File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.12951E-02 0.10885E-07 0.9586 0.00000000E+00 H2O 2 0. 0.55507E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13796E-03 0.9585 0.00000000E+00 SO4-- 4 -2. 0.27694E-04 0.25429E-04 0.8907 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.12670E-04 0.9585 0.00000000E+00 HS- 6 -1. -0.21894E-05 0.50611E-12 0.9585 0.00000000E+00 Al+++ 7 3. 0.25760E-03 0.83216E-21 0.7879 0.00000000E+00 H4SiO4 8 0. 0.82261E-03 0.37357E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.10533E-03 0.10868E-04 0.8906 0.00000000E+00 Mg++ 10 2. 0.62698E-04 0.43483E-07 0.8905 0.00000000E+00 Fe++ 11 2. 0.56328E-04 0.25672E-09 0.8905 0.00000000E+00 K+ 12 1. 0.16773E-04 0.16767E-04 0.9585 0.00000000E+00 Na+ 13 1. 0.25924E-03 0.25909E-03 0.9585 0.00000000E+00 Mn++ 14 2. 0.13697E-05 0.33418E-07 0.8905 0.00000000E+00 HPO4-- 15 -2. 0.46749E-06 0.51767E-08 0.8907 0.00000000E+00 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.200000E+00 TEMP = 100.0000 SINC = 0.4000E-02 TEMPC = 0.0000 TOTMIX = 0.790000E-01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.0316 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0298 MnO2-2 65 -2. 40.4638 Ca(HSiO3)+ 17 1. 7.6723 HMnO2- 66 -1. 29.1232 Mg(HSiO3)+ 18 1. 7.5773 MnO4- 67 -1. 83.3111 NaHSiO3,aq 19 0. 7.8210 MnO4-2 68 -2. 81.3005 AlO+ 20 1. 6.8663 MnCl+ 69 1. -0.7894 AlOH+2 21 2. 3.1691 MnSO4,aq 70 0. -2.4604 HAlO2,aq 22 0. 10.5671 NaCl,aq 71 0. 0.4796 AlO2- 23 -1. 16.2221 NaOH,aq 72 0. 12.3669 CH4,aq 24 0. 6.0126 O2,aq 73 0. 53.5502 C2H6,aq 25 0. 12.3733 OH- 74 -1. 12.2382 C3H8,aq 26 0. 17.3707 HO2- 75 -1. 50.8010 C4H10,aq 27 0. 22.3757 H2O2,aq 76 0. 40.0166 ethanol,aq 28 0. 15.3258 H3PO2,aq 77 0. 24.3066 CO,aq 29 0. 4.6892 H2PO2- 78 -1. 26.5366 CO2,aq 30 0. -6.3298 HPO3-2 79 -2. 11.9254 CO3-2 31 -2. 10.0588 H3PO3,aq 80 0. 3.5792 CaCO3,aq 32 0. 5.9605 H2PO3- 81 -1. 5.6232 Ca(HCO3)+ 33 1. -1.4070 H3PO4,aq 82 0. -9.8447 CaCl+ 34 1. -0.2091 H2PO4- 83 -1. -7.2659 CaCl2,aq 35 0. 0.4151 PO4-3 84 -3. 12.0884 CaOH+ 36 1. 10.1471 H4P2O7,aq 85 0. -17.8095 CaSO4,aq 37 0. -2.5018 H3P2O7- 86 -1. -15.9156 HCl,aq 38 0. 0.7370 H2P2O7-2 87 -2. -13.4262 HClO,aq 39 0. 32.4260 HP2O7-3 88 -3. -6.7266 ClO- 40 -1. 39.6530 P2O7-4 89 -4. 2.8952 HClO2,aq 41 0. 70.1812 H2S,aq 90 0. -6.4900 Fe+3 42 3. 8.3809 S2-2 91 -2. 1.2355 FeCl+ 43 1. -0.1994 S3-2 92 -2. -8.8031 FeCl2,aq 44 0. 4.3001 S3- 93 -1. -16.3389 FeCl+2 45 2. 6.5269 S4-2 94 -2. -18.6615 FeO,aq 46 0. 16.4104 S5-2 95 -2. -28.3439 FeOH+ 47 1. 7.4874 SO2,aq 96 0. -0.2309 HFeO2- 48 -1. 24.3908 SO3-2 97 -2. 10.3052 FeO+ 49 1. 11.4004 HSO3- 98 -1. 2.5086 FeOH+2 50 2. 9.1194 HSO4- 99 -1. -2.9839 FeO2- 51 -1. 24.0895 HSO5- 100 -1. 38.8366 HFeO2,aq 52 0. 15.9850 S2O3-2 101 -2. -4.5600 H2,aq 53 0. 9.4190 HS2O3- 102 -1. -6.8123 KCl,aq 54 0. 1.7417 H2S2O3,aq 103 0. -8.0173 KHSO4,aq 55 0. -0.4514 S2O4-2 104 -2. 10.5541 KOH,aq 56 0. 12.3695 HS2O4- 105 -1. 7.6551 KSO4- 57 -1. -1.1908 H2S2O4,aq 106 0. 6.6259 MgCO3,aq 58 0. 6.5614 S2O5-2 107 -2. 10.0741 Mg(HCO3)+ 59 1. -1.4164 S2O6-2 108 -2. 11.5521 MgCl+ 60 1. -0.1664 S2O8-2 109 -2. 42.0620 MgOH+ 61 1. 9.4041 S3O6-2 110 -2. 3.7866 Mn+3 62 3. 19.1453 S4O6-2 111 -2. -17.8657 MnO,aq 63 0. 17.9848 S5O6-2 112 -2. -14.1333 MnOH+ 64 1. 8.5194 113 0. 10.3111 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.0000E+00 osumilite(2) 124 20.667 0.0000E+00 CO2,gas 2 -6.660 0.0000E+00 osumilite-Fe 125 14.390 0.0000E+00 CH4,gas 3 4.544 0.0000E+00 pargasite 126 65.092 0.0000E+00 H2,gas 4 8.000 0.0000E+00 periclase 127 16.138 0.0000E+00 H2S,gas 5 -6.230 0.0000E+00 periclase-Fe 128 11.627 0.0000E+00 S2,gas 6 -7.335 0.0000E+00 perovskite-Al 129 12.344 0.0000E+00 CO,gas 7 3.215 0.0000E+00 perovskite-Ca 130 23.807 0.0000E+00 SO3,gas 8 17.121 0.0000E+00 perovskite-Fe 131 21.143 0.0000E+00 SO2,gas 9 0.832 0.0000E+00 perovskite-Mg 132 23.119 0.0000E+00 HCl,gas 10 5.189 0.0000E+00 phase_A 133 80.189 0.0000E+00 acmite 11 7.710 0.0000E+00 phlogopite-Na 134 29.647 0.0000E+00 akermanite 12 36.442 0.0000E+00 piemontite(ordered) 135 33.776 0.0000E+00 akimotoite 13 16.591 0.0000E+00 prehnite 136 19.372 0.0000E+00 akimotoite-Fe 14 13.067 0.0000E+00 prehnite-Fe 137 22.498 0.0000E+00 albite-high 15 0.693 0.0000E+00 pumpellyite-Fe 138 46.269 0.0000E+00 albite 16 -0.384 0.0000E+00 pumpellyite-Mg 139 48.995 0.0000E+00 almandine 17 24.442 0.0000E+00 px-Mg-tschermaks 140 19.616 0.0000E+00 pyrope 18 37.248 0.0000E+00 px-Ca-tschermaks 141 18.610 0.0000E+00 spessartine 19 24.457 0.0000E+00 pyrite 142 -21.247 0.0000E+00 analcite 20 3.322 0.0000E+00 pyrrhotite 143 -4.260 0.0000E+00 andalusite 21 5.002 0.0000E+00 pyrrhotiteFe0.875 144 -6.017 0.0000E+00 andradite 22 39.009 0.0000E+00 pyroxmangite 145 7.399 0.0000E+00 grossular 23 32.731 0.0000E+00 pyrophyllite 146 -6.176 0.0000E+00 anhydrite 24 -5.317 0.0000E+00 quartz 147 -2.989 0.0000E+00 ankerite 25 -2.135 0.0000E+00 rankinite 148 40.713 0.0000E+00 annite 26 20.123 0.0000E+00 ringwoodite-Fe 149 15.456 0.0000E+00 phlogopite 27 27.065 0.0000E+00 ringwoodite-Mg 150 27.575 0.0000E+00 biotite-Mn 28 32.960 0.0000E+00 rhodochrosite 151 -0.976 0.0000E+00 anorthite 29 12.710 0.0000E+00 rhodonite 152 7.446 0.0000E+00 anthophyllite 30 51.852 0.0000E+00 sanidine 153 -1.275 0.0000E+00 anthophyllite-Fe 31 29.306 0.0000E+00 sapphirine(351) 154 78.899 0.0000E+00 apatite-OH 32 -18.153 0.1538E-06 siderite 155 -2.608 0.0000E+00 apatite-OH-zs 33 -12.736 0.0000E+00 sillimanite 156 5.262 0.0000E+00 apatite-Cl-zs 34 -16.674 0.0000E+00 sodalite 157 49.976 0.0000E+00 aragonite 35 0.967 0.0000E+00 spinel 158 20.870 0.0000E+00 brucite 36 12.569 0.0000E+00 spurrite 159 59.482 0.0000E+00 calcite 37 0.812 0.0000E+00 staurolite-Fe 160 73.598 0.0000E+00 carnegieite-low 38 9.023 0.0000E+00 staurolite-Mg 161 89.802 0.0000E+00 carnegieite-high 39 10.093 0.0000E+00 staurolite-Mn 162 83.909 0.0000E+00 carpholite-Mg 40 8.582 0.0000E+00 stilbite 163 -7.522 0.2787E-04 carpholite-Fe 41 6.713 0.0000E+00 stilpnomelane-Fe 164 13.017 0.0000E+00 celadonite 42 5.342 0.0000E+00 stilpnomelane-Mg 165 27.441 0.0000E+00 celadonite-Fe 43 3.877 0.0000E+00 stishovite 166 2.720 0.0000E+00 chrysotile 44 23.892 0.0000E+00 sudoite-Fe 167 18.296 0.0000E+00 chondrodite 45 56.475 0.0000E+00 sudoite 168 21.077 0.0000E+00 clinochlore 46 39.070 0.1253E-04 sulfur 169 -9.152 0.0000E+00 daphnite 47 28.965 0.7762E-05 sylvite 170 1.338 0.0000E+00 chlorite-Mn 48 46.869 0.2654E-06 talc 171 16.491 0.0000E+00 chlorite-Al-free 49 47.173 0.0000E+00 talc-Fe 172 13.448 0.0000E+00 chloritoid-Mg 50 13.198 0.0000E+00 talc-tschermaks 173 19.091 0.0000E+00 chloritoid-Fe 51 9.174 0.0000E+00 tephroite 174 18.086 0.0000E+00 chloritoid-Mn 52 11.401 0.0000E+00 tilleyite 175 41.377 0.0000E+00 clinohumite 53 97.128 0.0000E+00 titanite-CaSi 176 15.479 0.0000E+00 coesite 54 -2.376 0.0000E+00 topaz-H 177 4.618 0.0000E+00 cordierite-H 55 23.715 0.0000E+00 tridymite 178 -2.626 0.0000E+00 cordierite 56 24.049 0.0000E+00 tremolite 179 47.869 0.0000E+00 cordierite-Fe 57 20.450 0.0000E+00 ferroactinolite 180 38.452 0.0000E+00 cordierite-Mn 58 25.066 0.0000E+00 troilite-low 181 -4.411 0.0000E+00 corundum 59 8.383 0.0000E+00 tschermakite 182 48.210 0.0000E+00 corundum-MgSi 60 18.891 0.0000E+00 vesuvianite 183 223.471 0.0000E+00 cristobalite 61 -2.560 0.0000E+00 wadeite-Si 184 20.216 0.0000E+00 cummingtonite 62 52.099 0.0000E+00 wadsleyite-Fe 185 15.680 0.0000E+00 cymrite-K 63 1.685 0.0000E+00 wadsleyite-Mg 186 25.850 0.0000E+00 deerite 64 95.671 0.0000E+00 wairakite 187 3.950 0.0000E+00 diaspore 65 2.874 0.0000E+00 walstromite 188 11.509 0.0000E+00 diamond 66 -3.102 0.0000E+00 wollastonite 189 10.461 0.0000E+00 diopside 67 16.181 0.0000E+00 pseudo-wollastonite 190 11.000 0.0000E+00 hedenbergite 68 14.208 0.0000E+00 zoisite 191 22.849 0.0000E+00 dolomite,ordered 69 0.546 0.0000E+00 akaganeite 192 7.755 0.0000E+00 eastonite 70 28.489 0.0000E+00 beidellite-Ca 193 -1.646 0.0000E+00 enstatite 71 17.265 0.0000E+00 beidellite-H 194 -2.326 0.0000E+00 clinoenstatite-HiP 72 18.354 0.0000E+00 beidellite-K 195 -1.520 0.0000E+00 clinoenstatite 73 17.166 0.0000E+00 beidellite-Mg 196 -1.790 0.0000E+00 protoenstatite 74 17.824 0.0000E+00 beidellite-Na 197 -1.342 0.0000E+00 epidote 75 24.670 0.0000E+00 calcium 198 84.026 0.0000E+00 clinozoisite 76 22.806 0.0000E+00 chalcedony 199 -2.802 0.0000E+00 epidote-Fe 77 29.841 0.0000E+00 dawsonite 200 1.682 0.0000E+00 fayalite 78 14.046 0.0000E+00 montmorillonite-Ca 201 -2.291 0.0000E+00 ferrosilite 79 11.149 0.0000E+00 montmorillonite-K 202 -2.237 0.0000E+00 forsterite 80 21.016 0.0000E+00 montmorillonite-Mg 203 -2.480 0.0000E+00 gedrite 81 50.522 0.0000E+00 montmorillonite-Na 204 -2.038 0.0000E+00 gehlenite 82 36.628 0.0000E+00 nontronite-Ca 205 3.215 0.0000E+00 gibbsite 83 4.079 0.0000E+00 nontronite-H 206 2.533 0.0000E+00 glaucophane 84 22.975 0.0000E+00 nontronite-K 207 3.341 0.0000E+00 glaucophane-Fe 85 17.276 0.0000E+00 nontronite-Mg 208 3.075 0.0000E+00 graphite 86 -3.546 0.0000E+00 nontronite-Na 209 3.520 0.0000E+00 greenalite 87 16.140 0.0000E+00 sepiolite 210 24.118 0.0000E+00 grunerite 88 31.215 0.0000E+00 alite 211 57.999 0.0000E+00 halite 89 1.575 0.0000E+00 belite 212 30.433 0.0000E+00 hematite 90 12.566 0.8758E-05 ettringite 213 43.232 0.0000E+00 heulandite 91 -5.827 0.0000E+00 gypsum 214 -4.955 0.0000E+00 hercynite 92 17.279 0.0000E+00 hemicarboaluminate 215 70.954 0.0000E+00 hollandite 93 25.673 0.0000E+00 hydrogarnet 216 60.662 0.0000E+00 iron 94 19.086 0.0000E+00 hydrogarnet-Si 217 50.586 0.0000E+00 jadeite 95 4.215 0.0000E+00 jennite 218 24.367 0.0000E+00 julgoldite 96 70.427 0.0000E+00 monosulfoaluminate 219 53.400 0.0000E+00 kalsilite 97 7.584 0.0000E+00 monocarboaluminate 220 61.898 0.0000E+00 kaolinite 98 -1.333 0.1297E-04 portlandite 221 18.272 0.0000E+00 kyanite 99 4.876 0.0000E+00 stratlingite 222 36.502 0.0000E+00 larnite-bredigite 100 30.686 0.0000E+00 tricarboaluminate 223 70.370 0.0000E+00 laumontite 101 2.883 0.0000E+00 tobermorite 224 9.823 0.0000E+00 lawsonite 102 9.616 0.6566E-04 C4AH13 225 81.816 0.0000E+00 leucite 103 4.119 0.0000E+00 C2AH8 226 45.203 0.0000E+00 lime 104 25.998 0.0000E+00 C3A 227 86.953 0.0000E+00 lizardite 105 23.244 0.0000E+00 C4AF 228 117.416 0.0000E+00 magnesite 106 0.691 0.0000E+00 CAH10 229 28.335 0.0000E+00 magnetite 107 20.087 0.0000E+00 alabandite 230 -0.978 0.0000E+00 minnesotaite 108 10.388 0.0000E+00 alunite 231 -10.435 0.0000E+00 minnesotaite-Mg 109 20.602 0.0000E+00 artinite 232 15.121 0.0000E+00 magnesioferrite 110 26.212 0.0000E+00 boehmite 233 4.406 0.0000E+00 majorite 111 53.251 0.0000E+00 dolomite,disordered 234 1.247 0.0000E+00 manganosite 112 14.058 0.0000E+00 ferrous-oxide 235 9.812 0.0000E+00 margarite 113 17.324 0.0000E+00 huntite 236 3.770 0.0000E+00 meionite 114 44.874 0.0000E+00 hydromagnesite 237 19.995 0.0000E+00 merwinite 115 55.930 0.0000E+00 nesquehonite 238 4.723 0.0000E+00 microcline 116 -2.486 0.0000E+00 potassium-oxide 239 69.038 0.0000E+00 monticellite 117 24.339 0.0000E+00 silica-amorphous 240 -2.091 0.0000E+00 mullite-Al 118 363.148 0.0000E+00 sodium-oxide 241 55.169 0.0000E+00 mullite-Si 119 7.264 0.0000E+00 an20ab80 242 2.018 0.0000E+00 muscovite 120 2.582 0.0000E+00 an25ab75 243 2.646 0.0000E+00 paragonite 121 4.239 0.0000E+00 an30ab70 244 3.279 0.0000E+00 nepheline 122 8.339 0.0000E+00 tr.625ac.25prg.125 245 45.165 0.0000E+00 osumilite(1) 123 21.717 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.0790000 g log = -1.1024 Original solution: 1000.0103000 g Original solution / Rock added: 12658.36 (Water/Rock Ratio), log = 4.1024 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 greenalite 18 iron 9 lizardite 18 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0790000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3024379E-03 Osmotic coef. = 0.9896 True ionic strength = .3343395E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10885E-07 -7.9632 0.10435E-07 -7.9815 0.95862E+00 -0.0184 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13224E-03 -3.8787 0.95848E+00 -0.0184 4 SO4-- 0.25429E-04 -4.5947 0.22651E-04 -4.6449 0.89073E+00 -0.0503 5 HCO3- 0.12670E-04 -4.8972 0.12144E-04 -4.9156 0.95851E+00 -0.0184 6 HS- 0.50611E-12 -12.2958 0.48509E-12 -12.3142 0.95848E+00 -0.0184 7 Al+++ 0.83216E-21 -21.0798 0.65568E-21 -21.1833 0.78793E+00 -0.1035 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.10868E-04 -4.9639 0.96786E-05 -5.0142 0.89057E+00 -0.0503 10 Mg++ 0.43483E-07 -7.3617 0.38720E-07 -7.4121 0.89047E+00 -0.0504 11 Fe++ 0.25672E-09 -9.5905 0.22861E-09 -9.6409 0.89050E+00 -0.0504 12 K+ 0.16767E-04 -4.7756 0.16071E-04 -4.7940 0.95852E+00 -0.0184 13 Na+ 0.25909E-03 -3.5866 0.24833E-03 -3.6050 0.95848E+00 -0.0184 14 Mn++ 0.33418E-07 -7.4760 0.29759E-07 -7.5264 0.89052E+00 -0.0504 15 HPO4-- 0.51767E-08 -8.2859 0.46110E-08 -8.3362 0.89074E+00 -0.0503 16 HSiO3- 0.34877E-04 -4.4575 0.33429E-04 -4.4759 0.95848E+00 -0.0184 17 Ca(HSiO3)+ 0.76870E-08 -8.1142 0.73682E-08 -8.1326 0.95852E+00 -0.0184 18 Mg(HSiO3)+ 0.38273E-10 -10.4171 0.36685E-10 -10.4355 0.95852E+00 -0.0184 19 NaHSiO3,aq 0.13426E-06 -6.8721 0.13426E-06 -6.8721 0.10000E+01 0.0000 20 AlO+ 0.85467E-12 -12.0682 0.81922E-12 -12.0866 0.95852E+00 -0.0184 21 AlOH+2 0.47798E-16 -16.3206 0.42566E-16 -16.3709 0.89054E+00 -0.0503 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.34605E-05 -5.4609 0.33167E-05 -5.4793 0.95844E+00 -0.0184 24 CH4,aq 0.25267E-18 -18.5975 0.25264E-18 -18.5975 0.99991E+00 0.0000 29 CO,aq 0.31024E-17 -17.5083 0.31024E-17 -17.5083 0.10000E+01 0.0000 30 CO2,aq 0.27080E-06 -6.5673 0.27078E-06 -6.5674 0.99991E+00 0.0000 31 CO3-2 0.11413E-06 -6.9426 0.10165E-06 -6.9929 0.89069E+00 -0.0503 32 CaCO3,aq 0.12337E-07 -7.9088 0.12337E-07 -7.9088 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.31301E-08 -8.5044 0.30003E-08 -8.5228 0.95852E+00 -0.0184 34 CaCl+ 0.21608E-08 -8.6654 0.20712E-08 -8.6838 0.95852E+00 -0.0184 35 CaCl2,aq 0.65070E-13 -13.1866 0.65070E-13 -13.1866 0.10000E+01 0.0000 36 CaOH+ 0.68965E-07 -7.1614 0.66104E-07 -7.1798 0.95852E+00 -0.0184 37 CaSO4,aq 0.69614E-07 -7.1573 0.69614E-07 -7.1573 0.10000E+01 0.0000 38 HCl,aq 0.25285E-12 -12.5971 0.25285E-12 -12.5971 0.10000E+01 0.0000 43 FeCl+ 0.49920E-13 -13.3017 0.47849E-13 -13.3201 0.95852E+00 -0.0184 46 FeO,aq 0.81600E-10 -10.0883 0.81600E-10 -10.0883 0.10000E+01 0.0000 47 FeOH+ 0.74399E-09 -9.1284 0.71314E-09 -9.1468 0.95852E+00 -0.0184 48 HFeO2- 0.85366E-10 -10.0687 0.81821E-10 -10.0871 0.95848E+00 -0.0184 49 FeO+ 0.83094E-13 -13.0804 0.79648E-13 -13.0988 0.95852E+00 -0.0184 50 FeOH+2 0.17823E-18 -18.7490 0.15872E-18 -18.7994 0.89054E+00 -0.0503 51 FeO2- 0.15616E-09 -9.8064 0.14968E-09 -9.8248 0.95848E+00 -0.0184 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45613E-09 -9.3409 0.45609E-09 -9.3410 0.99991E+00 0.0000 54 KCl,aq 0.38517E-10 -10.4143 0.38517E-10 -10.4143 0.10000E+01 0.0000 55 KHSO4,aq 0.10740E-16 -16.9690 0.10740E-16 -16.9690 0.10000E+01 0.0000 56 KOH,aq 0.65773E-09 -9.1820 0.65773E-09 -9.1820 0.10000E+01 0.0000 57 KSO4- 0.58934E-08 -8.2296 0.56487E-08 -8.2481 0.95848E+00 -0.0184 58 MgCO3,aq 0.12371E-10 -10.9076 0.12371E-10 -10.9076 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12796E-10 -10.8929 0.12265E-10 -10.9113 0.95852E+00 -0.0184 60 MgCl+ 0.78350E-11 -11.1060 0.75101E-11 -11.1244 0.95852E+00 -0.0184 61 MgOH+ 0.15267E-08 -8.8162 0.14634E-08 -8.8346 0.95852E+00 -0.0184 63 MnO,aq 0.28304E-09 -9.5482 0.28304E-09 -9.5482 0.10000E+01 0.0000 64 MnOH+ 0.89971E-08 -8.0459 0.86239E-08 -8.0643 0.95852E+00 -0.0184 65 MnO2-2 0.96856E-16 -16.0139 0.86268E-16 -16.0642 0.89069E+00 -0.0503 66 HMnO2- 0.20576E-12 -12.6866 0.19722E-12 -12.7051 0.95848E+00 -0.0184 69 MnCl+ 0.25282E-10 -10.5972 0.24233E-10 -10.6156 0.95852E+00 -0.0184 70 MnSO4,aq 0.19460E-09 -9.7109 0.19460E-09 -9.7109 0.10000E+01 0.0000 71 NaCl,aq 0.10883E-07 -7.9633 0.10883E-07 -7.9633 0.10000E+01 0.0000 72 NaOH,aq 0.10225E-07 -7.9903 0.10225E-07 -7.9903 0.10000E+01 0.0000 74 OH- 0.57771E-04 -4.2383 0.55370E-04 -4.2567 0.95844E+00 -0.0184 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.92603E-09 -9.0334 0.88760E-09 -9.0518 0.95850E+00 -0.0184 84 PO4-3 0.45702E-12 -12.3401 0.36053E-12 -12.4431 0.78889E+00 -0.1030 87 H2P2O7-2 0.69356E-19 -19.1589 0.61774E-19 -19.2092 0.89069E+00 -0.0503 88 HP2O7-3 0.15002E-17 -17.8238 0.11821E-17 -17.9274 0.78794E+00 -0.1035 89 P2O7-4 0.40745E-19 -19.3899 0.27063E-19 -19.5676 0.66419E+00 -0.1777 90 H2S,aq 0.15646E-13 -13.8056 0.15644E-13 -13.8056 0.99991E+00 0.0000 97 SO3-2 0.15067E-14 -14.8220 0.13425E-14 -14.8721 0.89101E+00 -0.0501 98 HSO3- 0.91509E-15 -15.0385 0.87709E-15 -15.0570 0.95848E+00 -0.0184 99 HSO4- 0.23763E-09 -9.6241 0.22778E-09 -9.6425 0.95855E+00 -0.0184 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1088522E-07 -.1066152E-03 -.1074561E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999455E+06 0.0000 3 Cl- 0.1379641E-03 0.1379772E-03 0.4891448E+01 4.1029 4 SO4-- 0.2542909E-04 0.2550496E-04 0.2449918E+01 11.3181 5 HCO3- 0.1266986E-04 0.1307029E-04 0.7974703E+00 3.0659 6 HS- 0.5061062E-12 0.7019429E-10 0.2321343E-05 -4.3327 7 Al+++ 0.8321604E-21 0.3476147E-05 0.9378671E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4085914E-03 0.3926985E+02 -3.4276 9 Ca++ 0.1086777E-04 0.1103166E-04 0.4421036E+00 10.9488 10 Mg++ 0.4348297E-07 0.4508095E-07 0.1095950E-02 8.5510 11 Fe++ 0.2567201E-09 0.1522617E-08 0.8502908E-04 6.3221 12 K+ 0.1676660E-04 0.1677319E-04 0.6558308E+00 3.1876 13 Na+ 0.2590856E-03 0.2592410E-03 0.5959583E+01 4.3765 14 Mn++ 0.3341818E-07 0.4291839E-07 0.2357726E-02 8.4367 15 HPO4-- 0.5176673E-08 0.6103161E-08 0.5857444E-03 7.6268 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1295083E-02 -.1066129E-03 -.1188470E-02 0.0000000E+00 2 H2O 0.5550726E+02 0.5550706E+02 0.2017065E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2769383E-04 0.2550440E-04 0.2189429E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2189359E-05 0.7019275E-10 -.2189429E-05 0.0000000E+00 7 Al+++ 0.2575986E-03 0.3476070E-05 0.2541225E-03 0.0000000E+00 8 H4SiO4 0.8226099E-03 0.4085824E-03 0.4140275E-03 0.0000000E+00 9 Ca++ 0.1053323E-03 0.1103142E-04 0.9430091E-04 0.0000000E+00 10 Mg++ 0.6269841E-04 0.4507996E-07 0.6265333E-04 0.0000000E+00 11 Fe++ 0.5632768E-04 0.1522583E-08 0.5632616E-04 0.0000000E+00 12 K+ 0.1677282E-04 0.1677282E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2592352E-03 0.2592352E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1369749E-05 0.4291744E-07 0.1326832E-05 0.0000000E+00 15 HPO4-- 0.4674886E-06 0.6103027E-08 0.4613855E-06 0.0000000E+00 Chg. balance for solid moles: 0.3193E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1538E-06 -6.813 0.7725E-04 -4.112 0.1337 0.2455E-04 clinochlore 0.1253E-04 -4.902 0.6965E-02 -2.157 12.05 0.2649E-02 daphnite 0.7762E-05 -5.110 0.5538E-02 -2.257 9.584 0.1678E-02 chlorite-Mn 0.2654E-06 -6.576 0.1881E-03 -3.726 0.3256 0.5995E-04 hematite 0.8758E-05 -5.058 0.1399E-02 -2.854 2.420 0.2651E-03 kaolinite 0.1297E-04 -4.887 0.3349E-02 -2.475 5.794 0.1288E-02 lawsonite 0.6566E-04 -4.183 0.2063E-01 -1.685 35.70 0.6654E-02 stilbite 0.2787E-04 -4.555 0.1964E-01 -1.707 33.99 0.9160E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3776E+00 0.3776E+00 1.0000 -0.423 chlorite-Mn 0.1291E-01 0.1291E-01 1.0000 -1.889 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.057790 g Volume = 0.021780 cm3 Porosity: 97.8887% V(tot) - V(min): 0.10098E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0790000 g log = -1.1024 Original solution: 1000.0103000 g Original solution / Rock added: 12658.36 (Water/Rock Ratio), log = 4.1024 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2819E-04 1.0071 0.2897E-04 0.2877E-04 CH4,gas 0.3600E-15 1.0125 0.3719E-15 0.3673E-15 H2,gas 0.5865E-06 1.0005 0.5988E-06 0.5985E-06 H2S,gas 0.4232E-12 0.9960 0.4301E-12 0.4318E-12 S2,gas 0.1898E-31 1.0000 0.1936E-31 0.1936E-31 CO,gas 0.4531E-14 1.0000 0.4623E-14 0.4623E-14 SO3,gas 0.9139E-36 1.0000 0.9325E-36 0.9325E-36 SO2,gas 0.2129E-19 1.0000 0.2172E-19 0.2172E-19 HCl,gas 0.4373E-15 1.0000 0.4462E-15 0.4462E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.18578E-10 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.90 -6.24 -2.079 0.10650E+05 -4.538 3 CH4,gas 4.54 -12.58 -17.13 -4.282 0.29247E+05 -15.430 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13526E+05 -6.223 5 H2S,gas -6.23 -20.30 -14.07 -7.033 0.24016E+05 -12.366 6 S2,gas -7.34 -40.75 -33.41 -5.140 0.57050E+05 -31.713 7 CO,gas 3.21 -12.82 -16.03 -4.934 0.27378E+05 -14.335 8 SO3,gas 17.12 -20.61 -37.73 -9.432 0.64422E+05 -36.030 9 SO2,gas 0.83 -20.53 -21.36 -5.697 0.36475E+05 -19.663 10 HCl,gas 5.19 -11.86 -17.05 -8.525 0.29112E+05 -15.351 11 acmite 7.71 3.80 -3.91 -0.406 0.66682E+04 15 albite-high 0.69 -3.15 -3.84 -0.295 0.65535E+04 16 albite -0.38 -3.15 -2.76 -0.212 0.47147E+04 19 spessartine 24.46 20.55 -3.91 -0.195 0.66724E+04 20 analcite 3.32 0.28 -3.04 -0.338 0.51896E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.66 -4.34 -2.171 0.74144E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.95 -2.91 -0.972 0.49770E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.95 -2.76 -0.920 0.47128E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29425E+04 42 celadonite 5.34 0.79 -4.55 -0.268 0.77730E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12919E+04 52 chloritoid-Mn 11.40 10.53 -0.87 -0.058 0.14848E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64757E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82456E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68784E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.28 -3.93 -0.393 0.67151E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 105 lizardite 23.24 18.80 -4.45 -0.371 0.75917E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20474E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.33 -1.85 -0.142 0.31547E+04 120 muscovite 2.58 1.19 -1.39 -0.082 0.23803E+04 121 paragonite 4.24 2.38 -1.86 -0.110 0.31794E+04 122 nepheline 8.34 3.71 -4.63 -0.661 0.79044E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49713E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.01 -2.39 -0.478 0.40803E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.46 -3.48 -1.161 0.59491E+04 152 rhodonite 7.45 5.01 -2.44 -0.487 0.41605E+04 153 sanidine -1.28 -4.33 -3.06 -0.235 0.52224E+04 155 siderite -2.61 -6.58 -3.97 -1.322 0.67733E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.31 -1.71 -0.051 0.29216E+04 165 stilpnomelane-Mg 27.44 22.45 -4.99 -0.149 0.85225E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83493E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54867E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77667E+04 174 tephroite 18.09 13.45 -4.64 -0.663 0.79229E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.09 -3.57 -0.219 0.61018E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.70 -3.36 -0.206 0.57357E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.23 -2.99 -0.183 0.51033E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.83 -2.80 -0.171 0.47730E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.95 -1.39 -0.089 0.23747E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.34 -1.18 -0.076 0.20104E+04 214 gypsum -4.96 -9.66 -4.70 -1.176 0.80320E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59582E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.59 -2.61 -0.201 0.44576E+04 243 an25ab75 2.65 0.05 -2.60 -0.200 0.44403E+04 244 an30ab70 3.28 0.68 -2.60 -0.200 0.44326E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.0790000 g New total amount of reactant added: 0.0830000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0830000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3042803E-03 Osmotic coef. = 0.9896 True ionic strength = .3376017E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10443E-07 -7.9812 0.10010E-07 -7.9996 0.95851E+00 -0.0184 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13222E-03 -3.8787 0.95837E+00 -0.0185 4 SO4-- 0.25434E-04 -4.5946 0.22645E-04 -4.6450 0.89032E+00 -0.0505 5 HCO3- 0.12677E-04 -4.8970 0.12149E-04 -4.9154 0.95840E+00 -0.0185 6 HS- 0.48505E-12 -12.3142 0.46486E-12 -12.3327 0.95837E+00 -0.0185 7 Al+++ 0.73536E-21 -21.1335 0.57880E-21 -21.2375 0.78710E+00 -0.1040 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.10005E-04 -4.9998 0.89064E-05 -5.0503 0.89016E+00 -0.0505 10 Mg++ 0.40032E-07 -7.3976 0.35631E-07 -7.4482 0.89006E+00 -0.0506 11 Fe++ 0.23633E-09 -9.6265 0.21035E-09 -9.6771 0.89008E+00 -0.0506 12 K+ 0.17616E-04 -4.7541 0.16883E-04 -4.7726 0.95841E+00 -0.0184 13 Na+ 0.26410E-03 -3.5782 0.25310E-03 -3.5967 0.95836E+00 -0.0185 14 Mn++ 0.30875E-07 -7.5104 0.27482E-07 -7.5610 0.89010E+00 -0.0506 15 HPO4-- 0.56281E-08 -8.2496 0.50108E-08 -8.3001 0.89032E+00 -0.0505 16 HSiO3- 0.36361E-04 -4.4394 0.34847E-04 -4.4578 0.95837E+00 -0.0185 17 Ca(HSiO3)+ 0.73749E-08 -8.1322 0.70682E-08 -8.1507 0.95841E+00 -0.0184 18 Mg(HSiO3)+ 0.36718E-10 -10.4351 0.35191E-10 -10.4536 0.95841E+00 -0.0184 19 NaHSiO3,aq 0.14265E-06 -6.8457 0.14265E-06 -6.8457 0.10000E+01 0.0000 20 AlO+ 0.81996E-12 -12.0862 0.78586E-12 -12.1047 0.95841E+00 -0.0184 21 AlOH+2 0.44005E-16 -16.3565 0.39170E-16 -16.4070 0.89012E+00 -0.0505 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.36078E-05 -5.4428 0.34575E-05 -5.4612 0.95832E+00 -0.0185 24 CH4,aq 0.24229E-18 -18.6157 0.24227E-18 -18.6157 0.99991E+00 0.0000 29 CO,aq 0.29767E-17 -17.5263 0.29767E-17 -17.5263 0.10000E+01 0.0000 30 CO2,aq 0.25988E-06 -6.5852 0.25986E-06 -6.5853 0.99991E+00 0.0000 31 CO3-2 0.11908E-06 -6.9242 0.10601E-06 -6.9746 0.89027E+00 -0.0505 32 CaCO3,aq 0.11839E-07 -7.9267 0.11839E-07 -7.9267 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28819E-08 -8.5403 0.27621E-08 -8.5588 0.95841E+00 -0.0184 34 CaCl+ 0.19884E-08 -8.7015 0.19057E-08 -8.7199 0.95841E+00 -0.0184 35 CaCl2,aq 0.59864E-13 -13.2228 0.59864E-13 -13.2228 0.10000E+01 0.0000 36 CaOH+ 0.66164E-07 -7.1794 0.63413E-07 -7.1978 0.95841E+00 -0.0184 37 CaSO4,aq 0.64044E-07 -7.1935 0.64044E-07 -7.1935 0.10000E+01 0.0000 38 HCl,aq 0.24253E-12 -12.6152 0.24253E-12 -12.6152 0.10000E+01 0.0000 43 FeCl+ 0.45933E-13 -13.3379 0.44023E-13 -13.3563 0.95841E+00 -0.0184 46 FeO,aq 0.81592E-10 -10.0884 0.81592E-10 -10.0884 0.10000E+01 0.0000 47 FeOH+ 0.71371E-09 -9.1465 0.68403E-09 -9.1649 0.95841E+00 -0.0184 48 HFeO2- 0.88991E-10 -10.0507 0.85286E-10 -10.0691 0.95837E+00 -0.0185 49 FeO+ 0.79720E-13 -13.0984 0.76405E-13 -13.1169 0.95841E+00 -0.0184 50 FeOH+2 0.16408E-18 -18.7849 0.14606E-18 -18.8355 0.89012E+00 -0.0505 51 FeO2- 0.16281E-09 -9.7883 0.15603E-09 -9.8068 0.95837E+00 -0.0185 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45604E-09 -9.3410 0.45600E-09 -9.3410 0.99991E+00 0.0000 54 KCl,aq 0.40458E-10 -10.3930 0.40458E-10 -10.3930 0.10000E+01 0.0000 55 KHSO4,aq 0.10820E-16 -16.9658 0.10820E-16 -16.9658 0.10000E+01 0.0000 56 KOH,aq 0.72028E-09 -9.1425 0.72028E-09 -9.1425 0.10000E+01 0.0000 57 KSO4- 0.61902E-08 -8.2083 0.59325E-08 -8.2268 0.95837E+00 -0.0185 58 MgCO3,aq 0.11872E-10 -10.9255 0.11872E-10 -10.9255 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11781E-10 -10.9288 0.11291E-10 -10.9473 0.95841E+00 -0.0184 60 MgCl+ 0.72099E-11 -11.1421 0.69100E-11 -11.1605 0.95841E+00 -0.0184 61 MgOH+ 0.14647E-08 -8.8343 0.14038E-08 -8.8527 0.95841E+00 -0.0184 63 MnO,aq 0.28404E-09 -9.5466 0.28404E-09 -9.5466 0.10000E+01 0.0000 64 MnOH+ 0.86622E-08 -8.0624 0.83020E-08 -8.0808 0.95841E+00 -0.0184 65 MnO2-2 0.10567E-15 -15.9760 0.94078E-16 -16.0265 0.89027E+00 -0.0505 66 HMnO2- 0.21528E-12 -12.6670 0.20631E-12 -12.6855 0.95837E+00 -0.0185 69 MnCl+ 0.23347E-10 -10.6318 0.22376E-10 -10.6502 0.95841E+00 -0.0184 70 MnSO4,aq 0.17966E-09 -9.7455 0.17966E-09 -9.7455 0.10000E+01 0.0000 71 NaCl,aq 0.11090E-07 -7.9551 0.11090E-07 -7.9551 0.10000E+01 0.0000 72 NaOH,aq 0.10864E-07 -7.9640 0.10864E-07 -7.9640 0.10000E+01 0.0000 74 OH- 0.60230E-04 -4.2202 0.57720E-04 -4.2387 0.95832E+00 -0.0185 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.96545E-09 -9.0153 0.92527E-09 -9.0337 0.95839E+00 -0.0185 84 PO4-3 0.51825E-12 -12.2855 0.40842E-12 -12.3889 0.78807E+00 -0.1034 87 H2P2O7-2 0.75403E-19 -19.1226 0.67130E-19 -19.1731 0.89027E+00 -0.0505 88 HP2O7-3 0.17013E-17 -17.7692 0.13391E-17 -17.8732 0.78711E+00 -0.1040 89 P2O7-4 0.48206E-19 -19.3169 0.31959E-19 -19.4954 0.66297E+00 -0.1785 90 H2S,aq 0.14383E-13 -13.8422 0.14381E-13 -13.8422 0.99991E+00 0.0000 97 SO3-2 0.15067E-14 -14.8220 0.13419E-14 -14.8723 0.89060E+00 -0.0503 98 HSO3- 0.87754E-15 -15.0567 0.84100E-15 -15.0752 0.95837E+00 -0.0185 99 HSO4- 0.22792E-09 -9.6422 0.21845E-09 -9.6607 0.95844E+00 -0.0184 Charge balance for all species = 0.7205E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1044319E-07 -.1111698E-03 -.1120465E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999453E+06 0.0000 3 Cl- 0.1379642E-03 0.1379773E-03 0.4891451E+01 4.1209 4 SO4-- 0.2543441E-04 0.2550498E-04 0.2449919E+01 11.3541 5 HCO3- 0.1267659E-04 0.1307030E-04 0.7974707E+00 3.0841 6 HS- 0.4850501E-12 0.6931910E-10 0.2292400E-05 -4.3331 7 Al+++ 0.7353575E-21 0.3623457E-05 0.9776113E-01 2.7612 8 H4SiO4 0.3735728E-03 0.4100841E-03 0.3941331E+02 -3.4276 9 Ca++ 0.1000539E-04 0.1015968E-04 0.4071581E+00 10.9488 10 Mg++ 0.4003200E-07 0.4156427E-07 0.1010457E-02 8.5510 11 Fe++ 0.2363258E-09 0.1482198E-08 0.8277191E-04 6.3221 12 K+ 0.1761553E-04 0.1762248E-04 0.6890377E+00 3.2270 13 Na+ 0.2640976E-03 0.2642622E-03 0.6075014E+01 4.4029 14 Mn++ 0.3087508E-07 0.4002457E-07 0.2198753E-02 8.4382 15 HPO4-- 0.5628074E-08 0.6594043E-08 0.6328560E-03 7.6990 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1361317E-02 -.1111672E-03 -.1250150E-02 0.0000000E+00 2 H2O 0.5550721E+02 0.5550702E+02 0.1934785E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2780468E-04 0.2550440E-04 0.2300282E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2300213E-05 0.6931752E-10 -.2300282E-05 0.0000000E+00 7 Al+++ 0.2706416E-03 0.3623375E-05 0.2670182E-03 0.0000000E+00 8 H4SiO4 0.8642610E-03 0.4100747E-03 0.4541862E-03 0.0000000E+00 9 Ca++ 0.1099329E-03 0.1015945E-04 0.9977345E-04 0.0000000E+00 10 Mg++ 0.6587302E-04 0.4156332E-07 0.6583145E-04 0.0000000E+00 11 Fe++ 0.5917971E-04 0.1482164E-08 0.5917823E-04 0.0000000E+00 12 K+ 0.1762208E-04 0.1762208E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2642562E-03 0.2642562E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1439103E-05 0.4002366E-07 0.1399080E-05 0.0000000E+00 15 HPO4-- 0.4911589E-06 0.6593892E-08 0.4845650E-06 0.0000000E+00 Chg. balance for solid moles: 0.1969E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0830000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1615E-06 -6.792 0.8114E-04 -4.091 0.1303 0.2578E-04 clinochlore 0.1317E-04 -4.881 0.7318E-02 -2.136 11.76 0.2784E-02 daphnite 0.8155E-05 -5.089 0.5819E-02 -2.235 9.347 0.1763E-02 chlorite-Mn 0.2798E-06 -6.553 0.1984E-03 -3.702 0.3187 0.6322E-04 hematite 0.9201E-05 -5.036 0.1469E-02 -2.833 2.360 0.2785E-03 kaolinite 0.1294E-04 -4.888 0.3341E-02 -2.476 5.367 0.1286E-02 lawsonite 0.6585E-04 -4.181 0.2069E-01 -1.684 33.24 0.6673E-02 stilbite 0.3311E-04 -4.480 0.2334E-01 -1.632 37.48 0.1088E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3775E+00 0.3775E+00 1.0000 -0.423 chlorite-Mn 0.1295E-01 0.1295E-01 1.0000 -1.888 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.062256 g Volume = 0.023757 cm3 Porosity: 97.7006% V(tot) - V(min): 0.10094E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0830000 g log = -1.0809 Original solution: 1000.0103000 g Original solution / Rock added: 12048.32 (Water/Rock Ratio), log = 4.0809 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2706E-04 1.0071 0.2780E-04 0.2761E-04 CH4,gas 0.3452E-15 1.0125 0.3566E-15 0.3522E-15 H2,gas 0.5864E-06 1.0005 0.5987E-06 0.5983E-06 H2S,gas 0.3890E-12 0.9960 0.3953E-12 0.3969E-12 S2,gas 0.1604E-31 1.0000 0.1637E-31 0.1637E-31 CO,gas 0.4348E-14 1.0000 0.4436E-14 0.4436E-14 SO3,gas 0.8408E-36 1.0000 0.8579E-36 0.8579E-36 SO2,gas 0.1958E-19 1.0000 0.1998E-19 0.1998E-19 HCl,gas 0.4194E-15 1.0000 0.4279E-15 0.4279E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.21232E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.92 -6.25 -2.085 0.10680E+05 -4.556 3 CH4,gas 4.54 -12.60 -17.15 -4.287 0.29278E+05 -15.448 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13526E+05 -6.223 5 H2S,gas -6.23 -20.33 -14.10 -7.051 0.24079E+05 -12.403 6 S2,gas -7.34 -40.82 -33.48 -5.152 0.57175E+05 -31.786 7 CO,gas 3.21 -12.84 -16.05 -4.939 0.27408E+05 -14.353 8 SO3,gas 17.12 -20.64 -37.77 -9.441 0.64484E+05 -36.067 9 SO2,gas 0.83 -20.57 -21.40 -5.706 0.36537E+05 -19.699 10 HCl,gas 5.19 -11.88 -17.07 -8.534 0.29142E+05 -15.369 11 acmite 7.71 3.83 -3.88 -0.403 0.66233E+04 15 albite-high 0.69 -3.12 -3.81 -0.293 0.65086E+04 16 albite -0.38 -3.12 -2.73 -0.210 0.46698E+04 19 spessartine 24.46 20.55 -3.90 -0.195 0.66646E+04 20 analcite 3.32 0.31 -3.01 -0.335 0.51446E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.70 -4.38 -2.189 0.74762E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.97 -2.93 -0.978 0.50075E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68599E+04 37 calcite 0.81 -1.97 -2.78 -0.926 0.47433E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29425E+04 42 celadonite 5.34 0.83 -4.51 -0.265 0.77056E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12920E+04 52 chloritoid-Mn 11.40 10.53 -0.87 -0.058 0.14821E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64758E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82457E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68786E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.31 -3.91 -0.391 0.66701E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.87 -4.99 -0.499 0.85132E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75918E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20475E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.29 -1.81 -0.139 0.30873E+04 120 muscovite 2.58 1.23 -1.35 -0.080 0.23129E+04 121 paragonite 4.24 2.40 -1.84 -0.108 0.31344E+04 122 nepheline 8.34 3.74 -4.60 -0.658 0.78595E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49714E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.01 -2.39 -0.478 0.40776E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.48 -3.50 -1.167 0.59770E+04 152 rhodonite 7.45 5.01 -2.44 -0.487 0.41579E+04 153 sanidine -1.28 -4.29 -3.02 -0.232 0.51551E+04 155 siderite -2.61 -6.59 -3.98 -1.328 0.68039E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.33 -1.69 -0.050 0.28883E+04 165 stilpnomelane-Mg 27.44 22.47 -4.97 -0.148 0.84888E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83495E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54867E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77667E+04 174 tephroite 18.09 13.45 -4.64 -0.662 0.79176E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.08 -3.56 -0.218 0.60795E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.69 -3.35 -0.205 0.57209E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.21 -2.98 -0.182 0.50811E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.82 -2.79 -0.171 0.47582E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.96 -1.38 -0.088 0.23525E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.35 -1.17 -0.075 0.19956E+04 214 gypsum -4.96 -9.70 -4.74 -1.185 0.80938E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59582E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.57 -2.59 -0.199 0.44216E+04 243 an25ab75 2.65 0.06 -2.58 -0.199 0.44066E+04 244 an30ab70 3.28 0.70 -2.58 -0.198 0.44011E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.0830000 g New total amount of reactant added: 0.0870000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0870000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3062959E-03 Osmotic coef. = 0.9895 True ionic strength = .3410847E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10022E-07 -7.9991 0.96047E-08 -8.0175 0.95839E+00 -0.0185 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13220E-03 -3.8788 0.95825E+00 -0.0185 4 SO4-- 0.25439E-04 -4.5945 0.22638E-04 -4.6452 0.88988E+00 -0.0507 5 HCO3- 0.12683E-04 -4.8968 0.12154E-04 -4.9153 0.95828E+00 -0.0185 6 HS- 0.46502E-12 -12.3325 0.44560E-12 -12.3511 0.95825E+00 -0.0185 7 Al+++ 0.65035E-21 -21.1869 0.51132E-21 -21.2913 0.78623E+00 -0.1044 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.92163E-05 -5.0354 0.82000E-05 -5.0862 0.88972E+00 -0.0507 10 Mg++ 0.36875E-07 -7.4333 0.32804E-07 -7.4841 0.88962E+00 -0.0508 11 Fe++ 0.21767E-09 -9.6622 0.19365E-09 -9.7130 0.88964E+00 -0.0508 12 K+ 0.18464E-04 -4.7337 0.17694E-04 -4.7522 0.95829E+00 -0.0185 13 Na+ 0.26911E-03 -3.5701 0.25787E-03 -3.5886 0.95825E+00 -0.0185 14 Mn++ 0.28527E-07 -7.5447 0.25380E-07 -7.5955 0.88966E+00 -0.0508 15 HPO4-- 0.61159E-08 -8.2135 0.54425E-08 -8.2642 0.88989E+00 -0.0507 16 HSiO3- 0.37900E-04 -4.4214 0.36317E-04 -4.4399 0.95825E+00 -0.0185 17 Ca(HSiO3)+ 0.70772E-08 -8.1501 0.67821E-08 -8.1686 0.95830E+00 -0.0185 18 Mg(HSiO3)+ 0.35236E-10 -10.4530 0.33766E-10 -10.4715 0.95830E+00 -0.0185 19 NaHSiO3,aq 0.15147E-06 -6.8197 0.15147E-06 -6.8197 0.10000E+01 0.0000 20 AlO+ 0.78687E-12 -12.1041 0.75405E-12 -12.1226 0.95830E+00 -0.0185 21 AlOH+2 0.40535E-16 -16.3922 0.36063E-16 -16.4429 0.88968E+00 -0.0508 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.37605E-05 -5.4248 0.36033E-05 -5.4433 0.95820E+00 -0.0185 24 CH4,aq 0.23241E-18 -18.6338 0.23238E-18 -18.6338 0.99990E+00 0.0000 29 CO,aq 0.28567E-17 -17.5441 0.28567E-17 -17.5441 0.10000E+01 0.0000 30 CO2,aq 0.24945E-06 -6.6030 0.24943E-06 -6.6031 0.99990E+00 0.0000 31 CO3-2 0.12421E-06 -6.9058 0.11052E-06 -6.9565 0.88983E+00 -0.0507 32 CaCO3,aq 0.11364E-07 -7.9445 0.11364E-07 -7.9445 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.26546E-08 -8.5760 0.25439E-08 -8.5945 0.95830E+00 -0.0185 34 CaCl+ 0.18307E-08 -8.7374 0.17544E-08 -8.7559 0.95830E+00 -0.0185 35 CaCl2,aq 0.55103E-13 -13.2588 0.55103E-13 -13.2588 0.10000E+01 0.0000 36 CaOH+ 0.63494E-07 -7.1973 0.60846E-07 -7.2158 0.95830E+00 -0.0185 37 CaSO4,aq 0.58946E-07 -7.2295 0.58946E-07 -7.2295 0.10000E+01 0.0000 38 HCl,aq 0.23268E-12 -12.6332 0.23268E-12 -12.6332 0.10000E+01 0.0000 43 FeCl+ 0.42286E-13 -13.3738 0.40522E-13 -13.3923 0.95830E+00 -0.0185 46 FeO,aq 0.81585E-10 -10.0884 0.81585E-10 -10.0884 0.10000E+01 0.0000 47 FeOH+ 0.68485E-09 -9.1644 0.65629E-09 -9.1829 0.95830E+00 -0.0185 48 HFeO2- 0.92748E-10 -10.0327 0.88876E-10 -10.0512 0.95825E+00 -0.0185 49 FeO+ 0.76503E-13 -13.1163 0.73312E-13 -13.1348 0.95830E+00 -0.0185 50 FeOH+2 0.15114E-18 -18.8206 0.13447E-18 -18.8714 0.88968E+00 -0.0508 51 FeO2- 0.16970E-09 -9.7703 0.16261E-09 -9.7888 0.95825E+00 -0.0185 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45596E-09 -9.3411 0.45592E-09 -9.3411 0.99990E+00 0.0000 54 KCl,aq 0.42397E-10 -10.3727 0.42397E-10 -10.3727 0.10000E+01 0.0000 55 KHSO4,aq 0.10878E-16 -16.9635 0.10878E-16 -16.9635 0.10000E+01 0.0000 56 KOH,aq 0.78674E-09 -9.1042 0.78674E-09 -9.1042 0.10000E+01 0.0000 57 KSO4- 0.64866E-08 -8.1880 0.62158E-08 -8.2065 0.95825E+00 -0.0185 58 MgCO3,aq 0.11395E-10 -10.9433 0.11395E-10 -10.9433 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10852E-10 -10.9645 0.10399E-10 -10.9830 0.95830E+00 -0.0185 60 MgCl+ 0.66379E-11 -11.1780 0.63611E-11 -11.1965 0.95830E+00 -0.0185 61 MgOH+ 0.14056E-08 -8.8522 0.13469E-08 -8.8707 0.95830E+00 -0.0185 63 MnO,aq 0.28491E-09 -9.5453 0.28491E-09 -9.5453 0.10000E+01 0.0000 64 MnOH+ 0.83381E-08 -8.0789 0.79903E-08 -8.0974 0.95830E+00 -0.0185 65 MnO2-2 0.11518E-15 -15.9386 0.10250E-15 -15.9893 0.88983E+00 -0.0507 66 HMnO2- 0.22507E-12 -12.6477 0.21568E-12 -12.6662 0.95825E+00 -0.0185 69 MnCl+ 0.21561E-10 -10.6663 0.20662E-10 -10.6848 0.95830E+00 -0.0185 70 MnSO4,aq 0.16587E-09 -9.7802 0.16587E-09 -9.7802 0.10000E+01 0.0000 71 NaCl,aq 0.11298E-07 -7.9470 0.11298E-07 -7.9470 0.10000E+01 0.0000 72 NaOH,aq 0.11535E-07 -7.9380 0.11535E-07 -7.9380 0.10000E+01 0.0000 74 OH- 0.62779E-04 -4.2022 0.60155E-04 -4.2207 0.95820E+00 -0.0185 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.10063E-08 -8.9973 0.96431E-09 -9.0158 0.95827E+00 -0.0185 84 PO4-3 0.58729E-12 -12.2311 0.46232E-12 -12.3351 0.78721E+00 -0.1039 87 H2P2O7-2 0.81940E-19 -19.0865 0.72913E-19 -19.1372 0.88983E+00 -0.0507 88 HP2O7-3 0.19279E-17 -17.7149 0.15158E-17 -17.8194 0.78624E+00 -0.1044 89 P2O7-4 0.56981E-19 -19.2443 0.37702E-19 -19.4236 0.66166E+00 -0.1794 90 H2S,aq 0.13229E-13 -13.8785 0.13228E-13 -13.8785 0.99990E+00 0.0000 97 SO3-2 0.15067E-14 -14.8220 0.13412E-14 -14.8725 0.89016E+00 -0.0505 98 HSO3- 0.84172E-15 -15.0748 0.80658E-15 -15.0934 0.95825E+00 -0.0185 99 HSO4- 0.21866E-09 -9.6602 0.20954E-09 -9.6787 0.95832E+00 -0.0185 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1002170E-07 -.1158893E-03 -.1168032E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999450E+06 0.0000 3 Cl- 0.1379642E-03 0.1379774E-03 0.4891453E+01 4.1388 4 SO4-- 0.2543925E-04 0.2550500E-04 0.2449921E+01 11.3899 5 HCO3- 0.1268261E-04 0.1307031E-04 0.7974711E+00 3.1022 6 HS- 0.4650183E-12 0.6841790E-10 0.2262596E-05 -4.3335 7 Al+++ 0.6503482E-21 0.3776120E-05 0.1018800E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4116312E-03 0.3956199E+02 -3.4276 9 Ca++ 0.9216345E-05 0.9361711E-05 0.3751787E+00 10.9488 10 Mg++ 0.3687458E-07 0.3834426E-07 0.9321759E-03 8.5510 11 Fe++ 0.2176704E-09 0.1445312E-08 0.8071206E-04 6.3220 12 K+ 0.1846446E-04 0.1847177E-04 0.7222447E+00 3.2653 13 Na+ 0.2691092E-03 0.2692835E-03 0.6190445E+01 4.4289 14 Mn++ 0.2852723E-07 0.3733784E-07 0.2051157E-02 8.4395 15 HPO4-- 0.6115935E-08 0.7122824E-08 0.6836051E-03 7.7708 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1427551E-02 -.1158866E-03 -.1311664E-02 0.0000000E+00 2 H2O 0.5550716E+02 0.5550697E+02 0.1852222E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2791554E-04 0.2550440E-04 0.2411135E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2411067E-05 0.6841629E-10 -.2411135E-05 0.0000000E+00 7 Al+++ 0.2836845E-03 0.3776031E-05 0.2799085E-03 0.0000000E+00 8 H4SiO4 0.9059121E-03 0.4116215E-03 0.4942906E-03 0.0000000E+00 9 Ca++ 0.1145335E-03 0.9361491E-05 0.1051720E-03 0.0000000E+00 10 Mg++ 0.6904762E-04 0.3834335E-07 0.6900928E-04 0.0000000E+00 11 Fe++ 0.6203175E-04 0.1445278E-08 0.6203030E-04 0.0000000E+00 12 K+ 0.1847134E-04 0.1847134E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2692772E-03 0.2692772E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1508458E-05 0.3733696E-07 0.1471121E-05 0.0000000E+00 15 HPO4-- 0.5148292E-06 0.7122657E-08 0.5077065E-06 0.0000000E+00 Chg. balance for solid moles: -.1609E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0870000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1692E-06 -6.772 0.8501E-04 -4.071 0.1274 0.2701E-04 clinochlore 0.1380E-04 -4.860 0.7671E-02 -2.115 11.50 0.2918E-02 daphnite 0.8548E-05 -5.068 0.6099E-02 -2.215 9.142 0.1848E-02 chlorite-Mn 0.2942E-06 -6.531 0.2086E-03 -3.681 0.3127 0.6647E-04 hematite 0.9645E-05 -5.016 0.1540E-02 -2.812 2.309 0.2919E-03 kaolinite 0.1298E-04 -4.887 0.3352E-02 -2.475 5.024 0.1290E-02 lawsonite 0.6598E-04 -4.181 0.2073E-01 -1.683 31.08 0.6686E-02 stilbite 0.3835E-04 -4.416 0.2702E-01 -1.568 40.51 0.1260E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3775E+00 0.3775E+00 1.0000 -0.423 chlorite-Mn 0.1299E-01 0.1299E-01 1.0000 -1.886 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.066714 g Volume = 0.025732 cm3 Porosity: 97.5133% V(tot) - V(min): 0.10091E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0870000 g log = -1.0605 Original solution: 1000.0103000 g Original solution / Rock added: 11494.37 (Water/Rock Ratio), log = 4.0605 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2597E-04 1.0071 0.2669E-04 0.2650E-04 CH4,gas 0.3311E-15 1.0125 0.3421E-15 0.3378E-15 H2,gas 0.5863E-06 1.0005 0.5986E-06 0.5982E-06 H2S,gas 0.3578E-12 0.9960 0.3636E-12 0.3651E-12 S2,gas 0.1358E-31 1.0000 0.1385E-31 0.1385E-31 CO,gas 0.4172E-14 1.0000 0.4257E-14 0.4257E-14 SO3,gas 0.7739E-36 1.0000 0.7896E-36 0.7896E-36 SO2,gas 0.1802E-19 1.0000 0.1839E-19 0.1839E-19 HCl,gas 0.4024E-15 1.0000 0.4106E-15 0.4106E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.93 -6.27 -2.091 0.10710E+05 -4.574 3 CH4,gas 4.54 -12.62 -17.16 -4.291 0.29309E+05 -15.466 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13526E+05 -6.223 5 H2S,gas -6.23 -20.37 -14.14 -7.069 0.24141E+05 -12.439 6 S2,gas -7.34 -40.89 -33.56 -5.163 0.57298E+05 -31.858 7 CO,gas 3.21 -12.85 -16.07 -4.945 0.27439E+05 -14.371 8 SO3,gas 17.12 -20.68 -37.80 -9.450 0.64545E+05 -36.103 9 SO2,gas 0.83 -20.60 -21.43 -5.716 0.36599E+05 -19.735 10 HCl,gas 5.19 -11.90 -17.09 -8.543 0.29173E+05 -15.387 11 acmite 7.71 3.86 -3.85 -0.400 0.65788E+04 15 albite-high 0.69 -3.09 -3.79 -0.291 0.64641E+04 16 albite -0.38 -3.09 -2.71 -0.208 0.46253E+04 19 spessartine 24.46 20.56 -3.90 -0.195 0.66578E+04 20 analcite 3.32 0.33 -2.99 -0.332 0.51001E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.73 -4.41 -2.207 0.75377E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -1.98 -2.95 -0.983 0.50379E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -1.98 -2.80 -0.932 0.47737E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29426E+04 42 celadonite 5.34 0.87 -4.47 -0.263 0.76402E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12921E+04 52 chloritoid-Mn 11.40 10.53 -0.87 -0.058 0.14799E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64758E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82458E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68788E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.33 -3.88 -0.388 0.66256E+04 97 kalsilite 7.58 2.60 -4.98 -0.712 0.85117E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.83 -4.95 -0.495 0.84478E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75918E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20475E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.26 -1.77 -0.136 0.30219E+04 120 muscovite 2.58 1.27 -1.32 -0.077 0.22474E+04 121 paragonite 4.24 2.43 -1.81 -0.106 0.30900E+04 122 nepheline 8.34 3.76 -4.58 -0.654 0.78150E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49714E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.01 -2.39 -0.477 0.40754E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.49 -3.52 -1.172 0.60051E+04 152 rhodonite 7.45 5.01 -2.43 -0.487 0.41556E+04 153 sanidine -1.28 -4.26 -2.98 -0.229 0.50896E+04 155 siderite -2.61 -6.61 -4.00 -1.334 0.68344E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.34 -1.67 -0.050 0.28559E+04 165 stilpnomelane-Mg 27.44 22.49 -4.95 -0.148 0.84562E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83496E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54867E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77668E+04 174 tephroite 18.09 13.45 -4.63 -0.662 0.79131E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.07 -3.55 -0.217 0.60579E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.68 -3.34 -0.205 0.57062E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.20 -2.96 -0.181 0.50595E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.82 -2.78 -0.170 0.47435E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.98 -1.37 -0.088 0.23309E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.36 -1.16 -0.074 0.19809E+04 214 gypsum -4.96 -9.73 -4.78 -1.194 0.81553E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59583E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.55 -2.57 -0.198 0.43860E+04 243 an25ab75 2.65 0.08 -2.56 -0.197 0.43732E+04 244 an30ab70 3.28 0.72 -2.56 -0.197 0.43700E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.0870000 g New total amount of reactant added: 0.0910000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0910000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3084740E-03 Osmotic coef. = 0.9895 True ionic strength = .3447751E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.96209E-08 -8.0168 0.92194E-08 -8.0353 0.95827E+00 -0.0185 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13219E-03 -3.8788 0.95812E+00 -0.0186 4 SO4-- 0.25444E-04 -4.5944 0.22630E-04 -4.6453 0.88942E+00 -0.0509 5 HCO3- 0.12688E-04 -4.8966 0.12157E-04 -4.9152 0.95816E+00 -0.0186 6 HS- 0.44600E-12 -12.3507 0.42733E-12 -12.3692 0.95813E+00 -0.0186 7 Al+++ 0.57585E-21 -21.2397 0.45222E-21 -21.3447 0.78531E+00 -0.1050 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.84961E-05 -5.0708 0.75552E-05 -5.1218 0.88926E+00 -0.0510 10 Mg++ 0.33993E-07 -7.4686 0.30225E-07 -7.5196 0.88916E+00 -0.0510 11 Fe++ 0.20065E-09 -9.6976 0.17841E-09 -9.7486 0.88918E+00 -0.0510 12 K+ 0.19313E-04 -4.7141 0.18505E-04 -4.7327 0.95817E+00 -0.0186 13 Na+ 0.27412E-03 -3.5621 0.26264E-03 -3.5806 0.95812E+00 -0.0186 14 Mn++ 0.26368E-07 -7.5789 0.23446E-07 -7.6299 0.88920E+00 -0.0510 15 HPO4-- 0.66413E-08 -8.1777 0.59069E-08 -8.2286 0.88942E+00 -0.0509 16 HSiO3- 0.39489E-04 -4.4035 0.37835E-04 -4.4221 0.95812E+00 -0.0186 17 Ca(HSiO3)+ 0.67942E-08 -8.1679 0.65100E-08 -8.1864 0.95817E+00 -0.0186 18 Mg(HSiO3)+ 0.33826E-10 -10.4707 0.32411E-10 -10.4893 0.95817E+00 -0.0186 19 NaHSiO3,aq 0.16072E-06 -6.7939 0.16072E-06 -6.7939 0.10000E+01 0.0000 20 AlO+ 0.75540E-12 -12.1218 0.72380E-12 -12.1404 0.95817E+00 -0.0186 21 AlOH+2 0.37367E-16 -16.4275 0.33228E-16 -16.4785 0.88922E+00 -0.0510 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.39182E-05 -5.4069 0.37539E-05 -5.4255 0.95808E+00 -0.0186 24 CH4,aq 0.22302E-18 -18.6517 0.22299E-18 -18.6517 0.99990E+00 0.0000 29 CO,aq 0.27425E-17 -17.5619 0.27425E-17 -17.5619 0.10000E+01 0.0000 30 CO2,aq 0.23951E-06 -6.6207 0.23949E-06 -6.6207 0.99990E+00 0.0000 31 CO3-2 0.12950E-06 -6.8877 0.11518E-06 -6.9386 0.88937E+00 -0.0509 32 CaCO3,aq 0.10911E-07 -7.9621 0.10911E-07 -7.9621 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.24469E-08 -8.6114 0.23445E-08 -8.6299 0.95817E+00 -0.0186 34 CaCl+ 0.16868E-08 -8.7729 0.16162E-08 -8.7915 0.95817E+00 -0.0186 35 CaCl2,aq 0.50757E-13 -13.2945 0.50757E-13 -13.2945 0.10000E+01 0.0000 36 CaOH+ 0.60954E-07 -7.2150 0.58405E-07 -7.2336 0.95817E+00 -0.0186 37 CaSO4,aq 0.54293E-07 -7.2653 0.54293E-07 -7.2653 0.10000E+01 0.0000 38 HCl,aq 0.22332E-12 -12.6511 0.22332E-12 -12.6511 0.10000E+01 0.0000 43 FeCl+ 0.38958E-13 -13.4094 0.37329E-13 -13.4280 0.95817E+00 -0.0186 46 FeO,aq 0.81579E-10 -10.0884 0.81579E-10 -10.0884 0.10000E+01 0.0000 47 FeOH+ 0.65741E-09 -9.1822 0.62991E-09 -9.2007 0.95817E+00 -0.0186 48 HFeO2- 0.96630E-10 -10.0149 0.92584E-10 -10.0335 0.95812E+00 -0.0186 49 FeO+ 0.73443E-13 -13.1341 0.70371E-13 -13.1526 0.95817E+00 -0.0186 50 FeOH+2 0.13933E-18 -18.8559 0.12390E-18 -18.9069 0.88922E+00 -0.0510 51 FeO2- 0.17681E-09 -9.7525 0.16941E-09 -9.7711 0.95812E+00 -0.0186 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45590E-09 -9.3411 0.45585E-09 -9.3412 0.99990E+00 0.0000 54 KCl,aq 0.44335E-10 -10.3533 0.44335E-10 -10.3533 0.10000E+01 0.0000 55 KHSO4,aq 0.10916E-16 -16.9619 0.10916E-16 -16.9619 0.10000E+01 0.0000 56 KOH,aq 0.85720E-09 -9.0669 0.85720E-09 -9.0669 0.10000E+01 0.0000 57 KSO4- 0.67825E-08 -8.1686 0.64985E-08 -8.1872 0.95812E+00 -0.0186 58 MgCO3,aq 0.10941E-10 -10.9609 0.10941E-10 -10.9609 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10002E-10 -10.9999 0.95840E-11 -11.0185 0.95817E+00 -0.0186 60 MgCl+ 0.61159E-11 -11.2135 0.58601E-11 -11.2321 0.95817E+00 -0.0186 61 MgOH+ 0.13493E-08 -8.8699 0.12929E-08 -8.8884 0.95817E+00 -0.0186 63 MnO,aq 0.28566E-09 -9.5441 0.28566E-09 -9.5441 0.10000E+01 0.0000 64 MnOH+ 0.80258E-08 -8.0955 0.76901E-08 -8.1141 0.95817E+00 -0.0186 65 MnO2-2 0.12541E-15 -15.9017 0.11154E-15 -15.9526 0.88937E+00 -0.0509 66 HMnO2- 0.23513E-12 -12.6287 0.22529E-12 -12.6473 0.95812E+00 -0.0186 69 MnCl+ 0.19918E-10 -10.7007 0.19085E-10 -10.7193 0.95817E+00 -0.0186 70 MnSO4,aq 0.15318E-09 -9.8148 0.15318E-09 -9.8148 0.10000E+01 0.0000 71 NaCl,aq 0.11505E-07 -7.9391 0.11505E-07 -7.9391 0.10000E+01 0.0000 72 NaOH,aq 0.12240E-07 -7.9122 0.12240E-07 -7.9122 0.10000E+01 0.0000 74 OH- 0.65411E-04 -4.1843 0.62669E-04 -4.2029 0.95808E+00 -0.0186 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.10485E-08 -8.9794 0.10046E-08 -8.9980 0.95815E+00 -0.0186 84 PO4-3 0.66482E-12 -12.1773 0.52275E-12 -12.2817 0.78630E+00 -0.1044 87 H2P2O7-2 0.88978E-19 -19.0507 0.79135E-19 -19.1016 0.88937E+00 -0.0509 88 HP2O7-3 0.21824E-17 -17.6611 0.17139E-17 -17.7660 0.78532E+00 -0.1050 89 P2O7-4 0.67260E-19 -19.1722 0.44412E-19 -19.3525 0.66030E+00 -0.1803 90 H2S,aq 0.12177E-13 -13.9144 0.12176E-13 -13.9145 0.99990E+00 0.0000 97 SO3-2 0.15068E-14 -14.8220 0.13406E-14 -14.8727 0.88970E+00 -0.0508 98 HSO3- 0.80766E-15 -15.0928 0.77384E-15 -15.1113 0.95812E+00 -0.0186 99 HSO4- 0.20984E-09 -9.6781 0.20107E-09 -9.6967 0.95819E+00 -0.0185 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9620883E-08 -.1207637E-03 -.1217160E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999448E+06 0.0000 3 Cl- 0.1379643E-03 0.1379775E-03 0.4891455E+01 4.1565 4 SO4-- 0.2544365E-04 0.2550502E-04 0.2449922E+01 11.4253 5 HCO3- 0.1268792E-04 0.1307032E-04 0.7974714E+00 3.1201 6 HS- 0.4460046E-12 0.6749211E-10 0.2231979E-05 -4.3339 7 Al+++ 0.5758453E-21 0.3933805E-05 0.1061343E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4132294E-03 0.3971558E+02 -3.4276 9 Ca++ 0.8496095E-05 0.8633181E-05 0.3459821E+00 10.9488 10 Mg++ 0.3399252E-07 0.3540274E-07 0.8606652E-03 8.5510 11 Fe++ 0.2006451E-09 0.1411834E-08 0.7884247E-04 6.3220 12 K+ 0.1931338E-04 0.1932106E-04 0.7554518E+00 3.3026 13 Na+ 0.2741204E-03 0.2743048E-03 0.6305875E+01 4.4547 14 Mn++ 0.2636767E-07 0.3485248E-07 0.1914623E-02 8.4407 15 HPO4-- 0.6641297E-08 0.7690460E-08 0.7380831E-03 7.8420 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1493785E-02 -.1207607E-03 -.1373024E-02 0.0000000E+00 2 H2O 0.5550711E+02 0.5550693E+02 0.1769395E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2802639E-04 0.2550440E-04 0.2521988E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2521920E-05 0.6749046E-10 -.2521988E-05 0.0000000E+00 7 Al+++ 0.2967275E-03 0.3933710E-05 0.2927938E-03 0.0000000E+00 8 H4SiO4 0.9475632E-03 0.4132193E-03 0.5343439E-03 0.0000000E+00 9 Ca++ 0.1191340E-03 0.8632971E-05 0.1105011E-03 0.0000000E+00 10 Mg++ 0.7222222E-04 0.3540187E-07 0.7218682E-04 0.0000000E+00 11 Fe++ 0.6488378E-04 0.1411800E-08 0.6488237E-04 0.0000000E+00 12 K+ 0.1932059E-04 0.1932059E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2742982E-03 0.2742982E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1577812E-05 0.3485164E-07 0.1542961E-05 0.0000000E+00 15 HPO4-- 0.5384995E-06 0.7690273E-08 0.5308092E-06 0.0000000E+00 Chg. balance for solid moles: -.2732E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0910000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1769E-06 -6.752 0.8888E-04 -4.051 0.1249 0.2824E-04 clinochlore 0.1444E-04 -4.841 0.8025E-02 -2.096 11.28 0.3052E-02 daphnite 0.8941E-05 -5.049 0.6380E-02 -2.195 8.965 0.1933E-02 chlorite-Mn 0.3086E-06 -6.511 0.2188E-03 -3.660 0.3074 0.6972E-04 hematite 0.1009E-04 -4.996 0.1611E-02 -2.793 2.264 0.3054E-03 kaolinite 0.1309E-04 -4.883 0.3380E-02 -2.471 4.750 0.1301E-02 lawsonite 0.6604E-04 -4.180 0.2075E-01 -1.683 29.16 0.6693E-02 stilbite 0.4357E-04 -4.361 0.3071E-01 -1.513 43.15 0.1432E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3775E+00 0.3775E+00 1.0000 -0.423 chlorite-Mn 0.1303E-01 0.1303E-01 1.0000 -1.885 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.071163 g Volume = 0.027704 cm3 Porosity: 97.3269% V(tot) - V(min): 0.10087E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0910000 g log = -1.0410 Original solution: 1000.0103000 g Original solution / Rock added: 10989.12 (Water/Rock Ratio), log = 4.0410 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2494E-04 1.0071 0.2562E-04 0.2544E-04 CH4,gas 0.3177E-15 1.0125 0.3282E-15 0.3242E-15 H2,gas 0.5862E-06 1.0005 0.5985E-06 0.5982E-06 H2S,gas 0.3294E-12 0.9960 0.3347E-12 0.3360E-12 S2,gas 0.1151E-31 1.0000 0.1174E-31 0.1174E-31 CO,gas 0.4005E-14 1.0000 0.4087E-14 0.4087E-14 SO3,gas 0.7128E-36 1.0000 0.7273E-36 0.7273E-36 SO2,gas 0.1660E-19 1.0000 0.1693E-19 0.1693E-19 HCl,gas 0.3862E-15 1.0000 0.3941E-15 0.3941E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.95 -6.29 -2.097 0.10741E+05 -4.591 3 CH4,gas 4.54 -12.64 -17.18 -4.296 0.29339E+05 -15.484 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13526E+05 -6.223 5 H2S,gas -6.23 -20.40 -14.17 -7.087 0.24202E+05 -12.475 6 S2,gas -7.34 -40.96 -33.63 -5.174 0.57421E+05 -31.930 7 CO,gas 3.21 -12.87 -16.09 -4.950 0.27469E+05 -14.389 8 SO3,gas 17.12 -20.72 -37.84 -9.459 0.64606E+05 -36.138 9 SO2,gas 0.83 -20.64 -21.47 -5.725 0.36660E+05 -19.771 10 HCl,gas 5.19 -11.91 -17.10 -8.552 0.29204E+05 -15.404 11 acmite 7.71 3.88 -3.83 -0.398 0.65349E+04 15 albite-high 0.69 -3.07 -3.76 -0.289 0.64201E+04 16 albite -0.38 -3.07 -2.68 -0.206 0.45813E+04 19 spessartine 24.46 20.56 -3.90 -0.195 0.66519E+04 20 analcite 3.32 0.36 -2.96 -0.329 0.50562E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.77 -4.45 -2.225 0.75987E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.00 -2.97 -0.989 0.50680E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.00 -2.81 -0.938 0.48038E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29426E+04 42 celadonite 5.34 0.90 -4.44 -0.261 0.75766E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12921E+04 52 chloritoid-Mn 11.40 10.54 -0.87 -0.058 0.14779E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64759E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82459E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68789E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.36 -3.85 -0.385 0.65817E+04 97 kalsilite 7.58 2.64 -4.95 -0.707 0.84481E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.79 -4.91 -0.491 0.83842E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75918E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20476E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.22 -1.73 -0.133 0.29583E+04 120 muscovite 2.58 1.30 -1.28 -0.075 0.21838E+04 121 paragonite 4.24 2.46 -1.78 -0.105 0.30460E+04 122 nepheline 8.34 3.79 -4.55 -0.650 0.77710E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49715E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58192E+04 145 pyroxmangite 7.40 5.01 -2.39 -0.477 0.40734E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.51 -3.53 -1.178 0.60333E+04 152 rhodonite 7.45 5.01 -2.43 -0.487 0.41537E+04 153 sanidine -1.28 -4.22 -2.94 -0.226 0.50260E+04 155 siderite -2.61 -6.63 -4.02 -1.340 0.68646E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.36 -1.65 -0.049 0.28244E+04 165 stilpnomelane-Mg 27.44 22.51 -4.93 -0.147 0.84244E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83497E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54867E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77668E+04 174 tephroite 18.09 13.45 -4.63 -0.662 0.79092E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.06 -3.54 -0.217 0.60369E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.68 -3.33 -0.204 0.56917E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.19 -2.95 -0.181 0.50385E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.81 -2.77 -0.170 0.47290E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 1.99 -1.35 -0.087 0.23099E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.37 -1.15 -0.074 0.19664E+04 214 gypsum -4.96 -9.77 -4.81 -1.203 0.82163E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59583E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.53 -2.55 -0.196 0.43509E+04 243 an25ab75 2.65 0.10 -2.54 -0.196 0.43402E+04 244 an30ab70 3.28 0.74 -2.54 -0.195 0.43392E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.0910000 g New total amount of reactant added: 0.0950000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0950000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3108034E-03 Osmotic coef. = 0.9895 True ionic strength = .3486584E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92406E-08 -8.0343 0.88538E-08 -8.0529 0.95814E+00 -0.0186 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13217E-03 -3.8789 0.95799E+00 -0.0186 4 SO4-- 0.25448E-04 -4.5944 0.22621E-04 -4.6455 0.88894E+00 -0.0511 5 HCO3- 0.12693E-04 -4.8965 0.12160E-04 -4.9151 0.95803E+00 -0.0186 6 HS- 0.42799E-12 -12.3686 0.41002E-12 -12.3872 0.95800E+00 -0.0186 7 Al+++ 0.51064E-21 -21.2919 0.40052E-21 -21.3974 0.78435E+00 -0.1055 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.78399E-05 -5.1057 0.69679E-05 -5.1569 0.88878E+00 -0.0512 10 Mg++ 0.31367E-07 -7.5035 0.27875E-07 -7.5548 0.88867E+00 -0.0513 11 Fe++ 0.18514E-09 -9.7325 0.16453E-09 -9.7838 0.88870E+00 -0.0512 12 K+ 0.20162E-04 -4.6955 0.19316E-04 -4.7141 0.95804E+00 -0.0186 13 Na+ 0.27913E-03 -3.5542 0.26740E-03 -3.5728 0.95799E+00 -0.0186 14 Mn++ 0.24387E-07 -7.6128 0.21673E-07 -7.6641 0.88871E+00 -0.0512 15 HPO4-- 0.72050E-08 -8.1424 0.64049E-08 -8.1935 0.88894E+00 -0.0511 16 HSiO3- 0.41125E-04 -4.3859 0.39398E-04 -4.4045 0.95799E+00 -0.0186 17 Ca(HSiO3)+ 0.65256E-08 -8.1854 0.62518E-08 -8.2040 0.95804E+00 -0.0186 18 Mg(HSiO3)+ 0.32489E-10 -10.4883 0.31126E-10 -10.5069 0.95804E+00 -0.0186 19 NaHSiO3,aq 0.17039E-06 -6.7686 0.17039E-06 -6.7686 0.10000E+01 0.0000 20 AlO+ 0.72554E-12 -12.1393 0.69510E-12 -12.1580 0.95804E+00 -0.0186 21 AlOH+2 0.34481E-16 -16.4624 0.30644E-16 -16.5136 0.88874E+00 -0.0512 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.40805E-05 -5.3893 0.39089E-05 -5.4079 0.95795E+00 -0.0187 24 CH4,aq 0.21411E-18 -18.6694 0.21409E-18 -18.6694 0.99990E+00 0.0000 29 CO,aq 0.26340E-17 -17.5794 0.26340E-17 -17.5794 0.10000E+01 0.0000 30 CO2,aq 0.23007E-06 -6.6381 0.23005E-06 -6.6382 0.99990E+00 0.0000 31 CO3-2 0.13496E-06 -6.8698 0.11996E-06 -6.9210 0.88889E+00 -0.0512 32 CaCO3,aq 0.10481E-07 -7.9796 0.10481E-07 -7.9796 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.22575E-08 -8.6464 0.21628E-08 -8.6650 0.95804E+00 -0.0186 34 CaCl+ 0.15556E-08 -8.8081 0.14904E-08 -8.8267 0.95804E+00 -0.0186 35 CaCl2,aq 0.46798E-13 -13.3298 0.46798E-13 -13.3298 0.10000E+01 0.0000 36 CaOH+ 0.58545E-07 -7.2325 0.56089E-07 -7.2511 0.95804E+00 -0.0186 37 CaSO4,aq 0.50053E-07 -7.3006 0.50053E-07 -7.3006 0.10000E+01 0.0000 38 HCl,aq 0.21443E-12 -12.6687 0.21443E-12 -12.6687 0.10000E+01 0.0000 43 FeCl+ 0.35927E-13 -13.4446 0.34420E-13 -13.4632 0.95804E+00 -0.0186 46 FeO,aq 0.81574E-10 -10.0885 0.81574E-10 -10.0885 0.10000E+01 0.0000 47 FeOH+ 0.63139E-09 -9.1997 0.60489E-09 -9.2183 0.95804E+00 -0.0186 48 HFeO2- 0.10063E-09 -9.9973 0.96401E-10 -10.0159 0.95799E+00 -0.0186 49 FeO+ 0.70540E-13 -13.1516 0.67580E-13 -13.1702 0.95804E+00 -0.0186 50 FeOH+2 0.12857E-18 -18.8909 0.11427E-18 -18.9421 0.88874E+00 -0.0512 51 FeO2- 0.18414E-09 -9.7349 0.17640E-09 -9.7535 0.95799E+00 -0.0186 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45584E-09 -9.3412 0.45580E-09 -9.3412 0.99990E+00 0.0000 54 KCl,aq 0.46271E-10 -10.3347 0.46271E-10 -10.3347 0.10000E+01 0.0000 55 KHSO4,aq 0.10938E-16 -16.9610 0.10938E-16 -16.9610 0.10000E+01 0.0000 56 KOH,aq 0.93170E-09 -9.0307 0.93170E-09 -9.0307 0.10000E+01 0.0000 57 KSO4- 0.70779E-08 -8.1501 0.67806E-08 -8.1687 0.95799E+00 -0.0186 58 MgCO3,aq 0.10510E-10 -10.9784 0.10510E-10 -10.9784 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.92280E-11 -11.0349 0.88408E-11 -11.0535 0.95804E+00 -0.0186 60 MgCl+ 0.56404E-11 -11.2487 0.54037E-11 -11.2673 0.95804E+00 -0.0186 61 MgOH+ 0.12960E-08 -8.8874 0.12416E-08 -8.9060 0.95804E+00 -0.0186 63 MnO,aq 0.28632E-09 -9.5431 0.28632E-09 -9.5431 0.10000E+01 0.0000 64 MnOH+ 0.77264E-08 -8.1120 0.74022E-08 -8.1306 0.95804E+00 -0.0186 65 MnO2-2 0.13637E-15 -15.8653 0.12122E-15 -15.9164 0.88889E+00 -0.0512 66 HMnO2- 0.24544E-12 -12.6101 0.23513E-12 -12.6287 0.95799E+00 -0.0186 69 MnCl+ 0.18412E-10 -10.7349 0.17640E-10 -10.7535 0.95804E+00 -0.0186 70 MnSO4,aq 0.14154E-09 -9.8491 0.14154E-09 -9.8491 0.10000E+01 0.0000 71 NaCl,aq 0.11713E-07 -7.9313 0.11713E-07 -7.9313 0.10000E+01 0.0000 72 NaOH,aq 0.12976E-07 -7.8868 0.12976E-07 -7.8868 0.10000E+01 0.0000 74 OH- 0.68122E-04 -4.1667 0.65257E-04 -4.1854 0.95795E+00 -0.0187 79 HPO3-2 0.10235E-19 -19.9899 0.90976E-20 -20.0411 0.88889E+00 -0.0512 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.10919E-08 -8.9618 0.10461E-08 -8.9804 0.95802E+00 -0.0186 84 PO4-3 0.75154E-12 -12.1241 0.59022E-12 -12.2290 0.78535E+00 -0.1049 87 H2P2O7-2 0.96531E-19 -19.0153 0.85806E-19 -19.0665 0.88889E+00 -0.0512 88 HP2O7-3 0.24672E-17 -17.6078 0.19351E-17 -17.7133 0.78436E+00 -0.1055 89 P2O7-4 0.79249E-19 -19.1010 0.52215E-19 -19.2822 0.65887E+00 -0.1812 90 H2S,aq 0.11221E-13 -13.9500 0.11220E-13 -13.9500 0.99990E+00 0.0000 97 SO3-2 0.15068E-14 -14.8219 0.13399E-14 -14.8729 0.88922E+00 -0.0510 98 HSO3- 0.77534E-15 -15.1105 0.74277E-15 -15.1291 0.95799E+00 -0.0186 99 HSO4- 0.20147E-09 -9.6958 0.19302E-09 -9.7144 0.95806E+00 -0.0186 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9240591E-08 -.1257822E-03 -.1267740E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999445E+06 0.0000 3 Cl- 0.1379643E-03 0.1379776E-03 0.4891458E+01 4.1740 4 SO4-- 0.2544764E-04 0.2550504E-04 0.2449923E+01 11.4603 5 HCO3- 0.1269255E-04 0.1307033E-04 0.7974718E+00 3.1378 6 HS- 0.4279931E-12 0.6654327E-10 0.2200600E-05 -4.3343 7 Al+++ 0.5106411E-21 0.4096164E-05 0.1105147E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4148751E-03 0.3987373E+02 -3.4276 9 Ca++ 0.7839857E-05 0.7969275E-05 0.3193754E+00 10.9488 10 Mg++ 0.3136667E-07 0.3272052E-07 0.7954583E-03 8.5510 11 Fe++ 0.1851357E-09 0.1381612E-08 0.7715475E-04 6.3220 12 K+ 0.2016230E-04 0.2017036E-04 0.7886588E+00 3.3388 13 Na+ 0.2791311E-03 0.2793262E-03 0.6421306E+01 4.4800 14 Mn++ 0.2438720E-07 0.3256010E-07 0.1788690E-02 8.4417 15 HPO4-- 0.7205028E-08 0.8297723E-08 0.7963642E-03 7.9123 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1560019E-02 -.1257790E-03 -.1434240E-02 0.0000000E+00 2 H2O 0.5550706E+02 0.5550689E+02 0.1686321E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2813724E-04 0.2550440E-04 0.2632840E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2632774E-05 0.6654159E-10 -.2632840E-05 0.0000000E+00 7 Al+++ 0.3097705E-03 0.4096061E-05 0.3056744E-03 0.0000000E+00 8 H4SiO4 0.9892144E-03 0.4148647E-03 0.5743497E-03 0.0000000E+00 9 Ca++ 0.1237346E-03 0.7969074E-05 0.1157655E-03 0.0000000E+00 10 Mg++ 0.7539683E-04 0.3271970E-07 0.7536411E-04 0.0000000E+00 11 Fe++ 0.6773582E-04 0.1381578E-08 0.6773443E-04 0.0000000E+00 12 K+ 0.2016985E-04 0.2016985E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2793191E-03 0.2793191E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1647167E-05 0.3255928E-07 0.1614607E-05 0.0000000E+00 15 HPO4-- 0.5621698E-06 0.8297514E-08 0.5538723E-06 0.0000000E+00 Chg. balance for solid moles: 0.1624E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0950000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1846E-06 -6.734 0.9274E-04 -4.033 0.1227 0.2947E-04 clinochlore 0.1507E-04 -4.822 0.8378E-02 -2.077 11.08 0.3187E-02 daphnite 0.9334E-05 -5.030 0.6660E-02 -2.177 8.809 0.2018E-02 chlorite-Mn 0.3229E-06 -6.491 0.2289E-03 -3.640 0.3028 0.7296E-04 hematite 0.1053E-04 -4.978 0.1682E-02 -2.774 2.225 0.3188E-03 kaolinite 0.1326E-04 -4.877 0.3424E-02 -2.465 4.529 0.1318E-02 lawsonite 0.6605E-04 -4.180 0.2076E-01 -1.683 27.45 0.6694E-02 stilbite 0.4879E-04 -4.312 0.3438E-01 -1.464 45.48 0.1604E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1306E-01 0.1306E-01 1.0000 -1.884 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.075605 g Volume = 0.029674 cm3 Porosity: 97.1412% V(tot) - V(min): 0.10083E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0950000 g log = -1.0223 Original solution: 1000.0103000 g Original solution / Rock added: 10526.42 (Water/Rock Ratio), log = 4.0223 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2395E-04 1.0071 0.2461E-04 0.2444E-04 CH4,gas 0.3050E-15 1.0125 0.3151E-15 0.3112E-15 H2,gas 0.5862E-06 1.0005 0.5984E-06 0.5981E-06 H2S,gas 0.3035E-12 0.9960 0.3084E-12 0.3096E-12 S2,gas 0.9772E-32 1.0000 0.9971E-32 0.9971E-32 CO,gas 0.3847E-14 1.0000 0.3925E-14 0.3925E-14 SO3,gas 0.6571E-36 1.0000 0.6705E-36 0.6705E-36 SO2,gas 0.1530E-19 1.0000 0.1561E-19 0.1561E-19 HCl,gas 0.3708E-15 1.0000 0.3784E-15 0.3784E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.97 -6.31 -2.103 0.10770E+05 -4.609 3 CH4,gas 4.54 -12.66 -17.20 -4.300 0.29369E+05 -15.502 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.44 -14.21 -7.105 0.24263E+05 -12.511 6 S2,gas -7.34 -41.04 -33.70 -5.185 0.57542E+05 -32.001 7 CO,gas 3.21 -12.89 -16.11 -4.955 0.27499E+05 -14.406 8 SO3,gas 17.12 -20.75 -37.87 -9.468 0.64666E+05 -36.174 9 SO2,gas 0.83 -20.67 -21.51 -5.735 0.36720E+05 -19.807 10 HCl,gas 5.19 -11.93 -17.12 -8.561 0.29234E+05 -15.422 11 acmite 7.71 3.91 -3.80 -0.395 0.64915E+04 15 albite-high 0.69 -3.04 -3.73 -0.287 0.63768E+04 16 albite -0.38 -3.04 -2.66 -0.204 0.45380E+04 19 spessartine 24.46 20.56 -3.89 -0.195 0.66467E+04 20 analcite 3.32 0.39 -2.94 -0.326 0.50129E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.80 -4.49 -2.243 0.76590E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.02 -2.99 -0.995 0.50979E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.02 -2.83 -0.944 0.48336E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29427E+04 42 celadonite 5.34 0.94 -4.40 -0.259 0.75148E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12922E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.058 0.14762E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64759E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82460E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68791E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.39 -3.83 -0.383 0.65383E+04 97 kalsilite 7.58 2.67 -4.91 -0.702 0.83863E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.76 -4.87 -0.487 0.83224E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75918E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20476E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.18 -1.70 -0.130 0.28965E+04 120 muscovite 2.58 1.34 -1.24 -0.073 0.21220E+04 121 paragonite 4.24 2.48 -1.76 -0.103 0.30027E+04 122 nepheline 8.34 3.81 -4.53 -0.647 0.77277E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49715E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.01 -2.38 -0.477 0.40717E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.53 -3.55 -1.183 0.60615E+04 152 rhodonite 7.45 5.01 -2.43 -0.486 0.41520E+04 153 sanidine -1.28 -4.18 -2.91 -0.224 0.49642E+04 155 siderite -2.61 -6.65 -4.04 -1.346 0.68945E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.38 -1.64 -0.049 0.27937E+04 165 stilpnomelane-Mg 27.44 22.53 -4.92 -0.147 0.83935E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83498E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54867E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77668E+04 174 tephroite 18.09 13.46 -4.63 -0.661 0.79057E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.04 -3.52 -0.216 0.60166E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.67 -3.33 -0.204 0.56774E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.18 -2.94 -0.180 0.50181E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.80 -2.76 -0.169 0.47147E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.00 -1.34 -0.086 0.22895E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.38 -1.14 -0.073 0.19521E+04 214 gypsum -4.96 -9.80 -4.85 -1.212 0.82766E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59584E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.51 -2.53 -0.194 0.43162E+04 243 an25ab75 2.65 0.12 -2.52 -0.194 0.43077E+04 244 an30ab70 3.28 0.76 -2.52 -0.194 0.43089E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.0950000 g New total amount of reactant added: 0.0990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.0990000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3132726E-03 Osmotic coef. = 0.9894 True ionic strength = .3527199E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88805E-08 -8.0516 0.85076E-08 -8.0702 0.95801E+00 -0.0186 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13215E-03 -3.8789 0.95786E+00 -0.0187 4 SO4-- 0.25451E-04 -4.5943 0.22612E-04 -4.6457 0.88844E+00 -0.0514 5 HCO3- 0.12697E-04 -4.8963 0.12162E-04 -4.9150 0.95789E+00 -0.0187 6 HS- 0.41096E-12 -12.3862 0.39364E-12 -12.4049 0.95786E+00 -0.0187 7 Al+++ 0.45362E-21 -21.3433 0.35535E-21 -21.4493 0.78336E+00 -0.1060 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.72428E-05 -5.1401 0.64335E-05 -5.1915 0.88827E+00 -0.0515 10 Mg++ 0.28977E-07 -7.5379 0.25737E-07 -7.5894 0.88817E+00 -0.0515 11 Fe++ 0.17103E-09 -9.7669 0.15190E-09 -9.8184 0.88819E+00 -0.0515 12 K+ 0.21011E-04 -4.6775 0.20127E-04 -4.6962 0.95790E+00 -0.0187 13 Na+ 0.28414E-03 -3.5465 0.27217E-03 -3.5652 0.95785E+00 -0.0187 14 Mn++ 0.22575E-07 -7.6464 0.20051E-07 -7.6979 0.88821E+00 -0.0515 15 HPO4-- 0.78078E-08 -8.1075 0.69368E-08 -8.1588 0.88844E+00 -0.0514 16 HSiO3- 0.42805E-04 -4.3685 0.41001E-04 -4.3872 0.95786E+00 -0.0187 17 Ca(HSiO3)+ 0.62713E-08 -8.2026 0.60073E-08 -8.2213 0.95791E+00 -0.0187 18 Mg(HSiO3)+ 0.31222E-10 -10.5055 0.29908E-10 -10.5242 0.95791E+00 -0.0187 19 NaHSiO3,aq 0.18048E-06 -6.7436 0.18048E-06 -6.7436 0.10000E+01 0.0000 20 AlO+ 0.69727E-12 -12.1566 0.66791E-12 -12.1753 0.95791E+00 -0.0187 21 AlOH+2 0.31855E-16 -16.4968 0.28294E-16 -16.5483 0.88823E+00 -0.0515 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.42472E-05 -5.3719 0.40680E-05 -5.3906 0.95781E+00 -0.0187 24 CH4,aq 0.20568E-18 -18.6868 0.20566E-18 -18.6868 0.99990E+00 0.0000 29 CO,aq 0.25312E-17 -17.5967 0.25312E-17 -17.5967 0.10000E+01 0.0000 30 CO2,aq 0.22111E-06 -6.6554 0.22109E-06 -6.6554 0.99990E+00 0.0000 31 CO3-2 0.14055E-06 -6.8522 0.12486E-06 -6.9036 0.88839E+00 -0.0514 32 CaCO3,aq 0.10073E-07 -7.9969 0.10073E-07 -7.9969 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20850E-08 -8.6809 0.19973E-08 -8.6996 0.95791E+00 -0.0187 34 CaCl+ 0.14363E-08 -8.8427 0.13759E-08 -8.8614 0.95791E+00 -0.0187 35 CaCl2,aq 0.43197E-13 -13.3645 0.43197E-13 -13.3645 0.10000E+01 0.0000 36 CaOH+ 0.56263E-07 -7.2498 0.53895E-07 -7.2685 0.95791E+00 -0.0187 37 CaSO4,aq 0.46195E-07 -7.3354 0.46195E-07 -7.3354 0.10000E+01 0.0000 38 HCl,aq 0.20602E-12 -12.6861 0.20602E-12 -12.6861 0.10000E+01 0.0000 43 FeCl+ 0.33170E-13 -13.4793 0.31774E-13 -13.4979 0.95791E+00 -0.0187 46 FeO,aq 0.81569E-10 -10.0885 0.81569E-10 -10.0885 0.10000E+01 0.0000 47 FeOH+ 0.60675E-09 -9.2170 0.58121E-09 -9.2357 0.95791E+00 -0.0187 48 HFeO2- 0.10473E-09 -9.9799 0.10032E-09 -9.9986 0.95786E+00 -0.0187 49 FeO+ 0.67791E-13 -13.1688 0.64937E-13 -13.1875 0.95791E+00 -0.0187 50 FeOH+2 0.11878E-18 -18.9253 0.10550E-18 -18.9767 0.88823E+00 -0.0515 51 FeO2- 0.19166E-09 -9.7175 0.18358E-09 -9.7362 0.95786E+00 -0.0187 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45579E-09 -9.3412 0.45575E-09 -9.3413 0.99990E+00 0.0000 54 KCl,aq 0.48206E-10 -10.3169 0.48206E-10 -10.3169 0.10000E+01 0.0000 55 KHSO4,aq 0.10947E-16 -16.9607 0.10947E-16 -16.9607 0.10000E+01 0.0000 56 KOH,aq 0.10103E-08 -8.9955 0.10103E-08 -8.9955 0.10000E+01 0.0000 57 KSO4- 0.73728E-08 -8.1324 0.70621E-08 -8.1511 0.95786E+00 -0.0187 58 MgCO3,aq 0.10100E-10 -10.9957 0.10100E-10 -10.9957 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85229E-11 -11.0694 0.81642E-11 -11.0881 0.95791E+00 -0.0187 60 MgCl+ 0.52078E-11 -11.2833 0.49886E-11 -11.3020 0.95791E+00 -0.0187 61 MgOH+ 0.12455E-08 -8.9047 0.11930E-08 -8.9233 0.95791E+00 -0.0187 63 MnO,aq 0.28690E-09 -9.5423 0.28690E-09 -9.5423 0.10000E+01 0.0000 64 MnOH+ 0.74402E-08 -8.1284 0.71270E-08 -8.1471 0.95791E+00 -0.0187 65 MnO2-2 0.14808E-15 -15.8295 0.13155E-15 -15.8809 0.88839E+00 -0.0514 66 HMnO2- 0.25598E-12 -12.5918 0.24519E-12 -12.6105 0.95786E+00 -0.0187 69 MnCl+ 0.17034E-10 -10.7687 0.16317E-10 -10.7874 0.95791E+00 -0.0187 70 MnSO4,aq 0.13089E-09 -9.8831 0.13089E-09 -9.8831 0.10000E+01 0.0000 71 NaCl,aq 0.11919E-07 -7.9237 0.11919E-07 -7.9237 0.10000E+01 0.0000 72 NaOH,aq 0.13745E-07 -7.8619 0.13745E-07 -7.8619 0.10000E+01 0.0000 74 OH- 0.70904E-04 -4.1493 0.67913E-04 -4.1680 0.95781E+00 -0.0187 79 HPO3-2 0.11090E-19 -19.9551 0.98521E-20 -20.0065 0.88839E+00 -0.0514 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.11365E-08 -8.9444 0.10887E-08 -8.9631 0.95788E+00 -0.0187 84 PO4-3 0.84815E-12 -12.0715 0.66525E-12 -12.1770 0.78436E+00 -0.1055 87 H2P2O7-2 0.10461E-18 -18.9804 0.92932E-19 -19.0318 0.88839E+00 -0.0514 88 HP2O7-3 0.27843E-17 -17.5553 0.21812E-17 -17.6613 0.78337E+00 -0.1060 89 P2O7-4 0.93169E-19 -19.0307 0.61248E-19 -19.2129 0.65738E+00 -0.1822 90 H2S,aq 0.10351E-13 -13.9850 0.10350E-13 -13.9850 0.99990E+00 0.0000 97 SO3-2 0.15068E-14 -14.8219 0.13392E-14 -14.8732 0.88873E+00 -0.0512 98 HSO3- 0.74473E-15 -15.1280 0.71334E-15 -15.1467 0.95786E+00 -0.0187 99 HSO4- 0.19353E-09 -9.7132 0.18539E-09 -9.7319 0.95793E+00 -0.0187 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8880462E-08 -.1309338E-03 -.1319663E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999442E+06 0.0000 3 Cl- 0.1379643E-03 0.1379778E-03 0.4891460E+01 4.1913 4 SO4-- 0.2545124E-04 0.2550506E-04 0.2449924E+01 11.4947 5 HCO3- 0.1269650E-04 0.1307034E-04 0.7974722E+00 3.1552 6 HS- 0.4109589E-12 0.6557303E-10 0.2168514E-05 -4.3347 7 Al+++ 0.4536207E-21 0.4262841E-05 0.1150116E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4165647E-03 0.4003611E+02 -3.4276 9 Ca++ 0.7242753E-05 0.7365077E-05 0.2951615E+00 10.9488 10 Mg++ 0.2897748E-07 0.3027800E-07 0.7360788E-03 8.5509 11 Fe++ 0.1710260E-09 0.1354479E-08 0.7563950E-04 6.3220 12 K+ 0.2101122E-04 0.2101965E-04 0.8218659E+00 3.3740 13 Na+ 0.2841413E-03 0.2843475E-03 0.6536737E+01 4.5050 14 Mn++ 0.2257513E-07 0.3045042E-07 0.1672794E-02 8.4425 15 HPO4-- 0.7807830E-08 0.8945223E-08 0.8585070E-03 7.9816 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1626253E-02 -.1309304E-03 -.1495323E-02 0.0000000E+00 2 H2O 0.5550701E+02 0.5550685E+02 0.1603021E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2824810E-04 0.2550440E-04 0.2743693E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2743627E-05 0.6557133E-10 -.2743693E-05 0.0000000E+00 7 Al+++ 0.3228134E-03 0.4262731E-05 0.3185507E-03 0.0000000E+00 8 H4SiO4 0.1030866E-02 0.4165539E-03 0.6143116E-03 0.0000000E+00 9 Ca++ 0.1283352E-03 0.7364886E-05 0.1209703E-03 0.0000000E+00 10 Mg++ 0.7857143E-04 0.3027721E-07 0.7854115E-04 0.0000000E+00 11 Fe++ 0.7058785E-04 0.1354444E-08 0.7058650E-04 0.0000000E+00 12 K+ 0.2101911E-04 0.2101911E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2843401E-03 0.2843401E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1716521E-05 0.3044963E-07 0.1686071E-05 0.0000000E+00 15 HPO4-- 0.5858401E-06 0.8944991E-08 0.5768951E-06 0.0000000E+00 Chg. balance for solid moles: 0.6840E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.0990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1923E-06 -6.716 0.9660E-04 -4.015 0.1207 0.3069E-04 clinochlore 0.1571E-04 -4.804 0.8731E-02 -2.059 10.91 0.3321E-02 daphnite 0.9727E-05 -5.012 0.6941E-02 -2.159 8.671 0.2103E-02 chlorite-Mn 0.3372E-06 -6.472 0.2391E-03 -3.621 0.2987 0.7619E-04 hematite 0.1097E-04 -4.960 0.1753E-02 -2.756 2.190 0.3322E-03 kaolinite 0.1349E-04 -4.870 0.3484E-02 -2.458 4.352 0.1340E-02 lawsonite 0.6601E-04 -4.180 0.2074E-01 -1.683 25.92 0.6689E-02 stilbite 0.5400E-04 -4.268 0.3805E-01 -1.420 47.54 0.1775E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1308E-01 0.1308E-01 1.0000 -1.883 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.080040 g Volume = 0.031642 cm3 Porosity: 96.9564% V(tot) - V(min): 0.10080E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0990000 g log = -1.0044 Original solution: 1000.0103000 g Original solution / Rock added: 10101.11 (Water/Rock Ratio), log = 4.0044 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2302E-04 1.0071 0.2365E-04 0.2349E-04 CH4,gas 0.2930E-15 1.0125 0.3027E-15 0.2990E-15 H2,gas 0.5861E-06 1.0005 0.5983E-06 0.5980E-06 H2S,gas 0.2800E-12 0.9960 0.2845E-12 0.2857E-12 S2,gas 0.8319E-32 1.0000 0.8488E-32 0.8488E-32 CO,gas 0.3697E-14 1.0000 0.3772E-14 0.3772E-14 SO3,gas 0.6065E-36 1.0000 0.6188E-36 0.6188E-36 SO2,gas 0.1412E-19 1.0000 0.1440E-19 0.1440E-19 HCl,gas 0.3563E-15 1.0000 0.3635E-15 0.3635E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -12.99 -6.33 -2.108 0.10800E+05 -4.626 3 CH4,gas 4.54 -12.67 -17.22 -4.304 0.29399E+05 -15.519 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.48 -14.24 -7.122 0.24323E+05 -12.546 6 S2,gas -7.34 -41.11 -33.77 -5.195 0.57662E+05 -32.071 7 CO,gas 3.21 -12.91 -16.12 -4.961 0.27529E+05 -14.423 8 SO3,gas 17.12 -20.79 -37.91 -9.477 0.64726E+05 -36.208 9 SO2,gas 0.83 -20.71 -21.54 -5.744 0.36780E+05 -19.841 10 HCl,gas 5.19 -11.95 -17.14 -8.569 0.29263E+05 -15.439 11 acmite 7.71 3.93 -3.78 -0.392 0.64489E+04 15 albite-high 0.69 -3.02 -3.71 -0.285 0.63341E+04 16 albite -0.38 -3.02 -2.63 -0.203 0.44953E+04 19 spessartine 24.46 20.57 -3.89 -0.195 0.66423E+04 20 analcite 3.32 0.41 -2.91 -0.323 0.49702E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.84 -4.52 -2.260 0.77185E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.04 -3.00 -1.001 0.51273E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.04 -2.85 -0.949 0.48631E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29427E+04 42 celadonite 5.34 0.98 -4.37 -0.257 0.74547E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12922E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.058 0.14747E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64760E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82461E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68792E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.41 -3.80 -0.380 0.64957E+04 97 kalsilite 7.58 2.71 -4.88 -0.697 0.83262E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.72 -4.84 -0.484 0.82623E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75919E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20477E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.15 -1.66 -0.128 0.28364E+04 120 muscovite 2.58 1.37 -1.21 -0.071 0.20620E+04 121 paragonite 4.24 2.51 -1.73 -0.102 0.29600E+04 122 nepheline 8.34 3.84 -4.50 -0.643 0.76850E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49716E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.01 -2.38 -0.477 0.40702E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.54 -3.57 -1.189 0.60894E+04 152 rhodonite 7.45 5.01 -2.43 -0.486 0.41505E+04 153 sanidine -1.28 -4.15 -2.87 -0.221 0.49042E+04 155 siderite -2.61 -6.66 -4.06 -1.352 0.69240E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.40 -1.62 -0.048 0.27639E+04 165 stilpnomelane-Mg 27.44 22.54 -4.90 -0.146 0.83635E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83499E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54867E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77668E+04 174 tephroite 18.09 13.46 -4.63 -0.661 0.79028E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.03 -3.51 -0.215 0.59967E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.66 -3.32 -0.203 0.56633E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.16 -2.93 -0.179 0.49983E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.79 -2.75 -0.169 0.47006E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.01 -1.33 -0.085 0.22697E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.38 -1.14 -0.073 0.19380E+04 214 gypsum -4.96 -9.84 -4.88 -1.221 0.83361E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59584E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.49 -2.51 -0.193 0.42821E+04 243 an25ab75 2.65 0.14 -2.50 -0.193 0.42757E+04 244 an30ab70 3.28 0.77 -2.51 -0.193 0.42790E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.0990000 g New total amount of reactant added: 0.1030000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1030000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3158701E-03 Osmotic coef. = 0.9894 True ionic strength = .3569449E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.85399E-08 -8.0685 0.81801E-08 -8.0872 0.95787E+00 -0.0187 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13213E-03 -3.8790 0.95772E+00 -0.0188 4 SO4-- 0.25454E-04 -4.5942 0.22602E-04 -4.6459 0.88792E+00 -0.0516 5 HCO3- 0.12700E-04 -4.8962 0.12163E-04 -4.9149 0.95775E+00 -0.0187 6 HS- 0.39487E-12 -12.4035 0.37818E-12 -12.4223 0.95772E+00 -0.0188 7 Al+++ 0.40377E-21 -21.3939 0.31588E-21 -21.5005 0.78233E+00 -0.1066 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.66999E-05 -5.1739 0.59479E-05 -5.2256 0.88775E+00 -0.0517 10 Mg++ 0.26806E-07 -7.5718 0.23794E-07 -7.6235 0.88765E+00 -0.0518 11 Fe++ 0.15820E-09 -9.8008 0.14043E-09 -9.8525 0.88767E+00 -0.0517 12 K+ 0.21860E-04 -4.6603 0.20937E-04 -4.6791 0.95776E+00 -0.0187 13 Na+ 0.28915E-03 -3.5389 0.27692E-03 -3.5576 0.95771E+00 -0.0188 14 Mn++ 0.20920E-07 -7.6794 0.18570E-07 -7.7312 0.88769E+00 -0.0517 15 HPO4-- 0.84503E-08 -8.0731 0.75032E-08 -8.1248 0.88793E+00 -0.0516 16 HSiO3- 0.44525E-04 -4.3514 0.42642E-04 -4.3702 0.95772E+00 -0.0188 17 Ca(HSiO3)+ 0.60309E-08 -8.2196 0.57762E-08 -8.2384 0.95777E+00 -0.0187 18 Mg(HSiO3)+ 0.30025E-10 -10.5225 0.28757E-10 -10.5413 0.95777E+00 -0.0187 19 NaHSiO3,aq 0.19099E-06 -6.7190 0.19099E-06 -6.7190 0.10000E+01 0.0000 20 AlO+ 0.67053E-12 -12.1736 0.64221E-12 -12.1923 0.95777E+00 -0.0187 21 AlOH+2 0.29467E-16 -16.5307 0.26159E-16 -16.5824 0.88771E+00 -0.0517 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.44178E-05 -5.3548 0.42308E-05 -5.3736 0.95767E+00 -0.0188 24 CH4,aq 0.19771E-18 -18.7040 0.19769E-18 -18.7040 0.99990E+00 0.0000 29 CO,aq 0.24338E-17 -17.6137 0.24338E-17 -17.6137 0.10000E+01 0.0000 30 CO2,aq 0.21262E-06 -6.6724 0.21260E-06 -6.6724 0.99990E+00 0.0000 31 CO3-2 0.14628E-06 -6.8348 0.12988E-06 -6.8865 0.88787E+00 -0.0516 32 CaCO3,aq 0.96862E-08 -8.0138 0.96862E-08 -8.0138 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19281E-08 -8.7149 0.18467E-08 -8.7336 0.95777E+00 -0.0187 34 CaCl+ 0.13279E-08 -8.8768 0.12718E-08 -8.8956 0.95777E+00 -0.0187 35 CaCl2,aq 0.39925E-13 -13.3988 0.39925E-13 -13.3988 0.10000E+01 0.0000 36 CaOH+ 0.54106E-07 -7.2668 0.51821E-07 -7.2855 0.95777E+00 -0.0187 37 CaSO4,aq 0.42688E-07 -7.3697 0.42688E-07 -7.3697 0.10000E+01 0.0000 38 HCl,aq 0.19806E-12 -12.7032 0.19806E-12 -12.7032 0.10000E+01 0.0000 43 FeCl+ 0.30665E-13 -13.5134 0.29370E-13 -13.5321 0.95777E+00 -0.0187 46 FeO,aq 0.81565E-10 -10.0885 0.81565E-10 -10.0885 0.10000E+01 0.0000 47 FeOH+ 0.58345E-09 -9.2340 0.55881E-09 -9.2527 0.95777E+00 -0.0187 48 HFeO2- 0.10894E-09 -9.9628 0.10433E-09 -9.9816 0.95772E+00 -0.0188 49 FeO+ 0.65192E-13 -13.1858 0.62438E-13 -13.2045 0.95777E+00 -0.0187 50 FeOH+2 0.10988E-18 -18.9591 0.97539E-19 -19.0108 0.88771E+00 -0.0517 51 FeO2- 0.19936E-09 -9.7004 0.19093E-09 -9.7191 0.95772E+00 -0.0188 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45575E-09 -9.3413 0.45570E-09 -9.3413 0.99990E+00 0.0000 54 KCl,aq 0.50139E-10 -10.2998 0.50139E-10 -10.2998 0.10000E+01 0.0000 55 KHSO4,aq 0.10944E-16 -16.9608 0.10944E-16 -16.9608 0.10000E+01 0.0000 56 KOH,aq 0.10930E-08 -8.9614 0.10930E-08 -8.9614 0.10000E+01 0.0000 57 KSO4- 0.76672E-08 -8.1154 0.73430E-08 -8.1341 0.95772E+00 -0.0188 58 MgCO3,aq 0.97126E-11 -11.0127 0.97126E-11 -11.0127 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.78816E-11 -11.1034 0.75487E-11 -11.1221 0.95777E+00 -0.0187 60 MgCl+ 0.48147E-11 -11.3174 0.46113E-11 -11.3362 0.95777E+00 -0.0187 61 MgOH+ 0.11977E-08 -8.9217 0.11471E-08 -8.9404 0.95777E+00 -0.0187 63 MnO,aq 0.28740E-09 -9.5415 0.28740E-09 -9.5415 0.10000E+01 0.0000 64 MnOH+ 0.71675E-08 -8.1446 0.68648E-08 -8.1634 0.95777E+00 -0.0187 65 MnO2-2 0.16054E-15 -15.7944 0.14254E-15 -15.8461 0.88787E+00 -0.0516 66 HMnO2- 0.26673E-12 -12.5739 0.25545E-12 -12.5927 0.95772E+00 -0.0188 69 MnCl+ 0.15776E-10 -10.8020 0.15110E-10 -10.8207 0.95777E+00 -0.0187 70 MnSO4,aq 0.12117E-09 -9.9166 0.12117E-09 -9.9166 0.10000E+01 0.0000 71 NaCl,aq 0.12126E-07 -7.9163 0.12126E-07 -7.9163 0.10000E+01 0.0000 72 NaOH,aq 0.14545E-07 -7.8373 0.14545E-07 -7.8373 0.10000E+01 0.0000 74 OH- 0.73753E-04 -4.1322 0.70631E-04 -4.1510 0.95767E+00 -0.0188 79 HPO3-2 0.12001E-19 -19.9208 0.10655E-19 -19.9724 0.88787E+00 -0.0516 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.11822E-08 -8.9273 0.11322E-08 -8.9461 0.95774E+00 -0.0188 84 PO4-3 0.95536E-12 -12.0198 0.74837E-12 -12.1259 0.78334E+00 -0.1060 87 H2P2O7-2 0.11321E-18 -18.9461 0.10052E-18 -18.9977 0.88787E+00 -0.0516 88 HP2O7-3 0.31363E-17 -17.5036 0.24537E-17 -17.6102 0.78234E+00 -0.1066 89 P2O7-4 0.10926E-18 -18.9615 0.71658E-19 -19.1447 0.65586E+00 -0.1832 90 H2S,aq 0.95619E-14 -14.0195 0.95609E-14 -14.0195 0.99990E+00 0.0000 97 SO3-2 0.15069E-14 -14.8219 0.13384E-14 -14.8734 0.88821E+00 -0.0515 98 HSO3- 0.71578E-15 -15.1452 0.68551E-15 -15.1640 0.95772E+00 -0.0188 99 HSO4- 0.18603E-09 -9.7304 0.17818E-09 -9.7492 0.95779E+00 -0.0187 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8539943E-08 -.1362077E-03 -.1372817E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999439E+06 0.0000 3 Cl- 0.1379643E-03 0.1379779E-03 0.4891462E+01 4.2082 4 SO4-- 0.2545449E-04 0.2550509E-04 0.2449926E+01 11.5286 5 HCO3- 0.1269981E-04 0.1307035E-04 0.7974726E+00 3.1723 6 HS- 0.3948702E-12 0.6458309E-10 0.2135775E-05 -4.3351 7 Al+++ 0.4037693E-21 0.4433482E-05 0.1196155E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4182948E-03 0.4020238E+02 -3.4276 9 Ca++ 0.6699935E-05 0.6815703E-05 0.2731448E+00 10.9488 10 Mg++ 0.2680555E-07 0.2805568E-07 0.6820525E-03 8.5509 11 Fe++ 0.1582008E-09 0.1330255E-08 0.7428671E-04 6.3219 12 K+ 0.2186014E-04 0.2186895E-04 0.8550730E+00 3.4081 13 Na+ 0.2891512E-03 0.2893688E-03 0.6652168E+01 4.5296 14 Mn++ 0.2091990E-07 0.2851200E-07 0.1566307E-02 8.4433 15 HPO4-- 0.8450262E-08 0.9633425E-08 0.9245560E-03 8.0497 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1692487E-02 -.1362041E-03 -.1556283E-02 0.0000000E+00 2 H2O 0.5550696E+02 0.5550681E+02 0.1519513E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2835895E-04 0.2550441E-04 0.2854546E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2854481E-05 0.6458136E-10 -.2854546E-05 0.0000000E+00 7 Al+++ 0.3358564E-03 0.4433364E-05 0.3314230E-03 0.0000000E+00 8 H4SiO4 0.1072517E-02 0.4182836E-03 0.6542330E-03 0.0000000E+00 9 Ca++ 0.1329358E-03 0.6815521E-05 0.1261202E-03 0.0000000E+00 10 Mg++ 0.8174603E-04 0.2805493E-07 0.8171798E-04 0.0000000E+00 11 Fe++ 0.7343989E-04 0.1330220E-08 0.7343855E-04 0.0000000E+00 12 K+ 0.2186837E-04 0.2186837E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2893611E-03 0.2893611E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1785875E-05 0.2851124E-07 0.1757364E-05 0.0000000E+00 15 HPO4-- 0.6095104E-06 0.9633168E-08 0.5998772E-06 0.0000000E+00 Chg. balance for solid moles: 0.2922E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1030000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2000E-06 -6.699 0.1004E-03 -3.998 0.1189 0.3192E-04 clinochlore 0.1634E-04 -4.787 0.9084E-02 -2.042 10.75 0.3455E-02 daphnite 0.1012E-04 -4.995 0.7221E-02 -2.141 8.549 0.2188E-02 chlorite-Mn 0.3515E-06 -6.454 0.2492E-03 -3.603 0.2950 0.7941E-04 hematite 0.1142E-04 -4.942 0.1823E-02 -2.739 2.159 0.3456E-03 kaolinite 0.1378E-04 -4.861 0.3556E-02 -2.449 4.210 0.1368E-02 lawsonite 0.6592E-04 -4.181 0.2072E-01 -1.684 24.52 0.6680E-02 stilbite 0.5920E-04 -4.228 0.4172E-01 -1.380 49.39 0.1946E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1311E-01 0.1311E-01 1.0000 -1.882 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.084469 g Volume = 0.033607 cm3 Porosity: 96.7722% V(tot) - V(min): 0.10076E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1030000 g log = -0.9872 Original solution: 1000.0103000 g Original solution / Rock added: 9708.84 (Water/Rock Ratio), log = 3.9872 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2214E-04 1.0071 0.2275E-04 0.2259E-04 CH4,gas 0.2817E-15 1.0125 0.2910E-15 0.2874E-15 H2,gas 0.5861E-06 1.0005 0.5983E-06 0.5980E-06 H2S,gas 0.2586E-12 0.9960 0.2628E-12 0.2639E-12 S2,gas 0.7100E-32 1.0000 0.7244E-32 0.7244E-32 CO,gas 0.3555E-14 1.0000 0.3627E-14 0.3627E-14 SO3,gas 0.5604E-36 1.0000 0.5718E-36 0.5718E-36 SO2,gas 0.1305E-19 1.0000 0.1331E-19 0.1331E-19 HCl,gas 0.3425E-15 1.0000 0.3495E-15 0.3495E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.00 -6.34 -2.114 0.10829E+05 -4.643 3 CH4,gas 4.54 -12.69 -17.24 -4.309 0.29428E+05 -15.536 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.51 -14.28 -7.140 0.24382E+05 -12.580 6 S2,gas -7.34 -41.17 -33.84 -5.206 0.57779E+05 -32.140 7 CO,gas 3.21 -12.92 -16.14 -4.966 0.27558E+05 -14.440 8 SO3,gas 17.12 -20.82 -37.94 -9.485 0.64784E+05 -36.243 9 SO2,gas 0.83 -20.74 -21.57 -5.753 0.36838E+05 -19.876 10 HCl,gas 5.19 -11.97 -17.16 -8.578 0.29293E+05 -15.457 11 acmite 7.71 3.96 -3.75 -0.390 0.64069E+04 15 albite-high 0.69 -2.99 -3.69 -0.283 0.62922E+04 16 albite -0.38 -2.99 -2.61 -0.201 0.44534E+04 19 spessartine 24.46 20.57 -3.89 -0.194 0.66384E+04 20 analcite 3.32 0.44 -2.89 -0.321 0.49282E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.87 -4.55 -2.277 0.77770E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.05 -3.02 -1.007 0.51563E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.05 -2.87 -0.955 0.48921E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23288E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29428E+04 42 celadonite 5.34 1.01 -4.33 -0.255 0.73964E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12923E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.058 0.14734E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64760E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82462E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68793E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.44 -3.78 -0.378 0.64537E+04 97 kalsilite 7.58 2.74 -4.84 -0.692 0.82678E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.69 -4.80 -0.480 0.82039E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75919E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20477E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.11 -1.63 -0.125 0.27780E+04 120 muscovite 2.58 1.41 -1.17 -0.069 0.20036E+04 121 paragonite 4.24 2.53 -1.71 -0.101 0.29180E+04 122 nepheline 8.34 3.86 -4.48 -0.639 0.76431E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49716E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.477 0.40689E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.56 -3.58 -1.194 0.61171E+04 152 rhodonite 7.45 5.02 -2.43 -0.486 0.41492E+04 153 sanidine -1.28 -4.11 -2.84 -0.218 0.48458E+04 155 siderite -2.61 -6.68 -4.07 -1.357 0.69530E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.42 -1.60 -0.048 0.27349E+04 165 stilpnomelane-Mg 27.44 22.56 -4.88 -0.146 0.83344E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83499E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77668E+04 174 tephroite 18.09 13.46 -4.63 -0.661 0.79002E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.02 -3.50 -0.214 0.59775E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.65 -3.31 -0.203 0.56495E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.15 -2.92 -0.179 0.49790E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.78 -2.74 -0.168 0.46868E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.02 -1.32 -0.085 0.22505E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.39 -1.13 -0.072 0.19242E+04 214 gypsum -4.96 -9.87 -4.92 -1.229 0.83946E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59585E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.47 -2.49 -0.191 0.42485E+04 243 an25ab75 2.65 0.16 -2.49 -0.191 0.42443E+04 244 an30ab70 3.28 0.79 -2.49 -0.191 0.42496E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1030000 g New total amount of reactant added: 0.1070000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1070000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3185849E-03 Osmotic coef. = 0.9893 True ionic strength = .3613193E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.82183E-08 -8.0852 0.78709E-08 -8.1040 0.95773E+00 -0.0188 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13211E-03 -3.8791 0.95757E+00 -0.0188 4 SO4-- 0.25457E-04 -4.5942 0.22591E-04 -4.6461 0.88739E+00 -0.0519 5 HCO3- 0.12703E-04 -4.8961 0.12164E-04 -4.9149 0.95761E+00 -0.0188 6 HS- 0.37969E-12 -12.4206 0.36358E-12 -12.4394 0.95758E+00 -0.0188 7 Al+++ 0.36017E-21 -21.4435 0.28139E-21 -21.5507 0.78127E+00 -0.1072 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.62067E-05 -5.2071 0.55067E-05 -5.2591 0.88722E+00 -0.0520 10 Mg++ 0.24832E-07 -7.6050 0.22029E-07 -7.6570 0.88711E+00 -0.0520 11 Fe++ 0.14655E-09 -9.8340 0.13001E-09 -9.8860 0.88714E+00 -0.0520 12 K+ 0.22709E-04 -4.6438 0.21747E-04 -4.6626 0.95762E+00 -0.0188 13 Na+ 0.29416E-03 -3.5314 0.28168E-03 -3.5502 0.95757E+00 -0.0188 14 Mn++ 0.19410E-07 -7.7120 0.17219E-07 -7.7640 0.88716E+00 -0.0520 15 HPO4-- 0.91328E-08 -8.0394 0.81043E-08 -8.0913 0.88739E+00 -0.0519 16 HSiO3- 0.46281E-04 -4.3346 0.44318E-04 -4.3534 0.95757E+00 -0.0188 17 Ca(HSiO3)+ 0.58038E-08 -8.2363 0.55578E-08 -8.2551 0.95762E+00 -0.0188 18 Mg(HSiO3)+ 0.28894E-10 -10.5392 0.27670E-10 -10.5580 0.95762E+00 -0.0188 19 NaHSiO3,aq 0.20190E-06 -6.6949 0.20190E-06 -6.6949 0.10000E+01 0.0000 20 AlO+ 0.64528E-12 -12.1903 0.61793E-12 -12.2091 0.95762E+00 -0.0188 21 AlOH+2 0.27298E-16 -16.5639 0.24218E-16 -16.6159 0.88718E+00 -0.0520 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.45921E-05 -5.3380 0.43971E-05 -5.3568 0.95753E+00 -0.0188 24 CH4,aq 0.19019E-18 -18.7208 0.19017E-18 -18.7209 0.99990E+00 0.0000 29 CO,aq 0.23417E-17 -17.6305 0.23417E-17 -17.6305 0.10000E+01 0.0000 30 CO2,aq 0.20460E-06 -6.6891 0.20458E-06 -6.6891 0.99990E+00 0.0000 31 CO3-2 0.15213E-06 -6.8178 0.13499E-06 -6.8697 0.88734E+00 -0.0519 32 CaCO3,aq 0.93207E-08 -8.0306 0.93207E-08 -8.0306 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.17855E-08 -8.7482 0.17098E-08 -8.7670 0.95762E+00 -0.0188 34 CaCl+ 0.12294E-08 -8.9103 0.11773E-08 -8.9291 0.95762E+00 -0.0188 35 CaCl2,aq 0.36952E-13 -13.4324 0.36952E-13 -13.4324 0.10000E+01 0.0000 36 CaOH+ 0.52069E-07 -7.2834 0.49862E-07 -7.3022 0.95762E+00 -0.0188 37 CaSO4,aq 0.39503E-07 -7.4034 0.39503E-07 -7.4034 0.10000E+01 0.0000 38 HCl,aq 0.19054E-12 -12.7200 0.19054E-12 -12.7200 0.10000E+01 0.0000 43 FeCl+ 0.28389E-13 -13.5468 0.27186E-13 -13.5657 0.95762E+00 -0.0188 46 FeO,aq 0.81562E-10 -10.0885 0.81562E-10 -10.0885 0.10000E+01 0.0000 47 FeOH+ 0.56146E-09 -9.2507 0.53766E-09 -9.2695 0.95762E+00 -0.0188 48 HFeO2- 0.11323E-09 -9.9460 0.10842E-09 -9.9649 0.95757E+00 -0.0188 49 FeO+ 0.62737E-13 -13.2025 0.60078E-13 -13.2213 0.95762E+00 -0.0188 50 FeOH+2 0.10179E-18 -18.9923 0.90304E-19 -19.0443 0.88718E+00 -0.0520 51 FeO2- 0.20722E-09 -9.6836 0.19843E-09 -9.7024 0.95757E+00 -0.0188 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45571E-09 -9.3413 0.45566E-09 -9.3414 0.99990E+00 0.0000 54 KCl,aq 0.52070E-10 -10.2834 0.52070E-10 -10.2834 0.10000E+01 0.0000 55 KHSO4,aq 0.10933E-16 -16.9613 0.10933E-16 -16.9613 0.10000E+01 0.0000 56 KOH,aq 0.11799E-08 -8.9281 0.11799E-08 -8.9281 0.10000E+01 0.0000 57 KSO4- 0.79611E-08 -8.0990 0.76233E-08 -8.1179 0.95757E+00 -0.0188 58 MgCO3,aq 0.93460E-11 -11.0294 0.93460E-11 -11.0294 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72984E-11 -11.1368 0.69891E-11 -11.1556 0.95762E+00 -0.0188 60 MgCl+ 0.44575E-11 -11.3509 0.42686E-11 -11.3697 0.95762E+00 -0.0188 61 MgOH+ 0.11526E-08 -8.9383 0.11037E-08 -8.9571 0.95762E+00 -0.0188 63 MnO,aq 0.28785E-09 -9.5408 0.28785E-09 -9.5408 0.10000E+01 0.0000 64 MnOH+ 0.69082E-08 -8.1606 0.66154E-08 -8.1794 0.95762E+00 -0.0188 65 MnO2-2 0.17378E-15 -15.7600 0.15420E-15 -15.8119 0.88734E+00 -0.0519 66 HMnO2- 0.27768E-12 -12.5565 0.26590E-12 -12.5753 0.95757E+00 -0.0188 69 MnCl+ 0.14628E-10 -10.8348 0.14008E-10 -10.8536 0.95762E+00 -0.0188 70 MnSO4,aq 0.11230E-09 -9.9496 0.11230E-09 -9.9496 0.10000E+01 0.0000 71 NaCl,aq 0.12332E-07 -7.9090 0.12332E-07 -7.9090 0.10000E+01 0.0000 72 NaOH,aq 0.15376E-07 -7.8132 0.15376E-07 -7.8132 0.10000E+01 0.0000 74 OH- 0.76662E-04 -4.1154 0.73406E-04 -4.1343 0.95753E+00 -0.0188 79 HPO3-2 0.12969E-19 -19.8871 0.11508E-19 -19.9390 0.88734E+00 -0.0519 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.12288E-08 -8.9105 0.11767E-08 -8.9293 0.95760E+00 -0.0188 84 PO4-3 0.10739E-11 -11.9690 0.84009E-12 -12.0757 0.78230E+00 -0.1066 87 H2P2O7-2 0.12236E-18 -18.9124 0.10857E-18 -18.9643 0.88734E+00 -0.0519 88 HP2O7-3 0.35255E-17 -17.4528 0.27544E-17 -17.5600 0.78128E+00 -0.1072 89 P2O7-4 0.12777E-18 -18.8936 0.83601E-19 -19.0778 0.65429E+00 -0.1842 90 H2S,aq 0.88454E-14 -14.0533 0.88445E-14 -14.0533 0.99990E+00 0.0000 97 SO3-2 0.15069E-14 -14.8219 0.13377E-14 -14.8737 0.88768E+00 -0.0517 98 HSO3- 0.68843E-15 -15.1621 0.65923E-15 -15.1810 0.95757E+00 -0.0188 99 HSO4- 0.17894E-09 -9.7473 0.17136E-09 -9.7661 0.95764E+00 -0.0188 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8218337E-08 -.1415933E-03 -.1427097E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999436E+06 0.0000 3 Cl- 0.1379643E-03 0.1379780E-03 0.4891464E+01 4.2249 4 SO4-- 0.2545741E-04 0.2550511E-04 0.2449927E+01 11.5619 5 HCO3- 0.1270251E-04 0.1307036E-04 0.7974729E+00 3.1891 6 HS- 0.3796893E-12 0.6357509E-10 0.2102440E-05 -4.3354 7 Al+++ 0.3601747E-21 0.4607744E-05 0.1243170E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4200617E-03 0.4037218E+02 -3.4276 9 Ca++ 0.6206694E-05 0.6316404E-05 0.2531350E+00 10.9488 10 Mg++ 0.2483201E-07 0.2603460E-07 0.6329184E-03 8.5509 11 Fe++ 0.1465483E-09 0.1308755E-08 0.7308604E-04 6.3219 12 K+ 0.2270905E-04 0.2271825E-04 0.8882801E+00 3.4414 13 Na+ 0.2941605E-03 0.2943902E-03 0.6767599E+01 4.5537 14 Mn++ 0.1940960E-07 0.2673283E-07 0.1468568E-02 8.4440 15 HPO4-- 0.9132756E-08 0.1036267E-07 0.9945439E-03 8.1167 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1758721E-02 -.1415894E-03 -.1617132E-02 0.0000000E+00 2 H2O 0.5550691E+02 0.5550677E+02 0.1435815E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2846980E-04 0.2550441E-04 0.2965398E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2965335E-05 0.6357334E-10 -.2965398E-05 0.0000000E+00 7 Al+++ 0.3488994E-03 0.4607618E-05 0.3442917E-03 0.0000000E+00 8 H4SiO4 0.1114168E-02 0.4200502E-03 0.6941176E-03 0.0000000E+00 9 Ca++ 0.1375363E-03 0.6316231E-05 0.1312201E-03 0.0000000E+00 10 Mg++ 0.8492063E-04 0.2603388E-07 0.8489460E-04 0.0000000E+00 11 Fe++ 0.7629192E-04 0.1308719E-08 0.7629061E-04 0.0000000E+00 12 K+ 0.2271762E-04 0.2271762E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2943821E-03 0.2943821E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1855230E-05 0.2673210E-07 0.1828498E-05 0.0000000E+00 15 HPO4-- 0.6331807E-06 0.1036238E-07 0.6228183E-06 0.0000000E+00 Chg. balance for solid moles: -.2795E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1070000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2076E-06 -6.683 0.1043E-03 -3.982 0.1173 0.3314E-04 clinochlore 0.1698E-04 -4.770 0.9437E-02 -2.025 10.62 0.3590E-02 daphnite 0.1051E-04 -4.978 0.7501E-02 -2.125 8.439 0.2273E-02 chlorite-Mn 0.3657E-06 -6.437 0.2593E-03 -3.586 0.2917 0.8262E-04 hematite 0.1186E-04 -4.926 0.1894E-02 -2.723 2.131 0.3590E-03 kaolinite 0.1411E-04 -4.851 0.3642E-02 -2.439 4.097 0.1401E-02 lawsonite 0.6579E-04 -4.182 0.2067E-01 -1.685 23.26 0.6667E-02 stilbite 0.6439E-04 -4.191 0.4538E-01 -1.343 51.05 0.2117E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1313E-01 0.1313E-01 1.0000 -1.882 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.088891 g Volume = 0.035571 cm3 Porosity: 96.5889% V(tot) - V(min): 0.10072E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1070000 g log = -0.9706 Original solution: 1000.0103000 g Original solution / Rock added: 9345.89 (Water/Rock Ratio), log = 3.9706 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2130E-04 1.0071 0.2189E-04 0.2173E-04 CH4,gas 0.2709E-15 1.0125 0.2799E-15 0.2765E-15 H2,gas 0.5860E-06 1.0005 0.5982E-06 0.5979E-06 H2S,gas 0.2392E-12 0.9960 0.2431E-12 0.2441E-12 S2,gas 0.6076E-32 1.0000 0.6200E-32 0.6200E-32 CO,gas 0.3420E-14 1.0000 0.3490E-14 0.3490E-14 SO3,gas 0.5186E-36 1.0000 0.5292E-36 0.5292E-36 SO2,gas 0.1207E-19 1.0000 0.1232E-19 0.1232E-19 HCl,gas 0.3295E-15 1.0000 0.3362E-15 0.3362E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.18578E-10 102 lawsonite 9.62 9.62 0.00 0.000 -0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.02 -6.36 -2.120 0.10857E+05 -4.660 3 CH4,gas 4.54 -12.71 -17.25 -4.313 0.29457E+05 -15.553 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.54 -14.31 -7.157 0.24439E+05 -12.614 6 S2,gas -7.34 -41.24 -33.91 -5.216 0.57895E+05 -32.208 7 CO,gas 3.21 -12.94 -16.16 -4.971 0.27586E+05 -14.457 8 SO3,gas 17.12 -20.85 -37.98 -9.494 0.64842E+05 -36.276 9 SO2,gas 0.83 -20.78 -21.61 -5.762 0.36896E+05 -19.910 10 HCl,gas 5.19 -11.98 -17.17 -8.586 0.29321E+05 -15.473 11 acmite 7.71 3.98 -3.73 -0.387 0.63657E+04 15 albite-high 0.69 -2.97 -3.66 -0.282 0.62510E+04 16 albite -0.38 -2.97 -2.58 -0.199 0.44122E+04 19 spessartine 24.46 20.57 -3.89 -0.194 0.66349E+04 20 analcite 3.32 0.46 -2.86 -0.318 0.48870E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.91 -4.59 -2.294 0.78345E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.07 -3.04 -1.012 0.51849E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.07 -2.88 -0.961 0.49206E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29428E+04 42 celadonite 5.34 1.04 -4.30 -0.253 0.73397E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12923E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14723E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64760E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82463E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68794E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.46 -3.76 -0.376 0.64125E+04 97 kalsilite 7.58 2.77 -4.81 -0.687 0.82111E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.65 -4.77 -0.477 0.81472E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75919E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20478E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.08 -1.59 -0.123 0.27213E+04 120 muscovite 2.58 1.44 -1.14 -0.067 0.19469E+04 121 paragonite 4.24 2.55 -1.68 -0.099 0.28768E+04 122 nepheline 8.34 3.89 -4.45 -0.636 0.76019E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49716E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40678E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.57 -3.60 -1.200 0.61445E+04 152 rhodonite 7.45 5.02 -2.43 -0.486 0.41480E+04 153 sanidine -1.28 -4.08 -2.80 -0.216 0.47891E+04 155 siderite -2.61 -6.70 -4.09 -1.363 0.69816E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.43 -1.59 -0.047 0.27067E+04 165 stilpnomelane-Mg 27.44 22.58 -4.86 -0.145 0.83061E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83500E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77669E+04 174 tephroite 18.09 13.46 -4.63 -0.661 0.78979E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.01 -3.49 -0.214 0.59588E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.64 -3.30 -0.202 0.56359E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.14 -2.91 -0.178 0.49603E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.77 -2.74 -0.168 0.46732E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.03 -1.31 -0.084 0.22317E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.40 -1.12 -0.072 0.19106E+04 214 gypsum -4.96 -9.91 -4.95 -1.238 0.84521E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59585E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.45 -2.47 -0.190 0.42156E+04 243 an25ab75 2.65 0.18 -2.47 -0.190 0.42134E+04 244 an30ab70 3.28 0.81 -2.47 -0.190 0.42208E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1070000 g New total amount of reactant added: 0.1110000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7207E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1110000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3214064E-03 Osmotic coef. = 0.9893 True ionic strength = .3658295E-03 Chg. balance for total moles = 0.7207E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.79148E-08 -8.1016 0.75791E-08 -8.1204 0.95758E+00 -0.0188 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13209E-03 -3.8791 0.95742E+00 -0.0189 4 SO4-- 0.25460E-04 -4.5941 0.22579E-04 -4.6463 0.88685E+00 -0.0522 5 HCO3- 0.12705E-04 -4.8960 0.12164E-04 -4.9149 0.95746E+00 -0.0189 6 HS- 0.36537E-12 -12.4373 0.34982E-12 -12.4562 0.95743E+00 -0.0189 7 Al+++ 0.32203E-21 -21.4921 0.25124E-21 -21.5999 0.78019E+00 -0.1078 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.57585E-05 -5.2397 0.51059E-05 -5.2919 0.88667E+00 -0.0522 10 Mg++ 0.23039E-07 -7.6375 0.20425E-07 -7.6898 0.88656E+00 -0.0523 11 Fe++ 0.13596E-09 -9.8666 0.12054E-09 -9.9189 0.88659E+00 -0.0523 12 K+ 0.23558E-04 -4.6279 0.22556E-04 -4.6467 0.95747E+00 -0.0189 13 Na+ 0.29917E-03 -3.5241 0.28643E-03 -3.5430 0.95742E+00 -0.0189 14 Mn++ 0.18032E-07 -7.7439 0.15988E-07 -7.7962 0.88661E+00 -0.0523 15 HPO4-- 0.98556E-08 -8.0063 0.87405E-08 -8.0585 0.88685E+00 -0.0522 16 HSiO3- 0.48071E-04 -4.3181 0.46024E-04 -4.3370 0.95742E+00 -0.0189 17 Ca(HSiO3)+ 0.55894E-08 -8.2526 0.53517E-08 -8.2715 0.95747E+00 -0.0189 18 Mg(HSiO3)+ 0.27827E-10 -10.5555 0.26643E-10 -10.5744 0.95747E+00 -0.0189 19 NaHSiO3,aq 0.21321E-06 -6.6712 0.21321E-06 -6.6712 0.10000E+01 0.0000 20 AlO+ 0.62145E-12 -12.2066 0.59502E-12 -12.2255 0.95747E+00 -0.0189 21 AlOH+2 0.25327E-16 -16.5964 0.22456E-16 -16.6487 0.88663E+00 -0.0523 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.47697E-05 -5.3215 0.45664E-05 -5.3404 0.95738E+00 -0.0189 24 CH4,aq 0.18309E-18 -18.7373 0.18307E-18 -18.7374 0.99990E+00 0.0000 29 CO,aq 0.22548E-17 -17.6469 0.22548E-17 -17.6469 0.10000E+01 0.0000 30 CO2,aq 0.19702E-06 -6.7055 0.19700E-06 -6.7055 0.99990E+00 0.0000 31 CO3-2 0.15808E-06 -6.8011 0.14019E-06 -6.8533 0.88679E+00 -0.0522 32 CaCO3,aq 0.89752E-08 -8.0470 0.89752E-08 -8.0470 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.16558E-08 -8.7810 0.15854E-08 -8.7999 0.95747E+00 -0.0189 34 CaCl+ 0.11399E-08 -8.9431 0.10915E-08 -8.9620 0.95747E+00 -0.0189 35 CaCl2,aq 0.34252E-13 -13.4653 0.34252E-13 -13.4653 0.10000E+01 0.0000 36 CaOH+ 0.50146E-07 -7.2998 0.48013E-07 -7.3186 0.95747E+00 -0.0189 37 CaSO4,aq 0.36609E-07 -7.4364 0.36609E-07 -7.4364 0.10000E+01 0.0000 38 HCl,aq 0.18345E-12 -12.7365 0.18345E-12 -12.7365 0.10000E+01 0.0000 43 FeCl+ 0.26322E-13 -13.5797 0.25203E-13 -13.5986 0.95747E+00 -0.0189 46 FeO,aq 0.81559E-10 -10.0885 0.81559E-10 -10.0885 0.10000E+01 0.0000 47 FeOH+ 0.54071E-09 -9.2670 0.51771E-09 -9.2859 0.95747E+00 -0.0189 48 HFeO2- 0.11760E-09 -9.9296 0.11259E-09 -9.9485 0.95742E+00 -0.0189 49 FeO+ 0.60420E-13 -13.2188 0.57850E-13 -13.2377 0.95747E+00 -0.0189 50 FeOH+2 0.94438E-19 -19.0249 0.83732E-19 -19.0771 0.88663E+00 -0.0523 51 FeO2- 0.21524E-09 -9.6671 0.20607E-09 -9.6860 0.95742E+00 -0.0189 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45568E-09 -9.3413 0.45563E-09 -9.3414 0.99990E+00 0.0000 54 KCl,aq 0.54000E-10 -10.2676 0.54000E-10 -10.2676 0.10000E+01 0.0000 55 KHSO4,aq 0.10914E-16 -16.9620 0.10914E-16 -16.9620 0.10000E+01 0.0000 56 KOH,aq 0.12710E-08 -8.8959 0.12710E-08 -8.8959 0.10000E+01 0.0000 57 KSO4- 0.82545E-08 -8.0833 0.79030E-08 -8.1022 0.95742E+00 -0.0189 58 MgCO3,aq 0.89995E-11 -11.0458 0.89995E-11 -11.0458 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.67684E-11 -11.1695 0.64805E-11 -11.1884 0.95747E+00 -0.0189 60 MgCl+ 0.41331E-11 -11.3837 0.39573E-11 -11.4026 0.95747E+00 -0.0189 61 MgOH+ 0.11100E-08 -8.9547 0.10628E-08 -8.9735 0.95747E+00 -0.0189 63 MnO,aq 0.28823E-09 -9.5403 0.28823E-09 -9.5403 0.10000E+01 0.0000 64 MnOH+ 0.66620E-08 -8.1764 0.63787E-08 -8.1953 0.95747E+00 -0.0189 65 MnO2-2 0.18778E-15 -15.7263 0.16653E-15 -15.7785 0.88679E+00 -0.0522 66 HMnO2- 0.28881E-12 -12.5394 0.27651E-12 -12.5583 0.95742E+00 -0.0189 69 MnCl+ 0.13582E-10 -10.8670 0.13004E-10 -10.8859 0.95747E+00 -0.0189 70 MnSO4,aq 0.10421E-09 -9.9821 0.10421E-09 -9.9821 0.10000E+01 0.0000 71 NaCl,aq 0.12539E-07 -7.9018 0.12539E-07 -7.9018 0.10000E+01 0.0000 72 NaOH,aq 0.16237E-07 -7.7895 0.16237E-07 -7.7895 0.10000E+01 0.0000 74 OH- 0.79626E-04 -4.0989 0.76233E-04 -4.1179 0.95738E+00 -0.0189 79 HPO3-2 0.13995E-19 -19.8540 0.12411E-19 -19.9062 0.88679E+00 -0.0522 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.12763E-08 -8.8940 0.12220E-08 -8.9129 0.95745E+00 -0.0189 84 PO4-3 0.12044E-11 -11.9192 0.94091E-12 -12.0265 0.78123E+00 -0.1072 87 H2P2O7-2 0.13204E-18 -18.8793 0.11710E-18 -18.9315 0.88679E+00 -0.0522 88 HP2O7-3 0.39541E-17 -17.4030 0.30850E-17 -17.5108 0.78020E+00 -0.1078 89 P2O7-4 0.14898E-18 -18.8269 0.97239E-19 -19.0122 0.65268E+00 -0.1853 90 H2S,aq 0.81950E-14 -14.0864 0.81942E-14 -14.0865 0.99990E+00 0.0000 97 SO3-2 0.15070E-14 -14.8219 0.13369E-14 -14.8739 0.88714E+00 -0.0520 98 HSO3- 0.66263E-15 -15.1787 0.63441E-15 -15.1976 0.95742E+00 -0.0189 99 HSO4- 0.17224E-09 -9.7639 0.16492E-09 -9.7827 0.95750E+00 -0.0189 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7914839E-08 -.1470804E-03 -.1482400E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999433E+06 0.0000 3 Cl- 0.1379643E-03 0.1379781E-03 0.4891467E+01 4.2413 4 SO4-- 0.2546005E-04 0.2550513E-04 0.2449928E+01 11.5945 5 HCO3- 0.1270462E-04 0.1307037E-04 0.7974733E+00 3.2055 6 HS- 0.3653749E-12 0.6255064E-10 0.2068561E-05 -4.3358 7 Al+++ 0.3220256E-21 0.4785298E-05 0.1291074E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4218622E-03 0.4054522E+02 -3.4276 9 Ca++ 0.5758530E-05 0.5862645E-05 0.2349501E+00 10.9488 10 Mg++ 0.2303886E-07 0.2419661E-07 0.5882355E-03 8.5509 11 Fe++ 0.1359617E-09 0.1289794E-08 0.7202713E-04 6.3219 12 K+ 0.2355797E-04 0.2356754E-04 0.9214872E+00 3.4736 13 Na+ 0.2991695E-03 0.2994115E-03 0.6883030E+01 4.5774 14 Mn++ 0.1803241E-07 0.2510077E-07 0.1378910E-02 8.4446 15 HPO4-- 0.9855635E-08 0.1113319E-07 0.1068493E-02 8.1823 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1824955E-02 -.1470762E-03 -.1677879E-02 0.0000000E+00 2 H2O 0.5550686E+02 0.5550672E+02 0.1351944E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2858066E-04 0.2550441E-04 0.3076251E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3076188E-05 0.6254888E-10 -.3076251E-05 0.0000000E+00 7 Al+++ 0.3619423E-03 0.4785163E-05 0.3571572E-03 0.0000000E+00 8 H4SiO4 0.1155819E-02 0.4218503E-03 0.7339686E-03 0.0000000E+00 9 Ca++ 0.1421369E-03 0.5862480E-05 0.1362744E-03 0.0000000E+00 10 Mg++ 0.8809524E-04 0.2419593E-07 0.8807104E-04 0.0000000E+00 11 Fe++ 0.7914395E-04 0.1289757E-08 0.7914266E-04 0.0000000E+00 12 K+ 0.2356688E-04 0.2356688E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2994030E-03 0.2994030E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1924584E-05 0.2510006E-07 0.1899484E-05 0.0000000E+00 15 HPO4-- 0.6568510E-06 0.1113288E-07 0.6457181E-06 0.0000000E+00 Chg. balance for solid moles: 0.1137E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1110000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2152E-06 -6.667 0.1081E-03 -3.966 0.1159 0.3436E-04 clinochlore 0.1761E-04 -4.754 0.9791E-02 -2.009 10.49 0.3724E-02 daphnite 0.1091E-04 -4.962 0.7782E-02 -2.109 8.340 0.2358E-02 chlorite-Mn 0.3799E-06 -6.420 0.2693E-03 -3.570 0.2887 0.8583E-04 hematite 0.1231E-04 -4.910 0.1965E-02 -2.707 2.106 0.3725E-03 kaolinite 0.1448E-04 -4.839 0.3738E-02 -2.427 4.006 0.1438E-02 lawsonite 0.6562E-04 -4.183 0.2062E-01 -1.686 22.10 0.6649E-02 stilbite 0.6958E-04 -4.158 0.4904E-01 -1.309 52.55 0.2287E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1314E-01 0.1314E-01 1.0000 -1.881 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.093308 g Volume = 0.037534 cm3 Porosity: 96.4062% V(tot) - V(min): 0.10069E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1110000 g log = -0.9547 Original solution: 1000.0103000 g Original solution / Rock added: 9009.10 (Water/Rock Ratio), log = 3.9547 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.2051E-04 1.0071 0.2108E-04 0.2093E-04 CH4,gas 0.2608E-15 1.0125 0.2695E-15 0.2661E-15 H2,gas 0.5860E-06 1.0005 0.5982E-06 0.5979E-06 H2S,gas 0.2216E-12 0.9960 0.2253E-12 0.2261E-12 S2,gas 0.5217E-32 1.0000 0.5323E-32 0.5323E-32 CO,gas 0.3293E-14 1.0000 0.3360E-14 0.3360E-14 SO3,gas 0.4806E-36 1.0000 0.4904E-36 0.4904E-36 SO2,gas 0.1119E-19 1.0000 0.1141E-19 0.1141E-19 HCl,gas 0.3173E-15 1.0000 0.3237E-15 0.3237E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.04 -6.38 -2.125 0.10885E+05 -4.676 3 CH4,gas 4.54 -12.72 -17.27 -4.317 0.29485E+05 -15.570 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.58 -14.35 -7.173 0.24496E+05 -12.647 6 S2,gas -7.34 -41.31 -33.97 -5.227 0.58008E+05 -32.274 7 CO,gas 3.21 -12.96 -16.17 -4.976 0.27614E+05 -14.474 8 SO3,gas 17.12 -20.89 -38.01 -9.502 0.64898E+05 -36.309 9 SO2,gas 0.83 -20.81 -21.64 -5.771 0.36952E+05 -19.943 10 HCl,gas 5.19 -12.00 -17.19 -8.594 0.29349E+05 -15.490 11 acmite 7.71 4.01 -3.70 -0.385 0.63253E+04 15 albite-high 0.69 -2.94 -3.64 -0.280 0.62106E+04 16 albite -0.38 -2.94 -2.56 -0.197 0.43718E+04 19 spessartine 24.46 20.57 -3.88 -0.194 0.66319E+04 20 analcite 3.32 0.48 -2.84 -0.315 0.48466E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.94 -4.62 -2.311 0.78909E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.09 -3.05 -1.018 0.52129E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.09 -2.90 -0.966 0.49487E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29428E+04 42 celadonite 5.34 1.08 -4.27 -0.251 0.72846E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12923E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14713E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64761E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82463E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68795E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.48 -3.73 -0.373 0.63721E+04 97 kalsilite 7.58 2.81 -4.78 -0.682 0.81560E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.62 -4.74 -0.474 0.80921E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75919E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20478E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.05 -1.56 -0.120 0.26662E+04 120 muscovite 2.58 1.47 -1.11 -0.065 0.18918E+04 121 paragonite 4.24 2.58 -1.66 -0.098 0.28364E+04 122 nepheline 8.34 3.91 -4.43 -0.633 0.75614E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49717E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40668E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.59 -3.61 -1.205 0.61715E+04 152 rhodonite 7.45 5.02 -2.43 -0.486 0.41470E+04 153 sanidine -1.28 -4.05 -2.77 -0.213 0.47340E+04 155 siderite -2.61 -6.71 -4.11 -1.368 0.70096E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.45 -1.57 -0.047 0.26793E+04 165 stilpnomelane-Mg 27.44 22.59 -4.85 -0.145 0.82785E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83500E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77669E+04 174 tephroite 18.09 13.46 -4.62 -0.661 0.78959E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -5.00 -3.48 -0.213 0.59406E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.64 -3.29 -0.202 0.56226E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.13 -2.89 -0.177 0.49421E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.77 -2.73 -0.167 0.46598E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.04 -1.30 -0.083 0.22135E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.41 -1.11 -0.071 0.18973E+04 214 gypsum -4.96 -9.94 -4.98 -1.246 0.85085E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59585E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.43 -2.45 -0.188 0.41832E+04 243 an25ab75 2.65 0.20 -2.45 -0.188 0.41831E+04 244 an30ab70 3.28 0.82 -2.46 -0.189 0.41925E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1110000 g New total amount of reactant added: 0.1150000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7207E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1150000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3243245E-03 Osmotic coef. = 0.9892 True ionic strength = .3704627E-03 Chg. balance for total moles = 0.7207E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.76286E-08 -8.1176 0.73038E-08 -8.1364 0.95743E+00 -0.0189 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13207E-03 -3.8792 0.95727E+00 -0.0190 4 SO4-- 0.25462E-04 -4.5941 0.22567E-04 -4.6465 0.88629E+00 -0.0524 5 HCO3- 0.12706E-04 -4.8960 0.12164E-04 -4.9149 0.95731E+00 -0.0189 6 HS- 0.35188E-12 -12.4536 0.33685E-12 -12.4726 0.95728E+00 -0.0190 7 Al+++ 0.28861E-21 -21.5397 0.22485E-21 -21.6481 0.77909E+00 -0.1084 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.53512E-05 -5.2715 0.47418E-05 -5.3241 0.88612E+00 -0.0525 10 Mg++ 0.21409E-07 -7.6694 0.18969E-07 -7.7220 0.88601E+00 -0.0526 11 Fe++ 0.12634E-09 -9.8985 0.11194E-09 -9.9510 0.88603E+00 -0.0526 12 K+ 0.24407E-04 -4.6125 0.23365E-04 -4.6314 0.95732E+00 -0.0189 13 Na+ 0.30418E-03 -3.5169 0.29118E-03 -3.5358 0.95727E+00 -0.0190 14 Mn++ 0.16777E-07 -7.7753 0.14865E-07 -7.8278 0.88605E+00 -0.0525 15 HPO4-- 0.10619E-07 -7.9739 0.94117E-08 -8.0263 0.88629E+00 -0.0524 16 HSiO3- 0.49890E-04 -4.3020 0.47759E-04 -4.3209 0.95727E+00 -0.0190 17 Ca(HSiO3)+ 0.53873E-08 -8.2686 0.51574E-08 -8.2876 0.95732E+00 -0.0189 18 Mg(HSiO3)+ 0.26820E-10 -10.5715 0.25676E-10 -10.5905 0.95732E+00 -0.0189 19 NaHSiO3,aq 0.22492E-06 -6.6480 0.22492E-06 -6.6480 0.10000E+01 0.0000 20 AlO+ 0.59897E-12 -12.2226 0.57341E-12 -12.2415 0.95732E+00 -0.0189 21 AlOH+2 0.23535E-16 -16.6283 0.20854E-16 -16.6808 0.88608E+00 -0.0525 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.49502E-05 -5.3054 0.47385E-05 -5.3244 0.95723E+00 -0.0190 24 CH4,aq 0.17638E-18 -18.7535 0.17637E-18 -18.7536 0.99990E+00 0.0000 29 CO,aq 0.21727E-17 -17.6630 0.21727E-17 -17.6630 0.10000E+01 0.0000 30 CO2,aq 0.18985E-06 -6.7216 0.18983E-06 -6.7216 0.99990E+00 0.0000 31 CO3-2 0.16414E-06 -6.7848 0.14547E-06 -6.8372 0.88624E+00 -0.0524 32 CaCO3,aq 0.86489E-08 -8.0630 0.86489E-08 -8.0630 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.15379E-08 -8.8131 0.14723E-08 -8.8320 0.95732E+00 -0.0189 34 CaCl+ 0.10586E-08 -8.9753 0.10135E-08 -8.9942 0.95732E+00 -0.0189 35 CaCl2,aq 0.31799E-13 -13.4976 0.31799E-13 -13.4976 0.10000E+01 0.0000 36 CaOH+ 0.48332E-07 -7.3158 0.46270E-07 -7.3347 0.95732E+00 -0.0189 37 CaSO4,aq 0.33980E-07 -7.4688 0.33980E-07 -7.4688 0.10000E+01 0.0000 38 HCl,aq 0.17676E-12 -12.7526 0.17676E-12 -12.7526 0.10000E+01 0.0000 43 FeCl+ 0.24444E-13 -13.6118 0.23401E-13 -13.6308 0.95732E+00 -0.0189 46 FeO,aq 0.81556E-10 -10.0885 0.81556E-10 -10.0885 0.10000E+01 0.0000 47 FeOH+ 0.52113E-09 -9.2831 0.49889E-09 -9.3020 0.95732E+00 -0.0189 48 HFeO2- 0.12205E-09 -9.9135 0.11683E-09 -9.9324 0.95727E+00 -0.0190 49 FeO+ 0.58235E-13 -13.2348 0.55749E-13 -13.2538 0.95732E+00 -0.0189 50 FeOH+2 0.87758E-19 -19.0567 0.77760E-19 -19.1092 0.88608E+00 -0.0525 51 FeO2- 0.22338E-09 -9.6509 0.21384E-09 -9.6699 0.95727E+00 -0.0190 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45565E-09 -9.3414 0.45560E-09 -9.3414 0.99990E+00 0.0000 54 KCl,aq 0.55928E-10 -10.2524 0.55928E-10 -10.2524 0.10000E+01 0.0000 55 KHSO4,aq 0.10889E-16 -16.9630 0.10889E-16 -16.9630 0.10000E+01 0.0000 56 KOH,aq 0.13662E-08 -8.8645 0.13662E-08 -8.8645 0.10000E+01 0.0000 57 KSO4- 0.85474E-08 -8.0682 0.81822E-08 -8.0871 0.95727E+00 -0.0190 58 MgCO3,aq 0.86723E-11 -11.0619 0.86723E-11 -11.0619 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.62864E-11 -11.2016 0.60181E-11 -11.2205 0.95732E+00 -0.0189 60 MgCl+ 0.38383E-11 -11.4159 0.36745E-11 -11.4348 0.95732E+00 -0.0189 61 MgOH+ 0.10699E-08 -8.9707 0.10242E-08 -8.9896 0.95732E+00 -0.0189 63 MnO,aq 0.28858E-09 -9.5397 0.28858E-09 -9.5397 0.10000E+01 0.0000 64 MnOH+ 0.64287E-08 -8.1919 0.61544E-08 -8.2108 0.95732E+00 -0.0189 65 MnO2-2 0.20257E-15 -15.6934 0.17953E-15 -15.7459 0.88624E+00 -0.0524 66 HMnO2- 0.30009E-12 -12.5227 0.28727E-12 -12.5417 0.95727E+00 -0.0190 69 MnCl+ 0.12628E-10 -10.8987 0.12089E-10 -10.9176 0.95732E+00 -0.0189 70 MnSO4,aq 0.96846E-10 -10.0139 0.96846E-10 -10.0139 0.10000E+01 0.0000 71 NaCl,aq 0.12744E-07 -7.8947 0.12744E-07 -7.8947 0.10000E+01 0.0000 72 NaOH,aq 0.17129E-07 -7.7663 0.17129E-07 -7.7663 0.10000E+01 0.0000 74 OH- 0.82640E-04 -4.0828 0.79106E-04 -4.1018 0.95723E+00 -0.0190 79 HPO3-2 0.15078E-19 -19.8217 0.13363E-19 -19.8741 0.88624E+00 -0.0524 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.13247E-08 -8.8779 0.12681E-08 -8.8968 0.95730E+00 -0.0190 84 PO4-3 0.13477E-11 -11.8704 0.10514E-11 -11.9783 0.78014E+00 -0.1078 87 H2P2O7-2 0.14227E-18 -18.8469 0.12609E-18 -18.8993 0.88624E+00 -0.0524 88 HP2O7-3 0.44244E-17 -17.3541 0.34471E-17 -17.4626 0.77910E+00 -0.1084 89 P2O7-4 0.17318E-18 -18.7615 0.11275E-18 -18.9479 0.65105E+00 -0.1864 90 H2S,aq 0.76046E-14 -14.1189 0.76038E-14 -14.1190 0.99990E+00 0.0000 97 SO3-2 0.15070E-14 -14.8219 0.13361E-14 -14.8742 0.88659E+00 -0.0523 98 HSO3- 0.63828E-15 -15.1950 0.61101E-15 -15.2140 0.95727E+00 -0.0190 99 HSO4- 0.16592E-09 -9.7801 0.15885E-09 -9.7990 0.95735E+00 -0.0189 Charge balance for all species = 0.7207E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7628576E-08 -.1526595E-03 -.1538631E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999430E+06 0.0000 3 Cl- 0.1379643E-03 0.1379782E-03 0.4891469E+01 4.2573 4 SO4-- 0.2546242E-04 0.2550515E-04 0.2449929E+01 11.6264 5 HCO3- 0.1270619E-04 0.1307038E-04 0.7974736E+00 3.2215 6 HS- 0.3518828E-12 0.6151128E-10 0.2034188E-05 -4.3361 7 Al+++ 0.2886061E-21 0.4965835E-05 0.1339782E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4236932E-03 0.4072118E+02 -3.4276 9 Ca++ 0.5351212E-05 0.5450157E-05 0.2184193E+00 10.9488 10 Mg++ 0.2140917E-07 0.2252465E-07 0.5475889E-03 8.5509 11 Fe++ 0.1263408E-09 0.1273188E-08 0.7109978E-04 6.3219 12 K+ 0.2440687E-04 0.2441684E-04 0.9546944E+00 3.5050 13 Na+ 0.3041781E-03 0.3044329E-03 0.6998462E+01 4.6006 14 Mn++ 0.1677682E-07 0.2360389E-07 0.1296679E-02 8.4451 15 HPO4-- 0.1061913E-07 0.1194514E-07 0.1146419E-02 8.2466 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1891189E-02 -.1526551E-03 -.1738534E-02 0.0000000E+00 2 H2O 0.5550681E+02 0.5550668E+02 0.1267918E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2869151E-04 0.2550441E-04 0.3187104E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3187042E-05 0.6150949E-10 -.3187104E-05 0.0000000E+00 7 Al+++ 0.3749853E-03 0.4965691E-05 0.3700196E-03 0.0000000E+00 8 H4SiO4 0.1197470E-02 0.4236809E-03 0.7737891E-03 0.0000000E+00 9 Ca++ 0.1467375E-03 0.5449999E-05 0.1412875E-03 0.0000000E+00 10 Mg++ 0.9126984E-04 0.2252400E-07 0.9124732E-04 0.0000000E+00 11 Fe++ 0.8199599E-04 0.1273151E-08 0.8199472E-04 0.0000000E+00 12 K+ 0.2441614E-04 0.2441614E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3044240E-03 0.3044240E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1993939E-05 0.2360321E-07 0.1970335E-05 0.0000000E+00 15 HPO4-- 0.6805213E-06 0.1194480E-07 0.6685765E-06 0.0000000E+00 Chg. balance for solid moles: 0.6607E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1150000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2229E-06 -6.652 0.1119E-03 -3.951 0.1146 0.3557E-04 clinochlore 0.1825E-04 -4.739 0.1014E-01 -1.994 10.38 0.3858E-02 daphnite 0.1130E-04 -4.947 0.8062E-02 -2.094 8.250 0.2443E-02 chlorite-Mn 0.3941E-06 -6.404 0.2794E-03 -3.554 0.2859 0.8903E-04 hematite 0.1275E-04 -4.895 0.2036E-02 -2.691 2.083 0.3859E-03 kaolinite 0.1489E-04 -4.827 0.3845E-02 -2.415 3.935 0.1479E-02 lawsonite 0.6541E-04 -4.184 0.2055E-01 -1.687 21.03 0.6628E-02 stilbite 0.7477E-04 -4.126 0.5269E-01 -1.278 53.92 0.2457E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1316E-01 0.1316E-01 1.0000 -1.881 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.097720 g Volume = 0.039494 cm3 Porosity: 96.2242% V(tot) - V(min): 0.10065E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1150000 g log = -0.9393 Original solution: 1000.0103000 g Original solution / Rock added: 8695.74 (Water/Rock Ratio), log = 3.9393 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1977E-04 1.0071 0.2031E-04 0.2017E-04 CH4,gas 0.2513E-15 1.0125 0.2596E-15 0.2564E-15 H2,gas 0.5859E-06 1.0005 0.5982E-06 0.5978E-06 H2S,gas 0.2057E-12 0.9960 0.2090E-12 0.2099E-12 S2,gas 0.4492E-32 1.0000 0.4584E-32 0.4584E-32 CO,gas 0.3173E-14 1.0000 0.3238E-14 0.3238E-14 SO3,gas 0.4461E-36 1.0000 0.4552E-36 0.4552E-36 SO2,gas 0.1038E-19 1.0000 0.1059E-19 0.1059E-19 HCl,gas 0.3057E-15 1.0000 0.3119E-15 0.3119E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.05 -6.39 -2.130 0.10913E+05 -4.692 3 CH4,gas 4.54 -12.74 -17.28 -4.321 0.29513E+05 -15.586 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.61 -14.38 -7.189 0.24551E+05 -12.680 6 S2,gas -7.34 -41.37 -34.04 -5.237 0.58119E+05 -32.339 7 CO,gas 3.21 -12.97 -16.19 -4.981 0.27642E+05 -14.490 8 SO3,gas 17.12 -20.92 -38.04 -9.510 0.64954E+05 -36.342 9 SO2,gas 0.83 -20.84 -21.67 -5.780 0.37008E+05 -19.975 10 HCl,gas 5.19 -12.02 -17.20 -8.602 0.29377E+05 -15.506 11 acmite 7.71 4.03 -3.68 -0.382 0.62857E+04 15 albite-high 0.69 -2.92 -3.61 -0.278 0.61709E+04 16 albite -0.38 -2.92 -2.54 -0.195 0.43321E+04 19 spessartine 24.46 20.57 -3.88 -0.194 0.66293E+04 20 analcite 3.32 0.51 -2.82 -0.313 0.48070E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -9.97 -4.65 -2.327 0.79462E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.10 -3.07 -1.023 0.52403E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.10 -2.91 -0.971 0.49761E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29429E+04 42 celadonite 5.34 1.11 -4.23 -0.249 0.72310E+04 43 celadonite-Fe 3.88 -1.12 -5.00 -0.294 0.85354E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12923E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14704E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64761E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82464E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68795E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.51 -3.71 -0.371 0.63325E+04 97 kalsilite 7.58 2.84 -4.75 -0.678 0.81024E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.59 -4.71 -0.471 0.80385E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75919E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20478E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -4.02 -1.53 -0.118 0.26126E+04 120 muscovite 2.58 1.51 -1.08 -0.063 0.18382E+04 121 paragonite 4.24 2.60 -1.64 -0.096 0.27968E+04 122 nepheline 8.34 3.93 -4.41 -0.629 0.75218E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49717E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40659E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.61 -3.63 -1.210 0.61981E+04 152 rhodonite 7.45 5.02 -2.43 -0.486 0.41461E+04 153 sanidine -1.28 -4.02 -2.74 -0.211 0.46804E+04 155 siderite -2.61 -6.73 -4.12 -1.374 0.70371E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.46 -1.55 -0.046 0.26526E+04 165 stilpnomelane-Mg 27.44 22.61 -4.83 -0.144 0.82518E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83501E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77669E+04 174 tephroite 18.09 13.46 -4.62 -0.660 0.78941E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.99 -3.47 -0.212 0.59229E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.63 -3.29 -0.201 0.56095E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.12 -2.88 -0.177 0.49244E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.76 -2.72 -0.167 0.46467E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.05 -1.29 -0.083 0.21959E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.42 -1.10 -0.071 0.18842E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59586E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.41 -2.43 -0.187 0.41515E+04 243 an25ab75 2.65 0.21 -2.43 -0.187 0.41533E+04 244 an30ab70 3.28 0.84 -2.44 -0.188 0.41648E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1150000 g New total amount of reactant added: 0.1190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1190000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3273300E-03 Osmotic coef. = 0.9892 True ionic strength = .3752071E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.73586E-08 -8.1332 0.70443E-08 -8.1522 0.95728E+00 -0.0190 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13205E-03 -3.8793 0.95712E+00 -0.0190 4 SO4-- 0.25465E-04 -4.5941 0.22555E-04 -4.6468 0.88573E+00 -0.0527 5 HCO3- 0.12707E-04 -4.8959 0.12163E-04 -4.9150 0.95716E+00 -0.0190 6 HS- 0.33917E-12 -12.4696 0.32463E-12 -12.4886 0.95712E+00 -0.0190 7 Al+++ 0.25929E-21 -21.5862 0.20172E-21 -21.6953 0.77797E+00 -0.1090 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.49808E-05 -5.3027 0.44108E-05 -5.3555 0.88555E+00 -0.0528 10 Mg++ 0.19927E-07 -7.7006 0.17644E-07 -7.7534 0.88544E+00 -0.0528 11 Fe++ 0.11759E-09 -9.9296 0.10412E-09 -9.9824 0.88547E+00 -0.0528 12 K+ 0.25256E-04 -4.5976 0.24174E-04 -4.6167 0.95716E+00 -0.0190 13 Na+ 0.30919E-03 -3.5098 0.29593E-03 -3.5288 0.95712E+00 -0.0190 14 Mn++ 0.15632E-07 -7.8060 0.13842E-07 -7.8588 0.88549E+00 -0.0528 15 HPO4-- 0.11423E-07 -7.9422 0.10118E-07 -7.9949 0.88573E+00 -0.0527 16 HSiO3- 0.51737E-04 -4.2862 0.49518E-04 -4.3052 0.95712E+00 -0.0190 17 Ca(HSiO3)+ 0.51967E-08 -8.2843 0.49741E-08 -8.3033 0.95717E+00 -0.0190 18 Mg(HSiO3)+ 0.25871E-10 -10.5872 0.24763E-10 -10.6062 0.95717E+00 -0.0190 19 NaHSiO3,aq 0.23701E-06 -6.6252 0.23701E-06 -6.6252 0.10000E+01 0.0000 20 AlO+ 0.57778E-12 -12.2382 0.55303E-12 -12.2572 0.95717E+00 -0.0190 21 AlOH+2 0.21906E-16 -16.6594 0.19398E-16 -16.7122 0.88551E+00 -0.0528 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.51334E-05 -5.2896 0.49131E-05 -5.3086 0.95707E+00 -0.0191 24 CH4,aq 0.17006E-18 -18.7694 0.17005E-18 -18.7694 0.99990E+00 0.0000 29 CO,aq 0.20952E-17 -17.6788 0.20952E-17 -17.6788 0.10000E+01 0.0000 30 CO2,aq 0.18309E-06 -6.7373 0.18307E-06 -6.7374 0.99990E+00 0.0000 31 CO3-2 0.17028E-06 -6.7688 0.15081E-06 -6.8216 0.88567E+00 -0.0527 32 CaCO3,aq 0.83409E-08 -8.0788 0.83409E-08 -8.0788 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.14307E-08 -8.8445 0.13694E-08 -8.8635 0.95717E+00 -0.0190 34 CaCl+ 0.98473E-09 -9.0067 0.94256E-09 -9.0257 0.95717E+00 -0.0190 35 CaCl2,aq 0.29570E-13 -13.5292 0.29570E-13 -13.5292 0.10000E+01 0.0000 36 CaOH+ 0.46622E-07 -7.3314 0.44625E-07 -7.3504 0.95717E+00 -0.0190 37 CaSO4,aq 0.31590E-07 -7.5004 0.31590E-07 -7.5004 0.10000E+01 0.0000 38 HCl,aq 0.17045E-12 -12.7684 0.17045E-12 -12.7684 0.10000E+01 0.0000 43 FeCl+ 0.22737E-13 -13.6433 0.21763E-13 -13.6623 0.95717E+00 -0.0190 46 FeO,aq 0.81554E-10 -10.0886 0.81554E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.50268E-09 -9.2987 0.48115E-09 -9.3177 0.95717E+00 -0.0190 48 HFeO2- 0.12656E-09 -9.8977 0.12114E-09 -9.9167 0.95712E+00 -0.0190 49 FeO+ 0.56174E-13 -13.2505 0.53768E-13 -13.2695 0.95717E+00 -0.0190 50 FeOH+2 0.81683E-19 -19.0879 0.72331E-19 -19.1407 0.88551E+00 -0.0528 51 FeO2- 0.23165E-09 -9.6352 0.22172E-09 -9.6542 0.95712E+00 -0.0190 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45562E-09 -9.3414 0.45558E-09 -9.3414 0.99990E+00 0.0000 54 KCl,aq 0.57855E-10 -10.2377 0.57855E-10 -10.2377 0.10000E+01 0.0000 55 KHSO4,aq 0.10859E-16 -16.9642 0.10859E-16 -16.9642 0.10000E+01 0.0000 56 KOH,aq 0.14655E-08 -8.8340 0.14655E-08 -8.8340 0.10000E+01 0.0000 57 KSO4- 0.88398E-08 -8.0536 0.84607E-08 -8.0726 0.95712E+00 -0.0190 58 MgCO3,aq 0.83634E-11 -11.0776 0.83634E-11 -11.0776 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.58480E-11 -11.2330 0.55975E-11 -11.2520 0.95717E+00 -0.0190 60 MgCl+ 0.35703E-11 -11.4473 0.34174E-11 -11.4663 0.95717E+00 -0.0190 61 MgOH+ 0.10320E-08 -8.9863 0.98781E-09 -9.0053 0.95717E+00 -0.0190 63 MnO,aq 0.28888E-09 -9.5393 0.28888E-09 -9.5393 0.10000E+01 0.0000 64 MnOH+ 0.62077E-08 -8.2071 0.59419E-08 -8.2261 0.95717E+00 -0.0190 65 MnO2-2 0.21814E-15 -15.6613 0.19320E-15 -15.7140 0.88567E+00 -0.0527 66 HMnO2- 0.31153E-12 -12.5065 0.29817E-12 -12.5255 0.95712E+00 -0.0190 69 MnCl+ 0.11759E-10 -10.9296 0.11255E-10 -10.9486 0.95717E+00 -0.0190 70 MnSO4,aq 0.90129E-10 -10.0451 0.90129E-10 -10.0451 0.10000E+01 0.0000 71 NaCl,aq 0.12950E-07 -7.8877 0.12950E-07 -7.8877 0.10000E+01 0.0000 72 NaOH,aq 0.18049E-07 -7.7435 0.18049E-07 -7.7435 0.10000E+01 0.0000 74 OH- 0.85699E-04 -4.0670 0.82020E-04 -4.0861 0.95707E+00 -0.0191 79 HPO3-2 0.16219E-19 -19.7900 0.14365E-19 -19.8427 0.88567E+00 -0.0527 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.13737E-08 -8.8621 0.13148E-08 -8.8811 0.95714E+00 -0.0190 84 PO4-3 0.15043E-11 -11.8227 0.11719E-11 -11.9311 0.77903E+00 -0.1084 87 H2P2O7-2 0.15305E-18 -18.8152 0.13555E-18 -18.8679 0.88567E+00 -0.0527 88 HP2O7-3 0.49389E-17 -17.3064 0.38423E-17 -17.4154 0.77798E+00 -0.1090 89 P2O7-4 0.20066E-18 -18.6975 0.13031E-18 -18.8850 0.64939E+00 -0.1875 90 H2S,aq 0.70682E-14 -14.1507 0.70675E-14 -14.1507 0.99990E+00 0.0000 97 SO3-2 0.15070E-14 -14.8219 0.13353E-14 -14.8744 0.88603E+00 -0.0526 98 HSO3- 0.61532E-15 -15.2109 0.58893E-15 -15.2299 0.95712E+00 -0.0190 99 HSO4- 0.15996E-09 -9.7960 0.15312E-09 -9.8150 0.95719E+00 -0.0190 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7358634E-08 -.1583218E-03 -.1595700E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999427E+06 0.0000 3 Cl- 0.1379643E-03 0.1379783E-03 0.4891471E+01 4.2729 4 SO4-- 0.2546455E-04 0.2550517E-04 0.2449930E+01 11.6576 5 HCO3- 0.1270723E-04 0.1307039E-04 0.7974740E+00 3.2372 6 HS- 0.3391676E-12 0.6045842E-10 0.1999369E-05 -4.3365 7 Al+++ 0.2592894E-21 0.5149066E-05 0.1389218E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4255518E-03 0.4089979E+02 -3.4276 9 Ca++ 0.4980807E-05 0.5074972E-05 0.2033834E+00 10.9488 10 Mg++ 0.1992717E-07 0.2100283E-07 0.5105924E-03 8.5509 11 Fe++ 0.1175925E-09 0.1258762E-08 0.7029415E-04 6.3219 12 K+ 0.2525578E-04 0.2526615E-04 0.9879016E+00 3.5355 13 Na+ 0.3091862E-03 0.3094542E-03 0.7113893E+01 4.6233 14 Mn++ 0.1563190E-07 0.2223071E-07 0.1221243E-02 8.4455 15 HPO4-- 0.1142342E-07 0.1279861E-07 0.1228329E-02 8.3094 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1957423E-02 -.1583171E-03 -.1799106E-02 0.0000000E+00 2 H2O 0.5550676E+02 0.5550664E+02 0.1183751E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2880237E-04 0.2550441E-04 0.3297956E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3297896E-05 0.6045662E-10 -.3297956E-05 0.0000000E+00 7 Al+++ 0.3880283E-03 0.5148913E-05 0.3828793E-03 0.0000000E+00 8 H4SiO4 0.1239121E-02 0.4255391E-03 0.8135821E-03 0.0000000E+00 9 Ca++ 0.1513380E-03 0.5074821E-05 0.1462632E-03 0.0000000E+00 10 Mg++ 0.9444444E-04 0.2100221E-07 0.9442344E-04 0.0000000E+00 11 Fe++ 0.8484802E-04 0.1258724E-08 0.8484676E-04 0.0000000E+00 12 K+ 0.2526539E-04 0.2526539E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3094450E-03 0.3094450E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2063293E-05 0.2223005E-07 0.2041063E-05 0.0000000E+00 15 HPO4-- 0.7041916E-06 0.1279823E-07 0.6913934E-06 0.0000000E+00 Chg. balance for solid moles: -.7708E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2305E-06 -6.637 0.1158E-03 -3.936 0.1134 0.3679E-04 clinochlore 0.1888E-04 -4.724 0.1050E-01 -1.979 10.28 0.3993E-02 daphnite 0.1169E-04 -4.932 0.8343E-02 -2.079 8.169 0.2528E-02 chlorite-Mn 0.4082E-06 -6.389 0.2894E-03 -3.538 0.2834 0.9223E-04 hematite 0.1319E-04 -4.880 0.2107E-02 -2.676 2.063 0.3993E-03 kaolinite 0.1534E-04 -4.814 0.3961E-02 -2.402 3.878 0.1524E-02 lawsonite 0.6517E-04 -4.186 0.2048E-01 -1.689 20.05 0.6604E-02 stilbite 0.7994E-04 -4.097 0.5634E-01 -1.249 55.16 0.2628E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1317E-01 0.1317E-01 1.0000 -1.880 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.102128 g Volume = 0.041454 cm3 Porosity: 96.0430% V(tot) - V(min): 0.10061E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1190000 g log = -0.9245 Original solution: 1000.0103000 g Original solution / Rock added: 8403.45 (Water/Rock Ratio), log = 3.9245 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1906E-04 1.0071 0.1959E-04 0.1945E-04 CH4,gas 0.2423E-15 1.0125 0.2503E-15 0.2472E-15 H2,gas 0.5859E-06 1.0005 0.5981E-06 0.5978E-06 H2S,gas 0.1912E-12 0.9960 0.1943E-12 0.1951E-12 S2,gas 0.3881E-32 1.0000 0.3960E-32 0.3960E-32 CO,gas 0.3060E-14 1.0000 0.3122E-14 0.3122E-14 SO3,gas 0.4147E-36 1.0000 0.4232E-36 0.4232E-36 SO2,gas 0.9651E-20 1.0000 0.9847E-20 0.9847E-20 HCl,gas 0.2948E-15 1.0000 0.3008E-15 0.3008E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.07 -6.41 -2.136 0.10940E+05 -4.708 3 CH4,gas 4.54 -12.76 -17.30 -4.325 0.29540E+05 -15.602 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.64 -14.41 -7.205 0.24606E+05 -12.712 6 S2,gas -7.34 -41.44 -34.10 -5.246 0.58227E+05 -32.402 7 CO,gas 3.21 -12.99 -16.20 -4.986 0.27669E+05 -14.506 8 SO3,gas 17.12 -20.95 -38.07 -9.518 0.65008E+05 -36.373 9 SO2,gas 0.83 -20.87 -21.71 -5.788 0.37062E+05 -20.007 10 HCl,gas 5.19 -12.03 -17.22 -8.610 0.29404E+05 -15.522 11 acmite 7.71 4.05 -3.66 -0.380 0.62468E+04 15 albite-high 0.69 -2.90 -3.59 -0.276 0.61321E+04 16 albite -0.38 -2.90 -2.51 -0.193 0.42933E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66270E+04 20 analcite 3.32 0.53 -2.79 -0.310 0.47682E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -10.00 -4.69 -2.343 0.80003E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.12 -3.08 -1.028 0.52672E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.12 -2.93 -0.977 0.50030E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29429E+04 42 celadonite 5.34 1.14 -4.20 -0.247 0.71789E+04 43 celadonite-Fe 3.88 -1.09 -4.97 -0.292 0.84834E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12924E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14696E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64761E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82464E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68796E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.53 -3.69 -0.369 0.62936E+04 97 kalsilite 7.58 2.87 -4.71 -0.674 0.80504E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.56 -4.68 -0.468 0.79865E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75919E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20478E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.99 -1.50 -0.115 0.25606E+04 120 muscovite 2.58 1.54 -1.05 -0.062 0.17861E+04 121 paragonite 4.24 2.62 -1.62 -0.095 0.27580E+04 122 nepheline 8.34 3.96 -4.38 -0.626 0.74830E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49717E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40651E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.62 -3.65 -1.215 0.62242E+04 152 rhodonite 7.45 5.02 -2.43 -0.486 0.41454E+04 153 sanidine -1.28 -3.99 -2.71 -0.209 0.46283E+04 155 siderite -2.61 -6.75 -4.14 -1.379 0.70640E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.48 -1.54 -0.046 0.26267E+04 165 stilpnomelane-Mg 27.44 22.62 -4.82 -0.144 0.82258E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83501E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77669E+04 174 tephroite 18.09 13.46 -4.62 -0.660 0.78926E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.98 -3.46 -0.212 0.59057E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.62 -3.28 -0.201 0.55967E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.11 -2.87 -0.176 0.49072E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.75 -2.71 -0.166 0.46339E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.06 -1.28 -0.082 0.21787E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.42 -1.10 -0.070 0.18714E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59586E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.40 -2.41 -0.186 0.41205E+04 243 an25ab75 2.65 0.23 -2.42 -0.186 0.41242E+04 244 an30ab70 3.28 0.86 -2.42 -0.186 0.41376E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1190000 g New total amount of reactant added: 0.1230000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7207E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1230000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3304143E-03 Osmotic coef. = 0.9891 True ionic strength = .3800517E-03 Chg. balance for total moles = 0.7207E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.71041E-08 -8.1485 0.67995E-08 -8.1675 0.95713E+00 -0.0190 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13203E-03 -3.8793 0.95696E+00 -0.0191 4 SO4-- 0.25466E-04 -4.5940 0.22542E-04 -4.6470 0.88515E+00 -0.0530 5 HCO3- 0.12708E-04 -4.8959 0.12161E-04 -4.9150 0.95700E+00 -0.0191 6 HS- 0.32718E-12 -12.4852 0.31310E-12 -12.5043 0.95697E+00 -0.0191 7 Al+++ 0.23353E-21 -21.6317 0.18141E-21 -21.7413 0.77683E+00 -0.1097 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.46437E-05 -5.3331 0.41096E-05 -5.3862 0.88498E+00 -0.0531 10 Mg++ 0.18578E-07 -7.7310 0.16439E-07 -7.7841 0.88486E+00 -0.0531 11 Fe++ 0.10963E-09 -9.9601 0.97011E-10 -10.0132 0.88489E+00 -0.0531 12 K+ 0.26105E-04 -4.5833 0.24982E-04 -4.6024 0.95701E+00 -0.0191 13 Na+ 0.31419E-03 -3.5028 0.30067E-03 -3.5219 0.95696E+00 -0.0191 14 Mn++ 0.14587E-07 -7.8360 0.12909E-07 -7.8891 0.88491E+00 -0.0531 15 HPO4-- 0.12269E-07 -7.9112 0.10860E-07 -7.9642 0.88516E+00 -0.0530 16 HSiO3- 0.53608E-04 -4.2708 0.51301E-04 -4.2899 0.95696E+00 -0.0191 17 Ca(HSiO3)+ 0.50169E-08 -8.2996 0.48013E-08 -8.3186 0.95702E+00 -0.0191 18 Mg(HSiO3)+ 0.24976E-10 -10.6025 0.23903E-10 -10.6216 0.95702E+00 -0.0191 19 NaHSiO3,aq 0.24947E-06 -6.6030 0.24947E-06 -6.6030 0.10000E+01 0.0000 20 AlO+ 0.55779E-12 -12.2535 0.53382E-12 -12.2726 0.95702E+00 -0.0191 21 AlOH+2 0.20424E-16 -16.6899 0.18074E-16 -16.7430 0.88493E+00 -0.0531 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.53191E-05 -5.2742 0.50899E-05 -5.2933 0.95692E+00 -0.0191 24 CH4,aq 0.16410E-18 -18.7849 0.16409E-18 -18.7849 0.99990E+00 0.0000 29 CO,aq 0.20220E-17 -17.6942 0.20220E-17 -17.6942 0.10000E+01 0.0000 30 CO2,aq 0.17671E-06 -6.7527 0.17669E-06 -6.7528 0.99990E+00 0.0000 31 CO3-2 0.17650E-06 -6.7532 0.15622E-06 -6.8063 0.88510E+00 -0.0530 32 CaCO3,aq 0.80501E-08 -8.0942 0.80501E-08 -8.0942 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.13330E-08 -8.8752 0.12757E-08 -8.8942 0.95702E+00 -0.0191 34 CaCl+ 0.91749E-09 -9.0374 0.87805E-09 -9.0565 0.95702E+00 -0.0191 35 CaCl2,aq 0.27542E-13 -13.5600 0.27542E-13 -13.5600 0.10000E+01 0.0000 36 CaOH+ 0.45009E-07 -7.3467 0.43075E-07 -7.3658 0.95702E+00 -0.0191 37 CaSO4,aq 0.29416E-07 -7.5314 0.29416E-07 -7.5314 0.10000E+01 0.0000 38 HCl,aq 0.16450E-12 -12.7838 0.16450E-12 -12.7838 0.10000E+01 0.0000 43 FeCl+ 0.21184E-13 -13.6740 0.20273E-13 -13.6931 0.95702E+00 -0.0191 46 FeO,aq 0.81552E-10 -10.0886 0.81552E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.48528E-09 -9.3140 0.46442E-09 -9.3331 0.95702E+00 -0.0191 48 HFeO2- 0.13114E-09 -9.8823 0.12549E-09 -9.9014 0.95696E+00 -0.0191 49 FeO+ 0.54231E-13 -13.2658 0.51900E-13 -13.2848 0.95702E+00 -0.0191 50 FeOH+2 0.76155E-19 -19.1183 0.67392E-19 -19.1714 0.88493E+00 -0.0531 51 FeO2- 0.24003E-09 -9.6197 0.22970E-09 -9.6388 0.95696E+00 -0.0191 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45560E-09 -9.3414 0.45555E-09 -9.3415 0.99990E+00 0.0000 54 KCl,aq 0.59780E-10 -10.2234 0.59780E-10 -10.2234 0.10000E+01 0.0000 55 KHSO4,aq 0.10826E-16 -16.9655 0.10826E-16 -16.9655 0.10000E+01 0.0000 56 KOH,aq 0.15691E-08 -8.8044 0.15691E-08 -8.8044 0.10000E+01 0.0000 57 KSO4- 0.91317E-08 -8.0394 0.87387E-08 -8.0586 0.95696E+00 -0.0191 58 MgCO3,aq 0.80718E-11 -11.0930 0.80718E-11 -11.0930 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.54488E-11 -11.2637 0.52146E-11 -11.2828 0.95702E+00 -0.0191 60 MgCl+ 0.33265E-11 -11.4780 0.31835E-11 -11.4971 0.95702E+00 -0.0191 61 MgOH+ 0.99630E-09 -9.0016 0.95348E-09 -9.0207 0.95702E+00 -0.0191 63 MnO,aq 0.28915E-09 -9.5389 0.28915E-09 -9.5389 0.10000E+01 0.0000 64 MnOH+ 0.59986E-08 -8.2220 0.57407E-08 -8.2410 0.95702E+00 -0.0191 65 MnO2-2 0.23450E-15 -15.6299 0.20755E-15 -15.6829 0.88510E+00 -0.0530 66 HMnO2- 0.32309E-12 -12.4907 0.30919E-12 -12.5098 0.95696E+00 -0.0191 69 MnCl+ 0.10966E-10 -10.9599 0.10495E-10 -10.9790 0.95702E+00 -0.0191 70 MnSO4,aq 0.84004E-10 -10.0757 0.84004E-10 -10.0757 0.10000E+01 0.0000 71 NaCl,aq 0.13156E-07 -7.8809 0.13156E-07 -7.8809 0.10000E+01 0.0000 72 NaOH,aq 0.18999E-07 -7.7213 0.18999E-07 -7.7213 0.10000E+01 0.0000 74 OH- 0.88799E-04 -4.0516 0.84973E-04 -4.0707 0.95692E+00 -0.0191 79 HPO3-2 0.17418E-19 -19.7590 0.15417E-19 -19.8120 0.88510E+00 -0.0530 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.14234E-08 -8.8467 0.13621E-08 -8.8658 0.95699E+00 -0.0191 84 PO4-3 0.16751E-11 -11.7760 0.13031E-11 -11.8850 0.77791E+00 -0.1091 87 H2P2O7-2 0.16437E-18 -18.7842 0.14549E-18 -18.8372 0.88510E+00 -0.0530 88 HP2O7-3 0.54997E-17 -17.2597 0.42724E-17 -17.3693 0.77684E+00 -0.1097 89 P2O7-4 0.23175E-18 -18.6350 0.15011E-18 -18.8236 0.64772E+00 -0.1886 90 H2S,aq 0.65805E-14 -14.1817 0.65798E-14 -14.1818 0.99990E+00 0.0000 97 SO3-2 0.15071E-14 -14.8219 0.13344E-14 -14.8747 0.88546E+00 -0.0528 98 HSO3- 0.59367E-15 -15.2265 0.56812E-15 -15.2456 0.95696E+00 -0.0191 99 HSO4- 0.15434E-09 -9.8115 0.14771E-09 -9.8306 0.95704E+00 -0.0191 Charge balance for all species = 0.7191E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7104083E-08 -.1640591E-03 -.1653525E+00 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9999424E+06 0.0000 3 Cl- 0.1379643E-03 0.1379784E-03 0.4891473E+01 4.2882 4 SO4-- 0.2546646E-04 0.2550519E-04 0.2449932E+01 11.6880 5 HCO3- 0.1270779E-04 0.1307040E-04 0.7974743E+00 3.2525 6 HS- 0.3271840E-12 0.5939339E-10 0.1964148E-05 -4.3368 7 Al+++ 0.2335293E-21 0.5334728E-05 0.1439309E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4274352E-03 0.4108080E+02 -3.4276 9 Ca++ 0.4643694E-05 0.4733437E-05 0.1896960E+00 10.9488 10 Mg++ 0.1857840E-07 0.1961653E-07 0.4768902E-03 8.5509 11 Fe++ 0.1096310E-09 0.1246347E-08 0.6960082E-04 6.3219 12 K+ 0.2610469E-04 0.2611545E-04 0.1021109E+01 3.5652 13 Na+ 0.3141940E-03 0.3144756E-03 0.7229324E+01 4.6456 14 Mn++ 0.1458740E-07 0.2097039E-07 0.1152006E-02 8.4459 15 HPO4-- 0.1226858E-07 0.1369363E-07 0.1314227E-02 8.3709 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2023657E-02 -.1640541E-03 -.1859603E-02 0.0000000E+00 2 H2O 0.5550671E+02 0.5550660E+02 0.1099457E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2891322E-04 0.2550441E-04 0.3408809E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3408749E-05 0.5939158E-10 -.3408809E-05 0.0000000E+00 7 Al+++ 0.4010712E-03 0.5334565E-05 0.3957367E-03 0.0000000E+00 8 H4SiO4 0.1280772E-02 0.4274221E-03 0.8533502E-03 0.0000000E+00 9 Ca++ 0.1559386E-03 0.4733293E-05 0.1512053E-03 0.0000000E+00 10 Mg++ 0.9761905E-04 0.1961593E-07 0.9759943E-04 0.0000000E+00 11 Fe++ 0.8770006E-04 0.1246309E-08 0.8769881E-04 0.0000000E+00 12 K+ 0.2611465E-04 0.2611465E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3144660E-03 0.3144660E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2132647E-05 0.2096975E-07 0.2111678E-05 0.0000000E+00 15 HPO4-- 0.7278619E-06 0.1369321E-07 0.7141687E-06 0.0000000E+00 Chg. balance for solid moles: 0.2238E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1230000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2381E-06 -6.623 0.1196E-03 -3.922 0.1122 0.3800E-04 clinochlore 0.1952E-04 -4.710 0.1085E-01 -1.965 10.18 0.4127E-02 daphnite 0.1209E-04 -4.918 0.8623E-02 -2.064 8.094 0.2613E-02 chlorite-Mn 0.4223E-06 -6.374 0.2994E-03 -3.524 0.2811 0.9542E-04 hematite 0.1364E-04 -4.865 0.2178E-02 -2.662 2.044 0.4127E-03 kaolinite 0.1583E-04 -4.801 0.4085E-02 -2.389 3.835 0.1572E-02 lawsonite 0.6490E-04 -4.188 0.2039E-01 -1.691 19.14 0.6576E-02 stilbite 0.8512E-04 -4.070 0.5998E-01 -1.222 56.31 0.2798E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1319E-01 0.1319E-01 1.0000 -1.880 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.106532 g Volume = 0.043412 cm3 Porosity: 95.8624% V(tot) - V(min): 0.10058E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1230000 g log = -0.9101 Original solution: 1000.0103000 g Original solution / Rock added: 8130.17 (Water/Rock Ratio), log = 3.9101 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1840E-04 1.0071 0.1890E-04 0.1877E-04 CH4,gas 0.2338E-15 1.0125 0.2415E-15 0.2385E-15 H2,gas 0.5859E-06 1.0005 0.5981E-06 0.5978E-06 H2S,gas 0.1780E-12 0.9960 0.1809E-12 0.1816E-12 S2,gas 0.3365E-32 1.0000 0.3433E-32 0.3433E-32 CO,gas 0.2953E-14 1.0000 0.3013E-14 0.3013E-14 SO3,gas 0.3862E-36 1.0000 0.3941E-36 0.3941E-36 SO2,gas 0.8986E-20 1.0000 0.9169E-20 0.9169E-20 HCl,gas 0.2845E-15 1.0000 0.2903E-15 0.2903E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.48529E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.08 -6.42 -2.141 0.10966E+05 -4.723 3 CH4,gas 4.54 -12.77 -17.32 -4.329 0.29567E+05 -15.617 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.67 -14.44 -7.221 0.24659E+05 -12.743 6 S2,gas -7.34 -41.50 -34.16 -5.256 0.58333E+05 -32.464 7 CO,gas 3.21 -13.00 -16.22 -4.991 0.27695E+05 -14.521 8 SO3,gas 17.12 -20.98 -38.10 -9.526 0.65061E+05 -36.404 9 SO2,gas 0.83 -20.90 -21.74 -5.796 0.37115E+05 -20.038 10 HCl,gas 5.19 -12.05 -17.24 -8.618 0.29430E+05 -15.537 11 acmite 7.71 4.07 -3.64 -0.378 0.62088E+04 15 albite-high 0.69 -2.88 -3.57 -0.275 0.60941E+04 16 albite -0.38 -2.88 -2.49 -0.192 0.42553E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66249E+04 20 analcite 3.32 0.55 -2.77 -0.308 0.47301E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -10.03 -4.72 -2.358 0.80532E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.13 -3.10 -1.033 0.52935E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.13 -2.95 -0.982 0.50293E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29429E+04 42 celadonite 5.34 1.17 -4.17 -0.246 0.71283E+04 43 celadonite-Fe 3.88 -1.06 -4.94 -0.291 0.84328E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12924E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14689E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60390E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64761E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82464E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68797E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.55 -3.66 -0.366 0.62556E+04 97 kalsilite 7.58 2.90 -4.69 -0.669 0.79997E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.53 -4.65 -0.465 0.79358E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75919E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20478E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.96 -1.47 -0.113 0.25100E+04 120 muscovite 2.58 1.57 -1.02 -0.060 0.17355E+04 121 paragonite 4.24 2.65 -1.59 -0.094 0.27200E+04 122 nepheline 8.34 3.98 -4.36 -0.623 0.74450E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49717E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40644E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.64 -3.66 -1.220 0.62499E+04 152 rhodonite 7.45 5.02 -2.43 -0.485 0.41447E+04 153 sanidine -1.28 -3.96 -2.68 -0.206 0.45777E+04 155 siderite -2.61 -6.76 -4.15 -1.384 0.70903E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.49 -1.52 -0.045 0.26014E+04 165 stilpnomelane-Mg 27.44 22.64 -4.80 -0.143 0.82005E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83502E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77669E+04 174 tephroite 18.09 13.46 -4.62 -0.660 0.78912E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.97 -3.45 -0.211 0.58890E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.61 -3.27 -0.200 0.55841E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.10 -2.86 -0.175 0.48905E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.74 -2.71 -0.166 0.46214E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.07 -1.27 -0.081 0.21620E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.43 -1.09 -0.070 0.18588E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59586E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.38 -2.40 -0.184 0.40900E+04 243 an25ab75 2.65 0.25 -2.40 -0.185 0.40957E+04 244 an30ab70 3.28 0.87 -2.41 -0.185 0.41110E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1230000 g New total amount of reactant added: 0.1270000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1270000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3335696E-03 Osmotic coef. = 0.9891 True ionic strength = .3849866E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.68640E-08 -8.1634 0.65686E-08 -8.1825 0.95697E+00 -0.0191 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13201E-03 -3.8794 0.95681E+00 -0.0192 4 SO4-- 0.25468E-04 -4.5940 0.22529E-04 -4.6473 0.88458E+00 -0.0533 5 HCO3- 0.12708E-04 -4.8959 0.12159E-04 -4.9151 0.95685E+00 -0.0192 6 HS- 0.31589E-12 -12.5005 0.30224E-12 -12.5196 0.95681E+00 -0.0192 7 Al+++ 0.21085E-21 -21.6760 0.16356E-21 -21.7863 0.77569E+00 -0.1103 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.43366E-05 -5.3629 0.38352E-05 -5.4162 0.88440E+00 -0.0534 10 Mg++ 0.17350E-07 -7.7607 0.15342E-07 -7.8141 0.88428E+00 -0.0534 11 Fe++ 0.10238E-09 -9.9898 0.90534E-10 -10.0432 0.88431E+00 -0.0534 12 K+ 0.26954E-04 -4.5694 0.25791E-04 -4.5885 0.95685E+00 -0.0192 13 Na+ 0.31920E-03 -3.4959 0.30541E-03 -3.5151 0.95680E+00 -0.0192 14 Mn++ 0.13634E-07 -7.8654 0.12057E-07 -7.9188 0.88433E+00 -0.0534 15 HPO4-- 0.13155E-07 -7.8809 0.11636E-07 -7.9342 0.88458E+00 -0.0533 16 HSiO3- 0.55501E-04 -4.2557 0.53104E-04 -4.2749 0.95681E+00 -0.0192 17 Ca(HSiO3)+ 0.48474E-08 -8.3145 0.46382E-08 -8.3336 0.95686E+00 -0.0192 18 Mg(HSiO3)+ 0.24132E-10 -10.6174 0.23091E-10 -10.6366 0.95686E+00 -0.0192 19 NaHSiO3,aq 0.26231E-06 -6.5812 0.26231E-06 -6.5812 0.10000E+01 0.0000 20 AlO+ 0.53894E-12 -12.2685 0.51569E-12 -12.2876 0.95686E+00 -0.0192 21 AlOH+2 0.19073E-16 -16.7196 0.16867E-16 -16.7730 0.88435E+00 -0.0534 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.55069E-05 -5.2591 0.52688E-05 -5.2783 0.95676E+00 -0.0192 24 CH4,aq 0.15848E-18 -18.8000 0.15846E-18 -18.8001 0.99990E+00 0.0000 29 CO,aq 0.19530E-17 -17.7093 0.19530E-17 -17.7093 0.10000E+01 0.0000 30 CO2,aq 0.17068E-06 -6.7678 0.17067E-06 -6.7679 0.99990E+00 0.0000 31 CO3-2 0.18280E-06 -6.7380 0.16169E-06 -6.7913 0.88452E+00 -0.0533 32 CaCO3,aq 0.77756E-08 -8.1093 0.77756E-08 -8.1093 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12441E-08 -8.9052 0.11904E-08 -8.9243 0.95686E+00 -0.0192 34 CaCl+ 0.85624E-09 -9.0674 0.81931E-09 -9.0866 0.95686E+00 -0.0192 35 CaCl2,aq 0.25695E-13 -13.5902 0.25695E-13 -13.5902 0.10000E+01 0.0000 36 CaOH+ 0.43488E-07 -7.3616 0.41612E-07 -7.3808 0.95686E+00 -0.0192 37 CaSO4,aq 0.27437E-07 -7.5617 0.27437E-07 -7.5617 0.10000E+01 0.0000 38 HCl,aq 0.15889E-12 -12.7989 0.15889E-12 -12.7989 0.10000E+01 0.0000 43 FeCl+ 0.19769E-13 -13.7040 0.18916E-13 -13.7232 0.95686E+00 -0.0192 46 FeO,aq 0.81550E-10 -10.0886 0.81550E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.46887E-09 -9.3289 0.44864E-09 -9.3481 0.95686E+00 -0.0192 48 HFeO2- 0.13576E-09 -9.8672 0.12990E-09 -9.8864 0.95681E+00 -0.0192 49 FeO+ 0.52398E-13 -13.2807 0.50138E-13 -13.2998 0.95686E+00 -0.0192 50 FeOH+2 0.71118E-19 -19.1480 0.62894E-19 -19.2014 0.88435E+00 -0.0534 51 FeO2- 0.24851E-09 -9.6047 0.23777E-09 -9.6238 0.95681E+00 -0.0192 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45558E-09 -9.3414 0.45553E-09 -9.3415 0.99990E+00 0.0000 54 KCl,aq 0.61704E-10 -10.2097 0.61704E-10 -10.2097 0.10000E+01 0.0000 55 KHSO4,aq 0.10791E-16 -16.9669 0.10791E-16 -16.9669 0.10000E+01 0.0000 56 KOH,aq 0.16768E-08 -8.7755 0.16768E-08 -8.7755 0.10000E+01 0.0000 57 KSO4- 0.94231E-08 -8.0258 0.90161E-08 -8.0450 0.95681E+00 -0.0192 58 MgCO3,aq 0.77965E-11 -11.1081 0.77965E-11 -11.1081 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.50851E-11 -11.2937 0.48658E-11 -11.3128 0.95686E+00 -0.0192 60 MgCl+ 0.31044E-11 -11.5080 0.29705E-11 -11.5272 0.95686E+00 -0.0192 61 MgOH+ 0.96263E-09 -9.0165 0.92110E-09 -9.0357 0.95686E+00 -0.0192 63 MnO,aq 0.28938E-09 -9.5385 0.28938E-09 -9.5385 0.10000E+01 0.0000 64 MnOH+ 0.58006E-08 -8.2365 0.55503E-08 -8.2557 0.95686E+00 -0.0192 65 MnO2-2 0.25164E-15 -15.5992 0.22258E-15 -15.6525 0.88452E+00 -0.0533 66 HMnO2- 0.33478E-12 -12.4752 0.32032E-12 -12.4944 0.95681E+00 -0.0192 69 MnCl+ 0.10243E-10 -10.9896 0.98007E-11 -11.0087 0.95686E+00 -0.0192 70 MnSO4,aq 0.78415E-10 -10.1056 0.78415E-10 -10.1056 0.10000E+01 0.0000 71 NaCl,aq 0.13361E-07 -7.8742 0.13361E-07 -7.8742 0.10000E+01 0.0000 72 NaOH,aq 0.19977E-07 -7.6995 0.19977E-07 -7.6995 0.10000E+01 0.0000 74 OH- 0.91935E-04 -4.0365 0.87959E-04 -4.0557 0.95676E+00 -0.0192 79 HPO3-2 0.18676E-19 -19.7287 0.16519E-19 -19.7820 0.88452E+00 -0.0533 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.14736E-08 -8.8316 0.14100E-08 -8.8508 0.95683E+00 -0.0192 84 PO4-3 0.18607E-11 -11.7303 0.14454E-11 -11.8400 0.77677E+00 -0.1097 87 H2P2O7-2 0.17624E-18 -18.7539 0.15589E-18 -18.8072 0.88452E+00 -0.0533 88 HP2O7-3 0.61092E-17 -17.2140 0.47389E-17 -17.3243 0.77570E+00 -0.1103 89 P2O7-4 0.26678E-18 -18.5738 0.17235E-18 -18.7636 0.64603E+00 -0.1897 90 H2S,aq 0.61365E-14 -14.2121 0.61359E-14 -14.2121 0.99990E+00 0.0000 97 SO3-2 0.15071E-14 -14.8219 0.13336E-14 -14.8750 0.88489E+00 -0.0531 98 HSO3- 0.57324E-15 -15.2417 0.54848E-15 -15.2608 0.95681E+00 -0.0192 99 HSO4- 0.14904E-09 -9.8267 0.14261E-09 -9.8458 0.95688E+00 -0.0191 Charge balance for all species = 0.7195E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6864002E-08 -.1698640E-03 -.1712031E+00 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9999420E+06 0.0000 3 Cl- 0.1379642E-03 0.1379785E-03 0.4891475E+01 4.3031 4 SO4-- 0.2546818E-04 0.2550521E-04 0.2449933E+01 11.7178 5 HCO3- 0.1270789E-04 0.1307041E-04 0.7974747E+00 3.2674 6 HS- 0.3158870E-12 0.5831741E-10 0.1928564E-05 -4.3371 7 Al+++ 0.2108524E-21 0.5522578E-05 0.1489990E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4293411E-03 0.4126395E+02 -3.4276 9 Ca++ 0.4336568E-05 0.4422216E-05 0.1772236E+00 10.9488 10 Mg++ 0.1734961E-07 0.1835236E-07 0.4461573E-03 8.5509 11 Fe++ 0.1023781E-09 0.1235784E-08 0.6901095E-04 6.3219 12 K+ 0.2695359E-04 0.2696475E-04 0.1054316E+01 3.5940 13 Na+ 0.3192013E-03 0.3194970E-03 0.7344756E+01 4.6674 14 Mn++ 0.1363381E-07 0.1981278E-07 0.1088413E-02 8.4463 15 HPO4-- 0.1315469E-07 0.1463019E-07 0.1404112E-02 8.4309 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2089891E-02 -.1698587E-03 -.1920033E-02 0.0000000E+00 2 H2O 0.5550666E+02 0.5550656E+02 0.1015050E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2902407E-04 0.2550441E-04 0.3519661E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3519603E-05 0.5831558E-10 -.3519661E-05 0.0000000E+00 7 Al+++ 0.4141142E-03 0.5522405E-05 0.4085918E-03 0.0000000E+00 8 H4SiO4 0.1322423E-02 0.4293276E-03 0.8930958E-03 0.0000000E+00 9 Ca++ 0.1605392E-03 0.4422078E-05 0.1561171E-03 0.0000000E+00 10 Mg++ 0.1007937E-03 0.1835178E-07 0.1007753E-03 0.0000000E+00 11 Fe++ 0.9055209E-04 0.1235746E-08 0.9055086E-04 0.0000000E+00 12 K+ 0.2696391E-04 0.2696391E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3194869E-03 0.3194869E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2202002E-05 0.1981215E-07 0.2182190E-05 0.0000000E+00 15 HPO4-- 0.7515322E-06 0.1462973E-07 0.7369025E-06 0.0000000E+00 Chg. balance for solid moles: -.1622E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1270000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2456E-06 -6.610 0.1234E-03 -3.909 0.1112 0.3921E-04 clinochlore 0.2016E-04 -4.696 0.1120E-01 -1.951 10.10 0.4261E-02 daphnite 0.1248E-04 -4.904 0.8904E-02 -2.050 8.026 0.2698E-02 chlorite-Mn 0.4364E-06 -6.360 0.3094E-03 -3.509 0.2789 0.9860E-04 hematite 0.1408E-04 -4.851 0.2248E-02 -2.648 2.027 0.4261E-03 kaolinite 0.1634E-04 -4.787 0.4217E-02 -2.375 3.802 0.1623E-02 lawsonite 0.6460E-04 -4.190 0.2030E-01 -1.692 18.30 0.6546E-02 stilbite 0.9029E-04 -4.044 0.6363E-01 -1.196 57.36 0.2968E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1320E-01 0.1320E-01 1.0000 -1.880 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.110933 g Volume = 0.045369 cm3 Porosity: 95.6824% V(tot) - V(min): 0.10054E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1270000 g log = -0.8962 Original solution: 1000.0103000 g Original solution / Rock added: 7874.10 (Water/Rock Ratio), log = 3.8962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1777E-04 1.0071 0.1826E-04 0.1813E-04 CH4,gas 0.2258E-15 1.0125 0.2332E-15 0.2304E-15 H2,gas 0.5858E-06 1.0005 0.5981E-06 0.5977E-06 H2S,gas 0.1660E-12 0.9960 0.1687E-12 0.1693E-12 S2,gas 0.2926E-32 1.0000 0.2986E-32 0.2986E-32 CO,gas 0.2852E-14 1.0000 0.2910E-14 0.2910E-14 SO3,gas 0.3602E-36 1.0000 0.3675E-36 0.3675E-36 SO2,gas 0.8381E-20 1.0000 0.8552E-20 0.8552E-20 HCl,gas 0.2748E-15 1.0000 0.2804E-15 0.2804E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.10 -6.44 -2.146 0.10992E+05 -4.739 3 CH4,gas 4.54 -12.79 -17.33 -4.333 0.29592E+05 -15.632 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.70 -14.47 -7.236 0.24710E+05 -12.773 6 S2,gas -7.34 -41.56 -34.22 -5.265 0.58436E+05 -32.525 7 CO,gas 3.21 -13.02 -16.24 -4.995 0.27721E+05 -14.536 8 SO3,gas 17.12 -21.01 -38.13 -9.533 0.65112E+05 -36.435 9 SO2,gas 0.83 -20.93 -21.77 -5.805 0.37166E+05 -20.068 10 HCl,gas 5.19 -12.06 -17.25 -8.626 0.29456E+05 -15.552 11 acmite 7.71 4.10 -3.61 -0.376 0.61716E+04 15 albite-high 0.69 -2.85 -3.55 -0.273 0.60569E+04 16 albite -0.38 -2.85 -2.47 -0.190 0.42181E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66231E+04 20 analcite 3.32 0.57 -2.75 -0.305 0.46929E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -10.06 -4.75 -2.373 0.81048E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.15 -3.12 -1.038 0.53193E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.15 -2.96 -0.987 0.50550E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29429E+04 42 celadonite 5.34 1.20 -4.15 -0.244 0.70791E+04 43 celadonite-Fe 3.88 -1.03 -4.91 -0.289 0.83836E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12924E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14683E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64761E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82465E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68797E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.57 -3.64 -0.364 0.62184E+04 97 kalsilite 7.58 2.93 -4.66 -0.665 0.79505E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.50 -4.62 -0.462 0.78866E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75919E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20479E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.93 -1.44 -0.111 0.24607E+04 120 muscovite 2.58 1.59 -0.99 -0.058 0.16863E+04 121 paragonite 4.24 2.67 -1.57 -0.092 0.26827E+04 122 nepheline 8.34 4.00 -4.34 -0.620 0.74077E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49717E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40638E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.65 -3.68 -1.225 0.62750E+04 152 rhodonite 7.45 5.02 -2.43 -0.485 0.41441E+04 153 sanidine -1.28 -3.93 -2.65 -0.204 0.45285E+04 155 siderite -2.61 -6.78 -4.17 -1.389 0.71161E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.51 -1.51 -0.045 0.25769E+04 165 stilpnomelane-Mg 27.44 22.65 -4.79 -0.143 0.81759E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83502E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77669E+04 174 tephroite 18.09 13.46 -4.62 -0.660 0.78900E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.96 -3.44 -0.211 0.58728E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.61 -3.26 -0.200 0.55719E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.09 -2.85 -0.175 0.48743E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.74 -2.70 -0.165 0.46091E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.08 -1.26 -0.081 0.21457E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.44 -1.08 -0.069 0.18465E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59586E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.36 -2.38 -0.183 0.40603E+04 243 an25ab75 2.65 0.26 -2.38 -0.183 0.40678E+04 244 an30ab70 3.28 0.89 -2.39 -0.184 0.40849E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1270000 g New total amount of reactant added: 0.1310000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1310000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3367888E-03 Osmotic coef. = 0.9890 True ionic strength = .3900027E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.66375E-08 -8.1780 0.63508E-08 -8.1972 0.95681E+00 -0.0192 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13198E-03 -3.8795 0.95665E+00 -0.0192 4 SO4-- 0.25470E-04 -4.5940 0.22515E-04 -4.6475 0.88399E+00 -0.0536 5 HCO3- 0.12708E-04 -4.8959 0.12157E-04 -4.9152 0.95669E+00 -0.0192 6 HS- 0.30523E-12 -12.5154 0.29200E-12 -12.5346 0.95665E+00 -0.0192 7 Al+++ 0.19085E-21 -21.7193 0.14782E-21 -21.8303 0.77453E+00 -0.1110 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.40564E-05 -5.3919 0.35851E-05 -5.4455 0.88381E+00 -0.0536 10 Mg++ 0.16229E-07 -7.7897 0.14341E-07 -7.8434 0.88369E+00 -0.0537 11 Fe++ 0.95763E-10 -10.0188 0.84628E-10 -10.0725 0.88372E+00 -0.0537 12 K+ 0.27802E-04 -4.5559 0.26598E-04 -4.5751 0.95669E+00 -0.0192 13 Na+ 0.32421E-03 -3.4892 0.31015E-03 -3.5084 0.95664E+00 -0.0192 14 Mn++ 0.12762E-07 -7.8941 0.11279E-07 -7.9477 0.88374E+00 -0.0537 15 HPO4-- 0.14082E-07 -7.8513 0.12448E-07 -7.9049 0.88400E+00 -0.0536 16 HSiO3- 0.57414E-04 -4.2410 0.54925E-04 -4.2602 0.95665E+00 -0.0192 17 Ca(HSiO3)+ 0.46874E-08 -8.3291 0.44844E-08 -8.3483 0.95670E+00 -0.0192 18 Mg(HSiO3)+ 0.23336E-10 -10.6320 0.22325E-10 -10.6512 0.95670E+00 -0.0192 19 NaHSiO3,aq 0.27552E-06 -6.5598 0.27552E-06 -6.5598 0.10000E+01 0.0000 20 AlO+ 0.52116E-12 -12.2830 0.49859E-12 -12.3023 0.95670E+00 -0.0192 21 AlOH+2 0.17841E-16 -16.7486 0.15767E-16 -16.8022 0.88377E+00 -0.0537 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.56968E-05 -5.2444 0.54495E-05 -5.2636 0.95660E+00 -0.0193 24 CH4,aq 0.15317E-18 -18.8148 0.15316E-18 -18.8149 0.99990E+00 0.0000 29 CO,aq 0.18878E-17 -17.7240 0.18878E-17 -17.7240 0.10000E+01 0.0000 30 CO2,aq 0.16499E-06 -6.7825 0.16498E-06 -6.7826 0.99990E+00 0.0000 31 CO3-2 0.18916E-06 -6.7232 0.16720E-06 -6.7768 0.88394E+00 -0.0536 32 CaCO3,aq 0.75163E-08 -8.1240 0.75163E-08 -8.1240 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.11629E-08 -8.9345 0.11125E-08 -8.9537 0.95670E+00 -0.0192 34 CaCl+ 0.80040E-09 -9.0967 0.76574E-09 -9.1159 0.95670E+00 -0.0192 35 CaCl2,aq 0.24011E-13 -13.6196 0.24011E-13 -13.6196 0.10000E+01 0.0000 36 CaOH+ 0.42053E-07 -7.3762 0.40232E-07 -7.3954 0.95670E+00 -0.0192 37 CaSO4,aq 0.25632E-07 -7.5912 0.25632E-07 -7.5912 0.10000E+01 0.0000 38 HCl,aq 0.15360E-12 -12.8136 0.15360E-12 -12.8136 0.10000E+01 0.0000 43 FeCl+ 0.18479E-13 -13.7333 0.17679E-13 -13.7525 0.95670E+00 -0.0192 46 FeO,aq 0.81548E-10 -10.0886 0.81548E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.45339E-09 -9.3435 0.43376E-09 -9.3628 0.95670E+00 -0.0192 48 HFeO2- 0.14044E-09 -9.8525 0.13435E-09 -9.8718 0.95665E+00 -0.0192 49 FeO+ 0.50669E-13 -13.2953 0.48475E-13 -13.3145 0.95670E+00 -0.0192 50 FeOH+2 0.66524E-19 -19.1770 0.58792E-19 -19.2307 0.88377E+00 -0.0537 51 FeO2- 0.25707E-09 -9.5899 0.24593E-09 -9.6092 0.95665E+00 -0.0192 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45556E-09 -9.3415 0.45552E-09 -9.3415 0.99990E+00 0.0000 54 KCl,aq 0.63626E-10 -10.1964 0.63626E-10 -10.1964 0.10000E+01 0.0000 55 KHSO4,aq 0.10753E-16 -16.9685 0.10753E-16 -16.9685 0.10000E+01 0.0000 56 KOH,aq 0.17886E-08 -8.7475 0.17886E-08 -8.7475 0.10000E+01 0.0000 57 KSO4- 0.97141E-08 -8.0126 0.92929E-08 -8.0318 0.95665E+00 -0.0192 58 MgCO3,aq 0.75365E-11 -11.1228 0.75365E-11 -11.1228 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.47534E-11 -11.3230 0.45475E-11 -11.3422 0.95670E+00 -0.0192 60 MgCl+ 0.29019E-11 -11.5373 0.27763E-11 -11.5565 0.95670E+00 -0.0192 61 MgOH+ 0.93086E-09 -9.0311 0.89056E-09 -9.0503 0.95670E+00 -0.0192 63 MnO,aq 0.28959E-09 -9.5382 0.28959E-09 -9.5382 0.10000E+01 0.0000 64 MnOH+ 0.56133E-08 -8.2508 0.53702E-08 -8.2700 0.95670E+00 -0.0192 65 MnO2-2 0.26957E-15 -15.5693 0.23829E-15 -15.6229 0.88394E+00 -0.0536 66 HMnO2- 0.34657E-12 -12.4602 0.33154E-12 -12.4795 0.95665E+00 -0.0192 69 MnCl+ 0.95815E-11 -11.0186 0.91667E-11 -11.0378 0.95670E+00 -0.0192 70 MnSO4,aq 0.73310E-10 -10.1348 0.73310E-10 -10.1348 0.10000E+01 0.0000 71 NaCl,aq 0.13566E-07 -7.8676 0.13566E-07 -7.8676 0.10000E+01 0.0000 72 NaOH,aq 0.20982E-07 -7.6781 0.20982E-07 -7.6781 0.10000E+01 0.0000 74 OH- 0.95104E-04 -4.0218 0.90976E-04 -4.0411 0.95660E+00 -0.0193 79 HPO3-2 0.19991E-19 -19.6992 0.17671E-19 -19.7527 0.88394E+00 -0.0536 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.15244E-08 -8.8169 0.14584E-08 -8.8361 0.95667E+00 -0.0192 84 PO4-3 0.20618E-11 -11.6857 0.15992E-11 -11.7961 0.77563E+00 -0.1103 87 H2P2O7-2 0.18867E-18 -18.7243 0.16677E-18 -18.7779 0.88394E+00 -0.0536 88 HP2O7-3 0.67696E-17 -17.1694 0.52434E-17 -17.2804 0.77454E+00 -0.1110 89 P2O7-4 0.30611E-18 -18.5141 0.19724E-18 -18.7050 0.64433E+00 -0.1909 90 H2S,aq 0.57320E-14 -14.2417 0.57314E-14 -14.2417 0.99990E+00 0.0000 97 SO3-2 0.15071E-14 -14.8219 0.13328E-14 -14.8752 0.88431E+00 -0.0534 98 HSO3- 0.55397E-15 -15.2565 0.52996E-15 -15.2758 0.95665E+00 -0.0192 99 HSO4- 0.14403E-09 -9.8415 0.13780E-09 -9.8607 0.95673E+00 -0.0192 Charge balance for all species = 0.7196E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6637486E-08 -.1757297E-03 -.1771149E+00 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9999417E+06 0.0000 3 Cl- 0.1379642E-03 0.1379786E-03 0.4891477E+01 4.3177 4 SO4-- 0.2546973E-04 0.2550523E-04 0.2449934E+01 11.7468 5 HCO3- 0.1270758E-04 0.1307042E-04 0.7974750E+00 3.2820 6 HS- 0.3052329E-12 0.5723156E-10 0.1892654E-05 -4.3374 7 Al+++ 0.1908492E-21 0.5712397E-05 0.1541203E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4312672E-03 0.4144905E+02 -3.4276 9 Ca++ 0.4056429E-05 0.4138281E-05 0.1658446E+00 10.9488 10 Mg++ 0.1622880E-07 0.1719819E-07 0.4180986E-03 8.5509 11 Fe++ 0.9576277E-10 0.1226926E-08 0.6851623E-04 6.3219 12 K+ 0.2780249E-04 0.2781406E-04 0.1087523E+01 3.6220 13 Na+ 0.3242083E-03 0.3245183E-03 0.7460187E+01 4.6887 14 Mn++ 0.1276239E-07 0.1874849E-07 0.1029946E-02 8.4466 15 HPO4-- 0.1408177E-07 0.1560826E-07 0.1497980E-02 8.4894 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2156126E-02 -.1757241E-03 -.1980401E-02 0.0000000E+00 2 H2O 0.5550661E+02 0.5550652E+02 0.9305399E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2913493E-04 0.2550441E-04 0.3630514E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3630457E-05 0.5722972E-10 -.3630514E-05 0.0000000E+00 7 Al+++ 0.4271572E-03 0.5712213E-05 0.4214449E-03 0.0000000E+00 8 H4SiO4 0.1364075E-02 0.4312533E-03 0.9328213E-03 0.0000000E+00 9 Ca++ 0.1651397E-03 0.4138148E-05 0.1610016E-03 0.0000000E+00 10 Mg++ 0.1039683E-03 0.1719764E-07 0.1039511E-03 0.0000000E+00 11 Fe++ 0.9340413E-04 0.1226887E-08 0.9340290E-04 0.0000000E+00 12 K+ 0.2781316E-04 0.2781316E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3245079E-03 0.3245079E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2271356E-05 0.1874789E-07 0.2252608E-05 0.0000000E+00 15 HPO4-- 0.7752025E-06 0.1560776E-07 0.7595948E-06 0.0000000E+00 Chg. balance for solid moles: -.1516E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1310000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2532E-06 -6.597 0.1272E-03 -3.896 0.1103 0.4042E-04 clinochlore 0.2079E-04 -4.682 0.1156E-01 -1.937 10.02 0.4396E-02 daphnite 0.1287E-04 -4.890 0.9184E-02 -2.037 7.963 0.2783E-02 chlorite-Mn 0.4505E-06 -6.346 0.3194E-03 -3.496 0.2770 0.1018E-03 hematite 0.1452E-04 -4.838 0.2319E-02 -2.635 2.011 0.4396E-03 kaolinite 0.1687E-04 -4.773 0.4356E-02 -2.361 3.777 0.1676E-02 lawsonite 0.6428E-04 -4.192 0.2020E-01 -1.695 17.52 0.6514E-02 stilbite 0.9545E-04 -4.020 0.6727E-01 -1.172 58.33 0.3137E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1321E-01 0.1321E-01 1.0000 -1.879 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.115330 g Volume = 0.047325 cm3 Porosity: 95.5031% V(tot) - V(min): 0.10051E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1310000 g log = -0.8827 Original solution: 1000.0103000 g Original solution / Rock added: 7633.67 (Water/Rock Ratio), log = 3.8827 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1718E-04 1.0071 0.1765E-04 0.1753E-04 CH4,gas 0.2182E-15 1.0125 0.2254E-15 0.2226E-15 H2,gas 0.5858E-06 1.0005 0.5980E-06 0.5977E-06 H2S,gas 0.1550E-12 0.9960 0.1576E-12 0.1582E-12 S2,gas 0.2553E-32 1.0000 0.2605E-32 0.2605E-32 CO,gas 0.2757E-14 1.0000 0.2813E-14 0.2813E-14 SO3,gas 0.3365E-36 1.0000 0.3434E-36 0.3434E-36 SO2,gas 0.7830E-20 1.0000 0.7989E-20 0.7989E-20 HCl,gas 0.2656E-15 1.0000 0.2710E-15 0.2710E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.11 -6.45 -2.151 0.11017E+05 -4.753 3 CH4,gas 4.54 -12.80 -17.35 -4.336 0.29618E+05 -15.647 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.73 -14.50 -7.251 0.24761E+05 -12.803 6 S2,gas -7.34 -41.62 -34.28 -5.274 0.58538E+05 -32.584 7 CO,gas 3.21 -13.03 -16.25 -5.000 0.27746E+05 -14.551 8 SO3,gas 17.12 -21.04 -38.16 -9.541 0.65163E+05 -36.464 9 SO2,gas 0.83 -20.96 -21.80 -5.812 0.37217E+05 -20.098 10 HCl,gas 5.19 -12.08 -17.27 -8.633 0.29481E+05 -15.567 11 acmite 7.71 4.12 -3.59 -0.373 0.61352E+04 15 albite-high 0.69 -2.83 -3.53 -0.271 0.60205E+04 16 albite -0.38 -2.83 -2.45 -0.188 0.41816E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66215E+04 20 analcite 3.32 0.59 -2.73 -0.303 0.46565E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -10.09 -4.78 -2.388 0.81553E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.16 -3.13 -1.043 0.53444E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.16 -2.98 -0.992 0.50802E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29429E+04 42 celadonite 5.34 1.22 -4.12 -0.242 0.70312E+04 43 celadonite-Fe 3.88 -1.01 -4.88 -0.287 0.83357E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12924E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14678E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64762E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82465E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68798E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.59 -3.62 -0.362 0.61820E+04 97 kalsilite 7.58 2.96 -4.63 -0.661 0.79026E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.47 -4.59 -0.459 0.78387E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20479E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.90 -1.41 -0.109 0.24129E+04 120 muscovite 2.58 1.62 -0.96 -0.056 0.16384E+04 121 paragonite 4.24 2.69 -1.55 -0.091 0.26463E+04 122 nepheline 8.34 4.02 -4.32 -0.617 0.73713E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49717E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40633E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.67 -3.69 -1.230 0.62996E+04 152 rhodonite 7.45 5.02 -2.43 -0.485 0.41435E+04 153 sanidine -1.28 -3.90 -2.62 -0.202 0.44806E+04 155 siderite -2.61 -6.79 -4.18 -1.394 0.71412E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.52 -1.50 -0.045 0.25530E+04 165 stilpnomelane-Mg 27.44 22.67 -4.77 -0.143 0.81519E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83502E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77669E+04 174 tephroite 18.09 13.47 -4.62 -0.660 0.78889E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.95 -3.43 -0.210 0.58570E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.60 -3.26 -0.199 0.55598E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.08 -2.85 -0.174 0.48585E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.73 -2.69 -0.165 0.45971E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.09 -1.25 -0.080 0.21299E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.45 -1.07 -0.069 0.18345E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59586E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.34 -2.36 -0.182 0.40311E+04 243 an25ab75 2.65 0.28 -2.37 -0.182 0.40405E+04 244 an30ab70 3.28 0.90 -2.38 -0.183 0.40594E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1310000 g New total amount of reactant added: 0.1350000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1350000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3400656E-03 Osmotic coef. = 0.9890 True ionic strength = .3950918E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.64237E-08 -8.1922 0.61452E-08 -8.2115 0.95665E+00 -0.0192 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13196E-03 -3.8796 0.95649E+00 -0.0193 4 SO4-- 0.25471E-04 -4.5940 0.22501E-04 -4.6478 0.88340E+00 -0.0538 5 HCO3- 0.12707E-04 -4.8960 0.12154E-04 -4.9153 0.95653E+00 -0.0193 6 HS- 0.29518E-12 -12.5299 0.28234E-12 -12.5492 0.95649E+00 -0.0193 7 Al+++ 0.17317E-21 -21.7615 0.13392E-21 -21.8731 0.77337E+00 -0.1116 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.38006E-05 -5.4202 0.33567E-05 -5.4741 0.88322E+00 -0.0539 10 Mg++ 0.15205E-07 -7.8180 0.13428E-07 -7.8720 0.88310E+00 -0.0540 11 Fe++ 0.89721E-10 -10.0471 0.79235E-10 -10.1011 0.88313E+00 -0.0540 12 K+ 0.28651E-04 -4.5429 0.27406E-04 -4.5622 0.95653E+00 -0.0193 13 Na+ 0.32921E-03 -3.4825 0.31489E-03 -3.5018 0.95648E+00 -0.0193 14 Mn++ 0.11965E-07 -7.9221 0.10567E-07 -7.9760 0.88315E+00 -0.0540 15 HPO4-- 0.15050E-07 -7.8225 0.13295E-07 -7.8763 0.88341E+00 -0.0538 16 HSiO3- 0.59345E-04 -4.2266 0.56763E-04 -4.2459 0.95649E+00 -0.0193 17 Ca(HSiO3)+ 0.45364E-08 -8.3433 0.43393E-08 -8.3626 0.95654E+00 -0.0193 18 Mg(HSiO3)+ 0.22584E-10 -10.6462 0.21602E-10 -10.6655 0.95654E+00 -0.0193 19 NaHSiO3,aq 0.28909E-06 -6.5390 0.28909E-06 -6.5390 0.10000E+01 0.0000 20 AlO+ 0.50437E-12 -12.2972 0.48245E-12 -12.3165 0.95654E+00 -0.0193 21 AlOH+2 0.16716E-16 -16.7769 0.14763E-16 -16.8308 0.88318E+00 -0.0540 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.58884E-05 -5.2300 0.56318E-05 -5.2494 0.95644E+00 -0.0193 24 CH4,aq 0.14816E-18 -18.8293 0.14814E-18 -18.8293 0.99989E+00 0.0000 29 CO,aq 0.18262E-17 -17.7384 0.18262E-17 -17.7384 0.10000E+01 0.0000 30 CO2,aq 0.15962E-06 -6.7969 0.15960E-06 -6.7970 0.99989E+00 0.0000 31 CO3-2 0.19557E-06 -6.7087 0.17276E-06 -6.7626 0.88335E+00 -0.0539 32 CaCO3,aq 0.72714E-08 -8.1384 0.72714E-08 -8.1384 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10888E-08 -8.9631 0.10414E-08 -8.9824 0.95654E+00 -0.0193 34 CaCl+ 0.74941E-09 -9.1253 0.71685E-09 -9.1446 0.95654E+00 -0.0193 35 CaCl2,aq 0.22474E-13 -13.6483 0.22474E-13 -13.6483 0.10000E+01 0.0000 36 CaOH+ 0.40699E-07 -7.3904 0.38930E-07 -7.4097 0.95654E+00 -0.0193 37 CaSO4,aq 0.23985E-07 -7.6201 0.23985E-07 -7.6201 0.10000E+01 0.0000 38 HCl,aq 0.14860E-12 -12.8280 0.14860E-12 -12.8280 0.10000E+01 0.0000 43 FeCl+ 0.17302E-13 -13.7619 0.16550E-13 -13.7812 0.95654E+00 -0.0193 46 FeO,aq 0.81547E-10 -10.0886 0.81547E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.43878E-09 -9.3578 0.41971E-09 -9.3771 0.95654E+00 -0.0193 48 HFeO2- 0.14516E-09 -9.8381 0.13885E-09 -9.8575 0.95649E+00 -0.0193 49 FeO+ 0.49037E-13 -13.3095 0.46906E-13 -13.3288 0.95654E+00 -0.0193 50 FeOH+2 0.62328E-19 -19.2053 0.55047E-19 -19.2593 0.88318E+00 -0.0540 51 FeO2- 0.26572E-09 -9.5756 0.25416E-09 -9.5949 0.95649E+00 -0.0193 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45555E-09 -9.3415 0.45550E-09 -9.3415 0.99989E+00 0.0000 54 KCl,aq 0.65547E-10 -10.1834 0.65547E-10 -10.1834 0.10000E+01 0.0000 55 KHSO4,aq 0.10715E-16 -16.9700 0.10715E-16 -16.9700 0.10000E+01 0.0000 56 KOH,aq 0.19046E-08 -8.7202 0.19046E-08 -8.7202 0.10000E+01 0.0000 57 KSO4- 0.10005E-07 -7.9998 0.95692E-08 -8.0191 0.95649E+00 -0.0193 58 MgCO3,aq 0.72909E-11 -11.1372 0.72909E-11 -11.1372 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.44503E-11 -11.3516 0.42569E-11 -11.3709 0.95654E+00 -0.0193 60 MgCl+ 0.27171E-11 -11.5659 0.25990E-11 -11.5852 0.95654E+00 -0.0193 61 MgOH+ 0.90087E-09 -9.0453 0.86172E-09 -9.0646 0.95654E+00 -0.0193 63 MnO,aq 0.28978E-09 -9.5379 0.28978E-09 -9.5379 0.10000E+01 0.0000 64 MnOH+ 0.54360E-08 -8.2647 0.51997E-08 -8.2840 0.95654E+00 -0.0193 65 MnO2-2 0.28829E-15 -15.5402 0.25466E-15 -15.5940 0.88335E+00 -0.0539 66 HMnO2- 0.35846E-12 -12.4456 0.34286E-12 -12.4649 0.95649E+00 -0.0193 69 MnCl+ 0.89770E-11 -11.0469 0.85869E-11 -11.0662 0.95654E+00 -0.0193 70 MnSO4,aq 0.68643E-10 -10.1634 0.68643E-10 -10.1634 0.10000E+01 0.0000 71 NaCl,aq 0.13771E-07 -7.8610 0.13771E-07 -7.8610 0.10000E+01 0.0000 72 NaOH,aq 0.22016E-07 -7.6573 0.22016E-07 -7.6573 0.10000E+01 0.0000 74 OH- 0.98302E-04 -4.0074 0.94020E-04 -4.0268 0.95644E+00 -0.0193 79 HPO3-2 0.21365E-19 -19.6703 0.18872E-19 -19.7242 0.88335E+00 -0.0539 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.15757E-08 -8.8025 0.15072E-08 -8.8218 0.95651E+00 -0.0193 84 PO4-3 0.22792E-11 -11.6422 0.17652E-11 -11.7532 0.77448E+00 -0.1110 87 H2P2O7-2 0.20164E-18 -18.6954 0.17811E-18 -18.7493 0.88335E+00 -0.0539 88 HP2O7-3 0.74833E-17 -17.1259 0.57874E-17 -17.2375 0.77338E+00 -0.1116 89 P2O7-4 0.35011E-18 -18.4558 0.22499E-18 -18.6478 0.64262E+00 -0.1920 90 H2S,aq 0.53629E-14 -14.2706 0.53623E-14 -14.2706 0.99989E+00 0.0000 97 SO3-2 0.15071E-14 -14.8218 0.13319E-14 -14.8755 0.88372E+00 -0.0537 98 HSO3- 0.53578E-15 -15.2710 0.51247E-15 -15.2903 0.95649E+00 -0.0193 99 HSO4- 0.13931E-09 -9.8560 0.13326E-09 -9.8753 0.95657E+00 -0.0193 Charge balance for all species = 0.7197E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6423664E-08 -.1816501E-03 -.1830820E+00 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9999414E+06 0.0000 3 Cl- 0.1379641E-03 0.1379787E-03 0.4891479E+01 4.3319 4 SO4-- 0.2547111E-04 0.2550525E-04 0.2449935E+01 11.7751 5 HCO3- 0.1270687E-04 0.1307043E-04 0.7974754E+00 3.2962 6 HS- 0.2951798E-12 0.5613685E-10 0.1856452E-05 -4.3378 7 Al+++ 0.1731667E-21 0.5903985E-05 0.1592893E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4332114E-03 0.4163590E+02 -3.4276 9 Ca++ 0.3800569E-05 0.3878898E-05 0.1554496E+00 10.9488 10 Mg++ 0.1520514E-07 0.1614306E-07 0.3924475E-03 8.5509 11 Fe++ 0.8972109E-10 0.1219634E-08 0.6810898E-04 6.3218 12 K+ 0.2865139E-04 0.2866336E-04 0.1120731E+01 3.6493 13 Na+ 0.3292149E-03 0.3295397E-03 0.7575619E+01 4.7096 14 Mn++ 0.1196519E-07 0.1776893E-07 0.9761337E-03 8.4469 15 HPO4-- 0.1504982E-07 0.1662779E-07 0.1595828E-02 8.5466 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2222360E-02 -.1816442E-03 -.2040715E-02 0.0000000E+00 2 H2O 0.5550656E+02 0.5550647E+02 0.8459385E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2924578E-04 0.2550441E-04 0.3741366E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3741310E-05 0.5613500E-10 -.3741366E-05 0.0000000E+00 7 Al+++ 0.4402001E-03 0.5903791E-05 0.4342963E-03 0.0000000E+00 8 H4SiO4 0.1405726E-02 0.4331972E-03 0.9725285E-03 0.0000000E+00 9 Ca++ 0.1697403E-03 0.3878771E-05 0.1658615E-03 0.0000000E+00 10 Mg++ 0.1071429E-03 0.1614252E-07 0.1071267E-03 0.0000000E+00 11 Fe++ 0.9625616E-04 0.1219594E-08 0.9625494E-04 0.0000000E+00 12 K+ 0.2866242E-04 0.2866242E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3295289E-03 0.3295289E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2340710E-05 0.1776835E-07 0.2322942E-05 0.0000000E+00 15 HPO4-- 0.7988728E-06 0.1662725E-07 0.7822456E-06 0.0000000E+00 Chg. balance for solid moles: -.2607E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1350000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2607E-06 -6.584 0.1310E-03 -3.883 0.1094 0.4162E-04 clinochlore 0.2143E-04 -4.669 0.1191E-01 -1.924 9.947 0.4530E-02 daphnite 0.1326E-04 -4.877 0.9465E-02 -2.024 7.905 0.2868E-02 chlorite-Mn 0.4646E-06 -6.333 0.3294E-03 -3.482 0.2751 0.1050E-03 hematite 0.1497E-04 -4.825 0.2390E-02 -2.622 1.996 0.4530E-03 kaolinite 0.1744E-04 -4.759 0.4501E-02 -2.347 3.760 0.1732E-02 lawsonite 0.6394E-04 -4.194 0.2009E-01 -1.697 16.78 0.6480E-02 stilbite 0.1006E-03 -3.997 0.7091E-01 -1.149 59.22 0.3307E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1322E-01 0.1322E-01 1.0000 -1.879 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.119724 g Volume = 0.049281 cm3 Porosity: 95.3244% V(tot) - V(min): 0.10047E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1350000 g log = -0.8697 Original solution: 1000.0103000 g Original solution / Rock added: 7407.48 (Water/Rock Ratio), log = 3.8697 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1662E-04 1.0071 0.1708E-04 0.1696E-04 CH4,gas 0.2111E-15 1.0125 0.2181E-15 0.2154E-15 H2,gas 0.5858E-06 1.0005 0.5980E-06 0.5977E-06 H2S,gas 0.1450E-12 0.9960 0.1474E-12 0.1480E-12 S2,gas 0.2235E-32 1.0000 0.2281E-32 0.2281E-32 CO,gas 0.2667E-14 1.0000 0.2721E-14 0.2721E-14 SO3,gas 0.3149E-36 1.0000 0.3213E-36 0.3213E-36 SO2,gas 0.7326E-20 1.0000 0.7475E-20 0.7475E-20 HCl,gas 0.2570E-15 1.0000 0.2622E-15 0.2622E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.13 -6.47 -2.156 0.11042E+05 -4.768 3 CH4,gas 4.54 -12.82 -17.36 -4.340 0.29642E+05 -15.661 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.76 -14.53 -7.265 0.24810E+05 -12.831 6 S2,gas -7.34 -41.68 -34.34 -5.283 0.58636E+05 -32.642 7 CO,gas 3.21 -13.05 -16.26 -5.004 0.27771E+05 -14.565 8 SO3,gas 17.12 -21.07 -38.19 -9.548 0.65212E+05 -36.493 9 SO2,gas 0.83 -20.99 -21.83 -5.820 0.37266E+05 -20.126 10 HCl,gas 5.19 -12.09 -17.28 -8.640 0.29506E+05 -15.581 11 acmite 7.71 4.14 -3.57 -0.371 0.60995E+04 15 albite-high 0.69 -2.81 -3.51 -0.270 0.59848E+04 16 albite -0.38 -2.81 -2.43 -0.187 0.41460E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66200E+04 20 analcite 3.32 0.62 -2.71 -0.301 0.46209E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -10.12 -4.81 -2.403 0.82045E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.18 -3.14 -1.048 0.53690E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.18 -2.99 -0.997 0.51048E+04 38 carnegieite-low 9.02 4.04 -4.98 -0.711 0.85033E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29429E+04 42 celadonite 5.34 1.25 -4.09 -0.241 0.69846E+04 43 celadonite-Fe 3.88 -0.98 -4.85 -0.286 0.82891E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12924E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14673E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64762E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82465E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68798E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.62 -3.60 -0.360 0.61463E+04 97 kalsilite 7.58 2.98 -4.60 -0.657 0.78561E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.44 -4.56 -0.456 0.77922E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20479E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.87 -1.39 -0.107 0.23663E+04 120 muscovite 2.58 1.65 -0.93 -0.055 0.15918E+04 121 paragonite 4.24 2.71 -1.53 -0.090 0.26107E+04 122 nepheline 8.34 4.04 -4.30 -0.614 0.73357E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40628E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.68 -3.70 -1.235 0.63237E+04 152 rhodonite 7.45 5.02 -2.43 -0.485 0.41431E+04 153 sanidine -1.28 -3.87 -2.60 -0.200 0.44340E+04 155 siderite -2.61 -6.80 -4.20 -1.399 0.71658E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.54 -1.48 -0.044 0.25298E+04 165 stilpnomelane-Mg 27.44 22.68 -4.76 -0.142 0.81287E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83503E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77669E+04 174 tephroite 18.09 13.47 -4.62 -0.660 0.78879E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.94 -3.42 -0.210 0.58416E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.59 -3.25 -0.199 0.55481E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.07 -2.84 -0.174 0.48431E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.72 -2.69 -0.164 0.45853E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.10 -1.24 -0.079 0.21146E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.45 -1.07 -0.069 0.18228E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59586E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.33 -2.34 -0.180 0.40026E+04 243 an25ab75 2.65 0.30 -2.35 -0.181 0.40137E+04 244 an30ab70 3.28 0.92 -2.36 -0.182 0.40345E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1350000 g New total amount of reactant added: 0.1390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1390000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3433941E-03 Osmotic coef. = 0.9889 True ionic strength = .4002466E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.62217E-08 -8.2061 0.59510E-08 -8.2254 0.95650E+00 -0.0193 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13194E-03 -3.8796 0.95633E+00 -0.0194 4 SO4-- 0.25472E-04 -4.5939 0.22487E-04 -4.6481 0.88281E+00 -0.0541 5 HCO3- 0.12706E-04 -4.8960 0.12151E-04 -4.9154 0.95637E+00 -0.0194 6 HS- 0.28569E-12 -12.5441 0.27321E-12 -12.5635 0.95633E+00 -0.0194 7 Al+++ 0.15750E-21 -21.8027 0.12162E-21 -21.9150 0.77221E+00 -0.1123 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.35666E-05 -5.4478 0.31479E-05 -5.5020 0.88263E+00 -0.0542 10 Mg++ 0.14269E-07 -7.8456 0.12592E-07 -7.8999 0.88251E+00 -0.0543 11 Fe++ 0.84195E-10 -10.0747 0.74306E-10 -10.1290 0.88254E+00 -0.0543 12 K+ 0.29500E-04 -4.5302 0.28213E-04 -4.5495 0.95637E+00 -0.0194 13 Na+ 0.33422E-03 -3.4760 0.31962E-03 -3.4954 0.95632E+00 -0.0194 14 Mn++ 0.11235E-07 -7.9494 0.99155E-08 -8.0037 0.88256E+00 -0.0543 15 HPO4-- 0.16059E-07 -7.7943 0.14177E-07 -7.8484 0.88282E+00 -0.0541 16 HSiO3- 0.61292E-04 -4.2126 0.58615E-04 -4.2320 0.95633E+00 -0.0194 17 Ca(HSiO3)+ 0.43938E-08 -8.3572 0.42021E-08 -8.3765 0.95638E+00 -0.0194 18 Mg(HSiO3)+ 0.21874E-10 -10.6601 0.20920E-10 -10.6794 0.95638E+00 -0.0194 19 NaHSiO3,aq 0.30301E-06 -6.5185 0.30301E-06 -6.5185 0.10000E+01 0.0000 20 AlO+ 0.48851E-12 -12.3111 0.46721E-12 -12.3305 0.95638E+00 -0.0194 21 AlOH+2 0.15686E-16 -16.8045 0.13844E-16 -16.8587 0.88258E+00 -0.0542 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.60815E-05 -5.2160 0.58156E-05 -5.2354 0.95628E+00 -0.0194 24 CH4,aq 0.14342E-18 -18.8434 0.14341E-18 -18.8434 0.99989E+00 0.0000 29 CO,aq 0.17680E-17 -17.7525 0.17680E-17 -17.7525 0.10000E+01 0.0000 30 CO2,aq 0.15453E-06 -6.8110 0.15452E-06 -6.8110 0.99989E+00 0.0000 31 CO3-2 0.20204E-06 -6.6946 0.17835E-06 -6.7487 0.88276E+00 -0.0542 32 CaCO3,aq 0.70398E-08 -8.1524 0.70398E-08 -8.1524 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10210E-08 -8.9910 0.97642E-09 -9.0104 0.95638E+00 -0.0194 34 CaCl+ 0.70280E-09 -9.1532 0.67214E-09 -9.1725 0.95638E+00 -0.0194 35 CaCl2,aq 0.21069E-13 -13.6764 0.21069E-13 -13.6764 0.10000E+01 0.0000 36 CaOH+ 0.39419E-07 -7.4043 0.37700E-07 -7.4237 0.95638E+00 -0.0194 37 CaSO4,aq 0.22479E-07 -7.6482 0.22479E-07 -7.6482 0.10000E+01 0.0000 38 HCl,aq 0.14388E-12 -12.8420 0.14388E-12 -12.8420 0.10000E+01 0.0000 43 FeCl+ 0.16225E-13 -13.7898 0.15518E-13 -13.8092 0.95638E+00 -0.0194 46 FeO,aq 0.81546E-10 -10.0886 0.81546E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.42498E-09 -9.3716 0.40644E-09 -9.3910 0.95638E+00 -0.0194 48 HFeO2- 0.14992E-09 -9.8241 0.14337E-09 -9.8435 0.95633E+00 -0.0194 49 FeO+ 0.47495E-13 -13.3233 0.45424E-13 -13.3427 0.95638E+00 -0.0194 50 FeOH+2 0.58490E-19 -19.2329 0.51623E-19 -19.2872 0.88258E+00 -0.0542 51 FeO2- 0.27444E-09 -9.5616 0.26245E-09 -9.5810 0.95633E+00 -0.0194 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45553E-09 -9.3415 0.45549E-09 -9.3415 0.99989E+00 0.0000 54 KCl,aq 0.67466E-10 -10.1709 0.67466E-10 -10.1709 0.10000E+01 0.0000 55 KHSO4,aq 0.10675E-16 -16.9716 0.10675E-16 -16.9716 0.10000E+01 0.0000 56 KOH,aq 0.20246E-08 -8.6937 0.20246E-08 -8.6937 0.10000E+01 0.0000 57 KSO4- 0.10295E-07 -7.9874 0.98450E-08 -8.0068 0.95633E+00 -0.0194 58 MgCO3,aq 0.70587E-11 -11.1513 0.70587E-11 -11.1513 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.41731E-11 -11.3795 0.39911E-11 -11.3989 0.95638E+00 -0.0194 60 MgCl+ 0.25480E-11 -11.5938 0.24369E-11 -11.6132 0.95638E+00 -0.0194 61 MgOH+ 0.87255E-09 -9.0592 0.83449E-09 -9.0786 0.95638E+00 -0.0194 63 MnO,aq 0.28995E-09 -9.5377 0.28995E-09 -9.5377 0.10000E+01 0.0000 64 MnOH+ 0.52681E-08 -8.2783 0.50383E-08 -8.2977 0.95638E+00 -0.0194 65 MnO2-2 0.30780E-15 -15.5117 0.27171E-15 -15.5659 0.88276E+00 -0.0542 66 HMnO2- 0.37043E-12 -12.4313 0.35425E-12 -12.4507 0.95633E+00 -0.0194 69 MnCl+ 0.84235E-11 -11.0745 0.80561E-11 -11.0939 0.95638E+00 -0.0194 70 MnSO4,aq 0.64371E-10 -10.1913 0.64371E-10 -10.1913 0.10000E+01 0.0000 71 NaCl,aq 0.13975E-07 -7.8546 0.13975E-07 -7.8546 0.10000E+01 0.0000 72 NaOH,aq 0.23076E-07 -7.6368 0.23076E-07 -7.6368 0.10000E+01 0.0000 74 OH- 0.10153E-03 -3.9934 0.97088E-04 -4.0128 0.95628E+00 -0.0194 79 HPO3-2 0.22796E-19 -19.6421 0.20124E-19 -19.6963 0.88276E+00 -0.0542 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.16274E-08 -8.7885 0.15564E-08 -8.8079 0.95635E+00 -0.0194 84 PO4-3 0.25134E-11 -11.5997 0.19437E-11 -11.7114 0.77333E+00 -0.1116 87 H2P2O7-2 0.21515E-18 -18.6673 0.18993E-18 -18.7214 0.88276E+00 -0.0542 88 HP2O7-3 0.82525E-17 -17.0834 0.63727E-17 -17.1957 0.77222E+00 -0.1123 89 P2O7-4 0.39916E-18 -18.3988 0.25582E-18 -18.5921 0.64090E+00 -0.1932 90 H2S,aq 0.50256E-14 -14.2988 0.50250E-14 -14.2989 0.99989E+00 0.0000 97 SO3-2 0.15072E-14 -14.8218 0.13310E-14 -14.8758 0.88314E+00 -0.0540 98 HSO3- 0.51860E-15 -15.2852 0.49595E-15 -15.3046 0.95633E+00 -0.0194 99 HSO4- 0.13485E-09 -9.8702 0.12897E-09 -9.8895 0.95641E+00 -0.0194 Charge balance for all species = 0.7198E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6221702E-08 -.1876198E-03 -.1890986E+00 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9999411E+06 0.0000 3 Cl- 0.1379641E-03 0.1379788E-03 0.4891481E+01 4.3458 4 SO4-- 0.2547236E-04 0.2550527E-04 0.2449936E+01 11.8028 5 HCO3- 0.1270580E-04 0.1307044E-04 0.7974757E+00 3.3100 6 HS- 0.2856877E-12 0.5503418E-10 0.1819986E-05 -4.3381 7 Al+++ 0.1575008E-21 0.6097166E-05 0.1645012E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4351721E-03 0.4182433E+02 -3.4276 9 Ca++ 0.3566553E-05 0.3641608E-05 0.1459399E+00 10.9488 10 Mg++ 0.1426888E-07 0.1517708E-07 0.3689639E-03 8.5509 11 Fe++ 0.8419542E-10 0.1213780E-08 0.6778208E-04 6.3218 12 K+ 0.2950029E-04 0.2951267E-04 0.1153938E+01 3.6759 13 Na+ 0.3342211E-03 0.3345611E-03 0.7691050E+01 4.7300 14 Mn++ 0.1123498E-07 0.1686624E-07 0.9265440E-03 8.4471 15 HPO4-- 0.1605881E-07 0.1768871E-07 0.1697647E-02 8.6024 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2288594E-02 -.1876135E-03 -.2100980E-02 0.0000000E+00 2 H2O 0.5550651E+02 0.5550643E+02 0.7612548E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2935663E-04 0.2550441E-04 0.3852219E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3852164E-05 0.5503233E-10 -.3852219E-05 0.0000000E+00 7 Al+++ 0.4532431E-03 0.6096961E-05 0.4471461E-03 0.0000000E+00 8 H4SiO4 0.1447377E-02 0.4351575E-03 0.1012219E-02 0.0000000E+00 9 Ca++ 0.1743409E-03 0.3641485E-05 0.1706994E-03 0.0000000E+00 10 Mg++ 0.1103175E-03 0.1517657E-07 0.1103023E-03 0.0000000E+00 11 Fe++ 0.9910819E-04 0.1213739E-08 0.9910698E-04 0.0000000E+00 12 K+ 0.2951168E-04 0.2951168E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3345499E-03 0.3345499E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2410065E-05 0.1686567E-07 0.2393199E-05 0.0000000E+00 15 HPO4-- 0.8225431E-06 0.1768812E-07 0.8048550E-06 0.0000000E+00 Chg. balance for solid moles: 0.2770E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2683E-06 -6.571 0.1348E-03 -3.870 0.1086 0.4282E-04 clinochlore 0.2206E-04 -4.656 0.1226E-01 -1.911 9.879 0.4664E-02 daphnite 0.1366E-04 -4.865 0.9745E-02 -2.011 7.852 0.2953E-02 chlorite-Mn 0.4786E-06 -6.320 0.3393E-03 -3.469 0.2734 0.1081E-03 hematite 0.1541E-04 -4.812 0.2461E-02 -2.609 1.983 0.4664E-03 kaolinite 0.1802E-04 -4.744 0.4652E-02 -2.332 3.748 0.1790E-02 lawsonite 0.6358E-04 -4.197 0.1998E-01 -1.699 16.10 0.6443E-02 stilbite 0.1058E-03 -3.976 0.7454E-01 -1.128 60.06 0.3477E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1322E-01 0.1322E-01 1.0000 -1.879 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.124116 g Volume = 0.051235 cm3 Porosity: 95.1464% V(tot) - V(min): 0.10044E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1390000 g log = -0.8570 Original solution: 1000.0103000 g Original solution / Rock added: 7194.32 (Water/Rock Ratio), log = 3.8570 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1609E-04 1.0071 0.1653E-04 0.1642E-04 CH4,gas 0.2043E-15 1.0125 0.2111E-15 0.2085E-15 H2,gas 0.5858E-06 1.0005 0.5980E-06 0.5977E-06 H2S,gas 0.1359E-12 0.9960 0.1381E-12 0.1387E-12 S2,gas 0.1963E-32 1.0000 0.2003E-32 0.2003E-32 CO,gas 0.2582E-14 1.0000 0.2635E-14 0.2635E-14 SO3,gas 0.2951E-36 1.0000 0.3011E-36 0.3011E-36 SO2,gas 0.6866E-20 1.0000 0.7005E-20 0.7005E-20 HCl,gas 0.2488E-15 1.0000 0.2539E-15 0.2539E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.18578E-10 102 lawsonite 9.62 9.62 0.00 0.000 -0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.14 -6.48 -2.160 0.11066E+05 -4.782 3 CH4,gas 4.54 -12.83 -17.37 -4.344 0.29666E+05 -15.676 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.79 -14.56 -7.279 0.24859E+05 -12.860 6 S2,gas -7.34 -41.73 -34.40 -5.292 0.58732E+05 -32.698 7 CO,gas 3.21 -13.06 -16.28 -5.009 0.27795E+05 -14.579 8 SO3,gas 17.12 -21.10 -38.22 -9.555 0.65260E+05 -36.521 9 SO2,gas 0.83 -21.02 -21.85 -5.828 0.37314E+05 -20.155 10 HCl,gas 5.19 -12.11 -17.29 -8.647 0.29530E+05 -15.595 11 acmite 7.71 4.16 -3.55 -0.369 0.60646E+04 15 albite-high 0.69 -2.79 -3.48 -0.268 0.59499E+04 16 albite -0.38 -2.79 -2.41 -0.185 0.41111E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66187E+04 20 analcite 3.32 0.64 -2.69 -0.298 0.45860E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -10.15 -4.83 -2.417 0.82526E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.19 -3.16 -1.053 0.53930E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.19 -3.00 -1.001 0.51288E+04 38 carnegieite-low 9.02 4.06 -4.96 -0.709 0.84684E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29429E+04 42 celadonite 5.34 1.28 -4.06 -0.239 0.69393E+04 43 celadonite-Fe 3.88 -0.95 -4.83 -0.284 0.82438E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12924E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14669E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64762E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82465E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68798E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.64 -3.58 -0.358 0.61115E+04 97 kalsilite 7.58 3.01 -4.57 -0.653 0.78107E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.42 -4.54 -0.454 0.77468E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20479E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.85 -1.36 -0.105 0.23209E+04 120 muscovite 2.58 1.68 -0.91 -0.053 0.15465E+04 121 paragonite 4.24 2.73 -1.51 -0.089 0.25758E+04 122 nepheline 8.34 4.06 -4.28 -0.611 0.73008E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40624E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.69 -3.72 -1.239 0.63472E+04 152 rhodonite 7.45 5.02 -2.43 -0.485 0.41426E+04 153 sanidine -1.28 -3.85 -2.57 -0.198 0.43887E+04 155 siderite -2.61 -6.82 -4.21 -1.404 0.71898E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.55 -1.47 -0.044 0.25072E+04 165 stilpnomelane-Mg 27.44 22.69 -4.75 -0.142 0.81060E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83503E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77669E+04 174 tephroite 18.09 13.47 -4.62 -0.660 0.78871E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.93 -3.41 -0.209 0.58266E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.58 -3.24 -0.199 0.55366E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.06 -2.83 -0.173 0.48282E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.72 -2.68 -0.164 0.45738E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.11 -1.23 -0.079 0.20996E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.46 -1.06 -0.068 0.18112E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59586E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.31 -2.33 -0.179 0.39747E+04 243 an25ab75 2.65 0.31 -2.34 -0.180 0.39876E+04 244 an30ab70 3.28 0.93 -2.35 -0.181 0.40101E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1390000 g New total amount of reactant added: 0.1430000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1430000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3467693E-03 Osmotic coef. = 0.9889 True ionic strength = .4054605E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.60308E-08 -8.2196 0.57675E-08 -8.2390 0.95634E+00 -0.0194 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13192E-03 -3.8797 0.95616E+00 -0.0195 4 SO4-- 0.25473E-04 -4.5939 0.22473E-04 -4.6483 0.88222E+00 -0.0544 5 HCO3- 0.12704E-04 -4.8960 0.12148E-04 -4.9155 0.95621E+00 -0.0194 6 HS- 0.27672E-12 -12.5580 0.26459E-12 -12.5774 0.95617E+00 -0.0195 7 Al+++ 0.14359E-21 -21.8429 0.11071E-21 -21.9558 0.77104E+00 -0.1129 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.33522E-05 -5.4747 0.29567E-05 -5.5292 0.88203E+00 -0.0545 10 Mg++ 0.13411E-07 -7.8725 0.11828E-07 -7.9271 0.88191E+00 -0.0546 11 Fe++ 0.79134E-10 -10.1016 0.69792E-10 -10.1562 0.88194E+00 -0.0546 12 K+ 0.30349E-04 -4.5179 0.29020E-04 -4.5373 0.95621E+00 -0.0194 13 Na+ 0.33923E-03 -3.4695 0.32436E-03 -3.4890 0.95616E+00 -0.0195 14 Mn++ 0.10565E-07 -7.9761 0.93181E-08 -8.0307 0.88196E+00 -0.0546 15 HPO4-- 0.17109E-07 -7.7668 0.15094E-07 -7.8212 0.88222E+00 -0.0544 16 HSiO3- 0.63253E-04 -4.1989 0.60481E-04 -4.2184 0.95616E+00 -0.0195 17 Ca(HSiO3)+ 0.42590E-08 -8.3707 0.40725E-08 -8.3901 0.95622E+00 -0.0194 18 Mg(HSiO3)+ 0.21203E-10 -10.6736 0.20274E-10 -10.6931 0.95622E+00 -0.0194 19 NaHSiO3,aq 0.31728E-06 -6.4986 0.31728E-06 -6.4986 0.10000E+01 0.0000 20 AlO+ 0.47353E-12 -12.3247 0.45280E-12 -12.3441 0.95622E+00 -0.0194 21 AlOH+2 0.14744E-16 -16.8314 0.13004E-16 -16.8859 0.88199E+00 -0.0545 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.62761E-05 -5.2023 0.60007E-05 -5.2218 0.95611E+00 -0.0195 24 CH4,aq 0.13895E-18 -18.8572 0.13893E-18 -18.8572 0.99989E+00 0.0000 29 CO,aq 0.17130E-17 -17.7663 0.17130E-17 -17.7663 0.10000E+01 0.0000 30 CO2,aq 0.14972E-06 -6.8247 0.14971E-06 -6.8248 0.99989E+00 0.0000 31 CO3-2 0.20855E-06 -6.6808 0.18398E-06 -6.7352 0.88216E+00 -0.0545 32 CaCO3,aq 0.68208E-08 -8.1662 0.68208E-08 -8.1662 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.95884E-09 -9.0183 0.91686E-09 -9.0377 0.95622E+00 -0.0194 34 CaCl+ 0.66011E-09 -9.1804 0.63121E-09 -9.1998 0.95622E+00 -0.0194 35 CaCl2,aq 0.19782E-13 -13.7037 0.19782E-13 -13.7037 0.10000E+01 0.0000 36 CaOH+ 0.38210E-07 -7.4178 0.36537E-07 -7.4373 0.95622E+00 -0.0194 37 CaSO4,aq 0.21100E-07 -7.6757 0.21100E-07 -7.6757 0.10000E+01 0.0000 38 HCl,aq 0.13942E-12 -12.8557 0.13942E-12 -12.8557 0.10000E+01 0.0000 43 FeCl+ 0.15240E-13 -13.8170 0.14573E-13 -13.8365 0.95622E+00 -0.0194 46 FeO,aq 0.81545E-10 -10.0886 0.81545E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.41193E-09 -9.3852 0.39390E-09 -9.4046 0.95622E+00 -0.0194 48 HFeO2- 0.15472E-09 -9.8105 0.14793E-09 -9.8299 0.95616E+00 -0.0195 49 FeO+ 0.46038E-13 -13.3369 0.44023E-13 -13.3563 0.95622E+00 -0.0194 50 FeOH+2 0.54975E-19 -19.2598 0.48487E-19 -19.3144 0.88199E+00 -0.0545 51 FeO2- 0.28322E-09 -9.5479 0.27080E-09 -9.5673 0.95616E+00 -0.0195 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45552E-09 -9.3415 0.45547E-09 -9.3415 0.99989E+00 0.0000 54 KCl,aq 0.69384E-10 -10.1587 0.69384E-10 -10.1587 0.10000E+01 0.0000 55 KHSO4,aq 0.10635E-16 -16.9733 0.10635E-16 -16.9733 0.10000E+01 0.0000 56 KOH,aq 0.21488E-08 -8.6678 0.21488E-08 -8.6678 0.10000E+01 0.0000 57 KSO4- 0.10584E-07 -7.9753 0.10120E-07 -7.9948 0.95616E+00 -0.0195 58 MgCO3,aq 0.68390E-11 -11.1650 0.68390E-11 -11.1650 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.39192E-11 -11.4068 0.37476E-11 -11.4262 0.95622E+00 -0.0194 60 MgCl+ 0.23933E-11 -11.6210 0.22885E-11 -11.6405 0.95622E+00 -0.0194 61 MgOH+ 0.84578E-09 -9.0727 0.80875E-09 -9.0922 0.95622E+00 -0.0194 63 MnO,aq 0.29010E-09 -9.5375 0.29010E-09 -9.5375 0.10000E+01 0.0000 64 MnOH+ 0.51092E-08 -8.2916 0.48855E-08 -8.3111 0.95622E+00 -0.0194 65 MnO2-2 0.32809E-15 -15.4840 0.28943E-15 -15.5385 0.88216E+00 -0.0545 66 HMnO2- 0.38248E-12 -12.4174 0.36572E-12 -12.4369 0.95616E+00 -0.0195 69 MnCl+ 0.79160E-11 -11.1015 0.75694E-11 -11.1209 0.95622E+00 -0.0194 70 MnSO4,aq 0.60455E-10 -10.2186 0.60455E-10 -10.2186 0.10000E+01 0.0000 71 NaCl,aq 0.14180E-07 -7.8483 0.14180E-07 -7.8483 0.10000E+01 0.0000 72 NaOH,aq 0.24163E-07 -7.6169 0.24163E-07 -7.6169 0.10000E+01 0.0000 74 OH- 0.10478E-03 -3.9797 0.10018E-03 -3.9992 0.95611E+00 -0.0195 79 HPO3-2 0.24286E-19 -19.6146 0.21424E-19 -19.6691 0.88216E+00 -0.0545 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.16795E-08 -8.7748 0.16059E-08 -8.7943 0.95619E+00 -0.0195 84 PO4-3 0.27652E-11 -11.5583 0.21352E-11 -11.6706 0.77217E+00 -0.1123 87 H2P2O7-2 0.22922E-18 -18.6397 0.20221E-18 -18.6942 0.88216E+00 -0.0545 88 HP2O7-3 0.90795E-17 -17.0419 0.70007E-17 -17.1549 0.77105E+00 -0.1129 89 P2O7-4 0.45367E-18 -18.3433 0.28998E-18 -18.5376 0.63918E+00 -0.1944 90 H2S,aq 0.47168E-14 -14.3263 0.47163E-14 -14.3264 0.99989E+00 0.0000 97 SO3-2 0.15072E-14 -14.8218 0.13302E-14 -14.8761 0.88255E+00 -0.0543 98 HSO3- 0.50236E-15 -15.2990 0.48034E-15 -15.3185 0.95616E+00 -0.0195 99 HSO4- 0.13063E-09 -9.8840 0.12491E-09 -9.9034 0.95625E+00 -0.0194 Charge balance for all species = 0.7200E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6030810E-08 -.1936337E-03 -.1951599E+00 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9999407E+06 0.0000 3 Cl- 0.1379640E-03 0.1379789E-03 0.4891484E+01 4.3593 4 SO4-- 0.2547347E-04 0.2550530E-04 0.2449937E+01 11.8297 5 HCO3- 0.1270438E-04 0.1307045E-04 0.7974760E+00 3.3235 6 HS- 0.2767188E-12 0.5392436E-10 0.1783283E-05 -4.3384 7 Al+++ 0.1435896E-21 0.6291778E-05 0.1697518E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4371476E-03 0.4201418E+02 -3.4276 9 Ca++ 0.3352195E-05 0.3424204E-05 0.1372273E+00 10.9488 10 Mg++ 0.1341127E-07 0.1429140E-07 0.3474324E-03 8.5509 11 Fe++ 0.7913412E-10 0.1209249E-08 0.6752900E-04 6.3218 12 K+ 0.3034918E-04 0.3036198E-04 0.1187145E+01 3.7017 13 Na+ 0.3392269E-03 0.3395825E-03 0.7806482E+01 4.7500 14 Mn++ 0.1056525E-07 0.1603328E-07 0.8807851E-03 8.4474 15 HPO4-- 0.1710872E-07 0.1879095E-07 0.1803432E-02 8.6568 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2354828E-02 -.1936270E-03 -.2161201E-02 0.0000000E+00 2 H2O 0.5550646E+02 0.5550639E+02 0.6764973E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2946749E-04 0.2550442E-04 0.3963071E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3963017E-05 0.5392250E-10 -.3963071E-05 0.0000000E+00 7 Al+++ 0.4662861E-03 0.6291562E-05 0.4599945E-03 0.0000000E+00 8 H4SiO4 0.1489028E-02 0.4371325E-03 0.1051895E-02 0.0000000E+00 9 Ca++ 0.1789415E-03 0.3424086E-05 0.1755174E-03 0.0000000E+00 10 Mg++ 0.1134921E-03 0.1429091E-07 0.1134778E-03 0.0000000E+00 11 Fe++ 0.1019602E-03 0.1209207E-08 0.1019590E-03 0.0000000E+00 12 K+ 0.3036093E-04 0.3036093E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3395708E-03 0.3395708E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2479419E-05 0.1603272E-07 0.2463387E-05 0.0000000E+00 15 HPO4-- 0.8462135E-06 0.1879030E-07 0.8274232E-06 0.0000000E+00 Chg. balance for solid moles: 0.2130E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1430000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2758E-06 -6.559 0.1385E-03 -3.858 0.1078 0.4402E-04 clinochlore 0.2270E-04 -4.644 0.1261E-01 -1.899 9.817 0.4798E-02 daphnite 0.1405E-04 -4.852 0.1003E-01 -1.999 7.802 0.3038E-02 chlorite-Mn 0.4927E-06 -6.307 0.3493E-03 -3.457 0.2718 0.1113E-03 hematite 0.1585E-04 -4.800 0.2532E-02 -2.597 1.970 0.4798E-03 kaolinite 0.1862E-04 -4.730 0.4807E-02 -2.318 3.741 0.1850E-02 lawsonite 0.6321E-04 -4.199 0.1986E-01 -1.702 15.46 0.6405E-02 stilbite 0.1109E-03 -3.955 0.7818E-01 -1.107 60.84 0.3646E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1323E-01 0.1323E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.128505 g Volume = 0.053189 cm3 Porosity: 94.9689% V(tot) - V(min): 0.10040E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1430000 g log = -0.8447 Original solution: 1000.0103000 g Original solution / Rock added: 6993.08 (Water/Rock Ratio), log = 3.8447 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1559E-04 1.0071 0.1602E-04 0.1590E-04 CH4,gas 0.1979E-15 1.0125 0.2045E-15 0.2020E-15 H2,gas 0.5858E-06 1.0005 0.5980E-06 0.5977E-06 H2S,gas 0.1276E-12 0.9960 0.1296E-12 0.1302E-12 S2,gas 0.1729E-32 1.0000 0.1764E-32 0.1764E-32 CO,gas 0.2502E-14 1.0000 0.2553E-14 0.2553E-14 SO3,gas 0.2770E-36 1.0000 0.2826E-36 0.2826E-36 SO2,gas 0.6445E-20 1.0000 0.6576E-20 0.6576E-20 HCl,gas 0.2411E-15 1.0000 0.2460E-15 0.2460E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.15 -6.49 -2.165 0.11089E+05 -4.795 3 CH4,gas 4.54 -12.84 -17.39 -4.347 0.29690E+05 -15.689 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.82 -14.59 -7.293 0.24906E+05 -12.887 6 S2,gas -7.34 -41.79 -34.45 -5.300 0.58826E+05 -32.753 7 CO,gas 3.21 -13.08 -16.29 -5.013 0.27818E+05 -14.593 8 SO3,gas 17.12 -21.13 -38.25 -9.562 0.65307E+05 -36.549 9 SO2,gas 0.83 -21.05 -21.88 -5.835 0.37361E+05 -20.182 10 HCl,gas 5.19 -12.12 -17.31 -8.654 0.29553E+05 -15.609 11 acmite 7.71 4.18 -3.53 -0.367 0.60305E+04 15 albite-high 0.69 -2.77 -3.46 -0.267 0.59158E+04 16 albite -0.38 -2.77 -2.39 -0.184 0.40770E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66176E+04 20 analcite 3.32 0.66 -2.67 -0.296 0.45518E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -10.18 -4.86 -2.430 0.82995E+04 26 annite 20.12 15.15 -4.98 -0.277 0.84995E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.21 -3.17 -1.057 0.54164E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.21 -3.02 -1.006 0.51522E+04 38 carnegieite-low 9.02 4.08 -4.94 -0.706 0.84343E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.30 -4.04 -0.238 0.68952E+04 43 celadonite-Fe 3.88 -0.93 -4.80 -0.282 0.81997E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12924E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14665E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64762E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82466E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68799E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.66 -3.56 -0.356 0.60773E+04 97 kalsilite 7.58 3.04 -4.55 -0.650 0.77666E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.39 -4.51 -0.451 0.77027E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20479E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.82 -1.33 -0.103 0.22768E+04 120 muscovite 2.58 1.70 -0.88 -0.052 0.15024E+04 121 paragonite 4.24 2.75 -1.49 -0.088 0.25417E+04 122 nepheline 8.34 4.08 -4.26 -0.608 0.72667E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40620E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.71 -3.73 -1.244 0.63703E+04 152 rhodonite 7.45 5.02 -2.43 -0.485 0.41422E+04 153 sanidine -1.28 -3.82 -2.54 -0.196 0.43445E+04 155 siderite -2.61 -6.83 -4.22 -1.408 0.72133E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.56 -1.46 -0.043 0.24852E+04 165 stilpnomelane-Mg 27.44 22.71 -4.73 -0.141 0.80839E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83503E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.660 0.78863E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.92 -3.40 -0.208 0.58121E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.58 -3.24 -0.198 0.55253E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.06 -2.82 -0.173 0.48136E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.71 -2.67 -0.164 0.45626E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.12 -1.22 -0.078 0.20850E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.47 -1.05 -0.068 0.18000E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.29 -2.31 -0.178 0.39474E+04 243 an25ab75 2.65 0.33 -2.32 -0.178 0.39620E+04 244 an30ab70 3.28 0.94 -2.33 -0.180 0.39862E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1430000 g New total amount of reactant added: 0.1470000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1470000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3501864E-03 Osmotic coef. = 0.9888 True ionic strength = .4107276E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.58502E-08 -8.2328 0.55939E-08 -8.2523 0.95618E+00 -0.0195 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13189E-03 -3.8798 0.95600E+00 -0.0195 4 SO4-- 0.25474E-04 -4.5939 0.22459E-04 -4.6486 0.88163E+00 -0.0547 5 HCO3- 0.12703E-04 -4.8961 0.12144E-04 -4.9156 0.95604E+00 -0.0195 6 HS- 0.26824E-12 -12.5715 0.25644E-12 -12.5910 0.95601E+00 -0.0195 7 Al+++ 0.13121E-21 -21.8820 0.10101E-21 -21.9956 0.76986E+00 -0.1136 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.31555E-05 -5.5009 0.27814E-05 -5.5557 0.88143E+00 -0.0548 10 Mg++ 0.12625E-07 -7.8988 0.11126E-07 -7.9537 0.88131E+00 -0.0549 11 Fe++ 0.74491E-10 -10.1279 0.65652E-10 -10.1828 0.88134E+00 -0.0549 12 K+ 0.31198E-04 -4.5059 0.29827E-04 -4.5254 0.95605E+00 -0.0195 13 Na+ 0.34423E-03 -3.4631 0.32909E-03 -3.4827 0.95600E+00 -0.0195 14 Mn++ 0.99501E-08 -8.0022 0.87697E-08 -8.0570 0.88136E+00 -0.0548 15 HPO4-- 0.18199E-07 -7.7399 0.16045E-07 -7.7947 0.88163E+00 -0.0547 16 HSiO3- 0.65228E-04 -4.1856 0.62358E-04 -4.2051 0.95600E+00 -0.0195 17 Ca(HSiO3)+ 0.41315E-08 -8.3839 0.39499E-08 -8.4034 0.95606E+00 -0.0195 18 Mg(HSiO3)+ 0.20568E-10 -10.6868 0.19664E-10 -10.7063 0.95606E+00 -0.0195 19 NaHSiO3,aq 0.33190E-06 -6.4790 0.33190E-06 -6.4790 0.10000E+01 0.0000 20 AlO+ 0.45935E-12 -12.3379 0.43916E-12 -12.3574 0.95606E+00 -0.0195 21 AlOH+2 0.13879E-16 -16.8577 0.12232E-16 -16.9125 0.88139E+00 -0.0548 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.64720E-05 -5.1890 0.61869E-05 -5.2085 0.95595E+00 -0.0196 24 CH4,aq 0.13471E-18 -18.8706 0.13470E-18 -18.8706 0.99989E+00 0.0000 29 CO,aq 0.16608E-17 -17.7797 0.16608E-17 -17.7797 0.10000E+01 0.0000 30 CO2,aq 0.14517E-06 -6.8381 0.14516E-06 -6.8382 0.99989E+00 0.0000 31 CO3-2 0.21510E-06 -6.6674 0.18963E-06 -6.7221 0.88157E+00 -0.0547 32 CaCO3,aq 0.66134E-08 -8.1796 0.66134E-08 -8.1796 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.90185E-09 -9.0449 0.86222E-09 -9.0644 0.95606E+00 -0.0195 34 CaCl+ 0.62097E-09 -9.2069 0.59368E-09 -9.2264 0.95606E+00 -0.0195 35 CaCl2,aq 0.18603E-13 -13.7304 0.18603E-13 -13.7304 0.10000E+01 0.0000 36 CaOH+ 0.37066E-07 -7.4310 0.35437E-07 -7.4505 0.95606E+00 -0.0195 37 CaSO4,aq 0.19836E-07 -7.7025 0.19836E-07 -7.7025 0.10000E+01 0.0000 38 HCl,aq 0.13520E-12 -12.8690 0.13520E-12 -12.8690 0.10000E+01 0.0000 43 FeCl+ 0.14336E-13 -13.8436 0.13706E-13 -13.8631 0.95606E+00 -0.0195 46 FeO,aq 0.81544E-10 -10.0886 0.81544E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.39959E-09 -9.3984 0.38203E-09 -9.4179 0.95606E+00 -0.0195 48 HFeO2- 0.15954E-09 -9.7971 0.15252E-09 -9.8167 0.95600E+00 -0.0195 49 FeO+ 0.44660E-13 -13.3501 0.42697E-13 -13.3696 0.95606E+00 -0.0195 50 FeOH+2 0.51750E-19 -19.2861 0.45612E-19 -19.3409 0.88139E+00 -0.0548 51 FeO2- 0.29206E-09 -9.5345 0.27921E-09 -9.5541 0.95600E+00 -0.0195 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45551E-09 -9.3415 0.45546E-09 -9.3415 0.99989E+00 0.0000 54 KCl,aq 0.71300E-10 -10.1469 0.71300E-10 -10.1469 0.10000E+01 0.0000 55 KHSO4,aq 0.10595E-16 -16.9749 0.10595E-16 -16.9749 0.10000E+01 0.0000 56 KOH,aq 0.22771E-08 -8.6426 0.22771E-08 -8.6426 0.10000E+01 0.0000 57 KSO4- 0.10873E-07 -7.9636 0.10395E-07 -7.9832 0.95600E+00 -0.0195 58 MgCO3,aq 0.66311E-11 -11.1784 0.66311E-11 -11.1784 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.36863E-11 -11.4334 0.35243E-11 -11.4529 0.95606E+00 -0.0195 60 MgCl+ 0.22513E-11 -11.6476 0.21524E-11 -11.6671 0.95606E+00 -0.0195 61 MgOH+ 0.82045E-09 -9.0859 0.78440E-09 -9.1055 0.95606E+00 -0.0195 63 MnO,aq 0.29024E-09 -9.5372 0.29024E-09 -9.5372 0.10000E+01 0.0000 64 MnOH+ 0.49585E-08 -8.3046 0.47406E-08 -8.3242 0.95606E+00 -0.0195 65 MnO2-2 0.34918E-15 -15.4570 0.30782E-15 -15.5117 0.88157E+00 -0.0547 66 HMnO2- 0.39461E-12 -12.4038 0.37724E-12 -12.4234 0.95600E+00 -0.0195 69 MnCl+ 0.74500E-11 -11.1278 0.71227E-11 -11.1474 0.95606E+00 -0.0195 70 MnSO4,aq 0.56860E-10 -10.2452 0.56860E-10 -10.2452 0.10000E+01 0.0000 71 NaCl,aq 0.14384E-07 -7.8421 0.14384E-07 -7.8421 0.10000E+01 0.0000 72 NaOH,aq 0.25276E-07 -7.5973 0.25276E-07 -7.5973 0.10000E+01 0.0000 74 OH- 0.10805E-03 -3.9664 0.10329E-03 -3.9860 0.95595E+00 -0.0196 79 HPO3-2 0.25834E-19 -19.5878 0.22774E-19 -19.6426 0.88157E+00 -0.0547 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.17319E-08 -8.7615 0.16557E-08 -8.7810 0.95603E+00 -0.0195 84 PO4-3 0.30353E-11 -11.5178 0.23403E-11 -11.6307 0.77101E+00 -0.1129 87 H2P2O7-2 0.24383E-18 -18.6129 0.21496E-18 -18.6676 0.88157E+00 -0.0547 88 HP2O7-3 0.99666E-17 -17.0015 0.76730E-17 -17.1150 0.76987E+00 -0.1136 89 P2O7-4 0.51406E-18 -18.2890 0.32769E-18 -18.4845 0.63746E+00 -0.1955 90 H2S,aq 0.44339E-14 -14.3532 0.44334E-14 -14.3533 0.99989E+00 0.0000 97 SO3-2 0.15072E-14 -14.8218 0.13293E-14 -14.8764 0.88196E+00 -0.0546 98 HSO3- 0.48700E-15 -15.3125 0.46557E-15 -15.3320 0.95600E+00 -0.0195 99 HSO4- 0.12664E-09 -9.8974 0.12107E-09 -9.9169 0.95608E+00 -0.0195 Charge balance for all species = 0.7201E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5850242E-08 -.1996876E-03 -.2012613E+00 0.0000 2 H2O 0.1000000E+01 0.5550831E+02 0.9999404E+06 0.0000 3 Cl- 0.1379640E-03 0.1379790E-03 0.4891486E+01 4.3725 4 SO4-- 0.2547448E-04 0.2550532E-04 0.2449939E+01 11.8560 5 HCO3- 0.1270266E-04 0.1307046E-04 0.7974764E+00 3.3367 6 HS- 0.2682376E-12 0.5280810E-10 0.1746368E-05 -4.3387 7 Al+++ 0.1312080E-21 0.6487679E-05 0.1750371E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4391364E-03 0.4220531E+02 -3.4276 9 Ca++ 0.3155543E-05 0.3224713E-05 0.1292325E+00 10.9488 10 Mg++ 0.1262451E-07 0.1347809E-07 0.3276603E-03 8.5509 11 Fe++ 0.7449101E-10 0.1205932E-08 0.6734374E-04 6.3218 12 K+ 0.3119807E-04 0.3121129E-04 0.1220353E+01 3.7269 13 Na+ 0.3442324E-03 0.3446040E-03 0.7921914E+01 4.7696 14 Mn++ 0.9950113E-08 0.1526359E-07 0.8385020E-03 8.4476 15 HPO4-- 0.1819949E-07 0.1993442E-07 0.1913174E-02 8.7099 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2421062E-02 -.1996805E-03 -.2221381E-02 0.0000000E+00 2 H2O 0.5550641E+02 0.5550635E+02 0.5916737E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2957834E-04 0.2550442E-04 0.4073924E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4073871E-05 0.5280624E-10 -.4073924E-05 0.0000000E+00 7 Al+++ 0.4793290E-03 0.6487451E-05 0.4728416E-03 0.0000000E+00 8 H4SiO4 0.1530679E-02 0.4391209E-03 0.1091558E-02 0.0000000E+00 9 Ca++ 0.1835420E-03 0.3224599E-05 0.1803174E-03 0.0000000E+00 10 Mg++ 0.1166667E-03 0.1347762E-07 0.1166532E-03 0.0000000E+00 11 Fe++ 0.1048123E-03 0.1205889E-08 0.1048111E-03 0.0000000E+00 12 K+ 0.3121019E-04 0.3121019E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3445918E-03 0.3445918E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2548774E-05 0.1526305E-07 0.2533511E-05 0.0000000E+00 15 HPO4-- 0.8698838E-06 0.1993371E-07 0.8499500E-06 0.0000000E+00 Chg. balance for solid moles: -.1637E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1470000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2833E-06 -6.548 0.1423E-03 -3.847 0.1071 0.4522E-04 clinochlore 0.2333E-04 -4.632 0.1297E-01 -1.887 9.758 0.4933E-02 daphnite 0.1444E-04 -4.840 0.1031E-01 -1.987 7.755 0.3123E-02 chlorite-Mn 0.5067E-06 -6.295 0.3592E-03 -3.445 0.2703 0.1145E-03 hematite 0.1630E-04 -4.788 0.2602E-02 -2.585 1.958 0.4933E-03 kaolinite 0.1924E-04 -4.716 0.4967E-02 -2.304 3.737 0.1911E-02 lawsonite 0.6281E-04 -4.202 0.1974E-01 -1.705 14.85 0.6365E-02 stilbite 0.1161E-03 -3.935 0.8181E-01 -1.087 61.56 0.3816E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1324E-01 0.1324E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.132892 g Volume = 0.055142 cm3 Porosity: 94.7920% V(tot) - V(min): 0.10037E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1470000 g log = -0.8327 Original solution: 1000.0103000 g Original solution / Rock added: 6802.79 (Water/Rock Ratio), log = 3.8327 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1511E-04 1.0071 0.1553E-04 0.1542E-04 CH4,gas 0.1919E-15 1.0125 0.1983E-15 0.1958E-15 H2,gas 0.5857E-06 1.0005 0.5980E-06 0.5976E-06 H2S,gas 0.1199E-12 0.9960 0.1219E-12 0.1224E-12 S2,gas 0.1528E-32 1.0000 0.1559E-32 0.1559E-32 CO,gas 0.2426E-14 1.0000 0.2475E-14 0.2475E-14 SO3,gas 0.2604E-36 1.0000 0.2657E-36 0.2657E-36 SO2,gas 0.6059E-20 1.0000 0.6182E-20 0.6182E-20 HCl,gas 0.2338E-15 1.0000 0.2386E-15 0.2386E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.15165E-10 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.17 -6.51 -2.169 0.11112E+05 -4.809 3 CH4,gas 4.54 -12.86 -17.40 -4.350 0.29713E+05 -15.703 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.84 -14.61 -7.307 0.24951E+05 -12.914 6 S2,gas -7.34 -41.84 -34.51 -5.309 0.58918E+05 -32.807 7 CO,gas 3.21 -13.09 -16.31 -5.017 0.27841E+05 -14.606 8 SO3,gas 17.12 -21.15 -38.27 -9.569 0.65353E+05 -36.576 9 SO2,gas 0.83 -21.08 -21.91 -5.842 0.37407E+05 -20.209 10 HCl,gas 5.19 -12.13 -17.32 -8.661 0.29576E+05 -15.622 11 acmite 7.71 4.20 -3.51 -0.365 0.59971E+04 15 albite-high 0.69 -2.75 -3.45 -0.265 0.58824E+04 16 albite -0.38 -2.75 -2.37 -0.182 0.40436E+04 19 spessartine 24.46 20.58 -3.88 -0.194 0.66165E+04 20 analcite 3.32 0.68 -2.65 -0.294 0.45184E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -10.20 -4.89 -2.444 0.83453E+04 26 annite 20.12 15.17 -4.95 -0.275 0.84565E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.22 -3.19 -1.062 0.54393E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.22 -3.03 -1.010 0.51751E+04 38 carnegieite-low 9.02 4.10 -4.92 -0.703 0.84009E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.33 -4.01 -0.236 0.68522E+04 43 celadonite-Fe 3.88 -0.90 -4.78 -0.281 0.81567E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14661E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64762E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82466E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68799E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.68 -3.54 -0.354 0.60439E+04 97 kalsilite 7.58 3.06 -4.52 -0.646 0.77236E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.37 -4.49 -0.449 0.76597E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20479E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.79 -1.31 -0.101 0.22338E+04 120 muscovite 2.58 1.73 -0.85 -0.050 0.14594E+04 121 paragonite 4.24 2.77 -1.47 -0.086 0.25083E+04 122 nepheline 8.34 4.10 -4.24 -0.605 0.72333E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40616E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.72 -3.74 -1.248 0.63928E+04 152 rhodonite 7.45 5.02 -2.43 -0.485 0.41419E+04 153 sanidine -1.28 -3.79 -2.52 -0.194 0.43015E+04 155 siderite -2.61 -6.85 -4.24 -1.413 0.72362E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.57 -1.44 -0.043 0.24637E+04 165 stilpnomelane-Mg 27.44 22.72 -4.72 -0.141 0.80625E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83503E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.660 0.78856E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.92 -3.40 -0.208 0.57979E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.57 -3.23 -0.198 0.55143E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.05 -2.81 -0.172 0.47994E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.70 -2.67 -0.163 0.45515E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.13 -1.21 -0.078 0.20708E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.47 -1.05 -0.067 0.17890E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.28 -2.30 -0.177 0.39207E+04 243 an25ab75 2.65 0.34 -2.31 -0.177 0.39369E+04 244 an30ab70 3.28 0.96 -2.32 -0.179 0.39628E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1470000 g New total amount of reactant added: 0.1510000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1510000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3536414E-03 Osmotic coef. = 0.9888 True ionic strength = .4160426E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.56793E-08 -8.2457 0.54295E-08 -8.2652 0.95602E+00 -0.0195 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13187E-03 -3.8798 0.95584E+00 -0.0196 4 SO4-- 0.25475E-04 -4.5939 0.22445E-04 -4.6489 0.88103E+00 -0.0550 5 HCO3- 0.12701E-04 -4.8962 0.12140E-04 -4.9158 0.95588E+00 -0.0196 6 HS- 0.26021E-12 -12.5847 0.24872E-12 -12.6043 0.95584E+00 -0.0196 7 Al+++ 0.12016E-21 -21.9202 0.92367E-22 -22.0345 0.76869E+00 -0.1142 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.29748E-05 -5.5265 0.26204E-05 -5.5816 0.88084E+00 -0.0551 10 Mg++ 0.11902E-07 -7.9244 0.10482E-07 -7.9796 0.88071E+00 -0.0552 11 Fe++ 0.70225E-10 -10.1535 0.61850E-10 -10.2087 0.88074E+00 -0.0552 12 K+ 0.32047E-04 -4.4942 0.30633E-04 -4.5138 0.95589E+00 -0.0196 13 Na+ 0.34924E-03 -3.4569 0.33381E-03 -3.4765 0.95584E+00 -0.0196 14 Mn++ 0.93843E-08 -8.0276 0.82654E-08 -8.0827 0.88077E+00 -0.0551 15 HPO4-- 0.19331E-07 -7.7137 0.17031E-07 -7.7688 0.88103E+00 -0.0550 16 HSiO3- 0.67214E-04 -4.1725 0.64245E-04 -4.1922 0.95584E+00 -0.0196 17 Ca(HSiO3)+ 0.40108E-08 -8.3968 0.38339E-08 -8.4164 0.95590E+00 -0.0196 18 Mg(HSiO3)+ 0.19967E-10 -10.6997 0.19086E-10 -10.7193 0.95590E+00 -0.0196 19 NaHSiO3,aq 0.34686E-06 -6.4598 0.34686E-06 -6.4598 0.10000E+01 0.0000 20 AlO+ 0.44593E-12 -12.3507 0.42626E-12 -12.3703 0.95590E+00 -0.0196 21 AlOH+2 0.13084E-16 -16.8833 0.11524E-16 -16.9384 0.88079E+00 -0.0551 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.66691E-05 -5.1759 0.63742E-05 -5.1956 0.95579E+00 -0.0196 24 CH4,aq 0.13070E-18 -18.8837 0.13068E-18 -18.8838 0.99989E+00 0.0000 29 CO,aq 0.16115E-17 -17.7928 0.16115E-17 -17.7928 0.10000E+01 0.0000 30 CO2,aq 0.14086E-06 -6.8512 0.14085E-06 -6.8513 0.99989E+00 0.0000 31 CO3-2 0.22169E-06 -6.6542 0.19530E-06 -6.7093 0.88097E+00 -0.0550 32 CaCO3,aq 0.64170E-08 -8.1927 0.64170E-08 -8.1927 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.84950E-09 -9.0708 0.81203E-09 -9.0904 0.95590E+00 -0.0196 34 CaCl+ 0.58501E-09 -9.2328 0.55921E-09 -9.2524 0.95590E+00 -0.0196 35 CaCl2,aq 0.17520E-13 -13.7565 0.17520E-13 -13.7565 0.10000E+01 0.0000 36 CaOH+ 0.35983E-07 -7.4439 0.34396E-07 -7.4635 0.95590E+00 -0.0196 37 CaSO4,aq 0.18676E-07 -7.7287 0.18676E-07 -7.7287 0.10000E+01 0.0000 38 HCl,aq 0.13120E-12 -12.8821 0.13120E-12 -12.8821 0.10000E+01 0.0000 43 FeCl+ 0.13506E-13 -13.8695 0.12910E-13 -13.8891 0.95590E+00 -0.0196 46 FeO,aq 0.81543E-10 -10.0886 0.81543E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.38791E-09 -9.4113 0.37080E-09 -9.4309 0.95590E+00 -0.0196 48 HFeO2- 0.16440E-09 -9.7841 0.15714E-09 -9.8037 0.95584E+00 -0.0196 49 FeO+ 0.43355E-13 -13.3630 0.41443E-13 -13.3826 0.95590E+00 -0.0196 50 FeOH+2 0.48787E-19 -19.3117 0.42971E-19 -19.3668 0.88079E+00 -0.0551 51 FeO2- 0.30095E-09 -9.5215 0.28766E-09 -9.5411 0.95584E+00 -0.0196 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45550E-09 -9.3415 0.45545E-09 -9.3416 0.99989E+00 0.0000 54 KCl,aq 0.73216E-10 -10.1354 0.73216E-10 -10.1354 0.10000E+01 0.0000 55 KHSO4,aq 0.10555E-16 -16.9766 0.10555E-16 -16.9766 0.10000E+01 0.0000 56 KOH,aq 0.24095E-08 -8.6181 0.24095E-08 -8.6181 0.10000E+01 0.0000 57 KSO4- 0.11162E-07 -7.9523 0.10669E-07 -7.9719 0.95584E+00 -0.0196 58 MgCO3,aq 0.64342E-11 -11.1915 0.64342E-11 -11.1915 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.34723E-11 -11.4594 0.33191E-11 -11.4790 0.95590E+00 -0.0196 60 MgCl+ 0.21210E-11 -11.6735 0.20274E-11 -11.6931 0.95590E+00 -0.0196 61 MgOH+ 0.79648E-09 -9.0988 0.76135E-09 -9.1184 0.95590E+00 -0.0196 63 MnO,aq 0.29036E-09 -9.5371 0.29036E-09 -9.5371 0.10000E+01 0.0000 64 MnOH+ 0.48157E-08 -8.3173 0.46033E-08 -8.3369 0.95590E+00 -0.0196 65 MnO2-2 0.37104E-15 -15.4306 0.32688E-15 -15.4856 0.88097E+00 -0.0550 66 HMnO2- 0.40679E-12 -12.3906 0.38883E-12 -12.4102 0.95584E+00 -0.0196 69 MnCl+ 0.70216E-11 -11.1536 0.67119E-11 -11.1732 0.95590E+00 -0.0196 70 MnSO4,aq 0.53556E-10 -10.2712 0.53556E-10 -10.2712 0.10000E+01 0.0000 71 NaCl,aq 0.14588E-07 -7.8360 0.14588E-07 -7.8360 0.10000E+01 0.0000 72 NaOH,aq 0.26415E-07 -7.5781 0.26415E-07 -7.5781 0.10000E+01 0.0000 74 OH- 0.11134E-03 -3.9534 0.10641E-03 -3.9730 0.95579E+00 -0.0196 79 HPO3-2 0.27439E-19 -19.5616 0.24173E-19 -19.6167 0.88097E+00 -0.0550 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.17846E-08 -8.7485 0.17059E-08 -8.7681 0.95587E+00 -0.0196 84 PO4-3 0.33244E-11 -11.4783 0.25593E-11 -11.5919 0.76985E+00 -0.1136 87 H2P2O7-2 0.25900E-18 -18.5867 0.22817E-18 -18.6417 0.88097E+00 -0.0550 88 HP2O7-3 0.10916E-16 -16.9619 0.83912E-17 -17.0762 0.76870E+00 -0.1142 89 P2O7-4 0.58075E-18 -18.2360 0.36921E-18 -18.4327 0.63574E+00 -0.1967 90 H2S,aq 0.41741E-14 -14.3794 0.41737E-14 -14.3795 0.99989E+00 0.0000 97 SO3-2 0.15072E-14 -14.8218 0.13284E-14 -14.8767 0.88136E+00 -0.0548 98 HSO3- 0.47246E-15 -15.3256 0.45160E-15 -15.3453 0.95584E+00 -0.0196 99 HSO4- 0.12286E-09 -9.9106 0.11744E-09 -9.9302 0.95592E+00 -0.0196 Charge balance for all species = 0.7201E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5679300E-08 -.2057773E-03 -.2073990E+00 0.0000 2 H2O 0.1000000E+01 0.5550831E+02 0.9999401E+06 0.0000 3 Cl- 0.1379639E-03 0.1379792E-03 0.4891488E+01 4.3854 4 SO4-- 0.2547537E-04 0.2550534E-04 0.2449940E+01 11.8816 5 HCO3- 0.1270064E-04 0.1307047E-04 0.7974767E+00 3.3495 6 HS- 0.2602110E-12 0.5168606E-10 0.1709261E-05 -4.3390 7 Al+++ 0.1201619E-21 0.6684741E-05 0.1803537E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4411372E-03 0.4239759E+02 -3.4276 9 Ca++ 0.2974849E-05 0.3041370E-05 0.1218849E+00 10.9488 10 Mg++ 0.1190159E-07 0.1273006E-07 0.3094751E-03 8.5509 11 Fe++ 0.7022480E-10 0.1203731E-08 0.6722083E-04 6.3218 12 K+ 0.3204696E-04 0.3206060E-04 0.1253560E+01 3.7514 13 Na+ 0.3492375E-03 0.3496254E-03 0.8037346E+01 4.7887 14 Mn++ 0.9384309E-08 0.1455134E-07 0.7993743E-03 8.4477 15 HPO4-- 0.1933110E-07 0.2111904E-07 0.2026865E-02 8.7617 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2487296E-02 -.2057699E-03 -.2281526E-02 0.0000000E+00 2 H2O 0.5550636E+02 0.5550631E+02 0.5067905E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2968919E-04 0.2550442E-04 0.4184776E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4184725E-05 0.5168419E-10 -.4184776E-05 0.0000000E+00 7 Al+++ 0.4923720E-03 0.6684500E-05 0.4856875E-03 0.0000000E+00 8 H4SiO4 0.1572330E-02 0.4411213E-03 0.1131209E-02 0.0000000E+00 9 Ca++ 0.1881426E-03 0.3041260E-05 0.1851013E-03 0.0000000E+00 10 Mg++ 0.1198413E-03 0.1272960E-07 0.1198285E-03 0.0000000E+00 11 Fe++ 0.1076643E-03 0.1203688E-08 0.1076631E-03 0.0000000E+00 12 K+ 0.3205945E-04 0.3205945E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3496128E-03 0.3496128E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2618128E-05 0.1455081E-07 0.2603577E-05 0.0000000E+00 15 HPO4-- 0.8935541E-06 0.2111828E-07 0.8724358E-06 0.0000000E+00 Chg. balance for solid moles: 0.2372E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1510000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2908E-06 -6.536 0.1461E-03 -3.835 0.1064 0.4642E-04 clinochlore 0.2397E-04 -4.620 0.1332E-01 -1.875 9.704 0.5067E-02 daphnite 0.1484E-04 -4.829 0.1059E-01 -1.975 7.712 0.3208E-02 chlorite-Mn 0.5207E-06 -6.283 0.3692E-03 -3.433 0.2689 0.1176E-03 hematite 0.1674E-04 -4.776 0.2673E-02 -2.573 1.947 0.5067E-03 kaolinite 0.1987E-04 -4.702 0.5130E-02 -2.290 3.737 0.1974E-02 lawsonite 0.6241E-04 -4.205 0.1961E-01 -1.708 14.29 0.6324E-02 stilbite 0.1212E-03 -3.916 0.8544E-01 -1.068 62.24 0.3985E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1324E-01 0.1324E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.137277 g Volume = 0.057094 cm3 Porosity: 94.6158% V(tot) - V(min): 0.10033E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1510000 g log = -0.8210 Original solution: 1000.0103000 g Original solution / Rock added: 6622.58 (Water/Rock Ratio), log = 3.8210 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1467E-04 1.0071 0.1507E-04 0.1496E-04 CH4,gas 0.1862E-15 1.0125 0.1924E-15 0.1900E-15 H2,gas 0.5857E-06 1.0005 0.5980E-06 0.5976E-06 H2S,gas 0.1129E-12 0.9960 0.1147E-12 0.1152E-12 S2,gas 0.1354E-32 1.0000 0.1382E-32 0.1382E-32 CO,gas 0.2354E-14 1.0000 0.2401E-14 0.2401E-14 SO3,gas 0.2452E-36 1.0000 0.2502E-36 0.2502E-36 SO2,gas 0.5704E-20 1.0000 0.5820E-20 0.5820E-20 HCl,gas 0.2269E-15 1.0000 0.2315E-15 0.2315E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.36397E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.18 -6.52 -2.174 0.11134E+05 -4.822 3 CH4,gas 4.54 -12.87 -17.41 -4.354 0.29735E+05 -15.716 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.87 -14.64 -7.320 0.24996E+05 -12.940 6 S2,gas -7.34 -41.89 -34.56 -5.317 0.59008E+05 -32.860 7 CO,gas 3.21 -13.10 -16.32 -5.021 0.27863E+05 -14.620 8 SO3,gas 17.12 -21.18 -38.30 -9.575 0.65397E+05 -36.602 9 SO2,gas 0.83 -21.10 -21.93 -5.849 0.37452E+05 -20.235 10 HCl,gas 5.19 -12.15 -17.33 -8.667 0.29598E+05 -15.635 11 acmite 7.71 4.22 -3.49 -0.363 0.59644E+04 15 albite-high 0.69 -2.73 -3.43 -0.264 0.58497E+04 16 albite -0.38 -2.73 -2.35 -0.181 0.40109E+04 19 spessartine 24.46 20.58 -3.87 -0.194 0.66156E+04 20 analcite 3.32 0.69 -2.63 -0.292 0.44857E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -10.23 -4.91 -2.457 0.83901E+04 26 annite 20.12 15.20 -4.93 -0.274 0.84147E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.23 -3.20 -1.066 0.54617E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.23 -3.04 -1.015 0.51975E+04 38 carnegieite-low 9.02 4.12 -4.90 -0.700 0.83682E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.35 -3.99 -0.235 0.68103E+04 43 celadonite-Fe 3.88 -0.88 -4.75 -0.280 0.81148E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14658E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64762E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82466E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68799E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.69 -3.52 -0.352 0.60112E+04 97 kalsilite 7.58 3.09 -4.50 -0.643 0.76817E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.34 -4.46 -0.446 0.76178E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20479E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.77 -1.28 -0.099 0.21919E+04 120 muscovite 2.58 1.75 -0.83 -0.049 0.14175E+04 121 paragonite 4.24 2.79 -1.45 -0.085 0.24756E+04 122 nepheline 8.34 4.12 -4.22 -0.602 0.72006E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40613E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.73 -3.76 -1.252 0.64149E+04 152 rhodonite 7.45 5.02 -2.43 -0.485 0.41416E+04 153 sanidine -1.28 -3.77 -2.49 -0.192 0.42596E+04 155 siderite -2.61 -6.86 -4.25 -1.417 0.72585E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.59 -1.43 -0.043 0.24428E+04 165 stilpnomelane-Mg 27.44 22.73 -4.71 -0.141 0.80415E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83503E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.660 0.78850E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.91 -3.39 -0.207 0.57840E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.57 -3.22 -0.197 0.55035E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.04 -2.80 -0.172 0.47856E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.70 -2.66 -0.163 0.45408E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.14 -1.20 -0.077 0.20570E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.48 -1.04 -0.067 0.17782E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.26 -2.28 -0.175 0.38945E+04 243 an25ab75 2.65 0.35 -2.29 -0.176 0.39124E+04 244 an30ab70 3.28 0.97 -2.31 -0.177 0.39399E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1510000 g New total amount of reactant added: 0.1550000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1550000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3571306E-03 Osmotic coef. = 0.9887 True ionic strength = .4214009E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.55173E-08 -8.2583 0.52738E-08 -8.2779 0.95585E+00 -0.0196 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13185E-03 -3.8799 0.95568E+00 -0.0197 4 SO4-- 0.25476E-04 -4.5939 0.22430E-04 -4.6492 0.88043E+00 -0.0553 5 HCO3- 0.12698E-04 -4.8963 0.12136E-04 -4.9159 0.95572E+00 -0.0197 6 HS- 0.25261E-12 -12.5976 0.24141E-12 -12.6172 0.95568E+00 -0.0197 7 Al+++ 0.11028E-21 -21.9575 0.84645E-22 -22.0724 0.76752E+00 -0.1149 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.28086E-05 -5.5515 0.24722E-05 -5.6069 0.88024E+00 -0.0554 10 Mg++ 0.11236E-07 -7.9494 0.98892E-08 -8.0048 0.88011E+00 -0.0555 11 Fe++ 0.66299E-10 -10.1785 0.58352E-10 -10.2339 0.88014E+00 -0.0554 12 K+ 0.32896E-04 -4.4829 0.31439E-04 -4.5025 0.95573E+00 -0.0197 13 Na+ 0.35424E-03 -3.4507 0.33854E-03 -3.4704 0.95567E+00 -0.0197 14 Mn++ 0.88631E-08 -8.0524 0.78010E-08 -8.1078 0.88017E+00 -0.0554 15 HPO4-- 0.20503E-07 -7.6882 0.18052E-07 -7.7435 0.88044E+00 -0.0553 16 HSiO3- 0.69210E-04 -4.1598 0.66142E-04 -4.1795 0.95568E+00 -0.0197 17 Ca(HSiO3)+ 0.38964E-08 -8.4093 0.37239E-08 -8.4290 0.95573E+00 -0.0197 18 Mg(HSiO3)+ 0.19397E-10 -10.7123 0.18539E-10 -10.7319 0.95573E+00 -0.0197 19 NaHSiO3,aq 0.36216E-06 -6.4411 0.36216E-06 -6.4411 0.10000E+01 0.0000 20 AlO+ 0.43321E-12 -12.3633 0.41403E-12 -12.3830 0.95573E+00 -0.0197 21 AlOH+2 0.12353E-16 -16.9082 0.10873E-16 -16.9637 0.88019E+00 -0.0554 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.68672E-05 -5.1632 0.65625E-05 -5.1829 0.95562E+00 -0.0197 24 CH4,aq 0.12689E-18 -18.8966 0.12688E-18 -18.8966 0.99989E+00 0.0000 29 CO,aq 0.15647E-17 -17.8056 0.15647E-17 -17.8056 0.10000E+01 0.0000 30 CO2,aq 0.13677E-06 -6.8640 0.13676E-06 -6.8640 0.99989E+00 0.0000 31 CO3-2 0.22831E-06 -6.6415 0.20100E-06 -6.6968 0.88038E+00 -0.0553 32 CaCO3,aq 0.62308E-08 -8.2055 0.62308E-08 -8.2055 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.80132E-09 -9.0962 0.76585E-09 -9.1159 0.95573E+00 -0.0197 34 CaCl+ 0.55193E-09 -9.2581 0.52750E-09 -9.2778 0.95573E+00 -0.0197 35 CaCl2,aq 0.16524E-13 -13.7819 0.16524E-13 -13.7819 0.10000E+01 0.0000 36 CaOH+ 0.34957E-07 -7.4565 0.33409E-07 -7.4761 0.95573E+00 -0.0197 37 CaSO4,aq 0.17608E-07 -7.7543 0.17608E-07 -7.7543 0.10000E+01 0.0000 38 HCl,aq 0.12742E-12 -12.8948 0.12742E-12 -12.8948 0.10000E+01 0.0000 43 FeCl+ 0.12742E-13 -13.8948 0.12178E-13 -13.9144 0.95573E+00 -0.0197 46 FeO,aq 0.81542E-10 -10.0886 0.81542E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.37685E-09 -9.4238 0.36017E-09 -9.4435 0.95573E+00 -0.0197 48 HFeO2- 0.16928E-09 -9.7714 0.16178E-09 -9.7911 0.95568E+00 -0.0197 49 FeO+ 0.42119E-13 -13.3755 0.40254E-13 -13.3952 0.95573E+00 -0.0197 50 FeOH+2 0.46060E-19 -19.3367 0.40541E-19 -19.3921 0.88019E+00 -0.0554 51 FeO2- 0.30989E-09 -9.5088 0.29615E-09 -9.5285 0.95568E+00 -0.0197 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45549E-09 -9.3415 0.45544E-09 -9.3416 0.99989E+00 0.0000 54 KCl,aq 0.75129E-10 -10.1242 0.75129E-10 -10.1242 0.10000E+01 0.0000 55 KHSO4,aq 0.10515E-16 -16.9782 0.10515E-16 -16.9782 0.10000E+01 0.0000 56 KOH,aq 0.25459E-08 -8.5942 0.25459E-08 -8.5942 0.10000E+01 0.0000 57 KSO4- 0.11450E-07 -7.9412 0.10943E-07 -7.9609 0.95568E+00 -0.0197 58 MgCO3,aq 0.62474E-11 -11.2043 0.62474E-11 -11.2043 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.32754E-11 -11.4847 0.31304E-11 -11.5044 0.95573E+00 -0.0197 60 MgCl+ 0.20010E-11 -11.6987 0.19125E-11 -11.7184 0.95573E+00 -0.0197 61 MgOH+ 0.77376E-09 -9.1114 0.73951E-09 -9.1311 0.95573E+00 -0.0197 63 MnO,aq 0.29047E-09 -9.5369 0.29047E-09 -9.5369 0.10000E+01 0.0000 64 MnOH+ 0.46801E-08 -8.3297 0.44730E-08 -8.3494 0.95573E+00 -0.0197 65 MnO2-2 0.39370E-15 -15.4048 0.34660E-15 -15.4602 0.88038E+00 -0.0553 66 HMnO2- 0.41904E-12 -12.3777 0.40046E-12 -12.3974 0.95568E+00 -0.0197 69 MnCl+ 0.66271E-11 -11.1787 0.63338E-11 -11.1983 0.95573E+00 -0.0197 70 MnSO4,aq 0.50515E-10 -10.2966 0.50515E-10 -10.2966 0.10000E+01 0.0000 71 NaCl,aq 0.14792E-07 -7.8300 0.14792E-07 -7.8300 0.10000E+01 0.0000 72 NaOH,aq 0.27580E-07 -7.5594 0.27580E-07 -7.5594 0.10000E+01 0.0000 74 OH- 0.11464E-03 -3.9406 0.10956E-03 -3.9604 0.95562E+00 -0.0197 79 HPO3-2 0.29103E-19 -19.5361 0.25622E-19 -19.5914 0.88038E+00 -0.0553 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.18376E-08 -8.7357 0.17562E-08 -8.7554 0.95570E+00 -0.0197 84 PO4-3 0.36332E-11 -11.4397 0.27928E-11 -11.5540 0.76869E+00 -0.1142 87 H2P2O7-2 0.27470E-18 -18.5611 0.24184E-18 -18.6165 0.88038E+00 -0.0553 88 HP2O7-3 0.11930E-16 -16.9234 0.91567E-17 -17.0383 0.76753E+00 -0.1149 89 P2O7-4 0.65422E-18 -18.1843 0.41479E-18 -18.3822 0.63402E+00 -0.1979 90 H2S,aq 0.39353E-14 -14.4050 0.39348E-14 -14.4051 0.99989E+00 0.0000 97 SO3-2 0.15072E-14 -14.8218 0.13275E-14 -14.8770 0.88077E+00 -0.0551 98 HSO3- 0.45868E-15 -15.3385 0.43835E-15 -15.3582 0.95568E+00 -0.0197 99 HSO4- 0.11928E-09 -9.9234 0.11400E-09 -9.9431 0.95576E+00 -0.0197 Charge balance for all species = 0.7202E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5517334E-08 -.2118996E-03 -.2135694E+00 0.0000 2 H2O 0.1000000E+01 0.5550831E+02 0.9999397E+06 0.0000 3 Cl- 0.1379638E-03 0.1379793E-03 0.4891490E+01 4.3980 4 SO4-- 0.2547618E-04 0.2550536E-04 0.2449941E+01 11.9066 5 HCO3- 0.1269835E-04 0.1307048E-04 0.7974770E+00 3.3620 6 HS- 0.2526078E-12 0.5055880E-10 0.1671982E-05 -4.3394 7 Al+++ 0.1102844E-21 0.6882848E-05 0.1856986E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4431490E-03 0.4259092E+02 -3.4276 9 Ca++ 0.2808554E-05 0.2872599E-05 0.1151212E+00 10.9488 10 Mg++ 0.1123628E-07 0.1204096E-07 0.2927226E-03 8.5509 11 Fe++ 0.6629864E-10 0.1202558E-08 0.6715527E-04 6.3218 12 K+ 0.3289585E-04 0.3290992E-04 0.1286768E+01 3.7754 13 Na+ 0.3542423E-03 0.3546468E-03 0.8152778E+01 4.8075 14 Mn++ 0.8863104E-08 0.1389127E-07 0.7631134E-03 8.4479 15 HPO4-- 0.2050348E-07 0.2234474E-07 0.2144499E-02 8.8123 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2553530E-02 -.2118917E-03 -.2341638E-02 0.0000000E+00 2 H2O 0.5550631E+02 0.5550627E+02 0.4218540E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2980005E-04 0.2550442E-04 0.4295629E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4295578E-05 0.5055694E-10 -.4295629E-05 0.0000000E+00 7 Al+++ 0.5054149E-03 0.6882594E-05 0.4985324E-03 0.0000000E+00 8 H4SiO4 0.1613981E-02 0.4431327E-03 0.1170849E-02 0.0000000E+00 9 Ca++ 0.1927432E-03 0.2872494E-05 0.1898707E-03 0.0000000E+00 10 Mg++ 0.1230159E-03 0.1204052E-07 0.1230038E-03 0.0000000E+00 11 Fe++ 0.1105163E-03 0.1202513E-08 0.1105151E-03 0.0000000E+00 12 K+ 0.3290870E-04 0.3290870E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3546338E-03 0.3546338E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2687482E-05 0.1389076E-07 0.2673592E-05 0.0000000E+00 15 HPO4-- 0.9172244E-06 0.2234392E-07 0.8948805E-06 0.0000000E+00 Chg. balance for solid moles: -.6675E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1550000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2983E-06 -6.525 0.1498E-03 -3.824 0.1058 0.4761E-04 clinochlore 0.2460E-04 -4.609 0.1367E-01 -1.864 9.653 0.5201E-02 daphnite 0.1523E-04 -4.817 0.1087E-01 -1.964 7.671 0.3293E-02 chlorite-Mn 0.5347E-06 -6.272 0.3791E-03 -3.421 0.2676 0.1208E-03 hematite 0.1718E-04 -4.765 0.2744E-02 -2.562 1.937 0.5201E-03 kaolinite 0.2052E-04 -4.688 0.5298E-02 -2.276 3.740 0.2038E-02 lawsonite 0.6199E-04 -4.208 0.1948E-01 -1.710 13.75 0.6282E-02 stilbite 0.1264E-03 -3.898 0.8907E-01 -1.050 62.88 0.4154E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1325E-01 0.1325E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.141661 g Volume = 0.059046 cm3 Porosity: 94.4401% V(tot) - V(min): 0.10030E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1550000 g log = -0.8097 Original solution: 1000.0103000 g Original solution / Rock added: 6451.68 (Water/Rock Ratio), log = 3.8097 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1424E-04 1.0071 0.1463E-04 0.1453E-04 CH4,gas 0.1808E-15 1.0125 0.1868E-15 0.1844E-15 H2,gas 0.5857E-06 1.0005 0.5979E-06 0.5976E-06 H2S,gas 0.1064E-12 0.9960 0.1082E-12 0.1086E-12 S2,gas 0.1204E-32 1.0000 0.1228E-32 0.1228E-32 CO,gas 0.2285E-14 1.0000 0.2332E-14 0.2332E-14 SO3,gas 0.2312E-36 1.0000 0.2359E-36 0.2359E-36 SO2,gas 0.5378E-20 1.0000 0.5487E-20 0.5487E-20 HCl,gas 0.2204E-15 1.0000 0.2248E-15 0.2248E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.19 -6.53 -2.178 0.11156E+05 -4.835 3 CH4,gas 4.54 -12.88 -17.43 -4.357 0.29757E+05 -15.729 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.90 -14.66 -7.332 0.25040E+05 -12.966 6 S2,gas -7.34 -41.95 -34.61 -5.325 0.59095E+05 -32.911 7 CO,gas 3.21 -13.12 -16.33 -5.025 0.27885E+05 -14.632 8 SO3,gas 17.12 -21.20 -38.33 -9.582 0.65441E+05 -36.627 9 SO2,gas 0.83 -21.13 -21.96 -5.856 0.37495E+05 -20.261 10 HCl,gas 5.19 -12.16 -17.35 -8.674 0.29620E+05 -15.648 11 acmite 7.71 4.24 -3.47 -0.361 0.59324E+04 15 albite-high 0.69 -2.71 -3.41 -0.262 0.58177E+04 16 albite -0.38 -2.71 -2.33 -0.179 0.39789E+04 19 spessartine 24.46 20.58 -3.87 -0.194 0.66148E+04 20 analcite 3.32 0.71 -2.61 -0.290 0.44537E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -10.26 -4.94 -2.470 0.84337E+04 26 annite 20.12 15.22 -4.90 -0.272 0.83738E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.24 -3.21 -1.070 0.54835E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.24 -3.06 -1.019 0.52193E+04 38 carnegieite-low 9.02 4.14 -4.88 -0.697 0.83362E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.38 -3.96 -0.233 0.67694E+04 43 celadonite-Fe 3.88 -0.85 -4.73 -0.278 0.80740E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14655E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64762E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82466E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68799E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.71 -3.50 -0.350 0.59792E+04 97 kalsilite 7.58 3.11 -4.47 -0.639 0.76408E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.32 -4.44 -0.444 0.75769E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20479E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.75 -1.26 -0.097 0.21510E+04 120 muscovite 2.58 1.78 -0.81 -0.047 0.13766E+04 121 paragonite 4.24 2.81 -1.43 -0.084 0.24436E+04 122 nepheline 8.34 4.14 -4.20 -0.600 0.71686E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40610E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.75 -3.77 -1.257 0.64364E+04 152 rhodonite 7.45 5.02 -2.43 -0.485 0.41413E+04 153 sanidine -1.28 -3.75 -2.47 -0.190 0.42188E+04 155 siderite -2.61 -6.87 -4.26 -1.421 0.72804E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.60 -1.42 -0.042 0.24224E+04 165 stilpnomelane-Mg 27.44 22.74 -4.70 -0.140 0.80211E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83504E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.660 0.78844E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.90 -3.38 -0.207 0.57706E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.56 -3.22 -0.197 0.54929E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.03 -2.79 -0.171 0.47721E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.69 -2.65 -0.162 0.45302E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.14 -1.20 -0.077 0.20435E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.48 -1.04 -0.066 0.17676E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.25 -2.27 -0.174 0.38689E+04 243 an25ab75 2.65 0.37 -2.28 -0.175 0.38884E+04 244 an30ab70 3.28 0.98 -2.29 -0.176 0.39175E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1550000 g New total amount of reactant added: 0.1590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1590000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3606506E-03 Osmotic coef. = 0.9887 True ionic strength = .4267981E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.53637E-08 -8.2705 0.51261E-08 -8.2902 0.95569E+00 -0.0197 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13183E-03 -3.8800 0.95551E+00 -0.0198 4 SO4-- 0.25477E-04 -4.5939 0.22416E-04 -4.6495 0.87984E+00 -0.0556 5 HCO3- 0.12696E-04 -4.8963 0.12132E-04 -4.9161 0.95556E+00 -0.0197 6 HS- 0.24540E-12 -12.6101 0.23448E-12 -12.6299 0.95552E+00 -0.0198 7 Al+++ 0.10143E-21 -21.9938 0.77732E-22 -22.1094 0.76634E+00 -0.1156 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.26553E-05 -5.5759 0.23357E-05 -5.6316 0.87964E+00 -0.0557 10 Mg++ 0.10623E-07 -7.9738 0.93431E-08 -8.0295 0.87952E+00 -0.0558 11 Fe++ 0.62680E-10 -10.2029 0.55130E-10 -10.2586 0.87955E+00 -0.0557 12 K+ 0.33745E-04 -4.4718 0.32245E-04 -4.4915 0.95556E+00 -0.0197 13 Na+ 0.35925E-03 -3.4446 0.34326E-03 -3.4644 0.95551E+00 -0.0198 14 Mn++ 0.83823E-08 -8.0766 0.73728E-08 -8.1324 0.87957E+00 -0.0557 15 HPO4-- 0.21717E-07 -7.6632 0.19107E-07 -7.7188 0.87984E+00 -0.0556 16 HSiO3- 0.71216E-04 -4.1474 0.68048E-04 -4.1672 0.95551E+00 -0.0198 17 Ca(HSiO3)+ 0.37879E-08 -8.4216 0.36196E-08 -8.4413 0.95557E+00 -0.0197 18 Mg(HSiO3)+ 0.18857E-10 -10.7245 0.18019E-10 -10.7443 0.95557E+00 -0.0197 19 NaHSiO3,aq 0.37779E-06 -6.4227 0.37779E-06 -6.4227 0.10000E+01 0.0000 20 AlO+ 0.42115E-12 -12.3756 0.40244E-12 -12.3953 0.95557E+00 -0.0197 21 AlOH+2 0.11678E-16 -16.9326 0.10272E-16 -16.9883 0.87959E+00 -0.0557 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.70663E-05 -5.1508 0.67515E-05 -5.1706 0.95546E+00 -0.0198 24 CH4,aq 0.12329E-18 -18.9091 0.12327E-18 -18.9091 0.99989E+00 0.0000 29 CO,aq 0.15203E-17 -17.8181 0.15203E-17 -17.8181 0.10000E+01 0.0000 30 CO2,aq 0.13289E-06 -6.8765 0.13288E-06 -6.8765 0.99989E+00 0.0000 31 CO3-2 0.23496E-06 -6.6290 0.20672E-06 -6.6846 0.87978E+00 -0.0556 32 CaCO3,aq 0.60541E-08 -8.2180 0.60541E-08 -8.2180 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.75692E-09 -9.1209 0.72329E-09 -9.1407 0.95557E+00 -0.0197 34 CaCl+ 0.52145E-09 -9.2828 0.49828E-09 -9.3025 0.95557E+00 -0.0197 35 CaCl2,aq 0.15606E-13 -13.8067 0.15606E-13 -13.8067 0.10000E+01 0.0000 36 CaOH+ 0.33983E-07 -7.4687 0.32474E-07 -7.4885 0.95557E+00 -0.0197 37 CaSO4,aq 0.16625E-07 -7.7792 0.16625E-07 -7.7792 0.10000E+01 0.0000 38 HCl,aq 0.12383E-12 -12.9072 0.12383E-12 -12.9072 0.10000E+01 0.0000 43 FeCl+ 0.12038E-13 -13.9194 0.11503E-13 -13.9392 0.95557E+00 -0.0197 46 FeO,aq 0.81541E-10 -10.0886 0.81541E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.36635E-09 -9.4361 0.35008E-09 -9.4558 0.95557E+00 -0.0197 48 HFeO2- 0.17419E-09 -9.7590 0.16644E-09 -9.7787 0.95551E+00 -0.0198 49 FeO+ 0.40946E-13 -13.3878 0.39127E-13 -13.4075 0.95557E+00 -0.0197 50 FeOH+2 0.43546E-19 -19.3611 0.38303E-19 -19.4168 0.87959E+00 -0.0557 51 FeO2- 0.31887E-09 -9.4964 0.30469E-09 -9.5161 0.95551E+00 -0.0198 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45549E-09 -9.3415 0.45544E-09 -9.3416 0.99989E+00 0.0000 54 KCl,aq 0.77042E-10 -10.1133 0.77042E-10 -10.1133 0.10000E+01 0.0000 55 KHSO4,aq 0.10476E-16 -16.9798 0.10476E-16 -16.9798 0.10000E+01 0.0000 56 KOH,aq 0.26864E-08 -8.5708 0.26864E-08 -8.5708 0.10000E+01 0.0000 57 KSO4- 0.11738E-07 -7.9304 0.11216E-07 -7.9502 0.95551E+00 -0.0198 58 MgCO3,aq 0.60702E-11 -11.2168 0.60702E-11 -11.2168 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.30939E-11 -11.5095 0.29564E-11 -11.5292 0.95557E+00 -0.0197 60 MgCl+ 0.18905E-11 -11.7234 0.18065E-11 -11.7432 0.95557E+00 -0.0197 61 MgOH+ 0.75222E-09 -9.1237 0.71880E-09 -9.1434 0.95557E+00 -0.0197 63 MnO,aq 0.29057E-09 -9.5367 0.29057E-09 -9.5367 0.10000E+01 0.0000 64 MnOH+ 0.45514E-08 -8.3419 0.43492E-08 -8.3616 0.95557E+00 -0.0197 65 MnO2-2 0.41713E-15 -15.3797 0.36699E-15 -15.4354 0.87978E+00 -0.0556 66 HMnO2- 0.43133E-12 -12.3652 0.41214E-12 -12.3850 0.95551E+00 -0.0198 69 MnCl+ 0.62633E-11 -11.2032 0.59850E-11 -11.2229 0.95557E+00 -0.0197 70 MnSO4,aq 0.47711E-10 -10.3214 0.47711E-10 -10.3214 0.10000E+01 0.0000 71 NaCl,aq 0.14996E-07 -7.8240 0.14996E-07 -7.8240 0.10000E+01 0.0000 72 NaOH,aq 0.28771E-07 -7.5410 0.28771E-07 -7.5410 0.10000E+01 0.0000 74 OH- 0.11797E-03 -3.9282 0.11271E-03 -3.9480 0.95546E+00 -0.0198 79 HPO3-2 0.30824E-19 -19.5111 0.27119E-19 -19.5667 0.87978E+00 -0.0556 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.18909E-08 -8.7233 0.18068E-08 -8.7431 0.95554E+00 -0.0198 84 PO4-3 0.39623E-11 -11.4021 0.30412E-11 -11.5170 0.76753E+00 -0.1149 87 H2P2O7-2 0.29096E-18 -18.5362 0.25598E-18 -18.5918 0.87978E+00 -0.0556 88 HP2O7-3 0.13011E-16 -16.8857 0.99711E-17 -17.0013 0.76636E+00 -0.1156 89 P2O7-4 0.73491E-18 -18.1338 0.46469E-18 -18.3328 0.63231E+00 -0.1991 90 H2S,aq 0.37153E-14 -14.4300 0.37149E-14 -14.4301 0.99989E+00 0.0000 97 SO3-2 0.15072E-14 -14.8218 0.13266E-14 -14.8772 0.88018E+00 -0.0554 98 HSO3- 0.44562E-15 -15.3510 0.42579E-15 -15.3708 0.95551E+00 -0.0198 99 HSO4- 0.11588E-09 -9.9360 0.11074E-09 -9.9557 0.95560E+00 -0.0197 Charge balance for all species = 0.7203E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5363735E-08 -.2180511E-03 -.2197693E+00 0.0000 2 H2O 0.1000000E+01 0.5550831E+02 0.9999394E+06 0.0000 3 Cl- 0.1379638E-03 0.1379794E-03 0.4891492E+01 4.4102 4 SO4-- 0.2547690E-04 0.2550538E-04 0.2449942E+01 11.9310 5 HCO3- 0.1269581E-04 0.1307049E-04 0.7974774E+00 3.3741 6 HS- 0.2453993E-12 0.4942686E-10 0.1634548E-05 -4.3397 7 Al+++ 0.1014315E-21 0.7081899E-05 0.1910689E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4451706E-03 0.4278520E+02 -3.4276 9 Ca++ 0.2655265E-05 0.2716994E-05 0.1088852E+00 10.9488 10 Mg++ 0.1062301E-07 0.1140514E-07 0.2772654E-03 8.5509 11 Fe++ 0.6267964E-10 0.1202329E-08 0.6714250E-04 6.3218 12 K+ 0.3374473E-04 0.3375923E-04 0.1319975E+01 3.7987 13 Na+ 0.3592467E-03 0.3596683E-03 0.8268210E+01 4.8258 14 Mn++ 0.8382259E-08 0.1327865E-07 0.7294591E-03 8.4481 15 HPO4-- 0.2171658E-07 0.2361143E-07 0.2266067E-02 8.8616 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2619764E-02 -.2180429E-03 -.2401721E-02 0.0000000E+00 2 H2O 0.5550626E+02 0.5550622E+02 0.3368694E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2991090E-04 0.2550442E-04 0.4406481E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4406432E-05 0.4942500E-10 -.4406481E-05 0.0000000E+00 7 Al+++ 0.5184579E-03 0.7081633E-05 0.5113763E-03 0.0000000E+00 8 H4SiO4 0.1655632E-02 0.4451538E-03 0.1210479E-02 0.0000000E+00 9 Ca++ 0.1973437E-03 0.2716892E-05 0.1946268E-03 0.0000000E+00 10 Mg++ 0.1261905E-03 0.1140471E-07 0.1261791E-03 0.0000000E+00 11 Fe++ 0.1133684E-03 0.1202284E-08 0.1133672E-03 0.0000000E+00 12 K+ 0.3375796E-04 0.3375796E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3596547E-03 0.3596547E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2756837E-05 0.1327815E-07 0.2743559E-05 0.0000000E+00 15 HPO4-- 0.9408947E-06 0.2361055E-07 0.9172841E-06 0.0000000E+00 Chg. balance for solid moles: 0.1525E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3058E-06 -6.515 0.1536E-03 -3.814 0.1052 0.4881E-04 clinochlore 0.2524E-04 -4.598 0.1403E-01 -1.853 9.605 0.5335E-02 daphnite 0.1562E-04 -4.806 0.1115E-01 -1.953 7.633 0.3378E-02 chlorite-Mn 0.5487E-06 -6.261 0.3890E-03 -3.410 0.2664 0.1240E-03 hematite 0.1763E-04 -4.754 0.2815E-02 -2.551 1.927 0.5335E-03 kaolinite 0.2118E-04 -4.674 0.5468E-02 -2.262 3.744 0.2104E-02 lawsonite 0.6156E-04 -4.211 0.1934E-01 -1.713 13.25 0.6238E-02 stilbite 0.1315E-03 -3.881 0.9270E-01 -1.033 63.47 0.4324E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1325E-01 0.1325E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.146042 g Volume = 0.060998 cm3 Porosity: 94.2650% V(tot) - V(min): 0.10026E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1590000 g log = -0.7986 Original solution: 1000.0103000 g Original solution / Rock added: 6289.37 (Water/Rock Ratio), log = 3.7986 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1384E-04 1.0071 0.1422E-04 0.1412E-04 CH4,gas 0.1756E-15 1.0125 0.1814E-15 0.1792E-15 H2,gas 0.5857E-06 1.0005 0.5979E-06 0.5976E-06 H2S,gas 0.1005E-12 0.9960 0.1021E-12 0.1025E-12 S2,gas 0.1073E-32 1.0000 0.1095E-32 0.1095E-32 CO,gas 0.2220E-14 1.0000 0.2265E-14 0.2265E-14 SO3,gas 0.2183E-36 1.0000 0.2227E-36 0.2227E-36 SO2,gas 0.5078E-20 1.0000 0.5181E-20 0.5181E-20 HCl,gas 0.2141E-15 1.0000 0.2185E-15 0.2185E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.21 -6.55 -2.182 0.11177E+05 -4.847 3 CH4,gas 4.54 -12.90 -17.44 -4.360 0.29779E+05 -15.741 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.92 -14.69 -7.345 0.25083E+05 -12.991 6 S2,gas -7.34 -42.00 -34.66 -5.332 0.59180E+05 -32.961 7 CO,gas 3.21 -13.13 -16.34 -5.029 0.27907E+05 -14.645 8 SO3,gas 17.12 -21.23 -38.35 -9.588 0.65484E+05 -36.652 9 SO2,gas 0.83 -21.15 -21.98 -5.863 0.37538E+05 -20.286 10 HCl,gas 5.19 -12.17 -17.36 -8.680 0.29641E+05 -15.661 11 acmite 7.71 4.25 -3.46 -0.359 0.59011E+04 15 albite-high 0.69 -2.70 -3.39 -0.261 0.57864E+04 16 albite -0.38 -2.70 -2.31 -0.178 0.39475E+04 19 spessartine 24.46 20.58 -3.87 -0.194 0.66140E+04 20 analcite 3.32 0.73 -2.59 -0.288 0.44224E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -10.28 -4.96 -2.482 0.84763E+04 26 annite 20.12 15.24 -4.88 -0.271 0.83340E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.26 -3.22 -1.075 0.55049E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.26 -3.07 -1.023 0.52406E+04 38 carnegieite-low 9.02 4.16 -4.86 -0.695 0.83049E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.40 -3.94 -0.232 0.67296E+04 43 celadonite-Fe 3.88 -0.83 -4.71 -0.277 0.80342E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14653E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64762E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82466E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68799E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.73 -3.48 -0.348 0.59479E+04 97 kalsilite 7.58 3.13 -4.45 -0.636 0.76010E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.30 -4.41 -0.441 0.75371E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20479E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.72 -1.24 -0.095 0.21112E+04 120 muscovite 2.58 1.80 -0.78 -0.046 0.13368E+04 121 paragonite 4.24 2.83 -1.41 -0.083 0.24122E+04 122 nepheline 8.34 4.16 -4.18 -0.597 0.71372E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40608E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.76 -3.78 -1.261 0.64575E+04 152 rhodonite 7.45 5.02 -2.43 -0.485 0.41410E+04 153 sanidine -1.28 -3.72 -2.45 -0.188 0.41790E+04 155 siderite -2.61 -6.88 -4.28 -1.425 0.73017E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.61 -1.41 -0.042 0.24026E+04 165 stilpnomelane-Mg 27.44 22.76 -4.69 -0.140 0.80012E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83504E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.660 0.78839E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.89 -3.37 -0.206 0.57574E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.55 -3.21 -0.197 0.54826E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.02 -2.79 -0.171 0.47590E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.68 -2.65 -0.162 0.45198E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.15 -1.19 -0.076 0.20304E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.49 -1.03 -0.066 0.17573E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.23 -2.25 -0.173 0.38439E+04 243 an25ab75 2.65 0.38 -2.26 -0.174 0.38649E+04 244 an30ab70 3.28 1.00 -2.28 -0.175 0.38956E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1590000 g New total amount of reactant added: 0.1630000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1630000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3641985E-03 Osmotic coef. = 0.9886 True ionic strength = .4322307E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.52179E-08 -8.2825 0.49859E-08 -8.3023 0.95553E+00 -0.0198 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13180E-03 -3.8801 0.95535E+00 -0.0198 4 SO4-- 0.25478E-04 -4.5938 0.22401E-04 -4.6497 0.87924E+00 -0.0559 5 HCO3- 0.12693E-04 -4.8964 0.12127E-04 -4.9163 0.95539E+00 -0.0198 6 HS- 0.23856E-12 -12.6224 0.22791E-12 -12.6422 0.95535E+00 -0.0198 7 Al+++ 0.93479E-22 -22.0293 0.71528E-22 -22.1455 0.76518E+00 -0.1162 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.25137E-05 -5.5997 0.22097E-05 -5.6557 0.87904E+00 -0.0560 10 Mg++ 0.10057E-07 -7.9975 0.88391E-08 -8.0536 0.87892E+00 -0.0561 11 Fe++ 0.59338E-10 -10.2267 0.52155E-10 -10.2827 0.87895E+00 -0.0560 12 K+ 0.34594E-04 -4.4610 0.33051E-04 -4.4808 0.95540E+00 -0.0198 13 Na+ 0.36425E-03 -3.4386 0.34799E-03 -3.4584 0.95535E+00 -0.0198 14 Mn++ 0.79380E-08 -8.1003 0.69772E-08 -8.1563 0.87897E+00 -0.0560 15 HPO4-- 0.22970E-07 -7.6388 0.20197E-07 -7.6947 0.87925E+00 -0.0559 16 HSiO3- 0.73231E-04 -4.1353 0.69961E-04 -4.1551 0.95535E+00 -0.0198 17 Ca(HSiO3)+ 0.36850E-08 -8.4336 0.35206E-08 -8.4534 0.95541E+00 -0.0198 18 Mg(HSiO3)+ 0.18345E-10 -10.7365 0.17527E-10 -10.7563 0.95541E+00 -0.0198 19 NaHSiO3,aq 0.39375E-06 -6.4048 0.39375E-06 -6.4048 0.10000E+01 0.0000 20 AlO+ 0.40971E-12 -12.3875 0.39144E-12 -12.4073 0.95541E+00 -0.0198 21 AlOH+2 0.11056E-16 -16.9564 0.97181E-17 -17.0124 0.87900E+00 -0.0560 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.72662E-05 -5.1387 0.69413E-05 -5.1586 0.95530E+00 -0.0199 24 CH4,aq 0.11986E-18 -18.9213 0.11985E-18 -18.9214 0.99989E+00 0.0000 29 CO,aq 0.14781E-17 -17.8303 0.14781E-17 -17.8303 0.10000E+01 0.0000 30 CO2,aq 0.12921E-06 -6.8887 0.12920E-06 -6.8888 0.99989E+00 0.0000 31 CO3-2 0.24164E-06 -6.6168 0.21245E-06 -6.6728 0.87918E+00 -0.0559 32 CaCO3,aq 0.58862E-08 -8.2302 0.58862E-08 -8.2302 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.71593E-09 -9.1451 0.68401E-09 -9.1649 0.95541E+00 -0.0198 34 CaCl+ 0.49332E-09 -9.3069 0.47133E-09 -9.3267 0.95541E+00 -0.0198 35 CaCl2,aq 0.14759E-13 -13.8309 0.14759E-13 -13.8309 0.10000E+01 0.0000 36 CaOH+ 0.33060E-07 -7.4807 0.31586E-07 -7.5005 0.95541E+00 -0.0198 37 CaSO4,aq 0.15718E-07 -7.8036 0.15718E-07 -7.8036 0.10000E+01 0.0000 38 HCl,aq 0.12042E-12 -12.9193 0.12042E-12 -12.9193 0.10000E+01 0.0000 43 FeCl+ 0.11389E-13 -13.9435 0.10881E-13 -13.9633 0.95541E+00 -0.0198 46 FeO,aq 0.81541E-10 -10.0886 0.81541E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.35639E-09 -9.4481 0.34050E-09 -9.4679 0.95541E+00 -0.0198 48 HFeO2- 0.17911E-09 -9.7469 0.17112E-09 -9.7667 0.95535E+00 -0.0198 49 FeO+ 0.39833E-13 -13.3998 0.38057E-13 -13.4196 0.95541E+00 -0.0198 50 FeOH+2 0.41225E-19 -19.3848 0.36236E-19 -19.4409 0.87900E+00 -0.0560 51 FeO2- 0.32789E-09 -9.4843 0.31325E-09 -9.5041 0.95535E+00 -0.0198 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45548E-09 -9.3415 0.45543E-09 -9.3416 0.99989E+00 0.0000 54 KCl,aq 0.78953E-10 -10.1026 0.78953E-10 -10.1026 0.10000E+01 0.0000 55 KHSO4,aq 0.10437E-16 -16.9814 0.10437E-16 -16.9814 0.10000E+01 0.0000 56 KOH,aq 0.28309E-08 -8.5481 0.28309E-08 -8.5481 0.10000E+01 0.0000 57 KSO4- 0.12026E-07 -7.9199 0.11489E-07 -7.9397 0.95535E+00 -0.0198 58 MgCO3,aq 0.59019E-11 -11.2290 0.59019E-11 -11.2290 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.29263E-11 -11.5337 0.27958E-11 -11.5535 0.95541E+00 -0.0198 60 MgCl+ 0.17886E-11 -11.7475 0.17088E-11 -11.7673 0.95541E+00 -0.0198 61 MgOH+ 0.73177E-09 -9.1356 0.69914E-09 -9.1554 0.95541E+00 -0.0198 63 MnO,aq 0.29066E-09 -9.5366 0.29066E-09 -9.5366 0.10000E+01 0.0000 64 MnOH+ 0.44291E-08 -8.3537 0.42316E-08 -8.3735 0.95541E+00 -0.0198 65 MnO2-2 0.44136E-15 -15.3552 0.38803E-15 -15.4111 0.87918E+00 -0.0559 66 HMnO2- 0.44367E-12 -12.3529 0.42386E-12 -12.3728 0.95535E+00 -0.0198 69 MnCl+ 0.59273E-11 -11.2271 0.56630E-11 -11.2470 0.95541E+00 -0.0198 70 MnSO4,aq 0.45122E-10 -10.3456 0.45122E-10 -10.3456 0.10000E+01 0.0000 71 NaCl,aq 0.15200E-07 -7.8182 0.15200E-07 -7.8182 0.10000E+01 0.0000 72 NaOH,aq 0.29987E-07 -7.5231 0.29987E-07 -7.5231 0.10000E+01 0.0000 74 OH- 0.12130E-03 -3.9161 0.11588E-03 -3.9360 0.95530E+00 -0.0199 79 HPO3-2 0.32603E-19 -19.4867 0.28664E-19 -19.5427 0.87918E+00 -0.0559 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.19444E-08 -8.7112 0.18576E-08 -8.7310 0.95538E+00 -0.0198 84 PO4-3 0.43125E-11 -11.3653 0.33050E-11 -11.4808 0.76637E+00 -0.1156 87 H2P2O7-2 0.30776E-18 -18.5118 0.27057E-18 -18.5677 0.87918E+00 -0.0559 88 HP2O7-3 0.14161E-16 -16.8489 0.10836E-16 -16.9651 0.76519E+00 -0.1162 89 P2O7-4 0.82334E-18 -18.0844 0.51920E-18 -18.2847 0.63060E+00 -0.2002 90 H2S,aq 0.35124E-14 -14.4544 0.35120E-14 -14.4544 0.99989E+00 0.0000 97 SO3-2 0.15072E-14 -14.8218 0.13258E-14 -14.8775 0.87959E+00 -0.0557 98 HSO3- 0.43322E-15 -15.3633 0.41387E-15 -15.3831 0.95535E+00 -0.0198 99 HSO4- 0.11266E-09 -9.9482 0.10764E-09 -9.9680 0.95544E+00 -0.0198 Charge balance for all species = 0.7205E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5217941E-08 -.2242291E-03 -.2259959E+00 0.0000 2 H2O 0.1000000E+01 0.5550831E+02 0.9999391E+06 0.0000 3 Cl- 0.1379637E-03 0.1379795E-03 0.4891494E+01 4.4222 4 SO4-- 0.2547755E-04 0.2550540E-04 0.2449943E+01 11.9548 5 HCO3- 0.1269304E-04 0.1307050E-04 0.7974777E+00 3.3860 6 HS- 0.2385588E-12 0.4829068E-10 0.1596974E-05 -4.3400 7 Al+++ 0.9347870E-22 0.7281803E-05 0.1964622E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4472011E-03 0.4298034E+02 -3.4276 9 Ca++ 0.2513741E-05 0.2573300E-05 0.1031265E+00 10.9488 10 Mg++ 0.1005681E-07 0.1081755E-07 0.2629804E-03 8.5509 11 Fe++ 0.5933846E-10 0.1202972E-08 0.6717837E-04 6.3218 12 K+ 0.3459361E-04 0.3460855E-04 0.1353182E+01 3.8214 13 Na+ 0.3642508E-03 0.3646897E-03 0.8383642E+01 4.8438 14 Mn++ 0.7937978E-08 0.1270923E-07 0.6981776E-03 8.4482 15 HPO4-- 0.2297036E-07 0.2491905E-07 0.2391562E-02 8.9098 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2685998E-02 -.2242205E-03 -.2461778E-02 0.0000000E+00 2 H2O 0.5550621E+02 0.5550618E+02 0.2518416E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3002176E-04 0.2550442E-04 0.4517334E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4517286E-05 0.4828882E-10 -.4517334E-05 0.0000000E+00 7 Al+++ 0.5315009E-03 0.7281523E-05 0.5242194E-03 0.0000000E+00 8 H4SiO4 0.1697284E-02 0.4471839E-03 0.1250100E-02 0.0000000E+00 9 Ca++ 0.2019443E-03 0.2573201E-05 0.1993711E-03 0.0000000E+00 10 Mg++ 0.1293651E-03 0.1081713E-07 0.1293543E-03 0.0000000E+00 11 Fe++ 0.1162204E-03 0.1202926E-08 0.1162192E-03 0.0000000E+00 12 K+ 0.3460722E-04 0.3460722E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3646757E-03 0.3646757E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2826191E-05 0.1270874E-07 0.2813482E-05 0.0000000E+00 15 HPO4-- 0.9645650E-06 0.2491809E-07 0.9396469E-06 0.0000000E+00 Chg. balance for solid moles: -.3134E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1630000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3132E-06 -6.504 0.1573E-03 -3.803 0.1046 0.5000E-04 clinochlore 0.2587E-04 -4.587 0.1438E-01 -1.842 9.560 0.5470E-02 daphnite 0.1602E-04 -4.795 0.1143E-01 -1.942 7.597 0.3463E-02 chlorite-Mn 0.5627E-06 -6.250 0.3989E-03 -3.399 0.2652 0.1271E-03 hematite 0.1807E-04 -4.743 0.2886E-02 -2.540 1.918 0.5469E-03 kaolinite 0.2185E-04 -4.660 0.5642E-02 -2.249 3.751 0.2171E-02 lawsonite 0.6112E-04 -4.214 0.1921E-01 -1.717 12.77 0.6193E-02 stilbite 0.1367E-03 -3.864 0.9633E-01 -1.016 64.04 0.4493E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1326E-01 0.1326E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.150423 g Volume = 0.062949 cm3 Porosity: 94.0904% V(tot) - V(min): 0.10023E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1630000 g log = -0.7878 Original solution: 1000.0103000 g Original solution / Rock added: 6135.03 (Water/Rock Ratio), log = 3.7878 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1345E-04 1.0071 0.1382E-04 0.1373E-04 CH4,gas 0.1708E-15 1.0125 0.1764E-15 0.1742E-15 H2,gas 0.5857E-06 1.0005 0.5979E-06 0.5976E-06 H2S,gas 0.9500E-13 0.9960 0.9654E-13 0.9693E-13 S2,gas 0.9591E-33 1.0000 0.9786E-33 0.9786E-33 CO,gas 0.2159E-14 1.0000 0.2203E-14 0.2203E-14 SO3,gas 0.2064E-36 1.0000 0.2106E-36 0.2106E-36 SO2,gas 0.4800E-20 1.0000 0.4898E-20 0.4898E-20 HCl,gas 0.2083E-15 1.0000 0.2125E-15 0.2125E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.18578E-10 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.22 -6.56 -2.186 0.11198E+05 -4.859 3 CH4,gas 4.54 -12.91 -17.45 -4.363 0.29800E+05 -15.753 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.94 -14.71 -7.357 0.25124E+05 -13.015 6 S2,gas -7.34 -42.04 -34.71 -5.340 0.59264E+05 -33.009 7 CO,gas 3.21 -13.14 -16.36 -5.033 0.27927E+05 -14.657 8 SO3,gas 17.12 -21.25 -38.38 -9.594 0.65525E+05 -36.677 9 SO2,gas 0.83 -21.18 -22.01 -5.869 0.37580E+05 -20.310 10 HCl,gas 5.19 -12.18 -17.37 -8.686 0.29662E+05 -15.673 11 acmite 7.71 4.27 -3.44 -0.357 0.58704E+04 15 albite-high 0.69 -2.68 -3.37 -0.259 0.57557E+04 16 albite -0.38 -2.68 -2.29 -0.176 0.39169E+04 19 spessartine 24.46 20.58 -3.87 -0.194 0.66133E+04 20 analcite 3.32 0.75 -2.57 -0.286 0.43917E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 24 anhydrite -5.32 -10.31 -4.99 -2.494 0.85179E+04 26 annite 20.12 15.27 -4.86 -0.270 0.82952E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.27 -3.24 -1.079 0.55257E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.27 -3.08 -1.027 0.52615E+04 38 carnegieite-low 9.02 4.18 -4.85 -0.692 0.82742E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.42 -3.92 -0.231 0.66907E+04 43 celadonite-Fe 3.88 -0.81 -4.68 -0.275 0.79953E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14650E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64762E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82466E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68800E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.75 -3.47 -0.347 0.59172E+04 97 kalsilite 7.58 3.16 -4.43 -0.633 0.75621E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.27 -4.39 -0.439 0.74983E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20479E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.70 -1.21 -0.093 0.20724E+04 120 muscovite 2.58 1.82 -0.76 -0.045 0.12979E+04 121 paragonite 4.24 2.84 -1.39 -0.082 0.23815E+04 122 nepheline 8.34 4.18 -4.16 -0.595 0.71065E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40606E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.77 -3.79 -1.265 0.64781E+04 152 rhodonite 7.45 5.02 -2.43 -0.485 0.41408E+04 153 sanidine -1.28 -3.70 -2.42 -0.187 0.41401E+04 155 siderite -2.61 -6.90 -4.29 -1.430 0.73226E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.62 -1.40 -0.042 0.23832E+04 165 stilpnomelane-Mg 27.44 22.77 -4.67 -0.140 0.79818E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83504E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.660 0.78835E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.88 -3.36 -0.206 0.57446E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.55 -3.21 -0.196 0.54725E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.02 -2.78 -0.170 0.47461E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.68 -2.64 -0.162 0.45097E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.16 -1.18 -0.076 0.20176E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.50 -1.02 -0.066 0.17471E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.22 -2.24 -0.172 0.38193E+04 243 an25ab75 2.65 0.40 -2.25 -0.173 0.38419E+04 244 an30ab70 3.28 1.01 -2.27 -0.175 0.38741E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1630000 g New total amount of reactant added: 0.1670000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1670000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3677718E-03 Osmotic coef. = 0.9886 True ionic strength = .4376951E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.50794E-08 -8.2942 0.48527E-08 -8.3140 0.95537E+00 -0.0198 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13178E-03 -3.8801 0.95519E+00 -0.0199 4 SO4-- 0.25478E-04 -4.5938 0.22386E-04 -4.6500 0.87865E+00 -0.0562 5 HCO3- 0.12690E-04 -4.8965 0.12122E-04 -4.9164 0.95523E+00 -0.0199 6 HS- 0.23206E-12 -12.6344 0.22166E-12 -12.6543 0.95519E+00 -0.0199 7 Al+++ 0.86318E-22 -22.0639 0.65948E-22 -22.1808 0.76401E+00 -0.1169 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.23829E-05 -5.6229 0.20932E-05 -5.6792 0.87845E+00 -0.0563 10 Mg++ 0.95332E-08 -8.0208 0.83732E-08 -8.0771 0.87832E+00 -0.0563 11 Fe++ 0.56249E-10 -10.2499 0.49406E-10 -10.3062 0.87835E+00 -0.0563 12 K+ 0.35442E-04 -4.4505 0.33856E-04 -4.4704 0.95524E+00 -0.0199 13 Na+ 0.36925E-03 -3.4327 0.35271E-03 -3.4526 0.95518E+00 -0.0199 14 Mn++ 0.75269E-08 -8.1234 0.66114E-08 -8.1797 0.87837E+00 -0.0563 15 HPO4-- 0.24265E-07 -7.6150 0.21320E-07 -7.6712 0.87865E+00 -0.0562 16 HSiO3- 0.75253E-04 -4.1235 0.71881E-04 -4.1434 0.95519E+00 -0.0199 17 Ca(HSiO3)+ 0.35872E-08 -8.4453 0.34266E-08 -8.4651 0.95525E+00 -0.0199 18 Mg(HSiO3)+ 0.17858E-10 -10.7482 0.17059E-10 -10.7681 0.95525E+00 -0.0199 19 NaHSiO3,aq 0.41005E-06 -6.3872 0.41005E-06 -6.3872 0.10000E+01 0.0000 20 AlO+ 0.39883E-12 -12.3992 0.38098E-12 -12.4191 0.95525E+00 -0.0199 21 AlOH+2 0.10480E-16 -16.9796 0.92059E-17 -17.0359 0.87840E+00 -0.0563 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.74668E-05 -5.1269 0.71318E-05 -5.1468 0.95513E+00 -0.0199 24 CH4,aq 0.11661E-18 -18.9333 0.11659E-18 -18.9333 0.99989E+00 0.0000 29 CO,aq 0.14380E-17 -17.8422 0.14380E-17 -17.8422 0.10000E+01 0.0000 30 CO2,aq 0.12571E-06 -6.9006 0.12569E-06 -6.9007 0.99989E+00 0.0000 31 CO3-2 0.24834E-06 -6.6050 0.21819E-06 -6.6612 0.87859E+00 -0.0562 32 CaCO3,aq 0.57267E-08 -8.2421 0.57267E-08 -8.2421 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.67804E-09 -9.1687 0.64770E-09 -9.1886 0.95525E+00 -0.0199 34 CaCl+ 0.46732E-09 -9.3304 0.44641E-09 -9.3503 0.95525E+00 -0.0199 35 CaCl2,aq 0.13976E-13 -13.8546 0.13976E-13 -13.8546 0.10000E+01 0.0000 36 CaOH+ 0.32182E-07 -7.4924 0.30742E-07 -7.5123 0.95525E+00 -0.0199 37 CaSO4,aq 0.14880E-07 -7.8274 0.14880E-07 -7.8274 0.10000E+01 0.0000 38 HCl,aq 0.11719E-12 -12.9311 0.11719E-12 -12.9311 0.10000E+01 0.0000 43 FeCl+ 0.10788E-13 -13.9670 0.10306E-13 -13.9869 0.95525E+00 -0.0199 46 FeO,aq 0.81540E-10 -10.0886 0.81540E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.34693E-09 -9.4598 0.33140E-09 -9.4796 0.95525E+00 -0.0199 48 HFeO2- 0.18406E-09 -9.7350 0.17581E-09 -9.7550 0.95519E+00 -0.0199 49 FeO+ 0.38776E-13 -13.4114 0.37040E-13 -13.4313 0.95525E+00 -0.0199 50 FeOH+2 0.39079E-19 -19.4081 0.34327E-19 -19.4644 0.87840E+00 -0.0563 51 FeO2- 0.33695E-09 -9.4724 0.32185E-09 -9.4923 0.95519E+00 -0.0199 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45547E-09 -9.3415 0.45542E-09 -9.3416 0.99989E+00 0.0000 54 KCl,aq 0.80863E-10 -10.0923 0.80863E-10 -10.0923 0.10000E+01 0.0000 55 KHSO4,aq 0.10399E-16 -16.9830 0.10399E-16 -16.9830 0.10000E+01 0.0000 56 KOH,aq 0.29794E-08 -8.5259 0.29794E-08 -8.5259 0.10000E+01 0.0000 57 KSO4- 0.12313E-07 -7.9096 0.11761E-07 -7.9296 0.95519E+00 -0.0199 58 MgCO3,aq 0.57419E-11 -11.2409 0.57419E-11 -11.2409 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27714E-11 -11.5573 0.26474E-11 -11.5772 0.95525E+00 -0.0199 60 MgCl+ 0.16943E-11 -11.7710 0.16185E-11 -11.7909 0.95525E+00 -0.0199 61 MgOH+ 0.71235E-09 -9.1473 0.68047E-09 -9.1672 0.95525E+00 -0.0199 63 MnO,aq 0.29074E-09 -9.5365 0.29074E-09 -9.5365 0.10000E+01 0.0000 64 MnOH+ 0.43128E-08 -8.3652 0.41197E-08 -8.3851 0.95525E+00 -0.0199 65 MnO2-2 0.46636E-15 -15.3313 0.40974E-15 -15.3875 0.87859E+00 -0.0562 66 HMnO2- 0.45605E-12 -12.3410 0.43562E-12 -12.3609 0.95519E+00 -0.0199 69 MnCl+ 0.56165E-11 -11.2505 0.53651E-11 -11.2704 0.95525E+00 -0.0199 70 MnSO4,aq 0.42728E-10 -10.3693 0.42728E-10 -10.3693 0.10000E+01 0.0000 71 NaCl,aq 0.15404E-07 -7.8124 0.15404E-07 -7.8124 0.10000E+01 0.0000 72 NaOH,aq 0.31228E-07 -7.5055 0.31228E-07 -7.5055 0.10000E+01 0.0000 74 OH- 0.12465E-03 -3.9043 0.11906E-03 -3.9242 0.95513E+00 -0.0199 79 HPO3-2 0.34440E-19 -19.4629 0.30259E-19 -19.5191 0.87859E+00 -0.0562 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.19981E-08 -8.6994 0.19086E-08 -8.7193 0.95522E+00 -0.0199 84 PO4-3 0.46844E-11 -11.3293 0.35846E-11 -11.4456 0.76522E+00 -0.1162 87 H2P2O7-2 0.32510E-18 -18.4880 0.28563E-18 -18.5442 0.87859E+00 -0.0562 88 HP2O7-3 0.15383E-16 -16.8130 0.11753E-16 -16.9299 0.76402E+00 -0.1169 89 P2O7-4 0.91998E-18 -18.0362 0.57858E-18 -18.2376 0.62890E+00 -0.2014 90 H2S,aq 0.33249E-14 -14.4782 0.33245E-14 -14.4783 0.99989E+00 0.0000 97 SO3-2 0.15072E-14 -14.8218 0.13249E-14 -14.8778 0.87900E+00 -0.0560 98 HSO3- 0.42144E-15 -15.3753 0.40255E-15 -15.3952 0.95519E+00 -0.0199 99 HSO4- 0.10960E-09 -9.9602 0.10469E-09 -9.9801 0.95527E+00 -0.0199 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5079428E-08 -.2304310E-03 -.2322467E+00 0.0000 2 H2O 0.1000000E+01 0.5550831E+02 0.9999387E+06 0.0000 3 Cl- 0.1379636E-03 0.1379796E-03 0.4891496E+01 4.4339 4 SO4-- 0.2547812E-04 0.2550542E-04 0.2449944E+01 11.9780 5 HCO3- 0.1269005E-04 0.1307051E-04 0.7974780E+00 3.3976 6 HS- 0.2320615E-12 0.4715068E-10 0.1559273E-05 -4.3403 7 Al+++ 0.8631845E-22 0.7482478E-05 0.2018763E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4492397E-03 0.4317625E+02 -3.4276 9 Ca++ 0.2382873E-05 0.2440394E-05 0.9780023E-01 10.9488 10 Mg++ 0.9533239E-08 0.1027365E-07 0.2497580E-03 8.5509 11 Fe++ 0.5624889E-10 0.1204419E-08 0.6725911E-04 6.3218 12 K+ 0.3544249E-04 0.3545786E-04 0.1386390E+01 3.8436 13 Na+ 0.3692545E-03 0.3697112E-03 0.8499074E+01 4.8614 14 Mn++ 0.7526864E-08 0.1217916E-07 0.6690585E-03 8.4483 15 HPO4-- 0.2426476E-07 0.2626752E-07 0.2520979E-02 8.9568 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2752232E-02 -.2304220E-03 -.2521810E-02 0.0000000E+00 2 H2O 0.5550616E+02 0.5550614E+02 0.1667749E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3013261E-04 0.2550442E-04 0.4628186E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4628139E-05 0.4714883E-10 -.4628186E-05 0.0000000E+00 7 Al+++ 0.5445438E-03 0.7482184E-05 0.5370617E-03 0.0000000E+00 8 H4SiO4 0.1738935E-02 0.4492221E-03 0.1289713E-02 0.0000000E+00 9 Ca++ 0.2065449E-03 0.2440299E-05 0.2041046E-03 0.0000000E+00 10 Mg++ 0.1325397E-03 0.1027325E-07 0.1325294E-03 0.0000000E+00 11 Fe++ 0.1190724E-03 0.1204371E-08 0.1190712E-03 0.0000000E+00 12 K+ 0.3545648E-04 0.3545648E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3696967E-03 0.3696967E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2895546E-05 0.1217868E-07 0.2883367E-05 0.0000000E+00 15 HPO4-- 0.9882353E-06 0.2626649E-07 0.9619688E-06 0.0000000E+00 Chg. balance for solid moles: -.8538E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1670000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3207E-06 -6.494 0.1611E-03 -3.793 0.1041 0.5118E-04 clinochlore 0.2651E-04 -4.577 0.1473E-01 -1.832 9.517 0.5604E-02 daphnite 0.1641E-04 -4.785 0.1171E-01 -1.932 7.563 0.3548E-02 chlorite-Mn 0.5767E-06 -6.239 0.4088E-03 -3.388 0.2641 0.1303E-03 hematite 0.1851E-04 -4.733 0.2956E-02 -2.529 1.910 0.5604E-03 kaolinite 0.2254E-04 -4.647 0.5818E-02 -2.235 3.759 0.2239E-02 lawsonite 0.6067E-04 -4.217 0.1906E-01 -1.720 12.32 0.6148E-02 stilbite 0.1418E-03 -3.848 0.9995E-01 -1.000 64.57 0.4662E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1326E-01 0.1326E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.154802 g Volume = 0.064900 cm3 Porosity: 93.9164% V(tot) - V(min): 0.10019E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1670000 g log = -0.7773 Original solution: 1000.0103000 g Original solution / Rock added: 5988.09 (Water/Rock Ratio), log = 3.7773 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1309E-04 1.0071 0.1345E-04 0.1335E-04 CH4,gas 0.1661E-15 1.0125 0.1716E-15 0.1695E-15 H2,gas 0.5857E-06 1.0005 0.5979E-06 0.5976E-06 H2S,gas 0.8993E-13 0.9960 0.9139E-13 0.9175E-13 S2,gas 0.8595E-33 1.0000 0.8769E-33 0.8769E-33 CO,gas 0.2100E-14 1.0000 0.2143E-14 0.2143E-14 SO3,gas 0.1954E-36 1.0000 0.1993E-36 0.1993E-36 SO2,gas 0.4544E-20 1.0000 0.4637E-20 0.4637E-20 HCl,gas 0.2027E-15 1.0000 0.2068E-15 0.2068E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.12132E-10 46 clinochlore 39.07 39.07 0.00 0.000 0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.36397E-10 90 hematite 12.57 12.57 0.00 0.000 0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.36397E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.23 -6.57 -2.190 0.11219E+05 -4.871 3 CH4,gas 4.54 -12.92 -17.46 -4.366 0.29820E+05 -15.765 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.97 -14.74 -7.369 0.25165E+05 -13.039 6 S2,gas -7.34 -42.09 -34.76 -5.347 0.59345E+05 -33.057 7 CO,gas 3.21 -13.15 -16.37 -5.036 0.27948E+05 -14.669 8 SO3,gas 17.12 -21.28 -38.40 -9.600 0.65566E+05 -36.700 9 SO2,gas 0.83 -21.20 -22.03 -5.875 0.37620E+05 -20.334 10 HCl,gas 5.19 -12.19 -17.38 -8.692 0.29682E+05 -15.684 11 acmite 7.71 4.29 -3.42 -0.355 0.58403E+04 15 albite-high 0.69 -2.66 -3.35 -0.258 0.57256E+04 16 albite -0.38 -2.66 -2.28 -0.175 0.38868E+04 19 spessartine 24.46 20.58 -3.87 -0.194 0.66127E+04 20 analcite 3.32 0.77 -2.55 -0.284 0.43616E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 15.29 -4.84 -0.269 0.82573E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.28 -3.25 -1.083 0.55461E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.28 -3.09 -1.031 0.52819E+04 38 carnegieite-low 9.02 4.20 -4.83 -0.690 0.82441E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.45 -3.90 -0.229 0.66528E+04 43 celadonite-Fe 3.88 -0.78 -4.66 -0.274 0.79574E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14648E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64762E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82467E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68800E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.77 -3.45 -0.345 0.58871E+04 97 kalsilite 7.58 3.18 -4.41 -0.630 0.75242E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.25 -4.37 -0.437 0.74603E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20479E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.68 -1.19 -0.092 0.20344E+04 120 muscovite 2.58 1.84 -0.74 -0.043 0.12600E+04 121 paragonite 4.24 2.86 -1.38 -0.081 0.23515E+04 122 nepheline 8.34 4.20 -4.14 -0.592 0.70765E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40603E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.78 -3.81 -1.269 0.64983E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41406E+04 153 sanidine -1.28 -3.68 -2.40 -0.185 0.41022E+04 155 siderite -2.61 -6.91 -4.30 -1.433 0.73430E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.63 -1.38 -0.041 0.23642E+04 165 stilpnomelane-Mg 27.44 22.78 -4.66 -0.139 0.79628E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83504E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54868E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.660 0.78830E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.88 -3.36 -0.206 0.57321E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.54 -3.20 -0.196 0.54625E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.01 -2.77 -0.170 0.47336E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.67 -2.64 -0.161 0.44998E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.17 -1.17 -0.075 0.20051E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.50 -1.02 -0.065 0.17372E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.20 -2.22 -0.171 0.37953E+04 243 an25ab75 2.65 0.41 -2.24 -0.172 0.38193E+04 244 an30ab70 3.28 1.02 -2.26 -0.174 0.38530E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1670000 g New total amount of reactant added: 0.1710000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1710000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3713680E-03 Osmotic coef. = 0.9885 True ionic strength = .4431884E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.49477E-08 -8.3056 0.47261E-08 -8.3255 0.95521E+00 -0.0199 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13176E-03 -3.8802 0.95503E+00 -0.0200 4 SO4-- 0.25479E-04 -4.5938 0.22372E-04 -4.6503 0.87806E+00 -0.0565 5 HCO3- 0.12687E-04 -4.8966 0.12117E-04 -4.9166 0.95507E+00 -0.0200 6 HS- 0.22588E-12 -12.6461 0.21573E-12 -12.6661 0.95503E+00 -0.0200 7 Al+++ 0.79858E-22 -22.0977 0.60919E-22 -22.2152 0.76284E+00 -0.1176 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.22617E-05 -5.6456 0.19854E-05 -5.7022 0.87785E+00 -0.0566 10 Mg++ 0.90483E-08 -8.0434 0.79419E-08 -8.1001 0.87772E+00 -0.0566 11 Fe++ 0.53388E-10 -10.2726 0.46861E-10 -10.3292 0.87775E+00 -0.0566 12 K+ 0.36291E-04 -4.4402 0.34661E-04 -4.4602 0.95508E+00 -0.0200 13 Na+ 0.37426E-03 -3.4268 0.35742E-03 -3.4468 0.95502E+00 -0.0200 14 Mn++ 0.71459E-08 -8.1459 0.62725E-08 -8.2026 0.87778E+00 -0.0566 15 HPO4-- 0.25600E-07 -7.5918 0.22478E-07 -7.6482 0.87806E+00 -0.0565 16 HSiO3- 0.77283E-04 -4.1119 0.73807E-04 -4.1319 0.95503E+00 -0.0200 17 Ca(HSiO3)+ 0.34941E-08 -8.4567 0.33372E-08 -8.4766 0.95508E+00 -0.0200 18 Mg(HSiO3)+ 0.17395E-10 -10.7596 0.16613E-10 -10.7795 0.95508E+00 -0.0200 19 NaHSiO3,aq 0.42667E-06 -6.3699 0.42667E-06 -6.3699 0.10000E+01 0.0000 20 AlO+ 0.38849E-12 -12.4106 0.37104E-12 -12.4306 0.95508E+00 -0.0200 21 AlOH+2 0.99473E-17 -17.0023 0.87317E-17 -17.0589 0.87780E+00 -0.0566 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.76682E-05 -5.1153 0.73229E-05 -5.1353 0.95497E+00 -0.0200 24 CH4,aq 0.11351E-18 -18.9450 0.11350E-18 -18.9450 0.99988E+00 -0.0001 29 CO,aq 0.13999E-17 -17.8539 0.13999E-17 -17.8539 0.10000E+01 0.0000 30 CO2,aq 0.12238E-06 -6.9123 0.12236E-06 -6.9123 0.99988E+00 -0.0001 31 CO3-2 0.25506E-06 -6.5934 0.22394E-06 -6.6499 0.87800E+00 -0.0565 32 CaCO3,aq 0.55749E-08 -8.2538 0.55749E-08 -8.2538 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64295E-09 -9.1918 0.61408E-09 -9.2118 0.95508E+00 -0.0200 34 CaCl+ 0.44325E-09 -9.3534 0.42334E-09 -9.3733 0.95508E+00 -0.0200 35 CaCl2,aq 0.13252E-13 -13.8777 0.13252E-13 -13.8777 0.10000E+01 0.0000 36 CaOH+ 0.31348E-07 -7.5038 0.29940E-07 -7.5238 0.95508E+00 -0.0200 37 CaSO4,aq 0.14104E-07 -7.8506 0.14104E-07 -7.8506 0.10000E+01 0.0000 38 HCl,aq 0.11411E-12 -12.9427 0.11411E-12 -12.9427 0.10000E+01 0.0000 43 FeCl+ 0.10233E-13 -13.9900 0.97730E-14 -14.0100 0.95508E+00 -0.0200 46 FeO,aq 0.81539E-10 -10.0886 0.81539E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.33793E-09 -9.4712 0.32275E-09 -9.4911 0.95508E+00 -0.0200 48 HFeO2- 0.18902E-09 -9.7235 0.18052E-09 -9.7435 0.95503E+00 -0.0200 49 FeO+ 0.37770E-13 -13.4228 0.36074E-13 -13.4428 0.95508E+00 -0.0200 50 FeOH+2 0.37091E-19 -19.4307 0.32559E-19 -19.4873 0.87780E+00 -0.0566 51 FeO2- 0.34603E-09 -9.4609 0.33047E-09 -9.4809 0.95503E+00 -0.0200 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45547E-09 -9.3415 0.45542E-09 -9.3416 0.99988E+00 -0.0001 54 KCl,aq 0.82771E-10 -10.0821 0.82771E-10 -10.0821 0.10000E+01 0.0000 55 KHSO4,aq 0.10362E-16 -16.9846 0.10362E-16 -16.9846 0.10000E+01 0.0000 56 KOH,aq 0.31320E-08 -8.5042 0.31320E-08 -8.5042 0.10000E+01 0.0000 57 KSO4- 0.12599E-07 -7.8996 0.12033E-07 -7.9196 0.95503E+00 -0.0200 58 MgCO3,aq 0.55897E-11 -11.2526 0.55897E-11 -11.2526 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26280E-11 -11.5804 0.25100E-11 -11.6003 0.95508E+00 -0.0200 60 MgCl+ 0.16070E-11 -11.7940 0.15348E-11 -11.8139 0.95508E+00 -0.0200 61 MgOH+ 0.69388E-09 -9.1587 0.66271E-09 -9.1787 0.95508E+00 -0.0200 63 MnO,aq 0.29082E-09 -9.5364 0.29082E-09 -9.5364 0.10000E+01 0.0000 64 MnOH+ 0.42020E-08 -8.3765 0.40133E-08 -8.3965 0.95508E+00 -0.0200 65 MnO2-2 0.49214E-15 -15.3079 0.43210E-15 -15.3644 0.87800E+00 -0.0565 66 HMnO2- 0.46847E-12 -12.3293 0.44740E-12 -12.3493 0.95503E+00 -0.0200 69 MnCl+ 0.53286E-11 -11.2734 0.50892E-11 -11.2933 0.95508E+00 -0.0200 70 MnSO4,aq 0.40511E-10 -10.3924 0.40511E-10 -10.3924 0.10000E+01 0.0000 71 NaCl,aq 0.15607E-07 -7.8067 0.15607E-07 -7.8067 0.10000E+01 0.0000 72 NaOH,aq 0.32493E-07 -7.4882 0.32493E-07 -7.4882 0.10000E+01 0.0000 74 OH- 0.12802E-03 -3.8927 0.12225E-03 -3.9127 0.95497E+00 -0.0200 79 HPO3-2 0.36335E-19 -19.4397 0.31902E-19 -19.4962 0.87800E+00 -0.0565 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.20520E-08 -8.6878 0.19597E-08 -8.7078 0.95505E+00 -0.0200 84 PO4-3 0.50787E-11 -11.2942 0.38805E-11 -11.4111 0.76407E+00 -0.1169 87 H2P2O7-2 0.34298E-18 -18.4647 0.30114E-18 -18.5212 0.87800E+00 -0.0565 88 HP2O7-3 0.16678E-16 -16.7779 0.12723E-16 -16.8954 0.76286E+00 -0.1176 89 P2O7-4 0.10254E-17 -17.9891 0.64312E-18 -18.1917 0.62720E+00 -0.2026 90 H2S,aq 0.31514E-14 -14.5015 0.31510E-14 -14.5015 0.99988E+00 -0.0001 97 SO3-2 0.15072E-14 -14.8218 0.13240E-14 -14.8781 0.87841E+00 -0.0563 98 HSO3- 0.41023E-15 -15.3870 0.39178E-15 -15.4070 0.95503E+00 -0.0200 99 HSO4- 0.10668E-09 -9.9719 0.10189E-09 -9.9918 0.95511E+00 -0.0199 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4947713E-08 -.2366548E-03 -.2385194E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999384E+06 0.0000 3 Cl- 0.1379636E-03 0.1379797E-03 0.4891498E+01 4.4453 4 SO4-- 0.2547864E-04 0.2550544E-04 0.2449945E+01 12.0007 5 HCO3- 0.1268686E-04 0.1307052E-04 0.7974784E+00 3.4089 6 HS- 0.2258846E-12 0.4600722E-10 0.1521459E-05 -4.3406 7 Al+++ 0.7985759E-22 0.7683851E-05 0.2073093E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4512857E-03 0.4337287E+02 -3.4276 9 Ca++ 0.2261669E-05 0.2317276E-05 0.9286617E-01 10.9488 10 Mg++ 0.9048336E-08 0.9769433E-08 0.2375001E-03 8.5509 11 Fe++ 0.5338753E-10 0.1206607E-08 0.6738127E-04 6.3218 12 K+ 0.3629137E-04 0.3630718E-04 0.1419597E+01 3.8653 13 Na+ 0.3742579E-03 0.3747326E-03 0.8614506E+01 4.8787 14 Mn++ 0.7145870E-08 0.1168501E-07 0.6419123E-03 8.4484 15 HPO4-- 0.2559973E-07 0.2765678E-07 0.2654309E-02 9.0028 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2818466E-02 -.2366453E-03 -.2581821E-02 0.0000000E+00 2 H2O 0.5550611E+02 0.5550610E+02 0.8167316E-05 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3024346E-04 0.2550442E-04 0.4739039E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4738993E-05 0.4600538E-10 -.4739039E-05 0.0000000E+00 7 Al+++ 0.5575868E-03 0.7683544E-05 0.5499033E-03 0.0000000E+00 8 H4SiO4 0.1780586E-02 0.4512676E-03 0.1329318E-02 0.0000000E+00 9 Ca++ 0.2111455E-03 0.2317184E-05 0.2088283E-03 0.0000000E+00 10 Mg++ 0.1357143E-03 0.9769043E-08 0.1357045E-03 0.0000000E+00 11 Fe++ 0.1219245E-03 0.1206558E-08 0.1219233E-03 0.0000000E+00 12 K+ 0.3630573E-04 0.3630573E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3747177E-03 0.3747177E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2964900E-05 0.1168454E-07 0.2953215E-05 0.0000000E+00 15 HPO4-- 0.1011906E-05 0.2765567E-07 0.9842499E-06 0.0000000E+00 Chg. balance for solid moles: -.9910E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1710000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3281E-06 -6.484 0.1648E-03 -3.783 0.1035 0.5237E-04 clinochlore 0.2714E-04 -4.566 0.1509E-01 -1.821 9.477 0.5738E-02 daphnite 0.1680E-04 -4.775 0.1199E-01 -1.921 7.531 0.3633E-02 chlorite-Mn 0.5906E-06 -6.229 0.4187E-03 -3.378 0.2631 0.1334E-03 hematite 0.1896E-04 -4.722 0.3027E-02 -2.519 1.902 0.5738E-03 kaolinite 0.2323E-04 -4.634 0.5997E-02 -2.222 3.767 0.2307E-02 lawsonite 0.6021E-04 -4.220 0.1892E-01 -1.723 11.89 0.6102E-02 stilbite 0.1470E-03 -3.833 0.1036 -0.985 65.07 0.4831E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1326E-01 0.1326E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.159180 g Volume = 0.066850 cm3 Porosity: 93.7430% V(tot) - V(min): 0.10016E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1710000 g log = -0.7670 Original solution: 1000.0103000 g Original solution / Rock added: 5848.01 (Water/Rock Ratio), log = 3.7670 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1274E-04 1.0071 0.1309E-04 0.1300E-04 CH4,gas 0.1617E-15 1.0125 0.1671E-15 0.1650E-15 H2,gas 0.5857E-06 1.0005 0.5979E-06 0.5976E-06 H2S,gas 0.8523E-13 0.9960 0.8662E-13 0.8696E-13 S2,gas 0.7721E-33 1.0000 0.7878E-33 0.7878E-33 CO,gas 0.2045E-14 1.0000 0.2086E-14 0.2086E-14 SO3,gas 0.1852E-36 1.0000 0.1889E-36 0.1889E-36 SO2,gas 0.4307E-20 1.0000 0.4395E-20 0.4395E-20 HCl,gas 0.1973E-15 1.0000 0.2013E-15 0.2013E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.24 -6.58 -2.194 0.11239E+05 -4.883 3 CH4,gas 4.54 -12.93 -17.48 -4.369 0.29840E+05 -15.777 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -20.99 -14.76 -7.381 0.25205E+05 -13.062 6 S2,gas -7.34 -42.14 -34.80 -5.354 0.59424E+05 -33.104 7 CO,gas 3.21 -13.16 -16.38 -5.040 0.27968E+05 -14.681 8 SO3,gas 17.12 -21.30 -38.42 -9.606 0.65606E+05 -36.724 9 SO2,gas 0.83 -21.22 -22.06 -5.882 0.37660E+05 -20.357 10 HCl,gas 5.19 -12.21 -17.40 -8.698 0.29702E+05 -15.696 11 acmite 7.71 4.31 -3.40 -0.354 0.58109E+04 15 albite-high 0.69 -2.64 -3.34 -0.257 0.56961E+04 16 albite -0.38 -2.64 -2.26 -0.174 0.38573E+04 19 spessartine 24.46 20.58 -3.87 -0.194 0.66121E+04 20 analcite 3.32 0.78 -2.54 -0.282 0.43322E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 15.31 -4.81 -0.267 0.82203E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.29 -3.26 -1.087 0.55660E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.29 -3.11 -1.035 0.53018E+04 38 carnegieite-low 9.02 4.21 -4.81 -0.687 0.82147E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.47 -3.87 -0.228 0.66158E+04 43 celadonite-Fe 3.88 -0.76 -4.64 -0.273 0.79204E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14646E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64762E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82467E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68800E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.78 -3.43 -0.343 0.58577E+04 97 kalsilite 7.58 3.20 -4.38 -0.626 0.74872E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.23 -4.35 -0.435 0.74233E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.66 -1.17 -0.090 0.19974E+04 120 muscovite 2.58 1.87 -0.72 -0.042 0.12230E+04 121 paragonite 4.24 2.88 -1.36 -0.080 0.23220E+04 122 nepheline 8.34 4.21 -4.13 -0.590 0.70470E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40602E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.79 -3.82 -1.272 0.65180E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41404E+04 153 sanidine -1.28 -3.66 -2.38 -0.183 0.40652E+04 155 siderite -2.61 -6.92 -4.31 -1.437 0.73629E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.64 -1.37 -0.041 0.23457E+04 165 stilpnomelane-Mg 27.44 22.79 -4.65 -0.139 0.79443E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83504E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.660 0.78826E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.87 -3.35 -0.205 0.57199E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.54 -3.19 -0.196 0.54528E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -5.00 -2.77 -0.169 0.47214E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.67 -2.63 -0.161 0.44901E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.17 -1.17 -0.075 0.19928E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.51 -1.01 -0.065 0.17275E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.19 -2.21 -0.170 0.37717E+04 243 an25ab75 2.65 0.42 -2.22 -0.171 0.37972E+04 244 an30ab70 3.28 1.03 -2.24 -0.173 0.38324E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1710000 g New total amount of reactant added: 0.1750000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1750000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3749851E-03 Osmotic coef. = 0.9885 True ionic strength = .4487080E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.48223E-08 -8.3167 0.46056E-08 -8.3367 0.95505E+00 -0.0200 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13174E-03 -3.8803 0.95486E+00 -0.0201 4 SO4-- 0.25479E-04 -4.5938 0.22357E-04 -4.6506 0.87746E+00 -0.0568 5 HCO3- 0.12683E-04 -4.8968 0.12112E-04 -4.9168 0.95491E+00 -0.0200 6 HS- 0.22001E-12 -12.6576 0.21008E-12 -12.6776 0.95487E+00 -0.0201 7 Al+++ 0.74015E-22 -22.1307 0.56376E-22 -22.2489 0.76168E+00 -0.1182 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.21492E-05 -5.6677 0.18854E-05 -5.7246 0.87726E+00 -0.0569 10 Mg++ 0.85986E-08 -8.0656 0.75420E-08 -8.1225 0.87713E+00 -0.0569 11 Fe++ 0.50733E-10 -10.2947 0.44501E-10 -10.3516 0.87716E+00 -0.0569 12 K+ 0.37140E-04 -4.4302 0.35466E-04 -4.4502 0.95492E+00 -0.0200 13 Na+ 0.37926E-03 -3.4211 0.36214E-03 -3.4411 0.95486E+00 -0.0201 14 Mn++ 0.67923E-08 -8.1680 0.59581E-08 -8.2249 0.87718E+00 -0.0569 15 HPO4-- 0.26975E-07 -7.5690 0.23670E-07 -7.6258 0.87747E+00 -0.0568 16 HSiO3- 0.79319E-04 -4.1006 0.75738E-04 -4.1207 0.95486E+00 -0.0201 17 Ca(HSiO3)+ 0.34056E-08 -8.4678 0.32521E-08 -8.4878 0.95492E+00 -0.0200 18 Mg(HSiO3)+ 0.16954E-10 -10.7707 0.16190E-10 -10.7908 0.95492E+00 -0.0200 19 NaHSiO3,aq 0.44361E-06 -6.3530 0.44361E-06 -6.3530 0.10000E+01 0.0000 20 AlO+ 0.37865E-12 -12.4218 0.36158E-12 -12.4418 0.95492E+00 -0.0200 21 AlOH+2 0.94528E-17 -17.0244 0.82921E-17 -17.0813 0.87721E+00 -0.0569 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.78702E-05 -5.1040 0.75145E-05 -5.1241 0.95481E+00 -0.0201 24 CH4,aq 0.11056E-18 -18.9564 0.11055E-18 -18.9564 0.99988E+00 -0.0001 29 CO,aq 0.13636E-17 -17.8653 0.13636E-17 -17.8653 0.10000E+01 0.0000 30 CO2,aq 0.11920E-06 -6.9237 0.11919E-06 -6.9238 0.99988E+00 -0.0001 31 CO3-2 0.26179E-06 -6.5820 0.22970E-06 -6.6388 0.87740E+00 -0.0568 32 CaCO3,aq 0.54304E-08 -8.2652 0.54304E-08 -8.2652 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61042E-09 -9.2144 0.58290E-09 -9.2344 0.95492E+00 -0.0200 34 CaCl+ 0.42093E-09 -9.3758 0.40196E-09 -9.3958 0.95492E+00 -0.0200 35 CaCl2,aq 0.12580E-13 -13.9003 0.12580E-13 -13.9003 0.10000E+01 0.0000 36 CaOH+ 0.30554E-07 -7.5149 0.29176E-07 -7.5350 0.95492E+00 -0.0200 37 CaSO4,aq 0.13385E-07 -7.8734 0.13385E-07 -7.8734 0.10000E+01 0.0000 38 HCl,aq 0.11118E-12 -12.9540 0.11118E-12 -12.9540 0.10000E+01 0.0000 43 FeCl+ 0.97173E-14 -14.0125 0.92792E-14 -14.0325 0.95492E+00 -0.0200 46 FeO,aq 0.81539E-10 -10.0886 0.81539E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.32937E-09 -9.4823 0.31452E-09 -9.5023 0.95492E+00 -0.0200 48 HFeO2- 0.19400E-09 -9.7122 0.18524E-09 -9.7323 0.95486E+00 -0.0201 49 FeO+ 0.36813E-13 -13.4340 0.35154E-13 -13.4540 0.95492E+00 -0.0200 50 FeOH+2 0.35247E-19 -19.4529 0.30919E-19 -19.5098 0.87721E+00 -0.0569 51 FeO2- 0.35515E-09 -9.4496 0.33912E-09 -9.4696 0.95486E+00 -0.0201 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45546E-09 -9.3415 0.45541E-09 -9.3416 0.99988E+00 -0.0001 54 KCl,aq 0.84679E-10 -10.0722 0.84679E-10 -10.0722 0.10000E+01 0.0000 55 KHSO4,aq 0.10325E-16 -16.9861 0.10325E-16 -16.9861 0.10000E+01 0.0000 56 KOH,aq 0.32886E-08 -8.4830 0.32886E-08 -8.4830 0.10000E+01 0.0000 57 KSO4- 0.12886E-07 -7.8899 0.12304E-07 -7.9100 0.95486E+00 -0.0201 58 MgCO3,aq 0.54448E-11 -11.2640 0.54448E-11 -11.2640 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24950E-11 -11.6029 0.23826E-11 -11.6230 0.95492E+00 -0.0200 60 MgCl+ 0.15261E-11 -11.8164 0.14573E-11 -11.8365 0.95492E+00 -0.0200 61 MgOH+ 0.67630E-09 -9.1699 0.64581E-09 -9.1899 0.95492E+00 -0.0200 63 MnO,aq 0.29089E-09 -9.5363 0.29089E-09 -9.5363 0.10000E+01 0.0000 64 MnOH+ 0.40965E-08 -8.3876 0.39119E-08 -8.4076 0.95492E+00 -0.0200 65 MnO2-2 0.51871E-15 -15.2851 0.45512E-15 -15.3419 0.87740E+00 -0.0568 66 HMnO2- 0.48093E-12 -12.3179 0.45922E-12 -12.3380 0.95486E+00 -0.0201 69 MnCl+ 0.50615E-11 -11.2957 0.48333E-11 -11.3158 0.95492E+00 -0.0200 70 MnSO4,aq 0.38455E-10 -10.4150 0.38455E-10 -10.4150 0.10000E+01 0.0000 71 NaCl,aq 0.15810E-07 -7.8011 0.15810E-07 -7.8011 0.10000E+01 0.0000 72 NaOH,aq 0.33784E-07 -7.4713 0.33784E-07 -7.4713 0.10000E+01 0.0000 74 OH- 0.13139E-03 -3.8814 0.12545E-03 -3.9015 0.95481E+00 -0.0201 79 HPO3-2 0.38286E-19 -19.4170 0.33593E-19 -19.4738 0.87740E+00 -0.0568 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.21060E-08 -8.6765 0.20110E-08 -8.6966 0.95489E+00 -0.0200 84 PO4-3 0.54962E-11 -11.2599 0.41932E-11 -11.3775 0.76292E+00 -0.1175 87 H2P2O7-2 0.36141E-18 -18.4420 0.31710E-18 -18.4988 0.87740E+00 -0.0568 88 HP2O7-3 0.18049E-16 -16.7435 0.13748E-16 -16.8618 0.76170E+00 -0.1182 89 P2O7-4 0.11401E-17 -17.9431 0.71313E-18 -18.1468 0.62552E+00 -0.2038 90 H2S,aq 0.29906E-14 -14.5242 0.29903E-14 -14.5243 0.99988E+00 -0.0001 97 SO3-2 0.15072E-14 -14.8218 0.13231E-14 -14.8784 0.87782E+00 -0.0566 98 HSO3- 0.39957E-15 -15.3984 0.38154E-15 -15.4185 0.95486E+00 -0.0201 99 HSO4- 0.10391E-09 -9.9833 0.99231E-10 -10.0034 0.95495E+00 -0.0200 Charge balance for all species = 0.7203E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4822349E-08 -.2428983E-03 -.2448120E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999380E+06 0.0000 3 Cl- 0.1379635E-03 0.1379798E-03 0.4891500E+01 4.4564 4 SO4-- 0.2547910E-04 0.2550546E-04 0.2449946E+01 12.0228 5 HCO3- 0.1268349E-04 0.1307053E-04 0.7974787E+00 3.4199 6 HS- 0.2200068E-12 0.4486063E-10 0.1483540E-05 -4.3409 7 Al+++ 0.7401522E-22 0.7885858E-05 0.2127593E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4533383E-03 0.4357014E+02 -3.4276 9 Ca++ 0.2149244E-05 0.2203050E-05 0.8828845E-01 10.9488 10 Mg++ 0.8598556E-08 0.9301272E-08 0.2261187E-03 8.5509 11 Fe++ 0.5073346E-10 0.1209480E-08 0.6754172E-04 6.3218 12 K+ 0.3714024E-04 0.3715650E-04 0.1452805E+01 3.8865 13 Na+ 0.3792609E-03 0.3797541E-03 0.8729939E+01 4.8956 14 Mn++ 0.6792271E-08 0.1122368E-07 0.6165687E-03 8.4485 15 HPO4-- 0.2697524E-07 0.2908676E-07 0.2791548E-02 9.0476 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2884700E-02 -.2428884E-03 -.2641812E-02 0.0000000E+00 2 H2O 0.5550606E+02 0.5550606E+02 -.3460266E-06 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3035432E-04 0.2550443E-04 0.4849891E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4849847E-05 0.4485881E-10 -.4849891E-05 0.0000000E+00 7 Al+++ 0.5706298E-03 0.7885536E-05 0.5627442E-03 0.0000000E+00 8 H4SiO4 0.1822237E-02 0.4533199E-03 0.1368917E-02 0.0000000E+00 9 Ca++ 0.2157460E-03 0.2202960E-05 0.2135431E-03 0.0000000E+00 10 Mg++ 0.1388889E-03 0.9300893E-08 0.1388796E-03 0.0000000E+00 11 Fe++ 0.1247765E-03 0.1209431E-08 0.1247753E-03 0.0000000E+00 12 K+ 0.3715499E-04 0.3715499E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3797386E-03 0.3797386E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3034254E-05 0.1122322E-07 0.3023031E-05 0.0000000E+00 15 HPO4-- 0.1035576E-05 0.2908557E-07 0.1006490E-05 0.0000000E+00 Chg. balance for solid moles: 0.2079E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1750000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3355E-06 -6.474 0.1685E-03 -3.773 0.1030 0.5355E-04 clinochlore 0.2778E-04 -4.556 0.1544E-01 -1.811 9.439 0.5872E-02 daphnite 0.1720E-04 -4.765 0.1227E-01 -1.911 7.501 0.3718E-02 chlorite-Mn 0.6046E-06 -6.219 0.4286E-03 -3.368 0.2621 0.1366E-03 hematite 0.1940E-04 -4.712 0.3098E-02 -2.509 1.894 0.5872E-03 kaolinite 0.2393E-04 -4.621 0.6178E-02 -2.209 3.777 0.2377E-02 lawsonite 0.5975E-04 -4.224 0.1877E-01 -1.726 11.48 0.6054E-02 stilbite 0.1521E-03 -3.818 0.1072 -0.970 65.54 0.5000E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1327E-01 0.1327E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.163557 g Volume = 0.068800 cm3 Porosity: 93.5701% V(tot) - V(min): 0.10012E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1750000 g log = -0.7570 Original solution: 1000.0103000 g Original solution / Rock added: 5714.34 (Water/Rock Ratio), log = 3.7570 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1241E-04 1.0071 0.1275E-04 0.1266E-04 CH4,gas 0.1575E-15 1.0125 0.1627E-15 0.1607E-15 H2,gas 0.5857E-06 1.0005 0.5979E-06 0.5976E-06 H2S,gas 0.8089E-13 0.9960 0.8220E-13 0.8253E-13 S2,gas 0.6954E-33 1.0000 0.7095E-33 0.7095E-33 CO,gas 0.1992E-14 1.0000 0.2032E-14 0.2032E-14 SO3,gas 0.1757E-36 1.0000 0.1793E-36 0.1793E-36 SO2,gas 0.4088E-20 1.0000 0.4171E-20 0.4171E-20 HCl,gas 0.1923E-15 1.0000 0.1962E-15 0.1962E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.25 -6.59 -2.198 0.11258E+05 -4.894 3 CH4,gas 4.54 -12.94 -17.49 -4.372 0.29859E+05 -15.789 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.01 -14.78 -7.392 0.25243E+05 -13.085 6 S2,gas -7.34 -42.18 -34.85 -5.361 0.59502E+05 -33.149 7 CO,gas 3.21 -13.18 -16.39 -5.043 0.27987E+05 -14.692 8 SO3,gas 17.12 -21.32 -38.45 -9.611 0.65644E+05 -36.746 9 SO2,gas 0.83 -21.25 -22.08 -5.888 0.37699E+05 -20.380 10 HCl,gas 5.19 -12.22 -17.41 -8.703 0.29721E+05 -15.707 11 acmite 7.71 4.32 -3.39 -0.352 0.57820E+04 15 albite-high 0.69 -2.63 -3.32 -0.255 0.56673E+04 16 albite -0.38 -2.63 -2.24 -0.172 0.38285E+04 19 spessartine 24.46 20.59 -3.87 -0.194 0.66116E+04 20 analcite 3.32 0.80 -2.52 -0.280 0.43033E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 15.33 -4.79 -0.266 0.81841E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.30 -3.27 -1.090 0.55855E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.30 -3.12 -1.039 0.53212E+04 38 carnegieite-low 9.02 4.23 -4.79 -0.685 0.81858E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.49 -3.85 -0.227 0.65796E+04 43 celadonite-Fe 3.88 -0.74 -4.62 -0.272 0.78842E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14645E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64762E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82467E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68800E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.80 -3.41 -0.341 0.58288E+04 97 kalsilite 7.58 3.22 -4.36 -0.623 0.74510E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.21 -4.33 -0.433 0.73871E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.64 -1.15 -0.088 0.19612E+04 120 muscovite 2.58 1.89 -0.70 -0.041 0.11868E+04 121 paragonite 4.24 2.90 -1.34 -0.079 0.22931E+04 122 nepheline 8.34 4.23 -4.11 -0.587 0.70181E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40600E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.80 -3.83 -1.276 0.65373E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41402E+04 153 sanidine -1.28 -3.64 -2.36 -0.182 0.40290E+04 155 siderite -2.61 -6.93 -4.32 -1.441 0.73824E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.65 -1.36 -0.041 0.23277E+04 165 stilpnomelane-Mg 27.44 22.80 -4.64 -0.139 0.79262E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83504E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.659 0.78823E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.86 -3.34 -0.205 0.57079E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.53 -3.19 -0.195 0.54433E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.99 -2.76 -0.169 0.47095E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.66 -2.62 -0.161 0.44805E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.18 -1.16 -0.074 0.19809E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.51 -1.01 -0.065 0.17180E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.18 -2.20 -0.169 0.37486E+04 243 an25ab75 2.65 0.43 -2.21 -0.170 0.37756E+04 244 an30ab70 3.28 1.05 -2.23 -0.172 0.38122E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1750000 g New total amount of reactant added: 0.1790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1790000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3786211E-03 Osmotic coef. = 0.9884 True ionic strength = .4542515E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.47029E-08 -8.3276 0.44908E-08 -8.3477 0.95489E+00 -0.0200 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13171E-03 -3.8804 0.95470E+00 -0.0201 4 SO4-- 0.25480E-04 -4.5938 0.22342E-04 -4.6509 0.87687E+00 -0.0571 5 HCO3- 0.12680E-04 -4.8969 0.12106E-04 -4.9170 0.95475E+00 -0.0201 6 HS- 0.21441E-12 -12.6688 0.20470E-12 -12.6889 0.95471E+00 -0.0201 7 Al+++ 0.68721E-22 -22.1629 0.52264E-22 -22.2818 0.76053E+00 -0.1189 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.20448E-05 -5.6893 0.17926E-05 -5.7465 0.87667E+00 -0.0572 10 Mg++ 0.81807E-08 -8.0872 0.71707E-08 -8.1444 0.87653E+00 -0.0572 11 Fe++ 0.48268E-10 -10.3163 0.42310E-10 -10.3736 0.87656E+00 -0.0572 12 K+ 0.37989E-04 -4.4203 0.36270E-04 -4.4404 0.95476E+00 -0.0201 13 Na+ 0.38426E-03 -3.4154 0.36686E-03 -3.4355 0.95470E+00 -0.0201 14 Mn++ 0.64636E-08 -8.1895 0.56659E-08 -8.2467 0.87659E+00 -0.0572 15 HPO4-- 0.28391E-07 -7.5468 0.24896E-07 -7.6039 0.87688E+00 -0.0571 16 HSiO3- 0.81360E-04 -4.0896 0.77675E-04 -4.1097 0.95470E+00 -0.0201 17 Ca(HSiO3)+ 0.33213E-08 -8.4787 0.31710E-08 -8.4988 0.95476E+00 -0.0201 18 Mg(HSiO3)+ 0.16534E-10 -10.7816 0.15786E-10 -10.8017 0.95476E+00 -0.0201 19 NaHSiO3,aq 0.46087E-06 -6.3364 0.46087E-06 -6.3364 0.10000E+01 0.0000 20 AlO+ 0.36927E-12 -12.4327 0.35256E-12 -12.4528 0.95476E+00 -0.0201 21 AlOH+2 0.89935E-17 -17.0461 0.78838E-17 -17.1033 0.87662E+00 -0.0572 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.80728E-05 -5.0930 0.77067E-05 -5.1131 0.95464E+00 -0.0202 24 CH4,aq 0.10775E-18 -18.9676 0.10774E-18 -18.9676 0.99988E+00 -0.0001 29 CO,aq 0.13290E-17 -17.8765 0.13290E-17 -17.8765 0.10000E+01 0.0000 30 CO2,aq 0.11618E-06 -6.9349 0.11617E-06 -6.9349 0.99988E+00 -0.0001 31 CO3-2 0.26855E-06 -6.5710 0.23547E-06 -6.6281 0.87681E+00 -0.0571 32 CaCO3,aq 0.52926E-08 -8.2763 0.52926E-08 -8.2763 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58020E-09 -9.2364 0.55395E-09 -9.2565 0.95476E+00 -0.0201 34 CaCl+ 0.40021E-09 -9.3977 0.38210E-09 -9.4178 0.95476E+00 -0.0201 35 CaCl2,aq 0.11957E-13 -13.9224 0.11957E-13 -13.9224 0.10000E+01 0.0000 36 CaOH+ 0.29797E-07 -7.5258 0.28449E-07 -7.5459 0.95476E+00 -0.0201 37 CaSO4,aq 0.12718E-07 -7.8956 0.12718E-07 -7.8956 0.10000E+01 0.0000 38 HCl,aq 0.10839E-12 -12.9650 0.10839E-12 -12.9650 0.10000E+01 0.0000 43 FeCl+ 0.92388E-14 -14.0344 0.88208E-14 -14.0545 0.95476E+00 -0.0201 46 FeO,aq 0.81539E-10 -10.0886 0.81539E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.32121E-09 -9.4932 0.30668E-09 -9.5133 0.95476E+00 -0.0201 48 HFeO2- 0.19899E-09 -9.7012 0.18998E-09 -9.7213 0.95470E+00 -0.0201 49 FeO+ 0.35902E-13 -13.4449 0.34278E-13 -13.4650 0.95476E+00 -0.0201 50 FeOH+2 0.33534E-19 -19.4745 0.29397E-19 -19.5317 0.87662E+00 -0.0572 51 FeO2- 0.36429E-09 -9.4386 0.34779E-09 -9.4587 0.95470E+00 -0.0201 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45546E-09 -9.3416 0.45541E-09 -9.3416 0.99988E+00 -0.0001 54 KCl,aq 0.86585E-10 -10.0626 0.86585E-10 -10.0626 0.10000E+01 0.0000 55 KHSO4,aq 0.10289E-16 -16.9876 0.10289E-16 -16.9876 0.10000E+01 0.0000 56 KOH,aq 0.34492E-08 -8.4623 0.34492E-08 -8.4623 0.10000E+01 0.0000 57 KSO4- 0.13172E-07 -7.8804 0.12575E-07 -7.9005 0.95470E+00 -0.0201 58 MgCO3,aq 0.53067E-11 -11.2752 0.53067E-11 -11.2752 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23715E-11 -11.6250 0.22642E-11 -11.6451 0.95476E+00 -0.0201 60 MgCl+ 0.14509E-11 -11.8383 0.13853E-11 -11.8585 0.95476E+00 -0.0201 61 MgOH+ 0.65955E-09 -9.1808 0.62971E-09 -9.2009 0.95476E+00 -0.0201 63 MnO,aq 0.29095E-09 -9.5362 0.29095E-09 -9.5362 0.10000E+01 0.0000 64 MnOH+ 0.39959E-08 -8.3984 0.38152E-08 -8.4185 0.95476E+00 -0.0201 65 MnO2-2 0.54606E-15 -15.2628 0.47879E-15 -15.3199 0.87681E+00 -0.0571 66 HMnO2- 0.49341E-12 -12.3068 0.47106E-12 -12.3269 0.95470E+00 -0.0201 69 MnCl+ 0.48133E-11 -11.3176 0.45956E-11 -11.3377 0.95476E+00 -0.0201 70 MnSO4,aq 0.36546E-10 -10.4372 0.36546E-10 -10.4372 0.10000E+01 0.0000 71 NaCl,aq 0.16013E-07 -7.7955 0.16013E-07 -7.7955 0.10000E+01 0.0000 72 NaOH,aq 0.35098E-07 -7.4547 0.35098E-07 -7.4547 0.10000E+01 0.0000 74 OH- 0.13477E-03 -3.8704 0.12866E-03 -3.8906 0.95464E+00 -0.0202 79 HPO3-2 0.40296E-19 -19.3947 0.35332E-19 -19.4518 0.87681E+00 -0.0571 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.21602E-08 -8.6655 0.20624E-08 -8.6856 0.95473E+00 -0.0201 84 PO4-3 0.59375E-11 -11.2264 0.45231E-11 -11.3446 0.76178E+00 -0.1182 87 H2P2O7-2 0.38038E-18 -18.4198 0.33353E-18 -18.4769 0.87681E+00 -0.0571 88 HP2O7-3 0.19499E-16 -16.7100 0.14830E-16 -16.8289 0.76054E+00 -0.1189 89 P2O7-4 0.12646E-17 -17.8980 0.78890E-18 -18.1030 0.62384E+00 -0.2049 90 H2S,aq 0.28414E-14 -14.5465 0.28411E-14 -14.5465 0.99988E+00 -0.0001 97 SO3-2 0.15072E-14 -14.8218 0.13222E-14 -14.8787 0.87724E+00 -0.0569 98 HSO3- 0.38942E-15 -15.4096 0.37178E-15 -15.4297 0.95470E+00 -0.0201 99 HSO4- 0.10127E-09 -9.9945 0.96694E-10 -10.0146 0.95479E+00 -0.0201 Charge balance for all species = 0.7202E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4702921E-08 -.2491597E-03 -.2511226E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999377E+06 0.0000 3 Cl- 0.1379634E-03 0.1379799E-03 0.4891502E+01 4.4673 4 SO4-- 0.2547950E-04 0.2550548E-04 0.2449947E+01 12.0445 5 HCO3- 0.1267993E-04 0.1307054E-04 0.7974790E+00 3.4307 6 HS- 0.2144085E-12 0.4371121E-10 0.1445529E-05 -4.3412 7 Al+++ 0.6872105E-22 0.8088439E-05 0.2182248E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4553971E-03 0.4376799E+02 -3.4276 9 Ca++ 0.2044805E-05 0.2096914E-05 0.8403497E-01 10.9488 10 Mg++ 0.8180727E-08 0.8865938E-08 0.2155355E-03 8.5509 11 Fe++ 0.4826796E-10 0.1212988E-08 0.6773761E-04 6.3218 12 K+ 0.3798912E-04 0.3800582E-04 0.1486013E+01 3.9072 13 Na+ 0.3842636E-03 0.3847756E-03 0.8845371E+01 4.9122 14 Mn++ 0.6463618E-08 0.1079236E-07 0.5928743E-03 8.4486 15 HPO4-- 0.2839124E-07 0.3055741E-07 0.2932689E-02 9.0915 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2950934E-02 -.2491494E-03 -.2701785E-02 0.0000000E+00 2 H2O 0.5550601E+02 0.5550602E+02 -.8862229E-05 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3046517E-04 0.2550443E-04 0.4960744E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4960700E-05 0.4370940E-10 -.4960744E-05 0.0000000E+00 7 Al+++ 0.5836727E-03 0.8088104E-05 0.5755846E-03 0.0000000E+00 8 H4SiO4 0.1863888E-02 0.4553782E-03 0.1408510E-02 0.0000000E+00 9 Ca++ 0.2203466E-03 0.2096827E-05 0.2182498E-03 0.0000000E+00 10 Mg++ 0.1420635E-03 0.8865570E-08 0.1420546E-03 0.0000000E+00 11 Fe++ 0.1276285E-03 0.1212938E-08 0.1276273E-03 0.0000000E+00 12 K+ 0.3800425E-04 0.3800425E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3847596E-03 0.3847596E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3103609E-05 0.1079191E-07 0.3092817E-05 0.0000000E+00 15 HPO4-- 0.1059246E-05 0.3055614E-07 0.1028690E-05 0.0000000E+00 Chg. balance for solid moles: -.3558E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3429E-06 -6.465 0.1722E-03 -3.764 0.1026 0.5473E-04 clinochlore 0.2841E-04 -4.547 0.1579E-01 -1.802 9.404 0.6007E-02 daphnite 0.1759E-04 -4.755 0.1255E-01 -1.901 7.473 0.3803E-02 chlorite-Mn 0.6186E-06 -6.209 0.4385E-03 -3.358 0.2611 0.1398E-03 hematite 0.1984E-04 -4.702 0.3169E-02 -2.499 1.887 0.6006E-03 kaolinite 0.2464E-04 -4.608 0.6361E-02 -2.196 3.788 0.2447E-02 lawsonite 0.5927E-04 -4.227 0.1863E-01 -1.730 11.09 0.6007E-02 stilbite 0.1573E-03 -3.803 0.1108 -0.955 65.99 0.5169E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1327E-01 0.1327E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.167933 g Volume = 0.070750 cm3 Porosity: 93.3978% V(tot) - V(min): 0.10009E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1790000 g log = -0.7471 Original solution: 1000.0103000 g Original solution / Rock added: 5586.65 (Water/Rock Ratio), log = 3.7472 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1210E-04 1.0071 0.1243E-04 0.1234E-04 CH4,gas 0.1535E-15 1.0125 0.1586E-15 0.1566E-15 H2,gas 0.5857E-06 1.0005 0.5979E-06 0.5976E-06 H2S,gas 0.7685E-13 0.9960 0.7810E-13 0.7841E-13 S2,gas 0.6277E-33 1.0000 0.6405E-33 0.6405E-33 CO,gas 0.1941E-14 1.0000 0.1980E-14 0.1980E-14 SO3,gas 0.1670E-36 1.0000 0.1704E-36 0.1704E-36 SO2,gas 0.3884E-20 1.0000 0.3963E-20 0.3963E-20 HCl,gas 0.1874E-15 1.0000 0.1913E-15 0.1913E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.17819E-10 102 lawsonite 9.62 9.62 0.00 0.000 0.24265E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.26 -6.60 -2.202 0.11277E+05 -4.906 3 CH4,gas 4.54 -12.96 -17.50 -4.375 0.29879E+05 -15.800 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.04 -14.81 -7.403 0.25281E+05 -13.107 6 S2,gas -7.34 -42.23 -34.89 -5.368 0.59578E+05 -33.194 7 CO,gas 3.21 -13.19 -16.40 -5.047 0.28006E+05 -14.703 8 SO3,gas 17.12 -21.35 -38.47 -9.617 0.65682E+05 -36.769 9 SO2,gas 0.83 -21.27 -22.10 -5.894 0.37737E+05 -20.402 10 HCl,gas 5.19 -12.23 -17.42 -8.709 0.29740E+05 -15.718 11 acmite 7.71 4.34 -3.37 -0.350 0.57537E+04 15 albite-high 0.69 -2.61 -3.30 -0.254 0.56390E+04 16 albite -0.38 -2.61 -2.23 -0.171 0.38001E+04 19 spessartine 24.46 20.59 -3.87 -0.194 0.66111E+04 20 analcite 3.32 0.82 -2.50 -0.278 0.42750E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 15.35 -4.77 -0.265 0.81488E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.32 -3.28 -1.094 0.56045E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.32 -3.13 -1.043 0.53403E+04 38 carnegieite-low 9.02 4.25 -4.78 -0.683 0.81575E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.51 -3.83 -0.225 0.65443E+04 43 celadonite-Fe 3.88 -0.72 -4.60 -0.270 0.78488E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14643E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82467E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68800E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.82 -3.40 -0.340 0.58005E+04 97 kalsilite 7.58 3.24 -4.34 -0.620 0.74157E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.19 -4.31 -0.431 0.73518E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.61 -1.13 -0.087 0.19259E+04 120 muscovite 2.58 1.91 -0.67 -0.040 0.11514E+04 121 paragonite 4.24 2.91 -1.33 -0.078 0.22648E+04 122 nepheline 8.34 4.25 -4.09 -0.585 0.69898E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40598E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.82 -3.84 -1.280 0.65562E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41401E+04 153 sanidine -1.28 -3.61 -2.34 -0.180 0.39936E+04 155 siderite -2.61 -6.94 -4.33 -1.445 0.74014E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.66 -1.35 -0.040 0.23100E+04 165 stilpnomelane-Mg 27.44 22.81 -4.63 -0.138 0.79085E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83504E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.659 0.78820E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.86 -3.34 -0.204 0.56963E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.52 -3.18 -0.195 0.54339E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.99 -2.75 -0.168 0.46978E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.66 -2.62 -0.160 0.44712E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.19 -1.15 -0.074 0.19692E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.52 -1.00 -0.064 0.17086E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.16 -2.18 -0.168 0.37259E+04 243 an25ab75 2.65 0.45 -2.20 -0.169 0.37544E+04 244 an30ab70 3.28 1.06 -2.22 -0.171 0.37924E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1790000 g New total amount of reactant added: 0.1830000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1830000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3822745E-03 Osmotic coef. = 0.9884 True ionic strength = .4598166E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.45890E-08 -8.3383 0.43813E-08 -8.3584 0.95473E+00 -0.0201 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13169E-03 -3.8804 0.95454E+00 -0.0202 4 SO4-- 0.25480E-04 -4.5938 0.22328E-04 -4.6512 0.87629E+00 -0.0574 5 HCO3- 0.12676E-04 -4.8970 0.12101E-04 -4.9172 0.95459E+00 -0.0202 6 HS- 0.20907E-12 -12.6797 0.19957E-12 -12.6999 0.95454E+00 -0.0202 7 Al+++ 0.63914E-22 -22.1944 0.48535E-22 -22.3139 0.75938E+00 -0.1195 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.19476E-05 -5.7105 0.17063E-05 -5.7679 0.87607E+00 -0.0575 10 Mg++ 0.77920E-08 -8.1084 0.68253E-08 -8.1659 0.87594E+00 -0.0575 11 Fe++ 0.45974E-10 -10.3375 0.40272E-10 -10.3950 0.87597E+00 -0.0575 12 K+ 0.38838E-04 -4.4107 0.37075E-04 -4.4309 0.95459E+00 -0.0202 13 Na+ 0.38927E-03 -3.4098 0.37157E-03 -3.4300 0.95454E+00 -0.0202 14 Mn++ 0.61577E-08 -8.2106 0.53941E-08 -8.2681 0.87600E+00 -0.0575 15 HPO4-- 0.29848E-07 -7.5251 0.26155E-07 -7.5824 0.87629E+00 -0.0574 16 HSiO3- 0.83407E-04 -4.0788 0.79615E-04 -4.0990 0.95454E+00 -0.0202 17 Ca(HSiO3)+ 0.32409E-08 -8.4893 0.30937E-08 -8.5095 0.95460E+00 -0.0202 18 Mg(HSiO3)+ 0.16134E-10 -10.7923 0.15401E-10 -10.8124 0.95460E+00 -0.0202 19 NaHSiO3,aq 0.47846E-06 -6.3202 0.47846E-06 -6.3202 0.10000E+01 0.0000 20 AlO+ 0.36033E-12 -12.4433 0.34397E-12 -12.4635 0.95460E+00 -0.0202 21 AlOH+2 0.85661E-17 -17.0672 0.75041E-17 -17.1247 0.87603E+00 -0.0575 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.82759E-05 -5.0822 0.78992E-05 -5.1024 0.95448E+00 -0.0202 24 CH4,aq 0.10507E-18 -18.9785 0.10506E-18 -18.9786 0.99988E+00 -0.0001 29 CO,aq 0.12960E-17 -17.8874 0.12960E-17 -17.8874 0.10000E+01 0.0000 30 CO2,aq 0.11330E-06 -6.9458 0.11328E-06 -6.9458 0.99988E+00 -0.0001 31 CO3-2 0.27531E-06 -6.5602 0.24124E-06 -6.6176 0.87622E+00 -0.0574 32 CaCO3,aq 0.51612E-08 -8.2872 0.51612E-08 -8.2872 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.55210E-09 -9.2580 0.52703E-09 -9.2782 0.95460E+00 -0.0202 34 CaCl+ 0.38093E-09 -9.4192 0.36364E-09 -9.4393 0.95460E+00 -0.0202 35 CaCl2,aq 0.11377E-13 -13.9440 0.11377E-13 -13.9440 0.10000E+01 0.0000 36 CaOH+ 0.29075E-07 -7.5365 0.27756E-07 -7.5567 0.95460E+00 -0.0202 37 CaSO4,aq 0.12098E-07 -7.9173 0.12098E-07 -7.9173 0.10000E+01 0.0000 38 HCl,aq 0.10573E-12 -12.9758 0.10573E-12 -12.9758 0.10000E+01 0.0000 43 FeCl+ 0.87938E-14 -14.0558 0.83946E-14 -14.0760 0.95460E+00 -0.0202 46 FeO,aq 0.81538E-10 -10.0886 0.81538E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.31343E-09 -9.5039 0.29920E-09 -9.5240 0.95460E+00 -0.0202 48 HFeO2- 0.20400E-09 -9.6904 0.19472E-09 -9.7106 0.95454E+00 -0.0202 49 FeO+ 0.35033E-13 -13.4555 0.33442E-13 -13.4757 0.95460E+00 -0.0202 50 FeOH+2 0.31941E-19 -19.4957 0.27981E-19 -19.5531 0.87603E+00 -0.0575 51 FeO2- 0.37346E-09 -9.4278 0.35648E-09 -9.4480 0.95454E+00 -0.0202 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45546E-09 -9.3416 0.45540E-09 -9.3416 0.99988E+00 -0.0001 54 KCl,aq 0.88490E-10 -10.0531 0.88490E-10 -10.0531 0.10000E+01 0.0000 55 KHSO4,aq 0.10254E-16 -16.9891 0.10254E-16 -16.9891 0.10000E+01 0.0000 56 KOH,aq 0.36137E-08 -8.4420 0.36137E-08 -8.4420 0.10000E+01 0.0000 57 KSO4- 0.13457E-07 -7.8711 0.12845E-07 -7.8913 0.95454E+00 -0.0202 58 MgCO3,aq 0.51750E-11 -11.2861 0.51750E-11 -11.2861 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22566E-11 -11.6465 0.21542E-11 -11.6667 0.95460E+00 -0.0202 60 MgCl+ 0.13811E-11 -11.8598 0.13184E-11 -11.8800 0.95460E+00 -0.0202 61 MgOH+ 0.64358E-09 -9.1914 0.61436E-09 -9.2116 0.95460E+00 -0.0202 63 MnO,aq 0.29101E-09 -9.5361 0.29101E-09 -9.5361 0.10000E+01 0.0000 64 MnOH+ 0.39000E-08 -8.4089 0.37229E-08 -8.4291 0.95460E+00 -0.0202 65 MnO2-2 0.57419E-15 -15.2409 0.50312E-15 -15.2983 0.87622E+00 -0.0574 66 HMnO2- 0.50593E-12 -12.2959 0.48293E-12 -12.3161 0.95454E+00 -0.0202 69 MnCl+ 0.45824E-11 -11.3389 0.43744E-11 -11.3591 0.95460E+00 -0.0202 70 MnSO4,aq 0.34770E-10 -10.4588 0.34770E-10 -10.4588 0.10000E+01 0.0000 71 NaCl,aq 0.16216E-07 -7.7900 0.16216E-07 -7.7900 0.10000E+01 0.0000 72 NaOH,aq 0.36437E-07 -7.4385 0.36437E-07 -7.4385 0.10000E+01 0.0000 74 OH- 0.13816E-03 -3.8596 0.13187E-03 -3.8798 0.95448E+00 -0.0202 79 HPO3-2 0.42363E-19 -19.3730 0.37119E-19 -19.4304 0.87622E+00 -0.0574 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.22146E-08 -8.6547 0.21140E-08 -8.6749 0.95457E+00 -0.0202 84 PO4-3 0.64034E-11 -11.1936 0.48707E-11 -11.3124 0.76064E+00 -0.1188 87 H2P2O7-2 0.39990E-18 -18.3980 0.35040E-18 -18.4554 0.87622E+00 -0.0574 88 HP2O7-3 0.21029E-16 -16.6772 0.15969E-16 -16.7967 0.75939E+00 -0.1195 89 P2O7-4 0.13995E-17 -17.8540 0.87075E-18 -18.0601 0.62217E+00 -0.2061 90 H2S,aq 0.27027E-14 -14.5682 0.27024E-14 -14.5683 0.99988E+00 -0.0001 97 SO3-2 0.15072E-14 -14.8218 0.13213E-14 -14.8790 0.87665E+00 -0.0572 98 HSO3- 0.37974E-15 -15.4205 0.36247E-15 -15.4407 0.95454E+00 -0.0202 99 HSO4- 0.98756E-10 -10.0054 0.94275E-10 -10.0256 0.95463E+00 -0.0202 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4589046E-08 -.2554375E-03 -.2574498E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999374E+06 0.0000 3 Cl- 0.1379633E-03 0.1379800E-03 0.4891504E+01 4.4780 4 SO4-- 0.2547986E-04 0.2550551E-04 0.2449949E+01 12.0656 5 HCO3- 0.1267622E-04 0.1307055E-04 0.7974793E+00 3.4412 6 HS- 0.2090718E-12 0.4255922E-10 0.1407432E-05 -4.3415 7 Al+++ 0.6391380E-22 0.8291544E-05 0.2237045E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4574615E-03 0.4396639E+02 -3.4276 9 Ca++ 0.1947642E-05 0.1998150E-05 0.8007694E-01 10.9488 10 Mg++ 0.7792010E-08 0.8460534E-08 0.2056798E-03 8.5509 11 Fe++ 0.4597425E-10 0.1217085E-08 0.6796633E-04 6.3218 12 K+ 0.3883799E-04 0.3885515E-04 0.1519220E+01 3.9275 13 Na+ 0.3892660E-03 0.3897971E-03 0.8960804E+01 4.9284 14 Mn++ 0.6157717E-08 0.1038855E-07 0.5706908E-03 8.4487 15 HPO4-- 0.2984770E-07 0.3206867E-07 0.3077729E-02 9.1343 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3017168E-02 -.2554267E-03 -.2761742E-02 0.0000000E+00 2 H2O 0.5550596E+02 0.5550597E+02 -.1738101E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3057602E-04 0.2550443E-04 0.5071596E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5071554E-05 0.4255742E-10 -.5071596E-05 0.0000000E+00 7 Al+++ 0.5967157E-03 0.8291194E-05 0.5884245E-03 0.0000000E+00 8 H4SiO4 0.1905539E-02 0.4574422E-03 0.1448097E-02 0.0000000E+00 9 Ca++ 0.2249472E-03 0.1998066E-05 0.2229491E-03 0.0000000E+00 10 Mg++ 0.1452381E-03 0.8460176E-08 0.1452296E-03 0.0000000E+00 11 Fe++ 0.1304806E-03 0.1217033E-08 0.1304794E-03 0.0000000E+00 12 K+ 0.3885350E-04 0.3885350E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3897806E-03 0.3897806E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3172963E-05 0.1038811E-07 0.3162575E-05 0.0000000E+00 15 HPO4-- 0.1082917E-05 0.3206732E-07 0.1050849E-05 0.0000000E+00 Chg. balance for solid moles: 0.9021E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1830000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3503E-06 -6.456 0.1760E-03 -3.755 0.1021 0.5591E-04 clinochlore 0.2905E-04 -4.537 0.1614E-01 -1.792 9.370 0.6141E-02 daphnite 0.1798E-04 -4.745 0.1283E-01 -1.892 7.446 0.3888E-02 chlorite-Mn 0.6325E-06 -6.199 0.4484E-03 -3.348 0.2603 0.1429E-03 hematite 0.2029E-04 -4.693 0.3240E-02 -2.489 1.880 0.6141E-03 kaolinite 0.2535E-04 -4.596 0.6546E-02 -2.184 3.799 0.2519E-02 lawsonite 0.5880E-04 -4.231 0.1848E-01 -1.733 10.72 0.5958E-02 stilbite 0.1624E-03 -3.789 0.1144 -0.941 66.42 0.5338E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1327E-01 0.1327E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.172308 g Volume = 0.072699 cm3 Porosity: 93.2260% V(tot) - V(min): 0.10005E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1830000 g log = -0.7375 Original solution: 1000.0103000 g Original solution / Rock added: 5464.54 (Water/Rock Ratio), log = 3.7376 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1180E-04 1.0071 0.1212E-04 0.1203E-04 CH4,gas 0.1497E-15 1.0125 0.1546E-15 0.1527E-15 H2,gas 0.5857E-06 1.0005 0.5979E-06 0.5976E-06 H2S,gas 0.7310E-13 0.9960 0.7429E-13 0.7458E-13 S2,gas 0.5679E-33 1.0000 0.5795E-33 0.5795E-33 CO,gas 0.1893E-14 1.0000 0.1931E-14 0.1931E-14 SO3,gas 0.1588E-36 1.0000 0.1621E-36 0.1621E-36 SO2,gas 0.3695E-20 1.0000 0.3770E-20 0.3770E-20 HCl,gas 0.1828E-15 1.0000 0.1866E-15 0.1866E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 0.00000E+00 47 daphnite 28.97 28.97 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.28 -6.62 -2.205 0.11296E+05 -4.916 3 CH4,gas 4.54 -12.97 -17.51 -4.377 0.29897E+05 -15.811 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.06 -14.83 -7.414 0.25319E+05 -13.129 6 S2,gas -7.34 -42.27 -34.94 -5.375 0.59652E+05 -33.237 7 CO,gas 3.21 -13.20 -16.41 -5.050 0.28025E+05 -14.714 8 SO3,gas 17.12 -21.37 -38.49 -9.622 0.65719E+05 -36.790 9 SO2,gas 0.83 -21.29 -22.12 -5.899 0.37774E+05 -20.424 10 HCl,gas 5.19 -12.24 -17.43 -8.714 0.29758E+05 -15.729 11 acmite 7.71 4.36 -3.35 -0.348 0.57259E+04 15 albite-high 0.69 -2.59 -3.29 -0.253 0.56112E+04 16 albite -0.38 -2.59 -2.21 -0.170 0.37724E+04 19 spessartine 24.46 20.59 -3.87 -0.194 0.66106E+04 20 analcite 3.32 0.83 -2.49 -0.276 0.42472E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 15.37 -4.75 -0.264 0.81142E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.33 -3.29 -1.098 0.56232E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.33 -3.14 -1.046 0.53589E+04 38 carnegieite-low 9.02 4.26 -4.76 -0.680 0.81297E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.53 -3.81 -0.224 0.65097E+04 43 celadonite-Fe 3.88 -0.70 -4.58 -0.269 0.78143E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43573E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14642E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82467E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68800E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.83 -3.38 -0.338 0.57727E+04 97 kalsilite 7.58 3.26 -4.32 -0.618 0.73811E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.17 -4.29 -0.429 0.73172E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.59 -1.11 -0.085 0.18913E+04 120 muscovite 2.58 1.93 -0.65 -0.038 0.11169E+04 121 paragonite 4.24 2.93 -1.31 -0.077 0.22370E+04 122 nepheline 8.34 4.26 -4.08 -0.582 0.69621E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40597E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.83 -3.85 -1.284 0.65747E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41399E+04 153 sanidine -1.28 -3.59 -2.32 -0.178 0.39591E+04 155 siderite -2.61 -6.95 -4.35 -1.449 0.74201E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.67 -1.34 -0.040 0.22927E+04 165 stilpnomelane-Mg 27.44 22.82 -4.62 -0.138 0.78913E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83504E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.659 0.78817E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.85 -3.33 -0.204 0.56849E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.52 -3.18 -0.195 0.54248E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.98 -2.74 -0.168 0.46864E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.65 -2.61 -0.160 0.44620E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.19 -1.15 -0.074 0.19578E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.52 -1.00 -0.064 0.16995E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.15 -2.17 -0.167 0.37037E+04 243 an25ab75 2.65 0.46 -2.19 -0.168 0.37335E+04 244 an30ab70 3.28 1.07 -2.21 -0.170 0.37729E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1830000 g New total amount of reactant added: 0.1870000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1870000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3859436E-03 Osmotic coef. = 0.9883 True ionic strength = .4654016E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.44804E-08 -8.3487 0.42769E-08 -8.3689 0.95458E+00 -0.0202 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13167E-03 -3.8805 0.95438E+00 -0.0203 4 SO4-- 0.25480E-04 -4.5938 0.22313E-04 -4.6514 0.87570E+00 -0.0576 5 HCO3- 0.12672E-04 -4.8971 0.12095E-04 -4.9174 0.95443E+00 -0.0203 6 HS- 0.20398E-12 -12.6904 0.19468E-12 -12.7107 0.95438E+00 -0.0203 7 Al+++ 0.59540E-22 -22.2252 0.45145E-22 -22.3454 0.75823E+00 -0.1202 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.18571E-05 -5.7312 0.16259E-05 -5.7889 0.87549E+00 -0.0578 10 Mg++ 0.74299E-08 -8.1290 0.65037E-08 -8.1868 0.87535E+00 -0.0578 11 Fe++ 0.43837E-10 -10.3582 0.38374E-10 -10.4160 0.87538E+00 -0.0578 12 K+ 0.39687E-04 -4.4014 0.37879E-04 -4.4216 0.95443E+00 -0.0203 13 Na+ 0.39427E-03 -3.4042 0.37628E-03 -3.4245 0.95438E+00 -0.0203 14 Mn++ 0.58726E-08 -8.2312 0.51409E-08 -8.2890 0.87541E+00 -0.0578 15 HPO4-- 0.31345E-07 -7.5038 0.27449E-07 -7.5615 0.87571E+00 -0.0576 16 HSiO3- 0.85459E-04 -4.0682 0.81560E-04 -4.0885 0.95438E+00 -0.0203 17 Ca(HSiO3)+ 0.31641E-08 -8.4997 0.30200E-08 -8.5200 0.95444E+00 -0.0203 18 Mg(HSiO3)+ 0.15752E-10 -10.8027 0.15034E-10 -10.8229 0.95444E+00 -0.0203 19 NaHSiO3,aq 0.49636E-06 -6.3042 0.49636E-06 -6.3042 0.10000E+01 0.0000 20 AlO+ 0.35180E-12 -12.4537 0.33577E-12 -12.4740 0.95444E+00 -0.0203 21 AlOH+2 0.81680E-17 -17.0879 0.71506E-17 -17.1457 0.87544E+00 -0.0578 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.84795E-05 -5.0716 0.80921E-05 -5.0919 0.95432E+00 -0.0203 24 CH4,aq 0.10252E-18 -18.9892 0.10250E-18 -18.9893 0.99988E+00 -0.0001 29 CO,aq 0.12645E-17 -17.8981 0.12645E-17 -17.8981 0.10000E+01 0.0000 30 CO2,aq 0.11054E-06 -6.9565 0.11053E-06 -6.9565 0.99988E+00 -0.0001 31 CO3-2 0.28209E-06 -6.5496 0.24701E-06 -6.6073 0.87564E+00 -0.0577 32 CaCO3,aq 0.50358E-08 -8.2979 0.50358E-08 -8.2979 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52592E-09 -9.2791 0.50196E-09 -9.2993 0.95444E+00 -0.0203 34 CaCl+ 0.36298E-09 -9.4401 0.34645E-09 -9.4604 0.95444E+00 -0.0203 35 CaCl2,aq 0.10837E-13 -13.9651 0.10837E-13 -13.9651 0.10000E+01 0.0000 36 CaOH+ 0.28387E-07 -7.5469 0.27094E-07 -7.5671 0.95444E+00 -0.0203 37 CaSO4,aq 0.11520E-07 -7.9385 0.11520E-07 -7.9385 0.10000E+01 0.0000 38 HCl,aq 0.10319E-12 -12.9864 0.10319E-12 -12.9864 0.10000E+01 0.0000 43 FeCl+ 0.83794E-14 -14.0768 0.79976E-14 -14.0970 0.95444E+00 -0.0203 46 FeO,aq 0.81538E-10 -10.0886 0.81538E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.30601E-09 -9.5143 0.29207E-09 -9.5345 0.95444E+00 -0.0203 48 HFeO2- 0.20901E-09 -9.6798 0.19948E-09 -9.7001 0.95438E+00 -0.0203 49 FeO+ 0.34203E-13 -13.4659 0.32645E-13 -13.4862 0.95444E+00 -0.0203 50 FeOH+2 0.30456E-19 -19.5163 0.26663E-19 -19.5741 0.87544E+00 -0.0578 51 FeO2- 0.38264E-09 -9.4172 0.36519E-09 -9.4375 0.95438E+00 -0.0203 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45545E-09 -9.3416 0.45540E-09 -9.3416 0.99988E+00 -0.0001 54 KCl,aq 0.90393E-10 -10.0439 0.90393E-10 -10.0439 0.10000E+01 0.0000 55 KHSO4,aq 0.10220E-16 -16.9905 0.10220E-16 -16.9905 0.10000E+01 0.0000 56 KOH,aq 0.37823E-08 -8.4222 0.37823E-08 -8.4222 0.10000E+01 0.0000 57 KSO4- 0.13742E-07 -7.8619 0.13115E-07 -7.8822 0.95438E+00 -0.0203 58 MgCO3,aq 0.50492E-11 -11.2968 0.50492E-11 -11.2968 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21497E-11 -11.6676 0.20517E-11 -11.6879 0.95444E+00 -0.0203 60 MgCl+ 0.13160E-11 -11.8807 0.12560E-11 -11.9010 0.95444E+00 -0.0203 61 MgOH+ 0.62834E-09 -9.2018 0.59971E-09 -9.2221 0.95444E+00 -0.0203 63 MnO,aq 0.29106E-09 -9.5360 0.29106E-09 -9.5360 0.10000E+01 0.0000 64 MnOH+ 0.38083E-08 -8.4193 0.36348E-08 -8.4395 0.95444E+00 -0.0203 65 MnO2-2 0.60309E-15 -15.2196 0.52809E-15 -15.2773 0.87564E+00 -0.0577 66 HMnO2- 0.51847E-12 -12.2853 0.49481E-12 -12.3056 0.95438E+00 -0.0203 69 MnCl+ 0.43673E-11 -11.3598 0.41683E-11 -11.3800 0.95444E+00 -0.0203 70 MnSO4,aq 0.33116E-10 -10.4800 0.33116E-10 -10.4800 0.10000E+01 0.0000 71 NaCl,aq 0.16419E-07 -7.7846 0.16419E-07 -7.7846 0.10000E+01 0.0000 72 NaOH,aq 0.37801E-07 -7.4225 0.37801E-07 -7.4225 0.10000E+01 0.0000 74 OH- 0.14156E-03 -3.8491 0.13509E-03 -3.8694 0.95432E+00 -0.0203 79 HPO3-2 0.44487E-19 -19.3518 0.38954E-19 -19.4094 0.87564E+00 -0.0577 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.22690E-08 -8.6442 0.21656E-08 -8.6644 0.95441E+00 -0.0203 84 PO4-3 0.68944E-11 -11.1615 0.52364E-11 -11.2810 0.75951E+00 -0.1195 87 H2P2O7-2 0.41995E-18 -18.3768 0.36773E-18 -18.4345 0.87564E+00 -0.0577 88 HP2O7-3 0.22642E-16 -16.6451 0.17168E-16 -16.7653 0.75824E+00 -0.1202 89 P2O7-4 0.15455E-17 -17.8109 0.95899E-18 -18.0182 0.62050E+00 -0.2073 90 H2S,aq 0.25735E-14 -14.5895 0.25732E-14 -14.5895 0.99988E+00 -0.0001 97 SO3-2 0.15072E-14 -14.8218 0.13205E-14 -14.8793 0.87607E+00 -0.0575 98 HSO3- 0.37050E-15 -15.4312 0.35360E-15 -15.4515 0.95438E+00 -0.0203 99 HSO4- 0.96354E-10 -10.0161 0.91967E-10 -10.0364 0.95447E+00 -0.0202 Charge balance for all species = 0.7205E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4480372E-08 -.2617302E-03 -.2637920E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999370E+06 0.0000 3 Cl- 0.1379632E-03 0.1379801E-03 0.4891506E+01 4.4884 4 SO4-- 0.2548018E-04 0.2550553E-04 0.2449950E+01 12.0863 5 HCO3- 0.1267236E-04 0.1307056E-04 0.7974797E+00 3.4515 6 HS- 0.2039799E-12 0.4140489E-10 0.1369257E-05 -4.3418 7 Al+++ 0.5953999E-22 0.8495125E-05 0.2291970E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4595310E-03 0.4416527E+02 -3.4276 9 Ca++ 0.1857119E-05 0.1906115E-05 0.7638854E-01 10.9488 10 Mg++ 0.7429856E-08 0.8082459E-08 0.1964886E-03 8.5509 11 Fe++ 0.4383731E-10 0.1221726E-08 0.6822551E-04 6.3218 12 K+ 0.3968686E-04 0.3970447E-04 0.1552428E+01 3.9473 13 Na+ 0.3942680E-03 0.3948186E-03 0.9076236E+01 4.9444 14 Mn++ 0.5872594E-08 0.1000997E-07 0.5498934E-03 8.4488 15 HPO4-- 0.3134457E-07 0.3362051E-07 0.3226662E-02 9.1763 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3083402E-02 -.2617190E-03 -.2821683E-02 0.0000000E+00 2 H2O 0.5550591E+02 0.5550593E+02 -.2590214E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3068688E-04 0.2550443E-04 0.5182449E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5182407E-05 0.4140310E-10 -.5182449E-05 0.0000000E+00 7 Al+++ 0.6097587E-03 0.8494759E-05 0.6012639E-03 0.0000000E+00 8 H4SiO4 0.1947190E-02 0.4595113E-03 0.1487679E-02 0.0000000E+00 9 Ca++ 0.2295477E-03 0.1906033E-05 0.2276417E-03 0.0000000E+00 10 Mg++ 0.1484127E-03 0.8082111E-08 0.1484046E-03 0.0000000E+00 11 Fe++ 0.1333326E-03 0.1221674E-08 0.1333314E-03 0.0000000E+00 12 K+ 0.3970276E-04 0.3970276E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3948016E-03 0.3948016E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3242317E-05 0.1000953E-07 0.3232308E-05 0.0000000E+00 15 HPO4-- 0.1106587E-05 0.3361906E-07 0.1072968E-05 0.0000000E+00 Chg. balance for solid moles: 0.6073E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1870000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3577E-06 -6.447 0.1797E-03 -3.746 0.1017 0.5709E-04 clinochlore 0.2968E-04 -4.528 0.1650E-01 -1.783 9.337 0.6275E-02 daphnite 0.1837E-04 -4.736 0.1311E-01 -1.882 7.420 0.3973E-02 chlorite-Mn 0.6465E-06 -6.189 0.4583E-03 -3.339 0.2594 0.1461E-03 hematite 0.2073E-04 -4.683 0.3311E-02 -2.480 1.874 0.6275E-03 kaolinite 0.2608E-04 -4.584 0.6732E-02 -2.172 3.810 0.2590E-02 lawsonite 0.5831E-04 -4.234 0.1832E-01 -1.737 10.37 0.5909E-02 stilbite 0.1675E-03 -3.776 0.1181 -0.928 66.83 0.5507E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1327E-01 0.1327E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.176683 g Volume = 0.074648 cm3 Porosity: 93.0547% V(tot) - V(min): 0.10002E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1870000 g log = -0.7282 Original solution: 1000.0103000 g Original solution / Rock added: 5347.65 (Water/Rock Ratio), log = 3.7282 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1151E-04 1.0071 0.1183E-04 0.1174E-04 CH4,gas 0.1460E-15 1.0125 0.1509E-15 0.1490E-15 H2,gas 0.5857E-06 1.0005 0.5979E-06 0.5976E-06 H2S,gas 0.6960E-13 0.9960 0.7074E-13 0.7102E-13 S2,gas 0.5150E-33 1.0000 0.5254E-33 0.5254E-33 CO,gas 0.1847E-14 1.0000 0.1884E-14 0.1884E-14 SO3,gas 0.1512E-36 1.0000 0.1543E-36 0.1543E-36 SO2,gas 0.3518E-20 1.0000 0.3590E-20 0.3590E-20 HCl,gas 0.1785E-15 1.0000 0.1821E-15 0.1821E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.24265E-10 90 hematite 12.57 12.57 0.00 0.000 -0.21232E-10 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.29 -6.63 -2.209 0.11314E+05 -4.927 3 CH4,gas 4.54 -12.98 -17.52 -4.380 0.29916E+05 -15.821 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.08 -14.85 -7.425 0.25355E+05 -13.150 6 S2,gas -7.34 -42.31 -34.98 -5.381 0.59725E+05 -33.279 7 CO,gas 3.21 -13.21 -16.42 -5.053 0.28043E+05 -14.725 8 SO3,gas 17.12 -21.39 -38.51 -9.628 0.65756E+05 -36.812 9 SO2,gas 0.83 -21.31 -22.14 -5.905 0.37810E+05 -20.445 10 HCl,gas 5.19 -12.25 -17.44 -8.719 0.29776E+05 -15.740 11 acmite 7.71 4.37 -3.34 -0.347 0.56987E+04 15 albite-high 0.69 -2.58 -3.27 -0.252 0.55840E+04 16 albite -0.38 -2.58 -2.19 -0.169 0.37451E+04 19 spessartine 24.46 20.59 -3.87 -0.194 0.66102E+04 20 analcite 3.32 0.85 -2.47 -0.275 0.42200E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 15.39 -4.73 -0.263 0.80804E+04 27 phlogopite 27.06 22.08 -4.99 -0.277 0.85138E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.34 -3.30 -1.101 0.56414E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.34 -3.15 -1.050 0.53772E+04 38 carnegieite-low 9.02 4.28 -4.75 -0.678 0.81025E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.55 -3.79 -0.223 0.64759E+04 43 celadonite-Fe 3.88 -0.68 -4.56 -0.268 0.77805E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14640E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82467E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68800E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.85 -3.36 -0.336 0.57455E+04 97 kalsilite 7.58 3.28 -4.30 -0.615 0.73473E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.15 -4.27 -0.427 0.72834E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.57 -1.09 -0.084 0.18575E+04 120 muscovite 2.58 1.95 -0.63 -0.037 0.10831E+04 121 paragonite 4.24 2.95 -1.29 -0.076 0.22098E+04 122 nepheline 8.34 4.28 -4.06 -0.580 0.69348E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.476 0.40595E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.84 -3.86 -1.287 0.65928E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41398E+04 153 sanidine -1.28 -3.57 -2.30 -0.177 0.39253E+04 155 siderite -2.61 -6.96 -4.36 -1.452 0.74383E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.68 -1.33 -0.040 0.22759E+04 165 stilpnomelane-Mg 27.44 22.83 -4.61 -0.138 0.78744E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83504E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.659 0.78814E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.84 -3.32 -0.203 0.56737E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.51 -3.17 -0.194 0.54158E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.97 -2.74 -0.168 0.46752E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.65 -2.61 -0.160 0.44531E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.20 -1.14 -0.073 0.19467E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.53 -0.99 -0.064 0.16905E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.14 -2.16 -0.166 0.36819E+04 243 an25ab75 2.65 0.47 -2.17 -0.167 0.37131E+04 244 an30ab70 3.28 1.08 -2.20 -0.169 0.37539E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1870000 g New total amount of reactant added: 0.1910000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1910000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3896272E-03 Osmotic coef. = 0.9882 True ionic strength = .4710046E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.43766E-08 -8.3589 0.41771E-08 -8.3791 0.95442E+00 -0.0203 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13165E-03 -3.8806 0.95422E+00 -0.0204 4 SO4-- 0.25480E-04 -4.5938 0.22298E-04 -4.6517 0.87512E+00 -0.0579 5 HCO3- 0.12668E-04 -4.8973 0.12089E-04 -4.9176 0.95427E+00 -0.0203 6 HS- 0.19912E-12 -12.7009 0.19000E-12 -12.7212 0.95422E+00 -0.0203 7 Al+++ 0.55553E-22 -22.2553 0.42059E-22 -22.3761 0.75709E+00 -0.1209 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.17727E-05 -5.7514 0.15509E-05 -5.8094 0.87490E+00 -0.0580 10 Mg++ 0.70920E-08 -8.1492 0.62038E-08 -8.2073 0.87476E+00 -0.0581 11 Fe++ 0.41844E-10 -10.3784 0.36605E-10 -10.4365 0.87480E+00 -0.0581 12 K+ 0.40536E-04 -4.3922 0.38682E-04 -4.4125 0.95428E+00 -0.0203 13 Na+ 0.39927E-03 -3.3987 0.38099E-03 -3.4191 0.95421E+00 -0.0204 14 Mn++ 0.56065E-08 -8.2513 0.49047E-08 -8.3094 0.87482E+00 -0.0581 15 HPO4-- 0.32882E-07 -7.4830 0.28776E-07 -7.5410 0.87512E+00 -0.0579 16 HSiO3- 0.87515E-04 -4.0579 0.83508E-04 -4.0783 0.95422E+00 -0.0204 17 Ca(HSiO3)+ 0.30908E-08 -8.5099 0.29495E-08 -8.5303 0.95428E+00 -0.0203 18 Mg(HSiO3)+ 0.15387E-10 -10.8129 0.14683E-10 -10.8332 0.95428E+00 -0.0203 19 NaHSiO3,aq 0.51458E-06 -6.2886 0.51458E-06 -6.2886 0.10000E+01 0.0000 20 AlO+ 0.34365E-12 -12.4639 0.32794E-12 -12.4842 0.95428E+00 -0.0203 21 AlOH+2 0.77965E-17 -17.1081 0.68208E-17 -17.1662 0.87485E+00 -0.0581 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.86835E-05 -5.0613 0.82854E-05 -5.0817 0.95416E+00 -0.0204 24 CH4,aq 0.10007E-18 -18.9997 0.10006E-18 -18.9997 0.99988E+00 -0.0001 29 CO,aq 0.12344E-17 -17.9086 0.12344E-17 -17.9086 0.10000E+01 0.0000 30 CO2,aq 0.10791E-06 -6.9669 0.10790E-06 -6.9670 0.99988E+00 -0.0001 31 CO3-2 0.28889E-06 -6.5393 0.25279E-06 -6.5972 0.87505E+00 -0.0580 32 CaCO3,aq 0.49159E-08 -8.3084 0.49159E-08 -8.3084 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.50151E-09 -9.2997 0.47858E-09 -9.3200 0.95428E+00 -0.0203 34 CaCl+ 0.34624E-09 -9.4606 0.33041E-09 -9.4809 0.95428E+00 -0.0203 35 CaCl2,aq 0.10334E-13 -13.9857 0.10334E-13 -13.9857 0.10000E+01 0.0000 36 CaOH+ 0.27729E-07 -7.5571 0.26462E-07 -7.5774 0.95428E+00 -0.0203 37 CaSO4,aq 0.10982E-07 -7.9593 0.10982E-07 -7.9593 0.10000E+01 0.0000 38 HCl,aq 0.10077E-12 -12.9967 0.10077E-12 -12.9967 0.10000E+01 0.0000 43 FeCl+ 0.79929E-14 -14.0973 0.76275E-14 -14.1176 0.95428E+00 -0.0203 46 FeO,aq 0.81537E-10 -10.0886 0.81537E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.29892E-09 -9.5244 0.28525E-09 -9.5448 0.95428E+00 -0.0203 48 HFeO2- 0.21404E-09 -9.6695 0.20424E-09 -9.6899 0.95422E+00 -0.0204 49 FeO+ 0.33411E-13 -13.4761 0.31883E-13 -13.4964 0.95428E+00 -0.0203 50 FeOH+2 0.29071E-19 -19.5365 0.25433E-19 -19.5946 0.87485E+00 -0.0581 51 FeO2- 0.39185E-09 -9.4069 0.37391E-09 -9.4272 0.95422E+00 -0.0204 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45545E-09 -9.3416 0.45539E-09 -9.3416 0.99988E+00 -0.0001 54 KCl,aq 0.92296E-10 -10.0348 0.92296E-10 -10.0348 0.10000E+01 0.0000 55 KHSO4,aq 0.10187E-16 -16.9920 0.10187E-16 -16.9920 0.10000E+01 0.0000 56 KOH,aq 0.39548E-08 -8.4029 0.39548E-08 -8.4029 0.10000E+01 0.0000 57 KSO4- 0.14027E-07 -7.8530 0.13385E-07 -7.8734 0.95422E+00 -0.0204 58 MgCO3,aq 0.49290E-11 -11.3072 0.49290E-11 -11.3072 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20499E-11 -11.6883 0.19562E-11 -11.7086 0.95428E+00 -0.0203 60 MgCl+ 0.12553E-11 -11.9013 0.11979E-11 -11.9216 0.95428E+00 -0.0203 61 MgOH+ 0.61378E-09 -9.2120 0.58572E-09 -9.2323 0.95428E+00 -0.0203 63 MnO,aq 0.29111E-09 -9.5359 0.29111E-09 -9.5359 0.10000E+01 0.0000 64 MnOH+ 0.37207E-08 -8.4294 0.35506E-08 -8.4497 0.95428E+00 -0.0203 65 MnO2-2 0.63278E-15 -15.1987 0.55371E-15 -15.2567 0.87505E+00 -0.0580 66 HMnO2- 0.53103E-12 -12.2749 0.50672E-12 -12.2952 0.95422E+00 -0.0204 69 MnCl+ 0.41666E-11 -11.3802 0.39761E-11 -11.4005 0.95428E+00 -0.0203 70 MnSO4,aq 0.31573E-10 -10.5007 0.31573E-10 -10.5007 0.10000E+01 0.0000 71 NaCl,aq 0.16622E-07 -7.7793 0.16622E-07 -7.7793 0.10000E+01 0.0000 72 NaOH,aq 0.39188E-07 -7.4068 0.39188E-07 -7.4068 0.10000E+01 0.0000 74 OH- 0.14497E-03 -3.8387 0.13832E-03 -3.8591 0.95416E+00 -0.0204 79 HPO3-2 0.46668E-19 -19.3310 0.40837E-19 -19.3889 0.87505E+00 -0.0580 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.23236E-08 -8.6338 0.22173E-08 -8.6542 0.95425E+00 -0.0203 84 PO4-3 0.74114E-11 -11.1301 0.56206E-11 -11.2502 0.75838E+00 -0.1201 87 H2P2O7-2 0.44055E-18 -18.3560 0.38551E-18 -18.4140 0.87505E+00 -0.0580 88 HP2O7-3 0.24340E-16 -16.6137 0.18428E-16 -16.7345 0.75710E+00 -0.1208 89 P2O7-4 0.17031E-17 -17.7688 0.10540E-17 -17.9772 0.61885E+00 -0.2084 90 H2S,aq 0.24532E-14 -14.6103 0.24529E-14 -14.6103 0.99988E+00 -0.0001 97 SO3-2 0.15072E-14 -14.8218 0.13196E-14 -14.8796 0.87549E+00 -0.0577 98 HSO3- 0.36168E-15 -15.4417 0.34512E-15 -15.4620 0.95422E+00 -0.0204 99 HSO4- 0.94060E-10 -10.0266 0.89763E-10 -10.0469 0.95431E+00 -0.0203 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4376571E-08 -.2680366E-03 -.2701479E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999367E+06 0.0000 3 Cl- 0.1379632E-03 0.1379802E-03 0.4891508E+01 4.4985 4 SO4-- 0.2548045E-04 0.2550555E-04 0.2449951E+01 12.1065 5 HCO3- 0.1266835E-04 0.1307057E-04 0.7974800E+00 3.4615 6 HS- 0.1991173E-12 0.4024843E-10 0.1331013E-05 -4.3421 7 Al+++ 0.5555284E-22 0.8699140E-05 0.2347012E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4616053E-03 0.4436460E+02 -3.4276 9 Ca++ 0.1772664E-05 0.1820229E-05 0.7294660E-01 10.9488 10 Mg++ 0.7091977E-08 0.7729378E-08 0.1879049E-03 8.5509 11 Fe++ 0.4184363E-10 0.1226874E-08 0.6851298E-04 6.3218 12 K+ 0.4053572E-04 0.4055380E-04 0.1585635E+01 3.9666 13 Na+ 0.3992697E-03 0.3998401E-03 0.9191669E+01 4.9600 14 Mn++ 0.5606476E-08 0.9654566E-08 0.5303694E-03 8.4489 15 HPO4-- 0.3288182E-07 0.3521287E-07 0.3379485E-02 9.2173 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3149636E-02 -.2680248E-03 -.2881612E-02 0.0000000E+00 2 H2O 0.5550586E+02 0.5550589E+02 -.3442538E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3079773E-04 0.2550443E-04 0.5293301E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5293261E-05 0.4024667E-10 -.5293301E-05 0.0000000E+00 7 Al+++ 0.6228016E-03 0.8698759E-05 0.6141029E-03 0.0000000E+00 8 H4SiO4 0.1988842E-02 0.4615850E-03 0.1527257E-02 0.0000000E+00 9 Ca++ 0.2341483E-03 0.1820150E-05 0.2323282E-03 0.0000000E+00 10 Mg++ 0.1515873E-03 0.7729039E-08 0.1515796E-03 0.0000000E+00 11 Fe++ 0.1361846E-03 0.1226821E-08 0.1361834E-03 0.0000000E+00 12 K+ 0.4055202E-04 0.4055202E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3998225E-03 0.3998225E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3311672E-05 0.9654143E-08 0.3302018E-05 0.0000000E+00 15 HPO4-- 0.1130257E-05 0.3521132E-07 0.1095046E-05 0.0000000E+00 Chg. balance for solid moles: 0.1935E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1910000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3650E-06 -6.438 0.1834E-03 -3.737 0.1013 0.5826E-04 clinochlore 0.3032E-04 -4.518 0.1685E-01 -1.773 9.307 0.6409E-02 daphnite 0.1877E-04 -4.727 0.1339E-01 -1.873 7.396 0.4058E-02 chlorite-Mn 0.6604E-06 -6.180 0.4682E-03 -3.330 0.2586 0.1492E-03 hematite 0.2117E-04 -4.674 0.3381E-02 -2.471 1.868 0.6409E-03 kaolinite 0.2680E-04 -4.572 0.6920E-02 -2.160 3.822 0.2663E-02 lawsonite 0.5782E-04 -4.238 0.1817E-01 -1.741 10.04 0.5859E-02 stilbite 0.1727E-03 -3.763 0.1217 -0.915 67.21 0.5676E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1328E-01 0.1328E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.181056 g Volume = 0.076597 cm3 Porosity: 92.8840% V(tot) - V(min): 0.99980E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1910000 g log = -0.7190 Original solution: 1000.0103000 g Original solution / Rock added: 5235.66 (Water/Rock Ratio), log = 3.7190 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1123E-04 1.0071 0.1154E-04 0.1146E-04 CH4,gas 0.1426E-15 1.0125 0.1473E-15 0.1455E-15 H2,gas 0.5857E-06 1.0005 0.5979E-06 0.5976E-06 H2S,gas 0.6635E-13 0.9960 0.6743E-13 0.6770E-13 S2,gas 0.4679E-33 1.0000 0.4774E-33 0.4774E-33 CO,gas 0.1803E-14 1.0000 0.1839E-14 0.1839E-14 SO3,gas 0.1442E-36 1.0000 0.1471E-36 0.1471E-36 SO2,gas 0.3354E-20 1.0000 0.3422E-20 0.3422E-20 HCl,gas 0.1743E-15 1.0000 0.1778E-15 0.1778E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.24265E-10 47 daphnite 28.97 28.97 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 0.00000E+00 90 hematite 12.57 12.57 0.00 0.000 -0.30331E-11 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.30 -6.64 -2.212 0.11332E+05 -4.938 3 CH4,gas 4.54 -12.99 -17.53 -4.383 0.29933E+05 -15.832 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.10 -14.87 -7.435 0.25390E+05 -13.171 6 S2,gas -7.34 -42.36 -35.02 -5.388 0.59796E+05 -33.321 7 CO,gas 3.21 -13.22 -16.43 -5.057 0.28061E+05 -14.735 8 SO3,gas 17.12 -21.41 -38.53 -9.633 0.65791E+05 -36.832 9 SO2,gas 0.83 -21.33 -22.16 -5.911 0.37846E+05 -20.466 10 HCl,gas 5.19 -12.26 -17.45 -8.725 0.29794E+05 -15.750 11 acmite 7.71 4.39 -3.32 -0.345 0.56719E+04 15 albite-high 0.69 -2.56 -3.25 -0.250 0.55572E+04 16 albite -0.38 -2.56 -2.18 -0.168 0.37184E+04 19 spessartine 24.46 20.59 -3.87 -0.194 0.66099E+04 20 analcite 3.32 0.87 -2.46 -0.273 0.41933E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 15.41 -4.71 -0.262 0.80473E+04 27 phlogopite 27.06 22.10 -4.97 -0.276 0.84807E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.35 -3.31 -1.105 0.56593E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.35 -3.16 -1.053 0.53951E+04 38 carnegieite-low 9.02 4.29 -4.73 -0.676 0.80757E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.57 -3.77 -0.222 0.64428E+04 43 celadonite-Fe 3.88 -0.66 -4.54 -0.267 0.77474E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14639E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82467E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68801E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.87 -3.35 -0.335 0.57187E+04 97 kalsilite 7.58 3.30 -4.28 -0.612 0.73142E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.13 -4.25 -0.425 0.72503E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.55 -1.07 -0.082 0.18244E+04 120 muscovite 2.58 1.97 -0.61 -0.036 0.10500E+04 121 paragonite 4.24 2.96 -1.28 -0.075 0.21831E+04 122 nepheline 8.34 4.29 -4.05 -0.578 0.69081E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40594E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.85 -3.87 -1.291 0.66106E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41397E+04 153 sanidine -1.28 -3.55 -2.28 -0.175 0.38922E+04 155 siderite -2.61 -6.97 -4.37 -1.456 0.74562E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.69 -1.32 -0.039 0.22593E+04 165 stilpnomelane-Mg 27.44 22.84 -4.60 -0.137 0.78578E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83504E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.659 0.78812E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.84 -3.32 -0.203 0.56628E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.51 -3.17 -0.194 0.54070E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.97 -2.73 -0.167 0.46643E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.64 -2.60 -0.159 0.44442E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.21 -1.13 -0.073 0.19358E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.53 -0.98 -0.063 0.16817E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.13 -2.14 -0.165 0.36605E+04 243 an25ab75 2.65 0.48 -2.16 -0.166 0.36931E+04 244 an30ab70 3.28 1.09 -2.19 -0.168 0.37352E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1910000 g New total amount of reactant added: 0.1950000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1950000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3933240E-03 Osmotic coef. = 0.9882 True ionic strength = .4766241E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.42773E-08 -8.3688 0.40817E-08 -8.3892 0.95426E+00 -0.0203 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13162E-03 -3.8807 0.95406E+00 -0.0204 4 SO4-- 0.25481E-04 -4.5938 0.22284E-04 -4.6520 0.87454E+00 -0.0582 5 HCO3- 0.12664E-04 -4.8974 0.12083E-04 -4.9178 0.95411E+00 -0.0204 6 HS- 0.19447E-12 -12.7111 0.18554E-12 -12.7316 0.95406E+00 -0.0204 7 Al+++ 0.51911E-22 -22.2847 0.39243E-22 -22.4062 0.75596E+00 -0.1215 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.16938E-05 -5.7711 0.14809E-05 -5.8295 0.87432E+00 -0.0583 10 Mg++ 0.67763E-08 -8.1690 0.59237E-08 -8.2274 0.87418E+00 -0.0584 11 Fe++ 0.39981E-10 -10.3981 0.34952E-10 -10.4565 0.87421E+00 -0.0584 12 K+ 0.41385E-04 -4.3832 0.39486E-04 -4.4036 0.95412E+00 -0.0204 13 Na+ 0.40427E-03 -3.3933 0.38570E-03 -3.4138 0.95405E+00 -0.0204 14 Mn++ 0.53578E-08 -8.2710 0.46840E-08 -8.3294 0.87424E+00 -0.0584 15 HPO4-- 0.34459E-07 -7.4627 0.30136E-07 -7.5209 0.87454E+00 -0.0582 16 HSiO3- 0.89575E-04 -4.0478 0.85460E-04 -4.0682 0.95406E+00 -0.0204 17 Ca(HSiO3)+ 0.30207E-08 -8.5199 0.28822E-08 -8.5403 0.95412E+00 -0.0204 18 Mg(HSiO3)+ 0.15038E-10 -10.8228 0.14348E-10 -10.8432 0.95412E+00 -0.0204 19 NaHSiO3,aq 0.53311E-06 -6.2732 0.53311E-06 -6.2732 0.10000E+01 0.0000 20 AlO+ 0.33585E-12 -12.4738 0.32045E-12 -12.4942 0.95412E+00 -0.0204 21 AlOH+2 0.74495E-17 -17.1279 0.65129E-17 -17.1862 0.87427E+00 -0.0584 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.88879E-05 -5.0512 0.84791E-05 -5.0717 0.95400E+00 -0.0205 24 CH4,aq 0.97737E-19 -19.0099 0.97725E-19 -19.0100 0.99988E+00 -0.0001 29 CO,aq 0.12056E-17 -17.9188 0.12056E-17 -17.9188 0.10000E+01 0.0000 30 CO2,aq 0.10540E-06 -6.9772 0.10538E-06 -6.9772 0.99988E+00 -0.0001 31 CO3-2 0.29569E-06 -6.5292 0.25857E-06 -6.5874 0.87447E+00 -0.0583 32 CaCO3,aq 0.48013E-08 -8.3186 0.48013E-08 -8.3186 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47871E-09 -9.3199 0.45675E-09 -9.3403 0.95412E+00 -0.0204 34 CaCl+ 0.33061E-09 -9.4807 0.31544E-09 -9.5011 0.95412E+00 -0.0204 35 CaCl2,aq 0.98643E-14 -14.0059 0.98643E-14 -14.0059 0.10000E+01 0.0000 36 CaOH+ 0.27101E-07 -7.5670 0.25857E-07 -7.5874 0.95412E+00 -0.0204 37 CaSO4,aq 0.10479E-07 -7.9797 0.10479E-07 -7.9797 0.10000E+01 0.0000 38 HCl,aq 0.98449E-13 -13.0068 0.98449E-13 -13.0068 0.10000E+01 0.0000 43 FeCl+ 0.76320E-14 -14.1174 0.72819E-14 -14.1378 0.95412E+00 -0.0204 46 FeO,aq 0.81537E-10 -10.0886 0.81537E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.29214E-09 -9.5344 0.27874E-09 -9.5548 0.95412E+00 -0.0204 48 HFeO2- 0.21908E-09 -9.6594 0.20901E-09 -9.6798 0.95406E+00 -0.0204 49 FeO+ 0.32653E-13 -13.4861 0.31155E-13 -13.5065 0.95412E+00 -0.0204 50 FeOH+2 0.27777E-19 -19.5563 0.24285E-19 -19.6147 0.87427E+00 -0.0584 51 FeO2- 0.40107E-09 -9.3968 0.38265E-09 -9.4172 0.95406E+00 -0.0204 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45545E-09 -9.3416 0.45539E-09 -9.3416 0.99988E+00 -0.0001 54 KCl,aq 0.94197E-10 -10.0260 0.94197E-10 -10.0260 0.10000E+01 0.0000 55 KHSO4,aq 0.10154E-16 -16.9933 0.10154E-16 -16.9933 0.10000E+01 0.0000 56 KOH,aq 0.41313E-08 -8.3839 0.41313E-08 -8.3839 0.10000E+01 0.0000 57 KSO4- 0.14311E-07 -7.8443 0.13654E-07 -7.8647 0.95406E+00 -0.0204 58 MgCO3,aq 0.48141E-11 -11.3175 0.48141E-11 -11.3175 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19567E-11 -11.7085 0.18669E-11 -11.7289 0.95412E+00 -0.0204 60 MgCl+ 0.11986E-11 -11.9213 0.11436E-11 -11.9417 0.95412E+00 -0.0204 61 MgOH+ 0.59986E-09 -9.2219 0.57234E-09 -9.2423 0.95412E+00 -0.0204 63 MnO,aq 0.29116E-09 -9.5359 0.29116E-09 -9.5359 0.10000E+01 0.0000 64 MnOH+ 0.36369E-08 -8.4393 0.34701E-08 -8.4597 0.95412E+00 -0.0204 65 MnO2-2 0.66324E-15 -15.1783 0.57998E-15 -15.2366 0.87447E+00 -0.0583 66 HMnO2- 0.54362E-12 -12.2647 0.51864E-12 -12.2851 0.95406E+00 -0.0204 69 MnCl+ 0.39791E-11 -11.4002 0.37965E-11 -11.4206 0.95412E+00 -0.0204 70 MnSO4,aq 0.30133E-10 -10.5210 0.30133E-10 -10.5210 0.10000E+01 0.0000 71 NaCl,aq 0.16824E-07 -7.7741 0.16824E-07 -7.7741 0.10000E+01 0.0000 72 NaOH,aq 0.40599E-07 -7.3915 0.40599E-07 -7.3915 0.10000E+01 0.0000 74 OH- 0.14838E-03 -3.8286 0.14155E-03 -3.8491 0.95400E+00 -0.0205 79 HPO3-2 0.48907E-19 -19.3106 0.42768E-19 -19.3689 0.87447E+00 -0.0583 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.23783E-08 -8.6237 0.22691E-08 -8.6441 0.95409E+00 -0.0204 84 PO4-3 0.79549E-11 -11.0994 0.60239E-11 -11.2201 0.75726E+00 -0.1208 87 H2P2O7-2 0.46169E-18 -18.3357 0.40373E-18 -18.3939 0.87447E+00 -0.0583 88 HP2O7-3 0.26126E-16 -16.5829 0.19751E-16 -16.7044 0.75597E+00 -0.1215 89 P2O7-4 0.18729E-17 -17.7275 0.11560E-17 -17.9371 0.61721E+00 -0.2096 90 H2S,aq 0.23408E-14 -14.6306 0.23405E-14 -14.6307 0.99988E+00 -0.0001 97 SO3-2 0.15072E-14 -14.8218 0.13187E-14 -14.8799 0.87492E+00 -0.0580 98 HSO3- 0.35324E-15 -15.4519 0.33701E-15 -15.4724 0.95406E+00 -0.0204 99 HSO4- 0.91867E-10 -10.0368 0.87655E-10 -10.0572 0.95415E+00 -0.0204 Charge balance for all species = 0.7203E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4277340E-08 -.2743554E-03 -.2765164E+00 0.0000 2 H2O 0.1000000E+01 0.5550833E+02 0.9999363E+06 0.0000 3 Cl- 0.1379631E-03 0.1379803E-03 0.4891510E+01 4.5085 4 SO4-- 0.2548070E-04 0.2550557E-04 0.2449952E+01 12.1263 5 HCO3- 0.1266421E-04 0.1307058E-04 0.7974803E+00 3.4713 6 HS- 0.1944698E-12 0.3909004E-10 0.1292705E-05 -4.3424 7 Al+++ 0.5191132E-22 0.8903551E-05 0.2402161E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4636838E-03 0.4456435E+02 -3.4276 9 Ca++ 0.1693762E-05 0.1739973E-05 0.6973027E-01 10.9488 10 Mg++ 0.6776317E-08 0.7399188E-08 0.1798778E-03 8.5509 11 Fe++ 0.3998106E-10 0.1232494E-08 0.6882676E-04 6.3218 12 K+ 0.4138459E-04 0.4140312E-04 0.1618843E+01 3.9856 13 Na+ 0.4042710E-03 0.4048616E-03 0.9307102E+01 4.9754 14 Mn++ 0.5357766E-08 0.9320494E-08 0.5120171E-03 8.4489 15 HPO4-- 0.3445943E-07 0.3684572E-07 0.3536193E-02 9.2574 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3215871E-02 -.2743432E-03 -.2941527E-02 0.0000000E+00 2 H2O 0.5550581E+02 0.5550585E+02 -.4295054E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3090858E-04 0.2550443E-04 0.5404154E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5404115E-05 0.3908829E-10 -.5404154E-05 0.0000000E+00 7 Al+++ 0.6358446E-03 0.8903154E-05 0.6269415E-03 0.0000000E+00 8 H4SiO4 0.2030493E-02 0.4636631E-03 0.1566830E-02 0.0000000E+00 9 Ca++ 0.2387489E-03 0.1739896E-05 0.2370090E-03 0.0000000E+00 10 Mg++ 0.1547619E-03 0.7398858E-08 0.1547545E-03 0.0000000E+00 11 Fe++ 0.1390367E-03 0.1232439E-08 0.1390354E-03 0.0000000E+00 12 K+ 0.4140127E-04 0.4140127E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.4048435E-03 0.4048435E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3381026E-05 0.9320078E-08 0.3371706E-05 0.0000000E+00 15 HPO4-- 0.1153927E-05 0.3684407E-07 0.1117083E-05 0.0000000E+00 Chg. balance for solid moles: -.5895E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1950000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3724E-06 -6.429 0.1870E-03 -3.728 0.1009 0.5944E-04 clinochlore 0.3095E-04 -4.509 0.1720E-01 -1.764 9.278 0.6544E-02 daphnite 0.1916E-04 -4.718 0.1367E-01 -1.864 7.373 0.4143E-02 chlorite-Mn 0.6743E-06 -6.171 0.4781E-03 -3.320 0.2578 0.1524E-03 hematite 0.2162E-04 -4.665 0.3452E-02 -2.462 1.862 0.6543E-03 kaolinite 0.2754E-04 -4.560 0.7109E-02 -2.148 3.834 0.2735E-02 lawsonite 0.5733E-04 -4.242 0.1801E-01 -1.744 9.715 0.5809E-02 stilbite 0.1778E-03 -3.750 0.1253 -0.902 67.58 0.5845E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1328E-01 0.1328E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.185429 g Volume = 0.078546 cm3 Porosity: 92.7138% V(tot) - V(min): 0.99945E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1950000 g log = -0.7100 Original solution: 1000.0103000 g Original solution / Rock added: 5128.26 (Water/Rock Ratio), log = 3.7100 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1097E-04 1.0071 0.1127E-04 0.1120E-04 CH4,gas 0.1392E-15 1.0125 0.1438E-15 0.1421E-15 H2,gas 0.5857E-06 1.0005 0.5979E-06 0.5975E-06 H2S,gas 0.6331E-13 0.9960 0.6434E-13 0.6460E-13 S2,gas 0.4261E-33 1.0000 0.4347E-33 0.4347E-33 CO,gas 0.1761E-14 1.0000 0.1797E-14 0.1797E-14 SO3,gas 0.1376E-36 1.0000 0.1404E-36 0.1404E-36 SO2,gas 0.3200E-20 1.0000 0.3265E-20 0.3265E-20 HCl,gas 0.1703E-15 1.0000 0.1737E-15 0.1737E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 0.00000E+00 46 clinochlore 39.07 39.07 0.00 0.000 -0.12132E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.48529E-10 90 hematite 12.57 12.57 0.00 0.000 0.90992E-11 98 kaolinite -1.33 -1.33 0.00 0.000 0.56870E-11 102 lawsonite 9.62 9.62 0.00 0.000 -0.12132E-10 163 stilbite -7.52 -7.52 0.00 0.000 -0.33364E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.31 -6.65 -2.216 0.11349E+05 -4.948 3 CH4,gas 4.54 -13.00 -17.54 -4.385 0.29951E+05 -15.842 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.12 -14.89 -7.445 0.25425E+05 -13.192 6 S2,gas -7.34 -42.40 -35.06 -5.394 0.59865E+05 -33.362 7 CO,gas 3.21 -13.23 -16.44 -5.060 0.28079E+05 -14.746 8 SO3,gas 17.12 -21.43 -38.55 -9.638 0.65826E+05 -36.853 9 SO2,gas 0.83 -21.35 -22.19 -5.916 0.37880E+05 -20.486 10 HCl,gas 5.19 -12.27 -17.46 -8.730 0.29811E+05 -15.760 11 acmite 7.71 4.40 -3.31 -0.344 0.56457E+04 15 albite-high 0.69 -2.55 -3.24 -0.249 0.55310E+04 16 albite -0.38 -2.55 -2.16 -0.166 0.36922E+04 19 spessartine 24.46 20.59 -3.87 -0.194 0.66095E+04 20 analcite 3.32 0.88 -2.44 -0.271 0.41670E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 15.43 -4.69 -0.261 0.80150E+04 27 phlogopite 27.06 22.12 -4.95 -0.275 0.84484E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.36 -3.32 -1.108 0.56768E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.36 -3.17 -1.057 0.54125E+04 38 carnegieite-low 9.02 4.31 -4.71 -0.673 0.80495E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.59 -3.75 -0.221 0.64104E+04 43 celadonite-Fe 3.88 -0.64 -4.52 -0.266 0.77150E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14638E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82467E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68801E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.88 -3.33 -0.333 0.56925E+04 97 kalsilite 7.58 3.32 -4.26 -0.609 0.72818E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.11 -4.23 -0.423 0.72179E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.54 -1.05 -0.081 0.17921E+04 120 muscovite 2.58 1.99 -0.60 -0.035 0.10176E+04 121 paragonite 4.24 2.98 -1.26 -0.074 0.21568E+04 122 nepheline 8.34 4.31 -4.03 -0.576 0.68819E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49718E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40593E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.86 -3.88 -1.294 0.66279E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41395E+04 153 sanidine -1.28 -3.54 -2.26 -0.174 0.38598E+04 155 siderite -2.61 -6.99 -4.38 -1.459 0.74737E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.70 -1.31 -0.039 0.22432E+04 165 stilpnomelane-Mg 27.44 22.85 -4.59 -0.137 0.78417E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83504E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.659 0.78809E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.83 -3.31 -0.203 0.56521E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.50 -3.16 -0.194 0.53983E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.96 -2.73 -0.167 0.46536E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.64 -2.60 -0.159 0.44356E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.21 -1.13 -0.072 0.19251E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.54 -0.98 -0.063 0.16730E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.11 -2.13 -0.164 0.36396E+04 243 an25ab75 2.65 0.49 -2.15 -0.165 0.36734E+04 244 an30ab70 3.28 1.10 -2.18 -0.167 0.37168E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1950000 g New total amount of reactant added: 0.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 0.1990000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3970329E-03 Osmotic coef. = 0.9881 True ionic strength = .4822587E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.41824E-08 -8.3786 0.39904E-08 -8.3990 0.95410E+00 -0.0204 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13160E-03 -3.8807 0.95390E+00 -0.0205 4 SO4-- 0.25481E-04 -4.5938 0.22269E-04 -4.6523 0.87396E+00 -0.0585 5 HCO3- 0.12660E-04 -4.8976 0.12077E-04 -4.9180 0.95395E+00 -0.0205 6 HS- 0.19002E-12 -12.7212 0.18126E-12 -12.7417 0.95390E+00 -0.0205 7 Al+++ 0.48579E-22 -22.3135 0.36669E-22 -22.4357 0.75483E+00 -0.1222 8 H4SiO4 0.37357E-03 -3.4276 0.37357E-03 -3.4276 0.10000E+01 0.0000 9 Ca++ 0.16200E-05 -5.7905 0.14154E-05 -5.8491 0.87374E+00 -0.0586 10 Mg++ 0.64810E-08 -8.1884 0.56618E-08 -8.2470 0.87360E+00 -0.0587 11 Fe++ 0.38239E-10 -10.4175 0.33406E-10 -10.4762 0.87363E+00 -0.0587 12 K+ 0.42233E-04 -4.3743 0.40289E-04 -4.3948 0.95396E+00 -0.0205 13 Na+ 0.40927E-03 -3.3880 0.39040E-03 -3.4085 0.95390E+00 -0.0205 14 Mn++ 0.51250E-08 -8.2903 0.44775E-08 -8.3490 0.87365E+00 -0.0587 15 HPO4-- 0.36077E-07 -7.4428 0.31530E-07 -7.5013 0.87396E+00 -0.0585 16 HSiO3- 0.91639E-04 -4.0379 0.87414E-04 -4.0584 0.95390E+00 -0.0205 17 Ca(HSiO3)+ 0.29537E-08 -8.5296 0.28177E-08 -8.5501 0.95396E+00 -0.0205 18 Mg(HSiO3)+ 0.14704E-10 -10.8326 0.14027E-10 -10.8530 0.95396E+00 -0.0205 19 NaHSiO3,aq 0.55195E-06 -6.2581 0.55195E-06 -6.2581 0.10000E+01 0.0000 20 AlO+ 0.32840E-12 -12.4836 0.31328E-12 -12.5041 0.95396E+00 -0.0205 21 AlOH+2 0.71249E-17 -17.1472 0.62249E-17 -17.2059 0.87368E+00 -0.0586 22 HAlO2,aq 0.15635E-07 -7.8059 0.15635E-07 -7.8059 0.10000E+01 0.0000 23 AlO2- 0.90927E-05 -5.0413 0.86730E-05 -5.0618 0.95384E+00 -0.0205 24 CH4,aq 0.95501E-19 -19.0200 0.95489E-19 -19.0200 0.99988E+00 -0.0001 29 CO,aq 0.11780E-17 -17.9289 0.11780E-17 -17.9289 0.10000E+01 0.0000 30 CO2,aq 0.10299E-06 -6.9872 0.10298E-06 -6.9873 0.99988E+00 -0.0001 31 CO3-2 0.30250E-06 -6.5193 0.26435E-06 -6.5778 0.87389E+00 -0.0585 32 CaCO3,aq 0.46916E-08 -8.3287 0.46916E-08 -8.3287 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45739E-09 -9.3397 0.43634E-09 -9.3602 0.95396E+00 -0.0205 34 CaCl+ 0.31599E-09 -9.5003 0.30145E-09 -9.5208 0.95396E+00 -0.0205 35 CaCl2,aq 0.94250E-14 -14.0257 0.94250E-14 -14.0257 0.10000E+01 0.0000 36 CaOH+ 0.26499E-07 -7.5768 0.25279E-07 -7.5972 0.95396E+00 -0.0205 37 CaSO4,aq 0.10009E-07 -7.9996 0.10009E-07 -7.9996 0.10000E+01 0.0000 38 HCl,aq 0.96232E-13 -13.0167 0.96232E-13 -13.0167 0.10000E+01 0.0000 43 FeCl+ 0.72945E-14 -14.1370 0.69587E-14 -14.1575 0.95396E+00 -0.0205 46 FeO,aq 0.81537E-10 -10.0886 0.81537E-10 -10.0886 0.10000E+01 0.0000 47 FeOH+ 0.28566E-09 -9.5442 0.27251E-09 -9.5646 0.95396E+00 -0.0205 48 HFeO2- 0.22413E-09 -9.6495 0.21379E-09 -9.6700 0.95390E+00 -0.0205 49 FeO+ 0.31928E-13 -13.4958 0.30459E-13 -13.5163 0.95396E+00 -0.0205 50 FeOH+2 0.26567E-19 -19.5757 0.23211E-19 -19.6343 0.87368E+00 -0.0586 51 FeO2- 0.41031E-09 -9.3869 0.39140E-09 -9.4074 0.95390E+00 -0.0205 52 HFeO2,aq 0.19864E-09 -9.7019 0.19864E-09 -9.7019 0.10000E+01 0.0000 53 H2,aq 0.45544E-09 -9.3416 0.45539E-09 -9.3416 0.99988E+00 -0.0001 54 KCl,aq 0.96097E-10 -10.0173 0.96097E-10 -10.0173 0.10000E+01 0.0000 55 KHSO4,aq 0.10123E-16 -16.9947 0.10123E-16 -16.9947 0.10000E+01 0.0000 56 KOH,aq 0.43117E-08 -8.3653 0.43117E-08 -8.3653 0.10000E+01 0.0000 57 KSO4- 0.14595E-07 -7.8358 0.13922E-07 -7.8563 0.95390E+00 -0.0205 58 MgCO3,aq 0.47041E-11 -11.3275 0.47041E-11 -11.3275 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18695E-11 -11.7283 0.17835E-11 -11.7487 0.95396E+00 -0.0205 60 MgCl+ 0.11456E-11 -11.9410 0.10929E-11 -11.9614 0.95396E+00 -0.0205 61 MgOH+ 0.58655E-09 -9.2317 0.55955E-09 -9.2522 0.95396E+00 -0.0205 63 MnO,aq 0.29120E-09 -9.5358 0.29120E-09 -9.5358 0.10000E+01 0.0000 64 MnOH+ 0.35567E-08 -8.4490 0.33930E-08 -8.4694 0.95396E+00 -0.0205 65 MnO2-2 0.69448E-15 -15.1583 0.60690E-15 -15.2169 0.87389E+00 -0.0585 66 HMnO2- 0.55622E-12 -12.2548 0.53058E-12 -12.2753 0.95390E+00 -0.0205 69 MnCl+ 0.38037E-11 -11.4198 0.36286E-11 -11.4403 0.95396E+00 -0.0205 70 MnSO4,aq 0.28786E-10 -10.5408 0.28786E-10 -10.5408 0.10000E+01 0.0000 71 NaCl,aq 0.17027E-07 -7.7689 0.17027E-07 -7.7689 0.10000E+01 0.0000 72 NaOH,aq 0.42034E-07 -7.3764 0.42034E-07 -7.3764 0.10000E+01 0.0000 74 OH- 0.15180E-03 -3.8187 0.14479E-03 -3.8393 0.95384E+00 -0.0205 79 HPO3-2 0.51203E-19 -19.2907 0.44746E-19 -19.3492 0.87389E+00 -0.0585 82 H3PO4,aq 0.35115E-14 -14.4545 0.35115E-14 -14.4545 0.10000E+01 0.0000 83 H2PO4- 0.24331E-08 -8.6138 0.23210E-08 -8.6343 0.95393E+00 -0.0205 84 PO4-3 0.85258E-11 -11.0693 0.64467E-11 -11.1907 0.75614E+00 -0.1214 87 H2P2O7-2 0.48337E-18 -18.3157 0.42241E-18 -18.3743 0.87389E+00 -0.0585 88 HP2O7-3 0.28002E-16 -16.5528 0.21137E-16 -16.6750 0.75484E+00 -0.1221 89 P2O7-4 0.20556E-17 -17.6871 0.12654E-17 -17.8978 0.61558E+00 -0.2107 90 H2S,aq 0.22358E-14 -14.6506 0.22355E-14 -14.6506 0.99988E+00 -0.0001 97 SO3-2 0.15072E-14 -14.8218 0.13178E-14 -14.8801 0.87434E+00 -0.0583 98 HSO3- 0.34517E-15 -15.4620 0.32926E-15 -15.4825 0.95390E+00 -0.0205 99 HSO4- 0.89770E-10 -10.0469 0.85640E-10 -10.0673 0.95400E+00 -0.0205 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4182399E-08 -.2806856E-03 -.2828964E+00 0.0000 2 H2O 0.1000000E+01 0.5550833E+02 0.9999360E+06 0.0000 3 Cl- 0.1379630E-03 0.1379804E-03 0.4891512E+01 4.5182 4 SO4-- 0.2548091E-04 0.2550559E-04 0.2449953E+01 12.1457 5 HCO3- 0.1265995E-04 0.1307059E-04 0.7974806E+00 3.4809 6 HS- 0.1900242E-12 0.3792988E-10 0.1254338E-05 -4.3427 7 Al+++ 0.4857941E-22 0.9108325E-05 0.2457407E+00 2.7612 8 H4SiO4 0.3735728E-03 0.4657662E-03 0.4476448E+02 -3.4276 9 Ca++ 0.1619951E-05 0.1664878E-05 0.6672076E-01 10.9488 10 Mg++ 0.6481022E-08 0.7089995E-08 0.1723611E-03 8.5509 11 Fe++ 0.3823867E-10 0.1238552E-08 0.6916504E-04 6.3218 12 K+ 0.4223345E-04 0.4225245E-04 0.1652051E+01 4.0042 13 Na+ 0.4092721E-03 0.4098831E-03 0.9422535E+01 4.9905 14 Mn++ 0.5125022E-08 0.9006071E-08 0.4947443E-03 8.4490 15 HPO4-- 0.3607737E-07 0.3851902E-07 0.3696783E-02 9.2967 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3282105E-02 -.2806729E-03 -.3001432E-02 0.0000000E+00 2 H2O 0.5550576E+02 0.5550581E+02 -.5147744E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3101944E-04 0.2550443E-04 0.5515006E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5514968E-05 0.3792816E-10 -.5515006E-05 0.0000000E+00 7 Al+++ 0.6488876E-03 0.9107911E-05 0.6397797E-03 0.0000000E+00 8 H4SiO4 0.2072144E-02 0.4657451E-03 0.1606399E-02 0.0000000E+00 9 Ca++ 0.2433494E-03 0.1664802E-05 0.2416846E-03 0.0000000E+00 10 Mg++ 0.1579365E-03 0.7089673E-08 0.1579294E-03 0.0000000E+00 11 Fe++ 0.1418887E-03 0.1238496E-08 0.1418875E-03 0.0000000E+00 12 K+ 0.4225053E-04 0.4225053E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.4098645E-03 0.4098645E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3450381E-05 0.9005662E-08 0.3441375E-05 0.0000000E+00 15 HPO4-- 0.1177598E-05 0.3851727E-07 0.1139080E-05 0.0000000E+00 Chg. balance for solid moles: -.3041E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 0.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3797E-06 -6.421 0.1907E-03 -3.720 0.1005 0.6061E-04 clinochlore 0.3159E-04 -4.501 0.1756E-01 -1.756 9.250 0.6678E-02 daphnite 0.1955E-04 -4.709 0.1395E-01 -1.855 7.351 0.4228E-02 chlorite-Mn 0.6883E-06 -6.162 0.4880E-03 -3.312 0.2571 0.1555E-03 hematite 0.2206E-04 -4.656 0.3523E-02 -2.453 1.856 0.6677E-03 kaolinite 0.2828E-04 -4.549 0.7300E-02 -2.137 3.846 0.2809E-02 lawsonite 0.5683E-04 -4.245 0.1786E-01 -1.748 9.409 0.5759E-02 stilbite 0.1830E-03 -3.738 0.1289 -0.890 67.93 0.6014E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1328E-01 0.1328E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.189801 g Volume = 0.080494 cm3 Porosity: 92.5441% V(tot) - V(min): 0.99911E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1990000 g log = -0.7011 Original solution: 1000.0103000 g Original solution / Rock added: 5025.18 (Water/Rock Ratio), log = 3.7012 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0203 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9860 0.1006E+01 0.1020E+01 CO2,gas 0.1072E-04 1.0071 0.1102E-04 0.1094E-04 CH4,gas 0.1361E-15 1.0125 0.1406E-15 0.1388E-15 H2,gas 0.5857E-06 1.0005 0.5979E-06 0.5975E-06 H2S,gas 0.6047E-13 0.9960 0.6145E-13 0.6170E-13 S2,gas 0.3887E-33 1.0000 0.3966E-33 0.3966E-33 CO,gas 0.1721E-14 1.0000 0.1755E-14 0.1755E-14 SO3,gas 0.1314E-36 1.0000 0.1341E-36 0.1341E-36 SO2,gas 0.3057E-20 1.0000 0.3119E-20 0.3119E-20 HCl,gas 0.1664E-15 1.0000 0.1698E-15 0.1698E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -18.15 -18.15 0.00 0.000 -0.60662E-11 46 clinochlore 39.07 39.07 0.00 0.000 -0.36397E-10 47 daphnite 28.97 28.97 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.87 46.87 0.00 0.000 -0.12132E-10 90 hematite 12.57 12.57 0.00 0.000 -0.15165E-10 98 kaolinite -1.33 -1.33 0.00 0.000 -0.64453E-11 102 lawsonite 9.62 9.62 0.00 0.000 0.00000E+00 163 stilbite -7.52 -7.52 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 0.00 -1.70 -1.696 0.28965E+04 0.003 2 CO2,gas -6.66 -13.32 -6.66 -2.219 0.11366E+05 -4.958 3 CH4,gas 4.54 -13.01 -17.55 -4.388 0.29968E+05 -15.852 4 H2,gas 8.00 0.08 -7.92 -4.527 0.13527E+05 -6.223 5 H2S,gas -6.23 -21.14 -14.91 -7.455 0.25459E+05 -13.211 6 S2,gas -7.34 -42.44 -35.10 -5.400 0.59933E+05 -33.402 7 CO,gas 3.21 -13.24 -16.45 -5.063 0.28096E+05 -14.756 8 SO3,gas 17.12 -21.45 -38.57 -9.643 0.65860E+05 -36.873 9 SO2,gas 0.83 -21.37 -22.21 -5.921 0.37914E+05 -20.506 10 HCl,gas 5.19 -12.28 -17.47 -8.735 0.29828E+05 -15.770 11 acmite 7.71 4.42 -3.29 -0.342 0.56199E+04 15 albite-high 0.69 -2.53 -3.22 -0.248 0.55052E+04 16 albite -0.38 -2.53 -2.15 -0.165 0.36664E+04 19 spessartine 24.46 20.59 -3.87 -0.194 0.66092E+04 20 analcite 3.32 0.90 -2.43 -0.269 0.41413E+04 21 andalusite 5.00 2.09 -2.91 -0.291 0.49631E+04 22 andradite 39.01 35.13 -3.88 -0.202 0.66231E+04 23 grossular 32.73 28.09 -4.65 -0.232 0.79317E+04 26 annite 20.12 15.45 -4.68 -0.260 0.79833E+04 27 phlogopite 27.06 22.14 -4.93 -0.274 0.84167E+04 29 anorthite 12.71 9.62 -3.09 -0.238 0.52833E+04 35 aragonite 0.97 -2.37 -3.33 -1.112 0.56939E+04 36 brucite 12.57 8.55 -4.02 -0.804 0.68600E+04 37 calcite 0.81 -2.37 -3.18 -1.060 0.54297E+04 38 carnegieite-low 9.02 4.32 -4.70 -0.671 0.80237E+04 40 carpholite-Mg 8.58 7.22 -1.36 -0.091 0.23289E+04 41 carpholite-Fe 6.71 4.99 -1.72 -0.115 0.29430E+04 42 celadonite 5.34 1.61 -3.74 -0.220 0.63787E+04 43 celadonite-Fe 3.88 -0.62 -4.50 -0.265 0.76833E+04 50 chloritoid-Mg 13.20 10.65 -2.55 -0.170 0.43574E+04 51 chloritoid-Fe 9.17 8.42 -0.76 -0.050 0.12925E+04 52 chloritoid-Mn 11.40 10.54 -0.86 -0.057 0.14637E+04 54 coesite -2.38 -3.43 -1.05 -0.351 0.17955E+04 59 corundum 8.38 5.52 -2.86 -0.260 0.48845E+04 61 cristobalite -2.56 -3.43 -0.87 -0.289 0.14809E+04 65 diaspore 2.87 2.76 -0.11 -0.019 0.19202E+03 67 diopside 16.18 12.64 -3.54 -0.354 0.60391E+04 68 hedenbergite 14.21 10.42 -3.79 -0.379 0.64763E+04 75 epidote 24.67 23.42 -1.25 -0.061 0.21335E+04 76 clinozoisite 22.81 19.90 -2.91 -0.132 0.49645E+04 77 epidote-Fe 29.84 26.94 -2.90 -0.151 0.49492E+04 78 fayalite 14.05 9.22 -4.83 -0.690 0.82467E+04 83 gibbsite 4.08 2.76 -1.32 -0.188 0.22506E+04 87 greenalite 16.14 12.11 -4.03 -0.336 0.68801E+04 91 heulandite -5.83 -7.52 -1.69 -0.077 0.28938E+04 95 jadeite 4.22 0.90 -3.32 -0.332 0.56668E+04 97 kalsilite 7.58 3.34 -4.25 -0.607 0.72501E+04 99 kyanite 4.88 2.09 -2.78 -0.278 0.47490E+04 101 laumontite 2.88 2.76 -0.12 -0.008 0.20932E+03 103 leucite 4.12 -0.09 -4.21 -0.421 0.71862E+04 105 lizardite 23.24 18.80 -4.45 -0.371 0.75920E+04 107 magnetite 20.09 18.89 -1.20 -0.098 0.20480E+04 113 margarite 17.32 15.14 -2.19 -0.087 0.37309E+04 116 microcline -2.49 -3.52 -1.03 -0.079 0.17604E+04 120 muscovite 2.58 2.01 -0.58 -0.034 0.98593E+03 121 paragonite 4.24 2.99 -1.25 -0.073 0.21311E+04 122 nepheline 8.34 4.32 -4.02 -0.574 0.68561E+04 136 prehnite 19.37 17.14 -2.23 -0.131 0.38155E+04 137 prehnite-Fe 22.50 20.66 -1.84 -0.111 0.31396E+04 138 pumpellyite-Fe 46.27 43.36 -2.91 -0.065 0.49719E+04 139 pumpellyite-Mg 48.99 45.59 -3.41 -0.076 0.58193E+04 145 pyroxmangite 7.40 5.02 -2.38 -0.475 0.40592E+04 146 pyrophyllite -6.18 -8.19 -2.01 -0.126 0.34358E+04 147 quartz -2.99 -3.43 -0.44 -0.146 0.74820E+03 151 rhodochrosite -0.98 -4.87 -3.89 -1.297 0.66450E+04 152 rhodonite 7.45 5.02 -2.42 -0.485 0.41394E+04 153 sanidine -1.28 -3.52 -2.24 -0.172 0.38281E+04 155 siderite -2.61 -7.00 -4.39 -1.462 0.74908E+04 156 sillimanite 5.26 2.09 -3.17 -0.317 0.54070E+04 164 stilpnomelane-Fe 13.02 11.71 -1.30 -0.039 0.22273E+04 165 stilpnomelane-Mg 27.44 22.86 -4.58 -0.137 0.78258E+04 167 sudoite-Fe 18.30 13.41 -4.89 -0.158 0.83504E+04 168 sudoite 21.08 17.86 -3.21 -0.104 0.54869E+04 171 talc 16.49 11.94 -4.55 -0.268 0.77670E+04 174 tephroite 18.09 13.47 -4.62 -0.659 0.78807E+04 177 topaz-H 4.62 2.09 -2.52 -0.229 0.43090E+04 178 tridymite -2.63 -3.43 -0.80 -0.267 0.13682E+04 187 wairakite 3.95 2.76 -1.19 -0.070 0.20313E+04 188 walstromite 11.51 7.52 -3.99 -0.798 0.68094E+04 189 wollastonite 10.46 7.52 -2.94 -0.588 0.50199E+04 190 pseudo-wollastonite 11.00 7.52 -3.48 -0.696 0.59397E+04 191 zoisite 22.85 19.90 -2.95 -0.134 0.50385E+04 192 akaganeite 7.75 6.28 -1.47 -0.318 0.25125E+04 193 beidellite-Ca -1.65 -4.34 -2.69 -0.167 0.45991E+04 194 beidellite-H -2.33 -6.15 -3.82 -0.244 0.65216E+04 195 beidellite-K -1.52 -4.82 -3.30 -0.202 0.56416E+04 196 beidellite-Mg -1.79 -4.73 -2.95 -0.182 0.50285E+04 197 beidellite-Na -1.34 -4.50 -3.16 -0.193 0.53898E+04 199 chalcedony -2.80 -3.43 -0.63 -0.208 0.10675E+04 201 montmorillonite-Ca -2.29 -4.47 -2.18 -0.135 0.37225E+04 202 montmorillonite-K -2.24 -4.96 -2.72 -0.167 0.46432E+04 203 montmorillonite-Mg -2.48 -4.87 -2.39 -0.148 0.40751E+04 204 montmorillonite-Na -2.04 -4.63 -2.59 -0.159 0.44271E+04 205 nontronite-Ca 3.21 2.70 -0.51 -0.033 0.87076E+03 206 nontronite-H 2.53 0.90 -1.63 -0.110 0.27912E+04 207 nontronite-K 3.34 2.22 -1.12 -0.072 0.19146E+04 208 nontronite-Mg 3.07 2.31 -0.77 -0.050 0.13074E+04 209 nontronite-Na 3.52 2.54 -0.97 -0.063 0.16645E+04 224 tobermorite 9.82 5.69 -4.13 -1.127 0.70524E+04 233 boehmite 4.41 2.76 -1.65 -0.274 0.28089E+04 235 ferrous-oxide 9.81 6.32 -3.49 -0.872 0.59587E+04 240 silica-amorphous -2.09 -3.43 -1.34 -0.445 0.22817E+04 242 an20ab80 2.02 -0.10 -2.12 -0.163 0.36189E+04 243 an25ab75 2.65 0.51 -2.14 -0.165 0.36541E+04 244 an30ab70 3.28 1.11 -2.17 -0.167 0.36988E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1990000 g New total amount of reactant added: 0.2030000 g Mixing fraction reached given limit of 0.2000E+00 TOTMIX = 0.2030E+00 Execution stopped.