File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.31813E-03 0.13806E-07 0.9589 0.00000000E+00 H2O 2 0. 0.55508E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13796E-03 0.9588 0.00000000E+00 SO4-- 4 -2. 0.26059E-04 0.25268E-04 0.8918 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.12596E-04 0.9588 0.00000000E+00 HS- 6 -1. -0.55427E-06 0.98441E-11 0.9588 0.00000000E+00 Al+++ 7 3. 0.65215E-04 0.21954E-20 0.7901 0.00000000E+00 H4SiO4 8 0. 0.20826E-03 0.17949E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.37474E-04 0.36799E-04 0.8917 0.00000000E+00 Mg++ 10 2. 0.15873E-04 0.97878E-07 0.8916 0.00000000E+00 Fe++ 11 2. 0.14260E-04 0.58093E-09 0.8916 0.00000000E+00 K+ 12 1. 0.42463E-05 0.42447E-05 0.9588 0.00000000E+00 Na+ 13 1. 0.18518E-03 0.18513E-03 0.9588 0.00000000E+00 Mn++ 14 2. 0.34677E-06 0.61217E-07 0.8916 0.00000000E+00 HPO4-- 15 -2. 0.11835E-06 0.92812E-09 0.8918 0.00000000E+00 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.400000E-01 TEMP = 100.0000 SINC = 0.1000E-02 TEMPC = 0.0000 TOTMIX = 0.200000E-01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.0080 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.0000E+00 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.0000E+00 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.0000E+00 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.3907E-07 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.0000E+00 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.0000E+00 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.3154E-05 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.1964E-05 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.5437E-07 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.5132E-04 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.0000E+00 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.0000E+00 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.2218E-05 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.0000E+00 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.0000E+00 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.0000E+00 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.0200000 g log = -1.6990 Original solution: 1000.0103000 g Original solution / Rock added: 50000.51 (Water/Rock Ratio), log = 4.6990 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0200000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3121479E-03 Osmotic coef. = 0.9894 True ionic strength = .3258500E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13806E-07 -7.8599 0.13238E-07 -7.8782 0.95892E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13227E-03 -3.8785 0.95878E+00 -0.0183 4 SO4-- 0.25268E-04 -4.5974 0.22534E-04 -4.6472 0.89182E+00 -0.0497 5 HCO3- 0.12596E-04 -4.8998 0.12077E-04 -4.9180 0.95881E+00 -0.0183 6 HS- 0.98441E-11 -11.0068 0.94383E-11 -11.0251 0.95878E+00 -0.0183 7 Al+++ 0.21954E-20 -20.6585 0.17346E-20 -20.7608 0.79009E+00 -0.1023 8 H4SiO4 0.17949E-03 -3.7460 0.17949E-03 -3.7460 0.10000E+01 0.0000 9 Ca++ 0.36799E-04 -4.4342 0.32813E-04 -4.4840 0.89167E+00 -0.0498 10 Mg++ 0.97878E-07 -7.0093 0.87265E-07 -7.0592 0.89157E+00 -0.0498 11 Fe++ 0.58093E-09 -9.2359 0.51795E-09 -9.2857 0.89159E+00 -0.0498 12 K+ 0.42447E-05 -5.3722 0.40699E-05 -5.3904 0.95882E+00 -0.0183 13 Na+ 0.18513E-03 -3.7325 0.17750E-03 -3.7508 0.95877E+00 -0.0183 14 Mn++ 0.61217E-07 -7.2131 0.54582E-07 -7.2630 0.89161E+00 -0.0498 15 HPO4-- 0.92812E-09 -9.0324 0.82772E-09 -9.0821 0.89182E+00 -0.0497 16 HSiO3- 0.13204E-04 -4.8793 0.12660E-04 -4.8976 0.95878E+00 -0.0183 17 Ca(HSiO3)+ 0.98665E-08 -8.0058 0.94602E-08 -8.0241 0.95882E+00 -0.0183 18 Mg(HSiO3)+ 0.32656E-10 -10.4860 0.31311E-10 -10.5043 0.95882E+00 -0.0183 19 NaHSiO3,aq 0.36343E-07 -7.4396 0.36343E-07 -7.4396 0.10000E+01 0.0000 20 AlO+ 0.14043E-11 -11.8525 0.13465E-11 -11.8708 0.95882E+00 -0.0183 21 AlOH+2 0.99549E-16 -16.0020 0.88760E-16 -16.0518 0.89163E+00 -0.0498 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.35327E-05 -5.4519 0.33870E-05 -5.4702 0.95874E+00 -0.0183 24 CH4,aq 0.49140E-17 -17.3086 0.49135E-17 -17.3086 0.99990E+00 0.0000 29 CO,aq 0.77556E-17 -17.1104 0.77556E-17 -17.1104 0.10000E+01 0.0000 30 CO2,aq 0.34166E-06 -6.4664 0.34162E-06 -6.4665 0.99990E+00 0.0000 31 CO3-2 0.89353E-07 -7.0489 0.79682E-07 -7.0986 0.89177E+00 -0.0497 32 CaCO3,aq 0.32784E-07 -7.4843 0.32784E-07 -7.4843 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10550E-07 -7.9768 0.10115E-07 -7.9950 0.95882E+00 -0.0183 34 CaCl+ 0.73255E-08 -8.1352 0.70238E-08 -8.1534 0.95882E+00 -0.0183 35 CaCl2,aq 0.22073E-12 -12.6561 0.22073E-12 -12.6561 0.10000E+01 0.0000 36 CaOH+ 0.18423E-06 -6.7346 0.17665E-06 -6.7529 0.95882E+00 -0.0183 37 CaSO4,aq 0.23480E-06 -6.6293 0.23480E-06 -6.6293 0.10000E+01 0.0000 38 HCl,aq 0.32088E-12 -12.4937 0.32088E-12 -12.4937 0.10000E+01 0.0000 43 FeCl+ 0.11310E-12 -12.9465 0.10844E-12 -12.9648 0.95882E+00 -0.0183 46 FeO,aq 0.11486E-09 -9.9398 0.11486E-09 -9.9398 0.10000E+01 0.0000 47 FeOH+ 0.13283E-08 -8.8767 0.12736E-08 -8.8950 0.95882E+00 -0.0183 48 HFeO2- 0.94687E-10 -10.0237 0.90784E-10 -10.0420 0.95878E+00 -0.0183 49 FeO+ 0.10539E-12 -12.9772 0.10105E-12 -12.9955 0.95882E+00 -0.0183 50 FeOH+2 0.28651E-18 -18.5429 0.25546E-18 -18.5927 0.89163E+00 -0.0498 51 FeO2- 0.12305E-09 -9.9099 0.11798E-09 -9.9282 0.95878E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.90381E-09 -9.0439 0.90373E-09 -9.0440 0.99990E+00 0.0000 54 KCl,aq 0.97569E-11 -11.0107 0.97569E-11 -11.0107 0.10000E+01 0.0000 55 KHSO4,aq 0.34328E-17 -17.4644 0.34328E-17 -17.4644 0.10000E+01 0.0000 56 KOH,aq 0.13129E-09 -9.8818 0.13129E-09 -9.8818 0.10000E+01 0.0000 57 KSO4- 0.14843E-08 -8.8285 0.14231E-08 -8.8468 0.95878E+00 -0.0183 58 MgCO3,aq 0.21854E-10 -10.6605 0.21854E-10 -10.6605 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28669E-10 -10.5426 0.27488E-10 -10.5609 0.95882E+00 -0.0183 60 MgCl+ 0.17657E-10 -10.7531 0.16930E-10 -10.7713 0.95882E+00 -0.0183 61 MgOH+ 0.27112E-08 -8.5668 0.25996E-08 -8.5851 0.95882E+00 -0.0183 63 MnO,aq 0.32253E-09 -9.4914 0.32253E-09 -9.4914 0.10000E+01 0.0000 64 MnOH+ 0.13003E-07 -7.8860 0.12467E-07 -7.9042 0.95882E+00 -0.0183 65 MnO2-2 0.68488E-16 -16.1644 0.61076E-16 -16.2141 0.89177E+00 -0.0497 66 HMnO2- 0.18476E-12 -12.7334 0.17714E-12 -12.7517 0.95878E+00 -0.0183 69 MnCl+ 0.46368E-10 -10.3338 0.44459E-10 -10.3520 0.95882E+00 -0.0183 70 MnSO4,aq 0.35508E-09 -9.4497 0.35508E-09 -9.4497 0.10000E+01 0.0000 71 NaCl,aq 0.77806E-08 -8.1090 0.77806E-08 -8.1090 0.10000E+01 0.0000 72 NaOH,aq 0.57606E-08 -8.2395 0.57606E-08 -8.2395 0.10000E+01 0.0000 74 OH- 0.45522E-04 -4.3418 0.43644E-04 -4.3601 0.95874E+00 -0.0183 82 H3PO4,aq 0.10146E-14 -14.9937 0.10146E-14 -14.9937 0.10000E+01 0.0000 83 H2PO4- 0.21083E-09 -9.6761 0.20214E-09 -9.6943 0.95880E+00 -0.0183 84 PO4-3 0.64489E-13 -13.1905 0.51013E-13 -13.2923 0.79104E+00 -0.1018 88 HP2O7-3 0.61162E-19 -19.2135 0.48324E-19 -19.3158 0.79010E+00 -0.1023 90 H2S,aq 0.38620E-12 -12.4132 0.38617E-12 -12.4132 0.99990E+00 0.0000 96 SO2,aq 0.15939E-19 -19.7975 0.15939E-19 -19.7975 0.10000E+01 0.0000 97 SO3-2 0.29665E-14 -14.5278 0.26464E-14 -14.5773 0.89209E+00 -0.0496 98 HSO3- 0.22879E-14 -14.6406 0.21936E-14 -14.6588 0.95878E+00 -0.0183 99 HSO4- 0.29983E-09 -9.5231 0.28749E-09 -9.5414 0.95884E+00 -0.0183 101 S2O3-2 0.11463E-18 -18.9407 0.10222E-18 -18.9905 0.89177E+00 -0.0497 Charge balance for all species = 0.2080E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1380559E-07 -.7293966E-04 -.7351651E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999674E+06 0.0000 3 Cl- 0.1379601E-03 0.1379752E-03 0.4891484E+01 3.9996 4 SO4-- 0.2526772E-04 0.2550447E-04 0.2449924E+01 11.1092 5 HCO3- 0.1259571E-04 0.1307010E-04 0.7974762E+00 2.9601 6 HS- 0.9844066E-11 0.1959600E-09 0.6480589E-05 -3.1469 7 Al+++ 0.2195448E-20 0.3552986E-05 0.9586190E-01 2.8737 8 H4SiO4 0.1794872E-03 0.1927374E-03 0.1852446E+02 -3.7460 9 Ca++ 0.3679929E-04 0.3727885E-04 0.1494015E+01 11.2724 10 Mg++ 0.9787787E-07 0.1006900E-06 0.2447898E-02 8.6972 11 Fe++ 0.5809288E-09 0.2440643E-08 0.1362984E-03 6.4706 12 K+ 0.4244692E-05 0.4246317E-05 0.1660343E+00 2.4877 13 Na+ 0.1851274E-03 0.1851773E-03 0.4257057E+01 4.1274 14 Mn++ 0.6121747E-07 0.7494457E-07 0.4117177E-02 8.4934 15 HPO4-- 0.9281188E-09 0.1139010E-08 0.1093176E-03 6.6742 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3181303E-03 -.7293910E-04 -.2451912E-03 0.0000000E+00 2 H2O 0.5550800E+02 0.5550786E+02 0.1381450E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2605874E-04 0.2550427E-04 0.5544641E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542682E-06 0.1959585E-09 -.5544641E-06 0.0000000E+00 7 Al+++ 0.6521483E-04 0.3552958E-05 0.6166187E-04 0.0000000E+00 8 H4SiO4 0.2082557E-03 0.1927360E-03 0.1551970E-04 0.0000000E+00 9 Ca++ 0.3747391E-04 0.3727856E-04 0.1953542E-06 0.0000000E+00 10 Mg++ 0.1587302E-04 0.1006892E-06 0.1577233E-04 0.0000000E+00 11 Fe++ 0.1426017E-04 0.2440625E-08 0.1425773E-04 0.0000000E+00 12 K+ 0.4246285E-05 0.4246285E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1851759E-03 0.1851759E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3467719E-06 0.7494399E-07 0.2718279E-06 0.0000000E+00 15 HPO4-- 0.1183515E-06 0.1139001E-08 0.1172125E-06 0.0000000E+00 Chg. balance for solid moles: -.1869E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0200000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3907E-07 -7.408 0.1963E-04 -4.707 0.2953 0.6236E-05 clinochlore 0.3154E-05 -5.501 0.1753E-02 -2.756 26.38 0.6669E-03 daphnite 0.1964E-05 -5.707 0.1402E-02 -2.853 21.09 0.4247E-03 chlorite-Mn 0.5437E-07 -7.265 0.3854E-04 -4.414 0.5800 0.1228E-04 diaspore 0.5132E-04 -4.290 0.3078E-02 -2.512 46.32 0.9165E-03 hematite 0.2218E-05 -5.654 0.3542E-03 -3.451 5.330 0.6713E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3797E+00 0.3797E+00 1.0000 -0.421 chlorite-Mn 0.1051E-01 0.1051E-01 1.0000 -1.978 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006646 g Volume = 0.002094 cm3 Porosity: 99.7923% V(tot) - V(min): 0.10059E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0200000 g log = -1.6990 Original solution: 1000.0103000 g Original solution / Rock added: 50000.51 (Water/Rock Ratio), log = 4.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3557E-04 1.0071 0.3655E-04 0.3629E-04 CH4,gas 0.7001E-14 1.0125 0.7232E-14 0.7143E-14 H2,gas 0.1162E-05 1.0005 0.1186E-05 0.1186E-05 H2S,gas 0.1045E-10 0.9960 0.1062E-10 0.1066E-10 S2,gas 0.2945E-29 1.0000 0.3005E-29 0.3005E-29 CO,gas 0.1133E-13 1.0000 0.1156E-13 0.1156E-13 SO3,gas 0.1463E-35 1.0000 0.1493E-35 0.1493E-35 SO2,gas 0.6755E-19 1.0000 0.6893E-19 0.6893E-19 HCl,gas 0.5549E-15 1.0000 0.5662E-15 0.5662E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.80 -6.14 -2.045 0.10477E+05 -4.437 3 CH4,gas 4.54 -11.30 -15.84 -3.960 0.27046E+05 -14.141 4 H2,gas 8.00 0.38 -7.62 -4.357 0.13019E+05 -5.926 5 H2S,gas -6.23 -18.90 -12.67 -6.337 0.21639E+05 -10.974 6 S2,gas -7.34 -38.56 -31.22 -4.803 0.53309E+05 -29.522 7 CO,gas 3.21 -12.42 -15.64 -4.811 0.26698E+05 -13.937 8 SO3,gas 17.12 -20.40 -37.52 -9.381 0.64073E+05 -35.826 9 SO2,gas 0.83 -20.03 -20.86 -5.563 0.35619E+05 -19.162 10 HCl,gas 5.19 -11.76 -16.95 -8.473 0.28935E+05 -15.247 11 acmite 7.71 2.92 -4.79 -0.498 0.81808E+04 15 albite-high 0.69 -4.24 -4.93 -0.379 0.84177E+04 16 albite -0.38 -4.24 -3.85 -0.296 0.65789E+04 19 spessartine 24.46 19.99 -4.47 -0.223 0.76285E+04 20 analcite 3.32 -0.49 -3.81 -0.424 0.65102E+04 21 andalusite 5.00 2.00 -3.00 -0.300 0.51226E+04 22 andradite 39.01 35.15 -3.86 -0.201 0.65966E+04 23 grossular 32.73 28.33 -4.40 -0.220 0.75211E+04 24 anhydrite -5.32 -9.13 -3.81 -1.907 0.65128E+04 29 anorthite 12.71 9.53 -3.18 -0.245 0.54340E+04 35 aragonite 0.97 -1.52 -2.49 -0.830 0.42522E+04 36 brucite 12.57 8.70 -3.87 -0.774 0.66103E+04 37 calcite 0.81 -1.52 -2.34 -0.779 0.39880E+04 40 carpholite-Mg 8.58 6.95 -1.63 -0.109 0.27823E+04 41 carpholite-Fe 6.71 4.73 -1.99 -0.132 0.33920E+04 50 chloritoid-Mg 13.20 10.70 -2.50 -0.167 0.42672E+04 51 chloritoid-Fe 9.17 8.47 -0.70 -0.047 0.11979E+04 52 chloritoid-Mn 11.40 10.49 -0.91 -0.060 0.15474E+04 54 coesite -2.38 -3.75 -1.37 -0.457 0.23391E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.75 -1.19 -0.395 0.20244E+04 67 diopside 16.18 12.48 -3.70 -0.370 0.63241E+04 68 hedenbergite 14.21 10.25 -3.96 -0.396 0.67569E+04 75 epidote 24.67 23.34 -1.33 -0.065 0.22754E+04 76 clinozoisite 22.81 19.93 -2.88 -0.131 0.49143E+04 77 epidote-Fe 29.84 26.75 -3.09 -0.161 0.52831E+04 78 fayalite 14.05 9.20 -4.85 -0.693 0.82820E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.92 -4.22 -0.352 0.72048E+04 91 heulandite -5.83 -9.20 -3.37 -0.153 0.57623E+04 95 jadeite 4.22 -0.49 -4.71 -0.471 0.80356E+04 98 kaolinite -1.33 -1.74 -0.41 -0.037 0.70309E+03 99 kyanite 4.88 2.00 -2.87 -0.287 0.49085E+04 101 laumontite 2.88 2.04 -0.85 -0.057 0.14471E+04 102 lawsonite 9.62 9.53 -0.09 -0.006 0.15067E+03 105 lizardite 23.24 18.60 -4.64 -0.387 0.79300E+04 106 magnesite 0.69 -4.10 -4.79 -1.597 0.81782E+04 107 magnetite 20.09 19.04 -1.05 -0.086 0.17939E+04 110 magnesioferrite 26.21 21.26 -4.95 -0.404 0.84504E+04 113 margarite 17.32 15.28 -2.05 -0.082 0.34976E+04 116 microcline -2.49 -5.88 -3.39 -0.261 0.57883E+04 120 muscovite 2.58 -0.13 -2.71 -0.159 0.46298E+04 121 paragonite 4.24 1.51 -2.73 -0.161 0.46595E+04 136 prehnite 19.37 17.05 -2.32 -0.136 0.39573E+04 137 prehnite-Fe 22.50 20.46 -2.03 -0.122 0.34734E+04 138 pumpellyite-Fe 46.27 43.45 -2.82 -0.063 0.48093E+04 139 pumpellyite-Mg 48.99 45.68 -3.32 -0.074 0.56612E+04 145 pyroxmangite 7.40 4.75 -2.65 -0.530 0.45270E+04 146 pyrophyllite -6.18 -9.24 -3.06 -0.191 0.52260E+04 147 quartz -2.99 -3.75 -0.76 -0.252 0.12918E+04 151 rhodochrosite -0.98 -4.30 -3.33 -1.109 0.56799E+04 152 rhodonite 7.45 4.75 -2.70 -0.540 0.46072E+04 153 sanidine -1.28 -5.88 -4.60 -0.354 0.78560E+04 155 siderite -2.61 -6.33 -3.72 -1.239 0.63474E+04 156 sillimanite 5.26 2.00 -3.26 -0.326 0.55665E+04 163 stilbite -7.52 -9.20 -1.68 -0.080 0.28685E+04 164 stilpnomelane-Fe 13.02 9.38 -3.64 -0.109 0.62158E+04 168 sudoite 21.08 17.65 -3.43 -0.111 0.58500E+04 174 tephroite 18.09 13.24 -4.85 -0.692 0.82727E+04 177 topaz-H 4.62 2.00 -2.62 -0.238 0.44686E+04 178 tridymite -2.63 -3.75 -1.12 -0.373 0.19117E+04 187 wairakite 3.95 2.04 -1.91 -0.113 0.32691E+04 188 walstromite 11.51 7.53 -3.98 -0.797 0.68006E+04 189 wollastonite 10.46 7.53 -2.93 -0.587 0.50110E+04 190 pseudo-wollastonite 11.00 7.53 -3.47 -0.695 0.59308E+04 191 zoisite 22.85 19.93 -2.92 -0.133 0.49883E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.19 -3.55 -0.219 0.60554E+04 194 beidellite-H -2.33 -7.05 -4.73 -0.302 0.80691E+04 195 beidellite-K -1.52 -6.23 -4.71 -0.288 0.80436E+04 196 beidellite-Mg -1.79 -5.62 -3.83 -0.237 0.65348E+04 197 beidellite-Na -1.34 -5.69 -4.35 -0.266 0.74236E+04 199 chalcedony -2.80 -3.75 -0.94 -0.315 0.16111E+04 201 montmorillonite-Ca -2.29 -5.45 -3.16 -0.196 0.54026E+04 202 montmorillonite-K -2.24 -6.49 -4.26 -0.261 0.72688E+04 203 montmorillonite-Mg -2.48 -5.88 -3.40 -0.210 0.58051E+04 204 montmorillonite-Na -2.04 -5.95 -3.91 -0.240 0.66846E+04 205 nontronite-Ca 3.21 1.63 -1.59 -0.103 0.27111E+04 206 nontronite-H 2.53 -0.23 -2.77 -0.185 0.47227E+04 207 nontronite-K 3.34 0.59 -2.75 -0.177 0.47006E+04 208 nontronite-Mg 3.07 1.20 -1.87 -0.121 0.31977E+04 209 nontronite-Na 3.52 1.13 -2.39 -0.153 0.40823E+04 214 gypsum -4.96 -9.13 -4.18 -1.044 0.71304E+04 224 tobermorite 9.82 5.64 -4.18 -1.140 0.71358E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.47 -3.34 -0.835 0.57046E+04 240 silica-amorphous -2.09 -3.75 -1.65 -0.552 0.28252E+04 242 an20ab80 2.02 -1.48 -3.50 -0.269 0.59790E+04 243 an25ab75 2.65 -0.80 -3.44 -0.265 0.58761E+04 244 an30ab70 3.28 -0.11 -3.39 -0.261 0.57827E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0200000 g New total amount of reactant added: 0.0210000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0210000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3159002E-03 Osmotic coef. = 0.9894 True ionic strength = .3306194E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13170E-07 -7.8804 0.12627E-07 -7.8987 0.95875E+00 -0.0183 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13225E-03 -3.8786 0.95861E+00 -0.0184 4 SO4-- 0.25261E-04 -4.5975 0.22513E-04 -4.6476 0.89121E+00 -0.0500 5 HCO3- 0.12604E-04 -4.8995 0.12083E-04 -4.9178 0.95865E+00 -0.0183 6 HS- 0.74901E-11 -11.1255 0.71801E-11 -11.1439 0.95861E+00 -0.0184 7 Al+++ 0.19079E-20 -20.7195 0.15051E-20 -20.8224 0.78887E+00 -0.1030 8 H4SiO4 0.18782E-03 -3.7263 0.18782E-03 -3.7263 0.10000E+01 0.0000 9 Ca++ 0.37914E-04 -4.4212 0.33783E-04 -4.4713 0.89105E+00 -0.0501 10 Mg++ 0.86710E-07 -7.0619 0.77255E-07 -7.1121 0.89095E+00 -0.0501 11 Fe++ 0.51416E-09 -9.2889 0.45810E-09 -9.3390 0.89098E+00 -0.0501 12 K+ 0.44569E-05 -5.3510 0.42726E-05 -5.3693 0.95865E+00 -0.0183 13 Na+ 0.18638E-03 -3.7296 0.17866E-03 -3.7480 0.95861E+00 -0.0184 14 Mn++ 0.55991E-07 -7.2519 0.49888E-07 -7.3020 0.89100E+00 -0.0501 15 HPO4-- 0.83063E-09 -9.0806 0.74027E-09 -9.1306 0.89121E+00 -0.0500 16 HSiO3- 0.14489E-04 -4.8390 0.13889E-04 -4.8573 0.95861E+00 -0.0184 17 Ca(HSiO3)+ 0.11147E-07 -7.9529 0.10686E-07 -7.9712 0.95866E+00 -0.0183 18 Mg(HSiO3)+ 0.31723E-10 -10.4986 0.30411E-10 -10.5170 0.95866E+00 -0.0183 19 NaHSiO3,aq 0.40135E-07 -7.3965 0.40135E-07 -7.3965 0.10000E+01 0.0000 20 AlO+ 0.13397E-11 -11.8730 0.12843E-11 -11.8913 0.95866E+00 -0.0183 21 AlOH+2 0.90622E-16 -16.0428 0.80746E-16 -16.0929 0.89102E+00 -0.0501 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.37045E-05 -5.4313 0.35511E-05 -5.4496 0.95857E+00 -0.0184 24 CH4,aq 0.37437E-17 -17.4267 0.37433E-17 -17.4267 0.99990E+00 0.0000 29 CO,aq 0.69957E-17 -17.1552 0.69957E-17 -17.1552 0.10000E+01 0.0000 30 CO2,aq 0.32602E-06 -6.4867 0.32599E-06 -6.4868 0.99990E+00 0.0000 31 CO3-2 0.93792E-07 -7.0278 0.83584E-07 -7.0779 0.89116E+00 -0.0500 32 CaCO3,aq 0.35406E-07 -7.4509 0.35406E-07 -7.4509 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10869E-07 -7.9638 0.10419E-07 -7.9822 0.95866E+00 -0.0183 34 CaCl+ 0.75421E-08 -8.1225 0.72303E-08 -8.1408 0.95866E+00 -0.0183 35 CaCl2,aq 0.22717E-12 -12.6436 0.22717E-12 -12.6436 0.10000E+01 0.0000 36 CaOH+ 0.19891E-06 -6.7013 0.19068E-06 -6.7197 0.95866E+00 -0.0183 37 CaSO4,aq 0.24151E-06 -6.6171 0.24151E-06 -6.6171 0.10000E+01 0.0000 38 HCl,aq 0.30600E-12 -12.5143 0.30600E-12 -12.5143 0.10000E+01 0.0000 43 FeCl+ 0.10003E-12 -12.9999 0.95895E-13 -13.0182 0.95866E+00 -0.0183 46 FeO,aq 0.11168E-09 -9.9520 0.11168E-09 -9.9520 0.10000E+01 0.0000 47 FeOH+ 0.12319E-08 -8.9094 0.11810E-08 -8.9278 0.95866E+00 -0.0183 48 HFeO2- 0.96536E-10 -10.0153 0.92541E-10 -10.0337 0.95861E+00 -0.0184 49 FeO+ 0.10053E-12 -12.9977 0.96377E-13 -13.0160 0.95866E+00 -0.0183 50 FeOH+2 0.26082E-18 -18.5837 0.23240E-18 -18.6338 0.89102E+00 -0.0501 51 FeO2- 0.12904E-09 -9.8893 0.12370E-09 -9.9076 0.95861E+00 -0.0184 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.85434E-09 -9.0684 0.85425E-09 -9.0684 0.99990E+00 0.0000 54 KCl,aq 0.10241E-10 -10.9896 0.10241E-10 -10.9896 0.10000E+01 0.0000 55 KHSO4,aq 0.34340E-17 -17.4642 0.34340E-17 -17.4642 0.10000E+01 0.0000 56 KOH,aq 0.14451E-09 -9.8401 0.14451E-09 -9.8401 0.10000E+01 0.0000 57 KSO4- 0.15571E-08 -8.8077 0.14926E-08 -8.8260 0.95861E+00 -0.0184 58 MgCO3,aq 0.20295E-10 -10.6926 0.20295E-10 -10.6926 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25397E-10 -10.5952 0.24347E-10 -10.6136 0.95866E+00 -0.0183 60 MgCl+ 0.15632E-10 -10.8060 0.14986E-10 -10.8243 0.95866E+00 -0.0183 61 MgOH+ 0.25170E-08 -8.5991 0.24129E-08 -8.6175 0.95866E+00 -0.0183 63 MnO,aq 0.32405E-09 -9.4894 0.32405E-09 -9.4894 0.10000E+01 0.0000 64 MnOH+ 0.12463E-07 -7.9044 0.11947E-07 -7.9227 0.95866E+00 -0.0183 65 MnO2-2 0.75693E-16 -16.1209 0.67455E-16 -16.1710 0.89116E+00 -0.0500 66 HMnO2- 0.19466E-12 -12.7107 0.18660E-12 -12.7291 0.95861E+00 -0.0184 69 MnCl+ 0.42380E-10 -10.3728 0.40628E-10 -10.3912 0.95866E+00 -0.0183 70 MnSO4,aq 0.32423E-09 -9.4891 0.32423E-09 -9.4891 0.10000E+01 0.0000 71 NaCl,aq 0.78305E-08 -8.1062 0.78305E-08 -8.1062 0.10000E+01 0.0000 72 NaOH,aq 0.60795E-08 -8.2161 0.60795E-08 -8.2161 0.10000E+01 0.0000 74 OH- 0.47736E-04 -4.3212 0.45758E-04 -4.3395 0.95857E+00 -0.0184 82 H3PO4,aq 0.82544E-15 -15.0833 0.82544E-15 -15.0833 0.10000E+01 0.0000 83 H2PO4- 0.17987E-09 -9.7450 0.17243E-09 -9.7634 0.95863E+00 -0.0183 84 PO4-3 0.60562E-13 -13.2178 0.47834E-13 -13.3203 0.78983E+00 -0.1025 88 HP2O7-3 0.46732E-19 -19.3304 0.36866E-19 -19.4334 0.78888E+00 -0.1030 90 H2S,aq 0.28022E-12 -12.5525 0.28020E-12 -12.5525 0.99990E+00 0.0000 96 SO2,aq 0.13693E-19 -19.8635 0.13693E-19 -19.8635 0.10000E+01 0.0000 97 SO3-2 0.28034E-14 -14.5523 0.24991E-14 -14.6022 0.89148E+00 -0.0499 98 HSO3- 0.20611E-14 -14.6859 0.19758E-14 -14.7043 0.95861E+00 -0.0184 99 HSO4- 0.28575E-09 -9.5440 0.27395E-09 -9.5623 0.95868E+00 -0.0183 101 S2O3-2 0.83149E-19 -19.0801 0.74099E-19 -19.1302 0.89116E+00 -0.0500 Charge balance for all species = 0.2080E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1316981E-07 -.7716844E-04 -.7777866E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999664E+06 0.0000 3 Cl- 0.1379599E-03 0.1379753E-03 0.4891481E+01 4.0201 4 SO4-- 0.2526099E-04 0.2550450E-04 0.2449924E+01 11.1499 5 HCO3- 0.1260397E-04 0.1307011E-04 0.7974756E+00 2.9809 6 HS- 0.7490103E-11 0.1803836E-09 0.5965455E-05 -3.2452 7 Al+++ 0.1907857E-20 0.3724803E-05 0.1004975E+00 2.8737 8 H4SiO4 0.1878183E-03 0.2023585E-03 0.1944915E+02 -3.7263 9 Ca++ 0.3791355E-04 0.3841894E-04 0.1539705E+01 11.3261 10 Mg++ 0.8671007E-07 0.8932009E-07 0.2171480E-02 8.6854 11 Fe++ 0.5141599E-09 0.2282165E-08 0.1274480E-03 6.4584 12 K+ 0.4456923E-05 0.4458635E-05 0.1743359E+00 2.5294 13 Na+ 0.1863786E-03 0.1864326E-03 0.4285911E+01 4.1508 14 Mn++ 0.5599114E-07 0.6914465E-07 0.3798547E-02 8.4954 15 HPO4-- 0.8306301E-09 0.1010560E-08 0.9698942E-04 6.6668 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3346888E-03 -.7716781E-04 -.2575210E-03 0.0000000E+00 2 H2O 0.5550799E+02 0.5550784E+02 0.1450744E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2608645E-04 0.2550429E-04 0.5821620E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5819816E-06 0.1803821E-09 -.5821620E-06 0.0000000E+00 7 Al+++ 0.6847557E-04 0.3724773E-05 0.6475080E-04 0.0000000E+00 8 H4SiO4 0.2186684E-03 0.2023569E-03 0.1631155E-04 0.0000000E+00 9 Ca++ 0.3862406E-04 0.3841862E-04 0.2054309E-06 0.0000000E+00 10 Mg++ 0.1666667E-04 0.8931937E-07 0.1657735E-04 0.0000000E+00 11 Fe++ 0.1497318E-04 0.2282147E-08 0.1497090E-04 0.0000000E+00 12 K+ 0.4458599E-05 0.4458599E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1864311E-03 0.1864311E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3641105E-06 0.6914410E-07 0.2949664E-06 0.0000000E+00 15 HPO4-- 0.1242691E-06 0.1010552E-08 0.1232586E-06 0.0000000E+00 Chg. balance for solid moles: 0.6353E-21 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0210000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4109E-07 -7.386 0.2064E-04 -4.685 0.2956 0.6558E-05 clinochlore 0.3315E-05 -5.479 0.1843E-02 -2.735 26.40 0.7010E-03 daphnite 0.2063E-05 -5.686 0.1472E-02 -2.832 21.08 0.4460E-03 chlorite-Mn 0.5899E-07 -7.229 0.4182E-04 -4.379 0.5991 0.1333E-04 diaspore 0.5388E-04 -4.269 0.3232E-02 -2.491 46.30 0.9622E-03 hematite 0.2329E-05 -5.633 0.3719E-03 -3.430 5.327 0.7049E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3794E+00 0.3794E+00 1.0000 -0.421 chlorite-Mn 0.1085E-01 0.1085E-01 1.0000 -1.965 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006981 g Volume = 0.002200 cm3 Porosity: 99.7819% V(tot) - V(min): 0.10062E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0210000 g log = -1.6778 Original solution: 1000.0103000 g Original solution / Rock added: 47619.54 (Water/Rock Ratio), log = 4.6778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3394E-04 1.0071 0.3488E-04 0.3463E-04 CH4,gas 0.5333E-14 1.0125 0.5510E-14 0.5442E-14 H2,gas 0.1099E-05 1.0005 0.1122E-05 0.1121E-05 H2S,gas 0.7579E-11 0.9960 0.7702E-11 0.7733E-11 S2,gas 0.1735E-29 1.0000 0.1770E-29 0.1770E-29 CO,gas 0.1022E-13 1.0000 0.1042E-13 0.1042E-13 SO3,gas 0.1330E-35 1.0000 0.1357E-35 0.1357E-35 SO2,gas 0.5803E-19 1.0000 0.5921E-19 0.5921E-19 HCl,gas 0.5292E-15 1.0000 0.5399E-15 0.5399E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.84059E+01 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.82 -6.16 -2.052 0.10512E+05 -4.457 3 CH4,gas 4.54 -11.41 -15.96 -3.989 0.27248E+05 -14.259 4 H2,gas 8.00 0.35 -7.65 -4.371 0.13061E+05 -5.950 5 H2S,gas -6.23 -19.04 -12.81 -6.406 0.21877E+05 -11.113 6 S2,gas -7.34 -38.79 -31.45 -4.839 0.53702E+05 -29.752 7 CO,gas 3.21 -12.47 -15.68 -4.825 0.26775E+05 -13.982 8 SO3,gas 17.12 -20.44 -37.57 -9.392 0.64144E+05 -35.867 9 SO2,gas 0.83 -20.09 -20.93 -5.580 0.35731E+05 -19.228 10 HCl,gas 5.19 -11.78 -16.97 -8.483 0.28970E+05 -15.268 11 acmite 7.71 2.98 -4.73 -0.491 0.80736E+04 15 albite-high 0.69 -4.15 -4.85 -0.373 0.82768E+04 16 albite -0.38 -4.15 -3.77 -0.290 0.64380E+04 19 spessartine 24.46 20.05 -4.40 -0.220 0.75171E+04 20 analcite 3.32 -0.43 -3.75 -0.417 0.64029E+04 21 andalusite 5.00 2.02 -2.98 -0.298 0.50889E+04 22 andradite 39.01 35.37 -3.64 -0.189 0.62203E+04 23 grossular 32.73 28.55 -4.18 -0.209 0.71448E+04 24 anhydrite -5.32 -9.12 -3.80 -1.901 0.64919E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52749E+04 35 aragonite 0.97 -1.49 -2.46 -0.819 0.41952E+04 36 brucite 12.57 8.69 -3.88 -0.777 0.66305E+04 37 calcite 0.81 -1.49 -2.30 -0.767 0.39309E+04 40 carpholite-Mg 8.58 6.98 -1.60 -0.107 0.27351E+04 41 carpholite-Fe 6.71 4.75 -1.96 -0.131 0.33456E+04 50 chloritoid-Mg 13.20 10.71 -2.49 -0.166 0.42537E+04 51 chloritoid-Fe 9.17 8.48 -0.69 -0.046 0.11852E+04 52 chloritoid-Mn 11.40 10.52 -0.88 -0.059 0.15103E+04 54 coesite -2.38 -3.73 -1.35 -0.450 0.23054E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.73 -1.17 -0.389 0.19908E+04 67 diopside 16.18 12.56 -3.62 -0.362 0.61852E+04 68 hedenbergite 14.21 10.33 -3.88 -0.388 0.66186E+04 75 epidote 24.67 23.50 -1.17 -0.057 0.19909E+04 76 clinozoisite 22.81 20.09 -2.71 -0.123 0.46298E+04 77 epidote-Fe 29.84 26.91 -2.93 -0.152 0.49986E+04 78 fayalite 14.05 9.19 -4.86 -0.694 0.82901E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.92 -4.22 -0.351 0.72002E+04 91 heulandite -5.83 -9.01 -3.18 -0.145 0.54350E+04 95 jadeite 4.22 -0.43 -4.64 -0.464 0.79284E+04 98 kaolinite -1.33 -1.71 -0.37 -0.034 0.63580E+03 99 kyanite 4.88 2.02 -2.86 -0.286 0.48748E+04 101 laumontite 2.88 2.17 -0.71 -0.048 0.12207E+04 105 lizardite 23.24 18.60 -4.64 -0.387 0.79232E+04 106 magnesite 0.69 -4.13 -4.82 -1.607 0.82331E+04 107 magnetite 20.09 19.02 -1.06 -0.087 0.18147E+04 110 magnesioferrite 26.21 21.25 -4.96 -0.405 0.84705E+04 113 margarite 17.32 15.37 -1.96 -0.078 0.33385E+04 116 microcline -2.49 -5.78 -3.29 -0.253 0.56162E+04 120 muscovite 2.58 -0.03 -2.61 -0.154 0.44577E+04 121 paragonite 4.24 1.59 -2.65 -0.156 0.45186E+04 136 prehnite 19.37 17.22 -2.15 -0.127 0.36728E+04 137 prehnite-Fe 22.50 20.63 -1.87 -0.112 0.31889E+04 138 pumpellyite-Fe 46.27 43.77 -2.50 -0.055 0.42612E+04 139 pumpellyite-Mg 48.99 46.00 -2.99 -0.067 0.51124E+04 145 pyroxmangite 7.40 4.77 -2.63 -0.526 0.44898E+04 146 pyrophyllite -6.18 -9.16 -2.98 -0.186 0.50914E+04 147 quartz -2.99 -3.73 -0.74 -0.246 0.12581E+04 151 rhodochrosite -0.98 -4.32 -3.34 -1.115 0.57112E+04 152 rhodonite 7.45 4.77 -2.68 -0.535 0.45701E+04 153 sanidine -1.28 -5.78 -4.50 -0.346 0.76839E+04 155 siderite -2.61 -6.36 -3.75 -1.250 0.64030E+04 156 sillimanite 5.26 2.02 -3.24 -0.324 0.55329E+04 163 stilbite -7.52 -9.01 -1.49 -0.071 0.25412E+04 164 stilpnomelane-Fe 13.02 9.49 -3.52 -0.105 0.60154E+04 168 sudoite 21.08 17.69 -3.39 -0.109 0.57894E+04 174 tephroite 18.09 13.26 -4.82 -0.689 0.82321E+04 177 topaz-H 4.62 2.02 -2.60 -0.236 0.44349E+04 178 tridymite -2.63 -3.73 -1.10 -0.367 0.18781E+04 187 wairakite 3.95 2.17 -1.78 -0.105 0.30427E+04 188 walstromite 11.51 7.60 -3.91 -0.782 0.66751E+04 189 wollastonite 10.46 7.60 -2.86 -0.572 0.48856E+04 190 pseudo-wollastonite 11.00 7.60 -3.40 -0.680 0.58054E+04 191 zoisite 22.85 20.09 -2.75 -0.125 0.47038E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.11 -3.47 -0.214 0.59168E+04 194 beidellite-H -2.33 -6.98 -4.65 -0.297 0.79456E+04 195 beidellite-K -1.52 -6.14 -4.62 -0.283 0.78966E+04 196 beidellite-Mg -1.79 -5.55 -3.76 -0.232 0.64146E+04 197 beidellite-Na -1.34 -5.61 -4.27 -0.261 0.72870E+04 199 chalcedony -2.80 -3.73 -0.92 -0.308 0.15774E+04 201 montmorillonite-Ca -2.29 -5.37 -3.08 -0.191 0.52595E+04 202 montmorillonite-K -2.24 -6.41 -4.17 -0.255 0.71174E+04 203 montmorillonite-Mg -2.48 -5.81 -3.33 -0.206 0.56805E+04 204 montmorillonite-Na -2.04 -5.87 -3.83 -0.235 0.65435E+04 205 nontronite-Ca 3.21 1.71 -1.51 -0.098 0.25725E+04 206 nontronite-H 2.53 -0.16 -2.69 -0.181 0.45992E+04 207 nontronite-K 3.34 0.67 -2.67 -0.171 0.45536E+04 208 nontronite-Mg 3.07 1.27 -1.80 -0.117 0.30776E+04 209 nontronite-Na 3.52 1.21 -2.31 -0.148 0.39457E+04 214 gypsum -4.96 -9.12 -4.16 -1.041 0.71095E+04 224 tobermorite 9.82 5.71 -4.11 -1.123 0.70257E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.46 -3.35 -0.838 0.57255E+04 240 silica-amorphous -2.09 -3.73 -1.63 -0.545 0.27916E+04 242 an20ab80 2.02 -1.40 -3.42 -0.263 0.58345E+04 243 an25ab75 2.65 -0.71 -3.36 -0.258 0.57306E+04 244 an30ab70 3.28 -0.02 -3.30 -0.254 0.56363E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0210000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3156139E-03 Osmotic coef. = 0.9894 True ionic strength = .3302778E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13213E-07 -7.8790 0.12668E-07 -7.8973 0.95876E+00 -0.0183 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13225E-03 -3.8786 0.95862E+00 -0.0184 4 SO4-- 0.25262E-04 -4.5975 0.22515E-04 -4.6475 0.89125E+00 -0.0500 5 HCO3- 0.12603E-04 -4.8995 0.12082E-04 -4.9178 0.95866E+00 -0.0183 6 HS- 0.75504E-11 -11.1220 0.72380E-11 -11.1404 0.95863E+00 -0.0184 7 Al+++ 0.19264E-20 -20.7153 0.15199E-20 -20.8182 0.78896E+00 -0.1029 8 H4SiO4 0.18765E-03 -3.7267 0.18765E-03 -3.7267 0.10000E+01 0.0000 9 Ca++ 0.37799E-04 -4.4225 0.33683E-04 -4.4726 0.89110E+00 -0.0501 10 Mg++ 0.87321E-07 -7.0589 0.77803E-07 -7.1090 0.89100E+00 -0.0501 11 Fe++ 0.51780E-09 -9.2858 0.46137E-09 -9.3359 0.89102E+00 -0.0501 12 K+ 0.44569E-05 -5.3510 0.42727E-05 -5.3693 0.95866E+00 -0.0183 13 Na+ 0.18638E-03 -3.7296 0.17867E-03 -3.7480 0.95862E+00 -0.0184 14 Mn++ 0.56319E-07 -7.2493 0.50182E-07 -7.2995 0.89104E+00 -0.0501 15 HPO4-- 0.83836E-09 -9.0766 0.74719E-09 -9.1266 0.89126E+00 -0.0500 16 HSiO3- 0.14428E-04 -4.8408 0.13831E-04 -4.8591 0.95862E+00 -0.0184 17 Ca(HSiO3)+ 0.11067E-07 -7.9560 0.10610E-07 -7.9743 0.95867E+00 -0.0183 18 Mg(HSiO3)+ 0.31815E-10 -10.4974 0.30500E-10 -10.5157 0.95867E+00 -0.0183 19 NaHSiO3,aq 0.39968E-07 -7.3983 0.39968E-07 -7.3983 0.10000E+01 0.0000 20 AlO+ 0.13440E-11 -11.8716 0.12885E-11 -11.8899 0.95867E+00 -0.0183 21 AlOH+2 0.91211E-16 -16.0400 0.81274E-16 -16.0900 0.89106E+00 -0.0501 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.36924E-05 -5.4327 0.35395E-05 -5.4511 0.95858E+00 -0.0184 24 CH4,aq 0.37735E-17 -17.4233 0.37731E-17 -17.4233 0.99990E+00 0.0000 29 CO,aq 0.70266E-17 -17.1533 0.70266E-17 -17.1533 0.10000E+01 0.0000 30 CO2,aq 0.32708E-06 -6.4853 0.32705E-06 -6.4854 0.99990E+00 0.0000 31 CO3-2 0.93480E-07 -7.0293 0.83310E-07 -7.0793 0.89121E+00 -0.0500 32 CaCO3,aq 0.35185E-07 -7.4536 0.35185E-07 -7.4536 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10836E-07 -7.9651 0.10388E-07 -7.9835 0.95867E+00 -0.0183 34 CaCl+ 0.75197E-08 -8.1238 0.72089E-08 -8.1421 0.95867E+00 -0.0183 35 CaCl2,aq 0.22650E-12 -12.6449 0.22650E-12 -12.6449 0.10000E+01 0.0000 36 CaOH+ 0.19767E-06 -6.7041 0.18950E-06 -6.7224 0.95867E+00 -0.0183 37 CaSO4,aq 0.24081E-06 -6.6183 0.24081E-06 -6.6183 0.10000E+01 0.0000 38 HCl,aq 0.30700E-12 -12.5129 0.30700E-12 -12.5129 0.10000E+01 0.0000 43 FeCl+ 0.10074E-12 -12.9968 0.96580E-13 -13.0151 0.95867E+00 -0.0183 46 FeO,aq 0.11174E-09 -9.9518 0.11174E-09 -9.9518 0.10000E+01 0.0000 47 FeOH+ 0.12366E-08 -8.9078 0.11855E-08 -8.9261 0.95867E+00 -0.0183 48 HFeO2- 0.96277E-10 -10.0165 0.92294E-10 -10.0348 0.95862E+00 -0.0184 49 FeO+ 0.10086E-12 -12.9963 0.96692E-13 -13.0146 0.95867E+00 -0.0183 50 FeOH+2 0.26251E-18 -18.5808 0.23392E-18 -18.6309 0.89106E+00 -0.0501 51 FeO2- 0.12861E-09 -9.8907 0.12329E-09 -9.9091 0.95862E+00 -0.0184 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.85534E-09 -9.0679 0.85526E-09 -9.0679 0.99990E+00 0.0000 54 KCl,aq 0.10241E-10 -10.9896 0.10241E-10 -10.9896 0.10000E+01 0.0000 55 KHSO4,aq 0.34455E-17 -17.4627 0.34455E-17 -17.4627 0.10000E+01 0.0000 56 KOH,aq 0.14404E-09 -9.8415 0.14404E-09 -9.8415 0.10000E+01 0.0000 57 KSO4- 0.15572E-08 -8.8077 0.14928E-08 -8.8260 0.95862E+00 -0.0184 58 MgCO3,aq 0.20372E-10 -10.6910 0.20372E-10 -10.6910 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25576E-10 -10.5922 0.24519E-10 -10.6105 0.95867E+00 -0.0183 60 MgCl+ 0.15743E-10 -10.8029 0.15092E-10 -10.8212 0.95867E+00 -0.0183 61 MgOH+ 0.25266E-08 -8.5975 0.24221E-08 -8.6158 0.95867E+00 -0.0183 63 MnO,aq 0.32384E-09 -9.4897 0.32384E-09 -9.4897 0.10000E+01 0.0000 64 MnOH+ 0.12495E-07 -7.9033 0.11979E-07 -7.9216 0.95867E+00 -0.0183 65 MnO2-2 0.75149E-16 -16.1241 0.66974E-16 -16.1741 0.89121E+00 -0.0500 66 HMnO2- 0.19390E-12 -12.7124 0.18587E-12 -12.7308 0.95862E+00 -0.0184 69 MnCl+ 0.42630E-10 -10.3703 0.40868E-10 -10.3886 0.95867E+00 -0.0183 70 MnSO4,aq 0.32617E-09 -9.4866 0.32617E-09 -9.4866 0.10000E+01 0.0000 71 NaCl,aq 0.78307E-08 -8.1062 0.78307E-08 -8.1062 0.10000E+01 0.0000 72 NaOH,aq 0.60597E-08 -8.2175 0.60597E-08 -8.2175 0.10000E+01 0.0000 74 OH- 0.47580E-04 -4.3226 0.45610E-04 -4.3409 0.95858E+00 -0.0184 82 H3PO4,aq 0.83861E-15 -15.0764 0.83861E-15 -15.0764 0.10000E+01 0.0000 83 H2PO4- 0.18214E-09 -9.7396 0.17461E-09 -9.7579 0.95865E+00 -0.0183 84 PO4-3 0.60923E-13 -13.2152 0.48124E-13 -13.3176 0.78991E+00 -0.1024 88 HP2O7-3 0.47761E-19 -19.3209 0.37682E-19 -19.4239 0.78897E+00 -0.1029 90 H2S,aq 0.28341E-12 -12.5476 0.28338E-12 -12.5476 0.99990E+00 0.0000 96 SO2,aq 0.13800E-19 -19.8601 0.13800E-19 -19.8601 0.10000E+01 0.0000 97 SO3-2 0.28067E-14 -14.5518 0.25023E-14 -14.6017 0.89152E+00 -0.0499 98 HSO3- 0.20704E-14 -14.6840 0.19847E-14 -14.7023 0.95862E+00 -0.0184 99 HSO4- 0.28671E-09 -9.5426 0.27486E-09 -9.5609 0.95869E+00 -0.0183 101 S2O3-2 0.84095E-19 -19.0752 0.74946E-19 -19.1252 0.89121E+00 -0.0500 Charge balance for all species = 0.2081E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1321266E-07 -.7690032E-04 -.7750842E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999664E+06 0.0000 3 Cl- 0.1379599E-03 0.1379753E-03 0.4891481E+01 4.0187 4 SO4-- 0.2526169E-04 0.2550450E-04 0.2449924E+01 11.1471 5 HCO3- 0.1260348E-04 0.1307011E-04 0.7974757E+00 2.9795 6 HS- 0.7550385E-11 0.1807503E-09 0.5977583E-05 -3.2431 7 Al+++ 0.1926400E-20 0.3712697E-05 0.1001709E+00 2.8737 8 H4SiO4 0.1876460E-03 0.2021253E-03 0.1942673E+02 -3.7267 9 Ca++ 0.3779897E-04 0.3830206E-04 0.1535021E+01 11.3220 10 Mg++ 0.8732113E-07 0.8994119E-07 0.2186580E-02 8.6856 11 Fe++ 0.5178021E-09 0.2289927E-08 0.1278814E-03 6.4586 12 K+ 0.4456923E-05 0.4458635E-05 0.1743359E+00 2.5280 13 Na+ 0.1863788E-03 0.1864326E-03 0.4285911E+01 4.1493 14 Mn++ 0.5631863E-07 0.6950667E-07 0.3818435E-02 8.4951 15 HPO4-- 0.8383590E-09 0.1020563E-08 0.9794943E-04 6.6680 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3346888E-03 -.7689970E-04 -.2577891E-03 0.0000000E+00 2 H2O 0.5550799E+02 0.5550784E+02 0.1448644E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2608645E-04 0.2550429E-04 0.5821623E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5819816E-06 0.1807489E-09 -.5821623E-06 0.0000000E+00 7 Al+++ 0.6847557E-04 0.3712667E-05 0.6476291E-04 0.0000000E+00 8 H4SiO4 0.2186684E-03 0.2021237E-03 0.1654474E-04 0.0000000E+00 9 Ca++ 0.3862406E-04 0.3830175E-04 0.3223095E-06 0.0000000E+00 10 Mg++ 0.1666667E-04 0.8994046E-07 0.1657673E-04 0.0000000E+00 11 Fe++ 0.1497318E-04 0.2289908E-08 0.1497089E-04 0.0000000E+00 12 K+ 0.4458599E-05 0.4458599E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1864311E-03 0.1864311E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3641105E-06 0.6950611E-07 0.2946044E-06 0.0000000E+00 15 HPO4-- 0.1242691E-06 0.1020554E-08 0.1232486E-06 0.0000000E+00 Chg. balance for solid moles: -.5717E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0210000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4108E-07 -7.386 0.2064E-04 -4.685 0.2946 0.6558E-05 clinochlore 0.3315E-05 -5.479 0.1843E-02 -2.735 26.31 0.7009E-03 daphnite 0.2063E-05 -5.686 0.1472E-02 -2.832 21.01 0.4460E-03 chlorite-Mn 0.5892E-07 -7.230 0.4177E-04 -4.379 0.5964 0.1331E-04 diaspore 0.5366E-04 -4.270 0.3219E-02 -2.492 45.95 0.9583E-03 hematite 0.2329E-05 -5.633 0.3719E-03 -3.430 5.309 0.7049E-04 lawsonite 0.1169E-06 -6.932 0.3673E-04 -4.435 0.5244 0.1185E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3794E+00 0.3794E+00 1.0000 -0.421 chlorite-Mn 0.1084E-01 0.1084E-01 1.0000 -1.965 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.007004 g Volume = 0.002207 cm3 Porosity: 99.7811% V(tot) - V(min): 0.10062E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0210000 g log = -1.6778 Original solution: 1000.0103000 g Original solution / Rock added: 47619.54 (Water/Rock Ratio), log = 4.6778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3405E-04 1.0071 0.3499E-04 0.3474E-04 CH4,gas 0.5376E-14 1.0125 0.5554E-14 0.5485E-14 H2,gas 0.1100E-05 1.0005 0.1123E-05 0.1122E-05 H2S,gas 0.7665E-11 0.9960 0.7790E-11 0.7821E-11 S2,gas 0.1771E-29 1.0000 0.1807E-29 0.1807E-29 CO,gas 0.1026E-13 1.0000 0.1047E-13 0.1047E-13 SO3,gas 0.1339E-35 1.0000 0.1366E-35 0.1366E-35 SO2,gas 0.5849E-19 1.0000 0.5968E-19 0.5968E-19 HCl,gas 0.5309E-15 1.0000 0.5417E-15 0.5417E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.82 -6.16 -2.052 0.10510E+05 -4.456 3 CH4,gas 4.54 -11.41 -15.95 -3.989 0.27242E+05 -14.255 4 H2,gas 8.00 0.35 -7.65 -4.371 0.13060E+05 -5.950 5 H2S,gas -6.23 -19.04 -12.81 -6.404 0.21868E+05 -11.108 6 S2,gas -7.34 -38.78 -31.44 -4.837 0.53687E+05 -29.743 7 CO,gas 3.21 -12.46 -15.68 -4.824 0.26771E+05 -13.980 8 SO3,gas 17.12 -20.44 -37.56 -9.391 0.64139E+05 -35.865 9 SO2,gas 0.83 -20.09 -20.92 -5.580 0.35726E+05 -19.224 10 HCl,gas 5.19 -11.78 -16.97 -8.483 0.28968E+05 -15.266 11 acmite 7.71 2.98 -4.73 -0.491 0.80774E+04 15 albite-high 0.69 -4.16 -4.85 -0.373 0.82812E+04 16 albite -0.38 -4.16 -3.77 -0.290 0.64424E+04 19 spessartine 24.46 20.05 -4.40 -0.220 0.75205E+04 20 analcite 3.32 -0.43 -3.75 -0.417 0.64067E+04 21 andalusite 5.00 2.02 -2.98 -0.298 0.50896E+04 22 andradite 39.01 35.35 -3.66 -0.190 0.62435E+04 23 grossular 32.73 28.53 -4.20 -0.210 0.71680E+04 24 anhydrite -5.32 -9.12 -3.80 -1.902 0.64941E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.49 -2.46 -0.820 0.41998E+04 36 brucite 12.57 8.69 -3.88 -0.777 0.66301E+04 37 calcite 0.81 -1.49 -2.30 -0.768 0.39356E+04 40 carpholite-Mg 8.58 6.98 -1.60 -0.107 0.27361E+04 41 carpholite-Fe 6.71 4.75 -1.96 -0.131 0.33465E+04 50 chloritoid-Mg 13.20 10.71 -2.49 -0.166 0.42540E+04 51 chloritoid-Fe 9.17 8.48 -0.69 -0.046 0.11854E+04 52 chloritoid-Mn 11.40 10.52 -0.89 -0.059 0.15114E+04 54 coesite -2.38 -3.73 -1.35 -0.450 0.23061E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.73 -1.17 -0.389 0.19915E+04 67 diopside 16.18 12.55 -3.63 -0.363 0.61932E+04 68 hedenbergite 14.21 10.33 -3.88 -0.388 0.66266E+04 75 epidote 24.67 23.49 -1.18 -0.057 0.20070E+04 76 clinozoisite 22.81 20.09 -2.72 -0.124 0.46459E+04 77 epidote-Fe 29.84 26.90 -2.94 -0.153 0.50147E+04 78 fayalite 14.05 9.19 -4.86 -0.694 0.82899E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.92 -4.22 -0.351 0.72002E+04 91 heulandite -5.83 -9.02 -3.19 -0.145 0.54468E+04 95 jadeite 4.22 -0.43 -4.65 -0.465 0.79322E+04 98 kaolinite -1.33 -1.71 -0.37 -0.034 0.63716E+03 99 kyanite 4.88 2.02 -2.86 -0.286 0.48755E+04 101 laumontite 2.88 2.16 -0.72 -0.048 0.12305E+04 105 lizardite 23.24 18.60 -4.64 -0.387 0.79233E+04 106 magnesite 0.69 -4.13 -4.82 -1.607 0.82303E+04 107 magnetite 20.09 19.02 -1.06 -0.087 0.18143E+04 110 magnesioferrite 26.21 21.25 -4.96 -0.405 0.84701E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.78 -3.29 -0.253 0.56206E+04 120 muscovite 2.58 -0.03 -2.61 -0.154 0.44622E+04 121 paragonite 4.24 1.59 -2.65 -0.156 0.45231E+04 136 prehnite 19.37 17.21 -2.16 -0.127 0.36889E+04 137 prehnite-Fe 22.50 20.62 -1.88 -0.113 0.32050E+04 138 pumpellyite-Fe 46.27 43.76 -2.51 -0.056 0.42930E+04 139 pumpellyite-Mg 48.99 45.98 -3.01 -0.067 0.51442E+04 145 pyroxmangite 7.40 4.77 -2.63 -0.526 0.44910E+04 146 pyrophyllite -6.18 -9.16 -2.98 -0.186 0.50942E+04 147 quartz -2.99 -3.73 -0.74 -0.246 0.12588E+04 151 rhodochrosite -0.98 -4.32 -3.34 -1.115 0.57092E+04 152 rhodonite 7.45 4.77 -2.68 -0.535 0.45712E+04 153 sanidine -1.28 -5.78 -4.50 -0.346 0.76884E+04 155 siderite -2.61 -6.36 -3.75 -1.249 0.64002E+04 156 sillimanite 5.26 2.02 -3.24 -0.324 0.55336E+04 163 stilbite -7.52 -9.02 -1.50 -0.071 0.25530E+04 164 stilpnomelane-Fe 13.02 9.49 -3.53 -0.105 0.60199E+04 168 sudoite 21.08 17.69 -3.39 -0.109 0.57907E+04 174 tephroite 18.09 13.26 -4.82 -0.689 0.82337E+04 177 topaz-H 4.62 2.02 -2.60 -0.236 0.44356E+04 178 tridymite -2.63 -3.73 -1.10 -0.367 0.18788E+04 187 wairakite 3.95 2.16 -1.79 -0.105 0.30525E+04 188 walstromite 11.51 7.60 -3.91 -0.783 0.66829E+04 189 wollastonite 10.46 7.60 -2.87 -0.573 0.48933E+04 190 pseudo-wollastonite 11.00 7.60 -3.40 -0.681 0.58131E+04 191 zoisite 22.85 20.09 -2.76 -0.126 0.47200E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.11 -3.47 -0.215 0.59205E+04 194 beidellite-H -2.33 -6.98 -4.65 -0.297 0.79481E+04 195 beidellite-K -1.52 -6.15 -4.63 -0.283 0.78999E+04 196 beidellite-Mg -1.79 -5.55 -3.76 -0.232 0.64171E+04 197 beidellite-Na -1.34 -5.61 -4.27 -0.261 0.72903E+04 199 chalcedony -2.80 -3.73 -0.92 -0.308 0.15781E+04 201 montmorillonite-Ca -2.29 -5.37 -3.08 -0.191 0.52632E+04 202 montmorillonite-K -2.24 -6.41 -4.17 -0.255 0.71208E+04 203 montmorillonite-Mg -2.48 -5.81 -3.33 -0.206 0.56830E+04 204 montmorillonite-Na -2.04 -5.87 -3.83 -0.235 0.65469E+04 205 nontronite-Ca 3.21 1.71 -1.51 -0.098 0.25762E+04 206 nontronite-H 2.53 -0.16 -2.70 -0.181 0.46017E+04 207 nontronite-K 3.34 0.67 -2.67 -0.171 0.45569E+04 208 nontronite-Mg 3.07 1.27 -1.80 -0.117 0.30800E+04 209 nontronite-Na 3.52 1.21 -2.31 -0.148 0.39490E+04 214 gypsum -4.96 -9.12 -4.17 -1.041 0.71117E+04 224 tobermorite 9.82 5.70 -4.12 -1.124 0.70322E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.46 -3.35 -0.838 0.57250E+04 240 silica-amorphous -2.09 -3.73 -1.64 -0.545 0.27923E+04 242 an20ab80 2.02 -1.40 -3.42 -0.263 0.58398E+04 243 an25ab75 2.65 -0.71 -3.36 -0.258 0.57361E+04 244 an30ab70 3.28 -0.03 -3.30 -0.254 0.56420E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0210000 g New total amount of reactant added: 0.0220000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0220000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3141122E-03 Osmotic coef. = 0.9894 True ionic strength = .3287817E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13397E-07 -7.8730 0.12846E-07 -7.8912 0.95882E+00 -0.0183 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13226E-03 -3.8786 0.95868E+00 -0.0183 4 SO4-- 0.25268E-04 -4.5974 0.22525E-04 -4.6473 0.89144E+00 -0.0499 5 HCO3- 0.12602E-04 -4.8996 0.12082E-04 -4.9179 0.95871E+00 -0.0183 6 HS- 0.67160E-11 -11.1729 0.64385E-11 -11.1912 0.95868E+00 -0.0183 7 Al+++ 0.20077E-20 -20.6973 0.15848E-20 -20.8000 0.78934E+00 -0.1027 8 H4SiO4 0.19280E-03 -3.7149 0.19280E-03 -3.7149 0.10000E+01 0.0000 9 Ca++ 0.36810E-04 -4.4340 0.32809E-04 -4.4840 0.89129E+00 -0.0500 10 Mg++ 0.88323E-07 -7.0539 0.78713E-07 -7.1040 0.89119E+00 -0.0500 11 Fe++ 0.52366E-09 -9.2810 0.46669E-09 -9.3310 0.89121E+00 -0.0500 12 K+ 0.46692E-05 -5.3308 0.44764E-05 -5.3491 0.95871E+00 -0.0183 13 Na+ 0.18763E-03 -3.7267 0.17988E-03 -3.7450 0.95867E+00 -0.0183 14 Mn++ 0.57361E-07 -7.2414 0.51122E-07 -7.2914 0.89123E+00 -0.0500 15 HPO4-- 0.89215E-09 -9.0496 0.79530E-09 -9.0995 0.89145E+00 -0.0499 16 HSiO3- 0.14618E-04 -4.8351 0.14014E-04 -4.8534 0.95868E+00 -0.0183 17 Ca(HSiO3)+ 0.10922E-07 -7.9617 0.10471E-07 -7.9800 0.95872E+00 -0.0183 18 Mg(HSiO3)+ 0.32611E-10 -10.4866 0.31264E-10 -10.5049 0.95872E+00 -0.0183 19 NaHSiO3,aq 0.40772E-07 -7.3896 0.40772E-07 -7.3896 0.10000E+01 0.0000 20 AlO+ 0.13628E-11 -11.8656 0.13066E-11 -11.8839 0.95872E+00 -0.0183 21 AlOH+2 0.93770E-16 -16.0279 0.83573E-16 -16.0779 0.89125E+00 -0.0500 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.36411E-05 -5.4388 0.34905E-05 -5.4571 0.95863E+00 -0.0183 24 CH4,aq 0.33549E-17 -17.4743 0.33546E-17 -17.4744 0.99990E+00 0.0000 29 CO,aq 0.68944E-17 -17.1615 0.68944E-17 -17.1615 0.10000E+01 0.0000 30 CO2,aq 0.33165E-06 -6.4793 0.33162E-06 -6.4794 0.99990E+00 0.0000 31 CO3-2 0.92159E-07 -7.0355 0.82150E-07 -7.0854 0.89140E+00 -0.0499 32 CaCO3,aq 0.33795E-07 -7.4711 0.33795E-07 -7.4711 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10554E-07 -7.9766 0.10118E-07 -7.9949 0.95872E+00 -0.0183 34 CaCl+ 0.73246E-08 -8.1352 0.70223E-08 -8.1535 0.95872E+00 -0.0183 35 CaCl2,aq 0.22065E-12 -12.6563 0.22065E-12 -12.6563 0.10000E+01 0.0000 36 CaOH+ 0.18986E-06 -6.7216 0.18203E-06 -6.7399 0.95872E+00 -0.0183 37 CaSO4,aq 0.23467E-06 -6.6295 0.23467E-06 -6.6295 0.10000E+01 0.0000 38 HCl,aq 0.31133E-12 -12.5068 0.31133E-12 -12.5068 0.10000E+01 0.0000 43 FeCl+ 0.10191E-12 -12.9918 0.97698E-13 -13.0101 0.95872E+00 -0.0183 46 FeO,aq 0.10992E-09 -9.9589 0.10992E-09 -9.9589 0.10000E+01 0.0000 47 FeOH+ 0.12335E-08 -8.9089 0.11826E-08 -8.9272 0.95872E+00 -0.0183 48 HFeO2- 0.93392E-10 -10.0297 0.89532E-10 -10.0480 0.95868E+00 -0.0183 49 FeO+ 0.10227E-12 -12.9902 0.98050E-13 -13.0086 0.95872E+00 -0.0183 50 FeOH+2 0.26988E-18 -18.5688 0.24053E-18 -18.6188 0.89125E+00 -0.0500 51 FeO2- 0.12683E-09 -9.8968 0.12159E-09 -9.9151 0.95868E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.82769E-09 -9.0821 0.82761E-09 -9.0822 0.99990E+00 0.0000 54 KCl,aq 0.10730E-10 -10.9694 0.10730E-10 -10.9694 0.10000E+01 0.0000 55 KHSO4,aq 0.36621E-17 -17.4363 0.36621E-17 -17.4363 0.10000E+01 0.0000 56 KOH,aq 0.14882E-09 -9.8273 0.14882E-09 -9.8273 0.10000E+01 0.0000 57 KSO4- 0.16321E-08 -8.7873 0.15646E-08 -8.8056 0.95868E+00 -0.0183 58 MgCO3,aq 0.20323E-10 -10.6920 0.20323E-10 -10.6920 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25872E-10 -10.5872 0.24804E-10 -10.6055 0.95872E+00 -0.0183 60 MgCl+ 0.15927E-10 -10.7979 0.15269E-10 -10.8162 0.95872E+00 -0.0183 61 MgOH+ 0.25206E-08 -8.5985 0.24165E-08 -8.6168 0.95872E+00 -0.0183 63 MnO,aq 0.32084E-09 -9.4937 0.32084E-09 -9.4937 0.10000E+01 0.0000 64 MnOH+ 0.12552E-07 -7.9013 0.12034E-07 -7.9196 0.95872E+00 -0.0183 65 MnO2-2 0.72388E-16 -16.1403 0.64527E-16 -16.1903 0.89140E+00 -0.0499 66 HMnO2- 0.18942E-12 -12.7226 0.18160E-12 -12.7409 0.95868E+00 -0.0183 69 MnCl+ 0.43429E-10 -10.3622 0.41636E-10 -10.3805 0.95872E+00 -0.0183 70 MnSO4,aq 0.33243E-09 -9.4783 0.33243E-09 -9.4783 0.10000E+01 0.0000 71 NaCl,aq 0.78842E-08 -8.1032 0.78842E-08 -8.1032 0.10000E+01 0.0000 72 NaOH,aq 0.60164E-08 -8.2207 0.60164E-08 -8.2207 0.10000E+01 0.0000 74 OH- 0.46919E-04 -4.3287 0.44978E-04 -4.3470 0.95863E+00 -0.0183 82 H3PO4,aq 0.91785E-15 -15.0372 0.91785E-15 -15.0372 0.10000E+01 0.0000 83 H2PO4- 0.19658E-09 -9.7065 0.18846E-09 -9.7248 0.95870E+00 -0.0183 84 PO4-3 0.63918E-13 -13.1944 0.50513E-13 -13.2966 0.79029E+00 -0.1022 88 HP2O7-3 0.54843E-19 -19.2609 0.43290E-19 -19.3636 0.78935E+00 -0.1027 90 H2S,aq 0.25564E-12 -12.5924 0.25562E-12 -12.5924 0.99990E+00 0.0000 96 SO2,aq 0.13738E-19 -19.8621 0.13738E-19 -19.8621 0.10000E+01 0.0000 97 SO3-2 0.27167E-14 -14.5660 0.24225E-14 -14.6157 0.89171E+00 -0.0498 98 HSO3- 0.20324E-14 -14.6920 0.19484E-14 -14.7103 0.95868E+00 -0.0183 99 HSO4- 0.29085E-09 -9.5363 0.27885E-09 -9.5546 0.95874E+00 -0.0183 101 S2O3-2 0.75875E-19 -19.1199 0.67635E-19 -19.1698 0.89140E+00 -0.0499 Charge balance for all species = 0.2013E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1339749E-07 -.7620902E-04 -.7681161E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999659E+06 0.0000 3 Cl- 0.1379601E-03 0.1379753E-03 0.4891480E+01 4.0127 4 SO4-- 0.2526775E-04 0.2550451E-04 0.2449924E+01 11.1351 5 HCO3- 0.1260191E-04 0.1307011E-04 0.7974755E+00 2.9734 6 HS- 0.6716010E-11 0.1731985E-09 0.5727832E-05 -3.3000 7 Al+++ 0.2007728E-20 0.3661368E-05 0.9878597E-01 2.8737 8 H4SiO4 0.1927982E-03 0.2074683E-03 0.1994025E+02 -3.7149 9 Ca++ 0.3681046E-04 0.3729759E-04 0.1494764E+01 11.2985 10 Mg++ 0.8832313E-07 0.9093843E-07 0.2210823E-02 8.6785 11 Fe++ 0.5236566E-09 0.2286152E-08 0.1276706E-03 6.4515 12 K+ 0.4669160E-05 0.4670952E-05 0.1826376E+00 2.5422 13 Na+ 0.1876333E-03 0.1876879E-03 0.4314767E+01 4.1462 14 Mn++ 0.5736122E-07 0.7061042E-07 0.3879069E-02 8.4911 15 HPO4-- 0.8921490E-09 0.1088795E-08 0.1044981E-03 6.6830 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3512473E-03 -.7620838E-04 -.2750390E-03 0.0000000E+00 2 H2O 0.5550797E+02 0.5550783E+02 0.1479425E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2611416E-04 0.2550430E-04 0.6098682E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6096950E-06 0.1731970E-09 -.6098682E-06 0.0000000E+00 7 Al+++ 0.7173632E-04 0.3661337E-05 0.6807498E-04 0.0000000E+00 8 H4SiO4 0.2290812E-03 0.2074666E-03 0.2161462E-04 0.0000000E+00 9 Ca++ 0.3977420E-04 0.3729728E-04 0.2476921E-05 0.0000000E+00 10 Mg++ 0.1746032E-04 0.9093767E-07 0.1736938E-04 0.0000000E+00 11 Fe++ 0.1568619E-04 0.2286133E-08 0.1568390E-04 0.0000000E+00 12 K+ 0.4670913E-05 0.4670913E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1876864E-03 0.1876864E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3814491E-06 0.7060983E-07 0.3108393E-06 0.0000000E+00 15 HPO4-- 0.1301867E-06 0.1088786E-08 0.1290979E-06 0.0000000E+00 Chg. balance for solid moles: 0.7200E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0220000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4303E-07 -7.366 0.2162E-04 -4.665 0.2783 0.6869E-05 clinochlore 0.3474E-05 -5.459 0.1931E-02 -2.714 24.86 0.7345E-03 daphnite 0.2161E-05 -5.665 0.1542E-02 -2.812 19.85 0.4672E-03 chlorite-Mn 0.6217E-07 -7.206 0.4408E-04 -4.356 0.5674 0.1405E-04 diaspore 0.5216E-04 -4.283 0.3129E-02 -2.505 40.28 0.9315E-03 hematite 0.2439E-05 -5.613 0.3896E-03 -3.409 5.015 0.7384E-04 lawsonite 0.2262E-05 -5.646 0.7107E-03 -3.148 9.150 0.2292E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3793E+00 0.3793E+00 1.0000 -0.421 chlorite-Mn 0.1091E-01 0.1091E-01 1.0000 -1.962 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.007768 g Volume = 0.002457 cm3 Porosity: 99.7564% V(tot) - V(min): 0.10063E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0220000 g log = -1.6576 Original solution: 1000.0103000 g Original solution / Rock added: 45455.01 (Water/Rock Ratio), log = 4.6576 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3453E-04 1.0071 0.3548E-04 0.3523E-04 CH4,gas 0.4779E-14 1.0125 0.4938E-14 0.4877E-14 H2,gas 0.1064E-05 1.0005 0.1087E-05 0.1086E-05 H2S,gas 0.6914E-11 0.9960 0.7027E-11 0.7055E-11 S2,gas 0.1539E-29 1.0000 0.1570E-29 0.1570E-29 CO,gas 0.1007E-13 1.0000 0.1027E-13 0.1027E-13 SO3,gas 0.1377E-35 1.0000 0.1405E-35 0.1405E-35 SO2,gas 0.5822E-19 1.0000 0.5941E-19 0.5941E-19 HCl,gas 0.5384E-15 1.0000 0.5493E-15 0.5493E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.81 -6.15 -2.050 0.10499E+05 -4.450 3 CH4,gas 4.54 -11.46 -16.01 -4.001 0.27329E+05 -14.306 4 H2,gas 8.00 0.34 -7.66 -4.379 0.13084E+05 -5.964 5 H2S,gas -6.23 -19.08 -12.85 -6.426 0.21945E+05 -11.153 6 S2,gas -7.34 -38.84 -31.50 -4.847 0.53791E+05 -29.804 7 CO,gas 3.21 -12.47 -15.69 -4.827 0.26786E+05 -13.988 8 SO3,gas 17.12 -20.43 -37.55 -9.388 0.64118E+05 -35.852 9 SO2,gas 0.83 -20.09 -20.93 -5.580 0.35729E+05 -19.226 10 HCl,gas 5.19 -11.77 -16.96 -8.480 0.28957E+05 -15.260 11 acmite 7.71 3.00 -4.71 -0.489 0.80425E+04 15 albite-high 0.69 -4.12 -4.82 -0.371 0.82263E+04 16 albite -0.38 -4.12 -3.74 -0.288 0.63875E+04 19 spessartine 24.46 20.08 -4.38 -0.219 0.74810E+04 20 analcite 3.32 -0.41 -3.73 -0.415 0.63718E+04 21 andalusite 5.00 2.03 -2.97 -0.297 0.50695E+04 22 andradite 39.01 35.32 -3.69 -0.192 0.63037E+04 23 grossular 32.73 28.50 -4.23 -0.212 0.72283E+04 24 anhydrite -5.32 -9.13 -3.81 -1.907 0.65132E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.51 -2.48 -0.826 0.42297E+04 36 brucite 12.57 8.68 -3.89 -0.778 0.66421E+04 37 calcite 0.81 -1.51 -2.32 -0.774 0.39655E+04 40 carpholite-Mg 8.58 7.00 -1.59 -0.106 0.27080E+04 41 carpholite-Fe 6.71 4.77 -1.94 -0.130 0.33185E+04 50 chloritoid-Mg 13.20 10.71 -2.49 -0.166 0.42459E+04 51 chloritoid-Fe 9.17 8.48 -0.69 -0.046 0.11775E+04 52 chloritoid-Mn 11.40 10.52 -0.88 -0.058 0.14983E+04 54 coesite -2.38 -3.71 -1.34 -0.446 0.22860E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.71 -1.15 -0.385 0.19714E+04 67 diopside 16.18 12.55 -3.63 -0.363 0.62052E+04 68 hedenbergite 14.21 10.32 -3.89 -0.389 0.66388E+04 75 epidote 24.67 23.48 -1.19 -0.058 0.20271E+04 76 clinozoisite 22.81 20.07 -2.73 -0.124 0.46660E+04 77 epidote-Fe 29.84 26.89 -2.95 -0.153 0.50348E+04 78 fayalite 14.05 9.19 -4.86 -0.694 0.82942E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.92 -4.21 -0.351 0.71966E+04 91 heulandite -5.83 -8.96 -3.13 -0.142 0.53464E+04 95 jadeite 4.22 -0.41 -4.63 -0.463 0.78973E+04 98 kaolinite -1.33 -1.68 -0.35 -0.032 0.59699E+03 99 kyanite 4.88 2.03 -2.84 -0.284 0.48554E+04 101 laumontite 2.88 2.19 -0.70 -0.046 0.11903E+04 105 lizardite 23.24 18.61 -4.64 -0.387 0.79194E+04 106 magnesite 0.69 -4.13 -4.82 -1.607 0.82321E+04 107 magnetite 20.09 19.02 -1.07 -0.087 0.18265E+04 110 magnesioferrite 26.21 21.24 -4.97 -0.406 0.84822E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.73 -3.24 -0.249 0.55362E+04 120 muscovite 2.58 0.02 -2.56 -0.151 0.43777E+04 121 paragonite 4.24 1.62 -2.62 -0.154 0.44681E+04 136 prehnite 19.37 17.20 -2.17 -0.128 0.37090E+04 137 prehnite-Fe 22.50 20.61 -1.89 -0.114 0.32251E+04 138 pumpellyite-Fe 46.27 43.72 -2.54 -0.057 0.43454E+04 139 pumpellyite-Mg 48.99 45.95 -3.04 -0.068 0.51964E+04 145 pyroxmangite 7.40 4.78 -2.62 -0.524 0.44778E+04 146 pyrophyllite -6.18 -9.11 -2.94 -0.184 0.50138E+04 147 quartz -2.99 -3.71 -0.73 -0.242 0.12387E+04 151 rhodochrosite -0.98 -4.32 -3.34 -1.114 0.57059E+04 152 rhodonite 7.45 4.78 -2.67 -0.534 0.45581E+04 153 sanidine -1.28 -5.73 -4.45 -0.343 0.76039E+04 155 siderite -2.61 -6.36 -3.75 -1.250 0.64021E+04 156 sillimanite 5.26 2.03 -3.23 -0.323 0.55135E+04 163 stilbite -7.52 -8.96 -1.44 -0.068 0.24525E+04 164 stilpnomelane-Fe 13.02 9.56 -3.46 -0.103 0.59080E+04 168 sudoite 21.08 17.71 -3.37 -0.109 0.57545E+04 174 tephroite 18.09 13.27 -4.82 -0.688 0.82275E+04 177 topaz-H 4.62 2.03 -2.59 -0.235 0.44155E+04 178 tridymite -2.63 -3.71 -1.09 -0.363 0.18587E+04 187 wairakite 3.95 2.19 -1.76 -0.104 0.30123E+04 188 walstromite 11.51 7.58 -3.93 -0.785 0.67029E+04 189 wollastonite 10.46 7.58 -2.88 -0.576 0.49134E+04 190 pseudo-wollastonite 11.00 7.58 -3.42 -0.683 0.58332E+04 191 zoisite 22.85 20.07 -2.78 -0.126 0.47400E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.07 -3.43 -0.212 0.58534E+04 194 beidellite-H -2.33 -6.94 -4.61 -0.294 0.78744E+04 195 beidellite-K -1.52 -6.10 -4.58 -0.280 0.78182E+04 196 beidellite-Mg -1.79 -5.51 -3.72 -0.230 0.63453E+04 197 beidellite-Na -1.34 -5.57 -4.23 -0.259 0.72183E+04 199 chalcedony -2.80 -3.71 -0.91 -0.304 0.15580E+04 201 montmorillonite-Ca -2.29 -5.33 -3.04 -0.188 0.51935E+04 202 montmorillonite-K -2.24 -6.36 -4.12 -0.252 0.70364E+04 203 montmorillonite-Mg -2.48 -5.76 -3.28 -0.203 0.56086E+04 204 montmorillonite-Na -2.04 -5.83 -3.79 -0.232 0.64723E+04 205 nontronite-Ca 3.21 1.75 -1.47 -0.095 0.25091E+04 206 nontronite-H 2.53 -0.12 -2.65 -0.178 0.45280E+04 207 nontronite-K 3.34 0.72 -2.62 -0.168 0.44752E+04 208 nontronite-Mg 3.07 1.31 -1.76 -0.114 0.30083E+04 209 nontronite-Na 3.52 1.25 -2.27 -0.146 0.38770E+04 214 gypsum -4.96 -9.13 -4.18 -1.044 0.71308E+04 224 tobermorite 9.82 5.70 -4.13 -1.126 0.70456E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.45 -3.36 -0.840 0.57372E+04 240 silica-amorphous -2.09 -3.71 -1.62 -0.541 0.27722E+04 242 an20ab80 2.02 -1.38 -3.39 -0.261 0.57958E+04 243 an25ab75 2.65 -0.69 -3.34 -0.257 0.56949E+04 244 an30ab70 3.28 0.00 -3.28 -0.252 0.56035E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0220000 g New total amount of reactant added: 0.0230000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0230000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3126665E-03 Osmotic coef. = 0.9894 True ionic strength = .3273492E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13577E-07 -7.8672 0.13019E-07 -7.8854 0.95886E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13227E-03 -3.8786 0.95872E+00 -0.0183 4 SO4-- 0.25274E-04 -4.5973 0.22535E-04 -4.6471 0.89163E+00 -0.0498 5 HCO3- 0.12600E-04 -4.8996 0.12081E-04 -4.9179 0.95876E+00 -0.0183 6 HS- 0.59855E-11 -11.2229 0.57385E-11 -11.2412 0.95873E+00 -0.0183 7 Al+++ 0.20889E-20 -20.6801 0.16496E-20 -20.7826 0.78971E+00 -0.1025 8 H4SiO4 0.19799E-03 -3.7034 0.19799E-03 -3.7034 0.10000E+01 0.0000 9 Ca++ 0.35843E-04 -4.4456 0.31953E-04 -4.4955 0.89147E+00 -0.0499 10 Mg++ 0.89261E-07 -7.0493 0.79565E-07 -7.0993 0.89137E+00 -0.0499 11 Fe++ 0.52913E-09 -9.2764 0.47167E-09 -9.3264 0.89140E+00 -0.0499 12 K+ 0.48814E-05 -5.3115 0.46801E-05 -5.3297 0.95876E+00 -0.0183 13 Na+ 0.18889E-03 -3.7238 0.18109E-03 -3.7421 0.95872E+00 -0.0183 14 Mn++ 0.58347E-07 -7.2340 0.52012E-07 -7.2839 0.89141E+00 -0.0499 15 HPO4-- 0.94888E-09 -9.0228 0.84605E-09 -9.0726 0.89163E+00 -0.0498 16 HSiO3- 0.14812E-04 -4.8294 0.14201E-04 -4.8477 0.95872E+00 -0.0183 17 Ca(HSiO3)+ 0.10778E-07 -7.9675 0.10334E-07 -7.9857 0.95877E+00 -0.0183 18 Mg(HSiO3)+ 0.33400E-10 -10.4762 0.32023E-10 -10.4945 0.95877E+00 -0.0183 19 NaHSiO3,aq 0.41592E-07 -7.3810 0.41592E-07 -7.3810 0.10000E+01 0.0000 20 AlO+ 0.13811E-11 -11.8598 0.13241E-11 -11.8781 0.95877E+00 -0.0183 21 AlOH+2 0.96290E-16 -16.0164 0.85836E-16 -16.0663 0.89144E+00 -0.0499 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.35926E-05 -5.4446 0.34442E-05 -5.4629 0.95868E+00 -0.0183 24 CH4,aq 0.29886E-17 -17.5245 0.29883E-17 -17.5246 0.99990E+00 0.0000 29 CO,aq 0.67651E-17 -17.1697 0.67651E-17 -17.1697 0.10000E+01 0.0000 30 CO2,aq 0.33609E-06 -6.4735 0.33605E-06 -6.4736 0.99990E+00 0.0000 31 CO3-2 0.90910E-07 -7.0414 0.81054E-07 -7.0912 0.89158E+00 -0.0498 32 CaCO3,aq 0.32475E-07 -7.4885 0.32475E-07 -7.4885 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10277E-07 -7.9881 0.98534E-08 -8.0064 0.95877E+00 -0.0183 34 CaCl+ 0.71336E-08 -8.1467 0.68395E-08 -8.1650 0.95877E+00 -0.0183 35 CaCl2,aq 0.21492E-12 -12.6677 0.21492E-12 -12.6677 0.10000E+01 0.0000 36 CaOH+ 0.18245E-06 -6.7389 0.17493E-06 -6.7571 0.95877E+00 -0.0183 37 CaSO4,aq 0.22865E-06 -6.6408 0.22865E-06 -6.6408 0.10000E+01 0.0000 38 HCl,aq 0.31553E-12 -12.5010 0.31553E-12 -12.5010 0.10000E+01 0.0000 43 FeCl+ 0.10299E-12 -12.9872 0.98746E-13 -13.0055 0.95877E+00 -0.0183 46 FeO,aq 0.10816E-09 -9.9659 0.10816E-09 -9.9659 0.10000E+01 0.0000 47 FeOH+ 0.12301E-08 -8.9101 0.11793E-08 -8.9284 0.95877E+00 -0.0183 48 HFeO2- 0.90674E-10 -10.0425 0.86932E-10 -10.0608 0.95872E+00 -0.0183 49 FeO+ 0.10364E-12 -12.9845 0.99369E-13 -13.0027 0.95877E+00 -0.0183 50 FeOH+2 0.27713E-18 -18.5573 0.24705E-18 -18.6072 0.89144E+00 -0.0499 51 FeO2- 0.12514E-09 -9.9026 0.11997E-09 -9.9209 0.95872E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.80144E-09 -9.0961 0.80136E-09 -9.0962 0.99990E+00 0.0000 54 KCl,aq 0.11219E-10 -10.9500 0.11219E-10 -10.9500 0.10000E+01 0.0000 55 KHSO4,aq 0.38820E-17 -17.4109 0.38820E-17 -17.4109 0.10000E+01 0.0000 56 KOH,aq 0.15353E-09 -9.8138 0.15353E-09 -9.8138 0.10000E+01 0.0000 57 KSO4- 0.17070E-08 -8.7678 0.16366E-08 -8.7861 0.95872E+00 -0.0183 58 MgCO3,aq 0.20269E-10 -10.6932 0.20269E-10 -10.6932 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26149E-10 -10.5825 0.25071E-10 -10.6008 0.95877E+00 -0.0183 60 MgCl+ 0.16099E-10 -10.7932 0.15436E-10 -10.8115 0.95877E+00 -0.0183 61 MgOH+ 0.25139E-08 -8.5997 0.24103E-08 -8.6179 0.95877E+00 -0.0183 63 MnO,aq 0.31781E-09 -9.4978 0.31781E-09 -9.4978 0.10000E+01 0.0000 64 MnOH+ 0.12601E-07 -7.8996 0.12081E-07 -7.9179 0.95877E+00 -0.0183 65 MnO2-2 0.69800E-16 -16.1561 0.62233E-16 -16.2060 0.89158E+00 -0.0498 66 HMnO2- 0.18514E-12 -12.7325 0.17750E-12 -12.7508 0.95872E+00 -0.0183 69 MnCl+ 0.44184E-10 -10.3547 0.42363E-10 -10.3730 0.95877E+00 -0.0183 70 MnSO4,aq 0.33837E-09 -9.4706 0.33837E-09 -9.4706 0.10000E+01 0.0000 71 NaCl,aq 0.79378E-08 -8.1003 0.79378E-08 -8.1003 0.10000E+01 0.0000 72 NaOH,aq 0.59765E-08 -8.2236 0.59765E-08 -8.2236 0.10000E+01 0.0000 74 OH- 0.46294E-04 -4.3345 0.44381E-04 -4.3528 0.95868E+00 -0.0183 82 H3PO4,aq 0.10029E-14 -14.9988 0.10029E-14 -14.9988 0.10000E+01 0.0000 83 H2PO4- 0.21193E-09 -9.6738 0.20318E-09 -9.6921 0.95875E+00 -0.0183 84 PO4-3 0.67063E-13 -13.1735 0.53023E-13 -13.2755 0.79065E+00 -0.1020 88 HP2O7-3 0.62870E-19 -19.2016 0.49650E-19 -19.3041 0.78972E+00 -0.1025 90 H2S,aq 0.23091E-12 -12.6366 0.23089E-12 -12.6366 0.99990E+00 0.0000 96 SO2,aq 0.13668E-19 -19.8643 0.13668E-19 -19.8643 0.10000E+01 0.0000 97 SO3-2 0.26311E-14 -14.5799 0.23467E-14 -14.6295 0.89190E+00 -0.0497 98 HSO3- 0.19952E-14 -14.7000 0.19128E-14 -14.7183 0.95872E+00 -0.0183 99 HSO4- 0.29488E-09 -9.5304 0.28272E-09 -9.5486 0.95879E+00 -0.0183 101 S2O3-2 0.68552E-19 -19.1640 0.61119E-19 -19.2138 0.89158E+00 -0.0498 Charge balance for all species = 0.2013E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1357702E-07 -.7556944E-04 -.7616695E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999654E+06 0.0000 3 Cl- 0.1379602E-03 0.1379754E-03 0.4891479E+01 4.0069 4 SO4-- 0.2527369E-04 0.2550452E-04 0.2449924E+01 11.1237 5 HCO3- 0.1260032E-04 0.1307011E-04 0.7974753E+00 2.9675 6 HS- 0.5985539E-11 0.1660925E-09 0.5492828E-05 -3.3558 7 Al+++ 0.2088878E-20 0.3612850E-05 0.9747690E-01 2.8737 8 H4SiO4 0.1979904E-03 0.2128548E-03 0.2045795E+02 -3.7034 9 Ca++ 0.3584314E-04 0.3631490E-04 0.1455381E+01 11.2754 10 Mg++ 0.8926094E-07 0.9187076E-07 0.2233488E-02 8.6716 11 Fe++ 0.5291341E-09 0.2282017E-08 0.1274396E-03 6.4445 12 K+ 0.4881397E-05 0.4883269E-05 0.1909393E+00 2.5557 13 Na+ 0.1888877E-03 0.1889432E-03 0.4343623E+01 4.1433 14 Mn++ 0.5834737E-07 0.7164850E-07 0.3936095E-02 8.4870 15 HPO4-- 0.9488809E-09 0.1160876E-08 0.1114161E-03 6.6983 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3678059E-03 -.7556879E-04 -.2922371E-03 0.0000000E+00 2 H2O 0.5550796E+02 0.5550781E+02 0.1510586E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2614188E-04 0.2550430E-04 0.6375745E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6374084E-06 0.1660910E-09 -.6375745E-06 0.0000000E+00 7 Al+++ 0.7499706E-04 0.3612819E-05 0.7138424E-04 0.0000000E+00 8 H4SiO4 0.2394940E-03 0.2128530E-03 0.2664102E-04 0.0000000E+00 9 Ca++ 0.4092434E-04 0.3631459E-04 0.4609750E-05 0.0000000E+00 10 Mg++ 0.1825397E-04 0.9186997E-07 0.1816210E-04 0.0000000E+00 11 Fe++ 0.1639920E-04 0.2281998E-08 0.1639692E-04 0.0000000E+00 12 K+ 0.4883227E-05 0.4883227E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1889416E-03 0.1889416E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3987877E-06 0.7164788E-07 0.3271398E-06 0.0000000E+00 15 HPO4-- 0.1361043E-06 0.1160866E-08 0.1349434E-06 0.0000000E+00 Chg. balance for solid moles: 0.2255E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0230000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4498E-07 -7.347 0.2259E-04 -4.646 0.2650 0.7180E-05 clinochlore 0.3632E-05 -5.440 0.2019E-02 -2.695 23.68 0.7680E-03 daphnite 0.2259E-05 -5.646 0.1612E-02 -2.793 18.91 0.4885E-03 chlorite-Mn 0.6543E-07 -7.184 0.4639E-04 -4.334 0.5440 0.1478E-04 diaspore 0.5070E-04 -4.295 0.3042E-02 -2.517 35.67 0.9055E-03 hematite 0.2550E-05 -5.593 0.4073E-03 -3.390 4.777 0.7720E-04 lawsonite 0.4385E-05 -5.358 0.1378E-02 -2.861 16.16 0.4443E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3793E+00 0.3793E+00 1.0000 -0.421 chlorite-Mn 0.1098E-01 0.1098E-01 1.0000 -1.959 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.008527 g Volume = 0.002705 cm3 Porosity: 99.7319% V(tot) - V(min): 0.10065E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0230000 g log = -1.6383 Original solution: 1000.0103000 g Original solution / Rock added: 43478.71 (Water/Rock Ratio), log = 4.6383 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3499E-04 1.0071 0.3595E-04 0.3570E-04 CH4,gas 0.4258E-14 1.0125 0.4399E-14 0.4344E-14 H2,gas 0.1031E-05 1.0005 0.1052E-05 0.1052E-05 H2S,gas 0.6245E-11 0.9960 0.6347E-11 0.6372E-11 S2,gas 0.1339E-29 1.0000 0.1366E-29 0.1366E-29 CO,gas 0.9880E-14 1.0000 0.1008E-13 0.1008E-13 SO3,gas 0.1415E-35 1.0000 0.1444E-35 0.1444E-35 SO2,gas 0.5793E-19 1.0000 0.5911E-19 0.5911E-19 HCl,gas 0.5457E-15 1.0000 0.5568E-15 0.5568E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.80 -6.14 -2.048 0.10489E+05 -4.444 3 CH4,gas 4.54 -11.51 -16.06 -4.014 0.27415E+05 -14.357 4 H2,gas 8.00 0.32 -7.68 -4.387 0.13108E+05 -5.978 5 H2S,gas -6.23 -19.13 -12.90 -6.448 0.22020E+05 -11.197 6 S2,gas -7.34 -38.90 -31.56 -4.856 0.53894E+05 -29.865 7 CO,gas 3.21 -12.48 -15.70 -4.829 0.26800E+05 -13.996 8 SO3,gas 17.12 -20.42 -37.54 -9.385 0.64097E+05 -35.840 9 SO2,gas 0.83 -20.10 -20.93 -5.581 0.35733E+05 -19.228 10 HCl,gas 5.19 -11.76 -16.95 -8.477 0.28947E+05 -15.254 11 acmite 7.71 3.02 -4.69 -0.487 0.80080E+04 15 albite-high 0.69 -4.09 -4.79 -0.368 0.81721E+04 16 albite -0.38 -4.09 -3.71 -0.285 0.63333E+04 19 spessartine 24.46 20.10 -4.36 -0.218 0.74430E+04 20 analcite 3.32 -0.39 -3.71 -0.412 0.63374E+04 21 andalusite 5.00 2.04 -2.96 -0.296 0.50498E+04 22 andradite 39.01 35.28 -3.73 -0.194 0.63628E+04 23 grossular 32.73 28.46 -4.27 -0.213 0.72874E+04 24 anhydrite -5.32 -9.14 -3.83 -1.913 0.65325E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.53 -2.49 -0.831 0.42593E+04 36 brucite 12.57 8.67 -3.90 -0.779 0.66540E+04 37 calcite 0.81 -1.53 -2.34 -0.780 0.39950E+04 40 carpholite-Mg 8.58 7.01 -1.57 -0.105 0.26804E+04 41 carpholite-Fe 6.71 4.79 -1.93 -0.128 0.32911E+04 50 chloritoid-Mg 13.20 10.72 -2.48 -0.165 0.42381E+04 51 chloritoid-Fe 9.17 8.49 -0.69 -0.046 0.11697E+04 52 chloritoid-Mn 11.40 10.53 -0.87 -0.058 0.14856E+04 54 coesite -2.38 -3.70 -1.33 -0.442 0.22663E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.70 -1.14 -0.381 0.19517E+04 67 diopside 16.18 12.54 -3.64 -0.364 0.62170E+04 68 hedenbergite 14.21 10.31 -3.90 -0.390 0.66508E+04 75 epidote 24.67 23.47 -1.20 -0.058 0.20468E+04 76 clinozoisite 22.81 20.06 -2.74 -0.125 0.46857E+04 77 epidote-Fe 29.84 26.88 -2.96 -0.154 0.50545E+04 78 fayalite 14.05 9.19 -4.86 -0.694 0.82984E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.93 -4.21 -0.351 0.71930E+04 91 heulandite -5.83 -8.90 -3.07 -0.140 0.52478E+04 95 jadeite 4.22 -0.39 -4.60 -0.460 0.78628E+04 98 kaolinite -1.33 -1.66 -0.33 -0.030 0.55757E+03 99 kyanite 4.88 2.04 -2.83 -0.283 0.48357E+04 101 laumontite 2.88 2.21 -0.67 -0.045 0.11509E+04 105 lizardite 23.24 18.61 -4.64 -0.386 0.79154E+04 106 magnesite 0.69 -4.13 -4.82 -1.607 0.82340E+04 107 magnetite 20.09 19.01 -1.08 -0.088 0.18384E+04 110 magnesioferrite 26.21 21.24 -4.97 -0.406 0.84940E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.68 -3.19 -0.246 0.54540E+04 120 muscovite 2.58 0.07 -2.52 -0.148 0.42955E+04 121 paragonite 4.24 1.65 -2.59 -0.152 0.44139E+04 136 prehnite 19.37 17.19 -2.18 -0.128 0.37287E+04 137 prehnite-Fe 22.50 20.60 -1.90 -0.114 0.32448E+04 138 pumpellyite-Fe 46.27 43.69 -2.58 -0.057 0.43967E+04 139 pumpellyite-Mg 48.99 45.92 -3.07 -0.068 0.52477E+04 145 pyroxmangite 7.40 4.78 -2.62 -0.523 0.44651E+04 146 pyrophyllite -6.18 -9.07 -2.89 -0.181 0.49350E+04 147 quartz -2.99 -3.70 -0.71 -0.238 0.12190E+04 151 rhodochrosite -0.98 -4.32 -3.34 -1.113 0.57030E+04 152 rhodonite 7.45 4.78 -2.66 -0.532 0.45454E+04 153 sanidine -1.28 -5.68 -4.41 -0.339 0.75217E+04 155 siderite -2.61 -6.36 -3.75 -1.250 0.64042E+04 156 sillimanite 5.26 2.04 -3.22 -0.322 0.54938E+04 163 stilbite -7.52 -8.90 -1.38 -0.066 0.23540E+04 164 stilpnomelane-Fe 13.02 9.62 -3.40 -0.101 0.57986E+04 168 sudoite 21.08 17.73 -3.35 -0.108 0.57191E+04 174 tephroite 18.09 13.27 -4.82 -0.688 0.82218E+04 177 topaz-H 4.62 2.04 -2.57 -0.234 0.43958E+04 178 tridymite -2.63 -3.70 -1.08 -0.359 0.18390E+04 187 wairakite 3.95 2.21 -1.74 -0.102 0.29729E+04 188 walstromite 11.51 7.57 -3.94 -0.787 0.67226E+04 189 wollastonite 10.46 7.57 -2.89 -0.578 0.49331E+04 190 pseudo-wollastonite 11.00 7.57 -3.43 -0.686 0.58529E+04 191 zoisite 22.85 20.06 -2.79 -0.127 0.47597E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.04 -3.39 -0.210 0.57876E+04 194 beidellite-H -2.33 -6.90 -4.57 -0.292 0.78021E+04 195 beidellite-K -1.52 -6.05 -4.53 -0.278 0.77383E+04 196 beidellite-Mg -1.79 -5.46 -3.68 -0.227 0.62750E+04 197 beidellite-Na -1.34 -5.53 -4.19 -0.256 0.71476E+04 199 chalcedony -2.80 -3.70 -0.90 -0.300 0.15383E+04 201 montmorillonite-Ca -2.29 -5.29 -3.00 -0.186 0.51251E+04 202 montmorillonite-K -2.24 -6.31 -4.07 -0.249 0.69539E+04 203 montmorillonite-Mg -2.48 -5.72 -3.24 -0.201 0.55357E+04 204 montmorillonite-Na -2.04 -5.79 -3.75 -0.229 0.63990E+04 205 nontronite-Ca 3.21 1.78 -1.43 -0.093 0.24432E+04 206 nontronite-H 2.53 -0.08 -2.61 -0.175 0.44557E+04 207 nontronite-K 3.34 0.77 -2.57 -0.165 0.43953E+04 208 nontronite-Mg 3.07 1.35 -1.72 -0.112 0.29379E+04 209 nontronite-Na 3.52 1.29 -2.23 -0.143 0.38063E+04 214 gypsum -4.96 -9.14 -4.19 -1.047 0.71501E+04 224 tobermorite 9.82 5.69 -4.13 -1.128 0.70587E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.44 -3.37 -0.842 0.57492E+04 240 silica-amorphous -2.09 -3.70 -1.61 -0.537 0.27525E+04 242 an20ab80 2.02 -1.35 -3.37 -0.259 0.57525E+04 243 an25ab75 2.65 -0.67 -3.31 -0.255 0.56542E+04 244 an30ab70 3.28 0.02 -3.26 -0.251 0.55656E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0230000 g New total amount of reactant added: 0.0240000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0240000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3112746E-03 Osmotic coef. = 0.9894 True ionic strength = .3259780E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13751E-07 -7.8617 0.13186E-07 -7.8799 0.95891E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13227E-03 -3.8785 0.95877E+00 -0.0183 4 SO4-- 0.25280E-04 -4.5972 0.22544E-04 -4.6470 0.89180E+00 -0.0497 5 HCO3- 0.12599E-04 -4.8997 0.12080E-04 -4.9179 0.95881E+00 -0.0183 6 HS- 0.53446E-11 -11.2721 0.51243E-11 -11.2904 0.95878E+00 -0.0183 7 Al+++ 0.21696E-20 -20.6636 0.17141E-20 -20.7660 0.79006E+00 -0.1023 8 H4SiO4 0.20322E-03 -3.6920 0.20322E-03 -3.6920 0.10000E+01 0.0000 9 Ca++ 0.34896E-04 -4.4572 0.31115E-04 -4.5070 0.89165E+00 -0.0498 10 Mg++ 0.90133E-07 -7.0451 0.80358E-07 -7.0950 0.89155E+00 -0.0499 11 Fe++ 0.53422E-09 -9.2723 0.47630E-09 -9.3221 0.89157E+00 -0.0498 12 K+ 0.50936E-05 -5.2930 0.48838E-05 -5.3112 0.95881E+00 -0.0183 13 Na+ 0.19014E-03 -3.7209 0.18230E-03 -3.7392 0.95877E+00 -0.0183 14 Mn++ 0.59277E-07 -7.2271 0.52851E-07 -7.2769 0.89159E+00 -0.0498 15 HPO4-- 0.10087E-08 -8.9962 0.89957E-09 -9.0460 0.89181E+00 -0.0497 16 HSiO3- 0.15009E-04 -4.8236 0.14391E-04 -4.8419 0.95877E+00 -0.0183 17 Ca(HSiO3)+ 0.10635E-07 -7.9732 0.10197E-07 -7.9915 0.95882E+00 -0.0183 18 Mg(HSiO3)+ 0.34183E-10 -10.4662 0.32775E-10 -10.4845 0.95882E+00 -0.0183 19 NaHSiO3,aq 0.42431E-07 -7.3723 0.42431E-07 -7.3723 0.10000E+01 0.0000 20 AlO+ 0.13988E-11 -11.8542 0.13412E-11 -11.8725 0.95882E+00 -0.0183 21 AlOH+2 0.98765E-16 -16.0054 0.88060E-16 -16.0552 0.89161E+00 -0.0498 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.35468E-05 -5.4502 0.34004E-05 -5.4685 0.95873E+00 -0.0183 24 CH4,aq 0.26674E-17 -17.5739 0.26671E-17 -17.5740 0.99990E+00 0.0000 29 CO,aq 0.66384E-17 -17.1779 0.66384E-17 -17.1779 0.10000E+01 0.0000 30 CO2,aq 0.34039E-06 -6.4680 0.34035E-06 -6.4681 0.99990E+00 0.0000 31 CO3-2 0.89730E-07 -7.0471 0.80018E-07 -7.0968 0.89176E+00 -0.0498 32 CaCO3,aq 0.31219E-07 -7.5056 0.31219E-07 -7.5056 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10006E-07 -7.9997 0.95943E-08 -8.0180 0.95882E+00 -0.0183 34 CaCl+ 0.69466E-08 -8.1582 0.66605E-08 -8.1765 0.95882E+00 -0.0183 35 CaCl2,aq 0.20931E-12 -12.6792 0.20931E-12 -12.6792 0.10000E+01 0.0000 36 CaOH+ 0.17540E-06 -6.7560 0.16817E-06 -6.7742 0.95882E+00 -0.0183 37 CaSO4,aq 0.22275E-06 -6.6522 0.22275E-06 -6.6522 0.10000E+01 0.0000 38 HCl,aq 0.31961E-12 -12.4954 0.31961E-12 -12.4954 0.10000E+01 0.0000 43 FeCl+ 0.10400E-12 -12.9829 0.99721E-13 -13.0012 0.95882E+00 -0.0183 46 FeO,aq 0.10647E-09 -9.9728 0.10647E-09 -9.9728 0.10000E+01 0.0000 47 FeOH+ 0.12263E-08 -8.9114 0.11758E-08 -8.9297 0.95882E+00 -0.0183 48 HFeO2- 0.88114E-10 -10.0550 0.84482E-10 -10.0732 0.95877E+00 -0.0183 49 FeO+ 0.10497E-12 -12.9789 0.10065E-12 -12.9972 0.95882E+00 -0.0183 50 FeOH+2 0.28426E-18 -18.5463 0.25345E-18 -18.5961 0.89161E+00 -0.0498 51 FeO2- 0.12354E-09 -9.9082 0.11845E-09 -9.9265 0.95877E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.77651E-09 -9.1099 0.77643E-09 -9.1099 0.99990E+00 0.0000 54 KCl,aq 0.11708E-10 -10.9315 0.11708E-10 -10.9315 0.10000E+01 0.0000 55 KHSO4,aq 0.41049E-17 -17.3867 0.41049E-17 -17.3867 0.10000E+01 0.0000 56 KOH,aq 0.15817E-09 -9.8009 0.15817E-09 -9.8009 0.10000E+01 0.0000 57 KSO4- 0.17820E-08 -8.7491 0.17085E-08 -8.7674 0.95877E+00 -0.0183 58 MgCO3,aq 0.20209E-10 -10.6944 0.20209E-10 -10.6944 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26406E-10 -10.5783 0.25319E-10 -10.5966 0.95882E+00 -0.0183 60 MgCl+ 0.16260E-10 -10.7889 0.15590E-10 -10.8071 0.95882E+00 -0.0183 61 MgOH+ 0.25066E-08 -8.6009 0.24034E-08 -8.6192 0.95882E+00 -0.0183 63 MnO,aq 0.31479E-09 -9.5020 0.31479E-09 -9.5020 0.10000E+01 0.0000 64 MnOH+ 0.12641E-07 -7.8982 0.12120E-07 -7.9165 0.95882E+00 -0.0183 65 MnO2-2 0.67377E-16 -16.1715 0.60084E-16 -16.2212 0.89176E+00 -0.0498 66 HMnO2- 0.18104E-12 -12.7422 0.17357E-12 -12.7605 0.95877E+00 -0.0183 69 MnCl+ 0.44898E-10 -10.3478 0.43049E-10 -10.3660 0.95882E+00 -0.0183 70 MnSO4,aq 0.34397E-09 -9.4635 0.34397E-09 -9.4635 0.10000E+01 0.0000 71 NaCl,aq 0.79913E-08 -8.0974 0.79913E-08 -8.0974 0.10000E+01 0.0000 72 NaOH,aq 0.59401E-08 -8.2262 0.59401E-08 -8.2262 0.10000E+01 0.0000 74 OH- 0.45703E-04 -4.3401 0.43817E-04 -4.3584 0.95873E+00 -0.0183 82 H3PO4,aq 0.10939E-14 -14.9610 0.10939E-14 -14.9610 0.10000E+01 0.0000 83 H2PO4- 0.22822E-09 -9.6416 0.21882E-09 -9.6599 0.95879E+00 -0.0183 84 PO4-3 0.70368E-13 -13.1526 0.55661E-13 -13.2544 0.79100E+00 -0.1018 88 HP2O7-3 0.71959E-19 -19.1429 0.56853E-19 -19.2452 0.79007E+00 -0.1023 90 H2S,aq 0.20885E-12 -12.6802 0.20883E-12 -12.6802 0.99990E+00 0.0000 96 SO2,aq 0.13592E-19 -19.8667 0.13592E-19 -19.8667 0.10000E+01 0.0000 97 SO3-2 0.25499E-14 -14.5935 0.22747E-14 -14.6431 0.89207E+00 -0.0496 98 HSO3- 0.19587E-14 -14.7080 0.18780E-14 -14.7263 0.95877E+00 -0.0183 99 HSO4- 0.29878E-09 -9.5246 0.28649E-09 -9.5429 0.95884E+00 -0.0183 101 S2O3-2 0.62016E-19 -19.2075 0.55303E-19 -19.2572 0.89176E+00 -0.0498 Charge balance for all species = 0.2014E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1375108E-07 -.7497973E-04 -.7557253E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999649E+06 0.0000 3 Cl- 0.1379604E-03 0.1379754E-03 0.4891478E+01 4.0014 4 SO4-- 0.2527952E-04 0.2550454E-04 0.2449924E+01 11.1128 5 HCO3- 0.1259873E-04 0.1307012E-04 0.7974751E+00 2.9619 6 HS- 0.5344613E-11 0.1593952E-09 0.5271341E-05 -3.4105 7 Al+++ 0.2169603E-20 0.3567026E-05 0.9624049E-01 2.8737 8 H4SiO4 0.2032207E-03 0.2182833E-03 0.2097968E+02 -3.6920 9 Ca++ 0.3489629E-04 0.3535324E-04 0.1416840E+01 11.2527 10 Mg++ 0.9013283E-07 0.9273647E-07 0.2254533E-02 8.6648 11 Fe++ 0.5342243E-09 0.2277494E-08 0.1271869E-03 6.4377 12 K+ 0.5093635E-05 0.5095587E-05 0.1992409E+00 2.5686 13 Na+ 0.1901422E-03 0.1901985E-03 0.4372479E+01 4.1407 14 Mn++ 0.5927722E-07 0.7262167E-07 0.3989555E-02 8.4828 15 HPO4-- 0.1008708E-08 0.1237002E-08 0.1187222E-03 6.7138 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3843644E-03 -.7497906E-04 -.3093853E-03 0.0000000E+00 2 H2O 0.5550795E+02 0.5550780E+02 0.1542114E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2616959E-04 0.2550431E-04 0.6652812E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6651218E-06 0.1593938E-09 -.6652812E-06 0.0000000E+00 7 Al+++ 0.7825780E-04 0.3566995E-05 0.7469080E-04 0.0000000E+00 8 H4SiO4 0.2499068E-03 0.2182813E-03 0.3162547E-04 0.0000000E+00 9 Ca++ 0.4207448E-04 0.3535293E-04 0.6721556E-05 0.0000000E+00 10 Mg++ 0.1904762E-04 0.9273564E-07 0.1895488E-04 0.0000000E+00 11 Fe++ 0.1711221E-04 0.2277474E-08 0.1710993E-04 0.0000000E+00 12 K+ 0.5095541E-05 0.5095541E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1901968E-03 0.1901968E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4161263E-06 0.7262103E-07 0.3435053E-06 0.0000000E+00 15 HPO4-- 0.1420218E-06 0.1236991E-08 0.1407848E-06 0.0000000E+00 Chg. balance for solid moles: 0.4585E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0240000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4693E-07 -7.329 0.2357E-04 -4.628 0.2540 0.7491E-05 clinochlore 0.3791E-05 -5.421 0.2107E-02 -2.676 22.70 0.8015E-03 daphnite 0.2358E-05 -5.628 0.1682E-02 -2.774 18.12 0.5097E-03 chlorite-Mn 0.6870E-07 -7.163 0.4871E-04 -4.312 0.5248 0.1552E-04 diaspore 0.4928E-04 -4.307 0.2956E-02 -2.529 31.85 0.8802E-03 hematite 0.2661E-05 -5.575 0.4250E-03 -3.372 4.579 0.8055E-04 lawsonite 0.6487E-05 -5.188 0.2038E-02 -2.691 21.96 0.6574E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3792E+00 0.3792E+00 1.0000 -0.421 chlorite-Mn 0.1105E-01 0.1105E-01 1.0000 -1.957 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.009281 g Volume = 0.002952 cm3 Porosity: 99.7076% V(tot) - V(min): 0.10066E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0240000 g log = -1.6198 Original solution: 1000.0103000 g Original solution / Rock added: 41667.10 (Water/Rock Ratio), log = 4.6198 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3544E-04 1.0071 0.3641E-04 0.3616E-04 CH4,gas 0.3800E-14 1.0125 0.3926E-14 0.3877E-14 H2,gas 0.9985E-06 1.0005 0.1019E-05 0.1019E-05 H2S,gas 0.5649E-11 0.9960 0.5741E-11 0.5763E-11 S2,gas 0.1167E-29 1.0000 0.1190E-29 0.1190E-29 CO,gas 0.9695E-14 1.0000 0.9893E-14 0.9893E-14 SO3,gas 0.1453E-35 1.0000 0.1482E-35 0.1482E-35 SO2,gas 0.5761E-19 1.0000 0.5878E-19 0.5878E-19 HCl,gas 0.5527E-15 1.0000 0.5640E-15 0.5640E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.80 -6.14 -2.046 0.10480E+05 -4.439 3 CH4,gas 4.54 -11.56 -16.11 -4.026 0.27499E+05 -14.406 4 H2,gas 8.00 0.31 -7.69 -4.395 0.13132E+05 -5.992 5 H2S,gas -6.23 -19.17 -12.94 -6.470 0.22095E+05 -11.241 6 S2,gas -7.34 -38.96 -31.62 -4.865 0.53996E+05 -29.924 7 CO,gas 3.21 -12.49 -15.70 -4.832 0.26814E+05 -14.005 8 SO3,gas 17.12 -20.41 -37.53 -9.382 0.64078E+05 -35.829 9 SO2,gas 0.83 -20.10 -20.93 -5.581 0.35737E+05 -19.231 10 HCl,gas 5.19 -11.76 -16.95 -8.474 0.28938E+05 -15.249 11 acmite 7.71 3.04 -4.67 -0.485 0.79739E+04 15 albite-high 0.69 -4.06 -4.75 -0.366 0.81186E+04 16 albite -0.38 -4.06 -3.68 -0.283 0.62798E+04 19 spessartine 24.46 20.12 -4.34 -0.217 0.74063E+04 20 analcite 3.32 -0.37 -3.69 -0.410 0.63032E+04 21 andalusite 5.00 2.06 -2.95 -0.295 0.50305E+04 22 andradite 39.01 35.25 -3.76 -0.195 0.64208E+04 23 grossular 32.73 28.43 -4.30 -0.215 0.73454E+04 24 anhydrite -5.32 -9.15 -3.84 -1.919 0.65519E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.55 -2.51 -0.837 0.42885E+04 36 brucite 12.57 8.66 -3.90 -0.781 0.66656E+04 37 calcite 0.81 -1.55 -2.36 -0.786 0.40243E+04 40 carpholite-Mg 8.58 7.03 -1.55 -0.104 0.26533E+04 41 carpholite-Fe 6.71 4.80 -1.91 -0.127 0.32641E+04 50 chloritoid-Mg 13.20 10.72 -2.48 -0.165 0.42303E+04 51 chloritoid-Fe 9.17 8.49 -0.68 -0.045 0.11621E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.058 0.14734E+04 54 coesite -2.38 -3.69 -1.32 -0.439 0.22470E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.69 -1.13 -0.377 0.19323E+04 67 diopside 16.18 12.53 -3.65 -0.365 0.62287E+04 68 hedenbergite 14.21 10.31 -3.90 -0.390 0.66625E+04 75 epidote 24.67 23.46 -1.21 -0.059 0.20661E+04 76 clinozoisite 22.81 20.05 -2.76 -0.125 0.47050E+04 77 epidote-Fe 29.84 26.87 -2.97 -0.154 0.50738E+04 78 fayalite 14.05 9.18 -4.86 -0.695 0.83025E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.93 -4.21 -0.351 0.71895E+04 91 heulandite -5.83 -8.84 -3.02 -0.137 0.51512E+04 95 jadeite 4.22 -0.37 -4.58 -0.458 0.78287E+04 98 kaolinite -1.33 -1.64 -0.30 -0.028 0.51890E+03 99 kyanite 4.88 2.06 -2.82 -0.282 0.48164E+04 101 laumontite 2.88 2.23 -0.65 -0.043 0.11123E+04 105 lizardite 23.24 18.61 -4.63 -0.386 0.79116E+04 106 magnesite 0.69 -4.13 -4.82 -1.608 0.82362E+04 107 magnetite 20.09 19.00 -1.08 -0.088 0.18501E+04 110 magnesioferrite 26.21 21.23 -4.98 -0.407 0.85056E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.63 -3.15 -0.242 0.53739E+04 120 muscovite 2.58 0.11 -2.47 -0.145 0.42154E+04 121 paragonite 4.24 1.69 -2.55 -0.150 0.43605E+04 136 prehnite 19.37 17.18 -2.20 -0.129 0.37481E+04 137 prehnite-Fe 22.50 20.59 -1.91 -0.115 0.32642E+04 138 pumpellyite-Fe 46.27 43.66 -2.60 -0.058 0.44471E+04 139 pumpellyite-Mg 48.99 45.89 -3.10 -0.069 0.52980E+04 145 pyroxmangite 7.40 4.79 -2.61 -0.522 0.44529E+04 146 pyrophyllite -6.18 -9.02 -2.84 -0.178 0.48577E+04 147 quartz -2.99 -3.69 -0.70 -0.234 0.11997E+04 151 rhodochrosite -0.98 -4.32 -3.34 -1.113 0.57007E+04 152 rhodonite 7.45 4.79 -2.65 -0.531 0.45331E+04 153 sanidine -1.28 -5.63 -4.36 -0.335 0.74416E+04 155 siderite -2.61 -6.36 -3.75 -1.251 0.64065E+04 156 sillimanite 5.26 2.06 -3.21 -0.321 0.54744E+04 163 stilbite -7.52 -8.84 -1.32 -0.063 0.22573E+04 164 stilpnomelane-Fe 13.02 9.68 -3.33 -0.100 0.56914E+04 168 sudoite 21.08 17.75 -3.33 -0.107 0.56843E+04 174 tephroite 18.09 13.27 -4.81 -0.687 0.82167E+04 177 topaz-H 4.62 2.06 -2.56 -0.233 0.43765E+04 178 tridymite -2.63 -3.69 -1.07 -0.355 0.18196E+04 187 wairakite 3.95 2.23 -1.72 -0.101 0.29342E+04 188 walstromite 11.51 7.56 -3.95 -0.790 0.67420E+04 189 wollastonite 10.46 7.56 -2.90 -0.580 0.49524E+04 190 pseudo-wollastonite 11.00 7.56 -3.44 -0.688 0.58722E+04 191 zoisite 22.85 20.05 -2.80 -0.127 0.47791E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -5.00 -3.35 -0.207 0.57230E+04 194 beidellite-H -2.33 -6.85 -4.53 -0.289 0.77311E+04 195 beidellite-K -1.52 -6.01 -4.49 -0.275 0.76600E+04 196 beidellite-Mg -1.79 -5.42 -3.63 -0.225 0.62059E+04 197 beidellite-Na -1.34 -5.49 -4.15 -0.254 0.70781E+04 199 chalcedony -2.80 -3.69 -0.89 -0.297 0.15190E+04 201 montmorillonite-Ca -2.29 -5.25 -2.96 -0.183 0.50580E+04 202 montmorillonite-K -2.24 -6.26 -4.03 -0.246 0.68731E+04 203 montmorillonite-Mg -2.48 -5.68 -3.20 -0.198 0.54641E+04 204 montmorillonite-Na -2.04 -5.74 -3.71 -0.227 0.63270E+04 205 nontronite-Ca 3.21 1.82 -1.39 -0.090 0.23787E+04 206 nontronite-H 2.53 -0.04 -2.57 -0.172 0.43847E+04 207 nontronite-K 3.34 0.81 -2.53 -0.162 0.43170E+04 208 nontronite-Mg 3.07 1.39 -1.68 -0.109 0.28689E+04 209 nontronite-Na 3.52 1.33 -2.19 -0.140 0.37369E+04 214 gypsum -4.96 -9.15 -4.20 -1.050 0.71695E+04 224 tobermorite 9.82 5.68 -4.14 -1.130 0.70716E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.44 -3.37 -0.843 0.57609E+04 240 silica-amorphous -2.09 -3.69 -1.60 -0.534 0.27331E+04 242 an20ab80 2.02 -1.33 -3.34 -0.257 0.57097E+04 243 an25ab75 2.65 -0.64 -3.29 -0.253 0.56141E+04 244 an30ab70 3.28 0.04 -3.24 -0.249 0.55282E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0240000 g New total amount of reactant added: 0.0250000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0250000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3099347E-03 Osmotic coef. = 0.9895 True ionic strength = .3246661E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13919E-07 -7.8564 0.13348E-07 -7.8746 0.95896E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13228E-03 -3.8785 0.95882E+00 -0.0183 4 SO4-- 0.25285E-04 -4.5971 0.22554E-04 -4.6468 0.89197E+00 -0.0496 5 HCO3- 0.12597E-04 -4.8997 0.12079E-04 -4.9180 0.95885E+00 -0.0182 6 HS- 0.47810E-11 -11.3205 0.45842E-11 -11.3387 0.95882E+00 -0.0183 7 Al+++ 0.22497E-20 -20.6479 0.17781E-20 -20.7500 0.79040E+00 -0.1022 8 H4SiO4 0.20849E-03 -3.6809 0.20849E-03 -3.6809 0.10000E+01 0.0000 9 Ca++ 0.33969E-04 -4.4689 0.30294E-04 -4.5186 0.89182E+00 -0.0497 10 Mg++ 0.90937E-07 -7.0413 0.81091E-07 -7.0910 0.89172E+00 -0.0498 11 Fe++ 0.53892E-09 -9.2685 0.48058E-09 -9.3182 0.89174E+00 -0.0498 12 K+ 0.53059E-05 -5.2752 0.50876E-05 -5.2935 0.95886E+00 -0.0182 13 Na+ 0.19140E-03 -3.7181 0.18351E-03 -3.7363 0.95881E+00 -0.0183 14 Mn++ 0.60151E-07 -7.2208 0.53640E-07 -7.2705 0.89176E+00 -0.0498 15 HPO4-- 0.10718E-08 -8.9699 0.95601E-09 -9.0195 0.89197E+00 -0.0496 16 HSiO3- 0.15211E-04 -4.8179 0.14584E-04 -4.8361 0.95882E+00 -0.0183 17 Ca(HSiO3)+ 0.10494E-07 -7.9791 0.10062E-07 -7.9973 0.95886E+00 -0.0182 18 Mg(HSiO3)+ 0.34957E-10 -10.4565 0.33519E-10 -10.4747 0.95886E+00 -0.0182 19 NaHSiO3,aq 0.43287E-07 -7.3636 0.43287E-07 -7.3636 0.10000E+01 0.0000 20 AlO+ 0.14159E-11 -11.8490 0.13577E-11 -11.8672 0.95886E+00 -0.0182 21 AlOH+2 0.10119E-15 -15.9949 0.90239E-16 -16.0446 0.89178E+00 -0.0497 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.35035E-05 -5.4555 0.33591E-05 -5.4738 0.95878E+00 -0.0183 24 CH4,aq 0.23850E-17 -17.6225 0.23848E-17 -17.6225 0.99990E+00 0.0000 29 CO,aq 0.65144E-17 -17.1861 0.65144E-17 -17.1861 0.10000E+01 0.0000 30 CO2,aq 0.34454E-06 -6.4628 0.34451E-06 -6.4628 0.99990E+00 0.0000 31 CO3-2 0.88617E-07 -7.0525 0.79040E-07 -7.1022 0.89193E+00 -0.0497 32 CaCO3,aq 0.30024E-07 -7.5225 0.30024E-07 -7.5225 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.97412E-08 -8.0114 0.93405E-08 -8.0296 0.95886E+00 -0.0182 34 CaCl+ 0.67633E-08 -8.1698 0.64851E-08 -8.1881 0.95886E+00 -0.0182 35 CaCl2,aq 0.20380E-12 -12.6908 0.20380E-12 -12.6908 0.10000E+01 0.0000 36 CaOH+ 0.16869E-06 -6.7729 0.16175E-06 -6.7912 0.95886E+00 -0.0182 37 CaSO4,aq 0.21696E-06 -6.6636 0.21696E-06 -6.6636 0.10000E+01 0.0000 38 HCl,aq 0.32355E-12 -12.4901 0.32355E-12 -12.4901 0.10000E+01 0.0000 43 FeCl+ 0.10494E-12 -12.9791 0.10062E-12 -12.9973 0.95886E+00 -0.0182 46 FeO,aq 0.10483E-09 -9.9795 0.10483E-09 -9.9795 0.10000E+01 0.0000 47 FeOH+ 0.12222E-08 -8.9129 0.11719E-08 -8.9311 0.95886E+00 -0.0182 48 HFeO2- 0.85701E-10 -10.0670 0.82172E-10 -10.0853 0.95882E+00 -0.0183 49 FeO+ 0.10626E-12 -12.9736 0.10189E-12 -12.9919 0.95886E+00 -0.0182 50 FeOH+2 0.29123E-18 -18.5358 0.25972E-18 -18.5855 0.89178E+00 -0.0497 51 FeO2- 0.12203E-09 -9.9135 0.11701E-09 -9.9318 0.95882E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.75280E-09 -9.1233 0.75273E-09 -9.1234 0.99990E+00 0.0000 54 KCl,aq 0.12197E-10 -10.9137 0.12197E-10 -10.9137 0.10000E+01 0.0000 55 KHSO4,aq 0.43305E-17 -17.3635 0.43305E-17 -17.3635 0.10000E+01 0.0000 56 KOH,aq 0.16277E-09 -9.7884 0.16277E-09 -9.7884 0.10000E+01 0.0000 57 KSO4- 0.18570E-08 -8.7312 0.17805E-08 -8.7494 0.95882E+00 -0.0183 58 MgCO3,aq 0.20144E-10 -10.6958 0.20144E-10 -10.6958 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26644E-10 -10.5744 0.25548E-10 -10.5927 0.95886E+00 -0.0182 60 MgCl+ 0.16408E-10 -10.7849 0.15733E-10 -10.8032 0.95886E+00 -0.0182 61 MgOH+ 0.24986E-08 -8.6023 0.23958E-08 -8.6205 0.95886E+00 -0.0182 63 MnO,aq 0.31177E-09 -9.5062 0.31177E-09 -9.5062 0.10000E+01 0.0000 64 MnOH+ 0.12673E-07 -7.8971 0.12152E-07 -7.9154 0.95886E+00 -0.0182 65 MnO2-2 0.65108E-16 -16.1864 0.58072E-16 -16.2360 0.89193E+00 -0.0497 66 HMnO2- 0.17712E-12 -12.7517 0.16982E-12 -12.7700 0.95882E+00 -0.0183 69 MnCl+ 0.45568E-10 -10.3413 0.43693E-10 -10.3596 0.95886E+00 -0.0182 70 MnSO4,aq 0.34926E-09 -9.4569 0.34926E-09 -9.4569 0.10000E+01 0.0000 71 NaCl,aq 0.80448E-08 -8.0945 0.80448E-08 -8.0945 0.10000E+01 0.0000 72 NaOH,aq 0.59069E-08 -8.2286 0.59069E-08 -8.2286 0.10000E+01 0.0000 74 OH- 0.45146E-04 -4.3454 0.43285E-04 -4.3637 0.95878E+00 -0.0183 82 H3PO4,aq 0.11913E-14 -14.9240 0.11913E-14 -14.9240 0.10000E+01 0.0000 83 H2PO4- 0.24551E-09 -9.6099 0.23541E-09 -9.6282 0.95884E+00 -0.0183 84 PO4-3 0.73844E-13 -13.1317 0.58435E-13 -13.2333 0.79134E+00 -0.1016 88 HP2O7-3 0.82236E-19 -19.0849 0.65000E-19 -19.1871 0.79041E+00 -0.1021 90 H2S,aq 0.18913E-12 -12.7232 0.18912E-12 -12.7233 0.99990E+00 0.0000 96 SO2,aq 0.13509E-19 -19.8694 0.13509E-19 -19.8694 0.10000E+01 0.0000 97 SO3-2 0.24726E-14 -14.6069 0.22061E-14 -14.6564 0.89224E+00 -0.0495 98 HSO3- 0.19230E-14 -14.7160 0.18438E-14 -14.7343 0.95882E+00 -0.0183 99 HSO4- 0.30257E-09 -9.5192 0.29013E-09 -9.5374 0.95888E+00 -0.0182 101 S2O3-2 0.56174E-19 -19.2505 0.50103E-19 -19.3001 0.89193E+00 -0.0497 Charge balance for all species = 0.2015E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1391949E-07 -.7443811E-04 -.7502659E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999643E+06 0.0000 3 Cl- 0.1379606E-03 0.1379754E-03 0.4891477E+01 3.9961 4 SO4-- 0.2528523E-04 0.2550455E-04 0.2449924E+01 11.1024 5 HCO3- 0.1259715E-04 0.1307012E-04 0.7974749E+00 2.9566 6 HS- 0.4781041E-11 0.1530735E-09 0.5062273E-05 -3.4642 7 Al+++ 0.2249653E-20 0.3523783E-05 0.9507371E-01 2.8737 8 H4SiO4 0.2084877E-03 0.2237522E-03 0.2150530E+02 -3.6809 9 Ca++ 0.3396922E-04 0.3441189E-04 0.1379113E+01 11.2305 10 Mg++ 0.9093726E-07 0.9353401E-07 0.2273921E-02 8.6581 11 Fe++ 0.5389175E-09 0.2272555E-08 0.1269111E-03 6.4309 12 K+ 0.5305872E-05 0.5307904E-05 0.2075426E+00 2.5811 13 Na+ 0.1913966E-03 0.1914538E-03 0.4401335E+01 4.1382 14 Mn++ 0.6015079E-07 0.7353048E-07 0.4039480E-02 8.4786 15 HPO4-- 0.1071794E-08 0.1317381E-08 0.1264366E-03 6.7296 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4009229E-03 -.7443743E-04 -.3264855E-03 0.0000000E+00 2 H2O 0.5550794E+02 0.5550778E+02 0.1573997E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2619731E-04 0.2550432E-04 0.6929883E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6928352E-06 0.1530721E-09 -.6929883E-06 0.0000000E+00 7 Al+++ 0.8151854E-04 0.3523751E-05 0.7799479E-04 0.0000000E+00 8 H4SiO4 0.2603196E-03 0.2237502E-03 0.3656938E-04 0.0000000E+00 9 Ca++ 0.4322463E-04 0.3441158E-04 0.8813047E-05 0.0000000E+00 10 Mg++ 0.1984127E-04 0.9353315E-07 0.1974774E-04 0.0000000E+00 11 Fe++ 0.1782521E-04 0.2272535E-08 0.1782294E-04 0.0000000E+00 12 K+ 0.5307856E-05 0.5307856E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1914521E-03 0.1914521E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4334649E-06 0.7352981E-07 0.3599351E-06 0.0000000E+00 15 HPO4-- 0.1479394E-06 0.1317369E-08 0.1466220E-06 0.0000000E+00 Chg. balance for solid moles: 0.1705E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0250000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4887E-07 -7.311 0.2455E-04 -4.610 0.2447 0.7801E-05 clinochlore 0.3950E-05 -5.403 0.2195E-02 -2.659 21.88 0.8350E-03 daphnite 0.2456E-05 -5.610 0.1752E-02 -2.756 17.47 0.5310E-03 chlorite-Mn 0.7199E-07 -7.143 0.5104E-04 -4.292 0.5087 0.1626E-04 diaspore 0.4790E-04 -4.320 0.2874E-02 -2.542 28.64 0.8555E-03 hematite 0.2772E-05 -5.557 0.4427E-03 -3.354 4.413 0.8390E-04 lawsonite 0.8569E-05 -5.067 0.2693E-02 -2.570 26.84 0.8683E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3791E+00 0.3791E+00 1.0000 -0.421 chlorite-Mn 0.1111E-01 0.1111E-01 1.0000 -1.954 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.010032 g Volume = 0.003198 cm3 Porosity: 99.6834% V(tot) - V(min): 0.10068E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0250000 g log = -1.6021 Original solution: 1000.0103000 g Original solution / Rock added: 40000.41 (Water/Rock Ratio), log = 4.6021 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3587E-04 1.0071 0.3686E-04 0.3660E-04 CH4,gas 0.3398E-14 1.0125 0.3510E-14 0.3467E-14 H2,gas 0.9680E-06 1.0005 0.9882E-06 0.9877E-06 H2S,gas 0.5115E-11 0.9960 0.5199E-11 0.5219E-11 S2,gas 0.1018E-29 1.0000 0.1039E-29 0.1039E-29 CO,gas 0.9514E-14 1.0000 0.9708E-14 0.9708E-14 SO3,gas 0.1489E-35 1.0000 0.1519E-35 0.1519E-35 SO2,gas 0.5725E-19 1.0000 0.5842E-19 0.5842E-19 HCl,gas 0.5595E-15 1.0000 0.5709E-15 0.5709E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.79 -6.13 -2.044 0.10471E+05 -4.433 3 CH4,gas 4.54 -11.61 -16.15 -4.038 0.27582E+05 -14.455 4 H2,gas 8.00 0.30 -7.70 -4.402 0.13155E+05 -6.005 5 H2S,gas -6.23 -19.21 -12.98 -6.492 0.22168E+05 -11.284 6 S2,gas -7.34 -39.02 -31.68 -4.874 0.54097E+05 -29.983 7 CO,gas 3.21 -12.50 -15.71 -4.834 0.26828E+05 -14.013 8 SO3,gas 17.12 -20.40 -37.52 -9.379 0.64060E+05 -35.818 9 SO2,gas 0.83 -20.10 -20.93 -5.582 0.35742E+05 -19.233 10 HCl,gas 5.19 -11.75 -16.94 -8.471 0.28929E+05 -15.243 11 acmite 7.71 3.06 -4.65 -0.483 0.79401E+04 15 albite-high 0.69 -4.03 -4.72 -0.363 0.80659E+04 16 albite -0.38 -4.03 -3.65 -0.281 0.62271E+04 19 spessartine 24.46 20.14 -4.32 -0.216 0.73708E+04 20 analcite 3.32 -0.35 -3.67 -0.408 0.62694E+04 21 andalusite 5.00 2.07 -2.94 -0.294 0.50115E+04 22 andradite 39.01 35.21 -3.79 -0.197 0.64778E+04 23 grossular 32.73 28.40 -4.34 -0.217 0.74023E+04 24 anhydrite -5.32 -9.17 -3.85 -1.924 0.65714E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.56 -2.53 -0.843 0.43174E+04 36 brucite 12.57 8.66 -3.91 -0.782 0.66770E+04 37 calcite 0.81 -1.56 -2.37 -0.791 0.40532E+04 40 carpholite-Mg 8.58 7.04 -1.54 -0.103 0.26268E+04 41 carpholite-Fe 6.71 4.82 -1.90 -0.126 0.32376E+04 50 chloritoid-Mg 13.20 10.72 -2.47 -0.165 0.42228E+04 51 chloritoid-Fe 9.17 8.50 -0.68 -0.045 0.11546E+04 52 chloritoid-Mn 11.40 10.55 -0.86 -0.057 0.14615E+04 54 coesite -2.38 -3.68 -1.30 -0.435 0.22280E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.68 -1.12 -0.374 0.19134E+04 67 diopside 16.18 12.53 -3.65 -0.365 0.62400E+04 68 hedenbergite 14.21 10.30 -3.91 -0.391 0.66740E+04 75 epidote 24.67 23.45 -1.22 -0.059 0.20851E+04 76 clinozoisite 22.81 20.04 -2.77 -0.126 0.47240E+04 77 epidote-Fe 29.84 26.86 -2.98 -0.155 0.50928E+04 78 fayalite 14.05 9.18 -4.86 -0.695 0.83065E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.93 -4.21 -0.351 0.71861E+04 91 heulandite -5.83 -8.79 -2.96 -0.135 0.50563E+04 95 jadeite 4.22 -0.35 -4.57 -0.457 0.77949E+04 98 kaolinite -1.33 -1.61 -0.28 -0.026 0.48095E+03 99 kyanite 4.88 2.07 -2.81 -0.281 0.47974E+04 101 laumontite 2.88 2.25 -0.63 -0.042 0.10743E+04 105 lizardite 23.24 18.61 -4.63 -0.386 0.79078E+04 106 magnesite 0.69 -4.13 -4.83 -1.608 0.82386E+04 107 magnetite 20.09 19.00 -1.09 -0.089 0.18616E+04 110 magnesioferrite 26.21 21.22 -4.99 -0.407 0.85170E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.59 -3.10 -0.239 0.52957E+04 120 muscovite 2.58 0.16 -2.42 -0.143 0.41372E+04 121 paragonite 4.24 1.72 -2.52 -0.148 0.43077E+04 136 prehnite 19.37 17.17 -2.21 -0.130 0.37670E+04 137 prehnite-Fe 22.50 20.58 -1.92 -0.116 0.32831E+04 138 pumpellyite-Fe 46.27 43.64 -2.63 -0.059 0.44966E+04 139 pumpellyite-Mg 48.99 45.86 -3.13 -0.070 0.53473E+04 145 pyroxmangite 7.40 4.80 -2.60 -0.520 0.44411E+04 146 pyrophyllite -6.18 -8.98 -2.80 -0.175 0.47818E+04 147 quartz -2.99 -3.68 -0.69 -0.230 0.11807E+04 151 rhodochrosite -0.98 -4.31 -3.34 -1.113 0.56988E+04 152 rhodonite 7.45 4.80 -2.65 -0.530 0.45213E+04 153 sanidine -1.28 -5.59 -4.31 -0.332 0.73634E+04 155 siderite -2.61 -6.36 -3.75 -1.251 0.64090E+04 156 sillimanite 5.26 2.07 -3.20 -0.320 0.54555E+04 163 stilbite -7.52 -8.79 -1.27 -0.060 0.21625E+04 164 stilpnomelane-Fe 13.02 9.75 -3.27 -0.098 0.55865E+04 167 sudoite-Fe 18.30 13.31 -4.98 -0.161 0.85072E+04 168 sudoite 21.08 17.77 -3.31 -0.107 0.56502E+04 174 tephroite 18.09 13.28 -4.81 -0.687 0.82120E+04 177 topaz-H 4.62 2.07 -2.55 -0.232 0.43575E+04 178 tridymite -2.63 -3.68 -1.05 -0.352 0.18007E+04 187 wairakite 3.95 2.25 -1.70 -0.100 0.28963E+04 188 walstromite 11.51 7.55 -3.96 -0.792 0.67610E+04 189 wollastonite 10.46 7.55 -2.91 -0.582 0.49714E+04 190 pseudo-wollastonite 11.00 7.55 -3.45 -0.690 0.58912E+04 191 zoisite 22.85 20.04 -2.81 -0.128 0.47981E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.96 -3.31 -0.205 0.56596E+04 194 beidellite-H -2.33 -6.81 -4.49 -0.286 0.76615E+04 195 beidellite-K -1.52 -5.96 -4.44 -0.272 0.75833E+04 196 beidellite-Mg -1.79 -5.38 -3.59 -0.222 0.61382E+04 197 beidellite-Na -1.34 -5.45 -4.11 -0.251 0.70099E+04 199 chalcedony -2.80 -3.68 -0.88 -0.293 0.15000E+04 201 montmorillonite-Ca -2.29 -5.21 -2.92 -0.181 0.49921E+04 202 montmorillonite-K -2.24 -6.22 -3.98 -0.244 0.67939E+04 203 montmorillonite-Mg -2.48 -5.64 -3.16 -0.195 0.53938E+04 204 montmorillonite-Na -2.04 -5.70 -3.66 -0.224 0.62562E+04 205 nontronite-Ca 3.21 1.86 -1.36 -0.088 0.23153E+04 206 nontronite-H 2.53 0.01 -2.53 -0.169 0.43151E+04 207 nontronite-K 3.34 0.86 -2.48 -0.159 0.42404E+04 208 nontronite-Mg 3.07 1.43 -1.64 -0.106 0.28011E+04 209 nontronite-Na 3.52 1.37 -2.15 -0.138 0.36686E+04 214 gypsum -4.96 -9.17 -4.21 -1.053 0.71890E+04 224 tobermorite 9.82 5.67 -4.15 -1.132 0.70842E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.43 -3.38 -0.845 0.57724E+04 240 silica-amorphous -2.09 -3.68 -1.59 -0.530 0.27142E+04 242 an20ab80 2.02 -1.30 -3.32 -0.255 0.56675E+04 243 an25ab75 2.65 -0.62 -3.26 -0.251 0.55745E+04 244 an30ab70 3.28 0.06 -3.22 -0.247 0.54912E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0250000 g New total amount of reactant added: 0.0260000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0260000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3086451E-03 Osmotic coef. = 0.9895 True ionic strength = .3234115E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14082E-07 -7.8513 0.13505E-07 -7.8695 0.95900E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13229E-03 -3.8785 0.95886E+00 -0.0182 4 SO4-- 0.25291E-04 -4.5970 0.22563E-04 -4.6466 0.89213E+00 -0.0496 5 HCO3- 0.12596E-04 -4.8998 0.12078E-04 -4.9180 0.95889E+00 -0.0182 6 HS- 0.42844E-11 -11.3681 0.41082E-11 -11.3863 0.95886E+00 -0.0182 7 Al+++ 0.23288E-20 -20.6329 0.18414E-20 -20.7348 0.79072E+00 -0.1020 8 H4SiO4 0.21379E-03 -3.6700 0.21379E-03 -3.6700 0.10000E+01 0.0000 9 Ca++ 0.33061E-04 -4.4807 0.29490E-04 -4.5303 0.89198E+00 -0.0496 10 Mg++ 0.91673E-07 -7.0378 0.81761E-07 -7.0875 0.89188E+00 -0.0497 11 Fe++ 0.54321E-09 -9.2650 0.48449E-09 -9.3147 0.89191E+00 -0.0497 12 K+ 0.55181E-05 -5.2582 0.52913E-05 -5.2764 0.95890E+00 -0.0182 13 Na+ 0.19265E-03 -3.7152 0.18473E-03 -3.7335 0.95886E+00 -0.0182 14 Mn++ 0.60968E-07 -7.2149 0.54379E-07 -7.2646 0.89192E+00 -0.0497 15 HPO4-- 0.11383E-08 -8.9437 0.10155E-08 -8.9933 0.89214E+00 -0.0496 16 HSiO3- 0.15416E-04 -4.8120 0.14782E-04 -4.8303 0.95886E+00 -0.0182 17 Ca(HSiO3)+ 0.10353E-07 -7.9849 0.99275E-08 -8.0032 0.95891E+00 -0.0182 18 Mg(HSiO3)+ 0.35722E-10 -10.4471 0.34254E-10 -10.4653 0.95891E+00 -0.0182 19 NaHSiO3,aq 0.44163E-07 -7.3549 0.44163E-07 -7.3549 0.10000E+01 0.0000 20 AlO+ 0.14325E-11 -11.8439 0.13736E-11 -11.8621 0.95891E+00 -0.0182 21 AlOH+2 0.10356E-15 -15.9848 0.92368E-16 -16.0345 0.89194E+00 -0.0497 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.34628E-05 -5.4606 0.33202E-05 -5.4788 0.95882E+00 -0.0183 24 CH4,aq 0.21364E-17 -17.6703 0.21362E-17 -17.6704 0.99990E+00 0.0000 29 CO,aq 0.63928E-17 -17.1943 0.63928E-17 -17.1943 0.10000E+01 0.0000 30 CO2,aq 0.34856E-06 -6.4577 0.34852E-06 -6.4578 0.99990E+00 0.0000 31 CO3-2 0.87567E-07 -7.0577 0.78117E-07 -7.1073 0.89209E+00 -0.0496 32 CaCO3,aq 0.28886E-07 -7.5393 0.28886E-07 -7.5393 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.94814E-08 -8.0231 0.90917E-08 -8.0414 0.95891E+00 -0.0182 34 CaCl+ 0.65838E-08 -8.1815 0.63132E-08 -8.1998 0.95891E+00 -0.0182 35 CaCl2,aq 0.19841E-12 -12.7024 0.19841E-12 -12.7024 0.10000E+01 0.0000 36 CaOH+ 0.16230E-06 -6.7897 0.15563E-06 -6.8079 0.95891E+00 -0.0182 37 CaSO4,aq 0.21129E-06 -6.6751 0.21129E-06 -6.6751 0.10000E+01 0.0000 38 HCl,aq 0.32736E-12 -12.4850 0.32736E-12 -12.4850 0.10000E+01 0.0000 43 FeCl+ 0.10579E-12 -12.9755 0.10144E-12 -12.9938 0.95891E+00 -0.0182 46 FeO,aq 0.10325E-09 -9.9861 0.10325E-09 -9.9861 0.10000E+01 0.0000 47 FeOH+ 0.12178E-08 -8.9144 0.11678E-08 -8.9326 0.95891E+00 -0.0182 48 HFeO2- 0.83425E-10 -10.0787 0.79993E-10 -10.0969 0.95886E+00 -0.0182 49 FeO+ 0.10750E-12 -12.9686 0.10308E-12 -12.9868 0.95891E+00 -0.0182 50 FeOH+2 0.29805E-18 -18.5257 0.26584E-18 -18.5754 0.89194E+00 -0.0497 51 FeO2- 0.12061E-09 -9.9186 0.11565E-09 -9.9368 0.95886E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.73024E-09 -9.1365 0.73017E-09 -9.1366 0.99990E+00 0.0000 54 KCl,aq 0.12686E-10 -10.8967 0.12686E-10 -10.8967 0.10000E+01 0.0000 55 KHSO4,aq 0.45585E-17 -17.3412 0.45585E-17 -17.3412 0.10000E+01 0.0000 56 KOH,aq 0.16733E-09 -9.7764 0.16733E-09 -9.7764 0.10000E+01 0.0000 57 KSO4- 0.19321E-08 -8.7140 0.18526E-08 -8.7322 0.95886E+00 -0.0182 58 MgCO3,aq 0.20074E-10 -10.6974 0.20074E-10 -10.6974 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26861E-10 -10.5709 0.25757E-10 -10.5891 0.95891E+00 -0.0182 60 MgCl+ 0.16544E-10 -10.7814 0.15864E-10 -10.7996 0.95891E+00 -0.0182 61 MgOH+ 0.24900E-08 -8.6038 0.23876E-08 -8.6220 0.95891E+00 -0.0182 63 MnO,aq 0.30878E-09 -9.5103 0.30878E-09 -9.5103 0.10000E+01 0.0000 64 MnOH+ 0.12698E-07 -7.8963 0.12176E-07 -7.9145 0.95891E+00 -0.0182 65 MnO2-2 0.62986E-16 -16.2008 0.56189E-16 -16.2503 0.89209E+00 -0.0496 66 HMnO2- 0.17338E-12 -12.7610 0.16624E-12 -12.7793 0.95886E+00 -0.0182 69 MnCl+ 0.46196E-10 -10.3354 0.44297E-10 -10.3536 0.95891E+00 -0.0182 70 MnSO4,aq 0.35421E-09 -9.4507 0.35421E-09 -9.4507 0.10000E+01 0.0000 71 NaCl,aq 0.80983E-08 -8.0916 0.80983E-08 -8.0916 0.10000E+01 0.0000 72 NaOH,aq 0.58770E-08 -8.2308 0.58770E-08 -8.2308 0.10000E+01 0.0000 74 OH- 0.44621E-04 -4.3505 0.42783E-04 -4.3687 0.95882E+00 -0.0183 82 H3PO4,aq 0.12953E-14 -14.8876 0.12953E-14 -14.8876 0.10000E+01 0.0000 83 H2PO4- 0.26384E-09 -9.5787 0.25299E-09 -9.5969 0.95888E+00 -0.0182 84 PO4-3 0.77500E-13 -13.1107 0.61354E-13 -13.2122 0.79166E+00 -0.1015 88 HP2O7-3 0.93844E-19 -19.0276 0.74205E-19 -19.1296 0.79073E+00 -0.1020 90 H2S,aq 0.17148E-12 -12.7658 0.17147E-12 -12.7658 0.99990E+00 0.0000 96 SO2,aq 0.13419E-19 -19.8723 0.13419E-19 -19.8723 0.10000E+01 0.0000 97 SO3-2 0.23990E-14 -14.6200 0.21409E-14 -14.6694 0.89240E+00 -0.0494 98 HSO3- 0.18879E-14 -14.7240 0.18103E-14 -14.7423 0.95886E+00 -0.0182 99 HSO4- 0.30623E-09 -9.5140 0.29365E-09 -9.5322 0.95893E+00 -0.0182 101 S2O3-2 0.50944E-19 -19.2929 0.45446E-19 -19.3425 0.89209E+00 -0.0496 Charge balance for all species = 0.2015E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1408209E-07 -.7394296E-04 -.7452748E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999638E+06 0.0000 3 Cl- 0.1379607E-03 0.1379755E-03 0.4891475E+01 3.9910 4 SO4-- 0.2529082E-04 0.2550456E-04 0.2449924E+01 11.0924 5 HCO3- 0.1259559E-04 0.1307012E-04 0.7974747E+00 2.9515 6 HS- 0.4284447E-11 0.1470975E-09 0.4864640E-05 -3.5168 7 Al+++ 0.2328777E-20 0.3483015E-05 0.9397371E-01 2.8737 8 H4SiO4 0.2137899E-03 0.2292605E-03 0.2203470E+02 -3.6700 9 Ca++ 0.3306131E-04 0.3349021E-04 0.1342174E+01 11.2087 10 Mg++ 0.9167288E-07 0.9426203E-07 0.2291619E-02 8.6516 11 Fe++ 0.5432055E-09 0.2267179E-08 0.1266108E-03 6.4243 12 K+ 0.5518110E-05 0.5520222E-05 0.2158442E+00 2.5931 13 Na+ 0.1926510E-03 0.1927091E-03 0.4430191E+01 4.1360 14 Mn++ 0.6096802E-07 0.7437532E-07 0.4085890E-02 8.4745 15 HPO4-- 0.1138311E-08 0.1402233E-08 0.1345802E-03 6.7457 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4174814E-03 -.7394226E-04 -.3435391E-03 0.0000000E+00 2 H2O 0.5550792E+02 0.5550776E+02 0.1606224E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2622502E-04 0.2550432E-04 0.7206957E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7205486E-06 0.1470961E-09 -.7206957E-06 0.0000000E+00 7 Al+++ 0.8477928E-04 0.3482982E-05 0.8129630E-04 0.0000000E+00 8 H4SiO4 0.2707324E-03 0.2292583E-03 0.4147406E-04 0.0000000E+00 9 Ca++ 0.4437477E-04 0.3348989E-04 0.1088488E-04 0.0000000E+00 10 Mg++ 0.2063492E-04 0.9426114E-07 0.2054066E-04 0.0000000E+00 11 Fe++ 0.1853822E-04 0.2267158E-08 0.1853596E-04 0.0000000E+00 12 K+ 0.5520170E-05 0.5520170E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1927073E-03 0.1927073E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4508035E-06 0.7437462E-07 0.3764289E-06 0.0000000E+00 15 HPO4-- 0.1538570E-06 0.1402220E-08 0.1524548E-06 0.0000000E+00 Chg. balance for solid moles: -.7475E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0260000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5082E-07 -7.294 0.2553E-04 -4.593 0.2368 0.8112E-05 clinochlore 0.4108E-05 -5.386 0.2283E-02 -2.641 21.18 0.8686E-03 daphnite 0.2554E-05 -5.593 0.1822E-02 -2.739 16.91 0.5522E-03 chlorite-Mn 0.7529E-07 -7.123 0.5338E-04 -4.273 0.4952 0.1701E-04 diaspore 0.4656E-04 -4.332 0.2793E-02 -2.554 25.91 0.8315E-03 hematite 0.2883E-05 -5.540 0.4604E-03 -3.337 4.271 0.8726E-04 lawsonite 0.1063E-04 -4.973 0.3341E-02 -2.476 30.99 0.1077E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3791E+00 0.3791E+00 1.0000 -0.421 chlorite-Mn 0.1117E-01 0.1117E-01 1.0000 -1.952 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.010779 g Volume = 0.003442 cm3 Porosity: 99.6593% V(tot) - V(min): 0.10070E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0260000 g log = -1.5850 Original solution: 1000.0103000 g Original solution / Rock added: 38461.93 (Water/Rock Ratio), log = 4.5850 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3629E-04 1.0071 0.3729E-04 0.3703E-04 CH4,gas 0.3044E-14 1.0125 0.3144E-14 0.3105E-14 H2,gas 0.9390E-06 1.0005 0.9586E-06 0.9581E-06 H2S,gas 0.4638E-11 0.9960 0.4714E-11 0.4732E-11 S2,gas 0.8894E-30 1.0000 0.9075E-30 0.9075E-30 CO,gas 0.9337E-14 1.0000 0.9527E-14 0.9527E-14 SO3,gas 0.1525E-35 1.0000 0.1556E-35 0.1556E-35 SO2,gas 0.5687E-19 1.0000 0.5803E-19 0.5803E-19 HCl,gas 0.5661E-15 1.0000 0.5776E-15 0.5776E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.79 -6.13 -2.042 0.10462E+05 -4.428 3 CH4,gas 4.54 -11.66 -16.20 -4.050 0.27664E+05 -14.502 4 H2,gas 8.00 0.28 -7.72 -4.410 0.13177E+05 -6.018 5 H2S,gas -6.23 -19.26 -13.03 -6.513 0.22241E+05 -11.327 6 S2,gas -7.34 -39.08 -31.74 -4.883 0.54197E+05 -30.042 7 CO,gas 3.21 -12.51 -15.72 -4.837 0.26842E+05 -14.021 8 SO3,gas 17.12 -20.39 -37.51 -9.377 0.64042E+05 -35.808 9 SO2,gas 0.83 -20.10 -20.94 -5.583 0.35747E+05 -19.236 10 HCl,gas 5.19 -11.75 -16.94 -8.469 0.28920E+05 -15.238 11 acmite 7.71 3.08 -4.63 -0.481 0.79066E+04 15 albite-high 0.69 -4.00 -4.69 -0.361 0.80138E+04 16 albite -0.38 -4.00 -3.62 -0.278 0.61750E+04 19 spessartine 24.46 20.16 -4.30 -0.215 0.73363E+04 20 analcite 3.32 -0.33 -3.65 -0.406 0.62359E+04 21 andalusite 5.00 2.08 -2.92 -0.292 0.49929E+04 22 andradite 39.01 35.18 -3.83 -0.199 0.65336E+04 23 grossular 32.73 28.36 -4.37 -0.218 0.74582E+04 24 anhydrite -5.32 -9.18 -3.86 -1.930 0.65911E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.58 -2.55 -0.848 0.43461E+04 36 brucite 12.57 8.65 -3.92 -0.783 0.66882E+04 37 calcite 0.81 -1.58 -2.39 -0.797 0.40819E+04 40 carpholite-Mg 8.58 7.06 -1.52 -0.102 0.26007E+04 41 carpholite-Fe 6.71 4.83 -1.88 -0.125 0.32117E+04 50 chloritoid-Mg 13.20 10.73 -2.47 -0.165 0.42153E+04 51 chloritoid-Fe 9.17 8.50 -0.67 -0.045 0.11473E+04 52 chloritoid-Mn 11.40 10.55 -0.85 -0.057 0.14500E+04 54 coesite -2.38 -3.67 -1.29 -0.431 0.22094E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.67 -1.11 -0.370 0.18947E+04 67 diopside 16.18 12.52 -3.66 -0.366 0.62512E+04 68 hedenbergite 14.21 10.29 -3.92 -0.392 0.66852E+04 75 epidote 24.67 23.44 -1.23 -0.060 0.21037E+04 76 clinozoisite 22.81 20.03 -2.78 -0.126 0.47426E+04 77 epidote-Fe 29.84 26.85 -2.99 -0.156 0.51114E+04 78 fayalite 14.05 9.18 -4.87 -0.695 0.83105E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.93 -4.21 -0.351 0.71826E+04 91 heulandite -5.83 -8.73 -2.91 -0.132 0.49632E+04 95 jadeite 4.22 -0.33 -4.55 -0.455 0.77614E+04 98 kaolinite -1.33 -1.59 -0.26 -0.024 0.44371E+03 99 kyanite 4.88 2.08 -2.80 -0.280 0.47788E+04 101 laumontite 2.88 2.28 -0.61 -0.040 0.10371E+04 105 lizardite 23.24 18.61 -4.63 -0.386 0.79041E+04 106 magnesite 0.69 -4.14 -4.83 -1.609 0.82412E+04 107 magnetite 20.09 18.99 -1.10 -0.090 0.18729E+04 110 magnesioferrite 26.21 21.22 -4.99 -0.408 0.85282E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.54 -3.06 -0.235 0.52193E+04 120 muscovite 2.58 0.20 -2.38 -0.140 0.40609E+04 121 paragonite 4.24 1.75 -2.49 -0.147 0.42556E+04 122 nepheline 8.34 3.34 -5.00 -0.714 0.85369E+04 136 prehnite 19.37 17.15 -2.22 -0.130 0.37857E+04 137 prehnite-Fe 22.50 20.56 -1.93 -0.116 0.33017E+04 138 pumpellyite-Fe 46.27 43.61 -2.66 -0.059 0.45451E+04 139 pumpellyite-Mg 48.99 45.83 -3.16 -0.070 0.53957E+04 145 pyroxmangite 7.40 4.80 -2.59 -0.519 0.44296E+04 146 pyrophyllite -6.18 -8.93 -2.76 -0.172 0.47073E+04 147 quartz -2.99 -3.67 -0.68 -0.227 0.11621E+04 151 rhodochrosite -0.98 -4.31 -3.34 -1.112 0.56974E+04 152 rhodonite 7.45 4.80 -2.64 -0.528 0.45098E+04 153 sanidine -1.28 -5.54 -4.27 -0.328 0.72871E+04 155 siderite -2.61 -6.36 -3.76 -1.252 0.64117E+04 156 sillimanite 5.26 2.08 -3.18 -0.318 0.54368E+04 163 stilbite -7.52 -8.73 -1.21 -0.058 0.20694E+04 164 stilpnomelane-Fe 13.02 9.81 -3.21 -0.096 0.54837E+04 167 sudoite-Fe 18.30 13.33 -4.96 -0.160 0.84739E+04 168 sudoite 21.08 17.79 -3.29 -0.106 0.56166E+04 174 tephroite 18.09 13.28 -4.81 -0.687 0.82076E+04 177 topaz-H 4.62 2.08 -2.54 -0.231 0.43389E+04 178 tridymite -2.63 -3.67 -1.04 -0.348 0.17820E+04 187 wairakite 3.95 2.28 -1.67 -0.098 0.28590E+04 188 walstromite 11.51 7.54 -3.97 -0.794 0.67796E+04 189 wollastonite 10.46 7.54 -2.92 -0.584 0.49900E+04 190 pseudo-wollastonite 11.00 7.54 -3.46 -0.692 0.59098E+04 191 zoisite 22.85 20.03 -2.82 -0.128 0.48167E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.92 -3.28 -0.203 0.55974E+04 194 beidellite-H -2.33 -6.77 -4.45 -0.284 0.75931E+04 195 beidellite-K -1.52 -5.92 -4.40 -0.269 0.75082E+04 196 beidellite-Mg -1.79 -5.35 -3.56 -0.220 0.60717E+04 197 beidellite-Na -1.34 -5.41 -4.07 -0.249 0.69428E+04 199 chalcedony -2.80 -3.67 -0.87 -0.289 0.14814E+04 201 montmorillonite-Ca -2.29 -5.18 -2.89 -0.179 0.49274E+04 202 montmorillonite-K -2.24 -6.17 -3.93 -0.241 0.67164E+04 203 montmorillonite-Mg -2.48 -5.60 -3.12 -0.193 0.53249E+04 204 montmorillonite-Na -2.04 -5.66 -3.62 -0.222 0.61866E+04 205 nontronite-Ca 3.21 1.89 -1.32 -0.086 0.22531E+04 206 nontronite-H 2.53 0.05 -2.49 -0.167 0.42467E+04 207 nontronite-K 3.34 0.90 -2.44 -0.157 0.41653E+04 208 nontronite-Mg 3.07 1.47 -1.60 -0.104 0.27346E+04 209 nontronite-Na 3.52 1.41 -2.11 -0.135 0.36015E+04 214 gypsum -4.96 -9.18 -4.22 -1.055 0.72086E+04 224 tobermorite 9.82 5.67 -4.16 -1.134 0.70966E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.42 -3.39 -0.847 0.57837E+04 240 silica-amorphous -2.09 -3.67 -1.58 -0.526 0.26955E+04 242 an20ab80 2.02 -1.28 -3.29 -0.253 0.56258E+04 243 an25ab75 2.65 -0.60 -3.24 -0.249 0.55355E+04 244 an30ab70 3.28 0.08 -3.19 -0.246 0.54548E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0260000 g New total amount of reactant added: 0.0270000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0270000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3074039E-03 Osmotic coef. = 0.9895 True ionic strength = .3222125E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14239E-07 -7.8465 0.13656E-07 -7.8647 0.95904E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13229E-03 -3.8785 0.95890E+00 -0.0182 4 SO4-- 0.25296E-04 -4.5969 0.22572E-04 -4.6464 0.89229E+00 -0.0495 5 HCO3- 0.12594E-04 -4.8998 0.12077E-04 -4.9180 0.95894E+00 -0.0182 6 HS- 0.38460E-11 -11.4150 0.36879E-11 -11.4332 0.95891E+00 -0.0182 7 Al+++ 0.24067E-20 -20.6186 0.19038E-20 -20.7204 0.79103E+00 -0.1018 8 H4SiO4 0.21913E-03 -3.6593 0.21913E-03 -3.6593 0.10000E+01 0.0000 9 Ca++ 0.32172E-04 -4.4925 0.28702E-04 -4.5421 0.89214E+00 -0.0496 10 Mg++ 0.92338E-07 -7.0346 0.82369E-07 -7.0842 0.89204E+00 -0.0496 11 Fe++ 0.54708E-09 -9.2619 0.48803E-09 -9.3116 0.89206E+00 -0.0496 12 K+ 0.57303E-05 -5.2418 0.54951E-05 -5.2600 0.95894E+00 -0.0182 13 Na+ 0.19391E-03 -3.7124 0.18594E-03 -3.7306 0.95890E+00 -0.0182 14 Mn++ 0.61729E-07 -7.2095 0.55067E-07 -7.2591 0.89208E+00 -0.0496 15 HPO4-- 0.12084E-08 -8.9178 0.10783E-08 -8.9673 0.89229E+00 -0.0495 16 HSiO3- 0.15626E-04 -4.8062 0.14983E-04 -4.8244 0.95890E+00 -0.0182 17 Ca(HSiO3)+ 0.10213E-07 -7.9908 0.97939E-08 -8.0090 0.95895E+00 -0.0182 18 Mg(HSiO3)+ 0.36477E-10 -10.4380 0.34979E-10 -10.4562 0.95895E+00 -0.0182 19 NaHSiO3,aq 0.45059E-07 -7.3462 0.45059E-07 -7.3462 0.10000E+01 0.0000 20 AlO+ 0.14484E-11 -11.8391 0.13889E-11 -11.8573 0.95895E+00 -0.0182 21 AlOH+2 0.10586E-15 -15.9752 0.94442E-16 -16.0248 0.89210E+00 -0.0496 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.34244E-05 -5.4654 0.32835E-05 -5.4837 0.95886E+00 -0.0182 24 CH4,aq 0.19169E-17 -17.7174 0.19167E-17 -17.7174 0.99990E+00 0.0000 29 CO,aq 0.62736E-17 -17.2025 0.62736E-17 -17.2025 0.10000E+01 0.0000 30 CO2,aq 0.35242E-06 -6.4529 0.35239E-06 -6.4530 0.99990E+00 0.0000 31 CO3-2 0.86578E-07 -7.0626 0.77248E-07 -7.1121 0.89224E+00 -0.0495 32 CaCO3,aq 0.27801E-07 -7.5559 0.27801E-07 -7.5559 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.92268E-08 -8.0349 0.88480E-08 -8.0532 0.95895E+00 -0.0182 34 CaCl+ 0.64078E-08 -8.1933 0.61447E-08 -8.2115 0.95895E+00 -0.0182 35 CaCl2,aq 0.19313E-12 -12.7142 0.19313E-12 -12.7142 0.10000E+01 0.0000 36 CaOH+ 0.15621E-06 -6.8063 0.14980E-06 -6.8245 0.95895E+00 -0.0182 37 CaSO4,aq 0.20572E-06 -6.6867 0.20572E-06 -6.6867 0.10000E+01 0.0000 38 HCl,aq 0.33103E-12 -12.4801 0.33103E-12 -12.4801 0.10000E+01 0.0000 43 FeCl+ 0.10657E-12 -12.9724 0.10219E-12 -12.9906 0.95895E+00 -0.0182 46 FeO,aq 0.10172E-09 -9.9926 0.10172E-09 -9.9926 0.10000E+01 0.0000 47 FeOH+ 0.12131E-08 -8.9161 0.11633E-08 -8.9343 0.95895E+00 -0.0182 48 HFeO2- 0.81278E-10 -10.0900 0.77938E-10 -10.1083 0.95890E+00 -0.0182 49 FeO+ 0.10869E-12 -12.9638 0.10423E-12 -12.9820 0.95895E+00 -0.0182 50 FeOH+2 0.30469E-18 -18.5161 0.27181E-18 -18.5657 0.89210E+00 -0.0496 51 FeO2- 0.11928E-09 -9.9234 0.11437E-09 -9.9417 0.95890E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.70877E-09 -9.1495 0.70870E-09 -9.1495 0.99990E+00 0.0000 54 KCl,aq 0.13175E-10 -10.8802 0.13175E-10 -10.8802 0.10000E+01 0.0000 55 KHSO4,aq 0.47888E-17 -17.3198 0.47888E-17 -17.3198 0.10000E+01 0.0000 56 KOH,aq 0.17185E-09 -9.7648 0.17185E-09 -9.7648 0.10000E+01 0.0000 57 KSO4- 0.20072E-08 -8.6974 0.19247E-08 -8.7156 0.95890E+00 -0.0182 58 MgCO3,aq 0.19998E-10 -10.6990 0.19998E-10 -10.6990 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27057E-10 -10.5677 0.25946E-10 -10.5859 0.95895E+00 -0.0182 60 MgCl+ 0.16667E-10 -10.7781 0.15983E-10 -10.7963 0.95895E+00 -0.0182 61 MgOH+ 0.24807E-08 -8.6054 0.23788E-08 -8.6236 0.95895E+00 -0.0182 63 MnO,aq 0.30582E-09 -9.5145 0.30582E-09 -9.5145 0.10000E+01 0.0000 64 MnOH+ 0.12716E-07 -7.8956 0.12194E-07 -7.9139 0.95895E+00 -0.0182 65 MnO2-2 0.61001E-16 -16.2147 0.54428E-16 -16.2642 0.89224E+00 -0.0495 66 HMnO2- 0.16981E-12 -12.7700 0.16283E-12 -12.7883 0.95890E+00 -0.0182 69 MnCl+ 0.46780E-10 -10.3299 0.44860E-10 -10.3481 0.95895E+00 -0.0182 70 MnSO4,aq 0.35883E-09 -9.4451 0.35883E-09 -9.4451 0.10000E+01 0.0000 71 NaCl,aq 0.81517E-08 -8.0888 0.81517E-08 -8.0888 0.10000E+01 0.0000 72 NaOH,aq 0.58502E-08 -8.2328 0.58502E-08 -8.2328 0.10000E+01 0.0000 74 OH- 0.44126E-04 -4.3553 0.42311E-04 -4.3736 0.95886E+00 -0.0182 82 H3PO4,aq 0.14063E-14 -14.8519 0.14063E-14 -14.8519 0.10000E+01 0.0000 83 H2PO4- 0.28326E-09 -9.5478 0.27163E-09 -9.5660 0.95892E+00 -0.0182 84 PO4-3 0.81349E-13 -13.0896 0.64426E-13 -13.1909 0.79196E+00 -0.1013 88 HP2O7-3 0.10694E-18 -18.9709 0.84594E-19 -19.0727 0.79104E+00 -0.1018 90 H2S,aq 0.15566E-12 -12.8078 0.15565E-12 -12.8079 0.99990E+00 0.0000 96 SO2,aq 0.13322E-19 -19.8754 0.13322E-19 -19.8754 0.10000E+01 0.0000 97 SO3-2 0.23290E-14 -14.6328 0.20787E-14 -14.6822 0.89255E+00 -0.0494 98 HSO3- 0.18535E-14 -14.7320 0.17773E-14 -14.7502 0.95890E+00 -0.0182 99 HSO4- 0.30975E-09 -9.5090 0.29704E-09 -9.5272 0.95897E+00 -0.0182 101 S2O3-2 0.46253E-19 -19.3349 0.41269E-19 -19.3844 0.89224E+00 -0.0495 Charge balance for all species = 0.2016E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1423874E-07 -.7349275E-04 -.7407368E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999633E+06 0.0000 3 Cl- 0.1379609E-03 0.1379755E-03 0.4891474E+01 3.9862 4 SO4-- 0.2529632E-04 0.2550458E-04 0.2449924E+01 11.0829 5 HCO3- 0.1259405E-04 0.1307013E-04 0.7974745E+00 2.9466 6 HS- 0.3845979E-11 0.1414405E-09 0.4677556E-05 -3.5685 7 Al+++ 0.2406727E-20 0.3444622E-05 0.9293781E-01 2.8737 8 H4SiO4 0.2191258E-03 0.2348067E-03 0.2256774E+02 -3.6593 9 Ca++ 0.3217199E-04 0.3258757E-04 0.1305999E+01 11.1873 10 Mg++ 0.9233849E-07 0.9491935E-07 0.2307598E-02 8.6451 11 Fe++ 0.5470811E-09 0.2261344E-08 0.1262849E-03 6.4178 12 K+ 0.5730347E-05 0.5732540E-05 0.2241459E+00 2.6047 13 Na+ 0.1939054E-03 0.1939645E-03 0.4459047E+01 4.1341 14 Mn++ 0.6172879E-07 0.7515646E-07 0.4128801E-02 8.4703 15 HPO4-- 0.1208446E-08 0.1491793E-08 0.1431757E-03 6.7621 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4340399E-03 -.7349204E-04 -.3605479E-03 0.0000000E+00 2 H2O 0.5550791E+02 0.5550775E+02 0.1638785E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2625273E-04 0.2550433E-04 0.7484035E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7482620E-06 0.1414391E-09 -.7484035E-06 0.0000000E+00 7 Al+++ 0.8804002E-04 0.3444589E-05 0.8459543E-04 0.0000000E+00 8 H4SiO4 0.2811451E-03 0.2348044E-03 0.4634074E-04 0.0000000E+00 9 Ca++ 0.4552491E-04 0.3258725E-04 0.1293766E-04 0.0000000E+00 10 Mg++ 0.2142857E-04 0.9491843E-07 0.2133365E-04 0.0000000E+00 11 Fe++ 0.1925123E-04 0.2261323E-08 0.1924897E-04 0.0000000E+00 12 K+ 0.5732484E-05 0.5732484E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1939626E-03 0.1939626E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4681421E-06 0.7515574E-07 0.3929864E-06 0.0000000E+00 15 HPO4-- 0.1597746E-06 0.1491778E-08 0.1582828E-06 0.0000000E+00 Chg. balance for solid moles: -.5453E-20 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0270000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5276E-07 -7.278 0.2650E-04 -4.577 0.2300 0.8422E-05 clinochlore 0.4267E-05 -5.370 0.2372E-02 -2.625 20.58 0.9021E-03 daphnite 0.2652E-05 -5.576 0.1892E-02 -2.723 16.43 0.5735E-03 chlorite-Mn 0.7860E-07 -7.105 0.5572E-04 -4.254 0.4836 0.1776E-04 diaspore 0.4525E-04 -4.344 0.2715E-02 -2.566 23.56 0.8082E-03 hematite 0.2994E-05 -5.524 0.4781E-03 -3.320 4.149 0.9061E-04 lawsonite 0.1267E-04 -4.897 0.3983E-02 -2.400 34.57 0.1284E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3790E+00 0.3790E+00 1.0000 -0.421 chlorite-Mn 0.1123E-01 0.1123E-01 1.0000 -1.950 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.011522 g Volume = 0.003685 cm3 Porosity: 99.6355% V(tot) - V(min): 0.10071E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0270000 g log = -1.5686 Original solution: 1000.0103000 g Original solution / Rock added: 37037.42 (Water/Rock Ratio), log = 4.5686 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3669E-04 1.0071 0.3770E-04 0.3744E-04 CH4,gas 0.2731E-14 1.0125 0.2821E-14 0.2786E-14 H2,gas 0.9114E-06 1.0005 0.9304E-06 0.9299E-06 H2S,gas 0.4210E-11 0.9960 0.4279E-11 0.4296E-11 S2,gas 0.7779E-30 1.0000 0.7937E-30 0.7937E-30 CO,gas 0.9163E-14 1.0000 0.9349E-14 0.9349E-14 SO3,gas 0.1560E-35 1.0000 0.1591E-35 0.1591E-35 SO2,gas 0.5646E-19 1.0000 0.5761E-19 0.5761E-19 HCl,gas 0.5725E-15 1.0000 0.5841E-15 0.5841E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.78 -6.12 -2.041 0.10454E+05 -4.424 3 CH4,gas 4.54 -11.70 -16.25 -4.062 0.27744E+05 -14.550 4 H2,gas 8.00 0.27 -7.73 -4.417 0.13199E+05 -6.031 5 H2S,gas -6.23 -19.30 -13.07 -6.534 0.22313E+05 -11.369 6 S2,gas -7.34 -39.13 -31.80 -4.892 0.54296E+05 -30.100 7 CO,gas 3.21 -12.51 -15.73 -4.839 0.26855E+05 -14.029 8 SO3,gas 17.12 -20.38 -37.50 -9.374 0.64025E+05 -35.798 9 SO2,gas 0.83 -20.11 -20.94 -5.584 0.35752E+05 -19.240 10 HCl,gas 5.19 -11.74 -16.93 -8.466 0.28912E+05 -15.233 11 acmite 7.71 3.10 -4.61 -0.479 0.78735E+04 15 albite-high 0.69 -3.97 -4.66 -0.359 0.79623E+04 16 albite -0.38 -3.97 -3.59 -0.276 0.61235E+04 19 spessartine 24.46 20.18 -4.28 -0.214 0.73029E+04 20 analcite 3.32 -0.31 -3.63 -0.404 0.62028E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49746E+04 22 andradite 39.01 35.15 -3.86 -0.200 0.65885E+04 23 grossular 32.73 28.33 -4.40 -0.220 0.75130E+04 24 anhydrite -5.32 -9.19 -3.87 -1.936 0.66109E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.60 -2.56 -0.854 0.43745E+04 36 brucite 12.57 8.65 -3.92 -0.785 0.66991E+04 37 calcite 0.81 -1.60 -2.41 -0.802 0.41103E+04 40 carpholite-Mg 8.58 7.07 -1.51 -0.101 0.25751E+04 41 carpholite-Fe 6.71 4.85 -1.87 -0.124 0.31862E+04 50 chloritoid-Mg 13.20 10.73 -2.46 -0.164 0.42080E+04 51 chloritoid-Fe 9.17 8.51 -0.67 -0.045 0.11401E+04 52 chloritoid-Mn 11.40 10.56 -0.84 -0.056 0.14389E+04 54 coesite -2.38 -3.66 -1.28 -0.428 0.21911E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.66 -1.10 -0.366 0.18765E+04 67 diopside 16.18 12.51 -3.67 -0.367 0.62622E+04 68 hedenbergite 14.21 10.29 -3.92 -0.392 0.66963E+04 75 epidote 24.67 23.43 -1.24 -0.060 0.21220E+04 76 clinozoisite 22.81 20.02 -2.79 -0.127 0.47609E+04 77 epidote-Fe 29.84 26.84 -3.00 -0.156 0.51297E+04 78 fayalite 14.05 9.18 -4.87 -0.696 0.83143E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.93 -4.20 -0.350 0.71793E+04 91 heulandite -5.83 -8.68 -2.85 -0.130 0.48718E+04 95 jadeite 4.22 -0.31 -4.53 -0.453 0.77283E+04 98 kaolinite -1.33 -1.57 -0.24 -0.022 0.40715E+03 99 kyanite 4.88 2.09 -2.79 -0.279 0.47605E+04 101 laumontite 2.88 2.30 -0.59 -0.039 0.10005E+04 105 lizardite 23.24 18.62 -4.63 -0.386 0.79005E+04 106 magnesite 0.69 -4.14 -4.83 -1.609 0.82440E+04 107 magnetite 20.09 18.98 -1.10 -0.090 0.18840E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.50 -3.01 -0.232 0.51447E+04 120 muscovite 2.58 0.25 -2.33 -0.137 0.39863E+04 121 paragonite 4.24 1.78 -2.46 -0.145 0.42041E+04 122 nepheline 8.34 3.35 -4.99 -0.713 0.85220E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38039E+04 137 prehnite-Fe 22.50 20.55 -1.94 -0.117 0.33200E+04 138 pumpellyite-Fe 46.27 43.58 -2.69 -0.060 0.45927E+04 139 pumpellyite-Mg 48.99 45.81 -3.19 -0.071 0.54433E+04 145 pyroxmangite 7.40 4.81 -2.59 -0.518 0.44184E+04 146 pyrophyllite -6.18 -8.89 -2.71 -0.170 0.46341E+04 147 quartz -2.99 -3.66 -0.67 -0.223 0.11438E+04 151 rhodochrosite -0.98 -4.31 -3.34 -1.112 0.56964E+04 152 rhodonite 7.45 4.81 -2.63 -0.527 0.44987E+04 153 sanidine -1.28 -5.50 -4.22 -0.325 0.72125E+04 155 siderite -2.61 -6.36 -3.76 -1.252 0.64146E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54186E+04 163 stilbite -7.52 -8.68 -1.16 -0.055 0.19780E+04 164 stilpnomelane-Fe 13.02 9.86 -3.15 -0.094 0.53829E+04 167 sudoite-Fe 18.30 13.35 -4.94 -0.159 0.84412E+04 168 sudoite 21.08 17.81 -3.27 -0.105 0.55838E+04 174 tephroite 18.09 13.28 -4.80 -0.686 0.82036E+04 177 topaz-H 4.62 2.09 -2.53 -0.230 0.43206E+04 178 tridymite -2.63 -3.66 -1.03 -0.344 0.17638E+04 187 wairakite 3.95 2.30 -1.65 -0.097 0.28225E+04 188 walstromite 11.51 7.53 -3.98 -0.796 0.67979E+04 189 wollastonite 10.46 7.53 -2.93 -0.587 0.50083E+04 190 pseudo-wollastonite 11.00 7.53 -3.47 -0.694 0.59281E+04 191 zoisite 22.85 20.02 -2.83 -0.129 0.48350E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.89 -3.24 -0.201 0.55364E+04 194 beidellite-H -2.33 -6.73 -4.41 -0.281 0.75260E+04 195 beidellite-K -1.52 -5.87 -4.35 -0.267 0.74346E+04 196 beidellite-Mg -1.79 -5.31 -3.52 -0.218 0.60064E+04 197 beidellite-Na -1.34 -5.37 -4.03 -0.247 0.68768E+04 199 chalcedony -2.80 -3.66 -0.86 -0.286 0.14631E+04 201 montmorillonite-Ca -2.29 -5.14 -2.85 -0.176 0.48640E+04 202 montmorillonite-K -2.24 -6.13 -3.89 -0.238 0.66404E+04 203 montmorillonite-Mg -2.48 -5.56 -3.08 -0.190 0.52572E+04 204 montmorillonite-Na -2.04 -5.62 -3.58 -0.219 0.61182E+04 205 nontronite-Ca 3.21 1.93 -1.28 -0.083 0.21920E+04 206 nontronite-H 2.53 0.08 -2.45 -0.164 0.41796E+04 207 nontronite-K 3.34 0.94 -2.40 -0.154 0.40916E+04 208 nontronite-Mg 3.07 1.51 -1.56 -0.101 0.26693E+04 209 nontronite-Na 3.52 1.45 -2.07 -0.133 0.35355E+04 214 gypsum -4.96 -9.19 -4.23 -1.058 0.72284E+04 224 tobermorite 9.82 5.66 -4.16 -1.136 0.71088E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.42 -3.39 -0.848 0.57947E+04 240 silica-amorphous -2.09 -3.66 -1.57 -0.523 0.26773E+04 242 an20ab80 2.02 -1.25 -3.27 -0.252 0.55846E+04 243 an25ab75 2.65 -0.57 -3.22 -0.248 0.54969E+04 244 an30ab70 3.28 0.11 -3.17 -0.244 0.54187E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0270000 g New total amount of reactant added: 0.0280000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0280000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3062098E-03 Osmotic coef. = 0.9895 True ionic strength = .3210674E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14389E-07 -7.8420 0.13800E-07 -7.8601 0.95908E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13230E-03 -3.8785 0.95894E+00 -0.0182 4 SO4-- 0.25302E-04 -4.5969 0.22580E-04 -4.6463 0.89244E+00 -0.0494 5 HCO3- 0.12593E-04 -4.8999 0.12076E-04 -4.9181 0.95898E+00 -0.0182 6 HS- 0.34581E-11 -11.4612 0.33161E-11 -11.4794 0.95895E+00 -0.0182 7 Al+++ 0.24833E-20 -20.6050 0.19651E-20 -20.7066 0.79133E+00 -0.1016 8 H4SiO4 0.22449E-03 -3.6488 0.22449E-03 -3.6488 0.10000E+01 0.0000 9 Ca++ 0.31301E-04 -4.5044 0.27929E-04 -4.5539 0.89228E+00 -0.0495 10 Mg++ 0.92933E-07 -7.0318 0.82914E-07 -7.0814 0.89219E+00 -0.0495 11 Fe++ 0.55054E-09 -9.2592 0.49120E-09 -9.3087 0.89221E+00 -0.0495 12 K+ 0.59426E-05 -5.2260 0.56988E-05 -5.2442 0.95898E+00 -0.0182 13 Na+ 0.19516E-03 -3.7096 0.18715E-03 -3.7278 0.95894E+00 -0.0182 14 Mn++ 0.62433E-07 -7.2046 0.55704E-07 -7.2541 0.89223E+00 -0.0495 15 HPO4-- 0.12824E-08 -8.8920 0.11445E-08 -8.9414 0.89244E+00 -0.0494 16 HSiO3- 0.15840E-04 -4.8003 0.15189E-04 -4.8185 0.95894E+00 -0.0182 17 Ca(HSiO3)+ 0.10074E-07 -7.9968 0.96612E-08 -8.0150 0.95899E+00 -0.0182 18 Mg(HSiO3)+ 0.37221E-10 -10.4292 0.35694E-10 -10.4474 0.95899E+00 -0.0182 19 NaHSiO3,aq 0.45975E-07 -7.3375 0.45975E-07 -7.3375 0.10000E+01 0.0000 20 AlO+ 0.14637E-11 -11.8345 0.14037E-11 -11.8527 0.95899E+00 -0.0182 21 AlOH+2 0.10811E-15 -15.9661 0.96458E-16 -16.0157 0.89225E+00 -0.0495 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.33883E-05 -5.4700 0.32490E-05 -5.4882 0.95890E+00 -0.0182 24 CH4,aq 0.17229E-17 -17.7637 0.17227E-17 -17.7638 0.99990E+00 0.0000 29 CO,aq 0.61566E-17 -17.2107 0.61566E-17 -17.2107 0.10000E+01 0.0000 30 CO2,aq 0.35613E-06 -6.4484 0.35610E-06 -6.4484 0.99990E+00 0.0000 31 CO3-2 0.85648E-07 -7.0673 0.76431E-07 -7.1167 0.89239E+00 -0.0494 32 CaCO3,aq 0.26766E-07 -7.5724 0.26766E-07 -7.5724 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.89774E-08 -8.0469 0.86092E-08 -8.0650 0.95899E+00 -0.0182 34 CaCl+ 0.62353E-08 -8.2051 0.59796E-08 -8.2233 0.95899E+00 -0.0182 35 CaCl2,aq 0.18794E-12 -12.7260 0.18794E-12 -12.7260 0.10000E+01 0.0000 36 CaOH+ 0.15040E-06 -6.8227 0.14423E-06 -6.8409 0.95899E+00 -0.0182 37 CaSO4,aq 0.20026E-06 -6.6984 0.20026E-06 -6.6984 0.10000E+01 0.0000 38 HCl,aq 0.33456E-12 -12.4755 0.33456E-12 -12.4755 0.10000E+01 0.0000 43 FeCl+ 0.10726E-12 -12.9696 0.10286E-12 -12.9878 0.95899E+00 -0.0182 46 FeO,aq 0.10024E-09 -9.9990 0.10024E-09 -9.9990 0.10000E+01 0.0000 47 FeOH+ 0.12081E-08 -8.9179 0.11586E-08 -8.9361 0.95899E+00 -0.0182 48 HFeO2- 0.79251E-10 -10.1010 0.75997E-10 -10.1192 0.95894E+00 -0.0182 49 FeO+ 0.10984E-12 -12.9592 0.10534E-12 -12.9774 0.95899E+00 -0.0182 50 FeOH+2 0.31114E-18 -18.5070 0.27762E-18 -18.5566 0.89225E+00 -0.0495 51 FeO2- 0.11802E-09 -9.9280 0.11317E-09 -9.9463 0.95894E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.68830E-09 -9.1622 0.68823E-09 -9.1623 0.99990E+00 0.0000 54 KCl,aq 0.13665E-10 -10.8644 0.13665E-10 -10.8644 0.10000E+01 0.0000 55 KHSO4,aq 0.50210E-17 -17.2992 0.50210E-17 -17.2992 0.10000E+01 0.0000 56 KOH,aq 0.17635E-09 -9.7536 0.17635E-09 -9.7536 0.10000E+01 0.0000 57 KSO4- 0.20823E-08 -8.6815 0.19968E-08 -8.6997 0.95894E+00 -0.0182 58 MgCO3,aq 0.19918E-10 -10.7008 0.19918E-10 -10.7008 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27233E-10 -10.5649 0.26116E-10 -10.5831 0.95899E+00 -0.0182 60 MgCl+ 0.16777E-10 -10.7753 0.16089E-10 -10.7935 0.95899E+00 -0.0182 61 MgOH+ 0.24707E-08 -8.6072 0.23694E-08 -8.6254 0.95899E+00 -0.0182 63 MnO,aq 0.30290E-09 -9.5187 0.30290E-09 -9.5187 0.10000E+01 0.0000 64 MnOH+ 0.12728E-07 -7.8953 0.12206E-07 -7.9134 0.95899E+00 -0.0182 65 MnO2-2 0.59145E-16 -16.2281 0.52781E-16 -16.2775 0.89239E+00 -0.0494 66 HMnO2- 0.16641E-12 -12.7788 0.15958E-12 -12.7970 0.95894E+00 -0.0182 69 MnCl+ 0.47322E-10 -10.3249 0.45381E-10 -10.3431 0.95899E+00 -0.0182 70 MnSO4,aq 0.36312E-09 -9.4399 0.36312E-09 -9.4399 0.10000E+01 0.0000 71 NaCl,aq 0.82051E-08 -8.0859 0.82051E-08 -8.0859 0.10000E+01 0.0000 72 NaOH,aq 0.58264E-08 -8.2346 0.58264E-08 -8.2346 0.10000E+01 0.0000 74 OH- 0.43661E-04 -4.3599 0.41866E-04 -4.3781 0.95890E+00 -0.0182 82 H3PO4,aq 0.15244E-14 -14.8169 0.15244E-14 -14.8169 0.10000E+01 0.0000 83 H2PO4- 0.30383E-09 -9.5174 0.29136E-09 -9.5356 0.95896E+00 -0.0182 84 PO4-3 0.85403E-13 -13.0685 0.67661E-13 -13.1697 0.79226E+00 -0.1011 88 HP2O7-3 0.12170E-18 -18.9147 0.96307E-19 -19.0163 0.79134E+00 -0.1016 90 H2S,aq 0.14145E-12 -12.8494 0.14144E-12 -12.8494 0.99990E+00 0.0000 96 SO2,aq 0.13218E-19 -19.8788 0.13218E-19 -19.8788 0.10000E+01 0.0000 97 SO3-2 0.22622E-14 -14.6455 0.20195E-14 -14.6948 0.89270E+00 -0.0493 98 HSO3- 0.18197E-14 -14.7400 0.17450E-14 -14.7582 0.95894E+00 -0.0182 99 HSO4- 0.31315E-09 -9.5043 0.30031E-09 -9.5224 0.95901E+00 -0.0182 101 S2O3-2 0.42040E-19 -19.3763 0.37516E-19 -19.4258 0.89239E+00 -0.0494 Charge balance for all species = 0.2017E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1438929E-07 -.7308609E-04 -.7366376E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999627E+06 0.0000 3 Cl- 0.1379610E-03 0.1379756E-03 0.4891473E+01 3.9817 4 SO4-- 0.2530170E-04 0.2550459E-04 0.2449924E+01 11.0739 5 HCO3- 0.1259256E-04 0.1307013E-04 0.7974743E+00 2.9420 6 HS- 0.3458066E-11 0.1360783E-09 0.4500222E-05 -3.6193 7 Al+++ 0.2483254E-20 0.3408513E-05 0.9196351E-01 2.8737 8 H4SiO4 0.2244941E-03 0.2403898E-03 0.2310434E+02 -3.6488 9 Ca++ 0.3130070E-04 0.3170341E-04 0.1270564E+01 11.1663 10 Mg++ 0.9293310E-07 0.9550496E-07 0.2321834E-02 8.6388 11 Fe++ 0.5505381E-09 0.2255034E-08 0.1259324E-03 6.4115 12 K+ 0.5942585E-05 0.5944857E-05 0.2324475E+00 2.6159 13 Na+ 0.1951598E-03 0.1952198E-03 0.4487903E+01 4.1323 14 Mn++ 0.6243296E-07 0.7587411E-07 0.4168223E-02 8.4661 15 HPO4-- 0.1282395E-08 0.1586308E-08 0.1522469E-03 6.7788 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4505984E-03 -.7308536E-04 -.3775131E-03 0.0000000E+00 2 H2O 0.5550790E+02 0.5550773E+02 0.1671670E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2628045E-04 0.2550433E-04 0.7761115E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7759754E-06 0.1360770E-09 -.7761115E-06 0.0000000E+00 7 Al+++ 0.9130077E-04 0.3408479E-05 0.8789229E-04 0.0000000E+00 8 H4SiO4 0.2915579E-03 0.2403874E-03 0.5117055E-04 0.0000000E+00 9 Ca++ 0.4667505E-04 0.3170310E-04 0.1497196E-04 0.0000000E+00 10 Mg++ 0.2222222E-04 0.9550401E-07 0.2212672E-04 0.0000000E+00 11 Fe++ 0.1996424E-04 0.2255012E-08 0.1996199E-04 0.0000000E+00 12 K+ 0.5944798E-05 0.5944798E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1952178E-03 0.1952178E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4854807E-06 0.7587336E-07 0.4096073E-06 0.0000000E+00 15 HPO4-- 0.1656921E-06 0.1586293E-08 0.1641059E-06 0.0000000E+00 Chg. balance for solid moles: -.8566E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0280000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5470E-07 -7.262 0.2748E-04 -4.561 0.2241 0.8731E-05 clinochlore 0.4425E-05 -5.354 0.2460E-02 -2.609 20.06 0.9356E-03 daphnite 0.2751E-05 -5.561 0.1963E-02 -2.707 16.01 0.5947E-03 chlorite-Mn 0.8192E-07 -7.087 0.5808E-04 -4.236 0.4737 0.1851E-04 diaspore 0.4398E-04 -4.357 0.2638E-02 -2.579 21.52 0.7855E-03 hematite 0.3104E-05 -5.508 0.4958E-03 -3.305 4.044 0.9397E-04 lawsonite 0.1470E-04 -4.833 0.4619E-02 -2.335 37.67 0.1489E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3790E+00 0.3790E+00 1.0000 -0.421 chlorite-Mn 0.1129E-01 0.1129E-01 1.0000 -1.947 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.012261 g Volume = 0.003926 cm3 Porosity: 99.6117% V(tot) - V(min): 0.10073E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0280000 g log = -1.5528 Original solution: 1000.0103000 g Original solution / Rock added: 35714.65 (Water/Rock Ratio), log = 4.5528 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3708E-04 1.0071 0.3810E-04 0.3783E-04 CH4,gas 0.2454E-14 1.0125 0.2536E-14 0.2504E-14 H2,gas 0.8851E-06 1.0005 0.9036E-06 0.9031E-06 H2S,gas 0.3826E-11 0.9960 0.3888E-11 0.3904E-11 S2,gas 0.6812E-30 1.0000 0.6950E-30 0.6950E-30 CO,gas 0.8992E-14 1.0000 0.9175E-14 0.9175E-14 SO3,gas 0.1594E-35 1.0000 0.1626E-35 0.1626E-35 SO2,gas 0.5602E-19 1.0000 0.5716E-19 0.5716E-19 HCl,gas 0.5786E-15 1.0000 0.5903E-15 0.5903E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.78 -6.12 -2.039 0.10446E+05 -4.419 3 CH4,gas 4.54 -11.75 -16.29 -4.074 0.27823E+05 -14.596 4 H2,gas 8.00 0.26 -7.74 -4.425 0.13221E+05 -6.044 5 H2S,gas -6.23 -19.34 -13.11 -6.555 0.22384E+05 -11.410 6 S2,gas -7.34 -39.19 -31.86 -4.901 0.54395E+05 -30.158 7 CO,gas 3.21 -12.52 -15.74 -4.842 0.26869E+05 -14.037 8 SO3,gas 17.12 -20.37 -37.49 -9.372 0.64009E+05 -35.789 9 SO2,gas 0.83 -20.11 -20.94 -5.585 0.35758E+05 -19.243 10 HCl,gas 5.19 -11.74 -16.93 -8.464 0.28904E+05 -15.229 11 acmite 7.71 3.12 -4.59 -0.477 0.78406E+04 15 albite-high 0.69 -3.94 -4.63 -0.356 0.79115E+04 16 albite -0.38 -3.94 -3.56 -0.274 0.60727E+04 19 spessartine 24.46 20.20 -4.26 -0.213 0.72705E+04 20 analcite 3.32 -0.29 -3.61 -0.401 0.61699E+04 21 andalusite 5.00 2.10 -2.90 -0.290 0.49567E+04 22 andradite 39.01 35.12 -3.89 -0.202 0.66423E+04 23 grossular 32.73 28.30 -4.43 -0.222 0.75669E+04 24 anhydrite -5.32 -9.20 -3.88 -1.942 0.66308E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.61 -2.58 -0.859 0.44026E+04 36 brucite 12.57 8.64 -3.93 -0.786 0.67099E+04 37 calcite 0.81 -1.61 -2.42 -0.808 0.41384E+04 40 carpholite-Mg 8.58 7.09 -1.49 -0.100 0.25500E+04 41 carpholite-Fe 6.71 4.86 -1.85 -0.123 0.31612E+04 50 chloritoid-Mg 13.20 10.74 -2.46 -0.164 0.42008E+04 51 chloritoid-Fe 9.17 8.51 -0.66 -0.044 0.11330E+04 52 chloritoid-Mn 11.40 10.56 -0.84 -0.056 0.14281E+04 54 coesite -2.38 -3.65 -1.27 -0.424 0.21732E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.65 -1.09 -0.363 0.18585E+04 67 diopside 16.18 12.51 -3.67 -0.367 0.62730E+04 68 hedenbergite 14.21 10.28 -3.93 -0.393 0.67072E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21399E+04 76 clinozoisite 22.81 20.01 -2.80 -0.127 0.47789E+04 77 epidote-Fe 29.84 26.83 -3.01 -0.157 0.51476E+04 78 fayalite 14.05 9.17 -4.87 -0.696 0.83181E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.94 -4.20 -0.350 0.71760E+04 91 heulandite -5.83 -8.63 -2.80 -0.127 0.47820E+04 95 jadeite 4.22 -0.29 -4.51 -0.451 0.76954E+04 98 kaolinite -1.33 -1.55 -0.22 -0.020 0.37125E+03 99 kyanite 4.88 2.10 -2.78 -0.278 0.47426E+04 101 laumontite 2.88 2.32 -0.56 -0.038 0.96460E+03 105 lizardite 23.24 18.62 -4.62 -0.385 0.78969E+04 106 magnesite 0.69 -4.14 -4.83 -1.610 0.82470E+04 107 magnetite 20.09 18.98 -1.11 -0.091 0.18949E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.46 -2.97 -0.228 0.50717E+04 120 muscovite 2.58 0.29 -2.29 -0.135 0.39132E+04 121 paragonite 4.24 1.81 -2.43 -0.143 0.41533E+04 122 nepheline 8.34 3.36 -4.98 -0.712 0.85071E+04 136 prehnite 19.37 17.13 -2.24 -0.132 0.38219E+04 137 prehnite-Fe 22.50 20.54 -1.95 -0.118 0.33380E+04 138 pumpellyite-Fe 46.27 43.55 -2.72 -0.060 0.46395E+04 139 pumpellyite-Mg 48.99 45.78 -3.22 -0.071 0.54900E+04 145 pyroxmangite 7.40 4.82 -2.58 -0.516 0.44076E+04 146 pyrophyllite -6.18 -8.85 -2.67 -0.167 0.45623E+04 147 quartz -2.99 -3.65 -0.66 -0.220 0.11258E+04 151 rhodochrosite -0.98 -4.31 -3.34 -1.112 0.56957E+04 152 rhodonite 7.45 4.82 -2.63 -0.526 0.44879E+04 153 sanidine -1.28 -5.46 -4.18 -0.322 0.71395E+04 155 siderite -2.61 -6.37 -3.76 -1.253 0.64177E+04 156 sillimanite 5.26 2.10 -3.16 -0.316 0.54006E+04 163 stilbite -7.52 -8.63 -1.11 -0.053 0.18882E+04 164 stilpnomelane-Fe 13.02 9.92 -3.09 -0.092 0.52840E+04 167 sudoite-Fe 18.30 13.37 -4.92 -0.159 0.84091E+04 168 sudoite 21.08 17.83 -3.25 -0.105 0.55515E+04 174 tephroite 18.09 13.28 -4.80 -0.686 0.81999E+04 177 topaz-H 4.62 2.10 -2.52 -0.229 0.43026E+04 178 tridymite -2.63 -3.65 -1.02 -0.341 0.17458E+04 187 wairakite 3.95 2.32 -1.63 -0.096 0.27866E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68158E+04 189 wollastonite 10.46 7.52 -2.94 -0.589 0.50262E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59461E+04 191 zoisite 22.85 20.01 -2.84 -0.129 0.48529E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.85 -3.21 -0.198 0.54764E+04 194 beidellite-H -2.33 -6.70 -4.37 -0.279 0.74602E+04 195 beidellite-K -1.52 -5.83 -4.31 -0.264 0.73624E+04 196 beidellite-Mg -1.79 -5.27 -3.48 -0.215 0.59423E+04 197 beidellite-Na -1.34 -5.33 -3.99 -0.244 0.68119E+04 199 chalcedony -2.80 -3.65 -0.85 -0.282 0.14451E+04 201 montmorillonite-Ca -2.29 -5.10 -2.81 -0.174 0.48016E+04 202 montmorillonite-K -2.24 -6.08 -3.85 -0.235 0.65658E+04 203 montmorillonite-Mg -2.48 -5.52 -3.04 -0.188 0.51907E+04 204 montmorillonite-Na -2.04 -5.58 -3.54 -0.217 0.60510E+04 205 nontronite-Ca 3.21 1.97 -1.25 -0.081 0.21321E+04 206 nontronite-H 2.53 0.12 -2.41 -0.161 0.41138E+04 207 nontronite-K 3.34 0.99 -2.35 -0.151 0.40194E+04 208 nontronite-Mg 3.07 1.55 -1.53 -0.099 0.26052E+04 209 nontronite-Na 3.52 1.49 -2.03 -0.130 0.34706E+04 214 gypsum -4.96 -9.20 -4.25 -1.061 0.72484E+04 224 tobermorite 9.82 5.65 -4.17 -1.138 0.71207E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.41 -3.40 -0.850 0.58056E+04 240 silica-amorphous -2.09 -3.65 -1.56 -0.519 0.26593E+04 242 an20ab80 2.02 -1.23 -3.25 -0.250 0.55440E+04 243 an25ab75 2.65 -0.55 -3.20 -0.246 0.54588E+04 244 an30ab70 3.28 0.13 -3.15 -0.243 0.53832E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0280000 g New total amount of reactant added: 0.0290000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0290000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3050612E-03 Osmotic coef. = 0.9895 True ionic strength = .3199748E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14534E-07 -7.8376 0.13939E-07 -7.8558 0.95912E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13230E-03 -3.8784 0.95898E+00 -0.0182 4 SO4-- 0.25307E-04 -4.5968 0.22588E-04 -4.6461 0.89258E+00 -0.0494 5 HCO3- 0.12591E-04 -4.8999 0.12075E-04 -4.9181 0.95901E+00 -0.0182 6 HS- 0.31142E-11 -11.5067 0.29865E-11 -11.5248 0.95898E+00 -0.0182 7 Al+++ 0.25581E-20 -20.5921 0.20250E-20 -20.6936 0.79161E+00 -0.1015 8 H4SiO4 0.22989E-03 -3.6385 0.22989E-03 -3.6385 0.10000E+01 0.0000 9 Ca++ 0.30447E-04 -4.5165 0.27172E-04 -4.5659 0.89243E+00 -0.0494 10 Mg++ 0.93456E-07 -7.0294 0.83393E-07 -7.0789 0.89233E+00 -0.0495 11 Fe++ 0.55357E-09 -9.2568 0.49398E-09 -9.3063 0.89235E+00 -0.0495 12 K+ 0.61548E-05 -5.2108 0.59026E-05 -5.2290 0.95902E+00 -0.0182 13 Na+ 0.19641E-03 -3.7068 0.18836E-03 -3.7250 0.95898E+00 -0.0182 14 Mn++ 0.63080E-07 -7.2001 0.56291E-07 -7.2496 0.89237E+00 -0.0495 15 HPO4-- 0.13604E-08 -8.8663 0.12142E-08 -8.9157 0.89258E+00 -0.0494 16 HSiO3- 0.16058E-04 -4.7943 0.15400E-04 -4.8125 0.95898E+00 -0.0182 17 Ca(HSiO3)+ 0.99364E-08 -8.0028 0.95293E-08 -8.0209 0.95902E+00 -0.0182 18 Mg(HSiO3)+ 0.37953E-10 -10.4208 0.36398E-10 -10.4389 0.95902E+00 -0.0182 19 NaHSiO3,aq 0.46913E-07 -7.3287 0.46913E-07 -7.3287 0.10000E+01 0.0000 20 AlO+ 0.14784E-11 -11.8302 0.14178E-11 -11.8484 0.95902E+00 -0.0182 21 AlOH+2 0.11028E-15 -15.9575 0.98410E-16 -16.0070 0.89239E+00 -0.0494 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.33543E-05 -5.4744 0.32166E-05 -5.4926 0.95894E+00 -0.0182 24 CH4,aq 0.15509E-17 -17.8094 0.15508E-17 -17.8094 0.99991E+00 0.0000 29 CO,aq 0.60418E-17 -17.2188 0.60418E-17 -17.2188 0.10000E+01 0.0000 30 CO2,aq 0.35969E-06 -6.4441 0.35966E-06 -6.4441 0.99991E+00 0.0000 31 CO3-2 0.84774E-07 -7.0717 0.75663E-07 -7.1211 0.89253E+00 -0.0494 32 CaCO3,aq 0.25779E-07 -7.5887 0.25779E-07 -7.5887 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.87329E-08 -8.0588 0.83751E-08 -8.0770 0.95902E+00 -0.0182 34 CaCl+ 0.60662E-08 -8.2171 0.58176E-08 -8.2353 0.95902E+00 -0.0182 35 CaCl2,aq 0.18286E-12 -12.7379 0.18286E-12 -12.7379 0.10000E+01 0.0000 36 CaOH+ 0.14486E-06 -6.8391 0.13892E-06 -6.8572 0.95902E+00 -0.0182 37 CaSO4,aq 0.19490E-06 -6.7102 0.19490E-06 -6.7102 0.10000E+01 0.0000 38 HCl,aq 0.33795E-12 -12.4712 0.33795E-12 -12.4712 0.10000E+01 0.0000 43 FeCl+ 0.10787E-12 -12.9671 0.10345E-12 -12.9853 0.95902E+00 -0.0182 46 FeO,aq 0.98806E-10 -10.0052 0.98806E-10 -10.0052 0.10000E+01 0.0000 47 FeOH+ 0.12028E-08 -8.9198 0.11535E-08 -8.9380 0.95902E+00 -0.0182 48 HFeO2- 0.77337E-10 -10.1116 0.74165E-10 -10.1298 0.95898E+00 -0.0182 49 FeO+ 0.11094E-12 -12.9549 0.10640E-12 -12.9731 0.95902E+00 -0.0182 50 FeOH+2 0.31739E-18 -18.4984 0.28324E-18 -18.5479 0.89239E+00 -0.0494 51 FeO2- 0.11684E-09 -9.9324 0.11205E-09 -9.9506 0.95898E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.66878E-09 -9.1747 0.66871E-09 -9.1748 0.99991E+00 0.0000 54 KCl,aq 0.14154E-10 -10.8491 0.14154E-10 -10.8491 0.10000E+01 0.0000 55 KHSO4,aq 0.52548E-17 -17.2794 0.52548E-17 -17.2794 0.10000E+01 0.0000 56 KOH,aq 0.18084E-09 -9.7427 0.18084E-09 -9.7427 0.10000E+01 0.0000 57 KSO4- 0.21575E-08 -8.6661 0.20690E-08 -8.6842 0.95898E+00 -0.0182 58 MgCO3,aq 0.19832E-10 -10.7026 0.19832E-10 -10.7026 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27387E-10 -10.5625 0.26265E-10 -10.5806 0.95902E+00 -0.0182 60 MgCl+ 0.16874E-10 -10.7728 0.16183E-10 -10.7909 0.95902E+00 -0.0182 61 MgOH+ 0.24601E-08 -8.6090 0.23593E-08 -8.6272 0.95902E+00 -0.0182 63 MnO,aq 0.30001E-09 -9.5229 0.30001E-09 -9.5229 0.10000E+01 0.0000 64 MnOH+ 0.12733E-07 -7.8951 0.12211E-07 -7.9132 0.95902E+00 -0.0182 65 MnO2-2 0.57411E-16 -16.2410 0.51241E-16 -16.2904 0.89253E+00 -0.0494 66 HMnO2- 0.16318E-12 -12.7873 0.15649E-12 -12.8055 0.95898E+00 -0.0182 69 MnCl+ 0.47820E-10 -10.3204 0.45861E-10 -10.3386 0.95902E+00 -0.0182 70 MnSO4,aq 0.36708E-09 -9.4352 0.36708E-09 -9.4352 0.10000E+01 0.0000 71 NaCl,aq 0.82586E-08 -8.0831 0.82586E-08 -8.0831 0.10000E+01 0.0000 72 NaOH,aq 0.58056E-08 -8.2362 0.58056E-08 -8.2362 0.10000E+01 0.0000 74 OH- 0.43224E-04 -4.3643 0.41449E-04 -4.3825 0.95894E+00 -0.0182 82 H3PO4,aq 0.16501E-14 -14.7825 0.16501E-14 -14.7825 0.10000E+01 0.0000 83 H2PO4- 0.32558E-09 -9.4873 0.31224E-09 -9.5055 0.95900E+00 -0.0182 84 PO4-3 0.89675E-13 -13.0473 0.71071E-13 -13.1483 0.79254E+00 -0.1010 88 HP2O7-3 0.13833E-18 -18.8591 0.10950E-18 -18.9606 0.79162E+00 -0.1015 90 H2S,aq 0.12867E-12 -12.8905 0.12866E-12 -12.8905 0.99991E+00 0.0000 96 SO2,aq 0.13108E-19 -19.8825 0.13108E-19 -19.8825 0.10000E+01 0.0000 97 SO3-2 0.21985E-14 -14.6579 0.19629E-14 -14.7071 0.89284E+00 -0.0492 98 HSO3- 0.17865E-14 -14.7480 0.17132E-14 -14.7662 0.95898E+00 -0.0182 99 HSO4- 0.31640E-09 -9.4998 0.30345E-09 -9.5179 0.95905E+00 -0.0182 101 S2O3-2 0.38250E-19 -19.4174 0.34140E-19 -19.4667 0.89253E+00 -0.0494 Charge balance for all species = 0.2017E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1453361E-07 -.7272166E-04 -.7329642E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999622E+06 0.0000 3 Cl- 0.1379612E-03 0.1379756E-03 0.4891472E+01 3.9773 4 SO4-- 0.2530699E-04 0.2550460E-04 0.2449924E+01 11.0654 5 HCO3- 0.1259111E-04 0.1307013E-04 0.7974741E+00 2.9376 6 HS- 0.3114218E-11 0.1309891E-09 0.4331916E-05 -3.6691 7 Al+++ 0.2558114E-20 0.3374599E-05 0.9104845E-01 2.8737 8 H4SiO4 0.2298936E-03 0.2460087E-03 0.2364437E+02 -3.6385 9 Ca++ 0.3044695E-04 0.3083723E-04 0.1235850E+01 11.1456 10 Mg++ 0.9345587E-07 0.9601806E-07 0.2334307E-02 8.6326 11 Fe++ 0.5535716E-09 0.2248233E-08 0.1255525E-03 6.4052 12 K+ 0.6154823E-05 0.6157175E-05 0.2407492E+00 2.6268 13 Na+ 0.1964141E-03 0.1964751E-03 0.4516759E+01 4.1307 14 Mn++ 0.6308040E-07 0.7652842E-07 0.4204166E-02 8.4619 15 HPO4-- 0.1360369E-08 0.1686044E-08 0.1618189E-03 6.7958 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4671569E-03 -.7272092E-04 -.3944360E-03 0.0000000E+00 2 H2O 0.5550789E+02 0.5550772E+02 0.1704872E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2630816E-04 0.2550434E-04 0.8038198E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8036889E-06 0.1309878E-09 -.8038198E-06 0.0000000E+00 7 Al+++ 0.9456151E-04 0.3374564E-05 0.9118694E-04 0.0000000E+00 8 H4SiO4 0.3019707E-03 0.2460062E-03 0.5596451E-04 0.0000000E+00 9 Ca++ 0.4782520E-04 0.3083691E-04 0.1698829E-04 0.0000000E+00 10 Mg++ 0.2301587E-04 0.9601708E-07 0.2291986E-04 0.0000000E+00 11 Fe++ 0.2067725E-04 0.2248210E-08 0.2067500E-04 0.0000000E+00 12 K+ 0.6157113E-05 0.6157113E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1964731E-03 0.1964731E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5028193E-06 0.7652764E-07 0.4262916E-06 0.0000000E+00 15 HPO4-- 0.1716097E-06 0.1686027E-08 0.1699237E-06 0.0000000E+00 Chg. balance for solid moles: -.3595E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0290000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5664E-07 -7.247 0.2845E-04 -4.546 0.2189 0.9041E-05 clinochlore 0.4584E-05 -5.339 0.2548E-02 -2.594 19.60 0.9692E-03 daphnite 0.2849E-05 -5.545 0.2033E-02 -2.692 15.64 0.6160E-03 chlorite-Mn 0.8526E-07 -7.069 0.6045E-04 -4.219 0.4651 0.1926E-04 diaspore 0.4274E-04 -4.369 0.2564E-02 -2.591 19.73 0.7633E-03 hematite 0.3215E-05 -5.493 0.5135E-03 -3.289 3.951 0.9732E-04 lawsonite 0.1671E-04 -4.777 0.5249E-02 -2.280 40.39 0.1693E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3789E+00 0.3789E+00 1.0000 -0.421 chlorite-Mn 0.1134E-01 0.1134E-01 1.0000 -1.945 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.012996 g Volume = 0.004167 cm3 Porosity: 99.5881% V(tot) - V(min): 0.10074E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0290000 g log = -1.5376 Original solution: 1000.0103000 g Original solution / Rock added: 34483.11 (Water/Rock Ratio), log = 4.5376 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3745E-04 1.0071 0.3848E-04 0.3821E-04 CH4,gas 0.2209E-14 1.0125 0.2283E-14 0.2254E-14 H2,gas 0.8600E-06 1.0005 0.8779E-06 0.8775E-06 H2S,gas 0.3480E-11 0.9960 0.3537E-11 0.3551E-11 S2,gas 0.5970E-30 1.0000 0.6092E-30 0.6092E-30 CO,gas 0.8824E-14 1.0000 0.9003E-14 0.9003E-14 SO3,gas 0.1626E-35 1.0000 0.1660E-35 0.1660E-35 SO2,gas 0.5555E-19 1.0000 0.5668E-19 0.5668E-19 HCl,gas 0.5844E-15 1.0000 0.5963E-15 0.5963E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.77 -6.11 -2.038 0.10439E+05 -4.415 3 CH4,gas 4.54 -11.80 -16.34 -4.085 0.27901E+05 -14.642 4 H2,gas 8.00 0.24 -7.76 -4.432 0.13242E+05 -6.057 5 H2S,gas -6.23 -19.38 -13.15 -6.575 0.22454E+05 -11.451 6 S2,gas -7.34 -39.25 -31.91 -4.910 0.54493E+05 -30.215 7 CO,gas 3.21 -12.53 -15.74 -4.844 0.26883E+05 -14.046 8 SO3,gas 17.12 -20.36 -37.48 -9.370 0.63994E+05 -35.780 9 SO2,gas 0.83 -20.11 -20.95 -5.585 0.35764E+05 -19.247 10 HCl,gas 5.19 -11.73 -16.92 -8.462 0.28896E+05 -15.225 11 acmite 7.71 3.14 -4.57 -0.475 0.78080E+04 15 albite-high 0.69 -3.91 -4.60 -0.354 0.78613E+04 16 albite -0.38 -3.91 -3.53 -0.271 0.60225E+04 19 spessartine 24.46 20.22 -4.24 -0.212 0.72389E+04 20 analcite 3.32 -0.27 -3.59 -0.399 0.61373E+04 21 andalusite 5.00 2.11 -2.89 -0.289 0.49390E+04 22 andradite 39.01 35.09 -3.92 -0.204 0.66952E+04 23 grossular 32.73 28.27 -4.46 -0.223 0.76197E+04 24 anhydrite -5.32 -9.21 -3.90 -1.948 0.66509E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.63 -2.59 -0.865 0.44305E+04 36 brucite 12.57 8.63 -3.94 -0.787 0.67205E+04 37 calcite 0.81 -1.63 -2.44 -0.813 0.41663E+04 40 carpholite-Mg 8.58 7.10 -1.48 -0.099 0.25254E+04 41 carpholite-Fe 6.71 4.88 -1.84 -0.122 0.31366E+04 50 chloritoid-Mg 13.20 10.74 -2.46 -0.164 0.41938E+04 51 chloritoid-Fe 9.17 8.51 -0.66 -0.044 0.11260E+04 52 chloritoid-Mn 11.40 10.57 -0.83 -0.055 0.14175E+04 54 coesite -2.38 -3.64 -1.26 -0.421 0.21555E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.64 -1.08 -0.359 0.18409E+04 67 diopside 16.18 12.50 -3.68 -0.368 0.62836E+04 68 hedenbergite 14.21 10.27 -3.93 -0.393 0.67178E+04 75 epidote 24.67 23.41 -1.26 -0.061 0.21576E+04 76 clinozoisite 22.81 20.00 -2.81 -0.128 0.47965E+04 77 epidote-Fe 29.84 26.82 -3.03 -0.157 0.51653E+04 78 fayalite 14.05 9.17 -4.87 -0.696 0.83218E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.94 -4.20 -0.350 0.71727E+04 91 heulandite -5.83 -8.58 -2.75 -0.125 0.46939E+04 95 jadeite 4.22 -0.27 -4.49 -0.449 0.76628E+04 98 kaolinite -1.33 -1.53 -0.20 -0.018 0.33600E+03 99 kyanite 4.88 2.11 -2.77 -0.277 0.47249E+04 101 laumontite 2.88 2.34 -0.54 -0.036 0.92935E+03 105 lizardite 23.24 18.62 -4.62 -0.385 0.78934E+04 106 magnesite 0.69 -4.14 -4.83 -1.611 0.82502E+04 107 magnetite 20.09 18.97 -1.12 -0.091 0.19055E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.41 -2.93 -0.225 0.50002E+04 120 muscovite 2.58 0.33 -2.25 -0.132 0.38417E+04 121 paragonite 4.24 1.84 -2.40 -0.141 0.41031E+04 122 nepheline 8.34 3.37 -4.97 -0.710 0.84921E+04 136 prehnite 19.37 17.12 -2.25 -0.132 0.38395E+04 137 prehnite-Fe 22.50 20.53 -1.97 -0.118 0.33556E+04 138 pumpellyite-Fe 46.27 43.53 -2.74 -0.061 0.46854E+04 139 pumpellyite-Mg 48.99 45.75 -3.24 -0.072 0.55358E+04 145 pyroxmangite 7.40 4.82 -2.58 -0.515 0.43971E+04 146 pyrophyllite -6.18 -8.81 -2.63 -0.164 0.44919E+04 147 quartz -2.99 -3.64 -0.65 -0.216 0.11082E+04 151 rhodochrosite -0.98 -4.31 -3.34 -1.112 0.56954E+04 152 rhodonite 7.45 4.82 -2.62 -0.524 0.44773E+04 153 sanidine -1.28 -5.41 -4.14 -0.318 0.70680E+04 155 siderite -2.61 -6.37 -3.76 -1.254 0.64210E+04 156 sillimanite 5.26 2.11 -3.15 -0.315 0.53830E+04 163 stilbite -7.52 -8.58 -1.05 -0.050 0.18001E+04 164 stilpnomelane-Fe 13.02 9.98 -3.04 -0.091 0.51871E+04 167 sudoite-Fe 18.30 13.39 -4.91 -0.158 0.83775E+04 168 sudoite 21.08 17.84 -3.23 -0.104 0.55198E+04 174 tephroite 18.09 13.29 -4.80 -0.686 0.81965E+04 177 topaz-H 4.62 2.11 -2.51 -0.228 0.42850E+04 178 tridymite -2.63 -3.64 -1.01 -0.337 0.17282E+04 187 wairakite 3.95 2.34 -1.61 -0.095 0.27513E+04 188 walstromite 11.51 7.51 -4.00 -0.800 0.68334E+04 189 wollastonite 10.46 7.51 -2.95 -0.591 0.50439E+04 190 pseudo-wollastonite 11.00 7.51 -3.49 -0.699 0.59637E+04 191 zoisite 22.85 20.00 -2.85 -0.130 0.48705E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.82 -3.17 -0.196 0.54176E+04 194 beidellite-H -2.33 -6.66 -4.33 -0.276 0.73955E+04 195 beidellite-K -1.52 -5.79 -4.27 -0.262 0.72916E+04 196 beidellite-Mg -1.79 -5.23 -3.44 -0.213 0.58794E+04 197 beidellite-Na -1.34 -5.29 -3.95 -0.242 0.67481E+04 199 chalcedony -2.80 -3.64 -0.84 -0.279 0.14275E+04 201 montmorillonite-Ca -2.29 -5.07 -2.78 -0.172 0.47405E+04 202 montmorillonite-K -2.24 -6.04 -3.80 -0.233 0.64926E+04 203 montmorillonite-Mg -2.48 -5.48 -3.00 -0.186 0.51255E+04 204 montmorillonite-Na -2.04 -5.54 -3.51 -0.215 0.59849E+04 205 nontronite-Ca 3.21 2.00 -1.21 -0.079 0.20732E+04 206 nontronite-H 2.53 0.16 -2.37 -0.159 0.40491E+04 207 nontronite-K 3.34 1.03 -2.31 -0.148 0.39486E+04 208 nontronite-Mg 3.07 1.59 -1.49 -0.097 0.25423E+04 209 nontronite-Na 3.52 1.52 -2.00 -0.128 0.34068E+04 214 gypsum -4.96 -9.21 -4.26 -1.064 0.72685E+04 224 tobermorite 9.82 5.65 -4.18 -1.140 0.71325E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.41 -3.41 -0.852 0.58163E+04 240 silica-amorphous -2.09 -3.64 -1.55 -0.516 0.26417E+04 242 an20ab80 2.02 -1.21 -3.22 -0.248 0.55038E+04 243 an25ab75 2.65 -0.53 -3.17 -0.244 0.54211E+04 244 an30ab70 3.28 0.15 -3.13 -0.241 0.53480E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0290000 g New total amount of reactant added: 0.0300000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0300000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3039568E-03 Osmotic coef. = 0.9896 True ionic strength = .3189333E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14672E-07 -7.8335 0.14072E-07 -7.8516 0.95915E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13231E-03 -3.8784 0.95902E+00 -0.0182 4 SO4-- 0.25312E-04 -4.5967 0.22597E-04 -4.6460 0.89271E+00 -0.0493 5 HCO3- 0.12590E-04 -4.9000 0.12074E-04 -4.9181 0.95905E+00 -0.0182 6 HS- 0.28089E-11 -11.5515 0.26938E-11 -11.5696 0.95902E+00 -0.0182 7 Al+++ 0.26311E-20 -20.5799 0.20835E-20 -20.6812 0.79188E+00 -0.1013 8 H4SiO4 0.23532E-03 -3.6283 0.23532E-03 -3.6283 0.10000E+01 0.0000 9 Ca++ 0.29610E-04 -4.5286 0.26429E-04 -4.5779 0.89256E+00 -0.0494 10 Mg++ 0.93906E-07 -7.0273 0.83808E-07 -7.0767 0.89247E+00 -0.0494 11 Fe++ 0.55618E-09 -9.2548 0.49638E-09 -9.3042 0.89249E+00 -0.0494 12 K+ 0.63671E-05 -5.1961 0.61064E-05 -5.2142 0.95906E+00 -0.0182 13 Na+ 0.19767E-03 -3.7041 0.18957E-03 -3.7222 0.95901E+00 -0.0182 14 Mn++ 0.63671E-07 -7.1961 0.56827E-07 -7.2454 0.89251E+00 -0.0494 15 HPO4-- 0.14426E-08 -8.8409 0.12878E-08 -8.8901 0.89272E+00 -0.0493 16 HSiO3- 0.16282E-04 -4.7883 0.15614E-04 -4.8065 0.95902E+00 -0.0182 17 Ca(HSiO3)+ 0.97993E-08 -8.0088 0.93981E-08 -8.0270 0.95906E+00 -0.0182 18 Mg(HSiO3)+ 0.38672E-10 -10.4126 0.37089E-10 -10.4308 0.95906E+00 -0.0182 19 NaHSiO3,aq 0.47873E-07 -7.3199 0.47873E-07 -7.3199 0.10000E+01 0.0000 20 AlO+ 0.14924E-11 -11.8261 0.14313E-11 -11.8443 0.95906E+00 -0.0182 21 AlOH+2 0.11237E-15 -15.9493 0.10030E-15 -15.9987 0.89253E+00 -0.0494 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.33225E-05 -5.4785 0.31862E-05 -5.4967 0.95898E+00 -0.0182 24 CH4,aq 0.13983E-17 -17.8544 0.13982E-17 -17.8544 0.99991E+00 0.0000 29 CO,aq 0.59290E-17 -17.2270 0.59290E-17 -17.2270 0.10000E+01 0.0000 30 CO2,aq 0.36310E-06 -6.4400 0.36306E-06 -6.4400 0.99991E+00 0.0000 31 CO3-2 0.83955E-07 -7.0760 0.74944E-07 -7.1253 0.89267E+00 -0.0493 32 CaCO3,aq 0.24836E-07 -7.6049 0.24836E-07 -7.6049 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.84933E-08 -8.0709 0.81456E-08 -8.0891 0.95906E+00 -0.0182 34 CaCl+ 0.59004E-08 -8.2291 0.56588E-08 -8.2473 0.95906E+00 -0.0182 35 CaCl2,aq 0.17788E-12 -12.7499 0.17788E-12 -12.7499 0.10000E+01 0.0000 36 CaOH+ 0.13956E-06 -6.8552 0.13385E-06 -6.8734 0.95906E+00 -0.0182 37 CaSO4,aq 0.18964E-06 -6.7221 0.18964E-06 -6.7221 0.10000E+01 0.0000 38 HCl,aq 0.34118E-12 -12.4670 0.34118E-12 -12.4670 0.10000E+01 0.0000 43 FeCl+ 0.10839E-12 -12.9650 0.10395E-12 -12.9832 0.95906E+00 -0.0182 46 FeO,aq 0.97420E-10 -10.0114 0.97420E-10 -10.0114 0.10000E+01 0.0000 47 FeOH+ 0.11972E-08 -8.9218 0.11482E-08 -8.9400 0.95906E+00 -0.0182 48 HFeO2- 0.75530E-10 -10.1219 0.72434E-10 -10.1401 0.95902E+00 -0.0182 49 FeO+ 0.11200E-12 -12.9508 0.10741E-12 -12.9689 0.95906E+00 -0.0182 50 FeOH+2 0.32342E-18 -18.4902 0.28866E-18 -18.5396 0.89253E+00 -0.0494 51 FeO2- 0.11573E-09 -9.9366 0.11099E-09 -9.9547 0.95902E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.65015E-09 -9.1870 0.65009E-09 -9.1870 0.99991E+00 0.0000 54 KCl,aq 0.14643E-10 -10.8344 0.14643E-10 -10.8344 0.10000E+01 0.0000 55 KHSO4,aq 0.54900E-17 -17.2604 0.54900E-17 -17.2604 0.10000E+01 0.0000 56 KOH,aq 0.18531E-09 -9.7321 0.18531E-09 -9.7321 0.10000E+01 0.0000 57 KSO4- 0.22327E-08 -8.6512 0.21412E-08 -8.6694 0.95902E+00 -0.0182 58 MgCO3,aq 0.19741E-10 -10.7046 0.19741E-10 -10.7046 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27520E-10 -10.5603 0.26394E-10 -10.5785 0.95906E+00 -0.0182 60 MgCl+ 0.16958E-10 -10.7706 0.16264E-10 -10.7888 0.95906E+00 -0.0182 61 MgOH+ 0.24489E-08 -8.6110 0.23487E-08 -8.6292 0.95906E+00 -0.0182 63 MnO,aq 0.29718E-09 -9.5270 0.29718E-09 -9.5270 0.10000E+01 0.0000 64 MnOH+ 0.12732E-07 -7.8951 0.12211E-07 -7.9132 0.95906E+00 -0.0182 65 MnO2-2 0.55791E-16 -16.2534 0.49803E-16 -16.3027 0.89267E+00 -0.0493 66 HMnO2- 0.16010E-12 -12.7956 0.15354E-12 -12.8138 0.95902E+00 -0.0182 69 MnCl+ 0.48275E-10 -10.3163 0.46299E-10 -10.3344 0.95906E+00 -0.0182 70 MnSO4,aq 0.37071E-09 -9.4310 0.37071E-09 -9.4310 0.10000E+01 0.0000 71 NaCl,aq 0.83119E-08 -8.0803 0.83119E-08 -8.0803 0.10000E+01 0.0000 72 NaOH,aq 0.57878E-08 -8.2375 0.57878E-08 -8.2375 0.10000E+01 0.0000 74 OH- 0.42814E-04 -4.3684 0.41057E-04 -4.3866 0.95898E+00 -0.0182 82 H3PO4,aq 0.17837E-14 -14.7487 0.17837E-14 -14.7487 0.10000E+01 0.0000 83 H2PO4- 0.34859E-09 -9.4577 0.33431E-09 -9.4758 0.95904E+00 -0.0182 84 PO4-3 0.94179E-13 -13.0260 0.74666E-13 -13.1269 0.79281E+00 -0.1008 88 HP2O7-3 0.15703E-18 -18.8040 0.12435E-18 -18.9054 0.79189E+00 -0.1013 90 H2S,aq 0.11717E-12 -12.9312 0.11716E-12 -12.9312 0.99991E+00 0.0000 96 SO2,aq 0.12992E-19 -19.8863 0.12992E-19 -19.8863 0.10000E+01 0.0000 97 SO3-2 0.21377E-14 -14.6701 0.19089E-14 -14.7192 0.89298E+00 -0.0492 98 HSO3- 0.17538E-14 -14.7560 0.16820E-14 -14.7742 0.95902E+00 -0.0182 99 HSO4- 0.31952E-09 -9.4955 0.30645E-09 -9.5136 0.95908E+00 -0.0181 101 S2O3-2 0.34837E-19 -19.4580 0.31098E-19 -19.5073 0.89267E+00 -0.0493 Charge balance for all species = 0.2018E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1467160E-07 -.7239827E-04 -.7297043E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999617E+06 0.0000 3 Cl- 0.1379613E-03 0.1379756E-03 0.4891470E+01 3.9732 4 SO4-- 0.2531217E-04 0.2550461E-04 0.2449924E+01 11.0573 5 HCO3- 0.1258971E-04 0.1307014E-04 0.7974739E+00 2.9335 6 HS- 0.2808860E-11 0.1261532E-09 0.4171984E-05 -3.7180 7 Al+++ 0.2631068E-20 0.3342799E-05 0.9019042E-01 2.8737 8 H4SiO4 0.2353232E-03 0.2516625E-03 0.2418776E+02 -3.6283 9 Ca++ 0.2961029E-04 0.2998853E-04 0.1201836E+01 11.1253 10 Mg++ 0.9390617E-07 0.9645799E-07 0.2345001E-02 8.6266 11 Fe++ 0.5561776E-09 0.2240927E-08 0.1251445E-03 6.3991 12 K+ 0.6367061E-05 0.6369494E-05 0.2490508E+00 2.6374 13 Na+ 0.1976684E-03 0.1977304E-03 0.4545615E+01 4.1294 14 Mn++ 0.6367096E-07 0.7711954E-07 0.4236638E-02 8.4578 15 HPO4-- 0.1442590E-08 0.1791279E-08 0.1719188E-03 6.8131 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4837155E-03 -.7239751E-04 -.4113180E-03 0.0000000E+00 2 H2O 0.5550787E+02 0.5550770E+02 0.1738381E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2633587E-04 0.2550434E-04 0.8315284E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8314023E-06 0.1261518E-09 -.8315284E-06 0.0000000E+00 7 Al+++ 0.9782225E-04 0.3342764E-05 0.9447948E-04 0.0000000E+00 8 H4SiO4 0.3123835E-03 0.2516599E-03 0.6072361E-04 0.0000000E+00 9 Ca++ 0.4897534E-04 0.2998821E-04 0.1898713E-04 0.0000000E+00 10 Mg++ 0.2380952E-04 0.9645698E-07 0.2371307E-04 0.0000000E+00 11 Fe++ 0.2139026E-04 0.2240904E-08 0.2138802E-04 0.0000000E+00 12 K+ 0.6369427E-05 0.6369427E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1977283E-03 0.1977283E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5201579E-06 0.7711873E-07 0.4430391E-06 0.0000000E+00 15 HPO4-- 0.1775273E-06 0.1791260E-08 0.1757360E-06 0.0000000E+00 Chg. balance for solid moles: 0.3356E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0300000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5858E-07 -7.232 0.2943E-04 -4.531 0.2143 0.9350E-05 clinochlore 0.4743E-05 -5.324 0.2636E-02 -2.579 19.20 0.1003E-02 daphnite 0.2947E-05 -5.531 0.2103E-02 -2.677 15.32 0.6372E-03 chlorite-Mn 0.8861E-07 -7.053 0.6282E-04 -4.202 0.4576 0.2002E-04 diaspore 0.4153E-04 -4.382 0.2492E-02 -2.604 18.15 0.7418E-03 hematite 0.3326E-05 -5.478 0.5312E-03 -3.275 3.869 0.1007E-03 lawsonite 0.1869E-04 -4.728 0.5874E-02 -2.231 42.79 0.1894E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3789E+00 0.3789E+00 1.0000 -0.421 chlorite-Mn 0.1139E-01 0.1139E-01 1.0000 -1.943 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.013728 g Volume = 0.004406 cm3 Porosity: 99.5646% V(tot) - V(min): 0.10076E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0300000 g log = -1.5229 Original solution: 1000.0103000 g Original solution / Rock added: 33333.68 (Water/Rock Ratio), log = 4.5229 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3780E-04 1.0071 0.3884E-04 0.3857E-04 CH4,gas 0.1992E-14 1.0125 0.2058E-14 0.2033E-14 H2,gas 0.8360E-06 1.0005 0.8535E-06 0.8530E-06 H2S,gas 0.3169E-11 0.9960 0.3221E-11 0.3233E-11 S2,gas 0.5238E-30 1.0000 0.5345E-30 0.5345E-30 CO,gas 0.8659E-14 1.0000 0.8835E-14 0.8835E-14 SO3,gas 0.1658E-35 1.0000 0.1692E-35 0.1692E-35 SO2,gas 0.5506E-19 1.0000 0.5618E-19 0.5618E-19 HCl,gas 0.5900E-15 1.0000 0.6020E-15 0.6020E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.77 -6.11 -2.037 0.10432E+05 -4.411 3 CH4,gas 4.54 -11.84 -16.39 -4.096 0.27978E+05 -14.687 4 H2,gas 8.00 0.23 -7.77 -4.439 0.13263E+05 -6.069 5 H2S,gas -6.23 -19.42 -13.19 -6.596 0.22523E+05 -11.492 6 S2,gas -7.34 -39.31 -31.97 -4.919 0.54590E+05 -30.272 7 CO,gas 3.21 -12.54 -15.75 -4.847 0.26897E+05 -14.054 8 SO3,gas 17.12 -20.35 -37.47 -9.368 0.63980E+05 -35.772 9 SO2,gas 0.83 -20.12 -20.95 -5.587 0.35771E+05 -19.250 10 HCl,gas 5.19 -11.73 -16.92 -8.460 0.28889E+05 -15.220 11 acmite 7.71 3.16 -4.55 -0.473 0.77757E+04 15 albite-high 0.69 -3.88 -4.57 -0.352 0.78116E+04 16 albite -0.38 -3.88 -3.50 -0.269 0.59728E+04 19 spessartine 24.46 20.24 -4.22 -0.211 0.72081E+04 20 analcite 3.32 -0.25 -3.58 -0.397 0.61050E+04 21 andalusite 5.00 2.12 -2.88 -0.288 0.49217E+04 22 andradite 39.01 35.06 -3.95 -0.205 0.67471E+04 23 grossular 32.73 28.24 -4.49 -0.225 0.76717E+04 24 anhydrite -5.32 -9.22 -3.91 -1.954 0.66712E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.64 -2.61 -0.870 0.44581E+04 36 brucite 12.57 8.63 -3.94 -0.788 0.67309E+04 37 calcite 0.81 -1.64 -2.46 -0.819 0.41939E+04 40 carpholite-Mg 8.58 7.12 -1.46 -0.098 0.25011E+04 41 carpholite-Fe 6.71 4.89 -1.82 -0.122 0.31124E+04 50 chloritoid-Mg 13.20 10.75 -2.45 -0.163 0.41869E+04 51 chloritoid-Fe 9.17 8.52 -0.66 -0.044 0.11192E+04 52 chloritoid-Mn 11.40 10.58 -0.82 -0.055 0.14073E+04 54 coesite -2.38 -3.63 -1.25 -0.417 0.21382E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.63 -1.07 -0.356 0.18236E+04 67 diopside 16.18 12.50 -3.69 -0.369 0.62940E+04 68 hedenbergite 14.21 10.27 -3.94 -0.394 0.67283E+04 75 epidote 24.67 23.40 -1.27 -0.062 0.21749E+04 76 clinozoisite 22.81 19.99 -2.82 -0.128 0.48138E+04 77 epidote-Fe 29.84 26.81 -3.04 -0.158 0.51826E+04 78 fayalite 14.05 9.17 -4.88 -0.697 0.83255E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.94 -4.20 -0.350 0.71695E+04 91 heulandite -5.83 -8.53 -2.70 -0.123 0.46074E+04 95 jadeite 4.22 -0.25 -4.47 -0.447 0.76305E+04 98 kaolinite -1.33 -1.51 -0.18 -0.016 0.30138E+03 99 kyanite 4.88 2.12 -2.76 -0.276 0.47076E+04 101 laumontite 2.88 2.36 -0.52 -0.035 0.89473E+03 105 lizardite 23.24 18.62 -4.62 -0.385 0.78900E+04 106 magnesite 0.69 -4.14 -4.83 -1.611 0.82536E+04 107 magnetite 20.09 18.97 -1.12 -0.092 0.19160E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.37 -2.89 -0.222 0.49302E+04 120 muscovite 2.58 0.37 -2.21 -0.130 0.37717E+04 121 paragonite 4.24 1.87 -2.37 -0.140 0.40535E+04 122 nepheline 8.34 3.37 -4.96 -0.709 0.84771E+04 136 prehnite 19.37 17.11 -2.26 -0.133 0.38568E+04 137 prehnite-Fe 22.50 20.52 -1.98 -0.119 0.33729E+04 138 pumpellyite-Fe 46.27 43.50 -2.77 -0.062 0.47305E+04 139 pumpellyite-Mg 48.99 45.73 -3.27 -0.073 0.55808E+04 145 pyroxmangite 7.40 4.83 -2.57 -0.514 0.43868E+04 146 pyrophyllite -6.18 -8.77 -2.59 -0.162 0.44226E+04 147 quartz -2.99 -3.63 -0.64 -0.213 0.10909E+04 151 rhodochrosite -0.98 -4.31 -3.34 -1.112 0.56955E+04 152 rhodonite 7.45 4.83 -2.62 -0.523 0.44671E+04 153 sanidine -1.28 -5.37 -4.10 -0.315 0.69979E+04 155 siderite -2.61 -6.37 -3.76 -1.254 0.64244E+04 156 sillimanite 5.26 2.12 -3.14 -0.314 0.53657E+04 163 stilbite -7.52 -8.53 -1.00 -0.048 0.17135E+04 164 stilpnomelane-Fe 13.02 10.03 -2.98 -0.089 0.50919E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83465E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54886E+04 174 tephroite 18.09 13.29 -4.80 -0.685 0.81933E+04 177 topaz-H 4.62 2.12 -2.50 -0.227 0.42677E+04 178 tridymite -2.63 -3.63 -1.00 -0.334 0.17109E+04 187 wairakite 3.95 2.36 -1.59 -0.094 0.27167E+04 188 walstromite 11.51 7.50 -4.01 -0.802 0.68507E+04 189 wollastonite 10.46 7.50 -2.96 -0.593 0.50612E+04 190 pseudo-wollastonite 11.00 7.50 -3.50 -0.701 0.59810E+04 191 zoisite 22.85 19.99 -2.86 -0.130 0.48878E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.78 -3.14 -0.194 0.53597E+04 194 beidellite-H -2.33 -6.62 -4.29 -0.274 0.73320E+04 195 beidellite-K -1.52 -5.75 -4.23 -0.259 0.72221E+04 196 beidellite-Mg -1.79 -5.20 -3.41 -0.211 0.58176E+04 197 beidellite-Na -1.34 -5.26 -3.92 -0.240 0.66853E+04 199 chalcedony -2.80 -3.63 -0.83 -0.275 0.14102E+04 201 montmorillonite-Ca -2.29 -5.03 -2.74 -0.170 0.46804E+04 202 montmorillonite-K -2.24 -6.00 -3.76 -0.230 0.64208E+04 203 montmorillonite-Mg -2.48 -5.44 -2.96 -0.183 0.50614E+04 204 montmorillonite-Na -2.04 -5.50 -3.47 -0.212 0.59198E+04 205 nontronite-Ca 3.21 2.03 -1.18 -0.077 0.20154E+04 206 nontronite-H 2.53 0.20 -2.33 -0.156 0.39856E+04 207 nontronite-K 3.34 1.07 -2.27 -0.146 0.38791E+04 208 nontronite-Mg 3.07 1.62 -1.45 -0.094 0.24805E+04 209 nontronite-Na 3.52 1.56 -1.96 -0.126 0.33441E+04 214 gypsum -4.96 -9.22 -4.27 -1.067 0.72888E+04 224 tobermorite 9.82 5.64 -4.18 -1.142 0.71440E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.40 -3.41 -0.853 0.58267E+04 240 silica-amorphous -2.09 -3.63 -1.54 -0.512 0.26244E+04 242 an20ab80 2.02 -1.18 -3.20 -0.246 0.54641E+04 243 an25ab75 2.65 -0.51 -3.15 -0.243 0.53839E+04 244 an30ab70 3.28 0.17 -3.11 -0.239 0.53133E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0300000 g New total amount of reactant added: 0.0310000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0310000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3028954E-03 Osmotic coef. = 0.9896 True ionic strength = .3179415E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14803E-07 -7.8296 0.14199E-07 -7.8477 0.95919E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13231E-03 -3.8784 0.95905E+00 -0.0182 4 SO4-- 0.25317E-04 -4.5966 0.22604E-04 -4.6458 0.89284E+00 -0.0492 5 HCO3- 0.12588E-04 -4.9000 0.12073E-04 -4.9182 0.95908E+00 -0.0181 6 HS- 0.25372E-11 -11.5956 0.24333E-11 -11.6138 0.95906E+00 -0.0182 7 Al+++ 0.27019E-20 -20.5683 0.21403E-20 -20.6695 0.79214E+00 -0.1012 8 H4SiO4 0.24078E-03 -3.6184 0.24078E-03 -3.6184 0.10000E+01 0.0000 9 Ca++ 0.28790E-04 -4.5408 0.25701E-04 -4.5901 0.89269E+00 -0.0493 10 Mg++ 0.94284E-07 -7.0256 0.84157E-07 -7.0749 0.89260E+00 -0.0493 11 Fe++ 0.55835E-09 -9.2531 0.49840E-09 -9.3024 0.89262E+00 -0.0493 12 K+ 0.65793E-05 -5.1818 0.63101E-05 -5.2000 0.95909E+00 -0.0181 13 Na+ 0.19892E-03 -3.7013 0.19078E-03 -3.7195 0.95905E+00 -0.0182 14 Mn++ 0.64205E-07 -7.1924 0.57311E-07 -7.2418 0.89264E+00 -0.0493 15 HPO4-- 0.15293E-08 -8.8155 0.13654E-08 -8.8647 0.89285E+00 -0.0492 16 HSiO3- 0.16510E-04 -4.7823 0.15834E-04 -4.8004 0.95905E+00 -0.0182 17 Ca(HSiO3)+ 0.96630E-08 -8.0149 0.92678E-08 -8.0330 0.95910E+00 -0.0181 18 Mg(HSiO3)+ 0.39378E-10 -10.4047 0.37767E-10 -10.4229 0.95910E+00 -0.0181 19 NaHSiO3,aq 0.48857E-07 -7.3111 0.48857E-07 -7.3111 0.10000E+01 0.0000 20 AlO+ 0.15058E-11 -11.8222 0.14442E-11 -11.8404 0.95910E+00 -0.0181 21 AlOH+2 0.11439E-15 -15.9416 0.10211E-15 -15.9909 0.89266E+00 -0.0493 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.32928E-05 -5.4824 0.31578E-05 -5.5006 0.95901E+00 -0.0182 24 CH4,aq 0.12626E-17 -17.8987 0.12625E-17 -17.8988 0.99991E+00 0.0000 29 CO,aq 0.58183E-17 -17.2352 0.58183E-17 -17.2352 0.10000E+01 0.0000 30 CO2,aq 0.36634E-06 -6.4361 0.36630E-06 -6.4362 0.99991E+00 0.0000 31 CO3-2 0.83188E-07 -7.0799 0.74270E-07 -7.1292 0.89280E+00 -0.0492 32 CaCO3,aq 0.23934E-07 -7.6210 0.23934E-07 -7.6210 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.82584E-08 -8.0831 0.79206E-08 -8.1012 0.95910E+00 -0.0181 34 CaCl+ 0.57378E-08 -8.2413 0.55031E-08 -8.2594 0.95910E+00 -0.0181 35 CaCl2,aq 0.17299E-12 -12.7620 0.17299E-12 -12.7620 0.10000E+01 0.0000 36 CaOH+ 0.13450E-06 -6.8713 0.12900E-06 -6.8894 0.95910E+00 -0.0181 37 CaSO4,aq 0.18448E-06 -6.7341 0.18448E-06 -6.7341 0.10000E+01 0.0000 38 HCl,aq 0.34426E-12 -12.4631 0.34426E-12 -12.4631 0.10000E+01 0.0000 43 FeCl+ 0.10883E-12 -12.9633 0.10438E-12 -12.9814 0.95910E+00 -0.0181 46 FeO,aq 0.96078E-10 -10.0174 0.96078E-10 -10.0174 0.10000E+01 0.0000 47 FeOH+ 0.11913E-08 -8.9240 0.11426E-08 -8.9421 0.95910E+00 -0.0181 48 HFeO2- 0.73822E-10 -10.1318 0.70799E-10 -10.1500 0.95905E+00 -0.0182 49 FeO+ 0.11300E-12 -12.9469 0.10838E-12 -12.9651 0.95910E+00 -0.0181 50 FeOH+2 0.32922E-18 -18.4825 0.29388E-18 -18.5318 0.89266E+00 -0.0493 51 FeO2- 0.11469E-09 -9.9405 0.11000E-09 -9.9586 0.95905E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.63235E-09 -9.1990 0.63230E-09 -9.1991 0.99991E+00 0.0000 54 KCl,aq 0.15132E-10 -10.8201 0.15132E-10 -10.8201 0.10000E+01 0.0000 55 KHSO4,aq 0.57263E-17 -17.2421 0.57263E-17 -17.2421 0.10000E+01 0.0000 56 KOH,aq 0.18979E-09 -9.7217 0.18979E-09 -9.7217 0.10000E+01 0.0000 57 KSO4- 0.23079E-08 -8.6368 0.22134E-08 -8.6549 0.95905E+00 -0.0182 58 MgCO3,aq 0.19645E-10 -10.7068 0.19645E-10 -10.7068 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27632E-10 -10.5586 0.26502E-10 -10.5767 0.95910E+00 -0.0181 60 MgCl+ 0.17029E-10 -10.7688 0.16332E-10 -10.7870 0.95910E+00 -0.0181 61 MgOH+ 0.24371E-08 -8.6131 0.23374E-08 -8.6313 0.95910E+00 -0.0181 63 MnO,aq 0.29439E-09 -9.5311 0.29439E-09 -9.5311 0.10000E+01 0.0000 64 MnOH+ 0.12726E-07 -7.8953 0.12205E-07 -7.9135 0.95910E+00 -0.0181 65 MnO2-2 0.54277E-16 -16.2654 0.48459E-16 -16.3146 0.89280E+00 -0.0492 66 HMnO2- 0.15718E-12 -12.8036 0.15074E-12 -12.8218 0.95905E+00 -0.0182 69 MnCl+ 0.48687E-10 -10.3126 0.46696E-10 -10.3307 0.95910E+00 -0.0181 70 MnSO4,aq 0.37400E-09 -9.4271 0.37400E-09 -9.4271 0.10000E+01 0.0000 71 NaCl,aq 0.83653E-08 -8.0775 0.83653E-08 -8.0775 0.10000E+01 0.0000 72 NaOH,aq 0.57727E-08 -8.2386 0.57727E-08 -8.2386 0.10000E+01 0.0000 74 OH- 0.42430E-04 -4.3723 0.40691E-04 -4.3905 0.95901E+00 -0.0182 82 H3PO4,aq 0.19253E-14 -14.7155 0.19253E-14 -14.7155 0.10000E+01 0.0000 83 H2PO4- 0.37291E-09 -9.4284 0.35765E-09 -9.4465 0.95907E+00 -0.0181 84 PO4-3 0.98932E-13 -13.0047 0.78459E-13 -13.1054 0.79306E+00 -0.1007 87 H2P2O7-2 0.11234E-19 -19.9495 0.10030E-19 -19.9987 0.89280E+00 -0.0492 88 HP2O7-3 0.17805E-18 -18.7494 0.14105E-18 -18.8506 0.79215E+00 -0.1012 90 H2S,aq 0.10679E-12 -12.9715 0.10678E-12 -12.9715 0.99991E+00 0.0000 96 SO2,aq 0.12869E-19 -19.8905 0.12869E-19 -19.8905 0.10000E+01 0.0000 97 SO3-2 0.20796E-14 -14.6820 0.18573E-14 -14.7311 0.89310E+00 -0.0491 98 HSO3- 0.17217E-14 -14.7640 0.16512E-14 -14.7822 0.95905E+00 -0.0182 99 HSO4- 0.32250E-09 -9.4915 0.30931E-09 -9.5096 0.95912E+00 -0.0181 101 S2O3-2 0.31758E-19 -19.4981 0.28354E-19 -19.5474 0.89280E+00 -0.0492 Charge balance for all species = 0.2018E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1480315E-07 -.7211480E-04 -.7268468E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999611E+06 0.0000 3 Cl- 0.1379615E-03 0.1379757E-03 0.4891469E+01 3.9693 4 SO4-- 0.2531726E-04 0.2550462E-04 0.2449924E+01 11.0497 5 HCO3- 0.1258838E-04 0.1307014E-04 0.7974737E+00 2.9296 6 HS- 0.2537190E-11 0.1215524E-09 0.4019832E-05 -3.7661 7 Al+++ 0.2701882E-20 0.3313036E-05 0.8938736E-01 2.8737 8 H4SiO4 0.2407817E-03 0.2573503E-03 0.2473441E+02 -3.6184 9 Ca++ 0.2879030E-04 0.2915688E-04 0.1168506E+01 11.1054 10 Mg++ 0.9428351E-07 0.9682430E-07 0.2353905E-02 8.6206 11 Fe++ 0.5583532E-09 0.2233108E-08 0.1247077E-03 6.3931 12 K+ 0.6579299E-05 0.6581812E-05 0.2573524E+00 2.6478 13 Na+ 0.1989227E-03 0.1989857E-03 0.4574471E+01 4.1283 14 Mn++ 0.6420458E-07 0.7764761E-07 0.4265646E-02 8.4537 15 HPO4-- 0.1529297E-08 0.1902311E-08 0.1825751E-03 6.8308 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5002740E-03 -.7211402E-04 -.4281600E-03 0.0000000E+00 2 H2O 0.5550786E+02 0.5550768E+02 0.1772190E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2636359E-04 0.2550435E-04 0.8592372E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8591157E-06 0.1215511E-09 -.8592372E-06 0.0000000E+00 7 Al+++ 0.1010830E-03 0.3313001E-05 0.9776999E-04 0.0000000E+00 8 H4SiO4 0.3227963E-03 0.2573476E-03 0.6544870E-04 0.0000000E+00 9 Ca++ 0.5012548E-04 0.2915656E-04 0.2096892E-04 0.0000000E+00 10 Mg++ 0.2460317E-04 0.9682325E-07 0.2450635E-04 0.0000000E+00 11 Fe++ 0.2210327E-04 0.2233084E-08 0.2210103E-04 0.0000000E+00 12 K+ 0.6581741E-05 0.6581741E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1989836E-03 0.1989836E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5374965E-06 0.7764677E-07 0.4598497E-06 0.0000000E+00 15 HPO4-- 0.1834449E-06 0.1902290E-08 0.1815426E-06 0.0000000E+00 Chg. balance for solid moles: -.3648E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0310000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6051E-07 -7.218 0.3040E-04 -4.517 0.2103 0.9659E-05 clinochlore 0.4901E-05 -5.310 0.2724E-02 -2.565 18.84 0.1036E-02 daphnite 0.3045E-05 -5.516 0.2173E-02 -2.663 15.03 0.6585E-03 chlorite-Mn 0.9197E-07 -7.036 0.6520E-04 -4.186 0.4510 0.2078E-04 diaspore 0.4036E-04 -4.394 0.2421E-02 -2.616 16.75 0.7208E-03 hematite 0.3437E-05 -5.464 0.5489E-03 -3.261 3.797 0.1040E-03 lawsonite 0.2067E-04 -4.685 0.6494E-02 -2.187 44.92 0.2094E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3788E+00 0.3788E+00 1.0000 -0.422 chlorite-Mn 0.1144E-01 0.1144E-01 1.0000 -1.942 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.014457 g Volume = 0.004644 cm3 Porosity: 99.5413% V(tot) - V(min): 0.10078E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0310000 g log = -1.5086 Original solution: 1000.0103000 g Original solution / Rock added: 32258.40 (Water/Rock Ratio), log = 4.5086 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3814E-04 1.0071 0.3919E-04 0.3891E-04 CH4,gas 0.1799E-14 1.0125 0.1858E-14 0.1835E-14 H2,gas 0.8131E-06 1.0005 0.8301E-06 0.8297E-06 H2S,gas 0.2888E-11 0.9960 0.2935E-11 0.2947E-11 S2,gas 0.4600E-30 1.0000 0.4693E-30 0.4693E-30 CO,gas 0.8498E-14 1.0000 0.8670E-14 0.8670E-14 SO3,gas 0.1689E-35 1.0000 0.1723E-35 0.1723E-35 SO2,gas 0.5454E-19 1.0000 0.5565E-19 0.5565E-19 HCl,gas 0.5954E-15 1.0000 0.6075E-15 0.6075E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.36397E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.90992E-11 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.77 -6.11 -2.035 0.10425E+05 -4.407 3 CH4,gas 4.54 -11.89 -16.43 -4.107 0.28054E+05 -14.731 4 H2,gas 8.00 0.22 -7.78 -4.446 0.13284E+05 -6.081 5 H2S,gas -6.23 -19.46 -13.23 -6.616 0.22592E+05 -11.532 6 S2,gas -7.34 -39.36 -32.03 -4.927 0.54686E+05 -30.329 7 CO,gas 3.21 -12.55 -15.76 -4.850 0.26911E+05 -14.062 8 SO3,gas 17.12 -20.34 -37.46 -9.366 0.63966E+05 -35.764 9 SO2,gas 0.83 -20.12 -20.95 -5.588 0.35778E+05 -19.255 10 HCl,gas 5.19 -11.73 -16.92 -8.458 0.28883E+05 -15.216 11 acmite 7.71 3.17 -4.54 -0.471 0.77436E+04 15 albite-high 0.69 -3.85 -4.55 -0.350 0.77625E+04 16 albite -0.38 -3.85 -3.47 -0.267 0.59237E+04 19 spessartine 24.46 20.25 -4.20 -0.210 0.71780E+04 20 analcite 3.32 -0.23 -3.56 -0.395 0.60729E+04 21 andalusite 5.00 2.13 -2.87 -0.287 0.49047E+04 22 andradite 39.01 35.03 -3.98 -0.207 0.67981E+04 23 grossular 32.73 28.21 -4.52 -0.226 0.77227E+04 24 anhydrite -5.32 -9.24 -3.92 -1.960 0.66917E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.66 -2.63 -0.876 0.44855E+04 36 brucite 12.57 8.62 -3.95 -0.790 0.67411E+04 37 calcite 0.81 -1.66 -2.47 -0.824 0.42213E+04 40 carpholite-Mg 8.58 7.13 -1.45 -0.097 0.24773E+04 41 carpholite-Fe 6.71 4.90 -1.81 -0.121 0.30887E+04 50 chloritoid-Mg 13.20 10.75 -2.45 -0.163 0.41801E+04 51 chloritoid-Fe 9.17 8.52 -0.65 -0.043 0.11125E+04 52 chloritoid-Mn 11.40 10.58 -0.82 -0.055 0.13973E+04 54 coesite -2.38 -3.62 -1.24 -0.414 0.21212E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.62 -1.06 -0.353 0.18066E+04 67 diopside 16.18 12.49 -3.69 -0.369 0.63042E+04 68 hedenbergite 14.21 10.26 -3.95 -0.395 0.67386E+04 75 epidote 24.67 23.39 -1.28 -0.062 0.21919E+04 76 clinozoisite 22.81 19.98 -2.83 -0.129 0.48308E+04 77 epidote-Fe 29.84 26.80 -3.05 -0.158 0.51996E+04 78 fayalite 14.05 9.17 -4.88 -0.697 0.83290E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.94 -4.20 -0.350 0.71664E+04 91 heulandite -5.83 -8.48 -2.65 -0.120 0.45223E+04 95 jadeite 4.22 -0.23 -4.45 -0.445 0.75984E+04 98 kaolinite -1.33 -1.49 -0.16 -0.014 0.26737E+03 99 kyanite 4.88 2.13 -2.75 -0.275 0.46906E+04 101 laumontite 2.88 2.38 -0.50 -0.034 0.86072E+03 105 lizardite 23.24 18.62 -4.62 -0.385 0.78866E+04 106 magnesite 0.69 -4.15 -4.84 -1.612 0.82572E+04 107 magnetite 20.09 18.96 -1.13 -0.092 0.19263E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.33 -2.85 -0.219 0.48614E+04 120 muscovite 2.58 0.41 -2.17 -0.128 0.37030E+04 121 paragonite 4.24 1.89 -2.35 -0.138 0.40044E+04 122 nepheline 8.34 3.38 -4.96 -0.708 0.84620E+04 136 prehnite 19.37 17.10 -2.27 -0.133 0.38738E+04 137 prehnite-Fe 22.50 20.51 -1.99 -0.119 0.33899E+04 138 pumpellyite-Fe 46.27 43.47 -2.80 -0.062 0.47748E+04 139 pumpellyite-Mg 48.99 45.70 -3.29 -0.073 0.56250E+04 145 pyroxmangite 7.40 4.84 -2.56 -0.513 0.43768E+04 146 pyrophyllite -6.18 -8.73 -2.55 -0.159 0.43546E+04 147 quartz -2.99 -3.62 -0.63 -0.210 0.10739E+04 151 rhodochrosite -0.98 -4.31 -3.34 -1.112 0.56959E+04 152 rhodonite 7.45 4.84 -2.61 -0.522 0.44571E+04 153 sanidine -1.28 -5.33 -4.06 -0.312 0.69292E+04 155 siderite -2.61 -6.37 -3.76 -1.255 0.64281E+04 156 sillimanite 5.26 2.13 -3.13 -0.313 0.53487E+04 163 stilbite -7.52 -8.48 -0.95 -0.045 0.16285E+04 164 stilpnomelane-Fe 13.02 10.09 -2.93 -0.087 0.49985E+04 167 sudoite-Fe 18.30 13.43 -4.87 -0.157 0.83161E+04 168 sudoite 21.08 17.88 -3.20 -0.103 0.54580E+04 174 tephroite 18.09 13.29 -4.80 -0.685 0.81903E+04 177 topaz-H 4.62 2.13 -2.49 -0.226 0.42507E+04 178 tridymite -2.63 -3.62 -0.99 -0.331 0.16939E+04 187 wairakite 3.95 2.38 -1.57 -0.092 0.26827E+04 188 walstromite 11.51 7.49 -4.02 -0.804 0.68677E+04 189 wollastonite 10.46 7.49 -2.97 -0.595 0.50782E+04 190 pseudo-wollastonite 11.00 7.49 -3.51 -0.703 0.59980E+04 191 zoisite 22.85 19.98 -2.87 -0.131 0.49048E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.75 -3.11 -0.192 0.53029E+04 194 beidellite-H -2.33 -6.58 -4.26 -0.272 0.72696E+04 195 beidellite-K -1.52 -5.71 -4.19 -0.257 0.71538E+04 196 beidellite-Mg -1.79 -5.16 -3.37 -0.209 0.57568E+04 197 beidellite-Na -1.34 -5.22 -3.88 -0.238 0.66236E+04 199 chalcedony -2.80 -3.62 -0.82 -0.272 0.13932E+04 201 montmorillonite-Ca -2.29 -5.00 -2.71 -0.167 0.46213E+04 202 montmorillonite-K -2.24 -5.96 -3.72 -0.228 0.63504E+04 203 montmorillonite-Mg -2.48 -5.41 -2.93 -0.181 0.49984E+04 204 montmorillonite-Na -2.04 -5.47 -3.43 -0.210 0.58558E+04 205 nontronite-Ca 3.21 2.07 -1.15 -0.074 0.19586E+04 206 nontronite-H 2.53 0.24 -2.30 -0.154 0.39232E+04 207 nontronite-K 3.34 1.11 -2.23 -0.143 0.38109E+04 208 nontronite-Mg 3.07 1.66 -1.42 -0.092 0.24198E+04 209 nontronite-Na 3.52 1.60 -1.92 -0.123 0.32823E+04 214 gypsum -4.96 -9.24 -4.28 -1.070 0.73093E+04 224 tobermorite 9.82 5.63 -4.19 -1.143 0.71553E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.39 -3.42 -0.855 0.58370E+04 240 silica-amorphous -2.09 -3.62 -1.53 -0.509 0.26074E+04 242 an20ab80 2.02 -1.16 -3.18 -0.244 0.54248E+04 243 an25ab75 2.65 -0.49 -3.13 -0.241 0.53470E+04 244 an30ab70 3.28 0.19 -3.09 -0.238 0.52789E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0310000 g New total amount of reactant added: 0.0320000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0320000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3018759E-03 Osmotic coef. = 0.9896 True ionic strength = .3169983E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14928E-07 -7.8260 0.14319E-07 -7.8441 0.95922E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13232E-03 -3.8784 0.95909E+00 -0.0181 4 SO4-- 0.25322E-04 -4.5965 0.22612E-04 -4.6457 0.89297E+00 -0.0492 5 HCO3- 0.12587E-04 -4.9001 0.12073E-04 -4.9182 0.95912E+00 -0.0181 6 HS- 0.22951E-11 -11.6392 0.22012E-11 -11.6573 0.95909E+00 -0.0181 7 Al+++ 0.27703E-20 -20.5575 0.21952E-20 -20.6585 0.79239E+00 -0.1011 8 H4SiO4 0.24627E-03 -3.6086 0.24627E-03 -3.6086 0.10000E+01 0.0000 9 Ca++ 0.27987E-04 -4.5531 0.24987E-04 -4.6023 0.89282E+00 -0.0492 10 Mg++ 0.94588E-07 -7.0242 0.84440E-07 -7.0735 0.89272E+00 -0.0493 11 Fe++ 0.56010E-09 -9.2517 0.50002E-09 -9.3010 0.89274E+00 -0.0493 12 K+ 0.67915E-05 -5.1680 0.65139E-05 -5.1862 0.95912E+00 -0.0181 13 Na+ 0.20018E-03 -3.6986 0.19199E-03 -3.7167 0.95908E+00 -0.0181 14 Mn++ 0.64681E-07 -7.1892 0.57745E-07 -7.2385 0.89276E+00 -0.0493 15 HPO4-- 0.16207E-08 -8.7903 0.14473E-08 -8.8394 0.89297E+00 -0.0492 16 HSiO3- 0.16744E-04 -4.7761 0.16059E-04 -4.7943 0.95909E+00 -0.0181 17 Ca(HSiO3)+ 0.95275E-08 -8.0210 0.91381E-08 -8.0391 0.95913E+00 -0.0181 18 Mg(HSiO3)+ 0.40070E-10 -10.3972 0.38432E-10 -10.4153 0.95913E+00 -0.0181 19 NaHSiO3,aq 0.49864E-07 -7.3022 0.49864E-07 -7.3022 0.10000E+01 0.0000 20 AlO+ 0.15185E-11 -11.8186 0.14565E-11 -11.8367 0.95913E+00 -0.0181 21 AlOH+2 0.11632E-15 -15.9343 0.10385E-15 -15.9836 0.89278E+00 -0.0493 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.32650E-05 -5.4861 0.31313E-05 -5.5043 0.95904E+00 -0.0182 24 CH4,aq 0.11417E-17 -17.9425 0.11416E-17 -17.9425 0.99991E+00 0.0000 29 CO,aq 0.57095E-17 -17.2434 0.57095E-17 -17.2434 0.10000E+01 0.0000 30 CO2,aq 0.36942E-06 -6.4325 0.36939E-06 -6.4325 0.99991E+00 0.0000 31 CO3-2 0.82471E-07 -7.0837 0.73640E-07 -7.1329 0.89292E+00 -0.0492 32 CaCO3,aq 0.23072E-07 -7.6369 0.23072E-07 -7.6369 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.80282E-08 -8.0954 0.77000E-08 -8.1135 0.95913E+00 -0.0181 34 CaCl+ 0.55784E-08 -8.2535 0.53504E-08 -8.2716 0.95913E+00 -0.0181 35 CaCl2,aq 0.16819E-12 -12.7742 0.16819E-12 -12.7742 0.10000E+01 0.0000 36 CaOH+ 0.12966E-06 -6.8872 0.12436E-06 -6.9053 0.95913E+00 -0.0181 37 CaSO4,aq 0.17941E-06 -6.7461 0.17941E-06 -6.7461 0.10000E+01 0.0000 38 HCl,aq 0.34720E-12 -12.4594 0.34720E-12 -12.4594 0.10000E+01 0.0000 43 FeCl+ 0.10918E-12 -12.9618 0.10472E-12 -12.9800 0.95913E+00 -0.0181 46 FeO,aq 0.94777E-10 -10.0233 0.94777E-10 -10.0233 0.10000E+01 0.0000 47 FeOH+ 0.11851E-08 -8.9262 0.11367E-08 -8.9444 0.95913E+00 -0.0181 48 HFeO2- 0.72208E-10 -10.1414 0.69253E-10 -10.1596 0.95909E+00 -0.0181 49 FeO+ 0.11396E-12 -12.9433 0.10930E-12 -12.9614 0.95913E+00 -0.0181 50 FeOH+2 0.33478E-18 -18.4752 0.29889E-18 -18.5245 0.89278E+00 -0.0493 51 FeO2- 0.11373E-09 -9.9441 0.10907E-09 -9.9623 0.95909E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.61535E-09 -9.2109 0.61529E-09 -9.2109 0.99991E+00 0.0000 54 KCl,aq 0.15621E-10 -10.8063 0.15621E-10 -10.8063 0.10000E+01 0.0000 55 KHSO4,aq 0.59633E-17 -17.2245 0.59633E-17 -17.2245 0.10000E+01 0.0000 56 KOH,aq 0.19427E-09 -9.7116 0.19427E-09 -9.7116 0.10000E+01 0.0000 57 KSO4- 0.23831E-08 -8.6229 0.22856E-08 -8.6410 0.95909E+00 -0.0181 58 MgCO3,aq 0.19544E-10 -10.7090 0.19544E-10 -10.7090 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27722E-10 -10.5572 0.26589E-10 -10.5753 0.95913E+00 -0.0181 60 MgCl+ 0.17086E-10 -10.7674 0.16388E-10 -10.7855 0.95913E+00 -0.0181 61 MgOH+ 0.24247E-08 -8.6153 0.23256E-08 -8.6335 0.95913E+00 -0.0181 63 MnO,aq 0.29165E-09 -9.5351 0.29165E-09 -9.5351 0.10000E+01 0.0000 64 MnOH+ 0.12714E-07 -7.8957 0.12194E-07 -7.9138 0.95913E+00 -0.0181 65 MnO2-2 0.52864E-16 -16.2768 0.47204E-16 -16.3260 0.89292E+00 -0.0492 66 HMnO2- 0.15440E-12 -12.8113 0.14809E-12 -12.8295 0.95909E+00 -0.0181 69 MnCl+ 0.49055E-10 -10.3093 0.47050E-10 -10.3274 0.95913E+00 -0.0181 70 MnSO4,aq 0.37695E-09 -9.4237 0.37695E-09 -9.4237 0.10000E+01 0.0000 71 NaCl,aq 0.84186E-08 -8.0748 0.84186E-08 -8.0748 0.10000E+01 0.0000 72 NaOH,aq 0.57605E-08 -8.2395 0.57605E-08 -8.2395 0.10000E+01 0.0000 74 OH- 0.42072E-04 -4.3760 0.40349E-04 -4.3942 0.95904E+00 -0.0182 82 H3PO4,aq 0.20755E-14 -14.6829 0.20755E-14 -14.6829 0.10000E+01 0.0000 83 H2PO4- 0.39860E-09 -9.3995 0.38230E-09 -9.4176 0.95911E+00 -0.0181 84 PO4-3 0.10395E-12 -12.9832 0.82463E-13 -13.0837 0.79331E+00 -0.1006 87 H2P2O7-2 0.12834E-19 -19.8916 0.11460E-19 -19.9408 0.89292E+00 -0.0492 88 HP2O7-3 0.20167E-18 -18.6954 0.15981E-18 -18.7964 0.79240E+00 -0.1011 90 H2S,aq 0.97424E-13 -13.0113 0.97415E-13 -13.0114 0.99991E+00 0.0000 96 SO2,aq 0.12740E-19 -19.8948 0.12740E-19 -19.8948 0.10000E+01 0.0000 97 SO3-2 0.20241E-14 -14.6938 0.18080E-14 -14.7428 0.89323E+00 -0.0490 98 HSO3- 0.16901E-14 -14.7721 0.16210E-14 -14.7902 0.95909E+00 -0.0181 99 HSO4- 0.32533E-09 -9.4877 0.31204E-09 -9.5058 0.95915E+00 -0.0181 101 S2O3-2 0.28978E-19 -19.5379 0.25875E-19 -19.5871 0.89292E+00 -0.0492 Charge balance for all species = 0.2019E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1492815E-07 -.7187023E-04 -.7243814E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999605E+06 0.0000 3 Cl- 0.1379616E-03 0.1379757E-03 0.4891468E+01 3.9657 4 SO4-- 0.2532225E-04 0.2550463E-04 0.2449923E+01 11.0425 5 HCO3- 0.1258711E-04 0.1307014E-04 0.7974735E+00 2.9259 6 HS- 0.2295067E-11 0.1171705E-09 0.3874917E-05 -3.8133 7 Al+++ 0.2770331E-20 0.3285239E-05 0.8863733E-01 2.8737 8 H4SiO4 0.2462682E-03 0.2630714E-03 0.2528425E+02 -3.6086 9 Ca++ 0.2798659E-04 0.2834187E-04 0.1135843E+01 11.0859 10 Mg++ 0.9458761E-07 0.9711669E-07 0.2361012E-02 8.6147 11 Fe++ 0.5600967E-09 0.2224766E-08 0.1242418E-03 6.3871 12 K+ 0.6791537E-05 0.6794130E-05 0.2656540E+00 2.6579 13 Na+ 0.2001770E-03 0.2002410E-03 0.4603327E+01 4.1273 14 Mn++ 0.6468119E-07 0.7811280E-07 0.4291199E-02 8.4497 15 HPO4-- 0.1620745E-08 0.2019455E-08 0.1938180E-03 6.8487 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5168325E-03 -.7186944E-04 -.4449631E-03 0.0000000E+00 2 H2O 0.5550785E+02 0.5550767E+02 0.1806294E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2639130E-04 0.2550435E-04 0.8869463E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8868291E-06 0.1171692E-09 -.8869463E-06 0.0000000E+00 7 Al+++ 0.1043437E-03 0.3285203E-05 0.1010585E-03 0.0000000E+00 8 H4SiO4 0.3332091E-03 0.2630684E-03 0.7014060E-04 0.0000000E+00 9 Ca++ 0.5127562E-04 0.2834156E-04 0.2293407E-04 0.0000000E+00 10 Mg++ 0.2539683E-04 0.9711562E-07 0.2529971E-04 0.0000000E+00 11 Fe++ 0.2281627E-04 0.2224741E-08 0.2281405E-04 0.0000000E+00 12 K+ 0.6794055E-05 0.6794055E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2002388E-03 0.2002388E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5548351E-06 0.7811194E-07 0.4767231E-06 0.0000000E+00 15 HPO4-- 0.1893625E-06 0.2019433E-08 0.1873430E-06 0.0000000E+00 Chg. balance for solid moles: 0.8137E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0320000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6245E-07 -7.204 0.3137E-04 -4.504 0.2066 0.9968E-05 clinochlore 0.5060E-05 -5.296 0.2812E-02 -2.551 18.52 0.1070E-02 daphnite 0.3144E-05 -5.503 0.2243E-02 -2.649 14.77 0.6797E-03 chlorite-Mn 0.9534E-07 -7.021 0.6760E-04 -4.170 0.4452 0.2154E-04 diaspore 0.3922E-04 -4.407 0.2353E-02 -2.628 15.50 0.7004E-03 hematite 0.3548E-05 -5.450 0.5666E-03 -3.247 3.732 0.1074E-03 lawsonite 0.2262E-04 -4.645 0.7109E-02 -2.148 46.82 0.2292E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3788E+00 0.3788E+00 1.0000 -0.422 chlorite-Mn 0.1149E-01 0.1149E-01 1.0000 -1.940 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.015182 g Volume = 0.004881 cm3 Porosity: 99.5181% V(tot) - V(min): 0.10079E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0320000 g log = -1.4949 Original solution: 1000.0103000 g Original solution / Rock added: 31250.32 (Water/Rock Ratio), log = 4.4949 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3846E-04 1.0071 0.3952E-04 0.3924E-04 CH4,gas 0.1626E-14 1.0125 0.1680E-14 0.1660E-14 H2,gas 0.7913E-06 1.0005 0.8078E-06 0.8074E-06 H2S,gas 0.2635E-11 0.9960 0.2678E-11 0.2689E-11 S2,gas 0.4043E-30 1.0000 0.4125E-30 0.4125E-30 CO,gas 0.8339E-14 1.0000 0.8508E-14 0.8508E-14 SO3,gas 0.1718E-35 1.0000 0.1753E-35 0.1753E-35 SO2,gas 0.5400E-19 1.0000 0.5509E-19 0.5509E-19 HCl,gas 0.6004E-15 1.0000 0.6126E-15 0.6126E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.76 -6.10 -2.034 0.10419E+05 -4.403 3 CH4,gas 4.54 -11.93 -16.47 -4.118 0.28128E+05 -14.775 4 H2,gas 8.00 0.21 -7.79 -4.452 0.13304E+05 -6.093 5 H2S,gas -6.23 -19.50 -13.27 -6.636 0.22660E+05 -11.572 6 S2,gas -7.34 -39.42 -32.08 -4.936 0.54782E+05 -30.385 7 CO,gas 3.21 -12.55 -15.77 -4.852 0.26925E+05 -14.070 8 SO3,gas 17.12 -20.33 -37.46 -9.364 0.63954E+05 -35.756 9 SO2,gas 0.83 -20.13 -20.96 -5.589 0.35785E+05 -19.259 10 HCl,gas 5.19 -11.72 -16.91 -8.456 0.28876E+05 -15.213 11 acmite 7.71 3.19 -4.52 -0.469 0.77117E+04 15 albite-high 0.69 -3.82 -4.52 -0.348 0.77140E+04 16 albite -0.38 -3.82 -3.44 -0.265 0.58752E+04 19 spessartine 24.46 20.27 -4.19 -0.209 0.71487E+04 20 analcite 3.32 -0.22 -3.54 -0.393 0.60410E+04 21 andalusite 5.00 2.14 -2.86 -0.286 0.48880E+04 22 andradite 39.01 35.00 -4.01 -0.208 0.68483E+04 23 grossular 32.73 28.18 -4.55 -0.228 0.77728E+04 24 anhydrite -5.32 -9.25 -3.93 -1.966 0.67123E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.68 -2.64 -0.881 0.45127E+04 36 brucite 12.57 8.61 -3.95 -0.791 0.67511E+04 37 calcite 0.81 -1.68 -2.49 -0.829 0.42485E+04 40 carpholite-Mg 8.58 7.14 -1.44 -0.096 0.24539E+04 41 carpholite-Fe 6.71 4.92 -1.80 -0.120 0.30654E+04 50 chloritoid-Mg 13.20 10.75 -2.44 -0.163 0.41734E+04 51 chloritoid-Fe 9.17 8.53 -0.65 -0.043 0.11059E+04 52 chloritoid-Mn 11.40 10.59 -0.81 -0.054 0.13875E+04 54 coesite -2.38 -3.61 -1.23 -0.411 0.21045E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.61 -1.05 -0.349 0.17899E+04 67 diopside 16.18 12.48 -3.70 -0.370 0.63142E+04 68 hedenbergite 14.21 10.26 -3.95 -0.395 0.67487E+04 75 epidote 24.67 23.38 -1.29 -0.063 0.22086E+04 76 clinozoisite 22.81 19.97 -2.84 -0.129 0.48475E+04 77 epidote-Fe 29.84 26.79 -3.05 -0.159 0.52163E+04 78 fayalite 14.05 9.17 -4.88 -0.697 0.83325E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.94 -4.20 -0.350 0.71633E+04 91 heulandite -5.83 -8.43 -2.60 -0.118 0.44388E+04 95 jadeite 4.22 -0.22 -4.43 -0.443 0.75665E+04 98 kaolinite -1.33 -1.47 -0.14 -0.012 0.23396E+03 99 kyanite 4.88 2.14 -2.74 -0.274 0.46739E+04 101 laumontite 2.88 2.40 -0.48 -0.032 0.82731E+03 105 lizardite 23.24 18.63 -4.62 -0.385 0.78833E+04 106 magnesite 0.69 -4.15 -4.84 -1.613 0.82611E+04 107 magnetite 20.09 18.95 -1.13 -0.093 0.19364E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.29 -2.81 -0.216 0.47940E+04 120 muscovite 2.58 0.45 -2.13 -0.125 0.36355E+04 121 paragonite 4.24 1.92 -2.32 -0.136 0.39558E+04 122 nepheline 8.34 3.39 -4.95 -0.707 0.84469E+04 136 prehnite 19.37 17.09 -2.28 -0.134 0.38905E+04 137 prehnite-Fe 22.50 20.50 -2.00 -0.120 0.34066E+04 138 pumpellyite-Fe 46.27 43.45 -2.82 -0.063 0.48183E+04 139 pumpellyite-Mg 48.99 45.68 -3.32 -0.074 0.56685E+04 145 pyroxmangite 7.40 4.84 -2.56 -0.512 0.43670E+04 146 pyrophyllite -6.18 -8.69 -2.51 -0.157 0.42878E+04 147 quartz -2.99 -3.61 -0.62 -0.206 0.10572E+04 151 rhodochrosite -0.98 -4.31 -3.34 -1.112 0.56966E+04 152 rhodonite 7.45 4.84 -2.60 -0.521 0.44473E+04 153 sanidine -1.28 -5.29 -4.02 -0.309 0.68618E+04 155 siderite -2.61 -6.38 -3.77 -1.256 0.64320E+04 156 sillimanite 5.26 2.14 -3.12 -0.312 0.53320E+04 163 stilbite -7.52 -8.43 -0.90 -0.043 0.15450E+04 164 stilpnomelane-Fe 13.02 10.14 -2.87 -0.086 0.49067E+04 167 sudoite-Fe 18.30 13.44 -4.85 -0.157 0.82862E+04 168 sudoite 21.08 17.90 -3.18 -0.103 0.54280E+04 174 tephroite 18.09 13.29 -4.80 -0.685 0.81874E+04 177 topaz-H 4.62 2.14 -2.48 -0.225 0.42340E+04 178 tridymite -2.63 -3.61 -0.98 -0.327 0.16772E+04 187 wairakite 3.95 2.40 -1.55 -0.091 0.26493E+04 188 walstromite 11.51 7.48 -4.03 -0.806 0.68845E+04 189 wollastonite 10.46 7.48 -2.98 -0.597 0.50949E+04 190 pseudo-wollastonite 11.00 7.48 -3.52 -0.705 0.60147E+04 191 zoisite 22.85 19.97 -2.88 -0.131 0.49216E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.72 -3.07 -0.190 0.52471E+04 194 beidellite-H -2.33 -6.55 -4.22 -0.269 0.72082E+04 195 beidellite-K -1.52 -5.67 -4.15 -0.254 0.70868E+04 196 beidellite-Mg -1.79 -5.13 -3.34 -0.206 0.56972E+04 197 beidellite-Na -1.34 -5.19 -3.84 -0.235 0.65628E+04 199 chalcedony -2.80 -3.61 -0.81 -0.269 0.13765E+04 201 montmorillonite-Ca -2.29 -4.96 -2.67 -0.165 0.45633E+04 202 montmorillonite-K -2.24 -5.92 -3.68 -0.225 0.62811E+04 203 montmorillonite-Mg -2.48 -5.37 -2.89 -0.179 0.49365E+04 204 montmorillonite-Na -2.04 -5.43 -3.39 -0.208 0.57928E+04 205 nontronite-Ca 3.21 2.10 -1.11 -0.072 0.19028E+04 206 nontronite-H 2.53 0.27 -2.26 -0.152 0.38618E+04 207 nontronite-K 3.34 1.15 -2.19 -0.141 0.37438E+04 208 nontronite-Mg 3.07 1.69 -1.38 -0.090 0.23601E+04 209 nontronite-Na 3.52 1.63 -1.89 -0.121 0.32215E+04 214 gypsum -4.96 -9.25 -4.29 -1.073 0.73299E+04 224 tobermorite 9.82 5.63 -4.20 -1.145 0.71665E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.39 -3.42 -0.856 0.58471E+04 240 silica-amorphous -2.09 -3.61 -1.52 -0.506 0.25907E+04 242 an20ab80 2.02 -1.14 -3.15 -0.243 0.53860E+04 243 an25ab75 2.65 -0.46 -3.11 -0.239 0.53106E+04 244 an30ab70 3.28 0.21 -3.07 -0.236 0.52449E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0320000 g New total amount of reactant added: 0.0330000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0330000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3008973E-03 Osmotic coef. = 0.9896 True ionic strength = .3161026E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15047E-07 -7.8226 0.14433E-07 -7.8406 0.95925E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13232E-03 -3.8784 0.95912E+00 -0.0181 4 SO4-- 0.25327E-04 -4.5964 0.22619E-04 -4.6455 0.89308E+00 -0.0491 5 HCO3- 0.12586E-04 -4.9001 0.12072E-04 -4.9182 0.95915E+00 -0.0181 6 HS- 0.20789E-11 -11.6822 0.19939E-11 -11.7003 0.95912E+00 -0.0181 7 Al+++ 0.28362E-20 -20.5473 0.22480E-20 -20.6482 0.79262E+00 -0.1009 8 H4SiO4 0.25178E-03 -3.5990 0.25178E-03 -3.5990 0.10000E+01 0.0000 9 Ca++ 0.27199E-04 -4.5655 0.24287E-04 -4.6146 0.89293E+00 -0.0492 10 Mg++ 0.94818E-07 -7.0231 0.84657E-07 -7.0723 0.89284E+00 -0.0492 11 Fe++ 0.56141E-09 -9.2507 0.50126E-09 -9.2999 0.89286E+00 -0.0492 12 K+ 0.70038E-05 -5.1547 0.67177E-05 -5.1728 0.95916E+00 -0.0181 13 Na+ 0.20143E-03 -3.6959 0.19320E-03 -3.7140 0.95911E+00 -0.0181 14 Mn++ 0.65101E-07 -7.1864 0.58127E-07 -7.2356 0.89288E+00 -0.0492 15 HPO4-- 0.17172E-08 -8.7652 0.15336E-08 -8.8143 0.89309E+00 -0.0491 16 HSiO3- 0.16983E-04 -4.7700 0.16289E-04 -4.7881 0.95912E+00 -0.0181 17 Ca(HSiO3)+ 0.93928E-08 -8.0272 0.90092E-08 -8.0453 0.95916E+00 -0.0181 18 Mg(HSiO3)+ 0.40746E-10 -10.3899 0.39082E-10 -10.4080 0.95916E+00 -0.0181 19 NaHSiO3,aq 0.50896E-07 -7.2933 0.50896E-07 -7.2933 0.10000E+01 0.0000 20 AlO+ 0.15306E-11 -11.8151 0.14681E-11 -11.8333 0.95916E+00 -0.0181 21 AlOH+2 0.11816E-15 -15.9275 0.10551E-15 -15.9767 0.89290E+00 -0.0492 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.32391E-05 -5.4896 0.31065E-05 -5.5077 0.95908E+00 -0.0181 24 CH4,aq 0.10338E-17 -17.9856 0.10337E-17 -17.9856 0.99991E+00 0.0000 29 CO,aq 0.56025E-17 -17.2516 0.56025E-17 -17.2516 0.10000E+01 0.0000 30 CO2,aq 0.37234E-06 -6.4291 0.37230E-06 -6.4291 0.99991E+00 0.0000 31 CO3-2 0.81804E-07 -7.0872 0.73054E-07 -7.1364 0.89304E+00 -0.0491 32 CaCO3,aq 0.22247E-07 -7.6527 0.22247E-07 -7.6527 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.78025E-08 -8.1078 0.74838E-08 -8.1259 0.95916E+00 -0.0181 34 CaCl+ 0.54221E-08 -8.2658 0.52007E-08 -8.2839 0.95916E+00 -0.0181 35 CaCl2,aq 0.16349E-12 -12.7865 0.16349E-12 -12.7865 0.10000E+01 0.0000 36 CaOH+ 0.12503E-06 -6.9030 0.11992E-06 -6.9211 0.95916E+00 -0.0181 37 CaSO4,aq 0.17444E-06 -6.7583 0.17444E-06 -6.7583 0.10000E+01 0.0000 38 HCl,aq 0.34997E-12 -12.4560 0.34997E-12 -12.4560 0.10000E+01 0.0000 43 FeCl+ 0.10945E-12 -12.9608 0.10498E-12 -12.9789 0.95916E+00 -0.0181 46 FeO,aq 0.93516E-10 -10.0291 0.93516E-10 -10.0291 0.10000E+01 0.0000 47 FeOH+ 0.11786E-08 -8.9286 0.11305E-08 -8.9467 0.95916E+00 -0.0181 48 HFeO2- 0.70682E-10 -10.1507 0.67792E-10 -10.1688 0.95912E+00 -0.0181 49 FeO+ 0.11486E-12 -12.9398 0.11017E-12 -12.9579 0.95916E+00 -0.0181 50 FeOH+2 0.34009E-18 -18.4684 0.30366E-18 -18.5176 0.89290E+00 -0.0492 51 FeO2- 0.11282E-09 -9.9476 0.10821E-09 -9.9657 0.95912E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.59909E-09 -9.2225 0.59903E-09 -9.2226 0.99991E+00 0.0000 54 KCl,aq 0.16111E-10 -10.7929 0.16111E-10 -10.7929 0.10000E+01 0.0000 55 KHSO4,aq 0.62009E-17 -17.2075 0.62009E-17 -17.2075 0.10000E+01 0.0000 56 KOH,aq 0.19876E-09 -9.7017 0.19876E-09 -9.7017 0.10000E+01 0.0000 57 KSO4- 0.24584E-08 -8.6093 0.23579E-08 -8.6275 0.95912E+00 -0.0181 58 MgCO3,aq 0.19438E-10 -10.7114 0.19438E-10 -10.7114 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27791E-10 -10.5561 0.26656E-10 -10.5742 0.95916E+00 -0.0181 60 MgCl+ 0.17130E-10 -10.7662 0.16430E-10 -10.7843 0.95916E+00 -0.0181 61 MgOH+ 0.24116E-08 -8.6177 0.23131E-08 -8.6358 0.95916E+00 -0.0181 63 MnO,aq 0.28896E-09 -9.5392 0.28896E-09 -9.5392 0.10000E+01 0.0000 64 MnOH+ 0.12696E-07 -7.8963 0.12178E-07 -7.9144 0.95916E+00 -0.0181 65 MnO2-2 0.51546E-16 -16.2878 0.46033E-16 -16.3369 0.89304E+00 -0.0491 66 HMnO2- 0.15177E-12 -12.8188 0.14556E-12 -12.8370 0.95912E+00 -0.0181 69 MnCl+ 0.49380E-10 -10.3064 0.47363E-10 -10.3246 0.95916E+00 -0.0181 70 MnSO4,aq 0.37957E-09 -9.4207 0.37957E-09 -9.4207 0.10000E+01 0.0000 71 NaCl,aq 0.84719E-08 -8.0720 0.84719E-08 -8.0720 0.10000E+01 0.0000 72 NaOH,aq 0.57510E-08 -8.2403 0.57510E-08 -8.2403 0.10000E+01 0.0000 74 OH- 0.41738E-04 -4.3795 0.40030E-04 -4.3976 0.95908E+00 -0.0181 82 H3PO4,aq 0.22345E-14 -14.6508 0.22345E-14 -14.6508 0.10000E+01 0.0000 83 H2PO4- 0.42573E-09 -9.3709 0.40834E-09 -9.3890 0.95914E+00 -0.0181 84 PO4-3 0.10925E-12 -12.9616 0.86692E-13 -13.0620 0.79354E+00 -0.1004 87 H2P2O7-2 0.14640E-19 -19.8345 0.13074E-19 -19.8836 0.89304E+00 -0.0491 88 HP2O7-3 0.22819E-18 -18.6417 0.18087E-18 -18.7426 0.79263E+00 -0.1009 90 H2S,aq 0.88954E-13 -13.0508 0.88945E-13 -13.0509 0.99991E+00 0.0000 96 SO2,aq 0.12606E-19 -19.8994 0.12606E-19 -19.8994 0.10000E+01 0.0000 97 SO3-2 0.19710E-14 -14.7053 0.17608E-14 -14.7543 0.89334E+00 -0.0490 98 HSO3- 0.16590E-14 -14.7801 0.15912E-14 -14.7983 0.95912E+00 -0.0181 99 HSO4- 0.32802E-09 -9.4841 0.31463E-09 -9.5022 0.95918E+00 -0.0181 101 S2O3-2 0.26464E-19 -19.5773 0.23633E-19 -19.6265 0.89304E+00 -0.0491 Charge balance for all species = 0.2020E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1504652E-07 -.7166364E-04 -.7222988E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999600E+06 0.0000 3 Cl- 0.1379618E-03 0.1379757E-03 0.4891466E+01 3.9623 4 SO4-- 0.2532715E-04 0.2550465E-04 0.2449923E+01 11.0357 5 HCO3- 0.1258591E-04 0.1307015E-04 0.7974733E+00 2.9224 6 HS- 0.2078906E-11 0.1129925E-09 0.3736746E-05 -3.8597 7 Al+++ 0.2836195E-20 0.3259341E-05 0.8793853E-01 2.8737 8 H4SiO4 0.2517817E-03 0.2688248E-03 0.2583722E+02 -3.5990 9 Ca++ 0.2719881E-04 0.2754315E-04 0.1103832E+01 11.0666 10 Mg++ 0.9481834E-07 0.9733506E-07 0.2366319E-02 8.6089 11 Fe++ 0.5614073E-09 0.2215895E-08 0.1237464E-03 6.3813 12 K+ 0.7003776E-05 0.7006449E-05 0.2739557E+00 2.6679 13 Na+ 0.2014312E-03 0.2014963E-03 0.4632183E+01 4.1266 14 Mn++ 0.6510080E-07 0.7851532E-07 0.4313310E-02 8.4456 15 HPO4-- 0.1717204E-08 0.2143047E-08 0.2056796E-03 6.8670 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5333910E-03 -.7166282E-04 -.4617282E-03 0.0000000E+00 2 H2O 0.5550784E+02 0.5550765E+02 0.1840685E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2641901E-04 0.2550436E-04 0.9146555E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9145425E-06 0.1129913E-09 -.9146555E-06 0.0000000E+00 7 Al+++ 0.1076045E-03 0.3259304E-05 0.1043452E-03 0.0000000E+00 8 H4SiO4 0.3436218E-03 0.2688218E-03 0.7480005E-04 0.0000000E+00 9 Ca++ 0.5242577E-04 0.2754283E-04 0.2488293E-04 0.0000000E+00 10 Mg++ 0.2619048E-04 0.9733396E-07 0.2609314E-04 0.0000000E+00 11 Fe++ 0.2352928E-04 0.2215870E-08 0.2352707E-04 0.0000000E+00 12 K+ 0.7006369E-05 0.7006369E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2014940E-03 0.2014940E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5721737E-06 0.7851444E-07 0.4936592E-06 0.0000000E+00 15 HPO4-- 0.1952800E-06 0.2143023E-08 0.1931370E-06 0.0000000E+00 Chg. balance for solid moles: -.1097E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0330000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6438E-07 -7.191 0.3234E-04 -4.490 0.2033 0.1028E-04 clinochlore 0.5219E-05 -5.282 0.2901E-02 -2.538 18.24 0.1103E-02 daphnite 0.3242E-05 -5.489 0.2313E-02 -2.636 14.54 0.7010E-03 chlorite-Mn 0.9873E-07 -7.006 0.7000E-04 -4.155 0.4401 0.2231E-04 diaspore 0.3810E-04 -4.419 0.2286E-02 -2.641 14.37 0.6805E-03 hematite 0.3659E-05 -5.437 0.5843E-03 -3.233 3.674 0.1107E-03 lawsonite 0.2456E-04 -4.610 0.7718E-02 -2.112 48.53 0.2489E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3788E+00 0.3788E+00 1.0000 -0.422 chlorite-Mn 0.1154E-01 0.1154E-01 1.0000 -1.938 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.015904 g Volume = 0.005117 cm3 Porosity: 99.4950% V(tot) - V(min): 0.10081E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0330000 g log = -1.4815 Original solution: 1000.0103000 g Original solution / Rock added: 30303.34 (Water/Rock Ratio), log = 4.4815 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3876E-04 1.0071 0.3983E-04 0.3955E-04 CH4,gas 0.1473E-14 1.0125 0.1522E-14 0.1503E-14 H2,gas 0.7704E-06 1.0005 0.7865E-06 0.7860E-06 H2S,gas 0.2406E-11 0.9960 0.2445E-11 0.2455E-11 S2,gas 0.3556E-30 1.0000 0.3628E-30 0.3628E-30 CO,gas 0.8182E-14 1.0000 0.8349E-14 0.8349E-14 SO3,gas 0.1746E-35 1.0000 0.1782E-35 0.1782E-35 SO2,gas 0.5343E-19 1.0000 0.5451E-19 0.5451E-19 HCl,gas 0.6052E-15 1.0000 0.6175E-15 0.6175E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.76 -6.10 -2.033 0.10413E+05 -4.400 3 CH4,gas 4.54 -11.97 -16.52 -4.129 0.28202E+05 -14.818 4 H2,gas 8.00 0.20 -7.80 -4.459 0.13324E+05 -6.104 5 H2S,gas -6.23 -19.54 -13.31 -6.655 0.22728E+05 -11.612 6 S2,gas -7.34 -39.47 -32.14 -4.945 0.54877E+05 -30.440 7 CO,gas 3.21 -12.56 -15.78 -4.855 0.26939E+05 -14.078 8 SO3,gas 17.12 -20.33 -37.45 -9.362 0.63942E+05 -35.749 9 SO2,gas 0.83 -20.13 -20.96 -5.590 0.35793E+05 -19.263 10 HCl,gas 5.19 -11.72 -16.91 -8.454 0.28870E+05 -15.209 11 acmite 7.71 3.21 -4.50 -0.467 0.76801E+04 15 albite-high 0.69 -3.80 -4.49 -0.345 0.76660E+04 16 albite -0.38 -3.80 -3.41 -0.263 0.58272E+04 19 spessartine 24.46 20.29 -4.17 -0.208 0.71201E+04 20 analcite 3.32 -0.20 -3.52 -0.391 0.60094E+04 21 andalusite 5.00 2.15 -2.85 -0.285 0.48716E+04 22 andradite 39.01 34.97 -4.04 -0.210 0.68975E+04 23 grossular 32.73 28.15 -4.58 -0.229 0.78221E+04 24 anhydrite -5.32 -9.26 -3.94 -1.972 0.67332E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.69 -2.66 -0.886 0.45397E+04 36 brucite 12.57 8.61 -3.96 -0.792 0.67610E+04 37 calcite 0.81 -1.69 -2.50 -0.835 0.42755E+04 40 carpholite-Mg 8.58 7.16 -1.42 -0.095 0.24310E+04 41 carpholite-Fe 6.71 4.93 -1.78 -0.119 0.30425E+04 50 chloritoid-Mg 13.20 10.76 -2.44 -0.163 0.41668E+04 51 chloritoid-Fe 9.17 8.53 -0.64 -0.043 0.10994E+04 52 chloritoid-Mn 11.40 10.59 -0.81 -0.054 0.13780E+04 54 coesite -2.38 -3.60 -1.22 -0.408 0.20881E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.60 -1.04 -0.346 0.17734E+04 67 diopside 16.18 12.48 -3.70 -0.370 0.63241E+04 68 hedenbergite 14.21 10.25 -3.96 -0.396 0.67586E+04 75 epidote 24.67 23.37 -1.30 -0.063 0.22250E+04 76 clinozoisite 22.81 19.96 -2.85 -0.129 0.48639E+04 77 epidote-Fe 29.84 26.78 -3.06 -0.159 0.52327E+04 78 fayalite 14.05 9.16 -4.88 -0.697 0.83360E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.95 -4.19 -0.349 0.71603E+04 91 heulandite -5.83 -8.38 -2.55 -0.116 0.43567E+04 95 jadeite 4.22 -0.20 -4.41 -0.441 0.75349E+04 98 kaolinite -1.33 -1.45 -0.12 -0.011 0.20112E+03 99 kyanite 4.88 2.15 -2.73 -0.273 0.46575E+04 101 laumontite 2.88 2.42 -0.47 -0.031 0.79447E+03 105 lizardite 23.24 18.63 -4.62 -0.385 0.78800E+04 106 magnesite 0.69 -4.15 -4.84 -1.614 0.82651E+04 107 magnetite 20.09 18.95 -1.14 -0.093 0.19463E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.26 -2.77 -0.213 0.47278E+04 120 muscovite 2.58 0.49 -2.09 -0.123 0.35693E+04 121 paragonite 4.24 1.95 -2.29 -0.135 0.39078E+04 122 nepheline 8.34 3.40 -4.94 -0.705 0.84317E+04 136 prehnite 19.37 17.08 -2.29 -0.135 0.39070E+04 137 prehnite-Fe 22.50 20.49 -2.00 -0.121 0.34230E+04 138 pumpellyite-Fe 46.27 43.42 -2.85 -0.063 0.48611E+04 139 pumpellyite-Mg 48.99 45.65 -3.34 -0.074 0.57112E+04 145 pyroxmangite 7.40 4.85 -2.55 -0.510 0.43575E+04 146 pyrophyllite -6.18 -8.65 -2.47 -0.155 0.42221E+04 147 quartz -2.99 -3.60 -0.61 -0.203 0.10408E+04 151 rhodochrosite -0.98 -4.31 -3.34 -1.112 0.56977E+04 152 rhodonite 7.45 4.85 -2.60 -0.520 0.44377E+04 153 sanidine -1.28 -5.26 -3.98 -0.306 0.67955E+04 155 siderite -2.61 -6.38 -3.77 -1.256 0.64361E+04 156 sillimanite 5.26 2.15 -3.11 -0.311 0.53155E+04 163 stilbite -7.52 -8.38 -0.86 -0.041 0.14629E+04 164 stilpnomelane-Fe 13.02 10.20 -2.82 -0.084 0.48165E+04 167 sudoite-Fe 18.30 13.46 -4.84 -0.156 0.82568E+04 168 sudoite 21.08 17.92 -3.16 -0.102 0.53984E+04 174 tephroite 18.09 13.29 -4.79 -0.685 0.81848E+04 177 topaz-H 4.62 2.15 -2.47 -0.225 0.42176E+04 178 tridymite -2.63 -3.60 -0.97 -0.324 0.16608E+04 187 wairakite 3.95 2.42 -1.53 -0.090 0.26164E+04 188 walstromite 11.51 7.47 -4.04 -0.808 0.69009E+04 189 wollastonite 10.46 7.47 -2.99 -0.599 0.51113E+04 190 pseudo-wollastonite 11.00 7.47 -3.53 -0.706 0.60311E+04 191 zoisite 22.85 19.96 -2.89 -0.131 0.49380E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.69 -3.04 -0.188 0.51923E+04 194 beidellite-H -2.33 -6.51 -4.19 -0.267 0.71480E+04 195 beidellite-K -1.52 -5.63 -4.11 -0.252 0.70210E+04 196 beidellite-Mg -1.79 -5.09 -3.30 -0.204 0.56385E+04 197 beidellite-Na -1.34 -5.15 -3.81 -0.233 0.65029E+04 199 chalcedony -2.80 -3.60 -0.80 -0.266 0.13601E+04 201 montmorillonite-Ca -2.29 -4.93 -2.64 -0.163 0.45063E+04 202 montmorillonite-K -2.24 -5.88 -3.64 -0.223 0.62131E+04 203 montmorillonite-Mg -2.48 -5.34 -2.86 -0.177 0.48757E+04 204 montmorillonite-Na -2.04 -5.39 -3.36 -0.206 0.57308E+04 205 nontronite-Ca 3.21 2.13 -1.08 -0.070 0.18480E+04 206 nontronite-H 2.53 0.31 -2.23 -0.149 0.38016E+04 207 nontronite-K 3.34 1.19 -2.15 -0.138 0.36780E+04 208 nontronite-Mg 3.07 1.73 -1.35 -0.087 0.23015E+04 209 nontronite-Na 3.52 1.67 -1.85 -0.119 0.31616E+04 214 gypsum -4.96 -9.26 -4.31 -1.076 0.73507E+04 224 tobermorite 9.82 5.62 -4.20 -1.147 0.71774E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.38 -3.43 -0.858 0.58571E+04 240 silica-amorphous -2.09 -3.60 -1.51 -0.503 0.25742E+04 242 an20ab80 2.02 -1.11 -3.13 -0.241 0.53475E+04 243 an25ab75 2.65 -0.44 -3.09 -0.238 0.52746E+04 244 an30ab70 3.28 0.23 -3.05 -0.235 0.52113E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0330000 g New total amount of reactant added: 0.0340000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0340000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2999585E-03 Osmotic coef. = 0.9896 True ionic strength = .3152536E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15158E-07 -7.8194 0.14541E-07 -7.8374 0.95928E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13233E-03 -3.8784 0.95915E+00 -0.0181 4 SO4-- 0.25332E-04 -4.5963 0.22626E-04 -4.6454 0.89319E+00 -0.0491 5 HCO3- 0.12585E-04 -4.9002 0.12071E-04 -4.9183 0.95918E+00 -0.0181 6 HS- 0.18856E-11 -11.7245 0.18086E-11 -11.7427 0.95915E+00 -0.0181 7 Al+++ 0.28993E-20 -20.5377 0.22987E-20 -20.6385 0.79285E+00 -0.1008 8 H4SiO4 0.25732E-03 -3.5895 0.25732E-03 -3.5895 0.10000E+01 0.0000 9 Ca++ 0.26427E-04 -4.5780 0.23600E-04 -4.6271 0.89304E+00 -0.0491 10 Mg++ 0.94976E-07 -7.0224 0.84809E-07 -7.0716 0.89295E+00 -0.0492 11 Fe++ 0.56229E-09 -9.2500 0.50210E-09 -9.2992 0.89297E+00 -0.0492 12 K+ 0.72160E-05 -5.1417 0.69215E-05 -5.1598 0.95919E+00 -0.0181 13 Na+ 0.20269E-03 -3.6932 0.19440E-03 -3.7113 0.95914E+00 -0.0181 14 Mn++ 0.65464E-07 -7.1840 0.58458E-07 -7.2332 0.89299E+00 -0.0492 15 HPO4-- 0.18190E-08 -8.7402 0.16247E-08 -8.7892 0.89320E+00 -0.0491 16 HSiO3- 0.17228E-04 -4.7638 0.16524E-04 -4.7819 0.95915E+00 -0.0181 17 Ca(HSiO3)+ 0.92588E-08 -8.0334 0.88809E-08 -8.0515 0.95919E+00 -0.0181 18 Mg(HSiO3)+ 0.41407E-10 -10.3829 0.39718E-10 -10.4010 0.95919E+00 -0.0181 19 NaHSiO3,aq 0.51954E-07 -7.2844 0.51954E-07 -7.2844 0.10000E+01 0.0000 20 AlO+ 0.15419E-11 -11.8119 0.14790E-11 -11.8300 0.95919E+00 -0.0181 21 AlOH+2 0.11992E-15 -15.9211 0.10709E-15 -15.9703 0.89301E+00 -0.0491 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.32150E-05 -5.4928 0.30835E-05 -5.5109 0.95911E+00 -0.0181 24 CH4,aq 0.93734E-18 -18.0281 0.93726E-18 -18.0281 0.99991E+00 0.0000 29 CO,aq 0.54972E-17 -17.2599 0.54972E-17 -17.2599 0.10000E+01 0.0000 30 CO2,aq 0.37509E-06 -6.4259 0.37506E-06 -6.4259 0.99991E+00 0.0000 31 CO3-2 0.81184E-07 -7.0905 0.72510E-07 -7.1396 0.89315E+00 -0.0491 32 CaCO3,aq 0.21457E-07 -7.6684 0.21457E-07 -7.6684 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.75812E-08 -8.1203 0.72718E-08 -8.1384 0.95919E+00 -0.0181 34 CaCl+ 0.52689E-08 -8.2783 0.50538E-08 -8.2964 0.95919E+00 -0.0181 35 CaCl2,aq 0.15888E-12 -12.7989 0.15888E-12 -12.7989 0.10000E+01 0.0000 36 CaOH+ 0.12059E-06 -6.9187 0.11567E-06 -6.9368 0.95919E+00 -0.0181 37 CaSO4,aq 0.16957E-06 -6.7707 0.16957E-06 -6.7707 0.10000E+01 0.0000 38 HCl,aq 0.35259E-12 -12.4527 0.35259E-12 -12.4527 0.10000E+01 0.0000 43 FeCl+ 0.10964E-12 -12.9600 0.10517E-12 -12.9781 0.95919E+00 -0.0181 46 FeO,aq 0.92294E-10 -10.0348 0.92294E-10 -10.0348 0.10000E+01 0.0000 47 FeOH+ 0.11718E-08 -8.9311 0.11240E-08 -8.9492 0.95919E+00 -0.0181 48 HFeO2- 0.69239E-10 -10.1596 0.66411E-10 -10.1778 0.95915E+00 -0.0181 49 FeO+ 0.11571E-12 -12.9366 0.11099E-12 -12.9547 0.95919E+00 -0.0181 50 FeOH+2 0.34513E-18 -18.4620 0.30821E-18 -18.5112 0.89301E+00 -0.0491 51 FeO2- 0.11198E-09 -9.9508 0.10741E-09 -9.9690 0.95915E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.58352E-09 -9.2339 0.58347E-09 -9.2340 0.99991E+00 0.0000 54 KCl,aq 0.16600E-10 -10.7799 0.16600E-10 -10.7799 0.10000E+01 0.0000 55 KHSO4,aq 0.64386E-17 -17.1912 0.64386E-17 -17.1912 0.10000E+01 0.0000 56 KOH,aq 0.20328E-09 -9.6919 0.20328E-09 -9.6919 0.10000E+01 0.0000 57 KSO4- 0.25337E-08 -8.5962 0.24302E-08 -8.6144 0.95915E+00 -0.0181 58 MgCO3,aq 0.19327E-10 -10.7138 0.19327E-10 -10.7138 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27838E-10 -10.5554 0.26702E-10 -10.5735 0.95919E+00 -0.0181 60 MgCl+ 0.17161E-10 -10.7655 0.16460E-10 -10.7836 0.95919E+00 -0.0181 61 MgOH+ 0.23980E-08 -8.6202 0.23001E-08 -8.6383 0.95919E+00 -0.0181 63 MnO,aq 0.28632E-09 -9.5431 0.28632E-09 -9.5431 0.10000E+01 0.0000 64 MnOH+ 0.12674E-07 -7.8971 0.12157E-07 -7.9152 0.95919E+00 -0.0181 65 MnO2-2 0.50316E-16 -16.2983 0.44940E-16 -16.3474 0.89315E+00 -0.0491 66 HMnO2- 0.14926E-12 -12.8260 0.14317E-12 -12.8442 0.95915E+00 -0.0181 69 MnCl+ 0.49662E-10 -10.3040 0.47635E-10 -10.3221 0.95919E+00 -0.0181 70 MnSO4,aq 0.38185E-09 -9.4181 0.38185E-09 -9.4181 0.10000E+01 0.0000 71 NaCl,aq 0.85252E-08 -8.0693 0.85252E-08 -8.0693 0.10000E+01 0.0000 72 NaOH,aq 0.57441E-08 -8.2408 0.57441E-08 -8.2408 0.10000E+01 0.0000 74 OH- 0.41428E-04 -4.3827 0.39734E-04 -4.4008 0.95911E+00 -0.0181 82 H3PO4,aq 0.24026E-14 -14.6193 0.24026E-14 -14.6193 0.10000E+01 0.0000 83 H2PO4- 0.45436E-09 -9.3426 0.43581E-09 -9.3607 0.95917E+00 -0.0181 84 PO4-3 0.11485E-12 -12.9399 0.91161E-13 -13.0402 0.79376E+00 -0.1003 87 H2P2O7-2 0.16674E-19 -19.7780 0.14892E-19 -19.8270 0.89315E+00 -0.0491 88 HP2O7-3 0.25793E-18 -18.5885 0.20450E-18 -18.6893 0.79285E+00 -0.1008 90 H2S,aq 0.81286E-13 -13.0900 0.81279E-13 -13.0900 0.99991E+00 0.0000 96 SO2,aq 0.12466E-19 -19.9043 0.12466E-19 -19.9043 0.10000E+01 0.0000 97 SO3-2 0.19201E-14 -14.7167 0.17156E-14 -14.7656 0.89345E+00 -0.0489 98 HSO3- 0.16284E-14 -14.7882 0.15619E-14 -14.8063 0.95915E+00 -0.0181 99 HSO4- 0.33055E-09 -9.4808 0.31707E-09 -9.4988 0.95921E+00 -0.0181 101 S2O3-2 0.24187E-19 -19.6164 0.21603E-19 -19.6655 0.89315E+00 -0.0491 Charge balance for all species = 0.2021E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1515820E-07 -.7149415E-04 -.7205901E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999594E+06 0.0000 3 Cl- 0.1379619E-03 0.1379758E-03 0.4891465E+01 3.9591 4 SO4-- 0.2533195E-04 0.2550466E-04 0.2449923E+01 11.0294 5 HCO3- 0.1258479E-04 0.1307015E-04 0.7974730E+00 2.9192 6 HS- 0.1885604E-11 0.1090048E-09 0.3604867E-05 -3.9053 7 Al+++ 0.2899269E-20 0.3235278E-05 0.8728926E-01 2.8737 8 H4SiO4 0.2573213E-03 0.2746101E-03 0.2639323E+02 -3.5895 9 Ca++ 0.2642664E-04 0.2676037E-04 0.1072460E+01 11.0477 10 Mg++ 0.9497578E-07 0.9747949E-07 0.2369829E-02 8.6033 11 Fe++ 0.5622854E-09 0.2206492E-08 0.1232211E-03 6.3756 12 K+ 0.7216014E-05 0.7218767E-05 0.2822573E+00 2.6776 13 Na+ 0.2026854E-03 0.2027516E-03 0.4661038E+01 4.1261 14 Mn++ 0.6546351E-07 0.7885543E-07 0.4331991E-02 8.4417 15 HPO4-- 0.1818963E-08 0.2273443E-08 0.2181943E-03 6.8856 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5499495E-03 -.7149332E-04 -.4784562E-03 0.0000000E+00 2 H2O 0.5550782E+02 0.5550764E+02 0.1875359E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2644673E-04 0.2550436E-04 0.9423649E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9422559E-06 0.1090036E-09 -.9423649E-06 0.0000000E+00 7 Al+++ 0.1108652E-03 0.3235240E-05 0.1076300E-03 0.0000000E+00 8 H4SiO4 0.3540346E-03 0.2746069E-03 0.7942771E-04 0.0000000E+00 9 Ca++ 0.5357591E-04 0.2676005E-04 0.2681586E-04 0.0000000E+00 10 Mg++ 0.2698413E-04 0.9747835E-07 0.2688665E-04 0.0000000E+00 11 Fe++ 0.2424229E-04 0.2206466E-08 0.2424009E-04 0.0000000E+00 12 K+ 0.7218684E-05 0.7218684E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2027493E-03 0.2027493E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5895123E-06 0.7885452E-07 0.5106577E-06 0.0000000E+00 15 HPO4-- 0.2011976E-06 0.2273417E-08 0.1989242E-06 0.0000000E+00 Chg. balance for solid moles: 0.1662E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0340000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6631E-07 -7.178 0.3331E-04 -4.477 0.2004 0.1058E-04 clinochlore 0.5377E-05 -5.269 0.2989E-02 -2.524 17.98 0.1137E-02 daphnite 0.3340E-05 -5.476 0.2383E-02 -2.623 14.34 0.7222E-03 chlorite-Mn 0.1021E-06 -6.991 0.7241E-04 -4.140 0.4356 0.2307E-04 diaspore 0.3702E-04 -4.432 0.2221E-02 -2.653 13.36 0.6612E-03 hematite 0.3769E-05 -5.424 0.6020E-03 -3.220 3.621 0.1141E-03 lawsonite 0.2648E-04 -4.577 0.8322E-02 -2.080 50.07 0.2684E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3787E+00 0.3787E+00 1.0000 -0.422 chlorite-Mn 0.1158E-01 0.1158E-01 1.0000 -1.936 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.016623 g Volume = 0.005352 cm3 Porosity: 99.4720% V(tot) - V(min): 0.10082E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0340000 g log = -1.4685 Original solution: 1000.0103000 g Original solution / Rock added: 29412.07 (Water/Rock Ratio), log = 4.4685 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3905E-04 1.0071 0.4013E-04 0.3984E-04 CH4,gas 0.1335E-14 1.0125 0.1380E-14 0.1363E-14 H2,gas 0.7503E-06 1.0005 0.7660E-06 0.7656E-06 H2S,gas 0.2198E-11 0.9960 0.2234E-11 0.2243E-11 S2,gas 0.3130E-30 1.0000 0.3193E-30 0.3193E-30 CO,gas 0.8029E-14 1.0000 0.8192E-14 0.8192E-14 SO3,gas 0.1773E-35 1.0000 0.1809E-35 0.1809E-35 SO2,gas 0.5283E-19 1.0000 0.5391E-19 0.5391E-19 HCl,gas 0.6098E-15 1.0000 0.6222E-15 0.6222E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.76 -6.10 -2.032 0.10408E+05 -4.397 3 CH4,gas 4.54 -12.02 -16.56 -4.140 0.28274E+05 -14.860 4 H2,gas 8.00 0.19 -7.81 -4.466 0.13343E+05 -6.116 5 H2S,gas -6.23 -19.58 -13.35 -6.675 0.22794E+05 -11.651 6 S2,gas -7.34 -39.53 -32.19 -4.953 0.54972E+05 -30.496 7 CO,gas 3.21 -12.57 -15.79 -4.857 0.26953E+05 -14.087 8 SO3,gas 17.12 -20.32 -37.44 -9.360 0.63930E+05 -35.743 9 SO2,gas 0.83 -20.14 -20.97 -5.591 0.35801E+05 -19.268 10 HCl,gas 5.19 -11.72 -16.91 -8.453 0.28865E+05 -15.206 11 acmite 7.71 3.23 -4.48 -0.465 0.76487E+04 15 albite-high 0.69 -3.77 -4.46 -0.343 0.76184E+04 16 albite -0.38 -3.77 -3.38 -0.260 0.57796E+04 19 spessartine 24.46 20.30 -4.15 -0.208 0.70921E+04 20 analcite 3.32 -0.18 -3.50 -0.389 0.59780E+04 21 andalusite 5.00 2.16 -2.84 -0.284 0.48555E+04 22 andradite 39.01 34.94 -4.07 -0.211 0.69459E+04 23 grossular 32.73 28.12 -4.61 -0.230 0.78705E+04 24 anhydrite -5.32 -9.27 -3.96 -1.978 0.67542E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.71 -2.67 -0.891 0.45666E+04 36 brucite 12.57 8.60 -3.97 -0.793 0.67707E+04 37 calcite 0.81 -1.71 -2.52 -0.840 0.43023E+04 40 carpholite-Mg 8.58 7.17 -1.41 -0.094 0.24084E+04 41 carpholite-Fe 6.71 4.94 -1.77 -0.118 0.30200E+04 50 chloritoid-Mg 13.20 10.76 -2.44 -0.162 0.41604E+04 51 chloritoid-Fe 9.17 8.53 -0.64 -0.043 0.10930E+04 52 chloritoid-Mn 11.40 10.60 -0.80 -0.053 0.13686E+04 54 coesite -2.38 -3.59 -1.21 -0.404 0.20720E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.59 -1.03 -0.343 0.17573E+04 67 diopside 16.18 12.47 -3.71 -0.371 0.63337E+04 68 hedenbergite 14.21 10.24 -3.96 -0.396 0.67684E+04 75 epidote 24.67 23.36 -1.31 -0.064 0.22411E+04 76 clinozoisite 22.81 19.95 -2.86 -0.130 0.48801E+04 77 epidote-Fe 29.84 26.77 -3.07 -0.160 0.52488E+04 78 fayalite 14.05 9.16 -4.88 -0.698 0.83394E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.95 -4.19 -0.349 0.71573E+04 91 heulandite -5.83 -8.33 -2.50 -0.114 0.42760E+04 95 jadeite 4.22 -0.18 -4.39 -0.439 0.75035E+04 98 kaolinite -1.33 -1.43 -0.10 -0.009 0.16884E+03 99 kyanite 4.88 2.16 -2.72 -0.272 0.46414E+04 101 laumontite 2.88 2.44 -0.45 -0.030 0.76220E+03 105 lizardite 23.24 18.63 -4.61 -0.384 0.78768E+04 106 magnesite 0.69 -4.15 -4.84 -1.614 0.82693E+04 107 magnetite 20.09 18.94 -1.15 -0.094 0.19561E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.22 -2.73 -0.210 0.46627E+04 120 muscovite 2.58 0.53 -2.05 -0.121 0.35043E+04 121 paragonite 4.24 1.98 -2.26 -0.133 0.38603E+04 122 nepheline 8.34 3.41 -4.93 -0.704 0.84164E+04 136 prehnite 19.37 17.07 -2.30 -0.135 0.39231E+04 137 prehnite-Fe 22.50 20.48 -2.01 -0.121 0.34392E+04 138 pumpellyite-Fe 46.27 43.40 -2.87 -0.064 0.49031E+04 139 pumpellyite-Mg 48.99 45.63 -3.37 -0.075 0.57531E+04 145 pyroxmangite 7.40 4.85 -2.55 -0.509 0.43482E+04 146 pyrophyllite -6.18 -8.61 -2.43 -0.152 0.41575E+04 147 quartz -2.99 -3.59 -0.60 -0.200 0.10246E+04 151 rhodochrosite -0.98 -4.31 -3.34 -1.113 0.56990E+04 152 rhodonite 7.45 4.85 -2.59 -0.519 0.44284E+04 153 sanidine -1.28 -5.22 -3.94 -0.303 0.67305E+04 155 siderite -2.61 -6.38 -3.77 -1.257 0.64404E+04 156 sillimanite 5.26 2.16 -3.10 -0.310 0.52994E+04 163 stilbite -7.52 -8.33 -0.81 -0.039 0.13822E+04 164 stilpnomelane-Fe 13.02 10.25 -2.77 -0.083 0.47279E+04 167 sudoite-Fe 18.30 13.48 -4.82 -0.155 0.82279E+04 168 sudoite 21.08 17.93 -3.14 -0.101 0.53694E+04 174 tephroite 18.09 13.29 -4.79 -0.685 0.81822E+04 177 topaz-H 4.62 2.16 -2.46 -0.224 0.42014E+04 178 tridymite -2.63 -3.59 -0.96 -0.321 0.16446E+04 187 wairakite 3.95 2.44 -1.51 -0.089 0.25842E+04 188 walstromite 11.51 7.46 -4.05 -0.810 0.69170E+04 189 wollastonite 10.46 7.46 -3.00 -0.601 0.51274E+04 190 pseudo-wollastonite 11.00 7.46 -3.54 -0.708 0.60473E+04 191 zoisite 22.85 19.95 -2.90 -0.132 0.49541E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.65 -3.01 -0.186 0.51384E+04 194 beidellite-H -2.33 -6.48 -4.15 -0.265 0.70888E+04 195 beidellite-K -1.52 -5.59 -4.07 -0.249 0.69562E+04 196 beidellite-Mg -1.79 -5.06 -3.27 -0.202 0.55809E+04 197 beidellite-Na -1.34 -5.12 -3.77 -0.231 0.64440E+04 199 chalcedony -2.80 -3.59 -0.79 -0.262 0.13439E+04 201 montmorillonite-Ca -2.29 -4.90 -2.61 -0.161 0.44503E+04 202 montmorillonite-K -2.24 -5.84 -3.60 -0.220 0.61463E+04 203 montmorillonite-Mg -2.48 -5.30 -2.82 -0.174 0.48160E+04 204 montmorillonite-Na -2.04 -5.36 -3.32 -0.203 0.56697E+04 205 nontronite-Ca 3.21 2.16 -1.05 -0.068 0.17941E+04 206 nontronite-H 2.53 0.34 -2.19 -0.147 0.37424E+04 207 nontronite-K 3.34 1.22 -2.12 -0.136 0.36133E+04 208 nontronite-Mg 3.07 1.76 -1.31 -0.085 0.22438E+04 209 nontronite-Na 3.52 1.70 -1.82 -0.117 0.31027E+04 214 gypsum -4.96 -9.27 -4.32 -1.079 0.73718E+04 224 tobermorite 9.82 5.61 -4.21 -1.149 0.71882E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.38 -3.44 -0.859 0.58668E+04 240 silica-amorphous -2.09 -3.59 -1.50 -0.499 0.25581E+04 242 an20ab80 2.02 -1.09 -3.11 -0.239 0.53095E+04 243 an25ab75 2.65 -0.42 -3.07 -0.236 0.52390E+04 244 an30ab70 3.28 0.25 -3.03 -0.233 0.51780E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0340000 g New total amount of reactant added: 0.0350000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0350000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2990587E-03 Osmotic coef. = 0.9896 True ionic strength = .3144502E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15263E-07 -7.8164 0.14642E-07 -7.8344 0.95931E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13233E-03 -3.8783 0.95918E+00 -0.0181 4 SO4-- 0.25337E-04 -4.5963 0.22633E-04 -4.6453 0.89330E+00 -0.0490 5 HCO3- 0.12584E-04 -4.9002 0.12070E-04 -4.9183 0.95921E+00 -0.0181 6 HS- 0.17125E-11 -11.7664 0.16426E-11 -11.7845 0.95918E+00 -0.0181 7 Al+++ 0.29594E-20 -20.5288 0.23469E-20 -20.6295 0.79306E+00 -0.1007 8 H4SiO4 0.26289E-03 -3.5802 0.26289E-03 -3.5802 0.10000E+01 0.0000 9 Ca++ 0.25670E-04 -4.5906 0.22927E-04 -4.6397 0.89315E+00 -0.0491 10 Mg++ 0.95060E-07 -7.0220 0.84894E-07 -7.0711 0.89305E+00 -0.0491 11 Fe++ 0.56273E-09 -9.2497 0.50256E-09 -9.2988 0.89308E+00 -0.0491 12 K+ 0.74283E-05 -5.1291 0.71253E-05 -5.1472 0.95921E+00 -0.0181 13 Na+ 0.20394E-03 -3.6905 0.19561E-03 -3.7086 0.95917E+00 -0.0181 14 Mn++ 0.65769E-07 -7.1820 0.58738E-07 -7.2311 0.89309E+00 -0.0491 15 HPO4-- 0.19263E-08 -8.7153 0.17208E-08 -8.7643 0.89330E+00 -0.0490 16 HSiO3- 0.17478E-04 -4.7575 0.16765E-04 -4.7756 0.95918E+00 -0.0181 17 Ca(HSiO3)+ 0.91255E-08 -8.0397 0.87533E-08 -8.0578 0.95922E+00 -0.0181 18 Mg(HSiO3)+ 0.42052E-10 -10.3762 0.40337E-10 -10.3943 0.95922E+00 -0.0181 19 NaHSiO3,aq 0.53039E-07 -7.2754 0.53039E-07 -7.2754 0.10000E+01 0.0000 20 AlO+ 0.15526E-11 -11.8089 0.14893E-11 -11.8270 0.95922E+00 -0.0181 21 AlOH+2 0.12158E-15 -15.9152 0.10858E-15 -15.9642 0.89311E+00 -0.0491 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.31927E-05 -5.4958 0.30623E-05 -5.5140 0.95913E+00 -0.0181 24 CH4,aq 0.85100E-18 -18.0701 0.85092E-18 -18.0701 0.99991E+00 0.0000 29 CO,aq 0.53938E-17 -17.2681 0.53938E-17 -17.2681 0.10000E+01 0.0000 30 CO2,aq 0.37768E-06 -6.4229 0.37764E-06 -6.4229 0.99991E+00 0.0000 31 CO3-2 0.80610E-07 -7.0936 0.72005E-07 -7.1426 0.89325E+00 -0.0490 32 CaCO3,aq 0.20700E-07 -7.6840 0.20700E-07 -7.6840 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.73644E-08 -8.1329 0.70640E-08 -8.1509 0.95922E+00 -0.0181 34 CaCl+ 0.51186E-08 -8.2909 0.49098E-08 -8.3089 0.95922E+00 -0.0181 35 CaCl2,aq 0.15436E-12 -12.8115 0.15436E-12 -12.8115 0.10000E+01 0.0000 36 CaOH+ 0.11634E-06 -6.9343 0.11160E-06 -6.9524 0.95922E+00 -0.0181 37 CaSO4,aq 0.16478E-06 -6.7831 0.16478E-06 -6.7831 0.10000E+01 0.0000 38 HCl,aq 0.35505E-12 -12.4497 0.35505E-12 -12.4497 0.10000E+01 0.0000 43 FeCl+ 0.10974E-12 -12.9596 0.10526E-12 -12.9777 0.95922E+00 -0.0181 46 FeO,aq 0.91107E-10 -10.0404 0.91107E-10 -10.0404 0.10000E+01 0.0000 47 FeOH+ 0.11648E-08 -8.9338 0.11173E-08 -8.9518 0.95922E+00 -0.0181 48 HFeO2- 0.67876E-10 -10.1683 0.65105E-10 -10.1864 0.95918E+00 -0.0181 49 FeO+ 0.11651E-12 -12.9336 0.11176E-12 -12.9517 0.95922E+00 -0.0181 50 FeOH+2 0.34991E-18 -18.4560 0.31251E-18 -18.5051 0.89311E+00 -0.0491 51 FeO2- 0.11121E-09 -9.9539 0.10667E-09 -9.9720 0.95918E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.56861E-09 -9.2452 0.56856E-09 -9.2452 0.99991E+00 0.0000 54 KCl,aq 0.17089E-10 -10.7673 0.17089E-10 -10.7673 0.10000E+01 0.0000 55 KHSO4,aq 0.66763E-17 -17.1755 0.66763E-17 -17.1755 0.10000E+01 0.0000 56 KOH,aq 0.20782E-09 -9.6823 0.20782E-09 -9.6823 0.10000E+01 0.0000 57 KSO4- 0.26090E-08 -8.5835 0.25025E-08 -8.6016 0.95918E+00 -0.0181 58 MgCO3,aq 0.19212E-10 -10.7164 0.19212E-10 -10.7164 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27864E-10 -10.5550 0.26727E-10 -10.5730 0.95922E+00 -0.0181 60 MgCl+ 0.17178E-10 -10.7650 0.16477E-10 -10.7831 0.95922E+00 -0.0181 61 MgOH+ 0.23838E-08 -8.6227 0.22865E-08 -8.6408 0.95922E+00 -0.0181 63 MnO,aq 0.28373E-09 -9.5471 0.28373E-09 -9.5471 0.10000E+01 0.0000 64 MnOH+ 0.12646E-07 -7.8980 0.12131E-07 -7.9161 0.95922E+00 -0.0181 65 MnO2-2 0.49170E-16 -16.3083 0.43922E-16 -16.3573 0.89325E+00 -0.0490 66 HMnO2- 0.14689E-12 -12.8330 0.14089E-12 -12.8511 0.95918E+00 -0.0181 69 MnCl+ 0.49900E-10 -10.3019 0.47865E-10 -10.3200 0.95922E+00 -0.0181 70 MnSO4,aq 0.38380E-09 -9.4159 0.38380E-09 -9.4159 0.10000E+01 0.0000 71 NaCl,aq 0.85785E-08 -8.0666 0.85785E-08 -8.0666 0.10000E+01 0.0000 72 NaOH,aq 0.57400E-08 -8.2411 0.57400E-08 -8.2411 0.10000E+01 0.0000 74 OH- 0.41141E-04 -4.3857 0.39460E-04 -4.4038 0.95913E+00 -0.0181 82 H3PO4,aq 0.25802E-14 -14.5883 0.25802E-14 -14.5883 0.10000E+01 0.0000 83 H2PO4- 0.48457E-09 -9.3146 0.46480E-09 -9.3327 0.95920E+00 -0.0181 84 PO4-3 0.12077E-12 -12.9180 0.95887E-13 -13.0182 0.79397E+00 -0.1002 87 H2P2O7-2 0.18964E-19 -19.7221 0.16939E-19 -19.7711 0.89325E+00 -0.0490 88 HP2O7-3 0.29128E-18 -18.5357 0.23101E-18 -18.6364 0.79306E+00 -0.1007 90 H2S,aq 0.74338E-13 -13.1288 0.74331E-13 -13.1288 0.99991E+00 0.0000 96 SO2,aq 0.12321E-19 -19.9094 0.12321E-19 -19.9094 0.10000E+01 0.0000 97 SO3-2 0.18714E-14 -14.7278 0.16722E-14 -14.7767 0.89356E+00 -0.0489 98 HSO3- 0.15983E-14 -14.7963 0.15331E-14 -14.8144 0.95918E+00 -0.0181 99 HSO4- 0.33294E-09 -9.4776 0.31937E-09 -9.4957 0.95924E+00 -0.0181 101 S2O3-2 0.22124E-19 -19.6551 0.19762E-19 -19.7042 0.89325E+00 -0.0490 Charge balance for all species = 0.2021E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1526310E-07 -.7136099E-04 -.7192476E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999589E+06 0.0000 3 Cl- 0.1379620E-03 0.1379758E-03 0.4891464E+01 3.9561 4 SO4-- 0.2533667E-04 0.2550467E-04 0.2449923E+01 11.0235 5 HCO3- 0.1258376E-04 0.1307016E-04 0.7974728E+00 2.9161 6 HS- 0.1712466E-11 0.1051949E-09 0.3478867E-05 -3.9501 7 Al+++ 0.2959354E-20 0.3212993E-05 0.8668794E-01 2.8737 8 H4SiO4 0.2628862E-03 0.2804265E-03 0.2695225E+02 -3.5802 9 Ca++ 0.2566980E-04 0.2599323E-04 0.1041715E+01 11.0291 10 Mg++ 0.9506015E-07 0.9755021E-07 0.2371547E-02 8.5977 11 Fe++ 0.5627323E-09 0.2196553E-08 0.1226661E-03 6.3700 12 K+ 0.7428252E-05 0.7431086E-05 0.2905589E+00 2.6872 13 Na+ 0.2039396E-03 0.2040070E-03 0.4689894E+01 4.1258 14 Mn++ 0.6576945E-07 0.7913344E-07 0.4347261E-02 8.4377 15 HPO4-- 0.1926328E-08 0.2411021E-08 0.2313982E-03 6.9045 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5665080E-03 -.7136014E-04 -.4951479E-03 0.0000000E+00 2 H2O 0.5550781E+02 0.5550762E+02 0.1910311E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2647444E-04 0.2550436E-04 0.9700745E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9699693E-06 0.1051936E-09 -.9700745E-06 0.0000000E+00 7 Al+++ 0.1141260E-03 0.3212954E-05 0.1109130E-03 0.0000000E+00 8 H4SiO4 0.3644474E-03 0.2804232E-03 0.8402420E-04 0.0000000E+00 9 Ca++ 0.5472605E-04 0.2599292E-04 0.2873314E-04 0.0000000E+00 10 Mg++ 0.2777778E-04 0.9754905E-07 0.2768023E-04 0.0000000E+00 11 Fe++ 0.2495530E-04 0.2196527E-08 0.2495310E-04 0.0000000E+00 12 K+ 0.7430998E-05 0.7430998E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2040045E-03 0.2040045E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6068509E-06 0.7913250E-07 0.5277184E-06 0.0000000E+00 15 HPO4-- 0.2071152E-06 0.2410992E-08 0.2047042E-06 0.0000000E+00 Chg. balance for solid moles: 0.5845E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0350000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6823E-07 -7.166 0.3428E-04 -4.465 0.1977 0.1089E-04 clinochlore 0.5536E-05 -5.257 0.3077E-02 -2.512 17.75 0.1170E-02 daphnite 0.3439E-05 -5.464 0.2453E-02 -2.610 14.15 0.7435E-03 chlorite-Mn 0.1055E-06 -6.977 0.7483E-04 -4.126 0.4316 0.2385E-04 diaspore 0.3597E-04 -4.444 0.2158E-02 -2.666 12.44 0.6424E-03 hematite 0.3880E-05 -5.411 0.6197E-03 -3.208 3.574 0.1175E-03 lawsonite 0.2839E-04 -4.547 0.8922E-02 -2.050 51.46 0.2877E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3787E+00 0.3787E+00 1.0000 -0.422 chlorite-Mn 0.1162E-01 0.1162E-01 1.0000 -1.935 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.017339 g Volume = 0.005586 cm3 Porosity: 99.4492% V(tot) - V(min): 0.10084E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0350000 g log = -1.4559 Original solution: 1000.0103000 g Original solution / Rock added: 28571.72 (Water/Rock Ratio), log = 4.4559 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3932E-04 1.0071 0.4040E-04 0.4012E-04 CH4,gas 0.1212E-14 1.0125 0.1252E-14 0.1237E-14 H2,gas 0.7312E-06 1.0005 0.7465E-06 0.7460E-06 H2S,gas 0.2011E-11 0.9960 0.2043E-11 0.2051E-11 S2,gas 0.2757E-30 1.0000 0.2813E-30 0.2813E-30 CO,gas 0.7878E-14 1.0000 0.8038E-14 0.8038E-14 SO3,gas 0.1798E-35 1.0000 0.1835E-35 0.1835E-35 SO2,gas 0.5222E-19 1.0000 0.5328E-19 0.5328E-19 HCl,gas 0.6140E-15 1.0000 0.6265E-15 0.6265E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.75 -6.09 -2.031 0.10403E+05 -4.394 3 CH4,gas 4.54 -12.06 -16.60 -4.150 0.28346E+05 -14.902 4 H2,gas 8.00 0.17 -7.83 -4.472 0.13363E+05 -6.127 5 H2S,gas -6.23 -19.62 -13.39 -6.694 0.22861E+05 -11.690 6 S2,gas -7.34 -39.59 -32.25 -4.962 0.55066E+05 -30.551 7 CO,gas 3.21 -12.58 -15.79 -4.860 0.26968E+05 -14.095 8 SO3,gas 17.12 -20.31 -37.44 -9.359 0.63920E+05 -35.736 9 SO2,gas 0.83 -20.14 -20.97 -5.593 0.35810E+05 -19.273 10 HCl,gas 5.19 -11.71 -16.90 -8.451 0.28860E+05 -15.203 11 acmite 7.71 3.25 -4.46 -0.464 0.76175E+04 15 albite-high 0.69 -3.74 -4.43 -0.341 0.75714E+04 16 albite -0.38 -3.74 -3.36 -0.258 0.57326E+04 19 spessartine 24.46 20.32 -4.14 -0.207 0.70646E+04 20 analcite 3.32 -0.16 -3.48 -0.387 0.59468E+04 21 andalusite 5.00 2.17 -2.83 -0.283 0.48396E+04 22 andradite 39.01 34.91 -4.10 -0.213 0.69935E+04 23 grossular 32.73 28.09 -4.64 -0.232 0.79181E+04 24 anhydrite -5.32 -9.28 -3.97 -1.984 0.67754E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.72 -2.69 -0.897 0.45932E+04 36 brucite 12.57 8.60 -3.97 -0.794 0.67802E+04 37 calcite 0.81 -1.72 -2.54 -0.845 0.43290E+04 40 carpholite-Mg 8.58 7.18 -1.40 -0.093 0.23862E+04 41 carpholite-Fe 6.71 4.96 -1.76 -0.117 0.29978E+04 50 chloritoid-Mg 13.20 10.76 -2.43 -0.162 0.41541E+04 51 chloritoid-Fe 9.17 8.54 -0.64 -0.042 0.10868E+04 52 chloritoid-Mn 11.40 10.60 -0.80 -0.053 0.13595E+04 54 coesite -2.38 -3.58 -1.20 -0.401 0.20561E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.58 -1.02 -0.340 0.17414E+04 67 diopside 16.18 12.47 -3.72 -0.372 0.63433E+04 68 hedenbergite 14.21 10.24 -3.97 -0.397 0.67780E+04 75 epidote 24.67 23.35 -1.32 -0.064 0.22570E+04 76 clinozoisite 22.81 19.94 -2.87 -0.130 0.48959E+04 77 epidote-Fe 29.84 26.76 -3.08 -0.160 0.52647E+04 78 fayalite 14.05 9.16 -4.89 -0.698 0.83427E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.95 -4.19 -0.349 0.71543E+04 91 heulandite -5.83 -8.29 -2.46 -0.112 0.41967E+04 95 jadeite 4.22 -0.16 -4.38 -0.438 0.74723E+04 98 kaolinite -1.33 -1.41 -0.08 -0.007 0.13711E+03 99 kyanite 4.88 2.17 -2.71 -0.271 0.46255E+04 101 laumontite 2.88 2.46 -0.43 -0.029 0.73046E+03 105 lizardite 23.24 18.63 -4.61 -0.384 0.78737E+04 106 magnesite 0.69 -4.16 -4.85 -1.615 0.82737E+04 107 magnetite 20.09 18.94 -1.15 -0.094 0.19657E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.18 -2.69 -0.207 0.45987E+04 120 muscovite 2.58 0.57 -2.01 -0.119 0.34403E+04 121 paragonite 4.24 2.01 -2.23 -0.131 0.38132E+04 122 nepheline 8.34 3.42 -4.92 -0.703 0.84011E+04 136 prehnite 19.37 17.06 -2.31 -0.136 0.39390E+04 137 prehnite-Fe 22.50 20.47 -2.02 -0.122 0.34550E+04 138 pumpellyite-Fe 46.27 43.37 -2.90 -0.064 0.49445E+04 139 pumpellyite-Mg 48.99 45.60 -3.39 -0.075 0.57944E+04 145 pyroxmangite 7.40 4.86 -2.54 -0.508 0.43390E+04 146 pyrophyllite -6.18 -8.57 -2.40 -0.150 0.40941E+04 147 quartz -2.99 -3.58 -0.59 -0.197 0.10088E+04 151 rhodochrosite -0.98 -4.31 -3.34 -1.113 0.57006E+04 152 rhodonite 7.45 4.86 -2.59 -0.518 0.44193E+04 153 sanidine -1.28 -5.18 -3.90 -0.300 0.66665E+04 155 siderite -2.61 -6.38 -3.77 -1.258 0.64449E+04 156 sillimanite 5.26 2.17 -3.09 -0.309 0.52835E+04 163 stilbite -7.52 -8.29 -0.76 -0.036 0.13029E+04 164 stilpnomelane-Fe 13.02 10.30 -2.72 -0.081 0.46407E+04 167 sudoite-Fe 18.30 13.49 -4.80 -0.155 0.81995E+04 168 sudoite 21.08 17.95 -3.13 -0.101 0.53408E+04 174 tephroite 18.09 13.30 -4.79 -0.684 0.81798E+04 177 topaz-H 4.62 2.17 -2.45 -0.223 0.41856E+04 178 tridymite -2.63 -3.58 -0.95 -0.318 0.16287E+04 187 wairakite 3.95 2.46 -1.49 -0.088 0.25524E+04 188 walstromite 11.51 7.45 -4.06 -0.812 0.69329E+04 189 wollastonite 10.46 7.45 -3.01 -0.602 0.51433E+04 190 pseudo-wollastonite 11.00 7.45 -3.55 -0.710 0.60631E+04 191 zoisite 22.85 19.94 -2.91 -0.132 0.49700E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.62 -2.98 -0.184 0.50854E+04 194 beidellite-H -2.33 -6.44 -4.12 -0.263 0.70305E+04 195 beidellite-K -1.52 -5.56 -4.04 -0.247 0.68926E+04 196 beidellite-Mg -1.79 -5.03 -3.24 -0.200 0.55243E+04 197 beidellite-Na -1.34 -5.08 -3.74 -0.229 0.63859E+04 199 chalcedony -2.80 -3.58 -0.78 -0.259 0.13281E+04 201 montmorillonite-Ca -2.29 -4.86 -2.57 -0.159 0.43952E+04 202 montmorillonite-K -2.24 -5.80 -3.56 -0.218 0.60805E+04 203 montmorillonite-Mg -2.48 -5.27 -2.79 -0.172 0.47572E+04 204 montmorillonite-Na -2.04 -5.32 -3.29 -0.201 0.56096E+04 205 nontronite-Ca 3.21 2.19 -1.02 -0.066 0.17411E+04 206 nontronite-H 2.53 0.38 -2.16 -0.145 0.36841E+04 207 nontronite-K 3.34 1.26 -2.08 -0.133 0.35496E+04 208 nontronite-Mg 3.07 1.79 -1.28 -0.083 0.21872E+04 209 nontronite-Na 3.52 1.74 -1.78 -0.114 0.30447E+04 214 gypsum -4.96 -9.28 -4.33 -1.082 0.73930E+04 224 tobermorite 9.82 5.61 -4.22 -1.150 0.71987E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.37 -3.44 -0.860 0.58764E+04 240 silica-amorphous -2.09 -3.58 -1.49 -0.496 0.25422E+04 242 an20ab80 2.02 -1.07 -3.09 -0.238 0.52719E+04 243 an25ab75 2.65 -0.40 -3.05 -0.234 0.52037E+04 244 an30ab70 3.28 0.27 -3.01 -0.232 0.51451E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0350000 g New total amount of reactant added: 0.0360000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0360000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2981972E-03 Osmotic coef. = 0.9897 True ionic strength = .3136917E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15361E-07 -7.8136 0.14737E-07 -7.8316 0.95934E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13233E-03 -3.8783 0.95920E+00 -0.0181 4 SO4-- 0.25341E-04 -4.5962 0.22640E-04 -4.6451 0.89340E+00 -0.0490 5 HCO3- 0.12583E-04 -4.9002 0.12070E-04 -4.9183 0.95923E+00 -0.0181 6 HS- 0.15571E-11 -11.8077 0.14936E-11 -11.8258 0.95921E+00 -0.0181 7 Al+++ 0.30163E-20 -20.5205 0.23927E-20 -20.6211 0.79326E+00 -0.1006 8 H4SiO4 0.26848E-03 -3.5711 0.26848E-03 -3.5711 0.10000E+01 0.0000 9 Ca++ 0.24928E-04 -4.6033 0.22267E-04 -4.6523 0.89325E+00 -0.0490 10 Mg++ 0.95072E-07 -7.0219 0.84914E-07 -7.0710 0.89315E+00 -0.0491 11 Fe++ 0.56275E-09 -9.2497 0.50264E-09 -9.2987 0.89318E+00 -0.0491 12 K+ 0.76405E-05 -5.1169 0.73291E-05 -5.1350 0.95924E+00 -0.0181 13 Na+ 0.20519E-03 -3.6878 0.19682E-03 -3.7059 0.95920E+00 -0.0181 14 Mn++ 0.66019E-07 -7.1803 0.58968E-07 -7.2294 0.89319E+00 -0.0491 15 HPO4-- 0.20396E-08 -8.6904 0.18222E-08 -8.7394 0.89340E+00 -0.0490 16 HSiO3- 0.17735E-04 -4.7512 0.17011E-04 -4.7693 0.95920E+00 -0.0181 17 Ca(HSiO3)+ 0.89929E-08 -8.0461 0.86264E-08 -8.0642 0.95925E+00 -0.0181 18 Mg(HSiO3)+ 0.42680E-10 -10.3698 0.40940E-10 -10.3879 0.95925E+00 -0.0181 19 NaHSiO3,aq 0.54152E-07 -7.2664 0.54152E-07 -7.2664 0.10000E+01 0.0000 20 AlO+ 0.15626E-11 -11.8062 0.14989E-11 -11.8242 0.95925E+00 -0.0181 21 AlOH+2 0.12314E-15 -15.9096 0.10999E-15 -15.9587 0.89321E+00 -0.0490 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.31722E-05 -5.4986 0.30426E-05 -5.5168 0.95916E+00 -0.0181 24 CH4,aq 0.77357E-18 -18.1115 0.77350E-18 -18.1115 0.99991E+00 0.0000 29 CO,aq 0.52919E-17 -17.2764 0.52919E-17 -17.2764 0.10000E+01 0.0000 30 CO2,aq 0.38010E-06 -6.4201 0.38006E-06 -6.4201 0.99991E+00 0.0000 31 CO3-2 0.80080E-07 -7.0965 0.71540E-07 -7.1455 0.89335E+00 -0.0490 32 CaCO3,aq 0.19974E-07 -7.6995 0.19974E-07 -7.6995 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.71518E-08 -8.1456 0.68603E-08 -8.1637 0.95925E+00 -0.0181 34 CaCl+ 0.49712E-08 -8.3035 0.47686E-08 -8.3216 0.95925E+00 -0.0181 35 CaCl2,aq 0.14992E-12 -12.8241 0.14992E-12 -12.8241 0.10000E+01 0.0000 36 CaOH+ 0.11226E-06 -6.9498 0.10769E-06 -6.9678 0.95925E+00 -0.0181 37 CaSO4,aq 0.16008E-06 -6.7957 0.16008E-06 -6.7957 0.10000E+01 0.0000 38 HCl,aq 0.35736E-12 -12.4469 0.35736E-12 -12.4469 0.10000E+01 0.0000 43 FeCl+ 0.10976E-12 -12.9596 0.10528E-12 -12.9776 0.95925E+00 -0.0181 46 FeO,aq 0.89955E-10 -10.0460 0.89955E-10 -10.0460 0.10000E+01 0.0000 47 FeOH+ 0.11574E-08 -8.9365 0.11103E-08 -8.9546 0.95925E+00 -0.0181 48 HFeO2- 0.66586E-10 -10.1766 0.63869E-10 -10.1947 0.95920E+00 -0.0181 49 FeO+ 0.11726E-12 -12.9308 0.11248E-12 -12.9489 0.95925E+00 -0.0181 50 FeOH+2 0.35440E-18 -18.4505 0.31655E-18 -18.4996 0.89321E+00 -0.0490 51 FeO2- 0.11049E-09 -9.9567 0.10598E-09 -9.9748 0.95920E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.55433E-09 -9.2562 0.55428E-09 -9.2563 0.99991E+00 0.0000 54 KCl,aq 0.17578E-10 -10.7550 0.17578E-10 -10.7550 0.10000E+01 0.0000 55 KHSO4,aq 0.69136E-17 -17.1603 0.69136E-17 -17.1603 0.10000E+01 0.0000 56 KOH,aq 0.21239E-09 -9.6729 0.21239E-09 -9.6729 0.10000E+01 0.0000 57 KSO4- 0.26843E-08 -8.5712 0.25748E-08 -8.5893 0.95920E+00 -0.0181 58 MgCO3,aq 0.19093E-10 -10.7191 0.19093E-10 -10.7191 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27868E-10 -10.5549 0.26732E-10 -10.5730 0.95925E+00 -0.0181 60 MgCl+ 0.17182E-10 -10.7649 0.16482E-10 -10.7830 0.95925E+00 -0.0181 61 MgOH+ 0.23690E-08 -8.6254 0.22724E-08 -8.6435 0.95925E+00 -0.0181 63 MnO,aq 0.28120E-09 -9.5510 0.28120E-09 -9.5510 0.10000E+01 0.0000 64 MnOH+ 0.12614E-07 -7.8991 0.12100E-07 -7.9172 0.95925E+00 -0.0181 65 MnO2-2 0.48103E-16 -16.3178 0.42973E-16 -16.3668 0.89335E+00 -0.0490 66 HMnO2- 0.14464E-12 -12.8397 0.13874E-12 -12.8578 0.95920E+00 -0.0181 69 MnCl+ 0.50094E-10 -10.3002 0.48053E-10 -10.3183 0.95925E+00 -0.0181 70 MnSO4,aq 0.38541E-09 -9.4141 0.38541E-09 -9.4141 0.10000E+01 0.0000 71 NaCl,aq 0.86317E-08 -8.0639 0.86317E-08 -8.0639 0.10000E+01 0.0000 72 NaOH,aq 0.57384E-08 -8.2412 0.57384E-08 -8.2412 0.10000E+01 0.0000 74 OH- 0.40876E-04 -4.3885 0.39207E-04 -4.4066 0.95916E+00 -0.0181 82 H3PO4,aq 0.27677E-14 -14.5579 0.27677E-14 -14.5579 0.10000E+01 0.0000 83 H2PO4- 0.51642E-09 -9.2870 0.49537E-09 -9.3051 0.95922E+00 -0.0181 84 PO4-3 0.12703E-12 -12.8961 0.10089E-12 -12.9962 0.79417E+00 -0.1001 87 H2P2O7-2 0.21538E-19 -19.6668 0.19241E-19 -19.7158 0.89335E+00 -0.0490 88 HP2O7-3 0.32865E-18 -18.4833 0.26071E-18 -18.5838 0.79326E+00 -0.1006 90 H2S,aq 0.68033E-13 -13.1673 0.68027E-13 -13.1673 0.99991E+00 0.0000 96 SO2,aq 0.12170E-19 -19.9147 0.12170E-19 -19.9147 0.10000E+01 0.0000 97 SO3-2 0.18248E-14 -14.7388 0.16307E-14 -14.7876 0.89366E+00 -0.0488 98 HSO3- 0.15686E-14 -14.8045 0.15046E-14 -14.8226 0.95920E+00 -0.0181 99 HSO4- 0.33518E-09 -9.4747 0.32153E-09 -9.4928 0.95927E+00 -0.0181 101 S2O3-2 0.20251E-19 -19.6935 0.18092E-19 -19.7425 0.89335E+00 -0.0490 Charge balance for all species = 0.2021E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1536119E-07 -.7126344E-04 -.7182640E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999583E+06 0.0000 3 Cl- 0.1379622E-03 0.1379759E-03 0.4891462E+01 3.9533 4 SO4-- 0.2534129E-04 0.2550468E-04 0.2449922E+01 11.0181 5 HCO3- 0.1258281E-04 0.1307016E-04 0.7974726E+00 2.9133 6 HS- 0.1557145E-11 0.1015512E-09 0.3358366E-05 -3.9942 7 Al+++ 0.3016267E-20 0.3192429E-05 0.8613308E-01 2.8737 8 H4SiO4 0.2684757E-03 0.2862736E-03 0.2751420E+02 -3.5711 9 Ca++ 0.2492802E-04 0.2524145E-04 0.1011586E+01 11.0109 10 Mg++ 0.9507187E-07 0.9754764E-07 0.2371483E-02 8.5922 11 Fe++ 0.5627506E-09 0.2186080E-08 0.1220811E-03 6.3645 12 K+ 0.7640491E-05 0.7643405E-05 0.2988605E+00 2.6967 13 Na+ 0.2051937E-03 0.2052623E-03 0.4718750E+01 4.1257 14 Mn++ 0.6601887E-07 0.7934975E-07 0.4359142E-02 8.4338 15 HPO4-- 0.2039628E-08 0.2556182E-08 0.2453300E-03 6.9238 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5830666E-03 -.7126258E-04 -.5118040E-03 0.0000000E+00 2 H2O 0.5550780E+02 0.5550760E+02 0.1945536E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2650215E-04 0.2550437E-04 0.9977843E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9976827E-06 0.1015499E-09 -.9977843E-06 0.0000000E+00 7 Al+++ 0.1173867E-03 0.3192390E-05 0.1141943E-03 0.0000000E+00 8 H4SiO4 0.3748602E-03 0.2862701E-03 0.8859005E-04 0.0000000E+00 9 Ca++ 0.5587620E-04 0.2524115E-04 0.3063505E-04 0.0000000E+00 10 Mg++ 0.2857143E-04 0.9754646E-07 0.2847388E-04 0.0000000E+00 11 Fe++ 0.2566831E-04 0.2186054E-08 0.2566612E-04 0.0000000E+00 12 K+ 0.7643312E-05 0.7643312E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2052598E-03 0.2052598E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6241895E-06 0.7934878E-07 0.5448407E-06 0.0000000E+00 15 HPO4-- 0.2130328E-06 0.2556151E-08 0.2104766E-06 0.0000000E+00 Chg. balance for solid moles: 0.1980E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0360000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7016E-07 -7.154 0.3524E-04 -4.453 0.1952 0.1120E-04 clinochlore 0.5695E-05 -5.245 0.3165E-02 -2.500 17.53 0.1204E-02 daphnite 0.3537E-05 -5.451 0.2524E-02 -2.598 13.98 0.7647E-03 chlorite-Mn 0.1090E-06 -6.963 0.7726E-04 -4.112 0.4280 0.2462E-04 diaspore 0.3494E-04 -4.457 0.2096E-02 -2.679 11.61 0.6241E-03 hematite 0.3991E-05 -5.399 0.6374E-03 -3.196 3.531 0.1208E-03 lawsonite 0.3028E-04 -4.519 0.9517E-02 -2.022 52.72 0.3069E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3786E+00 0.3786E+00 1.0000 -0.422 chlorite-Mn 0.1167E-01 0.1167E-01 1.0000 -1.933 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.018052 g Volume = 0.005818 cm3 Porosity: 99.4264% V(tot) - V(min): 0.10086E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0360000 g log = -1.4437 Original solution: 1000.0103000 g Original solution / Rock added: 27778.06 (Water/Rock Ratio), log = 4.4437 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3957E-04 1.0071 0.4066E-04 0.4038E-04 CH4,gas 0.1102E-14 1.0125 0.1139E-14 0.1124E-14 H2,gas 0.7128E-06 1.0005 0.7277E-06 0.7273E-06 H2S,gas 0.1840E-11 0.9960 0.1870E-11 0.1877E-11 S2,gas 0.2429E-30 1.0000 0.2479E-30 0.2479E-30 CO,gas 0.7729E-14 1.0000 0.7886E-14 0.7886E-14 SO3,gas 0.1822E-35 1.0000 0.1859E-35 0.1859E-35 SO2,gas 0.5158E-19 1.0000 0.5263E-19 0.5263E-19 HCl,gas 0.6180E-15 1.0000 0.6306E-15 0.6306E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.75 -6.09 -2.030 0.10398E+05 -4.391 3 CH4,gas 4.54 -12.10 -16.64 -4.161 0.28417E+05 -14.944 4 H2,gas 8.00 0.16 -7.84 -4.478 0.13381E+05 -6.138 5 H2S,gas -6.23 -19.66 -13.43 -6.714 0.22926E+05 -11.728 6 S2,gas -7.34 -39.64 -32.30 -4.970 0.55159E+05 -30.606 7 CO,gas 3.21 -12.59 -15.80 -4.862 0.26982E+05 -14.103 8 SO3,gas 17.12 -20.31 -37.43 -9.357 0.63910E+05 -35.731 9 SO2,gas 0.83 -20.15 -20.98 -5.594 0.35819E+05 -19.279 10 HCl,gas 5.19 -11.71 -16.90 -8.450 0.28855E+05 -15.200 11 acmite 7.71 3.27 -4.44 -0.462 0.75865E+04 15 albite-high 0.69 -3.71 -4.41 -0.339 0.75248E+04 16 albite -0.38 -3.71 -3.33 -0.256 0.56860E+04 19 spessartine 24.46 20.34 -4.12 -0.206 0.70378E+04 20 analcite 3.32 -0.14 -3.46 -0.385 0.59158E+04 21 andalusite 5.00 2.18 -2.83 -0.283 0.48240E+04 22 andradite 39.01 34.89 -4.12 -0.214 0.70403E+04 23 grossular 32.73 28.07 -4.66 -0.233 0.79649E+04 24 anhydrite -5.32 -9.30 -3.98 -1.990 0.67969E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.74 -2.71 -0.902 0.46197E+04 36 brucite 12.57 8.59 -3.98 -0.795 0.67896E+04 37 calcite 0.81 -1.74 -2.55 -0.850 0.43554E+04 40 carpholite-Mg 8.58 7.20 -1.38 -0.092 0.23643E+04 41 carpholite-Fe 6.71 4.97 -1.74 -0.116 0.29761E+04 50 chloritoid-Mg 13.20 10.77 -2.43 -0.162 0.41478E+04 51 chloritoid-Fe 9.17 8.54 -0.63 -0.042 0.10806E+04 52 chloritoid-Mn 11.40 10.61 -0.79 -0.053 0.13505E+04 54 coesite -2.38 -3.57 -1.20 -0.398 0.20405E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.57 -1.01 -0.337 0.17258E+04 67 diopside 16.18 12.46 -3.72 -0.372 0.63526E+04 68 hedenbergite 14.21 10.23 -3.98 -0.398 0.67874E+04 75 epidote 24.67 23.34 -1.33 -0.065 0.22726E+04 76 clinozoisite 22.81 19.93 -2.88 -0.131 0.49115E+04 77 epidote-Fe 29.84 26.75 -3.09 -0.161 0.52803E+04 78 fayalite 14.05 9.16 -4.89 -0.698 0.83460E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.95 -4.19 -0.349 0.71514E+04 91 heulandite -5.83 -8.24 -2.41 -0.110 0.41187E+04 95 jadeite 4.22 -0.14 -4.36 -0.436 0.74413E+04 98 kaolinite -1.33 -1.39 -0.06 -0.006 0.10591E+03 99 kyanite 4.88 2.18 -2.70 -0.270 0.46099E+04 101 laumontite 2.88 2.47 -0.41 -0.027 0.69926E+03 105 lizardite 23.24 18.63 -4.61 -0.384 0.78705E+04 106 magnesite 0.69 -4.16 -4.85 -1.616 0.82784E+04 107 magnetite 20.09 18.93 -1.16 -0.094 0.19751E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.14 -2.66 -0.204 0.45358E+04 120 muscovite 2.58 0.60 -1.98 -0.116 0.33773E+04 121 paragonite 4.24 2.03 -2.21 -0.130 0.37666E+04 122 nepheline 8.34 3.43 -4.91 -0.702 0.83857E+04 136 prehnite 19.37 17.06 -2.32 -0.136 0.39546E+04 137 prehnite-Fe 22.50 20.47 -2.03 -0.122 0.34706E+04 138 pumpellyite-Fe 46.27 43.35 -2.92 -0.065 0.49851E+04 139 pumpellyite-Mg 48.99 45.58 -3.42 -0.076 0.58349E+04 145 pyroxmangite 7.40 4.86 -2.54 -0.507 0.43301E+04 146 pyrophyllite -6.18 -8.54 -2.36 -0.148 0.40317E+04 147 quartz -2.99 -3.57 -0.58 -0.194 0.99317E+03 151 rhodochrosite -0.98 -4.32 -3.34 -1.113 0.57025E+04 152 rhodonite 7.45 4.86 -2.58 -0.517 0.44103E+04 153 sanidine -1.28 -5.14 -3.87 -0.297 0.66036E+04 155 siderite -2.61 -6.39 -3.78 -1.259 0.64496E+04 156 sillimanite 5.26 2.18 -3.09 -0.309 0.52679E+04 163 stilbite -7.52 -8.24 -0.72 -0.034 0.12249E+04 164 stilpnomelane-Fe 13.02 10.35 -2.67 -0.080 0.45550E+04 167 sudoite-Fe 18.30 13.51 -4.79 -0.154 0.81716E+04 168 sudoite 21.08 17.97 -3.11 -0.100 0.53128E+04 171 talc 16.49 11.49 -5.00 -0.294 0.85355E+04 174 tephroite 18.09 13.30 -4.79 -0.684 0.81775E+04 177 topaz-H 4.62 2.18 -2.44 -0.222 0.41700E+04 178 tridymite -2.63 -3.57 -0.94 -0.315 0.16131E+04 187 wairakite 3.95 2.47 -1.48 -0.087 0.25212E+04 188 walstromite 11.51 7.44 -4.07 -0.814 0.69485E+04 189 wollastonite 10.46 7.44 -3.02 -0.604 0.51589E+04 190 pseudo-wollastonite 11.00 7.44 -3.56 -0.712 0.60787E+04 191 zoisite 22.85 19.93 -2.92 -0.133 0.49856E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.59 -2.95 -0.182 0.50333E+04 194 beidellite-H -2.33 -6.41 -4.08 -0.261 0.69733E+04 195 beidellite-K -1.52 -5.52 -4.00 -0.245 0.68300E+04 196 beidellite-Mg -1.79 -4.99 -3.20 -0.198 0.54685E+04 197 beidellite-Na -1.34 -5.05 -3.71 -0.227 0.63287E+04 199 chalcedony -2.80 -3.57 -0.77 -0.256 0.13125E+04 201 montmorillonite-Ca -2.29 -4.83 -2.54 -0.157 0.43410E+04 202 montmorillonite-K -2.24 -5.76 -3.52 -0.216 0.60159E+04 203 montmorillonite-Mg -2.48 -5.23 -2.75 -0.170 0.46995E+04 204 montmorillonite-Na -2.04 -5.29 -3.25 -0.199 0.55503E+04 205 nontronite-Ca 3.21 2.23 -0.99 -0.064 0.16890E+04 206 nontronite-H 2.53 0.41 -2.12 -0.142 0.36269E+04 207 nontronite-K 3.34 1.30 -2.04 -0.131 0.34870E+04 208 nontronite-Mg 3.07 1.83 -1.25 -0.081 0.21315E+04 209 nontronite-Na 3.52 1.77 -1.75 -0.112 0.29875E+04 214 gypsum -4.96 -9.30 -4.34 -1.086 0.74145E+04 224 tobermorite 9.82 5.60 -4.22 -1.152 0.72091E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.36 -3.45 -0.862 0.58859E+04 240 silica-amorphous -2.09 -3.57 -1.48 -0.493 0.25266E+04 242 an20ab80 2.02 -1.05 -3.07 -0.236 0.52346E+04 243 an25ab75 2.65 -0.38 -3.03 -0.233 0.51687E+04 244 an30ab70 3.28 0.29 -2.99 -0.230 0.51125E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0360000 g New total amount of reactant added: 0.0370000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0370000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2973732E-03 Osmotic coef. = 0.9897 True ionic strength = .3129774E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15452E-07 -7.8110 0.14824E-07 -7.8290 0.95936E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13234E-03 -3.8783 0.95923E+00 -0.0181 4 SO4-- 0.25346E-04 -4.5961 0.22646E-04 -4.6450 0.89349E+00 -0.0489 5 HCO3- 0.12582E-04 -4.9003 0.12069E-04 -4.9183 0.95926E+00 -0.0181 6 HS- 0.14176E-11 -11.8484 0.13598E-11 -11.8665 0.95923E+00 -0.0181 7 Al+++ 0.30698E-20 -20.5129 0.24357E-20 -20.6134 0.79344E+00 -0.1005 8 H4SiO4 0.27409E-03 -3.5621 0.27409E-03 -3.5621 0.10000E+01 0.0000 9 Ca++ 0.24201E-04 -4.6162 0.21620E-04 -4.6651 0.89334E+00 -0.0490 10 Mg++ 0.95012E-07 -7.0222 0.84869E-07 -7.0713 0.89325E+00 -0.0490 11 Fe++ 0.56234E-09 -9.2500 0.50233E-09 -9.2990 0.89327E+00 -0.0490 12 K+ 0.78527E-05 -5.1050 0.75329E-05 -5.1230 0.95927E+00 -0.0181 13 Na+ 0.20645E-03 -3.6852 0.19803E-03 -3.7033 0.95922E+00 -0.0181 14 Mn++ 0.66212E-07 -7.1791 0.59147E-07 -7.2281 0.89329E+00 -0.0490 15 HPO4-- 0.21592E-08 -8.6657 0.19292E-08 -8.7146 0.89350E+00 -0.0489 16 HSiO3- 0.17998E-04 -4.7448 0.17264E-04 -4.7629 0.95923E+00 -0.0181 17 Ca(HSiO3)+ 0.88611E-08 -8.0525 0.85002E-08 -8.0706 0.95927E+00 -0.0181 18 Mg(HSiO3)+ 0.43289E-10 -10.3636 0.41526E-10 -10.3817 0.95927E+00 -0.0181 19 NaHSiO3,aq 0.55294E-07 -7.2573 0.55294E-07 -7.2573 0.10000E+01 0.0000 20 AlO+ 0.15718E-11 -11.8036 0.15078E-11 -11.8216 0.95927E+00 -0.0181 21 AlOH+2 0.12460E-15 -15.9045 0.11130E-15 -15.9535 0.89331E+00 -0.0490 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.31533E-05 -5.5012 0.30246E-05 -5.5193 0.95919E+00 -0.0181 24 CH4,aq 0.70403E-18 -18.1524 0.70397E-18 -18.1524 0.99991E+00 0.0000 29 CO,aq 0.51917E-17 -17.2847 0.51917E-17 -17.2847 0.10000E+01 0.0000 30 CO2,aq 0.38235E-06 -6.4175 0.38231E-06 -6.4176 0.99991E+00 0.0000 31 CO3-2 0.79594E-07 -7.0991 0.71113E-07 -7.1481 0.89345E+00 -0.0489 32 CaCO3,aq 0.19278E-07 -7.7149 0.19278E-07 -7.7149 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69435E-08 -8.1584 0.66607E-08 -8.1765 0.95927E+00 -0.0181 34 CaCl+ 0.48268E-08 -8.3163 0.46302E-08 -8.3344 0.95927E+00 -0.0181 35 CaCl2,aq 0.14558E-12 -12.8369 0.14558E-12 -12.8369 0.10000E+01 0.0000 36 CaOH+ 0.10835E-06 -6.9652 0.10394E-06 -6.9832 0.95927E+00 -0.0181 37 CaSO4,aq 0.15547E-06 -6.8083 0.15547E-06 -6.8083 0.10000E+01 0.0000 38 HCl,aq 0.35950E-12 -12.4443 0.35950E-12 -12.4443 0.10000E+01 0.0000 43 FeCl+ 0.10969E-12 -12.9598 0.10522E-12 -12.9779 0.95927E+00 -0.0181 46 FeO,aq 0.88837E-10 -10.0514 0.88837E-10 -10.0514 0.10000E+01 0.0000 47 FeOH+ 0.11498E-08 -8.9394 0.11030E-08 -8.9574 0.95927E+00 -0.0181 48 HFeO2- 0.65366E-10 -10.1846 0.62701E-10 -10.2027 0.95923E+00 -0.0181 49 FeO+ 0.11796E-12 -12.9283 0.11315E-12 -12.9463 0.95927E+00 -0.0181 50 FeOH+2 0.35860E-18 -18.4454 0.32034E-18 -18.4944 0.89331E+00 -0.0490 51 FeO2- 0.10983E-09 -9.9593 0.10536E-09 -9.9773 0.95923E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.54063E-09 -9.2671 0.54058E-09 -9.2671 0.99991E+00 0.0000 54 KCl,aq 0.18068E-10 -10.7431 0.18068E-10 -10.7431 0.10000E+01 0.0000 55 KHSO4,aq 0.71502E-17 -17.1457 0.71502E-17 -17.1457 0.10000E+01 0.0000 56 KOH,aq 0.21700E-09 -9.6635 0.21700E-09 -9.6635 0.10000E+01 0.0000 57 KSO4- 0.27597E-08 -8.5591 0.26472E-08 -8.5772 0.95923E+00 -0.0181 58 MgCO3,aq 0.18969E-10 -10.7220 0.18969E-10 -10.7220 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27851E-10 -10.5552 0.26717E-10 -10.5732 0.95927E+00 -0.0181 60 MgCl+ 0.17173E-10 -10.7652 0.16474E-10 -10.7832 0.95927E+00 -0.0181 61 MgOH+ 0.23536E-08 -8.6283 0.22577E-08 -8.6463 0.95927E+00 -0.0181 63 MnO,aq 0.27872E-09 -9.5548 0.27872E-09 -9.5548 0.10000E+01 0.0000 64 MnOH+ 0.12577E-07 -7.9004 0.12065E-07 -7.9185 0.95927E+00 -0.0181 65 MnO2-2 0.47110E-16 -16.3269 0.42090E-16 -16.3758 0.89345E+00 -0.0489 66 HMnO2- 0.14251E-12 -12.8462 0.13670E-12 -12.8642 0.95923E+00 -0.0181 69 MnCl+ 0.50246E-10 -10.2989 0.48200E-10 -10.3170 0.95927E+00 -0.0181 70 MnSO4,aq 0.38669E-09 -9.4126 0.38669E-09 -9.4126 0.10000E+01 0.0000 71 NaCl,aq 0.86850E-08 -8.0612 0.86850E-08 -8.0612 0.10000E+01 0.0000 72 NaOH,aq 0.57394E-08 -8.2411 0.57394E-08 -8.2411 0.10000E+01 0.0000 74 OH- 0.40633E-04 -4.3911 0.38974E-04 -4.4092 0.95919E+00 -0.0181 82 H3PO4,aq 0.29653E-14 -14.5279 0.29653E-14 -14.5279 0.10000E+01 0.0000 83 H2PO4- 0.55001E-09 -9.2596 0.52759E-09 -9.2777 0.95925E+00 -0.0181 84 PO4-3 0.13367E-12 -12.8740 0.10618E-12 -12.9740 0.79435E+00 -0.1000 87 H2P2O7-2 0.24429E-19 -19.6121 0.21826E-19 -19.6610 0.89345E+00 -0.0489 88 HP2O7-3 0.37051E-18 -18.4312 0.29398E-18 -18.5317 0.79345E+00 -0.1005 90 H2S,aq 0.62308E-13 -13.2055 0.62302E-13 -13.2055 0.99991E+00 0.0000 96 SO2,aq 0.12015E-19 -19.9203 0.12015E-19 -19.9203 0.10000E+01 0.0000 97 SO3-2 0.17800E-14 -14.7496 0.15909E-14 -14.7984 0.89375E+00 -0.0488 98 HSO3- 0.15394E-14 -14.8127 0.14766E-14 -14.8307 0.95923E+00 -0.0181 99 HSO4- 0.33727E-09 -9.4720 0.32354E-09 -9.4901 0.95929E+00 -0.0180 101 S2O3-2 0.18550E-19 -19.7317 0.16574E-19 -19.7806 0.89345E+00 -0.0489 Charge balance for all species = 0.2022E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1545242E-07 -.7120087E-04 -.7176329E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999577E+06 0.0000 3 Cl- 0.1379623E-03 0.1379759E-03 0.4891461E+01 3.9507 4 SO4-- 0.2534583E-04 0.2550469E-04 0.2449922E+01 11.0130 5 HCO3- 0.1258195E-04 0.1307016E-04 0.7974724E+00 2.9107 6 HS- 0.1417598E-11 0.9806322E-10 0.3243015E-05 -4.0375 7 Al+++ 0.3069835E-20 0.3173537E-05 0.8562332E-01 2.8737 8 H4SiO4 0.2740889E-03 0.2921508E-03 0.2807905E+02 -3.5621 9 Ca++ 0.2420106E-04 0.2450480E-04 0.9820635E+00 10.9929 10 Mg++ 0.9501151E-07 0.9747240E-07 0.2369653E-02 8.5868 11 Fe++ 0.5623437E-09 0.2175074E-08 0.1214665E-03 6.3590 12 K+ 0.7852729E-05 0.7855724E-05 0.3071621E+00 2.7060 13 Na+ 0.2064479E-03 0.2065176E-03 0.4747605E+01 4.1258 14 Mn++ 0.6621210E-07 0.7950482E-07 0.4367659E-02 8.4300 15 HPO4-- 0.2159210E-08 0.2709353E-08 0.2600304E-03 6.9434 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5996251E-03 -.7119998E-04 -.5284251E-03 0.0000000E+00 2 H2O 0.5550779E+02 0.5550759E+02 0.1981030E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2652987E-04 0.2550437E-04 0.1025494E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1025396E-05 0.9806200E-10 -.1025494E-05 0.0000000E+00 7 Al+++ 0.1206474E-03 0.3173498E-05 0.1174739E-03 0.0000000E+00 8 H4SiO4 0.3852730E-03 0.2921472E-03 0.9312578E-04 0.0000000E+00 9 Ca++ 0.5702634E-04 0.2450449E-04 0.3252184E-04 0.0000000E+00 10 Mg++ 0.2936508E-04 0.9747119E-07 0.2926761E-04 0.0000000E+00 11 Fe++ 0.2638132E-04 0.2175047E-08 0.2637914E-04 0.0000000E+00 12 K+ 0.7855626E-05 0.7855626E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2065150E-03 0.2065150E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6415281E-06 0.7950383E-07 0.5620242E-06 0.0000000E+00 15 HPO4-- 0.2189503E-06 0.2709319E-08 0.2162410E-06 0.0000000E+00 Chg. balance for solid moles: -.4733E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0370000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7208E-07 -7.142 0.3621E-04 -4.441 0.1930 0.1151E-04 clinochlore 0.5854E-05 -5.233 0.3254E-02 -2.488 17.34 0.1238E-02 daphnite 0.3635E-05 -5.439 0.2594E-02 -2.586 13.82 0.7860E-03 chlorite-Mn 0.1124E-06 -6.949 0.7969E-04 -4.099 0.4248 0.2540E-04 diaspore 0.3395E-04 -4.469 0.2037E-02 -2.691 10.86 0.6063E-03 hematite 0.4102E-05 -5.387 0.6551E-03 -3.184 3.492 0.1242E-03 lawsonite 0.3216E-04 -4.493 0.1011E-01 -1.995 53.87 0.3259E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3786E+00 0.3786E+00 1.0000 -0.422 chlorite-Mn 0.1171E-01 0.1171E-01 1.0000 -1.932 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.018761 g Volume = 0.006050 cm3 Porosity: 99.4038% V(tot) - V(min): 0.10088E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0370000 g log = -1.4318 Original solution: 1000.0103000 g Original solution / Rock added: 27027.31 (Water/Rock Ratio), log = 4.4318 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3981E-04 1.0071 0.4090E-04 0.4062E-04 CH4,gas 0.1003E-14 1.0125 0.1036E-14 0.1023E-14 H2,gas 0.6952E-06 1.0005 0.7097E-06 0.7093E-06 H2S,gas 0.1685E-11 0.9960 0.1713E-11 0.1719E-11 S2,gas 0.2142E-30 1.0000 0.2186E-30 0.2186E-30 CO,gas 0.7582E-14 1.0000 0.7737E-14 0.7737E-14 SO3,gas 0.1844E-35 1.0000 0.1882E-35 0.1882E-35 SO2,gas 0.5092E-19 1.0000 0.5196E-19 0.5196E-19 HCl,gas 0.6217E-15 1.0000 0.6343E-15 0.6343E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.75 -6.09 -2.029 0.10394E+05 -4.388 3 CH4,gas 4.54 -12.14 -16.68 -4.171 0.28487E+05 -14.985 4 H2,gas 8.00 0.15 -7.85 -4.485 0.13400E+05 -6.149 5 H2S,gas -6.23 -19.70 -13.47 -6.733 0.22992E+05 -11.766 6 S2,gas -7.34 -39.69 -32.36 -4.978 0.55253E+05 -30.660 7 CO,gas 3.21 -12.60 -15.81 -4.865 0.26996E+05 -14.111 8 SO3,gas 17.12 -20.30 -37.42 -9.356 0.63901E+05 -35.725 9 SO2,gas 0.83 -20.15 -20.98 -5.596 0.35828E+05 -19.284 10 HCl,gas 5.19 -11.71 -16.90 -8.448 0.28851E+05 -15.198 11 acmite 7.71 3.28 -4.43 -0.460 0.75557E+04 15 albite-high 0.69 -3.69 -4.38 -0.337 0.74786E+04 16 albite -0.38 -3.69 -3.30 -0.254 0.56398E+04 19 spessartine 24.46 20.35 -4.11 -0.205 0.70115E+04 20 analcite 3.32 -0.12 -3.45 -0.383 0.58850E+04 21 andalusite 5.00 2.19 -2.82 -0.282 0.48087E+04 22 andradite 39.01 34.86 -4.15 -0.216 0.70864E+04 23 grossular 32.73 28.04 -4.69 -0.235 0.80109E+04 24 anhydrite -5.32 -9.31 -3.99 -1.997 0.68185E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.75 -2.72 -0.907 0.46460E+04 36 brucite 12.57 8.59 -3.98 -0.796 0.67988E+04 37 calcite 0.81 -1.75 -2.57 -0.855 0.43817E+04 40 carpholite-Mg 8.58 7.21 -1.37 -0.091 0.23429E+04 41 carpholite-Fe 6.71 4.98 -1.73 -0.115 0.29547E+04 50 chloritoid-Mg 13.20 10.77 -2.43 -0.162 0.41417E+04 51 chloritoid-Fe 9.17 8.54 -0.63 -0.042 0.10745E+04 52 chloritoid-Mn 11.40 10.62 -0.79 -0.052 0.13418E+04 54 coesite -2.38 -3.56 -1.19 -0.395 0.20251E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.56 -1.00 -0.334 0.17105E+04 67 diopside 16.18 12.46 -3.73 -0.373 0.63619E+04 68 hedenbergite 14.21 10.23 -3.98 -0.398 0.67967E+04 75 epidote 24.67 23.33 -1.34 -0.065 0.22880E+04 76 clinozoisite 22.81 19.92 -2.89 -0.131 0.49269E+04 77 epidote-Fe 29.84 26.74 -3.10 -0.161 0.52957E+04 78 fayalite 14.05 9.16 -4.89 -0.699 0.83492E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.95 -4.19 -0.349 0.71486E+04 91 heulandite -5.83 -8.19 -2.37 -0.108 0.40420E+04 95 jadeite 4.22 -0.12 -4.34 -0.434 0.74105E+04 98 kaolinite -1.33 -1.38 -0.04 -0.004 0.75222E+02 99 kyanite 4.88 2.19 -2.69 -0.269 0.45946E+04 101 laumontite 2.88 2.49 -0.39 -0.026 0.66857E+03 105 lizardite 23.24 18.64 -4.61 -0.384 0.78675E+04 106 magnesite 0.69 -4.16 -4.85 -1.617 0.82832E+04 107 magnetite 20.09 18.93 -1.16 -0.095 0.19844E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.11 -2.62 -0.202 0.44738E+04 120 muscovite 2.58 0.64 -1.94 -0.114 0.33154E+04 121 paragonite 4.24 2.06 -2.18 -0.128 0.37204E+04 122 nepheline 8.34 3.44 -4.90 -0.700 0.83702E+04 136 prehnite 19.37 17.05 -2.33 -0.137 0.39699E+04 137 prehnite-Fe 22.50 20.46 -2.04 -0.123 0.34860E+04 138 pumpellyite-Fe 46.27 43.33 -2.94 -0.065 0.50251E+04 139 pumpellyite-Mg 48.99 45.55 -3.44 -0.076 0.58749E+04 145 pyroxmangite 7.40 4.87 -2.53 -0.506 0.43213E+04 146 pyrophyllite -6.18 -8.50 -2.33 -0.145 0.39703E+04 147 quartz -2.99 -3.56 -0.57 -0.191 0.97782E+03 151 rhodochrosite -0.98 -4.32 -3.34 -1.114 0.57047E+04 152 rhodonite 7.45 4.87 -2.58 -0.516 0.44015E+04 153 sanidine -1.28 -5.11 -3.83 -0.295 0.65416E+04 155 siderite -2.61 -6.39 -3.78 -1.260 0.64545E+04 156 sillimanite 5.26 2.19 -3.08 -0.308 0.52526E+04 163 stilbite -7.52 -8.19 -0.67 -0.032 0.11481E+04 164 stilpnomelane-Fe 13.02 10.40 -2.62 -0.078 0.44707E+04 167 sudoite-Fe 18.30 13.53 -4.77 -0.154 0.81441E+04 168 sudoite 21.08 17.98 -3.10 -0.100 0.52852E+04 171 talc 16.49 11.51 -4.98 -0.293 0.85017E+04 174 tephroite 18.09 13.30 -4.79 -0.684 0.81753E+04 177 topaz-H 4.62 2.19 -2.43 -0.221 0.41546E+04 178 tridymite -2.63 -3.56 -0.94 -0.312 0.15978E+04 187 wairakite 3.95 2.49 -1.46 -0.086 0.24905E+04 188 walstromite 11.51 7.43 -4.08 -0.816 0.69638E+04 189 wollastonite 10.46 7.43 -3.03 -0.606 0.51743E+04 190 pseudo-wollastonite 11.00 7.43 -3.57 -0.714 0.60941E+04 191 zoisite 22.85 19.92 -2.93 -0.133 0.50009E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.56 -2.92 -0.181 0.49821E+04 194 beidellite-H -2.33 -6.38 -4.05 -0.259 0.69170E+04 195 beidellite-K -1.52 -5.48 -3.96 -0.243 0.67685E+04 196 beidellite-Mg -1.79 -4.96 -3.17 -0.196 0.54138E+04 197 beidellite-Na -1.34 -5.02 -3.67 -0.225 0.62724E+04 199 chalcedony -2.80 -3.56 -0.76 -0.253 0.12971E+04 201 montmorillonite-Ca -2.29 -4.80 -2.51 -0.155 0.42878E+04 202 montmorillonite-K -2.24 -5.72 -3.49 -0.213 0.59523E+04 203 montmorillonite-Mg -2.48 -5.20 -2.72 -0.168 0.46427E+04 204 montmorillonite-Na -2.04 -5.25 -3.22 -0.197 0.54920E+04 205 nontronite-Ca 3.21 2.26 -0.96 -0.062 0.16377E+04 206 nontronite-H 2.53 0.44 -2.09 -0.140 0.35706E+04 207 nontronite-K 3.34 1.33 -2.01 -0.129 0.34255E+04 208 nontronite-Mg 3.07 1.86 -1.22 -0.079 0.20767E+04 209 nontronite-Na 3.52 1.80 -1.72 -0.110 0.29311E+04 214 gypsum -4.96 -9.31 -4.36 -1.089 0.74361E+04 224 tobermorite 9.82 5.59 -4.23 -1.154 0.72193E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.36 -3.45 -0.863 0.58951E+04 240 silica-amorphous -2.09 -3.56 -1.47 -0.490 0.25113E+04 242 an20ab80 2.02 -1.03 -3.04 -0.234 0.51977E+04 243 an25ab75 2.65 -0.36 -3.01 -0.231 0.51341E+04 244 an30ab70 3.28 0.30 -2.98 -0.229 0.50801E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0370000 g New total amount of reactant added: 0.0380000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0380000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2965860E-03 Osmotic coef. = 0.9897 True ionic strength = .3123066E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15537E-07 -7.8086 0.14906E-07 -7.8266 0.95939E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13234E-03 -3.8783 0.95925E+00 -0.0181 4 SO4-- 0.25350E-04 -4.5960 0.22653E-04 -4.6449 0.89358E+00 -0.0489 5 HCO3- 0.12581E-04 -4.9003 0.12069E-04 -4.9183 0.95928E+00 -0.0181 6 HS- 0.12920E-11 -11.8887 0.12394E-11 -11.9068 0.95925E+00 -0.0181 7 Al+++ 0.31199E-20 -20.5059 0.24760E-20 -20.6062 0.79362E+00 -0.1004 8 H4SiO4 0.27973E-03 -3.5533 0.27973E-03 -3.5533 0.10000E+01 0.0000 9 Ca++ 0.23489E-04 -4.6291 0.20986E-04 -4.6781 0.89343E+00 -0.0489 10 Mg++ 0.94880E-07 -7.0228 0.84760E-07 -7.0718 0.89334E+00 -0.0490 11 Fe++ 0.56152E-09 -9.2506 0.50164E-09 -9.2996 0.89336E+00 -0.0490 12 K+ 0.80650E-05 -5.0934 0.77366E-05 -5.1114 0.95929E+00 -0.0181 13 Na+ 0.20770E-03 -3.6826 0.19924E-03 -3.7006 0.95925E+00 -0.0181 14 Mn++ 0.66350E-07 -7.1782 0.59275E-07 -7.2271 0.89338E+00 -0.0490 15 HPO4-- 0.22854E-08 -8.6410 0.20422E-08 -8.6899 0.89358E+00 -0.0489 16 HSiO3- 0.18267E-04 -4.7383 0.17523E-04 -4.7564 0.95925E+00 -0.0181 17 Ca(HSiO3)+ 0.87299E-08 -8.0590 0.83745E-08 -8.0770 0.95929E+00 -0.0180 18 Mg(HSiO3)+ 0.43881E-10 -10.3577 0.42095E-10 -10.3758 0.95929E+00 -0.0180 19 NaHSiO3,aq 0.56466E-07 -7.2482 0.56466E-07 -7.2482 0.10000E+01 0.0000 20 AlO+ 0.15804E-11 -11.8012 0.15161E-11 -11.8193 0.95929E+00 -0.0180 21 AlOH+2 0.12595E-15 -15.8998 0.11253E-15 -15.9487 0.89340E+00 -0.0490 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.31360E-05 -5.5036 0.30081E-05 -5.5217 0.95921E+00 -0.0181 24 CH4,aq 0.64149E-18 -18.1928 0.64143E-18 -18.1928 0.99991E+00 0.0000 29 CO,aq 0.50931E-17 -17.2930 0.50931E-17 -17.2930 0.10000E+01 0.0000 30 CO2,aq 0.38443E-06 -6.4152 0.38440E-06 -6.4152 0.99991E+00 0.0000 31 CO3-2 0.79149E-07 -7.1016 0.70723E-07 -7.1504 0.89354E+00 -0.0489 32 CaCO3,aq 0.18610E-07 -7.7303 0.18610E-07 -7.7303 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.67394E-08 -8.1714 0.64651E-08 -8.1894 0.95929E+00 -0.0180 34 CaCl+ 0.46852E-08 -8.3293 0.44945E-08 -8.3473 0.95929E+00 -0.0180 35 CaCl2,aq 0.14131E-12 -12.8498 0.14131E-12 -12.8498 0.10000E+01 0.0000 36 CaOH+ 0.10460E-06 -6.9805 0.10034E-06 -6.9985 0.95929E+00 -0.0180 37 CaSO4,aq 0.15095E-06 -6.8212 0.15095E-06 -6.8212 0.10000E+01 0.0000 38 HCl,aq 0.36148E-12 -12.4419 0.36148E-12 -12.4419 0.10000E+01 0.0000 43 FeCl+ 0.10954E-12 -12.9604 0.10508E-12 -12.9785 0.95929E+00 -0.0180 46 FeO,aq 0.87750E-10 -10.0568 0.87750E-10 -10.0568 0.10000E+01 0.0000 47 FeOH+ 0.11420E-08 -8.9424 0.10955E-08 -8.9604 0.95929E+00 -0.0180 48 HFeO2- 0.64213E-10 -10.1924 0.61597E-10 -10.2104 0.95925E+00 -0.0181 49 FeO+ 0.11860E-12 -12.9259 0.11377E-12 -12.9440 0.95929E+00 -0.0180 50 FeOH+2 0.36251E-18 -18.4407 0.32386E-18 -18.4896 0.89340E+00 -0.0490 51 FeO2- 0.10923E-09 -9.9616 0.10478E-09 -9.9797 0.95925E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.52748E-09 -9.2778 0.52743E-09 -9.2778 0.99991E+00 0.0000 54 KCl,aq 0.18557E-10 -10.7315 0.18557E-10 -10.7315 0.10000E+01 0.0000 55 KHSO4,aq 0.73859E-17 -17.1316 0.73859E-17 -17.1316 0.10000E+01 0.0000 56 KOH,aq 0.22166E-09 -9.6543 0.22166E-09 -9.6543 0.10000E+01 0.0000 57 KSO4- 0.28350E-08 -8.5474 0.27195E-08 -8.5655 0.95925E+00 -0.0181 58 MgCO3,aq 0.18840E-10 -10.7249 0.18840E-10 -10.7249 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27814E-10 -10.5557 0.26682E-10 -10.5738 0.95929E+00 -0.0180 60 MgCl+ 0.17151E-10 -10.7657 0.16453E-10 -10.7838 0.95929E+00 -0.0180 61 MgOH+ 0.23377E-08 -8.6312 0.22425E-08 -8.6493 0.95929E+00 -0.0180 63 MnO,aq 0.27629E-09 -9.5586 0.27629E-09 -9.5586 0.10000E+01 0.0000 64 MnOH+ 0.12535E-07 -7.9019 0.12025E-07 -7.9199 0.95929E+00 -0.0180 65 MnO2-2 0.46186E-16 -16.3355 0.41269E-16 -16.3844 0.89354E+00 -0.0489 66 HMnO2- 0.14049E-12 -12.8523 0.13477E-12 -12.8704 0.95925E+00 -0.0181 69 MnCl+ 0.50356E-10 -10.2980 0.48306E-10 -10.3160 0.95929E+00 -0.0180 70 MnSO4,aq 0.38764E-09 -9.4116 0.38764E-09 -9.4116 0.10000E+01 0.0000 71 NaCl,aq 0.87382E-08 -8.0586 0.87382E-08 -8.0586 0.10000E+01 0.0000 72 NaOH,aq 0.57429E-08 -8.2409 0.57429E-08 -8.2409 0.10000E+01 0.0000 74 OH- 0.40410E-04 -4.3935 0.38762E-04 -4.4116 0.95921E+00 -0.0181 82 H3PO4,aq 0.31735E-14 -14.4985 0.31735E-14 -14.4985 0.10000E+01 0.0000 83 H2PO4- 0.58540E-09 -9.2326 0.56155E-09 -9.2506 0.95927E+00 -0.0181 84 PO4-3 0.14069E-12 -12.8517 0.11179E-12 -12.9516 0.79453E+00 -0.0999 87 H2P2O7-2 0.27672E-19 -19.5580 0.24726E-19 -19.6068 0.89354E+00 -0.0489 88 HP2O7-3 0.41736E-18 -18.3795 0.33123E-18 -18.4799 0.79363E+00 -0.1004 90 H2S,aq 0.57102E-13 -13.2434 0.57096E-13 -13.2434 0.99991E+00 0.0000 96 SO2,aq 0.11855E-19 -19.9261 0.11855E-19 -19.9261 0.10000E+01 0.0000 97 SO3-2 0.17370E-14 -14.7602 0.15526E-14 -14.8089 0.89384E+00 -0.0487 98 HSO3- 0.15106E-14 -14.8209 0.14490E-14 -14.8389 0.95925E+00 -0.0181 99 HSO4- 0.33920E-09 -9.4695 0.32540E-09 -9.4876 0.95931E+00 -0.0180 101 S2O3-2 0.17003E-19 -19.7695 0.15193E-19 -19.8184 0.89354E+00 -0.0489 Charge balance for all species = 0.2023E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1553674E-07 -.7117267E-04 -.7173483E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999571E+06 0.0000 3 Cl- 0.1379624E-03 0.1379759E-03 0.4891460E+01 3.9483 4 SO4-- 0.2535028E-04 0.2550470E-04 0.2449921E+01 11.0084 5 HCO3- 0.1258119E-04 0.1307017E-04 0.7974721E+00 2.9083 6 HS- 0.1292039E-11 0.9472127E-10 0.3132493E-05 -4.0801 7 Al+++ 0.3119902E-20 0.3156268E-05 0.8515733E-01 2.8737 8 H4SiO4 0.2797252E-03 0.2980577E-03 0.2864676E+02 -3.5533 9 Ca++ 0.2348873E-04 0.2378304E-04 0.9531375E+00 10.9752 10 Mg++ 0.9487985E-07 0.9732524E-07 0.2366074E-02 8.5815 11 Fe++ 0.5615161E-09 0.2163539E-08 0.1208222E-03 6.3537 12 K+ 0.8064968E-05 0.8068043E-05 0.3154636E+00 2.7152 13 Na+ 0.2077020E-03 0.2077729E-03 0.4776461E+01 4.1260 14 Mn++ 0.6634954E-07 0.7959922E-07 0.4372842E-02 8.4262 15 HPO4-- 0.2285446E-08 0.2870986E-08 0.2755430E-03 6.9634 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6161836E-03 -.7117176E-04 -.5450118E-03 0.0000000E+00 2 H2O 0.5550777E+02 0.5550757E+02 0.2016789E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2655758E-04 0.2550438E-04 0.1053204E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1053110E-05 0.9472007E-10 -.1053204E-05 0.0000000E+00 7 Al+++ 0.1239082E-03 0.3156228E-05 0.1207520E-03 0.0000000E+00 8 H4SiO4 0.3956858E-03 0.2980539E-03 0.9763182E-04 0.0000000E+00 9 Ca++ 0.5817648E-04 0.2378274E-04 0.3439374E-04 0.0000000E+00 10 Mg++ 0.3015873E-04 0.9732400E-07 0.3006141E-04 0.0000000E+00 11 Fe++ 0.2709433E-04 0.2163512E-08 0.2709216E-04 0.0000000E+00 12 K+ 0.8067941E-05 0.8067941E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2077703E-03 0.2077703E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6588666E-06 0.7959820E-07 0.5792684E-06 0.0000000E+00 15 HPO4-- 0.2248679E-06 0.2870949E-08 0.2219970E-06 0.0000000E+00 Chg. balance for solid moles: -.5347E-20 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0380000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7400E-07 -7.131 0.3717E-04 -4.430 0.1909 0.1181E-04 clinochlore 0.6012E-05 -5.221 0.3342E-02 -2.476 17.17 0.1271E-02 daphnite 0.3733E-05 -5.428 0.2664E-02 -2.575 13.68 0.8072E-03 chlorite-Mn 0.1159E-06 -6.936 0.8214E-04 -4.085 0.4219 0.2617E-04 diaspore 0.3298E-04 -4.482 0.1979E-02 -2.704 10.16 0.5890E-03 hematite 0.4213E-05 -5.375 0.6728E-03 -3.172 3.456 0.1275E-03 lawsonite 0.3402E-04 -4.468 0.1069E-01 -1.971 54.92 0.3448E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3786E+00 0.3786E+00 1.0000 -0.422 chlorite-Mn 0.1175E-01 0.1175E-01 1.0000 -1.930 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.019468 g Volume = 0.006281 cm3 Porosity: 99.3813% V(tot) - V(min): 0.10089E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0380000 g log = -1.4202 Original solution: 1000.0103000 g Original solution / Rock added: 26316.06 (Water/Rock Ratio), log = 4.4202 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4002E-04 1.0071 0.4113E-04 0.4084E-04 CH4,gas 0.9139E-15 1.0125 0.9441E-15 0.9325E-15 H2,gas 0.6783E-06 1.0005 0.6925E-06 0.6921E-06 H2S,gas 0.1544E-11 0.9960 0.1570E-11 0.1576E-11 S2,gas 0.1890E-30 1.0000 0.1928E-30 0.1928E-30 CO,gas 0.7438E-14 1.0000 0.7590E-14 0.7590E-14 SO3,gas 0.1865E-35 1.0000 0.1903E-35 0.1903E-35 SO2,gas 0.5024E-19 1.0000 0.5127E-19 0.5127E-19 HCl,gas 0.6251E-15 1.0000 0.6378E-15 0.6378E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.74 -6.08 -2.028 0.10390E+05 -4.386 3 CH4,gas 4.54 -12.18 -16.72 -4.181 0.28556E+05 -15.025 4 H2,gas 8.00 0.14 -7.86 -4.491 0.13418E+05 -6.160 5 H2S,gas -6.23 -19.73 -13.50 -6.752 0.23056E+05 -11.804 6 S2,gas -7.34 -39.75 -32.41 -4.987 0.55346E+05 -30.715 7 CO,gas 3.21 -12.60 -15.82 -4.867 0.27010E+05 -14.120 8 SO3,gas 17.12 -20.30 -37.42 -9.355 0.63893E+05 -35.721 9 SO2,gas 0.83 -20.16 -20.99 -5.597 0.35838E+05 -19.290 10 HCl,gas 5.19 -11.70 -16.89 -8.447 0.28846E+05 -15.195 11 acmite 7.71 3.30 -4.41 -0.458 0.75251E+04 15 albite-high 0.69 -3.66 -4.35 -0.335 0.74329E+04 16 albite -0.38 -3.66 -3.28 -0.252 0.55941E+04 19 spessartine 24.46 20.37 -4.09 -0.205 0.69857E+04 20 analcite 3.32 -0.11 -3.43 -0.381 0.58544E+04 21 andalusite 5.00 2.19 -2.81 -0.281 0.47936E+04 22 andradite 39.01 34.83 -4.18 -0.217 0.71316E+04 23 grossular 32.73 28.01 -4.72 -0.236 0.80562E+04 24 anhydrite -5.32 -9.32 -4.01 -2.003 0.68404E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.77 -2.74 -0.912 0.46721E+04 36 brucite 12.57 8.58 -3.99 -0.797 0.68078E+04 37 calcite 0.81 -1.77 -2.58 -0.861 0.44079E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23217E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29336E+04 50 chloritoid-Mg 13.20 10.78 -2.42 -0.161 0.41357E+04 51 chloritoid-Fe 9.17 8.55 -0.63 -0.042 0.10686E+04 52 chloritoid-Mn 11.40 10.62 -0.78 -0.052 0.13332E+04 54 coesite -2.38 -3.55 -1.18 -0.392 0.20100E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.55 -0.99 -0.331 0.16954E+04 67 diopside 16.18 12.45 -3.73 -0.373 0.63709E+04 68 hedenbergite 14.21 10.22 -3.99 -0.399 0.68058E+04 75 epidote 24.67 23.32 -1.35 -0.065 0.23030E+04 76 clinozoisite 22.81 19.91 -2.89 -0.132 0.49420E+04 77 epidote-Fe 29.84 26.73 -3.11 -0.162 0.53107E+04 78 fayalite 14.05 9.15 -4.89 -0.699 0.83523E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.95 -4.18 -0.349 0.71458E+04 91 heulandite -5.83 -8.15 -2.32 -0.106 0.39665E+04 95 jadeite 4.22 -0.11 -4.32 -0.432 0.73799E+04 98 kaolinite -1.33 -1.36 -0.03 -0.002 0.45033E+02 99 kyanite 4.88 2.19 -2.68 -0.268 0.45795E+04 101 laumontite 2.88 2.51 -0.37 -0.025 0.63838E+03 105 lizardite 23.24 18.64 -4.61 -0.384 0.78645E+04 106 magnesite 0.69 -4.16 -4.85 -1.618 0.82882E+04 107 magnetite 20.09 18.92 -1.17 -0.095 0.19935E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.07 -2.58 -0.199 0.44128E+04 120 muscovite 2.58 0.68 -1.91 -0.112 0.32544E+04 121 paragonite 4.24 2.09 -2.15 -0.127 0.36747E+04 122 nepheline 8.34 3.45 -4.89 -0.699 0.83547E+04 136 prehnite 19.37 17.04 -2.33 -0.137 0.39850E+04 137 prehnite-Fe 22.50 20.45 -2.05 -0.123 0.35011E+04 138 pumpellyite-Fe 46.27 43.30 -2.97 -0.066 0.50644E+04 139 pumpellyite-Mg 48.99 45.53 -3.46 -0.077 0.59141E+04 145 pyroxmangite 7.40 4.87 -2.53 -0.505 0.43127E+04 146 pyrophyllite -6.18 -8.47 -2.29 -0.143 0.39099E+04 147 quartz -2.99 -3.55 -0.56 -0.188 0.96273E+03 151 rhodochrosite -0.98 -4.32 -3.34 -1.114 0.57072E+04 152 rhodonite 7.45 4.87 -2.57 -0.515 0.43930E+04 153 sanidine -1.28 -5.07 -3.80 -0.292 0.64806E+04 155 siderite -2.61 -6.39 -3.78 -1.261 0.64596E+04 156 sillimanite 5.26 2.19 -3.07 -0.307 0.52375E+04 163 stilbite -7.52 -8.15 -0.63 -0.030 0.10727E+04 164 stilpnomelane-Fe 13.02 10.45 -2.57 -0.077 0.43877E+04 167 sudoite-Fe 18.30 13.54 -4.75 -0.153 0.81171E+04 168 sudoite 21.08 18.00 -3.08 -0.099 0.52580E+04 171 talc 16.49 11.53 -4.96 -0.292 0.84685E+04 174 tephroite 18.09 13.30 -4.79 -0.684 0.81732E+04 177 topaz-H 4.62 2.19 -2.42 -0.220 0.41395E+04 178 tridymite -2.63 -3.55 -0.93 -0.309 0.15827E+04 187 wairakite 3.95 2.51 -1.44 -0.085 0.24603E+04 188 walstromite 11.51 7.42 -4.09 -0.817 0.69789E+04 189 wollastonite 10.46 7.42 -3.04 -0.608 0.51894E+04 190 pseudo-wollastonite 11.00 7.42 -3.58 -0.716 0.61092E+04 191 zoisite 22.85 19.91 -2.94 -0.134 0.50160E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.53 -2.89 -0.179 0.49316E+04 194 beidellite-H -2.33 -6.34 -4.02 -0.256 0.68616E+04 195 beidellite-K -1.52 -5.45 -3.93 -0.241 0.67079E+04 196 beidellite-Mg -1.79 -4.93 -3.14 -0.194 0.53599E+04 197 beidellite-Na -1.34 -4.98 -3.64 -0.223 0.62168E+04 199 chalcedony -2.80 -3.55 -0.75 -0.250 0.12820E+04 201 montmorillonite-Ca -2.29 -4.77 -2.48 -0.153 0.42354E+04 202 montmorillonite-K -2.24 -5.69 -3.45 -0.211 0.58897E+04 203 montmorillonite-Mg -2.48 -5.17 -2.69 -0.166 0.45868E+04 204 montmorillonite-Na -2.04 -5.22 -3.18 -0.195 0.54344E+04 205 nontronite-Ca 3.21 2.28 -0.93 -0.060 0.15873E+04 206 nontronite-H 2.53 0.47 -2.06 -0.138 0.35152E+04 207 nontronite-K 3.34 1.37 -1.97 -0.126 0.33649E+04 208 nontronite-Mg 3.07 1.89 -1.18 -0.077 0.20228E+04 209 nontronite-Na 3.52 1.84 -1.68 -0.108 0.28756E+04 214 gypsum -4.96 -9.32 -4.37 -1.092 0.74580E+04 224 tobermorite 9.82 5.59 -4.23 -1.155 0.72294E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.35 -3.46 -0.864 0.59043E+04 240 silica-amorphous -2.09 -3.55 -1.46 -0.487 0.24962E+04 242 an20ab80 2.02 -1.00 -3.02 -0.233 0.51611E+04 243 an25ab75 2.65 -0.34 -2.99 -0.230 0.50998E+04 244 an30ab70 3.28 0.32 -2.96 -0.227 0.50481E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0380000 g New total amount of reactant added: 0.0390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0390000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2958351E-03 Osmotic coef. = 0.9897 True ionic strength = .3116789E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15614E-07 -7.8065 0.14980E-07 -7.8245 0.95941E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13234E-03 -3.8783 0.95927E+00 -0.0181 4 SO4-- 0.25355E-04 -4.5959 0.22659E-04 -4.6448 0.89366E+00 -0.0488 5 HCO3- 0.12581E-04 -4.9003 0.12069E-04 -4.9183 0.95931E+00 -0.0180 6 HS- 0.11789E-11 -11.9285 0.11309E-11 -11.9466 0.95928E+00 -0.0181 7 Al+++ 0.31663E-20 -20.4994 0.25134E-20 -20.5997 0.79379E+00 -0.1003 8 H4SiO4 0.28538E-03 -3.5446 0.28538E-03 -3.5446 0.10000E+01 0.0000 9 Ca++ 0.22791E-04 -4.6422 0.20364E-04 -4.6911 0.89351E+00 -0.0489 10 Mg++ 0.94678E-07 -7.0238 0.84587E-07 -7.0727 0.89342E+00 -0.0489 11 Fe++ 0.56027E-09 -9.2516 0.50057E-09 -9.3005 0.89344E+00 -0.0489 12 K+ 0.82772E-05 -5.0821 0.79404E-05 -5.1002 0.95931E+00 -0.0180 13 Na+ 0.20896E-03 -3.6799 0.20045E-03 -3.6980 0.95927E+00 -0.0181 14 Mn++ 0.66432E-07 -7.1776 0.59354E-07 -7.2265 0.89346E+00 -0.0489 15 HPO4-- 0.24187E-08 -8.6164 0.21615E-08 -8.6652 0.89367E+00 -0.0488 16 HSiO3- 0.18544E-04 -4.7318 0.17788E-04 -4.7499 0.95927E+00 -0.0181 17 Ca(HSiO3)+ 0.85994E-08 -8.0655 0.82496E-08 -8.0836 0.95932E+00 -0.0180 18 Mg(HSiO3)+ 0.44454E-10 -10.3521 0.42646E-10 -10.3701 0.95932E+00 -0.0180 19 NaHSiO3,aq 0.57668E-07 -7.2391 0.57668E-07 -7.2391 0.10000E+01 0.0000 20 AlO+ 0.15883E-11 -11.7991 0.15237E-11 -11.8171 0.95932E+00 -0.0180 21 AlOH+2 0.12721E-15 -15.8955 0.11366E-15 -15.9444 0.89348E+00 -0.0489 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.31203E-05 -5.5058 0.29931E-05 -5.5239 0.95923E+00 -0.0181 24 CH4,aq 0.58516E-18 -18.2327 0.58511E-18 -18.2328 0.99991E+00 0.0000 29 CO,aq 0.49959E-17 -17.3014 0.49959E-17 -17.3014 0.10000E+01 0.0000 30 CO2,aq 0.38634E-06 -6.4130 0.38631E-06 -6.4131 0.99991E+00 0.0000 31 CO3-2 0.78745E-07 -7.1038 0.70368E-07 -7.1526 0.89362E+00 -0.0488 32 CaCO3,aq 0.17968E-07 -7.7455 0.17968E-07 -7.7455 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65394E-08 -8.1845 0.62734E-08 -8.2025 0.95932E+00 -0.0180 34 CaCl+ 0.45464E-08 -8.3423 0.43614E-08 -8.3604 0.95932E+00 -0.0180 35 CaCl2,aq 0.13713E-12 -12.8629 0.13713E-12 -12.8629 0.10000E+01 0.0000 36 CaOH+ 0.10099E-06 -6.9957 0.96882E-07 -7.0138 0.95932E+00 -0.0180 37 CaSO4,aq 0.14652E-06 -6.8341 0.14652E-06 -6.8341 0.10000E+01 0.0000 38 HCl,aq 0.36329E-12 -12.4397 0.36329E-12 -12.4397 0.10000E+01 0.0000 43 FeCl+ 0.10931E-12 -12.9614 0.10486E-12 -12.9794 0.95932E+00 -0.0180 46 FeO,aq 0.86694E-10 -10.0620 0.86694E-10 -10.0620 0.10000E+01 0.0000 47 FeOH+ 0.11338E-08 -8.9455 0.10877E-08 -8.9635 0.95932E+00 -0.0180 48 HFeO2- 0.63123E-10 -10.1998 0.60552E-10 -10.2179 0.95927E+00 -0.0181 49 FeO+ 0.11919E-12 -12.9238 0.11434E-12 -12.9418 0.95932E+00 -0.0180 50 FeOH+2 0.36611E-18 -18.4364 0.32711E-18 -18.4853 0.89348E+00 -0.0489 51 FeO2- 0.10869E-09 -9.9638 0.10426E-09 -9.9819 0.95927E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.51486E-09 -9.2883 0.51481E-09 -9.2883 0.99991E+00 0.0000 54 KCl,aq 0.19046E-10 -10.7202 0.19046E-10 -10.7202 0.10000E+01 0.0000 55 KHSO4,aq 0.76204E-17 -17.1180 0.76204E-17 -17.1180 0.10000E+01 0.0000 56 KOH,aq 0.22636E-09 -9.6452 0.22636E-09 -9.6452 0.10000E+01 0.0000 57 KSO4- 0.29104E-08 -8.5360 0.27919E-08 -8.5541 0.95927E+00 -0.0181 58 MgCO3,aq 0.18708E-10 -10.7280 0.18708E-10 -10.7280 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27756E-10 -10.5566 0.26627E-10 -10.5747 0.95932E+00 -0.0180 60 MgCl+ 0.17116E-10 -10.7666 0.16420E-10 -10.7846 0.95932E+00 -0.0180 61 MgOH+ 0.23213E-08 -8.6343 0.22268E-08 -8.6523 0.95932E+00 -0.0180 63 MnO,aq 0.27391E-09 -9.5624 0.27391E-09 -9.5624 0.10000E+01 0.0000 64 MnOH+ 0.12489E-07 -7.9035 0.11981E-07 -7.9215 0.95932E+00 -0.0180 65 MnO2-2 0.45329E-16 -16.3436 0.40507E-16 -16.3925 0.89362E+00 -0.0488 66 HMnO2- 0.13859E-12 -12.8583 0.13294E-12 -12.8763 0.95927E+00 -0.0181 69 MnCl+ 0.50423E-10 -10.2974 0.48371E-10 -10.3154 0.95932E+00 -0.0180 70 MnSO4,aq 0.38825E-09 -9.4109 0.38825E-09 -9.4109 0.10000E+01 0.0000 71 NaCl,aq 0.87913E-08 -8.0559 0.87913E-08 -8.0559 0.10000E+01 0.0000 72 NaOH,aq 0.57489E-08 -8.2404 0.57489E-08 -8.2404 0.10000E+01 0.0000 74 OH- 0.40208E-04 -4.3957 0.38569E-04 -4.4138 0.95923E+00 -0.0181 82 H3PO4,aq 0.33926E-14 -14.4695 0.33926E-14 -14.4695 0.10000E+01 0.0000 83 H2PO4- 0.62268E-09 -9.2057 0.59733E-09 -9.2238 0.95929E+00 -0.0180 84 PO4-3 0.14814E-12 -12.8293 0.11773E-12 -12.9291 0.79469E+00 -0.0998 87 H2P2O7-2 0.31308E-19 -19.5043 0.27977E-19 -19.5532 0.89362E+00 -0.0488 88 HP2O7-3 0.46979E-18 -18.3281 0.37292E-18 -18.4284 0.79379E+00 -0.1003 90 H2S,aq 0.52364E-13 -13.2810 0.52359E-13 -13.2810 0.99991E+00 0.0000 96 SO2,aq 0.11691E-19 -19.9322 0.11691E-19 -19.9322 0.10000E+01 0.0000 97 SO3-2 0.16957E-14 -14.7706 0.15159E-14 -14.8193 0.89392E+00 -0.0487 98 HSO3- 0.14822E-14 -14.8291 0.14218E-14 -14.8472 0.95927E+00 -0.0181 99 HSO4- 0.34098E-09 -9.4673 0.32712E-09 -9.4853 0.95934E+00 -0.0180 101 S2O3-2 0.15595E-19 -19.8070 0.13936E-19 -19.8559 0.89362E+00 -0.0488 Charge balance for all species = 0.2024E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1561415E-07 -.7117832E-04 -.7174048E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999566E+06 0.0000 3 Cl- 0.1379625E-03 0.1379760E-03 0.4891458E+01 3.9462 4 SO4-- 0.2535464E-04 0.2550471E-04 0.2449921E+01 11.0042 5 HCO3- 0.1258053E-04 0.1307017E-04 0.7974719E+00 2.9061 6 HS- 0.1178905E-11 0.9151639E-10 0.3026504E-05 -4.1221 7 Al+++ 0.3166325E-20 0.3140576E-05 0.8473392E-01 2.8737 8 H4SiO4 0.2853841E-03 0.3039939E-03 0.2921728E+02 -3.5446 9 Ca++ 0.2279081E-04 0.2307598E-04 0.9248005E+00 10.9578 10 Mg++ 0.9467781E-07 0.9710711E-07 0.2360770E-02 8.5763 11 Fe++ 0.5602732E-09 0.2151481E-08 0.1201487E-03 6.3484 12 K+ 0.8277207E-05 0.8280362E-05 0.3237652E+00 2.7243 13 Na+ 0.2089560E-03 0.2090282E-03 0.4805317E+01 4.1265 14 Mn++ 0.6643172E-07 0.7963359E-07 0.4374728E-02 8.4224 15 HPO4-- 0.2418731E-08 0.3041562E-08 0.2919139E-03 6.9837 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6327421E-03 -.7117739E-04 -.5615647E-03 0.0000000E+00 2 H2O 0.5550776E+02 0.5550756E+02 0.2052812E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2658529E-04 0.2550438E-04 0.1080914E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1080823E-05 0.9151520E-10 -.1080914E-05 0.0000000E+00 7 Al+++ 0.1271689E-03 0.3140535E-05 0.1240284E-03 0.0000000E+00 8 H4SiO4 0.4060985E-03 0.3039900E-03 0.1021086E-03 0.0000000E+00 9 Ca++ 0.5932662E-04 0.2307568E-04 0.3625094E-04 0.0000000E+00 10 Mg++ 0.3095238E-04 0.9710585E-07 0.3085528E-04 0.0000000E+00 11 Fe++ 0.2780734E-04 0.2151453E-08 0.2780518E-04 0.0000000E+00 12 K+ 0.8280255E-05 0.8280255E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2090255E-03 0.2090255E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6762052E-06 0.7963256E-07 0.5965727E-06 0.0000000E+00 15 HPO4-- 0.2307855E-06 0.3041523E-08 0.2277440E-06 0.0000000E+00 Chg. balance for solid moles: -.1609E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7591E-07 -7.120 0.3813E-04 -4.419 0.1890 0.1212E-04 clinochlore 0.6171E-05 -5.210 0.3430E-02 -2.465 17.00 0.1305E-02 daphnite 0.3832E-05 -5.417 0.2734E-02 -2.563 13.55 0.8284E-03 chlorite-Mn 0.1193E-06 -6.923 0.8459E-04 -4.073 0.4194 0.2696E-04 diaspore 0.3204E-04 -4.494 0.1922E-02 -2.716 9.529 0.5722E-03 hematite 0.4324E-05 -5.364 0.6905E-03 -3.161 3.423 0.1309E-03 lawsonite 0.3587E-04 -4.445 0.1127E-01 -1.948 55.88 0.3635E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3785E+00 0.3785E+00 1.0000 -0.422 chlorite-Mn 0.1179E-01 0.1179E-01 1.0000 -1.929 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.020172 g Volume = 0.006510 cm3 Porosity: 99.3590% V(tot) - V(min): 0.10091E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0390000 g log = -1.4089 Original solution: 1000.0103000 g Original solution / Rock added: 25641.29 (Water/Rock Ratio), log = 4.4089 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4022E-04 1.0071 0.4133E-04 0.4104E-04 CH4,gas 0.8336E-15 1.0125 0.8612E-15 0.8506E-15 H2,gas 0.6621E-06 1.0005 0.6759E-06 0.6755E-06 H2S,gas 0.1416E-11 0.9960 0.1439E-11 0.1445E-11 S2,gas 0.1668E-30 1.0000 0.1702E-30 0.1702E-30 CO,gas 0.7297E-14 1.0000 0.7445E-14 0.7445E-14 SO3,gas 0.1884E-35 1.0000 0.1923E-35 0.1923E-35 SO2,gas 0.4955E-19 1.0000 0.5056E-19 0.5056E-19 HCl,gas 0.6283E-15 1.0000 0.6410E-15 0.6410E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.74 -6.08 -2.028 0.10386E+05 -4.384 3 CH4,gas 4.54 -12.22 -16.76 -4.191 0.28624E+05 -15.065 4 H2,gas 8.00 0.13 -7.87 -4.497 0.13436E+05 -6.170 5 H2S,gas -6.23 -19.77 -13.54 -6.770 0.23121E+05 -11.842 6 S2,gas -7.34 -39.80 -32.47 -4.995 0.55438E+05 -30.769 7 CO,gas 3.21 -12.61 -15.83 -4.870 0.27024E+05 -14.128 8 SO3,gas 17.12 -20.29 -37.42 -9.354 0.63885E+05 -35.716 9 SO2,gas 0.83 -20.16 -21.00 -5.599 0.35849E+05 -19.296 10 HCl,gas 5.19 -11.70 -16.89 -8.446 0.28843E+05 -15.193 11 acmite 7.71 3.32 -4.39 -0.456 0.74946E+04 15 albite-high 0.69 -3.63 -4.33 -0.333 0.73875E+04 16 albite -0.38 -3.63 -3.25 -0.250 0.55487E+04 19 spessartine 24.46 20.38 -4.08 -0.204 0.69604E+04 20 analcite 3.32 -0.09 -3.41 -0.379 0.58239E+04 21 andalusite 5.00 2.20 -2.80 -0.280 0.47787E+04 22 andradite 39.01 34.81 -4.20 -0.218 0.71762E+04 23 grossular 32.73 27.99 -4.74 -0.237 0.81007E+04 24 anhydrite -5.32 -9.34 -4.02 -2.010 0.68625E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.79 -2.75 -0.917 0.46982E+04 36 brucite 12.57 8.58 -3.99 -0.798 0.68167E+04 37 calcite 0.81 -1.79 -2.60 -0.866 0.44339E+04 40 carpholite-Mg 8.58 7.23 -1.35 -0.090 0.23009E+04 41 carpholite-Fe 6.71 5.01 -1.71 -0.114 0.29129E+04 50 chloritoid-Mg 13.20 10.78 -2.42 -0.161 0.41297E+04 51 chloritoid-Fe 9.17 8.55 -0.62 -0.041 0.10627E+04 52 chloritoid-Mn 11.40 10.63 -0.78 -0.052 0.13247E+04 54 coesite -2.38 -3.54 -1.17 -0.390 0.19952E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.54 -0.98 -0.328 0.16805E+04 67 diopside 16.18 12.44 -3.74 -0.374 0.63798E+04 68 hedenbergite 14.21 10.22 -3.99 -0.399 0.68148E+04 75 epidote 24.67 23.31 -1.36 -0.066 0.23179E+04 76 clinozoisite 22.81 19.90 -2.90 -0.132 0.49568E+04 77 epidote-Fe 29.84 26.72 -3.12 -0.162 0.53256E+04 78 fayalite 14.05 9.15 -4.89 -0.699 0.83554E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.96 -4.18 -0.349 0.71430E+04 91 heulandite -5.83 -8.11 -2.28 -0.104 0.38922E+04 95 jadeite 4.22 -0.09 -4.30 -0.430 0.73494E+04 98 kaolinite -1.33 -1.34 -0.01 -0.001 0.15330E+02 99 kyanite 4.88 2.20 -2.67 -0.267 0.45646E+04 101 laumontite 2.88 2.53 -0.36 -0.024 0.60868E+03 105 lizardite 23.24 18.64 -4.60 -0.384 0.78615E+04 106 magnesite 0.69 -4.17 -4.86 -1.619 0.82935E+04 107 magnetite 20.09 18.91 -1.17 -0.096 0.20025E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.04 -2.55 -0.196 0.43527E+04 120 muscovite 2.58 0.71 -1.87 -0.110 0.31942E+04 121 paragonite 4.24 2.11 -2.13 -0.125 0.36294E+04 122 nepheline 8.34 3.46 -4.88 -0.698 0.83390E+04 136 prehnite 19.37 17.03 -2.34 -0.138 0.39999E+04 137 prehnite-Fe 22.50 20.44 -2.06 -0.124 0.35159E+04 138 pumpellyite-Fe 46.27 43.28 -2.99 -0.066 0.51031E+04 139 pumpellyite-Mg 48.99 45.51 -3.49 -0.077 0.59527E+04 145 pyroxmangite 7.40 4.88 -2.52 -0.504 0.43043E+04 146 pyrophyllite -6.18 -8.43 -2.26 -0.141 0.38505E+04 147 quartz -2.99 -3.54 -0.56 -0.185 0.94788E+03 151 rhodochrosite -0.98 -4.32 -3.34 -1.115 0.57099E+04 152 rhodonite 7.45 4.88 -2.57 -0.514 0.43845E+04 153 sanidine -1.28 -5.04 -3.76 -0.289 0.64204E+04 155 siderite -2.61 -6.39 -3.79 -1.262 0.64649E+04 156 sillimanite 5.26 2.20 -3.06 -0.306 0.52226E+04 163 stilbite -7.52 -8.11 -0.58 -0.028 0.99841E+03 164 stilpnomelane-Fe 13.02 10.50 -2.52 -0.075 0.43060E+04 167 sudoite-Fe 18.30 13.56 -4.74 -0.153 0.80905E+04 168 sudoite 21.08 18.01 -3.06 -0.099 0.52313E+04 171 talc 16.49 11.55 -4.94 -0.291 0.84359E+04 174 tephroite 18.09 13.30 -4.79 -0.684 0.81712E+04 177 topaz-H 4.62 2.20 -2.42 -0.220 0.41247E+04 178 tridymite -2.63 -3.54 -0.92 -0.306 0.15679E+04 187 wairakite 3.95 2.53 -1.42 -0.084 0.24306E+04 188 walstromite 11.51 7.41 -4.10 -0.819 0.69938E+04 189 wollastonite 10.46 7.41 -3.05 -0.610 0.52042E+04 190 pseudo-wollastonite 11.00 7.41 -3.59 -0.717 0.61240E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50309E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.50 -2.86 -0.177 0.48820E+04 194 beidellite-H -2.33 -6.31 -3.99 -0.254 0.68071E+04 195 beidellite-K -1.52 -5.41 -3.89 -0.238 0.66482E+04 196 beidellite-Mg -1.79 -4.90 -3.11 -0.192 0.53068E+04 197 beidellite-Na -1.34 -4.95 -3.61 -0.221 0.61621E+04 199 chalcedony -2.80 -3.54 -0.74 -0.247 0.12672E+04 201 montmorillonite-Ca -2.29 -4.74 -2.45 -0.152 0.41838E+04 202 montmorillonite-K -2.24 -5.65 -3.41 -0.209 0.58281E+04 203 montmorillonite-Mg -2.48 -5.13 -2.65 -0.164 0.45318E+04 204 montmorillonite-Na -2.04 -5.19 -3.15 -0.193 0.53777E+04 205 nontronite-Ca 3.21 2.31 -0.90 -0.058 0.15377E+04 206 nontronite-H 2.53 0.51 -2.03 -0.136 0.34607E+04 207 nontronite-K 3.34 1.40 -1.94 -0.124 0.33052E+04 208 nontronite-Mg 3.07 1.92 -1.15 -0.075 0.19698E+04 209 nontronite-Na 3.52 1.87 -1.65 -0.106 0.28208E+04 214 gypsum -4.96 -9.34 -4.38 -1.095 0.74801E+04 224 tobermorite 9.82 5.58 -4.24 -1.157 0.72393E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.35 -3.46 -0.866 0.59132E+04 240 silica-amorphous -2.09 -3.54 -1.45 -0.484 0.24814E+04 242 an20ab80 2.02 -0.98 -3.00 -0.231 0.51248E+04 243 an25ab75 2.65 -0.32 -2.97 -0.228 0.50658E+04 244 an30ab70 3.28 0.34 -2.94 -0.226 0.50164E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0390000 g New total amount of reactant added: 0.0400000 g Mixing fraction reached given limit of 0.4000E-01 TOTMIX = 0.4000E-01 Execution stopped.