File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.63274E-03 0.15614E-07 0.9594 0.00000000E+00 H2O 2 0. 0.55508E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13796E-03 0.9593 0.00000000E+00 SO4-- 4 -2. 0.26585E-04 0.25355E-04 0.8937 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.12581E-04 0.9593 0.00000000E+00 HS- 6 -1. -0.10808E-05 0.11789E-11 0.9593 0.00000000E+00 Al+++ 7 3. 0.12717E-03 0.31663E-20 0.7938 0.00000000E+00 H4SiO4 8 0. 0.40610E-03 0.28538E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.59327E-04 0.22791E-04 0.8935 0.00000000E+00 Mg++ 10 2. 0.30952E-04 0.94678E-07 0.8934 0.00000000E+00 Fe++ 11 2. 0.27807E-04 0.56027E-09 0.8934 0.00000000E+00 K+ 12 1. 0.82803E-05 0.82772E-05 0.9593 0.00000000E+00 Na+ 13 1. 0.20903E-03 0.20896E-03 0.9593 0.00000000E+00 Mn++ 14 2. 0.67621E-06 0.66432E-07 0.8935 0.00000000E+00 HPO4-- 15 -2. 0.23079E-06 0.24187E-08 0.8937 0.00000000E+00 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.800000E-01 TEMP = 100.0000 SINC = 0.2000E-02 TEMPC = 0.0000 TOTMIX = 0.390000E-01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.0156 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.0000E+00 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.0000E+00 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.0000E+00 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.7591E-07 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.0000E+00 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.0000E+00 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.6171E-05 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.3832E-05 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.1193E-06 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.3204E-04 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.0000E+00 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.0000E+00 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.4324E-05 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.0000E+00 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.3587E-04 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.0000E+00 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.0000E+00 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.0390000 g log = -1.4089 Original solution: 1000.0103000 g Original solution / Rock added: 25641.29 (Water/Rock Ratio), log = 4.4089 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0390000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2958351E-03 Osmotic coef. = 0.9897 True ionic strength = .3116789E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15614E-07 -7.8065 0.14980E-07 -7.8245 0.95941E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13234E-03 -3.8783 0.95927E+00 -0.0181 4 SO4-- 0.25355E-04 -4.5959 0.22659E-04 -4.6448 0.89366E+00 -0.0488 5 HCO3- 0.12581E-04 -4.9003 0.12069E-04 -4.9183 0.95931E+00 -0.0180 6 HS- 0.11789E-11 -11.9285 0.11309E-11 -11.9466 0.95928E+00 -0.0181 7 Al+++ 0.31663E-20 -20.4994 0.25134E-20 -20.5997 0.79379E+00 -0.1003 8 H4SiO4 0.28538E-03 -3.5446 0.28538E-03 -3.5446 0.10000E+01 0.0000 9 Ca++ 0.22791E-04 -4.6422 0.20364E-04 -4.6911 0.89351E+00 -0.0489 10 Mg++ 0.94678E-07 -7.0238 0.84587E-07 -7.0727 0.89342E+00 -0.0489 11 Fe++ 0.56027E-09 -9.2516 0.50057E-09 -9.3005 0.89344E+00 -0.0489 12 K+ 0.82772E-05 -5.0821 0.79404E-05 -5.1002 0.95931E+00 -0.0180 13 Na+ 0.20896E-03 -3.6799 0.20045E-03 -3.6980 0.95927E+00 -0.0181 14 Mn++ 0.66432E-07 -7.1776 0.59354E-07 -7.2265 0.89346E+00 -0.0489 15 HPO4-- 0.24187E-08 -8.6164 0.21615E-08 -8.6652 0.89367E+00 -0.0488 16 HSiO3- 0.18544E-04 -4.7318 0.17788E-04 -4.7499 0.95927E+00 -0.0181 17 Ca(HSiO3)+ 0.85994E-08 -8.0655 0.82496E-08 -8.0836 0.95932E+00 -0.0180 18 Mg(HSiO3)+ 0.44454E-10 -10.3521 0.42646E-10 -10.3701 0.95932E+00 -0.0180 19 NaHSiO3,aq 0.57668E-07 -7.2391 0.57668E-07 -7.2391 0.10000E+01 0.0000 20 AlO+ 0.15883E-11 -11.7991 0.15237E-11 -11.8171 0.95932E+00 -0.0180 21 AlOH+2 0.12721E-15 -15.8955 0.11366E-15 -15.9444 0.89348E+00 -0.0489 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.31203E-05 -5.5058 0.29931E-05 -5.5239 0.95923E+00 -0.0181 24 CH4,aq 0.58516E-18 -18.2327 0.58511E-18 -18.2328 0.99991E+00 0.0000 29 CO,aq 0.49959E-17 -17.3014 0.49959E-17 -17.3014 0.10000E+01 0.0000 30 CO2,aq 0.38634E-06 -6.4130 0.38631E-06 -6.4131 0.99991E+00 0.0000 31 CO3-2 0.78745E-07 -7.1038 0.70368E-07 -7.1526 0.89362E+00 -0.0488 32 CaCO3,aq 0.17968E-07 -7.7455 0.17968E-07 -7.7455 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65394E-08 -8.1845 0.62734E-08 -8.2025 0.95932E+00 -0.0180 34 CaCl+ 0.45464E-08 -8.3423 0.43614E-08 -8.3604 0.95932E+00 -0.0180 35 CaCl2,aq 0.13713E-12 -12.8629 0.13713E-12 -12.8629 0.10000E+01 0.0000 36 CaOH+ 0.10099E-06 -6.9957 0.96882E-07 -7.0138 0.95932E+00 -0.0180 37 CaSO4,aq 0.14652E-06 -6.8341 0.14652E-06 -6.8341 0.10000E+01 0.0000 38 HCl,aq 0.36329E-12 -12.4397 0.36329E-12 -12.4397 0.10000E+01 0.0000 43 FeCl+ 0.10931E-12 -12.9614 0.10486E-12 -12.9794 0.95932E+00 -0.0180 46 FeO,aq 0.86694E-10 -10.0620 0.86694E-10 -10.0620 0.10000E+01 0.0000 47 FeOH+ 0.11338E-08 -8.9455 0.10877E-08 -8.9635 0.95932E+00 -0.0180 48 HFeO2- 0.63123E-10 -10.1998 0.60552E-10 -10.2179 0.95927E+00 -0.0181 49 FeO+ 0.11919E-12 -12.9238 0.11434E-12 -12.9418 0.95932E+00 -0.0180 50 FeOH+2 0.36611E-18 -18.4364 0.32711E-18 -18.4853 0.89348E+00 -0.0489 51 FeO2- 0.10869E-09 -9.9638 0.10426E-09 -9.9819 0.95927E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.51486E-09 -9.2883 0.51481E-09 -9.2883 0.99991E+00 0.0000 54 KCl,aq 0.19046E-10 -10.7202 0.19046E-10 -10.7202 0.10000E+01 0.0000 55 KHSO4,aq 0.76204E-17 -17.1180 0.76204E-17 -17.1180 0.10000E+01 0.0000 56 KOH,aq 0.22636E-09 -9.6452 0.22636E-09 -9.6452 0.10000E+01 0.0000 57 KSO4- 0.29104E-08 -8.5360 0.27919E-08 -8.5541 0.95927E+00 -0.0181 58 MgCO3,aq 0.18708E-10 -10.7280 0.18708E-10 -10.7280 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27756E-10 -10.5566 0.26627E-10 -10.5747 0.95932E+00 -0.0180 60 MgCl+ 0.17116E-10 -10.7666 0.16420E-10 -10.7846 0.95932E+00 -0.0180 61 MgOH+ 0.23213E-08 -8.6343 0.22268E-08 -8.6523 0.95932E+00 -0.0180 63 MnO,aq 0.27391E-09 -9.5624 0.27391E-09 -9.5624 0.10000E+01 0.0000 64 MnOH+ 0.12489E-07 -7.9035 0.11981E-07 -7.9215 0.95932E+00 -0.0180 65 MnO2-2 0.45329E-16 -16.3436 0.40507E-16 -16.3925 0.89362E+00 -0.0488 66 HMnO2- 0.13859E-12 -12.8583 0.13294E-12 -12.8763 0.95927E+00 -0.0181 69 MnCl+ 0.50423E-10 -10.2974 0.48371E-10 -10.3154 0.95932E+00 -0.0180 70 MnSO4,aq 0.38825E-09 -9.4109 0.38825E-09 -9.4109 0.10000E+01 0.0000 71 NaCl,aq 0.87913E-08 -8.0559 0.87913E-08 -8.0559 0.10000E+01 0.0000 72 NaOH,aq 0.57489E-08 -8.2404 0.57489E-08 -8.2404 0.10000E+01 0.0000 74 OH- 0.40208E-04 -4.3957 0.38569E-04 -4.4138 0.95923E+00 -0.0181 82 H3PO4,aq 0.33926E-14 -14.4695 0.33926E-14 -14.4695 0.10000E+01 0.0000 83 H2PO4- 0.62268E-09 -9.2057 0.59733E-09 -9.2238 0.95929E+00 -0.0180 84 PO4-3 0.14814E-12 -12.8293 0.11773E-12 -12.9291 0.79469E+00 -0.0998 87 H2P2O7-2 0.31308E-19 -19.5043 0.27977E-19 -19.5532 0.89362E+00 -0.0488 88 HP2O7-3 0.46979E-18 -18.3281 0.37292E-18 -18.4284 0.79379E+00 -0.1003 90 H2S,aq 0.52364E-13 -13.2810 0.52359E-13 -13.2810 0.99991E+00 0.0000 96 SO2,aq 0.11691E-19 -19.9322 0.11691E-19 -19.9322 0.10000E+01 0.0000 97 SO3-2 0.16957E-14 -14.7706 0.15159E-14 -14.8193 0.89392E+00 -0.0487 98 HSO3- 0.14822E-14 -14.8291 0.14218E-14 -14.8472 0.95927E+00 -0.0181 99 HSO4- 0.34098E-09 -9.4673 0.32712E-09 -9.4853 0.95934E+00 -0.0180 101 S2O3-2 0.15595E-19 -19.8070 0.13936E-19 -19.8559 0.89362E+00 -0.0488 Charge balance for all species = 0.2240E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1561415E-07 -.7117832E-04 -.7174048E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999566E+06 0.0000 3 Cl- 0.1379625E-03 0.1379760E-03 0.4891458E+01 3.9462 4 SO4-- 0.2535464E-04 0.2550471E-04 0.2449921E+01 11.0042 5 HCO3- 0.1258053E-04 0.1307017E-04 0.7974719E+00 2.9061 6 HS- 0.1178905E-11 0.9151639E-10 0.3026504E-05 -4.1221 7 Al+++ 0.3166325E-20 0.3140576E-05 0.8473392E-01 2.8737 8 H4SiO4 0.2853841E-03 0.3039939E-03 0.2921728E+02 -3.5446 9 Ca++ 0.2279081E-04 0.2307598E-04 0.9248005E+00 10.9578 10 Mg++ 0.9467781E-07 0.9710711E-07 0.2360770E-02 8.5763 11 Fe++ 0.5602732E-09 0.2151481E-08 0.1201487E-03 6.3484 12 K+ 0.8277207E-05 0.8280362E-05 0.3237652E+00 2.7243 13 Na+ 0.2089560E-03 0.2090282E-03 0.4805317E+01 4.1265 14 Mn++ 0.6643172E-07 0.7963359E-07 0.4374728E-02 8.4224 15 HPO4-- 0.2418731E-08 0.3041562E-08 0.2919139E-03 6.9837 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6327421E-03 -.7117739E-04 -.5615647E-03 0.0000000E+00 2 H2O 0.5550776E+02 0.5550756E+02 0.2052812E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2658529E-04 0.2550438E-04 0.1080914E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1080823E-05 0.9151520E-10 -.1080914E-05 0.0000000E+00 7 Al+++ 0.1271689E-03 0.3140535E-05 0.1240284E-03 0.0000000E+00 8 H4SiO4 0.4060985E-03 0.3039900E-03 0.1021086E-03 0.0000000E+00 9 Ca++ 0.5932662E-04 0.2307568E-04 0.3625094E-04 0.0000000E+00 10 Mg++ 0.3095238E-04 0.9710585E-07 0.3085528E-04 0.0000000E+00 11 Fe++ 0.2780734E-04 0.2151453E-08 0.2780518E-04 0.0000000E+00 12 K+ 0.8280255E-05 0.8280255E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2090255E-03 0.2090255E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6762052E-06 0.7963256E-07 0.5965727E-06 0.0000000E+00 15 HPO4-- 0.2307855E-06 0.3041523E-08 0.2277440E-06 0.0000000E+00 Chg. balance for solid moles: 0.3854E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7591E-07 -7.120 0.3813E-04 -4.419 0.1890 0.1212E-04 clinochlore 0.6171E-05 -5.210 0.3430E-02 -2.465 17.00 0.1305E-02 daphnite 0.3832E-05 -5.417 0.2734E-02 -2.563 13.55 0.8284E-03 chlorite-Mn 0.1193E-06 -6.923 0.8459E-04 -4.073 0.4194 0.2696E-04 diaspore 0.3204E-04 -4.494 0.1922E-02 -2.716 9.529 0.5722E-03 hematite 0.4324E-05 -5.364 0.6905E-03 -3.161 3.423 0.1309E-03 lawsonite 0.3587E-04 -4.445 0.1127E-01 -1.948 55.88 0.3635E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3785E+00 0.3785E+00 1.0000 -0.422 chlorite-Mn 0.1179E-01 0.1179E-01 1.0000 -1.929 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.020172 g Volume = 0.006510 cm3 Porosity: 99.3590% V(tot) - V(min): 0.10091E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0390000 g log = -1.4089 Original solution: 1000.0103000 g Original solution / Rock added: 25641.29 (Water/Rock Ratio), log = 4.4089 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4022E-04 1.0071 0.4133E-04 0.4104E-04 CH4,gas 0.8336E-15 1.0125 0.8612E-15 0.8506E-15 H2,gas 0.6621E-06 1.0005 0.6759E-06 0.6755E-06 H2S,gas 0.1416E-11 0.9960 0.1439E-11 0.1445E-11 S2,gas 0.1668E-30 1.0000 0.1702E-30 0.1702E-30 CO,gas 0.7297E-14 1.0000 0.7445E-14 0.7445E-14 SO3,gas 0.1884E-35 1.0000 0.1923E-35 0.1923E-35 SO2,gas 0.4955E-19 1.0000 0.5056E-19 0.5056E-19 HCl,gas 0.6283E-15 1.0000 0.6410E-15 0.6410E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.74 -6.08 -2.028 0.10386E+05 -4.384 3 CH4,gas 4.54 -12.22 -16.76 -4.191 0.28624E+05 -15.065 4 H2,gas 8.00 0.13 -7.87 -4.497 0.13436E+05 -6.170 5 H2S,gas -6.23 -19.77 -13.54 -6.770 0.23121E+05 -11.842 6 S2,gas -7.34 -39.80 -32.47 -4.995 0.55438E+05 -30.769 7 CO,gas 3.21 -12.61 -15.83 -4.870 0.27024E+05 -14.128 8 SO3,gas 17.12 -20.29 -37.42 -9.354 0.63885E+05 -35.716 9 SO2,gas 0.83 -20.16 -21.00 -5.599 0.35849E+05 -19.296 10 HCl,gas 5.19 -11.70 -16.89 -8.446 0.28843E+05 -15.193 11 acmite 7.71 3.32 -4.39 -0.456 0.74946E+04 15 albite-high 0.69 -3.63 -4.33 -0.333 0.73875E+04 16 albite -0.38 -3.63 -3.25 -0.250 0.55487E+04 19 spessartine 24.46 20.38 -4.08 -0.204 0.69604E+04 20 analcite 3.32 -0.09 -3.41 -0.379 0.58239E+04 21 andalusite 5.00 2.20 -2.80 -0.280 0.47787E+04 22 andradite 39.01 34.81 -4.20 -0.218 0.71762E+04 23 grossular 32.73 27.99 -4.74 -0.237 0.81007E+04 24 anhydrite -5.32 -9.34 -4.02 -2.010 0.68625E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.79 -2.75 -0.917 0.46982E+04 36 brucite 12.57 8.58 -3.99 -0.798 0.68167E+04 37 calcite 0.81 -1.79 -2.60 -0.866 0.44339E+04 40 carpholite-Mg 8.58 7.23 -1.35 -0.090 0.23009E+04 41 carpholite-Fe 6.71 5.01 -1.71 -0.114 0.29129E+04 50 chloritoid-Mg 13.20 10.78 -2.42 -0.161 0.41297E+04 51 chloritoid-Fe 9.17 8.55 -0.62 -0.041 0.10627E+04 52 chloritoid-Mn 11.40 10.63 -0.78 -0.052 0.13247E+04 54 coesite -2.38 -3.54 -1.17 -0.390 0.19952E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.54 -0.98 -0.328 0.16805E+04 67 diopside 16.18 12.44 -3.74 -0.374 0.63798E+04 68 hedenbergite 14.21 10.22 -3.99 -0.399 0.68148E+04 75 epidote 24.67 23.31 -1.36 -0.066 0.23179E+04 76 clinozoisite 22.81 19.90 -2.90 -0.132 0.49568E+04 77 epidote-Fe 29.84 26.72 -3.12 -0.162 0.53256E+04 78 fayalite 14.05 9.15 -4.89 -0.699 0.83554E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.96 -4.18 -0.349 0.71430E+04 91 heulandite -5.83 -8.11 -2.28 -0.104 0.38922E+04 95 jadeite 4.22 -0.09 -4.30 -0.430 0.73494E+04 98 kaolinite -1.33 -1.34 -0.01 -0.001 0.15330E+02 99 kyanite 4.88 2.20 -2.67 -0.267 0.45646E+04 101 laumontite 2.88 2.53 -0.36 -0.024 0.60868E+03 105 lizardite 23.24 18.64 -4.60 -0.384 0.78615E+04 106 magnesite 0.69 -4.17 -4.86 -1.619 0.82935E+04 107 magnetite 20.09 18.91 -1.17 -0.096 0.20025E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.04 -2.55 -0.196 0.43527E+04 120 muscovite 2.58 0.71 -1.87 -0.110 0.31942E+04 121 paragonite 4.24 2.11 -2.13 -0.125 0.36294E+04 122 nepheline 8.34 3.46 -4.88 -0.698 0.83390E+04 136 prehnite 19.37 17.03 -2.34 -0.138 0.39999E+04 137 prehnite-Fe 22.50 20.44 -2.06 -0.124 0.35159E+04 138 pumpellyite-Fe 46.27 43.28 -2.99 -0.066 0.51031E+04 139 pumpellyite-Mg 48.99 45.51 -3.49 -0.077 0.59527E+04 145 pyroxmangite 7.40 4.88 -2.52 -0.504 0.43043E+04 146 pyrophyllite -6.18 -8.43 -2.26 -0.141 0.38505E+04 147 quartz -2.99 -3.54 -0.56 -0.185 0.94788E+03 151 rhodochrosite -0.98 -4.32 -3.34 -1.115 0.57099E+04 152 rhodonite 7.45 4.88 -2.57 -0.514 0.43845E+04 153 sanidine -1.28 -5.04 -3.76 -0.289 0.64204E+04 155 siderite -2.61 -6.39 -3.79 -1.262 0.64649E+04 156 sillimanite 5.26 2.20 -3.06 -0.306 0.52226E+04 163 stilbite -7.52 -8.11 -0.58 -0.028 0.99841E+03 164 stilpnomelane-Fe 13.02 10.50 -2.52 -0.075 0.43060E+04 167 sudoite-Fe 18.30 13.56 -4.74 -0.153 0.80905E+04 168 sudoite 21.08 18.01 -3.06 -0.099 0.52313E+04 171 talc 16.49 11.55 -4.94 -0.291 0.84359E+04 174 tephroite 18.09 13.30 -4.79 -0.684 0.81712E+04 177 topaz-H 4.62 2.20 -2.42 -0.220 0.41247E+04 178 tridymite -2.63 -3.54 -0.92 -0.306 0.15679E+04 187 wairakite 3.95 2.53 -1.42 -0.084 0.24306E+04 188 walstromite 11.51 7.41 -4.10 -0.819 0.69938E+04 189 wollastonite 10.46 7.41 -3.05 -0.610 0.52042E+04 190 pseudo-wollastonite 11.00 7.41 -3.59 -0.717 0.61240E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50309E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.50 -2.86 -0.177 0.48820E+04 194 beidellite-H -2.33 -6.31 -3.99 -0.254 0.68071E+04 195 beidellite-K -1.52 -5.41 -3.89 -0.238 0.66482E+04 196 beidellite-Mg -1.79 -4.90 -3.11 -0.192 0.53068E+04 197 beidellite-Na -1.34 -4.95 -3.61 -0.221 0.61621E+04 199 chalcedony -2.80 -3.54 -0.74 -0.247 0.12672E+04 201 montmorillonite-Ca -2.29 -4.74 -2.45 -0.152 0.41838E+04 202 montmorillonite-K -2.24 -5.65 -3.41 -0.209 0.58281E+04 203 montmorillonite-Mg -2.48 -5.13 -2.65 -0.164 0.45318E+04 204 montmorillonite-Na -2.04 -5.19 -3.15 -0.193 0.53777E+04 205 nontronite-Ca 3.21 2.31 -0.90 -0.058 0.15377E+04 206 nontronite-H 2.53 0.51 -2.03 -0.136 0.34607E+04 207 nontronite-K 3.34 1.40 -1.94 -0.124 0.33052E+04 208 nontronite-Mg 3.07 1.92 -1.15 -0.075 0.19698E+04 209 nontronite-Na 3.52 1.87 -1.65 -0.106 0.28208E+04 214 gypsum -4.96 -9.34 -4.38 -1.095 0.74801E+04 224 tobermorite 9.82 5.58 -4.24 -1.157 0.72393E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.35 -3.46 -0.866 0.59132E+04 240 silica-amorphous -2.09 -3.54 -1.45 -0.484 0.24814E+04 242 an20ab80 2.02 -0.98 -3.00 -0.231 0.51248E+04 243 an25ab75 2.65 -0.32 -2.97 -0.228 0.50658E+04 244 an30ab70 3.28 0.34 -2.94 -0.226 0.50164E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0390000 g New total amount of reactant added: 0.0410000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0410000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2944399E-03 Osmotic coef. = 0.9897 True ionic strength = .3105502E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15748E-07 -7.8028 0.15110E-07 -7.8207 0.95945E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13235E-03 -3.8783 0.95931E+00 -0.0180 4 SO4-- 0.25363E-04 -4.5958 0.22670E-04 -4.6446 0.89381E+00 -0.0488 5 HCO3- 0.12580E-04 -4.9003 0.12068E-04 -4.9184 0.95935E+00 -0.0180 6 HS- 0.98460E-12 -12.0067 0.94454E-12 -12.0248 0.95932E+00 -0.0180 7 Al+++ 0.32478E-20 -20.4884 0.25790E-20 -20.5886 0.79409E+00 -0.1001 8 H4SiO4 0.29677E-03 -3.5276 0.29677E-03 -3.5276 0.10000E+01 0.0000 9 Ca++ 0.21438E-04 -4.6688 0.19158E-04 -4.7176 0.89366E+00 -0.0488 10 Mg++ 0.94067E-07 -7.0266 0.84056E-07 -7.0754 0.89357E+00 -0.0489 11 Fe++ 0.55657E-09 -9.2545 0.49735E-09 -9.3033 0.89359E+00 -0.0489 12 K+ 0.87017E-05 -5.0604 0.83480E-05 -5.0784 0.95935E+00 -0.0180 13 Na+ 0.21146E-03 -3.6748 0.20286E-03 -3.6928 0.95931E+00 -0.0180 14 Mn++ 0.66433E-07 -7.1776 0.59365E-07 -7.2265 0.89361E+00 -0.0489 15 HPO4-- 0.27082E-08 -8.5673 0.24206E-08 -8.6161 0.89381E+00 -0.0488 16 HSiO3- 0.19117E-04 -4.7186 0.18340E-04 -4.7366 0.95931E+00 -0.0180 17 Ca(HSiO3)+ 0.83406E-08 -8.0788 0.80016E-08 -8.0968 0.95936E+00 -0.0180 18 Mg(HSiO3)+ 0.45542E-10 -10.3416 0.43691E-10 -10.3596 0.95936E+00 -0.0180 19 NaHSiO3,aq 0.60172E-07 -7.2206 0.60172E-07 -7.2206 0.10000E+01 0.0000 20 AlO+ 0.16019E-11 -11.7954 0.15368E-11 -11.8134 0.95936E+00 -0.0180 21 AlOH+2 0.12939E-15 -15.8881 0.11562E-15 -15.9369 0.89363E+00 -0.0488 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.30935E-05 -5.5095 0.29675E-05 -5.5276 0.95927E+00 -0.0181 24 CH4,aq 0.48847E-18 -18.3112 0.48843E-18 -18.3112 0.99991E+00 0.0000 29 CO,aq 0.48061E-17 -17.3182 0.48061E-17 -17.3182 0.10000E+01 0.0000 30 CO2,aq 0.38966E-06 -6.4093 0.38962E-06 -6.4094 0.99991E+00 0.0000 31 CO3-2 0.78056E-07 -7.1076 0.69764E-07 -7.1564 0.89377E+00 -0.0488 32 CaCO3,aq 0.16759E-07 -7.7758 0.16759E-07 -7.7758 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61517E-08 -8.2110 0.59016E-08 -8.2290 0.95936E+00 -0.0180 34 CaCl+ 0.42772E-08 -8.3688 0.41033E-08 -8.3869 0.95936E+00 -0.0180 35 CaCl2,aq 0.12902E-12 -12.8893 0.12902E-12 -12.8893 0.10000E+01 0.0000 36 CaOH+ 0.94194E-07 -7.0260 0.90366E-07 -7.0440 0.95936E+00 -0.0180 37 CaSO4,aq 0.13791E-06 -6.8604 0.13791E-06 -6.8604 0.10000E+01 0.0000 38 HCl,aq 0.36644E-12 -12.4360 0.36644E-12 -12.4360 0.10000E+01 0.0000 43 FeCl+ 0.10860E-12 -12.9642 0.10419E-12 -12.9822 0.95936E+00 -0.0180 46 FeO,aq 0.84668E-10 -10.0723 0.84668E-10 -10.0723 0.10000E+01 0.0000 47 FeOH+ 0.11168E-08 -8.9520 0.10715E-08 -8.9700 0.95936E+00 -0.0180 48 HFeO2- 0.61118E-10 -10.2138 0.58631E-10 -10.2319 0.95931E+00 -0.0180 49 FeO+ 0.12022E-12 -12.9200 0.11533E-12 -12.9381 0.95936E+00 -0.0180 50 FeOH+2 0.37239E-18 -18.4290 0.33278E-18 -18.4778 0.89363E+00 -0.0488 51 FeO2- 0.10775E-09 -9.9676 0.10337E-09 -9.9856 0.95931E+00 -0.0180 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.49108E-09 -9.3088 0.49104E-09 -9.3089 0.99991E+00 0.0000 54 KCl,aq 0.20025E-10 -10.6984 0.20025E-10 -10.6984 0.10000E+01 0.0000 55 KHSO4,aq 0.80847E-17 -17.0923 0.80847E-17 -17.0923 0.10000E+01 0.0000 56 KOH,aq 0.23595E-09 -9.6272 0.23595E-09 -9.6272 0.10000E+01 0.0000 57 KSO4- 0.30612E-08 -8.5141 0.29367E-08 -8.5321 0.95931E+00 -0.0180 58 MgCO3,aq 0.18430E-10 -10.7345 0.18430E-10 -10.7345 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27579E-10 -10.5594 0.26458E-10 -10.5774 0.95936E+00 -0.0180 60 MgCl+ 0.17008E-10 -10.7693 0.16317E-10 -10.7874 0.95936E+00 -0.0180 61 MgOH+ 0.22869E-08 -8.6408 0.21939E-08 -8.6588 0.95936E+00 -0.0180 63 MnO,aq 0.26929E-09 -9.5698 0.26929E-09 -9.5698 0.10000E+01 0.0000 64 MnOH+ 0.12384E-07 -7.9071 0.11881E-07 -7.9252 0.95936E+00 -0.0180 65 MnO2-2 0.43799E-16 -16.3585 0.39146E-16 -16.4073 0.89377E+00 -0.0488 66 HMnO2- 0.13508E-12 -12.8694 0.12958E-12 -12.8874 0.95931E+00 -0.0180 69 MnCl+ 0.50432E-10 -10.2973 0.48383E-10 -10.3153 0.95936E+00 -0.0180 70 MnSO4,aq 0.38852E-09 -9.4106 0.38852E-09 -9.4106 0.10000E+01 0.0000 71 NaCl,aq 0.88976E-08 -8.0507 0.88976E-08 -8.0507 0.10000E+01 0.0000 72 NaOH,aq 0.57684E-08 -8.2389 0.57684E-08 -8.2389 0.10000E+01 0.0000 74 OH- 0.39862E-04 -4.3994 0.38239E-04 -4.4175 0.95927E+00 -0.0181 82 H3PO4,aq 0.38650E-14 -14.4129 0.38650E-14 -14.4129 0.10000E+01 0.0000 83 H2PO4- 0.70329E-09 -9.1529 0.67469E-09 -9.1709 0.95933E+00 -0.0180 84 PO4-3 0.16442E-12 -12.7841 0.13071E-12 -12.8837 0.79499E+00 -0.0996 87 H2P2O7-2 0.39935E-19 -19.3986 0.35693E-19 -19.4474 0.89377E+00 -0.0488 88 HP2O7-3 0.59400E-18 -18.2262 0.47169E-18 -18.3263 0.79409E+00 -0.1001 89 P2O7-4 0.11075E-19 -19.9557 0.74579E-20 -20.1274 0.67342E+00 -0.1717 90 H2S,aq 0.44112E-13 -13.3554 0.44108E-13 -13.3555 0.99991E+00 0.0000 96 SO2,aq 0.11350E-19 -19.9450 0.11350E-19 -19.9450 0.10000E+01 0.0000 97 SO3-2 0.16180E-14 -14.7910 0.14466E-14 -14.8397 0.89407E+00 -0.0486 98 HSO3- 0.14266E-14 -14.8457 0.13685E-14 -14.8638 0.95931E+00 -0.0180 99 HSO4- 0.34408E-09 -9.4633 0.33010E-09 -9.4814 0.95938E+00 -0.0180 101 S2O3-2 0.13142E-19 -19.8813 0.11746E-19 -19.9301 0.89377E+00 -0.0488 Charge balance for all species = 0.2239E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1574819E-07 -.7128928E-04 -.7185224E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999554E+06 0.0000 3 Cl- 0.1379628E-03 0.1379761E-03 0.4891455E+01 3.9425 4 SO4-- 0.2536311E-04 0.2550473E-04 0.2449920E+01 10.9969 5 HCO3- 0.1257950E-04 0.1307018E-04 0.7974714E+00 2.9024 6 HS- 0.9846012E-12 0.8548533E-10 0.2827050E-05 -4.2040 7 Al+++ 0.3247751E-20 0.3113761E-05 0.8401034E-01 2.8737 8 H4SiO4 0.2967668E-03 0.3159528E-03 0.3036663E+02 -3.5276 9 Ca++ 0.2143762E-04 0.2170526E-04 0.8698659E+00 10.9238 10 Mg++ 0.9406713E-07 0.9646255E-07 0.2345097E-02 8.5661 11 Fe++ 0.5565691E-09 0.2125824E-08 0.1187158E-03 6.3382 12 K+ 0.8701684E-05 0.8705001E-05 0.3403684E+00 2.7423 13 Na+ 0.2114640E-03 0.2115389E-03 0.4863028E+01 4.1279 14 Mn++ 0.6643289E-07 0.7952538E-07 0.4368778E-02 8.4150 15 HPO4-- 0.2708154E-08 0.3411614E-08 0.3274292E-03 7.0254 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6658591E-03 -.7128831E-04 -.5945708E-03 0.0000000E+00 2 H2O 0.5550774E+02 0.5550752E+02 0.2125633E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2664072E-04 0.2550438E-04 0.1136335E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1136250E-05 0.8548417E-10 -.1136335E-05 0.0000000E+00 7 Al+++ 0.1336904E-03 0.3113719E-05 0.1305767E-03 0.0000000E+00 8 H4SiO4 0.4269241E-03 0.3159485E-03 0.1109756E-03 0.0000000E+00 9 Ca++ 0.6162691E-04 0.2170496E-04 0.3992195E-04 0.0000000E+00 10 Mg++ 0.3253968E-04 0.9646124E-07 0.3244322E-04 0.0000000E+00 11 Fe++ 0.2923335E-04 0.2125795E-08 0.2923123E-04 0.0000000E+00 12 K+ 0.8704883E-05 0.8704883E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2115360E-03 0.2115360E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7108824E-06 0.7952430E-07 0.6313581E-06 0.0000000E+00 15 HPO4-- 0.2426206E-06 0.3411567E-08 0.2392091E-06 0.0000000E+00 Chg. balance for solid moles: -.1694E-20 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0410000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7974E-07 -7.098 0.4005E-04 -4.397 0.1857 0.1273E-04 clinochlore 0.6489E-05 -5.188 0.3607E-02 -2.443 16.72 0.1372E-02 daphnite 0.4028E-05 -5.395 0.2874E-02 -2.541 13.32 0.8709E-03 chlorite-Mn 0.1263E-06 -6.899 0.8952E-04 -4.048 0.4150 0.2853E-04 diaspore 0.3024E-04 -4.519 0.1814E-02 -2.741 8.411 0.5401E-03 hematite 0.4545E-05 -5.342 0.7259E-03 -3.139 3.365 0.1376E-03 lawsonite 0.3952E-04 -4.403 0.1242E-01 -1.906 57.58 0.4005E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3785E+00 0.3785E+00 1.0000 -0.422 chlorite-Mn 0.1186E-01 0.1186E-01 1.0000 -1.926 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.021570 g Volume = 0.006967 cm3 Porosity: 99.3146% V(tot) - V(min): 0.10094E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0410000 g log = -1.3872 Original solution: 1000.0103000 g Original solution / Rock added: 24390.50 (Water/Rock Ratio), log = 4.3872 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.4057E-04 1.0071 0.4169E-04 0.4139E-04 CH4,gas 0.6959E-15 1.0125 0.7189E-15 0.7100E-15 H2,gas 0.6315E-06 1.0005 0.6447E-06 0.6443E-06 H2S,gas 0.1193E-11 0.9960 0.1213E-11 0.1217E-11 S2,gas 0.1301E-30 1.0000 0.1328E-30 0.1328E-30 CO,gas 0.7019E-14 1.0000 0.7162E-14 0.7162E-14 SO3,gas 0.1918E-35 1.0000 0.1957E-35 0.1957E-35 SO2,gas 0.4810E-19 1.0000 0.4908E-19 0.4908E-19 HCl,gas 0.6337E-15 1.0000 0.6466E-15 0.6466E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 98 kaolinite -1.33 -1.31 0.02 0.002 -0.42675E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.74 -6.08 -2.026 0.10380E+05 -4.380 3 CH4,gas 4.54 -12.30 -16.84 -4.211 0.28758E+05 -15.143 4 H2,gas 8.00 0.11 -7.89 -4.508 0.13471E+05 -6.191 5 H2S,gas -6.23 -19.85 -13.62 -6.808 0.23248E+05 -11.916 6 S2,gas -7.34 -39.91 -32.58 -5.012 0.55622E+05 -30.877 7 CO,gas 3.21 -12.63 -15.84 -4.875 0.27053E+05 -14.145 8 SO3,gas 17.12 -20.29 -37.41 -9.352 0.63872E+05 -35.708 9 SO2,gas 0.83 -20.18 -21.01 -5.602 0.35871E+05 -19.309 10 HCl,gas 5.19 -11.70 -16.89 -8.444 0.28836E+05 -15.189 11 acmite 7.71 3.36 -4.35 -0.452 0.74341E+04 15 albite-high 0.69 -3.58 -4.27 -0.329 0.72980E+04 16 albite -0.38 -3.58 -3.20 -0.246 0.54592E+04 19 spessartine 24.46 20.41 -4.05 -0.202 0.69112E+04 20 analcite 3.32 -0.05 -3.38 -0.375 0.57634E+04 21 andalusite 5.00 2.22 -2.78 -0.278 0.47497E+04 22 andradite 39.01 34.75 -4.25 -0.221 0.72632E+04 23 grossular 32.73 27.94 -4.80 -0.240 0.81878E+04 24 anhydrite -5.32 -9.36 -4.05 -2.023 0.69074E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.82 -2.78 -0.927 0.47498E+04 36 brucite 12.57 8.57 -4.00 -0.801 0.68342E+04 37 calcite 0.81 -1.82 -2.63 -0.876 0.44856E+04 40 carpholite-Mg 8.58 7.26 -1.32 -0.088 0.22604E+04 41 carpholite-Fe 6.71 5.03 -1.68 -0.112 0.28724E+04 50 chloritoid-Mg 13.20 10.79 -2.41 -0.161 0.41181E+04 51 chloritoid-Fe 9.17 8.56 -0.62 -0.041 0.10512E+04 52 chloritoid-Mn 11.40 10.63 -0.77 -0.051 0.13083E+04 54 coesite -2.38 -3.53 -1.15 -0.384 0.19662E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.53 -0.97 -0.322 0.16515E+04 67 diopside 16.18 12.43 -3.75 -0.375 0.63972E+04 68 hedenbergite 14.21 10.21 -4.00 -0.400 0.68324E+04 75 epidote 24.67 23.30 -1.37 -0.067 0.23469E+04 76 clinozoisite 22.81 19.89 -2.92 -0.133 0.49858E+04 77 epidote-Fe 29.84 26.70 -3.14 -0.163 0.53546E+04 78 fayalite 14.05 9.15 -4.90 -0.700 0.83615E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.96 -4.18 -0.348 0.71376E+04 91 heulandite -5.83 -8.02 -2.19 -0.100 0.37472E+04 95 jadeite 4.22 -0.05 -4.27 -0.427 0.72889E+04 99 kyanite 4.88 2.22 -2.66 -0.266 0.45356E+04 101 laumontite 2.88 2.56 -0.32 -0.022 0.55068E+03 105 lizardite 23.24 18.64 -4.60 -0.383 0.78558E+04 106 magnesite 0.69 -4.17 -4.86 -1.621 0.83045E+04 107 magnetite 20.09 18.90 -1.18 -0.097 0.20200E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -4.97 -2.48 -0.191 0.42349E+04 120 muscovite 2.58 0.78 -1.80 -0.106 0.30765E+04 121 paragonite 4.24 2.17 -2.07 -0.122 0.35398E+04 122 nepheline 8.34 3.47 -4.87 -0.695 0.83075E+04 136 prehnite 19.37 17.01 -2.36 -0.139 0.40289E+04 137 prehnite-Fe 22.50 20.42 -2.08 -0.125 0.35449E+04 138 pumpellyite-Fe 46.27 43.24 -3.03 -0.067 0.51786E+04 139 pumpellyite-Mg 48.99 45.46 -3.53 -0.078 0.60281E+04 145 pyroxmangite 7.40 4.89 -2.51 -0.502 0.42879E+04 146 pyrophyllite -6.18 -8.36 -2.19 -0.137 0.37345E+04 147 quartz -2.99 -3.53 -0.54 -0.179 0.91888E+03 151 rhodochrosite -0.98 -4.32 -3.35 -1.116 0.57162E+04 152 rhodonite 7.45 4.89 -2.56 -0.512 0.43681E+04 153 sanidine -1.28 -4.97 -3.69 -0.284 0.63027E+04 155 siderite -2.61 -6.40 -3.79 -1.264 0.64761E+04 156 sillimanite 5.26 2.22 -3.04 -0.304 0.51936E+04 163 stilbite -7.52 -8.02 -0.50 -0.024 0.85339E+03 164 stilpnomelane-Fe 13.02 10.59 -2.43 -0.072 0.41463E+04 167 sudoite-Fe 18.30 13.59 -4.71 -0.152 0.80385E+04 168 sudoite 21.08 18.04 -3.03 -0.098 0.51791E+04 171 talc 16.49 11.59 -4.90 -0.288 0.83721E+04 174 tephroite 18.09 13.30 -4.78 -0.683 0.81674E+04 177 topaz-H 4.62 2.22 -2.40 -0.218 0.40957E+04 178 tridymite -2.63 -3.53 -0.90 -0.300 0.15389E+04 187 wairakite 3.95 2.56 -1.39 -0.082 0.23726E+04 188 walstromite 11.51 7.40 -4.11 -0.823 0.70228E+04 189 wollastonite 10.46 7.40 -3.06 -0.613 0.52332E+04 190 pseudo-wollastonite 11.00 7.40 -3.60 -0.721 0.61530E+04 191 zoisite 22.85 19.89 -2.96 -0.135 0.50599E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.45 -2.80 -0.173 0.47852E+04 194 beidellite-H -2.33 -6.25 -3.92 -0.250 0.67006E+04 195 beidellite-K -1.52 -5.35 -3.83 -0.234 0.65316E+04 196 beidellite-Mg -1.79 -4.84 -3.05 -0.189 0.52033E+04 197 beidellite-Na -1.34 -4.89 -3.55 -0.217 0.60548E+04 199 chalcedony -2.80 -3.53 -0.73 -0.242 0.12382E+04 201 montmorillonite-Ca -2.29 -4.68 -2.39 -0.148 0.40831E+04 202 montmorillonite-K -2.24 -5.58 -3.34 -0.205 0.57077E+04 203 montmorillonite-Mg -2.48 -5.07 -2.59 -0.160 0.44244E+04 204 montmorillonite-Na -2.04 -5.12 -3.08 -0.189 0.52666E+04 205 nontronite-Ca 3.21 2.37 -0.84 -0.055 0.14408E+04 206 nontronite-H 2.53 0.57 -1.96 -0.132 0.33542E+04 207 nontronite-K 3.34 1.47 -1.87 -0.120 0.31886E+04 208 nontronite-Mg 3.07 1.98 -1.09 -0.071 0.18662E+04 209 nontronite-Na 3.52 1.93 -1.59 -0.102 0.27135E+04 214 gypsum -4.96 -9.36 -4.41 -1.102 0.75250E+04 224 tobermorite 9.82 5.57 -4.25 -1.160 0.72586E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.34 -3.47 -0.868 0.59308E+04 240 silica-amorphous -2.09 -3.53 -1.44 -0.479 0.24524E+04 242 an20ab80 2.02 -0.94 -2.96 -0.228 0.50532E+04 243 an25ab75 2.65 -0.28 -2.93 -0.225 0.49987E+04 244 an30ab70 3.28 0.38 -2.90 -0.223 0.49537E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0410000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2954665E-03 Osmotic coef. = 0.9897 True ionic strength = .3116430E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15431E-07 -7.8116 0.14805E-07 -7.8296 0.95941E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13234E-03 -3.8783 0.95927E+00 -0.0181 4 SO4-- 0.25361E-04 -4.5958 0.22664E-04 -4.6447 0.89367E+00 -0.0488 5 HCO3- 0.12585E-04 -4.9002 0.12073E-04 -4.9182 0.95931E+00 -0.0180 6 HS- 0.11068E-11 -11.9559 0.10617E-11 -11.9740 0.95928E+00 -0.0181 7 Al+++ 0.30563E-20 -20.5148 0.24261E-20 -20.6151 0.79380E+00 -0.1003 8 H4SiO4 0.28835E-03 -3.5401 0.28835E-03 -3.5401 0.10000E+01 0.0000 9 Ca++ 0.21804E-04 -4.6615 0.19483E-04 -4.7104 0.89352E+00 -0.0489 10 Mg++ 0.91899E-07 -7.0367 0.82105E-07 -7.0856 0.89343E+00 -0.0489 11 Fe++ 0.54370E-09 -9.2646 0.48577E-09 -9.3136 0.89345E+00 -0.0489 12 K+ 0.87017E-05 -5.0604 0.83476E-05 -5.0784 0.95931E+00 -0.0180 13 Na+ 0.21146E-03 -3.6748 0.20285E-03 -3.6928 0.95927E+00 -0.0181 14 Mn++ 0.65042E-07 -7.1868 0.58113E-07 -7.2357 0.89346E+00 -0.0489 15 HPO4-- 0.25632E-08 -8.5912 0.22907E-08 -8.6400 0.89367E+00 -0.0488 16 HSiO3- 0.18958E-04 -4.7222 0.18186E-04 -4.7403 0.95927E+00 -0.0181 17 Ca(HSiO3)+ 0.84113E-08 -8.0751 0.80691E-08 -8.0932 0.95932E+00 -0.0180 18 Mg(HSiO3)+ 0.44115E-10 -10.3554 0.42320E-10 -10.3735 0.95932E+00 -0.0180 19 NaHSiO3,aq 0.59666E-07 -7.2243 0.59666E-07 -7.2243 0.10000E+01 0.0000 20 AlO+ 0.15697E-11 -11.8042 0.15058E-11 -11.8222 0.95932E+00 -0.0180 21 AlOH+2 0.12424E-15 -15.9057 0.11101E-15 -15.9546 0.89348E+00 -0.0489 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.31573E-05 -5.5007 0.30286E-05 -5.5188 0.95923E+00 -0.0181 24 CH4,aq 0.54942E-18 -18.2601 0.54937E-18 -18.2601 0.99991E+00 0.0000 29 CO,aq 0.48758E-17 -17.3120 0.48758E-17 -17.3120 0.10000E+01 0.0000 30 CO2,aq 0.38195E-06 -6.4180 0.38191E-06 -6.4180 0.99991E+00 0.0000 31 CO3-2 0.79706E-07 -7.0985 0.71227E-07 -7.1474 0.89362E+00 -0.0488 32 CaCO3,aq 0.17400E-07 -7.7594 0.17400E-07 -7.7594 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62586E-08 -8.2035 0.60039E-08 -8.2216 0.95932E+00 -0.0180 34 CaCl+ 0.43496E-08 -8.3615 0.41727E-08 -8.3796 0.95932E+00 -0.0180 35 CaCl2,aq 0.13120E-12 -12.8821 0.13120E-12 -12.8821 0.10000E+01 0.0000 36 CaOH+ 0.97766E-07 -7.0098 0.93788E-07 -7.0279 0.95932E+00 -0.0180 37 CaSO4,aq 0.14022E-06 -6.8532 0.14022E-06 -6.8532 0.10000E+01 0.0000 38 HCl,aq 0.35904E-12 -12.4449 0.35904E-12 -12.4449 0.10000E+01 0.0000 43 FeCl+ 0.10607E-12 -12.9744 0.10176E-12 -12.9924 0.95932E+00 -0.0180 46 FeO,aq 0.86137E-10 -10.0648 0.86137E-10 -10.0648 0.10000E+01 0.0000 47 FeOH+ 0.11133E-08 -8.9534 0.10681E-08 -8.9714 0.95932E+00 -0.0180 48 HFeO2- 0.63461E-10 -10.1975 0.60876E-10 -10.2156 0.95927E+00 -0.0181 49 FeO+ 0.11780E-12 -12.9289 0.11300E-12 -12.9469 0.95932E+00 -0.0180 50 FeOH+2 0.35758E-18 -18.4466 0.31949E-18 -18.4955 0.89348E+00 -0.0489 51 FeO2- 0.10997E-09 -9.9587 0.10550E-09 -9.9768 0.95927E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.50827E-09 -9.2939 0.50822E-09 -9.2939 0.99991E+00 0.0000 54 KCl,aq 0.20023E-10 -10.6985 0.20023E-10 -10.6985 0.10000E+01 0.0000 55 KHSO4,aq 0.79194E-17 -17.1013 0.79194E-17 -17.1013 0.10000E+01 0.0000 56 KOH,aq 0.24079E-09 -9.6184 0.24079E-09 -9.6184 0.10000E+01 0.0000 57 KSO4- 0.30604E-08 -8.5142 0.29358E-08 -8.5323 0.95927E+00 -0.0181 58 MgCO3,aq 0.18380E-10 -10.7356 0.18380E-10 -10.7356 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26950E-10 -10.5694 0.25854E-10 -10.5875 0.95932E+00 -0.0180 60 MgCl+ 0.16614E-10 -10.7795 0.15938E-10 -10.7976 0.95932E+00 -0.0180 61 MgOH+ 0.22799E-08 -8.6421 0.21871E-08 -8.6601 0.95932E+00 -0.0180 63 MnO,aq 0.27457E-09 -9.5613 0.27457E-09 -9.5613 0.10000E+01 0.0000 64 MnOH+ 0.12373E-07 -7.9075 0.11869E-07 -7.9256 0.95932E+00 -0.0180 65 MnO2-2 0.46523E-16 -16.3323 0.41574E-16 -16.3812 0.89362E+00 -0.0488 66 HMnO2- 0.14057E-12 -12.8521 0.13484E-12 -12.8702 0.95927E+00 -0.0181 69 MnCl+ 0.49368E-10 -10.3066 0.47360E-10 -10.3246 0.95932E+00 -0.0180 70 MnSO4,aq 0.38023E-09 -9.4200 0.38023E-09 -9.4200 0.10000E+01 0.0000 71 NaCl,aq 0.88969E-08 -8.0508 0.88969E-08 -8.0508 0.10000E+01 0.0000 72 NaOH,aq 0.58869E-08 -8.2301 0.58869E-08 -8.2301 0.10000E+01 0.0000 74 OH- 0.40685E-04 -4.3906 0.39026E-04 -4.4086 0.95923E+00 -0.0181 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.65215E-09 -9.1857 0.62560E-09 -9.2037 0.95930E+00 -0.0180 84 PO4-3 0.15885E-12 -12.7990 0.12624E-12 -12.8988 0.79470E+00 -0.0998 87 H2P2O7-2 0.34341E-19 -19.4642 0.30688E-19 -19.5130 0.89362E+00 -0.0488 88 HP2O7-3 0.52141E-18 -18.2828 0.41389E-18 -18.3831 0.79380E+00 -0.1003 90 H2S,aq 0.48585E-13 -13.3135 0.48581E-13 -13.3135 0.99991E+00 0.0000 96 SO2,aq 0.11275E-19 -19.9479 0.11275E-19 -19.9479 0.10000E+01 0.0000 97 SO3-2 0.16744E-14 -14.7761 0.14968E-14 -14.8248 0.89392E+00 -0.0487 98 HSO3- 0.14464E-14 -14.8397 0.13875E-14 -14.8578 0.95927E+00 -0.0181 99 HSO4- 0.33707E-09 -9.4723 0.32336E-09 -9.4903 0.95934E+00 -0.0180 101 S2O3-2 0.14473E-19 -19.8394 0.12934E-19 -19.8883 0.89362E+00 -0.0488 Charge balance for all species = 0.2235E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1543122E-07 -.7222102E-04 -.7279139E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999562E+06 0.0000 3 Cl- 0.1379627E-03 0.1379760E-03 0.4891458E+01 3.9513 4 SO4-- 0.2536082E-04 0.2550472E-04 0.2449921E+01 11.0145 5 HCO3- 0.1258482E-04 0.1307017E-04 0.7974719E+00 2.9114 6 HS- 0.1106798E-11 0.8963052E-10 0.2964136E-05 -4.1444 7 Al+++ 0.3056313E-20 0.3177558E-05 0.8573168E-01 2.8737 8 H4SiO4 0.2883492E-03 0.3073755E-03 0.2954228E+02 -3.5401 9 Ca++ 0.2180443E-04 0.2207883E-04 0.8848380E+00 10.9488 10 Mg++ 0.9189904E-07 0.9428495E-07 0.2292159E-02 8.5736 11 Fe++ 0.5437039E-09 0.2115490E-08 0.1181388E-03 6.3456 12 K+ 0.8701678E-05 0.8704999E-05 0.3403686E+00 2.7512 13 Na+ 0.2114644E-03 0.2115388E-03 0.4863030E+01 4.1368 14 Mn++ 0.6504191E-07 0.7811907E-07 0.4291525E-02 8.4235 15 HPO4-- 0.2563206E-08 0.3215515E-08 0.3086089E-03 7.0192 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6658591E-03 -.7222005E-04 -.5936391E-03 0.0000000E+00 2 H2O 0.5550774E+02 0.5550754E+02 0.1992009E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2664072E-04 0.2550438E-04 0.1136339E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1136250E-05 0.8962933E-10 -.1136339E-05 0.0000000E+00 7 Al+++ 0.1336904E-03 0.3177516E-05 0.1305129E-03 0.0000000E+00 8 H4SiO4 0.4269241E-03 0.3073714E-03 0.1195527E-03 0.0000000E+00 9 Ca++ 0.6162691E-04 0.2207853E-04 0.3954838E-04 0.0000000E+00 10 Mg++ 0.3253968E-04 0.9428369E-07 0.3244540E-04 0.0000000E+00 11 Fe++ 0.2923335E-04 0.2115462E-08 0.2923124E-04 0.0000000E+00 12 K+ 0.8704883E-05 0.8704883E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2115360E-03 0.2115360E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7108824E-06 0.7811803E-07 0.6327644E-06 0.0000000E+00 15 HPO4-- 0.2426206E-06 0.3215472E-08 0.2394052E-06 0.0000000E+00 Chg. balance for solid moles: -.3134E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0410000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7980E-07 -7.098 0.4009E-04 -4.397 0.1811 0.1274E-04 clinochlore 0.6489E-05 -5.188 0.3607E-02 -2.443 16.29 0.1372E-02 daphnite 0.4028E-05 -5.395 0.2874E-02 -2.541 12.98 0.8709E-03 chlorite-Mn 0.1266E-06 -6.898 0.8972E-04 -4.047 0.4053 0.2859E-04 diaspore 0.2160E-04 -4.665 0.1296E-02 -2.887 5.854 0.3858E-03 hematite 0.4545E-05 -5.342 0.7259E-03 -3.139 3.279 0.1376E-03 lawsonite 0.3915E-04 -4.407 0.1230E-01 -1.910 55.57 0.3967E-02 kaolinite 0.4661E-05 -5.331 0.1203E-02 -2.920 5.436 0.4630E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3784E+00 0.3784E+00 1.0000 -0.422 chlorite-Mn 0.1189E-01 0.1189E-01 1.0000 -1.925 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.022138 g Volume = 0.007238 cm3 Porosity: 99.2879% V(tot) - V(min): 0.10092E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0410000 g log = -1.3872 Original solution: 1000.0103000 g Original solution / Rock added: 24390.50 (Water/Rock Ratio), log = 4.3872 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3976E-04 1.0071 0.4086E-04 0.4057E-04 CH4,gas 0.7827E-15 1.0125 0.8086E-15 0.7986E-15 H2,gas 0.6536E-06 1.0005 0.6672E-06 0.6669E-06 H2S,gas 0.1314E-11 0.9960 0.1335E-11 0.1341E-11 S2,gas 0.1474E-30 1.0000 0.1504E-30 0.1504E-30 CO,gas 0.7121E-14 1.0000 0.7266E-14 0.7266E-14 SO3,gas 0.1841E-35 1.0000 0.1878E-35 0.1878E-35 SO2,gas 0.4779E-19 1.0000 0.4876E-19 0.4876E-19 HCl,gas 0.6209E-15 1.0000 0.6335E-15 0.6335E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.75 -6.09 -2.029 0.10395E+05 -4.389 3 CH4,gas 4.54 -12.25 -16.79 -4.198 0.28671E+05 -15.092 4 H2,gas 8.00 0.13 -7.87 -4.500 0.13446E+05 -6.176 5 H2S,gas -6.23 -19.80 -13.57 -6.787 0.23176E+05 -11.874 6 S2,gas -7.34 -39.86 -32.52 -5.003 0.55530E+05 -30.823 7 CO,gas 3.21 -12.62 -15.84 -4.873 0.27042E+05 -14.139 8 SO3,gas 17.12 -20.30 -37.43 -9.356 0.63903E+05 -35.726 9 SO2,gas 0.83 -20.18 -21.01 -5.603 0.35876E+05 -19.312 10 HCl,gas 5.19 -11.71 -16.90 -8.449 0.28852E+05 -15.198 11 acmite 7.71 3.34 -4.37 -0.454 0.74617E+04 15 albite-high 0.69 -3.61 -4.30 -0.331 0.73470E+04 16 albite -0.38 -3.61 -3.23 -0.248 0.55081E+04 19 spessartine 24.46 20.40 -4.06 -0.203 0.69320E+04 20 analcite 3.32 -0.07 -3.39 -0.377 0.57910E+04 21 andalusite 5.00 2.21 -2.79 -0.279 0.47710E+04 22 andradite 39.01 34.79 -4.22 -0.219 0.71992E+04 23 grossular 32.73 27.97 -4.76 -0.238 0.81237E+04 24 anhydrite -5.32 -9.36 -4.04 -2.019 0.68951E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.80 -2.77 -0.922 0.47220E+04 36 brucite 12.57 8.57 -4.00 -0.799 0.68214E+04 37 calcite 0.81 -1.80 -2.61 -0.870 0.44577E+04 40 carpholite-Mg 8.58 7.24 -1.34 -0.089 0.22902E+04 41 carpholite-Fe 6.71 5.01 -1.70 -0.113 0.29023E+04 50 chloritoid-Mg 13.20 10.78 -2.42 -0.161 0.41267E+04 51 chloritoid-Fe 9.17 8.55 -0.62 -0.041 0.10598E+04 52 chloritoid-Mn 11.40 10.63 -0.77 -0.051 0.13153E+04 54 coesite -2.38 -3.54 -1.16 -0.388 0.19875E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.54 -0.98 -0.327 0.16729E+04 67 diopside 16.18 12.44 -3.74 -0.374 0.63844E+04 68 hedenbergite 14.21 10.21 -3.99 -0.399 0.68196E+04 75 epidote 24.67 23.31 -1.36 -0.066 0.23256E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.72 -3.12 -0.162 0.53333E+04 78 fayalite 14.05 9.15 -4.89 -0.699 0.83573E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.96 -4.18 -0.349 0.71420E+04 91 heulandite -5.83 -8.08 -2.26 -0.103 0.38539E+04 95 jadeite 4.22 -0.07 -4.28 -0.428 0.73165E+04 99 kyanite 4.88 2.21 -2.67 -0.267 0.45569E+04 101 laumontite 2.88 2.54 -0.35 -0.023 0.59335E+03 105 lizardite 23.24 18.64 -4.60 -0.384 0.78600E+04 106 magnesite 0.69 -4.17 -4.86 -1.622 0.83066E+04 107 magnetite 20.09 18.91 -1.18 -0.096 0.20073E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -5.00 -2.51 -0.193 0.42839E+04 120 muscovite 2.58 0.75 -1.83 -0.108 0.31254E+04 121 paragonite 4.24 2.14 -2.10 -0.124 0.35888E+04 122 nepheline 8.34 3.47 -4.87 -0.696 0.83138E+04 136 prehnite 19.37 17.02 -2.35 -0.138 0.40075E+04 137 prehnite-Fe 22.50 20.43 -2.06 -0.124 0.35236E+04 138 pumpellyite-Fe 46.27 43.27 -3.00 -0.067 0.51232E+04 139 pumpellyite-Mg 48.99 45.50 -3.50 -0.078 0.59727E+04 145 pyroxmangite 7.40 4.88 -2.52 -0.503 0.42948E+04 146 pyrophyllite -6.18 -8.41 -2.24 -0.140 0.38198E+04 147 quartz -2.99 -3.54 -0.55 -0.184 0.94021E+03 151 rhodochrosite -0.98 -4.32 -3.35 -1.116 0.57166E+04 152 rhodonite 7.45 4.88 -2.56 -0.512 0.43751E+04 153 sanidine -1.28 -5.00 -3.72 -0.286 0.63516E+04 155 siderite -2.61 -6.40 -3.79 -1.265 0.64782E+04 156 sillimanite 5.26 2.21 -3.05 -0.305 0.52150E+04 163 stilbite -7.52 -8.08 -0.56 -0.027 0.96008E+03 164 stilpnomelane-Fe 13.02 10.53 -2.49 -0.074 0.42457E+04 167 sudoite-Fe 18.30 13.57 -4.73 -0.153 0.80770E+04 168 sudoite 21.08 18.02 -3.06 -0.099 0.52175E+04 171 talc 16.49 11.56 -4.93 -0.290 0.84191E+04 174 tephroite 18.09 13.31 -4.78 -0.683 0.81599E+04 177 topaz-H 4.62 2.21 -2.41 -0.219 0.41170E+04 178 tridymite -2.63 -3.54 -0.91 -0.305 0.15602E+04 187 wairakite 3.95 2.54 -1.41 -0.083 0.24153E+04 188 walstromite 11.51 7.41 -4.10 -0.820 0.70014E+04 189 wollastonite 10.46 7.41 -3.05 -0.610 0.52119E+04 190 pseudo-wollastonite 11.00 7.41 -3.59 -0.718 0.61317E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.49 -2.84 -0.176 0.48564E+04 194 beidellite-H -2.33 -6.30 -3.97 -0.253 0.67789E+04 195 beidellite-K -1.52 -5.39 -3.87 -0.237 0.66050E+04 196 beidellite-Mg -1.79 -4.88 -3.09 -0.191 0.52794E+04 197 beidellite-Na -1.34 -4.93 -3.59 -0.220 0.61281E+04 199 chalcedony -2.80 -3.54 -0.74 -0.246 0.12595E+04 201 montmorillonite-Ca -2.29 -4.73 -2.43 -0.151 0.41572E+04 202 montmorillonite-K -2.24 -5.62 -3.39 -0.207 0.57839E+04 203 montmorillonite-Mg -2.48 -5.12 -2.64 -0.163 0.45034E+04 204 montmorillonite-Na -2.04 -5.17 -3.13 -0.192 0.53428E+04 205 nontronite-Ca 3.21 2.33 -0.89 -0.057 0.15121E+04 206 nontronite-H 2.53 0.52 -2.01 -0.135 0.34325E+04 207 nontronite-K 3.34 1.43 -1.91 -0.123 0.32620E+04 208 nontronite-Mg 3.07 1.94 -1.14 -0.074 0.19424E+04 209 nontronite-Na 3.52 1.89 -1.63 -0.105 0.27869E+04 214 gypsum -4.96 -9.36 -4.40 -1.100 0.75127E+04 224 tobermorite 9.82 5.58 -4.24 -1.158 0.72444E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.35 -3.47 -0.866 0.59180E+04 240 silica-amorphous -2.09 -3.54 -1.45 -0.483 0.24737E+04 242 an20ab80 2.02 -0.96 -2.98 -0.229 0.50923E+04 243 an25ab75 2.65 -0.30 -2.95 -0.227 0.50354E+04 244 an30ab70 3.28 0.36 -2.92 -0.225 0.49880E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0410000 g New total amount of reactant added: 0.0430000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0430000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2955234E-03 Osmotic coef. = 0.9897 True ionic strength = .3120690E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15134E-07 -7.8200 0.14519E-07 -7.8381 0.95939E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13234E-03 -3.8783 0.95926E+00 -0.0181 4 SO4-- 0.25366E-04 -4.5957 0.22667E-04 -4.6446 0.89361E+00 -0.0489 5 HCO3- 0.12591E-04 -4.8999 0.12078E-04 -4.9180 0.95929E+00 -0.0180 6 HS- 0.10835E-11 -11.9652 0.10394E-11 -11.9832 0.95926E+00 -0.0181 7 Al+++ 0.28833E-20 -20.5401 0.22884E-20 -20.6405 0.79368E+00 -0.1004 8 H4SiO4 0.28835E-03 -3.5401 0.28835E-03 -3.5401 0.10000E+01 0.0000 9 Ca++ 0.20973E-04 -4.6783 0.18739E-04 -4.7273 0.89346E+00 -0.0489 10 Mg++ 0.88393E-07 -7.0536 0.78968E-07 -7.1025 0.89337E+00 -0.0490 11 Fe++ 0.52284E-09 -9.2816 0.46710E-09 -9.3306 0.89339E+00 -0.0490 12 K+ 0.91261E-05 -5.0397 0.87547E-05 -5.0578 0.95930E+00 -0.0180 13 Na+ 0.21397E-03 -3.6696 0.20525E-03 -3.6877 0.95926E+00 -0.0181 14 Mn++ 0.63101E-07 -7.2000 0.56375E-07 -7.2489 0.89341E+00 -0.0489 15 HPO4-- 0.26652E-08 -8.5743 0.23816E-08 -8.6231 0.89361E+00 -0.0488 16 HSiO3- 0.19331E-04 -4.7137 0.18544E-04 -4.7318 0.95926E+00 -0.0181 17 Ca(HSiO3)+ 0.82492E-08 -8.0836 0.79135E-08 -8.1016 0.95930E+00 -0.0180 18 Mg(HSiO3)+ 0.43264E-10 -10.3639 0.41503E-10 -10.3819 0.95930E+00 -0.0180 19 NaHSiO3,aq 0.61560E-07 -7.2107 0.61560E-07 -7.2107 0.10000E+01 0.0000 20 AlO+ 0.15394E-11 -11.8126 0.14768E-11 -11.8307 0.95930E+00 -0.0180 21 AlOH+2 0.11950E-15 -15.9226 0.10677E-15 -15.9716 0.89343E+00 -0.0489 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.32194E-05 -5.4922 0.30881E-05 -5.5103 0.95922E+00 -0.0181 24 CH4,aq 0.53802E-18 -18.2692 0.53797E-18 -18.2692 0.99991E+00 0.0000 29 CO,aq 0.47817E-17 -17.3204 0.47817E-17 -17.3204 0.10000E+01 0.0000 30 CO2,aq 0.37476E-06 -6.4262 0.37473E-06 -6.4263 0.99991E+00 0.0000 31 CO3-2 0.81316E-07 -7.0898 0.72662E-07 -7.1387 0.89357E+00 -0.0489 32 CaCO3,aq 0.17073E-07 -7.7677 0.17073E-07 -7.7677 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60225E-08 -8.2202 0.57774E-08 -8.2383 0.95930E+00 -0.0180 34 CaCl+ 0.41835E-08 -8.3785 0.40133E-08 -8.3965 0.95930E+00 -0.0180 35 CaCl2,aq 0.12618E-12 -12.8990 0.12618E-12 -12.8990 0.10000E+01 0.0000 36 CaOH+ 0.95882E-07 -7.0183 0.91980E-07 -7.0363 0.95930E+00 -0.0180 37 CaSO4,aq 0.13488E-06 -6.8701 0.13488E-06 -6.8701 0.10000E+01 0.0000 38 HCl,aq 0.35211E-12 -12.4533 0.35211E-12 -12.4533 0.10000E+01 0.0000 43 FeCl+ 0.10200E-12 -12.9914 0.97847E-13 -13.0095 0.95930E+00 -0.0180 46 FeO,aq 0.86116E-10 -10.0649 0.86116E-10 -10.0649 0.10000E+01 0.0000 47 FeOH+ 0.10916E-08 -8.9619 0.10472E-08 -8.9800 0.95930E+00 -0.0180 48 HFeO2- 0.64693E-10 -10.1891 0.62058E-10 -10.2072 0.95926E+00 -0.0181 49 FeO+ 0.11553E-12 -12.9373 0.11082E-12 -12.9554 0.95930E+00 -0.0180 50 FeOH+2 0.34395E-18 -18.4635 0.30729E-18 -18.5124 0.89343E+00 -0.0489 51 FeO2- 0.11214E-09 -9.9502 0.10757E-09 -9.9683 0.95926E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.50801E-09 -9.2941 0.50797E-09 -9.2942 0.99991E+00 0.0000 54 KCl,aq 0.20999E-10 -10.6778 0.20999E-10 -10.6778 0.10000E+01 0.0000 55 KHSO4,aq 0.81466E-17 -17.0890 0.81466E-17 -17.0890 0.10000E+01 0.0000 56 KOH,aq 0.25750E-09 -9.5892 0.25750E-09 -9.5892 0.10000E+01 0.0000 57 KSO4- 0.32102E-08 -8.4935 0.30794E-08 -8.5115 0.95926E+00 -0.0181 58 MgCO3,aq 0.18034E-10 -10.7439 0.18034E-10 -10.7439 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25933E-10 -10.5861 0.24878E-10 -10.6042 0.95930E+00 -0.0180 60 MgCl+ 0.15979E-10 -10.7965 0.15329E-10 -10.8145 0.95930E+00 -0.0180 61 MgOH+ 0.22359E-08 -8.6505 0.21449E-08 -8.6686 0.95930E+00 -0.0180 63 MnO,aq 0.27694E-09 -9.5576 0.27694E-09 -9.5576 0.10000E+01 0.0000 64 MnOH+ 0.12239E-07 -7.9122 0.11741E-07 -7.9303 0.95930E+00 -0.0180 65 MnO2-2 0.48790E-16 -16.3117 0.43598E-16 -16.3605 0.89357E+00 -0.0489 66 HMnO2- 0.14457E-12 -12.8399 0.13868E-12 -12.8580 0.95926E+00 -0.0181 69 MnCl+ 0.47892E-10 -10.3197 0.45943E-10 -10.3378 0.95930E+00 -0.0180 70 MnSO4,aq 0.36891E-09 -9.4331 0.36891E-09 -9.4331 0.10000E+01 0.0000 71 NaCl,aq 0.90022E-08 -8.0457 0.90022E-08 -8.0457 0.10000E+01 0.0000 72 NaOH,aq 0.60738E-08 -8.2165 0.60738E-08 -8.2165 0.10000E+01 0.0000 74 OH- 0.41485E-04 -4.3821 0.39793E-04 -4.4002 0.95922E+00 -0.0181 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.66498E-09 -9.1772 0.63790E-09 -9.1952 0.95928E+00 -0.0181 84 PO4-3 0.16843E-12 -12.7736 0.13383E-12 -12.8734 0.79459E+00 -0.0999 87 H2P2O7-2 0.35707E-19 -19.4472 0.31907E-19 -19.4961 0.89357E+00 -0.0489 88 HP2O7-3 0.55285E-18 -18.2574 0.43879E-18 -18.3577 0.79369E+00 -0.1003 89 P2O7-4 0.10731E-19 -19.9694 0.72197E-20 -20.1415 0.67282E+00 -0.1721 90 H2S,aq 0.46644E-13 -13.3312 0.46640E-13 -13.3312 0.99991E+00 0.0000 96 SO2,aq 0.10840E-19 -19.9650 0.10840E-19 -19.9650 0.10000E+01 0.0000 97 SO3-2 0.16739E-14 -14.7763 0.14963E-14 -14.8250 0.89387E+00 -0.0487 98 HSO3- 0.14180E-14 -14.8483 0.13603E-14 -14.8664 0.95926E+00 -0.0181 99 HSO4- 0.33062E-09 -9.4807 0.31717E-09 -9.4987 0.95932E+00 -0.0180 101 S2O3-2 0.13898E-19 -19.8570 0.12419E-19 -19.9059 0.89357E+00 -0.0489 Charge balance for all species = 0.2240E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1513390E-07 -.7365182E-04 -.7423349E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999561E+06 0.0000 3 Cl- 0.1379628E-03 0.1379761E-03 0.4891459E+01 3.9598 4 SO4-- 0.2536603E-04 0.2550473E-04 0.2449922E+01 11.0315 5 HCO3- 0.1259096E-04 0.1307018E-04 0.7974720E+00 2.9201 6 HS- 0.1083490E-11 0.8927246E-10 0.2952294E-05 -4.1452 7 Al+++ 0.2883306E-20 0.3239688E-05 0.8740796E-01 2.8737 8 H4SiO4 0.2883492E-03 0.3077503E-03 0.2957830E+02 -3.5401 9 Ca++ 0.2097296E-04 0.2123925E-04 0.8511906E+00 10.9488 10 Mg++ 0.8839331E-07 0.9073241E-07 0.2205793E-02 8.5736 11 Fe++ 0.5228421E-09 0.2076278E-08 0.1159490E-03 6.3455 12 K+ 0.9126147E-05 0.9129636E-05 0.3569720E+00 2.7803 13 Na+ 0.2139728E-03 0.2140494E-03 0.4920745E+01 4.1503 14 Mn++ 0.6310134E-07 0.7603437E-07 0.4177000E-02 8.4272 15 HPO4-- 0.2665159E-08 0.3330311E-08 0.3196264E-03 7.0530 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6989762E-03 -.7365082E-04 -.6253253E-03 0.0000000E+00 2 H2O 0.5550771E+02 0.5550752E+02 0.1884043E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2669615E-04 0.2550438E-04 0.1191766E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1191677E-05 0.8927124E-10 -.1191766E-05 0.0000000E+00 7 Al+++ 0.1402119E-03 0.3239644E-05 0.1369722E-03 0.0000000E+00 8 H4SiO4 0.4477497E-03 0.3077461E-03 0.1400035E-03 0.0000000E+00 9 Ca++ 0.6392719E-04 0.2123896E-04 0.4268824E-04 0.0000000E+00 10 Mg++ 0.3412698E-04 0.9073117E-07 0.3403625E-04 0.0000000E+00 11 Fe++ 0.3065937E-04 0.2076250E-08 0.3065729E-04 0.0000000E+00 12 K+ 0.9129512E-05 0.9129512E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2140465E-03 0.2140465E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7455596E-06 0.7603334E-07 0.6695263E-06 0.0000000E+00 15 HPO4-- 0.2544558E-06 0.3330265E-08 0.2511255E-06 0.0000000E+00 Chg. balance for solid moles: 0.1620E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0430000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8371E-07 -7.077 0.4205E-04 -4.376 0.1730 0.1336E-04 clinochlore 0.6807E-05 -5.167 0.3784E-02 -2.422 15.57 0.1439E-02 daphnite 0.4225E-05 -5.374 0.3014E-02 -2.521 12.40 0.9134E-03 chlorite-Mn 0.1339E-06 -6.873 0.9493E-04 -4.023 0.3906 0.3025E-04 diaspore 0.8135E-05 -5.090 0.4880E-03 -3.312 2.008 0.1453E-03 hematite 0.4767E-05 -5.322 0.7613E-03 -3.118 3.133 0.1443E-03 kaolinite 0.1098E-04 -4.959 0.2835E-02 -2.547 11.67 0.1091E-02 lawsonite 0.4227E-04 -4.374 0.1328E-01 -1.877 54.66 0.4283E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3784E+00 0.3784E+00 1.0000 -0.422 chlorite-Mn 0.1199E-01 0.1199E-01 1.0000 -1.921 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.024303 g Volume = 0.008060 cm3 Porosity: 99.2076% V(tot) - V(min): 0.10091E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0430000 g log = -1.3665 Original solution: 1000.0103000 g Original solution / Rock added: 23256.05 (Water/Rock Ratio), log = 4.3665 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3902E-04 1.0071 0.4009E-04 0.3981E-04 CH4,gas 0.7665E-15 1.0125 0.7919E-15 0.7821E-15 H2,gas 0.6533E-06 1.0005 0.6669E-06 0.6665E-06 H2S,gas 0.1262E-11 0.9960 0.1282E-11 0.1287E-11 S2,gas 0.1360E-30 1.0000 0.1387E-30 0.1387E-30 CO,gas 0.6984E-14 1.0000 0.7126E-14 0.7126E-14 SO3,gas 0.1771E-35 1.0000 0.1807E-35 0.1807E-35 SO2,gas 0.4594E-19 1.0000 0.4688E-19 0.4688E-19 HCl,gas 0.6089E-15 1.0000 0.6213E-15 0.6213E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 65 diaspore 2.87 2.87 0.00 0.000 -0.30331E-11 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.76 -6.10 -2.032 0.10409E+05 -4.397 3 CH4,gas 4.54 -12.26 -16.80 -4.200 0.28686E+05 -15.101 4 H2,gas 8.00 0.12 -7.87 -4.500 0.13446E+05 -6.176 5 H2S,gas -6.23 -19.82 -13.59 -6.796 0.23206E+05 -11.892 6 S2,gas -7.34 -39.89 -32.56 -5.009 0.55590E+05 -30.858 7 CO,gas 3.21 -12.63 -15.85 -4.876 0.27057E+05 -14.147 8 SO3,gas 17.12 -20.32 -37.44 -9.361 0.63931E+05 -35.743 9 SO2,gas 0.83 -20.20 -21.03 -5.607 0.35905E+05 -19.329 10 HCl,gas 5.19 -11.72 -16.91 -8.453 0.28866E+05 -15.207 11 acmite 7.71 3.35 -4.36 -0.453 0.74385E+04 15 albite-high 0.69 -3.60 -4.29 -0.330 0.73238E+04 16 albite -0.38 -3.60 -3.21 -0.247 0.54850E+04 19 spessartine 24.46 20.41 -4.05 -0.202 0.69129E+04 20 analcite 3.32 -0.06 -3.38 -0.375 0.57678E+04 21 andalusite 5.00 2.21 -2.79 -0.279 0.47710E+04 22 andradite 39.01 34.79 -4.22 -0.219 0.71992E+04 23 grossular 32.73 27.97 -4.76 -0.238 0.81237E+04 24 anhydrite -5.32 -9.37 -4.06 -2.028 0.69239E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.81 -2.77 -0.925 0.47361E+04 36 brucite 12.57 8.57 -4.00 -0.799 0.68214E+04 37 calcite 0.81 -1.81 -2.62 -0.873 0.44718E+04 40 carpholite-Mg 8.58 7.24 -1.34 -0.089 0.22902E+04 41 carpholite-Fe 6.71 5.01 -1.70 -0.113 0.29025E+04 50 chloritoid-Mg 13.20 10.78 -2.42 -0.161 0.41267E+04 51 chloritoid-Fe 9.17 8.55 -0.62 -0.041 0.10600E+04 52 chloritoid-Mn 11.40 10.63 -0.77 -0.051 0.13089E+04 54 coesite -2.38 -3.54 -1.16 -0.388 0.19875E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.54 -0.98 -0.327 0.16729E+04 67 diopside 16.18 12.44 -3.74 -0.374 0.63845E+04 68 hedenbergite 14.21 10.21 -3.99 -0.399 0.68198E+04 75 epidote 24.67 23.31 -1.36 -0.066 0.23256E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.72 -3.12 -0.162 0.53333E+04 78 fayalite 14.05 9.15 -4.89 -0.699 0.83577E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.96 -4.18 -0.349 0.71426E+04 91 heulandite -5.83 -8.08 -2.26 -0.103 0.38539E+04 95 jadeite 4.22 -0.06 -4.27 -0.427 0.72933E+04 99 kyanite 4.88 2.21 -2.67 -0.267 0.45569E+04 101 laumontite 2.88 2.54 -0.35 -0.023 0.59335E+03 105 lizardite 23.24 18.64 -4.60 -0.384 0.78601E+04 106 magnesite 0.69 -4.18 -4.87 -1.624 0.83207E+04 107 magnetite 20.09 18.91 -1.18 -0.096 0.20075E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -4.97 -2.48 -0.191 0.42341E+04 120 muscovite 2.58 0.78 -1.80 -0.106 0.30757E+04 121 paragonite 4.24 2.15 -2.09 -0.123 0.35656E+04 122 nepheline 8.34 3.48 -4.86 -0.694 0.82906E+04 136 prehnite 19.37 17.02 -2.35 -0.138 0.40075E+04 137 prehnite-Fe 22.50 20.43 -2.06 -0.124 0.35236E+04 138 pumpellyite-Fe 46.27 43.27 -3.00 -0.067 0.51234E+04 139 pumpellyite-Mg 48.99 45.50 -3.50 -0.078 0.59727E+04 145 pyroxmangite 7.40 4.89 -2.51 -0.502 0.42884E+04 146 pyrophyllite -6.18 -8.41 -2.24 -0.140 0.38198E+04 147 quartz -2.99 -3.54 -0.55 -0.184 0.94021E+03 151 rhodochrosite -0.98 -4.33 -3.35 -1.118 0.57244E+04 152 rhodonite 7.45 4.89 -2.56 -0.512 0.43687E+04 153 sanidine -1.28 -4.97 -3.69 -0.284 0.63019E+04 155 siderite -2.61 -6.41 -3.80 -1.267 0.64925E+04 156 sillimanite 5.26 2.21 -3.05 -0.305 0.52150E+04 163 stilbite -7.52 -8.08 -0.56 -0.027 0.96008E+03 164 stilpnomelane-Fe 13.02 10.54 -2.47 -0.074 0.42217E+04 167 sudoite-Fe 18.30 13.57 -4.73 -0.153 0.80774E+04 168 sudoite 21.08 18.02 -3.06 -0.099 0.52175E+04 171 talc 16.49 11.56 -4.93 -0.290 0.84191E+04 174 tephroite 18.09 13.31 -4.77 -0.682 0.81472E+04 177 topaz-H 4.62 2.21 -2.41 -0.219 0.41170E+04 178 tridymite -2.63 -3.54 -0.91 -0.305 0.15602E+04 187 wairakite 3.95 2.54 -1.41 -0.083 0.24153E+04 188 walstromite 11.51 7.41 -4.10 -0.820 0.70014E+04 189 wollastonite 10.46 7.41 -3.05 -0.610 0.52119E+04 190 pseudo-wollastonite 11.00 7.41 -3.59 -0.718 0.61317E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.49 -2.84 -0.176 0.48564E+04 194 beidellite-H -2.33 -6.30 -3.97 -0.253 0.67789E+04 195 beidellite-K -1.52 -5.38 -3.86 -0.236 0.65886E+04 196 beidellite-Mg -1.79 -4.88 -3.09 -0.191 0.52795E+04 197 beidellite-Na -1.34 -4.93 -3.58 -0.220 0.61205E+04 199 chalcedony -2.80 -3.54 -0.74 -0.246 0.12595E+04 201 montmorillonite-Ca -2.29 -4.73 -2.43 -0.151 0.41572E+04 202 montmorillonite-K -2.24 -5.61 -3.38 -0.207 0.57674E+04 203 montmorillonite-Mg -2.48 -5.12 -2.64 -0.163 0.45034E+04 204 montmorillonite-Na -2.04 -5.16 -3.12 -0.191 0.53351E+04 205 nontronite-Ca 3.21 2.33 -0.89 -0.057 0.15121E+04 206 nontronite-H 2.53 0.52 -2.01 -0.135 0.34325E+04 207 nontronite-K 3.34 1.44 -1.90 -0.122 0.32456E+04 208 nontronite-Mg 3.07 1.94 -1.14 -0.074 0.19424E+04 209 nontronite-Na 3.52 1.89 -1.63 -0.104 0.27792E+04 214 gypsum -4.96 -9.37 -4.42 -1.104 0.75415E+04 224 tobermorite 9.82 5.58 -4.24 -1.158 0.72444E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.35 -3.47 -0.867 0.59182E+04 240 silica-amorphous -2.09 -3.54 -1.45 -0.483 0.24737E+04 242 an20ab80 2.02 -0.95 -2.97 -0.229 0.50738E+04 243 an25ab75 2.65 -0.29 -2.94 -0.226 0.50180E+04 244 an30ab70 3.28 0.37 -2.91 -0.224 0.49718E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0430000 g New total amount of reactant added: 0.0450000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0450000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2956322E-03 Osmotic coef. = 0.9897 True ionic strength = .3125579E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14838E-07 -7.8286 0.14236E-07 -7.8466 0.95938E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13234E-03 -3.8783 0.95924E+00 -0.0181 4 SO4-- 0.25371E-04 -4.5957 0.22670E-04 -4.6445 0.89355E+00 -0.0489 5 HCO3- 0.12597E-04 -4.8997 0.12084E-04 -4.9178 0.95927E+00 -0.0181 6 HS- 0.10606E-11 -11.9745 0.10173E-11 -11.9925 0.95925E+00 -0.0181 7 Al+++ 0.27179E-20 -20.5658 0.21568E-20 -20.6662 0.79355E+00 -0.1004 8 H4SiO4 0.28835E-03 -3.5401 0.28835E-03 -3.5401 0.10000E+01 0.0000 9 Ca++ 0.20162E-04 -4.6955 0.18013E-04 -4.7444 0.89340E+00 -0.0490 10 Mg++ 0.84976E-07 -7.0707 0.75909E-07 -7.1197 0.89330E+00 -0.0490 11 Fe++ 0.50252E-09 -9.2988 0.44892E-09 -9.3478 0.89333E+00 -0.0490 12 K+ 0.95506E-05 -5.0200 0.91617E-05 -5.0380 0.95928E+00 -0.0181 13 Na+ 0.21648E-03 -3.6646 0.20766E-03 -3.6827 0.95924E+00 -0.0181 14 Mn++ 0.61138E-07 -7.2137 0.54617E-07 -7.2627 0.89334E+00 -0.0490 15 HPO4-- 0.27727E-08 -8.5571 0.24775E-08 -8.6060 0.89355E+00 -0.0489 16 HSiO3- 0.19717E-04 -4.7052 0.18913E-04 -4.7232 0.95924E+00 -0.0181 17 Ca(HSiO3)+ 0.80881E-08 -8.0922 0.77588E-08 -8.1102 0.95928E+00 -0.0181 18 Mg(HSiO3)+ 0.42418E-10 -10.3724 0.40691E-10 -10.3905 0.95928E+00 -0.0181 19 NaHSiO3,aq 0.63522E-07 -7.1971 0.63522E-07 -7.1971 0.10000E+01 0.0000 20 AlO+ 0.15094E-11 -11.8212 0.14479E-11 -11.8393 0.95928E+00 -0.0181 21 AlOH+2 0.11489E-15 -15.9397 0.10263E-15 -15.9887 0.89336E+00 -0.0490 22 HAlO2,aq 0.20256E-07 -7.6935 0.20256E-07 -7.6935 0.10000E+01 0.0000 23 AlO2- 0.32837E-05 -5.4836 0.31497E-05 -5.5017 0.95920E+00 -0.0181 24 CH4,aq 0.52681E-18 -18.2784 0.52676E-18 -18.2784 0.99991E+00 0.0000 29 CO,aq 0.46883E-17 -17.3290 0.46883E-17 -17.3290 0.10000E+01 0.0000 30 CO2,aq 0.36760E-06 -6.4346 0.36757E-06 -6.4347 0.99991E+00 0.0000 31 CO3-2 0.82982E-07 -7.0810 0.74145E-07 -7.1299 0.89350E+00 -0.0489 32 CaCO3,aq 0.16747E-07 -7.7761 0.16747E-07 -7.7761 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57921E-08 -8.2372 0.55562E-08 -8.2552 0.95928E+00 -0.0181 34 CaCl+ 0.40216E-08 -8.3956 0.38578E-08 -8.4137 0.95928E+00 -0.0181 35 CaCl2,aq 0.12129E-12 -12.9162 0.12129E-12 -12.9162 0.10000E+01 0.0000 36 CaOH+ 0.94009E-07 -7.0268 0.90182E-07 -7.0449 0.95928E+00 -0.0181 37 CaSO4,aq 0.12967E-06 -6.8871 0.12967E-06 -6.8871 0.10000E+01 0.0000 38 HCl,aq 0.34522E-12 -12.4619 0.34522E-12 -12.4619 0.10000E+01 0.0000 43 FeCl+ 0.98027E-13 -13.0087 0.94036E-13 -13.0267 0.95928E+00 -0.0181 46 FeO,aq 0.86096E-10 -10.0650 0.86096E-10 -10.0650 0.10000E+01 0.0000 47 FeOH+ 0.10701E-08 -8.9706 0.10265E-08 -8.9886 0.95928E+00 -0.0181 48 HFeO2- 0.65970E-10 -10.1807 0.63281E-10 -10.1987 0.95924E+00 -0.0181 49 FeO+ 0.11327E-12 -12.9459 0.10866E-12 -12.9639 0.95928E+00 -0.0181 50 FeOH+2 0.33065E-18 -18.4806 0.29539E-18 -18.5296 0.89336E+00 -0.0490 51 FeO2- 0.11438E-09 -9.9417 0.10971E-09 -9.9597 0.95924E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.50779E-09 -9.2943 0.50774E-09 -9.2944 0.99991E+00 0.0000 54 KCl,aq 0.21975E-10 -10.6581 0.21975E-10 -10.6581 0.10000E+01 0.0000 55 KHSO4,aq 0.83597E-17 -17.0778 0.83597E-17 -17.0778 0.10000E+01 0.0000 56 KOH,aq 0.27485E-09 -9.5609 0.27485E-09 -9.5609 0.10000E+01 0.0000 57 KSO4- 0.33599E-08 -8.4737 0.32230E-08 -8.4917 0.95924E+00 -0.0181 58 MgCO3,aq 0.17689E-10 -10.7523 0.17689E-10 -10.7523 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24941E-10 -10.6031 0.23925E-10 -10.6211 0.95928E+00 -0.0181 60 MgCl+ 0.15360E-10 -10.8136 0.14735E-10 -10.8317 0.95928E+00 -0.0181 61 MgOH+ 0.21922E-08 -8.6591 0.21029E-08 -8.6772 0.95928E+00 -0.0181 63 MnO,aq 0.27911E-09 -9.5542 0.27911E-09 -9.5542 0.10000E+01 0.0000 64 MnOH+ 0.12094E-07 -7.9174 0.11602E-07 -7.9355 0.95928E+00 -0.0181 65 MnO2-2 0.51157E-16 -16.2911 0.45709E-16 -16.3400 0.89350E+00 -0.0489 66 HMnO2- 0.14861E-12 -12.8279 0.14256E-12 -12.8460 0.95924E+00 -0.0181 69 MnCl+ 0.46399E-10 -10.3335 0.44510E-10 -10.3515 0.95928E+00 -0.0181 70 MnSO4,aq 0.35746E-09 -9.4468 0.35746E-09 -9.4468 0.10000E+01 0.0000 71 NaCl,aq 0.91074E-08 -8.0406 0.91074E-08 -8.0406 0.10000E+01 0.0000 72 NaOH,aq 0.62674E-08 -8.2029 0.62674E-08 -8.2029 0.10000E+01 0.0000 74 OH- 0.42313E-04 -4.3735 0.40587E-04 -4.3916 0.95920E+00 -0.0181 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.67825E-09 -9.1686 0.65062E-09 -9.1867 0.95926E+00 -0.0181 84 PO4-3 0.17873E-12 -12.7478 0.14200E-12 -12.8477 0.79446E+00 -0.0999 87 H2P2O7-2 0.37148E-19 -19.4301 0.33192E-19 -19.4790 0.89350E+00 -0.0489 88 HP2O7-3 0.58668E-18 -18.2316 0.46557E-18 -18.3320 0.79356E+00 -0.1004 89 P2O7-4 0.11616E-19 -19.9350 0.78130E-20 -20.1072 0.67262E+00 -0.1722 90 H2S,aq 0.44764E-13 -13.3491 0.44760E-13 -13.3491 0.99991E+00 0.0000 96 SO2,aq 0.10417E-19 -19.9822 0.10417E-19 -19.9822 0.10000E+01 0.0000 97 SO3-2 0.16735E-14 -14.7764 0.14958E-14 -14.8251 0.89380E+00 -0.0488 98 HSO3- 0.13899E-14 -14.8570 0.13332E-14 -14.8751 0.95924E+00 -0.0181 99 HSO4- 0.32421E-09 -9.4892 0.31101E-09 -9.5072 0.95931E+00 -0.0180 101 S2O3-2 0.13340E-19 -19.8748 0.11920E-19 -19.9237 0.89350E+00 -0.0489 Charge balance for all species = 0.2240E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1483832E-07 -.7513129E-04 -.7572464E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999561E+06 0.0000 3 Cl- 0.1379629E-03 0.1379761E-03 0.4891460E+01 3.9683 4 SO4-- 0.2537111E-04 0.2550474E-04 0.2449922E+01 11.0487 5 HCO3- 0.1259701E-04 0.1307018E-04 0.7974722E+00 2.9288 6 HS- 0.1060567E-11 0.8891143E-10 0.2940355E-05 -4.1459 7 Al+++ 0.2717936E-20 0.3303939E-05 0.8914147E-01 2.8737 8 H4SiO4 0.2883492E-03 0.3081379E-03 0.2961555E+02 -3.5401 9 Ca++ 0.2016243E-04 0.2042076E-04 0.8183888E+00 10.9488 10 Mg++ 0.8497594E-07 0.8726853E-07 0.2121583E-02 8.5735 11 Fe++ 0.5025240E-09 0.2037889E-08 0.1138052E-03 6.3454 12 K+ 0.9550616E-05 0.9554273E-05 0.3735754E+00 2.8086 13 Na+ 0.2164811E-03 0.2165600E-03 0.4978460E+01 4.1640 14 Mn++ 0.6113822E-07 0.7391548E-07 0.4060597E-02 8.4306 15 HPO4-- 0.2772699E-08 0.3451132E-08 0.3312222E-03 7.0873 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7320932E-03 -.7513025E-04 -.6569629E-03 0.0000000E+00 2 H2O 0.5550769E+02 0.5550751E+02 0.1776016E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2675157E-04 0.2550438E-04 0.1247192E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1247103E-05 0.8891020E-10 -.1247192E-05 0.0000000E+00 7 Al+++ 0.1467334E-03 0.3303893E-05 0.1434295E-03 0.0000000E+00 8 H4SiO4 0.4685752E-03 0.3081336E-03 0.1604416E-03 0.0000000E+00 9 Ca++ 0.6622748E-04 0.2042048E-04 0.4580700E-04 0.0000000E+00 10 Mg++ 0.3571429E-04 0.8726732E-07 0.3562702E-04 0.0000000E+00 11 Fe++ 0.3208539E-04 0.2037860E-08 0.3208335E-04 0.0000000E+00 12 K+ 0.9554140E-05 0.9554140E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2165570E-03 0.2165570E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7802368E-06 0.7391446E-07 0.7063224E-06 0.0000000E+00 15 HPO4-- 0.2662909E-06 0.3451084E-08 0.2628399E-06 0.0000000E+00 Chg. balance for solid moles: -.1075E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0450000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8761E-07 -7.057 0.4401E-04 -4.356 0.1663 0.1398E-04 clinochlore 0.7125E-05 -5.147 0.3961E-02 -2.402 14.97 0.1506E-02 daphnite 0.4421E-05 -5.354 0.3155E-02 -2.501 11.92 0.9559E-03 chlorite-Mn 0.1413E-06 -6.850 0.1002E-03 -3.999 0.3784 0.3192E-04 diaspore -.5324E-05 1.000 -.3194E-03 1.000 -1.207 -.9509E-04 hematite 0.4989E-05 -5.302 0.7967E-03 -3.099 3.010 0.1510E-03 kaolinite 0.1732E-04 -4.761 0.4471E-02 -2.350 16.90 0.1720E-02 lawsonite 0.4537E-04 -4.343 0.1426E-01 -1.846 53.87 0.4597E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3783E+00 0.3783E+00 1.0000 -0.422 chlorite-Mn 0.1209E-01 0.1209E-01 1.0000 -1.918 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.026465 g Volume = 0.008882 cm3 Porosity: 99.1275% V(tot) - V(min): 0.10091E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0450000 g log = -1.3468 Original solution: 1000.0103000 g Original solution / Rock added: 22222.45 (Water/Rock Ratio), log = 4.3468 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3827E-04 1.0071 0.3933E-04 0.3905E-04 CH4,gas 0.7505E-15 1.0125 0.7754E-15 0.7658E-15 H2,gas 0.6530E-06 1.0005 0.6666E-06 0.6662E-06 H2S,gas 0.1211E-11 0.9960 0.1230E-11 0.1235E-11 S2,gas 0.1253E-30 1.0000 0.1279E-30 0.1279E-30 CO,gas 0.6847E-14 1.0000 0.6987E-14 0.6987E-14 SO3,gas 0.1702E-35 1.0000 0.1737E-35 0.1737E-35 SO2,gas 0.4415E-19 1.0000 0.4505E-19 0.4505E-19 HCl,gas 0.5970E-15 1.0000 0.6092E-15 0.6092E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.76 -6.10 -2.035 0.10423E+05 -4.405 3 CH4,gas 4.54 -12.27 -16.81 -4.202 0.28702E+05 -15.111 4 H2,gas 8.00 0.12 -7.88 -4.500 0.13447E+05 -6.176 5 H2S,gas -6.23 -19.84 -13.61 -6.804 0.23237E+05 -11.910 6 S2,gas -7.34 -39.93 -32.59 -5.014 0.55650E+05 -30.893 7 CO,gas 3.21 -12.64 -15.85 -4.878 0.27071E+05 -14.156 8 SO3,gas 17.12 -20.34 -37.46 -9.365 0.63960E+05 -35.760 9 SO2,gas 0.83 -20.21 -21.05 -5.612 0.35934E+05 -19.346 10 HCl,gas 5.19 -11.72 -16.91 -8.457 0.28881E+05 -15.215 11 acmite 7.71 3.37 -4.34 -0.451 0.74152E+04 15 albite-high 0.69 -3.58 -4.28 -0.329 0.73005E+04 16 albite -0.38 -3.58 -3.20 -0.246 0.54617E+04 19 spessartine 24.46 20.42 -4.04 -0.202 0.68955E+04 20 analcite 3.32 -0.04 -3.36 -0.374 0.57445E+04 21 andalusite 5.00 2.21 -2.79 -0.279 0.47710E+04 22 andradite 39.01 34.79 -4.22 -0.219 0.71992E+04 23 grossular 32.73 27.97 -4.76 -0.238 0.81237E+04 24 anhydrite -5.32 -9.39 -4.07 -2.036 0.69531E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.82 -2.78 -0.927 0.47504E+04 36 brucite 12.57 8.57 -4.00 -0.799 0.68214E+04 37 calcite 0.81 -1.82 -2.63 -0.876 0.44861E+04 40 carpholite-Mg 8.58 7.24 -1.34 -0.089 0.22902E+04 41 carpholite-Fe 6.71 5.01 -1.70 -0.113 0.29027E+04 50 chloritoid-Mg 13.20 10.78 -2.42 -0.161 0.41267E+04 51 chloritoid-Fe 9.17 8.55 -0.62 -0.041 0.10601E+04 52 chloritoid-Mn 11.40 10.64 -0.76 -0.051 0.13031E+04 54 coesite -2.38 -3.54 -1.16 -0.388 0.19875E+04 59 corundum 8.38 5.75 -2.64 -0.240 0.45004E+04 61 cristobalite -2.56 -3.54 -0.98 -0.327 0.16729E+04 65 diaspore 2.87 2.87 0.00 0.000 0.30331E-11 67 diopside 16.18 12.44 -3.74 -0.374 0.63845E+04 68 hedenbergite 14.21 10.21 -3.99 -0.399 0.68200E+04 75 epidote 24.67 23.31 -1.36 -0.066 0.23256E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.72 -3.12 -0.162 0.53333E+04 78 fayalite 14.05 9.15 -4.89 -0.699 0.83580E+04 83 gibbsite 4.08 2.87 -1.21 -0.172 0.20585E+04 87 greenalite 16.14 11.96 -4.18 -0.349 0.71431E+04 91 heulandite -5.83 -8.08 -2.26 -0.103 0.38539E+04 95 jadeite 4.22 -0.04 -4.26 -0.426 0.72700E+04 99 kyanite 4.88 2.21 -2.67 -0.267 0.45569E+04 101 laumontite 2.88 2.54 -0.35 -0.023 0.59335E+03 105 lizardite 23.24 18.64 -4.60 -0.384 0.78601E+04 106 magnesite 0.69 -4.19 -4.88 -1.627 0.83350E+04 107 magnetite 20.09 18.91 -1.18 -0.096 0.20076E+04 113 margarite 17.32 15.36 -1.96 -0.078 0.33469E+04 116 microcline -2.49 -4.94 -2.45 -0.189 0.41858E+04 120 muscovite 2.58 0.81 -1.77 -0.104 0.30273E+04 121 paragonite 4.24 2.16 -2.07 -0.122 0.35423E+04 122 nepheline 8.34 3.50 -4.84 -0.692 0.82674E+04 136 prehnite 19.37 17.02 -2.35 -0.138 0.40075E+04 137 prehnite-Fe 22.50 20.43 -2.06 -0.124 0.35236E+04 138 pumpellyite-Fe 46.27 43.27 -3.00 -0.067 0.51235E+04 139 pumpellyite-Mg 48.99 45.50 -3.50 -0.078 0.59727E+04 145 pyroxmangite 7.40 4.89 -2.51 -0.502 0.42826E+04 146 pyrophyllite -6.18 -8.41 -2.24 -0.140 0.38198E+04 147 quartz -2.99 -3.54 -0.55 -0.184 0.94021E+03 151 rhodochrosite -0.98 -4.33 -3.36 -1.119 0.57329E+04 152 rhodonite 7.45 4.89 -2.56 -0.511 0.43629E+04 153 sanidine -1.28 -4.94 -3.66 -0.282 0.62535E+04 155 siderite -2.61 -6.42 -3.81 -1.270 0.65069E+04 156 sillimanite 5.26 2.21 -3.05 -0.305 0.52150E+04 163 stilbite -7.52 -8.08 -0.56 -0.027 0.96008E+03 164 stilpnomelane-Fe 13.02 10.56 -2.46 -0.073 0.41984E+04 167 sudoite-Fe 18.30 13.57 -4.73 -0.153 0.80777E+04 168 sudoite 21.08 18.02 -3.06 -0.099 0.52175E+04 171 talc 16.49 11.56 -4.93 -0.290 0.84191E+04 174 tephroite 18.09 13.32 -4.76 -0.681 0.81356E+04 177 topaz-H 4.62 2.21 -2.41 -0.219 0.41170E+04 178 tridymite -2.63 -3.54 -0.91 -0.305 0.15602E+04 187 wairakite 3.95 2.54 -1.41 -0.083 0.24153E+04 188 walstromite 11.51 7.41 -4.10 -0.820 0.70014E+04 189 wollastonite 10.46 7.41 -3.05 -0.610 0.52119E+04 190 pseudo-wollastonite 11.00 7.41 -3.59 -0.718 0.61317E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.49 -2.84 -0.176 0.48564E+04 194 beidellite-H -2.33 -6.30 -3.97 -0.253 0.67789E+04 195 beidellite-K -1.52 -5.37 -3.85 -0.236 0.65726E+04 196 beidellite-Mg -1.79 -4.88 -3.09 -0.191 0.52795E+04 197 beidellite-Na -1.34 -4.92 -3.58 -0.219 0.61128E+04 199 chalcedony -2.80 -3.54 -0.74 -0.246 0.12595E+04 201 montmorillonite-Ca -2.29 -4.73 -2.43 -0.151 0.41572E+04 202 montmorillonite-K -2.24 -5.61 -3.37 -0.206 0.57515E+04 203 montmorillonite-Mg -2.48 -5.12 -2.64 -0.163 0.45034E+04 204 montmorillonite-Na -2.04 -5.16 -3.12 -0.191 0.53274E+04 205 nontronite-Ca 3.21 2.33 -0.89 -0.057 0.15121E+04 206 nontronite-H 2.53 0.52 -2.01 -0.135 0.34325E+04 207 nontronite-K 3.34 1.45 -1.89 -0.121 0.32296E+04 208 nontronite-Mg 3.07 1.94 -1.14 -0.074 0.19424E+04 209 nontronite-Na 3.52 1.90 -1.62 -0.104 0.27715E+04 214 gypsum -4.96 -9.39 -4.43 -1.108 0.75707E+04 224 tobermorite 9.82 5.58 -4.24 -1.158 0.72444E+04 233 boehmite 4.41 2.87 -1.53 -0.255 0.26169E+04 235 ferrous-oxide 9.81 6.35 -3.47 -0.867 0.59184E+04 240 silica-amorphous -2.09 -3.54 -1.45 -0.483 0.24737E+04 242 an20ab80 2.02 -0.94 -2.96 -0.228 0.50552E+04 243 an25ab75 2.65 -0.28 -2.93 -0.225 0.50005E+04 244 an30ab70 3.28 0.38 -2.90 -0.223 0.49555E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0450000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2955117E-03 Osmotic coef. = 0.9897 True ionic strength = .3127921E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14867E-07 -7.8278 0.14263E-07 -7.8458 0.95937E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13234E-03 -3.8783 0.95923E+00 -0.0181 4 SO4-- 0.25371E-04 -4.5957 0.22669E-04 -4.6446 0.89352E+00 -0.0489 5 HCO3- 0.12596E-04 -4.8998 0.12083E-04 -4.9178 0.95927E+00 -0.0181 6 HS- 0.10340E-11 -11.9855 0.99182E-12 -12.0036 0.95924E+00 -0.0181 7 Al+++ 0.26876E-20 -20.5706 0.21326E-20 -20.6711 0.79349E+00 -0.1005 8 H4SiO4 0.29331E-03 -3.5327 0.29331E-03 -3.5327 0.10000E+01 0.0000 9 Ca++ 0.20241E-04 -4.6938 0.18082E-04 -4.7427 0.89337E+00 -0.0490 10 Mg++ 0.85016E-07 -7.0705 0.75942E-07 -7.1195 0.89327E+00 -0.0490 11 Fe++ 0.50276E-09 -9.2986 0.44911E-09 -9.3476 0.89330E+00 -0.0490 12 K+ 0.95506E-05 -5.0200 0.91616E-05 -5.0380 0.95927E+00 -0.0181 13 Na+ 0.21648E-03 -3.6646 0.20765E-03 -3.6827 0.95923E+00 -0.0181 14 Mn++ 0.61166E-07 -7.2135 0.54640E-07 -7.2625 0.89331E+00 -0.0490 15 HPO4-- 0.27622E-08 -8.5588 0.24680E-08 -8.6076 0.89352E+00 -0.0489 16 HSiO3- 0.20018E-04 -4.6986 0.19202E-04 -4.7167 0.95923E+00 -0.0181 17 Ca(HSiO3)+ 0.82432E-08 -8.0839 0.79075E-08 -8.1020 0.95928E+00 -0.0181 18 Mg(HSiO3)+ 0.43084E-10 -10.3657 0.41330E-10 -10.3837 0.95928E+00 -0.0181 19 NaHSiO3,aq 0.64490E-07 -7.1905 0.64490E-07 -7.1905 0.10000E+01 0.0000 20 AlO+ 0.14867E-11 -11.8278 0.14262E-11 -11.8458 0.95928E+00 -0.0181 21 AlOH+2 0.11338E-15 -15.9455 0.10129E-15 -15.9944 0.89333E+00 -0.0490 22 HAlO2,aq 0.19913E-07 -7.7009 0.19913E-07 -7.7009 0.10000E+01 0.0000 23 AlO2- 0.32220E-05 -5.4919 0.30905E-05 -5.5100 0.95919E+00 -0.0181 24 CH4,aq 0.51359E-18 -18.2894 0.51354E-18 -18.2894 0.99991E+00 0.0000 29 CO,aq 0.46652E-17 -17.3311 0.46652E-17 -17.3311 0.10000E+01 0.0000 30 CO2,aq 0.36829E-06 -6.4338 0.36826E-06 -6.4338 0.99991E+00 0.0000 31 CO3-2 0.82821E-07 -7.0819 0.73998E-07 -7.1308 0.89347E+00 -0.0489 32 CaCO3,aq 0.16778E-07 -7.7753 0.16778E-07 -7.7753 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58141E-08 -8.2355 0.55773E-08 -8.2536 0.95928E+00 -0.0181 34 CaCl+ 0.40370E-08 -8.3939 0.38726E-08 -8.4120 0.95928E+00 -0.0181 35 CaCl2,aq 0.12176E-12 -12.9145 0.12176E-12 -12.9145 0.10000E+01 0.0000 36 CaOH+ 0.94191E-07 -7.0260 0.90355E-07 -7.0440 0.95928E+00 -0.0181 37 CaSO4,aq 0.13017E-06 -6.8855 0.13017E-06 -6.8855 0.10000E+01 0.0000 38 HCl,aq 0.34588E-12 -12.4611 0.34588E-12 -12.4611 0.10000E+01 0.0000 43 FeCl+ 0.98069E-13 -13.0085 0.94076E-13 -13.0265 0.95928E+00 -0.0181 46 FeO,aq 0.85803E-10 -10.0665 0.85803E-10 -10.0665 0.10000E+01 0.0000 47 FeOH+ 0.10685E-08 -8.9712 0.10250E-08 -8.9893 0.95928E+00 -0.0181 48 HFeO2- 0.65619E-10 -10.1830 0.62944E-10 -10.2010 0.95923E+00 -0.0181 49 FeO+ 0.11349E-12 -12.9450 0.10887E-12 -12.9631 0.95928E+00 -0.0181 50 FeOH+2 0.33194E-18 -18.4789 0.29653E-18 -18.5279 0.89333E+00 -0.0490 51 FeO2- 0.11416E-09 -9.9425 0.10950E-09 -9.9606 0.95923E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.50434E-09 -9.2973 0.50429E-09 -9.2973 0.99991E+00 0.0000 54 KCl,aq 0.21974E-10 -10.6581 0.21974E-10 -10.6581 0.10000E+01 0.0000 55 KHSO4,aq 0.83753E-17 -17.0770 0.83753E-17 -17.0770 0.10000E+01 0.0000 56 KOH,aq 0.27432E-09 -9.5617 0.27432E-09 -9.5617 0.10000E+01 0.0000 57 KSO4- 0.33597E-08 -8.4737 0.32228E-08 -8.4918 0.95923E+00 -0.0181 58 MgCO3,aq 0.17662E-10 -10.7530 0.17662E-10 -10.7530 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24951E-10 -10.6029 0.23935E-10 -10.6210 0.95928E+00 -0.0181 60 MgCl+ 0.15367E-10 -10.8134 0.14741E-10 -10.8315 0.95928E+00 -0.0181 61 MgOH+ 0.21889E-08 -8.6598 0.20998E-08 -8.6778 0.95928E+00 -0.0181 63 MnO,aq 0.27816E-09 -9.5557 0.27816E-09 -9.5557 0.10000E+01 0.0000 64 MnOH+ 0.12076E-07 -7.9181 0.11584E-07 -7.9361 0.95928E+00 -0.0181 65 MnO2-2 0.50788E-16 -16.2942 0.45378E-16 -16.3432 0.89347E+00 -0.0489 66 HMnO2- 0.14782E-12 -12.8303 0.14180E-12 -12.8483 0.95923E+00 -0.0181 69 MnCl+ 0.46419E-10 -10.3333 0.44528E-10 -10.3514 0.95928E+00 -0.0181 70 MnSO4,aq 0.35759E-09 -9.4466 0.35759E-09 -9.4466 0.10000E+01 0.0000 71 NaCl,aq 0.91072E-08 -8.0406 0.91072E-08 -8.0406 0.10000E+01 0.0000 72 NaOH,aq 0.62553E-08 -8.2038 0.62553E-08 -8.2038 0.10000E+01 0.0000 74 OH- 0.42232E-04 -4.3744 0.40509E-04 -4.3925 0.95919E+00 -0.0181 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.67695E-09 -9.1694 0.64937E-09 -9.1875 0.95925E+00 -0.0181 84 PO4-3 0.17772E-12 -12.7503 0.14118E-12 -12.8502 0.79440E+00 -0.1000 87 H2P2O7-2 0.37006E-19 -19.4317 0.33064E-19 -19.4806 0.89347E+00 -0.0489 88 HP2O7-3 0.58335E-18 -18.2341 0.46289E-18 -18.3345 0.79350E+00 -0.1005 89 P2O7-4 0.11528E-19 -19.9382 0.77531E-20 -20.1105 0.67253E+00 -0.1723 90 H2S,aq 0.43724E-13 -13.3593 0.43720E-13 -13.3593 0.99991E+00 0.0000 96 SO2,aq 0.10386E-19 -19.9836 0.10386E-19 -19.9836 0.10000E+01 0.0000 97 SO3-2 0.16621E-14 -14.7793 0.14856E-14 -14.8281 0.89377E+00 -0.0488 98 HSO3- 0.13830E-14 -14.8592 0.13267E-14 -14.8772 0.95923E+00 -0.0181 99 HSO4- 0.32482E-09 -9.4884 0.31160E-09 -9.5064 0.95930E+00 -0.0180 101 S2O3-2 0.13030E-19 -19.8850 0.11642E-19 -19.9340 0.89347E+00 -0.0489 Charge balance for all species = 0.2297E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1486700E-07 -.7510381E-04 -.7569690E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999555E+06 0.0000 3 Cl- 0.1379629E-03 0.1379761E-03 0.4891458E+01 3.9675 4 SO4-- 0.2537062E-04 0.2550474E-04 0.2449921E+01 11.0470 5 HCO3- 0.1259644E-04 0.1307018E-04 0.7974719E+00 2.9280 6 HS- 0.1033963E-11 0.8804820E-10 0.2911805E-05 -4.1578 7 Al+++ 0.2687635E-20 0.3241892E-05 0.8746737E-01 2.8663 8 H4SiO4 0.2933095E-03 0.3134003E-03 0.3012131E+02 -3.5327 9 Ca++ 0.2024081E-04 0.2050004E-04 0.8215653E+00 10.9488 10 Mg++ 0.8501572E-07 0.8730573E-07 0.2122486E-02 8.5721 11 Fe++ 0.5027600E-09 0.2035681E-08 0.1136818E-03 6.3439 12 K+ 0.9550618E-05 0.9554274E-05 0.3735753E+00 2.8078 13 Na+ 0.2164801E-03 0.2165600E-03 0.4978458E+01 4.1631 14 Mn++ 0.6116612E-07 0.7392455E-07 0.4061093E-02 8.4291 15 HPO4-- 0.2762154E-08 0.3439289E-08 0.3300854E-03 7.0839 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7320932E-03 -.7510276E-04 -.6569904E-03 0.0000000E+00 2 H2O 0.5550769E+02 0.5550750E+02 0.1855397E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2675157E-04 0.2550438E-04 0.1247191E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1247103E-05 0.8804696E-10 -.1247191E-05 0.0000000E+00 7 Al+++ 0.1467334E-03 0.3241847E-05 0.1434915E-03 0.0000000E+00 8 H4SiO4 0.4685752E-03 0.3133959E-03 0.1551793E-03 0.0000000E+00 9 Ca++ 0.6622748E-04 0.2049975E-04 0.4572773E-04 0.0000000E+00 10 Mg++ 0.3571429E-04 0.8730450E-07 0.3562698E-04 0.0000000E+00 11 Fe++ 0.3208539E-04 0.2035653E-08 0.3208335E-04 0.0000000E+00 12 K+ 0.9554140E-05 0.9554140E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2165570E-03 0.2165570E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7802368E-06 0.7392351E-07 0.7063133E-06 0.0000000E+00 15 HPO4-- 0.2662909E-06 0.3439241E-08 0.2628517E-06 0.0000000E+00 Chg. balance for solid moles: 0.3240E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0450000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8762E-07 -7.057 0.4401E-04 -4.356 0.1686 0.1399E-04 clinochlore 0.7125E-05 -5.147 0.3961E-02 -2.402 15.17 0.1506E-02 daphnite 0.4421E-05 -5.354 0.3155E-02 -2.501 12.09 0.9559E-03 chlorite-Mn 0.1413E-06 -6.850 0.1002E-03 -3.999 0.3837 0.3192E-04 hematite 0.4989E-05 -5.302 0.7967E-03 -3.099 3.052 0.1510E-03 kaolinite 0.1477E-04 -4.831 0.3813E-02 -2.419 14.61 0.1467E-02 lawsonite 0.4529E-04 -4.344 0.1423E-01 -1.847 54.53 0.4589E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3783E+00 0.3783E+00 1.0000 -0.422 chlorite-Mn 0.1209E-01 0.1209E-01 1.0000 -1.918 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.026100 g Volume = 0.008716 cm3 Porosity: 99.1438% V(tot) - V(min): 0.10093E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0450000 g log = -1.3468 Original solution: 1000.0103000 g Original solution / Rock added: 22222.45 (Water/Rock Ratio), log = 4.3468 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3834E-04 1.0071 0.3940E-04 0.3912E-04 CH4,gas 0.7317E-15 1.0125 0.7559E-15 0.7465E-15 H2,gas 0.6485E-06 1.0005 0.6621E-06 0.6617E-06 H2S,gas 0.1183E-11 0.9960 0.1202E-11 0.1207E-11 S2,gas 0.1212E-30 1.0000 0.1237E-30 0.1237E-30 CO,gas 0.6813E-14 1.0000 0.6952E-14 0.6952E-14 SO3,gas 0.1709E-35 1.0000 0.1744E-35 0.1744E-35 SO2,gas 0.4402E-19 1.0000 0.4491E-19 0.4491E-19 HCl,gas 0.5982E-15 1.0000 0.6103E-15 0.6103E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.76 -6.10 -2.034 0.10422E+05 -4.405 3 CH4,gas 4.54 -12.28 -16.82 -4.205 0.28721E+05 -15.122 4 H2,gas 8.00 0.12 -7.88 -4.502 0.13452E+05 -6.179 5 H2S,gas -6.23 -19.85 -13.62 -6.810 0.23254E+05 -11.920 6 S2,gas -7.34 -39.94 -32.61 -5.016 0.55675E+05 -30.908 7 CO,gas 3.21 -12.64 -15.86 -4.879 0.27075E+05 -14.158 8 SO3,gas 17.12 -20.34 -37.46 -9.364 0.63958E+05 -35.759 9 SO2,gas 0.83 -20.21 -21.05 -5.612 0.35936E+05 -19.348 10 HCl,gas 5.19 -11.72 -16.91 -8.457 0.28879E+05 -15.214 11 acmite 7.71 3.38 -4.33 -0.450 0.73914E+04 15 albite-high 0.69 -3.57 -4.26 -0.328 0.72767E+04 16 albite -0.38 -3.57 -3.18 -0.245 0.54378E+04 19 spessartine 24.46 20.42 -4.04 -0.202 0.68905E+04 20 analcite 3.32 -0.04 -3.36 -0.373 0.57333E+04 21 andalusite 5.00 2.20 -2.80 -0.280 0.47837E+04 22 andradite 39.01 34.81 -4.19 -0.218 0.71613E+04 23 grossular 32.73 27.98 -4.75 -0.238 0.81111E+04 24 anhydrite -5.32 -9.39 -4.07 -2.035 0.69503E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.81 -2.78 -0.927 0.47490E+04 36 brucite 12.57 8.57 -4.00 -0.799 0.68239E+04 37 calcite 0.81 -1.81 -2.63 -0.876 0.44847E+04 40 carpholite-Mg 8.58 7.24 -1.34 -0.090 0.22928E+04 41 carpholite-Fe 6.71 5.01 -1.70 -0.113 0.29052E+04 50 chloritoid-Mg 13.20 10.77 -2.43 -0.162 0.41419E+04 51 chloritoid-Fe 9.17 8.54 -0.63 -0.042 0.10753E+04 52 chloritoid-Mn 11.40 10.63 -0.77 -0.051 0.13183E+04 54 coesite -2.38 -3.53 -1.16 -0.386 0.19749E+04 59 corundum 8.38 5.73 -2.65 -0.241 0.45257E+04 61 cristobalite -2.56 -3.53 -0.97 -0.324 0.16602E+04 65 diaspore 2.87 2.87 -0.01 -0.001 0.12648E+02 67 diopside 16.18 12.46 -3.73 -0.373 0.63617E+04 68 hedenbergite 14.21 10.23 -3.98 -0.398 0.67972E+04 75 epidote 24.67 23.32 -1.35 -0.066 0.23129E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.73 -3.11 -0.161 0.53080E+04 78 fayalite 14.05 9.16 -4.89 -0.699 0.83504E+04 83 gibbsite 4.08 2.87 -1.21 -0.173 0.20712E+04 87 greenalite 16.14 11.97 -4.17 -0.348 0.71253E+04 91 heulandite -5.83 -8.05 -2.22 -0.101 0.37907E+04 95 jadeite 4.22 -0.04 -4.25 -0.425 0.72588E+04 99 kyanite 4.88 2.20 -2.68 -0.268 0.45696E+04 101 laumontite 2.88 2.55 -0.33 -0.022 0.56805E+03 105 lizardite 23.24 18.65 -4.59 -0.383 0.78424E+04 106 magnesite 0.69 -4.19 -4.88 -1.627 0.83361E+04 107 magnetite 20.09 18.91 -1.18 -0.096 0.20102E+04 113 margarite 17.32 15.35 -1.97 -0.079 0.33722E+04 116 microcline -2.49 -4.92 -2.44 -0.187 0.41619E+04 120 muscovite 2.58 0.81 -1.77 -0.104 0.30287E+04 121 paragonite 4.24 2.16 -2.08 -0.122 0.35438E+04 122 nepheline 8.34 3.50 -4.84 -0.692 0.82688E+04 136 prehnite 19.37 17.03 -2.34 -0.138 0.39949E+04 137 prehnite-Fe 22.50 20.45 -2.05 -0.123 0.34983E+04 138 pumpellyite-Fe 46.27 43.27 -2.99 -0.067 0.51134E+04 139 pumpellyite-Mg 48.99 45.50 -3.49 -0.078 0.59626E+04 145 pyroxmangite 7.40 4.90 -2.50 -0.500 0.42725E+04 146 pyrophyllite -6.18 -8.40 -2.22 -0.139 0.37945E+04 147 quartz -2.99 -3.53 -0.54 -0.181 0.92757E+03 151 rhodochrosite -0.98 -4.33 -3.36 -1.119 0.57340E+04 152 rhodonite 7.45 4.90 -2.55 -0.510 0.43528E+04 153 sanidine -1.28 -4.92 -3.65 -0.281 0.62297E+04 155 siderite -2.61 -6.42 -3.81 -1.271 0.65081E+04 156 sillimanite 5.26 2.20 -3.06 -0.306 0.52276E+04 163 stilbite -7.52 -8.05 -0.53 -0.025 0.89684E+03 164 stilpnomelane-Fe 13.02 10.59 -2.42 -0.072 0.41358E+04 167 sudoite-Fe 18.30 13.56 -4.74 -0.153 0.80954E+04 168 sudoite 21.08 18.01 -3.07 -0.099 0.52353E+04 171 talc 16.49 11.59 -4.91 -0.289 0.83761E+04 174 tephroite 18.09 13.33 -4.76 -0.680 0.81280E+04 177 topaz-H 4.62 2.20 -2.42 -0.220 0.41297E+04 178 tridymite -2.63 -3.53 -0.91 -0.302 0.15475E+04 187 wairakite 3.95 2.55 -1.40 -0.082 0.23900E+04 188 walstromite 11.51 7.42 -4.09 -0.819 0.69888E+04 189 wollastonite 10.46 7.42 -3.04 -0.609 0.51992E+04 190 pseudo-wollastonite 11.00 7.42 -3.58 -0.717 0.61190E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.48 -2.83 -0.175 0.48395E+04 194 beidellite-H -2.33 -6.29 -3.96 -0.253 0.67620E+04 195 beidellite-K -1.52 -5.36 -3.84 -0.235 0.65561E+04 196 beidellite-Mg -1.79 -4.87 -3.08 -0.191 0.52629E+04 197 beidellite-Na -1.34 -4.91 -3.57 -0.219 0.60963E+04 199 chalcedony -2.80 -3.53 -0.73 -0.243 0.12469E+04 201 montmorillonite-Ca -2.29 -4.71 -2.42 -0.150 0.41286E+04 202 montmorillonite-K -2.24 -5.59 -3.35 -0.205 0.57233E+04 203 montmorillonite-Mg -2.48 -5.10 -2.62 -0.162 0.44752E+04 204 montmorillonite-Na -2.04 -5.14 -3.10 -0.190 0.52993E+04 205 nontronite-Ca 3.21 2.35 -0.86 -0.056 0.14699E+04 206 nontronite-H 2.53 0.55 -1.99 -0.133 0.33903E+04 207 nontronite-K 3.34 1.47 -1.87 -0.120 0.31878E+04 208 nontronite-Mg 3.07 1.96 -1.11 -0.072 0.19006E+04 209 nontronite-Na 3.52 1.92 -1.60 -0.103 0.27298E+04 214 gypsum -4.96 -9.39 -4.43 -1.108 0.75679E+04 224 tobermorite 9.82 5.59 -4.24 -1.156 0.72317E+04 233 boehmite 4.41 2.87 -1.54 -0.257 0.26296E+04 235 ferrous-oxide 9.81 6.34 -3.47 -0.867 0.59209E+04 240 silica-amorphous -2.09 -3.53 -1.44 -0.480 0.24610E+04 242 an20ab80 2.02 -0.93 -2.95 -0.227 0.50361E+04 243 an25ab75 2.65 -0.27 -2.92 -0.224 0.49826E+04 244 an30ab70 3.28 0.39 -2.89 -0.222 0.49388E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0450000 g New total amount of reactant added: 0.0470000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0470000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2953870E-03 Osmotic coef. = 0.9897 True ionic strength = .3139357E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14648E-07 -7.8342 0.14052E-07 -7.8523 0.95933E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13233E-03 -3.8783 0.95919E+00 -0.0181 4 SO4-- 0.25374E-04 -4.5956 0.22669E-04 -4.6446 0.89337E+00 -0.0490 5 HCO3- 0.12601E-04 -4.8996 0.12087E-04 -4.9177 0.95922E+00 -0.0181 6 HS- 0.95125E-12 -12.0217 0.91243E-12 -12.0398 0.95920E+00 -0.0181 7 Al+++ 0.24657E-20 -20.6081 0.19558E-20 -20.7087 0.79319E+00 -0.1006 8 H4SiO4 0.30583E-03 -3.5145 0.30583E-03 -3.5145 0.10000E+01 0.0000 9 Ca++ 0.19649E-04 -4.7067 0.17551E-04 -4.7557 0.89322E+00 -0.0490 10 Mg++ 0.81843E-07 -7.0870 0.73095E-07 -7.1361 0.89312E+00 -0.0491 11 Fe++ 0.48391E-09 -9.3152 0.43220E-09 -9.3643 0.89314E+00 -0.0491 12 K+ 0.99751E-05 -5.0011 0.95684E-05 -5.0192 0.95923E+00 -0.0181 13 Na+ 0.21899E-03 -3.6596 0.21005E-03 -3.6777 0.95919E+00 -0.0181 14 Mn++ 0.59300E-07 -7.2269 0.52964E-07 -7.2760 0.89316E+00 -0.0491 15 HPO4-- 0.28463E-08 -8.5457 0.25428E-08 -8.5947 0.89337E+00 -0.0490 16 HSiO3- 0.21187E-04 -4.6739 0.20323E-04 -4.6920 0.95919E+00 -0.0181 17 Ca(HSiO3)+ 0.84682E-08 -8.0722 0.81230E-08 -8.0903 0.95924E+00 -0.0181 18 Mg(HSiO3)+ 0.43891E-10 -10.3576 0.42102E-10 -10.3757 0.95924E+00 -0.0181 19 NaHSiO3,aq 0.69041E-07 -7.1609 0.69041E-07 -7.1609 0.10000E+01 0.0000 20 AlO+ 0.14048E-11 -11.8524 0.13475E-11 -11.8705 0.95924E+00 -0.0181 21 AlOH+2 0.10556E-15 -15.9765 0.94286E-16 -16.0256 0.89318E+00 -0.0491 22 HAlO2,aq 0.19098E-07 -7.7190 0.19098E-07 -7.7190 0.10000E+01 0.0000 23 AlO2- 0.31366E-05 -5.5035 0.30085E-05 -5.5217 0.95915E+00 -0.0181 24 CH4,aq 0.47264E-18 -18.3255 0.47259E-18 -18.3255 0.99991E+00 0.0000 29 CO,aq 0.45195E-17 -17.3449 0.45195E-17 -17.3449 0.10000E+01 0.0000 30 CO2,aq 0.36295E-06 -6.4402 0.36292E-06 -6.4402 0.99991E+00 0.0000 31 CO3-2 0.84106E-07 -7.0752 0.75134E-07 -7.1242 0.89332E+00 -0.0490 32 CaCO3,aq 0.16535E-07 -7.7816 0.16535E-07 -7.7816 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56452E-08 -8.2483 0.54151E-08 -8.2664 0.95924E+00 -0.0181 34 CaCl+ 0.39184E-08 -8.4069 0.37587E-08 -8.4250 0.95924E+00 -0.0181 35 CaCl2,aq 0.11817E-12 -12.9275 0.11817E-12 -12.9275 0.10000E+01 0.0000 36 CaOH+ 0.92801E-07 -7.0324 0.89018E-07 -7.0505 0.95924E+00 -0.0181 37 CaSO4,aq 0.12634E-06 -6.8985 0.12634E-06 -6.8985 0.10000E+01 0.0000 38 HCl,aq 0.34075E-12 -12.4676 0.34075E-12 -12.4676 0.10000E+01 0.0000 43 FeCl+ 0.94376E-13 -13.0251 0.90529E-13 -13.0432 0.95924E+00 -0.0181 46 FeO,aq 0.85072E-10 -10.0702 0.85072E-10 -10.0702 0.10000E+01 0.0000 47 FeOH+ 0.10437E-08 -8.9814 0.10012E-08 -8.9995 0.95924E+00 -0.0181 48 HFeO2- 0.66041E-10 -10.1802 0.63346E-10 -10.1983 0.95919E+00 -0.0181 49 FeO+ 0.11181E-12 -12.9515 0.10726E-12 -12.9696 0.95924E+00 -0.0181 50 FeOH+2 0.32224E-18 -18.4918 0.28782E-18 -18.5409 0.89318E+00 -0.0491 51 FeO2- 0.11588E-09 -9.9360 0.11115E-09 -9.9541 0.95919E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.49577E-09 -9.3047 0.49573E-09 -9.3048 0.99991E+00 0.0000 54 KCl,aq 0.22949E-10 -10.6392 0.22949E-10 -10.6392 0.10000E+01 0.0000 55 KHSO4,aq 0.86175E-17 -17.0646 0.86175E-17 -17.0646 0.10000E+01 0.0000 56 KOH,aq 0.29080E-09 -9.5364 0.29080E-09 -9.5364 0.10000E+01 0.0000 57 KSO4- 0.35090E-08 -8.4548 0.33658E-08 -8.4729 0.95919E+00 -0.0181 58 MgCO3,aq 0.17261E-10 -10.7629 0.17261E-10 -10.7629 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24024E-10 -10.6194 0.23045E-10 -10.6374 0.95924E+00 -0.0181 60 MgCl+ 0.14791E-10 -10.8300 0.14188E-10 -10.8481 0.95924E+00 -0.0181 61 MgOH+ 0.21386E-08 -8.6699 0.20515E-08 -8.6879 0.95924E+00 -0.0181 63 MnO,aq 0.27779E-09 -9.5563 0.27779E-09 -9.5563 0.10000E+01 0.0000 64 MnOH+ 0.11882E-07 -7.9251 0.11398E-07 -7.9432 0.95924E+00 -0.0181 65 MnO2-2 0.52265E-16 -16.2818 0.46690E-16 -16.3308 0.89332E+00 -0.0490 66 HMnO2- 0.14985E-12 -12.8243 0.14374E-12 -12.8424 0.95919E+00 -0.0181 69 MnCl+ 0.44995E-10 -10.3468 0.43160E-10 -10.3649 0.95924E+00 -0.0181 70 MnSO4,aq 0.34661E-09 -9.4602 0.34661E-09 -9.4602 0.10000E+01 0.0000 71 NaCl,aq 0.92118E-08 -8.0357 0.92118E-08 -8.0357 0.10000E+01 0.0000 72 NaOH,aq 0.64225E-08 -8.1923 0.64225E-08 -8.1923 0.10000E+01 0.0000 74 OH- 0.42869E-04 -4.3679 0.41118E-04 -4.3860 0.95915E+00 -0.0181 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.68716E-09 -9.1629 0.65913E-09 -9.1810 0.95921E+00 -0.0181 84 PO4-3 0.18592E-12 -12.7307 0.14764E-12 -12.8308 0.79410E+00 -0.1001 87 H2P2O7-2 0.38133E-19 -19.4187 0.34065E-19 -19.4677 0.89332E+00 -0.0490 88 HP2O7-3 0.61028E-18 -18.2145 0.48407E-18 -18.3151 0.79320E+00 -0.1006 89 P2O7-4 0.12245E-19 -19.9120 0.82298E-20 -20.0846 0.67208E+00 -0.1726 90 H2S,aq 0.39629E-13 -13.4020 0.39626E-13 -13.4020 0.99991E+00 0.0000 97 SO3-2 0.16341E-14 -14.7867 0.14603E-14 -14.8356 0.89362E+00 -0.0488 98 HSO3- 0.13395E-14 -14.8731 0.12848E-14 -14.8912 0.95919E+00 -0.0181 99 HSO4- 0.32001E-09 -9.4948 0.30698E-09 -9.5129 0.95926E+00 -0.0181 101 S2O3-2 0.11812E-19 -19.9277 0.10552E-19 -19.9767 0.89332E+00 -0.0490 Charge balance for all species = 0.2240E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1464752E-07 -.7657546E-04 -.7718007E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999542E+06 0.0000 3 Cl- 0.1379630E-03 0.1379762E-03 0.4891454E+01 3.9739 4 SO4-- 0.2537433E-04 0.2550476E-04 0.2449920E+01 11.0600 5 HCO3- 0.1260091E-04 0.1307019E-04 0.7974713E+00 2.9346 6 HS- 0.9512475E-12 0.8560618E-10 0.2831043E-05 -4.1875 7 Al+++ 0.2465734E-20 0.3155720E-05 0.8514230E-01 2.8481 8 H4SiO4 0.3058319E-03 0.3270966E-03 0.3143763E+02 -3.5145 9 Ca++ 0.1964926E-04 0.1990297E-04 0.7976361E+00 10.9488 10 Mg++ 0.8184261E-07 0.8408122E-07 0.2044093E-02 8.5684 11 Fe++ 0.4839065E-09 0.1993486E-08 0.1113253E-03 6.3402 12 K+ 0.9975092E-05 0.9978914E-05 0.3901783E+00 2.8331 13 Na+ 0.2189860E-03 0.2190707E-03 0.5036168E+01 4.1746 14 Mn++ 0.5929958E-07 0.7185115E-07 0.3947184E-02 8.4285 15 HPO4-- 0.2846270E-08 0.3533615E-08 0.3391379E-03 7.1098 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7652102E-03 -.7657434E-04 -.6886359E-03 0.0000000E+00 2 H2O 0.5550766E+02 0.5550747E+02 0.1947785E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2680700E-04 0.2550438E-04 0.1302616E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1302530E-05 0.8560493E-10 -.1302616E-05 0.0000000E+00 7 Al+++ 0.1532549E-03 0.3155674E-05 0.1500992E-03 0.0000000E+00 8 H4SiO4 0.4894008E-03 0.3270918E-03 0.1623090E-03 0.0000000E+00 9 Ca++ 0.6852776E-04 0.1990268E-04 0.4862509E-04 0.0000000E+00 10 Mg++ 0.3730159E-04 0.8407999E-07 0.3721751E-04 0.0000000E+00 11 Fe++ 0.3351140E-04 0.1993456E-08 0.3350941E-04 0.0000000E+00 12 K+ 0.9978769E-05 0.9978769E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2190675E-03 0.2190675E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.8149140E-06 0.7185010E-07 0.7430639E-06 0.0000000E+00 15 HPO4-- 0.2781261E-06 0.3533563E-08 0.2745925E-06 0.0000000E+00 Chg. balance for solid moles: 0.1022E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0470000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9153E-07 -7.038 0.4598E-04 -4.337 0.1682 0.1461E-04 clinochlore 0.7444E-05 -5.128 0.4137E-02 -2.383 15.13 0.1574E-02 daphnite 0.4618E-05 -5.336 0.3295E-02 -2.482 12.05 0.9984E-03 chlorite-Mn 0.1486E-06 -6.828 0.1054E-03 -3.977 0.3854 0.3358E-04 hematite 0.5210E-05 -5.283 0.8321E-03 -3.080 3.044 0.1577E-03 kaolinite 0.1467E-04 -4.834 0.3788E-02 -2.422 13.85 0.1457E-02 lawsonite 0.4817E-04 -4.317 0.1514E-01 -1.820 55.36 0.4881E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3782E+00 0.3782E+00 1.0000 -0.422 chlorite-Mn 0.1217E-01 0.1217E-01 1.0000 -1.915 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.027339 g Volume = 0.009117 cm3 Porosity: 99.1052% V(tot) - V(min): 0.10097E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0470000 g log = -1.3279 Original solution: 1000.0103000 g Original solution / Rock added: 21276.81 (Water/Rock Ratio), log = 4.3279 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3779E-04 1.0071 0.3883E-04 0.3855E-04 CH4,gas 0.6733E-15 1.0125 0.6956E-15 0.6870E-15 H2,gas 0.6375E-06 1.0005 0.6508E-06 0.6505E-06 H2S,gas 0.1072E-11 0.9960 0.1089E-11 0.1094E-11 S2,gas 0.1031E-30 1.0000 0.1051E-30 0.1051E-30 CO,gas 0.6601E-14 1.0000 0.6735E-14 0.6735E-14 SO3,gas 0.1659E-35 1.0000 0.1692E-35 0.1692E-35 SO2,gas 0.4200E-19 1.0000 0.4285E-19 0.4285E-19 HCl,gas 0.5893E-15 1.0000 0.6013E-15 0.6013E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.77 -6.11 -2.037 0.10432E+05 -4.411 3 CH4,gas 4.54 -12.31 -16.86 -4.214 0.28782E+05 -15.158 4 H2,gas 8.00 0.11 -7.89 -4.506 0.13464E+05 -6.187 5 H2S,gas -6.23 -19.89 -13.66 -6.831 0.23327E+05 -11.963 6 S2,gas -7.34 -40.01 -32.68 -5.027 0.55795E+05 -30.978 7 CO,gas 3.21 -12.66 -15.87 -4.883 0.27099E+05 -14.172 8 SO3,gas 17.12 -20.35 -37.47 -9.368 0.63980E+05 -35.772 9 SO2,gas 0.83 -20.23 -21.07 -5.618 0.35971E+05 -19.368 10 HCl,gas 5.19 -11.73 -16.92 -8.460 0.28890E+05 -15.221 11 acmite 7.71 3.43 -4.28 -0.445 0.73098E+04 15 albite-high 0.69 -3.52 -4.21 -0.324 0.71951E+04 16 albite -0.38 -3.52 -3.14 -0.241 0.53563E+04 19 spessartine 24.46 20.44 -4.02 -0.201 0.68624E+04 20 analcite 3.32 -0.01 -3.33 -0.370 0.56828E+04 21 andalusite 5.00 2.18 -2.82 -0.282 0.48147E+04 22 andradite 39.01 34.87 -4.14 -0.215 0.70682E+04 23 grossular 32.73 28.00 -4.73 -0.237 0.80801E+04 24 anhydrite -5.32 -9.40 -4.08 -2.042 0.69724E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.82 -2.79 -0.929 0.47598E+04 36 brucite 12.57 8.57 -4.00 -0.800 0.68301E+04 37 calcite 0.81 -1.82 -2.63 -0.878 0.44956E+04 40 carpholite-Mg 8.58 7.24 -1.35 -0.090 0.22990E+04 41 carpholite-Fe 6.71 5.01 -1.71 -0.114 0.29116E+04 50 chloritoid-Mg 13.20 10.75 -2.45 -0.163 0.41791E+04 51 chloritoid-Fe 9.17 8.52 -0.65 -0.043 0.11127E+04 52 chloritoid-Mn 11.40 10.61 -0.79 -0.053 0.13503E+04 54 coesite -2.38 -3.51 -1.14 -0.379 0.19439E+04 59 corundum 8.38 5.70 -2.69 -0.244 0.45877E+04 61 cristobalite -2.56 -3.51 -0.95 -0.318 0.16292E+04 65 diaspore 2.87 2.85 -0.03 -0.004 0.43650E+02 67 diopside 16.18 12.49 -3.69 -0.369 0.63059E+04 68 hedenbergite 14.21 10.26 -3.95 -0.395 0.67415E+04 75 epidote 24.67 23.33 -1.34 -0.065 0.22819E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.77 -3.07 -0.160 0.52460E+04 78 fayalite 14.05 9.17 -4.88 -0.697 0.83321E+04 83 gibbsite 4.08 2.85 -1.23 -0.176 0.21022E+04 87 greenalite 16.14 11.99 -4.15 -0.346 0.70824E+04 91 heulandite -5.83 -7.96 -2.13 -0.097 0.36357E+04 95 jadeite 4.22 -0.01 -4.22 -0.422 0.72083E+04 99 kyanite 4.88 2.18 -2.69 -0.269 0.46006E+04 101 laumontite 2.88 2.59 -0.30 -0.020 0.50605E+03 105 lizardite 23.24 18.68 -4.57 -0.381 0.77990E+04 106 magnesite 0.69 -4.20 -4.89 -1.631 0.83532E+04 107 magnetite 20.09 18.91 -1.18 -0.096 0.20165E+04 113 margarite 17.32 15.31 -2.01 -0.080 0.34342E+04 116 microcline -2.49 -4.86 -2.38 -0.183 0.40566E+04 120 muscovite 2.58 0.83 -1.75 -0.103 0.29855E+04 121 paragonite 4.24 2.18 -2.06 -0.121 0.35242E+04 122 nepheline 8.34 3.51 -4.83 -0.690 0.82492E+04 136 prehnite 19.37 17.05 -2.32 -0.137 0.39639E+04 137 prehnite-Fe 22.50 20.49 -2.01 -0.121 0.34363E+04 138 pumpellyite-Fe 46.27 43.29 -2.98 -0.066 0.50887E+04 139 pumpellyite-Mg 48.99 45.52 -3.48 -0.077 0.59378E+04 145 pyroxmangite 7.40 4.91 -2.48 -0.497 0.42425E+04 146 pyrophyllite -6.18 -8.36 -2.19 -0.137 0.37325E+04 147 quartz -2.99 -3.51 -0.53 -0.175 0.89656E+03 151 rhodochrosite -0.98 -4.34 -3.37 -1.122 0.57458E+04 152 rhodonite 7.45 4.91 -2.53 -0.506 0.43228E+04 153 sanidine -1.28 -4.86 -3.59 -0.276 0.61244E+04 155 siderite -2.61 -6.43 -3.82 -1.274 0.65252E+04 156 sillimanite 5.26 2.18 -3.08 -0.308 0.52586E+04 163 stilbite -7.52 -7.96 -0.43 -0.021 0.74183E+03 164 stilpnomelane-Fe 13.02 10.70 -2.32 -0.069 0.39599E+04 167 sudoite-Fe 18.30 13.53 -4.77 -0.154 0.81391E+04 168 sudoite 21.08 17.99 -3.09 -0.100 0.52787E+04 171 talc 16.49 11.65 -4.84 -0.285 0.82707E+04 174 tephroite 18.09 13.34 -4.74 -0.678 0.80990E+04 177 topaz-H 4.62 2.18 -2.44 -0.222 0.41607E+04 178 tridymite -2.63 -3.51 -0.89 -0.296 0.15165E+04 187 wairakite 3.95 2.59 -1.36 -0.080 0.23280E+04 188 walstromite 11.51 7.43 -4.07 -0.815 0.69578E+04 189 wollastonite 10.46 7.43 -3.03 -0.605 0.51682E+04 190 pseudo-wollastonite 11.00 7.43 -3.57 -0.713 0.60880E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.46 -2.81 -0.174 0.47979E+04 194 beidellite-H -2.33 -6.26 -3.94 -0.251 0.67204E+04 195 beidellite-K -1.52 -5.33 -3.81 -0.233 0.65003E+04 196 beidellite-Mg -1.79 -4.85 -3.06 -0.189 0.52224E+04 197 beidellite-Na -1.34 -4.88 -3.54 -0.217 0.60484E+04 199 chalcedony -2.80 -3.51 -0.71 -0.237 0.12159E+04 201 montmorillonite-Ca -2.29 -4.67 -2.38 -0.147 0.40584E+04 202 montmorillonite-K -2.24 -5.54 -3.30 -0.202 0.56389E+04 203 montmorillonite-Mg -2.48 -5.06 -2.58 -0.160 0.44060E+04 204 montmorillonite-Na -2.04 -5.10 -3.06 -0.187 0.52226E+04 205 nontronite-Ca 3.21 2.41 -0.80 -0.052 0.13663E+04 206 nontronite-H 2.53 0.61 -1.92 -0.129 0.32867E+04 207 nontronite-K 3.34 1.54 -1.80 -0.115 0.30700E+04 208 nontronite-Mg 3.07 2.02 -1.05 -0.068 0.17980E+04 209 nontronite-Na 3.52 1.99 -1.53 -0.098 0.26198E+04 214 gypsum -4.96 -9.40 -4.45 -1.111 0.75900E+04 224 tobermorite 9.82 5.61 -4.22 -1.151 0.72007E+04 233 boehmite 4.41 2.85 -1.56 -0.260 0.26606E+04 235 ferrous-oxide 9.81 6.34 -3.47 -0.868 0.59273E+04 240 silica-amorphous -2.09 -3.51 -1.42 -0.474 0.24300E+04 242 an20ab80 2.02 -0.89 -2.91 -0.224 0.49708E+04 243 an25ab75 2.65 -0.24 -2.88 -0.222 0.49215E+04 244 an30ab70 3.28 0.42 -2.86 -0.220 0.48817E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0470000 g New total amount of reactant added: 0.0490000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0490000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2953372E-03 Osmotic coef. = 0.9897 True ionic strength = .3151408E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14432E-07 -7.8407 0.13845E-07 -7.8587 0.95928E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13233E-03 -3.8784 0.95915E+00 -0.0181 4 SO4-- 0.25378E-04 -4.5955 0.22668E-04 -4.6446 0.89321E+00 -0.0490 5 HCO3- 0.12605E-04 -4.8994 0.12091E-04 -4.9175 0.95918E+00 -0.0181 6 HS- 0.87778E-12 -12.0566 0.84193E-12 -12.0747 0.95915E+00 -0.0181 7 Al+++ 0.22667E-20 -20.6446 0.17972E-20 -20.7454 0.79287E+00 -0.1008 8 H4SiO4 0.31833E-03 -3.4971 0.31833E-03 -3.4971 0.10000E+01 0.0000 9 Ca++ 0.19078E-04 -4.7195 0.17038E-04 -4.7686 0.89306E+00 -0.0491 10 Mg++ 0.78828E-07 -7.1033 0.70391E-07 -7.1525 0.89296E+00 -0.0492 11 Fe++ 0.46601E-09 -9.3316 0.41614E-09 -9.3808 0.89299E+00 -0.0492 12 K+ 0.10400E-04 -4.9830 0.99751E-05 -5.0011 0.95919E+00 -0.0181 13 Na+ 0.22149E-03 -3.6546 0.21244E-03 -3.6728 0.95915E+00 -0.0181 14 Mn++ 0.57480E-07 -7.2405 0.51330E-07 -7.2896 0.89300E+00 -0.0491 15 HPO4-- 0.29325E-08 -8.5328 0.26194E-08 -8.5818 0.89321E+00 -0.0490 16 HSiO3- 0.22384E-04 -4.6501 0.21470E-04 -4.6682 0.95915E+00 -0.0181 17 Ca(HSiO3)+ 0.86849E-08 -8.0612 0.83305E-08 -8.0793 0.95919E+00 -0.0181 18 Mg(HSiO3)+ 0.44655E-10 -10.3501 0.42832E-10 -10.3682 0.95919E+00 -0.0181 19 NaHSiO3,aq 0.73769E-07 -7.1321 0.73769E-07 -7.1321 0.10000E+01 0.0000 20 AlO+ 0.13298E-11 -11.8762 0.12755E-11 -11.8943 0.95919E+00 -0.0181 21 AlOH+2 0.98468E-16 -16.0067 0.87934E-16 -16.0558 0.89302E+00 -0.0491 22 HAlO2,aq 0.18348E-07 -7.7364 0.18348E-07 -7.7364 0.10000E+01 0.0000 23 AlO2- 0.30586E-05 -5.5145 0.29336E-05 -5.5326 0.95911E+00 -0.0181 24 CH4,aq 0.43626E-18 -18.3603 0.43622E-18 -18.3603 0.99991E+00 0.0000 29 CO,aq 0.43819E-17 -17.3583 0.43819E-17 -17.3583 0.10000E+01 0.0000 30 CO2,aq 0.35771E-06 -6.4465 0.35768E-06 -6.4465 0.99991E+00 0.0000 31 CO3-2 0.85404E-07 -7.0685 0.76280E-07 -7.1176 0.89316E+00 -0.0491 32 CaCO3,aq 0.16296E-07 -7.7879 0.16296E-07 -7.7879 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54821E-08 -8.2611 0.52584E-08 -8.2791 0.95919E+00 -0.0181 34 CaCl+ 0.38038E-08 -8.4198 0.36486E-08 -8.4379 0.95919E+00 -0.0181 35 CaCl2,aq 0.11471E-12 -12.9404 0.11471E-12 -12.9404 0.10000E+01 0.0000 36 CaOH+ 0.91438E-07 -7.0389 0.87706E-07 -7.0570 0.95919E+00 -0.0181 37 CaSO4,aq 0.12264E-06 -6.9114 0.12264E-06 -6.9114 0.10000E+01 0.0000 38 HCl,aq 0.33571E-12 -12.4740 0.33571E-12 -12.4740 0.10000E+01 0.0000 43 FeCl+ 0.90869E-13 -13.0416 0.87161E-13 -13.0597 0.95919E+00 -0.0181 46 FeO,aq 0.84378E-10 -10.0738 0.84378E-10 -10.0738 0.10000E+01 0.0000 47 FeOH+ 0.10200E-08 -8.9914 0.97840E-09 -9.0095 0.95919E+00 -0.0181 48 HFeO2- 0.66484E-10 -10.1773 0.63768E-10 -10.1954 0.95915E+00 -0.0181 49 FeO+ 0.11017E-12 -12.9579 0.10568E-12 -12.9760 0.95919E+00 -0.0181 50 FeOH+2 0.31287E-18 -18.5046 0.27940E-18 -18.5538 0.89302E+00 -0.0491 51 FeO2- 0.11762E-09 -9.9295 0.11281E-09 -9.9476 0.95915E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.48772E-09 -9.3118 0.48767E-09 -9.3119 0.99991E+00 0.0000 54 KCl,aq 0.23924E-10 -10.6212 0.23924E-10 -10.6212 0.10000E+01 0.0000 55 KHSO4,aq 0.88511E-17 -17.0530 0.88511E-17 -17.0530 0.10000E+01 0.0000 56 KOH,aq 0.30769E-09 -9.5119 0.30769E-09 -9.5119 0.10000E+01 0.0000 57 KSO4- 0.36582E-08 -8.4367 0.35087E-08 -8.4548 0.95915E+00 -0.0181 58 MgCO3,aq 0.16876E-10 -10.7727 0.16876E-10 -10.7727 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23143E-10 -10.6356 0.22198E-10 -10.6537 0.95919E+00 -0.0181 60 MgCl+ 0.14243E-10 -10.8464 0.13662E-10 -10.8645 0.95919E+00 -0.0181 61 MgOH+ 0.20904E-08 -8.6798 0.20051E-08 -8.6979 0.95919E+00 -0.0181 63 MnO,aq 0.27733E-09 -9.5570 0.27733E-09 -9.5570 0.10000E+01 0.0000 64 MnOH+ 0.11688E-07 -7.9323 0.11211E-07 -7.9503 0.95919E+00 -0.0181 65 MnO2-2 0.53760E-16 -16.2695 0.48016E-16 -16.3186 0.89316E+00 -0.0491 66 HMnO2- 0.15185E-12 -12.8186 0.14564E-12 -12.8367 0.95915E+00 -0.0181 69 MnCl+ 0.43606E-10 -10.3604 0.41827E-10 -10.3785 0.95919E+00 -0.0181 70 MnSO4,aq 0.33590E-09 -9.4738 0.33590E-09 -9.4738 0.10000E+01 0.0000 71 NaCl,aq 0.93164E-08 -8.0308 0.93164E-08 -8.0308 0.10000E+01 0.0000 72 NaOH,aq 0.65928E-08 -8.1809 0.65928E-08 -8.1809 0.10000E+01 0.0000 74 OH- 0.43511E-04 -4.3614 0.41732E-04 -4.3795 0.95911E+00 -0.0181 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.69746E-09 -9.1565 0.66898E-09 -9.1746 0.95917E+00 -0.0181 84 PO4-3 0.19446E-12 -12.7112 0.15436E-12 -12.8115 0.79379E+00 -0.1003 87 H2P2O7-2 0.39289E-19 -19.4057 0.35091E-19 -19.4548 0.89316E+00 -0.0491 88 HP2O7-3 0.63831E-18 -18.1950 0.50611E-18 -18.2958 0.79288E+00 -0.1008 89 P2O7-4 0.13003E-19 -19.8859 0.87330E-20 -20.0588 0.67160E+00 -0.1729 90 H2S,aq 0.36029E-13 -13.4434 0.36025E-13 -13.4434 0.99991E+00 0.0000 97 SO3-2 0.16078E-14 -14.7938 0.14365E-14 -14.8427 0.89347E+00 -0.0489 98 HSO3- 0.12983E-14 -14.8866 0.12453E-14 -14.9047 0.95915E+00 -0.0181 99 HSO4- 0.31530E-09 -9.5013 0.30244E-09 -9.5194 0.95921E+00 -0.0181 101 S2O3-2 0.10740E-19 -19.9690 0.95926E-20 -20.0181 0.89316E+00 -0.0491 Charge balance for all species = 0.2239E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1443241E-07 -.7811085E-04 -.7872747E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999528E+06 0.0000 3 Cl- 0.1379631E-03 0.1379763E-03 0.4891451E+01 3.9804 4 SO4-- 0.2537791E-04 0.2550478E-04 0.2449918E+01 11.0728 5 HCO3- 0.1260526E-04 0.1307020E-04 0.7974707E+00 2.9412 6 HS- 0.8777848E-12 0.8329775E-10 0.2754698E-05 -4.2160 7 Al+++ 0.2266660E-20 0.3076971E-05 0.8301752E-01 2.8307 8 H4SiO4 0.3183339E-03 0.3408004E-03 0.3275468E+02 -3.4971 9 Ca++ 0.1907808E-04 0.1932642E-04 0.7745292E+00 10.9488 10 Mg++ 0.7882812E-07 0.8101742E-07 0.1969606E-02 8.5649 11 Fe++ 0.4660064E-09 0.1953348E-08 0.1090837E-03 6.3367 12 K+ 0.1039957E-04 0.1040356E-04 0.4067813E+00 2.8576 13 Na+ 0.2214916E-03 0.2215813E-03 0.5093879E+01 4.1860 14 Mn++ 0.5748033E-07 0.6982543E-07 0.3835895E-02 8.4278 15 HPO4-- 0.2932527E-08 0.3630184E-08 0.3484056E-03 7.1356 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7983273E-03 -.7810966E-04 -.7202176E-03 0.0000000E+00 2 H2O 0.5550764E+02 0.5550743E+02 0.2039930E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2686243E-04 0.2550439E-04 0.1358040E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1357957E-05 0.8329649E-10 -.1358040E-05 0.0000000E+00 7 Al+++ 0.1597763E-03 0.3076924E-05 0.1566994E-03 0.0000000E+00 8 H4SiO4 0.5102264E-03 0.3407952E-03 0.1694312E-03 0.0000000E+00 9 Ca++ 0.7082805E-04 0.1932613E-04 0.5150192E-04 0.0000000E+00 10 Mg++ 0.3888889E-04 0.8101618E-07 0.3880787E-04 0.0000000E+00 11 Fe++ 0.3493742E-04 0.1953319E-08 0.3493547E-04 0.0000000E+00 12 K+ 0.1040340E-04 0.1040340E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2215779E-03 0.2215779E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.8495912E-06 0.6982437E-07 0.7797668E-06 0.0000000E+00 15 HPO4-- 0.2899613E-06 0.3630128E-08 0.2863311E-06 0.0000000E+00 Chg. balance for solid moles: -.5665E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0490000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9544E-07 -7.020 0.4794E-04 -4.319 0.1678 0.1523E-04 clinochlore 0.7762E-05 -5.110 0.4314E-02 -2.365 15.10 0.1641E-02 daphnite 0.4814E-05 -5.317 0.3435E-02 -2.464 12.02 0.1041E-02 chlorite-Mn 0.1560E-06 -6.807 0.1106E-03 -3.956 0.3869 0.3523E-04 hematite 0.5432E-05 -5.265 0.8675E-03 -3.062 3.036 0.1644E-03 kaolinite 0.1459E-04 -4.836 0.3767E-02 -2.424 13.18 0.1450E-02 lawsonite 0.5102E-04 -4.292 0.1603E-01 -1.795 56.11 0.5171E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3781E+00 0.3781E+00 1.0000 -0.422 chlorite-Mn 0.1225E-01 0.1225E-01 1.0000 -1.912 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.028577 g Volume = 0.009517 cm3 Porosity: 99.0666% V(tot) - V(min): 0.10101E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0490000 g log = -1.3098 Original solution: 1000.0103000 g Original solution / Rock added: 20408.37 (Water/Rock Ratio), log = 4.3098 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3724E-04 1.0071 0.3827E-04 0.3800E-04 CH4,gas 0.6215E-15 1.0125 0.6421E-15 0.6342E-15 H2,gas 0.6272E-06 1.0005 0.6403E-06 0.6399E-06 H2S,gas 0.9744E-12 0.9960 0.9903E-12 0.9943E-12 S2,gas 0.8801E-31 1.0000 0.8980E-31 0.8980E-31 CO,gas 0.6400E-14 1.0000 0.6530E-14 0.6530E-14 SO3,gas 0.1610E-35 1.0000 0.1643E-35 0.1643E-35 SO2,gas 0.4011E-19 1.0000 0.4092E-19 0.4092E-19 HCl,gas 0.5806E-15 1.0000 0.5924E-15 0.5924E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.18578E-10 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.78 -6.12 -2.039 0.10443E+05 -4.417 3 CH4,gas 4.54 -12.35 -16.89 -4.223 0.28842E+05 -15.192 4 H2,gas 8.00 0.11 -7.89 -4.510 0.13476E+05 -6.194 5 H2S,gas -6.23 -19.93 -13.70 -6.852 0.23398E+05 -12.004 6 S2,gas -7.34 -40.08 -32.75 -5.038 0.55912E+05 -31.047 7 CO,gas 3.21 -12.67 -15.88 -4.887 0.27122E+05 -14.185 8 SO3,gas 17.12 -20.36 -37.48 -9.371 0.64002E+05 -35.784 9 SO2,gas 0.83 -20.25 -21.09 -5.623 0.36006E+05 -19.388 10 HCl,gas 5.19 -11.74 -16.93 -8.463 0.28901E+05 -15.227 11 acmite 7.71 3.47 -4.23 -0.440 0.72310E+04 15 albite-high 0.69 -3.47 -4.17 -0.321 0.71163E+04 16 albite -0.38 -3.47 -3.09 -0.238 0.52774E+04 19 spessartine 24.46 20.45 -4.00 -0.200 0.68364E+04 20 analcite 3.32 0.02 -3.30 -0.367 0.56336E+04 21 andalusite 5.00 2.16 -2.84 -0.284 0.48444E+04 22 andradite 39.01 34.92 -4.09 -0.212 0.69791E+04 23 grossular 32.73 28.02 -4.71 -0.236 0.80504E+04 24 anhydrite -5.32 -9.41 -4.10 -2.048 0.69944E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.83 -2.79 -0.931 0.47706E+04 36 brucite 12.57 8.56 -4.00 -0.801 0.68361E+04 37 calcite 0.81 -1.83 -2.64 -0.880 0.45064E+04 40 carpholite-Mg 8.58 7.23 -1.35 -0.090 0.23049E+04 41 carpholite-Fe 6.71 5.00 -1.71 -0.114 0.29176E+04 50 chloritoid-Mg 13.20 10.73 -2.47 -0.165 0.42147E+04 51 chloritoid-Fe 9.17 8.50 -0.67 -0.045 0.11485E+04 52 chloritoid-Mn 11.40 10.59 -0.81 -0.054 0.13812E+04 54 coesite -2.38 -3.50 -1.12 -0.374 0.19142E+04 59 corundum 8.38 5.66 -2.72 -0.247 0.46471E+04 61 cristobalite -2.56 -3.50 -0.94 -0.312 0.15995E+04 65 diaspore 2.87 2.83 -0.04 -0.007 0.73360E+02 67 diopside 16.18 12.52 -3.66 -0.366 0.62524E+04 68 hedenbergite 14.21 10.29 -3.92 -0.392 0.66882E+04 75 epidote 24.67 23.35 -1.32 -0.064 0.22522E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.80 -3.04 -0.158 0.51865E+04 78 fayalite 14.05 9.18 -4.87 -0.696 0.83146E+04 83 gibbsite 4.08 2.83 -1.25 -0.178 0.21319E+04 87 greenalite 16.14 12.02 -4.12 -0.344 0.70412E+04 91 heulandite -5.83 -7.87 -2.04 -0.093 0.34871E+04 95 jadeite 4.22 0.02 -4.19 -0.419 0.71591E+04 99 kyanite 4.88 2.16 -2.71 -0.271 0.46303E+04 101 laumontite 2.88 2.62 -0.26 -0.017 0.44663E+03 105 lizardite 23.24 18.70 -4.54 -0.379 0.77575E+04 106 magnesite 0.69 -4.21 -4.90 -1.634 0.83699E+04 107 magnetite 20.09 18.90 -1.18 -0.097 0.20226E+04 113 margarite 17.32 15.28 -2.05 -0.082 0.34936E+04 116 microcline -2.49 -4.80 -2.32 -0.178 0.39553E+04 120 muscovite 2.58 0.86 -1.72 -0.101 0.29436E+04 121 paragonite 4.24 2.19 -2.05 -0.121 0.35048E+04 122 nepheline 8.34 3.52 -4.82 -0.689 0.82298E+04 136 prehnite 19.37 17.07 -2.30 -0.136 0.39342E+04 137 prehnite-Fe 22.50 20.52 -1.98 -0.119 0.33769E+04 138 pumpellyite-Fe 46.27 43.30 -2.97 -0.066 0.50651E+04 139 pumpellyite-Mg 48.99 45.53 -3.46 -0.077 0.59140E+04 145 pyroxmangite 7.40 4.93 -2.47 -0.494 0.42140E+04 146 pyrophyllite -6.18 -8.33 -2.15 -0.134 0.36731E+04 147 quartz -2.99 -3.50 -0.51 -0.169 0.86685E+03 151 rhodochrosite -0.98 -4.35 -3.37 -1.124 0.57578E+04 152 rhodonite 7.45 4.93 -2.51 -0.503 0.42943E+04 153 sanidine -1.28 -4.80 -3.53 -0.271 0.60231E+04 155 siderite -2.61 -6.44 -3.83 -1.277 0.65421E+04 156 sillimanite 5.26 2.16 -3.10 -0.310 0.52883E+04 163 stilbite -7.52 -7.87 -0.35 -0.017 0.59328E+03 164 stilpnomelane-Fe 13.02 10.80 -2.22 -0.066 0.37911E+04 167 sudoite-Fe 18.30 13.50 -4.79 -0.155 0.81810E+04 168 sudoite 21.08 17.96 -3.12 -0.101 0.53203E+04 171 talc 16.49 11.71 -4.78 -0.281 0.81698E+04 174 tephroite 18.09 13.36 -4.73 -0.675 0.80718E+04 177 topaz-H 4.62 2.16 -2.45 -0.223 0.41904E+04 178 tridymite -2.63 -3.50 -0.87 -0.290 0.14868E+04 187 wairakite 3.95 2.62 -1.33 -0.078 0.22686E+04 188 walstromite 11.51 7.45 -4.06 -0.812 0.69281E+04 189 wollastonite 10.46 7.45 -3.01 -0.602 0.51385E+04 190 pseudo-wollastonite 11.00 7.45 -3.55 -0.710 0.60583E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.43 -2.79 -0.172 0.47581E+04 194 beidellite-H -2.33 -6.24 -3.91 -0.250 0.66806E+04 195 beidellite-K -1.52 -5.30 -3.78 -0.231 0.64467E+04 196 beidellite-Mg -1.79 -4.83 -3.04 -0.188 0.51836E+04 197 beidellite-Na -1.34 -4.86 -3.52 -0.215 0.60021E+04 199 chalcedony -2.80 -3.50 -0.69 -0.232 0.11862E+04 201 montmorillonite-Ca -2.29 -4.63 -2.34 -0.145 0.39911E+04 202 montmorillonite-K -2.24 -5.49 -3.25 -0.199 0.55578E+04 203 montmorillonite-Mg -2.48 -5.02 -2.54 -0.157 0.43397E+04 204 montmorillonite-Na -2.04 -5.05 -3.02 -0.185 0.51490E+04 205 nontronite-Ca 3.21 2.47 -0.74 -0.048 0.12671E+04 206 nontronite-H 2.53 0.67 -1.87 -0.125 0.31875E+04 207 nontronite-K 3.34 1.61 -1.73 -0.111 0.29570E+04 208 nontronite-Mg 3.07 2.08 -1.00 -0.065 0.16998E+04 209 nontronite-Na 3.52 2.05 -1.47 -0.095 0.25141E+04 214 gypsum -4.96 -9.41 -4.46 -1.115 0.76120E+04 224 tobermorite 9.82 5.62 -4.20 -1.146 0.71710E+04 233 boehmite 4.41 2.83 -1.58 -0.263 0.26903E+04 235 ferrous-oxide 9.81 6.34 -3.47 -0.869 0.59333E+04 240 silica-amorphous -2.09 -3.50 -1.41 -0.469 0.24003E+04 242 an20ab80 2.02 -0.86 -2.87 -0.221 0.49078E+04 243 an25ab75 2.65 -0.20 -2.85 -0.219 0.48623E+04 244 an30ab70 3.28 0.45 -2.83 -0.217 0.48265E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0490000 g New total amount of reactant added: 0.0510000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0510000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2953573E-03 Osmotic coef. = 0.9897 True ionic strength = .3164057E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14222E-07 -7.8470 0.13642E-07 -7.8651 0.95924E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13232E-03 -3.8784 0.95910E+00 -0.0181 4 SO4-- 0.25381E-04 -4.5955 0.22667E-04 -4.6446 0.89304E+00 -0.0491 5 HCO3- 0.12609E-04 -4.8993 0.12094E-04 -4.9174 0.95914E+00 -0.0181 6 HS- 0.81225E-12 -12.0903 0.77904E-12 -12.1084 0.95911E+00 -0.0181 7 Al+++ 0.20876E-20 -20.6804 0.16545E-20 -20.7813 0.79254E+00 -0.1010 8 H4SiO4 0.33081E-03 -3.4804 0.33081E-03 -3.4804 0.10000E+01 0.0000 9 Ca++ 0.18527E-04 -4.7322 0.16542E-04 -4.7814 0.89289E+00 -0.0492 10 Mg++ 0.75962E-07 -7.1194 0.67819E-07 -7.1686 0.89280E+00 -0.0492 11 Fe++ 0.44900E-09 -9.3478 0.40087E-09 -9.3970 0.89282E+00 -0.0492 12 K+ 0.10824E-04 -4.9656 0.10382E-04 -4.9837 0.95914E+00 -0.0181 13 Na+ 0.22400E-03 -3.6498 0.21484E-03 -3.6679 0.95910E+00 -0.0181 14 Mn++ 0.55711E-07 -7.2541 0.49741E-07 -7.3033 0.89284E+00 -0.0492 15 HPO4-- 0.30209E-08 -8.5199 0.26978E-08 -8.5690 0.89304E+00 -0.0491 16 HSiO3- 0.23608E-04 -4.6269 0.22643E-04 -4.6451 0.95910E+00 -0.0181 17 Ca(HSiO3)+ 0.88936E-08 -8.0509 0.85303E-08 -8.0690 0.95915E+00 -0.0181 18 Mg(HSiO3)+ 0.45377E-10 -10.3432 0.43523E-10 -10.3613 0.95915E+00 -0.0181 19 NaHSiO3,aq 0.78677E-07 -7.1042 0.78677E-07 -7.1042 0.10000E+01 0.0000 20 AlO+ 0.12610E-11 -11.8993 0.12094E-11 -11.9174 0.95915E+00 -0.0181 21 AlOH+2 0.92015E-16 -16.0361 0.82156E-16 -16.0854 0.89286E+00 -0.0492 22 HAlO2,aq 0.17656E-07 -7.7531 0.17656E-07 -7.7531 0.10000E+01 0.0000 23 AlO2- 0.29871E-05 -5.5247 0.28648E-05 -5.5429 0.95906E+00 -0.0182 24 CH4,aq 0.40381E-18 -18.3938 0.40377E-18 -18.3939 0.99991E+00 0.0000 29 CO,aq 0.42516E-17 -17.3714 0.42516E-17 -17.3714 0.10000E+01 0.0000 30 CO2,aq 0.35258E-06 -6.4527 0.35254E-06 -6.4528 0.99991E+00 0.0000 31 CO3-2 0.86715E-07 -7.0619 0.77436E-07 -7.1111 0.89300E+00 -0.0492 32 CaCO3,aq 0.16062E-07 -7.7942 0.16062E-07 -7.7942 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53244E-08 -8.2737 0.51069E-08 -8.2918 0.95915E+00 -0.0181 34 CaCl+ 0.36932E-08 -8.4326 0.35423E-08 -8.4507 0.95915E+00 -0.0181 35 CaCl2,aq 0.11136E-12 -12.9533 0.11136E-12 -12.9533 0.10000E+01 0.0000 36 CaOH+ 0.90103E-07 -7.0453 0.86422E-07 -7.0634 0.95915E+00 -0.0181 37 CaSO4,aq 0.11907E-06 -6.9242 0.11907E-06 -6.9242 0.10000E+01 0.0000 38 HCl,aq 0.33078E-12 -12.4805 0.33078E-12 -12.4805 0.10000E+01 0.0000 43 FeCl+ 0.87536E-13 -13.0578 0.83960E-13 -13.0759 0.95915E+00 -0.0181 46 FeO,aq 0.83718E-10 -10.0772 0.83718E-10 -10.0772 0.10000E+01 0.0000 47 FeOH+ 0.99726E-09 -9.0012 0.95652E-09 -9.0193 0.95915E+00 -0.0181 48 HFeO2- 0.66948E-10 -10.1743 0.64210E-10 -10.1924 0.95910E+00 -0.0181 49 FeO+ 0.10856E-12 -12.9643 0.10413E-12 -12.9824 0.95915E+00 -0.0181 50 FeOH+2 0.30383E-18 -18.5174 0.27128E-18 -18.5666 0.89286E+00 -0.0492 51 FeO2- 0.11937E-09 -9.9231 0.11449E-09 -9.9412 0.95910E+00 -0.0181 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.48012E-09 -9.3187 0.48007E-09 -9.3187 0.99991E+00 0.0000 54 KCl,aq 0.24898E-10 -10.6038 0.24898E-10 -10.6038 0.10000E+01 0.0000 55 KHSO4,aq 0.90766E-17 -17.0421 0.90766E-17 -17.0421 0.10000E+01 0.0000 56 KOH,aq 0.32500E-09 -9.4881 0.32500E-09 -9.4881 0.10000E+01 0.0000 57 KSO4- 0.38073E-08 -8.4194 0.36516E-08 -8.4375 0.95910E+00 -0.0181 58 MgCO3,aq 0.16506E-10 -10.7824 0.16506E-10 -10.7824 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22305E-10 -10.6516 0.21394E-10 -10.6697 0.95915E+00 -0.0181 60 MgCl+ 0.13723E-10 -10.8626 0.13162E-10 -10.8807 0.95915E+00 -0.0181 61 MgOH+ 0.20440E-08 -8.6895 0.19605E-08 -8.7076 0.95915E+00 -0.0181 63 MnO,aq 0.27679E-09 -9.5578 0.27679E-09 -9.5578 0.10000E+01 0.0000 64 MnOH+ 0.11495E-07 -7.9395 0.11026E-07 -7.9576 0.95915E+00 -0.0181 65 MnO2-2 0.55273E-16 -16.2575 0.49359E-16 -16.3066 0.89300E+00 -0.0492 66 HMnO2- 0.15381E-12 -12.8130 0.14752E-12 -12.8311 0.95910E+00 -0.0181 69 MnCl+ 0.42257E-10 -10.3741 0.40530E-10 -10.3922 0.95915E+00 -0.0181 70 MnSO4,aq 0.32549E-09 -9.4875 0.32549E-09 -9.4875 0.10000E+01 0.0000 71 NaCl,aq 0.94209E-08 -8.0259 0.94209E-08 -8.0259 0.10000E+01 0.0000 72 NaOH,aq 0.67662E-08 -8.1697 0.67662E-08 -8.1697 0.10000E+01 0.0000 74 OH- 0.44160E-04 -4.3550 0.42353E-04 -4.3731 0.95906E+00 -0.0182 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.70786E-09 -9.1501 0.67893E-09 -9.1682 0.95913E+00 -0.0181 84 PO4-3 0.20335E-12 -12.6918 0.16135E-12 -12.7922 0.79346E+00 -0.1005 87 H2P2O7-2 0.40473E-19 -19.3928 0.36143E-19 -19.4420 0.89300E+00 -0.0492 88 HP2O7-3 0.66748E-18 -18.1756 0.52901E-18 -18.2765 0.79255E+00 -0.1010 89 P2O7-4 0.13804E-19 -19.8600 0.92640E-20 -20.0332 0.67110E+00 -0.1732 90 H2S,aq 0.32849E-13 -13.4835 0.32846E-13 -13.4835 0.99991E+00 0.0000 97 SO3-2 0.15830E-14 -14.8005 0.14141E-14 -14.8495 0.89330E+00 -0.0490 98 HSO3- 0.12593E-14 -14.8999 0.12078E-14 -14.9180 0.95910E+00 -0.0181 99 HSO4- 0.31068E-09 -9.5077 0.29800E-09 -9.5258 0.95917E+00 -0.0181 Charge balance for all species = 0.2240E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1422167E-07 -.7970629E-04 -.8033540E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999515E+06 0.0000 3 Cl- 0.1379632E-03 0.1379764E-03 0.4891447E+01 3.9868 4 SO4-- 0.2538136E-04 0.2550479E-04 0.2449917E+01 11.0856 5 HCO3- 0.1260949E-04 0.1307021E-04 0.7974701E+00 2.9477 6 HS- 0.8122512E-12 0.8110964E-10 0.2682332E-05 -4.2433 7 Al+++ 0.2087569E-20 0.3004777E-05 0.8106961E-01 2.8140 8 H4SiO4 0.3308147E-03 0.3545108E-03 0.3407235E+02 -3.4804 9 Ca++ 0.1852673E-04 0.1876987E-04 0.7522237E+00 10.9488 10 Mg++ 0.7596236E-07 0.7810431E-07 0.1898783E-02 8.5616 11 Fe++ 0.4489987E-09 0.1915136E-08 0.1069496E-03 6.3333 12 K+ 0.1082404E-04 0.1082820E-04 0.4233843E+00 2.8814 13 Na+ 0.2239971E-03 0.2240920E-03 0.5151589E+01 4.1972 14 Mn++ 0.5571132E-07 0.6785120E-07 0.3727435E-02 8.4270 15 HPO4-- 0.3020922E-08 0.3728989E-08 0.3578879E-03 7.1613 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8314443E-03 -.7970503E-04 -.7517393E-03 0.0000000E+00 2 H2O 0.5550761E+02 0.5550740E+02 0.2131839E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2691785E-04 0.2550439E-04 0.1413465E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1413384E-05 0.8110836E-10 -.1413465E-05 0.0000000E+00 7 Al+++ 0.1662978E-03 0.3004730E-05 0.1632931E-03 0.0000000E+00 8 H4SiO4 0.5310519E-03 0.3545052E-03 0.1765468E-03 0.0000000E+00 9 Ca++ 0.7312834E-04 0.1876957E-04 0.5435876E-04 0.0000000E+00 10 Mg++ 0.4047619E-04 0.7810307E-07 0.4039809E-04 0.0000000E+00 11 Fe++ 0.3636344E-04 0.1915105E-08 0.3636152E-04 0.0000000E+00 12 K+ 0.1082803E-04 0.1082803E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2240884E-03 0.2240884E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.8842684E-06 0.6785013E-07 0.8164183E-06 0.0000000E+00 15 HPO4-- 0.3017964E-06 0.3728930E-08 0.2980675E-06 0.0000000E+00 Chg. balance for solid moles: 0.1056E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0510000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9936E-07 -7.003 0.4991E-04 -4.302 0.1674 0.1586E-04 clinochlore 0.8080E-05 -5.093 0.4491E-02 -2.348 15.06 0.1708E-02 daphnite 0.5011E-05 -5.300 0.3575E-02 -2.447 11.99 0.1083E-02 chlorite-Mn 0.1633E-06 -6.787 0.1158E-03 -3.936 0.3883 0.3689E-04 hematite 0.5654E-05 -5.248 0.9029E-03 -3.044 3.029 0.1711E-03 kaolinite 0.1453E-04 -4.838 0.3751E-02 -2.426 12.58 0.1443E-02 lawsonite 0.5386E-04 -4.269 0.1693E-01 -1.771 56.78 0.5458E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3781E+00 0.3781E+00 1.0000 -0.422 chlorite-Mn 0.1232E-01 0.1232E-01 1.0000 -1.909 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.029812 g Volume = 0.009917 cm3 Porosity: 99.0281% V(tot) - V(min): 0.10105E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0510000 g log = -1.2924 Original solution: 1000.0103000 g Original solution / Rock added: 19608.05 (Water/Rock Ratio), log = 4.2924 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3671E-04 1.0071 0.3772E-04 0.3745E-04 CH4,gas 0.5753E-15 1.0125 0.5943E-15 0.5870E-15 H2,gas 0.6174E-06 1.0005 0.6303E-06 0.6299E-06 H2S,gas 0.8884E-12 0.9960 0.9029E-12 0.9065E-12 S2,gas 0.7550E-31 1.0000 0.7703E-31 0.7703E-31 CO,gas 0.6209E-14 1.0000 0.6336E-14 0.6336E-14 SO3,gas 0.1563E-35 1.0000 0.1595E-35 0.1595E-35 SO2,gas 0.3833E-19 1.0000 0.3911E-19 0.3911E-19 HCl,gas 0.5720E-15 1.0000 0.5837E-15 0.5837E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.17819E-10 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.78 -6.12 -2.041 0.10454E+05 -4.423 3 CH4,gas 4.54 -12.38 -16.92 -4.231 0.28899E+05 -15.226 4 H2,gas 8.00 0.10 -7.90 -4.514 0.13488E+05 -6.200 5 H2S,gas -6.23 -19.97 -13.74 -6.872 0.23466E+05 -12.044 6 S2,gas -7.34 -40.15 -32.81 -5.048 0.56026E+05 -31.113 7 CO,gas 3.21 -12.68 -15.90 -4.891 0.27144E+05 -14.198 8 SO3,gas 17.12 -20.37 -37.50 -9.374 0.64024E+05 -35.797 9 SO2,gas 0.83 -20.27 -21.11 -5.628 0.36039E+05 -19.408 10 HCl,gas 5.19 -11.74 -16.93 -8.466 0.28912E+05 -15.234 11 acmite 7.71 3.52 -4.19 -0.435 0.71547E+04 15 albite-high 0.69 -3.43 -4.12 -0.317 0.70400E+04 16 albite -0.38 -3.43 -3.05 -0.234 0.52012E+04 19 spessartine 24.46 20.47 -3.99 -0.199 0.68122E+04 20 analcite 3.32 0.05 -3.27 -0.363 0.55859E+04 21 andalusite 5.00 2.15 -2.85 -0.285 0.48729E+04 22 andradite 39.01 34.97 -4.04 -0.210 0.68936E+04 23 grossular 32.73 28.03 -4.70 -0.235 0.80219E+04 24 anhydrite -5.32 -9.43 -4.11 -2.055 0.70164E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.83 -2.80 -0.933 0.47813E+04 36 brucite 12.57 8.56 -4.01 -0.801 0.68418E+04 37 calcite 0.81 -1.83 -2.65 -0.882 0.45171E+04 40 carpholite-Mg 8.58 7.23 -1.35 -0.090 0.23107E+04 41 carpholite-Fe 6.71 5.00 -1.71 -0.114 0.29235E+04 50 chloritoid-Mg 13.20 10.71 -2.49 -0.166 0.42490E+04 51 chloritoid-Fe 9.17 8.48 -0.69 -0.046 0.11828E+04 52 chloritoid-Mn 11.40 10.57 -0.83 -0.055 0.14112E+04 54 coesite -2.38 -3.48 -1.10 -0.368 0.18857E+04 59 corundum 8.38 5.63 -2.76 -0.250 0.47042E+04 61 cristobalite -2.56 -3.48 -0.92 -0.307 0.15710E+04 65 diaspore 2.87 2.81 -0.06 -0.010 0.10188E+03 67 diopside 16.18 12.55 -3.63 -0.363 0.62011E+04 68 hedenbergite 14.21 10.32 -3.89 -0.389 0.66370E+04 75 epidote 24.67 23.37 -1.30 -0.063 0.22237E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.84 -3.00 -0.156 0.51295E+04 78 fayalite 14.05 9.19 -4.86 -0.694 0.82977E+04 83 gibbsite 4.08 2.81 -1.27 -0.181 0.21604E+04 87 greenalite 16.14 12.04 -4.10 -0.342 0.70016E+04 91 heulandite -5.83 -7.79 -1.96 -0.089 0.33445E+04 95 jadeite 4.22 0.05 -4.16 -0.416 0.71114E+04 99 kyanite 4.88 2.15 -2.73 -0.273 0.46588E+04 101 laumontite 2.88 2.66 -0.23 -0.015 0.38959E+03 105 lizardite 23.24 18.72 -4.52 -0.377 0.77176E+04 106 magnesite 0.69 -4.22 -4.91 -1.637 0.83863E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20284E+04 113 margarite 17.32 15.24 -2.08 -0.083 0.35507E+04 116 microcline -2.49 -4.75 -2.26 -0.174 0.38577E+04 120 muscovite 2.58 0.88 -1.70 -0.100 0.29030E+04 121 paragonite 4.24 2.20 -2.04 -0.120 0.34856E+04 122 nepheline 8.34 3.53 -4.81 -0.687 0.82106E+04 136 prehnite 19.37 17.08 -2.29 -0.135 0.39056E+04 137 prehnite-Fe 22.50 20.55 -1.94 -0.117 0.33198E+04 138 pumpellyite-Fe 46.27 43.32 -2.95 -0.066 0.50424E+04 139 pumpellyite-Mg 48.99 45.54 -3.45 -0.077 0.58912E+04 145 pyroxmangite 7.40 4.95 -2.45 -0.490 0.41870E+04 146 pyrophyllite -6.18 -8.29 -2.12 -0.132 0.36161E+04 147 quartz -2.99 -3.48 -0.49 -0.164 0.83834E+03 151 rhodochrosite -0.98 -4.36 -3.38 -1.126 0.57700E+04 152 rhodonite 7.45 4.95 -2.50 -0.500 0.42672E+04 153 sanidine -1.28 -4.75 -3.47 -0.267 0.59255E+04 155 siderite -2.61 -6.45 -3.84 -1.280 0.65587E+04 156 sillimanite 5.26 2.15 -3.11 -0.311 0.53169E+04 163 stilbite -7.52 -7.79 -0.26 -0.013 0.45069E+03 164 stilpnomelane-Fe 13.02 10.89 -2.13 -0.063 0.36288E+04 167 sudoite-Fe 18.30 13.48 -4.81 -0.155 0.82212E+04 168 sudoite 21.08 17.94 -3.14 -0.101 0.53602E+04 171 talc 16.49 11.76 -4.73 -0.278 0.80728E+04 174 tephroite 18.09 13.37 -4.71 -0.673 0.80461E+04 177 topaz-H 4.62 2.15 -2.47 -0.225 0.42189E+04 178 tridymite -2.63 -3.48 -0.85 -0.285 0.14583E+04 187 wairakite 3.95 2.66 -1.30 -0.076 0.22116E+04 188 walstromite 11.51 7.47 -4.04 -0.808 0.68996E+04 189 wollastonite 10.46 7.47 -2.99 -0.599 0.51100E+04 190 pseudo-wollastonite 11.00 7.47 -3.53 -0.706 0.60298E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.41 -2.76 -0.171 0.47199E+04 194 beidellite-H -2.33 -6.22 -3.89 -0.248 0.66424E+04 195 beidellite-K -1.52 -5.27 -3.75 -0.229 0.63951E+04 196 beidellite-Mg -1.79 -4.80 -3.01 -0.186 0.51463E+04 197 beidellite-Na -1.34 -4.83 -3.49 -0.214 0.59576E+04 199 chalcedony -2.80 -3.48 -0.68 -0.226 0.11576E+04 201 montmorillonite-Ca -2.29 -4.59 -2.30 -0.142 0.39265E+04 202 montmorillonite-K -2.24 -5.45 -3.21 -0.197 0.54798E+04 203 montmorillonite-Mg -2.48 -4.98 -2.50 -0.155 0.42761E+04 204 montmorillonite-Na -2.04 -5.01 -2.97 -0.182 0.50781E+04 205 nontronite-Ca 3.21 2.53 -0.69 -0.045 0.11718E+04 206 nontronite-H 2.53 0.72 -1.81 -0.121 0.30922E+04 207 nontronite-K 3.34 1.67 -1.67 -0.107 0.28483E+04 208 nontronite-Mg 3.07 2.13 -0.94 -0.061 0.16055E+04 209 nontronite-Na 3.52 2.11 -1.41 -0.091 0.24125E+04 214 gypsum -4.96 -9.43 -4.47 -1.118 0.76339E+04 224 tobermorite 9.82 5.64 -4.18 -1.141 0.71425E+04 233 boehmite 4.41 2.81 -1.59 -0.265 0.27188E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.870 0.59392E+04 240 silica-amorphous -2.09 -3.48 -1.39 -0.463 0.23718E+04 242 an20ab80 2.02 -0.82 -2.84 -0.218 0.48468E+04 243 an25ab75 2.65 -0.17 -2.81 -0.216 0.48051E+04 244 an30ab70 3.28 0.48 -2.80 -0.215 0.47731E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0510000 g New total amount of reactant added: 0.0530000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0530000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2954429E-03 Osmotic coef. = 0.9897 True ionic strength = .3177289E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14015E-07 -7.8534 0.13443E-07 -7.8715 0.95919E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13231E-03 -3.8784 0.95906E+00 -0.0182 4 SO4-- 0.25385E-04 -4.5954 0.22665E-04 -4.6446 0.89287E+00 -0.0492 5 HCO3- 0.12614E-04 -4.8992 0.12098E-04 -4.9173 0.95909E+00 -0.0181 6 HS- 0.75355E-12 -12.1229 0.72270E-12 -12.1410 0.95906E+00 -0.0182 7 Al+++ 0.19260E-20 -20.7153 0.15258E-20 -20.8165 0.79220E+00 -0.1012 8 H4SiO4 0.34327E-03 -3.4644 0.34327E-03 -3.4644 0.10000E+01 0.0000 9 Ca++ 0.17995E-04 -4.7449 0.16064E-04 -4.7941 0.89272E+00 -0.0493 10 Mg++ 0.73236E-07 -7.1353 0.65372E-07 -7.1846 0.89262E+00 -0.0493 11 Fe++ 0.43283E-09 -9.3637 0.38636E-09 -9.4130 0.89264E+00 -0.0493 12 K+ 0.11249E-04 -4.9489 0.10788E-04 -4.9670 0.95910E+00 -0.0181 13 Na+ 0.22650E-03 -3.6449 0.21723E-03 -3.6631 0.95905E+00 -0.0182 14 Mn++ 0.53995E-07 -7.2676 0.48199E-07 -7.3170 0.89266E+00 -0.0493 15 HPO4-- 0.31114E-08 -8.5070 0.27781E-08 -8.5562 0.89287E+00 -0.0492 16 HSiO3- 0.24861E-04 -4.6045 0.23843E-04 -4.6226 0.95906E+00 -0.0182 17 Ca(HSiO3)+ 0.90947E-08 -8.0412 0.87227E-08 -8.0593 0.95910E+00 -0.0181 18 Mg(HSiO3)+ 0.46060E-10 -10.3367 0.44176E-10 -10.3548 0.95910E+00 -0.0181 19 NaHSiO3,aq 0.83769E-07 -7.0769 0.83769E-07 -7.0769 0.10000E+01 0.0000 20 AlO+ 0.11976E-11 -11.9217 0.11486E-11 -11.9398 0.95910E+00 -0.0181 21 AlOH+2 0.86129E-16 -16.0649 0.76885E-16 -16.1142 0.89268E+00 -0.0493 22 HAlO2,aq 0.17015E-07 -7.7692 0.17015E-07 -7.7692 0.10000E+01 0.0000 23 AlO2- 0.29214E-05 -5.5344 0.28017E-05 -5.5526 0.95902E+00 -0.0182 24 CH4,aq 0.37474E-18 -18.4263 0.37470E-18 -18.4263 0.99991E+00 0.0000 29 CO,aq 0.41281E-17 -17.3842 0.41281E-17 -17.3842 0.10000E+01 0.0000 30 CO2,aq 0.34754E-06 -6.4590 0.34751E-06 -6.4590 0.99991E+00 0.0000 31 CO3-2 0.88037E-07 -7.0553 0.78602E-07 -7.1046 0.89282E+00 -0.0492 32 CaCO3,aq 0.15833E-07 -7.8004 0.15833E-07 -7.8004 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.51722E-08 -8.2863 0.49607E-08 -8.3045 0.95910E+00 -0.0181 34 CaCl+ 0.35865E-08 -8.4453 0.34398E-08 -8.4635 0.95910E+00 -0.0181 35 CaCl2,aq 0.10813E-12 -12.9661 0.10813E-12 -12.9661 0.10000E+01 0.0000 36 CaOH+ 0.88795E-07 -7.0516 0.85163E-07 -7.0697 0.95910E+00 -0.0181 37 CaSO4,aq 0.11562E-06 -6.9370 0.11562E-06 -6.9370 0.10000E+01 0.0000 38 HCl,aq 0.32595E-12 -12.4868 0.32595E-12 -12.4868 0.10000E+01 0.0000 43 FeCl+ 0.84367E-13 -13.0738 0.80917E-13 -13.0920 0.95910E+00 -0.0181 46 FeO,aq 0.83089E-10 -10.0805 0.83089E-10 -10.0805 0.10000E+01 0.0000 47 FeOH+ 0.97541E-09 -9.0108 0.93552E-09 -9.0289 0.95910E+00 -0.0181 48 HFeO2- 0.67429E-10 -10.1712 0.64669E-10 -10.1893 0.95906E+00 -0.0182 49 FeO+ 0.10699E-12 -12.9707 0.10261E-12 -12.9888 0.95910E+00 -0.0181 50 FeOH+2 0.29510E-18 -18.5300 0.26343E-18 -18.5793 0.89268E+00 -0.0493 51 FeO2- 0.12114E-09 -9.9167 0.11618E-09 -9.9349 0.95906E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.47293E-09 -9.3252 0.47289E-09 -9.3252 0.99991E+00 0.0000 54 KCl,aq 0.25872E-10 -10.5872 0.25872E-10 -10.5872 0.10000E+01 0.0000 55 KHSO4,aq 0.92942E-17 -17.0318 0.92942E-17 -17.0318 0.10000E+01 0.0000 56 KOH,aq 0.34272E-09 -9.4651 0.34272E-09 -9.4651 0.10000E+01 0.0000 57 KSO4- 0.39564E-08 -8.4027 0.37944E-08 -8.4209 0.95906E+00 -0.0182 58 MgCO3,aq 0.16150E-10 -10.7918 0.16150E-10 -10.7918 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21507E-10 -10.6674 0.20628E-10 -10.6856 0.95910E+00 -0.0181 60 MgCl+ 0.13228E-10 -10.8785 0.12687E-10 -10.8966 0.95910E+00 -0.0181 61 MgOH+ 0.19995E-08 -8.6991 0.19177E-08 -8.7172 0.95910E+00 -0.0181 63 MnO,aq 0.27619E-09 -9.5588 0.27619E-09 -9.5588 0.10000E+01 0.0000 64 MnOH+ 0.11304E-07 -7.9468 0.10842E-07 -7.9649 0.95910E+00 -0.0181 65 MnO2-2 0.56807E-16 -16.2456 0.50718E-16 -16.2948 0.89282E+00 -0.0492 66 HMnO2- 0.15575E-12 -12.8076 0.14938E-12 -12.8257 0.95906E+00 -0.0182 69 MnCl+ 0.40946E-10 -10.3878 0.39272E-10 -10.4059 0.95910E+00 -0.0181 70 MnSO4,aq 0.31538E-09 -9.5012 0.31538E-09 -9.5012 0.10000E+01 0.0000 71 NaCl,aq 0.95253E-08 -8.0211 0.95253E-08 -8.0211 0.10000E+01 0.0000 72 NaOH,aq 0.69426E-08 -8.1585 0.69426E-08 -8.1585 0.10000E+01 0.0000 74 OH- 0.44815E-04 -4.3486 0.42978E-04 -4.3668 0.95902E+00 -0.0182 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.71835E-09 -9.1437 0.68896E-09 -9.1618 0.95908E+00 -0.0181 84 PO4-3 0.21259E-12 -12.6725 0.16861E-12 -12.7731 0.79312E+00 -0.1007 87 H2P2O7-2 0.41686E-19 -19.3800 0.37218E-19 -19.4292 0.89282E+00 -0.0492 88 HP2O7-3 0.69781E-18 -18.1563 0.55281E-18 -18.2574 0.79220E+00 -0.1012 89 P2O7-4 0.14649E-19 -19.8342 0.98237E-20 -20.0077 0.67058E+00 -0.1735 90 H2S,aq 0.30030E-13 -13.5224 0.30027E-13 -13.5225 0.99991E+00 0.0000 97 SO3-2 0.15595E-14 -14.8070 0.13928E-14 -14.8561 0.89313E+00 -0.0491 98 HSO3- 0.12224E-14 -14.9128 0.11724E-14 -14.9309 0.95906E+00 -0.0182 99 HSO4- 0.30616E-09 -9.5141 0.29364E-09 -9.5322 0.95912E+00 -0.0181 Charge balance for all species = 0.2239E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1401530E-07 -.8135853E-04 -.8200057E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999501E+06 0.0000 3 Cl- 0.1379633E-03 0.1379764E-03 0.4891443E+01 3.9931 4 SO4-- 0.2538469E-04 0.2550481E-04 0.2449915E+01 11.0983 5 HCO3- 0.1261360E-04 0.1307021E-04 0.7974695E+00 2.9542 6 HS- 0.7535531E-12 0.7903035E-10 0.2613566E-05 -4.2695 7 Al+++ 0.1926050E-20 0.2938395E-05 0.7927850E-01 2.7980 8 H4SiO4 0.3432735E-03 0.3682271E-03 0.3539059E+02 -3.4644 9 Ca++ 0.1799470E-04 0.1823280E-04 0.7306990E+00 10.9488 10 Mg++ 0.7323643E-07 0.7533289E-07 0.1831405E-02 8.5584 11 Fe++ 0.4328286E-09 0.1878729E-08 0.1049163E-03 6.3300 12 K+ 0.1124851E-04 0.1125284E-04 0.4399873E+00 2.9044 13 Na+ 0.2265024E-03 0.2266026E-03 0.5209298E+01 4.2084 14 Mn++ 0.5399459E-07 0.6593119E-07 0.3621953E-02 8.4260 15 HPO4-- 0.3111445E-08 0.3830015E-08 0.3675833E-03 7.1867 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8645613E-03 -.8135719E-04 -.7832041E-03 0.0000000E+00 2 H2O 0.5550759E+02 0.5550736E+02 0.2223523E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2697328E-04 0.2550439E-04 0.1468890E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1468811E-05 0.7902905E-10 -.1468890E-05 0.0000000E+00 7 Al+++ 0.1728193E-03 0.2938347E-05 0.1698810E-03 0.0000000E+00 8 H4SiO4 0.5518775E-03 0.3682210E-03 0.1836565E-03 0.0000000E+00 9 Ca++ 0.7542862E-04 0.1823250E-04 0.5719612E-04 0.0000000E+00 10 Mg++ 0.4206349E-04 0.7533166E-07 0.4198816E-04 0.0000000E+00 11 Fe++ 0.3778946E-04 0.1878698E-08 0.3778758E-04 0.0000000E+00 12 K+ 0.1125265E-04 0.1125265E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2265989E-03 0.2265989E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.9189456E-06 0.6593010E-07 0.8530155E-06 0.0000000E+00 15 HPO4-- 0.3136316E-06 0.3829952E-08 0.3098016E-06 0.0000000E+00 Chg. balance for solid moles: -.9603E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0530000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1033E-06 -6.986 0.5187E-04 -4.285 0.1671 0.1648E-04 clinochlore 0.8398E-05 -5.076 0.4668E-02 -2.331 15.04 0.1775E-02 daphnite 0.5207E-05 -5.283 0.3715E-02 -2.430 11.97 0.1126E-02 chlorite-Mn 0.1706E-06 -6.768 0.1210E-03 -3.917 0.3896 0.3854E-04 hematite 0.5876E-05 -5.231 0.9383E-03 -3.028 3.022 0.1778E-03 kaolinite 0.1449E-04 -4.839 0.3739E-02 -2.427 12.05 0.1439E-02 lawsonite 0.5668E-04 -4.247 0.1781E-01 -1.749 57.37 0.5744E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3780E+00 0.3780E+00 1.0000 -0.422 chlorite-Mn 0.1238E-01 0.1238E-01 1.0000 -1.907 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.031045 g Volume = 0.010317 cm3 Porosity: 98.9897% V(tot) - V(min): 0.10109E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0530000 g log = -1.2757 Original solution: 1000.0103000 g Original solution / Rock added: 18868.12 (Water/Rock Ratio), log = 4.2757 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3618E-04 1.0071 0.3718E-04 0.3692E-04 CH4,gas 0.5339E-15 1.0125 0.5515E-15 0.5447E-15 H2,gas 0.6081E-06 1.0005 0.6208E-06 0.6205E-06 H2S,gas 0.8122E-12 0.9960 0.8254E-12 0.8287E-12 S2,gas 0.6503E-31 1.0000 0.6635E-31 0.6635E-31 CO,gas 0.6029E-14 1.0000 0.6152E-14 0.6152E-14 SO3,gas 0.1518E-35 1.0000 0.1549E-35 0.1549E-35 SO2,gas 0.3666E-19 1.0000 0.3741E-19 0.3741E-19 HCl,gas 0.5637E-15 1.0000 0.5751E-15 0.5751E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.79 -6.13 -2.043 0.10465E+05 -4.430 3 CH4,gas 4.54 -12.41 -16.96 -4.239 0.28954E+05 -15.258 4 H2,gas 8.00 0.09 -7.91 -4.518 0.13499E+05 -6.207 5 H2S,gas -6.23 -20.01 -13.78 -6.891 0.23533E+05 -12.083 6 S2,gas -7.34 -40.21 -32.88 -5.058 0.56137E+05 -31.178 7 CO,gas 3.21 -12.70 -15.91 -4.895 0.27166E+05 -14.211 8 SO3,gas 17.12 -20.39 -37.51 -9.377 0.64046E+05 -35.810 9 SO2,gas 0.83 -20.29 -21.13 -5.634 0.36072E+05 -19.427 10 HCl,gas 5.19 -11.75 -16.94 -8.470 0.28923E+05 -15.240 11 acmite 7.71 3.56 -4.15 -0.431 0.70808E+04 15 albite-high 0.69 -3.39 -4.08 -0.314 0.69661E+04 16 albite -0.38 -3.39 -3.00 -0.231 0.51272E+04 19 spessartine 24.46 20.48 -3.98 -0.199 0.67896E+04 20 analcite 3.32 0.08 -3.24 -0.360 0.55394E+04 21 andalusite 5.00 2.13 -2.87 -0.287 0.49003E+04 22 andradite 39.01 35.02 -3.99 -0.207 0.68113E+04 23 grossular 32.73 28.05 -4.68 -0.234 0.79944E+04 24 anhydrite -5.32 -9.44 -4.12 -2.061 0.70382E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.84 -2.81 -0.935 0.47920E+04 36 brucite 12.57 8.56 -4.01 -0.802 0.68473E+04 37 calcite 0.81 -1.84 -2.65 -0.884 0.45278E+04 40 carpholite-Mg 8.58 7.23 -1.36 -0.090 0.23162E+04 41 carpholite-Fe 6.71 5.00 -1.72 -0.114 0.29290E+04 42 celadonite 5.34 0.40 -4.94 -0.290 0.84319E+04 50 chloritoid-Mg 13.20 10.69 -2.51 -0.167 0.42819E+04 51 chloritoid-Fe 9.17 8.46 -0.71 -0.047 0.12158E+04 52 chloritoid-Mn 11.40 10.56 -0.84 -0.056 0.14402E+04 54 coesite -2.38 -3.46 -1.09 -0.363 0.18582E+04 59 corundum 8.38 5.60 -2.79 -0.253 0.47590E+04 61 cristobalite -2.56 -3.46 -0.90 -0.301 0.15436E+04 65 diaspore 2.87 2.80 -0.08 -0.013 0.12929E+03 67 diopside 16.18 12.58 -3.60 -0.360 0.61518E+04 68 hedenbergite 14.21 10.35 -3.86 -0.386 0.65877E+04 75 epidote 24.67 23.38 -1.29 -0.062 0.21963E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.87 -2.97 -0.154 0.50747E+04 78 fayalite 14.05 9.20 -4.85 -0.693 0.82815E+04 83 gibbsite 4.08 2.80 -1.28 -0.183 0.21878E+04 87 greenalite 16.14 12.06 -4.08 -0.340 0.69636E+04 91 heulandite -5.83 -7.71 -1.88 -0.085 0.32075E+04 95 jadeite 4.22 0.08 -4.14 -0.414 0.70649E+04 99 kyanite 4.88 2.13 -2.74 -0.274 0.46862E+04 101 laumontite 2.88 2.69 -0.20 -0.013 0.33477E+03 105 lizardite 23.24 18.75 -4.50 -0.375 0.76792E+04 106 magnesite 0.69 -4.23 -4.92 -1.640 0.84025E+04 107 magnetite 20.09 18.90 -1.19 -0.097 0.20340E+04 113 margarite 17.32 15.21 -2.11 -0.084 0.36055E+04 116 microcline -2.49 -4.69 -2.20 -0.170 0.37635E+04 120 muscovite 2.58 0.91 -1.68 -0.099 0.28637E+04 121 paragonite 4.24 2.21 -2.03 -0.119 0.34665E+04 122 nepheline 8.34 3.54 -4.80 -0.685 0.81915E+04 136 prehnite 19.37 17.10 -2.27 -0.134 0.38782E+04 137 prehnite-Fe 22.50 20.59 -1.91 -0.115 0.32650E+04 138 pumpellyite-Fe 46.27 43.33 -2.94 -0.065 0.50206E+04 139 pumpellyite-Mg 48.99 45.56 -3.44 -0.076 0.58693E+04 145 pyroxmangite 7.40 4.96 -2.44 -0.487 0.41611E+04 146 pyrophyllite -6.18 -8.26 -2.09 -0.130 0.35613E+04 147 quartz -2.99 -3.46 -0.47 -0.158 0.81092E+03 151 rhodochrosite -0.98 -4.36 -3.39 -1.129 0.57823E+04 152 rhodonite 7.45 4.96 -2.48 -0.497 0.42414E+04 153 sanidine -1.28 -4.69 -3.42 -0.263 0.58313E+04 155 siderite -2.61 -6.46 -3.85 -1.284 0.65749E+04 156 sillimanite 5.26 2.13 -3.13 -0.313 0.53443E+04 163 stilbite -7.52 -7.71 -0.18 -0.009 0.31362E+03 164 stilpnomelane-Fe 13.02 10.98 -2.03 -0.061 0.34726E+04 167 sudoite-Fe 18.30 13.46 -4.84 -0.156 0.82598E+04 168 sudoite 21.08 17.92 -3.16 -0.102 0.53986E+04 171 talc 16.49 11.82 -4.67 -0.275 0.79797E+04 174 tephroite 18.09 13.39 -4.70 -0.671 0.80219E+04 177 topaz-H 4.62 2.13 -2.49 -0.226 0.42463E+04 178 tridymite -2.63 -3.46 -0.84 -0.279 0.14309E+04 187 wairakite 3.95 2.69 -1.26 -0.074 0.21567E+04 188 walstromite 11.51 7.48 -4.02 -0.805 0.68721E+04 189 wollastonite 10.46 7.48 -2.98 -0.595 0.50826E+04 190 pseudo-wollastonite 11.00 7.48 -3.52 -0.703 0.60024E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.39 -2.74 -0.170 0.46832E+04 194 beidellite-H -2.33 -6.19 -3.87 -0.247 0.66057E+04 195 beidellite-K -1.52 -5.24 -3.72 -0.228 0.63453E+04 196 beidellite-Mg -1.79 -4.78 -2.99 -0.185 0.51105E+04 197 beidellite-Na -1.34 -4.81 -3.46 -0.212 0.59145E+04 199 chalcedony -2.80 -3.46 -0.66 -0.221 0.11302E+04 201 montmorillonite-Ca -2.29 -4.55 -2.26 -0.140 0.38645E+04 202 montmorillonite-K -2.24 -5.40 -3.17 -0.194 0.54048E+04 203 montmorillonite-Mg -2.48 -4.95 -2.47 -0.153 0.42150E+04 204 montmorillonite-Na -2.04 -4.97 -2.93 -0.180 0.50097E+04 205 nontronite-Ca 3.21 2.58 -0.63 -0.041 0.10803E+04 206 nontronite-H 2.53 0.78 -1.76 -0.118 0.30007E+04 207 nontronite-K 3.34 1.73 -1.61 -0.103 0.27438E+04 208 nontronite-Mg 3.07 2.19 -0.89 -0.058 0.15148E+04 209 nontronite-Na 3.52 2.16 -1.36 -0.087 0.23147E+04 214 gypsum -4.96 -9.44 -4.48 -1.121 0.76557E+04 224 tobermorite 9.82 5.66 -4.17 -1.137 0.71151E+04 233 boehmite 4.41 2.80 -1.61 -0.268 0.27462E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.870 0.59447E+04 240 silica-amorphous -2.09 -3.46 -1.37 -0.458 0.23444E+04 242 an20ab80 2.02 -0.79 -2.80 -0.216 0.47876E+04 243 an25ab75 2.65 -0.14 -2.78 -0.214 0.47497E+04 244 an30ab70 3.28 0.51 -2.77 -0.213 0.47214E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0530000 g New total amount of reactant added: 0.0550000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0550000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2955902E-03 Osmotic coef. = 0.9897 True ionic strength = .3191089E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13813E-07 -7.8597 0.13249E-07 -7.8778 0.95915E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13231E-03 -3.8784 0.95901E+00 -0.0182 4 SO4-- 0.25388E-04 -4.5954 0.22663E-04 -4.6447 0.89269E+00 -0.0493 5 HCO3- 0.12618E-04 -4.8990 0.12101E-04 -4.9172 0.95904E+00 -0.0182 6 HS- 0.70078E-12 -12.1544 0.67206E-12 -12.1726 0.95901E+00 -0.0182 7 Al+++ 0.17800E-20 -20.7496 0.14095E-20 -20.8509 0.79184E+00 -0.1014 8 H4SiO4 0.35571E-03 -3.4489 0.35571E-03 -3.4489 0.10000E+01 0.0000 9 Ca++ 0.17482E-04 -4.7574 0.15603E-04 -4.8068 0.89254E+00 -0.0494 10 Mg++ 0.70642E-07 -7.1509 0.63044E-07 -7.2004 0.89244E+00 -0.0494 11 Fe++ 0.41745E-09 -9.3794 0.37256E-09 -9.4288 0.89246E+00 -0.0494 12 K+ 0.11673E-04 -4.9328 0.11195E-04 -4.9510 0.95905E+00 -0.0182 13 Na+ 0.22901E-03 -3.6402 0.21962E-03 -3.6583 0.95901E+00 -0.0182 14 Mn++ 0.52331E-07 -7.2812 0.46705E-07 -7.3306 0.89248E+00 -0.0494 15 HPO4-- 0.32041E-08 -8.4943 0.28603E-08 -8.5436 0.89269E+00 -0.0493 16 HSiO3- 0.26141E-04 -4.5827 0.25069E-04 -4.6009 0.95901E+00 -0.0182 17 Ca(HSiO3)+ 0.92883E-08 -8.0321 0.89080E-08 -8.0502 0.95905E+00 -0.0182 18 Mg(HSiO3)+ 0.46706E-10 -10.3306 0.44794E-10 -10.3488 0.95905E+00 -0.0182 19 NaHSiO3,aq 0.89047E-07 -7.0504 0.89047E-07 -7.0504 0.10000E+01 0.0000 20 AlO+ 0.11390E-11 -11.9435 0.10924E-11 -11.9616 0.95905E+00 -0.0182 21 AlOH+2 0.80747E-16 -16.0929 0.72067E-16 -16.1423 0.89250E+00 -0.0494 22 HAlO2,aq 0.16420E-07 -7.7846 0.16420E-07 -7.7846 0.10000E+01 0.0000 23 AlO2- 0.28608E-05 -5.5435 0.27434E-05 -5.5617 0.95897E+00 -0.0182 24 CH4,aq 0.34860E-18 -18.4577 0.34856E-18 -18.4577 0.99991E+00 0.0000 29 CO,aq 0.40109E-17 -17.3968 0.40109E-17 -17.3968 0.10000E+01 0.0000 30 CO2,aq 0.34260E-06 -6.4652 0.34257E-06 -6.4652 0.99991E+00 0.0000 31 CO3-2 0.89371E-07 -7.0488 0.79776E-07 -7.0981 0.89264E+00 -0.0493 32 CaCO3,aq 0.15608E-07 -7.8067 0.15608E-07 -7.8067 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.50253E-08 -8.2988 0.48195E-08 -8.3170 0.95905E+00 -0.0182 34 CaCl+ 0.34835E-08 -8.4580 0.33408E-08 -8.4761 0.95905E+00 -0.0182 35 CaCl2,aq 0.10501E-12 -12.9788 0.10501E-12 -12.9788 0.10000E+01 0.0000 36 CaOH+ 0.87515E-07 -7.0579 0.83932E-07 -7.0761 0.95905E+00 -0.0182 37 CaSO4,aq 0.11229E-06 -6.9497 0.11229E-06 -6.9497 0.10000E+01 0.0000 38 HCl,aq 0.32122E-12 -12.4932 0.32122E-12 -12.4932 0.10000E+01 0.0000 43 FeCl+ 0.81352E-13 -13.0896 0.78021E-13 -13.1078 0.95905E+00 -0.0182 46 FeO,aq 0.82488E-10 -10.0836 0.82488E-10 -10.0836 0.10000E+01 0.0000 47 FeOH+ 0.95440E-09 -9.0203 0.91532E-09 -9.0384 0.95905E+00 -0.0182 48 HFeO2- 0.67928E-10 -10.1680 0.65144E-10 -10.1861 0.95901E+00 -0.0182 49 FeO+ 0.10545E-12 -12.9770 0.10113E-12 -12.9951 0.95905E+00 -0.0182 50 FeOH+2 0.28669E-18 -18.5426 0.25587E-18 -18.5920 0.89250E+00 -0.0494 51 FeO2- 0.12292E-09 -9.9104 0.11788E-09 -9.9285 0.95901E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.46612E-09 -9.3315 0.46608E-09 -9.3315 0.99991E+00 0.0000 54 KCl,aq 0.26845E-10 -10.5711 0.26845E-10 -10.5711 0.10000E+01 0.0000 55 KHSO4,aq 0.95042E-17 -17.0221 0.95042E-17 -17.0221 0.10000E+01 0.0000 56 KOH,aq 0.36085E-09 -9.4427 0.36085E-09 -9.4427 0.10000E+01 0.0000 57 KSO4- 0.41054E-08 -8.3866 0.39371E-08 -8.4048 0.95901E+00 -0.0182 58 MgCO3,aq 0.15807E-10 -10.8011 0.15807E-10 -10.8011 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20748E-10 -10.6830 0.19898E-10 -10.7012 0.95905E+00 -0.0182 60 MgCl+ 0.12757E-10 -10.8943 0.12234E-10 -10.9124 0.95905E+00 -0.0182 61 MgOH+ 0.19567E-08 -8.7085 0.18766E-08 -8.7266 0.95905E+00 -0.0182 63 MnO,aq 0.27554E-09 -9.5598 0.27554E-09 -9.5598 0.10000E+01 0.0000 64 MnOH+ 0.11115E-07 -7.9541 0.10660E-07 -7.9723 0.95905E+00 -0.0182 65 MnO2-2 0.58361E-16 -16.2339 0.52095E-16 -16.2832 0.89264E+00 -0.0493 66 HMnO2- 0.15768E-12 -12.8022 0.15121E-12 -12.8204 0.95901E+00 -0.0182 69 MnCl+ 0.39677E-10 -10.4015 0.38052E-10 -10.4196 0.95905E+00 -0.0182 70 MnSO4,aq 0.30558E-09 -9.5149 0.30558E-09 -9.5149 0.10000E+01 0.0000 71 NaCl,aq 0.96297E-08 -8.0164 0.96297E-08 -8.0164 0.10000E+01 0.0000 72 NaOH,aq 0.71220E-08 -8.1474 0.71220E-08 -8.1474 0.10000E+01 0.0000 74 OH- 0.45475E-04 -4.3422 0.43609E-04 -4.3604 0.95897E+00 -0.0182 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.72893E-09 -9.1373 0.69907E-09 -9.1555 0.95903E+00 -0.0182 84 PO4-3 0.22218E-12 -12.6533 0.17614E-12 -12.7541 0.79276E+00 -0.1009 87 H2P2O7-2 0.42927E-19 -19.3673 0.38319E-19 -19.4166 0.89264E+00 -0.0493 88 HP2O7-3 0.72932E-18 -18.1371 0.57750E-18 -18.2384 0.79184E+00 -0.1014 89 P2O7-4 0.15541E-19 -19.8085 0.10413E-19 -19.9824 0.67004E+00 -0.1739 90 H2S,aq 0.27522E-13 -13.5603 0.27519E-13 -13.5604 0.99991E+00 0.0000 97 SO3-2 0.15372E-14 -14.8133 0.13726E-14 -14.8624 0.89295E+00 -0.0492 98 HSO3- 0.11873E-14 -14.9254 0.11387E-14 -14.9436 0.95901E+00 -0.0182 99 HSO4- 0.30172E-09 -9.5204 0.28937E-09 -9.5385 0.95907E+00 -0.0181 Charge balance for all species = 0.2240E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1381330E-07 -.8306463E-04 -.8372002E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999487E+06 0.0000 3 Cl- 0.1379633E-03 0.1379765E-03 0.4891440E+01 3.9994 4 SO4-- 0.2538790E-04 0.2550483E-04 0.2449913E+01 11.1110 5 HCO3- 0.1261758E-04 0.1307022E-04 0.7974689E+00 2.9606 6 HS- 0.7007803E-12 0.7704989E-10 0.2548068E-05 -4.2948 7 Al+++ 0.1780039E-20 0.2877183E-05 0.7762688E-01 2.7825 8 H4SiO4 0.3557095E-03 0.3819486E-03 0.3670932E+02 -3.4489 9 Ca++ 0.1748151E-04 0.1771472E-04 0.7099354E+00 10.9488 10 Mg++ 0.7064227E-07 0.7269498E-07 0.1767273E-02 8.5553 11 Fe++ 0.4174467E-09 0.1844020E-08 0.1029779E-03 6.3268 12 K+ 0.1167299E-04 0.1167748E-04 0.4565903E+00 2.9268 13 Na+ 0.2290075E-03 0.2291133E-03 0.5267008E+01 4.2195 14 Mn++ 0.5233146E-07 0.6406724E-07 0.3519552E-02 8.4250 15 HPO4-- 0.3204080E-08 0.3933237E-08 0.3774895E-03 7.2120 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8976783E-03 -.8306322E-04 -.8146151E-03 0.0000000E+00 2 H2O 0.5550756E+02 0.5550733E+02 0.2314989E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2702871E-04 0.2550439E-04 0.1524315E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1524237E-05 0.7704858E-10 -.1524315E-05 0.0000000E+00 7 Al+++ 0.1793408E-03 0.2877134E-05 0.1764637E-03 0.0000000E+00 8 H4SiO4 0.5727031E-03 0.3819421E-03 0.1907610E-03 0.0000000E+00 9 Ca++ 0.7772891E-04 0.1771442E-04 0.6001449E-04 0.0000000E+00 10 Mg++ 0.4365079E-04 0.7269374E-07 0.4357810E-04 0.0000000E+00 11 Fe++ 0.3921547E-04 0.1843989E-08 0.3921363E-04 0.0000000E+00 12 K+ 0.1167728E-04 0.1167728E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2291094E-03 0.2291094E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.9536228E-06 0.6406615E-07 0.8895566E-06 0.0000000E+00 15 HPO4-- 0.3254667E-06 0.3933170E-08 0.3215335E-06 0.0000000E+00 Chg. balance for solid moles: -.4521E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0550000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1072E-06 -6.970 0.5384E-04 -4.269 0.1668 0.1711E-04 clinochlore 0.8716E-05 -5.060 0.4844E-02 -2.315 15.01 0.1843E-02 daphnite 0.5404E-05 -5.267 0.3856E-02 -2.414 11.95 0.1168E-02 chlorite-Mn 0.1779E-06 -6.750 0.1261E-03 -3.899 0.3908 0.4020E-04 hematite 0.6097E-05 -5.215 0.9737E-03 -3.012 3.017 0.1846E-03 kaolinite 0.1446E-04 -4.840 0.3732E-02 -2.428 11.56 0.1436E-02 lawsonite 0.5948E-04 -4.226 0.1869E-01 -1.728 57.91 0.6027E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3780E+00 0.3780E+00 1.0000 -0.423 chlorite-Mn 0.1244E-01 0.1244E-01 1.0000 -1.905 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.032276 g Volume = 0.010716 cm3 Porosity: 98.9515% V(tot) - V(min): 0.10113E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0550000 g log = -1.2596 Original solution: 1000.0103000 g Original solution / Rock added: 18182.01 (Water/Rock Ratio), log = 4.2596 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3567E-04 1.0071 0.3665E-04 0.3639E-04 CH4,gas 0.4966E-15 1.0125 0.5131E-15 0.5067E-15 H2,gas 0.5994E-06 1.0005 0.6119E-06 0.6116E-06 H2S,gas 0.7444E-12 0.9960 0.7565E-12 0.7595E-12 S2,gas 0.5623E-31 1.0000 0.5737E-31 0.5737E-31 CO,gas 0.5858E-14 1.0000 0.5977E-14 0.5977E-14 SO3,gas 0.1474E-35 1.0000 0.1504E-35 0.1504E-35 SO2,gas 0.3510E-19 1.0000 0.3581E-19 0.3581E-19 HCl,gas 0.5555E-15 1.0000 0.5668E-15 0.5668E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.80 -6.13 -2.045 0.10475E+05 -4.436 3 CH4,gas 4.54 -12.45 -16.99 -4.247 0.29008E+05 -15.290 4 H2,gas 8.00 0.09 -7.91 -4.521 0.13510E+05 -6.213 5 H2S,gas -6.23 -20.05 -13.82 -6.910 0.23598E+05 -12.121 6 S2,gas -7.34 -40.28 -32.94 -5.068 0.56245E+05 -31.241 7 CO,gas 3.21 -12.71 -15.92 -4.899 0.27187E+05 -14.224 8 SO3,gas 17.12 -20.40 -37.52 -9.380 0.64067E+05 -35.823 9 SO2,gas 0.83 -20.31 -21.14 -5.639 0.36104E+05 -19.446 10 HCl,gas 5.19 -11.76 -16.95 -8.473 0.28934E+05 -15.247 11 acmite 7.71 3.60 -4.10 -0.426 0.70091E+04 15 albite-high 0.69 -3.34 -4.04 -0.311 0.68944E+04 16 albite -0.38 -3.34 -2.96 -0.228 0.50555E+04 19 spessartine 24.46 20.49 -3.96 -0.198 0.67684E+04 20 analcite 3.32 0.10 -3.22 -0.358 0.54941E+04 21 andalusite 5.00 2.12 -2.89 -0.289 0.49267E+04 22 andradite 39.01 35.07 -3.94 -0.205 0.67322E+04 23 grossular 32.73 28.06 -4.67 -0.233 0.79681E+04 24 anhydrite -5.32 -9.45 -4.13 -2.067 0.70598E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.85 -2.81 -0.938 0.48026E+04 36 brucite 12.57 8.56 -4.01 -0.803 0.68526E+04 37 calcite 0.81 -1.85 -2.66 -0.886 0.45384E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23214E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29344E+04 42 celadonite 5.34 0.47 -4.87 -0.287 0.83198E+04 50 chloritoid-Mg 13.20 10.67 -2.53 -0.168 0.43136E+04 51 chloritoid-Fe 9.17 8.44 -0.73 -0.049 0.12476E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14683E+04 54 coesite -2.38 -3.45 -1.07 -0.358 0.18318E+04 59 corundum 8.38 5.57 -2.82 -0.256 0.48118E+04 61 cristobalite -2.56 -3.45 -0.89 -0.296 0.15172E+04 65 diaspore 2.87 2.78 -0.09 -0.015 0.15568E+03 67 diopside 16.18 12.61 -3.58 -0.358 0.61043E+04 68 hedenbergite 14.21 10.38 -3.83 -0.383 0.65403E+04 75 epidote 24.67 23.40 -1.27 -0.062 0.21699E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.90 -2.94 -0.153 0.50219E+04 78 fayalite 14.05 9.20 -4.84 -0.692 0.82658E+04 83 gibbsite 4.08 2.78 -1.30 -0.185 0.22142E+04 87 greenalite 16.14 12.08 -4.06 -0.338 0.69269E+04 91 heulandite -5.83 -7.63 -1.80 -0.082 0.30755E+04 95 jadeite 4.22 0.10 -4.11 -0.411 0.70196E+04 99 kyanite 4.88 2.12 -2.76 -0.276 0.47126E+04 101 laumontite 2.88 2.72 -0.17 -0.011 0.28199E+03 105 lizardite 23.24 18.77 -4.48 -0.373 0.76423E+04 106 magnesite 0.69 -4.24 -4.93 -1.643 0.84184E+04 107 magnetite 20.09 18.89 -1.19 -0.098 0.20394E+04 113 margarite 17.32 15.18 -2.14 -0.086 0.36583E+04 116 microcline -2.49 -4.64 -2.15 -0.165 0.36725E+04 120 muscovite 2.58 0.93 -1.65 -0.097 0.28254E+04 121 paragonite 4.24 2.22 -2.02 -0.119 0.34475E+04 122 nepheline 8.34 3.55 -4.79 -0.684 0.81726E+04 136 prehnite 19.37 17.12 -2.26 -0.133 0.38518E+04 137 prehnite-Fe 22.50 20.62 -1.88 -0.113 0.32122E+04 138 pumpellyite-Fe 46.27 43.34 -2.93 -0.065 0.49996E+04 139 pumpellyite-Mg 48.99 45.57 -3.43 -0.076 0.58482E+04 145 pyroxmangite 7.40 4.98 -2.42 -0.485 0.41365E+04 146 pyrophyllite -6.18 -8.23 -2.05 -0.128 0.35085E+04 147 quartz -2.99 -3.45 -0.46 -0.153 0.78453E+03 151 rhodochrosite -0.98 -4.37 -3.39 -1.131 0.57946E+04 152 rhodonite 7.45 4.98 -2.47 -0.494 0.42167E+04 153 sanidine -1.28 -4.64 -3.36 -0.259 0.57403E+04 155 siderite -2.61 -6.47 -3.86 -1.287 0.65909E+04 156 sillimanite 5.26 2.12 -3.15 -0.315 0.53707E+04 163 stilbite -7.52 -7.63 -0.11 -0.005 0.18167E+03 164 stilpnomelane-Fe 13.02 11.07 -1.95 -0.058 0.33221E+04 167 sudoite-Fe 18.30 13.44 -4.86 -0.157 0.82969E+04 168 sudoite 21.08 17.89 -3.18 -0.103 0.54356E+04 171 talc 16.49 11.87 -4.62 -0.272 0.78900E+04 174 tephroite 18.09 13.40 -4.68 -0.669 0.79990E+04 177 topaz-H 4.62 2.12 -2.50 -0.227 0.42727E+04 178 tridymite -2.63 -3.45 -0.82 -0.274 0.14045E+04 187 wairakite 3.95 2.72 -1.23 -0.072 0.21039E+04 188 walstromite 11.51 7.50 -4.01 -0.802 0.68458E+04 189 wollastonite 10.46 7.50 -2.96 -0.592 0.50562E+04 190 pseudo-wollastonite 11.00 7.50 -3.50 -0.700 0.59760E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.37 -2.72 -0.168 0.46478E+04 194 beidellite-H -2.33 -6.17 -3.85 -0.246 0.65703E+04 195 beidellite-K -1.52 -5.21 -3.69 -0.226 0.62974E+04 196 beidellite-Mg -1.79 -4.76 -2.97 -0.184 0.50760E+04 197 beidellite-Na -1.34 -4.78 -3.44 -0.211 0.58729E+04 199 chalcedony -2.80 -3.45 -0.65 -0.215 0.11038E+04 201 montmorillonite-Ca -2.29 -4.52 -2.23 -0.138 0.38047E+04 202 montmorillonite-K -2.24 -5.36 -3.12 -0.191 0.53324E+04 203 montmorillonite-Mg -2.48 -4.91 -2.43 -0.151 0.41561E+04 204 montmorillonite-Na -2.04 -4.93 -2.90 -0.177 0.49437E+04 205 nontronite-Ca 3.21 2.63 -0.58 -0.038 0.99212E+03 206 nontronite-H 2.53 0.83 -1.71 -0.114 0.29125E+04 207 nontronite-K 3.34 1.79 -1.55 -0.099 0.26430E+04 208 nontronite-Mg 3.07 2.24 -0.84 -0.054 0.14276E+04 209 nontronite-Na 3.52 2.22 -1.30 -0.083 0.22203E+04 214 gypsum -4.96 -9.45 -4.50 -1.124 0.76774E+04 224 tobermorite 9.82 5.67 -4.15 -1.133 0.70887E+04 233 boehmite 4.41 2.78 -1.62 -0.271 0.27726E+04 235 ferrous-oxide 9.81 6.33 -3.48 -0.871 0.59501E+04 240 silica-amorphous -2.09 -3.45 -1.36 -0.453 0.23180E+04 242 an20ab80 2.02 -0.75 -2.77 -0.213 0.47303E+04 243 an25ab75 2.65 -0.10 -2.75 -0.212 0.46959E+04 244 an30ab70 3.28 0.54 -2.74 -0.210 0.46712E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0550000 g New total amount of reactant added: 0.0570000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0570000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2957956E-03 Osmotic coef. = 0.9897 True ionic strength = .3205443E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13616E-07 -7.8660 0.13059E-07 -7.8841 0.95910E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13230E-03 -3.8784 0.95896E+00 -0.0182 4 SO4-- 0.25391E-04 -4.5953 0.22662E-04 -4.6447 0.89250E+00 -0.0494 5 HCO3- 0.12621E-04 -4.8989 0.12104E-04 -4.9171 0.95899E+00 -0.0182 6 HS- 0.65317E-12 -12.1850 0.62636E-12 -12.2032 0.95896E+00 -0.0182 7 Al+++ 0.16478E-20 -20.7831 0.13041E-20 -20.8847 0.79146E+00 -0.1016 8 H4SiO4 0.36812E-03 -3.4340 0.36812E-03 -3.4340 0.10000E+01 0.0000 9 Ca++ 0.16987E-04 -4.7699 0.15158E-04 -4.8194 0.89235E+00 -0.0495 10 Mg++ 0.68172E-07 -7.1664 0.60827E-07 -7.2159 0.89225E+00 -0.0495 11 Fe++ 0.40281E-09 -9.3949 0.35942E-09 -9.4444 0.89228E+00 -0.0495 12 K+ 0.12097E-04 -4.9173 0.11601E-04 -4.9355 0.95900E+00 -0.0182 13 Na+ 0.23151E-03 -3.6354 0.22201E-03 -3.6536 0.95896E+00 -0.0182 14 Mn++ 0.50723E-07 -7.2948 0.45259E-07 -7.3443 0.89229E+00 -0.0495 15 HPO4-- 0.32988E-08 -8.4816 0.29442E-08 -8.5310 0.89250E+00 -0.0494 16 HSiO3- 0.27448E-04 -4.5615 0.26322E-04 -4.5797 0.95896E+00 -0.0182 17 Ca(HSiO3)+ 0.94749E-08 -8.0234 0.90865E-08 -8.0416 0.95900E+00 -0.0182 18 Mg(HSiO3)+ 0.47318E-10 -10.3250 0.45378E-10 -10.3432 0.95900E+00 -0.0182 19 NaHSiO3,aq 0.94514E-07 -7.0245 0.94514E-07 -7.0245 0.10000E+01 0.0000 20 AlO+ 0.10849E-11 -11.9646 0.10404E-11 -11.9828 0.95900E+00 -0.0182 21 AlOH+2 0.75816E-16 -16.1202 0.67651E-16 -16.1697 0.89231E+00 -0.0495 22 HAlO2,aq 0.15866E-07 -7.7995 0.15866E-07 -7.7995 0.10000E+01 0.0000 23 AlO2- 0.28047E-05 -5.5521 0.26895E-05 -5.5703 0.95892E+00 -0.0182 24 CH4,aq 0.32501E-18 -18.4881 0.32498E-18 -18.4881 0.99991E+00 0.0000 29 CO,aq 0.38995E-17 -17.4090 0.38995E-17 -17.4090 0.10000E+01 0.0000 30 CO2,aq 0.33777E-06 -6.4714 0.33774E-06 -6.4714 0.99991E+00 0.0000 31 CO3-2 0.90715E-07 -7.0423 0.80959E-07 -7.0917 0.89246E+00 -0.0494 32 CaCO3,aq 0.15387E-07 -7.8128 0.15387E-07 -7.8128 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.48835E-08 -8.3113 0.46833E-08 -8.3295 0.95900E+00 -0.0182 34 CaCl+ 0.33842E-08 -8.4706 0.32454E-08 -8.4887 0.95900E+00 -0.0182 35 CaCl2,aq 0.10201E-12 -12.9914 0.10201E-12 -12.9914 0.10000E+01 0.0000 36 CaOH+ 0.86263E-07 -7.0642 0.82727E-07 -7.0824 0.95900E+00 -0.0182 37 CaSO4,aq 0.10908E-06 -6.9623 0.10908E-06 -6.9623 0.10000E+01 0.0000 38 HCl,aq 0.31659E-12 -12.4995 0.31659E-12 -12.4995 0.10000E+01 0.0000 43 FeCl+ 0.78483E-13 -13.1052 0.75265E-13 -13.1234 0.95900E+00 -0.0182 46 FeO,aq 0.81914E-10 -10.0866 0.81914E-10 -10.0866 0.10000E+01 0.0000 47 FeOH+ 0.93420E-09 -9.0296 0.89590E-09 -9.0477 0.95900E+00 -0.0182 48 HFeO2- 0.68442E-10 -10.1647 0.65633E-10 -10.1829 0.95896E+00 -0.0182 49 FeO+ 0.10394E-12 -12.9832 0.99676E-13 -13.0014 0.95900E+00 -0.0182 50 FeOH+2 0.27857E-18 -18.5551 0.24858E-18 -18.6045 0.89231E+00 -0.0495 51 FeO2- 0.12472E-09 -9.9041 0.11960E-09 -9.9223 0.95896E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45966E-09 -9.3376 0.45961E-09 -9.3376 0.99991E+00 0.0000 54 KCl,aq 0.27819E-10 -10.5557 0.27819E-10 -10.5557 0.10000E+01 0.0000 55 KHSO4,aq 0.97070E-17 -17.0129 0.97070E-17 -17.0129 0.10000E+01 0.0000 56 KOH,aq 0.37940E-09 -9.4209 0.37940E-09 -9.4209 0.10000E+01 0.0000 57 KSO4- 0.42543E-08 -8.3712 0.40797E-08 -8.3894 0.95896E+00 -0.0182 58 MgCO3,aq 0.15478E-10 -10.8103 0.15478E-10 -10.8103 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20024E-10 -10.6984 0.19203E-10 -10.7166 0.95900E+00 -0.0182 60 MgCl+ 0.12308E-10 -10.9098 0.11804E-10 -10.9280 0.95900E+00 -0.0182 61 MgOH+ 0.19155E-08 -8.7177 0.18370E-08 -8.7359 0.95900E+00 -0.0182 63 MnO,aq 0.27485E-09 -9.5609 0.27485E-09 -9.5609 0.10000E+01 0.0000 64 MnOH+ 0.10928E-07 -7.9614 0.10480E-07 -7.9796 0.95900E+00 -0.0182 65 MnO2-2 0.59935E-16 -16.2223 0.53490E-16 -16.2717 0.89246E+00 -0.0494 66 HMnO2- 0.15958E-12 -12.7970 0.15303E-12 -12.8152 0.95896E+00 -0.0182 69 MnCl+ 0.38449E-10 -10.4151 0.36873E-10 -10.4333 0.95900E+00 -0.0182 70 MnSO4,aq 0.29610E-09 -9.5286 0.29610E-09 -9.5286 0.10000E+01 0.0000 71 NaCl,aq 0.97340E-08 -8.0117 0.97340E-08 -8.0117 0.10000E+01 0.0000 72 NaOH,aq 0.73044E-08 -8.1364 0.73044E-08 -8.1364 0.10000E+01 0.0000 74 OH- 0.46140E-04 -4.3359 0.44244E-04 -4.3541 0.95892E+00 -0.0182 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.73959E-09 -9.1310 0.70925E-09 -9.1492 0.95898E+00 -0.0182 84 PO4-3 0.23215E-12 -12.6342 0.18395E-12 -12.7353 0.79239E+00 -0.1011 87 H2P2O7-2 0.44196E-19 -19.3546 0.39443E-19 -19.4040 0.89246E+00 -0.0494 88 HP2O7-3 0.76201E-18 -18.1180 0.60311E-18 -18.2196 0.79147E+00 -0.1016 89 P2O7-4 0.16480E-19 -19.7830 0.11033E-19 -19.9573 0.66948E+00 -0.1743 90 H2S,aq 0.25282E-13 -13.5972 0.25280E-13 -13.5972 0.99991E+00 0.0000 97 SO3-2 0.15161E-14 -14.8193 0.13535E-14 -14.8685 0.89277E+00 -0.0493 98 HSO3- 0.11540E-14 -14.9378 0.11067E-14 -14.9560 0.95896E+00 -0.0182 99 HSO4- 0.29738E-09 -9.5267 0.28519E-09 -9.5449 0.95902E+00 -0.0182 Charge balance for all species = 0.2240E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1361568E-07 -.8482195E-04 -.8549109E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999473E+06 0.0000 3 Cl- 0.1379634E-03 0.1379766E-03 0.4891436E+01 4.0057 4 SO4-- 0.2539099E-04 0.2550484E-04 0.2449912E+01 11.1235 5 HCO3- 0.1262144E-04 0.1307023E-04 0.7974683E+00 2.9670 6 HS- 0.6531699E-12 0.7515953E-10 0.2485550E-05 -4.3191 7 Al+++ 0.1647763E-20 0.2820585E-05 0.7609974E-01 2.7676 8 H4SiO4 0.3681222E-03 0.3956747E-03 0.3802850E+02 -3.4340 9 Ca++ 0.1698667E-04 0.1721514E-04 0.6899133E+00 10.9488 10 Mg++ 0.6817247E-07 0.7018309E-07 0.1706205E-02 8.5523 11 Fe++ 0.4028079E-09 0.1810914E-08 0.1011290E-03 6.3238 12 K+ 0.1209746E-04 0.1210212E-04 0.4731932E+00 2.9486 13 Na+ 0.2315124E-03 0.2316240E-03 0.5324718E+01 4.2305 14 Mn++ 0.5072264E-07 0.6226054E-07 0.3420295E-02 8.4239 15 HPO4-- 0.3298801E-08 0.4038627E-08 0.3876036E-03 7.2372 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9307954E-03 -.8482046E-04 -.8459749E-03 0.0000000E+00 2 H2O 0.5550754E+02 0.5550730E+02 0.2406245E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2708413E-04 0.2550439E-04 0.1579739E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1579664E-05 0.7515821E-10 -.1579739E-05 0.0000000E+00 7 Al+++ 0.1858623E-03 0.2820535E-05 0.1830417E-03 0.0000000E+00 8 H4SiO4 0.5935286E-03 0.3956677E-03 0.1978609E-03 0.0000000E+00 9 Ca++ 0.8002919E-04 0.1721484E-04 0.6281436E-04 0.0000000E+00 10 Mg++ 0.4523810E-04 0.7018186E-07 0.4516791E-04 0.0000000E+00 11 Fe++ 0.4064149E-04 0.1810882E-08 0.4063968E-04 0.0000000E+00 12 K+ 0.1210191E-04 0.1210191E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2316199E-03 0.2316199E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.9883000E-06 0.6225944E-07 0.9260405E-06 0.0000000E+00 15 HPO4-- 0.3373019E-06 0.4038555E-08 0.3332633E-06 0.0000000E+00 Chg. balance for solid moles: -.1186E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0570000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1111E-06 -6.954 0.5580E-04 -4.253 0.1665 0.1773E-04 clinochlore 0.9034E-05 -5.044 0.5021E-02 -2.299 14.99 0.1910E-02 daphnite 0.5600E-05 -5.252 0.3996E-02 -2.398 11.93 0.1211E-02 chlorite-Mn 0.1852E-06 -6.732 0.1313E-03 -3.882 0.3919 0.4184E-04 hematite 0.6319E-05 -5.199 0.1009E-02 -2.996 3.012 0.1913E-03 kaolinite 0.1444E-04 -4.840 0.3729E-02 -2.428 11.13 0.1435E-02 lawsonite 0.6226E-04 -4.206 0.1956E-01 -1.709 58.39 0.6309E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3779E+00 0.3779E+00 1.0000 -0.423 chlorite-Mn 0.1250E-01 0.1250E-01 1.0000 -1.903 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.033506 g Volume = 0.011115 cm3 Porosity: 98.9133% V(tot) - V(min): 0.10117E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0570000 g log = -1.2441 Original solution: 1000.0103000 g Original solution / Rock added: 17544.04 (Water/Rock Ratio), log = 4.2441 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3516E-04 1.0071 0.3613E-04 0.3588E-04 CH4,gas 0.4630E-15 1.0125 0.4783E-15 0.4724E-15 H2,gas 0.5911E-06 1.0005 0.6034E-06 0.6031E-06 H2S,gas 0.6838E-12 0.9960 0.6949E-12 0.6977E-12 S2,gas 0.4879E-31 1.0000 0.4978E-31 0.4978E-31 CO,gas 0.5695E-14 1.0000 0.5811E-14 0.5811E-14 SO3,gas 0.1432E-35 1.0000 0.1461E-35 0.1461E-35 SO2,gas 0.3362E-19 1.0000 0.3430E-19 0.3430E-19 HCl,gas 0.5475E-15 1.0000 0.5586E-15 0.5586E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.80 -6.14 -2.047 0.10486E+05 -4.442 3 CH4,gas 4.54 -12.48 -17.02 -4.255 0.29060E+05 -15.320 4 H2,gas 8.00 0.08 -7.92 -4.525 0.13520E+05 -6.219 5 H2S,gas -6.23 -20.09 -13.86 -6.929 0.23661E+05 -12.158 6 S2,gas -7.34 -40.34 -33.00 -5.077 0.56350E+05 -31.303 7 CO,gas 3.21 -12.72 -15.93 -4.903 0.27208E+05 -14.236 8 SO3,gas 17.12 -20.41 -37.53 -9.384 0.64089E+05 -35.835 9 SO2,gas 0.83 -20.33 -21.16 -5.644 0.36136E+05 -19.465 10 HCl,gas 5.19 -11.76 -16.95 -8.476 0.28945E+05 -15.253 11 acmite 7.71 3.65 -4.06 -0.422 0.69395E+04 15 albite-high 0.69 -3.30 -4.00 -0.307 0.68247E+04 16 albite -0.38 -3.30 -2.92 -0.225 0.49859E+04 19 spessartine 24.46 20.50 -3.95 -0.198 0.67486E+04 20 analcite 3.32 0.13 -3.19 -0.355 0.54499E+04 21 andalusite 5.00 2.10 -2.90 -0.290 0.49522E+04 22 andradite 39.01 35.11 -3.90 -0.202 0.66558E+04 23 grossular 32.73 28.08 -4.65 -0.233 0.79426E+04 24 anhydrite -5.32 -9.46 -4.15 -2.074 0.70813E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.85 -2.82 -0.940 0.48131E+04 36 brucite 12.57 8.55 -4.02 -0.803 0.68577E+04 37 calcite 0.81 -1.85 -2.66 -0.888 0.45489E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23265E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29396E+04 42 celadonite 5.34 0.53 -4.81 -0.283 0.82114E+04 50 chloritoid-Mg 13.20 10.65 -2.54 -0.170 0.43441E+04 51 chloritoid-Fe 9.17 8.43 -0.75 -0.050 0.12782E+04 52 chloritoid-Mn 11.40 10.53 -0.88 -0.058 0.14956E+04 54 coesite -2.38 -3.43 -1.06 -0.353 0.18064E+04 59 corundum 8.38 5.54 -2.85 -0.259 0.48627E+04 61 cristobalite -2.56 -3.43 -0.87 -0.291 0.14918E+04 65 diaspore 2.87 2.77 -0.11 -0.018 0.18112E+03 67 diopside 16.18 12.63 -3.55 -0.355 0.60585E+04 68 hedenbergite 14.21 10.40 -3.80 -0.380 0.64946E+04 75 epidote 24.67 23.41 -1.26 -0.061 0.21444E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.93 -2.91 -0.151 0.49710E+04 78 fayalite 14.05 9.21 -4.83 -0.690 0.82508E+04 83 gibbsite 4.08 2.77 -1.31 -0.187 0.22397E+04 87 greenalite 16.14 12.10 -4.04 -0.336 0.68916E+04 91 heulandite -5.83 -7.55 -1.73 -0.078 0.29483E+04 95 jadeite 4.22 0.13 -4.09 -0.409 0.69754E+04 99 kyanite 4.88 2.10 -2.77 -0.277 0.47381E+04 101 laumontite 2.88 2.75 -0.14 -0.009 0.23112E+03 105 lizardite 23.24 18.79 -4.45 -0.371 0.76067E+04 106 magnesite 0.69 -4.25 -4.94 -1.646 0.84340E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20446E+04 113 margarite 17.32 15.15 -2.17 -0.087 0.37091E+04 116 microcline -2.49 -4.59 -2.10 -0.161 0.35845E+04 120 muscovite 2.58 0.95 -1.63 -0.096 0.27883E+04 121 paragonite 4.24 2.23 -2.01 -0.118 0.34288E+04 122 nepheline 8.34 3.56 -4.78 -0.682 0.81538E+04 136 prehnite 19.37 17.13 -2.24 -0.132 0.38264E+04 137 prehnite-Fe 22.50 20.65 -1.85 -0.111 0.31614E+04 138 pumpellyite-Fe 46.27 43.35 -2.92 -0.065 0.49793E+04 139 pumpellyite-Mg 48.99 45.58 -3.41 -0.076 0.58279E+04 145 pyroxmangite 7.40 4.99 -2.41 -0.482 0.41129E+04 146 pyrophyllite -6.18 -8.20 -2.02 -0.127 0.34576E+04 147 quartz -2.99 -3.43 -0.44 -0.148 0.75910E+03 151 rhodochrosite -0.98 -4.38 -3.40 -1.134 0.58070E+04 152 rhodonite 7.45 4.99 -2.46 -0.491 0.41932E+04 153 sanidine -1.28 -4.59 -3.31 -0.255 0.56522E+04 155 siderite -2.61 -6.48 -3.87 -1.290 0.66066E+04 156 sillimanite 5.26 2.10 -3.16 -0.316 0.53961E+04 163 stilbite -7.52 -7.55 -0.03 -0.002 0.54495E+02 164 stilpnomelane-Fe 13.02 11.16 -1.86 -0.056 0.31768E+04 167 sudoite-Fe 18.30 13.42 -4.88 -0.157 0.83327E+04 168 sudoite 21.08 17.87 -3.20 -0.103 0.54712E+04 171 talc 16.49 11.92 -4.57 -0.269 0.78035E+04 174 tephroite 18.09 13.41 -4.67 -0.667 0.79773E+04 177 topaz-H 4.62 2.10 -2.52 -0.229 0.42981E+04 178 tridymite -2.63 -3.43 -0.81 -0.269 0.13791E+04 187 wairakite 3.95 2.75 -1.20 -0.071 0.20531E+04 188 walstromite 11.51 7.51 -3.99 -0.799 0.68203E+04 189 wollastonite 10.46 7.51 -2.95 -0.589 0.50308E+04 190 pseudo-wollastonite 11.00 7.51 -3.49 -0.697 0.59506E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.35 -2.70 -0.167 0.46137E+04 194 beidellite-H -2.33 -6.15 -3.83 -0.244 0.65362E+04 195 beidellite-K -1.52 -5.18 -3.66 -0.224 0.62510E+04 196 beidellite-Mg -1.79 -4.74 -2.95 -0.183 0.50427E+04 197 beidellite-Na -1.34 -4.76 -3.42 -0.209 0.58327E+04 199 chalcedony -2.80 -3.43 -0.63 -0.211 0.10784E+04 201 montmorillonite-Ca -2.29 -4.49 -2.19 -0.136 0.37472E+04 202 montmorillonite-K -2.24 -5.32 -3.08 -0.189 0.52626E+04 203 montmorillonite-Mg -2.48 -4.88 -2.40 -0.149 0.40994E+04 204 montmorillonite-Na -2.04 -4.90 -2.86 -0.175 0.48799E+04 205 nontronite-Ca 3.21 2.68 -0.53 -0.034 0.90717E+03 206 nontronite-H 2.53 0.88 -1.66 -0.111 0.28276E+04 207 nontronite-K 3.34 1.85 -1.49 -0.096 0.25458E+04 208 nontronite-Mg 3.07 2.29 -0.79 -0.051 0.13434E+04 209 nontronite-Na 3.52 2.27 -1.25 -0.080 0.21291E+04 214 gypsum -4.96 -9.46 -4.51 -1.127 0.76989E+04 224 tobermorite 9.82 5.69 -4.14 -1.129 0.70633E+04 233 boehmite 4.41 2.77 -1.64 -0.273 0.27980E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59553E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.448 0.22926E+04 242 an20ab80 2.02 -0.72 -2.74 -0.211 0.46746E+04 243 an25ab75 2.65 -0.07 -2.72 -0.209 0.46437E+04 244 an30ab70 3.28 0.57 -2.71 -0.208 0.46224E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0570000 g New total amount of reactant added: 0.0590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0590000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2960559E-03 Osmotic coef. = 0.9897 True ionic strength = .3220335E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13422E-07 -7.8722 0.12873E-07 -7.8903 0.95904E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13229E-03 -3.8785 0.95891E+00 -0.0182 4 SO4-- 0.25394E-04 -4.5953 0.22659E-04 -4.6448 0.89231E+00 -0.0495 5 HCO3- 0.12625E-04 -4.8988 0.12107E-04 -4.9170 0.95894E+00 -0.0182 6 HS- 0.61008E-12 -12.2146 0.58501E-12 -12.2328 0.95891E+00 -0.0182 7 Al+++ 0.15277E-20 -20.8160 0.12085E-20 -20.9177 0.79108E+00 -0.1018 8 H4SiO4 0.38051E-03 -3.4196 0.38051E-03 -3.4196 0.10000E+01 0.0000 9 Ca++ 0.16510E-04 -4.7823 0.14729E-04 -4.8318 0.89216E+00 -0.0496 10 Mg++ 0.65820E-07 -7.1816 0.58716E-07 -7.2312 0.89206E+00 -0.0496 11 Fe++ 0.38887E-09 -9.4102 0.34690E-09 -9.4598 0.89208E+00 -0.0496 12 K+ 0.12522E-04 -4.9023 0.12008E-04 -4.9205 0.95894E+00 -0.0182 13 Na+ 0.23402E-03 -3.6308 0.22440E-03 -3.6490 0.95890E+00 -0.0182 14 Mn++ 0.49168E-07 -7.3083 0.43863E-07 -7.3579 0.89210E+00 -0.0496 15 HPO4-- 0.33956E-08 -8.4691 0.30299E-08 -8.5186 0.89231E+00 -0.0495 16 HSiO3- 0.28784E-04 -4.5409 0.27601E-04 -4.5591 0.95891E+00 -0.0182 17 Ca(HSiO3)+ 0.96548E-08 -8.0153 0.92585E-08 -8.0335 0.95895E+00 -0.0182 18 Mg(HSiO3)+ 0.47898E-10 -10.3197 0.45932E-10 -10.3379 0.95895E+00 -0.0182 19 NaHSiO3,aq 0.10017E-06 -6.9992 0.10017E-06 -6.9992 0.10000E+01 0.0000 20 AlO+ 0.10347E-11 -11.9852 0.99218E-12 -12.0034 0.95895E+00 -0.0182 21 AlOH+2 0.71288E-16 -16.1470 0.63597E-16 -16.1966 0.89212E+00 -0.0496 22 HAlO2,aq 0.15350E-07 -7.8139 0.15350E-07 -7.8139 0.10000E+01 0.0000 23 AlO2- 0.27528E-05 -5.5602 0.26395E-05 -5.5785 0.95886E+00 -0.0182 24 CH4,aq 0.30365E-18 -18.5176 0.30362E-18 -18.5177 0.99991E+00 0.0000 29 CO,aq 0.37934E-17 -17.4210 0.37934E-17 -17.4210 0.10000E+01 0.0000 30 CO2,aq 0.33304E-06 -6.4775 0.33301E-06 -6.4775 0.99991E+00 0.0000 31 CO3-2 0.92068E-07 -7.0359 0.82149E-07 -7.0854 0.89226E+00 -0.0495 32 CaCO3,aq 0.15172E-07 -7.8190 0.15172E-07 -7.8190 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47467E-08 -8.3236 0.45519E-08 -8.3418 0.95895E+00 -0.0182 34 CaCl+ 0.32884E-08 -8.4830 0.31534E-08 -8.5012 0.95895E+00 -0.0182 35 CaCl2,aq 0.99113E-13 -13.0039 0.99113E-13 -13.0039 0.10000E+01 0.0000 36 CaOH+ 0.85039E-07 -7.0704 0.81548E-07 -7.0886 0.95895E+00 -0.0182 37 CaSO4,aq 0.10598E-06 -6.9748 0.10598E-06 -6.9748 0.10000E+01 0.0000 38 HCl,aq 0.31206E-12 -12.5058 0.31206E-12 -12.5058 0.10000E+01 0.0000 43 FeCl+ 0.75751E-13 -13.1206 0.72642E-13 -13.1388 0.95895E+00 -0.0182 46 FeO,aq 0.81365E-10 -10.0896 0.81365E-10 -10.0896 0.10000E+01 0.0000 47 FeOH+ 0.91477E-09 -9.0387 0.87721E-09 -9.0569 0.95895E+00 -0.0182 48 HFeO2- 0.68969E-10 -10.1613 0.66135E-10 -10.1796 0.95891E+00 -0.0182 49 FeO+ 0.10246E-12 -12.9894 0.98256E-13 -13.0076 0.95895E+00 -0.0182 50 FeOH+2 0.27075E-18 -18.5674 0.24154E-18 -18.6170 0.89212E+00 -0.0496 51 FeO2- 0.12653E-09 -9.8978 0.12133E-09 -9.9160 0.95891E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45351E-09 -9.3434 0.45347E-09 -9.3435 0.99991E+00 0.0000 54 KCl,aq 0.28792E-10 -10.5407 0.28792E-10 -10.5407 0.10000E+01 0.0000 55 KHSO4,aq 0.99029E-17 -17.0042 0.99029E-17 -17.0042 0.10000E+01 0.0000 56 KOH,aq 0.39837E-09 -9.3997 0.39837E-09 -9.3997 0.10000E+01 0.0000 57 KSO4- 0.44031E-08 -8.3562 0.42222E-08 -8.3745 0.95891E+00 -0.0182 58 MgCO3,aq 0.15160E-10 -10.8193 0.15160E-10 -10.8193 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19335E-10 -10.7137 0.18541E-10 -10.7319 0.95895E+00 -0.0182 60 MgCl+ 0.11881E-10 -10.9251 0.11393E-10 -10.9434 0.95895E+00 -0.0182 61 MgOH+ 0.18758E-08 -8.7268 0.17988E-08 -8.7450 0.95895E+00 -0.0182 63 MnO,aq 0.27413E-09 -9.5620 0.27413E-09 -9.5620 0.10000E+01 0.0000 64 MnOH+ 0.10745E-07 -7.9688 0.10304E-07 -7.9870 0.95895E+00 -0.0182 65 MnO2-2 0.61531E-16 -16.2109 0.54902E-16 -16.2604 0.89226E+00 -0.0495 66 HMnO2- 0.16147E-12 -12.7919 0.15483E-12 -12.8101 0.95891E+00 -0.0182 69 MnCl+ 0.37263E-10 -10.4287 0.35733E-10 -10.4469 0.95895E+00 -0.0182 70 MnSO4,aq 0.28693E-09 -9.5422 0.28693E-09 -9.5422 0.10000E+01 0.0000 71 NaCl,aq 0.98382E-08 -8.0071 0.98382E-08 -8.0071 0.10000E+01 0.0000 72 NaOH,aq 0.74897E-08 -8.1255 0.74897E-08 -8.1255 0.10000E+01 0.0000 74 OH- 0.46809E-04 -4.3297 0.44884E-04 -4.3479 0.95886E+00 -0.0182 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.75032E-09 -9.1248 0.71950E-09 -9.1430 0.95893E+00 -0.0182 84 PO4-3 0.24247E-12 -12.6153 0.19204E-12 -12.7166 0.79201E+00 -0.1013 87 H2P2O7-2 0.45493E-19 -19.3421 0.40592E-19 -19.3916 0.89226E+00 -0.0495 88 HP2O7-3 0.79592E-18 -18.0991 0.62964E-18 -18.2009 0.79108E+00 -0.1018 89 P2O7-4 0.17469E-19 -19.7577 0.11685E-19 -19.9324 0.66891E+00 -0.1746 90 H2S,aq 0.23277E-13 -13.6331 0.23274E-13 -13.6331 0.99991E+00 0.0000 97 SO3-2 0.14960E-14 -14.8251 0.13353E-14 -14.8744 0.89257E+00 -0.0494 98 HSO3- 0.11223E-14 -14.9499 0.10762E-14 -14.9681 0.95891E+00 -0.0182 99 HSO4- 0.29313E-09 -9.5329 0.28110E-09 -9.5511 0.95897E+00 -0.0182 Charge balance for all species = 0.2240E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1342242E-07 -.8662805E-04 -.8731132E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999460E+06 0.0000 3 Cl- 0.1379635E-03 0.1379767E-03 0.4891432E+01 4.0119 4 SO4-- 0.2539397E-04 0.2550486E-04 0.2449910E+01 11.1359 5 HCO3- 0.1262518E-04 0.1307024E-04 0.7974677E+00 2.9734 6 HS- 0.6100785E-12 0.7335161E-10 0.2425758E-05 -4.3425 7 Al+++ 0.1527692E-20 0.2768116E-05 0.7468403E-01 2.7532 8 H4SiO4 0.3805113E-03 0.4094051E-03 0.3934808E+02 -3.4196 9 Ca++ 0.1650969E-04 0.1673358E-04 0.6706132E+00 10.9488 10 Mg++ 0.6582025E-07 0.6779034E-07 0.1648033E-02 8.5494 11 Fe++ 0.3888708E-09 0.1779322E-08 0.9936458E-04 6.3209 12 K+ 0.1252194E-04 0.1252677E-04 0.4897961E+00 2.9698 13 Na+ 0.2340171E-03 0.2341346E-03 0.5382428E+01 4.2414 14 Mn++ 0.4916835E-07 0.6051165E-07 0.3324216E-02 8.4228 15 HPO4-- 0.3395579E-08 0.4146144E-08 0.3979220E-03 7.2621 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9639124E-03 -.8662647E-04 -.8772859E-03 0.0000000E+00 2 H2O 0.5550751E+02 0.5550726E+02 0.2497299E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2713956E-04 0.2550440E-04 0.1635164E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1635091E-05 0.7335027E-10 -.1635164E-05 0.0000000E+00 7 Al+++ 0.1923838E-03 0.2768066E-05 0.1896157E-03 0.0000000E+00 8 H4SiO4 0.6143542E-03 0.4093976E-03 0.2049566E-03 0.0000000E+00 9 Ca++ 0.8232948E-04 0.1673327E-04 0.6559621E-04 0.0000000E+00 10 Mg++ 0.4682540E-04 0.6778911E-07 0.4675761E-04 0.0000000E+00 11 Fe++ 0.4206751E-04 0.1779289E-08 0.4206573E-04 0.0000000E+00 12 K+ 0.1252654E-04 0.1252654E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2341304E-03 0.2341304E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1022977E-05 0.6051055E-07 0.9624666E-06 0.0000000E+00 15 HPO4-- 0.3491370E-06 0.4146069E-08 0.3449910E-06 0.0000000E+00 Chg. balance for solid moles: -.1634E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1150E-06 -6.939 0.5777E-04 -4.238 0.1663 0.1836E-04 clinochlore 0.9352E-05 -5.029 0.5198E-02 -2.284 14.96 0.1977E-02 daphnite 0.5797E-05 -5.237 0.4136E-02 -2.383 11.91 0.1253E-02 chlorite-Mn 0.1925E-06 -6.716 0.1365E-03 -3.865 0.3929 0.4349E-04 hematite 0.6541E-05 -5.184 0.1045E-02 -2.981 3.007 0.1980E-03 kaolinite 0.1445E-04 -4.840 0.3729E-02 -2.428 10.74 0.1435E-02 lawsonite 0.6502E-04 -4.187 0.2043E-01 -1.690 58.82 0.6589E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3779E+00 0.3779E+00 1.0000 -0.423 chlorite-Mn 0.1255E-01 0.1255E-01 1.0000 -1.901 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.034734 g Volume = 0.011514 cm3 Porosity: 98.8751% V(tot) - V(min): 0.10121E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0590000 g log = -1.2291 Original solution: 1000.0103000 g Original solution / Rock added: 16949.33 (Water/Rock Ratio), log = 4.2292 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3467E-04 1.0071 0.3563E-04 0.3538E-04 CH4,gas 0.4326E-15 1.0125 0.4469E-15 0.4414E-15 H2,gas 0.5832E-06 1.0005 0.5953E-06 0.5950E-06 H2S,gas 0.6295E-12 0.9960 0.6398E-12 0.6423E-12 S2,gas 0.4249E-31 1.0000 0.4335E-31 0.4335E-31 CO,gas 0.5540E-14 1.0000 0.5653E-14 0.5653E-14 SO3,gas 0.1391E-35 1.0000 0.1420E-35 0.1420E-35 SO2,gas 0.3223E-19 1.0000 0.3288E-19 0.3288E-19 HCl,gas 0.5397E-15 1.0000 0.5506E-15 0.5506E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.48 0.04 0.002 -0.68234E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.81 -6.15 -2.049 0.10496E+05 -4.448 3 CH4,gas 4.54 -12.51 -17.05 -4.262 0.29110E+05 -15.350 4 H2,gas 8.00 0.08 -7.92 -4.528 0.13530E+05 -6.225 5 H2S,gas -6.23 -20.12 -13.89 -6.946 0.23722E+05 -12.194 6 S2,gas -7.34 -40.40 -33.06 -5.086 0.56452E+05 -31.363 7 CO,gas 3.21 -12.73 -15.95 -4.907 0.27229E+05 -14.248 8 SO3,gas 17.12 -20.43 -37.55 -9.387 0.64110E+05 -35.848 9 SO2,gas 0.83 -20.35 -21.18 -5.649 0.36168E+05 -19.483 10 HCl,gas 5.19 -11.77 -16.96 -8.479 0.28955E+05 -15.259 11 acmite 7.71 3.69 -4.02 -0.418 0.68718E+04 15 albite-high 0.69 -3.26 -3.96 -0.304 0.67571E+04 16 albite -0.38 -3.26 -2.88 -0.222 0.49183E+04 19 spessartine 24.46 20.52 -3.94 -0.197 0.67299E+04 20 analcite 3.32 0.16 -3.17 -0.352 0.54068E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49767E+04 22 andradite 39.01 35.15 -3.85 -0.200 0.65822E+04 23 grossular 32.73 28.09 -4.64 -0.232 0.79181E+04 24 anhydrite -5.32 -9.48 -4.16 -2.080 0.71027E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.86 -2.82 -0.942 0.48236E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68626E+04 37 calcite 0.81 -1.86 -2.67 -0.890 0.45594E+04 40 carpholite-Mg 8.58 7.22 -1.37 -0.091 0.23315E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29446E+04 42 celadonite 5.34 0.59 -4.75 -0.279 0.81065E+04 50 chloritoid-Mg 13.20 10.64 -2.56 -0.171 0.43736E+04 51 chloritoid-Fe 9.17 8.41 -0.77 -0.051 0.13077E+04 52 chloritoid-Mn 11.40 10.51 -0.89 -0.059 0.15221E+04 54 coesite -2.38 -3.42 -1.04 -0.348 0.17819E+04 59 corundum 8.38 5.51 -2.88 -0.262 0.49118E+04 61 cristobalite -2.56 -3.42 -0.86 -0.286 0.14672E+04 65 diaspore 2.87 2.75 -0.12 -0.020 0.20566E+03 67 diopside 16.18 12.66 -3.52 -0.352 0.60143E+04 68 hedenbergite 14.21 10.43 -3.78 -0.378 0.64505E+04 75 epidote 24.67 23.43 -1.24 -0.060 0.21199E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.96 -2.88 -0.150 0.49219E+04 78 fayalite 14.05 9.22 -4.82 -0.689 0.82362E+04 83 gibbsite 4.08 2.75 -1.33 -0.189 0.22642E+04 87 greenalite 16.14 12.12 -4.02 -0.335 0.68575E+04 91 heulandite -5.83 -7.48 -1.65 -0.075 0.28256E+04 95 jadeite 4.22 0.16 -4.06 -0.406 0.69322E+04 99 kyanite 4.88 2.09 -2.79 -0.279 0.47626E+04 101 laumontite 2.88 2.78 -0.11 -0.007 0.18202E+03 105 lizardite 23.24 18.81 -4.43 -0.370 0.75724E+04 106 magnesite 0.69 -4.26 -4.95 -1.649 0.84494E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20495E+04 113 margarite 17.32 15.12 -2.20 -0.088 0.37582E+04 116 microcline -2.49 -4.54 -2.05 -0.158 0.34992E+04 120 muscovite 2.58 0.97 -1.61 -0.095 0.27521E+04 121 paragonite 4.24 2.24 -2.00 -0.117 0.34102E+04 122 nepheline 8.34 3.57 -4.76 -0.681 0.81352E+04 136 prehnite 19.37 17.15 -2.23 -0.131 0.38019E+04 137 prehnite-Fe 22.50 20.68 -1.82 -0.110 0.31123E+04 138 pumpellyite-Fe 46.27 43.36 -2.90 -0.065 0.49598E+04 139 pumpellyite-Mg 48.99 45.59 -3.40 -0.076 0.58082E+04 145 pyroxmangite 7.40 5.00 -2.40 -0.479 0.40903E+04 146 pyrophyllite -6.18 -8.17 -2.00 -0.125 0.34085E+04 147 quartz -2.99 -3.42 -0.43 -0.143 0.73455E+03 151 rhodochrosite -0.98 -4.38 -3.41 -1.136 0.58194E+04 152 rhodonite 7.45 5.00 -2.44 -0.489 0.41706E+04 153 sanidine -1.28 -4.54 -3.26 -0.251 0.55670E+04 155 siderite -2.61 -6.49 -3.88 -1.293 0.66221E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54206E+04 164 stilpnomelane-Fe 13.02 11.24 -1.78 -0.053 0.30364E+04 167 sudoite-Fe 18.30 13.40 -4.90 -0.158 0.83672E+04 168 sudoite 21.08 17.85 -3.22 -0.104 0.55056E+04 171 talc 16.49 11.97 -4.52 -0.266 0.77201E+04 174 tephroite 18.09 13.43 -4.66 -0.666 0.79567E+04 177 topaz-H 4.62 2.09 -2.53 -0.230 0.43227E+04 178 tridymite -2.63 -3.42 -0.79 -0.264 0.13545E+04 187 wairakite 3.95 2.78 -1.17 -0.069 0.20040E+04 188 walstromite 11.51 7.53 -3.98 -0.796 0.67958E+04 189 wollastonite 10.46 7.53 -2.93 -0.586 0.50062E+04 190 pseudo-wollastonite 11.00 7.53 -3.47 -0.694 0.59260E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.33 -2.68 -0.166 0.45808E+04 194 beidellite-H -2.33 -6.13 -3.81 -0.243 0.65033E+04 195 beidellite-K -1.52 -5.15 -3.63 -0.223 0.62062E+04 196 beidellite-Mg -1.79 -4.72 -2.93 -0.182 0.50107E+04 197 beidellite-Na -1.34 -4.74 -3.39 -0.208 0.57936E+04 199 chalcedony -2.80 -3.42 -0.62 -0.206 0.10538E+04 201 montmorillonite-Ca -2.29 -4.45 -2.16 -0.134 0.36916E+04 202 montmorillonite-K -2.24 -5.28 -3.04 -0.186 0.51951E+04 203 montmorillonite-Mg -2.48 -4.85 -2.37 -0.147 0.40446E+04 204 montmorillonite-Na -2.04 -4.86 -2.82 -0.173 0.48182E+04 205 nontronite-Ca 3.21 2.73 -0.48 -0.031 0.82518E+03 206 nontronite-H 2.53 0.92 -1.61 -0.108 0.27456E+04 207 nontronite-K 3.34 1.90 -1.44 -0.092 0.24519E+04 208 nontronite-Mg 3.07 2.34 -0.74 -0.048 0.12623E+04 209 nontronite-Na 3.52 2.32 -1.20 -0.077 0.20410E+04 214 gypsum -4.96 -9.48 -4.52 -1.130 0.77203E+04 224 tobermorite 9.82 5.70 -4.12 -1.125 0.70387E+04 233 boehmite 4.41 2.75 -1.65 -0.276 0.28226E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.09 -3.42 -1.33 -0.443 0.22680E+04 242 an20ab80 2.02 -0.69 -2.71 -0.208 0.46204E+04 243 an25ab75 2.65 -0.04 -2.69 -0.207 0.45929E+04 244 an30ab70 3.28 0.60 -2.68 -0.206 0.45751E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0590000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2961084E-03 Osmotic coef. = 0.9897 True ionic strength = .3217091E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13378E-07 -7.8736 0.12831E-07 -7.8918 0.95906E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13230E-03 -3.8785 0.95892E+00 -0.0182 4 SO4-- 0.25395E-04 -4.5953 0.22661E-04 -4.6447 0.89235E+00 -0.0495 5 HCO3- 0.12626E-04 -4.8987 0.12108E-04 -4.9169 0.95895E+00 -0.0182 6 HS- 0.62627E-12 -12.2032 0.60055E-12 -12.2215 0.95892E+00 -0.0182 7 Al+++ 0.15407E-20 -20.8123 0.12189E-20 -20.9140 0.79116E+00 -0.1017 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.16401E-04 -4.7851 0.14633E-04 -4.8347 0.89220E+00 -0.0495 10 Mg++ 0.65629E-07 -7.1829 0.58548E-07 -7.2325 0.89210E+00 -0.0496 11 Fe++ 0.38774E-09 -9.4115 0.34591E-09 -9.4610 0.89212E+00 -0.0496 12 K+ 0.12522E-04 -4.9023 0.12008E-04 -4.9205 0.95896E+00 -0.0182 13 Na+ 0.23402E-03 -3.6307 0.22440E-03 -3.6490 0.95891E+00 -0.0182 14 Mn++ 0.49032E-07 -7.3095 0.43743E-07 -7.3591 0.89214E+00 -0.0496 15 HPO4-- 0.34177E-08 -8.4663 0.30498E-08 -8.5157 0.89235E+00 -0.0495 16 HSiO3- 0.28351E-04 -4.5474 0.27186E-04 -4.5656 0.95892E+00 -0.0182 17 Ca(HSiO3)+ 0.94477E-08 -8.0247 0.90600E-08 -8.0429 0.95896E+00 -0.0182 18 Mg(HSiO3)+ 0.47043E-10 -10.3275 0.45113E-10 -10.3457 0.95896E+00 -0.0182 19 NaHSiO3,aq 0.98671E-07 -7.0058 0.98671E-07 -7.0058 0.10000E+01 0.0000 20 AlO+ 0.10504E-11 -11.9786 0.10073E-11 -11.9968 0.95896E+00 -0.0182 21 AlOH+2 0.72135E-16 -16.1419 0.64356E-16 -16.1914 0.89216E+00 -0.0496 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.28130E-05 -5.5508 0.26974E-05 -5.5691 0.95888E+00 -0.0182 24 CH4,aq 0.31172E-18 -18.5062 0.31169E-18 -18.5063 0.99991E+00 0.0000 29 CO,aq 0.38093E-17 -17.4192 0.38093E-17 -17.4192 0.10000E+01 0.0000 30 CO2,aq 0.33198E-06 -6.4789 0.33195E-06 -6.4789 0.99991E+00 0.0000 31 CO3-2 0.92373E-07 -7.0345 0.82425E-07 -7.0839 0.89230E+00 -0.0495 32 CaCO3,aq 0.15124E-07 -7.8203 0.15124E-07 -7.8203 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47161E-08 -8.3264 0.45226E-08 -8.3446 0.95896E+00 -0.0182 34 CaCl+ 0.32670E-08 -8.4859 0.31329E-08 -8.5041 0.95896E+00 -0.0182 35 CaCl2,aq 0.98469E-13 -13.0067 0.98469E-13 -13.0067 0.10000E+01 0.0000 36 CaOH+ 0.84760E-07 -7.0718 0.81282E-07 -7.0900 0.95896E+00 -0.0182 37 CaSO4,aq 0.10530E-06 -6.9776 0.10530E-06 -6.9776 0.10000E+01 0.0000 38 HCl,aq 0.31105E-12 -12.5072 0.31105E-12 -12.5072 0.10000E+01 0.0000 43 FeCl+ 0.75534E-13 -13.1219 0.72434E-13 -13.1401 0.95896E+00 -0.0182 46 FeO,aq 0.81664E-10 -10.0880 0.81664E-10 -10.0880 0.10000E+01 0.0000 47 FeOH+ 0.91513E-09 -9.0385 0.87757E-09 -9.0567 0.95896E+00 -0.0182 48 HFeO2- 0.69449E-10 -10.1583 0.66596E-10 -10.1766 0.95892E+00 -0.0182 49 FeO+ 0.10213E-12 -12.9909 0.97935E-13 -13.0091 0.95896E+00 -0.0182 50 FeOH+2 0.26897E-18 -18.5703 0.23997E-18 -18.6198 0.89216E+00 -0.0496 51 FeO2- 0.12694E-09 -9.8964 0.12173E-09 -9.9146 0.95892E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45685E-09 -9.3402 0.45681E-09 -9.3403 0.99991E+00 0.0000 54 KCl,aq 0.28792E-10 -10.5407 0.28792E-10 -10.5407 0.10000E+01 0.0000 55 KHSO4,aq 0.98714E-17 -17.0056 0.98714E-17 -17.0056 0.10000E+01 0.0000 56 KOH,aq 0.39968E-09 -9.3983 0.39968E-09 -9.3983 0.10000E+01 0.0000 57 KSO4- 0.44034E-08 -8.3562 0.42225E-08 -8.3744 0.95892E+00 -0.0182 58 MgCO3,aq 0.15167E-10 -10.8191 0.15167E-10 -10.8191 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19281E-10 -10.7149 0.18490E-10 -10.7331 0.95896E+00 -0.0182 60 MgCl+ 0.11847E-10 -10.9264 0.11361E-10 -10.9446 0.95896E+00 -0.0182 61 MgOH+ 0.18766E-08 -8.7266 0.17996E-08 -8.7448 0.95896E+00 -0.0182 63 MnO,aq 0.27517E-09 -9.5604 0.27517E-09 -9.5604 0.10000E+01 0.0000 64 MnOH+ 0.10750E-07 -7.9686 0.10309E-07 -7.9868 0.95896E+00 -0.0182 65 MnO2-2 0.62168E-16 -16.2064 0.55473E-16 -16.2559 0.89230E+00 -0.0495 66 HMnO2- 0.16262E-12 -12.7888 0.15593E-12 -12.8071 0.95892E+00 -0.0182 69 MnCl+ 0.37161E-10 -10.4299 0.35636E-10 -10.4481 0.95896E+00 -0.0182 70 MnSO4,aq 0.28617E-09 -9.5434 0.28617E-09 -9.5434 0.10000E+01 0.0000 71 NaCl,aq 0.98385E-08 -8.0071 0.98385E-08 -8.0071 0.10000E+01 0.0000 72 NaOH,aq 0.75144E-08 -8.1241 0.75144E-08 -8.1241 0.10000E+01 0.0000 74 OH- 0.46962E-04 -4.3283 0.45031E-04 -4.3465 0.95888E+00 -0.0182 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.75277E-09 -9.1233 0.72186E-09 -9.1415 0.95894E+00 -0.0182 84 PO4-3 0.24484E-12 -12.6111 0.19393E-12 -12.7123 0.79209E+00 -0.1012 87 H2P2O7-2 0.45789E-19 -19.3392 0.40858E-19 -19.3887 0.89230E+00 -0.0495 88 HP2O7-3 0.80369E-18 -18.0949 0.63585E-18 -18.1966 0.79117E+00 -0.1017 89 P2O7-4 0.17696E-19 -19.7521 0.11839E-19 -19.9267 0.66903E+00 -0.1746 90 H2S,aq 0.23817E-13 -13.6231 0.23815E-13 -13.6232 0.99991E+00 0.0000 97 SO3-2 0.15070E-14 -14.8219 0.13452E-14 -14.8712 0.89261E+00 -0.0493 98 HSO3- 0.11270E-14 -14.9481 0.10807E-14 -14.9663 0.95892E+00 -0.0182 99 HSO4- 0.29219E-09 -9.5343 0.28020E-09 -9.5525 0.95898E+00 -0.0182 Charge balance for all species = 0.2240E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1337843E-07 -.8658964E-04 -.8727266E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999467E+06 0.0000 3 Cl- 0.1379635E-03 0.1379767E-03 0.4891435E+01 4.0133 4 SO4-- 0.2539465E-04 0.2550486E-04 0.2449911E+01 11.1388 5 HCO3- 0.1262601E-04 0.1307024E-04 0.7974682E+00 2.9748 6 HS- 0.6262746E-12 0.7415345E-10 0.2452277E-05 -4.3297 7 Al+++ 0.1540707E-20 0.2828684E-05 0.7631820E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4020322E-03 0.3863949E+02 -3.4276 9 Ca++ 0.1640125E-04 0.1662387E-04 0.6662170E+00 10.9488 10 Mg++ 0.6562904E-07 0.6759894E-07 0.1643381E-02 8.5510 11 Fe++ 0.3877394E-09 0.1779742E-08 0.9938813E-04 6.3225 12 K+ 0.1252193E-04 0.1252677E-04 0.4897964E+00 2.9712 13 Na+ 0.2340186E-03 0.2341346E-03 0.5382431E+01 4.2428 14 Mn++ 0.4903196E-07 0.6038113E-07 0.3317048E-02 8.4244 15 HPO4-- 0.3417706E-08 0.4170723E-08 0.4002812E-03 7.2678 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9639124E-03 -.8658807E-04 -.8773243E-03 0.0000000E+00 2 H2O 0.5550751E+02 0.5550727E+02 0.2423764E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2713956E-04 0.2550440E-04 0.1635165E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1635091E-05 0.7415211E-10 -.1635165E-05 0.0000000E+00 7 Al+++ 0.1923838E-03 0.2828632E-05 0.1895551E-03 0.0000000E+00 8 H4SiO4 0.6143542E-03 0.4020249E-03 0.2123293E-03 0.0000000E+00 9 Ca++ 0.8232948E-04 0.1662357E-04 0.6570591E-04 0.0000000E+00 10 Mg++ 0.4682540E-04 0.6759772E-07 0.4675780E-04 0.0000000E+00 11 Fe++ 0.4206751E-04 0.1779710E-08 0.4206573E-04 0.0000000E+00 12 K+ 0.1252654E-04 0.1252654E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2341304E-03 0.2341304E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1022977E-05 0.6038004E-07 0.9625971E-06 0.0000000E+00 15 HPO4-- 0.3491370E-06 0.4170648E-08 0.3449664E-06 0.0000000E+00 Chg. balance for solid moles: 0.8439E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1150E-06 -6.939 0.5776E-04 -4.238 0.1636 0.1835E-04 clinochlore 0.9352E-05 -5.029 0.5198E-02 -2.284 14.72 0.1977E-02 daphnite 0.5797E-05 -5.237 0.4136E-02 -2.383 11.71 0.1253E-02 chlorite-Mn 0.1925E-06 -6.716 0.1365E-03 -3.865 0.3865 0.4350E-04 hematite 0.6541E-05 -5.184 0.1045E-02 -2.981 2.958 0.1980E-03 kaolinite 0.1431E-04 -4.844 0.3693E-02 -2.433 10.46 0.1421E-02 lawsonite 0.6364E-04 -4.196 0.2000E-01 -1.699 56.63 0.6449E-02 stilbite 0.1487E-05 -5.828 0.1048E-02 -2.980 2.967 0.4887E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3779E+00 0.3779E+00 1.0000 -0.423 chlorite-Mn 0.1255E-01 0.1255E-01 1.0000 -1.901 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.035313 g Volume = 0.011849 cm3 Porosity: 98.8424% V(tot) - V(min): 0.10118E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0590000 g log = -1.2291 Original solution: 1000.0103000 g Original solution / Rock added: 16949.33 (Water/Rock Ratio), log = 4.2292 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3456E-04 1.0071 0.3551E-04 0.3526E-04 CH4,gas 0.4441E-15 1.0125 0.4588E-15 0.4531E-15 H2,gas 0.5875E-06 1.0005 0.5997E-06 0.5994E-06 H2S,gas 0.6442E-12 0.9960 0.6546E-12 0.6572E-12 S2,gas 0.4383E-31 1.0000 0.4472E-31 0.4472E-31 CO,gas 0.5563E-14 1.0000 0.5677E-14 0.5677E-14 SO3,gas 0.1382E-35 1.0000 0.1411E-35 0.1411E-35 SO2,gas 0.3226E-19 1.0000 0.3291E-19 0.3291E-19 HCl,gas 0.5379E-15 1.0000 0.5489E-15 0.5489E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.81 -6.15 -2.050 0.10499E+05 -4.450 3 CH4,gas 4.54 -12.49 -17.04 -4.259 0.29091E+05 -15.338 4 H2,gas 8.00 0.08 -7.92 -4.526 0.13525E+05 -6.222 5 H2S,gas -6.23 -20.11 -13.88 -6.941 0.23705E+05 -12.184 6 S2,gas -7.34 -40.38 -33.05 -5.084 0.56429E+05 -31.349 7 CO,gas 3.21 -12.73 -15.94 -4.906 0.27225E+05 -14.246 8 SO3,gas 17.12 -20.43 -37.55 -9.387 0.64115E+05 -35.851 9 SO2,gas 0.83 -20.35 -21.18 -5.648 0.36167E+05 -19.483 10 HCl,gas 5.19 -11.77 -16.96 -8.480 0.28958E+05 -15.261 11 acmite 7.71 3.67 -4.04 -0.420 0.68966E+04 15 albite-high 0.69 -3.28 -3.97 -0.306 0.67819E+04 16 albite -0.38 -3.28 -2.89 -0.223 0.49431E+04 19 spessartine 24.46 20.51 -3.94 -0.197 0.67351E+04 20 analcite 3.32 0.15 -3.17 -0.353 0.54180E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.48 -4.16 -2.081 0.71075E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.86 -2.83 -0.942 0.48259E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.86 -2.67 -0.891 0.45617E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23287E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29419E+04 42 celadonite 5.34 0.57 -4.77 -0.281 0.81423E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43572E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12914E+04 52 chloritoid-Mn 11.40 10.52 -0.88 -0.059 0.15057E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60389E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64751E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82444E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68766E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.15 -4.07 -0.407 0.69434E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 105 lizardite 23.24 18.80 -4.45 -0.371 0.75915E+04 106 magnesite 0.69 -4.26 -4.95 -1.649 0.84490E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20468E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.55 -2.06 -0.159 0.35241E+04 120 muscovite 2.58 0.97 -1.61 -0.095 0.27496E+04 121 paragonite 4.24 2.24 -2.00 -0.117 0.34078E+04 122 nepheline 8.34 3.58 -4.76 -0.680 0.81328E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49707E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58191E+04 145 pyroxmangite 7.40 5.00 -2.40 -0.480 0.41012E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.38 -3.41 -1.136 0.58190E+04 152 rhodonite 7.45 5.00 -2.45 -0.490 0.41814E+04 153 sanidine -1.28 -4.55 -3.27 -0.252 0.55918E+04 155 siderite -2.61 -6.49 -3.88 -1.293 0.66217E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.20 -1.82 -0.054 0.31034E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83481E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54865E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77665E+04 174 tephroite 18.09 13.42 -4.66 -0.666 0.79647E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.17 -3.64 -0.223 0.62237E+04 196 beidellite-Mg -1.79 -4.73 -2.94 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.75 -3.40 -0.208 0.58111E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.30 -3.06 -0.187 0.52252E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.88 -2.84 -0.174 0.48483E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.88 -1.46 -0.094 0.24966E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.30 -1.22 -0.078 0.20858E+04 214 gypsum -4.96 -9.48 -4.52 -1.131 0.77251E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59576E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.70 -2.72 -0.209 0.46403E+04 243 an25ab75 2.65 -0.06 -2.70 -0.208 0.46116E+04 244 an30ab70 3.28 0.59 -2.69 -0.207 0.45925E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0590000 g New total amount of reactant added: 0.0610000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0610000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2965143E-03 Osmotic coef. = 0.9897 True ionic strength = .3226821E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13110E-07 -7.8824 0.12573E-07 -7.9006 0.95902E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13229E-03 -3.8785 0.95888E+00 -0.0182 4 SO4-- 0.25399E-04 -4.5952 0.22661E-04 -4.6447 0.89222E+00 -0.0495 5 HCO3- 0.12631E-04 -4.8986 0.12112E-04 -4.9168 0.95892E+00 -0.0182 6 HS- 0.61320E-12 -12.2124 0.58798E-12 -12.2306 0.95889E+00 -0.0182 7 Al+++ 0.14502E-20 -20.8386 0.11470E-20 -20.9404 0.79091E+00 -0.1019 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.15752E-04 -4.8027 0.14052E-04 -4.8523 0.89207E+00 -0.0496 10 Mg++ 0.63029E-07 -7.2005 0.56220E-07 -7.2501 0.89197E+00 -0.0496 11 Fe++ 0.37234E-09 -9.4291 0.33213E-09 -9.4787 0.89200E+00 -0.0496 12 K+ 0.12946E-04 -4.8879 0.12415E-04 -4.9061 0.95892E+00 -0.0182 13 Na+ 0.23653E-03 -3.6261 0.22680E-03 -3.6444 0.95888E+00 -0.0182 14 Mn++ 0.47273E-07 -7.3254 0.42168E-07 -7.3750 0.89202E+00 -0.0496 15 HPO4-- 0.35597E-08 -8.4486 0.31760E-08 -8.4981 0.89223E+00 -0.0495 16 HSiO3- 0.28933E-04 -4.5386 0.27743E-04 -4.5568 0.95888E+00 -0.0182 17 Ca(HSiO3)+ 0.92584E-08 -8.0335 0.88781E-08 -8.0517 0.95893E+00 -0.0182 18 Mg(HSiO3)+ 0.46100E-10 -10.3363 0.44206E-10 -10.3545 0.95893E+00 -0.0182 19 NaHSiO3,aq 0.10177E-06 -6.9924 0.10177E-06 -6.9924 0.10000E+01 0.0000 20 AlO+ 0.10294E-11 -11.9874 0.98709E-12 -12.0056 0.95893E+00 -0.0182 21 AlOH+2 0.69278E-16 -16.1594 0.61798E-16 -16.2090 0.89204E+00 -0.0496 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.28708E-05 -5.5420 0.27526E-05 -5.5603 0.95884E+00 -0.0183 24 CH4,aq 0.30530E-18 -18.5153 0.30528E-18 -18.5153 0.99991E+00 0.0000 29 CO,aq 0.37333E-17 -17.4279 0.37333E-17 -17.4279 0.10000E+01 0.0000 30 CO2,aq 0.32543E-06 -6.4875 0.32540E-06 -6.4876 0.99991E+00 0.0000 31 CO3-2 0.94313E-07 -7.0254 0.84144E-07 -7.0750 0.89218E+00 -0.0495 32 CaCO3,aq 0.14825E-07 -7.8290 0.14825E-07 -7.8290 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45305E-08 -8.3439 0.43444E-08 -8.3621 0.95893E+00 -0.0182 34 CaCl+ 0.31371E-08 -8.5035 0.30083E-08 -8.5217 0.95893E+00 -0.0182 35 CaCl2,aq 0.94548E-13 -13.0243 0.94548E-13 -13.0243 0.10000E+01 0.0000 36 CaOH+ 0.83062E-07 -7.0806 0.79650E-07 -7.0988 0.95893E+00 -0.0182 37 CaSO4,aq 0.10112E-06 -6.9952 0.10112E-06 -6.9952 0.10000E+01 0.0000 38 HCl,aq 0.30479E-12 -12.5160 0.30479E-12 -12.5160 0.10000E+01 0.0000 43 FeCl+ 0.72524E-13 -13.1395 0.69545E-13 -13.1577 0.95893E+00 -0.0182 46 FeO,aq 0.81655E-10 -10.0880 0.81655E-10 -10.0880 0.10000E+01 0.0000 47 FeOH+ 0.89669E-09 -9.0474 0.85986E-09 -9.0656 0.95893E+00 -0.0182 48 HFeO2- 0.70866E-10 -10.1496 0.67952E-10 -10.1678 0.95888E+00 -0.0182 49 FeO+ 0.10008E-12 -12.9997 0.95969E-13 -13.0179 0.95893E+00 -0.0182 50 FeOH+2 0.25832E-18 -18.5878 0.23043E-18 -18.6375 0.89204E+00 -0.0496 51 FeO2- 0.12955E-09 -9.8876 0.12422E-09 -9.9058 0.95888E+00 -0.0182 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45675E-09 -9.3403 0.45671E-09 -9.3404 0.99991E+00 0.0000 54 KCl,aq 0.29766E-10 -10.5263 0.29766E-10 -10.5263 0.10000E+01 0.0000 55 KHSO4,aq 0.10001E-16 -17.0000 0.10001E-16 -17.0000 0.10000E+01 0.0000 56 KOH,aq 0.42167E-09 -9.3750 0.42167E-09 -9.3750 0.10000E+01 0.0000 57 KSO4- 0.45528E-08 -8.3417 0.43656E-08 -8.3600 0.95888E+00 -0.0182 58 MgCO3,aq 0.14868E-10 -10.8277 0.14868E-10 -10.8277 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18522E-10 -10.7323 0.17761E-10 -10.7505 0.95893E+00 -0.0182 60 MgCl+ 0.11376E-10 -10.9440 0.10909E-10 -10.9622 0.95893E+00 -0.0182 61 MgOH+ 0.18389E-08 -8.7354 0.17634E-08 -8.7536 0.95893E+00 -0.0182 63 MnO,aq 0.27625E-09 -9.5587 0.27625E-09 -9.5587 0.10000E+01 0.0000 64 MnOH+ 0.10576E-07 -7.9757 0.10142E-07 -7.9939 0.95893E+00 -0.0182 65 MnO2-2 0.65003E-16 -16.1871 0.57994E-16 -16.2366 0.89218E+00 -0.0495 66 HMnO2- 0.16660E-12 -12.7783 0.15975E-12 -12.7966 0.95888E+00 -0.0182 69 MnCl+ 0.35823E-10 -10.4458 0.34352E-10 -10.4640 0.95893E+00 -0.0182 70 MnSO4,aq 0.27587E-09 -9.5593 0.27587E-09 -9.5593 0.10000E+01 0.0000 71 NaCl,aq 0.99433E-08 -8.0025 0.99433E-08 -8.0025 0.10000E+01 0.0000 72 NaOH,aq 0.77502E-08 -8.1107 0.77502E-08 -8.1107 0.10000E+01 0.0000 74 OH- 0.47926E-04 -4.3194 0.45953E-04 -4.3377 0.95884E+00 -0.0183 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.76822E-09 -9.1145 0.73665E-09 -9.1327 0.95890E+00 -0.0182 84 PO4-3 0.26028E-12 -12.5846 0.20610E-12 -12.6859 0.79184E+00 -0.1014 87 H2P2O7-2 0.47691E-19 -19.3216 0.42549E-19 -19.3711 0.89218E+00 -0.0495 88 HP2O7-3 0.85437E-18 -18.0684 0.67573E-18 -18.1702 0.79092E+00 -0.1019 89 P2O7-4 0.19202E-19 -19.7167 0.12839E-19 -19.8915 0.66865E+00 -0.1748 90 H2S,aq 0.22850E-13 -13.6411 0.22848E-13 -13.6411 0.99991E+00 0.0000 97 SO3-2 0.15070E-14 -14.8219 0.13449E-14 -14.8713 0.89249E+00 -0.0494 98 HSO3- 0.11042E-14 -14.9570 0.10588E-14 -14.9752 0.95888E+00 -0.0182 99 HSO4- 0.28634E-09 -9.5431 0.27459E-09 -9.5613 0.95895E+00 -0.0182 Charge balance for all species = 0.2142E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1311033E-07 -.8837581E-04 -.8907292E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999466E+06 0.0000 3 Cl- 0.1379636E-03 0.1379767E-03 0.4891437E+01 4.0221 4 SO4-- 0.2539871E-04 0.2550487E-04 0.2449912E+01 11.1564 5 HCO3- 0.1263111E-04 0.1307024E-04 0.7974684E+00 2.9838 6 HS- 0.6131953E-12 0.7378887E-10 0.2440220E-05 -4.3301 7 Al+++ 0.1450234E-20 0.2886413E-05 0.7787572E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4026169E-03 0.3869568E+02 -3.4276 9 Ca++ 0.1575161E-04 0.1596754E-04 0.6399139E+00 10.9488 10 Mg++ 0.6302878E-07 0.6495858E-07 0.1579192E-02 8.5510 11 Fe++ 0.3723403E-09 0.1749914E-08 0.9772240E-04 6.3224 12 K+ 0.1294640E-04 0.1295141E-04 0.5063998E+00 2.9945 13 Na+ 0.2365258E-03 0.2366452E-03 0.5440146E+01 4.2562 14 Mn++ 0.4727327E-07 0.5843748E-07 0.3210272E-02 8.4261 15 HPO4-- 0.3559669E-08 0.4328150E-08 0.4153901E-03 7.3030 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9970294E-03 -.8837418E-04 -.9086553E-03 0.0000000E+00 2 H2O 0.5550749E+02 0.5550725E+02 0.2383465E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2719499E-04 0.2550440E-04 0.1690592E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1690518E-05 0.7378751E-10 -.1690592E-05 0.0000000E+00 7 Al+++ 0.1989052E-03 0.2886359E-05 0.1960189E-03 0.0000000E+00 8 H4SiO4 0.6351798E-03 0.4026094E-03 0.2325703E-03 0.0000000E+00 9 Ca++ 0.8462976E-04 0.1596724E-04 0.6866252E-04 0.0000000E+00 10 Mg++ 0.4841270E-04 0.6495738E-07 0.4834774E-04 0.0000000E+00 11 Fe++ 0.4349352E-04 0.1749882E-08 0.4349177E-04 0.0000000E+00 12 K+ 0.1295117E-04 0.1295117E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2366409E-03 0.2366409E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1057654E-05 0.5843640E-07 0.9992180E-06 0.0000000E+00 15 HPO4-- 0.3609722E-06 0.4328070E-08 0.3566441E-06 0.0000000E+00 Chg. balance for solid moles: 0.1257E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0610000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1189E-06 -6.925 0.5972E-04 -4.224 0.1589 0.1898E-04 clinochlore 0.9670E-05 -5.015 0.5375E-02 -2.270 14.30 0.2044E-02 daphnite 0.5993E-05 -5.222 0.4276E-02 -2.369 11.38 0.1296E-02 chlorite-Mn 0.1998E-06 -6.699 0.1417E-03 -3.849 0.3771 0.4515E-04 hematite 0.6762E-05 -5.170 0.1080E-02 -2.967 2.874 0.2047E-03 kaolinite 0.1408E-04 -4.851 0.3635E-02 -2.440 9.673 0.1398E-02 lawsonite 0.6393E-04 -4.194 0.2009E-01 -1.697 53.47 0.6478E-02 stilbite 0.4138E-05 -5.383 0.2916E-02 -2.535 7.761 0.1360E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3778E+00 0.3778E+00 1.0000 -0.423 chlorite-Mn 0.1260E-01 0.1260E-01 1.0000 -1.900 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.037572 g Volume = 0.012846 cm3 Porosity: 98.7460% V(tot) - V(min): 0.10116E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0610000 g log = -1.2147 Original solution: 1000.0103000 g Original solution / Rock added: 16393.61 (Water/Rock Ratio), log = 4.2147 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3388E-04 1.0071 0.3481E-04 0.3457E-04 CH4,gas 0.4349E-15 1.0125 0.4493E-15 0.4438E-15 H2,gas 0.5873E-06 1.0005 0.5996E-06 0.5993E-06 H2S,gas 0.6180E-12 0.9960 0.6281E-12 0.6306E-12 S2,gas 0.4037E-31 1.0000 0.4119E-31 0.4119E-31 CO,gas 0.5453E-14 1.0000 0.5563E-14 0.5563E-14 SO3,gas 0.1328E-35 1.0000 0.1355E-35 0.1355E-35 SO2,gas 0.3097E-19 1.0000 0.3160E-19 0.3160E-19 HCl,gas 0.5271E-15 1.0000 0.5378E-15 0.5378E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.82 -6.16 -2.052 0.10513E+05 -4.458 3 CH4,gas 4.54 -12.50 -17.05 -4.262 0.29106E+05 -15.347 4 H2,gas 8.00 0.08 -7.92 -4.526 0.13525E+05 -6.222 5 H2S,gas -6.23 -20.13 -13.90 -6.950 0.23735E+05 -12.202 6 S2,gas -7.34 -40.42 -33.08 -5.090 0.56490E+05 -31.385 7 CO,gas 3.21 -12.74 -15.95 -4.909 0.27240E+05 -14.255 8 SO3,gas 17.12 -20.45 -37.57 -9.392 0.64145E+05 -35.868 9 SO2,gas 0.83 -20.37 -21.20 -5.653 0.36197E+05 -19.500 10 HCl,gas 5.19 -11.78 -16.97 -8.484 0.28973E+05 -15.269 11 acmite 7.71 3.68 -4.03 -0.418 0.68737E+04 15 albite-high 0.69 -3.27 -3.96 -0.304 0.67590E+04 16 albite -0.38 -3.27 -2.88 -0.222 0.49202E+04 19 spessartine 24.46 20.52 -3.94 -0.197 0.67264E+04 20 analcite 3.32 0.16 -3.16 -0.351 0.53950E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.50 -4.18 -2.090 0.71376E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.87 -2.84 -0.945 0.48407E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.87 -2.68 -0.893 0.45765E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23287E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29420E+04 42 celadonite 5.34 0.60 -4.75 -0.279 0.81026E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43572E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12914E+04 52 chloritoid-Mn 11.40 10.52 -0.88 -0.059 0.15028E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60389E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64752E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82446E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68768E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.16 -4.05 -0.405 0.69205E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 105 lizardite 23.24 18.80 -4.45 -0.371 0.75915E+04 106 magnesite 0.69 -4.27 -4.96 -1.652 0.84638E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20469E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.53 -2.04 -0.157 0.34844E+04 120 muscovite 2.58 1.00 -1.59 -0.093 0.27099E+04 121 paragonite 4.24 2.26 -1.98 -0.117 0.33849E+04 122 nepheline 8.34 3.59 -4.75 -0.679 0.81099E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49708E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.00 -2.40 -0.480 0.40983E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.39 -3.41 -1.138 0.58309E+04 152 rhodonite 7.45 5.00 -2.45 -0.489 0.41785E+04 153 sanidine -1.28 -4.53 -3.25 -0.250 0.55521E+04 155 siderite -2.61 -6.49 -3.89 -1.296 0.66366E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.21 -1.81 -0.054 0.30839E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83483E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54865E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77665E+04 174 tephroite 18.09 13.42 -4.66 -0.666 0.79589E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.16 -3.64 -0.223 0.62106E+04 196 beidellite-Mg -1.79 -4.73 -2.94 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.74 -3.40 -0.208 0.58036E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.29 -3.05 -0.187 0.52121E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.87 -2.84 -0.174 0.48408E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.89 -1.45 -0.093 0.24835E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.30 -1.22 -0.078 0.20782E+04 214 gypsum -4.96 -9.50 -4.54 -1.135 0.77551E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59576E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.69 -2.71 -0.208 0.46220E+04 243 an25ab75 2.65 -0.05 -2.69 -0.207 0.45944E+04 244 an30ab70 3.28 0.60 -2.68 -0.206 0.45764E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0610000 g New total amount of reactant added: 0.0630000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0630000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2969716E-03 Osmotic coef. = 0.9897 True ionic strength = .3237208E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12846E-07 -7.8912 0.12319E-07 -7.9094 0.95899E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13229E-03 -3.8785 0.95885E+00 -0.0183 4 SO4-- 0.25403E-04 -4.5951 0.22661E-04 -4.6447 0.89209E+00 -0.0496 5 HCO3- 0.12636E-04 -4.8984 0.12116E-04 -4.9166 0.95888E+00 -0.0182 6 HS- 0.60034E-12 -12.2216 0.57564E-12 -12.2399 0.95885E+00 -0.0182 7 Al+++ 0.13645E-20 -20.8650 0.10789E-20 -20.9670 0.79064E+00 -0.1020 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.15124E-04 -4.8203 0.13489E-04 -4.8700 0.89194E+00 -0.0497 10 Mg++ 0.60516E-07 -7.2181 0.53970E-07 -7.2678 0.89184E+00 -0.0497 11 Fe++ 0.35746E-09 -9.4468 0.31881E-09 -9.4965 0.89186E+00 -0.0497 12 K+ 0.13371E-04 -4.8738 0.12821E-04 -4.8921 0.95889E+00 -0.0182 13 Na+ 0.23903E-03 -3.6215 0.22920E-03 -3.6398 0.95884E+00 -0.0183 14 Mn++ 0.45552E-07 -7.3415 0.40627E-07 -7.3912 0.89188E+00 -0.0497 15 HPO4-- 0.37086E-08 -8.4308 0.33084E-08 -8.4804 0.89209E+00 -0.0496 16 HSiO3- 0.29531E-04 -4.5297 0.28316E-04 -4.5480 0.95885E+00 -0.0183 17 Ca(HSiO3)+ 0.90716E-08 -8.0423 0.86987E-08 -8.0605 0.95889E+00 -0.0182 18 Mg(HSiO3)+ 0.45170E-10 -10.3452 0.43313E-10 -10.3634 0.95889E+00 -0.0182 19 NaHSiO3,aq 0.10496E-06 -6.9790 0.10496E-06 -6.9790 0.10000E+01 0.0000 20 AlO+ 0.10086E-11 -11.9963 0.96715E-12 -12.0145 0.95889E+00 -0.0182 21 AlOH+2 0.66516E-16 -16.1771 0.59326E-16 -16.2268 0.89190E+00 -0.0497 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.29301E-05 -5.5331 0.28094E-05 -5.5514 0.95881E+00 -0.0183 24 CH4,aq 0.29900E-18 -18.5243 0.29897E-18 -18.5244 0.99991E+00 0.0000 29 CO,aq 0.36584E-17 -17.4367 0.36584E-17 -17.4367 0.10000E+01 0.0000 30 CO2,aq 0.31897E-06 -6.4963 0.31894E-06 -6.4963 0.99991E+00 0.0000 31 CO3-2 0.96307E-07 -7.0163 0.85910E-07 -7.0660 0.89204E+00 -0.0496 32 CaCO3,aq 0.14531E-07 -7.8377 0.14531E-07 -7.8377 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43509E-08 -8.3614 0.41721E-08 -8.3796 0.95889E+00 -0.0182 34 CaCl+ 0.30116E-08 -8.5212 0.28878E-08 -8.5394 0.95889E+00 -0.0182 35 CaCl2,aq 0.90759E-13 -13.0421 0.90759E-13 -13.0421 0.10000E+01 0.0000 36 CaOH+ 0.81386E-07 -7.0894 0.78041E-07 -7.1077 0.95889E+00 -0.0182 37 CaSO4,aq 0.97071E-07 -7.0129 0.97071E-07 -7.0129 0.10000E+01 0.0000 38 HCl,aq 0.29862E-12 -12.5249 0.29862E-12 -12.5249 0.10000E+01 0.0000 43 FeCl+ 0.69616E-13 -13.1573 0.66754E-13 -13.1755 0.95889E+00 -0.0182 46 FeO,aq 0.81647E-10 -10.0881 0.81647E-10 -10.0881 0.10000E+01 0.0000 47 FeOH+ 0.87851E-09 -9.0563 0.84240E-09 -9.0745 0.95889E+00 -0.0182 48 HFeO2- 0.72323E-10 -10.1407 0.69347E-10 -10.1590 0.95885E+00 -0.0183 49 FeO+ 0.98061E-13 -13.0085 0.94030E-13 -13.0267 0.95889E+00 -0.0182 50 FeOH+2 0.24802E-18 -18.6055 0.22121E-18 -18.6552 0.89190E+00 -0.0497 51 FeO2- 0.13222E-09 -9.8787 0.12678E-09 -9.8969 0.95885E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45666E-09 -9.3404 0.45662E-09 -9.3404 0.99991E+00 0.0000 54 KCl,aq 0.30740E-10 -10.5123 0.30740E-10 -10.5123 0.10000E+01 0.0000 55 KHSO4,aq 0.10120E-16 -16.9948 0.10120E-16 -16.9948 0.10000E+01 0.0000 56 KOH,aq 0.44446E-09 -9.3522 0.44446E-09 -9.3522 0.10000E+01 0.0000 57 KSO4- 0.47021E-08 -8.3277 0.45086E-08 -8.3460 0.95885E+00 -0.0183 58 MgCO3,aq 0.14573E-10 -10.8365 0.14573E-10 -10.8365 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17788E-10 -10.7499 0.17056E-10 -10.7681 0.95889E+00 -0.0182 60 MgCl+ 0.10921E-10 -10.9617 0.10472E-10 -10.9800 0.95889E+00 -0.0182 61 MgOH+ 0.18018E-08 -8.7443 0.17278E-08 -8.7625 0.95889E+00 -0.0182 63 MnO,aq 0.27724E-09 -9.5571 0.27724E-09 -9.5571 0.10000E+01 0.0000 64 MnOH+ 0.10400E-07 -7.9830 0.99725E-08 -8.0012 0.95889E+00 -0.0182 65 MnO2-2 0.67966E-16 -16.1677 0.60628E-16 -16.2173 0.89204E+00 -0.0496 66 HMnO2- 0.17065E-12 -12.7679 0.16363E-12 -12.7861 0.95885E+00 -0.0183 69 MnCl+ 0.34514E-10 -10.4620 0.33095E-10 -10.4802 0.95889E+00 -0.0182 70 MnSO4,aq 0.26579E-09 -9.5755 0.26579E-09 -9.5755 0.10000E+01 0.0000 71 NaCl,aq 0.10048E-07 -7.9979 0.10048E-07 -7.9979 0.10000E+01 0.0000 72 NaOH,aq 0.79936E-08 -8.0973 0.79936E-08 -8.0973 0.10000E+01 0.0000 74 OH- 0.48916E-04 -4.3105 0.46901E-04 -4.3288 0.95881E+00 -0.0183 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.78409E-09 -9.1056 0.75184E-09 -9.1239 0.95887E+00 -0.0182 84 PO4-3 0.27681E-12 -12.5578 0.21912E-12 -12.6593 0.79157E+00 -0.1015 87 H2P2O7-2 0.49686E-19 -19.3038 0.44322E-19 -19.3534 0.89204E+00 -0.0496 88 HP2O7-3 0.90863E-18 -18.0416 0.71841E-18 -18.1436 0.79065E+00 -0.1020 89 P2O7-4 0.20848E-19 -19.6809 0.13932E-19 -19.8560 0.66825E+00 -0.1751 90 H2S,aq 0.21919E-13 -13.6592 0.21917E-13 -13.6592 0.99991E+00 0.0000 97 SO3-2 0.15069E-14 -14.8219 0.13447E-14 -14.8714 0.89236E+00 -0.0495 98 HSO3- 0.10817E-14 -14.9659 0.10372E-14 -14.9841 0.95885E+00 -0.0183 99 HSO4- 0.28057E-09 -9.5520 0.26904E-09 -9.5702 0.95891E+00 -0.0182 Charge balance for all species = 0.2146E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1284589E-07 -.9021092E-04 -.9092249E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999465E+06 0.0000 3 Cl- 0.1379637E-03 0.1379768E-03 0.4891438E+01 4.0309 4 SO4-- 0.2540263E-04 0.2550488E-04 0.2449913E+01 11.1741 5 HCO3- 0.1263606E-04 0.1307025E-04 0.7974686E+00 2.9928 6 HS- 0.6003416E-12 0.7341755E-10 0.2427940E-05 -4.3304 7 Al+++ 0.1364549E-20 0.2945728E-05 0.7947606E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4032177E-03 0.3875342E+02 -3.4276 9 Ca++ 0.1512376E-04 0.1533318E-04 0.6144913E+00 10.9488 10 Mg++ 0.6051581E-07 0.6240609E-07 0.1517138E-02 8.5510 11 Fe++ 0.3574628E-09 0.1720982E-08 0.9610669E-04 6.3224 12 K+ 0.1337087E-04 0.1337605E-04 0.5230032E+00 3.0174 13 Na+ 0.2390329E-03 0.2391559E-03 0.5497861E+01 4.2696 14 Mn++ 0.4555235E-07 0.5653015E-07 0.3105493E-02 8.4277 15 HPO4-- 0.3708564E-08 0.4492934E-08 0.4312050E-03 7.3385 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1030146E-02 -.9020922E-04 -.9399373E-03 0.0000000E+00 2 H2O 0.5550746E+02 0.5550723E+02 0.2343082E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2725041E-04 0.2550440E-04 0.1746018E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1745945E-05 0.7341616E-10 -.1746018E-05 0.0000000E+00 7 Al+++ 0.2054267E-03 0.2945673E-05 0.2024810E-03 0.0000000E+00 8 H4SiO4 0.6560053E-03 0.4032101E-03 0.2527952E-03 0.0000000E+00 9 Ca++ 0.8693005E-04 0.1533289E-04 0.7159716E-04 0.0000000E+00 10 Mg++ 0.5000000E-04 0.6240491E-07 0.4993760E-04 0.0000000E+00 11 Fe++ 0.4491954E-04 0.1720949E-08 0.4491782E-04 0.0000000E+00 12 K+ 0.1337580E-04 0.1337580E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2391513E-03 0.2391513E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1092332E-05 0.5652908E-07 0.1035802E-05 0.0000000E+00 15 HPO4-- 0.3728073E-06 0.4492849E-08 0.3683145E-06 0.0000000E+00 Chg. balance for solid moles: 0.6141E-20 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0630000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1228E-06 -6.911 0.6167E-04 -4.210 0.1548 0.1960E-04 clinochlore 0.9988E-05 -5.001 0.5551E-02 -2.256 13.94 0.2112E-02 daphnite 0.6190E-05 -5.208 0.4417E-02 -2.355 11.09 0.1338E-02 chlorite-Mn 0.2072E-06 -6.684 0.1469E-03 -3.833 0.3688 0.4680E-04 hematite 0.6984E-05 -5.156 0.1115E-02 -2.953 2.800 0.2114E-03 kaolinite 0.1387E-04 -4.858 0.3581E-02 -2.446 8.992 0.1378E-02 lawsonite 0.6420E-04 -4.192 0.2017E-01 -1.695 50.65 0.6505E-02 stilbite 0.6786E-05 -5.168 0.4782E-02 -2.320 12.01 0.2230E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3778E+00 0.3778E+00 1.0000 -0.423 chlorite-Mn 0.1264E-01 0.1264E-01 1.0000 -1.898 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.039829 g Volume = 0.013842 cm3 Porosity: 98.6499% V(tot) - V(min): 0.10114E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0630000 g log = -1.2007 Original solution: 1000.0103000 g Original solution / Rock added: 15873.18 (Water/Rock Ratio), log = 4.2007 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3321E-04 1.0071 0.3412E-04 0.3388E-04 CH4,gas 0.4260E-15 1.0125 0.4401E-15 0.4346E-15 H2,gas 0.5872E-06 1.0005 0.5995E-06 0.5992E-06 H2S,gas 0.5928E-12 0.9960 0.6025E-12 0.6049E-12 S2,gas 0.3716E-31 1.0000 0.3791E-31 0.3791E-31 CO,gas 0.5343E-14 1.0000 0.5452E-14 0.5452E-14 SO3,gas 0.1274E-35 1.0000 0.1300E-35 0.1300E-35 SO2,gas 0.2972E-19 1.0000 0.3033E-19 0.3033E-19 HCl,gas 0.5164E-15 1.0000 0.5269E-15 0.5269E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.83 -6.17 -2.055 0.10528E+05 -4.467 3 CH4,gas 4.54 -12.51 -17.06 -4.264 0.29122E+05 -15.356 4 H2,gas 8.00 0.08 -7.92 -4.526 0.13525E+05 -6.222 5 H2S,gas -6.23 -20.15 -13.92 -6.960 0.23766E+05 -12.220 6 S2,gas -7.34 -40.46 -33.12 -5.095 0.56552E+05 -31.421 7 CO,gas 3.21 -12.75 -15.96 -4.912 0.27255E+05 -14.263 8 SO3,gas 17.12 -20.46 -37.58 -9.396 0.64175E+05 -35.886 9 SO2,gas 0.83 -20.38 -21.22 -5.658 0.36228E+05 -19.518 10 HCl,gas 5.19 -11.79 -16.98 -8.489 0.28988E+05 -15.278 11 acmite 7.71 3.70 -4.01 -0.417 0.68508E+04 15 albite-high 0.69 -3.25 -3.95 -0.303 0.67361E+04 16 albite -0.38 -3.25 -2.87 -0.221 0.48973E+04 19 spessartine 24.46 20.52 -3.93 -0.197 0.67184E+04 20 analcite 3.32 0.18 -3.15 -0.350 0.53721E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.51 -4.20 -2.099 0.71678E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.88 -2.84 -0.948 0.48556E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.88 -2.69 -0.896 0.45914E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23287E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29420E+04 42 celadonite 5.34 0.62 -4.72 -0.278 0.80636E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43572E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12915E+04 52 chloritoid-Mn 11.40 10.52 -0.88 -0.059 0.15001E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60389E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64753E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82447E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68771E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.18 -4.04 -0.404 0.68976E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 105 lizardite 23.24 18.80 -4.45 -0.371 0.75916E+04 106 magnesite 0.69 -4.28 -4.97 -1.655 0.84787E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20470E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.50 -2.02 -0.155 0.34453E+04 120 muscovite 2.58 1.02 -1.56 -0.092 0.26709E+04 121 paragonite 4.24 2.27 -1.97 -0.116 0.33619E+04 122 nepheline 8.34 3.60 -4.74 -0.677 0.80869E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49708E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.00 -2.40 -0.480 0.40956E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.40 -3.42 -1.141 0.58431E+04 152 rhodonite 7.45 5.00 -2.45 -0.489 0.41759E+04 153 sanidine -1.28 -4.50 -3.23 -0.248 0.55131E+04 155 siderite -2.61 -6.50 -3.90 -1.299 0.66515E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.22 -1.79 -0.054 0.30648E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83484E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54866E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77665E+04 174 tephroite 18.09 13.43 -4.66 -0.665 0.79536E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.15 -3.63 -0.222 0.61977E+04 196 beidellite-Mg -1.79 -4.73 -2.94 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.74 -3.39 -0.208 0.57960E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.28 -3.04 -0.186 0.51992E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.87 -2.83 -0.173 0.48332E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.89 -1.45 -0.093 0.24707E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.31 -1.21 -0.078 0.20707E+04 214 gypsum -4.96 -9.51 -4.56 -1.140 0.77854E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59577E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.68 -2.70 -0.207 0.46036E+04 243 an25ab75 2.65 -0.03 -2.68 -0.206 0.45772E+04 244 an30ab70 3.28 0.61 -2.67 -0.205 0.45604E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0630000 g New total amount of reactant added: 0.0650000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0650000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2974801E-03 Osmotic coef. = 0.9897 True ionic strength = .3248249E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12585E-07 -7.9001 0.12069E-07 -7.9183 0.95895E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13228E-03 -3.8785 0.95881E+00 -0.0183 4 SO4-- 0.25406E-04 -4.5951 0.22661E-04 -4.6447 0.89195E+00 -0.0497 5 HCO3- 0.12641E-04 -4.8982 0.12121E-04 -4.9165 0.95884E+00 -0.0183 6 HS- 0.58772E-12 -12.2308 0.56351E-12 -12.2491 0.95881E+00 -0.0183 7 Al+++ 0.12835E-20 -20.8916 0.10144E-20 -20.9938 0.79035E+00 -0.1022 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.14518E-04 -4.8381 0.12947E-04 -4.8878 0.89179E+00 -0.0497 10 Mg++ 0.58090E-07 -7.2359 0.51799E-07 -7.2857 0.89170E+00 -0.0498 11 Fe++ 0.34310E-09 -9.4646 0.30595E-09 -9.5143 0.89172E+00 -0.0498 12 K+ 0.13795E-04 -4.8603 0.13228E-04 -4.8785 0.95885E+00 -0.0183 13 Na+ 0.24154E-03 -3.6170 0.23159E-03 -3.6353 0.95881E+00 -0.0183 14 Mn++ 0.43872E-07 -7.3578 0.39123E-07 -7.4076 0.89174E+00 -0.0498 15 HPO4-- 0.38646E-08 -8.4129 0.34471E-08 -8.4626 0.89195E+00 -0.0497 16 HSiO3- 0.30145E-04 -4.5208 0.28903E-04 -4.5391 0.95881E+00 -0.0183 17 Ca(HSiO3)+ 0.88876E-08 -8.0512 0.85219E-08 -8.0695 0.95885E+00 -0.0182 18 Mg(HSiO3)+ 0.44253E-10 -10.3541 0.42432E-10 -10.3723 0.95885E+00 -0.0182 19 NaHSiO3,aq 0.10826E-06 -6.9655 0.10826E-06 -6.9655 0.10000E+01 0.0000 20 AlO+ 0.98815E-12 -12.0052 0.94749E-12 -12.0234 0.95885E+00 -0.0182 21 AlOH+2 0.63851E-16 -16.1948 0.56939E-16 -16.2446 0.89176E+00 -0.0498 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.29910E-05 -5.5242 0.28677E-05 -5.5425 0.95877E+00 -0.0183 24 CH4,aq 0.29280E-18 -18.5334 0.29277E-18 -18.5335 0.99991E+00 0.0000 29 CO,aq 0.35846E-17 -17.4456 0.35846E-17 -17.4456 0.10000E+01 0.0000 30 CO2,aq 0.31259E-06 -6.5050 0.31256E-06 -6.5051 0.99991E+00 0.0000 31 CO3-2 0.98353E-07 -7.0072 0.87722E-07 -7.0569 0.89190E+00 -0.0497 32 CaCO3,aq 0.14241E-07 -7.8465 0.14241E-07 -7.8465 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41775E-08 -8.3791 0.40056E-08 -8.3973 0.95885E+00 -0.0182 34 CaCl+ 0.28905E-08 -8.5390 0.27715E-08 -8.5573 0.95885E+00 -0.0182 35 CaCl2,aq 0.87101E-13 -13.0600 0.87101E-13 -13.0600 0.10000E+01 0.0000 36 CaOH+ 0.79736E-07 -7.0983 0.76455E-07 -7.1166 0.95885E+00 -0.0182 37 CaSO4,aq 0.93165E-07 -7.0307 0.93165E-07 -7.0307 0.10000E+01 0.0000 38 HCl,aq 0.29254E-12 -12.5338 0.29254E-12 -12.5338 0.10000E+01 0.0000 43 FeCl+ 0.66809E-13 -13.1752 0.64060E-13 -13.1934 0.95885E+00 -0.0182 46 FeO,aq 0.81640E-10 -10.0881 0.81640E-10 -10.0881 0.10000E+01 0.0000 47 FeOH+ 0.86061E-09 -9.0652 0.82520E-09 -9.0834 0.95885E+00 -0.0182 48 HFeO2- 0.73819E-10 -10.1318 0.70779E-10 -10.1501 0.95881E+00 -0.0183 49 FeO+ 0.96072E-13 -13.0174 0.92119E-13 -13.0357 0.95885E+00 -0.0182 50 FeOH+2 0.23808E-18 -18.6233 0.21231E-18 -18.6730 0.89176E+00 -0.0498 51 FeO2- 0.13497E-09 -9.8698 0.12941E-09 -9.8880 0.95881E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45658E-09 -9.3405 0.45653E-09 -9.3405 0.99991E+00 0.0000 54 KCl,aq 0.31713E-10 -10.4988 0.31713E-10 -10.4988 0.10000E+01 0.0000 55 KHSO4,aq 0.10228E-16 -16.9902 0.10228E-16 -16.9902 0.10000E+01 0.0000 56 KOH,aq 0.46807E-09 -9.3297 0.46807E-09 -9.3297 0.10000E+01 0.0000 57 KSO4- 0.48513E-08 -8.3141 0.46515E-08 -8.3324 0.95881E+00 -0.0183 58 MgCO3,aq 0.14281E-10 -10.8452 0.14281E-10 -10.8452 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17078E-10 -10.7676 0.16376E-10 -10.7858 0.95885E+00 -0.0182 60 MgCl+ 0.10481E-10 -10.9796 0.10050E-10 -10.9978 0.95885E+00 -0.0182 61 MgOH+ 0.17653E-08 -8.7532 0.16926E-08 -8.7714 0.95885E+00 -0.0182 63 MnO,aq 0.27816E-09 -9.5557 0.27816E-09 -9.5557 0.10000E+01 0.0000 64 MnOH+ 0.10223E-07 -7.9904 0.98024E-08 -8.0087 0.95885E+00 -0.0182 65 MnO2-2 0.71062E-16 -16.1484 0.63380E-16 -16.1980 0.89190E+00 -0.0497 66 HMnO2- 0.17478E-12 -12.7575 0.16758E-12 -12.7758 0.95881E+00 -0.0183 69 MnCl+ 0.33236E-10 -10.4784 0.31868E-10 -10.4966 0.95885E+00 -0.0182 70 MnSO4,aq 0.25594E-09 -9.5919 0.25594E-09 -9.5919 0.10000E+01 0.0000 71 NaCl,aq 0.10152E-07 -7.9934 0.10152E-07 -7.9934 0.10000E+01 0.0000 72 NaOH,aq 0.82447E-08 -8.0838 0.82447E-08 -8.0838 0.10000E+01 0.0000 74 OH- 0.49933E-04 -4.3016 0.47874E-04 -4.3199 0.95877E+00 -0.0183 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.80039E-09 -9.0967 0.76743E-09 -9.1150 0.95883E+00 -0.0183 84 PO4-3 0.29450E-12 -12.5309 0.23304E-12 -12.6326 0.79129E+00 -0.1017 87 H2P2O7-2 0.51777E-19 -19.2859 0.46180E-19 -19.3355 0.89190E+00 -0.0497 88 HP2O7-3 0.96671E-18 -18.0147 0.76405E-18 -18.1169 0.79036E+00 -0.1022 89 P2O7-4 0.22647E-19 -19.6450 0.15124E-19 -19.8203 0.66783E+00 -0.1753 90 H2S,aq 0.21021E-13 -13.6774 0.21019E-13 -13.6774 0.99991E+00 0.0000 97 SO3-2 0.15068E-14 -14.8219 0.13444E-14 -14.8715 0.89221E+00 -0.0495 98 HSO3- 0.10595E-14 -14.9749 0.10159E-14 -14.9931 0.95881E+00 -0.0183 99 HSO4- 0.27487E-09 -9.5609 0.26357E-09 -9.5791 0.95887E+00 -0.0182 Charge balance for all species = 0.2151E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1258534E-07 -.9209488E-04 -.9282130E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999464E+06 0.0000 3 Cl- 0.1379637E-03 0.1379768E-03 0.4891439E+01 4.0398 4 SO4-- 0.2540641E-04 0.2550489E-04 0.2449913E+01 11.1920 5 HCO3- 0.1264086E-04 0.1307025E-04 0.7974688E+00 3.0019 6 HS- 0.5877174E-12 0.7303933E-10 0.2415432E-05 -4.3308 7 Al+++ 0.1283501E-20 0.3006628E-05 0.8111914E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4038346E-03 0.3881271E+02 -3.4276 9 Ca++ 0.1451765E-04 0.1472075E-04 0.5899475E+00 10.9488 10 Mg++ 0.5808994E-07 0.5994129E-07 0.1457217E-02 8.5510 11 Fe++ 0.3431048E-09 0.1692957E-08 0.9454165E-04 6.3223 12 K+ 0.1379534E-04 0.1380069E-04 0.5396066E+00 3.0398 13 Na+ 0.2415398E-03 0.2416665E-03 0.5555576E+01 4.2831 14 Mn++ 0.4387235E-07 0.5466293E-07 0.3002916E-02 8.4291 15 HPO4-- 0.3864631E-08 0.4665316E-08 0.4477491E-03 7.3741 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1063264E-02 -.9209311E-04 -.9711704E-03 0.0000000E+00 2 H2O 0.5550744E+02 0.5550721E+02 0.2302616E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2730584E-04 0.2550440E-04 0.1801445E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1801372E-05 0.7303792E-10 -.1801445E-05 0.0000000E+00 7 Al+++ 0.2119482E-03 0.3006570E-05 0.2089416E-03 0.0000000E+00 8 H4SiO4 0.6768309E-03 0.4038268E-03 0.2730041E-03 0.0000000E+00 9 Ca++ 0.8923033E-04 0.1472046E-04 0.7450987E-04 0.0000000E+00 10 Mg++ 0.5158730E-04 0.5994014E-07 0.5152736E-04 0.0000000E+00 11 Fe++ 0.4634556E-04 0.1692924E-08 0.4634387E-04 0.0000000E+00 12 K+ 0.1380042E-04 0.1380042E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2416618E-03 0.2416618E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1127009E-05 0.5466188E-07 0.1072347E-05 0.0000000E+00 15 HPO4-- 0.3846425E-06 0.4665226E-08 0.3799773E-06 0.0000000E+00 Chg. balance for solid moles: -.6353E-20 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0650000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1267E-06 -6.897 0.6362E-04 -4.196 0.1512 0.2022E-04 clinochlore 0.1031E-04 -4.987 0.5728E-02 -2.242 13.61 0.2179E-02 daphnite 0.6386E-05 -5.195 0.4557E-02 -2.341 10.83 0.1381E-02 chlorite-Mn 0.2145E-06 -6.669 0.1521E-03 -3.818 0.3613 0.4846E-04 hematite 0.7206E-05 -5.142 0.1151E-02 -2.939 2.735 0.2181E-03 kaolinite 0.1369E-04 -4.864 0.3534E-02 -2.452 8.397 0.1360E-02 lawsonite 0.6445E-04 -4.191 0.2025E-01 -1.694 48.12 0.6531E-02 stilbite 0.9431E-05 -5.025 0.6646E-02 -2.177 15.79 0.3100E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3778E+00 0.3778E+00 1.0000 -0.423 chlorite-Mn 0.1269E-01 0.1269E-01 1.0000 -1.897 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.042083 g Volume = 0.014837 cm3 Porosity: 98.5539% V(tot) - V(min): 0.10112E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0650000 g log = -1.1871 Original solution: 1000.0103000 g Original solution / Rock added: 15384.77 (Water/Rock Ratio), log = 4.1871 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3254E-04 1.0071 0.3344E-04 0.3321E-04 CH4,gas 0.4171E-15 1.0125 0.4309E-15 0.4256E-15 H2,gas 0.5871E-06 1.0005 0.5994E-06 0.5991E-06 H2S,gas 0.5685E-12 0.9960 0.5778E-12 0.5801E-12 S2,gas 0.3419E-31 1.0000 0.3488E-31 0.3488E-31 CO,gas 0.5235E-14 1.0000 0.5342E-14 0.5342E-14 SO3,gas 0.1223E-35 1.0000 0.1248E-35 0.1248E-35 SO2,gas 0.2852E-19 1.0000 0.2910E-19 0.2910E-19 HCl,gas 0.5059E-15 1.0000 0.5162E-15 0.5162E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.17819E-10 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.27298E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.83 -6.17 -2.058 0.10543E+05 -4.476 3 CH4,gas 4.54 -12.52 -17.06 -4.266 0.29137E+05 -15.366 4 H2,gas 8.00 0.08 -7.92 -4.526 0.13525E+05 -6.222 5 H2S,gas -6.23 -20.17 -13.94 -6.969 0.23797E+05 -12.238 6 S2,gas -7.34 -40.49 -33.16 -5.101 0.56614E+05 -31.457 7 CO,gas 3.21 -12.76 -15.97 -4.914 0.27271E+05 -14.272 8 SO3,gas 17.12 -20.48 -37.60 -9.401 0.64206E+05 -35.904 9 SO2,gas 0.83 -20.40 -21.24 -5.663 0.36258E+05 -19.536 10 HCl,gas 5.19 -11.80 -16.99 -8.493 0.29003E+05 -15.287 11 acmite 7.71 3.71 -4.00 -0.415 0.68279E+04 15 albite-high 0.69 -3.24 -3.93 -0.302 0.67131E+04 16 albite -0.38 -3.24 -2.85 -0.220 0.48743E+04 19 spessartine 24.46 20.53 -3.93 -0.197 0.67111E+04 20 analcite 3.32 0.19 -3.13 -0.348 0.53492E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.53 -4.22 -2.108 0.71983E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.89 -2.85 -0.951 0.48706E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.89 -2.70 -0.899 0.46063E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29421E+04 42 celadonite 5.34 0.64 -4.70 -0.276 0.80252E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43572E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12916E+04 52 chloritoid-Mn 11.40 10.52 -0.88 -0.058 0.14976E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60389E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64753E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82448E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68773E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.19 -4.03 -0.403 0.68747E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 105 lizardite 23.24 18.80 -4.45 -0.371 0.75916E+04 106 magnesite 0.69 -4.28 -4.97 -1.658 0.84937E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20470E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.48 -2.00 -0.153 0.34070E+04 120 muscovite 2.58 1.04 -1.54 -0.091 0.26325E+04 121 paragonite 4.24 2.28 -1.96 -0.115 0.33390E+04 122 nepheline 8.34 3.62 -4.72 -0.675 0.80640E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49709E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.00 -2.40 -0.479 0.40931E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.41 -3.43 -1.143 0.58556E+04 152 rhodonite 7.45 5.00 -2.44 -0.489 0.41734E+04 153 sanidine -1.28 -4.48 -3.21 -0.247 0.54747E+04 155 siderite -2.61 -6.51 -3.90 -1.301 0.66665E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.23 -1.78 -0.053 0.30460E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83486E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54866E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77666E+04 174 tephroite 18.09 13.43 -4.66 -0.665 0.79486E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.14 -3.62 -0.222 0.61850E+04 196 beidellite-Mg -1.79 -4.73 -2.94 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.73 -3.39 -0.208 0.57884E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.27 -3.04 -0.186 0.51865E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.86 -2.83 -0.173 0.48256E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.90 -1.44 -0.092 0.24580E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.31 -1.21 -0.078 0.20631E+04 214 gypsum -4.96 -9.53 -4.58 -1.144 0.78159E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59578E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.67 -2.69 -0.207 0.45853E+04 243 an25ab75 2.65 -0.02 -2.67 -0.205 0.45600E+04 244 an30ab70 3.28 0.62 -2.66 -0.205 0.45443E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0650000 g New total amount of reactant added: 0.0670000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0670000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2980396E-03 Osmotic coef. = 0.9897 True ionic strength = .3259942E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12329E-07 -7.9091 0.11822E-07 -7.9273 0.95891E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13228E-03 -3.8785 0.95877E+00 -0.0183 4 SO4-- 0.25410E-04 -4.5950 0.22661E-04 -4.6447 0.89180E+00 -0.0497 5 HCO3- 0.12645E-04 -4.8981 0.12125E-04 -4.9163 0.95880E+00 -0.0183 6 HS- 0.57533E-12 -12.2401 0.55161E-12 -12.2584 0.95877E+00 -0.0183 7 Al+++ 0.12069E-20 -20.9183 0.95354E-21 -21.0207 0.79005E+00 -0.1023 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.13933E-04 -4.8559 0.12423E-04 -4.9058 0.89164E+00 -0.0498 10 Mg++ 0.55751E-07 -7.2537 0.49704E-07 -7.3036 0.89154E+00 -0.0499 11 Fe++ 0.32926E-09 -9.4825 0.29356E-09 -9.5323 0.89157E+00 -0.0498 12 K+ 0.14220E-04 -4.8471 0.13634E-04 -4.8654 0.95881E+00 -0.0183 13 Na+ 0.24405E-03 -3.6125 0.23398E-03 -3.6308 0.95876E+00 -0.0183 14 Mn++ 0.42236E-07 -7.3743 0.37657E-07 -7.4242 0.89159E+00 -0.0498 15 HPO4-- 0.40281E-08 -8.3949 0.35923E-08 -8.4446 0.89180E+00 -0.0497 16 HSiO3- 0.30774E-04 -4.5118 0.29505E-04 -4.5301 0.95877E+00 -0.0183 17 Ca(HSiO3)+ 0.87065E-08 -8.0602 0.83479E-08 -8.0784 0.95881E+00 -0.0183 18 Mg(HSiO3)+ 0.43351E-10 -10.3630 0.41565E-10 -10.3813 0.95881E+00 -0.0183 19 NaHSiO3,aq 0.11166E-06 -6.9521 0.11166E-06 -6.9521 0.10000E+01 0.0000 20 AlO+ 0.96802E-12 -12.0141 0.92815E-12 -12.0324 0.95881E+00 -0.0183 21 AlOH+2 0.61280E-16 -16.2127 0.54638E-16 -16.2625 0.89161E+00 -0.0498 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.30535E-05 -5.5152 0.29274E-05 -5.5335 0.95873E+00 -0.0183 24 CH4,aq 0.28672E-18 -18.5425 0.28669E-18 -18.5426 0.99991E+00 0.0000 29 CO,aq 0.35120E-17 -17.4544 0.35120E-17 -17.4544 0.10000E+01 0.0000 30 CO2,aq 0.30631E-06 -6.5138 0.30628E-06 -6.5139 0.99991E+00 0.0000 31 CO3-2 0.10045E-06 -6.9980 0.89579E-07 -7.0478 0.89175E+00 -0.0498 32 CaCO3,aq 0.13954E-07 -7.8553 0.13954E-07 -7.8553 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40101E-08 -8.3968 0.38449E-08 -8.4151 0.95881E+00 -0.0183 34 CaCl+ 0.27736E-08 -8.5570 0.26594E-08 -8.5752 0.95881E+00 -0.0183 35 CaCl2,aq 0.83573E-13 -13.0779 0.83573E-13 -13.0779 0.10000E+01 0.0000 36 CaOH+ 0.78111E-07 -7.1073 0.74894E-07 -7.1256 0.95881E+00 -0.0183 37 CaSO4,aq 0.89396E-07 -7.0487 0.89396E-07 -7.0487 0.10000E+01 0.0000 38 HCl,aq 0.28656E-12 -12.5428 0.28656E-12 -12.5428 0.10000E+01 0.0000 43 FeCl+ 0.64103E-13 -13.1931 0.61463E-13 -13.2114 0.95881E+00 -0.0183 46 FeO,aq 0.81632E-10 -10.0881 0.81632E-10 -10.0881 0.10000E+01 0.0000 47 FeOH+ 0.84300E-09 -9.0742 0.80828E-09 -9.0924 0.95881E+00 -0.0183 48 HFeO2- 0.75355E-10 -10.1229 0.72248E-10 -10.1412 0.95877E+00 -0.0183 49 FeO+ 0.94114E-13 -13.0263 0.90238E-13 -13.0446 0.95881E+00 -0.0183 50 FeOH+2 0.22850E-18 -18.6411 0.20373E-18 -18.6909 0.89161E+00 -0.0498 51 FeO2- 0.13779E-09 -9.8608 0.13211E-09 -9.8791 0.95877E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45650E-09 -9.3406 0.45645E-09 -9.3406 0.99991E+00 0.0000 54 KCl,aq 0.32686E-10 -10.4856 0.32686E-10 -10.4856 0.10000E+01 0.0000 55 KHSO4,aq 0.10327E-16 -16.9860 0.10327E-16 -16.9860 0.10000E+01 0.0000 56 KOH,aq 0.49250E-09 -9.3076 0.49250E-09 -9.3076 0.10000E+01 0.0000 57 KSO4- 0.50004E-08 -8.3010 0.47943E-08 -8.3193 0.95877E+00 -0.0183 58 MgCO3,aq 0.13994E-10 -10.8541 0.13994E-10 -10.8541 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16394E-10 -10.7853 0.15719E-10 -10.8036 0.95881E+00 -0.0183 60 MgCl+ 0.10058E-10 -10.9975 0.96433E-11 -11.0158 0.95881E+00 -0.0183 61 MgOH+ 0.17293E-08 -8.7621 0.16580E-08 -8.7804 0.95881E+00 -0.0183 63 MnO,aq 0.27902E-09 -9.5544 0.27902E-09 -9.5544 0.10000E+01 0.0000 64 MnOH+ 0.10046E-07 -7.9980 0.96318E-08 -8.0163 0.95881E+00 -0.0183 65 MnO2-2 0.74296E-16 -16.1290 0.66253E-16 -16.1788 0.89175E+00 -0.0498 66 HMnO2- 0.17898E-12 -12.7472 0.17160E-12 -12.7655 0.95877E+00 -0.0183 69 MnCl+ 0.31991E-10 -10.4950 0.30673E-10 -10.5132 0.95881E+00 -0.0183 70 MnSO4,aq 0.24635E-09 -9.6084 0.24635E-09 -9.6084 0.10000E+01 0.0000 71 NaCl,aq 0.10257E-07 -7.9890 0.10257E-07 -7.9890 0.10000E+01 0.0000 72 NaOH,aq 0.85035E-08 -8.0704 0.85035E-08 -8.0704 0.10000E+01 0.0000 74 OH- 0.50976E-04 -4.2926 0.48872E-04 -4.3109 0.95873E+00 -0.0183 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.81711E-09 -9.0877 0.78343E-09 -9.1060 0.95879E+00 -0.0183 84 PO4-3 0.31342E-12 -12.5039 0.24791E-12 -12.6057 0.79099E+00 -0.1018 87 H2P2O7-2 0.53967E-19 -19.2679 0.48125E-19 -19.3176 0.89175E+00 -0.0498 88 HP2O7-3 0.10288E-17 -17.9877 0.81283E-18 -18.0900 0.79006E+00 -0.1023 89 P2O7-4 0.24612E-19 -19.6089 0.16425E-19 -19.7845 0.66737E+00 -0.1756 90 H2S,aq 0.20157E-13 -13.6956 0.20155E-13 -13.6956 0.99991E+00 0.0000 97 SO3-2 0.15068E-14 -14.8220 0.13441E-14 -14.8716 0.89207E+00 -0.0496 98 HSO3- 0.10377E-14 -14.9839 0.99496E-15 -15.0022 0.95877E+00 -0.0183 99 HSO4- 0.26926E-09 -9.5698 0.25818E-09 -9.5881 0.95883E+00 -0.0183 Charge balance for all species = 0.2155E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1232888E-07 -.9402747E-04 -.9476912E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999463E+06 0.0000 3 Cl- 0.1379638E-03 0.1379769E-03 0.4891441E+01 4.0488 4 SO4-- 0.2541006E-04 0.2550490E-04 0.2449914E+01 11.2099 5 HCO3- 0.1264550E-04 0.1307026E-04 0.7974690E+00 3.0110 6 HS- 0.5753270E-12 0.7265411E-10 0.2402692E-05 -4.3311 7 Al+++ 0.1206931E-20 0.3069105E-05 0.8280476E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4044675E-03 0.3887353E+02 -3.4276 9 Ca++ 0.1393318E-04 0.1413014E-04 0.5662782E+00 10.9488 10 Mg++ 0.5575074E-07 0.5756381E-07 0.1399419E-02 8.5510 11 Fe++ 0.3292633E-09 0.1665848E-08 0.9302776E-04 6.3223 12 K+ 0.1421981E-04 0.1422533E-04 0.5562101E+00 3.0619 13 Na+ 0.2440467E-03 0.2441771E-03 0.5613291E+01 4.2965 14 Mn++ 0.4223586E-07 0.5283900E-07 0.2902718E-02 8.4304 15 HPO4-- 0.4028105E-08 0.4845527E-08 0.4650447E-03 7.4100 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1096381E-02 -.9402562E-04 -.1002355E-02 0.0000000E+00 2 H2O 0.5550741E+02 0.5550718E+02 0.2262066E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2736127E-04 0.2550440E-04 0.1856871E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1856798E-05 0.7265268E-10 -.1856871E-05 0.0000000E+00 7 Al+++ 0.2184697E-03 0.3069045E-05 0.2154006E-03 0.0000000E+00 8 H4SiO4 0.6976565E-03 0.4044595E-03 0.2931969E-03 0.0000000E+00 9 Ca++ 0.9153062E-04 0.1412986E-04 0.7740076E-04 0.0000000E+00 10 Mg++ 0.5317460E-04 0.5756268E-07 0.5311704E-04 0.0000000E+00 11 Fe++ 0.4777158E-04 0.1665815E-08 0.4776991E-04 0.0000000E+00 12 K+ 0.1422505E-04 0.1422505E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2441723E-03 0.2441723E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1161686E-05 0.5283796E-07 0.1108848E-05 0.0000000E+00 15 HPO4-- 0.3964776E-06 0.4845432E-08 0.3916322E-06 0.0000000E+00 Chg. balance for solid moles: 0.1538E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0670000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1305E-06 -6.884 0.6557E-04 -4.183 0.1479 0.2084E-04 clinochlore 0.1062E-04 -4.974 0.5905E-02 -2.229 13.32 0.2246E-02 daphnite 0.6583E-05 -5.182 0.4697E-02 -2.328 10.59 0.1423E-02 chlorite-Mn 0.2218E-06 -6.654 0.1572E-03 -3.803 0.3546 0.5010E-04 hematite 0.7427E-05 -5.129 0.1186E-02 -2.926 2.676 0.2248E-03 kaolinite 0.1352E-04 -4.869 0.3491E-02 -2.457 7.875 0.1343E-02 lawsonite 0.6467E-04 -4.189 0.2032E-01 -1.692 45.84 0.6554E-02 stilbite 0.1207E-04 -4.918 0.8509E-02 -2.070 19.19 0.3969E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3777E+00 0.3777E+00 1.0000 -0.423 chlorite-Mn 0.1272E-01 0.1272E-01 1.0000 -1.895 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.044334 g Volume = 0.015831 cm3 Porosity: 98.4582% V(tot) - V(min): 0.10110E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0670000 g log = -1.1739 Original solution: 1000.0103000 g Original solution / Rock added: 14925.53 (Water/Rock Ratio), log = 4.1739 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3189E-04 1.0071 0.3277E-04 0.3254E-04 CH4,gas 0.4085E-15 1.0125 0.4220E-15 0.4168E-15 H2,gas 0.5870E-06 1.0005 0.5993E-06 0.5989E-06 H2S,gas 0.5452E-12 0.9960 0.5540E-12 0.5562E-12 S2,gas 0.3144E-31 1.0000 0.3208E-31 0.3208E-31 CO,gas 0.5129E-14 1.0000 0.5234E-14 0.5234E-14 SO3,gas 0.1174E-35 1.0000 0.1198E-35 0.1198E-35 SO2,gas 0.2736E-19 1.0000 0.2792E-19 0.2792E-19 HCl,gas 0.4956E-15 1.0000 0.5056E-15 0.5056E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.84 -6.18 -2.061 0.10558E+05 -4.485 3 CH4,gas 4.54 -12.53 -17.07 -4.268 0.29153E+05 -15.375 4 H2,gas 8.00 0.08 -7.92 -4.526 0.13525E+05 -6.222 5 H2S,gas -6.23 -20.19 -13.96 -6.978 0.23829E+05 -12.256 6 S2,gas -7.34 -40.53 -33.19 -5.107 0.56676E+05 -31.494 7 CO,gas 3.21 -12.77 -15.98 -4.917 0.27286E+05 -14.281 8 SO3,gas 17.12 -20.50 -37.62 -9.405 0.64236E+05 -35.922 9 SO2,gas 0.83 -20.42 -21.25 -5.667 0.36289E+05 -19.554 10 HCl,gas 5.19 -11.81 -17.00 -8.498 0.29019E+05 -15.296 11 acmite 7.71 3.72 -3.99 -0.414 0.68049E+04 15 albite-high 0.69 -3.23 -3.92 -0.301 0.66902E+04 16 albite -0.38 -3.23 -2.84 -0.219 0.48514E+04 19 spessartine 24.46 20.53 -3.93 -0.196 0.67042E+04 20 analcite 3.32 0.20 -3.12 -0.347 0.53263E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.55 -4.23 -2.117 0.72289E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.89 -2.86 -0.954 0.48856E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.89 -2.71 -0.902 0.46214E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29422E+04 42 celadonite 5.34 0.66 -4.68 -0.275 0.79875E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43572E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12916E+04 52 chloritoid-Mn 11.40 10.53 -0.88 -0.058 0.14954E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60389E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64754E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82450E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68775E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.20 -4.01 -0.401 0.68518E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 105 lizardite 23.24 18.80 -4.45 -0.371 0.75916E+04 106 magnesite 0.69 -4.29 -4.98 -1.661 0.85087E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20471E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.46 -1.97 -0.152 0.33692E+04 120 muscovite 2.58 1.06 -1.52 -0.089 0.25948E+04 121 paragonite 4.24 2.30 -1.94 -0.114 0.33161E+04 122 nepheline 8.34 3.63 -4.71 -0.673 0.80411E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49710E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.00 -2.40 -0.479 0.40909E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.41 -3.44 -1.146 0.58684E+04 152 rhodonite 7.45 5.00 -2.44 -0.489 0.41711E+04 153 sanidine -1.28 -4.46 -3.18 -0.245 0.54370E+04 155 siderite -2.61 -6.52 -3.91 -1.304 0.66817E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.24 -1.77 -0.053 0.30274E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83487E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54866E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77666E+04 174 tephroite 18.09 13.43 -4.65 -0.665 0.79441E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.14 -3.62 -0.221 0.61726E+04 196 beidellite-Mg -1.79 -4.73 -2.94 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.73 -3.39 -0.207 0.57809E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.27 -3.03 -0.186 0.51741E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.86 -2.82 -0.173 0.48181E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.91 -1.43 -0.092 0.24455E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.32 -1.20 -0.077 0.20555E+04 214 gypsum -4.96 -9.55 -4.60 -1.149 0.78465E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59579E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.66 -2.67 -0.206 0.45669E+04 243 an25ab75 2.65 -0.01 -2.66 -0.205 0.45428E+04 244 an30ab70 3.28 0.63 -2.65 -0.204 0.45283E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0670000 g New total amount of reactant added: 0.0690000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0690000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2986497E-03 Osmotic coef. = 0.9897 True ionic strength = .3272282E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12077E-07 -7.9181 0.11580E-07 -7.9363 0.95886E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13227E-03 -3.8785 0.95872E+00 -0.0183 4 SO4-- 0.25414E-04 -4.5949 0.22660E-04 -4.6447 0.89164E+00 -0.0498 5 HCO3- 0.12650E-04 -4.8979 0.12128E-04 -4.9162 0.95876E+00 -0.0183 6 HS- 0.56317E-12 -12.2494 0.53993E-12 -12.2677 0.95873E+00 -0.0183 7 Al+++ 0.11347E-20 -20.9451 0.89610E-21 -21.0476 0.78974E+00 -0.1025 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.13370E-04 -4.8739 0.11919E-04 -4.9237 0.89148E+00 -0.0499 10 Mg++ 0.53498E-07 -7.2717 0.47687E-07 -7.3216 0.89139E+00 -0.0499 11 Fe++ 0.31593E-09 -9.5004 0.28163E-09 -9.5503 0.89141E+00 -0.0499 12 K+ 0.14644E-04 -4.8343 0.14040E-04 -4.8526 0.95876E+00 -0.0183 13 Na+ 0.24655E-03 -3.6081 0.23638E-03 -3.6264 0.95872E+00 -0.0183 14 Mn++ 0.40645E-07 -7.3910 0.36232E-07 -7.4409 0.89143E+00 -0.0499 15 HPO4-- 0.41992E-08 -8.3768 0.37442E-08 -8.4266 0.89164E+00 -0.0498 16 HSiO3- 0.31420E-04 -4.5028 0.30123E-04 -4.5211 0.95872E+00 -0.0183 17 Ca(HSiO3)+ 0.85284E-08 -8.0691 0.81768E-08 -8.0874 0.95877E+00 -0.0183 18 Mg(HSiO3)+ 0.42464E-10 -10.3720 0.40713E-10 -10.3903 0.95877E+00 -0.0183 19 NaHSiO3,aq 0.11516E-06 -6.9387 0.11516E-06 -6.9387 0.10000E+01 0.0000 20 AlO+ 0.94822E-12 -12.0231 0.90912E-12 -12.0414 0.95877E+00 -0.0183 21 AlOH+2 0.58804E-16 -16.2306 0.52421E-16 -16.2805 0.89145E+00 -0.0499 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.31175E-05 -5.5062 0.29887E-05 -5.5245 0.95868E+00 -0.0183 24 CH4,aq 0.28075E-18 -18.5517 0.28072E-18 -18.5517 0.99991E+00 0.0000 29 CO,aq 0.34405E-17 -17.4634 0.34405E-17 -17.4634 0.10000E+01 0.0000 30 CO2,aq 0.30012E-06 -6.5227 0.30010E-06 -6.5227 0.99991E+00 0.0000 31 CO3-2 0.10261E-06 -6.9888 0.91482E-07 -7.0387 0.89159E+00 -0.0498 32 CaCO3,aq 0.13672E-07 -7.8642 0.13672E-07 -7.8642 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.38487E-08 -8.4147 0.36901E-08 -8.4330 0.95877E+00 -0.0183 34 CaCl+ 0.26611E-08 -8.5749 0.25514E-08 -8.5932 0.95877E+00 -0.0183 35 CaCl2,aq 0.80175E-13 -13.0960 0.80175E-13 -13.0960 0.10000E+01 0.0000 36 CaOH+ 0.76513E-07 -7.1163 0.73358E-07 -7.1346 0.95877E+00 -0.0183 37 CaSO4,aq 0.85766E-07 -7.0667 0.85766E-07 -7.0667 0.10000E+01 0.0000 38 HCl,aq 0.28067E-12 -12.5518 0.28067E-12 -12.5518 0.10000E+01 0.0000 43 FeCl+ 0.61497E-13 -13.2111 0.58961E-13 -13.2294 0.95877E+00 -0.0183 46 FeO,aq 0.81626E-10 -10.0882 0.81626E-10 -10.0882 0.10000E+01 0.0000 47 FeOH+ 0.82569E-09 -9.0832 0.79165E-09 -9.1015 0.95877E+00 -0.0183 48 HFeO2- 0.76929E-10 -10.1139 0.73754E-10 -10.1322 0.95872E+00 -0.0183 49 FeO+ 0.92189E-13 -13.0353 0.88388E-13 -13.0536 0.95877E+00 -0.0183 50 FeOH+2 0.21927E-18 -18.6590 0.19546E-18 -18.7089 0.89145E+00 -0.0499 51 FeO2- 0.14068E-09 -9.8518 0.13488E-09 -9.8701 0.95872E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45642E-09 -9.3406 0.45638E-09 -9.3407 0.99991E+00 0.0000 54 KCl,aq 0.33659E-10 -10.4729 0.33659E-10 -10.4729 0.10000E+01 0.0000 55 KHSO4,aq 0.10417E-16 -16.9823 0.10417E-16 -16.9823 0.10000E+01 0.0000 56 KOH,aq 0.51780E-09 -9.2858 0.51780E-09 -9.2858 0.10000E+01 0.0000 57 KSO4- 0.51495E-08 -8.2882 0.49369E-08 -8.3065 0.95872E+00 -0.0183 58 MgCO3,aq 0.13711E-10 -10.8629 0.13711E-10 -10.8629 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15734E-10 -10.8032 0.15085E-10 -10.8214 0.95877E+00 -0.0183 60 MgCl+ 0.96494E-11 -11.0155 0.92515E-11 -11.0338 0.95877E+00 -0.0183 61 MgOH+ 0.16939E-08 -8.7711 0.16240E-08 -8.7894 0.95877E+00 -0.0183 63 MnO,aq 0.27982E-09 -9.5531 0.27982E-09 -9.5531 0.10000E+01 0.0000 64 MnOH+ 0.98682E-08 -8.0058 0.94613E-08 -8.0240 0.95877E+00 -0.0183 65 MnO2-2 0.77673E-16 -16.1097 0.69253E-16 -16.1596 0.89159E+00 -0.0498 66 HMnO2- 0.18326E-12 -12.7369 0.17569E-12 -12.7552 0.95872E+00 -0.0183 69 MnCl+ 0.30780E-10 -10.5117 0.29511E-10 -10.5300 0.95877E+00 -0.0183 70 MnSO4,aq 0.23702E-09 -9.6252 0.23702E-09 -9.6252 0.10000E+01 0.0000 71 NaCl,aq 0.10361E-07 -7.9846 0.10361E-07 -7.9846 0.10000E+01 0.0000 72 NaOH,aq 0.87702E-08 -8.0570 0.87702E-08 -8.0570 0.10000E+01 0.0000 74 OH- 0.52045E-04 -4.2836 0.49895E-04 -4.3019 0.95868E+00 -0.0183 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.83424E-09 -9.0787 0.79983E-09 -9.0970 0.95875E+00 -0.0183 84 PO4-3 0.33364E-12 -12.4767 0.26381E-12 -12.5787 0.79068E+00 -0.1020 87 H2P2O7-2 0.56260E-19 -19.2498 0.50161E-19 -19.2996 0.89159E+00 -0.0498 88 HP2O7-3 0.10952E-17 -17.9605 0.86494E-18 -18.0630 0.78975E+00 -0.1025 89 P2O7-4 0.26756E-19 -19.5726 0.17844E-19 -19.7485 0.66690E+00 -0.1759 90 H2S,aq 0.19325E-13 -13.7139 0.19324E-13 -13.7139 0.99991E+00 0.0000 97 SO3-2 0.15067E-14 -14.8220 0.13439E-14 -14.8716 0.89191E+00 -0.0497 98 HSO3- 0.10163E-14 -14.9930 0.97437E-15 -15.0113 0.95872E+00 -0.0183 99 HSO4- 0.26375E-09 -9.5788 0.25288E-09 -9.5971 0.95879E+00 -0.0183 Charge balance for all species = 0.2160E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1207669E-07 -.9600833E-04 -.9676559E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999461E+06 0.0000 3 Cl- 0.1379639E-03 0.1379769E-03 0.4891442E+01 4.0578 4 SO4-- 0.2541357E-04 0.2550491E-04 0.2449915E+01 11.2278 5 HCO3- 0.1264998E-04 0.1307026E-04 0.7974692E+00 3.0201 6 HS- 0.5631745E-12 0.7226181E-10 0.2389718E-05 -4.3314 7 Al+++ 0.1134675E-20 0.3133148E-05 0.8453262E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4051162E-03 0.3893588E+02 -3.4276 9 Ca++ 0.1337020E-04 0.1356119E-04 0.5434769E+00 10.9488 10 Mg++ 0.5349756E-07 0.5527300E-07 0.1343727E-02 8.5510 11 Fe++ 0.3159337E-09 0.1639661E-08 0.9156539E-04 6.3223 12 K+ 0.1464427E-04 0.1464998E-04 0.5728135E+00 3.0837 13 Na+ 0.2465535E-03 0.2466878E-03 0.5671007E+01 4.3099 14 Mn++ 0.4064498E-07 0.5106099E-07 0.2805042E-02 8.4317 15 HPO4-- 0.4199214E-08 0.5033793E-08 0.4831133E-03 7.4459 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1129498E-02 -.9600640E-04 -.1033491E-02 0.0000000E+00 2 H2O 0.5550739E+02 0.5550716E+02 0.2221433E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2741670E-04 0.2550440E-04 0.1912297E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1912225E-05 0.7226036E-10 -.1912297E-05 0.0000000E+00 7 Al+++ 0.2249912E-03 0.3133085E-05 0.2218581E-03 0.0000000E+00 8 H4SiO4 0.7184820E-03 0.4051081E-03 0.3133739E-03 0.0000000E+00 9 Ca++ 0.9383090E-04 0.1356092E-04 0.8026999E-04 0.0000000E+00 10 Mg++ 0.5476190E-04 0.5527190E-07 0.5470663E-04 0.0000000E+00 11 Fe++ 0.4919759E-04 0.1639628E-08 0.4919595E-04 0.0000000E+00 12 K+ 0.1464968E-04 0.1464968E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2466828E-03 0.2466828E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1196363E-05 0.5105996E-07 0.1145303E-05 0.0000000E+00 15 HPO4-- 0.4083128E-06 0.5033692E-08 0.4032791E-06 0.0000000E+00 Chg. balance for solid moles: 0.6130E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0690000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1344E-06 -6.872 0.6753E-04 -4.171 0.1450 0.2146E-04 clinochlore 0.1094E-04 -4.961 0.6082E-02 -2.216 13.06 0.2313E-02 daphnite 0.6780E-05 -5.169 0.4837E-02 -2.315 10.38 0.1466E-02 chlorite-Mn 0.2291E-06 -6.640 0.1624E-03 -3.789 0.3486 0.5175E-04 hematite 0.7649E-05 -5.116 0.1222E-02 -2.913 2.622 0.2315E-03 kaolinite 0.1338E-04 -4.874 0.3455E-02 -2.462 7.416 0.1329E-02 lawsonite 0.6488E-04 -4.188 0.2039E-01 -1.691 43.77 0.6575E-02 stilbite 0.1471E-04 -4.832 0.1037E-01 -1.984 22.26 0.4836E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3777E+00 0.3777E+00 1.0000 -0.423 chlorite-Mn 0.1276E-01 0.1276E-01 1.0000 -1.894 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.046583 g Volume = 0.016824 cm3 Porosity: 98.3628% V(tot) - V(min): 0.10108E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0690000 g log = -1.1612 Original solution: 1000.0103000 g Original solution / Rock added: 14492.90 (Water/Rock Ratio), log = 4.1612 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3125E-04 1.0071 0.3211E-04 0.3188E-04 CH4,gas 0.4000E-15 1.0125 0.4132E-15 0.4081E-15 H2,gas 0.5869E-06 1.0005 0.5992E-06 0.5988E-06 H2S,gas 0.5227E-12 0.9960 0.5312E-12 0.5333E-12 S2,gas 0.2891E-31 1.0000 0.2950E-31 0.2950E-31 CO,gas 0.5025E-14 1.0000 0.5127E-14 0.5127E-14 SO3,gas 0.1126E-35 1.0000 0.1149E-35 0.1149E-35 SO2,gas 0.2625E-19 1.0000 0.2678E-19 0.2678E-19 HCl,gas 0.4854E-15 1.0000 0.4953E-15 0.4953E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.17819E-10 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.85 -6.19 -2.064 0.10573E+05 -4.493 3 CH4,gas 4.54 -12.54 -17.08 -4.271 0.29168E+05 -15.384 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13526E+05 -6.222 5 H2S,gas -6.23 -20.20 -13.97 -6.987 0.23860E+05 -12.275 6 S2,gas -7.34 -40.56 -33.23 -5.112 0.56738E+05 -31.530 7 CO,gas 3.21 -12.77 -15.99 -4.920 0.27301E+05 -14.290 8 SO3,gas 17.12 -20.52 -37.64 -9.410 0.64267E+05 -35.940 9 SO2,gas 0.83 -20.44 -21.27 -5.672 0.36320E+05 -19.572 10 HCl,gas 5.19 -11.81 -17.00 -8.502 0.29034E+05 -15.305 11 acmite 7.71 3.74 -3.97 -0.413 0.67820E+04 15 albite-high 0.69 -3.21 -3.90 -0.300 0.66673E+04 16 albite -0.38 -3.21 -2.83 -0.218 0.48285E+04 19 spessartine 24.46 20.53 -3.92 -0.196 0.66979E+04 20 analcite 3.32 0.22 -3.11 -0.345 0.53034E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.57 -4.25 -2.126 0.72596E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.90 -2.87 -0.957 0.49007E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.90 -2.72 -0.905 0.46365E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29422E+04 42 celadonite 5.34 0.69 -4.66 -0.274 0.79503E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43572E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12917E+04 52 chloritoid-Mn 11.40 10.53 -0.87 -0.058 0.14932E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60389E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64755E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82451E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68776E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.22 -4.00 -0.400 0.68288E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 105 lizardite 23.24 18.80 -4.45 -0.371 0.75916E+04 106 magnesite 0.69 -4.30 -4.99 -1.664 0.85239E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20472E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.44 -1.95 -0.150 0.33321E+04 120 muscovite 2.58 1.08 -1.50 -0.088 0.25576E+04 121 paragonite 4.24 2.31 -1.93 -0.113 0.32932E+04 122 nepheline 8.34 3.64 -4.70 -0.671 0.80182E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49710E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.00 -2.39 -0.479 0.40888E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.42 -3.44 -1.148 0.58814E+04 152 rhodonite 7.45 5.00 -2.44 -0.488 0.41690E+04 153 sanidine -1.28 -4.44 -3.16 -0.243 0.53998E+04 155 siderite -2.61 -6.53 -3.92 -1.307 0.66969E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.25 -1.76 -0.053 0.30091E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83488E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54866E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77666E+04 174 tephroite 18.09 13.44 -4.65 -0.664 0.79398E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.13 -3.61 -0.221 0.61603E+04 196 beidellite-Mg -1.79 -4.73 -2.94 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.72 -3.38 -0.207 0.57733E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.26 -3.02 -0.185 0.51618E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.86 -2.82 -0.173 0.48105E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.92 -1.43 -0.091 0.24333E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.32 -1.20 -0.077 0.20480E+04 214 gypsum -4.96 -9.57 -4.61 -1.153 0.78772E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59579E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.65 -2.66 -0.205 0.45486E+04 243 an25ab75 2.65 0.00 -2.65 -0.204 0.45256E+04 244 an30ab70 3.28 0.64 -2.64 -0.203 0.45122E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0690000 g New total amount of reactant added: 0.0710000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0710000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2993100E-03 Osmotic coef. = 0.9896 True ionic strength = .3285262E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11829E-07 -7.9271 0.11342E-07 -7.9453 0.95882E+00 -0.0183 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13226E-03 -3.8786 0.95868E+00 -0.0183 4 SO4-- 0.25417E-04 -4.5949 0.22658E-04 -4.6448 0.89147E+00 -0.0499 5 HCO3- 0.12654E-04 -4.8978 0.12132E-04 -4.9161 0.95871E+00 -0.0183 6 HS- 0.55126E-12 -12.2586 0.52849E-12 -12.2770 0.95868E+00 -0.0183 7 Al+++ 0.10666E-20 -20.9720 0.84195E-21 -21.0747 0.78940E+00 -0.1027 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.12828E-04 -4.8918 0.11434E-04 -4.9418 0.89132E+00 -0.0500 10 Mg++ 0.51329E-07 -7.2896 0.45746E-07 -7.3396 0.89122E+00 -0.0500 11 Fe++ 0.30311E-09 -9.5184 0.27014E-09 -9.5684 0.89124E+00 -0.0500 12 K+ 0.15069E-04 -4.8219 0.14447E-04 -4.8402 0.95872E+00 -0.0183 13 Na+ 0.24906E-03 -3.6037 0.23877E-03 -3.6220 0.95868E+00 -0.0183 14 Mn++ 0.39101E-07 -7.4078 0.34849E-07 -7.4578 0.89126E+00 -0.0500 15 HPO4-- 0.43782E-08 -8.3587 0.39030E-08 -8.4086 0.89148E+00 -0.0499 16 HSiO3- 0.32081E-04 -4.4938 0.30755E-04 -4.5121 0.95868E+00 -0.0183 17 Ca(HSiO3)+ 0.83535E-08 -8.0781 0.80087E-08 -8.0964 0.95872E+00 -0.0183 18 Mg(HSiO3)+ 0.41592E-10 -10.3810 0.39875E-10 -10.3993 0.95872E+00 -0.0183 19 NaHSiO3,aq 0.11877E-06 -6.9253 0.11877E-06 -6.9253 0.10000E+01 0.0000 20 AlO+ 0.92876E-12 -12.0321 0.89043E-12 -12.0504 0.95872E+00 -0.0183 21 AlOH+2 0.56421E-16 -16.2486 0.50287E-16 -16.2985 0.89128E+00 -0.0500 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.31831E-05 -5.4971 0.30514E-05 -5.5155 0.95864E+00 -0.0183 24 CH4,aq 0.27489E-18 -18.5608 0.27486E-18 -18.5609 0.99991E+00 0.0000 29 CO,aq 0.33703E-17 -17.4723 0.33703E-17 -17.4723 0.10000E+01 0.0000 30 CO2,aq 0.29404E-06 -6.5316 0.29401E-06 -6.5316 0.99991E+00 0.0000 31 CO3-2 0.10481E-06 -6.9796 0.93430E-07 -7.0295 0.89143E+00 -0.0499 32 CaCO3,aq 0.13395E-07 -7.8730 0.13395E-07 -7.8730 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.36934E-08 -8.4326 0.35409E-08 -8.4509 0.95872E+00 -0.0183 34 CaCl+ 0.25528E-08 -8.5930 0.24474E-08 -8.6113 0.95872E+00 -0.0183 35 CaCl2,aq 0.76905E-13 -13.1140 0.76905E-13 -13.1140 0.10000E+01 0.0000 36 CaOH+ 0.74943E-07 -7.1253 0.71850E-07 -7.1436 0.95872E+00 -0.0183 37 CaSO4,aq 0.82271E-07 -7.0848 0.82271E-07 -7.0848 0.10000E+01 0.0000 38 HCl,aq 0.27489E-12 -12.5608 0.27489E-12 -12.5608 0.10000E+01 0.0000 43 FeCl+ 0.58990E-13 -13.2292 0.56555E-13 -13.2475 0.95872E+00 -0.0183 46 FeO,aq 0.81620E-10 -10.0882 0.81620E-10 -10.0882 0.10000E+01 0.0000 47 FeOH+ 0.80869E-09 -9.0922 0.77532E-09 -9.1105 0.95872E+00 -0.0183 48 HFeO2- 0.78542E-10 -10.1049 0.75296E-10 -10.1232 0.95868E+00 -0.0183 49 FeO+ 0.90298E-13 -13.0443 0.86571E-13 -13.0626 0.95872E+00 -0.0183 50 FeOH+2 0.21038E-18 -18.6770 0.18751E-18 -18.7270 0.89128E+00 -0.0500 51 FeO2- 0.14364E-09 -9.8427 0.13771E-09 -9.8610 0.95868E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45636E-09 -9.3407 0.45631E-09 -9.3407 0.99991E+00 0.0000 54 KCl,aq 0.34631E-10 -10.4605 0.34631E-10 -10.4605 0.10000E+01 0.0000 55 KHSO4,aq 0.10497E-16 -16.9789 0.10497E-16 -16.9789 0.10000E+01 0.0000 56 KOH,aq 0.54397E-09 -9.2644 0.54397E-09 -9.2644 0.10000E+01 0.0000 57 KSO4- 0.52985E-08 -8.2758 0.50795E-08 -8.2942 0.95868E+00 -0.0183 58 MgCO3,aq 0.13433E-10 -10.8718 0.13433E-10 -10.8718 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15099E-10 -10.8211 0.14475E-10 -10.8394 0.95872E+00 -0.0183 60 MgCl+ 0.92566E-11 -11.0335 0.88745E-11 -11.0519 0.95872E+00 -0.0183 61 MgOH+ 0.16591E-08 -8.7801 0.15906E-08 -8.7984 0.95872E+00 -0.0183 63 MnO,aq 0.28056E-09 -9.5520 0.28056E-09 -9.5520 0.10000E+01 0.0000 64 MnOH+ 0.96914E-08 -8.0136 0.92913E-08 -8.0319 0.95872E+00 -0.0183 65 MnO2-2 0.81198E-16 -16.0905 0.72382E-16 -16.1404 0.89143E+00 -0.0499 66 HMnO2- 0.18761E-12 -12.7268 0.17985E-12 -12.7451 0.95868E+00 -0.0183 69 MnCl+ 0.29606E-10 -10.5286 0.28384E-10 -10.5469 0.95872E+00 -0.0183 70 MnSO4,aq 0.22796E-09 -9.6421 0.22796E-09 -9.6421 0.10000E+01 0.0000 71 NaCl,aq 0.10466E-07 -7.9802 0.10466E-07 -7.9802 0.10000E+01 0.0000 72 NaOH,aq 0.90450E-08 -8.0436 0.90450E-08 -8.0436 0.10000E+01 0.0000 74 OH- 0.53140E-04 -4.2746 0.50942E-04 -4.2929 0.95864E+00 -0.0183 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.85179E-09 -9.0697 0.81662E-09 -9.0880 0.95870E+00 -0.0183 84 PO4-3 0.35525E-12 -12.4495 0.28077E-12 -12.5516 0.79035E+00 -0.1022 87 H2P2O7-2 0.58657E-19 -19.2317 0.52289E-19 -19.2816 0.89143E+00 -0.0499 88 HP2O7-3 0.11661E-17 -17.9333 0.92056E-18 -18.0359 0.78941E+00 -0.1027 89 P2O7-4 0.29097E-19 -19.5362 0.19390E-19 -19.7124 0.66640E+00 -0.1763 90 H2S,aq 0.18527E-13 -13.7322 0.18525E-13 -13.7322 0.99991E+00 0.0000 97 SO3-2 0.15067E-14 -14.8220 0.13436E-14 -14.8717 0.89174E+00 -0.0498 98 HSO3- 0.99527E-15 -15.0021 0.95414E-15 -15.0204 0.95868E+00 -0.0183 99 HSO4- 0.25832E-09 -9.5878 0.24766E-09 -9.6061 0.95875E+00 -0.0183 Charge balance for all species = 0.2165E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1182894E-07 -.9803697E-04 -.9881022E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999460E+06 0.0000 3 Cl- 0.1379639E-03 0.1379770E-03 0.4891443E+01 4.0668 4 SO4-- 0.2541694E-04 0.2550492E-04 0.2449915E+01 11.2459 5 HCO3- 0.1265430E-04 0.1307027E-04 0.7974695E+00 3.0292 6 HS- 0.5512638E-12 0.7186241E-10 0.2376509E-05 -4.3316 7 Al+++ 0.1066566E-20 0.3198740E-05 0.8630228E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4057807E-03 0.3899974E+02 -3.4276 9 Ca++ 0.1282847E-04 0.1301368E-04 0.5215348E+00 10.9488 10 Mg++ 0.5132950E-07 0.5306800E-07 0.1290122E-02 8.5510 11 Fe++ 0.3031104E-09 0.1614401E-08 0.9015477E-04 6.3222 12 K+ 0.1506874E-04 0.1507462E-04 0.5894169E+00 3.1051 13 Na+ 0.2490601E-03 0.2491984E-03 0.5728722E+01 4.3233 14 Mn++ 0.3910135E-07 0.4933102E-07 0.2710006E-02 8.4328 15 HPO4-- 0.4378178E-08 0.5230331E-08 0.5019757E-03 7.4820 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1162615E-02 -.9803496E-04 -.1064580E-02 0.0000000E+00 2 H2O 0.5550736E+02 0.5550714E+02 0.2180718E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2747212E-04 0.2550440E-04 0.1967724E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1967652E-05 0.7186094E-10 -.1967724E-05 0.0000000E+00 7 Al+++ 0.2315127E-03 0.3198674E-05 0.2283140E-03 0.0000000E+00 8 H4SiO4 0.7393076E-03 0.4057724E-03 0.3335352E-03 0.0000000E+00 9 Ca++ 0.9613119E-04 0.1301341E-04 0.8311778E-04 0.0000000E+00 10 Mg++ 0.5634921E-04 0.5306691E-07 0.5629614E-04 0.0000000E+00 11 Fe++ 0.5062361E-04 0.1614368E-08 0.5062200E-04 0.0000000E+00 12 K+ 0.1507431E-04 0.1507431E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2491933E-03 0.2491933E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1231040E-05 0.4933001E-07 0.1181710E-05 0.0000000E+00 15 HPO4-- 0.4201479E-06 0.5230224E-08 0.4149177E-06 0.0000000E+00 Chg. balance for solid moles: -.2520E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0710000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1383E-06 -6.859 0.6947E-04 -4.158 0.1423 0.2208E-04 clinochlore 0.1126E-04 -4.948 0.6258E-02 -2.204 12.82 0.2380E-02 daphnite 0.6976E-05 -5.156 0.4977E-02 -2.303 10.19 0.1508E-02 chlorite-Mn 0.2363E-06 -6.626 0.1676E-03 -3.776 0.3432 0.5340E-04 hematite 0.7871E-05 -5.104 0.1257E-02 -2.901 2.574 0.2382E-03 kaolinite 0.1326E-04 -4.877 0.3423E-02 -2.466 7.010 0.1317E-02 lawsonite 0.6508E-04 -4.187 0.2045E-01 -1.689 41.88 0.6595E-02 stilbite 0.1735E-04 -4.761 0.1223E-01 -1.913 25.04 0.5703E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3777E+00 0.3777E+00 1.0000 -0.423 chlorite-Mn 0.1279E-01 0.1279E-01 1.0000 -1.893 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.048829 g Volume = 0.017817 cm3 Porosity: 98.2675% V(tot) - V(min): 0.10106E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0710000 g log = -1.1487 Original solution: 1000.0103000 g Original solution / Rock added: 14084.65 (Water/Rock Ratio), log = 4.1487 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.3061E-04 1.0071 0.3146E-04 0.3123E-04 CH4,gas 0.3916E-15 1.0125 0.4046E-15 0.3996E-15 H2,gas 0.5868E-06 1.0005 0.5991E-06 0.5988E-06 H2S,gas 0.5011E-12 0.9960 0.5092E-12 0.5113E-12 S2,gas 0.2658E-31 1.0000 0.2712E-31 0.2712E-31 CO,gas 0.4922E-14 1.0000 0.5022E-14 0.5022E-14 SO3,gas 0.1080E-35 1.0000 0.1102E-35 0.1102E-35 SO2,gas 0.2517E-19 1.0000 0.2569E-19 0.2569E-19 HCl,gas 0.4754E-15 1.0000 0.4850E-15 0.4850E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.86 -6.20 -2.067 0.10588E+05 -4.502 3 CH4,gas 4.54 -12.55 -17.09 -4.273 0.29184E+05 -15.393 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13526E+05 -6.223 5 H2S,gas -6.23 -20.22 -13.99 -6.996 0.23891E+05 -12.293 6 S2,gas -7.34 -40.60 -33.27 -5.118 0.56800E+05 -31.567 7 CO,gas 3.21 -12.78 -16.00 -4.922 0.27316E+05 -14.299 8 SO3,gas 17.12 -20.54 -37.66 -9.414 0.64298E+05 -35.958 9 SO2,gas 0.83 -20.46 -21.29 -5.677 0.36351E+05 -19.590 10 HCl,gas 5.19 -11.82 -17.01 -8.507 0.29050E+05 -15.314 11 acmite 7.71 3.75 -3.96 -0.411 0.67592E+04 15 albite-high 0.69 -3.20 -3.89 -0.299 0.66444E+04 16 albite -0.38 -3.20 -2.81 -0.216 0.48056E+04 19 spessartine 24.46 20.54 -3.92 -0.196 0.66920E+04 20 analcite 3.32 0.23 -3.09 -0.344 0.52805E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.59 -4.27 -2.135 0.72905E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.91 -2.88 -0.960 0.49159E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.91 -2.72 -0.908 0.46517E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29423E+04 42 celadonite 5.34 0.71 -4.63 -0.273 0.79138E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43572E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12918E+04 52 chloritoid-Mn 11.40 10.53 -0.87 -0.058 0.14913E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64755E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82452E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68778E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.23 -3.99 -0.399 0.68060E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 105 lizardite 23.24 18.80 -4.45 -0.371 0.75917E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20472E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.42 -1.93 -0.148 0.32955E+04 120 muscovite 2.58 1.11 -1.48 -0.087 0.25211E+04 121 paragonite 4.24 2.32 -1.92 -0.113 0.32703E+04 122 nepheline 8.34 3.66 -4.68 -0.669 0.79953E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49711E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.01 -2.39 -0.479 0.40868E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.43 -3.45 -1.151 0.58946E+04 152 rhodonite 7.45 5.01 -2.44 -0.488 0.41670E+04 153 sanidine -1.28 -4.42 -3.14 -0.242 0.53633E+04 155 siderite -2.61 -6.54 -3.93 -1.310 0.67121E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.27 -1.75 -0.052 0.29911E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83489E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54866E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77666E+04 174 tephroite 18.09 13.44 -4.65 -0.664 0.79359E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.12 -3.60 -0.221 0.61482E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.72 -3.38 -0.207 0.57657E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.25 -3.02 -0.185 0.51497E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.85 -2.81 -0.172 0.48030E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.92 -1.42 -0.091 0.24212E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.32 -1.20 -0.077 0.20404E+04 214 gypsum -4.96 -9.59 -4.63 -1.158 0.79081E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59580E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.64 -2.65 -0.204 0.45303E+04 243 an25ab75 2.65 0.01 -2.64 -0.203 0.45085E+04 244 an30ab70 3.28 0.65 -2.63 -0.203 0.44962E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0710000 g New total amount of reactant added: 0.0730000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0730000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3000198E-03 Osmotic coef. = 0.9896 True ionic strength = .3298874E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11586E-07 -7.9361 0.11108E-07 -7.9544 0.95877E+00 -0.0183 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13226E-03 -3.8786 0.95863E+00 -0.0183 4 SO4-- 0.25420E-04 -4.5948 0.22657E-04 -4.6448 0.89130E+00 -0.0500 5 HCO3- 0.12658E-04 -4.8976 0.12135E-04 -4.9160 0.95867E+00 -0.0183 6 HS- 0.53960E-12 -12.2679 0.51728E-12 -12.2863 0.95864E+00 -0.0183 7 Al+++ 0.10024E-20 -20.9989 0.79098E-21 -21.1018 0.78906E+00 -0.1029 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.12308E-04 -4.9098 0.10968E-04 -4.9599 0.89114E+00 -0.0501 10 Mg++ 0.49245E-07 -7.3076 0.43880E-07 -7.3577 0.89104E+00 -0.0501 11 Fe++ 0.29079E-09 -9.5364 0.25911E-09 -9.5865 0.89107E+00 -0.0501 12 K+ 0.15493E-04 -4.8099 0.14853E-04 -4.8282 0.95867E+00 -0.0183 13 Na+ 0.25157E-03 -3.5993 0.24116E-03 -3.6177 0.95863E+00 -0.0183 14 Mn++ 0.37606E-07 -7.4247 0.33510E-07 -7.4748 0.89108E+00 -0.0501 15 HPO4-- 0.45652E-08 -8.3405 0.40690E-08 -8.3905 0.89130E+00 -0.0500 16 HSiO3- 0.32757E-04 -4.4847 0.31402E-04 -4.5030 0.95863E+00 -0.0183 17 Ca(HSiO3)+ 0.81818E-08 -8.0872 0.78437E-08 -8.1055 0.95868E+00 -0.0183 18 Mg(HSiO3)+ 0.40737E-10 -10.3900 0.39053E-10 -10.4083 0.95868E+00 -0.0183 19 NaHSiO3,aq 0.12248E-06 -6.9119 0.12248E-06 -6.9119 0.10000E+01 0.0000 20 AlO+ 0.90967E-12 -12.0411 0.87208E-12 -12.0594 0.95868E+00 -0.0183 21 AlOH+2 0.54131E-16 -16.2666 0.48236E-16 -16.3166 0.89111E+00 -0.0501 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.32502E-05 -5.4881 0.31156E-05 -5.5065 0.95859E+00 -0.0184 24 CH4,aq 0.26915E-18 -18.5700 0.26913E-18 -18.5700 0.99991E+00 0.0000 29 CO,aq 0.33013E-17 -17.4813 0.33013E-17 -17.4813 0.10000E+01 0.0000 30 CO2,aq 0.28806E-06 -6.5405 0.28804E-06 -6.5406 0.99991E+00 0.0000 31 CO3-2 0.10707E-06 -6.9704 0.95422E-07 -7.0204 0.89125E+00 -0.0500 32 CaCO3,aq 0.13123E-07 -7.8820 0.13123E-07 -7.8820 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.35439E-08 -8.4505 0.33975E-08 -8.4688 0.95868E+00 -0.0183 34 CaCl+ 0.24487E-08 -8.6111 0.23475E-08 -8.6294 0.95868E+00 -0.0183 35 CaCl2,aq 0.73762E-13 -13.1322 0.73762E-13 -13.1322 0.10000E+01 0.0000 36 CaOH+ 0.73403E-07 -7.1343 0.70370E-07 -7.1526 0.95868E+00 -0.0183 37 CaSO4,aq 0.78910E-07 -7.1029 0.78910E-07 -7.1029 0.10000E+01 0.0000 38 HCl,aq 0.26921E-12 -12.5699 0.26921E-12 -12.5699 0.10000E+01 0.0000 43 FeCl+ 0.56580E-13 -13.2473 0.54242E-13 -13.2657 0.95868E+00 -0.0183 46 FeO,aq 0.81614E-10 -10.0882 0.81614E-10 -10.0882 0.10000E+01 0.0000 47 FeOH+ 0.79202E-09 -9.1013 0.75929E-09 -9.1196 0.95868E+00 -0.0183 48 HFeO2- 0.80192E-10 -10.0959 0.76875E-10 -10.1142 0.95863E+00 -0.0183 49 FeO+ 0.88442E-13 -13.0533 0.84787E-13 -13.0717 0.95868E+00 -0.0183 50 FeOH+2 0.20184E-18 -18.6950 0.17986E-18 -18.7451 0.89111E+00 -0.0501 51 FeO2- 0.14667E-09 -9.8337 0.14060E-09 -9.8520 0.95863E+00 -0.0183 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45629E-09 -9.3408 0.45625E-09 -9.3408 0.99991E+00 0.0000 54 KCl,aq 0.35603E-10 -10.4485 0.35603E-10 -10.4485 0.10000E+01 0.0000 55 KHSO4,aq 0.10569E-16 -16.9760 0.10569E-16 -16.9760 0.10000E+01 0.0000 56 KOH,aq 0.57103E-09 -9.2433 0.57103E-09 -9.2433 0.10000E+01 0.0000 57 KSO4- 0.54473E-08 -8.2638 0.52220E-08 -8.2822 0.95863E+00 -0.0183 58 MgCO3,aq 0.13160E-10 -10.8807 0.13160E-10 -10.8807 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14488E-10 -10.8390 0.13889E-10 -10.8573 0.95868E+00 -0.0183 60 MgCl+ 0.88790E-11 -11.0516 0.85121E-11 -11.0700 0.95868E+00 -0.0183 61 MgOH+ 0.16250E-08 -8.7891 0.15579E-08 -8.8075 0.95868E+00 -0.0183 63 MnO,aq 0.28125E-09 -9.5509 0.28125E-09 -9.5509 0.10000E+01 0.0000 64 MnOH+ 0.95155E-08 -8.0216 0.91222E-08 -8.0399 0.95868E+00 -0.0183 65 MnO2-2 0.84874E-16 -16.0712 0.75644E-16 -16.1212 0.89125E+00 -0.0500 66 HMnO2- 0.19203E-12 -12.7166 0.18409E-12 -12.7350 0.95863E+00 -0.0183 69 MnCl+ 0.28468E-10 -10.5456 0.27292E-10 -10.5640 0.95868E+00 -0.0183 70 MnSO4,aq 0.21919E-09 -9.6592 0.21919E-09 -9.6592 0.10000E+01 0.0000 71 NaCl,aq 0.10570E-07 -7.9759 0.10570E-07 -7.9759 0.10000E+01 0.0000 72 NaOH,aq 0.93277E-08 -8.0302 0.93277E-08 -8.0302 0.10000E+01 0.0000 74 OH- 0.54260E-04 -4.2655 0.52014E-04 -4.2839 0.95859E+00 -0.0184 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.86976E-09 -9.0606 0.83380E-09 -9.0789 0.95865E+00 -0.0183 84 PO4-3 0.37831E-12 -12.4222 0.29887E-12 -12.5245 0.79001E+00 -0.1024 87 H2P2O7-2 0.61163E-19 -19.2135 0.54512E-19 -19.2635 0.89125E+00 -0.0500 88 HP2O7-3 0.12418E-17 -17.9059 0.97989E-18 -18.0088 0.78907E+00 -0.1029 89 P2O7-4 0.31648E-19 -19.4997 0.21074E-19 -19.6763 0.66588E+00 -0.1766 90 H2S,aq 0.17760E-13 -13.7505 0.17759E-13 -13.7506 0.99991E+00 0.0000 97 SO3-2 0.15067E-14 -14.8220 0.13433E-14 -14.8718 0.89157E+00 -0.0498 98 HSO3- 0.97461E-15 -15.0112 0.93429E-15 -15.0295 0.95863E+00 -0.0183 99 HSO4- 0.25299E-09 -9.5969 0.24255E-09 -9.6152 0.95870E+00 -0.0183 Charge balance for all species = 0.2169E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1158579E-07 -.1001128E-03 -.1009024E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999459E+06 0.0000 3 Cl- 0.1379640E-03 0.1379771E-03 0.4891444E+01 4.0758 4 SO4-- 0.2542017E-04 0.2550493E-04 0.2449916E+01 11.2639 5 HCO3- 0.1265845E-04 0.1307027E-04 0.7974697E+00 3.0384 6 HS- 0.5395987E-12 0.7145590E-10 0.2363066E-05 -4.3319 7 Al+++ 0.1002433E-20 0.3265861E-05 0.8811321E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4064607E-03 0.3906509E+02 -3.4276 9 Ca++ 0.1230771E-04 0.1248732E-04 0.5004408E+00 10.9488 10 Mg++ 0.4924544E-07 0.5094770E-07 0.1238576E-02 8.5510 11 Fe++ 0.2907861E-09 0.1590070E-08 0.8879597E-04 6.3222 12 K+ 0.1549321E-04 0.1549926E-04 0.6060204E+00 3.1262 13 Na+ 0.2515667E-03 0.2517090E-03 0.5786437E+01 4.3367 14 Mn++ 0.3760620E-07 0.4765075E-07 0.2617700E-02 8.4339 15 HPO4-- 0.4565209E-08 0.5435347E-08 0.5216518E-03 7.5182 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1195732E-02 -.1001107E-03 -.1095621E-02 0.0000000E+00 2 H2O 0.5550734E+02 0.5550712E+02 0.2139923E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2752755E-04 0.2550440E-04 0.2023150E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2023079E-05 0.7145441E-10 -.2023150E-05 0.0000000E+00 7 Al+++ 0.2380341E-03 0.3265793E-05 0.2347683E-03 0.0000000E+00 8 H4SiO4 0.7601332E-03 0.4064523E-03 0.3536809E-03 0.0000000E+00 9 Ca++ 0.9843147E-04 0.1248706E-04 0.8594441E-04 0.0000000E+00 10 Mg++ 0.5793651E-04 0.5094664E-07 0.5788556E-04 0.0000000E+00 11 Fe++ 0.5204963E-04 0.1590036E-08 0.5204804E-04 0.0000000E+00 12 K+ 0.1549894E-04 0.1549894E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2517038E-03 0.2517038E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1265718E-05 0.4764975E-07 0.1218068E-05 0.0000000E+00 15 HPO4-- 0.4319831E-06 0.5435234E-08 0.4265479E-06 0.0000000E+00 Chg. balance for solid moles: -.5633E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0730000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1422E-06 -6.847 0.7142E-04 -4.146 0.1398 0.2270E-04 clinochlore 0.1158E-04 -4.936 0.6435E-02 -2.191 12.60 0.2448E-02 daphnite 0.7173E-05 -5.144 0.5118E-02 -2.291 10.02 0.1551E-02 chlorite-Mn 0.2436E-06 -6.613 0.1727E-03 -3.763 0.3382 0.5504E-04 hematite 0.8093E-05 -5.092 0.1292E-02 -2.889 2.530 0.2450E-03 kaolinite 0.1316E-04 -4.881 0.3397E-02 -2.469 6.651 0.1307E-02 lawsonite 0.6525E-04 -4.185 0.2050E-01 -1.688 40.15 0.6612E-02 stilbite 0.1998E-04 -4.699 0.1408E-01 -1.851 27.57 0.6569E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3776E+00 0.3776E+00 1.0000 -0.423 chlorite-Mn 0.1283E-01 0.1283E-01 1.0000 -1.892 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.051073 g Volume = 0.018809 cm3 Porosity: 98.1725% V(tot) - V(min): 0.10104E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0730000 g log = -1.1367 Original solution: 1000.0103000 g Original solution / Rock added: 13698.77 (Water/Rock Ratio), log = 4.1367 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2999E-04 1.0071 0.3082E-04 0.3060E-04 CH4,gas 0.3834E-15 1.0125 0.3961E-15 0.3912E-15 H2,gas 0.5868E-06 1.0005 0.5990E-06 0.5987E-06 H2S,gas 0.4804E-12 0.9960 0.4882E-12 0.4901E-12 S2,gas 0.2443E-31 1.0000 0.2493E-31 0.2493E-31 CO,gas 0.4822E-14 1.0000 0.4920E-14 0.4920E-14 SO3,gas 0.1036E-35 1.0000 0.1057E-35 0.1057E-35 SO2,gas 0.2414E-19 1.0000 0.2463E-19 0.2463E-19 HCl,gas 0.4656E-15 1.0000 0.4750E-15 0.4750E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.87 -6.21 -2.070 0.10604E+05 -4.511 3 CH4,gas 4.54 -12.56 -17.10 -4.275 0.29200E+05 -15.402 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13526E+05 -6.223 5 H2S,gas -6.23 -20.24 -14.01 -7.005 0.23922E+05 -12.311 6 S2,gas -7.34 -40.64 -33.30 -5.123 0.56863E+05 -31.603 7 CO,gas 3.21 -12.79 -16.01 -4.925 0.27332E+05 -14.308 8 SO3,gas 17.12 -20.55 -37.67 -9.419 0.64329E+05 -35.976 9 SO2,gas 0.83 -20.48 -21.31 -5.682 0.36382E+05 -19.608 10 HCl,gas 5.19 -11.83 -17.02 -8.511 0.29065E+05 -15.323 11 acmite 7.71 3.76 -3.95 -0.410 0.67363E+04 15 albite-high 0.69 -3.18 -3.88 -0.298 0.66216E+04 16 albite -0.38 -3.18 -2.80 -0.215 0.47828E+04 19 spessartine 24.46 20.54 -3.92 -0.196 0.66865E+04 20 analcite 3.32 0.24 -3.08 -0.342 0.52577E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.60 -4.29 -2.144 0.73214E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.92 -2.89 -0.963 0.49312E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.92 -2.73 -0.911 0.46669E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29423E+04 42 celadonite 5.34 0.73 -4.61 -0.271 0.78778E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43572E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12918E+04 52 chloritoid-Mn 11.40 10.53 -0.87 -0.058 0.14895E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64756E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82453E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68780E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.24 -3.97 -0.397 0.67832E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 105 lizardite 23.24 18.80 -4.45 -0.371 0.75917E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20473E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.40 -1.91 -0.147 0.32595E+04 120 muscovite 2.58 1.13 -1.46 -0.086 0.24851E+04 121 paragonite 4.24 2.34 -1.90 -0.112 0.32475E+04 122 nepheline 8.34 3.67 -4.67 -0.667 0.79725E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49711E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.01 -2.39 -0.478 0.40850E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.44 -3.46 -1.153 0.59080E+04 152 rhodonite 7.45 5.01 -2.44 -0.488 0.41652E+04 153 sanidine -1.28 -4.40 -3.12 -0.240 0.53273E+04 155 siderite -2.61 -6.55 -3.94 -1.313 0.67274E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.28 -1.74 -0.052 0.29734E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83490E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54866E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77667E+04 174 tephroite 18.09 13.44 -4.65 -0.664 0.79323E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.11 -3.59 -0.220 0.61364E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.71 -3.37 -0.207 0.57582E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.25 -3.01 -0.184 0.51379E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.85 -2.81 -0.172 0.47954E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.93 -1.41 -0.091 0.24093E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.33 -1.19 -0.076 0.20329E+04 214 gypsum -4.96 -9.60 -4.65 -1.162 0.79390E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59580E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.62 -2.64 -0.203 0.45121E+04 243 an25ab75 2.65 0.02 -2.63 -0.202 0.44914E+04 244 an30ab70 3.28 0.66 -2.62 -0.202 0.44802E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0730000 g New total amount of reactant added: 0.0750000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0750000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3007783E-03 Osmotic coef. = 0.9896 True ionic strength = .3313108E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11347E-07 -7.9451 0.10879E-07 -7.9634 0.95873E+00 -0.0183 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13225E-03 -3.8786 0.95858E+00 -0.0184 4 SO4-- 0.25423E-04 -4.5948 0.22655E-04 -4.6448 0.89112E+00 -0.0501 5 HCO3- 0.12662E-04 -4.8975 0.12138E-04 -4.9158 0.95862E+00 -0.0184 6 HS- 0.52818E-12 -12.2772 0.50631E-12 -12.2956 0.95859E+00 -0.0184 7 Al+++ 0.94210E-21 -21.0259 0.74303E-21 -21.1290 0.78869E+00 -0.1031 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.11808E-04 -4.9278 0.10520E-04 -4.9780 0.89096E+00 -0.0501 10 Mg++ 0.47244E-07 -7.3257 0.42088E-07 -7.3758 0.89086E+00 -0.0502 11 Fe++ 0.27895E-09 -9.5545 0.24851E-09 -9.6046 0.89088E+00 -0.0502 12 K+ 0.15918E-04 -4.7981 0.15259E-04 -4.8165 0.95862E+00 -0.0184 13 Na+ 0.25407E-03 -3.5950 0.24355E-03 -3.6134 0.95858E+00 -0.0184 14 Mn++ 0.36160E-07 -7.4418 0.32215E-07 -7.4919 0.89090E+00 -0.0502 15 HPO4-- 0.47605E-08 -8.3223 0.42422E-08 -8.3724 0.89112E+00 -0.0501 16 HSiO3- 0.33449E-04 -4.4756 0.32064E-04 -4.4940 0.95858E+00 -0.0184 17 Ca(HSiO3)+ 0.80134E-08 -8.0962 0.76819E-08 -8.1145 0.95863E+00 -0.0183 18 Mg(HSiO3)+ 0.39898E-10 -10.3990 0.38248E-10 -10.4174 0.95863E+00 -0.0183 19 NaHSiO3,aq 0.12630E-06 -6.8986 0.12630E-06 -6.8986 0.10000E+01 0.0000 20 AlO+ 0.89095E-12 -12.0501 0.85409E-12 -12.0685 0.95863E+00 -0.0183 21 AlOH+2 0.51931E-16 -16.2846 0.46267E-16 -16.3347 0.89092E+00 -0.0502 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.33189E-05 -5.4790 0.31813E-05 -5.4974 0.95854E+00 -0.0184 24 CH4,aq 0.26354E-18 -18.5792 0.26351E-18 -18.5792 0.99991E+00 0.0000 29 CO,aq 0.32336E-17 -17.4903 0.32336E-17 -17.4903 0.10000E+01 0.0000 30 CO2,aq 0.28219E-06 -6.5495 0.28217E-06 -6.5495 0.99991E+00 0.0000 31 CO3-2 0.10937E-06 -6.9611 0.97458E-07 -7.0112 0.89107E+00 -0.0501 32 CaCO3,aq 0.12856E-07 -7.8909 0.12856E-07 -7.8909 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34003E-08 -8.4685 0.32596E-08 -8.4868 0.95863E+00 -0.0183 34 CaCl+ 0.23487E-08 -8.6292 0.22515E-08 -8.6475 0.95863E+00 -0.0183 35 CaCl2,aq 0.70743E-13 -13.1503 0.70743E-13 -13.1503 0.10000E+01 0.0000 36 CaOH+ 0.71893E-07 -7.1433 0.68918E-07 -7.1617 0.95863E+00 -0.0183 37 CaSO4,aq 0.75682E-07 -7.1210 0.75682E-07 -7.1210 0.10000E+01 0.0000 38 HCl,aq 0.26364E-12 -12.5790 0.26364E-12 -12.5790 0.10000E+01 0.0000 43 FeCl+ 0.54267E-13 -13.2655 0.52021E-13 -13.2838 0.95863E+00 -0.0183 46 FeO,aq 0.81609E-10 -10.0883 0.81609E-10 -10.0883 0.10000E+01 0.0000 47 FeOH+ 0.77567E-09 -9.1103 0.74358E-09 -9.1287 0.95863E+00 -0.0183 48 HFeO2- 0.81880E-10 -10.0868 0.78489E-10 -10.1052 0.95858E+00 -0.0184 49 FeO+ 0.86622E-13 -13.0624 0.83038E-13 -13.0807 0.95863E+00 -0.0183 50 FeOH+2 0.19364E-18 -18.7130 0.17252E-18 -18.7632 0.89092E+00 -0.0502 51 FeO2- 0.14977E-09 -9.8246 0.14357E-09 -9.8430 0.95858E+00 -0.0184 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45623E-09 -9.3408 0.45619E-09 -9.3409 0.99991E+00 0.0000 54 KCl,aq 0.36575E-10 -10.4368 0.36575E-10 -10.4368 0.10000E+01 0.0000 55 KHSO4,aq 0.10633E-16 -16.9733 0.10633E-16 -16.9733 0.10000E+01 0.0000 56 KOH,aq 0.59900E-09 -9.2226 0.59900E-09 -9.2226 0.10000E+01 0.0000 57 KSO4- 0.55961E-08 -8.2521 0.53644E-08 -8.2705 0.95858E+00 -0.0184 58 MgCO3,aq 0.12892E-10 -10.8897 0.12892E-10 -10.8897 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13900E-10 -10.8570 0.13325E-10 -10.8753 0.95863E+00 -0.0183 60 MgCl+ 0.85164E-11 -11.0697 0.81641E-11 -11.0881 0.95863E+00 -0.0183 61 MgOH+ 0.15916E-08 -8.7982 0.15257E-08 -8.8165 0.95863E+00 -0.0183 63 MnO,aq 0.28189E-09 -9.5499 0.28189E-09 -9.5499 0.10000E+01 0.0000 64 MnOH+ 0.93409E-08 -8.0296 0.89544E-08 -8.0480 0.95863E+00 -0.0183 65 MnO2-2 0.88707E-16 -16.0520 0.79044E-16 -16.1021 0.89107E+00 -0.0501 66 HMnO2- 0.19653E-12 -12.7066 0.18839E-12 -12.7249 0.95858E+00 -0.0184 69 MnCl+ 0.27368E-10 -10.5628 0.26236E-10 -10.5811 0.95863E+00 -0.0183 70 MnSO4,aq 0.21070E-09 -9.6763 0.21070E-09 -9.6763 0.10000E+01 0.0000 71 NaCl,aq 0.10674E-07 -7.9717 0.10674E-07 -7.9717 0.10000E+01 0.0000 72 NaOH,aq 0.96186E-08 -8.0169 0.96186E-08 -8.0169 0.10000E+01 0.0000 74 OH- 0.55406E-04 -4.2564 0.53109E-04 -4.2748 0.95854E+00 -0.0184 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.88812E-09 -9.0515 0.85136E-09 -9.0699 0.95861E+00 -0.0184 84 PO4-3 0.40290E-12 -12.3948 0.31815E-12 -12.4974 0.78965E+00 -0.1026 87 H2P2O7-2 0.63780E-19 -19.1953 0.56832E-19 -19.2454 0.89107E+00 -0.0501 88 HP2O7-3 0.13226E-17 -17.8786 0.10431E-17 -17.9817 0.78870E+00 -0.1031 89 P2O7-4 0.34428E-19 -19.4631 0.22906E-19 -19.6400 0.66534E+00 -0.1770 90 H2S,aq 0.17025E-13 -13.7689 0.17024E-13 -13.7689 0.99991E+00 0.0000 97 SO3-2 0.15067E-14 -14.8220 0.13430E-14 -14.8719 0.89139E+00 -0.0499 98 HSO3- 0.95435E-15 -15.0203 0.91483E-15 -15.0387 0.95858E+00 -0.0184 99 HSO4- 0.24777E-09 -9.6060 0.23752E-09 -9.6243 0.95865E+00 -0.0183 Charge balance for all species = 0.2174E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1134738E-07 -.1022350E-03 -.1030413E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999458E+06 0.0000 3 Cl- 0.1379640E-03 0.1379771E-03 0.4891446E+01 4.0848 4 SO4-- 0.2542327E-04 0.2550494E-04 0.2449917E+01 11.2820 5 HCO3- 0.1266243E-04 0.1307028E-04 0.7974699E+00 3.0476 6 HS- 0.5281823E-12 0.7104233E-10 0.2349389E-05 -4.3322 7 Al+++ 0.9421032E-21 0.3334488E-05 0.8996477E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4071560E-03 0.3913191E+02 -3.4276 9 Ca++ 0.1180761E-04 0.1198180E-04 0.4801813E+00 10.9488 10 Mg++ 0.4724404E-07 0.4891080E-07 0.1189057E-02 8.5510 11 Fe++ 0.2789527E-09 0.1566664E-08 0.8748892E-04 6.3222 12 K+ 0.1591767E-04 0.1592390E-04 0.6226238E+00 3.1469 13 Na+ 0.2540731E-03 0.2542197E-03 0.5844153E+01 4.3500 14 Mn++ 0.3616035E-07 0.4602139E-07 0.2528190E-02 8.4349 15 HPO4-- 0.4760509E-08 0.5649036E-08 0.5421603E-03 7.5544 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1228849E-02 -.1022328E-03 -.1126616E-02 0.0000000E+00 2 H2O 0.5550731E+02 0.5550710E+02 0.2099048E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2758298E-04 0.2550440E-04 0.2078577E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2078506E-05 0.7104083E-10 -.2078577E-05 0.0000000E+00 7 Al+++ 0.2445556E-03 0.3334417E-05 0.2412212E-03 0.0000000E+00 8 H4SiO4 0.7809587E-03 0.4071474E-03 0.3738113E-03 0.0000000E+00 9 Ca++ 0.1007318E-03 0.1198155E-04 0.8875021E-04 0.0000000E+00 10 Mg++ 0.5952381E-04 0.4890976E-07 0.5947490E-04 0.0000000E+00 11 Fe++ 0.5347564E-04 0.1566631E-08 0.5347408E-04 0.0000000E+00 12 K+ 0.1592357E-04 0.1592357E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2542143E-03 0.2542143E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1300395E-05 0.4602041E-07 0.1254374E-05 0.0000000E+00 15 HPO4-- 0.4438182E-06 0.5648916E-08 0.4381693E-06 0.0000000E+00 Chg. balance for solid moles: -.9423E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0750000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1461E-06 -6.835 0.7337E-04 -4.134 0.1376 0.2331E-04 clinochlore 0.1189E-04 -4.925 0.6612E-02 -2.180 12.40 0.2515E-02 daphnite 0.7369E-05 -5.133 0.5258E-02 -2.279 9.862 0.1593E-02 chlorite-Mn 0.2509E-06 -6.601 0.1779E-03 -3.750 0.3336 0.5668E-04 hematite 0.8314E-05 -5.080 0.1328E-02 -2.877 2.491 0.2517E-03 kaolinite 0.1308E-04 -4.884 0.3376E-02 -2.472 6.332 0.1299E-02 lawsonite 0.6540E-04 -4.184 0.2055E-01 -1.687 38.55 0.6628E-02 stilbite 0.2262E-04 -4.646 0.1594E-01 -1.798 29.89 0.7433E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3776E+00 0.3776E+00 1.0000 -0.423 chlorite-Mn 0.1286E-01 0.1286E-01 1.0000 -1.891 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.053314 g Volume = 0.019800 cm3 Porosity: 98.0777% V(tot) - V(min): 0.10102E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0750000 g log = -1.1249 Original solution: 1000.0103000 g Original solution / Rock added: 13333.47 (Water/Rock Ratio), log = 4.1249 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2938E-04 1.0071 0.3019E-04 0.2998E-04 CH4,gas 0.3754E-15 1.0125 0.3879E-15 0.3831E-15 H2,gas 0.5867E-06 1.0005 0.5989E-06 0.5986E-06 H2S,gas 0.4605E-12 0.9960 0.4680E-12 0.4698E-12 S2,gas 0.2246E-31 1.0000 0.2292E-31 0.2292E-31 CO,gas 0.4723E-14 1.0000 0.4819E-14 0.4819E-14 SO3,gas 0.9936E-36 1.0000 0.1014E-35 0.1014E-35 SO2,gas 0.2315E-19 1.0000 0.2362E-19 0.2362E-19 HCl,gas 0.4559E-15 1.0000 0.4652E-15 0.4652E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.17819E-10 102 lawsonite 9.62 9.62 0.00 0.000 0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.88 -6.22 -2.073 0.10619E+05 -4.520 3 CH4,gas 4.54 -12.57 -17.11 -4.278 0.29215E+05 -15.411 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13526E+05 -6.223 5 H2S,gas -6.23 -20.26 -14.03 -7.014 0.23954E+05 -12.330 6 S2,gas -7.34 -40.67 -33.34 -5.129 0.56925E+05 -31.640 7 CO,gas 3.21 -12.80 -16.02 -4.928 0.27347E+05 -14.317 8 SO3,gas 17.12 -20.57 -37.69 -9.423 0.64360E+05 -35.994 9 SO2,gas 0.83 -20.49 -21.33 -5.687 0.36413E+05 -19.627 10 HCl,gas 5.19 -11.84 -17.03 -8.516 0.29081E+05 -15.332 11 acmite 7.71 3.78 -3.93 -0.409 0.67136E+04 15 albite-high 0.69 -3.17 -3.86 -0.297 0.65989E+04 16 albite -0.38 -3.17 -2.79 -0.214 0.47600E+04 19 spessartine 24.46 20.54 -3.91 -0.196 0.66815E+04 20 analcite 3.32 0.26 -3.07 -0.341 0.52349E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.62 -4.31 -2.153 0.73524E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.93 -2.90 -0.966 0.49464E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.93 -2.74 -0.914 0.46822E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29424E+04 42 celadonite 5.34 0.75 -4.59 -0.270 0.78423E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43572E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12919E+04 52 chloritoid-Mn 11.40 10.53 -0.87 -0.058 0.14878E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64756E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82454E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68781E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.26 -3.96 -0.396 0.67604E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 105 lizardite 23.24 18.80 -4.45 -0.371 0.75917E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20473E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.37 -1.89 -0.145 0.32241E+04 120 muscovite 2.58 1.15 -1.43 -0.084 0.24496E+04 121 paragonite 4.24 2.35 -1.89 -0.111 0.32247E+04 122 nepheline 8.34 3.68 -4.66 -0.665 0.79497E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49712E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.01 -2.39 -0.478 0.40833E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.44 -3.47 -1.156 0.59216E+04 152 rhodonite 7.45 5.01 -2.44 -0.488 0.41635E+04 153 sanidine -1.28 -4.37 -3.10 -0.238 0.52918E+04 155 siderite -2.61 -6.56 -3.95 -1.316 0.67427E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.29 -1.73 -0.052 0.29559E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83491E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54866E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77667E+04 174 tephroite 18.09 13.44 -4.64 -0.663 0.79289E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.11 -3.59 -0.220 0.61247E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.71 -3.37 -0.206 0.57507E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.24 -3.00 -0.184 0.51262E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.84 -2.80 -0.172 0.47879E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.94 -1.40 -0.090 0.23976E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.33 -1.19 -0.076 0.20254E+04 214 gypsum -4.96 -9.62 -4.67 -1.167 0.79700E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59581E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.61 -2.63 -0.202 0.44939E+04 243 an25ab75 2.65 0.03 -2.62 -0.202 0.44743E+04 244 an30ab70 3.28 0.66 -2.61 -0.201 0.44643E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0750000 g New total amount of reactant added: 0.0770000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2240E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0770000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3015847E-03 Osmotic coef. = 0.9896 True ionic strength = .3327953E-03 Chg. balance for total moles = 0.2240E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11114E-07 -7.9541 0.10655E-07 -7.9725 0.95867E+00 -0.0183 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13224E-03 -3.8786 0.95853E+00 -0.0184 4 SO4-- 0.25426E-04 -4.5947 0.22653E-04 -4.6449 0.89093E+00 -0.0502 5 HCO3- 0.12666E-04 -4.8974 0.12141E-04 -4.9157 0.95857E+00 -0.0184 6 HS- 0.51702E-12 -12.2865 0.49558E-12 -12.3049 0.95854E+00 -0.0184 7 Al+++ 0.88540E-21 -21.0529 0.69798E-21 -21.1562 0.78832E+00 -0.1033 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.11328E-04 -4.9459 0.10090E-04 -4.9961 0.89077E+00 -0.0502 10 Mg++ 0.45324E-07 -7.3437 0.40369E-07 -7.3940 0.89067E+00 -0.0503 11 Fe++ 0.26760E-09 -9.5725 0.23835E-09 -9.6228 0.89069E+00 -0.0503 12 K+ 0.16342E-04 -4.7867 0.15665E-04 -4.8051 0.95857E+00 -0.0184 13 Na+ 0.25658E-03 -3.5908 0.24594E-03 -3.6092 0.95853E+00 -0.0184 14 Mn++ 0.34764E-07 -7.4589 0.30965E-07 -7.5091 0.89071E+00 -0.0503 15 HPO4-- 0.49643E-08 -8.3041 0.44228E-08 -8.3543 0.89093E+00 -0.0502 16 HSiO3- 0.34155E-04 -4.4665 0.32739E-04 -4.4849 0.95853E+00 -0.0184 17 Ca(HSiO3)+ 0.78485E-08 -8.1052 0.75234E-08 -8.1236 0.95858E+00 -0.0184 18 Mg(HSiO3)+ 0.39077E-10 -10.4081 0.37458E-10 -10.4265 0.95858E+00 -0.0184 19 NaHSiO3,aq 0.13023E-06 -6.8853 0.13023E-06 -6.8853 0.10000E+01 0.0000 20 AlO+ 0.87262E-12 -12.0592 0.83647E-12 -12.0775 0.95858E+00 -0.0184 21 AlOH+2 0.49821E-16 -16.3026 0.44377E-16 -16.3528 0.89073E+00 -0.0503 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.33890E-05 -5.4699 0.32483E-05 -5.4883 0.95849E+00 -0.0184 24 CH4,aq 0.25804E-18 -18.5883 0.25802E-18 -18.5884 0.99991E+00 0.0000 29 CO,aq 0.31673E-17 -17.4993 0.31673E-17 -17.4993 0.10000E+01 0.0000 30 CO2,aq 0.27644E-06 -6.5584 0.27641E-06 -6.5584 0.99991E+00 0.0000 31 CO3-2 0.11173E-06 -6.9518 0.99536E-07 -7.0020 0.89088E+00 -0.0502 32 CaCO3,aq 0.12594E-07 -7.8999 0.12594E-07 -7.8999 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.32624E-08 -8.4865 0.31273E-08 -8.5048 0.95858E+00 -0.0184 34 CaCl+ 0.22528E-08 -8.6473 0.21595E-08 -8.6657 0.95858E+00 -0.0184 35 CaCl2,aq 0.67846E-13 -13.1685 0.67846E-13 -13.1685 0.10000E+01 0.0000 36 CaOH+ 0.70413E-07 -7.1523 0.67496E-07 -7.1707 0.95858E+00 -0.0184 37 CaSO4,aq 0.72584E-07 -7.1392 0.72584E-07 -7.1392 0.10000E+01 0.0000 38 HCl,aq 0.25819E-12 -12.5881 0.25819E-12 -12.5881 0.10000E+01 0.0000 43 FeCl+ 0.52047E-13 -13.2836 0.49891E-13 -13.3020 0.95858E+00 -0.0184 46 FeO,aq 0.81604E-10 -10.0883 0.81604E-10 -10.0883 0.10000E+01 0.0000 47 FeOH+ 0.75966E-09 -9.1194 0.72819E-09 -9.1378 0.95858E+00 -0.0184 48 HFeO2- 0.83605E-10 -10.0778 0.80138E-10 -10.0962 0.95853E+00 -0.0184 49 FeO+ 0.84839E-13 -13.0714 0.81325E-13 -13.0898 0.95858E+00 -0.0184 50 FeOH+2 0.18577E-18 -18.7310 0.16547E-18 -18.7813 0.89073E+00 -0.0503 51 FeO2- 0.15293E-09 -9.8155 0.14659E-09 -9.8339 0.95853E+00 -0.0184 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45618E-09 -9.3409 0.45614E-09 -9.3409 0.99991E+00 0.0000 54 KCl,aq 0.37546E-10 -10.4254 0.37546E-10 -10.4254 0.10000E+01 0.0000 55 KHSO4,aq 0.10690E-16 -16.9710 0.10690E-16 -16.9710 0.10000E+01 0.0000 56 KOH,aq 0.62789E-09 -9.2021 0.62789E-09 -9.2021 0.10000E+01 0.0000 57 KSO4- 0.57448E-08 -8.2407 0.55066E-08 -8.2591 0.95853E+00 -0.0184 58 MgCO3,aq 0.12629E-10 -10.8986 0.12629E-10 -10.8986 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13336E-10 -10.8750 0.12784E-10 -10.8933 0.95858E+00 -0.0184 60 MgCl+ 0.81685E-11 -11.0879 0.78302E-11 -11.1062 0.95858E+00 -0.0184 61 MgOH+ 0.15588E-08 -8.8072 0.14942E-08 -8.8256 0.95858E+00 -0.0184 63 MnO,aq 0.28248E-09 -9.5490 0.28248E-09 -9.5490 0.10000E+01 0.0000 64 MnOH+ 0.91680E-08 -8.0377 0.87882E-08 -8.0561 0.95858E+00 -0.0184 65 MnO2-2 0.92699E-16 -16.0329 0.82584E-16 -16.0831 0.89088E+00 -0.0502 66 HMnO2- 0.20111E-12 -12.6966 0.19277E-12 -12.7150 0.95853E+00 -0.0184 69 MnCl+ 0.26306E-10 -10.5799 0.25216E-10 -10.5983 0.95858E+00 -0.0184 70 MnSO4,aq 0.20250E-09 -9.6936 0.20250E-09 -9.6936 0.10000E+01 0.0000 71 NaCl,aq 0.10778E-07 -7.9674 0.10778E-07 -7.9674 0.10000E+01 0.0000 72 NaOH,aq 0.99176E-08 -8.0036 0.99176E-08 -8.0036 0.10000E+01 0.0000 74 OH- 0.56576E-04 -4.2474 0.54228E-04 -4.2658 0.95849E+00 -0.0184 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.90688E-09 -9.0424 0.86929E-09 -9.0608 0.95855E+00 -0.0184 84 PO4-3 0.42911E-12 -12.3674 0.33869E-12 -12.4702 0.78928E+00 -0.1028 87 H2P2O7-2 0.66510E-19 -19.1771 0.59252E-19 -19.2273 0.89088E+00 -0.0502 88 HP2O7-3 0.14086E-17 -17.8512 0.11104E-17 -17.9545 0.78833E+00 -0.1033 89 P2O7-4 0.37454E-19 -19.4265 0.24898E-19 -19.6038 0.66478E+00 -0.1773 90 H2S,aq 0.16321E-13 -13.7873 0.16319E-13 -13.7873 0.99991E+00 0.0000 97 SO3-2 0.15067E-14 -14.8220 0.13428E-14 -14.8720 0.89120E+00 -0.0500 98 HSO3- 0.93451E-15 -15.0294 0.89576E-15 -15.0478 0.95853E+00 -0.0184 99 HSO4- 0.24265E-09 -9.6150 0.23260E-09 -9.6334 0.95860E+00 -0.0184 Charge balance for all species = 0.2178E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1111382E-07 -.1044028E-03 -.1052262E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999457E+06 0.0000 3 Cl- 0.1379641E-03 0.1379772E-03 0.4891447E+01 4.0938 4 SO4-- 0.2542625E-04 0.2550495E-04 0.2449917E+01 11.3001 5 HCO3- 0.1266623E-04 0.1307028E-04 0.7974701E+00 3.0567 6 HS- 0.5170175E-12 0.7062177E-10 0.2335480E-05 -4.3324 7 Al+++ 0.8854035E-21 0.3404594E-05 0.9185621E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4078664E-03 0.3920017E+02 -3.4276 9 Ca++ 0.1132777E-04 0.1149672E-04 0.4607413E+00 10.9488 10 Mg++ 0.4532379E-07 0.4695578E-07 0.1141529E-02 8.5510 11 Fe++ 0.2676008E-09 0.1544182E-08 0.8623341E-04 6.3221 12 K+ 0.1634214E-04 0.1634855E-04 0.6392273E+00 3.1674 13 Na+ 0.2565794E-03 0.2567303E-03 0.5901868E+01 4.3633 14 Mn++ 0.3476429E-07 0.4444378E-07 0.2441524E-02 8.4358 15 HPO4-- 0.4964270E-08 0.5871583E-08 0.5635190E-03 7.5906 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1261966E-02 -.1044006E-03 -.1157565E-02 0.0000000E+00 2 H2O 0.5550728E+02 0.5550708E+02 0.2058095E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2763840E-04 0.2550440E-04 0.2134003E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2133932E-05 0.7062024E-10 -.2134003E-05 0.0000000E+00 7 Al+++ 0.2510771E-03 0.3404520E-05 0.2476726E-03 0.0000000E+00 8 H4SiO4 0.8017843E-03 0.4078575E-03 0.3939267E-03 0.0000000E+00 9 Ca++ 0.1030320E-03 0.1149647E-04 0.9153557E-04 0.0000000E+00 10 Mg++ 0.6111111E-04 0.4695476E-07 0.6106416E-04 0.0000000E+00 11 Fe++ 0.5490166E-04 0.1544149E-08 0.5490012E-04 0.0000000E+00 12 K+ 0.1634820E-04 0.1634820E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2567248E-03 0.2567248E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1335072E-05 0.4444282E-07 0.1290629E-05 0.0000000E+00 15 HPO4-- 0.4556534E-06 0.5871456E-08 0.4497819E-06 0.0000000E+00 Chg. balance for solid moles: 0.2478E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0770000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1499E-06 -6.824 0.7531E-04 -4.123 0.1356 0.2393E-04 clinochlore 0.1221E-04 -4.913 0.6788E-02 -2.168 12.22 0.2582E-02 daphnite 0.7566E-05 -5.121 0.5398E-02 -2.268 9.717 0.1636E-02 chlorite-Mn 0.2581E-06 -6.588 0.1830E-03 -3.738 0.3294 0.5832E-04 hematite 0.8536E-05 -5.069 0.1363E-02 -2.865 2.454 0.2584E-03 kaolinite 0.1301E-04 -4.886 0.3360E-02 -2.474 6.048 0.1293E-02 lawsonite 0.6554E-04 -4.183 0.2060E-01 -1.686 37.07 0.6642E-02 stilbite 0.2524E-04 -4.598 0.1779E-01 -1.750 32.02 0.8297E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3776E+00 0.3776E+00 1.0000 -0.423 chlorite-Mn 0.1288E-01 0.1288E-01 1.0000 -1.890 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.055553 g Volume = 0.020790 cm3 Porosity: 97.9831% V(tot) - V(min): 0.10100E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0770000 g log = -1.1135 Original solution: 1000.0103000 g Original solution / Rock added: 12987.15 (Water/Rock Ratio), log = 4.1135 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2878E-04 1.0071 0.2957E-04 0.2937E-04 CH4,gas 0.3676E-15 1.0125 0.3798E-15 0.3751E-15 H2,gas 0.5866E-06 1.0005 0.5989E-06 0.5985E-06 H2S,gas 0.4414E-12 0.9960 0.4486E-12 0.4504E-12 S2,gas 0.2064E-31 1.0000 0.2106E-31 0.2106E-31 CO,gas 0.4626E-14 1.0000 0.4720E-14 0.4720E-14 SO3,gas 0.9529E-36 1.0000 0.9723E-36 0.9723E-36 SO2,gas 0.2220E-19 1.0000 0.2265E-19 0.2265E-19 HCl,gas 0.4465E-15 1.0000 0.4556E-15 0.4556E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.89 -6.23 -2.076 0.10634E+05 -4.529 3 CH4,gas 4.54 -12.58 -17.12 -4.280 0.29231E+05 -15.420 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13526E+05 -6.223 5 H2S,gas -6.23 -20.28 -14.05 -7.024 0.23985E+05 -12.348 6 S2,gas -7.34 -40.71 -33.38 -5.135 0.56988E+05 -31.676 7 CO,gas 3.21 -12.81 -16.03 -4.931 0.27362E+05 -14.326 8 SO3,gas 17.12 -20.59 -37.71 -9.428 0.64391E+05 -36.012 9 SO2,gas 0.83 -20.51 -21.34 -5.692 0.36444E+05 -19.645 10 HCl,gas 5.19 -11.85 -17.04 -8.520 0.29096E+05 -15.341 11 acmite 7.71 3.79 -3.92 -0.407 0.66909E+04 15 albite-high 0.69 -3.16 -3.85 -0.296 0.65762E+04 16 albite -0.38 -3.16 -2.77 -0.213 0.47373E+04 19 spessartine 24.46 20.55 -3.91 -0.196 0.66768E+04 20 analcite 3.32 0.27 -3.05 -0.339 0.52122E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.64 -4.32 -2.162 0.73834E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.94 -2.91 -0.969 0.49617E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.94 -2.75 -0.917 0.46975E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29424E+04 42 celadonite 5.34 0.77 -4.57 -0.269 0.78074E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43572E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12919E+04 52 chloritoid-Mn 11.40 10.53 -0.87 -0.058 0.14862E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64757E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82455E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68782E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.27 -3.95 -0.395 0.67377E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 105 lizardite 23.24 18.80 -4.45 -0.371 0.75917E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20474E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.35 -1.87 -0.144 0.31891E+04 120 muscovite 2.58 1.17 -1.41 -0.083 0.24147E+04 121 paragonite 4.24 2.36 -1.88 -0.110 0.32020E+04 122 nepheline 8.34 3.70 -4.64 -0.663 0.79270E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49712E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.01 -2.39 -0.478 0.40817E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.45 -3.48 -1.159 0.59353E+04 152 rhodonite 7.45 5.01 -2.44 -0.488 0.41620E+04 153 sanidine -1.28 -4.35 -3.08 -0.237 0.52569E+04 155 siderite -2.61 -6.57 -3.96 -1.319 0.67580E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.30 -1.72 -0.051 0.29386E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83492E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54867E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77667E+04 174 tephroite 18.09 13.44 -4.64 -0.663 0.79258E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.10 -3.58 -0.219 0.61131E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.71 -3.36 -0.206 0.57432E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.23 -3.00 -0.183 0.51146E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.84 -2.80 -0.171 0.47804E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.94 -1.40 -0.090 0.23861E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.34 -1.18 -0.076 0.20179E+04 214 gypsum -4.96 -9.64 -4.69 -1.171 0.80010E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59581E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.60 -2.62 -0.202 0.44757E+04 243 an25ab75 2.65 0.04 -2.61 -0.201 0.44572E+04 244 an30ab70 3.28 0.67 -2.61 -0.200 0.44484E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0770000 g New total amount of reactant added: 0.0790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2239E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0790000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3024379E-03 Osmotic coef. = 0.9896 True ionic strength = .3343395E-03 Chg. balance for total moles = 0.2239E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10885E-07 -7.9632 0.10435E-07 -7.9815 0.95862E+00 -0.0184 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13224E-03 -3.8787 0.95848E+00 -0.0184 4 SO4-- 0.25429E-04 -4.5947 0.22651E-04 -4.6449 0.89073E+00 -0.0503 5 HCO3- 0.12670E-04 -4.8972 0.12144E-04 -4.9156 0.95851E+00 -0.0184 6 HS- 0.50611E-12 -12.2958 0.48509E-12 -12.3142 0.95848E+00 -0.0184 7 Al+++ 0.83216E-21 -21.0798 0.65568E-21 -21.1833 0.78793E+00 -0.1035 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.10868E-04 -4.9639 0.96786E-05 -5.0142 0.89057E+00 -0.0503 10 Mg++ 0.43483E-07 -7.3617 0.38720E-07 -7.4121 0.89047E+00 -0.0504 11 Fe++ 0.25672E-09 -9.5905 0.22861E-09 -9.6409 0.89050E+00 -0.0504 12 K+ 0.16767E-04 -4.7756 0.16071E-04 -4.7940 0.95852E+00 -0.0184 13 Na+ 0.25909E-03 -3.5866 0.24833E-03 -3.6050 0.95848E+00 -0.0184 14 Mn++ 0.33418E-07 -7.4760 0.29759E-07 -7.5264 0.89052E+00 -0.0504 15 HPO4-- 0.51767E-08 -8.2859 0.46110E-08 -8.3362 0.89074E+00 -0.0503 16 HSiO3- 0.34877E-04 -4.4575 0.33429E-04 -4.4759 0.95848E+00 -0.0184 17 Ca(HSiO3)+ 0.76870E-08 -8.1142 0.73682E-08 -8.1326 0.95852E+00 -0.0184 18 Mg(HSiO3)+ 0.38273E-10 -10.4171 0.36685E-10 -10.4355 0.95852E+00 -0.0184 19 NaHSiO3,aq 0.13426E-06 -6.8721 0.13426E-06 -6.8721 0.10000E+01 0.0000 20 AlO+ 0.85467E-12 -12.0682 0.81922E-12 -12.0866 0.95852E+00 -0.0184 21 AlOH+2 0.47798E-16 -16.3206 0.42566E-16 -16.3709 0.89054E+00 -0.0503 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.34605E-05 -5.4609 0.33167E-05 -5.4793 0.95844E+00 -0.0184 24 CH4,aq 0.25267E-18 -18.5975 0.25264E-18 -18.5975 0.99991E+00 0.0000 29 CO,aq 0.31024E-17 -17.5083 0.31024E-17 -17.5083 0.10000E+01 0.0000 30 CO2,aq 0.27080E-06 -6.5673 0.27078E-06 -6.5674 0.99991E+00 0.0000 31 CO3-2 0.11413E-06 -6.9426 0.10165E-06 -6.9929 0.89069E+00 -0.0503 32 CaCO3,aq 0.12337E-07 -7.9088 0.12337E-07 -7.9088 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.31301E-08 -8.5044 0.30003E-08 -8.5228 0.95852E+00 -0.0184 34 CaCl+ 0.21608E-08 -8.6654 0.20712E-08 -8.6838 0.95852E+00 -0.0184 35 CaCl2,aq 0.65070E-13 -13.1866 0.65070E-13 -13.1866 0.10000E+01 0.0000 36 CaOH+ 0.68965E-07 -7.1614 0.66104E-07 -7.1798 0.95852E+00 -0.0184 37 CaSO4,aq 0.69614E-07 -7.1573 0.69614E-07 -7.1573 0.10000E+01 0.0000 38 HCl,aq 0.25285E-12 -12.5971 0.25285E-12 -12.5971 0.10000E+01 0.0000 43 FeCl+ 0.49920E-13 -13.3017 0.47849E-13 -13.3201 0.95852E+00 -0.0184 46 FeO,aq 0.81600E-10 -10.0883 0.81600E-10 -10.0883 0.10000E+01 0.0000 47 FeOH+ 0.74399E-09 -9.1284 0.71314E-09 -9.1468 0.95852E+00 -0.0184 48 HFeO2- 0.85366E-10 -10.0687 0.81821E-10 -10.0871 0.95848E+00 -0.0184 49 FeO+ 0.83094E-13 -13.0804 0.79648E-13 -13.0988 0.95852E+00 -0.0184 50 FeOH+2 0.17823E-18 -18.7490 0.15872E-18 -18.7994 0.89054E+00 -0.0503 51 FeO2- 0.15616E-09 -9.8064 0.14968E-09 -9.8248 0.95848E+00 -0.0184 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45613E-09 -9.3409 0.45609E-09 -9.3410 0.99991E+00 0.0000 54 KCl,aq 0.38517E-10 -10.4143 0.38517E-10 -10.4143 0.10000E+01 0.0000 55 KHSO4,aq 0.10740E-16 -16.9690 0.10740E-16 -16.9690 0.10000E+01 0.0000 56 KOH,aq 0.65773E-09 -9.1820 0.65773E-09 -9.1820 0.10000E+01 0.0000 57 KSO4- 0.58934E-08 -8.2296 0.56487E-08 -8.2481 0.95848E+00 -0.0184 58 MgCO3,aq 0.12371E-10 -10.9076 0.12371E-10 -10.9076 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12796E-10 -10.8929 0.12265E-10 -10.9113 0.95852E+00 -0.0184 60 MgCl+ 0.78350E-11 -11.1060 0.75101E-11 -11.1244 0.95852E+00 -0.0184 61 MgOH+ 0.15267E-08 -8.8162 0.14634E-08 -8.8346 0.95852E+00 -0.0184 63 MnO,aq 0.28304E-09 -9.5482 0.28304E-09 -9.5482 0.10000E+01 0.0000 64 MnOH+ 0.89971E-08 -8.0459 0.86239E-08 -8.0643 0.95852E+00 -0.0184 65 MnO2-2 0.96856E-16 -16.0139 0.86268E-16 -16.0642 0.89069E+00 -0.0503 66 HMnO2- 0.20576E-12 -12.6866 0.19722E-12 -12.7051 0.95848E+00 -0.0184 69 MnCl+ 0.25282E-10 -10.5972 0.24233E-10 -10.6156 0.95852E+00 -0.0184 70 MnSO4,aq 0.19460E-09 -9.7109 0.19460E-09 -9.7109 0.10000E+01 0.0000 71 NaCl,aq 0.10883E-07 -7.9633 0.10883E-07 -7.9633 0.10000E+01 0.0000 72 NaOH,aq 0.10225E-07 -7.9903 0.10225E-07 -7.9903 0.10000E+01 0.0000 74 OH- 0.57771E-04 -4.2383 0.55370E-04 -4.2567 0.95844E+00 -0.0184 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.92603E-09 -9.0334 0.88760E-09 -9.0518 0.95850E+00 -0.0184 84 PO4-3 0.45702E-12 -12.3401 0.36053E-12 -12.4431 0.78889E+00 -0.1030 87 H2P2O7-2 0.69356E-19 -19.1589 0.61774E-19 -19.2092 0.89069E+00 -0.0503 88 HP2O7-3 0.15002E-17 -17.8238 0.11821E-17 -17.9274 0.78794E+00 -0.1035 89 P2O7-4 0.40745E-19 -19.3899 0.27063E-19 -19.5676 0.66419E+00 -0.1777 90 H2S,aq 0.15646E-13 -13.8056 0.15644E-13 -13.8056 0.99991E+00 0.0000 97 SO3-2 0.15067E-14 -14.8220 0.13425E-14 -14.8721 0.89101E+00 -0.0501 98 HSO3- 0.91509E-15 -15.0385 0.87709E-15 -15.0570 0.95848E+00 -0.0184 99 HSO4- 0.23763E-09 -9.6241 0.22778E-09 -9.6425 0.95855E+00 -0.0184 Charge balance for all species = 0.2183E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1088522E-07 -.1066152E-03 -.1074561E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999455E+06 0.0000 3 Cl- 0.1379641E-03 0.1379772E-03 0.4891448E+01 4.1029 4 SO4-- 0.2542909E-04 0.2550496E-04 0.2449918E+01 11.3181 5 HCO3- 0.1266986E-04 0.1307029E-04 0.7974703E+00 3.0659 6 HS- 0.5061062E-12 0.7019429E-10 0.2321343E-05 -4.3327 7 Al+++ 0.8321604E-21 0.3476147E-05 0.9378671E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4085914E-03 0.3926985E+02 -3.4276 9 Ca++ 0.1086777E-04 0.1103166E-04 0.4421036E+00 10.9488 10 Mg++ 0.4348297E-07 0.4508095E-07 0.1095950E-02 8.5510 11 Fe++ 0.2567201E-09 0.1522617E-08 0.8502908E-04 6.3221 12 K+ 0.1676660E-04 0.1677319E-04 0.6558308E+00 3.1876 13 Na+ 0.2590856E-03 0.2592410E-03 0.5959583E+01 4.3765 14 Mn++ 0.3341818E-07 0.4291839E-07 0.2357726E-02 8.4367 15 HPO4-- 0.5176673E-08 0.6103161E-08 0.5857444E-03 7.6268 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1295083E-02 -.1066129E-03 -.1188470E-02 0.0000000E+00 2 H2O 0.5550726E+02 0.5550706E+02 0.2017065E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2769383E-04 0.2550440E-04 0.2189429E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2189359E-05 0.7019274E-10 -.2189429E-05 0.0000000E+00 7 Al+++ 0.2575986E-03 0.3476070E-05 0.2541225E-03 0.0000000E+00 8 H4SiO4 0.8226099E-03 0.4085824E-03 0.4140275E-03 0.0000000E+00 9 Ca++ 0.1053323E-03 0.1103142E-04 0.9430091E-04 0.0000000E+00 10 Mg++ 0.6269841E-04 0.4507996E-07 0.6265333E-04 0.0000000E+00 11 Fe++ 0.5632768E-04 0.1522583E-08 0.5632616E-04 0.0000000E+00 12 K+ 0.1677282E-04 0.1677282E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2592352E-03 0.2592352E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1369749E-05 0.4291744E-07 0.1326832E-05 0.0000000E+00 15 HPO4-- 0.4674886E-06 0.6103027E-08 0.4613855E-06 0.0000000E+00 Chg. balance for solid moles: -.2058E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1538E-06 -6.813 0.7725E-04 -4.112 0.1337 0.2455E-04 clinochlore 0.1253E-04 -4.902 0.6965E-02 -2.157 12.05 0.2649E-02 daphnite 0.7762E-05 -5.110 0.5538E-02 -2.257 9.584 0.1678E-02 chlorite-Mn 0.2654E-06 -6.576 0.1881E-03 -3.726 0.3256 0.5995E-04 hematite 0.8758E-05 -5.058 0.1399E-02 -2.854 2.420 0.2651E-03 kaolinite 0.1297E-04 -4.887 0.3349E-02 -2.475 5.794 0.1288E-02 lawsonite 0.6566E-04 -4.183 0.2063E-01 -1.685 35.70 0.6654E-02 stilbite 0.2787E-04 -4.555 0.1964E-01 -1.707 33.99 0.9160E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3776E+00 0.3776E+00 1.0000 -0.423 chlorite-Mn 0.1291E-01 0.1291E-01 1.0000 -1.889 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.057790 g Volume = 0.021780 cm3 Porosity: 97.8887% V(tot) - V(min): 0.10098E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0790000 g log = -1.1024 Original solution: 1000.0103000 g Original solution / Rock added: 12658.36 (Water/Rock Ratio), log = 4.1024 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2819E-04 1.0071 0.2897E-04 0.2877E-04 CH4,gas 0.3600E-15 1.0125 0.3719E-15 0.3673E-15 H2,gas 0.5865E-06 1.0005 0.5988E-06 0.5985E-06 H2S,gas 0.4232E-12 0.9960 0.4301E-12 0.4318E-12 S2,gas 0.1898E-31 1.0000 0.1936E-31 0.1936E-31 CO,gas 0.4531E-14 1.0000 0.4623E-14 0.4623E-14 SO3,gas 0.9139E-36 1.0000 0.9325E-36 0.9325E-36 SO2,gas 0.2129E-19 1.0000 0.2172E-19 0.2172E-19 HCl,gas 0.4373E-15 1.0000 0.4462E-15 0.4462E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.90 -6.24 -2.079 0.10650E+05 -4.538 3 CH4,gas 4.54 -12.58 -17.13 -4.282 0.29247E+05 -15.430 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13526E+05 -6.223 5 H2S,gas -6.23 -20.30 -14.07 -7.033 0.24016E+05 -12.366 6 S2,gas -7.34 -40.75 -33.41 -5.140 0.57050E+05 -31.713 7 CO,gas 3.21 -12.82 -16.03 -4.934 0.27378E+05 -14.335 8 SO3,gas 17.12 -20.61 -37.73 -9.432 0.64422E+05 -36.030 9 SO2,gas 0.83 -20.53 -21.36 -5.697 0.36475E+05 -19.663 10 HCl,gas 5.19 -11.86 -17.05 -8.525 0.29112E+05 -15.351 11 acmite 7.71 3.80 -3.91 -0.406 0.66682E+04 15 albite-high 0.69 -3.15 -3.84 -0.295 0.65535E+04 16 albite -0.38 -3.15 -2.76 -0.212 0.47147E+04 19 spessartine 24.46 20.55 -3.91 -0.195 0.66724E+04 20 analcite 3.32 0.28 -3.04 -0.338 0.51896E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.66 -4.34 -2.171 0.74144E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.95 -2.91 -0.972 0.49770E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.95 -2.76 -0.920 0.47128E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29425E+04 42 celadonite 5.34 0.79 -4.55 -0.268 0.77730E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12919E+04 52 chloritoid-Mn 11.40 10.53 -0.87 -0.058 0.14848E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64757E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82456E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68784E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.28 -3.93 -0.393 0.67151E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 105 lizardite 23.24 18.80 -4.45 -0.371 0.75917E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20474E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.33 -1.85 -0.142 0.31547E+04 120 muscovite 2.58 1.19 -1.39 -0.082 0.23803E+04 121 paragonite 4.24 2.38 -1.86 -0.110 0.31794E+04 122 nepheline 8.34 3.71 -4.63 -0.661 0.79044E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49713E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.01 -2.39 -0.478 0.40803E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.46 -3.48 -1.161 0.59491E+04 152 rhodonite 7.45 5.01 -2.44 -0.487 0.41605E+04 153 sanidine -1.28 -4.33 -3.06 -0.235 0.52224E+04 155 siderite -2.61 -6.58 -3.97 -1.322 0.67733E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.31 -1.71 -0.051 0.29216E+04 165 stilpnomelane-Mg 27.44 22.45 -4.99 -0.149 0.85225E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83493E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54867E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77667E+04 174 tephroite 18.09 13.45 -4.64 -0.663 0.79229E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.09 -3.57 -0.219 0.61018E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.70 -3.36 -0.206 0.57357E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.23 -2.99 -0.183 0.51033E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.83 -2.80 -0.171 0.47730E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.95 -1.39 -0.089 0.23747E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.34 -1.18 -0.076 0.20104E+04 214 gypsum -4.96 -9.66 -4.70 -1.176 0.80320E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59582E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.59 -2.61 -0.201 0.44576E+04 243 an25ab75 2.65 0.05 -2.60 -0.200 0.44403E+04 244 an30ab70 3.28 0.68 -2.60 -0.200 0.44326E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0020000 g Current total amount of reactant added: 0.0790000 g New total amount of reactant added: 0.0810000 g Mixing fraction reached given limit of 0.8000E-01 TOTMIX = 0.8100E-01 Execution stopped.