-02 8.3684 15 HPO4-- 0.2394793E-08 0.3235589E-08 0.3105412E-03 6.7129 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2055324E-03 -.4422537E-04 -.1613070E-03 0.0000000E+00 2 H2O 0.5550808E+02 0.5550799E+02 0.9112007E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2587029E-04 0.2550401E-04 0.3662762E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3658170E-06 0.4591654E-09 -.3662762E-06 0.0000000E+00 7 Al+++ 0.4304179E-04 0.2311584E-05 0.4073021E-04 0.0000000E+00 8 H4SiO4 0.1374487E-03 0.1273920E-03 0.1005673E-04 0.0000000E+00 9 Ca++ 0.2965294E-04 0.2952815E-04 0.1247941E-06 0.0000000E+00 10 Mg++ 0.1047619E-04 0.2961429E-06 0.1018005E-04 0.0000000E+00 11 Fe++ 0.9411713E-05 0.4894452E-08 0.9406819E-05 0.0000000E+00 12 K+ 0.2802548E-05 0.2802548E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1766402E-03 0.1766402E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2288695E-06 0.1243073E-06 0.1045621E-06 0.0000000E+00 15 HPO4-- 0.7811201E-07 0.3235573E-08 0.7487644E-07 0.0000000E+00 Chg. balance for solid moles: 0.1511E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0132000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2496E-07 -7.603 0.1254E-04 -4.902 0.2877 0.3984E-05 clinochlore 0.2036E-05 -5.691 0.1132E-02 -2.946 25.97 0.4305E-03 daphnite 0.1295E-05 -5.888 0.9242E-03 -3.034 21.21 0.2801E-03 chlorite-Mn 0.2091E-07 -7.680 0.1483E-04 -4.829 0.3402 0.4725E-05 diaspore 0.3403E-04 -4.468 0.2041E-02 -2.690 46.83 0.6077E-03 hematite 0.1465E-05 -5.834 0.2340E-03 -3.631 5.368 0.4435E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6074E+00 0.6074E+00 1.0000 -0.217 daphnite 0.3864E+00 0.3864E+00 1.0000 -0.413 chlorite-Mn 0.6238E-02 0.6238E-02 1.0000 -2.205 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004358 g Volume = 0.001371 cm3 Porosity: 99.8636% V(tot) - V(min): 0.10039E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0132000 g log = -1.8794 Original solution: 1000.0103000 g Original solution / Rock added: 75758.36 (Water/Rock Ratio), log = 4.8794 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.5427E-04 1.0071 0.5577E-04 0.5538E-04 CH4,gas 0.7969E-13 1.0125 0.8233E-13 0.8131E-13 H2,gas 0.1921E-05 1.0005 0.1961E-05 0.1960E-05 H2S,gas 0.1860E-09 0.9960 0.1890E-09 0.1898E-09 S2,gas 0.3419E-27 1.0000 0.3488E-27 0.3488E-27 CO,gas 0.2856E-13 1.0000 0.2915E-13 0.2915E-13 SO3,gas 0.3493E-35 1.0000 0.3564E-35 0.3564E-35 SO2,gas 0.2665E-18 1.0000 0.2719E-18 0.2719E-18 HCl,gas 0.8555E-15 1.0000 0.8730E-15 0.8730E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.61 -5.95 -1.984 0.10164E+05 -4.254 3 CH4,gas 4.54 -10.24 -14.78 -3.696 0.25242E+05 -13.084 4 H2,gas 8.00 0.59 -7.41 -4.232 0.12646E+05 -5.708 5 H2S,gas -6.23 -17.65 -11.42 -5.711 0.19504E+05 -9.723 6 S2,gas -7.34 -36.49 -29.16 -4.486 0.49784E+05 -27.457 7 CO,gas 3.21 -12.02 -15.23 -4.688 0.26012E+05 -13.535 8 SO3,gas 17.12 -20.03 -37.15 -9.287 0.63427E+05 -35.448 9 SO2,gas 0.83 -19.43 -20.26 -5.404 0.34601E+05 -18.566 10 HCl,gas 5.19 -11.57 -16.76 -8.379 0.28614E+05 -15.059 16 albite -0.38 -4.95 -4.57 -0.351 0.77997E+04 20 analcite 3.32 -1.04 -4.36 -0.484 0.74421E+04 21 andalusite 5.00 1.83 -3.17 -0.317 0.54115E+04 24 anhydrite -5.32 -9.23 -3.91 -1.955 0.66757E+04 29 anorthite 12.71 8.72 -3.99 -0.307 0.68198E+04 35 aragonite 0.97 -1.81 -2.78 -0.927 0.47469E+04 36 brucite 12.57 8.80 -3.77 -0.754 0.64399E+04 37 calcite 0.81 -1.81 -2.63 -0.875 0.44827E+04 40 carpholite-Mg 8.58 6.71 -1.87 -0.125 0.31897E+04 41 carpholite-Fe 6.71 4.50 -2.22 -0.148 0.37835E+04 50 chloritoid-Mg 13.20 10.63 -2.57 -0.171 0.43856E+04 51 chloritoid-Fe 9.17 8.41 -0.76 -0.051 0.13005E+04 52 chloritoid-Mn 11.40 10.20 -1.20 -0.080 0.20497E+04 54 coesite -2.38 -3.92 -1.54 -0.513 0.26280E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.92 -1.35 -0.452 0.23133E+04 67 diopside 16.18 11.77 -4.42 -0.442 0.75395E+04 68 hedenbergite 14.21 9.55 -4.66 -0.466 0.79564E+04 75 epidote 24.67 21.88 -2.79 -0.135 0.47581E+04 76 clinozoisite 22.81 18.47 -4.33 -0.197 0.73970E+04 77 epidote-Fe 29.84 25.29 -4.55 -0.236 0.77658E+04 78 fayalite 14.05 9.24 -4.80 -0.686 0.81984E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.353 0.72238E+04 92 hercynite 17.28 12.33 -4.95 -0.330 0.84544E+04 98 kaolinite -1.33 -2.08 -0.75 -0.068 0.12809E+04 99 kyanite 4.88 1.83 -3.04 -0.304 0.51974E+04 101 laumontite 2.88 0.89 -2.00 -0.133 0.34107E+04 102 lawsonite 9.62 8.72 -0.90 -0.060 0.15365E+04 105 lizardite 23.24 18.56 -4.68 -0.390 0.79966E+04 106 magnesite 0.69 -3.82 -4.51 -1.502 0.76944E+04 107 magnetite 20.09 19.15 -0.94 -0.077 0.16076E+04 110 magnesioferrite 26.21 21.36 -4.85 -0.396 0.82800E+04 113 margarite 17.32 14.46 -2.86 -0.114 0.48834E+04 116 microcline -2.49 -6.75 -4.26 -0.328 0.72823E+04 120 muscovite 2.58 -1.00 -3.59 -0.211 0.61239E+04 121 paragonite 4.24 0.80 -3.44 -0.203 0.58804E+04 136 prehnite 19.37 15.60 -3.77 -0.222 0.64401E+04 137 prehnite-Fe 22.50 19.01 -3.49 -0.210 0.59562E+04 145 pyroxmangite 7.40 4.45 -2.95 -0.589 0.50293E+04 146 pyrophyllite -6.18 -9.91 -3.74 -0.234 0.63816E+04 147 quartz -2.99 -3.92 -0.93 -0.309 0.15807E+04 151 rhodochrosite -0.98 -4.24 -3.27 -1.089 0.55799E+04 152 rhodonite 7.45 4.45 -2.99 -0.598 0.51095E+04 155 siderite -2.61 -6.03 -3.42 -1.142 0.58478E+04 156 sillimanite 5.26 1.83 -3.43 -0.343 0.58554E+04 163 stilbite -7.52 -10.86 -3.34 -0.159 0.56988E+04 164 stilpnomelane-Fe 13.02 8.38 -4.63 -0.138 0.79093E+04 168 sudoite 21.08 17.34 -3.73 -0.120 0.63759E+04 177 topaz-H 4.62 1.83 -2.79 -0.253 0.47575E+04 178 tridymite -2.63 -3.92 -1.29 -0.430 0.22006E+04 187 wairakite 3.95 0.89 -3.06 -0.180 0.52327E+04 188 walstromite 11.51 6.88 -4.63 -0.925 0.78975E+04 189 wollastonite 10.46 6.88 -3.58 -0.715 0.61079E+04 190 pseudo-wollastonite 11.00 6.88 -4.12 -0.823 0.70278E+04 191 zoisite 22.85 18.47 -4.38 -0.199 0.74711E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.89 -4.25 -0.263 0.72490E+04 196 beidellite-Mg -1.79 -6.22 -4.43 -0.274 0.75669E+04 199 chalcedony -2.80 -3.92 -1.11 -0.371 0.19000E+04 201 montmorillonite-Ca -2.29 -6.18 -3.89 -0.240 0.66352E+04 203 montmorillonite-Mg -2.48 -6.51 -4.03 -0.249 0.68763E+04 204 montmorillonite-Na -2.04 -6.67 -4.63 -0.283 0.79008E+04 205 nontronite-Ca 3.21 0.93 -2.29 -0.148 0.39047E+04 206 nontronite-H 2.53 -0.85 -3.39 -0.227 0.57829E+04 207 nontronite-K 3.34 -0.15 -3.50 -0.224 0.59679E+04 208 nontronite-Mg 3.07 0.60 -2.48 -0.161 0.42299E+04 209 nontronite-Na 3.52 0.44 -3.08 -0.198 0.52595E+04 214 gypsum -4.96 -9.23 -4.27 -1.068 0.72933E+04 224 tobermorite 9.82 5.08 -4.74 -1.294 0.80977E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.58 -3.23 -0.808 0.55183E+04 240 silica-amorphous -2.09 -3.92 -1.82 -0.608 0.31141E+04 242 an20ab80 2.02 -2.22 -4.24 -0.326 0.72329E+04 243 an25ab75 2.65 -1.53 -4.18 -0.322 0.71382E+04 244 an30ab70 3.28 -0.85 -4.13 -0.318 0.70530E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0132000 g New total amount of reactant added: 0.0136000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0136000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2880642E-03 Osmotic coef. = 0.9898 True ionic strength = .2956331E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20554E-07 -7.6871 0.19732E-07 -7.7048 0.95998E+00 -0.0177 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13242E-03 -3.8780 0.95986E+00 -0.0178 4 SO4-- 0.25311E-04 -4.5967 0.22674E-04 -4.6445 0.89581E+00 -0.0478 5 HCO3- 0.12480E-04 -4.9038 0.11979E-04 -4.9216 0.95989E+00 -0.0178 6 HS- 0.94470E-10 -10.0247 0.90678E-10 -10.0425 0.95986E+00 -0.0178 7 Al+++ 0.71967E-20 -20.1429 0.57437E-20 -20.2408 0.79810E+00 -0.0979 8 H4SiO4 0.12504E-03 -3.9029 0.12504E-03 -3.9029 0.10000E+01 0.0000 9 Ca++ 0.29657E-04 -4.5279 0.26563E-04 -4.5757 0.89567E+00 -0.0479 10 Mg++ 0.26803E-06 -6.5718 0.24005E-06 -6.6197 0.89558E+00 -0.0479 11 Fe++ 0.16205E-08 -8.7903 0.14513E-08 -8.8382 0.89561E+00 -0.0479 12 K+ 0.28864E-05 -5.5396 0.27706E-05 -5.5574 0.95989E+00 -0.0178 13 Na+ 0.17712E-03 -3.7517 0.17001E-03 -3.7695 0.95985E+00 -0.0178 14 Mn++ 0.10557E-06 -6.9764 0.94554E-07 -7.0243 0.89562E+00 -0.0479 15 HPO4-- 0.22372E-08 -8.6503 0.20041E-08 -8.6981 0.89582E+00 -0.0478 16 HSiO3- 0.61648E-05 -5.2101 0.59173E-05 -5.2279 0.95986E+00 -0.0178 17 Ca(HSiO3)+ 0.37292E-08 -8.4284 0.35796E-08 -8.4462 0.95990E+00 -0.0178 18 Mg(HSiO3)+ 0.41940E-10 -10.3774 0.40258E-10 -10.3951 0.95990E+00 -0.0178 19 NaHSiO3,aq 0.16270E-07 -7.7886 0.16270E-07 -7.7886 0.10000E+01 0.0000 20 AlO+ 0.20908E-11 -11.6797 0.20070E-11 -11.6975 0.95990E+00 -0.0178 21 AlOH+2 0.22016E-15 -15.6573 0.19719E-15 -15.7051 0.89564E+00 -0.0479 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.23675E-05 -5.6257 0.22724E-05 -5.6435 0.95982E+00 -0.0178 24 CH4,aq 0.46539E-16 -16.3322 0.46535E-16 -16.3322 0.99991E+00 0.0000 29 CO,aq 0.18241E-16 -16.7389 0.18241E-16 -16.7389 0.10000E+01 0.0000 30 CO2,aq 0.50510E-06 -6.2966 0.50506E-06 -6.2967 0.99991E+00 0.0000 31 CO3-2 0.59197E-07 -7.2277 0.53027E-07 -7.2755 0.89577E+00 -0.0478 32 CaCO3,aq 0.17662E-07 -7.7530 0.17662E-07 -7.7530 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.84616E-08 -8.0725 0.81223E-08 -8.0903 0.95990E+00 -0.0178 34 CaCl+ 0.59303E-08 -8.2269 0.56925E-08 -8.2447 0.95990E+00 -0.0178 35 CaCl2,aq 0.17909E-12 -12.7469 0.17909E-12 -12.7469 0.10000E+01 0.0000 36 CaOH+ 0.99952E-07 -7.0002 0.95944E-07 -7.0180 0.95990E+00 -0.0178 37 CaSO4,aq 0.19126E-06 -6.7184 0.19126E-06 -6.7184 0.10000E+01 0.0000 38 HCl,aq 0.47881E-12 -12.3198 0.47881E-12 -12.3198 0.10000E+01 0.0000 43 FeCl+ 0.31692E-12 -12.4991 0.30421E-12 -12.5168 0.95990E+00 -0.0178 46 FeO,aq 0.14488E-09 -9.8390 0.14488E-09 -9.8390 0.10000E+01 0.0000 47 FeOH+ 0.24943E-08 -8.6031 0.23943E-08 -8.6208 0.95990E+00 -0.0178 48 HFeO2- 0.80038E-10 -10.0967 0.76825E-10 -10.1145 0.95986E+00 -0.0178 49 FeO+ 0.15690E-12 -12.8044 0.15061E-12 -12.8221 0.95990E+00 -0.0178 50 FeOH+2 0.63365E-18 -18.1981 0.56753E-18 -18.2460 0.89564E+00 -0.0479 51 FeO2- 0.82465E-10 -10.0837 0.79154E-10 -10.1015 0.95986E+00 -0.0178 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.14379E-08 -8.8423 0.14378E-08 -8.8423 0.99991E+00 0.0000 54 KCl,aq 0.66497E-11 -11.1772 0.66497E-11 -11.1772 0.10000E+01 0.0000 55 KHSO4,aq 0.35048E-17 -17.4553 0.35048E-17 -17.4553 0.10000E+01 0.0000 56 KOH,aq 0.59965E-10 -10.2221 0.59965E-10 -10.2221 0.10000E+01 0.0000 57 KSO4- 0.10156E-08 -8.9933 0.97484E-09 -9.0111 0.95986E+00 -0.0178 58 MgCO3,aq 0.40006E-10 -10.3979 0.40006E-10 -10.3979 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.78135E-10 -10.1072 0.75001E-10 -10.1249 0.95990E+00 -0.0178 60 MgCl+ 0.48572E-10 -10.3136 0.46624E-10 -10.3314 0.95990E+00 -0.0178 61 MgOH+ 0.49981E-08 -8.3012 0.47977E-08 -8.3190 0.95990E+00 -0.0178 63 MnO,aq 0.25150E-09 -9.5995 0.25150E-09 -9.5995 0.10000E+01 0.0000 64 MnOH+ 0.15096E-07 -7.8211 0.14490E-07 -7.8389 0.95990E+00 -0.0178 65 MnO2-2 0.23932E-16 -16.6210 0.21438E-16 -16.6688 0.89577E+00 -0.0478 66 HMnO2- 0.96551E-13 -13.0152 0.92675E-13 -13.0330 0.95986E+00 -0.0178 69 MnCl+ 0.80326E-10 -10.0951 0.77105E-10 -10.1129 0.95990E+00 -0.0178 70 MnSO4,aq 0.61894E-09 -9.2084 0.61894E-09 -9.2084 0.10000E+01 0.0000 71 NaCl,aq 0.74607E-08 -8.1272 0.74607E-08 -8.1272 0.10000E+01 0.0000 72 NaOH,aq 0.37018E-08 -8.4316 0.37018E-08 -8.4316 0.10000E+01 0.0000 74 OH- 0.30507E-04 -4.5156 0.29281E-04 -4.5334 0.95982E+00 -0.0178 79 HPO3-2 0.10024E-19 -19.9989 0.89796E-20 -20.0467 0.89577E+00 -0.0478 82 H3PO4,aq 0.54573E-14 -14.2630 0.54573E-14 -14.2630 0.10000E+01 0.0000 83 H2PO4- 0.76000E-09 -9.1192 0.72950E-09 -9.1370 0.95988E+00 -0.0178 84 PO4-3 0.10372E-12 -12.9841 0.82870E-13 -13.0816 0.79897E+00 -0.0975 87 H2P2O7-2 0.46583E-19 -19.3318 0.41728E-19 -19.3796 0.89577E+00 -0.0478 88 HP2O7-3 0.52908E-18 -18.2765 0.42227E-18 -18.3744 0.79811E+00 -0.0979 90 H2S,aq 0.55303E-11 -11.2572 0.55298E-11 -11.2573 0.99991E+00 0.0000 96 SO2,aq 0.56684E-19 -19.2465 0.56684E-19 -19.2465 0.10000E+01 0.0000 97 SO3-2 0.47277E-14 -14.3253 0.42363E-14 -14.3730 0.89606E+00 -0.0477 98 HSO3- 0.54527E-14 -14.2634 0.52338E-14 -14.2812 0.95986E+00 -0.0178 99 HSO4- 0.44917E-09 -9.3476 0.43117E-09 -9.3654 0.95992E+00 -0.0178 101 S2O3-2 0.16442E-17 -17.7840 0.14729E-17 -17.8318 0.89577E+00 -0.0478 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2055424E-07 -.4590127E-04 -.4626459E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999738E+06 0.0000 3 Cl- 0.1379614E-03 0.1379749E-03 0.4891505E+01 3.8268 4 SO4-- 0.2531117E-04 0.2550418E-04 0.2449912E+01 10.7652 5 HCO3- 0.1247953E-04 0.1307007E-04 0.7974795E+00 2.7833 6 HS- 0.9446995E-10 0.4243154E-09 0.1403262E-04 -2.3377 7 Al+++ 0.7196684E-20 0.2387760E-05 0.6442378E-01 2.8737 8 H4SiO4 0.1250447E-03 0.1312296E-03 0.1261287E+02 -3.9029 9 Ca++ 0.2965703E-04 0.2998402E-04 0.1201670E+01 10.8339 10 Mg++ 0.2680326E-06 0.2732394E-06 0.6642834E-02 8.7900 11 Fe++ 0.1620522E-08 0.4621310E-08 0.2580800E-03 6.5714 12 K+ 0.2886406E-05 0.2887489E-05 0.1129038E+00 2.1474 13 Na+ 0.1771158E-03 0.1771432E-03 0.4072388E+01 3.9353 14 Mn++ 0.1055741E-06 0.1216208E-06 0.6681439E-02 8.3854 15 HPO4-- 0.2237221E-08 0.2997325E-08 0.2876732E-03 6.7116 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2121558E-03 -.4590103E-04 -.1662548E-03 0.0000000E+00 2 H2O 0.5550808E+02 0.5550799E+02 0.9388443E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2588137E-04 0.2550405E-04 0.3773267E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3769024E-06 0.4243132E-09 -.3773267E-06 0.0000000E+00 7 Al+++ 0.4434609E-04 0.2387748E-05 0.4195834E-04 0.0000000E+00 8 H4SiO4 0.1416138E-03 0.1312289E-03 0.1038497E-04 0.0000000E+00 9 Ca++ 0.3011300E-04 0.2998386E-04 0.1291362E-06 0.0000000E+00 10 Mg++ 0.1079365E-04 0.2732379E-06 0.1052041E-04 0.0000000E+00 11 Fe++ 0.9696917E-05 0.4621285E-08 0.9692296E-05 0.0000000E+00 12 K+ 0.2887473E-05 0.2887473E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1771423E-03 0.1771423E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2358049E-06 0.1216201E-06 0.1141848E-06 0.0000000E+00 15 HPO4-- 0.8047904E-07 0.2997309E-08 0.7748173E-07 0.0000000E+00 Chg. balance for solid moles: -.1800E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0136000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2583E-07 -7.588 0.1297E-04 -4.887 0.2887 0.4123E-05 clinochlore 0.2104E-05 -5.677 0.1170E-02 -2.932 26.02 0.4449E-03 daphnite 0.1335E-05 -5.875 0.9523E-03 -3.021 21.19 0.2886E-03 chlorite-Mn 0.2284E-07 -7.641 0.1619E-04 -4.791 0.3603 0.5160E-05 diaspore 0.3504E-04 -4.455 0.2102E-02 -2.677 46.77 0.6257E-03 hematite 0.1509E-05 -5.821 0.2410E-03 -3.618 5.364 0.4569E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6078E+00 0.6078E+00 1.0000 -0.216 daphnite 0.3856E+00 0.3856E+00 1.0000 -0.414 chlorite-Mn 0.6597E-02 0.6597E-02 1.0000 -2.181 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004494 g Volume = 0.001414 cm3 Porosity: 99.8594% V(tot) - V(min): 0.10040E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0136000 g log = -1.8665 Original solution: 1000.0103000 g Original solution / Rock added: 73530.17 (Water/Rock Ratio), log = 4.8665 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0204 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.5258E-04 1.0071 0.5404E-04 0.5365E-04 CH4,gas 0.6630E-13 1.0125 0.6850E-13 0.6765E-13 H2,gas 0.1849E-05 1.0005 0.1888E-05 0.1887E-05 H2S,gas 0.1496E-09 0.9960 0.1520E-09 0.1526E-09 S2,gas 0.2386E-27 1.0000 0.2434E-27 0.2434E-27 CO,gas 0.2664E-13 1.0000 0.2718E-13 0.2718E-13 SO3,gas 0.3271E-35 1.0000 0.3338E-35 0.3338E-35 SO2,gas 0.2402E-18 1.0000 0.2451E-18 0.2451E-18 HCl,gas 0.8280E-15 1.0000 0.8449E-15 0.8449E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.63 -5.97 -1.989 0.10187E+05 -4.267 3 CH4,gas 4.54 -10.32 -14.86 -3.716 0.25379E+05 -13.164 4 H2,gas 8.00 0.58 -7.42 -4.242 0.12675E+05 -5.724 5 H2S,gas -6.23 -17.75 -11.52 -5.759 0.19665E+05 -9.818 6 S2,gas -7.34 -36.65 -29.31 -4.510 0.50050E+05 -27.614 7 CO,gas 3.21 -12.05 -15.26 -4.697 0.26064E+05 -13.566 8 SO3,gas 17.12 -20.05 -37.18 -9.294 0.63476E+05 -35.477 9 SO2,gas 0.83 -19.48 -20.31 -5.416 0.34678E+05 -18.611 10 HCl,gas 5.19 -11.58 -16.77 -8.386 0.28638E+05 -15.073 16 albite -0.38 -4.90 -4.52 -0.347 0.77108E+04 20 analcite 3.32 -1.00 -4.32 -0.480 0.73741E+04 21 andalusite 5.00 1.84 -3.16 -0.316 0.53906E+04 24 anhydrite -5.32 -9.22 -3.90 -1.952 0.66649E+04 29 anorthite 12.71 8.78 -3.93 -0.303 0.67186E+04 35 aragonite 0.97 -1.79 -2.76 -0.920 0.47109E+04 36 brucite 12.57 8.79 -3.78 -0.756 0.64519E+04 37 calcite 0.81 -1.79 -2.60 -0.868 0.44467E+04 40 carpholite-Mg 8.58 6.73 -1.85 -0.123 0.31599E+04 41 carpholite-Fe 6.71 4.51 -2.20 -0.147 0.37559E+04 50 chloritoid-Mg 13.20 10.63 -2.56 -0.171 0.43767E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.051 0.12938E+04 52 chloritoid-Mn 11.40 10.23 -1.17 -0.078 0.19999E+04 54 coesite -2.38 -3.90 -1.53 -0.509 0.26071E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.90 -1.34 -0.448 0.22924E+04 67 diopside 16.18 11.82 -4.36 -0.436 0.74502E+04 68 hedenbergite 14.21 9.60 -4.61 -0.461 0.78693E+04 75 epidote 24.67 21.99 -2.68 -0.130 0.45766E+04 76 clinozoisite 22.81 18.58 -4.23 -0.192 0.72155E+04 77 epidote-Fe 29.84 25.40 -4.44 -0.231 0.75843E+04 78 fayalite 14.05 9.24 -4.81 -0.687 0.82057E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.353 0.72244E+04 91 heulandite -5.83 -10.74 -4.91 -0.223 0.83870E+04 92 hercynite 17.28 12.32 -4.96 -0.331 0.84686E+04 98 kaolinite -1.33 -2.06 -0.73 -0.066 0.12391E+04 99 kyanite 4.88 1.84 -3.03 -0.303 0.51765E+04 101 laumontite 2.88 0.97 -1.91 -0.128 0.32678E+04 102 lawsonite 9.62 8.78 -0.84 -0.056 0.14353E+04 105 lizardite 23.24 18.56 -4.68 -0.390 0.79907E+04 106 magnesite 0.69 -3.84 -4.53 -1.509 0.77298E+04 107 magnetite 20.09 19.14 -0.95 -0.078 0.16217E+04 110 magnesioferrite 26.21 21.36 -4.86 -0.396 0.82919E+04 113 margarite 17.32 14.52 -2.80 -0.112 0.47822E+04 116 microcline -2.49 -6.69 -4.20 -0.323 0.71734E+04 120 muscovite 2.58 -0.94 -3.52 -0.207 0.60150E+04 121 paragonite 4.24 0.85 -3.39 -0.200 0.57915E+04 136 prehnite 19.37 15.71 -3.67 -0.216 0.62586E+04 137 prehnite-Fe 22.50 19.12 -3.38 -0.203 0.57746E+04 145 pyroxmangite 7.40 4.48 -2.92 -0.583 0.49794E+04 146 pyrophyllite -6.18 -9.86 -3.69 -0.231 0.62981E+04 147 quartz -2.99 -3.90 -0.91 -0.304 0.15598E+04 151 rhodochrosite -0.98 -4.24 -3.26 -1.088 0.55745E+04 152 rhodonite 7.45 4.48 -2.96 -0.593 0.50597E+04 155 siderite -2.61 -6.05 -3.45 -1.149 0.58854E+04 156 sillimanite 5.26 1.84 -3.42 -0.342 0.58345E+04 163 stilbite -7.52 -10.74 -3.22 -0.153 0.54932E+04 164 stilpnomelane-Fe 13.02 8.45 -4.56 -0.136 0.77897E+04 168 sudoite 21.08 17.37 -3.71 -0.120 0.63372E+04 177 topaz-H 4.62 1.84 -2.77 -0.252 0.47366E+04 178 tridymite -2.63 -3.90 -1.28 -0.426 0.21798E+04 187 wairakite 3.95 0.97 -2.98 -0.175 0.50897E+04 188 walstromite 11.51 6.93 -4.58 -0.916 0.78172E+04 189 wollastonite 10.46 6.93 -3.53 -0.706 0.60276E+04 190 pseudo-wollastonite 11.00 6.93 -4.07 -0.814 0.69474E+04 191 zoisite 22.85 18.58 -4.27 -0.194 0.72896E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.84 -4.19 -0.260 0.71626E+04 196 beidellite-Mg -1.79 -6.18 -4.39 -0.271 0.74923E+04 197 beidellite-Na -1.34 -6.33 -4.99 -0.305 0.85155E+04 199 chalcedony -2.80 -3.90 -1.10 -0.367 0.18791E+04 201 montmorillonite-Ca -2.29 -6.12 -3.83 -0.237 0.65459E+04 202 montmorillonite-K -2.24 -7.20 -4.97 -0.304 0.84804E+04 203 montmorillonite-Mg -2.48 -6.46 -3.98 -0.246 0.67987E+04 204 montmorillonite-Na -2.04 -6.61 -4.58 -0.280 0.78126E+04 205 nontronite-Ca 3.21 0.98 -2.24 -0.145 0.38183E+04 206 nontronite-H 2.53 -0.81 -3.34 -0.224 0.57063E+04 207 nontronite-K 3.34 -0.10 -3.44 -0.221 0.58760E+04 208 nontronite-Mg 3.07 0.64 -2.43 -0.158 0.41552E+04 209 nontronite-Na 3.52 0.49 -3.03 -0.195 0.51742E+04 214 gypsum -4.96 -9.22 -4.27 -1.066 0.72825E+04 224 tobermorite 9.82 5.12 -4.70 -1.283 0.80274E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.57 -3.24 -0.810 0.55325E+04 240 silica-amorphous -2.09 -3.90 -1.81 -0.604 0.30933E+04 242 an20ab80 2.02 -2.16 -4.18 -0.322 0.71416E+04 243 an25ab75 2.65 -1.48 -4.13 -0.317 0.70462E+04 244 an30ab70 3.28 -0.80 -4.08 -0.314 0.69605E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0136000 g New total amount of reactant added: 0.0140000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0140000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2895632E-03 Osmotic coef. = 0.9898 True ionic strength = .2974934E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.19919E-07 -7.7007 0.19120E-07 -7.7185 0.95992E+00 -0.0178 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13241E-03 -3.8781 0.95979E+00 -0.0178 4 SO4-- 0.25308E-04 -4.5967 0.22665E-04 -4.6446 0.89556E+00 -0.0479 5 HCO3- 0.12492E-04 -4.9034 0.11990E-04 -4.9212 0.95982E+00 -0.0178 6 HS- 0.79060E-10 -10.1020 0.75881E-10 -10.1199 0.95979E+00 -0.0178 7 Al+++ 0.65525E-20 -20.1836 0.52262E-20 -20.2818 0.79759E+00 -0.0982 8 H4SiO4 0.12851E-03 -3.8911 0.12851E-03 -3.8911 0.10000E+01 0.0000 9 Ca++ 0.30104E-04 -4.5214 0.26956E-04 -4.5693 0.89542E+00 -0.0480 10 Mg++ 0.24782E-06 -6.6059 0.22188E-06 -6.6539 0.89533E+00 -0.0480 11 Fe++ 0.14945E-08 -8.8255 0.13381E-08 -8.8735 0.89535E+00 -0.0480 12 K+ 0.29713E-05 -5.5271 0.28519E-05 -5.5449 0.95982E+00 -0.0178 13 Na+ 0.17762E-03 -3.7505 0.17047E-03 -3.7683 0.95979E+00 -0.0178 14 Mn++ 0.10268E-06 -6.9885 0.91937E-07 -7.0365 0.89537E+00 -0.0480 15 HPO4-- 0.20940E-08 -8.6790 0.18754E-08 -8.7269 0.89556E+00 -0.0479 16 HSiO3- 0.65386E-05 -5.1845 0.62757E-05 -5.2023 0.95979E+00 -0.0178 17 Ca(HSiO3)+ 0.40137E-08 -8.3964 0.38525E-08 -8.4143 0.95983E+00 -0.0178 18 Mg(HSiO3)+ 0.41116E-10 -10.3860 0.39465E-10 -10.4038 0.95983E+00 -0.0178 19 NaHSiO3,aq 0.17303E-07 -7.7619 0.17303E-07 -7.7619 0.10000E+01 0.0000 20 AlO+ 0.20262E-11 -11.6933 0.19448E-11 -11.7111 0.95983E+00 -0.0178 21 AlOH+2 0.20679E-15 -15.6845 0.18516E-15 -15.7325 0.89539E+00 -0.0480 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.24434E-05 -5.6120 0.23450E-05 -5.6299 0.95975E+00 -0.0178 24 CH4,aq 0.38996E-16 -16.4090 0.38992E-16 -16.4090 0.99991E+00 0.0000 29 CO,aq 0.17057E-16 -16.7681 0.17057E-16 -16.7681 0.10000E+01 0.0000 30 CO2,aq 0.48990E-06 -6.3099 0.48986E-06 -6.3099 0.99991E+00 0.0000 31 CO3-2 0.61162E-07 -7.2135 0.54772E-07 -7.2614 0.89552E+00 -0.0479 32 CaCO3,aq 0.18513E-07 -7.7325 0.18513E-07 -7.7325 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.85952E-08 -8.0657 0.82499E-08 -8.0836 0.95983E+00 -0.0178 34 CaCl+ 0.60180E-08 -8.2205 0.57762E-08 -8.2384 0.95983E+00 -0.0178 35 CaCl2,aq 0.18171E-12 -12.7406 0.18171E-12 -12.7406 0.10000E+01 0.0000 36 CaOH+ 0.10468E-06 -6.9801 0.10047E-06 -6.9979 0.95983E+00 -0.0178 37 CaSO4,aq 0.19401E-06 -6.7122 0.19401E-06 -6.7122 0.10000E+01 0.0000 38 HCl,aq 0.46394E-12 -12.3335 0.46394E-12 -12.3335 0.10000E+01 0.0000 43 FeCl+ 0.29219E-12 -12.5343 0.28045E-12 -12.5521 0.95983E+00 -0.0178 46 FeO,aq 0.14225E-09 -9.8469 0.14225E-09 -9.8469 0.10000E+01 0.0000 47 FeOH+ 0.23734E-08 -8.6246 0.22780E-08 -8.6424 0.95983E+00 -0.0178 48 HFeO2- 0.81106E-10 -10.0909 0.77845E-10 -10.1088 0.95979E+00 -0.0178 49 FeO+ 0.15205E-12 -12.8180 0.14594E-12 -12.8358 0.95983E+00 -0.0178 50 FeOH+2 0.59517E-18 -18.2254 0.53291E-18 -18.2733 0.89539E+00 -0.0480 51 FeO2- 0.85107E-10 -10.0700 0.81685E-10 -10.0879 0.95979E+00 -0.0178 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.13862E-08 -8.8582 0.13861E-08 -8.8582 0.99991E+00 0.0000 54 KCl,aq 0.68443E-11 -11.1647 0.68443E-11 -11.1647 0.10000E+01 0.0000 55 KHSO4,aq 0.34945E-17 -17.4566 0.34945E-17 -17.4566 0.10000E+01 0.0000 56 KOH,aq 0.63698E-10 -10.1959 0.63698E-10 -10.1959 0.10000E+01 0.0000 57 KSO4- 0.10451E-08 -8.9809 0.10031E-08 -8.9987 0.95979E+00 -0.0178 58 MgCO3,aq 0.38195E-10 -10.4180 0.38195E-10 -10.4180 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72292E-10 -10.1409 0.69388E-10 -10.1587 0.95983E+00 -0.0178 60 MgCl+ 0.44896E-10 -10.3478 0.43093E-10 -10.3656 0.95983E+00 -0.0178 61 MgOH+ 0.47679E-08 -8.3217 0.45764E-08 -8.3395 0.95983E+00 -0.0178 63 MnO,aq 0.26043E-09 -9.5843 0.26043E-09 -9.5843 0.10000E+01 0.0000 64 MnOH+ 0.15148E-07 -7.8196 0.14540E-07 -7.8374 0.95983E+00 -0.0178 65 MnO2-2 0.26399E-16 -16.5784 0.23641E-16 -16.6263 0.89552E+00 -0.0479 66 HMnO2- 0.10318E-12 -12.9864 0.99031E-13 -13.0042 0.95979E+00 -0.0178 69 MnCl+ 0.78102E-10 -10.1073 0.74965E-10 -10.1251 0.95983E+00 -0.0178 70 MnSO4,aq 0.60157E-09 -9.2207 0.60157E-09 -9.2207 0.10000E+01 0.0000 71 NaCl,aq 0.74808E-08 -8.1261 0.74808E-08 -8.1261 0.10000E+01 0.0000 72 NaOH,aq 0.38307E-08 -8.4167 0.38307E-08 -8.4167 0.10000E+01 0.0000 74 OH- 0.31485E-04 -4.5019 0.30218E-04 -4.5197 0.95975E+00 -0.0178 82 H3PO4,aq 0.47951E-14 -14.3192 0.47951E-14 -14.3192 0.10000E+01 0.0000 83 H2PO4- 0.68917E-09 -9.1617 0.66148E-09 -9.1795 0.95981E+00 -0.0178 84 PO4-3 0.10022E-12 -12.9990 0.80024E-13 -13.0968 0.79846E+00 -0.0977 87 H2P2O7-2 0.38311E-19 -19.4167 0.34308E-19 -19.4646 0.89552E+00 -0.0479 88 HP2O7-3 0.44920E-18 -18.3476 0.35828E-18 -18.4458 0.79760E+00 -0.0982 90 H2S,aq 0.44845E-11 -11.3483 0.44841E-11 -11.3483 0.99991E+00 0.0000 96 SO2,aq 0.51295E-19 -19.2899 0.51295E-19 -19.2899 0.10000E+01 0.0000 97 SO3-2 0.45575E-14 -14.3413 0.40826E-14 -14.3891 0.89581E+00 -0.0478 98 HSO3- 0.50924E-14 -14.2931 0.48876E-14 -14.3109 0.95979E+00 -0.0178 99 HSO4- 0.43512E-09 -9.3614 0.41765E-09 -9.3792 0.95985E+00 -0.0178 101 S2O3-2 0.13332E-17 -17.8751 0.11939E-17 -17.9230 0.89552E+00 -0.0479 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1991886E-07 -.4758070E-04 -.4795729E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999734E+06 0.0000 3 Cl- 0.1379613E-03 0.1379749E-03 0.4891503E+01 3.8404 4 SO4-- 0.2530844E-04 0.2550421E-04 0.2449915E+01 10.7924 5 HCO3- 0.1249179E-04 0.1307007E-04 0.7974793E+00 2.7973 6 HS- 0.7906012E-10 0.3946214E-09 0.1305059E-04 -2.4014 7 Al+++ 0.6552491E-20 0.2463625E-05 0.6647064E-01 2.8737 8 H4SiO4 0.1285080E-03 0.1350679E-03 0.1298178E+02 -3.8911 9 Ca++ 0.3010396E-04 0.3043978E-04 0.1219935E+01 10.8677 10 Mg++ 0.2478166E-06 0.2527810E-06 0.6145458E-02 8.7831 11 Fe++ 0.1494520E-08 0.4375463E-08 0.2443504E-03 6.5635 12 K+ 0.2971300E-05 0.2972415E-05 0.1162245E+00 2.1736 13 Na+ 0.1776168E-03 0.1776454E-03 0.4083930E+01 3.9502 14 Mn++ 0.1026802E-06 0.1187686E-06 0.6524746E-02 8.4005 15 HPO4-- 0.2094046E-08 0.2783326E-08 0.2671342E-03 6.7101 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2187792E-03 -.4758044E-04 -.1711988E-03 0.0000000E+00 2 H2O 0.5550807E+02 0.5550798E+02 0.9664848E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2589246E-04 0.2550408E-04 0.3883823E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3879877E-06 0.3946192E-09 -.3883823E-06 0.0000000E+00 7 Al+++ 0.4565038E-04 0.2463612E-05 0.4318677E-04 0.0000000E+00 8 H4SiO4 0.1457790E-03 0.1350672E-03 0.1071179E-04 0.0000000E+00 9 Ca++ 0.3057306E-04 0.3043962E-04 0.1334379E-06 0.0000000E+00 10 Mg++ 0.1111111E-04 0.2527796E-06 0.1085833E-04 0.0000000E+00 11 Fe++ 0.9982120E-05 0.4375440E-08 0.9977745E-05 0.0000000E+00 12 K+ 0.2972399E-05 0.2972399E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1776444E-03 0.1776444E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2427403E-06 0.1187679E-06 0.1239724E-06 0.0000000E+00 15 HPO4-- 0.8284607E-07 0.2783311E-08 0.8006276E-07 0.0000000E+00 Chg. balance for solid moles: -.2324E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0140000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2669E-07 -7.574 0.1341E-04 -4.873 0.2896 0.4260E-05 clinochlore 0.2172E-05 -5.663 0.1207E-02 -2.918 26.08 0.4591E-03 daphnite 0.1374E-05 -5.862 0.9805E-03 -3.009 21.18 0.2971E-03 chlorite-Mn 0.2479E-07 -7.606 0.1758E-04 -4.755 0.3797 0.5602E-05 diaspore 0.3605E-04 -4.443 0.2162E-02 -2.665 46.71 0.6438E-03 hematite 0.1554E-05 -5.809 0.2481E-03 -3.605 5.360 0.4702E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6082E+00 0.6082E+00 1.0000 -0.216 daphnite 0.3848E+00 0.3848E+00 1.0000 -0.415 chlorite-Mn 0.6944E-02 0.6944E-02 1.0000 -2.158 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004629 g Volume = 0.001457 cm3 Porosity: 99.8551% V(tot) - V(min): 0.10041E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0140000 g log = -1.8539 Original solution: 1000.0103000 g Original solution / Rock added: 71429.31 (Water/Rock Ratio), log = 4.8539 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.5100E-04 1.0071 0.5241E-04 0.5204E-04 CH4,gas 0.5555E-13 1.0125 0.5739E-13 0.5668E-13 H2,gas 0.1783E-05 1.0005 0.1820E-05 0.1819E-05 H2S,gas 0.1213E-09 0.9960 0.1233E-09 0.1238E-09 S2,gas 0.1688E-27 1.0000 0.1722E-27 0.1722E-27 CO,gas 0.2491E-13 1.0000 0.2542E-13 0.2542E-13 SO3,gas 0.3071E-35 1.0000 0.3133E-35 0.3133E-35 SO2,gas 0.2174E-18 1.0000 0.2218E-18 0.2218E-18 HCl,gas 0.8023E-15 1.0000 0.8186E-15 0.8186E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.64 -5.98 -1.993 0.10210E+05 -4.281 3 CH4,gas 4.54 -10.40 -14.94 -3.735 0.25510E+05 -13.241 4 H2,gas 8.00 0.56 -7.44 -4.251 0.12702E+05 -5.740 5 H2S,gas -6.23 -17.84 -11.61 -5.804 0.19821E+05 -9.909 6 S2,gas -7.34 -36.80 -29.46 -4.533 0.50307E+05 -27.764 7 CO,gas 3.21 -12.08 -15.29 -4.706 0.26114E+05 -13.595 8 SO3,gas 17.12 -20.08 -37.20 -9.301 0.63523E+05 -35.504 9 SO2,gas 0.83 -19.52 -20.35 -5.427 0.34752E+05 -18.654 10 HCl,gas 5.19 -11.60 -16.79 -8.393 0.28661E+05 -15.087 16 albite -0.38 -4.85 -4.47 -0.343 0.76247E+04 20 analcite 3.32 -0.96 -4.28 -0.476 0.73082E+04 21 andalusite 5.00 1.86 -3.15 -0.315 0.53703E+04 24 anhydrite -5.32 -9.21 -3.90 -1.949 0.66543E+04 29 anorthite 12.71 8.83 -3.88 -0.298 0.66206E+04 35 aragonite 0.97 -1.77 -2.74 -0.913 0.46760E+04 36 brucite 12.57 8.78 -3.79 -0.757 0.64635E+04 37 calcite 0.81 -1.77 -2.58 -0.861 0.44118E+04 40 carpholite-Mg 8.58 6.75 -1.83 -0.122 0.31310E+04 41 carpholite-Fe 6.71 4.53 -2.18 -0.146 0.37289E+04 50 chloritoid-Mg 13.20 10.64 -2.56 -0.171 0.43682E+04 51 chloritoid-Fe 9.17 8.42 -0.75 -0.050 0.12871E+04 52 chloritoid-Mn 11.40 10.26 -1.14 -0.076 0.19538E+04 54 coesite -2.38 -3.89 -1.52 -0.505 0.25868E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.89 -1.33 -0.444 0.22722E+04 67 diopside 16.18 11.87 -4.31 -0.431 0.73639E+04 68 hedenbergite 14.21 9.65 -4.56 -0.456 0.77848E+04 75 epidote 24.67 22.09 -2.58 -0.125 0.44007E+04 76 clinozoisite 22.81 18.68 -4.12 -0.187 0.70396E+04 77 epidote-Fe 29.84 25.50 -4.34 -0.225 0.74084E+04 78 fayalite 14.05 9.24 -4.81 -0.687 0.82126E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.353 0.72246E+04 91 heulandite -5.83 -10.62 -4.80 -0.218 0.81877E+04 92 hercynite 17.28 12.31 -4.97 -0.331 0.84821E+04 98 kaolinite -1.33 -2.03 -0.70 -0.064 0.11986E+04 99 kyanite 4.88 1.86 -3.02 -0.302 0.51562E+04 101 laumontite 2.88 1.05 -1.83 -0.122 0.31292E+04 102 lawsonite 9.62 8.83 -0.78 -0.052 0.13372E+04 105 lizardite 23.24 18.57 -4.68 -0.390 0.79852E+04 106 magnesite 0.69 -3.86 -4.55 -1.516 0.77642E+04 107 magnetite 20.09 19.13 -0.96 -0.078 0.16353E+04 110 magnesioferrite 26.21 21.35 -4.86 -0.397 0.83036E+04 113 margarite 17.32 14.58 -2.74 -0.110 0.46841E+04 116 microcline -2.49 -6.63 -4.14 -0.318 0.70679E+04 120 muscovite 2.58 -0.88 -3.46 -0.204 0.59094E+04 121 paragonite 4.24 0.90 -3.34 -0.197 0.57053E+04 136 prehnite 19.37 15.81 -3.56 -0.210 0.60827E+04 137 prehnite-Fe 22.50 19.22 -3.28 -0.197 0.55988E+04 145 pyroxmangite 7.40 4.51 -2.89 -0.578 0.49333E+04 146 pyrophyllite -6.18 -9.82 -3.64 -0.228 0.62171E+04 147 quartz -2.99 -3.89 -0.90 -0.301 0.15395E+04 151 rhodochrosite -0.98 -4.24 -3.26 -1.088 0.55713E+04 152 rhodonite 7.45 4.51 -2.94 -0.587 0.50136E+04 155 siderite -2.61 -6.08 -3.47 -1.156 0.59216E+04 156 sillimanite 5.26 1.86 -3.41 -0.341 0.58143E+04 163 stilbite -7.52 -10.62 -3.10 -0.148 0.52938E+04 164 stilpnomelane-Fe 13.02 8.52 -4.49 -0.134 0.76731E+04 168 sudoite 21.08 17.39 -3.69 -0.119 0.62998E+04 177 topaz-H 4.62 1.86 -2.76 -0.251 0.47163E+04 178 tridymite -2.63 -3.89 -1.26 -0.422 0.21595E+04 187 wairakite 3.95 1.05 -2.90 -0.171 0.49511E+04 188 walstromite 11.51 6.98 -4.53 -0.907 0.77394E+04 189 wollastonite 10.46 6.98 -3.48 -0.697 0.59498E+04 190 pseudo-wollastonite 11.00 6.98 -4.02 -0.805 0.68696E+04 191 zoisite 22.85 18.68 -4.17 -0.189 0.71137E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.79 -4.15 -0.256 0.70787E+04 196 beidellite-Mg -1.79 -6.14 -4.35 -0.269 0.74199E+04 197 beidellite-Na -1.34 -6.28 -4.94 -0.302 0.84327E+04 199 chalcedony -2.80 -3.89 -1.09 -0.363 0.18588E+04 201 montmorillonite-Ca -2.29 -6.07 -3.78 -0.234 0.64592E+04 202 montmorillonite-K -2.24 -7.15 -4.91 -0.301 0.83884E+04 203 montmorillonite-Mg -2.48 -6.42 -3.94 -0.244 0.67235E+04 204 montmorillonite-Na -2.04 -6.56 -4.53 -0.277 0.77270E+04 205 nontronite-Ca 3.21 1.03 -2.19 -0.142 0.37344E+04 206 nontronite-H 2.53 -0.77 -3.30 -0.221 0.56320E+04 207 nontronite-K 3.34 -0.05 -3.39 -0.218 0.57868E+04 208 nontronite-Mg 3.07 0.68 -2.39 -0.155 0.40828E+04 209 nontronite-Na 3.52 0.54 -2.98 -0.191 0.50915E+04 214 gypsum -4.96 -9.21 -4.26 -1.065 0.72719E+04 224 tobermorite 9.82 5.16 -4.66 -1.272 0.79592E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.56 -3.25 -0.812 0.55460E+04 240 silica-amorphous -2.09 -3.89 -1.80 -0.600 0.30730E+04 242 an20ab80 2.02 -2.11 -4.13 -0.318 0.70530E+04 243 an25ab75 2.65 -1.43 -4.07 -0.313 0.69571E+04 244 an30ab70 3.28 -0.74 -4.02 -0.310 0.68707E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0140000 g New total amount of reactant added: 0.0144000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0144000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2910648E-03 Osmotic coef. = 0.9898 True ionic strength = .2993597E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.19324E-07 -7.7139 0.18548E-07 -7.7317 0.95985E+00 -0.0178 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13240E-03 -3.8781 0.95972E+00 -0.0179 4 SO4-- 0.25306E-04 -4.5968 0.22656E-04 -4.6448 0.89531E+00 -0.0480 5 HCO3- 0.12503E-04 -4.9030 0.12000E-04 -4.9208 0.95975E+00 -0.0178 6 HS- 0.66602E-10 -10.1765 0.63919E-10 -10.1944 0.95972E+00 -0.0179 7 Al+++ 0.59856E-20 -20.2229 0.47711E-20 -20.3214 0.79709E+00 -0.0985 8 H4SiO4 0.13196E-03 -3.8795 0.13196E-03 -3.8795 0.10000E+01 0.0000 9 Ca++ 0.30551E-04 -4.5150 0.27348E-04 -4.5631 0.89517E+00 -0.0481 10 Mg++ 0.22971E-06 -6.6388 0.20561E-06 -6.6870 0.89508E+00 -0.0481 11 Fe++ 0.13823E-08 -8.8594 0.12373E-08 -8.9075 0.89510E+00 -0.0481 12 K+ 0.30562E-05 -5.5148 0.29332E-05 -5.5327 0.95976E+00 -0.0178 13 Na+ 0.17812E-03 -3.7493 0.17094E-03 -3.7671 0.95972E+00 -0.0179 14 Mn++ 0.99704E-07 -7.0013 0.89247E-07 -7.0494 0.89511E+00 -0.0481 15 HPO4-- 0.19636E-08 -8.7069 0.17581E-08 -8.7550 0.89531E+00 -0.0480 16 HSiO3- 0.69219E-05 -5.1598 0.66431E-05 -5.1776 0.95972E+00 -0.0179 17 Ca(HSiO3)+ 0.43109E-08 -8.3654 0.41375E-08 -8.3833 0.95976E+00 -0.0178 18 Mg(HSiO3)+ 0.40335E-10 -10.3943 0.38712E-10 -10.4122 0.95976E+00 -0.0178 19 NaHSiO3,aq 0.18367E-07 -7.7360 0.18367E-07 -7.7360 0.10000E+01 0.0000 20 AlO+ 0.19657E-11 -11.7065 0.18866E-11 -11.7243 0.95976E+00 -0.0178 21 AlOH+2 0.19466E-15 -15.7107 0.17425E-15 -15.7588 0.89513E+00 -0.0481 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.25189E-05 -5.5988 0.24173E-05 -5.6167 0.95968E+00 -0.0179 24 CH4,aq 0.32888E-16 -16.4830 0.32885E-16 -16.4830 0.99991E+00 0.0000 29 CO,aq 0.15988E-16 -16.7962 0.15988E-16 -16.7962 0.10000E+01 0.0000 30 CO2,aq 0.47564E-06 -6.3227 0.47560E-06 -6.3228 0.99991E+00 0.0000 31 CO3-2 0.63119E-07 -7.1998 0.56508E-07 -7.2479 0.89527E+00 -0.0480 32 CaCO3,aq 0.19378E-07 -7.7127 0.19378E-07 -7.7127 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.87282E-08 -8.0591 0.83770E-08 -8.0769 0.95976E+00 -0.0178 34 CaCl+ 0.61056E-08 -8.2143 0.58599E-08 -8.2321 0.95976E+00 -0.0178 35 CaCl2,aq 0.18433E-12 -12.7344 0.18433E-12 -12.7344 0.10000E+01 0.0000 36 CaOH+ 0.10949E-06 -6.9606 0.10508E-06 -6.9785 0.95976E+00 -0.0178 37 CaSO4,aq 0.19676E-06 -6.7061 0.19676E-06 -6.7061 0.10000E+01 0.0000 38 HCl,aq 0.45003E-12 -12.3468 0.45003E-12 -12.3468 0.10000E+01 0.0000 43 FeCl+ 0.27017E-12 -12.5684 0.25930E-12 -12.5862 0.95976E+00 -0.0178 46 FeO,aq 0.13977E-09 -9.8546 0.13977E-09 -9.8546 0.10000E+01 0.0000 47 FeOH+ 0.22624E-08 -8.6454 0.21713E-08 -8.6633 0.95976E+00 -0.0178 48 HFeO2- 0.82155E-10 -10.0854 0.78845E-10 -10.1032 0.95972E+00 -0.0179 49 FeO+ 0.14751E-12 -12.8312 0.14158E-12 -12.8490 0.95976E+00 -0.0178 50 FeOH+2 0.56025E-18 -18.2516 0.50150E-18 -18.2997 0.89513E+00 -0.0481 51 FeO2- 0.87738E-10 -10.0568 0.84204E-10 -10.0747 0.95972E+00 -0.0179 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.13383E-08 -8.8734 0.13382E-08 -8.8735 0.99991E+00 0.0000 54 KCl,aq 0.70389E-11 -11.1525 0.70389E-11 -11.1525 0.10000E+01 0.0000 55 KHSO4,aq 0.34852E-17 -17.4578 0.34852E-17 -17.4578 0.10000E+01 0.0000 56 KOH,aq 0.67534E-10 -10.1705 0.67534E-10 -10.1705 0.10000E+01 0.0000 57 KSO4- 0.10745E-08 -8.9688 0.10312E-08 -8.9866 0.95972E+00 -0.0179 58 MgCO3,aq 0.36517E-10 -10.4375 0.36517E-10 -10.4375 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.67052E-10 -10.1736 0.64354E-10 -10.1914 0.95976E+00 -0.0178 60 MgCl+ 0.41604E-10 -10.3809 0.39930E-10 -10.3987 0.95976E+00 -0.0178 61 MgOH+ 0.45549E-08 -8.3415 0.43716E-08 -8.3594 0.95976E+00 -0.0178 63 MnO,aq 0.26864E-09 -9.5708 0.26864E-09 -9.5708 0.10000E+01 0.0000 64 MnOH+ 0.15160E-07 -7.8193 0.14550E-07 -7.8371 0.95976E+00 -0.0178 65 MnO2-2 0.28945E-16 -16.5384 0.25914E-16 -16.5865 0.89527E+00 -0.0480 66 HMnO2- 0.10972E-12 -12.9597 0.10530E-12 -12.9776 0.95972E+00 -0.0179 69 MnCl+ 0.75817E-10 -10.1202 0.72766E-10 -10.1381 0.95976E+00 -0.0178 70 MnSO4,aq 0.58374E-09 -9.2338 0.58374E-09 -9.2338 0.10000E+01 0.0000 71 NaCl,aq 0.75008E-08 -8.1249 0.75008E-08 -8.1249 0.10000E+01 0.0000 72 NaOH,aq 0.39597E-08 -8.4023 0.39597E-08 -8.4023 0.10000E+01 0.0000 74 OH- 0.32458E-04 -4.4887 0.31150E-04 -4.5065 0.95968E+00 -0.0179 82 H3PO4,aq 0.42303E-14 -14.3736 0.42303E-14 -14.3736 0.10000E+01 0.0000 83 H2PO4- 0.62679E-09 -9.2029 0.60155E-09 -9.2207 0.95974E+00 -0.0178 84 PO4-3 0.96912E-13 -13.0136 0.77332E-13 -13.1116 0.79796E+00 -0.0980 87 H2P2O7-2 0.31693E-19 -19.4990 0.28374E-19 -19.5471 0.89527E+00 -0.0480 88 HP2O7-3 0.38320E-18 -18.4166 0.30545E-18 -18.5151 0.79710E+00 -0.0985 90 H2S,aq 0.36646E-11 -11.4360 0.36642E-11 -11.4360 0.99991E+00 0.0000 96 SO2,aq 0.46584E-19 -19.3318 0.46584E-19 -19.3318 0.10000E+01 0.0000 97 SO3-2 0.43994E-14 -14.3566 0.39399E-14 -14.4045 0.89556E+00 -0.0479 98 HSO3- 0.47677E-14 -14.3217 0.45756E-14 -14.3396 0.95972E+00 -0.0179 99 HSO4- 0.42196E-09 -9.3747 0.40499E-09 -9.3926 0.95978E+00 -0.0178 101 S2O3-2 0.10893E-17 -17.9629 0.97520E-18 -18.0109 0.89527E+00 -0.0480 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1932430E-07 -.4926321E-04 -.4965311E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999730E+06 0.0000 3 Cl- 0.1379612E-03 0.1379750E-03 0.4891502E+01 3.8536 4 SO4-- 0.2530571E-04 0.2550424E-04 0.2449916E+01 10.8186 5 HCO3- 0.1250310E-04 0.1307007E-04 0.7974791E+00 2.8109 6 HS- 0.6660154E-10 0.3690288E-09 0.1220421E-04 -2.4627 7 Al+++ 0.5985620E-20 0.2539157E-05 0.6850853E-01 2.8737 8 H4SiO4 0.1319628E-03 0.1389075E-03 0.1335081E+02 -3.8795 9 Ca++ 0.3055082E-04 0.3089558E-04 0.1238202E+01 10.9003 10 Mg++ 0.2297107E-06 0.2344511E-06 0.5699830E-02 8.7764 11 Fe++ 0.1382291E-08 0.4153397E-08 0.2319489E-03 6.5559 12 K+ 0.3056193E-05 0.3057342E-05 0.1195452E+00 2.1990 13 Na+ 0.1781177E-03 0.1781475E-03 0.4095472E+01 3.9645 14 Mn++ 0.9970440E-07 0.1157923E-06 0.6361238E-02 8.4140 15 HPO4-- 0.1963630E-08 0.2590519E-08 0.2486291E-03 6.7084 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2254026E-03 -.4926294E-04 -.1761397E-03 0.0000000E+00 2 H2O 0.5550807E+02 0.5550797E+02 0.9941241E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2590354E-04 0.2550410E-04 0.3994421E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3990731E-06 0.3690267E-09 -.3994421E-06 0.0000000E+00 7 Al+++ 0.4695468E-04 0.2539143E-05 0.4441554E-04 0.0000000E+00 8 H4SiO4 0.1499441E-03 0.1389067E-03 0.1103738E-04 0.0000000E+00 9 Ca++ 0.3103311E-04 0.3089541E-04 0.1377043E-06 0.0000000E+00 10 Mg++ 0.1142857E-04 0.2344498E-06 0.1119412E-04 0.0000000E+00 11 Fe++ 0.1026732E-04 0.4153374E-08 0.1026317E-04 0.0000000E+00 12 K+ 0.3057325E-05 0.3057325E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1781465E-03 0.1781465E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2496758E-06 0.1157917E-06 0.1338841E-06 0.0000000E+00 15 HPO4-- 0.8521310E-07 0.2590504E-08 0.8262260E-07 0.0000000E+00 Chg. balance for solid moles: 0.1398E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0144000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2754E-07 -7.560 0.1383E-04 -4.859 0.2904 0.4396E-05 clinochlore 0.2239E-05 -5.650 0.1244E-02 -2.905 26.12 0.4733E-03 daphnite 0.1414E-05 -5.850 0.1009E-02 -2.996 21.17 0.3056E-03 chlorite-Mn 0.2678E-07 -7.572 0.1898E-04 -4.722 0.3985 0.6050E-05 diaspore 0.3706E-04 -4.431 0.2223E-02 -2.653 46.66 0.6618E-03 hematite 0.1598E-05 -5.796 0.2552E-03 -3.593 5.356 0.4836E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6085E+00 0.6085E+00 1.0000 -0.216 daphnite 0.3842E+00 0.3842E+00 1.0000 -0.415 chlorite-Mn 0.7278E-02 0.7278E-02 1.0000 -2.138 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004764 g Volume = 0.001500 cm3 Porosity: 99.8509% V(tot) - V(min): 0.10043E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0144000 g log = -1.8416 Original solution: 1000.0103000 g Original solution / Rock added: 69445.16 (Water/Rock Ratio), log = 4.8416 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4952E-04 1.0071 0.5088E-04 0.5053E-04 CH4,gas 0.4685E-13 1.0125 0.4841E-13 0.4781E-13 H2,gas 0.1721E-05 1.0005 0.1757E-05 0.1756E-05 H2S,gas 0.9911E-10 0.9960 0.1007E-09 0.1011E-09 S2,gas 0.1209E-27 1.0000 0.1234E-27 0.1234E-27 CO,gas 0.2335E-13 1.0000 0.2382E-13 0.2382E-13 SO3,gas 0.2888E-35 1.0000 0.2947E-35 0.2947E-35 SO2,gas 0.1974E-18 1.0000 0.2014E-18 0.2014E-18 HCl,gas 0.7783E-15 1.0000 0.7941E-15 0.7941E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.65 -5.99 -1.997 0.10232E+05 -4.293 3 CH4,gas 4.54 -10.47 -15.01 -3.754 0.25636E+05 -13.315 4 H2,gas 8.00 0.55 -7.45 -4.260 0.12728E+05 -5.755 5 H2S,gas -6.23 -17.93 -11.70 -5.848 0.19970E+05 -9.997 6 S2,gas -7.34 -36.94 -29.61 -4.555 0.50554E+05 -27.909 7 CO,gas 3.21 -12.11 -15.32 -4.714 0.26162E+05 -13.623 8 SO3,gas 17.12 -20.11 -37.23 -9.307 0.63568E+05 -35.531 9 SO2,gas 0.83 -19.56 -20.39 -5.439 0.34824E+05 -18.696 10 HCl,gas 5.19 -11.61 -16.80 -8.400 0.28684E+05 -15.100 16 albite -0.38 -4.80 -4.42 -0.340 0.75411E+04 20 analcite 3.32 -0.92 -4.24 -0.471 0.72443E+04 21 andalusite 5.00 1.87 -3.13 -0.313 0.53507E+04 24 anhydrite -5.32 -9.21 -3.89 -1.946 0.66439E+04 29 anorthite 12.71 8.89 -3.82 -0.294 0.65255E+04 35 aragonite 0.97 -1.75 -2.72 -0.906 0.46421E+04 36 brucite 12.57 8.78 -3.79 -0.758 0.64750E+04 37 calcite 0.81 -1.75 -2.56 -0.855 0.43779E+04 40 carpholite-Mg 8.58 6.76 -1.82 -0.121 0.31031E+04 41 carpholite-Fe 6.71 4.54 -2.17 -0.145 0.37026E+04 50 chloritoid-Mg 13.20 10.64 -2.55 -0.170 0.43599E+04 51 chloritoid-Fe 9.17 8.42 -0.75 -0.050 0.12805E+04 52 chloritoid-Mn 11.40 10.28 -1.12 -0.075 0.19111E+04 54 coesite -2.38 -3.88 -1.50 -0.501 0.25672E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.88 -1.32 -0.440 0.22525E+04 67 diopside 16.18 11.92 -4.26 -0.426 0.72802E+04 68 hedenbergite 14.21 9.70 -4.51 -0.451 0.77028E+04 75 epidote 24.67 22.19 -2.48 -0.120 0.42302E+04 76 clinozoisite 22.81 18.78 -4.02 -0.183 0.68691E+04 77 epidote-Fe 29.84 25.60 -4.24 -0.220 0.72379E+04 78 fayalite 14.05 9.23 -4.81 -0.688 0.82190E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.353 0.72244E+04 91 heulandite -5.83 -10.51 -4.68 -0.213 0.79942E+04 92 hercynite 17.28 12.30 -4.98 -0.332 0.84952E+04 98 kaolinite -1.33 -2.01 -0.68 -0.062 0.11593E+04 99 kyanite 4.88 1.87 -3.01 -0.301 0.51366E+04 101 laumontite 2.88 1.13 -1.75 -0.117 0.29947E+04 102 lawsonite 9.62 8.89 -0.73 -0.048 0.12421E+04 105 lizardite 23.24 18.57 -4.67 -0.389 0.79801E+04 106 magnesite 0.69 -3.88 -4.57 -1.522 0.77975E+04 107 magnetite 20.09 19.12 -0.97 -0.079 0.16483E+04 110 magnesioferrite 26.21 21.34 -4.87 -0.398 0.83150E+04 113 margarite 17.32 14.64 -2.69 -0.108 0.45890E+04 116 microcline -2.49 -6.57 -4.08 -0.314 0.69655E+04 120 muscovite 2.58 -0.82 -3.40 -0.200 0.58070E+04 121 paragonite 4.24 0.95 -3.29 -0.194 0.56218E+04 136 prehnite 19.37 15.91 -3.46 -0.204 0.59121E+04 137 prehnite-Fe 22.50 19.32 -3.18 -0.191 0.54282E+04 145 pyroxmangite 7.40 4.53 -2.86 -0.573 0.48906E+04 146 pyrophyllite -6.18 -9.77 -3.60 -0.225 0.61384E+04 147 quartz -2.99 -3.88 -0.89 -0.297 0.15198E+04 151 rhodochrosite -0.98 -4.24 -3.26 -1.087 0.55701E+04 152 rhodonite 7.45 4.53 -2.91 -0.582 0.49709E+04 155 siderite -2.61 -6.10 -3.49 -1.163 0.59565E+04 156 sillimanite 5.26 1.87 -3.39 -0.339 0.57946E+04 163 stilbite -7.52 -10.51 -2.99 -0.142 0.51004E+04 164 stilpnomelane-Fe 13.02 8.59 -4.43 -0.132 0.75593E+04 168 sudoite 21.08 17.41 -3.67 -0.118 0.62636E+04 177 topaz-H 4.62 1.87 -2.75 -0.250 0.46967E+04 178 tridymite -2.63 -3.88 -1.25 -0.418 0.21398E+04 187 wairakite 3.95 1.13 -2.82 -0.166 0.48167E+04 188 walstromite 11.51 7.02 -4.49 -0.898 0.76639E+04 189 wollastonite 10.46 7.02 -3.44 -0.688 0.58744E+04 190 pseudo-wollastonite 11.00 7.02 -3.98 -0.796 0.67942E+04 191 zoisite 22.85 18.78 -4.07 -0.185 0.69431E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.74 -4.10 -0.254 0.69973E+04 196 beidellite-Mg -1.79 -6.09 -4.30 -0.266 0.73495E+04 197 beidellite-Na -1.34 -6.23 -4.89 -0.300 0.83524E+04 199 chalcedony -2.80 -3.88 -1.08 -0.359 0.18391E+04 201 montmorillonite-Ca -2.29 -6.02 -3.73 -0.231 0.63751E+04 202 montmorillonite-K -2.24 -7.10 -4.86 -0.298 0.82992E+04 203 montmorillonite-Mg -2.48 -6.37 -3.89 -0.241 0.66505E+04 204 montmorillonite-Na -2.04 -6.51 -4.48 -0.274 0.76440E+04 205 nontronite-Ca 3.21 1.08 -2.14 -0.139 0.36530E+04 206 nontronite-H 2.53 -0.72 -3.26 -0.218 0.55598E+04 207 nontronite-K 3.34 0.00 -3.34 -0.214 0.57003E+04 208 nontronite-Mg 3.07 0.72 -2.35 -0.152 0.40125E+04 209 nontronite-Na 3.52 0.58 -2.93 -0.188 0.50112E+04 214 gypsum -4.96 -9.21 -4.25 -1.063 0.72615E+04 224 tobermorite 9.82 5.20 -4.62 -1.261 0.78930E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.56 -3.26 -0.814 0.55591E+04 240 silica-amorphous -2.09 -3.88 -1.79 -0.596 0.30533E+04 242 an20ab80 2.02 -2.06 -4.08 -0.314 0.69671E+04 243 an25ab75 2.65 -1.38 -4.02 -0.310 0.68706E+04 244 an30ab70 3.28 -0.69 -3.97 -0.306 0.67837E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0144000 g New total amount of reactant added: 0.0148000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0148000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2925685E-03 Osmotic coef. = 0.9898 True ionic strength = .3012313E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18767E-07 -7.7266 0.18012E-07 -7.7444 0.95978E+00 -0.0178 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13239E-03 -3.8781 0.95965E+00 -0.0179 4 SO4-- 0.25303E-04 -4.5968 0.22648E-04 -4.6450 0.89506E+00 -0.0481 5 HCO3- 0.12514E-04 -4.9026 0.12009E-04 -4.9205 0.95968E+00 -0.0179 6 HS- 0.56449E-10 -10.2483 0.54172E-10 -10.2662 0.95966E+00 -0.0179 7 Al+++ 0.54848E-20 -20.2608 0.43691E-20 -20.3596 0.79658E+00 -0.0988 8 H4SiO4 0.13541E-03 -3.8684 0.13541E-03 -3.8684 0.10000E+01 0.0000 9 Ca++ 0.30998E-04 -4.5087 0.27740E-04 -4.5569 0.89491E+00 -0.0482 10 Mg++ 0.21345E-06 -6.6707 0.19100E-06 -6.7190 0.89482E+00 -0.0483 11 Fe++ 0.12820E-08 -8.8921 0.11472E-08 -8.9404 0.89484E+00 -0.0483 12 K+ 0.31411E-05 -5.5029 0.30145E-05 -5.5208 0.95969E+00 -0.0179 13 Na+ 0.17862E-03 -3.7481 0.17141E-03 -3.7660 0.95965E+00 -0.0179 14 Mn++ 0.96680E-07 -7.0147 0.86515E-07 -7.0629 0.89486E+00 -0.0482 15 HPO4-- 0.18446E-08 -8.7341 0.16510E-08 -8.7823 0.89506E+00 -0.0481 16 HSiO3- 0.73147E-05 -5.1358 0.70195E-05 -5.1537 0.95965E+00 -0.0179 17 Ca(HSiO3)+ 0.46208E-08 -8.3353 0.44346E-08 -8.3531 0.95969E+00 -0.0179 18 Mg(HSiO3)+ 0.39595E-10 -10.4024 0.37999E-10 -10.4202 0.95969E+00 -0.0179 19 NaHSiO3,aq 0.19461E-07 -7.7108 0.19461E-07 -7.7108 0.10000E+01 0.0000 20 AlO+ 0.19090E-11 -11.7192 0.18321E-11 -11.7371 0.95969E+00 -0.0179 21 AlOH+2 0.18362E-15 -15.7361 0.16432E-15 -15.7843 0.89488E+00 -0.0482 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.25941E-05 -5.5860 0.24893E-05 -5.6039 0.95961E+00 -0.0179 24 CH4,aq 0.27905E-16 -16.5543 0.27903E-16 -16.5544 0.99991E+00 0.0000 29 CO,aq 0.15019E-16 -16.8234 0.15019E-16 -16.8234 0.10000E+01 0.0000 30 CO2,aq 0.46224E-06 -6.3351 0.46220E-06 -6.3352 0.99991E+00 0.0000 31 CO3-2 0.65066E-07 -7.1866 0.58235E-07 -7.2348 0.89501E+00 -0.0482 32 CaCO3,aq 0.20256E-07 -7.6934 0.20256E-07 -7.6934 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.88607E-08 -8.0525 0.85036E-08 -8.0704 0.95969E+00 -0.0179 34 CaCl+ 0.61931E-08 -8.2081 0.59435E-08 -8.2260 0.95969E+00 -0.0179 35 CaCl2,aq 0.18695E-12 -12.7283 0.18695E-12 -12.7283 0.10000E+01 0.0000 36 CaOH+ 0.11437E-06 -6.9417 0.10976E-06 -6.9596 0.95969E+00 -0.0179 37 CaSO4,aq 0.19950E-06 -6.7001 0.19950E-06 -6.7001 0.10000E+01 0.0000 38 HCl,aq 0.43699E-12 -12.3595 0.43699E-12 -12.3595 0.10000E+01 0.0000 43 FeCl+ 0.25049E-12 -12.6012 0.24040E-12 -12.6191 0.95969E+00 -0.0179 46 FeO,aq 0.13742E-09 -9.8619 0.13742E-09 -9.8619 0.10000E+01 0.0000 47 FeOH+ 0.21602E-08 -8.6655 0.20731E-08 -8.6834 0.95969E+00 -0.0179 48 HFeO2- 0.83183E-10 -10.0800 0.79827E-10 -10.0979 0.95965E+00 -0.0179 49 FeO+ 0.14326E-12 -12.8439 0.13749E-12 -12.8617 0.95969E+00 -0.0179 50 FeOH+2 0.52847E-18 -18.2770 0.47292E-18 -18.3252 0.89488E+00 -0.0482 51 FeO2- 0.90356E-10 -10.0440 0.86711E-10 -10.0619 0.95965E+00 -0.0179 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.12937E-08 -8.8882 0.12935E-08 -8.8882 0.99991E+00 0.0000 54 KCl,aq 0.72334E-11 -11.1407 0.72334E-11 -11.1407 0.10000E+01 0.0000 55 KHSO4,aq 0.34768E-17 -17.4588 0.34768E-17 -17.4588 0.10000E+01 0.0000 56 KOH,aq 0.71471E-10 -10.1459 0.71471E-10 -10.1459 0.10000E+01 0.0000 57 KSO4- 0.11039E-08 -8.9571 0.10594E-08 -8.9749 0.95965E+00 -0.0179 58 MgCO3,aq 0.34958E-10 -10.4565 0.34958E-10 -10.4565 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.62338E-10 -10.2052 0.59826E-10 -10.2231 0.95969E+00 -0.0179 60 MgCl+ 0.38647E-10 -10.4129 0.37089E-10 -10.4307 0.95969E+00 -0.0179 61 MgOH+ 0.43574E-08 -8.3608 0.41818E-08 -8.3786 0.95969E+00 -0.0179 63 MnO,aq 0.27615E-09 -9.5588 0.27615E-09 -9.5588 0.10000E+01 0.0000 64 MnOH+ 0.15134E-07 -7.8200 0.14524E-07 -7.8379 0.95969E+00 -0.0179 65 MnO2-2 0.31562E-16 -16.5008 0.28248E-16 -16.5490 0.89501E+00 -0.0482 66 HMnO2- 0.11616E-12 -12.9349 0.11147E-12 -12.9528 0.95965E+00 -0.0179 69 MnCl+ 0.73496E-10 -10.1337 0.70534E-10 -10.1516 0.95969E+00 -0.0179 70 MnSO4,aq 0.56565E-09 -9.2475 0.56565E-09 -9.2475 0.10000E+01 0.0000 71 NaCl,aq 0.75208E-08 -8.1237 0.75208E-08 -8.1237 0.10000E+01 0.0000 72 NaOH,aq 0.40887E-08 -8.3884 0.40887E-08 -8.3884 0.10000E+01 0.0000 74 OH- 0.33427E-04 -4.4759 0.32077E-04 -4.4938 0.95961E+00 -0.0179 82 H3PO4,aq 0.37463E-14 -14.4264 0.37463E-14 -14.4264 0.10000E+01 0.0000 83 H2PO4- 0.57164E-09 -9.2429 0.54858E-09 -9.2608 0.95967E+00 -0.0179 84 PO4-3 0.93778E-13 -13.0279 0.74784E-13 -13.1262 0.79746E+00 -0.0983 87 H2P2O7-2 0.26365E-19 -19.5790 0.23597E-19 -19.6271 0.89501E+00 -0.0482 88 HP2O7-3 0.32838E-18 -18.4836 0.26159E-18 -18.5824 0.79659E+00 -0.0988 90 H2S,aq 0.30159E-11 -11.5206 0.30157E-11 -11.5206 0.99991E+00 0.0000 96 SO2,aq 0.42447E-19 -19.3722 0.42447E-19 -19.3722 0.10000E+01 0.0000 97 SO3-2 0.42521E-14 -14.3714 0.38069E-14 -14.4194 0.89531E+00 -0.0480 98 HSO3- 0.44739E-14 -14.3493 0.42934E-14 -14.3672 0.95965E+00 -0.0179 99 HSO4- 0.40963E-09 -9.3876 0.39313E-09 -9.4055 0.95971E+00 -0.0179 101 S2O3-2 0.89639E-18 -18.0475 0.80228E-18 -18.0957 0.89501E+00 -0.0482 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1876696E-07 -.5094827E-04 -.5135147E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999726E+06 0.0000 3 Cl- 0.1379611E-03 0.1379750E-03 0.4891501E+01 3.8663 4 SO4-- 0.2530298E-04 0.2550427E-04 0.2449918E+01 10.8439 5 HCO3- 0.1251355E-04 0.1307008E-04 0.7974789E+00 2.8239 6 HS- 0.5644904E-10 0.3467380E-09 0.1146702E-04 -2.5218 7 Al+++ 0.5484846E-20 0.2614329E-05 0.7053672E-01 2.8737 8 H4SiO4 0.1354093E-03 0.1427481E-03 0.1371994E+02 -3.8684 9 Ca++ 0.3099761E-04 0.3135141E-04 0.1256470E+01 10.9320 10 Mg++ 0.2134457E-06 0.2179787E-06 0.5299361E-02 8.7699 11 Fe++ 0.1281957E-08 0.3952121E-08 0.2207084E-03 6.5485 12 K+ 0.3141086E-05 0.3142269E-05 0.1228658E+00 2.2236 13 Na+ 0.1786186E-03 0.1786496E-03 0.4107014E+01 3.9785 14 Mn++ 0.9667951E-07 0.1127290E-06 0.6192947E-02 8.4260 15 HPO4-- 0.1844551E-08 0.2416284E-08 0.2319066E-03 6.7066 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2320260E-03 -.5094797E-04 -.1810781E-03 0.0000000E+00 2 H2O 0.5550806E+02 0.5550796E+02 0.1021763E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2591463E-04 0.2550412E-04 0.4105052E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4101585E-06 0.3467360E-09 -.4105052E-06 0.0000000E+00 7 Al+++ 0.4825898E-04 0.2614314E-05 0.4564466E-04 0.0000000E+00 8 H4SiO4 0.1541092E-03 0.1427473E-03 0.1136188E-04 0.0000000E+00 9 Ca++ 0.3149317E-04 0.3135123E-04 0.1419398E-06 0.0000000E+00 10 Mg++ 0.1174603E-04 0.2179774E-06 0.1152805E-04 0.0000000E+00 11 Fe++ 0.1055253E-04 0.3952098E-08 0.1054858E-04 0.0000000E+00 12 K+ 0.3142251E-05 0.3142251E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1786486E-03 0.1786486E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2566112E-06 0.1127284E-06 0.1438829E-06 0.0000000E+00 15 HPO4-- 0.8758013E-07 0.2416271E-08 0.8516386E-07 0.0000000E+00 Chg. balance for solid moles: 0.1165E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0148000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2839E-07 -7.547 0.1426E-04 -4.846 0.2911 0.4531E-05 clinochlore 0.2306E-05 -5.637 0.1282E-02 -2.892 26.16 0.4875E-03 daphnite 0.1453E-05 -5.838 0.1037E-02 -2.984 21.16 0.3141E-03 chlorite-Mn 0.2878E-07 -7.541 0.2040E-04 -4.690 0.4165 0.6502E-05 diaspore 0.3807E-04 -4.419 0.2284E-02 -2.641 46.62 0.6799E-03 hematite 0.1642E-05 -5.785 0.2622E-03 -3.581 5.353 0.4970E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6088E+00 0.6088E+00 1.0000 -0.216 daphnite 0.3836E+00 0.3836E+00 1.0000 -0.416 chlorite-Mn 0.7598E-02 0.7598E-02 1.0000 -2.119 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004899 g Volume = 0.001542 cm3 Porosity: 99.8467% V(tot) - V(min): 0.10044E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0148000 g log = -1.8297 Original solution: 1000.0103000 g Original solution / Rock added: 67568.26 (Water/Rock Ratio), log = 4.8297 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4812E-04 1.0071 0.4945E-04 0.4910E-04 CH4,gas 0.3975E-13 1.0125 0.4107E-13 0.4056E-13 H2,gas 0.1663E-05 1.0005 0.1698E-05 0.1697E-05 H2S,gas 0.8157E-10 0.9960 0.8290E-10 0.8323E-10 S2,gas 0.8766E-28 1.0000 0.8944E-28 0.8944E-28 CO,gas 0.2194E-13 1.0000 0.2238E-13 0.2238E-13 SO3,gas 0.2723E-35 1.0000 0.2778E-35 0.2778E-35 SO2,gas 0.1799E-18 1.0000 0.1836E-18 0.1836E-18 HCl,gas 0.7557E-15 1.0000 0.7711E-15 0.7711E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.66 -6.00 -2.002 0.10253E+05 -4.306 3 CH4,gas 4.54 -10.54 -15.09 -3.771 0.25758E+05 -13.386 4 H2,gas 8.00 0.53 -7.47 -4.268 0.12753E+05 -5.770 5 H2S,gas -6.23 -18.01 -11.78 -5.890 0.20115E+05 -10.081 6 S2,gas -7.34 -37.08 -29.75 -4.577 0.50793E+05 -28.048 7 CO,gas 3.21 -12.13 -15.35 -4.723 0.26208E+05 -13.650 8 SO3,gas 17.12 -20.13 -37.26 -9.314 0.63612E+05 -35.556 9 SO2,gas 0.83 -19.60 -20.44 -5.449 0.34893E+05 -18.736 10 HCl,gas 5.19 -11.62 -16.81 -8.406 0.28706E+05 -15.113 16 albite -0.38 -4.75 -4.37 -0.336 0.74600E+04 20 analcite 3.32 -0.88 -4.21 -0.467 0.71823E+04 21 andalusite 5.00 1.88 -3.12 -0.312 0.53316E+04 24 anhydrite -5.32 -9.20 -3.89 -1.943 0.66336E+04 29 anorthite 12.71 8.94 -3.77 -0.290 0.64332E+04 35 aragonite 0.97 -1.73 -2.70 -0.900 0.46093E+04 36 brucite 12.57 8.77 -3.80 -0.760 0.64861E+04 37 calcite 0.81 -1.73 -2.54 -0.848 0.43450E+04 40 carpholite-Mg 8.58 6.78 -1.80 -0.120 0.30760E+04 41 carpholite-Fe 6.71 4.56 -2.15 -0.144 0.36770E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43519E+04 51 chloritoid-Fe 9.17 8.43 -0.75 -0.050 0.12739E+04 52 chloritoid-Mn 11.40 10.30 -1.10 -0.073 0.18715E+04 54 coesite -2.38 -3.87 -1.49 -0.497 0.25480E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.87 -1.31 -0.436 0.22334E+04 67 diopside 16.18 11.97 -4.22 -0.422 0.71990E+04 68 hedenbergite 14.21 9.74 -4.46 -0.446 0.76230E+04 75 epidote 24.67 22.29 -2.38 -0.115 0.40647E+04 76 clinozoisite 22.81 18.88 -3.93 -0.178 0.67036E+04 77 epidote-Fe 29.84 25.70 -4.14 -0.215 0.70724E+04 78 fayalite 14.05 9.23 -4.82 -0.688 0.82251E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.353 0.72239E+04 91 heulandite -5.83 -10.40 -4.57 -0.208 0.78063E+04 92 hercynite 17.28 12.30 -4.98 -0.332 0.85078E+04 98 kaolinite -1.33 -1.99 -0.66 -0.060 0.11210E+04 99 kyanite 4.88 1.88 -3.00 -0.300 0.51175E+04 101 laumontite 2.88 1.21 -1.68 -0.112 0.28642E+04 102 lawsonite 9.62 8.94 -0.67 -0.045 0.11498E+04 105 lizardite 23.24 18.57 -4.67 -0.389 0.79754E+04 106 magnesite 0.69 -3.90 -4.59 -1.529 0.78298E+04 107 magnetite 20.09 19.11 -0.97 -0.079 0.16609E+04 110 magnesioferrite 26.21 21.34 -4.88 -0.398 0.83262E+04 113 margarite 17.32 14.69 -2.63 -0.105 0.44967E+04 116 microcline -2.49 -6.51 -4.02 -0.309 0.68661E+04 120 muscovite 2.58 -0.76 -3.34 -0.197 0.57077E+04 121 paragonite 4.24 0.99 -3.24 -0.191 0.55406E+04 136 prehnite 19.37 16.01 -3.37 -0.198 0.57466E+04 137 prehnite-Fe 22.50 19.42 -3.08 -0.185 0.52627E+04 138 pumpellyite-Fe 46.27 41.43 -4.83 -0.107 0.82550E+04 145 pyroxmangite 7.40 4.56 -2.84 -0.568 0.48511E+04 146 pyrophyllite -6.18 -9.73 -3.55 -0.222 0.60619E+04 147 quartz -2.99 -3.87 -0.88 -0.293 0.15007E+04 151 rhodochrosite -0.98 -4.24 -3.26 -1.088 0.55709E+04 152 rhodonite 7.45 4.56 -2.89 -0.578 0.49313E+04 155 siderite -2.61 -6.12 -3.51 -1.169 0.59903E+04 156 sillimanite 5.26 1.88 -3.38 -0.338 0.57755E+04 163 stilbite -7.52 -10.40 -2.88 -0.137 0.49125E+04 164 stilpnomelane-Fe 13.02 8.65 -4.36 -0.130 0.74482E+04 168 sudoite 21.08 17.43 -3.65 -0.118 0.62286E+04 177 topaz-H 4.62 1.88 -2.74 -0.249 0.46775E+04 178 tridymite -2.63 -3.87 -1.24 -0.414 0.21207E+04 187 wairakite 3.95 1.21 -2.74 -0.161 0.46862E+04 188 walstromite 11.51 7.06 -4.45 -0.889 0.75907E+04 189 wollastonite 10.46 7.06 -3.40 -0.680 0.58012E+04 190 pseudo-wollastonite 11.00 7.06 -3.94 -0.787 0.67210E+04 191 zoisite 22.85 18.88 -3.97 -0.180 0.67777E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.70 -4.05 -0.251 0.69183E+04 196 beidellite-Mg -1.79 -6.05 -4.26 -0.264 0.72812E+04 197 beidellite-Na -1.34 -6.19 -4.85 -0.297 0.82744E+04 199 chalcedony -2.80 -3.87 -1.07 -0.355 0.18200E+04 201 montmorillonite-Ca -2.29 -5.98 -3.69 -0.228 0.62934E+04 202 montmorillonite-K -2.24 -7.05 -4.81 -0.295 0.82125E+04 203 montmorillonite-Mg -2.48 -6.33 -3.85 -0.238 0.65795E+04 204 montmorillonite-Na -2.04 -6.47 -4.43 -0.271 0.75634E+04 205 nontronite-Ca 3.21 1.12 -2.09 -0.136 0.35739E+04 206 nontronite-H 2.53 -0.68 -3.22 -0.215 0.54896E+04 207 nontronite-K 3.34 0.05 -3.29 -0.211 0.56163E+04 208 nontronite-Mg 3.07 0.76 -2.31 -0.150 0.39442E+04 209 nontronite-Na 3.52 0.63 -2.89 -0.185 0.49331E+04 214 gypsum -4.96 -9.20 -4.25 -1.062 0.72512E+04 224 tobermorite 9.82 5.24 -4.59 -1.251 0.78289E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.55 -3.26 -0.816 0.55716E+04 240 silica-amorphous -2.09 -3.87 -1.78 -0.592 0.30342E+04 242 an20ab80 2.02 -2.01 -4.03 -0.310 0.68838E+04 243 an25ab75 2.65 -1.33 -3.97 -0.306 0.67867E+04 244 an30ab70 3.28 -0.64 -3.92 -0.302 0.66992E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0148000 g New total amount of reactant added: 0.0152000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0152000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2940737E-03 Osmotic coef. = 0.9897 True ionic strength = .3031076E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18244E-07 -7.7389 0.17509E-07 -7.7567 0.95971E+00 -0.0179 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13239E-03 -3.8782 0.95958E+00 -0.0179 4 SO4-- 0.25300E-04 -4.5969 0.22639E-04 -4.6451 0.89481E+00 -0.0483 5 HCO3- 0.12523E-04 -4.9023 0.12017E-04 -4.9202 0.95962E+00 -0.0179 6 HS- 0.48115E-10 -10.3177 0.46171E-10 -10.3356 0.95959E+00 -0.0179 7 Al+++ 0.50408E-20 -20.2975 0.40129E-20 -20.3965 0.79608E+00 -0.0990 8 H4SiO4 0.13885E-03 -3.8575 0.13885E-03 -3.8575 0.10000E+01 0.0000 9 Ca++ 0.31444E-04 -4.5025 0.28132E-04 -4.5508 0.89466E+00 -0.0483 10 Mg++ 0.19879E-06 -6.7016 0.17783E-06 -6.7500 0.89457E+00 -0.0484 11 Fe++ 0.11919E-08 -8.9237 0.10663E-08 -8.9721 0.89459E+00 -0.0484 12 K+ 0.32260E-05 -5.4913 0.30957E-05 -5.5092 0.95962E+00 -0.0179 13 Na+ 0.17912E-03 -3.7469 0.17188E-03 -3.7648 0.95958E+00 -0.0179 14 Mn++ 0.93634E-07 -7.0286 0.83766E-07 -7.0769 0.89461E+00 -0.0484 15 HPO4-- 0.17356E-08 -8.7606 0.15530E-08 -8.8088 0.89481E+00 -0.0483 16 HSiO3- 0.77166E-05 -5.1126 0.74048E-05 -5.1305 0.95958E+00 -0.0179 17 Ca(HSiO3)+ 0.49436E-08 -8.3060 0.47440E-08 -8.3239 0.95963E+00 -0.0179 18 Mg(HSiO3)+ 0.38892E-10 -10.4101 0.37321E-10 -10.4280 0.95963E+00 -0.0179 19 NaHSiO3,aq 0.20585E-07 -7.6865 0.20585E-07 -7.6865 0.10000E+01 0.0000 20 AlO+ 0.18558E-11 -11.7315 0.17808E-11 -11.7494 0.95963E+00 -0.0179 21 AlOH+2 0.17355E-15 -15.7606 0.15526E-15 -15.8089 0.89463E+00 -0.0484 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.26689E-05 -5.5737 0.25609E-05 -5.5916 0.95954E+00 -0.0179 24 CH4,aq 0.23810E-16 -16.6232 0.23808E-16 -16.6233 0.99991E+00 0.0000 29 CO,aq 0.14139E-16 -16.8496 0.14139E-16 -16.8496 0.10000E+01 0.0000 30 CO2,aq 0.44964E-06 -6.3471 0.44960E-06 -6.3472 0.99991E+00 0.0000 31 CO3-2 0.67003E-07 -7.1739 0.59952E-07 -7.2222 0.89476E+00 -0.0483 32 CaCO3,aq 0.21148E-07 -7.6747 0.21148E-07 -7.6747 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.89928E-08 -8.0461 0.86297E-08 -8.0640 0.95963E+00 -0.0179 34 CaCl+ 0.62806E-08 -8.2020 0.60270E-08 -8.2199 0.95963E+00 -0.0179 35 CaCl2,aq 0.18956E-12 -12.7223 0.18956E-12 -12.7223 0.10000E+01 0.0000 36 CaOH+ 0.11933E-06 -6.9233 0.11451E-06 -6.9411 0.95963E+00 -0.0179 37 CaSO4,aq 0.20224E-06 -6.6941 0.20224E-06 -6.6941 0.10000E+01 0.0000 38 HCl,aq 0.42474E-12 -12.3719 0.42474E-12 -12.3719 0.10000E+01 0.0000 43 FeCl+ 0.23284E-12 -12.6329 0.22344E-12 -12.6508 0.95963E+00 -0.0179 46 FeO,aq 0.13519E-09 -9.8691 0.13519E-09 -9.8691 0.10000E+01 0.0000 47 FeOH+ 0.20658E-08 -8.6849 0.19824E-08 -8.7028 0.95963E+00 -0.0179 48 HFeO2- 0.84191E-10 -10.0747 0.80788E-10 -10.0927 0.95958E+00 -0.0179 49 FeO+ 0.13926E-12 -12.8562 0.13364E-12 -12.8741 0.95963E+00 -0.0179 50 FeOH+2 0.49948E-18 -18.3015 0.44685E-18 -18.3498 0.89463E+00 -0.0484 51 FeO2- 0.92961E-10 -10.0317 0.89204E-10 -10.0496 0.95958E+00 -0.0179 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.12520E-08 -8.9024 0.12518E-08 -8.9025 0.99991E+00 0.0000 54 KCl,aq 0.74278E-11 -11.1291 0.74278E-11 -11.1291 0.10000E+01 0.0000 55 KHSO4,aq 0.34694E-17 -17.4597 0.34694E-17 -17.4597 0.10000E+01 0.0000 56 KOH,aq 0.75508E-10 -10.1220 0.75508E-10 -10.1220 0.10000E+01 0.0000 57 KSO4- 0.11333E-08 -8.9456 0.10875E-08 -8.9636 0.95958E+00 -0.0179 58 MgCO3,aq 0.33508E-10 -10.4748 0.33508E-10 -10.4748 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.58087E-10 -10.2359 0.55742E-10 -10.2538 0.95963E+00 -0.0179 60 MgCl+ 0.35984E-10 -10.4439 0.34531E-10 -10.4618 0.95963E+00 -0.0179 61 MgOH+ 0.41741E-08 -8.3794 0.40056E-08 -8.3973 0.95963E+00 -0.0179 63 MnO,aq 0.28298E-09 -9.5482 0.28298E-09 -9.5482 0.10000E+01 0.0000 64 MnOH+ 0.15076E-07 -7.8217 0.14467E-07 -7.8396 0.95963E+00 -0.0179 65 MnO2-2 0.34238E-16 -16.4655 0.30635E-16 -16.5138 0.89476E+00 -0.0483 66 HMnO2- 0.12246E-12 -12.9120 0.11751E-12 -12.9299 0.95958E+00 -0.0179 69 MnCl+ 0.71161E-10 -10.1478 0.68287E-10 -10.1657 0.95963E+00 -0.0179 70 MnSO4,aq 0.54746E-09 -9.2616 0.54746E-09 -9.2616 0.10000E+01 0.0000 71 NaCl,aq 0.75408E-08 -8.1226 0.75408E-08 -8.1226 0.10000E+01 0.0000 72 NaOH,aq 0.42178E-08 -8.3749 0.42178E-08 -8.3749 0.10000E+01 0.0000 74 OH- 0.34391E-04 -4.4636 0.32999E-04 -4.4815 0.95954E+00 -0.0179 82 H3PO4,aq 0.33297E-14 -14.4776 0.33297E-14 -14.4776 0.10000E+01 0.0000 83 H2PO4- 0.52272E-09 -9.2817 0.50160E-09 -9.2996 0.95960E+00 -0.0179 84 PO4-3 0.90806E-13 -13.0419 0.72369E-13 -13.1404 0.79696E+00 -0.0986 87 H2P2O7-2 0.22049E-19 -19.6566 0.19728E-19 -19.7049 0.89476E+00 -0.0483 88 HP2O7-3 0.28262E-18 -18.5488 0.22499E-18 -18.6478 0.79608E+00 -0.0990 90 H2S,aq 0.24986E-11 -11.6023 0.24984E-11 -11.6023 0.99991E+00 0.0000 96 SO2,aq 0.38799E-19 -19.4112 0.38799E-19 -19.4112 0.10000E+01 0.0000 97 SO3-2 0.41146E-14 -14.3857 0.36828E-14 -14.4338 0.89506E+00 -0.0481 98 HSO3- 0.42073E-14 -14.3760 0.40373E-14 -14.3939 0.95958E+00 -0.0179 99 HSO4- 0.39806E-09 -9.4001 0.38199E-09 -9.4179 0.95965E+00 -0.0179 101 S2O3-2 0.74256E-18 -18.1293 0.66441E-18 -18.1776 0.89476E+00 -0.0483 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1824362E-07 -.5263538E-04 -.5305191E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999722E+06 0.0000 3 Cl- 0.1379611E-03 0.1379750E-03 0.4891500E+01 3.8786 4 SO4-- 0.2530025E-04 0.2550429E-04 0.2449919E+01 10.8683 5 HCO3- 0.1252321E-04 0.1307008E-04 0.7974787E+00 2.8366 6 HS- 0.4811518E-10 0.3271360E-09 0.1081876E-04 -2.5789 7 Al+++ 0.5040810E-20 0.2689120E-05 0.7255460E-01 2.8737 8 H4SiO4 0.1388475E-03 0.1465898E-03 0.1408916E+02 -3.8575 9 Ca++ 0.3144434E-04 0.3180727E-04 0.1274738E+01 10.9627 10 Mg++ 0.1987916E-06 0.2031321E-06 0.4938420E-02 8.7635 11 Fe++ 0.1191940E-08 0.3769099E-08 0.2104874E-03 6.5414 12 K+ 0.3225979E-05 0.3227195E-05 0.1261865E+00 2.2475 13 Na+ 0.1791194E-03 0.1791518E-03 0.4118555E+01 3.9920 14 Mn++ 0.9363405E-07 0.1096114E-06 0.6021676E-02 8.4366 15 HPO4-- 0.1735573E-08 0.2258383E-08 0.2167517E-03 6.7047 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2386494E-03 -.5263507E-04 -.1860144E-03 0.0000000E+00 2 H2O 0.5550806E+02 0.5550795E+02 0.1049404E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2592571E-04 0.2550414E-04 0.4215709E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4212438E-06 0.3271341E-09 -.4215709E-06 0.0000000E+00 7 Al+++ 0.4956327E-04 0.2689104E-05 0.4687417E-04 0.0000000E+00 8 H4SiO4 0.1582743E-03 0.1465889E-03 0.1168541E-04 0.0000000E+00 9 Ca++ 0.3195323E-04 0.3180708E-04 0.1461480E-06 0.0000000E+00 10 Mg++ 0.1206349E-04 0.2031309E-06 0.1186036E-04 0.0000000E+00 11 Fe++ 0.1083773E-04 0.3769077E-08 0.1083396E-04 0.0000000E+00 12 K+ 0.3227176E-05 0.3227176E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1791507E-03 0.1791507E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2635467E-06 0.1096108E-06 0.1539359E-06 0.0000000E+00 15 HPO4-- 0.8994716E-07 0.2258370E-08 0.8768879E-07 0.0000000E+00 Chg. balance for solid moles: -.2726E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0152000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2923E-07 -7.534 0.1468E-04 -4.833 0.2917 0.4666E-05 clinochlore 0.2372E-05 -5.625 0.1318E-02 -2.880 26.19 0.5015E-03 daphnite 0.1492E-05 -5.826 0.1065E-02 -2.973 21.15 0.3227E-03 chlorite-Mn 0.3079E-07 -7.512 0.2183E-04 -4.661 0.4336 0.6956E-05 diaspore 0.3908E-04 -4.408 0.2345E-02 -2.630 46.58 0.6980E-03 hematite 0.1686E-05 -5.773 0.2693E-03 -3.570 5.350 0.5104E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6090E+00 0.6090E+00 1.0000 -0.215 daphnite 0.3831E+00 0.3831E+00 1.0000 -0.417 chlorite-Mn 0.7904E-02 0.7904E-02 1.0000 -2.102 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005034 g Volume = 0.001585 cm3 Porosity: 99.8425% V(tot) - V(min): 0.10045E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0152000 g log = -1.8182 Original solution: 1000.0103000 g Original solution / Rock added: 65790.15 (Water/Rock Ratio), log = 4.8182 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4681E-04 1.0071 0.4810E-04 0.4776E-04 CH4,gas 0.3392E-13 1.0125 0.3504E-13 0.3461E-13 H2,gas 0.1610E-05 1.0005 0.1644E-05 0.1643E-05 H2S,gas 0.6758E-10 0.9960 0.6868E-10 0.6895E-10 S2,gas 0.6424E-28 1.0000 0.6555E-28 0.6555E-28 CO,gas 0.2065E-13 1.0000 0.2107E-13 0.2107E-13 SO3,gas 0.2572E-35 1.0000 0.2624E-35 0.2624E-35 SO2,gas 0.1644E-18 1.0000 0.1678E-18 0.1678E-18 HCl,gas 0.7345E-15 1.0000 0.7495E-15 0.7495E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.68 -6.02 -2.006 0.10274E+05 -4.318 3 CH4,gas 4.54 -10.61 -15.15 -3.789 0.25876E+05 -13.455 4 H2,gas 8.00 0.52 -7.48 -4.276 0.12777E+05 -5.784 5 H2S,gas -6.23 -18.09 -11.86 -5.931 0.20254E+05 -10.163 6 S2,gas -7.34 -37.22 -29.88 -4.597 0.51023E+05 -28.183 7 CO,gas 3.21 -12.16 -15.38 -4.731 0.26253E+05 -13.676 8 SO3,gas 17.12 -20.16 -37.28 -9.320 0.63655E+05 -35.581 9 SO2,gas 0.83 -19.64 -20.47 -5.460 0.34959E+05 -18.775 10 HCl,gas 5.19 -11.63 -16.82 -8.412 0.28727E+05 -15.125 16 albite -0.38 -4.71 -4.32 -0.333 0.73811E+04 19 spessartine 24.46 19.48 -4.97 -0.249 0.84907E+04 20 analcite 3.32 -0.85 -4.17 -0.463 0.71221E+04 21 andalusite 5.00 1.89 -3.11 -0.311 0.53130E+04 24 anhydrite -5.32 -9.20 -3.88 -1.940 0.66235E+04 29 anorthite 12.71 9.00 -3.72 -0.286 0.63435E+04 35 aragonite 0.97 -1.71 -2.68 -0.894 0.45773E+04 36 brucite 12.57 8.76 -3.81 -0.761 0.64970E+04 37 calcite 0.81 -1.71 -2.53 -0.842 0.43131E+04 40 carpholite-Mg 8.58 6.80 -1.79 -0.119 0.30497E+04 41 carpholite-Fe 6.71 4.57 -2.14 -0.143 0.36519E+04 50 chloritoid-Mg 13.20 10.65 -2.54 -0.170 0.43443E+04 51 chloritoid-Fe 9.17 8.43 -0.74 -0.049 0.12675E+04 52 chloritoid-Mn 11.40 10.33 -1.07 -0.072 0.18348E+04 54 coesite -2.38 -3.86 -1.48 -0.494 0.25294E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.86 -1.30 -0.432 0.22148E+04 67 diopside 16.18 12.01 -4.17 -0.417 0.71203E+04 68 hedenbergite 14.21 9.79 -4.42 -0.442 0.75455E+04 75 epidote 24.67 22.38 -2.29 -0.111 0.39040E+04 76 clinozoisite 22.81 18.97 -3.83 -0.174 0.65429E+04 77 epidote-Fe 29.84 25.79 -4.05 -0.210 0.69117E+04 78 fayalite 14.05 9.23 -4.82 -0.689 0.82308E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.353 0.72231E+04 91 heulandite -5.83 -10.29 -4.46 -0.203 0.76237E+04 92 hercynite 17.28 12.29 -4.99 -0.333 0.85199E+04 98 kaolinite -1.33 -1.97 -0.63 -0.058 0.10838E+04 99 kyanite 4.88 1.89 -2.99 -0.299 0.50989E+04 101 laumontite 2.88 1.28 -1.60 -0.107 0.27374E+04 102 lawsonite 9.62 9.00 -0.62 -0.041 0.10602E+04 105 lizardite 23.24 18.58 -4.67 -0.389 0.79709E+04 106 magnesite 0.69 -3.91 -4.60 -1.535 0.78613E+04 107 magnetite 20.09 19.11 -0.98 -0.080 0.16730E+04 110 magnesioferrite 26.21 21.33 -4.88 -0.399 0.83371E+04 113 margarite 17.32 14.74 -2.58 -0.103 0.44071E+04 116 microcline -2.49 -6.45 -3.96 -0.305 0.67696E+04 120 muscovite 2.58 -0.70 -3.29 -0.193 0.56111E+04 121 paragonite 4.24 1.04 -3.20 -0.188 0.54618E+04 136 prehnite 19.37 16.10 -3.27 -0.192 0.55860E+04 137 prehnite-Fe 22.50 19.51 -2.99 -0.180 0.51020E+04 138 pumpellyite-Fe 46.27 41.62 -4.65 -0.103 0.79458E+04 145 pyroxmangite 7.40 4.58 -2.82 -0.564 0.48144E+04 146 pyrophyllite -6.18 -9.68 -3.51 -0.219 0.59875E+04 147 quartz -2.99 -3.86 -0.87 -0.289 0.14821E+04 151 rhodochrosite -0.98 -4.24 -3.26 -1.088 0.55733E+04 152 rhodonite 7.45 4.58 -2.87 -0.573 0.48946E+04 155 siderite -2.61 -6.14 -3.53 -1.176 0.60230E+04 156 sillimanite 5.26 1.89 -3.37 -0.337 0.57569E+04 163 stilbite -7.52 -10.29 -2.77 -0.132 0.47299E+04 164 stilpnomelane-Fe 13.02 8.72 -4.30 -0.128 0.73398E+04 168 sudoite 21.08 17.45 -3.63 -0.117 0.61946E+04 177 topaz-H 4.62 1.89 -2.73 -0.248 0.46589E+04 178 tridymite -2.63 -3.86 -1.23 -0.410 0.21021E+04 187 wairakite 3.95 1.28 -2.67 -0.157 0.45593E+04 188 walstromite 11.51 7.11 -4.40 -0.881 0.75197E+04 189 wollastonite 10.46 7.11 -3.36 -0.671 0.57301E+04 190 pseudo-wollastonite 11.00 7.11 -3.89 -0.779 0.66500E+04 191 zoisite 22.85 18.97 -3.88 -0.176 0.66170E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.65 -4.01 -0.248 0.68414E+04 196 beidellite-Mg -1.79 -6.02 -4.23 -0.261 0.72148E+04 197 beidellite-Na -1.34 -6.14 -4.80 -0.294 0.81986E+04 199 chalcedony -2.80 -3.86 -1.06 -0.352 0.18014E+04 201 montmorillonite-Ca -2.29 -5.93 -3.64 -0.225 0.62139E+04 202 montmorillonite-K -2.24 -7.00 -4.76 -0.292 0.81283E+04 203 montmorillonite-Mg -2.48 -6.29 -3.81 -0.236 0.65105E+04 204 montmorillonite-Na -2.04 -6.42 -4.38 -0.268 0.74850E+04 205 nontronite-Ca 3.21 1.17 -2.05 -0.133 0.34970E+04 206 nontronite-H 2.53 -0.64 -3.18 -0.213 0.54214E+04 207 nontronite-K 3.34 0.10 -3.24 -0.208 0.55346E+04 208 nontronite-Mg 3.07 0.80 -2.27 -0.147 0.38777E+04 209 nontronite-Na 3.52 0.67 -2.84 -0.183 0.48573E+04 214 gypsum -4.96 -9.20 -4.24 -1.060 0.72411E+04 224 tobermorite 9.82 5.27 -4.55 -1.241 0.77666E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.54 -3.27 -0.818 0.55838E+04 240 silica-amorphous -2.09 -3.86 -1.77 -0.589 0.30156E+04 242 an20ab80 2.02 -1.97 -3.98 -0.306 0.68028E+04 243 an25ab75 2.65 -1.28 -3.93 -0.302 0.67052E+04 244 an30ab70 3.28 -0.60 -3.88 -0.298 0.66171E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0152000 g New total amount of reactant added: 0.0156000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0156000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2955801E-03 Osmotic coef. = 0.9897 True ionic strength = .3049880E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17751E-07 -7.7508 0.17035E-07 -7.7687 0.95965E+00 -0.0179 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13238E-03 -3.8782 0.95952E+00 -0.0179 4 SO4-- 0.25298E-04 -4.5969 0.22630E-04 -4.6453 0.89455E+00 -0.0484 5 HCO3- 0.12532E-04 -4.9020 0.12025E-04 -4.9199 0.95955E+00 -0.0179 6 HS- 0.41228E-10 -10.3848 0.39559E-10 -10.4028 0.95952E+00 -0.0179 7 Al+++ 0.46457E-20 -20.3330 0.36960E-20 -20.4323 0.79557E+00 -0.0993 8 H4SiO4 0.14228E-03 -3.8469 0.14228E-03 -3.8469 0.10000E+01 0.0000 9 Ca++ 0.31891E-04 -4.4963 0.28524E-04 -4.5448 0.89441E+00 -0.0485 10 Mg++ 0.18555E-06 -6.7315 0.16594E-06 -6.7800 0.89432E+00 -0.0485 11 Fe++ 0.11109E-08 -8.9543 0.99353E-09 -9.0028 0.89434E+00 -0.0485 12 K+ 0.33109E-05 -5.4801 0.31770E-05 -5.4980 0.95955E+00 -0.0179 13 Na+ 0.17962E-03 -3.7456 0.17235E-03 -3.7636 0.95951E+00 -0.0179 14 Mn++ 0.90593E-07 -7.0429 0.81022E-07 -7.0914 0.89436E+00 -0.0485 15 HPO4-- 0.16356E-08 -8.7863 0.14632E-08 -8.8347 0.89456E+00 -0.0484 16 HSiO3- 0.81277E-05 -5.0900 0.77986E-05 -5.1080 0.95952E+00 -0.0179 17 Ca(HSiO3)+ 0.52794E-08 -8.2774 0.50659E-08 -8.2953 0.95956E+00 -0.0179 18 Mg(HSiO3)+ 0.38224E-10 -10.4177 0.36678E-10 -10.4356 0.95956E+00 -0.0179 19 NaHSiO3,aq 0.21739E-07 -7.6628 0.21739E-07 -7.6628 0.10000E+01 0.0000 20 AlO+ 0.18057E-11 -11.7434 0.17327E-11 -11.7613 0.95956E+00 -0.0179 21 AlOH+2 0.16433E-15 -15.7843 0.14697E-15 -15.8328 0.89437E+00 -0.0485 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.27433E-05 -5.5617 0.26321E-05 -5.5797 0.95948E+00 -0.0180 24 CH4,aq 0.20421E-16 -16.6899 0.20419E-16 -16.6900 0.99991E+00 0.0000 29 CO,aq 0.13336E-16 -16.8750 0.13336E-16 -16.8750 0.10000E+01 0.0000 30 CO2,aq 0.43776E-06 -6.3588 0.43772E-06 -6.3588 0.99991E+00 0.0000 31 CO3-2 0.68929E-07 -7.1616 0.61658E-07 -7.2100 0.89451E+00 -0.0484 32 CaCO3,aq 0.22052E-07 -7.6565 0.22052E-07 -7.6565 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.91245E-08 -8.0398 0.87554E-08 -8.0577 0.95956E+00 -0.0179 34 CaCl+ 0.63680E-08 -8.1960 0.61105E-08 -8.2139 0.95956E+00 -0.0179 35 CaCl2,aq 0.19217E-12 -12.7163 0.19217E-12 -12.7163 0.10000E+01 0.0000 36 CaOH+ 0.12436E-06 -6.9053 0.11933E-06 -6.9232 0.95956E+00 -0.0179 37 CaSO4,aq 0.20497E-06 -6.6883 0.20497E-06 -6.6883 0.10000E+01 0.0000 38 HCl,aq 0.41322E-12 -12.3838 0.41322E-12 -12.3838 0.10000E+01 0.0000 43 FeCl+ 0.21695E-12 -12.6636 0.20817E-12 -12.6816 0.95956E+00 -0.0179 46 FeO,aq 0.13306E-09 -9.8759 0.13306E-09 -9.8759 0.10000E+01 0.0000 47 FeOH+ 0.19785E-08 -8.7037 0.18985E-08 -8.7216 0.95956E+00 -0.0179 48 HFeO2- 0.85177E-10 -10.0697 0.81729E-10 -10.0876 0.95952E+00 -0.0179 49 FeO+ 0.13551E-12 -12.8680 0.13003E-12 -12.8860 0.95956E+00 -0.0179 50 FeOH+2 0.47296E-18 -18.3252 0.42300E-18 -18.3737 0.89437E+00 -0.0485 51 FeO2- 0.95553E-10 -10.0198 0.91684E-10 -10.0377 0.95952E+00 -0.0179 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.12129E-08 -8.9162 0.12128E-08 -8.9162 0.99991E+00 0.0000 54 KCl,aq 0.76222E-11 -11.1179 0.76222E-11 -11.1179 0.10000E+01 0.0000 55 KHSO4,aq 0.34628E-17 -17.4606 0.34628E-17 -17.4606 0.10000E+01 0.0000 56 KOH,aq 0.79644E-10 -10.0988 0.79644E-10 -10.0988 0.10000E+01 0.0000 57 KSO4- 0.11627E-08 -8.9345 0.11156E-08 -8.9525 0.95952E+00 -0.0179 58 MgCO3,aq 0.32158E-10 -10.4927 0.32158E-10 -10.4927 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.54241E-10 -10.2657 0.52048E-10 -10.2836 0.95956E+00 -0.0179 60 MgCl+ 0.33578E-10 -10.4740 0.32220E-10 -10.4919 0.95956E+00 -0.0179 61 MgOH+ 0.40035E-08 -8.3976 0.38416E-08 -8.4155 0.95956E+00 -0.0179 63 MnO,aq 0.28914E-09 -9.5389 0.28914E-09 -9.5389 0.10000E+01 0.0000 64 MnOH+ 0.14988E-07 -7.8242 0.14382E-07 -7.8422 0.95956E+00 -0.0179 65 MnO2-2 0.36966E-16 -16.4322 0.33067E-16 -16.4806 0.89451E+00 -0.0484 66 HMnO2- 0.12862E-12 -12.8907 0.12341E-12 -12.9087 0.95952E+00 -0.0179 69 MnCl+ 0.68830E-10 -10.1622 0.66046E-10 -10.1802 0.95956E+00 -0.0179 70 MnSO4,aq 0.52932E-09 -9.2763 0.52932E-09 -9.2763 0.10000E+01 0.0000 71 NaCl,aq 0.75608E-08 -8.1214 0.75608E-08 -8.1214 0.10000E+01 0.0000 72 NaOH,aq 0.43469E-08 -8.3618 0.43469E-08 -8.3618 0.10000E+01 0.0000 74 OH- 0.35349E-04 -4.4516 0.33917E-04 -4.4696 0.95948E+00 -0.0180 82 H3PO4,aq 0.29696E-14 -14.5273 0.29696E-14 -14.5273 0.10000E+01 0.0000 83 H2PO4- 0.47919E-09 -9.3195 0.45980E-09 -9.3374 0.95954E+00 -0.0179 84 PO4-3 0.87986E-13 -13.0556 0.70077E-13 -13.1544 0.79646E+00 -0.0988 87 H2P2O7-2 0.18532E-19 -19.7321 0.16577E-19 -19.7805 0.89451E+00 -0.0484 88 HP2O7-3 0.24423E-18 -18.6122 0.19431E-18 -18.7115 0.79558E+00 -0.0993 90 H2S,aq 0.20829E-11 -11.6813 0.20827E-11 -11.6814 0.99991E+00 0.0000 96 SO2,aq 0.35569E-19 -19.4489 0.35569E-19 -19.4489 0.10000E+01 0.0000 97 SO3-2 0.39858E-14 -14.3995 0.35665E-14 -14.4478 0.89481E+00 -0.0483 98 HSO3- 0.39646E-14 -14.4018 0.38041E-14 -14.4197 0.95952E+00 -0.0179 99 HSO4- 0.38717E-09 -9.4121 0.37152E-09 -9.4300 0.95958E+00 -0.0179 101 S2O3-2 0.61895E-18 -18.2083 0.55365E-18 -18.2568 0.89451E+00 -0.0484 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1775140E-07 -.5432415E-04 -.5475403E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999718E+06 0.0000 3 Cl- 0.1379610E-03 0.1379750E-03 0.4891498E+01 3.8905 4 SO4-- 0.2529753E-04 0.2550431E-04 0.2449920E+01 10.8920 5 HCO3- 0.1253213E-04 0.1307008E-04 0.7974785E+00 2.8487 6 HS- 0.4122782E-10 0.3097476E-09 0.1024370E-04 -2.6341 7 Al+++ 0.4645677E-20 0.2763512E-05 0.7456171E-01 2.8737 8 H4SiO4 0.1422775E-03 0.1504322E-03 0.1445847E+02 -3.8469 9 Ca++ 0.3189099E-04 0.3226315E-04 0.1293008E+01 10.9925 10 Mg++ 0.1855515E-06 0.1897132E-06 0.4612185E-02 8.7573 11 Fe++ 0.1110909E-08 0.3602171E-08 0.2011651E-03 6.5345 12 K+ 0.3310872E-05 0.3312122E-05 0.1295072E+00 2.2707 13 Na+ 0.1796202E-03 0.1796539E-03 0.4130097E+01 4.0051 14 Mn++ 0.9059255E-07 0.1064683E-06 0.5848998E-02 8.4459 15 HPO4-- 0.1635616E-08 0.2114893E-08 0.2029799E-03 6.7026 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2452728E-03 -.5432382E-04 -.1909490E-03 0.0000000E+00 2 H2O 0.5550805E+02 0.5550795E+02 0.1077047E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2593680E-04 0.2550416E-04 0.4326389E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4323292E-06 0.3097458E-09 -.4326389E-06 0.0000000E+00 7 Al+++ 0.5086757E-04 0.2763495E-05 0.4810407E-04 0.0000000E+00 8 H4SiO4 0.1624394E-03 0.1504313E-03 0.1200809E-04 0.0000000E+00 9 Ca++ 0.3241329E-04 0.3226295E-04 0.1503322E-06 0.0000000E+00 10 Mg++ 0.1238095E-04 0.1897121E-06 0.1219124E-04 0.0000000E+00 11 Fe++ 0.1112293E-04 0.3602149E-08 0.1111933E-04 0.0000000E+00 12 K+ 0.3312102E-05 0.3312102E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1796528E-03 0.1796528E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2704821E-06 0.1064676E-06 0.1640145E-06 0.0000000E+00 15 HPO4-- 0.9231420E-07 0.2114880E-08 0.9019931E-07 0.0000000E+00 Chg. balance for solid moles: 0.1239E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0156000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3007E-07 -7.522 0.1510E-04 -4.821 0.2922 0.4799E-05 clinochlore 0.2438E-05 -5.613 0.1355E-02 -2.868 26.22 0.5155E-03 daphnite 0.1532E-05 -5.815 0.1093E-02 -2.961 21.14 0.3312E-03 chlorite-Mn 0.3280E-07 -7.484 0.2326E-04 -4.633 0.4500 0.7411E-05 diaspore 0.4010E-04 -4.397 0.2406E-02 -2.619 46.54 0.7161E-03 hematite 0.1731E-05 -5.762 0.2764E-03 -3.559 5.347 0.5238E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6092E+00 0.6092E+00 1.0000 -0.215 daphnite 0.3827E+00 0.3827E+00 1.0000 -0.417 chlorite-Mn 0.8195E-02 0.8195E-02 1.0000 -2.086 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005168 g Volume = 0.001627 cm3 Porosity: 99.8383% V(tot) - V(min): 0.10046E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0156000 g log = -1.8069 Original solution: 1000.0103000 g Original solution / Rock added: 64103.22 (Water/Rock Ratio), log = 4.8069 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4557E-04 1.0071 0.4683E-04 0.4650E-04 CH4,gas 0.2909E-13 1.0125 0.3006E-13 0.2968E-13 H2,gas 0.1560E-05 1.0005 0.1592E-05 0.1591E-05 H2S,gas 0.5633E-10 0.9960 0.5725E-10 0.5748E-10 S2,gas 0.4756E-28 1.0000 0.4853E-28 0.4853E-28 CO,gas 0.1948E-13 1.0000 0.1987E-13 0.1987E-13 SO3,gas 0.2434E-35 1.0000 0.2483E-35 0.2483E-35 SO2,gas 0.1507E-18 1.0000 0.1538E-18 0.1538E-18 HCl,gas 0.7146E-15 1.0000 0.7291E-15 0.7291E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.69 -6.03 -2.009 0.10293E+05 -4.329 3 CH4,gas 4.54 -10.68 -15.22 -3.805 0.25990E+05 -13.522 4 H2,gas 8.00 0.50 -7.50 -4.284 0.12801E+05 -5.798 5 H2S,gas -6.23 -18.17 -11.94 -5.971 0.20389E+05 -10.242 6 S2,gas -7.34 -37.35 -30.01 -4.617 0.51246E+05 -28.314 7 CO,gas 3.21 -12.19 -15.40 -4.739 0.26296E+05 -13.702 8 SO3,gas 17.12 -20.18 -37.30 -9.326 0.63696E+05 -35.605 9 SO2,gas 0.83 -19.68 -20.51 -5.470 0.35024E+05 -18.813 10 HCl,gas 5.19 -11.65 -16.84 -8.418 0.28747E+05 -15.137 16 albite -0.38 -4.66 -4.28 -0.329 0.73045E+04 19 spessartine 24.46 19.54 -4.91 -0.246 0.83885E+04 20 analcite 3.32 -0.81 -4.14 -0.460 0.70635E+04 21 andalusite 5.00 1.90 -3.10 -0.310 0.52949E+04 24 anhydrite -5.32 -9.19 -3.87 -1.937 0.66136E+04 29 anorthite 12.71 9.05 -3.66 -0.282 0.62564E+04 35 aragonite 0.97 -1.70 -2.66 -0.888 0.45463E+04 36 brucite 12.57 8.76 -3.81 -0.762 0.65077E+04 37 calcite 0.81 -1.70 -2.51 -0.836 0.42820E+04 40 carpholite-Mg 8.58 6.81 -1.77 -0.118 0.30242E+04 41 carpholite-Fe 6.71 4.59 -2.12 -0.142 0.36275E+04 50 chloritoid-Mg 13.20 10.66 -2.54 -0.169 0.43368E+04 51 chloritoid-Fe 9.17 8.44 -0.74 -0.049 0.12611E+04 52 chloritoid-Mn 11.40 10.35 -1.05 -0.070 0.18007E+04 54 coesite -2.38 -3.85 -1.47 -0.490 0.25114E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.85 -1.29 -0.429 0.21967E+04 67 diopside 16.18 12.06 -4.13 -0.413 0.70438E+04 68 hedenbergite 14.21 9.83 -4.37 -0.437 0.74702E+04 75 epidote 24.67 22.47 -2.19 -0.106 0.37479E+04 76 clinozoisite 22.81 19.07 -3.74 -0.170 0.63868E+04 77 epidote-Fe 29.84 25.88 -3.96 -0.206 0.67556E+04 78 fayalite 14.05 9.22 -4.82 -0.689 0.82362E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.352 0.72222E+04 91 heulandite -5.83 -10.19 -4.36 -0.198 0.74461E+04 92 hercynite 17.28 12.28 -5.00 -0.333 0.85317E+04 98 kaolinite -1.33 -1.95 -0.61 -0.056 0.10476E+04 99 kyanite 4.88 1.90 -2.98 -0.298 0.50808E+04 101 laumontite 2.88 1.35 -1.53 -0.102 0.26141E+04 102 lawsonite 9.62 9.05 -0.57 -0.038 0.97307E+03 105 lizardite 23.24 18.58 -4.67 -0.389 0.79667E+04 106 magnesite 0.69 -3.93 -4.62 -1.541 0.78918E+04 107 magnetite 20.09 19.10 -0.99 -0.081 0.16848E+04 110 magnesioferrite 26.21 21.32 -4.89 -0.399 0.83477E+04 113 margarite 17.32 14.79 -2.53 -0.101 0.43200E+04 116 microcline -2.49 -6.40 -3.91 -0.301 0.66758E+04 120 muscovite 2.58 -0.65 -3.23 -0.190 0.55173E+04 121 paragonite 4.24 1.09 -3.15 -0.186 0.53851E+04 136 prehnite 19.37 16.19 -3.18 -0.187 0.54298E+04 137 prehnite-Fe 22.50 19.60 -2.90 -0.174 0.49459E+04 138 pumpellyite-Fe 46.27 41.79 -4.48 -0.100 0.76453E+04 139 pumpellyite-Mg 48.99 44.01 -4.98 -0.111 0.85036E+04 145 pyroxmangite 7.40 4.60 -2.80 -0.560 0.47803E+04 146 pyrophyllite -6.18 -9.64 -3.46 -0.217 0.59151E+04 147 quartz -2.99 -3.85 -0.86 -0.286 0.14640E+04 151 rhodochrosite -0.98 -4.24 -3.27 -1.089 0.55772E+04 152 rhodonite 7.45 4.60 -2.85 -0.569 0.48605E+04 155 siderite -2.61 -6.15 -3.55 -1.182 0.60546E+04 156 sillimanite 5.26 1.90 -3.36 -0.336 0.57388E+04 163 stilbite -7.52 -10.19 -2.67 -0.127 0.45523E+04 164 stilpnomelane-Fe 13.02 8.78 -4.24 -0.126 0.72340E+04 168 sudoite 21.08 17.47 -3.61 -0.116 0.61616E+04 177 topaz-H 4.62 1.90 -2.72 -0.247 0.46408E+04 178 tridymite -2.63 -3.85 -1.22 -0.407 0.20840E+04 187 wairakite 3.95 1.35 -2.60 -0.153 0.44360E+04 188 walstromite 11.51 7.15 -4.36 -0.873 0.74507E+04 189 wollastonite 10.46 7.15 -3.32 -0.663 0.56611E+04 190 pseudo-wollastonite 11.00 7.15 -3.85 -0.771 0.65809E+04 191 zoisite 22.85 19.07 -3.78 -0.172 0.64609E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.61 -3.96 -0.245 0.67666E+04 196 beidellite-Mg -1.79 -5.98 -4.19 -0.259 0.71501E+04 197 beidellite-Na -1.34 -6.10 -4.76 -0.291 0.81248E+04 199 chalcedony -2.80 -3.85 -1.04 -0.348 0.17833E+04 201 montmorillonite-Ca -2.29 -5.88 -3.59 -0.222 0.61367E+04 202 montmorillonite-K -2.24 -6.95 -4.71 -0.289 0.80464E+04 203 montmorillonite-Mg -2.48 -6.25 -3.77 -0.233 0.64434E+04 204 montmorillonite-Na -2.04 -6.38 -4.34 -0.266 0.74087E+04 205 nontronite-Ca 3.21 1.21 -2.00 -0.130 0.34222E+04 206 nontronite-H 2.53 -0.60 -3.14 -0.210 0.53550E+04 207 nontronite-K 3.34 0.15 -3.19 -0.205 0.54551E+04 208 nontronite-Mg 3.07 0.84 -2.23 -0.145 0.38131E+04 209 nontronite-Na 3.52 0.72 -2.80 -0.180 0.47835E+04 214 gypsum -4.96 -9.19 -4.23 -1.059 0.72311E+04 224 tobermorite 9.82 5.31 -4.51 -1.231 0.77061E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.53 -3.28 -0.819 0.55955E+04 240 silica-amorphous -2.09 -3.85 -1.76 -0.585 0.29975E+04 242 an20ab80 2.02 -1.92 -3.94 -0.303 0.67240E+04 243 an25ab75 2.65 -1.23 -3.88 -0.299 0.66259E+04 244 an30ab70 3.28 -0.55 -3.83 -0.295 0.65374E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0156000 g New total amount of reactant added: 0.0160000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0160000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2970872E-03 Osmotic coef. = 0.9897 True ionic strength = .3068721E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17288E-07 -7.7623 0.16589E-07 -7.7802 0.95958E+00 -0.0179 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13237E-03 -3.8782 0.95945E+00 -0.0180 4 SO4-- 0.25295E-04 -4.5970 0.22621E-04 -4.6455 0.89430E+00 -0.0485 5 HCO3- 0.12540E-04 -4.9017 0.12032E-04 -4.9197 0.95948E+00 -0.0180 6 HS- 0.35500E-10 -10.4498 0.34061E-10 -10.4677 0.95945E+00 -0.0180 7 Al+++ 0.42929E-20 -20.3673 0.34131E-20 -20.4668 0.79507E+00 -0.0996 8 H4SiO4 0.14570E-03 -3.8365 0.14570E-03 -3.8365 0.10000E+01 0.0000 9 Ca++ 0.32338E-04 -4.4903 0.28915E-04 -4.5389 0.89416E+00 -0.0486 10 Mg++ 0.17356E-06 -6.7606 0.15517E-06 -6.8092 0.89406E+00 -0.0486 11 Fe++ 0.10377E-08 -8.9839 0.92783E-09 -9.0325 0.89409E+00 -0.0486 12 K+ 0.33958E-05 -5.4691 0.32582E-05 -5.4870 0.95949E+00 -0.0180 13 Na+ 0.18012E-03 -3.7444 0.17282E-03 -3.7624 0.95945E+00 -0.0180 14 Mn++ 0.87576E-07 -7.0576 0.78302E-07 -7.1062 0.89410E+00 -0.0486 15 HPO4-- 0.15437E-08 -8.8114 0.13806E-08 -8.8599 0.89431E+00 -0.0485 16 HSiO3- 0.85476E-05 -5.0682 0.82010E-05 -5.0861 0.95945E+00 -0.0180 17 Ca(HSiO3)+ 0.56283E-08 -8.2496 0.54003E-08 -8.2676 0.95949E+00 -0.0180 18 Mg(HSiO3)+ 0.37590E-10 -10.4249 0.36067E-10 -10.4429 0.95949E+00 -0.0180 19 NaHSiO3,aq 0.22922E-07 -7.6397 0.22922E-07 -7.6397 0.10000E+01 0.0000 20 AlO+ 0.17585E-11 -11.7548 0.16873E-11 -11.7728 0.95949E+00 -0.0180 21 AlOH+2 0.15588E-15 -15.8072 0.13937E-15 -15.8558 0.89412E+00 -0.0486 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.28172E-05 -5.5502 0.27029E-05 -5.5682 0.95941E+00 -0.0180 24 CH4,aq 0.17600E-16 -16.7545 0.17598E-16 -16.7545 0.99991E+00 0.0000 29 CO,aq 0.12601E-16 -16.8996 0.12601E-16 -16.8996 0.10000E+01 0.0000 30 CO2,aq 0.42654E-06 -6.3700 0.42650E-06 -6.3701 0.99991E+00 0.0000 31 CO3-2 0.70845E-07 -7.1497 0.63354E-07 -7.1982 0.89426E+00 -0.0485 32 CaCO3,aq 0.22970E-07 -7.6388 0.22970E-07 -7.6388 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.92557E-08 -8.0336 0.88808E-08 -8.0515 0.95949E+00 -0.0180 34 CaCl+ 0.64554E-08 -8.1901 0.61939E-08 -8.2080 0.95949E+00 -0.0180 35 CaCl2,aq 0.19478E-12 -12.7105 0.19478E-12 -12.7105 0.10000E+01 0.0000 36 CaOH+ 0.12947E-06 -6.8878 0.12422E-06 -6.9058 0.95949E+00 -0.0180 37 CaSO4,aq 0.20770E-06 -6.6826 0.20770E-06 -6.6826 0.10000E+01 0.0000 38 HCl,aq 0.40237E-12 -12.3954 0.40237E-12 -12.3954 0.10000E+01 0.0000 43 FeCl+ 0.20260E-12 -12.6934 0.19439E-12 -12.7113 0.95949E+00 -0.0180 46 FeO,aq 0.13104E-09 -9.8826 0.13104E-09 -9.8826 0.10000E+01 0.0000 47 FeOH+ 0.18975E-08 -8.7218 0.18206E-08 -8.7398 0.95949E+00 -0.0180 48 HFeO2- 0.86142E-10 -10.0648 0.82649E-10 -10.0828 0.95945E+00 -0.0180 49 FeO+ 0.13197E-12 -12.8795 0.12662E-12 -12.8975 0.95949E+00 -0.0180 50 FeOH+2 0.44864E-18 -18.3481 0.40114E-18 -18.3967 0.89412E+00 -0.0486 51 FeO2- 0.98129E-10 -10.0082 0.94150E-10 -10.0262 0.95945E+00 -0.0180 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.11763E-08 -8.9295 0.11761E-08 -8.9295 0.99991E+00 0.0000 54 KCl,aq 0.78165E-11 -11.1070 0.78165E-11 -11.1070 0.10000E+01 0.0000 55 KHSO4,aq 0.34570E-17 -17.4613 0.34570E-17 -17.4613 0.10000E+01 0.0000 56 KOH,aq 0.83877E-10 -10.0764 0.83877E-10 -10.0764 0.10000E+01 0.0000 57 KSO4- 0.11921E-08 -8.9237 0.11437E-08 -8.9417 0.95945E+00 -0.0180 58 MgCO3,aq 0.30897E-10 -10.5101 0.30897E-10 -10.5101 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.50754E-10 -10.2945 0.48698E-10 -10.3125 0.95949E+00 -0.0180 60 MgCl+ 0.31398E-10 -10.5031 0.30126E-10 -10.5211 0.95949E+00 -0.0180 61 MgOH+ 0.38446E-08 -8.4151 0.36889E-08 -8.4331 0.95949E+00 -0.0180 63 MnO,aq 0.29466E-09 -9.5307 0.29466E-09 -9.5307 0.10000E+01 0.0000 64 MnOH+ 0.14876E-07 -7.8275 0.14273E-07 -7.8455 0.95949E+00 -0.0180 65 MnO2-2 0.39737E-16 -16.4008 0.35535E-16 -16.4493 0.89426E+00 -0.0485 66 HMnO2- 0.13461E-12 -12.8709 0.12915E-12 -12.8889 0.95945E+00 -0.0180 69 MnCl+ 0.66519E-10 -10.1771 0.63824E-10 -10.1950 0.95949E+00 -0.0180 70 MnSO4,aq 0.51135E-09 -9.2913 0.51135E-09 -9.2913 0.10000E+01 0.0000 71 NaCl,aq 0.75808E-08 -8.1203 0.75808E-08 -8.1203 0.10000E+01 0.0000 72 NaOH,aq 0.44759E-08 -8.3491 0.44759E-08 -8.3491 0.10000E+01 0.0000 74 OH- 0.36302E-04 -4.4401 0.34829E-04 -4.4581 0.95941E+00 -0.0180 82 H3PO4,aq 0.26572E-14 -14.5756 0.26572E-14 -14.5756 0.10000E+01 0.0000 83 H2PO4- 0.44033E-09 -9.3562 0.42248E-09 -9.3742 0.95947E+00 -0.0180 84 PO4-3 0.85307E-13 -13.0690 0.67901E-13 -13.1681 0.79596E+00 -0.0991 87 H2P2O7-2 0.15651E-19 -19.8055 0.13996E-19 -19.8540 0.89426E+00 -0.0485 88 HP2O7-3 0.21188E-18 -18.6739 0.16846E-18 -18.7735 0.79507E+00 -0.0996 90 H2S,aq 0.17464E-11 -11.7578 0.17463E-11 -11.7579 0.99991E+00 0.0000 96 SO2,aq 0.32699E-19 -19.4855 0.32699E-19 -19.4855 0.10000E+01 0.0000 97 SO3-2 0.38650E-14 -14.4129 0.34574E-14 -14.4612 0.89456E+00 -0.0484 98 HSO3- 0.37429E-14 -14.4268 0.35911E-14 -14.4448 0.95945E+00 -0.0180 99 HSO4- 0.37691E-09 -9.4238 0.36165E-09 -9.4417 0.95951E+00 -0.0180 101 S2O3-2 0.51891E-18 -18.2849 0.46404E-18 -18.3334 0.89426E+00 -0.0485 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1728770E-07 -.5601424E-04 -.5645747E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999714E+06 0.0000 3 Cl- 0.1379609E-03 0.1379750E-03 0.4891497E+01 3.9020 4 SO4-- 0.2529481E-04 0.2550433E-04 0.2449921E+01 10.9149 5 HCO3- 0.1254039E-04 0.1307008E-04 0.7974782E+00 2.8605 6 HS- 0.3550005E-10 0.2941999E-09 0.9729516E-05 -2.6876 7 Al+++ 0.4292861E-20 0.2837490E-05 0.7655766E-01 2.8737 8 H4SiO4 0.1456993E-03 0.1542755E-03 0.1482785E+02 -3.8365 9 Ca++ 0.3233757E-04 0.3271905E-04 0.1311279E+01 11.0215 10 Mg++ 0.1735563E-06 0.1775515E-06 0.4316517E-02 8.7512 11 Fe++ 0.1037737E-08 0.3449485E-08 0.1926382E-03 6.5278 12 K+ 0.3395765E-05 0.3397049E-05 0.1328278E+00 2.2932 13 Na+ 0.1801210E-03 0.1801560E-03 0.4141639E+01 4.0178 14 Mn++ 0.8757573E-07 0.1033241E-06 0.5676266E-02 8.4541 15 HPO4-- 0.1543739E-08 0.1984159E-08 0.1904325E-03 6.7004 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2518962E-03 -.5601389E-04 -.1958824E-03 0.0000000E+00 2 H2O 0.5550805E+02 0.5550794E+02 0.1104693E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2594788E-04 0.2550418E-04 0.4437087E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4434145E-06 0.2941980E-09 -.4437087E-06 0.0000000E+00 7 Al+++ 0.5217187E-04 0.2837472E-05 0.4933439E-04 0.0000000E+00 8 H4SiO4 0.1666045E-03 0.1542745E-03 0.1232998E-04 0.0000000E+00 9 Ca++ 0.3287334E-04 0.3271885E-04 0.1544951E-06 0.0000000E+00 10 Mg++ 0.1269841E-04 0.1775504E-06 0.1252086E-04 0.0000000E+00 11 Fe++ 0.1140814E-04 0.3449464E-08 0.1140469E-04 0.0000000E+00 12 K+ 0.3397028E-05 0.3397028E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1801549E-03 0.1801549E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2774175E-06 0.1033235E-06 0.1740941E-06 0.0000000E+00 15 HPO4-- 0.9468123E-07 0.1984147E-08 0.9269708E-07 0.0000000E+00 Chg. balance for solid moles: -.2422E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0160000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3090E-07 -7.510 0.1552E-04 -4.809 0.2927 0.4932E-05 clinochlore 0.2504E-05 -5.601 0.1392E-02 -2.856 26.25 0.5294E-03 daphnite 0.1571E-05 -5.804 0.1121E-02 -2.950 21.14 0.3397E-03 chlorite-Mn 0.3482E-07 -7.458 0.2469E-04 -4.608 0.4655 0.7867E-05 diaspore 0.4111E-04 -4.386 0.2466E-02 -2.608 46.51 0.7343E-03 hematite 0.1775E-05 -5.751 0.2834E-03 -3.548 5.345 0.5372E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6093E+00 0.6093E+00 1.0000 -0.215 daphnite 0.3822E+00 0.3822E+00 1.0000 -0.418 chlorite-Mn 0.8472E-02 0.8472E-02 1.0000 -2.072 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005303 g Volume = 0.001670 cm3 Porosity: 99.8341% V(tot) - V(min): 0.10047E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0160000 g log = -1.7959 Original solution: 1000.0103000 g Original solution / Rock added: 62500.64 (Water/Rock Ratio), log = 4.7959 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4441E-04 1.0071 0.4563E-04 0.4531E-04 CH4,gas 0.2507E-13 1.0125 0.2590E-13 0.2558E-13 H2,gas 0.1513E-05 1.0005 0.1544E-05 0.1543E-05 H2S,gas 0.4723E-10 0.9960 0.4800E-10 0.4820E-10 S2,gas 0.3555E-28 1.0000 0.3628E-28 0.3628E-28 CO,gas 0.1840E-13 1.0000 0.1878E-13 0.1878E-13 SO3,gas 0.2307E-35 1.0000 0.2354E-35 0.2354E-35 SO2,gas 0.1386E-18 1.0000 0.1414E-18 0.1414E-18 HCl,gas 0.6958E-15 1.0000 0.7100E-15 0.7100E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.70 -6.04 -2.013 0.10313E+05 -4.341 3 CH4,gas 4.54 -10.74 -15.29 -3.821 0.26100E+05 -13.587 4 H2,gas 8.00 0.49 -7.51 -4.292 0.12824E+05 -5.811 5 H2S,gas -6.23 -18.25 -12.02 -6.009 0.20520E+05 -10.319 6 S2,gas -7.34 -37.47 -30.14 -4.637 0.51462E+05 -28.440 7 CO,gas 3.21 -12.21 -15.43 -4.746 0.26338E+05 -13.726 8 SO3,gas 17.12 -20.21 -37.33 -9.332 0.63735E+05 -35.628 9 SO2,gas 0.83 -19.72 -20.55 -5.480 0.35086E+05 -18.850 10 HCl,gas 5.19 -11.66 -16.85 -8.424 0.28767E+05 -15.149 16 albite -0.38 -4.62 -4.23 -0.326 0.72299E+04 19 spessartine 24.46 19.60 -4.86 -0.243 0.82935E+04 20 analcite 3.32 -0.78 -4.10 -0.456 0.70066E+04 21 andalusite 5.00 1.91 -3.09 -0.309 0.52772E+04 22 andradite 39.01 34.12 -4.89 -0.254 0.83457E+04 24 anhydrite -5.32 -9.18 -3.87 -1.934 0.66038E+04 29 anorthite 12.71 9.10 -3.61 -0.278 0.61717E+04 35 aragonite 0.97 -1.68 -2.64 -0.882 0.45160E+04 36 brucite 12.57 8.75 -3.82 -0.763 0.65181E+04 37 calcite 0.81 -1.68 -2.49 -0.830 0.42518E+04 40 carpholite-Mg 8.58 6.83 -1.76 -0.117 0.29994E+04 41 carpholite-Fe 6.71 4.60 -2.11 -0.141 0.36036E+04 50 chloritoid-Mg 13.20 10.66 -2.54 -0.169 0.43296E+04 51 chloritoid-Fe 9.17 8.44 -0.73 -0.049 0.12549E+04 52 chloritoid-Mn 11.40 10.36 -1.04 -0.069 0.17691E+04 54 coesite -2.38 -3.84 -1.46 -0.487 0.24937E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.84 -1.28 -0.425 0.21791E+04 67 diopside 16.18 12.10 -4.08 -0.408 0.69695E+04 68 hedenbergite 14.21 9.88 -4.33 -0.433 0.73969E+04 75 epidote 24.67 22.56 -2.11 -0.102 0.35961E+04 76 clinozoisite 22.81 19.15 -3.65 -0.166 0.62350E+04 77 epidote-Fe 29.84 25.97 -3.87 -0.201 0.66038E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82413E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.352 0.72211E+04 91 heulandite -5.83 -10.09 -4.26 -0.194 0.72733E+04 95 jadeite 4.22 -0.78 -5.00 -0.500 0.85321E+04 98 kaolinite -1.33 -1.93 -0.59 -0.054 0.10124E+04 99 kyanite 4.88 1.91 -2.97 -0.297 0.50631E+04 101 laumontite 2.88 1.42 -1.46 -0.097 0.24941E+04 102 lawsonite 9.62 9.10 -0.52 -0.035 0.88836E+03 105 lizardite 23.24 18.58 -4.66 -0.389 0.79626E+04 106 magnesite 0.69 -3.95 -4.64 -1.546 0.79214E+04 107 magnetite 20.09 19.09 -0.99 -0.081 0.16962E+04 110 magnesioferrite 26.21 21.32 -4.90 -0.400 0.83581E+04 113 margarite 17.32 14.84 -2.48 -0.099 0.42353E+04 116 microcline -2.49 -6.34 -3.86 -0.297 0.65845E+04 120 muscovite 2.58 -0.60 -3.18 -0.187 0.54260E+04 121 paragonite 4.24 1.13 -3.11 -0.183 0.53106E+04 136 prehnite 19.37 16.28 -3.09 -0.182 0.52780E+04 137 prehnite-Fe 22.50 19.69 -2.81 -0.169 0.47941E+04 138 pumpellyite-Fe 46.27 41.96 -4.31 -0.096 0.73531E+04 139 pumpellyite-Mg 48.99 44.19 -4.81 -0.107 0.82104E+04 145 pyroxmangite 7.40 4.62 -2.78 -0.556 0.47486E+04 146 pyrophyllite -6.18 -9.60 -3.42 -0.214 0.58446E+04 147 quartz -2.99 -3.84 -0.85 -0.282 0.14464E+04 151 rhodochrosite -0.98 -4.25 -3.27 -1.090 0.55824E+04 152 rhodonite 7.45 4.62 -2.83 -0.566 0.48289E+04 155 siderite -2.61 -6.17 -3.56 -1.188 0.60852E+04 156 sillimanite 5.26 1.91 -3.35 -0.335 0.57212E+04 163 stilbite -7.52 -10.09 -2.56 -0.122 0.43794E+04 164 stilpnomelane-Fe 13.02 8.84 -4.18 -0.125 0.71307E+04 168 sudoite 21.08 17.49 -3.59 -0.116 0.61296E+04 177 topaz-H 4.62 1.91 -2.71 -0.246 0.46232E+04 178 tridymite -2.63 -3.84 -1.21 -0.403 0.20664E+04 187 wairakite 3.95 1.42 -2.53 -0.149 0.43161E+04 188 walstromite 11.51 7.18 -4.32 -0.865 0.73836E+04 189 wollastonite 10.46 7.18 -3.28 -0.655 0.55940E+04 190 pseudo-wollastonite 11.00 7.18 -3.81 -0.763 0.65139E+04 191 zoisite 22.85 19.15 -3.69 -0.168 0.63091E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.57 -3.92 -0.243 0.66937E+04 196 beidellite-Mg -1.79 -5.94 -4.15 -0.257 0.70872E+04 197 beidellite-Na -1.34 -6.06 -4.72 -0.289 0.80530E+04 199 chalcedony -2.80 -3.84 -1.03 -0.345 0.17657E+04 201 montmorillonite-Ca -2.29 -5.84 -3.55 -0.220 0.60614E+04 202 montmorillonite-K -2.24 -6.90 -4.67 -0.286 0.79666E+04 203 montmorillonite-Mg -2.48 -6.22 -3.74 -0.231 0.63781E+04 204 montmorillonite-Na -2.04 -6.33 -4.30 -0.263 0.73345E+04 205 nontronite-Ca 3.21 1.25 -1.96 -0.127 0.33494E+04 206 nontronite-H 2.53 -0.57 -3.10 -0.208 0.52903E+04 207 nontronite-K 3.34 0.19 -3.15 -0.202 0.53778E+04 208 nontronite-Mg 3.07 0.88 -2.20 -0.142 0.37501E+04 209 nontronite-Na 3.52 0.76 -2.76 -0.177 0.47117E+04 214 gypsum -4.96 -9.18 -4.23 -1.057 0.72213E+04 224 tobermorite 9.82 5.34 -4.48 -1.222 0.76473E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.53 -3.28 -0.821 0.56069E+04 240 silica-amorphous -2.09 -3.84 -1.75 -0.582 0.29799E+04 242 an20ab80 2.02 -1.88 -3.89 -0.299 0.66474E+04 243 an25ab75 2.65 -1.19 -3.84 -0.295 0.65488E+04 244 an30ab70 3.28 -0.50 -3.78 -0.291 0.64598E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0160000 g New total amount of reactant added: 0.0164000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0164000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2985947E-03 Osmotic coef. = 0.9897 True ionic strength = .3087595E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16850E-07 -7.7734 0.16168E-07 -7.7913 0.95951E+00 -0.0179 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13236E-03 -3.8783 0.95938E+00 -0.0180 4 SO4-- 0.25292E-04 -4.5970 0.22612E-04 -4.6457 0.89405E+00 -0.0486 5 HCO3- 0.12548E-04 -4.9014 0.12039E-04 -4.9194 0.95941E+00 -0.0180 6 HS- 0.30709E-10 -10.5127 0.29461E-10 -10.5307 0.95938E+00 -0.0180 7 Al+++ 0.39768E-20 -20.4005 0.31598E-20 -20.5003 0.79456E+00 -0.0999 8 H4SiO4 0.14911E-03 -3.8265 0.14911E-03 -3.8265 0.10000E+01 0.0000 9 Ca++ 0.32784E-04 -4.4843 0.29306E-04 -4.5330 0.89390E+00 -0.0487 10 Mg++ 0.16266E-06 -6.7887 0.14539E-06 -6.8375 0.89381E+00 -0.0488 11 Fe++ 0.97146E-09 -9.0126 0.86833E-09 -9.0613 0.89383E+00 -0.0487 12 K+ 0.34807E-05 -5.4583 0.33394E-05 -5.4763 0.95942E+00 -0.0180 13 Na+ 0.18062E-03 -3.7432 0.17328E-03 -3.7612 0.95938E+00 -0.0180 14 Mn++ 0.84601E-07 -7.0726 0.75620E-07 -7.1214 0.89385E+00 -0.0487 15 HPO4-- 0.14591E-08 -8.8359 0.13045E-08 -8.8845 0.89405E+00 -0.0486 16 HSiO3- 0.89763E-05 -5.0469 0.86116E-05 -5.0649 0.95938E+00 -0.0180 17 Ca(HSiO3)+ 0.59905E-08 -8.2225 0.57475E-08 -8.2405 0.95942E+00 -0.0180 18 Mg(HSiO3)+ 0.36986E-10 -10.4320 0.35485E-10 -10.4500 0.95942E+00 -0.0180 19 NaHSiO3,aq 0.24135E-07 -7.6173 0.24135E-07 -7.6173 0.10000E+01 0.0000 20 AlO+ 0.17140E-11 -11.7660 0.16445E-11 -11.7840 0.95942E+00 -0.0180 21 AlOH+2 0.14811E-15 -15.8294 0.13239E-15 -15.8781 0.89387E+00 -0.0487 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.28908E-05 -5.5390 0.27732E-05 -5.5570 0.95934E+00 -0.0180 24 CH4,aq 0.15238E-16 -16.8171 0.15236E-16 -16.8171 0.99991E+00 0.0000 29 CO,aq 0.11928E-16 -16.9234 0.11928E-16 -16.9234 0.10000E+01 0.0000 30 CO2,aq 0.41594E-06 -6.3810 0.41590E-06 -6.3810 0.99991E+00 0.0000 31 CO3-2 0.72749E-07 -7.1382 0.65038E-07 -7.1868 0.89401E+00 -0.0487 32 CaCO3,aq 0.23899E-07 -7.6216 0.23899E-07 -7.6216 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.93866E-08 -8.0275 0.90057E-08 -8.0455 0.95942E+00 -0.0180 34 CaCl+ 0.65426E-08 -8.1842 0.62772E-08 -8.2022 0.95942E+00 -0.0180 35 CaCl2,aq 0.19739E-12 -12.7047 0.19739E-12 -12.7047 0.10000E+01 0.0000 36 CaOH+ 0.13465E-06 -6.8708 0.12918E-06 -6.8888 0.95942E+00 -0.0180 37 CaSO4,aq 0.21043E-06 -6.6769 0.21043E-06 -6.6769 0.10000E+01 0.0000 38 HCl,aq 0.39214E-12 -12.4066 0.39214E-12 -12.4066 0.10000E+01 0.0000 43 FeCl+ 0.18961E-12 -12.7221 0.18191E-12 -12.7401 0.95942E+00 -0.0180 46 FeO,aq 0.12910E-09 -9.8891 0.12910E-09 -9.8891 0.10000E+01 0.0000 47 FeOH+ 0.18221E-08 -8.7394 0.17482E-08 -8.7574 0.95942E+00 -0.0180 48 HFeO2- 0.87087E-10 -10.0600 0.83549E-10 -10.0781 0.95938E+00 -0.0180 49 FeO+ 0.12863E-12 -12.8907 0.12341E-12 -12.9087 0.95942E+00 -0.0180 50 FeOH+2 0.42628E-18 -18.3703 0.38104E-18 -18.4190 0.89387E+00 -0.0487 51 FeO2- 0.10069E-09 -9.9970 0.96601E-10 -10.0150 0.95938E+00 -0.0180 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.11418E-08 -8.9424 0.11417E-08 -8.9425 0.99991E+00 0.0000 54 KCl,aq 0.80108E-11 -11.0963 0.80108E-11 -11.0963 0.10000E+01 0.0000 55 KHSO4,aq 0.34519E-17 -17.4619 0.34519E-17 -17.4619 0.10000E+01 0.0000 56 KOH,aq 0.88206E-10 -10.0545 0.88206E-10 -10.0545 0.10000E+01 0.0000 57 KSO4- 0.12214E-08 -8.9132 0.11718E-08 -8.9312 0.95938E+00 -0.0180 58 MgCO3,aq 0.29719E-10 -10.5270 0.29719E-10 -10.5270 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.47583E-10 -10.3225 0.45652E-10 -10.3405 0.95942E+00 -0.0180 60 MgCl+ 0.29418E-10 -10.5314 0.28225E-10 -10.5494 0.95942E+00 -0.0180 61 MgOH+ 0.36963E-08 -8.4322 0.35463E-08 -8.4502 0.95942E+00 -0.0180 63 MnO,aq 0.29959E-09 -9.5235 0.29959E-09 -9.5235 0.10000E+01 0.0000 64 MnOH+ 0.14741E-07 -7.8315 0.14143E-07 -7.8495 0.95942E+00 -0.0180 65 MnO2-2 0.42544E-16 -16.3712 0.38035E-16 -16.4198 0.89401E+00 -0.0487 66 HMnO2- 0.14043E-12 -12.8525 0.13472E-12 -12.8706 0.95938E+00 -0.0180 69 MnCl+ 0.64241E-10 -10.1922 0.61634E-10 -10.2102 0.95942E+00 -0.0180 70 MnSO4,aq 0.49365E-09 -9.3066 0.49365E-09 -9.3066 0.10000E+01 0.0000 71 NaCl,aq 0.76008E-08 -8.1191 0.76008E-08 -8.1191 0.10000E+01 0.0000 72 NaOH,aq 0.46049E-08 -8.3368 0.46049E-08 -8.3368 0.10000E+01 0.0000 74 OH- 0.37250E-04 -4.4289 0.35736E-04 -4.4469 0.95934E+00 -0.0180 82 H3PO4,aq 0.23850E-14 -14.6225 0.23850E-14 -14.6225 0.10000E+01 0.0000 83 H2PO4- 0.40555E-09 -9.3920 0.38908E-09 -9.4100 0.95940E+00 -0.0180 84 PO4-3 0.82758E-13 -13.0822 0.65831E-13 -13.1816 0.79546E+00 -0.0994 87 H2P2O7-2 0.13277E-19 -19.8769 0.11870E-19 -19.9255 0.89401E+00 -0.0487 88 HP2O7-3 0.18450E-18 -18.7340 0.14660E-18 -18.8339 0.79457E+00 -0.0999 90 H2S,aq 0.14723E-11 -11.8320 0.14722E-11 -11.8320 0.99991E+00 0.0000 96 SO2,aq 0.30138E-19 -19.5209 0.30138E-19 -19.5209 0.10000E+01 0.0000 97 SO3-2 0.37513E-14 -14.4258 0.33548E-14 -14.4743 0.89431E+00 -0.0485 98 HSO3- 0.35399E-14 -14.4510 0.33961E-14 -14.4690 0.95938E+00 -0.0180 99 HSO4- 0.36723E-09 -9.4351 0.35233E-09 -9.4530 0.95944E+00 -0.0180 101 S2O3-2 0.43740E-18 -18.3591 0.39104E-18 -18.4078 0.89401E+00 -0.0487 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1685020E-07 -.5770536E-04 -.5816194E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999710E+06 0.0000 3 Cl- 0.1379608E-03 0.1379751E-03 0.4891496E+01 3.9131 4 SO4-- 0.2529209E-04 0.2550435E-04 0.2449922E+01 10.9370 5 HCO3- 0.1254803E-04 0.1307008E-04 0.7974780E+00 2.8719 6 HS- 0.3070867E-10 0.2801972E-09 0.9266429E-05 -2.7394 7 Al+++ 0.3976805E-20 0.2911043E-05 0.7854216E-01 2.8737 8 H4SiO4 0.1491130E-03 0.1581195E-03 0.1519730E+02 -3.8265 9 Ca++ 0.3278408E-04 0.3317497E-04 0.1329550E+01 11.0496 10 Mg++ 0.1626604E-06 0.1665004E-06 0.4047847E-02 8.7452 11 Fe++ 0.9714634E-09 0.3309449E-08 0.1848178E-03 6.5214 12 K+ 0.3480658E-05 0.3481975E-05 0.1361485E+00 2.3150 13 Na+ 0.1806218E-03 0.1806581E-03 0.4153181E+01 4.0301 14 Mn++ 0.8460076E-07 0.1001998E-06 0.5504624E-02 8.4613 15 HPO4-- 0.1459117E-08 0.1864751E-08 0.1789720E-03 6.6981 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2585197E-03 -.5770499E-04 -.2008147E-03 0.0000000E+00 2 H2O 0.5550804E+02 0.5550793E+02 0.1132344E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2595897E-04 0.2550419E-04 0.4547801E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4544999E-06 0.2801954E-09 -.4547801E-06 0.0000000E+00 7 Al+++ 0.5347616E-04 0.2911025E-05 0.5056514E-04 0.0000000E+00 8 H4SiO4 0.1707696E-03 0.1581184E-03 0.1265119E-04 0.0000000E+00 9 Ca++ 0.3333340E-04 0.3317476E-04 0.1586392E-06 0.0000000E+00 10 Mg++ 0.1301587E-04 0.1664994E-06 0.1284937E-04 0.0000000E+00 11 Fe++ 0.1169334E-04 0.3309428E-08 0.1169003E-04 0.0000000E+00 12 K+ 0.3481953E-05 0.3481953E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1806570E-03 0.1806570E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2843530E-06 0.1001991E-06 0.1841538E-06 0.0000000E+00 15 HPO4-- 0.9704826E-07 0.1864739E-08 0.9518352E-07 0.0000000E+00 Chg. balance for solid moles: -.1466E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0164000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3173E-07 -7.499 0.1594E-04 -4.798 0.2931 0.5064E-05 clinochlore 0.2570E-05 -5.590 0.1428E-02 -2.845 26.27 0.5433E-03 daphnite 0.1610E-05 -5.793 0.1149E-02 -2.940 21.13 0.3482E-03 chlorite-Mn 0.3683E-07 -7.434 0.2611E-04 -4.583 0.4802 0.8321E-05 diaspore 0.4213E-04 -4.375 0.2527E-02 -2.597 46.48 0.7524E-03 hematite 0.1819E-05 -5.740 0.2905E-03 -3.537 5.343 0.5506E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3819E+00 0.3819E+00 1.0000 -0.418 chlorite-Mn 0.8734E-02 0.8734E-02 1.0000 -2.059 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005437 g Volume = 0.001712 cm3 Porosity: 99.8299% V(tot) - V(min): 0.10048E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0164000 g log = -1.7852 Original solution: 1000.0103000 g Original solution / Rock added: 60976.24 (Water/Rock Ratio), log = 4.7852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4330E-04 1.0071 0.4450E-04 0.4418E-04 CH4,gas 0.2171E-13 1.0125 0.2243E-13 0.2215E-13 H2,gas 0.1468E-05 1.0005 0.1499E-05 0.1498E-05 H2S,gas 0.3982E-10 0.9960 0.4047E-10 0.4063E-10 S2,gas 0.2682E-28 1.0000 0.2736E-28 0.2736E-28 CO,gas 0.1742E-13 1.0000 0.1778E-13 0.1778E-13 SO3,gas 0.2190E-35 1.0000 0.2235E-35 0.2235E-35 SO2,gas 0.1277E-18 1.0000 0.1303E-18 0.1303E-18 HCl,gas 0.6781E-15 1.0000 0.6919E-15 0.6919E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.71 -6.05 -2.017 0.10331E+05 -4.352 3 CH4,gas 4.54 -10.80 -15.35 -3.837 0.26207E+05 -13.649 4 H2,gas 8.00 0.48 -7.52 -4.299 0.12846E+05 -5.824 5 H2S,gas -6.23 -18.32 -12.09 -6.046 0.20647E+05 -10.393 6 S2,gas -7.34 -37.60 -30.26 -4.656 0.51671E+05 -28.563 7 CO,gas 3.21 -12.23 -15.45 -4.754 0.26379E+05 -13.750 8 SO3,gas 17.12 -20.23 -37.35 -9.337 0.63774E+05 -35.651 9 SO2,gas 0.83 -19.75 -20.58 -5.489 0.35146E+05 -18.885 10 HCl,gas 5.19 -11.67 -16.86 -8.429 0.28786E+05 -15.160 16 albite -0.38 -4.58 -4.19 -0.322 0.71574E+04 19 spessartine 24.46 19.65 -4.81 -0.240 0.82051E+04 20 analcite 3.32 -0.75 -4.07 -0.452 0.69512E+04 21 andalusite 5.00 1.92 -3.08 -0.308 0.52601E+04 22 andradite 39.01 34.24 -4.77 -0.248 0.81499E+04 24 anhydrite -5.32 -9.18 -3.86 -1.931 0.65941E+04 29 anorthite 12.71 9.14 -3.57 -0.274 0.60893E+04 35 aragonite 0.97 -1.66 -2.63 -0.876 0.44866E+04 36 brucite 12.57 8.75 -3.82 -0.765 0.65283E+04 37 calcite 0.81 -1.66 -2.47 -0.824 0.42224E+04 40 carpholite-Mg 8.58 6.84 -1.74 -0.116 0.29752E+04 41 carpholite-Fe 6.71 4.62 -2.10 -0.140 0.35803E+04 50 chloritoid-Mg 13.20 10.67 -2.53 -0.169 0.43226E+04 51 chloritoid-Fe 9.17 8.44 -0.73 -0.049 0.12487E+04 52 chloritoid-Mn 11.40 10.38 -1.02 -0.068 0.17396E+04 54 coesite -2.38 -3.83 -1.45 -0.483 0.24766E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.83 -1.27 -0.422 0.21619E+04 67 diopside 16.18 12.14 -4.04 -0.404 0.68973E+04 68 hedenbergite 14.21 9.92 -4.29 -0.429 0.73255E+04 75 epidote 24.67 22.65 -2.02 -0.098 0.34484E+04 76 clinozoisite 22.81 19.24 -3.57 -0.162 0.60873E+04 77 epidote-Fe 29.84 26.06 -3.78 -0.196 0.64561E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82462E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.352 0.72198E+04 91 heulandite -5.83 -9.99 -4.16 -0.189 0.71050E+04 95 jadeite 4.22 -0.75 -4.96 -0.496 0.84767E+04 98 kaolinite -1.33 -1.91 -0.57 -0.052 0.97805E+03 99 kyanite 4.88 1.92 -2.96 -0.296 0.50460E+04 101 laumontite 2.88 1.49 -1.39 -0.093 0.23773E+04 102 lawsonite 9.62 9.14 -0.47 -0.031 0.80593E+03 105 lizardite 23.24 18.58 -4.66 -0.388 0.79588E+04 106 magnesite 0.69 -3.97 -4.66 -1.552 0.79502E+04 107 magnetite 20.09 19.09 -1.00 -0.082 0.17072E+04 110 magnesioferrite 26.21 21.31 -4.90 -0.400 0.83683E+04 113 margarite 17.32 14.89 -2.43 -0.097 0.41528E+04 116 microcline -2.49 -6.29 -3.80 -0.293 0.64957E+04 120 muscovite 2.58 -0.54 -3.13 -0.184 0.53372E+04 121 paragonite 4.24 1.17 -3.07 -0.180 0.52380E+04 136 prehnite 19.37 16.37 -3.00 -0.177 0.51304E+04 137 prehnite-Fe 22.50 19.78 -2.72 -0.164 0.46464E+04 138 pumpellyite-Fe 46.27 42.13 -4.14 -0.092 0.70688E+04 139 pumpellyite-Mg 48.99 44.35 -4.64 -0.103 0.79253E+04 145 pyroxmangite 7.40 4.63 -2.76 -0.553 0.47192E+04 146 pyrophyllite -6.18 -9.56 -3.38 -0.211 0.57759E+04 147 quartz -2.99 -3.83 -0.84 -0.279 0.14292E+04 151 rhodochrosite -0.98 -4.25 -3.27 -1.091 0.55888E+04 152 rhodonite 7.45 4.63 -2.81 -0.562 0.47994E+04 155 siderite -2.61 -6.19 -3.58 -1.194 0.61149E+04 156 sillimanite 5.26 1.92 -3.34 -0.334 0.57040E+04 163 stilbite -7.52 -9.99 -2.47 -0.117 0.42111E+04 164 stilpnomelane-Fe 13.02 8.90 -4.12 -0.123 0.70298E+04 168 sudoite 21.08 17.51 -3.57 -0.115 0.60984E+04 174 tephroite 18.09 13.10 -4.99 -0.713 0.85196E+04 177 topaz-H 4.62 1.92 -2.70 -0.245 0.46060E+04 178 tridymite -2.63 -3.83 -1.20 -0.400 0.20492E+04 187 wairakite 3.95 1.49 -2.46 -0.145 0.41993E+04 188 walstromite 11.51 7.22 -4.29 -0.857 0.73183E+04 189 wollastonite 10.46 7.22 -3.24 -0.648 0.55288E+04 190 pseudo-wollastonite 11.00 7.22 -3.78 -0.755 0.64486E+04 191 zoisite 22.85 19.24 -3.61 -0.164 0.61614E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.52 -3.88 -0.240 0.66228E+04 196 beidellite-Mg -1.79 -5.90 -4.11 -0.255 0.70258E+04 197 beidellite-Na -1.34 -6.02 -4.68 -0.286 0.79830E+04 199 chalcedony -2.80 -3.83 -1.02 -0.341 0.17485E+04 201 montmorillonite-Ca -2.29 -5.80 -3.51 -0.217 0.59882E+04 202 montmorillonite-K -2.24 -6.86 -4.62 -0.283 0.78890E+04 203 montmorillonite-Mg -2.48 -6.18 -3.70 -0.229 0.63144E+04 204 montmorillonite-Na -2.04 -6.29 -4.25 -0.260 0.72622E+04 205 nontronite-Ca 3.21 1.29 -1.92 -0.125 0.32784E+04 206 nontronite-H 2.53 -0.53 -3.06 -0.205 0.52272E+04 207 nontronite-K 3.34 0.24 -3.11 -0.199 0.53025E+04 208 nontronite-Mg 3.07 0.91 -2.16 -0.140 0.36887E+04 209 nontronite-Na 3.52 0.80 -2.72 -0.174 0.46417E+04 214 gypsum -4.96 -9.18 -4.22 -1.056 0.72117E+04 224 tobermorite 9.82 5.38 -4.45 -1.213 0.75900E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.52 -3.29 -0.823 0.56179E+04 240 silica-amorphous -2.09 -3.83 -1.74 -0.578 0.29627E+04 242 an20ab80 2.02 -1.83 -3.85 -0.296 0.65729E+04 243 an25ab75 2.65 -1.15 -3.79 -0.292 0.64737E+04 244 an30ab70 3.28 -0.46 -3.74 -0.288 0.63842E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0164000 g New total amount of reactant added: 0.0168000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0168000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3001024E-03 Osmotic coef. = 0.9896 True ionic strength = .3106499E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16437E-07 -7.7842 0.15770E-07 -7.8022 0.95945E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13235E-03 -3.8783 0.95931E+00 -0.0180 4 SO4-- 0.25289E-04 -4.5971 0.22604E-04 -4.6458 0.89380E+00 -0.0488 5 HCO3- 0.12555E-04 -4.9012 0.12045E-04 -4.9192 0.95934E+00 -0.0180 6 HS- 0.26679E-10 -10.5738 0.25593E-10 -10.5919 0.95932E+00 -0.0180 7 Al+++ 0.36928E-20 -20.4326 0.29323E-20 -20.5328 0.79406E+00 -0.1001 8 H4SiO4 0.15252E-03 -3.8167 0.15252E-03 -3.8167 0.10000E+01 0.0000 9 Ca++ 0.33231E-04 -4.4785 0.29697E-04 -4.5273 0.89365E+00 -0.0488 10 Mg++ 0.15274E-06 -6.8161 0.13648E-06 -6.8649 0.89356E+00 -0.0489 11 Fe++ 0.91127E-09 -9.0404 0.81429E-09 -9.0892 0.89358E+00 -0.0489 12 K+ 0.35656E-05 -5.4479 0.34206E-05 -5.4659 0.95935E+00 -0.0180 13 Na+ 0.18112E-03 -3.7420 0.17375E-03 -3.7601 0.95931E+00 -0.0180 14 Mn++ 0.81682E-07 -7.0879 0.72991E-07 -7.1367 0.89360E+00 -0.0489 15 HPO4-- 0.13810E-08 -8.8598 0.12344E-08 -8.9086 0.89380E+00 -0.0488 16 HSiO3- 0.94135E-05 -5.0262 0.90305E-05 -5.0443 0.95931E+00 -0.0180 17 Ca(HSiO3)+ 0.63661E-08 -8.1961 0.61074E-08 -8.2141 0.95936E+00 -0.0180 18 Mg(HSiO3)+ 0.36411E-10 -10.4388 0.34932E-10 -10.4568 0.95936E+00 -0.0180 19 NaHSiO3,aq 0.25378E-07 -7.5955 0.25378E-07 -7.5955 0.10000E+01 0.0000 20 AlO+ 0.16720E-11 -11.7768 0.16040E-11 -11.7948 0.95936E+00 -0.0180 21 AlOH+2 0.14095E-15 -15.8509 0.12596E-15 -15.8998 0.89362E+00 -0.0488 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.29639E-05 -5.5281 0.28432E-05 -5.5462 0.95927E+00 -0.0181 24 CH4,aq 0.13249E-16 -16.8778 0.13247E-16 -16.8779 0.99991E+00 0.0000 29 CO,aq 0.11309E-16 -16.9466 0.11309E-16 -16.9466 0.10000E+01 0.0000 30 CO2,aq 0.40591E-06 -6.3916 0.40587E-06 -6.3916 0.99991E+00 0.0000 31 CO3-2 0.74642E-07 -7.1270 0.66711E-07 -7.1758 0.89376E+00 -0.0488 32 CaCO3,aq 0.24841E-07 -7.6048 0.24841E-07 -7.6048 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.95171E-08 -8.0215 0.91303E-08 -8.0395 0.95936E+00 -0.0180 34 CaCl+ 0.66299E-08 -8.1785 0.63604E-08 -8.1965 0.95936E+00 -0.0180 35 CaCl2,aq 0.19999E-12 -12.6990 0.19999E-12 -12.6990 0.10000E+01 0.0000 36 CaOH+ 0.13989E-06 -6.8542 0.13421E-06 -6.8722 0.95936E+00 -0.0180 37 CaSO4,aq 0.21315E-06 -6.6713 0.21315E-06 -6.6713 0.10000E+01 0.0000 38 HCl,aq 0.38246E-12 -12.4174 0.38246E-12 -12.4174 0.10000E+01 0.0000 43 FeCl+ 0.17781E-12 -12.7500 0.17058E-12 -12.7681 0.95936E+00 -0.0180 46 FeO,aq 0.12725E-09 -9.8953 0.12725E-09 -9.8953 0.10000E+01 0.0000 47 FeOH+ 0.17520E-08 -8.7565 0.16808E-08 -8.7745 0.95936E+00 -0.0180 48 HFeO2- 0.88010E-10 -10.0555 0.84429E-10 -10.0735 0.95931E+00 -0.0180 49 FeO+ 0.12547E-12 -12.9015 0.12037E-12 -12.9195 0.95936E+00 -0.0180 50 FeOH+2 0.40568E-18 -18.3918 0.36252E-18 -18.4407 0.89362E+00 -0.0488 51 FeO2- 0.10324E-09 -9.9862 0.99038E-10 -10.0042 0.95931E+00 -0.0180 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.11093E-08 -8.9549 0.11092E-08 -8.9550 0.99991E+00 0.0000 54 KCl,aq 0.82050E-11 -11.0859 0.82050E-11 -11.0859 0.10000E+01 0.0000 55 KHSO4,aq 0.34475E-17 -17.4625 0.34475E-17 -17.4625 0.10000E+01 0.0000 56 KOH,aq 0.92630E-10 -10.0332 0.92630E-10 -10.0332 0.10000E+01 0.0000 57 KSO4- 0.12507E-08 -8.9029 0.11998E-08 -8.9209 0.95931E+00 -0.0180 58 MgCO3,aq 0.28616E-10 -10.5434 0.28616E-10 -10.5434 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.44693E-10 -10.3498 0.42877E-10 -10.3678 0.95936E+00 -0.0180 60 MgCl+ 0.27616E-10 -10.5588 0.26494E-10 -10.5769 0.95936E+00 -0.0180 61 MgOH+ 0.35576E-08 -8.4488 0.34130E-08 -8.4669 0.95936E+00 -0.0180 63 MnO,aq 0.30394E-09 -9.5172 0.30394E-09 -9.5172 0.10000E+01 0.0000 64 MnOH+ 0.14589E-07 -7.8360 0.13996E-07 -7.8540 0.95936E+00 -0.0180 65 MnO2-2 0.45379E-16 -16.3431 0.40558E-16 -16.3919 0.89376E+00 -0.0488 66 HMnO2- 0.14607E-12 -12.8354 0.14013E-12 -12.8535 0.95931E+00 -0.0180 69 MnCl+ 0.62007E-10 -10.2076 0.59486E-10 -10.2256 0.95936E+00 -0.0180 70 MnSO4,aq 0.47630E-09 -9.3221 0.47630E-09 -9.3221 0.10000E+01 0.0000 71 NaCl,aq 0.76208E-08 -8.1180 0.76208E-08 -8.1180 0.10000E+01 0.0000 72 NaOH,aq 0.47338E-08 -8.3248 0.47338E-08 -8.3248 0.10000E+01 0.0000 74 OH- 0.38192E-04 -4.4180 0.36637E-04 -4.4361 0.95927E+00 -0.0181 82 H3PO4,aq 0.21471E-14 -14.6682 0.21471E-14 -14.6682 0.10000E+01 0.0000 83 H2PO4- 0.37432E-09 -9.4268 0.35910E-09 -9.4448 0.95933E+00 -0.0180 84 PO4-3 0.80332E-13 -13.0951 0.63861E-13 -13.1948 0.79496E+00 -0.0997 87 H2P2O7-2 0.11313E-19 -19.9464 0.10111E-19 -19.9952 0.89376E+00 -0.0488 88 HP2O7-3 0.16122E-18 -18.7926 0.12802E-18 -18.8927 0.79407E+00 -0.1001 90 H2S,aq 0.12475E-11 -11.9040 0.12474E-11 -11.9040 0.99991E+00 0.0000 96 SO2,aq 0.27847E-19 -19.5552 0.27847E-19 -19.5552 0.10000E+01 0.0000 97 SO3-2 0.36442E-14 -14.4384 0.32581E-14 -14.4870 0.89406E+00 -0.0486 98 HSO3- 0.33535E-14 -14.4745 0.32171E-14 -14.4925 0.95931E+00 -0.0180 99 HSO4- 0.35808E-09 -9.4460 0.34353E-09 -9.4640 0.95938E+00 -0.0180 101 S2O3-2 0.37059E-18 -18.4311 0.33121E-18 -18.4799 0.89376E+00 -0.0488 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1643681E-07 -.5939725E-04 -.5986721E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999706E+06 0.0000 3 Cl- 0.1379607E-03 0.1379751E-03 0.4891494E+01 3.9239 4 SO4-- 0.2528937E-04 0.2550437E-04 0.2449922E+01 10.9585 5 HCO3- 0.1255510E-04 0.1307009E-04 0.7974778E+00 2.8830 6 HS- 0.2667862E-10 0.2675031E-09 0.8846615E-05 -2.7897 7 Al+++ 0.3692797E-20 0.2984163E-05 0.8051495E-01 2.8737 8 H4SiO4 0.1525187E-03 0.1619640E-03 0.1556681E+02 -3.8167 9 Ca++ 0.3323051E-04 0.3363091E-04 0.1347822E+01 11.0770 10 Mg++ 0.1527382E-06 0.1564331E-06 0.3803096E-02 8.7394 11 Fe++ 0.9112665E-09 0.3180688E-08 0.1776269E-03 6.5151 12 K+ 0.3565551E-05 0.3566902E-05 0.1394691E+00 2.3363 13 Na+ 0.1811225E-03 0.1811603E-03 0.4164723E+01 4.0421 14 Mn++ 0.8168160E-07 0.9711262E-07 0.5335025E-02 8.4676 15 HPO4-- 0.1381025E-08 0.1755429E-08 0.1684796E-03 6.6958 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2651431E-03 -.5939687E-04 -.2057462E-03 0.0000000E+00 2 H2O 0.5550804E+02 0.5550792E+02 0.1159999E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2597006E-04 0.2550420E-04 0.4658528E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4655853E-06 0.2675013E-09 -.4658528E-06 0.0000000E+00 7 Al+++ 0.5478046E-04 0.2984143E-05 0.5179632E-04 0.0000000E+00 8 H4SiO4 0.1749348E-03 0.1619630E-03 0.1297177E-04 0.0000000E+00 9 Ca++ 0.3379346E-04 0.3363069E-04 0.1627664E-06 0.0000000E+00 10 Mg++ 0.1333333E-04 0.1564321E-06 0.1317690E-04 0.0000000E+00 11 Fe++ 0.1197854E-04 0.3180667E-08 0.1197536E-04 0.0000000E+00 12 K+ 0.3566879E-05 0.3566879E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1811591E-03 0.1811591E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2912884E-06 0.9711199E-07 0.1941764E-06 0.0000000E+00 15 HPO4-- 0.9941529E-07 0.1755417E-08 0.9765987E-07 0.0000000E+00 Chg. balance for solid moles: -.2748E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0168000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3255E-07 -7.487 0.1635E-04 -4.786 0.2935 0.5196E-05 clinochlore 0.2635E-05 -5.579 0.1465E-02 -2.834 26.29 0.5572E-03 daphnite 0.1650E-05 -5.783 0.1177E-02 -2.929 21.13 0.3567E-03 chlorite-Mn 0.3884E-07 -7.411 0.2753E-04 -4.560 0.4941 0.8774E-05 diaspore 0.4315E-04 -4.365 0.2588E-02 -2.587 46.46 0.7706E-03 hematite 0.1863E-05 -5.730 0.2976E-03 -3.526 5.341 0.5640E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3815E+00 0.3815E+00 1.0000 -0.418 chlorite-Mn 0.8981E-02 0.8981E-02 1.0000 -2.047 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005572 g Volume = 0.001755 cm3 Porosity: 99.8257% V(tot) - V(min): 0.10050E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0168000 g log = -1.7747 Original solution: 1000.0103000 g Original solution / Rock added: 59524.42 (Water/Rock Ratio), log = 4.7747 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4226E-04 1.0071 0.4342E-04 0.4312E-04 CH4,gas 0.1887E-13 1.0125 0.1950E-13 0.1926E-13 H2,gas 0.1426E-05 1.0005 0.1456E-05 0.1455E-05 H2S,gas 0.3374E-10 0.9960 0.3429E-10 0.3443E-10 S2,gas 0.2040E-28 1.0000 0.2081E-28 0.2081E-28 CO,gas 0.1652E-13 1.0000 0.1685E-13 0.1685E-13 SO3,gas 0.2083E-35 1.0000 0.2126E-35 0.2126E-35 SO2,gas 0.1180E-18 1.0000 0.1204E-18 0.1204E-18 HCl,gas 0.6614E-15 1.0000 0.6749E-15 0.6749E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.72 -6.06 -2.020 0.10349E+05 -4.362 3 CH4,gas 4.54 -10.87 -15.41 -3.852 0.26310E+05 -13.710 4 H2,gas 8.00 0.46 -7.54 -4.306 0.12867E+05 -5.837 5 H2S,gas -6.23 -18.39 -12.16 -6.082 0.20769E+05 -10.465 6 S2,gas -7.34 -37.72 -30.38 -4.674 0.51874E+05 -28.682 7 CO,gas 3.21 -12.26 -15.47 -4.761 0.26419E+05 -13.773 8 SO3,gas 17.12 -20.25 -37.37 -9.343 0.63811E+05 -35.673 9 SO2,gas 0.83 -19.79 -20.62 -5.498 0.35205E+05 -18.919 10 HCl,gas 5.19 -11.68 -16.87 -8.435 0.28805E+05 -15.171 16 albite -0.38 -4.53 -4.15 -0.319 0.70866E+04 19 spessartine 24.46 19.70 -4.76 -0.238 0.81228E+04 20 analcite 3.32 -0.72 -4.04 -0.449 0.68972E+04 21 andalusite 5.00 1.93 -3.07 -0.307 0.52433E+04 22 andradite 39.01 34.35 -4.66 -0.242 0.79594E+04 24 anhydrite -5.32 -9.17 -3.86 -1.928 0.65845E+04 29 anorthite 12.71 9.19 -3.52 -0.271 0.60090E+04 35 aragonite 0.97 -1.64 -2.61 -0.870 0.44580E+04 36 brucite 12.57 8.74 -3.83 -0.766 0.65382E+04 37 calcite 0.81 -1.64 -2.46 -0.819 0.41937E+04 40 carpholite-Mg 8.58 6.85 -1.73 -0.115 0.29516E+04 41 carpholite-Fe 6.71 4.63 -2.08 -0.139 0.35575E+04 50 chloritoid-Mg 13.20 10.67 -2.53 -0.169 0.43158E+04 51 chloritoid-Fe 9.17 8.45 -0.73 -0.049 0.12427E+04 52 chloritoid-Mn 11.40 10.40 -1.00 -0.067 0.17122E+04 54 coesite -2.38 -3.82 -1.44 -0.480 0.24598E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.82 -1.26 -0.419 0.21452E+04 67 diopside 16.18 12.18 -4.00 -0.400 0.68270E+04 68 hedenbergite 14.21 9.96 -4.25 -0.425 0.72559E+04 75 epidote 24.67 22.73 -1.94 -0.094 0.33046E+04 76 clinozoisite 22.81 19.33 -3.48 -0.158 0.59436E+04 77 epidote-Fe 29.84 26.14 -3.70 -0.192 0.63123E+04 78 fayalite 14.05 9.21 -4.83 -0.690 0.82508E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.352 0.72184E+04 91 heulandite -5.83 -9.89 -4.07 -0.185 0.69410E+04 95 jadeite 4.22 -0.72 -4.93 -0.493 0.84227E+04 98 kaolinite -1.33 -1.89 -0.55 -0.050 0.94456E+03 99 kyanite 4.88 1.93 -2.95 -0.295 0.50292E+04 101 laumontite 2.88 1.56 -1.33 -0.088 0.22636E+04 102 lawsonite 9.62 9.19 -0.43 -0.028 0.72568E+03 105 lizardite 23.24 18.58 -4.66 -0.388 0.79551E+04 106 magnesite 0.69 -3.98 -4.67 -1.558 0.79783E+04 107 magnetite 20.09 19.08 -1.01 -0.082 0.17179E+04 110 magnesioferrite 26.21 21.31 -4.91 -0.401 0.83783E+04 113 margarite 17.32 14.94 -2.39 -0.095 0.40726E+04 116 microcline -2.49 -6.24 -3.75 -0.289 0.64091E+04 120 muscovite 2.58 -0.49 -3.08 -0.181 0.52507E+04 121 paragonite 4.24 1.21 -3.03 -0.178 0.51673E+04 136 prehnite 19.37 16.45 -2.92 -0.172 0.49866E+04 137 prehnite-Fe 22.50 19.86 -2.64 -0.159 0.45027E+04 138 pumpellyite-Fe 46.27 42.29 -3.98 -0.088 0.67919E+04 139 pumpellyite-Mg 48.99 44.52 -4.48 -0.100 0.76477E+04 145 pyroxmangite 7.40 4.65 -2.75 -0.550 0.46917E+04 146 pyrophyllite -6.18 -9.52 -3.34 -0.209 0.57090E+04 147 quartz -2.99 -3.82 -0.83 -0.276 0.14125E+04 151 rhodochrosite -0.98 -4.25 -3.28 -1.092 0.55962E+04 152 rhodonite 7.45 4.65 -2.79 -0.559 0.47720E+04 153 sanidine -1.28 -6.24 -4.96 -0.382 0.84769E+04 155 siderite -2.61 -6.21 -3.60 -1.199 0.61437E+04 156 sillimanite 5.26 1.93 -3.33 -0.333 0.56873E+04 163 stilbite -7.52 -9.89 -2.37 -0.113 0.40472E+04 164 stilpnomelane-Fe 13.02 8.96 -4.06 -0.121 0.69312E+04 168 sudoite 21.08 17.52 -3.55 -0.115 0.60680E+04 174 tephroite 18.09 13.12 -4.97 -0.710 0.84815E+04 177 topaz-H 4.62 1.93 -2.69 -0.244 0.45893E+04 178 tridymite -2.63 -3.82 -1.19 -0.397 0.20325E+04 187 wairakite 3.95 1.56 -2.39 -0.141 0.40855E+04 188 walstromite 11.51 7.26 -4.25 -0.850 0.72548E+04 189 wollastonite 10.46 7.26 -3.20 -0.640 0.54653E+04 190 pseudo-wollastonite 11.00 7.26 -3.74 -0.748 0.63851E+04 191 zoisite 22.85 19.33 -3.52 -0.160 0.60176E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.48 -3.84 -0.237 0.65536E+04 194 beidellite-H -2.33 -7.31 -4.99 -0.318 0.85122E+04 196 beidellite-Mg -1.79 -5.87 -4.08 -0.252 0.69660E+04 197 beidellite-Na -1.34 -5.98 -4.64 -0.284 0.79148E+04 199 chalcedony -2.80 -3.82 -1.01 -0.338 0.17318E+04 201 montmorillonite-Ca -2.29 -5.76 -3.47 -0.214 0.59167E+04 202 montmorillonite-K -2.24 -6.81 -4.58 -0.280 0.78133E+04 203 montmorillonite-Mg -2.48 -6.14 -3.66 -0.227 0.62523E+04 204 montmorillonite-Na -2.04 -6.25 -4.21 -0.258 0.71918E+04 205 nontronite-Ca 3.21 1.34 -1.88 -0.122 0.32092E+04 206 nontronite-H 2.53 -0.49 -3.03 -0.203 0.51658E+04 207 nontronite-K 3.34 0.28 -3.06 -0.197 0.52290E+04 208 nontronite-Mg 3.07 0.95 -2.13 -0.138 0.36289E+04 209 nontronite-Na 3.52 0.84 -2.68 -0.172 0.45735E+04 214 gypsum -4.96 -9.17 -4.22 -1.055 0.72021E+04 224 tobermorite 9.82 5.41 -4.41 -1.204 0.75343E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.52 -3.30 -0.824 0.56286E+04 240 silica-amorphous -2.09 -3.82 -1.73 -0.575 0.29460E+04 242 an20ab80 2.02 -1.79 -3.81 -0.293 0.65003E+04 243 an25ab75 2.65 -1.10 -3.75 -0.288 0.64007E+04 244 an30ab70 3.28 -0.42 -3.70 -0.284 0.63106E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0168000 g New total amount of reactant added: 0.0172000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0172000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3016100E-03 Osmotic coef. = 0.9896 True ionic strength = .3125430E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16046E-07 -7.7946 0.15394E-07 -7.8127 0.95938E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13234E-03 -3.8783 0.95925E+00 -0.0181 4 SO4-- 0.25287E-04 -4.5971 0.22595E-04 -4.6460 0.89355E+00 -0.0489 5 HCO3- 0.12562E-04 -4.9010 0.12050E-04 -4.9190 0.95928E+00 -0.0181 6 HS- 0.23272E-10 -10.6332 0.22323E-10 -10.6512 0.95925E+00 -0.0181 7 Al+++ 0.34368E-20 -20.4638 0.27273E-20 -20.5643 0.79356E+00 -0.1004 8 H4SiO4 0.15592E-03 -3.8071 0.15592E-03 -3.8071 0.10000E+01 0.0000 9 Ca++ 0.33677E-04 -4.4727 0.30087E-04 -4.5216 0.89340E+00 -0.0490 10 Mg++ 0.14368E-06 -6.8426 0.12835E-06 -6.8916 0.89331E+00 -0.0490 11 Fe++ 0.85644E-09 -9.0673 0.76509E-09 -9.1163 0.89333E+00 -0.0490 12 K+ 0.36504E-05 -5.4377 0.35018E-05 -5.4557 0.95928E+00 -0.0181 13 Na+ 0.18162E-03 -3.7408 0.17422E-03 -3.7589 0.95924E+00 -0.0181 14 Mn++ 0.78829E-07 -7.1033 0.70422E-07 -7.1523 0.89335E+00 -0.0490 15 HPO4-- 0.13088E-08 -8.8831 0.11695E-08 -8.9320 0.89355E+00 -0.0489 16 HSiO3- 0.98592E-05 -5.0062 0.94574E-05 -5.0242 0.95925E+00 -0.0181 17 Ca(HSiO3)+ 0.67552E-08 -8.1704 0.64802E-08 -8.1884 0.95929E+00 -0.0181 18 Mg(HSiO3)+ 0.35864E-10 -10.4453 0.34404E-10 -10.4634 0.95929E+00 -0.0181 19 NaHSiO3,aq 0.26649E-07 -7.5743 0.26649E-07 -7.5743 0.10000E+01 0.0000 20 AlO+ 0.16322E-11 -11.7872 0.15657E-11 -11.8053 0.95929E+00 -0.0181 21 AlOH+2 0.13434E-15 -15.8718 0.12002E-15 -15.9208 0.89337E+00 -0.0490 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.30366E-05 -5.5176 0.29127E-05 -5.5357 0.95921E+00 -0.0181 24 CH4,aq 0.11566E-16 -16.9368 0.11564E-16 -16.9369 0.99991E+00 0.0000 29 CO,aq 0.10739E-16 -16.9690 0.10739E-16 -16.9690 0.10000E+01 0.0000 30 CO2,aq 0.39640E-06 -6.4019 0.39636E-06 -6.4019 0.99991E+00 0.0000 31 CO3-2 0.76522E-07 -7.1162 0.68373E-07 -7.1651 0.89351E+00 -0.0489 32 CaCO3,aq 0.25794E-07 -7.5885 0.25794E-07 -7.5885 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.96473E-08 -8.0156 0.92545E-08 -8.0336 0.95929E+00 -0.0181 34 CaCl+ 0.67170E-08 -8.1728 0.64436E-08 -8.1909 0.95929E+00 -0.0181 35 CaCl2,aq 0.20259E-12 -12.6934 0.20259E-12 -12.6934 0.10000E+01 0.0000 36 CaOH+ 0.14521E-06 -6.8380 0.13929E-06 -6.8561 0.95929E+00 -0.0181 37 CaSO4,aq 0.21587E-06 -6.6658 0.21587E-06 -6.6658 0.10000E+01 0.0000 38 HCl,aq 0.37331E-12 -12.4279 0.37331E-12 -12.4279 0.10000E+01 0.0000 43 FeCl+ 0.16706E-12 -12.7771 0.16026E-12 -12.7952 0.95929E+00 -0.0181 46 FeO,aq 0.12548E-09 -9.9014 0.12548E-09 -9.9014 0.10000E+01 0.0000 47 FeOH+ 0.16865E-08 -8.7730 0.16178E-08 -8.7911 0.95929E+00 -0.0181 48 HFeO2- 0.88913E-10 -10.0510 0.85289E-10 -10.0691 0.95925E+00 -0.0181 49 FeO+ 0.12249E-12 -12.9119 0.11750E-12 -12.9300 0.95929E+00 -0.0181 50 FeOH+2 0.38665E-18 -18.4127 0.34542E-18 -18.4616 0.89337E+00 -0.0490 51 FeO2- 0.10577E-09 -9.9756 0.10146E-09 -9.9937 0.95925E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.10786E-08 -8.9671 0.10785E-08 -8.9672 0.99991E+00 0.0000 54 KCl,aq 0.83992E-11 -11.0758 0.83992E-11 -11.0758 0.10000E+01 0.0000 55 KHSO4,aq 0.34438E-17 -17.4630 0.34438E-17 -17.4630 0.10000E+01 0.0000 56 KOH,aq 0.97147E-10 -10.0126 0.97147E-10 -10.0126 0.10000E+01 0.0000 57 KSO4- 0.12800E-08 -8.8928 0.12278E-08 -8.9109 0.95925E+00 -0.0181 58 MgCO3,aq 0.27582E-10 -10.5594 0.27582E-10 -10.5594 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.42053E-10 -10.3762 0.40341E-10 -10.3943 0.95929E+00 -0.0181 60 MgCl+ 0.25971E-10 -10.5855 0.24914E-10 -10.6036 0.95929E+00 -0.0181 61 MgOH+ 0.34277E-08 -8.4650 0.32882E-08 -8.4830 0.95929E+00 -0.0181 63 MnO,aq 0.30776E-09 -9.5118 0.30776E-09 -9.5118 0.10000E+01 0.0000 64 MnOH+ 0.14420E-07 -7.8410 0.13833E-07 -7.8591 0.95929E+00 -0.0181 65 MnO2-2 0.48237E-16 -16.3166 0.43100E-16 -16.3655 0.89351E+00 -0.0489 66 HMnO2- 0.15153E-12 -12.8195 0.14536E-12 -12.8376 0.95925E+00 -0.0181 69 MnCl+ 0.59825E-10 -10.2231 0.57389E-10 -10.2412 0.95929E+00 -0.0181 70 MnSO4,aq 0.45936E-09 -9.3378 0.45936E-09 -9.3378 0.10000E+01 0.0000 71 NaCl,aq 0.76408E-08 -8.1169 0.76408E-08 -8.1169 0.10000E+01 0.0000 72 NaOH,aq 0.48626E-08 -8.3131 0.48626E-08 -8.3131 0.10000E+01 0.0000 74 OH- 0.39129E-04 -4.4075 0.37533E-04 -4.4256 0.95921E+00 -0.0181 82 H3PO4,aq 0.19383E-14 -14.7126 0.19383E-14 -14.7126 0.10000E+01 0.0000 83 H2PO4- 0.34621E-09 -9.4607 0.33211E-09 -9.4787 0.95927E+00 -0.0181 84 PO4-3 0.78021E-13 -13.1078 0.61985E-13 -13.2077 0.79447E+00 -0.0999 88 HP2O7-3 0.14136E-18 -18.8497 0.11218E-18 -18.9501 0.79357E+00 -0.1004 90 H2S,aq 0.10622E-11 -11.9738 0.10621E-11 -11.9739 0.99991E+00 0.0000 96 SO2,aq 0.25790E-19 -19.5885 0.25790E-19 -19.5885 0.10000E+01 0.0000 97 SO3-2 0.35430E-14 -14.4506 0.31668E-14 -14.4994 0.89381E+00 -0.0488 98 HSO3- 0.31820E-14 -14.4973 0.30523E-14 -14.5154 0.95925E+00 -0.0181 99 HSO4- 0.34942E-09 -9.4567 0.33520E-09 -9.4747 0.95931E+00 -0.0180 101 S2O3-2 0.31549E-18 -18.5010 0.28189E-18 -18.5499 0.89351E+00 -0.0489 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1604565E-07 -.6108972E-04 -.6157303E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999702E+06 0.0000 3 Cl- 0.1379606E-03 0.1379751E-03 0.4891493E+01 3.9343 4 SO4-- 0.2528665E-04 0.2550438E-04 0.2449923E+01 10.9793 5 HCO3- 0.1256165E-04 0.1307009E-04 0.7974776E+00 2.8936 6 HS- 0.2327151E-10 0.2559263E-09 0.8463755E-05 -2.8386 7 Al+++ 0.3436830E-20 0.3056842E-05 0.8247586E-01 2.8737 8 H4SiO4 0.1559166E-03 0.1658092E-03 0.1593637E+02 -3.8071 9 Ca++ 0.3367687E-04 0.3408686E-04 0.1366095E+01 11.1037 10 Mg++ 0.1436806E-06 0.1472398E-06 0.3579594E-02 8.7337 11 Fe++ 0.8564415E-09 0.3062009E-08 0.1709992E-03 6.5090 12 K+ 0.3650443E-05 0.3651829E-05 0.1427898E+00 2.3569 13 Na+ 0.1816232E-03 0.1816624E-03 0.4176264E+01 4.0538 14 Mn++ 0.7882933E-07 0.9407682E-07 0.5168246E-02 8.4730 15 HPO4-- 0.1308823E-08 0.1655115E-08 0.1588518E-03 6.6933 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2717665E-03 -.6108931E-04 -.2106772E-03 0.0000000E+00 2 H2O 0.5550803E+02 0.5550792E+02 0.1187658E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2598114E-04 0.2550421E-04 0.4769266E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4766706E-06 0.2559246E-09 -.4769266E-06 0.0000000E+00 7 Al+++ 0.5608476E-04 0.3056822E-05 0.5302793E-04 0.0000000E+00 8 H4SiO4 0.1790999E-03 0.1658081E-03 0.1329179E-04 0.0000000E+00 9 Ca++ 0.3425351E-04 0.3408663E-04 0.1668787E-06 0.0000000E+00 10 Mg++ 0.1365079E-04 0.1472389E-06 0.1350355E-04 0.0000000E+00 11 Fe++ 0.1226375E-04 0.3061988E-08 0.1226069E-04 0.0000000E+00 12 K+ 0.3651805E-05 0.3651805E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1816612E-03 0.1816612E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2982239E-06 0.9407619E-07 0.2041477E-06 0.0000000E+00 15 HPO4-- 0.1017823E-06 0.1655104E-08 0.1001272E-06 0.0000000E+00 Chg. balance for solid moles: -.9423E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0172000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3338E-07 -7.477 0.1677E-04 -4.776 0.2938 0.5327E-05 clinochlore 0.2701E-05 -5.569 0.1501E-02 -2.824 26.31 0.5710E-03 daphnite 0.1689E-05 -5.772 0.1205E-02 -2.919 21.12 0.3652E-03 chlorite-Mn 0.4083E-07 -7.389 0.2895E-04 -4.538 0.5073 0.9225E-05 diaspore 0.4417E-04 -4.355 0.2650E-02 -2.577 46.43 0.7888E-03 hematite 0.1908E-05 -5.719 0.3047E-03 -3.516 5.339 0.5774E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3812E+00 0.3812E+00 1.0000 -0.419 chlorite-Mn 0.9215E-02 0.9215E-02 1.0000 -2.035 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005706 g Volume = 0.001797 cm3 Porosity: 99.8215% V(tot) - V(min): 0.10051E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0172000 g log = -1.7645 Original solution: 1000.0103000 g Original solution / Rock added: 58140.13 (Water/Rock Ratio), log = 4.7645 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4127E-04 1.0071 0.4241E-04 0.4211E-04 CH4,gas 0.1648E-13 1.0125 0.1702E-13 0.1681E-13 H2,gas 0.1387E-05 1.0005 0.1416E-05 0.1415E-05 H2S,gas 0.2873E-10 0.9960 0.2920E-10 0.2931E-10 S2,gas 0.1564E-28 1.0000 0.1596E-28 0.1596E-28 CO,gas 0.1568E-13 1.0000 0.1600E-13 0.1600E-13 SO3,gas 0.1984E-35 1.0000 0.2024E-35 0.2024E-35 SO2,gas 0.1093E-18 1.0000 0.1115E-18 0.1115E-18 HCl,gas 0.6456E-15 1.0000 0.6587E-15 0.6587E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.73 -6.07 -2.024 0.10367E+05 -4.373 3 CH4,gas 4.54 -10.92 -15.47 -3.867 0.26411E+05 -13.769 4 H2,gas 8.00 0.45 -7.55 -4.313 0.12888E+05 -5.849 5 H2S,gas -6.23 -18.46 -12.23 -6.117 0.20889E+05 -10.535 6 S2,gas -7.34 -37.83 -30.50 -4.692 0.52071E+05 -28.797 7 CO,gas 3.21 -12.28 -15.49 -4.768 0.26457E+05 -13.796 8 SO3,gas 17.12 -20.27 -37.39 -9.348 0.63847E+05 -35.694 9 SO2,gas 0.83 -19.82 -20.65 -5.507 0.35262E+05 -18.953 10 HCl,gas 5.19 -11.69 -16.88 -8.440 0.28823E+05 -15.181 11 acmite 7.71 2.72 -4.99 -0.518 0.85153E+04 16 albite -0.38 -4.49 -4.11 -0.316 0.70177E+04 19 spessartine 24.46 19.75 -4.71 -0.236 0.80460E+04 20 analcite 3.32 -0.69 -4.01 -0.445 0.68446E+04 21 andalusite 5.00 1.94 -3.06 -0.306 0.52270E+04 22 andradite 39.01 34.46 -4.55 -0.237 0.77738E+04 24 anhydrite -5.32 -9.17 -3.85 -1.925 0.65751E+04 29 anorthite 12.71 9.24 -3.47 -0.267 0.59308E+04 35 aragonite 0.97 -1.63 -2.59 -0.865 0.44300E+04 36 brucite 12.57 8.73 -3.83 -0.767 0.65479E+04 37 calcite 0.81 -1.63 -2.44 -0.813 0.41658E+04 40 carpholite-Mg 8.58 6.87 -1.72 -0.114 0.29287E+04 41 carpholite-Fe 6.71 4.64 -2.07 -0.138 0.35352E+04 50 chloritoid-Mg 13.20 10.67 -2.52 -0.168 0.43092E+04 51 chloritoid-Fe 9.17 8.45 -0.72 -0.048 0.12368E+04 52 chloritoid-Mn 11.40 10.41 -0.99 -0.066 0.16866E+04 54 coesite -2.38 -3.81 -1.43 -0.477 0.24435E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.81 -1.25 -0.416 0.21288E+04 67 diopside 16.18 12.22 -3.96 -0.396 0.67585E+04 68 hedenbergite 14.21 10.00 -4.21 -0.421 0.71881E+04 75 epidote 24.67 22.82 -1.85 -0.090 0.31646E+04 76 clinozoisite 22.81 19.41 -3.40 -0.154 0.58035E+04 77 epidote-Fe 29.84 26.23 -3.61 -0.188 0.61723E+04 78 fayalite 14.05 9.21 -4.83 -0.691 0.82553E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.352 0.72169E+04 91 heulandite -5.83 -9.80 -3.97 -0.181 0.67811E+04 95 jadeite 4.22 -0.69 -4.90 -0.490 0.83701E+04 98 kaolinite -1.33 -1.87 -0.53 -0.049 0.91188E+03 99 kyanite 4.88 1.94 -2.94 -0.294 0.50129E+04 101 laumontite 2.88 1.62 -1.26 -0.084 0.21527E+04 102 lawsonite 9.62 9.24 -0.38 -0.025 0.64749E+03 105 lizardite 23.24 18.59 -4.66 -0.388 0.79516E+04 106 magnesite 0.69 -4.00 -4.69 -1.563 0.80056E+04 107 magnetite 20.09 19.08 -1.01 -0.083 0.17283E+04 110 magnesioferrite 26.21 21.30 -4.91 -0.401 0.83880E+04 113 margarite 17.32 14.98 -2.34 -0.094 0.39944E+04 116 microcline -2.49 -6.19 -3.70 -0.285 0.63248E+04 120 muscovite 2.58 -0.44 -3.03 -0.178 0.51663E+04 121 paragonite 4.24 1.25 -2.99 -0.176 0.50984E+04 136 prehnite 19.37 16.53 -2.84 -0.167 0.48466E+04 137 prehnite-Fe 22.50 19.94 -2.56 -0.154 0.43626E+04 138 pumpellyite-Fe 46.27 42.45 -3.82 -0.085 0.65223E+04 139 pumpellyite-Mg 48.99 44.67 -4.32 -0.096 0.73773E+04 145 pyroxmangite 7.40 4.67 -2.73 -0.547 0.46661E+04 146 pyrophyllite -6.18 -9.48 -3.31 -0.207 0.56436E+04 147 quartz -2.99 -3.81 -0.82 -0.273 0.13962E+04 151 rhodochrosite -0.98 -4.26 -3.28 -1.094 0.56045E+04 152 rhodonite 7.45 4.67 -2.78 -0.556 0.47464E+04 153 sanidine -1.28 -6.19 -4.92 -0.378 0.83925E+04 155 siderite -2.61 -6.22 -3.61 -1.205 0.61717E+04 156 sillimanite 5.26 1.94 -3.32 -0.332 0.56709E+04 163 stilbite -7.52 -9.80 -2.28 -0.108 0.38873E+04 164 stilpnomelane-Fe 13.02 9.01 -4.00 -0.119 0.68348E+04 168 sudoite 21.08 17.54 -3.54 -0.114 0.60384E+04 174 tephroite 18.09 13.14 -4.95 -0.707 0.84467E+04 177 topaz-H 4.62 1.94 -2.68 -0.243 0.45730E+04 178 tridymite -2.63 -3.81 -1.18 -0.394 0.20161E+04 187 wairakite 3.95 1.62 -2.33 -0.137 0.39747E+04 188 walstromite 11.51 7.30 -4.21 -0.843 0.71930E+04 189 wollastonite 10.46 7.30 -3.16 -0.633 0.54034E+04 190 pseudo-wollastonite 11.00 7.30 -3.70 -0.741 0.63232E+04 191 zoisite 22.85 19.41 -3.44 -0.156 0.58776E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.44 -3.80 -0.235 0.64861E+04 194 beidellite-H -2.33 -7.28 -4.95 -0.316 0.84522E+04 195 beidellite-K -1.52 -6.50 -4.98 -0.305 0.85004E+04 196 beidellite-Mg -1.79 -5.84 -4.05 -0.250 0.69076E+04 197 beidellite-Na -1.34 -5.94 -4.60 -0.281 0.78482E+04 199 chalcedony -2.80 -3.81 -1.00 -0.335 0.17155E+04 201 montmorillonite-Ca -2.29 -5.72 -3.42 -0.212 0.58471E+04 202 montmorillonite-K -2.24 -6.77 -4.53 -0.278 0.77395E+04 203 montmorillonite-Mg -2.48 -6.11 -3.63 -0.224 0.61918E+04 204 montmorillonite-Na -2.04 -6.21 -4.17 -0.255 0.71231E+04 205 nontronite-Ca 3.21 1.37 -1.84 -0.119 0.31418E+04 206 nontronite-H 2.53 -0.46 -2.99 -0.200 0.51058E+04 207 nontronite-K 3.34 0.32 -3.02 -0.194 0.51574E+04 208 nontronite-Mg 3.07 0.98 -2.09 -0.136 0.35706E+04 209 nontronite-Na 3.52 0.88 -2.64 -0.169 0.45069E+04 214 gypsum -4.96 -9.17 -4.21 -1.053 0.71927E+04 224 tobermorite 9.82 5.44 -4.38 -1.195 0.74801E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.51 -3.30 -0.826 0.56390E+04 240 silica-amorphous -2.09 -3.81 -1.72 -0.572 0.29296E+04 242 an20ab80 2.02 -1.75 -3.77 -0.290 0.64295E+04 243 an25ab75 2.65 -1.06 -3.71 -0.285 0.63294E+04 244 an30ab70 3.28 -0.37 -3.65 -0.281 0.62389E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0172000 g New total amount of reactant added: 0.0176000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0176000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3031174E-03 Osmotic coef. = 0.9896 True ionic strength = .3144384E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15675E-07 -7.8048 0.15037E-07 -7.8228 0.95931E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13233E-03 -3.8783 0.95918E+00 -0.0181 4 SO4-- 0.25284E-04 -4.5972 0.22586E-04 -4.6462 0.89330E+00 -0.0490 5 HCO3- 0.12568E-04 -4.9007 0.12055E-04 -4.9188 0.95921E+00 -0.0181 6 HS- 0.20377E-10 -10.6909 0.19545E-10 -10.7090 0.95918E+00 -0.0181 7 Al+++ 0.32055E-20 -20.4941 0.25421E-20 -20.5948 0.79306E+00 -0.1007 8 H4SiO4 0.15931E-03 -3.7978 0.15931E-03 -3.7978 0.10000E+01 0.0000 9 Ca++ 0.34123E-04 -4.4670 0.30477E-04 -4.5160 0.89315E+00 -0.0491 10 Mg++ 0.13539E-06 -6.8684 0.12091E-06 -6.9175 0.89306E+00 -0.0491 11 Fe++ 0.80638E-09 -9.0935 0.72016E-09 -9.1426 0.89308E+00 -0.0491 12 K+ 0.37353E-05 -5.4277 0.35830E-05 -5.4458 0.95922E+00 -0.0181 13 Na+ 0.18212E-03 -3.7396 0.17469E-03 -3.7577 0.95918E+00 -0.0181 14 Mn++ 0.76053E-07 -7.1189 0.67922E-07 -7.1680 0.89310E+00 -0.0491 15 HPO4-- 0.12419E-08 -8.9059 0.11094E-08 -8.9549 0.89331E+00 -0.0490 16 HSiO3- 0.10313E-04 -4.9866 0.98922E-05 -5.0047 0.95918E+00 -0.0181 17 Ca(HSiO3)+ 0.71579E-08 -8.1452 0.68660E-08 -8.1633 0.95922E+00 -0.0181 18 Mg(HSiO3)+ 0.35341E-10 -10.4517 0.33900E-10 -10.4698 0.95922E+00 -0.0181 19 NaHSiO3,aq 0.27949E-07 -7.5536 0.27949E-07 -7.5536 0.10000E+01 0.0000 20 AlO+ 0.15945E-11 -11.7974 0.15295E-11 -11.8155 0.95922E+00 -0.0181 21 AlOH+2 0.12823E-15 -15.8920 0.11452E-15 -15.9411 0.89312E+00 -0.0491 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.31088E-05 -5.5074 0.29818E-05 -5.5255 0.95914E+00 -0.0181 24 CH4,aq 0.10134E-16 -16.9942 0.10133E-16 -16.9942 0.99991E+00 0.0000 29 CO,aq 0.10212E-16 -16.9909 0.10212E-16 -16.9909 0.10000E+01 0.0000 30 CO2,aq 0.38738E-06 -6.4119 0.38734E-06 -6.4119 0.99991E+00 0.0000 31 CO3-2 0.78391E-07 -7.1057 0.70024E-07 -7.1548 0.89326E+00 -0.0490 32 CaCO3,aq 0.26760E-07 -7.5725 0.26760E-07 -7.5725 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.97771E-08 -8.0098 0.93784E-08 -8.0279 0.95922E+00 -0.0181 34 CaCl+ 0.68041E-08 -8.1672 0.65267E-08 -8.1853 0.95922E+00 -0.0181 35 CaCl2,aq 0.20519E-12 -12.6878 0.20519E-12 -12.6878 0.10000E+01 0.0000 36 CaOH+ 0.15059E-06 -6.8222 0.14445E-06 -6.8403 0.95922E+00 -0.0181 37 CaSO4,aq 0.21859E-06 -6.6604 0.21859E-06 -6.6604 0.10000E+01 0.0000 38 HCl,aq 0.36463E-12 -12.4381 0.36463E-12 -12.4381 0.10000E+01 0.0000 43 FeCl+ 0.15725E-12 -12.8034 0.15084E-12 -12.8215 0.95922E+00 -0.0181 46 FeO,aq 0.12378E-09 -9.9073 0.12378E-09 -9.9073 0.10000E+01 0.0000 47 FeOH+ 0.16252E-08 -8.7891 0.15589E-08 -8.8072 0.95922E+00 -0.0181 48 HFeO2- 0.89795E-10 -10.0467 0.86130E-10 -10.0648 0.95918E+00 -0.0181 49 FeO+ 0.11966E-12 -12.9221 0.11478E-12 -12.9401 0.95922E+00 -0.0181 50 FeOH+2 0.36905E-18 -18.4329 0.32960E-18 -18.4820 0.89312E+00 -0.0491 51 FeO2- 0.10829E-09 -9.9654 0.10387E-09 -9.9835 0.95918E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.10496E-08 -8.9790 0.10495E-08 -8.9790 0.99991E+00 0.0000 54 KCl,aq 0.85933E-11 -11.0658 0.85933E-11 -11.0658 0.10000E+01 0.0000 55 KHSO4,aq 0.34407E-17 -17.4634 0.34407E-17 -17.4634 0.10000E+01 0.0000 56 KOH,aq 0.10176E-09 -9.9924 0.10176E-09 -9.9924 0.10000E+01 0.0000 57 KSO4- 0.13092E-08 -8.8830 0.12558E-08 -8.9011 0.95918E+00 -0.0181 58 MgCO3,aq 0.26611E-10 -10.5749 0.26611E-10 -10.5749 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.39635E-10 -10.4019 0.38019E-10 -10.4200 0.95922E+00 -0.0181 60 MgCl+ 0.24466E-10 -10.6114 0.23469E-10 -10.6295 0.95922E+00 -0.0181 61 MgOH+ 0.33059E-08 -8.4807 0.31711E-08 -8.4988 0.95922E+00 -0.0181 63 MnO,aq 0.31108E-09 -9.5071 0.31108E-09 -9.5071 0.10000E+01 0.0000 64 MnOH+ 0.14239E-07 -7.8465 0.13659E-07 -7.8646 0.95922E+00 -0.0181 65 MnO2-2 0.51112E-16 -16.2915 0.45657E-16 -16.3405 0.89326E+00 -0.0490 66 HMnO2- 0.15681E-12 -12.8046 0.15041E-12 -12.8227 0.95918E+00 -0.0181 69 MnCl+ 0.57701E-10 -10.2388 0.55348E-10 -10.2569 0.95922E+00 -0.0181 70 MnSO4,aq 0.44289E-09 -9.3537 0.44289E-09 -9.3537 0.10000E+01 0.0000 71 NaCl,aq 0.76608E-08 -8.1157 0.76608E-08 -8.1157 0.10000E+01 0.0000 72 NaOH,aq 0.49913E-08 -8.3018 0.49913E-08 -8.3018 0.10000E+01 0.0000 74 OH- 0.40060E-04 -4.3973 0.38423E-04 -4.4154 0.95914E+00 -0.0181 82 H3PO4,aq 0.17545E-14 -14.7558 0.17545E-14 -14.7558 0.10000E+01 0.0000 83 H2PO4- 0.32084E-09 -9.4937 0.30775E-09 -9.5118 0.95920E+00 -0.0181 84 PO4-3 0.75816E-13 -13.1202 0.60196E-13 -13.2204 0.79397E+00 -0.1002 88 HP2O7-3 0.12434E-18 -18.9054 0.98614E-19 -19.0061 0.79307E+00 -0.1007 90 H2S,aq 0.90844E-12 -12.0417 0.90836E-12 -12.0417 0.99991E+00 0.0000 96 SO2,aq 0.23938E-19 -19.6209 0.23938E-19 -19.6209 0.10000E+01 0.0000 97 SO3-2 0.34473E-14 -14.4625 0.30804E-14 -14.5114 0.89356E+00 -0.0489 98 HSO3- 0.30237E-14 -14.5195 0.29003E-14 -14.5376 0.95918E+00 -0.0181 99 HSO4- 0.34122E-09 -9.4670 0.32731E-09 -9.4850 0.95924E+00 -0.0181 101 S2O3-2 0.26980E-18 -18.5690 0.24100E-18 -18.6180 0.89326E+00 -0.0490 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1567502E-07 -.6278256E-04 -.6327924E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999698E+06 0.0000 3 Cl- 0.1379606E-03 0.1379751E-03 0.4891492E+01 3.9445 4 SO4-- 0.2528394E-04 0.2550440E-04 0.2449923E+01 10.9995 5 HCO3- 0.1256772E-04 0.1307009E-04 0.7974774E+00 2.9040 6 HS- 0.2037712E-10 0.2453110E-09 0.8112695E-05 -2.8861 7 Al+++ 0.3205481E-20 0.3129076E-05 0.8442475E-01 2.8737 8 H4SiO4 0.1593065E-03 0.1696549E-03 0.1630598E+02 -3.7978 9 Ca++ 0.3412315E-04 0.3454283E-04 0.1384368E+01 11.1296 10 Mg++ 0.1353932E-06 0.1388252E-06 0.3375021E-02 8.7281 11 Fe++ 0.8063807E-09 0.2952373E-08 0.1648764E-03 6.5031 12 K+ 0.3735336E-05 0.3736756E-05 0.1461104E+00 2.3771 13 Na+ 0.1821239E-03 0.1821645E-03 0.4187806E+01 4.0651 14 Mn++ 0.7605252E-07 0.9110372E-07 0.5004913E-02 8.4777 15 HPO4-- 0.1241947E-08 0.1562869E-08 0.1499983E-03 6.6908 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2783899E-03 -.6278213E-04 -.2156077E-03 0.0000000E+00 2 H2O 0.5550803E+02 0.5550791E+02 0.1215324E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2599223E-04 0.2550422E-04 0.4880013E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4877560E-06 0.2453094E-09 -.4880013E-06 0.0000000E+00 7 Al+++ 0.5738905E-04 0.3129055E-05 0.5426000E-04 0.0000000E+00 8 H4SiO4 0.1832650E-03 0.1696537E-03 0.1361128E-04 0.0000000E+00 9 Ca++ 0.3471357E-04 0.3454259E-04 0.1709775E-06 0.0000000E+00 10 Mg++ 0.1396825E-04 0.1388242E-06 0.1382943E-04 0.0000000E+00 11 Fe++ 0.1254895E-04 0.2952353E-08 0.1254600E-04 0.0000000E+00 12 K+ 0.3736730E-05 0.3736730E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1821633E-03 0.1821633E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3051593E-06 0.9110310E-07 0.2140562E-06 0.0000000E+00 15 HPO4-- 0.1041493E-06 0.1562858E-08 0.1025865E-06 0.0000000E+00 Chg. balance for solid moles: 0.3335E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0176000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3420E-07 -7.466 0.1718E-04 -4.765 0.2941 0.5458E-05 clinochlore 0.2766E-05 -5.558 0.1537E-02 -2.813 26.32 0.5848E-03 daphnite 0.1728E-05 -5.762 0.1233E-02 -2.909 21.11 0.3737E-03 chlorite-Mn 0.4281E-07 -7.368 0.3035E-04 -4.518 0.5197 0.9672E-05 diaspore 0.4519E-04 -4.345 0.2711E-02 -2.567 46.41 0.8070E-03 hematite 0.1952E-05 -5.710 0.3117E-03 -3.506 5.337 0.5909E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3809E+00 0.3809E+00 1.0000 -0.419 chlorite-Mn 0.9436E-02 0.9436E-02 1.0000 -2.025 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005841 g Volume = 0.001840 cm3 Porosity: 99.8173% V(tot) - V(min): 0.10052E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0176000 g log = -1.7545 Original solution: 1000.0103000 g Original solution / Rock added: 56818.77 (Water/Rock Ratio), log = 4.7545 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4033E-04 1.0071 0.4144E-04 0.4115E-04 CH4,gas 0.1444E-13 1.0125 0.1492E-13 0.1473E-13 H2,gas 0.1350E-05 1.0005 0.1378E-05 0.1377E-05 H2S,gas 0.2457E-10 0.9960 0.2497E-10 0.2507E-10 S2,gas 0.1208E-28 1.0000 0.1233E-28 0.1233E-28 CO,gas 0.1491E-13 1.0000 0.1522E-13 0.1522E-13 SO3,gas 0.1893E-35 1.0000 0.1931E-35 0.1931E-35 SO2,gas 0.1015E-18 1.0000 0.1035E-18 0.1035E-18 HCl,gas 0.6306E-15 1.0000 0.6434E-15 0.6434E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.74 -6.08 -2.027 0.10384E+05 -4.383 3 CH4,gas 4.54 -10.98 -15.53 -3.881 0.26509E+05 -13.826 4 H2,gas 8.00 0.44 -7.56 -4.320 0.12908E+05 -5.861 5 H2S,gas -6.23 -18.53 -12.30 -6.151 0.21005E+05 -10.603 6 S2,gas -7.34 -37.94 -30.61 -4.709 0.52263E+05 -28.909 7 CO,gas 3.21 -12.30 -15.52 -4.774 0.26494E+05 -13.818 8 SO3,gas 17.12 -20.29 -37.41 -9.353 0.63882E+05 -35.714 9 SO2,gas 0.83 -19.85 -20.68 -5.516 0.35317E+05 -18.985 10 HCl,gas 5.19 -11.70 -16.89 -8.445 0.28840E+05 -15.192 11 acmite 7.71 2.75 -4.96 -0.515 0.84640E+04 16 albite -0.38 -4.45 -4.07 -0.313 0.69505E+04 19 spessartine 24.46 19.79 -4.67 -0.234 0.79743E+04 20 analcite 3.32 -0.66 -3.98 -0.442 0.67934E+04 21 andalusite 5.00 1.95 -3.05 -0.305 0.52110E+04 22 andradite 39.01 34.56 -4.45 -0.231 0.75930E+04 23 grossular 32.73 27.74 -4.99 -0.249 0.85176E+04 24 anhydrite -5.32 -9.16 -3.85 -1.923 0.65659E+04 29 anorthite 12.71 9.28 -3.43 -0.264 0.58546E+04 35 aragonite 0.97 -1.61 -2.58 -0.860 0.44028E+04 36 brucite 12.57 8.73 -3.84 -0.768 0.65574E+04 37 calcite 0.81 -1.61 -2.42 -0.808 0.41386E+04 40 carpholite-Mg 8.58 6.88 -1.70 -0.113 0.29063E+04 41 carpholite-Fe 6.71 4.65 -2.06 -0.137 0.35134E+04 50 chloritoid-Mg 13.20 10.68 -2.52 -0.168 0.43027E+04 51 chloritoid-Fe 9.17 8.45 -0.72 -0.048 0.12309E+04 52 chloritoid-Mn 11.40 10.43 -0.97 -0.065 0.16627E+04 54 coesite -2.38 -3.80 -1.42 -0.474 0.24275E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.80 -1.24 -0.412 0.21129E+04 67 diopside 16.18 12.26 -3.92 -0.392 0.66918E+04 68 hedenbergite 14.21 10.04 -4.17 -0.417 0.71220E+04 75 epidote 24.67 22.90 -1.77 -0.086 0.30281E+04 76 clinozoisite 22.81 19.49 -3.32 -0.151 0.56670E+04 77 epidote-Fe 29.84 26.31 -3.53 -0.184 0.60358E+04 78 fayalite 14.05 9.21 -4.84 -0.691 0.82596E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.23 -0.352 0.72154E+04 91 heulandite -5.83 -9.71 -3.88 -0.176 0.66251E+04 95 jadeite 4.22 -0.66 -4.87 -0.487 0.83188E+04 98 kaolinite -1.33 -1.85 -0.52 -0.047 0.87998E+03 99 kyanite 4.88 1.95 -2.93 -0.293 0.49969E+04 101 laumontite 2.88 1.69 -1.20 -0.080 0.20446E+04 102 lawsonite 9.62 9.28 -0.33 -0.022 0.57127E+03 105 lizardite 23.24 18.59 -4.65 -0.388 0.79482E+04 106 magnesite 0.69 -4.01 -4.70 -1.568 0.80322E+04 107 magnetite 20.09 19.07 -1.02 -0.083 0.17384E+04 110 magnesioferrite 26.21 21.29 -4.92 -0.401 0.83975E+04 113 margarite 17.32 15.03 -2.29 -0.092 0.39182E+04 116 microcline -2.49 -6.14 -3.66 -0.281 0.62426E+04 120 muscovite 2.58 -0.40 -2.98 -0.175 0.50841E+04 121 paragonite 4.24 1.29 -2.95 -0.173 0.50311E+04 136 prehnite 19.37 16.61 -2.76 -0.162 0.47101E+04 137 prehnite-Fe 22.50 20.02 -2.48 -0.149 0.42262E+04 138 pumpellyite-Fe 46.27 42.60 -3.67 -0.081 0.62594E+04 139 pumpellyite-Mg 48.99 44.83 -4.17 -0.093 0.71138E+04 145 pyroxmangite 7.40 4.68 -2.72 -0.544 0.46422E+04 146 pyrophyllite -6.18 -9.44 -3.27 -0.204 0.55798E+04 147 quartz -2.99 -3.80 -0.81 -0.269 0.13802E+04 151 rhodochrosite -0.98 -4.26 -3.29 -1.096 0.56136E+04 152 rhodonite 7.45 4.68 -2.77 -0.553 0.47225E+04 153 sanidine -1.28 -6.14 -4.87 -0.374 0.83103E+04 155 siderite -2.61 -6.24 -3.63 -1.210 0.61988E+04 156 sillimanite 5.26 1.95 -3.31 -0.331 0.56550E+04 163 stilbite -7.52 -9.71 -2.19 -0.104 0.37313E+04 164 stilpnomelane-Fe 13.02 9.07 -3.95 -0.118 0.67406E+04 168 sudoite 21.08 17.56 -3.52 -0.114 0.60096E+04 174 tephroite 18.09 13.16 -4.93 -0.704 0.84148E+04 177 topaz-H 4.62 1.95 -2.67 -0.243 0.45570E+04 178 tridymite -2.63 -3.80 -1.17 -0.390 0.20002E+04 187 wairakite 3.95 1.69 -2.26 -0.133 0.38666E+04 188 walstromite 11.51 7.33 -4.18 -0.835 0.71327E+04 189 wollastonite 10.46 7.33 -3.13 -0.626 0.53432E+04 190 pseudo-wollastonite 11.00 7.33 -3.67 -0.734 0.62630E+04 191 zoisite 22.85 19.49 -3.36 -0.153 0.57411E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.41 -3.76 -0.233 0.64203E+04 194 beidellite-H -2.33 -7.24 -4.92 -0.314 0.83937E+04 195 beidellite-K -1.52 -6.46 -4.94 -0.302 0.84305E+04 196 beidellite-Mg -1.79 -5.80 -4.01 -0.248 0.68507E+04 197 beidellite-Na -1.34 -5.90 -4.56 -0.279 0.77833E+04 199 chalcedony -2.80 -3.80 -1.00 -0.332 0.16995E+04 201 montmorillonite-Ca -2.29 -5.68 -3.38 -0.209 0.57791E+04 202 montmorillonite-K -2.24 -6.73 -4.49 -0.275 0.76675E+04 203 montmorillonite-Mg -2.48 -6.07 -3.59 -0.222 0.61327E+04 204 montmorillonite-Na -2.04 -6.17 -4.13 -0.253 0.70560E+04 205 nontronite-Ca 3.21 1.41 -1.80 -0.117 0.30759E+04 206 nontronite-H 2.53 -0.42 -2.96 -0.198 0.50473E+04 207 nontronite-K 3.34 0.36 -2.98 -0.191 0.50875E+04 208 nontronite-Mg 3.07 1.02 -2.06 -0.133 0.35136E+04 209 nontronite-Na 3.52 0.92 -2.60 -0.167 0.44420E+04 214 gypsum -4.96 -9.16 -4.21 -1.052 0.71835E+04 224 tobermorite 9.82 5.47 -4.35 -1.187 0.74272E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.50 -3.31 -0.827 0.56492E+04 240 silica-amorphous -2.09 -3.80 -1.71 -0.569 0.29137E+04 242 an20ab80 2.02 -1.71 -3.73 -0.287 0.63605E+04 243 an25ab75 2.65 -1.02 -3.67 -0.282 0.62599E+04 244 an30ab70 3.28 -0.33 -3.61 -0.278 0.61690E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0176000 g New total amount of reactant added: 0.0180000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0180000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3046243E-03 Osmotic coef. = 0.9896 True ionic strength = .3163360E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15323E-07 -7.8146 0.14699E-07 -7.8327 0.95925E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13232E-03 -3.8784 0.95911E+00 -0.0181 4 SO4-- 0.25281E-04 -4.5972 0.22578E-04 -4.6463 0.89305E+00 -0.0491 5 HCO3- 0.12573E-04 -4.9005 0.12060E-04 -4.9187 0.95914E+00 -0.0181 6 HS- 0.17907E-10 -10.7470 0.17175E-10 -10.7651 0.95911E+00 -0.0181 7 Al+++ 0.29958E-20 -20.5235 0.23744E-20 -20.6245 0.79256E+00 -0.1010 8 H4SiO4 0.16269E-03 -3.7886 0.16269E-03 -3.7886 0.10000E+01 0.0000 9 Ca++ 0.34569E-04 -4.4613 0.30867E-04 -4.5105 0.89290E+00 -0.0492 10 Mg++ 0.12779E-06 -6.8935 0.11410E-06 -6.9427 0.89281E+00 -0.0492 11 Fe++ 0.76056E-09 -9.1189 0.67905E-09 -9.1681 0.89283E+00 -0.0492 12 K+ 0.38202E-05 -5.4179 0.36642E-05 -5.4360 0.95915E+00 -0.0181 13 Na+ 0.18262E-03 -3.7384 0.17516E-03 -3.7566 0.95911E+00 -0.0181 14 Mn++ 0.73358E-07 -7.1346 0.65497E-07 -7.1838 0.89285E+00 -0.0492 15 HPO4-- 0.11799E-08 -8.9282 0.10537E-08 -8.9773 0.89306E+00 -0.0491 16 HSiO3- 0.10775E-04 -4.9676 0.10335E-04 -4.9857 0.95911E+00 -0.0181 17 Ca(HSiO3)+ 0.75743E-08 -8.1207 0.72649E-08 -8.1388 0.95915E+00 -0.0181 18 Mg(HSiO3)+ 0.34843E-10 -10.4579 0.33420E-10 -10.4760 0.95915E+00 -0.0181 19 NaHSiO3,aq 0.29277E-07 -7.5335 0.29277E-07 -7.5335 0.10000E+01 0.0000 20 AlO+ 0.15587E-11 -11.8072 0.14951E-11 -11.8253 0.95915E+00 -0.0181 21 AlOH+2 0.12255E-15 -15.9117 0.10943E-15 -15.9609 0.89287E+00 -0.0492 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.31806E-05 -5.4975 0.30504E-05 -5.5156 0.95907E+00 -0.0181 24 CH4,aq 0.89122E-17 -17.0500 0.89113E-17 -17.0501 0.99991E+00 0.0000 29 CO,aq 0.97247E-17 -17.0121 0.97247E-17 -17.0121 0.10000E+01 0.0000 30 CO2,aq 0.37881E-06 -6.4216 0.37877E-06 -6.4216 0.99991E+00 0.0000 31 CO3-2 0.80248E-07 -7.0956 0.71663E-07 -7.1447 0.89301E+00 -0.0491 32 CaCO3,aq 0.27736E-07 -7.5570 0.27736E-07 -7.5570 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.99066E-08 -8.0041 0.95020E-08 -8.0222 0.95915E+00 -0.0181 34 CaCl+ 0.68912E-08 -8.1617 0.66097E-08 -8.1798 0.95915E+00 -0.0181 35 CaCl2,aq 0.20778E-12 -12.6824 0.20778E-12 -12.6824 0.10000E+01 0.0000 36 CaOH+ 0.15604E-06 -6.8068 0.14966E-06 -6.8249 0.95915E+00 -0.0181 37 CaSO4,aq 0.22130E-06 -6.6550 0.22130E-06 -6.6550 0.10000E+01 0.0000 38 HCl,aq 0.35640E-12 -12.4481 0.35640E-12 -12.4481 0.10000E+01 0.0000 43 FeCl+ 0.14828E-12 -12.8289 0.14222E-12 -12.8470 0.95915E+00 -0.0181 46 FeO,aq 0.12215E-09 -9.9131 0.12215E-09 -9.9131 0.10000E+01 0.0000 47 FeOH+ 0.15678E-08 -8.8047 0.15038E-08 -8.8228 0.95915E+00 -0.0181 48 HFeO2- 0.90658E-10 -10.0426 0.86951E-10 -10.0607 0.95911E+00 -0.0181 49 FeO+ 0.11697E-12 -12.9319 0.11220E-12 -12.9500 0.95915E+00 -0.0181 50 FeOH+2 0.35273E-18 -18.4526 0.31494E-18 -18.5018 0.89287E+00 -0.0492 51 FeO2- 0.11079E-09 -9.9555 0.10626E-09 -9.9736 0.95911E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.10221E-08 -8.9905 0.10220E-08 -8.9905 0.99991E+00 0.0000 54 KCl,aq 0.87874E-11 -11.0561 0.87874E-11 -11.0561 0.10000E+01 0.0000 55 KHSO4,aq 0.34381E-17 -17.4637 0.34381E-17 -17.4637 0.10000E+01 0.0000 56 KOH,aq 0.10646E-09 -9.9728 0.10646E-09 -9.9728 0.10000E+01 0.0000 57 KSO4- 0.13385E-08 -8.8734 0.12837E-08 -8.8915 0.95911E+00 -0.0181 58 MgCO3,aq 0.25698E-10 -10.5901 0.25698E-10 -10.5901 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.37417E-10 -10.4269 0.35889E-10 -10.4450 0.95915E+00 -0.0181 60 MgCl+ 0.23086E-10 -10.6366 0.22143E-10 -10.6548 0.95915E+00 -0.0181 61 MgOH+ 0.31915E-08 -8.4960 0.30612E-08 -8.5141 0.95915E+00 -0.0181 63 MnO,aq 0.31394E-09 -9.5032 0.31394E-09 -9.5032 0.10000E+01 0.0000 64 MnOH+ 0.14048E-07 -7.8524 0.13474E-07 -7.8705 0.95915E+00 -0.0181 65 MnO2-2 0.54000E-16 -16.2676 0.48222E-16 -16.3168 0.89301E+00 -0.0491 66 HMnO2- 0.16191E-12 -12.7907 0.15529E-12 -12.8089 0.95911E+00 -0.0181 69 MnCl+ 0.55641E-10 -10.2546 0.53368E-10 -10.2727 0.95915E+00 -0.0181 70 MnSO4,aq 0.42691E-09 -9.3697 0.42691E-09 -9.3697 0.10000E+01 0.0000 71 NaCl,aq 0.76808E-08 -8.1146 0.76808E-08 -8.1146 0.10000E+01 0.0000 72 NaOH,aq 0.51198E-08 -8.2907 0.51198E-08 -8.2907 0.10000E+01 0.0000 74 OH- 0.40985E-04 -4.3874 0.39307E-04 -4.4055 0.95907E+00 -0.0181 82 H3PO4,aq 0.15923E-14 -14.7980 0.15923E-14 -14.7980 0.10000E+01 0.0000 83 H2PO4- 0.29789E-09 -9.5259 0.28572E-09 -9.5441 0.95913E+00 -0.0181 84 PO4-3 0.73711E-13 -13.1325 0.58489E-13 -13.2329 0.79348E+00 -0.1005 88 HP2O7-3 0.10971E-18 -18.9597 0.86955E-19 -19.0607 0.79257E+00 -0.1010 90 H2S,aq 0.78031E-12 -12.1077 0.78024E-12 -12.1078 0.99991E+00 0.0000 96 SO2,aq 0.22265E-19 -19.6524 0.22265E-19 -19.6524 0.10000E+01 0.0000 97 SO3-2 0.33567E-14 -14.4741 0.29986E-14 -14.5231 0.89331E+00 -0.0490 98 HSO3- 0.28774E-14 -14.5410 0.27597E-14 -14.5591 0.95911E+00 -0.0181 99 HSO4- 0.33344E-09 -9.4770 0.31982E-09 -9.4951 0.95917E+00 -0.0181 101 S2O3-2 0.23172E-18 -18.6350 0.20693E-18 -18.6842 0.89301E+00 -0.0491 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1532338E-07 -.6447561E-04 -.6498566E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999694E+06 0.0000 3 Cl- 0.1379605E-03 0.1379751E-03 0.4891491E+01 3.9543 4 SO4-- 0.2528123E-04 0.2550441E-04 0.2449923E+01 11.0191 5 HCO3- 0.1257333E-04 0.1307009E-04 0.7974772E+00 2.9140 6 HS- 0.1790712E-10 0.2355294E-09 0.7789201E-05 -2.9324 7 Al+++ 0.2995817E-20 0.3200861E-05 0.8636152E-01 2.8737 8 H4SiO4 0.1626888E-03 0.1735010E-03 0.1667563E+02 -3.7886 9 Ca++ 0.3456936E-04 0.3499881E-04 0.1402641E+01 11.1549 10 Mg++ 0.1277935E-06 0.1311061E-06 0.3187358E-02 8.7227 11 Fe++ 0.7605582E-09 0.2850873E-08 0.1592081E-03 6.4973 12 K+ 0.3820229E-05 0.3821683E-05 0.1494311E+00 2.3967 13 Na+ 0.1826246E-03 0.1826667E-03 0.4199348E+01 4.0761 14 Mn++ 0.7335754E-07 0.8820219E-07 0.4845511E-02 8.4817 15 HPO4-- 0.1179897E-08 0.1477867E-08 0.1418401E-03 6.6882 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2850133E-03 -.6447516E-04 -.2205381E-03 0.0000000E+00 2 H2O 0.5550802E+02 0.5550790E+02 0.1242995E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2600331E-04 0.2550423E-04 0.4990769E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4988414E-06 0.2355277E-09 -.4990769E-06 0.0000000E+00 7 Al+++ 0.5869335E-04 0.3200838E-05 0.5549251E-04 0.0000000E+00 8 H4SiO4 0.1874301E-03 0.1734998E-03 0.1393031E-04 0.0000000E+00 9 Ca++ 0.3517363E-04 0.3499856E-04 0.1750642E-06 0.0000000E+00 10 Mg++ 0.1428571E-04 0.1311051E-06 0.1415461E-04 0.0000000E+00 11 Fe++ 0.1283415E-04 0.2850853E-08 0.1283130E-04 0.0000000E+00 12 K+ 0.3821656E-05 0.3821656E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1826654E-03 0.1826654E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3120947E-06 0.8820158E-07 0.2238932E-06 0.0000000E+00 15 HPO4-- 0.1065164E-06 0.1477857E-08 0.1050385E-06 0.0000000E+00 Chg. balance for solid moles: -.1498E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0180000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3501E-07 -7.456 0.1759E-04 -4.755 0.2944 0.5589E-05 clinochlore 0.2831E-05 -5.548 0.1574E-02 -2.803 26.34 0.5985E-03 daphnite 0.1768E-05 -5.753 0.1261E-02 -2.899 21.11 0.3822E-03 chlorite-Mn 0.4478E-07 -7.349 0.3175E-04 -4.498 0.5313 0.1012E-04 diaspore 0.4621E-04 -4.335 0.2772E-02 -2.557 46.39 0.8252E-03 hematite 0.1996E-05 -5.700 0.3188E-03 -3.496 5.336 0.6043E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3807E+00 0.3807E+00 1.0000 -0.419 chlorite-Mn 0.9643E-02 0.9643E-02 1.0000 -2.016 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005975 g Volume = 0.001882 cm3 Porosity: 99.8131% V(tot) - V(min): 0.10053E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0180000 g log = -1.7447 Original solution: 1000.0103000 g Original solution / Rock added: 55556.13 (Water/Rock Ratio), log = 4.7447 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3944E-04 1.0071 0.4052E-04 0.4024E-04 CH4,gas 0.1270E-13 1.0125 0.1312E-13 0.1295E-13 H2,gas 0.1314E-05 1.0005 0.1342E-05 0.1341E-05 H2S,gas 0.2110E-10 0.9960 0.2145E-10 0.2153E-10 S2,gas 0.9399E-29 1.0000 0.9591E-29 0.9591E-29 CO,gas 0.1420E-13 1.0000 0.1449E-13 0.1449E-13 SO3,gas 0.1808E-35 1.0000 0.1844E-35 0.1844E-35 SO2,gas 0.9436E-19 1.0000 0.9628E-19 0.9628E-19 HCl,gas 0.6163E-15 1.0000 0.6289E-15 0.6289E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.75 -6.09 -2.030 0.10401E+05 -4.392 3 CH4,gas 4.54 -11.04 -15.58 -3.895 0.26604E+05 -13.882 4 H2,gas 8.00 0.43 -7.57 -4.326 0.12928E+05 -5.872 5 H2S,gas -6.23 -18.60 -12.37 -6.184 0.21117E+05 -10.669 6 S2,gas -7.34 -38.05 -30.72 -4.726 0.52449E+05 -29.018 7 CO,gas 3.21 -12.32 -15.54 -4.781 0.26530E+05 -13.839 8 SO3,gas 17.12 -20.31 -37.43 -9.358 0.63916E+05 -35.734 9 SO2,gas 0.83 -19.88 -20.72 -5.524 0.35371E+05 -19.016 10 HCl,gas 5.19 -11.71 -16.90 -8.450 0.28857E+05 -15.201 11 acmite 7.71 2.78 -4.93 -0.512 0.84140E+04 16 albite -0.38 -4.42 -4.03 -0.310 0.68849E+04 19 spessartine 24.46 19.83 -4.63 -0.232 0.79071E+04 20 analcite 3.32 -0.63 -3.95 -0.439 0.67433E+04 21 andalusite 5.00 1.96 -3.04 -0.304 0.51955E+04 22 andradite 39.01 34.67 -4.34 -0.226 0.74168E+04 23 grossular 32.73 27.85 -4.89 -0.244 0.83413E+04 24 anhydrite -5.32 -9.16 -3.84 -1.920 0.65567E+04 29 anorthite 12.71 9.33 -3.39 -0.260 0.57803E+04 35 aragonite 0.97 -1.60 -2.56 -0.854 0.43762E+04 36 brucite 12.57 8.72 -3.85 -0.769 0.65667E+04 37 calcite 0.81 -1.60 -2.41 -0.803 0.41120E+04 40 carpholite-Mg 8.58 6.89 -1.69 -0.113 0.28844E+04 41 carpholite-Fe 6.71 4.67 -2.05 -0.136 0.34921E+04 50 chloritoid-Mg 13.20 10.68 -2.52 -0.168 0.42964E+04 51 chloritoid-Fe 9.17 8.46 -0.72 -0.048 0.12252E+04 52 chloritoid-Mn 11.40 10.44 -0.96 -0.064 0.16403E+04 54 coesite -2.38 -3.79 -1.41 -0.471 0.24119E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.79 -1.23 -0.409 0.20973E+04 67 diopside 16.18 12.30 -3.88 -0.388 0.66267E+04 68 hedenbergite 14.21 10.07 -4.13 -0.413 0.70575E+04 75 epidote 24.67 22.97 -1.70 -0.082 0.28950E+04 76 clinozoisite 22.81 19.57 -3.24 -0.147 0.55339E+04 77 epidote-Fe 29.84 26.38 -3.46 -0.180 0.59027E+04 78 fayalite 14.05 9.21 -4.84 -0.691 0.82637E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.91 -4.22 -0.352 0.72137E+04 91 heulandite -5.83 -9.62 -3.79 -0.172 0.64729E+04 95 jadeite 4.22 -0.63 -4.84 -0.484 0.82688E+04 98 kaolinite -1.33 -1.83 -0.50 -0.045 0.84882E+03 99 kyanite 4.88 1.96 -2.92 -0.292 0.49814E+04 101 laumontite 2.88 1.75 -1.14 -0.076 0.19391E+04 102 lawsonite 9.62 9.33 -0.29 -0.019 0.49694E+03 105 lizardite 23.24 18.59 -4.65 -0.388 0.79449E+04 106 magnesite 0.69 -4.03 -4.72 -1.573 0.80580E+04 107 magnetite 20.09 19.06 -1.02 -0.084 0.17482E+04 110 magnesioferrite 26.21 21.29 -4.92 -0.402 0.84068E+04 113 margarite 17.32 15.07 -2.25 -0.090 0.38438E+04 116 microcline -2.49 -6.10 -3.61 -0.278 0.61623E+04 120 muscovite 2.58 -0.35 -2.93 -0.172 0.50039E+04 121 paragonite 4.24 1.33 -2.91 -0.171 0.49655E+04 136 prehnite 19.37 16.69 -2.68 -0.158 0.45770E+04 137 prehnite-Fe 22.50 20.10 -2.40 -0.144 0.40931E+04 138 pumpellyite-Fe 46.27 42.75 -3.52 -0.078 0.60031E+04 139 pumpellyite-Mg 48.99 44.98 -4.02 -0.089 0.68569E+04 145 pyroxmangite 7.40 4.69 -2.71 -0.541 0.46199E+04 146 pyrophyllite -6.18 -9.41 -3.23 -0.202 0.55175E+04 147 quartz -2.99 -3.79 -0.80 -0.266 0.13646E+04 151 rhodochrosite -0.98 -4.27 -3.29 -1.098 0.56234E+04 152 rhodonite 7.45 4.69 -2.75 -0.551 0.47001E+04 153 sanidine -1.28 -6.10 -4.82 -0.371 0.82301E+04 155 siderite -2.61 -6.25 -3.65 -1.215 0.62253E+04 156 sillimanite 5.26 1.96 -3.30 -0.330 0.56394E+04 163 stilbite -7.52 -9.62 -2.10 -0.100 0.35791E+04 164 stilpnomelane-Fe 13.02 9.12 -3.89 -0.116 0.66484E+04 168 sudoite 21.08 17.57 -3.50 -0.113 0.59814E+04 174 tephroite 18.09 13.17 -4.91 -0.702 0.83856E+04 177 topaz-H 4.62 1.96 -2.66 -0.242 0.45414E+04 178 tridymite -2.63 -3.79 -1.16 -0.387 0.19846E+04 187 wairakite 3.95 1.75 -2.20 -0.130 0.37611E+04 188 walstromite 11.51 7.37 -4.14 -0.829 0.70740E+04 189 wollastonite 10.46 7.37 -3.09 -0.619 0.52844E+04 190 pseudo-wollastonite 11.00 7.37 -3.63 -0.727 0.62042E+04 191 zoisite 22.85 19.57 -3.28 -0.149 0.56080E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.37 -3.72 -0.230 0.63560E+04 194 beidellite-H -2.33 -7.21 -4.88 -0.312 0.83365E+04 195 beidellite-K -1.52 -6.42 -4.90 -0.300 0.83623E+04 196 beidellite-Mg -1.79 -5.77 -3.98 -0.246 0.67950E+04 197 beidellite-Na -1.34 -5.86 -4.52 -0.277 0.77199E+04 199 chalcedony -2.80 -3.79 -0.99 -0.329 0.16839E+04 201 montmorillonite-Ca -2.29 -5.64 -3.35 -0.207 0.57127E+04 202 montmorillonite-K -2.24 -6.69 -4.45 -0.272 0.75972E+04 203 montmorillonite-Mg -2.48 -6.04 -3.56 -0.220 0.60750E+04 204 montmorillonite-Na -2.04 -6.13 -4.09 -0.251 0.69905E+04 205 nontronite-Ca 3.21 1.45 -1.76 -0.114 0.30116E+04 206 nontronite-H 2.53 -0.39 -2.92 -0.196 0.49901E+04 207 nontronite-K 3.34 0.40 -2.94 -0.189 0.50193E+04 208 nontronite-Mg 3.07 1.05 -2.03 -0.131 0.34580E+04 209 nontronite-Na 3.52 0.96 -2.56 -0.165 0.43786E+04 214 gypsum -4.96 -9.16 -4.20 -1.050 0.71743E+04 224 tobermorite 9.82 5.50 -4.32 -1.179 0.73757E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.50 -3.31 -0.829 0.56590E+04 240 silica-amorphous -2.09 -3.79 -1.70 -0.566 0.28981E+04 242 an20ab80 2.02 -1.67 -3.69 -0.284 0.62931E+04 243 an25ab75 2.65 -0.98 -3.63 -0.279 0.61922E+04 244 an30ab70 3.28 -0.29 -3.57 -0.275 0.61008E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0180000 g New total amount of reactant added: 0.0184000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0184000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3061306E-03 Osmotic coef. = 0.9895 True ionic strength = .3182355E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14989E-07 -7.8242 0.14377E-07 -7.8423 0.95918E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13231E-03 -3.8784 0.95904E+00 -0.0182 4 SO4-- 0.25279E-04 -4.5972 0.22569E-04 -4.6465 0.89281E+00 -0.0492 5 HCO3- 0.12579E-04 -4.9004 0.12064E-04 -4.9185 0.95908E+00 -0.0181 6 HS- 0.15790E-10 -10.8016 0.15144E-10 -10.8198 0.95905E+00 -0.0182 7 Al+++ 0.28053E-20 -20.5520 0.22220E-20 -20.6533 0.79207E+00 -0.1012 8 H4SiO4 0.16606E-03 -3.7797 0.16606E-03 -3.7797 0.10000E+01 0.0000 9 Ca++ 0.35015E-04 -4.4557 0.31257E-04 -4.5051 0.89265E+00 -0.0493 10 Mg++ 0.12081E-06 -6.9179 0.10783E-06 -6.9673 0.89256E+00 -0.0494 11 Fe++ 0.71852E-09 -9.1436 0.64134E-09 -9.1929 0.89258E+00 -0.0494 12 K+ 0.39051E-05 -5.4084 0.37453E-05 -5.4265 0.95908E+00 -0.0181 13 Na+ 0.18313E-03 -3.7373 0.17562E-03 -3.7554 0.95904E+00 -0.0182 14 Mn++ 0.70749E-07 -7.1503 0.63150E-07 -7.1996 0.89260E+00 -0.0493 15 HPO4-- 0.11222E-08 -8.9499 0.10019E-08 -8.9992 0.89281E+00 -0.0492 16 HSiO3- 0.11246E-04 -4.9490 0.10785E-04 -4.9672 0.95904E+00 -0.0182 17 Ca(HSiO3)+ 0.80046E-08 -8.0967 0.76771E-08 -8.1148 0.95909E+00 -0.0181 18 Mg(HSiO3)+ 0.34366E-10 -10.4639 0.32960E-10 -10.4820 0.95909E+00 -0.0181 19 NaHSiO3,aq 0.30634E-07 -7.5138 0.30634E-07 -7.5138 0.10000E+01 0.0000 20 AlO+ 0.15247E-11 -11.8168 0.14624E-11 -11.8349 0.95909E+00 -0.0181 21 AlOH+2 0.11729E-15 -15.9308 0.10469E-15 -15.9801 0.89262E+00 -0.0493 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.32519E-05 -5.4879 0.31186E-05 -5.5060 0.95900E+00 -0.0182 24 CH4,aq 0.78638E-17 -17.1044 0.78631E-17 -17.1044 0.99991E+00 0.0000 29 CO,aq 0.92725E-17 -17.0328 0.92725E-17 -17.0328 0.10000E+01 0.0000 30 CO2,aq 0.37065E-06 -6.4310 0.37061E-06 -6.4311 0.99991E+00 0.0000 31 CO3-2 0.82093E-07 -7.0857 0.73290E-07 -7.1350 0.89276E+00 -0.0493 32 CaCO3,aq 0.28724E-07 -7.5418 0.28724E-07 -7.5418 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10036E-07 -7.9984 0.96252E-08 -8.0166 0.95909E+00 -0.0181 34 CaCl+ 0.69782E-08 -8.1563 0.66927E-08 -8.1744 0.95909E+00 -0.0181 35 CaCl2,aq 0.21038E-12 -12.6770 0.21038E-12 -12.6770 0.10000E+01 0.0000 36 CaOH+ 0.16155E-06 -6.7917 0.15494E-06 -6.8098 0.95909E+00 -0.0181 37 CaSO4,aq 0.22401E-06 -6.6497 0.22401E-06 -6.6497 0.10000E+01 0.0000 38 HCl,aq 0.34859E-12 -12.4577 0.34859E-12 -12.4577 0.10000E+01 0.0000 43 FeCl+ 0.14004E-12 -12.8537 0.13431E-12 -12.8719 0.95909E+00 -0.0181 46 FeO,aq 0.12058E-09 -9.9187 0.12058E-09 -9.9187 0.10000E+01 0.0000 47 FeOH+ 0.15139E-08 -8.8199 0.14520E-08 -8.8380 0.95909E+00 -0.0181 48 HFeO2- 0.91501E-10 -10.0386 0.87753E-10 -10.0567 0.95904E+00 -0.0182 49 FeO+ 0.11442E-12 -12.9415 0.10974E-12 -12.9596 0.95909E+00 -0.0181 50 FeOH+2 0.33756E-18 -18.4716 0.30132E-18 -18.5210 0.89262E+00 -0.0493 51 FeO2- 0.11327E-09 -9.9459 0.10863E-09 -9.9640 0.95904E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.99606E-09 -9.0017 0.99596E-09 -9.0018 0.99991E+00 0.0000 54 KCl,aq 0.89814E-11 -11.0467 0.89814E-11 -11.0467 0.10000E+01 0.0000 55 KHSO4,aq 0.34361E-17 -17.4639 0.34361E-17 -17.4639 0.10000E+01 0.0000 56 KOH,aq 0.11125E-09 -9.9537 0.11125E-09 -9.9537 0.10000E+01 0.0000 57 KSO4- 0.13677E-08 -8.8640 0.13117E-08 -8.8822 0.95904E+00 -0.0182 58 MgCO3,aq 0.24838E-10 -10.6049 0.24838E-10 -10.6049 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.35377E-10 -10.4513 0.33929E-10 -10.4694 0.95909E+00 -0.0181 60 MgCl+ 0.21819E-10 -10.6612 0.20926E-10 -10.6793 0.95909E+00 -0.0181 61 MgOH+ 0.30839E-08 -8.5109 0.29577E-08 -8.5290 0.95909E+00 -0.0181 63 MnO,aq 0.31638E-09 -9.4998 0.31638E-09 -9.4998 0.10000E+01 0.0000 64 MnOH+ 0.13848E-07 -7.8586 0.13282E-07 -7.8767 0.95909E+00 -0.0181 65 MnO2-2 0.56895E-16 -16.2449 0.50794E-16 -16.2942 0.89276E+00 -0.0493 66 HMnO2- 0.16683E-12 -12.7777 0.15999E-12 -12.7959 0.95904E+00 -0.0182 69 MnCl+ 0.53647E-10 -10.2705 0.51452E-10 -10.2886 0.95909E+00 -0.0181 70 MnSO4,aq 0.41145E-09 -9.3857 0.41145E-09 -9.3857 0.10000E+01 0.0000 71 NaCl,aq 0.77008E-08 -8.1135 0.77008E-08 -8.1135 0.10000E+01 0.0000 72 NaOH,aq 0.52483E-08 -8.2800 0.52483E-08 -8.2800 0.10000E+01 0.0000 74 OH- 0.41904E-04 -4.3777 0.40186E-04 -4.3959 0.95900E+00 -0.0182 82 H3PO4,aq 0.14485E-14 -14.8391 0.14485E-14 -14.8391 0.10000E+01 0.0000 83 H2PO4- 0.27708E-09 -9.5574 0.26574E-09 -9.5755 0.95906E+00 -0.0182 84 PO4-3 0.71701E-13 -13.1445 0.56858E-13 -13.2452 0.79299E+00 -0.1007 88 HP2O7-3 0.97087E-19 -19.0128 0.76900E-19 -19.1141 0.79208E+00 -0.1012 90 H2S,aq 0.67297E-12 -12.1720 0.67291E-12 -12.1720 0.99991E+00 0.0000 96 SO2,aq 0.20751E-19 -19.6830 0.20751E-19 -19.6830 0.10000E+01 0.0000 97 SO3-2 0.32707E-14 -14.4854 0.29210E-14 -14.5345 0.89307E+00 -0.0491 98 HSO3- 0.27418E-14 -14.5620 0.26295E-14 -14.5801 0.95904E+00 -0.0182 99 HSO4- 0.32604E-09 -9.4867 0.31271E-09 -9.5049 0.95911E+00 -0.0181 101 S2O3-2 0.19983E-18 -18.6993 0.17840E-18 -18.7486 0.89276E+00 -0.0493 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1498934E-07 -.6616873E-04 -.6669215E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999690E+06 0.0000 3 Cl- 0.1379604E-03 0.1379752E-03 0.4891489E+01 3.9639 4 SO4-- 0.2527852E-04 0.2550442E-04 0.2449924E+01 11.0381 5 HCO3- 0.1257853E-04 0.1307009E-04 0.7974770E+00 2.9238 6 HS- 0.1579024E-10 0.2264752E-09 0.7489766E-05 -2.9775 7 Al+++ 0.2805314E-20 0.3272193E-05 0.8828609E-01 2.8737 8 H4SiO4 0.1660634E-03 0.1773476E-03 0.1704533E+02 -3.7797 9 Ca++ 0.3501550E-04 0.3545480E-04 0.1420916E+01 11.1796 10 Mg++ 0.1208095E-06 0.1240098E-06 0.3014837E-02 8.7174 11 Fe++ 0.7185177E-09 0.2756713E-08 0.1539496E-03 6.4917 12 K+ 0.3905122E-05 0.3906610E-05 0.1527517E+00 2.4158 13 Na+ 0.1831252E-03 0.1831688E-03 0.4210890E+01 4.0869 14 Mn++ 0.7074890E-07 0.8537896E-07 0.4690411E-02 8.4850 15 HPO4-- 0.1122231E-08 0.1399387E-08 0.1343078E-03 6.6855 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2916367E-03 -.6616826E-04 -.2254684E-03 0.0000000E+00 2 H2O 0.5550802E+02 0.5550789E+02 0.1270673E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2601440E-04 0.2550424E-04 0.5101532E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5099267E-06 0.2264736E-09 -.5101532E-06 0.0000000E+00 7 Al+++ 0.5999765E-04 0.3272170E-05 0.5672548E-04 0.0000000E+00 8 H4SiO4 0.1915952E-03 0.1773463E-03 0.1424892E-04 0.0000000E+00 9 Ca++ 0.3563368E-04 0.3545454E-04 0.1791401E-06 0.0000000E+00 10 Mg++ 0.1460317E-04 0.1240089E-06 0.1447917E-04 0.0000000E+00 11 Fe++ 0.1311936E-04 0.2756694E-08 0.1311660E-04 0.0000000E+00 12 K+ 0.3906582E-05 0.3906582E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1831675E-03 0.1831675E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3190302E-06 0.8537836E-07 0.2336518E-06 0.0000000E+00 15 HPO4-- 0.1088834E-06 0.1399377E-08 0.1074840E-06 0.0000000E+00 Chg. balance for solid moles: 0.1747E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0184000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3583E-07 -7.446 0.1800E-04 -4.745 0.2946 0.5719E-05 clinochlore 0.2896E-05 -5.538 0.1610E-02 -2.793 26.35 0.6122E-03 daphnite 0.1807E-05 -5.743 0.1289E-02 -2.890 21.11 0.3907E-03 chlorite-Mn 0.4673E-07 -7.330 0.3313E-04 -4.480 0.5423 0.1056E-04 diaspore 0.4723E-04 -4.326 0.2833E-02 -2.548 46.38 0.8434E-03 hematite 0.2041E-05 -5.690 0.3259E-03 -3.487 5.334 0.6177E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3805E+00 0.3805E+00 1.0000 -0.420 chlorite-Mn 0.9839E-02 0.9839E-02 1.0000 -2.007 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006109 g Volume = 0.001924 cm3 Porosity: 99.8090% V(tot) - V(min): 0.10054E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0184000 g log = -1.7352 Original solution: 1000.0103000 g Original solution / Rock added: 54348.39 (Water/Rock Ratio), log = 4.7352 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3859E-04 1.0071 0.3965E-04 0.3937E-04 CH4,gas 0.1120E-13 1.0125 0.1157E-13 0.1143E-13 H2,gas 0.1281E-05 1.0005 0.1308E-05 0.1307E-05 H2S,gas 0.1820E-10 0.9960 0.1850E-10 0.1857E-10 S2,gas 0.7362E-29 1.0000 0.7512E-29 0.7512E-29 CO,gas 0.1354E-13 1.0000 0.1382E-13 0.1382E-13 SO3,gas 0.1729E-35 1.0000 0.1764E-35 0.1764E-35 SO2,gas 0.8795E-19 1.0000 0.8973E-19 0.8973E-19 HCl,gas 0.6028E-15 1.0000 0.6151E-15 0.6151E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.76 -6.10 -2.034 0.10417E+05 -4.402 3 CH4,gas 4.54 -11.09 -15.64 -3.909 0.26697E+05 -13.937 4 H2,gas 8.00 0.42 -7.58 -4.333 0.12947E+05 -5.884 5 H2S,gas -6.23 -18.66 -12.43 -6.216 0.21227E+05 -10.733 6 S2,gas -7.34 -38.16 -30.82 -4.742 0.52630E+05 -29.124 7 CO,gas 3.21 -12.34 -15.56 -4.787 0.26566E+05 -13.860 8 SO3,gas 17.12 -20.33 -37.45 -9.363 0.63949E+05 -35.754 9 SO2,gas 0.83 -19.91 -20.75 -5.532 0.35423E+05 -19.047 10 HCl,gas 5.19 -11.72 -16.91 -8.455 0.28873E+05 -15.211 11 acmite 7.71 2.81 -4.90 -0.509 0.83652E+04 16 albite -0.38 -4.38 -3.99 -0.307 0.68209E+04 19 spessartine 24.46 19.86 -4.59 -0.230 0.78443E+04 20 analcite 3.32 -0.60 -3.92 -0.436 0.66945E+04 21 andalusite 5.00 1.97 -3.03 -0.303 0.51802E+04 22 andradite 39.01 34.77 -4.24 -0.220 0.72448E+04 23 grossular 32.73 27.95 -4.78 -0.239 0.81694E+04 24 anhydrite -5.32 -9.15 -3.83 -1.917 0.65477E+04 29 anorthite 12.71 9.37 -3.34 -0.257 0.57077E+04 35 aragonite 0.97 -1.58 -2.55 -0.849 0.43503E+04 36 brucite 12.57 8.72 -3.85 -0.770 0.65758E+04 37 calcite 0.81 -1.58 -2.39 -0.798 0.40860E+04 40 carpholite-Mg 8.58 6.91 -1.68 -0.112 0.28630E+04 41 carpholite-Fe 6.71 4.68 -2.03 -0.136 0.34713E+04 50 chloritoid-Mg 13.20 10.69 -2.51 -0.168 0.42903E+04 51 chloritoid-Fe 9.17 8.46 -0.71 -0.048 0.12195E+04 52 chloritoid-Mn 11.40 10.45 -0.95 -0.063 0.16194E+04 54 coesite -2.38 -3.78 -1.40 -0.468 0.23967E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.78 -1.22 -0.406 0.20821E+04 67 diopside 16.18 12.34 -3.84 -0.384 0.65633E+04 68 hedenbergite 14.21 10.11 -4.10 -0.410 0.69945E+04 75 epidote 24.67 23.05 -1.62 -0.079 0.27652E+04 76 clinozoisite 22.81 19.64 -3.16 -0.144 0.54041E+04 77 epidote-Fe 29.84 26.46 -3.38 -0.176 0.57729E+04 78 fayalite 14.05 9.20 -4.84 -0.692 0.82676E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.92 -4.22 -0.352 0.72120E+04 91 heulandite -5.83 -9.53 -3.70 -0.168 0.63242E+04 95 jadeite 4.22 -0.60 -4.81 -0.481 0.82200E+04 98 kaolinite -1.33 -1.81 -0.48 -0.044 0.81837E+03 99 kyanite 4.88 1.97 -2.91 -0.291 0.49661E+04 101 laumontite 2.88 1.81 -1.08 -0.072 0.18361E+04 102 lawsonite 9.62 9.37 -0.25 -0.017 0.42440E+03 105 lizardite 23.24 18.59 -4.65 -0.388 0.79418E+04 106 magnesite 0.69 -4.04 -4.73 -1.578 0.80833E+04 107 magnetite 20.09 19.06 -1.03 -0.084 0.17578E+04 110 magnesioferrite 26.21 21.28 -4.93 -0.402 0.84159E+04 113 margarite 17.32 15.11 -2.21 -0.088 0.37713E+04 116 microcline -2.49 -6.05 -3.56 -0.274 0.60840E+04 120 muscovite 2.58 -0.30 -2.88 -0.170 0.49256E+04 121 paragonite 4.24 1.37 -2.87 -0.169 0.49015E+04 136 prehnite 19.37 16.77 -2.60 -0.153 0.44471E+04 137 prehnite-Fe 22.50 20.18 -2.32 -0.140 0.39632E+04 138 pumpellyite-Fe 46.27 42.90 -3.37 -0.075 0.57529E+04 139 pumpellyite-Mg 48.99 45.13 -3.87 -0.086 0.66063E+04 145 pyroxmangite 7.40 4.71 -2.69 -0.539 0.45989E+04 146 pyrophyllite -6.18 -9.37 -3.20 -0.200 0.54566E+04 147 quartz -2.99 -3.78 -0.79 -0.263 0.13494E+04 151 rhodochrosite -0.98 -4.28 -3.30 -1.100 0.56338E+04 152 rhodonite 7.45 4.71 -2.74 -0.548 0.46791E+04 153 sanidine -1.28 -6.05 -4.77 -0.367 0.81518E+04 155 siderite -2.61 -6.27 -3.66 -1.220 0.62510E+04 156 sillimanite 5.26 1.97 -3.29 -0.329 0.56242E+04 163 stilbite -7.52 -9.53 -2.01 -0.096 0.34304E+04 164 stilpnomelane-Fe 13.02 9.18 -3.84 -0.115 0.65582E+04 168 sudoite 21.08 17.59 -3.49 -0.112 0.59540E+04 174 tephroite 18.09 13.19 -4.90 -0.699 0.83589E+04 177 topaz-H 4.62 1.97 -2.65 -0.241 0.45262E+04 178 tridymite -2.63 -3.78 -1.15 -0.384 0.19694E+04 187 wairakite 3.95 1.81 -2.14 -0.126 0.36581E+04 188 walstromite 11.51 7.40 -4.11 -0.822 0.70166E+04 189 wollastonite 10.46 7.40 -3.06 -0.612 0.52271E+04 190 pseudo-wollastonite 11.00 7.40 -3.60 -0.720 0.61469E+04 191 zoisite 22.85 19.64 -3.21 -0.146 0.54781E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.33 -3.69 -0.228 0.62931E+04 194 beidellite-H -2.33 -7.18 -4.85 -0.309 0.82806E+04 195 beidellite-K -1.52 -6.38 -4.86 -0.298 0.82956E+04 196 beidellite-Mg -1.79 -5.74 -3.95 -0.244 0.67406E+04 197 beidellite-Na -1.34 -5.83 -4.48 -0.275 0.76580E+04 199 chalcedony -2.80 -3.78 -0.98 -0.326 0.16687E+04 201 montmorillonite-Ca -2.29 -5.60 -3.31 -0.205 0.56479E+04 202 montmorillonite-K -2.24 -6.65 -4.41 -0.270 0.75285E+04 203 montmorillonite-Mg -2.48 -6.00 -3.52 -0.218 0.60186E+04 204 montmorillonite-Na -2.04 -6.09 -4.06 -0.248 0.69266E+04 205 nontronite-Ca 3.21 1.49 -1.73 -0.112 0.29488E+04 206 nontronite-H 2.53 -0.36 -2.89 -0.194 0.49342E+04 207 nontronite-K 3.34 0.44 -2.90 -0.186 0.49527E+04 208 nontronite-Mg 3.07 1.08 -1.99 -0.129 0.34036E+04 209 nontronite-Na 3.52 0.99 -2.53 -0.162 0.43167E+04 214 gypsum -4.96 -9.15 -4.20 -1.049 0.71653E+04 224 tobermorite 9.82 5.53 -4.29 -1.171 0.73254E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.49 -3.32 -0.830 0.56686E+04 240 silica-amorphous -2.09 -3.78 -1.69 -0.563 0.28829E+04 242 an20ab80 2.02 -1.63 -3.65 -0.281 0.62274E+04 243 an25ab75 2.65 -0.94 -3.59 -0.276 0.61260E+04 244 an30ab70 3.28 -0.25 -3.53 -0.272 0.60342E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0184000 g New total amount of reactant added: 0.0188000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0188000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3076363E-03 Osmotic coef. = 0.9895 True ionic strength = .3201369E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14672E-07 -7.8335 0.14072E-07 -7.8517 0.95911E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13230E-03 -3.8784 0.95898E+00 -0.0182 4 SO4-- 0.25276E-04 -4.5973 0.22560E-04 -4.6467 0.89256E+00 -0.0494 5 HCO3- 0.12583E-04 -4.9002 0.12068E-04 -4.9184 0.95901E+00 -0.0182 6 HS- 0.13969E-10 -10.8548 0.13396E-10 -10.8730 0.95898E+00 -0.0182 7 Al+++ 0.26318E-20 -20.5797 0.20833E-20 -20.6813 0.79157E+00 -0.1015 8 H4SiO4 0.16943E-03 -3.7710 0.16943E-03 -3.7710 0.10000E+01 0.0000 9 Ca++ 0.35462E-04 -4.4502 0.31646E-04 -4.4997 0.89241E+00 -0.0494 10 Mg++ 0.11438E-06 -6.9417 0.10206E-06 -6.9911 0.89231E+00 -0.0495 11 Fe++ 0.67986E-09 -9.1676 0.60666E-09 -9.2171 0.89233E+00 -0.0495 12 K+ 0.39900E-05 -5.3990 0.38265E-05 -5.4172 0.95902E+00 -0.0182 13 Na+ 0.18363E-03 -3.7361 0.17609E-03 -3.7543 0.95897E+00 -0.0182 14 Mn++ 0.68229E-07 -7.1660 0.60885E-07 -7.2155 0.89235E+00 -0.0495 15 HPO4-- 0.10686E-08 -8.9712 0.95375E-09 -9.0206 0.89256E+00 -0.0494 16 HSiO3- 0.11724E-04 -4.9309 0.11243E-04 -4.9491 0.95898E+00 -0.0182 17 Ca(HSiO3)+ 0.84488E-08 -8.0732 0.81026E-08 -8.0914 0.95902E+00 -0.0182 18 Mg(HSiO3)+ 0.33911E-10 -10.4697 0.32521E-10 -10.4878 0.95902E+00 -0.0182 19 NaHSiO3,aq 0.32020E-07 -7.4946 0.32020E-07 -7.4946 0.10000E+01 0.0000 20 AlO+ 0.14924E-11 -11.8261 0.14313E-11 -11.8443 0.95902E+00 -0.0182 21 AlOH+2 0.11238E-15 -15.9493 0.10029E-15 -15.9988 0.89237E+00 -0.0495 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.33228E-05 -5.4785 0.31864E-05 -5.4967 0.95894E+00 -0.0182 24 CH4,aq 0.69610E-17 -17.1573 0.69603E-17 -17.1574 0.99990E+00 0.0000 29 CO,aq 0.88524E-17 -17.0529 0.88524E-17 -17.0529 0.10000E+01 0.0000 30 CO2,aq 0.36288E-06 -6.4402 0.36285E-06 -6.4403 0.99990E+00 0.0000 31 CO3-2 0.83926E-07 -7.0761 0.74905E-07 -7.1255 0.89251E+00 -0.0494 32 CaCO3,aq 0.29723E-07 -7.5269 0.29723E-07 -7.5269 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10165E-07 -7.9929 0.97482E-08 -8.0111 0.95902E+00 -0.0182 34 CaCl+ 0.70651E-08 -8.1509 0.67756E-08 -8.1691 0.95902E+00 -0.0182 35 CaCl2,aq 0.21297E-12 -12.6717 0.21297E-12 -12.6717 0.10000E+01 0.0000 36 CaOH+ 0.16713E-06 -6.7770 0.16028E-06 -6.7951 0.95902E+00 -0.0182 37 CaSO4,aq 0.22671E-06 -6.6445 0.22671E-06 -6.6445 0.10000E+01 0.0000 38 HCl,aq 0.34115E-12 -12.4671 0.34115E-12 -12.4671 0.10000E+01 0.0000 43 FeCl+ 0.13247E-12 -12.8779 0.12704E-12 -12.8961 0.95902E+00 -0.0182 46 FeO,aq 0.11907E-09 -9.9242 0.11907E-09 -9.9242 0.10000E+01 0.0000 47 FeOH+ 0.14633E-08 -8.8347 0.14033E-08 -8.8528 0.95902E+00 -0.0182 48 HFeO2- 0.92325E-10 -10.0347 0.88537E-10 -10.0529 0.95898E+00 -0.0182 49 FeO+ 0.11200E-12 -12.9508 0.10741E-12 -12.9690 0.95902E+00 -0.0182 50 FeOH+2 0.32345E-18 -18.4902 0.28864E-18 -18.5396 0.89237E+00 -0.0495 51 FeO2- 0.11574E-09 -9.9365 0.11099E-09 -9.9547 0.95898E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.97128E-09 -9.0127 0.97118E-09 -9.0127 0.99990E+00 0.0000 54 KCl,aq 0.91753E-11 -11.0374 0.91753E-11 -11.0374 0.10000E+01 0.0000 55 KHSO4,aq 0.34346E-17 -17.4641 0.34346E-17 -17.4641 0.10000E+01 0.0000 56 KOH,aq 0.11613E-09 -9.9351 0.11613E-09 -9.9351 0.10000E+01 0.0000 57 KSO4- 0.13969E-08 -8.8548 0.13396E-08 -8.8730 0.95898E+00 -0.0182 58 MgCO3,aq 0.24028E-10 -10.6193 0.24028E-10 -10.6193 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.33497E-10 -10.4750 0.32124E-10 -10.4932 0.95902E+00 -0.0182 60 MgCl+ 0.20651E-10 -10.6851 0.19805E-10 -10.7032 0.95902E+00 -0.0182 61 MgOH+ 0.29825E-08 -8.5254 0.28603E-08 -8.5436 0.95902E+00 -0.0182 63 MnO,aq 0.31842E-09 -9.4970 0.31842E-09 -9.4970 0.10000E+01 0.0000 64 MnOH+ 0.13643E-07 -7.8651 0.13083E-07 -7.8833 0.95902E+00 -0.0182 65 MnO2-2 0.59794E-16 -16.2233 0.53367E-16 -16.2727 0.89251E+00 -0.0494 66 HMnO2- 0.17156E-12 -12.7656 0.16453E-12 -12.7838 0.95898E+00 -0.0182 69 MnCl+ 0.51722E-10 -10.2863 0.49603E-10 -10.3045 0.95902E+00 -0.0182 70 MnSO4,aq 0.39654E-09 -9.4017 0.39654E-09 -9.4017 0.10000E+01 0.0000 71 NaCl,aq 0.77207E-08 -8.1123 0.77207E-08 -8.1123 0.10000E+01 0.0000 72 NaOH,aq 0.53766E-08 -8.2695 0.53766E-08 -8.2695 0.10000E+01 0.0000 74 OH- 0.42817E-04 -4.3684 0.41059E-04 -4.3866 0.95894E+00 -0.0182 82 H3PO4,aq 0.13209E-14 -14.8791 0.13209E-14 -14.8791 0.10000E+01 0.0000 83 H2PO4- 0.25817E-09 -9.5881 0.24758E-09 -9.6063 0.95900E+00 -0.0182 84 PO4-3 0.69778E-13 -13.1563 0.55299E-13 -13.2573 0.79250E+00 -0.1010 88 HP2O7-3 0.86156E-19 -19.0647 0.68200E-19 -19.1662 0.79158E+00 -0.1015 90 H2S,aq 0.58264E-12 -12.2346 0.58258E-12 -12.2346 0.99990E+00 0.0000 96 SO2,aq 0.19376E-19 -19.7127 0.19376E-19 -19.7127 0.10000E+01 0.0000 97 SO3-2 0.31890E-14 -14.4963 0.28472E-14 -14.5456 0.89282E+00 -0.0492 98 HSO3- 0.26159E-14 -14.5824 0.25086E-14 -14.6006 0.95898E+00 -0.0182 99 HSO4- 0.31901E-09 -9.4962 0.30594E-09 -9.5144 0.95904E+00 -0.0182 101 S2O3-2 0.17298E-18 -18.7620 0.15439E-18 -18.8114 0.89251E+00 -0.0494 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1467164E-07 -.6786180E-04 -.6839858E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999686E+06 0.0000 3 Cl- 0.1379603E-03 0.1379752E-03 0.4891488E+01 3.9732 4 SO4-- 0.2527582E-04 0.2550444E-04 0.2449924E+01 11.0566 5 HCO3- 0.1258334E-04 0.1307009E-04 0.7974768E+00 2.9333 6 HS- 0.1396864E-10 0.2180600E-09 0.7211465E-05 -3.0214 7 Al+++ 0.2631793E-20 0.3343073E-05 0.9019842E-01 2.8737 8 H4SiO4 0.1694304E-03 0.1811945E-03 0.1741506E+02 -3.7710 9 Ca++ 0.3546156E-04 0.3591080E-04 0.1439190E+01 11.2036 10 Mg++ 0.1143781E-06 0.1174728E-06 0.2855912E-02 8.7122 11 Fe++ 0.6798613E-09 0.2669194E-08 0.1490620E-03 6.4862 12 K+ 0.3990014E-05 0.3991536E-05 0.1560724E+00 2.4345 13 Na+ 0.1836258E-03 0.1836709E-03 0.4222432E+01 4.0974 14 Mn++ 0.6822950E-07 0.8263891E-07 0.4539881E-02 8.4878 15 HPO4-- 0.1068554E-08 0.1326791E-08 0.1273403E-03 6.6827 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2982601E-03 -.6786131E-04 -.2303988E-03 0.0000000E+00 2 H2O 0.5550801E+02 0.5550788E+02 0.1298357E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2602548E-04 0.2550425E-04 0.5212301E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5210121E-06 0.2180584E-09 -.5212301E-06 0.0000000E+00 7 Al+++ 0.6130194E-04 0.3343048E-05 0.5795889E-04 0.0000000E+00 8 H4SiO4 0.1957603E-03 0.1811932E-03 0.1456712E-04 0.0000000E+00 9 Ca++ 0.3609374E-04 0.3591054E-04 0.1832061E-06 0.0000000E+00 10 Mg++ 0.1492063E-04 0.1174719E-06 0.1480316E-04 0.0000000E+00 11 Fe++ 0.1340456E-04 0.2669175E-08 0.1340189E-04 0.0000000E+00 12 K+ 0.3991507E-05 0.3991507E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1836696E-03 0.1836696E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3259656E-06 0.8263831E-07 0.2433273E-06 0.0000000E+00 15 HPO4-- 0.1112504E-06 0.1326781E-08 0.1099237E-06 0.0000000E+00 Chg. balance for solid moles: -.3640E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0188000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3664E-07 -7.436 0.1841E-04 -4.735 0.2948 0.5849E-05 clinochlore 0.2961E-05 -5.529 0.1646E-02 -2.784 26.36 0.6259E-03 daphnite 0.1846E-05 -5.734 0.1317E-02 -2.880 21.10 0.3992E-03 chlorite-Mn 0.4867E-07 -7.313 0.3450E-04 -4.462 0.5526 0.1100E-04 diaspore 0.4825E-04 -4.317 0.2894E-02 -2.538 46.36 0.8617E-03 hematite 0.2085E-05 -5.681 0.3330E-03 -3.478 5.333 0.6311E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3803E+00 0.3803E+00 1.0000 -0.420 chlorite-Mn 0.1002E-01 0.1002E-01 1.0000 -1.999 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006243 g Volume = 0.001967 cm3 Porosity: 99.8048% V(tot) - V(min): 0.10056E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0188000 g log = -1.7258 Original solution: 1000.0103000 g Original solution / Rock added: 53192.04 (Water/Rock Ratio), log = 4.7258 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3778E-04 1.0071 0.3882E-04 0.3855E-04 CH4,gas 0.9917E-14 1.0125 0.1025E-13 0.1012E-13 H2,gas 0.1249E-05 1.0005 0.1275E-05 0.1274E-05 H2S,gas 0.1576E-10 0.9960 0.1601E-10 0.1608E-10 S2,gas 0.5804E-29 1.0000 0.5922E-29 0.5922E-29 CO,gas 0.1293E-13 1.0000 0.1319E-13 0.1319E-13 SO3,gas 0.1655E-35 1.0000 0.1689E-35 0.1689E-35 SO2,gas 0.8212E-19 1.0000 0.8379E-19 0.8379E-19 HCl,gas 0.5900E-15 1.0000 0.6020E-15 0.6020E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.77 -6.11 -2.037 0.10432E+05 -4.411 3 CH4,gas 4.54 -11.14 -15.69 -3.922 0.26788E+05 -13.989 4 H2,gas 8.00 0.41 -7.59 -4.339 0.12966E+05 -5.894 5 H2S,gas -6.23 -18.72 -12.49 -6.247 0.21334E+05 -10.795 6 S2,gas -7.34 -38.26 -30.93 -4.758 0.52806E+05 -29.228 7 CO,gas 3.21 -12.36 -15.58 -4.793 0.26600E+05 -13.880 8 SO3,gas 17.12 -20.35 -37.47 -9.368 0.63981E+05 -35.772 9 SO2,gas 0.83 -19.94 -20.78 -5.540 0.35474E+05 -19.077 10 HCl,gas 5.19 -11.73 -16.92 -8.460 0.28889E+05 -15.220 11 acmite 7.71 2.84 -4.87 -0.506 0.83175E+04 16 albite -0.38 -4.34 -3.96 -0.304 0.67583E+04 19 spessartine 24.46 19.90 -4.56 -0.228 0.77853E+04 20 analcite 3.32 -0.57 -3.89 -0.433 0.66468E+04 21 andalusite 5.00 1.98 -3.03 -0.303 0.51653E+04 22 andradite 39.01 34.86 -4.14 -0.215 0.70770E+04 23 grossular 32.73 28.05 -4.69 -0.234 0.80015E+04 24 anhydrite -5.32 -9.15 -3.83 -1.915 0.65388E+04 29 anorthite 12.71 9.41 -3.30 -0.254 0.56369E+04 35 aragonite 0.97 -1.57 -2.53 -0.844 0.43249E+04 36 brucite 12.57 8.71 -3.86 -0.771 0.65847E+04 37 calcite 0.81 -1.57 -2.38 -0.793 0.40607E+04 40 carpholite-Mg 8.58 6.92 -1.66 -0.111 0.28422E+04 41 carpholite-Fe 6.71 4.69 -2.02 -0.135 0.34508E+04 50 chloritoid-Mg 13.20 10.69 -2.51 -0.167 0.42843E+04 51 chloritoid-Fe 9.17 8.46 -0.71 -0.047 0.12140E+04 52 chloritoid-Mn 11.40 10.46 -0.94 -0.062 0.15997E+04 54 coesite -2.38 -3.77 -1.39 -0.465 0.23818E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.77 -1.21 -0.404 0.20672E+04 67 diopside 16.18 12.37 -3.81 -0.381 0.65014E+04 68 hedenbergite 14.21 10.15 -4.06 -0.406 0.69331E+04 75 epidote 24.67 23.12 -1.55 -0.075 0.26384E+04 76 clinozoisite 22.81 19.72 -3.09 -0.140 0.52773E+04 77 epidote-Fe 29.84 26.53 -3.31 -0.172 0.56461E+04 78 fayalite 14.05 9.20 -4.84 -0.692 0.82714E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.92 -4.22 -0.352 0.72103E+04 91 heulandite -5.83 -9.45 -3.62 -0.164 0.61790E+04 95 jadeite 4.22 -0.57 -4.79 -0.479 0.81723E+04 98 kaolinite -1.33 -1.79 -0.46 -0.042 0.78860E+03 99 kyanite 4.88 1.98 -2.90 -0.290 0.49512E+04 101 laumontite 2.88 1.87 -1.02 -0.068 0.17355E+04 102 lawsonite 9.62 9.41 -0.21 -0.014 0.35357E+03 105 lizardite 23.24 18.59 -4.65 -0.387 0.79387E+04 106 magnesite 0.69 -4.06 -4.75 -1.583 0.81079E+04 107 magnetite 20.09 19.05 -1.03 -0.084 0.17672E+04 110 magnesioferrite 26.21 21.28 -4.93 -0.403 0.84248E+04 113 margarite 17.32 15.16 -2.17 -0.087 0.37005E+04 116 microcline -2.49 -6.00 -3.52 -0.271 0.60075E+04 120 muscovite 2.58 -0.26 -2.84 -0.167 0.48491E+04 121 paragonite 4.24 1.41 -2.83 -0.167 0.48389E+04 136 prehnite 19.37 16.84 -2.53 -0.149 0.43204E+04 137 prehnite-Fe 22.50 20.25 -2.25 -0.135 0.38364E+04 138 pumpellyite-Fe 46.27 43.04 -3.23 -0.072 0.55087E+04 139 pumpellyite-Mg 48.99 45.27 -3.73 -0.083 0.63617E+04 145 pyroxmangite 7.40 4.72 -2.68 -0.536 0.45792E+04 146 pyrophyllite -6.18 -9.34 -3.16 -0.198 0.53971E+04 147 quartz -2.99 -3.77 -0.78 -0.261 0.13345E+04 151 rhodochrosite -0.98 -4.28 -3.31 -1.102 0.56447E+04 152 rhodonite 7.45 4.72 -2.73 -0.546 0.46595E+04 153 sanidine -1.28 -6.00 -4.73 -0.364 0.80753E+04 155 siderite -2.61 -6.28 -3.68 -1.225 0.62761E+04 156 sillimanite 5.26 1.98 -3.29 -0.329 0.56093E+04 163 stilbite -7.52 -9.45 -1.92 -0.092 0.32852E+04 164 stilpnomelane-Fe 13.02 9.23 -3.79 -0.113 0.64699E+04 168 sudoite 21.08 17.61 -3.47 -0.112 0.59271E+04 174 tephroite 18.09 13.20 -4.88 -0.697 0.83345E+04 177 topaz-H 4.62 1.98 -2.64 -0.240 0.45113E+04 178 tridymite -2.63 -3.77 -1.14 -0.382 0.19545E+04 187 wairakite 3.95 1.87 -2.08 -0.123 0.35575E+04 188 walstromite 11.51 7.43 -4.08 -0.815 0.69607E+04 189 wollastonite 10.46 7.43 -3.03 -0.606 0.51711E+04 190 pseudo-wollastonite 11.00 7.43 -3.57 -0.713 0.60910E+04 191 zoisite 22.85 19.72 -3.13 -0.142 0.53514E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.30 -3.65 -0.226 0.62317E+04 194 beidellite-H -2.33 -7.14 -4.82 -0.307 0.82260E+04 195 beidellite-K -1.52 -6.34 -4.82 -0.295 0.82305E+04 196 beidellite-Mg -1.79 -5.71 -3.92 -0.242 0.66875E+04 197 beidellite-Na -1.34 -5.79 -4.45 -0.272 0.75974E+04 199 chalcedony -2.80 -3.77 -0.97 -0.323 0.16538E+04 201 montmorillonite-Ca -2.29 -5.56 -3.27 -0.202 0.55845E+04 202 montmorillonite-K -2.24 -6.61 -4.37 -0.268 0.74614E+04 203 montmorillonite-Mg -2.48 -5.97 -3.49 -0.216 0.59635E+04 204 montmorillonite-Na -2.04 -6.06 -4.02 -0.246 0.68641E+04 205 nontronite-Ca 3.21 1.52 -1.69 -0.110 0.28874E+04 206 nontronite-H 2.53 -0.33 -2.86 -0.192 0.48796E+04 207 nontronite-K 3.34 0.48 -2.86 -0.184 0.48875E+04 208 nontronite-Mg 3.07 1.11 -1.96 -0.127 0.33504E+04 209 nontronite-Na 3.52 1.03 -2.49 -0.160 0.42561E+04 214 gypsum -4.96 -9.15 -4.19 -1.048 0.71564E+04 224 tobermorite 9.82 5.56 -4.26 -1.163 0.72763E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.49 -3.33 -0.831 0.56779E+04 240 silica-amorphous -2.09 -3.77 -1.68 -0.560 0.28680E+04 242 an20ab80 2.02 -1.59 -3.61 -0.278 0.61632E+04 243 an25ab75 2.65 -0.90 -3.55 -0.273 0.60614E+04 244 an30ab70 3.28 -0.22 -3.50 -0.269 0.59692E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0188000 g New total amount of reactant added: 0.0192000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0192000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3091411E-03 Osmotic coef. = 0.9895 True ionic strength = .3220398E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14369E-07 -7.8426 0.13781E-07 -7.8607 0.95905E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13229E-03 -3.8785 0.95891E+00 -0.0182 4 SO4-- 0.25273E-04 -4.5973 0.22551E-04 -4.6468 0.89231E+00 -0.0495 5 HCO3- 0.12588E-04 -4.9001 0.12071E-04 -4.9183 0.95894E+00 -0.0182 6 HS- 0.12395E-10 -10.9068 0.11886E-10 -10.9250 0.95891E+00 -0.0182 7 Al+++ 0.24734E-20 -20.6067 0.19566E-20 -20.7085 0.79108E+00 -0.1018 8 H4SiO4 0.17279E-03 -3.7625 0.17279E-03 -3.7625 0.10000E+01 0.0000 9 Ca++ 0.35908E-04 -4.4448 0.32035E-04 -4.4944 0.89216E+00 -0.0496 10 Mg++ 0.10844E-06 -6.9648 0.96739E-07 -7.0144 0.89206E+00 -0.0496 11 Fe++ 0.64424E-09 -9.1910 0.57472E-09 -9.2405 0.89209E+00 -0.0496 12 K+ 0.40749E-05 -5.3899 0.39076E-05 -5.4081 0.95895E+00 -0.0182 13 Na+ 0.18413E-03 -3.7349 0.17656E-03 -3.7531 0.95891E+00 -0.0182 14 Mn++ 0.65801E-07 -7.1818 0.58701E-07 -7.2314 0.89210E+00 -0.0496 15 HPO4-- 0.10185E-08 -8.9920 0.90884E-09 -9.0415 0.89231E+00 -0.0495 16 HSiO3- 0.12209E-04 -4.9133 0.11708E-04 -4.9315 0.95891E+00 -0.0182 17 Ca(HSiO3)+ 0.89072E-08 -8.0503 0.85416E-08 -8.0685 0.95895E+00 -0.0182 18 Mg(HSiO3)+ 0.33474E-10 -10.4753 0.32100E-10 -10.4935 0.95895E+00 -0.0182 19 NaHSiO3,aq 0.33433E-07 -7.4758 0.33433E-07 -7.4758 0.10000E+01 0.0000 20 AlO+ 0.14617E-11 -11.8352 0.14017E-11 -11.8534 0.95895E+00 -0.0182 21 AlOH+2 0.10781E-15 -15.9673 0.96181E-16 -16.0169 0.89212E+00 -0.0496 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.33932E-05 -5.4694 0.32537E-05 -5.4876 0.95887E+00 -0.0182 24 CH4,aq 0.61805E-17 -17.2090 0.61800E-17 -17.2090 0.99990E+00 0.0000 29 CO,aq 0.84612E-17 -17.0726 0.84612E-17 -17.0726 0.10000E+01 0.0000 30 CO2,aq 0.35548E-06 -6.4492 0.35544E-06 -6.4492 0.99990E+00 0.0000 31 CO3-2 0.85747E-07 -7.0668 0.76509E-07 -7.1163 0.89227E+00 -0.0495 32 CaCO3,aq 0.30733E-07 -7.5124 0.30733E-07 -7.5124 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10293E-07 -7.9874 0.98708E-08 -8.0056 0.95895E+00 -0.0182 34 CaCl+ 0.71520E-08 -8.1456 0.68584E-08 -8.1638 0.95895E+00 -0.0182 35 CaCl2,aq 0.21556E-12 -12.6664 0.21556E-12 -12.6664 0.10000E+01 0.0000 36 CaOH+ 0.17277E-06 -6.7625 0.16568E-06 -6.7807 0.95895E+00 -0.0182 37 CaSO4,aq 0.22941E-06 -6.6394 0.22941E-06 -6.6394 0.10000E+01 0.0000 38 HCl,aq 0.33407E-12 -12.4762 0.33407E-12 -12.4762 0.10000E+01 0.0000 43 FeCl+ 0.12549E-12 -12.9014 0.12034E-12 -12.9196 0.95895E+00 -0.0182 46 FeO,aq 0.11762E-09 -9.9295 0.11762E-09 -9.9295 0.10000E+01 0.0000 47 FeOH+ 0.14156E-08 -8.8490 0.13575E-08 -8.8673 0.95895E+00 -0.0182 48 HFeO2- 0.93130E-10 -10.0309 0.89304E-10 -10.0491 0.95891E+00 -0.0182 49 FeO+ 0.10969E-12 -12.9598 0.10519E-12 -12.9780 0.95895E+00 -0.0182 50 FeOH+2 0.31029E-18 -18.5082 0.27682E-18 -18.5578 0.89212E+00 -0.0496 51 FeO2- 0.11819E-09 -9.9274 0.11334E-09 -9.9456 0.95891E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.94770E-09 -9.0233 0.94761E-09 -9.0234 0.99990E+00 0.0000 54 KCl,aq 0.93692E-11 -11.0283 0.93692E-11 -11.0283 0.10000E+01 0.0000 55 KHSO4,aq 0.34336E-17 -17.4643 0.34336E-17 -17.4643 0.10000E+01 0.0000 56 KOH,aq 0.12110E-09 -9.9169 0.12110E-09 -9.9169 0.10000E+01 0.0000 57 KSO4- 0.14261E-08 -8.8459 0.13675E-08 -8.8641 0.95891E+00 -0.0182 58 MgCO3,aq 0.23262E-10 -10.6333 0.23262E-10 -10.6333 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.31761E-10 -10.4981 0.30458E-10 -10.5163 0.95895E+00 -0.0182 60 MgCl+ 0.19574E-10 -10.7083 0.18771E-10 -10.7265 0.95895E+00 -0.0182 61 MgOH+ 0.28869E-08 -8.5396 0.27684E-08 -8.5578 0.95895E+00 -0.0182 63 MnO,aq 0.32011E-09 -9.4947 0.32011E-09 -9.4947 0.10000E+01 0.0000 64 MnOH+ 0.13432E-07 -7.8719 0.12881E-07 -7.8901 0.95895E+00 -0.0182 65 MnO2-2 0.62695E-16 -16.2028 0.55941E-16 -16.2523 0.89227E+00 -0.0495 66 HMnO2- 0.17613E-12 -12.7542 0.16889E-12 -12.7724 0.95891E+00 -0.0182 69 MnCl+ 0.49867E-10 -10.3022 0.47820E-10 -10.3204 0.95895E+00 -0.0182 70 MnSO4,aq 0.38217E-09 -9.4177 0.38217E-09 -9.4177 0.10000E+01 0.0000 71 NaCl,aq 0.77407E-08 -8.1112 0.77407E-08 -8.1112 0.10000E+01 0.0000 72 NaOH,aq 0.55047E-08 -8.2593 0.55047E-08 -8.2593 0.10000E+01 0.0000 74 OH- 0.43725E-04 -4.3593 0.41926E-04 -4.3775 0.95887E+00 -0.0182 82 H3PO4,aq 0.12071E-14 -14.9183 0.12071E-14 -14.9183 0.10000E+01 0.0000 83 H2PO4- 0.24094E-09 -9.6181 0.23104E-09 -9.6363 0.95893E+00 -0.0182 84 PO4-3 0.67939E-13 -13.1679 0.53808E-13 -13.2692 0.79201E+00 -0.1013 88 HP2O7-3 0.76662E-19 -19.1154 0.60646E-19 -19.2172 0.79109E+00 -0.1018 90 H2S,aq 0.50628E-12 -12.2956 0.50623E-12 -12.2957 0.99990E+00 0.0000 96 SO2,aq 0.18124E-19 -19.7417 0.18124E-19 -19.7417 0.10000E+01 0.0000 97 SO3-2 0.31112E-14 -14.5071 0.27770E-14 -14.5564 0.89258E+00 -0.0494 98 HSO3- 0.24988E-14 -14.6023 0.23961E-14 -14.6205 0.95891E+00 -0.0182 99 HSO4- 0.31231E-09 -9.5054 0.29950E-09 -9.5236 0.95897E+00 -0.0182 101 S2O3-2 0.15030E-18 -18.8231 0.13410E-18 -18.8726 0.89227E+00 -0.0495 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1436913E-07 -.6955471E-04 -.7010485E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999682E+06 0.0000 3 Cl- 0.1379602E-03 0.1379752E-03 0.4891487E+01 3.9823 4 SO4-- 0.2527312E-04 0.2550445E-04 0.2449924E+01 11.0746 5 HCO3- 0.1258779E-04 0.1307010E-04 0.7974766E+00 2.9425 6 HS- 0.1239510E-10 0.2102094E-09 0.6951836E-05 -3.0642 7 Al+++ 0.2473367E-20 0.3413498E-05 0.9209850E-01 2.8737 8 H4SiO4 0.1727900E-03 0.1850418E-03 0.1778483E+02 -3.7625 9 Ca++ 0.3590754E-04 0.3636681E-04 0.1457465E+01 11.2271 10 Mg++ 0.1084440E-06 0.1114390E-06 0.2709223E-02 8.7071 11 Fe++ 0.6442415E-09 0.2587697E-08 0.1445108E-03 6.4809 12 K+ 0.4074907E-05 0.4076463E-05 0.1593930E+00 2.4526 13 Na+ 0.1841264E-03 0.1841730E-03 0.4233973E+01 4.1076 14 Mn++ 0.6580094E-07 0.7998535E-07 0.4394102E-02 8.4901 15 HPO4-- 0.1018514E-08 0.1259519E-08 0.1208837E-03 6.6799 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3048835E-03 -.6955419E-04 -.2353293E-03 0.0000000E+00 2 H2O 0.5550801E+02 0.5550788E+02 0.1326048E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2603657E-04 0.2550426E-04 0.5323077E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5320975E-06 0.2102079E-09 -.5323077E-06 0.0000000E+00 7 Al+++ 0.6260624E-04 0.3413472E-05 0.5919277E-04 0.0000000E+00 8 H4SiO4 0.1999254E-03 0.1850405E-03 0.1488497E-04 0.0000000E+00 9 Ca++ 0.3655380E-04 0.3636654E-04 0.1872633E-06 0.0000000E+00 10 Mg++ 0.1523810E-04 0.1114382E-06 0.1512666E-04 0.0000000E+00 11 Fe++ 0.1368976E-04 0.2587678E-08 0.1368718E-04 0.0000000E+00 12 K+ 0.4076433E-05 0.4076433E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1841717E-03 0.1841717E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3329010E-06 0.7998476E-07 0.2529163E-06 0.0000000E+00 15 HPO4-- 0.1136175E-06 0.1259509E-08 0.1123580E-06 0.0000000E+00 Chg. balance for solid moles: -.4817E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0192000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3745E-07 -7.427 0.1881E-04 -4.726 0.2950 0.5978E-05 clinochlore 0.3025E-05 -5.519 0.1682E-02 -2.774 26.37 0.6396E-03 daphnite 0.1886E-05 -5.725 0.1345E-02 -2.871 21.10 0.4077E-03 chlorite-Mn 0.5058E-07 -7.296 0.3586E-04 -4.445 0.5623 0.1143E-04 diaspore 0.4927E-04 -4.307 0.2956E-02 -2.529 46.35 0.8799E-03 hematite 0.2129E-05 -5.672 0.3400E-03 -3.468 5.332 0.6445E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3801E+00 0.3801E+00 1.0000 -0.420 chlorite-Mn 0.1019E-01 0.1019E-01 1.0000 -1.992 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006377 g Volume = 0.002009 cm3 Porosity: 99.8006% V(tot) - V(min): 0.10057E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0192000 g log = -1.7167 Original solution: 1000.0103000 g Original solution / Rock added: 52083.87 (Water/Rock Ratio), log = 4.7167 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3701E-04 1.0071 0.3803E-04 0.3776E-04 CH4,gas 0.8805E-14 1.0125 0.9096E-14 0.8984E-14 H2,gas 0.1219E-05 1.0005 0.1244E-05 0.1243E-05 H2S,gas 0.1369E-10 0.9960 0.1392E-10 0.1397E-10 S2,gas 0.4603E-29 1.0000 0.4696E-29 0.4696E-29 CO,gas 0.1236E-13 1.0000 0.1261E-13 0.1261E-13 SO3,gas 0.1587E-35 1.0000 0.1619E-35 0.1619E-35 SO2,gas 0.7681E-19 1.0000 0.7838E-19 0.7838E-19 HCl,gas 0.5777E-15 1.0000 0.5895E-15 0.5895E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.78 -6.12 -2.040 0.10448E+05 -4.420 3 CH4,gas 4.54 -11.20 -15.74 -3.935 0.26876E+05 -14.041 4 H2,gas 8.00 0.40 -7.60 -4.345 0.12984E+05 -5.905 5 H2S,gas -6.23 -18.79 -12.56 -6.278 0.21438E+05 -10.856 6 S2,gas -7.34 -38.36 -31.03 -4.773 0.52978E+05 -29.328 7 CO,gas 3.21 -12.38 -15.60 -4.799 0.26634E+05 -13.899 8 SO3,gas 17.12 -20.37 -37.49 -9.372 0.64013E+05 -35.791 9 SO2,gas 0.83 -19.97 -20.80 -5.548 0.35524E+05 -19.106 10 HCl,gas 5.19 -11.74 -16.93 -8.464 0.28905E+05 -15.230 11 acmite 7.71 2.87 -4.84 -0.503 0.82709E+04 15 albite-high 0.69 -4.31 -5.00 -0.385 0.85360E+04 16 albite -0.38 -4.31 -3.92 -0.302 0.66972E+04 19 spessartine 24.46 19.93 -4.53 -0.226 0.77298E+04 20 analcite 3.32 -0.54 -3.87 -0.430 0.66002E+04 21 andalusite 5.00 1.98 -3.02 -0.302 0.51508E+04 22 andradite 39.01 34.96 -4.05 -0.210 0.69131E+04 23 grossular 32.73 28.14 -4.59 -0.230 0.78377E+04 24 anhydrite -5.32 -9.14 -3.82 -1.912 0.65300E+04 29 anorthite 12.71 9.45 -3.26 -0.251 0.55677E+04 35 aragonite 0.97 -1.55 -2.52 -0.839 0.43001E+04 36 brucite 12.57 8.71 -3.86 -0.772 0.65934E+04 37 calcite 0.81 -1.55 -2.36 -0.788 0.40359E+04 40 carpholite-Mg 8.58 6.93 -1.65 -0.110 0.28218E+04 41 carpholite-Fe 6.71 4.70 -2.01 -0.134 0.34308E+04 50 chloritoid-Mg 13.20 10.69 -2.51 -0.167 0.42785E+04 51 chloritoid-Fe 9.17 8.47 -0.71 -0.047 0.12085E+04 52 chloritoid-Mn 11.40 10.48 -0.93 -0.062 0.15812E+04 54 coesite -2.38 -3.76 -1.39 -0.462 0.23673E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.76 -1.20 -0.401 0.20526E+04 67 diopside 16.18 12.41 -3.77 -0.377 0.64409E+04 68 hedenbergite 14.21 10.18 -4.03 -0.403 0.68730E+04 75 epidote 24.67 23.20 -1.47 -0.071 0.25146E+04 76 clinozoisite 22.81 19.79 -3.02 -0.137 0.51535E+04 77 epidote-Fe 29.84 26.61 -3.23 -0.168 0.55223E+04 78 fayalite 14.05 9.20 -4.85 -0.692 0.82751E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.92 -4.22 -0.352 0.72085E+04 91 heulandite -5.83 -9.36 -3.54 -0.161 0.60370E+04 95 jadeite 4.22 -0.54 -4.76 -0.476 0.81257E+04 98 kaolinite -1.33 -1.78 -0.44 -0.040 0.75948E+03 99 kyanite 4.88 1.98 -2.89 -0.289 0.49367E+04 101 laumontite 2.88 1.92 -0.96 -0.064 0.16372E+04 102 lawsonite 9.62 9.45 -0.17 -0.011 0.28439E+03 105 lizardite 23.24 18.60 -4.65 -0.387 0.79357E+04 106 magnesite 0.69 -4.07 -4.76 -1.588 0.81319E+04 107 magnetite 20.09 19.05 -1.04 -0.085 0.17763E+04 110 magnesioferrite 26.21 21.27 -4.94 -0.403 0.84335E+04 113 margarite 17.32 15.20 -2.13 -0.085 0.36313E+04 116 microcline -2.49 -5.96 -3.47 -0.267 0.59328E+04 120 muscovite 2.58 -0.21 -2.80 -0.164 0.47743E+04 121 paragonite 4.24 1.44 -2.80 -0.165 0.47778E+04 136 prehnite 19.37 16.91 -2.46 -0.145 0.41966E+04 137 prehnite-Fe 22.50 20.32 -2.17 -0.131 0.37126E+04 138 pumpellyite-Fe 46.27 43.18 -3.09 -0.069 0.52702E+04 139 pumpellyite-Mg 48.99 45.41 -3.59 -0.080 0.61228E+04 145 pyroxmangite 7.40 4.73 -2.67 -0.534 0.45608E+04 146 pyrophyllite -6.18 -9.30 -3.13 -0.195 0.53388E+04 147 quartz -2.99 -3.76 -0.77 -0.258 0.13200E+04 151 rhodochrosite -0.98 -4.29 -3.31 -1.104 0.56561E+04 152 rhodonite 7.45 4.73 -2.72 -0.544 0.46410E+04 153 sanidine -1.28 -5.96 -4.69 -0.360 0.80006E+04 155 siderite -2.61 -6.30 -3.69 -1.230 0.63005E+04 156 sillimanite 5.26 1.98 -3.28 -0.328 0.55947E+04 163 stilbite -7.52 -9.36 -1.84 -0.088 0.31432E+04 164 stilpnomelane-Fe 13.02 9.28 -3.74 -0.112 0.63834E+04 168 sudoite 21.08 17.62 -3.46 -0.111 0.59008E+04 174 tephroite 18.09 13.22 -4.87 -0.695 0.83121E+04 177 topaz-H 4.62 1.98 -2.63 -0.239 0.44968E+04 178 tridymite -2.63 -3.76 -1.14 -0.379 0.19399E+04 187 wairakite 3.95 1.92 -2.03 -0.119 0.34592E+04 188 walstromite 11.51 7.46 -4.04 -0.809 0.69061E+04 189 wollastonite 10.46 7.46 -3.00 -0.599 0.51165E+04 190 pseudo-wollastonite 11.00 7.46 -3.54 -0.707 0.60363E+04 191 zoisite 22.85 19.79 -3.06 -0.139 0.52276E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.26 -3.61 -0.224 0.61717E+04 194 beidellite-H -2.33 -7.11 -4.79 -0.305 0.81726E+04 195 beidellite-K -1.52 -6.30 -4.78 -0.293 0.81668E+04 196 beidellite-Mg -1.79 -5.68 -3.89 -0.240 0.66355E+04 197 beidellite-Na -1.34 -5.76 -4.41 -0.270 0.75382E+04 199 chalcedony -2.80 -3.76 -0.96 -0.320 0.16393E+04 201 montmorillonite-Ca -2.29 -5.53 -3.23 -0.200 0.55225E+04 202 montmorillonite-K -2.24 -6.57 -4.33 -0.265 0.73958E+04 203 montmorillonite-Mg -2.48 -5.94 -3.46 -0.214 0.59095E+04 204 montmorillonite-Na -2.04 -6.02 -3.98 -0.244 0.68029E+04 205 nontronite-Ca 3.21 1.56 -1.66 -0.107 0.28274E+04 206 nontronite-H 2.53 -0.29 -2.83 -0.189 0.48262E+04 207 nontronite-K 3.34 0.52 -2.83 -0.181 0.48238E+04 208 nontronite-Mg 3.07 1.14 -1.93 -0.125 0.32984E+04 209 nontronite-Na 3.52 1.06 -2.46 -0.158 0.41969E+04 214 gypsum -4.96 -9.14 -4.19 -1.047 0.71476E+04 224 tobermorite 9.82 5.59 -4.23 -1.155 0.72284E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.48 -3.33 -0.833 0.56870E+04 240 silica-amorphous -2.09 -3.76 -1.67 -0.557 0.28534E+04 242 an20ab80 2.02 -1.55 -3.57 -0.275 0.61004E+04 243 an25ab75 2.65 -0.87 -3.51 -0.270 0.59982E+04 244 an30ab70 3.28 -0.18 -3.46 -0.266 0.59056E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0192000 g New total amount of reactant added: 0.0196000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0196000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3106450E-03 Osmotic coef. = 0.9895 True ionic strength = .3239442E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14081E-07 -7.8514 0.13503E-07 -7.8696 0.95898E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13228E-03 -3.8785 0.95884E+00 -0.0183 4 SO4-- 0.25270E-04 -4.5974 0.22543E-04 -4.6470 0.89207E+00 -0.0496 5 HCO3- 0.12592E-04 -4.8999 0.12074E-04 -4.9181 0.95888E+00 -0.0182 6 HS- 0.11031E-10 -10.9574 0.10577E-10 -10.9756 0.95885E+00 -0.0183 7 Al+++ 0.23284E-20 -20.6329 0.18408E-20 -20.7350 0.79059E+00 -0.1021 8 H4SiO4 0.17614E-03 -3.7541 0.17614E-03 -3.7541 0.10000E+01 0.0000 9 Ca++ 0.36353E-04 -4.4395 0.32424E-04 -4.4891 0.89191E+00 -0.0497 10 Mg++ 0.10296E-06 -6.9873 0.91820E-07 -7.0371 0.89181E+00 -0.0497 11 Fe++ 0.61135E-09 -9.2137 0.54523E-09 -9.2634 0.89184E+00 -0.0497 12 K+ 0.41598E-05 -5.3809 0.39888E-05 -5.3992 0.95888E+00 -0.0182 13 Na+ 0.18463E-03 -3.7337 0.17703E-03 -3.7520 0.95884E+00 -0.0183 14 Mn++ 0.63464E-07 -7.1975 0.56600E-07 -7.2472 0.89186E+00 -0.0497 15 HPO4-- 0.97180E-09 -9.0124 0.86691E-09 -9.0620 0.89207E+00 -0.0496 16 HSiO3- 0.12703E-04 -4.8961 0.12180E-04 -4.9143 0.95884E+00 -0.0183 17 Ca(HSiO3)+ 0.93797E-08 -8.0278 0.89941E-08 -8.0460 0.95889E+00 -0.0182 18 Mg(HSiO3)+ 0.33056E-10 -10.4807 0.31697E-10 -10.4990 0.95889E+00 -0.0182 19 NaHSiO3,aq 0.34874E-07 -7.4575 0.34874E-07 -7.4575 0.10000E+01 0.0000 20 AlO+ 0.14323E-11 -11.8440 0.13734E-11 -11.8622 0.95889E+00 -0.0182 21 AlOH+2 0.10354E-15 -15.9849 0.92347E-16 -16.0346 0.89188E+00 -0.0497 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.34632E-05 -5.4605 0.33205E-05 -5.4788 0.95880E+00 -0.0183 24 CH4,aq 0.55035E-17 -17.2594 0.55029E-17 -17.2594 0.99990E+00 0.0000 29 CO,aq 0.80964E-17 -17.0917 0.80964E-17 -17.0917 0.10000E+01 0.0000 30 CO2,aq 0.34841E-06 -6.4579 0.34838E-06 -6.4580 0.99990E+00 0.0000 31 CO3-2 0.87556E-07 -7.0577 0.78102E-07 -7.1073 0.89202E+00 -0.0496 32 CaCO3,aq 0.31753E-07 -7.4982 0.31753E-07 -7.4982 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10422E-07 -7.9821 0.99932E-08 -8.0003 0.95889E+00 -0.0182 34 CaCl+ 0.72388E-08 -8.1403 0.69412E-08 -8.1586 0.95889E+00 -0.0182 35 CaCl2,aq 0.21814E-12 -12.6613 0.21814E-12 -12.6613 0.10000E+01 0.0000 36 CaOH+ 0.17847E-06 -6.7484 0.17113E-06 -6.7667 0.95889E+00 -0.0182 37 CaSO4,aq 0.23210E-06 -6.6343 0.23210E-06 -6.6343 0.10000E+01 0.0000 38 HCl,aq 0.32732E-12 -12.4850 0.32732E-12 -12.4850 0.10000E+01 0.0000 43 FeCl+ 0.11905E-12 -12.9243 0.11416E-12 -12.9425 0.95889E+00 -0.0182 46 FeO,aq 0.11622E-09 -9.9347 0.11622E-09 -9.9347 0.10000E+01 0.0000 47 FeOH+ 0.13707E-08 -8.8631 0.13143E-08 -8.8813 0.95889E+00 -0.0182 48 HFeO2- 0.93918E-10 -10.0273 0.90052E-10 -10.0455 0.95884E+00 -0.0183 49 FeO+ 0.10749E-12 -12.9686 0.10307E-12 -12.9869 0.95889E+00 -0.0182 50 FeOH+2 0.29801E-18 -18.5258 0.26578E-18 -18.5755 0.89188E+00 -0.0497 51 FeO2- 0.12063E-09 -9.9185 0.11566E-09 -9.9368 0.95884E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.92524E-09 -9.0337 0.92515E-09 -9.0338 0.99990E+00 0.0000 54 KCl,aq 0.95631E-11 -11.0194 0.95631E-11 -11.0194 0.10000E+01 0.0000 55 KHSO4,aq 0.34330E-17 -17.4643 0.34330E-17 -17.4643 0.10000E+01 0.0000 56 KOH,aq 0.12615E-09 -9.8991 0.12615E-09 -9.8991 0.10000E+01 0.0000 57 KSO4- 0.14552E-08 -8.8371 0.13953E-08 -8.8553 0.95884E+00 -0.0183 58 MgCO3,aq 0.22539E-10 -10.6471 0.22539E-10 -10.6471 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.30156E-10 -10.5206 0.28916E-10 -10.5389 0.95889E+00 -0.0182 60 MgCl+ 0.18579E-10 -10.7310 0.17815E-10 -10.7492 0.95889E+00 -0.0182 61 MgOH+ 0.27966E-08 -8.5534 0.26817E-08 -8.5716 0.95889E+00 -0.0182 63 MnO,aq 0.32147E-09 -9.4929 0.32147E-09 -9.4929 0.10000E+01 0.0000 64 MnOH+ 0.13218E-07 -7.8788 0.12675E-07 -7.8971 0.95889E+00 -0.0182 65 MnO2-2 0.65594E-16 -16.1831 0.58511E-16 -16.2328 0.89202E+00 -0.0496 66 HMnO2- 0.18052E-12 -12.7435 0.17309E-12 -12.7617 0.95884E+00 -0.0183 69 MnCl+ 0.48083E-10 -10.3180 0.46106E-10 -10.3362 0.95889E+00 -0.0182 70 MnSO4,aq 0.36835E-09 -9.4337 0.36835E-09 -9.4337 0.10000E+01 0.0000 71 NaCl,aq 0.77607E-08 -8.1101 0.77607E-08 -8.1101 0.10000E+01 0.0000 72 NaOH,aq 0.56327E-08 -8.2493 0.56327E-08 -8.2493 0.10000E+01 0.0000 74 OH- 0.44626E-04 -4.3504 0.42788E-04 -4.3687 0.95880E+00 -0.0183 82 H3PO4,aq 0.11055E-14 -14.9564 0.11055E-14 -14.9564 0.10000E+01 0.0000 83 H2PO4- 0.22521E-09 -9.6474 0.21594E-09 -9.6657 0.95886E+00 -0.0182 84 PO4-3 0.66177E-13 -13.1793 0.52380E-13 -13.2808 0.79152E+00 -0.1015 88 HP2O7-3 0.68390E-19 -19.1650 0.54069E-19 -19.2671 0.79059E+00 -0.1020 90 H2S,aq 0.44145E-12 -12.3551 0.44141E-12 -12.3552 0.99990E+00 0.0000 96 SO2,aq 0.16983E-19 -19.7700 0.16983E-19 -19.7700 0.10000E+01 0.0000 97 SO3-2 0.30372E-14 -14.5175 0.27102E-14 -14.5670 0.89233E+00 -0.0495 98 HSO3- 0.23897E-14 -14.6217 0.22914E-14 -14.6399 0.95884E+00 -0.0183 99 HSO4- 0.30593E-09 -9.5144 0.29336E-09 -9.5326 0.95891E+00 -0.0182 101 S2O3-2 0.13104E-18 -18.8826 0.11689E-18 -18.9322 0.89202E+00 -0.0496 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1408076E-07 -.7124735E-04 -.7181086E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999678E+06 0.0000 3 Cl- 0.1379601E-03 0.1379752E-03 0.4891486E+01 3.9911 4 SO4-- 0.2527042E-04 0.2550446E-04 0.2449924E+01 11.0921 5 HCO3- 0.1259191E-04 0.1307010E-04 0.7974764E+00 2.9514 6 HS- 0.1103089E-10 0.2028607E-09 0.6708802E-05 -3.1061 7 Al+++ 0.2328395E-20 0.3483469E-05 0.9398632E-01 2.8737 8 H4SiO4 0.1761422E-03 0.1888895E-03 0.1815463E+02 -3.7541 9 Ca++ 0.3635345E-04 0.3682282E-04 0.1475740E+01 11.2500 10 Mg++ 0.1029583E-06 0.1058592E-06 0.2573571E-02 8.7021 11 Fe++ 0.6113534E-09 0.2511676E-08 0.1402652E-03 6.4757 12 K+ 0.4159799E-05 0.4161390E-05 0.1627137E+00 2.4704 13 Na+ 0.1846269E-03 0.1846752E-03 0.4245515E+01 4.1176 14 Mn++ 0.6346373E-07 0.7742027E-07 0.4253184E-02 8.4919 15 HPO4-- 0.9717961E-09 0.1197072E-08 0.1148903E-03 6.6771 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3115069E-03 -.7124682E-04 -.2402601E-03 0.0000000E+00 2 H2O 0.5550800E+02 0.5550787E+02 0.1353745E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2604765E-04 0.2550427E-04 0.5433857E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5431828E-06 0.2028591E-09 -.5433857E-06 0.0000000E+00 7 Al+++ 0.6391054E-04 0.3483442E-05 0.6042709E-04 0.0000000E+00 8 H4SiO4 0.2040905E-03 0.1888881E-03 0.1520249E-04 0.0000000E+00 9 Ca++ 0.3701386E-04 0.3682254E-04 0.1913124E-06 0.0000000E+00 10 Mg++ 0.1555556E-04 0.1058584E-06 0.1544970E-04 0.0000000E+00 11 Fe++ 0.1397497E-04 0.2511657E-08 0.1397246E-04 0.0000000E+00 12 K+ 0.4161359E-05 0.4161359E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1846738E-03 0.1846738E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3398365E-06 0.7741968E-07 0.2624168E-06 0.0000000E+00 15 HPO4-- 0.1159845E-06 0.1197063E-08 0.1147874E-06 0.0000000E+00 Chg. balance for solid moles: 0.1141E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0196000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3826E-07 -7.417 0.1922E-04 -4.716 0.2952 0.6107E-05 clinochlore 0.3090E-05 -5.510 0.1717E-02 -2.765 26.38 0.6533E-03 daphnite 0.1925E-05 -5.716 0.1374E-02 -2.862 21.09 0.4162E-03 chlorite-Mn 0.5248E-07 -7.280 0.3721E-04 -4.429 0.5714 0.1186E-04 diaspore 0.5029E-04 -4.299 0.3017E-02 -2.520 46.33 0.8982E-03 hematite 0.2174E-05 -5.663 0.3471E-03 -3.460 5.331 0.6579E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3799E+00 0.3799E+00 1.0000 -0.420 chlorite-Mn 0.1036E-01 0.1036E-01 1.0000 -1.985 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006512 g Volume = 0.002051 cm3 Porosity: 99.7964% V(tot) - V(min): 0.10058E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0196000 g log = -1.7077 Original solution: 1000.0103000 g Original solution / Rock added: 51020.93 (Water/Rock Ratio), log = 4.7077 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3627E-04 1.0071 0.3727E-04 0.3701E-04 CH4,gas 0.7840E-14 1.0125 0.8100E-14 0.8000E-14 H2,gas 0.1190E-05 1.0005 0.1215E-05 0.1214E-05 H2S,gas 0.1194E-10 0.9960 0.1213E-10 0.1218E-10 S2,gas 0.3672E-29 1.0000 0.3746E-29 0.3746E-29 CO,gas 0.1182E-13 1.0000 0.1207E-13 0.1207E-13 SO3,gas 0.1523E-35 1.0000 0.1554E-35 0.1554E-35 SO2,gas 0.7198E-19 1.0000 0.7344E-19 0.7344E-19 HCl,gas 0.5661E-15 1.0000 0.5776E-15 0.5776E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.79 -6.13 -2.043 0.10463E+05 -4.429 3 CH4,gas 4.54 -11.25 -15.79 -3.948 0.26962E+05 -14.092 4 H2,gas 8.00 0.39 -7.61 -4.351 0.13002E+05 -5.916 5 H2S,gas -6.23 -18.85 -12.61 -6.307 0.21540E+05 -10.916 6 S2,gas -7.34 -38.46 -31.13 -4.789 0.53146E+05 -29.426 7 CO,gas 3.21 -12.40 -15.62 -4.805 0.26666E+05 -13.918 8 SO3,gas 17.12 -20.39 -37.51 -9.377 0.64043E+05 -35.809 9 SO2,gas 0.83 -20.00 -20.83 -5.555 0.35572E+05 -19.134 10 HCl,gas 5.19 -11.75 -16.94 -8.469 0.28920E+05 -15.238 11 acmite 7.71 2.89 -4.82 -0.500 0.82254E+04 15 albite-high 0.69 -4.27 -4.96 -0.382 0.84762E+04 16 albite -0.38 -4.27 -3.89 -0.299 0.66374E+04 19 spessartine 24.46 19.96 -4.50 -0.225 0.76777E+04 20 analcite 3.32 -0.52 -3.84 -0.427 0.65547E+04 21 andalusite 5.00 1.99 -3.01 -0.301 0.51365E+04 22 andradite 39.01 35.05 -3.95 -0.205 0.67530E+04 23 grossular 32.73 28.23 -4.50 -0.225 0.76776E+04 24 anhydrite -5.32 -9.14 -3.82 -1.910 0.65214E+04 29 anorthite 12.71 9.49 -3.22 -0.248 0.55001E+04 35 aragonite 0.97 -1.54 -2.50 -0.835 0.42759E+04 36 brucite 12.57 8.70 -3.87 -0.773 0.66019E+04 37 calcite 0.81 -1.54 -2.35 -0.783 0.40117E+04 40 carpholite-Mg 8.58 6.94 -1.64 -0.109 0.28018E+04 41 carpholite-Fe 6.71 4.71 -2.00 -0.133 0.34112E+04 50 chloritoid-Mg 13.20 10.70 -2.50 -0.167 0.42727E+04 51 chloritoid-Fe 9.17 8.47 -0.70 -0.047 0.12032E+04 52 chloritoid-Mn 11.40 10.49 -0.92 -0.061 0.15638E+04 54 coesite -2.38 -3.75 -1.38 -0.459 0.23530E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.75 -1.19 -0.398 0.20384E+04 67 diopside 16.18 12.44 -3.74 -0.374 0.63818E+04 68 hedenbergite 14.21 10.22 -3.99 -0.399 0.68143E+04 75 epidote 24.67 23.27 -1.40 -0.068 0.23936E+04 76 clinozoisite 22.81 19.86 -2.95 -0.134 0.50325E+04 77 epidote-Fe 29.84 26.68 -3.16 -0.164 0.54013E+04 78 fayalite 14.05 9.20 -4.85 -0.693 0.82786E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.92 -4.22 -0.352 0.72067E+04 91 heulandite -5.83 -9.28 -3.45 -0.157 0.58982E+04 95 jadeite 4.22 -0.52 -4.73 -0.473 0.80802E+04 98 kaolinite -1.33 -1.76 -0.43 -0.039 0.73099E+03 99 kyanite 4.88 1.99 -2.88 -0.288 0.49224E+04 101 laumontite 2.88 1.98 -0.90 -0.060 0.15411E+04 102 lawsonite 9.62 9.49 -0.13 -0.008 0.21678E+03 105 lizardite 23.24 18.60 -4.65 -0.387 0.79328E+04 106 magnesite 0.69 -4.09 -4.78 -1.592 0.81553E+04 107 magnetite 20.09 19.04 -1.05 -0.085 0.17852E+04 110 magnesioferrite 26.21 21.27 -4.94 -0.404 0.84420E+04 113 margarite 17.32 15.24 -2.09 -0.083 0.35637E+04 116 microcline -2.49 -5.92 -3.43 -0.264 0.58597E+04 120 muscovite 2.58 -0.17 -2.75 -0.162 0.47013E+04 121 paragonite 4.24 1.48 -2.76 -0.163 0.47180E+04 136 prehnite 19.37 16.98 -2.39 -0.140 0.40756E+04 137 prehnite-Fe 22.50 20.39 -2.10 -0.127 0.35917E+04 138 pumpellyite-Fe 46.27 43.32 -2.95 -0.066 0.50372E+04 139 pumpellyite-Mg 48.99 45.55 -3.45 -0.077 0.58894E+04 145 pyroxmangite 7.40 4.74 -2.66 -0.532 0.45434E+04 146 pyrophyllite -6.18 -9.27 -3.09 -0.193 0.52818E+04 147 quartz -2.99 -3.75 -0.76 -0.255 0.13057E+04 151 rhodochrosite -0.98 -4.30 -3.32 -1.106 0.56679E+04 152 rhodonite 7.45 4.74 -2.71 -0.542 0.46236E+04 153 sanidine -1.28 -5.92 -4.64 -0.357 0.79275E+04 155 siderite -2.61 -6.31 -3.70 -1.235 0.63242E+04 156 sillimanite 5.26 1.99 -3.27 -0.327 0.55805E+04 163 stilbite -7.52 -9.28 -1.76 -0.084 0.30043E+04 164 stilpnomelane-Fe 13.02 9.33 -3.69 -0.110 0.62988E+04 168 sudoite 21.08 17.64 -3.44 -0.111 0.58752E+04 174 tephroite 18.09 13.23 -4.86 -0.694 0.82915E+04 177 topaz-H 4.62 1.99 -2.63 -0.239 0.44825E+04 178 tridymite -2.63 -3.75 -1.13 -0.376 0.19257E+04 187 wairakite 3.95 1.98 -1.97 -0.116 0.33631E+04 188 walstromite 11.51 7.50 -4.01 -0.803 0.68527E+04 189 wollastonite 10.46 7.50 -2.97 -0.593 0.50632E+04 190 pseudo-wollastonite 11.00 7.50 -3.50 -0.701 0.59830E+04 191 zoisite 22.85 19.86 -2.99 -0.136 0.51066E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.23 -3.58 -0.221 0.61129E+04 194 beidellite-H -2.33 -7.08 -4.76 -0.303 0.81203E+04 195 beidellite-K -1.52 -6.27 -4.75 -0.291 0.81045E+04 196 beidellite-Mg -1.79 -5.65 -3.86 -0.239 0.65846E+04 197 beidellite-Na -1.34 -5.72 -4.38 -0.268 0.74803E+04 199 chalcedony -2.80 -3.75 -0.95 -0.317 0.16250E+04 201 montmorillonite-Ca -2.29 -5.49 -3.20 -0.198 0.54619E+04 202 montmorillonite-K -2.24 -6.53 -4.29 -0.263 0.73316E+04 203 montmorillonite-Mg -2.48 -5.91 -3.43 -0.212 0.58568E+04 204 montmorillonite-Na -2.04 -5.99 -3.95 -0.242 0.67431E+04 205 nontronite-Ca 3.21 1.59 -1.62 -0.105 0.27686E+04 206 nontronite-H 2.53 -0.26 -2.80 -0.187 0.47739E+04 207 nontronite-K 3.34 0.55 -2.79 -0.179 0.47615E+04 208 nontronite-Mg 3.07 1.17 -1.90 -0.123 0.32475E+04 209 nontronite-Na 3.52 1.10 -2.42 -0.156 0.41390E+04 214 gypsum -4.96 -9.14 -4.18 -1.045 0.71390E+04 224 tobermorite 9.82 5.62 -4.21 -1.148 0.71815E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.48 -3.34 -0.834 0.56959E+04 240 silica-amorphous -2.09 -3.75 -1.66 -0.554 0.28392E+04 242 an20ab80 2.02 -1.52 -3.54 -0.272 0.60391E+04 243 an25ab75 2.65 -0.83 -3.48 -0.267 0.59365E+04 244 an30ab70 3.28 -0.14 -3.42 -0.263 0.58435E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0196000 g New total amount of reactant added: 0.0200000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0200000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3121479E-03 Osmotic coef. = 0.9894 True ionic strength = .3258500E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13806E-07 -7.8599 0.13238E-07 -7.8782 0.95892E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13227E-03 -3.8785 0.95878E+00 -0.0183 4 SO4-- 0.25268E-04 -4.5974 0.22534E-04 -4.6472 0.89182E+00 -0.0497 5 HCO3- 0.12596E-04 -4.8998 0.12077E-04 -4.9180 0.95881E+00 -0.0183 6 HS- 0.98441E-11 -11.0068 0.94383E-11 -11.0251 0.95878E+00 -0.0183 7 Al+++ 0.21954E-20 -20.6585 0.17346E-20 -20.7608 0.79009E+00 -0.1023 8 H4SiO4 0.17949E-03 -3.7460 0.17949E-03 -3.7460 0.10000E+01 0.0000 9 Ca++ 0.36799E-04 -4.4342 0.32813E-04 -4.4840 0.89167E+00 -0.0498 10 Mg++ 0.97878E-07 -7.0093 0.87265E-07 -7.0592 0.89157E+00 -0.0498 11 Fe++ 0.58093E-09 -9.2359 0.51795E-09 -9.2857 0.89159E+00 -0.0498 12 K+ 0.42447E-05 -5.3722 0.40699E-05 -5.3904 0.95882E+00 -0.0183 13 Na+ 0.18513E-03 -3.7325 0.17750E-03 -3.7508 0.95877E+00 -0.0183 14 Mn++ 0.61217E-07 -7.2131 0.54582E-07 -7.2630 0.89161E+00 -0.0498 15 HPO4-- 0.92812E-09 -9.0324 0.82772E-09 -9.0821 0.89182E+00 -0.0497 16 HSiO3- 0.13204E-04 -4.8793 0.12660E-04 -4.8976 0.95878E+00 -0.0183 17 Ca(HSiO3)+ 0.98665E-08 -8.0058 0.94602E-08 -8.0241 0.95882E+00 -0.0183 18 Mg(HSiO3)+ 0.32656E-10 -10.4860 0.31311E-10 -10.5043 0.95882E+00 -0.0183 19 NaHSiO3,aq 0.36343E-07 -7.4396 0.36343E-07 -7.4396 0.10000E+01 0.0000 20 AlO+ 0.14043E-11 -11.8525 0.13465E-11 -11.8708 0.95882E+00 -0.0183 21 AlOH+2 0.99549E-16 -16.0020 0.88760E-16 -16.0518 0.89163E+00 -0.0498 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.35327E-05 -5.4519 0.33870E-05 -5.4702 0.95874E+00 -0.0183 24 CH4,aq 0.49140E-17 -17.3086 0.49135E-17 -17.3086 0.99990E+00 0.0000 29 CO,aq 0.77556E-17 -17.1104 0.77556E-17 -17.1104 0.10000E+01 0.0000 30 CO2,aq 0.34166E-06 -6.4664 0.34162E-06 -6.4665 0.99990E+00 0.0000 31 CO3-2 0.89353E-07 -7.0489 0.79682E-07 -7.0986 0.89177E+00 -0.0497 32 CaCO3,aq 0.32784E-07 -7.4843 0.32784E-07 -7.4843 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10550E-07 -7.9768 0.10115E-07 -7.9950 0.95882E+00 -0.0183 34 CaCl+ 0.73255E-08 -8.1352 0.70238E-08 -8.1534 0.95882E+00 -0.0183 35 CaCl2,aq 0.22073E-12 -12.6561 0.22073E-12 -12.6561 0.10000E+01 0.0000 36 CaOH+ 0.18423E-06 -6.7346 0.17665E-06 -6.7529 0.95882E+00 -0.0183 37 CaSO4,aq 0.23480E-06 -6.6293 0.23480E-06 -6.6293 0.10000E+01 0.0000 38 HCl,aq 0.32088E-12 -12.4937 0.32088E-12 -12.4937 0.10000E+01 0.0000 43 FeCl+ 0.11310E-12 -12.9465 0.10844E-12 -12.9648 0.95882E+00 -0.0183 46 FeO,aq 0.11486E-09 -9.9398 0.11486E-09 -9.9398 0.10000E+01 0.0000 47 FeOH+ 0.13283E-08 -8.8767 0.12736E-08 -8.8950 0.95882E+00 -0.0183 48 HFeO2- 0.94687E-10 -10.0237 0.90784E-10 -10.0420 0.95878E+00 -0.0183 49 FeO+ 0.10539E-12 -12.9772 0.10105E-12 -12.9955 0.95882E+00 -0.0183 50 FeOH+2 0.28651E-18 -18.5429 0.25546E-18 -18.5927 0.89163E+00 -0.0498 51 FeO2- 0.12305E-09 -9.9099 0.11798E-09 -9.9282 0.95878E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.90381E-09 -9.0439 0.90373E-09 -9.0440 0.99990E+00 0.0000 54 KCl,aq 0.97569E-11 -11.0107 0.97569E-11 -11.0107 0.10000E+01 0.0000 55 KHSO4,aq 0.34328E-17 -17.4644 0.34328E-17 -17.4644 0.10000E+01 0.0000 56 KOH,aq 0.13129E-09 -9.8818 0.13129E-09 -9.8818 0.10000E+01 0.0000 57 KSO4- 0.14843E-08 -8.8285 0.14231E-08 -8.8468 0.95878E+00 -0.0183 58 MgCO3,aq 0.21854E-10 -10.6605 0.21854E-10 -10.6605 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28669E-10 -10.5426 0.27488E-10 -10.5609 0.95882E+00 -0.0183 60 MgCl+ 0.17657E-10 -10.7531 0.16930E-10 -10.7713 0.95882E+00 -0.0183 61 MgOH+ 0.27112E-08 -8.5668 0.25996E-08 -8.5851 0.95882E+00 -0.0183 63 MnO,aq 0.32253E-09 -9.4914 0.32253E-09 -9.4914 0.10000E+01 0.0000 64 MnOH+ 0.13003E-07 -7.8860 0.12467E-07 -7.9042 0.95882E+00 -0.0183 65 MnO2-2 0.68488E-16 -16.1644 0.61076E-16 -16.2141 0.89177E+00 -0.0497 66 HMnO2- 0.18476E-12 -12.7334 0.17714E-12 -12.7517 0.95878E+00 -0.0183 69 MnCl+ 0.46368E-10 -10.3338 0.44459E-10 -10.3520 0.95882E+00 -0.0183 70 MnSO4,aq 0.35508E-09 -9.4497 0.35508E-09 -9.4497 0.10000E+01 0.0000 71 NaCl,aq 0.77806E-08 -8.1090 0.77806E-08 -8.1090 0.10000E+01 0.0000 72 NaOH,aq 0.57606E-08 -8.2395 0.57606E-08 -8.2395 0.10000E+01 0.0000 74 OH- 0.45522E-04 -4.3418 0.43644E-04 -4.3601 0.95874E+00 -0.0183 82 H3PO4,aq 0.10146E-14 -14.9937 0.10146E-14 -14.9937 0.10000E+01 0.0000 83 H2PO4- 0.21083E-09 -9.6761 0.20214E-09 -9.6943 0.95880E+00 -0.0183 84 PO4-3 0.64489E-13 -13.1905 0.51013E-13 -13.2923 0.79104E+00 -0.1018 88 HP2O7-3 0.61162E-19 -19.2135 0.48324E-19 -19.3158 0.79010E+00 -0.1023 90 H2S,aq 0.38620E-12 -12.4132 0.38617E-12 -12.4132 0.99990E+00 0.0000 96 SO2,aq 0.15939E-19 -19.7975 0.15939E-19 -19.7975 0.10000E+01 0.0000 97 SO3-2 0.29665E-14 -14.5278 0.26464E-14 -14.5773 0.89209E+00 -0.0496 98 HSO3- 0.22879E-14 -14.6406 0.21936E-14 -14.6588 0.95878E+00 -0.0183 99 HSO4- 0.29983E-09 -9.5231 0.28749E-09 -9.5414 0.95884E+00 -0.0183 101 S2O3-2 0.11463E-18 -18.9407 0.10222E-18 -18.9905 0.89177E+00 -0.0497 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1380559E-07 -.7293966E-04 -.7351651E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999674E+06 0.0000 3 Cl- 0.1379601E-03 0.1379752E-03 0.4891484E+01 3.9996 4 SO4-- 0.2526772E-04 0.2550447E-04 0.2449924E+01 11.1092 5 HCO3- 0.1259571E-04 0.1307010E-04 0.7974762E+00 2.9601 6 HS- 0.9844066E-11 0.1959600E-09 0.6480589E-05 -3.1469 7 Al+++ 0.2195448E-20 0.3552986E-05 0.9586190E-01 2.8737 8 H4SiO4 0.1794872E-03 0.1927374E-03 0.1852446E+02 -3.7460 9 Ca++ 0.3679929E-04 0.3727885E-04 0.1494015E+01 11.2724 10 Mg++ 0.9787787E-07 0.1006900E-06 0.2447898E-02 8.6972 11 Fe++ 0.5809288E-09 0.2440643E-08 0.1362984E-03 6.4706 12 K+ 0.4244692E-05 0.4246317E-05 0.1660343E+00 2.4877 13 Na+ 0.1851274E-03 0.1851773E-03 0.4257057E+01 4.1274 14 Mn++ 0.6121747E-07 0.7494457E-07 0.4117177E-02 8.4934 15 HPO4-- 0.9281188E-09 0.1139010E-08 0.1093176E-03 6.6742 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3181303E-03 -.7293910E-04 -.2451912E-03 0.0000000E+00 2 H2O 0.5550800E+02 0.5550786E+02 0.1381450E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2605874E-04 0.2550427E-04 0.5544641E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542682E-06 0.1959585E-09 -.5544641E-06 0.0000000E+00 7 Al+++ 0.6521483E-04 0.3552958E-05 0.6166187E-04 0.0000000E+00 8 H4SiO4 0.2082557E-03 0.1927360E-03 0.1551970E-04 0.0000000E+00 9 Ca++ 0.3747391E-04 0.3727856E-04 0.1953542E-06 0.0000000E+00 10 Mg++ 0.1587302E-04 0.1006892E-06 0.1577233E-04 0.0000000E+00 11 Fe++ 0.1426017E-04 0.2440625E-08 0.1425773E-04 0.0000000E+00 12 K+ 0.4246285E-05 0.4246285E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1851759E-03 0.1851759E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3467719E-06 0.7494399E-07 0.2718279E-06 0.0000000E+00 15 HPO4-- 0.1183515E-06 0.1139001E-08 0.1172125E-06 0.0000000E+00 Chg. balance for solid moles: 0.7041E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0200000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3907E-07 -7.408 0.1963E-04 -4.707 0.2953 0.6236E-05 clinochlore 0.3154E-05 -5.501 0.1753E-02 -2.756 26.38 0.6669E-03 daphnite 0.1964E-05 -5.707 0.1402E-02 -2.853 21.09 0.4247E-03 chlorite-Mn 0.5437E-07 -7.265 0.3854E-04 -4.414 0.5800 0.1228E-04 diaspore 0.5132E-04 -4.290 0.3078E-02 -2.512 46.32 0.9165E-03 hematite 0.2218E-05 -5.654 0.3542E-03 -3.451 5.330 0.6713E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3797E+00 0.3797E+00 1.0000 -0.421 chlorite-Mn 0.1051E-01 0.1051E-01 1.0000 -1.978 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006646 g Volume = 0.002094 cm3 Porosity: 99.7923% V(tot) - V(min): 0.10059E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0200000 g log = -1.6990 Original solution: 1000.0103000 g Original solution / Rock added: 50000.52 (Water/Rock Ratio), log = 4.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3557E-04 1.0071 0.3655E-04 0.3629E-04 CH4,gas 0.7001E-14 1.0125 0.7232E-14 0.7143E-14 H2,gas 0.1162E-05 1.0005 0.1186E-05 0.1186E-05 H2S,gas 0.1045E-10 0.9960 0.1062E-10 0.1066E-10 S2,gas 0.2945E-29 1.0000 0.3005E-29 0.3005E-29 CO,gas 0.1133E-13 1.0000 0.1156E-13 0.1156E-13 SO3,gas 0.1463E-35 1.0000 0.1493E-35 0.1493E-35 SO2,gas 0.6755E-19 1.0000 0.6893E-19 0.6893E-19 HCl,gas 0.5549E-15 1.0000 0.5662E-15 0.5662E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.80 -6.14 -2.045 0.10477E+05 -4.437 3 CH4,gas 4.54 -11.30 -15.84 -3.960 0.27046E+05 -14.141 4 H2,gas 8.00 0.38 -7.62 -4.357 0.13019E+05 -5.926 5 H2S,gas -6.23 -18.90 -12.67 -6.337 0.21639E+05 -10.974 6 S2,gas -7.34 -38.56 -31.22 -4.803 0.53309E+05 -29.522 7 CO,gas 3.21 -12.42 -15.64 -4.811 0.26698E+05 -13.937 8 SO3,gas 17.12 -20.40 -37.52 -9.381 0.64073E+05 -35.826 9 SO2,gas 0.83 -20.03 -20.86 -5.563 0.35619E+05 -19.162 10 HCl,gas 5.19 -11.76 -16.95 -8.473 0.28935E+05 -15.247 11 acmite 7.71 2.92 -4.79 -0.498 0.81808E+04 15 albite-high 0.69 -4.24 -4.93 -0.379 0.84177E+04 16 albite -0.38 -4.24 -3.85 -0.296 0.65789E+04 19 spessartine 24.46 19.99 -4.47 -0.223 0.76285E+04 20 analcite 3.32 -0.49 -3.81 -0.424 0.65102E+04 21 andalusite 5.00 2.00 -3.00 -0.300 0.51226E+04 22 andradite 39.01 35.15 -3.86 -0.201 0.65966E+04 23 grossular 32.73 28.33 -4.40 -0.220 0.75211E+04 24 anhydrite -5.32 -9.13 -3.81 -1.907 0.65128E+04 29 anorthite 12.71 9.53 -3.18 -0.245 0.54340E+04 35 aragonite 0.97 -1.52 -2.49 -0.830 0.42522E+04 36 brucite 12.57 8.70 -3.87 -0.774 0.66103E+04 37 calcite 0.81 -1.52 -2.34 -0.779 0.39880E+04 40 carpholite-Mg 8.58 6.95 -1.63 -0.109 0.27823E+04 41 carpholite-Fe 6.71 4.73 -1.99 -0.132 0.33920E+04 50 chloritoid-Mg 13.20 10.70 -2.50 -0.167 0.42672E+04 51 chloritoid-Fe 9.17 8.47 -0.70 -0.047 0.11979E+04 52 chloritoid-Mn 11.40 10.49 -0.91 -0.060 0.15474E+04 54 coesite -2.38 -3.75 -1.37 -0.457 0.23391E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.75 -1.19 -0.395 0.20244E+04 67 diopside 16.18 12.48 -3.70 -0.370 0.63241E+04 68 hedenbergite 14.21 10.25 -3.96 -0.396 0.67569E+04 75 epidote 24.67 23.34 -1.33 -0.065 0.22754E+04 76 clinozoisite 22.81 19.93 -2.88 -0.131 0.49143E+04 77 epidote-Fe 29.84 26.75 -3.09 -0.161 0.52831E+04 78 fayalite 14.05 9.20 -4.85 -0.693 0.82820E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.92 -4.22 -0.352 0.72048E+04 91 heulandite -5.83 -9.20 -3.37 -0.153 0.57623E+04 95 jadeite 4.22 -0.49 -4.71 -0.471 0.80356E+04 98 kaolinite -1.33 -1.74 -0.41 -0.037 0.70309E+03 99 kyanite 4.88 2.00 -2.87 -0.287 0.49085E+04 101 laumontite 2.88 2.04 -0.85 -0.057 0.14471E+04 102 lawsonite 9.62 9.53 -0.09 -0.006 0.15067E+03 105 lizardite 23.24 18.60 -4.64 -0.387 0.79300E+04 106 magnesite 0.69 -4.10 -4.79 -1.597 0.81782E+04 107 magnetite 20.09 19.04 -1.05 -0.086 0.17939E+04 110 magnesioferrite 26.21 21.26 -4.95 -0.404 0.84504E+04 113 margarite 17.32 15.28 -2.05 -0.082 0.34976E+04 116 microcline -2.49 -5.88 -3.39 -0.261 0.57883E+04 120 muscovite 2.58 -0.13 -2.71 -0.159 0.46298E+04 121 paragonite 4.24 1.51 -2.73 -0.161 0.46595E+04 136 prehnite 19.37 17.05 -2.32 -0.136 0.39573E+04 137 prehnite-Fe 22.50 20.46 -2.03 -0.122 0.34734E+04 138 pumpellyite-Fe 46.27 43.45 -2.82 -0.063 0.48093E+04 139 pumpellyite-Mg 48.99 45.68 -3.32 -0.074 0.56612E+04 145 pyroxmangite 7.40 4.75 -2.65 -0.530 0.45270E+04 146 pyrophyllite -6.18 -9.24 -3.06 -0.191 0.52260E+04 147 quartz -2.99 -3.75 -0.76 -0.252 0.12918E+04 151 rhodochrosite -0.98 -4.30 -3.33 -1.109 0.56799E+04 152 rhodonite 7.45 4.75 -2.70 -0.540 0.46072E+04 153 sanidine -1.28 -5.88 -4.60 -0.354 0.78560E+04 155 siderite -2.61 -6.33 -3.72 -1.239 0.63474E+04 156 sillimanite 5.26 2.00 -3.26 -0.326 0.55665E+04 163 stilbite -7.52 -9.20 -1.68 -0.080 0.28685E+04 164 stilpnomelane-Fe 13.02 9.38 -3.64 -0.109 0.62158E+04 168 sudoite 21.08 17.65 -3.43 -0.111 0.58500E+04 174 tephroite 18.09 13.24 -4.85 -0.692 0.82727E+04 177 topaz-H 4.62 2.00 -2.62 -0.238 0.44686E+04 178 tridymite -2.63 -3.75 -1.12 -0.373 0.19117E+04 187 wairakite 3.95 2.04 -1.91 -0.113 0.32691E+04 188 walstromite 11.51 7.53 -3.98 -0.797 0.68006E+04 189 wollastonite 10.46 7.53 -2.93 -0.587 0.50110E+04 190 pseudo-wollastonite 11.00 7.53 -3.47 -0.695 0.59308E+04 191 zoisite 22.85 19.93 -2.92 -0.133 0.49883E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.19 -3.55 -0.219 0.60554E+04 194 beidellite-H -2.33 -7.05 -4.73 -0.302 0.80691E+04 195 beidellite-K -1.52 -6.23 -4.71 -0.288 0.80436E+04 196 beidellite-Mg -1.79 -5.62 -3.83 -0.237 0.65348E+04 197 beidellite-Na -1.34 -5.69 -4.35 -0.266 0.74236E+04 199 chalcedony -2.80 -3.75 -0.94 -0.315 0.16111E+04 201 montmorillonite-Ca -2.29 -5.45 -3.16 -0.196 0.54026E+04 202 montmorillonite-K -2.24 -6.49 -4.26 -0.261 0.72688E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58051E+04 204 montmorillonite-Na -2.04 -5.95 -3.91 -0.240 0.66846E+04 205 nontronite-Ca 3.21 1.63 -1.59 -0.103 0.27111E+04 206 nontronite-H 2.53 -0.23 -2.77 -0.185 0.47227E+04 207 nontronite-K 3.34 0.59 -2.75 -0.177 0.47006E+04 208 nontronite-Mg 3.07 1.20 -1.87 -0.121 0.31977E+04 209 nontronite-Na 3.52 1.13 -2.39 -0.153 0.40823E+04 214 gypsum -4.96 -9.13 -4.18 -1.044 0.71304E+04 224 tobermorite 9.82 5.64 -4.18 -1.140 0.71358E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.47 -3.34 -0.835 0.57046E+04 240 silica-amorphous -2.09 -3.75 -1.65 -0.552 0.28252E+04 242 an20ab80 2.02 -1.48 -3.50 -0.269 0.59790E+04 243 an25ab75 2.65 -0.80 -3.44 -0.265 0.58761E+04 244 an30ab70 3.28 -0.11 -3.39 -0.261 0.57827E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0200000 g New total amount of reactant added: 0.0204000 g Mixing fraction reached given limit of 0.2000E-01 TOTMIX = 0.2040E-01 Execution stopped.